MATERIAL SAFETY DATA SHEET

Product Trade Name: TLC-80

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: TLC-80

Synonyms: None

Chemical Family: Organic acid

Application: Diverter

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Benzoic acid 65-85-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

TLC-80

Page 1 of 6

HESI101613
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 252

Flash Point/Range (C): 122

Flash Point Method: PMCC

Autoignition Temperature (F): 1065

Autoignition Temperature (C): 573

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to tan

Odor: Characteristic

TLC-80

Page 2 of 6

HESI101614
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.31

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 43.3

Boiling Point/Range (F): 480

Boiling Point/Range (C): 248

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.02

Vapor Density (Air=1): 4.21

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.29

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 122.12

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Reacts with water to form hydrogen.

Hazardous Decomposition

Products

Phenol. Benzene. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact Causes eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2530 mg/kg (Rat)

Dermal Toxicity: Not determined

TLC-80

Page 3 of 6

HESI101615
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

TLC-80

Page 4 of 6

HESI101616
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5000 Pounds based on Benzoic acid (CAS: 65-85-

0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

TLC-80

Page 5 of 6

HESI101617
TLC-80

Page 6 of 6

HESI101618
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: TLC-W3 - ROCK SALT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: TLC-W3 - ROCK SALT

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

TLC-W3 - ROCK SALT

Page 1 of 5

HESI101619
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.16

TLC-W3 - ROCK SALT

Page 2 of 5

HESI101620
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 92.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 58.44

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

TLC-W3 - ROCK SALT

Page 3 of 5

HESI101621
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

TLC-W3 - ROCK SALT

Page 4 of 5

HESI101622
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

TLC-W3 - ROCK SALT

Page 5 of 5

HESI101623
MATERIAL SAFETY DATA SHEET 

 

 Page: 1 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

 

 Product Identifier: TOMADOL ® 1-73B 

 Product Description: Detergent Range Alcohol ethoxylate 

MANUFACTURER: 24 HR. EMERGENCY 

 Tomah Reserve, Inc. TELEPHONE NUMBERS: 

474 West 19th Street CHEMTREC: (800) 424-9300 

Reserve, LA 70084 Emergency Contact: (608) 868-6811 

 Customer Service: (888) 255-9252 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

 

 Wt.% CAS Registry #

Poly-(oxy-1,2-ethanediyl)-alpha-undecyl-omega ~100 34398-01-1 

 

OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) 

 EXPOSURE LIMITS 

 OSHA PEL ACGIH TLV SUPPLIER

Poly-(oxy-1,2-ethanediyl)-alpha-undecyl-omega Not Established 

3. HAZARDS IDENTIFICATION 

EMERGENCY OVERVIEW 

IMMEDIATE CONCERNS 

 Warning! 

 Causes eye and skin irritation 

 Harmful if ingested 

POTENTIAL HEALTH EFFECTS 

EYES: Causes moderate to severe eye irritation. 

SKIN: May cause moderate irritation to skin. Repeated exposure may cause skin dryness or cracking. 

INGESTION: Irritating to mouth esophagus and stomach if ingested. 

INHALATION: Not expected to be a relevant route of exposure. However, high vapor or aerosol mist 

concentrations may be irritating to the nose, throat, and upper respiratory tract. 

HESI101624
MATERIAL SAFETY DATA SHEET 

 

 Page: 2 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

SIGNS AND SYMPTOMS OF OVER EXPOSURE 

Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision. 

Defatting dermatitis signs and symptoms may include a burning sensation and/or a dried/cracked 

appearance. Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or 

blisters. 

 

MEDICAL CONDITIONS AGGRAVATED: 

 Preexisting skin and eye disorders may be aggravated by exposure to this product. 

4. FIRST AID MEASURES 

EYES: 

 Immediately flush eyes with large amounts of water for at least 15 minutes while holding 

 eyelids open. Get prompt medical attention. 

 SKIN: 

 Immediately flush eyes with large amounts of water for at least 15 minutes; use soap if 

 available. Remove contaminated clothing, including shoes, after flushing has begun. 

 Get prompt medical attention. Do not reuse clothing or shoes until thoroughly cleaned. 

 INGESTION: 

 Do not give liquids if victim is unconscious or very drowsy. Otherwise, give no more than 2 

 glasses of water and induce vomiting by giving 30cc (2 Tablespoons) syrup of IPECAC*. IF 

 IPECAC is not available, give two glasses of water and induce vomiting by touching finger to 

 back of victim’s throat. Keep victim’s head below hips while vomiting. Get Medical 

 Attention. 

 INHALATION: 

 Using proper respiratory protection, immediately remove the affected victim from exposure. 

 Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical 

 attention. 

 

 NOTES TO PHYSICIAN: 

 If victim is a child, give no more than 1 glass of water and 15 cc (1 Tablespoon) syrup of 

 IPECAC. If symptoms such as loss of gag reflex, convulsions or unconsciousness occur 

 Before emesis, gastric lavage should be considered following intubation with a cuffed 

 endotracheal tube. 

 

5. FIRE FIGHTING MEASURES 

 Flash point and method: 154.0 °C / 310.0 °F (Pensky Martin Closed Cup) 

 Flammable limits: Not applicable 

 

HESI101625
MATERIAL SAFETY DATA SHEET 

 

 Page: 3 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

EXTINGUISHING MEDIA: 

Use alcohol type foam, universal foam, dry chemical, carbon dioxide or water spray to extinguish fire. 

 HAZARDOUS COMBUSTION PRODUCTS: 

Carbon Monoxide, Carbon Dioxide. 

FIRE FIGHTING PROCEDURES: 

Use water spray to cool fire exposed surfaces and to protect personnel. Isolate “fuel” supply from fire. 

 

FIRE EXPLOSION: 

Low Hazard, liquid can burn upon heating to temperatures at or above the flashpoint. Empty containers 

retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, 

BRAZE, SOLDER, DRILL, GRING, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, 

STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE 

INJURY OR DEATH. 

Empty drums should be completely drained, properly bunged and promptly returned to drum reconditioner, or 

properly disposed of. 

SENSITIVE TO STATIC DISCHARGE: 

Unknown, use proper grounding procedure. 

 

6. ACCIDENTAL RELEASE MEASURES 

SMALL SPILL: 

For small spill, take up material with an absorbent such as clay or sand and dispose of properly. Flush area 

with water to remove trace residue. 

LARGE SPILL: 

Wear respirator and protective clothing as appropriate. Shut off source of leak if it is safe to do so. Dike and 

contain spilled material. Remove with vacuum trucks or pump to storage/savage containers. Soap up 

residue with an absorbent such as clay, sand or other suitable material. Flush area with water to remove 

trace residue. Consult an expert on disposal of recovered material and ensure conformity to local disposal 

regulations. 

ENVIROMENTAL PRECAUTIONS: 

WATER SPILL: 

Remove from surface by skimming or with suitable adsorbents. If allowed by local authorities. And 

environmental agencies, sinking and/or suitable dispersants may be used in non-confined waters. Consult an 

expert on disposal of recovered material and ensure conformity to local disposal regulations. 

LAND SPILL: 

Eliminate sources of ignition. Prevent additional discharge of material. if possible to do so with out hazard. 

For small spills implement cleanup procedures; for large spills implement cleanup procedures and, if in public 

area, keep public away and advise authorities. Also, if this product is subject to CERCLA reporting (see 

Section 15) notify the National Response Center. 

HESI101626
MATERIAL SAFETY DATA SHEET 

 

 Page: 4 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

7. HANDLING AND STORAGE 

 

GENERAL PROCEDURES: 

Keep container closed. Handle and open container with care. Store in a cool, well vented location. Place 

away from incompatible materials. Do NOT handle or store near an open flame or heat or other sources of 

ignition. Protect material from direct sunlight. It is not known if this material is a static accumulator. 

Therefore, use proper grounding procedures. Do NOT pressurize, cut, heat, or weld containers. Empty 

product containers may contain product residue. Do NOT reuse empty containers without commercial 

cleaning or reconditioning. 

It is recommended that bulk storage tanks be fitted with heating coils when ambient conditions can result in 

handling this product below its melting/freezing point. 

 

 Storage Temperature: 70o

F minimum to125 oF(50 C) maximum 

 Loading Temperature: 70 oF minimum to150 oF maximum 

 Loading/Unloading Viscosity: ~10 to 50 cps 

 

 SPECIAL SENSITIVITY: 

It is recommended to store this product with a nitrogen blanket to minimize the potential for ethoxylate 

oxidation. Overheating of an ethoxylate stored with air should be avoided. When an ethoxylate is vigorously 

mixed in the presence of air or oxygen at temperatures>125o

F (50 o C), it can undergo exothermic oxidative 

degradation. 

 ELECTROSTATIC ACCUMULATION HAZARD: 

 Unknown, use proper grounding procedure. 

MATERIALS/COATINGS SUITABLE 

Stainless steel, epoxy resins, polyester 

MATERIALS/COATINGS UNSUITABLE 

Aluminum, copper, copper alloys 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

 

ENGINEERING CONTROLS: 

 Ventilation should be provided to control worker exposure and prevent health risk. 

 

 PERSONAL PROTECTION: 

RESPIRATORY: 

Use a NIOSH-Approved respirator as required to prevent overexposure. In accord with 20CFR 1910.134, 

use either atmosphere–supplying or air-purifying respirator for organic vapors 

HESI101627
MATERIAL SAFETY DATA SHEET 

 

 Page: 5 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

WORK HYGIENIC PRACTICES: 

Avoid contact with eyes, skin and clothing. Where contact may occur, wear long sleeves, chemical resistant 

gloves (nitrile or neoprene), goggles, and face shield. Where concentrations in air may exceed the limits 

provided in this section, NIOSH/MSHA approved respirators may be necessary to prevent overexposure by 

inhalation. 

 9. PHYSICAL AND CHEMICAL PROPERTIES 

 

Physical State: Clear to slightly hazy liquid.

Odor: Mild odor 

Appearance: Clear liquid 

Vapor Pressure:< 0.1 hPa at 37.8 °C / 100.0 °F

Boiling Point: > 176.7 °C / 350.0 °F

Pour Point: 10.0 °C / 50.0 °F 

Viscosity: 22.0 cst at 37.8 °C / 100.0 °F 

Specific Gravity: 0.975 at 25.0 °C / 77.0 °F 

Coefficient of thermal expansion: 0.0035 PPG 

VOC Content: ~10 % EPA Method 24 

Water solubility: 100.0 g/l Complete, may form gel. Complete, may form gel. 

10. STABILITY AND REACTIVITY 

STABLE: Yes 

HAZARDOUS POLYMERIZATION: No 

STABILITY: Not Applicable 

POLYMERIZATION: Not Applicable 

 

CONDITIONS TO AVOID: 

Oxidation of alcohol ethoxylates may occur under certain conditions. Avoid overheating (temperatures > 125 o

F, 50 oC) especially when vigorously mixed with air. See special precautions. 

 

HAZARDOUS DECOMPOSITION: 

Carbon monoxide and unidentified organic compounds may be formed during combustion. 

 

INCOMPATIBLE MATERIALS 

Strong Acids, oxidizing agents, copper, copper alloys, aluminum 

 

11. TOXICOLOGICAL INFORMATION 

 This product is expected to have the following toxicity based on comparison to similar products. 

HESI101628
MATERIAL SAFETY DATA SHEET 

 

 Page: 6 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

Acute Oral Toxicity : 1 g/kg< LD50 < 2 g/kg , Rat

Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rat 

Sensitisation : Not a skin sensitiser.

 

12. ECOLOGICAL INFORMATION 

ECOTOXICOLOGICAL INFORMATION 

 96 hr fathead minnow static acute LC 50: Is expected to be between 1-10 mg/L 

48 hr daphnia static acute LC 50: Is expected to be between 1-10 mg/L 

CHEMICAL FATE INFORMATION 

This product is expected to be readily biodegradable based on the data below for a similar product 

performance in an OECD 301 F Respirometer test. 

 >75% oxygen removal in 28 days 

 >85% DOC removal 

 

13. DISPOSAL CONSIDERATIONS: 

DISPOSAL METHOD 

Dispose of this product in accordance with federal, state and local regulations 

. 

RCRA/USPA WASTE INFORAMTION:

If this product becomes a waste, it would not be a hazardous waste by RCRA criteria (40CFR 

261). However, the waste should be properly characterized to evaluate whether its composition has been 

modified through procession prior to disposal. 

14. TRANSPORT INFORMATION 

DOT (DEPARTMENT OF TRANSPORTATION) 

Proper Shipping Name: Not Regulated 

INTERNATIONAL (I.M.O.) 

Proper shipping Name: Not Regulated 

AIR (I.C.A.O.) 

Proper shipping Name: Not Regulated 

HESI101629
MATERIAL SAFETY DATA SHEET 

 

 Page: 7 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

15. REGULATORY INFORMATION 

UNITED STATES 

SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 

311/312 Hazard Categories: 

 Under the provisions of Title III, Sections 311/312 of Superfund Amendments and Reauthorizations Act 

(SARA) this product is classified into the hazards listed below: 

. Fire: No Pressure Generating: No Reactivity: No Acute: Yes Chronic: No 

SARA 313 Reportable Ingredients: This product contains no ingredients reportable under Section 313: 

 

CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILTY ACT) 

If this product is accidentally spilled, it is not subject to any special reporting under the requirements of the 

Comprehensive Environmental Response,Compensation and Liability Act (CERCLA). We recommend you 

contact local authorities to determine if there may be other reporting requirements. 

 

TSCA (TOXIC SUBSTANCE CONTROL ACT) 

 TSCA Status: Components of this product are listed on the TSCA Inventory. 

 

RCRA STATUS:

 If this product becomes a waste, it would not be a hazardous waste by RCRA criteria (40CFR 

 261). However, the waste should be properly characterized to evaluate whether its 

 composition has been modified through procession prior to disposal. 

 STATE REGULATIONS 

 PROPOSITION 65 STATEMENT: 

This product contains the following levels of compounds found by the State of California to cause, birth 

defects and other reproductive harm. 

 Ethylene oxide: CAS NO. 75-21-8 <1 ppm 

The following chemicals are specified listed by individual states; other product specific health and safety data 

in other sections of the MSDS mat also be applicable for state requirements. For details on your regulatory 

requirements you should contact the appropriate agency in your state. 

 

 Ethylene oxide: CAS No 75-21-8 <1 ppm 

 Massachusetts; California Safe drinking water and toxics enforcement act of 1986 

 New Jersey Right to Know Act 

 Pennsylvania Right to Know Act 

 GENERAL COMMENTS: 

PROTECTION OF STRATOSPHERIC OZONE (PURSANT TO SECTION 622 OF THE CLEAN AIR ACT 

AMMENDMENTS OF 1990): 

Per 40 CFR Part 82, this product does not contain nor was it directly manufactured with any Class I or Class 

II ozone depleting substances. 

 

HESI101630
MATERIAL SAFETY DATA SHEET 

 

 Page: 8 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

INTERNATIONAL 

EC Label Name Alcohol ethoxylate 

EC Classification Xn Harmful 

EC Risk Phrases R41 Risk of serious damage to eyes. 

R22 Harmful if ingested 

R51 toxic to aquatic organisms. 

EC Safety Phrases S25 Avoid contact with eyes. 

S26 In case of contact with eyes, rinse immediately with plenty of water 

and seek medical advice. 

S37/39 Wear suitable gloves and eye/face protection. 

S61 Avoid release to the environment. Refer to special 

instructions/Safety data sheets. 

WHMIS Classification (CANADA) Class D Division 2 Subdivision B-Toxic Material 

This product is listed on the following international inventories: 

 US TSCA 

 Canadian DSL 

 European EINECS—No Longer Polymer 

 Australian 

 Korean KE-13383 

 Phillipine 

 Japanese 

 China 

16. OTHER INFORMATION 

 Approval date: 4.29.2005 

 

 NFPA CODES: 

 Fire: 1 Health: 2 Reactivity: 0 

HMIS CODES: 

 Fire: 1 Health: 2 Reactivity: 0 

 MANUFACTURER DISCLAIMER: 

 This information relates to the specific material designated and may not be valid for such 

 Material used in combination with any other materials or in any process. Such information 

 is to the best of our knowledge and belief, accurate and reliable as of the date complied. 

 However, no representation, warranty or guarantee is made as to its accuracy, reliability or 

 completeness. It is the users responsibility to satisfy himself as to the suitability and 

 completeness of such information for his own particular use. We do not accept liability for any 

 loss or damage that may occur from the use of this information nor do we offer warranty against 

HESI101631
MATERIAL SAFETY DATA SHEET 

 

 Page: 9 

 DATE PREPARED: 4.29.2005 

 MSDS No 601730

 TOMADOL ® 1-73B 

 

 patent infringement. 

HESI101632
THE DOW CHEMICAL COMPANY 

MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 1 of 17

* or ® Indicates a Trademark of The Dow Chemical Company. 

 

Dow (hereinafter, and for purposes of this MSDS only, refers to The Dow Chemical Company and to Dow 

Chemical Canada Inc.) encourages and expects you to read and understand the entire MSDS, as there is 

important information throughout the document. Dow expects you to follow the precautions identified in 

this document unless your use conditions would necessitate other appropriate methods or actions.

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

1.1 IDENTIFICATION 

Product Name UCARCIDE(TM) 150 Antimicrobial

1.2 COMPANY IDENTIFICATION 

The Dow Chemical Company 

Midland, MI 48674 

 

1.3 EMERGENCY TELEPHONE NUMBER 

 24-HOUR EMERGENCY TELEPHONE NUMBER: (989)636-4400.

Customer Information Number: 1-800-258-2436. 

 

HESI101633
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 2 of 17

2. COMPOSITION INFORMATION 

Component CAS # Amount (%W/W ) 

Glutaraldehyde 111-30-8 50 %

Water 7732-18-5 <= 50%

Methanol 67-56-1 <= 0.5%

 

 

3. HAZARDS IDENTIFICATION 

3.1 EMERGENCY OVERVIEW 

Appearance Transparent colorless 

Physical 

State 

Liquid 

Odor Sharp, Fruity, Medicinal 

Hazards of 

product

CORROSIVE. 

CAUSES IRREVERSIBLE EYE DAMAGE. 

CAUSES SKIN BURNS. 

HARMFUL IF INHALED. 

MAY BE FATAL IF SWALLOWED. 

HARMFUL IF ABSORBED THROUGH SKIN. 

PROLONGED OR FREQUENTLY REPEATED SKIN CONTACT MAY 

CAUSE ALLERGIC REACTIONS IN SOME INDIVIDUALS. 

 

CAUSES ASTHMATIC SIGNS AND SYMPTOMS IN HYPERREACTIVE INDIVIDUALS. 

ASPIRATION MAY CAUSE LUNG DAMAGE. 

 

3.2 POTENTIAL HEALTH EFFECTS 

 

Effects of Single Acute Overexposure 

HESI101634
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 3 of 17

Inhalation Vapor may cause severe irritation of the upper respiratory tract (nose and throat).

Vapor from heated material may cause serious adverse effects, even death. Case reports and 

medical surveys link asthma and respiratory irritation to glutaraldehyde exposure, primarily in 

medical personnel. Asthma-like symptoms may occur in people prone to respiratory disorders or 

other allergies. Symptoms may include coughing, tightness, and discomfort in the chest, difficulty 

breathing and headaches. 

Eye Contact May cause severe irritation with corneal injury which may result in permanent 

impairment of vision, even blindness. Chemical burns may occur. Vapor may cause eye irritation 

experienced as mild discomfort and redness. 

Skin Contact Brief contact may cause skin irritation with local redness. Prolonged contact 

may cause severe skin burns. Symptoms may include pain, severe local redness, swelling, and 

tissue damage. Skin contact may cause an allergic skin reaction in a small proportion of 

individuals. Has caused allergic skin reactions when tested in guinea pigs. Has caused allergic 

skin reactions when tested in mice. Inhalation of vapors may result in skin sensitization. In 

sensitized individuals, reexposure to very small amounts of vapor, mist, or liquid may cause a 

severe allergic skin reaction. May stain skin. May cause itching. 

Skin Absorption Harmful if absorbed through skin. 

Swallowing May be fatal if swallowed. Oral toxicity of glutaraldehyde increases with dilution. 

Drinking water following ingestion of concentrated glutaraldehyde solutions can enhance the 

toxicity of glutaraldehyde. Swallowing may result in irritation or burns of the mouth, throat, and 

gastrointestinal tract. Swallowing may result in gastrointestinal irritation or ulceration. Excessive 

exposure may cause headache, dizziness, anesthesia, drowsiness, unconsciousness and other 

central nervous system effects, including death. Aspiration into the lungs may occur during 

ingestion or vomiting, causing tissue damage or lung injury.

Chronic, Prolonged or Repeated Overexposure 

Effects of Repeated Overexposure Repeated skin contact may result in absorption of 

amounts which could cause death. May cause nausea or vomiting. 

Other Effects of Overexposure No information available. 

 

See Section 11 for toxicological information and additional information about potential health 

effects. 

3.3 POTENTIAL ENVIRONMENTAL EFFECTS 

See Section 12 for Ecological Information. 

HESI101635
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 4 of 17

4. FIRST AID PROCEDURES 

4.1 INHALATION 

Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial 

respiration; if by mouth to mouth use rescuer protection (pocket mask etc). Call a poison control 

center or doctor for treatment advice. If breathing is difficult, oxygen should be administered by 

qualified personnel. 

4.2 EYE CONTACT

Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact 

lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, 

preferably from an ophthalmologist. 

4.3 SKIN CONTACT 

Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. 

Call a poison control center or doctor for treatment advice. First Aid responders should pay 

attention to self-protection and use the recommended protective clothing (chemical resistant 

gloves, splash protection). Wash clothing before reuse. Shoes and other leather items which 

cannot be decontaminated should be disposed of properly. 

4.4 SWALLOWING 

Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by 

a poison control center or doctor. Do not give any liquid to the person. Do not give anything by 

mouth to an unconscious person. Seek medical attention immediately. 

4.5 NOTES TO PHYSICIAN 

Probable mucosal damage may contraindicate the use of gastric lavage. 

Chemical eye burns may require extended irrigation. Obtain prompt consultation, preferably 

from an ophthalmologist. 

Maintain adequate ventilation and oxygenation of the patient. 

May cause asthma-like (reactive airways) symptoms. Bronchodilators, expectorants and 

antitussives may be of help. 

Glutaraldehyde may transiently worsen reversible airways obstruction including asthma or 

reactive airways disease. 

Treat bronchospasm with inhaled beta-2 agonist and oral or parenteral corticosteroids. 

Inhalation of vapors may result in skin sensitization. In sensitized individuals, reexposure to very 

small amounts of vapor, mist, or liquid may cause a severe allergic skin reaction. 

If burn is present, treat as any thermal burn, after decontamination. 

 

5. FIRE FIGHTING MEASURES 

HESI101636
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 5 of 17

5.1 FLAMMABLE PROPERTIES - REFER TO SECTION 9, PHYSICAL AND 

CHEMICAL PROPERTIES 

5.2 EXTINGUISHING MEDIA 

To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical 

or foam. 

5.3 FIRE FIGHTING PROCEDURES 

Keep people away. Isolate fire and deny unnecessary entry. To extinguish combustible 

residues of this product use water fog, carbon dioxide, dry chemical or foam. Contain fire water 

run-off if possible. Fire water run-off, if not contained, may cause environmental damage. 

Review the "Accidental Release Measures" and the "Ecological Information" sections of this 

MSDS. 

5.4 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS 

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting 

clothing (includes fire fighting helmet, coat, pants, boots, and gloves). Avoid contact with this 

material during fire fighting operations. If contact is likely, change to full chemical resistant fire 

fighting clothing with SCBA. If this is not available, wear full chemical resistant clothing with 

SCBA and fight fire from a remote location. For protective equipment in post-fire or non-fire 

clean up situations, refer to the relevant sections. 

5.5 UNUSUAL FIRE AND EXPLOSION HAZARDS 

This material will not burn until the water has evaporated. Residue can burn. 

 

5.6 HAZARDOUS COMBUSTION PRODUCTS 

Under fire conditions some components of this product may decompose. The smoke may 

contain unidentified toxic and/or irritating compounds. Combustion products may include and 

are not limited to: Carbon monoxide. Carbon dioxide. 

6. ACCIDENTAL RELEASE MEASURES 

Steps to be Taken if Material is Released or Spilled: 

Contain spilled material if possible. Collect in suitable and properly labeled containers. This 

product is toxic to fish. Avoid discharge to sewers and natural waterways. Very low 

concentrations (5 ppm or less of glutaraldehyde) can be degraded in a biological wastewater 

treatment system. Thus, small spills can be flushed with large quantities of water. Large 

quantities or 'slugs' can be harmful to the treatment system. Thus, large spills should be 

collected for disposal. It may also be possible to decontaminate spilled material by careful 

application of aqueous sodium hydroxide or sodium bisulfite. Depending on conditions, 

considerable heat and fumes can be liberated by the decontamination reaction. See Section 13, 

Disposal Considerations, for additional information. 

HESI101637
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 6 of 17

Personal Precautions: Use appropriate safety equipment. For additional information, refer to 

Section 8, Exposure Controls and Personal Protection. Evacuate area. Keep upwind of spill. 

Ventilate area of leak or spill. Only trained and properly protected personnel must be involved 

in clean-up operations. Refer to Section 7, Handling for additional precautionary measures. 

Environmental Precautions: Spills or discharge to natural waterways is likely to kill aquatic 

organisms. Prevent from entering into soil, ditches, sewers, waterways and/ or groundwater. 

See Section 12, Ecological Information. 

7. HANDLING AND STORAGE 

7.1 HANDLING 

General Handling 

Do not get in eyes, on skin, on clothing. 

Avoid breathing vapor. 

Do not swallow. 

Wear goggles, protective clothing and butyl or nitrile gloves. 

Remove contaminated clothing and wash before reuse. 

Keep container closed. 

Use with adequate ventilation. 

Wash thoroughly with soap and water after handling. 

Ventilation 

Provide general and/or local exhaust ventilation to control airborne levels below the exposure 

guidelines. However, if vapors are strong enough to be irritating to the nose or eyes, the TLV is 

probably being exceeded and special ventilation and or respiratory protection may be required. 

Other Precautions 

This product in its undiluted form must not be used in a spray or aerosol application. If dilutions 

or mixtures of this product are used in a spray application, full personal protective equipment is 

strongly recommended to prevent exposure. 

7.2 STORAGE 

Please refer to Dow publication: GLUTARALDEHYDE. Safe Handling and Storage Guide; Form 

No. 253-01338. 

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 

8.1 EXPOSURE LIMITS 

HESI101638
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 7 of 17

Component Exposure Limits Skin. Form 

Glutaraldehyde 0.05 ppm CEILING ACGIH activated and unactivated 

Methanol 200 ppm TWA8 ACGIH Yes 

250 ppm STEL ACGIH Yes 

200 ppm TWA8 OSHA 

260 mg/m3 TWA8 OSHA 

In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the 

Form Column for a particular limit, the listed limit includes all airborne forms of the substance 

that can be inhaled. 

A "Yes" in the Skin Column indicates a potential significant contribution to overall exposure by 

the cutaneous (skin) route, including mucous membranes and the eyes, either by contact with 

vapors or by direct skin contact with the substance. A "Blank" in the Skin Column indicates that 

exposure by the cutaneous (skin) route is not a potential significant contributor to overall 

exposure. 

 

8.2 PERSONAL PROTECTION 

Respiratory 

Protection:

Atmospheric levels should be maintained below the exposure 

guideline. When atmospheric levels may exceed the exposure 

guideline, use an approved air purifying respirator. The respirator 

should contain an organic vapor sorbent. 

For emergency and other conditions where the exposure guideline 

may be exceeded, use an approved positive-pressure self-contained 

breathing apparatus or positive-pressure airline with auxiliary selfcontained air supply. 

Ventilation: Provide general and/or local exhaust ventilation to control airborne 

levels below the exposure guidelines. 

However, if vapors are strong enough to be irritating to the nose or 

eyes, the TLV is probably being exceeded and special ventilation and 

or respiratory protection may be required. 

Eye Protection: Use splashproof monogoggles or safety glasses with side shields in 

conjunction with a face shield. 

Eye wash fountain should be located in immediate work area. 

If exposure causes eye discomfort, use a full-face respirator. 

HESI101639
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 8 of 17

Protective 

Gloves:

Use gloves chemically resistant to this material when prolonged or 

frequently repeated contact could occur. 

Examples of preferred glove barrier materials include: 

Butyl rubber. 

Examples of acceptable glove barrier materials include: 

Nitrile/butadiene rubber ("nitrile" or "NBR"). 

NOTICE: The selection of a specific glove for a particular application 

and duration of use in a workplace should also take into account all 

relevant workplace factors such as, but not limited to: Other chemicals 

which may be handled, physical requirements (cut/puncture protection, 

dexterity, thermal protection), potential body reactions to glove 

materials, as well as the instructions/specifications provided by the 

glove supplier. 

Other Protective 

Equipment:

Use chemical protective clothing resistant to this material. 

Remove contaminated clothing immediately, wash skin area with soap 

and water, and launder clothing before reuse or dispose of properly. 

Items which cannot be decontaminated, such as shoes, belts and 

watchbands, should be removed and disposed of properly. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Physical State: Liquid 

Appearance: Transparent colorless 

Odor: Sharp, Fruity, Medicinal 

Flash Point - Closed Cup: Tag Closed Cup ASTM D 56 None. 

Flammable Limits In Air: 

Lower Not Determined, Aqueous System 

Upper Not Determined, Aqueous System 

Autoignition Temperature: None. 

Vapor Pressure: 0.20 mmHg 20 °C Based on glutaraldehyde

Boiling Point (760 mmHg): ~ 100.5 °C ~ 213 °F As product.

Vapor Density (air = 1): 1.1 

Specific Gravity (H2O = 1): 1.129 20 °C / 20 °C

HESI101640
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 9 of 17

Freezing Point: ~ -21 °C ~ -6 °F 

Melting Point: Not applicable. 

Solubility in Water (by weight): 100 % 20 °C 

pH: 3.1 - 4.5 

Molecular Weight: 100.11 g/mol 

Octanol/Water Partition Coefficient - Measured: -0.333

Evaporation Rate (Butyl Acetate = 1): 1.0 

 

10. STABILITY AND REACTIVITY 

10.1 STABILITY/INSTABILITY Stable. 

Conditions to Avoid: Active ingredient decomposes at elevated temperatures. 

Incompatible Materials: Avoid contact with: Strong acids. Strong bases. 

Thermal Decomposition: Decomposition products depend upon temperature, air supply and 

the presence of other materials. 

10.2 HAZARDOUS POLYMERIZATION 

Will not occur. 

 

11. TOXICOLOGICAL INFORMATION 

ACUTE TOXICITY 

Peroral 

Rat; male; LD50 = 1468 mg/kg

HESI101641
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 10 of 17

Peroral 

Mouse; LD50 = 226 - 305 mg/kg

SENSITIZATION (ANIMAL AND HUMAN STUDIES) 

Has caused allergic skin reactions when tested in guinea pigs., Has caused allergic skin 

reactions when tested in mice. 

DEVELOPMENTAL TOXICITY 

Did not cause birth defects in laboratory animals., Has been toxic to the fetus in lab animals at 

doses toxic to the mother. 

REPRODUCTIVE TOXICITY 

In animal studies, did not interfere with reproduction. 

CHRONIC TOXICITY AND CARCINOGENICITY 

An increase in large, granular lymphocytes in Fischer rats dosed with glutaraldehyde for two 

years was random or a secondary carcinogenic effect due to a modifying influence on the 

occurrence of this common neoplasm in this rat strain., In a NTP chronic 2-year inhalation study 

on glutaraldehyde, no carcinogenicity was seen in rats or in mice. 

GENETIC TOXICOLOGY 

In Vitro 

In vitro genetic toxicity studies were negative in some cases and positive in other cases. 

In Vivo 

Animal genetic toxicity studies were predominantly negative. 

SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMANS 

Repeated skin contact may result in absorption of amounts which could cause death. 

May cause nausea or vomiting. 

12. ECOLOGICAL INFORMATION 

12.1 ENVIRONMENTAL FATE 

Based largely or completely on information for glutaraldehyde. expressed on a 100% active 

ingredient basis. Material is readily biodegradable. Passes OECD test(s) for ready 

HESI101642
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 11 of 17

biodegradability. The rate constant for the vapor phase reaction with photochemically produced 

hydroxyl radicals at 25C is estimated to be: 4.69E-11 cm3/molecule-sec. 

BOD (% Oxygen consumption) 

 Day 5 Day 10 Day 15 Day 20 Day 28/30 

28 % 57 - 63 % 72 - 74 % 

DOC die-away test (OECD 301A) (% dissolved organic carbon disappearance) 

 Day 7 Day 14 Day 21 Day 28 

 83 % 

12.2 ECOTOXICITY 

Based largely or completely on information for glutaraldehyde., expressed on a 100% active 

ingredient basis., Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 

between 0.1 and 1 mg/L in the most sensitive species tested)., Inhibitory concentration (IC50) in 

OECD Activated Sludge Respiration Inhibition Test (OECD Test No. 209) is:, >50 mg/L. 

Toxicity to Micro-organisms 

Bacterial Growth Inhibition; 16 h; EC50 

Result value: (17 - 25) mg/L 

Toxicity to Aquatic Invertebrates 

water flea (Daphnia magna); Acute LC50 

Result value: 5.0 mg/L 

Toxicity to Aquatic Invertebrates 

grass shrimp (Palaemonetes pugio); Acute LC50 

Result value: 41 mg/L 

Toxicity to Aquatic Invertebrates 

copepod Acartia tonsa; Acute LC50 

Result value: 0.11 mg/L 

Toxicity to Aquatic Invertebrates 

saltwater mysid (Mysidopsis bahia); Acute LC50 

Result value: 7.1 mg/L 

Toxicity to Aquatic Invertebrates 

eastern oyster (Crassostrea virginica); Shell deposition inhibition; EC50 

Result value: 0.78 mg/L 

Toxicity to Aquatic Invertebrates 

mussel Mytilus edulis; Acute EC50 

HESI101643
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 12 of 17

Result value: 0.2 mg/L 

Toxicity to Aquatic Plants 

alga (Scenedesmus sp.); Growth inhibition; EC50 

Result value: 0.97 mg/L 

Toxicity to Aquatic Plants 

green alga Selenastrum capricornutum; Growth inhibition; EC50 

Result value: 0.81 mg/L 

Toxicity to Aquatic Plants 

diatom Skeletonema costatum; Growth inhibition; EC50 

Result value: 0.61 mg/L 

Toxicity to Fish 

fathead minnow (Pimephales promelas); Acute LC50 

Result value: 5.4 mg/L 

Toxicity to Fish 

bluegill (Lepomis macrochirus); Acute LC50 

Result value: 9.4 - 11 mg/L 

Toxicity to Fish 

rainbow trout (Oncorhynchus mykiss); Acute LC50 

Result value: 11 mg/L 

Toxicity to Fish 

sheepshead minnow (Cyprinodon variegatus); Acute LC50 

Result value: 32 mg/L 

12.3 FURTHER INFORMATION 

Based largely or completely on information for glutaraldehyde. expressed on a 100% active 

ingredient basis. Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for 

mobility in soil is high (Koc between 50 and 150). Soil organic carbon/water partition coefficient 

(Koc) is estimated to be: 120 - 500. Henry's Law Constant (H) is estimated to be: 3.3E-08 atmm3/mole. The hydrolysis half-life is pH9 - 46 days 25°C Acute oral LD50 in mallard (Anas 

platyrhynchos) is 408 - 466 mg/kg. Dietary LC50 in bobwhite (Colinus virginianus) is >5000 

ppm. Dietary LC50 in mallard (Anas platyrhynchos) is >5000 ppm. Material is moderately toxic 

to birds on an acute basis (LD50 between 51 and 500 mg/kg). Material is practically non-toxic to 

birds on a dietary basis (LC50 > 5000 ppm). 

