Attachment O 

Base G4 

Attainment Demonstration Data 

2009 Best & Final Emission 

Inventory 
Key

Ozone site only -- No PM data -- not SMAT data

Site omitted per state recommendation

2005 not yet available -- incomplete calculation

Modeled CY and FY data filled in by Environ

NH4

DON*so4 + .29*no3 ; where DON is the degree of neutralization = NH4/SO4; and was aquired 

from the SMAT tool

PBW Particle Bound Water =

(-0.002618) + (0.980314*nh4) + (-0.260011*no3) + (-0.000784*so4)+ (-0.159452*nh4^2) + (-

0.356957*no3*nh4) + (0.153894*no3^2)+ (0.212891*so4*nh4) + (0.044366*so4*no3) + (-

0.048352*so4^2)

Sheets Description

Sites_used_SMAT

Information on the sites as gathered from the SMAT tool. Includes DON and % compostions for 

each quarter

Sites_used_PM_DVC Inforation used to calculate the DVC -- this is where ARS would add any new PM data

CY modeled - PM

Environ entered the component data from model for base year/current year (CY-2002gt2a); 

formulas calculate NH4 and PBW

FY modeled - PM

Environ added the component data from the model for future year (FY -2009g4a) to the Red 

highlighted columns; Yellow columns are calcualted

RRF-DVF_data Calculates the needed RRFs and DVFs; 
Sited_used_SMAT

AIRS ID State County Pollutant(s) Site Name City Name County Name MSA Latitud47-009-0011 TN Blount PM2.5 Maryville Blount Knoxville,TN 47-093-0028 TN Knox PM2.5 Knoxville Knox Knoxville,TN 47-093-1013 TN Knox PM2.5 Knoxville Knox Knoxville,TN 47-093-1017 TN Knox PM2.5 Knoxville Knox Knoxville,TN 47-093-1020 TN Knox O3 and PM2.5 Knoxville Knox Knoxville,TN 47-105-0108 TN Loudon O3 and PM2.5 Loudon Loudon Knoxville,TN 47-145-0004 TN Roane PM2.5 Harriman Roane 

Page 2 of 32
Sited_used_SMAT

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1013 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

AIRS ID Speciated profile in SMAT 3 yrs of data O

47-009-0011 YES Used for PM on

47-093-0028 YES Used for PM on

47-093-1013 Use 47-093-1020 profile, Used for PM on47-093-1017 YES Used for PM on

47-093-1020 YES YES 47-105-0108 Use 47-093-1020 profile, no data 2003 47-145-0004 YES Used for PM on

Page 3 of 32
Sited_used_SMAT

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1013 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

Verified by 

State

Site/Parameter Shut Down blank qtr donQ1 frac. Crustal frac. 

USE 0.5 1 0.2894 0.01993726 0.03USE 0.5 1 0.2894 0.017059553 0.034

DO NOT USE PM2.5 0.5 1 0.28777 0.020411215 0.04

USE 0.5 1 0.2894 0.016424797 0.03USE 0.5 1 0.28777 0.020411215 0.04USE 0.5USE 0.5 1 0.28854 0.02401104 0.04

Page 4 of 32
Sited_used_SMAT

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1013 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

frac NO3 frac NH4 frac H2O Q donQ2 frac. Crustal frac. EC Frac O0.013594 0.066886 0.06087 2 0.29103 0.045003934 0.03 0.42030.011632 0.057232 0.052085 2 0.29103 0.043969676 0.02931 0.43360.017271 0.063746 0.056577 2 0.29476 0.040538721 0.03282 0.44550.011199 0.055102 0.050147 2 0.29103 0.041886629 0.02792 0.46040.017271 0.063746 0.056577 2 0.29476 0.040538721 0.03282 0.44550.031125 0.08113 0.069212 2 0.29827 0.05551858 0.03389 0.3834

