## Appendix A Eastman Chemical Company Supplemental Submittal to Petition for Reconsideration, Amendment, and Administrative Stay of Commercial and Industrial Solid Waste Incineration Units (78 Fed. Reg. 9112)
Boiler 20 NOx Data Collection & Reporting A NOx analyzer was temporarily installed on an existing 02 dry-extractive CEMS equipped with a data acquisition and handling system (DAHS). NOx and 02 CEMS data were collected by a data controller, which computed minute averages and hourly averages of ppm NOx, %02, and ppm NOx corrected to 7% 02. Minute and hourly average data were polled from the data controller by a PC and archived by the DAHS. Hourly average %02, ppm NOx, and ppm NOx corrected to 7% 02 data are reported from 5/3/13 to 5/17/13, and from 5/23/13 to 6/10/13, during normal operation at Boiler 20. About 80% of data were collected while burning coal only, and about 20% while burning both coal and bio-sludge. During the period from 5/17/13 to 5/23113, the NOx analyzer was removed from Boiler 20 for other monitoring needs.

Boiler 20 NOx & 02 Data Quality Assurance Quality of NOx data were assured by: • Daily Calibration Drift testing (per 40 CFR 60 Appendix F& Performance Specification 2 in 40 CFR 60 Appendix B) • 7-Day Calibration Drift test (per Performance Specification 2 in 40 CFR 60 Appendix B) • Cylinder Gas Audit (per 40 CFR 60 Appendix F) Quality of 02 data were assured by: • Daily Calibration Drift testing (per Performance Specification 3 in 40 CFR 60 Appendix B) • 7-Day Calibration Drift test (per Performance Specification 3 in 40 CFR 60 Appendix B)
Results of all quality assurance tests are included below. CEMS times are all Eastern Standard Time, because the CEMS maintains Standard Time throughout the year.

### Eastman Chemical Company Environmental Services Laboralory



## Seven Day Calibration Drift Determination

for MACT or RCRA CEMS
Date: 5/14/2013 Reason for Test: Initial Certification Source: 20 Reason for Test: Building: B-83
Monitor: NOx, Span: 600 ppmv PrimaryAnalyzer: TEC042C-HL 42CHL-75882 AlternateAnalyzer: Performed By: 

## I RLZ
C linder Number Concentration Units 

## I Ex iration Date I heck Ex



### . Nitro en 0 ppmv CC422761 546.0 ppmv 12/10/2020 OK mv ppmv
Day Date Time Reference Values ppmv Actual Values ppmv Absolute

Difference ppmv Percent

of Span
1 5/812013 8:29 0 1.7 1.7 0.3% 2 5/9/2013 8`.06 0 0.5 0.5 0.1% 3 5110/2013 8:13 0 0.0 0.0 0.0% ZERO (LOW LEVEL) 4 5/1112013' 7:44 0 0.0



### . 0.0 0.0% 5 5/12/2013. 

### ` 8:45



### . 0 0:0



### . 0.0 0.0% 6 5/13/2013 9:08 0 0:8 0.8 0.1 

### % 7 5/14/2013 

## 1 8:06 0 0.1 0.1 0.0% Maximum Limit <= 2.5% of S an 1.7 0.3% PASS 1 5/8/2013 8:33 546.0 537.8 8.2 1.4% 2 5/9/2013 8:10 546.0 540.1 5.9 1.0% 3 5/10/2013 8;18 546.0 540.7 5.3 1 0.9% HIGH LEVEL 4 5/11/2013 7:55 546.0 541.2 4.8 0.8% 5 5/12/2013 8:50 546:0 539.3 6.7 1.1 

### % 6 5/13/2013 9:13 546:0 540.5 5.5 0.9% 7 5/14/2013 8:11 546.0 1543.1 2.9 0.5% Maximum Limit <= 2.5% of Spa n 8.2 1.4% PASS
Comments: Tliis test was conducted for 

## qu ality assurance of th e NOx analyzer temporarily insta Iled on the permanent O 2 CEM S at Boiler 20 

## in order to Explain "Reason record NOx emissions data. It was p erformed for initial certif ication after the analyzer was placed in senrice on 5/2/13. No adjustment s weie for Test," e.g., cite made to the NOx anlayzer during the 7-da y test period. the maintenance event, if "Diagnostic."