Theoretical Oxygen Demand (THOD) - calculated: 1.92 mg/mg 

Octanol/Water Partition Coefficient - Measured: -0.333 

HESI101644
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 13 of 17

13. DISPOSAL CONSIDERATIONS 

13.1 DISPOSAL 

DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.

All disposal practices must be in compliance with all Federal, State/Provincial and local laws and 

regulations. Regulations may vary in different locations. Waste characterizations and 

compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS 

NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING 

PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION 

PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED 

CONDITION AS DESCRIBED IN MSDS SECTION 2 (Composition/ Information on Ingredients).

FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred option is to contact your State 

Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the 

nearest EPA Regional Office for guidance. The preferred option in other jurisdictions is to 

contact the regulatory authority for this product for guidance. As a service to its customers, Dow 

can provide names of information resources to help identify waste management companies and 

other facilities which recycle, reprocess or manage chemicals or plastics, and that manage used 

drums. Telephone Dow's Customer Information Group at 1-800-258-2436 or 1-989-832-1556 

(U.S.), or 1-800-331-6451 (Canada) for further details . 

 

14. TRANSPORT INFORMATION 

 

14.1 U.S. D.O.T. 

 

NON-BULK 

Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, ORGANIC, NOS 

Technical Name : CONTAINS GLUTARALDEHYDE 

Hazard Class : 8.

ID Number : UN3265 

Packing Group : PG II 

BULK 

Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, ORGANIC, NOS

Technical Name : CONTAINS GLUTARALDEHYDE

Hazard Class : 8.

ID Number : UN3265 

Packing Group : PG II 

 

HESI101645
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 14 of 17

This information is not intended to convey all specific regulatory or operational 

requirements/information relating to this product. Additional transportation system information 

can be obtained through an authorized sales or customer service representative. It is the 

responsibility of the transporting organization to follow all applicable laws, regulations and rules 

relating to the transportation of the material. 

15. REGULATORY INFORMATION 

15.1 FEDERAL/NATIONAL 

OSHA HAZARD COMMUNICATION STANDARD 

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication 

Standard, 29 CFR 1910.1200. 

SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND 

COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313

To the best of our knowledge this product does not contain chemicals at levels which 

require reporting under this statute. 

COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF 1980 (CERCLA)

SECTION 103

To the best of our knowledge this product does not contain chemicals at levels which 

require reporting under this statute. 

SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND 

COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 302

To the best of our knowledge this product does not contain chemicals at levels which 

require reporting under this statute. 

 

SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND 

COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311 AND 312

Delayed (Chronic) Health Hazard : Yes 

Fire Hazard : No 

HESI101646
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 15 of 17

Immediate (Acute) Health Hazard : Yes 

Reactive Hazard : No 

Sudden Release of Pressure Hazard : No 

TOXIC SUBSTANCES CONTROL ACT (TSCA)

All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory 

requirements under 40 CFR 720.30. 

EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS)

The components of this product are on the EINECS inventory or are exempt from EINECS 

inventory requirements. 

CEPA - DOMESTIC SUBSTANCES LIST (DSL)

All substances contained in this product are listed on the Canadian Domestic Substances List 

(DSL) or are not required to be listed. 

15.2 STATE/LOCAL 

PENNSYLVANIA (WORKER AND COMMUNITY RIGHT-TO-KNOW ACT): PENNSYLVANIA HAZARDOUS SUBSTANCES 

LIST AND/OR PENNSYLVANIA ENVIRONMENTAL HAZARDOUS SUBSTANCE LIST:

 The following product components are cited in the Pennsylvania Hazardous Substance List 

and/or the Pennsylvania Environmental Substance List, and are present at levels which require 

reporting. 

Component CAS # Amount 

Glutaraldehyde 111-30-8 <= 50.0000%

PENNSYLVANIA (WORKER AND COMMUNITY RIGHT-TO-KNOW ACT): PENNSYLVANIA SPECIAL HAZARDOUS 

SUBSTANCES LIST:

To the best of our knowledge this product does not contain chemicals at levels which require 

reporting under this statute. 

HESI101647
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 16 of 17

CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986)

This product contains no listed substances known to the State of California to cause cancer, 

birth defects or other reproductive harm, at levels which would require a warning under the 

statute. 

 

CALIFORNIA SCAQMD RULE 443.1 (SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT RULE 443.1,

LABELING OF MATERIALS CONTAINING ORGANIC SOLVENTS)

VOC: Not applicable. 

 This section provides selected regulatory information on this product including its components. 

This is not intended to include all regulations. It is the responsibility of the user to know and 

comply with all applicable rules, regulations and laws relating to the product being used. 

16. OTHER INFORMATION 

16.1 ADDITIONAL INFORMATION 

Additional information on this product may be obtained by calling Dow's Customer Information 

Group at 1-800-258-2436 (U.S.) or 1-800-331-6451 (Canada). 

 

16.2 HAZARD RATING SYSTEM 

NFPA ratings for this product are: H - 3 F - 1 R - 0 

These ratings are part of a specific hazard communication program and should be disregarded 

where individuals are not trained in the use of this hazard rating system. You should be familiar 

with the hazard communication programs applicable to your workplace. 

16.3 RECOMMENDED USES AND RESTRICTIONS 

HESI101648
MATERIAL SAFETY DATA SHEET

Product Name: UCARCIDE(TM) 150 Antimicrobial Effective Date: 07/26/2004

MSDS#: 1976 Page 17 of 17

This product in its undiluted form must not be used in a spray or aerosol application. If dilutions 

or mixtures of this product are used in a spray application, full personal protective equipment is 

strongly recommended to prevent exposure. 

FOR INDUSTRY USE ONLY. 

16.4 REVISION 

Version: 6.0 

Revision: 07/26/2004 

Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this 

document. 

16.5 LEGEND 

Bacterial/NA Non Acclimated Bacteria 

F Fire 

H Health 

IHG Industrial Hygiene Guideline 

N/A Not available 

NFPA National Fire Protection Association 

O Oxidizer 

R Reactivity 

TS Trade secret 

VOL/VOL Volume/Volume 

W Water Reactive 

W/W Weight/Weight 

NOTICE: Dow urges each customer or recipient of this MSDS to study it carefully and consult 

appropriate expertise, as necessary or appropriate, to become aware of and understand the data 

contained in this MSDS and any hazards associated with the product. The information herein is 

provided in good faith and believed to be accurate as of the effective date shown above. 

However, no warranty, express or implied, is given., Regulatory requirements are subject to 

change and may differ between various locations. It is the buyer's/user's responsibility to ensure 

that its activities comply with all federal, state, provincial or local laws. The information 

presented here pertains only to the product as shipped. Since conditions for use of the product 

are not under the control of Dow, it is the buyer's/user's duty to determine the conditions 

necessary for the safe use of this product., Due to the proliferation of sources for information 

such as manufacturer-specific MSDSs, Dow is not and cannot be responsible for MSDSs 

obtained from any source other than Dow. If you have obtained a Dow MSDS from a non-Dow 

source or if you are not sure that a Dow MSDS is current, please contact Dow for the most 

current version.

HESI101649
Norton Proppants, Inc.

Contact Us Storage/

Transportation

Manufacturing 

Process

Technical 

Library

Proppant 

Product

http://www.nortonproppants.com/06_products/06_05_versaprop.htm (1 of 4)1/12/2004 4:17:08 AM

1. Chemical Name and Company Identification

1.0 Product Name : Versaprop(all mesh sizes)

Synonym(s) Ceramic Proppant

Chemical Family: Aluminosilicate

Manufacturer: NORTON PROPPANTS

5300 GERBER ROAD

FORT SMITH, ARKANSAS 72904

24-HOUR EMERGENCY (479)782-2001

2. Component Information 

2.0 Chemical Name Common Name % By Weight (Typical)

Aluminum Silicate Mullite 35-65

Aluminum Oxide Corundum 35-65

3. Hazards Identification 

3.1 Emergency Overview 

HMIS Rating

Health: 1. (Slight)

Flammability: 0. (minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

Inhalation: Prolonged exposure to dusts may cause respiratory tract irritation.

Ingestion: No known adverse effects.

Eye Contact: May cause irritation on prolonged or repeated contact.

Skin Contact: May cause irritation on prolonged or repeated contact.

4. First Aid Measures

4.0 Ingestion: Seek medical attention if large quantities are ingested.

Inhalation: Remove to fresh air.

HESI101650
Norton Proppants, Inc.

http://www.nortonproppants.com/06_products/06_05_versaprop.htm (2 of 4)1/12/2004 4:17:08 AM

Eye Contact: Immediately flush eyes with large quantities of water, call a physician 

if irritation persists.

5. Fire Fighting Measure

5.0 Flash Point: Non Flammable 

Lower Explosion Limit: Not Applicable 

Upper Explosion Limit: Not Applicable

Autoignition Temperature: Not Applicable

Use extinguishing agent suitable for type of surrounding fire.

6. Accidental Release Measures

6.0 Spills: No special procedures are required for clean-up of spills or leaks. Spherical 

shape of spilled pellets can create a slip hazzard.

7. Handling and Storage

7.0 Store under dry conditions. Handle with adequate ventilation. Use a niosh/MSHA 

approved respirator if dust is present.

8. Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creating dust.

8.2 Personal Protection 

Use Niosh/MHSA approved respiratory protective equipment when airborne 

caoncentrations exceed applicable criteria. Wear safety glasses at all times to 

prevent eye irritation.

8.3 Exposure Guidelines 

Ingredient CAS# %/Weight OSHA PEL/TWA ACGIH-TWA TLV

Corundum 1302-44-

56

35-65 15mg/m3 (total)

5mg/m3 (respir)

10mg/m3 (total)

3mg/m3 (respir)

Aluminum 

Silicate 

1302-76-7 35-65 15mg/m3 (total)

5mg/m3 (respir)

10mg/m3 (total)

3mg/m3 (respir)

9. Physical and Chemical Properties

9.0 Appearance: Grayish brown to black free flowing granules.

Odor: None

Flash Point: N/A This material does not give a flashpoint by conventional 

methods.

Stability: Stable

Specific Gravity: 3.05-3.20

PH Not Applicable 

Vapor Pressure @25°C Not Applicable 

Viscocity Not Applicable 

Solubility in Water Non-Soluble

Boiling Point Not Applicable 

HESI101651
Norton Proppants, Inc.

http://www.nortonproppants.com/06_products/06_05_versaprop.htm (3 of 4)1/12/2004 4:17:08 AM

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1)

11. Toxicological Information 

See Section 3.

LC50 Not Available 

LD50 Not Available

12. Ecological Information 

Not Determined 

13. Disposal Considerations 

Dispose of according to local, state/provencial requirements.

14. Transportation Information 

14.1 U.S. Department of Transportation

Non-regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated

15. U.S. Regulatory Information (Selected regulations)

SARA Title III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA) N/A

Cercla Reportable Quantity: None

Clean Air Ammendments-Hazardous Air Pollutants: None

California State Proposition 65: N/A

16. OTHER INFORMATION

The OHSA Hazard Communication Standard 29CFR 1910.1200 requires that the 

information contained on these sheets be made available to your workers. Instruct 

your workers to handle this product properly. Consult with appropriate experts to 

guard against hazards associated with use of this product and its ingredients.

DISCLAIMER

Seller makes no warranty, expressed or implied, concerning the product or the 

merchantability or fitness thereof for any purpose, except that the product 

conforms to contracted specifications, and that the product does not infringe any 

valid United States or Canadian patent. No claim of any kind shall be greater in 

amount than the purchase price of the quantity of product in respect of which 

damages are claimed. In no event shall seller be liable for incidental or 

consequential damages, whether buyer's claim is based on contract, breach of 

warranty, negligence or otherwise.

HESI101652
Norton Proppants, Inc.

http://www.nortonproppants.com/06_products/06_05_versaprop.htm (4 of 4)1/12/2004 4:17:08 AM

ISSUE DATE: 1-MARCH-00 

*patent pending

Valuprop | Naplite | Interprop | Sintered Bauxite | Versaprop

 

HESI101653
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: VICON FB

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: VICON FB

Synonyms: None

Chemical Family: Inorganic

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium bromate 7789-38-0 10 - 30% Not applicable Not applicable

Sodium chloride 7647-14-5 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Repeated overexposure may cause liver and kidney effects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Remove contaminated shoes and discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

VICON FB

Page 1 of 5

HESI101654
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. If allowed to dry, this product is an

oxidizer.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Do not allow product to dry. Dry

material is an oxidizer.

Storage Information Store away from acids. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Odorless

pH: Not Determined

VICON FB

Page 2 of 5

HESI101655
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.2

Density @ 20 C (lbs./gallon): 10

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Reactive metals such as aluminum and magnesium. Bromine

trifluoride.

Hazardous Decomposition

Products

Oxygen. Bromine. Sodium oxides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

VICON FB

Page 3 of 5

HESI101656
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

VICON FB

Page 4 of 5

HESI101657
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

VICON FB

Page 5 of 5

HESI101658
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: VICON NF BREAKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: VICON NF BREAKER

Synonyms: None

Chemical Family: Blend

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Chlorous acid, sodium salt 7758-19-2 5 - 10% Not applicable Not applicable

Sodium chloride 7647-14-5 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Chlorine dioxide vapors are emitted when this product contacts acids or chlorine. If

these vapors are inhaled, monitor patient for delayed development of pulmonary

edema, which may occur up to 48-72 hours post inhalation. Following ingestion,

neutralization and use of activated charcoal is not indicated.

VICON NF BREAKER

Page 1 of 6

HESI101659
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Product is not expected to burn unless all the water is boiled away. Use water spray

to cool fire exposed surfaces. Decomposition in fire may produce toxic gases. If

allowed to dry, this product is an oxidizer.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 1

HMIS Ratings: Health 2, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from reducing agents. Store away from direct

sunlight. Keep from excessive heat. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor/acid gas/chlorine respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear tan

VICON NF BREAKER

Page 2 of 6

HESI101660
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Mild chlorine

pH: 12 - 13

Specific Gravity @ 20 C (Water=1): 1.205

Density @ 20 C (lbs./gallon): 10.04

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 223-226

Boiling Point/Range (C): 106-108

Freezing Point/Range (F): 37- 39

Freezing Point/Range (C): 3-4

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with organic materials. Avoid

friction.

Incompatibility (Materials to

Avoid)

Prolonged contact with aluminum. Contact with metals. Organic matter. Contact with

ammonia. All flammables, especially petroleum products, asphalt & other volatile

flammables. Ammonium compounds. Strong acids.

Hazardous Decomposition

Products

Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Blood disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause damage to the thyroid gland. Prolonged

or repeated exposure may cause adverse effects on the blood.

Other Information None known.

Toxicity Tests

VICON NF BREAKER

Page 3 of 6

HESI101661
Oral Toxicity: LD50: 350 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 290 mg/l (Oncorhynchus mykiss) TLM96: 208 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:TLM96: 0.29 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1908,Chlorite Solution(14% Available Chlorine), 8, III

NAERG 154

Canadian TDG

Chlorite Solution(14% Available Chlorine), 8, UN1908, III

ADR

UN1908,Chlorite Solution(14% Available Chlorine), 8, III

Air Transportation

VICON NF BREAKER

Page 4 of 6

HESI101662
ICAO/IATA

UN1908,Chlorite Solution, 8, III

(14% Available Chlorine)

Sea Transportation

IMDG

UN1908,Chlorite Solution(14% Available Chlorine), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

VICON NF BREAKER

Page 5 of 6

HESI101663
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

VICON NF BREAKER

Page 6 of 6

HESI101664
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WAC-9 ADDITIVE

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WAC-9 ADDITIVE

Synonyms: None

Chemical Family: Sand

Application: Fluid Loss Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

WAC-9 ADDITIVE

Page 1 of 7

HESI101665
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Treat symptomatically.

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Do not reuse empty container.

WAC-9 ADDITIVE

Page 2 of 7

HESI101666
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 72

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.09

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

WAC-9 ADDITIVE

Page 3 of 7

HESI101667
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause mechanical skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

WAC-9 ADDITIVE

Page 4 of 7

HESI101668
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

WAC-9 ADDITIVE

Page 5 of 7

HESI101669
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WAC-9 ADDITIVE

Page 6 of 7

HESI101670
WAC-9 ADDITIVE

Page 7 of 7

HESI101671
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-11 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-11 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-11 GELLING AGENT

Page 1 of 6

HESI101672
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): 950

Autoignition Temperature (C): 510

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.29

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

WG-11 GELLING AGENT

Page 2 of 6

HESI101673
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White to light straw

Odor: Bean

pH: 10.1

Specific Gravity @ 20 C (Water=1): 1.3

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 36

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 9400 mg/kg (Rat)

WG-11 GELLING AGENT

Page 3 of 6

HESI101674
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

WG-11 GELLING AGENT

Page 4 of 6

HESI101675
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

WG-11 GELLING AGENT

Page 5 of 6

HESI101676
***END OF MSDS***

WG-11 GELLING AGENT

Page 6 of 6

HESI101677
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-17 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-17 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cellulose derivative 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-17 GELLING AGENT

Page 1 of 6

HESI101678
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 752

Autoignition Temperature (C): 400

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

WG-17 GELLING AGENT

Page 2 of 6

HESI101679
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White

Odor: Characteristic

pH: 7

Specific Gravity @ 20 C (Water=1): 1.36

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 32.1

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: <5

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 1,000,000

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

WG-17 GELLING AGENT

Page 3 of 6

HESI101680
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

WG-17 GELLING AGENT

Page 4 of 6

HESI101681
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

WG-17 GELLING AGENT

Page 5 of 6

HESI101682
***END OF MSDS***

WG-17 GELLING AGENT

Page 6 of 6

HESI101683
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-18 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-18 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-18 GELLING AGENT

Page 1 of 5

HESI101684
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): 932

Autoignition Temperature (C): 500

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Slippery when wet. Avoid contact with eyes, skin, or clothing. Avoid creating or

inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

WG-18 GELLING AGENT

Page 2 of 5

HESI101685
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bland

pH: 9-10

Specific Gravity @ 20 C (Water=1): 1.3

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 35-45

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

WG-18 GELLING AGENT

Page 3 of 5

HESI101686
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WG-18 GELLING AGENT

Page 4 of 5

HESI101687
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-18 GELLING AGENT

Page 5 of 5

HESI101688
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-19 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-19 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

Monoethanolamine 141-43-5 < 1.5 3 ppm 3 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-19 GELLING AGENT

Page 1 of 5

HESI101689
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 430

Autoignition Temperature (C): 221

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.8

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

WG-19 GELLING AGENT

Page 2 of 5

HESI101690
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bean

pH: 8.5

Specific Gravity @ 20 C (Water=1): 1.3

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 36

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7060 mg/kg (Rat)

Dermal Toxicity: Not determined

WG-19 GELLING AGENT

Page 3 of 5

HESI101691
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 268,300 ppm COD: 1,500,000 ppm Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WG-19 GELLING AGENT

Page 4 of 5

HESI101692
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-19 GELLING AGENT

Page 5 of 5

HESI101693
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-24 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-24 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Xanthan gum 11138-66-2 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-24 GELLING AGENT

Page 1 of 5

HESI101694
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 400

Autoignition Temperature (C): 204

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Slippery when wet. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 12

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to tan

WG-24 GELLING AGENT

Page 2 of 5

HESI101695
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Slight

pH: 6-8.5

Specific Gravity @ 20 C (Water=1): 0.8

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 50

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 1,000,000

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May impede respiration.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

WG-24 GELLING AGENT

Page 3 of 5

HESI101696
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 200 mg/g COD: 1600 mg/g

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 75000 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WG-24 GELLING AGENT

Page 4 of 5

HESI101697
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-24 GELLING AGENT

Page 5 of 5

HESI101698
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-31 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-31 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-31 GELLING AGENT

Page 1 of 6

HESI101699
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust. Slippery

when wet.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust. Slippery when wet.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

WG-31 GELLING AGENT

Page 2 of 6

HESI101700
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Off white

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.47

Density @ 20 C (lbs./gallon): 12.27

Bulk Density @ 20 C (lbs/ft3): 91.77

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

WG-31 GELLING AGENT

Page 3 of 6

HESI101701
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

WG-31 GELLING AGENT

Page 4 of 6

HESI101702
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

WG-31 GELLING AGENT

Page 5 of 6

HESI101703
***END OF MSDS***

WG-31 GELLING AGENT

Page 6 of 6

HESI101704
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-35 GELLING AGENT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-35 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-35 GELLING AGENT

Page 1 of 5

HESI101705
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

WG-35 GELLING AGENT

Page 2 of 5

HESI101706
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bean

pH: 6.5-7.5

Specific Gravity @ 20 C (Water=1): 1.42 -1.47

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 29

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WG-35 GELLING AGENT

Page 3 of 5

HESI101707
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

WG-35 GELLING AGENT

Page 4 of 5

HESI101708
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-35 GELLING AGENT

Page 5 of 5

HESI101709
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-36 GELLING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-36 GELLING AGENT

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-36 GELLING AGENT

Page 1 of 5

HESI101710
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

WG-36 GELLING AGENT

Page 2 of 5

HESI101711
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bean

pH: 6.5-7.5

Specific Gravity @ 20 C (Water=1): 1.42 -1.47

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WG-36 GELLING AGENT

Page 3 of 5

HESI101712
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WG-36 GELLING AGENT

Page 4 of 5

HESI101713
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-36 GELLING AGENT

Page 5 of 5

HESI101714
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WG-37

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WG-37

Synonyms: None

Chemical Family: Polysaccharide

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Xanthan gum 11138-66-2 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WG-37

Page 1 of 6

HESI101715
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 400

Autoignition Temperature (C): 204

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust. Slippery

when wet.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust. Slippery when wet. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool, dry location. Keep from heat, sparks, and

open flames. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

WG-37

Page 2 of 6

HESI101716
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to tan

Odor: Slight

pH: 5.5-8.6 (1%)

Specific Gravity @ 20 C (Water=1): 1.6

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 50

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 1,000,000

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May impede respiration.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

WG-37

Page 3 of 6

HESI101717
Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: LC50: > 21 mg/l (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 200 mg/g COD: 1600 mg/g

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 320-560 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM96: > 75000 ppm (Mysidopsis bahia) LC50: 980 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

WG-37

Page 4 of 6

HESI101718
Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

WG-37

Page 5 of 6

HESI101719
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WG-37

Page 6 of 6

HESI101720
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WLC-4 FLUID LOSS ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WLC-4 FLUID LOSS ADDITIVE

Synonyms: None

Chemical Family: Polysaccharide

Application: Fluid Loss Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Complex carbohydrate 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WLC-4 FLUID LOSS ADDITIVE

Page 1 of 5

HESI101721
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust. Avoid dust accumulations.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Starch

WLC-4 FLUID LOSS ADDITIVE

Page 2 of 5

HESI101722
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 7.1

Specific Gravity @ 20 C (Water=1): 0.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 31.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact None known.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WLC-4 FLUID LOSS ADDITIVE

Page 3 of 5

HESI101723
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WLC-4 FLUID LOSS ADDITIVE

Page 4 of 5

HESI101724
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WLC-4 FLUID LOSS ADDITIVE

Page 5 of 5

HESI101725
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WLC-5 FLUID LOSS ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WLC-5 FLUID LOSS ADDITIVE

Synonyms: None

Chemical Family: Polysaccharide

Application: Fluid Loss Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Complex carbohydrate 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WLC-5 FLUID LOSS ADDITIVE

Page 1 of 5

HESI101726
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust. Avoid dust accumulations.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Starch

WLC-5 FLUID LOSS ADDITIVE

Page 2 of 5

HESI101727
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 7.1

Specific Gravity @ 20 C (Water=1): 0.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 31.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact None known.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WLC-5 FLUID LOSS ADDITIVE

Page 3 of 5

HESI101728
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WLC-5 FLUID LOSS ADDITIVE

Page 4 of 5

HESI101729
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WLC-5 FLUID LOSS ADDITIVE

Page 5 of 5

HESI101730
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WLC-6 FLUID LOSS ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WLC-6 FLUID LOSS ADDITIVE

Synonyms: None

Chemical Family: Fatty-Acid

Application: Fluid Loss Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Tallow soap 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WLC-6 FLUID LOSS ADDITIVE

Page 1 of 5

HESI101731
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Keep from excessive heat.

Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Amber

WLC-6 FLUID LOSS ADDITIVE

Page 2 of 5

HESI101732
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Slightly soapy

pH: Not Determined

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WLC-6 FLUID LOSS ADDITIVE

Page 3 of 5

HESI101733
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WLC-6 FLUID LOSS ADDITIVE

Page 4 of 5

HESI101734
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WLC-6 FLUID LOSS ADDITIVE

Page 5 of 5

HESI101735
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WLC-7 FLUID LOSS ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WLC-7 FLUID LOSS ADDITIVE

Synonyms: None

Chemical Family: Fatty-Acid

Application: Fluid Loss Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Tallow soap 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

WLC-7 FLUID LOSS ADDITIVE

Page 1 of 5

HESI101736
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Keep from excessive heat.

Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Amber

WLC-7 FLUID LOSS ADDITIVE

Page 2 of 5

HESI101737
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Slightly soapy

pH: 9-10.5

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

WLC-7 FLUID LOSS ADDITIVE

Page 3 of 5

HESI101738
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

WLC-7 FLUID LOSS ADDITIVE

Page 4 of 5

HESI101739
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WLC-7 FLUID LOSS ADDITIVE

Page 5 of 5

HESI101740
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: WS-36 EMULSIFYING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: WS-36 EMULSIFYING AGENT

Synonyms: None

Chemical Family: Fatty-Acid

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated sorbitol esters 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

WS-36 EMULSIFYING AGENT

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HESI101741
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Mineral oil

pH: Not Determined

WS-36 EMULSIFYING AGENT

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HESI101742
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of phosphorus. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

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HESI101743
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

WS-36 EMULSIFYING AGENT

Page 4 of 6

HESI101744
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

WS-36 EMULSIFYING AGENT

Page 5 of 6

HESI101745
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

WS-36 EMULSIFYING AGENT

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HESI101746
MATERIAL SAFETY DATA SHEET 

PRODUCT NAME - X-CIDE 600 INDUSTRIAL 

BACTERICIDE 

MANUFACTURER - BAKER PETROLITE 

BAKER HUGHES 

BAKER PETROLITE 

MATERIAL SAFETY DATA SHEET 

------SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----

- 

PRODUCT NAME: X-CIDE® 600 INDUSTRIAL BACTERICIDE 

CODE: XC600 

VERSION: 4.0 

SUPPLIER:

BAKER PETROLITE 

A BAKER HUGHES COMPANY 

12645 W. AIRPORT BLVD. (77478) 

P.O. BOX 5050 

SUGAR LAND, TX 77487-5050 

FOR PRODUCT INFORMATION/MSDSS CALL: 800-231-3606 

(8:00 A.M. - 5:00 P.M. CST, MONDAY - FRIDAY) 281-276-5400 

MATERIAL USES: INDUSTRIAL BACTERICIDE. 

24 HOUR EMERGENCY NUMBERS:

CHEMTREC: 800-424-9300 (U.S. 24 HOUR) 

BAKER PETROLITE:

800-231-3606 

(001)281-276-5400 

CANUTEC: 613-996-6666 (CANADA 24 HOURS) 

CHEMTREC INT'L: 01-703-527-3887 (INTERNATIONAL 24 HOUR) 

EFFECTIVE DATE: 4/4/2006 

PRINT DATE: 4/4/2006 

® A TRADEMARK OF BAKER HUGHES, INC. 

NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):

HEALTH 3 

FLAMMABILITY 1 

INSTABILITY 2 

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SPECIFIC HAZARD 

------SECTION 2. HAZARDS IDENTIFICATION ------

PHYSICAL STATE AND APPEARANCE:

STATE: POWDER. SOLID. 

COLOR: WHITE. 

ODOR: CHARACTERISTIC. 

CERCLA REPORTABLE QUANTITY: NOT APPLICABLE. 

HAZARD SUMMARY:

DANGER. MAY CAUSE CHRONIC EFFECTS. FLAMMABLE SOLID. MAY BE IRRITATING TO 

EYES, SKIN AND RESPIRATORY TRACT. MAY CAUSE SKIN SENSITIZATION (ALLERGIC 

REACTION). 

ROUTES OF EXPOSURE: SKIN (CONTACT), EYES, INHALATION. 

POTENTIAL ACUTE HEALTH EFFECTS:

EYES:

MAY BE CORROSIVE TO THE EYES. MAY CAUSE EYE BURNS AND PERMANENT EYE INJURY. 

SKIN:

MAY BE SEVERELY IRRITATING TO THE SKIN. MAY CAUSE BURNS ON PROLONGED CONTACT. 

SKIN SENSITIZER. MAY CAUSE ALLERGIC SKIN REACTIONS WITH REPEATED EXPOSURE. 

INHALATION: MAY BE SEVERELY IRRITATING TO THE LUNGS. 

INGESTION:

NOT CONSIDERED A LIKELY ROUTE OF EXPOSURE, HOWEVER, MAY BE CORROSIVE IF 

SWALLOWED. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

EXPOSURE TO THIS PRODUCT MAY AGGRAVATE MEDICAL CONDITIONS INVOLVING THE 

FOLLOWING: GASTROINTESTINAL TRACT, RESPIRATORY TRACT, SKIN/EPITHELIUM, EYES. 

SEE TOXICOLOGICAL INFORMATION (SECTION 11) 

ADDITIONAL HAZARD IDENTIFICATION REMARKS:

REPEATED OR PROLONGED CONTACT MAY CAUSE DERMATITIS (INFLAMMATION) AND 

DEFATTING OF THE SKIN (DRYNESS). 

------SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS ------

NAME CAS # % BY WEIGHT 

2-BROMO-2-NITROPROPANE-1,3-DIOL 52-51-7 60-100 

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HESI101748
SEE SECTION 8 FOR INFORMATION ON PERMISSIBLE EXPOSURE LIMITS AND THRESHOLD 

LIMIT VALUES. 

------SECTION 4. FIRST AID MEASURES ------ 

EYE CONTACT:

IMMEDIATELY FLUSH THE EYE(S) CONTINUOUSLY WITH LUKEWARM, GENTLY FLOWING WATER 

FOR AT LEAST 20-60 MINUTES WHILE HOLDING THE EYELID(S) OPEN. GET MEDICAL 

ATTENTION IMMEDIATELY. 

SKIN CONTACT:

REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH 

SOAP AND MILD DETERGENT AND LARGE AMOUNTS OF LUKEWARM, GENTLY FLOWING WATER 

UNTIL NO EVIDENCE OF CHEMICAL REMAINS (FOR AT LEAST 20-60 MINUTES). GET 

MEDICAL ATTENTION IF IRRITATION OCCURS. 

INHALATION:

REMOVE TO FRESH AIR. OXYGEN MAY BE ADMINISTERED IF BREATHING IS DIFFICULT. IF 

NOT BREATHING, ADMINISTER ARTIFICIAL RESPIRATION AND SEEK MEDICAL ATTENTION. 

GET MEDICAL ATTENTION IF SYMPTOMS APPEAR. 

INGESTION:

GET MEDICAL ATTENTION IMMEDIATELY. IF SWALLOWED, DO NOT INDUCE VOMITING 

UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. WASH OUT MOUTH WITH WATER IF 

PERSON IS CONSCIOUS. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A 

VICTIM WHO IS UNCONSCIOUS OR HAVING CONVULSIONS. 

NOTES TO PHYSICIAN: NOT AVAILABLE. 

ADDITIONAL FIRST AID REMARKS: NOT AVAILABLE. 

------SECTION 5. FIRE FIGHTING MEASURES ------ 

FLAMMABILITY OF THE PRODUCT:

FLAMMABLE SOLID. MAY BE IGNITED BY FRICTION, SPARK OR FLAME. 

OSHA FLAMMABILITY CLASS: IIIB 

PRODUCTS OF COMBUSTION:

THESE PRODUCTS ARE NITROGEN OXIDES (NO, NO2 ETC.) CARBON OXIDES (CO, CO2) 

HYDROGEN BROMIDE. BROMINE. FORMALDEHYDE. 

FIRE HAZARDS IN PRESENCE OF VARIOUS SUBSTANCES:

OPEN FLAMES/SPARKS/STATIC. HEAT. 

FIRE FIGHTING MEDIA AND INSTRUCTIONS:

IN CASE OF FIRE, USE FOAM, DRY CHEMICALS, OR CO2 FIRE EXTINGUISHERS. EVACUATE 

AREA AND FIGHT FIRE FROM A SAFE DISTANCE. WATER SPRAY MAY BE USED TO KEEP 

FIRE-EXPOSED CONTAINERS COOL. KEEP WATER RUN OFF OUT OF SEWERS AND PUBLIC 

WATERWAYS. 

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PROTECTIVE CLOTHING (FIRE):

DO NOT ENTER FIRE AREA WITHOUT PROPER PERSONAL PROTECTIVE EQUIPMENT, 

INCLUDING NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. 

SPECIAL REMARKS ON FIRE HAZARDS:

AS WITH MOST SOLID PARTICULATE ORGANIC MATERIALS, HIGH CONCENTRATIONS OF 

DUSTS FROM THIS PRODUCT SUSPENDED IN AIR ARE AN EXPLOSION HAZARD IN THE 

PRESENCE OF SPARKS, FLAMES, AND HEAT. DO NOT ALLOW DUST TO ACCUMULATE ON 

EQUIPMENT AND SURFACES WHERE THIS PRODUCT IS USED. IN THE NATIONAL FIRE 

PROTECTION ASSOCIATION (NFPA) CODE 499, A "COMBUSTIBLE DUST" IS ANY FINELY 

DIVIDED SOLID MATERIAL 420 MICRONS OR LESS IN DIAMETER THAT PRESENTS A FIRE 

OR EXPLOSION HAZARD WHEN DISPERSED IN AIR. 

------SECTION 6. ACCIDENTAL RELEASE MEASURES ------ 

SPILL:

PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. EVACUATE SURROUNDING AREAS, 

IF NECESSARY. VACUUM OR CAREFULLY SCOOP UP SPILLED MATERIALS AND PLACE IN AN 

APPROPRIATE CONTAINER FOR DISPOSAL. WASTE MUST BE DISPOSED OF IN ACCORDANCE 

WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. 

OTHER STATEMENTS: NOT APPLICABLE. 

ADDITIONAL ACCIDENTAL RELEASE MEASURES REMARKS: NOT AVAILABLE. 

------SECTION 7. HANDLING AND STORAGE ------ 

HANDLING AND STORAGE:

PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH EYES, 

SKIN, AND CLOTHING. AVOID BREATHING VAPORS OR DUSTS. USE ONLY WITH ADEQUATE 

VENTILATION. STORE IN A DRY, COOL AND WELL VENTILATED AREA. KEEP AWAY FROM 

INCOMPATIBLES. KEEP CONTAINER TIGHTLY CLOSED AND DRY. 

