United States

Environmental Protection

Agency

EPA-600/R-98-131-

October 1998

Research and

Development

DEMONSTRATION OF A

NO-VOC/NO-HAP WOOD KITCHEN

CABINET COATING SYSTEM

Prepared for

Environmental Technology Initiative

Prepared by

National Risk Management

Research Laboratory

Research Triangle Park, NC 2771 I
FOREWORD

The U. S. Environmental Protection Agency is charged by Congress with protecting the Nation’s land, air, and water resources. Under a mandate of national

environmental laws, the Agency strives to formulate and implement actions leading to a compatible balance between human activities and the ability of natural

systems to support and nurture life. To meet this mandate, EPA’s research

program is providing data and technical support for solving environmental problems today and building a science knowledge base necessary to manage our ecological resources wisely, understand how pollutants affect our health, and prevent or reduce environmental risks in the future.

The National Risk Management Research Laboratory is the Agency’s center for

investigation of technological and management approaches for reducing risks

from threats to human health and the environment. The focus of the Laboratory’s

research program is on methods for the prevention and control of pollution to air,

land, water, and subsurface resources; protection of water quality in public water

systems; remediation of contaminated sites and groundwater; and prevention and

control of indoor air pollution. The goal of this research effort is to catalyze

development and implementation of innovative, cost-effective environmental

technologies; develop scientific and engineering information needed by EPA to

support regulatory and policy decisions; and provide technical support and information transfer to ensure effective implementation of environmental regulations

and strategies.

This publication has been produced as part of the Laboratory’s strategic longterm research plan. It is published and made available by EPA’s Office of Research and Development to assist the user community and to link researchers

with their clients.

E. Timothy Oppelt, Director

National Risk Management Research Laboratory

EPA REVIEW NOTICE

This report has been peer and administratively reviewed by the U.S. Environmental

Protection Agency, and approved for publication. Mention of trade names or

commercial products does not constitute endorsement or recommendation for use.

This document is available to the public through the National Technical Information

Service, Springfield, Virginia 22161.
EPA-600/R-98-131

October 1998

DEMONSTRATION OF A

NO-VOC/NO-HAP WOOD KITCHEN CABINET COATING SYSTEM

Prepared by:

Eddy W. Huang

AeroVironment Environmental Services, Inc.

222 E. Huntington Drive

Monrovia, CA 91016

EPA Contract No. 68-D5-0128 (Option 2)

EPA Project Officer:

Robert C. McCrillis

U.S. Environmental Protection Agency (MD-61)

National Risk Management Research Laboratory

Air Pollution Prevention and Control Division

Research Triangle Park, NC 27711

Prepared for:

U.S. Environmental Protection Agency

Office of Research and Development

Washington, D.C. 20460
ABSTRACT

The United States Environmental Protection Agency has contracted with AeroVironment

Environmental Services, Inc. and its subcontractor, Adhesive Coatings Co., to develop and

demonstrate a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood

furniture coating system. The overall objective of this contract was to promote the wider utilization

of low-to-no-VOCXIAP wood furniture coatings. The results of the basic contract, to demonstrate

the application of this coating system to residential wood furniture, have already been published.

The objective of Option 2 (Option 1 was not exercised) of this contract was to demonstrate the

coating system at one or more kitchen cabinet manufacturing plants and to implement the technology

transfer plan to make furniture manufacturers aware of the product’s application and performance

characteristics.

This no-VOC/no-HAP coating system was demonstrated at cabinet manufacturing plants in Portland,

OR, and Redwood City, CA . Technology transfer efforts were made by presentations at

conferences and workshops and publication in journals.

A survey of seven wood kitchen cabinet manufacturers in California’s South Coast Basin was

conducted to gain a more in depth understanding of the problems they faced when switching from

solvent- to water-based coatings.

Outside of this contract, the adaptability of the coating to metal substrates on chassis components

was demonstrated at two large recreational vehicle manufacturers. Also outside of this contract,

preliminary analysis of the potential for incorporating epoxidized vegetable oils into new resins was

completed.

ii
CONTENTS

Section

1.0

2.0

3.0

4.0

5.0

6.0

ABSTRACT ...............................................

LISTOFFIGURES .........................................

ACKNOWLEDGMENTS ....................................

INTRODUCTION ..........................................

DEMONSTRATION ........................................

TECHNOLOGY TRANSFER .................................

MANUFACTURER FOLLOW-UP PROGRAM ..................

CONCLUSIONS AND RECOMMENDATIONS .................

REFERENCES ............................................

............ ii

............ iv

............ iv

. . . . . . . . . . 1

. . . . . . . . . . 2

. . . . . . . . . . 8

. . . . . . . . . . 9

. . . . . . . . . 11

. . . . . . . . . 12

APPENDICES

APPENDIX A - MANUFACTURER TELEPHONE INTERVIEW NOTES .......... Al

APPENDIX B - COATING TECHNICAL DATA SHEETS AND MATERIAL

SAFETY DATA SHEETS .................................................. Bl

B.l. TOP COAT .................................................. B1.l

B.2. SANDING SEALER ........................................... B2.1

B.3.STAINBASE .................................................. B3.1

APPENDIX C - CASE STUDIES ............................................ Cl

C. 1. FIELD DEMONSTRATION FOR APPLICATION ON METALS ....... Cl. 1

C.2. POTENTIAL FORMULATION USING SOY BEAN OIL ............. C2.1

. . .

111
LIST OF FIGURES

Figure 1. Stanford University library cabinet (doors open) after refinishing with zero VOC/

HAP stain, sanding sealer, and satin topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6

Figure 2. Stanford University library cabinet (doors closed) after refinishing with zero VOW

HAP stain, sanding sealer, and satin topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

ACKNOWLEDGMENTS

This study was conducted under USEPA Contract 68D50128 (Option 2) by AeroVironrnent

Environmental Services, Inc. The author would like to thank the Adhesive Coatings Co. staff for

their technical support, Boden Store Fixtures in Portland, OR, for their participation in the

demonstration, and wood kitchen cabinet coaters for sharing their data and concerns with us.

iv
1.0 INTRODUCTION

Under United States Environmental Protection Agency (USEPA) sponsorship, AeroVironment

Environmental Services, Inc. and Adhesive Coatings Co. (ADCO) are teamed to develop and

demonstrate a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood

furniture/cabinet coating system. This two-part system consists, in general, of an epoxy resin

emulsion and an aqueous solution of a reaction product of certain polyamines and urea-formaldehyde

ether monomers’*2~3. The performance characteristics of this new coating system are excellent in

terms of adhesion, drying times, gloss, hardness, mar resistance, level of solvents, and stain

resistance4”. In Option 2 of this contract, the coating system has been demonstrated by two cabinet

manufacturers. A technology transfer plan was implemented to encourage widespread usage.

A survey of seven kitchen cabinet manufacturers was conducted to gain an understanding of the

effort made by the kitchen cabinet industry to change over to water-based coating systems in general.

Two activities germane to the project but not funded by this EPA contract are described in Appendix

C of the final report. (1) Results of demonstrations by Sierra Performance Coatings at two

recreational vehicle (RV) manufacturers, where the new coating system was evaluated as a rustinhibiting coating for chassis components. (2) ADCO undertook a preliminary analysis of the

potential for incorporating epoxidized vegetable oils into new resins.
2.0 DEMONSTRATION

2.1 Approaches

Many facilities were contacted to find 1 or 2 that would try this no-VOC/no-HAP wood coating.

Information sent to the contacted parties included technical data sheets, material safety data sheets

(MSDS) and published papers. Then, AVES and ADCO staff made follow-up phone calls and/or

visited the facilities who were interested in this system. Wood panels coated with this coating

system were also sent to some of the facilities for their examination and testing. The following is a

list of facilities contacted.

American Classics Cabinetry

7333 Cold Water Canyon, Bld. No. 38

North Hollywood, CA 91605

(8 18) 503-0485/(8 18) 503-0542 (FAX)

Asian Neighborhood Design

1232 Connecticut Street

San Francisco, CA 94017

(415) 648-7070/(415) 648-6303 (FAX)

Barbosa Cabinets

5000 Bailey Ave.

Tracy, CA 95376

(209) 836-2501/(209) 836-0847 (FAX)

Becker Zeyko

1030 Marina Village Pkwy.

Alameda, CA 94501

(510) 865-1616

Boden Store Fixtures

41780 Christy Street

Portland, Oregon 97230

(503) 252-4728/(503) 252-4932 (FAX)

Cal Mode Furniture Mfg. Co.

