As per the requirements of the REACH regulation (EC) No.: 1907/2006

Revision Date : 16/11/2011, Date Printed : 1/23/2012 S-KCP 009/1 Page 1 of 10 

### 1 Identification of the substance/mixture and of the company/undertaking

· Product identifier

· Trade name: Registration number Pre-registration Number: Pr oprietary Basic violet 1 05-2116777483- 33 -0000 64

- 19 -7 Acetic acid glacial 05-2116777531- 40 -0000 111

- 46 -6 Diethylene glycol 05-2116777526- 31 -0000 7732

- 18 -5 Water Exempted from REACH Registration 7647- 01 -0 Hydrochloric acid 05-2116777507- 31 -0000 118

- 75 -2 p-chloranil 05-2116777525- 33 -0000 7440- 62 -2 Vanadium Not pre-registered - Tonnage < 1MT/Year 7439- 98 -7 Molybdenum Not pre-registered - Tonnage < 1MT/Year
· Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation Used as basic dye for ink production

· Details of the supplier of the safety data sheet
· Manufacturer/ Supplier:

· Further information obtainable from: Email: Telephone: Fax: Manufacturing Site : Email :

· Emergency telephone number: Emergency telephone number: +91 2646 654161, 654162, 654163 Opening hours: 24 Hrs Other comments (e.g. language(s) of the phone service): English 

### 2 Hazards identification

· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS05 corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage.

GHS09 environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

GHS07 Acute Tox. 4 H302 Harmful if swallowed. 

### FOR CHEMICAL EMERGENCY Spill, Leak, Fire, Exposure or Accident 

### CALL CHEMTREC®
- DAY OR NIGHT 

# 800 - 424 - 9300
OUTSIDE THE UNITED STATES CALL 703 - 527 - 3887As per the requirements of the REACH regulation (EC) No.: 1907/2006

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· Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R34: Causes burns. Xn; Harmful R22: Harmful if swallowed. N; Dangerous for the environment R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version.
· Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

· Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms

GHS05 GHS07 GHS09

· Signal word Danger

· Hazard-determining components of labelling: Basiv violet 1 2,2'-oxybisethanol
· Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects. Can become flammable in use.
· Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin

with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.
· Other hazards
· Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.As per the requirements of the REACH regulation (EC) No.: 1907/2006

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### 3 Composition/information on ingredients

· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous components: CAS: Proprietary Basic violet 1

Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, 50.0±5%

CAS: 64

- 19

- 7 EINECS: 200

- 580

- 7 acetic acid C R35 R10 Flam. Liq. 3, H226; Skin Corr. 1A, H314 35.0±5%

CAS: 111

- 46

- 6 EINECS: 203

- 872

- 2 2,2'

- oxybisethanol Xn R22 Acute Tox. 4, H302 4.0±1%

CAS: 7647

- 01

- 0 EINECS: 231

- 595

- 7 hydrogen chloride C R34; Xi R37 Skin Corr. 1B, H314; STOT SE 3, H335 2.0±0.5%

CAS: 118

- 75

- 2 EINECS: 204

- 274

- 4 tetrachloro

- p - benzoquinone Xi R36/38; N R50/53 Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Skin Irrit. 2, H315; Eye Irrit. 2, H319 0.9±0.1%

CAS: 7732

- 18

- 5 EINECS: 231

- 791

- 2 water, distilled, conductivity or of similar purity 6.0±2% CAS: 7440

- 62

- 2 EINECS: 231

- 171

- 1 vanadium

R52 0.12±0.5% CAS: 7439

- 98

- 7 EINECS: 231

- 107

- 2 molybdenum

R33 Press. Gas, H280; STOT RE 2, H373 0.073±0.05 %

· Additional information: For the wording of the listed risk phrases refer to section 16.


### 4 First aid measures

· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product. · After inhalation: Remove from contaminated area. Encourage patient to blow nose to ensure clear passage of breathing. If irritation or discomfort persists seek medical attention
· After skin contact: If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
· After eye contact: If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. If pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel · After swallowing:If swallowed do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (headdown position, if possible) to maintain open airway and prevent aspiration. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. · Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.

