# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls PFOA Page 1 of 5 **Sample**

**Name Sample ID**  **Sample Comment Sample Type**  **Analyte**

**Peak**

**Name Analyte** 

**Peak Area**

**(counts) Analyte** 

**Retention**

**Time (min) Analyte** 

**Conc.**

**(ng/mL) Use** 

**Record Calculated** 

**Concentration**

**(ng/mL) Accuracy** 

**(%) Record** 

**Modified Dilution**  **On-coln**

**conc**

k110715a001 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 428552 15.4 N/A 0.215 N/A 1 1

k110715a002 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 61016 15.4 N/A 0.0134 N/A 1 1

k110715a003 11003-26-8 1.0 ng/mL FC std in Milli Q Water Unknown PFOA 2275254 15.4 N/A 1.23 N/A 1 1

k110715a004 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 18073 15.4 N/A < 0 N/A 1 1

k110715a005 11003-26-9 2.5 ng/mL FC std in Milli Q Water Unknown PFOA 5241381 15.4 N/A 2.89 N/A 0 1

k110715a006 11003-26-9 2.5 ng/mL FC std in Milli Q Water Unknown PFOA 5181599 15.4 N/A 2.85 N/A 1 1

k110715a007 11003-26-9 2.5 ng/mL FC std in Milli Q Water Unknown PFOA 5092887 15.4 N/A 2.8 N/A 1 1

k110715a008 11003-26-9 2.5 ng/mL FC std in Milli Q Water Unknown PFOA 4943181 15.4 N/A 2.72 N/A 1 1

k110715a009 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6656 15.7 N/A < 0 N/A 0 1

k110715a010 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 5330 15.7 N/A < 0 N/A 0 1

k110715a011 11003-26-1 0.025 ng/mL FC std in Milli Q Water Standard PFOA 79684 15.5 0.025 1 0.0237 94.7 0 1

k110715a012 11003-26-2 0.03 ng/mL FC std in Milli Q Water Standard PFOA 84914 15.5 0.03 1 0.0266 88.5 1 1

k110715a013 11003-26-3 0.04 ng/mL FC std in Milli Q Water Standard PFOA 107795 15.4 0.04 1 0.0391 97.8 1 1

k110715a014 11003-26-4 0.05 ng/mL FC std in Milli Q Water Standard PFOA 118906 15.4 0.05 1 0.0452 90.4 0 1

k110715a015 11003-26-5 0.1 ng/mL FC std in Milli Q Water Standard PFOA 222109 15.4 0.1 1 0.102 102 0 1

k110715a016 11003-26-6 0.25 ng/mL FC std in Milli Q Water Standard PFOA 516292 15.4 0.25 1 0.263 105 1 1

k110715a017 11003-26-7 0.5 ng/mL FC std in Milli Q Water Standard PFOA 981883 15.4 0.5 1 0.52 104 1 1

k110715a018 11003-26-8 1.0 ng/mL FC std in Milli Q Water Standard PFOA 2026711 15.4 1 1 1.1 110 1 1

k110715a019 11003-26-9 2.5 ng/mL FC std in Milli Q Water Standard PFOA 4777305 15.5 2.5 1 2.63 105 1 1

k110715a020 11003-26-10 5.0 ng/mL FC std in Milli Q Water Standard PFOA 9217151 15.4 5 1 5.14 103 1 1

k110715a021 11003-26-11 10 ng/mL FC std in Milli Q Water Standard PFOA 17757632 15.4 10 1 10.1 101 1 1

k110715a022 11003-26-12 25 ng/mL FC std in Milli Q Water Standard PFOA 41779501 15.5 25 1 25.3 101 1 1

k110715a023 11003-26-13 50 ng/mL FC std in Milli Q Water Standard PFOA 72084171 15.4 50 1 48.5 96.9 1 1

k110715a024 11003-26-14 75 ng/mL FC std in Milli Q Water Standard PFOA 96394636 15.4 75 1 73.3 97.7 1 1

k110715a025 11003-26-15 100 ng/mL FC std in Milli Q Water Standard PFOA 114703888 15.5 100 1 104 104 1 1

k110715a026 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 30048 15.5 N/A < 0 N/A 0 1

k110715a027 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 8455 15.5 N/A < 0 N/A 0 1

k110715a028 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 7526 15.5 N/A < 0 N/A 0 1

k110715a029 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 5416 15.5 N/A < 0 N/A 0 1

k110715a030 LCS-110714-1 0.5ppb LCS Quality Control PFOA 963879 15.5 0.498 1 0.51 102 1 1

k110715a031 LCS-110714-2 0.5ppb LCS Quality Control PFOA 956199 15.4 0.498 1 0.506 102 0 1

k110715a032 LCS-110714-3 0.5ppb LCS Quality Control PFOA 1031950 15.4 0.498 1 0.547 110 0 1

k110715a033 LCS-110714-4 5ppb LCS Quality Control PFOA 9252077 15.4 4.98 1 5.16 104 0 1

k110715a034 LCS-110714-5 5ppb LCS Quality Control PFOA 9439709 15.5 4.98 1 5.26 106 0 1

k110715a035 LCS-110714-6 5ppb LCS Quality Control PFOA 9440299 15.4 4.98 1 5.26 106 1 1

k110715a036 LCS-110714-7 30ppb LCS Quality Control PFOA 46053927 15.5 29.9 1 28.3 94.6 1 1

k110715a037 LCS-110714-8 30ppb LCS Quality Control PFOA 44939921 15.4 29.9 1 27.5 92 1 1

k110715a038 LCS-110714-9 30ppb LCS Quality Control PFOA 46186425 15.5 29.9 1 28.4 94.9 1 1

k110715a039 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6779 15.5 N/A < 0 N/A 0 1

k110715a040 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3416 15.9 N/A < 0 N/A 0 1

k110715a041 11003-26-10 5.0 ng/mL FC std in Milli Q Water Quality Control PFOA 8932786 15.5 5 1 4.97 99.5 0 1

k110715a042 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 5900 15.5 N/A < 0 N/A 0 1

k110715a043 LCS-110714-10 0.5ppb LCS ECF Quality Control PFOA 986975 15.5 0.498 1 0.522 105 1 1

k110715a044 LCS-110714-11 0.5ppb LCS ECF Quality Control PFOA 892323 15.4 0.498 1 0.47 94.4 1 1

k110715a045 LCS-110714-12 0.5ppb LCS ECF Quality Control PFOA 928923 15.4 0.498 1 0.491 98.5 1 1

k110715a046 LCS-110714-13 5ppb LCS ECF Quality Control PFOA 8898047 15.5 4.99 1 4.96 99.3 1 1

k110715a047 LCS-110714-14 5ppb LCS ECF Quality Control PFOA 8956716 15.4 4.99 1 4.99 100 1 1

k110715a048 LCS-110714-15 5ppb LCS ECF Quality Control PFOA 9291104 15.4 4.99 1 5.18 104 1 1

k110715a049 LCS-110714-16 30ppb LCS ECF Quality Control PFOA 50287005 15.5 29.9 1 31.3 105 1 1

k110715a050 LCS-110714-17 30ppb LCS ECF Quality Control PFOA 48914304 15.4 29.9 1 30.3 101 1 1

k110715a051 LCS-110714-18 30ppb LCS ECF Quality Control PFOA 49150855 15.4 29.9 1 30.5 102 1 1

k110715a052 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 5294 15.8 N/A < 0 N/A 0 1

k110715a053 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 5588 15.8 N/A < 0 N/A 0 1

k110715a054 11003-26-9 2.5 ng/mL FC std in Milli Q Water Quality Control PFOA 4515007 15.4 2.5 1 2.48 99.2 1 1

k110715a055 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3733 15.5 N/A < 0 N/A 0 1

k110715a056 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6154 15.8 N/A < 0 N/A 0 1

k110715a057 GLP10-01-01-18-001 Trip Blank Set 2 Sample Unknown PFOA 2801 15.9 N/A < 0 N/A 0 1 #VALUE!

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls PFOA Page 2 of 5 **Sample**

**Name Sample ID**  **Sample Comment Sample Type**  **Analyte**

**Peak**

**Name Analyte** 

**Peak Area**

**(counts) Analyte** 

**Retention**

**Time (min) Analyte** 

**Conc.**

**(ng/mL) Use** 

**Record Calculated** 

**Concentration**

**(ng/mL) Accuracy** 

**(%) Record** 

**Modified Dilution**  **On-coln**

**conc**

k110715a058 GLP10-01-01-18-002 Trip Blank Set 2 LS Unknown PFOA 1769988 15.4 N/A 0.954 N/A 1 1 0.954

k110715a059 GLP10-01-01-18-003 Trip Blank Set 2 MS Unknown PFOA 16364277 15.4 N/A 9.29 N/A 1 1 9.29

k110715a060 GLP10-01-01-18-004 Trip Blank Set 2 MHS Unknown PFOA 30513068 15.4 N/A 89.7 N/A 1 5 17.94

k110715a061 GLP10-01-01-18-005 Trip Blank Set 2 HS (dil 1:100) Unknown PFOA 7982102 15.4 N/A 443 N/A 1 100 4.43

k110715a062 GLP10-01-01-18-006 DAL GW 130R 0 110630 (dil 1:100) Unknown PFOA 14802990 15.5 N/A 837 N/A 1 100 8.37

k110715a063 GLP10-01-01-18-007 DAL GW 130R DB 110630 (dil 1:100) Unknown PFOA 14565294 15.4 N/A 823 N/A 1 100 8.23

k110715a064 GLP10-01-01-18-008 DAL GW 130R LS 110630 (dil 1:100) Unknown PFOA 14746656 15.5 N/A 833 N/A 1 100 8.33

k110715a065 GLP10-01-01-18-009 DAL GW 130R MS 110630 (dil 1:100) Unknown PFOA 16243219 15.4 N/A 921 N/A 1 100 9.21

k110715a066 GLP10-01-01-18-010 DAL GW 130R HS 110630 (dil 1:100) Unknown PFOA 22303777 15.4 N/A 1280 N/A 1 100 12.8

k110715a067 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 9964 15.9 N/A < 0 N/A 0 1

k110715a068 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 8526 15.5 N/A < 0 N/A 0 1

k110715a069 11003-26-10 5.0 ng/mL FC std in Milli Q Water Quality Control PFOA 8839420 15.4 5 1 4.92 98.4 1 1

k110715a070 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3608 15.9 N/A < 0 N/A 0 1

k110715a071 GLP10-01-01-18-011 DAL GW 130S 0 110630 (dil 1:10) Unknown PFOA 30524073 15.4 N/A 180 N/A 1 10 18

k110715a072 GLP10-01-01-18-012 DAL GW 130S 0 110630 (dil 1:10) Unknown PFOA 30349497 15.4 N/A 178 N/A 1 10 17.8

k110715a073 GLP10-01-01-18-013 DAL GW 130S LS 110630 (dil 1:100) Unknown PFOA 3316855 15.4 N/A 181 N/A 1 100 1.81

k110715a074 GLP10-01-01-18-014 DAL GW 130S MS 110630 (dil 1:100) Unknown PFOA 4819966 15.4 N/A 265 N/A 1 100 2.65

k110715a075 GLP10-01-01-18-015 DAL GW 130S HS 110630 (dil 1:100) Unknown PFOA 12596334 15.4 N/A 708 N/A 1 100 7.08

k110715a076 GLP10-01-01-18-016 DAL GW 130L 0 110630 (dil 1:10) Unknown PFOA 11898880 15.4 N/A 66.8 N/A 1 10 6.68

k110715a077 GLP10-01-01-18-017 DAL GW 130L DB 110630 (dil 1:10) Unknown PFOA 11302154 15.4 N/A 63.3 N/A 1 10 6.33

k110715a078 GLP10-01-01-18-018 DAL GW 130L LS 110630 (dil 1:10) Unknown PFOA 12235962 15.4 N/A 68.7 N/A 1 10 6.87

k110715a079 GLP10-01-01-18-019 DAL GW 130L MS 110630 (dil 1:10) Unknown PFOA 13283959 15.4 N/A 74.8 N/A 1 10 7.48

k110715a080 GLP10-01-01-18-020 DAL GW 130L HS 110630 (dil 1:10) Unknown PFOA 27046340 15.4 N/A 158 N/A 1 10 15.8

k110715a081 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3547 15.5 N/A < 0 N/A 0 1

k110715a082 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 4296 15.5 N/A < 0 N/A 0 1

k110715a083 11003-26-11 10 ng/mL FC std in Milli Q Water Quality Control PFOA 16989171 15.4 10 1 9.66 96.6 1 1

k110715a084 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 7816 15.5 N/A < 0 N/A 0 1

k110715a085 GLP10-01-01-18-021 DAL GW 131R 0 110622 (dil 1:100) Unknown PFOA 38390775 15.4 N/A 2310 N/A 1 100 23.1

k110715a086 GLP10-01-01-18-022 DAL GW 131R DB 110622 (dil 1:100) Unknown PFOA 42046962 15.4 N/A 2550 N/A 1 100 25.5

k110715a087 GLP10-01-01-18-023 DAL GW 131R LS 110622 (dil 1:100) Unknown PFOA 41164570 15.5 N/A 2490 N/A 1 100 24.9

k110715a088 GLP10-01-01-18-024 DAL GW 131R HS 110622 (dil 1:100) Unknown PFOA 62574999 15.4 N/A 4060 N/A 1 100 40.6

k110715a089 GLP10-01-01-18-025 DAL GW 131S 0 110622 (dil 1:10) Unknown PFOA 1006429 15.4 N/A 26.7 N/A 1 50 0.534

k110715a090 GLP10-01-01-18-026 DAL GW 131S DB 110622 (dil 1:10) Unknown PFOA 972385 15.4 N/A 25.7 N/A 1 50 0.514

k110715a091 GLP10-01-01-18-027 DAL GW 131S LS 110622 (dil 1:10) Unknown PFOA 1003100 15.4 N/A 26.6 N/A 1 50 0.532

k110715a092 GLP10-01-01-18-028 DAL GW 131S MS 110622 (dil 1:10) Unknown PFOA 1343986 15.4 N/A 36 N/A 1 50 0.72

k110715a093 GLP10-01-01-18-029 DAL GW 131S HS 110622 (dil 1:10) Unknown PFOA 4205983 15.4 N/A 115 N/A 1 50 2.3

k110715a094 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3033 15.8 N/A < 0 N/A 0 1

k110715a095 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6444 15.5 N/A < 0 N/A 0 1

k110715a096 11003-26-9 2.5 ng/mL FC std in Milli Q Water Quality Control PFOA 4559996 15.4 2.5 1 2.51 100 1 1

k110715a097 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 2847 15.5 N/A < 0 N/A 0 1

k110715a098 GLP10-01-01-18-030 DAL GW 131L 0 110622 (dil 1:10) Unknown PFOA 16548643 15.4 N/A 93.9 N/A 1 10 9.39

k110715a099 GLP10-01-01-18-031 DAL GW 131L DB 110622 (dil 1:10) Unknown PFOA 16924324 15.4 N/A 96.2 N/A 1 10 9.62

k110715a100 GLP10-01-01-18-032 DAL GW 131L LS 110622 (dil 1:10) Unknown PFOA 17123392 15.4 N/A 97.3 N/A 1 10 9.73

k110715a101 GLP10-01-01-18-033 DAL GW 131L MS 110622 (dil 1:10) Unknown PFOA 18828610 15.5 N/A 107 N/A 1 10 10.7

k110715a102 GLP10-01-01-18-034 DAL GW 131L HS 110622 (dil 1:10) Unknown PFOA 31418926 15.4 N/A 185 N/A 1 10 18.5

k110715a103 GLP10-01-01-18-035 DAL GW 133L 0 110630 (dil 1:10) Unknown PFOA 8260473 15.4 N/A 230 N/A 1 50 4.600

k110715a104 GLP10-01-01-18-036 DAL GW 133L DB 110630 (dil 1:10) Unknown PFOA 8131453 15.4 N/A 226 N/A 1 50 4.52

k110715a105 GLP10-01-01-18-037 DAL GW 133L LS 110630 (dil 1:10) Unknown PFOA 9508711 15.4 N/A 265 N/A 1 50 5.300

k110715a106 GLP10-01-01-18-038 DAL GW 133L MS 110630 (dil 1:10) Unknown PFOA 14767838 15.4 N/A 417 N/A 1 50 8.34

k110715a107 GLP10-01-01-18-039 DAL GW 133L HS 110630 (dil 1:10) Unknown PFOA 24465047 15.4 N/A 708 N/A 1 50 14.16

k110715a108 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6908 15.5 N/A < 0 N/A 0 1

k110715a109 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 7830 15.9 N/A < 0 N/A 0 1

k110715a110 11003-26-10 5.0 ng/mL FC std in Milli Q Water Quality Control PFOA 8946596 15.5 5 1 4.98 99.7 1 1

k110715a111 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 7396 15.9 N/A < 0 N/A 0 1

k110715a112 GLP10-01-01-18-040 DAL GW 133S 0 110630 (dil 1:10) Unknown PFOA 11104112 15.4 N/A 311 N/A 1 50 6.22

k110715a113 GLP10-01-01-18-041 DAL GW 133S DB 110630 (dil 1:10) Unknown PFOA 11217865 15.4 N/A 314 N/A 1 50 6.28

k110715a114 GLP10-01-01-18-042 DAL GW 133S LS 110630 (dil 1:10) Unknown PFOA 11289175 15.4 N/A 316 N/A 1 50 6.32

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls PFOA Page 3 of 5 **Sample**

**Name Sample ID**  **Sample Comment Sample Type**  **Analyte**

**Peak**

**Name Analyte** 

**Peak Area**

**(counts) Analyte** 

**Retention**

**Time (min) Analyte** 

**Conc.**

**(ng/mL) Use** 

**Record Calculated** 

**Concentration**

**(ng/mL) Accuracy** 

**(%) Record** 

**Modified Dilution**  **On-coln**

**conc**

k110715a115 GLP10-01-01-18-043 DAL GW 133S MS 110630 (dil 1:10) Unknown PFOA 14063129 15.4 N/A 397 N/A 1 50 7.94

k110715a116 GLP10-01-01-18-044 DAL GW 133S HS 110630 (dil 1:10) Unknown PFOA 26384544 15.4 N/A 768 N/A 1 50 15.36

k110715a117 GLP10-01-01-18-045 DAL GW 133R 0 110630 (dil 1:10) Unknown PFOA 18890925 15.4 N/A 108 N/A 1 10 10.8

k110715a118 GLP10-01-01-18-046 DAL GW 133R DB 110630 (dil 1:10) Unknown PFOA 18909016 15.4 N/A 108 N/A 1 10 10.8

k110715a119 GLP10-01-01-18-047 DAL GW 133R LS 110630 (dil 1:10) Unknown PFOA 17002577 15.4 N/A 96.6 N/A 1 10 9.66

k110715a120 GLP10-01-01-18-048 DAL GW 133R MS 110630 (dil 1:10) Unknown PFOA 19563778 15.4 N/A 112 N/A 1 10 11.2

k110715a121 GLP10-01-01-18-049 DAL GW 133R HS 110630 (dil 1:10) Unknown PFOA 32146060 15.4 N/A 190 N/A 1 10 19

k110715a122 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 4509 15.5 N/A < 0 N/A 0 1

k110715a123 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3247 15.9 N/A < 0 N/A 0 1

k110715a124 11003-26-8 1.0 ng/mL FC std in Milli Q Water Quality Control PFOA 1950690 15.4 1 1 1.05 105 1 1

k110715a125 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 3896 15.7 N/A < 0 N/A 0 1

k110715a126 GLP10-01-01-18-050 DAL GW 134R 0 110628 (dil 1:100) Unknown PFOA 30420430 15.5 N/A 1790 N/A 1 100 17.9

k110715a127 GLP10-01-01-18-051 DAL GW 134R DB 110628 (dil 1:100) Unknown PFOA 30552302 15.4 N/A 1800 N/A 1 100 18

k110715a128 GLP10-01-01-18-052 DAL GW 134R LS 110628 (dil 1:100) Unknown PFOA 31722139 15.4 N/A 1870 N/A 1 100 18.7

k110715a129 GLP10-01-01-18-053 DAL GW 134R HS 110628 (dil 1:100) Unknown PFOA 56764811 15.4 N/A 3610 N/A 1 100 36.1

k110715a130 GLP10-01-01-18-054 DAL GW 134L 0 110628 (dil 1:10) Unknown PFOA 18471422 15.4 N/A 527 N/A 1 50 10.54

k110715a131 GLP10-01-01-18-055 DAL GW 134L DB 110628 (dil 1:10) Unknown PFOA 20629650 15.4 N/A 592 N/A 1 50 11.84

k110715a132 GLP10-01-01-18-056 DAL GW 134L LS 110628 (dil 1:10) Unknown PFOA 20968155 15.4 N/A 602 N/A 1 50 12.04

k110715a133 GLP10-01-01-18-057 DAL GW 134L MS 110628 (dil 1:10) Unknown PFOA 23431483 15.4 N/A 677 N/A 1 50 13.54

k110715a134 GLP10-01-01-18-058 DAL GW 134L HS 110628 (dil 1:10) Unknown PFOA 34169371 15.4 N/A 1010 N/A 1 50 20.2

k110715a135 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 11090 15.5 N/A < 0 N/A 0 1

k110715a136 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 25177 15.5 N/A < 0 N/A 0 1

k110715a137 11003-26-9 2.5 ng/mL FC std in Milli Q Water Quality Control PFOA 4618301 15.4 2.5 1 2.54 102 1 1

k110715a138 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 14220 15.5 N/A < 0 N/A 0 1

k110715a139 GLP10-01-01-18-059 DAL GW 134S 0 110628 Unknown PFOA 3535193 15.4 N/A 9.67 N/A 1 5 1.934

k110715a140 GLP10-01-01-18-060 DAL GW 134S DB 110628 Unknown PFOA 3624220 15.4 N/A 9.92 N/A 1 5 1.984

k110715a141 GLP10-01-01-18-061 DAL GW 134S LS 110628 Unknown PFOA 3510557 15.4 N/A 9.6 N/A 1 5 1.92

k110715a142 GLP10-01-01-18-062 DAL GW 134S MS 110628 Unknown PFOA 3904635 15.4 N/A 10.7 N/A 1 5 2.14

k110715a143 GLP10-01-01-18-063 DAL GW 134S HS 110628 Unknown PFOA 7077087 15.4 N/A 19.6 N/A 1 5 3.92

k110715a144 GLP10-01-01-18-064 Trip Blank Set 1 Sample Unknown PFOA 9562 15.4 N/A < 0 N/A 1 1 #VALUE!