Reviewed B: IJoseph Kellogg

Document Number: THSE-ESL-CEM-5015-3 Effective Date: 06/23/05Eastman Chemical Company Environmental Services Laboralory



### Seven Day Calibration 

## Drift Determination

for MACT or RCRA CEMS

Monitor: 

# I NOx Span: 600 ppmv PrimaryAnalyzer: 

## I TEG042C-HL 42CHL-75882 AlternateAnalyzer: Performed By: IRLZ
C Iinder Number Concentration Units Ex iration Date Check Ex

. Nitro en 0 ppmv CC422761 546.0 ppmv 12/10/2020 OK mv ppmv

Day Date Time Reference Values ppmv Actual Values ppmv Absolute

Difference ppmv Percent

of Span
1 5/25/2013 8:00 0 4`.9 4.9 0.8% 2 5/26/2013 8:26 0 4.1 4.1 0.7% 3 5/27/2013 8:29 0 3.2 3.2 0.5% ZERO (LOW LEVEL) 4 5/28/2013 9`.52 0 5.4 5.4 0.9% 5 5/29/2013 8:02 0 4.9 4.9 0.8% 6 5/30/2013 8:46 0 4.4 4.4 0.7% 7 5/31/2013 8:11 0 4.5 4.5 0.8% Maximum Limit <= 2.5% of Span 5.4 0.9% PASS 1 5/25/2013 8:04 546.0 533.0 13.0 2.2% 2 5/26/2013 8:31 546.0 535.2 10.8 1.8% 3 5/27/2013 8:34 546.0 533.0 13.0 1 2.2% HIGH LEVEL 4 5/28/2013 9:56 546.0 535.2 10.8 1.8% 5 5/29/2013

. 8:05 546.0 533.7 12.3 2.0% 6 5/30/2013 8:50 546.0 539.7 6.3 1.0% 7 1 5/31/2013 8:15 546.0 547.4 1.4 0.2% Maximum Limit <= 2.5% of Span 13.0 2.2% PASS
Comments: This test was,conducted for qu ality assuYance of th e NOx analyzer temporarily insta Iled on the permanent O 2 CEMS at Boiler 20 in order to Explain "Reaso n record NO x emissions data. It was.p erPormed for.recer tification after the ana lyzer had been remove d from service on 5/1 7/13 and then for Test," e.g., cite returned to service on 5/23/1 3. No adjustments were made to the NOx anlayzer dur ing the 7-day test perio d. the maintenance event, if

„ Diagnostic."

Reviewed B : IJoseph Kellogg

Document Number: THSE-ESL-CEM-5015-3 Effective Date: 06/23/05Boiler 20 Temporary NOx CEMS Calibration Check Data

Level NOx Concentration IGas Ex iration Zero 0.0 ppm Nitrogen N/A Hi h 546.0 ppm CC422761 12/10/2020 600 ppm INOXCEMS anal zer s an value 2.5% of span NOx CEMS Calibration Drift Performance Specification (40 CFR 60, Appendix B, Performance Specification 2, Section 13.1) 5.0% of soan NOx CEMS Dailv Calibration Drift ReauiremenE (40 CFR 60, Appendix F, Section 4.1