·As per the requirements of the REACH regulation (EC) No.: 1907/2006

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### 5 Firefighting measures

· Extinguishing media
· Suitable extinguishing agents: Use water spray or fog, foam, dry chemical powder, BCF (where regulations permit), carbon dioxide · For safety reasons unsuitable extinguishing agents: Avoid contact with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. · Special hazards arising from the substance or mixture Combustion products include: nitrogen oxides (NOx) and sulfur oxides (SOx). · Advice for firefighters
· Protective equipment: • Wear breathing apparatus plus protective gloves. • Alert Fire Brigade and tell them location and nature of hazard.


### 6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Keep away from ignition sources. Ensure adequate ventilation
· Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Do not flush with water or aqueous cleansing agents · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 

### 7 Handling and storage

· Handling:
· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols.
· Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges.

· Conditions for safe storage, including any incompatibilities · Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool, dry, well-ventilated area away from incompatible substances.
· Information about storage in one common storage facility: Store away from oxidizing agents. · Further information about storage conditions: Keep container tightly sealed. · Specific end use(s) Used as basic dye for ink productionAs per the requirements of the REACH regulation (EC) No.: 1907/2006

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### 8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7. · Control parameters

· Ingredients with limit values that require monitoring at the workplace: 64
- 19
- 7 acetic acid IOELV (EU) 25 mg/m3, 10 ppm 7647
- 01
- 0 hydrogen chloride IOELV (EU) Short

- term value: 15 mg/m3, 10 ppm

Long

- term value: 8 mg/m3, 5 ppm 7440
- 62
- 2 vanadium IDLH Value 35mg/m3 7439
- 98
- 7 molybdenum IDLH Value 5000mg/m3 STEL 20 ppm

· Exposure controls · Personal protective equipment:
· General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Respiratory protection: In case of brief exposure or low pollution use NIOSH certified organic vapor cartridge respirator. In case of intensive or longer exposure use self-contained respiratory protective device. · Protection of hands:

Impervious gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves PVC gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection: Safety glasses with side shield.
· Body protection: Protective work clothing 

### 9 Physical and chemical properties

· Information on basic physical and chemical properties · General Information
· Appearance: Form: Colour:As per the requirements of the REACH regulation (EC) No.: 1907/2006

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· Odour:

· pH
- value:

· Change in condition Melting point/Melting range:

· Flash point:

· Flammability (solid, gaseous): Not applicable.

· Ignition temperature:

· Self
- igniting: Product is not selfigniting.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

· Explosion limits: Lower: 4.0 Vol % Upper: 17.0 Vol %

· Vapour pressure at 20°C:

· Density: Not determined.

· Solubility in / Miscibility with water: Miscible

· Solvent content: Organic solvents: 39.0 % Water: 6.0 % VOC (EC) 39.00 % Solids content: 52.9 %
· Other information No further relevant information available.


### 10 Stability and reactivity

· Reactivity · Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions Hazardous polymerization will not occur
· Conditions to avoid Heat, flame and other sources of ignition · Incompatible materials: Avoid contact with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc · Hazardous decomposition products: Combustion products include: nitrogen oxides (NOx) and sulfur oxides (SOx). 

### 11 Toxicological information

· Information on toxicological effects · Acute toxicity:
· LD/LC50 values relevant for classification: 64
- 19 -7 acetic acid Oral LD50 3310 mg/kg (rat) Dermal LD50 1060 mg/kg (rabbit) 118- 75
- 2 tetrachloro-p-benzoquinone Oral LD50 4000 mg/kg (rat)As per the requirements of the REACH regulation (EC) No.: 1907/2006

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· Specific symptoms in biological assay: VANADIUM- Exposure to vanadium dusts can induce cough, rhinorrhea, ocular burning and conjunctivitis, nasal catarrh and hemorrhage, wheezing , rales, green to black tongue and bronchi. MOLYBDENUM- An increased incidence of non-specific symptoms including headache,weakness, fatigue, anorexia and joint and muscle weakness has been reported to occur in mining and metallurgy workers exposed to 60-600 mg (as Mo). Some investigators have attributed gout and elevated uric acid concentration found in some Armenians to result from exposures to Armenian soils rich in molybdenum, whilst exposure has been implicated as a cause of bone disease amongst Indians. DIETHYLENE GLYCOL- The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterized by skin redness (erythema) and swelling epidermis.Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis. HYDROCHLORIC ACID- Asthma-like symptoms may continue for months or even years after exposure to the material ceases. · Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes. · on the eye: Strong caustic effect.
· Sensitization: No sensitizing effects known. · Subacute to chronic toxicity: VANADIUM: Subcutaneous (rabbit) LD50: 59 mg/kg P-CHLORANIL: Intraperitoneal (rat) LD50: 500 mg/kg · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Corrosive Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. 