k110715a145 GLP10-01-01-18-065 Trip Blank Set 1 LS Unknown PFOA 1818046 15.4 N/A 0.981 N/A 1 1 0.981

k110715a146 GLP10-01-01-18-066 Trip Blank Set 1 MS Unknown PFOA 17620512 15.4 N/A 10 N/A 1 1 10

k110715a147 GLP10-01-01-18-067 Trip Blank Set 1 MHS Unknown PFOA 32332229 15.4 N/A 95.5 N/A 1 5 19.1

k110715a148 GLP10-01-01-18-068 Trip Blank Set 1 HS (dil 1:100) Unknown PFOA 8849618 15.4 N/A 493 N/A 1 100 4.93

k110715a149 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 4243 15.5 N/A < 0 N/A 0 1

k110715a150 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 4567 15.5 N/A < 0 N/A 1 1

k110715a151 11003-26-11 10 ng/mL FC std in Milli Q Water Quality Control PFOA 17545963 15.5 10 1 9.99 99.9 1 1

k110715a152 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6473 15.6 N/A < 0 N/A 1 1

k110715a153 GLP10-01-01-18-069 DAL GW 135S 0 110628 Unknown PFOA 6830157 15.4 N/A 18.9 N/A 1 5 3.78

k110715a154 GLP10-01-01-18-070 DAL GW 135S DB 110628 Unknown PFOA 7322715 15.4 N/A 20.3 N/A 1 5 4.06

k110715a155 GLP10-01-01-18-071 DAL GW 135S LS 110628 Unknown PFOA 8709535 15.4 N/A 24.2 N/A 1 5 4.84

k110715a156 GLP10-01-01-18-072 DAL GW 135S MS 110628 Unknown PFOA 7427254 15.4 N/A 20.6 N/A 1 5 4.12

k110715a157 GLP10-01-01-18-073 DAL GW 135S HS 110628 Unknown PFOA 14135478 15.4 N/A 39.9 N/A 1 5 7.98

k110715a158 GLP10-01-01-18-074 DAL GW 135L 0 110628 (dil 1:10) Unknown PFOA 46122156 15.5 N/A 283 N/A 1 10 28.3

k110715a159 GLP10-01-01-18-075 DAL GW 135L DB 110628 (dil 1:10) Unknown PFOA 44519562 15.5 N/A 272 N/A 1 10 27.2

k110715a160 GLP10-01-01-18-076 DAL GW 135L LS 110628 (dil 1:10) Unknown PFOA 45307922 15.5 N/A 278 N/A 1 10 27.8

k110715a161 GLP10-01-01-18-077 DAL GW 135L MS 110628 (dil 1:10) Unknown PFOA 46939862 15.5 N/A 289 N/A 1 10 28.9

k110715a162 GLP10-01-01-18-078 DAL GW 135L HS 110628 (dil 1:10) Unknown PFOA 57279088 15.5 N/A 365 N/A 1 10 36.5

k110715a163 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 8337 15.5 N/A < 0 N/A 0 1

k110715a164 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 2637 15.6 N/A < 0 N/A 0 1

k110715a165 11003-26-10 5.0 ng/mL FC std in Milli Q Water Quality Control PFOA 8986786 15.5 5 1 5.01 100 1 1

k110715a166 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 12628 15.6 N/A < 0 N/A 0 1

k110715a167 GLP10-01-01-18-079 DAL GW 135R 0 110628 (dil 1:100) Unknown PFOA 56222974 15.5 N/A 3570 N/A 1 100 35.70

k110715a168 GLP10-01-01-18-080 DAL GW 135R DB 110628 (dil 1:100) Unknown PFOA 54804934 15.4 N/A 3460 N/A 1 100 34.60

k110715a169 GLP10-01-01-18-081 DAL GW 135R LS 110628 (dil 1:100) Unknown PFOA 56700713 15.4 N/A 3600 N/A 1 100 36.00

k110715a170 GLP10-01-01-18-083 DAL GW 135R HS 110628 (dil 1:100) Unknown PFOA 76644663 15.4 N/A 5250 N/A 1 100 52.5

k110715a171 GLP10-01-01-18-084 DAL GW 136L 0 110630 (dil 1:10) Unknown PFOA 2925019 15.4 N/A 79.7 N/A 1 50 1.594

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls PFOA Page 4 of 5 **Sample**

**Name Sample ID**  **Sample Comment Sample Type**  **Analyte**

**Peak**

**Name Analyte** 

**Peak Area**

**(counts) Analyte** 

**Retention**

**Time (min) Analyte** 

**Conc.**

**(ng/mL) Use** 

**Record Calculated** 

**Concentration**

**(ng/mL) Accuracy** 

**(%) Record** 

**Modified Dilution**  **On-coln**

**conc**

k110715a172 GLP10-01-01-18-085 DAL GW 136L DB 110630 (dil 1:10) Unknown PFOA 2874905 15.4 N/A 78.3 N/A 1 50 1.566

k110715a173 GLP10-01-01-18-086 DAL GW 136L LS 110630 (dil 1:10) Unknown PFOA 2921336 15.4 N/A 79.6 N/A 1 50 1.592

k110715a174 GLP10-01-01-18-155 DAL GW 136L MS 110630 (dil 1:10) Unknown PFOA 3263811 15.4 N/A 89.1 N/A 1 50 1.782

k110715a175 GLP10-01-01-18-087 DAL GW 136L HS 110630 (dil 1:10) Unknown PFOA 6143782 15.4 N/A 170 N/A 1 50 3.4

k110715a176 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 10303 15.4 N/A < 0 N/A 0 1

k110715a177 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 2943 15.5 N/A < 0 N/A 0 1

k110715a178 11003-26-8 1.0 ng/mL FC std in Milli Q Water Quality Control PFOA 1945252 15.4 1 1 1.05 105 1 1

k110715a179 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6033 15.5 N/A < 0 N/A 0 1

k110715a180 GLP10-01-01-18-088 DAL GW 136S 0 110630 (dil 1:10) Unknown PFOA 22653847 15.4 N/A 131 N/A 1 10 13.1

k110715a181 GLP10-01-01-18-089 DAL GW 136S DB 110630 (dil 1:10) Unknown PFOA 22668981 15.4 N/A 131 N/A 1 10 13.1

k110715a182 GLP10-01-01-18-090 DAL GW 136S LS 110630 (dil 1:10) Unknown PFOA 22817944 15.4 N/A 132 N/A 1 10 13.2

k110715a183 GLP10-01-01-18-091 DAL GW 136S MS 110630 (dil 1:10) Unknown PFOA 23475309 15.5 N/A 136 N/A 1 10 13.6

k110715a184 GLP10-01-01-18-092 DAL GW 136S HS 110630 (dil 1:10) Unknown PFOA 36337810 15.4 N/A 217 N/A 1 10 21.7

k110715a185 GLP10-01-01-18-093 DAL GW 137S 0 110624 Unknown PFOA 553876 15.5 N/A 0.284 N/A 1 1 0.284

k110715a186 GLP10-01-01-18-094 DAL GW 137S DB 110624 Unknown PFOA 525864 15.5 N/A 0.269 N/A 1 1 0.269

k110715a187 GLP10-01-01-18-095 DAL GW 137S LS 110624 Unknown PFOA 733508 15.4 N/A 0.383 N/A 1 1 0.383

k110715a188 GLP10-01-01-18-096 DAL GW 137S MS 110624 Unknown PFOA 2180672 15.4 N/A 1.18 N/A 0 1 1.18

k110715a189 GLP10-01-01-18-097 DAL GW 137S HS 110624 Unknown PFOA 16430196 15.4 N/A 9.32 N/A 0 1 9.32

k110715a190 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 24247 15.5 N/A < 0 N/A 0 1

k110715a191 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 11381 15.4 N/A < 0 N/A 0 1

k110715a192 11003-26-9 2.5 ng/mL FC std in Milli Q Water Quality Control PFOA 4738949 15.4 2.5 1 2.61 104 1 1

k110715a193 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6875 15.5 N/A < 0 N/A 0 1

k110715a194 GLP10-01-01-18-098 DAL GW 137L 0 110624 Unknown PFOA 713968 15.4 N/A 0.372 N/A 1 1 0.372

k110715a195 GLP10-01-01-18-099 DAL GW 137L DB 110624 Unknown PFOA 729396 15.4 N/A 0.381 N/A 1 1 0.381

k110715a196 GLP10-01-01-18-100 DAL GW 137L LS 110624 Unknown PFOA 905110 15.4 N/A 0.477 N/A 1 1 0.477

k110715a197 GLP10-01-01-18-101 DAL GW 137L MS 110624 Unknown PFOA 2479176 15.4 N/A 1.35 N/A 1 1 1.35

k110715a198 GLP10-01-01-18-102 DAL GW 137L HS 110624 Unknown PFOA 17534357 15.4 N/A 9.98 N/A 0 1 9.98

k110715a199 GLP10-01-01-18-103 DAL GW 138R 0 110630 (dil 1:10) Unknown PFOA 47583692 15.4 N/A 294 N/A 1 10 29.4

k110715a200 GLP10-01-01-18-104 DAL GW 138R DB 110630 (dil 1:10) Unknown PFOA 46726845 15.4 N/A 288 N/A 1 10 28.8

k110715a201 GLP10-01-01-18-105 DAL GW 138R LS 110630 (dil 1:10) Unknown PFOA 47383282 15.4 N/A 292 N/A 1 10 29.2

k110715a202 GLP10-01-01-18-106 DAL GW 138R MS 110630 (dil 1:10) Unknown PFOA 58021857 15.4 N/A 370 N/A 1 10 37

k110715a203 GLP10-01-01-18-107 DAL GW 138R HS 110630 (dil 1:10) Unknown PFOA 94415521 15.4 N/A 709 N/A 1 10 70.9

k110715a204 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 51098 15.5 N/A 0.008 N/A 0 1

k110715a205 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 14265 15.4 N/A < 0 N/A 1 1

k110715a206 11003-26-11 10 ng/mL FC std in Milli Q Water Quality Control PFOA 17469490 15.4 10 1 9.94 99.4 0 1

k110715a207 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 34849 15.5 N/A < 0 N/A 1 1

k110715a208 GLP10-01-01-18-108 DAL GW 138L 0 110630 Unknown PFOA 1655909 15.4 N/A 0.891 N/A 1 1 0.891

k110715a209 GLP10-01-01-18-109 DAL GW 138L DB 110630 Unknown PFOA 1660589 15.4 N/A 0.894 N/A 1 1 0.894

k110715a210 GLP10-01-01-18-110 DAL GW 138L LS 110630 Unknown PFOA 1805976 15.4 N/A 0.974 N/A 1 1 0.974

k110715a211 GLP10-01-01-18-111 DAL GW 138L MS 110630 Unknown PFOA 3092233 15.4 N/A 1.69 N/A 1 1 1.69

k110715a212 GLP10-01-01-18-112 DAL GW 138L HS 110630 Unknown PFOA 16119725 15.4 N/A 9.14 N/A 1 1 9.14

k110715a213 GLP10-01-01-18-113 DAL GW 138S 0 110630 (dil 1:10) Unknown PFOA 5604337 15.4 N/A 155 N/A 1 50 3.1

k110715a214 GLP10-01-01-18-114 DAL GW 138S DB 110630 (dil 1:10) Unknown PFOA 5557016 15.4 N/A 153 N/A 1 50 3.06

k110715a215 GLP10-01-01-18-115 DAL GW 138S LS 110630 (dil 1:10) Unknown PFOA 5836366 15.4 N/A 161 N/A 1 50 3.22

k110715a216 GLP10-01-01-18-116 DAL GW 138S MS 110630 (dil 1:10) Unknown PFOA 8301390 15.4 N/A 231 N/A 1 50 4.62

k110715a217 GLP10-01-01-18-117 DAL GW 138S HS 110630 (dil 1:10) Unknown PFOA 21245685 15.4 N/A 610 N/A 1 50 12.2

k110715a218 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 9819 15.6 N/A < 0 N/A 0 1

k110715a219 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6440 15.5 N/A < 0 N/A 0 1

k110715a220 11003-26-10 5.0 ng/mL FC std in Milli Q Water Quality Control PFOA 8639138 15.4 5 1 4.81 96.1 1 1

k110715a221 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 9608 15.5 N/A < 0 N/A 0 1

k110715a222 GLP10-01-01-18-118 DAL GW CW26C 0 110622 (dil 1:10) Unknown PFOA 15087641 15.4 N/A 427 N/A 1 50 8.54

k110715a223 GLP10-01-01-18-119 DAL GW CW26C DB 110622 (dil 1:10) Unknown PFOA 15029361 15.4 N/A 425 N/A 1 50 8.5

k110715a224 GLP10-01-01-18-120 DAL GW CW26C LS 110622 (dil 1:10) Unknown PFOA 15420534 15.4 N/A 436 N/A 1 50 8.72

k110715a225 GLP10-01-01-18-121 DAL GW CW26C MS 110622 (dil 1:10) Unknown PFOA 17638111 15.4 N/A 502 N/A 1 50 10.04

k110715a226 GLP10-01-01-18-122 DAL GW CW26C HS 110622 (dil 1:10) Unknown PFOA 28731422 15.4 N/A 841 N/A 1 50 16.82

k110715a227 GLP10-01-01-18-123 DAL GW CW26L 0 110622 (dil 1:10) Unknown PFOA 22392308 15.4 N/A 645 N/A 1 50 12.9

k110715a228 GLP10-01-01-18-124 DAL GW CW26L DB 110622 (dil 1:10) Unknown PFOA 22371522 15.4 N/A 644 N/A 1 50 12.88

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls PFOA Page 5 of 5 **Sample**

**Name Sample ID**  **Sample Comment Sample Type**  **Analyte**

**Peak**

**Name Analyte** 

**Peak Area**

**(counts) Analyte** 

**Retention**

**Time (min) Analyte** 

**Conc.**

**(ng/mL) Use** 

**Record Calculated** 

**Concentration**

**(ng/mL) Accuracy** 

**(%) Record** 

**Modified Dilution**  **On-coln**

**conc**

k110715a229 GLP10-01-01-18-125 DAL GW CW26L LS 110622 (dil 1:10) Unknown PFOA 23131837 15.4 N/A 667 N/A 1 50 13.34

k110715a230 GLP10-01-01-18-126 DAL GW CW26L MS 110622 (dil 1:10) Unknown PFOA 24932867 15.4 N/A 723 N/A 1 50 14.46

k110715a231 GLP10-01-01-18-127 DAL GW CW26L HS 110622 (dil 1:10) Unknown PFOA 35691197 15.4 N/A 1060 N/A 1 50 21.2

k110715a232 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 10934 15.5 N/A < 0 N/A 0 1

k110715a233 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 8493 15.5 N/A < 0 N/A 0 1

k110715a234 11003-26-8 1.0 ng/mL FC std in Milli Q Water Quality Control PFOA 1832372 15.4 1 1 0.989 98.9 1 1

k110715a235 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 14786 15.5 N/A < 0 N/A 0 1

k110715a236 GLP10-01-01-18-133 DAL GW 130L RB 110630 Unknown PFOA 19418 15.5 N/A < 0 N/A 1 1 #VALUE!

k110715a237 GLP10-01-01-18-134 DAL GW 133S RB 110630 Unknown PFOA 34878 15.4 N/A < 0 N/A 1 1 #VALUE!

k110715a238 GLP10-01-01-18-128 DAL GW 140R 0 110622 (dil 1:10) Unknown PFOA 4604487 15.4 N/A 127 N/A 1 50 2.54

k110715a239 GLP10-01-01-18-129 DAL GW 140R DB 110622 (dil 1:10) Unknown PFOA 4720472 15.4 N/A 130 N/A 1 50 2.6

k110715a240 GLP10-01-01-18-130 DAL GW 140R LS 110622 (dil 1:10) Unknown PFOA 5135995 15.4 N/A 141 N/A 1 50 2.82

k110715a241 GLP10-01-01-18-131 DAL GW 140R MS 110622 (dil 1:10) Unknown PFOA 8041247 15.4 N/A 223 N/A 1 50 4.46

k110715a242 GLP10-01-01-18-132 DAL GW 140R HS 110622 (dil 1:10) Unknown PFOA 19828387 15.4 N/A 567 N/A 1 50 11.3

k110715a243 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 21562 15.4 N/A < 0 N/A 1 1

k110715a244 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 8578 15.5 N/A < 0 N/A 0 1

k110715a245 11003-26-9 2.5 ng/mL FC std in Milli Q Water Quality Control PFOA 4397053 15.4 2.5 1 2.41 96.6 0 1

k110715a246 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 13307 15.4 N/A < 0 N/A 1 1

k110715b244 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 48843 15.5 N/A 0.00676 N/A 1 1

k110715b245 11003-26-9 2.5 ng/mL FC std in Milli Q Water Quality Control PFOA 4556666 15.4 2.5 1 2.5 100 1 1

k110715b246 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 21311 15.4 N/A < 0 N/A 1 1

k110715b247 GLP10-01-01-18-135 DAL GW 141R 0 110630 Unknown PFOA 2918997 15.4 N/A 1.59 N/A 1 1 1.59

k110715b248 GLP10-01-01-18-136 DAL GW 141R DB 110630 Unknown PFOA 2876040 15.4 N/A 1.57 N/A 1 1 1.57

k110715b249 GLP10-01-01-18-137 DAL GW 141R LS 110630 Unknown PFOA 4546065 15.4 N/A 2.5 N/A 1 1 2.50

k110715b250 GLP10-01-01-18-138 DAL GW 141R MS 110630 Unknown PFOA 3854963 15.4 N/A 10.6 N/A 1 5 2.12

k110715b251 GLP10-01-01-18-139 DAL GW 141R HS 110630 (dil 1:10) Unknown PFOA 3354229 15.4 N/A 91.6 N/A 1 50 1.83

k110715b252 GLP10-01-01-18-140 DAL GW 142R 0 110622 (dil 1:10) Unknown PFOA 1857178 15.4 N/A 50.1 N/A 1 50 1.00

k110715b253 GLP10-01-01-18-141 DAL GW 142R DB 110622 (dil 1:10) Unknown PFOA 1903540 15.4 N/A 51.4 N/A 1 50 1.03

k110715b254 GLP10-01-01-18-142 DAL GW 142R LS 110622 (dil 1:10) Unknown PFOA 1883286 15.4 N/A 50.9 N/A 1 50 1.02

k110715b255 GLP10-01-01-18-143 DAL GW 142R MS 110622 (dil 1:10) Unknown PFOA 2123043 15.4 N/A 57.5 N/A 1 50 1.15

k110715b256 GLP10-01-01-18-144 DAL GW 142R HS 110622 (dil 1:10) Unknown PFOA 5245686 15.4 N/A 144 N/A 1 50 2.88

k110715b257 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 4532 15.6 N/A < 0 N/A 0 1

k110715b258 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 7817 15.9 N/A < 0 N/A 0 1

k110715b259 11003-26-11 10 ng/mL FC std in Milli Q Water Quality Control PFOA 17345305 15.4 10 1 9.87 98.7 1 1

k110715b260 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 14730 15.7 N/A < 0 N/A 0 1

k110715b261 GLP10-01-01-18-145 DAL GW 143R 0 110622 (dil 1:10) Unknown PFOA 4252765 15.4 N/A 23.3 N/A 1 10 2.33

k110715b262 GLP10-01-01-18-146 DAL GW 143R DB 110622 (dil 1:10) Unknown PFOA 4516701 15.4 N/A 24.8 N/A 1 10 2.48

k110715b263 GLP10-01-01-18-147 DAL GW 143R LS 110622 (dil 1:10) Unknown PFOA 4640869 15.4 N/A 25.5 N/A 1 10 2.55

k110715b264 GLP10-01-01-18-148 DAL GW 143R MS 110622 (dil 1:10) Unknown PFOA 5994380 15.4 N/A 33.1 N/A 1 10 3.31

k110715b265 GLP10-01-01-18-149 DAL GW 143R HS 110622 (dil 1:10) Unknown PFOA 20382201 15.4 N/A 117 N/A 1 10 11.7

k110715b266 GLP10-01-01-18-150 DAL GW 144S 0 110628 (dil 1:10) Unknown PFOA 1927318 15.4 N/A 52.1 N/A 1 50 1.04

k110715b267 GLP10-01-01-18-151 DAL GW 144S DB 110622 (dil 1:10) Unknown PFOA 1816698 15.4 N/A 49 N/A 1 50 0.980

k110715b268 GLP10-01-01-18-152 DAL GW 144S LS 110622 (dil 1:10) Unknown PFOA 1895993 15.4 N/A 51.2 N/A 1 50 1.02

k110715b269 GLP10-01-01-18-153 DAL GW 144S MS 110622 (dil 1:10) Unknown PFOA 2224801 15.4 N/A 60.3 N/A 1 50 1.21

k110715b270 GLP10-01-01-18-154 DAL GW 144S HS 110622 (dil 1:10) Unknown PFOA 5015176 15.4 N/A 138 N/A 1 50 2.76

k110715b271 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 6774 15.5 N/A < 0 N/A 0 1

k110715b272 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 2572 15.5 N/A < 0 N/A 1 1

k110715b273 11003-26-10 5.0 ng/mL FC std in Milli Q Water Quality Control PFOA 9041166 15.4 5 1 5.04 101 1 1

k110715b274 Solvent Blank Milli Q Water TN11-0234 Unknown PFOA 14726 15.5 N/A < 0 N/A 1 1

# Printing Date and Time:

9/2/2011; 8:37 AM

k110715a.xls Regressions Page 1 of 1 

# Regressions

Peak Name: PFOA

No Internal Standard

Q1/Q3 Masses: 413.00/369.00 413.00/219.00 413.00/169.00 Da

Fit Quadratic Weighting 1 / x Iterate No

a0 3.65E+04

a1 1.82E+06

a2 -6.93E+03

Correlation coefficient 0.9998

Use Area

Curve fit criteria r> 0.994987437

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls System Suitability Page 1 of 1 