ADDITIONAL HANDLING AND STORAGE REMARKS: NOT AVAILABLE. 

------SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ------

EXPOSURE LIMITS:

2-BROMO-2-NITROPROPANE-1,3-DIOL: NOT AVAILABLE. 

ADDITIONAL INFORMATION ON EXPOSURE LIMITS: NOT AVAILABLE. 

ENGINEERING CONTROLS:

PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE 

AIRBORNE CONCENTRATIONS OF VAPORS OR PARTICLES BELOW THEIR RESPECTIVE 

THRESHOLD LIMIT VALUE. ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE 

PROXIMAL TO THE WORK-STATION LOCATION. 

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PERSONAL PROTECTION:

PERSONAL PROTECTIVE EQUIPMENT RECOMMENDATIONS ARE BASED ON ANTICIPATED KNOWN 

MANUFACTURING AND USE CONDITIONS. THESE CONDITIONS ARE EXPECTED TO RESULT IN 

ONLY INCIDENTAL EXPOSURE. A THOROUGH REVIEW OF THE JOB TASKS AND CONDITIONS 

BY A SAFETY PROFESSIONAL IS RECOMMENDED, HOWEVER, TO DETERMINE THE LEVEL OF 

PERSONAL PROTECTIVE EQUIPMENT APPROPRIATE FOR THESE JOB TASKS AND CONDITIONS. 

EYES: CHEMICAL SAFETY GOGGLES. 

BODY: WEAR LONG SLEEVES TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. 

RESPIRATORY:

RESPIRATOR USE IS NOT EXPECTED TO BE NECESSARY UNDER NORMAL CONDITIONS OF 

USE. IN POORLY VENTILATED AREAS OR IN EMERGENCY SITUATIONS, USE NIOSH 

APPROVED FULL FACE RESPIRATOR. 

HANDS: CHEMICAL RESISTANT GLOVES. NITRILE OR NEOPRENE GLOVES. PVC GLOVES. 

FEET: CHEMICAL RESISTANT BOOTS OR OVERSHOES. 

OTHER INFORMATION: NOT AVAILABLE. 

ADDITIONAL EXPOSURE CONTROL REMARKS: NOT AVAILABLE. 

------SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES ------ 

PHYSICAL STATE AND APPEARANCE: POWDER. SOLID. 

ODOR: CHARACTERISTIC. 

COLOR: WHITE. 

pH: 5-7 (10 G/L) 

SPECIFIC GRAVITY: NOT APPLICABLE. 

DENSITY: NOT APPLICABLE. 

FLASH POINTS:

CLOSED CUP: >93.4 DEG. C (200 DEG. F). (SFCC) 

FLAMMABLE LIMITS:

L.E.L.: NOT AVAILABLE. 

U.E.L.: NOT AVAILABLE. 

AUTOIGNITION TEMPERATURE: NOT AVAILABLE. 

INITIAL BOILING POINT: NOT AVAILABLE. 

BOILING POINT: DECOMPOSES AT >130 DEG. C (>266 DEG. F) 

VAPOR DENSITY: >1 (AIR=1) 

VAPOR PRESSURE: 0.0005 - MM HG @ 42 DEG. C (108 DEG. F) 

EVAPORATION RATE: NOT AVAILABLE OR NOT APPLICABLE FOR SOLIDS. 

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HESI101751
VOC: NOT AVAILABLE. 

VISCOSITY: NOT AVAILABLE. 

POUR POINT: 130 DEG. C (266 DEG. F) FREEZING POINT 

SOLUBILITY (WATER): SOLUBLE 

PHYSICAL CHEMICAL COMMENTS:

BULK DENSITY: 1.1 G/CC 

------SECTION 10. STABILITY AND REACTIVITY ------

STABILITY AND REACTIVITY: THE PRODUCT IS STABLE. 

CONDITIONS OF INSTABILITY: NOT AVAILABLE. 

INCOMPATIBILITY WITH VARIOUS SUBSTANCES:

OXIDIZING MATERIAL. METAL. ACID. ALKALI. 

HAZARDOUS DECOMPOSITION PRODUCTS: NOT APPLICABLE. 

HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION IS NOT EXPECTED TO OCCUR. 

SPECIAL STABILITY & REACTIVITY REMARKS:

INCOMPATIBLE WITH AMINES. PRODUCT CAN REACT WITH BASES TO GENERATE FLAMMABLE 

FORMALDEHYDE GAS. 

------SECTION 11. TOXICOLOGICAL INFORMATION ------

COMPONENT TOXICOLOGICAL INFORMATION:

ACUTE ANIMAL TOXICITY:

2-BROMO-2-NITROPROPANE-1,3-DIOL:

ORAL (LD50):

ACUTE:

180 MG/KG (RAT). 

270 MG/KG (MOUSE). 

DERMAL (LD50):

ACUTE:

64 TO 160 MG/KG (RAT). 

4750 MG/KG (MOUSE). 

CHRONIC TOXICITY DATA:

1) 2-BROMO-2-NITROPROPANE-1,3-DIOL:

1,3-PROPANEDIOL, 2-BROMO-2-NITRO-, IS A COMPONENT OF THIS PRODUCT. DAILY FOR 

90-DAYS, ORAL DOSES OF 20 MG/KG ADMINISTRERED TO MALE AND FEMALE RATS WERE 

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WELL TOLERATED. DOSES OF 80 AND 160 MG/KG CASED GASTROINTESTINAL LESIONS, 

RESPIRATORY DISTRESS, AND SOME DEATHS. 

PRODUCT TOXICOLOGICAL INFORMATION:

ACUTE ANIMAL TOXICITY:

ORAL (LD50):

ACUTE:

254 MG/KG (RAT). 

180 TO 400 MG/KG (FEMALE RAT). 

DERMAL (LD50):

ACUTE:

1600 MG/KG (RAT). 

64 TO 160 MG/KG (RAT). 

TARGET ORGANS:

GASTROINTESTINAL TRACT, RESPIRATORY TRACT, SKIN/EPITHELIUM, EYES. 

OTHER ADVERSE EFFECTS: NOT AVAILABLE. 

------SECTION 12. ECOLOGICAL INFORMATION ------ 

ECOTOXICITY: X-CIDE® 600 INDUSTRIAL BACTERICIDE 

DAPHNIA MAGNA (EC50): 48 HOUR/HOURS 1.4 MG/L 

RAINBOW TROUT (LC50): 96 HOUR/HOURS 41.2 MG/L 

BOD5 AND COD: NOT AVAILABLE. 

BIODEGRADABLE/OECD: NOT AVAILABLE. 

TOXICITY OF THE PRODUCTS OF BIODEGRADATION: NOT AVAILABLE. 

SPECIAL REMARKS:

THIS PESTICIDE IS TOXIC TO FISH AND AQUATIC ORGANISMS. DO NOT DISCHARGE 

EFFLUENT CONTAINING THIS PRODUCT INTO LAKES, STEAMS, PONDS OR ESTUARIES, 

OCEANS OR OTHER WATERS UNLESS IN ACCORDANCE WITH THE REQUIREMENTS OF A 

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) PERMIT AND THE 

PERMITTING AUTHORITY HAS BEEN NOTIFIED IN WRITING PRIOR TO DISCHARGE. DO NOT 

DISCHARGE EFFLUENT CONTAINING THIS PRODUCT TO SEWER SYSTEMS WITHOUT 

PREVIOUSLY NOTIFYING THE LOCAL SEWAGE TREATMENT PLANT AUTHORITY. FOR GUIDANCE 

CONTACT YOUR STATE WATER BOARD OR REGIONAL OFFICE OF THE EPA. 

------SECTION 13. DISPOSAL CONSIDERATIONS ------

RESPONSIBILITY FOR PROPER WASTE DISPOSAL RESTS WITH THE GENERATOR OF THE 

WASTE. DISPOSE OF ANY WASTE MATERIAL IN ACCORDANCE WITH ALL APPLICABLE 

FEDERAL, STATE AND LOCAL REGULATIONS. NOTE THAT THESE REGULATIONS MAY ALSO 

APPLY TO EMPTY CONTAINERS, LINERS AND RINSATE. PROCESSING, USE, DILUTION OR 

CONTAMINATION OF THIS PRODUCT MAY CAUSE ITS PHYSICAL AND CHEMICAL PROPERTIES 

TO CHANGE. 

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ADDITIONAL WASTE REMARKS: NOT AVAILABLE. 

------SECTION 14. TRANSPORT INFORMATION ------ 

DOT CLASSIFICATION: 2-BROMO-2-NITROPROPANE-1,3-DIOL, 4.1, UN3241, III 

FLAMMABLE SOLID, CLASS/DIVISION 4.1 

DOT REPORTABLE QUANTITY: NOT APPLICABLE. 

MARINE POLLUTANT: NOT APPLICABLE. 

ADDITIONAL DOT INFORMATION:

THIS MATERIAL MUST BE PACKED ACCORDING TO PACKING METHOD OP6. IT MUST BE 

PROTECTED FROM DIRECT SUNSHINE AND HEAT. 

EMERGENCY RESPONSE GUIDE PAGE NUMBER: 133 

------SECTION 15. REGULATORY INFORMATION ------

HCS CLASSIFICATION: TARGET ORGAN EFFECTS. FLAMMABLE SOLID. IRRITANT. TOXIC. 

U.S. FEDERAL REGULATIONS:

ENVIRONMENTAL REGULATIONS:

EXTREMELY HAZARDOUS SUBSTANCES:

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

SARA 302/304 EMERGENCY PLANNING AND NOTIFICATION SUBSTANCES:

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

HAZARDOUS SUBSTANCES (CERCLA 302):

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

SARA 311/312 MSDS DISTRIBUTION - CHEMICAL INVENTORY - HAZARD IDENTIFICATION:

FIRE; REACTIVE; IMMEDIATE HEALTH HAZARD; DELAYED HEALTH HAZARD; 

CLEAN WATER ACT (CWA) 307 PRIORITY POLLUTANTS:

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

CLEAN WATER ACT (CWA) 311 HAZARDOUS SUBSTANCES:

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

CLEAN AIR ACT (CAA) 112(R) ACCIDENTAL RELEASE PREVENTION SUBSTANCES:

NOT APPLICABLE TO ANY COMPONENTS IN THIS PRODUCT. 

THRESHOLD PLANNING QUANTITY (TPQ): NOT APPLICABLE. 

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TSCA INVENTORY STATUS:

ALL COMPONENTS ARE INCLUDED OR ARE EXEMPTED FROM LISTING ON THE US TOXIC 

SUBSTANCES CONTROL ACT INVENTORY. 

THIS PRODUCT DOES NOT CONTAIN ANY COMPONENTS THAT ARE SUBJECT TO THE 

REPORTING REQUIREMENTS OF TSCA SECTION 12(B) IF EXPORTED FROM THE UNITED 

STATES. 

STATE REGULATIONS:

STATE SPECIFIC INFORMATION IS AVAILABLE UPON REQUEST FROM BAKER PETROLITE. 

INTERNATIONAL REGULATIONS:

CANADA:

ALL COMPONENTS ARE COMPLIANT WITH OR ARE EXEMPTED FROM LISTING ON THE 

CANADIAN DOMESTIC SUBSTANCE LIST. 

WHMIS (CANADA): B-4, D-1B, D-2B 

EUROPEAN UNION:

ALL COMPONENTS ARE INCLUDED OR ARE EXEMPTED FROM LISTING ON THE EUROPEAN 

INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES OR THE EUROPEAN LIST OF 

NOTIFIED CHEMICAL SUBSTANCES. 

INTERNATIONAL INVENTORY STATUS INFORMATION IS AVAILABLE UPON REQUEST FROM 

BAKER PETROLITE FOR THE FOLLOWING COUNTRIES:

AUSTRALIA, CHINA, KOREA (TCCL), PHILIPPINES (RA6969), OR JAPAN. 

OTHER REGULATORY INFORMATION:

THIS PRODUCT IS SUBJECT TO REGULATION UNDER THE US FEDERAL INSECTICIDE, 

FUNGICIDE AND RODENTICIDE ACT (FIFRA) AND IS THEREFORE EXEMPT FROM US TOXIC 

SUBSTANCE CONTROL ACT (TSCA) INVENTORY LISTING REQUIREMENTS. EPA REGISTRATION 

NO. 10707-53 

------SECTION 16. OTHER INFORMATION ------

OTHER SPECIAL CONSIDERATIONS:

FILE 944 

09/03/03 - CHANGES TO SECTIONS 5, 8, 10 AND 15. 

03/25/04 - CHANGE TO SECTION 14. 

09/15/05 - CHANGES TO SECTIONS 1, 2, 3, 5, 8, 9, 11, 14 AND 15. 

4/4/06 CHANGES TO SECTIONS 2, 5, 9, 10, 11, AND 12 

IN APRIL, 2005, A NUMBER OF FORMAT CHANGES WERE MADE. THE MOST NOTABLE OF 

THESE WERE SWITCHING SECTIONS 2 AND 3, MOVING THE EXPOSURE LIMITS TO SECTION 

8, AND MOVING THE FLASH POINT FROM SECTION 5 TO SECTION 9. 

BAKER PETROLITE DISCLAIMER:

NOTE:

THE INFORMATION ON THIS MSDS IS BASED ON DATA WHICH IS CONSIDERED TO BE 

ACCURATE. BAKER PETROLITE, HOWEVER, MAKES NO GUARANTEES OR WARRANTY, EITHER 

EXPRESSED OR IMPLIED OF THE ACCURACY OR COMPLETENESS OF THIS INFORMATION. 

THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE AND DISPOSAL OF THE 

Top of Document

Dolphin MSDS - X-CIDE 600 INDUSTRIAL BACTERICIDE - BAKER PETROLITE Page 9 of 10

file://C:\Documents and Settings\gvrz071\Local Settings\Temporary Internet Files\OLK8E... 9/25/2007

HESI101755
PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND 

OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM 

LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED 

WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT. 

THIS MSDS WAS PREPARED AND IS TO BE USED FOR THIS PRODUCT. IF THE PRODUCT IS 

USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE 

APPLICABLE. 

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MATERIAL SAFETY DATA SHEET

Product Trade Name: XL-1

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: XL-1

Synonyms: None

Chemical Family: Inorganic acid

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ferric chloride 7705-08-0 37-45 1 mg/m3 1 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause damage to internal organs.

May be fatal if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician If ingested, a stomach wash followed by saline catharsis and cenodyne is

recommended.

XL-1

Page 1 of 6

HESI101757
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool, dry location.

Keep from excessive heat. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls A well ventilated area to control dust levels.

Respiratory Protection Acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber boots. Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Red brown

Odor: Mild acidic

pH: < 1

XL-1

Page 2 of 6

HESI101758
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.43

Density @ 20 C (lbs./gallon): 11.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 230

Boiling Point/Range (C): 110

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong alkalis. Contact with metals. Concrete.

Hazardous Decomposition

Products

Hydrogen chloride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns. May cause permanent eye

damage. May cause eye tissue discoloration.

Ingestion May be fatal if swallowed. May cause abdominal pain, vomiting, nausea, and

diarrhea. May cause liver and kidney damage. May affect the blood and blood

system. Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Lung disorders. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and blood effects.

Prolonged or repeated exposure may cause lung damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

XL-1

Page 3 of 6

HESI101759
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2582,Ferric Chloride Solution, 8, III

NAERG 154

Canadian TDG

Ferric Chloride Solution, 8, UN2582, III

ADR

UN2582,Ferric Chloride Solution, 8, III

Air Transportation

ICAO/IATA

XL-1

Page 4 of 6

HESI101760
UN2582,Ferric Chloride Solution, 8, III

Sea Transportation

IMDG

UN2582,Ferric Chloride Solution, 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 210 Gallons based on Ferric chloride (CAS: 7705-

08-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

XL-1

Page 5 of 6

HESI101761
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

XL-1

Page 6 of 6

HESI101762
HESI101763
HESI101764
HESI101765
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HESI101767
HESI101768
HESI101769
HESI101770
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1/8

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: XRTTM CeramaxTM E, all sizes 

1. Chemical Product and Company Identification 

DESCRIPTION: XRTTM CeramaxTM E, all sizes 

PRODUCT CODE: 346961GEN 

PRODUCT TYPE: Resin-coated ceramic proppant 

APPLICATION: Oil/Gas well proppant 

SOLD UNDER BORDEN U.S. PATENT NUMBERS 4,694,905, 

4,722,991, 6,528,157 & PATENTS PENDING 

Manufacturer/Supplier Information 

MSDS prepared by: 

Hexion Specialty Chemicals, Inc. 

Oilfield Technology Group 

15115 Park Row, Suite 160 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or 

delayed(*) health hazards. Risk of damage and effects depends upon duration and level of 

exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ 

AND UNDERSTAND THE MSDS. 

% by weight 

1302-93-8 Mullite 50.0 - 70.0 

7631-86-9 *Silica 10.0 - 30.0 

14464-46-1 *Cristobalite 10.0 - 30.0 

Any applicable Canadian trade secret numbers will be listed in Section 15.2.

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Gray to white free flowing granules 

Odor Odorless

CAUTION! 

This product is coated with a phenolic resin which may abrade during handling or mechanical 

conveyance generating organic dust. When handling or conveying in enclosed spaces, any 

abraded phenolic resin dust from this product can be combustible and may present a fire or 

explosion hazard when dispersed and ignited in air. 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

HESI101771
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May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

3.2 Potential Health Effects

Immediate Hazards 

INGESTION: Not expected to be harmful under normal conditions of use.

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and 

lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

7631-86-9 Silica

Can cause lung fibrosis. Pre-existing respiratory disorders may be aggravated by exposure. 

-- See Footnote 

14464-46-1 Cristobalite

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which 

may be invisible). Inhaled silica has been listed by NTP and classified by IARC as a human 

carcinogen.

Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis 

and/or pneumoconiosis) and/or other diseases which may lead to permanent disability and/or 

death. Silicosis is a form of disabling pulmonary fibrosis which can be progressive. Prolonged 

exposure to respirable silica may cause diminished lung capacity with shortness of breath 

during physical exertion and may cause fatigue, breathlessness, wheezing, cough, and 

sputum production. Preexisting respiratory disorders may be aggravated by exposure. 

Smoking may aggravate the effects of exposure and may increase the risk of developing 

respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is 

some evidence that breathing respirable crystalline silica or the disease silicosis is associated 

with an increased incidence of significant disease endpoints such as scleroderma (an immune 

system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney 

disease. Silicosis is also reported to increase the risk of tuberculosis. 

Footnote: As of the date of issuance of this document, this material has not been listed by 

NTP, classified by IARC nor regulated by OSHA as a carcinogen. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. If 

the individual is drowsy or unconscious, do not give anything by mouth. 

Immediately contact poison control center or hospital emergency room 

for advice on whether to induce vomiting or for any other additional 

treatment directions.

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INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

5. Fire Fighting Measures 

Flash point Not combustible (Fire Train Test, 49 CFR 

173, Appendix E) 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Not readily combustible.

In case of fire, water should be used to keep fire-exposed containers cool.

UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is coated with a phenolic resin. 

The phenolic resin surface may abrade during handling or mechanical conveyance. Such 

abrasion may allow dispersion of organic dust. When handling or conveying in enclosed 

spaces, any abraded phenolic resin dust from this product can be combustible and may 

present a fire or explosion hazard when dispersed and ignited in air.

6. Accidental Release Measures 

Gently sweep (scoop) up to avoid creating dust clouds and remove to a chemical disposal 

area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices 

include avoiding unnecessary exposure and removal of the material from eyes, skin and 

clothing. Wash thoroughly after handling. Always use appropriate Personal Protective 

Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

COMBUSTIBLE DUST HANDLING PROCEDURES: This product is coated with a phenolic 

resin. The phenolic resin surface may abrade during handling or mechanical conveyance. 

Such abrasion may allow dispersion of organic dust. Take precautionary measures, such as 

capturing dust at generation points, practicing good housekeeping, controlling sources of 

ignition (including static electricity), and grounding equipment, to minimize dust accumulation, 

airborne dust, and static discharges during handling and/or conveyance as instructed in NFPA 

Pamphlet No. 654, "Standard for the Prevention of Fire and Dust Explosions from the 

Manufacturing, Processing, and Handling of Combustible Particulate Solids," UK HSE 

Guidance HSG 103 or other national guidance on safe handling of combustible dusts. 

HESI101773
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7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient 

ventilation in volume and air flow patterns should be provided to keep air contaminant 

concentration levels below acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) 

approved respiratory protection equipment. Respirators should be selected based on the form 

and concentration of contaminants in air in accordance with OSHA laws and regulations or 

other applicable standards or guidelines, including ANSI standards regarding respiratory 

protection. Wear impervious gloves as required to prevent skin contact.

8.3 Exposure Guidelines 

1302-93-8 Mullite 

ACGIH TLV 8-hr TWA 10 mg/m3 inhalable particulate; Particles 

(Insoluble or Poorly Soluble) 

Not Otherwise Specified 

OSHA PEL 8-hr TWA 5 mg/m3 respirable particulate 

8-hr TWA 15 mg/m3 total dust 

VENDOR 

OEL 

8-hr TWA 2 mg/m3 (as Kaolin) 

7631-86-9 Silica 

ACGIH TLV 8-hr TWA 10 mg/m3 (as amorphous silica) 

OSHA PEL 8-hr TWA 80/(%SiO2) 

mg/m3

20 mppcf; (as amorphous 

silica) 

Remanded TWA 6 mg/m3 (as amorphous silica); 1989 

PEL remanded, but in effect 

in some states 

14464-46-1 Cristobalite 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction 

OSHA PEL 8-hr TWA 5/(%SiO2+

2) mg/m3

respirable dust; (as Quartz) 

8-hr TWA 15/(%SiO2

+2) mg/m3

total dust; (as Quartz) 

Remanded TWA 0.05 mg/m3 respirable dust; (as Quartz); 

1989 PEL remanded, but in 

effect in some states 

NIOSH 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline 

Silica 

HESI101774
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9. Physical and Chemical Properties 

Appearance Gray to white free flowing granules 

Odor Odorless

Odor threshold Not available 

Specific gravity 2.55 - 2.60 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Melting Point 2,037.8 - 3,315.6 °C (3,700.0 - 6,000.1 °F)

Solubility in water Negligible 

Octanol/water partition coefficient Not available 

Vapor pressure Not available 

Vapor density Not available 

Evaporation rate Not available 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities: 

Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, 

particulate matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

11. Toxicological Information 

See Section 3 Hazards Identification information.

1302-93-8 Mullite 

LC50: Not available

LD50: Not available

7631-86-9 Silica 

LC50: Not available

LD50: Oral-rat= 3,160 mg/kg (RTECS)

14464-46-1 Cristobalite 

LC50: Not available

LD50: Not available

12. Ecological Information 

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Test results on representative products: 

In accordance with OSPAR requirements (Oslo and Paris Commission for the protection of the 

marine environment of the North-East Atlantic), aquatic toxicity, bioaccumulation and 

biodegradation was conducted on the resin coated proppant as well as its components. The 

resin coated product cannot be considered to bioaccumulate and is not readily biodegradable 

in the marine environment. The algae, crustacean, fish and sediment tests conducted on a 

similar product resulted in a non harmful classification according to the EU and was 

considered acceptable for unused and used drilling muds. 

Ecotoxicity:

Algae test (Skeletonema costatum): 

EC50 (72 hour): >10,000 mg/l 

NOEC (72 hour): >10,000 mg/l 

Crustacean test (Acartia tonsa): 

LC90 (48 hour): >10,000 mg/l 

NOEC (48 hour): >10,000 mg/l 

Sediment reworker test (Corophium volutator): 

LC50 (10 days): >10,000 mg/kg 

NOEC (10 days): 260-3,125 mg/kg 

Fish test (Scophthalmus maximus or Sheepshead minnow): 

LC50 (96 hour): >10,000 mg/l 

Environmental Fate:

Bioaccumulation: Weighted Average Log Pow: 1.5-2.5 

Biodegradation: BOC (28 Days): 13-16% 

13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your 

package size. You will need to apply the appropriate regulations to properly classify your 

shipment for transportation.

Regulation: Non regulated 

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated 

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

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This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 

"Hazard Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard 

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of 

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and 

Subpart C-Supplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications 

of compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled 

Products Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic Substances List (DSL) or 

otherwise comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the 

Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release 

Inventory. 

None required. 

16. Other Information

User's Responsibility

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The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace 

Hazardous Materials Information System (WHMIS) require that the information contained on 

these sheets be made available to your workers. Educate and train your workers regarding 

OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult 

with appropriate experts to guard against hazards associated with use of this product and its 

ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT 

OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that 

the product shall conform to contracted specifications, and that the product does not infringe 

any valid United States or Canadian patent. No claim of any kind shall be greater in amount 

than the purchase price of the quantity of product in respect of which damages are claimed. In 

no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim 

is based on contract, breach of warranty, negligence or otherwise. 

HESI101778
HESI101779
HESI101780
HESI101781
HESI101782
HESI101783
HESI101784
HESI101785
HESI101786
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: XYLENE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: XYLENE

Synonyms: None

Chemical Family: Aromatic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Xylene 1330-20-7 79-83 100 ppm 100 ppm

Ethyl benzene 100-41-4 16-20 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

XYLENE

Page 1 of 6

HESI101787
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 79

Flash Point/Range (C): 26

Flash Point Method: Not Determined

Autoignition Temperature (F): 930

Autoignition Temperature (C): 498

Flammability Limits in Air - Lower (%): 1

Flammability Limits in Air - Upper (%): 7

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Avoid spraying water directly into

storage containers due to danger of boilover. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

XYLENE

Page 2 of 6

HESI101788
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to water white

Odor: Aromatic hydrocarbon

pH: 7

Specific Gravity @ 20 C (Water=1): 0.86

Density @ 20 C (lbs./gallon): 7.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 281

Boiling Point/Range (C): 138

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 21

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 106

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May be absorbed through the

skin and produce effects similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation May cause eye burns.

XYLENE

Page 3 of 6

HESI101789
Ingestion Irritation of the mouth, throat, and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. Aspiration into the lungs may cause chemical

pneumonitis including coughing, difficulty breathing, wheezing, coughing up blood

and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Lung disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 4300 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

XYLENE

Page 4 of 6

HESI101790
DOT

UN1307,Xylenes, 3, III, (26.1 C)

RQ (Xylene - 45.4 kg.)

NAERG 130

Canadian TDG

Xylenes, 3, UN1307, III, (26.1 C)

ADR

UN1307,Xylenes, 3, III

Air Transportation

ICAO/IATA

UN1307,Xylenes, 3, III

RQ (Xylene - 45.4 kg.)

Sea Transportation

IMDG

UN1307,Xylenes, 3, III, (26.1 C)

RQ (Xylene - 45.4 kg.)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Fire Hazard

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethyl Benzene//100-41-4

Xylene//1330-20-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 17 Gallons based on Xylene (CAS: 1330-20-7).

XYLENE

Page 5 of 6

HESI101791
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Listed Waste U239

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

XYLENE

Page 6 of 6

HESI101792
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: XYLENE BOTTOMS

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: XYLENE BOTTOMS

Synonyms: None

Chemical Family: Aromatic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Benzene 71-43-2 0.1-10 0.5 ppm 1 ppm

Toluene 108-88-3 0.1-10 20 ppm 200 ppm

Xylene 1330-20-7 >60 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin. Repeated overexposure may cause liver and kidney effects. Potential

carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

XYLENE BOTTOMS

Page 1 of 6

HESI101793
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 111

Flash Point/Range (C): 43

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Avoid spraying water directly into

storage containers due to danger of boilover. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

XYLENE BOTTOMS

Page 2 of 6

HESI101794
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Aromatic hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.89

Density @ 20 C (lbs./gallon): 7.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May be absorbed through the

skin and produce effects similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation May cause eye burns.

XYLENE BOTTOMS

Page 3 of 6

HESI101795
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions. Aspiration into the lungs may cause chemical pneumonitis including

coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which

can be fatal. May cause pulmonary edema.

Aggravated Medical Conditions Skin disorders. Eye ailments. Lung disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Contains benzene, a known carcinogen,

over-exposures may result in bone marrow depression possibly leading to leukemia.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

XYLENE BOTTOMS

Page 4 of 6

HESI101796
DOT

UN1268,Petroleum Distillates, N.O.S., III, (43.9 C)

RQ (Xylene - 60.5 kg.)

Canadian TDG

Petroleum Distillates, N.O.S., UN1268, III, (43.9 C)

ADR

UN1268,Petroleum Distillates, N.O.S., III

Air Transportation

ICAO/IATA

UN1268,Petroleum Distillates, N.O.S., III

RQ (Xylene - 60.5 kg.)

Sea Transportation

IMDG

UN1268,Petroleum Distillates, N.O.S., III, (43.9 C)

RQ (Xylene - 60.5 kg.)

EmS F-E, S-E

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Benzene//71-43-2

Toluene//108-88-3

Xylene//1330-20-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 19 Gallons based on Xylene (CAS: 1330-20-7).

XYLENE BOTTOMS

Page 5 of 6

HESI101797
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Listed Waste U239

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

XYLENE BOTTOMS

Page 6 of 6

HESI101798
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ACFRAC PR-6000 PROPPANT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ACFRAC PR-6000 PROPPANT

Synonyms: None

Chemical Family: Resin coated sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phenol / formaldehyde resin 9003-35-4 1 - 5% Not applicable Not applicable

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation. May cause allergic skin and respiratory

reaction.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

ACFRAC PR-6000 PROPPANT

Page 1 of 7

HESI101799
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use.

ACFRAC PR-6000 PROPPANT

Page 2 of 7

HESI101800
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark gray

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.53

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 100

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Aldehydes. Phenol. Hydrogen cyanide.

Ammonia. Benzo(A)pyrene. Other organic materials. Amorphous silica may

transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

ACFRAC PR-6000 PROPPANT

Page 3 of 7

HESI101801
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation. May cause a rash and itching of the skin.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

ACFRAC PR-6000 PROPPANT

Page 4 of 7

HESI101802
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

ACFRAC PR-6000 PROPPANT

Page 5 of 7

HESI101803
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ACFRAC PR-6000 PROPPANT

Page 6 of 7

HESI101804
ACFRAC PR-6000 PROPPANT

Page 7 of 7

HESI101805
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AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

1/6

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® Black Plus, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: AcFrac® Black Plus, all sizes 

PRODUCT CODE: 306874GEN 

PRODUCT TYPE: Oil/Gas Well Proppant 

APPLICATION: Hydraulic Fracturing 

SOLD UNDER BORDEN U.S. PATENT NUMBERS 4,581,253; 

4,694,905 & 4,722,991 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

14808-60-7 *Quartz (SiO2) 70.0 - 100.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Charcoal, free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

HESI101806
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3.2 Potential Health Effects

Immediate Hazards 

INGESTION: Not expected to be harmful under normal conditions of use. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

14808-60-7 Quartz (SiO2)

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an 

increased incidence of significant disease endpoints such as scleroderma (an immune system disorder 

manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also 

reported to increase the risk of tuberculosis. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

HESI101807
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3/6

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact. Wear safety glasses with sideshields at all times to prevent eye 

irritation.

8.3 Exposure Guidelines 

14808-60-7 Quartz (SiO2) 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction; A2 - 

Suspected Human Carcinogen 

OSHA PEL 8-hr TWA 10/(%SiO2+

2) mg/m3 

respirable dust 

8-hr TWA 30/(%SiO2+

2) mg/m3 

total dust 

Remanded TWA 0.1 mg/m3 respirable dust; 1989 PEL 

remanded, but in effect in some 

HESI101808
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AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

4/6

states 

NIOSH 8-hr TWA 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline Silica 

9. Physical and Chemical Properties 

Appearance Charcoal, free flowing granules 

Odor Odorless 

Odor threshold Not applicable 

Specific gravity Approx. 2.53 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Solubility in water Negligible 

Octanol/water partition coefficient Not available 

Vapor pressure Not applicable 

Vapor density Not applicable 

Evaporation rate Not applicable 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities: 

None known to company.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

14808-60-7 Quartz (SiO2) 

LC50: Not available

LD50: Not available

12. Ecological Information 

Not determined. 

13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

HESI101809
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14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated 

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated 

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

HESI101810
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All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI101811
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ACO-1 FOAMER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ACO-1 FOAMER

Synonyms: None

Chemical Family: Acetate

Application: Foaming Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Fluoroaliphatic polymeric

esters

Mixture 30 - 60% Not applicable Not applicable

Ethyl acetate 141-78-6 30 - 60% 400 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ACO-1 FOAMER

Page 1 of 6

HESI101812
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 18

Flash Point/Range (C): -8

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

ACO-1 FOAMER

Page 2 of 6

HESI101813
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Pleasant

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 171

Boiling Point/Range (C): 77

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 76

Vapor Density (Air=1): Not Determined

Percent Volatiles: <60

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis. Nitrates.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. Causes drying of the skin.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

ACO-1 FOAMER

Page 3 of 6

HESI101814
Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Repeated, excessive exposure may cause liver and blood effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 10000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(20 Day): 0.56 g/g COD: 1.3 g/g Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 943 mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1866,Resin Solution, 3, II, (-8 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (-8 C)

ACO-1 FOAMER

Page 4 of 6

HESI101815
ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (-8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1142 Gallons based on Ethyl acetate (CAS: 141-78-

6).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

ACO-1 FOAMER

Page 5 of 6

HESI101816
WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ACO-1 FOAMER

Page 6 of 6

HESI101817
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AS-11a

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AS-11a

Synonyms: None

Chemical Family: Sulfate

Application: Anti-sludging Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium salt 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

AS-11a

Page 1 of 5

HESI101818
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 94

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe.

7. HANDLING AND STORAGE

Handling Precautions Not Determined

Storage Information Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Neoprene gloves.

Skin Protection Neoprene coated apron or clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Mild

pH: 6 - 7 (10%)

AS-11a

Page 2 of 5

HESI101819
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.01

Density @ 20 C (lbs./gallon): 8.42

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 70

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Contact with oxidizing agents.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Excessive inhalation causes headache, dizziness,

nausea and incoordination.

Skin Contact May cause severe skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion May cause central nervous system effects. Irritation of the mouth, throat, and

stomach. May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

AS-11a

Page 3 of 5

HESI101820
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

AS-11a

Page 4 of 5

HESI101821
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AS-11a

Page 5 of 5

HESI101822
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AS-11e

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AS-11e

Synonyms: None

Chemical Family: Surfactant

Application: Non-Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Amine 30 - 60% Not applicable Not applicable

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause skin burns. May be harmful if

swallowed. May cause headache, dizziness, and other central nervous system

effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

AS-11e

Page 1 of 6

HESI101823
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 70

Flash Point/Range (C): 21

Flash Point Method: PMCC

Autoignition Temperature (F): 748.4

Autoignition Temperature (C): 398

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves. Use Viton or 4H gloves. Butyl rubber gloves. Neoprene

gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

AS-11e

Page 2 of 6

HESI101824
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: > 7 (1%)

Specific Gravity @ 20 C (Water=1): 0.89

Density @ 20 C (lbs./gallon): 7.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 176

Boiling Point/Range (C): 80

Freezing Point/Range (F): -32.8

Freezing Point/Range (C): -36

Vapor Pressure @ 20 C (mmHg): < 22

Vapor Density (Air=1): 2

Percent Volatiles: 60-65

Evaporation Rate (Butyl Acetate=1): 1.6

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin burns.

