Appendix A 

Eastman Chemical Company 

Supplemental Submittal to 

Petition for Reconsideration, Amendment, and Administrative Stay of 

Commercial and Industrial Solid Waste Incineration Units (78 Fed. Reg. 9112) 

Boiler 20 NOx Data Collection & Reporting 

A NOx analyzer was temporarily installed on an existing 02 dry-extractive CEMS equipped with a data 

acquisition and handling system (DAHS). 

NOx and 02 CEMS data were collected by a data controller, which computed minute averages and 

hourly averages of ppm NOx, %02, and ppm NOx corrected to 7% 02. Minute and hourly average data 

were polled from the data controller by a PC and archived by the DAHS. 

Hourly average %02, ppm NOx, and ppm NOx corrected to 7% 02 data are reported from 5/3/13 to 

5/17/13, and from 5/23/13 to 6/10/13, during normal operation at Boiler 20. About 80% of data were 

collected while burning coal only, and about 20% while burning both coal and bio-sludge. 

During the period from 5/17/13 to 5/23113, the NOx analyzer was removed from Boiler 20 for other 

monitoring needs. 

Boiler 20 NOx & 02 Data Quality Assurance 

Quality of NOx data were assured by: 

• Daily Calibration Drift testing (per 40 CFR 60 Appendix F& Performance Specification 2 in 40 

CFR 60 Appendix B) 

• 7-Day Calibration Drift test (per Performance Specification 2 in 40 CFR 60 Appendix B) 

• Cylinder Gas Audit (per 40 CFR 60 Appendix F) 

Quality of 02 data were assured by: 

• Daily Calibration Drift testing (per Performance Specification 3 in 40 CFR 60 Appendix B) 

• 7-Day Calibration Drift test (per Performance Specification 3 in 40 CFR 60 Appendix B) 

Results of all quality assurance tests are included below. 

CEMS times are all Eastern Standard Time, because the CEMS maintains Standard Time throughout the 

year. 
Eastman Chemical Company Environmental Services Laboralory 

Seven Day Calibration Drift Determination 

for MACT or RCRA CEMS 

Date: 5/14/2013 Reason for Test: Initial Certification 

Source: 20 Reason for Test: 

Building: B-83 

Monitor: NOx, Span: 600 ppmv 

PrimaryAnalyzer: TEC042C-HL 42CHL-75882 AlternateAnalyzer: 

Performed By: I RLZ 

C linder Number Concentration Units I Ex iration Date I heck Ex . 

Nitro en 0 ppmv 

CC422761 546.0 ppmv 12/10/2020 OK 

mv 

ppmv 

Day Date Time 

Reference 

Values 

ppmv 

Actual 

Values 

ppmv 

Absolute 

Difference 

ppmv 

Percent 

of Span 

1 5/812013 8:29 0 1.7 1.7 0.3% 

2 5/9/2013 8`.06 0 0.5 0.5 0.1% 

3 5110/2013 8:13 0 0.0 0.0 0.0% 

ZERO (LOW LEVEL) 4 5/1112013' 7:44 0 0.0 . 0.0 0.0% 

5 5/12/2013. ` 8:45 . 0 0:0 . 0.0 0.0% 

6 5/13/2013 9:08 0 0:8 0.8 0.1 % 

7 5/14/2013 1 8:06 0 0.1 0.1 0.0% 

Maximum 

Limit <= 2.5% of S an 

1.7 0.3% 

PASS 

1 5/8/2013 8:33 546.0 537.8 8.2 1.4% 

2 5/9/2013 8:10 546.0 540.1 5.9 1.0% 

3 5/10/2013 8;18 546.0 540.7 5.3 1 0.9% 

HIGH LEVEL 4 5/11/2013 7:55 546.0 541.2 4.8 0.8% 

5 5/12/2013 8:50 546:0 539.3 6.7 1.1 % 

6 5/13/2013 9:13 546:0 540.5 5.5 0.9% 

7 5/14/2013 8:11 546.0 1543.1 2.9 0.5% 

Maximum 

Limit <= 2.5% of Spa n 

8.2 1.4% 

PASS 

Comments: Tliis test was conducted for qu ality assurance of th e NOx analyzer temporarily insta Iled on the permanent O 2 CEM S at Boiler 20 in order to 

Explain "Reason record NOx emissions data. It was p erformed for initial certif ication after the analyzer was placed in senrice on 5/2/13. No adjustment s weie 

for Test," e.g., cite made to the NOx anlayzer during the 7-da y test period. 

the maintenance 

event, if 

"Diagnostic." 

