# Patent

## Title
Resist composition and method for producing resist pattern

## Abstract

A resist composition contains; a resin having a structural unit represented by the formula (aa) and a structural unit represented by the formula (ab); and an acid generator,




    
    
        wherein Raa1 represents a hydrogen atom and a methyl group; Aaa1 represents an optionally substituted C1 to C6 alkanediyl group etc.; Raa2 represents an optionally substituted C1 to C18 aliphatic hydrocarbon group; Rab1 represents a hydrogen atom and a methyl group; Aab1 represents a single bond, an optionally substituted C1 to C6 alkanediyl group etc.; W1 represents an optionally substituted C4 to C24 alicyclic hydrocarbon group; n represents 1 or 2; Aab2 in each occurrence independently represents an optionally substituted C1 to C6 aliphatic hydrocarbon group; Rab2 in each occurrence independently represents a C1 to C12 fluorinated alkyl group.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims priority to Japanese Applications No. 2010-239427 filed on Oct. 26, 2010 and No. 2011-157527 filed on Jul. 19, 2011. The entire disclosures of Japanese Applications No. 2010-239427 and No. 2011-157527 are incorporated hereinto by reference.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a resin, a resist composition and a method for producing a resist pattern.
2. Background Information
Various kinds of photolithographic technique in which short wavelength light such as ArF excimer laser (193 nm of wavelength) is a exposure light source have been actively studied in the past as the semiconductor microfabrication. A resist composition used for such photolithographic technique contains a resin which is insoluble or poorly soluble in aqueous alkali solution, but becomes soluble in aqueous alkali solution by the action of acid and an acid generator.
A resist composition used for such photolithographic technique contains a resin having a polymer obtained by polymerizing a compound represented by the formula (u-A) and a compound represented by the formula (u-B), and a polymer obtained by polymerizing a compound represented by the formula (u-B), a compound represented by the formula (u-C) and a compound represented by the formula (u-D); an acid generator; and a solvent, is described in Patent document, pamphlet of JP-2010-197413-A.




However, with the conventional resist composition containing the above resin, the critical dimension uniformity (CDU) of the obtained resist pattern may be not always satisfied with.
SUMMARY OF THE INVENTION
The present invention provides following inventions.
<1> A resist composition comprising;
a resin having a structural unit represented by the formula (aa) and a structural unit represented by the formula (ab); and
an acid generator,




wherein Raa1 represents a hydrogen atom or a methyl group;
Aaa1 represents an optionally substituted C1 to C6 alkanediyl group or a group represented by the formula (a-1);




wherein s represents 0 or 1;
X10 and X11 independently represents an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group;
A10, A11 and A12 independently represent an optionally substituted C1 to C5 aliphatic hydrocarbon group;
* represents a bond to —O—C(O)—Raa2;
Raa2 represents an optionally substituted C1 to C18 aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—;




wherein Rab1 represents a hydrogen atom or a methyl group;
Aab1 represents a single bond, an optionally substituted C1 to C6 alkanediyl group or a group represented by the formula (a-2);




wherein t represents 0 or 1;
X30 and X31 independently represents an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group;
A30 and A31 independently represent an optionally substituted C1 to C5 aliphatic hydrocarbon group;
A32 represents an optionally substituted C1 to C5 aliphatic hydrocarbon group or a single bond;
* represents a bond to W1;
W1 represents an optionally substituted C4 to C24 alicyclic hydrocarbon group, and one or more —CH2— contained in the alicyclic hydrocarbon group may be replaced by —O— or —CO—;
n represents 1 or 2;
Aab2 in each occurrence independently represents an optionally substituted C1 to C6 aliphatic hydrocarbon group, and one or more —CH2-contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—; and
Rab2 in each occurrence independently represents a C1 to C12 fluorinated alkyl group, and one or more hydrogen atom contained in the fluorinated alkyl group may be replaced by a hydroxy group or a hydroxymethyl group.
<2> The resist composition according to <1>, wherein Aaa1 of the formula (aa) is a C1 to C6 alkanediyl group.
<3> The resist composition according to <1> or <2>, wherein Aaa1 of the formula (aa) is an ethylene group.
<4> The resist composition according to any one of <1> to <3>, wherein the structural unit represented by the formula (aa) is a structural unit represented by the formula (I).




wherein Raa1 and Aaa1 have the same definition of the above;
A13 represents a C1 to C15 divalent aliphatic hydrocarbon group that optionally has a fluorine atom;
X12 represent a carbonyloxy group or an oxycarbonyl group;
A14 represents a C1 to C15 aliphatic hydrocarbon group that optionally has a fluorine atom; and
provided that A13 and A14 have a fluorine atom and the total carbon number of A13 and A14 is 16 or less.
<5> The resist composition according to <4>, wherein A13 of the formula (I) is a C1 to C6 perfluoroalkanediyl group.
<6> The resist composition according to <4> or <5>, wherein X12 of the formula (I) is *—CO—O—, * represents a bond to A13.
<7> The resist composition according to any one of <4> to <6>, wherein A14 of the formula (I) is a cyclohexyl group, norbornyl group or adamantyl group.
<8> The resist composition according to any one of <1> to <7>, wherein —W1-(Aab2-Rab2)n of the formula (ab) is a group represented by the formula (W1-1) or a group represented by the formula (W1-2);




wherein one or more —CH2— contained in the adamantane ring may be replaced by —O— or —CO—;
one or more hydrogen atom contained in the adamantane ring may be replaced by a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
provided that a total carbon number of the adamantane ring and its substituent is 36 or less;
* represents a bond to Aab1; and
Aab2, Rab2 and n have the same definition of the above;




wherein one or more —CH2— contained in the cyclohexane ring may be replaced by —O— or —CO—;
one or more hydrogen atom contained in the cyclohexane ring may be replaced by a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
provided that a total carbon number of the cyclohexane ring and its substituent is 36 or less;
* represents a bond to Aab1; and
Aab2, Rab2 and n have the same definition of the above.
<9> The resist composition according to any one of <1> to <8>, wherein the acid generator is an acid generator represented by the formula (B1);




wherein Q1 and Q2 independently represent a fluorine atom or a C1 to C6 perfluoroalkyl group;
Lb1 represents an optionally substituted C1 to C17 divalent aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—;
Y represents an optionally substituted C1 to C18 aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O—, —CO— or —SO2—; and
Z+ represents an organic cation.
<10> The resist composition according to any one of <1> to <9>, wherein Y of the formula (B1) is an optionally substituted C3 to C18 alicyclic hydrocarbon group.
<11> The resist composition according to any one of <1> to <10>, further comprising a resin which is insoluble or poorly soluble in aqueous alkali solution, but becomes soluble in aqueous alkali solution by the action of acid.
<12> The resist composition according to any one of <1> to <11>, further comprising a solvent.
<13> A method for producing a resist pattern comprising steps of;
(1) applying the resist composition according to any one of <1> to <12> onto a substrate;
(2) drying the applied composition to form a composition layer;
(3) exposing the composition layer;
(4) heating the exposed composition layer; and
(5) developing the heated composition layer.
According to a resist composition of the present invention, it is possible to produce a resist pattern with excellent CDU, and with few defects in the obtained resist pattern.


DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Definition
In the present specification, any group exemplified below is applicable to any of the chemical formulae having a similar group with optionally selecting the number of carbon atoms, unless otherwise specified. The number attached to “C” means the carbon number of each group. When a group can form linear and branched chain and/or cyclic structures, all structures are included and may simultaneously present in one group, unless otherwise specified. When one group of moiety takes a stereoisomeric form, all stereoisomeric forms are included. Each group can form monovalent, or di- or more-valent group depending on the bonded position and bonding form.
A hydrocarbon group includes an aliphatic hydrocarbon group and an aromatic group. The aliphatic hydrocarbon group includes a chain aliphatic hydrocarbon group, an alicyclic hydrocarbon group and a combination thereof.
Examples of a monovalent chain aliphatic hydrocarbon group include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, decyl, dodecyl, hexadecyl, pentadecyl, hexyldecyl, heptadecyl and octadecyl groups. The aliphatic hydrocarbon group may be any of a liner and a branched chain aliphatic hydrocarbon groups. The chain aliphatic hydrocarbon group may include a carbon-carbon double bond, but a saturated chain aliphatic hydrocarbon group, i.e., alkyl group, is preferable.
Examples of a divalent chain aliphatic hydrocarbon group include a group in which one hydrogen atom is removed from the above the monovalent chain aliphatic hydrocarbon group, i.e., alkanediyl group.
The cyclic aliphatic hydrocarbon group may be any of a monocyclic or a polycyclic aliphatic hydrocarbon groups. The cyclic aliphatic hydrocarbon group hereinafter may be referred to as “alicyclic hydrocarbon group”. The alicyclic hydrocarbon group may include a carbon-carbon double bond, but a saturated alicyclic hydrocarbon group is preferable.
Examples of a monovalent alicyclic hydrocarbon group include a group in which one hydrogen atom is removed from an alicyclic hydrocarbon. Examples of a divalent alicyclic hydrocarbon group include a group in which two hydrogen atoms are removed from the alicyclic hydrocarbon group.
Examples of the alicyclic hydrocarbon typically include a cycloalkane below.










Examples of the aromatic hydrocarbon group typically include an aryl group such as phenyl, naphthyl, anthryl, biphenyl, phenanthryl and fluorenyl groups.
The aliphatic hydrocarbon group and the aromatic hydrocarbon group may be substituted with a substituent.
Typical examples of the substituent of the aliphatic hydrocarbon group include a halogen atom, an alkoxy group, an acyl group, an aryl group, an aralkyl group and an aryloxy group.
Typical examples of the substituent of the aromatic hydrocarbon group include a halogen atom, an alkoxy group, an acyl group, an alkyl group and an aryloxy group.
Examples of the halogen atom include fluorine, chlorine, bromine and iodine atoms.
Examples of the alkoxyl group include methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy and dodecyloxy groups. The alkoxyl group may be any of a liner and a branched chain alkoxyl groups.
Examples of the acyl group include a group bonding a carbonyl group to the alkyl group, such as, acetyl, propionyl, butyryl, valeryl, hexylcarbonyl, heptylcarbonyl, octylcarbonyl, decylcarbonyl and dodecylcarbonyl groups, and a group bonding a carbonyl group to the aryl group, such as, benzoyl group. The alkyl group in the acyl group may be any of a liner and a branched chain alkyl groups.
Examples of the aryloxy group include a group bonding an oxygen atom to the above aryl group.
Examples of the aralkyl group include benzyl, phenethyl, phenylpropyl, naphthylmethyl and naphthylethyl groups.
“(meth)acrylic monomer” means at least one monomer having a structure of “CH2═CH—CO—” or “CH2═C(CH3)—CO—”, as well as “(meth)acrylate” and “(meth)acrylic acid” mean “at least one acrylate or methacrylate” and “at least one acrylic acid or methacrylic acid”, respectively.
<Resist Composition>
The resist composition of the present invention contains;
a resin (hereinafter may be referred to as “resin (X)”), and
an acid generator (hereinafter may be referred to as “acid generator (B)”).
The resist composition can provide a resist pattern with excellent CDU by using the resin (X).
Further, the present resist composition preferably contains a resin which is different from the resin (X), and which has properties that are insoluble or poorly soluble in alkali aqueous solution, but become soluble in an alkali aqueous solution by the action of an acid. Hereinafter such resin may be referred to as “resin (A)”.
The resin (X) may have the above properties. By having such properties, it is possible to form a good resist pattern by using the present resist composition through a synergetic effect of the resin and the acid generator (B).
When the resin (X) has the above properties, the present resist composition may not always contain the resin (A).
Also, the present resist composition preferably contains a solvent (hereinafter may be referred to as “solvent (D)”) and/or an additive such as a basic compound (hereinafter may be referred to as “basic compound (C)”) which is known as a quencher in this technical field, as needed.
<Resin (X)>
The resin (X) has a structural unit represented by the formula (aa) (hereinafter may be referred to as “structural unit (aa)”) and a structural unit represented by the formula (ab) (hereinafter may be referred to as “structural unit (ab)”).
<Structural Unit (aa)>
The structural unit (aa) represents by the formula (aa) below.




wherein Raa1 represents a hydrogen atom or a methyl group;

Aaa1 represents an optionally substituted C1 to C6 alkanediyl group or a group represented by the formula (a-1);




wherein s represents 0 or 1;
X10 and X11 independently represents an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group;
A10, A11 and A12 independently represent an optionally substituted C1 to C5 aliphatic hydrocarbon group;
* represents a bond to —O—C(O)—Raa2;
Raa2 represents an optionally substituted C1 to C1s aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—.
The alkanediyl group of the Aaa1 may be either a linear or a branched chain alkanediyl group. Examples of the alkanediyl group include a linear alkanediyl group such as methylene, ethylene, propane-1,3-diyl, propane-1,2-diyl, butane-1,4-diyl, pentane-1,5-diyl, pentane-1,4-diyl, hexane-1,6-diyl and hexane-1,5-diyl; a branched chain alkanediyl group such as 1-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, 1-methylbutane-1,4-diyl and 2-methylbutane-1,4-diyl groups.
Examples of the substituent of the alkanediyl group include a hydroxy group and a C1 to C6 alkoxy group.
The group (a-1) is a divalent group containing an atom or atomic group of an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group such as X10 and X11.
Examples of the aliphatic hydrocarbon group of A10, A11 and A12 in the group (a-1) include an alkanediyl group such as methylene, ethylene, propane-1,3-diyl, propane-1,2-diyl, butane-1,4-diyl, 1-methylpropane-1,3-diyl, 2-methylpropane-1,3-diyl and 2-methylpropane-1,2-diyl groups.
Examples of the substituent of A10, A11 and A12 include a hydroxy group and a C1 to C6 alkoxy group.
Examples of the group (a-1) containing an oxygen atom include as below. In the formula, * represents a bond (the similar shall apply hereinafter for “bond”). In particular, the bond here represents a bonding site.




Examples of the group (a-1) containing a carbonyl group include as below.




Examples of the group (a-1) containing a carbonyloxy group include as below.




Examples of the group (a-1) containing an oxycarbonyl group include as below.




The aliphatic hydrocarbon group of Raa2 may include a carbon-carbon double bond, but a saturated aliphatic hydrocarbon group is preferable. Preferable examples of the aliphatic hydrocarbon group include either a linear or a branched chain alkyl group and an alicyclic hydrocarbon group.
Examples of an alkyl group include methyl, ethyl, propyl, butyl group, pentyl, hexyl, heptyl and octyl groups.
Examples of an alicyclic hydrocarbon group include a mono-alicyclic hydrocarbon group, i.e., a cycloalkyl group, such as cyclopentyl, cyclohexyl, methylcyclohexyl, dimethylcyclohexyl, cycloheptyl and cyclooctyl groups; and poly-alicyclic hydrocarbon groups such as decahydronaphthyl, adamantyl, norbornyl (i.e., bicyclo[2.2.1]hexyl) and methyl norbornyl groups as well as groups as below, and a group in combination thereof.




The —CH2— contained in the aliphatic hydrocarbon group of Raa2 may be replaced by at most two of oxygen atom and/or carbonyl group. Examples of one or more —CH2— contained in the aliphatic hydrocarbon group replaced by an oxygen atom and/or a carbonyl group include a group represented by the formula (a-g2) below.
The aliphatic hydrocarbon group of Raa2 is preferable an aliphatic hydrocarbon group having a substituent.
Examples of the substituent preferably include a fluorine atom or a group represented by the formula (a-g3).

—X12-A14  (a-g3)

wherein X12 represent a carbonyloxy group or an oxycarbonyl group;
A14 represents a C1 to C15 aliphatic hydrocarbon group that optionally has a fluorine atom.
The aliphatic hydrocarbon group of Raa2 may be substituted with one or more group(s) represented by the formula (a-g3), provided that the total carbon number of Raa2 and the substituent(s) is 18 or less. Thus, it is preferable that the number of the group(s) represented by the formula (a-g3) to be substituted is 1.
Raa2 is preferably a group substituted with a fluorine atom, and more preferably an aliphatic hydrocarbon group substituted with a fluorine atom or a group represented by the formula (a-g2).

