76044 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

DEPARTMENT OF TRANSPORTATION

Research and Special Programs 

Administration 

49 CFR Parts 171, 172, 173, 175, 176, 

178 and 180 

[Docket No. RSPA–04–17036 (HM–215G)] 

RIN 2137–AD92 

Harmonization With the United Nations 

Recommendations, International 

Maritime Dangerous Goods Code, and 

International Civil Aviation 

Organization’s Technical Instructions

AGENCY: Research and Special Programs 

Administration (RSPA), DOT.

ACTION: Final rule.

SUMMARY: RSPA is amending the 

Hazardous Materials Regulations (HMR) 

to maintain alignment with 

international standards by incorporating 

various amendments, including changes 

to proper shipping names, hazard 

classes, packing groups, special 

provisions, packaging authorizations, air 

transport quantity limitations and vessel 

stowage requirements. Because of recent 

changes to the International Maritime 

Dangerous Goods Code (IMDG Code), 

the International Civil Aviation 

Organization’s Technical Instructions 

for the Safe Transport of Dangerous 

Goods by Air (ICAO Technical 

Instructions), and the United Nations 

Recommendations on the Transport of 

Dangerous Goods (UN 

Recommendations), these revisions are 

necessary to facilitate the transport of 

hazardous materials in international 

commerce.

DATES: The effective date of these 

amendments is January 1, 2005 

Delayed Compliance Date: Unless 

otherwise specified, compliance with 

the amendments adopted in this final 

rule is required beginning January 1, 

2006. 

Incorporation by Reference Date: The 

incorporation by reference of the 

publications adopted in § 171.7 of this 

final rule have been approved by the 

Director of the Federal Register as of 

January 1, 2005.

FOR FURTHER INFORMATION CONTACT:

Charles Betts, Office of Hazardous 

Materials Standards, telephone (202) 

366–8553, or Shane Kelley, 

International Standards, telephone (202) 

366–0656, Research and Special 

Programs Administration, U.S. 

Department of Transportation, 400 

Seventh Street, SW., Washington, DC 

20590–0001.

SUPPLEMENTARY INFORMATION:

Contents 

I. Background 

II. Overview of Changes in this Final Rule 

III. Overview of Amendments Not Being 

Considered for Adoption in this Final 

Rule 

IV. Section-By-Section Review 

V. Regulatory Analyses and Notices 

A. Statutory/Legal Authority for this 

Rulemaking 

B. Executive Order 12866 and DOT 

Regulatory Policies and Procedures 

C. Executive Order 13132 

D. Executive Order 13175 

E. Regulatory Flexibility Act, Executive 

Order 13272, and DOT Regulatory 

Policies and Procedures 

F. Paperwork Reduction Act 

G. Regulatory Identifier Number (RIN) 

H. Unfunded Mandates Reform Act 

I. Environmental Assessment 

J. Privacy Act

I. Background 

On December 21, 1990, RSPA (we) 

published a final rule (Docket HM–181; 

55 FR 52402) based on the UN 

Recommendations, which 

comprehensively revised the Hazardous 

Materials Regulations (HMR), 49 CFR 

Parts 171 to 180, for harmonization with 

international standards. Since 

publication of the 1990 final rule we 

have issued five additional international 

harmonization final rules (Dockets HM–

215A, 59 FR 67390; HM–215B, 62 FR 

24690; HM–215C, 64 FR 10742; HM–

215D, 66 FR 33316; and HM–215E, 68 

FR 44992). The rules provided 

additional harmonization with 

international transportation 

requirements by more fully aligning the 

HMR with the corresponding biennial 

updates of the UN Recommendations, 

the IMDG Code and the ICAO Technical 

Instructions. 

The UN Recommendations are not 

regulations, but rather are 

recommendations issued by the UN 

Committee of Experts on the Transport 

of Dangerous Goods (TDG) and on the 

Globally Harmonized System of 

Classification and Labeling (GHS). 

These recommendations are amended 

and updated biennially by the UN 

Committee of Experts. They serve as the 

basis for National, regional, and 

international modal regulations; 

specifically, the IMDG Code issued by 

the International Maritime Organization 

(IMO), and the ICAO Technical 

Instructions issued by the ICAO. In 49 

CFR 171.12, the HMR authorize 

domestic transportation of hazardous 

materials shipments prepared in 

accordance with the IMDG Code if all or 

part of the transportation is by vessel, 

subject to certain conditions and 

limitations. In § 171.11, subject to 

certain conditions and limitations, the 

HMR authorize the offering, acceptance 

and transport of hazardous materials by 

aircraft, and by motor vehicle either 

before or after being transported by 

aircraft, provided the shipment is in 

accordance with the ICAO Technical 

Instructions. 

The continually increasing amount of 

hazardous materials transported in 

international commerce warrants the 

harmonization of domestic and 

international requirements to the 

greatest extent possible. Harmonization 

serves to facilitate international 

transportation and at the same time 

ensures the safety of people, property 

and the environment. While the intent 

of the harmonization rulemakings is to 

align the HMR with international 

standards, we review and consider each 

amendment on its own merit. Each 

amendment is considered on the basis 

of the overall impact on transportation 

safety and the economic implications 

associated with its adoption into the 

HMR. Our goal is to harmonize without 

diminishing the level of safety currently 

provided by the HMR and without 

imposing undue burdens on the 

regulated public. In our efforts to 

continue to align the HMR with 

international requirements, this final 

rule incorporates changes into the HMR 

based on the Thirteenth Revised Edition 

of the UN Recommendations, 

Amendment 32 to the IMDG Code, and 

the 2005–2006 ICAO Technical 

Instructions, which become effective 

January 1, 2005. Petitions for 

rulemaking concerning harmonization 

with international standards and 

additional measures concerning 

facilitation of international 

transportation are also addressed in this 

final rule and serve as the basis of 

certain amendments. Other amendments 

are based on feedback from the 

regulated industry, other DOT modal 

administrations and our initiative. Also 

included are various editorial 

clarifications. Unless otherwise stated, 

the revisions are for harmonization with 

international standards. 

II. Overview of Changes in This Final 

Rule 

Amendments to the HMR in this final 

rule include, but are not limited to the 

following:

—Amendments to the Hazardous 

Materials Table (HMT) which add, 

revise or remove certain proper 

shipping names, hazard classes, 

packing groups, special provisions, 

packaging authorizations, bulk 

packaging requirements, passenger 

and cargo aircraft maximum quantity 

limitations and vessel stowage 

provisions. 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76045

—Amendments to the List of Marine 

Pollutants. 

—Revisions and additions of special 

provisions. 

—Removal of the air eligibility marking 

requirement. 

—Addition of a ‘‘KEEP AWAY FROM 

HEAT’’ marking requirement for 

packages offered for transportation by 

air. 

—Amendment to require that aerosols 

that are carried aboard an aircraft in 

accordance with § 175.10(a)(4) have 

their release devices protected by a 

cap or other suitable means. 

—A grandfather provision to allow the 

shipment of materials classified as 

corrosive to steel or aluminum under 

ASTM G 31–72. 

— A provision to require that the word 

‘‘overpack’’ be marked on overpacks 

to indicate that inside packages 

comply with prescribed 

specifications.

—An amendment to the criteria for 

classification of materials that are 

corrosive to metals. 

—Revision of the limited quantity 

provisions for Class 6.1, PG II 

materials and for materials with a 

subsidiary hazard of 6.1, PG II. 

—Amendments to the packaging 

requirements for materials classified 

as Division 6.1, Packing Group I, 

Hazard Zone A or Hazard Zone B. 

—Revision of the organic peroxide 

packaging requirements in order to 

have one consolidated packaging 

section for organic peroxides. The 

revised section will include three 

separate tables for organic peroxides 

authorized for transport in non-bulk 

packagings, IBCs, and bulk packagings 

other than IBCs, respectively. 

Additionally, the packaging tables 

will be updated through the 

amendments to the organic peroxide 

requirements that will add, revise, or 

delete certain entries in the organic 

peroxide tables. 

III. Overview of Amendments Not Being 

Considered for Adoption in This Final 

Rule 

This final rule makes changes to the 

HMR based on amendments to the 

Thirteenth Revised Edition of the UN 

Recommendations, Amendment 32 to 

the IMDG Code, and the 2005–2006 

ICAO Technical Instructions, which 

become effective January 1, 2005. 

However, we are not adopting all of the 

amendments to those documents into 

the HMR. In many cases, amendments 

to the international regulation have not 

been adopted because of the framework 

or structure of the HMR. In several 

cases, we are handling certain 

amendments in separate rulemakings. 

For example, all amendments related to 

infectious substances are being handled 

under Docket HM–226A. In some 

instances, such as the amendment to 

ICAO Technical Instructions to allow 

certain oxygen generators aboard 

passenger carrying aircraft, we do not 

believe the amendment to be in the 

interest of public safety. 

One of the goals of this rulemaking is 

to continue to maintain consistency 

between the HMR and the international 

requirements. We are not striving to 

make the HMR identical to the 

international regulations but rather 

striving to remove or avoid potential 

barriers to international transportation. 

Below is a listing of those significant 

amendments to the international 

regulations that we have not included in 

this final rule with a brief explanation 

of why the amendment was not 

included: 

• Requirements for infectious 

substances and genetically modified 

micro-organisms; 

[Amendments to the HMR related to 

infectious substances will be addressed 

in a future rulemaking under Docket 

HM–226A. Several other federal 

agencies regulate genetically modified 

micro-organisms; thus we do not plan to 

adopt provisions for their transport in 

the HMR.] 

• Compressed gas cylinders; 

[Amendments to the HMR related to 

compressed gas cylinders will be 

addressed in a future rulemaking under 

Docket HM–220E.] 

• Environmentally hazardous 

substances; 

[Delay in action pending further 

amendments to the international 

regulations.] 

• Hazardous materials security;

[Amendments to the HMR related to 

the UN Model Regulation’s hazardous 

materials security requirements were 

promulgated in a rulemaking under the 

HM–232 Docket series.] 

• Requirements for radioactive 

materials; 

[Amendments to the HMR related to 

Class 7 (radioactive) materials are being 

addressed in a rulemaking under the 

HM–230 Docket series.] 

• Non-specification bulk packagings; 

[We are not adopting the new 

requirements in the UN 

Recommendations for non-specification 

bulk packagings including the 

additional inspection, testing and 

marking requirements. We are unsure 

about the cost impacts of imposing these 

additional amendments and, therefore, 

are not adopting any additional 

amendments at this time.] 

• The reference to EN 10028–3, Part 

3 for defining steel grain size relevant to 

the definition of fine grain steel; 

[We do not believe there is a need to 

adopt the European standard EN 10028–

3, Part 3 because this standard is 

equivalent to ASTM E 112–96 (IBR, see 

§ 171.7 of this subchapter). In addition, 

the ASTM standard is currently 

referenced in the HMR and is more 

commonly used and recognized in the 

U.S.] 

• Bulk authorization for UN0331, 

UN0332 and UN3375; 

[For several years, we have 

authorized, under exemption, the 

transport of certain blasting agents in 

bulk packagings. We are currently 

reviewing those exemptions to 

determine if they should be included in 

the HMR. The amendments in the UN 

Recommendations related to the bulk 

authorizations for UN0331, UN0332 and 

UN3375 will be included in that 

review.] 

• The removal of wooden barrel 

requirements; 

[The removal of the wooden barrel 

requirements (2C1 and 2C2) may be 

considered in a future rulemaking.] 

• The 24-hour gasket relaxation 

requirement; 

[A requirement that removable head 

packagings for liquids not be drop tested 

until at least 24 hours after filling and 

closing to allow for any possible gasket 

relaxation was adopted in the thirteenth 

revised edition of the UN Model 

Regulations. We have conducted testing 

in coordination with drum 

manufacturers and have determined that 

this requirement is not substantiated by 

the results of the tests conducted. 

Therefore, we are not adopting into the 

HMR amendments relative to the 24-

hour gasket relaxation requirement. We 

also opposed this requirement when it 

was considered by the UN TDG SubCommittee.] 

• Authorization to transport 

protective breathing equipment (PBE’s) 

with an oxygen generator as cargo 

onboard a passenger-carrying aircraft. 

[We do not believe that oxygen 

generators should be transported aboard 

passenger carrying aircraft. Therefore, 

we are not adopting the ICAO 

amendment that would allow oxygen 

generators in protective breathing 

equipment to be transported in 

passenger carrying aircraft.]

IV. Section-By-Section Review 

Part 171 

Section 171.7 

Paragraph (a)(3) (incorporation by 

reference materials) is updated to 

include the most recent editions of the 

76046 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

ICAO Technical Instructions, the IMDG 

Code and the UN Recommendations. 

The updated editions of these standards 

become effective January 1, 2005. 

Additionally, the International Maritime 

Organization (IMO) recommends 

authorizing a one-year transition period, 

with a delayed compliance date of 

January 1, 2006, for the use of the 

updated edition (Amendment 32) of the 

IMDG Code. 

The updated additions are as follows:

—The ICAO Technical Instructions, 

2005–2006 Edition. 

—The IMDG Code, Amendment 32. 

—The UN Recommendations, 

Thirteenth Edition. 

—The UN Manual of Tests and Criteria, 

4th Revised Edition.

Paragraph (b) (list of informational 

materials not requiring incorporation by 

reference) is revised by adding an 

additional reference for a new method 

for determining the size of an 

emergency-relief device for portable 

tanks transporting organic peroxides. 

This revision is based on a petition for 

rulemaking numbered P–1428. The 

petition was submitted by the Organic 

Peroxides Producers Safety Division of 

the Society of the Plastics Industry, Inc. 

One commenter recommended that 

we revise the ‘‘Note to Paragraph 

(h)(3)(vi)’’ in § 173.225 to maintain 

format consistency with the 

incorporation by reference entry for 

‘‘Example of a Test Method for Venting 

Sizing: OPPSD/SPI Methodology’’ found 

in § 171.7(a). We disagree. The reference 

to a second example of a test method for 

venting sizing is not found in § 171.7(a) 

as a material incorporated by reference. 

Rather, it is found in § 171.7(b) as 

informational material not requiring 

incorporation by reference. Therefore, 

for clarification we are revising 

§ 171.7(b) to include the reference to the 

‘‘American Institute of Chemical 

Engineers Process Safety Progress 

Journal.’’ In addition, we are revising 

the ‘‘Note to Paragraph (h)(3)(vi)’’ in 

§ 173.225 to include a reference to 

§ 171.7(b), list of informational 

materials not requiring incorporation by 

reference. 

Section 171.8 

The definition for ‘‘salvage 

packaging’’ is revised to include the 

term ‘‘non-conforming.’’ The term ‘‘nonconforming’’ was added to the 

definition by the UN Committee of 

Experts in December 2000 to 

accommodate the use of salvage 

packaging for. Occasionally an 

undamaged package is found to be 

tested to a performance level which is 

less than that required for the specific 

substance it contains (e.g., a drum tested 

to PG II standards containing a PG I 

substance). In other instances, the 

package is found to be a nonperformance tested packaging 

containing a regulated substance. In 

these situations, it may not be safe or 

practical to transfer the material to the 

correct packaging to continue on to the 

consignee in order to ensure compliance 

with the HMR. Therefore, the use of 

salvage packaging to contain ‘‘nonconforming’’ packages will minimize 

the risk to those handling the package 

during its transport back to the shipper 

or to an appropriate disposal location.

Section 171.11 

Paragraph (d)(15) is revised to clarify 

that the limitations therein also apply to 

oxygen generators contained in personal 

breathing equipment. In addition, 

paragraph (d)(17) is revised to indicate 

that an organic peroxide that is not 

identified by a technical name in any of 

the organic peroxide tables found in 

§ 173.225 must be approved by the 

Associate Administrator in accordance 

with the requirements of § 173.128(d). 

Section 171.12 

In § 171.12, paragraph (b)(20) is 

revised to indicate that an organic 

peroxide that is not identified by a 

technical name in any of the organic 

peroxide tables found in § 173.225 must 

be approved by the Associate 

Administrator in accordance with the 

requirements of § 173.128(d). 

Section 171.12a 

Paragraph (a) is revised to clarify the 

requirements for the return to Canada of 

bulk packagings that correspond to DOT 

or UN Specifications. Paragraph 

(b)(9)(ii) is revised to indicate that the 

shipping certification must be 

completed for shipments from Canada 

that enter the U.S. Paragraph (b)(18) is 

revised to indicate that an organic 

peroxide that is not identified by a 

technical name in any of the organic 

peroxide tables found in § 173.22 must 

be approved by the Associate 

Administrator in accordance with the 

requirements of § 173.128(d). 

Section 171.14 

Paragraphs (d) and (d)(1) are revised 

to authorize a delayed implementation 

date for the amendments in this final 

rule. The effective date of this final rule 

is January 1, 2005. We are also, 

authorizing a delayed compliance date 

of January 1, 2006, which is comparable 

to the transitional provisions provided 

in the final rule published under Docket 

HM–215E. The delayed mandatory 

compliance date offers sufficient time to 

implement the new requirements. 

Paragraph (d)(2) is revised to 

authorize certain intermixing of old and 

new requirements. 

Part 172 

Section 172.101 

The regulatory text preceding the 

Hazardous Materials Table is revised as 

follows: 

Paragraph (c)(11) and the 

corresponding note to paragraph (c)(11) 

are amended to revise a section 

reference. The reference to § 173.225(c) 

in the first sentence is revised to read 

§ 173.225(b) and the reference to 

§ 173.225(c)(2) in the note to paragraph 

(c)(11) is revised to read § 173.225(b)(2). 

Paragraph (d)(4) is revised by adding 

a statement indicating that when the 

abbreviation ‘‘Comb liq.’’ is found in the 

‘‘Hazard class or division’’ column of 

the Hazardous Materials Table (column 

3), the material falls into the 

‘‘Combustible liquid’’ hazard class. 

Paragraph (i)(3) of this section is 

revised to specify that Column 7 of the 

Hazardous Materials Table contains 

additional bulk packaging 

authorizations and limitations for the 

use of UN portable tanks.

§ 172.101 The Hazardous Materials 

Table (HMT). In this final rule we made 

various amendments to the HMT. 

Readers should review all changes for a 

complete understanding of the Table 

amendments. The HMT has been 

reprinted in its entirety due to the 

numerous changes. Under this final rule 

the changes to the HMT for the purpose 

of harmonizing with international 

standards, unless otherwise stated, 

include, but are not limited to the 

following: 

• We revised several entries by 

adding the qualifying word ‘‘liquid.’’

This action is consistent with the 

revisions to proper shipping names that 

were incorporated into the Thirteenth 

Revised Edition of the UN 

Recommendations. Affected entries are 

as follows:

UN1392 Alkaline earth metal amalgam 

UN1420 Potassium metal alloys 

UN1422 Potassium sodium alloys 

UN1701 Xylyl bromide 

UN1742 Boron trifluoride acetic acid 

complex 

UN1743 Boron trifluoride propionic 

acid complex 

UN2235 Chlorobenzyl chlorides 

UN2236 3-Chloro-4-methylphenyl 

isocyanate 

UN2306 Nitrobenzotrifluorides 

UN2445 Lithium alkyls 

UN2552 Hexafluoroacetone hydrate 

UN2937 alpha-Methylbenzyl alcohol 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76047

UN3276 Nitriles, toxic, n.o.s. 

UN3278 Organophosphorus 

compound, toxic, n.o.s. 

UN3280 Organoarsenic compound, 

n.o.s. 

UN3282 Organometallic compound, 

toxic, n.o.s. 

UN3281 Metal carbonyls, n.o.s.

• We revised several entries by 

adding the qualifying word ‘‘solid.’’

This action is consistent with the 

revisions to proper shipping names that 

were incorporated into the Thirteenth 

Revised Edition of the UN 

Recommendations. Affected entries are 

as follows:

UN1445 Barium chlorate 

UN1447 Barium perchlorate 

UN1459 Chlorate and magnesium 

chloride mixture 

UN1470 Lead perchlorate 

UN1578 Chloronitrobenzenes 

UN1579 4-Chloro-o-toluidine 

hydrochloride 

UN1650 beta-Naphthylamine 

UN1680 Potassium cyanide

UN1689 Sodium cyanide 

UN1690 Sodium fluoride 

UN1697 Chloroacetophenone 

UN1709 2,4-Toluylenediamine 

UN1812 Potassium fluoride 

UN1843 Ammonium dinitro-ocresolate 

UN2074 Acrylamide 

UN2239 Chlorotoluidines 

UN2261 Xylenols 

UN2446 Nitrocresols 

UN2662 Hydroquinone 

UN3283 Selenium compound, n.o.s.

• We revised several entries by 

removing the qualifying word ‘‘solid.’’

This action provides consistency with 

the Thirteenth Revised Edition of the 

UN Recommendations. The affected 

entries are as follows:

UN1489 Potassium perchlorate, solid 

UN1598 Dinitro-o-cresol, solid

UN1638 Mercury iodide, solid

UN1740 Hydrogendifluorides, n.o.s. 

solid

UN2439 Sodium hydrogendifluoride, 

solid

• We deleted several entries. This 

action removes from the HMR the 

solution form of entries that are not 

identified as solutions in the Thirteenth 

Revised Edition of the UN 

Recommendations. The deleted entries 

are as follows:

UN1489 Potassium perchlorate, 

solution 

UN1598 Dinitro-o-cresol, solution

UN1638 Mercury iodide, solution

UN1740 Hydrogendifluorides, n.o.s. 

solutions

UN2439 Sodium hydrogendifluoride 

solution

• We revised the proper shipping 

name ‘‘Butadienes, stabilized,’’ UN1010 

to read ‘‘Butadienes, stabilized or

Butadienes and hydrocarbon mixture, 

stabilized, containing more than 40% 

butadienes.’’

• We revised the proper shipping 

name ‘‘Potassium hydrogendifluoride, 

solid,’’ UN1811 to read ‘‘Potassium 

hydrogendifluoride, solid.’’

• We revised the proper shipping 

name ‘‘Refrigerating machines, 

containing non-flammable, non-toxic, 

liquefied gas or ammonia solution 

(UN2672),’’ UN2857 to read 

‘‘Refrigerating machines containing nonflammable, non-toxic gases or ammonia 

solutions (UN2672).’’

• We removed four references to IB52 

and four references to T23 from column 

7 of the HMT. This change is necessary 

because IB52 and T23 have been 

relocated to § 173.225. The affected 

entries are:

UN3109 Organic peroxide type F, 

liquid 

UN3110 Organic peroxide type F, 

solid 

UN3119 Organic peroxide type F, 

liquid, temperature controlled 

UN3120 Organic peroxide type F, 

solid, temperature controlled

• IP5 is removed from column 7 of 

the HMT for the following UN entries:

UN1791 Hypochlorite solution 

UN2014 Hydrogen peroxide, aqueous 

solution with not less than 20% but 

not more than 60% hydrogen 

peroxide (stabilized as necessary). 

UN3149 Hydrogen peroxide and 

peroxyacetic acid mixture with 

acid(s), water and not more than 5% 

peroxyacetic acid.

• We deleted several entries. This 

action is consistent with the deletion of 

proper shipping names that were 

incorporated into the Thirteenth 

Revised Edition of the UN 

Recommendations that we are 

proposing to adopt into the HMR. The 

entries affected are:

UN2003 Metal alkyls, water-reactive, 

n.o.s. or Metal aryls, water-reactive, 

n.o.s. 

UN3049 Metal alkyl halides, waterreactive, n.o.s. or Metal aryl halides, 

water-reactive, n.o.s. 

UN3050 Metal alkyl hydrides, waterreactive, n.o.s. or Metal aryl hydrides, 

water-reactive, n.o.s. 

UN3207 Organometallic compound or

Compound solution or Compound 

dispersion, water-reactive, flammable, 

n.o.s. 

UN3203 Pyrophoric organometallic 

compound, water-reactive, n.o.s., 

liquid Pyrophoric organometallic 

compound, water-reactive, n.o.s., 

solid 

UN3372 Organometallic compound, 

solid, water-reactive, flammable, 

n.o.s.

• We added the following new 

entries. Many of these entries are the 

liquid or solid form of entries that are 

already listed in the HMT. This action 

is consistent with the addition of proper 

shipping names that were incorporated 

into the Thirteenth Revised Edition of 

the UN Recommendations. The new 

entries are as follows:

UN3377 Sodium perborate 

monohydrate 

UN3378 Sodium carbonate 

peroxyhydrate 

UN3379 Desensitized explosives, 

liquid, n.o.s. 

UN3380 Desensitized explosives, 

solid, n.o.s. 

UN3401 Alkali metal amalgam, solid

UN3402 Alkaline earth metal 

amalgam, solid 

UN3403 Potassium metal alloys, solid 

UN3404 Potassium sodium alloys, 

solid 

UN3405 Barium chlorate solution 

UN3406 Barium perchlorate solution 

UN3407 Chlorate and magnesium 

chloride mixture solution 

UN3408 Lead perchlorate solution 

UN3409 Chloronitrobenzenes, liquid 

UN3410 4-Chloro-o-toluidine 

hydrochloride solution 

UN3411 beta-Naphthylamine solution 

UN3413 Potassium cyanide solution 

UN3414 Sodium cyanide solution 

UN3415 Sodium fluoride solution 

UN3416 Chloroacetophenone, liquid 

UN3417 Xylyl bromide, solid 

UN3418 2,4-Toluylenediamine 

solution 

UN3419 Boron trifluoride acetic acid 

complex, solid 

UN3420 Boron trifluoride propionic, 

acid complex, solid 

UN3421 Potassium 

hydrogendifluoride solution 

UN3422 Potassium fluoride solution 

UN3423 Tetramethylammonium 

hydroxide, solid 

UN3424 Ammonium dinitro-ocresolate solution 

UN3425 Bromoacetic acid, solid 

UN3426 Acrylamide solution 

UN3427 Chlorobenzyl chlorides, solid 

UN3428 3-Chloro-4-Methylphenyl 

isocyanate, solid 

UN3429 Chloro-toluidines, liquid 

UN3430 Xylenols, liquids 

UN3431 Nitrobenzotrifluorides, solid 

UN3432 Polychlorinated biphenyls, 

solid 

UN3433 Lithium alkyls, solid 

UN3434 Nitrocresols, liquid 

UN3435 Hydroquinone solution 

UN3436 Hexafluoroacetone hydrate, 

solid

76048 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

UN3437 Chlorocresols, solid 

UN3438 alpha-Methylbenzyl alcohol, 

solid 

UN3439 Nitriles, toxic, solid, n.o.s. 

UN3440 Selenium compound, liquid, 

n.o.s. 

UN3441 Chlorodinitrobenzenes, solid 

UN3442 Dichloroanilines, solid 

UN3443 Dinitrobenzenes, solid 

UN3444 Nicotine hydrochloride, solid 

UN3445 Nicotine sulphate, solid 

UN3446 Nitrotoluenes, solid

UN3447 Nitroxylenes, solid 

UN3448 Tear gas substance, solid, 

n.o.s. 

UN3449 Bromobenzyl cyanides, solid 

UN3450 Diphenylchloroarsine, solid 

UN3451 Toluidines, solid 

UN3452 Xylidines, solid 

UN3453 Phosphoric acid, solid 

UN3454 Dinitrotoluenes, solid 

UN3455 Cresols, solid 

UN3456 Nitrosyl-sulphuric acid, solid 

UN3457 Chloronitrotoluenes, solid 

UN3458 Nitroanisoles, solid 

UN3459 Nitrobromobenzenes, solid 

UN3460 N-Ethylbenzyltoluidines, 

solid 

UN3461 Aluminium alkyl halides, 

solid 

UN3462 Toxins, extracted from living 

sources, solid, n.o.s. 

UN3464 Organophosphorus 

compound, toxic, solid, n.o.s. 

UN3465 Organoarsenic compound, 

solid, n.o.s. 

UN3466 Metal carbonyls, solid, n.o.s. 

UN3467 Organometallic compound, 

toxic, solid, n.o.s. 

UN3468 Hydrogen in a metal hydride 

storage system

A commenter stated that by adding 

the shipping names for desensitized 

explosives under identification numbers 

UN3379 and UN3380, approvals should 

be modified to authorize the use of 

classifications for the applicable 

hazardous materials. The commenter 

also noted that due to these additions, 

the definitions for flammable solids and 

flammable liquids require revision to 

account for the new shipping names. 

We do not anticipate a significant 

number of explosives being assigned to 

these shipping names. Therefore, we 

disagree with the commenter’s 

contention that each holder of an EX 

number request an updated shipping 

classification. In addition, we do not 

agree with the commenter’s request to 

revise the definitions of flammable solid 

and flammable liquid to include the 

additional proper shipping names. The 

definitions of flammable solid and 

flammable liquid adequately describe 

materials assigned to those shipping 

names. Additionally, shipping names 

are not found under hazard class 

definitions, but rather, in the HMT. 

• We added the following new 

generic entries for materials that are 

toxic by inhalation. These new names 

will replace the existing generic entries 

in the HMT. This action is consistent 

with the addition of proper shipping 

names that were incorporated into the 

Thirteenth Revised Edition of the UN 

Recommendations. Affected entries are 

as follows:

UN3381 Toxic by inhalation liquid, 

n.o.s. with an inhalation toxicity 

lower than or equal to 200 ml/m3 and 

saturated vapor concentration greater 

than or equal to 500 LC50. 

UN3382 Toxic by inhalation liquid, 

n.o.s. with an inhalation toxicity 

lower than or equal to 1000 ml/m3

and saturated vapor concentration 

greater than or equal to 10 LC50. 

UN3383 Toxic by inhalation liquid, 

flammable, n.o.s. with an inhalation 

toxicity lower than or equal to 200 ml/

m3 and saturated vapor concentration 

greater than or equal to 500 LC50. 

UN3384 Toxic by inhalation liquid, 

flammable, n.o.s. with an inhalation 

toxicity lower than or equal to 1000 

ml/m3 and saturated vapor 

concentration greater than or equal to 

10 LC50. 

UN3385 Toxic by inhalation liquid, 

water-reactive, n.o.s. with an 

inhalation toxicity lower than or 

equal to 200 ml/m3 and saturated 

vapor concentration greater than or 

equal to 500 LC50. 

UN3386 Toxic by inhalation liquid, 

water-reactive, n.o.s. with an 

inhalation toxicity lower than or 

equal to 1000 ml/m3 and saturated 

vapor concentration greater than or 

equal to 10 LC50. 

UN3387 Toxic by inhalation liquid, 

oxidizing, n.o.s. with an inhalation 

toxicity lower than or equal to 200 ml/

m3 and saturated vapor concentration 

greater than or equal to 500 LC50. 

UN3388 Toxic by inhalation liquid, 

oxidizing, n.o.s. with an inhalation 

toxicity lower than or equal to 1000 

ml/m3 and saturated vapor 

concentration greater than or equal to 

10 LC50. 

UN3389 Toxic by inhalation liquid, 

corrosive, n.o.s. with an inhalation 

toxicity lower than or equal to 200 ml/

m3 and saturated vapor concentration 

greater than or equal to 500 LC50.

UN3390 Toxic by inhalation liquid, 

corrosive, n.o.s. with an inhalation 

toxicity lower than or equal to 1000 

ml/m3 and saturated vapor 

concentration greater than or equal to 

10 LC50.

• We added the following new 

generic entries for organometallic 

substances. This action is consistent 

with the addition of proper shipping 

names that were incorporated into the 

Thirteenth Revised Edition of the UN 

Recommendations. The new entries are 

as follows:

UN3391 Organometallic substance, 

solid, pyrophoric 

UN3392 Organometallic substance, 

liquid, pyrophoric 

UN3393 Organometallic substance, 

solid, pyrophoric, water-reactive 

UN3394 Organometallic substance, 

liquid, pyrophoric, water-reactive 

UN3395 Organometallic substance, 

solid, water-reactive 

UN3396 Organometallic substance, 

solid, water-reactive, flammable 

UN3397 Organometallic substance, 

solid, water-reactive, self-heating 

UN3398 Organometallic substance, 

liquid, water-reactive 

UN3399 Organometallic substance, 

liquid, water-reactive, flammable 

UN3400 Organometallic substance, 

solid, self-heating

In addition, we are continuing to 

allow the use of the following specific 

Organometallic entries: UN1366, 

UN1370, UN2005, UN2445, UN3051, 

UN3052, UN3053, and UN3076. 

However, we anticipate removing these 

entries from the HMT by January 1, 

2007. 

• The U.N. Recommendations have 

adopted a rationalized approach for the 

assignment of UN portable tank 

instructions for solid materials. Based 

on that rationalized approach, we made 

several changes to UN portable tank 

authorizations in the HMR. These 

changes are summarized as follows. For 

a more specific identification of the 

affected shipping descriptions, refer to 

the UN report located in the public 

Docket. 

For Division 4.1, Packing Group I 

materials, the use of UN portable tanks 

is not authorized. 

For Division 4.3 materials with a 

subsidiary class of 6.1, in Packing Group 

I, the use of portable tanks is not 

authorized. 

For materials of Divisions 4.1, 4.2, 4.3, 

5.1, 6.1, and Classes 8 and 9, in Packing 

Group II, Special Provisions T3 is 

specified. 

For Division 4.2, Packing Group I 

materials, T21 and TP7 is specified. 

For Division 4.3, Packing Group I 

materials, T9 and TP7 is specified. 

For Division 5.1, Packing Group I 

materials, the use of UN portable tanks 

is not authorized. 

For Division 6.1 and Class 8, Packing 

Group I materials, T6 is specified. 

For materials of Divisions 4.1, 4.2, 4.3, 

5.1, 6.1, and Classes 8 and 9, in Packing 

Group III, Special Provisions T1 is 

specified.

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76049

• Several entries in the HMT have 

been revised by amending column 9B to 

read ‘‘forbidden’’ so that the materials 

are no longer authorized for transport 

aboard cargo aircraft. The entries have 

been revised because they meet the 

criteria of either Zone C or Zone D 

inhalation toxicity. All other Zone C 

and Zone D toxic by inhalation 

materials listed in the HMR are 

currently already forbidden from 

transport aboard passenger and cargo 

aircraft (these materials are already 

forbidden from transport aboard 

passenger aircraft). The entries to be 

revised include: 

Zone C 

UN2204 Carbonyl sulfide 

UN1023 Coal gas, compressed 

UN1064 Methyl mercaptan 

UN1048 Hydrogen bromide, 

anhydrous 

UN1079 Sulfur dioxide 

Zone D 

UN1005 Ammonia, anhydrous 

UN3318 Ammonia solution, relative 

density less than 0.880 at 15 degrees 

C in water, with more than 50 percent 

ammonia

UN1040 Ethylene oxide or Ethylene 

oxide with nitrogen up to a total 

pressure of 1MPa (10 bar) at 50 

degrees C

UN1040 Ethylene oxide or Ethylene 

oxide with nitrogen up to a total 

pressure of 1MPa (10 bar) at 50 

degrees C

UN2191 Sulfuryl fluoride

Also, see § 172.102 for additional 

HMT amendments. 

Appendix B to § 172.101 

In Appendix B to § 172.101, List of 

Marine Pollutants, we removed the 

entries ‘‘Diphenyl oxide and biphenyl 

phenyl ether mixtures,’’ ‘‘Isoamyl 

mercaptan,’’ ‘‘Pentanethiols,’’ and 

‘‘Tetrachlorophenol.’’ We revised the 

entry ‘‘2, 6-Di-tert-Butylphenol’’ and we 

added the entry ‘‘Chloropicrin.’’

Section 172.102 

We amended § 172.102, Special 

Provisions, as follows: 

• Several entries in the HMT are 

revised by adding special provisions A3, 

A6, A7, A9, A10, N3, and N36 to align 

this section with the equivalent special 

provisions in the ICAO Technical 

Instructions (13, 2, 5, 4, 7, 21, and 3 

respectively). We removed the ‘‘A’’

special provisions for several entries 

because we have determined that the 

materials to which the provisions apply 

are currently not authorized for 

transportation on either passenger or 

cargo aircraft. 

The following entries are revised by 

adding special provision A3:

UN1154 Diethylamine 

UN1788 Hydrobromic acid, not more 

than 49% strength

UN1789 Hydrochloric acid 

UN2031 Nitric acid, other than red 

fuming, with more than 70% nitric 

acid

UN2604 Boron trifluoride diethyl 

etherate

• The following entries are revised by 

adding A6:

UN1111 Amyl mercaptan 

UN1228 Mercaptans, liquid, 

flammable, toxic, n.o.s. 

UN1760 Corrosive liquid, n.o.s. 

UN1903 Disinfectants, liquid, 

corrosive, n.o.s. 

UN2031 Nitric acid, other than red 

fuming, with not more than 70% 

nitric acid

UN2054 Morpholine 

UN2347 Butyl mercaptan 

UN2363 Ethyl mercaptan 

UN2402 Propanethiols

UN2801 Dye, liquid, corrosive, n.o.s. 

UN2920 Corrosive liquid, flammable, 

n.o.s. 

UN2922 Corrosive liquid, toxic, n.o.s. 

UN3071 Mercaptans, liquid, toxic, 

flammable, n.o.s. 

UN3093 Corrosive liquid, oxidizing, 

n.o.s. 

UN3093 Corrosive liquid, oxidizing, 

n.o.s. 

UN3094 Corrosive liquid, waterreactive, n.o.s. 

UN3094 Corrosive liquid, waterreactive, n.o.s. 

UN3098 Oxidizing liquid, corrosive, 

n.o.s. 

UN3099 Oxidizing liquid, toxic, n.o.s. 

UN3139 Oxidizing liquid, n.o.s. 

UN3145 Alkylphenols, liquid, n.o.s. 

(including C2-C12 homologues) 

UN3264 Corrosive liquid, acidic, 

inorganic, n.o.s. 

UN3265 Corrosive liquid, acidic, 

organic, n.o.s. 

UN3266 Corrosive liquid, basic, 

inorganic, n.o.s. 

UN3267 Corrosive liquid, basic, 

organic, n.o.s. 

UN3301 Corrosive liquid, self-heating, 

n.o.s.

• The following entries are revised by 

adding special provision A7:

UN1167 Divinyl ether, stabilized 

UN1277 Propylamine 

UN1389 Alkali metal amalgam, liquid 

UN1389 Alkali metal amalgam, solid 

UN1391 Alkali metal dispersion or

Alkaline earth metal dispersion 

UN1407 Cesium or Caesium 

UN1420 Potassium metal alloys 

UN1421 Alkali metal alloy, liquid, 

n.o.s. 

UN1422 Potassium sodium alloys 

UN1431 Sodium methylate 

UN1796 Nitrating acid mixture with 

not more than 50% nitric acid

UN1796 Nitrating acid mixture with 

more than 50% nitric acid

UN1826 Nitrating acid mixture, spent 

with not more than 50% nitric acid

UN1826 Nitrating acid mixture, spent 

with more than 50% nitric acid

UN1828 Sulphur chlorides 

UN1938 Bromoacetic acid 

UN2257 Potassium 

UN2749 Tetramethylsilane 

UN3093 Corrosive liquid, oxidizing, 

n.o.s. 

UN3093 Corrosive liquid, oxidizing, 

n.o.s. 

UN3094 Corrosive liquid, waterreactive, n.o.s. 

UN3094 Corrosive liquid, waterreactive, n.o.s. 

UN3205 Alkaline earth metal 

alcoholates, n.o.s. 

UN3205 Alkaline earth metal 

alcoholates, n.o.s.

UN3206 Alkali metal alcoholates, selfheating, corrosive, n.o.s. 

UN3206 Alkali metal alcoholates, selfheating, corrosive, n.o.s. 

UN3208 Metallic substance, waterreactive, n.o.s. 

UN3208 Metallic substance, waterreactive, n.o.s. 

UN3208 Metallic substance, waterreactive, n.o.s. 

UN3209 Metallic substance, waterreactive, self-heating, n.o.s. 

UN3209 Metallic substance, waterreactive, self-heating, n.o.s. 

UN3209 Metallic substance, waterreactive, self-heating, n.o.s.

• The following entries are revised by 

adding special provision A9:

UN1449 Barium peroxide 

UN1452 Calcium chlorate 

UN3212 Hypochlorites, inorganic, 

n.o.s.

• The following entries are revised by 

adding special provision A10:

UN1828 Sulphur chlorides 

UN2401 Piperidine

• The following entry is revised by 

adding special provision N3:

UN2817 Ammonium 

hydrogendifluoride solution

• The following entries are revised by 

adding special provision N36:

UN1184 Ethylene dichloride 

UN1732 Antimony pentafluoride 

UN1777 Fluorosulphonic acid 

UN2699 Trifluoroacetic acid

• The following entries are revised by 

removing certain ‘‘A’’ special provisions 

since the materials themselves are 

forbidden for transportation aboard 

passenger and cargo aircraft:

76050 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

UN1541 Acetone cyanohydrin, 

stabilized (remove A3) 

UN1722 Allyl chloroformate (remove 

A3) 

UN2692 Boron tribromide (remove A3, 

A7) 

UN1744 Bromine or Bromine solutions 

(remove A3, A6) 

UN2484 tert-Butyl isocyanate (remove 

A7) 

UN2485 n-Butyl isocyanate (remove 

A7) 

UN1752 Chloroacetyl chloride 

(remove A3, A6, A7) 

UN1754 Chlorosulfonic acid (with or 

without sulfur trioxide) (remove A3, 

A6, A10)

UN2382 Dimethylhydrazine, 

symmetrical (remove A7) 

UN1182 Ethyl chloroformate (remove 

A3, A6, A7) 

UN2481 Ethyl isocyanate (remove A7) 

UN2014 Hydrogen peroxide, aqueous 

solutions with more than 40 percent 

but not more than 60 percent 

hydrogen peroxide (stabilized as 

necessary) (remove A3, A6) 

UN2015 Hydrogen peroxide, stabilized 

or Hydrogen peroxide aqueous 

solutions, stabilized with more than 

60 percent hydrogen peroxide

(remove A3, A6) 

NA9206 Methyl phosphonic 

dichloride (remove A3) 

UN2534 Methylchlorosilane (remove 

A2, A3, A7) 

UN2304 Naphthalene, molten (remove 

A1) 

UN1670 Perchloromethyl mercaptan 

(remove A3, A7) 

UN1810 Phosphorus oxychloride 

(remove A7) 

UN2740 n-Propyl chloroformate 

(remove A3, A6, A7) 

UN1829 Sulfur trioxide, stabilized 

(remove A7) 

UN1831 Sulfuric acid, fuming with 30 

percent or more free sulfur trioxide

(remove A3, A6, A7) 

UN1834 Sulfuryl chloride (remove A3) 

UN1836 Thionyl chloride (remove A7) 

UN2474 Thiophosgene (remove A7) 

UN1838 Titanium tetrachloride 

(remove A3, A6) 

UN2441 Titanium trichloride, 

pyrophoric or Titanium trichloride 

mixtures, pyrophoric (remove A7, A8, 

A19, A20) 

UN2442 Trichloroacetyl chloride 

(remove A3, A7) 

UN1295 Trichlorosilane (remove A7) 

UN2438 Trimethylacetyl chloride 

(remove A3, A6, A7)

• Paragraph (b)(3) of this section is 

amended to specify that a ‘‘B’’ code 

refers to a special provision that applies 

only to certain bulk packaging 

requirements and that, unless otherwise 

stated, does not apply to UN, IM 

Specification portable tanks or IBCs. 

• Paragraph (b)(4) of this section is 

amended to specify that a code 

containing the letters ‘‘IB’’ or ‘‘IP’’ refers 

to a special provision that applies only 

to transportation in IBCs. 

• Paragraph (b)(7) of this section is 

amended to specify that a code 

containing the letter ‘‘T’’ refers to a 

special provision which applies only to 

transportation in UN or IM Specification 

portable tanks. 

• Paragraph (b)(8) is redesignated 

(b)(9) and a new paragraph (b)(8) is 

added to specify that a code containing 

the letters ‘‘TP’’ refers to a special 

provision that is in addition to those 

provided by the portable tank 

instructions or the requirements in part 

178.

• Special Provision 47 is revised to 

include an additional exception 

currently in the UN Model Regulations 

specifying that a leakproofness test is 

not required when the liquids are fully 

absorbed in solid material contained in 

sealed bags. 

• Special Provision 135 is revised to 

expand the applicability of the proper 

shipping names ‘‘Vehicle, flammable 

liquid powered’’ and ‘‘Vehicle, 

flammable gas powered’’ to include 

hybrid electric vehicles. 

• Special Provision 137 is revised to 

expand the exception for ‘‘Cotton, dry’’. 

• Special Provision 143 is removed 

and relocated to § 173.219 so that the 

limitations on the types of hazardous 

materials authorized apply to both selfinflating and non-self-inflating lifesaving appliances. 

• Special Provision 153 is relocated 

to new paragraph (k) in § 173.115 and 

revised to include amended 

classification criteria for aerosols 

containing flammable constituents 

consistent with criteria in the UN Model 

Regulations. The revised criteria include 

methods for the classification of 

aerosols based on the percentage of 

flammable components. One commenter 

agreed with the removal of Special 

Provision 153 and the relocation of 

classification criteria for aerosols to 

§ 173.115(k). 

• New Special Provision 163 is added 

to specify that Ammonium Nitrate 

Emulsions are required to satisfactorily 

pass Test Series 8 of the UN Manual of 

Tests and Criteria, Part I, Section 18. 

• New Special Provision 164 is added 

to specify that an approval is required 

for ‘‘Desensitized explosives, liquid, 

n.o.s.’’ and ‘‘Desensitized explosives, 

solid, n.o.s.’’

• New Special Provision 165 is added 

to the calcium hypochlorite PG II and 

the PG III entries for UN1748 and 

UN2880 to specify the danger of 

exothermic decomposition and require 

shading from direct sunlight and 

sources of heat during transportation. 

One commenter agreed with our efforts 

to harmonize the HMR with UN 

Recommendations, but was concerned 

with the intent of Special Provision 165. 

This commenter agreed that calcium 

hypochlorite should be shaded from 

direct sunlight but questioned the 

ambient heat and ventilation provisions. 

The commenter stated that calcium 

hypochlorite is currently transported in 

closed cargo transport units, thus, 

satisfying the requirement to protect this 

hazardous material from direct sunlight. 

However, since the cargo transport units 

are not ventilated by fan or induced 

ventilation, and the cargo transport 

units would be subjected to ambient 

heat, a violation of Special Provision 

165 appears imminent. We disagree. We 

feel Special Provision 165 provides 

latitude for compliance with the 

ventilation and ambient heat 

requirements. Proper ventilation and 

protection from ambient heat can be 

achieved during the loading process of 

the cargo transport units and throughout 

the transportation cycle by allowing 

adequate space for air movement around 

the calcium hypochlorite packages. We 

do agree; however, that cargo transport 

units themselves should not be required 

to be shaded from direct sunlight. 

Therefore, we have revised the 

regulatory text accordingly. 

• New Special Provision 166 is added 

to the PG II entry for calcium 

hypochlorite, UN2880 and UN1748 to 

indicate that calcium hypochlorite in 

the non-friable tablet form may be 

transported as a PG III material. 

• New Special Provision 167 is added 

to the new entry for ‘‘Hydrogen in a 

metal hydride storage system’’ to specify 

that such storage systems shall always 

be considered as containing hydrogen. 

• New Special Provision 170 is added 

to Organometallic substances entries 

(UN3391, UN3392, UN3393, and 

UN3394). The special provision requires 

air to be eliminated from the vapor 

space by nitrogen or other means. 

• New Special Provision 171 is added 

to the UN2880 PG III entry. Since 

UN2880 also covers mixtures of 

hydrated calcium hypochlorite in any 

concentration, some formulations in 

other than tablet form (e.g., in granular 

form) may meet the criteria for 

classification in Division 5.1, Packing 

Group III when subjected to the relevant 

test in the UN Manual of Tests and 

Criteria. The PG III entry for calcium 

hypochlorite is only authorized when 

the material is offered in the non-friable 

tablet form or for granular or powdered 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76051

mixtures. This entry is not authorized 

for the pure form of ‘‘Calcium 

hypochlorite, hydrated’’. We also 

recognize that some formulations, when 

tested, do not meet the criteria for 

classification in Division 5.1. In light of 

this, we added a new Special Provision 

171 to the UN2880, PG III entry in the 

HMT to allow for the possibility to 

classify powdered or granular mixtures 

of hydrated calcium hypochlorite in 

Packing Group III when data indicate 

that the mixture meets the criteria for 

assignment to PG III. One commenter 

supports the revisions that align 

calcium hypochlorite entries in the 

HMT with UN Recommendations. 

However, this commenter requested the 

addition of Special Provision 171 to the 

entry, ‘‘Calcium hypochlorite, dry or 

Calcium hypochlorite mixtures dry, 

(UN1748)’’ for consistent alignment 

with the UN Recommendations. We 

agree. After further review of the UN 

Recommendations, we have determined 

that the UN Special Provision 316 is 

equivalent to the proposed Special 

Provision 171 in Docket HM–215G, and 

is applicable to both the ‘‘dry’’ and 

‘‘hydrated’’ calcium hypochlorite 

entries. Therefore, we are assigning 

Special Provision 171 to the ‘‘Calcium 

hypochlorite, dry or Calcium 

hypochlorite mixtures dry, (UN1748)’’

entry.

• Special Provision A11 is currently 

assigned to UN 2983, Ethylene oxide 

and Propylene oxide mixtures and UN 

1411, Lithium aluminum hydride, 

ethereal. In the ICAO Technical 

Instructions these substances are only 

authorized for transport in metal 

cylinders. A11 states ‘‘For combination 

packagings, when metal inner 

packagings are permitted, only 

specification cylinders constructed of 

metals which are compatible with the 

hazardous material may be used. In the 

NPRM, we proposed to harmonize with 

the applicable ICAO Technical 

Instruction particular packing 

requirement (PPR 8), however 

discussions with the ICAO Dangerous 

Goods Panel and further analysis of 

ICAO PPR 8 has revealed that the 

requirement may need to be amended. 

Our analysis showed that other 

packagings, including glass inner 

packagings, are authorized, and as such 

restricting packagings to only 

specification cylinders appears 

unnecessarily restrictive. As such we 

are not proposing to amend Special 

Provision A11 in this final rule. 

• Consistent with ICAO, we are 

adding a proper shipping name to the 

HMT for ‘‘Receptacles, small containing 

gas, 2.2 with a subsidiary of 5.1.’’ A new 

‘‘A’’ code (A14) is added to prohibit this 

material from being transported as a 

limited quantity or consumer 

commodity in accordance with 

§ 173.306 aboard an aircraft. This new 

‘‘A’’ code has also been added to the 

following additional shipping names: 

‘‘Oxygen, compressed,’’ Carbon dioxide 

and oxygen mixtures,’’ ‘‘Nitrous oxide’’, 

‘‘Compressed gas oxidizing,’’ and 

‘‘Liquefied gas, oxidizing.’’

• For consistency, the authorization 

in Special Provision B69 to allow dry 

sodium or potassium cyanide in 

siftproof, water-resistant fiberboard IBCs 

is relocated to new Special Provision 

IP20. 

• Paragraph (c)(4) of this section is 

amended by relocating ‘‘Table 2.—

Organic Peroxide IBC Code (IB52)’’ to 

paragraph (e) of § 173.225 and renaming 

it the ‘‘Organic Peroxide IBC Table.’’

Table 3.—IP Codes is redesignated Table 

2.—IP Codes. The wording of paragraph 

(c)(4) is revised to indicate that Table 

3.—IP Codes had been redesignated 

Table 2.—IP Codes. All references to 

IB52 in the HMR are removed and 

replaced with ‘‘Organic Peroxide IBC 

Table’’ or ‘‘§ 173.225(e),’’ as applicable. 

• Paragraph (c)(7) is amended by 

relocating the Portable Tank Code T50 

Table to § 173.313 and renaming it ‘‘UN 

Portable Tank Table for Liquefied 

Compressed Gases.’’ The T50 Table and 

its description is removed from 

paragraph (c)(7)(iv) and replaced with a 

statement indicating that the new ‘‘UN 

Portable Tank Table for Liquefied 

Compressed Gases’’ is found in 

§ 173.313. All references to T50 in the 

HMR are removed and replaced with 

‘‘UN Portable Tank Table for Liquefied 

Compressed Gases in § 173.313.’’ In 

addition, paragraph (c)(7) is amended by 

relocating Portable Tank Code T23 to 

paragraph (g) of § 173.225 and renaming 

it the ‘‘Organic Peroxide Portable Tank 

Table.’’ Portable Tank Code T23 and its 

description found in paragraph (c)(7)(iii) 

are removed and paragraphs (c)(7)(iv)–

(c)(7)(vii) are redesignated (c)(7)(iii)–

(c)(7)(vi), respectively. All references to 

T23 in the HMR are removed and 

replaced with ‘‘Organic Peroxide 

Portable Tank Table’’ or ‘‘§ 173.225(g),’’

as applicable. 

• New paragraph (c)(8) is added to 

provide an introduction to the ‘‘TP’’

codes (i.e., portable tank special 

provisions). The existing paragraph 

(c)(8) is redesignated paragraph (c)(9). 

• New Special IBC Packing Provision 

IP13 is added to specify that 

transportation by vessel in IBCs is 

prohibited. 

• New Special IBC Packing Provision 

IP14 is added to specify that air must be 

eliminated from the vapor space by 

nitrogen purging or other means. 

• New Special IBC Packing Provision 

IP20 is added to specify that dry sodium 

cyanide and potassium cyanide are also 

permitted in siftproof, water-resistant, 

fiberboard IBCs when transported in 

closed freight containers or transport 

vehicles.

• Portable tank Special Provision TP3 

is revised to include the maximum 

degree of filling (in %) for solids 

transported above their melting points. 

• Special Provision TP6 is revised by 

removing the word ‘‘event’’ and 

replacing it with the word ‘‘incident.’’

• Portable tank Special Provision TP9 

is removed from column (7) of the HMT 

for all materials that reference a T code 

special provision. Special provision TP9 

states that a material with TP9 in 

Column (7) may only be transported in 

a portable tank if approved by the 

Associate Administrator. A material that 

has been given a T code does not require 

approval and is not subject to Special 

Provision TP9. 

• In the NPRM we proposed adoption 

of a new portable tank special provision, 

TP33, by adding the new provision to 

certain entries in the HMT. However, 

we neglected to include the text of the 

provision itself. We are correcting this 

omission in this final rule. 

Section 172.202 

We are editorially revising paragraph 

(a)(2)(iii) by removing the examples that 

illustrate the optional provision to enter 

primary and subsidiary hazard class or 

division names on shipping papers for 

domestic shipments. In the HM–215E 

response to appeals final rule (69 FR 

34604) that was published on June 22, 

2004, we reinstated the provision which 

was removed in a previous rulemaking 

(68 FR 44992). During the process of 

correcting a printing error in one of the 

examples, we determined that the 

regulatory text is complete and 

sufficient without the use of examples. 

In the NPRM [69 FR 34741] we 

proposed to amend paragraph (a)(5)(i) to 

require the quantity shown on a 

shipping paper for an explosive article, 

such as Cartridges, small arms, to be the 

net mass of the entire article rather than 

the net mass of the explosive contained 

in the article. Commenters generally 

support the proposal, suggesting that it 

will provide for consistency across 

modes of transportation and for more 

accurate calculations. However, several 

of these commenters note that, for 

certain explosive articles that contain 

very small amounts of an explosive, 

showing the net mass of the article 

rather than of the explosive contained in 

the article could misrepresent the 

transportation risk associated with the 

article. Two commenters state that, 

76052 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

because shippers have historically 

calculated the net mass based on the 

actual explosive material contained in 

the article rather than the entire article, 

the clarification proposed in the NPRM 

could cause increased confusion for 

shippers. 

Internationally, as well, there is some 

concern that, at least for large explosive 

articles, the quantity indicated on the 

shipping paper should be the net mass 

of the explosive substances contained in 

the article rather than the net mass of 

the article itself. As suggested by some 

commenters to the NPRM, a number of 

the members of UN Transport of 

Dangerous Goods Sub-Committee agree 

using the net mass of the entire article 

rather than the net mass of the explosive 

material contained in the article may 

not appropriately communicate the 

explosive hazard to emergency 

responders. Until this issue is resolved 

through a change to the UN Model 

Recommendations, we are, in this final 

rule, amending paragraph (a)(5)(i) to 

clarify that for explosive articles the 

quantity shown on a shipping paper 

may be expressed in terms of the net 

mass of the article or the net mass of the 

explosive substances contained in the 

article. It should be noted, however, that 

for purposes of determining the perpackage quantity limitations shown in 

Column 9 of the HMT, § 172.101(j)(3) 

specifies that when articles or devices 

are specifically listed by name, the net 

quantity limitation applies to the entire 

article or device rather than to its 

hazardous components. This would 

include explosive articles listed by 

name in the HMT. For example, in the 

case of a listed explosive article 

weighing 15 kg and containing 500 

grams of explosive substance, the 

weight shown on the shipping paper 

may be 500 grams or 15 kg, but the 

weight used for purposes of compliance 

with Column (9) of the HMT must be 15 

kg as required by § 172.101(j)(3). 

Particularly for large articles, the 

quantity indicated on the shipping 

paper should be the net mass of the 

explosive substances contained in the 

article. For small explosive articles, 

such as Cartridges, small arms, we 

believe that the net mass of the article 

can be used to satisfy the total quantity 

requirement in § 172.202(a)(5)(i). As a 

practical matter, it is easier, and in 

certain instances necessary, for an 

offeror to provide the net mass of the 

article and the net explosive mass. For 

example, as previously stated, the net 

mass of an article must be used to 

ensure compliance with the per package 

quantity limitations set forth in Column 

9 of the § 172.101 Hazardous Materials 

Table for transport aboard aircraft or 

passenger rail (see § 172.101(j)(3)). 

However, for operational purposes, such 

as for stowage and segregation of large 

quantities of explosives or determining 

the quantity of explosives that can be 

transported on a vessel [see 

§ 176.142(b)], the net explosive mass of 

the explosive substances contained in 

articles is needed.

Section 172.203 

Paragraph (f) is revised by including 

the passenger and cargo aircraft 

limitation certification statement that is 

found in § 172.204. This aligns the HMR 

with the ICAO TI (see 4.1.5.8.1(b) of the 

ICAO TI). A new paragraph (i)(3) is 

added to specify additional shipping 

paper description requirements for a 

hazardous material consigned under an 

‘‘n.o.s.’’ entry when offered for 

transportation by vessel. In addition, 

paragraph (m)(2) is revised to specify 

that the phrase ‘‘Poison Inhalation 

Hazard’’ or ‘‘Toxic Inhalation Hazard’’ is 

not required to be repeated if it 

otherwise appears in the shipping 

description. Finally, in paragraph (o)(3), 

the reference to § 173.225(c)(2) is 

amended to read § 173.225(b)(2). 

One commenter felt the requirement 

to add a segregation code on the 

shipping paper for ‘‘n.o.s.’’ entries is 

unnecessary and unduly burdensome. 

In addition, the commenter is concerned 

that there may not be sufficient space on 

the shipping paper to indicate this 

notation. If, however, this requirement 

is adopted, the commenter requested an 

example of the required entry on 

shipping papers. We disagree. We do 

not feel this additional requirement is 

unnecessary or overly burdensome. The 

additional shipping paper description 

requirements apply only to hazardous 

material consigned under an ‘‘n.o.s.’’

entry when offered for transportation by 

vessel. We believe that consignors 

should be familiar with the hazards and 

segregation risks of their shipments, 

specifically ‘‘n.o.s.’’ materials that are 

not assigned segregation groups. By 

indicating the need to segregate such 

materials on the shipping paper, the 

consignor increases the likelihood that 

appropriate stowage procedures are 

followed, ensuring the safety of the 

vessel and its cargo. We also do not 

agree that there is inadequate space 

available on shipping papers to include 

the segregation group. However, we do 

agree that an example of the required 

entry should be presented for clarity 

and uniformity. Therefore, as 

recommended by the commenter, we are 

adding the example ‘‘IMDG Code 

segregation group—1 Acids’’ to 

§ 172.203. 

Section 172.204 and Section 172.321—

Air Eligibility Marking 

Under HM–215E (68 FR 44992), the 

air eligibility marking was adopted into 

the HMR as new § 172.321. Since 

publication of that final rule, the ICAO’s 

Dangerous Goods Panel removed the air 

eligibility marking requirement from the 

ICAO Technical Instructions. In lieu of 

this marking, ICAO adopted a 

requirement that the shipping paper 

certification statement include the 

statement ‘‘I declare that all of the 

applicable air transport requirements 

have been met’’ when a hazardous 

material is offered for air transportation. 

Additionally, the revised section 

provided examples of the applicable air 

transport requirements that must be 

met. Based on this action, we revised 

the air eligibility marking requirement 

by making it optional rather than 

mandatory and adding the additional 

shipping paper certification statement 

for shipments going by aircraft. 

Therefore, we revised § 172.204(c)(3) by 

requiring that the statement ‘‘I declare 

that all of the applicable air transport 

requirements have been met’’ be 

included on the shipping paper in 

addition to the current certification 

statement when a hazardous material is 

offered for air transportation. 

Additionally, the revised section 

provides examples of the applicable air 

transport requirements that must be met 

and various section references. In order 

to allow shippers to expend stocks of 

preprinted shipping papers containing 

the previous certification statement, we 

are providing an additional ten month 

transitional provision for the new 

certification statement. Two 

commenters support RSPA’s decision 

requiring shippers to sign the 

certification declaring compliance with 

requirements for air transportation. 

Additionally, several commenters agree 

with the revision to make the air 

eligibility marking optional. However, 

some commenters suggest making the 

marking ‘‘permissible’’ instead of 

‘‘optional’’ to avoid potential confusion. 

We disagree. We are removing the 

requirement for shippers to mark 

packages acceptable for air transport 

with the air eligibility marking. This 

revision does not prohibit the use of the 

marking. 

Section 172.315 

Section 172.315 is amended to ensure 

that packages containing limited 

quantities which are transported by air 

are marked with the proper shipping 

name. Although the amendment was not 

proposed in this rulemaking, it was 

previously proposed and adopted under 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76053

HM–215E (68 FR 45000) but was 

omitted due to an editorial error during 

publication. The amendment provides 

harmonization with the ICAO Technical 

Instructions, which do not allow the UN 

number within a square-on-point border 

as a substitute for the proper shipping 

name. Note that this amendment does 

not preclude the ID number/square-onpoint border from appearing on a 

package transported by air, it simply 

ensures that the proper shipping name 

is also required.

Section 172.317 

A new § 172.317 is added to require 

a ‘‘KEEP AWAY FROM HEAT’’

handling mark on packages containing 

self-reactive substances of Division 4.1 

or organic peroxides of Division 5.2 

when such packages are transported by 

air. 

Part 173 

Section 173.3 

The NPRM proposed to revise the 

requirements for use of salvage drums to 

include packages of hazardous materials 

that are found not to conform with the 

requirements of the HMR. In addition, 

the NPRM proposed to clarify that 

salvage drums may only be used for 

damaged, defective, non-conforming, or 

leaking packages identified as such after 

the packages have been placed in 

transportation. One commenter suggests 

that the phrase ‘‘after having been 

placed in transportation’’ as used in the 

NPRM is confusing and requests that we 

clarify the phrase using the terms ‘‘pretransportation functions’’ and 

‘‘transportation functions’’ as defined in 

a final rule published under Docket 

HM–223 October 30, 2003 (68 FR 

61905). In response to this comment, in 

this final rule, we modified § 173.3(c) to 

clarify that salvage drums are to be used 

for damaged, defective, non-conforming, 

or leaking packages identified during 

transportation as ‘‘transportation’’ is 

defined in § 5102(12) of Federal 

hazardous materials transportation 

law—that is, the movement of property 

and loading, unloading, or storage 

incidental to the movement. When the 

HM–223 final rule becomes effective, 

the statutory definition for 

‘‘transportation’’ will be added to 

§ 171.8 of the HMR, as will definitions 

for ‘‘movement,’’ ‘‘loading incidental to 

movement,’’ ‘‘unloading incidental to 

movement,’’ and ‘‘storage incidental to 

movement.’’ Note that a package found 

to be leaking prior to its being placed in 

transportation may not be packaged in 

a salvage drum. Instead, it must be 

repackaged into an authorized 

packaging in accordance with 

applicable HMR requirements. 

Section 173.24 

For consistency with the UN 

Recommendations, paragraphs (g)(4) 

and (g)(5) are revised to clarify the 

following: 

(A) That IBCs (subject to the 

requirements in § 173.24(g)) are 

permitted to be vented to reduce 

internal pressure; and 

(B) That venting of IBCs is not 

conditional upon whether a bulk special 

provision is indicated for a particular 

hazardous material in the § 172.101 

hazardous materials table. 

In addition, paragraph (i) is revised to 

clarify that other general requirements 

specific to air transportation apply and 

are found in § 173.27. 

Section 173.25 

Paragraph (a)(2) is revised by 

removing the requirement to mark an 

overpack with the air eligibility 

marking. In addition, in paragraph 

(a)(4), we are amending the HMR to 

require overpacks to be marked with the 

word ‘‘OVERPACK’’ or, alternatively, 

until October 1, 2007, with a statement 

indicating that inside packages comply 

with prescribed specifications. This is 

in response to adoption by the United 

Nations of the ‘‘OVERPACK’’ marking to 

indicate that packages within an 

overpack comply with prescribed 

specifications when specification 

markings on inside packagings within 

the overpack are not visible. 

Section 173.27 

Paragraph (i) is revised to indicate 

that the air eligibility mark has been 

removed. This section references a new 

requirement for shippers to place the 

following statement at the end of the 

certification statement when a 

hazardous material is authorized for air 

transportation: ‘‘I declare that all 

applicable air transport requirements 

have been met.’’

Section 173.28 

In paragraph (c)(2), we deleted the 

words ‘‘or a UN 1H1 plastic drum’’ in 

order to harmonize the HMR with the 

UN Model Regulations and remove a 

source of confusion within the regulated 

community regarding the reconditioning 

of a non-bulk packaging. 

Section 173.115 

In § 173.115, a new paragraph (k) is 

added (see discussion under § 172.102, 

Special Provision 153). One commenter 

noted that the proposed new 

§ 173.115(k) would not allow aerosols to 

contain corrosive substances of Packing 

Group II. The commenter further noted 

that UN Special Provision 63 allows 

aerosols to contain corrosive substances 

of Packing Group II and requested we 

harmonize with the UN Special 

Provision 63 in this regard. We agree 

with the commenter and further note 

that currently, the HMR authorizes a 

proper shipping name of ‘‘Aerosols, 

corrosive Packing Group II or III, each 

not exceeding 1 L capacity’’. We are 

amending § 173.115(k) accordingly to 

clarify that aerosols may contain 

corrosive substances of Packing Group 

II. 

Section 173.120 and Appendix H to Part 

173 

A commenter noted that under 

section § 173.120(a)(3), the reference to 

Appendix H for sustained 

combustibility tests directs the reader to 

Figures 5.1 and 5.2 found in the UN 

Recommendations. These figures are no 

longer in the UN Recommendations, 

but, rather, are located in section 32.5.2 

of the Fourth Revised Edition of the UN 

Manual of Tests and Criteria. We agree 

with the commenter. Therefore, we are 

amending Appendix H to Part 173 to 

reference the UN Manual of Tests and 

Criteria. 

Section 173.128 

In paragraph (d)(1)(i), the section 

reference is revised to read § 173.225(c). 

In addition, in paragraphs (d)(1)(ii) and 

(d)(1)(iii), the section reference is 

revised to read § 173.225(b). 

Section 173.132

In paragraph (b)(1), we revised the 

definition of LD50 for acute oral toxicity 

to indicate that adult albino rats may be 

tested without regard to gender. The 

current definition for LD50 for acute oral 

toxicity in § 173.132(b)(1) is based on 

the Organization for Economic CoOperation and Development (OECD) 

Test Guideline (TG) 401. The OECD has 

agreed to three test methods that will 

replace the current TG 401. The United 

Kingdom, Germany and the United 

States of America took the lead in the 

development of the three alternative 

tests that OECD has now adopted and 

published in the OECD Guidelines for 

the Testing of Chemicals. In a 

continuing attempt to improve the 

estimate of acute oral toxicity while 

reducing the number of animals used 

per test, three alternative TGs have been 

developed and implemented to replace 

TG 401. The three TGs are the Fixed 

Dose Procedure (FDP, TG 420), the 

Acute Toxic Class Method (ATCM, TG 

423), and the Up-and-Down Procedure 

(UDP, TG 425). The text is consistent 

76054 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

with the text in the 13th revised edition 

of the UN Model Regulations. 

Section 173.136 

We added a new paragraph (d) to 

provide a grandfather clause that will 

allow for the continued shipment of 

materials classified as corrosive to steel 

or aluminum under ASTM G 31–72 

without retesting. 

Section 173.137 

In paragraph (c)(2), we propose to 

eliminate the references to ASTM G 31–

72 as an acceptable test description and 

add a statement indicating an acceptable 

test is prescribed in the Manual of Tests 

and Criteria, Part III, Section 37. 

Sections 173.150, 173.151, 173.152, 

173.153 and 173.154 

We are allowing most Division 6.1, 

Packing Group II materials to be 

transported under the limited quantity 

provisions when the packagings contain 

not more than 100 mL (3.38 ounces) 

each for liquids or 0.5 kg (1.1 pounds) 

each for solids. However, consistent 

with the limited quantity authorization 

for Division 6.1, Packing Group III, we 

are not providing a labeling exception 

for these materials. We are also not 

allowing these materials to be shipped 

as consumer commodities. In addition, 

we revised the limited quantity sections 

for the other hazard classes of materials 

to take into account materials with a 

subsidiary hazard of 6.1 Packing Group 

II. One commenter agreed with the 

amendment allowing numerous Class 3, 

PG II materials with Class 8 and other 

subsidiary hazards to be transported as 

limited quantities. 

Section 173.185 

In § 173.185, we amended paragraphs 

(c)(3) and (e)(6), to require those lithium 

cell and battery design types that are 

required to be subjected to the UN 

performance tests to be of a type that is 

proven to meet the requirements of the 

performance tests specified in the UN 

Manual of Tests and Criteria, Fourth 

Revised Edition. These cells and 

batteries are currently required to be of 

a type that is proven to meet the tests 

in the third revised edition. We also 

proposed a grandfather provision that 

would authorize a lithium cell or battery 

that was transported prior to the 

effective date of this rule that is of a 

type proven to meet the UN 

performance tests in the third revised 

edition to not be required to be retested 

in accordance with the tests in the 

fourth revised edition. One commenter 

supported this approach and stated that 

it is both necessary and appropriate to 

allow continued transport of cells and 

batteries tested and qualified under the 

UN lithium battery design qualification 

tests in accordance with the UN Manual 

of Tests and Criteria, Third Revised 

Edition. The commenter further stated 

that providing a grandfather provision 

for previously tested cells and batteries 

would avoid the need and expense of 

requalifying these cells and batteries in 

accordance with the new tests 

prescribed in the Fourth Revised 

Edition of the UN Manual of Tests and 

Criteria. After further consideration, we 

believe that authorizing an indefinite 

period for the transport of batteries that 

were tested in accordance with the UN 

Manual of Tests and Criteria, Third 

Revised Edition, 1999 may not be in the 

best interest of safety. The tests in the 

UN Manual of Tests and Criteria, Fourth 

Revised Edition provide a slightly 

higher level of safety and we believe 

that further consideration needs to be 

taken in considering whether at some 

point in time all applicable lithium 

batteries and cell design types should be 

proven to meet the requirements of the 

UN Manual of Tests and Criteria, Fourth 

Revised Edition. As a result, we will 

issue a proposal shortly specifically to 

address the full unrestricted adoption of 

the Fourth Revised Edition of the UN 

Manual of Tests and Criteria. 

Section 173.186 

In § 173.186, in paragraph (e), we 

amended the gross weight for UN 4G 

outer packages authorized for the 

transportation of strike-anywhere 

matches, to be consistent with the UN 

Model Regulations by increasing the 

weight from 27 kg (60 pounds) to 30 kg 

(66 pounds).

Section 173.187 

We revised § 173.187 to authorize 

certain solid hazardous materials to be 

transported in DOT specification 

cylinders other than Specification 8 and 

3HT cylinders. This change eliminates 

the need for DOT Exemption ‘‘DOT–E 

11548.’’

Sections 173.211, 173.212, and 173.213 

We revised these sections to authorize 

certain solid hazardous materials to be 

transported in DOT specification 

cylinders other than Specification 8 and 

3HT cylinders. This change removed the 

need for DOT Exemption ‘‘DOT–E 

11548.’’

Section 173.219 

We revised § 173.219 for consistency 

with the UN Model Regulations and the 

ICAO Technical Instructions. Included 

in the revision is an allowance for selfinflating life-saving appliances to 

contain cartridges, power devices of 

Division 1.4S, for purposes of the selfinflating mechanism. In addition, we 

provided an exception from regulation 

for life-saving appliances containing 

only carbon dioxide cylinders not 

exceeding 100 cm3 capacity, provided 

they are overpacked in rigid outer 

packagings with a maximum gross mass 

of 40 kg. Finally, the limitations 

currently found in Special Provision 

143 are relocated to § 173.219 (see 

preamble discussion under Special 

Provision 143). 

Section 173.220 

Paragraph (b)(2) is amended to 

harmonize the requirements for 

transporting flammable gas powered 

vehicles by air with the requirements of 

Packing Instruction 900 of the ICAO 

Technical Instructions. 

Section 173.224 

Paragraph (b)(4) of this section is 

amended to include the new references 

for § 173.225. The section reference to 

§ 173.225(e) for the authorization of 

bulk packagings is replaced with 

§ 173.225(f) for IBCs and § 173.225(h) 

for other bulk packagings. 

Section 173.225 

This section is amended to update the 

Organic Peroxide Table and eliminate 

special provisions IB52 and T23 from 

§ 172.102(c). The purpose of the change 

is to consolidate the packaging 

requirements for organic peroxides into 

one section and to have separate tables 

for organic peroxides authorized for 

transport in non-bulk packagings, IBCs, 

and bulk packagings other than IBCs. 

The changes are as follows: 

Paragraph (a) is revised by adding 

paragraphs (b) and (b)(6), which state 

that bulk packagings may require a 

lower control temperature than those 

specified for non-bulk packagings and 

that an organic peroxide not identified 

in either the Organic Peroxide Table, 

Organic Peroxide IBC Table, or Organic 

Peroxide Portable Tank Table must be 

approved under § 173.128(c). 

Paragraph (b) is revised to eliminate 

all IBC and other bulk packaging 

authorizations from column 6 of the 

Organic Peroxide Table. Various 

obsolete entries were also removed. The 

current paragraph (b), ‘‘Organic 

Peroxide Table,’’ is moved to paragraph 

(c) and the current paragraph (c), ‘‘New 

organic peroxides, formulations and 

samples,’’ is moved to paragraph (b). 

The notes following the Organic 

Peroxide Table are changed as follows: 

• Revise note 22 to indicate that 

ethylbenzene with greater than or equal 

to 25% of dilutant type A is acceptable. 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76055

• Revise note 23 to indicate that 

methyl isobutyl keytone with greater 

than or equal to 19% of dilutant type A 

is acceptable. 

• Add a new note 29 to identify 

materials which are not included in the 

UN Model Regulations and note that a 

Competent Authority approval is 

required for international 

transportation. 

• Remove Notes 9, 11, and 14 

following the Organic Peroxide Table. 

In addition, The Packing Method 

Table found in paragraph (d), is revised 

by replacing the 200 kg maximum 

quantity for solids and combination 

packagings listed in OP8 with a 400 kg 

maximum quantity. Note 2, following 

the table, is revised to allow 200 kg of 

solid material per box and up to 400 kg 

of material per authorized combination 

packaging. The note also indicates that 

the outer packaging must be a box (4C1, 

4C2, 4D, 4F, 4G, 4H1, and 4H2) and 

each inner packaging must be of plastics 

or fiber with a maximum net mass of 25 

kg. Paragraph (d)(3) is clarified by 

revising the text to state that the 

maximum content acceptable for glass 

receptacles used as inner packagings of 

a combination packaging is 0.5 kg for 

solids or 0.5 L for liquids.

A new paragraph (e) is added to 

include the new ‘‘Organic Peroxide IBC 

Table’’ that replaces the current ‘‘Table 

2.—Organic Peroxide IBC Code (IB52)’’

in § 172.102(c)(4). The new table is 

revised to add an organic peroxide, 

‘‘Dicyclohexylperoxydicarbonate, not 

more than 42% as a stable dispersion, 

in water.’’ In addition, the new Organic 

Peroxide IBC Table identifies, by 

technical name, those organic peroxides 

authorized for transportation in the IBCs 

that are specifically listed in the table. 

A new paragraph (f) is added to 

include the current IBC requirements 

contained in paragraph (e)(5) of this 

section. Paragraph (f) also includes 

requirements that are specific to organic 

peroxides packaged in IBCs. 

A new paragraph (g) is added to 

include the new ‘‘Organic Peroxide 

Portable Tank Table,’’ that replaces the 

current ‘‘Portable Tank Code T23’’

found in § 172.102(c)(7)(iii). The new 

table is identical to the current table 

except that for UN 3109, in the entry for 

Pinanyl hydroperoxyde, 50% is 

replaced by 56% and all references to 

self-reactive materials are removed. In 

addition, the Organic Peroxide Portable 

Tank Table provides certain portable 

tank requirements and identifies, by 

technical name, those organic peroxides 

authorized for transportation in the bulk 

packagings listed in the new paragraph 

(h). 

The current paragraph (e) is 

redesignated as paragraph (h). Paragraph 

(h) establishes requirements that are 

specific to organic peroxides packaged 

in certain bulk packagings. 

Additionally, the new ‘‘Note to 

Paragraph (h)(3)(vi)’’ is revised to 

include changes brought forth by 

petition for rulemaking P–1428. The 

petition proposed to amend the current 

paragraph (e)(3)(vi) and allow for a 

second but equally acceptable example 

of an emergency-relief device sizing 

method to be added to the HMR. We 

agreed with the petitioner and added a 

statement to the new paragraph 

(h)(3)(vi) indicating that an additional 

example of an emergency-relief device 

sizing method can be found in the 

‘‘American Institute of Chemical 

Engineers Process Safety Progress 

Journal, June 2002 issue (Vol. 21, No. 

2)’’ as referenced in § 171.7(b). 

The changes to this section altered the 

order of the paragraphs within this 

section; therefore, various citations were 

changed. Also, paragraphs referencing 

IB52 or TP23 are revised to indicate that 

those provisions no longer exist and the 

updated requirements are found in 

paragraph (e) and (g), respectively. A 

commenter requested that § 173.225 be 

revised to allow for increased industry 

flexibility, regulatory uniformity, and to 

better align with the UN 

Recommendations. We agree and have 

made the following revisions: 

• Added wording to 173.225(a) to 

show that organic peroxides that are not 

identified in the organic peroxide table, 

but are in paragraph (b)(3) are not 

subject to the requirements of § 173.128. 

• Removed Note 1 from both entries 

of tert-Butyl cumyl peroxide and Note 

11 from Dicumyl peroxide. 

• Removed the sentence ‘‘The 

additional requirements in paragraph 

(h)(5)(i) and (h)(5)(ii) of this section also 

apply’’ from § 173.225(f) and 

renumbered (f)(i) and (f)(ii) as (f)(1) and 

(f)(2), respectively. 

• Revised the introductory text to 

Paragraph (h) to indicate that the bulk 

packagings that follow are for materials 

authorized for transport in a bulk 

packaging by Paragraph (h) and organic 

peroxides listed in the Organic Peroxide 

Portable Tank Table.

• Removed two occurrences of the 

term ‘‘Type F’’ from Paragraph (h)(3) to 

broaden the applicability of the 

provisions. 

• Removed statement from 

§ 173.225(h)(3)(xii) indicating that DOT 

Specification 57 portable tanks are not 

subject to the requirements of 

paragraphs (h)(3)(ii) and (h)(3)(iv) of this 

section. 

Sections 173.226 and 173.227 

We revised the packaging 

requirements of §§ 173.226 and 173.227 

for materials poisonous by inhalation, 

Division 6.1, Packing Group I, 

Hazardous Zone A and Hazard Zone B. 

These amendments have: Reduced the 

hydrostatic test pressure of the inner 

drum in a drum-within-a-drum 

configuration authorized in 

§ 173.226(b); standardized the minimum 

thickness requirements of the inner 

drums in the drum-within-a-drum 

configuration authorized in 

§§ 173.226(b) and 173.227(b); clarified 

the test requirements for inner 

packaging systems in § 173.226(b)(2)(iv); 

and in § 173.226(d) added a provision to 

authorize transportation of PIH 

materials in single packages when 

subjected to additional operational 

controls and approved by the Associate 

Administrator. Section 173.226(c)(2) is 

reformatted for ease of understanding. 

We removed an expired transitional 

date from paragraph (a) that allows the 

transport of welded cylinders filled 

before October 1, 2003 for the purpose 

of reprocessing or disposal of 

cylinders’s content until December 31, 

2003. One commenter recommended 

that we include a provision in 

§ 173.227(b) to allow for the testing of 

the outer drum of a drum-in-drum 

package as either as a package intended 

to contain inner packagings 

(combination package) or as a single 

packaging intended to contain solids or 

liquids. We agree and have revised 

§ 173.227(b) accordingly. Another 

commenter suggested that we increase 

the minimum thickness of a UN 1A1 

drum in PIH service from .69 mm to 1.0 

mm. Increasing the minimum thickness 

of a UN 1A1 drum in PIH service was 

not proposed in this rulemaking and 

inclusion of such a requirement is 

beyond the scope of this rulemaking. 

However, we are reviewing this request 

for consideration in a future rulemaking. 

Section 173.249 

Paragraph (c) is revised to be 

consistent with the current ‘‘Bromine’’

entry in the § 172.101 ‘‘Hazardous 

Material Table’’ that authorizes the use 

of a UN portable tank conforming to 

tank code T22. A commenter suggested 

that we include a provision authorizing 

the returning of a tank containing 

bromine residue. We agree that such a 

provision is necessary and have 

amended § 173.249 accordingly. 

Sections 173.306 and 173.307 

To add clarity to the HMR, the text 

currently found in § 173.306(i) is 

removed and replaced with the text 

76056 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

currently found in § 173.307(a)(5). Since 

§ 173.306 is devoted exclusively to 

limited quantities of compressed gases, 

relocating § 173.307(a)(5) to § 173.306 

makes the exception easier to find.

Section 173.313 

A new § 173.313 is added to serve as 

the new location for the Portable Tank 

Code T50 Table. The table is renamed 

‘‘UN Portable Tank Table for Liquefied 

Compressed Gases.’’ The table provides 

the maximum allowable working 

pressures, bottom opening 

requirements, pressure relief 

requirements and degree of filling 

requirements for liquefied compressed 

gases permitted for transport in portable 

tanks. The change relocates these 

packaging requirements to Part 173, 

which is a more appropriate location, 

and makes the special provisions less 

cumbersome. In addition, the new UN 

Portable Tank Table for Liquefied 

Compressed Gases is amended by 

revising the Column 3 heading to read 

‘‘Minimum design pressure (bar) * * *’’

The values in column 3 are actually 

minimum values, however the title of 

the column is misleading because it 

uses the term ‘‘Maximum allowable 

working pressure (bar) * * *’’

Section 173.315 

In paragraph (a), the reference to 

‘‘portable tank provision T50 in 

§ 172.102’’ is revised to read ‘‘the UN 

Portable Tank Table for Liquefied 

Compressed Gases in § 173.313.’’

Section 173.323 

After further considering the 

proposed changes to the packaging 

authorizations for ethylene oxide in 

§ 173.323, we noted that the total 

quantity per package of ethylene oxide 

authorized for transport when glass 

inner receptacles are used was proposed 

to be increased from 100 grams to 2.5 

kg. Due to the extremely flammable and 

explosive properties of ethylene oxide 

and the fragile properties of glass, after 

further consideration we have chosen 

not to adopt the 2.5 kg outer package 

limit found in the UN 

Recommendations and to retain our 

current outer package limit of 100 

grams. The total quantity per package 

when metal inner receptacles are used 

will remain unchanged from the 

proposed 2.5 kg. In this rule, paragraphs 

(b)(1)–(b)(3) are revised and 

consolidated for consistency with 

current international requirements for 

the transportation of ethylene oxide in 

combination packagings. Paragraphs 

(b)(1)–(b)(3) provide the current 

authorizations for glass, aluminum, and 

metal receptacles respectively. 

Amendments to this section include (1) 

removing the HMR limitation of 12 

inner receptacles per outer package 

currently applied to aluminum and 

other metal receptacles, (2) removing 

the overpack restriction in (b)(2) which 

specifies a maximum of 10 boxes per 

overpack, (3) requiring a hot water bath 

test for all inner receptacles, (4) 

removing the pressure relief device and 

burst pressure requirements currently 

applied to metal receptacles, (5) 

applying the same outer package 

authorizations consistently to all inner 

packaging types and allowing any outer 

package authorized in § 172.201(b), and 

(6) requiring all inner packagings to be 

suitably cushioned (the top and bottom 

pad and perimeter liner requirement 

currently only applied to outer packages 

containing aluminum inner packagings 

is removed). Though we are eliminating 

the option to utilize certain packaging 

authorizations for glass and aluminum 

inner packagings, we believe that this 

change will have little or no economic 

impact on the ethylene oxide industry 

because of the amount of materials that 

are transported in international 

commerce. 3M Package Engineering 

requested that we reduce the maximum 

quantity of ethylene oxide permitted in 

any metal inner packaging from 340 g 

(12 ounces) to 200 g (7 ounces). They 

stated that such a change would more 

adequately align the HMR with 

international standards. We agree that 

such a change would align the HMR 

with international requirements. 

However, allowing a metal inner 

packaging to contain a maximum 

quantity of 340 g (12 ounces) does not 

limit compliance with international 

requirements. In addition, we cannot 

adopt the 200 g (7 ounces) limitation in 

this rulemaking because such a change 

would be more restrictive then the 

requirements we proposed. We may 

consider adopting the 200 g (7 ounces) 

limitation in a future rulemaking.

Part 175 

Section 175.10 

Consistent with an amendment to the 

ICAO TI, we are requiring that aerosol 

cans that are carried aboard an aircraft 

in accordance with § 175.10(a)(4) have 

their release devices protected by a cap 

or other suitable means. In addition, the 

ICAO Dangerous Goods Panel will 

convene a series of working groups to 

develop recommendations for 

consideration during the 20th session of 

the Dangerous Goods Panel to further 

review this issue. These 

recommendations may lead to 

additional amendments to the ICAO TI. 

Finally, we note that non-flammable 

gases (e.g., nitrogen) other than carbon 

dioxide are used for the operation of 

mechanical limbs. Consistent with an 

amendment to the ICAO TI, we are 

proposing to provide an exception from 

the HMR for mechanical limbs that are 

powered by any Division 2.2 gas. One 

commenter recommended that the 

release device requirements added to 

§ 175.10 also be incorporated into Part 

173. Specifically, they requested that 

aerosol cans that are transported in 

commerce be protected by a cap or other 

suitable means to prevent inadvertent 

release. They indicated that this change 

should be coordinated with the Federal 

Aviation Administration (FAA). We 

disagree. Section 173.24(b)(1) states that 

each package used for the shipment of 

hazardous materials must be 

constructed, maintained, filled, its 

contents so limited, and closed, so that 

under conditions normally incident to 

transportation there will be no 

identifiable release of hazardous 

materials to the environment. We feel 

this section adequately addresses the 

commenter’s concerns, and allows 

shippers the flexibility to properly 

protect aerosol cans. 

Section 175.85 

In § 175.85, a new paragraph (j) is 

added to specify the cargo location of a 

package bearing the ‘‘KEEP AWAY 

FROM HEAT’’ handling marking. 

Part 176 

Section 176.2 

Certain definitions are revised. The 

definitions for ‘‘Explosive article’’ and 

‘‘Explosive substance’’ are revised to 

remove an incorrect reference. The 

definition for ‘‘Magazine’’ is revised to 

include a compartment in the vessel. 

The definition for ‘‘Magazine’’ is also 

revised to specify vessel storage location 

and accessibility. The term ‘‘Transport 

unit’’ is revised to read ‘‘Cargo transport 

unit’’ to be consistent with Amendment 

32 of the IMDG Code. In addition, in the 

definition ‘‘In containers or the like’’ the 

term ‘‘transport unit’’ is removed and 

the term ‘‘cargo transport unit’’ is added 

in its place. 

Section 176.27 

In this section, the words ‘‘transport 

unit’’ are replaced with the words 

‘‘transport vehicle’’ in each place they 

appear to be consistent with the removal 

of the term ‘‘transport unit’’ from the 

definitions in § 176.2. 

Section 176.63 

Paragraph (e) is revised to align the 

definition of ‘‘Closed cargo transport 

unit’’ to be consistent with the 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76057

definition in Amendment 32 of the 

IMDG Code. 

Section 176.76 

Paragraph (i) is revised to clarify that 

for container ships, a distance 

equivalent to one container space 

athwartships (i.e., in the direction of the 

breadth of the vessel) away from 

possible sources of ignition applied in 

any direction satisfies the requirement 

that a cargo transport unit packed or 

loaded with flammable gas or flammable 

liquid having a flashpoint below +23 °C 

transported on deck be stowed ‘‘away 

from’’ possible ignition sources. This is 

consistent with Amendment 32 of the 

IMDG Code. In addition, in paragraphs 

(h) and (i), the words ‘‘transport unit’’

are removed and replaced with the 

words ‘‘cargo transport unit’’ in each 

place they appear to be consistent with 

Amendment 32 of the IMDG.