Page 5 of 32
Sited_used_SMAT

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1013 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

frac NH4 frac H2O Q donQ3 frac. Crustal frac. EC Frac OC frac.SO0.093269 0.090898 3 0.27318 0.038482759 0.02298 0.313222 0.409940.091126 0.088809 3 0.27318 0.038187845 0.02281 0.318486 0.406800.089521 0.087885 3 0.27351 0.029368248 0.02311 0.399891 0.358670.086809 0.084602 3 0.27318 0.034244456 0.02045 0.388861 0.364790.089521 0.087885 3 0.27351 0.029368248 0.02311 0.399891 0.358670.098706 0.09749 3 0.28146 0.052046263 0.02776 0.256028 0.42851

Page 6 of 32
Sited_used_SMAT

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1013 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

frac H2O Q donQ4 frac. Crustal frac. EC Frac OC frac.SO4 frac NO0.102685 4 0.27378 0.026580035 0.0443 0.477774 0.277318 0.020370.101898 4 0.27378 0.023213825 0.03869 0.543911 0.242198 0.017790.090231 4 0.27255 0.021746376 0.05324 0.486635 0.260207 0.031490.091375 4 0.27378 0.022523912 0.03754 0.557466 0.234999 0.017260.090231 4 0.27255 0.021746376 0.05324 0.486635 0.260207 0.031490.114298 4 0.28405 0.032684426 0.05249 0.373195 0.31793 0.03664

Page 7 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s) Site Name City Name County Name MSA47-009-0011 TN Blount PM2.5 Maryville Blount Knoxvill

47-093-0028 TN Knox PM2.5 Knoxville Knox Knoxvill

47-093-1013 TN Knox PM2.5 Knoxville Knox Knoxvill

47-093-1017 TN Knox PM2.5 Knoxville Knox Knoxvill

47-093-1020 TN Knox O3 and PM2.5 Knoxville Knox Knoxvill

47-105-0108 TN Loudon O3 and PM2.5 Loudon Loudon Knoxvill

47-145-0004 TN Roane PM2.5 Harriman Roane 

Page 8 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

Latitude Longitude AIRS ID

Speciated profile in 

SMAT 

35.768333 -83.942222 47-009-0011 YES 

35.943611 -84.038889 47-093-0028 YES 

35.98055 -83.93277 47-093-1013 NO 

35.975 -83.954444 47-093-1017 YES 

36.01944 -83.87361 47-093-1020 YES 

35.7447 -84.3174 47-105-0108 NO 

35.9386 -84.5438 47-145-0004 YES 

Page 9 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

3 yrs of data 

PM25

Verified by 

State

Site/Parameter Shut Down 2000 - Q1 2000 - 

YES USE 18.959 YES USE 16.552 17.933 

2004 incomplete DO NOT USE PM2.5

YES USE 18.651 19.883 YES USE 15.389 18.315 

2003 incomplete USE

YES USE 14.550 15.876 

Page 10 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

2000 - Q4 2001 - Q1 2001 - Q2 2001 - Q3 2001 - Q4 2002 - Q1 218.579 15.353 14.873 18.452 11.011 11.535 119.815 13.921 16.553 20.471 11.904 13.396 1

1

20.412 14.999 17.720 21.533 15.572 13.894 119.553 15.299 18.529 20.528 13.521 13.238 120.335 12.383 16.361 20.761 11.404 11.745 1

Page 11 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

2002 - Q4 2003 - Q1 2003 - Q2 2003 - Q3 2003 - Q4 2004 - Q1 211.787 11.686 14.393 18.850 10.635 10.326 113.423 12.960 15.262 18.313 10.883 10.978 112.740 14.385 16.400 20.589 12.743 11.75013.819 12.807 14.813 21.460 12.979 13.400 113.836 12.014 13.363 19.826 11.961 12.488 1

11.285 1

10.597 10.900 12.174 19.186 10.969 9.970 1

Page 12 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

2004 - Q4 2005 - Q1 2005 - Q2 2005 - Q3 2005 - Q4 2000-2002 Q1 12.147 13.444 12.417 14.623 13.687 15.848 13.048 14.642 12.16712.837 12.893 