-A13-X12-A14  (a-g2)

wherein A13 represents a C1 to C15 divalent aliphatic hydrocarbon group that optionally has a fluorine atom;
X12 represent a carbonyloxy group or an oxycarbonyl group;
A14 represents a C1 to C15 aliphatic hydrocarbon group that optionally has a fluorine atom;
provided that A13 or A14 have a fluorine atom and a total carbon number of A13 and A14 is 16 or less.
The aliphatic hydrocarbon group substituted with a fluorine atom of Raa2 is preferably a saturated aliphatic hydrocarbon group substituted with a fluorine atom, more preferably an aliphatic hydrocarbon group in which all hydrogen atoms contained in the group is substituted with fluorine atoms (e.g., perfluoroalkyl group or perfluorocycloalkyl group), and still more preferably a saturated liner chain aliphatic hydrocarbon group substituted with a fluorine atom, in particular, perfluoroalkyl group.
Examples of the fluorinated liner chain aliphatic hydrocarbon group include difluoromethyl, trifluoromethyl, 1,1-difluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, perfluoroethyl, 1,1,2,2-tetrafluoropropyl, 1,1,2,2,3,3-hexafluoropropyl, perfluoroethylmethyl, 1-(trifluoromethyl)-1,2,2,2-tetrafluoroethyl, perfluoropropyl, 1,1,2,2-tetrafluorobutyl, 1,1,2,2,3,3-hexafluorobutyl, 1,1,2,2,3,3,4,4-octafluorobutyl, perfluorobutyl, 1,1-bis(trifluoro)methyl-2,2,2-trifluoroethyl, 2-(perfluoropropyl)ethyl, 1,1,2,2,3,3,4,4-octafluoropentyl, perfluoropentyl, 1,1,2,2,3,3,4,4,5,5-decafluoropentyl, 1,1-bis(trifluoromethyl)-2,2,3,3,3-pentafluoropropyl, perfluoropentyl, 2-(perfluorobutyl)ethyl, 1,1,2,2,3,3,4,4,5,5-decafluorohexyl, 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorohexyl, perfluoropentylmethyl, perfluorohexyl, perfluoroheptyl and perfluoroctyl groups.
Among these, trifluoromethyl, perfluoroethyl, perfluoropropyl, perfluorobutyl, perfluoropentyl, perfluorohexyl, perfluoroheptyl and perfluorooctyl groups are preferable, a C1 to C6 perfluoroalkyl group is more preferable and a C1 to C3 perfluoroalkyl group is still more preferable.
When Raa2 in the formula (aa) has a group represented by the formula (a-g3), the structural unit represented by the formula (aa) may be a structural unit represented by the formula (I). Hereinafter may be referred to as “structural unit (I)”.




wherein Raa1 and Aaa1 have the same definition of the above;
A13 represents a C1 to C15 divalent aliphatic hydrocarbon group that optionally has a fluorine atom;
X12 represent a carbonyloxy group or an oxycarbonyl group;
A14 represents a C1 to C15 aliphatic hydrocarbon group that optionally has a fluorine atom; and
provided that A13 and A14 have a fluorine atom and a total carbon number of A13 and A14 is 16 or less.
The aliphatic hydrocarbon group of A13 includes a divalent chain aliphatic hydrocarbon group, a divalent alicyclic hydrocarbon group and a combination thereof. The aliphatic hydrocarbon group may include a carbon-carbon double bond, but a saturated aliphatic hydrocarbon group is preferable.
The aliphatic hydrocarbon group that optionally has a fluorine atom of A13 is preferably a saturated aliphatic hydrocarbon group that optionally has a fluorine atom.
Examples of the divalent chain aliphatic hydrocarbon group that optionally has a fluorine atom include methylene, difluoromethylene, ethylene, perfluoroethylene, propanediyl, perfluoropropanediyl, butanediyl, perfluorobutanediyl, pentanediyl and perfluoropentanediyl groups.
Examples of the divalent alicyclic hydrocarbon group that optionally has a fluorine atom include either a mono-alicyclic hydrocarbon group such as cyclohexanediyl and perfluorocyclohexanediyl groups, or poly-alicyclic hydrocarbon group such as adamantanediyl, norbornanediyl and perfluoroadamantanediyl groups.
The aliphatic hydrocarbon group of A14 includes a chain aliphatic hydrocarbon group, an alicyclic hydrocarbon group and a combination thereof. The aliphatic hydrocarbon group may include a carbon-carbon double bond, but a saturated aliphatic hydrocarbon group is preferable.
The aliphatic hydrocarbon group that optionally has a fluorine atom of A14 is preferably a saturated aliphatic hydrocarbon group that optionally has a fluorine atom.
Examples of the chain aliphatic hydrocarbon group that optionally has a fluorine atom include difluoromethyl, trifluoromethyl, methyl, perfluoroethyl, 1,1,1-trifluoroethyl, 1,1,2,2-tetrafluoroethyl, ethyl, perfluoropropyl, 1,1,1,2,2-pentafluoropropyl, propyl, perfluorobuthyl, 1,1,2,2,3,3,4,4-octafluorobutyl, butyl, perfluoropentyl, 1,1,1,2,2,3,3,4,4-nonafluoropentyl, pentyl, hexyl, perfluorohexyl, heptyl, perfluoroheptyl, octyl and perfluorooctyl groups.
Examples of the alicyclic hydrocarbon group that optionally has a fluorine atom include either a mono-alicyclic hydrocarbon group such as cyclohexyl and pentafluorocyclohexyl groups, or poly-alicyclic hydrocarbon group such as adamantyl, perfluoroadamantyl and norbornyl groups.
Examples of the group represented by *-A13-X12-A14 (* represents a bond to carbonyl group) include groups below.







In particular, Aaa1 in the formula (aa) and the formula (I) is preferably a C1 to C6 alkanediyl group, more preferably a C1 to C3 alkanediyl group, and still more preferably an ethylene group.
The aliphatic hydrocarbon group of A13 in the formula (I) is preferably a C1 to C6 aliphatic hydrocarbon group, more preferably a C2 to C3 aliphatic hydrocarbon group, and among these, preferably a chain aliphatic hydrocarbon group. In particular, A13 is preferably a fluorinated alkanediyl group, and more preferably C1 to C6 perfluorinated alkanediyl group.
The aliphatic hydrocarbon group of A14 in the formula (I) is preferably a C6 to C12 aliphatic hydrocarbon group, more preferably a C6 to C10 aliphatic hydrocarbon group, and among these, preferably a C6 to C12 alicyclic hydrocarbon group, and more preferably cyclohexyl, norbornyl and adamantyl groups.
Both of A13 and A14 may have a fluorine atom, but it is preferable that one of A13 and A14 has a fluorine atom, and more preferable that A13 has a fluorine atom.
X12 is preferably *—CO—O— (* represents a bond to A13).
Example of the structural unit (aa) and the structural unit (I) include structural units below.



















Also, examples of the structural units above include structural units in which a partial structure M in the structural units represented by the above is replaced by a partial structure A as described below.




The structural unit (aa) is derived from the compound represented by the formula (aa′), hereinafter may be referred to as “compound (aa′)”.




wherein Aaa1, Raa1 and Raa2 have the same definition of the above.
The compound (aa′) can be produced by methods described as below (1) to (3).
(1) The compound (aa′) can be obtained, for example, by reacting a compound represented by the formula (aas-1) with a compound represented by the formula (aas-2) in presence of a basic catalyst in a solvent.




wherein Aaa1, Raa1 and Raa2 have the same definition of the above.
Preferred examples of the solvent include tetrahydrofuran. Preferred examples of the basic catalyst include pyridine.
As the compound represented by the formula (aas-1), a marketed product, or a product which is produced according to the known method may be used.
The known method is, for example, a method in which a (meth)acrylic acid or a derivative (e.g., a (meth)acrylic acid chloride) is condensed with an appropriate diol (HO-Aaa1-OH). Examples of the marketed product include hydroxyethylmethacrylate.
As the compound represented by the formula (aas-2), a compound which is converted from a corresponding carboxylic acid to an acid anhydride corresponding to the kinds of Raa2 may be used. Examples of the marketed product include heptafluoroisobutyric anhydride.
(2) The compound represented by the formula (aa′) can be obtained by reacting a compound represented by the formula (aas-3) and a compound represented by the formula (aas-4) in the presence of or in the absence of a solvent.




wherein Aaa1, Raa1 and Raa2 have the same definition of the above.
The compound represented by the formula (aas-3) is a (meth)acryl chloride, which is a marketed product. Alternatively, a compound represented by the formula (aas-3) in which a chorine atom is replaced by a bromine or an iodine atom may be used in stead of the compound represented by the formula (aas-3). The compound represented by the formula (aas-3) in which a chorine atom is replaced by a bromine or an iodine atom can be produced by reacting a (meth)acrylic acid and a brominating agent or a iodinating agent.
The compound represented by the formula (aas-4) can be produced by the condensation of a carboxylic acid (e.g., Raa2—COOH) or a derivative (e.g., Raa2—COCl) corresponding to the kinds of Raa2 with an appropriate diol (HO-Aaa1-OH).
A deoxidizing agent (e.g., sodium carbonate) may be allowed to coexist in this reaction. Examples of the solvent preferably include tetrahydrofuran, methyl isobutyl ketone and toluene.
(3) The compound represented by the formula (aa′) can be obtained by reacting a compound represented by the formula (aas-1) and a compound represented by the formula (aas-5).




wherein Aaa1, Raa1 and Raa2 have the same definition of the above.
Examples of the solvent preferably include tetrahydrofuran and toluene.
Examples of compound represented by the formula (aas-1) include the same as defined above.
A conventional esterifying agent (e.g., acid catalyst and carbodiimide catalyst) may be allowed to coexist in this reaction.
A carboxylic acid represented by the formula (aas-5) can be produced corresponding to the kinds of Raa2 and according to the known method.
In particular, the structural unit (I) is derived from the compound represented by the formula (I′), hereinafter may be referred to as “compound (I′)”.




wherein Aaa1, Raa1, A13, X12 and A14 have the same definition of the above.
The compound represented by the formula (I′) can be obtained by reacting a compound represented by the formula (Is-1) and a compound represented by the formula (Is-2).




This reaction is generally performed in a solvent. Examples of the solvent preferably include tetrahydrofuran and toluene. A conventional esterifying agent (e.g., acid catalyst and carbodiimide catalyst) may be allowed to coexist in this reaction.
As the compound represented by the formula (Is-1), a marketed product or a product which is produced according to the known method may be used.
The known method is, for example, a method in which a (meth)acrylic acid or a derivative (e.g., a (meth)acrylic acid chloride) is condensed with an appropriate diol (HO-Aaa1-OH). Examples of the marketed product include hydroxyethylmethacrylate.
The carboxylic acid represented by the formula (Is-2) can be produced according to the known method. When the compound represented by the formula (I′) is produced, the following compounds can be used.







<Structural Unit (ab)>





wherein Rab1 represents a hydrogen atom or a methyl group;
Aab1 represents a single bond, an optionally substituted C1 to C6 alkanediyl group or a group represented by the formula (a-2);




wherein t represents 0 or 1;
X30 and X31 independently represents an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group;
A30 and A31 independently represent an optionally substituted C1 to C5 aliphatic hydrocarbon group;
A32 represents an optionally substituted C1 to C5 aliphatic hydrocarbon group or a single bond;
* represents a bond to W1;
W1 represents an optionally substituted C4 to C24 alicyclic hydrocarbon group, and one or more —CH2— contained in the alicyclic hydrocarbon group may be replaced by —O— or —CO—;
n represents 1 or 2;
Aab2 in each occurrence independently represents an optionally substituted C1 to C6 aliphatic hydrocarbon group, and one or more —CH2-contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—; and
Rab2 in each occurrence independently represents a C1 to C12 fluorinated alkyl group, and one or more hydrogen atom contained in the fluorinated alkyl group may be replaced by a hydroxy group or a hydroxymethyl group.
Examples of the alkanediyl group of the Aab1 include the same examples described in Aaa1 of the formula (aa). Examples of the substituent of the alkanediyl group include the same examples described above, i.e, a hydroxy group and a C1 to C6 alkoxy group.
Examples of the aliphatic hydrocarbon group of A30, A31 and A32 in the group (a-2) include the same examples described in A10, A11 and A12 of the group (a-1).
Examples of the group (a-2) except a group (a-2) in which A32 is a single bond include the same examples described in the formula (a-1)
Examples of the group (a-2) containing an oxygen atom in which A32 is a single bond include as below. In the formula, * represents a bond.




Examples of the group (a-2) containing a carbonyl group in which A32 is a single bond include as below.




Examples of the group (a-2) containing a carbonyloxy group in which A32 is a single bond include as below.




Examples of the group (a-2) containing an oxycarbonyl group in which A32 is a single bond include as below.




The group (a-2) may be a group containing two or more atoms or groups selected by the group consisting of a oxygen atom, a carbonyl group, an oxycarbonyl group and a carbonyloxy group. Examples of the group (a-2) containing an oxygen atom and a carbonyloxy group include as below.




Among theses, Aab1 is preferably an optionally substituted alkanediyl group or a single bond, more preferably non-substituted alkanediyl group or a single bond, and more preferably a single bond.
Examples of the alicyclic hydrocarbon group of W1 include a group in which (n+1) hydrogen atoms are removed from the above groups represented by the formula (KA-1) to the formula (KA-22), is preferably a C5 to C18 alicyclic hydrocarbon group, and more preferably a C6 to C12 alicyclic hydrocarbon group. Among these, a group in which (n+1) hydrogen atoms are removed from adamantane, cyclohexane, norbornane or norbornene ring is preferable, and a group in which (n+1) hydrogen atoms are removed from adamantane or cyclohexane ring is more preferable.
Examples of the alicyclic hydrocarbon group of W1 in which one or more —CH2— contained in the aliphatic hydrocarbon group is replaced by —O— or —CO— include, for example, alicyclic hydrocarbons below. The —CH2— contained in an alicyclic hydrocarbon group may preferably replaced by about two of —O— and/or —CO—.




When one or more —CH2— contained in the alicyclic hydrocarbon group is replaced by —O— or —CO—, the carbon number thereof is a carbon number before the —CH2— contained in the alicyclic hydrocarbon group is replaced by —O— or —CO—.
The alicyclic hydrocarbon group of W1 may have a substituent.
Examples of the substituent thereof include a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group.
Provided that the total carbon atom of the alicyclic hydrocarbon group and the substituent of W1 is preferably 4 to 36.
Examples of the alkyl group include methyl, ethyl, propyl, butyl, heptyl, hexyl and octyl groups. The alkyl group may be a liner or branched chain alkyl group.
Examples of the alkoxy group include methoxy, ethoxy, propoxy, butoxy, hexyloxy and octyloxy groups. The alkoxyl group may be a liner or branched chain alkoxyl group.
Examples of the alicyclic hydrocarbon group include cyclohexyl, adamantyl and norbornyl groups.
Examples of the aromatic hydrocarbon group include phenyl and naphtyl groups.
Aab2 may be an aliphatic hydrocarbon group which is either a saturated or an unsaturated group, preferably a saturated aliphatic hydrocarbon group, i.e., an alkanediyl group. Examples of the alkanediyl group of the Aab2 include the same examples described in Aaa1 of the formula (aa).
Examples of the aliphatic hydrocarbon group in which one or more —CH2-contained therein is replaced by —O— or —CO— include groups below. In the formula, * represents a bond.




Examples of the fluorinated alkyl group of Rab2 include a liner or branched chain fluorinated alkyl group such as difluoromethyl, trifluoromethyl, 1,1-difluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, perfluoroethyl, 1,1,2,2-tetrafluoropropyl, 1,1,2,2,3,3-hexafluoropropyl, perfluoroethylmethyl, 1-(trifluoromethyl)-1,2,2,2-tetratrifluoroethyl, perfluoropropyl, 1,1,2,2-tetrafluorobutyl, 1,1,2,2,3,3-hexafluorobutyl, 1,1,2,2,3,3,4,4-octafluorobutyl, perfluorobutyl, 1,1-bis(trifluoro)methyl-2,2,2-trifluoroethyl, 2-(perfluoropropyl)ethyl, 1,1,2,2,3,3,4,4-octafluoropentyl, perfluoropentyl, 1,1,2,2,3,3,4,4,5,5-decafluoropentyl, 1,1-bis(trifluoromethyl)-2,2,3,3,3-pentafluoropropyl, perfluoropentyl, 2-(perfluorobutyl)ethyl, 1,1,2,2,3,3,4,4,5,5-decafluorohexyl, 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorohexyl, perfluoropentylmethyl, perfluorohexyl groups and groups below.




Among these, a perfluoroalkyl group is preferable, and trifluoromethyl, perfluoroethyl, perfluoropropyl, perfluorobutyl, perfluoropentyl, perfluorohexyl, perfluoroheptyl and perfluorooctyl groups are more preferable.
The fluorinated alkyl group may be substituted with a group such as a hydroxyl and a hydroxymethyl group.
Examples of the —W1-(Aab2-Rab2)n include a group represented by the formula (W1-1) and a group represented by the formula (W1-2).




wherein one or more —CH2— contained in the adamantane ring may be replaced by —O— or —CO—;
one or more hydrogen atom contained in the adamantane ring may be replaced by a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
provided that the total carbon atom of the adamantane ring and the substituent is preferably 36 or less;
* represents a bond to Aab1;
Aab2, Rab2 and n have the same definition of the above.




wherein one or more —CH2— contained in the cyclohexane ring may be replaced by —O— or —CO—;
one or more hydrogen atom contained in the cyclohexane ring may be replaced by a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
provided that the total carbon atom of the adamantane ring and the substituent is preferably 36 or less;
* represents a bond to Aab1;
Aab2, Rab2 and n have the same definition of the above.
When one or more —CH2— contained in the adamantane ring or cyclohexane ring is replaced by —O— or —CO—, the number of the —CH2— to be replaced may be at most two, and preferably zero.
When one or more hydrogen atom contained in the adamantane ring or cyclohexane ring is replaced by the above substituent, the number of the substituent may be at most three, and the substituent(s) is in each occurrence independent.
n is preferably 1, and, therefore, W1 is preferably a divalent group. When n is 1, adamantanediyl and cyclohexandiyl groups are preferable for W1.
Examples of the structural unit (ab) in which n is 1 includes below. In addition, examples of the structural unit (ab) also include compounds in which the adamantane ring in the structural unit below is replaced by the cyclohexane ring. When n is 2, examples of the structural unit (ab) may includes structural units in which one or more hydrogen atom contained in the adamantane group is replaced by -Aab2-Rab2 (the definitions of Aab2 and Rab2 are the same meaning in the structural unit (ab)).



















Further, examples of the structural units (ab) include structural units in which a partial structure M of the structural units described above is replaced by a partial structure A as described above.
The structural unit (ab) is derived from the compound represented by the formula (ab′), hereinafter may be referred to as “compound (ab′)”.




wherein Aab1, Aab2, Rab1, Rab2 and n have the same definition of the above.
The compound (ab′) can be produced by a known method or a modified method thereof, for example, according to the method described in the pamphlet of WO 2008/015876, for example.
When the resin (X) is produced, the compound (aa′) and the compound (ab′) may be used as a single compound or as a mixture of two or more compounds, respectively, and it is preferable that one compound (aa′) and one compound (ab′) is used from the aspect of easy production of the resin (X).
Examples of the combination of the structural unit (aa) and the structural unit (ab) in the resin (X) as described below.