Section 176.83 

Paragraph (l) is revised to correct an 

error pertaining to the Segregation Table 

that sets forth the general requirements 

for segregation of containers on board 

hatchless container vessels. In addition, 

throughout the section the words 

‘‘transport units’’ are removed and 

replaced with the words ‘‘cargo 

transport units’’ in each place they 

appear to be consistent with 

Amendment 32 of the IMDG. A new 

paragraph (m) is added to specify the 

provisions for segregation groups. 

Section 176.84 

Paragraph (a) is revised to specify the 

various chemical groups listed in the 

segregation table. In the paragraph (b) 

Table of Provisions, we added eleven 

new provisions (codes) for certain 

stowage and segregation requirements 

for hazardous materials that are 

transported by vessel. In addition, in 

paragraph (c)(2) Provisions for the 

stowage of Class 1 (explosive) materials, 

we revised three notes. The terms 

‘‘separated from’’ and ‘‘away from’’ in 

the codes are defined in § 176.83 of the 

HMR. 

Code 133 is added to the entries 

‘‘Barium chlorate solution,’’ UN3405; 

‘‘Barium perchlorate solution,’’ UN3406; 

and ‘‘Chlorate and magnesium chloride 

mixture solution,’’ UN3407, that 

requires the material to be stowed 

‘‘separated from’’ sulfur. 

Code 134 is added to the entry 

‘‘Aluminum alkyl halides, solid,’’

UN3461, that requires the material to be 

stowed ‘‘separated from’’ UN2716. 

Code 135 is added to the entries 

‘‘Methylamine, aqueous solution,’’

UN1235 and ‘‘Trimethylamine, aqueous 

solutions,’’ UN1297, that requires the 

material to be stowed ‘‘separated from’’

mercury and mercury compounds. 

Code 136 is added to the entry 

‘‘Tributylphosphane,’’ UN3254, that 

requires the material to be stowed 

‘‘separated from’’ carbon tetrachloride. 

Code 137 is added to the entries 

‘‘Arsenic compounds, liquid, n.o.s.,’’

UN1556 and ‘‘Arsenic compounds, 

solid, n.o.s.,’’ UN1557, that requires 

arsenic sulphides to be stowed 

‘‘separated from’’ acids. 

Code 138 is added to the entries for 

UN1448; UN1456; UN1479; UN1482; 

UN1490; UN1503; UN1515; UN3085; 

UN3087; UN3098; UN3099; UN3139; 

and UN3214, that requires the material 

to be stowed ‘‘separated from’’

peroxides. 

Code 139 is added to the entry ‘‘1, 4-

Butynediol,’’ UN2716, that requires the 

material to be stowed ‘‘separated from’’

mercury salts. 

Code 140 is added to the entry ‘‘1, 4-

Butynediol,’’ UN2716, that requires the 

material to be stowed ‘‘separated from’’

UN3052 and UN3461. 

Code 141 is added to the entries for 

UN1732; UN1755; UN1806; UN1908; 

UN2433; UN2859; and UN2861, that 

requires the material to be stowed 

‘‘away from’’ radioactive materials. 

Code 142 is added to the entries for 

UN1748; UN2208; and UN2880, that 

requires packages in cargo transport 

units to be stowed so as to allow for 

adequate air circulation throughout the 

cargo. 

Code 143 is added to the entry for 

Organometallic Substance, Liquid, 

Pyrophoric, UN3392, prohibiting 

transportation on any vessel carrying 

explosives (except explosives in 

Division 1.4, compatibility group S. 

Note 19E is revised to specify that 

materials under entries NA0331; 

UN0004; UN0222; UN0241; and 

UN0402 must be stowed ‘‘away from’’

explosives containing chlorates or 

perchlorates. 

Note 22E is revised to specify that 

materials under the entry ‘‘Explosive, 

blasting, type C,’’ must be stowed ‘‘away 

from’’ ammonium compounds and 

explosives containing ammonium 

compounds or salts. 

Note 23E is revised to specify that 

materials under entries UN0247; 

UN0395; UN0396; UN0397; UN0398; 

UN0399; UN0400; UN0449; and 

UN0450 must be ‘‘separated from’’

Division 1.4 and ‘‘separated 

longitudinally by an intervening 

complete compartment or hold from’’

Division 1.1, 1.2, 1.3, 1.5, and 1.6 except 

from explosives of compatibility group 

J. 

A commenter questioned how 

adequate air circulation was achieved in 

a cargo transport unit. In addition, the 

commenter stated that it fails to 

understand why air circulation is 

necessary in a closed cargo transport 

unit, as indicated by Stowage Provision 

142. Stowage Provision 142 indicates 

that packages in cargo transport units 

must be stowed so as to allow for 

adequate air circulation throughout the 

cargo. We feel cargo transport units that 

are properly loaded will allow for the 

adequate circulation of air by natural 

means so as to safeguard against 

excessive heat buildup within the cargo.

Section 176.116 

In paragraph (c), the words ‘‘transport 

units’’ are revised to read ‘‘cargo 

transport units.’’ In addition, a new 

paragraph (f) is added to specify the 

under deck stowage requirements of 

Class 1 (explosive) materials allocated 

stowage categories 09 and 10. 

Sections 176.122 and 176.124 

Sections 176.122 and 176.124 are 

removed and reserved. 

Section 176.128 

In § 176.128, the section heading and 

section are revised. 

Section 176.132 

Section 176.132 is removed and 

reserved. 

Section 176.133 

Section 176.133 is revised to clarify 

the construction and stowage location 

requirements for magazine stowage type 

C. 

Section 176.136 

Section 176.136 is revised to clarify 

the special stowage requirements of 

Class 1 (explosive) materials. In 

addition, minor editorial revisions are 

made. 

Section 176.138 

Paragraph (a) is removed and reserved 

to be consistent with Amendment 32 of 

the IMDG Code. This paragraph 

currently requires Class 1 (explosive) 

material that is stowed on deck to be 

carried as close to the vessel’s centerline 

as practicable.(See also change to 

§ 176.170.) 

Section 176.142 

Paragraph (a) is revised to remove 

‘‘Pyrophoric organometallic compound, 

water-reactive, n.o.s.’’ from the list of 

liquid hazardous materials of extreme 

flammability that may not be 

transported in a vessel carrying Class 1 

(explosive) materials. Additionally, we 

added to the above list the following 

new liquid entries: 

76058 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

• ‘‘Organometallic substance, liquid, 

pyrophoric, UN3392’’

• ‘‘Organometallic substance, liquid, 

pyrophoric, water-reactive, UN3394’’

These changes are consistent with 

Amendment 32 of the IMDG Code. 

Section 176.144 

In this section, the words ‘‘transport 

unit’’ are replaced with the words 

‘‘cargo transport unit’’ in each place 

they appear to be consistent with the 

definition in Amendment 32 of the 

IMDG Code. Additional notes are added 

to Table 176.144(a)—‘‘Authorized 

Mixed Stowage For Explosives’’ to 

address additional exceptions for mixed 

stowage of Class 1 materials.

Section 176.146 

In § 176.146, in paragraph (d)(1), the 

wording ‘‘transport units’’ is revised to 

read ‘‘cargo transport units.’’

Section 176.168 

In § 176.168, in the title before the 

section heading, the wording 

‘‘TRANSPORT UNITS AND 

SHIPBORNE BARGES’’ are revised to 

read ‘‘CARGO TRANSPORT UNITS 

AND SHIPBORNE BARGES.’’

Section 176.170 

A new paragraph (b) is added to 

prohibit freight containers loaded with 

Class 1 (explosive) materials, except for 

explosives in Division 1.4, from being 

stowed in the outermost row of 

containers. This change is consistent 

with Amendment 32 of the IMDG Code. 

Section 176.174 

Paragraphs (a) and (b) are revised to 

remove the references to portable 

magazines. This change is consistent 

with Amendment 32 of the IMDG Code. 

Section 176.600 

In § 176.600, in paragraph (a), the 

wording ‘‘closed transport units’’ is 

revised to read ‘‘closed cargo transport 

units.’’

Part 178 

Section 178.274 

Paragraph (f)(v) is revised to more 

clearly specify the rated flow capacity 

marking required to be placed on every 

UN portable tank’s pressure relief 

device. 

Section 178.275 

Paragraph (i)(2) is revised to more 

clearly specify the combined delivery 

capacity of UN portable tank’s pressure 

relief systems. 

Section 178.276 

In paragraph (a)(4)(ii)(A), the 

reference to ‘‘portable tank special 

provision T50’’ is revised to read ‘‘the 

UN Portable Tank Table for Liquefied 

Compressed Gases in § 173.313.’’ In 

addition, paragraph (d), the reference to 

‘‘portable tank special provision T50 in 

§ 172.102(c)(7)’’ is revised to read ‘‘UN 

Portable Tank Table for Liquefied 

Compressed Gases in § 173.313.’’

Finally, in paragraph (e)(3), the 

reference to ‘‘portable tank special 

provision T50 in § 172.102’’ is revised to 

read ‘‘the UN Portable Tank Table for 

Liquefied Compressed Gases in 

§ 173.313.’’

Section 178.602 

Paragraph (b) is revised to clarify the 

requirements applicable to filling 

packaging other than bags in 

preparation for testing. 

Section 178.603 

Paragraph (c) is revised to add a 

definition indicating that a minimum 

specific gravity for solutions of water 

and anti-freeze is 0.95 for testing at 18 

°C (0 °F) or lower. Additionally, in 

paragraph (e), we specify the drop test 

height for liquids in single packagings 

and for inner packagings of combination 

packagings, when the test is performed 

in water. 

Section 178.810 

Paragraph (b)(3) is revised to specify 

that water/anti-freeze solutions with a 

minimum specific gravity of 0.95 for 

testing at ¥18 °C (0 °F) or lower are 

acceptable test liquids for use when 

conducting IBC drop tests. This is 

consistent with our amendment to 

§ 178.603(c)(1) regarding the testing of 

non-bulk packages. In addition, we 

added a sentence to clarify that when 

conditioning is required by § 178.810(b), 

the conditioning specified in § 178.802 

(which requires a higher temperature) 

does not apply.We received a comment 

from the Reusable Industrial Packaging 

Association (RIPA) concerning this 

revision. RIPA believes that RSPA 

intended to clarify that water/antifreeze 

solutions with a minimum specific 

gravity of 0.95 are equivalent for testing 

purposes to IBCs containing only water, 

thereby eliminating the need to adjust 

the drop height of test units. RIPA stated 

that § 178.810(b)(3) should be revised to 

indicate that this solution may be 

considered equivalent to water for 

testing purposes. We agree and have 

revised the section accordingly. 

Part 180 

Section 180.350 

Paragraph (c) is revised to expand the 

definition of routine maintenance of 

IBCs to include flexible, plastic and 

textile IBCs. 

Section 180.352 

Paragraph (d)(1)(iv) is revised to 

require persons other than the owner of 

metal, rigid plastics, and composite 

IBCs to mark the IBC indicating routine 

maintenance has been performed when 

such maintenance is performed. A new 

paragraph (d)(1)(v) is added to this 

section. This paragraph states that 

retests and inspections performed under 

paragraphs (d)(1)(i) and (ii) of this 

section may be used to satisfy the tests 

and inspections required by paragraph 

(b) of this section. This addition 

incorporates changes made to the 12th 

revised edition of the Transport of 

Dangerous Goods Model Regulations 

into the HMR. Three commenters 

requested that we revise § 180.352 to 

distinguish requirements applicable to 

repair and routine maintenance of IBCs. 

We agree and have revised § 180.352 

creating a new paragraph entitled, 

‘‘Requirements applicable to routine 

maintenance of IBCs.’’

V. Regulatory Analyses and Notices 

A. Statutory/Legal Authority for This 

Rulemaking 

This final rule is published under the 

following statutory authorities: 

1. 49 U.S.C. 5103(b) authorizes the 

Secretary of Transportation to prescribe 

regulations for the safe transportation, 

including security, of hazardous 

material in intrastate, interstate, and 

foreign commerce. This final rule 

amends regulations to maintain 

alignment with international standards 

by incorporating various amendments, 

including changes to proper shipping 

names, hazard classes, packing groups, 

special provisions, packaging 

authorizations, air transport quantity 

limitations and vessel stowage 

requirements. To this end, as discussed 

in detail earlier in this preamble, the 

final rule amends the HMR to more fully 

align it with the biennial updates of the 

UN Recommendations, the IMDG Code 

and the ICAO Technical Instructions to 

facilitate the transport of hazardous 

materials in international commerce. 

2. 49 U.S.C. 5120(b) authorizes the 

Secretary of Transportation to ensure 

that, to the extent practicable, 

regulations governing the transportation 

of hazardous materials in commerce are 

consistent with standards adopted by 

international authorities. This final rule 

amends the HMR to maintain alignment 

with international standards by 

incorporating various amendments to 

facilitate the transport of hazardous 

material in international commerce. To 

this end, as discussed in detail earlier in 

this preamble, the final rule 

incorporates changes into the HMR 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76059

based on the Thirteenth Revised Edition 

of the UN Recommendation, 

Amendment 32 to the IMDG Code, and 

the 2005–2006 ICAO Technical 

Instructions, which become effective 

January 1, 2005. The continually 

increasing amount of hazardous 

materials transported in international 

commerce warrants the harmonization 

of domestic and international 

requirements to the greatest extent 

possible. Harmonization serves to 

facilitate international transportation; at 

the same time, harmonization ensures 

the safety of people, property, and the 

environment by reducing the potential 

for confusion and misunderstanding 

that could result if shippers and 

transporters were required to comply 

with two or more conflicting sets of 

regulatory requirements. While the 

intent of this rulemaking is to align the 

HMR with international standards, we 

review and consider each amendment 

on its own merit based on its overall 

impact on transportation safety and the 

economic implications associated with 

its adoption into the HMR. Our goal is 

to harmonize without sacrificing the 

current HMR level of safety and without 

imposing undue burdens on the 

regulated public. Thus, as discussed in 

detail earlier in this preamble, there are 

several instances where we elected not 

to adopt a specific provision of the UN 

Recommendations, the IMDG Code or 

the ICAO Technical Instructions; 

further, we are maintaining a number of 

current exceptions for domestic 

transportation that should minimize the 

compliance burden on the regulated 

community. 

B. Executive Order 12866 and DOT 

Regulatory Policies and Procedures 

This final rule is not considered a 

significant regulatory action under 

section 3(f) of Executive Order 12866 

and, therefore, was not reviewed by the 

Office of Management and Budget. This 

final rule is not considered a significant 

rule under the Regulatory Policies and 

Procedures of the Department of 

Transportation [44 FR 11034]. Benefits 

resulting from the adoption of the 

amendments in this final rule include 

enhanced transportation safety resulting 

from the consistency of domestic and 

international hazard communications 

and continued access to foreign markets 

by domestic shippers of hazardous 

materials. This final rule applies to 

offerors and carriers of hazardous 

materials, such as chemical 

manufacturers, chemical users and 

suppliers, packaging manufacturers, 

distributors, battery manufacturers, 

radiopharmaceutical companies, and 

training companies. 

The majority of amendments in this 

final rule should result in cost savings 

and ease the regulatory compliance 

burden for shippers engaged in 

domestic and international commerce, 

including trans-border shipments 

within North America. For example, 

cost savings will be realized by shippers 

and carriers as a result of the following:

—Eliminating the air eligibility marking 

requirement. 

—Amendments allowing numerous 

Class 3, PG II materials with a Class 

8 sub-risk and others to be transported 

as a limited quantity. 

—Allowing cylinders to be used for 

many more substances than currently 

authorized. 

—Allowing salvage packagings to be 

used for non-conforming packages; 

and generally minimizing differences 

between U.S. and international 

hazardous materials transportation 

regulations.

We are authorizing a delayed effective 

date and a one-year transition period to 

allow for training of employees and to 

ease any burden on entities affected by 

the amendments. The total net increase 

in costs to businesses in implementing 

this rulemaking is considered to be 

minimal and a regulatory evaluation is 

available for review in the Docket.

C. Executive Order 13132 

This final rule has been analyzed in 

accordance with the principles and 

criteria contained in Executive Order 

13132 (‘‘Federalism’’). This final rule 

preempts State, local and Indian tribe 

requirements but does not propose any 

regulation that has substantial direct 

effects on the States, the relationship 

between the national government and 

the States, or the distribution of power 

and responsibilities among the various 

levels of government. Therefore, the 

consultation and funding requirements 

of Executive Order 13132 do not apply. 

The Federal hazardous material 

transportation law, 49 U.S.C. 5101–

5127, contains an express preemption 

provision (49 U.S.C. 5125(b)) that 

preempts State, local, and Indian tribe 

requirements on certain covered 

subjects. Covered subjects are:

(1) The designation, description, and 

classification of hazardous materials; 

(2) The packing, repacking, handling, 

labeling, marking, and placarding of 

hazardous materials; 

(3) The preparation, execution, and use of 

shipping documents related to hazardous 

materials and requirements related to the 

number, contents, and placement of those 

documents; 

(4) The written notification, recording, and 

reporting of the unintentional release in 

transportation of hazardous; and 

(5) The design, manufacture, fabrication, 

marking, maintenance, recondition, repair, or 

testing of a packaging or container 

represented, marked, certified, or sold as 

qualified for use in transporting hazardous 

material.

This final rule addresses covered 

subject items (1), (2), (3), and (5) above 

and preempts State, local, and Indian 

tribe requirements not meeting the 

‘‘substantively the same’’ standard. This 

final rule is necessary to incorporate 

changes adopted in international 

standards, effective January 1, 2005. If 

the changes in this final rule are not 

adopted in the HMR, U.S. companies, 

including numerous small entities 

competing in foreign markets, are at an 

economic disadvantage. These 

companies are forced to comply with a 

dual system of regulations. The changes 

in this rulemaking are intended to avoid 

this result. Federal hazardous materials 

transportation law provides at section 

5125(b)(2) that, if DOT issues a 

regulation concerning any of the 

covered subjects, DOT must determine 

and publish in the Federal Register the 

effective date of Federal preemption. 

The effective date may not be earlier 

than the 90th day following the date of 

issuance of the final rule and not later 

than two years after the date of issuance. 

The effective date of Federal preemption 

is March 21, 2005. 

D. Executive Order 13175 

This final rule was analyzed in 

accordance with the principles and 

criteria contained in Executive Order 

13175 (‘‘Consultation and Coordination 

with Indian Tribal Governments’’). 

Because this final rule does not have 

tribal implications, does not impose 

substantial direct compliance costs, and 

is required by statute, the funding and 

consultation requirements of Executive 

Order 13175 do not apply.

E. Regulatory Flexibility Act, Executive 

Order 13272, and DOT Procedures and 

Policies 

The Regulatory Flexibility Act (5 

U.S.C. 601 et seq.) requires an agency to 

review regulations to assess their impact 

on small entities, unless the agency 

determines that a rule is not expected to 

have a significant impact on a 

substantial number of small entities. 

This final rule facilitates the 

transportation of hazardous materials in 

international commerce by providing 

consistency with international 

standards. This final rule applies to 

offerors and carriers of hazardous 

materials, some of whom are small 

entities, such as chemical users and 

suppliers, packaging manufacturers, 

distributors, battery manufacturers, and 

76060 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

training companies. As discussed above, 

under Executive Order 12866, the 

majority of amendments in this final 

rule should result in cost savings and 

ease the regulatory compliance burden 

for shippers engaged in domestic and 

international commerce, including 

trans-border shipments within North 

America. 

Many companies will realize 

economic benefits as a result of these 

amendments. Additionally, the changes 

brought forth by this final rule will 

relive U.S. companies, including small 

entities competing in foreign markets, 

from the burden of complying with a 

dual system of regulations. Therefore, I 

certify that these amendments will not, 

if promulgated, have a significant 

economic impact on a substantial 

number of small entities. 

This final rule has been developed in 

accordance with Executive Order 13272 

(‘‘Proper Consideration of Small Entities 

in Agency Rulemaking’’) and DOT’s 

procedures and policies to promote 

compliance with the Regulatory 

Flexibility Act to ensure that potential 

impacts of draft rules on small entities 

are properly considered. 

F. Paperwork Reduction Act 

Under the Paperwork Reduction Act 

of 1995, no person is required to 

respond to a collection of information 

unless it displays a valid Office of 

Management and Budget (OMB) control 

number. Section 1320.8(d), Title 5, Code 

of Federal Regulations requires that 

RSPA provide interested members of the 

public and affected agencies an 

opportunity to comment on information 

collection and recordkeeping requests. 

RSPA currently has two approved 

information collections affecting this 

final rule: OMB Control Number 2137–

0557, ‘‘Approvals for Hazardous 

Materials’’ with 25,605 burden hours 

and $562,837.40 burden costs; and OMB 

Control Number 2137–0613, 

‘‘Subsidiary Hazard Class & Number/

Type of Packagings’’ with 63,309 burden 

hours and $216,705 burden costs. 

There are minor editorial changes 

under this rule. However, there is no net 

increase in burden for OMB Control 

Number 2137–0557 or OMB Control 

Number 2137–0613. We estimate that 

the total information collection and 

recordkeeping burden as follows: 

‘‘Approvals for Hazardous Materials’’

OMB Number 2137–0557: 

Total Annual Number of 

Respondents: 3,523. 

Total Annual Responses: 3,874.8. 

Total Annual Burden Hours: 25,605. 

Total Annual Burden Cost:

$562,837.40. 

‘‘Subsidiary Hazard Class & Number/

Type of Packagings’’

OMB Number 2137–0613: 

Total Annual Number of 

Respondents: 250,000. 

Total Annual Responses: 6,337,500. 

Total Annual Burden Hours: 17,604. 

Total Annual Burden Cost: $216,705. 

Total First Year Burden Hours:

45,705. 

Total First Year Burden Cost:

$1,115,992. 

Requests for a copy of this 

information collection should be 

directed to Deborah Boothe or T. Glenn 

Foster, Office of Hazardous Materials 

Standards (DHM–10), Research and 

Special Programs Administration, Room 

8422, 400 Seventh Street, SW., 

Washington, DC 20590–0001, telephone 

(202) 366–8553. 

G. Regulatory Identifier Number (RIN) 

A regulation identifier number (RIN) 

is assigned to each regulatory action 

listed in the Unified Agenda of Federal 

Regulations. The Regulatory Information 

Service Center publishes the Unified 

Agenda in April and October of each 

year. The RIN contained in the heading 

of this document can be used to crossreference this action with the Unified 

Agenda.

H. Unfunded Mandates Reform Act 

This final rule does not impose 

unfunded mandates under the 

Unfunded Mandates Reform Act of 

1995. It does not result in costs of 

$120.7 million or more to either State, 

local or tribal governments, in the 

aggregate, or to the private sector, and 

is the least burdensome alternative that 

achieves the objective of the rule. 

I. Environmental Assessment 

The National Environmental Policy 

Act of 1969 (NEPA) requires Federal 

agencies to consider the consequences 

of major Federal actions and prepare a 

detailed statement on actions 

significantly affecting the quality of the 

human environment. We developed an 

assessment to determine the effects of 

these revisions on the environment and 

whether a more comprehensive 

environmental impact statement may be 

required. Our findings conclude that 

there are no significant environmental 

impacts associated with this final rule. 

Consistency in the regulations for the 

transportation of hazardous materials 

aids in the shipper’s understanding of 

what is required and permits shippers to 

more easily comply with safety 

regulations and avoid the potential for 

environmental damage or 

contamination. For interested parties, an 

environmental assessment is available 

in the public docket. 

J. Privacy Act 

Anyone is able to search the 

electronic form of any written 

communications and comments 

received into any of our dockets by the 

name of the individual submitting the 

document (or signing the document, if 

submitted on behalf of an association, 

business, labor union, etc.). You may 

review DOT’s complete Privacy Act 

Statement in the Federal Register

published on April 11, 2000 (Volume 

65, Number 70; Pages 19477–78) or you 

may visit http://dms.dot.gov.

List of Subjects 

49 CFR Part 171 

Exports, Hazardous materials 

transportation, Hazardous waste, 

Imports, Incorporation by reference, 

Reporting and recordkeeping 

requirements. 

49 CFR Part 172 

Education, Hazardous materials 

transportation, Hazardous waste, 

Incorporation by reference, Labeling, 

Markings, Packaging and containers, 

Reporting and recordkeeping 

requirements. 

49 CFR Part 173 

Hazardous materials transportation, 

Incorporation by reference, Packaging 

and containers, Radioactive materials, 

Reporting and recordkeeping 

requirements, Uranium. 

49 CFR Part 175 

Air carriers, Hazardous materials 

transportation, Incorporation by 

reference, Radioactive materials, 

Reporting and recordkeeping 

requirements. 

49 CFR Part 176 

Hazardous materials transportation, 

Incorporation by reference, Maritime 

carriers, Radioactive materials, 

Reporting and recordkeeping 

requirements. 

49 CFR Part 178 

Hazardous materials transportation, 

Incorporation by reference, Motor 

vehicle safety, Packaging and 

containers, Reporting and recordkeeping 

requirements. 

49 CFR Part 180 

Hazardous materials transportation, 

Motor carriers, Motor vehicle safety, 

Packaging and containers, Railroad 

safety, Reporting and recordkeeping 

requirements.

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76061

■ In consideration of the foregoing, 49 

CFR Chapter I is amended as follows:

PART 171—GENERAL INFORMATION, 

REGULATIONS, AND DEFINITIONS

■ 1. The authority citation for part 171 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127, 44701; 49 

CFR 1.45 and 1.53; Pub. L. 101–410 section 

4 (28 U.S.C. 2461 note); Pub. L. 104–134 

section 31001.

■ 2. In § 171.7, in the paragraph (a)(3) 

table, the following changes are made:

■ a. Under the entry ‘‘International Civil 

Aviation Organization (ICAO),’’ the 

existing entry is revised;

■ b. Under the entry ‘‘International 

Maritime Organization (IMO),’’ the entry 

‘‘International Maritime Dangerous 

Goods (IMDG) Code, 2002 Consolidated 

Edition, as amended by Amendment 31 

(English edition)’’ is removed and one 

entry is added in its place;

■ c. Under the entry ‘‘United Nations,’’

the entry ‘‘UN Recommendations on the 

Transport of Dangerous Goods, Twelfth 

Revised Edition (2001)’’ is revised;

■ d. Under the entry ‘‘United Nations,’’

the entry ‘‘UN Recommendations on the 

Transport of Dangerous Goods, Manual 

of Tests and Criteria, Third Revised 

Edition (1999)’’ is revised; and

■ e. In paragraph (b), a new entry 

‘‘American Institute of Chemical 

Engineers (AIChE),’’ 3 Park Avenue New 

York, NY 10016–5991, Process Safety 

Progress Journal, Vol. 21, No. 2, 

‘‘Example of a Test Method for Venting 

Sizing: OPPSD/SPI Methodology’’ is 

added in alphabetical order. 

The revisions and additions read as 

follows:

§ 171.7 Reference material. 

(a) * * * 

(3) Table of material incorporated by 

reference. * * *

Source and name of material 49 CFR reference 

* * * * * * * 

International Civil Aviation Organization (ICAO), 

* * * * * * * 

Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), 2005–2006 Edition ........................................................................................................................................................................................ 171.8; 171.11; 

172.202; 172.401; 

172.512; 172.602; 

173.320; 175.33; 

178.3. 

International Maritime Organization (IMO), 

* * * * * * * 

International Maritime Dangerous Goods Code (IMDG Code), 2004 Edition, Incorporating Amendment 32–04 (English 

Edition), Volumes 1 and 2 ................................................................................................................................................... 171.12; 172.202; 

172.401; 172.502; 

172.602; 173.21; 

176.2; 176.5; 176.11; 

176.27; 176.30; 

178.3. 

* * * * * * * 

United Nations, 

* * * * * * * 

UN Recommendations on the Transport of Dangerous Goods, Thirteenth Revised Edition (2003), Volumes I and II ......... 171.12; 172.202; 

172.401; 172.502; 

173.22; 173.24; 

173.24b; 173.197; 

Part 173, appendix H; 

178.274; 178.801. 

UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Fourth Revised Edition, 

(2003) ................................................................................................................................................................................... 172.102; 173.21; 

173.56; 173.57; 

173.58; 173.115; 

173.124; 173.125; 

173.127; 173.128; 

173.185. 

* * * * * * * 

(b) List of informational materials not 

requiring incorporation by reference.

***

Source and name of material 49 CFR reference 

* * * * * * * 

American Institute of Chemical Engineers (AIChE), 

76062 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

Source and name of material 49 CFR reference 

3 Park Avenue New York, NY 10016–5991 

Process Safety Progress Journal, Vol. 21, No. 2 

Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology ............................................................................. Note to § 173. 

225(h)(3)(vi). 

* * * * * * * 

■ 3. In § 171.8, the definition for 

‘‘Salvage packaging’’ is revised to read as 

follows:

§ 171.8 Definitions and abbreviations.

* * * * *

Salvage packaging means a special 

packaging conforming to § 173.3 of this 

subchapter into which damaged, 

defective, leaking, or non-conforming 

hazardous materials packages, or 

hazardous materials that have spilled or 

leaked, are placed for purposes of 

transport for recovery or disposal.

* * * * *

■ 4. In § 171.11, paragraphs (d)(15) and 

(d)(17) are revised to read as follows:

§ 171.11 Use of ICAO Technical 

Instructions.

* * * * *

(d) * * * 

(15) A chemical oxygen generator, 

including when fitted in protective 

breathing equipment or other apparatus, 

is forbidden for transportation aboard a 

passenger-carrying aircraft and must be 

approved, classed, described and 

packaged in accordance with the 

requirements of this subchapter for 

transportation on cargo-only aircraft. A 

chemical oxygen generator that has been 

used or spent is also forbidden for 

transportation on a passenger aircraft 

and cargo aircraft only.

* * * * *

(17) A self-reactive substance that is 

not identified by technical name in the 

Self-reactive Materials Table in 

§ 173.224(b) of this subchapter must be 

approved by the Associate 

Administrator in accordance with the 

requirements of § 173.124(a)(2)(iii) of 

this subchapter. An organic peroxide 

that is not identified by a technical 

name in any of the organic peroxide 

tables found in § 173.225 of this 

subchapter must be approved by the 

Associate Administrator in accordance 

with the requirements of § 173.128(d) of 

this subchapter.

■ 5. In § 171.12, paragraph (b)(20) is 

revised to read as follows:

§ 171.12 Import and export shipments.

* * * * *

(b) * * * 

(20) A self-reactive substance that is 

not identified by technical name in the 

Self-Reactive Materials Table in 

§ 173.224(b) of this subchapter must be 

approved by the Associate 

Administrator in accordance with the 

requirements of § 173.124(a)(2)(iii) of 

this subchapter. An organic peroxide 

that is not identified by a technical 

name in any of the organic peroxide 

tables found in § 173.225 of this 

subchapter must be approved by the 

Associate Administrator in accordance 

with the requirements of § 173.128(d) of 

this subchapter.

* * * * *

■ 6. In § 171.12a, paragraphs (a), (b)(9), 

and (b)(18) are revised to read as follows:

§ 171.12a Canadian shipments and 

packagings. 

(a) Scope and applicability. This 

section sets forth provisions for the 

transportation by rail or highway of 

shipments of hazardous materials which 

conform to the regulations of the 

Government of Canada but which may 

differ from the requirements of this 

subchapter with regard to hazard 

communication, classification or 

packaging. Except as provided in 

paragraph (b)(5)(iv) of this section, the 

provisions apply only to shipments 

which originate in Canada and either 

terminate in the U.S. or transit the U.S. 

to a Canadian or foreign destination, 

and to the return to Canada of bulk 

packagings that meet the requirements 

of a DOT or UN Specification and other 

bulk packagings containing only 

residues of hazardous materials that 

were originally imported into the U.S. 

Reciprocal provisions, applicable to 

exports from the U.S., appear in the 

regulations of the Government of 

Canada. 

(b) * * * 

(9) For hazardous waste as defined in 

this subchapter—

(i) The word ‘‘Waste’’ must precede 

the proper shipping name on shipping 

papers and packages; and 

(ii) The requirements of § 172.204 of 

this subchapter with respect to the 

shipper’s certification and § 172.205 of 

this subchapter with respect to 

hazardous waste manifests are 

applicable;

* * * * *

(18) A self-reactive substance that is 

not identified by technical name in the 

Self-reactive Materials Table in 

§ 173.224(b) of this subchapter must be 

approved by the Associate 

Administrator in accordance with the 

requirements of § 173.124(a)(2)(iii) of 

this subchapter. An organic peroxide 

that is not identified by a technical 

name in any of the organic peroxide 

tables found in § 173.225 of this 

subchapter must be approved by the 

Associate Administrator in accordance 

with the requirements of § 173.128(d) of 

this subchapter.

* * * * *

■ 7. In § 171.14, paragraphs (d) 

introductory text, (d)(1), and (d)(2) are 

revised to read as follows:

§ 171.14 Transitional provisions for 

implementing certain requirements.

* * * * *

(d) A final rule published in the 

Federal Register on December 20, 2004, 

effective January 1, 2005, resulted in 

revisions to this subchapter. During the 

transition period, until January 1, 2006, 

as provided in paragraph (d)(1) of this 

section, a person may elect to comply 

with either the applicable requirements 

of this subchapter in effect on December 

31, 2004, or the requirements published 

in the December 20, 2004, final rule. 

(1) Transition dates. The effective 

date of the final rule published on 

December 20, 2004, is January 1, 2005. 

A delayed compliance date of January 1, 

2006 is authorized. On and after January 

1, 2006, all applicable regulatory 

requirements adopted in the final rule 

in effect on January 1, 2005 must be 

met. 

(2) Intermixing old and new 

requirements. Marking, labeling, 

placarding, and shipping paper 

descriptions must conform to either the 

old requirements of this subchapter in 

effect on December 31, 2004, or the new 

requirements of this subchapter in the 

final rule without intermixing 

communication elements, except that 

intermixing is permitted, during the 

applicable transition period, for 

packaging, hazard communication, and 

handling provisions, as follows:

* * * * *

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76063

PART 172—HAZARDOUS MATERIALS 

TABLE, SPECIAL PROVISIONS, 

HAZARDOUS MATERIALS 

COMMUNICATIONS, EMERGENCY 

RESPONSE INFORMATION, AND 

TRAINING REQUIREMENTS

■ 8. The authority citation for part 172 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127; 49 CFR 

1.53.

■ 9. In § 172.101, the following 

amendments are made:

■ a. Paragraph (c)(11) is revised;

■ b. Paragraph (d)(4) is revised;

■ c. Paragraph (i)(3) is revised;

■ d. Hazardous Materials Table is 

revised as set forth below:

§ 172.101 Purpose and use of hazardous 

materials table.

* * * * *

(c) * * * 

(11) Except for a material subject to or 

prohibited by § 173.21, 173.54, 

173.56(d), 173.56(e), 173.224(c) or 

173.225(b) of this subchapter, a material 

that is considered to be a hazardous 

waste or a sample of a material for 

which the hazard class is uncertain and 

must be determined by testing may be 

assigned a tentative proper shipping 

name, hazard class, identification 

number and packing group, if 

applicable, based on the shipper’s 

tentative determination according to: 

(i) Defining criteria in this subchapter; 

(ii) The hazard precedence prescribed 

in § 173.2a of this subchapter; 

(iii) The shipper’s knowledge of the 

material; 

(iv) In addition to paragraphs (c)(11)(i) 

through (iii) of this section, for a sample 

of a material other than a waste, the 

following must be met: 

(A) Except when the word ‘‘Sample’’

already appears in the proper shipping 

name, the word ‘‘Sample’’ must appear 

as part of the proper shipping name or 

in association with the basic description 

on the shipping paper. 

(B) When the proper shipping 

description for a sample is assigned a 

‘‘G’’ in Column (1) of the § 172.101 

Table, and the primary constituent(s) for 

which the tentative classification is 

based are not known, the provisions 

requiring a technical name for the 

constituent(s) do not apply; and 

(C) A sample must be transported in 

a combination packaging that conforms 

to the requirements of this subchapter 

that are applicable to the tentative 

packing group assigned, and may not 

exceed a net mass of 2.5 kg (5.5 pounds) 

per package. 

Note to Paragraph (c)(11): For the 

transportation of self-reactive, organic 

peroxide and explosive samples, see 

§§ 173.224(c)(3), 173.225(b)(2) and 

173.56(d) of this subchapter, 

respectively.

* * * * *

(d) * * * 

(4) When an entry in this column 

reads ‘‘Comb liq’’, the material is 

assigned to the hazard class 

‘‘Combustible liquid.’’ Additionally, 

each reference to a Class 3 material is 

modified to read ‘‘Combustible liquid’’

when that material is reclassified in 

accordance with § 173.150 (e) or (f) of 

this subchapter or has a flash point 

above 60.5 °C (141 °F) but below 93 °C 

(200 °F).

* * * * *

(i) * * * 

(3) Bulk packaging. Column 8C 

specifies the section in part 173 of this 

subchapter that prescribes packaging 

requirements for bulk packagings, 

subject to the limitations, requirements 

and additional authorizations of 

Column 7. A ‘‘None’’ in this column 

means bulk packagings are not 

authorized, except as may be provided 

by special provisions in Column 7. 

Additional authorizations and 

limitations for use of UN portable tanks 

are set forth in Column 7. For each 

reference in this column to a material 

that is a hazardous waste or a hazardous 

substance, and whose proper shipping 

name is preceded in Column 1 of the 

Table by the letter ‘‘A’’ or ‘‘W’’ and that 

is offered for transportation or 

transported by a mode in which its 

transportation is not otherwise subject 

to the requirements of this subchapter:

* * * * *

BILLING CODE 4910–60–P

76064 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Accellerene, see p-Nitrosodimethylaniline ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Accumulators, electric, see Batteries, wet etc ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Accumulators, pressurized, pneumatic or hydraulic (containing non-flamable gas), see Articles 

pressurized, pneumatic or hydraulic (containing non-flamable gas).

.................... ........... .......... .......... .......... .................... .................... ............

Acetal ............................................................................................................................................... 3 UN1088 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Acetaldehyde ................................................................................................................................... 3 UN1089 I 3 ........ A3, B16, T11, 

TP2, TP7

None .... 201 ...... 243 ...... Forbidden 30 L E ............

A Acetaldehyde ammonia ................................................................................................................... 9 UN1841 III 9 ........ IB8, IP3, IP7, T1, 

TP33

155 ...... 204 ...... 240 ...... 200 kg 200 kg A 34

Acetaldehyde oxime ........................................................................................................................ 3 UN2332 III 3 ........ B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass .................. 8 UN2789 II 8, 3 .... A3, A6, A7, A10, 

B2, IB2, T7, TP2

154 ...... 202 ...... 243 ...... 1 L 30 L A ............

Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by mass ........ 8 UN2790 II 8 ........ A3, A6, A7, A10, 

B2, IB2, T7, TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Acetic acid solution, with more than 10 percent and less than 50 percent acid, by mass ............ 8 UN2790 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 242 ...... 5 L 60 L A ............Acetic anhydride .............................................................................................................................. 8 UN1715 II 8, 3 .... A3, A6, A7, A10, 

B2, IB2, T7, TP2

154 ...... 202 ...... 243 ...... 1 L 30 L A 40

Acetone ........................................................................................................................................... 3 UN1090 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Acetone cyanohydrin, stabilized ...................................................................................................... 6.1 UN1541 I 6.1 ..... 2, B9, B14, B32, 

B76, B77, N34, 

T20, TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 25, 40, 

52, 53

Acetone oils ..................................................................................................................................... 3 UN1091 II 3 ........ IB2, T4, TP1, 

TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

Acetonitrile ....................................................................................................................................... 3 UN1648 II 3 ........ IB2, T7, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Acetyl acetone peroxide with more than 9 percent by mass active oxygen .................................. Forbidden ........... .......... .......... .......... .................... .................... ............Acetyl benzoyl peroxide, solid, or with more than 40 percent in solution ...................................... Forbidden ........... .......... .......... .......... .................... .................... ............Acetyl bromide ................................................................................................................................. 8 UN1716 II 8 ........ B2, IB2, T8, TP2, 

TP12

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Acetyl chloride ................................................................................................................................. 3 UN1717 II 3, 8 .... A3, A6, A7, IB1, 

N34, T8, TP2, 

TP12

150 ...... 202 ...... 243 ...... 1 L 5 L B 40

Acetyl cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent water. Forbidden ........... .......... .......... .......... .................... .................... ............Acetyl iodide .................................................................................................................................... 8 UN1898 II 8 ........ B2, IB2, T7, TP2, 

TP13

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Acetyl methyl carbinol ..................................................................................................................... 3 UN2621 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Acetyl peroxide, solid, or with more than 25 percent in solution .................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Acetylene, dissolved ........................................................................................................................ 2.1 UN1001 ............ 2.1 ..... None .... 303 ...... None .... Forbidden 15 kg D 25, 40, 

57

Acetylene (liquefied) ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Acetylene silver nitrate .................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Acetylene tetrabromide, see Tetrabromoethane ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Acid butyl phosphate, see Butyl acid phosphate ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Acid, sludge, see Sludge acid ......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Acridine ............................................................................................................................................ 6.1 UN2713 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Acrolein dimer, stabilized ................................................................................................................ 3 UN2607 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40Acrolein, stabilized .......................................................................................................................... 6.1 UN1092 I 6.1, 3 1, B9, B14, B30, 

B42, B72, B77, 

T22, TP2, TP7, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Acrylamide, solid ............................................................................................................................. 6.1 UN2074 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 12

Acrylamide solution ......................................................................................................................... 6.1 UN3426 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 12Acrylic acid, stabilized ..................................................................................................................... 8 UN2218 II 8, 3 .... B2, IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L C 25, 40Acrylonitrile, stabilized ..................................................................................................................... 3 UN1093 I 3, 6.1 B9, T14, TP2, 

TP13

None .... 201 ...... 243 ...... Forbidden 30 L E 40

Actuating cartridge, explosive, see Cartridges, power device ........................................................ .................... ........... .......... .......... .......... .................... .................... ............Adhesives, containing a flammable liquid ....................................................................................... 3 UN1133 I 3 ........ B42, T11, TP1, 

TP8, TP27

150 ...... 201 ...... 143 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... II 3 ........ 149, B52, IB2, 

T4, TP1, TP8

150 ...... 173 ...... 242 ...... 5 L 60 L B ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76065

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T2, 

TP1

150 ...... 173 ...... 242 ...... 60 L 220 L A ............

Adiponitrile ....................................................................................................................................... 6.1 UN2205 III 6.1 ..... IB3, T3, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Aerosols, corrosive, Packing Group II or III, (each not exceeding 1 L capacity) ........................... 2.2 UN1950 ............ 2.2, 8 153, A34 306 ...... None .... None .... 75 kg 150 kg A 48, 87, 

126

Aerosols, flammable, (each not exceeding 1 L capacity) ............................................................... 2.1 UN1950 ............ 2.1 ..... 153, N82 306 ...... None .... None .... 75 kg 150 kg A 48, 87, 

126

Aerosols, flammable, n.o.s. (engine starting fluid) (each not exceeding 1 L capacity) .................. 2.1 UN1950 ............ 2.1 ..... 153, N82 306 ...... 304 ...... None .... Forbidden 150 kg A 48, 87, 

126

Aerosols, non-flammable, (each not exceeding 1 L capacity) ........................................................ 2.2 UN1950 ............ 2.2 ..... 153 306 ...... None .... None .... 75 kg 150 kg A 48, 87, 

126

Aerosols, poison, each not exceeding 1 L capacity ....................................................................... 2.2 UN1950 ............ 2.2, 

6.1.

153 306 ...... None .... None .... Forbidden Forbidden A 48, 87, 

126

I Air bag inflators, or Air bag modules, or Seat-belt pretensioners. ................................................. 1.4G UN0503 II 1.4G .. 161 None .... 62 ........ None .... Forbidden 75 kg 02 ............

Air bag inflators, or Air bag modules, or Seat-belt pretensioners. ................................................. 9 UN3268 III 9 ........ 160 166 ...... 166 ...... 166 ...... 25 kg 100 kg A ............Air, compressed .............................................................................................................................. 2.2 UN1002 ............ 2.2 ..... 78 306 ...... 302 ...... 302 ...... 75 kg 150 kg A ............Air, refrigerated liquid, (cryogenic liquid) ........................................................................................ 2.2 UN1003 ............ 2.2, 

5.1.

T75, TP5, TP22 320 ...... 316 ...... 318, 

319.

Forbidden 150 kg D 51

Air, refrigerated liquid, (cryogenic liquid) non-pressurized ............................................................. 2.2 UN1003 ............ 2.2, 

5.1.

T75, TP5, TP22 320 ...... 316 ...... 318, 

319.

Forbidden Forbidden D 51

Aircraft engines (including turbines), see Engines, internal combustion ........................................ .................... ........... .......... .......... .......... .................... .................... ............Aircraft evacuation slides, see Life saving appliances etc ............................................................. .................... ........... .......... .......... .......... .................... .................... ............Aircraft hydraulic power unit fuel tank (containing a mixture of anhydrous hydrazine and 

monomethyl hydrazine) (M86 fuel).

3 UN3165 I 3, 6.1, 

8.

None .... 172 ...... None .... Forbidden 42 L E ............

Aircraft survival kits, see Life saving appliances etc ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............

G Alcoholates solution, n.o.s., in alcohol ............................................................................................ 3 UN3274 II 3, 8 .... IB2 150 ...... 202 ...... 243 ...... 1 L 5 L B ............

Alcoholic beverages ........................................................................................................................ 3 UN3065 II 3 ........ 24, 149, B1, IB2, 

T4, TP1

150 ...... 202 ...... 242 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 3 ........ 24, B1, IB3, N11, 

T2, TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Alcohols, n.o.s. ................................................................................................................................ 3 UN1987 I 3 ........ T11, TP1, TP8, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Alcohols, flammable, toxic, n.o.s. .................................................................................................... 3 UN1986 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L E 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

.......................................................................................................................................................... .................... III 3, 6.1 B1, IB3, T7, TP1, 

TP28

None .... 203 ...... 242 ...... 60 L 220 L A ............

Aldehydes, n.o.s. ............................................................................................................................. 3 UN1989 I 3 ........ T11, TP1, TP27 None .... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Aldehydes, flammable, toxic, n.o.s. ................................................................................................ 3 UN1988 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L E 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

.......................................................................................................................................................... .................... III 3, 6.1 B1, IB3, T7, TP1, 

TP28

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Aldol ................................................................................................................................................. 6.1 UN2839 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 12

G Alkali metal alcoholates, self-heating, corrosive, n.o.s. .................................................................. 4.2 UN3206 II 4.2, 8 64, A7, IB5, IP2, 

T3, TP33

None .... 212 ...... 242 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 4.2, 8 64, A7, IB8, IP3, 

T1, TP33

None .... 213 ...... 242 ...... 25 kg 100 kg B ............

Alkali metal alloys, liquid, n.o.s. ...................................................................................................... 4.3 UN1421 I 4.3 ..... A2, A3, A7, B48, 

N34

None .... 201 ...... 244 ...... Forbidden 1 L D 52

Alkali metal amalgam, liquid ........................................................................................................... 4.3 UN1389 I 4.3 ..... A2, A3, A7, N34 None .... 201 ...... 244 ...... Forbidden 1 L D 40, 52Alkali metal amalgam, solid ............................................................................................................ 4.3 UN3401 I 4.3 ..... IB4, IP1, N40, 

T9, TP7, TP33

None .... 211 ...... 242 ...... Forbidden 15 kg D 52

Alkali metal amides ......................................................................................................................... 4.3 UN1390 II 4.3 ..... A6, A7, A8, A19, 

A20, IB7, IP2, 

T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg E 40, 52

Alkali metal dispersions, or Alkaline earth metal dispersions ......................................................... 4.3 UN1391 I 4.3 ..... A2, A3, A7 None .... 201 ...... 244 ...... Forbidden 1 L D 52Alkaline corrosive liquids, n.o.s., see Caustic alkali liquids, n.o.s. ................................................. .................... ........... .......... .......... .......... .................... .................... ............

G Alkaline earth metal alcoholates, n.o.s. .......................................................................................... 4.2 UN3205 II 4.2 ..... 65, A7, IB6, IP2, 

T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 4.2 ..... 65, A7, IB8, IP3, 

T1, TP33

None .... 213 ...... 241 ...... 25 kg 100 kg B ............

Alkaline earth metal alloys, n.o.s. ................................................................................................... 4.3 UN1393 II 4.3 ..... A19, IB7, IP2, 

T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg E 52

Alkaline earth metal amalgams, liquid ............................................................................................ 4.3 UN1392 I 4.3 ..... A19, N34, N40 None .... 201 ...... 244 ...... Forbidden 1 L E 40, 52

76066 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Alkaline earth metal amalgams, solid ............................................................................................. 4.3 UN3402 I 4.3 ..... A19, N34, N40, 

T9, TP7, TP33

None .... 211 ...... 242 ...... Forbidden 15 kg D 52

G Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. ................................................................... 6.1 UN3140 I 6.1 ..... A4, T14, TP2, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

G Alkaloids, solid, n.o.s. [or] Alkaloid salts, solid, n.o.s. [poisonous] ................................................. 6.1 UN1544 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric 

acid.

8 UN2584 II 8 ........ B2, IB2, T8, TP2, 

TP12, TP13

154 ...... 202 ...... 242 ...... 1 L 30 L B ............

Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric 

acid.

8 UN2586 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L B ............

Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric 

acid.

8 UN2583 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric 

acid.

8 UN2585 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) ........................................................... 8 UN3145 I 8 ........ A6, T14, TP2 None .... 201 ...... 243 ...... 0.5 L 2.5 L B ............

.......................................................................................................................................................... .................... II 8 ........ IB2, T11, TP2, 

TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Alkylphenols, solid, n.o.s. (including C2-C12 homologues) ............................................................ 8 UN2430 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg B ............

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Alkylsulfuric acids ............................................................................................................................ 8 UN2571 II 8 ........ B2, IB2, T8, TP2, 

TP12, TP13, 

TP28

154 ...... 202 ...... 242 ...... 1 L 30 L C 14

Allethrin, see Pesticides, liquid, toxic, n.o.s. ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Allyl acetate ..................................................................................................................................... 3 UN2333 II 3, 6.1 IB2, T7, TP1, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Allyl alcohol ..................................................................................................................................... 6.1 UN1098 I 6.1, 3 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Allyl bromide .................................................................................................................................... 3 UN1099 I 3, 6.1 T14, TP2, TP13 None .... 201 ...... 243 ...... Forbidden 30 L B 40Allyl chloride .................................................................................................................................... 3 UN1100 I 3, 6.1 T14, TP2, TP13 None .... 201 ...... 243 ...... Forbidden 30 L E 40Allyl chlorocarbonate, see Allyl chloroformate ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Allyl chloroformate ........................................................................................................................... 6.1 UN1722 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, N41, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Allyl ethyl ether ................................................................................................................................ 3 UN2335 II 3, 6.1 IB2, T7, TP1, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Allyl formate ..................................................................................................................................... 3 UN2336 I 3, 6.1 T14, TP2, TP13 None .... 201 ...... 243 ...... Forbidden 30 L E 40Allyl glycidyl ether ............................................................................................................................ 3 UN2219 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Allyl iodide ....................................................................................................................................... 3 UN1723 II 3, 8 .... A3, A6, IB1, 

N34, T7, TP2, 

TP13

150 ...... 202 ...... 243 ...... 1 L 5 L B 40

Allyl isothiocyanate, stabilized ......................................................................................................... 6.1 UN1545 II 6.1, 3 A3, A7, IB2, T7, 

TP2

None .... 202 ...... 243 ...... Forbidden 60 L D 40

Allylamine ........................................................................................................................................ 6.1 UN2334 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76067

Allyltrichlorosilane, stabilized ........................................................................................................... 8 UN1724 II 8, 3 .... A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 243 ...... Forbidden 30 L C 40

Aluminum alkyl halides, liquid ......................................................................................................... 4.2 UN3052 I 4.2, 

4.3.

B9, B11, T21, 

TP2, TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D 134

Aluminium alkyl halides, solid ......................................................................................................... 4.2 UN3461 I 4.2, 

4.3.

T21, TP7, TP33 None .... 181 ...... 244 ...... Forbidden Forbidden D 134

Aluminum alkyl hydrides ................................................................................................................. 4.2 UN3076 I 4.2, 

4.3.

B9, B11, T21, 

TP2, TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D ............

Aluminum alkyls .............................................................................................................................. 4.2 UN3051 I 4.2, 

4.3.

B9, B11, T21, 

TP2, TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D ............

Aluminum borohydride or Aluminum borohydride in devices ......................................................... 4.2 UN2870 I 4.2, 

4.3.

B11, T21, TP7, 

TP33

None .... 181 ...... 244 ...... Forbidden Forbidden D ............

Aluminum bromide, anhydrous ....................................................................................................... 8 UN1725 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 40

Aluminum bromide, solution ............................................................................................................ 8 UN2580 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Aluminum carbide ............................................................................................................................ 4.3 UN1394 II 4.3 ..... A20, IB7, IP2, 

N41, T3, TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg A 52

Aluminum chloride, anhydrous ........................................................................................................ 8 UN1726 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 40

Aluminum chloride, solution ............................................................................................................ 8 UN2581 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Aluminum dross, wet or hot ............................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Aluminum ferrosilicon powder ......................................................................................................... 4.3 UN1395 II 4.3, 

6.1.

A19, IB5, IP2, 

T3, TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg A 39, 40, 

52, 53, 

85, 103

.......................................................................................................................................................... .................... III 4.3, 

6.1.

A19, A20, IB4 151 ...... 213 ...... 241 ...... 25 kg 100 kg A 39, 40, 

52, 53, 

85, 103

Aluminum hydride ............................................................................................................................ 4.3 UN2463 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E ............

D Aluminum, molten ............................................................................................................................ 9 NA9260 III 9 ........ IB3, T1, TP3 None .... None .... 247 ...... Forbidden Forbidden D ............

Aluminum nitrate ............................................................................................................................. 5.1 UN1438 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Aluminum phosphate solution, see Corrosive liquids, etc .............................................................. .................... ........... .......... .......... .......... .................... .................... ............Aluminum phosphide ....................................................................................................................... 4.3 UN1397 I 4.3, 

6.1.

A8, A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 40, 52, 

85

Aluminum phosphide pesticides ...................................................................................................... 6.1 UN3048 I 6.1 ..... A8, IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... Forbidden 15 kg E 40, 85

Aluminum powder, coated ............................................................................................................... 4.1 UN1309 II 4.1 ..... IB8, IP2, IP4, T3, 

TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg A 13, 39, 

52, 53, 

74, 101

.......................................................................................................................................................... .................... III 4.1 ..... IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A 13, 39, 

52, 53, 

74, 101

Aluminum powder, uncoated ........................................................................................................... 4.3 UN1396 II 4.3 ..... A19, A20, IB7, 

IP2, T3, TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg A 39, 52, 

53

.......................................................................................................................................................... .................... III 4.3 ..... A19, A20, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg A 39, 52, 

53

Aluminum resinate ........................................................................................................................... 4.1 UN2715 III 4.1 ..... IB6, T1, TP33 151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............Aluminum silicon powder, uncoated ............................................................................................... 4.3 UN1398 III 4.3 ..... A1, A19, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg A 39, 40, 

52, 53, 

85, 103

Aluminum smelting by-products or Aluminum remelting by-products ............................................ 4.3 UN3170 II 4.3 ..... 128, B115, IB7, 

IP2, T3, TP33

None .... 212 ...... 242 ...... 15 kg 50 kg B 85, 103

.......................................................................................................................................................... .................... III 4.3 ..... 128, B115, IB8, 

IP4, T1, TP33

None .... 213 ...... 241 ...... 25 kg 100 kg B 85, 103

Amatols, see Explosives, blasting, type B ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

G Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s. ....................... 3 UN2733 I 3, 8 .... T14, TP1, TP27 None .... 201 ...... 243 ...... 0.5 L 2.5 L D 40

.......................................................................................................................................................... .................... II 3, 8 .... IB2, T11, TP1, 

TP27

150 ...... 202 ...... 243 ...... 1 L 5 L B 40

.......................................................................................................................................................... .................... III 3, 8 .... B1, IB3, T7, TP1, 

TP28

150 ...... 203 ...... 242 ...... 5 L 60 L A 40

G Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s. .. 8 UN2734 I 8, 3 .... A3, A6, N34, 

T14, TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L A 52

.......................................................................................................................................................... .................... II 8, 3 .... IB2, T11, TP2, 

TP27

None .... 202 ...... 243 ...... 1 L 30 L A 52

G Amines, liquid, corrosive, n.o.s., or Polyamines, liquid, corrosive, n.o.s. ....................................... 8 UN2735 I 8 ........ A3, A6, B10, 

N34, T14, TP2, 

TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L A 52

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, T11, 

TP1, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L A 52

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 52

G Amines, solid, corrosive, n.o.s., or Polyamines, solid, corrosive n.o.s. .......................................... 8 UN3259 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg A 52

76068 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 52

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 52

2-Amino-4-chlorophenol .................................................................................................................. 6.1 UN2673 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

2-Amino-5-diethylaminopentane ...................................................................................................... 6.1 UN2946 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............2-Amino-4,6-Dinitrophenol, wetted with not less than 20 percent water by mass ......................... 4.1 UN3317 I 4.1 ..... 23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg E 28, 36

2-(2-Aminoethoxy) ethanol .............................................................................................................. 8 UN3055 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............N-Aminoethylpiperazine .................................................................................................................. 8 UN2815 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A 12

+ Aminophenols (o-; m-; p-) ............................................................................................................... 6.1 UN2512 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Aminopropyldiethanolamine, see Amines, etc ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............n-Aminopropylmorpholine, see Amines, etc ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Aminopyridines (o-; m-; p-) ............................................................................................................. 6.1 UN2671 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 12, 40

I Ammonia, anhydrous ...................................................................................................................... 2.3 UN1005 ............ 2.3, 8 4, T50 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 57

D Ammonia, anhydrous ...................................................................................................................... 2.2 UN1005 ............ 2.2 ..... 13, T50 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 57

D Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 

percent ammonia.

2.2 UN3318 ............ 2.2 ..... 13, T50 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 57

I Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 

percent ammonia.

2.3 UN3318 ............ 2.3, 8 4, T50 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 57

Ammonia solutions, relative density between 0.880 and 0.957 at 15 degrees C in water, with 

more than 10 percent but not more than 35 percent ammonia.

8 UN2672 III 8 ........ IB3, IP8, T7, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A 40, 85

Ammonia solutions, relative density less than 0.880 at 15 degrees C in water, with more than 

35 percent but not more than 50 percent ammonia.

2.2 UN2073 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40, 57

Ammonium arsenate ....................................................................................................................... 6.1 UN1546 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 53

Ammonium azide ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Ammonium bifluoride, solid, see Ammonium hydrogen difluoride, solid ........................................ .................... ........... .......... .......... .......... .................... .................... ............Ammonium bifluoride solution, see Ammonium hydrogen difluoride, solution ............................... .................... ........... .......... .......... .......... .................... .................... ............Ammonium bromate ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Ammonium chlorate ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Ammonium dichromate ................................................................................................................... 5.1 UN1439 II 5.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 52

Ammonium dinitro-o-cresolate, solid ............................................................................................... 6.1 UN1843 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 36, 65, 

66, 77

Ammonium dinitro-o-cresolate solution ........................................................................................... 6.1 UN3424 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L B 36, 66, 

78, 91

.......................................................................................................................................................... .................... III 6.1 ..... IB2, T7, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L A 36, 66, 

78, 91

Ammonium fluoride ......................................................................................................................... 6.1 UN2505 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Ammonium fluorosilicate ................................................................................................................. 6.1 UN2854 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Ammonium fulminate ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Ammonium hydrogen sulfate .......................................................................................................... 8 UN2506 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 40

Ammonium hydrogendifluoride, solid .............................................................................................. 8 UN1727 II 8 ........ IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 25, 40, 

52

Ammonium hydrogendifluoride, solution ......................................................................................... 8 UN2817 II 8, 6.1 IB2, N34, T8, 

TP2, TP12, TP13

154 ...... 202 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... III 8, 6.1 IB3, N3, T4, 

TP1, TP12, TP13

154 ...... 203 ...... 241 ...... 5 L 60 L B 40, 95

Ammonium hydrosulfide, solution, see Ammonium sulfide solution ............................................... .................... ........... .......... .......... .......... .................... .................... ............

D Ammonium hydroxide, see Ammonia solutions, etc ....................................................................... .................... ........... .......... .......... .......... .................... .................... ............

Ammonium metavanadate .............................................................................................................. 6.1 UN2859 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 44, 89, 

100, 

141

Ammonium nitrate based fertilizer .................................................................................................. 5.1 UN2067 III 5.1 ..... 52, 150, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg B 48, 59, 

60, 66, 

117

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76069

A W Ammonium nitrate based fertilizer .................................................................................................. 9 UN2071 III 9 ........ 132, IB8, IP3 155 ...... 213 ...... 240 ...... 200 kg 200 kg A ............

Ammonium nitrate emulsion or Ammonium nitrate suspension or Ammonium nitrate gel, intermediate for blasting explosives. 5.1 UN3375 II ........... 147, 163 None .... 214 ...... 214 ...... Forbidden Forbidden D 48, 59, 60, 66, 

124

D Ammonium nitrate-fuel oil mixture containing only prilled ammonium nitrate and fuel oil ............. 1.5D NA0331 II 1.5D .. None .... 62 ........ None .... Forbidden Forbidden 10 19E 

Ammonium nitrate, liquid (hot concentrated solution) .................................................................... 5.1 UN2426 ............ 5.1 ..... B5, T7 None .... None .... 243 ...... Forbidden Forbidden D 59, 60Ammonium nitrate, with more than 0.2 percent combustible substances, including any organic 

substance calculated as carbon, to the exclusion of any other added substance.

1.1D UN0222 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 19E 

Ammonium nitrate, with not more than 0.2% total combustible material, including any organic 

substance, calculated as carbon to the exclusion of any other added substance.

5.1 UN1942 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 48, 59, 

60, 116

Ammonium nitrite ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Ammonium perchlorate ................................................................................................................... 1.1D UN0402 II 1.1D .. 107 None .... 62 ........ None .... Forbidden Forbidden 10 19E Ammonium perchlorate ................................................................................................................... 5.1 UN1442 II 5.1 ..... 107, A9, IB6, 

IP2, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg E 58, 69

Ammonium permanganate .............................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Ammonium persulfate ..................................................................................................................... 5.1 UN1444 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Ammonium picrate, dry or wetted with less than 10 percent water, by mass ............................... 1.1D UN0004 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E, 

19E 

Ammonium picrate, wetted with not less than 10 percent water, by mass .................................... 4.1 UN1310 I 4.1 ..... 23, A2, N41 None .... 211 ...... None .... 0.5 kg 0.5 kg D 28, 36Ammonium polysulfide, solution ...................................................................................................... 8 UN2818 II 8, 6.1 IB2, T7, TP2, 

TP13

154 ...... 202 ...... 243 ...... 1 L 30 L B 12, 40, 

52

.......................................................................................................................................................... .................... III 8, 6.1 IB3, T4, TP1, 

TP13

154 ...... 203 ...... 241 ...... 5 L 60 L B 12, 40, 

52

Ammonium polyvanadate ................................................................................................................ 6.1 UN2861 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 44, 89, 

100, 

141

Ammonium silicofluoride, see Ammonium fluorosilicate ................................................................. .................... ........... .......... .......... .......... .................... .................... ............Ammonium sulfide solution ............................................................................................................. 8 UN2683 II 8, 6.1, 

3.

IB1, T7, TP2, 

TP13

154 ...... 202 ...... 243 ...... 1 L 30 L B 12, 22, 

52, 100

Ammunition, blank, see Cartridges for weapons, blank ................................................................. .................... ........... .......... .......... .......... .................... .................... ............Ammunition, illuminating with or without burster, expelling charge or propelling charge .............. 1.2G UN0171 II 1.2G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Ammunition, illuminating with or without burster, expelling charge or propelling charge .............. 1.3G UN0254 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Ammunition, illuminating with or without burster, expelling charge or propelling charge .............. 1.4G UN0297 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Ammunition, incendiary liquid or gel, with burster, expelling charge or propelling charge ............ 1.3J UN0247 II 1.3J ... .......... 62 ........ None .... Forbidden Forbidden 04 23E Ammunition, incendiary (water-activated contrivances) with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc.. .................... ........... .......... .......... .......... .................... .................... ............Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge 1.2H UN0243 II 1.2H .. .......... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 

15E, 

17E 

Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge 1.3H UN0244 II 1.3H .. .......... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 

15E, 

17E 

Ammunition, incendiary with or without burster, expelling charge, or propelling charge ............... 1.2G UN0009 II 1.2G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Ammunition, incendiary with or without burster, expelling charge, or propelling charge ............... 1.3G UN0010 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Ammunition, incendiary with or without burster, expelling charge or propelling charge ................ 1.4G UN0300 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Ammunition, practice ....................................................................................................................... 1.4G UN0362 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Ammunition, practice ....................................................................................................................... 1.3G UN0488 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Ammunition, proof ........................................................................................................................... 1.4G UN0363 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Ammunition, rocket, see Warheads, rocket etc .............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Ammunition, SA (small arms), see Cartridges for weapons, etc .................................................... .................... ........... .......... .......... .......... .................... .................... ............Ammunition, smoke (water-activated contrivances), white phosphorus, with burster, expelling 

charge or propelling charge, see Contrivances, water-activated, etc. (UN 0248).

.................... ........... .......... .......... .......... .................... .................... ............

Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides, 

with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. 

(UN 0249).

.................... ........... .......... .......... .......... .................... .................... ............

Ammunition smoke, white phosphorus with burster,expelling charge, or propelling charge ......... 1.2H UN0245 II 1.2H .. .......... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

Ammunition, smoke, white phosphorus with burster, expelling charge, or propelling charge ....... 1.3H UN0246 II 1.3H .. .......... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

Ammunition, smoke with or without burster, expelling charge or propelling charge ...................... 1.2G UN0015 II 1.2G .. .......... 62 ........ None .... Forbidden Forbidden 8E, 

17E, 

20E 

Ammunition, smoke with or without burster, expelling charge or propelling charge ...................... 1.3G UN0016 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 8E, 

17E, 

20E 

76070 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Ammunition, smoke with or without burster, expelling charge or propelling charge ...................... 1.4G UN0303 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 7E, 8E, 

14E, 15E, 

17E 

Ammunition, sporting, see Cartridges for weapons, etc. (UN 0012; UN 0328; UN 0339) ............. .................... ........... .......... .......... .......... .................... .................... ............Ammunition, tear-producing, non-explosive, without burster or expelling charge, non-fuzed ........ 6.1 UN2017 II 6.1, 8 None .... 212 ...... None .... Forbidden 50 kg E 13, 40Ammunition, tear-producing with burster, expelling charge or propelling charge .......................... 1.2G UN0018 II 1.2G, 

8, 6.1.

.......... 62 ........ None .... Forbidden Forbidden 8E, 

17E, 

20E 

Ammunition, tear-producing with burster, expelling charge or propelling charge .......................... 1.3G UN0019 II 1.3G, 

8, 6.1.

.......... 62 ........ None .... Forbidden Forbidden 8E, 

17E, 

20E 

Ammunition, tear-producing with burster, expelling charge or propelling charge .......................... 1.4G UN0301 II 1.4G, 

8, 6.1.

.......... 62 ........ None .... Forbidden 75 kg 7E, 8E, 

14E, 15E, 

17E 

Ammunition, toxic, non-explosive, without burster or expelling charge, non-fuzed ....................... 6.1 UN2016 II 6.1 ..... None .... 212 ...... None .... Forbidden 100 kg E 13, 40Ammunition, toxic (water-activated contrivances), with burster, expelling charge or propelling 

charge, see Contrivances, water-activated, etc.

.................... ........... .......... .......... .......... .................... .................... ............

G Ammunition, toxic with burster, expelling charge, or propelling charge ......................................... 1.2K UN0020 II 1.2K, 

6.1.

.......... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

G Ammunition, toxic with burster, expelling charge, or propelling charge ......................................... 1.3K UN0021 II 1.3K, 

6.1.

.......... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

Amyl acetates .................................................................................................................................. 3 UN1104 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Amyl acid phosphate ....................................................................................................................... 8 UN2819 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Amyl butyrates ................................................................................................................................. 3 UN2620 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Amyl chlorides ................................................................................................................................. 3 UN1107 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Amyl formates ................................................................................................................................. 3 UN1109 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Amyl mercaptans ............................................................................................................................. 3 UN1111 II 3 ........ A3, A6, IB2, T4, 

TP1

None .... 202 ...... 242 ...... 5 L 60 L B 95, 102

n-Amyl methyl ketone ...................................................................................................................... 3 UN1110 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Amyl nitrate ..................................................................................................................................... 3 UN1112 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40Amyl nitrites ..................................................................................................................................... 3 UN1113 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E 40Amylamines ..................................................................................................................................... 3 UN1106 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............

.......................................................................................................................................................... .................... III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A ............

Amyltrichlorosilane .......................................................................................................................... 8 UN1728 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Anhydrous ammonia, see Ammonia, anhydrous ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Anhydrous hydrofluoric acid, see Hydrogen fluoride, anhydrous ................................................... .................... ........... .......... .......... .......... .................... .................... ............

+ Aniline .............................................................................................................................................. 6.1 UN1547 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40, 52

Aniline hydrochloride ....................................................................................................................... 6.1 UN1548 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Aniline oil, see Aniline ..................................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Anisidines ........................................................................................................................................ 6.1 UN2431 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Anisole ............................................................................................................................................. 3 UN2222 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Anisoyl chloride ............................................................................................................................... 8 UN1729 II 8 ........ B2, B4, IB8, IP2, 

IP4, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Anti-freeze, liquid, see Flammable liquids, n.o.s. ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Antimonous chloride, see Antimony trichloride ............................................................................... .................... ........... .......... .......... .......... .................... .................... ............Antimony compounds, inorganic, liquid, n.o.s. ............................................................................... 6.1 UN3141 III 6.1 ..... 35, IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Antimony compounds, inorganic, solid, n.o.s. ................................................................................ 6.1 UN1549 III 6.1 ..... 35, IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Antimony lactate .............................................................................................................................. 6.1 UN1550 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Antimony pentachloride, liquid ........................................................................................................ 8 UN1730 II 8 ........ B2, IB2, T7, TP2 None .... 202 ...... 242 ...... 1 L 30 L C 40Antimony pentachloride, solutions .................................................................................................. 8 UN1731 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L C 40

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L C 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76071

Antimony pentafluoride .................................................................................................................... 8 UN1732 II 8, 6.1 A3, A6, A7, A10, 

IB2, N3, N36, 

T7, TP2

None .... 202 ...... 243 ...... Forbidden 30 L D 44, 89, 

100, 

141

Antimony potassium tartrate ........................................................................................................... 6.1 UN1551 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Antimony powder ............................................................................................................................. 6.1 UN2871 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Antimony sulfide and a chlorate, mixtures of .................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Antimony sulfide, solid, see Antimony compounds, inorganic, n.o.s. ............................................. .................... ........... .......... .......... .......... .................... .................... ............Antimony trichloride, liquid .............................................................................................................. 8 UN1733 II 8 ........ B2, IB2 154 ...... 202 ...... 242 ...... 1 L 30 L C 40Antimony trichloride, solid ............................................................................................................... 8 UN1733 II 8 ........ IB8, IP2, IP4 154 ...... 212 ...... 240 ...... 15 kg 50 kg A 40Aqua ammonia, see Ammonia solution, etc ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Argon, compressed ......................................................................................................................... 2.2 UN1006 ............ 2.2 ..... 306 ...... 302 ...... 314, 

315.

75 kg 150 kg A ............

Argon, refrigerated liquid (cryogenic liquid) .................................................................................... 2.2 UN1951 ............ 2.2 ..... T75, TP5 320 ...... 316 ...... 318 ...... 50 kg 500 kg B ............Arsenic ............................................................................................................................................. 6.1 UN1558 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Arsenic acid, liquid .......................................................................................................................... 6.1 UN1553 I 6.1 ..... T20, TP2, TP7, 

TP13

None .... 201 ...... 243 ...... 1 L 30 L B 46

Arsenic acid, solid ........................................................................................................................... 6.1 UN1554 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Arsenic bromide .............................................................................................................................. 6.1 UN1555 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 12, 40

Arsenic chloride, see Arsenic trichloride ......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.. 6.1 UN1556 I 6.1 ..... T14, TP2, TP13, TP27 None .... 201 ...... 243 ...... 1 L 30 L B 40, 137

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40, 137

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L B 40, 137

Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic 

sulfides, n.o.s.; and organic compounds of arsenic, n.o.s..

6.1 UN1557 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 137

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 137

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 137

Arsenic pentoxide ............................................................................................................................ 6.1 UN1559 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Arsenic sulfide and a chlorate, mixtures of ..................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Arsenic trichloride ............................................................................................................................ 6.1 UN1560 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden B 40

Arsenic trioxide ................................................................................................................................ 6.1 UN1561 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Arsenic, white, solid, see Arsenic trioxide ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Arsenical dust .................................................................................................................................. 6.1 UN1562 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ........................ 3 UN2760 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Arsenical pesticides, liquid, toxic .................................................................................................... 6.1 UN2994 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Arsenical pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C .................. 6.1 UN2993 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Arsenical pesticides, solid, toxic ..................................................................................................... 6.1 UN2759 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Arsenious acid, solid, see Arsenic trioxide ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Arsenious and mercuric iodide solution, see Arsenic compounds, liquid, n.o.s. ........................... .................... ........... .......... .......... .......... .................... .................... ............Arsine .............................................................................................................................................. 2.3 UN2188 ............ 2.3, 

2.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

Articles, explosive, extremely insensitive or Articles, EEI .............................................................. 1.6N UN0486 II 1.6N .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............

76072 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

G Articles, explosive, n.o.s. ................................................................................................................. 1.4S UN0349 II 1.4S ... 101 None .... 62 ........ None .... 25 kg 100 kg 05 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.4B UN0350 II 1.4B ... 101 None .... 62 ........ None .... Forbidden Forbidden 06 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.4C UN0351 II 1.4C .. 101 None .... 62 ........ None .... Forbidden 75 kg 06 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.4D UN0352 II 1.4D .. 101 None .... 62 ........ None .... Forbidden 75 kg 06 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.4G UN0353 II 1.4G .. 101 None .... 62 ........ None .... Forbidden 75 kg 06 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.1L UN0354 II 1.1L ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

G Articles, explosive, n.o.s. ................................................................................................................. 1.2L UN0355 II 1.2L ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

G Articles, explosive, n.o.s. ................................................................................................................. 1.3L UN0356 II 1.3L ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

G Articles, explosive, n.o.s. ................................................................................................................. 1.1C UN0462 II 1.1C .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.1D UN0463 II 1.1D .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.1E UN0464 II 1.1E ... 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.1F UN0465 II 1.1F ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.2C UN0466 II 1.2C .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.2D UN0467 II 1.2D .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.2E UN0468 II 1.2E ... 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.2F UN0469 II 1.2F ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.3C UN0470 II 1.3C .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.4E UN0471 II 1.4E ... 101 None .... 62 ........ None .... Forbidden 75 kg 06 ............G Articles, explosive, n.o.s. ................................................................................................................. 1.4F UN0472 II 1.4F ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 ............

Articles, pressurized pneumatic or hydraulic containing non-flammable gas ................................. 2.2 UN3164 ............ 2.2 ..... 306 ...... 302, 

304.

None .... No limit No limit A ............

Articles, pyrophoric .......................................................................................................................... 1.2L UN0380 II 1.2L ... None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 15E, 

17E 

Articles, pyrotechnic for technical purposes ................................................................................... 1.1G UN0428 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Articles, pyrotechnic for technical purposes ................................................................................... 1.2G UN0429 II 1.2G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Articles, pyrotechnic for technical purposes ................................................................................... 1.3G UN0430 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Articles, pyrotechnic for technical purposes ................................................................................... 1.4G UN0431 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Articles, pyrotechnic for technical purposes ................................................................................... 1.4S UN0432 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............

D Asbestos .......................................................................................................................................... 9 NA2212 III 9 ........ 156, IB8, IP2, 

IP4

155 ...... 216 ...... 240 ...... 200 kg 200 kg A 34, 40

Ascaridole (organic peroxide) ......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............

D Asphalt, at or above its flash point ................................................................................................. 3 NA1999 III 3 ........ IB3, T1, TP3 150 ...... 203 ...... 247 ...... Forbidden Forbidden D ............D Asphalt, cut back, see Tars, liquid, etc ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

Automobile, motorcycle, tractor, other self-propelled vehicle, engine, or other mechanical apparatus, see Vehicles or Battery etc. .................... ........... .......... .......... .......... .................... .................... ............

A G Aviation regulated liquid, n.o.s. ....................................................................................................... 9 UN3334 ............ 9 ........ A35 155 ...... 204 ...... .......... No limit No limit A ............A G Aviation regulated solid, n.o.s. ........................................................................................................ 9 UN3335 ............ 9 ........ A35 155 ...... 204 ...... .......... No limit No limit A ............

Azaurolic acid (salt of) (dry) ............................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Azido guanidine picrate (dry) .......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............5-Azido-1-hydroxy tetrazole ............................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Azido hydroxy tetrazole (mercury and silver salts) ......................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............3-Azido-1,2-Propylene glycol dinitrate ............................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Azidodithiocarbonic acid .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Azidoethyl nitrate ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............1-Aziridinylphosphine oxide-(tris), see Tris-(1-aziridinyl) phosphine oxide, solution ...................... .................... ........... .......... .......... .......... .................... .................... ............Azodicarbonamide ........................................................................................................................... 4.1 UN3242 II 4.1 ..... 38, IB8, T3, 

TP33

151 ...... 212 ...... 240 ...... Forbidden Forbidden D 12, 52, 

53, 74

Azotetrazole (dry) ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Barium ............................................................................................................................................. 4.3 UN1400 II 4.3 ..... A19, IB7, IP2, 

T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg E 52

Barium alloys, pyrophoric ................................................................................................................ 4.2 UN1854 I 4.2 ..... T21, TP7, TP33 None .... 181 ...... None .... Forbidden Forbidden D ............Barium azide, dry or wetted with less than 50 percent water, by mass ........................................ 1.1A UN0224 II 1.1A, 

6.1.

111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76073

Barium azide, wetted with not less than 50 percent water, by mass ............................................. 4.1 UN1571 I 4.1, 

6.1.

162, A2 None .... 182 ...... None .... Forbidden 0.5 kg D 28

Barium bromate ............................................................................................................................... 5.1 UN2719 II 5.1, 

6.1.

IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Barium chlorate, solid ...................................................................................................................... 5.1 UN1445 II 5.1, 

6.1.

A9, IB6, IP2, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Barium chlorate, solution ................................................................................................................. 5.1 UN3405 II 5.1, 

6.1.

A9, IB2, N34, T4, 

TP1

152 ...... 202 ...... 243 ...... 1 L 5 L A 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1, 

6.1.

A9, IB2, N34, T4, 

TP1

152 ...... 203 ...... 242 ...... 2.5 L 30 L A 56, 58, 

133

Barium compounds, n.o.s. .............................................................................................................. 6.1 UN1564 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Barium cyanide ................................................................................................................................ 6.1 UN1565 I 6.1 ..... IB7, IP1, N74, 

N75, T6, TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40, 52

Barium hypochlorite with more than 22 percent available chlorine ................................................ 5.1 UN2741 II 5.1, 

6.1.

A7, A9, IB8, IP2, 

IP4, N34, T3, 

TP33

152 ...... 212 ...... None .... 5 kg 25 kg B 4, 52, 

56, 58, 

106

Barium nitrate .................................................................................................................................. 5.1 UN1446 II 5.1, 

6.1.

IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A ............

Barium oxide ................................................................................................................................... 6.1 UN1884 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Barium perchlorate, solid ................................................................................................................ 5.1 UN1447 II 5.1, 

6.1.

IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Barium perchlorate, solution ........................................................................................................... 5.1 UN3406 II 5.1, 

6.1.

IB2, T4, TP1 152 ...... 202 ...... 243 ...... 1 L 5 L A 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1, 

6.1.

IB2, T4, TP1 152 ...... 203 ...... 242 ...... 2.5 L 30 L A 56, 58, 

133

Barium permanganate ..................................................................................................................... 5.1 UN1448 II 5.1, 

6.1.

IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg D 56, 58, 

138

Barium peroxide .............................................................................................................................. 5.1 UN1449 II 5.1, 

6.1.

A9, IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 13, 52, 

56, 75

Barium selenate, see Selenates or Selenites ................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Barium selenite, see Selenates or Selenites .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Batteries, containing sodium ........................................................................................................... 4.3 UN3292 II 4.3 ..... 189 ...... 189 ...... 189 ...... Forbidden No limit A ............Batteries, dry, containing potassium hydroxide solid, electric, storage .......................................... 8 UN3028 III 8 ........ None .... 213 ...... None .... 25 kg gross 230 kg 

gross 

A ............

Batteries, wet, filled with acid, electric storage ............................................................................... 8 UN2794 III 8 ........ 159 ...... 159 ...... 159 ...... 30 kg gross No limit A ............Batteries, wet, filled with alkali, electric storage ............................................................................. 8 UN2795 III 8 ........ 159 ...... 159 ...... 159 ...... 30 kg gross No limit A ............Batteries, wet, non-spillable, electric storage ................................................................................. 8 UN2800 III 8 ........ 159 ...... 159 ...... 159 ...... No Limit No Limit A ............Batteries, dry, not subject to the requirements of this subchapter ................................................. .................... ........... 130 .......... .......... .......... .................... .................... ............Battery fluid, acid ............................................................................................................................. 8 UN2796 II 8 ........ A3, A7, B2, B15, 

IB2, N6, N34, 

T8, TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L B ............

Battery fluid, alkali ........................................................................................................................... 8 UN2797 II 8 ........ B2, IB2, N6, T7, 

TP2, TP28

154 ...... 202 ...... 242 ...... 1 L 30 L A 29

Battery lithium type, see Lithium batteries etc ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Battery-powered vehicle or Battery-powered equipment ................................................................ 9 UN3171 ............ 9 ........ 134 220 ...... 220 ...... None .... No limit No limit ............Battery, wet, filled with acid or alkali with vehicle or mechanical equipment containing an internal combustion engine, see Vehicle, etc. or Engines, internal combustion, etc. .................... ........... .......... .......... .......... .................... .................... ............

+ Benzaldehyde .................................................................................................................................. 9 UN1990 III 9 ........ IB3, T2, TP1 155 ...... 203 ...... 241 ...... 100 L 220 L A ............

Benzene .......................................................................................................................................... 3 UN1114 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Benzene diazonium chloride (dry) .................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Benzene diazonium nitrate (dry) ..................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Benzene phosphorus dichloride, see Phenyl phosphorus dichloride ............................................. .................... ........... .......... .......... .......... .................... .................... ............Benzene phosphorus thiodichloride, see Phenyl phosphorus thiodichloride ................................. .................... ........... .......... .......... .......... .................... .................... ............Benzene sulfonyl chloride ............................................................................................................... 8 UN2225 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A 40Benzene triozonide .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Benzenethiol, see Phenyl mercaptan ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Benzidine ......................................................................................................................................... 6.1 UN1885 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Benzol, see Benzene ...................................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Benzonitrile ...................................................................................................................................... 6.1 UN2224 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40, 52Benzoquinone .................................................................................................................................. 6.1 UN2587 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Benzotrichloride ............................................................................................................................... 8 UN2226 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 40Benzotrifluoride ................................................................................................................................ 3 UN2338 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Benzoxidiazoles (dry) ...................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Benzoyl azide .................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Benzoyl chloride .............................................................................................................................. 8 UN1736 II 8 ........ B2, IB2, T8, TP2, 

TP12, TP13

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Benzyl bromide ................................................................................................................................ 6.1 UN1737 II 6.1, 8 A3, A7, IB2, 

N33, N34, T8, 

TP2, TP12, TP13

153 ...... 202 ...... 243 ...... 1 L 30 L D 13, 40

76074 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Benzyl chloride ................................................................................................................................ 6.1 UN1738 II 6.1, 8 A3, A7, B70, IB2, 

N33, N42, T8, 

TP2, TP12, TP13

153 ...... 202 ...... 243 ...... 1 L 30 L D 13, 40

Benzyl chloride unstabilized ............................................................................................................ 6.1 UN1738 II 6.1, 8 A3, A7, B8, B11, 

IB2, N33, N34, 

N43, T8, TP2, 

TP12, TP13

153 ...... 202 ...... 243 ...... 1 L 30 L D 13, 40

Benzyl chloroformate ....................................................................................................................... 8 UN1739 I 8 ........ A3, A6, B4, N41, 

T10, TP2, TP12, 

TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L D 40

Benzyl iodide ................................................................................................................................... 6.1 UN2653 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L B 12, 40Benzyldimethylamine ....................................................................................................................... 8 UN2619 II 8, 3 .... B2, IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L A 40, 48Benzylidene chloride ....................................................................................................................... 6.1 UN1886 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L D 40Beryllium compounds, n.o.s. ........................................................................................................... 6.1 UN1566 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Beryllium nitrate ............................................................................................................................... 5.1 UN2464 II 5.1, 

6.1.

IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A ............

Beryllium, powder ............................................................................................................................ 6.1 UN1567 II 6.1, 

4.1.

IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg A ............

Bicyclo [2,2,1] hepta-2,5-diene, stabilized or 2,5-Norbornadiene, stabilized .................................. 3 UN2251 II 3 ........ IB2, T7, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L D ............Biphenyl triozonide .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C .................... 3 UN2782 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L E ............

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Bipyridilium pesticides, liquid, toxic ................................................................................................. 6.1 UN3016 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Bipyridilium pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C .............. 6.1 UN3015 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 21, 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 21, 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 21, 40

Bipyridilium pesticides, solid, toxic .................................................................................................. 6.1 UN2781 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Bis (Aminopropyl) piperazine, see Corrosive liquid, n.o.s. ............................................................. .................... ........... .......... .......... .......... .................... .................... ............Bisulfate, aqueous solution ............................................................................................................. 8 UN2837 II 8 ........ A7, B2, IB2, 

N34, T7, TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ A7, IB3, N34, T4, 

TP1

154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Bisulfites, aqueous solutions, n.o.s. ................................................................................................ 8 UN2693 III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40, 52

Black powder, compressed or Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets. 1.1D UN0028 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Black powder or Gunpowder, granular or as a meal ...................................................................... 1.1D UN0027 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

D Black powder for small arms ........................................................................................................... 4.1 NA0027 I 4.1 ..... 70 None .... 170 ...... None .... Forbidden Forbidden E ............

Blasting agent, n.o.s., see Explosives, blasting etc ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Blasting cap assemblies, see Detonator assemblies, non-electric, for blasting ............................. .................... ........... .......... .......... .......... .................... .................... ............Blasting caps, electric, see Detonators, electric for blasting .......................................................... .................... ........... .......... .......... .......... .................... .................... ............Blasting caps, non-electric, see Detonators, non-electric, for blasting ........................................... .................... ........... .......... .......... .......... .................... .................... ............Bleaching powder, see Calcium hypochlorite mixtures, etc ........................................................... .................... ........... .......... .......... .......... .................... .................... ............

I Blue asbestos (Crocidolite) or Brown asbestos (amosite, mysorite) .............................................. 9 UN2212 II 9 ........ 156, IB8, IP2, 

IP4, T3, TP33

155 ...... 216 ...... 240 ...... Forbidden Forbidden A 34, 40

Bombs, photo-flash ......................................................................................................................... 1.1F UN0037 II 1.1F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Bombs, photo-flash ......................................................................................................................... 1.1D UN0038 II 1.1D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76075

Bombs, photo-flash ......................................................................................................................... 1.2G UN0039 II 1.2G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Bombs, photo-flash ......................................................................................................................... 1.3G UN0299 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Bombs, smoke, non-explosive, with corrosive liquid, without initiating device ............................... 8 UN2028 II 8 ........ None .... 160 ...... None .... Forbidden 50 kg E 40Bombs, with bursting charge ........................................................................................................... 1.1F UN0033 II 1.1F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Bombs, with bursting charge ........................................................................................................... 1.1D UN0034 II 1.1D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Bombs, with bursting charge ........................................................................................................... 1.2D UN0035 II 1.2D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Bombs, with bursting charge ........................................................................................................... 1.2F UN0291 II 1.2F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Bombs with flammable liquid, with bursting charge ........................................................................ 1.1J UN0399 II 1.1J ... .......... 62 ........ None .... Forbidden Forbidden 04 23E Bombs with flammable liquid, with bursting charge ........................................................................ 1.2J UN0400 II 1.2J ... .......... 62 ........ None .... Forbidden Forbidden 04 23E Boosters with detonator .................................................................................................................. 1.1B UN0225 II 1.1B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Boosters with detonator .................................................................................................................. 1.2B UN0268 II 1.2B ... None .... 62 ........ None .... Forbidden Forbidden 07 ............Boosters, without detonator ............................................................................................................ 1.1D UN0042 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Boosters, without detonator ............................................................................................................ 1.2D UN0283 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Borate and chlorate mixtures, see Chlorate and borate mixtures .................................................. .................... ........... .......... .......... .......... .................... .................... ............Borneol ............................................................................................................................................ 4.1 UN1312 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg A ............