# System Suitability

Data File Sample ID Area Counts Retention Time

k110715a005 11003-26-9 5241381 15.4

k110715a006 11003-26-9 5181599 15.4

k110715a007 11003-26-9 5092887 15.4

k110715a008 11003-26-9 4943181 15.4

Average 5114762 15.4

%RSD 2.5 0.0

Acceptance criteria: area count RSD <5%, %RSD <2% PFOA

# Printing Date and Time:

9/2/2011; 8:37 AM

k110715a.xls] CCVs Page 1 of 1 CCV Recoveries

**Sample Name Sample ID**  **Sample Comment Spiked** 

**Conc.**

**(ng/mL) Calc.** 

**Conc.**

**(ng/mL) %Rec.** 

k110715a041 11003-26-10 5.0 ng/mL FC std in Milli Q Water 5.00 4.97 99.5

k110715a054 11003-26-9 2.5 ng/mL FC std in Milli Q Water 2.50 2.48 99.2

k110715a069 11003-26-10 5.0 ng/mL FC std in Milli Q Water 5.00 4.92 98.4

k110715a083 11003-26-11 10 ng/mL FC std in Milli Q Water 10.0 9.66 96.6

k110715a096 11003-26-9 2.5 ng/mL FC std in Milli Q Water 2.50 2.51 100

k110715a110 11003-26-10 5.0 ng/mL FC std in Milli Q Water 5.00 4.98 99.7

k110715a124 11003-26-8 1.0 ng/mL FC std in Milli Q Water 1.00 1.05 105

k110715a137 11003-26-9 2.5 ng/mL FC std in Milli Q Water 2.50 2.54 102

k110715a151 11003-26-11 10 ng/mL FC std in Milli Q Water 10.0 9.99 99.9

k110715a165 11003-26-10 5.0 ng/mL FC std in Milli Q Water 5.00 5.01 100

k110715a178 11003-26-8 1.0 ng/mL FC std in Milli Q Water 1.00 1.05 105

k110715a192 11003-26-9 2.5 ng/mL FC std in Milli Q Water 2.50 2.61 104

k110715a206 11003-26-11 10 ng/mL FC std in Milli Q Water 10.0 9.94 99.4

k110715a220 11003-26-10 5.0 ng/mL FC std in Milli Q Water 5.00 4.81 96.1

k110715a234 11003-26-8 1.0 ng/mL FC std in Milli Q Water 1.00 0.989 98.9

k110715a245 11003-26-9 2.5 ng/mL FC std in Milli Q Water 2.50 2.41 96.6

k110715b245 11003-26-9 2.5 ng/mL FC std in Milli Q Water 2.50 2.50 100

k110715b259 11003-26-11 10 ng/mL FC std in Milli Q Water 10.0 9.87 98.7

k110715b273 11003-26-10 5.0 ng/mL FC std in Milli Q Water 5.00 5.04 101 **PFOA**

# Printing Date and Time:

9/2/2011; 8:37 AM

k110715a.xls Method Blanks Page 1 of 1 Method Blanks

**PFOA - traditional**

**Sample Name Sample ID**  **Sample Comment Area Counts** 

k110715a001 Solvent Blank Milli Q Water TN11-0234 428552 warm up blank - not used for LOQ determination

k110715a002 Solvent Blank Milli Q Water TN11-0234 61016 warm up blank - not used for LOQ determination

k110715a004 Solvent Blank Milli Q Water TN11-0234 18073

k110715a009 Solvent Blank Milli Q Water TN11-0234 6656

k110715a010 Solvent Blank Milli Q Water TN11-0234 5330

k110715a026 Solvent Blank Milli Q Water TN11-0234 30048

k110715a027 Solvent Blank Milli Q Water TN11-0234 8455

k110715a028 Solvent Blank Milli Q Water TN11-0234 7526

k110715a029 Solvent Blank Milli Q Water TN11-0234 5416

k110715a039 Solvent Blank Milli Q Water TN11-0234 6779

k110715a040 Solvent Blank Milli Q Water TN11-0234 3416

k110715a042 Solvent Blank Milli Q Water TN11-0234 5900

k110715a052 Solvent Blank Milli Q Water TN11-0234 5294

k110715a053 Solvent Blank Milli Q Water TN11-0234 5588

k110715a055 Solvent Blank Milli Q Water TN11-0234 3733

k110715a056 Solvent Blank Milli Q Water TN11-0234 6154

k110715a067 Solvent Blank Milli Q Water TN11-0234 9964

k110715a068 Solvent Blank Milli Q Water TN11-0234 8526

k110715a070 Solvent Blank Milli Q Water TN11-0234 3608

k110715a081 Solvent Blank Milli Q Water TN11-0234 3547

k110715a082 Solvent Blank Milli Q Water TN11-0234 4296

k110715a084 Solvent Blank Milli Q Water TN11-0234 7816

k110715a094 Solvent Blank Milli Q Water TN11-0234 3033

k110715a095 Solvent Blank Milli Q Water TN11-0234 6444

k110715a097 Solvent Blank Milli Q Water TN11-0234 2847

k110715a108 Solvent Blank Milli Q Water TN11-0234 6908

k110715a109 Solvent Blank Milli Q Water TN11-0234 7830

k110715a111 Solvent Blank Milli Q Water TN11-0234 7396

k110715a122 Solvent Blank Milli Q Water TN11-0234 4509

k110715a123 Solvent Blank Milli Q Water TN11-0234 3247

k110715a125 Solvent Blank Milli Q Water TN11-0234 3896

k110715a135 Solvent Blank Milli Q Water TN11-0234 11090

k110715a136 Solvent Blank Milli Q Water TN11-0234 25177

k110715a138 Solvent Blank Milli Q Water TN11-0234 14220

k110715a149 Solvent Blank Milli Q Water TN11-0234 4243

k110715a150 Solvent Blank Milli Q Water TN11-0234 4567

k110715a152 Solvent Blank Milli Q Water TN11-0234 6473

k110715a163 Solvent Blank Milli Q Water TN11-0234 8337

k110715a164 Solvent Blank Milli Q Water TN11-0234 2637

k110715a166 Solvent Blank Milli Q Water TN11-0234 12628

k110715a176 Solvent Blank Milli Q Water TN11-0234 10303

k110715a177 Solvent Blank Milli Q Water TN11-0234 2943

k110715a179 Solvent Blank Milli Q Water TN11-0234 6033

k110715a190 Solvent Blank Milli Q Water TN11-0234 24247

k110715a191 Solvent Blank Milli Q Water TN11-0234 11381

k110715a193 Solvent Blank Milli Q Water TN11-0234 6875

k110715a204 Solvent Blank Milli Q Water TN11-0234 51098

k110715a205 Solvent Blank Milli Q Water TN11-0234 14265

k110715a207 Solvent Blank Milli Q Water TN11-0234 34849

k110715a218 Solvent Blank Milli Q Water TN11-0234 9819

k110715a219 Solvent Blank Milli Q Water TN11-0234 6440

k110715a221 Solvent Blank Milli Q Water TN11-0234 9608

k110715a232 Solvent Blank Milli Q Water TN11-0234 10934

k110715a233 Solvent Blank Milli Q Water TN11-0234 8493

k110715a235 Solvent Blank Milli Q Water TN11-0234 14786

k110715a243 Solvent Blank Milli Q Water TN11-0234 21562

k110715a244 Solvent Blank Milli Q Water TN11-0234 8578

k110715a246 Solvent Blank Milli Q Water TN11-0234 13307

k110715b244 Solvent Blank Milli Q Water TN11-0234 48843

k110715b246 Solvent Blank Milli Q Water TN11-0234 21311

k110715b257 Solvent Blank Milli Q Water TN11-0234 4532

k110715b258 Solvent Blank Milli Q Water TN11-0234 7817

k110715b260 Solvent Blank Milli Q Water TN11-0234 14730

k110715b271 Solvent Blank Milli Q Water TN11-0234 6774

k110715b272 Solvent Blank Milli Q Water TN11-0234 2572

k110715b274 Solvent Blank Milli Q Water TN11-0234 14726

Average Area Counts of Method Blanks 10601

%RSD 92

Average Area Counts of Method Blanks Multiplied by Two 21201

LOQ Standard area counts 79684

LOQ standard conc., ng/mL 0.0250

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls LCS Page 1 of 1 

# LCS Recoveries

LCS

**Sample**

**Name Sample ID**  **Sample Comment Spiked** 

**Conc.**

**(ng/mL) Calc. Conc.** 

**(ng/mL) %Rec.**  Set average RSD

k110715a030 LCS-110714-1 0.5ppb LCS 0.498 0.510 102

k110715a031 LCS-110714-2 0.5ppb LCS 0.498 0.506 102 105 4.4

k110715a032 LCS-110714-3 0.5ppb LCS 0.498 0.547 110

k110715a033 LCS-110714-4 5ppb LCS 4.98 5.16 104

k110715a034 LCS-110714-5 5ppb LCS 4.98 5.26 106 105 1.1

k110715a035 LCS-110714-6 5ppb LCS 4.98 5.26 106

k110715a036 LCS-110714-7 30ppb LCS 29.9 28.3 94.6

k110715a037 LCS-110714-8 30ppb LCS 29.9 27.5 92.0 93.8 1.7

k110715a038 LCS-110714-9 30ppb LCS 29.9 28.4 94.9

Overall Average **101**

%RSD **6.1**

ECF

**Sample**

**Name Sample ID**  **Sample Comment Spiked** 

**Conc.**

**(ng/mL) Calc. Conc.** 

**(ng/mL) %Rec.**  Set average RSD

k110715a043 LCS-110714-10 0.5ppb LCS ECF 0.498 0.522 105

k110715a044 LCS-110714-11 0.5ppb LCS ECF 0.498 0.470 94.4 99.3 5.4

k110715a045 LCS-110714-12 0.5ppb LCS ECF 0.498 0.491 98.5

k110715a046 LCS-110714-13 5ppb LCS ECF 4.99 4.96 99.3

k110715a047 LCS-110714-14 5ppb LCS ECF 4.99 4.99 100 101 2.5

k110715a048 LCS-110714-15 5ppb LCS ECF 4.99 5.18 104

k110715a049 LCS-110714-16 30ppb LCS ECF 29.9 31.3 105

k110715a050 LCS-110714-17 30ppb LCS ECF 29.9 30.3 101 103 2.0

k110715a051 LCS-110714-18 30ppb LCS ECF 29.9 30.5 102

Overall Average **101**

%RSD **3.4 PFOA** 

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 1 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# GLP10-01-01-18 Rinseate Blanks

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a236 1 GLP10-01-01-18-133 DAL GW 130L RB 110630 <0.0250 NA

k110715a237 1 GLP10-01-01-18-134 DAL GW 133S RB 110630 <0.0250 NA



# DAL GW 137S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a185 1 GLP10-01-01-18-093 DAL GW 137S 0 110624 0.284 NA

k110715a186 1 GLP10-01-01-18-094 DAL GW 137S DB 110624 0.269 NA

k110715a187 1 GLP10-01-01-18-095 DAL GW 137S LS 110624 0.383 NC

k110715a188 1 GLP10-01-01-18-096 DAL GW 137S MS 110624 1.18 91.7

k110715a189 1 GLP10-01-01-18-097 DAL GW 137S HS 110624 9.32 91.8

**Average** 0.277

**Low Field Matrix Spike** 0.0985

**Mid Field Matrix Spike** 0.985

**High Field Matrix Spike** 9.85

**%RPD** 5.4



# DAL GW 137L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a194 1 GLP10-01-01-18-098 DAL GW 137L 0 110624 0.372 NA

k110715a195 1 GLP10-01-01-18-099 DAL GW 137L DB 110624 0.381 NA

k110715a196 1 GLP10-01-01-18-100 DAL GW 137L LS 110624 0.477 NC

k110715a197 1 GLP10-01-01-18-101 DAL GW 137L MS 110624 1.35 98.8

k110715a198 1 GLP10-01-01-18-102 DAL GW 137L HS 110624 9.98 97.5

**Average** 0.377

**Low Field Matrix Spike** 0.0985

**Mid Field Matrix Spike** 0.985

**High Field Matrix Spike** 9.85

**%RPD** 2.4



# DAL GW 138L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a208 1 GLP10-01-01-18-108 DAL GW 138L 0 110630 0.891 NA

k110715a209 1 GLP10-01-01-18-109 DAL GW 138L DB 110630 0.894 NA

k110715a210 1 GLP10-01-01-18-110 DAL GW 138L LS 110630 0.974 NC

k110715a211 1 GLP10-01-01-18-111 DAL GW 138L MS 110630 1.69 81.0

k110715a212 1 GLP10-01-01-18-112 DAL GW 138L HS 110630 9.14 83.7

**Average** 0.893

**Low Field Matrix Spike** 0.0985

**Mid Field Matrix Spike** 0.985

**High Field Matrix Spike** 9.85

**%RPD** 0.34



# DAL GW 138R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a199 10 GLP10-01-01-18-103 DAL GW 138R 0 110630 (dil 1:10) 294 NA

k110715a200 10 GLP10-01-01-18-104 DAL GW 138R DB 110630 (dil 1:10) 288 NA

k110715a201 10 GLP10-01-01-18-105 DAL GW 138R LS 110630 (dil 1:10) 292 NC

k110715a202 10 GLP10-01-01-18-106 DAL GW 138R MS 110630 (dil 1:10) 370 NC

k110715a203 10 GLP10-01-01-18-107 DAL GW 138R HS 110630 (dil 1:10) 709 84.7

**Average** 291

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 2.1



# DAL GW 134S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a139 5 GLP10-01-01-18-059 DAL GW 134S 0 110628 9.67 NA

k110715a140 5 GLP10-01-01-18-060 DAL GW 134S DB 110628 9.92 NA

k110715a141 5 GLP10-01-01-18-061 DAL GW 134S LS 110628 9.60 NC

k110715a142 5 GLP10-01-01-18-062 DAL GW 134S MS 110628 10.7 NC

k110715a143 5 GLP10-01-01-18-063 DAL GW 134S HS 110628 19.6 99.5

**Average** 9.80

**Low Field Matrix Spike** 0.0985

**Mid Field Matrix Spike** 0.985

**High Field Matrix Spike** 9.85

**%RPD** 2.6 

# PFOA **PFOA**

**PFOA**

**PFOA**

**PFOA**

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 2 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# DAL GW 130L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a076 10 GLP10-01-01-18-016 DAL GW 130L 0 110630 (dil 1:10) 66.8 NA

k110715a077 10 GLP10-01-01-18-017 DAL GW 130L DB 110630 (dil 1:10) 63.3 NA

k110715a078 10 GLP10-01-01-18-018 DAL GW 130L LS 110630 (dil 1:10) 68.7 NC

k110715a079 10 GLP10-01-01-18-019 DAL GW 130L MS 110630 (dil 1:10) 74.8 NC

k110715a080 10 GLP10-01-01-18-020 DAL GW 130L HS 110630 (dil 1:10) 158 94.2

**Average** 65.1

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 5.4



# DAL GW 131S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a089 50 GLP10-01-01-18-025 DAL GW 131S 0 110622 (dil 1:10) 26.7 NA

k110715a090 50 GLP10-01-01-18-026 DAL GW 131S DB 110622 (dil 1:10) 25.7 NA

k110715a091 50 GLP10-01-01-18-027 DAL GW 131S LS 110622 (dil 1:10) 26.6 NC

k110715a092 50 GLP10-01-01-18-028 DAL GW 131S MS 110622 (dil 1:10) 36.0 NC

k110715a093 50 GLP10-01-01-18-029 DAL GW 131S HS 110622 (dil 1:10) 115 90.0

**Average** 26.2

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 3.8



# DAL GW 131L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a098 10 GLP10-01-01-18-030 DAL GW 131L 0 110622 (dil 1:10) 93.9 NA

k110715a099 10 GLP10-01-01-18-031 DAL GW 131L DB 110622 (dil 1:10) 96.2 NA

k110715a100 10 GLP10-01-01-18-032 DAL GW 131L LS 110622 (dil 1:10) 97.3 NC

k110715a101 10 GLP10-01-01-18-033 DAL GW 131L MS 110622 (dil 1:10) 107 NC

k110715a102 10 GLP10-01-01-18-034 DAL GW 131L HS 110622 (dil 1:10) 185 91.1

**Average** 95.1

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 2.4



# DAL GW 133R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a117 10 GLP10-01-01-18-045 DAL GW 133R 0 110630 (dil 1:10) 108 NA

k110715a118 10 GLP10-01-01-18-046 DAL GW 133R DB 110630 (dil 1:10) 108 NA

k110715a119 10 GLP10-01-01-18-047 DAL GW 133R LS 110630 (dil 1:10) 96.6 NC

k110715a120 10 GLP10-01-01-18-048 DAL GW 133R MS 110630 (dil 1:10) 112 NC

k110715a121 10 GLP10-01-01-18-049 DAL GW 133R HS 110630 (dil 1:10) 190 83.1

**Average** 108

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 0.0 

# PFOA

**PFOA PFOA** 

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 3 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# DAL GW 133S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a112 50 GLP10-01-01-18-040 DAL GW 133S 0 110630 (dil 1:10) 311 NA

k110715a113 50 GLP10-01-01-18-041 DAL GW 133S DB 110630 (dil 1:10) 314 NA

k110715a114 50 GLP10-01-01-18-042 DAL GW 133S LS 110630 (dil 1:10) 316 NC

k110715a115 50 GLP10-01-01-18-043 DAL GW 133S MS 110630 (dil 1:10) 397 NC

k110715a116 50 GLP10-01-01-18-044 DAL GW 133S HS 110630 (dil 1:10) 768 92.3

**Average** 313

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 1.0



# DAL GW 133L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a103 50 GLP10-01-01-18-035 DAL GW 133L 0 110630 (dil 1:10) 230 NA

k110715a104 50 GLP10-01-01-18-036 DAL GW 133L DB 110630 (dil 1:10) 226 NA

k110715a105 50 GLP10-01-01-18-037 DAL GW 133L LS 110630 (dil 1:10) 265 NC

k110715a106 50 GLP10-01-01-18-038 DAL GW 133L MS 110630 (dil 1:10) 417 NC

k110715a107 50 GLP10-01-01-18-039 DAL GW 133L HS 110630 (dil 1:10) 708 97.3

**Average** 228

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 1.8



# DAL GW 134L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a130 50 GLP10-01-01-18-054 DAL GW 134L 0 110628 (dil 1:10) 527 NA

k110715a131 50 GLP10-01-01-18-055 DAL GW 134L DB 110628 (dil 1:10) 592 NA

k110715a132 50 GLP10-01-01-18-056 DAL GW 134L LS 110628 (dil 1:10) 602 NC

k110715a133 50 GLP10-01-01-18-057 DAL GW 134L MS 110628 (dil 1:10) 677 NC

k110715a134 50 GLP10-01-01-18-058 DAL GW 134L HS 110628 (dil 1:10) 1010 91.3

**Average** 560

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 12



# DAL GW 136S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a180 10 GLP10-01-01-18-088 DAL GW 136S 0 110630 (dil 1:10) 131 NA

k110715a181 10 GLP10-01-01-18-089 DAL GW 136S DB 110630 (dil 1:10) 131 NA

k110715a182 10 GLP10-01-01-18-090 DAL GW 136S LS 110630 (dil 1:10) 132 NC

k110715a183 10 GLP10-01-01-18-091 DAL GW 136S MS 110630 (dil 1:10) 136 NC

k110715a184 10 GLP10-01-01-18-092 DAL GW 136S HS 110630 (dil 1:10) 217 87.1

**Average** 131

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 0.0



# DAL GW 136L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a171 50 GLP10-01-01-18-084 DAL GW 136L 0 110630 (dil 1:10) 79.7 NA

k110715a172 50 GLP10-01-01-18-085 DAL GW 136L DB 110630 (dil 1:10) 78.3 NA

k110715a173 50 GLP10-01-01-18-086 DAL GW 136L LS 110630 (dil 1:10) 79.6 NC

k110715a174 50 GLP10-01-01-18-155 DAL GW 136L MS 110630 (dil 1:10) 89.1 NC

k110715a175 50 GLP10-01-01-18-087 DAL GW 136L HS 110630 (dil 1:10) 170 92.2

**Average** 79.0

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 1.8 

# PFOA **PFOA**

**PFOA PFOA** 

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 4 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# DAL GW 138S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a213 50 GLP10-01-01-18-113 DAL GW 138S 0 110630 (dil 1:10) 155 NA

k110715a214 50 GLP10-01-01-18-114 DAL GW 138S DB 110630 (dil 1:10) 153 NA

k110715a215 50 GLP10-01-01-18-115 DAL GW 138S LS 110630 (dil 1:10) 161 NC

k110715a216 50 GLP10-01-01-18-116 DAL GW 138S MS 110630 (dil 1:10) 231 78.0

k110715a217 50 GLP10-01-01-18-117 DAL GW 138S HS 110630 (dil 1:10) 610 92.4

**Average** 154

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 1.3



# DAL GW CW26C

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a222 50 GLP10-01-01-18-118 DAL GW CW26C 0 110622 (dil 1:10) 427 NA

k110715a223 50 GLP10-01-01-18-119 DAL GW CW26C DB 110622 (dil 1:10) 425 NA

k110715a224 50 GLP10-01-01-18-120 DAL GW CW26C LS 110622 (dil 1:10) 436 NC

k110715a225 50 GLP10-01-01-18-121 DAL GW CW26C MS 110622 (dil 1:10) 502 NC

k110715a226 50 GLP10-01-01-18-122 DAL GW CW26C HS 110622 (dil 1:10) 841 84.1

**Average** 426

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 0.47



# DAL GW CW26L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a227 50 GLP10-01-01-18-123 DAL GW CW26L 0 110622 (dil 1:10) 645 NA

k110715a228 50 GLP10-01-01-18-124 DAL GW CW26L DB 110622 (dil 1:10) 644 NA

k110715a229 50 GLP10-01-01-18-125 DAL GW CW26L LS 110622 (dil 1:10) 667 NC

k110715a230 50 GLP10-01-01-18-126 DAL GW CW26L MS 110622 (dil 1:10) 723 NC

k110715a231 50 GLP10-01-01-18-127 DAL GW CW26L HS 110622 (dil 1:10) 1060 84.2

**Average** 645

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 0.16



# DAL GW 140R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a238 50 GLP10-01-01-18-128 DAL GW 140R 0 110622 (dil 1:10) 127 NA

k110715a239 50 GLP10-01-01-18-129 DAL GW 140R DB 110622 (dil 1:10) 130 NA

k110715a240 50 GLP10-01-01-18-130 DAL GW 140R LS 110622 (dil 1:10) 141 NC

k110715a241 50 GLP10-01-01-18-131 DAL GW 140R MS 110622 (dil 1:10) 223 95.7

k110715a242 50 GLP10-01-01-18-132 DAL GW 140R HS 110622 (dil 1:10) 567 88.9

**Average** 129

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 2.3



# DAL GW 141R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715b247 1 GLP10-01-01-18-135 DAL GW 141R 0 110630 1.59 NA

k110715b248 1 GLP10-01-01-18-136 DAL GW 141R DB 110630 1.57 NA

k110715b249 1 GLP10-01-01-18-137 DAL GW 141R LS 110630 2.50 93.4

k110715b250 5 GLP10-01-01-18-138 DAL GW 141R MS 110630 10.6 91.6

k110715b251 50 GLP10-01-01-18-139 DAL GW 141R HS 110630 (dil 1:10) 91.6 91.2

**Average** 1.58

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 1.3 

# PFOA

**PFOA**

**PFOA**

**PFOA**

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 5 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# DAL GW 142R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715b252 50 GLP10-01-01-18-140 DAL GW 142R 0 110622 (dil 1:10) 50.1 NA

k110715b253 50 GLP10-01-01-18-141 DAL GW 142R DB 110622 (dil 1:10) 51.4 NA

k110715b254 50 GLP10-01-01-18-142 DAL GW 142R LS 110622 (dil 1:10) 50.9 NC

k110715b255 50 GLP10-01-01-18-143 DAL GW 142R MS 110622 (dil 1:10) 57.5 NC

k110715b256 50 GLP10-01-01-18-144 DAL GW 142R HS 110622 (dil 1:10) 144 94.5

**Average** 50.8

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 2.6



# DAL GW 143R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715b261 10 GLP10-01-01-18-145 DAL GW 143R 0 110622 (dil 1:10) 23.3 NA

k110715b262 10 GLP10-01-01-18-146 DAL GW 143R DB 110622 (dil 1:10) 24.8 NA

k110715b263 10 GLP10-01-01-18-147 DAL GW 143R LS 110622 (dil 1:10) 25.5 NC

k110715b264 10 GLP10-01-01-18-148 DAL GW 143R MS 110622 (dil 1:10) 33.1 NC

k110715b265 10 GLP10-01-01-18-149 DAL GW 143R HS 110622 (dil 1:10) 117 94.2

**Average** 24.1

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 6.2



# DAL GW 144S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715b266 50 GLP10-01-01-18-150 DAL GW 144S 0 110628 (dil 1:10) 52.1 NA

k110715b267 50 GLP10-01-01-18-151 DAL GW 144S DB 110622 (dil 1:10) 49.0 NA

k110715b268 50 GLP10-01-01-18-152 DAL GW 144S LS 110622 (dil 1:10) 51.2 NC

k110715b269 50 GLP10-01-01-18-153 DAL GW 144S MS 110622 (dil 1:10) 60.3 NC

k110715b270 50 GLP10-01-01-18-154 DAL GW 144S HS 110622 (dil 1:10) 138 88.6

Samples GLP10-01-01-18-151 thru 154 were incorrectly named in the sequence (incorrect date of sampling). Final report will reflect correct description.