TABLE 1







Resin (X)
Structural Unit (aa)
Structural Unit (ab)









X-1
(aa-6)
(ab-1)



X-2
(aa-6)
(ab-3)



X-3
(aa-2)
(ab-1)



X-4
(aa-2)
(ab-3)



X-5
(aa-4)
(ab-1)



X-6
(aa-4)
(ab-3)



X-7
(aa-6)/(aa-4)
(ab-3)



X-8
(aa-6)/(aa-2)
(ab-3)



X-9
(aa-2)/(aa-4)
(ab-3)



X-10
(aa-6)/(aa-4)
(ab-1)



X-11
(aa-6)/(aa-2)
(ab-1)



X-12
(aa-2)/(aa-4)
(ab-1)



X-13
(aa-6)
(ab-1)/(ab-3)



X-14
(aa-6)/(aa-4)
(ab-1)/(ab-3)



X-15
(aa-6)
(ab-5)



X-16
(aa-6)
(ab-7)



X-17
(aa-6)
(ab-2)



X-18
(aa-8)
(ab-3)



X-19
(aa-10)
(ab-3)



X-20
(aa-15)
(ab-3)



X-21
(I-4)
(ab-1)



X-22
(I-4)
(ab-3)



X-23
(I-5)
(ab-1)



X-24
(I-5)
(ab-3)



X-25
(I-16)
(ab-1)



X-26
(I-16)
(ab-3)



X-27
(I-5)/(aa-4)
(ab-1)



X-28
(I-5)/(aa-4)
(ab-3)





















TABLE 2







Resin (X)
Structural Unit (aa)
Structural Unit (ab)









X-1′
(aa-6)
(ab-1′)



X-2′
(aa-6)
(ab-3′)



X-3′
(aa-2)
(ab-1′)



X-4′
(aa-2)
(ab-3′)



X-5′
(aa-4)
(ab-1′)



X-6′
(aa-4)
(ab-3′)



X-7′
(aa-6)/(aa-4)
(ab-3′)



X-8′
(aa-6)/(aa-2)
(ab-3′)



X-9′
(aa-2)/(aa-4)
(ab-3′)



X-10′
(aa-6)/(aa-4)
(ab-1′)



X-11′
(aa-6)/(aa-2)
(ab-1′)



X-12′
(aa-2)/(aa-4)
(ab-1′)



X-13′
(aa-6)
(ab-1′)/(ab-3′)



X-14′
(aa-6)/(aa-4)
(ab-1′)/(ab-3′)



X-15′
(aa-6)
(ab-5′)



X-16′
(aa-6)
(ab-7′)



X-17′
(aa-6)
(ab-2′)



X-18′
(aa-8)
(ab-3′)



X-19′
(aa-10)
(ab-3′)



X-20′
(aa-15)
(ab-3′)



X-21′
(I-4)
(ab-1′)



X-22′
(I-4)
(ab-3′)



X-23′
(I-5)
(ab-1′)



X-24′
(I-5)
(ab-3′)



X-25′
(I-16)
(ab-1′)



X-26′
(I-16)
(ab-3′)



X-27′
(I-5)/(aa-4)
(ab-1′)



X-28′
(I-5)/(aa-4)
(ab-3′)










Among these, X-1 to X-28 for resin (X) are preferable.
The total proportion of the structural unit (aa) (or the structural unit (I)) and the structural unit (ab) in the resin (X) is generally 1 to 100 mol %, preferably 5 to 100 mol %, and more preferably 10 to 100 mol %, with respect to the total structural unit (100 mol %) of the resin (X).
The proportion of the structural unit (aa) (or the structural unit (I)) and the proportion of the structural unit (ab) in the resin (X) are generally 5 to 95 mol %, preferably 10 to 90 mol %, respectively, with respect to the total structural unit (100 mol %) of the resin (X).
The weight ratio of the structural unit (aa) (or the structural unit (I)):the structural unit (ab) in the resin (X) may be 1:99 to 99:1, preferably 3:97 to 97:3, and more preferably 50:50 to 95:5.
For achieving the proportion of the structural unit (aa) and the structural unit (ab) in the resin (X) within the above range, the amount of the compound (aa′) and the compound (ab′) to be used can be adjusted with respect to the total amount of the monomer to be used when the resin (X) is produced (the same shall apply hereinafter for corresponding adjustment of the proportion).
The resin (X) may have one or more structural unit(s) other than the structural unit (aa) and the structural unit (ab). Examples of such structural unit(s) include any of structural units or monomers as described below, and known compounds, among these, the structural unit derived from an acid stable monomer (a4) as described below is preferable.
<Resin (A)>
The resin (A) has properties that are insoluble or poorly soluble in alkali aqueous solution, but become soluble in an alkali aqueous solution by the action of an acid as described above. Therefore, the resin (A) has one or more acid-labile group in its molecular, i.e., the resin (A) has one or more structural unit having one or more acid-labile group. Hereinafter, the structural unit having the acid-labile group may refer to as a “structural unit (a1)”, and a monomer giving the structural unit (a1) may refer to as an “acid-labile monomer (a1)”.
Here, the “acid-labile group” means a group in which an elimination group (i.e., the protecting group) is cleaved in contact with the acid and resulting in having a hydrophilic group. Examples of the hydrophilic group include a carboxy and a hydroxy group, and a carboxy group is preferable.
The resin (A) may have the structural unit (aa) or the structural unit (ab), but may not have both of the structural unit (aa) and the structural unit (ab).
When the resin (X) has the above properties, the acid-labile group is preferably contained in the resin (X) in addition to the structural unit (aa) and the structural unit (ab).
A resist pattern can be produced from the present resist composition by using such resin through the synergism of the resin and the acid generator (B).
<Acid-labile Group>
Examples of the acid-labile group when the hydrophilic group is carboxy group include a group in which one or more hydrogen atom of the carboxyl group (i.e., —COOH) is replaced with an organic group and an atom of the organic group which bonds to —O— of the carboxyl group is tertiary carbon atom, i.e., an ester of a tertiary alcohol.
Among such the acid-labile group, preferred examples thereof include a group represented by the formula (1) below. Hereinafter the group represented by the formula (1) may refer to as an “acid-labile group (1)”.




wherein Ra1, Ra2 and Ra3 independently represent a C1 to C8 alkyl group, a C3 to C20 alicyclic hydrocarbon group, or Ra1 and Ra2 may be bonded together with a carbon atom bonded to Ra1 and Ra2 to form a C3 to C20 ring, one or more —CH2— contained in the alkyl group, the alicyclic hydrocarbon group and the ring may be replaced by —O—, —S— or —CO—, * represents a bond.
Examples of the alkyl group of Ra1 to Ra3 include methyl, ethyl, propyl, butyl, pentyl and hexyl groups.
Examples of the alicyclic hydrocarbon group of Ra1 to R3 include a monocyclic hydrocarbon groups such as cyclopentyl, cyclohexyl, methylcyclohexyl, dimethylcyclohexyl, cycloheptyl, cyclooctyl groups; and polycyclic hydrocarbon groups such as decahydronaphthyl, adamantyl, norbornyl (i.e., bicyclo[2.2.1]hexyl), and methyl norbornyl groups as well as groups as below.




When Ra1 and Ra2 are bonded together to form a ring, examples of the group —C(Ra1)(Ra2)(Ra3) include a group below.




The ring preferably has 3 to 12 carbon atoms.
In the formula (1), the alicyclic hydrocarbon group of Ra1 to Ra3 preferably has 3 to 16 carbon atoms, and more preferably has 3 to 12 carbon atoms.
Specific examples of the acid-labile group include, for example,
1,1-dialkylalkoxycarbonyl group (a group in which Ra1 to Ra3 are alkyl groups, preferably tert-butoxycarbonyl group, in the formula (1)),
2-alkyladamantane-2-yloxycarbonyl group (a group in which Ra1, Ra2 and a carbon atom forms adamantyl group, and Ra3 is alkyl group, in the formula (1)), and
1-(adamantine-1-yl)-1-alkylalkoxycarbonyl group (a group in which Ra1 and Ra2 are alkyl group, and Ra3 is adamantyl group, in the formula (1)).
Examples of the acid-labile group when the hydrophilic group is a hydroxy group include a group in which a hydrogen atom of the hydroxy group is replaced by an organic group and resulting in having an acetal structure or a ketal structure. Among such the acid-labile group, preferred examples thereof include a group represented by the formula (2) below. Hereinafter the group represented by the formula (2) may refer to as an “acid-labile group (2)”.




wherein Rb1 and Rb2 independently represent a hydrogen atom or a C1 to C20 hydrocarbon group, Rb3 represents a C1 to C20 hydrocarbon group, or Rb2 and Rb3 may be bonded together with a carbon atom and an oxygen atom bonded to Rb2 and Rb3 respectively to form a C3 to C20 ring. One or more —CH2— contained in the hydrocarbon group and the ring may be replaced by —O—, —S— or —CO—, * represents a bond.
The hydrocarbon group of Rb1 to Rb3 includes any of an alkyl group, an alicyclic hydrocarbon group and an aromatic hydrocarbon group.
Examples of the ring which is formed by bonding with Rb2 and Rb3 include rings in which a carbon atom is replaced by an oxygen atom in the ring which are formed by bonding with Rat and Rae.
At least one of Rb1 and Rb2 is preferably a hydrogen atom.
Specific examples of the acid-labile group (2) include a group below.




The structural unit having the acid-labile group is preferably a structural unit having an acid-labile group and a carbon-carbon double bond, and more preferably a structural unit derived from a (meth)acrylic monomer having the acid-labile group.
Preferable examples of the structural unit (a1) include a structural unit having an acid-labile group (1) and/or an acid-labile group (2), and a structural unit having an acid-labile group (1) is more preferable.
Among the structural unit having an acid-labile group (1), it is preferably a structural unit containing an acid-labile group (1) having a C5 to C20 alicyclic hydrocarbon structure. When the resin (A) which can be obtained by polymerizing monomers having bulky structure such as the alicyclic hydrocarbon group is used, the resist composition having excellent resolution tends to be obtained during the production of a resist pattern.
<Acid-Labile Structural Unit (a1)>
As the structural unit derived from the (meth)acrylic monomer containing an acid-labile group (1) having the alicyclic hydrocarbon structure, examples thereof include a structural unit represented by the formula (a1-1) (hereinafter may be referred to as a “structural unit (a1-1)”) and a structural unit represented by the formula (a1-2) (hereinafter may be referred to as a “structural unit (a1-2)”). The structural unit (a1-1) and the structural unit (a1-2) may be used as a single unit or as a combination of two or more units.




wherein La1 and La2 independently represent *—O— or *—O—(CH2)k1—CO—O—, k1 represents an integer of 1 to 7, * represents a bond to the carbonyl group (—CO—);
Ra4 and Ra5 independently represent a hydrogen atom or a methyl group;
Ra6 and Ra7 independently represent a C1 to C10 aliphatic hydrocarbon group;
m1 represents an integer 0 to 14;
n1 represents an integer 0 to 10; and
n1′ represents an integer 0 to 3.
In the formula (a1-1) and the formula (a1-2), La1 and La2 are preferably —O— or *—O—(CH2)k1′—CO—O—, here k1′ represents an integer of 1 to 4, more preferably *—O— or *—O—CH2—CO—O—, and still more preferably *—O—.
Ra4 and Ra5 are preferably a methyl group.
The aliphatic hydrocarbon groups of Ra6 and Ra7 are independently preferably a C1 to C8 alkyl group or C3 to C10 alicyclic hydrocarbon group, more preferably a C1 to C8 alkyl group or C3 to C8 alicyclic hydrocarbon group, and still more preferably a C1 to C6 alkyl group or C3 to C6 alicyclic hydrocarbon group.
m1 is preferably an integer of 0 to 3, and more preferably 0 or 1.
n1 is preferably an integer of 0 to 3, and more preferably 0 or 1.
n1′ is preferably 0 or 1, and more preferably 1.
Examples of the structural unit (a1-1) include structural units below.

























Also, examples of the structural units (a1-1) include structural units in which a partial structure M of the structural units represented by the formula (a1-1-1) to the formula (a1-1-38) is replaced by a partial structure A as described above.
Among these, structural units represented by the formula (a1-1-1), the formula (a1-1-2), the formula (a1-1-3) and the structural units in which a partial structure M of the structural units represented by the formula (a1-1-1), the formula (a1-1-2), the formula (a1-1-3) is replaced by a partial structure A are preferable, structural units represented by the formula (a1-1-1), the formula (a1-1-2) and the formula (a1-1-3) are more preferable, and structural units represented by the formula (a1-1-1) and the formula (a1-1-2) are still more preferable.
When the resin (A) having the structural unit of (a1-1) is produced, 2-methyl-2-adamantane-2-yl(meth)acrylate, 2-ethyl-2-adamantane-2-yl(meth)acrylate and 2-isopropyl-2-adamantane-2-yl (meth)acrylate may be used as a starting material (i.e., monomer).
Examples of the structural unit (a1-2) include structural units below.







Also, examples of the structural units (a1-2) include structural units in which a partial structure M of the structural units represented by the formula (a1-2-1) to the formula (a1-2-12) is replaced by a partial structure A as described above.
Among these, structural units represented by the formula (a1-2-1), the formula (a1-2-2), the formula (a1-2-4), the formula (a1-2-5) and the structural units in which a partial structure M of the structural units represented by the formula (a1-2-1), the formula (a1-2-2), the formula (a1-2-4), the formula (a1-2-5) is replaced by a partial structure A are preferable, structural units represented by the formula (a1-2-4), the formula (a1-2-5) and the structural units in which a partial structure M of the structural units represented by the formula (a1-2-4) and the formula (a1-2-5) replaced by a partial structure A are more preferable.
When the resin (A) having the structural unit of (a1-2) is produced, 2-methylcyclohexane-2-yl(meth)acrylate may be used as a starting material (i.e., monomer).
When the resin (A) contains the structural unit (a1-1) and/or the structural unit (a1-2), the total proportion thereof is generally 10 to 95 mol %, preferably 15 to 90 mol %, more preferably 20 to 85 mol %, and more preferably 25 to 60 mol %, with respect to the total structural units (100 mol %) of the resin (A).
When the resin (X) contains the structural unit (a1-1) and/or the structural unit (a1-2), the total proportion thereof is generally 5 to 50 mol %, preferably 10 to 45 mol %, and more preferably 15 to 40 mol %, with respect to the total structural units (100 mol %) of the resin (X).
For achieving the proportion of the structural units (a1-1) and/or the structural units (a1-2) within the above range, the amount of the monomer giving the structural unit (a1-1) and/or the monomer giving the structural unit (a1-2) to be used can be adjusted with respect to the total amount of the monomer to be used when the resin (A) is produced (the similar shall apply hereinafter for corresponding adjustment of the proportion).
When the resin (X) is produced, the amount of the monomer giving the structural unit (a1-1) and/or the monomer giving the structural unit (a1-2) to be used can be adjusted with respect to the total amount of the compound (aa′) and the compound (ab′) to be used.
<Acid-Labile Monomer>
Examples of the monomers having an acid-labile group (1) and a carbon-carbon double bond include a monomer having norbornene ring presented by the formula (a1-3). Such monomer may be hereinafter referred to as “monomer (a1-3)”.




wherein Ra9 represents a hydrogen atom, a C1 to C3 alkyl group that optionally has a hydroxy group, a carboxy group, a cyano group or a —COORa13,
Ra13 represents a C1 to C20 aliphatic hydrocarbon group, one or more hydrogen atom contained in the aliphatic hydrocarbon group may be replaced by a hydroxy group, one or more —CH2— contained therein may be replaced by —O— or —CO—;
Ra10, Ra11 and Ra12 independently represent a C1 to C20 aliphatic hydrocarbon group, or Ra10 and Ra11 may be bonded together to form a C1 to C20 ring, one or more hydrogen atom contained in the aliphatic hydrocarbon group and the ring may be replaced by a hydroxy group or the like, one or more —CH2— contained in the aliphatic hydrocarbon group and the ring may be replaced by —O— or —CO—.
Examples of the alkyl group having a hydroxy group of Ra9 include hydroxymethyl and 2-hydroxyethyl groups.
The aliphatic hydrocarbon group of Ra10 to Ra12 is any of a chain aliphatic hydrocarbon group (e.g., alkyl group), an alicyclic hydrocarbon group and a combination thereof. Examples of the aliphatic hydrocarbon group of Ra10 to Ra12 include methyl, ethyl, cyclohexyl, methylcyclohexyl, hydroxycyclohexyl, oxocyclohexyl and adamantyl groups.
Preferable examples of the ring formed together with Ra10 and Ra11 include an alicyclic hydrocarbon group such as cyclohexane and adamantane ring.
The aliphatic hydrocarbon group of Ra13 is preferably a C1 to C8 alkyl group and a C3 to C20 alicyclic hydrocarbon group, examples of the —COORa13 group include a group in which a carbonyl group bonds to an alkoxy group, such as methoxycarbonyl and ethoxycarbonyl groups.
Examples of the monomer having a norbornene ring (a1-3) include, for example, tert-butyl 5-norbornene-2-carboxylate, 1-cyclohexyl-1-methylethyl 5-norbornene-2-carboxylate, 1-methylcyclohexyl 5-norbornene-2-carboxylate, 2-methyl-2-adamantane-2-yl 5-norbornene-2-carboxylate, 2-ethyl-2-adamantane-2-yl 5-norbornene-2-carboxylate, 1-(4-methylcyclohexyl)-1-methylethyl 5-norbornene-2-carboxylate, 1-(4-hydroxycyclohexyl)-1-methylethyl 5-norbornene-2-carboxylate, 1-methyl-(4-oxocyclohexyl)-1-ethyl 5-norbornene-2-carboxylate, and 1-(1-adamantane-1-yl)-1-methylethyl 5-norbornene-2-carboxylate.
A resin having a structural unit derived from the monomer (a1-3) can improve the resolution of the obtained resist composition because it has a bulky structure, and also can improve a dry-etching tolerance of the obtained resist composition because of incorporated a rigid norbornene ring into a main chain of the resin (A).
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a1-3), the proportion thereof is generally 10 to 95 mol %, preferably 15 to 90 mol %, and more preferably 20 to 85 mol %, with respect to the total structural units (100 mol %) constituting the resin (A), from the aspect of the improvement of the resolution and/or the dry-etching tolerance.
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a1-3), the proportion thereof is generally 5 to 50 mol %, preferably 10 to 45 mol %, and more preferably 15 to 40 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
Examples of a monomer having an acid-labile group (2) and a carbon-carbon double bond include a monomer represented by the formula (a1-4). Such monomer may be hereinafter referred to as “monomer (a1-4)”.




wherein Ra32 represents a hydrogen atom, a halogen atom or a C1 to C6 alkyl group that optionally has a halogen atom (i.e., haloalkyl group);
Ra33 in each occurrence independently represent a halogen atom, a hydroxy group, a C1 to C6 alkyl group, a C1 to C6 alkoxy group, a C2 to C4 acyl group, a C2 to C4 acyloxy group, an acryloyl group or methacryloyl group;
la represents an integer 0 to 4;
Ra34 and Ra35 independently represent a hydrogen atom or a C1 to C12 hydrocarbon group;
Xa2 represents a single bond or an optionally substituted C1 to C17 divalent aliphatic hydrocarbon group, one or more hydrogen atom contained therein may be replaced by a halogen atom, a hydroxy group, a C1 to C6 alkoxy group, a C2 to C4 acyl group or a C2 to C4 acyloxy group, and one or more —CH2— contained therein may be replaced by —CO—, —O—, —S—, —SO2— or —N(Rc)—, Rc represents a hydrogen atom or a C1 to C6 alkyl group;
Ya3 represents a C1 to C18 hydrocarbon group, one or more hydrogen atom contained therein may be replaced by a halogen atom, a hydroxy group, a C1 to C6 alkyl group, a C1 to C6 alkoxy group, a C2 to C4 acyl group, and a C2 to C4 acyloxy group.
Examples of the alkyl group that optionally has a halogen atom of Ra32 include trifluoromethyl, perfluoroethyl, perfluoropropyl, perfluoro-isopropyl, perfluorobutyl, perfluoro-sec-butyl, perfluoro-tert-butyl, perfluoropentyl, perfluorohexyl, trichloromethyl, triburomomethyl and triiodomethyl groups.
Examples of the alkoxyl group include methoxy, ethoxy, propoxy, butoxy, pentyloxy and hexyloxy groups.
Examples of the acyl group include acetyl, propionyl and butyryl groups.
Examples of the acyloxy group include acetyloxy, propionyloxy and butyryloxy groups.
In the formula (a1-4), the alkyl group of Ra32 and Ra33 is preferably a C1 to C4 alkyl group, more preferably a C1 to C2 alkyl group, and still more preferably methyl group.
The alkoxy group of Ra33 is preferably a C1 to C4 alkoxy group, more preferably a C1 to C2 alkoxy group, and still more preferably methoxy group.
Examples of the hydrocarbon group of Ra34 and Ra35 include any of a chain aliphatic hydrocarbon group, an alicyclic hydrocarbon group and an aromatic hydrocarbon group.
Preferred examples of the aliphatic hydrocarbon group include an alkyl group such as iso-propyl, n-butyl, sec-butyl, tert-butyl, pentyl, hexyl, octyl, and 2-ethylhexyl groups.
Preferred examples of the alicyclic hydrocarbon group include a monocyclic or polycyclic saturated hydrocarbon groups such as cyclohexyl, adamantyl, 2-alkyl-2-adamantan-2-yl, 1-(1-adamantan-1-yl)-1-alkyl, and isobornyl groups.
Preferred examples of the aromatic hydrocarbon group include phenyl, naphthyl, p-methylphenyl, p-tert-butylphenyl, p-adamantylphenyl, tolyl, xylyl, cumenyl, mesityl, biphenyl, anthryl, phenanthryl, 2,6-diethylphenyl and 2-methyl-6-ethylphenyl groups.
The aliphatic hydrocarbon group of Xa2 is preferably a chain aliphatic hydrocarbon group, and more preferably an alkyl group.
The hydrocarbon group of Ya3 is preferably a C3 to C18 alicyclic hydrocarbon group and a C6 to C18 aromatic hydrocarbon group.
Preferred examples of the substituent that may be optionally substituted to Xa2 and Ya3 include a hydroxy group.
Examples of the monomer represented by the formula (a1-4) include a monomer below.