+ Boron tribromide .............................................................................................................................. 8 UN2692 I 8, 6.1 2, B9, B14, B32, 

B74, N34, T20, 

TP2, TP12, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden C 12

Boron trichloride .............................................................................................................................. 2.3 UN1741 ............ 2.3, 8 3, B9, B14 None .... 304 ...... 314 ...... Forbidden Forbidden D 25, 40Boron trifluoride ............................................................................................................................... 2.3 UN1008 ............ 2.3 ..... 2, B9, B14 None .... 302 ...... 314, 

315.

Forbidden Forbidden D 40

Boron trifluoride acetic acid complex, liquid ................................................................................... 8 UN1742 II 8 ........ B2, B6, IB2, T8, 

TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Boron trifluoride acetic acid complex, solid .................................................................................... 8 UN3419 II 8 ........ B2, B6, IB8, IP2, 

IP4, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Boron trifluoride diethyl etherate ..................................................................................................... 8 UN2604 I 8, 3 .... A3, A19, T10, 

TP2

None .... 201 ...... 243 ...... 0.5 L 2.5 L D 40

Boron trifluoride dihydrate ............................................................................................................... 8 UN2851 II 8 ........ IB2, T7, TP2 154 ...... 212 ...... 240 ...... 15 kg 50 kg B 12, 40, Boron trifluoride dimethyl etherate .................................................................................................. 4.3 UN2965 I 4.3, 8, 

3.

A19, T10, TP2, 

TP7

None .... 201 ...... 243 ...... Forbidden 1 L D 21, 28, 

40, 49, 

100

Boron trifluoride propionic acid complex, liquid .............................................................................. 8 UN1743 II 8 ........ B2, IB2, T8, TP2, 

TP12

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Boron trifluoride propionic acid complex, solid ............................................................................... 8 UN3420 II 8 ........ B2, IB8, IP2, IP4, 

T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Box toe gum, see Nitrocellulose etc ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Bromates, inorganic, aqueous solution, n.o.s. ................................................................................ 5.1 UN3213 II 5.1 ..... IB2, T4, TP1 152 ...... 202 ...... 242 ...... 1 L 5 L B 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... IB2, T4, TP1 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 58, 

133

Bromates, inorganic, n.o.s. ............................................................................................................. 5.1 UN1450 II 5.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Bromine azide ................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............

+ Bromine or Bromine solutions ......................................................................................................... 8 UN1744 I 8, 6.1 1, B9, B64, B85, 

N34, N43, T22, 

TP2, TP10, 

TP12, TP13

None .... 226 ...... 249 ...... Forbidden Forbidden 12, 40, 

66, 74, 

89, 90

Bromine chloride ............................................................................................................................. 2.3 UN2901 ............ 2.3, 8, 

5.1.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 89, 

90

+ Bromine pentafluoride ..................................................................................................................... 5.1 UN1745 I 5.1, 

6.1, 8.

1, B9, B14, B30, 

B72, T22, TP2, 

TP12, TP13, 

TP38, TP44

None .... 228 ...... 244 ...... Forbidden Forbidden D 25, 40, 

66, 90

+ Bromine trifluoride ........................................................................................................................... 5.1 UN1746 I 5.1, 

6.1, 8.

2, B9, B14, B32, 

B74, T22, TP2, 

TP12, TP13, 

TP38, TP45

None .... 228 ...... 244 ...... Forbidden Forbidden D 25, 40, 

66, 90

4-Bromo-1,2-dinitrobenzene ............................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C) ............................................................... Forbidden ........... .......... .......... .......... .................... .................... ............1-Bromo-3-chloropropane ............................................................................................................... 6.1 UN2688 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............1-Bromo-3-methylbutane ................................................................................................................. 3 UN2341 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............1-Bromo-3-nitrobenzene (unstable at 56 degrees C) ..................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2-Bromo-2-nitropropane-1,3-diol ..................................................................................................... 4.1 UN3241 III 4.1 ..... 46, IB8, IP3 151 ...... 213 ...... None .... 25 kg 50 kg C 12, 25, 

40

Bromoacetic acid, solid ................................................................................................................... 8 UN3425 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Bromoacetic acid solution ............................................................................................................... 8 UN1938 II 8 ........ A7, B2, IB2, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A 40

.......................................................................................................................................................... .................... III 8 ........ B2, IB3, T7, TP2 154 ...... 203 ...... 241 ...... 5 L 60 L A 40

+ Bromoacetone ................................................................................................................................. 6.1 UN1569 II 6.1, 3 2, T20, TP2, 

TP13

None .... 193 ...... 245 ...... Forbidden Forbidden D 40

76076 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Bromoacetyl bromide ...................................................................................................................... 8 UN2513 II 8 ........ B2, IB2, T8, TP2, 

TP12

154 ...... 202 ...... 242 ...... 1 L 30 L C 40, 53

Bromobenzene ................................................................................................................................ 3 UN2514 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Bromobenzyl cyanides, liquid .......................................................................................................... 6.1 UN1694 I 6.1 ..... T14, TP2, TP13 None .... 201 ...... 243 ...... Forbidden 30 L D 12, 40, 

52

Bromobenzyl cyanides, solid ........................................................................................................... 6.1 UN3449 I 6.1 ..... T6, TP33 None .... 211 ...... 242 ...... 5 kg 50 kg D 12, 40, 

52

1-Bromobutane ................................................................................................................................ 3 UN1126 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 402-Bromobutane ................................................................................................................................ 3 UN2339 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Bromochloromethane ...................................................................................................................... 6.1 UN1887 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............2-Bromoethyl ethyl ether ................................................................................................................. 3 UN2340 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Bromoform ....................................................................................................................................... 6.1 UN2515 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 12, 40Bromomethylpropanes .................................................................................................................... 3 UN2342 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............2-Bromopentane .............................................................................................................................. 3 UN2343 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Bromopropanes ............................................................................................................................... 3 UN2344 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 3 ........ IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

3-Bromopropyne .............................................................................................................................. 3 UN2345 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L D 40Bromosilane ..................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Bromotoluene-alpha, see Benzyl bromide ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Bromotrifluoroethylene .................................................................................................................... 2.1 UN2419 ............ 2.1 ..... None .... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Bromotrifluoromethane or Refrigerant gas, R 13B1. ...................................................................... 2.2 UN1009 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Brucine ............................................................................................................................................ 6.1 UN1570 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A ............

Bursters, explosive .......................................................................................................................... 1.1D UN0043 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Butadienes, stabilized or Butadienes and Hydrocarbon mixture, stabilized containing more than 

40% butadienes.

2.1 UN1010 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Butane see also Petroleum gases, liquefied .................................................................................. 2.1 UN1011 ............ 2.1 ..... 19, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Butane, butane mixtures and mixtures having similar properties in cartridges each not exceeding 500 grams, see Receptacles, etc. .................... ........... .......... .......... .......... .................... .................... ............Butanedione .................................................................................................................................... 3 UN2346 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............1,2,4-Butanetriol trinitrate ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Butanols ........................................................................................................................................... 3 UN1120 II 3 ........ IB2, T4, TP1, 

TP29

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

tert-Butoxycarbonyl azide ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Butyl acetates .................................................................................................................................. 3 UN1123 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Butyl acid phosphate ....................................................................................................................... 8 UN1718 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Butyl acrylates, stabilized ................................................................................................................ 3 UN2348 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Butyl alcohols, see Butanols ........................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Butyl benzenes ................................................................................................................................ 3 UN2709 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............n-Butyl bromide, see 1-Bromobutane ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............n-Butyl chloride, see Chlorobutanes ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

D sec-Butyl chloroformate ................................................................................................................... 6.1 NA2742 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... 1 L 30 L A 12, 13, 

22, 25, 

40, 48, 

100

n-Butyl chloroformate ...................................................................................................................... 6.1 UN2743 I 6.1, 8, 

3.

2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A 12, 13, 

21, 25, 

40, 100

Butyl ethers, see Dibutyl ethers ...................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Butyl ethyl ether, see Ethyl butyl ether ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............n-Butyl formate ................................................................................................................................ 3 UN1128 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............tert-Butyl hydroperoxide, with more than 90 percent with water .................................................... Forbidden ........... .......... .......... .......... .................... .................... ............tert-Butyl hypochlorite ...................................................................................................................... 4.2 UN3255 I 4.2, 8 None .... 211 ...... 243 ...... Forbidden Forbidden D ............N-n-Butyl imidazole ......................................................................................................................... 6.1 UN2690 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............tert-Butyl isocyanate ........................................................................................................................ 6.1 UN2484 I 6.1, 3 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76077

n-Butyl isocyanate ........................................................................................................................... 6.1 UN2485 I 6.1, 3 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Butyl mercaptans ............................................................................................................................. 3 UN2347 II 3 ........ A3, A6, IB2, T4, 

TP1

150 ...... 202 ...... 242 ...... 5 L 60 L D 52, 95

n-Butyl methacrylate, stabilized ...................................................................................................... 3 UN2227 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Butyl methyl ether ........................................................................................................................... 3 UN2350 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Butyl nitrites ..................................................................................................................................... 3 UN2351 I 3 ........ T11, TP1, TP8, 

TP27

150 ...... 201 ...... 243 ...... 1 L 30 L E 40

.......................................................................................................................................................... .................... II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40

tert-Butyl peroxyacetate, with more than 76 percent in solution .................................................... Forbidden ........... .......... .......... .......... .................... .................... ............n-Butyl peroxydicarbonate, with more than 52 percent in solution ................................................ Forbidden ........... .......... .......... .......... .................... .................... ............tert-Butyl peroxyisobutyrate, with more than 77 percent in solution .............................................. Forbidden ........... .......... .......... .......... .................... .................... ............Butyl phosphoric acid, see Butyl acid phosphate ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Butyl propionates ............................................................................................................................. 3 UN1914 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene ......................................................................... 4.1 UN2956 III 4.1 ..... 159 None .... 223 ...... None .... Forbidden Forbidden D D12, 

25, 48, 

127

Butyl vinyl ether, stabilized .............................................................................................................. 3 UN2352 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40n-Butylamine .................................................................................................................................... 3 UN1125 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 242 ...... 1 L 5 L B 40N-Butylaniline .................................................................................................................................. 6.1 UN2738 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 74tert-Butylcyclohexylchloroformate .................................................................................................... 6.1 UN2747 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 12, 13, 

25

Butylene see also Petroleum gases, liquefied ................................................................................ 2.1 UN1012 ............ 2.1 ..... 19, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

1,2-Butylene oxide, stabilized ......................................................................................................... 3 UN3022 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 27, 49Butyltoluenes ................................................................................................................................... 6.1 UN2667 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Butyltrichlorosilane .......................................................................................................................... 8 UN1747 II 8, 3 .... A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 243 ...... Forbidden 30 L C 40

1,4-Butynediol .................................................................................................................................. 6.1 UN2716 III 6.1 ..... A1, IB8, IP3, T1, 

TP33

None .... 213 ...... 240 ...... 100 kg 200 kg A 52, 53, 

70, 

139, 

140

Butyraldehyde .................................................................................................................................. 3 UN1129 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Butyraldoxime .................................................................................................................................. 3 UN2840 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Butyric acid ...................................................................................................................................... 8 UN2820 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A 12Butyric anhydride ............................................................................................................................. 8 UN2739 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Butyronitrile ...................................................................................................................................... 3 UN2411 II 3, 6.1 IB2, T7, TP1, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Butyryl chloride ................................................................................................................................ 3 UN2353 II 3, 8 .... IB2, T8, TP2, 

TP12, TP13

150 ...... 202 ...... 243 ...... 1 L 5 L C 40

Cacodylic acid ................................................................................................................................. 6.1 UN1572 II 6.1 ..... IB8, IP2, IP4,T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg E 52

Cadmium compounds ..................................................................................................................... 6.1 UN2570 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Caesium hydroxide .......................................................................................................................... 8 UN2682 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 29

Caesium hydroxide solution ............................................................................................................ 8 UN2681 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 29

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A 29

Calcium ............................................................................................................................................ 4.3 UN1401 II 4.3 ..... IB7, IP2, T3, 

TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg E 52

Calcium arsenate ............................................................................................................................ 6.1 UN1573 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Calcium arsenate and calcium arsenite, mixtures, solid ................................................................ 6.1 UN1574 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Calcium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. ............................................... .................... ........... .......... .......... .......... .................... .................... ............Calcium carbide ............................................................................................................................... 4.3 UN1402 I 4.3 ..... A1, A8, B55, 

B59, IB4, IP1, 

N34, T9, TP7, 

TP33

None .... 211 ...... 242 ...... Forbidden 15 kg B 52

.......................................................................................................................................................... .................... II 4.3 ..... A1, A8, B55, 

B59, IB7, IP2, 

N34, T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg B 52

Calcium chlorate .............................................................................................................................. 5.1 UN1452 II 5.1 ..... A9, IB8, IP2, IP4, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Calcium chlorate aqueous solution ................................................................................................. 5.1 UN2429 II 5.1 ..... A2, IB2, N41, T4, 

TP1

152 ...... 202 ...... 242 ...... 1 L 5 L B 56, 58, 

133

76078 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... III 5.1 ..... A2, IB2, N41, T4, 

TP1

152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 68, 

133

Calcium chlorite ............................................................................................................................... 5.1 UN1453 II 5.1 ..... A9, IB8, IP2, IP4, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Calcium cyanamide with more than 0.1 percent of calcium carbide .............................................. 4.3 UN1403 III 4.3 ..... A1, A19, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg A 52

Calcium cyanide .............................................................................................................................. 6.1 UN1575 I 6.1 ..... IB7, IP1, N79, 

N80, T6, TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40, 52

Calcium dithionite or Calcium hydrosulfite ...................................................................................... 4.2 UN1923 II 4.2 ..... A19, A20, IB6, 

IP2, T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg E 13

Calcium hydride ............................................................................................................................... 4.3 UN1404 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Calcium hydrosulfite, see Calcium dithionite .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen). 5.1 UN1748 II 5.1 ..... 165, 166, A7, A9, IB8, IP2, IP4, 

IP13, N34, W9

152 ...... 212 ...... None .... 5 kg 25 kg D 4, 25, 

48, 52, 

56, 58, 

69, 142

.......................................................................................................................................................... .................... III 5.1 ..... 165, 171, A7, 

A9, IB8, IP4, 

IP13, N34, W9

152 ...... 213 ...... 240 ...... 25 kg 100 kg D 4, 25, 

48, 52, 

56, 58, 

69, 142

Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not less than 

5.5 percent but not more than 16 percent water.

5.1 UN2880 II 5.1 ..... 165, 166, IB8, 

IP2, IP4, IP13, 

W9

152 ...... 212 ...... 240 ...... 5 kg 25 kg D 4, 25, 

48, 52, 

56, 58, 

69, 142

.......................................................................................................................................................... .................... III 5.1 ..... 165, 171, IB8, 

IP4, IP13, W9

152 ...... 213 ...... 240 ...... 25 kg 100 kg D 4, 25, 

48, 52, 

56, 58, 

69, 142

Calcium hypochlorite mixtures, dry, with more than 10 percent but not more than 39 percent 

available chlorine.

5.1 UN2208 III 5.1 ..... 165, A1, A29, 

IB8, IP3, IP13, 

N34, W9

152 ...... 213 ...... 240 ...... 25 kg 100 kg D 4, 25, 

48, 52, 

56, 58, 

69, 142

Calcium manganese silicon ............................................................................................................ 4.3 UN2844 III 4.3 ..... A1, A19, IB8, 

IP2, IP4, T1, 

TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg A 52, 85, 

103

Calcium nitrate ................................................................................................................................ 5.1 UN1454 III 5.1 ..... 34, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

A Calcium oxide .................................................................................................................................. 8 UN1910 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Calcium perchlorate ........................................................................................................................ 5.1 UN1455 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Calcium permanganate ................................................................................................................... 5.1 UN1456 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg D 56, 58, 

138

Calcium peroxide ............................................................................................................................. 5.1 UN1457 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 13, 52, 

56, 75

Calcium phosphide .......................................................................................................................... 4.3 UN1360 I 4.3, 

6.1.

A8, A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 40, 52, 

85

Calcium, pyrophoric or Calcium alloys, pyrophoric ......................................................................... 4.2 UN1855 I 4.2 ..... None .... 187 ...... None .... Forbidden Forbidden D ............Calcium resinate .............................................................................................................................. 4.1 UN1313 III 4.1 ..... A1, A19, IB6, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg A ............

Calcium resinate, fused ................................................................................................................... 4.1 UN1314 III 4.1 ..... A1, A19, IB4, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg A ............

Calcium selenate, see Selenates or Selenites ............................................................................... .................... ........... .......... .......... .......... .................... .................... ............Calcium silicide ................................................................................................................................ 4.3 UN1405 II 4.3 ..... A19, IB7, IP2, 

T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg B 52, 85, 

103

.......................................................................................................................................................... .................... III 4.3 ..... A1, A19, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg B 52, 85, 

103

Camphor oil ..................................................................................................................................... 3 UN1130 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Camphor, synthetic ......................................................................................................................... 4.1 UN2717 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg A ............

Cannon primers, see Primers, tubular ............................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Caproic acid .................................................................................................................................... 8 UN2829 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Caps, blasting, see Detonators, etc ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ..................... 3 UN2758 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76079

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Carbamate pesticides, liquid, toxic ................................................................................................. 6.1 UN2992 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C ............... 6.1 UN2991 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Carbamate pesticides, solid, toxic .................................................................................................. 6.1 UN2757 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Carbolic acid, see Phenol, solid or Phenol, molten ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Carbolic acid solutions, see Phenol solutions ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............

I Carbon, activated ............................................................................................................................ 4.2 UN1362 III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 0.5 kg 0.5 kg A 12

I Carbon, animal or vegetable origin ................................................................................................. 4.2 UN1361 II 4.2 ..... IB6, T3, TP33 None .... 212 ...... 242 ...... Forbidden Forbidden A 12

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... Forbidden Forbidden A 12

Carbon bisulfide, see Carbon disulfide ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Carbon dioxide ................................................................................................................................ 2.2 UN1013 ............ 2.2 ..... 306 ...... 302, 

304.

302, 

314, 315.

75 kg 150 kg A ............

Carbon dioxide and nitrous oxide mixtures .................................................................................... 2.2 UN1015 ............ 2.2 ..... 306 ...... None .... 314, 

315.

75 kg 150 kg A ............

Carbon dioxide and oxygen mixtures, compressed ........................................................................ 2.2 UN1014 ............ 2.2, 

5.1.

77, A14 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Carbon dioxide, refrigerated liquid .................................................................................................. 2.2 UN2187 ............ 2.2 ..... T75, TP5 306 ...... 304 ...... 314, 

315.

50 kg 500 kg B ............

A W Carbon dioxide, solid or Dry ice ...................................................................................................... 9 UN1845 III None 217 ...... 217 ...... 240 ...... 200 kg 200 kg C 40

Carbon disulfide .............................................................................................................................. 3 UN1131 I 3, 6.1 B16, T14, TP2, 

TP7, TP13

None .... 201 ...... 243 ...... Forbidden Forbidden D 18, 40, 

115

Carbon monoxide, compressed ...................................................................................................... 2.3 UN1016 ............ 2.3, 

2.1.

4 None .... 302 ...... 314, 

315.

Forbidden 25 kg D 40

Carbon monoxide and hydrogen mixture, compressed .................................................................. 2.3 UN2600 ............ 2.3, 

2.1.

6 None .... 302 ...... 302 ...... Forbidden Forbidden D 40, 57

D Carbon monoxide, refrigerated liquid (cryogenic liquid) ................................................................. 2.3 NA9202 ............ 2.3, 

2.1.

4, T75, TP5 None .... 316 ...... 318 ...... Forbidden Forbidden D ............

Carbon tetrabromide ....................................................................................................................... 6.1 UN2516 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 25

Carbon tetrachloride ........................................................................................................................ 6.1 UN1846 II 6.1 ..... IB2, N36, T7, 

TP2

153 ...... 202 ...... 243 ...... 5 L 60 L A 40

Carbonyl chloride, see Phosgene ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Carbonyl fluoride ............................................................................................................................. 2.3 UN2417 ............ 2.3, 8 2 None .... 302 ...... None .... Forbidden Forbidden D 40Carbonyl sulfide ............................................................................................................................... 2.3 UN2204 ............ 2.3, 

2.1.

3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Cartridge cases, empty primed, see Cases, cartridge, empty, with primer ................................... .................... ........... .......... .......... .......... .................... .................... ............Cartridges, actuating, for aircraft ejector seat catapult, fire extinguisher, canopy removal or apparatus, see Cartridges, power device. .................... ........... .......... .......... .......... .................... .................... ............Cartridges, explosive, see Charges, demolition ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Cartridges, flash .............................................................................................................................. 1.1G UN0049 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cartridges, flash .............................................................................................................................. 1.3G UN0050 II 1.3G .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Cartridges for weapons, blank ........................................................................................................ 1.1C UN0326 II 1.1C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cartridges for weapons, blank ........................................................................................................ 1.2C UN0413 II 1.2C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cartridges for weapons, blank or Cartridges, small arms, blank ................................................... 1.4S UN0014 II None 63 ........ 62 ........ None .... 25 kg 100 kg 05 ............Cartridges for weapons, blank or Cartridges, small arms, blank ................................................... 1.3C UN0327 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cartridges for weapons, blank or Cartridges, small arms, blank ................................................... 1.4C UN0338 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cartridges for weapons, inert projectile .......................................................................................... 1.2C UN0328 II 1.2C .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Cartridges for weapons, inert projectile or Cartridges, small arms ................................................ 1.4S UN0012 II None 63 ........ 62 ........ None .... 25 kg 100 kg 05 ............Cartridges for weapons, inert projectile or Cartridges, small arms ................................................ 1.4C UN0339 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cartridges for weapons, inert projectile or Cartridges, small arms ................................................ 1.3C UN0417 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 06 ............Cartridges for weapons, with bursting charge ................................................................................ 1.1F UN0005 II 1.1F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Cartridges for weapons, with bursting charge ................................................................................ 1.1E UN0006 II 1.1E ... None .... 62 ........ None .... Forbidden Forbidden 03 ............Cartridges for weapons, with bursting charge ................................................................................ 1.2F UN0007 II 1.2F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Cartridges for weapons, with bursting charge ................................................................................ 1.2E UN0321 II 1.2E ... None .... 62 ........ None .... Forbidden Forbidden 03 ............Cartridges for weapons, with bursting charge ................................................................................ 1.4F UN0348 II 1.4F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Cartridges for weapons, with bursting charge ................................................................................ 1.4E UN0412 II 1.4E ... None .... 62 ........ None .... Forbidden 75 kg 02 ............

76080 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Cartridges, oil well ........................................................................................................................... 1.3C UN0277 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cartridges, oil well ........................................................................................................................... 1.4C UN0278 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cartridges, power device ................................................................................................................ 1.3C UN0275 II 1.3C .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Cartridges, power device ................................................................................................................ 1.4C UN0276 II 1.4C .. 110 None .... 62 ........ None .... Forbidden 75 kg 06 ............Cartridges, power device ................................................................................................................ 1.4S UN0323 II 1.4S ... 110 63 ........ 62 ........ None .... 25 kg 100 kg 05 ............Cartridges, power device ................................................................................................................ 1.2C UN0381 II 1.2C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cartridges, safety, blank, see Cartridges for weapons, blank (UN 0014) ...................................... .................... ........... .......... .......... .......... .................... .................... ............Cartridges, safety, see Cartridges for weapons, other than blank or Cartridges, power device 

(UN 0323).

.................... ........... .......... .......... .......... .................... .................... ............

Cartridges, signal ............................................................................................................................ 1.3G UN0054 II 1.3G .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Cartridges, signal ............................................................................................................................ 1.4G UN0312 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cartridges, signal ............................................................................................................................ 1.4S UN0405 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............

D Cartridges, small arms .................................................................................................................... ORM-D ............ None 63 ........ None .... None .... 30 kg gross 30 kg gross A ............D Cartridges power device (used to project fastening devices) ......................................................... ORM-D ............ None 63 ........ None .... None .... 30 kg gross 30 kg gross A ............

Cartridges, sporting, see Cartridges for weapons, other than blank .............................................. .................... ........... .......... .......... .......... .................... .................... ............Cartridges, starter, jet engine, see Cartridges, power device ........................................................ .................... ........... .......... .......... .......... .................... .................... ............Cases, cartridge, empty with primer ............................................................................................... 1.4S UN0055 II 1.4S ... 50 None .... 62 ........ None .... 25 kg 100 kg 05 ............Cases, cartridges, empty with primer ............................................................................................. 1.4C UN0379 II 1.4C .. 50 None .... 62 ........ None .... Forbidden 75 kg 06 ............Cases, combustible, empty, without primer .................................................................................... 1.4C UN0446 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cases, combustible, empty, without primer .................................................................................... 1.3C UN0447 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Casinghead gasoline see Gasoline ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............

A W Castor beans or Castor meal or Castor pomace or Castor flake ................................................... 9 UN2969 II None IB8, IP2, IP4, T3, 

TP33

155 ...... 204 ...... 240 ...... No limit No limit E 34, 40

G Caustic alkali liquids, n.o.s. ............................................................................................................. 8 UN1719 II 8 ........ B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L A 29

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 29

Caustic potash, see Potassium hydroxide etc ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Caustic soda, (etc.) see Sodium hydroxide etc .............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Cells, containing sodium ................................................................................................................. 4.3 UN3292 II 4.3 ..... 189 ...... 189 ...... 189 ...... 25 kg gross No limit A ............Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap .................................................... 4.1 UN2000 III 4.1 ..... None .... 213 ...... 240 ...... 25 kg 100 kg A ............Celluloid, scrap ................................................................................................................................ 4.2 UN2002 III 4.2 ..... IB8, IP3 None .... 213 ...... 241 ...... Forbidden Forbidden D ............Cement, see Adhesives containing flammable liquid ..................................................................... .................... ........... .......... .......... .......... .................... .................... ............Cerium, slabs, ingots, or rods ......................................................................................................... 4.1 UN1333 II 4.1 ..... IB8, IP2, IP4, 

N34

None .... 212 ...... 240 ...... 15 kg 50 kg A 74, 91

Cerium, turnings or gritty powder .................................................................................................... 4.3 UN3078 II 4.3 ..... A1, IB7, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg E 52

Cesium or Caesium ......................................................................................................................... 4.3 UN1407 I 4.3 ..... A7, A19, IB4, 

IP1, N34, N40

None .... 211 ...... 242 ...... Forbidden 15 kg D 52

Cesium nitrate or Caesium nitrate .................................................................................................. 5.1 UN1451 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

D Charcoal briquettes, shell, screenings, wood, etc. ......................................................................... 4.2 NA1361 III 4.2 ..... IB8, T1, TP33 151 ...... 213 ...... 240 ...... 25 kg 100 kg A 12

Charges, bursting, plastics bonded ................................................................................................. 1.1D UN0457 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, bursting, plastics bonded ................................................................................................. 1.2D UN0458 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, bursting, plastics bonded ................................................................................................. 1.4D UN0459 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Charges, bursting, plastics bonded ................................................................................................. 1.4S UN0460 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Charges, demolition ........................................................................................................................ 1.1D UN0048 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Charges, depth ................................................................................................................................ 1.1D UN0056 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Charges, expelling, explosive, for fire extinguishers, see Cartridges, power device ..................... .................... ........... .......... .......... .......... .................... .................... ............Charges, explosive, commercial without detonator ........................................................................ 1.1D UN0442 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, explosive, commercial without detonator ........................................................................ 1.2D UN0443 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, explosive, commercial without detonator ........................................................................ 1.4D UN0444 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Charges, explosive, commercial without detonator ........................................................................ 1.4S UN0445 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Charges, propelling ......................................................................................................................... 1.1C UN0271 II 1.1C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, propelling ......................................................................................................................... 1.3C UN0272 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, propelling ......................................................................................................................... 1.2C UN0415 II 1.2C .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, propelling ......................................................................................................................... 1.4C UN0491 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Charges, propelling, for cannon ...................................................................................................... 1.3C UN0242 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Charges, propelling, for cannon ...................................................................................................... 1.1C UN0279 II 1.1C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Charges, propelling, for cannon ...................................................................................................... 1.2C UN0414 II 1.2C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Charges, shaped, flexible, linear ..................................................................................................... 1.4D UN0237 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Charges, shaped, flexible, linear ..................................................................................................... 1.1D UN0288 II 1.1D .. 101 None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, shaped, without detonator ............................................................................................... 1.1D UN0059 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, shaped, without detonator ............................................................................................... 1.2D UN0439 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Charges, shaped, without detonator ............................................................................................... 1.4D UN0440 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 06 ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76081

Charges, shaped, without detonator ............................................................................................... 1.4S UN0441 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Charges, supplementary explosive ................................................................................................. 1.1D UN0060 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

D Chemical kit ..................................................................................................................................... 8 NA1760 II 8 ........ 154 ...... 161 ...... None .... 1 L 30 L B 40

Chemical kits ................................................................................................................................... 9 UN3316 ............ 9 ........ 15 161 ...... 161 ...... None .... 10 kg 10 kg A ............Chloral, anhydrous, stabilized ......................................................................................................... 6.1 UN2075 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L D 40Chlorate and borate mixtures .......................................................................................................... 5.1 UN1458 II 5.1 ..... A9, IB8, IP2, IP4, 

N34, T3, TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 56, 58

.......................................................................................................................................................... .................... III 5.1 ..... A9, IB8, IP3, 

N34, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Chlorate and magnesium chloride mixture, solid ............................................................................ 5.1 UN1459 II 5.1 ..... A9, IB8, IP2, IP4, 

N34, T3, TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 56, 58

Chlorate and magnesium chloride mixture solution ........................................................................ 5.1 UN3407 II 5.1 ..... A9, IB2, N34, T4, 

TP1

152 ...... 202 ...... 242 ...... 1 L 5 L A 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... A9, IB2, N34, T4, 

TP1

152 ...... 203 ...... 241 ...... 2.5 L 30 L A 56, 58, 

133

Chlorate and magnesium chloride mixture, solid ............................................................................ 5.1 UN1459 III 5.1 ..... A9, IB8, IP3, 

N34, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Chlorate of potash, see Potassium chlorate ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Chlorate of soda, see Sodium chlorate .......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Chlorates, inorganic, aqueous solution, n.o.s. ................................................................................ 5.1 UN3210 II 5.1 ..... IB2, T4, TP1 152 ...... 202 ...... 242 ...... 1 L 5 L B 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... IB2, T4, TP1 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 58, 

133

Chlorates, inorganic, n.o.s. ............................................................................................................. 5.1 UN1461 II 5.1 ..... A9, IB6, IP2, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Chloric acid aqueous solution, with not more than 10 percent chloric acid ................................... 5.1 UN2626 II 5.1 ..... IB2, T4, TP1 None .... 229 ...... None .... Forbidden Forbidden D 56, 58Chloride of phosphorus, see Phosphorus trichloride ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Chloride of sulfur, see Sulfur chloride ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Chlorinated lime, see Calcium hypochlorite mixtures, etc .............................................................. .................... ........... .......... .......... .......... .................... .................... ............Chlorine ........................................................................................................................................... 2.3 UN1017 ............ 2.3, 8 2, B9, B14, T50, 

TP19

None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 51, 

55, 62, 

68, 89, 

90

Chlorine azide ................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............

D Chlorine dioxide, hydrate, frozen .................................................................................................... 5.1 NA9191 II 5.1, 

6.1.

None .... 229 ...... None .... Forbidden Forbidden E ............

Chlorine dioxide (not hydrate) ......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Chlorine pentafluoride ..................................................................................................................... 2.3 UN2548 ............ 2.3, 

5.1, 8.

1, B7, B9, B14 None .... 304 ...... 314 ...... Forbidden Forbidden D 40, 89, 

90

Chlorine trifluoride ........................................................................................................................... 2.3 UN1749 ............ 2.3, 

5.1, 8.

2, B7, B9, B14 None .... 304 ...... 314 ...... Forbidden Forbidden D 40, 89, 

90

Chlorite solution ............................................................................................................................... 8 UN1908 II 8 ........ A3, A6, A7, B2, 

IB2, N34, T7, 

TP2, TP24

154 ...... 202 ...... 242 ...... 1 L 30 L B 26, 44, 

89, 

100, 

141

.......................................................................................................................................................... .................... III 8 ........ A3, A6, A7, B2, 

IB3, N34, T4, 

TP2, TP24

154 ...... 203 ...... 241 ...... 5 L 60 L B 26, 44, 

89, 

100, 

141

Chlorites, inorganic, n.o.s. ............................................................................................................... 5.1 UN1462 II 5.1 ..... A7, IB6, IP2, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b ................................................................. 2.1 UN2517 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

3-Chloro-4-methylphenyl isocyanate, liquid .................................................................................... 6.1 UN2236 II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... 5 L 60 L B 403-Chloro-4-methylphenyl isocyanate, solid ..................................................................................... 6.1 UN3428 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 40

1-Chloro-1,2,2,2-tetrafluoroethaneor Refrigerant gas R 124 .......................................................... 2.2 UN1021 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

4-Chloro-o-toluidine hydrochloride, solid ......................................................................................... 6.1 UN1579 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

4-Chloro-o-toluidine hydrochloride, solution .................................................................................... 6.1 UN3410 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a .............................................................. 2.2 UN1983 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Chloroacetic acid, molten ................................................................................................................ 6.1 UN3250 II 6.1, 8 IB1, T7, TP3, 

TP28

None .... 202 ...... 243 ...... Forbidden Forbidden C 40

Chloroacetic acid, solid ................................................................................................................... 6.1 UN1751 II 6.1, 8 A3, A7, IB8, IP4, 

N34, T3, TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg A 40

Chloroacetic acid, solution .............................................................................................................. 6.1 UN1750 II 6.1, 8 A7, IB2, N34, T7, 

TP2

153 ...... 202 ...... 243 ...... 1 L 30 L C 40

76082 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Chloroacetone, stabilized ................................................................................................................ 6.1 UN1695 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, N12, N32, 

N34, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 21, 40, 

100

Chloroacetone (unstabilized) ........................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............

+ Chloroacetonitrile ............................................................................................................................. 6.1 UN2668 II 6.1, 3 2, B9, B14, B32, 

B74, IB99, T20, 

TP2, TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A 12, 40, 

52

Chloroacetophenone, liquid CN ...................................................................................................... 6.1 UN3416 II 6.1 ..... A3, IB2, N12, 

N32, N33, T7, 

TP2, TP13

None .... 202 ...... 243 ...... Forbidden 60 L D 12, 40

Chloroacetophenone, solid (CN) ..................................................................................................... 6.1 UN1697 II 6.1 ..... A3, IB8, IP2, IP4, 

N12, N32, N33, 

N34, T3, TP33 

TP2, TP13

None .... 212 ...... None .... Forbidden 100 kg D 12, 40

Chloroacetyl chloride ....................................................................................................................... 6.1 UN1752 I 6.1, 8 2, B3, B8, B9, 

B14, B32, B74, 

B77, N34, N43, 

T20, TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Chloroanilines, liquid ....................................................................................................................... 6.1 UN2019 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 52Chloroanilines, solid ........................................................................................................................ 6.1 UN2018 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Chloroanisidines .............................................................................................................................. 6.1 UN2233 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Chlorobenzene ................................................................................................................................ 3 UN1134 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Chlorobenzol, see Chlorobenzene .................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Chlorobenzotrifluorides .................................................................................................................... 3 UN2234 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40Chlorobenzyl chlorides, liquid ......................................................................................................... 6.1 UN2235 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Chlorobenzyl chlorides, solid .......................................................................................................... 6.1 UN3427 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Chlorobutanes ................................................................................................................................. 3 UN1127 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Chlorocresols solution ..................................................................................................................... 6.1 UN2669 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 12

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L A 12

Chlorocresols, solid ......................................................................................................................... 6.1 UN3437 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 12

Chlorodifluorobromomethane or Refrigerant gas R 12B1 .............................................................. 2.2 UN1974 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Chlorodifluoromethane and chloropentafluoroethane mixture or Refrigerant gas R 502 with 

fixed boiling point, with approximately 49 percent chlorodifluoromethane.

2.2 UN1973 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Chlorodifluoromethane or Refrigerant gas R 22 ............................................................................. 2.2 UN1018 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

+ Chlorodinitrobenzenes, liquid. ......................................................................................................... 6.1 UN1577 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L B 91

Chlorodinitro-benzenes, solid .......................................................................................................... 6.1 UN3441 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 91

2-Chloroethanal ............................................................................................................................... 6.1 UN2232 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Chloroform ....................................................................................................................................... 6.1 UN1888 III 6.1 ..... IB3, N36, T7, 

TP2

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

G Chloroformates, toxic, corrosive, flammable, n.o.s. ........................................................................ 6.1 UN2742 II 6.1, 8, 

3.

5, IB1, T7, TP2 153 ...... 202 ...... 243 ...... 1 L 30 L A 12, 13, 

21, 25, 

40, 100

G Chloroformates, toxic, corrosive, n.o.s. ........................................................................................... 6.1 UN3277 II 6.1, 8 IB2, T8, TP2, 

TP13, TP28

153 ...... 202 ...... 243 ...... 1 L 30 L A 12, 13, 

25, 40

Chloromethyl chloroformate ............................................................................................................ 6.1 UN2745 II 6.1, 8 IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L A 12, 13, 

21, 25, 

40, 100

Chloromethyl ethyl ether ................................................................................................................. 3 UN2354 II 3, 6.1 IB2, T7, TP1, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Chloronitroanilines ........................................................................................................................... 6.1 UN2237 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

+ Chloronitrobenzene, liquid ortho ..................................................................................................... 6.1 UN3409 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76083

+ Chloronitrobenzenes, solid meta or para ........................................................................................ 6.1 UN1578 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Chloronitrotoluenes, liquid ............................................................................................................... 6.1 UN2433 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 44, 89, 

100, 

141

Chloronitrotoluenes, solid ................................................................................................................ 6.1 UN3457 III 6.1 ..... IB8, IP3,T1, 

TP33

153 ...... 213 ...... 240 ...... 25 kg 200 kg A ............

Chloropentafluoroethane or Refrigerant gas R 115 ........................................................................ 2.2 UN1020 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Chlorophenolates, liquid or Phenolates, liquid ................................................................................ 8 UN2904 III 8 ........ IB3 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Chlorophenolates, solid or Phenolates, solid .................................................................................. 8 UN2905 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Chlorophenols, liquid ....................................................................................................................... 6.1 UN2021 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Chlorophenols, solid ........................................................................................................................ 6.1 UN2020 III 6.1 ..... IB8, IP3, T1, 

TP1, TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Chlorophenyltrichlorosilane ............................................................................................................. 8 UN1753 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2

None .... 202 ...... 242 ...... Forbidden 30 L C 40

+ Chloropicrin ..................................................................................................................................... 6.1 UN1580 I 6.1 ..... 2, B7, B9, B14, 

B32, B46, B74, 

T20, TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Chloropicrin and methyl bromide mixtures ..................................................................................... 2.3 UN1581 ............ 2.3 ..... 2, B9, B14, T50 None .... 193 ...... 314, 

315.

Forbidden Forbidden D 25, 40

Chloropicrin and methyl chloride mixtures ...................................................................................... 2.3 UN1582 ............ 2.3 ..... 2, T50 None .... 193 ...... 245 ...... Forbidden Forbidden D 25, 40Chloropicrin mixture, flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point 

below 100 degrees F) see Toxic liquids, flammable, etc.

.................... ........... .......... .......... .......... .................... .................... ............

Chloropicrin mixtures, n.o.s. ............................................................................................................ 6.1 UN1583 I 6.1 ..... 5 None .... 201 ...... 243 ...... Forbidden Forbidden C 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... Forbidden Forbidden C 40.......................................................................................................................................................... .................... III 6.1 ..... IB3 153 ...... 203 ...... 241 ...... Forbidden Forbidden C 40

D Chloropivaloyl chloride .................................................................................................................... 6.1 NA9263 I 6.1, 8 2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden B 40

Chloroplatinic acid, solid ................................................................................................................. 8 UN2507 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Chloroprene, stabilized .................................................................................................................... 3 UN1991 I 3, 6.1 B57, T14, TP2, 

TP13

None .... 201 ...... 243 ...... Forbidden 30 L D 40

Chloroprene, uninhibited ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............1-Chloropropane .............................................................................................................................. 3 UN1278 II 3 ........ IB2, IP8, N34, 

T7, TP2

None .... 202 ...... 242 ...... Forbidden 60 L E ............

2-Chloropropane .............................................................................................................................. 3 UN2356 I 3 ........ N36, T11, TP2, 

TP13

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

3-Chloropropanol-1 .......................................................................................................................... 6.1 UN2849 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............2-Chloropropene .............................................................................................................................. 3 UN2456 I 3 ........ A3, N36, T11, 

TP2

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

2-Chloropropionic acid .................................................................................................................... 8 UN2511 III 8 ........ IB3, T4, TP2 154 ...... 203 ...... 241 ...... 5 L 60 L A 82-Chloropyridine .............................................................................................................................. 6.1 UN2822 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40Chlorosilanes, corrosive, flammable, n.o.s. .................................................................................... 8 UN2986 II 8, 3 .... IB2, T11, TP2, 

TP27

None .... 202 ...... 243 ...... 1 L 30 L C 40

Chlorosilanes, corrosive, n.o.s. ....................................................................................................... 8 UN2987 II 8 ........ B2, IB2, T14, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Chlorosilanes, flammable, corrosive, n.o.s. .................................................................................... 3 UN2985 II 3, 8 .... IB1, T11, TP2, 

TP13, TP27

150 ...... 201 ...... 243 ...... 1 L 5 L B 40

Chlorosilanes, toxic, corrosive, n.o.s. ............................................................................................. 6.1 UN3361 II 6.1, 8 IB1, T11, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L C 40

Chlorosilanes, toxic, corrosive, flammable, n.o.s. ........................................................................... 6.1 UN3362 II 6.1, 3, 

8.

IB1, T11, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L C 40, 125

Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. ........................................................... 4.3 UN2988 I 4.3, 3, 

8.

A2, T10, TP2, 

TP7, TP13

None .... 201 ...... 244 ...... Forbidden 1 L D 21, 28, 

40, 49, 

100

+ Chlorosulfonic acid (with or without sulfur trioxide) ........................................................................ 8 UN1754 I 8, 6.1 2, B9, B10, B14, 

B32, B74, T20, 

TP2, TP12, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden C 40

Chlorotoluenes ................................................................................................................................ 3 UN2238 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Chlorotoluidines, liquid .................................................................................................................... 6.1 UN3429 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Chlorotoluidines, solid ..................................................................................................................... 6.1 UN2239 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with 

approximately 60 percent chlorotrifluoromethane.

2.2 UN2599 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Chlorotrifluoromethane or Refrigerant gas R 13 ............................................................................. 2.2 UN1022 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

76084 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Chromic acid solution ...................................................................................................................... 8 UN1755 II 8 ........ B2, IB2, T8, TP2, 

TP12

154 ...... 202 ...... 242 ...... 1 L 30 L C 40, 44, 

89, 

100, 

141

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1, 

TP12

154 ...... 203 ...... 241 ...... 5 L 60 L C 40, 44, 

89, 

100, 

141

Chromic anhydride, see Chromium trioxide, anhydrous ................................................................. .................... ........... .......... .......... .......... .................... .................... ............Chromic fluoride, solid ..................................................................................................................... 8 UN1756 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 52

Chromic fluoride, solution ................................................................................................................ 8 UN1757 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Chromium nitrate ............................................................................................................................. 5.1 UN2720 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Chromium oxychloride ..................................................................................................................... 8 UN1758 I 8 ........ A3, A6, A7, B10, 

N34, T10, TP2, 

TP12

None .... 201 ...... 243 ...... 0.5 L 2.5 L C 40, 66, 

74, 89, 

90

Chromium trioxide, anhydrous ........................................................................................................ 5.1 UN1463 II 5.1, 8 IB8, IP4, T3, 

TP33

None .... 212 ...... 242 ...... 5 kg 25 kg A ............

Chromosulfuric acid ......................................................................................................................... 8 UN2240 I 8 ........ A3, A6, A7, B4, 

B6, N34, T10, 

TP2, TP12, TP13

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40, 66, 

74, 89, 

90

Chromyl chloride, see Chromium oxychloride ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Cigar and cigarette lighters, charged with fuel, see Lighters or Lighter refills containing flammable gas.. .................... ........... .......... .......... .......... .................... .................... ............Coal briquettes, hot ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Coal gas, compressed .................................................................................................................... 2.3 UN1023 ............ 2.3, 

2.1.

3 None .... 302 ...... 314, 

315.

Forbidden Forbidden D 40

Coal tar distillates, flammable ......................................................................................................... 3 UN1136 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or solid, n.o.s. or Dye intermediates, liquid or solid, corrosive, n.o.s.. .................... ........... .......... .......... .......... .................... .................... ............Coating solution (includes surface treatments or coatings used for industrial or other purposes 

such as vehicle undercoating, drum or barrel lining).

3 UN1139 I 3 ........ T11, TP1, TP8, 

TP27

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Cobalt naphthenates, powder ......................................................................................................... 4.1 UN2001 III 4.1 ..... A19, IB8, IP3, 

T1, TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Cobalt resinate, precipitated ........................................................................................................... 4.1 UN1318 III 4.1 ..... A1, A19, IB6, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Coke, hot ......................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Collodion, see Nitrocellulose etc ..................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

D G Combustible liquid, n.o.s. ................................................................................................................ Comb liq NA1993 III None IB3, T1, T4, TP1 150 ...... 203 ...... 241 ...... 60 L 220 L A ............

G Components, explosive train, n.o.s. ................................................................................................ 1.2B UN0382 II 1.2B ... 101 None .... 62 ........ None .... Forbidden Forbidden 11 ............G Components, explosive train, n.o.s. ................................................................................................ 1.4B UN0383 II 1.4B ... 101 None .... 62 ........ None .... Forbidden 75 kg 06 ............G Components, explosive train, n.o.s. ................................................................................................ 1.4S UN0384 II 1.4S ... 101 None .... 62 ........ None .... 25 kg 100 kg 05 ............G Components, explosive train, n.o.s. ................................................................................................ 1.1B UN0461 II 1.1B ... 101 None .... 62 ........ None .... Forbidden Forbidden 11 ............

Composition B, see Hexolite, etc .................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

D G Compounds, cleaning liquid ............................................................................................................ 8 NA1760 I 8 ........ A7, B10, T14, 

TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, N37, 

T11, TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... III 8 ........ IB3, N37, T7, 

TP1, TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40

D G Compounds, cleaning liquid ............................................................................................................ 3 NA1993 I 3 ........ T11, TP1 150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

D G Compounds, tree killing, liquid or Compounds, weed killing, liquid ............................................... 8 NA1760 I 8 ........ A7, B10, T14, 

TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76085

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, N37, 

T11, TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... III 8 ........ IB3, N37, T7, 

TP1, TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40

D G Compounds, tree killing, liquid or Compounds, weed killing, liquid ............................................... 3 NA1993 I 3 ........ T11, TP1 150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

D G Compounds, tree killing, liquid or Compounds, weed killing, liquid ............................................... 6.1 NA2810 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

G Compressed gas, flammable, n.o.s. ............................................................................................... 2.1 UN1954 ............ 2.1 ..... 306 ...... 302, 

305.

314, 

315.

Forbidden 150 kg D 40

G Compressed gas, n.o.s. .................................................................................................................. 2.2 UN1956 ............ 2.2 ..... 306, 

307.

302, 

305.

314, 

315.

75 kg 150 kg A ............

G Compressed gas, oxidizing, n.o.s. .................................................................................................. 2.2 UN3156 ............ 2.2, 

5.1.

A14 306 ...... 302 ...... 314, 

315.

75 kg 150 kg D ............

G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A ............................................. 2.3 UN3304 ............ 2.3, 8 1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B ............................................. 2.3 UN3304 ............ 2.3, 8 2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C ............................................. 2.3 UN3304 ............ 2.3, 8 3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D ............................................. 2.3 UN3304 ............ 2.3, 8 4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A .......................... 2.3 UN3305 ............ 2.3, 

2.1, 8.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 17, 40

G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B .......................... 2.3 UN3305 ............ 2.3, 

2.1, 8.

2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 17, 40

G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C .......................... 2.3 UN3305 ............ 2.3, 

2.1, 8.

3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 17, 40

G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D .......................... 2.3 UN3305 ............ 2.3, 

2.1, 8.

4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 17, 40

G Compressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone A ............................................ 2.3 UN1953 ............ 2.3, 

2.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

G Compressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone B ............................................ 2.3 UN1953 ............ 2.3, 

2.1.

2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C ........................................... 2.3 UN1953 ............ 2.3, 

2.1.

3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D ........................................... 2.3 UN1953 ............ 2.3, 

2.1.

4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone A .............................................................. 2.3 UN1955 ............ 2.3 ..... 1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone B .............................................................. 2.3 UN1955 ............ 2.3 ..... 2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone C .............................................................. 2.3 UN1955 ............ 2.3 ..... 3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone D .............................................................. 2.3 UN1955 ............ 2.3 ..... 4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G I Compressed gas, toxic, oxdizing, corrosive, n.o.s. Inhalation Hazard Zone A .............................. 2.3 UN3306 ............ 2.3, 

5.1, 8.

1 None .... 192 ...... 244 ...... Forbidden Forbidden D 40, 89, 

90

G I Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B ............................. 2.3 UN3306 ............ 2.3, 

5.1, 8.

2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40, 89, 

90

G I Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C ............................. 2.3 UN3306 ............ 2.3, 

5.1, 8.

3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40, 89, 

90

G I Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D ............................. 2.3 UN3306 ............ 2.3, 

5.1, 8.

4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40, 89, 

90

G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A .............................................. 2.3 UN3303 ............ 2.3, 

5.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B .............................................. 2.3 UN3303 ............ 2.3, 

5.1.

2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C .............................................. 2.3 UN3303 ............ 2.3, 

5.1.

3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D .............................................. 2.3 UN3303 ............ 2.3, 

5.1.

4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

76086 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

D Consumer commodity ..................................................................................................................... ORM-D ............ None 156, 

306.

156, 

306.

None .... 30 kg gross 30 kg gross A ............

Contrivances, water-activated, with burster, expelling charge or propelling charge ...................... 1.2L UN0248 II 1.2L ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 

15E, 

17E 

Contrivances, water-activated, with burster, expelling charge or propelling charge ...................... 1.3L UN0249 II 1.3L ... 101 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 

15E, 

17E 

Copper acetoarsenite ...................................................................................................................... 6.1 UN1585 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Copper acetylide ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Copper amine azide ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Copper arsenite ............................................................................................................................... 6.1 UN1586 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ................ 3 UN2776 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Copper based pesticides, liquid, toxic ............................................................................................ 6.1 UN3010 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Copper based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C .......... 6.1 UN3009 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Copper based pesticides, solid, toxic ............................................................................................. 6.1 UN2775 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Copper chlorate ............................................................................................................................... 5.1 UN2721 II 5.1 ..... A1, IB8, IP2, IP4, 

T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Copper chloride ............................................................................................................................... 8 UN2802 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Copper cyanide ............................................................................................................................... 6.1 UN1587 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 204 ...... 242 ...... 25 kg 100 kg A 52

Copper selenate, see Selenates or Selenites ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Copper selenite, see Selenates or Selenites .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Copper tetramine nitrate ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............

A W Copra ............................................................................................................................................... 4.2 UN1363 III 4.2 ..... IB8, IP3, IP7 None .... 213 ...... 241 ...... Forbidden Forbidden A 13, 19, 

48, 119

Cord, detonating, flexible ................................................................................................................ 1.1D UN0065 II 1.1D .. 102 63(a) .... 62 ........ None .... Forbidden Forbidden 07 ............Cord, detonating, flexible ................................................................................................................ 1.4D UN0289 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cord detonating or Fuse detonating metal clad ............................................................................. 1.2D UN0102 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cord, detonating or Fuse, detonating metal clad ........................................................................... 1.1D UN0290 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Cord, detonating, mild effect or Fuse, detonating, mild effect metal clad ...................................... 1.4D UN0104 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cord, igniter ..................................................................................................................................... 1.4G UN0066 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Cordeau detonant fuse, see Cord, detonating, etc; Cord, detonating, flexible .............................. .................... ........... .......... .......... .......... .................... .................... ............Cordite, see Powder, smokeless .................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

G Corrosive liquid, acidic, inorganic, n.o.s. ........................................................................................ 8 UN3264 I 8 ........ A6, B10, T14, 

TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

.......................................................................................................................................................... .................... II 8 ........ A6, B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40

G Corrosive liquid, acidic, organic, n.o.s. ........................................................................................... 8 UN3265 I 8 ........ A6, B10, T14, 

TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76087

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40

G Corrosive liquid, basic, inorganic, n.o.s. ......................................................................................... 8 UN3266 I 8 ........ A6, T14, TP2, 

TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40, 52

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40, 52

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40, 52

G Corrosive liquid, basic, organic, n.o.s. ............................................................................................ 8 UN3267 I 8 ........ A6, B10, T14, 

TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40, 52

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40, 52

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40, 52

G Corrosive liquid, self-heating, n.o.s. ................................................................................................ 8 UN3301 I 8, 4.2 A6, B10 None .... 201 ...... 243 ...... 0.5 L 2.5 L D ............

.......................................................................................................................................................... .................... II 8, 4.2 B2, IB1 154 ...... 202 ...... 242 ...... 1 L 30 L D ............

G Corrosive liquids, flammable, n.o.s. ................................................................................................ 8 UN2920 I 8, 3 .... A6, B10, T14, 

TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L C 25, 40

.......................................................................................................................................................... .................... II 8, 3 .... B2, IB2, T11, 

TP2, TP27

None .... 202 ...... 243 ...... 1 L 30 L C 25, 40

G Corrosive liquids, n.o.s. ................................................................................................................... 8 UN1760 I 8 ........ A6, A7, B10, 

T14, TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

.......................................................................................................................................................... .................... II 8 ........ B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... III 8 ........ IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A 40

G Corrosive liquids, oxidizing, n.o.s. ................................................................................................... 8 UN3093 I 8, 5.1 A6, A7 None .... 201 ...... 243 ...... Forbidden 2.5 L C 89

.......................................................................................................................................................... .................... II 8, 5.1 A6, A7, IB2 None .... 202 ...... 243 ...... 1 L 30 L C 89

G Corrosive liquids, toxic, n.o.s. ......................................................................................................... 8 UN2922 I 8, 6.1 A7, A6, B10, 

T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

.......................................................................................................................................................... .................... II 8, 6.1 B3, IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L B 40.......................................................................................................................................................... .................... III 8, 6.1 IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L B 40

G Corrosive liquids, water-reactive, n.o.s. .......................................................................................... 8 UN3094 I 8, 4.3 A6, A7 None .... 201 ...... 243 ...... Forbidden 1 L E ............

.......................................................................................................................................................... .................... II 8, 4.3 A6, A7 None .... 202 ...... 243 ...... 1 L 5 L E ............

G Corrosive solid, acidic, inorganic, n.o.s. ......................................................................................... 8 UN3260 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg B ............

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

G Corrosive solid, acidic, organic, n.o.s. ............................................................................................ 8 UN3261 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg B ............

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

G Corrosive solid, basic, inorganic, n.o.s. .......................................................................................... 8 UN3262 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg B 52

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B 52

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 52

G Corrosive solid, basic, organic, n.o.s. ............................................................................................. 8 UN3263 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg B 52

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B 52

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 52

G Corrosive solids, flammable, n.o.s. ................................................................................................. 8 UN2921 I 8, 4.1 IB6, T6, TP33 None .... 211 ...... 242 ...... 1 kg 25 kg B 12, 25

.......................................................................................................................................................... .................... II 8, 4.1 IB8, IP2, IP4, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg B 12, 25

G Corrosive solids, n.o.s. .................................................................................................................... 8 UN1759 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg B ............

.......................................................................................................................................................... .................... II 8 ........ 128, IB8, IP2, 

IP4, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

.......................................................................................................................................................... .................... III 8 ........ 128, IB8, IP3, 

T1, TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

G Corrosive solids, oxidizing, n.o.s. .................................................................................................... 8 UN3084 I 8, 5.1 T6, TP33 None .... 211 ...... 242 ...... 1 kg 25 kg C ............

.......................................................................................................................................................... .................... II 8, 5.1 IB6, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg C ............

G Corrosive solids, self-heating, n.o.s. ............................................................................................... 8 UN3095 I 8, 4.2 T6, TP33 None .... 211 ...... 243 ...... 1 kg 25 kg C ............

76088 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... II 8, 4.2 IB6, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg C ............

G Corrosive solids, toxic, n.o.s. .......................................................................................................... 8 UN2923 I 8, 6.1 IB7, T6, TP33 None .... 211 ...... 242 ...... 1 kg 25 kg B 40

.......................................................................................................................................................... .................... II 8, 6.1 IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B 40

.......................................................................................................................................................... .................... III 8, 6.1 IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg B 40, 95

G Corrosive solids, water-reactive, n.o.s. ........................................................................................... 8 UN3096 I 8, 4.3 IB4, IP1, T6, 

TP33

None .... 211 ...... 243 ...... 1 kg 25 kg D ............

.......................................................................................................................................................... .................... II 8, 4.3 IB6, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg D ............

D W Cotton .............................................................................................................................................. 9 NA1365 ............ 9 ........ 137, IB8, IP2, 

IP4, W41

None .... None .... None .... No limit No limit A ............

A W Cotton waste, oily ............................................................................................................................ 4.2 UN1364 III 4.2 ..... IB8, IP3, IP7 None .... 213 ...... None .... Forbidden Forbidden A 54

A I W Cotton, wet ...................................................................................................................................... 4.2 UN1365 III 4.2 ..... IB8, IP3, IP7 None .... 204 ...... 241 ...... Forbidden Forbidden A ............

Coumarin derivative pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ...... 3 UN3024 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Coumarin derivative pesticides, liquid, toxic ................................................................................... 6.1 UN3026 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Coumarin derivative pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3025 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP1, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Coumarin derivative pesticides, solid, toxic .................................................................................... 6.1 UN3027 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Cresols, liquid .................................................................................................................................. 6.1 UN2076 II 6.1, 8 IB2, IP2, IP4, T7, 

TP2

153 ...... 202 ...... 243 ...... 1 L 30 L B ............

Cresols, solid ................................................................................................................................... 6.1 UN3455 II 6.1, 8 IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg B ............

Cresylic acid .................................................................................................................................... 6.1 UN2022 II 6.1, 8 IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L B ............

Crotonaldehyde, stabilized .............................................................................................................. 6.1 UN1143 I 6.1, 3 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden B 40

Crotonic acid liquid .......................................................................................................................... 8 UN2823 III 8 ........ IB8, T1 154 ...... 203 ...... 241 ...... 5 L 60 L A 12Crotonic acid, solid .......................................................................................................................... 8 UN2823 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 12

Crotonylene ..................................................................................................................................... 3 UN1144 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E ............Cupriethylenediamine solution ........................................................................................................ 8 UN1761 II 8, 6.1 IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8, 6.1 IB3, T7, TP1, 

TP28

154 ...... 203 ...... 242 ...... 5 L 60 L A 95

Cutters, cable, explosive ................................................................................................................. 1.4S UN0070 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Cyanide or cyanide mixtures, dry, see Cyanides, inorganic, solid, n.o.s. ...................................... .................... ........... .......... .......... .......... .................... .................... ............Cyanide solutions, n.o.s. ................................................................................................................. 6.1 UN1935 I 6.1 ..... B37, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40, 52

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L A 40, 52

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP13, TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40, 52

Cyanides, inorganic, solid, n.o.s. .................................................................................................... 6.1 UN1588 I 6.1 ..... IB7, IP1, N74, 

N75, T6, TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 52

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76089

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, 

N74, N75, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, N74, 

N75, T1, TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Cyanogen ........................................................................................................................................ 2.3 UN1026 ............ 2.3, 

2.1.

2 None .... 304 ...... 245 ...... Forbidden Forbidden D 40

Cyanogen bromide .......................................................................................................................... 6.1 UN1889 I 6.1, 8 A6, A8, T6, TP33 None .... 211 ...... 242 ...... 1 kg 15 kg D 40Cyanogen chloride, stabilized ......................................................................................................... 2.3 UN1589 ............ 2.3, 8 1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40Cyanuric chloride ............................................................................................................................. 8 UN2670 II 8 ........ IB8, IP2, IP4, T3, 

TP33

None .... 212 ...... 240 ...... 15 kg 50 kg A 12, 40

Cyanuric triazide .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Cyclobutane ..................................................................................................................................... 2.1 UN2601 ............ 2.1 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Cyclobutyl chloroformate ................................................................................................................. 6.1 UN2744 II 6.1, 8, 

3.

IB1, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L A 12, 13, 

21, 25, 

40, 100

1,5,9-Cyclododecatriene .................................................................................................................. 6.1 UN2518 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 40Cycloheptane ................................................................................................................................... 3 UN2241 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Cycloheptatriene .............................................................................................................................. 3 UN2603 II 3, 6.1 IB2, T7, TP1, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Cycloheptene ................................................................................................................................... 3 UN2242 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Cyclohexane .................................................................................................................................... 3 UN1145 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Cyclohexanone ................................................................................................................................ 3 UN1915 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Cyclohexene .................................................................................................................................... 3 UN2256 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Cyclohexenyltrichlorosilane ............................................................................................................. 8 UN1762 II 8 ........ A7, B2, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Cyclohexyl acetate .......................................................................................................................... 3 UN2243 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Cyclohexyl isocyanate ..................................................................................................................... 6.1 UN2488 I 6.1, 3 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Cyclohexyl mercaptan ..................................................................................................................... 3 UN3054 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40, 95Cyclohexylamine ............................................................................................................................. 8 UN2357 II 8, 3 .... IB2, T7, TP2 None .... 202 ...... 243 ...... 1 L 30 L A 40Cyclohexyltrichlorosilane ................................................................................................................. 8 UN1763 II 8 ........ A7, B2, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Cyclonite and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and 

HMX mixtures, wetted or desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Cyclonite and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or

desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Cyclonite and octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or

desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Cyclonite, see Cyclotrimethylenetrinitramine, etc ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Cyclooctadiene phosphines, see 9-Phosphabicyclononanes ......................................................... .................... ........... .......... .......... .......... .................... .................... ............Cyclooctadienes .............................................................................................................................. 3 UN2520 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Cyclooctatetraene ............................................................................................................................ 3 UN2358 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Cyclopentane ................................................................................................................................... 3 UN1146 II 3 ........ IB2, T7, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Cyclopentane, methyl, see Methylcyclopentane ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Cyclopentanol .................................................................................................................................. 3 UN2244 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Cyclopentanone ............................................................................................................................... 3 UN2245 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Cyclopentene ................................................................................................................................... 3 UN2246 II 3 ........ IB2, IP8, T7, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Cyclopropane .................................................................................................................................. 2.1 UN1027 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Cyclotetramethylene tetranitramine (dry or unphlegmatized) (HMX) ............................................. Forbidden ........... .......... .......... .......... .................... .................... ............Cyclotetramethylenetetranitramine, desensitized or Octogen, desensitized or HMX, desensitized 1.1D UN0484 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Cyclotetramethylenetetranitramine, wetted or HMX, wetted or Octogen, wetted with not less 

than 15 percent water, by mass.

1.1D UN0226 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

Cyclotrimethylenetrinitramine and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. .................... ........... .......... .......... .......... .................... .................... ............Cyclotrimethylenenitramine and octogen, mixtures, wetted or desensitized see RDX and HMX 

mixtures, wetted or desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Cyclotrimethylenetrinitramine and HMX mixtures, wetted or desensitized see RDX and HMX 

mixtures, wetted or desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Cyclotrimethylenetrinitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized 

or RDX, desensitized.

1.1D UN0483 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted 

with not less than 15 percent water by mass.

1.1D UN0072 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

Cymenes ......................................................................................................................................... 3 UN2046 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Dangerous Goods in Machinery or Dangerous Goods in Apparatus ............................................. 9 UN3363 ............ ........... 136 None .... 222 ...... None .... No limit No limit A ............Decaborane ..................................................................................................................................... 4.1 UN1868 II 4.1, 

6.1.

A19, A20, IB6, 

IP2, T3, TP33

None .... 212 ...... None .... Forbidden 50 kg A 74

Decahydronaphthalene ................................................................................................................... 3 UN1147 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............n-Decane ......................................................................................................................................... 3 UN2247 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

76090 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Deflagrating metal salts of aromatic nitroderivatives, n.o.s. ........................................................... 1.3C UN0132 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 5E Delay electric igniter, see Igniters ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Depth charges, see Charges, depth ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

G Desensitized explosive, liquid, n.o.s. .............................................................................................. 3 UN3379 I 3 ........ 164 None .... 201 ...... None .... Forbidden Forbidden D 36G Desensitized explosive, solid, n.o.s. ............................................................................................... 4.1 UN3380 I 4.1 ..... 164 None .... 211 ...... None .... Forbidden Forbidden D 28, 36

Detonating relays, see Detonators, etc ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Detonator assemblies, non-electric for blasting .............................................................................. 1.1B UN0360 II 1.1B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Detonator assemblies, non-electric, for blasting ............................................................................. 1.4B UN0361 II 1.4B ... 103 63(f), 

63(g).

62 ........ None .... Forbidden 75 kg 06 ............

Detonator, assemblies, non-electric for blasting ............................................................................. 1.4S UN0500 II 1.4S ... 63(f), 

63(g).

62 ........ None .... 25 kg 100 kg 05 ............

Detonators, electric, for blasting ..................................................................................................... 1.1B UN0030 II 1.1B ... 63(f), 

63(g).

62 ........ None .... Forbidden Forbidden 11 ............

Detonators, electric, for blasting ..................................................................................................... 1.4B UN0255 II 1.4B ... 103 63(f), 

63(g).

62 ........ None .... Forbidden 75 kg 06 ............

Detonators, electric for blasting ...................................................................................................... 1.4S UN0456 II 1.4S ... 63(f), 

63(g).

62 ........ None .... 25 kg 100 kg 05 ............

Detonators for ammunition .............................................................................................................. 1.1B UN0073 II 1.1B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Detonators for ammunition .............................................................................................................. 1.2B UN0364 II 1.2B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Detonators for ammunition .............................................................................................................. 1.4B UN0365 II 1.4B ... 103 None .... 62 ........ None .... Forbidden 75 kg 06 ............Detonators for ammunition .............................................................................................................. 1.4S UN0366 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Detonators, non-electric, for blasting .............................................................................................. 1.1B UN0029 II 1.1B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Detonators, non-electric, for blasting .............................................................................................. 1.4B UN0267 II 1.4B ... 103 63(f), 

63(g).

62 ........ None .... Forbidden 75 kg 06 ............

Detonators, non-electric,for blasting ............................................................................................... 1.4S UN0455 II 1.4S ... 63(f), 

63(g).

62 ........ None .... 25 kg 100 kg 5 ............

Deuterium, compressed .................................................................................................................. 2.1 UN1957 ............ 2.1 ..... 306 ...... 302 ...... None .... Forbidden 150 kg E 40Devices, small, hydrocarbon gas powered or Hydrocarbon gas refills for small devices with release device. 2.1 UN3150 ............ 2.1 ..... 306 ...... 304 ...... None .... 1 kg 15 kg B 40Di-n-amylamine ............................................................................................................................... 3 UN2841 III 3, 6.1 B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Di-n-butyl peroxydicarbonate, with more than 52 percent in solution ............................................ Forbidden ........... .......... .......... .......... .................... .................... ............Di-n-butylamine ............................................................................................................................... 8 UN2248 II 8, 3 .... IB2, T7, TP2 None .... 202 ...... 243 ...... 1 L 30 L A ............2,2-Di-(tert-butylperoxy) butane, with more than 55 percent in solution ........................................ Forbidden ........... .......... .......... .......... .................... .................... ............Di-(tert-butylperoxy) phthalate, with more than 55 percent in solution ........................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more than 42 percent with inert solid .... Forbidden ........... .......... .......... .......... .................... .................... ............Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent with water ........................................ Forbidden ........... .......... .......... .......... .................... .................... ............1,2-Di-(dimethylamino)ethane ......................................................................................................... 3 UN2372 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Di-2-ethylhexyl phosphoric acid, see Diisooctyl acid phosphate .................................................... .................... ........... .......... .......... .......... .................... .................... ............Di-(1-hydroxytetrazole) (dry) ........................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Di-(1-naphthoyl) peroxide ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............a,a’-Di-(nitroxy) methylether ............................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Di-(beta-nitroxyethyl) ammonium nitrate ......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diacetone alcohol ............................................................................................................................ 3 UN1148 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Diacetone alcohol peroxides, with more than 57 percent in solution with more than 9 percent 

hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass.

Forbidden ........... .......... .......... .......... .................... .................... ............

Diacetyl, see Butanedione .............................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Diacetyl peroxide, solid, or with more than 25 percent in solution ................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Diagnostic specimen ....................................................................................................................... 6.2 ............ ........... A82 134 ...... 199 ...... None .... 4 L or 4 kg 4 L or 4 kg A 40Diallylamine ..................................................................................................................................... 3 UN2359 II 3, 6.1, 

8.

IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 21, 40, 

100

Diallylether ....................................................................................................................................... 3 UN2360 II 3, 6.1 IB2, N12, T7, 

TP1, TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

4,4’-Diaminodiphenyl methane ........................................................................................................ 6.1 UN2651 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

p-Diazidobenzene ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............1,2-Diazidoethane ........................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............1,1’-Diazoaminonaphthalene ........................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diazoaminotetrazole (dry) ............................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diazodinitrophenol (dry) .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Diazodinitrophenol, wetted with not less than 40 percent water or mixture of alcohol and water, 

by mass.

1.1A UN0074 II 1.1A ... 111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............

Diazodiphenylmethane .................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diazonium nitrates (dry) .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76091

Diazonium perchlorates (dry) .......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............1,3-Diazopropane ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Dibenzyl peroxydicarbonate, with more than 87 percent with water .............................................. Forbidden ........... .......... .......... .......... .................... .................... ............Dibenzyldichlorosilane ..................................................................................................................... 8 UN2434 II 8 ........ B2, IB2, T7, TP2, 

TP13

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Diborane .......................................................................................................................................... 2.3 UN1911 ............ 2.3, 

2.1.

1 None .... 302 ...... None .... Forbidden Forbidden D 40, 57

D Diborane mixtures ........................................................................................................................... 2.1 NA1911 ............ 2.1 ..... 5 None .... 302 ...... 245 ...... Forbidden Forbidden D 40, 57

Dibromoacetylene ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............1,2-Dibromobutan-3-one ................................................................................................................. 6.1 UN2648 II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... 5 L 60 L B 40Dibromochloropropane .................................................................................................................... 6.1 UN2872 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

A Dibromodifluoromethane, R12B2 .................................................................................................... 9 UN1941 III None T11, TP2 155 ...... 203 ...... 241 ...... 100 L 220 L A 25

1,2-Dibromoethane, see Ethylene dibromide .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Dibromomethane ............................................................................................................................. 6.1 UN2664 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Dibutyl ethers .................................................................................................................................. 3 UN1149 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Dibutylaminoethanol ........................................................................................................................ 6.1 UN2873 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............N,N’-Dichlorazodicarbonamidine (salts of) (dry) ............................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............1,1-Dichloro-1-nitroethane ............................................................................................................... 6.1 UN2650 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 12, 40, 

74

D 3,5-Dichloro-2,4,6-trifluoropyridine .................................................................................................. 6.1 NA9264 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A 40

Dichloroacetic acid .......................................................................................................................... 8 UN1764 II 8 ........ A3, A6, A7, B2, 

IB2, N34, T8, 

TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

1,3-Dichloroacetone ........................................................................................................................ 6.1 UN2649 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 12, 40

Dichloroacetyl chloride .................................................................................................................... 8 UN1765 II 8 ........ A3, A6, A7, B2, 

B6, IB2, N34, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L D 40

Dichloroacetylene ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............

+ Dichloroanilines, liquid ..................................................................................................................... 6.1 UN1590 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40

Dichloroanilines, solid ...................................................................................................................... 6.1 UN3442 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

+ o-Dichlorobenzene .......................................................................................................................... 6.1 UN1591 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

2,2’-Dichlorodiethyl ether ................................................................................................................. 6.1 UN1916 II 6.1, 3 IB2, N33, N34, 

T7, TP2

153 ...... 202 ...... 243 ...... 5 L 60 L A ............

Dichlorodifluoromethane and difluoroethane azeotropic mixture or Refrigerant gas R 500 with 

approximately 74 percent dichlorodifluoromethane.

2.2 UN2602 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Dichlorodifluoromethane or Refrigerant gas R 12 .......................................................................... 2.2 UN1028 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Dichlorodimethyl ether, symmetrical ............................................................................................... 6.1 UN2249 I 6.1, 3 None .... 201 ...... 243 ...... Forbidden Forbidden 401,1-Dichloroethane .......................................................................................................................... 3 UN2362 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 401,2-Dichloroethane, see Ethylene dichloride .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Dichloroethyl sulfide ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............1,2-Dichloroethylene ........................................................................................................................ 3 UN1150 II 3 ........ IB2, T7, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Dichlorofluoromethane or Refrigerant gas R21 .............................................................................. 2.2 UN1029 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts ..................................................... 5.1 UN2465 II 5.1 ..... 28, IB8, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 13

Dichloroisopropyl ether .................................................................................................................... 6.1 UN2490 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L B ............Dichloromethane ............................................................................................................................. 6.1 UN1593 III 6.1 ..... IB3, IP8, N36, 

T7, TP2

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Dichloropentanes ............................................................................................................................. 3 UN1152 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Dichlorophenyl isocyanates ............................................................................................................. 6.1 UN2250 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 25, 40, 

48

Dichlorophenyltrichlorosilane ........................................................................................................... 8 UN1766 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

1,2-Dichloropropane ........................................................................................................................ 3 UN1279 II 3 ........ IB2, N36, T4, 

TP1

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

1,3-Dichloropropanol-2 .................................................................................................................... 6.1 UN2750 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 12, 40Dichloropropene and propylene dichloride mixture, see 1,2- Dichloropropane ............................. .................... ........... .......... .......... .......... .................... .................... ............Dichloropropenes ............................................................................................................................ 3 UN2047 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Dichlorosilane .................................................................................................................................. 2.3 UN2189 ............ 2.3, 

2.1, 8.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 17, 40

1,2-Dichloro-1,1,2,2- tetrafluoroethane or Refrigerant gas R 114 .................................................. 2.2 UN1958 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Dichlorovinylchloroarsine ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Dicycloheptadiene, see Bicyclo [2,2,1] hepta-2,5-diene, stabilized ................................................ .................... ........... .......... .......... .......... .................... .................... ............Dicyclohexylamine ........................................................................................................................... 8 UN2565 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

76092 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Dicyclohexylammonium nitrite ......................................................................................................... 4.1 UN2687 III 4.1 ..... IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A 48

Dicyclopentadiene ........................................................................................................................... 3 UN2048 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Didymium nitrate ............................................................................................................................. 5.1 UN1465 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

D Diesel fuel ........................................................................................................................................ 3 NA1993 III None 144, B1, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

I Diesel fuel ........................................................................................................................................ 3 UN1202 III 3 ........ 144, B1, IB3, T2, 

TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Diethanol nitrosamine dinitrate (dry) ............................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diethoxymethane ............................................................................................................................. 3 UN2373 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............3,3-Diethoxypropene ....................................................................................................................... 3 UN2374 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Diethyl carbonate ............................................................................................................................ 3 UN2366 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Diethyl cellosolve, see Ethylene glycol diethyl ether ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Diethyl ether or Ethyl ether ............................................................................................................. 3 UN1155 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E 40Diethyl ketone .................................................................................................................................. 3 UN1156 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Diethyl peroxydicarbonate, with more than 27 percent in solution ................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Diethyl sulfate .................................................................................................................................. 6.1 UN1594 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L C ............Diethyl sulfide .................................................................................................................................. 3 UN2375 II 3 ........ IB2, T7, TP1, 

TP13

None .... 202 ...... 243 ...... 5 L 60 L E ............

Diethylamine .................................................................................................................................... 3 UN1154 II 3, 8 .... A3, IB2, N34, T7, 

TP1

150 ...... 202 ...... 243 ...... 1 L 5 L E 40

2-Diethylaminoethanol ..................................................................................................................... 8 UN2686 II 8, 3 .... B2, IB2, T7, TP2 None .... 202 ...... 243 ...... 1 L 30 L A ............3-Diethyamino-propylamine. ............................................................................................................ 3 UN2684 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A ............

+ N, N-Diethylaniline ........................................................................................................................... 6.1 UN2432 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Diethylbenzene ................................................................................................................................ 3 UN2049 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Diethyldichlorosilane ........................................................................................................................ 8 UN1767 II 8, 3 .... A7, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 243 ...... Forbidden 30 L C 40

Diethylene glycol dinitrate ............................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diethyleneglycol dinitrate, desensitized with not less than 25 percent non-volatile water-insoluble phlegmatizer, by mass. 1.1D UN0075 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 13 21E Diethylenetriamine ........................................................................................................................... 8 UN2079 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 40, 52N,N-Diethylethylenediamine ............................................................................................................ 8 UN2685 II 8, 3 .... IB2, T7, TP2 None .... 202 ...... 243 ...... 1 L 30 L A ............Diethylgold bromide ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diethylthiophosphoryl chloride ........................................................................................................ 8 UN2751 II 8 ........ B2, IB2, T7, TP2 None .... 212 ...... 240 ...... 15 kg 50 kg D 12, 40Diethylzinc ....................................................................................................................................... 4.2 UN1366 I 4.2, 

4.3.

B11, T21, TP2, 

TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D 18

Difluorochloroethanes, see 1-Chloro-1,1-difluoroethanes ............................................................... .................... ........... .......... .......... .......... .................... .................... ............1,1-Difluoroethane or Refrigerant gas R 152a ................................................................................ 2.1 UN1030 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

1,1-Difluoroethylene or Refrigerant gas R 1132a ........................................................................... 2.1 UN1959 ............ 2.1 ..... 306 ...... 304 ...... None .... Forbidden 150 kg E 40Difluoromethane or Refrigerant gas R 32 ....................................................................................... 2.1 UN3252 ............ 2.1 ..... T50 306 ...... 302 ...... 314, 

315.

Forbidden 150 kg D 40

Difluorophosphoric acid, anhydrous ................................................................................................ 8 UN1768 II 8 ........ A6, A7, B2, IB2, 

N5, N34, T8, 

TP2, TP12

None .... 202 ...... 242 ...... 1 L 30 L A 40

2,3-Dihydropyran ............................................................................................................................. 3 UN2376 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic acid) .............................................. Forbidden ........... .......... .......... .......... .................... .................... ............Diiodoacetylene ............................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diisobutyl ketone ............................................................................................................................. 3 UN1157 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Diisobutylamine ............................................................................................................................... 3 UN2361 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A ............Diisobutylene, isomeric compounds ................................................................................................ 3 UN2050 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Diisooctyl acid phosphate ............................................................................................................... 8 UN1902 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Diisopropyl ether ............................................................................................................................. 3 UN1159 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E 40Diisopropylamine ............................................................................................................................. 3 UN1158 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............Diisopropylbenzene hydroperoxide, with more than 72 percent in solution ................................... Forbidden ........... .......... .......... .......... .................... .................... ............Diketene, stabilized ......................................................................................................................... 6.1 UN2521 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 26, 27, 

40

1,2-Dimethoxyethane ...................................................................................................................... 3 UN2252 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............1,1-Dimethoxyethane ...................................................................................................................... 3 UN2377 II 3 ........ IB2, T7, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Dimethyl carbonate ......................................................................................................................... 3 UN1161 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Dimethyl chlorothiophosphate, see Dimethyl thiophosphoryl chloride ........................................... .................... ........... .......... .......... .......... .................... .................... ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76093

2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 percent with water ........................... Forbidden ........... .......... .......... .......... .................... .................... ............Dimethyl disulfide ............................................................................................................................ 3 UN2381 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Dimethyl ether ................................................................................................................................. 2.1 UN1033 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Dimethyl-N-propylamine .................................................................................................................. 3 UN2266 II 3, 8 .... IB2, T7, TP2, 

TP13

150 ...... 202 ...... 243 ...... 1 L 5 L B 40

Dimethyl sulfate ............................................................................................................................... 6.1 UN1595 I 6.1, 8 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Dimethyl sulfide ............................................................................................................................... 3 UN1164 II 3 ........ IB2, IP8, T7, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L E 40Dimethyl thiophosphoryl chloride .................................................................................................... 6.1 UN2267 II 6.1, 8 IB2, T7, TP2 153 ...... 202 ...... 243 ...... 1 L 30 L B 25Dimethylamine, anhydrous .............................................................................................................. 2.1 UN1032 ............ 2.1 ..... T50 None .... 304 ...... 314, 

315.

Forbidden 150 kg D 40

Dimethylamine solution ................................................................................................................... 3 UN1160 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............2-Dimethylaminoacetonitrile ............................................................................................................ 3 UN2378 II 3, 6.1 IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 60 L A 52, 402-Dimethylaminoethanol .................................................................................................................. 8 UN2051 II 8, 3 .... B2, IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L A ............2-Dimethylaminoethyl acrylate ........................................................................................................ 6.1 UN3302 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L D 252-Dimethylaminoethyl methacrylate ................................................................................................ 6.1 UN2522 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L B 40N,N-Dimethylaniline ......................................................................................................................... 6.1 UN2253 II 6.1 ..... IB1, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............2,3-Dimethylbutane ......................................................................................................................... 3 UN2457 II 3 ........ IB2, T7, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............1,3-Dimethylbutylamine ................................................................................................................... 3 UN2379 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............Dimethylcarbamoyl chloride ............................................................................................................ 8 UN2262 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 40Dimethylcyclohexanes ..................................................................................................................... 3 UN2263 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............N,N-Dimethylcyclohexylamine ......................................................................................................... 8 UN2264 II 8, 3 .... B2, IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L A 40Dimethyldichlorosilane ..................................................................................................................... 3 UN1162 II 3, 8 .... B77, IB2, T7, 

TP2, TP13

None .... 202 ...... 243 ...... Forbidden Forbidden B 40

Dimethyldiethoxysilane .................................................................................................................... 3 UN2380 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Dimethyldioxanes ............................................................................................................................ 3 UN2707 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

N,N-Dimethylformamide .................................................................................................................. 3 UN2265 III 3 ........ B1, IB3, T2, TP2 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Dimethylhexane dihydroperoxide (dry) ........................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Dimethylhydrazine, symmetrical ...................................................................................................... 6.1 UN2382 I 6.1, 3 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40, 74

Dimethylhydrazine, unsymmetrical .................................................................................................. 6.1 UN1163 I 6.1, 3, 

8.

2, B7, B9, B14, 

B32, B74, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 21, 38, 

40, 100

2,2-Dimethylpropane ....................................................................................................................... 2.1 UN2044 ............ 2.1 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Dimethylzinc .................................................................................................................................... 4.2 UN1370 I 4.2, 

4.3.

B11, B16, T21, 

TP2, TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D 18

Dinitro-o-cresol ................................................................................................................................ 6.1 UN1598 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

1,3-Dinitro-5,5-dimethyl hydantoin .................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Dinitro-7,8-dimethylglycoluril (dry) ................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............1,3-Dinitro-4,5-dinitrosobenzene ..................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry) ................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............2,4-Dinitro-1,3,5-trimethylbenzene .................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Dinitroanilines .................................................................................................................................. 6.1 UN1596 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 91

Dinitrobenzenes, liquid .................................................................................................................... 6.1 UN1597 II 6.1 ..... 11, IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 91

.......................................................................................................................................................... .................... III 6.1 ..... 11, IB3, T7, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L A 91

Dinitrobenzenes, solid ..................................................................................................................... 6.1 UN3443 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 91

Dinitrochlorobenzene, see Chlorodinitrobenzene ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............1,2-Dinitroethane ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............1,1-Dinitroethane (dry) .................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Dinitrogen tetroxide ......................................................................................................................... 2.3 UN1067 ............ 2.3, 

5.1, 8.

1, B7, B14, B45, 

B46, B61, B66, 

B67, B77, T50, 

TP21

None .... 336 ...... 314 ...... Forbidden Forbidden D 40, 89, 

90

Dinitroglycoluril or Dingu ................................................................................................................. 1.1D UN0489 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Dinitromethane ................................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Dinitrophenol, dry or wetted with less than 15 percent water, by mass ........................................ 1.1D UN0076 II 1.1D, 

6.1.

None .... 62 ........ None .... Forbidden Forbidden 10 5E 

Dinitrophenol solutions .................................................................................................................... 6.1 UN1599 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 36

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 36

Dinitrophenol, wetted with not less than 15 percent water, by mass ............................................. 4.1 UN1320 I 4.1, 

6.1.

23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg E 28, 36

Dinitrophenolates alkali metals, dry or wetted with less than 15 percent water, by mass ............ 1.3C UN0077 II 1.3C, 

6.1.

None .... 62 ........ None .... Forbidden Forbidden 10 5E 

Dinitrophenolates, wetted with not less than 15 percent water, by mass ...................................... 4.1 UN1321 I 4.1, 

6.1.

23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg E 28, 36

76094 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Dinitropropylene glycol .................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Dinitroresorcinol, dry or wetted with less than 15 percent water, by mass .................................... 1.1D UN0078 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E 2,4-Dinitroresorcinol (heavy metal salts of) (dry) ............................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............4,6-Dinitroresorcinol (heavy metal salts of) (dry) ............................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Dinitroresorcinol, wetted with not less than 15 percent water, by mass ........................................ 4.1 UN1322 I 4.1 ..... 23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg E 28, 36

3,5-Dinitrosalicylic acid (lead salt) (dry) .......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Dinitrosobenzene ............................................................................................................................. 1.3C UN0406 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Dinitrosobenzylamidine and salts of (dry) ....................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,2-Dinitrostilbene ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Dinitrotoluenes, liquid ...................................................................................................................... 6.1 UN2038 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Dinitrotoluenes, solid ....................................................................................................................... 6.1 UN3454 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Dinitrotoluenes, molten .................................................................................................................... 6.1 UN1600 II 6.1 ..... T7, TP3 None .... 202 ...... 243 ...... Forbidden Forbidden C ............1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry) ................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Dioxane ........................................................................................................................................... 3 UN1165 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Dioxolane ......................................................................................................................................... 3 UN1166 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Dipentene ........................................................................................................................................ 3 UN2052 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Diphenylamine chloroarsine ............................................................................................................ 6.1 UN1698 I 6.1 ..... T6, TP33 None .... 201 ...... None .... Forbidden Forbidden D 40Diphenylchloroarsine, liquid ............................................................................................................ 6.1 UN1699 I 6.1 ..... A8, B14, B32, 

N33, N34, T14, 

TP2, TP13, TP27

None .... 201 ...... 243 ...... Forbidden 30 L D 40

Diphenyl-chloroarsine, solid ............................................................................................................ 6.1 UN3450 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg D 40

Diphenyldichlorosilane ..................................................................................................................... 8 UN1769 II 8 ........ A7, B2, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Diphenylmethyl bromide .................................................................................................................. 8 UN1770 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg D 40

Dipicryl sulfide, dry or wetted with less than 10 percent water, by mass ...................................... 1.1D UN0401 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Dipicryl sulfide, wetted with not less than 10 percent water, by mass ........................................... 4.1 UN2852 I 4.1 ..... 162, A2, N41, 

N84

None .... 211 ...... None .... Forbidden 0.5 kg D 28

Dipicrylamine, see Hexanitrodiphenylamine ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Dipropionyl peroxide, with more than 28 percent in solution ......................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Di-n-propyl ether .............................................................................................................................. 3 UN2384 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Dipropyl ketone ............................................................................................................................... 3 UN2710 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Dipropylamine .................................................................................................................................. 3 UN2383 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............

G Disinfectant, liquid, corrosive, n.o.s. ............................................................................................... 8 UN1903 I 8 ........ A6, A7, B10, 

T14, TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B ............

G Disinfectants, liquid, corrosive n.o.s. ............................................................................................... 8 UN1903 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

G Disinfectants, liquid, toxic, n.o.s. ..................................................................................................... 6.1 UN3142 I 6.1 ..... A4, T14, TP2, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

G Disinfectants, solid, toxic, n.o.s. ...................................................................................................... 6.1 UN1601 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Disodium trioxosilicate ..................................................................................................................... 8 UN3253 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

G Dispersant gases, n.o.s. see Refrigerant gases, n.o.s. .................................................................. .................... ........... .......... .......... .......... .................... .................... ............

Divinyl ether, stabilized ................................................................................................................... 3 UN1167 I 3 ........ A7, T11, TP2 None .... 201 ...... 243 ...... 1 L 30 L E 40Dodecyltrichlorosilane ..................................................................................................................... 8 UN1771 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Dry ice, see Carbon dioxide, solid .................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............

G Dyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid, corrosive, n.o.s. ................................. 8 UN2801 I 8 ........ 11, A6, B10, 

T14, TP2, TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L A ............

.......................................................................................................................................................... .................... II 8 ........ 11, B2, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76095

.......................................................................................................................................................... .................... III 8 ........ 11, IB3, T7, TP1, 

TP28

154 ...... 203 ...... 241 ...... 5 L 60 L A ............

G Dyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic, n.o.s. ............................................... 6.1 UN1602 I 6.1 ..... None .... 201 ...... 243 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... 5 L 60 L A ...................................................................................................................................................................... .................... III 6.1 ..... IB3 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

G Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s. ................................... 8 UN3147 I 8 ........ IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 25 kg A ............