**Average** 50.6

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 6.1



# DAL GW 130R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a062 100 GLP10-01-01-18-006 DAL GW 130R 0 110630 (dil 1:100) 837 NA

k110715a063 100 GLP10-01-01-18-007 DAL GW 130R DB 110630 (dil 1:100) 823 NA

k110715a064 100 GLP10-01-01-18-008 DAL GW 130R LS 110630 (dil 1:100) 833 NC

k110715a065 100 GLP10-01-01-18-009 DAL GW 130R MS 110630 (dil 1:100) 921 NC

k110715a066 100 GLP10-01-01-18-010 DAL GW 130R HS 110630 (dil 1:100) 1280 91.2

**Average** 830

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 1.7



# DAL GW 130S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a071 10 GLP10-01-01-18-011 DAL GW 130S 0 110630 (dil 1:10) 180 NA

k110715a072 10 GLP10-01-01-18-012 DAL GW 130S 0 110630 (dil 1:10) 178 NA

k110715a073 100 GLP10-01-01-18-013 DAL GW 130S LS 110630 (dil 1:100) 181 NC

k110715a074 100 GLP10-01-01-18-014 DAL GW 130S MS 110630 (dil 1:100) 265 87.1

k110715a075 100 GLP10-01-01-18-015 DAL GW 130S HS 110630 (dil 1:100) 708 107

**Average** 179

**Low Field Matrix Spike** 9.85

**Mid Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

**%RPD** 1.1 

# PFOA

**PFOA PFOA**  **PFOA**

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 6 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# DAL GW 131R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a085 100 GLP10-01-01-18-021 DAL GW 131R 0 110622 (dil 1:100) 2310 NA

k110715a086 100 GLP10-01-01-18-022 DAL GW 131R DB 110622 (dil 1:100) 2550 NA

k110715a087 100 GLP10-01-01-18-023 DAL GW 131R LS 110622 (dil 1:100) 2490 NC

k110715a088 100 GLP10-01-01-18-024 DAL GW 131R HS 110622 (dil 1:100) 4060 83.3

**Average** 2430

**Low Field Matrix Spike** 98.7

**High Field Matrix Spike** 1956

**%RPD** 9.9



# DAL GW 134R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a126 100 GLP10-01-01-18-050 DAL GW 134R 0 110628 (dil 1:100) 1790 NA

k110715a127 100 GLP10-01-01-18-051 DAL GW 134R DB 110628 (dil 1:100) 1800 NA

k110715a128 100 GLP10-01-01-18-052 DAL GW 134R LS 110628 (dil 1:100) 1870 NC

k110715a129 100 GLP10-01-01-18-053 DAL GW 134R HS 110628 (dil 1:100) 3610 92.8

**Average** 1795

**Low Field Matrix Spike** 98.7

**High Field Matrix Spike** 1956

**%RPD** 0.56



# DAL GW 135R

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a167 100 GLP10-01-01-18-079 DAL GW 135R 0 110628 (dil 1:100) 3570 NA

k110715a168 100 GLP10-01-01-18-080 DAL GW 135R DB 110628 (dil 1:100) 3460 NA

k110715a169 100 GLP10-01-01-18-081 DAL GW 135R LS 110628 (dil 1:100) 3600 NC

k110715a170 100 GLP10-01-01-18-083 DAL GW 135R HS 110628 (dil 1:100) 5250 88.7

**Average** 3515

**Low Field Matrix Spike** 98.7

**High Field Matrix Spike** 1956

**%RPD** 3.1



# DAL GW 135S

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a153 5 GLP10-01-01-18-069 DAL GW 135S 0 110628 18.9 NA

k110715a154 5 GLP10-01-01-18-070 DAL GW 135S DB 110628 20.3 NA

k110715a155 5 GLP10-01-01-18-071 DAL GW 135S LS 110628 24.2 NC

k110715a156 5 GLP10-01-01-18-072 DAL GW 135S MS 110628 20.6 NC

k110715a157 5 GLP10-01-01-18-073 DAL GW 135S HS 110628 39.9 206

**Average** 19.6

**Low Field Matrix Spike** 0.0985

**Mid Field Matrix Spike** 0.985

**High Field Matrix Spike** 9.85

**%RPD** 7.1



# DAL GW 135L

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a158 10 GLP10-01-01-18-074 DAL GW 135L 0 110628 (dil 1:10) 283 NA

k110715a159 10 GLP10-01-01-18-075 DAL GW 135L DB 110628 (dil 1:10) 272 NA

k110715a160 10 GLP10-01-01-18-076 DAL GW 135L LS 110628 (dil 1:10) 278 NC

k110715a161 10 GLP10-01-01-18-077 DAL GW 135L MS 110628 (dil 1:10) 289 NC

k110715a162 10 GLP10-01-01-18-078 DAL GW 135L HS 110628 (dil 1:10) 365 NC

**Average** 278

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**High Field Matrix Spike** 98.7

**%RPD** 4.0 

# PFOA **PFOA**

**PFOA**

**PFOA**

**PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls Sample Data wQC Page 7 of 7 

# Sample Result with QC

**NC = Not Calculated; Endogenous sample greater than 2x spike level**



# Trip Blank 1

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a144 1 GLP10-01-01-18-064 Trip Blank Set 1 Sample <0.0250 NA

k110715a145 1 GLP10-01-01-18-065 Trip Blank Set 1 LS 0.981 99.6

k110715a146 1 GLP10-01-01-18-066 Trip Blank Set 1 MS 10.0 102

k110715a147 5 GLP10-01-01-18-067 Trip Blank Set 1 MHS 95.5 96.8

k110715a148 100 GLP10-01-01-18-068 Trip Blank Set 1 HS (dil 1:100) 493 99.9

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**Mid High Field Matrix Spike** 98.7

**High Field Matrix Spike** 494



# Trip Blank 2

Datafile Dilution **3M LIMS ID Sample Description**  **Conc.**

**(ng/mL) FMS** 

**%Recovery**

k110715a057 1 GLP10-01-01-18-001 Trip Blank Set 2 Sample <0.0250 NA

k110715a058 1 GLP10-01-01-18-002 Trip Blank Set 2 LS 0.954 96.9

k110715a059 1 GLP10-01-01-18-003 Trip Blank Set 2 MS 9.29 94.3

k110715a060 5 GLP10-01-01-18-004 Trip Blank Set 2 MHS 89.7 90.9

k110715a061 100 GLP10-01-01-18-005 Trip Blank Set 2 HS (dil 1:100) 443 89.8

**Low Field Matrix Spike** 0.985

**Mid Field Matrix Spike** 9.85

**Mid High Field Matrix Spike** 98.7

**High Field Matrix Spike** 494

LOQ 0.0250

LOQ*10 0.250

LOQ*50 1.25

LOQ*100 2.50 

# PFOA **PFOA**

# Printing Date and Time

9/2/2011; 8:37 AM

k110715a.xls FMS Page 1 of 1 **Concentration (ug/mL)**

Stock ID PFOA

10 006-141 1.97

10 006-140 98.7

10 006-139 489

Final Spike Concentration (ng/mL)

PFOA Stock ID 1 Spike Volume

(uL) Final Volume

(mL)

Low FMS 0.0985 10 006-141 10 200

Mid FMS 0.985 10 006-141 100 200

High FMS 9.85 10 006-141 1000 200

Low FMS 0.985 10 006-141 100 200

Mid FMS 9.85 10 006-141 1000 200

High FMS 98.7 10 006-140 200 200

Low FMS 9.85 10 006-141 1000 200

Mid FMS 98.7 10 006-140 200 200

High FMS 494 10 006-140 1000 200

Low FMS 98.7 10 006-140 200 200

High FMS 1956 10 006-139 800 200

Trip Blanks Low FMS 0.985 10 006-141 100 200

Mid FMS 9.85 10 006-141 1000 200

Mid High FMS 98.7 10 006-140 200 200

High FMS 494 10 006-140 1000 200

Final Spike Concentration (ng/mL) = Volume Spike (uL)*Spike Solution Concentratin (ug/mL)/Final Volume (mL) 134S, 135S, 136R, 137R, 137S, 137L

and 138L

130L, 131S, 131L, 133R, 135L, 136S,

136L, 141R, 142R, 143R, 144R[144S]

130R, 130S, 133S, 133L, 134L, 138R,

138S, CW26C, CW26L and 140R

131R, 134R and 135RSample Name: "k110715a001" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 1Sample Type: UnknownConcentration: N/ACalculated Conc: 0.215 ng/mLAcq. Date: 7/15/2011Acq. Time: 3:46:38 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 428552 countsHeight: 3.95e+004 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02000.04000.06000.08000.01.0e41.2e41.4e41.6e41.8e42.0e42.2e42.4e42.6e42.8e43.0e43.2e43.4e43.6e43.8e44.0e44.2e44.4e44.6e44.8e45.0e45.2e4

Intensity, cps15.9215.4215.2416.7415.1417.1715.0114.7817.4714.4614.3613.3317.575.0013.0118.1012.8110.40Sample Name: "k110715a002" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 2Sample Type: UnknownConcentration: N/ACalculated Conc: 0.0134 ng/mLAcq. Date: 7/15/2011Acq. Time: 4:08:31 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 61016 countsHeight: 1.09e+004 cpsStart Time: 15.3 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e41.4e4

Intensity, cps15.4315.4516.5614.8916.6816.7817.1014.5917.2914.2719.2713.815.0118.2413.4013.1411.7510.439.188.257.03Sample Name: "k110715a003" Sample ID: "11003-26-8" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "1.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 3Sample Type: UnknownConcentration: N/ACalculated Conc: 1.23 ng/mLAcq. Date: 7/15/2011Acq. Time: 4:29:35 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2275254 countsHeight: 3.15e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e5

Intensity, cps15.43Sample Name: "k110715a004" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 4Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/15/2011Acq. Time: 4:50:43 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 18073 countsHeight: 5.03e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e41.9e42.0e4

Intensity, cps16.6916.6617.1216.4917.2215.8617.4215.3817.5814.9214.5418.1914.3314.1412.6910.0410.469.04Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 1 of 70Printing Time: 12:19:02 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a005" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 5Sample Type: UnknownConcentration: N/ACalculated Conc: 2.89 ng/mLAcq. Date: 7/15/2011Acq. Time: 5:11:49 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 5241381 countsHeight: 7.29e+005 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e5

Intensity, cps15.44Sample Name: "k110715a006" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 6Sample Type: UnknownConcentration: N/ACalculated Conc: 2.85 ng/mLAcq. Date: 7/15/2011Acq. Time: 5:32:59 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 5181599 countsHeight: 7.13e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e5

Intensity, cps15.42Sample Name: "k110715a007" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 7Sample Type: UnknownConcentration: N/ACalculated Conc: 2.80 ng/mLAcq. Date: 7/15/2011Acq. Time: 5:54:05 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 5092887 countsHeight: 7.09e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e5

Intensity, cps15.44Sample Name: "k110715a008" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 8Sample Type: UnknownConcentration: N/ACalculated Conc: 2.72 ng/mLAcq. Date: 7/15/2011Acq. Time: 6:15:12 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 4943181 countsHeight: 6.70e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 2 of 70Printing Time: 12:19:02 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a009" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 9Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/15/2011Acq. Time: 6:36:17 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.7 minArea: 6656 countsHeight: 5.50e+003 cpsStart Time: 15.7 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e4

Intensity, cps16.7116.0115.4517.4517.6015.3114.9019.2814.6318.4314.4314.1213.4113.3211.925.019.328.987.986.886.03Sample Name: "k110715a010" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 10Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/15/2011Acq. Time: 6:57:23 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.7 minArea: 5330 countsHeight: 5.16e+003 cpsStart Time: 15.7 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e41.05e41.10e41.15e41.20e4

Intensity, cps16.6716.4917.1517.4716.1715.8515.6918.2914.7214.3313.7313.0012.8311.575.0110.248.677.696.56Sample Name: "k110715a011" Sample ID: "11003-26-1" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.025 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 11Sample Type: StandardConcentration: 0.0250 ng/mLCalculated Conc: 0.0237 ng/mLAcq. Date: 7/15/2011Acq. Time: 7:18:27 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 79684 countsHeight: 1.29e+004 cpsStart Time: 15.4 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps15.4716.6417.1015.2515.0114.8318.2314.3614.1413.3511.2410.799.547.176.47Sample Name: "k110715a012" Sample ID: "11003-26-2" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.03 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 12Sample Type: StandardConcentration: 0.0300 ng/mLCalculated Conc: 0.0266 ng/mLAcq. Date: 7/15/2011Acq. Time: 7:39:34 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 84914 countsHeight: 1.30e+004 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps15.4716.70 17.4017.4915.5615.1214.8519.2714.6014.4614.1613.8313.1711.651.3910.358.94Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 3 of 70Printing Time: 12:19:02 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a013" Sample ID: "11003-26-3" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.04 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 13Sample Type: StandardConcentration: 0.0400 ng/mLCalculated Conc: 0.0391 ng/mLAcq. Date: 7/15/2011Acq. Time: 8:00:43 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 50Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 107795 countsHeight: 1.61e+004 cpsStart Time: 15.3 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e4

Intensity, cps15.4317.5017.4314.9814.6818.2914.2614.0813.3610.9410.409.30Sample Name: "k110715a014" Sample ID: "11003-26-4" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.05 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 14Sample Type: StandardConcentration: 0.0500 ng/mLCalculated Conc: 0.0452 ng/mLAcq. Date: 7/15/2011Acq. Time: 8:21:50 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 118906 countsHeight: 1.78e+004 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e41.9e42.0e4

Intensity, cps15.4517.3816.1415.5415.0514.8518.1214.5314.3213.5812.7511.589.537.569.18Sample Name: "k110715a015" Sample ID: "11003-26-5" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.1 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 15Sample Type: StandardConcentration: 0.100 ng/mLCalculated Conc: 0.102 ng/mLAcq. Date: 7/15/2011Acq. Time: 8:42:56 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 222109 countsHeight: 3.19e+004 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02000.04000.06000.08000.01.0e41.2e41.4e41.6e41.8e42.0e42.2e42.4e42.6e42.8e43.0e43.2e43.4e4

Intensity, cps15.4515.5316.5517.4614.9719.181.4014.4413.49Sample Name: "k110715a016" Sample ID: "11003-26-6" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.25 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 16Sample Type: StandardConcentration: 0.250 ng/mLCalculated Conc: 0.263 ng/mLAcq. Date: 7/15/2011Acq. Time: 9:04:00 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 516292 countsHeight: 7.34e+004 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e47.0e47.5e4

Intensity, cps15.4415.3616.4616.7915.1919.22Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 4 of 70Printing Time: 12:19:02 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a017" Sample ID: "11003-26-7" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 17Sample Type: StandardConcentration: 0.500 ng/mLCalculated Conc: 0.520 ng/mLAcq. Date: 7/15/2011Acq. Time: 9:25:04 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 981883 countsHeight: 1.35e+005 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e47.0e47.5e48.0e48.5e49.0e49.5e41.0e51.1e51.1e51.2e51.2e51.3e51.3e51.4e5

Intensity, cps15.4417.5816.9815.26Sample Name: "k110715a018" Sample ID: "11003-26-8" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "1.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 18Sample Type: StandardConcentration: 1.00 ng/mLCalculated Conc: 1.10 ng/mLAcq. Date: 7/15/2011Acq. Time: 9:46:11 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 2026711 countsHeight: 2.83e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e5

Intensity, cps15.45Sample Name: "k110715a019" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 19Sample Type: StandardConcentration: 2.50 ng/mLCalculated Conc: 2.63 ng/mLAcq. Date: 7/15/2011Acq. Time: 10:07:17 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 4777305 countsHeight: 6.71e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.46Sample Name: "k110715a020" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 20Sample Type: StandardConcentration: 5.00 ng/mLCalculated Conc: 5.14 ng/mLAcq. Date: 7/15/2011Acq. Time: 10:28:22 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 9217151 countsHeight: 1.21e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e6

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 5 of 70Printing Time: 12:19:02 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a021" Sample ID: "11003-26-11" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "10 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 21Sample Type: StandardConcentration: 10.0 ng/mLCalculated Conc: 10.1 ng/mLAcq. Date: 7/15/2011Acq. Time: 10:49:29 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 17757632 countsHeight: 2.39e+006 cpsStart Time: 15.3 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e6

Intensity, cps15.44Sample Name: "k110715a022" Sample ID: "11003-26-12" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "25 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 22Sample Type: StandardConcentration: 25.0 ng/mLCalculated Conc: 25.3 ng/mLAcq. Date: 7/15/2011Acq. Time: 11:10:36 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 41779501 countsHeight: 5.39e+006 cpsStart Time: 15.3 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.46Sample Name: "k110715a023" Sample ID: "11003-26-13" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "50 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 23Sample Type: StandardConcentration: 50.0 ng/mLCalculated Conc: 48.5 ng/mLAcq. Date: 7/15/2011Acq. Time: 11:31:40 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 72084171 countsHeight: 8.62e+006 cpsStart Time: 15.3 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e66.0e66.5e67.0e67.5e68.0e68.5e6

Intensity, cps15.45Sample Name: "k110715a024" Sample ID: "11003-26-14" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "75 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 24Sample Type: StandardConcentration: 75.0 ng/mLCalculated Conc: 73.3 ng/mLAcq. Date: 7/15/2011Acq. Time: 11:52:46 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 1Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 96394636 countsHeight: 1.08e+007 cpsStart Time: 15.3 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e51.00e61.50e62.00e62.50e63.00e63.50e64.00e64.50e65.00e65.50e66.00e66.50e67.00e67.50e68.00e68.50e69.00e69.50e61.00e71.05e7

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 6 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a025" Sample ID: "11003-26-15" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "100 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 25Sample Type: StandardConcentration: 100. ng/mLCalculated Conc: 104. ng/mLAcq. Date: 7/16/2011Acq. Time: 12:13:54 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 114703888 countsHeight: 1.22e+007 cpsStart Time: 15.3 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e51.00e61.50e62.00e62.50e63.00e63.50e64.00e64.50e65.00e65.50e66.00e66.50e67.00e67.50e68.00e68.50e69.00e69.50e61.00e71.05e71.10e71.15e71.20e7

Intensity, cps15.45Sample Name: "k110715a026" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 26Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 12:34:59 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 30048 countsHeight: 6.77e+003 cpsStart Time: 15.4 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e41.05e41.10e41.15e41.20e41.25e4

Intensity, cps16.9816.5417.5516.2115.5015.2814.9719.2614.6814.4014.0813.701.3612.0310.959.468.161.596.780.35 3.59Sample Name: "k110715a027" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 27Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 12:56:04 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 8455 countsHeight: 7.19e+003 cpsStart Time: 15.5 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e41.05e41.10e41.15e41.20e4

Intensity, cps16.8317.4716.6816.4715.5317.6115.3918.3314.9119.2014.3514.1513.7713.2411.215.019.669.227.09Sample Name: "k110715a028" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 28Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 1:17:08 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 7526 countsHeight: 4.77e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e4

Intensity, cps17.4816.7516.4816.2015.8315.4519.2114.7314.5314.3013.6612.9011.739.899.121.467.886.84Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 7 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a029" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 29Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 1:38:13 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 5416 countsHeight: 4.53e+003 cpsStart Time: 15.5 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e41.05e41.10e41.15e41.20e4

Intensity, cps16.8417.4917.5616.5516.4716.0015.8414.8518.2314.8019.2914.5914.0514.195.0113.6612.4810.369.698.757.415.99Sample Name: "k110715a030" Sample ID: "LCS-110714-1" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5ppb LCS" Annotation: ""Sample Index: 30Sample Type: QCConcentration: 0.498 ng/mLCalculated Conc: 0.510 ng/mLAcq. Date: 7/16/2011Acq. Time: 1:59:18 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 963879 countsHeight: 1.38e+005 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e5

Intensity, cps15.4616.6516.97Sample Name: "k110715a031" Sample ID: "LCS-110714-2" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5ppb LCS" Annotation: ""Sample Index: 31Sample Type: QCConcentration: 0.498 ng/mLCalculated Conc: 0.506 ng/mLAcq. Date: 7/16/2011Acq. Time: 2:20:26 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 956199 countsHeight: 1.36e+005 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e47.0e47.5e48.0e48.5e49.0e49.5e41.0e51.1e51.1e51.2e51.2e51.3e51.3e51.4e5

Intensity, cps15.4516.6517.47Sample Name: "k110715a032" Sample ID: "LCS-110714-3" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5ppb LCS" Annotation: ""Sample Index: 32Sample Type: QCConcentration: 0.498 ng/mLCalculated Conc: 0.547 ng/mLAcq. Date: 7/16/2011Acq. Time: 2:41:32 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1031950 countsHeight: 1.42e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e5

Intensity, cps15.4416.9217.6015.28Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 8 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a033" Sample ID: "LCS-110714-4" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5ppb LCS" Annotation: ""Sample Index: 33Sample Type: QCConcentration: 4.98 ng/mLCalculated Conc: 5.16 ng/mLAcq. Date: 7/16/2011Acq. Time: 3:02:38 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 9252077 countsHeight: 1.27e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e61.25e6

Intensity, cps15.45Sample Name: "k110715a034" Sample ID: "LCS-110714-5" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5ppb LCS" Annotation: ""Sample Index: 34Sample Type: QCConcentration: 4.98 ng/mLCalculated Conc: 5.26 ng/mLAcq. Date: 7/16/2011Acq. Time: 3:23:45 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 9439709 countsHeight: 1.28e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e61.25e6