Culver City, CA

(2 13) 870-482 l/(3 10) 202-0720 (FAX)

Catalina Furniture

La Mirada, CA 90638

(714) 523-7000

Cervitor Kitchens

10775 Lower Azusa

El Monte, CA 91731

(818) 443-0184/(818) 443-0400 (FAX)

Douglas Furniture Corp.

Redondo Beach, CA 90277

(3 10) 692-7668/(3 10) 536-0636 (FAX)

Douglas Furniture of California, Inc.

Redondo Beach, CA 90277

(3 10) 643-7200

Edgewater Cabinets

P.O. Box 127

Boring, OR 97009

(503)663-1341/(503) 663-2523 (FAX)

Eurodesign Cabinets, Inc.

13428 Benson Ave.

Chino, CA 91710

(909) 590-4300

Fairway Painting

1150 University Drive, Suite 109

Menlo Park, CA 94025

(650) 322-4166

G & H Cabinet, Co.

7660 Densmore

Van Nuys, CA 91406

(818) 786-4141

2
Gaylan Industries

2 106 Glassel

Orange, CA

(714) 282-2284

Gem’s Cabinet, Inc.

12201 Magnolia Ave.

Riverside, CA 92503

(909) 371-3530

Houck Industries, Inc.

Tulare, CA 93274

(209) 688-2983

Keller Thomas Woodworks

Redwood City, CA 94063

(415) 369-2468

Kitchen Cabinet Manufacturers Association

1899 Preston White Dr.

Reston, VA 2209 l-4326

(703) 264- 1690

Marge Carson

9056 E. Garvey

Rosemead, CA 9 1770

(818) 571-1111

Monschein Industries, Inc.

6344 Roselle Ave. Suite 101

Riverbank, CA 95367

(209) 869-45 14/(209) 869- 1464 (FAX)

Quality Cabinets

5 15 Big Stone Gap Road

Duncanville, TX 75 115

(972) 298-6101/(972) 709-7753 (FAX)

Royal Cabinets

Pomona, CA 9 1769

(909) 629-8565

Snaidero Intl.

201 W 132nd St.

Los Angeles, CA 90061

(310) 516-8499

South Coast Cabinet

755 Pinefalls Ave.

Walnut, CA 91789

(909) 444-1380

Standard Cabinet Works, Inc

Los Angeles, CA 90086

(213) 749-2111

Texas Cabinet Doors, Inc

4078 Shilling Way

Dallas, TX 75237

(423) 586-7233

Virco Mfg. Group

Torrance, CA 90503

(3 10) 533-0474

W. L. Rubottom Co., Inc.

320 West Lewis Street

Ventura, CA 93001

(805) 648-6943/(805) 648-7856 (FAX)

Walker Wood Products, Inc.

2872 South Santa Fe Ave.

San Marcos, CA 92069-6099

(619) 727-4700/(619) 727-3022 (FAX)

Wambold Furniture

Simi Valley, CA 93065

(805) 526-5200

Western Construction and Engineering

1535 Chestnut Street

Redwood City, CA 94063

(650) 322-4166

Worthem Enterprises, Inc.

Dba Classic Cabinets

4620 Raley Blvd.

3
Sacramento, CA 95838

(9 16) 922-6029/(9 16) 922-2904 (FAX)

Zelco Cabinet Manufacturing

298 West Robles Ave.

Santa Rosa, CA 95407

(707) 584-l 121/(707) 584-5071 (FAX)

2.2 First Demonstration

The first cabinet demonstration was conducted at Boden Store Fixtures, Portland, Oregon, on

September 29, 1997. This plant manufactures wood products including cabinets. The purpose of

the demonstration was to show that this new no-VOC/no-HAP wood coating system could be used

successfully on kitchen cabinets. Product Data Sheets and Material Safety Data Sheets can be found

in Appendix B. The following summarizes the demonstration process.

Date:

Place:

Present:

Products used:

September 29, 1997

Boden Store Fixtures

41780 Christy Street

Portland, OR 97203

Robert McCrillis - U.S. Environmental Protection Agency

Eddy Huang - AeroVironment Environmental Services, Inc.

Gary Effenberger - Boden Store Fixtures

James Shannon, Jr. - Adhesive Coatings Co.

James Birdsall - Adhesive Coatings Co.

New No-VOC/No-HAP Wood Topcoat Gloss (WTC-96-RT4)

New No-VOC/No-HAP Wood Topcoat Satin (WTC-96-ISA)

New No-VOC/No-HAP Wood Sanding Sealer (WSS-96-25)

New No-VOCYNo-HAP Stain Base (WST-96-3)

AVES and ADCO worked with Gary Effenberger of Boden Store Fixtures, Portland, Oregon to set

up a demonstration on September 29, 1997. During the demonstration, Boden and ADCO staff

applied with a rag, the stain base mixed with Boden’s pigmentation to meet their color requirements.

Sanding sealer was then sprayed on the maple “Coffee Story” cabinet custom made for Star Buck

Coffee Stores. This step was performed in the spraying booth. After the sanding sealer was dry

enough to be sanded (in about 15 minutes), the wood surface was lightly sanded. The satin top coat

was then sprayed onto the cabinet. It took about 20 minutes for the top coat to dry. Stain, sanding

sealer, and gloss and satin top coat were also applied to other wood panels including pine, oak, and

mahogany. Boden Store Fixtures staff were quite satisfied with the results. They asked for a gallon

of clear satin top coat so that they could spray it on their current products without having to worry

about matching the color. Boden Store Fixtures staff will try to use existing stains and sealer, then

4
apply the new top coat on their products. This type of stepwise conversion is much easier for the

manufacturer to accept.

2.3 Second Demonstration

There is severe water damage in the Stanford University Main Library Basement due to flooding.

Stanford University contracted Fairway Painting (Menlo Park, California) to restore the damaged

cabinets including repainting and refinishing. AVES and ADCO staff contacted Fairway Painting

and set up the arrangement to use ADCO’s no-VOC/no-HAP wood cabinet coatings in the

refinishing process.

Demonstration of the new no-VOC/no-HAP wood coating system was conducted at Fairway

Painting’s offsite shop (Western Construction and Engineering) at Redwood City, California, on

March 23, 1998. This shop specializes in painting and refinishing wood products ( including

cabinets). The purpose of the demonstration was to show that this new wood coating system could

be used successfully to finish/refinish cabinets. Product Data Sheets and Material Safety Data

Sheets can be found in Appendix B. The following summarizes the demonstration activity.

Date: March 23,1998

Place: Western Construction and Engineering

1535 Chestnut Street

Redwood City, CA 94063

Present: Eddy Huang - AeroVironment Environmental Services, Inc.

Harry Finkle - Fairway Painting

Norm Biron - Fairway Painting

Jim Shannon - Adhesive Coatings Co.

Patrick Terrizzi - Adhesive Coatings Co.

Bill Durgall - Sierra Performance Coatings (licensed by ADCO to market the

new coatings)

Products used: New No-VOCNo-HAP Wood Topcoat Satin (S-8 l-03)

New No-VOC/No-HAP Wood Sanding Sealer (S-91-03)

New No-VOC/No-HAP Stain Base (S-93-03)

During the demonstration, ADCO staff applied the no-VOC stain base mixed with Fairway

Painting’s pigmentation to meet color requirements. The sanding sealer was then sprayed on the

alder cabinet and oak molding pieces. This step was performed in the spraying booth. After the

sanding sealer was dry enough to be sanded (in about 12 minutes), the wood surface was lightly

sanded. A second coat of sanding sealer was then applied on the cabinet surface to improve its

durability. Since the wood surface was tilled with the first layer of sanding sealer, it took about 15

5
minutes for the second layer of sanding sealer to dry. The topcoat was then applied on the cabinet

surfaces. (See Figures 1 and 2.) It took about 20 minutes for the topcoat to dry to touch. Stain,

sanding sealer, and topcoat were also applied to other wood panels including oak molding. Western

Construction and Engineering staff were quite satisfied with the results.

It should be noted that the coatings dried quickly without leaving any milky appearance, in spite of

the fact that it was a cold, rainy day and the demonstration took place in an old, drafty warehouse. In

fact, dry times were not significantly different from those observed under more favorable weather

conditions.

Figure 1. Stanford University library cabinet (doors open) after refinishing with no-VOC/HAP

stain, sanding sealer, and satin top coat. Nonparallel sides caused by camera closeup lens distortion.

6
Figure 2. Stanford University library cabinet (doors closed) after refinishing with no-VOC/HAP

stain, sanding sealer, and satin top coat. Note that nonparallel sides are due to distortion caused by

camera closeup lens.