.......................................................................................................................................................... .................... II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

G Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s. ................................................. 6.1 UN3143 I 6.1 ..... A5, IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Dynamite, see Explosive, blasting, type A ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Electrolyte (acid or alkali) for batteries, see Battery fluid, acid or Battery fluid, alkali ................... .................... ........... .......... .......... .......... .................... .................... ............Elevated temperature liquid, flammable, n.o.s., with flash point above 37.8 C, at or above its 

flash point.

3 UN3256 III 3 ........ IB1, T3, TP3, 

TP29

None .... None .... 247 ...... Forbidden Forbidden A ............

Elevated temperature liquid, n.o.s., at or above 100 C and below its flash point (including molten metals, molten salts, etc.). 9 UN3257 III 9 ........ IB1, T3, TP3, TP29 None .... None .... 247 ...... Forbidden Forbidden A 85Elevated temperature solid, n.o.s., at or above 240 C, see § 173.247(h)(4) ................................. 9 UN3258 III 9 ........ 247(h) 

(4).

None .... 247 ...... Forbidden Forbidden A 85

Engines, internal combustion, flammable gas powered ................................................................. 9 UN3166 ............ 9 ........ 135 220 ...... 220 ...... 220 ...... Forbidden No limit A ............Engines, internal combustion, flammable liquid powered ............................................................... 9 UN3166 ............ 9 ........ 135 220 ...... 220 ...... 220 ...... No limit No limit A ............

G Environmentally hazardous substances, liquid, n.o.s. .................................................................... 9 UN3082 III 9 ........ 8, 146, IB3, T4, 

TP1, TP29

155 ...... 203 ...... 241 ...... No limit No limit A ............

G Environmentally hazardous substances, solid, n.o.s. ..................................................................... 9 UN3077 III 9 ........ 8, 146, B54, IB8, 

IP3, N20, T1, 

TP33

155 ...... 213 ...... 240 ...... No limit No limit A ............

Epibromohydrin ............................................................................................................................... 6.1 UN2558 I 6.1, 3 T14, TP2, TP13 None .... 201 ...... 243 ...... Forbidden Forbidden D 40

+ Epichlorohydrin ................................................................................................................................ 6.1 UN2023 II 6.1, 3 IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 5 L 60 L A 40

1,2-Epoxy-3-ethoxypropane ............................................................................................................ 3 UN2752 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Esters, n.o.s. ................................................................................................................................... 3 UN3272 II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Etching acid, liquid, n.o.s., see Hydrofluoric acid, solution etc ...................................................... .................... ........... .......... .......... .......... .................... .................... ............Ethane ............................................................................................................................................. 2.1 UN1035 ............ 2.1 ..... 306 ...... 304 ...... 302 ...... Forbidden 150 kg E 40

D Ethane-Propane mixture, refrigerated liquid ................................................................................... 2.1 NA1961 ............ 2.1 ..... T75, TP5 None .... 316 ...... 314, 

315.

Forbidden Forbidden D 40

Ethane, refrigerated liquid ............................................................................................................... 2.1 UN1961 ............ 2.1 ..... T75, TP5 None .... None .... 315 ...... Forbidden Forbidden D 40Ethanol amine dinitrate ................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl alcohol solutions ....................................... 3 UN1170 II 3 ........ 24, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 3 ........ 24, B1, IB3, T2, 

TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Ethanolamine or Ethanolamine solutions ........................................................................................ 8 UN2491 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Ether, see Diethyl ether .................................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Ethers, n.o.s. ................................................................................................................................... 3 UN3271 II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Ethyl acetate .................................................................................................................................... 3 UN1173 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl acrylate, stabilized .................................................................................................................. 3 UN1917 II 3 ........ IB2, T4, TP1, 

TP13

150 ...... 202 ...... 242 ...... 5 L 60 L B 40

Ethyl alcohol, see Ethanol ............................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Ethyl aldehyde, see Acetaldehyde .................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Ethyl amyl ketone ............................................................................................................................ 3 UN2271 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............N-Ethylbenzyltoluidines, solid .......................................................................................................... 6.1 UN3460 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

N-Ethyl-N-benzylaniline ................................................................................................................... 6.1 UN2274 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Ethyl borate ..................................................................................................................................... 3 UN1176 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl bromide .................................................................................................................................. 6.1 UN1891 II 6.1 ..... IB2, IP8, T7, 

TP2, TP13

153 ...... 202 ...... 243 ...... 5 L 60 L B 40, 85

Ethyl bromoacetate ......................................................................................................................... 6.1 UN1603 II 6.1, 3 IB2, T7, TP2 None .... 202 ...... 243 ...... Forbidden Forbidden D 40Ethyl butyl ether .............................................................................................................................. 3 UN1179 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl butyrate .................................................................................................................................. 3 UN1180 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethyl chloride ................................................................................................................................... 2.1 UN1037 ............ 2.1 ..... B77, T50 None .... 322 ...... 314, 

315.

Forbidden 150 kg B 40

Ethyl chloroacetate .......................................................................................................................... 6.1 UN1181 II 6.1, 3 IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

76096 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Ethyl chloroformate ......................................................................................................................... 6.1 UN1182 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, N34, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 21, 40, 

100

Ethyl 2-chloropropionate ................................................................................................................. 3 UN2935 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

+ Ethyl chlorothioformate .................................................................................................................... 8 UN2826 II 8, 6.1, 

3.

2, B9, B14, B32, 

B74, T20, TP2, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A 40

Ethyl crotonate ................................................................................................................................ 3 UN1862 II 3 ........ IB2, T4, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl ether, see Diethyl ether .......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Ethyl fluoride or Refrigerant gas R161 ........................................................................................... 2.1 UN2453 ............ 2.1 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Ethyl formate ................................................................................................................................... 3 UN1190 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Ethyl hydroperoxide ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Ethyl isobutyrate .............................................................................................................................. 3 UN2385 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

+ Ethyl isocyanate .............................................................................................................................. 3 UN2481 I 3, 6.1 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40, 52

Ethyl lactate ..................................................................................................................................... 3 UN1192 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethyl mercaptan .............................................................................................................................. 3 UN2363 I 3 ........ A6, T11, TP2, 

TP13

None .... 201 ...... 243 ...... Forbidden 30 L E 95, 102

Ethyl methacrylate, stabilized .......................................................................................................... 3 UN2277 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl methyl ether ........................................................................................................................... 2.1 UN1039 ............ 2.1 ..... None .... 201 ...... 314, 

315.

Forbidden 150 kg B 40

Ethyl methyl ketone or Methyl ethyl ketone .................................................................................... 3 UN1193 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl nitrite solutions ....................................................................................................................... 3 UN1194 I 3, 6.1 None .... 201 ...... None .... Forbidden Forbidden E 40, 105Ethyl orthoformate ........................................................................................................................... 3 UN2524 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethyl oxalate .................................................................................................................................... 6.1 UN2525 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Ethyl perchlorate ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............

D Ethyl phosphonothioic dichloride, anhydrous .................................................................................. 6.1 NA2927 I 6.1, 8 2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

D Ethyl phosphonous dichloride, anhydrous pyrophoric liquid ........................................................... 6.1 NA2845 I 6.1, 

4.2.

2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 18

D Ethyl phosphorodichloridate ............................................................................................................ 6.1 NA2927 I 6.1, 8 2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Ethyl propionate .............................................................................................................................. 3 UN1195 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyl propyl ether ............................................................................................................................ 3 UN2615 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Ethyl silicate, see Tetraethyl silicate ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Ethylacetylene, stabilized ................................................................................................................ 2.1 UN2452 ............ 2.1 ..... None .... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Ethylamine ....................................................................................................................................... 2.1 UN1036 ............ 2.1 ..... B77, T50 None .... 321 ...... 314, 

315.

Forbidden 150 kg D 40

Ethylamine, aqueous solution with not less than 50 percent but not more than 70 percent ethylamine. 3 UN2270 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40N-Ethylaniline .................................................................................................................................. 6.1 UN2272 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 52, 742-Ethylaniline ................................................................................................................................... 6.1 UN2273 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 52, 74Ethylbenzene ................................................................................................................................... 3 UN1175 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............N-Ethylbenzyltoluidines liquid .......................................................................................................... 6.1 UN2753 III 6.1 ..... IB3, T7, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............2-Ethylbutanol .................................................................................................................................. 3 UN2275 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............2-Ethylbutyl acetate ......................................................................................................................... 3 UN1177 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............2-Ethylbutyraldehyde ....................................................................................................................... 3 UN1178 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Ethyldichloroarsine .......................................................................................................................... 6.1 UN1892 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Ethyldichlorosilane ........................................................................................................................... 4.3 UN1183 I 4.3, 8, 

3.

A2, A3, A7, N34, 

T10, TP2, TP7, 

TP13

None .... 201 ...... 244 ...... Forbidden 1 L D 21, 28, 

40, 49, 

100

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76097

Ethylene, acetylene and propylene in mixture, refrigerated liquid with at least 71.5 percent 

ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene.

2.1 UN3138 ............ 2.1 ..... T75, TP5 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 57

Ethylene chlorohydrin ...................................................................................................................... 6.1 UN1135 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Ethylene ........................................................................................................................................... 2.1 UN1962 ............ 2.1 ..... 306 ...... 304 ...... 302 ...... Forbidden 150 kg E 40Ethylene diamine diperchlorate ....................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Ethylene dibromide .......................................................................................................................... 6.1 UN1605 I 6.1 ..... 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Ethylene dibromide and methyl bromide liquid mixtures, see Methyl bromide and ethylene 

dibromide, liquid mixtures.

.................... ........... .......... .......... .......... .................... .................... ............

Ethylene dichloride .......................................................................................................................... 3 UN1184 II 3, 6.1 IB2, N36, T7, 

TP1

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Ethylene glycol diethyl ether ........................................................................................................... 3 UN1153 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Ethylene glycol dinitrate .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Ethylene glycol monoethyl ether ..................................................................................................... 3 UN1171 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethylene glycol monoethyl ether acetate ........................................................................................ 3 UN1172 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethylene glycol monomethyl ether .................................................................................................. 3 UN1188 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethylene glycol monomethyl ether acetate ..................................................................................... 3 UN1189 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Ethylene oxide and carbon dioxide mixture with more than 87 percent ethylene oxide ................ 2.3 UN3300 ............ 2.3, 

2.1.

4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Ethylene oxide and carbon dioxide mixtures with more than 9 percent but not more than 87 

percent ethylene oxide.

2.1 UN1041 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 25 kg B 40

Ethylene oxide and carbon dioxide mixtures with not more than 9 percent ethylene oxide .......... 2.2 UN1952 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Ethylene oxide and chlorotetrafluoroethane mixture with not more than 8.8 percent ethylene 

oxide.

2.2 UN3297 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5 percent ethylene 

oxide.

2.2 UN3070 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Ethylene oxide and pentafluoroethane mixture with not more than 7.9 percent ethylene oxide ... 2.2 UN3298 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Ethylene oxide and propylene oxide mixtures, with not more than 30 percent ethylene oxide ..... 3 UN2983 I 3, 6.1 5, A11, N4, N34, 

T14, TP2, TP7, 

TP13

None .... 201 ...... 243 ...... Forbidden 30 L E 40

Ethylene oxide and tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide ..... 2.2 UN3299 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 

degrees C.

2.3 UN1040 ............ 2.3, 

2.1.

4, T50, TP20 None .... 323 ...... 323 ...... Forbidden Forbidden D 40

Ethylene, refrigerated liquid (cryogenic liquid) ................................................................................ 2.1 UN1038 ............ 2.1 ..... T75, TP5 None .... 316 ...... 318, 

319.

Forbidden Forbidden D 40

Ethylenediamine .............................................................................................................................. 8 UN1604 II 8, 3 .... IB2, T7, TP2 154 ...... 202 ...... 243 ...... 1 L 30 L A 40Ethyleneimine, stabilized ................................................................................................................. 6.1 UN1185 I 6.1, 3 1, B9, B14, B30, 

B72, B77, N25, 

N32, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Ethylhexaldehyde, see Octyl aldehydes etc ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............2-Ethylhexyl chloroformate .............................................................................................................. 6.1 UN2748 II 6.1, 8 IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L A 12, 13, 

21, 25, 

40, 100

2-Ethylhexylamine ........................................................................................................................... 3 UN2276 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A 40Ethylphenyldichlorosilane ................................................................................................................ 8 UN2435 II 8 ........ A7, B2, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C ............

1-Ethylpiperidine .............................................................................................................................. 3 UN2386 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............N-Ethyltoluidines .............................................................................................................................. 6.1 UN2754 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Ethyltrichlorosilane .......................................................................................................................... 3 UN1196 II 3, 8 .... A7, IB1, N34, T7, 

TP2, TP13

150 ...... 202 ...... 243 ...... 1 L 5 L B 40

Etiologic agent, see Infectious substances, etc .............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Explosive articles, see Articles, explosive , n.o.s. etc .................................................................... .................... ........... .......... .......... .......... .................... .................... ............Explosive, blasting, type A .............................................................................................................. 1.1D UN0081 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 21E, 

29E 

Explosive, blasting, type B .............................................................................................................. 1.1D UN0082 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 29E Explosive, blasting, type B or Agent blasting, Type B .................................................................... 1.5D UN0331 II 1.5D .. 105, 106 None .... 62 ........ None .... Forbidden Forbidden 10 29E Explosive, blasting, type C .............................................................................................................. 1.1D UN0083 II 1.1D .. 123 None .... 62 ........ None .... Forbidden Forbidden 10 22E Explosive, blasting, type D .............................................................................................................. 1.1D UN0084 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Explosive, blasting, type E .............................................................................................................. 1.1D UN0241 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 19E, 

29E 

Explosive, blasting, type E or Agent blasting, Type E .................................................................... 1.5D UN0332 II 1.5D .. 105, 106 None .... 62 ........ None .... Forbidden Forbidden 10 29E Explosive, forbidden. See § 173.54 ................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Explosive substances, see Substances, explosive, n.o.s. etc ........................................................ .................... ........... .......... .......... .......... .................... .................... ............

76098 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Explosives, slurry, see Explosive, blasting, type E ......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Explosives, water gels, see Explosive, blasting, type E ................................................................. .................... ........... .......... .......... .......... .................... .................... ............Extracts, aromatic, liquid ................................................................................................................. 3 UN1169 II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Extracts, flavoring, liquid ................................................................................................................. 3 UN1197 II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Fabric with animal or vegetable oil, see Fibers or fabrics, etc ....................................................... .................... ........... .......... .......... .......... .................... .................... ............Ferric arsenate ................................................................................................................................ 6.1 UN1606 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Ferric arsenite ................................................................................................................................. 6.1 UN1607 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Ferric chloride, anhydrous ............................................................................................................... 8 UN1773 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Ferric chloride, solution ................................................................................................................... 8 UN2582 III 8 ........ B15, IB3, T4, 

TP1

154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Ferric nitrate .................................................................................................................................... 5.1 UN1466 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Ferrocerium ..................................................................................................................................... 4.1 UN1323 II 4.1 ..... 59, A19, IB8, 

IP2, IP4, T3, 

TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Ferrosilicon with 30 percent or more but less than 90 percent silicon ........................................... 4.3 UN1408 III 4.3, 

6.1.

A1, A19, B6, IB8, 

IP4, IP7, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A 13, 40, 

52, 53, 

85, 103

Ferrous arsenate ............................................................................................................................. 6.1 UN1608 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

D Ferrous chloride, solid ..................................................................................................................... 8 NA1759 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

D Ferrous chloride, solution ................................................................................................................ 8 NA1760 II 8 ........ B3, IB2, T11, 

TP2, TP27

154 ...... 202 ...... 242 ...... 1 L 30 L B 40

Ferrous metal borings or Ferrous metal shavings or Ferrous metal turnings or Ferrous metal 

cuttings in a form liable to self-heating.

4.2 UN2793 III 4.2 ..... A1, A19, IB8, 

IP3, IP7

None .... 213 ...... 241 ...... 25 kg 100 kg A ............

Fertilizer ammoniating solution with free ammonia ........................................................................ 2.2 UN1043 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

A I W Fibers, animal or Fibers, vegetable burnt, wet or damp. ................................................................ 4.2 UN1372 III ........... 151 ...... 213 ...... 240 ...... Forbidden Forbidden A ............

I W Fibers, vegetable, dry ...................................................................................................................... 4.1 UN3360 ............ 4.1 ..... 137 151 ...... 213 ...... 240 ...... No Limit No Limit A ............

A W Fibers or Fabrics, animal or vegetable or Synthetic, n.o.s. with animal or vegetable oil .............. 4.2 UN1373 III 4.2 ..... 137, IB8, IP3, 

T1, TP33

None .... 213 ...... 241 ...... Forbidden Forbidden A ............

Fibers or Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s. ...................................... 4.1 UN1353 III 4.1 ..... A1, IB8, IP3 None .... 213 ...... 240 ...... 25 kg 100 kg D ............Films, nitrocellulose base, from which gelatine has been removed; film scrap, see Celluloid 

scrap.

.................... ........... .......... .......... .......... .................... .................... ............

Films, nitrocellulose base, gelatine coated (except scrap) ............................................................. 4.1 UN1324 III 4.1 ..... None .... 183 ...... None .... 25 kg 100 kg D 28Fire extinguisher charges, corrosive liquid ..................................................................................... 8 UN1774 II 8 ........ N41 154 ...... 202 ...... None .... 1 L 30 L A ............Fire extinguisher charges, expelling, explosive, see Cartridges, power device ............................. .................... ........... .......... .......... .......... .................... .................... ............Fire extinguishers containing compressed or liquefied gas ............................................................ 2.2 UN1044 ............ 2.2 ..... 18, 110 309 ...... 309 ...... None .... 75 kg 150 kg A ............Firelighters, solid with flammable liquid .......................................................................................... 4.1 UN2623 III 4.1 ..... A1, A19 None .... 213 ...... None .... 25 kg 100 kg A 52Fireworks ......................................................................................................................................... 1.1G UN0333 II 1.1G .. 108 None .... 62 ........ None .... Forbidden Forbidden 07 ............Fireworks ......................................................................................................................................... 1.2G UN0334 II 1.2G .. 108 None .... 62 ........ None .... Forbidden Forbidden 07 ............Fireworks ......................................................................................................................................... 1.3G UN0335 II 1.3G .. 108 None .... 62 ........ None .... Forbidden Forbidden 07 ............Fireworks ......................................................................................................................................... 1.4G UN0336 II 1.4G .. 108 None .... 62 ........ None .... Forbidden 75 kg 06 ............Fireworks ......................................................................................................................................... 1.4S UN0337 II 1.4S ... 108 None .... 62 ........ None .... 25 kg 100 kg 05 ............First aid kits ..................................................................................................................................... 9 UN3316 ............ 9 ........ 15 161 ...... 161 ...... None .... 10 kg 10 kg A ............

W Fish meal, stabilized or Fish scrap, stabilized ................................................................................ 9 UN2216 III None 155, IB8, IP3, 

T1, TP33

155 ...... 218 ...... 218 ...... No limit No limit B 88, 

122, 

128

Fish meal, unstablized or Fish scrap, unstabilized ......................................................................... 4.2 UN1374 II 4.2 ..... 155, A1, A19, 

IB8, IP2, IP4, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg B 18, 128

Fissile radioactive materials, see Radioactive material, fissile, n.o.s. ............................................ .................... ........... .......... .......... .......... .................... .................... ............Flammable compressed gas, see Compressed or Liquefied gas, flammable, etc ........................ .................... ........... .......... .......... .......... .................... .................... ............Flammable compressed gas (small receptacles not fitted with a dispersion device, not refillable), see Receptacles, etc. .................... ........... .......... .......... .......... .................... .................... ............Flammable gas in lighters, see Lighters or lighter refills, cigarettes, containing flammable gas ... .................... ........... .......... .......... .......... .................... .................... ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76099

G Flammable liquid, toxic, corrosive, n.o.s. ........................................................................................ 3 UN3286 I 3, 6.1, 

8.

T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 2.5 L E 21, 40, 

100

.......................................................................................................................................................... .................... II 3, 6.1, 

8.

IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 5 L B 21, 40, 

100

G Flammable liquids, corrosive, n.o.s. ................................................................................................ 3 UN2924 I 3, 8 .... T14, TP2 None .... 201 ...... 243 ...... 0.5 L 2.5 L E 40

.......................................................................................................................................................... .................... II 3, 8 .... IB2, T11, TP2, 

TP27

150 ...... 202 ...... 243 ...... 1 L 5 L B 40

.......................................................................................................................................................... .................... III 3, 8 .... B1, IB3, T7, TP1, 

TP28

150 ...... 203 ...... 242 ...... 5 L 60 L A 40

G Flammable liquids, n.o.s. ................................................................................................................ 3 UN1993 I 3 ........ T11, TP1, TP27 150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Flammable liquids, toxic, n.o.s. ....................................................................................................... 3 UN1992 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L E 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T7, TP2, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

.......................................................................................................................................................... .................... III 3, 6.1 B1, IB3, T7, TP1, 

TP28

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Flammable solid, corrosive, inorganic, n.o.s. .................................................................................. 4.1 UN3180 II 4.1, 8 A1, IB6, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg D 40

.......................................................................................................................................................... .................... III 4.1, 8 A1, IB6, T1, 

TP33

151 ...... 213 ...... 242 ...... 25 kg 100 kg D 40

G Flammable solid, inorganic, n.o.s. .................................................................................................. 4.1 UN3178 II 4.1 ..... A1, IB8, IP2, IP4, 

T3, TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg B ............

G Flammable solid, organic, molten, n.o.s. ........................................................................................ 4.1 UN3176 II 4.1 ..... IB1, T3, TP3, 

TP26

151 ...... 212 ...... 240 ...... Forbidden Forbidden C ............

.......................................................................................................................................................... .................... III 4.1 ..... IB1, T1, TP3, 

TP26

151 ...... 213 ...... 240 ...... Forbidden Forbidden C ............

G Flammable solid, oxidizing, n.o.s. ................................................................................................... 4.1 UN3097 II 4.1, 

5.1.

131 None .... 214 ...... 214 ...... Forbidden Forbidden E 40

.......................................................................................................................................................... .................... III 4.1, 

5.1.

131, T1, TP33 None .... 214 ...... 214 ...... Forbidden Forbidden D 40

G Flammable solid, toxic, inorganic, n.o.s. ......................................................................................... 4.1 UN3179 II 4.1, 

6.1.

A1, IB6, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg B 40

.......................................................................................................................................................... .................... III 4.1, 

6.1.

A1, IB6, T1, 

TP33

151 ...... 213 ...... 242 ...... 25 kg 100 kg B 40

G Flammable solids, corrosive, organic, n.o.s. ................................................................................... 4.1 UN2925 II 4.1, 8 A1, IB6, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg D 40

.......................................................................................................................................................... .................... III 4.1, 8 A1, IB6, T1, 

TP33

151 ...... 213 ...... 242 ...... 25 kg 100 kg D 40

G Flammable solids, organic, n.o.s. ................................................................................................... 4.1 UN1325 II 4.1 ..... A1, IB8, IP2, IP4, 

T3, TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg B ............

G Flammable solids, toxic, organic, n.o.s. .......................................................................................... 4.1 UN2926 II 4.1, 

6.1.

A1, IB6, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg B 40

.......................................................................................................................................................... .................... III 4.1, 

6.1.

A1, IB6, T1, 

TP33

151 ...... 213 ...... 242 ...... 25 kg 100 kg B 40

Flares, aerial .................................................................................................................................... 1.3G UN0093 II 1.3G .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Flares, aerial .................................................................................................................................... 1.4G UN0403 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Flares, aerial .................................................................................................................................... 1.4S UN0404 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Flares, aerial .................................................................................................................................... 1.1G UN0420 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Flares, aerial .................................................................................................................................... 1.2G UN0421 II 1.2G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Flares, airplane, see Flares, aerial ................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Flares, signal, see Cartridges, signal .............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Flares, surface ................................................................................................................................. 1.3G UN0092 II 1.3G .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Flares, surface ................................................................................................................................. 1.1G UN0418 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Flares, surface ................................................................................................................................. 1.2G UN0419 II 1.2G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Flares, water-activated, see Contrivances, water-activated, etc .................................................... .................... ........... .......... .......... .......... .................... .................... ............Flash powder ................................................................................................................................... 1.1G UN0094 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 15 ............Flash powder ................................................................................................................................... 1.3G UN0305 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 15 ............Flue dusts, poisonous, see Arsenical dust ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Fluoric acid, see Hydrofluoric acid, etc ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Fluorine, compressed ...................................................................................................................... 2.3 UN1045 ............ 2.3, 

5.1, 8.

1 None .... 302 ...... None .... Forbidden Forbidden D 40, 89, 

90

Fluoroacetic acid ............................................................................................................................. 6.1 UN2642 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 1 kg 15 kg E ............

Fluoroanilines .................................................................................................................................. 6.1 UN2941 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Fluorobenzene ................................................................................................................................. 3 UN2387 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

76100 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Fluoroboric acid ............................................................................................................................... 8 UN1775 II 8 ........ A6, A7, B2, B15, 

IB2, N3, N34, 

T7, TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Fluorophosphoric acid anhydrous ................................................................................................... 8 UN1776 II 8 ........ A6, A7, B2, IB2, 

N3, N34, T8, 

TP2, TP12

None .... 202 ...... 242 ...... 1 L 30 L A ............

Fluorosilicates, n.o.s. ....................................................................................................................... 6.1 UN2856 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Fluorosilicic acid .............................................................................................................................. 8 UN1778 II 8 ........ A6, A7, B2, B15, 

IB2, N3, N34, 

T8, TP2, TP12

None .... 202 ...... 242 ...... 1 L 30 L A ............

Fluorosulfonic acid .......................................................................................................................... 8 UN1777 I 8 ........ A3, A6, A7, A10, 

B6, B10, N3, 

N36, T10, TP2, 

TP12

None .... 201 ...... 243 ...... 0.5 L 2.5 L D 40

Fluorotoluenes ................................................................................................................................. 3 UN2388 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Forbidden materials. See § 173.21 ................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Formaldehyde, solutions, flammable .............................................................................................. 3 UN1198 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A 40Formaldehyde, solutions, with not less than 25 percent formaldehyde ......................................... 8 UN2209 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Formalin, see Formaldehyde, solutions .......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Formic acid ...................................................................................................................................... 8 UN1779 II 8 ........ B2, B28, IB2, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A 40

Fracturing devices, explosive, without detonators for oil wells ....................................................... 1.1D UN0099 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Fuel, aviation, turbine engine .......................................................................................................... 3 UN1863 I 3 ........ 144, T11, TP1, 

TP8, TP28

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 144, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ 144, B1, IB3, T2, 

TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

D Fuel oil (No. 1, 2, 4, 5, or 6) ........................................................................................................... 3 NA1993 III 3 ........ 144, B1, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Fuel system components (including fuel control units (FCU), carburetors, fuel lines, fuel pumps) 

see Dangerous Goods in Apparatus or Dangerous Goods in Machinery.

.................... ........... .......... .......... .......... .................... .................... ............

Fulminate of mercury (dry) .............................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Fulminate of mercury, wet, see Mercury fulminate, etc .................................................................. .................... ........... .......... .......... .......... .................... .................... ............Fulminating gold .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Fulminating mercury ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Fulminating platinum ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Fulminating silver ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Fulminic acid ................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Fumaryl chloride .............................................................................................................................. 8 UN1780 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L C 8, 40Fumigated lading, see §§ 172.302(g), 173.9 and 176.76(h) ........................................................... .................... ........... .......... .......... .......... .................... .................... ............Fumigated transport vehicle or freight container see 173.9 ........................................................... .................... ........... .......... .......... .......... .................... .................... ............Furaldehydes ................................................................................................................................... 6.1 UN1199 II 6.1, 3 IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Furan ............................................................................................................................................... 3 UN2389 I 3 ........ T12, TP2, TP13 None .... 201 ...... 243 ...... 1 L 30 L E 40Furfuryl alcohol ................................................................................................................................ 6.1 UN2874 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 52, 74Furfurylamine ................................................................................................................................... 3 UN2526 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A 40Fuse, detonating, metal clad, see Cord, detonating, metal clad .................................................... .................... ........... .......... .......... .......... .................... .................... ............Fuse, detonating, mild effect, metal clad, see Cord, detonating, mild effect, metal clad .............. .................... ........... .......... .......... .......... .................... .................... ............Fuse, igniter tubular metal clad ....................................................................................................... 1.4G UN0103 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Fuse, non-detonating instantaneous or quickmatch ....................................................................... 1.3G UN0101 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Fuse, safety ..................................................................................................................................... 1.4S UN0105 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............

D Fusee (railway or highway) ............................................................................................................. 4.1 NA1325 II 4.1 ..... None .... 184 ...... None .... 15 kg 50 kg B ............

Fusel oil ........................................................................................................................................... 3 UN1201 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Fuses, tracer, see Tracers for ammunition ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Fuzes, combination, percussion and time, see Fuzes, detonating (UN0257, UN0367); Fuzes, 

igniting (UN0317, UN0368).

.................... ........... .......... .......... .......... .................... .................... ............

Fuzes, detonating ............................................................................................................................ 1.1B UN0106 II 1.1B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Fuzes, detonating ............................................................................................................................ 1.2B UN0107 II 1.2B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Fuzes, detonating ............................................................................................................................ 1.4B UN0257 II 1.4B ... 116 None .... 62 ........ None .... Forbidden 75 kg 06 ............Fuzes, detonating ............................................................................................................................ 1.4S UN0367 II 1.4S ... 116 None .... 62 ........ None .... 25 kg 100 kg 05 ............Fuzes, detonating, with protective features .................................................................................... 1.1D UN0408 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Fuzes, detonating, with protective features .................................................................................... 1.2D UN0409 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Fuzes, detonating, with protective features .................................................................................... 1.4D UN0410 II 1.4D .. 116 None .... 62 ........ None .... Forbidden 75 kg 06 ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76101

Fuzes, igniting ................................................................................................................................. 1.3G UN0316 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Fuzes, igniting ................................................................................................................................. 1.4G UN0317 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Fuzes, igniting ................................................................................................................................. 1.4S UN0368 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Galactsan trinitrate .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Gallium ............................................................................................................................................ 8 UN2803 III 8 ........ T1, TP33 None .... 162 ...... 240 ...... 20 kg 20 kg B 48Gas cartridges, (flammable) without a release device, non-refillable ............................................. 2.1 UN2037 ............ 2.1 ..... 306 ...... 304 ...... None .... 1 kg 15 kg B 40Gas generator assemblies (aircraft), containing a non-flammable non-toxic gas and a propellant 

cartridge.

2.2 ............ 2.2 ..... None .... 335 ...... None .... 75 kg 150 kg A ............

D Gas identification set ....................................................................................................................... 2.3 NA9035 ............ 2.3 ..... 6 None .... 194 ...... None .... Forbidden Forbidden D ............

Gas oil ............................................................................................................................................. 3 UN1202 III 3 ........ 144, B1, IB3, T2, 

TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Gas, refrigerated liquid, flammable, n.o.s. (cryogenic liquid) ......................................................... 2.1 UN3312 ............ 2.1 ..... T75, TP5 None .... 316 ...... 318 ...... Forbidden Forbidden D 40G Gas, refrigerated liquid, n.o.s. (cryogenic liquid) ............................................................................ 2.2 UN3158 ............ 2.2 ..... T75, TP5 320 ...... 316 ...... 318 ...... 50 kg 500 kg D ............G Gas, refrigerated liquid, oxidizing, n.o.s. (cryogenic liquid) ............................................................ 2.2 UN3311 ............ 2.2, 

5.1.

T75, TP5, TP22 320 ...... 316 ...... 318 ...... Forbidden Forbidden D ............

Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid ....................................... 2.1 UN3167 ............ 2.1 ..... 306 ...... 302, 

304.

None .... 1 L 5 L D ............

Gas sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid ............................. 2.3 UN3168 ............ 2.3, 

2.1.

6 306 ...... 302 ...... None .... Forbidden 1 L D ............

Gas sample, non-pressurized, toxic, n.o.s., not refrigerated liquid ................................................ 2.3 UN3169 ............ 2.3 ..... 6 306 ...... 302, 

304.

None .... Forbidden 1 L D ............

D Gasohol gasoline mixed with ethyl alcohol, with not more than 20 percent alcohol ..................... 3 NA1203 II 3 ........ 144 150 ...... 202 ...... 242 ...... 5 L 60 L E ............

Gasoline .......................................................................................................................................... 3 UN1203 II 3 ........ 139, B33, B101, 

T8

150 ...... 202 ...... 242 ...... 5 L 60 L E ............

Gasoline, casinghead, see Gasoline .............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Gelatine, blasting, see Explosive, blasting, type A ......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Gelatine dynamites, see Explosive, blasting, type A ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Germane .......................................................................................................................................... 2.3 UN2192 ............ 2.3, 

2.1.

2 None .... 302 ...... 245 ...... Forbidden Forbidden D 40

Glycerol-1,3-dinitrate ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Glycerol gluconate trinitrate ............................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Glycerol lactate trinitrate ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Glycerol alpha-monochlorohydrin .................................................................................................... 6.1 UN2689 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Glyceryl trinitrate, see Nitroglycerin, etc ......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Glycidaldehyde ................................................................................................................................ 3 UN2622 II 3, 6.1 IB2, IP8, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 60 L A 40Grenades, hand or rifle, with bursting charge ................................................................................ 1.1D UN0284 II 1.1D .. .......... 62 ........ None .... Forbidden Forbidden 07 ............Grenades, hand or rifle, with bursting charge ................................................................................ 1.2D UN0285 II 1.2D .. .......... 62 ........ None .... Forbidden Forbidden 07 ............Grenades, hand or rifle, with bursting charge ................................................................................ 1.1F UN0292 II 1.1F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Grenades, hand or rifle, with bursting charge ................................................................................ 1.2F UN0293 II 1.2F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Grenades, illuminating, see Ammunition, illuminating, etc ............................................................. .................... ........... .......... .......... .......... .................... .................... ............Grenades, practice, hand or rifle .................................................................................................... 1.4S UN0110 II 1.4S ... .......... 62 ........ None .... 25 kg 100 kg 05 ............Grenades, practice, hand or rifle .................................................................................................... 1.3G UN0318 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 07 ............Grenades, practice, hand or rifle .................................................................................................... 1.2G UN0372 II 1.2G .. .......... 62 ........ None .... Forbidden Forbidden 07 ............Grenades practice Hand or rifle ...................................................................................................... 1.4G UN0452 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 06 ............Grenades, smoke, see Ammunition, smoke, etc ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Guanidine nitrate ............................................................................................................................. 5.1 UN1467 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 73

Guanyl nitrosaminoguanylidene hydrazine (dry) ............................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Guanyl nitrosaminoguanylidene hydrazine, wetted with not less than 30 percent water, by mass 1.1A UN0113 II 1.1A ... 111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............Guanyl nitrosaminoguanyltetrazene (dry) ....................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Guanyl nitrosaminoguanyltetrazene, wetted or Tetrazene, wetted with not less than 30 percent 

water or mixture of alcohol and water, by mass.

1.1A UN0114 II 1.1A ... 111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............

Gunpowder, compressed or Gunpowder in pellets, see Black powder (UN 0028) ....................... .................... ........... .......... .......... .......... .................... .................... ............Gunpowder, granular or as a meal, see Black powder (UN 0027) ................................................ .................... ........... .......... .......... .......... .................... .................... ............Hafnium powder, dry ....................................................................................................................... 4.2 UN2545 I 4.2 ..... None .... 211 ...... 242 ...... Forbidden Forbidden D ............

.......................................................................................................................................................... .................... II 4.2 ..... A19, A20, IB6, 

IP2, N34, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg D ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg D ............

Hafnium powder, wetted with not less than 25 percent water (a visible excess of water must be 

present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns.

4.1 UN1326 II 4.1 ..... A6, A19, A20, 

IB6, IP2, N34, 

T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg E 74

Hand signal device, see Signal devices, hand ............................................................................... .................... ........... .......... .......... .......... .................... .................... ............Hazardous substances, liquid or solid, n.o.s., see Environmentally hazardous substances, etc .. .................... ........... .......... .......... .......... .................... .................... ............

D G Hazardous waste, liquid, n.o.s. ....................................................................................................... 9 NA3082 III 9 ........ IB3, T2, TP1 155 ...... 203 ...... 241 ...... No limit No limit A ............D G Hazardous waste, solid, n.o.s. ........................................................................................................ 9 NA3077 III 9 ........ B54, IB8, IP2, 

T1, TP33

155 ...... 213 ...... 240 ...... No limit No limit A ............

Heating oil, light ............................................................................................................................... 3 UN1202 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Helium, compressed ........................................................................................................................ 2.2 UN1046 ............ 2.2 ..... 306 ...... 302 ...... 302, 

314.

75 kg 150 kg A 85

Helium-oxygen mixture, see Rare gases and oxygen mixtures ..................................................... .................... ........... .......... .......... .......... .................... .................... ............Helium, refrigerated liquid (cryogenic liquid) ................................................................................... 2.2 UN1963 ............ 2.2 ..... T75, TP5 320 ...... 316 ...... 318 ...... 50 kg 500 kg B ............Heptafluoropropane or Refrigerant gas R 227 ............................................................................... 2.2 UN3296 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

76102 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

n-Heptaldehyde ............................................................................................................................... 3 UN3056 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Heptanes ......................................................................................................................................... 3 UN1206 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............n-Heptene ........................................................................................................................................ 3 UN2278 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Hexachloroacetone .......................................................................................................................... 6.1 UN2661 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L B 12, 40Hexachlorobenzene ......................................................................................................................... 6.1 UN2729 III 6.1 ..... B3, IB8, IP3, T1, 

TP33

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Hexachlorobutadiene ....................................................................................................................... 6.1 UN2279 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Hexachlorocyclopentadiene ............................................................................................................ 6.1 UN2646 I 6.1 ..... 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Hexachlorophene ............................................................................................................................ 6.1 UN2875 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Hexadecyltrichlorosilane .................................................................................................................. 8 UN1781 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Hexadienes ...................................................................................................................................... 3 UN2458 II 3 ........ IB2, T4, TP1 None .... 202 ...... 242 ...... 5 L 60 L B ............Hexaethyl tetraphosphate and compressed gas mixtures .............................................................. 2.3 UN1612 ............ 2.3 ..... 3 None .... 334 ...... None .... Forbidden Forbidden D 40Hexaethyl tetraphosphate, liquid ..................................................................................................... 6.1 UN1611 II 6.1 ..... IB2, N76, T7, 

TP2

153 ...... 202 ...... 243 ...... 5 L 60 L E 40

Hexaethyl tetraphosphate, solid ...................................................................................................... 6.1 UN1611 II 6.1 ..... IB8, IP2, IP4, 

N76

153 ...... 212 ...... 242 ...... 25 kg 100 kg E 40

Hexafluoroacetone .......................................................................................................................... 2.3 UN2420 ............ 2.3, 8 2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Hexafluoroacetone hydrate, liquid ................................................................................................... 6.1 UN2552 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L B 40Hexafluoroacetone hydrate, solid .................................................................................................... 6.1 UN3436 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 40

Hexafluoroethane, or Refrigerant gas R 116 .................................................................................. 2.2 UN2193 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Hexafluorophosphoric acid .............................................................................................................. 8 UN1782 II 8 ........ A6, A7, B2, IB2, 

N3, N34, T8, 

TP2, TP12

None .... 202 ...... 242 ...... 1 L 30 L A ............

Hexafluoropropylene compressed or Refrigerant gas R 1216 ....................................................... 2.2 UN1858 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Hexaldehyde .................................................................................................................................... 3 UN1207 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Hexamethylene diisocyanate .......................................................................................................... 6.1 UN2281 II 6.1 ..... IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 5 L 60 L C 13, 40

Hexamethylene triperoxide diamine (dry) ....................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hexamethylenediamine, solid ......................................................................................................... 8 UN2280 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 12

Hexamethylenediamine solution ..................................................................................................... 8 UN1783 II 8 ........ IB2, T7, TP2 None .... 202 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Hexamethyleneimine ....................................................................................................................... 3 UN2493 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40Hexamethylenetetramine ................................................................................................................. 4.1 UN1328 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Hexamethylol benzene hexanitrate ................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Hexanes .......................................................................................................................................... 3 UN1208 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............2,2’,4,4’,6,6’- Hexanitro-3,3’-dihydroxyazobenzene (dry) ................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Hexanitroazoxy benzene ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............N,N’-(hexanitrodiphenyl) ethylene dinitramine (dry) ........................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Hexanitrodiphenyl urea ................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,2’,3’,4,4’,6-Hexanitrodiphenylamine ............................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Hexanitrodiphenylamine or Dipicrylamine or Hexyl ........................................................................ 1.1D UN0079 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............2,3’,4,4’,6,6’-Hexanitrodiphenylether ............................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hexanitroethane .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Hexanitrooxanilide ........................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hexanitrostilbene ............................................................................................................................. 1.1D UN0392 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Hexanoic acid, see Corrosive liquids, n.o.s. ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Hexanols .......................................................................................................................................... 3 UN2282 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 741-Hexene ......................................................................................................................................... 3 UN2370 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Hexogen and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and 

HMX mixtures, wetted or desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Hexogen and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or

desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Hexogen and octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or

desensitized etc.

.................... ........... .......... .......... .......... .................... .................... ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76103

Hexogen, see Cyclotrimethylenetrinitramine, etc ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Hexolite, or Hexotol dry or wetted with less than 15 percent water, by mass ............................... 1.1D UN0118 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Hexotonal ........................................................................................................................................ 1.1D UN0393 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Hexyl, see Hexanitrodiphenylamine ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Hexyltrichlorosilane ......................................................................................................................... 8 UN1784 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

High explosives, see individual explosives’ entries ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............HMX, see Cyclotetramethylenete tranitramine, etc ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Hydrazine, anhydrous ..................................................................................................................... 8 UN2029 I 8, 3, 

6.1.

A3, A6, A7, A10, 

B7, B16, B53

None .... 201 ...... 243 ...... Forbidden 2.5 L D 40, 125

Hydrazine, aqueous solution with not more than 37 percent hydrazine, by mass ........................ 6.1 UN3293 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Hydrazine azide ............................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hydrazine chlorate .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hydrazine dicarbonic acid diazide .................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Hydrazine aqueous solution, with more than 37% hydrazine, by mass ......................................... 8 UN2030 I 8, 6.1 151, B16, B53, 

T10, TP2, TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L D 40

.......................................................................................................................................................... .................... II 8, 6.1 B16, B53, IB2, 

T7, TP2, TP13

None .... 202 ...... 243 ...... Forbidden 30 L D 40

.......................................................................................................................................................... .................... III 8, 6.1 B16, B53, IB3, 

T4, TP1

154 ...... 203 ...... 241 ...... 5 L 60 L D 40

Hydrazine perchlorate ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hydrazine selenate .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hydriodic acid, anhydrous, see Hydrogen iodide, anhydrous ........................................................ .................... ........... .......... .......... .......... .................... .................... ............Hydriodic acid .................................................................................................................................. 8 UN1787 II 8 ........ A3, A6, B2, IB2, 

N41, T7, TP2

154 ...... 202 ...... 242 ...... 1 L 30 L C ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L C 8

Hydrobromic acid, anhydrous, see Hydrogen bromide, anhydrous ............................................... .................... ........... .......... .......... .......... .................... .................... ............Hydrobromic acid, with more than 49 percent hydrobromic acid ................................................... 8 UN1788 II 8 ........ B2, B15, IB2, 

N41, T7, TP2

154 ...... 202 ...... 242 ...... Forbidden Forbidden C ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... Forbidden Forbidden C 8

Hydrobromic acid, with not more than 49 percent hydrobromic acid ............................................. 8 UN1788 II 8 ........ A3, A6, B2, B15, 

IB2, N41, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L C ............

.......................................................................................................................................................... .................... III 8 ........ A3, IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L C 8

Hydrocarbon gas mixture, compressed, n.o.s. ............................................................................... 2.1 UN1964 ............ 2.1 ..... 306 ...... 302 ...... 314, 

315.

Forbidden 150 kg E 40

Hydrocarbon gas mixture, liquefied, n.o.s. ..................................................................................... 2.1 UN1965 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Hydrocarbons, liquid, n.o.s. ............................................................................................................. 3 UN3295 I 3 ........ 144, T11, TP1, 

TP8, TP28

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 144, IB2, T7, 

TP1, TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ 144, B1, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Hydrochloric acid, anhydrous, see Hydrogen chloride, anhydrous ................................................ .................... ........... .......... .......... .......... .................... .................... ............Hydrochloric acid ............................................................................................................................. 8 UN1789 II 8 ........ A3, A6, B3, B15, 

IB2, N41, T8, 

TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L C ............

.......................................................................................................................................................... .................... III 8 ........ A3, IB3, T4, TP1, 

TP12

154 ...... 203 ...... 241 ...... 5 L 60 L C 8

Hydrocyanic acid, anhydrous, see Hydrogen cyanide etc .............................................................. .................... ........... .......... .......... .......... .................... .................... ............Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, aqueous solutions with not more 

than 20 percent hydrogen cyanide.

6.1 UN1613 I 6.1 ..... 2, B61, B65, 

B77, B82, T20, 

TP2, TP13

None .... 195 ...... 244 ...... Forbidden Forbidden D 40

D Hydrocyanic acid, aqueous solutions with less than 5 percent hydrogen cyanide ........................ 6.1 NA1613 II 6.1 ..... IB1, T14, TP2, 

TP13, TP27

None .... 195 ...... 243 ...... Forbidden 5 L D 40

Hydrocyanic acid, liquefied, see Hydrogen cyanide, etc ................................................................ .................... ........... .......... .......... .......... .................... .................... ............Hydrocyanic acid (prussic), unstabilized ......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hydrofluoric acid and Sulfuric acid mixtures ................................................................................... 8 UN1786 I 8, 6.1 A6, A7, B15, 

B23, N5, N34, 

T10, TP2, TP12, 

TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L D 40

Hydrofluoric acid, anhydrous, see Hydrogen fluoride, anhydrous .................................................. .................... ........... .......... .......... .......... .................... .................... ............Hydrofluoric acid, with more than 60 percent strength ................................................................... 8 UN1790 I 8, 6.1 A6, A7, B4, B15, 

B23, N5, N34, 

T10, TP2, TP12, 

TP13

None .... 201 ...... 243 ...... 0.5 L 2.5 L D 12, 40

Hydrofluoric acid, with not more than 60 percent strength ............................................................. 8 UN1790 II 8, 6.1 A6, A7, B15, IB2, 

N5, N34, T8, 

TP2, TP12

154 ...... 202 ...... 243 ...... 1 L 30 L D 12, 40

Hydrofluoroboric acid, see Fluoroboric acid ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Hydrofluorosilicic acid, see Fluorosilicic acid .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............

76104 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Hydrogen and Methane mixtures, compressed .............................................................................. 2.1 UN2034 ............ 2.1 ..... 306 ...... 302 ...... 302, 

314, 315.

Forbidden 150 kg E 40, 57

Hydrogen bromide, anhydrous ........................................................................................................ 2.3 UN1048 ............ 2.3, 8 3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Hydrogen chloride, anhydrous ........................................................................................................ 2.3 UN1050 ............ 2.3, 8 3 None .... 304 ...... None .... Forbidden Forbidden D 40Hydrogen chloride, refrigerated liquid ............................................................................................. 2.3 UN2186 ............ 2.3, 8 3, B6 None .... None .... 314, 

315.

Forbidden Forbidden B 40

Hydrogen, compressed ................................................................................................................... 2.1 UN1049 ............ 2.1 ..... 306 ...... 302 ...... 302, 

314.

Forbidden 150 kg E 40, 57

Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide ............. 6.1 UN3294 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Hydrogen cyanide, stabilized with less than 3 percent water ........................................................ 6.1 UN1051 I 6.1, 3 1, B35, B61, 

B65, B77, B82

None .... 195 ...... 244 ...... Forbidden Forbidden D 40

Hydrogen cyanide, stabilized, with less than 3 percent water and absorbed in a porous inert 

material.

6.1 UN1614 I 6.1 ..... 5 None .... 195 ...... None .... Forbidden Forbidden D 25, 40

Hydrogen fluoride, anhydrous ......................................................................................................... 8 UN1052 I 8, 6.1 3, B7, B46, B71, 

B77, T10, TP2

None .... 163 ...... 243 ...... Forbidden Forbidden D 40

Hydrogen in a metal hydride storage system ................................................................................. 2.1 UN3468 ............ 2.1 ..... 167 None .... 214 ...... None .... Forbidden Forbidden D ............Hydrogen iodide, anhydrous ........................................................................................................... 2.3 UN2197 ............ 2.3 ..... 3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Hydrogen iodide solution, see Hydriodic acid, solution .................................................................. .................... ........... .......... .......... .......... .................... .................... ............Hydrogen peroxide and peroxyacetic acid mixtures, stabilized with acids, water and not more 

than 5 percent peroxyacetic acid.

5.1 UN3149 II 5.1, 8 145, A2, A3, A6, 

B53, IB2, IP5, 

T7, TP2, TP6, 

TP24

None .... 202 ...... 243 ...... 1 L 5 L D 25, 66, 

75

Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent 

hydrogen peroxide (stabilized as necessary).

5.1 UN2014 II 5.1, 8 12, B53, B80, 

B81, B85, IB2, 

T7, TP2, TP6, 

TP24, TP37

None .... 202 ...... 243 ...... Forbidden Forbidden D 25, 66, 

75

Hydrogen peroxide, aqueous solutions with not less than 20 percent but not more than 40 percent hydrogen peroxide (stabilized as necessary). 5.1 UN2014 II 5.1, 8 A2, A3, A6, B53, IB2, IP5, T7, 

TP2, TP6, TP24, 

TP37

None .... 202 ...... 243 ...... 1 L 5 L D 25, 66, 

75

Hydrogen peroxide, aqueous solutions with not less than 8 percent but less than 20 percent 

hydrogen peroxide (stabilized as necessary).

5.1 UN2984 III 5.1 ..... A1, IB2, IP5, T4, 

TP1, TP6, TP24, 

TP37

152 ...... 203 ...... 241 ...... 2.5 L 30 L B 25, 66, 

75

Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more 

than 60 percent hydrogen peroxide.

5.1 UN2015 I 5.1, 8 12, B53, B80, 

B81, B85, T10, 

TP2, TP6, TP24, 

TP37

None .... 201 ...... 243 ...... Forbidden Forbidden D 25, 66, 

75

Hydrogen, refrigerated liquid (cryogenic liquid) .............................................................................. 2.1 UN1966 ............ 2.1 ..... T75, TP5 None .... 316 ...... 318, 

319.

Forbidden Forbidden D 40

Hydrogen selenide, anhydrous ....................................................................................................... 2.3 UN2202 ............ 2.3, 

2.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

Hydrogen sulfate, see Sulfuric acid ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Hydrogen sulfide ............................................................................................................................. 2.3 UN1053 ............ 2.3, 

2.1.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Hydrogendifluorides, n.o.s. .............................................................................................................. 8 UN1740 II 8 ........ IB8, IP2, IP4, 

N3, N34, T3, 

TP33

None .... 212 ...... 240 ...... 15 kg 50 kg A 25, 40, 

52

.......................................................................................................................................................... .................... III 8 ........ IB8, IP3, N3, 

N34, T1, TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 25, 40, 

52

Hydroquinone, solid ......................................................................................................................... 6.1 UN2662 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Hydroquinone solution ..................................................................................................................... 6.1 UN3435 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Hydrosilicofluoric acid, see Fluorosilicic acid .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Hydroxyl amine iodide ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Hydroxylamine sulfate ..................................................................................................................... 8 UN2865 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76105

Hypochlorite solutions ..................................................................................................................... 8 UN1791 II 8 ........ A7, B2, B15, IB2, 

IP5, N34, T7, 

TP2, TP24

154 ...... 202 ...... 242 ...... 1 L 30 L B 26

.......................................................................................................................................................... .................... III 8 ........ IB3, N34, T4, 

TP2, TP24

154 ...... 203 ...... 241 ...... 5 L 60 L B 26

Hypochlorites, inorganic, n.o.s. ....................................................................................................... 5.1 UN3212 II 5.1 ..... A9, IB8, IP2, IP4, 

T3, TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg D 4, 48, 

52, 56, 

58, 69, 

106, 

116 

118

Hyponitrous acid .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Igniter fuse, metal clad, see Fuse, igniter, tubular, metal clad ....................................................... .................... ........... .......... .......... .......... .................... .................... ............Igniters ............................................................................................................................................. 1.1G UN0121 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Igniters ............................................................................................................................................. 1.2G UN0314 II 1.2G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Igniters ............................................................................................................................................. 1.3G UN0315 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Igniters ............................................................................................................................................. 1.4G UN0325 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Igniters ............................................................................................................................................. 1.4S UN0454 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............3,3’-Iminodipropylamine .................................................................................................................. 8 UN2269 III 8 ........ IB3, T4, TP2 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

G Infectious substances, affecting animals only ................................................................................. 6.2 UN2900 ............ 6.2 ..... A81, A82 134 ...... 196 ...... None .... 50 mL or 50 

g

4 L or 4 kg B 40

G Infectious substances, affecting humans ........................................................................................ 6.2 UN2814 ............ 6.2 ..... A81, A82 134 ...... 196 ...... None .... 50 mL or 50 

g

4 L or 4 kg B 40

Inflammable, see Flammable .......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Initiating explosives (dry) ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Inositol hexanitrate (dry) .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............

G Insecticide gases, n.o.s. .................................................................................................................. 2.2 UN1968 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

G Insecticide gases, flammable, n.o.s. ............................................................................................... 2.1 UN3354 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg D 40

G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone A ........................................... 2.3 UN3355 ............ 2.3, 

2.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone B ........................................... 2.3 UN3355 ............ 2.3, 

2.1.

2, B9, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D 40

G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone C ........................................... 2.3 UN3355 ............ 2.3, 

2.1.

3, B14 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D ............

G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone D ........................................... 2.3 UN3355 ............ 2.3, 

2.1.

4 None .... 302, 

305.

314, 

315.

Forbidden Forbidden D ............

G Insecticide gases, toxic, n.o.s. ........................................................................................................ 2.3 UN1967 ............ 2.3 ..... 3 None .... 193, 

334.

245 ...... Forbidden Forbidden D 40

Inulin trinitrate (dry) ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Iodine azide (dry) ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Iodine monochloride ........................................................................................................................ 8 UN1792 II 8 ........ B6, IB8, IP2, IP4, 

N41, T7, TP2

None .... 212 ...... 240 ...... Forbidden 50 kg D 40, 66, 

74, 89, 

90

Iodine pentafluoride ......................................................................................................................... 5.1 UN2495 I 5.1, 

6.1, 8.

None .... 205 ...... 243 ...... Forbidden Forbidden D 25, 40, 

52, 66, 

90

2-Iodobutane ................................................................................................................................... 3 UN2390 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Iodomethylpropanes ........................................................................................................................ 3 UN2391 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Iodopropanes ................................................................................................................................... 3 UN2392 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Iodoxy compounds (dry) .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Iridium nitratopentamine iridium nitrate ........................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Iron chloride, see Ferric chloride .................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Iron oxide, spent, or Iron sponge, spent obtained from coal gas purification ................................ 4.2 UN1376 III 4.2 ..... B18, IB8, IP3, 

T1, TP33

None .... 213 ...... 240 ...... Forbidden Forbidden E ............

Iron pentacarbonyl ........................................................................................................................... 6.1 UN1994 I 6.1, 3 1, B9, B14, B30, 

B72, B77, T22, 

TP2, TP13, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Iron sesquichloride, see Ferric chloride .......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Irritating material, see Tear gas substances, etc ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Isobutane see also Petroleum gases, liquefied .............................................................................. 2.1 UN1969 ............ 2.1 ..... 19, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Isobutanol or Isobutyl alcohol ......................................................................................................... 3 UN1212 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isobutyl acetate ............................................................................................................................... 3 UN1213 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isobutyl acrylate, stabilized ............................................................................................................. 3 UN2527 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isobutyl alcohol, see Isobutanol ...................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Isobutyl aldehyde, see Isobutyraldehyde ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............

D Isobutyl chloroformate ..................................................................................................................... 6.1 NA2742 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... 1 L 30 L A 12, 13, 

22, 25, 

40, 48, 

100

Isobutyl formate ............................................................................................................................... 3 UN2393 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isobutyl isobutyrate ......................................................................................................................... 3 UN2528 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

76106 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

+ Isobutyl isocyanate .......................................................................................................................... 3 UN2486 I 3, 6.1 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP27

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Isobutyl methacrylate, stabilized ..................................................................................................... 3 UN2283 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isobutyl propionate .......................................................................................................................... 3 UN2394 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L B ............Isobutylamine .................................................................................................................................. 3 UN1214 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40Isobutylene see also Petroleum gases, liquefied ........................................................................... 2.1 UN1055 ............ 2.1 ..... 19, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Isobutyraldehyde or Isobutyl aldehyde ........................................................................................... 3 UN2045 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E 40Isobutyric acid ................................................................................................................................. 3 UN2529 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A ............Isobutyronitrile ................................................................................................................................. 3 UN2284 II 3, 6.1 IB2, T7, TP2, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Isobutyryl chloride ........................................................................................................................... 3 UN2395 II 3, 8 .... IB1, T7, TP2 150 ...... 202 ...... 243 ...... 1 L 5 L C 40

G Isocyanates, flammable, toxic, n.o.s. or Isocyanate solutions, flammable, toxic, n.o.s. flash point 

less than 23 degrees C.

3 UN2478 II 3, 6.1 5, A3, A7, IB2, 

T11, TP2, TP13, 

TP27

150 ...... 202 ...... 243 ...... 1 L 60 L D 40

.......................................................................................................................................................... .................... III 3, 6.1 5, A3, A7, IB3, 

T7, TP1, TP13, 

TP28

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Isocyanates, toxic, flammable, n.o.s. or Isocyanate solutions, toxic, flammable, n.o.s., flash 

point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C.

6.1 UN3080 II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 25, 40, 

48

G Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C. 6.1 UN2206 II 6.1 ..... IB2, T11, TP2, TP13, TP27 153 ...... 202 ...... 243 ...... 5 L 60 L E 25, 40, 48

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP13, TP28

153 ...... 203 ...... 241 ...... 60 L 220 L E 25, 40, 

48

Isocyanatobenzotrifluorides ............................................................................................................. 6.1 UN2285 II 6.1, 3 5, IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L D 25, 40, 

48

Isoheptenes ..................................................................................................................................... 3 UN2287 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isohexenes ...................................................................................................................................... 3 UN2288 II 3 ........ IB2, IP8, T11, 

TP1

150 ...... 202 ...... 242 ...... 5 L 60 L E ............

Isooctane, see Octanes .................................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Isooctenes ....................................................................................................................................... 3 UN1216 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isopentane, see Pentane ................................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Isopentanoic acid, see Corrosive liquids, n.o.s. ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Isopentenes ..................................................................................................................................... 3 UN2371 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E ............Isophorone diisocyanate ................................................................................................................. 6.1 UN2290 III 6.1 ..... IB3, T4, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L B 40Isophoronediamine .......................................................................................................................... 8 UN2289 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Isoprene, stabilized ......................................................................................................................... 3 UN1218 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E ............Isopropanol or Isopropyl alcohol ..................................................................................................... 3 UN1219 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isopropenyl acetate ......................................................................................................................... 3 UN2403 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isopropenylbenzene ........................................................................................................................ 3 UN2303 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isopropyl acetate ............................................................................................................................. 3 UN1220 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isopropyl acid phosphate ................................................................................................................ 8 UN1793 III 8 ........ IB2, T4, TP1 154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............Isopropyl alcohol, see Isopropanol ................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Isopropyl butyrate ............................................................................................................................ 3 UN2405 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isopropyl chloroacetate ................................................................................................................... 3 UN2947 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isopropyl chloroformate ................................................................................................................... 6.1 UN2407 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP44

None .... 227 ...... 244 ...... Forbidden Forbidden B 40

Isopropyl 2-chloropropionate ........................................................................................................... 3 UN2934 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isopropyl isobutyrate ....................................................................................................................... 3 UN2406 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

+ Isopropyl isocyanate ........................................................................................................................ 3 UN2483 I 3, 6.1 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Isopropyl mercaptan, see Propanethiols ......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Isopropyl nitrate ............................................................................................................................... 3 UN1222 II 3 ........ IB99 150 ...... 202 ...... None .... 5 L 60 L D ............Isopropyl phosphoric acid, see Isopropyl acid phosphate .............................................................. .................... ........... .......... .......... .......... .................... .................... ............Isopropyl propionate ........................................................................................................................ 3 UN2409 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Isopropylamine ................................................................................................................................ 3 UN1221 I 3, 8 .... T11, TP2 None .... 201 ...... 243 ...... 0.5 L 2.5 L E ............Isopropylbenzene ............................................................................................................................ 3 UN1918 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Isopropylcumyl hydroperoxide, with more than 72 percent in solution .......................................... Forbidden ........... .......... .......... .......... .................... .................... ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76107

Isosorbide dinitrate mixture with not less than 60 percent lactose, mannose, starch or calcium 

hydrogen phosphate.

4.1 UN2907 II 4.1 ..... IB6, IP2, N85 None .... 212 ...... None .... 15 kg 50 kg E 28, 36

Isosorbide-5-mononitrate ................................................................................................................. 4.1 UN3251 III 4.1 ..... 66, IB8 151 ...... 213 ...... 240 ...... Forbidden Forbidden D 12Isothiocyanic acid ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Jet fuel, see Fuel aviation, turbine engine ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

D Jet perforating guns, charged oil well, with detonator .................................................................... 1.1D NA0124 II 1.1D .. 55, 56 None .... 62 ........ None .... Forbidden Forbidden 07 ............D Jet perforating guns, charged oil well, with detonator .................................................................... 1.4D NA0494 II 1.4D .. 55, 56 None .... 62 ........ None .... Forbidden Forbidden 06 ............

Jet perforating guns, charged oil well, without detonator ............................................................... 1.1D UN0124 II 1.1D .. 55 None .... 62 ........ None .... Forbidden Forbidden 07 ............Jet perforating guns, charged, oil well, without detonator .............................................................. 1.4D UN0494 II 1.4D .. 55, 114 None .... 62 ........ None .... Forbidden 300 kg 06 ............Jet perforators, see Charges, shaped, etc ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Jet tappers, without detonator, see Charges, shaped, etc ............................................................. .................... ........... .......... .......... .......... .................... .................... ............Jet thrust igniters, for rocket motors or Jato, see Igniters .............................................................. .................... ........... .......... .......... .......... .................... .................... ............Jet thrust unit (Jato), see Rocket motors ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Kerosene ......................................................................................................................................... 3 UN1223 III 3 ........ 144, B1, IB3, T2, 

TP2

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Ketones, liquid, n.o.s. ...................................................................................................................... 3 UN1224 I 3 ........ T11, TP1, TP8, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Krypton, compressed ...................................................................................................................... 2.2 UN1056 ............ 2.2 ..... 306 ...... 302 ...... None .... 75 kg 150 kg A ............Krypton, refrigerated liquid (cryogenic liquid) ................................................................................. 2.2 UN1970 ............ 2.2 ..... T75, TP5 320 ...... None .... None .... 50 kg 500 kg B ............Lacquer base or lacquer chips, nitrocellulose, dry, see Nitrocellulose, etc. (UN 2557) ................ .................... ........... .......... .......... .......... .................... .................... ............Lacquer base or lacquer chips, plastic, wet with alcohol or solvent, see Nitrocellulose (UN2059, 

UN2555, UN2556, UN2557) or Paint etc.(UN1263).

.................... ........... .......... .......... .......... .................... .................... ............

Lead acetate .................................................................................................................................... 6.1 UN1616 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Lead arsenates ................................................................................................................................ 6.1 UN1617 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Lead arsenites ................................................................................................................................. 6.1 UN1618 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Lead azide (dry) .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Lead azide, wetted with not less than 20 percent water or mixture of alcohol and water, by 

mass.

1.1A UN0129 II 1.1A ... 111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............

Lead compounds, soluble, n.o.s. .................................................................................................... 6.1 UN2291 III 6.1 ..... 138, IB8, IP3, 

T1, TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Lead cyanide ................................................................................................................................... 6.1 UN1620 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52

Lead dioxide .................................................................................................................................... 5.1 UN1872 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Lead dross, see Lead sulfate, with more than 3 percent free acid ................................................ .................... ........... .......... .......... .......... .................... .................... ............Lead nitrate ..................................................................................................................................... 5.1 UN1469 II 5.1, 

6.1.

IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A ............

Lead nitroresorcinate (dry) .............................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Lead perchlorate, solid .................................................................................................................... 5.1 UN1470 II 5.1, 

6.1.

IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Lead perchlorate, solution ............................................................................................................... 5.1 UN3408 III 5.1, 

6.1.

IB2, T4, TP1 152 ...... 203 ...... 242 ...... 2.5 L 30 L A 56, 58

.......................................................................................................................................................... .................... II 5.1, 

6.1.

IB2, T4, TP1 152 ...... 202 ...... 243 ...... 1 L 5 L A 56, 58

Lead peroxide, see Lead dioxide .................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Lead phosphite, dibasic .................................................................................................................. 4.1 UN2989 II 4.1 ..... IB8, IP2, IP4, T3, 

TP33

None .... 212 ...... 240 ...... 5 kg 25 kg B 34

.......................................................................................................................................................... .................... III 4.1 ..... IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 15 kg 50 kg B 34

Lead picrate (dry) ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Lead styphnate (dry) ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Lead styphnate, wetted or Lead trinitroresorcinate, wetted with not less than 20 percent water 

or mixture of alcohol and water, by mass.

1.1A UN0130 II 1.1A ... 111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............

Lead sulfate with more than 3 percent free acid ............................................................................ 8 UN1794 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Lead trinitroresorcinate, see Lead styphnate, etc ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Life-saving appliances, not self inflating containing dangerous goods as equipment ................... 9 UN3072 ............ None ............................ None .... 219 ...... None .... No limit No limit A ............Life-saving appliances, self inflating ............................................................................................... 9 UN2990 ............ None None .... 219 ...... None .... No limit No limit A ............Lighter replacement cartridges containing liquefied petroleum gases (and similar devices, each 

not exceeding 65 grams), see Lighters or lighter refills etc. containing flammable gas.

.................... ........... .......... .......... .......... .................... .................... ............

Lighters, fuse ................................................................................................................................... 1.4S UN0131 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Lighters or Lighter refills containing flammable gas ....................................................................... 2.1 UN1057 ............ 2.1 ..... N10 None .... 21, 308 None .... 1 kg 15 kg B 40Lime, unslaked, see Calcium oxide ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............

G Liquefied gas, flammable, n.o.s. ..................................................................................................... 2.1 UN3161 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg D 40

G Liquefied gas, n.o.s. ........................................................................................................................ 2.2 UN3163 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

G Liquefied gas, oxidizing, n.o.s. ........................................................................................................ 2.2 UN3157 ............ 2.2, 

5.1.

A14 306 ...... 304 ...... 314, 

315.

75 kg 150 kg D ............

76108 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A ................................................... 2.3 UN3308 ............ 2.3, 8 1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B ................................................... 2.3 UN3308 ............ 2.3, 8 2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C ................................................... 2.3 UN3308 ............ 2.3, 8 3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D ................................................... 2.3 UN3308 ............ 2.3, 8 4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G I Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A ................................ 2.3 UN3309 ............ 2.3, 

2.1, 8.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 17, 40

G I Liquefied gas toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B ................................. 2.3 UN3309 ............ 2.3, 

2.1, 8.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 17, 40

G I Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C ................................ 2.3 UN3309 ............ 2.3, 

2.1, 8.

3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 17, 40

G I Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D ................................ 2.3 UN3309 ............ 2.3, 

2.1, 8.

4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 17, 40

G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone A ................................................. 2.3 UN3160 ............ 2.3, 

2.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone B ................................................. 2.3 UN3160 ............ 2.3, 

2.1.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C ................................................. 2.3 UN3160 ............ 2.3, 

2.1.

3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D ................................................. 2.3 UN3160 ............ 2.3, 

2.1.

4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A .................................................................... 2.3 UN3162 ............ 2.3 ..... 1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone B .................................................................... 2.3 UN3162 ............ 2.3 ..... 2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone C .................................................................... 2.3 UN3162 ............ 2.3 ..... 3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone D .................................................................... 2.3 UN3162 ............ 2.3 ..... 4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone A ................................... 2.3 UN3310 ............ 2.3, 

5.1, 8.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40, 89, 

90

G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B ................................... 2.3 UN3310 ............ 2.3, 

5.1, 8.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 89, 

90

G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C ................................... 2.3 UN3310 ............ 2.3, 

5.1, 8.

3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 89, 

90

G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D ................................... 2.3 UN3310 ............ 2.3, 

5.1, 8.

4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40, 89, 

90

G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A .................................................... 2.3 UN3307 ............ 2.3, 

5.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B .................................................... 2.3 UN3307 ............ 2.3, 

5.1.

2, B9, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C ................................................... 2.3 UN3307 ............ 2.3, 

5.1.

3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D ................................................... 2.3 UN3307 ............ 2.3, 

5.1.

4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Liquefied gases, non-flammable charged with nitrogen, carbon dioxide or air .............................. 2.2 UN1058 ............ 2.2 ..... 306 ...... 304 ...... None .... 75 kg 150 kg A ............Liquefied hydrocarbon gas, see Hydrocarbon gas mixture, liquefied, n.o.s. ................................. .................... ........... .......... .......... .......... .................... .................... ............Liquefied natural gas, see Methane, etc. (UN 1972) ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Liquefied petroleum gas see Petroleum gases, liquefied ............................................................... .................... ........... .......... .......... .......... .................... .................... ............Lithium ............................................................................................................................................. 4.3 UN1415 I 4.3 ..... A7, A19, IB4, 

IP1, N45

None .... 211 ...... 244 ...... Forbidden 15 kg E 52

Lithium acetylide ethylenediamine complex, see Water reactive solid etc .................................... .................... ........... .......... .......... .......... .................... .................... ............Lithium alkyls, liquid ........................................................................................................................ 4.2 UN2445 I 4.2, 

4.3.

B11, T21, TP2, 

TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D ............

Lithium alkyls, solid ......................................................................................................................... 4.2 UN3433 I 4.2, 

4.3.

B11, T21, TP7, 

TP33

None .... 181 ...... 244 ...... Forbidden Forbidden D ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76109

Lithium aluminum hydride ............................................................................................................... 4.3 UN1410 I 4.3 ..... A19 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Lithium aluminum hydride, ethereal ................................................................................................ 4.3 UN1411 I 4.3, 3 A2, A3, A11, 

N34

None .... 201 ...... 244 ...... Forbidden 1 L D 40

Lithium batteries, contained in equipment ...................................................................................... 9 UN3091 II 9 ........ 29, A54, A55, 

A102, A104

185 ...... 185 ...... None .... 5 kg 5 kg A ............

Lithium batteries packed with equipment ........................................................................................ 9 UN3091 II 9 ........ 29, A54, A55, 

A101, A103

185 ...... 185 ...... None .... 5 kg gross 35 kg gross A ............

Lithium battery ................................................................................................................................. 9 UN3090 II 9 ........ 29, A54, A55, 

A100

185 ...... 185 ...... None .... 5 kg gross 35 kg gross A ............

Lithium borohydride ......................................................................................................................... 4.3 UN1413 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Lithium ferrosilicon .......................................................................................................................... 4.3 UN2830 II 4.3 ..... A19, IB7, IP2, 

T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg E 40, 85, 

103

Lithium hydride ................................................................................................................................ 4.3 UN1414 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Lithium hydride, fused solid ............................................................................................................ 4.3 UN2805 II 4.3 ..... A8, A19, A20, 

IB4, T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg E 52

Lithium hydroxide ............................................................................................................................ 8 UN2680 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Lithium hydroxide, solution .............................................................................................................. 8 UN2679 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 29

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP2 154 ...... 203 ...... 241 ...... 5 L 60 L A 29, 96

Lithium hypochlorite, dry with more than 39% available chlorine (8.8% available oxygen) or

Lithium hypochlorite mixtures, dry with more than 39% available chlorine (8.8% available oxygen).

5.1 UN1471 II 5.1 ..... A9, IB8, IP2, IP4, 

N34

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 4, 48, 

52, 56, 58, 69, 

106, 

116

Lithium in cartridges, see Lithium ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Lithium nitrate .................................................................................................................................. 5.1 UN2722 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Lithium nitride .................................................................................................................................. 4.3 UN2806 I 4.3 ..... A19, IB4, IP1, 

N40

None .... 211 ...... 242 ...... Forbidden 15 kg E ............

Lithium peroxide .............................................................................................................................. 5.1 UN1472 II 5.1 ..... A9, IB6, IP2, 

N34, T3, TP33

152 ...... 212 ...... None .... 5 kg 25 kg A 13, 52, 

66, 75

Lithium silicon .................................................................................................................................. 4.3 UN1417 II 4.3 ..... A19, A20, IB7, 

IP2, T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg A 85, 103

LNG, see Methane etc. (UN 1972) ................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............London purple ................................................................................................................................. 6.1 UN1621 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

LPG, see Petroleum gases, liquefied ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Lye, see Sodium hydroxide, solutions ............................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Magnesium alkyls ............................................................................................................................ 4.2 UN3053 I 4.2, 

4.3.

B11, T21, TP2, 

TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D 18

Magnesium aluminum phosphide ................................................................................................... 4.3 UN1419 I 4.3, 

6.1.

A19, N34, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 40, 52, 

85

+ Magnesium arsenate ....................................................................................................................... 6.1 UN1622 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Magnesium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. ......................................... .................... ........... .......... .......... .......... .................... .................... ............Magnesium bromate ........................................................................................................................ 5.1 UN1473 II 5.1 ..... A1, IB8, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Magnesium chlorate ........................................................................................................................ 5.1 UN2723 II 5.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Magnesium diamide ........................................................................................................................ 4.2 UN2004 II 4.2 ..... A8, A19, A20, 

IB6, T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg C ............

Magnesium diphenyl ....................................................................................................................... 4.2 UN2005 I 4.2 ..... T21, TP7, TP33 None .... 187 ...... 244 ...... Forbidden Forbidden C ............Magnesium dross, wet or hot .......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Magnesium fluorosilicate ................................................................................................................. 6.1 UN2853 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Magnesium granules, coated, particle size not less than 149 microns .......................................... 4.3 UN2950 III 4.3 ..... A1, A19, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A 52

Magnesium hydride ......................................................................................................................... 4.3 UN2010 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Magnesium or Magnesium alloys with more than 50 percent magnesium in pellets, turnings or 

ribbons.

4.1 UN1869 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A 39, 52, 

53, 74, 

101

Magnesium nitrate ........................................................................................................................... 5.1 UN1474 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Magnesium perchlorate ................................................................................................................... 5.1 UN1475 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Magnesium peroxide ....................................................................................................................... 5.1 UN1476 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 13, 52, 

66, 75

Magnesium phosphide .................................................................................................................... 4.3 UN2011 I 4.3, 

6.1.

A19, N40 None .... 211 ...... None .... Forbidden 15 kg E 40, 52, 

85

Magnesium, powder or Magnesium alloys, powder ....................................................................... 4.3 UN1418 I 4.3, 

4.2.

A19, B56 None .... 211 ...... 244 ...... Forbidden 15 kg A 39, 52

.......................................................................................................................................................... .................... II 4.3, 

4.2.

A19, B56, IB5, 

IP2, T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg A 39, 52

.......................................................................................................................................................... .................... III 4.3, 

4.2.

A19, B56, IB8, 

IP4, T1, TP33

None .... 213 ...... 241 ...... 25 kg 100 kg A 39, 52

76110 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Magnesium scrap, see Magnesium, etc. (UN 1869) ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Magnesium silicide .......................................................................................................................... 4.3 UN2624 II 4.3 ..... A19, A20, IB7, 

IP2, T3, TP33

151 ...... 212 ...... 241 ...... 15 kg 50 kg B 85, 103

Magnetized material, see § 173.21 ................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Maleic anhydride ............................................................................................................................. 8 UN2215 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Maleic anhydride, molten ................................................................................................................ 8 UN2215 III 8 ........ T4, TP3 None .... 213 ...... 240 ...... Forbidden Forbidden A ............Malononitrile .................................................................................................................................... 6.1 UN2647 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 12

Mancozeb (manganese ethylenebisdithiocarbamate complex with zinc) see Maneb .................... .................... ........... .......... .......... .......... .................... .................... ............Maneb or Maneb preparations with not less than 60 percent maneb ............................................ 4.2 UN2210 III 4.2, 

4.3.

57, A1, A19, IB6, 

T1, TP33

None .... 213 ...... 242 ...... 25 kg 100 kg A 34

Maneb stabilized or Maneb preparations, stabilized against self-heating ...................................... 4.3 UN2968 III 4.3 ..... 54, A1, A19, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 242 ...... 25 kg 100 kg B 34, 52

Manganese nitrate ........................................................................................................................... 5.1 UN2724 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Manganese resinate ........................................................................................................................ 4.1 UN1330 III 4.1 ..... A1, IB6, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Mannitan tetranitrate ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Mannitol hexanitrate (dry) ............................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Mannitol hexanitrate, wetted or Nitromannite, wetted with not less than 40 percent water, or 

mixture of alcohol and water, by mass.

1.1D UN0133 II 1.1D .. 121 None .... 62 ........ None .... Forbidden Forbidden 10 ............

Marine pollutants, liquid or solid, n.o.s., see Environmentally hazardous substances, liquid or

solid, n.o.s..

.................... ........... .......... .......... .......... .................... .................... ............

Matches, block, see Matches, ’strike anywhere’ ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Matches, fusee ................................................................................................................................ 4.1 UN2254 III 4.1 ..... 186 ...... 186 ...... None .... Forbidden Forbidden A ............Matches, safety (book, card or strike on box) ................................................................................ 4.1 UN1944 III 4.1 ..... 186 ...... 186 ...... None .... 25 kg 100 kg A ............Matches, strike anywhere ............................................................................................................... 4.1 UN1331 III 4.1 ..... 186 ...... 186 ...... None .... Forbidden Forbidden B ............Matches, wax, Vesta ....................................................................................................................... 4.1 UN1945 III 4.1 ..... 186 ...... 186 ...... None .... 25 kg 100 kg B ............Matting acid, see Sulfuric acid ........................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Medicine, liquid, flammable, toxic, n.o.s. ........................................................................................ 3 UN3248 II 3, 6.1 36, IB2 150 ...... 202 ...... None .... 1 L 5 L B 40

.......................................................................................................................................................... .................... III 3, 6.1 36, IB3 150 ...... 203 ...... None .... 5 L 5 L A ............

Medicine, liquid, toxic, n.o.s. ........................................................................................................... 6.1 UN1851 II 6.1 ..... 36 153 ...... 202 ...... 243 ...... 5 L 5 L C 40

.......................................................................................................................................................... .................... III 6.1 ..... 36 153 ...... 203 ...... 241 ...... 5 L 5 L C 40

Medicine, solid, toxic, n.o.s. ............................................................................................................ 6.1 UN3249 II 6.1 ..... 36, T3, TP33 153 ...... 212 ...... None .... 5 kg 5 kg C 40

.......................................................................................................................................................... .................... III 6.1 ..... 36, T1, TP33 153 ...... 213 ...... None .... 5 kg 5 kg C 40

Memtetrahydrophthalic anhydride, see Corrosive liquids, n.o.s. .................................................... .................... ........... .......... .......... .......... .................... .................... ............Mercaptans, liquid, flammable, n.o.s. or Mercaptan mixture, liquid, flammable, n.o.s. ................. 3 UN3336 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E 95

.......................................................................................................................................................... .................... II 3 ........ IB2, T7, TP1, 

TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B 95

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 241 ...... 60 L 220 L B 95

Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, 

n.o.s..

3 UN1228 II 3, 6.1 IB2, T11, TP2, 

TP27

None .... 202 ...... 243 ...... Forbidden 60 L B 40, 95

.......................................................................................................................................................... .................... III 3, 6.1 A6, B1, IB3, T7, 

TP1, TP28

150 ...... 203 ...... 242 ...... 5 L 220 L A 40, 95

Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan mixtures, liquid, toxic, flammable, 

n.o.s., flash point not less than 23 degrees C.

6.1 UN3071 II 6.1, 3 A6, IB2, T11, 

TP2, TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L C 40, 121

5-Mercaptotetrazol-1-acetic acid ..................................................................................................... 1.4C UN0448 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 09 ............Mercuric arsenate ............................................................................................................................ 6.1 UN1623 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercuric chloride ............................................................................................................................. 6.1 UN1624 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercuric compounds, see Mercury compounds, etc ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Mercuric nitrate ................................................................................................................................ 6.1 UN1625 II 6.1 ..... IB8, IP2, IP4, 

N73, T3, TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

+ Mercuric potassium cyanide ............................................................................................................ 6.1 UN1626 I 6.1 ..... IB7, IP1, N74, 

N75, T6, TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 52

Mercuric sulfocyanate, see Mercury thiocyanate ............................................................................ .................... ........... .......... .......... .......... .................... .................... ............Mercurol, see Mercury nucleate ...................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Mercurous azide .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Mercurous compounds, see Mercury compounds, etc ................................................................... .................... ........... .......... .......... .......... .................... .................... ............Mercurous nitrate ............................................................................................................................ 6.1 UN1627 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

A W Mercury ............................................................................................................................................ 8 UN2809 III 8 ........ 164 ...... 164 ...... 240 ...... 35 kg 35 kg B 40, 97

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76111

Mercury acetate ............................................................................................................................... 6.1 UN1629 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury acetylide ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Mercury ammonium chloride ........................................................................................................... 6.1 UN1630 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ............... 3 UN2778 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Mercury based pesticides, liquid, toxic ........................................................................................... 6.1 UN3012 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Mercury based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C ........ 6.1 UN3011 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Mercury based pesticides, solid, toxic ............................................................................................ 6.1 UN2777 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Mercury benzoate ............................................................................................................................ 6.1 UN1631 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury bromides ............................................................................................................................ 6.1 UN1634 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury compounds, liquid, n.o.s. .................................................................................................. 6.1 UN2024 I 6.1 ..... None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... 5 L 60 L B 40.......................................................................................................................................................... .................... III 6.1 ..... IB3 153 ...... 203 ...... 241 ...... 60 L 220 L B 40

Mercury compounds, solid, n.o.s. ................................................................................................... 6.1 UN2025 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

A Mercury contained in manufactured articles ................................................................................... 8 UN2809 III 8 ........ None .... 164 ...... None .... No limit No limit B 40, 97

Mercury cyanide .............................................................................................................................. 6.1 UN1636 II 6.1 ..... IB8, IP2, IP4, 

N74, N75, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52

Mercury fulminate, wetted with not less than 20 percent water, or mixture of alcohol and water, 

by mass.

1.1A UN0135 II 1.1A ... 111, 117 None .... 62 ........ None .... Forbidden Forbidden 12 ............

Mercury gluconate ........................................................................................................................... 6.1 UN1637 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury iodide ................................................................................................................................. 6.1 UN1638 II 6.1 ..... IB2, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury iodide aquabasic ammonobasic (Iodide of Millon’s base) ................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Mercury nitride ................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Mercury nucleate ............................................................................................................................. 6.1 UN1639 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury oleate ................................................................................................................................. 6.1 UN1640 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury oxide .................................................................................................................................. 6.1 UN1641 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury oxycyanide ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Mercury oxycyanide, desensitized .................................................................................................. 6.1 UN1642 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52, 91

Mercury potassium iodide ............................................................................................................... 6.1 UN1643 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury salicylate ............................................................................................................................ 6.1 UN1644 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

+ Mercury sulfates .............................................................................................................................. 6.1 UN1645 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mercury thiocyanate ........................................................................................................................ 6.1 UN1646 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Mesityl oxide .................................................................................................................................... 3 UN1229 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Metal carbonyls, liquid, n.o.s. .......................................................................................................... 6.1 UN3281 I 6.1 ..... 5, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

76112 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

G Metal carbonyls, solid, n.o.s. ........................................................................................................... 6.1 UN3466 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg D 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg B 40

Metal catalyst, dry ........................................................................................................................... 4.2 UN2881 I 4.2 ..... N34, T21, TP7, 

TP33

None .... 187 ...... None .... Forbidden Forbidden C ............

.......................................................................................................................................................... .................... II 4.2 ..... IB6, IP2, N34, 

T3, TP33

None .... 187 ...... 242 ...... Forbidden 50 kg C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, N34, 

T1, TP33

None .... 187 ...... 241 ...... 25 kg 100 kg C ............

Metal catalyst, wetted with a visible excess of liquid ..................................................................... 4.2 UN1378 II 4.2 ..... A2, A8, IB1, 

N34, T3, TP33

None .... 212 ...... None .... Forbidden 50 kg C ............

Metal hydrides, flammable, n.o.s. ................................................................................................... 4.1 UN3182 II 4.1 ..... A1, IB4, T3, 

TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg E ............

.......................................................................................................................................................... .................... III 4.1 ..... A1, IB4, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg E ............

Metal hydrides, water reactive, n.o.s. ............................................................................................. 4.3 UN1409 I 4.3 ..... A19, N34, N40 None .... 211 ...... 242 ...... Forbidden 15 kg D 52

.......................................................................................................................................................... .................... II 4.3 ..... A19, IB4, N34, 

N40, T3, TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg D 52

Metal powder, self-heating, n.o.s. ................................................................................................... 4.2 UN3189 II 4.2 ..... IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg C ............

Metal powders, flammable, n.o.s. ................................................................................................... 4.1 UN3089 II 4.1 ..... IB8, IP2, IP4, T3, 

TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

.......................................................................................................................................................... .................... III 4.1 ..... IB6, T1, TP33 151 ...... 213 ...... 240 ...... 25 kg 100 kg B ............

Metal salts of methyl nitramine (dry) ............................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............

G Metal salts of organic compounds, flammable, n.o.s. .................................................................... 4.1 UN3181 II 4.1 ..... A1, IB8, IP2, IP4, 

T3, TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg B 40

.......................................................................................................................................................... .................... III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg B 40

Metaldehyde .................................................................................................................................... 4.1 UN1332 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

G Metallic substance, water-reactive, n.o.s. ....................................................................................... 4.3 UN3208 I 4.3 ..... A7, IB4 None .... 211 ...... 242 ...... Forbidden 15 kg E 40

.......................................................................................................................................................... .................... II 4.3 ..... A7, IB7, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg E 40

.......................................................................................................................................................... .................... III 4.3 ..... A7, IB8, IP4, T1, 

TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg E 40

G Metallic substance, water-reactive, self-heating, n.o.s. .................................................................. 4.3 UN3209 I 4.3, 

4.2.

A7 None .... 211 ...... 242 ...... Forbidden 15 kg E 40

.......................................................................................................................................................... .................... II 4.3, 

4.2.

A7, IB5, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg E 40

.......................................................................................................................................................... .................... III 4.3, 

4.2.

A7, IB8, IP4, T1, 

TP33

None .... 213 ...... 242 ...... 25 kg 100 kg E 40

Methacrylaldehyde, stabilized ......................................................................................................... 3 UN2396 II 3, 6.1 45, IB2, T7, TP1, 

TP13

150 ...... 202 ...... 243 ...... 1 L 60 L E 40

Methacrylic acid, stabilized ............................................................................................................. 8 UN2531 II 8 ........ IB2, T7, TP1, 

TP18, TP30

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

+ Methacrylonitrile, stabilized ............................................................................................................. 3 UN3079 I 3, 6.1 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 12, 40, 

48

Methallyl alcohol .............................................................................................................................. 3 UN2614 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methane and hydrogen, mixtures, see Hydrogen and methane, mixtures, etc ............................. .................... ........... .......... .......... .......... .................... .................... ............Methane, compressed or Natural gas, compressed (with high methane content) ......................... 2.1 UN1971 ............ 2.1 ..... 306 ...... 302 ...... 302 ...... Forbidden 150 kg E 40Methane, refrigerated liquid (cryogenic liquid) or Natural gas, refrigerated liquid (cryogenic liquid), with high methane content). 2.1 UN1972 ............ 2.1 ..... T75, TP5 None .... None .... 318 ...... Forbidden Forbidden D 40Methanesulfonyl chloride ................................................................................................................. 6.1 UN3246 I 6.1, 8 2, B9, B14, B32, 

B74, T20, TP2, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76113

+ I Methanol .......................................................................................................................................... 3 UN1230 II 3, 6.1 IB2, T7, TP2 150 ...... 202 ...... 242 ...... 1 L 60 L B 40

D Methanol .......................................................................................................................................... 3 UN1230 II 3 ........ IB2, T7, TP2 150 ...... 202 ...... 242 ...... 1 L 60 L B 40

Methazoic acid ................................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............4-Methoxy-4-methylpentan-2-one ................................................................................................... 3 UN2293 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............1-Methoxy-2-propanol ..................................................................................................................... 3 UN3092 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

+ Methoxymethyl isocyanate .............................................................................................................. 3 UN2605 I 3, 6.1 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Methyl acetate ................................................................................................................................. 3 UN1231 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyl acetylene and propadiene mixtures, stabilized ................................................................... 2.1 UN1060 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Methyl acrylate, stabilized ............................................................................................................... 3 UN1919 II 3 ........ IB2, T4, TP1, 

TP13

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

Methyl alcohol, see Methanol ......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Methyl allyl chloride ......................................................................................................................... 3 UN2554 II 3 ........ IB2, T4, TP1, 

TP13

150 ...... 202 ...... 242 ...... 5 L 60 L E ............