Intensity, cps15.45Sample Name: "k110715a035" Sample ID: "LCS-110714-6" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5ppb LCS" Annotation: ""Sample Index: 35Sample Type: QCConcentration: 4.98 ng/mLCalculated Conc: 5.26 ng/mLAcq. Date: 7/16/2011Acq. Time: 3:44:54 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 9440299 countsHeight: 1.33e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e6

Intensity, cps15.45Sample Name: "k110715a036" Sample ID: "LCS-110714-7" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "30ppb LCS" Annotation: ""Sample Index: 36Sample Type: QCConcentration: 29.9 ng/mLCalculated Conc: 28.3 ng/mLAcq. Date: 7/16/2011Acq. Time: 4:06:03 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 46053927 countsHeight: 5.84e+006 cpsStart Time: 15.3 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e6

Intensity, cps15.47Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 9 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a037" Sample ID: "LCS-110714-8" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "30ppb LCS" Annotation: ""Sample Index: 37Sample Type: QCConcentration: 29.9 ng/mLCalculated Conc: 27.5 ng/mLAcq. Date: 7/16/2011Acq. Time: 4:27:13 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 1Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 44939921 countsHeight: 5.68e+006 cpsStart Time: 15.3 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e6

Intensity, cps15.45Sample Name: "k110715a038" Sample ID: "LCS-110714-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "30ppb LCS" Annotation: ""Sample Index: 38Sample Type: QCConcentration: 29.9 ng/mLCalculated Conc: 28.4 ng/mLAcq. Date: 7/16/2011Acq. Time: 4:48:19 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 1Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 46186425 countsHeight: 5.96e+006 cpsStart Time: 15.3 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e6

Intensity, cps15.46Sample Name: "k110715a039" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 39Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 5:09:26 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6779 countsHeight: 7.04e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e4

Intensity, cps17.4317.6017.2516.2515.4715.2219.2214.9214.6814.5314.2913.8213.4312.5011.158.881.418.537.29Sample Name: "k110715a040" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 40Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 5:30:32 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 3416 countsHeight: 6.32e+003 cpsStart Time: 15.9 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e41.05e41.10e41.15e41.20e4

Intensity, cps17.5816.8217.4016.1615.4615.3218.4114.7414.4714.2813.9013.235.0112.3310.979.698.506.74Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 10 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a041" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 41Sample Type: QCConcentration: 5.00 ng/mLCalculated Conc: 4.97 ng/mLAcq. Date: 7/16/2011Acq. Time: 5:51:40 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 8932786 countsHeight: 1.22e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e6

Intensity, cps15.45Sample Name: "k110715a042" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 42Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 6:12:52 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 5900 countsHeight: 4.64e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.00500.001000.001500.002000.002500.003000.003500.004000.004500.005000.005500.006000.006500.007000.007500.008000.008500.009000.009500.001.00e41.05e41.10e41.15e41.20e41.25e4

Intensity, cps16.8317.6017.0316.6416.3815.8215.5318.4114.7219.2014.4514.3914.0813.3312.7911.478.438.827.776.91Sample Name: "k110715a043" Sample ID: "LCS-110714-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5ppb LCS ECF" Annotation: ""Sample Index: 43Sample Type: QCConcentration: 0.498 ng/mLCalculated Conc: 0.522 ng/mLAcq. Date: 7/16/2011Acq. Time: 6:34:01 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 986975 countsHeight: 1.18e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e51.10e51.15e5

Intensity, cps15.4515.5017.6017.0515.0318.33Sample Name: "k110715a044" Sample ID: "LCS-110714-11" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5ppb LCS ECF" Annotation: ""Sample Index: 44Sample Type: QCConcentration: 0.498 ng/mLCalculated Conc: 0.470 ng/mLAcq. Date: 7/16/2011Acq. Time: 6:55:11 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 892323 countsHeight: 1.03e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e5

Intensity, cps15.4415.2915.5717.5819.2115.10Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 11 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a045" Sample ID: "LCS-110714-12" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "0.5ppb LCS ECF" Annotation: ""Sample Index: 45Sample Type: QCConcentration: 0.498 ng/mLCalculated Conc: 0.491 ng/mLAcq. Date: 7/16/2011Acq. Time: 7:16:17 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 928923 countsHeight: 1.05e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e5

Intensity, cps15.4416.8517.4515.2315.0618.21Sample Name: "k110715a046" Sample ID: "LCS-110714-13" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5ppb LCS ECF" Annotation: ""Sample Index: 46Sample Type: QCConcentration: 4.99 ng/mLCalculated Conc: 4.96 ng/mLAcq. Date: 7/16/2011Acq. Time: 7:37:26 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 8898047 countsHeight: 1.02e+006 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e6

Intensity, cps15.4615.36Sample Name: "k110715a047" Sample ID: "LCS-110714-14" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5ppb LCS ECF" Annotation: ""Sample Index: 47Sample Type: QCConcentration: 4.99 ng/mLCalculated Conc: 4.99 ng/mLAcq. Date: 7/16/2011Acq. Time: 7:58:32 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8956716 countsHeight: 1.01e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e6

Intensity, cps15.43Sample Name: "k110715a048" Sample ID: "LCS-110714-15" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5ppb LCS ECF" Annotation: ""Sample Index: 48Sample Type: QCConcentration: 4.99 ng/mLCalculated Conc: 5.18 ng/mLAcq. Date: 7/16/2011Acq. Time: 8:19:38 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 9291104 countsHeight: 1.05e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e6

Intensity, cps15.4415.50Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 12 of 70Printing Time: 12:19:03 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a049" Sample ID: "LCS-110714-16" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "30ppb LCS ECF" Annotation: ""Sample Index: 49Sample Type: QCConcentration: 29.9 ng/mLCalculated Conc: 31.3 ng/mLAcq. Date: 7/16/2011Acq. Time: 8:40:46 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 50287005 countsHeight: 5.39e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.4515.31Sample Name: "k110715a050" Sample ID: "LCS-110714-17" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "30ppb LCS ECF" Annotation: ""Sample Index: 50Sample Type: QCConcentration: 29.9 ng/mLCalculated Conc: 30.3 ng/mLAcq. Date: 7/16/2011Acq. Time: 9:01:54 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 48914304 countsHeight: 5.43e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e65.4e6

Intensity, cps15.4415.30Sample Name: "k110715a051" Sample ID: "LCS-110714-18" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "30ppb LCS ECF" Annotation: ""Sample Index: 51Sample Type: QCConcentration: 29.9 ng/mLCalculated Conc: 30.5 ng/mLAcq. Date: 7/16/2011Acq. Time: 9:22:59 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 49150855 countsHeight: 5.39e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.44Sample Name: "k110715a052" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 52Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 9:44:06 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.8 minArea: 5294 countsHeight: 6.71e+003 cpsStart Time: 15.8 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.1417.4516.6517.5716.7116.5415.7715.6218.2815.2719.1815.0014.7814.4114.2313.645.0112.2311.599.788.848.18Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 13 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a053" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 53Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 10:05:16 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.8 minArea: 5588 countsHeight: 5.66e+003 cpsStart Time: 15.8 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e41.4e4

Intensity, cps17.2016.5117.5816.7116.0215.7815.5315.4018.3719.1714.7514.4014.2113.8813.1412.0310.899.398.405.016.88Sample Name: "k110715a054" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 54Sample Type: QCConcentration: 2.50 ng/mLCalculated Conc: 2.48 ng/mLAcq. Date: 7/16/2011Acq. Time: 10:26:25 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 4515007 countsHeight: 6.09e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.45Sample Name: "k110715a055" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 55Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 10:47:35 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 3733 countsHeight: 3.98e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e41.4e4

Intensity, cps17.5816.9416.5016.1515.9715.3918.3714.9919.1414.9514.4514.2613.8813.4412.0310.509.218.156.585.01Sample Name: "k110715a056" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 56Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 11:08:45 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.8 minArea: 6154 countsHeight: 4.12e+003 cpsStart Time: 15.7 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps17.4717.1417.2916.7616.6015.8615.3419.1818.1615.2014.8014.5614.3014.1713.9112.9110.699.808.867.46Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 14 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a057" Sample ID: "GLP10-01-01-18-001" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 2 Sample" Annotation: ""Sample Index: 57Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 11:29:50 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 2801 countsHeight: 3.95e+003 cpsStart Time: 15.9 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps14.0916.8616.7217.5217.5915.7915.6719.2218.211.391.2913.9112.9311.451.5510.279.018.06Sample Name: "k110715a058" Sample ID: "GLP10-01-01-18-002" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 2 LS" Annotation: ""Sample Index: 58Sample Type: UnknownConcentration: N/ACalculated Conc: 0.954 ng/mLAcq. Date: 7/16/2011Acq. Time: 11:51:03 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1769988 countsHeight: 2.46e+005 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e52.4e5

Intensity, cps15.4417.6114.10Sample Name: "k110715a059" Sample ID: "GLP10-01-01-18-003" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 2 MS" Annotation: ""Sample Index: 59Sample Type: UnknownConcentration: N/ACalculated Conc: 9.29 ng/mLAcq. Date: 7/16/2011Acq. Time: 12:12:10 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 16364277 countsHeight: 2.24e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e6

Intensity, cps15.44Sample Name: "k110715a060" Sample ID: "GLP10-01-01-18-004" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 2 MHS" Annotation: ""Sample Index: 60Sample Type: UnknownConcentration: N/ACalculated Conc: 89.7 ng/mLAcq. Date: 7/16/2011Acq. Time: 12:33:16 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 30513068 countsHeight: 4.19e+006 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e6

Intensity, cps15.38Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 15 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a061" Sample ID: "GLP10-01-01-18-005" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 2 HS (dil 1:100)" Annotation: ""Sample Index: 61Sample Type: UnknownConcentration: N/ACalculated Conc: 443. ng/mLAcq. Date: 7/16/2011Acq. Time: 12:54:17 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 7982102 countsHeight: 1.10e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e6

Intensity, cps15.43Sample Name: "k110715a062" Sample ID: "GLP10-01-01-18-006" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130R 0 110630 (dil 1:100)" Annotation: ""Sample Index: 62Sample Type: UnknownConcentration: N/ACalculated Conc: 837. ng/mLAcq. Date: 7/16/2011Acq. Time: 1:15:18 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 14802990 countsHeight: 1.72e+006 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e6

Intensity, cps15.4615.35Sample Name: "k110715a063" Sample ID: "GLP10-01-01-18-007" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130R DB 110630 (dil 1:100)" Annotation: ""Sample Index: 63Sample Type: UnknownConcentration: N/ACalculated Conc: 823. ng/mLAcq. Date: 7/16/2011Acq. Time: 1:36:27 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 14565294 countsHeight: 1.70e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e6

Intensity, cps15.4515.30Sample Name: "k110715a064" Sample ID: "GLP10-01-01-18-008" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130R LS 110630 (dil 1:100)" Annotation: ""Sample Index: 64Sample Type: UnknownConcentration: N/ACalculated Conc: 833. ng/mLAcq. Date: 7/16/2011Acq. Time: 1:57:36 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 14746656 countsHeight: 1.70e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e6

Intensity, cps15.4515.35Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 16 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a065" Sample ID: "GLP10-01-01-18-009" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130R MS 110630 (dil 1:100)" Annotation: ""Sample Index: 65Sample Type: UnknownConcentration: N/ACalculated Conc: 921. ng/mLAcq. Date: 7/16/2011Acq. Time: 2:18:46 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 16243219 countsHeight: 1.88e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e6

Intensity, cps15.44Sample Name: "k110715a066" Sample ID: "GLP10-01-01-18-010" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130R HS 110630 (dil 1:100)" Annotation: ""Sample Index: 66Sample Type: UnknownConcentration: N/ACalculated Conc: 1280. ng/mLAcq. Date: 7/16/2011Acq. Time: 2:39:57 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 22303777 countsHeight: 2.78e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e62.7e6

Intensity, cps15.4415.29Sample Name: "k110715a067" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 67Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 3:01:06 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 9964 countsHeight: 7.45e+003 cpsStart Time: 15.9 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps17.4617.5916.9016.5815.9715.5215.2715.3719.1615.0414.645.0114.4214.1813.2412.0710.378.45Sample Name: "k110715a068" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 68Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 3:22:18 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 8526 countsHeight: 4.20e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e41.4e4

Intensity, cps17.3617.5216.9616.2315.8215.6415.4518.3415.2514.8819.2414.4114.1313.7712.4810.969.178.115.017.776.85Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 17 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a069" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 69Sample Type: QCConcentration: 5.00 ng/mLCalculated Conc: 4.92 ng/mLAcq. Date: 7/16/2011Acq. Time: 3:43:24 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8839420 countsHeight: 1.21e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e6

Intensity, cps15.45Sample Name: "k110715a070" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 70Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 4:04:34 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 3608 countsHeight: 4.33e+003 cpsStart Time: 15.9 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps17.5616.7916.8716.4916.2115.7815.4618.2915.1119.1814.6714.4714.2113.9512.3411.879.0510.708.67Sample Name: "k110715a071" Sample ID: "GLP10-01-01-18-011" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130S 0 110630 (dil 1:10)" Annotation: ""Sample Index: 71Sample Type: UnknownConcentration: N/ACalculated Conc: 180. ng/mLAcq. Date: 7/16/2011Acq. Time: 4:25:43 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 30524073 countsHeight: 3.46e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e6

Intensity, cps15.4515.29Sample Name: "k110715a072" Sample ID: "GLP10-01-01-18-012" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130S 0 110630 (dil 1:10)" Annotation: ""Sample Index: 72Sample Type: UnknownConcentration: N/ACalculated Conc: 178. ng/mLAcq. Date: 7/16/2011Acq. Time: 4:46:54 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 30349497 countsHeight: 3.38e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e6

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 18 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a073" Sample ID: "GLP10-01-01-18-013" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130S LS 110630 (dil 1:100)" Annotation: ""Sample Index: 73Sample Type: UnknownConcentration: N/ACalculated Conc: 181. ng/mLAcq. Date: 7/16/2011Acq. Time: 5:08:01 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 3316855 countsHeight: 3.87e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e5

Intensity, cps15.4315.32Sample Name: "k110715a074" Sample ID: "GLP10-01-01-18-014" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130S MS 110630 (dil 1:100)" Annotation: ""Sample Index: 74Sample Type: UnknownConcentration: N/ACalculated Conc: 265. ng/mLAcq. Date: 7/16/2011Acq. Time: 5:29:07 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 4819966 countsHeight: 6.08e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.4415.36Sample Name: "k110715a075" Sample ID: "GLP10-01-01-18-015" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130S HS 110630 (dil 1:100)" Annotation: ""Sample Index: 75Sample Type: UnknownConcentration: N/ACalculated Conc: 708. ng/mLAcq. Date: 7/16/2011Acq. Time: 5:50:18 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 12596334 countsHeight: 1.63e+006 cpsStart Time: 15.2 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e6

Intensity, cps15.44Sample Name: "k110715a076" Sample ID: "GLP10-01-01-18-016" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130L 0 110630 (dil 1:10)" Annotation: ""Sample Index: 76Sample Type: UnknownConcentration: N/ACalculated Conc: 66.8 ng/mLAcq. Date: 7/16/2011Acq. Time: 6:11:26 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 11898880 countsHeight: 1.39e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e61.4e6

Intensity, cps15.43Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 19 of 70Printing Time: 12:19:04 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a077" Sample ID: "GLP10-01-01-18-017" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130L DB 110630 (dil 1:10)" Annotation: ""Sample Index: 77Sample Type: UnknownConcentration: N/ACalculated Conc: 63.3 ng/mLAcq. Date: 7/16/2011Acq. Time: 6:32:34 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 6Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 11302154 countsHeight: 1.32e+006 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e6

Intensity, cps15.4515.30Sample Name: "k110715a078" Sample ID: "GLP10-01-01-18-018" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130L LS 110630 (dil 1:10)" Annotation: ""Sample Index: 78Sample Type: UnknownConcentration: N/ACalculated Conc: 68.7 ng/mLAcq. Date: 7/16/2011Acq. Time: 6:53:42 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 12235962 countsHeight: 1.44e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e6

Intensity, cps15.44Sample Name: "k110715a079" Sample ID: "GLP10-01-01-18-019" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130L MS 110630 (dil 1:10)" Annotation: ""Sample Index: 79Sample Type: UnknownConcentration: N/ACalculated Conc: 74.8 ng/mLAcq. Date: 7/16/2011Acq. Time: 7:14:51 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 13283959 countsHeight: 1.57e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e6

Intensity, cps15.45Sample Name: "k110715a080" Sample ID: "GLP10-01-01-18-020" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130L HS 110630 (dil 1:10)" Annotation: ""Sample Index: 80Sample Type: UnknownConcentration: N/ACalculated Conc: 158. ng/mLAcq. Date: 7/16/2011Acq. Time: 7:35:59 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 27046340 countsHeight: 3.38e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e6

Intensity, cps15.4515.31Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 20 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a081" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 81Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 7:57:07 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 3547 countsHeight: 4.47e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps17.2116.8817.3816.1215.5418.0618.3215.0718.371.3814.4314.3614.261.4912.9912.6210.519.658.24Sample Name: "k110715a082" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 82Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 8:18:17 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 4296 countsHeight: 4.17e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e4

Intensity, cps17.2016.9717.5516.4116.5116.1518.1015.8219.2115.3214.991.3314.521.4114.4614.0313.5412.611.5610.578.398.897.756.86Sample Name: "k110715a083" Sample ID: "11003-26-11" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "10 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 83Sample Type: QCConcentration: 10.0 ng/mLCalculated Conc: 9.66 ng/mLAcq. Date: 7/16/2011Acq. Time: 8:39:26 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 16989171 countsHeight: 2.27e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e6

Intensity, cps15.43Sample Name: "k110715a084" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 84Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/16/2011Acq. Time: 9:00:35 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 7816 countsHeight: 5.12e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e4

Intensity, cps17.5816.8817.5116.4416.1015.8915.5915.4918.1119.2615.3314.8214.4914.2014.0312.975.0110.729.348.067.57Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 21 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a085" Sample ID: "GLP10-01-01-18-021" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131R 0 110622 (dil 1:100)" Annotation: ""Sample Index: 85Sample Type: UnknownConcentration: N/ACalculated Conc: 2310. ng/mLAcq. Date: 7/16/2011Acq. Time: 9:21:44 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 38390775 countsHeight: 4.34e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e6

Intensity, cps15.44Sample Name: "k110715a086" Sample ID: "GLP10-01-01-18-022" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131R DB 110622 (dil 1:100)" Annotation: ""Sample Index: 86Sample Type: UnknownConcentration: N/ACalculated Conc: 2550. ng/mLAcq. Date: 7/16/2011Acq. Time: 9:43:00 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 42046962 countsHeight: 4.74e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e6

Intensity, cps15.44Sample Name: "k110715a087" Sample ID: "GLP10-01-01-18-023" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131R LS 110622 (dil 1:100)" Annotation: ""Sample Index: 87Sample Type: UnknownConcentration: N/ACalculated Conc: 2490. ng/mLAcq. Date: 7/16/2011Acq. Time: 10:04:09 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 41164570 countsHeight: 4.67e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e6

Intensity, cps15.4515.27Sample Name: "k110715a088" Sample ID: "GLP10-01-01-18-024" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131R HS 110622 (dil 1:100)" Annotation: ""Sample Index: 88Sample Type: UnknownConcentration: N/ACalculated Conc: 4060. ng/mLAcq. Date: 7/16/2011Acq. Time: 10:25:18 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 62574999 countsHeight: 7.01e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e66.0e66.5e6

Intensity, cps15.4415.48Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 22 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a089" Sample ID: "GLP10-01-01-18-025" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131S 0 110622 (dil 1:10)" Annotation: ""Sample Index: 89Sample Type: UnknownConcentration: N/ACalculated Conc: 26.7 ng/mLAcq. Date: 7/16/2011Acq. Time: 10:46:27 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 1006429 countsHeight: 1.21e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e51.10e51.15e51.20e5

Intensity, cps15.3917.0117.5118.29Sample Name: "k110715a090" Sample ID: "GLP10-01-01-18-026" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131S DB 110622 (dil 1:10)" Annotation: ""Sample Index: 90Sample Type: UnknownConcentration: N/ACalculated Conc: 25.7 ng/mLAcq. Date: 7/16/2011Acq. Time: 11:07:29 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 972385 countsHeight: 1.14e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e51.10e51.15e5

Intensity, cps15.4015.3217.5318.2614.59Sample Name: "k110715a091" Sample ID: "GLP10-01-01-18-027" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131S LS 110622 (dil 1:10)" Annotation: ""Sample Index: 91Sample Type: UnknownConcentration: N/ACalculated Conc: 26.6 ng/mLAcq. Date: 7/16/2011Acq. Time: 11:28:29 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1003100 countsHeight: 1.21e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e51.10e51.15e51.20e5

Intensity, cps15.3815.2515.1817.5217.0118.30Sample Name: "k110715a092" Sample ID: "GLP10-01-01-18-028" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131S MS 110622 (dil 1:10)" Annotation: ""Sample Index: 92Sample Type: UnknownConcentration: N/ACalculated Conc: 36.0 ng/mLAcq. Date: 7/16/2011Acq. Time: 11:49:26 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1343986 countsHeight: 1.70e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e5

Intensity, cps15.3917.1017.41Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 23 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a093" Sample ID: "GLP10-01-01-18-029" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131S HS 110622 (dil 1:10)" Annotation: ""Sample Index: 93Sample Type: UnknownConcentration: N/ACalculated Conc: 115. ng/mLAcq. Date: 7/17/2011Acq. Time: 12:10:25 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 4205983 countsHeight: 5.59e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e5

Intensity, cps15.3815.23Sample Name: "k110715a094" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 94Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 12:31:25 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.8 minArea: 3033 countsHeight: 4.79e+003 cpsStart Time: 15.7 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e41.4e4

Intensity, cps17.5917.0116.1215.9215.6418.3215.2814.8115.051.3814.5314.4014.1613.9813.3712.249.498.989.911.607.156.894.89Sample Name: "k110715a095" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 95Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 12:52:31 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6444 countsHeight: 4.74e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps17.1617.5317.3816.1415.3618.3615.5015.2219.1914.5614.2813.8912.2711.118.785.01Sample Name: "k110715a096" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 96Sample Type: QCConcentration: 2.50 ng/mLCalculated Conc: 2.51 ng/mLAcq. Date: 7/17/2011Acq. Time: 1:13:39 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 4559996 countsHeight: 6.35e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.43Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 24 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a097" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 97Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 1:34:48 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 2847 countsHeight: 3.59e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps17.6016.6717.4116.2215.8816.0518.4115.2519.1914.9214.7014.3614.2313.5812.6810.7610.469.106.58Sample Name: "k110715a098" Sample ID: "GLP10-01-01-18-030" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131L 0 110622 (dil 1:10)" Annotation: ""Sample Index: 98Sample Type: UnknownConcentration: N/ACalculated Conc: 93.9 ng/mLAcq. Date: 7/17/2011Acq. Time: 1:55:56 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 16548643 countsHeight: 1.87e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e6