Eye Contact Causes severe eye irritation

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause headache, dizziness, nausea, vomiting,

gastrointestinal irritation and central nervous system depression.

AS-11e

Page 3 of 6

HESI101825
Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, II, (21 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, II, (21 C)

AS-11e

Page 4 of 6

HESI101826
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, II, (21 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

AS-11e

Page 5 of 6

HESI101827
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

E Corrosive Material

B2 Flammable Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AS-11e

Page 6 of 6

HESI101828
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BA-40LM

Revision Date: 26-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BA-40LM

Synonyms: None

Chemical Family: Carbonate

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium carbonate 584-08-7 10 - 30% Not applicable Not applicable

Sodium carbonate 497-19-8 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. In case of contact,

immediately flush skin with plenty of soap and water for at least 15 minutes. Get

medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BA-40LM

Page 1 of 6

HESI101829
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Physical Hazard 0 , PPE: Dt

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

BA-40LM

Page 2 of 6

HESI101830
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Odorless

pH: 13.5

Specific Gravity @ 20 C (Water=1): 1.435

Density @ 20 C (lbs./gallon): 11.95

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 266

Boiling Point/Range (C): 130

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Contact with acids and lime dust will cause the formation of potassium

hydroxide and sodium hydroxide.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause chemical pneumonia. Causes severe respiratory burns.

Skin Contact Causes severe skin irritation. May cause skin burns. May cause an allergic skin

reaction.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

BA-40LM

Page 3 of 6

HESI101831
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

BA-40LM

Page 4 of 6

HESI101832
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

BA-40LM

Page 5 of 6

HESI101833
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BA-40LM

Page 6 of 6

HESI101834
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BA-50 BUFFERING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BA-50 BUFFERING AGENT

Synonyms: None

Chemical Family: Acid

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Boric acid 10043-35-3 60 - 100% 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Potential reproductive hazard.

Contains a material which may cause embryo/fetotoxicity based on animal data.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BA-50 BUFFERING AGENT

Page 1 of 5

HESI101835
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 5.1

Specific Gravity @ 20 C (Water=1): 1.84

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

BA-50 BUFFERING AGENT

Page 2 of 5

HESI101836
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 69.619

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Potassium. Anhydrides.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and

central nervous system depression.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause reproductive system damage. Prolonged

or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3160 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

BA-50 BUFFERING AGENT

Page 3 of 5

HESI101837
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

BA-50 BUFFERING AGENT

Page 4 of 5

HESI101838
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BA-50 BUFFERING AGENT

Page 5 of 5

HESI101839
 

Page 1 of 5

Material Safety Data Sheet 

1. PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME Bactron® K-31 Antimicrobial 

PRODUCT USE Biocide 

 

COMPANY MAILING 

ADDRESS 

Special Products 

P.O. Box 27727 

Houston, TX, 77227 

USA 

EMERGENCY 

TELEPHONE NUMBERS 

24 HRS. 

1-800-424-9300 (CHEMTREC) 

1-703-527-3887 (CHEMTREC - International) 

1-613-996-6666 (CANUTEC - Canada) 

1-281-431-2561 ( Special Products )

2. COMPOSITION/INFORMATION ON INGREDIENTS 

SUBSTANCE CAS-NO. WEIGHT % 

Glutaraldehyde 111-30-8 10.0 - 30.0 

EMERGENCY OVERVIEW 

DANGER! 

APPEARANCE & ODOR Clear Colorless, Liquid , Sharp Pungent

HEALTH HAZARDS Corrosive, Harmful, May cause sensitization by 

inhalation., May cause sensitization by skin contact. 

PHYSICAL HAZARDS This product is not expected to be a fire hazard. 

HEALTH HAZARDS

SKIN Harmful in contact with skin. May cause sensitization by skin contact. 

Irritating to skin. 

EYE Causes burns. 

INHALATION Harmful by inhalation. May cause sensitization by inhalation. 

INGESTION Harmful if swallowed. 

POTENTIAL ENVIRONMENTAL 

EFFECTS 

Prevent product from entering drains (waterways).

SKIN Wash off immediately with soap and plenty of water while removing all 

contaminated clothes and shoes. Call a physician immediately. 

EYE Rinse immediately with plenty of water, also under the eyelids, for at least 

15 minutes. Call a physician immediately. 

3. HAZARDS IDENTIFICATION

4. FIRST AID MEASURES 

Effective date: 10/20/2007 

Report version 2.1 

HESI101840
Bactron® K-31 Antimicrobial 

Page 2 of 5 Effective date: 10/20/2007 

Report version 2.1 

INHALATION Move to fresh air. Call a physician immediately. Aspiration may cause 

lung damage. Probable mucosal damage may contraindicate the use of 

gastric lavage. 

INGESTION Obtain medical attention. Immediately give large quantities of water to 

drink. Never give anything by mouth to an unconscious person. Do not 

induce vomiting. 

5. FIRE-FIGHTING MEASURES 

FLASH POINT > 200 °F (> 93 °C) PMCC

EXTINGUISHING MEDIA Water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 

SPECIAL HAZARDS Vapors are heavier than air and may travel considerable distance along 

the ground or be moved by ventilation to ignition sources. Empty product 

containers may contain product residue. Do not pressurize, cut, heat, 

weld or expose containers to flame or other sources of ignition. 

SPECIAL PROTECTIVE 

EQUIPMENT FOR FIRE 

FIGHTERS 

Wear positive-pressure self-contained breathing apparatus (SCBA) and 

full protective fire fighting gear. Equipment should be thoroughly 

decontaminated after use. 

HAZARDOUS 

COMBUSTION PRODUCTS 

Combustion products may include carbon monoxide and carbon dioxide. 

FIRE FIGHTING / FURTHER 

ADVICE 

Evacuate area and fight fire from safe distance. Use water spray to cool 

fire exposed structures and to protect personnel. Shut off source of flow 

if possible. If a leak or spill has not ignited, use water spray to disperse 

the vapors. 

6. ACCIDENTAL RELEASE MEASURES 

CLEAN UP METHODS Eliminate all ignition sources. No flares, smoking or flames in hazard 

area. Stop leak if you can do it without risk. Liquids may need to be 

neutralized before collection begins. Take up spill with sand or other 

noncombustible absorbent material and place in containers for later 

disposal. Always wear proper personal protective equipment when 

addressing spill or leak. 

ENVIRONMENTAL 

PRECAUTIONS 

Prevent product from entering drains (waterways). 

7. HANDLING AND STORAGE 

GENERAL PRECAUTIONS Handle in accordance with good industrial hygiene and safety practices. 

These practices include avoiding unnecessary exposure and removal of 

material from eyes, skin and clothing. Wash thoroughly after handling. 

Avoid breathing vapor. Use only with adequate ventilation. Keep away 

from heat and sources of ignition. Take precautionary measures against 

static discharges. 

STORAGE Keep container closed when not in use. Store in cool, dry place. 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION 

HESI101841
Bactron® K-31 Antimicrobial 

Page 3 of 5 Effective date: 10/20/2007 

Report version 2.1 

OCCUPATIONAL EXPOSURE LIMITS 

NAME SOURCE TYPE PPM MG/M3 NOTATION 

Glutaraldehyde ACGIH 

NIOSH 

 

 

 

 Ceiling 

 Ceiling 

 

 0.05 

 0.2 

 

 0.8 

 

* = Can be absorbed through the skin. 

ENGINEERING MEASURES Provide general and/or local exhaust ventilation, process enclosures or 

other engineering controls to control airborne levels below exposure 

guidelines. 

RESPIRATORY 

PROTECTION 

When respiratory protection is required, use an approved air purifying 

respirator or positive-pressure supplied-air respirator depending on 

potential airborne concentration. 

HAND PROTECTION Wear chemical-resistant gloves to prevent skin contact. Glove/protective 

clothing suppliers can provide recommendations for your specific 

applications. Wash immediately if skin is contaminated. Good personal 

hygiene practices such as properly handling contaminated clothing, 

using wash facilities before eating, drinking or smoking are essential for 

preventing personal chemical contamination. Contaminated gloves 

should be replaced. 

EYE PROTECTION Use chemical splash goggles, safety glasses and/or face shield. An 

emergency eye wash fountain should be located in immediate work area. 

BODY PROTECTION A safety shower should be located in the immediate work area. Remove 

contaminated clothing, wash skin with soap and water and launder 

clothing before reuse or dispose of properly. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

 

FORM Liquid 

COLOR Clear Colorless 

ODOR Sharp Pungent 

ODOR THRESHOLD Not available 

BOILING POINT Not available 

POUR POINT 14 °F (-10 °C) 

FLASH POINT > 200 °F (> 93 °C) PMCC 

LOWER EXPLOSION LIMIT Not available

UPPER EXPLOSION LIMIT Not available

AUTOIGNITION TEMPERATURE Not available

EVAPORATION RATE Not available

pH 3.0 - 4.5 

SOLUBILITY Water 

RELATIVE VAPOR DENSITY (AIR = 1) Not available

SPECIFIC GRAVITY (H2O = 1) 1.0515 - 1.0815 @ 68 °F (20 °C) 

HESI101842
Bactron® K-31 Antimicrobial 

Page 4 of 5 Effective date: 10/20/2007 

Report version 2.1 

VAPOR PRESSURE 5.171 mmHg 

VISCOSITY 4 - 6 cPs

PARTITION COEFFICIENT (NOCTANOL/WATER) 

Not available 

10. STABILITY AND REACTIVITY 

STABILITY Stable 

CONDITIONS TO AVOID Flames, High temperatures, Evaporation of water 

MATERIALS TO AVOID Alkalies catalyze an aldol type condensation., Amines, Ammonia, Strong 

Acids, Strong Bases, Strong oxidizers, Aluminum and mild steel, Copper 

and Iron, carbon steel 

HAZARDOUS 

DECOMPOSITION 

PRODUCTS 

Oxides of carbon 

HAZARDOUS 

POLYMERIZATION 

 Will not occur 

11. TOXICOLOGICAL INFORMATION 

SUBSTANCE SOURCE GROUP LIST ATTRIBUTE 

CARCINOGENICITY 

Glutaraldehyde ACGIH Sensitiser. 

ACGIH Group A4 Not classifiable as a human carcinogen. 

SENSITIZATION 

The following component(s) may cause sensitization by skin contact: 

Glutaraldehyde

The following component(s) may cause sensitization by inhalation: 

Glutaraldehyde 

12. ECOLOGICAL INFORMATION 

No data is available on the product itself. 

 

13. DISPOSAL CONSIDERATIONS 

ADVICE ON DISPOSAL Dispose of in accordance with local regulations. 

14. TRANSPORT INFORMATION 

Refer to the bill of lading or container label for DOT or other transportation hazard classification. 

Additionally, be aware that shipping descriptions may vary based on mode of transport, shipment volume 

or weight, container size or type, and/or origin and destination. Consult your company's Hazardous 

Materials / Dangerous Goods expert or your legal counsel for information specific to your situation. 

15. REGULATORY INFORMATION 

HESI101843
Bactron® K-31 Antimicrobial 

Page 5 of 5 Effective date: 10/20/2007 

Report version 2.1 

STATE REGULATORY STATUS 

STATE RIGHT TO KNOW 

MASSACHUSETTS RIGHT-TO-KNOW CHEMICAL LIST

Glutaraldehyde

PENNSYLVANIA RIGHT-TO-KNOW CHEMICAL LIST

Glutaraldehyde

INVENTORY STATUS 

NOTIFICATION STATUS 

TSCA Listed or Exempt 

16. OTHER INFORMATION 

 NFPA RATING 

HEALTH 3 

FLAMMABILITY 0 

INSTABILITY 0 

Prepared By: Product Stewardship 

Preparation Date: 10/20/2007 

The data and information contained herein are being furnished for informational purposes only, upon the 

express condition that each customer shall make its own assessment of appropriate use and appropriate 

shipping, transfer and storage materials and procedures for Special Products. Although based on 

information sources which Special Products considers accurate and reliable, Special Products makes no 

warranty, either express or implied, including any warranties or merchantability or fitness for a particular 

purpose, regarding the validity of this information, the information sources upon which the same are 

based, or the results to be obtained, and expressly disclaims liabilities for damages or injuries resulting 

from the use thereof. 

HESI101844
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BARACARB® 50

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BARACARB® 50

Synonyms: None

Chemical Family: Mineral

Application: Bridging Agent

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Limestone 1317-65-3 60 - 100% 10 mg/m3 15 mg/m3

Crystalline silica, quartz 14808-60-7 0 - 1% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

BARACARB® 50

Page 1 of 7

HESI101845
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. This

product contains quartz, cristobalite, and/or tridymite which may become airborne

without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use

only with adequate ventilation to keep exposure below recommended exposure

limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator

when using this product. Material is slippery when wet.

Storage Information Store away from acids. Store in a cool, dry location. Use good housekeeping in

storage and work areas to prevent accumulation of dust. Close container when not

in use. Do not reuse empty container. Product has a shelf life of 60 months.

BARACARB® 50

Page 2 of 7

HESI101846
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Use approved industrial ventilation and local exhaust

as required to maintain exposures below applicable exposure limits listed in Section

2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid Powder

Color: White

Odor: Odorless

pH: 8-9

Specific Gravity @ 20 C (Water=1): 2.7

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 72-112

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated

temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

BARACARB® 50

Page 3 of 7

HESI101847
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

BARACARB® 50

Page 4 of 7

HESI101848
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: >1,000,000 ppm (Mysidopsis bahia) SPP @ 178.5 ppb

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

BARACARB® 50

Page 5 of 7

HESI101849
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BARACARB® 50

Page 6 of 7

HESI101850
BARACARB® 50

Page 7 of 7

HESI101851
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BARACORTM 100

Revision Date: 15-May-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BARACORTM 100

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

Nitrilotriacetic acid, trisodium

salt monohydrate

5064-31-3 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Potential carcinogen. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

BARACORTM 100

Page 1 of 6

HESI101852
Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 92

Flash Point/Range (C): 33

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

BARACORTM 100

Page 2 of 6

HESI101853
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Brown

Odor: Alcohol

pH: 9-11

Specific Gravity @ 20 C (Water=1): 1.01

Density @ 20 C (lbs./gallon): 8.4

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -9

Freezing Point/Range (C): -23

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): 1.6

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 35

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: -0.84 (OECD117)

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation May cause eye burns.

BARACORTM 100

Page 3 of 6

HESI101854
Ingestion May be fatal or cause blindness if swallowed. May produce nervous system effects

such as feeling of weakness, unsteady walk, and dilation of blood vessels.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Contains nitrilotriacetic acid or its salts,

which is NTP Classification 2 (Reasonably Anticipated to be a Human Carcinogen)

and IARC Classification 2B (a Possible Human Carcinogen)

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3500 mg/kg (Rat)

Dermal Toxicity: LD50: > 3000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(28 Day): 10% of COD

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM48: 402.5 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

BARACORTM 100

Page 4 of 6

HESI101855
DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (33.3 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol), 3, UN1993, III, (33.3 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (33.3 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2380 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

BARACORTM 100

Page 5 of 6

HESI101856
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D2A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BARACORTM 100

Page 6 of 6

HESI101857
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BARITE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BARITE

Synonyms: None

Chemical Family: Mineral

Application: Weight Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Barium sulfate 7727-43-7 60 - 100% 10 mg/m3 15 mg/m3

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

BARITE

Page 1 of 7

HESI101858
Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1*, Flammability 0, Physical Hazard 0 , PPE: E

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Do not reuse empty

container.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

BARITE

Page 2 of 7

HESI101859
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the

selection and proper use of personal protective equipment should be determined by

an industrial hygienist or other qualified professional based on the specific

application of this product.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Pink to tan to gray

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 4.23

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 135

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 233.4

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

BARITE

Page 3 of 7

HESI101860
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion May produce nervous system effects such as feeling of weakness, unsteady walk,

and dilation of blood vessels. May affect the heart and cardiovascular system.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Prolonged inhalation of fine barium sulfate dusts form harmless nodular granules in

lung, an affliction called baritosis. Baritosis produces no symptoms of bronchitis or

emphysema, and lung functioning is not affected although dyspnea, upon exertion,

may occur. The nodulation disappears if exposure is stopped.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

BARITE

Page 4 of 7

HESI101861
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 7500 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

BARITE

Page 5 of 7

HESI101862
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

BARITE

Page 6 of 7

HESI101863
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BARITE

Page 7 of 7

HESI101864
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BAROID®

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BAROID®

Synonyms: None

Chemical Family: Mineral

Application: Weight Additive

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Barium sulfate 7727-43-7 60 - 100% 10 mg/m3 15 mg/m3

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

BAROID®

Page 1 of 7

HESI101865
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Do not reuse empty

container. Product has a shelf life of 60 months.

BAROID®

Page 2 of 7

HESI101866
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the

selection and proper use of personal protective equipment should be determined by

an industrial hygienist or other qualified professional based on the specific

application of this product.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Pink to tan to gray

Odor: Odorless

pH: 8-9-

Specific Gravity @ 20 C (Water=1): 4.2

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 100- 155

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 233.4

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

BAROID®

Page 3 of 7

HESI101867
Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion May produce nervous system effects such as feeling of weakness, unsteady walk,

and dilation of blood vessels. May affect the heart and cardiovascular system.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Prolonged inhalation of fine barium sulfate dusts form harmless nodular granules in

lung, an affliction called baritosis. Baritosis produces no symptoms of bronchitis or

emphysema, and lung functioning is not affected although dyspnea, upon exertion,

may occur. The nodulation disappears if exposure is stopped.

BAROID®

Page 4 of 7

HESI101868
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 7500 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 132.6 ppb

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

BAROID®

Page 5 of 7

HESI101869
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

BAROID®

Page 6 of 7

HESI101870
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BAROID®

Page 7 of 7

HESI101871
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BAROID® 41

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BAROID® 41

Synonyms: None

Chemical Family: Mineral

Application: Weight Additive

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Barium sulfate 7727-43-7 60 - 100% 10 mg/m3 15 mg/m3

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

BAROID® 41

Page 1 of 6

HESI101872
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Get medical attention if irritation persists. Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Do not reuse empty container. Store in a cool, dry location. Use good housekeeping

in storage and work areas to prevent accumulation of dust. Close container when

not in use. Product has a shelf life of 60 months.

BAROID® 41

Page 2 of 6

HESI101873
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Pink to tan to gray

Odor: Odorless

pH: 8-9-

Specific Gravity @ 20 C (Water=1): 4.1

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 100- 155

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 233.4

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

BAROID® 41

Page 3 of 6

HESI101874
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion May produce nervous system effects such as feeling of weakness, unsteady walk,

and dilation of blood vessels. May affect the heart and cardiovascular system.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

BAROID® 41

Page 4 of 6

HESI101875
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 7500 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 132.6 ppb

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

BAROID® 41

Page 5 of 6

HESI101876
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BAROID® 41

Page 6 of 6

HESI101877
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BC-140C

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BC-140C

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Monoethanolamine borate 26038-87-9 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BC-140C

Page 1 of 6

HESI101878
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Blue

Odor: Amine

BC-140C

Page 2 of 6

HESI101879
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 7.9

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Dehydrating agents.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion May be harmful if swallowed. May cause abdominal pain, vomiting, nausea, and

diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause lung damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

BC-140C

Page 3 of 6

HESI101880
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

BC-140C

Page 4 of 6

HESI101881
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

BC-140C

Page 5 of 6

HESI101882
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BC-140C

Page 6 of 6

HESI101883
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BE-5 MICROBIOCIDE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BE-5 MICROBIOCIDE

Synonyms: None

Chemical Family: Blend

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

5-Chloro-2-methyl-4-

isothiazolin-3-one

26172-55-4 5 - 10% Not applicable Not applicable

Magnesium nitrate 10377-60-3 5 - 10% Not applicable Not applicable

Crystalline silica, cristobalite 14464-46-1 0 - 1% 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

Crystalline silica, quartz 14808-60-7 0 - 1% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

BE-5 MICROBIOCIDE

Page 1 of 7

HESI101884
3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed. May cause allergic skin reaction. Repeated overexposure may cause

liver and kidney effects.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: >100

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Flammability Limits in Air - Upper (oz./ft3):

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0 , Corrosive

HMIS Ratings: Health 3*, Flammability 1, Physical Hazard 0 , PPE: J

BE-5 MICROBIOCIDE

Page 2 of 7

HESI101885
6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Use good

housekeeping in storage and work areas to prevent accumulation of dust. Close

container when not in use. Keep from heat, sparks, and open flames.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron. Wear clothing appropriate for the work environment. Dusty clothing

should be laundered before reuse. Use precautionary measures to avoid creating

dust when removing or laundering clothing. Rubber boots.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Granular

Color: Red brown

Odor: Slight

pH: 1.9-4.0

Specific Gravity @ 20 C (Water=1): 0.72

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 5.59

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

BE-5 MICROBIOCIDE

Page 3 of 7

HESI101886
9. PHYSICAL AND CHEMICAL PROPERTIES

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and

carbon dioxide. Silicon dioxide. Magnesium oxides Metal oxides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause chemical pneumonia. Inhaled

crystalline silica in the form of quartz or cristobalite from occupational sources is

carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

May cause allergic respiratory reaction.

Skin Contact Causes severe skin irritation. May cause skin burns. May cause an allergic skin

reaction.

Eye Contact Corrosive to eye tissue and may cause severe damage and blindness.

Ingestion Causes burns of the mouth, throat and stomach. May cause liver and kidney

damage.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

BE-5 MICROBIOCIDE

Page 4 of 7

HESI101887
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

BE-5 MICROBIOCIDE

Page 5 of 7

HESI101888
Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Triple rinse, reusing rinsate as product. Return for reuse or puncture container and

dispose in a sanitary landfill according to national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3261,Corrosive Solid, Acidic, Organic, N.O.S.(Contains 5-Chloro-2-Methyl-4-Isothiazolin-3-One, 2-Methyl-4-

Isothiazolin-3-One), 8, II

NAERG 154

Canadian TDG

Corrosive Solid, Acidic, Organic, N.O.S.(Contains 5-Chloro-2-Methyl-4-Isothiazolin-3-One, 2-Methyl-4-Isothiazolin-3-One),

8, UN3261, II

ADR

UN3261,Corrosive Solid, Acidic, Organic, N.O.S.(Contains 5-Chloro-2-Methyl-4-Isothiazolin-3-One, 2-Methyl-4-

Isothiazolin-3-One), 8, II

Air Transportation

ICAO/IATA

UN3261,Corrosive Solid, Acidic, Organic, N.O.S., 8, II

(Contains 5-Chloro-2-Methyl-4-Isothiazolin-3-One, 2-Methyl-4-Isothiazolin-3-One)

Sea Transportation

IMDG

UN3261,Corrosive Solid, Acidic, Organic, N.O.S.(Contains 5-Chloro-2-Methyl-4-Isothiazolin-3-One, 2-Methyl-4-

Isothiazolin-3-One), 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

BE-5 MICROBIOCIDE

Page 6 of 7

HESI101889
EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

Federal Insecticide, Fungicide

and Rodenticide Act:

Label in accordance with Federal Insecticide, Fungicide, and Rodenticide Act

(FIFRA) requirements.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BE-5 MICROBIOCIDE

Page 7 of 7

HESI101890
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BE-7TM

Revision Date: 11-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BE-7TM

Synonyms: None

Chemical Family: Inorganic

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hypochlorite 7681-52-9 10 - 30% Not applicable Not applicable

Sodium hydroxide 1310-73-2 1 - 5% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Immediately flush eyes with large amounts of water for at least 20 minutes. Seek

prompt medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treatment based on sound judgment of physician and individual reactions of patient.

BE-7TM

Page 1 of 6

HESI101891
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Reacts with metals to generate

flammable hydrogen gas.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Physical Hazard 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove. Hypochlorite can be broken down by covering it with a reducing agent such

as sodium sulfite or sodium thiosulfate.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from reducing agents. Store in a cool well

ventilated area. Store away from direct sunlight. Keep container closed when not in

use. Store between 59 F (15 C) and 84 F (29 C). Keep from freezing. Product has a

shelf life of up to 6 months at 60F or lower.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Acid gas respirator with a dust/mist filter. In high concentrations, supplied air

respirator or a self-contained breathing apparatus.

BE-7TM

Page 2 of 6

HESI101892
Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves. Viton gloves Butyl rubber

gloves.

Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain

jacket, pants or coverall, as appropriate, to prevent skin contact.

Eye Protection Splashproof chemical monogoggles or safety glasses with side shields in conjunction

with a face shield.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Pungent

pH: 11-13

Specific Gravity @ 20 C (Water=1): 1.21

Density @ 20 C (lbs./gallon): 10.0

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): ~230

Boiling Point/Range (C): ~110

Freezing Point/Range (F): 7.5

Freezing Point/Range (C): -13.6

Vapor Pressure @ 20 C (mmHg): 12

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with hydrochloric acid. Can react to release chlorine gas. Contact with

certain metals produces hydrogen gas. Hazards increase greatly if material is

allowed to dry.

Incompatibility (Materials to

Avoid)

Strong acids. Contact with metals. Ammonium compounds. Organic matter.

Cyanides. Alcohols. Nitrogen compounds. Cellulose. Ethyleneimine.

Hazardous Decomposition

Products

Hydrogen chloride. Chlorine. Hypochlorous acid. Flammable hydrogen gas. Sodium

oxides. Oxygen. Chlorine dioxide. Sodium chlorate

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

BE-7TM

Page 3 of 6

HESI101893
Skin Contact Causes severe skin irritation. May cause skin burns. May cause an allergic skin

reaction.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May be fatal if swallowed.

Aggravated Medical Conditions Skin disorders. Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 8910 mg/kg (Rat)

Dermal Toxicity: LD50: > 10000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Sodium hypochlorite caused mutations in several short-term studies using bacteria

and cultured mammalian cells. The significance of these tests is unclear. It was not

mutagenic in tests (chromosome aberration and micronucleus) on live animals.

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM48: 0.07 mg/l (Oncorhynchus mykiss) TLM96: 5.9 mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

BE-7TM

Page 4 of 6

HESI101894
DOT

Hypochlorite Solution, 8, UN1791, III

RQ (Sodium Hypochlorite - 454 kg.)

NAERG 154

Canadian TDG

Hypochlorite Solution, 8, UN1791, III

ADR

UN1791,Hypochlorite Solution, 8, III

Air Transportation

ICAO/IATA

UN1791,Hypochlorite Solution, 8, III

RQ (Sodium Hypochlorite - 454 kg.)

Sea Transportation

IMDG

UN1791,Hypochlorite Solution, 8, III

RQ (Sodium Hypochlorite - 454 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 80 Gallons based on Sodium hypochlorite (CAS:

7681-52-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it MAY meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

BE-7TM

Page 5 of 6

HESI101895
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BE-7TM

Page 6 of 6

HESI101896
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BE-9

Revision Date: 03-Feb-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BE-9

Synonyms: None

Chemical Family: Solution

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Tributyl tetradecyl

phosphonium chloride

81741-28-8 5 - 10% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed. May be harmful if inhaled.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse. Remove contaminated shoes and

discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, do NOT induce vomiting. Give victim two glasses of water, Call a

physician immediately. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BE-9

Page 1 of 6

HESI101897
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways. Use water spray to cool fire exposed surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 0

HMIS Ratings: Health 3, Flammability 0, Physical Hazard 0 , PPE: F

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. Do NOT consume food, drink, or tobacco in

contaminated areas.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Store

away from direct sunlight. Store in a dry location. Store in a manner to prevent

commingling with incompatible materials. Store away from alkalis. Store away from

reducing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves. Neoprene gloves. Polyvinylchloride gloves.

Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain

jacket, pants or coverall, as appropriate, to prevent skin contact.

BE-9

Page 2 of 6

HESI101898
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Slight

pH: 6-8

Specific Gravity @ 20 C (Water=1): 0.95-1.00

Density @ 20 C (lbs./gallon): 8.12

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): 55-65

Partition Coefficient/n-Octanol/Water: < 3

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Reducing agents. Strong alkalis.

Hazardous Decomposition

Products

Chlorine. Phosphorus acids. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May be harmful if inhaled.

Skin Contact May cause skin burns. Harmful if absorbed through the skin.

Eye Contact May cause eye burns.

Ingestion May be harmful if swallowed.

Aggravated Medical Conditions Lung disorders. Skin disorders.

Chronic Effects/Carcinogenicity Not determined

BE-9

Page 3 of 6

HESI101899
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: LC50: 0.9 mg/l 4-hour (rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Ames test: negative

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: LC50: (96 hour) 0.46 mg/L (Oncorhynchus mykiss)

LC50: (96 hour) 0.06 mg/l (Lepomis macrochirus)

 LC50: (96 hour) 0.58 mg/l (fish)

Acute Crustaceans Toxicity:TLM96: 1.6 mg/l (Crangon crangon) TLM48: 0.025 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Incineration recommended in approved incinerator according to federal, state, and

local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2922, Corrosive Liquid, Toxic, N.O.S.(contains Tributyl Tetradecyl Phosphonium Chloride), 8, (6.1), II

NAERG 154

Canadian TDG

Corrosive Liquid, Toxic, N.O.S.(contains Tributyl Tetradecyl Phosphonium Chloride), 8, (6.1), UN2922, II

BE-9

Page 4 of 6

HESI101900
ADR

UN2922, Corrosive Liquid, Toxic, N.O.S.(contains Tributyl Tetradecyl Phosphonium Chloride), 8, (6.1), II

Air Transportation

ICAO/IATA

UN2922, Corrosive Liquid, Toxic, N.O.S., 8, (6.1), II

(contains Tributyl Tetradecyl Phosphonium Chloride Solution)

Sea Transportation

IMDG

UN2922, Corrosive Liquid, Toxic, N.O.S.(contains Tributyl Tetradecyl Phosphonium Chloride), 8, (6.1), II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it MAY meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D1A Very Toxic Materials

BE-9

Page 5 of 6

HESI101901
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BE-9

Page 6 of 6

HESI101902
 Report Date : 07/01/2009 51 /

SDS NO.: 10794

MATERIAL SAFETY DATA SHEET

Bellacide 350

 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME Bellacide 350

CHEMICAL NAME Aqueous solution of tributyl tetradecyl phosphonium chloride

PRODUCT NO. BWA00110481

PRODUCT USE Industrial Water Treatment

SUPPLIER BWA Water Additives US LLC

1979 Lakeside Parkway

Suite 925,Tucker. GA30084.

TEL (800) 600-4523 

CUSTOMER SERVICE

EMERGENCY TELEPHONE Chemtrec Phone: 1-800-424-9300

IDENTIFICATION No. 2927

 2 HAZARDS IDENTIFICATION

POTENTIAL HEALTH EFFECTS

INHALATION

LC50 <0.9 mg/L. Administered as a liquid aerosol for a single 4 hr nose only exposure to rats. Toxic by inhalation.

INGESTION

Harmful if swallowed.

SKIN CONTACT

Causes burns.

Not a skin sensitizer.

EYE CONTACT

Causes burns.

HEALTH WARNINGS

This substance is corrosive. 3 COMPOSITION/INFORMATION ON INGREDIENTS

Name EC No. CAS-No. Weight

Tributyl tetradecyl phosphonium chloride 279-808-2 81741-28-8 30-60%

EC No. 279-808-2

CAS-No. 81741-28-8

COMPOSITION COMMENTS

50% Solution of tributyl tetradecyl phosphonium chloride in water 4 FIRST-AID MEASURES

INHALATION

Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. Get medical attention if any 

discomfort continues.

INGESTION

DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Get medical attention.

SKIN CONTACT

Immediately remove contaminated clothing. Rinse immediately with plenty of water. Continue to rinse for at least 15 

minutes. Get medical attention if irritation persists after washing.

EYE CONTACT

Rinse the eye with water immediately. Continue to rinse for at least 15 minutes. Contact physician if irritation persists.

HESI101903
 Report Date : 07/01/2009 52 /

SDS NO.: 10794

Bellacide 350

 5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA

Use: Water spray, fog or mist. Foam, carbon dioxide or dry powder.

SPECIAL FIRE FIGHTING PROCEDURES

Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the 

fire is out. Keep run-off water out of sewers and water sources. Dike for water control.

UNUSUAL FIRE & EXPLOSION HAZARDS

No unusual fire or explosion hazards noted.

SPECIFIC HAZARDS

Fire creates: Toxic gases/vapors/fumes of Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Phosphorus. 

Chlorine.

PROTECTIVE MEASURES IN FIRE

Use self-contained breathing apparatus Leave danger zone immediately. 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS

Follow precautions for safe handling described in this safety data sheet. For personal protection, see section 8.

ENVIRONMENTAL PRECAUTIONS

Avoid release to the environment. To prevent release, place container with damaged side up.

SPILL CLEAN UP METHODS

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect and 

reclaim or dispose in sealed containers in licensed waste. Containers with collected spillage must be properly labelled with 

correct contents and hazard symbol. Product is toxic to aquatic organisms. Minimise/prevent product from entering drains 

or water courses

 7 HANDLING AND STORAGE

HANDLING

Avoid spilling, skin and eye contact.

STORAGE

Keep containers tightly closed. Keep separate from food, feedstuffs, fertilizers and other sensitive material. Store at 

moderate temperatures in dry, well ventilated area. Protect from light, including direct sunrays.

STORAGE CLASS

Corrosive storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT COMMENTS

No exposure limits noted for ingredient(s).

PROCESS CONDITIONS

Provide eyewash station.

PROTECTIVE EQUIPMENT

ENGINEERING MEASURES

Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit 

is not exceeded.

RESPIRATORY EQUIPMENT

No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended 

Occupational Exposure Limit

HAND PROTECTION

Selection of a suitable glove depends on work conditions and whether the product is present on its own or in combination 

with other substances. It has been found that gloves made from rubber, neoprene or PVC provide short-term splash 

protection. Gloves should be replaced immediately if signs of degradation are observed.

EYE PROTECTION

Wear approved safety goggles.

HESI101904
 Report Date : 07/01/2009 53 /

SDS NO.: 10794

Bellacide 350

OTHER PROTECTION

Wear appropriate clothing to prevent repeated or prolonged skin contact.

HYGIENE MEASURES

No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working 

with chemicals.

SKIN PROTECTION

Wear apron or protective clothing in case of contact. 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Liquid

COLOR Colorless

ODOR Slight odor

SOLUBILITY Miscible with water.

BOILING POINT (°C) 100 - 101 RELATIVE DENSITY 0.95 - 1.00 @ 20 °C

pH-VALUE, CONC. SOLUTION 6-8 VISCOSITY 55 - 65 cSt @ 20 °C

 10 STABILITY AND REACTIVITY

STABILITY

Stable under normal temperature conditions and recommended use.

HAZARDOUS DECOMPOSITION PRODUCTS

Carbon dioxide (CO2). Carbon monoxide (CO). Chlorine. Oxides of: Phosphorus. 11 TOXICOLOGICAL INFORMATION

TOXIC DOSE 1 - LD 50 1002 mg/kg (oral rat)

TOXIC DOSE 2 - LD 50 4000 mg/kg (ipr-rat)

TOXICOLOGICAL INFORMATION

Ames Test negative

INHALATION

LC50 <0.9 mg/L. Administered as a liquid aerosol for a single 4 hr nose only exposure to rats. Toxic by inhalation.