7
3.0 TECHNOLOGY TRANSFER

The following is a summary of the technology transfer efforts made by AVES and ADCO staff for

this contract.

An article authored by AVES staff (Eddy W. Huang , Ruiling Guan) and EPA Project Officer

(Robert C. McCrillis) and presented at an AWMA Specialty Conference6 was also published in

Coatings World jouma17.

AVES Staff, Eddy Huang was invited to present “No-VOC Coating Technologies” at the

“Pollution Prevention 2000 Conference and Exhibition” held in Southern California Gas

Company Energy Resources Center, Downey, CA, August 7, 1997.

The team prepared and presented new information on no-VOC/no-HAP wood furniture/cabinet

coatings at the “New Technologies for Clean Air” symposium from September 29, 1997 through

October 1, 1997 in U.C. Irvine, California. This symposium is co-sponsored by the California

Air Resources Board (CARB), the California Air Pollution Control Officers Association, the

U.S. Environmental Protection Agency, and the California Environmental Dialogue. This was a

good opportunity for community outreach and technology transfer.

AVES and ADCO worked with the EPA Project Officer, Robert C. McCrillis, to present new

information on no-VOC/no-HAP wood furniture/cabinet coatings at the “EPA Pollution

Prevention/Green Manufacturing Conference” held November 17- 19, 1997 in Atlanta, GA. In

addition to the new coating’s performance characteristics, cost analysis and environmental

impact analysis data were also included in the presentation’. ADCO staff set up an exhibition

booth and displayed wood panels coated with the new stain, sealer, an-d topcoat. Coating product

data sheets and material safety data sheets were displayed on the table and distributed in the

exhibition. This was the second occasion for community outreach and technology transfer.

ADCO finalized a licensing agreement with Sierra Performance Coatings, Inc. to manufacture

ADCO’s no-VOC coatings; the complete no-VOC/no-HAP wood furniture coating system is

now commercially available.

Eddy Huang was invited as a conference speaker to present new information on no-VOC/noHAP wood furniture/cabinet coatings at the “Emerging Low-Emission Technologies and

Innovative Approaches to Air Pollution Control” symposium on December 5, 1997 at the South

Coast Air Quality Management District. In addition to the new coating’s performance

characteristics, cost analysis and environmental impact analysis data were also included in the

presentation. This was the third event of the technology transfer efforts.

8
4.0 MANUFACTURER FOLLOW-UP PROGRAM

As noted previously, AVES staff contacted many cabinets manufacturers and solicited their

participation in production scale demonstrations. In addition, a survey of seven kitchen cabinet

manufacturers using a variety of water-based coatings (but not the new coating) was conducted to

better understand the problems they faced when switching from solvent-based coatings. The

following is a summary of the survey results. Appendix A contains a brief description of the current

coatings used by the seven companies.

1. Question: What kind of wood is coated at this facility?

Answers:

hpe 1 Oak 1 Walnut I Maple I

ISolid 1 61 11 41

IVeneer I 61 11 31

IPlywood 1

2. Question: Is the final product finish satisfactory? Any comments about no-/low-VOC coatings?

Answers:

0 We are able to overcome the difficulties when converting to water-based coatings

0 Happy with the appearance

0 The current water-base coating we use dries as fast as the solvent-based coating

0 More time is needed for drying and it takes a lot of storage space

0 Milking problem

0 Difficulties in achieving film thickness

0 Since the current (solvent-based) coating system meets the regulations, we don’t want to

switch to water-based coating

0 Water-base coatings don’t pass UV stability test

0 Edge soak is an issue when we test water-based coatings

0 Can’t compete with the quality achieved with the solvent-based coatings

0 Positive response in general

3. Question: Are additional steps in your manufacturing process necessary in order to use the no-

/low-VOC coatings you’ve tried?

Answers:

Yes. (5)

4. Question: Will additional employees be required because of the implementation of no-/low-VOC

coatings?

Answers:

No. (5)

9
5. Question: What type of application equipment are you using?

Answers:

HVLP/Air Assisted Airless W)

6. Question: Do you experience any problems cleaning the equipment?

Answers:

Yes/No. As long as you handle it properly. (z/3)

7. Question: Does your coating need to be force dried? Do you have ovens or drying equipment?

Answers:

Yes/No (4V3)

8. Question: Do you have a conveyor?

Answers:

Yes/No (14

a 3 Gas Ovens and 1 IR.

10
5.0 CONCLUSIONS AND RECOMMENDATIONS

1.

2.

3.

4.

5.

6.

7.

There are water-based coatings available on the market9. Some manufacturers are able to

overcome the difficulties associated with water-based coating (such as grain raising, color

matching and edge soak) when converting from solvent based coatings.

The performance characteristics of this new wood coating are excellent. This water-based

coating system drys as fast as many of the solvent-based coating systems and faster than most

combination water/solvent coatings.

When using this new no-VOC, no-HAP water-based coating, additional finishing steps may

required. However, most facility owners do not expect to add additional employees.

The keys to successful conversion to new water-based coatings are staff training and technical

support from the coating manufacturers. Personnel may need retraining on spraying techniques

for water-based wood coating applicationslo.

As a first step, manufacturers will try to use existing stains and sealer, then apply the no-VOC

top coat on their products. This type of stepwise conversion is much easier for the manufacturer

to accept.

Demonstrations at two cabinet manufacturing facilities showed that the new coating system was

adaptable to this type of application. Dry times of 15 - 20 minutes for each coat were typical

without use of auxiliary heating, even in humid atmospheric conditions.

Independent demonstrations by the coating vendor at two large RV manufacturers showed that

the new coating provided excellent corrosion protection on chassis components. The current

organic solvent-based coating failed the ASTM salt spray test after 192 hours, whereas the new

coating continued on for 1700 hours before showing any sign of failure.

11
6.0 REFERENCES

1. U.S. Patent No. 4812,493, “Dual cure rate water-based coating composition,” Adhesive

Coatings Co., San Mateo, CA, March 14, 1989.

2. U.S. Patent No. 4,906,726, “Water-based coating compositions containing hydroxides and

oxides of calcium and strontium and barium,” Adhesive Coatings Co., San Mateo, CA,

March 6, 1990.

3. Huang, E.W., L. Watkins, and R.C. McCrillis, “Formulating Ultra-Low VOC Wood

Furniture Coatings,” Modem Paints and Coatings, Vol. 83, No. 12, November 1993, pg. 41-

43.

4. Huang, E.W., and R.C. McCrillis, “Developing a No-VOC Wood Topcoat,” Modem Paints

and Coatings, Vol. 85, No. 7, July 1995, pg. 38-41.

5. Huang, E.W., Develonment of a No-VOC/No-HAP Wood Furniture Coatings System, EPA600/R-98-019 (NTIS PB98-127301), U.S. Environmental Protection Agency, National Risk

Management Research Laboratory, Research Triangle Park, NC, February 1998.

6. Huang, E.W., R. Guan, and R.C. McCrillis, “Demonstration of No-VOC/No-HAP Wood

Furniture Coating System,” in Proceedings: Emerging Solutions to VOC and Air Toxics

Control, Air & Waste Management Association, February 25-27, 1997, San Diego, CA,

7. Huang, E.W., Ruiling Guan, and R.C. McCrillis, “Demonstration of a No-VOC/No-HAP

Wood Furniture Coating System,” published in: Coatings World, Vol. 2, No. 6,

November/December, 1997, pg. 21-26.

8. McCrillis, R.C., E.W. Huang, and R. Guan, “A No-VOC/No-HAP Wood Furniture Coating

System,” presented at EPA Pollution Prevention/Green Manufacturing Conference, Atlanta,

GA, November 17-19,1997.

9. Huang, E.W. and R.C. McCrillis, “Demonstration of No-VOC Wood Topcoat,” presented at

the Low- and No-VOC Coating Technologies 2”d Biennial International Conference, Durham,

NC, March 13-15, 1995.

10. Huang, E.W. and R.C. McCrillis, “Source Reduction of VOC and Hazardous Organic

Emissions from Wood Furniture Coatings,” in Proceedings: The Emission Inventorv: Kev to

Planning. Permits, Comnliance and Renorting, New Orleans, LA, Sept. 4-6, 1996.

12
APPENDIX A

MANUFACTURER INTERVIEW NOTES (BY TELEPHONE)

Facility A: A Kitchen Cabinet Manufacturer

Comments:

This is a big kitchen cabinet manufacture in southern California. They are looking for a water-based

coating with very good UV stability. In addition, for 2-component coatings, they are looking for a

special feature; they want to be able to deactivate the mix to prolong the coating shelf life (for

example, overnight). Usually, after part A and part B mixed, the remainder of the coating will be

wasted if not totally consumed. Therefore, an agent to deactivate the mixed coating will be very

useful.

