*E nte'rgy 4'. Entergy Nuclear Operations, Inc.

Palisades Nuclear Plant

27780 Blue Star Memorial Highway

Covert, Ml 49043

May 10, 2007 10 CFR 50, Appendix I

Technical Specification 5.6.2

U. S. Nuclear Regulatory Commission

ATTN: Document Control Desk

Washington, DC 20555-0001

Palisades Nuclear Plant

Dockets 50-255 and 72-7

License No. DPR-20

2006 Radiolociical Environmental Operatina Report

Entergy Nuclear Operations, Inc., is submitting the attached Radiological Environmental

Operating Report for the Palisades Nuclear Plant. This report was prepared in

accordance with the requirements of 10 CFR 50, Appendix I, Sections IV.B.2, IV.B.3,

IV.C, and Technical Specification 5.6.2. The period covered by the enclosed report is

January 1, 2006, through December 31, 2006.

Summary of Commitments

This letter contains no new commitments and no revisions to existing commitments.

Q$ 'A S'_-

Christopher J. Schwarz

Site Vice President

Palisades Nuclear Plant

CC Administrator, Region Ill, USNRC

Project Manager, Palisades, USNRC

Resident Inspector, Palisades, USNRC

Enclosure

25-

ý-,f -S-5
ENCLOSURE 1

ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT

JANUARY 1, 2006 THROUGH DECEMBER 31, 2006

TABLE OF CONTENTS

1. INTRODUCTION .............................................................................. 1

I1. NON-ROUTINE REPORTS ........................................................... ... 1

II1. DISCUSSION AND INTERPRETATION OF RESULTS

A . A ir S am ples ..................................................................... ....... 1

B . Lake W ate r ........................................................................... 2

C . D rinking W ate r .................................................................. ..... 2

D . W ell W ater .................................................................. 3

E . M ilk ................................................................................. . ....... 3

F. TLDs - Gamma Dose ........................................................... 3

G . C ro p s ..................................................................................... . 4

H . S ed im e nt ......................................................................... . ....... 5

I. F is h ................................................................................ . ..... 5

J. Broad Leaf Vegetation ......................................................... 5

K. Non-Routine Samples ............................................................. 5

L. Gaseous and Liquid Radwaste Effluent Composite Samples. 6

IV. ASSESSMENT OF PALISADES OPERATION

ENVIRONMENTAL IMPACT ........................................................... 6

V. TABLES

A. Table 10.4-1 Sampling and Analysis Summary .................... 7

B. Table 10.4-2 Sample Data Summary ................................... 8

C. Table 10.4-3 Greatest Mean Sampling Location ................... 10

VI. ATTACHMENTS

A. Sample Collection Anomalies

B. Palisades Land Use Census

C. Health Physics Procedure HP 10.10, "Palisades Radiological

Environmental Program Sample Collection and Shipment"

D. Palisades 2006 Final Report - Radiological Environmental Monitoring

Program (REMP)*as provided by Environmental, Inc., Midwest Laboratory

E. Environmental, Inc., Midwest Laboratory, Interlaboratory Comparison

Program Results

Page i of ii
TABLE OF CONTENTS (CONTINUED)

F. Data Graphs

1. Palisades Air Particulate (gross beta), Operational Comparison

Graphs, 1968-1969 (pre-op) and 2000-2006

2. Palisades Lake Water (Ludington Control vs. Intake, South Haven

Treated and Raw), 2000-2006 in gross beta trending

3. Palisades TLD Quarterly Palisades Operational Comparison

Graph, 1968-1969 and 2000-2006

Page ii of ii
I. INTRODUCTION

The Radiological Environmental Operating Report provides a summary and data

interpretation of the Palisades Nuclear Plant (PNP) Radiological Environmental

Monitoring Program, as conducted during the 2006 reporting period. This report

was prepared in accordance with the requirements of 10 CFR 50, Appendix I,

Sections IV.B.2, IV.B.3, IV.C, and Technical Specification 5.6.2.

Detailed sample station identification and location information can be found in

Attachment 2 of Health Physics Procedure HP 10.10, "Palisades Radiological

Environmental Program Sample Collection and Shipment." HP 10.10 is included as

Attachment C. The results of all environmental samples collected are evaluated as

follows:

A. Air iodine and particulate and thermoluminescent dosimetry (TLD) data

were statistically evaluated at the 95% confidence level. The data were

compared against two criteria. The first criterion is the statistical

difference, which indicates whether the sample results from near sites are

greater than those from control sites, and whether or not the difference is

significant (e.g., statistical "T-Test" of indicator vs. control results).

If the T-Test concludes that the control and indicator populations are

statistically different and the indicator populations are higher, then the

evaluation level (twice the statistical difference) is computed. This is the

minimum difference in the population means for which a corresponding

difference in sample means will exceed the statistical difference with 95%

confidence. If the evaluation level is exceeded, then correlation of the

results with effluent releases is performed.

B. If a sufficient number of positive sample results were available (e.g., >1

control and > 1 indicator) then well water, lake water, sediment, fish, and

other aquatic biota samples were evaluated using data mean

comparisons and the PNP Offsite Dose Calculation Manual (ODCM),

Appendix A, reporting limits.

I1. NON-ROUTINE REPORTS

Non-routine reportable events did not occur during this reporting period.

III. DISCUSSION AND INTERPRETATION OF RESULTS

A. Air Samples

There were 258 air samples collected and analyzed for gross beta and

1-131. Air iodine/particulate samples are collected weekly from five airsampling locations. Air is metered into the sampling unit at an

Page 1 of 10
approximate one cubic foot per minute flow rate through a Radeco 47-mm

air filter (air particulate) and a HI-Q air iodine cartridge. Both filters are inline with each other and housed within the same filter holder. Weekly

samples were sent to Environmental, Inc., Midwest Laboratory for

analysis.

Statistical analysis of the airborne particulate sample data, between the

four near-site indicator locations and the control location, demonstrated

no statistical difference. The mean values of gross beta results for

indicator and control locations were 0.026 pCi/m 3, and 0.028 pCi/m 3,

respectively. The control station 10-GR had the highest annual mean for

gross beta results at 0.028 pCi/m 3. No trends in gross beta results are

discernable when compared to previous years' sample results.

All 1-131 activity results were below the Minimum Detectable Activity

(MDA) levels.

B. Lake Water (Surface Water)

Palisades lake water inlet, South Haven Municipal Raw and Ludington

lake water inlet water samples were collected daily and combined into

monthly composite samples. One gallon of Palisades Lake-In (1 -ST) and

Ludington Lake-in (32-LP) and two gallons of South Haven Municipal Raw

(25-SH) were sent to Environmental, Inc., Midwest Laboratory for analysis

each month. No treatment of the water samples with preservative is

required. Thirty-six monthly lake water composite samples collected from

the three locations were analyzed for gross beta and tritium.

No statistical difference was found between the indicator and the control

location samples and no PNP ODCM Appendix A reporting limits were

exceeded.

C. Drinking Water

Water samples from South Haven Municipal Water System (25-SH

Treated), and Ludington Lake-in (32-LP), were collected daily and

combined into separate monthly composite samples. (The South Haven

Treated is obtained at the PNP site.) One gallon of the Ludington Lake-in

and South Haven treated samples (twenty-four total) were sent to

Environmental, Inc., Midwest Laboratory for beta and tritium analysis. No

treatment of water samples with preservative is required.

No statistical difference was found in the beta results between the

indicator and the control location samples and no PNP ODCM Appendix A

reporting limits were exceeded.

Page 2 of 10
D. Well Water

Two one-gallon well samples are taken quarterly from each of the three

monitoring wells adjacent to the steam generator storage facility (41 -ST,

42-ST and 43-ST). Twelve total samples were sent to Environmental, Inc.,

Midwest Laboratory for beta and tritium analysis. No treatment of water

samples with preservative is required.

Tritium was detected in the fourth quarter well # 15 sample (42-ST) at a

level of 300 pCi/L. A gross beta value of 11.4 pCi/L was detected in the

third quarter well # 16 sample (43-ST). As this value was greater than

10 pCi/L, a follow up gamma analysis was performed, and showed less

than minimum detectable activity values for gamma emitters. Note that

these wells are not associated with any drinking water supply.

E. Milk

Two one-gallon quantities of raw milk (grab sample) are obtained per

sample location per month from dairy milk holding tanks. Each sample

quantity is treated with a sodium bisulfate preservative prior to being sent

to Environmental, Inc., Midwest Laboratory for analysis.

Forty-eight monthly milk samples were collected from the four dairy farms

(stations 26-JH, 27-DH, 28-DC and 29-WS).

No milk analysis identified activity above the minimum detectable level,

with the exception of naturally occurring potassium-40.

F. TLDs - Gamma Dose

Environmental gamma doses are measured quarterly by placement of

TLDs at each designated location. Each TLD badge contains a 4-zone

Calcium Sulfate (CaSO4) wafer (the wafer includes an additional

backup/reserve readout zone). Sensitivity for the multi-zone TLDs is 10

millirem, with a linear response of 0.1 millirem to 1000 rem.

The PNP gamma assessment program consists of 29 locations. There is

a total of 16 inner ring TLDs, including one on-site, nine near-site and six

steam generator storage facility locations. There are ten outer ring TLD

locations (1.0 to 5.5 miles out) and three control TLDs (30 to 55 miles

out). A 30 h TLD is placed in a lead storage cave (location number 22),

and is used as a control for in-transit dose monitoring and subtraction.

There were 115 TLDs collected and analyzed during 2006. The one onsite TLD location (1-ST) serves as an individual reference TLD; however,

Page 3 of 10
it was evaluated along with the inner ring (site boundary) TLDs in the

statistical evaluation.

The TLD data evaluations were performed by comparing the inner ring

TLDs (site boundary locations 1, 13-21 and 33-38), and the outer ring

TLDs (locations 2-9, 23 and 24), against the control TLD locations (10, 11,

12).

For 2006, the quarterly average gamma readings (mR) were Inner Ring -

12.5, Outer Ring - 14.5 and Control - 14.8

The highest average dose was observed at outer ring station number 2

(5.6 miles south) with a dose of 17.6 mrem.

Statistical analysis demonstrated that inner ring vs. control TLDs were two

different populations. However, the control mean was greater than the

inner ring mean. There was no statistical difference between the outer ring

and control populations. No trends are discernable when comparing inner

ring with outer ring and control TLD results. Overall, outer ring TLD mean

results are consistently higher than inner ring TLD mean results, and

control station TLD mean results are slightly higher than outer ring mean

results. (The likely reason for the lower results seen for the site perimeter

locations is that these TLDs are placed in wooded areas and thus

shielded to some degree from cosmic background radiation.)

G. Crops

Food crop samples are collected when available, and in season. Two

principal area crops, apples and blueberries, are regularly collected.

Approximately 1 kg of sample is placed in a sealable plastic bag for

shipment to Environmental, Inc., Midwest Laboratory. No special

treatment of the samples with a preservative is necessary.

Three crop samples were collected. Blueberries and apples were

collected at indicator station 4-JS (3.5 miles SE), and apples at a control

station located in the least prevalent wind direction, approximately 11

miles NNE. (Control blueberries were lost during shipment.),

No crop analysis identified activity above the Minimum Detectable Activity

for either 1-131 or gamma emitters.

Page 4 of 10
H. Sediment

Sediment samples are collected semi-annually from each designated

location. No treatment of the samples with a preservative is necessary

prior to shipment to Environmental, Inc., Midwest Laboratory.

Four sediment samples were collected from two locations. Two were

obtained from Palisades, 30-STN (0.5 miles north of discharge), and two

from the Ludington Control Station (32-LP).

No sediment analysis identified any gamma activity.

1. Fish

Fish samples are collected semi-annually. Samples consist of two species

of commercially and/or recreational important species near the plant

discharge area. One sample of the same species in an area not

influenced by plant discharge is collected. Each one-liter quantity of fish

sample is prepared for shipment to Environmental, Inc., Midwest

Laboratory. Each sample is frozen for preservation.

Seven individual fish samples were collected from two locations. Three

indicator samples were obtained from Palisades (1-ST discharge) and

four control samples were obtained from Ludington Station (32-LP).

Cs-137 was the only gamma emitter detected and was seen in two

indicator samples and two control samples. The average values were

0.049 pCi/g and 0.044 pCi/g respectively. No trends in Cs-137 are

discernable when compared to previous years' sample results. The

ODCM reporting limit for Cs-137 is 2000 pCi/kg (2 pCi/gm).

J. Broad Leaf Veqetation

No broad leaf vegetation samples were collected from the surrounding

PNP environs during 2006. The collection of broad leaf vegetation

samples serves as a backup and/or alternative sampling medium in case

any milk sampling location(s) become(s) unavailable.

K. Non-Routine Samples

There were no non-routine samples collected during this reporting period.

Page 5 of 10
L. Gaseous and Liauid Radwaste Effluent Composite Samples

Both the gaseous and liquid radwaste effluent composite samples are

collected monthly and sent to Teledyne Brown for analysis. No special

sample treatment with a preservative is required prior to laboratory

analysis. The liquid effluent composite sample is based on a specific

amount of sample collected, per total batch volume release. The gaseous

radwaste effluent weekly composite sample results are based on

analyzing weekly stack gas filters.

Although not a direct reporting component in the PNP Annual Radiological

Environmental Operating Report, results of the gaseous and liquid

monthly radwaste effluent composite samples are evaluated against

overall environmental trending data. This evaluation is the basis for

determining isotopic dispersion and deposition patterns within the

surrounding environs of PNP. All gaseous and liquid effluent results are

compared to the PNP ODCM, Appendix A, reporting levels. All isotopic

lower limits of detection (LLDs) were met.

IV. ASSESSMENT OF PALISADES OPERATION ENVIRONMENTAL IMPACT

In reviewing the 2006 PNP radiological environmental monitoring data, and

comparing it to previous operational and pre-operational data, all trending

parameters continue to indicate that the operation of PNP has minimal

environmental impact. Most isotopic activity is at environmental background

levels. Evidence of an overall environmental isotopic buildup (attributable to

plant effluents) remains negligible as well. In most instances, sample analytical

results were below previously established environmental background levels.