### 12 Ecological information

· Toxicity

· Acquatic toxicity: 118
- 75
- 2 tetrachloro
-

p - benzoquinone EC50 (24hr) (static) LC50 (96hr) (static) < 0.36 mg/L (Daphnia magna)

4.6 mg/L (Leuciscus idus (Fish, fresh water))

· Persistence and degradability No further relevant information available. · Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available.
· Ecotoxical effects: · Remark: Very toxic for fish
· Additional ecological information: · General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Must not reach sewage water or drainage ditch undiluted or unneutralized.As per the requirements of the REACH regulation (EC) No.: 1907/2006

Revision Date : 16/11/2011, Date Printed : 1/23/2012 S-KCP 009/1 Page 8 of 10 Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms
· Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
· Other adverse effects No further relevant information available. 

### 13 Disposal considerations

· Waste treatment methods · Recommendation Dispose off waste material according to local, state and federal regulations. Recycle wherever possible or consult manufacturer for recycling options. Bury residue in an authorised landfill.

· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations. Recycle containers if possible, or dispose of in an authorised landfill. 

### 14 Transport information

· UN
- Number
· ADR, IMDG, IATA UN2801

· UN proper shipping name
· ADR 2801 DYE, LIQUID, CORROSIVE, N.O.S. (ACETIC ACID, GLACIAL, HYDROCHLORIC ACID), ENVIRONMENTALLY HAZARDOUS · IMDG, IATA D Y E , L I Q U I D , C O R R O S I V E , N

. O

. S

. ( A C E T I C A C I D , GLACIAL, HYDROCHLORIC ACID)

· Transport hazard class(es)

· ADR

· Class 8 Corrosive substances. · Label 8+6.1

· IMDG

· Class 8 Corrosive substances.
· Label 8+6.1
· IATA

· Class 8 Corrosive substances.
· Label 8+6.1As per the requirements of the REACH regulation (EC) No.: 1907/2006

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· Packing group
· ADR, IMDG, IATA III

· Environmental hazards: Product contains environmentally hazardous substances: Basic violet 1
· Marine pollutant: Yes Symbol (fish and tree) · Special marking (ADR): Symbol (fish and tree)

· Special precautions for user Warning: Corrosive substances.
· Danger code (Kemler): 38
· EMS Number: F-A,S-B
· Segregation groups Acids

· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information:

· ADR
· Tunnel restriction code D/E

· UN "Model Regulation": UN2801, DYE, LIQUID, CORROSIVE, N.O.S. (ACETIC ACID, GLACIAL, HYDROCHLORIC ACID), ENVIRONMENTALLY HAZARDOUS, 3 (8), III 

### 15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Labelling according to Regulation (EC) No 1272/2008
· Hazard pictograms Please refer section 2 · Signal word Danger · Hazard statements Please refer section 2
· Precautionary statements Please refer section 2 · Chemical safety assessment: A Chemical Safety Assessment has not been carried out and shall be available at the time of REACH registration. 

### 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrases H226 Flammable liquid and vapour. H280 Contains gas under pressure; may explode if heated. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. R10 Flammable. R22 Harmful if swallowed. R33 Danger of cumulative effects. R34 Causes burns. R35 Causes severe burns. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52 Harmful to aquatic organisms.As per the requirements of the REACH regulation (EC) No.: 1907/2006

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· Department issuing MSDS: Product safety department.
· Contact: Corporate Office : Email: Telephone: Fax: Manufacturing Site : Email : Tel : Fax :
· Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organization GHS: Globally Harmonized System of Classification and Labelling of Chemicals VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent · Sources REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
· * Data compared to the previous version altered. • Section 2 : Hazard Identificat ion - Changes in classification and labelling • Section 6 : Accidental Release Measures • Section 7 : Handling and Storage • Section 8 : Exposure Controls / Personal Protection • Section 9 : Physical and Chemical Properties • Section 10 : Stability and Reactivity • Section 11 : Toxicological Information • Section 12 : Ecological Information • Section 13 : Disposal Considerations