INGESTION

Harmful if swallowed.

SKIN CONTACT

Causes burns. Not a skin sensitizer.

EYE CONTACT

Causes burns.

HEALTH WARNINGS

This substance is corrosive. 12 ECOLOGICAL INFORMATION

LC 50, 96 hrs, Fish mg/l 0.46 mg/l Rainbow Trout; 0.06 mg/l Bluegill; 1.6 mg/l Brown Shrimp

EC 50, 48 hrs, Daphnia, mg/l 0.025 mg/l 13 DISPOSAL CONSIDERATIONS

WASTE MANAGEMENT

When handling waste, consideration should be made to the safety precautions applying to handling of the product.

DISPOSAL METHODS

Absorb in vermiculite or dry sand, dispose in licensed hazardous waste. Liquid material should be incinerated. Material 

absorbed onto sand or earth should be disposed of as solid waste in accordance with local regulations. Empty packaging 

may contain product residues and due consideration should be given prior to disposal. 14 TRANSPORT INFORMATION

HESI101905
 Report Date : 07/01/2009 54 /

SDS NO.: 10794

Bellacide 350

TDG SHIPPING NAME TOXIC LIQUID, CORROSIVE, ORGANIC N.O.S., (contains tributyltetradecyl phosphonium 

chloride)

DOT PROPER SHIPPING 

NAME

TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.(contains tributyltetradecyl phosphonium 

chloride)

TDG SHIPPING NAME TOXIC LIQUID, CORROSIVE, ORGANIC N.O.S., (contains tributyltetradecyl phosphonium 

chloride)

IDENTIFICATION No. 2927 DOT HAZARD CLASS 6.1 (8)

DOT PACKING GROUP II Poison Poison Inhalation 

Hazard Corrosive

U.S DOT HAZARD LABEL

UN NO. SEA 2927 IMDG CLASS 6.1 (8)

IMDG PACK GR. II EMS F-A, S-B

UN NO. AIR 2927 AIR CLASS 6.1 (8)

AIR PACK GR. II DOT PACKING GROUP II 15 REGULATORY INFORMATION

INVENTORIES

COMPONENT CAN US EU AUS JAP KOR CHN PHLP

Tributyl tetradecyl phosphonium chloride DSL Yes EINECS Yes Exemp Yes Yes Yes

COMPONENT CAS CA FL MA MN NJ PA RI

Tributyl tetradecyl phosphonium chloride 81741-28-8 No No No No No No No

REGULATORY STATUS (US)

SECTION 313: This product does not contain toxic chemical subject to the reporting requirements of Section 313 of Title III 

of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. PROPOSITION 65: This product does 

not contain chemicals considered by the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as 

causing cancer or reproductive toxicity and for which warnings are now required. EPA REGISTRATION NUMBER:83451-15

LABEL(S) FOR SUPPLY

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM -WHMIS

Materials 

Causing 

Immediate and 

Serious Toxic 

Effect.

Corrosive 

Material.

CONTROLLED PRODUCT CLASSIFICATION

Canadian WHMIS Classification D1A E

 16 OTHER INFORMATION

HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS)

HESI101906
 Report Date : 07/01/2009 55 /

SDS NO.: 10794

Bellacide 350

HEALTH

FLAMMABILITY

PHYSICAL

PERSONAL PROTECTION F

0

0

3

(3)

(0)

(0)

N/A

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)

HEALTH

FIRE

INSTABILITY

SPECIFIC

REVISION COMMENTS

NOTE: Lines within the margin indicate significant changes from the previous revision.

Section 14 Revised Transport classification.

ISSUED BY

G.B.

REVISION DATE 7th January 2009

VERSION No. 5

SAFETY DATA SHEET STATUS

Approved.

DATE 7th January 2009

DISCLAIMER

For safety reasons it is IMPERATIVE that customers:- 

1. Ensure that all those within their control who use the products are supplied with all relevant information contained within the Safety 

Data Sheet and Technical Bulletin concerning the applications for which the product is designed and any instructions and warnings 

contained therein. 

2. Consult BWA Water Additives before using or supplying the product for any other applications. The information contained herein is 

based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It 

should not therefore be construed as guaranteeing specific properties.

HESI101907
 Report Date : 10/03/2009 51 /

SDS NO.: 10795

MATERIAL SAFETY DATA SHEET

Bellacide 355

 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME Bellacide 355

CHEMICAL NAME Aqueous solution of tributyl tetradecyl phosphonium chloride.

PRODUCT NO. 100736, 100737, 100833.

PRODUCT USE Industrial Water Treatment

SUPPLIER BWA Water Additives US LLC

1979 Lakeside Parkway

Suite 925,Tucker. GA30084.

TEL (800) 600-4523 

CUSTOMER SERVICE

EMERGENCY TELEPHONE Chemtrec Phone: 1-800-424-9300

IDENTIFICATION No. 2922

 2 HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

EPA SIGNAL WORD: DANGER.

POTENTIAL HEALTH EFFECTS

INHALATION

Harmful by inhalation. LC50 0.9 mg/L. Administered as a liquid aerosol for a single 4h nose only exposure to rats.

INGESTION

Harmful if swallowed.

SKIN CONTACT

Causes burns.

Not a skin sensitizer.

EYE CONTACT

Causes burns.

HEALTH WARNINGS

This substance is corrosive.

ROUTE OF ENTRY

Skin and/or eye contact. Ingestion. Inhalation.

TARGET ORGANS

Eyes. Skin. 3 COMPOSITION/INFORMATION ON INGREDIENTS

Name EC No. CAS-No. Weight

Tributyl tetradecyl phosphonium chloride 279-808-2 81741-28-8 3.5 - 6.5%

COMPOSITION COMMENTS

Aqueous solution of tributyl tetradecyl phosphonium chloride. 4 FIRST-AID MEASURES

NOTES TO THE PHYSICIAN

Probable mucosal damage may contraindicate the use of gastric lavage.

INHALATION

Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any 

discomfort continues.

INGESTION

NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Do not induce vomiting. If vomiting occurs, the 

head should be kept low so that stomach vomit doesn't enter the lungs. Rinse mouth thoroughly. Get medical attention.

HESI101908
 Report Date : 10/03/2009 52 /

SDS NO.: 10795

Bellacide 355

SKIN CONTACT

Remove victim immediately from source of exposure. Immediately remove contaminated clothing. Wash skin thoroughly 

with soap and water for several minutes. Get medical attention if any discomfort continues.

EYE CONTACT

Remove victim immediately from source of exposure. Immediately flush with plenty of water for up to 15 minutes. Remove 

any contact lenses and open eyes wide apart. Contact physician if irritation persists. 5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA

Fire can be extinguished using: Carbon dioxide (CO2). Foam. Dry chemicals, sand, dolomite etc. Water spray, fog or 

mist.

SPECIAL FIRE FIGHTING PROCEDURES

Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the 

fire is out. Keep run-off water out of sewers and water sources. Dike for water control.

UNUSUAL FIRE & EXPLOSION HAZARDS

No unusual fire or explosion hazards noted.

SPECIFIC HAZARDS

Fire creates: Toxic gases/vapors/fumes of Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Phosphorus. 

Chlorine.

PROTECTIVE MEASURES IN FIRE

Leave danger zone immediately. Self contained breathing apparatus and full protective clothing must be worn in case of 

fire. 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS

Follow precautions for safe handling described in this safety data sheet. For personal protection, see section 8.

ENVIRONMENTAL PRECAUTIONS

Avoid release to the environment. To prevent release, place container with damaged side up.

SPILL CLEAN UP METHODS

Should be prevented from entering drains. Absorb in vermiculite, dry sand or earth and place into containers. Collect and 

reclaim or dispose in sealed containers in licensed waste. Containers with collected spillage must be properly labelled with 

correct contents and hazard symbol. 7 HANDLING AND STORAGE

HANDLING

Avoid spilling, skin and eye contact. Avoid inhalation of vapors. Observe good industrial hygiene practices.

STORAGE

Do NOT use container made of: Carbon steel. Store separated from: Alkalies. Reducing Agents. Keep containers tightly 

closed. Keep separate from food, feedstuffs, fertilizers and other sensitive material. Store at moderate temperatures in 

dry, well ventilated area. Protect from light, including direct sunrays.

STORAGE CLASS

Corrosive storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT COMMENTS

No exposure limits noted for ingredient(s).

PROCESS CONDITIONS

Provide eyewash station.

PROTECTIVE EQUIPMENT

ENGINEERING MEASURES

Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors.

Provide adequate ventilation.

HESI101909
 Report Date : 10/03/2009 53 /

SDS NO.: 10795

Bellacide 355

RESPIRATORY EQUIPMENT

No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when 

excessive air contamination exists.

A respiratory protection programme that meets OSHA 1910.134 and ANZI Z88.2 requirements must be followed whenever 

work place conditions warrent a respirator's use.

HAND PROTECTION

Selection of a suitable glove depends on work conditions and whether the product is present on its own or in combination 

with other substances.

Gloves should be replaced immediately if signs of degradation are observed.

It has been found that gloves made from rubber, neoprene or PVC provide short-term splash protection.

EYE PROTECTION

Wear protective eye wear (goggles or face mask).

Use face shield in case of splash risk.

HYGIENE MEASURES

No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working 

with chemicals.

SKIN PROTECTION

When handling the product to prevent skin contact by splashing, wear a rubber apron. 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Liquid

COLOR Colorless

ODOR Slight odor

BOILING POINT (°C) 100

pH-VALUE, CONC. SOLUTION 6 - 8

 10 STABILITY AND REACTIVITY

STABILITY

Stable under normal temperature conditions and recommended use.

HAZARDOUS DECOMPOSITION PRODUCTS

Fire creates: Toxic gases/vapors/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Phosphorus. 

Chlorine. 11 TOXICOLOGICAL INFORMATION

TOXIC DOSE 1 - LD 50 >2000 mg/kg (oral rat)

TOXIC DOSE 2 - LD 50 >4000 mg/kg (ipr-rat)

TOXICOLOGICAL INFORMATION

Ames Test negative

INHALATION

Harmful by inhalation. LC50 0.9 mg/L. Administered as a liquid aerosol for a single 4h nose only exposure to rats.

INGESTION

Harmful if swallowed.

SKIN CONTACT

Causes burns. Not a skin sensitizer.

EYE CONTACT

Causes burns.

HEALTH WARNINGS

This substance is corrosive. 12 ECOLOGICAL INFORMATION

ECOTOXICITY

The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the 

aquatic environment. 13 DISPOSAL CONSIDERATIONS

WASTE MANAGEMENT

When handling waste, consideration should be made to the safety precautions applying to handling of the product.

Triple rinse drums prior to recycling or disposal.

HESI101910
 Report Date : 10/03/2009 54 /

SDS NO.: 10795

Bellacide 355

DISPOSAL METHODS

Absorb in vermiculite or dry sand, dispose in licensed hazardous waste.

Liquid material should be incinerated. Material absorbed onto sand or earth should be disposed of as solid waste in 

accordance with local regulations. Empty packaging may contain product residues and due consideration should be given 

prior to disposal. 14 TRANSPORT INFORMATION

TDG SHIPPING NAME CORROSIVE LIQUID, TOXIC, N.O.S.(contains tributyl tetradecyl phosphonium chloride)

DOT PROPER SHIPPING 

NAME

CORROSIVE LIQUID, TOXIC, N.O.S.(contains tributyl tetradecyl phosphonium chloride)

TDG SHIPPING NAME CORROSIVE LIQUID, TOXIC, N.O.S.(contains tributyl tetradecyl phosphonium chloride)

IDENTIFICATION No. 2922

DOT HAZARD CLASS 8 (6.1)

DOT PACKING GROUP III

U.S DOT HAZARD LABEL Corrosive Poison

UN NO. AIR 2922

AIR CLASS 8 (6.1)

AIR PACK GR. III

TDG CLASS 8 (6.1)

DOT PACKING GROUP III 15 REGULATORY INFORMATION

INVENTORIES

COMPONENT CAN US EU AUS JAP KOR CHN PHLP

Tributyl tetradecyl phosphonium chloride DSL Yes EINECS Yes Exemp Yes Yes Yes

COMPONENT CAS CA FL MA MN NJ PA RI

Tributyl tetradecyl phosphonium chloride 81741-28-8 No No No No No No No

REGULATORY STATUS (US)

PROPOSITION 65: This product does not contain chemicals considered by the State of California's Safe Drinking Water 

and Toxic Enforcement Act of 1986 as causing cancer or reproductive toxicity and for which warnings are now required. 

SECTION 313: This product does not contain toxic chemical subject to the reporting requirements of Section 313 of Title III 

of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. EPA REGISTRATION 

NUMBER:83451-15

REGULATORY REFERENCES

29 CFR 1910.1010 Federal Regulations (OSHA Standard).

LABEL(S) FOR SUPPLY

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM -WHIMIS

Materials 

Causing 

Immediate and 

Serious Toxic 

Effect.

Corrosive 

Material.

HESI101911
 Report Date : 10/03/2009 55 /

SDS NO.: 10795

Bellacide 355

CONTROLLED PRODUCT CLASSIFICATION

Canadian WHMIS Classification D1A E

 16 OTHER INFORMATION

HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS)

HEALTH

FLAMMABILITY

PHYSICAL

PERSONAL PROTECTION D

0

0

3

(3)

(0)

(0)

N/A

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)

HEALTH

FIRE

INSTABILITY

SPECIFIC

REVISION COMMENTS

Amended MSDS

NOTE: Lines within the margin indicate significant changes from the previous revision.

Section 14 Revised Transport classification.

ISSUED BY

G.B.

REVISION DATE 6th March 2009

VERSION No. 4

SAFETY DATA SHEET STATUS

Approved.

DATE 6th March 2009

DISCLAIMER

For safety reasons it is IMPERATIVE that customers:- 

1. Ensure that all those within their control who use the products are supplied with all relevant information contained within the Safety 

Data Sheet and Technical Bulletin concerning the applications for which the product is designed and any instructions and warnings 

contained therein. 

2. Consult BWA Water Additives before using or supplying the product for any other applications. The information contained herein is 

based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It 

should not therefore be construed as guaranteeing specific properties.

HESI101912
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BENTONITE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BENTONITE

Synonyms: None

Chemical Family: Mineral

Application: Weight Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Bentonite 1302-78-9 60 - 100% Not applicable Not applicable

Crystalline silica, cristobalite 14464-46-1 0 - 1% 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

Crystalline silica, tridymite 15468-32-3 0 - 1% 0.05 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

Crystalline silica, quartz 14808-60-7 < 3 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

BENTONITE

Page 1 of 7

HESI101913
3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Treat symptomatically.

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

BENTONITE

Page 2 of 7

HESI101914
Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Do not reuse empty container.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Various

Odor: Odorless

pH: 9.9

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 60

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

BENTONITE

Page 3 of 7

HESI101915
10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause mechanical skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

BENTONITE

Page 4 of 7

HESI101916
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

BENTONITE

Page 5 of 7

HESI101917
Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

BENTONITE

Page 6 of 7

HESI101918
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BENTONITE

Page 7 of 7

HESI101919
HESI101920
HESI101921
HESI101922
SANTROL 

MATERIAL SAFETY DATA SHEET 

Issue 03 1 01/28/03 

 

1. PRODUCT AND COMPANY IDENTIFICATION 

Product Name BioBalls MR, Bioballs HR 

Manufacturer / Supplier Santrol 

 2727 FM 521 

 Fresno 

 Texas, 77545 USA 

Telephone 281-431-0670 

Facsimile 281-431-0044 

Emergency Contact 281-431-0670 (ext 124) 

 

2. COMPOSITION / INFORMATION ON COMPONENTS 

Chemical Characterisation Water soluble balls of polyvinylalcohol/polyvinylacetate copolymer, 

compounded with plasticisers and lubricants 

Contains no hazardous ingredients (91/155/EEC) 

 

3. HAZARD IDENTIFICATION 

Health Effect No hazards known 

Physical / Chemical Effects No chemical hazards known. Avoid spillage and use under conditions 

of good industrial hygiene. 

 

4. FIRST AID MEASURES 

After eye contact No known adverse effects 

After skin contact Wash skin with soap and water. 

After ingestion Small diameter balls represent a choking hazard. If ingested, seek 

immediate medical attention. 

 

5. FIRE FIGHTING MEASURES 

Extinguishing Media Use water spray, alcohol resistant foam, dry chemical or CO2. 

Special Hazards This product may give rise to hazardous fumes in a fire. 

Protective Equipment Wear chemical protection suit, suitable boots and gloves as well as selfcontained breathing apparatus. 

 

6. ACCIDENTAL RELEASE MEASURES 

Personal Precautions When wet, residue from these water-soluble balls may present a slip 

hazard. 

HESI101923
SANTROL 

MATERIAL SAFETY DATA SHEET 

Issue 03 2 01/28/03 

Environmental Precautions Try to prevent material from entering sewers or water-courses. Advise 

authorities if spillage as entered watercourse or sewer or has 

contaminated soil or vegetation. 

Spillage Transfer to suitable containers for recovery or disposal. 

 

7. HANDLING & STORAGE 

Handling Keep container tightly closed when not in use. Do not eat, drink or 

smoke whilst handling the product. 

Storage Storage area should be cool, dry and well ventilated. 

 

8. EXPOSURE CONTROL / PERSONAL PROTECTION 

Control Parameters None applicable 

Hand Protection For sensitive skin, prolonged contact may require the use of gloves. 

 Wash hands during breaks and at end of work period. 

Eye Protection Not required. 

Skin and Body Protection No special clothing required. 

 

9. PHYSICAL & CHEMICAL PROPERTIES 

Colour Off white / Natural 

Form Solid balls of various diameters 

Odour None/Slightly vinegary 

PH 6-8 in aqueous solution 

Boiling point / range N/A 

Melting point / range 150-230°C by DSC 

Flash Point (Open Cup) N/A 

Flammability N/A 

Autoignition Temperature >300°C 

Explosive Properties N/A 

Oxidising Properties N/A 

Vapour Pressure N/A 

Bulk Density 1.18 g/cc. 

Solubility (H2O) Soluble 

Solubility (ethyl acetate/ 

isopropanol/acetone/ 

dichloromethane/ether) Insoluble 

Partition Coefficient 

(n-octanol/H2O) N/A 

 

10. STABILITY & REACTIVITY 

Stability Stable under normal conditions. No unusual reactivity. 

Materials to Avoid Strong mineral acids, alkalis, bases and oxidising agents, except where 

contact with these is as part of the products functionality. 

HESI101924
SANTROL 

MATERIAL SAFETY DATA SHEET 

Issue 03 3 01/28/03 

Hazardous Decomposition 

Products Combustion will generate: oxides of Carbon, smoke and irritating 

fumes. 

 

11. TOXICOLOGICAL INFORMATION 

Polyvinylalcohol / Polyvinylacetate Co-polymer: 

RTECS # TR8100000 

LD50 / oral / rat >20 g/kg 

LD50 / oral / mice >20 g/kg 

All other components are non-toxic and by analogy with similar products are expected to have LD50 / oral / 

rat: >=3,000 mg/kg 

 

12. ECOLOGICAL INFORMATION 

This product is essentially a compound of polyvinylalcohol / polyvinylacetate co-polymer. All components 

are expected to be biodegradable. It contains no materials constituting a long-term environmental hazard 

and poses little or no risk of bioaccumulation. 

The components of this product are not expected to cause long-term adverse effects to the aquatic 

environment. By analogy to similar products, the toxicity of this product to fish (LD50 /96hr) when tested 

in pure water is expected to be >1,000 ppm. 

 

13. DISPOSAL 

This product is classified as non-hazardous. Dispose of in accordance with local regulations. 

 

14. TRANSPORT INFORMATION 

Not classified as Hazardous for transport by Road, Rail, Air or Sea. 

 

15. REGULATORY INFORMATION 

Supply Classification Not classified as hazardous to users 

Hazard Symbol N/A 

Risk Phrases N/A 

Safety Phrases N/A 

 

16. OTHER INFORMATION 

Recommended Use Intended for use in applications where the plugging of perforation 

outlets in oil wells is required for a short period of time. 

EINECS All components of this product are considered notified in EINECS 

within the meaning of Directive 92/32/EEC; Art.13.2. 

TSCA All components of this product are considered TSCA listed. 

AICS All components of this product are considered AICS listed. 

HESI101925
SANTROL 

MATERIAL SAFETY DATA SHEET 

Issue 03 4 01/28/03 

DSL/NDSL All components of this product are considered DSL listed. 

MITI All components of this product are considered MITI listed. 

FDA Conformance All components of this product are in compliance with FDA CFR-21 

Part 175.300 or are recognised food additives. 

BGA Conformance N/A 

Date :26th February 2001 

Compiled by: P.R. Okell 

HESI101926
SANTROL Material Safety Data Sheet

BioBalls

Page 1 

Section I

Manufacturer's Name Telephone/Fax Number

Santrol, Inc. (281) 431-0670 F(281) 431-0044 

2727 FM 521 

Fresno, TX 77545 Original Date:8/14/98 Revised: 3/26/99 

Section II - Hazardous Ingredients

Hazardous components CAS # % by Wt. OSHA PEL ACGIH TLV OTHER 

Collagen 9000-70-8 Trade Secret N/E N/E 

Glycerol 56-81-5 Trade Secret 10 mg/m3 TWA N/E 

Methyl Salicylate 119-36-8 Trade Secret N/E N/E 

Hazard Rating Scale: Product: 

0-Minimal 3-Serious Health: 0 

1-Slight 4-Severe Fire: 0 

2-Moderate Reactivity: 0 

Special: None 

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency 

Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: 

CAS# Chemical Name % by Weight 

None None 

Section III - Physical/Chemical Characteristics

Boiling Point: N/A Specific Gravity (H2O=1): 1.1 

Vapor Pressure (mmHg): N/A at 20o

C Melting Point: 150o F 

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A 

Solubility in Water: Soluble in all proportions 

Appearance and Odor: Appearance of light brown sphere no appreciable odor 

HESI101927
SANTROL Material Safety Data Sheet

BioBalls

Page 2 

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) None 

Flammable Limits in air, % Lower: None Upper: None. 

Extinguishing Media: Water, Carbon Dioxide, Foam, Dry Chemical. 

Special Fire Fighting Procedures: None. 

Unusual Fire and Explosion Hazards: None 

Section V - Reactivity Data

Stability: Stable Polymerization will not occur. 

Conditions to avoid: N/A 

Materials to avoid: N/A 

Hazardous decomposition products: May liberate oxides of carbon in smoke. 

Section VI - Health Hazard Data

Carcinogenicty: Not carcinogenic IARC, NTP, OSHA 

Primary Routes of exposure: Swallowing, or eye contact 

Emergency and First Aid Procedures: 

Inhalation: Not Inhalable. 

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical 

attention. 

Skin contact: N/A. 

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate 

medical attention. 

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released: 

Surfaces could become slippery due to the round nature of product. Sweep up or pick spilled material to prevent 

falls. Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste. 

Precautions to Be Taken in Handling and Storing: 

Keep away from excess heat (+120 o F). Store in a cool, dry place. 

Repair and Maintenance Precautions: 

Do not cut, grind, weld, or drill on or near this container. 

Other Precautions: 

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard 

warnings and handle empty containers as if they were full. 

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at the 

point of use. 

Ventilation: Local mechanical exhaust ventilation is recommended in confined spaces or assure natural air 

HESI101928
SANTROL Material Safety Data Sheet

BioBalls

Page 3 

movement.. 

Eye Protection: Eye Goggles 

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes. 

Other Precautions: None 

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance Act 

(FHSA) criteria. 

Dermal: This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is not 

lethal when applied to the skin of rabbits under the FHSA criteria. 

HOCNF: Biodegredation OECD guideline 306 for testing of chemicals. BioBalls were degraded by 76% after 28 days 

based on COD calculations and measurements to account for O2 consumption. The substance can be 

characterized as readily biodegradable in the marine environment according to the OED guideline 306 

(1992). 

Sediment Phase Toxicity The Corophium volutator sediment reworker test was performed on BioBalls based on 

the draft from the 1994 of the Paris Commission guideline “MAFF/ERT Harmonized Protocol using a 

sediment Bioassay with an amphipod Corophium sp. The ten day LC50 value for the test substance 

BioBalls was 5.040.7 mg/kg of sediment (dry weight). Confidence range 2,566 - 9,900 mg/kg of dry 

weight sediment. The test met the validity requirements with regard to control mortality. The control 

parameters temperature, dissolved oxygen, pH and salinity were within the recommended ranges. UK 

revised OCNS group D (since LC50 is between 1,000 - 10,000 ppm). The Norwegian Pollution Control 

Authority (SFT) regards Corophium LC50 >1,000 mg/kg of dry weight sediment to be acceptable for 

unused and used drilling muds. 

Toxicity Test Results with Arcartia tonsa. Testing with BioBalls on Marine Copepods Arcartia tonsa showed 

the LC50 after 48 hours to be 200 mg/l. The 95% confidence range was 180-220 mg/l. The LC10 value was 

estimated to 115 mg/l, the LC90 value was estimated to 360 mg/l, and the NOEC value was estimated to 

100 mg/l. Based on the mean value the BioBall substance cannot be classified as harmful according to 

the EEC classification system. 

 

Toxicity Test Results with Skeletonema costatum. Testing BioBalls with Skeletonema costatum based on 

ISO 102 53: “Water Quality Marine Algal Growth Inhibition Test with Skeletonema costatum and 

Phaeodactylum tricornutum.

 The EC50 value found for BioBalls after 72 hours was 105 mg/l. The 95% confidence limit could not be 

calculated. The EC10 value was estimated to 56 mg/l, the EC90 value was estimated to 200 mg/l and the 

NOEC value (EC2.4) was estimated to 50 mg/l. Based on the mean value, the test substance BioBalls 

cannot be classified as harmful according to the EEC classification system. 

Toxicity Test Results with Juvenile Turbot Scophthalmus maximus. BioBalls were assessed for potential 

toxicity to juvenile turbot in semi-static test over 96 hours in accordance with the PARCOM method 1995, 

OECD guideline 203 and as detailed in Hyder SOP III.6. Concentrations of BioBall material were 

prepared over the range 100.0 mg l -1 to 1000.0 mg l -1 . Juvenile turbot were exposed to the test 

concentration in order to determine the concentration which killed 50% of the test organisms over 96 

hours (LC50). From this study the LC50 was determined to be 421.7 mg l -1 . 

 Compiled P.R. Okell 3/26/99 

 

HESI101929
SANTROL Material Safety Data Sheet

BioBalls

Page 4 

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided herein. 

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes no 

representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their own 

operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon, information 

contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.

HESI101930
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BP-10

Revision Date: 03-Apr-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BP-10

Synonyms: None

Chemical Family: Polysaccharide

Application: Viscosifier

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Xanthan gum 11138-66-2 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

BP-10

Page 1 of 6

HESI101931
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 950

Flash Point/Range (C): 510

Flash Point Method: Not Determined

Autoignition Temperature (F): 400

Autoignition Temperature (C): 204

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.04 - 0.4

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Slippery when wet. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 6

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

BP-10

Page 2 of 6

HESI101932
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White to yellow

Odor: Slight

pH: 5.5-8.5

Specific Gravity @ 20 C (Water=1): 1.6

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 52.4

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 1,000,000

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May impede respiration.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

BP-10

Page 3 of 6

HESI101933
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 200 mg/g COD: 1600 mg/g

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 320-560 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM96: > 75000 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

BP-10

Page 4 of 6

HESI101934
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

BP-10

Page 5 of 6

HESI101935
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BP-10

Page 6 of 6

HESI101936
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Baroid Fluid Services

a Product Service Line of Halliburton Energy Services, Inc.

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium chloride 10043-52-4 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Page 1 of 5

HESI101937
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Odorless

pH: 5.2

Specific Gravity @ 20 C (Water=1): 1.01-1.39

Density @ 20 C (lbs./gallon): 8.4-11.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Page 2 of 5

HESI101938
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): 230

Boiling Point/Range (C): 110

Freezing Point/Range (F): 39.5

Freezing Point/Range (C): 4

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause severe skin irritation. May cause skin burns on prolonged contact.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Page 3 of 5

HESI101939
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Page 4 of 5

HESI101940
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CALCIUM CHLORIDE BRINE 8.4-11.6 PPG

Page 5 of 5

HESI101941
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CALCIUM CHLORIDE - FLAKE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CALCIUM CHLORIDE - FLAKE

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium chloride 10043-52-4 60 - 100% Not applicable Not applicable

Sodium chloride 7647-14-5 1-2 Not applicable Not applicable

Potassium chloride 7447-40-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CALCIUM CHLORIDE - FLAKE

Page 1 of 5

HESI101942
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 10

Specific Gravity @ 20 C (Water=1): 1.85

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 56

CALCIUM CHLORIDE - FLAKE

Page 2 of 5

HESI101943
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 98

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 111

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns on prolonged contact.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1000 mg/kg (Rat)

Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CALCIUM CHLORIDE - FLAKE

Page 3 of 5

HESI101944
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

CALCIUM CHLORIDE - FLAKE

Page 4 of 5

HESI101945
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CALCIUM CHLORIDE - FLAKE

Page 5 of 5

HESI101946
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CALCIUM CHLORIDE - HI-TEST PELLETS

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CALCIUM CHLORIDE - HI-TEST PELLETS

Synonyms: None

Chemical Family: Inorganic Salt

Application: Accelerator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium chloride 10043-52-4 94-96 Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CALCIUM CHLORIDE - HI-TEST PELLETS

Page 1 of 5

HESI101947
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 10

Specific Gravity @ 20 C (Water=1): 2.2

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 55

CALCIUM CHLORIDE - HI-TEST PELLETS

Page 2 of 5

HESI101948
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): 1500

Boiling Point/Range (C): 815

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 60

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 111

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause skin burns on prolonged contact.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1000 mg/kg (Rat)

Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CALCIUM CHLORIDE - HI-TEST PELLETS

Page 3 of 5

HESI101949
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

CALCIUM CHLORIDE - HI-TEST PELLETS

Page 4 of 5

HESI101950
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CALCIUM CHLORIDE - HI-TEST PELLETS

Page 5 of 5

HESI101951
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CARBO-PROP PROPPANT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CARBO-PROP PROPPANT

Synonyms: None

Chemical Family: Mineral

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum oxide 1344-28-1 30-70 10 mg/m3 10 mg/m3

Crystalline silica, cristobalite 14464-46-1 <1 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. May cause delayed injury to lungs. Potential carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

CARBO-PROP PROPPANT

Page 1 of 6

HESI101959
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark green

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.28

Density @ 20 C (lbs./gallon): Not Determined

CARBO-PROP PROPPANT

Page 2 of 6

HESI101960
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 110

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause silicosis, which reduces lung function. The lung damage can lead to

heart problems.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity Contains crystalline silica which may cause silicosis, a delayed and progressive lung

disease. The IARC and NTP have determined there is sufficient evidence in humans

of the carcinogenicity of crystalline silica with repeated respiratory exposure.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

CARBO-PROP PROPPANT

Page 3 of 6

HESI101961
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

CARBO-PROP PROPPANT

Page 4 of 6

HESI101962
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum Oxide//1344-28-1

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CARBO-PROP PROPPANT

Page 5 of 6

HESI101963
CARBO-PROP PROPPANT

Page 6 of 6

HESI101964
CARBOACCUCAST® LD(All Mesh Sizes) 

MSDS NO: 05 

REVISION DATE: February 27, 2007 

MATERIAL SAFETY DATA SHEET PAGE 1 OF 3 

1. PRODUCT AND COMPANY IDENTIFICATION 

TRADE NAME: CARBOACCUCAST® LD (All Mesh Sizes) 

SYNONYM(S): Ceramic Proppant; Semi-Crystalline Alumina Silicate 

CHEMICAL FAMILY: Aluminosilicate 

MANUFACTURER: CARBO Ceramics 

4810 Industrial Drive 

New Iberia, Louisiana 70560 

 Phone: 1-337-367-6151 

EMERGENCY PHONE: 1-800-551-3247 (U.S.A.) 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

INGREDIENTS CAS NUMBER CONCENTRATION CLASSIFICATION R-PHRASES 

Silicon Dioxide, (amorphous 

as glass) 7631-86-9 5-35% Not Classified Not assigned 

Mullite 1302-93-8 60-85% Not Classified Not assigned 

Silica Crystalline-Cristobalite 14464-46-1 0-20% Not Classified Not assigned 

3. HEALTH HAZARD INFORMATION 

INHALATION: Inhalation of dusts may cause respiratory tract irritation. Repeated or prolonged breathing of particles of respirable 

size may cause severe respiratory disease. However, this product contains few particles of respirable size. 

Repeated indoor air quality monitoring and testing conducted throughout the production and shipping process at 

CARBO Ceramics Inc. Ceramics, Inc. shows that the final product produces levels of respirable silica (in the form of 

crystalline crystobalite) below laboratory detection limits and applicable exposure limits (see section 8). The amount 

of dust due to breakdown during shipment and handling is not expected to exceed applicable exposure limits (see 

section 8). Analyses for crystalline forms of silica at CARBO Ceramics Inc. Ceramics, Inc. facilities were performed 

by X-ray diffraction based upon OSHA ID 142 guidelines. 

EYE CONTACT: Airborne dust may cause irritation to eyes. 

SKIN CONTACT: Prolonged contact with a skin may cause irritation. 

HMIS RATING: HEALTH 1 (slight) FLAMMABILITY 0 (minimal) REACTIVITY 0 (minimal) SPECIAL PROTECTION: 

(See section 8) 

4. FIRST AID MEASURES 

INHALATION: Remove affected person from source of exposure. Get medical attention if irritation occurs. 

INGESTION: Seek medical attention if large quantities are ingested. 

EYE CONTACT: Immediately flush eyes with large amounts of water, lifting the lower and upper lids occasionally. If irritation is 

present after washing, get medical attention. 

SKIN CONTACT: Wash the affected area with soap and water. Get medical attention if irritation occurs. 

5. FIRE-FIGHTING MEASURES 

ESTIMATED EXPLOSIVE LIMITS (% By volume in air): LEL: N/A UEL: N/A FLASH POINT: N/A 

SPECIAL FIRE FIGHTING PROCEDURES: This material does not give a flash point by conventional test methods. Use 

extinguishing agent suitable for type of surrounding fire. 

UNUSUAL HAZARDS: N/A 

6. SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: No Special procedures are required for clean-up of spills or 

leaks of this material. Caution should be exercised regarding personal safety and exposure to the spilled material, the material’s nature 

could cause reduced traction. Persons should take care so as not to slip. 

HESI101952
CARBOACCUCAST® LD(All Mesh Sizes) 

MSDS NO: 05 

REVISION DATE: February 27, 2007 

MATERIAL SAFETY DATA SHEET PAGE 2 OF 3 

7. HANDLING AND STORAGE 

HANDLING: Do not create dust. Use personal protective equipment. Refer to section 8 for personal protective equipment. 

STORAGE: Store dry in closed container to reduce dust. 