Reviewed B: IJoseph Kellogg 

Document Number: THSE-ESL-CEM-5015-3 Effective Date: 06/23/05 
Eastman Chemical Company Environmental Services Laboralory 

Seven Day Calibration Drift Determination 

for MACT or RCRA CEMS 

Monitor: I NOx Span: 600 ppmv 

PrimaryAnalyzer: I TEG042C-HL 42CHL-75882 AlternateAnalyzer: 

Performed By: IRLZ 

C Iinder Number Concentration Units Ex iration Date Check Ex . 

Nitro en 0 ppmv 

CC422761 546.0 ppmv 12/10/2020 OK 

mv 

ppmv 

Day Date Time 

Reference 

Values 

ppmv 

Actual 

Values 

ppmv 

Absolute 

Difference 

ppmv 

Percent 

of Span 

1 5/25/2013 8:00 0 4`.9 4.9 0.8% 

2 5/26/2013 8:26 0 4.1 4.1 0.7% 

3 5/27/2013 8:29 0 3.2 3.2 0.5% 

ZERO (LOW LEVEL) 4 5/28/2013 9`.52 0 5.4 5.4 0.9% 

5 5/29/2013 8:02 0 4.9 4.9 0.8% 

6 5/30/2013 8:46 0 4.4 4.4 0.7% 

7 5/31/2013 8:11 0 4.5 4.5 0.8% 

Maximum 

Limit <= 2.5% of Span 

5.4 0.9% 

PASS 

1 5/25/2013 8:04 546.0 533.0 13.0 2.2% 

2 5/26/2013 8:31 546.0 535.2 10.8 1.8% 

3 5/27/2013 8:34 546.0 533.0 13.0 1 2.2% 

HIGH LEVEL 4 5/28/2013 9:56 546.0 535.2 10.8 1.8% 

5 5/29/2013 . 8:05 546.0 533.7 12.3 2.0% 

6 5/30/2013 8:50 546.0 539.7 6.3 1.0% 

7 1 5/31/2013 8:15 546.0 547.4 1.4 0.2% 

Maximum 

Limit <= 2.5% of Span 

13.0 2.2% 

PASS 

Comments: This test was,conducted for qu ality assuYance of th e NOx analyzer temporarily insta Iled on the permanent O 2 CEMS at Boiler 20 in order to 

Explain "Reaso n record NO x emissions data. It was.p erPormed for.recer tification after the ana lyzer had been remove d from service on 5/1 7/13 and then 

for Test," e.g., cite returned to service on 5/23/1 3. No adjustments were made to the NOx anlayzer dur ing the 7-day test perio d. 

the maintenance 

event, if 

„

Diagnostic." 

Reviewed B : IJoseph Kellogg 

Document Number: THSE-ESL-CEM-5015-3 Effective Date: 06/23/05 
Boiler 20 Temporary NOx CEMS Calibration Check Data 

Level NOx Concentration IGas Ex iration 

Zero 0.0 ppm Nitrogen N/A 

Hi h 546.0 ppm CC422761 12/10/2020 

600 ppm INOXCEMS anal zer s an value 

2.5% of span NOx CEMS Calibration Drift Performance Specification (40 CFR 60, Appendix B, Performance Specification 2, Section 13.1) 

5.0% of soan NOx CEMS Dailv Calibration Drift ReauiremenE (40 CFR 60, Appendix F, Section 4.1 

_ 

Calibration 

NOx 

Reference 

Value 

( m) 

NOx 

Actual 

Response 

( m) 

NOx 

Calibration 

Drift 

Values 

(% ofs an). 

NOx 

Calibration 

Drift 

Limit 

(% ofs an) 

NOx_ 

Calibration 

Drift 

Status 

(Pass/Fail) 