Page 13 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

2000-2002 Q3 2000-2002 Q4 2001-2003 Q1 2001-2003 Q2 2001-2018.292 13.792 12.858 14.811 18.837 19.385 15.047 13.426 15.775 19.380 20.454 12.740 14.385 16.883 20.521 21.258 16.601 13.900 16.263 21.506 20.296 15.636 13.517 15.978 20.542 18.487 14.112 11.676 14.301 19.246 

Page 14 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

2002-2004 Q1 2002-2004 Q2 2002-2004 Q3 2002-2004 Q4 2003-2011.182 14.548 18.497 11.523 11.006 12.445 15.151 18.359 12.241 11.969 13.067 16.883 20.521 12.741 13.067 13.367 15.329 20.447 13.495 13.104 12.580 14.682 20.193 12.948 12.251 11.285 15.960 19.270 12.167 11.285 10.872 13.946 18.342 11.468 10.435 

Page 15 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

2003-2005 Q3 2003-2005 Q4 2000-2004 Q1 2000-2004 Q2 2000-218.141 11.391 11.995 14.730 1817.862 11.650 12.998 15.364 1820.589 12.743 13.226 16.544 1919.908 13.333 13.872 16.015 2019.654 12.504 13.080 15.596 1919.270 12.167 10.785 15.460 1818.617 11.903 11.313 14.094 18

Page 16 of 32
Sited_used_PM_DVC

AIRS ID State County Pollutant(s)47-009-0011 TN Blount PM2.5

47-093-0028 TN Knox PM2.5

47-093-1013 TN Knox PM2.5

47-093-1017 TN Knox PM2.5

47-093-1020 TN Knox O3 and PM2.5

47-105-0108 TN Loudon O3 and PM2.5

47-145-0004 TN Roane PM2.5

# Q used

1920

8

2020

4

20

Page 17 of 32
CY modeled - PM

AIRS ID State County Pollutant(s) Crustal EC OC SO4 NO3 Crustal 

47-009-0011 TN Blount PM2.5 2.2075 0.5429 2.6069 2.3923 1.2188 1.6

47-093-0028 TN Knox PM2.5 2.1038 0.6328 2.6089 2.4472 1.4701 1.7

47-093-1017 TN Knox PM2.5 2.1716 0.6177 2.5562 2.4299 1.4143 1.7

47-093-1020 TN Knox O3 and PM2.5 1.8081 0.5864 2.4076 2.3976 1.4849 1.4

47-105-0108 TN Loudon O3 and PM2.5 1.7759 0.4886 2.6714 2.4011 1.4274 1.2

47-145-0004 TN Roane PM2.5 1.4830 0.3845 2.4494 2.2909 1.2631 1.0

Q1 

Page 18 of 32
CY modeled - PM

AIRS ID State County Pollutant(s)

47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

SO4 NO3 Crustal EC OC SO4 

4.1760 0.3716 1.8627 0.4138 4.3430 7.1444 4.4061 0.4199 1.9315 0.5414 4.4561 7.5263 4.3001 0.4100 1.9045 0.5058 4.3632 7.3351 4.3446 0.4289 1.4785 0.4787 4.2044 7.3496 4.3180 0.4359 1.5019 0.3870 4.6275 7.3606 4.2440 0.3901 1.0907 0.2564 3.9815 7.0300 

Q3

Page 19 of 32
CY modeled - PM

AIRS ID State County Pollutant(s)

47-009-0011 TN Blount PM2.547-093-0028 TN Knox PM2.547-093-1017 TN Knox PM2.547-093-1020 TN Knox O3 and PM2.547-105-0108 TN Loudon O3 and PM2.547-145-0004 TN Roane PM2.5

EC OC SO4 NO3

0.5407 2.6779 3.4079 1.67520.6406 2.6503 3.5254 1.98140.6235 2.6167 3.4717 1.90830.5788 2.4350 3.4397 1.98760.4675 2.6961 3.4696 2.08520.3331 2.3465 3.2712 1.7693

Q4

Page 20 of 32