Page 6 of 10
Table HP 10.4-1

Sample Data Summary

Palisades Nuclear Plant, Van Buren County. MI Docket 50-255

Annual Radioloqical Environmental Operatinci Report

January 1, 2006 to December 31, 2006

Number of

Collection Samples Frequency of

Medium Description Location Collected Type of Analysis Analysis

Continuous at appx

Air 1 cfm Stations 4, 5, 8, 9 and 10 258 Gross Beta, 1-131 Weekly

Lake Intake and South Haven Gross Beta, Tritium (Tritium not done

Lake Water 1 gallon composite Raw 24 on South Haven Raw) Monthly

Lake Water -

Control 1 gallon composite Ludington Lake In 12 Gross Beta, Tritium, Sr-89 and Sr-90 Monthly

Drinking Water 1 gallon composite South Haven Municipal 12 Gross Beta, Tritium Monthly

Three sites adjacent to Interim

Well Water 2 gallons grab Steam Generator Storage Facility 12 Gross Beta, Tritium Quarterly

Shine Farm, D Hessey, D Gamma isotopic, 1-131 and other

Milk 2 gallons grab Carpenter & J Hay Dairy Farms 48 isotopic Monthly

TLD Continuous Inner Ring, Outer Ring, Controls 115 Gamma dose Quarterly

At time of

Food Products Grab J Sarno and Control 3 Gamma isotopic and 1-131 harvest

Discharge 1/2 mile north of

Sediment Grab Palisades and Ludington Control 4 Gamma isotopic Semiannually

Fish Grab Discharge and Control 7 Gamma isotopic Semiannually

Broadleaf

Vegetation Grab NA - no samples taken

Page 7 of 10
Table HP 10.4-2

Sample Data Summary

Environmental Radioloqical Monitorinq Proqram Summary

Name of Facility Palisades Nuclear Plant Docket No 50-255

Location of Facility (County. State) Van Buren. Michiaan Reiortina Period Jan 1.2006 to Dec 31.2006

Medium or Pathway Type/Total Lower All Indicator Name b Control Number of Number of Limit of Locations Mean (fb Locations ( asure) Analyses Detectiona Mean (fib Distance Range Mean (!ý OReportable

(UnitofMeasure) Performed (LLD) Range Direction Range Occurrences

I-131/258 0.03 <LLD <LLD 0

Air Particulates

(pCi/m3) Gross 0.01 0.026 GR-10 Grand 0.028 (51/51) 0.028 (51/51) 0

Beta/258 (207/207) Rapids 0.014 - 0.045 0.014 - 0.045

0.011 - 0.048 55 miles NNE

Gross 4.0 1.55 (24/24) South Haven SH-25 1.70 (12/12) 1.48 (12/12) 0

Lake Water Beta/36 0.6 - 3.4 51⁄22 miles N 1.0- 3.4 0.9 - 2.3

(pCi/L)

Tritium/36 500 151 (1/24) South Haven SH-25 151 (1/12) < LLD 0

151 -151 51/2 miles N 151-151

Gross 4.0 1.70 (12/12) South Haven 1.70 (12/12) 1.48 (12/12) 0

Beta/24 1.0 - 2.8 Municipal 1.0 - 2.8 0.9- 2.3

Drinking Water

(pCi/mi) Tritium/24 500 186 (5/12) South Haven 186 (5/12) < LLD 0

154-240 Municipal 154-240

Page 8 of 10
Table HP 10.4-2

Sample Data Summary

Number of

Type/Total Lower All Indicator Name LoationPo

Medium or Pathway Number of Limit of Locations Mean (f b Locations REPORTAB

Sampled Analyses Detectiona Mean (f b Distance & Mean (f4 b LE

(Unit of Measure) Performed (LLD) Range Direction Range- OCCURENC

ES

Milk 1-131/48 1.0 <LLD .... <LLD 0

(pCi/L) Cs-137/48 18.0 <LLD .... <LLD 0

Other 15.0 <LLD .... <LLD 0

Gamma/48

Inner Ring TLD Gamma 10.0 12.5 (63/63) Kalamazoo ST-1 1 16.4 (4/4) 14.8 (12/12) 0

(Gamma mR) Dose/75 9.9-15.6 35 miles E 15.0-17.8 12.6-17.8

Outer Ring Gamma 10.0 14.5 (40/40) ST-02 17.6 (4/4) 14.8 (12/12) 0

(Gamma mR) Dose/52 11.4-19.1 5.6 miles S 16.5-19.1 12.6-17.8

Food Products 1-131/3 0.06 <LLD .... <LLD 0

Gamma 0.05-0.10 <LLD .... <LLD 0

(pCi/gm wet) Spec/3

Gamma 0.05 to <LLD .... <LLD 0

Sediment Spec/4 0.18

(pCi/gm dry)

Gamma 0.10 to 0.049 (2/3) Plant Discharge 0.062 (1/3) 0.044 (2/4) 0

Fish Spec/7 0.26 0.036 - 0.062 1/2 mile N 0.062 0.029 - 0.059

(pCi/gm wet)

a Nominal Lower Limit of Detection (LLD) as defined in table notation c of Table E-3

b Mean and range based on detectable measurements only. Fraction of detectable measurements at specific locations is indicated in parenthesis

(f)

Page 9 of 10
Table HP 10.4-3

Greatest Mean Sampling Location

January 1, 2006 to December 31, 2006

Table HP 10.4-3

Medium or

Pathway

Sampled

(unit of

measurement) Type of Analysis Location High Low Mean

Air (pCi/m3) 1-131 NA NA NA NA

Gross Beta GR-10 0.045 0.014 0.028

Lake Water Gross Beta 25-SH SHRAW 3.4 1.0 1.7

(pCi/L)

Tritium 25-SH SHRAW 151 151 151

Drinking Water Gross Beta 25-SH Treated 2.8 1.0 1.7

(pCi/L)

Tritium 25-SH Treated 240 154 186

1-131 NA NA NA NA

(pCi/L) Cs- 137 NA NA NA NA

Other gamma NA NA NA NA

Inner Ring TLD

(gamma mR) Quarterly ST-11 KZ 17.8 15.0 16.4

Outer Ring TLD

(gamma mR) Quarterly ST-02 Outer Ring 19.1 16.5 17.6

Crops 1-131 NA NA NA NA

(pCi/g wet) Other Gamma NA NA NA NA

Sediment

pCi/gm dry) Gamma Emitters NA NA NA NA

Fish

(pCi/gm wet) Gamma Emitters Discharge 0.062 0.036 0.049

Broadleaf Gross Beta

Vegetation Cs-137 NA - no samples taken

Other Gamma

Page 10 of 10
ATTACHMENT A

SAMPLE COLLECTION ANOMOLIES

Sample

Affected

Air

I Location Date

........ 5-P R ...................... 4/10/06 .

Problem Evaluation

Air 10-GR 4/23/06

Air

TLD

Air

.. . ................................................................. . ..................................... ...... ... . .. 10-GR 6/8/06

21 -ST 9/30/06

Sample not Air sample pump found not

obtained running. PNP corrective action

report number 01023185

initiated.

Required LLD Sample not shipped to vendor in

not attained time to permit meeting the

required LLD. PNP corrective

action report number 01025707

initiated.

Sample not Sample lost during shipment.

received at PNP corrective action report Palisades number 01034669 initiated.

TLD missing Likely a squirrel or chipmunk

from holder removed TLD from holder. PNP

corrective action report number

01053121 initiated.

Weekly Weekly air sample ran two weeks sample not prior to change-out. PNP

taken corrective action report number

..........

10-GR 12/7/06

01066120 initiated.

Page 1 of 1
ATTACHMENT B

PALISADES LAND USE CENSUS

The attached tables are the results of the PNP Land Use Census conducted on

September 21, 2006.

Table 10.11-1 references the distance from PNP to the nearest residence, garden

(greater than 500 square feet), beef/dairy cattle, and goat per meteorological sector.

Table 10.11-2 identifies the locations of the nearest residence, garden, beef/dairy cattle

and goats within a five (5) mile radius of PNP per meteorological sector.

Table 10.11-3 lists the critical receptor locations used in calculation of the offsite doses

by the GASPAR computer program.

The XOQ/DOQ values in the ODCM will be changed to reflect the changes noted in the

Land Use Census. PNP uses the 1992-1996 meteorological data.

Page 1 of 5
2006 PALISADES LAND USE CENSUS

TABLE 10.11-1

Distance to the nearest residence, garden, dairy/beef cattle and goat in each sector.

SECTOR RESIDENCE GARDEN

NNE

NE

ENE

E

ESE

SE

SSE

S

SSW

1.1 mi

1.2 mi

1.3 mi

1.0 mi

1.0 mi

1.0 mi

0.7 mi

0.5 mi

0.7 mi

1.7 mi

1.2 mi

1.6 ml

2.1 mi

>5 mi

>5 mi

1.6 mi

4.0 mi

>5 mi

BEEF CATTLE

>5 mi

>5 mi

>5 mi

>5 mi

>5 mi

1.9 ml

>5 mi

>5 ml

>5 ml

DAIRY COW

>5 mi

>5 mi

>5 mi

>5 mi

>5 ml

>5 ml

>5 ml

>5 mi

>5 mi

GOAT

>5mi

>5 mi

>5 ml

>5 ml

>5 ml

>5 ml

4.8 mi

>5 mi

>5 mi

Page 2 of 5
2006 PALISADES LAND USE CENSUS

TABLE 10.11-2

Nearest Locations per Sector Within 5 Miles

Sector Location Description

State Park Manager

Item How Many

NNE

Ruggles Rd

Residence 1

NNE

20th

NE

Blue Star

Highway

0.1 mile south of Ruggles Rd SW

corner of 201h and 0 fire lane

Route 3, Box 133 (East side of

highway)

M-43, N side of road, between 1 2 th

and 1 6 th (approximately 0.3 mile

outside of the 5-mile limit)

Trailer-West 24th avenue, dead end

at sand dune

Garden

Residence

Garden

1

1

NE

M-43

Goats Appx 20

ENE

24th avenue

Residence 1

ENE

E

77th

E

75th

2291872nd street Garden 1

77th St., dead end of 7 7 th St. near 28th Avenue intersection

27723 7 5th, 0.1 mile N of 2 8th (East

side of road)

Residence

Covert Gen Co.

Garden

1

1

ESE

2 8 th avenue

SE/ESE 28 th

77401 28th avenue

77555 28th Avenue

Residence

Residence

1

1

SE

7 6 th

SSE

SSE

77 1/2

SSE 376 th

SE Corner of 76th and 30th , east side of road

80119 29th Avenue

77 1/2 St., 0.3 mile N of 3 2 nd Ave,

West side of 77 1/2 St.

376 th, North side of road, 0.3 mile

East of 7 6 th

Cattle 4

Residence

Garden

Goat

1

1

Appx 20

Page 3 of 5
2006 PALISADES LAND USE CENSUS

TABLE 10.11-2

Nearest Locations per Sector within 5 Miles

Sector

S

2 9 th Ave

S

7 8 th

SSW

2 9 th

Location Description

Palisades Park, 0.5 mile West of

29th Ave and Blue Star Highway

th 78 , 0.5 mile North of CR 376 west

side of road

29th Ave, at dead end of Palisades

Park

Item

Residence

Garden

Residence

How Many

1

Page 4 of 5
2006 PALISADES LAND USE CENSUS

TABLE 10.11-3

Critical Receptor Items

Sector Distance Location/Description Item

(miles)

SSE 0.48 Site Boundary N/A

S 0.5 Residence, Palisades Park, 1/2 mile west Residence

of 29th avenue and Blue Star Highway

NE 1.2 Route 3, Box 133 (East side of highway) Garden

SE 1.9 SE Corner of 76tn Street and 30tn Beef Cattle

SSE 4.8 376tn, North side of road, 0.3 mile East of Goat

76 76 th

No dairy cattle are within the 5 mile radius of PNP

Page 5 of 5
ATTACHMENT C

HEALTH PHYSICS PROCEDURE HP 10.10

"PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT"

33 Pages Follow
Procedure No HP 10.10

Revision 9

Effective Date 7/6/05

PALISADES NUCLEAR PLANT

HEALTH PHYSICS PROCEDURE

TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

Approved: JBBurnett / 7/1/05

Procedure Sponsor Date

New Procedure/Revision Summary:

Editorial to Revision 9

Specific Changes
PALISADES NUCLEAR PLANT Proc No HP 10.10

HEALTH PHYSICS PROCEDURE Revision 9

Page i

TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

Table of Contents

1.0 P U R P O S E ...................................................................................................................... 1

2.0 R E FE R E N C E S ............................................................................................................... 1

2.1 SO URCE DO CUM ENTS ................................................................................ 1

2.2 REFERENCE DOCUM ENTS ......................................................................... 1

3.0 PREREQ UISITES .................................................................................................... 2

4.0 PRECAUTIONS AND LIMITATIONS .......................................................................... 2

5.0 P R O C E D U R E ................................................................................................................. 3

5.1 CONTROL AND OVERSIGHT OF SAMPLING FOR THE

RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM ............ 3

5.2 REMP AIR SAMPLE COLLECTION ......................................................... 4

5.2.1 Precautions ......................................................................... 4

5.2.2 Prerequisites ....................................................................... 4

5.3 REMP LAKE (DRINKING) WATER SAMPLE COLLECTION -

SOUTH HAVEN, MICHIGAN ..................................................................... 7

5.3.1 Prerequisites ....................................................................... 7

5.4 STEAM GENERATOR STORAGE FACILITY MONITORING WELL

WATER SAMPLE COLLECTION (QUARTERLY) .................................... 8

5.4.1 Prerequisites ....................................................................... 8

5.5 REMP MILK SAMPLE COLLECTION ...................................................... 8

5.5.1 Precautions ......................................................................... 8

5.5.2 Prerequisites ....................................................................... 9

5.6 REMP AQUATIC BIOTA COLLECTION .................................................. 9

5.6.1 Precautions ......................................................................... 9

5.6.2 Prerequisites ..................................................................... 10

5.7 REMP SEDIMENT SAMPLE COLLECTION ........................................... 11

5.7.1 Prerequisites ..................................................................... 11

5.8 REMP FOOD PRODUCT SAMPLE COLLECTION ................................. 11

5.9 REMP TLD SAMPLE COLLECTION ....................................................... 12

5.9.1 Prerequisites ..................................................................... 12
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TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

Table of Contents

5.10 MISCELLANEOUS SAMPLES ............................................................... 13

5.10.1 Ludington - Control Station ............................................. 13

5.10.2 Palisades Daily Sam ples .................................................. 13

6.0 ACCEPTANCE CRITERIA ....................................................................................... 13

7.0 ATTACHMENTS AND RECORDS .......................................................................... 14

7.1 ATTA CHM ENTS ...................................................................................... 14

7.2 R ECO R DS .............................................................................................. 14

8.0 SPECIA L REVIEW S ................................................................................................ 14

ATTACHMENTS

Attachment 1, "Environmental Sample Collection Schedule"

Attachment 2, "Sample Locations"

Attachment 3, "Sample Identification"

Attachment 4, "Sample Packaging and Shipment"

Attachment 5, "Palisades Sample Collection Forms and Records"
PALISADES NUCLEAR PLANT Proc No HP 10.10

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TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

USER ALERT

INFORMATION USE PROCEDURE

The activities covered by this procedure may

be performed from memory.