Event 

Date Time Level Date Time Description 

5/2/2013 13:06 High 546.0 542.7 -0.5% 5.0% Pass 

5/2/2013 13:17 Zero 0.0 2.2 0.4% 5.0% Pass 

5/2/2013 13:31 Begin NOx analyzer on-line 

5/3/2013 7:33 Zero 0.0 0.7 0.1% 5.0% Pass 

5/3/2013 7:38 High 546.0 547.3 0.2% 5.0% Pass 

5/3/2013 8:08 Start Cylinder Gas Audit 

5/3/2013 8:33 End Cylinder Gas Audit 

5/4/2013 8:33 Zero 0.0 2.6 0.4% 5.0% Pass 

5/4/2013 8:37 High 546.0 531.2 -2.5% 5.0% Pass 

5/5/2013 7:28 Zero 0.0 0.0 0.0% 5.0% Pass 

5/5/2013 7:33 High 546.0 532.9 -2.2% 5.0% Pass 

5/6/2013 8:36 Zero 0.0 0.0 0.0% 5.0% Pass 

5/6/2013 8:40 High 546.0 532.5 -2.3% 5.0% Pass 

5/7/2013 8:08 Zero 0.0 0.0 0.0% 5.0% Pass 

5/7/2013 8:13 High 546.0 529.6 -2.7% 5.0% Pass 

5/8/2013 8:29 Zero 0.0 1.7 0.3% 5.0% Pass 5/8/2013 8:29 Start 7-Day Calibration Drift 

5/8/2013 8:33 High 546.0 537.8 -1.4% 5.0% Pass 

5/9/2013 8:06 Zero 0.0 0.5 0.1% 5.0% Pass 

5/9/2013 8:10 High 546.0 540.1 -1.0% 5.0% Pass 

5/10/2013 8:13 Zero 0.0 0.0 0.0% 5.0% Pass 

5/10/2013 8:18 High 546.0 540.7 -0.9% 5.0% Pass 

5/11/2013 7:44 Zero 0.0 0.0 0.0% 5.0% Pass 

5/11/2013 7:55 High 546.0 541.2 -0.8% 5.0% Pass 

5/12/2013 8:45 Zero 0.0 0.0 0.0% 5.0% Pass 

5/12/2013 8:50 High 546.0 539.3 -1.1% 5.0% Pass 

5/13/2013 9:08 Zero 0.0 0.8 0.1% 5.0% Pass 

5/13/2013 9:13 High 546.0 540.5 -0.9% 5.0% Pass 

5/14/2013 8:06 Zero 0.0 0.1 0.0% 5.0% Pass 

5/14/2013 8:11 High 546.0 543.1 -0.5% 5.0% Pass 5/14/2013 8:11 7-Day Calibration Drift Passed 

5/15/2013 8:25 Zero 0.0 0.0 0.0% 5.0% Pass 

5/15/2013 8:30 High 546.0 556.2 1.7% 5.0% Pass 

5/16/2013 9:31 Zero 0.0 0.1 0.0% 5.0% Pass 

5/16/2013 9:36 High 546.0 537.6 -1.4% 5.0% Pass 

5/17/2013 7:09 Begin NOx analyzer off-line 

S/23/2013 9:12 Zero 0.0 4.5 0.8% 5.0% Pass 

5/23/2013 9:15 High 546.0 544.1 -0.3% 5:0% Pass 

5/23/2013 9:35 End NOx analyzer off-line 

5/23/2013 10:45 Start Cylinder Gas Audit 

5/23/2013 11:12 End Cylinder Gas Audit 

5/24/2013 10:22 Zero 0.0 4.3 0.7% 5.00/. Pass 

5/24/2013 10:27 High 546.0 530.5 -2.6% 5.0% Pass 

5/25/2013 8:00 Zero 0.0 4.9 0.8% 5.0% Pass 5/25/2013 8:00 Start 7-Day Calibration Drift 

5/25/2013 8:04 High 546.0 533.0 -2.2% S.0% Pass 

5/26/2013 8:26 Zero 0.0 4.1 0.7% 5.0% Pass 

5/26/2013 8:31 High 546.0 535.2 -1.8% 5.0% Pass 

5/27/2013 8:29 Zero 0.0 3.2 0.5% 5.0% Pass 

5/27/2013 8:34 High 546.0 533.0 -2.2% 5.0% Pass 

5/28/2013 9:52 Zero 010 5.4 0.9% 5.0% Pass 

5/28/2013 9:56 High 546.0 535.2 -1.8% 5.0% Pass 

5/29/2013 8:02 Zero 0.0 4.9 0.8% 5.0% Pass 

5/29/2013 8:05 High 546.0 533.7 -2.0% 5.0% Pass 

5/30/2013 8:46 Zero 0.0 4.4 0.7% 5.0% Pass 

5/30/2013 8:50 High 546.0 539.7 -1.0% 5.0% Pass 

5/31/2013 8:11 Zero 0.0 4.5 0.8% 5.0% Pass 

5/31/2013 8:15 High 546.0 547.4 0.2% 5.0% Pass 5/31/2013 8:15 7-Day Calibration Drift Passed 