Intensity, cps15.44Sample Name: "k110715a099" Sample ID: "GLP10-01-01-18-031" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131L DB 110622 (dil 1:10)" Annotation: ""Sample Index: 99Sample Type: UnknownConcentration: N/ACalculated Conc: 96.2 ng/mLAcq. Date: 7/17/2011Acq. Time: 2:17:14 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 16924324 countsHeight: 1.90e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e6

Intensity, cps15.45Sample Name: "k110715a100" Sample ID: "GLP10-01-01-18-032" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131L LS 110622 (dil 1:10)" Annotation: ""Sample Index: 100Sample Type: UnknownConcentration: N/ACalculated Conc: 97.3 ng/mLAcq. Date: 7/17/2011Acq. Time: 2:38:26 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 17123392 countsHeight: 1.93e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e6

Intensity, cps15.4415.30Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 25 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a101" Sample ID: "GLP10-01-01-18-033" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131L MS 110622 (dil 1:10)" Annotation: ""Sample Index: 101Sample Type: UnknownConcentration: N/ACalculated Conc: 107. ng/mLAcq. Date: 7/17/2011Acq. Time: 2:59:36 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 18828610 countsHeight: 2.15e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e6

Intensity, cps15.45Sample Name: "k110715a102" Sample ID: "GLP10-01-01-18-034" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 131L HS 110622 (dil 1:10)" Annotation: ""Sample Index: 102Sample Type: UnknownConcentration: N/ACalculated Conc: 185. ng/mLAcq. Date: 7/17/2011Acq. Time: 3:20:46 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 31418926 countsHeight: 3.74e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e6

Intensity, cps15.4415.29Sample Name: "k110715a103" Sample ID: "GLP10-01-01-18-035" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133L 0 110630 (dil 1:10)" Annotation: ""Sample Index: 103Sample Type: UnknownConcentration: N/ACalculated Conc: 230. ng/mLAcq. Date: 7/17/2011Acq. Time: 3:42:01 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8260473 countsHeight: 9.49e+005 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e5

Intensity, cps15.37Sample Name: "k110715a104" Sample ID: "GLP10-01-01-18-036" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133L DB 110630 (dil 1:10)" Annotation: ""Sample Index: 104Sample Type: UnknownConcentration: N/ACalculated Conc: 226. ng/mLAcq. Date: 7/17/2011Acq. Time: 4:03:07 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8131453 countsHeight: 9.50e+005 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e5

Intensity, cps15.3715.24Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 26 of 70Printing Time: 12:19:05 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a105" Sample ID: "GLP10-01-01-18-037" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133L LS 110630 (dil 1:10)" Annotation: ""Sample Index: 105Sample Type: UnknownConcentration: N/ACalculated Conc: 265. ng/mLAcq. Date: 7/17/2011Acq. Time: 4:24:04 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 9508711 countsHeight: 1.09e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e6

Intensity, cps15.38Sample Name: "k110715a106" Sample ID: "GLP10-01-01-18-038" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133L MS 110630 (dil 1:10)" Annotation: ""Sample Index: 106Sample Type: UnknownConcentration: N/ACalculated Conc: 417. ng/mLAcq. Date: 7/17/2011Acq. Time: 4:45:03 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 14767838 countsHeight: 1.74e+006 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e6

Intensity, cps15.35Sample Name: "k110715a107" Sample ID: "GLP10-01-01-18-039" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133L HS 110630 (dil 1:10)" Annotation: ""Sample Index: 107Sample Type: UnknownConcentration: N/ACalculated Conc: 708. ng/mLAcq. Date: 7/17/2011Acq. Time: 5:06:02 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 24465047 countsHeight: 3.09e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e6

Intensity, cps15.3815.42Sample Name: "k110715a108" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 108Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 5:26:57 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6908 countsHeight: 4.99e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.1717.2617.6116.9617.4516.4715.9618.1615.7819.1915.2814.7714.4814.0413.9513.6612.265.01 11.189.268.40Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 27 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a109" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 109Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 5:48:02 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 7830 countsHeight: 4.94e+003 cpsStart Time: 15.8 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e41.4e4

Intensity, cps17.6216.7016.4716.1915.9015.4418.1314.6214.3114.0013.745.0112.6812.3010.708.267.796.63Sample Name: "k110715a110" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 110Sample Type: QCConcentration: 5.00 ng/mLCalculated Conc: 4.98 ng/mLAcq. Date: 7/17/2011Acq. Time: 6:09:19 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 8946596 countsHeight: 1.22e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e6

Intensity, cps15.46Sample Name: "k110715a111" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 111Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 6:30:33 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 7396 countsHeight: 7.44e+003 cpsStart Time: 15.9 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.6116.6818.3416.2315.6519.2214.8814.7014.3313.895.0113.7112.3711.2410.758.637.90Sample Name: "k110715a112" Sample ID: "GLP10-01-01-18-040" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133S 0 110630 (dil 1:10)" Annotation: ""Sample Index: 112Sample Type: UnknownConcentration: N/ACalculated Conc: 311. ng/mLAcq. Date: 7/17/2011Acq. Time: 6:51:49 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 11104112 countsHeight: 1.28e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e61.25e6

Intensity, cps15.40Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 28 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a113" Sample ID: "GLP10-01-01-18-041" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133S DB 110630 (dil 1:10)" Annotation: ""Sample Index: 113Sample Type: UnknownConcentration: N/ACalculated Conc: 314. ng/mLAcq. Date: 7/17/2011Acq. Time: 7:12:53 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 11217865 countsHeight: 1.30e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e6

Intensity, cps15.3715.42Sample Name: "k110715a114" Sample ID: "GLP10-01-01-18-042" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133S LS 110630 (dil 1:10)" Annotation: ""Sample Index: 114Sample Type: UnknownConcentration: N/ACalculated Conc: 316. ng/mLAcq. Date: 7/17/2011Acq. Time: 7:33:59 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 11289175 countsHeight: 1.30e+006 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e6

Intensity, cps15.4015.28Sample Name: "k110715a115" Sample ID: "GLP10-01-01-18-043" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133S MS 110630 (dil 1:10)" Annotation: ""Sample Index: 115Sample Type: UnknownConcentration: N/ACalculated Conc: 397. ng/mLAcq. Date: 7/17/2011Acq. Time: 7:54:58 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 14063129 countsHeight: 1.69e+006 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e6

Intensity, cps15.3915.34Sample Name: "k110715a116" Sample ID: "GLP10-01-01-18-044" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133S HS 110630 (dil 1:10)" Annotation: ""Sample Index: 116Sample Type: UnknownConcentration: N/ACalculated Conc: 768. ng/mLAcq. Date: 7/17/2011Acq. Time: 8:15:57 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 26384544 countsHeight: 3.30e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e6

Intensity, cps15.39Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 29 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a117" Sample ID: "GLP10-01-01-18-045" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133R 0 110630 (dil 1:10)" Annotation: ""Sample Index: 117Sample Type: UnknownConcentration: N/ACalculated Conc: 108. ng/mLAcq. Date: 7/17/2011Acq. Time: 8:36:55 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 18890925 countsHeight: 2.10e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e6

Intensity, cps15.4515.28Sample Name: "k110715a118" Sample ID: "GLP10-01-01-18-046" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133R DB 110630 (dil 1:10)" Annotation: ""Sample Index: 118Sample Type: UnknownConcentration: N/ACalculated Conc: 108. ng/mLAcq. Date: 7/17/2011Acq. Time: 8:58:00 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 18909016 countsHeight: 2.25e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e6

Intensity, cps15.4515.28Sample Name: "k110715a119" Sample ID: "GLP10-01-01-18-047" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133R LS 110630 (dil 1:10)" Annotation: ""Sample Index: 119Sample Type: UnknownConcentration: N/ACalculated Conc: 96.6 ng/mLAcq. Date: 7/17/2011Acq. Time: 9:19:14 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 17002577 countsHeight: 2.03e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e6

Intensity, cps15.45Sample Name: "k110715a120" Sample ID: "GLP10-01-01-18-048" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133R MS 110630 (dil 1:10)" Annotation: ""Sample Index: 120Sample Type: UnknownConcentration: N/ACalculated Conc: 112. ng/mLAcq. Date: 7/17/2011Acq. Time: 9:40:26 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 19563778 countsHeight: 2.26e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e6

Intensity, cps15.45Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 30 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a121" Sample ID: "GLP10-01-01-18-049" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133R HS 110630 (dil 1:10)" Annotation: ""Sample Index: 121Sample Type: UnknownConcentration: N/ACalculated Conc: 190. ng/mLAcq. Date: 7/17/2011Acq. Time: 10:01:43 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 32146060 countsHeight: 3.88e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e6

Intensity, cps15.44Sample Name: "k110715a122" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 122Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 10:22:52 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 4509 countsHeight: 4.32e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps16.6717.4616.8217.6018.1516.4716.0915.5219.1715.1414.8714.4314.2713.8613.095.0111.899.918.22Sample Name: "k110715a123" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 123Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 10:44:10 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 3247 countsHeight: 5.03e+003 cpsStart Time: 15.9 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.2417.0616.8817.4616.7215.9718.4115.8319.1715.3715.0914.4314.2713.8611.719.0711.108.32Sample Name: "k110715a124" Sample ID: "11003-26-8" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "1.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 124Sample Type: QCConcentration: 1.00 ng/mLCalculated Conc: 1.05 ng/mLAcq. Date: 7/17/2011Acq. Time: 11:05:20 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1950690 countsHeight: 2.65e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e52.4e52.5e52.6e5

Intensity, cps15.4417.3916.92Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 31 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a125" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 125Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 11:26:31 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.7 minArea: 3896 countsHeight: 5.54e+003 cpsStart Time: 15.7 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e4

Intensity, cps17.5917.4117.1716.7916.5918.2215.8518.4215.5719.1915.2814.8714.5814.1113.3211.9610.73Sample Name: "k110715a126" Sample ID: "GLP10-01-01-18-050" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134R 0 110628 (dil 1:100)" Annotation: ""Sample Index: 126Sample Type: UnknownConcentration: N/ACalculated Conc: 1790. ng/mLAcq. Date: 7/17/2011Acq. Time: 11:47:43 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 30420430 countsHeight: 3.32e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e6

Intensity, cps15.45Sample Name: "k110715a127" Sample ID: "GLP10-01-01-18-051" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134R DB 110628 (dil 1:100)" Annotation: ""Sample Index: 127Sample Type: UnknownConcentration: N/ACalculated Conc: 1800. ng/mLAcq. Date: 7/17/2011Acq. Time: 12:08:55 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 30552302 countsHeight: 3.33e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e6

Intensity, cps15.43Sample Name: "k110715a128" Sample ID: "GLP10-01-01-18-052" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134R LS 110628 (dil 1:100)" Annotation: ""Sample Index: 128Sample Type: UnknownConcentration: N/ACalculated Conc: 1870. ng/mLAcq. Date: 7/17/2011Acq. Time: 12:30:08 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 31722139 countsHeight: 3.46e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e6

Intensity, cps15.4415.31Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 32 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a129" Sample ID: "GLP10-01-01-18-053" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134R HS 110628 (dil 1:100)" Annotation: ""Sample Index: 129Sample Type: UnknownConcentration: N/ACalculated Conc: 3610. ng/mLAcq. Date: 7/17/2011Acq. Time: 12:51:18 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 50Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 56764811 countsHeight: 6.39e+006 cpsStart Time: 15.1 minEnd Time: 16.1 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e66.0e6

Intensity, cps15.44Sample Name: "k110715a130" Sample ID: "GLP10-01-01-18-054" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134L 0 110628 (dil 1:10)" Annotation: ""Sample Index: 130Sample Type: UnknownConcentration: N/ACalculated Conc: 527. ng/mLAcq. Date: 7/17/2011Acq. Time: 1:12:27 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 18471422 countsHeight: 2.16e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e6

Intensity, cps15.3615.40Sample Name: "k110715a131" Sample ID: "GLP10-01-01-18-055" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134L DB 110628 (dil 1:10)" Annotation: ""Sample Index: 131Sample Type: UnknownConcentration: N/ACalculated Conc: 592. ng/mLAcq. Date: 7/17/2011Acq. Time: 1:33:31 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 20629650 countsHeight: 2.34e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e6

Intensity, cps15.3915.25Sample Name: "k110715a132" Sample ID: "GLP10-01-01-18-056" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134L LS 110628 (dil 1:10)" Annotation: ""Sample Index: 132Sample Type: UnknownConcentration: N/ACalculated Conc: 602. ng/mLAcq. Date: 7/17/2011Acq. Time: 1:54:28 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 20968155 countsHeight: 2.36e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e6

Intensity, cps15.37Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 33 of 70Printing Time: 12:19:06 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a133" Sample ID: "GLP10-01-01-18-057" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134L MS 110628 (dil 1:10)" Annotation: ""Sample Index: 133Sample Type: UnknownConcentration: N/ACalculated Conc: 677. ng/mLAcq. Date: 7/17/2011Acq. Time: 2:15:31 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 23431483 countsHeight: 2.70e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e6

Intensity, cps15.37Sample Name: "k110715a134" Sample ID: "GLP10-01-01-18-058" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134L HS 110628 (dil 1:10)" Annotation: ""Sample Index: 134Sample Type: UnknownConcentration: N/ACalculated Conc: 1010. ng/mLAcq. Date: 7/17/2011Acq. Time: 2:36:32 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 34169371 countsHeight: 4.06e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e6

Intensity, cps15.3815.41Sample Name: "k110715a135" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 135Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 2:57:31 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 11090 countsHeight: 6.53e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps16.9117.6117.5016.6716.5018.3615.5015.1819.1715.0314.6914.2314.0213.3812.185.007.8410.878.977.60Sample Name: "k110715a136" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 136Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 3:18:37 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 25177 countsHeight: 7.26e+003 cpsStart Time: 15.4 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.6017.0617.4316.8916.6318.2916.4116.1615.3519.2014.9814.7914.6314.4014.3013.3813.1910.499.955.018.92Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 34 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a137" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 137Sample Type: QCConcentration: 2.50 ng/mLCalculated Conc: 2.54 ng/mLAcq. Date: 7/17/2011Acq. Time: 3:39:50 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 1Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 4618301 countsHeight: 6.31e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.45Sample Name: "k110715a138" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 138Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 4:01:04 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 14220 countsHeight: 5.53e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps16.7917.5216.7117.6316.4815.9019.1715.2914.7814.4814.0913.9412.7911.555.016.8010.518.57Sample Name: "k110715a139" Sample ID: "GLP10-01-01-18-059" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134S 0 110628" Annotation: ""Sample Index: 139Sample Type: UnknownConcentration: N/ACalculated Conc: 9.67 ng/mLAcq. Date: 7/17/2011Acq. Time: 4:22:16 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3535193 countsHeight: 4.16e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e54.2e5

Intensity, cps15.3717.54Sample Name: "k110715a140" Sample ID: "GLP10-01-01-18-060" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134S DB 110628" Annotation: ""Sample Index: 140Sample Type: UnknownConcentration: N/ACalculated Conc: 9.92 ng/mLAcq. Date: 7/17/2011Acq. Time: 4:43:24 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3624220 countsHeight: 4.25e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e54.2e5

Intensity, cps15.3815.29Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 35 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a141" Sample ID: "GLP10-01-01-18-061" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134S LS 110628" Annotation: ""Sample Index: 141Sample Type: UnknownConcentration: N/ACalculated Conc: 9.60 ng/mLAcq. Date: 7/17/2011Acq. Time: 5:04:22 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3510557 countsHeight: 4.04e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e5

Intensity, cps15.37Sample Name: "k110715a142" Sample ID: "GLP10-01-01-18-062" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134S MS 110628" Annotation: ""Sample Index: 142Sample Type: UnknownConcentration: N/ACalculated Conc: 10.7 ng/mLAcq. Date: 7/17/2011Acq. Time: 5:25:23 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3904635 countsHeight: 4.57e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e54.2e54.4e54.6e5

Intensity, cps15.3615.21Sample Name: "k110715a143" Sample ID: "GLP10-01-01-18-063" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 134S HS 110628" Annotation: ""Sample Index: 143Sample Type: UnknownConcentration: N/ACalculated Conc: 19.6 ng/mLAcq. Date: 7/17/2011Acq. Time: 5:46:23 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 7077087 countsHeight: 9.07e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e5

Intensity, cps15.3715.42Sample Name: "k110715a144" Sample ID: "GLP10-01-01-18-064" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 1 Sample" Annotation: ""Sample Index: 144Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 6:07:22 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 9562 countsHeight: 5.21e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps14.1017.5117.2116.6916.1518.3115.4818.2614.1913.9613.8412.3811.239.627.35Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 36 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a145" Sample ID: "GLP10-01-01-18-065" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 1 LS" Annotation: ""Sample Index: 145Sample Type: UnknownConcentration: N/ACalculated Conc: 0.981 ng/mLAcq. Date: 7/17/2011Acq. Time: 6:28:28 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1818046 countsHeight: 2.52e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e52.4e52.5e5

Intensity, cps15.4414.1217.6017.201.38Sample Name: "k110715a146" Sample ID: "GLP10-01-01-18-066" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 1 MS" Annotation: ""Sample Index: 146Sample Type: UnknownConcentration: N/ACalculated Conc: 10.0 ng/mLAcq. Date: 7/17/2011Acq. Time: 6:49:40 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 17620512 countsHeight: 2.44e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e6

Intensity, cps15.43Sample Name: "k110715a147" Sample ID: "GLP10-01-01-18-067" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 1 MHS" Annotation: ""Sample Index: 147Sample Type: UnknownConcentration: N/ACalculated Conc: 95.5 ng/mLAcq. Date: 7/17/2011Acq. Time: 7:10:50 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 32332229 countsHeight: 4.41e+006 cpsStart Time: 15.2 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e6

Intensity, cps15.38Sample Name: "k110715a148" Sample ID: "GLP10-01-01-18-068" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Trip Blank Set 1 HS (dil 1:100)" Annotation: ""Sample Index: 148Sample Type: UnknownConcentration: N/ACalculated Conc: 493. ng/mLAcq. Date: 7/17/2011Acq. Time: 7:31:53 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8849618 countsHeight: 1.24e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e6

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 37 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a149" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 149Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 7:53:00 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 4243 countsHeight: 4.49e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.4417.0116.2318.3415.9515.6415.4419.1715.2614.6814.4114.1713.905.0113.6012.3211.037.60 8.97Sample Name: "k110715a150" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 150Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 8:14:14 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 4567 countsHeight: 4.20e+003 cpsStart Time: 15.5 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps17.5817.4917.0216.2518.4115.4419.1315.1914.1914.0413.2411.589.255.01Sample Name: "k110715a151" Sample ID: "11003-26-11" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "10 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 151Sample Type: QCConcentration: 10.0 ng/mLCalculated Conc: 9.99 ng/mLAcq. Date: 7/17/2011Acq. Time: 8:35:26 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 17545963 countsHeight: 2.37e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e6

Intensity, cps15.48Sample Name: "k110715a152" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 152Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/17/2011Acq. Time: 8:56:39 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.6 minArea: 6473 countsHeight: 4.52e+003 cpsStart Time: 15.5 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps17.5516.7517.4816.6116.5516.2218.2315.6118.1615.2519.1714.7614.2214.0213.3912.3210.406.995.01Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 38 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a153" Sample ID: "GLP10-01-01-18-069" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135S 0 110628" Annotation: ""Sample Index: 153Sample Type: UnknownConcentration: N/ACalculated Conc: 18.9 ng/mLAcq. Date: 7/17/2011Acq. Time: 9:17:51 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 6830157 countsHeight: 7.66e+005 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e5

Intensity, cps15.42Sample Name: "k110715a154" Sample ID: "GLP10-01-01-18-070" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135S DB 110628" Annotation: ""Sample Index: 154Sample Type: UnknownConcentration: N/ACalculated Conc: 20.3 ng/mLAcq. Date: 7/17/2011Acq. Time: 9:39:02 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 7322715 countsHeight: 8.34e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e5

Intensity, cps15.40Sample Name: "k110715a155" Sample ID: "GLP10-01-01-18-071" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135S LS 110628" Annotation: ""Sample Index: 155Sample Type: UnknownConcentration: N/ACalculated Conc: 24.2 ng/mLAcq. Date: 7/17/2011Acq. Time: 10:00:02 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 8709535 countsHeight: 9.92e+005 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e5

Intensity, cps15.4115.27Sample Name: "k110715a156" Sample ID: "GLP10-01-01-18-072" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135S MS 110628" Annotation: ""Sample Index: 156Sample Type: UnknownConcentration: N/ACalculated Conc: 20.6 ng/mLAcq. Date: 7/17/2011Acq. Time: 10:21:01 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 7427254 countsHeight: 8.46e+005 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e5

Intensity, cps15.4015.25Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 39 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a157" Sample ID: "GLP10-01-01-18-073" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135S HS 110628" Annotation: ""Sample Index: 157Sample Type: UnknownConcentration: N/ACalculated Conc: 39.9 ng/mLAcq. Date: 7/17/2011Acq. Time: 10:42:03 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 6Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 14135478 countsHeight: 1.72e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e6

Intensity, cps15.42Sample Name: "k110715a158" Sample ID: "GLP10-01-01-18-074" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135L 0 110628 (dil 1:10)" Annotation: ""Sample Index: 158Sample Type: UnknownConcentration: N/ACalculated Conc: 283. ng/mLAcq. Date: 7/17/2011Acq. Time: 11:03:03 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 46122156 countsHeight: 5.15e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e6

Intensity, cps15.46Sample Name: "k110715a159" Sample ID: "GLP10-01-01-18-075" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135L DB 110628 (dil 1:10)" Annotation: ""Sample Index: 159Sample Type: UnknownConcentration: N/ACalculated Conc: 272. ng/mLAcq. Date: 7/17/2011Acq. Time: 11:24:08 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 44519562 countsHeight: 5.04e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e6

Intensity, cps15.45Sample Name: "k110715a160" Sample ID: "GLP10-01-01-18-076" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135L LS 110628 (dil 1:10)" Annotation: ""Sample Index: 160Sample Type: UnknownConcentration: N/ACalculated Conc: 278. ng/mLAcq. Date: 7/17/2011Acq. Time: 11:45:17 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 45307922 countsHeight: 5.20e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.4615.32Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 40 of 70Printing Time: 12:19:07 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a161" Sample ID: "GLP10-01-01-18-077" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135L MS 110628 (dil 1:10)" Annotation: ""Sample Index: 161Sample Type: UnknownConcentration: N/ACalculated Conc: 289. ng/mLAcq. Date: 7/18/2011Acq. Time: 12:06:30 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 46939862 countsHeight: 5.26e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.4615.32Sample Name: "k110715a162" Sample ID: "GLP10-01-01-18-078" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135L HS 110628 (dil 1:10)" Annotation: ""Sample Index: 162Sample Type: UnknownConcentration: N/ACalculated Conc: 365. ng/mLAcq. Date: 7/18/2011Acq. Time: 12:27:42 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 57279088 countsHeight: 6.18e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e66.0e6