Facility B: A Kitchen Cabinet Manufacturer

Comments:

This facility is using solvent-based coatings. Because the VOC content of the coatings complies

with the current rule limits, they do not intend to switch to water-based coating now. However,

they foresee the switching several years down the road. They have tested some water-based

coatings. Several issues are of concern:

a Drying time

0 Grain raising

0 Proper cleaning of the gun

Facility C: A Kitchen Cabinet Manufacturer

Comments:

It takes a lot of money to convert to low-VOC coatings. New procedures need to be learned.

Because of longer drying time, large space is needed to store the products. The following properties

need to be improved:

0 Grain raising

0 Milking

0 Film thickness

There are lots of new products on the market; therefore, it takes a lot of effort to test new coating

products.

Al
Facility D: A Kitchen Cabinet Manufacturer

Comments:

This facility is located in San Francisco. Currently they use solvent-based coatings. Solvent-based

coatings dry very fast. No heating required.

Facility E: A Kitchen Cabinet Manufacturer

Comments:

This company manufactures high-end kitchen cabinets. They have converted to water-based

coatings. They are able to overcome the problems associated with water-based coatings. Grain

raising, color matching and edge soak are the concerns when selecting new coatings.

Facility F: A Kitchen Cabinet Manufacturer

Comments:

This company use both solvent-base and water-base coatings. They like the appearance that waterbase coatings deliver; they dry fast too. Overall cost of using water-base coating is higher than using

solvent-base coating. They are interested in exploring new water-base coatings.

Facility G: A Kitchen Cabinet Manufacturer

Comments:

Water-base coating have very good mar resistance. The concerns of using water-base coatings are:

0 Film thickness

0 Making repairs

0 Matching color

0 Milking

In their experience application procedures are more complex for water-base coatings. A step-wise

change over to a new coating system is the preferred approach. He thinks that appearance of waterbase coating can’t compete with solvent-base coating.

A2
APPENDIX B

COATING TECHNICAL DATA SHEETS AND MATERIAL SAFETY DATA SHEETS

Bl
APPENDIX B.l

Sierra

Performance Coatings

TOP COAT

Product Data Sheet

Clear Wood Top Coat Product Code: WTC-97-2

This two component, high performance, water based wood top coat is a hard, durable, chemical and stain resistant interior wood coating that contains

no organic solvents. This wood top coat is designed to be used with the companion Zero VOC Stain and Sanding Sealer for furniture, cabinets and

other wood applications

Very low odor - no solvent smell

Non-flammable

Chemical and stain resistant

Bright, clear finish

Easily washed and cleaned

Surpasses alVOC air quality regulations

SPECIFICATIONS

j Color: Clear

1 Finish: Gloss & Satin

1 Pot Life: 6 hours @ 70°F

1Clean Up: Use warm, soapy water

Density: 8.85 #/gal (Mixed System)

Volume Solids: 35%

1 Weight Solids: 39%

~Theor. Coverage @ 2 mils: 270 sq.ft/gal

Flash Point: >350 “F

Shelf Life: > I year

Dry Time; @ 77 “T & 50% RK 3 mil film

To Touch: 30 minutes

To Recoat: 1 hour

Full cure: 1 week

VOC: Coating 0 #/gal, 0 grams per liter

Material 0 #/gal, 0 grams per liter

~ Viscosity (Part A & B mixed) @ 25 “C

#3 spindle @ 12 ‘pm: 500 cps

/Usage: PartA PartB

/By Volume 1.0 1.0

/By Weight 1.0 1.0

Pencil Hardness: 2H I

Intercoat Adhesion: Excellent

KCMA Al61.1 1990 Testing

Detergent & Water Resistance: Pass

Edge Test: Pass

Hot Cold Check: Pass

Stain Resistance: 24 hour exposure

Coffee

Grape Juice

Lemon Juice

Orange Juice

Olive Oil

100 Proof Alcohol

Detergent

Mustard (I hour)

Pint Sol

Fantastic

Simple Green

Bleach

Ketchup

Distilled water

Sierra Performance Coatings, Inc.

2755 Campus Drive, San Mateo, CA 94403 Phone: 415-378-8659 Fax 415-574-3412

For technical assistance, please call: 510-451-2326

B1.l
MATERIAL SAFETY DATA SHEET

PRODUCT: Wood Top Coat Part A (WTC-97-2)

iPART 1 - GENERAL INFORMATION

Manufacturer:

Sierra Performance Coatings, Inc.

2755 Campus Drive

San Mateo, CA 94403

(650)378-8659

Emergency Numbers: l-800-424-9300 (Chemtrec)

NPCA HMIS Rating

Health:

Flammability:

Reactivity:

Personal Protection:

1

0

0

D

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 6Date: 1 O/l O/97

Latex Paint

Water Based Epoxy Paint

Water Based Paint, n.o.s.

Not Regulated

I

1 PART 2 - Ingredients

Ingredient Name CAS # Ohweight OSHA(pel~ ACGIH(tIv)

RESILEXTM Epoxy Polymer 025085-99-s 52% N/A N/A

PART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C

VOC excluding water: 0 grams/liter and 0 #/gal pH: 6.5 -7.5

Volatile portion: 45 % wt Freezing Point: 0 “C

Specific Gravity: 1.09 @2O”C Viscosity: 6OO.cps

Solubility in water: Dilutable Vapor Pressure: Negligible

Appearance and Odor: Milky White Liquid / mild odor

Conditions and materials to avoid: High temperatures, oxidizing conditions.

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released

upon decomposition.

~ PART 4 - FIRE AND EXPLOSION

Flash Point: > 250°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower: N/DA Upper: N/DA

Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special tire-fighting procedures: Do not enter fire area without special protection. Fight fire from safe

B1.2
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture

closed containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for

cooling. Notify authorities if liquid enters sewer or public waters.

tPART 5 - EMERGENCY AND FIRST AID

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.

Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergency Medical Treatment: Treat symptomatically.

~ PART 6 - EFFECTS OF EXPOSURE

Routes of exposure:

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absorption: Potential route. Although no data was found for this product, the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some -

individuals after repeated skin contact.

Ingestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated by exposure: No additional medical information found.

E-~--- PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES .

Respiratory Protection: If this material is handled under mist forming conditions, use NIOSHMSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use.

Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation

is recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or

using the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower

B1.3
after work using plenty of soap and water.

I-PART 8 - REACTIVITY DATA

Stability: Stable

Incompatibility: Strong bases and acids.

Hazardous polymerization: Will not occur.

Hazardous decomposition: Will not occur.

~ PART 9 - SPILL OR LEAK PROCEDURES

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with

federal, state, and local regulations.

LPART 10 - STORAGE AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated

material.

PART 11 - REGULATORY INFORMATION

TRANSPORTATION

Not Regulated

:P.ART 12 - LABEL INFORMATION

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant.

May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.

Wash thoroughly after handling.

Do not swallow. Prevent contact with food, chewing or smoking materials. .

FIRST AID

EYES: Immediately flush with plenty of clean water

INHALATION: Remove to fresh air if effects occur. Consult a physician.

SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.

INGESTION: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of

physician in response to reaction of the patient.

Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The

information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,

express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our

control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,

damage, or expense allsing out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared

and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

B1.4
This MSDS has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).

C:\SierraMSDS\SPCMEA.msd.doc

B1.5
MATERIAL SAFETY DATA SHEET

PRODUCT: WOOD TOP COAT PART B (WTC-97-2)

.

PART 1 - GENERAL INFORMATION

Manufacturer: .

Adhesive Coatings Co. .

2755 Campus Drive

San Mateo, CA 94403

(415) 571-7947

NPCA HMIS Rating

Health: 1

Flammability: 0

Reactivity: 0

Personal Protection: D

Emergency Numbers:, l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class

Revision: 1 Date: 6/18/96

Polyamine

Polyamine curing agent

Paint related materials, n.o.s.

:Not regulated

1 PART 2 - ingredients

Ingredient Name

Tetraethyienepentbmine (polyamine)

#CAS

112-57-2

Ohweight

<l%

OSHA(pe1)

N/A

ACGIH(tIv)

N/A

/PART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C

VOC excluding water: 0 grams/fiter and 0 #/gal pH: 11.5

Volatile portion: 28.5 % wt Freezing Point: 0°C

Specific Gravity: 1.8 @2O”C Viscosity: 900 f 50 cps

Solubility in water: Dilutable Vapor Pressure: Negligible

Appearance and Odor: Amber milky liquid / slight ammonia odor

Conditions and materials to avoid: High temperatures, oxidizing conditions. ’

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released

upon decomposition.