6/1/2013 9:48 Zero 0.0 4.3 0.7% 5.0% Pass 

6/1/2013 9:54 High 546.0 542.6 -0.6% 5.0% Pass 
Calibration 

NOx 

Reference 

Value 

m 

NOx 

Actual 

Response 

m 

NOx 

Calibration 

Drift 

Values 

% ofs an 

NOx 

Calibration 

Drift 

Limit 

% ofs an 

NOx 

Calibration 

Drift 

Status 

Pass/Fail 

Event 

Date Time Level Date Time Description 

6/2/2013 6:37 Zero 0.0 4.5 0.8% 5.0% Pass 

6/2/2013 6;43 High 546.0 543.3 -0.5% 5.0% Pass 

6/3/2013 8:23 Zero 0.0 4.8 0.8% 5.0% Pass 

6/3/2013 8:27 High 546.0 541.2 -0.8% 5.0% Pass 

6/4/2013 7:36 Zero 0.0 5.5 0.9% 5.0% Pass 

6/4/2013 7:39 High 546.0 546.8 0.1% 5.0% Pass 

6/5/2013 9:50 Zero 0.0 4.6 0.8% 5.0% Pass 

6/5/2013 9:53 High 546.0 556.0 1.7% 5.0% Pass 

6/6/2013 7:45 Zero 0.0 5.5 0.9% 5.0% Pass 

6/6/2013 7:49 High 546.0 543.3 -0.5% 5.0% Pass 

6/7/2013 8:01 Zero 0.0 4.7 0.8% 5.0% Pass 

6/7/2013 8:05 High 546.0 546.0 0.0% 5.0% Pass 

6/8/2013 8:44 Zero 0.0 4.1 0.7% 5.0% Pass 

6/8/2013 8:47 High 546.0 550.6 0.8% 5.0% Pass 

6/9/2013 8:38 Zero 0.0 5.1 0.9% 5.0% Pass 

6/9/2013 8:41 High 546.0 552.2 1:0% 5.0% Pass 

6/10/2013 6:48 Boiler 20 off-line 
Eastman Chemical CQnpany Environmental Servbes Laboratory 

NOx Cylinder Gas Audit Determination 

Date: 5/3/2013 Reason for Test: Initial Certification 

Source: Boiler20 ' Reason for Test: 2nd Quarter C G Audit 

Building: B-83 Test Aborted: No 

Primary Anal zer: TECO 42C-HL I 42CHL-75882 Alternate Analyzer: 

Performed By: I RLZ 

Monitor: NOx Span: 600 ppmv 

Level Cylinder Number Concentration Units Expiration Date Check 

Low CC72443 150.3 ppmv 3/22/2014 OK: 120-180 

High CC48550 337.8 ppmv 1/31/2021 OK: 300-360 

Start Time: 8:08 Finish Time: 8:33 

Run 

Reference 

Value 

ppmv 

Actual 

Value 

ppmv 

Average Values & CEMS Accurac 

Low High 

ppmv p mv 

154.0 341.5 

3.7 3.7 

2% 1 % 

PASS PASS 

Low - 1 150.3 153.1 

Hi h -1 337.8 340.2 

Low - 2 150.3 154.6 

High - 2 337.8 342:9 

Low - 3 150.3 154.2 

Hi h- 3 337.8 341:5 

Average CEMS Responss 

CEMS Accuracy (ppmv) 

CEMS Accuracy (percent) 

Limit <= 15% (or <= 5 ppmv) 

Comments: This testwas conducted for quality assurance of the NOx analyzer temporarily installed on the permanent 02 CEMS at 

Explain "Reason Boiler 20 in order to record NOx emissions data. It was performed for initial certification on 5/3/13 after the analyzer was 

for Test," e.g., cite placed in service on 5/2/13. 

the maintenance 

event, if 

"Dia nostic." 