Also, examples of the monomer (a1-4) include monomers in which a partial structure P of the monomers above are replaced by a partial structure V as described below.




When the resin (A) contains the structural unit derived from the monomer represented by the formula (a1-4), the proportion thereof is generally 10 to 95 mol %, preferably 15 to 90 mol %, more preferably 20 to 85 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a1-4), the proportion thereof is generally 5 to 50 mol %, preferably 10 to 45 mol %, and more preferably 15 to 40 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
Examples of a monomer having an acid-labile group (2) and a carbon-carbon double bond include a monomer represented by the formula (a1-5). Such monomer may be hereinafter referred to as “monomer (a1-5)”.




wherein R31 represents a hydrogen atom, a halogen atom or a C1 to C6 alkyl group that optionally has a halogen atom;
L1, L2 and L3 independently represent *—O—, *—S— or *—O—(CH2)k1—CO—O—, k1 represents an integer of 1 to 7, * represents a bond to the carbonyl group (—CO—);
s1 represents an integer of 0 to 4;
s1′ represents an integer of 0 to 4;
Z1 represents a single bond or a C1 to C6 alkanediyl group, and one or more —CH2— contained in the alkanediyl group may be replaced by —O— or —CO—.
In the formula (a1-5), R31 is preferably a hydrogen atom or a methyl group;
L1 is preferably —O—;
L2 and L3 are independently preferably *—O— or *—S—, and more preferably —O— for one and —S— for another;
s1 is preferably 1;
s1′ is preferably an integer of 0 to 2;
Z1 is preferably a single bond or —CH2—CO—O—.
Examples of the compound represented by the formula (a1-5) include compounds below.




Also, examples of the monomer (a1-5) include monomers in which a partial structure V of the monomers above are replaced by a partial structure P as described above.
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a1-5), the proportion thereof is generally 10 to 95 mol %, preferably 15 to 90 mol %, and more preferably 20 to 85 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a1-5), the proportion thereof is generally 5 to 50 mol %, preferably 10 to 45 mol %, and more preferably 15 to 40 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
Further, a monomer derived from another structural unit having an acid-labile group (1) and carbon-carbon double bond may be used.
Specific examples of such another monomer include a monomer below.







When the resin (A) contains the structural unit derived from the other acid-labile monomer, the proportion thereof is generally 10 to 95 mol %, preferably 15 to 90 mol %, and more preferably 20 to 85 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the other acid-labile monomer, the proportion thereof is generally 5 to 50 mol %, preferably 10 to 45 mol %, and more preferably 15 to 40 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
<Acid-Stable Structural Unit>
The resin (X) is preferably a copolymer having a structural unit derived from a monomer not having the acid-labile group (hereinafter may be referred to as an “acid-stable structural unit”) in addition to the structural unit (aa), the structural unit (ab).
The resin (A) is preferably a copolymer having the acid-stable structural unit in addition to the acid-labile structural unit (a1).
The acid-stable structural unit may be used as a single unit or as a combination of two or more units.
<Acid-Stable Structural Unit (a2)>
As the acid-stable structural unit, a structural unit having a hydroxy group or a lactone ring is preferable. When a resin containing the structural unit having hydroxy group (hereinafter such acid-stable structural unit may be referred to as “acid-stable structural unit (a2)”) or the acid-stable structural unit having a lactone ring (hereinafter such acid-stable structural unit may be referred to as “acid-stable structural unit (a3)”) is used, the adhesiveness of resist to a substrate and resolution of resist tend to be improved.
The acid-stable structural unit (a2) is preferably selected depending on the kinds of an exposure light source at producing the resist pattern.
For example, when KrF excimer laser lithography (248 nm), or high-energy irradiation such as electron beam or EUV light is used for the resist composition, using the acid-stable monomer having a phenolic hydroxy group (a2-0) such as hydroxystyrene as the acid-stable structural unit (a2) having the hydroxy group is preferable.
When ArF excimer laser lithography (193 nm), i.e., short wavelength excimer laser lithography is used, using the acid-stable monomer having a hydroxy adamantyl group represented by the formula (a2-1) as the acid-stable structural unit (a2) having the hydroxy group is preferable.
The acid-stable structural unit (a2) having the hydroxy group may be used as a single unit or as a combination of two or more units.
<Acid-Stable Structural Unit (a2-0)>
Examples of the acid-stable structural unit (a2) having phenolic hydroxy group include a structural unit represented by the formula (a2-0) (hereinafter the structural unit may be referred to as “acid-stable structural unit (a2-0)”) such as p- or m-hydroxystyrene.




wherein Ra30 represents a hydrogen atom, a halogen atom or a C1 to C6 alkyl group that optionally has a halogen atom;
Ra31 in each occurrence independently represents a halogen atom, a hydroxy group, a C1 to C6 alkyl group, a C1 to C6 alkoxy group, a C2 to C4 acyl group, a C2 to C4 acyloxy group, an acryloyl group or methacryloyl group;
ma represents an integer 0 to 4.
In the formula (a2-0), examples of the alkyl group having a halogen atom of Ra30 include the same examples described in Ra32 of the formula (a1-4).
The alkyl group of Ra30 and Ra31 is preferably a C1 to C4 alkyl group, more preferably a C1 to C2 alkyl group, and still more preferably methyl group.
Examples of the alkoxy group of Ra31 include the same examples described in Ra33 of the formula (a1-4).
The alkoxy group of Ra31 is preferably a C1 to C4 alkoxy group, more preferably a C1 to C2 alkoxy group, and still more preferably methoxy group.
ma is preferably 0, 1 or 2, more preferably 0 or 1, and still more preferably 0.
Specific examples of the acid-stable structural unit (a2-0) include structural units derived from monomers below.




Also, examples thereof include a monomer in which methyl or ethyl group bonding the benzene ring is replaced by at least one substituent described in the examples of Ra31.
When the resin (A) is produced using the monomer providing the acid-stable structural unit (a2-0), a monomer in which the phenolic hydroxy group is protected by a protecting group can be used. Such protecting group may be a group which can be deprotected through contact with an acid or a base. Because the phenolic hydroxy group protected by the protecting group is deprotected through contact with the acid or the base, the acid-stable monomer (a2-0) can be easily obtained. However, because the resin (A) has the structural unit derived from the monomer having the acid-labile group (a1) as described above, when the phenolic hydroxy group protected by the protecting group is deprotected, the phenolic hydroxy group is preferably placed in contact with the base, so that the acid-labile group does not get seriously impaired. Examples of the protecting group which is deprotectable by the base include an acetyl group or benzoyl group. Examples of the base include 4-dimethylaminopyrizine and triethylamine.
Among these, 4-hydroxystyrene and 4-hydroxy-α-methylstyrene are preferable. These 4-hydroxystyrene and 4-hydroxy-α-methylstyrene may be protected its phenolic hydroxy group by an appropriate protecting group.
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a2-0), the proportion thereof is generally 5 to 95 mol %, preferably 10 to 80 mol %, and more preferably 15 to 80 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a2-0), the proportion thereof is generally 0 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
<Acid-Stable Structural Unit (a2-1)>
Examples of the acid-stable structural unit having a hydroxy adamantyl group include a structural unit represented by the formula (a2-1) (hereinafter the structural unit may be referred to as “acid-stable structural unit (a2-1)”).




wherein La3 represents *—O— or *—O—(CH2)k2—CO—O—, k2 represents an integer of 1 to 7, * represents a bond to a carbonyl group (—CO—);
Ra14 represents a hydrogen atom or a methyl group;
Ra15 and Ra16 independently represent a hydrogen atom, a methyl group or a hydroxy group;
o1 represents an integer of 0 to 10.
In the formula (a2-1), La3 is preferably *—O—, *—O—(CH2)k2′, —CO—O—, here k2′ represents an integer of 1 to 4, and more preferably *—O— or *—O—CH2—CO—O—, and still more preferably *—O—;
Ra14 is preferably a methyl group.
Ra15 is preferably a hydrogen atom.
Ra16 is preferably a hydrogen atom or a hydroxy group.
o1 is preferably an integer of 0 to 3, and more preferably an integer of 0 or 1.
Examples of the acid-stable structural unit (a2-1) having the hydroxy adamantyl group include units below.













Further, examples of the structural units (a2-1) include structural units in which a partial structure M of the structural units represented by the formula (a1-1-1) to the formula (a1-1-17) is replaced by a partial structure A as described above.
Among these, structural units represented by the formula (a1-1-1), the formula (a1-1-2), the formula (a1-1-13), the formula (a1-1-15) and the structural units in which a partial structure M of the structural units represented by the formula (a1-1-1), the formula (a1-1-2), the formula (a1-1-13) and the formula (a1-1-15) is replaced by a partial structure A are preferable, structural units represented by the formula (a1-1-1), the formula (a1-1-2), the formula (a1-1-13) and the formula (a1-1-15) are more preferable.
When the resin (A) having the structural unit of (a2-1) is produced, 3-hydroxyadamantane-1-yl(meth)acrylate, 3,5-dihydroxyadamantane-1-yl (meth)acrylate and 1-(3,5-dihydroxyadamantane-1-yl oxycarbonyl)methyl (meth)acrylate may be used as a starting material (i.e., monomer).
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a2-1), the proportion thereof is generally 3 to 40 mol %, preferably 5 to 35 mol %, and more preferably 5 to 30 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a2-1), the proportion thereof is generally 1 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
<Acid-Stable Structural Unit (a3)>
The lactone ring included in the acid-stable structural unit (a3) may be a monocyclic compound such as p-propiolactone ring, γ-butyrolactone, δ-valerolactone, or a condensed ring with monocyclic lactone ring and other ring. Among these, γ-butyrolactone and condensed ring with γ-butyrolactone and other ring are preferable.
Examples of the acid-stable structural unit (a3) having the lactone ring include structural units represented by any of the formula (a3-1), the formula (a3-2) or the formula (a3-3). Hereinafter these structural units may be referred to as “acid-stable structural unit (a3-1)”, “acid-stable structural unit (a3-2)” or “acid-stable structural unit (a3-3)”. These structural units may be used as a single unit or as a combination of two or more units.




wherein La4, La5 and La6 independently represents *—O— or —O—(CH2)k3—CO—O—, k3 represents an integer of 1 to 7, * represents a bond to a carbonyl group;
Ra18, Ra19 and Ra20 independently represent a hydrogen atom or a methyl group;
Ra21 in each occurrence represents a C1 to C4 aliphatic hydrocarbon group;
Ra22 and Ra23 in each occurrence independently represent a carboxy group, a cyano group or a C1 to C4 aliphatic hydrocarbon group;
p1 represents an integer of 0 to 5;
q1 and r1 independently represent an integer of 0 to 3.
In the formulae (a3-1) to (a3-3), La4 to La6 is independently preferably —O—, *—O—(CH2)k3′—CO—O—, here k3′ represents an integer of 1 to 4, more preferably —O— or *—O—CH2—CO—O—, and still more preferably *—O—.
Ra18 to Ra20 is preferably a methyl group.
Ra21 is preferably a methyl group.
Ra22 and Ra23 are independently preferably a carboxy group, a cyano group or a methyl group.
p1, q1 and r1 are independently preferably an integer of 0 to 2, and more preferably 0 or 1.
Examples of the acid-stable structural units having γ-butyrolactone ring (a3-1) include units below.










Examples of the acid-stable structural units having γ-butyrolactone ring and norbornene ring (a3-2) include units below.










Examples of the acid-stable structural units having a condensed ring with γ-butyrolactone ring and cyclohexane ring (a3-3) include units below.







Also, examples of the structural units (a3-1), the structural units (a3-2) and the structural units (a3-3) include structural units in which a partial structure M of the structural units represented by the formula (a3-1-1) to the formula (a3-1-11), the structural units represented by the formula (a3-2-1) to the formula (a3-2-11) and the structural units represented by the formula (a3-3-1) to the formula (a3-3-6) is replaced by a partial structure A as described above.
Further, examples thereof include the structural units in which methyl group bonding the lactone ring is replaced by at least one substituent described in the examples of Ra21, Ra22 and Ra23.
Among the acid-stable structural unit having lactone ring (a3), the acid-stable structural unit derived from α-(meth)acryloyloxy-γ-butyrolactone, β-(meth)acryloyloxy-γ-butyrolactone, α-(meth)acryloyloxy-β, β-dimethyl-γ-butyrolactone, α-(meth)acryloyloxy-α-methyl-γ-butyrolactone, β-(meth)acryloyloxy-α-methyl-γ-butyrolactone, (5-oxo-4-oxatricyclo[4.2.1.03,7]nonane-2-yl) (meth)acrylate, tetrahydro-2-oxo-3-furyl(meth)acrylate, and 2-(5-oxo-4-oxatricyclo[4.2.1.03,7]nonane-2-yloxy)-2-oxoethyl(meth)acrylate are preferable.
When the resin (A) contains the structural unit represented by the formula (a3-1), the structural unit represented by the formula (a3-2) and/or the structural unit represented by the formula (a3-3), the total proportion thereof is preferably 5 to 70 mol %, more preferably 10 to 65 mol %, still more preferably 10 to 60 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (A) contains the structural unit represented by the formula (a3-1), the structural unit represented by the formula (a3-2) and/or the structural unit represented by the formula (a3-3), the proportion thereof is preferably 5 to 60 mol %, more preferably 10 to 55 mol %, still more preferably 20 to 50 mol %, and further more preferably 20 to 45 mol %, with respect to the total structural units (100 mil %) constituting the resin (A), respectively.
When the resin (X) contains the structural unit represented by the formula (a3-1), the structural unit represented by the formula (a3-2) and/or the structural unit represented by the formula (a3-3), the total proportion thereof is generally 0 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
<Acid-Stable Monomer (a4)>
Examples of the acid-stable monomer other than the above include maleic anhydride represented by the formula (a4-1), itaconic anhydride represented by the formula (a4-2) or an acid-stable monomer having norbornene ring represented by the formula (a4-3), for example, hereinafter the monomers may be referred to as “acid-stable monomer (a-4-1)”, “acid-stable monomer (a-4-2)” and “acid-stable monomer (a-4-3)”, respectively.




wherein Ra25 and Ra26 independently represent a hydrogen atom, a C1 to C3 alkyl group that optionally has a hydroxy group, a cyano group, a carboxy group or —COORa27, or Ra25 and Ra26 may be bonded together to form —CO—O—CO—,
Ra27 represents a C1 to C18 aliphatic hydrocarbon group, one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—, provided that excluding a group in which the —COORa27 is an acid-labile group, that is, Ra27 does not include a group in which the tertiary carbon atom bonds to —O—.
Examples of the alkyl group that optionally has a hydroxy group of Ra25 and Ra26 include, for example, methyl, ethyl, propyl, hydroxymethyl and 2-hydroxyethyl groups.
The aliphatic hydrocarbon group of Ra27 has preferably a C1 to C8 alkyl group and a C4 to C18 alicyclic hydrocarbon group, and more preferably a C1 to C6 alkyl group and a C4 to C12 alicyclic hydrocarbon group, and still more preferably a methyl, ethyl, propyl, 2-oxo-oxalane-3-yl and 2-oxo-oxalane-4-yl groups.
Specific examples of the acid-stable monomer having the norbornene ring (a-4-3) include 2-norbornene, 2-hydroxy-5-norbornene, 5-norbornene-2-carboxylic acid, methyl 5-norbornene-2-carboxylate, 2-hydroxy-1-ethyl 5-norbornene-2-carboxylate, 5-norbornene-2-methanol and 5-norbornene-2,3-dicarboxylic acid anhydride.
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a4-1), the monomer represented by the formula (a4-2) and/or the monomer represented by the formula (a4-3), the total proportion thereof is generally 2 to 40 mol %, preferably 3 to 30 mol %, and more preferably 5 to 20 mol %, with respect to the total structural units (100%) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a4-1), the monomer represented by the formula (a4-2) and/or the monomer represented by the formula (a4-3), the total proportion thereof is preferably 5 to 20 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
Further, examples of the acid-stable monomer other than the above include a monomer having a sultone ring represented by the formula (a4-4).




wherein La7 represents an oxygen atom or *-T-(CH2)k2—CO—O—, k2 represents an integer of 1 to 7, T represents an oxygen atom or NH, * represents a single bond to carbonyl group;
Ra28 represents a hydrogen atom or a methyl group;
W10 represent a group having an optionally substituted sultone ring.
The sultone ring is a ring in which two of adjacent methylene groups are replaced by an oxygen atom and a sulfonyl group, respectively, and examples thereof include a ring below. The sultone ring group is a group in which one or more hydrogen atom contained in the sultone ring below is replaced by a bond, which correspond to a bond to La7 in the formula (a4-4)




The group having an optionally substituted sultone ring means a group in which one or more hydrogen atom other than a hydrogen atom which has been replaced by a bond contained in the sultone ring is replaced by a substituent (monovalent group other than a hydrogen atom), and examples thereof include a hydroxy group, cyano group, a C1 to C6 alkyl group, a C1 to C6 fluorinated alkyl group, a C1 to C6 hydroxy alkyl group, a C1 to C6 alkoxy group, a C1 to C7 alkoxycarbonyl group, a C1 to C7 acyl group and a C1 to C8 acyloxy group.
Specific examples of the acid-stable monomer (a-4-4) having a sultone ring include a monomer below.














































Further, examples of the structural units (a-4-4) include structural units in which a partial structure V of the structural units above is replaced by a partial structure P as described above.
When the resin (A) contains the structural unit derived from the acid-stable monomer (a-4-4), the proportion thereof is generally 2 to 40 mol %, preferably 3 to 35 mol %, and more preferably 5 to 30 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the acid-stable monomer (a-4-4), the proportion thereof is generally 0 to 90 mol %, preferably 0 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
An acid-stable monomer (a-4-5) containing a fluorine atom as follows is used for manufacturing the resin.