Methyl amyl ketone, see Amyl methyl ketone ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Methyl bromide ................................................................................................................................ 2.3 UN1062 ............ 2.3 ..... 3, B14, T50 None .... 193 ...... 314, 

315.

Forbidden Forbidden D 40

Methyl bromide and chloropicrin mixtures with more than 2 percent chloropicrin, see

Chloropicrin and methyl bromide mixtures.

.................... ........... .......... .......... .......... .................... .................... ............

Methyl bromide and chloropicrin mixtures with not more than 2 percent chloropicrin, see Methyl 

bromide.

.................... ........... .......... .......... .......... .................... .................... ............

Methyl bromide and ethylene dibromide mixtures, liquid ............................................................... 6.1 UN1647 I 6.1 ..... 2, B9, B14, B32, 

B74, N65, T20, 

TP2, TP13, 

TP38, TP44

None .... 227 ...... 244 ...... Forbidden Forbidden C 40

Methyl bromoacetate ....................................................................................................................... 6.1 UN2643 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L D 402-Methlybutanal ............................................................................................................................... 3 UN3371 II ........... 3IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............2-Methyl-1-butene ........................................................................................................................... 3 UN2459 I 3 ........ T11, TP2 None .... 201 ...... 243 ...... 1 L 30 L E ............2-Methyl-2-butene ........................................................................................................................... 3 UN2460 II 3 ........ IB2, IP8, T7, TP1 None .... 202 ...... 242 ...... 5 L 60 L E ............3-Methyl-1-butene ........................................................................................................................... 3 UN2561 I 3 ........ T11, TP2 None .... 201 ...... 243 ...... 1 L 30 L E ............Methyl tert-butyl ether ..................................................................................................................... 3 UN2398 II 3 ........ IB2, T7, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Methyl butyrate ................................................................................................................................ 3 UN1237 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyl chloride, or Refrigerant gas R 40 ........................................................................................ 2.1 UN1063 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

5 kg 100 kg D 40

Methyl chloride and chloropicrin mixtures, see Chloropicrin and methyl chloride mixtures ........... .................... ........... .......... .......... .......... .................... .................... ............Methyl chloride and methylene chloride mixtures ........................................................................... 2.1 UN1912 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg D 40

Methyl chloroacetate ....................................................................................................................... 6.1 UN2295 I 6.1, 3 T14, TP2, TP13 None .... 201 ...... 243 ...... 1 L 30 L D ............Methyl chlorocarbonate, see Methyl chloroformate ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Methyl chloroform, see 1,1,1-Trichloroethane ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Methyl chloroformate ....................................................................................................................... 6.1 UN1238 I 6.1, 3, 

8.

1, B9, B14, B30, 

B72, N34, T22, 

TP2, TP13, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 21, 40, 

100

Methyl chloromethyl ether ............................................................................................................... 6.1 UN1239 I 6.1, 3 1, B9, B14, B30, 

B72, T22, TP2, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Methyl 2-chloropropionate ............................................................................................................... 3 UN2933 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methyl dichloroacetate .................................................................................................................... 6.1 UN2299 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Methyl ethyl ether, see Ethyl methyl ether ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Methyl ethyl ketone, see Ethyl methyl ketone ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Methyl ethyl ketone peroxide, in solution with more than 9 percent by mass active oxygen ........ Forbidden ........... .......... .......... .......... .................... .................... ............2-Methyl-5-ethylpyridine .................................................................................................................. 6.1 UN2300 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Methyl fluoride, or Refrigerant gas R 41 ......................................................................................... 2.1 UN2454 ............ 2.1 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Methyl formate ................................................................................................................................. 3 UN1243 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E ............2-Methyl-2-heptanethiol ................................................................................................................... 6.1 UN3023 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40, 102

Methyl iodide ................................................................................................................................... 6.1 UN2644 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A 12, 40

Methyl isobutyl carbinol ................................................................................................................... 3 UN2053 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methyl isobutyl ketone ..................................................................................................................... 3 UN1245 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyl isobutyl ketone peroxide, in solution with more than 9 percent by mass active oxygen ... Forbidden ........... .......... .......... .......... .................... .................... ............Methyl isocyanate ............................................................................................................................ 6.1 UN2480 I 6.1, 3 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40, 52

Methyl isopropenyl ketone, stabilized ............................................................................................. 3 UN1246 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

76114 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Methyl isothiocyanate ...................................................................................................................... 6.1 UN2477 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A ............

Methyl isovalerate ........................................................................................................................... 3 UN2400 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyl magnesium bromide, in ethyl ether ..................................................................................... 4.3 UN1928 I 4.3, 3 None .... 201 ...... 243 ...... Forbidden 1 L D ............Methyl mercaptan ............................................................................................................................ 2.3 UN1064 ............ 2.3, 

2.1.

3, B7, B9, B14, 

T50

None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Methyl mercaptopropionaldehyde, see Thia-4-pentanal ................................................................. .................... ........... .......... .......... .......... .................... .................... ............Methyl methacrylate monomer, stabilized ....................................................................................... 3 UN1247 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40Methyl nitramine (dry) ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methyl nitrate ................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methyl nitrite .................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methyl norbornene dicarboxylic anhydride, see Corrosive liquids, n.o.s. ...................................... .................... ........... .......... .......... .......... .................... .................... ............Methyl orthosilicate .......................................................................................................................... 6.1 UN2606 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden E 40

D Methyl phosphonic dichloride .......................................................................................................... 6.1 NA9206 I 6.1, 8 2, B9, B14, B32, 

B74, N34, N43, 

T20, TP4, TP12, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden C ............

Methyl phosphonothioic dichloride, anhydrous, see Corrosive liquid, n.o.s. .................................. .................... ........... .......... .......... .......... .................... .................... ............

D Methyl phosphonous dichloride, pyrophoric liquid .......................................................................... 6.1 NA2845 I 6.1, 

4.2.

2, B9, B14, B16, 

B32, B74, T20, 

TP4, TP12, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 18

Methyl picric acid (heavy metal salts of) ......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methyl propionate ............................................................................................................................ 3 UN1248 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyl propyl ether .......................................................................................................................... 3 UN2612 II 3 ........ IB2, IP8, T7, TP2 150 ...... 202 ...... 242 ...... 5 L 60 L E 40Methyl propyl ketone ....................................................................................................................... 3 UN1249 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyl sulfate, see Dimethyl sulfate ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Methyl sulfide, see Dimethyl sulfide ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Methyl trichloroacetate .................................................................................................................... 6.1 UN2533 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Methyl trimethylol methane trinitrate ............................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methyl vinyl ketone, stabilized ........................................................................................................ 6.1 UN1251 I 6.1, 3, 

8.

1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden B 40

Methylal ........................................................................................................................................... 3 UN1234 II 3 ........ IB2, IP8, T7, TP2 None .... 202 ...... 242 ...... 5 L 60 L E ............Methylamine, anhydrous ................................................................................................................. 2.1 UN1061 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Methylamine, aqueous solution ....................................................................................................... 3 UN1235 II 3, 8 .... B1, IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L E 135Methylamine dinitramine and dry salts thereof ............................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methylamine nitroform ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Methylamine perchlorate (dry) ........................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Methylamyl acetate ......................................................................................................................... 3 UN1233 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............N-Methylaniline ................................................................................................................................ 6.1 UN2294 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............alpha-Methylbenzyl alcohol, liquid .................................................................................................. 6.1 UN2937 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............alpha-Methylbenzyl alcohol, solid ................................................................................................... 6.1 UN3438 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

3-Methylbutan-2-one ....................................................................................................................... 3 UN2397 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............N-Methylbutylamine ......................................................................................................................... 3 UN2945 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40Methylchlorosilane ........................................................................................................................... 2.3 UN2534 ............ 2.3, 

2.1, 8.

2, B9, B14, N34 None .... 226 ...... 314, 

315.

Forbidden Forbidden D 17, 40

Methylcyclohexane .......................................................................................................................... 3 UN2296 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methylcyclohexanols, flammable ..................................................................................................... 3 UN2617 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methylcyclohexanone ...................................................................................................................... 3 UN2297 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methylcyclopentane ......................................................................................................................... 3 UN2298 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

D Methyldichloroarsine ........................................................................................................................ 6.1 NA1556 I 6.1 ..... 2, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 192 ...... None .... Forbidden Forbidden D 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76115

Methyldichlorosilane ........................................................................................................................ 4.3 UN1242 I 4.3, 8, 

3.

A2, A3, A7, B6, 

B77, N34, T10, 

TP2, TP7, TP13

None .... 201 ...... 243 ...... Forbidden 1 L D 21, 28, 

40, 49, 

100

Methylene chloride, see Dichloromethane ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Methylene glycol dinitrate ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............2-Methylfuran ................................................................................................................................... 3 UN2301 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............a-Methylglucoside tetranitrate ......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............a-Methylglycerol trinitrate ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............5-Methylhexan-2-one ....................................................................................................................... 3 UN2302 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methylhydrazine .............................................................................................................................. 6.1 UN1244 I 6.1, 3, 

8.

1, B7, B9, B14, 

B30, B72, B77, 

N34, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 21, 40, 

49, 100

4-Methylmorpholine or n-methylmorpholine .................................................................................... 3 UN2535 II 3, 8 .... B6, IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40Methylpentadienes .......................................................................................................................... 3 UN2461 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............2-Methylpentan-2-ol ......................................................................................................................... 3 UN2560 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Methylpentanes, see Hexanes ........................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Methylphenyldichlorosilane ............................................................................................................. 8 UN2437 II 8 ........ IB2, T7, TP2, 

TP13

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

1-Methylpiperidine ........................................................................................................................... 3 UN2399 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B ............Methyltetrahydrofuran ...................................................................................................................... 3 UN2536 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Methyltrichlorosilane ........................................................................................................................ 3 UN1250 I 3, 8 .... A7, B6, B77, 

N34, T11, TP2, 

TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L B 40

alpha-Methylvaleraldehyde .............................................................................................................. 3 UN2367 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Mine rescue equipment containing carbon dioxide, see Carbon dioxide ....................................... .................... ........... .......... .......... .......... .................... .................... ............Mines with bursting charge ............................................................................................................. 1.1F UN0136 II 1.1F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Mines with bursting charge ............................................................................................................. 1.1D UN0137 II 1.1D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Mines with bursting charge ............................................................................................................. 1.2D UN0138 II 1.2D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Mines with bursting charge ............................................................................................................. 1.2F UN0294 II 1.2F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Mixed acid, see Nitrating acid, mixtures etc ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Mobility aids, see Battery powered equipment or Battery powered vehicle’ .................................. .................... ........... .......... .......... .......... .................... .................... ............

D Model rocket motor ......................................................................................................................... 1.4C NA0276 II 1.4C .. 51 None .... 62 ........ None .... Forbidden 75 kg 06 ............D Model rocket motor ......................................................................................................................... 1.4S NA0323 II 1.4S ... 51 None .... 62 ........ None .... 25 kg 100 kg 05 ............

Molybdenum pentachloride ............................................................................................................. 8 UN2508 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg C 40

Monochloroacetone (unstabilized) .................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Monochloroethylene, see Vinyl chloride, stabilized ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Monoethanolamine, see Ethanolamine, solutions .......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Monoethylamine, see Ethylamine ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Morpholine ....................................................................................................................................... 8 UN2054 I 8, 3 .... A6, T10, TP2 None .... 201 ...... 243 ...... 0.5 L 2.5 L A ............Morpholine, aqueous, mixture, see Corrosive liquids, n.o.s. .......................................................... .................... ........... .......... .......... .......... .................... .................... ............Motor fuel anti-knock compounds see Motor fuel anti-knock mixtures .......................................... .................... ........... .......... .......... .......... .................... .................... ............

+ Motor fuel anti-knock mixtures ........................................................................................................ 6.1 UN1649 I 6.1, 3 14, 151, B9, 

B90, T14, TP2, 

TP13

None .... 201 ...... 244 ...... Forbidden 30 L D 25, 40

Motor spirit, see Gasoline ............................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Muriatic acid, see Hydrochloric acid ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Musk xylene, see 5-tert-Butyl-2,4,6-trinitro-m-xylene ..................................................................... .................... ........... .......... .......... .......... .................... .................... ............Naphtha see Petroleum distillates n.o.s. ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Naphthalene, crude or Naphthalene, refined .................................................................................. 4.1 UN1334 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Naphthalene diozonide .................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............beta-Naphthylamine ........................................................................................................................ 6.1 UN1650 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

beta-Naphthylamine, solid ............................................................................................................... 6.1 UN1650 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

beta-Naphthylamine solution ........................................................................................................... 6.1 UN3411 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB2, T7, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

alpha-Naphthylamine ....................................................................................................................... 6.1 UN2077 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Naphthalene, molten ....................................................................................................................... 4.1 UN2304 III 4.1 ..... IB1, T1, TP3 151 ...... 213 ...... 241 ...... Forbidden Forbidden C ............Naphthylamineperchlorate ............................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Naphthylthiourea ............................................................................................................................. 6.1 UN1651 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Naphthylurea ................................................................................................................................... 6.1 UN1652 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Natural gases (with high methane content), see Methane, etc. (UN 1971, UN 1972) .................. .................... ........... .......... .......... .......... .................... .................... ............Neohexane, see Hexanes ............................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Neon, compressed .......................................................................................................................... 2.2 UN1065 ............ 2.2 ..... 306 ...... 302 ...... 302 ...... 75 kg 150 kg A ............Neon, refrigerated liquid (cryogenic liquid) ..................................................................................... 2.2 UN1913 ............ 2.2 ..... T75, TP5 320 ...... 316 ...... None .... 50 kg 500 kg B ............New explosive or explosive device, see §§ 173.51 and 173.56 ..................................................... .................... ........... .......... .......... .......... .................... .................... ............Nickel carbonyl ................................................................................................................................ 6.1 UN1259 I 6.1, 3 1 None .... 198 ...... None .... Forbidden Forbidden D 18, 40

76116 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Nickel cyanide ................................................................................................................................. 6.1 UN1653 II 6.1 ..... IB8, IP2, IP4, 

N74, N75, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52

Nickel nitrate .................................................................................................................................... 5.1 UN2725 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Nickel nitrite ..................................................................................................................................... 5.1 UN2726 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Nickel picrate ................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nicotine ............................................................................................................................................ 6.1 UN1654 II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s. ..................................... 6.1 UN3144 I 6.1 ..... A4 None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L B 40

Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s. ....................................... 6.1 UN1655 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Nicotine hydrochloride liquid or solution ......................................................................................... 6.1 UN1656 II 6.1 ..... IB2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Nicotine hydrochloride, solid ........................................................................................................... 6.1 UN3444 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nicotine salicylate ............................................................................................................................ 6.1 UN1657 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nicotine sulfate solution .................................................................................................................. 6.1 UN1658 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Nicotine sulphate, solid ................................................................................................................... 6.1 UN3445 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nicotine tartrate ............................................................................................................................... 6.1 UN1659 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nitrated paper (unstable) ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Nitrates, inorganic, aqueous solution, n.o.s. ................................................................................... 5.1 UN3218 II 5.1 ..... 58, IB2, T4, TP1 152 ...... 202 ...... 242 ...... 1 L 5 L B 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... 58, IB2, T4, TP1 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 58, 

133

Nitrates, inorganic, n.o.s. ................................................................................................................ 5.1 UN1477 II 5.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 56, 58

.......................................................................................................................................................... .................... III 5.1 ..... IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Nitrates of diazonium compounds ................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitrating acid mixtures, spent with more than 50 percent nitric acid ............................................. 8 UN1826 I 8, 5.1 A7, T10, TP2, 

TP12, TP13

None .... 158 ...... 243 ...... Forbidden 2.5 L D 40, 66

Nitrating acid mixtures spent with not more than 50 percent nitric acid ........................................ 8 UN1826 II 8 ........ A7, B2, IB2, T8, 

TP2, TP12

None .... 158 ...... 242 ...... Forbidden 30 L D 40

Nitrating acid mixtures with more than 50 percent nitric acid ........................................................ 8 UN1796 I 8, 5.1 A7, T10, TP2, 

TP12, TP13

None .... 158 ...... 243 ...... Forbidden 2.5 L D 40, 66

Nitrating acid mixtures with not more than 50 percent nitric acid .................................................. 8 UN1796 II 8 ........ A7, B2, IB2, T8, 

TP2, TP12, TP13

None .... 158 ...... 242 ...... Forbidden 30 L D 40

Nitric acid other than red fuming, with more than 70 percent nitric acid ....................................... 8 UN2031 I 8, 5.1 A3, B47, B53, 

T10, TP2, TP12, 

TP13

None .... 158 ...... 243 ...... Forbidden 2.5 L D 44, 66, 

89, 90, 

110, 

111

Nitric acid other than red fuming, with not more than 70 percent nitric acid ................................. 8 UN2031 II 8 ........ A6, B2, B47, 

B53, IB2, T8, 

TP2, TP12

None .... 158 ...... 242 ...... Forbidden 30 L D 44, 66, 

89, 90, 

110, 

111

+ Nitric acid, red fuming ..................................................................................................................... 8 UN2032 I 8, 5.1, 

6.1.

2, B9, B32, B74, 

T20, TP2, TP12, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40, 66, 

74, 89, 

90

Nitric oxide, compressed ................................................................................................................. 2.3 UN1660 ............ 2.3, 

5.1, 8.

1, B37, B46, 

B50, B60, B77

None .... 337 ...... None .... Forbidden Forbidden D 40, 89, 

90

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76117

Nitric oxide and dinitrogen tetroxide mixtures or Nitric oxide and nitrogen dioxide mixtures ........ 2.3 UN1975 ............ 2.3, 

5.1, 8.

1, B7, B9, B14, 

B45, B46, B61, 

B66, B67, B77

None .... 337 ...... None .... Forbidden Forbidden D 40, 89, 

90

G Nitriles, flammable, toxic, n.o.s. ...................................................................................................... 3 UN3273 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L E 40, 52

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40, 52

G Nitriles, toxic, flammable, n.o.s. ...................................................................................................... 6.1 UN3275 I 6.1, 3 5, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40, 52

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40, 52

G Nitriles, toxic, liquid, n.o.s. .............................................................................................................. 6.1 UN3276 I 6.1 ..... 5, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 52

G Nitriles, toxic, solid, n.o.s. ............................................................................................................... 6.1 UN3439 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg D 52

G Nitriles, toxic, liquid, n.o.s. .............................................................................................................. 6.1 UN3276 II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 52

G Nitriles, toxic, solid, n.o.s. ............................................................................................................... 6.1 UN3439 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 52

G Nitriles, toxic, liquid, n.o.s. .............................................................................................................. 6.1 UN3276 III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 52

G Nitriles, toxic, solid, n.o.s. ............................................................................................................... 6.1 UN3439 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Nitrites, inorganic, aqueous solution, n.o.s. .................................................................................... 5.1 UN3219 II 5.1 ..... IB1, T4, TP1 152 ...... 202 ...... 242 ...... 1 L 5 L B 46, 56, 

58, 133

.......................................................................................................................................................... .................... III 5.1 ..... IB2, T4, TP1 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 46, 56, 

58, 133

Nitrites, inorganic, n.o.s. .................................................................................................................. 5.1 UN2627 II 5.1 ..... 33, IB8, IP4, T3, 

TP33

152 ...... 212 ...... None .... 5 kg 25 kg A 46, 56, 

58, 133

3-Nitro-4-chlorobenzotrifluoride ....................................................................................................... 6.1 UN2307 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 406-Nitro-4-diazotoluene-3-sulfonic acid (dry) .................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitro isobutane triol trinitrate ........................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............N-Nitro-N-methylglycolamide nitrate ............................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2-Nitro-2-methylpropanol nitrate ...................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitro urea ......................................................................................................................................... 1.1D UN0147 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............N-Nitroaniline ................................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............

+ Nitroanilines (o-; m-; p-;) ................................................................................................................. 6.1 UN1661 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nitroanisole, liquid ........................................................................................................................... 6.1 UN2730 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Nitroanisoles, solid .......................................................................................................................... 6.1 UN3458 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

+ Nitrobenzene ................................................................................................................................... 6.1 UN1662 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40

m-Nitrobenzene diazonium perchlorate .......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitrobenzenesulfonic acid ............................................................................................................... 8 UN2305 II 8 ........ B2, B4, IB8, IP2, 

IP4, T3, TP33

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Nitrobenzol, see Nitrobenzene ........................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............5-Nitrobenzotriazol .......................................................................................................................... 1.1D UN0385 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Nitrobenzotrifluorides, liquid ............................................................................................................ 6.1 UN2306 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40Nitrobenzotrifluorides, solid ............................................................................................................. 6.1 UN3431 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

Nitrobromobenzenes, liquid ............................................................................................................. 6.1 UN2732 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Nitrobromobenzenes, solid .............................................................................................................. 6.1 UN3459 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Nitrocellulose, dry or wetted with less than 25 percent water (or alcohol), by mass ..................... 1.1D UN0340 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 13 27E Nitrocellulose membrane filters, with not more than 12.6% nitrogen, by dry mass ....................... 4.1 UN3270 II 4.1 ..... 43, A1 151 ...... 212 ...... 240 ...... 1 kg 15 kg D ............Nitrocellulose, plasticized with not less than 18 percent plasticizing substance, by mass ............ 1.3C UN0343 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass, and not 

more than 55 percent nitrocellulose.

3 UN2059 I 3 ........ T11, TP1, TP8, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T4, TP1, 

TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Nitrocellulose, unmodified or plasticized with less than 18 percent plasticizing substance, by 

mass.

1.1D UN0341 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 13 27E 

Nitrocellulose, wetted with not less than 25 percent alcohol, by mass .......................................... 1.3C UN0342 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Nitrocellulose with alcohol with not less than 25 percent alcohol by mass, and with not more 

than 12.6 percent nitrogen, by dry mass.

4.1 UN2556 II 4.1 ..... 151 ...... 212 ...... None .... 1 kg 15 kg D 28

Nitrocellulose, with not more than 12.6 percent nitrogen, by dry mass, or Nitrocellulose mixture 

with pigment or Nitrocellulose mixture with plasticizer or Nitrocellulose mixture with pigment 

and plasticizer.

4.1 UN2557 II 4.1 ..... 44 151 ...... 212 ...... None .... 1 kg 15 kg D 28

Nitrocellulose with water with not less than 25 percent water, by mass ........................................ 4.1 UN2555 II 4.1 ..... 151 ...... 212 ...... None .... 15 kg 50 kg E 28Nitrochlorobenzene, see Chloronitrobenzenes etc ......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Nitrocresols, solid ............................................................................................................................ 6.1 UN2446 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Nitrocresols, liquid ........................................................................................................................... 6.1 UN3434 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Nitroethane ...................................................................................................................................... 3 UN2842 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

76118 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Nitroethyl nitrate .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Nitroethylene polymer ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitrogen, compressed ..................................................................................................................... 2.2 UN1066 ............ 2.2 ..... 306 ...... 302 ...... 314, 

315.

75 kg 150 kg A ............

Nitrogen dioxide, see Dinitrogen tetroxide ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Nitrogen fertilizer solution, see Fertilizer ammoniating solution etc ............................................... .................... ........... .......... .......... .......... .................... .................... ............Nitrogen, mixtures with rare gases, see Rare gases and nitrogen mixtures ................................. .................... ........... .......... .......... .......... .................... .................... ............Nitrogen peroxide, see Dinitrogen tetroxide ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Nitrogen, refrigerated liquid cryogenic liquid ................................................................................... 2.2 UN1977 ............ 2.2 ..... T75, TP5 320 ...... 316 ...... 318 ...... 50 kg 500 kg D ............Nitrogen tetroxide and nitric oxide mixtures, see Nitric oxide and nitrogen tetroxide mixtures ..... .................... ........... .......... .......... .......... .................... .................... ............Nitrogen tetroxide, see Dinitrogen tetroxide ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Nitrogen trichloride .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitrogen trifluoride ........................................................................................................................... 2.2 UN2451 ............ 2.2, 

5.1.

None .... 302 ...... None .... 75 kg 150 kg D 40

Nitrogen triiodide ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Nitrogen triiodide monoamine ......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitrogen trioxide .............................................................................................................................. 2.3 UN2421 ............ 2.3, 

5.1, 8.

1 None .... 336 ...... 245 ...... Forbidden Forbidden D 40, 89, 

90

Nitroglycerin, desensitized with not less than 40 percent non-volatile water insoluble 

phlegmatizer, by mass.

1.1D UN0143 II 1.1D, 

6.1.

125 None .... 62 ........ None .... Forbidden Forbidden 13 21E 

Nitroglycerin, liquid, not desensitized .............................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Nitroglycerin mixture, desensitized, liquid, flammable, n.o.s. with not more than 30 percent nitroglycerin, by mass. 3 UN3343 ............ 3 ........ 129 None .... 214 ...... None .... Forbidden Forbidden D ............Nitroglycerin mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin, by mass 3 UN3357 II 3 ........ 142 None .... 202 ...... 243 ...... 5 L 60 L E ............Nitroglycerin mixture, desensitized, solid, n.o.s. with more than 2 percent but not more than 10 

percent nitroglycerin, by mass.

4.1 UN3319 II 4.1 ..... 118 None .... None .... None .... Forbidden 0.5 kg E ............

Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 5 percent nitroglycerin. 3 UN3064 II 3 ........ N8 None .... 202 ...... None .... Forbidden 5 L E ............Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 10 percent 

nitrogylcerin.

1.1D UN0144 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 21E 

Nitroglycerin solution in alcohol with not more than 1 percent nitroglycerin .................................. 3 UN1204 II 3 ........ IB2, N34 150 ...... 202 ...... None .... 5 L 60 L B ............Nitroguanidine nitrate ...................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitroguanidine or Picrite, dry or wetted with less than 20 percent water, by mass ....................... 1.1D UN0282 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Nitroguanidine, wetted or Picrite, wetted with not less than 20 percent water, by mass .............. 4.1 UN1336 I 4.1 ..... 23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg E 28

1-Nitrohydantoin .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Nitrohydrochloric acid ...................................................................................................................... 8 UN1798 I 8 ........ A3, B10, N41, 

T10, TP2, TP12, 

TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L D 40, 66, 

74, 89, 

90

Nitromannite (dry) ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Nitromannite, wetted, see Mannitol hexanitrate, etc ....................................................................... .................... ........... .......... .......... .......... .................... .................... ............Nitromethane ................................................................................................................................... 3 UN1261 II 3 ........ 150 ...... 202 ...... None .... Forbidden 60 L A ............Nitromuriatic acid, see Nitrohydrochloric acid ................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Nitronaphthalene ............................................................................................................................. 4.1 UN2538 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

4-Nitrophenylhydrazine, with not less than 30% water, by mass ................................................... 4.1 UN3376 I 4.1 ..... 164, A8, A19, 

A20, N41

None .... 211 ...... None .... Forbidden 15 kg E 36

+ Nitrophenols (o-; m-; p-;) ................................................................................................................. 6.1 UN1663 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

m-Nitrophenyldinitro methane ......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Nitropropanes .................................................................................................................................. 3 UN2608 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............p-Nitrosodimethylaniline .................................................................................................................. 4.2 UN1369 II 4.2 ..... A19, A20, IB6, 

IP2, N34, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg D 34

Nitrostarch, dry or wetted with less than 20 percent water, by mass ............................................ 1.1D UN0146 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Nitrostarch, wetted with not less than 20 percent water, by mass ................................................. 4.1 UN1337 I 4.1 ..... 23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg D 28

Nitrosugars (dry) .............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Nitrosyl chloride ............................................................................................................................... 2.3 UN1069 ............ 2.3, 8 3, B14 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Nitrosylsulfuric acid, liquid ............................................................................................................... 8 UN2308 II 8 ........ A3, A6, A7, B2, 

IB2, N34, T8, 

TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L D 40, 66, 

74, 89, 

90

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76119

Nitrosylsulphuric acid, solid ............................................................................................................. 8 UN3456 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg D 40, 66, 

74, 89, 

90

Nitrotoluenes, liquid ......................................................................................................................... 6.1 UN1664 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Nitrotoluenes, solid .......................................................................................................................... 6.1 UN3446 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nitrotoluidines (mono) ..................................................................................................................... 6.1 UN2660 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Nitrotriazolone or NTO .................................................................................................................... 1.1D UN0490 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Nitrous oxide and carbon dioxide mixtures, see Carbon dioxide and nitrous oxide mixtures ....... .................... ........... .......... .......... .......... .................... .................... ............Nitrous oxide ................................................................................................................................... 2.2 UN1070 ............ 2.2, 

5.1.

A14 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A 40

Nitrous oxide, refrigerated liquid ..................................................................................................... 2.2 UN2201 ............ 2.2, 

5.1.

B6, T75, TP5, 

TP22

None .... 304 ...... 314, 

315.

Forbidden Forbidden B 40

Nitroxylenes, liquid .......................................................................................................................... 6.1 UN1665 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Nitroxylenes, solid ........................................................................................................................... 6.1 UN3447 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Nitroxylol, see Nitroxylenes ............................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Nonanes .......................................................................................................................................... 3 UN1920 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Non-flammable gas, n.o.s., see Compressed gas, etc. or Liquefied gas, etc ............................... .................... ........... .......... .......... .......... .................... .................... ............Nonliquefied gases, see Compressed gases, etc .......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Nonliquefied hydrocarbon gas, see Hydrocarbon gas mixture, compressed, n.o.s. ...................... .................... ........... .......... .......... .......... .................... .................... ............Nonyltrichlorosilane ......................................................................................................................... 8 UN1799 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Nordhausen acid, see Sulfuric acid, fuming etc ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............2,5-Norbornadiene, stabilized, see Bicyclo 2,2,1 hepta-2,5-diene, stabilized ................................ .................... ........... .......... .......... .......... .................... .................... ............Octadecyltrichlorosilane .................................................................................................................. 8 UN1800 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Octadiene ........................................................................................................................................ 3 UN2309 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acid ........................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Octafluorobut-2-ene or Refrigerant gas R 1318 ............................................................................. 2.2 UN2422 ............ 2.2 ..... None .... 304 ...... 314, 

315.

75 kg 150 kg A ............

Octafluorocyclobutane, or Refrigerant gas RC 318 ........................................................................ 2.2 UN1976 ............ 2.2 ..... T50 None .... 304 ...... 314, 

315.

75 kg 150 kg A ............

Octafluoropropaneor Refrigerant gas R 218 ................................................................................... 2.2 UN2424 ............ 2.2 ..... T50 None .... 304 ...... 314, 

315.

75 kg 150 kg A ............

Octanes ........................................................................................................................................... 3 UN1262 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Octogen, etc. see Cyclotetramethylene tetranitramine, etc. ........................................................... .................... ........... .......... .......... .......... .................... .................... ............Octolite or Octol, dry or wetted with less than 15 percent water, by mass ................................... 1.1D UN0266 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Octonal ............................................................................................................................................ 1.1D UN0496 ............ 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Octyl aldehydes ............................................................................................................................... 3 UN1191 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Octyltrichlorosilane .......................................................................................................................... 8 UN1801 II 8 ........ A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Oil gas, compressed ....................................................................................................................... 2.3 UN1071 ............ 2.3, 

2.1.

6 None .... 304 ...... 314, 

315.

Forbidden 25 kg D 40

Oleum, see Sulfuric acid, fuming .................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Organic peroxide type A, liquid or solid .......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............

G Organic peroxide type B, liquid ....................................................................................................... 5.2 UN3101 II 5.2, 1 53 152 ...... 225 ...... None .... Forbidden Forbidden D 12, 40, 

52, 53

G Organic peroxide type B, liquid, temperature controlled ................................................................ 5.2 UN3111 II 5.2, 1 53 None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type B, solid ........................................................................................................ 5.2 UN3102 II 5.2, 1 53 152 ...... 225 ...... None .... Forbidden Forbidden D 12, 40, 

52, 53

G Organic peroxide type B, solid, temperature controlled ................................................................. 5.2 UN3112 II 5.2, 1 53 None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type C, liquid ....................................................................................................... 5.2 UN3103 II 5.2 ..... 152 ...... 225 ...... None .... 5 L 10 L D 12, 40, 

52, 53

G Organic peroxide type C, liquid, temperature controlled ................................................................ 5.2 UN3113 II 5.2 ..... None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type C, solid ........................................................................................................ 5.2 UN3104 II 5.2 ..... 152 ...... 225 ...... None .... 5 kg 10 kg D 12, 40, 

52, 53

G Organic peroxide type C, solid, temperature controlled ................................................................. 5.2 UN3114 II 5.2 ..... None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type D, liquid ....................................................................................................... 5.2 UN3105 II 5.2 ..... 152 ...... 225 ...... None .... 5 L 10 L D 12, 40, 

52, 53

G Organic peroxide type D, liquid, temperature controlled ................................................................ 5.2 UN3115 II 5.2 ..... None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type D, solid ........................................................................................................ 5.2 UN3106 II 5.2 ..... 152 ...... 225 ...... None .... 5 kg 10 kg D 12, 40, 

52, 53

G Organic peroxide type D, solid, temperature controlled ................................................................. 5.2 UN3116 II 5.2 ..... None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type E, liquid ....................................................................................................... 5.2 UN3107 II 5.2 ..... 152 ...... 225 ...... None .... 10 L 25 L D 12, 40, 

52, 53

76120 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

G Organic peroxide type E, liquid, temperature controlled ................................................................ 5.2 UN3117 II 5.2 ..... None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type E, solid ........................................................................................................ 5.2 UN3108 II 5.2 ..... 152 ...... 225 ...... None .... 10 kg 25 kg D 12, 40, 

52, 53

G Organic peroxide type E, solid, temperature controlled ................................................................. 5.2 UN3118 II 5.2 ..... None .... 225 ...... None .... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type F, liquid ....................................................................................................... 5.2 UN3109 II 5.2 ..... IP5 152 ...... 225 ...... 225 ...... 10 L 25 L D 12, 40, 

52, 53

G Organic peroxide type F, liquid, temperature controlled ................................................................. 5.2 UN3119 II 5.2 ..... IP5 None .... 225 ...... 225 ...... Forbidden Forbidden D 2, 40, 

52, 53

G Organic peroxide type F, solid ........................................................................................................ 5.2 UN3110 II 5.2 ..... TP33 152 ...... 225 ...... 225 ...... 10 kg 25 kg D 12, 40, 

52, 53

G Organic peroxide type F, solid, temperature controlled .................................................................. 5.2 UN3120 II 5.2 ..... TP33 None .... 225 ...... 225 ...... Forbidden Forbidden D 2, 52, 

53

D Organic phosphate, mixed with compressed gas or Organic phosphate compound, mixed with 

compressed gas or Organic phosphorus compound, mixed with compressed gas.

2.3 NA1955 ............ 2.3 ..... 3 None .... 334 ...... None .... Forbidden Forbidden D 40

Organic pigments, self-heating ....................................................................................................... 4.2 UN3313 II 4.2 ..... IB8, IP2, IP4, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg C ............

G Organoarsenic compound, liquid, n.o.s. ......................................................................................... 6.1 UN3280 I 6.1 ..... 5, T14, TP2, 

TP13, TP27

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

G Organoarsenic compound, solid, n.o.s. .......................................................................................... 6.1 UN3465 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C ............... 3 UN2762 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Organochlorine pesticides, liquid, toxic ........................................................................................... 6.1 UN2996 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C ........ 6.1 UN2995 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Organochlorine pesticides, solid, toxic ............................................................................................ 6.1 UN2761 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

G Organometallic compound, toxic, liquid, n.o.s. ............................................................................... 6.1 UN3282 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

G Organometallic compound, toxic, solid, n.o.s. ................................................................................ 6.1 UN3467 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76121

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

G Organometallic substance, liquid, pyrophoric ................................................................................. 4.2 UN3392 I 4.2 ..... B11, T21, TP2, 

TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D 143

G Organometallic substance, liquid, pyrophoric, water-reactive ........................................................ 4.2 UN3394 I 4.2, 

4.3.

B11, T21, TP2, 

TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D ............

G Organometallic substance, liquid, water-reactive ........................................................................... 4.3 UN3398 I 4.3 ..... T13, TP2, TP7 None .... 201 ...... 244 ...... Forbidden Forbidden E 40, 52

.......................................................................................................................................................... .................... II 4.3 ..... IB1, T7, TP2, 

TP7

None .... 202 ...... 243 ...... 1 L 5 L E 40, 52

.......................................................................................................................................................... .................... III 4.3 ..... IB2, T7, TP2, 

TP7

None .... 203 ...... 242 ...... 5 L 60 L E 40, 52

G Organometallic substance, liquid, water-reactive, flammable ......................................................... 4.3 UN3399 I 4.3, 3 T13, TP2, TP7 None .... 201 ...... 244 ...... Forbidden Fobidden E 40, 52

.......................................................................................................................................................... .................... II 4.3, 3 IB1, T7, TP2, 

TP7

None .... 202 ...... 243 ...... Forbidden Forbidden E 40, 52

.......................................................................................................................................................... .................... III 4.3, 3 IB2, T7, TP2, 

TP7

None .... 203 ...... 242 ...... Forbidden Forbidden E 40, 52

G Organometallic substance, solid, pyrophoric .................................................................................. 4.2 UN3391 I 4.2 ..... T21, TP7, TP33 None .... 181 ...... 244 ...... Forbidden Forbidden D ............G Organometallic substance, solid, pyrophoric, water-reactive ......................................................... 4.2 UN3393 I 4.2, 

4.3.

B11, T21, TP7, 

TP33

None .... 181 ...... 244 ...... Forbidden Forbidden D 52

G Organometallic substance, solid, self-heating ................................................................................ 4.2 UN3400 II 4.2 ..... IB6, T3, TP33 None .... 212 ...... 242 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, T1, TP33 None .... 203 ...... 242 ...... 25 kg 100 kg C ............

G Organometallic substance, solid, water-reactive ............................................................................ 4.3 UN3395 I 4.3 ..... N40, T9, TP7, 

TP33

None .... 211 ...... 242 ...... Forbidden Forbidden E 40, 52

.......................................................................................................................................................... .................... II 4.3 ..... IB4, T3, TP33 151 ...... 212 ...... 242 ...... 15 kg 50 kg E 40, 52.......................................................................................................................................................... .................... III 4.3 ..... IB6, T1, TP33 151 ...... 213 ...... 241 ...... 25 kg 100 kg E 40, 52

G Organometallic substance, solid, water-reactive, flammable .......................................................... 4.3 UN3396 I 4.3, 

4.1.

N40, T9, TP7, 

TP33

None .... 211 ...... 242 ...... Forbidden Forbidden E 40, 52

.......................................................................................................................................................... .................... II 4.3, 

4.1.

IB4, T3, TP33 151 ...... 212 ...... 242 ...... 15 kg 50 kg E 40, 52

.......................................................................................................................................................... .................... III 4.3, 

4.1.

IB6, T1, TP33 151 ...... 213 ...... 241 ...... 25 kg 100 kg E 40, 52

G Organometallic substance, solid, water-reactive, self-heating ........................................................ 4.3 UN3397 I 4.3, 

4.2.

N40, T9, TP7, 

TP33

None .... 211 ...... 242 ...... Forbidden Forbidden E 40, 52

.......................................................................................................................................................... .................... II 4.3, 

4.2.

IB4, T3, TP33 None .... 212 ...... 242 ...... 15 kg 50 kg E 40, 52

.......................................................................................................................................................... .................... III 4.3, 

4.2.

IB6, T1, TP33 None .... 213 ...... 241 ...... 25 kg 100 kg E 40, 52

Organophosphorus compound, toxic, flammable, n.o.s. ................................................................ 6.1 UN3279 I 6.1, 3 5, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

G Organophosphorus compound, toxic, liquid, n.o.s. ......................................................................... 6.1 UN3278 I 6.1 ..... 5, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

G Organophosphorus compound, toxic, solid, n.o.s. .......................................................................... 6.1 UN3464 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ........ 3 UN2784 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Organophosphorus pesticides, liquid, toxic .................................................................................... 6.1 UN3018 I 6.1 ..... N76, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, N76, T11, 

TP2, TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, N76, T7, 

TP2, TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Organophosphorus pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C .. 6.1 UN3017 I 6.1, 3 N76, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, N76, T11, 

TP2, TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, N76, T7, 

TP2, TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Organophosphorus pesticides, solid, toxic ..................................................................................... 6.1 UN2783 I 6.1 ..... IB7, IP1, N77, 

T6, TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, 

N77, T3, TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, N77, 

T1, TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

76122 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Organotin compounds, liquid, n.o.s. ............................................................................................... 6.1 UN2788 I 6.1 ..... A3, N33, N34, 

T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... A3, IB2, N33, 

N34, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Organotin compounds, solid, n.o.s. ................................................................................................ 6.1 UN3146 I 6.1 ..... A5, IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ....................... 3 UN2787 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Organotin pesticides, liquid, toxic ................................................................................................... 6.1 UN3020 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Organotin pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C ................. 6.1 UN3019 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Organotin pesticides, solid, toxic .................................................................................................... 6.1 UN2786 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Orthonitroaniline, see Nitroanilines etc ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Osmium tetroxide ............................................................................................................................ 6.1 UN2471 I 6.1 ..... A8, IB7, IP1, 

N33, N34, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B 40

D G Other regulated substances, liquid, n.o.s. ...................................................................................... 9 NA3082 III 9 ........ IB3, T2, TP1 155 ...... 203 ...... 241 ...... No limit No limit A ............D G Other regulated substances, solid, n.o.s. ....................................................................................... 9 NA3077 III 9 ........ B54, IB8, IP2, 

T1, TP33

155 ...... 213 ...... 240 ...... No limit No limit A ............

G Oxidizing liquid, corrosive, n.o.s. .................................................................................................... 5.1 UN3098 I 5.1, 8 A6 None .... 201 ...... 244 ...... Forbidden 2.5 L D 13, 56, 

58, 

106, 

138

.......................................................................................................................................................... .................... II 5.1, 8 IB1 None .... 202 ...... 243 ...... 1 L 5 L B 34, 56, 

58, 

106, 

138

.......................................................................................................................................................... .................... III 5.1, 8 IB2 152 ...... 203 ...... 242 ...... 2.5 L 30 L B 34, 56, 

58, 

106, 

138

G Oxidizing liquid, n.o.s. ..................................................................................................................... 5.1 UN3139 I 5.1 ..... 127, A2, A6 None .... 201 ...... 243 ...... Forbidden 2.5 L D 56, 58, 

106, 

138

.......................................................................................................................................................... .................... II 5.1 ..... 127, A2, IB2 152 ...... 202 ...... 242 ...... 1 L 5 L B 56, 58, 

106, 

138

.......................................................................................................................................................... .................... III 5.1 ..... 127, A2, IB2 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 58, 

106, 

138

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76123

G Oxidizing liquid, toxic, n.o.s. ............................................................................................................ 5.1 UN3099 I 5.1, 

6.1.

A6 None .... 201 ...... 244 ...... Forbidden 2.5 L D 56, 58, 

106, 

138

.......................................................................................................................................................... .................... II 5.1, 

6.1.

IB1 152 ...... 202 ...... 243 ...... 1 L 5 L B 56, 58, 

95, 

106, 

138

.......................................................................................................................................................... .................... III 5.1, 

6.1.

IB2 152 ...... 203 ...... 242 ...... 2.5 L 30 L B 56, 58, 

95, 

106, 

138

G Oxidizing solid, corrosive, n.o.s. ..................................................................................................... 5.1 UN3085 I 5.1, 8 None .... 211 ...... 242 ...... 1 kg 15 kg D 13, 56, 

58, 

106, 

138

.......................................................................................................................................................... .................... II 5.1, 8 IB6, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 5 kg 25 kg B 13, 34, 

56, 58, 

106, 

138

.......................................................................................................................................................... .................... III 5.1, 8 IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg B 13, 34, 

56, 58, 

106, 

138

G Oxidizing solid, flammable, n.o.s. ................................................................................................... 5.1 UN3137 I 5.1, 

4.1.

None .... 214 ...... 214 ...... Forbidden Forbidden ............

G Oxidizing solid, n.o.s. ...................................................................................................................... 5.1 UN1479 I 5.1 ..... IB5, IP1 None .... 211 ...... 242 ...... 1 kg 15 kg D 56, 58, 

106, 

138

.......................................................................................................................................................... .................... II 5.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg B 56, 58, 

106, 

138

.......................................................................................................................................................... .................... III 5.1 ..... IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg B 56, 58, 

106, 

138

G Oxidizing solid, self-heating, n.o.s. ................................................................................................. 5.1 UN3100 I 5.1, 

4.2.

None .... 214 ...... 214 ...... Forbidden Forbidden ............

.......................................................................................................................................................... .................... II 5.1, 

4.2.

None .... 214 ...... 214 ...... Forbidden Forbidden ............

G Oxidizing solid, toxic, n.o.s. ............................................................................................................. 5.1 UN3087 I 5.1, 

6.1.

None .... 211 ...... 242 ...... 1 kg 15 kg D 56, 58, 

106, 

138

.......................................................................................................................................................... .................... II 5.1, 

6.1.

IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg B 56, 58, 

95, 

106, 

138

.......................................................................................................................................................... .................... III 5.1, 

6.1.

IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg B 56, 58, 

95, 

106, 

138

G Oxidizing solid, water-reactive, n.o.s. ............................................................................................. 5.1 UN3121 ............ 5.1, 

4.3.

None .... 214 ...... 214 ...... Forbidden Forbidden ............

Oxygen and carbon dioxide mixtures, see Carbon dioxide and oxygen mixtures ......................... .................... ........... .......... .......... .......... .................... .................... ............Oxygen, compressed ...................................................................................................................... 2.2 UN1072 ............ 2.2, 

5.1.

A14, A52 306 ...... 302 ...... 314, 

315.

75 kg 150 kg A ............

Oxygen difluoride, compressed ....................................................................................................... 2.3 UN2190 ............ 2.3, 

5.1, 8.

1 None .... 304 ...... None .... Forbidden Forbidden D 13, 40, 

89, 90

Oxygen generator, chemical (including when contained in associated equipment, e.g., passenger service units (PSUs), portable breathing equipment (PBE), etc).. 5.1 UN3356 II 5.1 ..... 60, A51 None .... 212 ...... None .... Forbidden 25 kg gross D 56, 58, 69, 106

+ Oxygen generator, chemical, spent ................................................................................................ 9 NA3356 III 9 ........ 61 None .... 213 ...... None .... Forbidden Forbidden A ............

Oxygen, mixtures with rare gases, see Rare gases and oxygen mixtures .................................... .................... ........... .......... .......... .......... .................... .................... ............Oxygen, refrigerated liquid (cryogenic liquid) ................................................................................. 2.2 UN1073 ............ 2.2, 

5.1.

T75, TP5, TP22 320 ...... 316 ...... 318 ...... Forbidden Forbidden D ............

Paint including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and 

liquid lacquer base.

3 UN1263 I 3 ........ T11, TP1, TP8 150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 149, B52, IB2, 

T4, TP1, TP8

150 ...... 173 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T2, 

TP1

150 ...... 173 ...... 242 ...... 60 L 220 L A ............

Paint or Paint related material ........................................................................................................ 8 UN3066 II 8 ........ B2, IB2, T7, TP2 154 ...... 173 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ B52, IB3, T4, 

TP1

154 ...... 173 ...... 241 ...... 5 L 60 L A ............

Paint related material including paint thinning, drying, removing, or reducing compound ............. 3 UN1263 I 3 ........ T11, TP1, TP8 150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 149, B52, IB2, 

T4, TP1, TP8

150 ...... 173 ...... 242 ...... 5 L 60 L B ............

76124 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T2, 

TP1

150 ...... 173 ...... 242 ...... 60 L 220 L A ............

Paper, unsaturated oil treated incompletely dried (including carbon paper) .................................. 4.2 UN1379 III 4.2 ..... IB8, IP3 None .... 213 ...... 241 ...... Forbidden Forbidden A ............Paraformaldehyde ........................................................................................................................... 4.1 UN2213 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Paraldehyde .................................................................................................................................... 3 UN1264 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Paranitroaniline, solid, see Nitroanilines etc ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

D Parathion and compressed gas mixture ......................................................................................... 2.3 NA1967 ............ 2.3 ..... 3 None .... 334 ...... 245 ...... Forbidden Forbidden E 40

Paris green, solid, see Copper acetoarsenite ................................................................................. .................... ........... .......... .......... .......... .................... .................... ............

A W PCB, see Polychlorinated biphenyls ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

+ Pentaborane .................................................................................................................................... 4.2 UN1380 I 4.2, 

6.1.

1 None .... 205 ...... 245 ...... Forbidden Forbidden D ............

Pentachloroethane .......................................................................................................................... 6.1 UN1669 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40Pentachlorophenol ........................................................................................................................... 6.1 UN3155 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Pentaerythrite tetranitrate (dry) ....................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Pentaerythrite tetranitrate mixture, desensitized, solid, n.o.s. with more than 10 percent but not 

more than 20 percent PETN, by mass.

4.1 UN3344 II 4.1 ..... 118, N85 None .... 214 ...... None .... Forbidden Forbidden E ............

Pentaerythrite tetranitrate or Pentaerythritol tetranitrate or PETN, with not less than 7 percent 

wax by mass.

1.1D UN0411 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

Pentaerythrite tetranitrate, wetted or Pentaerythritol tetranitrate, wetted, or PETN, wetted with 

not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pentaerythritol 

tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass.

1.1D UN0150 II 1.1D .. 121 None .... 62 ........ None .... Forbidden Forbidden 10 ............

Pentaerythritol tetranitrate, see Pentaerythrite tetranitrate, etc ...................................................... .................... ........... .......... .......... .......... .................... .................... ............Pentafluoroethane or Refrigerant gas R 125 .................................................................................. 2.2 UN3220 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Pentamethylheptane ........................................................................................................................ 3 UN2286 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Pentane-2,4-dione ........................................................................................................................... 3 UN2310 III 3, 6.1 B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Pentanes ......................................................................................................................................... 3 UN1265 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ IB2, IP8, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............

Pentanitroaniline (dry) ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Pentanols ......................................................................................................................................... 3 UN1105 II 3 ........ IB2, T4, TP1, 

TP29

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B3, IB3, T2, 

TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

1-Pentene (n-amylene) .................................................................................................................... 3 UN1108 I 3 ........ T11, TP2 150 ...... 201 ...... 243 ...... 1 L 30 L E ............1-Pentol ........................................................................................................................................... 8 UN2705 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L B 26, 27Pentolite, dry or wetted with less than 15 percent water, by mass ................................................ 1.1D UN0151 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Pepper spray, see Aerosols, etc. or Self-defense spray, non-pressurized .................................... .................... ........... .......... .......... .......... .................... .................... ............Perchlorates, inorganic, aqueous solution, n.o.s. ........................................................................... 5.1 UN3211 II 5.1 ..... IB2, T4, TP1 152 ...... 202 ...... 242 ...... 1 L 5 L B 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... IB2, T4, TP1 152 ...... 202 ...... 241 ...... 2.5 L 30 L B 56, 58, 

69, 133

Perchlorates, inorganic, n.o.s. ......................................................................................................... 5.1 UN1481 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

.......................................................................................................................................................... .................... III 5.1 ..... IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Perchloric acid, with more than 72 percent acid by mass .............................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Perchloric acid with more than 50 percent but not more than 72 percent acid, by mass ............. 5.1 UN1873 I 5.1, 8 A2, A3, N41, 

T10, TP1, TP12

None .... 201 ...... 243 ...... Forbidden 2.5 L D 66

Perchloric acid with not more than 50 percent acid by mass ........................................................ 8 UN1802 II 8, 5.1 IB2, N41, T7, 

TP2

None .... 202 ...... 243 ...... Forbidden 30 L C 66

Perchloroethylene, see Tetrachloroethylene ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Perchloromethyl mercaptan ............................................................................................................ 6.1 UN1670 I 6.1 ..... 2, B9, B14, B32, 

B74, N34, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Perchloryl fluoride ............................................................................................................................ 2.3 UN3083 ............ 2.3, 

5.1.

2, B9, B14 None .... 302 ...... 314, 

315.

Forbidden Forbidden D 40

Percussion caps, see Primers, cap type ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Perfluoro-2-butene, see Octafluorobut-2-ene ................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Perfluoro(ethyl vinyl ether) .............................................................................................................. 2.1 UN3154 ............ 2.1 ..... 306 ...... 302, 

304, 305.

314, 

315.

Forbidden 150 kg E 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76125

Perfluoro(methyl vinyl ether) ........................................................................................................... 2.1 UN3153 ............ 2.1 ..... T50 306 ...... 302, 

304, 305.

314, 

315.

Forbidden 150 kg E 40

Perfumery products with flammable solvents ................................................................................. 3 UN1266 II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 15 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Permanganates, inorganic, aqueous solution, n.o.s. ...................................................................... 5.1 UN3214 II 5.1 ..... 26, IB2, T4, TP1 152 ...... 202 ...... 242 ...... 1 L 5 L D 56, 58, 

133, 

138

Permanganates, inorganic, n.o.s. ................................................................................................... 5.1 UN1482 II 5.1 ..... 26, A30, IB6, 

IP2, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg D 56, 58, 

138

.......................................................................................................................................................... .................... III 5.1 ..... 26, A30, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg D 56, 58, 

138

Peroxides, inorganic, n.o.s. ............................................................................................................. 5.1 UN1483 II 5.1 ..... A7, A20, IB6, 

IP2, N34, T3, 

TP33

None .... 212 ...... 242 ...... 5 kg 25 kg A 13, 52, 

66, 75

.......................................................................................................................................................... .................... III 5.1 ..... A7, A20, IB8, 

IP3, N34, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 13, 52, 

66, 75

Peroxyacetic acid, with more than 43 percent and with more than 6 percent hydrogen peroxide Forbidden ........... .......... .......... .......... .................... .................... ............Persulfates, inorganic, aqueous solution, n.o.s. ............................................................................. 5.1 UN3216 III 5.1 ..... IB2, T4, TP1, 

TP29

152 ...... 203 ...... 241 ...... 2.5 L 30 L A 56, 133

Persulfates, inorganic, n.o.s. ........................................................................................................... 5.1 UN3215 III 5.1 ..... IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

G Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C ....................................... 3 UN3021 I 3, 6.1 B5, T14, TP2, 

TP13, TP27

None .... 201 ...... 243 ...... Forbidden 30 L B ............

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B ............

G Pesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C ....................... 6.1 UN2903 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2 153 ...... 203 ...... 242 ...... 60 L 220 L A 40

G Pesticides, liquid, toxic, n.o.s. ......................................................................................................... 6.1 UN2902 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

G Pesticides, solid, toxic, n.o.s. .......................................................................................................... 6.1 UN2588 I 6.1 ..... IB7, T6, TP33 None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

PETN, see Pentaerythrite tetranitrate ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............PETN/TNT, see Pentolite, etc ......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Petrol, see Gasoline ........................................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Petroleum crude oil ......................................................................................................................... 3 UN1267 I 3 ........ 144, T11, TP1, 

TP8

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 144, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ 144, B1, IB3, T2, 

TP1

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Petroleum distillates, n.o.s. or Petroleum products, n.o.s. ............................................................. 3 UN1268 I 3 ........ 144, T11, TP1, 

TP8

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 144, IB2, T7, 

TP1, TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ 144, B1, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Petroleum gases, liquefied or Liquefied petroleum gas ................................................................. 2.1 UN1075 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

D Petroleum oil ................................................................................................................................... 3 NA1270 I 3 ........ 144, T11, TP1 None .... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 144, IB2, T7, 

TP1, TP8, TP28

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ 144, B1, IB3, T4, 

TP1, TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Phenacyl bromide ............................................................................................................................ 6.1 UN2645 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B 40

+ Phenetidines .................................................................................................................................... 6.1 UN2311 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Phenol, molten ................................................................................................................................ 6.1 UN2312 II 6.1 ..... B14, T7, TP3 None .... 202 ...... 243 ...... Forbidden Forbidden B 40

+ Phenol, solid .................................................................................................................................... 6.1 UN1671 II 6.1 ..... IB8, IP2, IP4, 

N78, T3, TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Phenol solutions .............................................................................................................................. 6.1 UN2821 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

76126 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Phenolsulfonic acid, liquid ............................................................................................................... 8 UN1803 II 8 ........ B2, IB2, N41, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L C 14

Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic flash point less than 23 degrees C. 3 UN3346 I 3, 6.1 T14, TP2, TP13, TP27 None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Phenoxyacetic acid derivative pesticide, liquid, toxic ..................................................................... 6.1 UN3348 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flash point not less than 23 

degrees C.

6.1 UN3347 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Phenoxyacetic acid derivative pesticide, solid, toxic ...................................................................... 6.1 UN3345 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Phenyl chloroformate ...................................................................................................................... 6.1 UN2746 II 6.1, 8 IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L A 12, 13, 

21, 25, 

40, 100

Phenyl isocyanate ........................................................................................................................... 6.1 UN2487 I 6.1, 3 2, B9, B14, B32, 

B74, B77, N33, 

N34, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Phenyl mercaptan ........................................................................................................................... 6.1 UN2337 I 6.1, 3 2, B9, B14, B32, 

B74, B77, T20, 

TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden B 40, 52

Phenyl phosphorus dichloride ......................................................................................................... 8 UN2798 II 8 ........ B2, B15, IB2, T7, 

TP2

154 ...... 202 ...... 242 ...... Forbidden 30 L B 40

Phenyl phosphorus thiodichloride ................................................................................................... 8 UN2799 II 8 ........ B2, B15, IB2, T7, 

TP2

154 ...... 202 ...... 242 ...... Forbidden 30 L B 40

Phenylacetonitrile, liquid .................................................................................................................. 6.1 UN2470 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 52Phenylacetyl chloride ...................................................................................................................... 8 UN2577 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L C 40Phenylcarbylamine chloride ............................................................................................................ 6.1 UN1672 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

m-Phenylene diaminediperchlorate (dry) ........................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............

+ Phenylenediamines (o-; m-; p-;) ...................................................................................................... 6.1 UN1673 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Phenylhydrazine .............................................................................................................................. 6.1 UN2572 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40Phenylmercuric acetate ................................................................................................................... 6.1 UN1674 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Phenylmercuric compounds, n.o.s. ................................................................................................. 6.1 UN2026 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Phenylmercuric hydroxide ............................................................................................................... 6.1 UN1894 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Phenylmercuric nitrate ..................................................................................................................... 6.1 UN1895 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Phenyltrichlorosilane ....................................................................................................................... 8 UN1804 II 8 ........ A7, B6, IB2, 

N34, T7, TP2

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Phosgene ........................................................................................................................................ 2.3 UN1076 ............ 2.3, 8 1, B7, B46 None .... 192 ...... 314 ...... Forbidden Forbidden D 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76127

9-Phosphabicyclononanes or Cyclooctadiene phosphines ............................................................. 4.2 UN2940 II 4.2 ..... A19, IB6, IP2, 

T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg A ............

Phosphine ........................................................................................................................................ 2.3 UN2199 ............ 2.3, 

2.1.

1 None .... 192 ...... 245 ...... Forbidden Forbidden D 40

Phosphoric acid solution ................................................................................................................. 8 UN1805 III 8 ........ A7, IB3, N34, T4, 

TP1

154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Phosphoric acid, solid ..................................................................................................................... 8 UN3453 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Phosphoric acid triethyleneimine, see Tris-(1-aziridiyl)phosphine oxide, solution ......................... .................... ........... .......... .......... .......... .................... .................... ............Phosphoric anhydride, see Phosphorus pentoxide ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Phosphorous acid ............................................................................................................................ 8 UN2834 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 48

Phosphorus, amorphous ................................................................................................................. 4.1 UN1338 III 4.1 ..... A1, A19, B1, B9, 

B26, IB8, IP3, 

T1, TP33

None .... 213 ...... 243 ...... 25 kg 100 kg A 74

Phosphorus bromide, see Phosphorus tribromide .......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Phosphorus chloride, see Phosphorus trichloride .......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Phosphorus heptasulfide, free from yellow or white phosphorus ................................................... 4.1 UN1339 II 4.1 ..... A20, IB4, N34, 

T3, TP33

None .... 212 ...... 240 ...... 15 kg 50 kg B 74

Phosphorus oxybromide .................................................................................................................. 8 UN1939 II 8 ........ B8, IB8, IP2, IP4, 

N41, N43, T3, 

TP33

None .... 212 ...... 240 ...... Forbidden 50 kg C 12, 40

Phosphorus oxybromide, molten ..................................................................................................... 8 UN2576 II 8 ........ B2, B8, IB1, 

N41, N43, T7, 

TP3, TP13

None .... 202 ...... 242 ...... Forbidden Forbidden C 40

+ Phosphorus oxychloride .................................................................................................................. 8 UN1810 II 8, 6.1 2, B9, B14, B32, 

B74, B77, N34, 

T20, TP2, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden C 40

Phosphorus pentabromide .............................................................................................................. 8 UN2691 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... Forbidden 50 kg B 12, 40, 

53, 55

Phosphorus pentachloride ............................................................................................................... 8 UN1806 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

None .... 212 ...... 240 ...... Forbidden 50 kg C 40, 44, 

89, 

100, 

141

Phosphorus ..................................................................................................................................... 2.3 UN2198 ............ 2.3, 8 2, B9, B14 None .... 302, 

304.

314, 

315.

Forbidden Forbidden D 40

Phosphorus pentasulfide, free from yellow or white phosphorus ................................................... 4.3 UN1340 II 4.3, 

4.1.

A20, B59, IB4, 

T3, TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg B 74

Phosphorus pentoxide ..................................................................................................................... 8 UN1807 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Phosphorus sesquisulfide, free from yellow or white phosphorus ................................................. 4.1 UN1341 II 4.1 ..... A20, IB4, N34, 

T3, TP33

None .... 212 ...... 240 ...... 15 kg 50 kg B 74

Phosphorus tribromide .................................................................................................................... 8 UN1808 II 8 ........ A3, A6, A7, B2, 

B25, IB2, N34, 

N43, T7, TP2

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Phosphorus trichloride ..................................................................................................................... 6.1 UN1809 I 6.1, 8 2, B9, B14, B15, 

B32, B74, B77, 

N34, T20, TP2, 

TP13, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden C 40

Phosphorus trioxide ......................................................................................................................... 8 UN2578 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 12

Phosphorus trisulfide, free from yellow or white phosphorus ......................................................... 4.1 UN1343 II 4.1 ..... A20, IB4, N34, 

T3, TP33

None .... 212 ...... 240 ...... 15 kg 50 kg B 74

Phosphorus, white dry or Phosphorus, white, under water or Phosphorus white, in solution or

Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution.

4.2 UN1381 I 4.2, 

6.1.

B9, B26, N34, 

T9, TP3, TP31

None .... 188 ...... 243 ...... Forbidden Forbidden E ............

Phosphorus white, molten ............................................................................................................... 4.2 UN2447 I 4.2, 

6.1.

B9, B26, N34, 

T21, TP3, TP7, 

TP26

None .... 188 ...... 243 ...... Forbidden Forbidden D ............

Phosphorus (white or red) and a chlorate, mixtures of .................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Phosphoryl chloride, see Phosphorus oxychloride ......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Phthalic anhydride with more than .05 percent maleic anhydride .................................................. 8 UN2214 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Picolines .......................................................................................................................................... 3 UN2313 III 3 ........ B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40Picric acid, see Trinitrophenol, etc .................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Picrite, see Nitroguanidine, etc ....................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Picryl chloride, see Trinitrochlorobenzene ...................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Pine oil ............................................................................................................................................. 3 UN1272 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............alpha-Pinene ................................................................................................................................... 3 UN2368 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Piperazine ........................................................................................................................................ 8 UN2579 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 12, 52

Piperidine ......................................................................................................................................... 8 UN2401 I 8, 3 .... A10, T10, TP2 None .... 201 ...... 243 ...... 0.5 L 2.5 L B 52Pivaloyl chloride, see Trimethylacetyl chloride ............................................................................... .................... ........... .......... .......... .......... .................... .................... ............

76128 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Plastic molding compound in dough, sheet or extruded rope form evolving flammable vapor ..... 9 UN3314 III 9 ........ 32, IB8, IP3, IP7 155 ...... 221 ...... 221 ...... 100 kg 200 kg A 85, 87Plastic solvent, n.o.s., see Flammable liquids, n.o.s. ..................................................................... .................... ........... .......... .......... .......... .................... .................... ............Plastics, nitrocellulose-based, self-heating, n.o.s. .......................................................................... 4.2 UN2006 III 4.2 ..... None .... 213 ...... None .... Forbidden Forbidden C ............Poisonous gases, n.o.s., see Compressed or liquefied gases, flammable or toxic, n.o.s. ............ .................... ........... .......... .......... .......... .................... .................... ............Polyalkylamines, n.o.s., see Amines, etc ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Polychlorinated biphenyls, liquid ..................................................................................................... 9 UN2315 II 9 ........ 9, 81, 140, IB3, 

T4, TP1

155 ...... 202 ...... 241 ...... 100 L 220 L A 95

Polychlorinated biphenyls, solid ...................................................................................................... 9 UN3432 II 9 ........ 9, 81, 140, IB8, 

T3, TP33

155 ...... 212 ...... 240 ...... 100 kg 200 kg A 95

Polyester resin kit ............................................................................................................................ 3 UN3269 ............ 3 ........ 40, 149 152 ...... 225 ...... None .... 5 kg 5 kg B ............Polyhalogenated biphenyls, liquid or Polyhalogenated terphenyls liquid ....................................... 9 UN3151 II 9 ........ IB2 155 ...... 204 ...... 241 ...... 100 L 220 L A 95Polyhalogenated biphenyls, solid or Polyhalogenated terphenyls, solid ........................................ 9 UN3152 II 9 ........ IB8, IP2, IP4, T3, 

TP33

155 ...... 204 ...... 241 ...... 100 kg 200 kg A 95

Polymeric beads, expandable, evolving flammable vapor .............................................................. 9 UN2211 III 9 ........ 32, IB8, IP3, IP7, 

T1, TP33

155 ...... 221 ...... 221 ...... 100 kg 200 kg A 85, 87

Potassium ........................................................................................................................................ 4.3 UN2257 I 4.3 ..... A7, A19, A20, 

B27, IB4, IP1, 

N6, N34, T9, 

TP7, TP33

None .... 211 ...... 244 ...... Forbidden 15 kg D 52

Potassium arsenate ......................................................................................................................... 6.1 UN1677 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Potassium arsenite .......................................................................................................................... 6.1 UN1678 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Potassium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. ........................................... .................... ........... .......... .......... .......... .................... .................... ............Potassium borohydride .................................................................................................................... 4.3 UN1870 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Potassium bromate ......................................................................................................................... 5.1 UN1484 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Potassium carbonyl ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Potassium chlorate .......................................................................................................................... 5.1 UN1485 II 5.1 ..... A9, IB8, IP4, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Potassium chlorate, aqueous solution ............................................................................................ 5.1 UN2427 II 5.1 ..... A2, IB2, T4, TP1 152 ...... 202 ...... 241 ...... 1 L 5 L B 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... A2, IB2, T4, TP1 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 58, 

69, 133

Potassium chlorate mixed with mineral oil, see Explosive, blasting, type C .................................. .................... ........... .......... .......... .......... .................... .................... ............Potassium cuprocyanide ................................................................................................................. 6.1 UN1679 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52

Potassium cyanide, solid ................................................................................................................. 6.1 UN1680 I 6.1 ..... B69, B77, IB7, 

IP1, N74, N75, 

T6, TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B 52

Potassium cyanide solution ............................................................................................................. 6.1 UN3413 I 6.1 ..... B69, B77, N74, 

N75, T14, TP2, 

TP13

None .... 201 ...... 243 ...... 1 L 30 L B 52

.......................................................................................................................................................... .................... II 6.1 ..... B69, B77, IB2, 

N74, N75, T11, 

TP2, TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 52

.......................................................................................................................................................... .................... III 6.1 ..... B69, B77, IB3, 

N74, N75, T7, 

TP2, TP13, TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 52

Potassium dichloro isocyanurate or Potassium dichloro-s-triazinetrione, see Dichloroisocyanuric 

acid, dry or Dichloroisocyanuric acid salts etc.

.................... ........... .......... .......... .......... .................... .................... ............

Potassium dithionite or Potassium hydrosulfite .............................................................................. 4.2 UN1929 II 4.2 ..... A8, A19, A20, 

IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg E 13

Potassium fluoride, solid ................................................................................................................. 6.1 UN1812 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Potassium fluoride solution ............................................................................................................. 6.1 UN3422 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 52Potassium fluoroacetate .................................................................................................................. 6.1 UN2628 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg E ............

Potassium fluorosilicate ................................................................................................................... 6.1 UN2655 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Potassium hydrate, see Potassium hydroxide, solid ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Potassium hydrogen fluoride, see Potassium hydrogen difluoride ................................................. .................... ........... .......... .......... .......... .................... .................... ............Potassium hydrogen fluoride solution, see Corrosive liquid, n.o.s. ................................................ .................... ........... .......... .......... .......... .................... .................... ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76129

Potassium hydrogen sulfate ............................................................................................................ 8 UN2509 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Potassium hydrogendifluoride solid ................................................................................................ 8 UN1811 II 8, 6.1 IB8, IP2, IP4, 

N3, N34, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 25, 40, 

52

Potassium hydrogendifluoride solution ........................................................................................... 8 UN3421 II 8, 6.1 IB2, N3, N34, 

T7, TP2

154 ...... 202 ...... 243 ...... 1 L 30 L A 25, 40, 

52

.......................................................................................................................................................... .................... III 8, 6.1 IB3, N3, N34, 

T4, TP1

154 ...... 203 ...... 241 ...... 5 L 60 L A 40, 52

Potassium hydrosulfite, see Potassium dithionite ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Potassium hydroxide, liquid, see Potassium hydroxide solution .................................................... .................... ........... .......... .......... .......... .................... .................... ............Potassium hydroxide, solid ............................................................................................................. 8 UN1813 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Potassium hydroxide, solution ........................................................................................................ 8 UN1814 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Potassium hypochlorite, solution, see Hypochlorite solutions, etc ................................................. .................... ........... .......... .......... .......... .................... .................... ............Potassium, metal alloys, liquid ........................................................................................................ 4.3 UN1420 I 4.3 ..... A7, A19, A20, 

B27

None .... 201 ...... 244 ...... Forbidden 1 L E 40, 52

Potassium, metal alloys, solid ......................................................................................................... 4.3 UN3403 I 4.3 ..... A19, A20, B27, 

IB4, IP1, T9, 

TP7, TP33

None .... 211 ...... 244 ...... Forbidden 15 kg D ............

Potassium metal, liquid alloy, see Alkali metal alloys, liquid, n.o.s. ............................................... .................... ........... .......... .......... .......... .................... .................... ............Potassium metavanadate ................................................................................................................ 6.1 UN2864 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Potassium monoxide ....................................................................................................................... 8 UN2033 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 29

Potassium nitrate ............................................................................................................................. 5.1 UN1486 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Potassium nitrate and sodium nitrite mixtures ................................................................................ 5.1 UN1487 II 5.1 ..... B78, IB8, IP4, 

T3, TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 56, 58

Potassium nitrite .............................................................................................................................. 5.1 UN1488 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Potassium perchlorate ..................................................................................................................... 5.1 UN1489 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Potassium permanganate ............................................................................................................... 5.1 UN1490 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg D 56, 58, 

138

Potassium peroxide ......................................................................................................................... 5.1 UN1491 I 5.1 ..... A20, IB6, IP1, 

N34

None .... 211 ...... None .... Forbidden 15 kg B 13, 52, 

66, 75

Potassium persulfate ....................................................................................................................... 5.1 UN1492 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Potassium phosphide ...................................................................................................................... 4.3 UN2012 I 4.3, 

6.1.

A19, N40 None .... 211 ...... None .... Forbidden 15 kg E 40, 52, 

85

Potassium selenate, see Selenates or Selenites ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Potassium selenite, see Selenates or Selenites ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Potassium sodium alloys, solid ....................................................................................................... 4.3 UN3404 I 4.3 ..... A19, B27, N34, 

N40, T9, TP7, 

TP33

None .... 211 ...... 244 ...... Forbidden 15 kg D 52

Potassium sodium alloys, liquid ...................................................................................................... 4.3 UN1422 I 4.3 ..... A7, A19, B27, 

N34, N40, T9, 

TP3, TP7, TP31

None .... 201 ...... 244 ...... Forbidden 1 L E 40, 52

Potassium sulfide, anhydrous or Potassium sulfide with less than 30 percent water of crystallization. 4.2 UN1382 II 4.2 ..... A19, A20, B16, IB6, IP2, N34, 

T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg A 52

Potassium sulfide, hydrated with not less than 30 percent water of crystallization ....................... 8 UN1847 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 52

Potassium superoxide ..................................................................................................................... 5.1 UN2466 I 5.1 ..... A20, IB6, IP1 None .... 211 ...... None .... Forbidden 15 kg B 13, 52, 

66, 75

Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass ... 1.1C UN0433 II 1.1C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Powder cake, wetted or Powder paste, wetted with not less than 25 percent water, by mass .... 1.3C UN0159 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Powder paste, see Powder cake, etc ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Powder, smokeless ......................................................................................................................... 1.1C UN0160 II 1.1C .. None .... 62 ........ None .... Forbidden Forbidden 26E Powder, smokeless ......................................................................................................................... 1.3C UN0161 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 26E Power device, explosive, see Cartridges, power device ................................................................ .................... ........... .......... .......... .......... .................... .................... ............Primers, cap type ............................................................................................................................ 1.4S UN0044 II None None .... 62 ........ None .... 25 kg 100 kg 05 ............Primers, cap type ............................................................................................................................ 1.1B UN0377 II 1.1B ... None .... 62 ........ None .... Forbidden Forbidden 11 ............Primers, cap type ............................................................................................................................ 1.4B UN0378 II 1.4B ... None .... 62 ........ None .... Forbidden 75 kg 06 ............Primers, small arms, see Primers, cap type ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Primers, tubular ............................................................................................................................... 1.3G UN0319 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Primers, tubular ............................................................................................................................... 1.4G UN0320 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Primers, tubular ............................................................................................................................... 1.4S UN0376 II None None .... 62 ........ None .... 25 kg 100 kg 05 ............Printing ink, flammable or Printing ink related material (including printing ink thinning or reducing compound), flammable. 3 UN1210 I 3 ........ T11, TP1, TP8 150 ...... 173 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 173 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 173 ...... 242 ...... 60 L 220 L A ............

76130 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Projectiles, illuminating, see Ammunition, illuminating, etc ............................................................ .................... ........... .......... .......... .......... .................... .................... ............Projectiles, inert with tracer ............................................................................................................. 1.4S UN0345 II 1.4S ... .......... 62 ........ None .... 25 kg 100 kg 01 ............Projectiles, inert, with tracer ............................................................................................................ 1.3G UN0424 II 1.3G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Projectiles, inert, with tracer ............................................................................................................ 1.4G UN0425 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Projectiles, with burster or expelling charge ................................................................................... 1.2D UN0346 II 1.2D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Projectiles, with burster or expelling charge ................................................................................... 1.4D UN0347 II 1.4D .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Projectiles, with burster or expelling charge ................................................................................... 1.2F UN0426 II 1.2F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Projectiles, with burster or expelling charge ................................................................................... 1.4F UN0427 II 1.4F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Projectiles, with burster or expelling charge ................................................................................... 1.2G UN0434 II 1.2G .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Projectiles, with burster or expelling charge ................................................................................... 1.4G UN0435 II 1.4G .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Projectiles, with bursting charge ..................................................................................................... 1.1F UN0167 II 1.1F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Projectiles, with bursting charge ..................................................................................................... 1.1D UN0168 II 1.1D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Projectiles, with bursting charge ..................................................................................................... 1.2D UN0169 II 1.2D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............Projectiles, with bursting charge ..................................................................................................... 1.2F UN0324 II 1.2F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Projectiles, with bursting charge ..................................................................................................... 1.4D UN0344 II 1.4D .. .......... 62 ........ None .... Forbidden 75 kg 02 ............Propadiene, stabilized ..................................................................................................................... 2.1 UN2200 ............ 2.1 ..... None .... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Propadiene mixed with methyl acetylene, see Methyl acetylene and propadiene mixtures, stabilized. .................... ........... .......... .......... .......... .................... .................... ............Propane see also Petroleum gases, liquefied ................................................................................ 2.1 UN1978 ............ 2.1 ..... 19, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Propanethiols ................................................................................................................................... 3 UN2402 II 3 ........ A6, IB2, T4, TP1, 

TP13

150 ...... 202 ...... 242 ...... 5 L 60 L E 95, 102

n-Propanol or Propyl alcohol, normal ............................................................................................. 3 UN1274 II 3 ........ B1, IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Propellant, liquid .............................................................................................................................. 1.3C UN0495 II 1.3C .. 37 None .... 62 ........ None .... Forbidden Forbidden 10 ............Propellant, liquid .............................................................................................................................. 1.1C UN0497 II 1.1C .. 37 None .... 62 ........ None .... Forbidden Forbidden 10 ............Propellant, solid ............................................................................................................................... 1.1C UN0498 II 1.1C .. None .... 62 ........ None .... Forbidden Forbidden 26E Propellant, solid ............................................................................................................................... 1.3C UN0499 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 26E Propellant, solid ............................................................................................................................... 1.4C UN0501 ............ 1.4C .. None .... 62 ........ None .... Forbidden Forbidden A 24E Propionaldehyde .............................................................................................................................. 3 UN1275 II 3 ........ IB2, T7, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L E ............Propionic acid .................................................................................................................................. 8 UN1848 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Propionic anhydride ......................................................................................................................... 8 UN2496 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Propionitrile ...................................................................................................................................... 3 UN2404 II 3, 6.1 IB2, T7, TP1, 

TP13

None .... 202 ...... 243 ...... Forbidden 60 L E 40

Propionyl chloride ............................................................................................................................ 3 UN1815 II 3, 8 .... IB1, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40n-Propyl acetate .............................................................................................................................. 3 UN1276 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Propyl alcohol, see Propanol .......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............n-Propyl benzene ............................................................................................................................ 3 UN2364 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............n-Propyl chloroformate .................................................................................................................... 6.1 UN2740 I 6.1, 3, 

8.

2, B9, B14, B32, 

B74, B77, N34, 

T20, TP2, TP13, 

TP38, TP44

None .... 227 ...... 244 ...... Forbidden Forbidden B 21, 40, 

100

Propyl chloride see 1-Chloropropane ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Propyl formates ............................................................................................................................... 3 UN1281 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............n-Propyl isocyanate ......................................................................................................................... 6.1 UN2482 I 6.1, 3 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

Propyl mercaptan, see Propanethiols ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............n-Propyl nitrate ................................................................................................................................ 3 UN1865 II 3 ........ IB99 150 ...... 202 ...... None .... 5 L 60 L D 44, 89, 

90, 100

Propylamine ..................................................................................................................................... 3 UN1277 II 3, 8 .... A7, IB2, N34, T7, 

TP1

150 ...... 202 ...... 243 ...... 1 L 5 L E 40

Propylene see also Petroleum gases, liquefied .............................................................................. 2.1 UN1077 ............ 2.1 ..... 19, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Propylene chlorohydrin .................................................................................................................... 6.1 UN2611 II 6.1, 3 IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 5 L 60 L A 12, 40, 

48

Propylene oxide ............................................................................................................................... 3 UN1280 I 3 ........ A3, N34, T11, 

TP2, TP7

None .... 201 ...... 243 ...... 1 L 30 L E 40

Propylene tetramer .......................................................................................................................... 3 UN2850 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............1,2-Propylenediamine ...................................................................................................................... 8 UN2258 II 8, 3 .... A3, A6, IB2, 

N34, T7, TP2

None .... 202 ...... 243 ...... 1 L 30 L A 40

Propyleneimine, stabilized ............................................................................................................... 3 UN1921 I 3, 6.1 A3, N34, T14, 

TP2, TP13

None .... 201 ...... 243 ...... 1 L 30 L B 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76131

Propyltrichlorosilane ........................................................................................................................ 8 UN1816 II 8, 3 .... A7, B2, B6, IB2, 

N34, T7, TP2, 

TP13

None .... 202 ...... 243 ...... Forbidden 30 L C 40

Prussic acid, see Hydrogen cyanide ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Pyrethroid pesticide, liquid, flammable, toxic, flash point less than 23 degrees C ........................ 3 UN3350 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Pyrethroid pesticide, liquid toxic ...................................................................................................... 6.1 UN3352 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 211 ...... 242 ...... 1 L 30 L A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 212 ...... 242 ...... 5 L 60 L A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 213 ...... 240 ...... 60 L 220 L A 40

Pyrethroid pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C .................. 6.1 UN3351 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L B 40

Pyrethroid pesticide, solid, toxic ...................................................................................................... 6.1 UN3349 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Pyridine ............................................................................................................................................ 3 UN1282 II 3 ........ IB2, T4, TP2 None .... 202 ...... 242 ...... 5 L 60 L B 21, 100Pyridine perchlorate ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............

G Pyrophoric liquid, inorganic, n.o.s. .................................................................................................. 4.2 UN3194 I 4.2 ..... None .... 181 ...... 244 ...... Forbidden Forbidden D 18G Pyrophoric liquids, organic, n.o.s. ................................................................................................... 4.2 UN2845 I 4.2 ..... B11, T22, TP2, 

TP7

None .... 181 ...... 244 ...... Forbidden Forbidden D 18

G Pyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s. ................................................................... 4.2 UN1383 I 4.2 ..... B11, T21, TP7, 

TP33

None .... 187 ...... 242 ...... Forbidden Forbidden D ............

G Pyrophoric solid, inorganic, n.o.s. ................................................................................................... 4.2 UN3200 I 4.2 ..... T21, TP7, TP33 None .... 187 ...... 242 ...... Forbidden Forbidden D ............G Pyrophoric solids, organic, n.o.s. .................................................................................................... 4.2 UN2846 I 4.2 ..... None .... 187 ...... 242 ...... Forbidden Forbidden D ............

Pyrosulfuryl chloride ........................................................................................................................ 8 UN1817 II 8 ........ B2, IB2, T8, TP2, 

TP12

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Pyroxylin solution or solvent, see Nitrocellulose ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Pyrrolidine ........................................................................................................................................ 3 UN1922 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40Quebrachitol pentanitrate ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Quicklime, see Calcium oxide ......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Quinoline ......................................................................................................................................... 6.1 UN2656 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 12R 12, see Dichlorodifluoromethane ................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............R 12B1, see Chlorodifluorobromomethane ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............R 13, see Chlorotrifluoromethane ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............R 13B1, see Bromotrifluoromethane ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............R 14, see Tetrafluoromethane ........................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............R 21, see Dichlorofluoromethane ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............R 22, see Chlorodifluoromethane ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............R 114, see Dichlorotetrafluoroethane ............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............R 115, see Chloropentafluoroethane .............................................................................................. .................... ........... .......... .......... .......... .................... .................... ............R 116, see Hexafluoroethane ......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............R 124, see Chlorotetrafluoroethane ................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............R 133a, see Chlorotrifluoroethane .................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............R 152a, see Difluoroethane ............................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............R 500, see Dichlorodifluoromethane and difluorethane, etc .......................................................... .................... ........... .......... .......... .......... .................... .................... ............R 502, see Chlorodifluoromethane and chloropentafluoroethane mixture, etc .............................. .................... ........... .......... .......... .......... .................... .................... ............R 503, see Chlorotrifluoromethane and trifluoromethane, etc ........................................................ .................... ........... .......... .......... .......... .................... .................... ............Radioactive material, excepted package-articles manufactured from natural uranium or depleted uranium or natural thorium. 7 UN2909 ............ None 422, 426. 422, 426. 422, 426. .................... .................... A ............Radioactive material, excepted package-empty packaging ............................................................ 7 UN2908 ............ Empty 422, 

428.

422, 

428.

422, 

428.

.................... .................... A ............

Radioactive material, excepted package-instruments or articles ................................................... 7 UN2911 ............ None 422, 

424.

422, 

424.

.......... .................... .................... A ............

Radioactive material, excepted package-limited quantity of material ............................................. 7 UN2910 ............ None 421, 

422.

421, 

422.

421, 

422.

.................... .................... A ............

Radioactive material, low specific activity (LSA-I) non fissile or fissile-excepted .......................... 7 UN2912 ............ 7 ........ A56, T5, TP4, 

W7

421, 

422, 428.

427 ...... 427 ...... .................... .................... A 95, 129

Radioactive material, low specific activity (LSA-II) non fissile or fissile-excepted ......................... 7 UN3321 ............ 7 ........ A56, T5, TP4, 

W7

421, 

422, 428.

427 ...... 427 ...... .................... .................... A 95, 129

Radioactive material, low specific activity (LSA-III) non fissile or fissile excepted ........................ 7 UN3322 ............ 7 ........ A56, T5, TP4, 

W7

421, 

422, 428.

427 ...... 427 ...... .................... .................... A 95, 129

76132 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Radioactive material, surface contaminated objects (SCO-I or SCO-II) non fissile or fissile-excepted. 7 UN2913 ............ 7 ........ A56 421, 422, 

428.

427 ...... 427 ...... .................... .................... A 95

Radioactive material, transported under special arrangement, non fissile or fissile excepted ...... 7 UN2919 ............ 7 ........ A56, 139 .......... .......... .......... .................... .................... A 95, 105Radioactive material, transported under special arrangement, fissile ............................................ 7 UN3331 ............ 7 ........ A56, 139 .......... .......... .......... .................... .................... A 95, 105Radioactive material, Type A package, fissile non-special form .................................................... 7 UN3327 ............ 7 ........ A56, W7, W8 453 ...... 417 ...... 417 ...... .................... .................... A 95, 

105, 

131

Radioactive material, Type A package non-special form, non fissile or fissile-excepted .............. 7 UN2915 ............ 7 ........ A56, W7, W8 .......... 415 ...... 415 ...... .................... .................... A 95, 130Radioactive material, Type A package, special form non fissile or fissile-excepted ...................... 7 UN3332 ............ 7 ........ A56, W7, W8 .......... 415, 

476.

415, 

476.

.................... .................... A 95

Radioactive material, Type A package, special form, fissile .......................................................... 7 UN3333 ............ 7 ........ A56, W7, W8 453 ...... 417, 

476.

417, 

476.

.................... .................... A 95, 105

Radioactive material, Type B(M) package, fissile ........................................................................... 7 UN3329 ............ 7 ........ A56 453 ...... 417 ...... 417 ...... .................... .................... A 95, 105Radioactive material, Type B(M) package non fissile or fissile-excepted ...................................... 7 UN2917 ............ 7 ........ A56 .......... 416 ...... 416 ...... .................... .................... A 95, 105Radioactive material, Type B(U) package, fissile ........................................................................... 7 UN3328 ............ 7 ........ A56 453 ...... 417 ...... 417 ...... .................... .................... A 95, 105Radioactive material, Type B(U) package non fissile or fissile-excepted ...................................... 7 UN2916 ............ 7 ........ A56 .......... 416 ...... 416 ...... .................... .................... A 95, 105Radioactive material, uranium hexafluoride non fissile or fissile-excepted .................................... 7 UN2978 ............ 7, 8 .... 423 ...... 420, 

427.

420, 

427.

.................... .................... A 95, 132

I Radioactive material, uranium hexafluoride, fissile ......................................................................... 7 UN2977 ............ 7, 8 .... 453 ...... 417, 

420.

417, 

420.

.................... .................... A 95, 132

A W Rags, oily ......................................................................................................................................... 4.2 UN1856 III 4.2 ..... 151 ...... 213 ...... 240 ...... Forbidden Forbidden A ............

Railway torpedo, see Signals, railway track, explosive .................................................................. .................... ........... .......... .......... .......... .................... .................... ............Rare gases and nitrogen mixtures, compressed ............................................................................ 2.2 UN1981 ............ 2.2 ..... 306 ...... 302 ...... None .... 75 kg 150 kg A ............Rare gases and oxygen mixtures, compressed ............................................................................. 2.2 UN1980 ............ 2.2 ..... 79 306 ...... 302 ...... None .... 75 kg 150 kg A ............Rare gases mixtures, compressed ................................................................................................. 2.2 UN1979 ............ 2.2 ..... 306 ...... 302 ...... None .... 75 kg 150 kg A ............RC 318, see Octafluorocyclobutane ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............RDX and cyclotetramethylenetetranitramine, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized. .................... ........... .......... .......... .......... .................... .................... ............RDX and HMX mixtures, wetted with not less than 15 percent water by mass or RDX and HMX 

mixtures, desensitized with not less than 10 percent phlegmatizer by mass.

1.1D UN0391 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

RDX and Octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. .................... ........... .......... .......... .......... .................... .................... ............RDX, see Cyclotrimethylene trinitramine, etc ................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Receptacles, small, containing gas (gas cartridges) flammable, without release device, not refillable and not exceeding 1 L capacity. 2.1 UN2037 ............ 2.1 ..... 306 ...... 304 ...... None .... 1 kg 15 kg B 40Receptacles, small, containing gas (gas cartridges) non-flammable, without release device, not 

refillable and not exceeding 1 L capacity.

2.2 UN2037 ............ 2.2 ..... 306 ...... 304 ...... None .... 1 kg 15 kg B 40

.......................................................................................................................................................... .................... ............ 2.2, 

5.1.