1.0 PURPOSE

To provide methodology for collection of environmental samples in support of the

Radiological Environmental Monitoring Program (REMP).

2.0 REFERENCES

2.1 SOURCE DOCUMENTS

2.1.1 Reg Guide 4.15(7)

2.1.2 10CFR50, Appendix I

2.1.3 Palisades Administrative Procedure 7.08, "Palisades Radiological Environmental

Monitoring Program"

2.1.4 REMP Sample Shipping Manual, Environmental Inc

2.1.5 Health Physics Procedure HP 10.1, "Radiological Environmental Monitoring Program

Surveillance"

2.1.6 Offsite Dose Calculation Manual (ODCM)

2.1.7 Branch Technical Position (Revision 1, 1979), "Radiological Portion of the

Environmental Monitoring Program"

2.2 REFERENCE DOCUMENTS

2.2.1 Palisades ODCM, Appendix A, Sections Ill.J, IV.C, and Tables E-1 and E-2

2.2.2 Palisades Administrative Procedure 10.46, "Plant Records"

2.2.3 Palisades Administrative Procedure 10.41, "Procedure and Policy Processes"

2.2.4 Health Physics Procedure HP 6.52, "Palisades (Onsite) Radiological Environmental

Program Sample Collection"

2.2.5 Palisades Administrative Procedure 3.19, "Technical Specifications Programs"
PALISADES NUCLEAR PLANT Proc No HP 10.10

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TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

3.0 PREREQUISITES

As indicated in procedure.

4.0 PRECAUTIONS AND LIMITATIONS

4.1 This procedure shall be applicable to Palisades/Chemistry & Radiation Protection,

Environmental Department, and any contractual personnel assigned to collect or

evaluate REMP samples.

4.2 Any revisions to this procedure shall be reviewed against Palisades ODCM

Specifications to verify compliance to all requirements.

4.3 Deviations from the required sampling schedule shall be documented in the Annual

Radiological Environmental Operating Report.

4.4 Every effort shall be made to complete corrective action on malfunctioning sampling

equipment prior to the end of the next sampling period.

4.5 If it is not possible to obtain the required samples, suitable alternative media and

locations shall be substituted within 30 days.

4.6 Samples shall be collected, prepared, and shipped for analysis in a timely manner to

preserve integrity. Other specific handling precautions for sample media are

indicated in Section 5.0 as required.

4.7 Obtain best available replacement sample for any missing sample. Some samples

are not replaceable (TLDs, air samples, etc), however, water, milk, crop samples,

etc, should be.

4.8 Document any missing samples or malfunctioning equipment on sample data

collection sheets.
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TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

5.0 PROCEDURE

USER ALERT

INFORMATION USE PROCEDURE

The activities covered by this procedure may

be performed from memory.

5.1 CONTROL AND OVERSIGHT OF SAMPLING FOR THE RADIOLOGICAL

ENVIRONMENTAL MONITORING PROGRAM

5.1.1 Sampling techniques described by this procedure must be strictly adhered with.

a. This includes use of tweezers for air sample media change out to ensure the

collected media is not disturbed.

b. Recorded data should be verified including verification of transcribed data to

avoid errors.

c. All deviations from performance requirements, unavailable samples, or other

sampling anomalies must be reported to the C&RP Radiological

Environmental Contact.

5.1.2 Failure of sample collectors to comply with sampling and reporting requirements

may result in remedial training, or reassignment of sampling duties.

5.1.3 The C&RP Radiological Environmental Contact shall conduct periodic (annual)

audits of air sampling activities performed by non-Palisades C&RP personnel.

a. These audits shall include observation of collection techniques, verification of

procedural compliance, and review of equipment condition.

Included in the review of equipment condition, is to ensure that any fast

growing trees and bushes in the vicinity of the station are removed, along with

any branches extending over the top of the sampler. The goal is to keep

every station away from the drip line (with the exception of station 9, which

has an existing canopy 50 feet above the station).

b. Audits should specifically address air sample collection and should include

observation of all individuals involved in sample changeout.
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TITLE: PALISADES RADIOLOGICAL ENVIRONMENTAL PROGRAM

SAMPLE COLLECTION AND SHIPMENT

c. Results of the audits and any follow up action should be documented in the

REMP file.

Collect samples using the following methodology in accordance with schedule and

location data described in Attachments 1 and 2.

5.2 REMP AIR SAMPLE COLLECTION

5.2.1 Precautions

a. New filters and cartridges should be transported and handled such that

potential contamination of them is minimized (ie, placed in clean plastic bags,

etc).

b. If an air sampling unit is discovered not operating, attempt to find the cause

and repair. If this cannot be done, replace applicable component and

document on air sample collection data sheet.

c. Airflow meters shall be calibrated annually by General Meter. All in service

calibrated meters will have affixed a valid calibration sticker/card stating date

of calibration and calibration due date.

d. Airflow meters shall be changed out prior to the expiration of calibration dates.

e. Air station leakage shall be none detectable. If the replacement of air station

components is required due to air leakage, document on air sample collection

data sheet.

5.2.2 Prerequisites

a. Glass fiber (particulate) air filters

b. Charcoal cartridges for iodine sampling (prelabeled for each air sampler)

c. Glassine or plastic envelopes (prelabeled for each air sampler)

d. REMP Air Sample Data Sheet (containing installation data)

e. Replacement air sample meters (as required)

f. Tweezers
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SAMPLE COLLECTION AND SHIPMENT

g. Stop Watch

h. Step Ladder

NOTE: The Control Station 10-GR, is changed out weekly by an independent collector, and

mailed in separately. The prelabeling of cartridges and envelopes, detailed below, is

not required for this station as sample mix-up is not possible. In addition, for control

station, the Palisades Sample Collection Form and Records (Page 1 of

Attachment 5) is completed by the Technician changing out the four local stations by

transferring the recorded data provided by the independent collector.

5.2.3 Perform the following weekly at each sample location:

a, Open the protective cover on the air sample station and verify the sampling

location number written on the inside of the door is the same as the

prelabeled sample change-out package.

b, Verify that the meter serial number and calibration due date are correctly

documented on Palisades Plant Environmental Monitor Operability Check and

Sample Collection data form (Page 1 of Attachment 5).

c, Determine and record the "As Found Flow" rate (seconds for one cubic foot of

volume).

d. Determine and record the "As Found Leak" rate by placing hand over filter

housing inlet to form a seal. While holding hand over the inlet, determine if air

leakage is evident by checking the air flow meter needle for movement

(leakage). If no air leakage, record (N) in the "As Found Leak" column. If air

leakage is indicated, determine the cause and repair as soon as possible.

e. Unplug or turn off the air pump and record the "REMOVED

MONTH/DAY/YEAR," "REMOVED TIME," and "GAS METER READING

REMOVED."

f. Remove the prelabeled charcoal cartridge and place in zip lock bag.

g. Using tweezers, carefully remove particulate filter from the sampler head and

place in the prelabeled glassine envelope or plastic envelope.

h. Clean out any residue or moisture buildup in sampler head before

replacement filter is installed. Check the condition of the sampler head

o-rings. Replace cracked o-rings as necessary to prevent air leakage.
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SAMPLE COLLECTION AND SHIPMENT

Install new particulate filter and charcoal cartridge and ensure that both are

properly centered in sampler head to prevent air leakage. Ensure the fiber

side of the particulate filter is facing out (smooth side facing inward).

j. Restart air pump. Place hand over the filter housing inlet to form a seal,

determine if air leakage is evident by checking air flow meter needle

movement. If no air leakage, record (N) in the "As Left Leak" column. If air

leakage indicated, determine the cause of the leakage (filter not centered in

holder properly or cracked o-ring) and correct problem as soon as possible,

restoring system to no air leakage.

k. Determine and record "As Left" flow rate. If greater than 90 seconds are

required for one cubic foot of volume, the sample pump is degrading.

Replace pump as soon as possible to avoid failure to reach minimum sample

volume. (5000 ft3).

1. If an airflow meter must be replaced, record this in the "Comments" column.

Record replacement meter data in the reading on the upcoming week's

sample collection data sheet.

m. Close the protective cover on the air sample station.

n. Proceed to the next station. Date and sign the current week's data sheet

upon completion of the entry of all current data.

o. Calculate and record "SAMPLE VOL (FT3)," ALSO ensure all pertinent data

is recorded.

p. Transcribe the "REMOVED MONTH/DAY/YR" and "GAS METER READING

REMOVED" taken in Step 5.2.3e to the "INSTALLED" reading columns on the

sample collection sheet to be used for the upcoming week's air sample

collection. Also transcribe the meter serial number and calibration due date

to the upcoming week's sample collection sheet.
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SAMPLE COLLECTION AND SHIPMENT

5.3 REMP LAKE (DRINKING) WATER SAMPLE COLLECTION -

SOUTH HAVEN, MICHIGAN

5.3.1 Prerequisites

a. Two clean, one-gallon plastic containers labeled with sample type, location,

amount, and date (or collection period)

b. Data Sheet (Attachment 3)

5.3.2 Perform the following sample collection monthly:

a. Leave two containers with the plant personnel at the South Haven Municipal

Water Treatment Plant. New water sample containers should be left at the

South Haven Water Treatment Plant upon pickup of end-of-month composite

samples.

b. Instruct the plant personnel to add approximately 300 ml per day of raw water

to containers labeled "RAW."

c. Return at end of month to collect containers. Obtain verbal verification that

Step 5.3.2b was carried out. Note any deviations in "Remarks" column of

data sheet.

d. Label containers with sample type, location, and collection period.

e. Package and ship samples per Attachment 4.

f. Record location, sample types, and amount on sample identification data

sheet (Attachment 3).
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SAMPLE COLLECTION AND SHIPMENT

5.4 STEAM GENERATOR STORAGE FACILITY MONITORING WELL WATER

SAMPLE COLLECTION (QUARTERLY)

5.4.1 Prerequisites

a. Clean, one-gallon plastic containers

b. Data Sheet (Attachment 3)

5.4.2 Perform the following sample collection quarterly:

a. Begin pumping water, and allow water to run for approximately one minute to

purge the lines.

b. Fill two clean, one-gallon plastic containers with well water from each sample

location.

c. Label containers with sample type, location, and collection date.

d. Package and ship samples per Attachment 4.

e. Record on data sheet location, type, date, amount, and under "Remarks" any

pertinent information.

5.5 REMP MILK SAMPLE COLLECTION

5.5.1 Precautions

a. Milk samples shall be sent to the laboratory as soon as possible because of

the short half-life of 1-131. Any undue delay may cause ODCM, Appendix A,

Table E-3 analytical LLD requirements to be violated.

b. Obtain best available replacement sample for any missing milk sample(s).

Identify new sample location(s) and update location in Attachment 2.

c. If milk samples are unavailable, then samples of three different kinds of broad

leaf vegetation grown nearest to Palisades in each of two different offsite

locations of the highest predicted average ground level D/Q (SE or SSE

sectors near site), and one sample of each kind of similar broad leaf

vegetation grown 15-30 km distant from Palisades in the least prevalent wind

direction (NNE, NE or ENE sectors) may be used as replacement samples.

The new sample locations shall be identified and the REMP procedures

revised within 30 days to reflect sampling changes. Collect approximately

one kilogram (2.2 Ib) of each sample type.
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SAMPLE COLLECTION AND SHIPMENT

5.5.2 Prerequisites

a. Two clean, plastic one-gallon containers for each sample location

b. Sodium bisulfite preservative (approximately 40 gm per gallon of milk

required)

c. Data Sheet (Attachment 3)

5.5.3 Perform the following monthly at each specified sample collection location:

a. Obtain two one-gallon grab samples of raw milk as specified in Attachments 1

and 2.

b. Add approximately 40 gm of sodium bisulfite to each one-gallon container of

milk and thoroughly mix. The sodium bisulfite can either be in prepared

packets or "scooped" with a volumetric measure from its container.

c. Label containers with sample type, location, and date.

d. Package and ship samples as per Attachment 4.

e. Record on Sample Data Sheet, the location, type, date, and amount of

samples. Under "Remarks," note any other pertinent information.