Among these, 5-(3,3,3-trifluoro-2-hydroxy-2-[trifluoromethyl]propyl) bicyclo[2.2.1]hept-2-yl (meth)acrylate, 6-(3,3,3-trifluoro-2-hydroxy-2-[trifluoromethyl]propyl) bicyclo[2.2.1]hept-2-yl (meth)acrylate, 4,4-bis(trifluoromethyl)-3-oxatricyclo[4.2.1.02,5]nonyl (meth)acrylate which have mono- or poly-alicyclic hydrocarbon group are preferable.
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a4-5), the proportion thereof is generally 1 to 20 mol %, preferably 2 to 15 mol %, and more preferably 3 to 10 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a4-5), the proportion thereof is preferably 5 to 40 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
The acid-stable monomer (a4) may have a group represented by the formula (3) below. The acid-stable monomer having a group represented by the formula (3) hereinafter may be referred to as “acid-stable monomer (a-4-6)”.




wherein R10 represents a C1 to C6 fluorinated alkyl group; * represents a bond.
Examples of the fluorinated alkyl group of R10 include difluoromethyl, trifluoromethyl, 1,1-difluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, perfluoroethyl, 1,1,2,2-tetrafluoropropyl, 1,1,2,2,3,3-hexafluoropropyl, perfluoroethylmethyl, 1 -(trifluoromethyl)-1,2,2,2-tetrafluoroethyl, perfluoropropyl, 1,1,2,2-tetrafluorobutyl, 1,1,2,2,3,3-hexafluorobutyl, 1,1,2,2,3,3,4,4-octafluorobutyl, perfluorobutyl, 1,1-bis(trifluoro)methyl-2,2,2-trifluoroethyl, 2-(perfluoropropyl)ethyl, 1,1,2,2,3,3,4,4-octafluoropentyl, perfluoropentyl, 1,1,2,2,3,3,4,4,5,5-decafluoropentyl, 1,1-bis(trifluoromethyl)-2,2,3,3,3-pentafluoropropyl, 2-(perfluorobutyl)ethyl, 1,1,2,2,3,3,4,4,5,5-decafluorohexyl, 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorohexyl, perfluoropentylmethyl and perfluorohexyl groups.
The fluorinated alkyl group of R10 preferably has 1 to 4 carbon atom, more preferably trifluoromethyl, perfluoroethyl and perfluoropropyl groups, and still more preferably trifluoromethyl group.
Specific examples of the acid stable monomer (a-4-6) include monomers below.







Further, examples of the structural units (a-4-6) include structural units in which a partial structure V of the structural units above is replaced by a partial structure P as described above.
Other specific examples of the acid stable monomer (a-4-6) include monomers below.




When the resin (A) contains the structural unit derived from the acid-stable monomer (a-4-6), the proportion thereof is generally 5 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) of the resin (A).
When the resin (X) contains the structural unit derived from the acid-stable monomer (a-4-6), the proportion thereof is generally 0 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) of the resin (X).
The acid-stable monomer (a4) may have a group represented by the formula (4).




wherein R11 represents an optionally substituted C6 to C12 aromatic hydrocarbon group;
R12 represents an optionally substituted C1 to C12 hydrocarbon group, and the hydrocarbon group may contain a hetero atom;
A3 represents a single bond, —(CH2)m10—SO2—O—* or —(CH2)m10—CO—O—*, one or more —CH2— contained in the [—(CH2)m10-] may be replaced by —O—, —CO— or —SO2—, one or more hydrogen atom contained in the [—(CH2)m10-] may be replaced by a fluorine atom;
m10 represents an integer 1 to 12.
Examples of the aromatic hydrocarbon group of R11 include the same examples described above.
One or more hydrogen atom contained in the aromatic hydrocarbon group may be replaced by a C1 to C4 alkyl group, a halogen atom, a phenyl group, a nitro group, a cyano group, a hydroxy group, a phenyloxy group or tert-butylphenyl group.
Specific examples of the preferable group for R11 include a group below. * represents a bond to carbon atom.







The hydrocarbon group of R12 may be any of a chain aliphatic hydrocarbon group, an alicyclic hydrocarbon group and an aromatic hydrocarbon group.
Typical examples of the aliphatic hydrocarbon group are an alkyl group, and examples of the alkyl group include the same groups of Ra34 and Ra35 in the formula (a1-4).
When R12 is an aliphatic hydrocarbon group or an alicyclic hydrocarbon group, these may contain a hetero atom. Examples of the hetero atom include a halogen atom, a sulfur atom, an oxygen atom and a nitrogen atom, and may include a configuration of linking group such as a sulfonyl group and a carbonyl group.
Specific examples of R12 containing such hetero atom include a group below.







When R12 is an aromatic hydrocarbon group, specific examples thereof include the same examples described above.
Specific examples of A3 include a group below.







An acid-stable monomer (a4) containing a group represented by the formula (4) include an acid-stable monomer represented by the formula (a4-7).




wherein R13 represents a hydrogen atom or a methyl group;
R11, R12 and A3 are the same meanings described above.
Specific examples of the acid-stable monomer (a-4-7) include a monomer below.







Further, examples of the structural units (a-4-7) include structural units in which a partial structure V of the structural units above is replaced by a partial structure P as described above.
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a4-7), the proportion thereof is generally 5 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a4-7), the proportion thereof is generally 0 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
The acid-stable monomer (a4) may also have a (meth)acrylic monomer having an alicyclic hydrocarbon group such as a monomer represented by the formula (a4-8).




wherein ring W2 represents a C3 to C36 alicyclic hydrocarbon ring;
A4 represents a single bond or an C1 to C17 divalent aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—, provided that an atom bonded to —O— is a carbon atom;
R14 represents a C1 to C6 alkyl group that optionally has a halogen atom, a hydrogen atom or a halogen atom;
R15 and R16 independently represent a C1 to C6 alkyl group that optionally has a halogen atom.
The alicyclic hydrocarbon group of ring W2 includes a monocyclic or polycyclic hydrocarbon group, preferably a C5 to C18 alicyclic hydrocarbon group, and more preferably a C6 to C12 alicyclic hydrocarbon group. Examples thereof include a ring represented by the formula (KA-1) to the formula (KA-22). That is, the group illustrated below




in the formula (a4-8) is a group in which one hydrogen atom bonded to an atom constituting any one of the ring represented by the formula (KA-1) to the formula (KA-22) is replaced by a bond to A4, and other two hydrogen atoms bonded to another atom constituting the ring are replaced respectively with a bond to —O—CO—R15 and a bond to —O—CO—R16.

Examples of the ring W2 preferably include a cyclohexane ring, an adamantane ring, a norbornene ring and a norbornane ring.
Examples of the divalent aliphatic hydrocarbon group of A4 include a divalent chain alkanediyl group, a divalent alicyclic hydrocarbon group described above and a combination thereof.
Examples of the combination of the alkanediyl group and the alicyclic hydrocarbon group include groups below.




wherein XX1 and XX2 independently represent a C1 to C6 alkanediyl group or a single bond, provided that both of XX1 and XX2 are not a single bond, and the total carbon number of the groups represented by the formula (XX-A), the formula (XX—B) and the formula (XX—C) is 17 or less, respectively.
The aliphatic hydrocarbon group of A4 may have a substituent.
Examples of A4 in which one or more —CH2— contained in the aliphatic hydrocarbon group is replaced by —O— or —CO— include, for example, the same example of the group (a-1) in the formula (aa).
A4 is preferably a single bond or a group represented by *—(CH2)s1—CO—O—, s1 represents an integer of 1 to 6, and more preferably a single bond or *—CH2—CO—O—, * represent a bond to —O—.
R14 is preferably a hydrogen atom or a methyl group.
The halogen atom of R14, R15 and R16 is preferably fluorine atom.
Examples of the alkyl group having a halogen atom include trifluoromethyl, perfluoroethyl, perfluoropropyl, perfluoro-isopropyl and perfluorobutyl groups. Among these, trifluoromethyl, perfluoroethyl and perfluoropropyl are preferable.
Examples of the acid-stable monomer (a-4-8) include acid-stable monomers below. R14 to R16 and A4 are the same meaning defined above.




Among these, acid-stable monomers (a-4-8) represented by the formula below are preferable.




Specific examples of the acid-stable monomer (a-4-8) include acid-stable monomer below.







Further, examples of the structural units (a-4-8) include structural units in which a partial structure V of the structural units above is replaced by a partial structure P as described below.
Preferable acid-stable monomer (a-4-8) can be produced by reacting a compound represented by the formula (a-4-8-a) and a compound represented by the formula (a4-8-b).
Typical compound represented by the formula (a4-8-a) is 1-methacryloyloxy-4-oxoadamantane described in JP2002-226436-A.
Examples of the compound represented by the formula (a4-8-b) include pentafluoropropionic anhydride, heptafluoro butyric anhydride and trifluoro butyric anhydride.
The reaction is preferably carried out at around a boiling point of the compound represented by the formula (a4-8-b) to be used.




wherein R14, R15, R16, A4 and W2 have the same meaning as defined above.
When the resin (A) contains the structural unit derived from the monomer represented by the formula (a4-8), the proportion thereof is generally 5 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (A).
When the resin (X) contains the structural unit derived from the monomer represented by the formula (a4-8), the proportion thereof is generally 0 to 90 mol %, preferably 10 to 80 mol %, and more preferably 20 to 70 mol %, with respect to the total structural units (100 mol %) constituting the resin (X).
<Production of the Resin>
The resin (X) may be a copolymer obtained by polymerizing the compound (aa′), the compound (ab′) and the acid-stable monomer as needed, in particular, a copolymer obtained by polymerizing the compound (aa′), the compound (ab′) and the acid-stable monomer (a4). The acid-stable monomer (a4) is preferably the acid-stable monomer (a-4-6) and/or the acid-stable monomer (a-4-7), and more preferably the acid-stable monomer (a-4-6).
When the resin (X) contains the structural unit (a1), the ratio of [the acid-labile structural unit (a1)]:[the acid-stable structural unit] is preferably 10 to 80 mol %:90 to 20 mol %, and more preferably 20 to 60 mol %:80 to 40 mol %. When the amount of the acid-stable structural unit is calculated, the structural unit (aa) and the structural unit (ab) are preferably included in the acid-stable structural unit.
The structural unit (aa) and the structural unit (ab) may be generally regarded as the acid-stable structural unit.
The resin (A) preferably is a (co)polymer having the acid-labile structural unit (a1) (in particular, at least one of the acid-labile structural unit (a1-1) and the acid-labile structural unit (a1-2), and preferably the acid-labile structural unit (a1-1)), more preferably a copolymer having the acid-labile structural unit (a1) and the acid-stable structural unit, and still more preferably a copolymer having the acid-labile structural unit (a1-1) and/or the acid-labile structural unit (a1-2) and the acid-stable structural unit. The acid-stable structural unit is preferably the structural unit (a2) (more preferably the structural unit having the hydroxyadamantyl group (a2-1)) and the structural unit (a3). The structural unit (a3) is preferably the structural unit having at least one of the γ-butyrolactone ring (a3-1), and the structural unit having the condensed ring of the γ-butyrolactone ring and the norbornene ring (a3-2).
When the resin (A) is produced with a monomer providing the acid-stable structural unit, the proportion of the acid-stable structural unit to be used can be adjusted based on the amount of the monomer providing the acid-labile structural unit (a1). For example, the ratio of [the acid-labile structural unit (a1)]:[the acid-stable structural unit] is preferably 10 to 80 mol %:90 to 20 mol %, and more preferably 20 to 60 mol %:80 to 40 mol %.
When the monomer having an adamantyl group is used as the monomer (a1), the proportion of the monomer having an adamantyl group (in particular, the monomer having the acid-labile group (a1-1)) is preferably 15 mol % or more with respect to the monomer having the acid-labile group (a1). As the mole ratio of the monomer having an adamantyl group increases within this range, the dry etching resistance of the resulting resist improves.
The combination of the resin (X) and the resin (A) is preferably used in the present resist composition, and the combination of the resin (X) not having the acid-labile group (a1) and the resin (A) is more preferable.
When the present resist composition contains the resin (X) and the resin (A), the weight ratio of the resin (X) and the resin (A) can be adjusted so as to produce a resist pattern by the present resist composition through the interaction of the resin and the acid generator (described below). When the resin (X) contains the acid-labile group (a1), the weight ratio of the resins (X):(A) is preferably, for example, 0.1 to 100:10, and more preferably 1 to 50:10. When the resin (X) does not contain the acid-labile group (a1), the weight ratio of the resins (X):(A) is preferably, for example, 0.01 to 2:10, and more preferably 0.1 to 1:10.
The resin (X) and the resin (A) can be produced by a known polymerization method, for example, radical polymerization method, using the monomers. The monomer may be used as a single compound or as a mixture of two or more compounds.
The weight average molecular weight of the resin (X) is preferably 5,000 or more (more preferably 8,000 or more and still more preferably 10,000 or more), and 80,000 or less (more preferably 60,000 or less and still more preferably 50,000 or less).
The weight average molecular weight of the resin (A) is preferably 2500 or more (more preferably 3000 or more, and still more preferably 3500 or more), and 50,000 or less (more preferably 30,000 or less, and still more preferably 10,000 or less).
The weight average molecular weight is a value determined by gel permeation chromatography using polystyrene as the standard product. The detailed condition of this analysis is described in Examples.
<Acid Generator (B)>
An acid generator (B) is classified into non-ionic-based or ionic-based acid generator. The present resist composition may be used either acid generators.
Examples of the non-ionic-based acid generator include organic halogenated compounds; sulfonate esters such as 2-nitrobenzyl ester, aromatic sulfonate, oxime sulfonate, N-sulfonyl oxyimide, sulfonyl oxyketone and diazo naphthoquinone 4-sulfonate; sulfones such as disulfone, ketosulfone and sulfone diazomethane.
Examples of the ionic acid generator includes onium salts containing onium cation (such as diazonium salts, phosphonium salts, sulfonium salts, iodonium salts).
Examples of anion of onium salts include sulfonate anion, sulfonylimide anion and sulfonylmethyde anion.
For the acid generator (B), compounds which generate an acid by radiation described in JP S63-26653-A, JP S55-164824-A, JP S62-69263-A, JP S63-146038-A, JP S63-163452-A, JP S62-153853-A, JP S63-146029-A, U.S. Pat. No. 3,779,778-B, U.S. Pat. No. 3,849,137-B, DE3,914,407-B and EP-126,712-A can be used.
The acid generator (B) is preferably a fluorine-containing acid generator represented by the formula (B1) as described below. In the acid generator (B1), electropositive Z+ hereinafter may be referred to as “an organic cation”, and electronegative one in which the organic cation has been removed from the compound may be referred to as “sulfonate anion”.




wherein Q1 and Q2 independently represent a fluorine atom or a C1 to C6 perfluoroalkyl group;
Lb1 represents an optionally substituted C1 to C17 divalent aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—;
Y represents an optionally substituted C1 to C17 aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O—, —CO— or —SO2—; and
Z+ represents an organic cation.
Examples of the perfluoroalkyl group of Q1 and Q2 include trifluoromethyl, perfluoroethyl, perfluoropropyl, perfluoro-isopropyl, perfluorobutyl, perfluoro-sec-butyl, perfluoro-tert-butyl, perfluoropentyl and perfluorohexyl groups.
Among these, Q1 and Q2 are independently preferably trifluoromethyl or fluorine atom, and more preferably both a fluorine atom.
Examples of the a divalent aliphatic hydrocarbon group of Lb1 include;
a linear chain alkanediyl group such as methylene, ethylene, propane-1,3-diyl, propane-1,2-diyl, butane-1,4-diyl, pentane-1,5-diyl, hexane-1,6-diyl, heptane-1,7-diyl, octane-1,8-diyl, nonane-1,9-diyl, decane-1,10-diyl, undecane-1,11-diyl, dodecane-1,12-diyl, tridecane-1,13-diyl, tetradecane-1,14-diyl, pentadecane-1,15-diyl, hexadecane-1,16-diyl, heptadecane-1,17-diyl groups, methylidene, ethylidene, propylidene and 2-propyliden groups;
a branched chain alkanediyl group such as a group in which a linear chain alkanediyl group is bonded a side chain of a C1 to C4 alkyl group such as methyl, ethyl, propyl, isopropyl, butyl, sec-butyl and tert-butyl, for example, butan-1,3-diyl, 2-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, pentane-1,4-diyl, 2-methylbutane-1,4-diyl groups;
a mono-alicyclic hydrocarbon group such as cyclobutan-1,3-diyl, cyclopentan-1,3-diyl, cyclohexane-1,2-diyl, 1-methylhexane-1,2-diyl, cyclohexane-1,4-diyl, cyclooctan-1,2-diyl, cyclooctan-1,5-diyl groups;
a poly-alicyclic hydrocarbon group such as norbornane-1,4-diyl, norbornane-2,5-diyl, adamantane-1,5-diyl and adamantane-2,6-diyl groups; and
a combination of two or more groups.
Examples of the aliphatic hydrocarbon group of Lb1 in which one or more —CH2— contained in the aliphatic hydrocarbon group is replaced by —O— or —CO—include groups represented by the formula (b1-1) to the formula (b1-6) below.
In the formula (b1-1) to the formula (b1-6), the group is represented so as to correspond with two sides of the formula (B1), that is, the left side of the group bonds to C(Q1)(Q2)- and the right side of the group bonds to —Y (examples of the formula (b1-1) to the formula (b1-6) are the same as above). * represents a bond.




wherein Lb2 represents a single bond or a C1 to C15 divalent aliphatic hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group;
Lb3 represents a single bond or a C1 to C12 divalent aliphatic hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group;
Lb4 represents a C1 to C13 divalent aliphatic hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group, the total number of the carbon atoms in Lb3 and Lb4 is at most 13;
Lb5 represents a C1 to C15 divalent saturated hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group;
Lb6 and Lb7 independently represent a C1 to C15 divalent aliphatic hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group, the total number of the carbon atoms in Lb6 and Lb7 is at most 16;
Lb8 represents a C1 to C14 divalent aliphatic hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group;
Lb9 and Lb10 independently represent a C1 to C11 divalent aliphatic hydrocarbon group, the aliphatic hydrocarbon group is preferably a saturated aliphatic hydrocarbon group, the total number of the carbon atoms in Lb9 and Lb10 is at most 12.
Among these, the groups represented by the formula (b1-1) to the formula (b1-4) are preferable, the group represented by the formula (b1-1) to the formula (b1-3) is still more preferable, and the group represented by the formula (b1-1) or the formula (b1-2) is further more preferable. In particular, the divalent group represented by the formula (b1-1) is more preferable, and the divalent group represented by the formula (b1-1) in which Lb2 represents a single bond or —CH2— is more preferable.
Specific examples of the divalent group represented by the formula (b1-1) include groups below. In the formula below, * represent a bond.