A14 306 ...... 304 ...... None .... 1 kg 15 kg B 40

Red phosphorus, see Phosphorus, amorphous ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Refrigerant gas R 404A .................................................................................................................. 2.2 UN3337 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Refrigerant gas R 407A .................................................................................................................. 2.2 UN3338 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Refrigerant gas R 407B .................................................................................................................. 2.2 UN3339 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Refrigerant gas R 407C .................................................................................................................. 2.2 UN3340 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

G Refrigerant gases, n.o.s. ................................................................................................................. 2.2 UN1078 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

D Refrigerant gases, n.o.s. or Dispersant gases, n.o.s. .................................................................... 2.1 NA1954 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg D 40

Refrigerating machines, containing flammable, non-toxic, liquefied gas ........................................ 2.1 UN3358 ............ 2.1 ..... 306 ...... 306 ...... 306 ...... Forbidden Forbidden C 40Refrigerating machines, containing non-flammable, non-toxic, or ammonia solution (UN2672) ... 2.2 UN2857 ............ 2.2 ..... A53 306, 

307.

306 ...... 306, 

307.

450 kg 450 kg A ............

Regulated medical waste ................................................................................................................ 6.2 UN3291 II 6.2 ..... A13 134 ...... 197 ...... 197 ...... No limit No limit A 40Release devices, explosive ............................................................................................................. 1.4S UN0173 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Resin solution, flammable ............................................................................................................... 3 UN1866 I 3 ........ B52, T11, TP1, 

TP8, TP28

150 ...... 201 ...... 243 ...... 1 L 30 L E ............

.......................................................................................................................................................... .................... II 3 ........ 149, B52, IB2, 

T4, TP1, TP8

150 ...... 173 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B52, IB3, T2, 

TP1

150 ...... 173 ...... 242 ...... 60 L 220 L A ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76133

Resorcinol ........................................................................................................................................ 6.1 UN2876 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Rifle grenade, see Grenades, hand or rifle, etc ............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Rifle powder, see Powder, smokeless (UN 0160) .......................................................................... .................... ........... .......... .......... .......... .................... .................... ............Rivets, explosive ............................................................................................................................. 1.4S UN0174 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Road asphalt or tar liquid, see Tars, liquid, etc .............................................................................. .................... ........... .......... .......... .......... .................... .................... ............Rocket motors ................................................................................................................................. 1.3C UN0186 II 1.3C .. 109 None .... 62 ........ None .... Forbidden 220 kg 03 ............Rocket motors ................................................................................................................................. 1.1C UN0280 II 1.1C .. 109 None .... 62 ........ None .... Forbidden Forbidden 03 ............Rocket motors ................................................................................................................................. 1.2C UN0281 II 1.2C .. 109 None .... 62 ........ None .... Forbidden Forbidden 03 ............Rocket motors, liquid fueled ............................................................................................................ 1.2J UN0395 II 1.2J ... 109 None .... 62 ........ None .... Forbidden Forbidden 04 23E Rocket motors, liquid fueled ............................................................................................................ 1.3J UN0396 II 1.3J ... 109 None .... 62 ........ None .... Forbidden Forbidden 04 23E Rocket motors with hypergolic liquids with or without an expelling charge ................................... 1.3L UN0250 II 1.3L ... 109 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 

15E 

Rocket motors with hypergolic liquids with or without an expelling charge ................................... 1.2L UN0322 II 1.2L ... 109 None .... 62 ........ None .... Forbidden Forbidden 08 8E, 

14E, 

15E 

Rockets, line-throwing ..................................................................................................................... 1.2G UN0238 II 1.2G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Rockets, line-throwing ..................................................................................................................... 1.3G UN0240 II 1.3G .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Rockets, line-throwing ..................................................................................................................... 1.4G UN0453 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Rockets, liquid fueled with bursting charge .................................................................................... 1.1J UN0397 II 1.1J ... None .... 62 ........ None .... Forbidden Forbidden 04 23E Rockets, liquid fueled with bursting charge .................................................................................... 1.2J UN0398 II 1.2J ... None .... 62 ........ None .... Forbidden Forbidden 04 23E Rockets, with bursting charge ......................................................................................................... 1.1F UN0180 II 1.1F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Rockets, with bursting charge ......................................................................................................... 1.1E UN0181 II 1.1E ... None .... 62 ........ None .... Forbidden Forbidden 03 ............Rockets, with bursting charge ......................................................................................................... 1.2E UN0182 II 1.2E ... None .... 62 ........ None .... Forbidden Forbidden 03 ............Rockets, with bursting charge ......................................................................................................... 1.2F UN0295 II 1.2F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Rockets, with expelling charge ....................................................................................................... 1.2C UN0436 II 1.2C .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Rockets, with expelling charge ....................................................................................................... 1.3C UN0437 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Rockets, with expelling charge ....................................................................................................... 1.4C UN0438 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 02 ............Rockets, with inert head .................................................................................................................. 1.3C UN0183 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Rockets, with inert head .................................................................................................................. 1.2C UN0502 ............ 1.2C .. None .... 62 ........ None .... Forbidden Forbidden B 1E, 5E Rosin oil ........................................................................................................................................... 3 UN1286 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Rubber solution ............................................................................................................................... 3 UN1287 II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

Rubber scrap or shoddy, powdered or granulated, not exceeding 840 microns and rubber contend exceeding 45%. 4.1 UN1345 II 4.1 ..... IB8, IP2, IP4, T3, TP33 151 ...... 212 ...... 240 ...... 15 kg 50 kg A ............Rubber solution ............................................................................................................................... 3 UN1287 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Rubidium ......................................................................................................................................... 4.3 UN1423 I 4.3 ..... 22, A7, A19, IB4, 

IP1, N34, N40, 

N45

None .... 211 ...... 242 ...... Forbidden 15 kg D 52

Rubidium hydroxide ......................................................................................................................... 8 UN2678 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 29

Rubidium hydroxide solution ........................................................................................................... 8 UN2677 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 29

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A 29

Safety fuse, see Fuse, safety ......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Sand acid, see Fluorosilicic acid ..................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Seed cake, containing vegetable oil solvent extractions and expelled seeds, with not more than 

10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined.

4.2 UN1386 III None IB8, IP3, IP7, N7 None .... 213 ...... 241 ...... Forbidden Forbidden A 13

I Seed cake with more than 1.5 percent oil and not more than 11 percent moisture ...................... 4.2 UN1386 III None IB8, IP3, IP7, N7 None .... 213 ...... 241 ...... Forbidden Forbidden E 13I Seed cake with not more than 1.5 percent oil and not more than 11 percent moisture ............... 4.2 UN2217 III None IB8, IP3, IP7, N7 None .... 213 ...... 241 ...... Forbidden Forbidden A 13

Selenates or Selenites .................................................................................................................... 6.1 UN2630 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg E ............

Selenic acid ..................................................................................................................................... 8 UN1905 I 8 ........ IB7, IP1, N34, 

T6, TP33

None .... 211 ...... 242 ...... Forbidden 25 kg A ............

Selenium compound, solid, n.o.s. ................................................................................................... 6.1 UN3283 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

Selenium compound, liquid, n.o.s. .................................................................................................. 6.1 UN3440 I 6.1 ..... T14, TP2, TP27 None .... 201 ...... 243 ...... 1 L 30 L B ............Selenium compound, solid, n.o.s. ................................................................................................... 6.1 UN3283 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

Selenium compound, liquid, n.o.s. .................................................................................................. 6.1 UN3440 II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B ............

Selenium compound, solid, n.o.s. ................................................................................................... 6.1 UN3283 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Selenium compound, liquid, n.o.s. .................................................................................................. 6.1 UN3440 III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Selenium disulfide ........................................................................................................................... 6.1 UN2657 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Selenium hexafluoride ..................................................................................................................... 2.3 UN2194 ............ 2.3, 8 1 None .... 302 ...... None .... Forbidden Forbidden D 40Selenium nitride ............................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Selenium oxychloride ...................................................................................................................... 8 UN2879 I 8, 6.1 A3, A6, A7, N34, 

T10, TP2, TP12, 

TP13

None .... 201 ...... 243 ...... 0.5 L 2.5 L E 40

Self-defense spray, aerosol, see Aerosols, etc .............................................................................. .................... ........... .......... .......... .......... .................... .................... ............

76134 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

+ A D Self-defense spray, non-pressurized .............................................................................................. 9 NA3334 III 9 ........ A37 155 ...... 203 ...... None .... No limit No limit A ............

G Self-heating liquid, corrosive, inorganic, n.o.s. ............................................................................... 4.2 UN3188 II 4.2, 8 IB2 None .... 202 ...... 243 ...... 1 L 5 L C ............

.......................................................................................................................................................... .................... III 4.2, 8 IB2 None .... 203 ...... 241 ...... 5 L 60 L C ............

G Self-heating liquid, corrosive, organic, n.o.s. .................................................................................. 4.2 UN3185 II 4.2, 8 IB2 None .... 202 ...... 243 ...... 1 L 5 L C ............

.......................................................................................................................................................... .................... III 4.2, 8 IB2 None .... 203 ...... 241 ...... 5 L 60 L C ............

G Self-heating liquid, inorganic, n.o.s. ................................................................................................ 4.2 UN3186 II 4.2 ..... IB2 None .... 202 ...... 242 ...... 1 L 5 L C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB2 None .... 203 ...... 241 ...... 5 L 60 L C ............

G Self-heating liquid, organic, n.o.s. ................................................................................................... 4.2 UN3183 II 4.2 ..... IB2 None .... 202 ...... 242 ...... 1 L 5 L C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB2 None .... 203 ...... 241 ...... 5 L 60 L C ............

G Self-heating liquid, toxic, inorganic, n.o.s. ...................................................................................... 4.2 UN3187 II 4.2, 

6.1.

IB2 None .... 202 ...... 243 ...... 1 L 5 L C ............

.......................................................................................................................................................... .................... III 4.2, 

6.1.

IB2 None .... 203 ...... 241 ...... 5 L 60 L C ............

G Self-heating liquid, toxic, organic, n.o.s. ......................................................................................... 4.2 UN3184 II 4.2, 

6.1.

IB2 None .... 202 ...... 243 ...... 1 L 5 L C ............

.......................................................................................................................................................... .................... III 4.2, 

6.1.

IB2 None .... 203 ...... 241 ...... 5 L 60 L C ............

G Self-heating solid, corrosive, inorganic, n.o.s. ................................................................................ 4.2 UN3192 II 4.2, 8 IB5, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2, 8 IB8, IP3, T1, 

TP33

None .... 213 ...... 242 ...... 25 kg 100 kg C ............

G Self-heating, solid, corrosive, organic, n.o.s. .................................................................................. 4.2 UN3126 II 4.2, 8 IB5, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2, 8 IB8, IP3, T1, 

TP33

None .... 213 ...... 242 ...... 25 kg 100 kg C ............

G Self-heating solid, inorganic, n.o.s. ................................................................................................. 4.2 UN3190 II 4.2 ..... IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg C ............

G Self-heating, solid, organic, n.o.s. ................................................................................................... 4.2 UN3088 II 4.2 ..... IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg C ............

G Self-heating, solid, oxidizing, n.o.s. ................................................................................................. 4.2 UN3127 ............ 4.2, 

5.1.

None .... 214 ...... 214 ...... Forbidden Forbidden ............

G Self-heating solid, toxic, inorganic, n.o.s. ....................................................................................... 4.2 UN3191 II 4.2, 

6.1.

IB5, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2, 

6.1.

IB8, IP3, T1, 

TP33

None .... 213 ...... 242 ...... 25 kg 100 kg C ............

G Self-heating, solid, toxic, organic, n.o.s. ......................................................................................... 4.2 UN3128 II 4.2, 

6.1.

IB5, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg C ............

.......................................................................................................................................................... .................... III 4.2, 

6.1.

IB8, IP3, T1, 

TP33

None .... 213 ...... 242 ...... 25 kg 100 kg C ............

Self-propelled vehicle, see Engines or Batteries etc ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............

G Self-reactive liquid type B ............................................................................................................... 4.1 UN3221 II 4.1 ..... 53 None .... 224 ...... None .... Forbidden Forbidden D 52, 53G Self-reactive liquid type B, temperature controlled ......................................................................... 4.1 UN3231 II 4.1 ..... 53 None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive liquid type C ............................................................................................................... 4.1 UN3223 II 4.1 ..... None .... 224 ...... None .... 5 L 10 L D 52, 53G Self-reactive liquid type C, temperature controlled ......................................................................... 4.1 UN3233 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive liquid type D ............................................................................................................... 4.1 UN3225 II 4.1 ..... None .... 224 ...... None .... 5 L 10 L D 52, 53G Self-reactive liquid type D, temperature controlled ......................................................................... 4.1 UN3235 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive liquid type E ............................................................................................................... 4.1 UN3227 II 4.1 ..... None .... 224 ...... None .... 10 L 25 L D 52, 53G Self-reactive liquid type E, temperature controlled ......................................................................... 4.1 UN3237 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive liquid type F ................................................................................................................ 4.1 UN3229 II 4.1 ..... T23 None .... 224 ...... None .... 10 L 25 L D 52, 53G Self-reactive liquid type F, temperature controlled ......................................................................... 4.1 UN3239 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive solid type B ................................................................................................................ 4.1 UN3222 II 4.1 ..... 53 None .... 224 ...... None .... Forbidden Forbidden D 52, 53G Self-reactive solid type B, temperature controlled .......................................................................... 4.1 UN3232 II 4.1 ..... 53 None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive solid type C ................................................................................................................ 4.1 UN3224 II 4.1 ..... None .... 224 ...... None .... 5 kg 10 kg D 52, 53G Self-reactive solid type C, temperature controlled .......................................................................... 4.1 UN3234 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76135

G Self-reactive solid type D ................................................................................................................ 4.1 UN3226 II 4.1 ..... None .... 224 ...... None .... 5 kg 10 kg D 52, 53G Self-reactive solid type D, temperature controlled .......................................................................... 4.1 UN3236 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive solid type E ................................................................................................................ 4.1 UN3228 II 4.1 ..... None .... 224 ...... None .... 10 kg 25 kg D 52, 53G Self-reactive solid type E, temperature controlled .......................................................................... 4.1 UN3238 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

G Self-reactive solid type F ................................................................................................................. 4.1 UN3230 II 4.1 ..... None .... 224 ...... None .... 10 kg 25 kg D 52, 53G Self-reactive solid type F, temperature controlled .......................................................................... 4.1 UN3240 II 4.1 ..... None .... 224 ...... None .... Forbidden Forbidden D 2, 52, 

53

Shale oil ........................................................................................................................................... 3 UN1288 I 3 ........ T11, TP1, TP8, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T4, TP1, 

TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Shaped charges, see Charges, shaped, etc .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Signal devices, hand ....................................................................................................................... 1.4G UN0191 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Signal devices, hand ....................................................................................................................... 1.4S UN0373 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Signals, distress, ship ..................................................................................................................... 1.1G UN0194 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Signals, distress, ship ..................................................................................................................... 1.3G UN0195 II 1.3G .. None .... 62 ........ None .... Forbidden 75 kg 07 ............Signals, highway, see Signal devices, hand ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Signals, railway track, explosive ..................................................................................................... 1.1G UN0192 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Signals, railway track, explosive ..................................................................................................... 1.4S UN0193 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............Signals, railway track, explosive ..................................................................................................... 1.3G UN0492 ............ 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Signals, railway track, explosive ..................................................................................................... 1.4G UN0493 ............ 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Signals, ship distress, water-activated, see Contrivances, water-activated, etc ............................ .................... ........... .......... .......... .......... .................... .................... ............Signals, smoke ................................................................................................................................ 1.1G UN0196 II 1.1G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Signals, smoke ................................................................................................................................ 1.4G UN0197 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Signals, smoke ................................................................................................................................ 1.2G UN0313 II 1.2G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Signals, smoke ................................................................................................................................ 1.3G UN0487 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Silane ............................................................................................................................................... 2.1 UN2203 ............ 2.1 ..... None .... 302 ...... None .... Forbidden Forbidden E 40, 57, 

104

Silicofluoric acid, see Fluorosilicic acid ........................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Silicon chloride, see Silicon tetrachloride ....................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Silicon powder, amorphous ............................................................................................................. 4.1 UN1346 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg A 74

Silicon tetrachloride ......................................................................................................................... 8 UN1818 II 8 ........ A3, A6, B2, B6, 

IB2, T7, TP2, 

TP7

154 ...... 202 ...... 242 ...... 1 L 30 L C 40

Silicon tetrafluoride .......................................................................................................................... 2.3 UN1859 ............ 2.3, 8 2 None .... 302 ...... None .... Forbidden Forbidden D 40Silver acetylide (dry) ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Silver arsenite .................................................................................................................................. 6.1 UN1683 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Silver azide (dry) ............................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Silver chlorite (dry) .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Silver cyanide .................................................................................................................................. 6.1 UN1684 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40, 52

Silver fulminate (dry) ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Silver nitrate .................................................................................................................................... 5.1 UN1493 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A ............

Silver oxalate (dry) .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Silver picrate (dry) ........................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Silver picrate, wetted with not less than 30 percent water, by mass ............................................. 4.1 UN1347 I 4.1 ..... 23 None .... 211 ...... None .... Forbidden Forbidden D 28, 36Sludge, acid ..................................................................................................................................... 8 UN1906 II 8 ........ A3, A7, B2, IB2, 

N34, T8, TP2, 

TP12, TP28

None .... 202 ...... 242 ...... Forbidden 30 L C 14

D Smokeless powder for small arms (100 pounds or less) ............................................................... 4.1 NA3178 I 4.1 ..... 16 None .... 171 ...... None .... Forbidden 7.3 kg A ............

Soda lime with more than 4 percent sodium hydroxide ................................................................. 8 UN1907 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Sodium ............................................................................................................................................ 4.3 UN1428 I 4.3 ..... A7, A8, A19, 

A20, B9, B48, B68, IB4, IP1, 

N34, T9, TP7, 

TP33, TP46

None .... 211 ...... 244 ...... Forbidden 15 kg D 52

Sodium aluminate, solid .................................................................................................................. 8 UN2812 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Sodium aluminate, solution ............................................................................................................. 8 UN1819 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Sodium aluminum hydride ............................................................................................................... 4.3 UN2835 II 4.3 ..... A8, A19, A20, 

IB4, T3, TP33

151 ...... 212 ...... 242 ...... Forbidden 50 kg E 52

Sodium ammonium vanadate ......................................................................................................... 6.1 UN2863 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Sodium arsanilate ............................................................................................................................ 6.1 UN2473 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Sodium arsenate ............................................................................................................................. 6.1 UN1685 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

76136 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sodium arsenite, aqueous solutions ............................................................................................... 6.1 UN1686 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T4, TP2 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Sodium arsenite, solid ..................................................................................................................... 6.1 UN2027 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Sodium azide ................................................................................................................................... 6.1 UN1687 II 6.1 ..... IB8, IP2, IP4 153 ...... 212 ...... 242 ...... 25 kg 100 kg A 36, 52, 

91

Sodium bifluoride, see Sodium hydrogendifluoride ........................................................................ .................... ........... .......... .......... .......... .................... .................... ............Sodium bisulfite, solution, see Bisulfites, aqueous solutions, n.o.s. .............................................. .................... ........... .......... .......... .......... .................... .................... ............Sodium borohydride ........................................................................................................................ 4.3 UN1426 I 4.3 ..... N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52Sodium borohydride and sodium hydroxide solution, with not more than 12 percent sodium 

borohydride and not more than 40 percent sodium hydroxide by mass.

8 UN3320 II 8 ........ B2, IB2, N34, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A 52

.......................................................................................................................................................... .................... III 8 ........ B2, IB3, N34, T4, 

TP2

154 ...... 203 ...... 241 ...... 5 L 60 L A 52

Sodium bromate .............................................................................................................................. 5.1 UN1494 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Sodium cacodylate .......................................................................................................................... 6.1 UN1688 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 52

Sodium carbonate peroxyhydrate ................................................................................................... 5.1 UN3378 II 5.1 ..... IB8, IP2, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 13, 48, 

75

.......................................................................................................................................................... .................... III 5.1 ..... IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 13, 48, 

75

Sodium chlorate .............................................................................................................................. 5.1 UN1495 II 5.1 ..... A9, IB8, IP4, 

N34, T3, TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 56, 58

Sodium chlorate, aqueous solution ................................................................................................. 5.1 UN2428 II 5.1 ..... A2, IB2, T4, TP1 152 ...... 202 ...... 241 ...... 1 L 5 L B 56, 58, 

133

.......................................................................................................................................................... .................... III 5.1 ..... A2, IB2, T4, TP1 152 ...... 203 ...... 241 ...... 2.5 L 30 L B 56, 58, 

69, 133

Sodium chlorate mixed with dinitrotoluene, see Explosive blasting, type C .................................. .................... ........... .......... .......... .......... .................... .................... ............Sodium chlorite ................................................................................................................................ 5.1 UN1496 II 5.1 ..... A9, IB8, IP2, IP4, 

N34, T3, TP33

None .... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Sodium chloroacetate ...................................................................................................................... 6.1 UN2659 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Sodium cuprocyanide, solid ............................................................................................................ 6.1 UN2316 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 52

Sodium cuprocyanide, solution ....................................................................................................... 6.1 UN2317 I 6.1 ..... T14, TP2, TP13 None .... 201 ...... 243 ...... 1 L 30 L B 40, 52Sodium cyanide, solid ..................................................................................................................... 6.1 UN1689 I 6.1 ..... B69, B77, IB7, 

N74, N75, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B 52

Sodium cyanide solution ................................................................................................................. 6.1 UN3414 I 6.1 ..... B69, B77, N74, 

N75, T14, TP2, 

TP13

None .... 201 ...... 243 ...... 1 L 30 L B 52

.......................................................................................................................................................... .................... II 6.1 ..... B69, B77, IB2, 

N74, N75, T11, 

TP2, TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 52

.......................................................................................................................................................... .................... III 6.1 ..... B69, B77, IB3, 

N74, N75, T7, 

TP2, TP13, TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 52

Sodium dichloroisocyanurate or Sodium dichloro-s-triazinetrione, see Dichloroisocyanuric acid 

etc.

.................... ........... .......... .......... .......... .................... .................... ............

Sodium dinitro-o-cresolate, dry or wetted with less than 15 percent water, by mass ................... 1.3C UN0234 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 5E Sodium dinitro-o-cresolate, wetted with not less than 10% water, by mass .................................. 4.1 UN3369 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

Sodium dinitro-o-cresolate, wetted with not less than 15 percent water, by mass ........................ 4.1 UN1348 I 4.1, 

6.1.

23, A8, A19, 

A20, N41

None .... 211 ...... None .... 1 kg 15 kg E 28, 36

Sodium dithionite or Sodium hydrosulfite ....................................................................................... 4.2 UN1384 II 4.2 ..... A19, A20, IB6, 

IP2, T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg E 13

Sodium fluoride, solid ...................................................................................................................... 6.1 UN1690 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Sodium fluoride solution .................................................................................................................. 6.1 UN3415 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A 52Sodium fluoroacetate ...................................................................................................................... 6.1 UN2629 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg E ............

Sodium fluorosilicate ....................................................................................................................... 6.1 UN2674 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Sodium hydrate, see Sodium hydroxide, solid ............................................................................... .................... ........... .......... .......... .......... .................... .................... ............Sodium hydride ............................................................................................................................... 4.3 UN1427 I 4.3 ..... A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 52

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76137

Sodium hydrogendifluoride .............................................................................................................. 8 UN2439 II 8 ........ IB8, IP2, IP4, 

N3, N34, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 12, 25, 

40, 52

Sodium hydrosulfide, with less than 25 percent water of crystallization ........................................ 4.2 UN2318 II 4.2 ..... A7, A19, A20, 

IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg A ............

Sodium hydrosulfide with not less than 25 percent water of crystallization ................................... 8 UN2949 II 8 ........ A7, IB8, IP2, IP4, 

T7, TP2

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 52

Sodium hydrosulfite, see Sodium dithionite .................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Sodium hydroxide, solid .................................................................................................................. 8 UN1823 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Sodium hydroxide solution .............................................................................................................. 8 UN1824 II 8 ........ B2, IB2, N34, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... III 8 ........ IB3, N34, T4, 

TP1

154 ...... 203 ...... 241 ...... 5 L 60 L A ............

Sodium hypochlorite, solution, see Hypochlorite solutions etc ....................................................... .................... ........... .......... .......... .......... .................... .................... ............Sodium metal, liquid alloy, see Alkali metal alloys, liquid, n.o.s. ................................................... .................... ........... .......... .......... .......... .................... .................... ............Sodium methylate ............................................................................................................................ 4.2 UN1431 II 4.2, 8 A7, A19, IB5, 

IP2, T3, TP33

None .... 212 ...... 242 ...... 15 kg 50 kg B ............

Sodium methylate solutions in alcohol ............................................................................................ 3 UN1289 II 3, 8 .... IB2, T7, TP1, 

TP8

150 ...... 202 ...... 243 ...... 1 L 5 L B ............

.......................................................................................................................................................... .................... III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A ............

Sodium monoxide ............................................................................................................................ 8 UN1825 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Sodium nitrate ................................................................................................................................. 5.1 UN1498 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Sodium nitrate and potassium nitrate mixtures .............................................................................. 5.1 UN1499 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Sodium nitrite .................................................................................................................................. 5.1 UN1500 III 5.1, 

6.1.

A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Sodium pentachlorophenate ........................................................................................................... 6.1 UN2567 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Sodium perborate monohydrate ...................................................................................................... 5.1 UN3377 III 5.1 ..... IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 13, 48, 

75

Sodium perchlorate ......................................................................................................................... 5.1 UN1502 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Sodium permanganate .................................................................................................................... 5.1 UN1503 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg D 56, 58, 

138

Sodium peroxide ............................................................................................................................. 5.1 UN1504 I 5.1 ..... A20, IB5, IP1, 

N34

None .... 211 ...... None .... Forbidden 15 kg B 13, 52, 

66, 75

Sodium peroxoborate, anhydrous ................................................................................................... 5.1 UN3247 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 13, 25

Sodium persulfate ........................................................................................................................... 5.1 UN1505 III 5.1 ..... A1, IB8, IP3, T1, 

TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Sodium phosphide ........................................................................................................................... 4.3 UN1432 I 4.3, 

6.1.

A19, N40 None .... 211 ...... None .... Forbidden 15 kg E 40, 52, 

85

Sodium picramate, dry or wetted with less than 20 percent water, by mass ................................ 1.3C UN0235 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 5E Sodium picramate, wetted with not less than 20 percent water, by mass ..................................... 4.1 UN1349 I 4.1 ..... 23, A8, A19, N41 None .... 211 ...... None .... Forbidden 15 kg E 28, 36Sodium picryl peroxide .................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Sodium potassium alloys, see Potassium sodium alloys ............................................................... .................... ........... .......... .......... .......... .................... .................... ............Sodium selenate, see Selenates or Selenites ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization .. 4.2 UN1385 II 4.2 ..... A19, A20, IB6, 

IP2, N34, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg A 52

Sodium sulfide, hydrated with not less than 30 percent water ....................................................... 8 UN1849 II 8 ........ IB8, IP2, IP4, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 26

Sodium superoxide .......................................................................................................................... 5.1 UN2547 I 5.1 ..... A20, IB6, IP1, 

N34

None .... 211 ...... None .... Forbidden 15 kg E 13, 52, 

66, 75

Sodium tetranitride .......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............

G Solids containing corrosive liquid, n.o.s. ......................................................................................... 8 UN3244 II 8 ........ 49, IB5, T3, 

TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg B 40

G Solids containing flammable liquid, n.o.s. ....................................................................................... 4.1 UN3175 II 4.1 ..... 47, IB6, IP2, T3, 

TP33

151 ...... 212 ...... 240 ...... 15 kg 50 kg B ............

G Solids containing toxic liquid, n.o.s. ................................................................................................ 6.1 UN3243 II 6.1 ..... 48, IB2, T2, 

TP33

153 ...... 212 ...... 240 ...... 25 kg 100 kg B 40

Sounding devices, explosive ........................................................................................................... 1.2F UN0204 II 1.2F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Sounding devices, explosive ........................................................................................................... 1.1F UN0296 II 1.1F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Sounding devices, explosive ........................................................................................................... 1.1D UN0374 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Sounding devices, explosive ........................................................................................................... 1.2D UN0375 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Spirits of salt, see Hydrochloric acid ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Squibs, see Igniters etc ................................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Stannic chloride, anhydrous ............................................................................................................ 8 UN1827 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L C ............Stannic chloride pentahydrate ......................................................................................................... 8 UN2440 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

76138 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Stannic phosphide ........................................................................................................................... 4.3 UN1433 I 4.3, 

6.1.

A19, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 40, 52, 

85

Steel swarf, see Ferrous metal borings, etc ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Stibine .............................................................................................................................................. 2.3 UN2676 ............ 2.3, 

2.1.

1 None .... 304 ...... None .... Forbidden Forbidden D 40

Storage batteries, wet, see Batteries, wet etc ................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Strontium arsenite ........................................................................................................................... 6.1 UN1691 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Strontium chlorate ........................................................................................................................... 5.1 UN1506 II 5.1 ..... A1, A9, IB8, IP2, 

IP4, N34, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Strontium nitrate .............................................................................................................................. 5.1 UN1507 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Strontium perchlorate ...................................................................................................................... 5.1 UN1508 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Strontium peroxide .......................................................................................................................... 5.1 UN1509 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 13, 52, 

66, 75

Strontium phosphide ....................................................................................................................... 4.3 UN2013 I 4.3, 

6.1.

A19, N40 None .... 211 ...... None .... Forbidden 15 kg E 40, 52, 

85

Strychnine or Strychnine salts ........................................................................................................ 6.1 UN1692 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

Styphnic acid, see Trinitroresorcinol, etc ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Styrene monomer, stabilized ........................................................................................................... 3 UN2055 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

G Substances, explosive, n.o.s. .......................................................................................................... 1.1L UN0357 II 1.1L ... 101 None .... 62 ........ None .... Forbidden Forbidden 8E, 

14E, 15E, 

17E 

G Substances, explosive, n.o.s. .......................................................................................................... 1.2L UN0358 II 1.2L ... 101 None .... 62 ........ None .... Forbidden Forbidden 8E, 

14E, 15E, 

17E 

G Substances, explosive, n.o.s. .......................................................................................................... 1.3L UN0359 II 1.3L ... 101 None .... 62 ........ None .... Forbidden Forbidden 8E, 

14E, 15E, 

17E 

G Substances, explosive, n.o.s. .......................................................................................................... 1.1A UN0473 II 1.1A ... 101, 111 None .... 62 ........ None .... Forbidden Forbidden 12 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.1C UN0474 II 1.1C .. 101 None .... 62 ........ None .... Forbidden Forbidden 10 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.1D UN0475 II 1.1D .. 101 None .... 62 ........ None .... Forbidden Forbidden 10 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.1G UN0476 II 1.1G .. 101 None .... 62 ........ None .... Forbidden Forbidden 08 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.3C UN0477 II 1.3C .. 101 None .... 62 ........ None .... Forbidden Forbidden 10 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.3G UN0478 II 1.3G .. 101 None .... 62 ........ None .... Forbidden Forbidden 08 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.4C UN0479 II 1.4C .. 101 None .... 62 ........ None .... Forbidden 75 kg 09 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.4D UN0480 II 1.4D .. 101 None .... 62 ........ None .... Forbidden 75 kg 09 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.4S UN0481 II 1.4S ... 101 None .... 62 ........ None .... 25 kg 75 kg 05 ............G Substances, explosive, n.o.s. .......................................................................................................... 1.4G UN0485 II 1.4G .. 101 None .... 62 ........ None .... Forbidden 75 kg 08 ............G Substances, explosive, very insensitive, n.o.s., or Substances, EVI, n.o.s. .................................. 1.5D UN0482 II 1.5D .. 101 None .... 62 ........ None .... Forbidden Forbidden 10 ............

Substituted nitrophenol pesticides, liquid, flammable, toxic, flash point less than 23 degrees C .. 3 UN2780 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Substituted nitrophenol pesticides, liquid, toxic .............................................................................. 6.1 UN3014 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Substituted nitrophenol pesticides, liquid, toxic, flammable, flash point not less than 23 degrees 

C.

6.1 UN3013 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 B1, IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Substituted nitrophenol pesticides, solid, toxic ............................................................................... 6.1 UN2779 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76139

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Sucrose octanitrate (dry) ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Sulfamic acid ................................................................................................................................... 8 UN2967 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

D Sulfur ............................................................................................................................................... 9 NA1350 III 9 ........ 10, IB8, IP2 None .... None .... 240 ...... No limit No limit A 19, 74

I Sulfur ............................................................................................................................................... 4.1 UN1350 III 4.1 ..... 30, IB8, IP3, T1, 

TP33

None .... None .... 240 ...... No limit No limit A 19, 74

Sulfur and chlorate, loose mixtures of ............................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Sulfur chlorides ................................................................................................................................ 8 UN1828 I 8 ........ 5, A3, A7, A10, 

B10, B77, N34, 

T20, TP2, TP12

None .... 201 ...... 243 ...... Forbidden 2.5 L C 40

Sulfur dichloride, see Sulfur chlorides ............................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Sulfur dioxide ................................................................................................................................... 2.3 UN1079 ............ 2.3, 8 3, B14, T50, 

TP19

None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Sulfur dioxide solution, see Sulfurous acid ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Sulfur hexafluoride .......................................................................................................................... 2.2 UN1080 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

D Sulfur, molten .................................................................................................................................. 9 NA2448 III 9 ........ 30, IB3, T1, TP3 None .... 213 ...... 247 ...... Forbidden Forbidden C 61

I Sulfur, molten .................................................................................................................................. 4.1 UN2448 III 4.1 ..... 30, IB1, T1, TP3 None .... 213 ...... 247 ...... Forbidden Forbidden C 61

Sulfur tetrafluoride ........................................................................................................................... 2.3 UN2418 ............ 2.3, 8 1 None .... 302 ...... 245 ...... Forbidden Forbidden D 40, 52

+ Sulfur trioxide, stabilized ................................................................................................................. 8 UN1829 I 8, 6.1 2, B9, B14, B32, 

B49, B74, B77, 

N34, T20, TP4, 

TP12, TP13, 

TP25, TP26, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden A 40

Sulfuretted hydrogen, see Hydrogen sulfide ................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Sulfuric acid, fuming with less than 30 percent free sulfur trioxide ................................................ 8 UN1831 I 8 ........ B84, N34, T20, 

TP2, TP12, TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L C 14, 40

+ Sulfuric acid, fuming with 30 percent or more free sulfur trioxide .................................................. 8 UN1831 I 8, 6.1 2, A3, A6, A7, 

B9, B14, B32, 

B74, B77, B84, 

N34, T20, TP2, 

TP12, TP13

None .... 227 ...... 244 ...... Forbidden Forbidden C 14, 40

Sulfuric acid, spent .......................................................................................................................... 8 UN1832 II 8 ........ A3, A7, B2, B83, 

B84, IB2, N34, T8, TP2, TP12

None .... 202 ...... 242 ...... Forbidden 30 L C 14

Sulfuric acid with more than 51 percent acid ................................................................................. 8 UN1830 II 8 ........ A3, A7, B3, B83, 

B84, IB2, N34, 

T8, TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L C 14

Sulfuric acid with not more than 51% acid ..................................................................................... 8 UN2796 II 8 ........ A3, A7, B2, B15, 

IB2, N6, N34, 

T8, TP2, TP12

154 ...... 202 ...... 242 ...... 1 L 30 L B ............

Sulfuric and hydrofluoric acid mixtures, see Hydrofluoric and sulfuric acid mixtures .................... .................... ........... .......... .......... .......... .................... .................... ............Sulfuric anhydride, see Sulfur trioxide, stabilized ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Sulfurous acid .................................................................................................................................. 8 UN1833 II 8 ........ B3, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L B 40

+ Sulfuryl chloride ............................................................................................................................... 8 UN1834 I 8, 6.1 1, B6, B9, B10, 

B14, B30, B74, B77, N34, T22, 

TP2, TP12, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden C 40

Sulfuryl fluoride ................................................................................................................................ 2.3 UN2191 ............ 2.3 ..... 4 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Tars, liquid including road asphalt and oils, bitumen and cut backs .............................................. 3 UN1999 II 3 ........ 149, B13, IB2, 

T3, TP3, TP29

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, B13, IB3, T1, 

TP3

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Tear gas candles ............................................................................................................................. 6.1 UN1700 II 6.1, 

4.1.

None .... 340 ...... None .... Forbidden 50 kg D 40

Tear gas cartridges, see Ammunition, tear-producing, etc ............................................................. .................... ........... .......... .......... .......... .................... .................... ............

D Tear gas devices with more than 2 percent tear gas substances, by mass .................................. 6.1 NA1693 I 6.1 ..... None .... 340 ...... None .... Forbidden Forbidden D 40

.......................................................................................................................................................... .................... II 6.1 ..... None .... 340 ...... None .... Forbidden Forbidden D 40

Tear gas devices, with not more than 2 percent tear gas substances, by mass, see Aerosols, 

etc.

.................... ........... .......... .......... .......... .................... .................... ............

Tear gas grenades, see Tear gas candles ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

G Tear gas substances, liquid, n.o.s. ................................................................................................. 6.1 UN1693 I 6.1 ..... None .... 201 ...... None .... Forbidden Forbidden D 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2 None .... 202 ...... None .... Forbidden 5 L D 40

G Tear gas substance, solid, n.o.s. .................................................................................................... 6.1 UN3448 I 6.1 ..... T6, TP33 None .... 211 ...... 242 ...... Forbidden Forbidden D 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

None .... 212 ...... 242 ...... Forbidden 25 kg D 40

Tellurium compound, n.o.s. ............................................................................................................. 6.1 UN3284 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

76140 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Tellurium hexafluoride ..................................................................................................................... 2.3 UN2195 ............ 2.3, 8 1 None .... 302 ...... None .... Forbidden Forbidden D 40Terpene hydrocarbons, n.o.s. ......................................................................................................... 3 UN2319 III 3 ........ B1, IB3, T4, TP1, 

TP29

150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Terpinolene ...................................................................................................................................... 3 UN2541 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Tetraazido benzene quinone ........................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetrabromoethane ........................................................................................................................... 6.1 UN2504 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............1,1,2,2-Tetrachloroethane ............................................................................................................... 6.1 UN1702 II 6.1 ..... IB2, N36, T7, 

TP2

153 ...... 202 ...... 243 ...... 5 L 60 L A 40

Tetrachloroethylene ......................................................................................................................... 6.1 UN1897 III 6.1 ..... IB3, N36, T4, 

TP1

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Tetraethyl dithiopyrophosphate ....................................................................................................... 6.1 UN1704 II 6.1 ..... IB2, T7, TP2 153 ...... 212 ...... 242 ...... 25 kg 100 kg D 40Tetraethyl silicate ............................................................................................................................ 3 UN1292 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Tetraethylammonium perchlorate (dry) ........................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetraethylenepentamine .................................................................................................................. 8 UN2320 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a ..................................................................... 2.2 UN3159 ............ 2.2 ..... T50 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

Tetrafluoroethylene, stabilized ........................................................................................................ 2.1 UN1081 ............ 2.1 ..... 306 ...... 304 ...... None .... Forbidden 150 kg E 40Tetrafluoromethane or Refrigerant gas R 14 .................................................................................. 2.2 UN1982 ............ 2.2 ..... None .... 302 ...... None .... 75 kg 150 kg A ............1,2,3,6-Tetrahydrobenzaldehyde ..................................................................................................... 3 UN2498 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Tetrahydrofuran ............................................................................................................................... 3 UN2056 II 3 ........ IB2, T4, TP1 None .... 202 ...... 242 ...... 5 L 60 L B ............Tetrahydrofurfurylamine .................................................................................................................. 3 UN2943 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Tetrahydrophthalic anhydrides with more than 0.05 percent of maleic anhydride ......................... 8 UN2698 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

1,2,3,6-Tetrahydropyridine .............................................................................................................. 3 UN2410 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Tetrahydrothiophene ....................................................................................................................... 3 UN2412 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Tetramethylammonium hydroxide, solid ......................................................................................... 8 UN3423 II 8 ........ B2, IB8, IP2, IP4, 

T3, TP33

154 ...... 213 ...... 240 ...... 15 kg 50 kg A 52

Tetramethylammonium hydroxide solution ..................................................................................... 8 UN1835 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L A 52

.......................................................................................................................................................... .................... III 8 ........ B2, IB3, T7, TP2 154 ...... 203 ...... 241 ...... 5 L 60 L A 52

Tetramethylene diperoxide dicarbamide ......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetramethylsilane ............................................................................................................................ 3 UN2749 I 3 ........ A7, T14, TP2 None .... 201 ...... 243 ...... Forbidden 30 L D ............Tetranitro diglycerin ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetranitroaniline ............................................................................................................................... 1.1D UN0207 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

+ Tetranitromethane ........................................................................................................................... 5.1 UN1510 I 5.1, 

6.1.

2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP44

None .... 227 ...... None .... Forbidden Forbidden D 40, 66

2,3,4,6-Tetranitrophenol .................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............2,3,4,6-Tetranitrophenyl methyl nitramine ....................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,3,4,6-Tetranitrophenylnitramine .................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetranitroresorcinol (dry) ................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............2,3,5,6-Tetranitroso-1,4-dinitrobenzene .......................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,3,5,6-Tetranitroso nitrobenzene (dry) ........................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetrapropylorthotitanate .................................................................................................................. 3 UN2413 III 3 ........ B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Tetrazene, see Guanyl nitrosaminoguanyltetrazene ...................................................................... .................... ........... .......... .......... .......... .................... .................... ............Tetrazine (dry) ................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Tetrazol-1-acetic acid ...................................................................................................................... 1.4C UN0407 II 1.4C .. None .... 62 ........ None .... Forbidden 75 kg 09 ............1H-Tetrazole .................................................................................................................................... 1.1D UN0504 ............ 1.1D .. None .... 62 ........ None .... Forbidden Forbidden B 1E, 5E Tetrazolyl azide (dry) ....................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Tetryl, see Trinitrophenylmethylnitramine ....................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

A I W Textile waste, wet ............................................................................................................................ 4.2 UN1857 III 4.2 ..... 151 ...... 213 ...... 240 ...... Forbidden Forbidden A ............

Thallium chlorate ............................................................................................................................. 5.1 UN2573 II 5.1, 

6.1.

IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Thallium compounds, n.o.s. ............................................................................................................ 6.1 UN1707 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Thallium nitrate ................................................................................................................................ 6.1 UN2727 II 6.1, 

5.1.

IB6, IP2, T3, 

TP33

153 ...... 212 ...... 242 ...... 5 kg 25 kg A ............

4-Thiapentanal ................................................................................................................................. 6.1 UN2785 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L D 25, 49Thioacetic acid ................................................................................................................................ 3 UN2436 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Thiocarbamate pesticide, liquid, flammable, toxic, flash point less than 23 degrees C ................ 3 UN2772 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76141

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP13, 

TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Thiocarbamate pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C .......... 6.1 UN3005 I 6.1, 3 T14, TP2, TP13 None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Thiocarbamate pesticide, liquid, toxic ............................................................................................. 6.1 UN3006 I 6.1 ..... T14, TP2, TP13 None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Thiocarbamate pesticides, solid, toxic ............................................................................................ 6.1 UN2771 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Thiocarbonylchloride, see Thiophosgene ....................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Thioglycol ........................................................................................................................................ 6.1 UN2966 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Thioglycolic acid .............................................................................................................................. 8 UN1940 II 8 ........ A7, B2, IB2, 

N34, T7, TP2

154 ...... 202 ...... 242 ...... 1 L 30 L A ............

Thiolactic acid .................................................................................................................................. 6.1 UN2936 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Thionyl chloride ............................................................................................................................... 8 UN1836 I 8 ........ B6, B10, N34, 

T10, TP2, TP12, 

TP13

None .... 201 ...... 243 ...... Forbidden Forbidden C 40

Thiophene ........................................................................................................................................ 3 UN2414 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B 40

+ Thiophosgene .................................................................................................................................. 6.1 UN2474 II 6.1 ..... 2, B9, B14, B32, 

B74, N33, N34, 

T20, TP2, TP38, 

TP45

None .... 227 ...... 244 ...... Forbidden Forbidden B 40, 52

Thiophosphoryl chloride .................................................................................................................. 8 UN1837 II 8 ........ A3, A7, B2, B8, 

B25, IB2, N34, 

T7, TP2

None .... 202 ...... 242 ...... Forbidden 30 L C 40

Thiourea dioxide .............................................................................................................................. 4.2 UN3341 II 4.2 ..... IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg D ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg D ............

Tin chloride, fuming, see Stannic chloride, anhydrous ................................................................... .................... ........... .......... .......... .......... .................... .................... ............Tin perchloride or Tin tetrachloride, see Stannic chloride, anhydrous ........................................... .................... ........... .......... .......... .......... .................... .................... ............Tinctures, medicinal ........................................................................................................................ 3 UN1293 II 3 ........ IB2, T4, TP1, 

TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Tinning flux, see Zinc chloride ........................................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Titanium disulphide ......................................................................................................................... 4.2 UN3174 III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg A ............

Titanium hydride .............................................................................................................................. 4.1 UN1871 II 4.1 ..... A19, A20, IB4, 

N34, T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg E ............

Titanium powder, dry ....................................................................................................................... 4.2 UN2546 I 4.2 ..... None .... 211 ...... 242 ...... Forbidden Forbidden D ............

.......................................................................................................................................................... .................... II 4.2 ..... A19, A20, IB6, 

IP2, N5, N34, 

T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg D ............

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg D ............

Titanium powder, wetted with not less than 25 percent water (a visible excess of water must be 

present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns.

4.1 UN1352 II 4.1 ..... A19, A20, IB6, 

IP2, N34, T3, 

TP33

None .... 212 ...... 240 ...... 15 kg 50 kg E 74

Titanium sponge granules or Titanium sponge powders ................................................................ 4.1 UN2878 III 4.1 ..... A1, IB8, IP3, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg D 74

+ Titanium tetrachloride ...................................................................................................................... 8 UN1838 II 8, 6.1 2, B7, B9, B14, 

B32, B74, B77, 

T20, TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden C 40

Titanium trichloride mixtures ........................................................................................................... 8 UN2869 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A 40

.......................................................................................................................................................... .................... III 8 ........ A7, IB8, IP3, 

N34, T1, TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 40

Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric ................................. 4.2 UN2441 I 4.2, 8 N34 None .... 181 ...... 244 ...... Forbidden Forbidden D 40TNT mixed with aluminum, see Tritonal ......................................................................................... .................... ........... .......... .......... .......... .................... .................... ............TNT, see Trinitrotoluene, etc .......................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Toluene ............................................................................................................................................ 3 UN1294 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

+ Toluene diisocyanate ...................................................................................................................... 6.1 UN2078 II 6.1 ..... IB2, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 5 L 60 L D 25, 40

Toluene sulfonic acid, see Alkyl, or Aryl sulfonic acid etc .............................................................. .................... ........... .......... .......... .......... .................... .................... ............

+ Toluidines, liquid .............................................................................................................................. 6.1 UN1708 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

76142 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Toluidines, solid ............................................................................................................................... 6.1 UN3451 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

2,4-Toluylenediamine, solid or 2,4-Toluenediamine, solid .............................................................. 6.1 UN1709 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

2,4-Toluylenediamine solution or 2,4-Toluenediamine solution ...................................................... 6.1 UN3418 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Torpedoes, liquid fueled, with inert head ........................................................................................ 1.3J UN0450 II 1.3J ... .......... 62 ........ None .... Forbidden Forbidden 04 23E Torpedoes, liquid fueled, with or without bursting charge .............................................................. 1.1J UN0449 II 1.1J ... .......... 62 ........ None .... Forbidden Forbidden 04 23E Torpedoes with bursting charge ...................................................................................................... 1.1E UN0329 II 1.1E ... .......... 62 ........ None .... Forbidden Forbidden 03 ............Torpedoes with bursting charge ...................................................................................................... 1.1F UN0330 II 1.1F ... .......... 62 ........ None .... Forbidden Forbidden 08 ............Torpedoes with bursting charge ...................................................................................................... 1.1D UN0451 II 1.1D .. .......... 62 ........ None .... Forbidden Forbidden 03 ............

G Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and 

saturated vapor concentration greater than or equal to 500 LC50.

6.1 UN3381 I 6.1 ..... 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP27, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, n.o.s. with an inhalation toxicity toxicity lower than or equal to 1000 

ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

6.1 UN3382 I 6.1 ..... 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP27, 

TP38, TP4527, 

TP38, TP4513

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 

200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

6.1 UN3383 I 6.1, 3 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP27, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 

1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

6.1 UN3384 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP27, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 

200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

6.1 UN3385 I 6.1, 

4.3.

1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 

1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

6.1 UN3386 I 6.1, 

4.3.

2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP38, 

TP44

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 200 

ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

6.1 UN3387 I 6.1, 

5.1.

1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP38, 

TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 1000 

ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

6.1 UN3388 I 6.1, 

5.1.

2, B9, B14, B32, 

T20, TP2, TP13, 

TP38, TP44

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 200 

ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

6.1 UN3389 I 6.1, 8 1, B9, B14, B30, 

B72, T22, TP2, 

TP13, TP27, 

TP38, TP44

None .... 226 ...... 244 ...... Forbidden Forbidden D 40

G Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 

1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

6.1 UN3390 I 6.1, 8 2, B9, B14, B32, 

B74, T20, TP2, 

TP13, TP27, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

G Toxic liquid, corrosive, inorganic, n.o.s. .......................................................................................... 6.1 UN3289 I 6.1, 8 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L A ............

.......................................................................................................................................................... .................... II 6.1, 8 IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 1 L 30 L A ............

G Toxic liquid, inorganic, n.o.s. ........................................................................................................... 6.1 UN3287 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A ............

G Toxic liquids, corrosive, organic, n.o.s. ........................................................................................... 6.1 UN2927 I 6.1, 8 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 40

.......................................................................................................................................................... .................... II 6.1, 8 IB2, T11, TP2, 

TP27

153 ...... 202 ...... 243 ...... 1 L 30 L B 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76143

G Toxic liquids, flammable, organic, n.o.s. ......................................................................................... 6.1 UN2929 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

G Toxic, liquids, organic, n.o.s. ........................................................................................................... 6.1 UN2810 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP1, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

G Toxic liquids, oxidizing, n.o.s. ......................................................................................................... 6.1 UN3122 I 6.1, 

5.1.

A4 None .... 201 ...... 243 ...... Forbidden 2.5 L C ............

.......................................................................................................................................................... .................... II 6.1, 

5.1.

IB2 153 ...... 202 ...... 243 ...... 1 L 5 L C ............

G Toxic liquids, water-reactive, n.o.s. ................................................................................................. 6.1 UN3123 I 6.1, 

4.3.

A4 None .... 201 ...... 243 ...... Forbidden 1 L E 40

.......................................................................................................................................................... .................... II 6.1, 

4.3.

IB2 None .... 202 ...... 243 ...... 1 L 5 L E 40

G Toxic solid, corrosive, inorganic, n.o.s. ........................................................................................... 6.1 UN3290 I 6.1, 8 IB7, T6, TP33 None .... 211 ...... 242 ...... 1 kg 25 kg A ............

.......................................................................................................................................................... .................... II 6.1, 8 IB6, IP2, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg A ............

G Toxic solid, inorganic, n.o.s. ............................................................................................................ 6.1 UN3288 I 6.1 ..... IB7, T6, TP33 None .... 211 ...... 242 ...... 5 kg 50 kg A ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

G Toxic solids, corrosive, organic, n.o.s. ............................................................................................ 6.1 UN2928 I 6.1, 8 IB7, T6, TP33 None .... 211 ...... 242 ...... 1 kg 25 kg B 40

.......................................................................................................................................................... .................... II 6.1, 8 IB6, IP2, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg B 40

G Toxic solids, flammable, organic, n.o.s. .......................................................................................... 6.1 UN2930 I 6.1, 

4.1.

IB6, T6, TP33 None .... 211 ...... 242 ...... 1 kg 15 kg B ............

.......................................................................................................................................................... .................... II 6.1, 

4.1.

IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg B ............

G Toxic solids, organic, n.o.s. ............................................................................................................. 6.1 UN2811 I 6.1 ..... IB7, T6, TP33 None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

G Toxic solids, oxidizing, n.o.s. .......................................................................................................... 6.1 UN3086 I 6.1, 

5.1.

T6, TP33 None .... 211 ...... 242 ...... 1 kg 15 kg C ............

.......................................................................................................................................................... .................... II 6.1, 

5.1.

IB6, IP2, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg C ............

G Toxic solids, self-heating, n.o.s. ...................................................................................................... 6.1 UN3124 I 6.1, 

4.2.

A5, T6, TP33 None .... 211 ...... 242 ...... 5 kg 15 kg D 40

.......................................................................................................................................................... .................... II 6.1, 

4.2.

IB6, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg D 40

G Toxic solids, water-reactive, n.o.s. .................................................................................................. 6.1 UN3125 I 6.1, 

4.3.

A5, T6, TP33 None .... 211 ...... 242 ...... 5 kg 15 kg D 40

.......................................................................................................................................................... .................... II 6.1, 

4.3.

IB6, IP2, T3, 

TP33

153 ...... 212 ...... 242 ...... 15 kg 50 kg D 40

G Toxins, extracted from living sources, liquid, n.o.s. ........................................................................ 6.1 UN3172 I 6.1 ..... 141 None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... 141, IB2 None .... 202 ...... 243 ...... 5 L 60 L B 40.......................................................................................................................................................... .................... III 6.1 ..... 141, IB3 153 ...... 203 ...... 241 ...... 60 L 220 L B 40

Toxins, extracted from living sources, solid, n.o.s. ......................................................................... 6.1 UN3462 I 6.1 ..... 141, IB7, IP1, 

T6, TP33

None .... 211 ...... 243 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... 141, IB8, IP2, 

IP4, T3, TP33

None .... 212 ...... 243 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... 141, IB8, IP3, 

T1, TP33

153 ...... 213 ...... 241 ...... 100 kg 200 kg A ............

D Toy Caps ......................................................................................................................................... 1.4S NA0337 II 1.4S ... None .... 62 ........ None .... 25 kg 100 kg 05 ............

Tracers for ammunition ................................................................................................................... 1.3G UN0212 II 1.3G .. None .... 62 ........ None .... Forbidden Forbidden 07 ............Tracers for ammunition ................................................................................................................... 1.4G UN0306 II 1.4G .. None .... 62 ........ None .... Forbidden 75 kg 06 ............Tractors, see Vehicle, etc ............................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Tri-(b-nitroxyethyl) ammonium nitrate ............................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Triallyl borate ................................................................................................................................... 6.1 UN2609 III 6.1 ..... IB3 153 ...... 203 ...... 241 ...... 60 L 220 L A 13Triallylamine .................................................................................................................................... 3 UN2610 III 3, 8 .... B1, IB3, T4, TP1 None .... 203 ...... 242 ...... 5 L 60 L A 40Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C .......................... 3 UN2764 I 3, 6.1 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... Forbidden 30 L B 40

.......................................................................................................................................................... .................... II 3, 6.1 IB2, T11, TP2, 

TP13, TP27

150 ...... 202 ...... 243 ...... 1 L 60 L B 40

Triazine pesticides, liquid, toxic ...................................................................................................... 6.1 UN2998 I 6.1 ..... T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1 ..... IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

76144 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T7, TP2, 

TP28

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Triazine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C .................... 6.1 UN2997 I 6.1, 3 T14, TP2, TP13, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B 40

.......................................................................................................................................................... .................... II 6.1, 3 IB2, T11, TP2, 

TP13, TP27

153 ...... 202 ...... 243 ...... 5 L 60 L B 40

.......................................................................................................................................................... .................... III 6.1, 3 IB3, T7, TP2, 

TP28

153 ...... 203 ...... 242 ...... 60 L 220 L A 40

Triazine pesticides, solid, toxic ....................................................................................................... 6.1 UN2763 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 40

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A 40

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Tributylamine ................................................................................................................................... 6.1 UN2542 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Tributylphosphane ........................................................................................................................... 4.2 UN3254 I 4.2 ..... T21, TP7, TP33 None .... 211 ...... 242 ...... Forbidden Forbidden D 136Trichloro-s-triazinetrione dry, with more than 39 percent available chlorine, see

Trichloroisocyanuric acid, dry.

.................... ........... .......... .......... .......... .................... .................... ............

Trichloroacetic acid ......................................................................................................................... 8 UN1839 II 8 ........ A7, IB8, IP2, IP4, 

N34, T3, TP33

154 ...... 212 ...... 240 ...... 15 kg 50 kg A ............

Trichloroacetic acid, solution ........................................................................................................... 8 UN2564 II 8 ........ A3, A6, A7, B2, 

IB2, N34, T7, 

TP2

154 ...... 202 ...... 242 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... III 8 ........ A3, A6, A7, IB3, 

N34, T4, TP1

154 ...... 203 ...... 241 ...... 5 L 60 L B 8

+ Trichloroacetyl chloride ................................................................................................................... 8 UN2442 II 8, 6.1 2, B9, B14, B32, 

B74, N34, T20, 

TP2, TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 40

Trichlorobenzenes, liquid ................................................................................................................ 6.1 UN2321 III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............Trichlorobutene ................................................................................................................................ 6.1 UN2322 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 25, 401,1,1-Trichloroethane ...................................................................................................................... 6.1 UN2831 III 6.1 ..... IB3, N36, T4, 

TP1

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Trichloroethylene ............................................................................................................................. 6.1 UN1710 III 6.1 ..... IB3, N36, T4, 

TP1

153 ...... 203 ...... 241 ...... 60 L 220 L A 40

Trichloroisocyanuric acid, dry .......................................................................................................... 5.1 UN2468 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A 13

Trichloromethyl perchlorate ............................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Trichlorosilane ................................................................................................................................. 4.3 UN1295 I 4.3, 3, 

8.

N34, T14, TP2, 

TP7, TP13

None .... 201 ...... 244 ...... Forbidden Forbidden D 21, 28, 

40, 49, 

100

Tricresyl phosphate with more than 3 percent ortho isomer .......................................................... 6.1 UN2574 II 6.1 ..... A3, IB2, N33, 

N34, T7, TP2

153 ...... 202 ...... 243 ...... 5 L 60 L A ............

Triethyl phosphite ............................................................................................................................ 3 UN2323 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Triethylamine ................................................................................................................................... 3 UN1296 II 3, 8 .... IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40Triethylenetetramine ........................................................................................................................ 8 UN2259 II 8 ........ B2, IB2, T7, TP2 154 ...... 202 ...... 242 ...... 1 L 30 L B 40, 52Trifluoroacetic acid .......................................................................................................................... 8 UN2699 I 8 ........ A3, A6, A7, B4, 

N3, N34, N36, 

T10, TP2, TP12

None .... 201 ...... 243 ...... 0.5 L 2.5 L B 12, 40

Trifluoroacetyl chloride .................................................................................................................... 2.3 UN3057 ............ 2.3, 8 2, B7, B9, B14, 

T50, TP21

None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Trifluorochloroethylene, stabilized ................................................................................................... 2.3 UN1082 ............ 2.3, 

2.1.

3, B14, T50 None .... 304 ...... 314, 

315.

Forbidden Forbidden D 40

Trifluoromethane or Refrigerant gas R 23 ...................................................................................... 2.2 UN1984 ............ 2.2 ..... 306 ...... 304 ...... 314, 

315.

75 kg 150 kg A ............

1,1,1-Trifluoroethane or Refrigerant gas, R 143a ........................................................................... 2.1 UN2035 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Trifluoromethane, refrigerated liquid ............................................................................................... 2.2 UN3136 ............ 2.2 ..... T75, TP5 306 ...... None .... 314, 

315.

50 kg 500 kg D ............

2-Trifluoromethylaniline ................................................................................................................... 6.1 UN2942 III 6.1 ..... IB3 153 ...... 203 ...... 241 ...... 60 L 220 L A ............3-Trifluoromethylaniline ................................................................................................................... 6.1 UN2948 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A 40Triformoxime trinitrate ..................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Triisobutylene .................................................................................................................................. 3 UN2324 III 3 ........ B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Triisopropyl borate ........................................................................................................................... 3 UN2616 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76145

D Trimethoxysilane ............................................................................................................................. 6.1 NA9269 I 6.1, 3 2, B9, B14, B32, 

B74, T20, TP4, 

TP12, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden E 40

Trimethyl borate .............................................................................................................................. 3 UN2416 II 3 ........ IB2, T7, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Trimethyl phosphite ......................................................................................................................... 3 UN2329 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............1,3,5-Trimethyl-2,4,6-trinitrobenzene .............................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Trimethylacetyl chloride ................................................................................................................... 6.1 UN2438 I 6.1, 8, 

3.

2, B3, B9, B14, 

B32, B74, N34, 

T20, TP2, TP13, 

TP38, TP45

None .... 227 ...... 244 ...... Forbidden Forbidden D 25, 40

Trimethylamine, anhydrous ............................................................................................................. 2.1 UN1083 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Trimethylamine, aqueous solutions with not more than 50 percent trimethylamine by mass ....... 3 UN1297 I 3, 8 .... T11, TP1 None .... 201 ...... 243 ...... 0.5 L 2.5 L D 40, 135

.......................................................................................................................................................... .................... II 3, 8 .... B1, IB2, T7, TP1 150 ...... 202 ...... 243 ...... 1 L 5 L B 40, 41.......................................................................................................................................................... .................... III 3, 8 .... B1, IB3, T7, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A 40, 41

1,3,5-Trimethylbenzene ................................................................................................................... 3 UN2325 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Trimethylchlorosilane ....................................................................................................................... 3 UN1298 II 3, 8 .... A3, A7, B77, IB2, 

N34, T7, TP2, 

TP13

150 ...... 202 ...... 243 ...... 1 L 5 L E 40

Trimethylcyclohexylamine ............................................................................................................... 8 UN2326 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Trimethylene glycol diperchlorate ................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Trimethylhexamethylene diisocyanate ............................................................................................ 6.1 UN2328 III 6.1 ..... IB3, T4, TP2, 

TP13

153 ...... 203 ...... 241 ...... 60 L 220 L B ............

Trimethylhexamethylenediamines ................................................................................................... 8 UN2327 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Trimethylol nitromethane trinitrate ................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Trinitro-meta-cresol ......................................................................................................................... 1.1D UN0216 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E 2,4,6-Trinitro-1,3-diazobenzene ...................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,4,6-Trinitro-1,3,5-triazido benzene (dry) ....................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Trinitroacetic acid ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Trinitroacetonitrile ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Trinitroamine cobalt ......................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Trinitroaniline or Picramide ............................................................................................................. 1.1D UN0153 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitroanisole .................................................................................................................................. 1.1D UN0213 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrobenzene (picryl chloride), wetted, with not less than 10% water by mass ......................... 4.1 UN3365 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

Trinitrobenzene, wetted, with not less than 10% water, by mass .................................................. 4.1 UN3367 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

Trinitrobenzene, dry or wetted with less than 30 percent water, by mass ..................................... 1.1D UN0214 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrobenzene, wetted with not less than 30 percent water, by mass ......................................... 4.1 UN1354 I 4.1 ..... 23, A2, A8, A19, 

N41

None .... 211 ...... None .... 0.5 kg 0.5 kg E 28

Trinitrobenzenesulfonic acid ............................................................................................................ 1.1D UN0386 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E Trinitrobenzoic acid, dry or wetted with less than 30 percent water, by mass .............................. 1.1D UN0215 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrobenzoic acid, wetted with not less than 10% water by mass .............................................. 4.1 UN3368 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

Trinitrobenzoic acid, wetted with not less than 30 percent water, by mass ................................... 4.1 UN1355 I 4.1 ..... 23, A2, A8, A19, 

N41

None .... 211 ...... None .... 0.5 kg 0.5 kg E 28

Trinitrochlorobenzene or Picryl chloride .......................................................................................... 1.1D UN0155 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitroethanol .................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Trinitroethylnitrate ............................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Trinitrofluorenone ............................................................................................................................ 1.1D UN0387 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitromethane ............................................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............1,3,5-Trinitronaphthalene ................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Trinitronaphthalene .......................................................................................................................... 1.1D UN0217 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrophenetole .............................................................................................................................. 1.1D UN0218 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrophenol (picric acid), wetted, with not less than 10 percent water by mass ........................ 4.1 UN3364 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

Trinitrophenol or Picric acid, dry or wetted with less than 30 percent water, by mass ................. 1.1D UN0154 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E Trinitrophenol, wetted with not less than 30 percent water, by mass ............................................ 4.1 UN1344 I 4.1 ..... 23, A8, A19, N41 None .... 211 ...... None .... 1 kg 15 kg E 28, 362,4,6-Trinitrophenyl guanidine (dry) ................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............2,4,6-Trinitrophenyl nitramine .......................................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate (dry) ..................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Trinitrophenylmethylnitramine or Tetryl ........................................................................................... 1.1D UN0208 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitroresorcinol or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of 

alcohol and water, by mass.

1.1D UN0219 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E 

Trinitroresorcinol, wetted or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass. 1.1D UN0394 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 5E 2,4,6-Trinitroso-3-methyl nitraminoanisole ...................................................................................... Forbidden ........... .......... .......... .......... .................... .................... ............Trinitrotetramine cobalt nitrate ........................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Trinitrotoluene and Trinitrobenzene mixtures or TNT and trinitrobenzene mixtures or TNT and 

hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures.

1.1D UN0388 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............

Trinitrotoluene mixtures containing Trinitrobenzene and Hexanitrostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene. 1.1D UN0389 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrotoluene or TNT, dry or wetted with less than 30 percent water, by mass .......................... 1.1D UN0209 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Trinitrotoluene (TNT), wetted, with not less than 10 percent water by mass ................................ 4.1 UN3366 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

76146 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Trinitrotoluene, wetted with not less than 30 percent water, by mass ........................................... 4.1 UN1356 I 4.1 ..... 23, A2, A8, A19, 

N41

None .... 211 ...... None .... 0.5 kg 0.5 kg E 28

Tripropylamine ................................................................................................................................. 3 UN2260 III 3, 8 .... B1, IB3, T4, TP1 150 ...... 203 ...... 242 ...... 5 L 60 L A 40Tripropylene ..................................................................................................................................... 3 UN2057 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Tris-(1-aziridinyl)phosphine oxide, solution ..................................................................................... 6.1 UN2501 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

.......................................................................................................................................................... .................... III 6.1 ..... IB3, T4, TP1 153 ...... 203 ...... 241 ...... 60 L 220 L A ............

Tris, bis-bifluoroamino diethoxy propane (TVOPA) ........................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Tritonal ............................................................................................................................................. 1.1D UN0390 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 10 ............Tungsten hexafluoride ..................................................................................................................... 2.3 UN2196 ............ 2.3, 8 2 None .... 338 ...... None .... Forbidden Forbidden D 40Turpentine ....................................................................................................................................... 3 UN1299 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Turpentine substitute ....................................................................................................................... 3 UN1300 I 3 ........ T11, TP1, TP8, 

TP27

None .... 201 ...... 243 ...... 1 L 30 L B ............

.......................................................................................................................................................... .................... II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ...................................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Undecane ........................................................................................................................................ 3 UN2330 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Urea hydrogen peroxide .................................................................................................................. 5.1 UN1511 III 5.1, 8 A1, A7, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 13

Urea nitrate, dry or wetted with less than 20 percent water, by mass ........................................... 1.1D UN0220 II 1.1D .. 119 None .... 62 ........ None .... Forbidden Forbidden 10 ............Urea nitrate, wetted, with not less than 10 percent water by mass ............................................... 4.1 UN3370 I 4.1 ..... 162, A8, A19, 

N41, N84

None .... 211 ...... None .... 0.5 kg 0.5 kg E 36

Urea nitrate, wetted with not less than 20 percent water, by mass ............................................... 4.1 UN1357 I 4.1 ..... 23, 39, A8, A19, 

N41

None .... 211 ...... None .... 1 kg 15 kg E 28, 36

Urea peroxide, see Urea hydrogen peroxide .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Valeraldehyde .................................................................................................................................. 3 UN2058 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Valeric acid, see Corrosive liquids, n.o.s. ....................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Valeryl chloride ................................................................................................................................ 8 UN2502 II 8, 3 .... A3, A6, A7, B2, 

IB2, N34, T7, 

TP2

154 ...... 202 ...... 243 ...... 1 L 30 L C 40

Vanadium compound, n.o.s. ........................................................................................................... 6.1 UN3285 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg B ............

.......................................................................................................................................................... .................... II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg B ............

.......................................................................................................................................................... .................... III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A ............

Vanadium oxytrichloride .................................................................................................................. 8 UN2443 II 8 ........ A3, A6, A7, B2, 

B16, IB2, N34, 

T7, TP2

154 ...... 202 ...... 242 ...... Forbidden 30 L C 40

Vanadium pentoxide, non-fused form ............................................................................................. 6.1 UN2862 III 6.1 ..... IB8, IP3, T1,

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 40

Vanadium tetrachloride ................................................................................................................... 8 UN2444 I 8 ........ A3, A6, A7, B4, 

N34, T10, TP2

None .... 201 ...... 243 ...... Forbidden 2.5 L C 40

Vanadium trichloride ........................................................................................................................ 8 UN2475 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A 40

Vanadyl sulfate ................................................................................................................................ 6.1 UN2931 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Vehicle, flammable gas powered .................................................................................................... 9 UN3166 ............ 9 ........ 135, 157 220 ...... 220 ...... 220 ...... Forbidden No limit A ............Vehicle, flammable liquid powered ................................................................................................. 9 UN3166 ............ 9 ........ 135, 157 220 ...... 220 ...... 220 ...... No limit No limit A ............Very signal cartridge, see Cartridges, signal .................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Vinyl acetate, stabilized ................................................................................................................... 3 UN1301 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Vinyl bromide, stabilized ................................................................................................................. 2.1 UN1085 ............ 2.1 ..... T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Vinyl butyrate, stabilized ................................................................................................................. 3 UN2838 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Vinyl chloride, stabilized .................................................................................................................. 2.1 UN1086 ............ 2.1 ..... 21, B44, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Vinyl chloroacetate .......................................................................................................................... 6.1 UN2589 II 6.1, 3 IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Vinyl ethyl ether, stabilized ............................................................................................................. 3 UN1302 I 3 ........ A3, T11, TP2 None .... 201 ...... 243 ...... 1 L 30 L D ............Vinyl fluoride, stabilized ................................................................................................................... 2.1 UN1860 ............ 2.1 ..... 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg E 40

Vinyl isobutyl ether, stabilized ......................................................................................................... 3 UN1304 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............Vinyl methyl ether, stabilized .......................................................................................................... 2.1 UN1087 ............ 2.1 ..... B44, T50 306 ...... 304 ...... 314, 

315.

Forbidden 150 kg B 40

Vinyl nitrate polymer ........................................................................................................................ Forbidden ........... .......... .......... .......... .................... .................... ............Vinylidene chloride, stabilized ......................................................................................................... 3 UN1303 I 3 ........ T12, TP2, TP7 150 ...... 201 ...... 243 ...... 1 L 30 L E 40

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76147

Vinylpyridines, stabilized ................................................................................................................. 6.1 UN3073 II 6.1, 3, 

8.

IB1, T7, TP2, 

TP13

153 ...... 202 ...... 243 ...... 1 L 30 L B 40

Vinyltoluenes, stabilized .................................................................................................................. 3 UN2618 III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............Vinyltrichlorosilane, stabilized ......................................................................................................... 3 UN1305 I 3, 8 .... A3, A7, B6, N34, 

T11, TP2, TP13

None .... 201 ...... 243 ...... Forbidden 2.5 L B 40

Warheads, rocket with burster or expelling charge ........................................................................ 1.4D UN0370 II 1.4D .. None .... 62 ........ None .... Forbidden 75 kg 02 ............Warheads, rocket with burster or expelling charge ........................................................................ 1.4F UN0371 II 1.4F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Warheads, rocket with bursting charge .......................................................................................... 1.1D UN0286 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Warheads, rocket with bursting charge .......................................................................................... 1.2D UN0287 II 1.2D .. None .... 62 ........ None .... Forbidden Forbidden 03 ............Warheads, rocket with bursting charge .......................................................................................... 1.1F UN0369 II 1.1F ... None .... 62 ........ None .... Forbidden Forbidden 08 ............Warheads, torpedo with bursting charge ........................................................................................ 1.1D UN0221 II 1.1D .. None .... 62 ........ None .... Forbidden Forbidden 03 ............

G Water-reactive liquid, corrosive, n.o.s. ............................................................................................ 4.3 UN3129 I 4.3, 8 None .... 201 ...... 243 ...... Forbidden 1 L D ............

.......................................................................................................................................................... .................... II 4.3, 8 IB1 None .... 202 ...... 243 ...... 1 L 5 L E 85.......................................................................................................................................................... .................... III 4.3, 8 IB2 None .... 203 ...... 242 ...... 5 L 60 L E ............

G Water-reactive liquid, n.o.s. ............................................................................................................. 4.3 UN3148 I 4.3 ..... None .... 201 ...... 244 ...... Forbidden 1 L E 40

.......................................................................................................................................................... .................... II 4.3 ..... IB1 None .... 202 ...... 243 ...... 1 L 5 L E 40.......................................................................................................................................................... .................... III 4.3 ..... IB2 None .... 203 ...... 242 ...... 5 L 60 L E 40

G Water-reactive liquid, toxic, n.o.s. ................................................................................................... 4.3 UN3130 I 4.3, 

6.1.

A4 None .... 201 ...... 243 ...... Forbidden 1 L D ............

.......................................................................................................................................................... .................... II 4.3, 

6.1.

IB1 None .... 202 ...... 243 ...... 1 L 5 L E 85

.......................................................................................................................................................... .................... III 4.3, 

6.1.

IB2 None .... 203 ...... 242 ...... 5 L 60 L E 85

G Water-reactive solid, corrosive, n.o.s. ............................................................................................. 4.3 UN3131 I 4.3, 8 IB4, IP1, N40 None .... 211 ...... 242 ...... Forbidden 15 kg D ............

.......................................................................................................................................................... .................... II 4.3, 8 IB6, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg E 85

.......................................................................................................................................................... .................... III 4.3, 8 IB8, IP4, T1, 

TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg E 85

G Water-reactive solid, flammable, n.o.s. ........................................................................................... 4.3 UN3132 I 4.3, 

4.1.

IB4, N40 None .... 211 ...... 242 ...... Forbidden 15 kg D ............

.......................................................................................................................................................... .................... II 4.3, 

4.1.

IB4, T3, TP33 151 ...... 212 ...... 242 ...... 15 kg 50 kg E ............

.......................................................................................................................................................... .................... III 4.3, 

4.1.

IB6, T1, TP33 151 ...... 213 ...... 241 ...... 25 kg 100 kg E ............

G Water-reactive solid, n.o.s. .............................................................................................................. 4.3 UN2813 I 4.3 ..... IB4, N40 None .... 211 ...... 242 ...... Forbidden 15 kg E 40

.......................................................................................................................................................... .................... II 4.3 ..... IB7, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg E 40

.......................................................................................................................................................... .................... III 4.3 ..... IB8, IP4, T1, 

TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg E 40

G Water-reactive, solid, oxidizing, n.o.s. ............................................................................................ 4.3 UN3133 II 4.3, 

5.1.

None .... 214 ...... 214 ...... Forbidden Forbidden E 40

.......................................................................................................................................................... .................... III 4.3, 

5.1.

None .... 214 ...... 214 ...... Forbidden Forbidden E 40

G Water-reactive solid, self-heating, n.o.s. ......................................................................................... 4.3 UN3135 I 4.3, 

4.2.

N40 None .... 211 ...... 242 ...... Forbidden 15 kg E ............

.......................................................................................................................................................... .................... II 4.3, 

4.2.

IB5, IP2, T3, 

TP33

None .... 212 ...... 242 ...... 15 kg 50 kg E ............

.......................................................................................................................................................... .................... III 4.3, 

4.2.

IB8, IP4, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg E ............

G Water-reactive solid, toxic, n.o.s. .................................................................................................... 4.3 UN3134 I 4.3, 

6.1.

A8, IB4, IP1, 

N40

None .... 211 ...... 242 ...... Forbidden 15 kg D ............

.......................................................................................................................................................... .................... II 4.3, 

6.1.

IB5, IP2, T3, 

TP33

151 ...... 212 ...... 242 ...... 15 kg 50 kg E 85

.......................................................................................................................................................... .................... III 4.3, 

6.1.

IB8, IP4, T1, 

TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg E 85

Wheel chair, electric, see Battery powered vehicle or Battery powered equipment ...................... .................... ........... .......... .......... .......... .................... .................... ............White acid, see Hydrofluoric acid ................................................................................................... .................... ........... .......... .......... .......... .................... .................... ............

I White asbestos (chrysotile, actinolite, anthophyllite, tremolite) ...................................................... 9 UN2590 III 9 ........ 156, IB8, IP2, 

IP3, T1, TP33

155 ...... 216 ...... 240 ...... 200 kg 200 kg A 34, 40

Wood preservatives, liquid .............................................................................................................. 3 UN1306 II 3 ........ 149, IB2, T4, 

TP1, TP8

150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A 40

A I W Wool waste, wet .............................................................................................................................. 4.2 UN1387 III 4.2 ..... 151 ...... 213 ...... 240 ...... Forbidden Forbidden A ............

Xanthates ........................................................................................................................................ 4.2 UN3342 II 4.2 ..... IB6, IP2, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg D 40

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg D 40

Xenon .............................................................................................................................................. 2.2 UN2036 ............ 2.2 ..... 306 ...... 302 ...... None .... 75 kg 150 kg A ............Xenon, refrigerated liquid (cryogenic liquids) .................................................................................. 2.2 UN2591 ............ 2.2 ..... T75, TP5 320 ...... None .... None .... 50 kg 500 kg B ............Xylenes ............................................................................................................................................ 3 UN1307 II 3 ........ IB2, T4, TP1 150 ...... 202 ...... 242 ...... 5 L 60 L B ............

.......................................................................................................................................................... .................... III 3 ........ B1, IB3, T2, TP1 150 ...... 203 ...... 242 ...... 60 L 220 L A ............

Xylenols, solid ................................................................................................................................. 6.1 UN2261 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Xylenols, liquid ................................................................................................................................ 6.1 UN3430 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............Xylidines, liquid ................................................................................................................................ 6.1 UN1711 II 6.1 ..... IB2, T7, TP2 153 ...... 202 ...... 243 ...... 5 L 60 L A ............

76148 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

§ 172.101 HAZARDOUS

MATERIALS

TABLE

—Continued

Symbols Hazardous materials descriptions and proper shipping names Hazard class or Di- vision Identifica- tion Num- bers PG Label Codes Special provisions 

(§172.102) 

(8)

Packaging (§173.***) 

(9)

Quantity limitations 

(10)

Vessel stowage 

Exceptions Non- bulk Bulk Passenger aircraft/rail Cargo air- craft only Loca- tion Other 

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Xylidines, solid ................................................................................................................................. 6.1 UN3452 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Xylyl bromide, liquid ........................................................................................................................ 6.1 UN1701 II 6.1 ..... A3, A6, A7, IB2, 

N33, T7, TP2, 

TP13

None .... 340 ...... None .... Forbidden 60 L D 40

Xylyl bromide, solid ......................................................................................................................... 6.1 UN3417 II 6.1 ..... A3, A6, A7, IB8, 

IP2, IP4, N33, 

T3, TP33

None .... 340 ...... None .... 25 kg 100 kg B 40

p-Xylyl diazide ................................................................................................................................. Forbidden ........... .......... .......... .......... .................... .................... ............Zinc ammonium nitrite ..................................................................................................................... 5.1 UN1512 II 5.1 ..... IB8, IP4, T3, 

TP33

None .... 212 ...... 242 ...... 5 kg 25 kg E ............

Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc arsenite mixtures ................................. 6.1 UN1712 II 6.1 ..... IB8, IP2, IP4, T3, 

TP33

153 ...... 212 ...... 242 ...... 25 kg 100 kg A ............

Zinc ashes ....................................................................................................................................... 4.3 UN1435 III 4.3 ..... A1, A19, IB8, 

IP4, T1, TP33

151 ...... 213 ...... 241 ...... 25 kg 100 kg A ............

Zinc bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. ..................................................... .................... ........... .......... .......... .......... .................... .................... ............Zinc bromate ................................................................................................................................... 5.1 UN2469 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A 56, 58

Zinc chlorate .................................................................................................................................... 5.1 UN1513 II 5.1 ..... A9, IB8, IP2, IP4, 

N34, T3, TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 56, 58

Zinc chloride, anhydrous ................................................................................................................. 8 UN2331 III 8 ........ IB8, IP3, T1, 

TP33

None .... 213 ...... 240 ...... 25 kg 100 kg A ............

Zinc chloride, solution ..................................................................................................................... 8 UN1840 III 8 ........ IB3, T4, TP1 154 ...... 203 ...... 241 ...... 5 L 60 L A ............Zinc cyanide .................................................................................................................................... 6.1 UN1713 I 6.1 ..... IB7, IP1, T6, 

TP33

None .... 211 ...... 242 ...... 5 kg 50 kg A 52

Zinc dithionite or Zinc hydrosulfite .................................................................................................. 9 UN1931 III None IB8, IP3, T1, 

TP33

155 ...... 204 ...... 240 ...... 100 kg 200 kg A 49

Zinc ethyl, see Diethylzinc .............................................................................................................. .................... ........... .......... .......... .......... .................... .................... ............Zinc fluorosilicate ............................................................................................................................. 6.1 UN2855 III 6.1 ..... IB8, IP3, T1, 

TP33

153 ...... 213 ...... 240 ...... 100 kg 200 kg A 52

Zinc hydrosulfite, see Zinc dithionite ............................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Zinc muriate solution, see Zinc chloride, solution ........................................................................... .................... ........... .......... .......... .......... .................... .................... ............Zinc nitrate ....................................................................................................................................... 5.1 UN1514 II 5.1 ..... IB8, IP4, T3, 

TP33

152 ...... 212 ...... 240 ...... 5 kg 25 kg A ............

Zinc permanganate ......................................................................................................................... 5.1 UN1515 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg D 56, 58, 

138

Zinc peroxide ................................................................................................................................... 5.1 UN1516 II 5.1 ..... IB6, IP2, T3, 

TP33

152 ...... 212 ...... 242 ...... 5 kg 25 kg A 13, 52, 

66, 75

Zinc phosphide ................................................................................................................................ 4.3 UN1714 I 4.3, 

6.1.

A19, N40 None .... 211 ...... None .... Forbidden 15 kg E 40, 52, 

85

Zinc powder or Zinc dust ................................................................................................................ 4.3 UN1436 I 4.3, 

4.2.

A19, IB4, IP1, 

N40

None .... 211 ...... 242 ...... Forbidden 15 kg A 52, 53

.......................................................................................................................................................... .................... II 4.3, 

4.2.

A19, IB7, IP2, 

T3, TP33

None .... 212 ...... 242 ...... 15 kg 50 kg A 52, 53

.......................................................................................................................................................... .................... III 4.3, 

4.2.

IB8, IP4, T1, 

TP33

None .... 213 ...... 242 ...... 25 kg 100 kg A 52, 53

Zinc resinate .................................................................................................................................... 4.1 UN2714 III 4.1 ..... A1, IB6, T1, 

TP33

151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Zinc selenate, see Selenates or Selenites ..................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Zinc selenite, see Selenates or Selenites ....................................................................................... .................... ........... .......... .......... .......... .................... .................... ............Zinc silicofluoride, see Zinc fluorosilicate ........................................................................................ .................... ........... .......... .......... .......... .................... .................... ............Zirconium, dry, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns). 4.1 UN2858 III 4.1 ..... A1 151 ...... 213 ...... 240 ...... 25 kg 100 kg A ............Zirconium, dry, finished sheets, strip or coiled wire ....................................................................... 4.2 UN2009 III 4.2 ..... A1, A19 None .... 213 ...... 240 ...... 25 kg 100 kg D ............Zirconium hydride ............................................................................................................................ 4.1 UN1437 II 4.1 ..... A19, A20, IB4, 

N34, T3, TP33

None .... 212 ...... 240 ...... 15 kg 50 kg E ............

Zirconium nitrate .............................................................................................................................. 5.1 UN2728 III 5.1 ..... A1, A29, IB8, 

IP3, T1, TP33

152 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

Zirconium picramate, dry or wetted with less than 20 percent water, by mass ............................. 1.3C UN0236 II 1.3C .. None .... 62 ........ None .... Forbidden Forbidden 10 5E Zirconium picramate, wetted with not less than 20 percent water, by mass ................................. 4.1 UN1517 I 4.1 ..... 23, N41 None .... 211 ...... None .... 1 kg 15 kg D 28, 36Zirconium powder, dry ..................................................................................................................... 4.2 UN2008 I 4.2 ..... T21, TP7, TP33 None .... 211 ...... 242 ...... Forbidden Forbidden D ............

.......................................................................................................................................................... .................... II 4.2 ..... A19, A20, IB6, 

IP2, N5, N34, 

T3, TP33

None .... 212 ...... 241 ...... 15 kg 50 kg D ............

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76149

.......................................................................................................................................................... .................... III 4.2 ..... IB8, IP3, T1, 

TP33

None .... 213 ...... 241 ...... 25 kg 100 kg D ............

Zirconium powder, wetted with not less than 25 percent water (a visible excess of water must 

be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns.

4.1 UN1358 II 4.1 ..... A19, A20, IB6, 

IP2, N34, T3, 

TP33

None .... 212 ...... 241 ...... 15 kg 50 kg E 74

Zirconium scrap ............................................................................................................................... 4.2 UN1932 III 4.2 ..... IB8, IP3, N34, 

T1, TP33

None .... 213 ...... 240 ...... Forbidden Forbidden D ............

Zirconium suspended in a liquid ..................................................................................................... 3 UN1308 I 3 ........ None .... 201 ...... 243 ...... Forbidden Forbidden B ............

.......................................................................................................................................................... .................... II 3 ........ IB2 None .... 202 ...... 242 ...... 5 L 60 L B ...................................................................................................................................................................... .................... III 3 ........ B1, IB2 150 ...... 203 ...... 242 ...... 60 L 220 L B ............

Zirconium tetrachloride .................................................................................................................... 8 UN2503 III 8 ........ IB8, IP3, T1, 

TP33

154 ...... 213 ...... 240 ...... 25 kg 100 kg A ............

76150 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

BILLING CODE 4910–01–S

* * * * *

■ 10. In Appendix B to § 172.101, the 

List of Marine Pollutants is amended by 

removing three entries, revising one 

entry and adding one entry in 

appropriate alphabetical order to read as 

follows: 

Appendix B to § 172.101—List of 

Marine Pollutants.

* * * * *

LIST OF MARINE POLLUTANTS

S, M, P

(1) 

Marine Pollutant

(2) 

[Remove:] .. Diphenyl oxide and biphenyl 

phenyl ether mixtures 

Isoamyl mercaptan 

Pentanethiols 

Tetrachlorophenol 

[Revise:] 

PP .............. 2, 6-Di-tert-Butylphenol 

[Add:] 

*****

Chloropicrin 

*****

■ 11. In § 172.102:

■ a. Paragraphs (b)(3), (b)(4), (b)(7) and 

(b)(8) are revised and a new paragraph 

(b)(9) is added.

■ b. In paragraph (c)(1), Special 

Provisions 47, 135, and 137 are revised; 

Special Provisions 163, 164, 165, 166, 

167, 170 and 171 are added; and Special 

Provision 143 and 153 are removed.

■ c. In paragraph (c)(2), a new Special 

Provision A14 is added.

■ d. The introductory text of paragraph 

(c)(3) is revised; in paragraph (c)(3) 

Special Provision B69 is revised and 

paragraph (c)(4) is revised.

■ e. Paragraphs (c)(7)(viii) and (c)(8) are 

redesignated as paragraphs (c)(8) and 

(c)(9) respectively, the introductory 

paragraph of (c)(8) is revised, a new 

paragraph (c)(8)(ii) is added, Special 

Provisions TP3 and TP6 are revised and 

a new Special Provision TP32 and TP33 

are added.

■ f. Paragraph (c)(7) is revised.

The additions and revisions read as 

follows:

§ 172.102 Special provisions.

* * * * *

(b) * * *

(3) A code containing the letter ‘‘B’’

refers to a special provision that applies 

only to bulk packaging requirements. 

Unless otherwise provided in this 

subchapter, these special provisions do 

not apply to UN, IM Specification 

portable tanks or IBCs.

(4) A code containing the letters ‘‘IB’’

or ‘‘IP’’ refers to a special provision that 

applies only to transportation in IBCs.

* * * * *

(7) A code containing the letter ‘‘T’’

refers to a special provision which 

applies only to transportation in UN or 

IM Specification portable tanks. 

(8) A code containing the letters ‘‘TP’’

refers to a portable tank special 

provision for UN or IM Specification 

portable tanks that is in addition to 

those provided by the portable tank 

instructions or the requirements in part 

178 of this subchapter. 

(9) A code containing the letter ‘‘W’’

refers to a special provision that applies 

only to transportation by water. 

(c) * * * 

(1) * * * 

Code/Special Provisions

* * * * *

47 Mixtures of solids that are not 

subject to this subchapter and 

flammable liquids may be transported 

under this entry without first applying 

the classification criteria of Division 4.1, 

provided there is no free liquid visible 

at the time the material is loaded or at 

the time the packaging or transport unit 

is closed. Except when the liquids are 

fully absorbed in solid material 

contained in sealed bags, each 

packaging must correspond to a design 

type that has passed a leakproofness test 

at the Packing Group II level. Small 

inner packagings consisting of sealed 

packets containing less than 10 mL of a 

Class 3 liquid in Packing Group II or III 

absorbed into a solid material are not 

subject to this subchapter provided 

there is no free liquid in the packet.