### _

Calibration NOx

Reference Value 

### ( m) NOx

Actual Response 

### ( m) NOx

Calibration Drift Values (% ofs an). NOx

Calibration Drift Limit (% ofs an) NOx_

Calibration Drift Status (Pass/Fail) Event Date Time Level Date Time Description

5/2/2013 13:06 High 546.0 542.7 -0.5% 5.0% Pass 5/2/2013 13:17 Zero 0.0 2.2 0.4% 5.0% Pass 5/2/2013 13:31 Begin NOx analyzer on-line 5/3/2013 7:33 Zero 0.0 0.7 0.1% 5.0% Pass 5/3/2013 7:38 High 546.0 547.3 0.2% 5.0% Pass 5/3/2013 8:08 Start Cylinder Gas Audit 5/3/2013 8:33 End Cylinder Gas Audit 5/4/2013 8:33 Zero 0.0 2.6 0.4% 5.0% Pass 5/4/2013 8:37 High 546.0 531.2 -2.5% 5.0% Pass 5/5/2013 7:28 Zero 0.0 0.0 0.0% 5.0% Pass 5/5/2013 7:33 High 546.0 532.9 -2.2% 5.0% Pass 5/6/2013 8:36 Zero 0.0 0.0 0.0% 5.0% Pass 5/6/2013 8:40 High 546.0 532.5 -2.3% 5.0% Pass 5/7/2013 8:08 Zero 0.0 0.0 0.0% 5.0% Pass 5/7/2013 8:13 High 546.0 529.6 -2.7% 5.0% Pass 5/8/2013 8:29 Zero 0.0 1.7 0.3% 5.0% Pass 5/8/2013 8:29 Start 7-Day Calibration Drift 5/8/2013 8:33 High 546.0 537.8 -1.4% 5.0% Pass 5/9/2013 8:06 Zero 0.0 0.5 0.1% 5.0% Pass 5/9/2013 8:10 High 546.0 540.1 -1.0% 5.0% Pass 5/10/2013 8:13 Zero 0.0 0.0 0.0% 5.0% Pass 5/10/2013 8:18 High 546.0 540.7 -0.9% 5.0% Pass 5/11/2013 7:44 Zero 0.0 0.0 0.0% 5.0% Pass 5/11/2013 7:55 High 546.0 541.2 -0.8% 5.0% Pass 5/12/2013 8:45 Zero 0.0 0.0 0.0% 5.0% Pass 5/12/2013 8:50 High 546.0 539.3 -1.1% 5.0% Pass 5/13/2013 9:08 Zero 0.0 0.8 0.1% 5.0% Pass 5/13/2013 9:13 High 546.0 540.5 -0.9% 5.0% Pass 5/14/2013 8:06 Zero 0.0 0.1 0.0% 5.0% Pass 5/14/2013 8:11 High 546.0 543.1 -0.5% 5.0% Pass 5/14/2013 8:11 7-Day Calibration Drift Passed 5/15/2013 8:25 Zero 0.0 0.0 0.0% 5.0% Pass 5/15/2013 8:30 High 546.0 556.2 1.7% 5.0% Pass 5/16/2013 9:31 Zero 0.0 0.1 0.0% 5.0% Pass 5/16/2013 9:36 High 546.0 537.6 -1.4% 5.0% Pass 5/17/2013 7:09 Begin NOx analyzer off-line S/23/2013 9:12 Zero 0.0 4.5 0.8% 5.0% Pass 5/23/2013 9:15 High 546.0 544.1 -0.3% 5:0% Pass 5/23/2013 9:35 End NOx analyzer off-line 5/23/2013 10:45 Start Cylinder Gas Audit 5/23/2013 11:12 End Cylinder Gas Audit 5/24/2013 10:22 Zero 0.0 4.3 0.7% 5.0 0 /. Pass 5/24/2013 10:27 High 546.0 530.5 -2.6% 5.0% Pass 5/25/2013 8:00 Zero 0.0 4.9 0.8% 5.0% Pass 5/25/2013 8:00 Start 7-Day Calibration Drift 5/25/2013 8:04 High 546.0 533.0 -2.2% S.0% Pass 5/26/2013 8:26 Zero 0.0 4.1 0.7% 5.0% Pass 5/26/2013 8:31 High 546.0 535.2 -1.8% 5.0% Pass 5/27/2013 8:29 Zero 0.0 3.2 0.5% 5.0% Pass 5/27/2013 8:34 High 546.0 533.0 -2.2% 5.0% Pass 5/28/2013 9:52 Zero 010 5.4 0.9% 5.0% Pass 5/28/2013 9:56 High 546.0 535.2 -1.8% 5.0% Pass 5/29/2013 8:02 Zero 0.0 4.9 0.8% 5.0% Pass 5/29/2013 8:05 High 546.0 533.7 -2.0% 5.0% Pass 5/30/2013 8:46 Zero 0.0 4.4 0.7% 5.0% Pass 5/30/2013 8:50 High 546.0 539.7 -1.0% 5.0% Pass 5/31/2013 8:11 Zero 0.0 4.5 0.8% 5.0% Pass 5/31/2013 8:15 High 546.0 547.4 0.2% 5.0% Pass 5/31/2013 8:15 7-Day Calibration Drift Passed 6/1/2013 9:48 Zero 0.0 4.3 0.7% 5.0% Pass 6/1/2013 9:54 High 546.0 542.6 -0.6% 5.0% PassCalibration NOx Reference Value 