Specific examples of the divalent group represented by the formula (b1-2) include groups below.




Specific examples of the divalent group represented by the formula (b1-3) include groups below.




Specific examples of the divalent group represented by the formula (b1-4) include a group below.




Specific examples of the divalent group represented by the formula (b1-5) include groups below.




Specific examples of the divalent group represented by the formula (b1-6) include groups below.




Examples of the substituent of the aliphatic hydrocarbon group of La1 include a halogen atom, a hydroxy group, a carboxy group, a C6 to C18 aromatic hydrocarbon group, a C7 to C21 aralkyl group, a C2 to C4 acyl group and a glycidyloxy group.
The aliphatic hydrocarbon group of Y is preferably an alkyl group and alicyclic hydrocarbon group or a combination group thereof, more preferably a C1 to C6 alkyl group and a C3 to C12 alicyclic hydrocarbon group, and still more preferably a C3 to C12 alicyclic hydrocarbon group.
Examples of the alkyl group include methyl, ethyl, 1-methylethyl, 1,1-dimethylethyl, 2,2-dimethylethyl, propyl, 1-methylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, butyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1-propylbutyl, pentyl, 1-methylpentyl, hexyl, 1,4-dimethylhexyl, heptyl, 1-methylheptyl, octyl, methyloctyl, methylnonyl, 2-ethylhexyl, nonyl, decyl, undecyl and dodecyl groups. The aliphatic hydrocarbon group may be any of a liner and a branched chain alkyl groups.
Examples of the alicyclic hydrocarbon group include groups represented by the formula (Y-1) to the formula (Y-11) below.
Examples of Y in which one or more —CH2— contained in the aliphatic hydrocarbon group is replaced by —O—, —CO— or SO2— include, for example,
an alkyl group in which one or more —CH2— is replaced by one or more —O— or —CO—,
a cyclic ether group (a group replaced one or two —CH2— by one or two —O—),
a cyclic ketone group (a group replaced one or two —CH2— by one or two —CO—),
a sultone ring group (a group replaced adjacent two —CH2— by —O— and —SO2—, respectively), or
a lactone ring group (a group replaced adjacent two —CH2— by —O— and —CO—, respectively).
Specific examples thereof include groups represented by the formula (Y-12) to the formula (Y-26) below.










The aliphatic hydrocarbon group of Y is preferably groups represented by the formula (Y11), the formula (Y14), the formula (Y15), the formula (Y16) and the formula (Y19), more preferably a group represented by the formula (Y11), the formula (Y14), the formula (Y15) and the formula (Y19), and still more preferably a group represented by the formula (Y11) and the formula (Y14).
Examples of the substituent of Y include a halogen atom (other than a fluorine atom), a hydroxy group, a C1 to C12 alkoxy group, a C6 to C18 aromatic hydrocarbon group, a C7 to C21 aralkyl group, a C2 to C4 acyl group, a glycidyloxy group or a —(CH2)j2—O—CO—Rb1 group, wherein Rb1 represents a C1 to C16 hydrocarbon group, j2 represents an integer of 0 to 4. The aromatic hydrocarbon group and the aralkyl group may further have a substituent such as a C1 to C6 alkyl group, a halogen atom or a hydroxy group.
Examples of the halogen atom include chlorine, bromine and iodine atoms.
Examples of the alkoxyl group include methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, sec-butoxy, tert-butoxy, n-pentyloxy and n-hexyloxy groups.
Examples of the aromatic hydrocarbon group include phenyl, naphthyl, p-methylphenyl, p-tert-butylphenyl, p-adamantylphenyl, tolyl, xylyl, cumenyl, mesityl, biphenyl, anthryl, phenanthryl, 2,6-diethylphenyl and 2-methyl-6-ethylphenyl groups.
Examples of the aralkyl group include benzyl, phenethyl, phenylpropyl, trityl, naphthylmethyl and naphthylethyl groups.
Examples of the acyl group include acetyl, propionyl and butyryl groups.
Examples of Y include the groups below.




Y is preferably an optionally substituted C3 to C18 alicyclic hydrocarbon group, more preferably an adamantyl group which is optionally substituted, and more preferably an adamantyl group, an oxoadamantyl group and a hydroxyadamantyl group.
The sulfonate anion is preferably an anion represented by the formula (b1-1-1) to the formula (b1-1-9) below in which Lb1 is a group represented by the formula (b1-1).
In the formula (b1-1-1) to the formula (b1-1-9), Q1, Q2 and Lb2 represent the same meaning as defined above (preferably both fluorine atom for Q1 and Q2). Rb2 and Rb3 independently represent a group which is the same group described in the substituent of Y, is preferably a C1 to C4 aliphatic hydrocarbon group or a hydroxy group, and more preferably methyl group or a hydroxy group.




Examples of the sulfonate anion include sulfonate anions described in JP2010-204646A.
The sulfonate anion is more preferably an anion in which Lb1 is a group represented by the formula (b1-1) and Y is an alicyclic hydrocarbon group represented by the formula (Y-1) or the formula (Y-2).
Examples of the sulfonate anion in which Y is a non-substituted alicyclic hydrocarbon group include anions represented by the formula (b1-s-0) to the formula (b1-s-9).




Examples of the sulfonate anion in which Y is an alicyclic hydrocarbon group having a hydroxy group include anions represented by the formula (b1-s-10) to the formula (b1-s-18).




Examples of the sulfonate anion in which Y is a cyclic ketone group include anions represented by the formula (b1-s-19) to the formula (b1-s-29).




Examples of the sulfonate anion in which Y is an aromatic hydrocarbon group include anions represented by the formula (b1-s-30) to the formula (b1-s-35).




Examples of the sulfonate anion in which Y is a lactone ring or sulfonate ring group include anions represented by the formula (b1-s-36) to the formula (b1-s-41).




Examples of the cation of the acid generator (B) include an organic onium cation, for example, an organic sulfonium cation, an organic iodonium cation, an organic ammonium cation, an organic benzothiazolium cation and an organic phosphonium cation. Among these, an organic sulfonium cation and an organic iodonium cation are preferable, and organic sulfonium cations represented by any of the formula (b2-1), the formula (b2-3) and the formula (b2-4) are more preferable. The organic iodonium cation is represented by the formula (b2-2).
Z+ of the formula (B1) is preferably represented by any of the formula (b2-1) to the formula (b2-4).




wherein Rb4, Rb5 and Rb6 independently represent a C1 to C30 hydrocarbon group which preferably includes a C1 to C30 alkyl group, a C3 to C18 alicyclic hydrocarbon group or a C6 to C18 aromatic hydrocarbon group, the alkyl group may be substituted with a hydroxy group, a C1 to C12 alkoxy group or a C6 to C18 aromatic hydrocarbon group, the alicyclic hydrocarbon group may be substituted with a halogen atom, a C2 to C4 acyl group and a glycidyloxy group, the aromatic hydrocarbon group may be substituted with a halogen atom, a hydroxy group, a C1 to C18 alkyl group, a C3 to C18 alicyclic hydrocarbon group or a C1 to C12 alkoxy group;
Rb7 and Rb8 in each occurrence independently represent a hydroxy group, a C1 to C12 alkyl group or a C1 to C12 alkoxyl group;
m2 and n2 independently represent an integer of 0 to 5;
Rb9 and Rb10 independently represent a C1 to C18 alkyl group or a C3 to C18 alicyclic hydrocarbon group, or Rb9 and Rb10 may be bonded together with a sulfur atom bonded thereto to form a sulfur-containing 3- to 12-membered (preferably 3- to 7-membered) ring, and one or more —CH2— contained in the ring may be replaced by —O—, —S— or —CO—;
Rb11 represents a hydrogen atom, a C1 to C18 alkyl group, a C3 to C18 alicyclic hydrocarbon group or a C6 to C18 aromatic hydrocarbon group;
Rb12 represents a C1 to C18 hydrocarbon group which preferably includes a C1 to C18 alkyl group, a C3 to C18 alicyclic hydrocarbon group and a C6 to C18 aromatic hydrocarbon group, the aromatic hydrocarbon group may be substituted with a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C18 alicyclic hydrocarbon group or a C1 to C12 alkyl carbonyloxy group;
Rb11 and Rb12 may be bonded together with —CH—CO— bonded thereto to form a 3- to 12-membered (preferably a 3- to 7-membered) ring, and one or more —CH2— contained in the ring may be replaced by —O—, —S— or —CO—;
Rb13, Rb14, Rb15, Rb16, Rb17 and Rb18 in each occurrence independently represent a hydroxy group, a C1 to C12 alkyl group or a C1 to C12 alkoxy group;
Lb11 represents —S— or —O—;
o2, p2, s2 and t2 independently represent an integer of 0 to 5;
q2 or r2 independently represent an integer of 0 to 4;
u2 represents an integer of 0 or 1.
Examples of the alkyl group include methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, pentyl, hexyl, octyl and 2-ethylhexyl groups.
Examples of the alicyclic hydrocarbon group include a monocyclic hydrocarbon groups such as cyclopentyl, cyclohexyl, methylcyclohexyl, dimethylcyclohexyl, cycloheptyl, cyclooctyl groups; and polycyclic hydrocarbon groups such as decahydronaphtyl, adamantyl, norbornyl (i.e., bicyclo[2.2.1]hexyl) and methyl norbornyl groups as well as groups as below.




Examples of the aromatic hydrocarbon group include phenyl, naphthyl, p-methylphenyl, p-tert-butylphenyl, p-adamantylphenyl, tolyl, xylyl, cumenyl, mesityl, biphenyl, anthryl, phenanthryl, 2,6-diethylphenyl and 2-methyl-6-ethylphenyl groups.
Examples of the alkoxyl group include methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, decyloxy and dodecyloxy groups.
Examples of the halogen atom include fluorine, chlorine, bromine and iodine atoms.
Examples of the acyl group include acetyl, propionyl and butyryl groups.
Examples of the alkylcarbonyloxy group of the Rb12 include methylcarbonyloxy, ethylcarbonyloxy, n-propylcarbonyloxy, isopropylcarbonyloxy, n-butylcarbonyloxy, sec-butylcarbonyloxy, tert-butylcarbonyloxy, pentylcarbonyloxy, hexylcarbonyloxy, octylcarbonyloxy, and 2-ethylhexylcarbonyloxy groups.
Preferred examples of the alkyl group include methyl, ethyl, propyl, butyl, hexyl, octyl, and 2-ethylhexyl groups, in particular, the alkyl group of Rb9 to Rb11 is preferably a C1 to C12 alkyl group.
Preferred examples of the alicyclic hydrocarbon group include a cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclodecyl, 2-alkyladamantane-2-yl, 1-(adamantane-1-yl)alkane-1-yl and isobornyl groups, in particular, the alicyclic hydrocarbon group of Rb9 to Rb11 is preferably a C3 to C18 alicyclic hydrocarbon group, and more preferably a C4 to C12 alicyclic hydrocarbon group.
Preferred examples of the aromatic hydrocarbon groups include phenyl, 4-methylphenyl, 4-ethylphenyl, 4-tert-butylphenyl, 4-cyclohexylphenyl, 4-methoxyphenyl, biphenyl and naphthyl groups.
Examples of the aromatic group substituted with an alkyl group typically represent an aralkyl group such as benzyl, phenethyl, phenylpropyl, trityl, naphthylmethyl and naphthylethyl groups.
Examples of the ring having —CH—CO— and formed by Rb9 and Rb10 bonded together include thiolane-1-ium ring (tetrahydrothiophenium ring), thian-1-ium ring and 1,4-oxathian-4-ium ring.
Examples of the ring having a sulfur atom and formed by Rb11 and Rb12 bonded together include oxocycloheptane ring, oxocyclohexane ring, oxonorbornane ring and oxoadamantane ring.
Specific examples of the organic cations represented by the formula (b2-1) to the formula (b2-4) include, for example, compounds described in JP2010-204646-A.
Among the cations represented by the formula (b2-1) to the formula (b2-4), the cation represented by the formula (b2-1) is preferable, and triphenyl sulfonium cation (v2=w2=x2=0 in the formula (b2-1-1)), diphenyl tolyl sulfonium cation (v2=w2=x2=0, x2=1, Rb21 is methyl group in the formula (b2-1-1)) and tritolyl sulfonium cation (v2=w2=x2=1, and Rb19, Rb20 and Rb21 are a methyl group in the formula (b2-1-1)) are more preferable.




wherein Rb19, Rb20 and Rb21 in each occurrence independently represent a halogen atom, a hydroxy group, a C1 to C18 aliphatic hydrocarbon group or a C1 to C12 alkoxy group;
v2 to x2 independently represent an integer of 0 to 5.
The aliphatic hydrocarbon group is preferably a C1 to C12 aliphatic hydrocarbon group, and more preferably a C1 to C12 alkyl group or a C4 to C15 alicyclic hydrocarbon group.
In the formula (b2-1-1), Rb19 to Rb21 independently preferably represent a halogen atom (and more preferably fluorine atom), a hydroxy group, a C1 to C12 alkyl group or a C1 to C12 alkoxy group; and
v2 to x2 independently represent preferably 0 or 1.
Specific examples of the cation of the formula (b2-1-1) include a cation below.
















Specific examples of the cation of the formula (b2-3) include a cation below.




The acid generator (B1) is a compound in combination of the above sulfonate anion and an organic cation.
The above sulfonate anion and the organic cation may optionally be combined, for example, as described in the Table 3 below. The sulfonate anion represented by the formula (b1-s-2) is expressed “(b1-s-2)”, and the organic cation represented by the formula (b1-c-1) is expressed “(b2-c-1)” in the table, for example.











TABLE 3







Acid generator (B1)
Sulfonate Anion
Organic Cation









(B1-1P)
(b1-s-2)
(b2-c-1)



(B1-2P)
(b1-s-2)
(b2-c-21)



(B1-3P)
(b1-s-11)
(b2-c-1)



(B1-4P)
(b1-s-11)
(b2-c-2)



(B1-5P)
(b1-s-11)
(b2-c-6)



(B1-6P)
(b1-s-11)
(b2-c-10)



(B1-7P)
(b1-s-11)
(b2-c-12)



(B1-8P)
(b1-s-11)
(b2-c-15)



(B1-9P)
(b1-s-11)
(b2-c-21)



(B1-10P)
(b1-s-11)
(b2-c-23)



(B1-11P)
(b1-s-14)
(b2-c-1)



(B1-12P)
(b1-s-14)
(b2-c-2)



(B1-13P)
(b1-s-14)
(b2-c-6)



(B1-14P)
(b1-s-14)
(b2-c-10)



(B1-15P)
(b1-s-14)
(b2-c-12)



(B1-16P)
(b1-s-14)
(b2-c-15)



(B1-17P)
(b1-s-14)
(b2-c-21)



(B1-18P)
(b1-s-14)
(b2-c-23)



(B1-19P)
(b1-s-20)
(b2-c-1)



(B1-20P)
(b1-s-20)
(b2-c-2)



(B1-21P)
(b1-s-20)
(b2-c-6)



(B1-22P)
(b1-s-20)
(b2-c-10)



(B1-23P)
(b1-s-20)
(b2-c-12)



(B1-24P)
(b1-s-20)
(b2-c-15)



(B1-25P)
(b1-s-20)
(b2-c-21)



(B1-26P)
(b1-s-20)
(b2-c-23)



(B1-27P)
(b1-s-4)
(b2-c-1)



(B1-28P)
(b1-s-35)
(b2-c-1)



(B1-29P)
(b1-s-36)
(b2-c-1)



(B1-30P)
(b1-s-39)
(b2-c-1)



(B1-31P)
(b1-s-40)
(b2-c-1)



(B1-32P)
(b1-s-41)
(b2-c-1)



(B1-33P)
(b1-s-42)
(b2-c-1)










Preferred acid generators (B1) are a salt represented by the formula (B1-1) to the formula (B1-17) below. Among these, the formulae (B1-2), (B1-3), (B1-6), (B1-7), (B1-11), (B1-12), (B1-13) and (B1-14) which contain triphenyl sulfonium cation or tritolyl sulfonium cation are preferable, and the formulae (B1-2), (B1-3), (B1-6), (B1-7), (B1-11) in which Y is an optionally substituted alicyclic hydrocarbon group are more preferable.