PART 4 - FIRE AND EXPLOSION 1

Flash Point: > 250°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower: N/DA Upper: N/DA

Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressure, rupture

B1.6
closed containers spreading fire and increase the risk of bums and injuries. Use-water spray/fog for

cooling. Notify authorities if liquid enters sewer or public waters.

PART 5 - EMERGENCY AND FIRST AID

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eye Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.

Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (11 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergency Medical Treatment: Treat symptomatically.

IPART 6 - EFFECTS OF EXPOSURE

Routes of exposure:

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absorption: Potential route. Although no data was found for this product, the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some

individuals after repeated skin contact.

Ingestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated by exposure: No additional medical information found.

PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES ~---l

Resniratorv Protection: If this material is handled under mist forming condition’s, use NIOSH/MSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use.

Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation

is recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or

using the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower

after work using plenty of soap and water.

B1.7
APPENDIX B.2

SANDING SEALER

MATERIAL SAFETY DATA SHEET

PRODUCT: Wood Sanding Sealer, Part 1 (S91-03)

IPART 1 - GENERAL INFORMATION I

Manufacturer:

Sierra Performance Coatings, Inc.

330 Primrose Road #502

Burlingame, CA 940 10

(650) 548-5 188

NPCA HMIS Rating

Health: 1

Flammability: 0

Reactivity: 0

Personal Protection: DI

Emergency Numbers: l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 6 Date: lo/lo/97

Latex Paint

Water Based Epoxy Paint

Water Based Paint, n.o.s.

Not Regulated

PART 2 - Ingredients

Inpredient Name CAS # Ohweight OSHA(ne1) ACGIH(tlv)

RESILEXTM Epoxy Polymer 025085-99-8 52% N/A N/A

IPART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C

VOC excluding water: 0 grams/liter and 0 #/gal pH: 6.5 - 7.5

Volatile portion: 45 % wt Freezing Point: 0°C

Specific Gravity: 1.09 @2O”C Viscosity: 600 +/- 200 cps

Solubility in water: Dilutable Vapor Pressure:Negligible

Appearance and Odor: Milky White Liquid / mild odor

Conditions and materials to avoid: High temperatures, oxidizing conditions.

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon

decomposition.

IPART 4 - FIRE AND EXPLOSION I

B2.1
Flash Point: > 250°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower: N/DA Upper: N/DA

Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special fire-fighting procedures: Do not enter fire area without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed

containers spreading fire and increase the risk of bums and injuries. Use water spray/fog for cooling.

Notify authorities if liquid enters sewer or public waters.

IPART 5 - EMERGENCY AND FIRST AID

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.

Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergency Medical Treatment: Treat symptomatically.

PART 6 - EFFECTS OF EXPOSURE

Routes of exposure:

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absorntion: Potential route. Although no data was found for this product, the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some

individuals after repeated skin contact.

Inaestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated by exposure: No additional medical information found.

PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES .

Respiratory Protection: If this material is handled under mist forming conditions, use NIOSWMSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

B2.2
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use. ’

Engineering; Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation

is recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using

the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work

using plenty of soap and water.

IPART 8 - REACTIVITY DATA I

Stabilitv: Stable

Incomnatibilitv: Strong bases and acids.

Hazardous polymerization: Will not occur.

Hazardous decomposition: Will not occur.

IPART 9 - SPILL OR LEAK PROCEDURES I

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with

federal, state, and local regulations.

PART 10 - STORAGE AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated

material.

PART 1 1 - REGULATORY INFORMATION

TRANSPORTATION

Not Regulated

.

IPART 12 - LABEL INFORMATION

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant.

May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.

Wash thoroughly after handling. Do not swallow. Prevent contact with food, chewing or smoking

materials.

B2.3
FIRST AID

EYES: Immediately flush with plenty of clean water

INHALATION: Remove to fresh air if effects occur. Consult a physician.

SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.

INGESTION: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of

physician in response to reaction of the patient.

Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information

in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or

implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may

be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense

arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only

for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been

prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).

C:\SierraMSDS\SPCMEA.msd.doc

B2.4
MATERIAL SAFETY DATA SHEET

PRODUCT: WOOD SANDING SEALER - PART 2 (S91-03)

IPART 1 - GENERAL INFORMATION I

Manufacturer: NPCA HMIS Rating

Sierra Performance Coatings, Inc. Health: 1

330 Primrose Road #502 Flammability: 0

Burlingame, CA 940 10 Reactivity: 0

(650) 548-5 188 Personal Protection: D

Emergency Numbers: l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 1 Date: 6/18/96

Polyamine /latex blend

Polyamine curing agent

Paint related materials, n.o.s.

Not regulated

PART 2 - Ingredients

Ingredient Name CAS #

RESILINKTM B-2003 (polyamine) 170904-70-8

Ohweight

<1.2%

OSHA(pe1)

Nl A

ACGIH(tlv)

N/A

IPART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point:. 100°C

VOC excluding water: 0 grams/liter and 0 #/gal pH: 9.5 - 10.0

Volatile portion: 70 % wt Freezing Point: 0°C

Specific Gravity: 1.03 @2O”C Viscosity: 900 f 150 cps

Solubility in water: Dilutable Vapor Pressure: Negligible

Appearance and Odor: Amber milky liquid / slight ammonia odor

Conditions and materials to avoid: High temperatures, oxidizing conditions.

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon

decomposition.

PART 4 - FIRE AND EXPLOSION

Flash Point: > 250°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower: N/DA Upper: N/DA

B2.5
Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed

containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for cooling.

Notify authorities if liquid enters sewer or public waters.

.

IPART 5 - EMERGENCY AND FIRST AID I

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.

Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergencv Medical Treatment: Treat symptomatically.

PART 6 - EFFECTS OF EXPOSURE

Routes of exposure: .

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absomtion: Potential route. Although no data was found for this product, the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation, May cause an allergic skin reaction in some

individuals after repeated skin contact.

Ingestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated bv exposure: No additional medical information found.

PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES I

Respiratorv Protection: If this material is handled under mist forming conditions, use NIOSHMSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use.

Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation

B2.6
is recommended.

Other Hvaienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using

the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work

using plenty of soap and water.

IPART 8 - REACTIVITY DATA

Stabilitv: Stable

Incompatibilitv: Strong bases and acids.

Hazardous polvmerization: Will not occur.

Hazardous decomposition: Will not occur.

IPART 9 - SPILL OR LEAK PROCEDURES

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with

federal, state, and local regulations.

IPART 10 - srrorwcz AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated

material.

PART 1 1 - REGULATORY INFORMATION

TRANSPORTATION

Not regulated

California Proposition 65: NA

IPART 12 - LABEL INFORMATION

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant.

May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.

Wash thoroughly after handling. Do not swallow. Prevent contact with food, chewing or smoking

materials.

FIRST AID

EYES: Immediately flush with plenty of clean water

INHALATION: Remove to fresh air if effects occur. Consult a physician.

SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.

B2.7
INGESTION: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of

physician in response to reaction of the patient.

Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information

in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or

implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may

be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense

arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only

for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been

prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).

C:\adco\msds\wss9616b.msd

B2.8
Sierra

Performance Coatings

Wood Sanding Sealer

Product Data Sheet

Product Code: WSS-96-25

This two component epoxy/acrylic, clear sanding sealer is a fast drying sealer that provides a sandable surface for wood

finishing that contains no organic solvents. This sanding sealer is designed to be used with the companion Zero VOC Stain

and Top Coat.

Very low odor - no solvent smell

Non-flammable

Sandable

Fast Drying

Surpasses flVOC air quality regulations

SPECIFICATIONS

(

1

I

(

1

7

1

I

1

,

I

1

I

1

1

30lor: Clear

‘inish: Matte

?ot Life: 6 hours @ 70°F

?lean Up: Use warm, soarp water

Density: 8.7 #/gal (Mixed System)

Volume Solids: 27. 1 %

Weight Solids: 30.1%

Theor. Coverage @ I mils: 435 sq.ft/gal

Flash Point: ~3 50 T

Shelf Life: > 1 year

Dry Time: @ 77 “F & 50% RK I mil film

To Touch: 15 minutes

To Re-oat: 20 minutes

VOC: Coating 0 #/gal, 0 grams per liter

Material O#/gal, 0 grams per liter

Viscosity (Part A & B mixed) @ 25 “C

Y3 spindle @ 12 rpm: 500 cps

Usage: PartA PartB

By Volume 1.0 4.0

By Weight 1.0 4.0

When used with ADCO Wood Top Coat

Intercoat Adhesion: Excellent

KCMA A161.1 1990 Testing

Detergent & Water Resistance: Pass

Edge Test: Pass

Hot Cold Check: Pass .