8. EXPOSURE CONTROLS/PROTECTION DURING USE 

EXPOSURE LIMITS: INGREDIENTS OSHA PEL-TWA ACGIH-TWA TLV 

 

Silicon Dioxide, amorphous as 

glass 80 mg/m3

/%SiO2 (total) - 

 

 Mullite 15 mg/m3 (total) 10 mg/m3 (total) 

 5 mg/m3 (respirable) 3 mg/m3 (resp) 

Silica Crystalline Cristobalite 15 mg/m3

/(%SiO2+2) (total) 

 5 mg/m3

/(%SiO2+2) 

(respirable) 

0.05 mg/m3 

(respirable)

ENGINEERING CONTROL 

MEASURES: 

Exposure to this material may be controlled in a number of ways. The measures 

appropriate for a particular worksite depend on how the material is used and the potential 

for exposure. Use of the basic principles of industrial hygiene will enable safe handling of 

the material. 

RESPIRATORY: An applicable NIOSH/MSHA or equivalent approved respirator should be worn where 

airborne exposures may exceed OSHA/ACGIH permissible air concentrations. 

EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact 

lenses when working with this substance unless protected under full coverage goggles. 

CLOTHING/GLOVES: Gloves are optional to reduce abrasion. 

WORK HYGIENE PRACTICES: Handle in accordance with good personal hygiene and safety practices. 

VENTILATION: Provide sufficient (general and/or local exhaust) ventilation to maintain exposure below 

permissible air concentrations. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

BOILING POINT: N/A °

F SPECIFIC GRAVITY: 2.7 (H2O=1) pH: N/A 

MELTING POINT: 4000 °

F (estimated) BULK DENSITY: 97 lb/cu.ft. 

VAPOR PRESSURE: N/A mm Hg % VOLATILE BY 

WEIGHT: 

N/A 

VAPOR DENSITY: N/A (Air=1) EVAPORATION RATE: N/A (Butyl Acetate=1) 

APPEARANCE/ODOR: Odorless cream to light–gray spheres SOLUBILITY IN WATER: Insoluble 

VOLATILE ORGANIC COMPOUNDS (VOC): 0 lbs/gal (EPA Reference Methods 24) 

10. STABILITY AND REACTIVITY 

REACTIVITY: Minimal 

STABILITY: Stable 

INCOMPATIBLE MATERIALS: Chlorine Triflouride. 

11. TOXICOLOGICAL INFORMATION 

ACUTE EFFECTS Coughing and throat irritation are early symptoms of excessive exposure. Acute pneumoconiosis from 

excessive exposure to silica dust has occurred. May be irritating to the respiratory system, lungs and skin. 

May also cause irritation to eyes. 

CHRONIC EFFECTS: Inhalation of respirable crystalline-crystobalite in excess of established human exposure values is known to 

cause human cancer. Chronic exposure can cause severe respiratory disease. 

HESI101953
CARBOACCUCAST® LD(All Mesh Sizes) 

MSDS NO: 05 

REVISION DATE: February 27, 2007 

MATERIAL SAFETY DATA SHEET PAGE 3 OF 3 

12. ECOLOGICAL INFORMATION 

This product poses no significant environmental contamination impact during expected use, handling, and proper disposal. 

13. DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL: Disposal must be at an approved waste disposal facility and in accordance with applicable Federal, State and 

Local laws and regulations. Contact the district Director of the Environmental Protection Agency and/or state regulatory agency for 

appropriate requirements. 

14. TRANSPORTATION INFORMATION 

UN NO. N/A 

ICAO/IATA Not Restricted 

RID/ADR Not Restricted 

DOT SHIPPING DESCRIPTION Not Restricted 

CAN Not Restricted 

IMO Not Restricted 

15. REGULATORY INFORMATION 

TOXIC SUBSTANCE CONTROL ACT (TSCA) STATUS: All chemicals in this product are 

listed, automatically included, or are exempt from listing on the TSCA Inventory. 

SARA TITLE III: Section 302: 

Section 312: 

Section 313: 

None 

None 

None 

CERCLA REPORTABLE QUANTITY: None 

CLEAN AIR AMENDMENTS-HAZARDOUS AIR POLLUTANTS (HAPS): None 

CALIFORNIA STATE PROPOSITION 65: Silica, crystalline (airborne particles of respirable size) 

 

16. OTHER INFORMATION 

HESI101954
CARBO CERAMICS 

 

CARBOACCUCAST T M LD 60 Physical and Chemical Properties 

 Sieve Analysis

 U.S. Mesh (microns) Specification Average 

+30 (+600) 0 0 

-30/+40 (-600/+425) 0-10 .8 

-40/+50 (-425/+300) 21-47 34.1 

-50/+70 (-300/+212) 17-38 27.7 

-70/+100 (-212/+150) 12-30 21.7 

-100/+140 (-150/+106) 9-20 14.8 

-140/+200 (-106/+75) 0-10 2.1 

-200/+270 (-75/+53) 0 0 

Pan 0 0 

GFN 58 – 63 60 

Median Particle Diameter (microns) 271 

 

Compressisve Strength, by % -140 mesh 

particulate generated) @ 5 kpsi 5.0 (max) 2.9 

Roundness 0.8 (min) 0.9 

Sphericity 0.8 (min) 0.9 

Bulk Density

(g/cc) 1.44 – 1.55 1.47 

Apparent Specific Gravity 2.60 – 2.78 2.71 

pH 6.0 - 8.0 7.8 

% Moisture 0.0 – 0.1 0.01 

 

Chemical Analysis

Chemistry (weight %) 

 Al2O3 42.0 - 52.0 47.7 

 

 SiO2 43.5 - 54.5 48.5 

 

 TiO2 1.1 - 3.1 2.1 

 

 Fe2O3 0.5 - 1.5 1.0 

 

 

 Other 0.2 - 1.2 0.7 

 

Controlled D-255.LD60 Rev1 effective 7/20/05

HESI101955
CARBOHYDROPROPTM (All Mesh 

Sizes) 

MSDS NO: 10 

REVISION DATE: December 11, 2007 

MATERIAL SAFETY DATA SHEET PAGE 1 OF 3 

1. PRODUCT AND COMPANY IDENTIFICATION 

TRADE NAME: CARBOHYDROPROP TM (All Mesh Sizes) 

SYNONYM(S): Ceramic Proppant; Semi-Crystalline Alumina Silicate 

CHEMICAL FAMILY: Aluminosilicate 

MANUFACTURER: CARBO Ceramics 

4810 Industrial Drive 

New Iberia, Louisiana 70560 

 Phone: 1-337-367-6151 

EMERGENCY PHONE: 1-800-551-3247 (U.S.A.) 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

INGREDIENTS CAS NUMBER CONCENTRATION CLASSIFICATION R-PHRASES 

Silicon Dioxide, (amorphous 

as glass) 7631-86-9 0 - 10% Not Classified Not assigned 

Mullite 1302-93-8 65 - 85% Not Classified Not assigned 

Silica Crystalline-Cristobalite 14464-46-1 15 - 30% Not Classified Not assigned 

3. HEALTH HAZARD INFORMATION 

INHALATION: Inhalation of dusts may cause respiratory tract irritation. Repeated or prolonged breathing of particles of respirable 

size may cause severe respiratory disease. However, this product contains few particles of respirable size. 

Repeated indoor air quality monitoring and testing conducted throughout the production and shipping process at 

CARBO Ceramics, Inc. shows that the final product produces levels of respirable silica (in the form of crystalline 

crystobalite) below laboratory detection limits and applicable exposure limits (see section 8). The amount of dust 

due to breakdown during shipment and intended use and handling is not expected to exceed applicable exposure 

limits (see section 8). Analyses for crystalline forms of silica at CARBO Ceramics, Inc. facilities were performed by 

X-ray diffraction based upon OSHA ID 142 guidelines. 

EYE CONTACT: Airborne dust may cause irritation to eyes. 

SKIN CONTACT: Prolonged contact with a skin may cause irritation. 

HMIS RATING: HEALTH 1 (slight) FLAMMABILITY 0 (minimal) REACTIVITY 0 (minimal) SPECIAL PROTECTION: 

(See section 8) 

4. FIRST AID MEASURES 

INHALATION: Remove affected person from source of exposure. Get medical attention if irritation occurs. 

INGESTION: Seek medical attention if large quantities are ingested. 

EYE CONTACT: Immediately flush eyes with large amounts of water, lifting the lower and upper lids occasionally. If irritation is 

present after washing, get medical attention. 

SKIN CONTACT: Wash the affected area with soap and water. Get medical attention if irritation occurs. 

5. FIRE-FIGHTING MEASURES 

ESTIMATED EXPLOSIVE LIMITS (% By volume in air): LEL: N/A UEL: N/A FLASH POINT: N/A 

SPECIAL FIRE FIGHTING PROCEDURES: This material does not give a flash point by conventional test methods. Use 

extinguishing agent suitable for type of surrounding fire. 

UNUSUAL HAZARDS: N/A 

6. SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: No Special procedures are required for clean-up of spills or 

leaks of this material. Caution should be exercised regarding personal safety and exposure to the spilled material, the material’s nature 

could cause reduced traction. Persons should take care so as not to slip. 

HESI101956
CARBOHYDROPROPTM (All Mesh 

Sizes) 

MSDS NO: 10 

REVISION DATE: December 11, 2007 

MATERIAL SAFETY DATA SHEET PAGE 2 OF 3 

7. HANDLING AND STORAGE 

HANDLING: Do not create dust. Use personal protective equipment. Refer to section 8 for suggested personal protective 

equipment. 

STORAGE: Store dry in closed container to reduce dust. 

8. EXPOSURE CONTROLS/PROTECTION DURING USE 

EXPOSURE LIMITS: INGREDIENTS OSHA PEL-TWA ACGIH-TWA TLV 

 

Silicon Dioxide, amorphous as 

glass 80 mg/m3

/%SiO2 (total) - 

 

 Mullite 15 mg/m3 (total) 10 mg/m3 (total) 

 5 mg/m3 (respirable) 3 mg/m3 (resp) 

Silica Crystalline Cristobalite 15 mg/m3

/(%SiO2+2) (total) 

 5 mg/m3

/(%SiO2+2) 

(respirable) 

0.05 mg/m3 

(respirable) 

ENGINEERING CONTROL 

MEASURES: 

Exposure to this material may be controlled in a number of ways. The measures 

appropriate for a particular worksite depend on how the material is used and the potential 

for exposure. Use of the basic principles of industrial hygiene will enable safe handling of 

the material. 

RESPIRATORY: An applicable NIOSH/MSHA or equivalent approved respirator should be worn where 

airborne exposures may exceed OSHA/ACGIH permissible air concentrations. 

EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact 

lenses when working with this substance unless protected under full coverage goggles. 

CLOTHING/GLOVES: Gloves are optional to reduce abrasion. 

WORK HYGIENE PRACTICES: Handle in accordance with good personal hygiene and safety practices. 

VENTILATION: Provide sufficient (general and/or local exhaust) ventilation to maintain exposure below 

permissible air concentrations. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

BOILING POINT: N/A °

F SPECIFIC GRAVITY: 2.55 (H2O=1) pH: N/A 

MELTING POINT: 4000 °

F (estimated) BULK DENSITY: 87 lb/cu.ft. 

VAPOR PRESSURE: N/A mm Hg % VOLATILE BY 

WEIGHT: 

N/A 

VAPOR DENSITY: N/A (Air=1) EVAPORATION RATE: N/A (Butyl Acetate=1) 

APPEARANCE/ODOR: Odorless cream to light–gray spheres SOLUBILITY IN WATER: Insoluble 

VOLATILE ORGANIC COMPOUNDS (VOC): 0 lbs/gal (EPA Reference Methods 24) 

10. STABILITY AND REACTIVITY 

REACTIVITY: Minimal 

STABILITY: Stable 

INCOMPATIBLE MATERIALS:: Chlorine Triflouride. 

11. TOXICOLOGICAL INFORMATION 

ACUTE EFFECTS Coughing and throat irritation are early symptoms of excessive exposure. Acute pneumoconiosis from 

excessive exposure to silica dust has occurred. May be irritating to the respiratory system, lungs and skin. 

May also cause irritation to eyes. 

CHRONIC EFFECTS: Inhalation of respirable crystalline-crystobalite in excess of established human exposure values is known to 

cause human cancer. Chronic exposure can cause severe respiratory disease. 

HESI101957
CARBOHYDROPROPTM (All Mesh 

Sizes) 

MSDS NO: 10 

REVISION DATE: December 11, 2007 

MATERIAL SAFETY DATA SHEET PAGE 3 OF 3 

12. ECOLOGICAL INFORMATION 

This product poses no significant environmental contamination impact during expected use, handling, and proper disposal. 

13. DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL: Disposal must be at an approved waste disposal facility and in accordance with applicable Federal, State and 

Local laws and regulations. Contact the district Director of the Environmental Protection Agency and/or state regulatory agency for 

appropriate requirements. 

14. TRANSPORTATION INFORMATION 

UN NO. N/A 

ICAO/IATA Not Restricted 

RID/ADR Not Restricted 

DOT SHIPPING DESCRIPTION Not Restricted 

CAN Not Restricted 

IMO Not Restricted 

15. REGULATORY INFORMATION 

TOXIC SUBSTANCE CONTROL ACT (TSCA) STATUS: All chemicals in this product are 

listed, automatically included, or are exempt from listing on the TSCA Inventory. 

SARA TITLE III: Section 302: 

Section 312: 

Section 313: 

None 

None 

None 

CERCLA REPORTABLE QUANTITY: None 

CLEAN AIR AMENDMENTS-HAZARDOUS AIR POLLUTANTS (HAPS): None 

CALIFORNIA STATE PROPOSITION 65: Silica, crystalline (airborne particles of respirable size) 

 

16. OTHER INFORMATION 

HESI101958
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAT-OS-2

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAT-OS-2

Synonyms: None

Chemical Family: Blend

Application: Chelating agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylenediaminetetraacetic

acid, tetrasodium salt

64-02-8 30 - 60% Not applicable Not applicable

Nitrilotriacetic acid, trisodium

salt monohydrate

5064-31-3 1 - 5% Not applicable Not applicable

Sodium hydroxide 1310-73-2 1 - 5% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. Potential

carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAT-OS-2

Page 1 of 6

HESI101965
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Mild amine

pH: 11.5

Specific Gravity @ 20 C (Water=1): 1.31

CAT-OS-2

Page 2 of 6

HESI101966
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 10.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 223

Boiling Point/Range (C): 106

Freezing Point/Range (F): -24

Freezing Point/Range (C): -31

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong oxidizers. Prolonged contact with aluminum.

Hazardous Decomposition

Products

Oxides of nitrogen. Flammable hydrogen gas. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation.

Eye Contact Causes severe eye irritation

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains nitrilotriacetic acid or its salts, which is listed as a suspect carcinogen of the

urinary tract and kidneys by NTP, based on feeding studies with laboratory animals.

According to the ACGIH guidelines, NTA would "not be considered an occupational

carcinogen of any significance." IARC cancer review classification: 2B (Possibly

Carcinogenic to Humans)

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

CAT-OS-2

Page 3 of 6

HESI101967
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

CAT-OS-2

Page 4 of 6

HESI101968
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 9165 Gallons based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

D2B Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CAT-OS-2

Page 5 of 6

HESI101969
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAT-OS-2

Page 6 of 6

HESI101970
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAUSTIC SODA LIQUID - 50%

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAUSTIC SODA LIQUID - 50%

Synonyms: None

Chemical Family: Hydroxide

Application: pH Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 30 - 60% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAUSTIC SODA LIQUID - 50%

Page 1 of 6

HESI101971
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong acids. Reaction with steel and certain other

metals generates flammable hydrogen gas.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Odorless

CAUSTIC SODA LIQUID - 50%

Page 2 of 6

HESI101972
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 14

Specific Gravity @ 20 C (Water=1): 1.52

Density @ 20 C (lbs./gallon): 12.7

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 291

Boiling Point/Range (C): 144

Freezing Point/Range (F): 54

Freezing Point/Range (C): 12

Vapor Pressure @ 20 C (mmHg): 13 @ 60C

Vapor Density (Air=1): Not Determined

Percent Volatiles: < 50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Soluble in alcohols

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 40

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Peroxides. Halogenated compounds. Amphoteric metals such as

aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 140-340 mg/kg (Rat)

Dermal Toxicity: LD50: 1350 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

CAUSTIC SODA LIQUID - 50%

Page 3 of 6

HESI101973
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1824,Sodium Hydroxide Solution, 8, II

RQ (Sodium Hydroxide - 908 kg.)

NAERG 154

Canadian TDG

Sodium Hydroxide Solution, 8, UN1824, II

ADR

UN1824,Sodium Hydroxide Solution, 8, II

Air Transportation

ICAO/IATA

UN1824,Sodium Hydroxide Solution, 8, II

RQ (Sodium Hydroxide - 908 kg.)

CAUSTIC SODA LIQUID - 50%

Page 4 of 6

HESI101974
Sea Transportation

IMDG

UN1824,Sodium Hydroxide Solution, 8, II

RQ (Sodium Hydroxide - 908 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 155 Gallons based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CAUSTIC SODA LIQUID - 50%

Page 5 of 6

HESI101975
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAUSTIC SODA LIQUID - 50%

Page 6 of 6

HESI101976
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAUSTIC FLAKE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAUSTIC FLAKE

Synonyms: None

Chemical Family: Hydroxide

Application: pH Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 60 - 100% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAUSTIC FLAKE

Page 1 of 6

HESI101977
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong acids. Reaction with steel and certain other

metals generates flammable hydrogen gas.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to off white

Odor: Odorless

pH: 14

CAUSTIC FLAKE

Page 2 of 6

HESI101978
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.13

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 71.5

Boiling Point/Range (F): 2535

Boiling Point/Range (C): 1390

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Soluble in alcohols

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 40

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Peroxides. Halogenated compounds. Prolonged contact with

aluminum, lead, or zinc may liberate flammable hydrogen.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns. May cause chemical pneumonia.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 140-340 mg/kg (Rat)

Dermal Toxicity: LD50: 1350 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

CAUSTIC FLAKE

Page 3 of 6

HESI101979
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1823,Sodium Hydroxide, Solid, 8, II

NAERG 154

Canadian TDG

Sodium Hydroxide, Solid, 8, UN1823, II

ADR

UN1823,Sodium Hydroxide, Solid, 8, II

Air Transportation

ICAO/IATA

UN1823,Sodium Hydroxide, Solid, 8, II

CAUSTIC FLAKE

Page 4 of 6

HESI101980
Sea Transportation

IMDG

UN1823,Sodium Hydroxide, Solid, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CAUSTIC FLAKE

Page 5 of 6

HESI101981
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAUSTIC FLAKE

Page 6 of 6

HESI101982
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAUSTIC SODA

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAUSTIC SODA

Synonyms: None

Chemical Family: Hydroxide

Application: pH Control

Manufacturer/Supplier Baroid Fluid Services

Product Service Line of Halliburton

P.O. Box 1675

Houston, TX 77251

Telephone: (281) 871-4000

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 60 - 100% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAUSTIC SODA

Page 1 of 6

HESI101983
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong acids. Reaction with steel and certain other

metals generates flammable hydrogen gas.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from acids. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection HEPA Respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to off white

Odor: Odorless

pH: 14

Specific Gravity @ 20 C (Water=1): 2.13

CAUSTIC SODA

Page 2 of 6

HESI101984
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 71.5

Boiling Point/Range (F): 2535

Boiling Point/Range (C): 1390

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Soluble in alcohols

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 40

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Contact with acids. Peroxides. Halogenated compounds. Prolonged contact with

aluminum, lead, or zinc may liberate flammable hydrogen.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns. May cause chemical pneumonia.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 140-340 mg/kg (Rat)

Dermal Toxicity: LD50: 1350 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

CAUSTIC SODA

Page 3 of 6

HESI101985
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 730 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1823,Sodium Hydroxide, Solid, 8, II

NAERG 154

Canadian TDG

Sodium Hydroxide, Solid, 8, UN1823, II

ADR

UN1823,Sodium Hydroxide, Solid, 8, II

Air Transportation

ICAO/IATA

UN1823,Sodium Hydroxide, Solid, 8, II

Sea Transportation

CAUSTIC SODA

Page 4 of 6

HESI101986
IMDG

UN1823,Sodium Hydroxide, Solid, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CAUSTIC SODA

Page 5 of 6

HESI101987
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAUSTIC SODA

Page 6 of 6

HESI101988
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAUSTIC SODA BEADS

Revision Date: 03-Mar-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAUSTIC SODA BEADS

Synonyms: None

Chemical Family: Hydroxide

Application: pH Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 97-98.2 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAUSTIC SODA BEADS

Page 1 of 6

HESI101989
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong acids. Reaction with steel and certain other

metals generates flammable hydrogen gas.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 2

HMIS Ratings: Health 3, Flammability 0, Reactivity 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to off white

Odor: Odorless

pH: 14

CAUSTIC SODA BEADS

Page 2 of 6

HESI101990
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.13

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 71.5

Boiling Point/Range (F): 2530

Boiling Point/Range (C): 1388

Freezing Point/Range (F): 604

Freezing Point/Range (C): 318

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Soluble in alcohols

VOCs (lbs./gallon): 0

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 40

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Halogenated compounds. Prolonged contact with aluminum, lead, or

zinc may liberate flammable hydrogen.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns. May cause chemical pneumonia.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 140-340 mg/kg (Rat)

Dermal Toxicity: LD50: 1350 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

CAUSTIC SODA BEADS

Page 3 of 6

HESI101991
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1823,Sodium Hydroxide, Solid, 8, II

NAERG 154

Canadian TDG

Sodium Hydroxide, Solid, 8, UN1823, II

ADR

UN1823,Sodium Hydroxide, Solid, 8, II

Air Transportation

ICAO/IATA

UN1823,Sodium Hydroxide, Solid, 8, II

Sea Transportation

CAUSTIC SODA BEADS

Page 4 of 6

HESI101992
IMDG

UN1823,Sodium Hydroxide, Solid, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CAUSTIC SODA BEADS

Page 5 of 6

HESI101993
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAUSTIC SODA BEADS

Page 6 of 6

HESI101994
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Ceramic Abrasive

Revision Date: 15-Sep-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Ceramic Abrasive

Synonyms: None

Chemical Family: Inorganic

Application: Abrasive

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Iron oxide 1332-37-2 3-25 Not applicable 10 mg/m3

Titanium dioxide 13463-67-7 1-3 10 mg/m3 15 mg/m3

Aluminum oxide 1344-28-1 30-75 10 mg/m3 10 mg/m3

Silica, amorphous - fumed 7631-86-9 2-9 2 mg/m3 10 mg/m3

Calcium oxide 1305-78-8 1 - 5% 2 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Notes to Physician Not Applicable

Ceramic Abrasive

Page 1 of 6

HESI101995
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

Ceramic Abrasive

Page 2 of 6

HESI101996
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Gray to Black

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.58-3.68

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 99.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Eye ailments.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure to dust may cause pneumoconiosis, a lung disease

caused by inhaling dust particles less than 0.5 micrometers into the lungs.

Other Information None known.

Toxicity Tests

Ceramic Abrasive

Page 3 of 6

HESI101997
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

%PHJJzHP Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Ceramic Abrasive

Page 4 of 6

HESI101998
Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Ceramic Abrasive

Page 5 of 6

HESI101999
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Ceramic Abrasive

Page 6 of 6

HESI102000
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-11 CROSSLINKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-11 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Titanium complex 60 - 100% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin. Repeated overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CL-11 CROSSLINKER

Page 1 of 6

HESI102001
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 61

Flash Point/Range (C): 16

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 1

HMIS Ratings: Flammability 3, Reactivity 2, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

CL-11 CROSSLINKER

Page 2 of 6

HESI102002
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Alcohol

pH: 8

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 185

Boiling Point/Range (C): 85

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): < 16

Percent Volatiles: 20

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Olefins. Amines. Flammable hydrocarbons. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Lung disorders.

CL-11 CROSSLINKER

Page 3 of 6

HESI102003
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 13250 mg/kg (Rat)

Dermal Toxicity: LD50: 12900 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 1600 ppm/4 hr. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 1000-3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Isopropanol Solution, 3, UN1219, II, (16.1 C)

NAERG 129

Canadian TDG

Isopropanol Solution, 3, UN1219, II, (16.1 C)

ADR

CL-11 CROSSLINKER

Page 4 of 6

HESI102004
UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (16.1 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

CL-11 CROSSLINKER

Page 5 of 6

HESI102005
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-11 CROSSLINKER

Page 6 of 6

HESI102006
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-36 CROSSLINKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-36 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Organic titanate 10 - 30% Not applicable Not applicable

Glycerine 56-81-5 30 - 60% 10 mg/m3 15 mg/m3

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May cause allergic respiratory

reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CL-36 CROSSLINKER

Page 1 of 6

HESI102007
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 81

Flash Point/Range (C): 27

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 1

HMIS Ratings: Health 1, Flammability 3, Reactivity 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

CL-36 CROSSLINKER

Page 2 of 6

HESI102008
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Cream to light yellow

Odor: Alcohol

pH: 8

Specific Gravity @ 20 C (Water=1): 1.128

Density @ 20 C (lbs./gallon): 9.40

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation. May

cause an allergic skin reaction.

Eye Contact May cause severe eye irritation.

CL-36 CROSSLINKER

Page 3 of 6

HESI102009
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

CL-36 CROSSLINKER

Page 4 of 6

HESI102010
UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (27 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (27 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (27 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

CL-36 CROSSLINKER

Page 5 of 6

HESI102011
NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-36 CROSSLINKER

Page 6 of 6

HESI102012
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-37M Crosslinker

Revision Date: 11-Mar-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-37M Crosslinker

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glycerine 56-81-5 5 - 10% 10 mg/m3 15 mg/m3

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

Propanol 71-23-8 5 - 10% 100 ppm 200 ppm

Triethanolamine zirconate 101033-44-7 30 - 60% 5 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Repeated overexposure may

cause liver and kidney effects. May cause blindness. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

CL-37M Crosslinker

Page 1 of 6

HESI102013
Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 54

Flash Point/Range (C): 11

Flash Point Method: TCC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Fight fire from a safe distance and from a

protected location. Use water spray to cool fire exposed surfaces. Closed containers

may explode in fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Ground and

bond containers when transferring from one container to another. Avoid contact with

eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store away from acids. Keep from heat, sparks, and open

flames. Keep container closed when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

CL-37M Crosslinker

Page 2 of 6

HESI102014
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Organic vapor respirators have a short service life. Positive pressure self-contained

breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow

Odor: Alcohol

pH: 7-9

Specific Gravity @ 20 C (Water=1): 0.94

Density @ 20 C (lbs./gallon): 7.8

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Olefins. Oxides of nitrogen. Other organic materials. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

CL-37M Crosslinker

Page 3 of 6

HESI102015
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause an allergic skin

reaction.

Eye Contact May cause moderate eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May cause central

nervous system depression including headache, dizziness, drowsiness, muscular

weakness, incoordination, slowed reaction time, fatigue blurred vision, slurred

speech, giddiness, tremors and convulsions. May be fatal or cause blindness if

swallowed.

Aggravated Medical Conditions Liver and kidney disorders. Skin disorders. Lung disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

CL-37M Crosslinker

Page 4 of 6

HESI102016
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, II, (11 C)

(Contains Methanol, Propanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, UN1993, II, (11 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Methanol, Propanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, II, (11 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1253 gallons based on Methanol (CAS: 67-56-1).

CL-37M Crosslinker

Page 5 of 6

HESI102017
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

D1B Toxic Materials

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-37M Crosslinker

Page 6 of 6

HESI102018
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Clayfix 2

Revision Date: 11-Mar-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Clayfix 2

Synonyms: None

Chemical Family: Organic Salt

Application: Clay Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkylated quaternary chloride 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be fatal if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

Clayfix 2

Page 1 of 6

HESI102019
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

Clayfix 2

Page 2 of 6

HESI102020
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Mild amine

pH: 3.5 (10%)

Specific Gravity @ 20 C (Water=1): 1.027

Density @ 20 C (lbs./gallon): 8.56

Bulk Density @ 20 C (lbs/ft3): 64

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 5-10

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Chlorine. Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye burns.

Ingestion May be fatal if swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Clayfix 2

Page 3 of 6

HESI102021
Oral Toxicity: LD50: 220 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10.5 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Toxic Liquid, Organic, N.O.S., 6.1, UN2810, III

(Contains Tetramethylammonium Chloride)

NAERG 153

Canadian TDG

Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, UN2810, III

ADR

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

Air Transportation

ICAO/IATA

Clayfix 2

Page 4 of 6

HESI102022
UN2810,Toxic Liquid, Organic, N.O.S., 6.1, III

(Contains Tetramethylammonium Chloride Solution)

Sea Transportation

IMDG

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

EmS F-A, S-A

Other Shipping Information

Labels: Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2381 gallons based on Sodium dodecylbenzene

sulfonate (CAS: 25155-30-0)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Clayfix 2

Page 5 of 6

HESI102023
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Clayfix 2

Page 6 of 6

HESI102024
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Clayfix II Plus

Revision Date: 14-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Clayfix II Plus

Synonyms: None

Chemical Family: Organic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkylated quaternary chloride 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May be fatal if swallowed. May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

Clayfix II Plus

Page 1 of 6

HESI102025
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact

with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume food, drink, or

tobacco in contaminated areas.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

Clayfix II Plus

Page 2 of 6

HESI102026
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Mild amine

pH: 4- 9

Specific Gravity @ 20 C (Water=1): 1.035

Density @ 20 C (lbs./gallon): 8.60

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -40

Freezing Point/Range (C): -40

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 20

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Chlorine. Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. Harmful if absorbed through the skin.

Eye Contact Causes eye irritation.

Ingestion May be fatal if swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Clayfix II Plus

Page 3 of 6

HESI102027
Oral Toxicity: LD50: 77 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10.5 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

NAERG 153

Canadian TDG

Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, UN2810, III

ADR

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

Air Transportation

ICAO/IATA

UN2810,Toxic Liquid, Organic, N.O.S., 6.1, III

Clayfix II Plus

Page 4 of 6

HESI102028
(Contains Tetramethylammonium Chloride Solution)

Sea Transportation

IMDG

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

EmS F-A, S-A

Other Shipping Information

Labels: Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Clayfix II Plus

Page 5 of 6

HESI102029
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Clayfix II Plus

Page 6 of 6

HESI102030
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CoalStim Part B1

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CoalStim Part B1

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Propylene glycol 57-55-6 5 - 10% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CoalStim Part B1

Page 1 of 6

HESI102031
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Store at temperatures between 50 and 100 F (10 and 37.8

C). Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron. Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CoalStim Part B1

Page 2 of 6

HESI102032
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to Off white

Odor: Ester

pH: 3

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 56

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Unknown

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

CoalStim Part B1

Page 3 of 6

HESI102033
Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: LC50 (48): > 100 mg/l

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

CoalStim Part B1

Page 4 of 6

HESI102034
Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CoalStim Part B1

Page 5 of 6

HESI102035
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CoalStim Part B1

Page 6 of 6

HESI102036
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CoilSweep I

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CoilSweep I

Synonyms: None

Chemical Family: Blend

Application: Viscosifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 30 - 60% 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

CoilSweep I

Page 1 of 6

HESI102037
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 160

Flash Point/Range (C): 71

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CoilSweep I

Page 2 of 6

HESI102038
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light gray

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.10

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 300

Boiling Point/Range (C): Not DeterminedMin: > 148

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): 5.1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

CoilSweep I

Page 3 of 6

HESI102039
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether)

Canadian TDG

Not restricted

ADR Not restricted

CoilSweep I

Page 4 of 6

HESI102040
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CoilSweep I

Page 5 of 6

HESI102041
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CoilSweep I

Page 6 of 6

HESI102042
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: COMPONENT R

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: COMPONENT R

Synonyms: None

Chemical Family: Inorganic Salt

Application: Component

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium pentaborate 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

COMPONENT R

Page 1 of 5

HESI102043
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 7.6-8.5

Specific Gravity @ 20 C (Water=1): 1.74

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

COMPONENT R

Page 2 of 5

HESI102044
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 293

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Reducing agents.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause mechanical irritation to eye.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

COMPONENT R

Page 3 of 5

HESI102045
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

COMPONENT R

Page 4 of 5

HESI102046
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

COMPONENT R

Page 5 of 5

HESI102047
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CRA 78M ACID RETARDER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CRA 78M ACID RETARDER

Synonyms: None

Chemical Family: Blend

Application: Acid Retarder

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

Ammonium chloride 12125-02-9 1 - 5% 10 mg/m3 10 mg/m3

Nonylphenol ethoxylate 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause birth

defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CRA 78M ACID RETARDER

Page 1 of 6

HESI102048
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Product is not expected to burn unless all the water is boiled away. Decomposition

in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to hazy

Odor: Sweet

CRA 78M ACID RETARDER

Page 2 of 6

HESI102049
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 5-6

Specific Gravity @ 20 C (Water=1): 1.08

Density @ 20 C (lbs./gallon): 9.0

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 124

Viscosity, Kinematic @ 20 C (centistrokes): 114

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Vapors given off by heated product may be harmful. May cause central nervous

system depression including headache, dizziness, drowsiness, incoordination,

slowed reaction time, slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion May be fatal if swallowed. May cause heart, kidney and brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause liver, heart, blood and brain damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

CRA 78M ACID RETARDER

Page 3 of 6

HESI102050
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

CRA 78M ACID RETARDER

Page 4 of 6

HESI102051
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

Ammonium Chloride//12125-02-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 3543 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CRA 78M ACID RETARDER

Page 5 of 6

HESI102052
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CRA 78M ACID RETARDER

Page 6 of 6

HESI102053
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CW-1

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CW-1

Synonyms: None

Chemical Family: Phosphate salt

Application: pH Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium phosphate 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CW-1

Page 1 of 5

HESI102054
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to off white

Odor: Odorless

pH: 4.5

Specific Gravity @ 20 C (Water=1): 2.04

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 65

CW-1

Page 2 of 5

HESI102055
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 119.98

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Oxides of phosphorus.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CW-1

Page 3 of 5

HESI102056
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

CW-1

Page 4 of 5

HESI102057
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CW-1

Page 5 of 5

HESI102058
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: DK-Intensifier

Revision Date: 28-Oct-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: DK-Intensifier

Synonyms: None

Chemical Family: Ketone

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cyclohexanone 108-94-1 60 - 100% 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

DK-Intensifier

Page 1 of 6

HESI102059
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 110

Flash Point/Range (C): 43

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways. Special Exposure Hazards

Special Protective Equipment for

Fire-Fighters

Not Determined

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Physical Hazard 0 , PPE: H

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

DK-Intensifier

Page 2 of 6

HESI102060
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Ketone

pH: 5

Specific Gravity @ 20 C (Water=1): 0.95

Density @ 20 C (lbs./gallon): 7.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 312

Boiling Point/Range (C): 156

Freezing Point/Range (F): -26

Freezing Point/Range (C): -32

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): 3.4

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Slightly soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.81

Molecular Weight (g/mole): 98.14

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Nitric acid. Sulfuric acid. Amines.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

May cause liver damage. May cause kidney damage. May cause chemical

pneumonia. May cause lungs to fill with fluids.

Skin Contact May cause skin defatting with prolonged exposure. May be absorbed through the

skin and produce effects similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation. May cause corneal injury.