The acid generator (B) may include an acid generator other than the acid generator (B1) as described above, in this case, the proportion of the acid generator (B1) is preferably 70 weight % or more, more preferably 90 weight % or more, and still more preferably substantially 100 weight %, with respect to total weight (100 weight %) of acid generator (B).
<Basic Compound (C)”>
The resist composition of the present invention may contain a basic compound (C). The basic compound (C) is a compound having a property to quench an acid, in particular, generated from the acid generator (B), and called “quencher”.
As the basic compounds (C), nitrogen-containing basic compounds (for example, amine and basic ammonium salt) are preferable. The amine may be an aliphatic amine or an aromatic amine. The aliphatic amine includes any of a primary amine, secondary amine and tertiary amine. The aromatic amine includes an amine in which an amino group is bonded to an aromatic ring such as aniline, and a hetero-aromatic amine such as pyridine.
Preferred basic compounds (C) include compounds presented by the formula (C1) to the formula (C8) as described below. Among these, the basic compound presented by the formula (C1) is more preferable.




wherein Rc1, Rc2 and Rc3 independently represent a hydrogen atom, a C1 to C6 alkyl group, C5 to C10 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group, one or more hydrogen atom contained in the alkyl group and alicyclic hydrocarbon group may be replaced by a hydroxy group, an amino group or a C1 to C10 alkoxyl group, one or more hydrogen atom contained in the aromatic hydrocarbon group may be replaced by a C1 to C6 alkyl group, a C1 to C6 alkoxyl group, a C5 to C10 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group.




wherein Rc2 and Rc3 have the same definition of the above;
Rc4 in each occurrence represents a C1 to C6 alkyl group, a C1 to C6 alkoxyl group, a C5 to C10 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
m3 represents an integer 0 to 3.




wherein Rc5, Rc6, Rc7 and Rc8 independently represent the any of the group as described in Rc1 of the above;
Rc9 in each occurrence independently represents a C1 to C6 alkyl group, a C3 to C6 alicyclic hydrocarbon group or a C2 to C6 alkanoyl group;
n3 represents an integer of 0 to 8.




wherein Rc10, Rc11, Rc12, Rc13 and Rc16 independently represent the any of the groups as described in Rc1;
Rc14, Rc15 and Rc17 in each occurrence independently represent the any of the groups as described in Rc4;
o3 and p3 represent an integer of 0 to 3;
Lc1 represents a divalent C1 to C6 alkanediyl group, —CO—, —C(═NH)—, —S— or a combination thereof;




wherein Rc18, Rc19 and Rc20 in each occurrence independently represent the any of the groups as described in Rc4;
q3, r3 and s3 represent an integer of 0 to 3;
Lc2 represents a single bond, a divalent C1 to C6 alkanediyl group, —CO—, —C(═NH)—, —S— or a combination thereof.
Examples of the alkanoyl group include acetyl group, 2-methylacetyl group, 2,2-dimethylacetyl group, propionyl group, butyryl group, isobutyryl group, pentanoyl group, and 2,2-dimethylpropionyl group.
Specific examples of the amine represented by the formula (C1) include 1-naphthylamine and 2-naphthylamine, aniline, diisopropylaniline, 2-, 3- or 4-methylaniline, 4-nitroaniline, N-methylaniline, N,N-dimethylaniline, diphenylamine, hexylamine, heptylamine, octylamine, nonylamine, decylamine, dibutylamine, dipentylamine, dihexylamine, diheptylamine, dioctylamine, dinonylamine, didecylamine, triethylamine, trimethylamine, tripropylamine, tributylamine, tripentylamine, trihexylamine, triheptylamine, trioctylamine, trinonylamine, tridecylamine, methyldibutylamine, methyldipentylamine, methyldihexylamine, methyldicyclohexylamine, methyldiheptylamine, methyldioctylamine, methyldinonylamine, methyldidecylamine, ethyldibutylamine, ethyldipentylamine, ethyldihexylamine, ethyldiheptylamine, ethyldioctylamine, ethyldinonylamine, ethyldidecylamine, dicyclohexylmethylamine, tris[2-(2-methoxyethoxy)ethyl]amine, triisopropanolamine, ethylene diamine, tetramethylene diamine, hexamethylene diamine, 4,4′-diamino-1,2-diphenylethane, 4,4′-diamino-3,3′-dimethyldiphenylmethane and 4,4′-diamino-3,3′-diethyldiphenylmethane.
Among these, diisopropylaniline is preferable, particularly 2,6-diisopropylaniline is more preferable as the basic compounds (C) contained in the present resist compound.
Specific examples of the compound represented by the formula (C2) include, for example, piperazine.
Specific examples of the compound represented by the formula (C3) include, for example, morpholine.
Specific examples of the compound represented by the formula (C4) include, for example, piperidine, a hindered amine compound having piperidine skeleton described in JP H11-52575-A.
Specific examples of the compound represented by the formula (C5) include, for example, 2,2′-methylenebisaniline.
Specific examples of the compound represented by the formula (C6) include, for example, imidazole and 4-methylimidazole.
Specific examples of the compound represented by the formula (C7) include, for example, pyrizine and 4-methylpyrizine.
Specific examples of the compound represented by the formula (C(8) include, for example, 1,2-di(2-pyridyl)ethane, 1,2-di(4-pyridyl)ethane, 1,2-di(2-pyridyl)ethene, 1,2-di(4-pyridyl)ethene, 1,3-di(4-pyridyl)propane, 1,2-di(4-pyridyloxy)ethane, di(2-pyridyl)ketone, 4,4′-dipyridyl sulfide, 4,4′-dipyridyl disulfide, 2,2′-dipyridylamine, 2,2′-dipicolylamine and bipyridine.
Examples of the ammonium salt include tetramethylammonium hydroxide, tetraisopropylammonium hydroxide, tetrabutylammonium hydroxide, tetrahexylammonium hydroxide, tetraoctylammonium hydroxide, phenyltrimethyl ammonium hydroxide, 3-(trifluoromethyl)phenyltrimethylammonium hydroxide, tetra-n-butyl ammonium salicylate and choline.
<Solvent (Hereinafter May be Referred to “Solvent (D)”>
The resist composition of the present invention preferably includes a solvent (D). The solvent (D) can be preferably selected depending on the kinds and an amount of the resin (X) having the structural unit derived from the compound (aa) and the structural unit derived from the compound (ab), and a kind and an amount of the acid generator from a viewpoint of good coating properties.
Examples of the solvent (D) include glycol ether esters such as ethylcellosolve acetate, methylcellosolve acetate and propylene glycol monomethyl ether acetate; ethers such as diethylene glycol dimethyl ether; esters such as ethyl lactate, butyl acetate, amyl acetate and ethyl pyruvate; ketones such as acetone, methyl isobutyl ketone, 2-heptanone and cyclohexanone; and cyclic esters such as γ-butyrolactone. These solvents may be used as a single solvent or as a mixture of two or more solvents.
<Other Ingredient (Hereinafter May be Referred to “Other Ingredient (F)”>
The resist composition can also include various additives as needed. Examples of the other ingredient (F) include sensitizers, dissolution inhibitors, surfactants, stabilizers and dyes.
<Preparing the Resist Composition>
The present resist composition can be prepared by mixing the resin (in particular a combination of the resin (A) and the resin (X)) and the acid generator (B), or by mixing the resin (in particular a combination of the resin (A) and the resin (X)), the acid generator (B1), and the basic compound (C), the solvent (D) and the other ingredient (F) as needed. There is no particular limitation on the order of mixing. The mixing may be performed in an arbitrary order. The temperature of mixing may be adjusted to an appropriate temperature within the range of 10 to 40° C., depending on the kinds of the resin and solubility in the solvent (D) of the resin. The time of mixing may be adjusted to an appropriate time within the range of 0.5 to 24 hours, depending on the mixing temperature. There is no particular limitation to the tool for mixing. An agitation mixing may be adopted.
After mixing the above ingredients, the present resist compositions can be prepared by filtering the mixture through a filter having about 0.01 to 0.2 μm pore diameter.
The proportion of the resin (i.e., total amount of the resin (A) and the resin (X)) can be adjusted with respect to the total solid proportion of the resist composition. Foe example, the resist composition of the present invention preferably contains 80 weight % or more and 99 weight % or less, with respect to the total solid proportion of the resist composition.
In the specification, the term “solid proportion of the resist composition” means the entire proportion of all ingredients other than the solvent (D). For example, if the proportion of the solvent (D) is 90 weight % of the resin, the solid proportion of the resist composition is 10 weight %.
In the resist composition of the present invention, the proportion of the acid generator (B) is preferably 1 part by weight or more (and more preferably 3 parts by weight or more), and also preferably 30 parts by weight or less (and more preferably 25 parts by weight or less), with respect to 100 parts by weight of the resin.
When the resist composition includes the basic compound (C), the proportion thereof is preferably 0.01 to 1 weight % with respect to the total solid proportion of the resist composition.
The proportion of the solvent (D) may be adjusted depending on the kinds of the resin (X), and it may be 90 weight % or more, preferably 92 weight % or more, and more preferably 94 weight % or more, and also preferably 99 weight % or less and more preferably 99.9 weight % or less. If the resist composition contains the solvent within such range, such resist composition is preferable for forming the thin resist film which can be used for producing a composition layer of 30 to 300 nm thick.
The proportion of the resin (X), the acid generator (B), the basic compound (C), and solvent (D) can be adjusted depending on each ingredient used during the preparation of the present resist composition, and can be measured with a known analytical method such as, for example, liquid chromatography and gas chromatography, after preparing the present resist composition.
If the other ingredient (F) is used in the present resist composition, the proportion thereof can also be adjusted depending on the kinds thereof.
<Method for Forming Resist Pattern>
The method for forming resist pattern of the present invention includes the steps of:
(1) applying the resist composition of the present invention onto a substrate;
(2) drying the applied composition to form a composition layer;
(3) exposing the composition layer;
(4) heating the exposed composition layer, and
(5) developing the heated composition layer.
Applying the resist composition onto the substrate can generally be carried out through the use of a resist application device, such as a spin coater known in the field of semiconductor microfabrication technique. The thickness of the applied resist composition layer can be adjusted by controlling the variable conditions of the resist application device. These conditions can be selected based on a pre-experiment carried out beforehand. The substrate can be selected from various substrates intended to be microfabricated. The substrate may be washed, and an organic antireflection film may be formed on the substrate by use of a commercially available antireflection composition, before the application of the resist composition.
Drying the applied composition layer, for example, can be carried out using a heating device such as a hotplate (so-called “prebake”), a decompression device, or a combination thereof. Thus, the solvent evaporates from the resist composition and a composition layer with the solvent removed is formed. The condition of the heating device or the decompression device can be adjusted depending on the kinds of the solvent used. The temperature in this case is generally within the range of 50 to 200° C. Moreover, the pressure is generally within the range of 1 to 1.0×105 Pa.
The composition layer thus obtained is generally exposed using an exposure apparatus or a liquid immersion exposure apparatus. The exposure is generally carried out through a mask that corresponds to the desired pattern. Various types of exposure light source can be used, such as irradiation with ultraviolet lasers such as KrF excimer laser (wavelength: 248 nm), ArF excimer laser (wavelength: 193 nm), F2 excimer laser (wavelength: 157 nm), or irradiation with far-ultraviolet wavelength-converted laser light from a solid-state laser source (YAG or semiconductor laser or the like), or vacuum ultraviolet harmonic laser light or the like. Also, the exposure device may be one which irradiates electron beam or extreme-ultraviolet light (EUV).
The composition layer may be formed with an exposed portion and an unexposed portion by the above exposure carried out through the mask. In the exposed portion, acid is produced from the acid generator contained in the resist composition upon receiving the energy of the exposure. Thus, the acid-labile group contained in the resin (X) reacts with the acid to eliminate the protecting group and generate the hydrophilic group. As the result, the resin in the exposed portion of the composition layer becomes soluble in an alkali aqueous solution. On the other hand, in the unexposed portion, the resin (X) remains insoluble or poorly soluble in an alkali aqueous solution because of the lack of exposure. In this way, the solubility in the alkali solution will be different between the composition layer in the exposed portion and the composition layer in the unexposed portion.
After exposure, the composition layer is subjected to a heat treatment (so-called “post-exposure bake”) to promote the deprotection reaction. The heat treatment can be carried out using a heating device such as a hotplate. The heating temperature is generally in the range of 50 to 200° C., preferably in the range of 70 to 150° C.
The composition layer is developed after the heat treatment, generally with an alkaline developing solution and using a developing apparatus. The development here means to bring the composition layer after the heat treatment into contact with an alkaline solution. Thus, the exposed portion of the composition layer is dissolved by the alkaline solution and removed, and the unexposed portion of the composition layer remains on the substrate, whereby producing a resist pattern. Here, as the alkaline developing solution, various types of aqueous alkaline solutions used in this field can be used. Examples include aqueous solutions of tetramethylammonium hydroxide and (2-hydroxyethyl)trimethylammonium hydroxide (common name: choline).
After the development, it is preferable to rinse the substrate and the pattern with ultrapure water and to remove any residual water thereon.
<Application>
The resist composition of the present invention is useful as the resist composition for excimer laser lithography such as with ArF, KrF or the like, and the resist composition for electron beam (EB) exposure lithography and extreme-ultraviolet (EUV) exposure lithography, as well as liquid immersion exposure lithography.
The resist composition of the present invention can be used in semiconductor microfabrication and in manufacture of liquid crystals, thermal print heads for circuit boards and the like, and furthermore in other photofabrication processes, which can be suitably used in a wide range of applications.
EXAMPLES
The present invention will be described more specifically by way of examples, which are not construed to limit the scope of the present invention.
All percentages and parts expressing the proportion or amounts used in the Examples and Comparative Examples are based on weight, unless otherwise specified.
The composition ratio of the resin (the copolymerization ratio of the structural unit derived from each monomer used in the preparation with respect to the resin) was calculated by measuring the amount of the unreacted monomer in the reacted solution after the completion of the reaction through liquid chromatography, and calculating the amount of the monomer use in the polymerization from the obtained results.
The weight average molecular weight is a value determined by gel permeation chromatography using polystyrene as the standard product.
Column: TSKgel Multipore HXL-Mx3 connecting+guardcolumn (Tosoh Co. ltd.)
Eluant: tetrahydrofuran
Flow rate: 1.0 mL/min
Detecting device: RI detector
Column temperature: 40° C.
Injection amount: 100 μL
Standard material for calculating molecular weight: standard polysthylene (Tosoh Co., ltd.)
Synthesis Example 1
Synthesis of Compound (M-E)




10.00 parts of a compound (E-2), 40.00 parts of tetrahydrofuran and 7.29 parts of pyridine were mixed, and stirred for 30 minutes at 23° C. The obtained mixture was cooled to 0° C. To this mixture was added 33.08 parts of a compound (E-1) over 1 hour while maintaining at the same temperature. The temperature of the mixture was then elevated to about 23° C., and the mixture was stirred for 3 hour at the same temperature. Thus obtained reactant was added to 361.51 parts of ethyl acetate and 20.19 parts of 5% of hydrochloric acid solution to obtain a mixture, the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 81.42 parts of a saturated sodium hydrogen carbonate was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to recover the organic layer. To the recovered organic layer was added 90.38 parts of ion-exchanged water, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. These washing operations were repeated for 5 times. The obtained organic layer was concentrated, resulting in 23.40 parts of the compound (M-E).
MS (mass spectroscopy): 326.0 (molecular peak)
Synthesis Example 2
Synthesis of Compound (M-L)




88.00 parts of a compound (L-2), 616.00 parts of methyl isobutyl ketone and 60.98 parts of pyridine were mixed, and stirred for 30 minutes at 23° C. The obtained mixture was cooled to 0° C. To this mixture was added 199.17 parts of a compound (L-1) over 1 hour while maintaining at the same temperature. The temperature of the mixture was then elevated to about 10° C., and the mixture was stirred for 1 hour at the same temperature. Thus obtained reactant was added to 1446.22 parts of n-heptane and 703.41 parts of 2% of hydrochloric acid solution to obtain a mixture, the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 337.64 parts of 2% of hydrochloric acid solution was added to obtain a mixture, and the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 361.56 parts of ion-exchanged water was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. To the obtained organic layer, 443.92 parts of 10% of potassium carbonate was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to recover the organic layer. These washing operations were repeated for 2 times. To the obtained organic layer, 361.56 parts of ion-exchanged water was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. These washing operations were repeated for 5 times. The obtained organic layer was concentrated, resulting in 163.65 parts of the compound (M-L).
MS (mass spectroscopy): 276.0 (molecular ion peak)
Synthesis Example 3
Synthesis of Compound (M-M)




9.60 parts of a compound (M-2), 38.40 parts of tetrahydrofuran and 5.99 parts of pyridine were mixed, and stirred for 30 minutes at 23° C. The obtained mixture was cooled to 0° C. To this mixture was added 14.00 parts of a compound (M-1) over 1 hour while maintaining at the same temperature. The temperature of the mixture was then elevated to about 10° C., and the mixture was stirred for 1 hour at the same temperature. Thus obtained reactant was added to 14.51 parts of the compound (M-4) and 8.20 parts of the compound (M-5), and stirred for 3 hours at 23° C. To the reacted solution, 271.95 parts of ethyl acetate and 16.57 parts of 5% of hydrochloric acid solution was added to obtain a mixture, the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 63.64 parts of a saturated sodium hydrogen carbonate was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer. These washing operations were repeated for 2 times. To the washed organic layer was added 67.99 parts of ion-exchanged water, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. These washing operations were repeated for 5 times. The obtained organic layer was concentrated, to the concentrate, 107.71 parts of ethyl acetate was added to obtain a mixture, the mixture was stirred until the added ethyl acetate was complete to dissolve. To this mixture, 646.26 parts of n-heptane was added in the form of drops. Thereafter, the mixture was stirred for 30 minutes at 23° C., and filtrated, resulting in 15.11 parts of the compound (M-M).
MS (mass spectroscopy): 486.2 (molecular ion peak)
Synthesis Example 4
Synthesis of Compound (M-N)




6.32 parts of a compound (N-2), 30.0 parts of tetrahydrofuran and 5.99 parts of pyridine were mixed, and stirred for 30 minutes at 23° C. The obtained mixture was cooled to 0° C. To this mixture was added 14.00 parts of a compound (N-1) over 1 hour while maintaining at the same temperature. The temperature of the mixture was then elevated to about 10° C., and the mixture was stirred for 1 hour at the same temperature. Thus obtained reactant was added to 14.51 parts of the compound (N-4) and 8.20 parts of the compound (N-5), and stirred for 3 hours at 23° C. To the reacted solution, 270 parts of ethyl acetate and 16.57 parts of 5% of hydrochloric acid solution was added to obtain a mixture, the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 65 parts of a saturated sodium hydrogen carbonate was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer. These washing operations were repeated for 2 times. To the washed organic layer was added 65 parts of ion-exchanged water, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. These washing operations were repeated for 5 times. The obtained organic layer was concentrated, the concentrate was treated by column (stationary phase: Merck, silica gel 60-200 mesh, developing solvent: n-heptane/ethyl acetate), resulting in 9.90 parts of the compound (M-N).
MS (mass spectroscopy): 434.1 (molecular ion peak)
Synthesis Example 5
Synthesis of Compound (M-O)




7.08 parts of a compound (O-2), 30.00 parts of tetrahydrofuran and 5.99 parts of pyridine were mixed, and stirred for 30 minutes at 23° C. The obtained mixture was cooled to 0° C. To this mixture was added 14.00 parts of a compound (O-1) over 1 hour while maintaining at the same temperature, elevated the temperature to about 10° C., and stirred for 1 hour at the same temperature. Thus obtained reactant was added to 14.51 parts of the compound (O-4) and 8.20 parts of the compound (O-5), and stirred for 3 hours at 23° C. To the reacted solution, 270 parts of ethyl acetate and 16.57 parts of 5% of hydrochloric acid solution was added to obtain a mixture, the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 65 parts of a saturated sodium hydrogen carbonate was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer. These washing operations were repeated for 2 times. To the washed organic layer was added 65 parts of ion-exchanged water, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. These washing operations were repeated for 5 times. The obtained organic layer was concentrated, the concentrate was treated by column (stationary phase: Merck, silica gel 60-200 mesh, developing solvent: n-heptane/ethyl acetate), resulting in 10.24 parts of the compound (M-O).
MS (mass spectroscopy): 446.1 (molecular ion peak)
Synthesis Example 6
Synthesis of Compound (M-Q)




6.32 parts of a compound (Q-2), 30.00 parts of tetrahydrofuran and 5.99 parts of pyridine were mixed, and stirred for 30 minutes at 23° C. The obtained mixture was cooled to 0° C. To this mixture was added 14.00 parts of a compound (Q-1) over 1 hour while maintaining at the same temperature, elevated the temperature to about 10° C., and stirred for 1 hour at the same temperature. Thus obtained reactant was added to 14.51 parts of the compound (Q-4) and 11.47 parts of the compound (Q-5), and stirred for 3 hours at 23° C. To the reacted solution, 300 parts of ethyl acetate and 16.57 parts of 5% of hydrochloric acid solution was added to obtain a mixture, the mixture was stirred for 30 minutes at 23° C. The obtained solution was allowed to stand, and then separated to recover an organic layer. To the recovered organic layer, 65 parts of a saturated sodium hydrogen carbonate was added, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer. These washing operations were repeated for 2 times. To the washed organic layer was added 100 parts of ion-exchanged water, and the obtained solution was stirred for 30 minutes at 23° C., allowed to stand, and then separated to wash the organic layer with water. These washing operations were repeated for 5 times. The obtained organic layer was concentrated, the concentrate was treated by column (stationary phase: Merck, silica gel 60-200 mesh, developing solvent: n-heptane/ethyl acetate), resulting in 16.89 parts of the compound (M-Q).
MS (mass spectroscopy): 490.2 (molecular ion peak)
Synthetic Example of the Resin
The monomers used the synthesis of the resin are shown below.