Stain Resistance: 24 hour exposure

Coffee

Grape Juice

Lemon Juice

Orange Juice

Olive Oil

100 proof alcohol

Detergent

Mustard (I hour)

Pine Sol

Fantastic

Simple Green

Bleach

Ketchup

Distilled water

Sierra Performance Coatings, Inc.

2755 Campus Drive, San Mateo, CA 94403 Phone: 415-378-8659 Fax: 415-574-3412

For technical assistance, please call: 510-451-2326

B2.9
MATERIAL SAFETY DATA SHEET

PRODUCT: Wood Sanding Sealer Part A (WSS-96-25)

1 PART I - GENERAL INFORMATION I

Manufacturer: NPCA HMIS Rating

Sierra Performance Coatings, Inc. Health: 1

2755 Campus Drive Flammability: 0

San Mateo, CA 94403 Reactivity: 0

(650)378-8659 Personal Protection: D

Emergency Numbers: l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 6 Date: 10/l O/97

Latex Paint

Water Based Epoxy Paint

Water Based Paint, n.o.s.

Not Regulated

PART 2 - Ingredients .

Inpredient Name

RESILEXTm Epoxy Polymer

CAS # Ohweight OSHA(i)el) ACGIH(tIv)

025085-99-s 52% N/A N/A

PART 3 - PHYSICAL AND CHEMICAL DATA 1

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C

VOC excluding water: 0 grams/liter and 0 #/gal pH: 6.5 - 7.5

Volatile portion: 45 % wt Freezing Point: 0°C

Specific Gravity: 1.09 @2O”C Viscosity: 600 cps

Solubility in water: Dilutable Vapor Pressure: Negligible

Appearance and Odor: Milky White Liquid / mild odor

Conditions and materials to avoid: High temperatures, oxidizing conditions.

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon

decomposition.

PART 4 - FIRE AND EXPLOSION

Flash Point: > 250°C (Method: IS0 3679)

Autoignition temperature: N/DA

B2.10
Flammable limits (%volume in air) Lower: N/DA Upper: N/DA

Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special fire-fighting procedures: DC not enter fire irea without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressire, rupture closed

containers spreading fire and increase the risk of burns and injuries. Use water spray 1 fog for cooling.

Notify authorities if liquid enters sewer or public waters.

PART 5 - EMERGENCY AND FIRST AID

Inhalation: If Overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly-with mild soap and water.

Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergencv Medical Treatment: Treat symptomatically.

PART 6 - EFFECTS OF EXPOSURE

Routes of exuosure:

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absorption: Potential route. Although no data was found for this product. the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause -.n allergic skin reaction in some

individuals after repeated skin contact.

Ingestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated by exposure: No additional medical information found.

PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES 1

Respiratory Protection: If this material is handled under mist forming conditions, use NIOSI-IMSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

B2.11
protection should be worn. This equipment should be cleaned after each use.

Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation is

recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using

the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work

using plenty of soap and water.

1 PART 8 - REACTIVITY DATA

Stabilitv: Stable

Incomnatibilitv: Strong bases and acids.

Hazardous polymerization: Will not occur.

Hazardous decomposition: Will not occur.

PART 9 - SPILL OR -LEAK PROCEDURES

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with

federal, state, and local regulations.

PART 10 - STORAGE AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated

material.

1 PART 1 1 - REGULATORY INFORMATION . 1

TRANSPORTATION

Not Regulated

PART 12 - LABEL INFORMATION

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant.

May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.

Wash thoroughly after handling.

Do not swallow. Prevent contact with food, chewing or smoking materials.

FIRST AID

B2.12
EYES: Immediately flush with plenty of clean water

INHALATION: Remove to fresh air if effects occur. Consult a physician.

SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.

INGESTION: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of physician

in response to reaction of the

patient.

Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself The information

in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or

implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may

be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense

arising out ofor in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only

for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been

prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200). C:\SierraMSDS\SPCMEA.msd.doc

B2.13
MATERIAL, SAFETY DATA SHEET

PRODUCT: WOOD SANDING SEALER - PART B (WSS-96-25)

1 PART 1 - GENERAL INFORMATION

Manufacturer: NPCA HMIS Rating

Adhesive Coatings Co. Health: 1

2755 Campus Drive Flammability: 0

San Mateo, CA 94403 Reactivity: 1

(415) 571-7947 Personal Protection: D

Emergency Numbers: l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 1 Date: 6/18/96

Polyamine /LATEX BLEND *

Polyamine curing agent

Paint related materials, n.o.s.

Not regulated

PART 2 - Ingredients

Ingredient Name CAS #

RESILINK- B-2003 (polyamine) 170904-70-8

Ohweight

<1.2%

OSHA(pe1)

N/A

ACGIH(tlv)

N/A

1 PART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C

VOC excluding water: 0 grams/liter and 0 #/gal pH: 9.5 - 10.0

Volatile portion: 70 % wt Freezing Point 0°C

Specific Gravity: 1.03 @2O”C Viscosity: 900 f 50 cps

Solubility in water: Dilutable Vapor Pressure: Negligible

Appearance and Odor: Amber milky liquid / slight ammonia odor

Conditions and materials to avoid: High temperatures, oxidizing conditions.

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon

decomposition.

1 PART 4 - FIRE AND EXPLOSION I

Flash Point: > 250°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower N/DA Upper: N/DA

Fire and explosion hazards: Not-flammable

B2.14
Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special tirefighting procedures: Do not enter fire area without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed

containers spreading tire and increase the risk of burns and injuries. Use water spray/fog for cooling.

Notify authorities if liquid enters sewer or public waters.

PART 5 - EMERGENCY AND FIRST AID

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eye Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.

Flush with lukewarm water for

15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (11 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergency Medical Treatment: Treat symptomatically.

PART 6 - EFFECTS OF EXPOSURE

Routes of exnosure:

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to Its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absorption: Potential route. Although no data was found for this product, the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some

;ndividuals after repeated skin contact.

Ingestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated by exposure: No additional medical information found.

PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES

Resuiratorv Protection: If this material is handled under mist forming conditions, use NIOSI-IMSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use.

B2.15
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation is

recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using

the toilet facilities. Promptly

remove soiled clothing and wash thoroughly before reuse. Shower after work using plenty of soap and

water.

PART 8 - REACTIVITY DATA I

Stabilitv: Stable

Incomnatibilitv- Strong bases and acids.

Hazardous Polymerization: Will not occur.

Hazardous decomposition: Will not occur.

PART 9 - SPILL OR LEAK PROCEDURES

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting.

Flush contaminated area with water. Dispose in accordance with federal, state, and local regulations.

I PART 10 - STORAGE AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice caution and

personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated material.

I PART 1 1 - REGULATORY INFORMATION

TRANSPORTATION

Not regulated

California Proposition 65: NA

I PART 12 - LABEL INFORMATION

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant.

May, cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.

Wash thoroughly after handling.

Do not swallow. Prevent contact with food, chewing or smoking materials.

I FIRST AID I

B2.16
EYES: Immediately flush with plenty of clean water

INHALATION: Remove to fresh air if effects occur. Consult a physician. I

SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.

INGESTION: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of physician

in response to reaction of the patient.

Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information

in this IVISDS was obtained horn sources which we believe are reliable. However, the information is provided without any warranty, express or

implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may

be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense

arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only

for this product. If the product is used as a component in another product, this IVISDS information may not be applicable. This MSDS has been

prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200). C:\adco\msds\wss9616b,msd

B2.17
Sierra

Performance Coatings

STAIN BASE

Product Data Sheet

Wood Stain Base Product Code: WST-96-3

This fast drying stain base can be colored with a variety of water dispersed pigments, dyes and tints into

a wide variety of hues, colors and stains and contains ag organic solvents. This stain base is designed to

be used with the companion Zero VOC Sanding Scaler and Top Coat.

Very low odor - no solvent smell

Non-flammable

Fast drying

Improves corrosion resistance

Surpasses alJVOC air quality regulations

SPECIFICATIONS

Color: Clear

Finish: Matte

Pot Life: 6 hours

VOC: Coating 0 #gal, 0 grams per liter

Material 0 #/gal, 0 gram per liter

Clean Up: Warm, soapy water

Density: 8.6 #/gal (Mixed system)

Volume Solids: 17.8%

Weight Solids: 19.8%

Theor. Coverage @ 1 mils: 285 sq.ft/gal

Flash Point: > 350 “F

Shelf Life: > I year

Dry Time: @ 77°F & 50% RH, 1 mil film

To Touch: 15 minutes

To Recoat: 15 minutes

Viscosity (Part A & B mixed) @ 25°C

#3 spindle @ 12 rpm: 500 cps

Sierra Performance Coatings, Inc.