5.6 REMP AQUATIC BIOTA COLLECTION

5.6.1 Precautions

a. Collection to be coordinated between Radiological Services Department

responsible Section and the Environmental Department. At least one

individual in the collection party is required to have Michigan Department of

Environmental Quality (MDEQ) Cultural and Scientific Fish Collectors Permit

if gill net is used.

b. If logistical problems prevent use of a boat to set gill nets from the lake side of

Palisades, then the nets can be set offshore from the site boundary (by

wading). Notify Security prior to using offshore wading method for beach

access.
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5.6.2 Prerequisites

a. Boat with required safety equipment, or waders

b. Gill nets with weights and floats

c. Plastic one-liter wide-mouth bottles

d. Data Sheet (Attachment 3)

e. Fillet knives

f. Black permanent felt markers for sample identification on containers

g. Notify district MDEQ Fisheries biologist prior to sample collection

5.6.3 Collect samples twice during the season of greatest abundance (typically May

through October) as follows:

a. Gill nets are placed at the locations specified in Attachment 1 to collect at

least two species of commercially and/or recreationally important fish in the

vicinity of the Plant discharge area and the same species in an area not

influenced by the Plant discharge (Ludington Pump Storage Plant or other

Consumers Energy facility). One liter of flesh should be collected for each

species caught for analysis accuracy.

b. Normally fish will be collected first from the vicinity of the discharge. REMP

coordinator will then collect at least two of the same species at Ludington

(control station). Or REMP coordinator will provide the Ludington collector

with a list of the species collected in the vicinity of the discharge, with

instructions to collect at least two of the same species.

c. Label all containers with sample type, location, and date.

d. Package and ship samples per Attachment 4.

e. Record on data sheet location, type, date, amount, and under "Remarks"

indicate any pertinent information.
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5.7 REMP SEDIMENT SAMPLE COLLECTION

5.7.1 Prerequisites

a. One-liter, wide-mouth plastic sample bottles

b. Data Sheet (Attachment 3)

5.7.2 Collect sediment samples semiannually at station 30, 0.5 miles north of discharge,

and a control sample at the Ludington Pump Storage Plant.

a. Label containers with sample type, location, and date.

b. Package and ship samples per Attachment 4.

c. Record on Sample Data Sheet location, type, date, and amount of sample.

Note any other pertinent information in the "Remarks" section.

5.8 REMP FOOD PRODUCT SAMPLE COLLECTION

a. Sample containers

b. Data Sheet (Attachment 3)

5.8.1 Collect food samples monthly during the harvest season, as per ODCM, Appendix A,

Table E-1. One sample each of the two principal fruit crops blueberries and apples

must be collected.

a. Collect approximately one kilogram (2.2 Ib) of each sample type. Samples

are not to be washed, shaken, or cleaned. Samples should not be collected

from a single source, but at random from the entire orchard or field.

b. Label all containers with sample type, location, and date.

c. Package and ship samples per Attachment 4.

d. Record on data sheet location, type, date, amount, and under "Remarks" note

any unusual conditions.
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SAMPLE COLLECTION AND SHIPMENT

5.9 REMP TLD SAMPLE COLLECTION

5.9.1 Prerequisites

a. TLDs

b. TLD Data Sheet (Attachment 5)

5.9.2 Quarterly at each sample location perform the following:

a. Upon receipt of TLDs from the laboratory contractor, all TLDs shall be

inventoried and immediately placed in the lead cave. Note date of receipt and

inventory on TLD data sheet.

b. Field TLDs shall only be removed from the lead cave for delivery to their

proper locations. All control TLDs remain in the lead cave throughout the

entire exposure period.

c. Remove and replace TLDs at each sample location.

d. For any missing TLDs, perform the following:

1. Search immediate area.

2. If lost TLD is found, collect it and perform standard change out

procedure.

3. If lost TLD is not found, post the new TLD in proper location.

4. Record in "Remarks" column of data sheet any of the above

circumstances.

e. Store collected field TLDs in lead cave along with control TLDs until ready for

mailing to laboratory contractor. Mark "Do not x-ray" on TLD package.

f. Transportation control TLDs (Shield TLDs) are to be stored in a special lead

shield provided by laboratory contractor after the field TLDs are posted.

Ensure that designated transportation control TLDs are included with the

correct TLD package being mailed to laboratory contractor. Also ensure that

laboratory contractor's TLD data sheet is completed and enclosed with

shipment.
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SAMPLE COLLECTION AND SHIPMENT

g. Record TLD collection date and the date that the TLDs are returned to the

vendor. Initial/sign the data sheet (Attachment 5). Record the installation

date for the new TLDs on the appropriate data sheet.

h. Package and ship samples per Attachment 4.

5.10 MISCELLANEOUS SAMPLES

5.10.1 Ludington - Control Station

NOTE: Sediment samples are also collected at Ludington Pump Storage Plant per

Section 5.7 of this procedure.

a. Ludington Lake In composites are collected daily and shipped to Palisades on

a monthly basis.

b. Palisades RETS/REMP personnel record appropriate data on the Sample

Data Sheet for shipment to Environmental Inc.

5.10.2 Palisades Daily Samples

a. Palisades Lake In, Lake Out, Site Water, Service Water, and Turbine Sump

effluent samples are collected on a daily basis per Palisades per Health

Physics Procedure HP 6.52, "Palisades (Onsite) Radiological Environmental

Program Sample Collection."

b. Palisades RETS/REMP personnel record appropriate data on the Sample

Data Sheet and label all samples.

6.0 ACCEPTANCE CRITERIA

Proper completion of procedure.
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SAMPLE COLLECTION AND SHIPMENT

7.0 ATTACHMENTS AND RECORDS

7.1 ATTACHMENTS

7.1.1 Attachment 1, "Environmental Sample Collection Schedule"

7.1.2 Attachment 2, "Sample Locations"

7.1.3 Attachment 3, "Sample Identification"

7.1.4 Attachment 4, "Sample Packaging and Shipment"

7.1.5 Attachment 5, "Palisades Sample Collection Forms and Records"

7.2 RECORDS

7.2.1 Distribution of Sample Collection Data Sheet as per Attachment 4.

7.2.2 All Radiological Environmental Monitoring Program Records shall be considered

complete when the Annual Radiological Environmental Operating Report is

submitted to the NRC. Records shall be retained in accordance with Palisades

Administrative Procedure 10.46, "Plant Records."

8.0 SPECIAL REVIEWS

The scope of this procedure includes activities that require a PRC Review per

Palisades Administrative Procedure 3.19, "Technical Specifications Programs," but

do not require a 50.59 Review per Palisades Administrative Procedure 10.41,

"Procedure and Policy Processes." Therefore, changes to this procedure require a

PRC Review but do not require a 50.59 Review.
Proc No HP 10.10

ENVIRONMENTAL SAMPLE COLLECTION SCHEDULE Attachment 1

Revision 9

Palisades Nuclear Plant Page 1 of 2

Exposure Pathway

and/or Sample

Airborne:

Particulates

Number of Samples

and Locations*

4-Within a 10 km

- Radius

1 - 25 to 89 km Distant

Collection

Sample Type Frequency

Continuous at

approximately

1 cfm (may be less

due to dust

loading)

Weekly

lodines

Waterborne:

Lake Water

Drinking

Water

Same as Particulates

1 - Intake

1 - Intake (Ludington

Control)

1 - S Haven Municipal

System - Raw

1 - Domestic Water

**3 - Plant Site Locations

1 - 0.8 km North of

discharge

1 - Ludington control

Same as

particulates

Daily composite to

obtain a

one-gallon sample

Weekly

Monthly

Well Water

Sediment

Two-gallon grab

sample

One-liter grab

sample

Quarterly

Semiannually

**These are monitoring wells of the groundwater for the Steam Generator Storage

Facility, this is not part of the environmental sampling program.

*If samples are unavailable at the specified location, an attempt should be made to

sample at an alternate location (refer to Step 4.5).
Proc No HP 10.10

ENVIRONMENTAL SAMPLE COLLECTION SCHEDULE Attachment 1

Revision 9

Palisades Nuclear Plant Page 2 of 2

Exposure Pathway

and/or Sample

Number of Samples

and Locations*

Collection

Sample Type Frequency

NOTE: Currently there are no dairy farms within a distance of 5 to 8 km from the

Plant. However, milk samples will be obtained at 3 locations within a distance

of 15 km when available. When milk samples are collected, broad leaf

vegetation sampling is not required.

Ingestion:

Milk

Food Products

Fish

3 - From 5 to 8 km

1 - Control from

15 to 30 km

1 - Each of two principal

fruit crops

(blueberries and

apples).

2 - Location in vicinity of

Plant discharge

2 - Ludington control

or other CMS Energy

facility

1 -Onsite

16 - Site boundary

9 -Within 12 km radius

3 -Control stations

1 -Control in lead cave

Two-gallon grab

sample

Two-pound grab

sample

At time of

harvest

Monthly

One-liter fish flesh

from each

available species,

two species

required. Obtain

the same species

from the control

location.

Continuous

Twice in

season

Direct: Quarterly

TLD

*If samples are unavailable at the specified location, an attempt should be made to

sample at an alternate location (refer to Step 4.5).
Proc No HP 10.10

Attachment 2

Revision 9

SAMPLE LOCATIONS Page 1 of 9

Palisades Nuclear Plant

Air Air Lake Well Food

Station Code Location Particulates Iodine Water Water Milk Products Sediment TLD Fish

"1 ST Palisades Nuclear Plant Onsite, on tree near nw corner of X X X

bag crew bldg.

2 TH RR 3 TLD located on 80th Street, west X

Coloma, MI side on post, 200 feet south of the

5.6 miles S old air sample station.

3 HS 76182 48th Ave Along 48th Ave, 1/4 mile west of X

Covert, MI 76th St. In barnyard 50 yds off north

5.8 miles SSE side of road.

4 JS 36197 M-140 Hwy Along 36th Ave, 1/2 mile east of X X X X

Covert, MI M-140 15 ft off south side of road.

3-1/2 miles SE TLD located in front yard of

residence.

5 PR 72723 CR 378 Along CR 378, 3/4 mile east of X X X

Covert, MI M-140, 30 ft off north side of road.

3-1/2 miles ESE TLD located at Paul Rood residence,

on tree in back yard just past

driveway.

6 RB RR 3 Along 12th Ave (CR 384), turn nw X

South Haven, MI past maple grove, go 1/4 mile

4-1/2 miles NE located in orchard on north side of

road.

7a SN21 Emergency Siren 21 On Monroe Blvd, at corner of 11 th X

4.1 miles NNE Street.

8 SP State Park Onsite along the dump road, north of X X X

1 mile N Plant. One mile from main gate.

Near State Park boundary, on side

of road as road turns west.

9 TP Covert Township Park Along 32nd Ave, 1/4 mile west of X X X

1.5 miles SSW Blue Star Hwy. 5 ft off south side of

road. TLD located at end of road, at

entrance to HSarno residence,

attached to emergency siren SN38.

10 GR Grand Rapids, MI Grand Rapids Service Center, in X X X

55 miles NNE storage area. Air sample on west

side near shed. Control TLD

100 feet north of air sample station.
Proc No HP 10.10

Attachment 2

Revision 9

SAMPLE LOCATIONS Page 2 of 9

Palisades Nuclear Plant

Air Air Lake Well Food

Station Code Location Particulates Iodine Water Water Milk Products Sediment TLD Fish

11 KZ Kalamazoo, MI Kalamazoo Service Center, in X

35 miles E parking area on post in SE corner

Control TLD.

12 DG Dowagiac, MI TLD located at first farm past old air X

30 miles SSE sampler station, same side of road.

13 ST Perimeter of Palisades Past #8 along dump road. Proceed X

NNE west up dune path at right of

containment test structure. At first

crest, turn north and proceed up

adjacent hill to #13 at top (approx

50 yds from crest). Near State Park

fence line.

14 ST Perimeter of Palisades Along dump road to point where X

fence divides old Blue Star Hwy, NE 25 yds to east of road.

15 ST Perimeter of Palisades North along Blue Star Hwy, X

E 0.75 miles from access road, 1 Oft off west side of road.

16 ST Perimeter of Palisades North along Blue Star Hwy, 0.4 miles X

E from access road, 50 ft off west side of road.

17 ST Perimeter of Palisades Along access road, 25 yds south of X

ESE southern power line, 15 yds off east

side of road.

18 ST Perimeter of Palisades 20 yds from access road along south X

SE road. 40 yds off south road.

19 ST Perimeter of Palisades 0.2 miles along south road from X

SSE access road, 30 ft off north side of

road.

20 ST Perimeter of Palisades 0.4 miles along south road from X

S access road, 20 ft off south side of

road.

21 ST Perimeter of Palisades 0.7 miles along south road from X

SSW access road. 5 ft off east side of road. Near Lake Michigan Bluff.
Proc No HP 10.10

Attachment 2

Revision 9

SAMPLE LOCATIONS Page 3 of 9

Palisades Nuclear Plant

Air Air Lake Well Food

Station Code Location Particulates Iodine Water Water Milk Products Sediment TLD Fish

22 MG Mike Grogan Control TLD in lead cave inside X

13 miles SSW garage at RETS/REMP residence.

23 SN19 Emergency On CR 380. X

Siren 19

3 miles ENE

24 SN26 Emergency On 67th Street. X

Siren 26

6 miles E

25 SH South Haven, Ml South Haven Water Treatment X

5-1/2 miles NNE Plant.

26 JH Joseph Hay X

41799 CR 681

Bangor, MI

11.4 miles ESE

27 DH Dennis Hessey X

26959 66th St

South Haven, MI

6.6 miles E

28 DC Danny Carpenter X

64015 M-43

Bangor, MI

7.25 miles E

29 WS William Shine X

60364 M-43 West

Bangor, MI

8.7 miles E

30 STN 1/2 mile N of discharge X

32 LP Ludington Pumped X X X

Storage 125 Miles N

33 ST Perimeter of Palisades Onsite along south side dump road, X

NE just 15 yards west of Air Station

8SP.
Proc No HP 10.10

Attachment 2

Revision 9

SAMPLE LOCATIONS Page 4 of 9

Palisades Nuclear Plant

Air Air Lake Well Food

Station Code Location Particulates Iodine Water Water Milk Products Sediment TLD Fish

34 ST Perimeter of Palisades Along dump road to area where X

NE fence divides old Blue Star Hwy, 25

yards east of road, near Station 14.

35 ST Perimeter of Palisades Located on the main post directly X

ENE across the storeroom, near Training

Building.