Reviewed B: IJoseph Kello g 

Document Number: lHSE-ESL-CEM-5065-3 Effective Date: June14, 2010 
Eastman Chemical Canpany Environmental Servbes Laboratory 

NOx Cylinder Gas Audit Determination 

Date: 5/23/2013 Reason for Test: Recertification 

Source: Boiler 20 Reason for Test: 

Building: B-83 Test Aborted: No 

Primary Anal zer: TECO 42C-HL I 42CHL-75882 Alternate Analyzer: 

Performed By: I RLZ 

Monitor: NOx Span: 600 ppmv 

Level Cylinder Number Concentration Units Expiration Date Check 

Low CC72443 150.3 ppmv 3/22/2014 OK: 120-180 

High CC48550 337.8 ppmv 1/31/2021 OK: 300-360 

Start Time: 10:45 Finish Time: 11:12 

Run 

Reference 

Value 

ppmv 

Actual 

Value 

ppmv 

Avera e Values & CEMS Accuracy 

Low High 

ppmv ppmv 

154.4 338.9 

4.1 1.1 

3% 0% 

PASS I PASS 

Low - 1 150.3 153.7 

Hi h- 1 337.8 335.9 

Low - 2 150.3 153.6 

High - 2 337.8 336.7 

Low - 3 150.3 155.8 

High - 3 1 337.8 344.0 

Average CEMS Response 

CEMS Accuracy (ppmv) 

CEMS Accuracy (percent) 

Limit <= 15% (or <= 5 ppmv) 

Comments: This test was conducted for quality assurance of the NOx analyzer temporarily installed on the permanent 02 CEMS at 

Explain "Reason Boiler 20 in order to record NOx emissions data. It wm performed for recertification on 5/23/13 after the analyzer had 

for Test," e.g., cite been removed from service on 5/17/13 and then returned to service earlier on 5/23/13. 

the maintenance 

event, if 

"Diagnostic." 

Reviewed B : IJoseph Kellogg 

Document Number: -TI ISE-ESL-CEM-5065-3 Effective Date: June14, 2010 
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Eastman Chemical Company Environmental Services Laboralory 

Seven Day Calibration Drift Determination 

for MACT or RCRA CEMS 

Monitor: 1 02 1 Span: 1 25 % 

Primary Analyzer: I Servomex 1440 I 01440DIV02/3705 I Alternate Analyzer: 

Performed By: IRLZ 

C linder Number Concentration Units Ex iration Date I Check Ex . 

Nitro en 0 % 

XC008802B 15.02 % 2/27/2021 OK 

CC172026 15.00 % 2/2712021 OK 

% 

Day Date Time 

Reference 

Values 

Actual 

Values 

Absolute 

Difference 

Percent 

of Span 

1 5/8/2013 5:28 0 0.0 0.0 0.0% 

2 5/9/2013 5:27 0 0.0 0.0 0.0% 

3 5/10/2013 5:27 0 0.0 0.0 0.0% 

ZERO (LOW LEVEL) 4 5/11/2013 5:27 0 0.0 0.0 0.0% 

5 5/12/2013 5:27 0 0.0 0.0 1 0.0% 

6 5/13/2013 5:28 0 0.0 0.0 1 0.0% 

7 5/14/2013 5:27 0' 0.0 0.0 0.0% 

Maximum 

Limit <= 0.5% Difference 

0.0 0.0% 

PASS 

1 51812013 5:28 15.0 14.8 0.2 0.8% 

2 5/9/2013 5:27 15.0 14.9 . 0.1 0.4% 

3 5/10/2013 5:27 15.0 14.9 : 0.1 0.4% 

HIGH LEVEL 4 5/11/2013 5:27 15.0 14.8 0.2 0.8% 

5 5/12/2013 5:27 15.0 14.8 0.2 0.8% 

6 5/13/2013 5:28 15.0 14.9 0.1 0.4% 

7 5/14/2013 5:27 15.0 14.9 0.1 0.4% 

Maximum 

Limit <= 0.5% Difference 

0.2 0.8% 

PASS 

Comments: This test was conducted for qu ality assurance of th e permanent 02 CEMS at Boiler 20 in order to recor d NOz emissions data cor rected to 

Explain "Reaso n 7%,02. It was perrormed for recer tification of the 02 CEMS afte r the NOx analyzer was fir st placed in service on this CEMS on 5/2/2013. : 

for Test," e.g., cite Cylinder XC008802B was removed f rom service after the daily cal check on 5/9 /2013, and cylinder C C172026 was put in service before the 

the maintenance daily cal check on 5/10/2013. N o adjustments were made to the 02 anlayzer during the 7-day test period. The pe rmanent 02 CEMS was in 

event, if service continuously from 5/2/20 13, when the NOx analyze r was first installed, thr ough 6/10/2013, wh en.NOx monitoring ceased . 

"Diagnostic." 

i 

Reviewed B: iJoseph Kellogg 

Document Number: THSE-ESL-CEM-5015-3 Effective Date: 06/23/05