### m NOx

Actual 

### Response m NOx Calibration Drift Values % ofs an NOx

Calibration Drift Limit % ofs an NOx

Calibration Drift Status Pass/Fail Event Date Time Level Date Time Description

6/2/2013 6:37 Zero 0.0 4.5 0.8% 5.0% Pass 6/2/2013 6;43 High 546.0 543.3 -0.5% 5.0% Pass 6/3/2013 8:23 Zero 0.0 4.8 0.8% 5.0% Pass 6/3/2013 8:27 High 546.0 541.2 -0.8% 5.0% Pass 6/4/2013 7:36 Zero 0.0 5.5 0.9% 5.0% Pass 6/4/2013 7:39 High 546.0 546.8 0.1% 5.0% Pass 6/5/2013 9:50 Zero 0.0 4.6 0.8% 5.0% Pass 6/5/2013 9:53 High 546.0 556.0 1.7% 5.0% Pass 6/6/2013 7:45 Zero 0.0 5.5 0.9% 5.0% Pass 6/6/2013 7:49 High 546.0 543.3 -0.5% 5.0% Pass 6/7/2013 8:01 Zero 0.0 4.7 0.8% 5.0% Pass 6/7/2013 8:05 High 546.0 546.0 0.0% 5.0% Pass 6/8/2013 8:44 Zero 0.0 4.1 0.7% 5.0% Pass 6/8/2013 8:47 High 546.0 550.6 0.8% 5.0% Pass 6/9/2013 8:38 Zero 0.0 5.1 0.9% 5.0% Pass 6/9/2013 8:41 High 546.0 552.2 1:0% 5.0% Pass 6/10/2013 6:48 Boiler 20 off-line

### Eastman Chemical CQnpany Environmental Servbes Laboratory



# NOx Cylinder Gas Audit Determination
Date: 5/3/2013 Reason for Test: 

### Initial Certification Source: 

### Boiler20 

## ' Reason for Test: 

### 2nd Quarter C G Audit Building: B-83 Test Aborted: No Primary Anal zer: TECO 42C-HL 

# I 42CHL-75882 Alternate Analyzer: Performed By: 

# I RLZ
Monitor: NOx Span: 600 ppmv Level Cylinder Number Concentration 

### Units Expiration Date Check Low CC72443 150.3 ppmv 3/22/2014 OK: 120-180 High CC48550 337.8 ppmv 1/31/2021 OK: 300-360 Start Time: 8:08 Finish Time: 8:33
Run Reference Value ppmv Actual Value ppmv

Average Values 

## & CEMS Accurac Low High 

### ppmv 

## p mv 154.0 341.5 3.7 3.7 2% 1 

## % PASS PASS Low 

## - 1 150.3 153.1 Hi h -1 337.8 340.2 Low 

## - 2 150.3 154.6 High 

## - 2 337.8 342:9 Low 

## - 3 150.3 154.2 Hi h- 

### 3 337.8 341:5 Average CEMS Responss CEMS Accuracy (ppmv) CEMS Accuracy (percent) Limit 

### <= 15% (or 

### <= 5 ppmv)


### Comments: This testwas conducted for quality assurance 

# of the NOx analyzer temporarily installed 

# on the permanent 02 CEMS 

# at Explain "Reason Boiler 20 

# in order to record NOx emissions data. It was performed for initial certification on 5/3/13 after the analyzer was for Test," e.g., cite placed in service on 5/2/13. the maintenance event, if "Dia nostic." Reviewed B: IJoseph Kello g

Document Number: lHSE-ESL-CEM-5065-3 Effective Date: June14, 2010

### Eastman Chemical Canpany Environmental Servbes Laboratory



## NOx Cylinder Gas Audit Determination
Date: 5/23/2013 Reason for Test: 

### Recertification Source: Boiler 20 Reason for 

### Test: Building: B-83 Test Aborted: No Primary Anal zer: TECO 42C-HL 

# I 42CHL-75882 Alternate Analyzer: Performed By: 

# I RLZ
Monitor: NOx Span: 600 ppmv Level Cylinder Number Concentration Units Expiration Date Check Low CC72443 150.3 ppmv 3/22/2014 OK: 120-180 High CC48550 337.8 ppmv 1/31/2021 OK: 300-360 Start Time: 10:45 Finish Time: 11:12
Run Reference Value ppmv Actual Value 