36 ST Perimeter of Palisades North along Blue Star Hwy, 0.9 miles X

ENE from access road, 50 Ft off west side

of road.

37 ST Perimeter of Palisades North along Blue Star Hwy, 0.6 miles X

E from access road, 50 Ft off west side

of road.

38 ST Perimeter of Palisades North along Blue Star Hwy,X

SE 0.15 miles from access road, near

old RR spur, 50 Ft off west side of

road.

41 ST Plant Site Monitoring X

Well #14

42 ST Plant Site Monitoring X

Well #15

43 ST Plant Site Monitoring X

Well #16

44 CN Control Station 11-12 miles, NNE of Plant, used as X

NNE control station for crops.
A, -~

0"

1.

SA of

cnm

ficICl

!m

/ T

/

no

PALISADES PLANT .... CD" o

SITE ENVIRONMENT •-

TLD STATIONSo
SAMPLE LOCATIONS

Palisades Nuclear Plant

Proc No HP 10.10

Attachment 2

Revision 9

Page 6 of 9

it

IL

NOT SHOWN (Control Locations)

10 Grand Rapids (55 mi NNE)

11 Kalamazoo (35 mi E

12 Dowagiac (30 mi SS)

22 Control TLD placed in lead cave off site

26 Joe Hay (JH- 11.4 mi ESE)
Proc No HP 10.10

Attachment 2

Revision 9

Page 7 of 9

SAMPLE LOCATIONS

Palisades Nuclear Plant

MPLING STATIONS

Ludington Pumped

Stimoge Project

N N

0. 2 , .. - , . MILLS$

C11$

:t

ftft

F

I
REMP SAMPLING

NO

NO

NO

NO

NO

NO

NUMBER

#1

#2

#3

#4

#5

#6

SAMPLE LOCATIONS

Palisades Nuclear Plant

WELL STATUS LOCATION

Abandon NA

Abandon North side of Support Buil

Abandon Across from East-Radwas

Abandon NA

Proc No HP 10.10

Attachment 2

Revision 9

Page 8 of 9

ding. Supports Plant site.

ste (South Side) backup for well #2.

Abandon

Active

NO

NO

NO

NO

NO

YES

YES

YES

#7

#8

#9

#10

#11

#12

#13

#14

#15

#16

Abandon

Abandon

Abandon

Abandon

Abandon

Abandon

Abandon

Active

Active

Active

NA

Located - 145 ft west of Blue Star Hwy. Used for training trailers,

well capped when not in service and well is outside of Westerly

Groundwater Flow to Plant and interim storage facility.

Just to the west & between outage building and interim storage

facility: Water is nonpotable and used in warehouse restrooms (later

to be used for fire system only).

NA

Located at junction of access and warehouse road, domestic water

supply for warehouse when it is put in service.

NA

North of access road and east of construction road,

supplies domestic water for outage building, all

in one tie-in.

East of Interim Storage Facility, used for REMP monitoring well.

Southwest of Interim Storage Facility, used for REMP monitoring well.

Northwest of Interim Storage Facility, used for REMP monitoring well.
SAMPLE LOCATIONS

Palisades Nuclear Plant

Proc No HP 10.10

Attachment 2

Revision 9

Page 9 of 9

/

WEST

12. 126 7'

+

515nl

#15

+

/

#16

~D ~zfZD

80'

29'

1291'4" --

110'/

PROPOSE MO•• 1+WEL

LOCATOM 4 #14
Proc No HP 10.10

Attachment 3

Revision 9

SAMPLE IDENTIFICATION Page 1 of 2

Date:

Collector:

PLANT

Miscellaneous Radiological Environmental Samples

SAMPLE

Location I Type DATE TIME AMOUNT REMARKS

4 4 I

4 * * 4 I

t t 4 t

4 4 4 4 4.

4 4 4 4 4-

4 4 4 4 4-

4 4 4 4 +

4 4 1 4 4-

4 1 1 4 .1-

4- 4. 4- 4 4

4- 4- 4. 4 4

4- 4- 4- I +

+ 4- 1. I. 4.

+ 4- *I- 4. 4.

+ 4- 4. 4.

+ + 4 4-
Proc No HP 10.10

Attachment 3

Revision 9

SAMPLE IDENTIFICATION Page 2 of 2

PALISADES PLANT

Miscellaneous Radiological Environmental Samples

Date Shipped:

Location Type Date Time Amount Remarks

Allen Karr Milk 2 Gallons

Danny Carpenter Milk 2 Gallons

Dennis Hessey Milk 2 Gallons

William Shine Milk 2 Gallons

Monthly

South Haven Raw Water Composite - NA 2 Gallons

Site #14 Well Water 2 Gallons

Site #15 Well Water 2 Gallons

Site #16 Well Water 2 Gallons

Monthly

Lake In Plant Water Composite - NA 1 Gallon

Monthly

Service Water Plant Water Composite - NA 1 Gallon

Monthly

Plant Drinking Plant Water Composite - NA 1 Gallon

Water

Control Monthly

Ludington Lake Sample Composite - NA 1 Gallon
Proc No HP 10.10

Attachment 4

Revision 9

Page 1 of 1

SAMPLE PACKAGING AND SHIPMENT

1. Label samples clearly per Attachment 3.

2. Seal all liquid, biota, fish, and sediment sample containers with tape to prevent

leakage.

3. Ship liquid samples separately from air particulate and air iodine samples and TLDs.

4. Use sufficient packing material (ie, crumpled newspaper) to avoid possible sample

container damage during shipment.

5. Package air filters in glassine or plastic envelopes.

6. For TLD shipments, make sure that laboratory contractor's own TLD data sheet is

enclosed with package.

7. Ship milk samples as soon as possible. Be sure to add a sufficient amount of

sodium bisulfite (40 grams) as preservative to each sample.

8. Ship food products as soon as possible after collection.

9. Ship fish frozen or packed in ice, or with a 10% formaldehyde solution added

(preservative). Only 10 milliliters is required per sample. Samples should be

shipped as soon as possible after processing.

10. Distribute copies of the Sample Collection Data Sheet(s) to the:

Analytical Laboratory

Radiological Services Department Environmental Contact (Palisades)

11. Send samples to the following address:

Environmental Inc.

Att: Laboratory Manager

700 Landwehr Road

Northbrook, IL 60062

12. Ship all samples to the laboratory contractor with minimal delay after collection so as

to avoid elevated analytical levels of detection.
Proc No HP 10.10

Attachment 5

Revision 9

PALISADES SAMPLE COLLECTION FORMS AND RECORDS Page 1 of 2

PALISADES PLANT

ENVIRONMENTAL MONITOR OPERABILITY CHECK

AND SAMPLE COLLECTION

INSTALLED

(MO/DA/YR)

REMOVED REMOVED

(MO/DAIYR) TIME

GAS METER READING

INSTALLED REMOVED

(Ft 3) (Ft 3)

METER

SERIAL

NO

CAL

DUE

DATE

AS FOUND

FLOW LEAK

(SEC/Ft3) (Y/N)

AS LEFT

FLOW I LEAK

(SEC/Ft3) (Y/N)

FLOW TEST

REPLACEMENT METER

SERIAL

NUMBER SML

CAL DUE CALIB

DATE ACCURACY

SAMPLE VOL

(Ft 3) COMMENTS

ACCEPTABLE

4JS

5PR

8SP

9TP

10OGR

TEST PERFORMED BY:

REVIEWED BY:

DATE:

DATE:
PALISADES SAMPLE COLLECTION FORMS

AND RECORDS

CONSUMERS ENERGY

PALISADES ENVIRONMENTAL TLD REPORT

Proc No HP 10.10

Attachment 5

Revision 9

Page 2 of 2

El QUARTERLY

Collector

STATION - LOCATION INSTALLED COLLECTED

DATE TIME DATE TIME

C-1

C-2

ST1 ST

ST2 TH

ST3 HS

ST4 JS

ST5 PR

ST6 RB

ST7a SN21

ST8 SP

ST9 TP

STIO GR

ST11 KZ

ST12 DG

ST13 ST

ST14 ST

ST15 ST

ST16 ST

ST17 ST

ST18 ST

ST19 ST

ST20 ST

ST21 ST

ST22 CVS

ST23 SN19R

ST24 SN26

ST-33 ST

ST-34 ST

ST-35 ST

ST-36 ST

ST-37 ST

ST-38 ST

SH-1, SH-2 SH

Date TLDs Returned to Vendor For

Date Received From Vendor (With Intransit Date TLDs Inventoried and Placed in Lead Analysis (With Intransit TLDs) and

TLDs) and Initials Cave (With Intransit TLDs) and Initials Initials
ATTACHMENT D

PALISADES FINAL REPORT

RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP)

AS PROVIDED BY ENVIRONMENTAL, INC, MIDWEST LABORATORY

32 Pages Follow
. ;......-... -, ., ...,,.... ... X."."... .... " '

- " Environmental, Inc.

Midwest Laboratory an Allegheny Technologies Co.

700 Landwehr Road - Northbrook, IL 60062-2310

(847) 564-0700 fax (847) 564-4517

FINAL REPORT

TO

CONSUMERS ENERGY COMPANY

JACKSON, MICHIGAN

RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM (REMP)

FOR

PALISADES NUCLEAR GENERATING PLANT

PREPARED AND SUBMITTED

BY

ENVIRONMENTAL INCORPORATED MIDWEST LABORATORY

Project Number: 8022

Reporting Period: January-December, 2006

Reviewed and

Approved by_ Date z2-06-goo.7

Distribution: J. Burnett (1
PALISADES

TABLE OF CONTENTS

Section

1.0

2.0

Appendices

A

B

C

Page

List of Tables ............................................................................................................... iii

INTRO DUCTIO N ..................................................................................................... iv

LISTING O F M ISSED SAM PLES ............................................................................ v

Interlaboratory Com parison Program Results ..................................................... A-1

Data Reporting Conventions ................................................................................ B-1

Special Analyses .................................................................................................. C-1

ii
PALISADES

LIST OF TABLES

No. Page

I Airborne Particulates and Iodine-131

Location 4JS .................................................................................................... 1-4

Location 5PR ................................................................................................... 1-5

Location 8SP ................................................................................................... 1-6

Location 9TP ................................................................................................... 1-7

Location 10GR ................................................................................................. 1-8

2 Gam m a Radiation, as Measured by TLDs, Quarterly Exposure ................................. 2-1

3 Lake W ater, Intake and South Haven (Raw) ................................................................ 3-1

4 W ell W ater, Palisades Drinking W ater ......................................................................... 4-1

5 W ell W ater, Quarterly ................................................................................................... 5-1

6 W ater, Ludington controls ............................................................................................ 6-1

7 In-Plant W ater .............................................................................................................. 7-1

8 M ilk ............................................................................................................................... 8 -1

9 Food Crops ................................................................................................................... 9-1

1 0 F is h ............................................................................................................................. 1 0 -1

11 Bottom Sedim ents ...................................................................................................... 11-1

12 Special Samples

12.1 Liquid Radwaste ............................................................................................ 14.1-1

12.2 Stack Filters ................................................................................................... 14.2-1
1.0 INTRODUCTION

The following constitutes the final 2006 Monthly Progress Report for the Radiological

Environmental Monitoring Program conducted at the Consumers Energy Company, Palisades

Nuclear Generating Plant. Results of completed analyses are presented in the attached tables.

For all gamma isotopic analyses, spectrum is computer scanned from 80 to 2048 KeV.

Specifically included are Mn-54, Fe-59, Co-58, Co-60, Zn-65, Zr-95, Nb-95, 1-131, Ba-La-140,

Cs-134 and Cs-137. Naturally-occuring gamma-emitters, such as K-40 and Ra daughters, are

frequently detected but not listed here. Data listed as "<" are at the 4.66 sigma level, others are

2 sigma.

All concentrations, except gross alpha and gross beta, are decay corrected to the time of

collection.

All samples were collected within the scheduled period unless noted otherwise in the Listing

of Missed Samples.

iv
PALISADES

2.0 LISTING OF MISSED SAMPLES

Expected

Sample Type Location Collection Date Reason

AP/AI 5PR 04-10-06 Sample not obtained.

BS Ludington 04-19-06 Sample not sent.

(Sample received 07-06-06.)

AP/AI 1OGR 05-17-06 Sample not not received from G.R.

F Ludington 05-23-06 Sample not sent.

TLD ST-21 09-30-06 TLD missing in field.

AP/AI 1 0GR 11-22-06 Sample not not received from G.R.

v
PALISADES

Table 1. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-1 31.

Location: 4JS - Covert (3.5 mi. SE)

Units: pCi/m 3

Collection: Continuous, weekly exchange.