DK-Intensifier

Page 3 of 6

HESI102061
Ingestion May cause liver and kidney damage. Irritation of the mouth, throat, and stomach.

May cause abdominal pain, vomiting, nausea, and diarrhea. May cause central

nervous system depression including headache, dizziness, drowsiness, muscular

weakness, incoordination, slowed reaction time, fatigue blurred vision, slurred

speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Liver and kidney disorders. Central nervous system disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. Prolonged or repeated

exposure may cause central nervous system and brain effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1530 mg/kg (Rat) LD50: 1535 mg/kg (Rat)

Dermal Toxicity: LD50: 948 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 8000 ppm/4 hr. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:EC50: 800 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

DK-Intensifier

Page 4 of 6

HESI102062
Cyclohexanone, 3, UN1915, III, (43.9 C)

NAERG 127

Canadian TDG

Cyclohexanone, 3, UN1915, III, (43.9 C)

ADR

UN1915, Cyclohexanone, 3, III

Air Transportation

ICAO/IATA

UN1915, Cyclohexanone, 3, III

Sea Transportation

IMDG

UN1915, Cyclohexanone, 3, III, (43.9 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 632 Gallons based on Cyclohexanone (CAS: 108-

94-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

DK-Intensifier

Page 5 of 6

HESI102063
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1B Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

DK-Intensifier

Page 6 of 6

HESI102064
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: DOPE BUSTER M

Revision Date: 28-Jul-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: DOPE BUSTER M

Synonyms: None

Chemical Family: Blend

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diethanolamine 111-42-2 1 - 5% 2 mg/m3 Not applicable

D-Limonene 5989-27-5 10 - 30% Not applicable Not applicable

Acetic acid 64-19-7 10 - 30% 10 ppm 10 ppm

Terpene hydrocarbon byproducts68956-56-9 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May be

absorbed through the skin. May cause allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

DOPE BUSTER M

Page 1 of 6

HESI102065
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 130

Flash Point/Range (C): 54

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas. Slippery when wet.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Open container slowly to release pressure. Avoid contact with eyes, skin, or clothing.

Avoid breathing vapors. Wash hands after use. Launder contaminated clothing

before reuse.

Storage Information Store away from oxidizers. Store in a dry location. Store in a cool well ventilated

area. Keep from heat, sparks, and open flames. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

DOPE BUSTER M

Page 2 of 6

HESI102066
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Terpene

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.913

Density @ 20 C (lbs./gallon): 7.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -25

Freezing Point/Range (C): -32

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Strong acids. Prolonged contact with aluminum.

Pentafluoroethylene.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause an allergic skin

reaction.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

DOPE BUSTER M

Page 3 of 6

HESI102067
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Terpene Hydrocarbons, N.O.S., 3, UN2319, III, (54.4 C)

NAERG 128

Canadian TDG

Terpene Hydrocarbons, N.O.S., 3, UN2319, III, (54.4 C)

ADR

UN2319,Terpene Hydrocarbons, N.O.S., 3, III

DOPE BUSTER M

Page 4 of 6

HESI102068
Air Transportation

ICAO/IATA

UN2319,Terpene Hydrocarbons, N.O.S., 3, III

Sea Transportation

IMDG

UN2319,Terpene Hydrocarbons, N.O.S., 3, III, (54.4 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Diethanolamine//111-42-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 6631 Gallons based on Acetic acid (CAS: 64-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

DOPE BUSTER M

Page 5 of 6

HESI102069
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

DOPE BUSTER M

Page 6 of 6

HESI102070
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ECONOLITE ADDITIVE

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ECONOLITE ADDITIVE

Synonyms: None

Chemical Family: Silicate

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium metasilicate,

anhydrous

6834-92-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ECONOLITE ADDITIVE

Page 1 of 6

HESI102071
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection HEPA Respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 12.7

Specific Gravity @ 20 C (Water=1): 2.4

ECONOLITE ADDITIVE

Page 2 of 6

HESI102072
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 75

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 18

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 124.09

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Prolonged contact with aluminum, lead, or zinc may liberate flammable

hydrogen.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1280 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

ECONOLITE ADDITIVE

Page 3 of 6

HESI102073
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Solid, Basic, Inorganic, N.O.S., 8, UN3262, II

(Sodium Metasilicate, Anhydrous)

NAERG 154

Canadian TDG

Corrosive Solid, Basic, Inorganic, N.O.S.(Sodium Metasilicate, Anhydrous) , 8, UN3262, II

ADR

UN3262,Corrosive Solid, Basic, Inorganic, N.O.S.(Sodium Metasilicate, Anhydrous) , 8, II

Air Transportation

ICAO/IATA

UN3262,Corrosive Solid, Basic, Inorganic, N.O.S., 8, II

(Sodium Metasilicate, Anhydrous)

ECONOLITE ADDITIVE

Page 4 of 6

HESI102074
Sea Transportation

IMDG

UN3262,Corrosive Solid, Basic, Inorganic, N.O.S.(Sodium Metasilicate, Anhydrous) , 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

ECONOLITE ADDITIVE

Page 5 of 6

HESI102075
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ECONOLITE ADDITIVE

Page 6 of 6

HESI102076
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EDTA ACID CRYSTALS

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EDTA ACID CRYSTALS

Synonyms: None

Chemical Family: Not applicable

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylenediaminetetraacetic

acid

60-00-4 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EDTA ACID CRYSTALS

Page 1 of 5

HESI102077
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Mild acidic

pH: 2.5

Specific Gravity @ 20 C (Water=1): 0.72

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 45

EDTA ACID CRYSTALS

Page 2 of 5

HESI102078
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.03

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 292.2

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Amphoteric metals such as aluminum, magnesium, lead, tin, or

zinc.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

EDTA ACID CRYSTALS

Page 3 of 5

HESI102079
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

EDTA ACID CRYSTALS

Page 4 of 5

HESI102080
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5035 Pounds based on Ethylenediaminetetraacetic

acid (CAS: 60-00-4).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EDTA ACID CRYSTALS

Page 5 of 5

HESI102081
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ER-1 RESIN

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ER-1 RESIN

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Butyl glycidyl ether 2426-08-6 10 - 30% 3 ppm (S,SEN) 50 ppm

Bisphenol A / Epichlorohydrin

resin

25068-38-6 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin. May cause allergic skin reaction. Potential carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ER-1 RESIN

Page 1 of 6

HESI102082
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 164

Flash Point/Range (C): 73

Flash Point Method: SETA

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Keep away from friction, impact, and heat. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Mild

ER-1 RESIN

Page 2 of 6

HESI102083
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.13

Density @ 20 C (lbs./gallon): 9.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 430

Boiling Point/Range (C): 221

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): 4.5

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion. May cause an allergic

skin reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity This product is a potential carcinogen.

Other Information None known.

Toxicity Tests

ER-1 RESIN

Page 3 of 6

HESI102084
Oral Toxicity: LD50: 14000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Resin Solution, Combustible Liquid, UN1866, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ER-1 RESIN

Page 4 of 6

HESI102085
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

ER-1 RESIN

Page 5 of 6

HESI102086
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ER-1 RESIN

Page 6 of 6

HESI102087
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S591M-02

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S591M-02

Synonyms: None

Chemical Family: Organic acid

Application: Scale Remover

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic anhydride 108-24-7 10 - 30% 5 ppm 5 ppm

Terpenes 30 - 60% Not applicable Not applicable

Acetic acid 64-19-7 10 - 30% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Remove contaminated shoes and discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S591M-02

Page 1 of 6

HESI102100
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 100

Flash Point/Range (C): 37

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 3

Flammability Limits in Air - Upper (%): 19

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Fight fire from a safe distance and from a

protected location. Use water spray to cool fire exposed surfaces. Closed containers

may explode in fire. Reaction with water may be highly exothermic.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 1

HMIS Ratings: Flammability 2, Reactivity 1, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse only competent persons for cleanup. Use appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Neutralize to pH of

6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ground and bond

containers when transferring from one container to another.

Storage Information Store away from alkalis. Store away from oxidizers. Keep from heat, sparks, and

open flames. Keep container closed when not in use. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Butyl rubber gloves.

Skin Protection Butyl coated apron or clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S591M-02

Page 2 of 6

HESI102101
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Pungent acrid

pH: 3-4

Specific Gravity @ 20 C (Water=1): 0.981

Density @ 20 C (lbs./gallon): 8.17

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 7.24

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Reacts

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Water. Strong alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Lung disorders.

Chronic Effects/Carcinogenicity Repeated excessive ingestion may cause central nervous system effects.

Prolonged, excessive exposure may cause erosion of the teeth.

FDP-S591M-02

Page 3 of 6

HESI102102
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Flammable, N.O.S., 8, (3), UN2920, II, (37.8 C)

(Contains Acetic Anhydride, Terpene Hydrocarbons)

NAERG 132

Canadian TDG

Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Terpene Hydrocarbons), 8, (3), UN2920, II, (37.8 C)

ADR

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Terpene Hydrocarbons), 8, (3), II

FDP-S591M-02

Page 4 of 6

HESI102103
Air Transportation

ICAO/IATA

UN2920,Corrosive Liquid, Flammable, N.O.S., 8, (3), II

(Contains Acetic Anhydride, Terpene Hydrocarbons Solution)

Sea Transportation

IMDG

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Terpene Hydrocarbons), 8, (3), II, (37.8 C)

EmS F-E, S-C

Other Shipping Information

Labels: Corrosive

Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2273 Gallons based on Acetic anhydride (CAS:

108-24-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

FDP-S591M-02

Page 5 of 6

HESI102104
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S591M-02

Page 6 of 6

HESI102105
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S633F-03

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S633F-03

Synonyms: None

Chemical Family: Amine

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glycol ether 30 - 60% Not applicable Not applicable

4,4`-Diaminodiphenyl sulfone 80-08-0 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S633F-03

Page 1 of 6

HESI102106
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

FDP-S633F-03

Page 2 of 6

HESI102107
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.147

Density @ 20 C (lbs./gallon): 9.554

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Peroxides. Carbon monoxide and carbon

dioxide. Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May reduce the blood's ability to transport oxygen

(methemaglobinemia).

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion May be harmful if swallowed.

Aggravated Medical Conditions Respiratory disorders. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

FDP-S633F-03

Page 3 of 6

HESI102108
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Can possible cause birth defects.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S633F-03

Page 4 of 6

HESI102109
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-77-3

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S633F-03

Page 5 of 6

HESI102110
***END OF MSDS***

FDP-S633F-03

Page 6 of 6

HESI102111
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S660-02

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S660-02

Synonyms: None

Chemical Family: Blend

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 5-10 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S660-02

Page 1 of 5

HESI102112
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): Not Determined

Flash Point Method: SFCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves.

Skin Protection Rubber apron. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

FDP-S660-02

Page 2 of 5

HESI102113
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Slight

pH: 6.5-7.5

Specific Gravity @ 20 C (Water=1): 1.169-1.181

Density @ 20 C (lbs./gallon): 9.74-9.84

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 0

Freezing Point/Range (C): -17.8

Vapor Pressure @ 20 C (mmHg): 19.3 (21C)

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Ammonia. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation In high air concentrations:

May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause slight eye irritation.

Ingestion In large amounts: May be harmful if swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

FDP-S660-02

Page 3 of 5

HESI102114
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

FDP-S660-02

Page 4 of 5

HESI102115
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 6294 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S660-02

Page 5 of 5

HESI102116
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S683-03

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S683-03

Synonyms: None

Chemical Family: Proprietary Aqueous Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 0 - 1% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S683-03

Page 1 of 6

HESI102117
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Store at temperatures between 50 and

100 F (10 and 37.8 C). Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow to brown

Odor: Odorless

pH: > 12

FDP-S683-03

Page 2 of 6

HESI102118
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.15

Density @ 20 C (lbs./gallon): 9.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 25000 @ 25C

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S683-03

Page 3 of 6

HESI102119
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S683-03

Page 4 of 6

HESI102120
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S683-03

Page 5 of 6

HESI102121
***END OF MSDS***

FDP-S683-03

Page 6 of 6

HESI102122
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S716-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S716-04

Synonyms: None

Chemical Family: Not determined

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Bisphenol A / Epichlorohydrin

resin

25068-38-6 30 - 60% Not applicable Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause blindness. May be absorbed

through the skin. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. Wash with soap and

water. Get medical attention if irritation persists. Remove contaminated shoes and

discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S716-04

Page 1 of 6

HESI102123
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 52

Flash Point/Range (C): 11

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36

Flammability Limits in Air - Upper (oz./ft3): 36

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard. Vapors are

heavier than air and may accumulate in low areas. Vapors may travel along the

ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S716-04

Page 2 of 6

HESI102124
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.12

Density @ 20 C (lbs./gallon): 9.33

Bulk Density @ 20 C (lbs/ft3): 69.82

Boiling Point/Range (F): 149Min: > 149

Boiling Point/Range (C): 65Min: > 65

Freezing Point/Range (F): 77

Freezing Point/Range (C): 25

Vapor Pressure @ 20 C (mmHg): < 96

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines. Prolonged contact with

aluminum, lead, or zinc may liberate flammable hydrogen. Certain coatings, plastics,

and rubbers. Strong oxidizers.

Hazardous Decomposition

Products

Formaldehyde. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause skin defatting with

prolonged exposure. May cause an allergic skin reaction.

Eye Contact May cause moderate eye irritation.

FDP-S716-04

Page 3 of 6

HESI102125
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

FDP-S716-04

Page 4 of 6

HESI102126
DOT

UN1866,Resin Solution, 3, II, (11 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (11 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (11 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 6635 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

FDP-S716-04

Page 5 of 6

HESI102127
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S716-04

Page 6 of 6

HESI102128
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S722A-04

Revision Date: 07-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S722A-04

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Epoxy resin 60 - 100% Not applicable Not applicable

Butyl glycidyl ether 2426-08-6 10 - 30% 3 ppm (S,SEN) 50 ppm

Butyl lactate 138-22-7 5 - 10% 5 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin. May cause allergic skin reaction. Potential carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S722A-04

Page 1 of 6

HESI102129
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 166

Flash Point/Range (C): 74

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Mild

FDP-S722A-04

Page 2 of 6

HESI102130
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion. May cause an allergic

skin reaction.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity This product contains a potential carcinogen.

Other Information None known.

Toxicity Tests

FDP-S722A-04

Page 3 of 6

HESI102131
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Resin Solution, Combustible Liquid, UN1866, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FDP-S722A-04

Page 4 of 6

HESI102132
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S722A-04

Page 5 of 6

HESI102133
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S722A-04

Page 6 of 6

HESI102134
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S722B-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S722B-04

Synonyms: None

Chemical Family: Blend

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phosphate ester 5 - 10% Not applicable Not applicable

Modified cycloaliphatic amine

adduct

Mixture 30 - 60% Not applicable Not applicable

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. May cause allergic skin reaction.

Repeated overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

FDP-S722B-04

Page 1 of 6

HESI102135
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 55

Flash Point/Range (C): 12.8

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperatures between 32 and 200 F (0 and 93 C).

Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S722B-04

Page 2 of 6

HESI102136
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark amber

Odor: Ammonia

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): 4.6

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of phosphorus. Acids. Aldehydes. Bromine. Hydrogen

bromide. Ketones. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause liver damage. May cause kidney damage.

Skin Contact May cause an allergic skin reaction. May cause severe skin irritation. May be

absorbed through the skin and produce nervous system effects.

Eye Contact May cause eye burns.

FDP-S722B-04

Page 3 of 6

HESI102137
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

FDP-S722B-04

Page 4 of 6

HESI102138
UN1866,Resin Solution, 3, II, (12.8 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (12.8 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (12.8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1524 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

FDP-S722B-04

Page 5 of 6

HESI102139
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S722B-04

Page 6 of 6

HESI102140
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S729-04

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S729-04

Synonyms: None

Chemical Family: Polymer

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Titanium dioxide 13463-67-7 1 - 5% 10 mg/m3 15 mg/m3

Nylon fibers 25038-54-4 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation Not a hazard under normal use conditions.

Skin Wash with soap and water. Get medical attention if irritation persists. If molten

polymer gets on skin, cool rapidly with cold water. Do not attempt to peel polymer

from skin. Seek immediate medical attention.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

FDP-S729-04

Page 1 of 5

HESI102141
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): > 752

Autoignition Temperature (C): > 400

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Foam. Water.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 0 , PPE: B

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Pellet

Color: Gray

Odor: Slight

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.12 - 1.15

Density @ 20 C (lbs./gallon): Not Determined

FDP-S729-04

Page 2 of 5

HESI102142
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong acids. Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Hydrogen cyanide. Ammonia.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 15000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Non-irritating

FDP-S729-04

Page 3 of 5

HESI102143
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S729-04

Page 4 of 5

HESI102144
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S729-04

Page 5 of 5

HESI102145
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S733-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S733-04

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polysaccharide 30 - 60% Not applicable Not applicable

Hydrotreated light petroleum

distillate

64742-47-8 30 - 60% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S733-04

Page 1 of 6

HESI102146
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): > 475

Autoignition Temperature (C): > 246

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Slippery when wet.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

FDP-S733-04

Page 2 of 6

HESI102147
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Green to Beige

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.12

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): 20

Freezing Point/Range (C): -6.7

Vapor Pressure @ 20 C (mmHg): < 0.13

Vapor Density (Air=1): >1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

FDP-S733-04

Page 3 of 6

HESI102148
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

FDP-S733-04

Page 4 of 6

HESI102149
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S733-04

Page 5 of 6

HESI102150
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S733-04

Page 6 of 6

HESI102151
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S736-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S736-04

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated heavy

naphthenic distillate

64742-52-5 30 - 60% 5 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FDP-S736-04

Page 1 of 6

HESI102152
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 212

Flash Point/Range (C): > 100

Flash Point Method: PMCC (ASTM D-93)

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Slippery when wet.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S736-04

Page 2 of 6

HESI102153
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to off white

Odor: Sweet hydrocarbon

pH: 7.5 (1%)

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): > 212

Boiling Point/Range (C): > 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. If heated: May cause central nervous system

depression including headache, dizziness, drowsiness, incoordination, slowed

reaction time, slurred speech, giddiness and unconsciousness.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

FDP-S736-04

Page 3 of 6

HESI102154
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FDP-S736-04

Page 4 of 6

HESI102155
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S736-04

Page 5 of 6

HESI102156
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S736-04

Page 6 of 6

HESI102157
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S779-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S779-05

Synonyms: None

Chemical Family: Aldehyde

Application: Diluent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Furfural 98-01-1 60 - 100% 2 ppm 5 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May be fatal if swallowed. May be fatal if inhaled. May be absorbed through the skin.

May cause allergic skin reaction. May cause eye, skin, and respiratory irritation. May

cause headache, dizziness, and other central nervous system effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S779-05

Page 1 of 6

HESI102158
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 135

Flash Point/Range (C): 57.2

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Contain spill with sand

or other inert materials. Scoop up and remove. Isolate spill and stop leak where

safe.

7. HANDLING AND STORAGE

Handling Precautions Do NOT consume food, drink, or tobacco in contaminated areas. Wash hands after

use. Launder contaminated clothing before reuse. Avoid contact with eyes, skin, or

clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperature below 68 F (20 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves. Viton gloves

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S779-05

Page 2 of 6

HESI102159
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear yellow to amber

Odor: Almond

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.15

Density @ 20 C (lbs./gallon): 10

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): <-30

Freezing Point/Range (C): <-34

Vapor Pressure @ 20 C (mmHg): <1.7

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Hazardous polymerization will occur when product comes in contact with strong

acids or oxidizing agents.

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. In high air concentrations:

May cause lungs to fill with fluids. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause an allergic skin

reaction. May cause photosensitization resulting in a rash on exposure to sunlight.

Eye Contact May cause severe eye irritation.

FDP-S779-05

Page 3 of 6

HESI102160
Ingestion May be fatal if swallowed. May cause abdominal pain, vomiting, nausea, and

diarrhea. May produce nervous system effects such as feeling of weakness,

unsteady walk, and dilation of blood vessels.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. Prolonged or repeated

exposure may cause central nervous system and brain effects. Prolonged or

repeated exposure may cause urinary tract damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Furfural has caused mutations in microbial test systems, insects, rodent cells, and

human lymphocytes.

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

FDP-S779-05

Page 4 of 6

HESI102161
DOT

Furaldehydes, 6.1, (3), UN1199, II, (57.2 C)

NAERG 132

Canadian TDG

Furaldehydes, 6.1, (3), UN1199, II, (57.2 C)

ADR

UN1199,Furaldehydes, 6.1, (3), II

Air Transportation

ICAO/IATA

UN1199,Furaldehydes, 6.1, (3), II

Sea Transportation

IMDG

UN1199,Furaldehydes, 6.1, (3), II, (57.2 C)

EmS F-E, S-D

Other Shipping Information

Labels: Toxic

Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 528 Gallons based on Furfural (CAS: 98-01-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

FDP-S779-05

Page 5 of 6

HESI102162
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1B Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S779-05

Page 6 of 6

HESI102163
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S800-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S800-05

Synonyms: None

Chemical Family: Blend

Application: Flow Enhancer

This product can only be used under the TSCA 5(h)(3) Research Exemption.

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic acid 64-19-7 1 - 5% 10 ppm 10 ppm

Ethylene glycol 107-21-1 1 - 5% 100 mg/m3 50 ppm

Heavy aromatic petroleum

naphtha

64742-94-5 10 - 30% 5 mg/m3 5 mg/m3

Naphthalene 91-20-3 0 - 1% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May be harmful if swallowed. May cause eye and skin irritation. May cause

headache, dizziness, and other central nervous system effects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

FDP-S800-05

Page 1 of 6

HESI102164
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200Min: > 203

Flash Point/Range (C): > 93Min: > 95

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Avoid spraying water directly into storage containers due to danger of boilover.

Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

FDP-S800-05

Page 2 of 6

HESI102165
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to Light tan

Odor: Hydrocarbon

pH: 4.0-8.8

Specific Gravity @ 20 C (Water=1): 0.98-1.02

Density @ 20 C (lbs./gallon): 8.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 17

Freezing Point/Range (C): -8.33

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation. Harmful if absorbed through the skin.

Eye Contact May cause mild eye irritation.

Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions. Aspiration into

the lungs may cause chemical pneumonitis including coughing, difficulty breathing,

wheezing, coughing up blood and pneumonia, which can be fatal. May cause liver

and kidney damage.

FDP-S800-05

Page 3 of 6

HESI102166
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

FDP-S800-05

Page 4 of 6

HESI102167
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1200 Gallons based on Naphthalene (CAS: 91-20-

3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S800-05

Page 5 of 6

HESI102168
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S800-05

Page 6 of 6

HESI102169
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S803-05

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S803-05

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 30 - 60% 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin. Repeated overexposure may cause liver and kidney effects. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S803-05

Page 1 of 6

HESI102170
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 185Min: > 150

Flash Point/Range (C): 85Min: > 65

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Product

has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

FDP-S803-05

Page 2 of 6

HESI102171
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Light tan

Odor: Ether

pH: 5-8.5

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 350Min: > 350

Boiling Point/Range (C): 177Min: > 177

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.17

Vapor Density (Air=1): Not Determined

Percent Volatiles: 55

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion May be harmful if swallowed. May cause central nervous system depression

including headache, dizziness, drowsiness, muscular weakness, incoordination,

slowed reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

FDP-S803-05

Page 3 of 6

HESI102172
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether)

Canadian TDG

Not restricted

ADR Not restricted

FDP-S803-05

Page 4 of 6

HESI102173
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S803-05

Page 5 of 6

HESI102174
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S803-05

Page 6 of 6

HESI102175
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S833-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S833-06

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethyl benzene 100-41-4 0 - 1% 100 ppm 100 ppm

Ethylene glycol monobutyl

ether

111-76-2 10 - 30% 20 ppm 50 ppm

Isopropanol 67-63-0 5 - 10% 200 ppm 400 ppm

Furfuryl alcohol 98-00-0 5 - 10% 10 ppm 50 pm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause severe eye irritation. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May be absorbed through the skin. May cause allergic skin reaction.

Potential carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. In case of contact,

immediately flush skin with plenty of soap and water for at least 15 minutes. Get

medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

FDP-S833-06

Page 1 of 6

HESI102176
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 100

Flash Point/Range (C): 37.8

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove. Remove ignition sources and work with non-sparking tools.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Keep container closed when not in use. Keep from heat, sparks, and open flames.

Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves. Butyl rubber gloves. Neoprene gloves. Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S833-06

Page 2 of 6

HESI102177
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Furan

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.17

Density @ 20 C (lbs./gallon): 9.746

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide. Aldehydes. Ketones. Alcohols.

Formaldehyde.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion. May cause an allergic

skin reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Eye ailments. Skin disorders.

FDP-S833-06

Page 3 of 6

HESI102178
Chronic Effects/Carcinogenicity This product is a potential carcinogen.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1866,Resin Solution, 3, III, (37.8 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, III, (37.8 C)

ADR

FDP-S833-06

Page 4 of 6

HESI102179
UN1866,Resin Solution, 3, III

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, III

Sea Transportation

IMDG

UN1866,Resin Solution, 3, III, (37.8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Fire Hazard

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethyl Benzene//100-41-4

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

FDP-S833-06

Page 5 of 6

HESI102180
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

D1B Toxic Materials

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S833-06

Page 6 of 6

HESI102181
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S835-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S835-06

Synonyms: None

Chemical Family: Anionic Polymer in Water

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

FDP-S835-06

Page 1 of 5

HESI102182
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Spills produce extremely slippery

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Spills of this product are very slippery.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 6

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellowish

Odor: Odorless

FDP-S835-06

Page 2 of 5

HESI102183
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 4.2-5.5

Specific Gravity @ 20 C (Water=1): 1.072

Density @ 20 C (lbs./gallon): 8.93

Bulk Density @ 20 C (lbs/ft3): 66.8

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): 32

Freezing Point/Range (C): 0

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 80

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Ammonia. Oxides of nitrogen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

FDP-S835-06

Page 3 of 5

HESI102184
Inhalation Toxicity: LC50: > 2500 mg/m3/4-hour (rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not readily biodegradable.

COD: 25000 ppm

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: LC50:(96 hour) >100 mg/l (Brachidanio rerio)

Acute Crustaceans Toxicity:TLM48: > 100 mg/l (Daphnia magna)

Acute Algae Toxicity: IC50: >100 mg/l (Selenastrum capracornutum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S835-06

Page 4 of 5

HESI102185
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S835-06

Page 5 of 5

HESI102186
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S836-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S836-06

Synonyms: None

Chemical Family: Phosphate salt

Application: Acid Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S836-06

Page 1 of 5

HESI102187
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresNot Determined

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Avoid contact with eyes, skin, or clothing. Avoid creating or

inhaling dust.

Storage Information Store in a dry location. Keep container closed when not in use. Product has a shelf

life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Flake

Color: White

Odor: Odorless

pH: 8

FDP-S836-06

Page 2 of 5

HESI102188
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.62

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 1112

Freezing Point/Range (C): 600

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 50

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Oxides of phosphorus. Sodium oxides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause mechanical irritation to eye.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S836-06

Page 3 of 5

HESI102189
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation No bioconcentration is expected because of the relatively high water solubility.

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S836-06

Page 4 of 5

HESI102190
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S836-06

Page 5 of 5

HESI102191
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S867A-07

Revision Date: 22-Jun-2007

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S867A-07

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Epoxy resin 10 - 30% Not applicable Not applicable

Potassium chloride 7447-40-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S867A-07

Page 1 of 6

HESI102192
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): >210

Flash Point/Range (C): 99

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. Avoid breathing mist.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Supplied air respirator

Hand Protection Polyvinylchloride gloves. Nitrile gloves.

Skin Protection PVC coated apron or clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S867A-07

Page 2 of 6

HESI102193
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky

Odor: Mild aromatic

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.043

Density @ 20 C (lbs./gallon): 8.69

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Irritation of the mouth, throat, and stomach. A burning feeling in the Stomach May

cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments. Respiratory disorders.

FDP-S867A-07

Page 3 of 6

HESI102194
Chronic Effects/Carcinogenicity May cause testicular toxicity. Contains epichlorohydrin which has been reported to

produce cancer in laboratory animals. Epidemiological studies present "weak"

evidence of cancer risk to humans.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not readily biodegradable.

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

FDP-S867A-07

Page 4 of 6

HESI102195
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S867A-07

Page 5 of 6

HESI102196
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S867A-07

Page 6 of 6

HESI102197
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S867B-07

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S867B-07

Synonyms: None

Chemical Family: Blend

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyamine Polymer Proprietary 5 - 10% Not applicable Not applicable

Potassium chloride 7447-40-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S867B-07

Page 1 of 6

HESI102198
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 210

Flash Point/Range (C): > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Product

has a shelf life of 3 months

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Positive pressure self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S867B-07

Page 2 of 6

HESI102199
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Ammonia

pH: 7

Specific Gravity @ 20 C (Water=1): 1.027

Density @ 20 C (lbs./gallon): 8.55

Bulk Density @ 20 C (lbs/ft3): 66.7

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Sodium nitrite Peroxides. Strong oxidizers.

Hazardous Decomposition

Products

Ammonia. Carbon monoxide and carbon dioxide. Oxides of nitrogen. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause moderate eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

FDP-S867B-07

Page 3 of 6

HESI102200
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FDP-S867B-07

Page 4 of 6

HESI102201
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S867B-07

Page 5 of 6

HESI102202
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S867B-07

Page 6 of 6

HESI102203
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S883-07

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S883-07

Synonyms: None

Chemical Family: Polymer

Application: Viscosifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polylactide resin 90 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S883-07

Page 1 of 6

HESI102204
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Spills of this product are very slippery.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust

accumulations.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Store between 40.5 F (4.7 C) and 120.5 F (49 C).

Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

FDP-S883-07

Page 2 of 6

HESI102205
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: Clear

Odor: Sweet

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.25

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperature over 440 F (240 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Toxic fumes. Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Large doses may cause nausea,

vomiting and diarrhea.

Aggravated Medical Conditions None known.

FDP-S883-07

Page 3 of 6

HESI102206
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Will not bio-accumulate.

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: EC50: >1100 mg/l

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

FDP-S883-07

Page 4 of 6

HESI102207
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S883-07

Page 5 of 6

HESI102208
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S883-07

Page 6 of 6

HESI102209
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S890-08

Revision Date: 25-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S890-08

Synonyms: None

Chemical Family: Surfactant Blend

Application: Defoamer

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Fatty alcohol alkoxylate Proprietary 5 - 10% Not applicable Not applicable

Proprietary Component 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Rinse mouth with water many times. If swallowed, give at least 3-4 glasses of water,

but do not induce vomiting. Do not give anything by mouth to an unconscious or

convulsing person. Get medical attention.

Notes to Physician Not Applicable

FDP-S890-08

Page 1 of 6

HESI102210
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 212

Flash Point/Range (C): > 100

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Avoid spraying water directly into

storage containers due to danger of boilover.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Material is slippery underfoot. Avoid contact with eyes, skin, or clothing. Keep floors

clean of spills.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally necessary.

Hand Protection Impervious rubber gloves. Butyl rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

FDP-S890-08

Page 2 of 6

HESI102211
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Characteristic

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): 8.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Hydrocarbons.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Heated vapors may cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion May cause stomach discomfort.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

FDP-S890-08

Page 3 of 6

HESI102212
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Non-irritating

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

FDP-S890-08

Page 4 of 6

HESI102213
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S890-08

Page 5 of 6

HESI102214
***END OF MSDS***

FDP-S890-08

Page 6 of 6

HESI102215
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S891A-08

Revision Date: 13-Feb-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S891A-08

Synonyms: None

Chemical Family: Resin

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 5 - 10% 100 ppm 100 ppm

Butyl lactate 138-22-7 5 - 10% 5 ppm Not applicable

Diethylene glycol monomethyl

ether

111-77-3 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May be

absorbed through the skin. May cause allergic skin reaction. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Notes to Physician Not Applicable

FDP-S891A-08

Page 1 of 6

HESI102216
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 197

Flash Point/Range (C): 92

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Contain spill with sand

or other inert materials. Scoop up and remove. Isolate spill and stop leak where

safe.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact

with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S891A-08

Page 2 of 6

HESI102217
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Ether

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.12

Density @ 20 C (lbs./gallon): 9.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -10

Freezing Point/Range (C): -23

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines.

Hazardous Decomposition

Products

Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion. May cause an allergic

skin reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May cause liver and

kidney damage.

Aggravated Medical Conditions Skin disorders. Eye ailments.

FDP-S891A-08

Page 3 of 6

HESI102218
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Possible risk of harm to the unborn child. Possible risk of impaired fertility.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Resin Solution, Combustible Liquid, UN1866, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

FDP-S891A-08

Page 4 of 6

HESI102219
Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Fire Hazard

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S891A-08

Page 5 of 6

HESI102220
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S891A-08

Page 6 of 6

HESI102221
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S891B-08

Revision Date: 13-Feb-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S891B-08

Synonyms: None

Chemical Family: Blend

Application: Resin Curing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 10 - 30% 100 ppm 100 ppm

Diethylene glycol monomethyl

ether

111-77-3 10 - 30% Not applicable Not applicable

Methanol 67-56-1 1 - 5% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May cause

allergic skin reaction. May be fatal if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

FDP-S891B-08

Page 1 of 6

HESI102222
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 142

Flash Point/Range (C): 61

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Contain spill with sand

or other inert materials. Scoop up and remove. Isolate spill and stop leak where

safe.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact

with eyes, skin, or clothing. Avoid breathing vapors. Ground and bond containers

when transferring from one container to another.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

FDP-S891B-08

Page 2 of 6

HESI102223
Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Amine

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -10

Freezing Point/Range (C): -23

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines.

Hazardous Decomposition

Products

Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

FDP-S891B-08

Page 3 of 6

HESI102224
Ingestion May be fatal or cause blindness if swallowed. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions. May cause liver and kidney damage.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Possible risk of harm to the unborn child. Possible risk of impaired fertility.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

FDP-S891B-08

Page 4 of 6

HESI102225
Not restricted

DOT (Bulk)

Resin Solution, Combustible Liquid, UN1866, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Fire Hazard

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

The EPA Reportable Spill Quantity is well above quantities required for any expected

use of this product.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

FDP-S891B-08

Page 5 of 6

HESI102226
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S891B-08

Page 6 of 6

HESI102227
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S895-08

Revision Date: 21-Feb-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S895-08

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

10 - 30% 200 mg/m3 Not applicable

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

FDP-S895-08

Page 1 of 7

HESI102228
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 182

Flash Point/Range (C): 83

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing mist. This product contains

quartz, cristobalite, and/or tridymite which may become airborne without a visible

cloud if this product becomes dry. Avoid breathing or creating dust. Use only with

adequate ventilation to keep exposures below recommended exposure limits. Wear

a NIOSH certified, European Standard EN 149, or equivalent respirator when using

dried product. Wash hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use.

FDP-S895-08

Page 2 of 7

HESI102229
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Red

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.21

Density @ 20 C (lbs./gallon): 10.1

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -27

Freezing Point/Range (C): -33

Vapor Pressure @ 20 C (mmHg): .1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C). Carbon monoxide and carbon dioxide.

FDP-S895-08

Page 3 of 7

HESI102230
Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. If heated: May cause central nervous system

depression including headache, dizziness, drowsiness, incoordination, slowed

reaction time, slurred speech, giddiness and unconsciousness.

Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust. Skin

disorders.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

FDP-S895-08

Page 4 of 7

HESI102231
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Distillates)

FDP-S895-08

Page 5 of 7

HESI102232
Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S895-08

Page 6 of 7

HESI102233
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S895-08

Page 7 of 7

HESI102234
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S897-08

Revision Date: 02-Jun-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S897-08

Synonyms: None

Chemical Family: Blend

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated amines 30 - 60% Not applicable Not applicable

Proprietary Component 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause respiratory irritation. May be harmful if swallowed. May cause eye and

skin burns.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Check for and remove contact lenses if present. Immediately flush eyes with large

amounts of water for at least 20 minutes. Seek prompt medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S897-08

Page 1 of 6

HESI102235
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 132

Flash Point/Range (C): 56

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact

with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing mist. Ground

and bond containers when transferring from one container to another.

Storage Information Store away from acids. Store away from oxidizers. Store away from alkalis. Keep

container closed when not in use. Keep from heat, sparks, and open flames. Store in

a cool, dry location. Store in a well ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Neoprene gloves. Nitrile gloves.

FDP-S897-08

Page 2 of 6

HESI102236
Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Golden

Odor: Woody

pH: 6.65 - 7.37 (1%)

Specific Gravity @ 20 C (Water=1): 0.93

Density @ 20 C (lbs./gallon): 8.27

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Emulsifies, forms colloids

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Oxides of nitrogen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns. May cause an allergic skin reaction.

Eye Contact Causes eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

FDP-S897-08

Page 3 of 6

HESI102237
Chronic Effects/Carcinogenicity Not determined

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (55.6 C)

(Terpene Hydrocarbons, Alkoxylated Fatty Amines)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Terpene Hydrocarbons, Alkoxylated Fatty Amines), 3, (8), UN2924, III, (55.6 C)

FDP-S897-08

Page 4 of 6

HESI102238
ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Terpene Hydrocarbons, Alkoxylated Fatty Amines), 3, (8), III

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Terpene Hydrocarbons, Alkoxylated Fatty Amines Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Terpene Hydrocarbons, Alkoxylated Fatty Amines), 3, (8), III, (55.6 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

B3 Combustible Liquids

FDP-S897-08

Page 5 of 6

HESI102239
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S897-08

Page 6 of 6

HESI102240
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S903-08

Revision Date: 22-Jul-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S903-08

Synonyms: None

Chemical Family: Polymer

Application: Viscosifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polylactide resin 90 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S903-08

Page 1 of 6

HESI102241
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Spills of this product are very slippery.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust

accumulations.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Store between 40.5 F (4.7 C) and 120.5 F (49 C).

Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

FDP-S903-08

Page 2 of 6

HESI102242
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: Clear

Odor: Sweet

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.25

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperature over 440 F (240 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Toxic fumes. Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Large doses may cause nausea,

vomiting and diarrhea.

Aggravated Medical Conditions None known.

FDP-S903-08

Page 3 of 6

HESI102243
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Will not bio-accumulate.

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: EC50: >1100 mg/l

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

FDP-S903-08

Page 4 of 6

HESI102244
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S903-08

Page 5 of 6

HESI102245
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S903-08

Page 6 of 6

HESI102246
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S906-08

Revision Date: 04-Sep-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S906-08

Synonyms: None

Chemical Family: Blend

Application: Acid gelling polymer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated heavy

naphthenic distillate

64742-52-5 1 - 5% 5 mg/m3 5 mg/m3

Mineral oil 8042-47-5 30 - 60% 5 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FDP-S906-08

Page 1 of 6

HESI102247
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200Min: > 212

Flash Point/Range (C): > 93.3Min: > 100

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Physical Hazard 0 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Launder contaminated clothing before reuse. Avoid breathing vapors. Avoid contact

with eyes, skin, or clothing. Avoid breathing mist. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor cartridge with particulate prefilter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S906-08

Page 2 of 6

HESI102248
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky white

Odor: Mild hydrocarbon

pH: 6.8 (1%)

Specific Gravity @ 20 C (Water=1): 1.056

Density @ 20 C (lbs./gallon): 8.8

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 212

Boiling Point/Range (C): Not DeterminedMin: > 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration can be a hazard if this material is swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

FDP-S906-08

Page 3 of 6

HESI102249
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

FDP-S906-08

Page 4 of 6

HESI102250
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

The EPA Reportable Spill Quantity is well above quantities required for any expected

use of this product.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S906-08

Page 5 of 6

HESI102251
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S906-08

Page 6 of 6

HESI102252
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S909-08

Revision Date: 05-Nov-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S909-08

Synonyms: None

Chemical Family: Oxidant

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chlorate 7775-09-9 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. Oxidizer.

If allowed to evaporate to dryness, the residue may act as an oxidizer to initiate and

sustain the combustion of flammable materials.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Destroy or

properly dispose of contaminated shoes. Remove contaminated clothing and launder

before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

FDP-S909-08

Page 1 of 6

HESI102253
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water.

Special Exposure Hazards If allowed to dry, this product is an oxidizer. Decomposition in fire may produce toxic

gases. Use water spray to cool fire exposed surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 2

HMIS Ratings: Health 2, Flammability 0, Physical Hazard 2 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. Avoid breathing mist. Do not allow product to

dry. Dry material is an oxidizer.

Storage Information Store away from combustibles. Keep container closed when not in use. Do not allow

this solution to evaporate to dryness, which will create a hazard of combustion. Store

away from reducing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Local exhaust ventilation should be used in areas without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

FDP-S909-08

Page 2 of 6

HESI102254
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to Green or Yellow

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.17

Density @ 20 C (lbs./gallon): 9.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 230

Boiling Point/Range (C): 110

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Do not expose to heat or store at temperatures above 120 F (49 C).

Incompatibility (Materials to

Avoid)

Organic matter. Reducing agents. Combustible materials.

Hazardous Decomposition

Products

Sodium oxides. Chlorine. Chlorine dioxide. Oxygen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May reduce the blood's

ability to transport oxygen (methemalobinemia). May cause liver and kidney damage.

Coma, shock and death may occur.

Aggravated Medical Conditions Lung disorders. Blood disorders. Kidney disorders.

Chronic Effects/Carcinogenicity Contains trace amounts of hexavalent chromium (chromate), which can cause

allergic contact dermatitis and skin ulcerations. Hexavalent chromium is classified as

a known human carcinogen by NTP and IARC.

FDP-S909-08

Page 3 of 6

HESI102255
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1200 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Sodium Chlorate, Aqueous Solution, 5.1, UN2428 , II

NAERG 140

Canadian TDG

Sodium Chlorate, Aqueous Solution, 5.1, UN2428 , II

ADR

UN2428, Sodium Chlorate, Aqueous Solution, 5.1, II

FDP-S909-08

Page 4 of 6

HESI102256
Air Transportation

ICAO/IATA

UN2428, Sodium Chlorate, Aqueous Solution, 5.1, II

Sea Transportation

IMDG

UN2428, Sodium Chlorate, Aqueous Solution, II

EmS F-H, S-Q

Other Shipping Information

Labels: Oxidizer

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S909-08

Page 5 of 6

HESI102257
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S909-08

Page 6 of 6

HESI102258
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S912-08

Revision Date: 27-Mar-2006

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S912-08

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 10 - 30% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S912-08

Page 1 of 6

HESI102259
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0 , PPE: C

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Contain spill with sand or other inert materials. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing mist. Avoid breathing

vapors. Wash hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator.

Hand Protection Nitrile gloves. Polyvinylchloride gloves. Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S912-08

Page 2 of 6

HESI102260
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to Light straw

Odor: Mild ammonia

pH: 5.0-5.5

Specific Gravity @ 20 C (Water=1): 1.18-1.22

Density @ 20 C (lbs./gallon): 9.83-10.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 242

Boiling Point/Range (C): 117

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: May Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Excessive inhalation causes headache, dizziness,

nausea and incoordination.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion In large amounts: May cause abdominal pain, vomiting, nausea, and diarrhea. May

be harmful if swallowed.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

FDP-S912-08

Page 3 of 6

HESI102261
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

FDP-S912-08

Page 4 of 6

HESI102262
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S912-08

Page 5 of 6

HESI102263
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S912-08

Page 6 of 6

HESI102264
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S918-09

Revision Date: 06-Apr-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S918-09

Synonyms: None

Chemical Family: Surfactant Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Surfactant blend 30 - 60% Not applicable Not applicable

Methanol 67-56-1 5 - 10% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. May cause allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S918-09

Page 1 of 6

HESI102265
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 86

Flash Point/Range (C): 30

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Ground and

bond containers when transferring from one container to another. Avoid contact with

eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing mist.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirators have a short service life.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

FDP-S918-09

Page 2 of 6

HESI102266
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Straw

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.99

Density @ 20 C (lbs./gallon): 8.25

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -20

Freezing Point/Range (C): -29

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and contribute to the

symptoms listed under ingestion. May cause skin defatting with prolonged exposure.

May cause an allergic skin reaction.

Eye Contact May cause moderate eye irritation.

FDP-S918-09

Page 3 of 6

HESI102267
Ingestion May be fatal or cause blindness if swallowed. May cause headache, dizziness,

nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Aspiration can be a hazard if this material is swallowed.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

May adversely affect or disrupt reproductive development or other hormonally

controlled processes in both humans and animals.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

FDP-S918-09

Page 4 of 6

HESI102268
DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, III, (30 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, UN1993, III, (30 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Methanol, Terpenes Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Terpenes), 3, III, (30 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5914 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

FDP-S918-09

Page 5 of 6

HESI102269
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

D2A Very Toxic Materials

D2B Toxic Materials

B2 Flammable Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S918-09

Page 6 of 6

HESI102270
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S944-09

Revision Date: 19-Oct-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S944-09

Synonyms: None

Chemical Family: Cationic Polymer in Emulsion

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FDP-S944-09

Page 1 of 6

HESI102271
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): > 419

Autoignition Temperature (C): > 215

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0 , PPE: A

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Spills of this product are very slippery.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing

mist. Wash hands after use. Launder contaminated clothing before reuse. Material

is slippery underfoot.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location. Store in a well ventilated area. Keep from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

FDP-S944-09

Page 2 of 6

HESI102272
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): 65.3

Boiling Point/Range (F): >212

Boiling Point/Range (C): >100

Freezing Point/Range (F): < 14

Freezing Point/Range (C): < -10

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 45

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Oxides of nitrogen. Oxides of sulfur.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhalation of mist or heated vapors may cause respiratory irritation.

Skin Contact May cause skin defatting with prolonged exposure.

Eye Contact May cause slight eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

FDP-S944-09

Page 3 of 6

HESI102273
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

FDP-S944-09

Page 4 of 6

HESI102274
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S944-09

Page 5 of 6

HESI102275
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S944-09

Page 6 of 6

HESI102276
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S646M-02

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S646M-02

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aldehyde 10 - 30% Not applicable Not applicable

Chloromethylnaphthalene

quinoline quaternary amine

15619-48-4 5 - 10% Not applicable Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

FDP-S646M-02

Page 1 of 6

HESI102277
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 62

Flash Point/Range (C): 16.7

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S646M-02

Page 2 of 6

HESI102278
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Alcohol

pH: 2-4

Specific Gravity @ 20 C (Water=1): 0.979

Density @ 20 C (lbs./gallon): 8.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -30

Freezing Point/Range (C): < -34.4

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 2-25

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Oxides of phosphorus. Hydrocarbons. Carbon

monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May cause liver and kidney damage.

FDP-S646M-02

Page 3 of 6

HESI102279
Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, II, (16.7 C)

(Contains Isopropanol, Methanol)

NAERG 128

Canadian TDG

FDP-S646M-02

Page 4 of 6

HESI102280
Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, UN1993, II, (16.7 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II, (16.7 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 3608 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

FDP-S646M-02

Page 5 of 6

HESI102281
WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S646M-02

Page 6 of 6

HESI102282
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-W905-08

Revision Date: 27-Aug-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-W905-08

Synonyms: None

Chemical Family: Blend

Application: Conformance Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-W905-08

Page 1 of 6

HESI102283
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

FDP-W905-08

Page 2 of 6

HESI102284
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Amine

pH: 8.5 - 8.9

Specific Gravity @ 20 C (Water=1): 1.0127

Density @ 20 C (lbs./gallon): 8.44

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.5

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

FDP-W905-08

Page 3 of 6

HESI102285
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

FDP-W905-08

Page 4 of 6

HESI102286
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-W905-08

Page 5 of 6

HESI102287
***END OF MSDS***

FDP-W905-08

Page 6 of 6

HESI102288
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S633F-03

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S633F-03

Synonyms: None

Chemical Family: Amine

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glycol ether 30 - 60% Not applicable Not applicable

4,4`-Diaminodiphenyl sulfone 80-08-0 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S633F-03

Page 1 of 6

HESI102088
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

FDP-S633F-03

Page 2 of 6

HESI102089
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.147

Density @ 20 C (lbs./gallon): 9.554

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Peroxides. Carbon monoxide and carbon

dioxide. Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May reduce the blood's ability to transport oxygen

(methemaglobinemia).

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion May be harmful if swallowed.

Aggravated Medical Conditions Respiratory disorders. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

FDP-S633F-03

Page 3 of 6

HESI102090
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Can possible cause birth defects.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S633F-03

Page 4 of 6

HESI102091
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-77-3

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S633F-03

Page 5 of 6

HESI102092
***END OF MSDS***

FDP-S633F-03

Page 6 of 6

HESI102093
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S683-03

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S683-03

Synonyms: None

Chemical Family: Proprietary Aqueous Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 0 - 1% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S683-03

Page 1 of 6

HESI102094
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Store at temperatures between 50 and

100 F (10 and 37.8 C). Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow to brown

Odor: Odorless

pH: > 12

FDP-S683-03

Page 2 of 6

HESI102095
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.15

Density @ 20 C (lbs./gallon): 9.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 25000 @ 25C

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S683-03

Page 3 of 6

HESI102096
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S683-03

Page 4 of 6

HESI102097
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S683-03

Page 5 of 6

HESI102098
***END OF MSDS***

FDP-S683-03

Page 6 of 6

HESI102099
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-3

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-3

Synonyms: None

Chemical Family: Not applicable

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Nitrilotriacetic acid 139-13-9 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May be

absorbed through the skin. Potential carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FE-3

Page 1 of 6

HESI102289
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Aminoacetate

pH: 2.5

Specific Gravity @ 20 C (Water=1): 1.78

Density @ 20 C (lbs./gallon): Not Determined

FE-3

Page 2 of 6

HESI102290
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 42.46

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 4.3

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Coughing, chest pains, and breathing difficulty may

occur.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains nitrilotriacetic acid or its salts, which is listed as a suspect carcinogen of the

urinary tract and kidneys by NTP, based on feeding studies with laboratory animals.

According to the ACGIH guidelines, NTA would "not be considered an occupational

carcinogen of any significance." IARC cancer review classification: 2B (Possibly

Carcinogenic to Humans)

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1470 mg/kg (Rat)

FE-3

Page 3 of 6

HESI102291
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

FE-3

Page 4 of 6

HESI102292
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Nitrilotriacetic Acid//139-13-9

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FE-3

Page 5 of 6

HESI102293
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-3

Page 6 of 6

HESI102294
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-5

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-5

Synonyms: None

Chemical Family: Not applicable

Application: Iron Reducing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Thioglycolic acid 68-11-1 60 - 100% 1 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause allergic skin reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician None known.

FE-5

Page 1 of 6

HESI102295
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 212

Flash Point/Range (C): 100

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a dry location. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing. Not normally necessary.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

FE-5

Page 2 of 6

HESI102296
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Irritating

pH: 1.04

Specific Gravity @ 20 C (Water=1): 1.29

Density @ 20 C (lbs./gallon): 10.81

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 221

Boiling Point/Range (C): 105

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 10

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 92.11

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis. Contact with metals.

Hazardous Decomposition

Products

Hydrogen sulfide. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns.

Skin Contact Causes severe burns. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause weakness, dyspnea, or

coma.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated skin exposure may cause dermatitis.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

FE-5

Page 3 of 6

HESI102297
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1940,Thioglycolic Acid, 8, II

NAERG 153

Canadian TDG

Thioglycolic Acid, 8, UN1940, II

ADR

UN1940,Thioglycolic Acid, 8, II

Air Transportation

ICAO/IATA

UN1940,Thioglycolic Acid, 8, II

FE-5

Page 4 of 6

HESI102298
Sea Transportation

IMDG

UN1940,Thioglycolic Acid, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FE-5

Page 5 of 6

HESI102299
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-5

Page 6 of 6

HESI102300
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-36

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-36

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 20 - 40% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FR-36

Page 1 of 6

HESI102301
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Product is not expected to burn unless all the water is boiled away.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Neoprene gloves. Nitrile gloves. Butyl rubber gloves. Polyvinylchloride gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

FR-36

Page 2 of 6

HESI102302
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White, opaque

Odor: Mild hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.81

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): 10

Freezing Point/Range (C): -12

Vapor Pressure @ 20 C (mmHg): < 5

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 400-1400 (@24C)

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Freezing conditions.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide. Oxides of sulfur.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Not a likely route of exposure.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause liver damage.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

FR-36

Page 3 of 6

HESI102303
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

FR-36

Page 4 of 6

HESI102304
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FR-36

Page 5 of 6

HESI102305
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-36

Page 6 of 6

HESI102306
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-66

Revision Date: 24-Jun-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-66

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FR-66

Page 1 of 6

HESI102307
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): > 419

Autoignition Temperature (C): > 215

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0 , PPE: C

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Avoid breathing mist.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location. Store in a well ventilated area. Keep from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FR-66

Page 2 of 6

HESI102308
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): 65.4

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < 14

Freezing Point/Range (C): < -10

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhalation of mist or heated vapors may cause respiratory irritation.

Skin Contact May cause skin defatting with prolonged exposure.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

FR-66

Page 3 of 6

HESI102309
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FR-66

Page 4 of 6

HESI102310
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FR-66

Page 5 of 6

HESI102311
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-66

Page 6 of 6

HESI102312
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: G-SPERSE

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: G-SPERSE

Synonyms: None

Chemical Family: Sulfate

Application: Dispersant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium sulfate 7757-82-6 1 - 5% Not applicable Not applicable

Sodium chloride 7647-14-5 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

G-SPERSE

Page 1 of 5

HESI102340
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Product is not expected to burn unless all the water is boiled away. Decomposition

in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Keep container closed when not in use. Product has a shelf

life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow to brown

G-SPERSE

Page 2 of 5

HESI102341
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Disinfectant

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.14

Density @ 20 C (lbs./gallon): 9.50

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 17.8

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion None known

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

G-SPERSE

Page 3 of 5

HESI102342
Inhalation Toxicity: LC50: > 2500 mg/m3/4-hour (rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

G-SPERSE

Page 4 of 5

HESI102343
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

G-SPERSE

Page 5 of 5

HESI102344
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GasPerm 1000M

Revision Date: 04-Mar-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GasPerm 1000M

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

Citrus, extract 94266-47-4 5 - 10% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. In case of contact,

immediately flush skin with plenty of soap and water for at least 15 minutes. Get

medical attention.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration. Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk

and seek medical attention. Never give anything by mouth to an unconscious

person.

Notes to Physician Not Applicable

GasPerm 1000M

Page 1 of 6

HESI102313
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 70

Flash Point/Range (C): 21.1

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. May be ignited by heat, sparks

or flames.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove. Contain spill with sand or other inert materials. Isolate spill

and stop leak where safe. Remove ignition sources and work with non-sparking

tools.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Terpene containing products should be stored in phenoliclined metal, stainless steel, PET, or fluorinated plastic containers. Product has a shelf

life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

GasPerm 1000M

Page 2 of 6

HESI102314
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Nitrile gloves. Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Alcohol

pH: 8.7

Specific Gravity @ 20 C (Water=1): 0.924

Density @ 20 C (lbs./gallon): 7.70

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 310

Boiling Point/Range (C): 154

Freezing Point/Range (F): < 0

Freezing Point/Range (C): < -17.8

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50-75

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Iodine pentafluorethylene Strong acids. Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

GasPerm 1000M

Page 3 of 6

HESI102315
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin defatting with prolonged exposure. May be absorbed through the

skin and produce effects similar to those caused by inhalation and/or ingestion. May

cause mild skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

GasPerm 1000M

Page 4 of 6

HESI102316
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1219,Isopropanol Solution, 3, II, (21.1 C)

NAERG 129

Canadian TDG

Isopropanol Solution, 3, UN1219, II, (21.1 C)

ADR

UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (21.1 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

GasPerm 1000M

Page 5 of 6

HESI102317
EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B2 Flammable Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GasPerm 1000M

Page 6 of 6

HESI102318
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GasPerm 1100

Revision Date: 04-Mar-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GasPerm 1100

Synonyms: None

Chemical Family: Blend

Application: Non-ionic Surfactant

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Terpenes and Terpenoids, sweet

orange-oil

68647-72-3 1 - 5% Not applicable Not applicable

Ethanol 64-17-5 30 - 60% 1000 ppm 1000 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic skin reaction. May be

harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person. Get

medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

GasPerm 1100

Page 1 of 6

HESI102319
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 70

Flash Point/Range (C): 21

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 6.1

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0 , PPE: H

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Scoop up and remove. Contain spill with sand or other inert

materials.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Terpene containing products should be stored in phenoliclined metal, stainless steel, PET, or fluorinated plastic containers. Product has a shelf

life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

GasPerm 1100

Page 2 of 6

HESI102320
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Nitrile gloves. Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Alcohol

pH: 7

Specific Gravity @ 20 C (Water=1): 0.9368

Density @ 20 C (lbs./gallon): 7.818

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < 0

Freezing Point/Range (C): < -18

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Iodine pentafluorethylene Strong acids. Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

GasPerm 1100

Page 3 of 6

HESI102321
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Causes depression and fatigue.

Skin Contact May cause skin defatting with prolonged exposure. May cause mild skin irritation.

May cause an allergic skin reaction.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Inherently biodegradable

Bio-accumulation Not expected to bioaccumulate.

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:May be toxic to aquatic life.

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

GasPerm 1100

Page 4 of 6

HESI102322
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol, Citrus Terpenes), 3, II, (21.1 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Ethanol, Citrus Terpenes), 3, UN1993, II, (21.1 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol, Citrus Terpenes), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Ethanol, Citrus Terpenes Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol, Citrus Terpenes), 3, II, (21.1 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

GasPerm 1100

Page 5 of 6

HESI102323
EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GasPerm 1100

Page 6 of 6

HESI102324
HESI102325
HESI102326
HESI102327
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GILSONITE RESIN

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GILSONITE RESIN

Synonyms: None

Chemical Family: Asphalt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Natural asphalt 12002-43-6 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

GILSONITE RESIN

Page 1 of 6

HESI102328
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 599

Flash Point/Range (C): 315

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.02

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

GILSONITE RESIN

Page 2 of 6

HESI102329
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Dark brown

Odor: Asphalt

pH: 5-7

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 65.55

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 2

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

GILSONITE RESIN

Page 3 of 6

HESI102330
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 10000 mg/l (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

GILSONITE RESIN

Page 4 of 6

HESI102331
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

GILSONITE RESIN

Page 5 of 6

HESI102332
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GILSONITE RESIN

Page 6 of 6

HESI102333
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GS-5 ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GS-5 ADDITIVE

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Branched ethoxylated

nonylphenol

68412-54-4 1 - 5% Not applicable Not applicable

Ethylene glycol 107-21-1 5 - 10% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause birth defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

GS-5 ADDITIVE

Page 1 of 6

HESI102334
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2*, Flammability 1, Physical Hazard 0 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing

mist.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

GS-5 ADDITIVE

Page 2 of 6

HESI102335
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Odorless

pH: 2.5-4.5

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Excessive inhalation causes headache, dizziness, nausea and incoordination. May

cause respiratory irritation.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Harmful if swallowed. May cause kidney damage. May affect the heart and

cardiovascular system. May cause brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause reproductive system damage. Prolonged

or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

GS-5 ADDITIVE

Page 3 of 6

HESI102336
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

May adversely affect or disrupt reproductive development or other hormonally

controlled processes in both humans and animals.

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: LC50 (96): > 100 mg/l

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

GS-5 ADDITIVE

Page 4 of 6

HESI102337
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 10004 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

GS-5 ADDITIVE

Page 5 of 6

HESI102338
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GS-5 ADDITIVE

Page 6 of 6

HESI102339
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HL BREAKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HL BREAKER

Synonyms: None

Chemical Family: Hydroxide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium oxide 1305-78-8 60 - 100% 2 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HL BREAKER

Page 1 of 6

HESI102345
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 12.2

Specific Gravity @ 20 C (Water=1): 2.34

HL BREAKER

Page 2 of 6

HESI102346
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 31

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.2

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 74.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7340 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HL BREAKER

Page 3 of 6

HESI102347
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

HL BREAKER

Page 4 of 6

HESI102348
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

HL BREAKER

Page 5 of 6

HESI102349
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HL BREAKER

Page 6 of 6

HESI102350
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HMP CON

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HMP CON

Synonyms: None

Chemical Family: Proprietary Aqueous Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyethylene glycol 25322-68-3 10 - 30% Not applicable Not applicable

Sodium hydroxide 1310-73-2 0 - 1% 2 mg/m3 2 mg/m3

Potassium chloride 7447-40-7 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HMP CON

Page 1 of 6

HESI102351
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow to brown

Odor: Odorless

pH: > 13 (1%)

Specific Gravity @ 20 C (Water=1): 1.15

HMP CON

Page 2 of 6

HESI102352
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 25000 @ 25C

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HMP CON

Page 3 of 6

HESI102353
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

HMP CON

Page 4 of 6

HESI102354
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

HMP CON

Page 5 of 6

HESI102355
***END OF MSDS***

HMP CON

Page 6 of 6

HESI102356
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HYFLO IV SURFACTANT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HYFLO IV SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Naphthalene 91-20-3 5-10 10 ppm 10 ppm

Isooctanol 26952-21-6 5 - 10% 50 ppm Not applicable

Alkyl hexanol 5-10 Not applicable Not applicable

Heavy aromatic petroleum

naphtha

64742-94-5 30 - 60% 5 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

HYFLO IV SURFACTANT

Page 1 of 6

HESI102357
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 128

Flash Point/Range (C): 53

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

HYFLO IV SURFACTANT

Page 2 of 6

HESI102358
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to slightly hazy amber

Odor: Hydrocarbon

pH: 6.8

Specific Gravity @ 20 C (Water=1): 0.91

Density @ 20 C (lbs./gallon): 7.60

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 20.3

Vapor Density (Air=1): Not Determined

Percent Volatiles: 37.87

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. This material is an anesthetic. May cause central

nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

HYFLO IV SURFACTANT

Page 3 of 6

HESI102359
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Amyl Alcohol, Petroleum Naphtha), 3, III, (59 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Amyl Alcohol, Petroleum Naphtha), 3, UN1993, III, (59 C)

HYFLO IV SURFACTANT

Page 4 of 6

HESI102360
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Amyl Alcohol, Petroleum Naphtha), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Amyl Alcohol, Petroleum Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Amyl Alcohol, Petroleum Naphtha), 3, III, (59 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 263 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

HYFLO IV SURFACTANT

Page 5 of 6

HESI102361
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HYFLO IV SURFACTANT

Page 6 of 6

HESI102362
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HZ-10

Revision Date: 07-Mar-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HZ-10

Synonyms: None

Chemical Family: Polymer

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

HZ-10

Page 1 of 5

HESI102363
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Spills of this product are very slippery.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool, dry location. Store at temperature above

32 F (0 C). Do not freeze. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellowish

Odor: Odorless

pH: 3

HZ-10

Page 2 of 5

HESI102364
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HZ-10

Page 3 of 5

HESI102365
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: > 1000 g/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: EC50: > 1000 mg/l (Skeletonema costatum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

HZ-10

Page 4 of 5

HESI102366
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HZ-10

Page 5 of 5

HESI102367
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HZ-20

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HZ-20

Synonyms: None

Chemical Family: Polymer

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyamine 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

HZ-20

Page 1 of 6

HESI102368
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 212

Flash Point/Range (C): Not DeterminedMin: > 100

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a dry location. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow

Odor: Mild amine

pH: 12

HZ-20

Page 2 of 6

HESI102369
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): 5

Freezing Point/Range (C): -15

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact None known.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HZ-20

Page 3 of 6

HESI102370
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability COD: 20-70%

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S.(Contains Polyethyleneimine), 9, III, Marine Pollutant

Canadian TDG

Environmentally Hazardous Substance, Liquid, N.O.S.(Contains Polyethyleneimine), 9, UN3082, III, Marine Pollutant

ADR

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S.(Contains Polyethyleneimine), 9, III, Marine Pollutant

Air Transportation

ICAO/IATA

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S., 9, III

(Contains Polyethyleneimine Mixture), Marine Pollutant

Sea Transportation

HZ-20

Page 4 of 6

HESI102371
IMDG

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S.(Contains Polyethyleneimine), 9, III

, Marine Pollutant

EmS F-A, S-F

Other Shipping Information

Labels: Miscellaneous - Class 9

Marine Pollutant

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

HZ-20

Page 5 of 6

HESI102372
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HZ-20

Page 6 of 6

HESI102373
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: INJECTROL® COMPONENT A

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: INJECTROL® COMPONENT A

Synonyms: None

Chemical Family: Silicate

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium silicate 1344-09-8 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

INJECTROL® COMPONENT A

Page 1 of 6

HESI102374
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove. Do NOT spread spilled product with

water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to hazy

Odor: Slightly soapy

INJECTROL® COMPONENT A

Page 2 of 6

HESI102375
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 11.3

Specific Gravity @ 20 C (Water=1): 1.4

Density @ 20 C (lbs./gallon): 11.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 213

Boiling Point/Range (C): 100

Freezing Point/Range (F): 30

Freezing Point/Range (C): -2

Vapor Pressure @ 20 C (mmHg): 156

Vapor Density (Air=1): Not Determined

Percent Volatiles: 80

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May cause skin burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2000-3000 mg/kg (Rat)

Dermal Toxicity: Not determined

INJECTROL® COMPONENT A

Page 3 of 6

HESI102376
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

INJECTROL® COMPONENT A

Page 4 of 6

HESI102377
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

INJECTROL® COMPONENT A

Page 5 of 6

HESI102378
INJECTROL® COMPONENT A

Page 6 of 6

HESI102379
HESI102380
HESI102381
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: K-33

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: K-33

Synonyms: None

Chemical Family: Sulfite

Application: Oxygen Scavenger

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium bisulfite 7631-90-5 60 - 100% 5 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

K-33

Page 1 of 5

HESI102382
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Light tan

Odor: Mild sulfur

pH: 8.2

Specific Gravity @ 20 C (Water=1): 1.48

Density @ 20 C (lbs./gallon): Not Determined

K-33

Page 2 of 5

HESI102383
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 86

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 28

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 104.06

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Oxides of sulfur. Hydrogen sulfide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

K-33

Page 3 of 5

HESI102384
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

K-33

Page 4 of 5

HESI102385
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5000 Pounds based on Sodium bisulfite (CAS:

7631-90-5).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

K-33

Page 5 of 5

HESI102386
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: K-42

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: K-42

Synonyms: None

Chemical Family: Polymer

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

n,n`-Methylenebisacrylamide 110-26-9 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

K-42

Page 1 of 6

HESI102387
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Colorless

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.23

K-42

Page 2 of 6

HESI102388
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 71

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 154.19

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 390 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: LC50: > 2 mg/l/4 hr. (Rat)

K-42

Page 3 of 6

HESI102389
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2811,Toxic Solid, Organic, N.O.S.(Contains N,N'-Methylene Bisacrylamide), 6.1, III

NAERG 154

Canadian TDG

Toxic Solid, Organic, N.O.S.(Contains N,N'-Methylene Bisacrylamide), 6.1, UN2811, III

ADR

UN2811,Toxic Solid, Organic, N.O.S.(Contains N,N'-Methylene Bisacrylamide), 6.1, III

Air Transportation

ICAO/IATA

UN2811,Toxic Solid, Organic, N.O.S., 6.1, III

(Contains N,N'-Methylene Bisacrylamide Solution)

K-42

Page 4 of 6

HESI102390
Sea Transportation

IMDG

UN2811,Toxic Solid, Organic, N.O.S.(Contains N,N'-Methylene Bisacrylamide), 6.1, III

EmS F-A, S-A

Other Shipping Information

Labels: Keep Away From Food

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

K-42

Page 5 of 6

HESI102391
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

K-42

Page 6 of 6

HESI102392
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: KAYDOL WHITE MINERAL OIL

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: KAYDOL WHITE MINERAL OIL

Synonyms: None

Chemical Family: Organic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Mineral oil 8042-47-5 60 - 100% 5 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

KAYDOL WHITE MINERAL OIL

Page 1 of 6

HESI102393
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 425

Flash Point/Range (C): 218

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Water white

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.87

Density @ 20 C (lbs./gallon): 7.29

KAYDOL WHITE MINERAL OIL

Page 2 of 6

HESI102394
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 660

Boiling Point/Range (C): 348

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): <0.1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. Prolonged or repeated contact

may cause slight skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

KAYDOL WHITE MINERAL OIL

Page 3 of 6

HESI102395
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

KAYDOL WHITE MINERAL OIL

Page 4 of 6

HESI102396
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

KAYDOL WHITE MINERAL OIL

Page 5 of 6

HESI102397
***END OF MSDS***

KAYDOL WHITE MINERAL OIL

Page 6 of 6

HESI102398
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: KOL-SEAL

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: KOL-SEAL

Synonyms: None

Chemical Family: Coal

Application: Loss Circulation Material

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Coal, granular 50815-10-6 60 - 100% 0.9 mg/m3 1 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. May cause delayed injury to lungs. Airborne dust may be

explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

KOL-SEAL

Page 1 of 5

HESI102399
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 93

Flash Point/Range (C): Not DeterminedMin: > 200

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Flammable dust when in finely divided and highly suspended state.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 36

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Black

Odor: Coal

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.3

Density @ 20 C (lbs./gallon): Not Determined

KOL-SEAL

Page 2 of 5

HESI102400
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 50

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Toxic fumes. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause lung damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

KOL-SEAL

Page 3 of 5

HESI102401
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

KOL-SEAL

Page 4 of 5

HESI102402
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

KOL-SEAL

Page 5 of 5

HESI102403
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: KW-1

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: KW-1

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

KW-1

Page 1 of 5

HESI102404
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Product is not expected to burn unless all the water is boiled away. Decomposition

in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Product has a shelf

life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Sweet

pH: 4.1

KW-1

Page 2 of 5

HESI102405
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.02

Density @ 20 C (lbs./gallon): 8.50

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 64

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with oxidizers.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye and skin contact.

Inhalation None known.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

KW-1

Page 3 of 5

HESI102406
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

KW-1

Page 4 of 5

HESI102407
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

KW-1

Page 5 of 5

HESI102408
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: KW-2

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: KW-2

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium chloride 7447-40-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treatment should be directed at preventing absorption, administering to symptoms

as they occur, and providing supportive therapy.

KW-2

Page 1 of 5

HESI102409
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Product

has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Odorless

pH: 4

KW-2

Page 2 of 5

HESI102410
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye and skin contact.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

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Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

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