These monomers are referred to as “monomer (M-A)” to “monomer (M-Q)”.
Synthetic Example 7
Synthesis of Resin A1
Monomer (M-E) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-E):monomer (M-G)=70:30, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 72° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 77% yield of copolymer having a weight average molecular weight of about 14000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A1.




Synthetic Example 8
Synthesis of Resin A2
Monomer (M-E) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-E):monomer (M-G)=80:20, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 72° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 75% yield of copolymer having a weight average molecular weight of about 12000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A2.




Synthetic Example 9
Synthesis of Resin A3
Monomer (M-E) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-E):monomer (M-G)=90:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 72° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 70% yield of copolymer having a weight average molecular weight of about 13000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A3.




Synthetic Example 10
Synthesis of Resin A4
Monomer (M-E), monomer (M-F) and monomer (M-H) were mixed together with a mole ratio of monomer (M-E):monomer (M-F):monomer (M-H)=30:10:60, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1.2 mol % and 3.6 mol % respectively with respect to the entire amount of monomers, and the reacted mixture was heated for about 5 hours at 72° C. After that, the obtained reaction mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 91% yield of copolymer having a weight average molecular weight of about 12000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A4.




Synthetic Example 11
Synthesis of Resin A5
Monomer (M-I), monomer (M-J), monomer (M-D), monomer (M-K) and monomer (M-C) were mixed together with a mole ratio of monomer (M-I):monomer (M-J):monomer (M-D):monomer (M-K):monomer (M-C)=32:7:8:10:43, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 73° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 63% yield of copolymer having a weight average molecular weight of about 7200. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A5.




Synthetic Example 12
Synthesis of Resin A6
Monomer (M-B), monomer (M-C) and monomer (M-D) were mixed together with a mole ratio of monomer (M-B):monomer (M-C):monomer (M-D)=35:45:20, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1.0 mol % and 3.0 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 75° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 75% yield of copolymer having a weight average molecular weight of about 7000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A6.




Synthetic Example 13
Synthesis of Resin A7
Monomer (M-A) and monomer (M-S) were mixed together with a mole ratio of monomer (M-A):monomer (M-B)=80:20, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 0.5 mol % and 1.5 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 70° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and ion-exchanged water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 70% yield of copolymer having a weight average molecular weight of about 28000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A7.




Synthetic Example 14
Synthesis of Resin A8
Monomer (M-L), monomer (M-M) and monomer (M-G) were mixed together with a mole ratio of monomer (M-L):monomer (M-M):monomer (M-G)=80:10:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 0.7 mol % and 2.1 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 75° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 84% yield of copolymer having a weight average molecular weight of about 20000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A8.




Synthetic Example 15
Synthesis of Resin A9
Monomer (M-N) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-N):monomer (M-G)=90:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 0.7 mol % and 2.1 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 75° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 83% yield of copolymer having a weight average molecular weight of about 19000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A9.




Synthetic Example 16
Synthesis of Resin A10
Monomer (M-O) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-O):monomer (M-G)=90:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 0.7 mol % and 2.1 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 75° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 79% yield of copolymer having a weight average molecular weight of about 21000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A10.




Synthetic Example 17
Synthesis of Resin A11
Monomer (M-I), monomer (M-J), monomer (M-D), monomer (M-C) and monomer (M-K) were mixed together with a mole ratio of monomer (M-I):monomer (M-J):monomer (M-D):monomer (M-C):monomer (M-K)=30:14:6:20:30, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 73° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 65% yield of copolymer having a weight average molecular weight of about 8100. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A11.




Synthetic Example 18
Synthesis of Resin A12
Monomer (M-P), monomer (M-J), monomer (M-D), monomer (M-C) and monomer (M-K) were mixed together with a mole ratio of monomer (M-P):monomer (M-J):monomer (M-D):monomer (M-C):monomer (M-K) 30:14:6:20:30, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 73° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water (methanol:water=4:1 by weight) to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 2 times, resulting in a 68% yield of copolymer having a weight average molecular weight of about 7800. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A12.




Synthetic Example 19
Synthesis of Resin A13
Monomer (M-P), monomer (M-D) and monomer (M-C) were mixed together with a mole ratio of monomer (M-P):monomer (M-D):monomer (M-C)=50:25:25, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1.0 mol % and 3.0 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 8 hours at 80° C. After that, the obtained reacted mixture was poured into a mixture of a large amount of methanol and water (methanol:water=4:1 by weight) to precipitate a resin. The obtained resin was filtrated. Thus obtained resin was dissolved in another dioxane to obtain a solution, and the solution was poured into a mixture of methanol and water to precipitate a resin. The obtained resin was filtrated. These operations were repeated 3 times to purify by reprecipitation, resulting in a 60% yield of copolymer having a weight average molecular weight of about 9200. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A13.




Synthetic Example 20
Synthesis of Resin A14
Monomer (M-L) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-L):monomer (M-G)=90:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 1 mol % and 3 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 72° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 82% yield of copolymer having a weight average molecular weight of about 14000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A14.




Synthetic Example 21
Synthesis of Resin A15
Monomer (M-N) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-N):monomer (M-G)=90:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 0.9 mol % and 2.7 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 70° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 82% yield of copolymer having a weight average molecular weight of about 15000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A15.




Synthetic Example 22
Synthesis of Resin A16
Monomer (M-Q) and monomer (M-G) were mixed together with a mole ratio of Monomer (M-Q):monomer (M-G)=90:10, and dioxane was added thereto in an amount equal to 1.5 times by weight of the total amount of monomers to obtain a solution. Azobisisobutyronitrile and azobis(2,4-dimethylvaleronitrile) was added as an initiator to obtain a solution in an amount of 0.9 mol % and 2.7 mol % respectively with respect to the entire amount of monomers, and the resultant mixture was heated for about 5 hours at 70° C. After that, the obtained reacted mixture was poured into a large amount of n-heptane to precipitate a resin. The obtained resin was filtrated, resulting in a 82% yield of copolymer having a weight average molecular weight of about 14000. This copolymer, which had the structural units derived from the monomers of the following formula, was referred to Resin A16.




(Preparing Resist Composition)

Resist compositions were prepared by mixing and dissolving each of the components shown in Table 4, and then filtrating through a fluororesin filter having 0.2 μm pore diameter.












TABLE 4







Resin
Acid generator
Basic Comp.
PB/PEB



(parts)
(parts)
(parts)
(° C./° C.)




















Ex. 1
A1/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 2
A2/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 3
A3/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 4
A4/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 5
A1/A5 = 0.2/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 6
A1/A5 = 0.1/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 7
A1/A6 = 0.3/10
B2/B3 =
C1 = 0.07
110/110




1.0/0.1


Ex. 8
A8/A11 = 0.7/10
B1 = 1.3
C1 = 0.07
95/85


Ex. 9
A8/A12 = 0.7/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 10
A8/A13 = 0.7/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 11
A9/A11 = 0.7/10
B1 = 1.3
C1 = 0.07
95/85


Ex. 12
A9/A12 = 0.7/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 13
A9/A13 = 0.7/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 14
A10/A11 = 0.7/10
B1 = 1.3
C1 = 0.07
95/85


Ex. 15
A10/A12 = 0.7/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 16
A10/A13 = 0.7/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 17
A9/A6 = 0.3/10
B1 = 1.3
C1 = 0.07
110/105


Ex. 18
A14/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 19
A15/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Ex. 20
A16/A5 = 0.3/10
B1 = 1.0
C1 = 0.07
95/85


Comp.
A7/A6 = 0.1/10
B2/B3 =
C1 = 0.07
110/110


Ex. 1

1.0/0.1


Comp.
A7/A6 = 0.3/10
B2/B3 =
C1 = 0.07
110/105


Ex. 2

1.0/0.1









<Resin>

A1 to A16: Resin A1 to Resin A16 prepared by the Synthetic Examples
Resin (X): A1 to A4, A8 to A10 and A14 to A 16
<Acid Generator>
Acid generator B1: this was prepared by a method according to the method described in the Examples of JP2010-152341




Acid generator B2: this was prepared by a method according to the method described in the Examples of WO 2008/99869




Acid generator B3: this was prepared by a method according to the method described in the Examples of JP2007-108581




<Quencher>

C1: 2,6-diisopropylaniline (obtained from Tokyo Chemical Industry Co., LTD) <Solvent>
















Propylene glycol monomethyl ether acetate
265.0 parts 



Propylene glycol monomethyl ether
20.0 parts



2-Heptanone
20.0 parts



γ-butyrolactone
 3.5 parts










(Producing Resist Pattern by Immersion Lithography)

A composition for an organic antireflective film (“ARC-29”, by Nissan Chemical Co. Ltd.) was applied onto silicon wafers and baked for 60 seconds at 205° C. to form a 78 nm thick organic antireflective film on each of the silicon wafers.
The above resist compositions were then applied thereon by spin coating so that the thickness of the resulting composition layer became 85 nm after drying (i.e., prebake).
The obtained wafers were then pre-baked for 60 seconds on a direct hot plate at the temperatures given in the “PB” column in Table 4 to form a composition layer.
Contact hole patterns were then exposed using a mask pattern (hole pitch: 100 nm, hole diameter: 70 nm) through stepwise changes in exposure quantity using an ArF excimer laser stepper for immersion lithography (“XT:1900Gi” by ASML Ltd.: NA=1.35, 3/42 annular X-Y polarization), on the wafers on which the composition layer had thus been formed. The ultrapure water was used as medium of immersion.
After the exposure, post-exposure baking was carried out for 60 seconds at the temperatures given in the “PEB” column in Table 4.
Then, puddle development was carried out with 2.38 wt % tetramethylammonium hydroxide aqueous solution for 60 seconds to obtain resist patterns.
Each resist pattern is produced based on the resist composition using the mask pattern (hole pitch: 100 nm, hole diameter: 70 nm) as described above. The exposure amount at which a 55 nm-hole diameter is achieved in the pattern is defined as the effective sensitivity.
(Critical Dimension Uniformity (CDU) Evaluation)
The resist patterns were formed by the same method described above with the effective sensitivity. The hole diameter was measured 24 times per one hole, and an average of those was an average hole diameter. The standard deviation was obtained from the average hole diameter based on the population which was 400 values of the above average hole diameter within the same wafer.
A Scanning Electron Microscope (CD SEM Hitachi CG-4000) was used for CDU evaluation. Table 5 shows the results thereof.
(Evaluation of Defects)
The above resist compositions were applied on each of the 12-inch-silicon wafers by spin coating so that the thickness of the resulting film became 150 nm after drying.
The obtained wafers were then pre-baked for 60 seconds on a direct hot plate at the temperatures given in the “PB” column in Table 4 to obtain a composition layer.
The thus obtained wafers with the produced composition layers are rinsed with water for 60 seconds using a developing apparatus (ACT-12, Tokyo electron Co. Ltd.).
Thereafter, the number of defects was counted using a defect inspection apparatus (KLA-2360, KLA-Tencor Co. Ltd.)
Table 5 illustrates the results thereof.










TABLE 5







CDU
Defects




















Ex. 1
1.42
240



Ex. 2
1.44
280



Ex. 3
1.43
360



Ex. 4
1.48
350



Ex. 5
1.46
330



Ex. 6
1.42
410



Ex. 7
1.86
510



Ex. 8
1.55
60



Ex. 9
1.73
90



Ex. 10
1.89
120



Ex. 11
1.42
90



Ex. 12
1.52
130



Ex. 13
1.69
180



Ex. 14
1.49
70



Ex. 15
1.63
100



Ex. 16
1.74
130



Ex. 17
1.96
310



Ex. 18
1.38
320



Ex. 19
1.42
190



Ex. 20
1.49
160



Comp. Ex. 1
2.15
720



Comp. Ex. 2
2.28
720










The present resist composition (the resist compositions of Example 1 to Example 20) was possible to achieve an excellent CDU when producing the resist patterns.
Meanwhile, with the Comparative Example 1, there were a poor CDU when producing the resist pattern.
Also, the present resist composition (the resist compositions of Example 1 to Example 20) was possible to achieve few defects compared to the Comparative Example when producing the resist patterns.
According to the resist composition of the present invention, it is possible to produce a resist pattern with excellent CDU and with few defects when producing the resist pattern. Therefore, the present resist composition can be used for semiconductor microfabrication.

## Claims

1. A resist composition comprising;
a resin having a structural unit represented by the formula (aa) and a structural unit represented by the formula (ab); and
an acid generator,




wherein Raa1 represents a hydrogen atom or a methyl group;
Aaa1 represents an optionally substituted C1 to C6 alkanediyl group or a group represented by the formula (a-1);




wherein s represents 0 or 1;
X10 and X11 independently represents an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group;
A10, A11 and A12 independently represent an optionally substituted C1 to C5 aliphatic hydrocarbon group;
* represents a bond to —O—C(O)—Raa2;
Raa2 represents a perfluoro C1 to C18 aliphatic hydrocarbon group;




wherein Rab1 represents a hydrogen atom or a methyl group;
Aab1 represents a single bond, an optionally substituted C1 to C6 alkanediyl group or a group represented by the formula (a-2);




wherein t represents 0 or 1;
X30 and X31 independently represents an oxygen atom, a carbonyl group, a carbonyloxy group or an oxycarbonyl group;
A30 and A31 independently represent an optionally substituted C1 to C5 aliphatic hydrocarbon group;
A32 represents an optionally substituted C1 to C5 aliphatic hydrocarbon group or a single bond;
* represents a bond to W1;
wherein —W1-(Aab2-Rab2)n is a group represented by the formula (W1-1) or a group represented by the formula (W1-2);




wherein one or more —CH2— contained in the adamantane ring may be replaced by —O— or —CO—;
one or more hydrogen atom contained in the adamantane ring may be replaced by a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
provided that a total carbon number of the adamantane ring and its substituent is 36 or less;
* represents a bond to Aab1;
Aab2 in each occurrence independently represents an optionally substituted C1 to C6 aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—;
Rab2 in each occurrence independently represents a C1 to C12 fluorinated alkyl group, and one or more hydrogen atom contained in the fluorinated alkyl group may be replaced by a hydroxy group or a hydroxymethyl group; and
n represents 1 or 2;




wherein one or more —CH2— contained in the cyclohexane ring may be replaced by —O— or —CO—;
one or more hydrogen atom contained in the cyclohexane ring may be replaced by a hydroxy group, a C1 to C12 alkyl group, a C1 to C12 alkoxy group, a C3 to C12 alicyclic hydrocarbon group or a C6 to C10 aromatic hydrocarbon group;
provided that a total carbon number of the cyclohexane ring and its substituent is 36 or less;
* represents a bond to Aab1; and
Aab2, Rab2 and n have the same definition of the above.

2. The resist composition according to claim 1, wherein Aaa1 of the formula (aa) is a C1 to C6 alkanediyl group.

3. The resist composition according to claim 1, wherein Aaa1 of the formula (aa) is an ethylene group.

4. The resist composition according to claim 1, wherein the acid generator is an acid generator represented by the formula (B1);



wherein Q1 and Q2 independently represent a fluorine atom or a C1 to C6 perfluoroalkyl group;
Lb1 represents an optionally substituted C1 to C17 divalent aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O— or —CO—;
Y represents an optionally substituted C1 to C18 aliphatic hydrocarbon group, and one or more —CH2— contained in the aliphatic hydrocarbon group may be replaced by —O—, —CO— or —SO2—; and
Z+ represents an organic cation.

5. The resist composition according to claim 4, wherein Y of the formula (B1) is an optionally substituted C3 to C18 alicyclic hydrocarbon group.

6. The resist composition according to claim 1, further comprising a resin which is insoluble or poorly soluble in aqueous alkali solution, but becomes soluble in aqueous alkali solution by the action of acid.

7. The resist composition according to claim 1, further comprising a solvent.

8. A method for producing a resist pattern comprising steps of;
(1) applying the resist composition according to claim 1 onto a substrate;
(2) drying the applied composition to form a composition layer;
(3) exposing the composition layer;
(4) heating the exposed composition layer; and
(5) developing the heated composition layer.