Date Volume Date Volume

Collected (M3) Gross Beta 1-131 Collected (M3) Gross Beta 1-131

Required LLD 0.010 0.030 0.010

01-09-06

01-16-06

01-23-06

01-30-06

02-06-06

02-13-06

02-20-06

02-27-06

03-06-06

03-13-06

03-20-06

03-27-06

04-03-06

346

337

343

346

340

346

351

348

337

343

340

340

331

0.022

0.028

0.023

0.026

0.027

0.024

0.035

0.034

0.019

0.022

0.024

0.011

0.019

± 0.003

± 0.004

± 0.003

+ 0.003

± 0.004

± 0.003

± 0.004

+ 0.004

+ 0.003

+ 0.003

± 0.003

± 0.003

± 0.003

< 0.011

< 0.011

< 0.007

< 0.018

< 0.052

< 0.021

< 0.026

< 0.017

< 0.012

< 0.026

< 0.025

< 0.022

< 0.013

07-10-06

07-17-06

07-24-06

07-31-06

08-07-06

08-14-06

08-21-06

08-28-06

09-05-06

09-11-06

09-18-06

09-25-06

10-02-06

320

317

320

314

314

317

317

314

371

263

320

323

337

0.029 ± 0.004

0.027 ± 0.004

0.025 ± 0.004

0.040 ± 0.004

0.028 ± 0.004

0.025 ± 0.004

0.035 ± 0.004

0.036 ± 0.004

0.023 ± 0.004

0.040 ± 0.005

0.028 ± 0.004

,0.023 ± 0.003

0.025 ± 0.003

0.030

< 0.019

< 0.010

< 0.015

< 0.018

< 0.012

< 0.017

< 0.005

< 0.015

< 0.017

< 0.013

< 0.016

< 0.008

< 0.017

1st Qtr. Mean ± s.d. 0.024 ± 0.006 < 0.052 3rd Qtr. Mean ± s.d. 0.030 ± 0.006 < 0.019

04-10-06

04-17-06

04-24-06

05-01-06

05-08-06

05-15-06

05-22-06

05-30-06

06-05-06

06-12-06

06-19-06

06-26-06

07-03-06

337

329

329

334

331

334

331

368

278

323

320

323

320

0.024 ± 0.003

0.031 ± 0.004

0.017 ± 0.003

0.023 ± 0.003

0.019 ± 0.003

0.016 ± 0.003

0.012 ± 0.003

0.030 ± 0.003

0.021 ± 0.004

0.021 ± 0.003

0.026 ± 0.004

0.022 ± 0.001

0.029 ± 0.004

0.022 ± 0.006

< 0.009

< 0.012

< 0.012

< 0.012

< 0.011

< 0.015

< 0.013

< 0.012

< 0.016

< 0.010

< 0.010

< 0.025

< 0.017

< 0.025

10-09-06

10-16-06

10-23-06

10-30-06

11-06-06

11-13-06

11-20-06

11-27-06

12-04-06

12-11-06

12-18-06

12-26-06

01-02-07

314

326

331

331

337

329

334

331

337

343

334

382

334

0.024 ± 0.004

0.019 ± 0.003

0.029 ± 0.004

0.016 ± 0.003

0.034 ± 0.004

0.034 ± 0.004

0.028 ± 0.004

0.036 ± 0.004

0.031 ± 0.004

0.035 ± 0.004

0.040 ± 0.004

0.027 ± 0.003

0.039 ± 0.004

< 0.013

< 0.007

< 0.014

< 0.013

< 0.011

< 0.018

< 0.013

< 0.018

< 0.013

< 0.015

< 0.010

< 0.013

< 0.012

2nd Qtr. Mean ± s.d. 4th Qtr. Mean ± s.d. 0.030 ± 0.007 < 0.018

Cumulative Average

Previous Annual Average

0.027

0.029

a 1-131 LLD not reached due to age of sample.

1-1
PALISADES

Table 1. Airborne particulates and charcoal canisters,

Location: 5PR - Covert (3.5 mi. ESE)

Units: pCi/m 3

Collection: Continuous, weekly exchange.

analyses for gross beta and iodine-131.

Date Volume Date Volume

Collected (M3) Gross Beta 1-131 Collected (M3

) Gross Beta 1-131

Required LLD 0.010

01-09-06

01-16-06

01-23-06

01-30-06

02-06-06

02-13-06

02-20-06

02-27-06

03-06-06

03-13-06

03-20-06

03-27-06

04-03-06

351

346

351

337

334

340

346

340

340

337

133

312

300

0.024

0.025

0.023

0.027

0.024

0.021

0.030

0.035

± 0.004

± 0.003

± 0.003

± 0.004

+ 0.003

± 0.003

± 0.004

+ 0.004

0.030

< 0.011

< 0.011

< 0.007

< 0.018

< 0.059

< 0.034

< 0.019

< 0.017

< 0.012

< 0.026

< 0.063

< 0.024

< 0.015

0.010 0.030

a

a

07-10-06

07-17-06

07-24-06

07-31-06

08-07-06

08-14-06

08-21-06

08-28-06

09-05-06

09-11-06

09-18-06

09-25-06

10-02-06

300

297

300

295

300

300

303

297

354

255

306

312

329

0.025

0.028

0.023

0.048

0.028

0.022

0.034

0.038

± 0.004

± 0.004

± 0.004

± 0.005

± 0.004

± 0.004

± 0.004

± 0.004

< 0.020

< 0.011

< 0.016

< 0.020

< 0.013

< 0.017

< 0.006

< 0.016

< 0.026

< 0.013

< 0.017

< 0.009

< 0.018

0.023 ± 0.003

0.024 ± 0.004

0.029 ± 0.007

0.013 + 0.003

0.024 + 0.004

b

0.019 ± 0.004

0.032 ± 0.005

0.031 ± 0.004

0.024 ± 0.004

0.022 ± 0.003

1st Qtr. Mean ± s.d. 0.025 ± 0.005 < 0.063 3rd Qtr. Mean ± s.d. 0.029 ± 0.008 < 0.026

04-10-06

04-17-06

04-24-06

05-01-06

05-08-06

05-15-06

05-22-06

05-30-06

06-05-06

06-12-06

06-19-06

06-26-06

07-03-06

297

297

309

306

312

312

343

261

303

306

306

300

NDc

0.029 ± 0.004

0.021 ± 0.004

0.027 + 0.004

0.022 ± 0.003

0.019 + 0.003

0.016 ± 0.003

0.031 ± 0.004

0.025 ± 0.004

0.024 ± 0.004

0.024 ± 0.004

0.022 ± 0.001

0.032 ± 0.004

< 0.013

< 0.013

< 0.013

< 0.012

< 0.017

< 0.014

< 0.013

< 0.017

< 0.010

< 0.010

< 0.027

< 0.018

10-09-06

10-16-06

10-23-06

10-30-06

11-06-06

11-13-06

11-20-06

11-27-06

12-04-06

12-11-06

12-18-06

12-26-06

01-02-07

312

317

326

326

329

323

329

323

334

334

329

379

331

0.026 ± 0.004

0.022 ± 0.003

0.028 ± 0.004

0.018 ± 0.003

0.032 ± 0.004

0.029 ± 0.004

0.032 ± 0.004

0.033 ± 0.004

0.029 ± 0.004

0.039 ± 0.004

0.045 ± 0.004

0.028 ± 0.003

0.039 ± 0.004

< 0.013

< 0.007

< 0.014

< 0.013

< 0.012

< 0.018

< 0.013

< 0.019

< 0.013

< 0.015

< 0.008

< 0.013

< 0.012

2nd Qtr. Mean ± s.d. 0.024 ± 0.005 < 0.027 4th Qtr. Mean ± s.d. 0.031 ± 0.007 < 0.019

Cumulative Average

Previous Annual Average

0.027

0.028

a 1-131 LLD not reached due to age of sample. b Pump replaced. C"ND" = No data; see Table 2.0, Listing of Missed Samples.

1-2
PALISADES

Table 1. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-1 31.

Location: 8SP - State Park (1.0 mi. N)

Units: pCi/m 3

Collection: Continuous, weekly exchange.

Date Volume Date Volume

Collected (M3) Gross Beta 1-131 Collected (M3

) Gross Beta 1-131

Required LLD 0.010 0.030 0.010 0.030

01-09-06

01-16-06

01-23-06

01-30-06

02-06-06

02-13-06

02-20-06

02-27-06

03-06-06

03-13-06

03-20-06

03-27-06

04-03-06

374

351

379

374

371

379

385

379

374

374

368

377

360

0.022 ± 0.003

0.030 ± 0.004

0.023 ± 0.003

0.025 ± 0.003

0.023 ± 0.003

0.024 ± 0.003

0.028 ± 0.003

0.034 ± 0.003

0.019 ± 0.003

0.022 ± 0.003

0.021 + 0.003

0.015 + 0.003

0.023 + 0.003

< 0.010

< 0.010

< 0.007

< 0.016

< 0.032

< 0.030

< 0.015

< 0.015

< 0.011

< 0.024

< 0.023

< 0.020

< 0.012

a

07-10-06

07-17-06

07-24-06

07-31-06

08-07-06

08-14-06

08-21-06

08-28-06

09-05-06

09-11-06

09-18-06

09-25-06

10-02-06

348

346

348

340

405

348

351

346

411

295

354

357

374

0.027 ± 0.003

0.027 ± 0.004

0.024 ± 0.003

0.045 ± 0.004

0.024 ± 0.003

0.025 ± 0.003

0.034 ± 0.004

0.036 ± 0.004

0.019 ± 0.003

0.034 ± 0.004

0.031 ± 0.004

0.021 ± 0.003

0.020 ± 0.003

< 0.017

< 0.010

< 0.014

< 0.017

< 0.010

< 0.015

< 0.005

< 0.013

< 0.011

< 0.011

< 0.014

< 0.007

< 0.015

1st Qtr. Mean ± s.d. 0.024 ± 0.005 < 0.032 3rd Qtr. Mean ± s.d. 0.028 ± 0.007 < 0.017

04-10-06

04-17-06

04-24-06

05-01-06

05-08-06

05-15-06

05-22-06

05-30-06

06-05-06

06-12-06

06-19-06

06-26-06

07-03-06

368

354

357

363

340

363

360

402

295

354

348

351

346

0.024 ± 0.003

0.027 ± 0.003

0.017 ± 0.003

0.024 ± 0.003

0.022

0.017

0.012

0.027

0.025

0.022

0.023

0.023

0.031

+ 0.003

+ 0.003

± 0.003

± 0.003

± 0.004

+ 0.003

± 0.003

± 0.001

+ 0.004

< 0.008

< 0.011

< 0.011

< 0.011

< 0.011

< 0.014

< 0.012

< 0.011

< 0.015

< 0.009

< 0.009

< 0.023

< 0.016

10-09-06

10-16-06

10-23-06

10-30-06

11-06-06

11-13-06

11-20-06

11-27-06

12-04-06

12-11-06

12-18-06

12-26-06

01-02-07

348

354

368

371

374

363

371

368

377

377

368

419

374

0.024 ± 0.003

0.019 ± 0.003

0.027 ± 0.003

0.017 ± 0.003

0.033 ± 0.004

0.026 ± 0.003

0.030 ± 0.004

0.032 ± 0.004

0.031 ± 0.003

0.034 ± 0.004

0.039 ± 0.004

0.028 ± 0.003

0.038 ± 0.004

< 0.012

< 0.007

< 0.013

< 0.012

< 0.010

< 0.016

< 0.012

< 0.017

< 0.012

< 0.013

< 0.008

< 0.012

< 0.011

2nd Qtr. Mean ± s.d. 0.023 ± 0.005 <s0.023 4th Qtr. Mean ± s.d. 0.029 ± 0.007 < 0.017

Cumulative Average

Previous Annual Average

0.026

0.028

a 1- 131 LLD not reached due to age of sample.

1-3
PALISADES

Table 1. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-131.

Location: 9TP - Covert Township Park (1.5 mi. SSW)

Units: pCi/m 3

Collection: Continuous, weekly exchange.

Date Volume Date Volume

Collected (M3) Gross Beta 1-131 Collected (M3) Gross Beta 1-131

Required LLD 0.010 0.030 0.010 0.030

01-09-06

01-16-06

01-23-06

01-30-06

02-06-06

02-13-06

02-20-06

02-27-06

03-06-06

03-13-06

03-20-06

03-27-06

04-03-06

365

351

357

357

357

360

368

360

357

351

357

357

346

0.021 ± 0.003

0.028 ± 0.003

0.024 ± 0.003

0.023 ± 0.003

0.024 ± 0.003

0.023 ± 0.003

0.028 + 0.003

0.036 ± 0.004

0.020 . 0.003

0.022 ± 0.003

0.021 ± 0.003

0.015 + 0.003

0.022 + 0.003

< 0.011

< 0.010

< 0.007

< 0.017

< 0.042

< 0.026

< 0.020

< 0.016

< 0.011

< 0.025

< 0.023

< 0.021

< 0.013

a

07-10-06

07-17-06

07-24-06

07-31-06

08-07-06

08-14-06

08-21-06

08-28-06

09-05-06

09-11-06

09-18-06

09-25-06

10-02-06

334

334

334

331

292

334

337

334

130

275

340

351

365

0.026 ± 0.004

0.027 ± 0.004

0.025 ± 0.003

0.040 ± 0.004

0.030 ± 0.004

0.024 ± 0.003

0.029 ± 0.004

0.035 ± 0.004

0.020 ± 0.008

0.028 ± 0.004

0.032 ± 0.004

0.023 ± 0.003

0.020 ± 0.003

< 0.018

< 0.010

< 0.015

< 0.017

< 0.013

< 0.016

< 0.005

< 0.014

< 0.082 b

< 0.012 C

< 0.015

< 0.008

< 0.016

1st Qtr. Mean ± s.d. 0.024 ± 0.005 < 0.042 3rd Qtr. Mean ± s.d. 0.028 ± 0.006 < 0.082

04-10-06

04-17-06

04-24-06

05-01-06

05-08-06

05-15-06

05-22-06

05-30-06

06-05-06

06-12-06

06-19-06

06-26-06

07-03-06

354

340

334

348

343

346

346

326

292

337

334

337

331

0.022 ± 0.003

0.028 ± 0.004

0.017 ± 0.003

0.021 ± 0.003

0.026

0.016

0.014

0.031

0.026

0.025

0.025

0.020

0.026

± 0.003

± 0.003

± 0.003

± 0.004

± 0.004

± 0.003

± 0.003

± 0.001

± 0.004

< 0.009

< 0.012

< 0.012

< 0.011

< 0.011

< 0.015

< 0.013

< 0.013

< 0.015

< 0.009

< 0.009

< 0.024

< 0.017

10-09-06

10-16-06

10-23-06

10-30-06

11-06-06

11-13-06

11-20-06

11-27-06

12-04-06

12-11-06

12-18-06

12-26-06

01-02-07

343

201

317

357

360

354

357

354

363

371

357

416

363

0.024 ± 0.003

0.022 ± 0.005

0.026 ± 0.004

0.019 ± 0.003

0.034

0.026

0.030

0.035

0.032

0.035

0.039

0.029

0.039

± 0.004

± 0.003

± 0.004

± 0.004

± 0.004

± 0.004

+ 0.004

± 0.003

+ 0.004

< 0.012

< 0.012

< 0.015

< 0.012

< 0.011

< 0.016

< 0.012

< 0.017

< 0.012

< 0.013

< 0.006

< 0.012

< 0.011

2nd Qtr. Mean ± s.d. 0.023 ± 0.005 < 0.024 4th Qtr. Mean ± s.d. 0.030 ± 0.006 < 0.017

Cumulative Average

Previous Annual Average

0.026

0.029

a 1-131 LLD not reached due to age of sample.

b Volume low; power off to sampler; GFI tripped. c Pump not running but hot; replaced pump.