### ppmv

Avera e Values 

### & CEMS 

### Accuracy Low High 

### ppmv ppmv 154.4 338.9 4.1 1.1 3% 0% PASS I PASS Low - 1 150.3 153.7 Hi h- 1 337.8 335.9 Low - 2 150.3 153.6 High - 2 337.8 336.7 Low 

### - 3 150.3 155.8 High - 3 1 337.8 344.0 Average CEMS Response CEMS Accuracy (ppmv) CEMS Accuracy (percent) Limit 

### <= 15% (or 

### <= 5 ppmv)
Comments: This test was conducted for quality assurance of the NOx analyzer temporarily installed on the permanent 02 CEMS at Explain "Reason Boiler 20 in order to record NOx emissions data. It 

# wm performed for recertification on 5/23/13 after the analyzer had for Test," e.g., cite been removed from service on 5/17/13 and then returned to service earlier on 5/23/13. the maintenance event, if "Diagnostic." Reviewed B : IJoseph Kellogg

Document Number:
- TI ISE-ESL-CEM-5065-3 Effective Date: June14, 2010

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### Eastman Chemical Company Environmental Services Laboralory



## Seven Day Calibration Drift Determination

for MACT or RCRA CEMS

Monitor: 

## 1 02 

## 1 Span: 

## 1 25 % Primary Analyzer: 

## I Servomex 1440 

## I 01440DIV02/3705 

## I Alternate Analyzer: Performed By: IRLZ
C linder Number Concentration Units Ex iration Date 

## I Check Ex

. 

### Nitro en 0 % 

### XC008802B 15.02 % 

### 2/27/2021 OK CC172026 15.00 % 

### 2/2712021 OK %



### Day Date Time Reference Values Actual Values Absolute

Difference Percent

of Span
1 5/8/2013 5:28 0 0.0 0.0 0.0% 2 5/9/2013 5:27 0 0.0 0.0 0.0% 3 5/10/2013 5:27 0 0.0 0.0 0.0% ZERO (LOW LEVEL) 4 5/11/2013 5:27 0 0.0 0.0 0.0% 5 5/12/2013 5:27 0 0.0 0.0 

## 1 0.0% 6 5/13/2013 5:28 0 0.0 0.0 

## 1 0.0% 7 5/14/2013 5:27 0' 0.0 0.0 0.0% Maximum Limit <= 0.5% Difference 0.0 0.0% PASS 1 51812013 5:28 15.0 14.8 0.2 0.8% 2 5/9/2013 5:27 15.0 14.9

. 

### 0.1 0.4% 3 5/10/2013 5:27 15.0 14.9 : 

### 0.1 0.4% HIGH LEVEL 4 5/11/2013 5:27 15.0 14.8 0.2 0.8% 5 5/12/2013 5:27 15.0 14.8 0.2 0.8% 6 5/13/2013 5:28 15.0 14.9 0.1 0.4% 7 5/14/2013 5:27 15.0 14.9 0.1 0.4% Maximum Limit <= 0.5% Difference 0.2 0.8% PASS
Comments: This test was conducted for qu ality assurance of th e permanent 02 CEMS at Boiler 20 in order to recor d NOz emissions data cor rected to Explain "Reaso n 7%,02. It was perrormed for recer tification of the 02 CEMS afte r the NOx analyzer was fir st placed in service on this CEMS on 5/2/2013. : for Test," e.g., cite Cylinder XC008802B was removed f rom service after the daily cal check on 5/9 /2013, and cylinder C C172026 was put in service before the the maintenance daily cal check on 5/10/2013. N o adjustments were made to the 02 anlayzer during the 7-day test period. The pe rmanent 02 CEMS was in event, if service continuously from 5/2/20 13, when the NOx analyze r was first installed, thr ough 6/10/2013, wh en.NOx monitoring ceased . "Diagnostic." i



### Reviewed B: iJoseph Kellogg

Document Number: THSE-ESL-CEM-5015-3 Effective Date: 06/23/05