* * * * *

135 The entries ‘‘Vehicle, 

flammable gas powered’’ or ‘‘Vehicle, 

flammable liquid powered,’’ as 

appropriate, must be used when internal 

combustion engines are installed in a 

vehicle. These entries include hybrid 

electric vehicles powered by both an 

internal combustion engine and 

batteries.

* * * * *

137 Cotton, dry; flax, dry; and sisal, 

dry are not subject to the requirements 

of this subchapter when they are baled 

in accordance with ISO 8115, ‘‘Cotton 

Bales—Dimensions and Density’’ (IBR, 

see § 171.7 of this subchapter) to a 

density of not less than 360 kg/m3 (22.1 

lb/ft3) for cotton, 400 kg/m3 (24.97 lb/

ft3) for flax and 620 kg/m3 (38.71 lb/ft3) 

for sisal and transported in a freight 

container or closed transport vehicle.

* * * * *

163 Substances must satisfactorily 

pass Test Series 8 of the UN Manual of 

Tests and Criteria, Part I, Section 18 

(IBR, see § 171.7 of this subchapter). 

164 Substances must not be 

transported under this entry unless 

approved by the Associate 

Administrator on the basis of the results 

of appropriate tests according to Part I 

of the UN Manual of Tests and Criteria 

(IBR, see § 171.7 of this subchapter). The 

material must be packaged so that the 

percentage of diluent does not fall 

below that stated in the approval at any 

time during transportation. 

165 These substances are 

susceptible to exothermic 

decomposition at elevated temperatures. 

Decomposition can be initiated by heat, 

moisture or by impurities (e.g., 

powdered metals (iron, manganese, 

cobalt, magnesium)). During the course 

of transportation, these substances must 

be shaded from direct sunlight and all 

sources of heat and be placed in 

adequately ventilated areas. 

166 When transported in non-friable 

tablet form calcium hypochlorite, dry or 

hydrated, may be transported as a 

Packing Group III material. 

167 These storage systems shall 

always be considered as containing 

hydrogen. 

170 Air must be eliminated from the 

vapor space by nitrogen or other means. 

171 This entry may only be used 

when the material is transported in nonfriable tablet form or for granular or 

powered mixtures that have been shown 

to meet the PG III criteria in § 173.127. 

(2) ‘‘A’’ codes. These provisions apply 

only to transportation by aircraft: 

Code/Special Provisions

* * * * *

A14 This material is not authorized 

to be transported as a limited quantity 

or consumer commodity in accordance 

with § 173.306 of this subchapter when 

transported aboard an aircraft.

* * * * *

(3) ‘‘B’’ codes. These provisions apply 

only to bulk packagings. Except as 

otherwise provided in this subchapter, 

these special provisions do not apply to 

UN portable tanks or IBCs: 

Code/Special Provisions

* * * * *

B69 Dry sodium cyanide or potassium 

cyanide may be shipped in sift-proof 

weather-resistant metal covered hopper 

cars, covered motor vehicles, portable 

tanks or non-specification bins. Bins 

must approved by the Associate 

Administrator.

* * * * *

(4) Table 1 and Table 2—IB Codes 

and IP Special IBC Packing Provisions.

These provisions apply only to

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76151

transportation in IBCs. When no IBC 

code is assigned in the § 172.101 Table 

for a specific proper shipping name, or 

in § 173.225(e) for Type F organic 

peroxides, an IBC may not be used 

unless authorized by the Associate 

Administrator. The letter ‘‘Z’’ shown in 

the marking code for composite IBCs 

must be replaced with a capital code 

letter designation found in 

§ 178.702(a)(2) of this subchapter to 

specify the material used for the outer 

packaging. Tables 1 and 2 follow:

TABLE 1.—IB CODES (IBC CODES) 

IBC Code Authorized IBCs 

IB1 ................ Authorized IBCs: Metal (31A, 31B and 31N). 

Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 

kPa at 55 °C (1.3 bar at 131 °F) are authorized. 

B2 ................. Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). 

Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 

130kPa at 55 °C (1.3 bar at 131 °F) are authorized. 

IB3 ................ Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 

31HD2 and 31HH2). 

Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 

kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 3 for UN2672). 

IB4 ................ Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N). 

IB5 ................ Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 

and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1). 

IB6 ................ Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 

and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). 

Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported 

may become liquid during transport. 

IB7 ................ Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 

and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F). 

Additional Requirement: Liners of wooden IBCs must be sift- proof. 

IB8 ................ Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 

and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); 

Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). 

IB9 ................ IBCs are only authorized if approved by the Associate Administrator. 

TABLE 2.—IP CODES

IBC Code Authorized IBCs 

IP1 ................ IBCs must be packed in closed freight containers or a closed transport vehicle. 

IP2 ................ When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container 

or a closed transport vehicle. 

IP3 ................ Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. 

IP4 ................ Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. 

IP5 ................ IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under 

maximum filling conditions. 

IP6 ................ Non-specification bulk bins are authorized. 

IP7 ................ For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet 

the IBC performance tests specified in part 178, subpart N of this subchapter. 

IP8 ................ Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully 

passed, without leakage or permanent deformation, the hydrostatic test specified in § 178.814 of this subchapter at a test 

pressure that is not less than 1.5 times the vapor pressure of the contents at 55 °C (131 °F). 

IP13 .............. Transportation by vessel in IBCs is prohibited. 

IP14 .............. Air shall be eliminated from the vapor space by nitrogen or other means. 

IP20 .............. Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in 

closed freight containers or transport vehicles. 

* * * * *

(7) ‘‘T’’ codes. (i) These provisions 

apply to the transportation of hazardous 

materials in UN portable tanks. Portable 

tank instructions specify the 

requirements applicable to a portable 

tank when used for the transportation of 

a specific hazardous material. These 

requirements must be met in addition to 

the design and construction 

specifications in part 178 of this 

subchapter. Portable tank instructions 

T1 through T22 specify the applicable 

minimum test pressure, the minimum 

shell thickness (in reference steel), 

bottom opening requirements and 

pressure relief requirements. Liquefied 

compressed gases are assigned to 

portable tank instruction T50. 

Refrigerated liquefied gases that are 

authorized to be transported in portable 

tanks are specified in tank instruction 

T75.

(ii) The following table specifies the 

portable tank requirements applicable to 

‘‘T’’ Codes T1 through T22. Column 1 

specifies the ‘‘T’’ Code. Column 2 

specifies the minimum test pressure, in 

bar (1 bar = 14.5 psig), at which the 

periodic hydrostatic testing required by 

§ 180.605 of this subchapter must be 

conducted. Column 3 specifies the 

section reference for minimum shell 

thickness or, alternatively, the 

minimum shell thickness value. Column 

4 specifies the applicability of 

§ 178.275(g)(3) of this subchapter for the 

pressure relief devices. When the word 

‘‘Normal’’ is indicated, § 178.275(g)(3) of 

this subchapter does not apply. Column 

5 references the applicable requirements 

for bottom openings in part 178 of this 

76152 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

subchapter or references ‘‘Prohibited’’ which means bottom openings are 

prohibited. The table follows:

TABLE OF PORTABLE TANK T CODES T1–T22 

[Portable tank codes T1–T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.] 

Portable tank instruction

(1) 

Minimum test pressure (bar)

(2) 

Minimum shell thickness (in 

mm-reference steel)

(See § 178.274(d))

(3) 

Pressure-relief requirements

(See § 178.275(g))

(4) 

Bottom opening requirements

(See § 178.275(d))

(5) 

T1 ..................... 1.5 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(2)0

T2 ..................... 1.5 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(3) 

T3 ..................... 2.65 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(2) 

T4 ..................... 2.65 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(3) 

T5 ..................... 2.65 § 178.274(d)(2) § 178.275(g)(3) ................................................... Prohibited 

T6 ..................... 4 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(2) 

T7 ..................... 4 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(3) 

T8 ..................... 4 § 178.274(d)(2) Normal ................................................................ Prohibited 

T9 ..................... 4 6 mm Normal ................................................................ Prohibited 

T10 ................... 4 6 mm § 178.275(g)(3) ................................................... Prohibited 

T11 ................... 6 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(3) 

T12 ................... 6 § 178.274(d)(2) § 178.275(g)(3) ................................................... § 178.275(d)(3) 

T13 ................... 6 6 mm Normal ................................................................ Prohibited 

T14 ................... 6 6 mm § 178.275(g)(3) ................................................... Prohibited 

T15 ................... 10 § 178.274(d)(2) Normal ................................................................ § 178.275(d)(3) 

T16 ................... 10 § 178.274(d)(2) § 178.275(g)(3) ................................................... § 178.275(d)(3) 

T17 ................... 10 6 mm Normal ................................................................ § 178.275(d)(3) 

T18 ................... 10 6 mm § 178.275(g)(3) ................................................... § 178.275(d)(3) 

T19 ................... 10 6 mm § 178.275(g)(3) ................................................... Prohibited 

T20 ................... 10 8 mm § 178.275(g)(3) ................................................... Prohibited 

T21 ................... 10 10 mm Normal ................................................................ Prohibited 

T22 ................... 10 10 mm § 178.275(g)(3) ................................................... Prohibited 

(iii) T50. When portable tank 

instruction T50 is referenced in Column 

(7) of the § 172.101 Table, the applicable 

liquefied compressed gases are 

authorized to be transported in portable 

tanks in accordance with the 

requirements of § 173.313 of this 

subchapter. 

(iv) T75. When portable tank 

instruction T75 is referenced in Column 

(7) of the § 172.101 Table, the applicable 

refrigerated liquefied gases are 

authorized to be transported in portable 

tanks in accordance with the 

requirements of § 178.277 of this 

subchapter. 

(v) UN and IM portable tank codes/

special provisions. When a specific 

portable tank instruction is specified by 

a ‘‘T’’ Code in Column (7) of the 

§ 172.101 Table for a specific hazardous 

material, a specification portable tank 

conforming to an alternative tank 

instruction may be used if: 

(A) The alternative portable tank has 

a higher or equivalent test pressure (for 

example, 4 bar when 2.65 bar is 

specified); 

(B) The alternative portable tank has 

greater or equivalent wall thickness (for 

example, 10 mm when 6 mm is 

specified); 

(C) The alternative portable tank has 

a pressure relief device as specified in 

the ‘‘T’’ Code. If a frangible disc is 

required in series with the reclosing 

pressure relief device for the specified 

portable tank, the alternative portable 

tank must be fitted with a frangible disc 

in series with the reclosing pressure 

relief device; and

(D) With regard to bottom openings—

(1) When two effective means are 

specified, the alternative portable tank 

is fitted with bottom openings having 

two or three effective means of closure 

or no bottom openings; or 

(2) When three effective means are 

specified, the portable tank has no 

bottom openings or three effective 

means of closure; or 

(3) When no bottom openings are 

authorized, the alternative portable tank 

must not have bottom openings. 

(vi) Except when an organic peroxide 

is authorized under § 173.225(g), if a 

hazardous material is not assigned a 

portable tank ‘‘T’’ Code, the hazardous 

material may not be transported in a 

portable tank unless approved by the 

Associate Administrator. 

(8) ‘‘TP’’ codes. (i) These provisions 

apply to the transportation of hazardous 

materials in IM and UN Specification 

portable tanks. Portable tank special 

provisions are assigned to certain 

hazardous materials to specify 

requirements that are in addition to 

those provided by the portable tank 

instructions or the requirements in part 

178 of this subchapter. Portable tank 

special provisions are designated with 

the abbreviation TP (tank provision) and 

are assigned to specific hazardous 

materials in Column (7) of the § 172.101 

Table. 

(ii) The following is a list of the 

portable tank special provisions:

* * * * *

Code/Special Provisions

* * * * *

TP3 The maximum degree of filling 

(in %) for solids transported above their 

melting points and for elevated 

temperature liquids shall be determined 

by the following:

Degree of filling = 95 dr

df









⋅

Where: df and dr are the mean 

densities of the liquid at the mean 

temperature of the liquid during filling 

and the maximum mean bulk 

temperature during transport 

respectively.

* * * * *

TP6 The tank must be equipped with 

a pressure release device which prevent 

a tank from bursting under fire 

engulfment conditions (the conditions 

prescribed in CGA pamphlet S–1.2 (see 

§ 171.7 of this subchapter) or alternative 

conditions approved by the Associate 

Administrator may be used to consider 

the fire engulfment condition), taking 


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into account the properties of the 

hazardous material to be transported.

* * * * *

TP32 Portable tanks may be used 

subject to the following conditions: 

a. Each portable tank constructed of 

metal must be fitted with a pressurerelief device consisting of a reclosing 

spring loaded type, a frangible disc or a 

fusible element. The set to discharge for 

the spring loaded pressure relief device 

and the burst pressure for the frangible 

disc, as applicable, must not be greater 

than 2.65 bar for portable tanks with 

minimum test pressures greater than 4 

bar;

b. The suitability for transport in 

tanks must be demonstrated using test 

8(d) in Test Series 8 (see UN Manual of 

Tests and Criteria, Part 1, Sub-section 

18.7) (IBR, see § 171.7 of this 

subchapter) or an alternative means 

approved by the Associate 

Administrator. 

TP33 The portable tank instruction 

assigned for this substance applies for 

granular and powdered solids and for 

solids which are filled and discharged at 

temperatures above their melting point 

which are cooled and transported as a 

solid mass. Solid substances transported 

or offered for transport above their 

melting point are authorized for 

transportation in portable tanks 

conforming to the provisions of portable 

tank instruction T4 for solid substances 

of packing group III or T7 for solid 

substances of packing group II, unless a 

tank with more stringent requirements 

for minimum shell thickness, maximum 

allowable working pressure, pressurerelief devices or bottom outlets are 

assigned in which case the more 

stringent tank instruction and special 

provisions shall apply. Filling limits 

must be in accordance with portable 

tank special provision TP3. Solids 

meeting the definition of an elevated 

temperature material must be 

transported in accordance with the 

applicable requirements of this 

subchapter.

* * * * *

■ 12. In § 172.202, paragraphs (a)(2)(iii) 

and (a)(5)(i) are revised to read as 

follows:

§ 172.202 Description of hazardous 

material on shipping papers. 

(a) * * * 

(2) * * * 

(iii) For domestic shipments, primary 

and subsidiary hazard class or division 

names may be entered following the 

numerical hazard class or division, or 

following the basic description. 

(5) * * * 

(i) For Class I materials, the quantity 

must be the net explosive mass. For an 

explosive that is an article, such as 

Cartridges, small arms, the net explosive 

mass may be expressed in terms of the 

net mass of either the article or the 

explosive materials contained in the 

article.

* * * * *

■ 13. In § 172.203, paragraphs (f), (m)(2) 

and (o)(3) are revised and a new 

paragraph (i)(3) is added to read as 

follows:

§ 172.203 Additional description 

requirements.

* * * * *

(f) Transportation by air. A statement 

indicating that the shipment is within 

the limitations prescribed for either 

passenger and cargo aircraft or cargo 

aircraft only must be entered on the 

shipping paper.

* * * * *

(i) * * * 

(3) For a hazardous material 

consigned under an ‘‘n.o.s.’’ entry not 

included in the segregation groups 

listed in section 3.1.4 of the IMDG Code 

but belonging, in the opinion of the 

consignor, to one of these groups, the 

appropriate segregation group must be 

shown in association with the basic 

description (for example, IMDG Code 

segregation group—1 Acids). When no 

segregation group is applicable, there is 

no requirement to indicate that 

condition.

* * * * *

(m) * * * 

(2) For materials that are poisonous by 

inhalation (see § 171.8 of this 

subchapter), the words ‘‘PoisonInhalation Hazard’’ or ‘‘Toxic-Inhalation 

Hazard’’ and the words ‘‘Zone A’’, 

‘‘Zone B’’, ‘‘Zone C’’, or ‘‘Zone D’’, for 

gases or ‘‘Zone A’’ or ‘‘Zone B’’ for 

liquids, as appropriate, must be entered 

on the shipping description. The word 

‘‘Poison’’ or ‘‘Toxic’’ or the phrase 

‘‘Poison-Inhalation Hazard’’ or ‘‘Toxic 

Inhalation Hazard’’ need not be repeated 

if it otherwise appears in the shipping 

description.

* * * * *

(o) * * * 

(3) The word ‘‘SAMPLE’’ must be 

included in association with the basic 

description when a sample of a Division 

4.1 (self-reactive) material (see 

§ 173.224(c)(3) of this subchapter) or 

Division 5.2 (organic peroxide) material 

(see § 173.225(b)(2) of this subchapter) 

is offered for transportation.

■ 14. In § 172.204, paragraph (c)(3) is 

revised to read as follows:

§ 172.204 Shipper’s certification.

* * * * *

(c) * * * 

(3) Additional certification 

requirements. Effective October 1, 2006, 

each person who offers a hazardous 

material for transportation by air must 

add to the certification required in this 

section the following statement: 

‘‘I declare that all of the applicable air 

transport requirements have been met.’’

(i) Each person who offers any 

package or overpack of hazardous 

materials for transport by air must 

ensure that: 

(A) The articles or substances are not 

prohibited for transport by air (see the 

§ 172.101 Table); 

(B) The articles or substances are 

properly classed, marked and labeled 

and otherwise in a condition for 

transport as required by this subchapter; 

(C) The articles or substances are 

packaged in accordance with all the 

applicable air transport requirements, 

including appropriate types of 

packaging that conform to the packing 

requirements and the ‘‘A’’ Special 

Provisions in § 172.102; inner packaging 

and maximum quantity per package 

limits; the compatibility requirements 

(see, for example, § 173.24 of this 

subchapter); and requirements for 

closure for both inner and outer 

packagings, absorbent materials, and 

pressure differential in § 173.27 of this 

subchapter. Other requirements may 

also apply. For example, single 

packagings may be prohibited, inner 

packaging may need to be packed in 

intermediate packagings, and certain 

materials may be required to be 

transported in packagings meeting a 

more stringent performance level. 

(ii) [Reserved]

* * * * *

■ 14a. The introductory text of § 172.315 

is revised to read as follows:

§ 172.315 Packages containing limited 

quantities. 

Except for transportation by aircraft or 

as otherwise provided in this 

subchapter, a package containing a 

limited quantity of hazardous materials 

is not required to be marked with the 

proper shipping name provided it is 

marked with the identification (ID) 

number, preceded by the letters ‘‘UN’’

or ‘‘NA,’’ as applicable, for the entry as 

shown in the § 172.101 Table, and 

placed within a square-on-point border 

in accordance with the following:

* * * * *

■ 15. A new § 172.317 is added to read 

as follows:

§ 172.317 KEEP AWAY FROM HEAT 

handling mark. 

(a) General. For transportation by 

aircraft, each package containing selfVerDate jul<14>2003 19:42 Dec 17, 2004 Jkt 205001 PO 00000 Frm 00111 Fmt 4701 Sfmt 4700 E:\FR\FM\20DER2.SGM 20DER2
76154 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

reactive substances of Division 4.1 or 

organic peroxides of Division 5.2 must 

be marked with the KEEP AWAY FROM 

HEAT handling mark specified in this 

section. 

(b) Location and design. The marking 

must be a rectangle measuring at least 

105 mm (4.1 inches) in height by 74 mm 

(2.9 inches) in width. Markings with not 

less than half this dimension are 

permissible where the dimensions of the 

package can only bear a smaller mark. 

(c) KEEP AWAY FROM HEAT 

handling mark. The KEEP AWAY 

FROM HEAT handling mark must 

conform to the following: 

(1) Except for size, the KEEP AWAY 

FROM HEAT handling mark must 

appear as follows: 

BILLING CODE 4910–60–U

(2) The symbol, letters and border 

must be black and the background 

white, except for the starburst which 

must be red. 

(3) The KEEP AWAY FROM HEAT 

handling marking required by paragraph 

(a) of this section must be durable, 

legible and displayed on a background 

of contrasting color.

§ 172.321 [Removed]

■ 16. Section 172.321 is removed.

PART 173—SHIPPERS—GENERAL 

REQUIREMENTS FOR SHIPMENTS 

AND PACKAGINGS

■ 17. The authority citation for part 173 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127, 44701; 49 

CFR 1.45, 1.53.

■ 18. In § 173.3, paragraph (c) 

introductory text is revised to read as 

follows:

§ 173.3 Packaging and exceptions.

* * * * *

(c) Salvage drums. During 

transportation, as defined in 49 U.S.C. 

5102(12), damaged or defective 

hazardous materials packages, 

hazardous materials packages that are 

found not to conform with the 

requirements of this subchapter, leaking 

hazardous materials packages, or 

hazardous materials that have spilled or 

leaked may be placed for repackaging or 

disposal in a metal or plastic removable 

head salvage drum that is compatible 

with the lading under the following 

conditions:

* * * * *

■ 19. In § 173.24, paragraphs (g) and (i) 

are revised to read as follows:

§ 173.24 General requirements for 

packagings and packages.

* * * * *

(g) Venting. Venting of packagings, to 

reduce internal pressure which may 

develop by the evolution of gas from the 

contents, is permitted only when—

(1) Transportation by aircraft is not 

involved; 

(2) Except as otherwise provided in 

this subchapter, the evolved gases are 

not poisonous, likely to create a 

flammable mixture with air or be an 

asphyxiant under normal conditions of 

transportation; 

(3) The packaging is designed so as to 

preclude an unintentional release of 

hazardous materials from the receptacle; 

(4) For bulk packagings, other than 

IBCs, venting is authorized for the 

specific hazardous material by a special 

provision in the § 172.101 table or by 

the applicable bulk packaging 

specification in part 178 of this 

subchapter; and 

(5) Intermediate bulk packagings 

(IBCs) may be vented when required to 

reduce internal pressure that may 

develop by the evolution of gas subject 

to the requirements of paragraphs (g)(1) 

through (g)(3) of this section. The IBC 


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must be of a type that has successfully 

passed (with the vent in place) the 

applicable design qualification tests 

with no release of hazardous material.

* * * * *

(i) Air transportation. Packages 

offered or intended for transportation by 

aircraft are subject to requirements 

additional to those of other modes of 

transport (e.g., quantity limitations, 

requirements for absorbent material, 

pressure differential requirements, 

appropriate closure procedures, and 

specific packaging requirements) and 

must conform to the general 

requirements for transportation by 

aircraft in § 173.27.

■ 20. In § 173.25, paragraphs (a)(2) and 

(a)(4) are revised to read as follows:

§ 173.25 Authorized packagings and 

overpacks. 

(a) * * *

* * * * *

(2) The overpack is marked with the 

proper shipping name and identification 

number, when applicable, and is labeled 

as required by this subchapter for each 

hazardous material contained therein, 

unless marking and labels 

representative of each hazardous 

material in the overpack are visible.

* * * * *

(4) The overpack is marked with the 

word ‘‘OVERPACK’’ when specification 

packagings are required, unless 

specification markings on the inside 

packages are visible. Alternatively, until 

October 1, 2007, the overpack may be 

marked with a statement indicating that 

the ‘‘inside (inner) packages comply 

with prescribed specifications.’’

* * * * *

■ 21. In § 173.27, paragraph (i) is revised 

to read as follows:

§ 173.27 General requirements for 

transportation by aircraft.

* * * * *

(i) Effective October 1, 2006, each 

person who offers a hazardous material 

for transportation by aircraft must 

include the certification statement 

specified in § 172.204(c)(3).

■ 22. In § 173.28, paragraph (c)(2) 

introductory text is revised to read as 

follows:

§ 173.28 Reuse, reconditioning and 

remanufacture of packagings.

* * * * *

(c) * * *

(2) For the purpose of this subchapter, 

reconditioning of a non-bulk packaging 

other than a metal drum includes:

* * * * *

■ 23. In § 173.115, a new paragraph (k) 

is added to read as follows:

§ 173.115 Class 2, Division 2.1, 2.2 and 

2.3—Definitions.

* * * * *

(k) The following applies to aerosols 

(see § 171.8 of this subchapter): 

(1) An aerosol must be assigned to 

Division 2.1 if the contents include 85% 

by mass or more flammable components 

and the chemical heat of combustion is 

30 kJ/g or more; 

(2) An aerosol must be assigned to 

Division 2.2 if the contents contain 1% 

by mass or less flammable components 

and the heat of combustion is less than 

20 kJ/g. 

(3) Aerosols not meeting the 

provisions of paragraphs (a) or (b) of this 

section must be classed in accordance 

with the appropriate tests of the UN 

Manual of Tests and Criteria (IBR, see 

§ 171.7 of this subchapter). 

(4) Division 2.3 gases may not be 

transported in an aerosol container. 

(5) When the contents are classified as 

Division 6.1 or Class 8, PG III, the 

aerosol must be assigned a subsidiary 

hazard of Division 6.1 or Class 8. 

(6) Substances of Division 6.1, PG I or 

II, and substances of Class 8, PG I are 

forbidden from transportation in an 

aerosol container. 

(7) Flammable components are Class 

3 flammable liquids, Class 4.1 

flammable solids, or Division 2.1 

flammable gases. The chemical heat of 

combustion must be determined in 

accordance with the UN Manual of 

Tests and Criteria (IBR, see § 171.7 of 

this subchapter).

■ 24. In § 173.128, paragraph (d)(1) is 

revised to read as follows:

§ 173.128 Class 5, Division 5.2—

Definitions and types.

* * * * *

(d) Approvals. (1) An organic 

peroxide must be approved, in writing, 

by the Associate Administrator, before 

being offered for transportation or 

transported, including assignment of a 

generic type and shipping description, 

except for—

(i) An organic peroxide which is 

identified by technical name in the 

Organic Peroxides Table in § 173.225(c); 

(ii) A mixture of organic peroxides 

prepared according to § 173.225(b); or 

(iii) An organic peroxide which may 

be shipped as a sample under the 

provisions of § 173.225(b).

* * * * *

■ 25. In 173.132, paragraph (b)(1) is 

revised to read as follows:

§ 173.132 Class 6, Division 6.1—

Definitions.

* * * * *

(b) * * * 

(1) LD50 (median lethal dose) for acute 

oral toxicity is the statistically derived 

single dose of a substance that can be 

expected to cause death within 14 days 

in 50% of young adult albino rats when 

administered by the oral route. The LD50

value is expressed in terms of mass of 

test substance per mass of test animal 

(mg/kg).

* * * * *

■ 26. In § 173.136, paragraph (d) is added 

to read as follows:

§ 173.136 Class 8—Definitions.

* * * * *

(d) Steel or aluminum corrosion test 

data produced no later than September 

30, 2005, using the procedures of 

§ 173.137(c)(2), in effect on September 

30, 2004 (see 49 CFR 173.137 revised as 

of October 1, 2003), for appropriate steel 

or aluminum types may be used for 

classification and assignment of packing 

group for Class 8 materials corrosive to 

steel or aluminum.

■ 27. In § 173.137, paragraph (c)(2) is 

revised to read as follows:

§ 173.137 Class 8—Assignment of packing 

group.

* * * * *

(c) * * *

* * * * *

(2) That do not cause full thickness 

destruction of intact skin tissue but 

exhibit a corrosion on steel or 

aluminum surfaces exceeding 6.25 mm 

(0.25 inch) a year at a test temperature 

of 55 °C (130 °F). The corrosion must be 

determined in accordance with the UN 

Manual of Tests and Criteria (IBR, see 

§ 171.7 of this subchapter).

■ 28. In § 173.150, paragraph (a), the 

introductory text of paragraph (b), 

paragraph (b)(2) and paragraph (c) are 

revised to read as follows:

§ 173.150 Exceptions for Class 3 

(flammable) and combustible liquids. 

(a) General. Exceptions for hazardous 

materials shipments in the following 

paragraphs are permitted only if this 

section is referenced for the specific 

hazardous material in the § 172.101 

Table of this subchapter. 

(b) Limited quantities. Limited 

quantities of flammable liquids (Class 3) 

and combustible liquids are excepted 

from labeling requirements, unless the 

material also meets the definition of 

Division 6.1 or is offered for 

transportation or transported by aircraft, 

and the specification packaging 

requirements of this subchapter when 

packaged in combination packagings 

according to this paragraph. In addition, 

shipments of limited quantities are not 

subject to subpart F (Placarding) of part 

172 of this subchapter. Each package 

must conform to the packaging 

76156 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

requirements of subpart B of this part 

and may not exceed 30 kg (66 pounds) 

gross weight. The following 

combination packagings are authorized:

* * * * *

(2) For flammable liquids in Packing 

Group II, inner packagings not over 1.0 

L (0.3 gallons) net capacity each, unless 

the material has a subsidiary hazard of 

Division 6.1, Packing Group II, in which 

case the inner packagings may not 

exceed 100 mL (3.38 ounces) net 

capacity each, packed in a strong outer 

packaging.

* * * * *

(c) Consumer commodities. Except for 

a material that has a subsidiary hazard 

of Division 6.1, Packing Group II, a 

limited quantity which conforms to the 

provisions of paragraph (b) of this 

section and is a ‘‘consumer commodity’’

as defined in 171.8 of this subchapter, 

may be renamed ‘‘Consumer 

commodity’’ and reclassed as ORM–D 

material. In addition to the exceptions 

provided by paragraph (b) of this 

section, shipments of ORM–D materials 

are not subject to the shipping paper 

requirements of subpart C of part 172 of 

this subchapter, unless the material 

meets the definition of a hazardous 

substance, hazardous waste, marine 

pollutant, or are offered for 

transportation and transported by 

aircraft, and are eligible for the 

exceptions provided in § 173.156.

* * * * *

■ 29. In 173.151, paragraphs (b) and (c), 

and the introductory text of paragraph 

(d) are revised to read as follows:

§ 173.151 Exceptions for Class 4.

* * * * *

(b) Limited quantities of Division 4.1.

Limited quantities of flammable solids 

(Division 4.1) in Packing Group II or III 

are excepted from labeling 

requirements, unless the material also 

meets the definition of Division 6.1 or 

is offered for transportation or 

transported by aircraft, and the 

specification packaging requirements of 

this subchapter when packaged in 

combination packagings according to 

this paragraph. In addition, shipments 

of limited quantities are not subject to 

subpart F (Placarding) of part 172 of this 

subchapter. Each package must conform 

to the packaging requirements of 

subpart B of this part and may not 

exceed 30 kg (66 pounds) gross weight. 

The following combination packagings 

are authorized: 

(1) For flammable solids in Packing 

Group II, inner packagings not over 1.0 

kg (2.2 pounds) net capacity each, 

unless the material has a subsidiary 

hazard of Division 6.1, Packing Group II, 

in which case the inner packagings may 

not exceed 0.5 kg (1.1 pounds) net 

capacity each, packed in a strong outer 

packaging. 

(2) For flammable solids in Packing 

Group III, inner packagings not over 5.0 

kg (11 pounds) net capacity each, 

packed in a strong outer packaging. 

(c) Consumer commodities. Except for 

a material that has a subsidiary hazard 

of Division 6.1, Packing Group II, a 

limited quantity which conforms to the 

provisions of paragraph (b) of this 

section, and charcoal briquettes in 

packagings not exceeding 30 kg (66 

pounds) gross weight, may be renamed 

‘‘Consumer commodity’’ and reclassed 

as ORM–D material if the material is a 

‘‘consumer commodity’’ as defined in 

171.8 of this subchapter. In addition to 

the exceptions provided by paragraph 

(b) of this section, shipments of ORM–

D materials are not subject to the 

shipping paper requirements of subpart 

C of part 172 of this subchapter, unless 

the material meets the definition of a 

hazardous substance, hazardous waste, 

marine pollutant, or is offered for 

transportation and transported by 

aircraft, and are eligible for the 

exceptions provided in § 173.156. 

(d) Limited quantities of Division 4.3.

Limited quantities of dangerous when 

wet (Division 4.3) solids in Packing 

Group II or III are excepted from 

labeling requirements, unless the 

material also meets the definition of 

Division 6.1 or is offered for 

transportation or transported by aircraft, 

and the specification packaging 

requirements of this subchapter when 

packaged in combination packagings 

according to this paragraph. In addition, 

shipments of limited quantities are not 

subject to subpart F (Placarding) of part 

172 of this subchapter. Each package 

must conform to the packaging 

requirements of subpart B of this part 

and may not exceed 30 kg (66 pounds) 

gross weight. The following 

combination packagings are authorized:

* * * * *

■ 30. In § 173.152, the introductory text 

of paragraph (b), paragraph (b)(1), and 

paragraph (c) are revised to read as 

follows:

§ 173.152 Exceptions for Division 5.1 

(oxidizers) and Division 5.2 (organic 

peroxides).

* * * * *

(b) Limited quantities. Limited 

quantities of oxidizers (Division 5.1) in 

Packing Group II and III and organic 

peroxides are excepted from labeling 

requirements, unless the material also 

meets the definition of Division 6.1 or 

is offered for transportation or 

transported by aircraft, and the 

specification packaging requirements of 

this subchapter when packaged in 

combination packagings according to 

this paragraph. In addition, shipments 

of limited quantities are not subject to 

subpart F (Placarding) of part 172 of this 

subchapter. Each package must conform 

to the packaging requirements of 

subpart B of this part and may not 

exceed 30 kg (66 pounds) gross weight. 

The following combination packagings 

are authorized: 

(1) For oxidizers in Packing Group II, 

inner packagings not over 1.0 L (0.3 

gallon) net capacity each for liquids or 

not over 1.0 kg (2.2 pounds) net capacity 

each for solids, unless the material has 

a subsidiary hazard of Division 6.1, 

Packing Group II, in which case the 

inner packagings may not exceed 100 

mL (3.38 ounces) for liquids or 0.5 kg 

(1.1 pounds) for solids, packed in a 

strong outer packaging.

* * * * *

(c) Consumer commodities. Except for 

a material that has a subsidiary hazard 

of Division 6.1, Packing Group II, a 

limited quantity which conforms to the 

provisions of paragraph (b) of this 

section, and is a ‘‘consumer 

commodity’’ as defined in § 171.8 of this 

subchapter, may be renamed ‘‘Consumer 

commodity’’ and reclassed as ORM–D. 

In addition to the exceptions provided 

by paragraph (b) of this section, 

shipments of ORM–D materials are not 

subject to the shipping paper 

requirements of subpart C of part 172 of 

this subchapter, unless the material 

meets the definition of a hazardous 

substance, hazardous waste, marine 

pollutant, or are offered for 

transportation and transported by 

aircraft, and are eligible for the 

exceptions provided in § 173.156.

■ 31. In § 173.153, paragraph (b), and 

paragraph (c)(1) are revised to read as 

follows:

§ 173.153 Exceptions for Division 6.1 

(poisonous materials).

* * * * *

(b) Limited quantities. The exceptions 

in this paragraph do not apply to 

poison-by-inhalation materials. Limited 

quantities of poisonous materials 

(Division 6.1) in Packing Group II and 

III are excepted from the specification 

packaging requirements of this 

subchapter when packaged in 

combination packagings according to 

this paragraph. In addition, shipments 

of limited quantities are not subject to 

subpart F (Placarding) of part 172 of this 

subchapter. Each package must conform 

to the packaging requirements of 

subpart B of this part and may not 

exceed 30 kg (66 pounds) gross weight. 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76157

The following combination packagings 

are authorized: 

(1) For poisonous materials in Packing 

Group II, inner packagings not over 100 

mL (3.38 ounces) each for liquids or 0.5 

kg (1.1 pounds) each for solids, packed 

in a strong outer packaging. 

(2) For poisonous materials in Packing 

Group III, inner packagings not over 4 

L (1.0 gallon) each for liquids or 5.0 kg 

(11 pounds) each for solids, packed in 

a strong outer packaging. 

(c) * * * 

(1) A limited quantity of poisonous 

material in Packing Group III which 

conforms to the provisions of paragraph 

(b) of this section, and is a ‘‘consumer 

commodity’’ as defined in § 171.8 of this 

subchapter, may be renamed ‘‘Consumer 

commodity’’ and reclassed as ORM–D.

* * * * *

■ 32. In § 173.154, the introductory text 

of paragraph (b), paragraph (b)(1), and 

paragraph (c) are revised to read as 

follows:

§ 173.154 Exceptions for Class 8 

(corrosive materials).

* * * * *

(b) Limited quantities. Limited 

quantities of corrosive materials (Class 

8) in Packing Group II and III are 

excepted from labeling requirements, 

unless the material also meets the 

definition of Division 6.1 or is offered 

for transportation or transported by 

aircraft, and the specification packaging 

requirements of this subchapter when 

packaged in combination packagings 

according to this paragraph. In addition, 

shipments of limited quantities are not 

subject to subpart F (Placarding) of part 

172 of this subchapter. Each package 

must conform to the packaging 

requirements of subpart B of this part 

and may not exceed 30 kg (66 pounds) 

gross weight. The following 

combination packagings are authorized: 

(1) For corrosive materials in Packing 

Group II, inner packagings not over 1.0 

L (0.3 gallon) net capacity each for 

liquids or not over 1.0 kg (2.2 pounds) 

net capacity each for solids, unless the 

material has a subsidiary hazard of 

Division 6.1, Packing Group II in which 

case the inner packagings may not 

exceed 100 mL (3.38 ounces) for liquids 

or 0.5 kg (1.1 pounds) for solids, packed 

in a strong outer packaging.

* * * * *

(c) Consumer commodities. Except for 

a material that has a subsidiary hazard 

of Division 6.1, Packing Group II, a 

limited quantity which conforms to the 

provisions of paragraph (b) of this 

section, and is a ‘‘consumer 

commodity’’ as defined in § 171.8 of this 

subchapter, may be renamed ‘‘Consumer 

commodity’’ and reclassed as ORM–D. 

In addition to the exceptions provided 

by paragraph (b) of this section, 

shipments of ORM–D materials are not 

subject to the shipping paper 

requirements of subpart C of part 172 of 

this subchapter, unless the material 

meets the definition of a hazardous 

substance, hazardous waste, marine 

pollutant, or are offered for 

transportation and transported by 

aircraft, and are eligible for the 

exceptions provided in § 173.156.

* * * * *

■ 33. In § 173.185, paragraphs (c)(3) and 

(e)(6) are revised to read as follows:

§ 173.185 Lithium batteries and cells.

* * * * *

(c) * * * 

(3) Each cell or battery is of the type 

proven to be non-dangerous by testing 

in accordance with Tests in the UN 

Manual of Tests and Criteria (IBR; see 

§ 171.7 of this subchapter). Such testing 

must be carried out on each type of cell 

or battery prior to the initial transport of 

that type. A cell or battery and 

equipment containing a cell or battery 

which was first transported prior to 

January 1, 2006 and is of a type proven 

to meet the criteria of Class 9 by testing 

in accordance with the tests in the UN 

Manual of Tests and Criteria, Third 

Revised Edition, 1999 is not required to 

be retested;

* * * * *

(e) * * * 

(6) Each cell or battery is of the type 

proven to meet the lithium battery 

requirements in the UN Manual of Tests 

and Criteria (IBR; see § 171.7 of this 

subchapter). A cell or battery and 

equipment containing a cell or battery 

which was first transported prior to 

January 1, 2006 and is of a type proven 

to meet the criteria of Class 9 by testing 

in accordance with the tests in the UN 

Manual of Tests and Criteria, Third 

Revised Edition, 1999 is not required to 

be retested.

* * * * *

■ 34. In § 173.186, paragraph (e) is 

revised to read as follows:

§ 173.186 Matches.

* * * * *

(e) Packagings. Strike-anywhere 

matches must be tightly packed in 

securely closed chipboard, fiberboard, 

wooden, or metal inner packagings to 

prevent accidental ignition under 

conditions normally incident to 

transportation. Each inner packaging 

may contain no more than 700 strikeanywhere matches and must be packed 

in outer steel drums (1A2), aluminum 

drums (1B2), steel jerricans (3A2), 

wooden (4C1, 4C2), plywood (4D), 

reconstituted wood (4F) or fiberboard 

(4G) boxes, plywood (1D) or fiber (1G) 

drums. Gross weight of fiberboard boxes 

(4G) must not exceed 30 kg (66 pounds). 

Gross weight of other outer packagings 

must not exceed 45 kg (100 pounds).

■ 35. In § 173.187, a new paragraph (f) is 

added to read as follows:

§ 173.187 Pyrophoric solids, metals or 

alloys, n.o.s.

* * * * *

(f) In specification cylinders, as 

prescribed for any compressed gas, 

except for Specifications 8 and 3HT.

■ 36. In § 173.211, paragraph (c) is 

revised to read as follows:

§ 173.211 Non-bulk packagings for solid 

hazardous materials in Packing Group I.

* * * * *

(c) Except for transportation by 

passenger aircraft, the following single 

packagings are authorized:

Steel drum: 1A1 or 1A2 

Aluminum drum: 1B1 or 1B2

Metal drum other than steel or 

aluminum: 1N1 or 1N2

Plastic drum: 1H1 or 1H2 

Fiber drum: 1G 

Steel jerrican: 3A1 or 3A2 

Plastic jerrican: 3H1 or 3H2 

Aluminum jerrican: 3B1 or 3B2 

Steel box with liner: 4A 

Aluminum box with liner: 4B 

Natural wood box, sift proof: 4C2 

Plastic receptacle in steel, aluminum, 

plywood, fiber or plastic drum: 6HA1, 

6HB1, 6HD1, 6HG1 or 6HH1 

Glass, porcelain or stoneware in steel, 

aluminum, plywood or fiber drum: 

6PA1, 6PB1, 6PD1 or 6PG1 

Glass, porcelain or stoneware in steel, 

aluminum, wooden or fiberboard box: 

6PA2, 6PB2, 6PC or 6PG2 

Glass, porcelain or stoneware in 

expanded or solid plastic packaging: 

6PH1 or 6PH2 

Cylinders, as prescribed for any 

compressed gas, except for 

Specification 8 and 3HT

■ 37. In § 173.212, paragraph (c) is 

revised to read as follows:

§ 173.212 Non-bulk packagings for solid 

hazardous materials in Packing Group III.

* * * * *

(c) Except for transportation by 

passenger aircraft, the following single 

packagings are authorized:

Steel drum: 1A1 or 1A2 

Aluminum drum: 1B1 or 1B2 

Plywood drum: 1D 

Plastic drum: 1H1 or 1H2 

Fiber drum: 1G 

Metal drum other than steel or 

aluminum: 1N1 or 1N2 

76158 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

Wooden barrel: 2C1 or 2C2 

Steel jerrican: 3A1 or 3A2 

Plastic jerrican: 3H1 or 3H2 

Aluminum jerrican: 3B1 or 3B2 

Steel box: 4A 

Steel box with liner: 4A 

Aluminum box: 4B 

Aluminum box with liner: 4B 

Natural wood box: 4C1 

Natural wood box, sift proof: 4C2 

Plywood box: 4D 

Reconstituted wood box: 4F 

Fiberboard box: 4G 

Expanded plastic box: 4H1 

Solid plastic box: 4H2 

Bag, woven plastic: 5H1, 5H2 or 5H3 

Bag, plastic film: 5H4 

Bag, textile: 5L1, 5L2 or 5L3 

Bag, paper, multiwall, water resistant: 

5M2 

Plastic receptacle in steel, aluminum, 

plywood, fiber or plastic drum: 6HA1, 

6HB1, 6HD1, 6HG1 or 6HH1 

Plastic receptacle in steel, aluminum, 

wood, plywood or fiberboard box: 

6HA2, 6HB2, 6HC, 6HD2 or 6HG2 

Glass, porcelain or stoneware in steel, 

aluminum, plywood or fiber drum: 

6PA1, 6PB1, 6PD1 or 6PG1 

Glass, porcelain or stoneware in steel, 

aluminum, wooden or fiberboard box: 

6PA2, 6PB1, 6PC or 6PG2 

Glass, porcelain or stoneware in 

expanded or solid plastic packaging: 

6PH1 or 6PH2 

Cylinders, as prescribed for any 

compressed gas, except for 

Specification 8 and 3HT

■ 38. In § 173.213, paragraph (c) is 

revised to read as follows:

§ 173.213 Non-bulk packagings for solid 

hazardous materials in Packing Group III.

* * * * *

(c) The following single packagings 

are authorized:

Steel drum: 1A1 or 1A2 

Aluminum drum: 1B1 or 1B2 

Plywood drum: 1D 

Plastic drum: 1H1 or 1H2 

Fiber drum: 1G 

Metal drum other than steel or 

aluminum: 1N1 or 1N2 

Wooden barrel: 2C1 or 2C2 

Steel jerrican: 3A1 or 3A2 

Plastic jerrican: 3H1 or 3H2 

Aluminum jerrican: 3B1 or 3B2 

Steel box: 4A 

Steel box with liner: 4A 

Aluminum box: 4B 

Aluminum box with liner: 4B 

Natural wood box: 4C1 

Natural wood box, sift proof: 4C2 

Plywood box: 4D 

Reconstituted wood box: 4F 

Fiberboard box: 4G 

Expanded plastic box: 4H1 

Solid plastic box: 4H2 

Bag, woven plastic: 5H1, 5H2 or 5H3 

Bag, plastic film: 5H4 

Bag, textile: 5L1, 5L2 or 5L3 

Bag, paper, multiwall, water resistant: 

5M2 

Plastic receptacle in steel, aluminum, 

plywood, fiber or plastic drum: 6HA1, 

6HB1, 6HD1, 6HG1 or 6HH1 

Plastic receptacle in steel, aluminum, 

wood, plywood or fiberboard box: 

6HA2, 6HB2, 6HC, 6HD2 or 6HG2 

Glass, porcelain or stoneware in steel, 

aluminum, plywood or fiber drum: 

6PA1, 6PB1, 6PD1 or 6PG1

Glass, porcelain or stoneware in steel, 

aluminum, wooden or fiberboard box: 

6PA2, 6PB1, 6PC or 6PG2 

Glass, porcelain or stoneware in 

expanded or solid plastic packaging: 

6PH1 or 6PH2 

Cylinders, as prescribed for any 

compressed gas, except for 

Specification 8 and 3HT

■ 39. Section 173.219 is revised to read 

as follows:

§ 173.219 Life-saving appliances. 

(a) A life-saving appliance, selfinflating or non-self-inflating, 

containing small quantities of hazardous 

materials that are required as part of the 

life-saving appliance must conform to 

the requirements of this section. 

Packagings must conform to the general 

packaging requirements of subpart B of 

this part but need not conform to the 

requirements of part 178 of this 

subchapter. The appliances must be 

packed, so that they cannot be 

accidentally activated and, except for 

life vests, the hazardous materials must 

be in inner packagings packed so as to 

prevent movement. The hazardous 

materials must be an integral part of the 

appliance and in quantities that do not 

exceed those appropriate for the actual 

appliance when in use. 

(b) Life saving appliances may 

contain: 

(1) Division 2.2 compressed gases, 

including oxygen. However, oxygen 

generators are not permitted; 

(2) Signal devices (Class 1), which 

may include smoke and illumination 

signal flares; 

(3) Electric storage batteries and 

lithium batteries (Life saving appliances 

containing lithium batteries must be 

transported in accordance with 

§ 173.185.); 

(4) First aid or repair kits conforming 

to the applicable material and quantity 

limitations of § 173.161 of this 

subchapter; 

(5) Strike-anywhere matches; 

(6) For self-inflating life saving 

appliances only, cartridges power 

device of Division 1.4S, for purposes of 

the self-inflating mechanism provided 

that the quantity of explosives per 

appliance does not exceed 3.2 g; or 

(7) Limited quantities of other 

hazardous materials. 

(c) Hazardous materials in life saving 

appliances must be packaged as follows: 

(1) Division 2.2 compressed gases 

must be packaged in cylinders in 

accordance with the requirements of 

this subchapter; 

(2) Signal devices (Class 1) must be in 

packagings that prevent them from 

being inadvertently activated; 

(3) Strike-anywhere matches must be 

cushioned to prevent movement or 

friction in a metal or composition 

receptacle with a screw-type closure in 

a manner that prevents them from being 

inadvertently activated;

(4) Limited quantities of other 

hazardous materials must be packaged 

in accordance with the requirements of 

this subchapter; and 

(5) For other than transportation by 

aircraft, life saving appliances 

containing no hazardous materials other 

than carbon dioxide cylinders with a 

capacity not exceeding 100 cm3 are not 

subject to the provisions of this 

subchapter provided they are 

overpacked in rigid outer packagings 

with a maximum gross mass of 40 kg.

■ 40. In § 173.220, paragraph (b)(2) is 

revised to read as follows:

§ 173.220 Internal combustion engines, 

self-propelled vehicles, mechanical 

equipment containing internal combustion 

engines, and battery powered vehicles or 

equipment.

* * * * *

(b) * * *

(2) Flammable liquefied or 

compressed gas fuel. (i) For 

transportation by motor vehicle, rail car 

or vessel, fuel tanks and fuel systems 

containing flammable liquefied or 

compressed gas fuel must be securely 

closed. For transportation by vessel, the 

requirements of §§ 176.78(k) and 

176.905 of this subchapter apply. 

(ii) For transportation by aircraft: 

(A) Flammable gas-powered vehicles, 

machines, equipment or cylinders 

containing the flammable gas must be 

completely emptied of flammable gas. 

Lines from vessels to gas regulators, and 

gas regulators themselves, must also be 

drained of all traces of flammable gas. 

To ensure that these conditions are met, 

gas shut-off valves must be left open and 

connections of lines to gas regulators 

must be left disconnected upon delivery 

of the vehicle to the operator. Shut-off 

valves must be closed and lines 

reconnected at gas regulators before 

loading the vehicle aboard the aircraft; 

or alternatively 

(B) Flammable gas powered vehicles, 

machines or equipment, which have

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76159

cylinders (fuel tanks) that are equipped 

with electrically operated valves, may 

be transported under the following 

conditions: 

(1) The valves must be in the closed 

position and in the case of electrically 

operated valves, power to those valves 

must be disconnected; 

(2) After closing the valves, the 

vehicle, equipment or machinery must 

be operated until it stops from lack of 

fuel before being loaded aboard the 

aircraft; 

(3) In no part of the system between 

the pressure receptacle and the shut off 

valve shall the pressure exceed more 

than 5% of the maximum allowable 

working pressure of the system; and 

(4) There must not be any residual 

liquefied gas in the system, including 

the fuel tank.

■ 41. In § 173.224, paragraph (b)(4) is 

revised to read as follows:

§ 173.224 Packaging and control and 

emergency temperatures for self-reactive 

materials.

* * * * *

(b) * * * 

(4) Packing method. Column 4 

specifies the highest packing method 

which is authorized for the self-reactive 

material. A packing method 

corresponding to a smaller package size 

may be used, but a packing method 

corresponding to a larger package size 

may not be used. The Table of Packing 

Methods in § 173.225(d) defines the 

packing methods. Bulk packagings for 

Type F self-reactive substances are 

authorized by § 173.225(f) for IBCs and 

§ 173.225(h) for bulk packagings other 

than IBCs. Additional bulk packagings 

are authorized if approved by the 

Associate Administrator.

* * * * *

■ 42. Section 173.225 is revised to read 

as follows:

§ 173.225 Packaging requirements and 

other provisions for organic peroxides. 

(a) General. When the § 172.101 table 

specifies that an organic peroxide must 

be packaged under this section, the 

organic peroxide must be packaged and 

offered for transportation in accordance 

with the provisions of this section. Each 

packaging must conform to the general 

requirements of subpart B of part 173 

and to the applicable requirements of 

part 178 of this subchapter. Non-bulk 

packagings must meet Packing Group II 

performance levels. To avoid 

unnecessary confinement, metallic nonbulk packagings meeting Packing Group 

I are not authorized. No used material, 

other than production residues or 

regrind from the same production 

process, may be used in plastic 

packagings. Organic peroxides that 

require temperature control are subject 

to the provisions of § 173.21(f). When an 

IBC or bulk packaging is authorized and 

meets the requirements of paragraph (f) 

or (h) of this section, respectively, lower 

control temperatures than those 

specified for non-bulk packaging may be 

required. An organic peroxide not 

identified in paragraph (c), (e), or (g) of 

this section by technical name, or not 

assigned to a generic type in accordance 

with the provisions in paragraph (b)(3) 

of this section, must conform to the 

provisions of paragraph (c) of § 173.128.

(b) New organic peroxides, 

formulations and samples. (1) Except as 

provided for samples in paragraph (b)(2) 

of this section, no person may offer for 

transportation an organic peroxide that 

is not identified by technical name in 

the Organic Peroxides Table, Organic 

Peroxide IBC Table, or the Organic 

Peroxide Portable Tank Table of this 

section, or a formulation of one or more 

organic peroxides that are identified by 

technical name in one of those tables, 

unless the organic peroxide is assigned 

a generic type and shipping description 

and is approved by the Associate 

Administrator under the provisions of 

§ 173.128(d) of this subchapter. 

(2) Samples. Samples of new organic 

peroxides or new formulations of 

organic peroxides identified in the 

Organic Peroxides Table in paragraph 

(c) of this section, for which complete 

test data are not available, and that are 

to be transported for further testing or 

product evaluation, may be assigned an 

appropriate shipping description for 

organic peroxide Type C, packaged and 

offered for transportation, under the 

following conditions: 

(i) Data available to the person 

offering the material for transportation 

must indicate that the sample would 

pose a level of hazard no greater than 

that of an organic peroxide Type B and 

that the control temperature, if any, is 

sufficiently low to prevent any 

dangerous decomposition and 

sufficiently high to prevent any 

dangerous phase separation; 

(ii) The sample must be packaged in 

accordance with packing method OP2, 

for a liquid or solid, respectively; 

(iii) Packages of the organic peroxide 

may be offered for transportation and 

transported in a quantity not to exceed 

10 kg (22 pounds) per transport vehicle; 

and 

(iv) One of the following shipping 

descriptions must be assigned: 

(A) Organic peroxide Type C, liquid, 

5.2, UN 3103; 

(B) Organic peroxide Type C, solid, 

5.2, UN 3104; 

(C) Organic peroxide Type C, liquid, 

temperature controlled, 5.2, UN 3113; or 

(D) Organic peroxide Type C, solid, 

temperature controlled, 5.2, UN 3114. 

(3) Mixtures. Mixtures of organic 

peroxides individually identified in the 

Organic Peroxides Table in paragraph 

(c) of this section may be classified as 

the same type of organic peroxide as 

that of the most dangerous component 

and be transported under the conditions 

for transportation given for this type. If 

the stable components form a thermally 

less stable mixture, the SADT of the 

mixture must be determined and the 

new control and emergency temperature 

derived under the provisions of 

§ 173.21(f). 

(c) Organic peroxides table. The 

following Organic Peroxides Table 

specifies by technical name those 

organic peroxides that are authorized for 

transportation and not subject to the 

approval provisions of § 173.128 of this 

part. An organic peroxide identified by 

technical name in the following table is 

authorized for transportation only if it 

conforms to all applicable provisions of 

the table. The column headings of the 

Organic Peroxides Table are as follows: 

(1) Technical name. The first column 

specifies the technical name. 

(2) ID number. The second column 

specifies the identification (ID) number 

which is used to identify the proper 

shipping name in the § 172.101 table. 

The word ‘‘EXEMPT’’ appearing in the 

column denotes that the material is not 

regulated as an organic peroxide. 

(3) Concentration of organic peroxide.

The third column specifies 

concentration (mass percent) 

limitations, if any, in mixtures or 

solutions for the organic peroxide. 

Limitations are given as minimums, 

maximums, or a range, as appropriate. A 

range includes the lower and upper 

limits (i.e., ‘‘53–100’’ means from, and 

including, 53% to, and including 

100%). See introductory paragraph of 

§ 172.203(k) of this subchapter for 

additional description requirements for 

an organic peroxide that may qualify for 

more than one generic listing, 

depending on its concentration. 

(4) Concentration of diluents. The 

fourth column specifies the type and 

concentration (mass percent) of diluent 

or inert solid, when required. Other 

types and concentrations of diluents 

may be used if approved by the 

Associate Administrator. 

(i) The required mass percent of 

‘‘Diluent type A’’ is specified in column 

4a. A diluent type A is an organic liquid 

that does not detrimentally affect the 

thermal stability or increase the hazard 

of the organic peroxide and with a 

boiling point not less than 150 °C at 

76160 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

atmospheric pressure. Type A diluents 

may be used for desensitizing all 

organic peroxides. 

(ii) The required mass percent of 

‘‘Diluent type B’’ is specified in column 

4b. A diluent type B is an organic liquid 

which is compatible with the organic 

peroxide and which has a boiling point, 

at atmospheric pressure, of less than 

150 °C (302 °F) but at least 60 °C (140 °F), 

and a flash point greater than 5 °C 

(41 °F). Type B diluents may be used for 

desensitizing all organic peroxides, 

when specified in the organic peroxide 

tables, provided that the boiling point is 

at least 60 °C (140 °F) above the SADT of 

the peroxide in a 50 kg (110 lbs) 

package. A type A diluent may be used 

to replace a type B diluent in equal 

concentration. 

(iii) The required mass percent of 

‘‘Inert solid’’ is specified in column 4c. 

An inert solid is a solid that does not 

detrimentally affect the thermal stability 

or hazard of the organic peroxide. 

(5) Concentration of water. Column 5 

specifies, in mass percent, the minimum 

amount of water, if any, which must be 

in formulation.

(6) Packing method. Column 6 

specifies the highest packing method 

(largest packaging capacity) authorized 

for the organic peroxide. Lower 

numbered packing methods (smaller 

packaging capacities) are also 

authorized. For example, if OP3 is 

specified, then OP2 and OP1 are also 

authorized. The Table of Packing 

Methods in paragraph (d) of this section 

defines the non-bulk packing methods. 

(7) Temperatures. Column 7a 

specifies the control temperature. 

Column 7b specifies the emergency 

temperature. Temperatures are specified 

only when temperature controls are 

required. (See § 173.21(f)). 

(8) Notes. Column 8 specifies other 

applicable provisions, as set forth in 

notes following the table. 

BILLING CODE 4910–60–U

ORGANIC PEROXIDE TABLE

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

Acetyl acetone peroxide ... UN3105 ≤42 ................................... ≥48 .. ...... ...... ≥8 .......... OP7 ....... ...... ...... 2

Acetyl acetone peroxide 

[as a paste].

UN3106 ≤32 ................................... ...... ...... ...... ............ OP7 ....... ...... ...... 21

Acetyl cyclohexanesulfonyl 

peroxide.

UN3112 ≤82 ................................... ...... ...... ...... ≥12 ........ OP4 ....... ¥10 0 ......

Acetyl cyclohexanesulfonyl 

peroxide.

UN3115 ≤32 ................................... ...... ≥68 .. ...... ............ OP7 ....... ¥10 0 ......

tert-Amyl hydroperoxide .... UN3107 ≤88 ................................... ≥6 .... ...... ...... ≥6 .......... OP8 ....... ...... ......

tert-Amyl peroxyacetate .... UN3105 ≤62 ................................... ≥38 .. ...... ...... ............ OP7 ....... ...... ......

tert-Amyl peroxybenzoate UN3103 ≤100 ................................. ...... ...... ...... ............ OP5 ....... ...... ......

tert-Amyl peroxy-2-

ethylhexanoate.

UN3115 ≤100 ................................. ...... ...... ...... ............ OP7 ....... +20 +25 ..

tert-Amyl peroxy-2-

ethylhexyl carbonate.

UN3105 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

tert-Amyl peroxy isopropyl 

carbonate.

UN3103 ≤77 ................................... ≥23 .. ...... ...... ............ OP5 ....... ...... ......

tert-Amyl 

peroxyneodecanoate.

UN3115 ≤77 ................................... ...... ≥23 .. ...... ............ OP7 ....... 0 ...... +10 ..

tert-Amyl peroxypivalate ... UN3113 ≤77 ................................... ...... ≥23 .. ...... ............ OP5 ....... +10 +15 ..

tert-Amyl peroxy-3,5,5-

trimethylhexanoate.

UN3101 ≤100 ................................. ...... ...... ...... ............ OP5 ....... ...... ......

tert-Butyl cumyl peroxide .. UN3107 >42–100 ........................... ...... ...... ...... ............ OP8 ....... ...... ...... 9

tert-Butyl cumyl peroxide .. UN3108 ≤52 ................................... ...... ...... ≥48 .. ............ OP8 ....... ...... ...... 9

n-Butyl-4,4-di-(tertbutylperoxy)valerate.UN3103 >52–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

n-Butyl-4,4-di-(tertbutylperoxy)valerate.UN3108 ≤52 ................................... ...... ...... ≥48 .. ............ OP8 ....... ...... ......

tert-Butyl hydroperoxide ... UN3103 >79–90 ............................. ...... ...... ...... ≥10 ........ OP5 ....... ...... ...... 13

tert-Butyl hydroperoxide ... UN3105 ≤80 ................................... ≥20 .. ...... ...... ............ OP7 ....... ...... ...... 4, 13

tert-Butyl hydroperoxide ... UN3107 ≤79 ................................... ...... ...... ...... >14 ........ OP8 ....... ...... ...... 13, 16

tert-Butyl hydroperoxide ... UN3109 ≤72 ................................... ...... ...... ...... ≥28 ........ OP8 ....... ...... ...... 13

tert-Butyl hydroperoxide 

[and] Di-tertbutylperoxide.

UN3103 <82+>9 ............................. ...... ...... ...... ≥7 .......... OP5 ....... ...... ...... 13

tert-Butyl 

monoperoxymaleate.

UN3102 >52–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

tert-Butyl 

monoperoxymaleate.

UN3103 ≤52 ................................... ≥48 .. ...... ...... ............ OP6 ....... ...... ......

tert-Butyl 

monoperoxymaleate.

UN3108 ≤52 ................................... ...... ...... ≥48 .. ............ OP8 ....... ...... ......

tert-Butyl 

monoperoxymaleate [as 

a paste].

UN3108 ≤52 ................................... ...... ...... ...... ............ OP8 ....... ...... ......

tert-Butyl peroxyacetate .... UN3101 >52–77 ............................. ≥23 .. ...... ...... ............ OP5 ....... ...... ......

tert-Butyl peroxyacetate .... UN3103 >32–52 ............................. ≥48 .. ...... ...... ............ OP6 ....... ...... ......

tert-Butyl peroxyacetate .... UN3109 ≤32 ................................... ...... ≥68 .. ...... ............ OP8 ....... ...... ......

tert-Butyl peroxybenzoate UN3103 >77–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76161

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

tert-Butyl peroxybenzoate UN3105 >52–77 ............................. ≥23 .. ...... ...... ............ OP7 ....... ...... ...... 1

tert-Butyl peroxybenzoate UN3106 ≤52 ................................... ...... ...... ≥48 .. ............ OP7 ....... ...... ......

tert-Butyl peroxybutyl fumarate.UN3105 ≤52 ................................... ≥48 .. ...... ...... ............ OP7 ....... ...... ......

tert-Butyl peroxycrotonate UN3105 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... ...... ......

tert-Butyl 

peroxydiethylacetate.

UN3113 ≤100 ................................. ...... ...... ...... ............ OP5 ....... +20 +25 ..

tert-Butyl peroxy-2-

ethylhexanoate.

UN3113 >52–100 ........................... ...... ...... ...... ............ OP6 ....... +20 +25 ..

tert-Butyl peroxy-2-

ethylhexanoate.

UN3117 >32–52 ............................. ...... ≥48 .. ...... ............ OP8 ....... +30 +35 ..

tert-Butyl peroxy-2-

ethylhexanoate.

UN3118 ≤52 ................................... ...... ...... ≥48 .. ............ OP8 ....... +20 +25 ..

tert-Butyl peroxy-2-

ethylhexanoate.

UN3119 ≤32 ................................... ...... ≥68 .. ...... ............ OP8 ....... +40 +45 ..

tert-Butyl peroxy-2-

ethylhexanoate [and] 

2,2-di-(tertButylperoxy)butane.

UN3106 ≤12+≤14 ........................... ≥14 .. ...... ≥60 .. ............ OP7 ....... ...... ......

tert-Butyl peroxy-2-

ethylhexanoate [and] 

2,2-di-(tertButylperoxy)butane.

UN3115 ≤31+≤36 ........................... ...... ≥33 .. ...... ............ OP7 ....... +35 +40 ..

tert-Butyl peroxy-2-

ethylhexylcarbonate.

UN3105 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

tert-Butyl 

peroxyisobutyrate.

UN3111 >52–77 ............................. ...... ≥23 .. ...... ............ OP5 ....... +15 +20 ..

tert-Butyl 

peroxyisobutyrate.

UN3115 ≤52 ................................... ...... ≥48 .. ...... ............ OP7 ....... +15 +20 ..

tert-Butylperoxy 

isopropylcarbonate.

UN3103 ≤77 ................................... ≥23 .. ...... ...... ............ OP5 ....... ...... ......

1-(2-tert-Butylperoxy isopropyl)-3-

isopropenylbenzene.

UN3105 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... ...... ......

1-(2-tert-Butylperoxy isopropyl)-3-

isopropenylbenzene.

UN3108 ≤42 ................................... ...... ...... ≥58 .. ............ OP8 ....... ...... ......

tert-Butyl peroxy-2-

methylbenzoate.

UN3103 ≤100 ................................. ...... ...... ...... ............ OP5 ....... ...... ......

tert-Butyl 

peroxyneodecanoate.

UN3115 >77–100 ........................... ...... ...... ...... ............ OP7 ....... ¥5 .. +5 ....

tert-Butyl 

peroxyneodecanoate.

UN3115 ≤77 ................................... ...... ≥23 .. ...... ............ OP7 ....... 0 ...... +10 ..

tert-Butyl 

peroxyneodecanoate [as 

a stable dispersion in 

water].

UN3119 ≤52 ................................... ...... ...... ...... ............ OP8 ....... 0 ...... +10 ..

tert-Butyl 

peroxyneodecanoate [as 

a stable dispersion in 

water (frozen)].

UN3118 ≤42 ................................... ...... ...... ...... ............ OP8 ....... 0 ...... +10 ..

tert-Butyl 

peroxyneodecanoate.

UN3119 ≤32 ................................... ≥68 .. ...... ...... ............ OP8 ....... 0 ...... +10 ..

tert-Butyl 

peroxyneoheptanoate.

UN3115 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... 0 ...... +10 ..

tert-Butyl 

peroxyneoheptanoate 

[as a stable dispersion 

in water].

UN3117 ≤42 ................................... ...... ...... ...... ............ OP8 ....... 0 ...... +10 ..

tert-Butyl peroxypivalate ... UN3113 >67–77 ............................. ≥23 .. ...... ...... ............ OP5 ....... 0 ...... +10 ..

tert-Butyl peroxypivalate ... UN3115 >27–67 ............................. ...... ≥33 .. ...... ............ OP7 ....... 0 ...... +10 ..

tert-Butyl peroxypivalate ... UN3119 ≤27 ................................... ...... ≥73 .. ...... ............ OP8 ....... +30 +35 ..

tert-Butylperoxy 

stearylcarbonate.

UN3106 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

tert-Butyl peroxy-3,5,5-

trimethylhexanoate.

UN3105 >32–100 ........................... ...... ...... ...... ............ OP7 ....... ...... ......

76162 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

tert-Butyl peroxy-3,5,5-

trimethylhexanoate.

UN3109 ≤32 ................................... ...... ≥68 .. ...... ............ OP8 ....... ...... ......

3-Chloroperoxybenzoic 

acid.

UN3102 >57–86 ............................. ...... ...... ≥14 .. ............ OP1 ....... ...... ......

3-Chloroperoxybenzoic 

acid.

UN3106 ≤57 ................................... ...... ...... ≥3 .... ≥40 ........ OP7 ....... ...... ......

3-Chloroperoxybenzoic 

acid.

UN3106 ≤77 ................................... ...... ...... ≥6 .... ≥17 ........ OP7 ....... ...... ......

Cumyl hydroperoxide ........ UN3107 >90–98 ............................. ≤10 .. ...... ...... ............ OP8 ....... ...... ...... 13

Cumyl hydroperoxide ........ UN3109 ≤90 ................................... ≥10 .. ...... ...... ............ OP8 ....... ...... ...... 13, 15

Cumyl 

peroxyneodecanoate.

UN3115 ≤77 ................................... ...... ≥23 .. ...... ............ OP7 ....... ¥10 0 ......

Cumyl 

peroxyneodecanoate [as 

a stable dispersion in 

water].

UN3119 ≤52 ................................... ...... ...... ...... ............ OP8 ....... ¥10 0 ......

Cumyl 

peroxyneoheptanoate.

UN3115 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... ¥10 0 ......

Cumyl peroxypivalate ....... UN3115 ≤77 ................................... ...... ≥23 .. ...... ............ OP7 ....... ¥5 .. +5 ....

Cyclohexanone peroxide(s).UN3104 ≤91 ................................... ...... ...... ...... ≥9 .......... OP6 ....... ...... ...... 13

Cyclohexanone peroxide(s).UN3105 ≤72 ................................... ≥28 .. ...... ...... ............ OP7 ....... ...... ...... 5

Cyclohexanone peroxide(s) [as a paste].UN3106 ≤72 ................................... ...... ...... ...... ............ OP7 ....... ...... ...... 5, 21

Cyclohexanone peroxide(s).Exempt .. ≤32 ................................... ...... ...... ≥68 .. ............ Exempt .. ...... ......

Diacetone alcohol peroxides.UN3115 ≤57 ................................... ...... ≥26 .. ...... ≥8 .......... OP7 ....... +40 +45 .. 5

Diacetyl peroxide .............. UN3115 ≤27 ................................... ...... ≥73 .. ...... ............ OP7 ....... +20 +25 .. 8,13

Di-tert-amyl peroxide ........ UN3107 ≤100 ................................. ...... ...... ...... ............ OP8 ....... ...... ......

1,1-Di-(tertamylperoxy)cyclohexane.UN3103 ≤82 ................................... ≥18 .. ...... ...... ............ OP6 ....... ...... ......

Dibenzoyl peroxide ........... UN3102 >51–100 ........................... ...... ...... ≤48 .. ............ OP2 ....... ...... ...... 3

Dibenzoyl peroxide ........... UN3102 >77–94 ............................. ...... ...... ...... ≥6 .......... OP4 ....... ...... ...... 3

Dibenzoyl peroxide ........... UN3104 ≤77 ................................... ...... ...... ...... ≥23 ........ OP6 ....... ...... ......

Dibenzoyl peroxide ........... UN3106 ≤62 ................................... ...... ...... ≥28 .. ≥10 ........ OP7 ....... ...... ......

Dibenzoyl peroxide [as a 

paste].

UN3106 >52–62 ............................. ...... ...... ...... ............ OP7 ....... ...... ...... 21

Dibenzoyl peroxide ........... UN3106 >35–52 ............................. ...... ...... ≥48 .. ............ OP7 ....... ...... ......

Dibenzoyl peroxide ........... UN3107 >36–42 ............................. ≥18 .. ...... ...... ≤40 ........ OP8 ....... ...... ......

Dibenzoyl peroxide [as a 

paste].

UN3108 ≤56.5 ................................ ...... ...... ...... ≥15 ........ OP8 ....... ...... ......

Dibenzoyl peroxide [as a 

paste].

UN3108 ≤52 ................................... ...... ...... ...... ............ OP8 ....... ...... ...... 21

Dibenzoyl peroxide [as a 

stable dispersion in 

water].

UN3109 ≤42 ................................... ...... ...... ...... ............ OP8 ....... ...... ......

Dibenzoyl peroxide ........... Exempt .. ≤35 ................................... ...... ...... ≥65 .. ............ Exempt .. ...... ......

Di-(4-tertbutylcyclohexyl)peroxydicarbonate.UN3114 ≤100 ................................. ...... ...... ...... ............ OP6 ....... +30 +35 ..

Di-(4-tertbutylcyclohexyl)peroxydicarbonate [as 

a stable dispersion in 

water].

UN3119 ≤42 ................................... ...... ...... ...... ............ OP8 ....... +30 +35 ..

Di-tert-butyl peroxide ........ UN3107 >52–100 ........................... ...... ...... ...... ............ OP8 ....... ...... ......

Di-tert-butyl peroxide ........ UN3109 ≤52 ................................... ...... ≥48 .. ...... ............ OP8 ....... ...... ...... 24

Di-tert-butyl peroxyazelate UN3105 ≤52 ................................... ≥48 .. ...... ...... ............ OP7 ....... ...... ......

2,2-Di-(tertbutylperoxy)butane.UN3103 ≤52 ................................... ≥48 .. ...... ...... ............ OP6 ....... ...... ......

1,6-Di-(tertbutylperoxycarbonyloxy)hexane.UN3103 ≤72 ................................... ≥28 .. ...... ...... ............ OP5 ....... ...... ......

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76163

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

1,1-Di-(tertbutylperoxy)cyclohexane.UN3101 >80–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

1,1-Di-(tertbutylperoxy)cyclohexane.UN3103 >52–80 ............................. ≥20 .. ...... ...... ............ OP5 ....... ...... ......

1,1-Di-(tertbutylperoxy)cyclohexane.UN3105 >42–52 ............................. ≥48 .. ...... ...... ............ OP7 ....... ...... ......

1,1-Di-(tertbutylperoxy)cyclohexane.UN3106 ≤42 ................................... ≥13 .. ...... ≥45 .. ............ OP7 ....... ...... ......

1,1-Di-(tertbutylperoxy)cyclohexane.UN3107 ≤27 ................................... ≥25 .. ...... ...... ............ OP8 ....... ...... ...... 22

1,1-Di-(tertbutylperoxy)cyclohexane.UN3109 ≤42 ................................... ≥58 .. ...... ...... ............ OP8 ....... ...... ......

1,1-Di-(tertbutylperoxy)cyclohexane.UN3109 ≤25 ................................... ≥25 .. ≥50 .. ...... ............ OP8 ....... ...... ...... 29

1,1-Di-(tertbutylperoxy)cyclohexane.UN3109 ≤13 ................................... ≥13 .. ≥74 .. ...... ............ OP8 ....... ...... ......

Di-n-butyl 

peroxydicarbonate.

UN3115 >27–52 ............................. ...... ≥48 .. ...... ............ OP7 ....... ¥15 ¥5 ...

Di-n-butyl 

peroxydicarbonate.

UN3117 ≤27 ................................... ...... ≥73 .. ...... ............ OP8 ....... ¥10 0 ......

Di-n-butyl 

peroxydicarbonate [as a 

stable dispersion in 

water (frozen)].

UN3118 ≤42 ................................... ...... ...... ...... ............ OP8 ....... ¥15 ¥5 ...

Di-sec-butyl 

peroxydicarbonate.

UN3113 >52–100 ........................... ...... ...... ...... ............ OP4 ....... ¥20 ¥10 6

Di-sec-butyl 

peroxydicarbonate.

UN3115 ≤52 ................................... ...... ≥48 .. ...... ............ OP7 ....... ¥15 ¥5 ...

Di-(2-tertbutylperoxyisopropyl)benzene(s).UN3106 >42–100 ........................... ...... ...... ≤57 .. ............ OP7 ....... ...... ...... 1, 9

Di-(2-tertbutylperoxyisopropyl)benzene(s).Exempt .. ≤42 ................................... ...... ...... ≥58 .. ............ Exempt .. ...... ......

Di-(tertbutylperoxy)phthalate.UN3105 >42–52 ............................. ≥48 .. ...... ...... ............ OP7 ....... ...... ......

Di-(tertbutylperoxy)phthalate 

[as a paste].

UN3106 ≤52 ................................... ...... ...... ...... ............ OP7 ....... ...... ...... 21

Di-(tertbutylperoxy)phthalate.UN3107 ≤42 ................................... ≥58 .. ...... ...... ............ OP8 ....... ...... ......

2,2-Di-(tertbutylperoxy)propane.UN3105 ≤52 ................................... ≥48 .. ...... ...... ............ OP7 ....... ...... ......

2,2-Di-(tertbutylperoxy)propane.UN3106 ≤42 ................................... ≥13 .. ...... ≥45 .. ............ OP7 ....... ...... ......

1,1-Di-(tert-butylperoxy)-

3,3,5-

trimethylcyclohexane.

UN3101 >90–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

1,1-Di-(tert-butylperoxy)-

3,3,5-

trimethylcyclohexane.

UN3103 >57–90 ............................. ≥10 .. ...... ...... ............ OP5 ....... ...... ......

1,1-Di-(tert-butylperoxy)-

3,3,5-

trimethylcyclohexane.

UN3103 ≤77 ................................... ...... ≥23 .. ...... ............ OP5 ....... ...... ......

1,1-Di-(tert-butylperoxy)-

3,3,5-

trimethylcyclohexane.

UN3110 ≤57 ................................... ...... ...... ≥43 .. ............ OP8 ....... ...... ......

1,1-Di-(tert-butylperoxy)-

3,3,5-

trimethylcyclohexane.

UN3107 ≤57 ................................... ≥43 .. ...... ...... ............ OP8 ....... ...... ......

1,1-Di-(tert-butylperoxy)-

3,3,5-

trimethylcyclohexane.

UN3107 ≤32 ................................... ≥26 .. ≥42 .. ...... ............ OP8 ....... ...... ......

Dicetyl peroxydicarbonate UN3116 ≤100 ................................. ...... ...... ...... ............ OP7 ....... +30 +35 ..

76164 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

Dicetyl peroxydicarbonate 

[as a stable dispersion 

in water].

UN3119 ≤42 ................................... ...... ...... ...... ............ OP8 ....... +30 +35 ..

Di-4-chlorobenzoyl peroxide.UN3102 ≤77 ................................... ...... ...... ...... ≥23 ........ OP5 ....... ...... ......

Di-4-chlorobenzoyl peroxide [as a paste].UN3106 ≤52 ................................... ...... ...... ...... ............ OP7 ....... ...... ...... 21

Di-4-chlorobenzoyl peroxide.Exempt .. ≤32 ................................... ...... ...... ≥68 .. ............ Exempt .. ...... ......

Dicumyl peroxide .............. UN3110 >52–100 ........................... ...... ...... ≤48 .. ............ OP8 ....... ...... ......

Dicumyl peroxide .............. Exempt .. ≤52 ................................... ...... ...... ≥48 .. ............ Exempt .. ...... ......

Dicyclohexyl 

peroxydicarbonate.

UN3112 >91–100 ........................... ...... ...... ...... ............ OP3 ....... +10 +15 ..

Dicyclohexyl 

peroxydicarbonate.

UN3114 ≤91 ................................... ...... ...... ...... ≥9 .......... OP5 ....... +10 +15 ..

Dicyclohexyl 

peroxydicarbonate [as a 

stable dispersion in 

water].

UN3119 ≤42 ................................... ...... ...... ...... ............ OP8 ....... +15 +20 ..

Didecanoyl peroxide ......... UN3114 ≤100 ................................. ...... ...... ...... ............ OP6 ....... +30 +35 ..

2,2-Di-(4,4-di(tertbutylperoxy)cyclohexyl)propane.UN3106 ≤42 ................................... ...... ...... ≥58 .. ............ OP7 ....... ...... ......

2,2-Di-(4,4-di(tertbutylperoxy)cyclohexyl)propane.UN3107 ≤22 ................................... ...... ≥78 .. ...... ............ OP8 ....... ...... ......

Di-2,4-dichlorobenzoyl peroxide.UN3102 ≤77 ................................... ...... ...... ...... ≥23 ........ OP5 ....... ...... ......

Di-2,4-dichlorobenzoyl peroxide [as a paste with 

silicone oil].

UN3106 ≤52 ................................... ...... ...... ...... ............ OP7 ....... ...... ......

Di-(2-ethoxyethyl) 

peroxydicarbonate.

UN3115 ≤52 ................................... ...... ≥48 .. ...... ............ OP7 ....... ¥10 0 ......

Di-(2-ethylhexyl) 

peroxydicarbonate.

UN3113 >77–100 ........................... ...... ...... ...... ............ OP5 ....... ¥20 ¥10

Di-(2-ethylhexyl) 

peroxydicarbonate.

UN3115 ≤77 ................................... ...... ≥23 .. ...... ............ OP7 ....... ¥15 ¥5 ...

Di-(2-ethylhexyl) 

peroxydicarbonate [as a 

stable dispersion in 

water].

UN3117 ≤62 ................................... ...... ...... ...... ............ OP8 ....... ¥15 ¥5 ...

Di-(2-ethylhexyl) 

peroxydicarbonate [as a 

stable dispersion in 

water].

UN3119 ≤52 ................................... ...... ...... ...... ............ OP8 ....... ¥15 ¥5 ...

Di-(2-ethylhexyl) 

peroxydicarbonate [as a 

stable dispersion in 

water (frozen)].

UN3120 ≤52 ................................... ...... ...... ...... ............ OP8 ....... ¥15 ¥5 ...

2,2-Dihydroperoxypropane UN3102 ≤27 ................................... ...... ...... ≥73 .. ............ OP5 ....... ...... ......

Di-(1-

hydroxycyclohexyl)peroxide.

UN3106 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

Diisobutyryl peroxide ........ UN3111 >32–52 ............................. ...... ≥48 .. ...... ............ OP5 ....... ¥20 ¥10

Diisobutyryl peroxide ........ UN3115 ≤32 ................................... ...... ≥68 .. ...... ............ OP7 ....... ¥20 ¥10

Diisopropylbenzene 

dihydroperoxide.

UN3106 ≤82 ................................... ≥5 .... ...... ...... ≥5 .......... OP7 ....... ...... ...... 17

Diisopropyl 

peroxydicarbonate.

UN3112 >52–100 ........................... ...... ...... ...... ............ OP2 ....... ¥15 ¥5 ...

Diisopropyl 

peroxydicarbonate.

UN3115 ≤52 ................................... ...... ≥48 .. ...... ............ OP7 ....... ¥20 ¥10

Diisopropyl 

peroxydicarbonate.

UN3115 ≤28 ................................... ≥72 .. ...... ...... ............ OP7 ....... ¥15 ¥5 ...

Dilauroyl peroxide ............. UN3106 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76165

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

Dilauroyl peroxide [as a 

stable dispersion in 

water].

UN3109 ≤42 ................................... ...... ...... ...... ............ OP8 ....... ...... ......

Di-(3-methoxybutyl) 

peroxydicarbonate.

UN3115 ≤52 ................................... ...... ≥48 .. ...... ............ OP7 ....... ¥5 .. +5 ....

Di-(2-

methylbenzoyl)peroxide.

UN3112 ≤87 ................................... ...... ...... ...... ≥13 ........ OP5 ....... +30 +35 ..

Di-(4-

methylbenzoyl)peroxide 

[as a paste with silicone 

oil].

UN3106 ≤52 ................................... ...... ...... ...... ............ OP7 ....... ...... ......

Di-(3-methylbenzoyl) peroxide + Benzoyl (3-

methylbenzoyl) peroxide 

+ Dibenzoyl peroxide.

UN3115 ≤20+≤18+≤4 ..................... ...... ≥58 .. ...... ............ OP7 ....... +35 +40 ..

2,5-Dimethyl-2,5-di-

(benzoylperoxy)hexane.

UN3102 >82–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

2,5-Dimethyl-2,5-di-

(benzoylperoxy)hexane.

UN3106 ≤82 ................................... ...... ...... ≥18 .. ............ OP7 ....... ...... ......

2,5-Dimethyl-2,5-di-

(benzoylperoxy)hexane.

UN3104 ≤82 ................................... ...... ...... ...... ≥18 ........ OP5 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexane.UN3105 >52–100 ........................... ...... ...... ...... ............ OP7 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexane.UN3108 ≤77 ................................... ...... ...... ≥23 .. ............ OP8 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexane.UN3109 ≤52 ................................... ≥48 .. ...... ...... ............ OP8 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexane [as 

a paste].

UN3108 ≤47 ................................... ...... ...... ...... ............ OP8 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexyne-3.UN3101 >86–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexyne-3.UN3103 >52–86 ............................. ≥14 .. ...... ...... ............ OP5 ....... ...... ......

2,5-Dimethyl-2,5-di-(tertbutylperoxy)hexyne-3.UN3106 ≤52 ................................... ...... ...... ≥48 .. ............ OP7 ....... ...... ......

2,5-Dimethyl-2,5-di-(2-

ethylhexanoylperoxy)hexane.

UN3113 ≤100 ................................. ...... ...... ...... ............ OP5 ....... +20 +25 ..

2,5-Dimethyl-2,5-

dihydroperoxyhexane.

UN3104 ≤82 ................................... ...... ...... ...... ≥18 ........ OP6 ....... ...... ......

2,5-Dimethyl-2,5-di-(3,5,5-

trimethylhexanoylperoxy)hexane.

UN3105 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... ...... ......

1,1-Dimethyl-3-

hydroxybutylperoxyneoheptanoate.

UN3117 ≤52 ................................... ≥48 .. ...... ...... ............ OP8 ....... 0 ...... +10 ..

Dimyristyl 

peroxydicarbonate.

UN3116 ≤100 ................................. ...... ...... ...... ............ OP7 ....... +20 +25 ..

Dimyristyl 

peroxydicarbonate [as a 

stable dispersion in 

water].

UN3119 ≤42 ................................... ...... ...... ...... ............ OP8 ....... +20 +25 ..

Di-(2-

neodecanoylperoxyisopropyl)benzene.

UN3115 ≤52 ................................... ≥48 .. ...... ...... ............ OP7 ....... ¥10 0 ......

Di-n-nonanoyl peroxide ..... UN3116 ≤100 ................................. ...... ...... ...... ............ OP7 ....... 0 ...... +10 ..

Di-n-octanoyl peroxide ...... UN3114 ≤100 ................................. ...... ...... ...... ............ OP5 ....... +10 +15 ..

Di-(2-

phenoxyethyl)peroxydicarbonate.

UN3102 >85–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

Di-(2-

phenoxyethyl)peroxydicarbonate.

UN3106 ≤85 ................................... ...... ...... ...... ≥15 ........ OP7 ....... ...... ......

Dipropionyl peroxide ......... UN3117 ≤27 ................................... ...... ≥73 .. ...... ............ OP8 ....... +15 +20 ..

76166 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

Di-n-propyl 

peroxydicarbonate.

UN3113 ≤100 ................................. ...... ...... ...... ............ OP3 ....... ¥25 ¥15

Di-n-propyl 

peroxydicarbonate.

UN3113 ≤77 ................................... ...... ≥23 .. ...... ............ OP5 ....... ¥20 ¥10

Disuccinic acid peroxide ... UN3102 >72–100 ........................... ...... ...... ...... ............ OP4 ....... ...... ...... 18

Disuccinic acid peroxide ... UN3116 ≤72 ................................... ...... ...... ...... ≥28 ........ OP7 ....... +10 +15 ..

Di-(3,5,5-

trimethylhexanoyl)peroxide.

UN3115 >38–82 ............................. ≥18 .. ...... ...... ............ OP7 ....... 0 ...... +10 ..

Di-(3,5,5-

trimethylhexanoyl)peroxide [as a stable 

dispersion in water].

UN3119 ≤52 ................................... ...... ...... ...... ............ OP8 ....... +10 +15 ..

Di-(3,5,5-

trimethylhexanoyl)peroxide.

UN3119 ≤38 ................................... ≥62 .. ...... ...... ............ OP8 ....... +20 +25 ..

Ethyl 3,3-di-(tertamylperoxy)butyrate.UN3105 ≤67 ................................... ≥33 .. ...... ...... ............ OP7 ....... ...... ......

Ethyl 3,3-di-(tertbutylperoxy)butyrate.UN3103 >77–100 ........................... ...... ...... ...... ............ OP5 ....... ...... ......

Ethyl 3,3-di-(tertbutylperoxy)butyrate.UN3105 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... ...... ......

Ethyl 3,3-di-(tertbutylperoxy)butyrate.UN3106 ≤52 ................................... ...... ...... ≥48 .. ............ OP7 ....... ...... ......

1-(2-ethylhexanoylperoxy)-

1,3-Dimethylbutyl 

peroxypivalate.

UN3115 ≤52 ................................... ≥45 .. ≥10 .. ...... ............ OP7 ....... ¥20 ¥10

tert-Hexyl 

peroxyneodecanoate.

UN3115 ≤71 ................................... ≥29 .. ...... ...... ............ OP7 ....... 0 ...... +10 ..

tert-Hexyl peroxypivalate .. UN3115 ≤72 ................................... ...... ≥28 .. ...... ............ OP7 ....... +10 +15 ..

Isopropyl sec-butyl 

peroxydicarbonat +Disec-butyl 

peroxydicarbonate+Diisopropyl 

peroxydicarbonate.

UN3111 ≤52+≤28+≤22 ................... ...... ...... ...... ............ OP5 ....... ¥20 ¥10

Isopropyl sec-butyl 

peroxydicarbonate+Disec-butyl 

peroxydicarbonate+Diisopropyl 

peroxydicarbonate.

UN3115 ≤32+≤15¥18+≤12¥15 .... ≥38 .. ...... ...... ............ OP7 ....... ¥20 ¥10

Isopropylcumyl 

hydroperoxide.

UN3109 ≤72 ................................... ≥28 .. ...... ...... ............ OP8 ....... ...... ...... 13

p-Menthyl hydroperoxide .. UN3105 > 72–100 .......................... ...... ...... ...... ............ OP7 ....... ...... ...... 13

p-Menthyl hydroperoxide .. UN3109 ≤72 ................................... ≥28 .. ...... ...... ............ OP8 ....... ...... ......

Methylcyclohexanone peroxide(s).UN3115 ≤67 ................................... ...... ≥33 .. ...... ............ OP7 ....... +35 +40 ..