1-4
PALISADES

Table 1. Airborne particulates and charcoal canisters, analyses for gross beta and iodine-1 31.

Location: 10GR - Grand Rapids (55 mi. NNE)

Units: pCi/m 3

Collection: Continuous, weekly exchange.

Date Volume Date Volume

Collected (M3) Gross Beta 1-131 Collected (M3

) Gross Beta 1-131

Required LLD 0.010

01-04-06

01-12-06

01-19-06

01-25-06

02-03-06

02-08-06

02-16-06

02-22-06

03-01-06

03-10-06

03-15-06

03-22-06

03-30-06

346

394

354

286

430

269

391

309

348

419

244

337

377

0.023 ± 0.003

0.023 ± 0.003

0.024 ± 0.003

0.039 ± 0.004

0.024 ± 0.003

0.026 ± 0.004

0.026 ± 0.003

0.038 ± 0.004

0.027 ± 0.004

0.019 ± 0.003

0.029 ± 0.005

0.034 ± 0.004

0.014 ± 0.003

0.030

< 0.017

< 0.014

< 0.010

< 0.031

< 0.064

< 0.071

< 0.018

< 0.028

< 0.018

< 0.030

< 0.049

< 0.034

< 0.017

0.010 0.030

a

a

a

a

a

07-05-06

07-12-06

07-19-06

07-26-06

08-02-06

08-09-06

08-16-06

08-23-06

08-30-06

09-06-06

09-13-06

09-20-06

09-25-06

317

303

278

312

278

303

303

295

295

278

314

303

320

0.031 ± 0.004

0.024 ± 0.004

0.039 ± 0.005

0.029 ± 0.004

0.045 ± 0.005

0.029 ± 0.004

0.025 ± 0.004

0.033 ± 0.004

0.039 ± 0.005

0.024 ± 0.004

0.032 ± 0.004

0.031 ± 0.004

0.025 ± 0.004

< 0.029

< 0.017

< 0.027

< 0.029

< 0.021

< 0.027

< 0.008

< 0.024

< 0.064 c

< 0.020

< 0.025

< 0.013

< 0.028

1st Qtr. Mean ± s.d. 0.027 ± 0.007 < 0.071 3rd Qtr. Mean ± s.d. 0.031 ± 0.006 < 0.064

04-05-06

04-13-06

04-21-06

04-28-06

05-03-06

05-10-06

05-17-06

05-24-06

05-31-06

06-07-06

06-14-06

06-21-06

06-28-06

326

329

357

331

229

317

385

303

312

323

312

309

0.023 ± 0.003

0.030 ± 0.004

0.019 ± 0.003

0.022 ± 0.003

0.029 ± 0.005

0.022 ± 0.004

NDb

0.024 ± 0.003

0.037 ± 0.004

0.025 ± 0.004

0.020 ± 0.003

0.029 ± 0.002

0.023 ± 0.004

< 0.013

< 0.017

< 0.015

< 0.015

< 0.023

< 0.025

< 0.018

< 0.024

< 0.016

< 0.015

< 0.040

< 0.027

10-04-06

10-11-06

10-18-06

10-25-06

11-01-06

11-09-06

11-15-06

11-22-06

11-29-06

12-06-06

12-13-06

12-20-06

12-27-06

01-03-07

334

329

337

340

351

0.021 ± 0.003

0.021 ± 0.003

0.019 ± 0.003

0.023 ± 0.003

0.026 ± 0.003

377 0.038 ± 0.004

289 0.021 ± 0.004

NDb

680 0.032 ± 0.002

< 0.019

< 0.011

< 0.022

< 0.019

< 0.017

< 0.022

< 0.022

d < 0.009

< 0.019

< 0.009

< 0.012

< 0.019

< 0.012

a

346

348

343

346

343

0.035 ± 0.004

0.031 ± 0.004

0.043 ± 0.004

0.035 ± 0.004

0.039 ± 0.004

2nd Qtr. Mean ± s.d. 0.025 ± 0.005 < 0.040 4th Qtr. Mean ± s.d. 0.030 ± 0.008 < 0.022

Cumulative Average

Previous Annual Average

0.028

0.031

a LLD not reached due to age of sample.

b,,ND" = no data; see Table 2.0, Listing of Missed Samples.

c LLD not reached due to age of sample; sample received 09-19-06.

d Two-week runtime.

1-5
PALISADES

Table 2. Gamma radiation, as measured by TLDs, quarterly exposure.

Units: mRI91 daysa

Date Placed

Date Removed

Intransit (mR)

1st Qtr.

01-03-06

03-30-06

3.8 ± 0.3

2nd Qtr.

03-30-06

06-30-06

1.7 ± 0.5

3rd Qtr.

06-30-06

09-30-06

1.8 ± 0.3

4th Qtr.

09-30-06

01-03-07

1.6 ± 0.7

ST-01

ST-02

ST-03

ST-04

ST-05

ST-06

ST-07A

ST-08

ST-09

ST-1 0

ST-11

ST-12

ST-13

ST-14

ST-i5

ST- 6

ST-17

ST-18

ST-19

ST-20

ST-21

ST-22

ST-23

ST-24

ST-33

ST-34

ST-35

ST-36

ST-37

ST-38

Mean ± s.d.

Control 1

Control 2

12.1 ± 0.9

16.9 ± 0.8

14.1 ±0.5

14.5 ±0.8

15.1 ±0.7

14.4 ± 0.8

12.7 ± 0.5

12.8 ±0.6

12.3 ± 0.6

13.8 ± 0.9

15.0 ± 0.8

12.9 ± 0.6

12.1 ± 0.8

12.0 ± 0.8

12.0 ± 1.4

12.4 ± 0.8

12.1 ± 0.5

13.1 ± 0.5

14.1 ± 0.6

12.0 ± 0.5

13.7 ± 0.4

7.8 ± 0.4

13.8 ± 0.7

14.8 ± 0.9

12.0 ± 0.7

12.5 ± 0.6

14.9 ± 0.9

12.6 ± 1.1

12.9 ± 0.7

11.9 ± 1.3

13.1 ± 1.6

6.8 ± 0.6

6.9 ± 0.5

11.9 ±0.6

16.5 ± 0.7

13.2 ± 0.5

14.5 ± 0.6

14.1 ± 0.6

12.3 ± 0.5

11.4 ± 0.7

12.1 ± 0.7

11.7 ±0.5

12.8 ± 0.6

16.1 ± 0.7

13.8 ± 0.6

11.4 ± 0.6

9.9 ± 0.5

10.8 ± 0.6

10.7 ± 0.7

10.6 ± 0.6

11.5 ±0.6

11.5 ±0.5

11.3 ± 0.6

10.5 ± 0.8

6.2 ± 0.6

12.3 ± 0.6

13.6 ± 0.6

10.6 ± 0.7

10.9 ± 0.6

12.5 ± 0.7

11.1 ±0.7

11.1 ±0.6

10.9 ± 0.7

11.9 ± 1.9

6.6 ± 0.6

6.8 ± 0.6

12.9 ± 1.3

18.0 ± 1.0

14.9 ± 0.6

15.3 ± 0.6

15.3 ± 0.5

14.8 ± 0.5

13.1 ± 0.4

13.4 ± 0.5

12.7 ± 0.6

14.3 ± 0.4

16.5 ± 0.8

12.6 ± 0.5

12.5 ± 0.8

10.9 ± 0.6

11.9 ± 1.1

11.4 ± 1.0

11.8 ±0.5

12.8 ± 0.5

13.2 ± 0.4

11.9 ±0.4

NDb

7.4 ± 0.5

13.7 ± 0.6

14.5 ± 0.5

12.7 ± 0.6

12.2 ± 0.5

14.5 ± 0.6

12.0 ± 0.4

12.6 ± 0.7

11.3 ± 0.7

13.1 ± 2.0

6.6 ± 0.4

6.7 ± 0.4

14.3 ± 1.0

19.1 ± 1.1

16.3 ± 0.8

17.3 ± 0.8

17.1 ± 0.8

15.4 ± 0.8

14.2 ± 0.8

15.0 ± 0.8

14.7 ± 0.7

15.9 ±0.8

17.8 ±0.8

16.6 ±0.8

13.9 ±0.7

12.4 ±0.7

13.5 ±0.8

13.5 ±0.8

13.1 ±0.9

14.6 ±0.8

14.5 ±0.7

14.3 ±0.7

13.3 ±0.9

7.3 ± 0.7

15.4 ± 0.8

16.7 ±0.8

13.1 ±0.9

13.5 ±0.8

15.6 ± 1.0

13.5 ±0.9

13.9 ± 1.0

13.3 ± 0.9

14.6 ± 2.1

8.0 ± 0.7

8.3 ± 0.8

a Intransit exposure has been subtracted.

b. ND" = No data; TLD missing in field.

2-1
PALISADES

Table 3. Lake Water, analyses for gross alpha, gross beta and tritium.

Collection: Monthly composites of daily collections.

Units: pCi/L

Location Intake

Date Collected Lab Code Gross Beta H-3

Required LLD 4.0 500

01-31-06 PALW -613 1.7 ± 0.4 < 182

02-28-06 PALW -1579 1.4 ± 0.4 < 161

03-31-06 PALW -2230 1.3 ± 0.4 < 137

04-30-06 PALW -3118 1.0 ± 0.4 < 163

05-31-06 PALW -3747 1.3 ± 0.4 < 134

06-30-06 PALW -4481 0.6 ± 0.4 < 166

07-31-06 PALW -5673 2.2 ± 0.8 < 162

08-31-06 PALW -6397 1.9 ± 0.7 < 187

09-30-06 PALW -7095 1.0 ± 0.4 < 162

10-31-06 PALW -8214 1.4 ± 0.4 < 145

11-30-06 PALW -8831 2.1 ± 0.7 < 176

12-31-06 PALW -9578 1.4 ± 0.4 < 147

Lake Water, analysis for gross beta.

Collection: Monthly composites of daily collections.

Units: pCi/L

Location South Haven Municipal System (Raw)

Date Collected Lab Code Gross Beta H-3

Required LLD 4.0 500

01-13-06 PALW -1138 1.5 ± 0.4

02-28-06 PALW -1353 1.1 ± 0.3

03-31-06 PALW -2383 1.1 ± 0.3

05-02-06 PALW -3120 1.7 ± 0.4 < 96a

05-31-06 PALW -4073 1.2 ± 0.3 151 ± 73

06-30-06 PALW -4970 1.0 ± 0.3 < 142

07-31-06 PALW -5674 2.3 ± 0.6 < 162

08-31-06 PALW -6398 1.8 ± 0.5 < 187

09-30-06 PALW -7097 3.4 ± 0.6 < 146

10-31-06 PALW -8217 1.3 ± 0.3 < 145

11-30-06 PALW -8833 1.8 ± 0.6 < 183

12-31-06 PALW -9581 1.6 ± 0.4 < 147

a Analysis added by station.

3-1
PALISADES

Table 4. Well water, analyses for gross beta and tritium.

Collection: Monthly composites of daily collections.

Units: pCi/L

Location South Haven Municipal System (Treated)

Date Collected Lab Code Gross Beta H-3

Required LLD 4.0 500

01-31-06 PAWW -614 2.3 ± 0.6 < 182

02-28-06 PAWW -1580 1.0 ± 0.3 < 162

03-31-06 PAWW -2232 1.5 ± 0.4 240 ± 80

04-30-06 PAWW -3121 1.4 ± 0.4 < 130

05-31-06 PAWW -3748 1.5 ± 0.4 154 ± 78

06-30-06 PAWW -4482 1.1 ± 0.3 194 ± 94

07-31-06 PAWW -5675 2.2 ± 0.6 165 ± 92

08-31-06 PAWW -6399 2.8 ± 0.6 < 187

09-30-06 PAWW -7098 1.9 ± 0.6 < 162

10-31-06 PAWW -8218 1.7 ± 0.4 178 ± 81

11-30-06 PAWW -8834 1.4 ± 0.5 < 183

12-31-06 PAWW -9582 1.6 ± 0.4 < 147

4-1
PALISADES

Table 5. Well water, analyses for gross beta and tritium.

Collection: Quarterly

Units: pCi/L

Location Site Well #14

Date Collected Lab Code Gross Beta H-3

Required LLD 4.0 500

03-22-06 PAWW -1581 2.2 ± 0.4 < 161

05-25-06 PAWW -3749 3.2 ± 0.5 < 135

08-22-06 PAWW -5773 4.0 ± 0.6 < 132

10-27-06 PAWW -8219 5.7 ± 0.7 < 145

Location Site Well #15

Date Collected Lab Code Gross Beta H-3

Required LLD 4.0 500

03-22-06 PAWW -1582 2.5 ± 0.4 < 161

05-25-06 PAWW -3750 5.5 t 0.7 < 135

08-22-06 PAWW -5774 5.1 ± 0.6 < 132

10-27-06 PAWW -8220 5.6 ± 0.7 300 ± 86

NOTE: Gamma isotopic analysis required if gross beta exceeds 10 pCi/L. Results listed in Appendix C.

5-1
PALISADES

Table 5. Well water, analyses for gross beta and tritium.

Collection: Quarterly

Units: pCi/L

Location Site Well #16

Date Collected Lab Code Gross Beta H-3

Required LLD 4.0 500

03-22-06 PAWW 1583,4 8.3 ± 0.5 < 161

05-25-06 PAWW 3751,2 9.4 ± 0.5 < 135

08-22-06 PAWW -5775 a 11.4 ± 0.8 < 145

10-27-06 PAWW -8221 5.0 ± 0.6 < 145

NOTE: Gamma isotopic analysis required if gross beta exceeds 10 pCi/L. Results listed in Appendix C.

a Gross beta recounted with a result of 13.5±1.3 pCi/L.