Intensity, cps15.4615.31Sample Name: "k110715a163" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 163Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 12:48:53 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 8337 countsHeight: 5.01e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps17.6017.2417.4816.6416.5018.2616.0815.6018.3615.4415.1214.3414.0813.6012.5211.00Sample Name: "k110715a164" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 164Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 1:10:05 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.6 minArea: 2637 countsHeight: 3.53e+003 cpsStart Time: 15.6 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps17.5617.4517.1716.5416.1519.1616.0815.9418.3515.3815.0514.8614.3214.2114.0312.799.359.99Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 41 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a165" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 165Sample Type: QCConcentration: 5.00 ng/mLCalculated Conc: 5.01 ng/mLAcq. Date: 7/18/2011Acq. Time: 1:31:18 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 8986786 countsHeight: 1.22e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e61.15e61.20e6

Intensity, cps15.46Sample Name: "k110715a166" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 166Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 1:52:35 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.6 minArea: 12628 countsHeight: 6.22e+003 cpsStart Time: 15.5 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.1017.2216.8417.5616.6019.1716.1617.5915.5715.0614.9514.5414.7214.1212.895.0111.8110.58Sample Name: "k110715a167" Sample ID: "GLP10-01-01-18-079" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135R 0 110628 (dil 1:100)" Annotation: ""Sample Index: 167Sample Type: UnknownConcentration: N/ACalculated Conc: 3570. ng/mLAcq. Date: 7/18/2011Acq. Time: 2:13:50 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 56222974 countsHeight: 5.80e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e6

Intensity, cps15.46Sample Name: "k110715a168" Sample ID: "GLP10-01-01-18-080" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135R DB 110628 (dil 1:100)" Annotation: ""Sample Index: 168Sample Type: UnknownConcentration: N/ACalculated Conc: 3460. ng/mLAcq. Date: 7/18/2011Acq. Time: 2:35:04 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 54804934 countsHeight: 5.74e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e6

Intensity, cps15.45Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 42 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a169" Sample ID: "GLP10-01-01-18-081" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135R LS 110628 (dil 1:100)" Annotation: ""Sample Index: 169Sample Type: UnknownConcentration: N/ACalculated Conc: 3600. ng/mLAcq. Date: 7/18/2011Acq. Time: 2:56:19 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 56700713 countsHeight: 5.87e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e6

Intensity, cps15.44Sample Name: "k110715a170" Sample ID: "GLP10-01-01-18-083" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 135R HS 110628 (dil 1:100)" Annotation: ""Sample Index: 170Sample Type: UnknownConcentration: N/ACalculated Conc: 5250. ng/mLAcq. Date: 7/18/2011Acq. Time: 3:17:34 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 76644663 countsHeight: 8.14e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e66.0e66.5e67.0e67.5e68.0e6

Intensity, cps15.4515.31Sample Name: "k110715a171" Sample ID: "GLP10-01-01-18-084" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136L 0 110630 (dil 1:10)" Annotation: ""Sample Index: 171Sample Type: UnknownConcentration: N/ACalculated Conc: 79.7 ng/mLAcq. Date: 7/18/2011Acq. Time: 3:38:47 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 2925019 countsHeight: 3.48e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e5

Intensity, cps15.3915.2417.53Sample Name: "k110715a172" Sample ID: "GLP10-01-01-18-085" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136L DB 110630 (dil 1:10)" Annotation: ""Sample Index: 172Sample Type: UnknownConcentration: N/ACalculated Conc: 78.3 ng/mLAcq. Date: 7/18/2011Acq. Time: 3:59:58 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2874905 countsHeight: 3.40e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e5

Intensity, cps15.3915.25Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 43 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a173" Sample ID: "GLP10-01-01-18-086" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136L LS 110630 (dil 1:10)" Annotation: ""Sample Index: 173Sample Type: UnknownConcentration: N/ACalculated Conc: 79.6 ng/mLAcq. Date: 7/18/2011Acq. Time: 4:21:01 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2921336 countsHeight: 3.40e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e5

Intensity, cps15.3915.2417.51Sample Name: "k110715a174" Sample ID: "GLP10-01-01-18-155" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136L MS 110630 (dil 1:10)" Annotation: ""Sample Index: 174Sample Type: UnknownConcentration: N/ACalculated Conc: 89.1 ng/mLAcq. Date: 7/18/2011Acq. Time: 4:42:04 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3263811 countsHeight: 3.89e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e5

Intensity, cps15.3815.24Sample Name: "k110715a175" Sample ID: "GLP10-01-01-18-087" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136L HS 110630 (dil 1:10)" Annotation: ""Sample Index: 175Sample Type: UnknownConcentration: N/ACalculated Conc: 170. ng/mLAcq. Date: 7/18/2011Acq. Time: 5:03:04 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 6143782 countsHeight: 7.62e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e5

Intensity, cps15.3615.22Sample Name: "k110715a176" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 176Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 5:24:03 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 10303 countsHeight: 6.50e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.0417.5816.7517.6016.7016.4516.2718.2215.4415.3615.1614.5614.2113.9312.535.0110.9510.63Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 44 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a177" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 177Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 5:45:13 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 2943 countsHeight: 5.42e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.5917.0417.4616.0615.9018.3915.0114.8514.4714.1113.1611.605.01Sample Name: "k110715a178" Sample ID: "11003-26-8" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "1.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 178Sample Type: QCConcentration: 1.00 ng/mLCalculated Conc: 1.05 ng/mLAcq. Date: 7/18/2011Acq. Time: 6:06:26 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 1945252 countsHeight: 2.64e+005 cpsStart Time: 15.4 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e52.4e52.5e52.6e5

Intensity, cps15.4517.6217.24Sample Name: "k110715a179" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 179Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 6:27:40 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6033 countsHeight: 4.83e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e4

Intensity, cps17.2017.5817.4416.5516.7216.2215.4519.1815.3114.8014.691.3814.3514.171.2513.4312.0610.49Sample Name: "k110715a180" Sample ID: "GLP10-01-01-18-088" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136S 0 110630 (dil 1:10)" Annotation: ""Sample Index: 180Sample Type: UnknownConcentration: N/ACalculated Conc: 131. ng/mLAcq. Date: 7/18/2011Acq. Time: 6:48:58 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 22653847 countsHeight: 2.62e+006 cpsStart Time: 15.0 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e6

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 45 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a181" Sample ID: "GLP10-01-01-18-089" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136S DB 110630 (dil 1:10)" Annotation: ""Sample Index: 181Sample Type: UnknownConcentration: N/ACalculated Conc: 131. ng/mLAcq. Date: 7/18/2011Acq. Time: 7:10:12 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 22668981 countsHeight: 2.55e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e6

Intensity, cps15.44Sample Name: "k110715a182" Sample ID: "GLP10-01-01-18-090" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136S LS 110630 (dil 1:10)" Annotation: ""Sample Index: 182Sample Type: UnknownConcentration: N/ACalculated Conc: 132. ng/mLAcq. Date: 7/18/2011Acq. Time: 7:31:27 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 22817944 countsHeight: 2.54e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e6

Intensity, cps15.44Sample Name: "k110715a183" Sample ID: "GLP10-01-01-18-091" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136S MS 110630 (dil 1:10)" Annotation: ""Sample Index: 183Sample Type: UnknownConcentration: N/ACalculated Conc: 136. ng/mLAcq. Date: 7/18/2011Acq. Time: 7:52:39 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 23475309 countsHeight: 2.63e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e6

Intensity, cps15.45Sample Name: "k110715a184" Sample ID: "GLP10-01-01-18-092" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 136S HS 110630 (dil 1:10)" Annotation: ""Sample Index: 184Sample Type: UnknownConcentration: N/ACalculated Conc: 217. ng/mLAcq. Date: 7/18/2011Acq. Time: 8:13:51 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 36337810 countsHeight: 4.30e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e6

Intensity, cps15.4415.45Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 46 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a185" Sample ID: "GLP10-01-01-18-093" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137S 0 110624" Annotation: ""Sample Index: 185Sample Type: UnknownConcentration: N/ACalculated Conc: 0.284 ng/mLAcq. Date: 7/18/2011Acq. Time: 8:35:05 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 553876 countsHeight: 6.21e+004 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e4

Intensity, cps15.4617.5917.1214.1117.4218.3814.19Sample Name: "k110715a186" Sample ID: "GLP10-01-01-18-094" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137S DB 110624" Annotation: ""Sample Index: 186Sample Type: UnknownConcentration: N/ACalculated Conc: 0.269 ng/mLAcq. Date: 7/18/2011Acq. Time: 8:56:19 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 525864 countsHeight: 6.20e+004 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e4

Intensity, cps15.4515.3117.6014.1417.3218.33Sample Name: "k110715a187" Sample ID: "GLP10-01-01-18-095" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137S LS 110624" Annotation: ""Sample Index: 187Sample Type: UnknownConcentration: N/ACalculated Conc: 0.383 ng/mLAcq. Date: 7/18/2011Acq. Time: 9:17:32 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 733508 countsHeight: 8.97e+004 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e47.0e47.5e48.0e48.5e49.0e4

Intensity, cps15.4415.3017.0214.1117.6018.34Sample Name: "k110715a188" Sample ID: "GLP10-01-01-18-096" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137S MS 110624" Annotation: ""Sample Index: 188Sample Type: UnknownConcentration: N/ACalculated Conc: 1.18 ng/mLAcq. Date: 7/18/2011Acq. Time: 9:38:45 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2180672 countsHeight: 3.06e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e5

Intensity, cps15.4517.0417.59Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 47 of 70Printing Time: 12:19:08 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a189" Sample ID: "GLP10-01-01-18-097" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137S HS 110624" Annotation: ""Sample Index: 189Sample Type: UnknownConcentration: N/ACalculated Conc: 9.32 ng/mLAcq. Date: 7/18/2011Acq. Time: 10:00:01 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 16430196 countsHeight: 2.27e+006 cpsStart Time: 15.2 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e6

Intensity, cps15.43Sample Name: "k110715a190" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 190Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 10:21:14 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 24247 countsHeight: 6.06e+003 cpsStart Time: 15.4 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e4

Intensity, cps17.6117.1716.9717.4416.6816.1418.1819.2015.5415.2414.7114.3014.465.0113.9713.6112.2610.96Sample Name: "k110715a191" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 191Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 10:42:32 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 11381 countsHeight: 4.46e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps17.6017.2117.5216.7019.2016.5018.1915.3914.8814.6914.6014.1413.7812.4011.228.90Sample Name: "k110715a192" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 192Sample Type: QCConcentration: 2.50 ng/mLCalculated Conc: 2.61 ng/mLAcq. Date: 7/18/2011Acq. Time: 11:03:45 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 4738949 countsHeight: 6.70e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.43Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 48 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a193" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 193Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 11:25:00 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6875 countsHeight: 5.80e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.5916.9116.6916.4716.1818.3215.981.37 15.2615.0514.9314.4614.151.541.2413.7512.8911.3010.06Sample Name: "k110715a194" Sample ID: "GLP10-01-01-18-098" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137L 0 110624" Annotation: ""Sample Index: 194Sample Type: UnknownConcentration: N/ACalculated Conc: 0.372 ng/mLAcq. Date: 7/18/2011Acq. Time: 11:46:14 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 713968 countsHeight: 8.90e+004 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e47.0e47.5e48.0e48.5e49.0e4

Intensity, cps15.4315.4114.1017.3117.59Sample Name: "k110715a195" Sample ID: "GLP10-01-01-18-099" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137L DB 110624" Annotation: ""Sample Index: 195Sample Type: UnknownConcentration: N/ACalculated Conc: 0.381 ng/mLAcq. Date: 7/18/2011Acq. Time: 12:07:30 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 729396 countsHeight: 9.28e+004 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05000.01.0e41.5e42.0e42.5e43.0e43.5e44.0e44.5e45.0e45.5e46.0e46.5e47.0e47.5e48.0e48.5e49.0e49.5e4

Intensity, cps15.4415.3017.4314.1017.0718.1619.19Sample Name: "k110715a196" Sample ID: "GLP10-01-01-18-100" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137L LS 110624" Annotation: ""Sample Index: 196Sample Type: UnknownConcentration: N/ACalculated Conc: 0.477 ng/mLAcq. Date: 7/18/2011Acq. Time: 12:28:42 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 905110 countsHeight: 1.15e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005000.001.00e41.50e42.00e42.50e43.00e43.50e44.00e44.50e45.00e45.50e46.00e46.50e47.00e47.50e48.00e48.50e49.00e49.50e41.00e51.05e51.10e51.15e5

Intensity, cps15.4217.5815.2917.1614.1017.4118.27Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 49 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a197" Sample ID: "GLP10-01-01-18-101" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137L MS 110624" Annotation: ""Sample Index: 197Sample Type: UnknownConcentration: N/ACalculated Conc: 1.35 ng/mLAcq. Date: 7/18/2011Acq. Time: 12:49:58 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 2479176 countsHeight: 3.39e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e5

Intensity, cps15.4415.30Sample Name: "k110715a198" Sample ID: "GLP10-01-01-18-102" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 137L HS 110624" Annotation: ""Sample Index: 198Sample Type: UnknownConcentration: N/ACalculated Conc: 9.98 ng/mLAcq. Date: 7/18/2011Acq. Time: 1:11:15 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 17534357 countsHeight: 2.48e+006 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e6

Intensity, cps15.45Sample Name: "k110715a199" Sample ID: "GLP10-01-01-18-103" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138R 0 110630 (dil 1:10)" Annotation: ""Sample Index: 199Sample Type: UnknownConcentration: N/ACalculated Conc: 294. ng/mLAcq. Date: 7/18/2011Acq. Time: 1:32:30 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 47583692 countsHeight: 5.33e+006 cpsStart Time: 15.1 minEnd Time: 16.0 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.4415.29Sample Name: "k110715a200" Sample ID: "GLP10-01-01-18-104" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138R DB 110630 (dil 1:10)" Annotation: ""Sample Index: 200Sample Type: UnknownConcentration: N/ACalculated Conc: 288. ng/mLAcq. Date: 7/18/2011Acq. Time: 1:53:44 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 46726845 countsHeight: 5.35e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e6

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 50 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a201" Sample ID: "GLP10-01-01-18-105" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138R LS 110630 (dil 1:10)" Annotation: ""Sample Index: 201Sample Type: UnknownConcentration: N/ACalculated Conc: 292. ng/mLAcq. Date: 7/18/2011Acq. Time: 2:14:57 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 47383282 countsHeight: 5.42e+006 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e64.8e65.0e65.2e65.4e6

Intensity, cps15.44Sample Name: "k110715a202" Sample ID: "GLP10-01-01-18-106" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138R MS 110630 (dil 1:10)" Annotation: ""Sample Index: 202Sample Type: UnknownConcentration: N/ACalculated Conc: 370. ng/mLAcq. Date: 7/18/2011Acq. Time: 2:36:17 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 58021857 countsHeight: 6.57e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e51.0e61.5e62.0e62.5e63.0e63.5e64.0e64.5e65.0e65.5e66.0e66.5e6

Intensity, cps15.4515.30Sample Name: "k110715a203" Sample ID: "GLP10-01-01-18-107" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138R HS 110630 (dil 1:10)" Annotation: ""Sample Index: 203Sample Type: UnknownConcentration: N/ACalculated Conc: 709. ng/mLAcq. Date: 7/18/2011Acq. Time: 2:57:32 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 94415521 countsHeight: 1.05e+007 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e51.00e61.50e62.00e62.50e63.00e63.50e64.00e64.50e65.00e65.50e66.00e66.50e67.00e67.50e68.00e68.50e69.00e69.50e61.00e71.05e7

Intensity, cps15.4315.29Sample Name: "k110715a204" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 204Sample Type: UnknownConcentration: N/ACalculated Conc: 0.00800 ng/mLAcq. Date: 7/18/2011Acq. Time: 3:18:44 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 51098 countsHeight: 8.55e+003 cpsStart Time: 15.4 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.5917.2116.6517.4615.5119.151.4119.2015.0014.7514.6014.491.5114.2514.0213.5912.5110.61Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 51 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a205" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 205Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 3:40:00 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 14265 countsHeight: 6.04e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.4616.9517.6016.5815.9219.1615.531.3918.2515.091.3214.9514.6414.3514.2414.081.5813.3511.4010.59Sample Name: "k110715a206" Sample ID: "11003-26-11" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "10 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 206Sample Type: QCConcentration: 10.0 ng/mLCalculated Conc: 9.94 ng/mLAcq. Date: 7/18/2011Acq. Time: 4:01:13 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 17469490 countsHeight: 2.62e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e6

Intensity, cps15.44Sample Name: "k110715a207" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 207Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 4:22:29 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 34849 countsHeight: 7.08e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.5917.1116.7816.1717.4415.4915.3014.3814.1313.7313.4612.3610.878.675.018.40Sample Name: "k110715a208" Sample ID: "GLP10-01-01-18-108" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138L 0 110630" Annotation: ""Sample Index: 208Sample Type: UnknownConcentration: N/ACalculated Conc: 0.891 ng/mLAcq. Date: 7/18/2011Acq. Time: 4:43:44 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1655909 countsHeight: 2.04e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e5

Intensity, cps15.4214.1017.0917.58Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 52 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a209" Sample ID: "GLP10-01-01-18-109" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138L DB 110630" Annotation: ""Sample Index: 209Sample Type: UnknownConcentration: N/ACalculated Conc: 0.894 ng/mLAcq. Date: 7/18/2011Acq. Time: 5:05:00 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1660589 countsHeight: 2.10e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e5

Intensity, cps15.4414.0916.9517.37Sample Name: "k110715a210" Sample ID: "GLP10-01-01-18-110" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138L LS 110630" Annotation: ""Sample Index: 210Sample Type: UnknownConcentration: N/ACalculated Conc: 0.974 ng/mLAcq. Date: 7/18/2011Acq. Time: 5:26:17 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1805976 countsHeight: 2.33e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e5

Intensity, cps15.4315.3014.1319.2216.8417.28Sample Name: "k110715a211" Sample ID: "GLP10-01-01-18-111" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138L MS 110630" Annotation: ""Sample Index: 211Sample Type: UnknownConcentration: N/ACalculated Conc: 1.69 ng/mLAcq. Date: 7/18/2011Acq. Time: 5:47:32 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3092233 countsHeight: 4.36e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e54.2e5

Intensity, cps15.4215.45Sample Name: "k110715a212" Sample ID: "GLP10-01-01-18-112" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138L HS 110630" Annotation: ""Sample Index: 212Sample Type: UnknownConcentration: N/ACalculated Conc: 9.14 ng/mLAcq. Date: 7/18/2011Acq. Time: 6:08:47 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 16119725 countsHeight: 2.37e+006 cpsStart Time: 15.2 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e6

Intensity, cps15.43Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 53 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a213" Sample ID: "GLP10-01-01-18-113" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138S 0 110630 (dil 1:10)" Annotation: ""Sample Index: 213Sample Type: UnknownConcentration: N/ACalculated Conc: 155. ng/mLAcq. Date: 7/18/2011Acq. Time: 6:30:04 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 5604337 countsHeight: 7.07e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e5

Intensity, cps15.37Sample Name: "k110715a214" Sample ID: "GLP10-01-01-18-114" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138S DB 110630 (dil 1:10)" Annotation: ""Sample Index: 214Sample Type: UnknownConcentration: N/ACalculated Conc: 153. ng/mLAcq. Date: 7/18/2011Acq. Time: 6:51:14 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 5557016 countsHeight: 7.27e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e5

Intensity, cps15.37Sample Name: "k110715a215" Sample ID: "GLP10-01-01-18-115" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138S LS 110630 (dil 1:10)" Annotation: ""Sample Index: 215Sample Type: UnknownConcentration: N/ACalculated Conc: 161. ng/mLAcq. Date: 7/18/2011Acq. Time: 7:12:13 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 5836366 countsHeight: 7.71e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e5

Intensity, cps15.3715.22Sample Name: "k110715a216" Sample ID: "GLP10-01-01-18-116" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138S MS 110630 (dil 1:10)" Annotation: ""Sample Index: 216Sample Type: UnknownConcentration: N/ACalculated Conc: 231. ng/mLAcq. Date: 7/18/2011Acq. Time: 7:33:13 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8301390 countsHeight: 1.11e+006 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e6

Intensity, cps15.3615.22Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 54 of 70Printing Time: 12:19:09 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a217" Sample ID: "GLP10-01-01-18-117" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 138S HS 110630 (dil 1:10)" Annotation: ""Sample Index: 217Sample Type: UnknownConcentration: N/ACalculated Conc: 610. ng/mLAcq. Date: 7/18/2011Acq. Time: 7:54:22 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 21245685 countsHeight: 3.01e+006 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e6

Intensity, cps15.38Sample Name: "k110715a218" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 218Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 8:15:26 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.6 minArea: 9819 countsHeight: 5.35e+003 cpsStart Time: 15.5 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.0500.01000.01500.02000.02500.03000.03500.04000.04500.05000.05500.06000.06500.07000.07500.08000.08500.09000.09500.01.0e41.1e41.1e41.2e41.2e41.3e41.3e4

Intensity, cps16.7217.0916.0317.5715.8819.1815.4917.4318.281.4114.9715.1314.3414.031.2613.641.5712.8711.6210.008.446.74Sample Name: "k110715a219" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 219Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 8:36:35 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6440 countsHeight: 4.14e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps17.2416.7017.1016.5816.2017.5716.3219.2315.6215.4615.1518.291.4114.7314.361.3514.3014.0013.401.5912.6710.869.787.90Sample Name: "k110715a220" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 220Sample Type: QCConcentration: 5.00 ng/mLCalculated Conc: 4.81 ng/mLAcq. Date: 7/18/2011Acq. Time: 8:57:48 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8639138 countsHeight: 1.39e+006 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e61.4e6

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 55 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a221" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 221Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/18/2011Acq. Time: 9:19:03 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 9608 countsHeight: 5.22e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e4

Intensity, cps16.6516.9816.8716.1419.2117.5915.9115.5815.3318.3314.9214.6314.4614.1613.8213.4912.895.0111.1210.578.08Sample Name: "k110715a222" Sample ID: "GLP10-01-01-18-118" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26C 0 110622 (dil 1:10)" Annotation: ""Sample Index: 222Sample Type: UnknownConcentration: N/ACalculated Conc: 427. ng/mLAcq. Date: 7/18/2011Acq. Time: 9:40:19 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 15087641 countsHeight: 1.89e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e6

Intensity, cps15.37Sample Name: "k110715a223" Sample ID: "GLP10-01-01-18-119" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26C DB 110622 (dil 1:10)" Annotation: ""Sample Index: 223Sample Type: UnknownConcentration: N/ACalculated Conc: 425. ng/mLAcq. Date: 7/18/2011Acq. Time: 10:01:31 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 15029361 countsHeight: 1.92e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e6