2755 Campus Drive, San Mateo, CA 94403 Phone: 415-378-8659 Fax: 415-574-3412

For technical assistance, please call: 5 lo-45 l-2326

B3.1
MATERIAL SAFETY DATA SHEET

PRODUCT: WOOD STAIN BASE (WST-96-3)

IPART 1 - GENERAL INFORMATION I

Manufacturer: NPCA HMIS Rating

Adhesive Coatings Co. Health: 1

2755 Campus Drive Flammability: 0

San Mateo, CA 94403 Reactivity: 0

(415) 571-7947 Personal Protection: D

Emergency Numbers: l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 1 Date: 6/18/96

Latex Paint

Water Based Stain

Water Based Paint, n.o.s.

Not Regulated

PART 2 - Ingredients

Inpredient Name

Acrylic Polymer

CAS #

N/A

%weight

15%

OSHA(pe1)

N/A

ACGIH(tlv)

N/A

FART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal

VOC excluding water: 0 grams/liter and 0 #/gal

Boiling Point: 100°C

pH: 6.0 - 7.0

Volatile portion: 80.1 % wt

Freezing Point: 0°C

Specific Gravity: 1.03 @2O”C

Viscosity: 500:* 50 cps

Solubility in water: Slight

Vapor Pressure: Negligible

Appearance and Odor: Milky white liquid/mild odor Conditions and materials to avoid: High

temperatures, oxidizing conditions. Hazardous decomposition products: Acrid smoke, fumes, carbon

monoxide/dioxide may be released upon decomposition.

Stability: Stable

B3.2
IPART 4 - FIRI~ AND EXPLOSION I

Flash Point: > 212°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower: N/DA Upper: NIDA

Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical,CO,,Water spray, Foam, Water fog.

Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressure, rupture

closed containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for

cooling. NotifL authorities if liquid enters sewer or public waters.

IPART 5 - EMERGENCY AND FIRST AID I

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give

oxygen or artificial respiration as needed. Obtain emergency medical attention,

prompt action is essential.

Eve Contact: In case of eye contact, immediately flush eyes with clean water for

20 - 30 minutes. Retract eyelids often. Obtain emergency medical attention if pain,

blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly

with mild soap and water. Flush with lukewarm water for 15 minutes. If sticky, use

waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is

completely conscious and alert. Do not induce vomiting, risk of damage to lungs

exceeds poisoning risk. Obtain emergency medical attention.

Emergency Medical Treatment: Treat symptomatically.

IPART 6 - EFFECTS 0~ EXPOSURE

Routes of exnosure:

Inhalation: This material is not expected to present an inhalation hazard at

standard conditions due to its low volatility. However, overexposure to

mists/aerosols may cause respiratory tract irritation such as coughing, shortness of

breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include

tearing, blinking, redness and swelling.

Skin absorption: Potential route. Although no data was found for this product, the

potential for skin absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause an allergic

skin reaction in some individuals after repeated skin contact.

Inpestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated bv exnosure: No additional medical information’

found.

B3.3
IPART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES I

Respirator-v Protection: If this material is handled under mist forming conditions, use NIOSIIMSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use.

Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation

is recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or

using the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower

after work using plenty of soap and water.

IPART 8 - REACTIVITY DATA

Stabilitv: Stable

Incomnatibilitv: Strong bases and acids.

Hazardous polymerization: Will not occur.

Hazardous decomposition: Will not occur.

IPART 9 - SPILL OR LEAK PROCEDURES I

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with

federal, state, and local regulations.

PART 10 - STORAGE AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice caution and

personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated material.

IPART 1 1 - REGULATORY INFORMATION I

None required for this product.

PART 12 - LABEL INFORMATION I

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant. May cause allergic

reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist. Wash thoroughly

B3.4
after handling. Do not swallow. Prevent contact with food, chewing or smoking materials.

1 FIRST AID

m: Immediately flush with plenty of clean water

Inhalation: Remove to fresh air if effects occur. Consult a physician.

Skin contact: Wash thoroughly with mild soap and flowing water or shower.

Ingestion: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of

physician in response to reaction of the patient.

SPILLS

Avoid all personal contact. Take up with absorbent material. Shovel into closed container. Flush

contaminated area with water. Dispose of collected materials in accordance with federal, state, and local

regulations. Avoid breathing vapors of heated material.

DISCLAIMERS

Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The

information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,

express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our

control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,

damage, or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared

and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

This MSDS has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).

B3.5
MATERIAL SAFETY DATA SHEET

PRODUCT: WOOD STAIN BASE (S93-03)

IPART 1 - GENERAL INFORMATION

Manufacturer:

Sierra Performance Coatings, Inc.

330 Primrose Road #502

Burlingame, CA 940 10

(650) 548-5 188

NPCA HMIS Rating

Health: 1

Flammability: 0

Reactivity: 0

Personal Protection: D

Emergency Numbers: l-800-424-9300 (Chemtrec)

Chemical Family:

Generic Name:

DOT Proper Shipping Name:

DOT Hazard Class:

Revision: 1 Date: 6/18/96

Latex Paint

Water Based Stain

Water Based Paint, n.o.s.

Not Regulated

PART 2 - Ingredients

Ingredient Name CAS # %weight OSHA(ue1) ACGIH(tlv)

Acrylic Polymer N/A <15% N/A N/A

IPART 3 - PHYSICAL AND CHEMICAL DATA

VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C

VOC excluding water: 0 grams/liter and 0 #/gal pH: 6.0 - 7.0

Volatile portion: 80 % wt Freezing Point: 0°C

Specific Gravity: 1.03 @2O”C Viscosity: 200 f 150 cps

Solubility in water: Slight Vapor Pressure: Negligible

Appearance and Odor: Milky white liquid/mild odor

Conditions and materials to avoid: High temperatures, oxidizing conditions. .

Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon

decomposition.

Stability: Stable

IPART 4 - FIRE AND EXPLOSION

Flash Point: > 212°C (Method: IS0 3679)

Autoignition temperature: N/DA

Flammable limits (%volume in air) Lower: N/DA Upper: N/DA

B3.6
Fire and explosion hazards: Not-flammable

Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.

Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe

distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed

containers spreading fire and increase the risk of bums and injuries. Use water spray/fog for cooling.

Notify authorities if liquid enters sewer or public waters.

IPART 5 - EMERGENCY AND FIRST AID

Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial

respiration as needed. Obtain emergency medical attention, prompt action is essential.

Eye Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract

eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.

Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.

Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.

Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious

and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency

medical attention.

Emergency Medical Treatment: Treat symptomatically.

IPART 6 - EFFECTS OF EXPOSURE

Routes of exposure:

Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its

low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as

coughing, shortness of breath, and mucus production.

Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness

and swelling.

Skin absorption: Potential route. Although no data was found for this product, the potential for skin

absorption does exist.

Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some

individuals after repeated skin contact.

Ingestion: This material may be a health hazard if ingested in large quantities.

Medical conditions aggravated by exposure: No additional medical information found.

IPART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES I

Respiratorv Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA

approved respiratory protection equipment.

Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when

possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact

lenses should not be worn.

Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face

protection should be worn. This equipment should be cleaned after each use.

B3.7
Enpineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation

is recommended.

Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the

immediate vicinity of any potential exposure.

Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using

the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work

using plenty of soap and water.

PART 8 - REACTIVITY DATA

Stable Stabilitv:

Incomnatibilitv: Strong bases and acids.

Hazardous polymerization: Will not occur.

Hazardous decomposition: Will not occur.

IPART 9 - SPILL OR LEAK PROCEDURES

Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed

container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with

federal, state, and local regulations.

IPART lo - STORAGE AND SPECIAL PRECAUTIONS

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:

Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated

material.

IPART 11- REGULATORY INFORMATION

None required for this product.

IPART 12 - LABEL INFORMATION

FOR INDUSTRIAL USE ONLY! ! Skin contact hazard. Eye and skin irritant.

May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.

Wash thoroughly after handling. Do not swallow. Prevent contact with food, chewing or smoking

materials.

FIRST AID I

EYES: Immediately flush with plenty of clean water

INHALATION: Remove to fresh air if effects occur. Consult a physician.

SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.

B3.8
INGESTION: Give fluids. Call a physician.

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of

physician in response to reaction of the patient.

SPILLS

Avoid all personal contact. Take up with absorbent material. Shovel into closed container. Flush

contaminated area with water. Dispose of collected materials in accordance with federal, state, and local

regulations. Avoid breathing vapors of heated material.

DISCLAIMERS

Some of the information presented and conclusions drawn herein are from sources other than direct test dataon the product itself. The information

in this MSDS was obtained 6om sources which we believe are reliable. However, the information is provided without any warranty, express or

implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may

be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense

arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only

for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been

prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).

C:\adco\msds\WST963.msd

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APPENDIX C

CASE STUDIES

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APPENDIX C.l

FIELD DEMONSTRATIONS FOR APPLICATION ON METALS

This No-VOC coating technology can formulate coatings that are applied not only on wood

products, but also on metals. AVES, working jointly with ADCO, formulated a state of the art

metal coating and demonstrated the potential for commercialization of this metal coating system.

Performance features of this new no-VOC industrial maintenance coating are:

0 Requires no solvents.

0 Delivers hardness with flexibility.

0 Versatile-compatible with most lattices.

0 Increases toughness/scrub resistance.

0 Increases chemical resistance.

0 Decreases dry times in slow dry systems.

0 Aids in coalescence to allow reduction or elimination of solvents.

Demonstrations of the new metal coating system were conducted at two manufacturing facilities.

The purpose of the demonstrations was to show that this new coating system could be used

successfully in a commercial metal finishing operation. The following summarizes the

demonstration processes.

C.l.l. Demonstrations at Facilitv A

Facility A manufactures motor homes. The operations at the Riverside facility include wood and

metal coatings, metal fabrication, wood and metal cutting, drywall fabrication, and engine

mounting. One of metal coatings involves coating of the metal chassis and structural beams of

the motor homes. The metal chassis provides the motor home frame on which other components

such as wheels and engine are mounted. The structural beams are referred to as Pace beams.

The metal Pace beams are mounted on top of the chassis, forming the sides and bottom of the

motor home.

Facility A coats the chassis and Pace beams to provide rust protection. The coating operation is

conducted inside a large spray booth with a dimension of 48’ L. x 22’ W. x 12’ H. Current

coating system used is a compliant coating with a VOC content of 1.2 lb/gal. Approximately,

half of a gallon is used for a singe chassis. The coating is applied using a high volume/ low

pressure (HVLP) gun. Four 5-HP fans exhaust the coating fumes from the spray booth.

Since the motor home is manufactured using an assembly line process, dry time is a critical

parameter. The current coating system dry time is approximately half an hour. Depending on

ambient temperature, the dry time for the current compliant coating product could vary

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substantially (from l/2 hour on a dry day to 2 days on high humidity days).

Demonstration, Conducted on Januarv 20. 1998

Representatives of AVES, ADCO, GRACO Equipment Manufacturer, and Butler Compressor &

Spray Equipment Co. conducted testing at Facility A on January 20, 1998 Two sets of a regular

RV chassis platform and several metal pieces were coated with ADCO’s no-VOC metal coatings.

The chassis surfaces were dry quickly. However, the Production Supervisor of Facility A

suggested that the painting be done by a professional painter, because the testing took too long

and the production schedule allowed only 30 minutes per chassis.

Staff took the plant’s advise and brought a professional painter from Fairway Painting to Facility

A on January 28, 1998. Two sets of a Pace-Beam RV chassis platform were coated. The first set

of Pace-Beam RV chassis platform was coated within 40 minutes and consumed 1.5 gallons of

coating. The painter changed the air pressure of the spray gun and reduced overspray from the

second set of Pace-Beam RV chassis platform. About 1.25 gallons of coating was consumed for

the second set of RV chassis. At 659 temperature and 78% relative humidity, the coated chassis

surface was dry in less than 30 minutes. Facility A staff was satisfied with the demonstration

results.

C.1.2. Demonstrations at Facilitv B

Facility B also manufactures motor homes. The process is very similar to the process at Facility

A. Facility B is planning a large expansion, and is thus expressing high interest in a non-VOC

coating like the ADCO system.

Currently, Facility B does not coat the whole chassis and Pace beam. Only the metal weld joints

on the chassis and Pace are coated using aerosol cans. The joints are coated for rust protection.

The coating is conducted outdoors without any confinement. The current coating system used

has a VOC content of 2 lb/gal. Facility B indicates that rust protection is a major issue. Another

critical parameter is dry time. Half an hour is an acceptable dry time for the coating process.

Demonstration, Conducted on Januarv 12. 1,998

Representatives of AVES, ADCO, GRACO Equipment Manufacturer, and Butler Compressor &

Spray Equipment Co. conducted testing at Facility B on January 12, 1998. The purposes of this

testing were: (1) to test the feasibility of the in-situ mixing spray gun to avoid premixing a two

part component coating system, and (2) to coordinate with Facility B personnel to expand the noVOC metal coating application (both RV chassis and trailer chassis). Two sets of powerstructure RV chassis platform were coated with ADCO’s no-VOC metal coatings. The first set of

power-structure RV chassis platform was slightly overcoated and resulted in dripping. Butler

Compressor & Spray Equipment Co. staff changed the tip size of the spray gun and reduced

dripping from the second set of power-structure RV chassis platform. About 1 to 1.25 gallons of

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coating was consumed for each set of RV chassis. Even if it was a cold day (temperature less

than 55% outdoors), the coated chassis surfaces were dry in about 30 minutes. After completion

of these two sets of power-structure RV chassis platform, the engineering services manager of

Facility B asked staff to coat a rusted trailer chassis to see whether this new no-VOC metal

coating can be applied to rusted surfaces and protect the surfaces from further corrosion. About

1.5 gallons of coating was used to cover this big trailer chassis. Facility B was satisfied with the

demonstration results.

C.1.3. Coatirw Comparison

Comparison of No-VOUNo-HAP Coating and the Current Compliant Coating

This no-VOC/no-HAP coating and the current compliant coating, (VOC 333 g/l) were sprayed

on metal panels and put in a salt spray cabinet using ASTM Method B 117 for corrosion

resistance testing. The current compliant coating failed after 192 hours (showed cracks and

blisters on coating surface) and the no-VOC coating reached 1700 hours before signs of cracking

appeared.

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APPENDIX C.2

POTENTIAL FORMULATION USING SOY BEAN OIL

For the past five years ADCO has been developing resin systems for industrial paints and

coatings that emit no volatile organic compounds (VOCs), and no hazardous air pollutants

(HAPS). These systems are based on ADCO’s patented technology which utilizes epoxy

functional materials emulsified in water, and then reacted to increase the molecular weight and

thus create unique resin systems which combine the qualities of high performance with the

practical benefits of ease of use, very low odor, and no volatiles other than water. Increasing the

molecular weight in such a manner creates resins that are well on their way to forming resin

films which are the binders for paints and coatings and which, to a large extent, define the

performance characteristics of a finished paint.

The same resin technology can be used to develop a high performance soy polymer (HPSP) that

employs epoxidized soybean oils and ADCO’s patented epoxy-functional, high molecular weight

technology as a resin for paints and coatings. The HPSP can be used with a variety of crosslinking materials including carboxyl, amino and hydroxyl functional resins, as well as

conventional driers. When developed these products could make a significant impact on sizable

markets offering these advantages: high performance at relatively low cost (up to 30-50% less

than competitive paint systems), user friendliness (water-based with no odor), versatility (can be

air dry or low bake), and environmental consciousness (utilizing a renewable resource material to

replace non-renewable resources as well as eliminating VOC and HAP emitting materials).

These systems differ from the epoxy systems in molecular backbone structure but not in

functionality. This research and development work focuses on the homopolymerization and

polymer chain extension of commercially available epoxidized soybean oils completed as water

emulsions or dispersions. The resultant high molecular weight soybean oil in water has distinct

advantages to paint and coating performance and versatility. One advantage is that when a paint

is applied fully, about one third to one half of the resin is already polymerized, so the cure time

is shortened considerably. This is an important consideration for all resin systems, specifically

for soy based paint products which are typically slow curing or require significant heat to give a

reasonable cure response. Another advantage would be that, when polymerized in this fashion,

the resulting resin usually requires no extra coalescing aids (normally VOCs) that contribute odor

and potential health risks allowing a lower odor, safer paint or coating product to be produced.

Still another advantage is that, being a water-based system, the paint or coating could be

pigmented using conventional dispersing techniques and tinted with commercially available

water-based tints for the full color spectrum.

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