Methyl ethyl ketone peroxide(s).UN3101 ≤52 ................................... ≥48 .. ...... ...... ............ OP5 ....... ...... ...... 5, 13, 29

Methyl ethyl ketone peroxide(s).UN3105 ≤45 ................................... ≥55 .. ...... ...... ............ OP7 ....... ...... ...... 5, 29

Methyl ethyl ketone peroxide(s).UN3107 ≤40 ................................... ≥60 .. ...... ...... ............ OP8 ....... ...... ...... 7

Methyl isobutyl ketone peroxide(s).UN3105 ≤62 ................................... ≥19 .. ...... ...... ............ OP7 ....... ...... ...... 5, 23

Organic peroxide, liquid, 

sample.

UN3103 ....................................... ...... ...... ...... ............ OP2 ....... ...... ...... 12

Organic peroxide, liquid, 

sample, temperature 

controlled.

UN3113 ....................................... ...... ...... ...... ............ OP2 ....... ...... ...... 12

Organic peroxide, solid, 

sample.

UN3104 ....................................... ...... ...... ...... ............ OP2 ....... ...... ...... 12

Organic peroxide, solid, 

sample, temperature 

controlled.

UN3114 ....................................... ...... ...... ...... ............ OP2 ....... ...... ...... 12

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76167

ORGANIC PEROXIDE TABLE—Continued

Technical name ID number Concentration (mass %) 

Diluent (mass %) 

Water 

(mass %) 

Packing 

method 

Temperature 

(°C) 

Notes 

A B I Control Emergency 

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) 

Peroxyacetic acid, type D, 

stabilized.

UN3105 ≤43 ................................... ...... ...... ...... ............ OP7 ....... ...... ...... 13, 20

Peroxyacetic acid, type E, 

stabilized.

UN3107 ≤43 ................................... ...... ...... ...... ............ OP8 ....... ...... ...... 13, 20

Peroxyacetic acid, type F, 

stabilized.

UN3109 ≤43 ................................... ...... ...... ...... ............ OP8 ....... ...... ...... 13, 20, 

28

Peroxyacetic acid or peracetic acid [with not 

more than 7% hydrogen 

peroxide].

UN3107 ≤36 ................................... ...... ...... ...... ≥15 ........ OP8 ....... ...... ...... 13, 20, 

28, 29

Peroxyacetic acid or peracetic acid [with not 

more than 20% hydrogen peroxide].

Exempt .. ≤6 ..................................... ...... ...... ...... ≥60 ........ Exempt .. ...... ...... 28, 29

Peroxyacetic acid or peracetic acid [with not 

more than 26% hydrogen peroxide].

UN3109 ≤17 ................................... ...... ...... ...... ............ OP8 ....... ...... ...... 13, 20, 

28, 29

Peroxylauric acid .............. UN3118 ≤100 ................................. ...... ...... ...... ............ OP8 ....... +35 +40 ..

Pinanyl hydroperoxide ...... UN3105 >56–100 ........................... ...... ...... ...... ............ OP7 ....... ...... ...... 13

Pinanyl hydroperoxide ...... UN3109 ≤56 ................................... ≥44 .. ...... ...... ............ OP8 ....... ...... ......

Polyether poly-tertbutylperoxycarbonate.UN3107 ≤52 ................................... ...... ≥48 .. ...... ............ OP8 ....... ...... ......

Tetrahydronaphthyl 

hydroperoxide.

UN3106 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

1,1,3,3-Tetramethylbutyl 

hydroperoxide.

UN3105 ≤100 ................................. ...... ...... ...... ............ OP7 ....... ...... ......

1,1,3,3-Tetramethylbutyl 

peroxy-2-ethylhexanoate.

UN3115 ≤100 ................................. ...... ...... ...... ............ OP7 ....... +15 +20 ..

1,1,3,3-Tetramethylbutyl 

peroxyneodecanoate.

UN3115 ≤72 ................................... ...... ≥28 .. ...... ............ OP7 ....... -5 .... +5 ....

1,1,3,3-Tetramethylbutyl 

peroxyneodecanoate [as 

a stable dispersion in 

water].

UN3119 ≤52 ................................... ...... ...... ...... ............ OP8 ....... ¥5 .. +5 ....

1,1,3,3-tetramethylbutyl 

peroxypivalate.

UN3115 ≤77 ................................... ≥23 .. ...... ...... ............ OP7 ....... 0 ...... +10 ..

3,6,9-Triethyl-3,6,9-

trimethyl-1,4,7-

triperoxonane.

UN3105 ≤42 ................................... ≥58 .. ...... ...... ............ OP7 ....... ...... ...... 26

BILLING CODE 4910–60–S

Notes 

1. For domestic shipments, OP8 is 

authorized. 

2. Available oxygen must be <4.7%. 

3. For concentrations <80% OP5 is 

allowed. For concentrations of at least 80% 

but <85%, OP4 is allowed. For 

concentrations of at least 85%, maximum 

package size is OP2. 

4. The diluent may be replaced by di-tertbutyl peroxide. 

5. Available oxygen must be ≤9% with or 

without water. 

6. For domestic shipments, OP5 is 

authorized. 

7. Available oxygen must be ≤8.2% with or 

without water. 

8. Only non-metallic packagings are 

authorized. 

9. For domestic shipments this material 

maybe transported under the provisions of 

paragraph (h)(3)(xii) of this section. 

10. [Reserved] 

11. [Reserved] 

12. Samples may only be offered for 

transportation under the provisions of 

paragraph (c)(2) of this section. 

13. ‘‘Corrosive’’ subsidiary risk label is 

required. 

14. [Reserved] 

15. No ‘‘Corrosive’’ subsidiary risk label is 

required for concentrations below 80%. 

16. With <6% di-tert-butyl peroxide. 

17. With ≥8% 1-isopropylhydroperoxy-4-

isopropylhydroxybenzene. 

18. Addition of water to this organic 

peroxide will decrease its thermal stability. 

19. [Reserved] 

20. Mixtures with hydrogen peroxide, 

water and acid(s). 

21. With diluent type A, with or without 

water. 

22. With ≥36% diluent type A by mass, 

and in addition ethylbenzene. 

23. With ≥19% diluent type A by mass, 

and in addition methyl isobutyl ketone. 

24. Diluent type B with boiling point >100 

C. 

25. No ‘‘Corrosive’’ subsidiary risk label is 

required for concentrations below 56%. 

26. Available oxygen must be ≤7.6%. 

27. Formulations derived from distillation 

of peroxyacetic acid originating from 

peroxyacetic acid in a concentration of not 

more than 41% with water, total active 

oxygen less than or equal to 9.5% 

(peroxyacetic acid plus hydrogen peroxide). 

28. For the purposes of this section, the 

names ‘‘Peroxyacetic acid’’ and ‘‘Peracetic 

acid’’ are synonymous. 

29. For international transportation, 

shipments of this material must be 

accompanied by a Competent Authority 

approval from the Associate Administrator.

(d) Packing Method Table. Packagings 

for organic peroxides and self-reactive 

substances are listed in the Maximum 

76168 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

Quantity per Packing Method Table. 

The packing methods are designated 

OP1 to OP8. The quantities specified for 

each packing method represent the 

maximum that is authorized. 

(1) The following types of packagings 

are authorized: 

(i) Drums: 1A1, 1A2, 1B1, 1B2, 1D, 

1G, 1H1, 1H2; 

(ii) Jerricans: 3A1, 3A2, 3B1, 3B2, 

3H1, 3H2; 

(iii) Boxes: 4C1, 4C2, 4D, 4F, 4G, 4H1, 

4H2, 4A, 4B; or 

(iv) Composite packagings with a 

plastic inner receptacle: 6HA1, 6HA2, 

6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 

6HG2, 6HH1, 6HH2. 

(2) Metal packaging (including inner 

packagings of combination packagings 

and outer packagings of combination or 

composite packagings) are used only for 

packing methods OP7 and OP8. 

(3) In combination packagings, glass 

receptacles are used only as inner 

packagings with a maximum content of 

0.5 kg for solids or 0.5 L for liquids. 

(4) The maximum quantity per 

packaging or package for Packing 

Methods OP1–OP8 must be as follows:

MAXIMUM QUANTITY PER PACKAGING/PACKAGE

[For Packing Methods OP1 to OP8] 

Maximum quantity 

Packing Method 

OP1 OP2 OP3 OP4 1 OP5 OP6 OP7 OP8 

Solids and combination packagings (liquid and 

solid) (kg) ...................................................... 0.5 0.5/10 5 5 25 50 50 2 400 

Liquids (L) ........................................................ 0.5 ................ 5 ................ 30 60 60 3 225 

1 If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package. 2 60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 

4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg. 3 60 L for jerricans. 

(e) Organic Peroxide IBC Table. The 

following Organic Peroxide IBC Table 

specifies, by technical name, those 

organic peroxides that are authorized for 

transportation in certain IBCs and not 

subject to the approval provisions of 

§ 173.128 of this part. Additional 

requirements for authorized IBCs are 

found in paragraph (f) of this section.

ORGANIC PEROXIDE IBC TABLE

UN No. Organic peroxide Type of IBC Maximum 

quantity (litres) 

Control temperature Emergency 

temperature 

3109 ................................. ORGANIC PEROXIDE, TYPE F, LIQUID.

tert-Butyl hydroperoxide, not more than 72% with 

water.

31A 1250

tert-Butyl peroxyacetate, not more than 32% in diluent type A.31A 1250

............................................................................... 31HA1 1000

tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more 

than 32% in diluent type A.

31A 1250

............................................................................... 31HA1 1000 

Cumyl hydroperoxide, not more than 90% in diluent 

type A.

31HA1 1250 

Dibenzoyl peroxide, not more than 42% as a stable 

dispersion.

31H1 1000

Di-tert-butyl peroxide, not more than 52% in diluent 

type B.

31A 1250

............................................................................... 31HA1 1000 

1,1-Di-(tert-butylperoxy) cyclohexane, not more 

than 42% in diluent type A.

31H1 1000 

Dicumyl peroxide, less than or equal to 100% ......... 31A 1250 

............................................................................... 31HA1 1000 

Dilauroyl peroxide, not more than 42%, stable dispersion, in water.31HA1 1000

Isopropyl cumyl hydroperoxide, not more than 72% 

in diluent type A.

31HA1 1250

p-Menthyl hydroperoxide, not more than 72% in diluent type A.31HA1 1250 

Peroxyacetic acid, stabilized, not more than 17% ... 31H1 1500 

............................................................................... 31HA1 1500 

............................................................................... 31A 1500 

Peroxyacetic acid, with not more than 26% hydrogen peroxide.31A 1500 

............................................................................... 31HA1 1500 

Peroxyacetic acid, type F, stabilized ........................ 31A 1500 

................................................................................... 31HA1 1500 

3110 ................................. ORGANIC PEROXIDE TYPE F, SOLID.

Dicumyl peroxide, less than or equal to 100% ......... 31A 2000 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76169

ORGANIC PEROXIDE IBC TABLE—Continued

UN No. Organic peroxide Type of IBC Maximum 

quantity (litres) 

Control temperature Emergency 

temperature 

............................................................................... 31H1 

............................................................................... 31HA1 

3119 ................................. ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED.

tert-Butyl peroxy-2-ethylhexanoate, not more than 

32% in diluent type B.

31HA1 1000 +30 °C +35 °C 

............................................................................... 31A 1250 +30 °C +35 °C 

tert-Butyl peroxyneodecanoate, not more than 32% 

in diluent type A.

31A 1250 0 °C +10 °C 

tert-Butyl peroxyneodecanoate, not more than 42% 

stable dispersion, in water.

31A 1250 ¥5 °C +5 °C 

tert-Butyl peroxypivalate, not more than 27% in diluent type B.31HA1 1000 +10 °C +15 °C 

............................................................................... 31A 1250 +10 °C +15 °C 

Cumyl peroxyneodecanoate, not more than 52%, 

stable dispersion, in water.

31A 1250 ¥15 °C ¥5 °C 

Dicyclohexylperoxydicarbonate, not more than 42% 

as a stable dispersion, in water.

31A 1250 +10 °C +15 °C 

Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not 

more than 42%, stable dispersion, in water.

31HA1 1000 +30 °C +35 °C 

Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water.31HA1 1000 +30 °C +35 °C 

Di-(2-ethylhexyl) peroxydicarbonate, not more than 

52%, stable dispersion, in water.

31A 1250 ¥20 °C ¥10 °C 

Dimyristyl peroxydicarbonate, not more than 42%, 

stable dispersion, in water.

31HA1 1000 +15 °C +20 °C 

Di-(3,5,5-trimethylhexanoyl) peroxide, not more 

than 38% in diluent type A.

31HA1 1000 +10 °C +15 °C 

............................................................................... 31A 1250 +10 °C +15 °C 

Di-(3,5,5-trimethylhexanoyl) peroxide, not more 

than 52%, stable dispersion, in water.

31A 1250 +10 °C +15 °C 

1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not 

more than 52%, stable dispersion, in water.

31A 1250 ¥5 °C +5 °C 

(f) IBCs. IBCs are authorized subject to 

the conditions and limitations of this 

section if the IBC type is authorized 

according to paragraph (e) of this 

section, as applicable, and the IBC 

conforms to the requirements in subpart 

O of part 178 of this subchapter at the 

Packing Group II performance level. 

Type F organic peroxides or selfreactive substances are not authorized 

for transportation in IBCs other than 

those specified, unless approved by the 

Associate Administrator. 

(1) IBCs shall be provided with a 

device to allow venting during 

transportation. The inlet to the pressure 

relief device shall be sited in the vapor 

space of the IBC under maximum filling 

conditions during transportation. 

(2) To prevent explosive rupture of 

metal IBCs or composite IBCs with a 

complete metal casing, the emergencyrelief devices shall be designed to vent 

all the decomposition products and 

vapors evolved during self-accelerating 

decomposition or during a period of not 

less than one hour of complete fireengulfment as calculated by the formula 

in paragraph (h)(3)(v) of this section. 

The control and emergency 

temperatures specified in the Organic 

Peroxide IBC Table are based on a noninsulated IBC. 

(g) Organic Peroxide Portable Tank 

Table. The following Organic Peroxide 

Portable Tank Table provides certain 

portable tank requirements and 

identifies, by technical name, those 

organic peroxides that are authorized for 

transportation in the bulk packagings 

listed in paragraph (h). Organic 

peroxides listed in this table, provided 

they meet the specific packaging 

requirements found in paragraph (h), are 

not subject to the approval provisions of 

§ 173.128 of this part.

76170 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

ORGANIC

PEROXIDE

PORTABLE

TANK

TABLE

UN No. Hazardous material 

Minimum 

test pressure (bar) 

Minimum shell 

thickness (mm-reference steel)

See. . . 

Bottom opening requirements

See. . . 

Pressure-relief requirements 

See. . . 

Filling limits Control temperature Emergency temperature 

3109 ..... ORGANIC PEROXIDE, TYPE 

F, LIQUID.

tert-Butyl hydroperoxide, not 

more than 72% with water.

*Provided that steps have been 

taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

Cumyl hydro-peroxide, not 

more than 90% in diluent type A.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

Di-tert-butyl peroxide, not more 

32% in diluent type A.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

Dicumyl peroxide, less than or 

equal to 100% in diluent type B.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

Isopropyl cumyl hydroperoxide, 

not more 72% in diluent type A.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

p-Menthyl hydro-peroxide, not 

more 72% in diluent type A.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

Pinanyl hydro-peroxide, not 

more than 56% in diluent type A.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

3110 ..... ORGANIC PEROXIDE, TYPE 

F, SOLID.

Dicumyl peroxide less than or 

equal to 100% with inert solids.

*Maximum quantity per portable 

tank 2,000 kg.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

3119 ..... ORGANIC PEROXIDE, TYPE 

F, LIQUID, TEMPERATURE CONTROLLED.

tert-Butyl peroxyacetate, not 

more than 32% in diluent type B.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

+30 °C +35 °C 

tert-Butyl peroxy-2-

ethylhexanoate, not more than 32% in diluent B.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

+15 °C +20 °C 

tert-Butylperoxypivalate, not 

more than 27% in diluent type B.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

+5 °C +10 °C 

tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 

32% in diluent type B.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

+35 °C +40 °C 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76171

Di-(3,5,5-trimethyl-hexanoyl) 

peroxide, not more than 38% in diluent type A.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

0 °C +5 °C 

Peroxyacetic acid, distilled, stabilized, not more than 41%.

4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 

90% at 59 °F (15 °C) 

+30 °C +35 °C 

76172 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

(h) Bulk packagings other than IBCs.

The following bulk packagings are 

authorized, subject to the conditions 

and limitations of this section, if the 

organic peroxide is listed in the Organic 

Peroxide Portable Tank Table and bulk 

packagings are authorized, or if the 

organic peroxide is specifically 

authorized for transport in a bulk 

packaging by this paragraph (h), and the 

bulk packaging conforms to the 

requirements of this subchapter: 

(1) Rail cars. Class DOT 103, 104, 105, 

109, 111, 112, 114, 115, or 120 fusionweld tank car tanks are authorized. DOT 

103W, 111A60F1 and 111A60W1 tank 

car tanks must have bottom outlets 

effectively sealed from inside. Gauging 

devices are required on DOT 103W tank 

car tanks. Riveted tank car tanks are not 

authorized. 

(2) Cargo tanks. Specification MC 307, 

MC 310, MC 311, MC 312, DOT 407, 

and DOT 412 cargo tank motor vehicles 

with a tank design pressure of at least 

172 kPa (25 psig) are authorized. 

(3) Portable tanks. The following 

requirements apply to portable tanks 

intended for the transport of organic 

peroxides or self-reactive substances. 

DOT 51, 57, IM 101 portable tanks, and 

UN portable tanks that conform to the 

requirements of paragraph (g) of this 

section, are authorized. Type F organic 

peroxide or self-reactive substance 

formulations other than those indicated 

in the Organic Peroxide Portable Tank 

Table may be transported in portable 

tanks if approved by the Associate 

Administrator. The following conditions 

also apply: 

(i) The portable tank must be designed 

for a test pressure of at least 0.4 MPa (4 

bar). 

(ii) The portable tank must be fitted 

with temperature-sensing devices. 

(iii) The portable tank must be fitted 

with pressure relief devices and 

emergency-relief devices. Vacuum-relief 

devices may also be used. Pressure relief 

devices must operate at pressures 

determined according to both the 

properties of the hazardous material and 

the construction characteristics of the 

portable tank. Fusible elements are not 

allowed in the shell. 

(iv) The pressure relief devices must 

consist of reclosing devices fitted to 

prevent significant build-up within the 

portable tank of the decomposition 

products and vapors released at a 

temperature of 50 °C (122 °F). The 

capacity and start-to-discharge pressure 

of the relief devices must be in 

accordance with the applicable 

requirements of this subchapter 

specified for the portable tank. The 

pressure relief devices must not allow 

liquid to escape in the event the 

portable tank is overturned in a loaded 

condition. 

(v)(A) The emergency-relief devices 

may be of the reclosing or frangible 

types, or a combination of the two, 

designed to vent all the decomposition 

products and vapors evolved during a 

period of not less than one hour of 

complete fire engulfment as calculated 

by the following formula:

q = 70961 F A0.82

Where: 

q = heat absorption (W) 

A = wetted area (m2) 

F = insulation factor (¥)

(B) Insulation factor (F) in the formula 

in paragraph (h)(3)(v)(A) of this section 

equals 1 for non-insulated vessels and 

for insulated vessels F is calculated 

using the following formula:

F

TPO = U 923 ( ) −

47032

Where: 

U = K/L = heat transfer coefficient of the 

insulation (W·m¥2·K¥1); where K = 

heat conductivity of insulation 

layer (W·m¥1·K¥1), and L = 

thickness of insulation layer (m). 

TPO = temperature of material at 

relieving conditions (K).

(vi) The start-to-discharge pressure of 

emergency-relief devices must be higher 

than that specified for the pressure relief 

devices in paragraph (h)(3)(iv) of this 

section. The emergency-relief devices 

must be sized and designed in such a 

way that the maximum pressure in the 

shell never exceeds the test pressure of 

the portable tank.

Note to Paragraph (h)(3)(vi): An example 

of a method to determine the size of 

emergency-relief devices is given in 

Appendix 5 of the UN Manual of Tests and 

Criteria (IBR, see § 171.7 of this subchapter). 

A second example of a test method for 

venting sizing is given in the American 

Institute of Chemical Engineers Process 

Safety Progress Journal, June 2002 issue (Vol. 

21, No. 2) (Informational materials not 

requiring incorporation by reference, see 

§ 171.7(b)).

(vii) For insulated portable tanks, the 

capacity and setting of emergency-relief 

devices must be determined assuming a 

loss of insulation from 1% of the surface 

area. 

(viii) Vacuum-relief devices and 

reclosing devices on portable tanks used 

for flammable hazardous materials must 

be provided with flame arresters. Any 

reduction of the relief capacity caused 

by the flame arrester must be taken into 

account and the appropriate relief 

capacity must be provided. 

(ix) Service equipment such as 

devices and external piping must be 

designed and constructed so that no 

hazardous material remains in them 

after filling the portable tank. 

(x) Portable tanks may be either 

insulated or protected by a sun-shield. 

If the SADT of the hazardous material 

in the portable tank is 55 °C (131 °F) or 

less, the portable tank must be 

completely insulated. The outer surface 

must be finished in white or bright 

metal. 

(xi) The degree of filling must not 

exceed 90% at 15 °C (59 °F). 

(xii) DOT 57 metal portable tanks are 

authorized only for tert-butyl cumyl 

peroxide, di-(2-tertbutylperoxyisopropyl-benzene(s)), 

dicumyl peroxide and mixtures of two 

or more of these peroxides. DOT 57 

portable tanks must conform to the 

venting requirements of paragraph (f) of 

this section. These portable tanks are 

not subject to any other requirements of 

paragraph (h) of this section. 

(4) For tertiary butyl hydroperoxide 

(TBHP), each tank car, cargo tank or 

portable tank must contain 7.6 cm (3.0 

inches) low density polyethylene (PE) 

saddles having a melt index of at least 

0.2 grams per 10 minutes (for example 

see, ASTM D1238, condition E) as part 

of the lading, with a ratio of PE to TBHP 

over a range of 0.008 to 0.012 by mass. 

Alternatively, plastic or metal 

containers equipped with fusible plugs 

having a melting point between 69 °C 

(156 °F) and 71 °C (160 °F) and filled 

with a sufficient quantity of water to 

dilute the TBHP to 65% or less by mass 

may be used. The PE saddles must be 

visually inspected after each trip and, at 

a minimum, once every 12 months, and 

replaced when discoloration, fracture, 

severe deformation, or other indication 

of change is noted.

■ 43. Section 173.226 is revised to read 

as follows:

§ 173.226 Materials poisonous by 

inhalation, Division 6.1, Packing Group I, 

Hazard Zone A. 

Division 6.1, Packing Group I, Zone A 

poisonous by inhalation (see § 173.133) 

must be packed in non-bulk packagings 

in accordance with the following 

paragraphs: 

(a) In seamless specification cylinders 

conforming to the requirements of 

§ 173.40. 

(b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 

drums further packed in a 1A2 or 1H2 

drum. Both inner and outer drums must 

conform to the performance test 

requirements of subpart M of part 178 

of this subchapter at the Packing Group 

I performance level. The outer drums 

may be tested either as a package 


ER20DE04.002</MATH> ER20DE04.003</MATH>
Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76173

intended to contain inner packagings 

(combination package) or as a single 

packaging intended to contain solids or 

liquids at a mass corresponding to the 

mass of the assembled packaging 

system. All outer drums, even those 

tested to contain inner packaging or as 

single packagings for solids, must 

withstand a hydrostatic test pressure of 

100 kPa (15 psig). The outer drum must 

have a minimum thickness of 1.35 mm 

(0.053 inch) for a 1A2 outer drum or 6.3 

mm (0.248 inch) for a 1H2 outer drum. 

In addition, the inner drum must—

(1) Be capable of satisfactorily 

withstanding the hydrostatic pressure 

test in § 178.605 of this subchapter at a 

test pressure of 300 kPa (45 psig); 

(2) Satisfactorily withstand the 

leakproofness test in § 178.604 of this 

subchapter using an internal air 

pressure of at least twice the vapor 

pressure at 55 °C (131 °F) of the material 

to be packaged; 

(3) Have screw-type closures that 

are—

(i) Closed and tightened to a torque 

prescribed by the closure manufacturer, 

using a properly calibrated device that 

is capable of measuring torque; 

(ii) Physically held in place by any 

means capable of preventing back-off or 

loosening of the closure by impact or 

vibration during transportation; and 

(iii) Provided with a cap seal that is 

properly applied in accordance with the 

cap seal manufacturer’s 

recommendations and is capable of 

withstanding an internal pressure of at 

least 100 kPa (15 psig). 

(4) Have a minimum thickness as 

follows: 

(i) For a 1A1 or 1N1 drum, 1.3 mm 

(0.051 inch); 

(ii) For a 1B1 drum, 3.9 mm (0.154 

inch); 

(iii) For a 1H1 drum, 3.16 mm (0.124 

inch); and 

(iv) For a 6HA1 drum, the plastic 

inner container shall be 1.58 mm 

(0.0622 inch) and the outer steel drum 

shall be 0.96 mm (0.0378 inch). 

(5) Be isolated from the outer drum by 

a shock-mitigating, non-reactive 

material, which completely surrounds 

the inner packaging on all sides. 

(c) In combination packagings, 

consisting of an inner packaging system 

and an outer packaging, as follows: 

(1) Outer packagings:

Steel drum: 1A2 

Aluminum drum: 1B2 

Metal drum, other than steel or 

aluminum: 1N2 

Plywood drum: 1D 

Fiber drum: 1G 

Plastic drum: 1H2 

Steel box: 4A 

Aluminum box: 4B 

Natural wood box: 4C1 or 4C2 

Plywood box: 4D 

Reconstituted wood box: 4F 

Fiberboard box: 4G 

Expanded plastic box: 4H2 

Solid plastic box: 4H2 

(2) Inner packaging system. The inner 

packaging system consists of two 

packagings: 

(i) an impact-resistant receptacle of 

glass, earthenware, plastic or metal 

securely cushioned with a non-reactive, 

absorbent material, and 

(A) Capacity of each inner receptacle 

may not exceed 4 L (1 gallon). 

(B) An inner receptacle that has a 

closure must have a closure which is 

physically held in place by any means 

capable of preventing back-off or 

loosening of the closure by impact or 

vibration during transportation. 

(ii) Packed within a leak-tight 

packaging of metal or plastic. 

(iii) This combination packaging in 

turn is packed within the outer 

packaging.

(A) The total amount of liquid 

contained in the outer packaging may 

not exceed 16 L (4 gallons). 

(iv) the inner packaging system must 

conform to the performance test 

requirements of subpart M of part 178 

of this subchapter, at the Packaging 

Group I performance level when 

subjected to the following tests: 

(A) § 178.603—Drop Test 

(B) § 178.604—Leakproofness Test 

(C) § 178.605—Hydrostatic Pressure 

Test 

(v) The inner packaging system must 

meet the above tests without the benefit 

of the outer packaging. 

(vi) The leakproofness and hydrostatic 

pressure test may be conducted on 

either the inner receptacle or the outer 

packaging of the inner packaging 

system. 

(vii) In addition to the requirements 

in § 173.226(b), the outer package must 

conform to the performance test 

requirements of subpart M of part 178 

of this subchapter, at the Packaging 

Group I performance level as applicable 

for the type of package being used. 

(d) If approved by the Associate 

Administrator, 1A1, 1B1, 1H1, 1N1, 

6HA1 or 6HH1 drums described in 

paragraph (b) of this section may be 

used without being further packed in a 

1A2 or 1H2 drum if the shipper loads 

the material, palletizes the drums, 

blocks and braces the drums within the 

transport vehicle and seals the transport 

vehicle used. Drums may not be stacked 

(double decked) within the transport 

vehicle. Shipments must be from one 

origin to one destination only without 

any intermediate pickup or delivery. 

(e) Prior to reuse, all authorized inner 

drums must be leakproofness tested and 

marked in accordance with § 173.28 

using a minimum test pressure as 

indicated in paragraph (b)(2) of this 

section.

■ 44. Section 173.227 is revised to read 

as follows:

§ 173.227 Materials poisonous by 

inhalation. Division 6.1, Packing Group I, 

Hazard Zone B. 

(a) In packagings as authorized in 

§ 173.226 and seamless and welded 

specification cylinders conforming to 

the requirements of § 173.40. 

(b) 1A1, 1B1, 1N1 or 1H1 drum or 

6HA1 composite further packed in a 

1A2 or 1H2 drum. Both the inner and 

outer drums must conform to the 

performance test requirements of 

subpart M of part 178 of this subchapter 

at the Packing Group I performance 

level. The outer drums may be tested 

either as a package intended to contain 

inner packagings (combination package) 

or as a single packaging intended to 

contain solids or liquids at a mass 

corresponding to the mass of the 

assembled packaging system. The outer 

drum must have a minimum thickness 

of 1.35 mm (0.053 inches) for a 1A2 

outer drum or 6.30 mm (0.248 inches) 

for a 1H2 outer drum. Outer 1A2 and 

1H2 drums must withstand a 

hydrostatic test pressure of 100 kPa (15 

psig). Capacity of the inner drum may 

not exceed 220 liters. In addition, the 

inner drum must conform to all of the 

following requirements: 

(2) Have screw closures that are—

(i) Closed and tightened to a torque 

prescribed by the closure manufacturer, 

using a properly calibrated device that 

is capable of measuring torque; 

(ii) Physically held in place by any 

means capable of preventing back-off or 

loosening of the closure by impact or 

vibration during transportation; and 

(iii) Provided with a cap seal that is 

properly applied in accordance with the 

cap seal manufacturer’s 

recommendations and is capable of 

withstanding an internal pressure of at 

least 100 kPa (15 psig). 

(3) Have a minimum thickness as 

follows: 

(i) For a 1A1 drum, 0.69 mm (0.027 

inch); 

(ii) For a 1B1 drum, 2.79 mm (0.110 

inch); 

(iii) For a 1H1 drum, 1.14 mm (0.045 

inch); or 

(iv) For a 6HA1 drum, the plastic 

inner container shall be 1.58 mm 

(0.0625 inch), the outer steel drum shall 

be 0.70 mm (0.027 inch). 

(4) Be isolated from the outer drum by 

a shock-mitigating, non-reactive 

76174 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

material which completely surrounds 

the inner packaging on all sides. 

(5) Prior to reuse, all authorized inner 

drums must be leakproofness tested and 

marked in accordance with § 173.28 

using a minimum test pressure as 

indicated in paragraph (b)(1) of this 

section. 

(c) 1A1, 1B1, 1H1, 1N1, 6HA1 or 

6HH1 drums described in paragraph (b) 

of this section may be used without 

being further packed in a 1A2 or 1H2 

drum if the shipper loads the material, 

blocks and braces the drums within the 

transport vehicle and seals the transport 

vehicle used. Drums may not be stacked 

(double decked) within the transport 

vehicle. Shipments must be from one 

origin to one destination only without 

any intermediate pickup or delivery.

■ 45. In § 173.249, paragraph (c) is 

revised to read as follows:

§ 173.249 Bromine.

* * * * *

(c) UN portable tanks conforming to 

tank code T22 (see § 172.102 of this 

subchapter) or specification IM 101 

portable tanks conforming with 

paragraphs (d) through (f) of this 

section. Except when transported as a 

residue, the total quantity in one tank 

may not be less than 88% nor more than 

92% of the volume of the tank.

* * * * *

■ 46. In § 173.306, paragraphs (i) and (j) 

are removed and a new paragraph (i) is 

added to read as follows:

§ 173.306 Limited quantities of 

compressed gases.

* * * * *

(i) Aerosols with a capacity of less 

than 50 ml. Aerosols, as defined in 

§ 171.8 of this subchapter, with a 

capacity not exceeding 50 ml and with 

a pressure not exceeding 970 kPa (141 

psig) at 55 °C (131 °F), containing no 

hazardous materials other than a 

Division 2.2 gas, are not subject to the 

requirements of this subchapter.

* * * * *

§ 173.307 [Amended]

■ 47. In § 173.307, paragraph (a)(5) is 

removed.

■ 48. Section 173.313 is added to read as 

follows:

§ 173.313 UN Portable Tank Table for 

Liquefied Compressed Gases. 

The UN Portable Tank Table for 

Liquefied Compressed Gases is 

referenced in § 172.102(c)(7)(iii) of this 

subchapter for portable tanks that are 

used to transport liquefied compressed 

gases. The table applies to each 

liquefied compressed gas that is 

identified with Special Provision T50 in 

Column (7) of the § 172.101 Table. In 

addition to providing the UN 

identification number and proper 

shipping name, the table provides 

maximum allowable working pressures, 

bottom opening requirements, pressure 

relief device requirements, and degree 

of filling requirements for liquefied 

compressed gas permitted for 

transportation in a T50 portable tank. In 

the minimum test pressure column, 

‘‘small’’ means a portable tank with a 

diameter of 1.5 meters or less when 

measured at the widest part of the shell, 

‘‘sunshield’’ means a portable tank with 

a shield covering at least the upper third 

of the shell, ‘‘bare’’ means no sunshield 

or insulation is provided, and 

‘‘insulated’’ means a complete cladding 

of sufficient thickness of insulating 

material necessary to provide a 

minimum conductance of not more than 

0.67 w/m2/k. In the pressure relief 

requirements column, the word 

‘‘Normal’’ denotes that a frangible disc 

as specified in § 178.276(e)(3) of this 

subchapter is not required.

UN PORTABLE TANK TABLE FOR LIQUEFIED COMPRESSED GASES

UN No. Non-refrigerated liquefied compressed gases 

Minimum design 

pressure (bar) 

small; bare; 

sunshield; insulated 

Openings 

below liquid 

level 

Pressure relief requirements (See

§ 178.276(e)) 

Maximum filling density 

(kg/l) 

1005 ....... Ammonia, anhydrous ........................................................... 29.0 Allowed § 178.276(e)(3) 0.53

25.7

22.0

19.7

1009 ....... Bromotrifluoromethane or Refrigerant gas R 13B1 ............. 38.0 Allowed Normal 1.13

34.0 

30.0 

27.5 

1010 ....... Butadienes, stabilized .......................................................... 7.5 Allowed Normal 0.55

7.0 

7.0 

7.0 

1011 ....... Butane .................................................................................. 7.0 Allowed Normal 0.51

7.0 

7.0 

7.0 

1012 ....... Butylene ............................................................................... 8.0 Allowed Normal 0.53

7.0 

7.0 

7.0 

1017 ....... Chlorine ................................................................................ 19.0 Not § 178.276(e)(3) 1.25

17.0 Allowed 

15.0 

13.5 

1018 ....... Chlorodifluoromethane or Refrigerant gas R 22 .................. 26.0 Allowed Normal 1.03

24.0 

21.0 

19.0 

1020 ....... Chloropentafluoroethane or Refrigerant gas R 115 ............. 23.0 Allowed Normal 1.06

20.0 

18.0 

16.0 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76175

UN PORTABLE TANK TABLE FOR LIQUEFIED COMPRESSED GASES—Continued

UN No. Non-refrigerated liquefied compressed gases 

Minimum design 

pressure (bar) 

small; bare; 

sunshield; insulated 

Openings 

below liquid 

level 

Pressure relief requirements (See

§ 178.276(e)) 

Maximum filling density 

(kg/l) 

1021 ....... 1-Chloro-1,2,2,2-tetrafluoroethane or Refrigerant gas R 

124.

10.3 Allowed Normal 1.2

9.8 

7.9 

7.0 

1027 ....... Cyclopropane ....................................................................... 18.0 Allowed Normal 0.53

16.0 

14.5 

13.0 

1028 ....... Dichlorodifluoromethane or Refrigerant gas R 12 ............... 16.0 Allowed Normal 1.15

15.0 

13.0 

11.5 

1029 ....... Dichlorofluoromethane or Refrigerant gas R 21 .................. 7.0 Allowed Normal 1.23

7.0 

7.0 

7.0 

1030 ....... 1,1-Difluoroethane or Refrigerant gas R 152a ..................... 16.0 Allowed Normal 0.79

14.0 

12.4 

11.0 

1032 ....... Dimethylamine, anhydrous ................................................... 7.0 Allowed Normal 0.59

7.0 

7.0 

7.0 

1033 ....... Dimethyl ether ...................................................................... 15.5 Allowed Normal 0.58

13.8 

12.0 

10.6 

1036 ....... Ethylamine ............................................................................ 7.0 Allowed Normal 0.61

7.0 

7.0 

7.0 

1037 ....... Ethyl chloride ........................................................................ 7.0 Allowed Normal 0.8

7.0 

7.0 

7.0 

1040 ....... Ethylene oxide with nitrogen up to a total pressure of 

1MPa (10 bar) at 50 °C.

Only authorized in 

10 bar insulated portable 

tanks—

Not Allowed § 178.276(e)(3) 0.78

1041 ....... Ethylene oxide and carbon dioxide mixture with more than 

9% but not more than 87% ethylene oxide.

See MAWP definition in 

§ 178.276(a) 

Allowed Normal See

§ 173.32(f) 

1055 ....... Isobutylene ........................................................................... 8.1 Allowed Normal 0.52

7.0 

7.0 

7.0 

1060 ....... Methyl acetylene and propadiene mixture, stabilized .......... 28.0 Allowed Normal 0.43

24.5 

22.0 

20.0 

1061 ....... Methylamine, anhydrous ...................................................... 10.8 Allowed Normal 0.58

9.6 

7.8 

7.0

1062 ....... Methyl bromide ..................................................................... 7.0 Not Allowed § 178.276(e)(3) 1.51

7.0

7.0

7.0

1063 ....... Methyl chloride or Refrigerant gas R 40 .............................. 14.5 Allowed Normal 0.81

12.7

11.3

10.0

1064 ....... Methyl mercaptan ................................................................. 7.0 Not Allowed § 178.276(e)(3) 0.78

7.0

7.0

7.0

76176 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

UN PORTABLE TANK TABLE FOR LIQUEFIED COMPRESSED GASES—Continued

UN No. Non-refrigerated liquefied compressed gases 

Minimum design 

pressure (bar) 

small; bare; 

sunshield; insulated 

Openings 

below liquid 

level 

Pressure relief requirements (See

§ 178.276(e)) 

Maximum filling density 

(kg/l) 

1067 ....... Dinitrogen tetroxide .............................................................. 7.0 Not Allowed § 178.276(e)(3) 1.3

7.0

7.0

7.0

1075 ....... Petroleum gas, liquefied ...................................................... See MAWP definition in 

§ 178.276(a) 

Allowed Normal See 

§ 173.32(f) 

1077 ....... Propylene ............................................................................. 28.0 Allowed Normal 0.43

24.5

22.0

20.0

1078 ....... Refrigerant gas, n.o.s. .......................................................... See MAWP definition in 

§ 178.276(a) 

Allowed Normal See 

§ 173.32(f) 

1079 ....... Sulphur dioxide .................................................................... 11.6 Not Allowed § 178.276(e)(3) 1.23

10.3

8.5

7.6

1082 ....... Trifluorochloroethylene, stabilized or Refrigerant gas R 

1113.

17.0 Not Allowed § 178.276(e)(3) 1.13

15.0

13.1

11.6

1083 ....... Trimethylamine, anhydrous .................................................. 7.0 Allowed Normal 0.56

7.0

7.0

7.0

1085 ....... Vinyl bromide, stabilized ...................................................... 7.0 Allowed Normal 1.37

7.0

7.0

7.0

1086 ....... Vinyl chloride, stabilized ....................................................... 10.6 Allowed Normal 0.81

9.3

8.0

7.0

1087 ....... Vinyl methyl ether, stabilized ............................................... 7.0 Allowed Normal 0.67

7.0

7.0

7.0

1581 ....... Chloropicrin and methyl bromide mixture ............................ 7.0 Not Allowed § 178.276(e)(3) 1.51

7.0

7.0

7.0

1582 ....... Chloropicrin and methyl chloride mixture ............................. 19.2 Not Allowed § 178.276(e)(3) 0.81

16.9

15.1

13.1

1858 ....... Hexafluoropropylene compressed or Refrigerant gas R 

1216.

19.2 Allowed Normal 1.11

16.9

15.1

13.1

1912 ....... Methyl chloride and methylene chloride mixture ................. 15.2 Allowed Normal 0.811954

1954 ....... n.o.s..

13.0

11.6

10.1

NA .......... Insecticide gases, flammable, .............................................. See MAWP definition in 

§ 178.276(a) 

Allowed Normal § 173.32(f) 

1958 ....... 1,2-Dichloro-1,1,2,2-tetrafluoroethane or Refrigerant gas R 

114.

7.0 Allowed Normal 1.3

7.0

7.0

7.0

1965 ....... Hydrocarbon gas, mixture liquefied, n.o.s. .......................... See MAWP definition in 

178.276(a) 

Allowed Normal See 

§ 173.32(f) 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76177

UN PORTABLE TANK TABLE FOR LIQUEFIED COMPRESSED GASES—Continued

UN No. Non-refrigerated liquefied compressed gases 

Minimum design 

pressure (bar) 

small; bare; 

sunshield; insulated 

Openings 

below liquid 

level 

Pressure relief requirements (See

§ 178.276(e)) 

Maximum filling density 

(kg/l) 

1969 ....... Isobutane .............................................................................. 8.5 Allowed Normal 0.49

7.5

7.0

7.0

1973 ....... Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% 

chlorodifluoromethane or Refrigerant gas R 502.

28.3 Allowed Normal 1.05

25.3

22.8

20.3

1974 ....... Chlorodifluorobromomethane or Refrigerant gas R 12B1 ... 7.4 Allowed Normal 1.61

7.0

7.0

7.0

1976 ....... Octafluorocyclobutane or Refrigerant gas RC 318 .............. 8.8 Allowed Normal 1.34

7.8

7.0

7.0

1978 ....... Propane ................................................................................ 22.5 Allowed Normal 0.42

20.4

18.0

16.5

1983 ....... 1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a ... 7.0 Allowed Normal 1.18

7.0

7.0

7.0

2035 ....... 1,1,1-Trifluoroethane compressed or Refrigerant gas R 

143a.

31.0 Allowed Normal 0.76

27.5

24.2

21.8

2424 ....... Octafluoropropane or Refrigerant gas R 218 ...................... 23.1 Allowed Normal 1.07

20.8

18.6

16.6

2517 ....... 1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b ...... 8.9 Allowed Normal 0.99

7.8

7.0

7.0

2602 ....... Dichlorodifluoromethane and difluoroethane azeotropic 

mixture with approximately 74% dichlorodifluoromethane 

or Refrigerant gas R 500.

20.0 Allowed Normal 1.01

18.0

16.0

14.5

3057 ....... Trifluoroacetyl chloride 14.6 Not allowed § 178.276(e)(3) 1.17

12.9

11.3

9.9

3070 ....... Ethylene oxide and dichlorodifluoromethane mixture with 

not more than 12.5% ethylene oxide.

14.0 Allowed § 178.276(e)(3) 1.09

12.0

11.0

9.0

3153 ....... Perfluoro (methyl vinyl ether) ............................................... 14.3 Allowed Normal 1.14

13.4

11.2

10.2

3159 ....... 1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a .......... 17.7 Allowed Normal 1.04

15.7

13.8

12.1

3161 ....... Liquefied gas, flammable, n.o.s. .......................................... See MAWP definition in 

§ 178.276(a) 

Allowed Normal § 173.32(f) 

3163 ....... Liquefied gas, n.o.s. ............................................................. See MAWP definition in 

§ 178.276(a) 

Allowed Normal § 173.32(f) 

76178 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

UN PORTABLE TANK TABLE FOR LIQUEFIED COMPRESSED GASES—Continued

UN No. Non-refrigerated liquefied compressed gases 

Minimum design 

pressure (bar) 

small; bare; 

sunshield; insulated 

Openings 

below liquid 

level 

Pressure relief requirements (See

§ 178.276(e)) 

Maximum filling density 

(kg/l) 

3220 ....... Pentafluoroethane or Refrigerant gas R 125 ....................... 34.4 Allowed Normal 0.95

30.8

27.5

24.5

3252 ....... Difluoromethane or Refrigerant gas R 32 ............................ 43.0 Allowed Normal 0.78

39.0

34.4

30.5

3296 ....... Heptafluoropropane or Refrigerant gas R 227 .................... 16.0 Allowed Normal 1.2

14.0

12.5

11.0

3297 ....... Ethylene oxide and chlorotetrafluoroethane mixture, with 

not more than 8.8% ethylene oxide.

8.1 Allowed Normal 1.16

7.0

7.0

7.0

3298 ....... Ethylene oxide and pentafluoroethane mixture, with not 

more than 7.9% ethylene oxide.

25.9 Allowed Normal 1.02

23.4

20.9

18.6

3299 ....... Ethylene oxide and tetrafluoroethane mixture, with not 

more than 5.6% ethylene oxide.

16.7 Allowed Normal 1.03

14.7

12.9

11.2

3318 ....... Ammonia solution, relative density less than 0.880 at 15 

°C in water, with more than 50% ammonia.

See MAWP definition in 

§ 178.276(a) 

Allowed § 178.276(e)(3) § 173.32(f) 

3337 ....... Refrigerant gas R 404A ....................................................... 31.6 Allowed Normal 0.84

28.3

25.3

22.5

3338 ....... Refrigerant gas R 407A ....................................................... 31.3 Allowed Normal 0.95

28.1

25.1

22.4

3339 ....... Refrigerant gas R 407B ....................................................... 33.0 Allowed Normal 0.95

29.6

26.5

23.6

3340 ....... Refrigerant gas R 407C ....................................................... 29.9 Allowed Normal 0.95

26.8

23.9

21.3

■ 49. In § 173.315, paragraph (a) 

introductory text is revised to read as 

follows:

§ 173.315 Compressed gases in cargo 

tanks and portable tanks. 

(a) Liquefied compressed gases that 

are transported in UN portable tanks 

must be loaded and offered for 

transportation in accordance with the 

UN Portable Tank Table for Liquefied 

Compressed Gases in § 173.313. A 

liquefied compressed gas offered for 

transportation in a cargo tank motor 

vehicle or a portable tank must be 

prepared in accordance with this 

section, §§ 173.32 and 173.33 and 

subpart E or subpart G of part 180 of this 

subchapter, as applicable. For cryogenic 

liquids, see § 173.318. For marking 

requirements, see §§ 172.326 and 

172.328 of this subchapter. Except for 

UN portable tanks, a liquefied 

compressed gas must be loaded and 

offered for transportation in accordance 

with the following table:

* * * * *

■ 50. In § 173.323, paragraph (b) is 

revised to read as follows:

§ 173.323 Ethylene oxide.

* * * * *

(b) Ethylene oxide must be packaged 

in one of the following: 

(1) In hermetically sealed glass or 

metal inner packagings suitably 

cushioned in an outer package 

authorized by § 173.201(b). The 

maximum quantity permitted in any 

glass inner packaging is 100 g (3.5 

ounces), and the maximum quantity 

permitted in any metal inner packaging 

is 340 g (12 ounces). After filling, each 

inner packaging shall be determined to 

be leak-tight by placing the inner 

packaging in a hot water bath at a 

temperature, and for a period of time, 

sufficient to ensure that an internal 

pressure equal to the vapor pressure of 

ethylene oxide at 55 °C is achieved. The 

total quantity in any outer packaging 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76179

shall not exceed 100 g (3.5 ounces), and 

the total quantity in any outer packaging 

containing only metal inner packagings 

shall not exceed 2.5 kg (5.5 pounds). 

Each completed package must be 

capable of passing all Packing Group I 

performance tests. 

(2) In specification cylinders, as 

authorized for any compressed gas 

except acetylene. Pressurizing valves 

and insulation are required for cylinders 

over 4 L (1 gallon) capacity. Eductor 

tubes must be provided for cylinders 

over 19 L (5 gallons) capacity. Cylinders 

must be seamless or welded steel (not 

brazed) with a nominal capacity of no 

more than 115 L (30 gallons) and may 

not be liquid full below 82 °C (180 °F). 

Before each refilling, each cylinder must 

be tested for leakage at no less than 

103.4 kPa (15 psig) pressure. In 

addition, each cylinder must be 

equipped with a fusible type relief 

device with yield temperature of 69 °C 

to 77 °C (157 °F to 170 °F). The capacity 

of the relief device and the effectiveness 

of the insulation must be such that the 

charged cylinder will not explode when 

tested by the method described in CGA 

Pamphlet C–14 or other equivalent 

method. 

(3) In 1A1 steel drums of no more 

than 231 L (61 gallons) and meeting 

Packing Group I performance standards. 

The drum must be lagged of all welded 

construction with the inner shell having 

a minimum thickness of 1.7 mm (0.068 

inches) and the outer shell having a 

minimum thickness of 2.4 mm (0.095 

inches). Drums must be capable of 

withstanding a hydrostatic test pressure 

of 690 kPa (100 psig). Lagging must be 

of sufficient thickness so that the drum, 

when filled with ethylene oxide and 

equipped with the required pressure 

relief device, will not rupture when 

exposed to fire. The drum may not be 

liquid full below 85 °C (185 °F), and 

must be marked ‘‘THIS END UP’’ on the 

top head. Before each refilling, each 

drum must be tested for leakage at no 

less than 103 kPa (15 psig) pressure. 

Each drum must be equipped with a 

fusible type relief device with yield 

temperature of 69 °C to 77 °C (157 °F to 

170 °F), and the capacity of the relief 

device must be such that the filled drum 

is capable of passing, without rupture, 

the test method described in CGA 

Pamphlet C–14 or other equivalent 

method.

* * * * *

■ 50a. In Appendix H to Part 173, the 

fifth sentence of paragraph 3. and 

paragraph 3.(a) are revised to read as 

follows: 

Appendix H to Part 173—Method of 

Testing for Sustained Combustibility 

3. * * * A suitable apparatus is 

shown in Figure 32.5.2.1 of the UN 

Manual of Test and Criteria, and the 

essential dimensions are given in 

Figures 32.5.2.1 and 32.5.2.2 of the UN 

Manual and Tests and Criteria. * * * 

(a) Gauge, for checking that the height 

of the center of the gas jet above the top 

of the test portion well is 2.2 mm (see

Figure 32.5.2.1);

* * * * *

PART 175—CARRIAGE BY AIRCRAFT

■ 51. The authority citation for part 175 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127; 49 CFR 

1.53.

■ 52. In § 175.10, paragraphs (a)(4)(i), 

(a)(4)(iii), and (a)(18) are revised to read 

as follows:

§ 175.10 Exceptions. 

(a) * * * 

(4) * * * 

(i) Non-radioactive medicinal and 

toilet articles (including aerosols) may 

be carried in checked or carry-on 

baggage. Release devices on aerosols 

must be protected by a cap or other 

suitable means to prevent inadvertent 

release;

* * * * *

(iii) Other aerosols in Division 2.2 

with no subsidiary risk may be carried 

in checked baggage only. Release 

devices on aerosols must be protected 

by a cap or other suitable means to 

prevent inadvertent release;

* * * * *

(18) Compressed gas cylinders of 

Division 2.2 worn by passengers for the 

operation of mechanical limbs and spare 

cylinders of a similar size for the same 

purpose in sufficient quantities to 

ensure an adequate supply for the 

duration of the journey.

* * * * *

■ 53. Section 175.85 is revised by adding 

new paragraph (j) to read as follows:

§ 175.85 Cargo location.

* * * * *

(j) A package bearing a KEEP AWAY 

FROM HEAT handling marking must be 

protected from direct sunshine and 

stored in a cool and ventilated place, 

away from sources of heat.

PART 176—CARRIAGE BY VESSEL

■ 54. The authority citation for part 176 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127; 49 CFR 

1.53.

■ 55. In § 176.2:

■ a. The definitions for ‘‘Explosive 

article’’, ‘‘Explosive substance’’ and 

‘‘Magazine’’ are revised.

■ b. The term ‘‘Transport unit’’ is revised 

to read ‘‘Cargo transport unit’’.

■ c. In the definition ‘‘In containers or 

the like’’, the term ‘‘transport unit’’ is 

removed and the term ‘‘cargo transport 

unit’’ is added in its place. 

The revisions and additions read as 

follows:

* * * * *

Cargo transport unit means a 

transport vehicle, a freight container or 

a portable tank. A closed cargo transport 

unit means a cargo transport unit in 

which the contents are totally enclosed 

by permanent structures. An open cargo 

transport unit means a cargo transport 

unit that is not a closed cargo transport 

unit. Cargo transport units with fabric 

sides or tops are not closed cargo 

transport units for the purposes of this 

part.

* * * * *

Explosive article means an article or 

device which contains one or more 

explosive substances. Individual 

explosive substances are identified in 

column 17 of the Dangerous Goods List 

in the IMDG Code.

* * * * *

Explosive substance means a solid or 

liquid material, or a mixture of 

materials, which is in itself capable by 

chemical reaction of producing gas at 

such a temperature and pressure and at 

such a speed as to cause damage to its 

surroundings. Individual explosive 

substances are identified in column 17 

of the Dangerous Goods List in the 

IMDG Code.

* * * * *

In containers or the like means any 

clean, substantial, weatherproof box 

structure which can be secured to the 

vessel’s structure, including a portable 

magazine or a closed cargo transport 

unit. Whenever this stowage is 

specified, stowage in deckhouses, mast 

lockers and oversized weatherproof 

packages (overpacks) is also acceptable.

* * * * *

Magazine means an enclosure 

designed to protect certain goods of 

Class 1 (explosive) materials from 

damage by other cargo and adverse 

weather conditions during loading, 

unloading, and when in transit; and to 

prevent unauthorized access. A 

magazine may be a fixed structure or 

compartment in the vessel, a closed 

freight container, a closed transport 

vehicle, or a portable magazine. 

Magazines may be positioned in any 

part of the ship conforming with the 

relevant provisions for Class 1 

(explosive) materials contained in

76180 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

Subpart G of this part provided that 

magazines which are fixed structures 

are sited so that their doors, where 

fitted, are easily accessible.

* * * * *

■ 56. Section 176.27 is revised to read as 

follows:

§ 176.27 Certificate. 

(a) A carrier may not transport a 

hazardous material by vessel unless a 

certificate prepared in accordance with 

§ 172.204 of this subchapter has been 

received. 

(b) In the case of an import or export 

shipment of a hazardous material that 

will not be transported by rail, highway, 

or air, the shipper may certify on the bill 

of lading or other shipping paper that 

the hazardous material is properly 

classed, described, marked, packaged, 

and labeled according to part 172 of this 

subchapter or in accordance with the 

requirements of the IMDG Code (IBR, 

see § 171.7 of this subchapter). See

§ 171.12 of this subchapter. 

(c)(1) A person responsible for 

packing or loading a freight container or 

transport vehicle with packages of 

hazardous materials for transportation 

by a manned vessel in ocean or 

coastwise service, must provide the 

vessel operator, at the time the shipment 

is offered for transportation by vessel, 

with a signed container packing 

certificate stating, at a minimum, that—

(i) The freight container or transport 

vehicle is serviceable for the materials 

loaded therein, contains no 

incompatible goods, and is properly 

marked, labeled or placarded, as 

applicable; and 

(ii) When the freight container or 

transport vehicle contains packages, 

those packages have been inspected 

prior to loading, are properly marked, 

labeled or placarded, as applicable; are 

not damaged; and are properly secured. 

(2) The certification may appear on a 

shipping paper or on a separate 

document as a statement, such as ‘‘It is 

declared that the packing of the 

container has been carried out in 

accordance with the applicable 

provisions [of 49 CFR], [of the IMDG 

Code], or [of 49 CFR and the IMDG 

Code].’’

■ 57. In § 176.63, paragraph (e) is revised 

to read as follows:

§ 176.63 Stowage locations.

* * * * *

(e) Closed cargo transport unit, for the 

purpose of stowage of Class 1 

(explosive) materials on board a vessel, 

means a unit which fully encloses the 

contents by permanent structures and 

can be secured to the ship’s structure, 

and includes a magazine. Cargo 

transport units with fabric sides or tops 

are not closed cargo transport units. 

Where this stowage is specified, stowage 

in small compartments such as deckhouses and mast lockers are acceptable 

alternatives. The floor of any closed 

cargo transport unit or compartment 

shall either be constructed of wood, 

close-boarded or so arranged that goods 

are stowed on sparred gratings, wooden 

pallets or dunnage. Provided that the 

necessary additional specifications are 

met, a closed cargo transport unit may 

be used for type ‘‘A’’ or ‘‘C’’ class 1 

stowage or as a magazine.’’

* * * * *

■ 58. In § 176.76, paragraphs (h) and (i) 

are revised to read as follows:

§ 176.76 Transport vehicles, freight 

containers, and portable tanks containing 

hazardous materials.

* * * * *

(h) A fumigated cargo transport unit 

may only be transported on board a 

vessel subject to the following 

conditions and limitations: 

(1) The fumigated cargo transport unit 

may be placed on board a vessel only if 

at least 24 hours have elapsed since the 

unit was last fumigated; 

(2) The fumigated cargo transport unit 

is accompanied by a document showing 

the date of fumigation and the type and 

amount of fumigant used; 

(3) Prior to loading, the master is 

informed of the intended placement of 

the fumigated cargo transport unit on 

board the vessel and the information 

provided on the accompanying 

document; 

(4) Equipment that is capable of 

detecting the fumigant and instructions 

for the equipment’s use is provided on 

the vessel; 

(5) The fumigated cargo transport unit 

must be stowed at least 5 m from any 

opening to accommodation spaces; 

(6) Fumigated cargo transport units 

may only be transported on deck on 

vessels carrying more than 25 

passengers; and 

(7) Fumigants may not be added to 

cargo transport units while on board a 

vessel. 

(i) A cargo transport unit packed or 

loaded with flammable gas or flammable 

liquid having a flashpoint below +23 °C 

transported on deck must be stowed 

‘‘away from’’ possible sources of 

ignition. In the case of container ships, 

a distance equivalent to one container 

space athwartships away from possible 

sources of ignition applied in any 

direction will satisfy this requirement.

■ 59. In § 176.83:

■ a. Paragraphs (a)(5), (d), (e), (f)(1), 

(f)(3), (g)(1), (g)(2), (g)(3), and (l) are 

revised;

■ b. The headings to paragraphs (g) and 

(f) and the title to Table 176.83(g) are 

revised; and

■ c. A new paragraph (m) is added.

The revisions and additions read as 

follows:

§ 176.83 Segregation.

* * * * *

(a) * * * 

(5) Whenever hazardous materials are 

stowed together, whether or not in a 

cargo transport unit, the segregation of 

such hazardous materials from others 

must always be in accordance with the 

most restrictive requirements for any of 

the hazardous materials concerned.

* * * * *

(d) Segregation in cargo transport 

units: Two hazardous materials for 

which any segregation is required may 

not be stowed in the same cargo 

transport unit. 

(e) Segregation of hazardous materials 

stowed as breakbulk cargo from those 

packed in cargo transport units: (1) 

Hazardous materials stowed as 

breakbulk cargo must be segregated from 

materials packed in open cargo 

transport units in accordance with 

paragraph (c) of this section. 

(2) Hazardous materials stowed as 

breakbulk cargo must be segregated from 

materials packed in closed cargo 

transport units in accordance with 

paragraph (c) of this section, except that: 

(i) Where ‘‘away from’’ is required, no 

segregation between packages and the 

closed cargo transport units is required; 

and 

(ii) Where ‘‘separated from’’ is 

required, the segregation between the 

packages and the closed cargo transport 

units may be the same as for ‘‘away 

from’’. 

(f) Segregation of cargo transport units 

on board container vessels: (1) Except 

for hatchless container ships, this 

paragraph applies to segregation of 

cargo transport units that are carried on 

board container vessels, or on other 

types of vessels, provided these cargo 

spaces are properly fitted for permanent 

stowage of containers during transport.

* * * * *

(3) Segregation Table. Table 

§ 176.83(f) sets forth the general 

requirements for segregation between 

cargo transport units on board container 

vessels.

* * * * *

(g) Segregation of cargo transport 

units on board trailerships and 

trainships: (1) The requirements of this 

paragraph apply to the segregation of 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76181

cargo transport units which are carried 

on board trailerships and trainships or 

in ‘‘roll-on/roll-off’’ cargo spaces. 

(2) For trailerships and trainships 

which have spaces suitable for 

breakbulk cargo, containers, or any 

other method of stowage, the 

appropriate paragraph of this section 

applies to the relevant cargo space. 

(3) Segregation Table. Table 

§ 176.83(g) sets forth the general 

requirements for segregation between 

transport units on board trailerships and 

trainships. 

Table 176.83(g).—Segregation of Cargo 

Transport Units on Board Trailerships 

and Trainships

* * * * *

(1) Segregation of containers on board 

hatchless (open-top) container ships: (1) 

This paragraph applies to the 

segregation of cargo transport units that 

are transported on board hatchless 

container ships provided that the cargo 

spaces are properly fitted to give 

permanent stowage of the cargo 

transport units during transport. 

(2) For container ships that have both 

hatchless container spaces and other 

spaces suitable for breakbulk cargo, 

conventional container stowage, or any 

other method of stowage, the 

appropriate requirements of this section 

apply to the relevant cargo space. 

(3) Segregation Table. Table 

§ 176.83(l)(3) sets forth the general 

requirements for segregation of cargo 

transport units on board hatchless 

container ships. 

(4) In Table § 176.83(l)(3), a container 

space means a distance of not less than 

6 m (20 feet) fore and aft or not less than 

2.5 m (8 feet) athwartship.

76182 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations TABLE 176.83(L)(3)

—

SEGREGATION OF

CARGO

TRANSPORT

UNITS ON

BOARD

HATCHLESS

CONTAINER

SHIPS

VERTICAL HORIZONTAL 

Segregation requirement 

Closed 

versus 

closed 

Closed 

versus 

open 

Open versus 

open 

Closed versus closed Closed versus open Open versus open 

On deck Under deck On deck Under deck On deck Under deck 

‘‘Away from’’ ..............................................................1. ...............................................................................

One on top 

of the other permitted.

Open on 

top of closed permitted.

.................. Fore and 

AFT.

No restriction ... No restriction ... No restriction ... No restriction ... one container 

space.

one container 

space or one

bulkhead 

............. Otherwise 

as for ‘‘Open versus open’’.

.................. Athwartships. No restriction ... No restriction ... No restriction ... No restriction ... One con- tainer 

space.

One container 

space 

‘‘Separated from’’ ......................................................

2. ...............................................................................

............. ............. Not in the 

same vertical line.

Fore and 

AFT.

One container 

space.

One container 

space or one bulkhead.

One container 

space.

one container 

space or one bulkhead.

One container 

space and not in or above same hold.

One bulkhead 

Not in the 

same vertical line.

As for 

‘‘open versus open’’.

.................. Athwartships. One container space. One container space. Two container spaces. Two container spaces. Two con- tainer 

spaces and not in or above same hold.

One bulkhead 

‘‘Separated by a complete compartment or hold 

from’’.

3. ...............................................................................

............. ............. .................. Fore and 

AFT.

One container 

space and not in or above same hold.

One bulkhead .. One container 

space and not in or above same hold.

One bulkhead .. Two container 

spaces and not in or above same hold.

Two bulkheads 

............. ............. .................. Athwartships. Two container spaces and 

not in or above same hold.

One bulkhead .. Two container 

spaces and not in or above same hold.

One bulkhead .. Tree container 

spaces and not in or above same hold.

Two bulkheads 

‘‘Separated longitudinally by an intervening complete compartment or hold from’’.

4. ...............................................................................

Prohibited Fore and 

AFT.

Minimum horizontal distance of 24 

m and not in or above same hold.

One bulkhead 

and minimum horizontal distance of 24 M*.

Minimum horizontal distance of 24 m 

and not in or above same hold.

Two bulkheads Minimum horizontal distance of 24 m 

and not in or above same hold.

Two bulkheads.

............. Athwartships. Prohibited ..... Prohibited Prohibited ........ Prohibited ........ Prohibited ........ Prohibited.

*Containers not less than 6 m (20 feet) from intervening bulkhead. Note: All bulkheads and decks must be resistant to fire and liquid. 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76183

(m) Provisions for segregation groups:

(1) For the purpose of segregation, 

materials having certain similar 

chemical properties have been grouped 

together in segregation groups. The 

segregation groups (such as ‘‘acids’’, 

‘‘chlorates’’, ‘‘permanganates’’) and the 

entries allocated to each of these groups 

include the substances identified in 

section 3.1.4 of the IMDG Code. When 

column (10B) of the § 172.101 Table 

refers to a numbered stowage provision 

set forth in § 176.84(b) such as ‘‘Stow 

‘away from’ acids’’, that particular 

stowage/segregation requirement 

applies to all the materials allocated to 

the respective segregation group. 

(2) Not all hazardous materials falling 

within a segregation group are listed by 

name in the regulations. These materials 

are shipped under ‘‘n.o.s.’’ entries. 

Although these ‘‘n.o.s.’’ entries are not 

listed themselves in the above groups, 

the shipper must decide whether 

allocation under a segregation group is 

appropriate. Mixtures, solutions or 

preparations containing hazardous 

materials falling within a segregation 

group and shipped under an ‘‘n.o.s.’’

entry are also considered to fall within 

that segregation group. 

(3) The segregation groups described 

above do not address materials which 

fall outside the classification criteria of 

the hazardous materials regulations 

although it is recognized that some nonhazardous materials have certain 

chemical properties similar to 

hazardous materials listed in the 

segregation groups. A shipper or the 

person responsible for packing the 

materials into a cargo transport unit 

who does have knowledge of the 

chemical properties of such nonhazardous materials may identify a 

relevant segregation group and apply 

the segregation requirements for that 

segregation group.

■ 60. In § 176.84, paragraph (a) is 

revised, in paragraph (b), Table of 

provisions, eleven new entries are added 

in appropriate numerical order and in 

paragraph (c)(2), three notes in the 

Provisions for the stowage of Class 1 

(explosive) materials table are revised to 

read as follows: § 176.84 Other 

requirements for stowage and 

segregation for cargo vessels and 

passenger vessels.

(a) General. When Column 10B of the 

§ 172.101 Table refers to a numbered or 

alpha-numeric stowage provision for 

water shipments, the meaning and 

requirements of that provision are set 

forth in this section. Terms in quotation 

marks are defined in § 176.83. Other 

terms used in the table in this section 

such as ‘‘acids’’, ‘‘chlorates’’ and 

‘‘permanganates’’ indicate different 

chemical groups referred to here as 

segregation groups. Materials falling 

within a segregation group are 

considered to have certain similar 

chemical properties and, although not 

exhaustive in nature, the materials 

belonging to each group include those 

substances identified in section 3.1.4 of 

the IMDG Code as set forth in 

§ 176.83(m). 

(b) * * *

Code Provisions 

*****

133 ...... Stow ‘‘separated from’’ sulfur. 

134 ...... Stow ‘‘separated from’’ UN2716. 

135 ...... Stow ‘‘Separated from’’ mercury 

and mercury compounds. 

136 ...... Stow ‘‘Separated from’’ carbon tetrachloride. 

137 ...... For arsenic sulphides, Stow ‘‘separated from’’ acids. 

138 ...... Stow ‘‘Separated from’’ peroxides. 

139 ...... Stow ‘‘Separated from’’ mercury 

salts. 

140 ...... Stow ‘‘Separated from’’ UN3052 

and UN3461. 

141 ...... Stow ‘‘away from’’ radioactive materials. 

142 ...... Packages in cargo transport units 

must be stowed so as to allow 

for adequate air circulation 

throughout the cargo. 

143 ...... Prohibited on any vessel carrying 

explosives (except explosives in 

Division 1.4, Compatibility group 

S). 

*****

* * * * *

(c) * * * 

(2) * * *

Note Provision 

*****

19E ...... ‘‘Away from’’ explosives containing 

chlorates or perchlorates. 

*****

22E ...... ‘‘Away from’’ ammonium compounds and explosives containing ammonium compounds or 

salts. 

23E ...... ‘‘Separated from’’ Division 1.4 and 

‘‘separated longitudinally by an 

intervening complete compartment or hold from’’ Division 1.1, 

1.2, 1.3, 1.5, and 1.6 except from 

explosives of compatibility group 

J. 

*****

* * * * *

■ 61. In § 176.116, paragraph (c) is 

revised and a new paragraph (f) is added 

to read as follows:

§ 176.116 General stowage conditions for 

Class 1 (explosive) materials.

* * * * *

(c) Security: All compartments, 

magazines, and cargo transport units 

containing Class 1 (explosive) materials 

must be locked or suitably secured in 

order to prevent unauthorized access.

* * * * *

(f) Under deck stowage of Class 1 

(explosive) materials allocated stowage 

categories 09 and 10:

(1) These Class 1 (explosive) materials 

must not be stowed in the same 

compartment or hold with other cargo 

that is readily combustible (such as 

items packaged in straw). 

(2) The position of stowage of these 

Class 1 (explosive) materials must be 

such as to maintain direct access to the 

hatchway by not overstowing with other 

cargo except for other Class 1 

(explosive) materials. 

(3) In all cases, all cargo within the 

compartment or hold, including Class 1 

(explosive) materials stowed in cargo 

transport units, must be secured so as to 

eliminate the possibility of significant 

movement. Where an entire deck is used 

as a magazine, the stowage must be so 

arranged that the Class 1 (explosive) 

materials stowed therein must be 

removed from the ship before working 

any cargo in any decks above or below 

the space in the same hold.

§ 176.122 [Removed and Reserved]

■ 62. Section 176.122 is removed and 

reserved.

§ 176.124 [Removed and Reserved]

■ 63. Section 176.124 is removed and 

reserved.

■ 64. Section 176.128 is revised to read 

as follows:

§ 176.128 Magazine stowage types ‘‘A’’, 

‘‘C’’ and Special Stowage. 

(a) The stowage arrangements of Class 

1 (explosive) substances and certain 

articles are subject to varying levels of 

containment, (except for compatibility 

group S substances), when stowed 

below deck. The levels are dependent 

on the hazard presented and the nature 

of the particular explosives involved. 

Columns (10A) and (10B) of the 

Hazardous Materials Table specify the 

stowage applicable to each substance or 

article. The different levels of 

containment are defined below as ‘‘A’’, 

‘‘C’’ and ‘‘Special’’.

(b) Magazine stowage type ‘‘A’’.

Magazine stowage type A is required for 

those substances that must be kept clear 

of steelwork. 

(c) Magazine stowage type ‘‘C’’.

Magazine stowage type C is required for 

76184 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

those substances in compatibility group 

A. 

(d) Special Stowage. Special Stowage 

is required for Explosive substances, 

n.o.s. in compatibility groups G or L, 

and for articles in compatibility groups 

G, H, L and K, which are particularly 

hazardous.

§ 176.132 [Removed and Reserved]

■ 65. Section 176.132 is removed and 

reserved.

■ 66. Section 176.133 is revised to read 

as follows:

§ 176.133 Magazine stowage Type C. 

The construction requirements for 

magazine stowage type C are the same 

as for a closed cargo transport unit in 

§ 176.63(e). In addition, the magazine 

must be located as near as practicable to 

the centerline of the vessel and must not 

be closer to the vessel’s side than a 

distance equal to one-eighth of the 

vessel’s beam or 2.4 m (8 feet), 

whichever is less.

■ 67. Section 176.136 is revised to read 

as follows:

§ 176.136 Special stowage. 

(a) Special stowage is required for 

certain articles presenting both 

explosive and chemical hazards, such as 

smoke or lachrymatory (compatibility 

group G or H), toxic (compatibility 

group K), or substances and articles 

which present a special risk 

(compatibility group L). Except as 

permitted in paragraph (c) of this 

section, Class 1 (explosive) materials 

requiring special stowage must be 

stowed on deck unless such stowage is 

impracticable and the COTP authorizes 

special stowage below deck. Where on 

deck stowage is recommended and an 

alternative stowage below deck is 

permitted by the COTP, the stowage 

must always be subject to special 

stowage. 

(b) Class 1 (explosive) materials for 

which special stowage is required must 

be stowed as far away as practicable 

from living, accommodation, and 

working areas, and may not be 

overstowed. Closed cargo transport 

units in which such Class 1 (explosive) 

materials are stowed may not be located 

closer to the vessel’s side than a 

distance equal to one-eighth of the 

vessel’s beam or 2.4 m (8 feet), 

whichever is less. 

(c) Class 1 (explosive) materials in 

compatibility groups G and H may be 

transported in steel magazines or in 

freight containers. If a freight container 

is used for this purpose, the floor of the 

freight container must be leakproof; for 

example, an all-metal container may be 

used and a fillet of cement or other 

material worked across the bottom of 

the door opening. 

(d) Class 1 (explosive) materials 

stowed in one compartment may not be 

of more than one compatibility group, 

except the COTP may allow Class 1 

(explosive) materials of compatibility 

groups G and H in separate steel 

magazines to be stowed in the same 

compartment, not less than 3 m (10 feet) 

apart. 

(e) Class 1 (explosive) materials in 

compatibility groups K and L must be 

stowed in a steel magazine regardless of 

the stowage position in the vessel.

■ 68. In § 176.138, paragraph (a) is 

revised to read as follows:

§ 176.138 Deck stowage. 

(a) [Reserved]

* * * * *

■ 69. In § 176.142, paragraph (a) is 

revised to read as follows:

§ 176.142 Hazardous materials of extreme 

flammability. 

(a) Except as allowed by paragraph (b) 

of this section, certain hazardous 

materials of extreme flammability may 

not be transported in a vessel carrying 

Class 1 (explosive) materials. This 

prohibition applies to the following 

liquid hazardous materials:

Carbon disulfide.UN1131 ... Class 3 

Diethylzinc ...... UN1366 ... Division 4.2 

Dimethylzinc ... UN1370 ... Division 4.2 

Magnesium 

alkys.

UN3053 ... Division 4.2 

Methyl 

phosphonous 

di-chloride, 

pyrophoric 

liquid..

NA2845 ... Division 6.1 

Nickel carbonyl UN1259 ... Division 6.1 

Pyrophoric liquid, inorganic, n.o.s..UN3194 ... Division 4.2 

Pyrophoric liquid, organic, 

n.o.s..

UN2845 ... Division 4.2 

Organometallic 

substance, 

liquid, 

pyrophoric..

UN3392 ... Division 4.2 

Organometallic 

substance, 

liquid, 

pyrophoric, 

water-reactive..

UN3394 ... Division 4.2 

* * * * *

■ 70. In § 176.144, paragraphs (a), (b), (c) 

and (e) are revised to read as follows:

§ 176.144 Segregation of Class 1 

(explosive) materials. 

(a) Except as provided in § 176.145 of 

this subchapter, stowage of Class 1 

(explosive) materials within the same 

compartment, magazine, or cargo 

transport unit is subject to provisions 

contained in table 176.144(a).

TABLE 176.144(A)—AUTHORIZED MIXED STOWAGE FOR EXPLOSIVES

[An ‘‘X’’ indicates that explosives in the two different compatibility groups reflected by the location of the ‘‘X’’ may not be stowed in the same 

compartment, magazine, or cargo transport unit] 

Compatibility groups A B C D E F G H J K L N S 

A ................................................. .......... X X X X X X X X X X X X 

B ................................................. X .......... XXXXXXXXXX ..........

C ................................................. X X .......... 6 6 X 1 XXXX4 ..........

D ................................................. X X 6 .......... 6 X 1 XXXX4 ..........

E ................................................. X X 6 6 .......... .......... 1 XXXX4 ..........

F ................................................. XXXXXXXXXXXX ..........

G ................................................. X X 1 1 1 X .......... XXXXX ..........

H ................................................. XXXXXXX .......... XXXX ..........

J .................................................. XXXXXXXX .......... X X X ..........

K ................................................. XXXXXXXXX .......... X X ..........

L ................................................. X X X X X X X X X X 2 X X 

N ................................................. X X 4 4 4 X X X X X X 3 5 

S ................................................. X .......... .......... .......... .......... .......... .......... .......... .......... .......... X 5 ..........

NOTES: 1. Explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of 

compatibility groups C, D, and E, provided no explosive substances are carried in the same compartment, magazine or cargo transport unit. 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76185

2. Explosives in compatibility group L may only be stowed in the same compartment, magazine or cargo transport unit with identical explosives 

within compatibility group L. 

3. Different types of articles of Division 1.6, compatibility group N, may only be transported together when it is proven that there is no additional risk of sympathetic detonation between the articles. Otherwise they must be treated as division 1.1. 

4. When articles of compatibility group N are transported with articles or substances of compatibility groups C, D or E, the goods of compatibility group N must be treated as compatibility group D. 

5. When articles of compatibility group N are transported together with articles or substances of compatibility group S, the entire load must be 

treated as compatibility group N. 

6. Any combination of articles in compatibility groups C, D and E must be treated as compatibility group E. Any combination of substances in 

compatibility groups C and D must be treated as the most appropriate compatibility group shown in Table 2 of § 173.52 taking into account the 

predominant characteristics of the combined load. This overall classification code must be displayed on any label or placard on a unit load or 

cargo transport unit as prescribed in subpart E (Labeling) and subpart F (Placarding). 

(b) Where Class 1 (explosive) 

materials of different compatibility 

groups are allowed to be stowed in the 

same compartment, magazine, or cargo 

transport unit, the stowage 

arrangements must conform to the most 

stringent requirements for the entire 

load. 

(c) Where a mixed load of Class 1 

(explosive) materials of different hazard 

divisions and/or stowage arrangements 

is carried within a compartment, 

magazine, or cargo transport unit, the 

entire load must be treated as belonging 

to the hazard division having the 

greatest hazard. (For example, if a load 

of Division 1.1 (explosive) materials is 

mixed with Division 1.3 (explosive) 

materials, the load is treated as a 

Division 1.1 (explosive) material as 

defined in § 173.50(b) of this subchapter 

and the stowage must conform to the 

most stringent requirements for the 

entire load).

* * * * *

(e) Segregation on deck: When Class 

1 (explosive) materials in different 

compatibility groups are carried on 

deck, they must be stored not less than 

6 m (20 feet) apart unless they are 

allowed under Table 176.144(a) to be 

stowed in the same compartment, 

magazine, or cargo transport unit.

* * * * *

■ 71. In § 176.146, paragraph (d)(1) is 

revised to read as follows:

§ 176.146 Segregation from nonhazardous materials.

* * * * *

(d) In order to avoid contamination: 

(1) An explosive substance or article 

which has a secondary POISON hazard 

label must be stowed ‘‘separated from’’

all foodstuffs, except when such 

materials are stowed in separate closed 

cargo transport units, the requirements 

for ‘‘away from’’ segregation apply.

* * * * *

§ 176.168 [Amended]

■ 72. In § 176.168, the undesignated 

center heading before § 176.168 is 

revised to read ‘‘CARGO TRANSPORT 

UNITS AND SHIPBORNE BARGES’’.

■ 73. In § 176.170, a new paragraph (b) 

is added to read as follows:

§ 176.170 Transport of Class 1 (explosive) 

materials in freight containers.

* * * * *

(b) Freight containers loaded with 

Class 1 (explosive) materials, except for 

explosives in Division 1.4, must not be 

stowed in the outermost row of 

containers.

* * * * *

■ 74. In § 176.174, paragraphs (a) and (b) 

are revised to read as follows:

§ 176.174 Transport of Class 1 (explosive) 

materials in shipborne barges. 

(a) Fixed magazines may be built 

within a shipboard barge. Freight 

containers may be used as magazines 

within a barge. 

(b) Shipborne barges may be used for 

the carriage of all types of Class 1 

(explosive) materials. When carrying 

Class 1 (explosive) materials requiring 

special stowage, the following 

requirements apply: 

(1) Class 1 (explosive) materials in 

compatibility group G or H must be 

stowed in freight containers. 

(2) Class 1 (explosive) materials in 

compatibility group K or L must be 

stowed in steel magazines.

* * * * *

§ 176.600 [Amended]

■ 75. In § 176.600, in paragraph (a), in 

the last sentence, the wording ‘‘closed 

transport units’’ is removed and the 

wording ‘‘closed cargo transport units’’

is added in its place.

PART 178—SPECIFICATIONS FOR 

PACKAGINGS

■ 76. The authority citation for part 178 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127; 49 CFR 

1.53.

■ 77. In § 178.274, paragraph (f)(l)(v) is 

revised to read as follows:

§ 178.274 Specifications for UN portable 

tanks.

* * * * *

(f) * * * 

(l) * * * 

(v) The rated flow capacity of the 

spring loaded pressure relief devices, 

frangible disc or fusible elements in 

standard cubic meters of air per second 

(m3/s). For spring loaded pressure relief 

device the rated flow capacity shall be 

determined according to ISO 4126–1 

(IBR, see § 171.1 of this subchapter); and

* * * * *

■ 78. In § 178.275, paragraph (i)(2) is 

revised to read as follows:

§ 178.275 Specification for UN Portable 

Tanks intended for the transportation of 

liquid and solid hazardous materials.

* * * * *

(i) * * * 

(2) The combined delivery capacity of 

the pressure relief system (taking into 

account the reduction of the flow when 

the portable tank is fitted with frangiblediscs preceding spring-loaded pressurerelief devices or when the spring-loaded 

pressure-relief devices are provided 

with a device to prevent the passage of 

the flame), in condition of complete fire 

engulfment of the portable tank must be 

sufficient to limit the pressure in the 

shell to 20% above the start to discharge 

pressure limiting device (pressure relief 

device). The total required capacity of 

the relief devices may be determined 

using the formula in paragraph 

(i)(2)(i)(A) of this section or the table in 

paragraph (i)(2)(iii) of this section.

* * * * *

■ 79. In § 178.276, paragraphs 

(a)(4)(ii)(A), (d), and (e)(3) are revised to 

read as follows:

§ 178.276 Requirements for the design, 

construction, inspection and testing of 

portable tanks intended for the 

transportation of non-refrigerated liquefied 

compressed gases. 

(a) * * * 

(4) * * * 

(ii) * * * 

(A) Not less than the pressure 

specified for each liquefied compressed 

gas listed in the UN Portable Tank Table 

for Liquefied Compressed Gases in 

§ 173.313; and

* * * * *

(d) Bottom openings. Bottom openings 

are prohibited on portable tanks when 

the UN Portable Tank Table for 

Liquefied Compressed Gases in 

§ 173.313 of this subchapter indicates 

that bottom openings are not allowed. In 

76186 Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 

this case, there may be no openings 

located below the liquid level of the 

shell when it is filled to its maximum 

permissible filling limit. 

(e) * * * 

(3) A portable tank intended for the 

transportation of certain liquefied 

compressed gases identified in the UN 

Portable Tank Table for Liquefied 

Compressed Gases in § 173.313 of this 

subchapter must have a pressure relief 

device which conforms to the 

requirements of this subchapter. Unless 

a portable tank, in dedicated service, is 

fitted with a relief device constructed of 

materials compatible with the 

hazardous material, the relief device 

must be comprised of a frangible disc 

preceded by a reclosing device. The 

space between the frangible disc and the 

device must be provided with a pressure 

gauge or a suitable tell-tale indicator. 

This arrangement must facilitate the 

detection of disc rupture, pinholing or 

leakage which could cause a 

malfunction of the pressure relief 

device. The frangible disc must rupture 

at a nominal pressure 10% above the 

start-to-discharge pressure of the relief 

device.

* * * * *

■ 80. In § 178.602, paragraph (b) is 

revised to read as follows:

§ 178.602 Preparation of packagings and 

packages for testing.

* * * * *

(b) For the drop and stacking test, 

inner and single-unit receptacles other 

than bags must be filled to not less than 

95% of maximum capacity (see § 171.8 

of this subchapter) in the case of solids 

and not less than 98% of maximum in 

the case of liquids. Bags shall be filled 

to the maximum mass at which they 

may be used. The material to be 

transported in the packagings may be 

replaced by a non-hazardous material, 

except for chemical compatibility 

testing or where this would invalidate 

the results of the tests.

* * * * *

■ 81. In § 178.603, paragraphs (c) and 

(e)(2) introductory text are revised to 

read as follows:

§ 178.603 Drop test.

* * * * *

(c) Special preparation of test samples 

for the drop test.

(1) Testing of plastic drums, plastic 

jerricans, plastic boxes other than 

expanded polystyrene boxes, composite 

packagings (plastic material), and 

combination packagings with plastic 

inner packagings other than plastic bags 

intended to contain solids or articles 

must be carried out when the 

temperature of the test sample and its 

contents has been reduced to ¥18 °C (0 

°F) or lower. Test liquids must be kept 

in the liquid state, if necessary, by the 

addition of anti-freeze. Water/anti-freeze 

solutions with a minimum specific 

gravity of 0.95 for testing at ¥18 °C (0 

°F) or lower are considered acceptable 

test liquids. Test samples prepared in 

this way are not required to be 

conditioned in accordance with 

§ 178.602(d).

* * * * *

(e) * * *

* * * * *

(2) For liquids in single packagings 

and for inner packagings of combination 

packagings, if the test is performed with 

water:

* * * * *

■ 82. In § 178.810, paragraph (b)(3) is 

revised to read as follows:

§ 178.810 Drop test.

* * * * *

(b) Special preparation for the drop 

test.

* * * * *

(3) Rigid plastic IBCs and composite 

IBCs with plastic inner receptacles must 

be conditioned for testing by reducing 

the temperature of the packaging and its 

contents to ¥18 °C (0 °F) or lower. Test 

liquids must be kept in the liquid state, 

if necessary, by the addition of antifreeze. Water/anti-freeze solutions with 

a minimum specific gravity of 0.95 for 

testing at ¥18 °C (0 °F) or lower are 

considered acceptable test liquids, and 

may be considered equivalent to water 

for test purposes. IBCs conditioned in 

this way are not required to be 

conditioned in accordance with 

§ 178.802.

* * * * *

PART 180—CONTINUING 

QUALIFICATION AND MAINTENANCE 

OF PACKAGINGS

■ 83. The authority citation for part 180 

continues to read as follows:

Authority: 49 U.S.C. 5101–5127; 49 CFR 

1.53.

■ 84. In § 180.350, paragraph (c) is 

revised to read as follows:

§ 180.350 Applicability and definitions.

* * * * *

(c) Routine maintenance of IBCs is the 

routine performance on: 

(1) Metal, rigid plastic or composite 

IBCs of operations such as: 

(i) Cleaning; 

(ii) Removal and reinstallation or 

replacement of body closures (including 

associated gaskets), or of service 

equipment conforming to the original 

manufacturer’s specifications provided 

that the leaktightness of the IBC is 

verified; or 

(iii) Restoration of structural 

equipment not directly performing a 

hazardous material containment or 

discharge pressure retention function so 

as to conform to the design type (for 

example, the straightening of legs or 

lifting attachments), provided the 

containment function of the IBC is not 

affected. 

(2) Plastics or textile flexible IBCs of 

operations, such as: 

(i) Cleaning; or 

(ii) Replacement of non-integral 

components, such as non-integral liners 

and closure ties, with components 

conforming to the original 

manufacturer’s specification; provided 

that these operations do not adversely 

affect the containment function of the 

flexible IBC or alter the design type.

■ 85. In § 180.352, paragraph (d)(1)(iv) is 

revised and a new paragraph (d)(1)(v) is 

added to read as follows:

§ 180.352 Requirements for retest and 

inspection of IBCs.

* * * * *

(d) * * * 

(1) * * * 

(iv) Retests and inspections performed 

in accordance with paragraphs (d)(1)(i) 

and (ii) of this section may be used to 

satisfy the requirements for the 2.5 and 

five year periodic tests and inspections 

required by paragraph (b) of this section, 

as applicable. 

(A) The County in which the routine 

maintenance was carried out; and 

(B) The name or authorized symbol of 

the party performing the routine 

maintenance. 

(v) Retests and inspections performed 

in accordance with paragraphs (d)(1)(i) 

and (ii) of this section may be used to 

satisfy the requirements for the 2.5 and 

five year periodic tests and inspections 

required by paragraph (b) of this section, 

as applicable. 

(e) Requirements applicable to routine 

maintenance of IBCs. Except for routine 

maintenance of metal, rigid plastics and 

composite IBCs performed by the owner 

of the IBC, whose State and name or 

authorized symbol is durably marked on 

the IBC, the party performing the 

routine maintenance shall durably mark 

the IBC near the manufacturer’s UN 

design type marking to show the 

following: 

(1) The County in which the routine 

maintenance was carried out; and 

(2) The name or authorized symbol of 

the party performing the routine 

maintenance. 

(f) Retest date. The date of the most 

recent periodic retest must be marked as 

Federal Register / Vol. 69, No. 243 / Monday December 20, 2004 / Rules and Regulations 76187

provided in § 178.703(b) of this 

subchapter. 

(g) Record retention. The owner or 

lessee of the IBC must keep records of 

periodic retests, initial and periodic 

inspections, and tests performed on the 

IBC if it has been repaired. Records 

must include design types and 

packaging specifications, test and 

inspection dates, name and address of 

test and inspection facilities, names or 

name of any persons conducting tests or 

inspections, and test or inspection 

specifics and results. Records must be 

kept for each packaging at each location 

where periodic tests are conducted, 

until such tests are successfully 

performed again or for at least 2.5 years 

from the date of the last test. These 

records must be made available for 

inspection by a representative of the 

Department on request.

* * * * *

Issued in Washington, DC on November 24, 

2004, under authority delegated in 49 CFR 

part 1. 

Elaine E. Joost, 

Acting Deputy Administrator, Research and 

Special Programs Administration.

[FR Doc. 04–27087 Filed 12–17–04; 8:45 am] 

BILLING CODE 4910–60–P