Intensity, cps15.37Sample Name: "k110715a224" Sample ID: "GLP10-01-01-18-120" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26C LS 110622 (dil 1:10)" Annotation: ""Sample Index: 224Sample Type: UnknownConcentration: N/ACalculated Conc: 436. ng/mLAcq. Date: 7/18/2011Acq. Time: 10:22:35 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 15420534 countsHeight: 1.99e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e6

Intensity, cps15.36Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 56 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a225" Sample ID: "GLP10-01-01-18-121" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26C MS 110622 (dil 1:10)" Annotation: ""Sample Index: 225Sample Type: UnknownConcentration: N/ACalculated Conc: 502. ng/mLAcq. Date: 7/18/2011Acq. Time: 10:43:43 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 17638111 countsHeight: 2.24e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e6

Intensity, cps15.38Sample Name: "k110715a226" Sample ID: "GLP10-01-01-18-122" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26C HS 110622 (dil 1:10)" Annotation: ""Sample Index: 226Sample Type: UnknownConcentration: N/ACalculated Conc: 841. ng/mLAcq. Date: 7/18/2011Acq. Time: 11:04:50 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 28731422 countsHeight: 3.73e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e6

Intensity, cps15.3915.23Sample Name: "k110715a227" Sample ID: "GLP10-01-01-18-123" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26L 0 110622 (dil 1:10)" Annotation: ""Sample Index: 227Sample Type: UnknownConcentration: N/ACalculated Conc: 645. ng/mLAcq. Date: 7/18/2011Acq. Time: 11:25:52 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 22392308 countsHeight: 2.78e+006 cpsStart Time: 15.0 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e62.7e6

Intensity, cps15.37Sample Name: "k110715a228" Sample ID: "GLP10-01-01-18-124" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26L DB 110622 (dil 1:10)" Annotation: ""Sample Index: 228Sample Type: UnknownConcentration: N/ACalculated Conc: 644. ng/mLAcq. Date: 7/18/2011Acq. Time: 11:47:01 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 22371522 countsHeight: 2.73e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e62.6e62.7e6

Intensity, cps15.3915.25Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 57 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a229" Sample ID: "GLP10-01-01-18-125" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26L LS 110622 (dil 1:10)" Annotation: ""Sample Index: 229Sample Type: UnknownConcentration: N/ACalculated Conc: 667. ng/mLAcq. Date: 7/19/2011Acq. Time: 12:08:03 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 23131837 countsHeight: 2.92e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e6

Intensity, cps15.37Sample Name: "k110715a230" Sample ID: "GLP10-01-01-18-126" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26L MS 110622 (dil 1:10)" Annotation: ""Sample Index: 230Sample Type: UnknownConcentration: N/ACalculated Conc: 723. ng/mLAcq. Date: 7/19/2011Acq. Time: 12:29:04 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 24932867 countsHeight: 3.23e+006 cpsStart Time: 15.0 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e6

Intensity, cps15.39Sample Name: "k110715a231" Sample ID: "GLP10-01-01-18-127" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW CW26L HS 110622 (dil 1:10)" Annotation: ""Sample Index: 231Sample Type: UnknownConcentration: N/ACalculated Conc: 1060. ng/mLAcq. Date: 7/19/2011Acq. Time: 12:50:10 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 35691197 countsHeight: 4.60e+006 cpsStart Time: 15.0 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e63.0e63.2e63.4e63.6e63.8e64.0e64.2e64.4e64.6e6

Intensity, cps15.37Sample Name: "k110715a232" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 232Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 1:11:13 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 10934 countsHeight: 7.54e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps16.9716.6517.1219.1917.3215.5015.0918.2614.9414.7614.2714.1614.0513.4512.7111.498.935.00Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 58 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a233" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 233Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 1:32:21 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 8493 countsHeight: 5.95e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.5917.1216.7216.4817.4515.9915.4319.2218.2914.7514.2714.0213.5312.6511.309.75Sample Name: "k110715a234" Sample ID: "11003-26-8" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "1.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 234Sample Type: QCConcentration: 1.00 ng/mLCalculated Conc: 0.989 ng/mLAcq. Date: 7/19/2011Acq. Time: 1:53:42 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 1832372 countsHeight: 2.83e+005 cpsStart Time: 15.3 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e5

Intensity, cps15.4317.00Sample Name: "k110715a235" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 235Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 2:14:58 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 14786 countsHeight: 6.31e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.3316.8816.7917.5719.1815.5215.4615.3018.2914.9114.3014.1214.0013.8613.1511.6010.905.019.11Sample Name: "k110715a236" Sample ID: "GLP10-01-01-18-133" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 130L RB 110630" Annotation: ""Sample Index: 236Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 2:36:20 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 19418 countsHeight: 6.30e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps14.141.4016.6917.6016.6117.4719.1616.1715.8015.691.2814.021.6113.6413.0110.9510.59Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 59 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a237" Sample ID: "GLP10-01-01-18-134" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 133S RB 110630" Annotation: ""Sample Index: 237Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 2:57:36 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 34878 countsHeight: 9.00e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e41.8e4

Intensity, cps17.6014.1016.9915.4017.4119.1618.1914.0213.3212.495.00 11.32Sample Name: "k110715a238" Sample ID: "GLP10-01-01-18-128" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 140R 0 110622 (dil 1:10)" Annotation: ""Sample Index: 238Sample Type: UnknownConcentration: N/ACalculated Conc: 127. ng/mLAcq. Date: 7/19/2011Acq. Time: 3:18:51 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 4604487 countsHeight: 5.86e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e5

Intensity, cps15.3715.23Sample Name: "k110715a239" Sample ID: "GLP10-01-01-18-129" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 140R DB 110622 (dil 1:10)" Annotation: ""Sample Index: 239Sample Type: UnknownConcentration: N/ACalculated Conc: 130. ng/mLAcq. Date: 7/19/2011Acq. Time: 3:39:59 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 4720472 countsHeight: 6.11e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.37Sample Name: "k110715a240" Sample ID: "GLP10-01-01-18-130" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 140R LS 110622 (dil 1:10)" Annotation: ""Sample Index: 240Sample Type: UnknownConcentration: N/ACalculated Conc: 141. ng/mLAcq. Date: 7/19/2011Acq. Time: 4:01:07 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 6Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 5135995 countsHeight: 6.86e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.3815.23Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 60 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a241" Sample ID: "GLP10-01-01-18-131" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 140R MS 110622 (dil 1:10)" Annotation: ""Sample Index: 241Sample Type: UnknownConcentration: N/ACalculated Conc: 223. ng/mLAcq. Date: 7/19/2011Acq. Time: 4:22:12 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 8041247 countsHeight: 1.12e+006 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.005.00e41.00e51.50e52.00e52.50e53.00e53.50e54.00e54.50e55.00e55.50e56.00e56.50e57.00e57.50e58.00e58.50e59.00e59.50e51.00e61.05e61.10e6

Intensity, cps15.3815.41Sample Name: "k110715a242" Sample ID: "GLP10-01-01-18-132" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 140R HS 110622 (dil 1:10)" Annotation: ""Sample Index: 242Sample Type: UnknownConcentration: N/ACalculated Conc: 567. ng/mLAcq. Date: 7/19/2011Acq. Time: 4:43:16 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 19828387 countsHeight: 2.84e+006 cpsStart Time: 15.1 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e6

Intensity, cps15.38Sample Name: "k110715a243" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 243Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 5:04:17 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.5 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 21562 countsHeight: 7.40e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.0317.4019.1916.8617.6116.0615.5018.2515.1715.0514.7114.4314.1614.041.3613.4512.5511.379.23Sample Name: "k110715a244" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 244Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 5:25:31 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 8578 countsHeight: 7.15e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e4

Intensity, cps16.7317.2916.5219.1616.0918.3515.3415.221.3614.5514.3014.161.2813.991.5313.2512.2511.069.51Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 61 of 70Printing Time: 12:19:10 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715a245" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 245Sample Type: QCConcentration: 2.50 ng/mLCalculated Conc: 2.41 ng/mLAcq. Date: 7/19/2011Acq. Time: 5:46:48 AMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 4397053 countsHeight: 6.58e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.43Sample Name: "k110715a246" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 246Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 6:08:04 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 13307 countsHeight: 7.07e+003 cpsStart Time: 15.4 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.5617.0916.8415.9115.6615.4519.2215.3714.7014.6714.3514.1513.9113.6812.4011.7310.579.355.018.43Sample Name: "k110715b244" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 248Sample Type: UnknownConcentration: N/ACalculated Conc: 0.00676 ng/mLAcq. Date: 7/19/2011Acq. Time: 9:03:43 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.5 minArea: 48843 countsHeight: 8.90e+003 cpsStart Time: 15.4 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps16.9917.1816.8315.5417.3814.8919.3214.2713.8218.2612.8111.9510.347.689.12Sample Name: "k110715b245" Sample ID: "11003-26-9" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "2.5 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 249Sample Type: QCConcentration: 2.50 ng/mLCalculated Conc: 2.50 ng/mLAcq. Date: 7/19/2011Acq. Time: 9:24:59 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 4556666 countsHeight: 6.96e+005 cpsStart Time: 15.3 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.43Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 62 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b246" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 250Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 9:46:14 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 21311 countsHeight: 7.34e+003 cpsStart Time: 15.3 minEnd Time: 15.4 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps16.8217.5215.6117.4219.2515.4215.1818.3314.9314.3814.1713.995.0113.5512.6710.908.27Sample Name: "k110715b247" Sample ID: "GLP10-01-01-18-135" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 141R 0 110630" Annotation: ""Sample Index: 251Sample Type: UnknownConcentration: N/ACalculated Conc: 1.59 ng/mLAcq. Date: 7/19/2011Acq. Time: 10:07:27 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 2918997 countsHeight: 3.67e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e5

Intensity, cps15.4415.26Sample Name: "k110715b248" Sample ID: "GLP10-01-01-18-136" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 141R DB 110630" Annotation: ""Sample Index: 252Sample Type: UnknownConcentration: N/ACalculated Conc: 1.57 ng/mLAcq. Date: 7/19/2011Acq. Time: 10:28:39 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2876040 countsHeight: 3.65e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e5

Intensity, cps15.4315.57Sample Name: "k110715b249" Sample ID: "GLP10-01-01-18-137" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 141R LS 110630" Annotation: ""Sample Index: 253Sample Type: UnknownConcentration: N/ACalculated Conc: 2.50 ng/mLAcq. Date: 7/19/2011Acq. Time: 10:49:54 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 4546065 countsHeight: 6.11e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.44Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 63 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b250" Sample ID: "GLP10-01-01-18-138" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 141R MS 110630" Annotation: ""Sample Index: 254Sample Type: UnknownConcentration: N/ACalculated Conc: 10.6 ng/mLAcq. Date: 7/19/2011Acq. Time: 11:11:06 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3854963 countsHeight: 5.68e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e5

Intensity, cps15.38Sample Name: "k110715b251" Sample ID: "GLP10-01-01-18-139" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 141R HS 110630 (dil 1:10)" Annotation: ""Sample Index: 255Sample Type: UnknownConcentration: N/ACalculated Conc: 91.6 ng/mLAcq. Date: 7/19/2011Acq. Time: 11:32:15 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 3354229 countsHeight: 5.07e+005 cpsStart Time: 15.2 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e54.2e54.4e54.6e54.8e55.0e5

Intensity, cps15.39Sample Name: "k110715b252" Sample ID: "GLP10-01-01-18-140" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 142R 0 110622 (dil 1:10)" Annotation: ""Sample Index: 256Sample Type: UnknownConcentration: N/ACalculated Conc: 50.1 ng/mLAcq. Date: 7/19/2011Acq. Time: 11:53:17 AMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1857178 countsHeight: 2.41e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e52.4e5

Intensity, cps15.3815.2416.7317.39Sample Name: "k110715b253" Sample ID: "GLP10-01-01-18-141" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 142R DB 110622 (dil 1:10)" Annotation: ""Sample Index: 257Sample Type: UnknownConcentration: N/ACalculated Conc: 51.4 ng/mLAcq. Date: 7/19/2011Acq. Time: 12:14:21 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 1903540 countsHeight: 2.39e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e52.4e5

Intensity, cps15.3715.2216.7417.41Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 64 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b254" Sample ID: "GLP10-01-01-18-142" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 142R LS 110622 (dil 1:10)" Annotation: ""Sample Index: 258Sample Type: UnknownConcentration: N/ACalculated Conc: 50.9 ng/mLAcq. Date: 7/19/2011Acq. Time: 12:35:22 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1883286 countsHeight: 2.32e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e5

Intensity, cps15.3816.6617.1715.1719.14Sample Name: "k110715b255" Sample ID: "GLP10-01-01-18-143" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 142R MS 110622 (dil 1:10)" Annotation: ""Sample Index: 259Sample Type: UnknownConcentration: N/ACalculated Conc: 57.5 ng/mLAcq. Date: 7/19/2011Acq. Time: 12:56:20 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2123043 countsHeight: 2.80e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e5

Intensity, cps15.3915.2616.9417.52Sample Name: "k110715b256" Sample ID: "GLP10-01-01-18-144" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 142R HS 110622 (dil 1:10)" Annotation: ""Sample Index: 260Sample Type: UnknownConcentration: N/ACalculated Conc: 144. ng/mLAcq. Date: 7/19/2011Acq. Time: 1:17:18 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 5245686 countsHeight: 7.33e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e5

Intensity, cps15.4215.27Sample Name: "k110715b257" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 261Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 1:38:18 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.6 minArea: 4532 countsHeight: 6.40e+003 cpsStart Time: 15.6 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps16.8719.1817.0216.6615.7715.5018.2815.2615.1914.8014.5614.4513.9113.1912.5711.299.08Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 65 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b258" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 262Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 1:59:24 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.9 minArea: 7817 countsHeight: 6.08e+003 cpsStart Time: 15.9 minEnd Time: 15.9 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps16.6217.0419.1917.3016.3816.0615.1218.2814.9714.5214.0813.9613.4212.335.0010.746.968.40Sample Name: "k110715b259" Sample ID: "11003-26-11" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "10 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 263Sample Type: QCConcentration: 10.0 ng/mLCalculated Conc: 9.87 ng/mLAcq. Date: 7/19/2011Acq. Time: 2:20:38 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 17345305 countsHeight: 2.55e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e52.0e53.0e54.0e55.0e56.0e57.0e58.0e59.0e51.0e61.1e61.2e61.3e61.4e61.5e61.6e61.7e61.8e61.9e62.0e62.1e62.2e62.3e62.4e62.5e6

Intensity, cps15.45Sample Name: "k110715b260" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 264Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 2:41:51 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.7 minArea: 14730 countsHeight: 6.95e+003 cpsStart Time: 15.7 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.3817.1117.6417.0016.8116.4415.6819.3615.0914.8814.5114.1213.5813.4512.3011.085.019.728.55Sample Name: "k110715b261" Sample ID: "GLP10-01-01-18-145" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 143R 0 110622 (dil 1:10)" Annotation: ""Sample Index: 265Sample Type: UnknownConcentration: N/ACalculated Conc: 23.3 ng/mLAcq. Date: 7/19/2011Acq. Time: 3:03:02 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 5Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 4252765 countsHeight: 5.53e+005 cpsStart Time: 15.1 minEnd Time: 15.7 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e53.0e53.2e53.4e53.6e53.8e54.0e54.2e54.4e54.6e54.8e55.0e55.2e55.4e5

Intensity, cps15.4215.40Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 66 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b262" Sample ID: "GLP10-01-01-18-146" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 143R DB 110622 (dil 1:10)" Annotation: ""Sample Index: 266Sample Type: UnknownConcentration: N/ACalculated Conc: 24.8 ng/mLAcq. Date: 7/19/2011Acq. Time: 3:24:21 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 4516701 countsHeight: 5.64e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e5

Intensity, cps15.4215.28Sample Name: "k110715b263" Sample ID: "GLP10-01-01-18-147" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 143R LS 110622 (dil 1:10)" Annotation: ""Sample Index: 267Sample Type: UnknownConcentration: N/ACalculated Conc: 25.5 ng/mLAcq. Date: 7/19/2011Acq. Time: 3:45:32 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 4640869 countsHeight: 5.99e+005 cpsStart Time: 15.2 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e5

Intensity, cps15.40Sample Name: "k110715b264" Sample ID: "GLP10-01-01-18-148" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 143R MS 110622 (dil 1:10)" Annotation: ""Sample Index: 268Sample Type: UnknownConcentration: N/ACalculated Conc: 33.1 ng/mLAcq. Date: 7/19/2011Acq. Time: 4:06:47 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 5994380 countsHeight: 8.06e+005 cpsStart Time: 15.1 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e5

Intensity, cps15.4315.30Sample Name: "k110715b265" Sample ID: "GLP10-01-01-18-149" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 143R HS 110622 (dil 1:10)" Annotation: ""Sample Index: 269Sample Type: UnknownConcentration: N/ACalculated Conc: 117. ng/mLAcq. Date: 7/19/2011Acq. Time: 4:28:01 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 20382201 countsHeight: 2.88e+006 cpsStart Time: 15.2 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e54.0e56.0e58.0e51.0e61.2e61.4e61.6e61.8e62.0e62.2e62.4e62.6e62.8e6

Intensity, cps15.43Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 67 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b266" Sample ID: "GLP10-01-01-18-150" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 144S 0 110628 (dil 1:10)" Annotation: ""Sample Index: 270Sample Type: UnknownConcentration: N/ACalculated Conc: 52.1 ng/mLAcq. Date: 7/19/2011Acq. Time: 4:49:12 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 4Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1927318 countsHeight: 2.35e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e5

Intensity, cps15.3615.2517.1017.51Sample Name: "k110715b267" Sample ID: "GLP10-01-01-18-151" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 144S DB 110622 (dil 1:10)" Annotation: ""Sample Index: 271Sample Type: UnknownConcentration: N/ACalculated Conc: 49.0 ng/mLAcq. Date: 7/19/2011Acq. Time: 5:10:18 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1816698 countsHeight: 2.24e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e5

Intensity, cps15.3615.2315.5017.0419.14Sample Name: "k110715b268" Sample ID: "GLP10-01-01-18-152" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 144S LS 110622 (dil 1:10)" Annotation: ""Sample Index: 272Sample Type: UnknownConcentration: N/ACalculated Conc: 51.2 ng/mLAcq. Date: 7/19/2011Acq. Time: 5:31:20 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 1895993 countsHeight: 2.36e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01.0e42.0e43.0e44.0e45.0e46.0e47.0e48.0e49.0e41.0e51.1e51.2e51.3e51.4e51.5e51.6e51.7e51.8e51.9e52.0e52.1e52.2e52.3e5

Intensity, cps15.3715.2416.6717.32Sample Name: "k110715b269" Sample ID: "GLP10-01-01-18-153" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 144S MS 110622 (dil 1:10)" Annotation: ""Sample Index: 273Sample Type: UnknownConcentration: N/ACalculated Conc: 60.3 ng/mLAcq. Date: 7/19/2011Acq. Time: 5:52:20 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.4 minArea: 2224801 countsHeight: 2.80e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.02.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e52.0e52.2e52.4e52.6e52.8e5

Intensity, cps15.3715.2217.5316.97Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 68 of 70Printing Time: 12:19:11 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b270" Sample ID: "GLP10-01-01-18-154" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "DAL GW 144S HS 110622 (dil 1:10)" Annotation: ""Sample Index: 274Sample Type: UnknownConcentration: N/ACalculated Conc: 138. ng/mLAcq. Date: 7/19/2011Acq. Time: 6:13:20 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ValleyRetention Time: 15.4 minArea: 5015176 countsHeight: 6.96e+005 cpsStart Time: 15.1 minEnd Time: 15.6 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e5

Intensity, cps15.3615.23Sample Name: "k110715b271" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 275Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 6:34:19 PMModified: NoProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.7 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 6774 countsHeight: 5.89e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps17.0816.7717.3616.4916.4515.3717.5719.1515.4614.9214.7914.4214.0113.7413.2212.0210.819.485.01Sample Name: "k110715b272" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 276Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 6:55:26 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: Base To BaseRetention Time: 15.5 minArea: 2572 countsHeight: 5.79e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e41.7e4

Intensity, cps16.7417.0917.4416.5617.5516.4419.2115.3815.4918.2715.1914.7314.5514.2314.0913.7812.9111.3510.98Sample Name: "k110715b273" Sample ID: "11003-26-10" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "5.0 ng/mL FC std in Milli Q Water" Annotation: ""Sample Index: 277Sample Type: QCConcentration: 5.00 ng/mLCalculated Conc: 5.04 ng/mLAcq. Date: 7/19/2011Acq. Time: 7:16:36 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 2Report Largest Peak: YesMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.4 minArea: 9041166 countsHeight: 1.31e+006 cpsStart Time: 15.3 minEnd Time: 15.8 min0 2 4 6 8 10 12 14 16 18 20Time, min0.05.0e41.0e51.5e52.0e52.5e53.0e53.5e54.0e54.5e55.0e55.5e56.0e56.5e57.0e57.5e58.0e58.5e59.0e59.5e51.0e61.1e61.1e61.2e61.2e61.3e61.3e6

Intensity, cps15.42Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 69 of 70Printing Time: 12:19:12 PMPrinting Date: Wednesday, July 20, 2011Sample Name: "k110715b274" Sample ID: "Solvent Blank" File: "k110715a.wiff"Peak Name: "PFOA" Mass(es): "413.000/369.000 Da,413.000/219.000 Da,413.000/169.000 Da"Comment: "Milli Q Water TN11-0234" Annotation: ""Sample Index: 278Sample Type: UnknownConcentration: N/ACalculated Conc: < 0Acq. Date: 7/19/2011Acq. Time: 7:37:54 PMModified: YesProc. Algorithm: Specify Parameters - MQ IIINoise Percentage: 90Base. Sub. Window: 1.00 minPeak-Split. Factor: 3Report Largest Peak: NoMin. Peak Height: 0.00 cpsMin. Peak Width: 0.00 secSmoothing Width: 0 pointsRT Window: 30.0 secExpected RT: 15.4 minUse Relative RT: NoInt. Type: ManualRetention Time: 15.5 minArea: 14726 countsHeight: 7.55e+003 cpsStart Time: 15.5 minEnd Time: 15.5 min0 2 4 6 8 10 12 14 16 18 20Time, min0.01000.02000.03000.04000.05000.06000.07000.08000.09000.01.0e41.1e41.2e41.3e41.4e41.5e41.6e4

Intensity, cps16.9117.6016.6915.9315.6719.1715.4915.2314.8414.6114.1713.9913.8313.0412.3110.737.73Workstation: ETSKIRKResults Name: k110715a.rdbData worked up by KJUPage 70 of 70Printing Time: 12:19:12 PMPrinting Date: Wednesday, July 20, 2011