5-2
PALISADES

Table 6. Water, Ludington controls, analyses for gross beta, tritium and strontium.

Collection: Monthly composites of daily collections.

Units: pCi/L

Location Ludington (Lake In)

Date Collected Lab Code Gross Beta H-3 Sr-89 Sr-90

Required LLD 4.0 500 5.0 1.0

01-31-06 PALW -1137 5.3 ± 0.6 < 160 < 0.9 < 0.6

03-01-06 PALW -1352 1.2 ± 0.3 < 159 < 0.8 < 0.7

03-31-06 PALW -2231 1.4 ± 0.4 < 137 < 0.6 < 0.4

05-02-06 PALW -3119 1.1 ± 0.3 < 163 < 0.7 < 0.6

05-31-06 PALW -4072 1.3 ± 0.3 < 129 < 0.7 < 0.7

07-10-06 PALW -4969 1.9 ± 0.4 < 173 < 0.6 < 0.5

08-01-06 PALW -5772 1.4 ± 0.4 < 132 < 0.7 < 0.6

09-05-06 PALW -6432 1.8 ± 0.6 < 187 < 0.8 < 0.5

10-02-06 PALW -7096 1.1 ± 0.3 < 162 < 0.9 < 0.6

11-01-06 PALW 8215,6 1.9 ± 0.4 < 145 < 0.6 < 0.4

12-04-06 PALW -8832 2.3 ± 0.6 < 183 < 0.8 < 0.6

01-04-07 PALW 9579,80 0.9 ± 0.2 < 147 < 0.6 < 0.5

6-1
PALISADES

Table 7. In-Plant water, analyses for gross alpha, gross beta, strontium-89, strontium-90, tritium and

gamma emitting isotopes.

Collection: Monthly composites

Units: uCi/mL

Location Service Water

Date Collected

Lab Code

Gross Alpha

Gross Beta

H-3

Sr-89

Sr-90

Cs-1 37

Othersa

Required

LLD

1.0 E-07

1.0 E-09

1.0 E-05

5.0 E-08

5.0 E-08

5.0 E-07

5.0 E-07

Required

LLD

1.0 E-07

1.0 E-09

1.0 E-05

5.0 E-08

5.0 E-08

5.0 E-07

5.0 E-07

01-31-06

PACW-611

02-28-06

NSb

< 1.1 E-09

3.5 ± 0.8 E-09

< 1.5 E-07

< 6.3 E-10

< 5.1 E-10

< 5.1 E-09

< 1.8 E-09

04-30-06

NSb

03-31-06

NSb

Date Collected

Lab Code

Gross Alpha

Gross Beta

05-31-06

NSb

H-3

Sr-89

Sr-90

Cs-1 37

Othersa

Co-60

b ,NS" = No sample; sample not sent.

7-1
PALISADES

Table 7. In-Plant water, analyses for gross alpha, gross beta, strontium-89, strontium-90, tritium and

gamma emitting isotopes.

Collection: Monthly composites

Units: uCi/mL

Location Turbine SumD

Date Collected

Lab Code

Gross Alpha

Gross Beta

H-3

Sr-89

Sr-90

Cs-137

Othersa

Required

LLD

1.0 E-07

1.0 E-09

1.0 E-05

5.0 E-08

5.0 E-08

5.0 E-07

5.0 E-07

Required

LLD

1.0 E-07

1.0 E-09

1.0 E-05

5.0 E-08

5.0 E-08

5.0 E-07

5.0 E-07

01-31-06

PACW-612

< 6.7 E-10

1.3 ± 0.6 E-09

1.6 ± 0.1 E-06

< 6.9 E-10

< 5.2 E-10

< 5.5 E-09

< 4.1 E-09

04-30-06

NSb

02-28-06

NSb

03-31-06

NSb

Date Collected

Lab Code

Gross Alpha

Gross Beta

05-31-06

NSb

H-3

Sr-89

Sr-90

Cs-137

Othersa

a Co-60

b "NS" = No sample; sample not sent.

7-2
PALISADES

Table 8. Milk, analyses for iodine-131 and gamma emitting isotopes,

Collection: Monthly

Location JH -Joseph Hay Farm

Date Lab Concentration (pCi/L)

Collected Code 1-131 K-40 Cs-1 34 Cs-137 Ba-La-140

Required LLD 1.0 15.0 18.0 15.0

01-10-06 PAMI 154,5 < 0.4 1312 ± 68 < 3.7 < 3.0 < 1.1

02-07-06 PAMI -606 < 0.2 1295 ± 102 < 4.6 < 3.5 < 1.8

03-07-06 PAMI -1218 < 0.2 1200 ± 141 < 4.7 < 5.8 < 2.0

04-11-06 PAMI -2339 < 0.2 1292 ±+143 < 4.8 < 3.8 < 4.3

05-09-06 PAMI -3126 < 0.3 1217 ± 105 < 4.1 < 4.5 < 1.9

06-12-06 PAMI -3889 <0.3 1310 ± 119 <4.3 <3.2 <2.6

07-18-06 PAMI -4855 < 0.2 1417 ± 120 < 3.7 < 3.3 < 3.6

08-08-06 PAMI -5345 < 0.2 1393 ± 120 < 4.9 < 4.2 < 1.8

09-05-06 PAMI -6041 < 0.4 1499 ± 114 < 4.6 < 3.5 < 3.1

10-10-06 PAMI -7040 < 0.4 1077 ± 110 < 3.5 < 3.4 < 3.5

11-07-06 PAMI -8095 < 0.3 1064 ± 107 < 3.3 < 4.9 < 2.2

12-05-06 PAMI -8734 < 0.3 1279 ± 102 < 3.0 < 3.3 < 2.7

Location DC - Danny Carpenter Farm

Date Lab Concentration (pCi/L)

Collected Code 1-131 K-40 Cs-134 Cs-137 Ba-La-140

Required LLD 1.0 - 15.0 18.0 15.0

01-10-06 PAMI -152 < 0.3 1237 ± 106 < 3.2 < 2.8 < 2.7

02-07-06 PAMI -604 < 0.2 1317 ± 110 < 4.3 < 3.4 < 4.0

03-07-06 PAMI -1216 < 0.3 1455 ± 152 < 5.6 < 5.6 < 5.4

04-11-06 PAMI -2337 < 0.2 1210 ± 52 < 1.8 < 2.2 < 2.4

05-09-06 PAMI -3123 < 0.3 1072 ± 115 < 4.4 < 3.8 < 3.6

06-12-06 PAMI,3886,7 < 0.3 1372 ± 81 < 3.1 < 3.5 < 1.8

07-18-06 PAMI -4853 < 0.5 1347 ± 92 < 2.2 < 3.1 < 3.1

08-08-06 PAMI -5343 < 0.5 1271 ± 108 < 3.4 < 3.4 < 2.3

09-05-06 PAMI -6039 < 0.4 1325 ± 112 < 3.0 < 3.5 < 2.1

10-10-06 PAMI 7037,8 < 0.4 1289 ± 82 < 3.9 < 3.5 < 3.3

11-07-06 PAMI -8093 <0.3 1181 ± 126 <2.9 <2.7 <3.1

12-05-06 PAMI -8732 < 0.3 1422 ± 123 < 4.5 < 4.5 < 2.8

8-1
PALISADES

Table 8. Milk, analyses for iodine-131 and gamma emitting isotopes,

Collection: Monthly

Location DH - Dennis Hessey Farm

Date Lab Concentration (pCi/L)

Collected Code 1-131 K-40 Cs-1 34 Cs-137 Ba-La-140

Required LLD 1.0 - 15.0 18.0 15.0

01-10-06 PAMI -153 < 0.2 1290 ± 114 < 2.8 < 3.3 < 2.4

02-07-06 PAMI -605 < 0.5 1185 ± 107 < 3.2 < 4.2 < 1.6

03-07-06 PAMI -1217 < 0.2 532 ± 73 < 2.8 < 1.6 < 2.1

04-11-06 PAMI -2338 < 0.2 1189 ± 111 < 3.0 < 3.7 < 2.4

05-09-06 PAMI 3124,5 < 0.4 1068 ± 76 < 3.5 < 3.4 < 1.9

06-12-06 PAMI -3888 < 0.2 1171 ± 109 < 3.2 < 3.2 < 1.2

07-19-06 PAMI -4854 < 0.2 1352 ± 116 < 3.9 < 3.7 < 2.6

08-08-06 PAMI -5344 < 0.2 1416 ± 84 < 2.5 < 2.7 < 1.6

09-05-06 PAMI -6040 < 0.5 1458 ± 111 < 2.6 < 3.5 < 2.4

10-10-06 PAMI -7039 < 0.2 1359 ± 117 < 3.4 < 2.6 < 1.6

11-07-06 PAMI -8094 <0.3 1312 ± 118 <2.5 <3.2 <3.3

12-05-06 PAMI -8733 < 0.3 1477 ± 115 < 2.8 < 3.4 < 1.7

Location WS - William Shine Farm

Date Lab Concentration (pCi/L)

Collected Code 1-131 K-40 Cs-134 Cs-137 Ba-La-140

Required LLD 1.0 15.0 18.0 15.0

01-10-06 PAMI -156 < 0.2 1665 ± 92 < 3.3 < 3.4 < 2.5

02-07-06 PAMI -607 < 0.4 1352 ± 106 < 3.1 < 3.5 < 3.0

03-07-06 PAMI -1219 < 0.2 1529 ± 159 < 4.3 < 1.9 < 2.8

04-11-06 PAMI -2340 <0.2 1165 ±58 <2.2 <2.5 < 1.8

05-09-06 PAMI -3127 < 0.3 1176 ± 102 < 2.2 < 4.6 < 1.7

06-12-06 PAMI -3890 < 0.3 1333 ± 143 < 3.4 < 3.1 < 3.3

07-19-06 PAMI -4856 < 0.2 1186 ± 103 < 2.6 < 3.6 < 2.1

08-08-06 PAMI -5346 < 0.4 1245 ± 114 < 2.7 < 3.8 < 2.6

09-05-06 PAMI -6042 < 0.4 1246 ± 104 < 3.4 < 4.4 < 2.5

10-10-06 PAMI -7041 < 0.4 1286 ± 118 < 2.9 < 3.9 < 3.0

11-07-06 PAMI -8096 < 0.3 1526 ± 120 < 3.2 < 4.2 < 2.0

12-05-06 PAMI -8735 < 0.3 1393 ± 124 < 3.7 < 4.9 < 2.7

8-2
PALISADES

Table 9. Food Crops, analyses for gross beta and gamma-emitting isotopes.

Collection: Semiannually, at the time of harvest.

Units: pCi/g wet

Location J. Sarno Farm

Lab Code

Date Collected

Sample Type

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

1-131

Cs-1 34

Cs-1 37

PAVE-6443

8/31/2006

Blueberries

< 0.004

< 0.014

< 0.005

< 0.007

< 0.008

< 0.009

< 0.278

< 0.008

< 0.009

PAVE-6444

9/18/2006

Apples

< 0.017

< 0.035

< 0.010

< 0.018

< 0.026

< 0.023

< 0.030

< 0.014

< 0.010

Req. LLD

0.08

0.10

0.08

0.05

0.10

0.10

0.06 a

0.08

0.08

a Required for broadleaf vegetation only.

9-1
PALISADES

Table 9. Food Crops, analyses for gross beta and gamma-emitting isotopes.

Collection: Semiannually, at the time of harvest.

Units: pCi/g wet

Location Control Station

Lab Code

Date Collected

Sample Type

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

1-131

Cs-134

Cs-137

PAVE-6618,9

9/19/2006

Apples

Req. LLD

< 0.006

< 0.007

< 0.009

< 0.006

< 0.007

< 0.011

< 0.029

< 0.005

< 0.008

0.08

0.10

0.08

0.05

0.10

0.10

0.06 a

0.08

0.08

Required for broadleaf vegetation only.

9-2
PALISADES

Table 10. Fish, analyses for gross beta and gamma-emitting isotopes.

Collection: Semiannually

Units: pCi/g wet

Location Discharae

Lab Code

Date Collected

Sample Type

PAF-3764

5/23/2006

Carp

PAF-5336

8/3/2006

Perch

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

Cs-1 34

Cs-137

< 0.015

< 0.036

<0.013

< 0.009

< 0.021

< 0.023

< 0.015

<0.017

<0.012

< 0.043

<0.013

<0.015

< 0.030

<0.014

<0.012

0.062 ± 0.019

PAF-9574

11/26/2006

Steelhead

<0.015

< 0.046

< 0.027

<0.012

< 0.043

< 0.028

< 0.009

0.036 ± 0.021

0.13

0.26

0.13

0.13

0.26

0.10

0.13

0.15

Req. LLD

Location Ludington Pumped Storage Plant (Control)

Lab Code

Date Collected

Sample Type

N Da

5/23/2006

PAF-5334

8/3/2006

Carp

PAF-5335

8/3/2006

Perch

Req. LLD

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

Cs-1 34

Cs-1 37

< 0.021

< 0.029

<0.015

<0.015

< 0.054

<0.013

<0.013

< 0.025

<0.011

<0.017

<0.019

< 0.022

< 0.044

<0.033

< 0.021

< 0.028

0.13

0.26

0.13

0.13

0.26

0.10

0.13

0.15

Location Ludington Pumped Storage Plant (Control)

Lab Code

Date Collected

Sample Type

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

Cs-1 34

Cs-137

PAF-9575b

7/16/2006

Chinook Salmon

< 0.010

< 0.165

< 0.035

< 0.007

< 0.029

< 0.298

< 0.009

0.059 ± 0.012

PAF-9576

12/29/2006 Req. LLD

Steelhead Trout

<0.010

< 0.023

< 0.022

< 0.015

< 0.025

< 0.022

< 0.016

0.029 ± 0.016

0.13

0.26

0.13

0.13

0.26

0.10

0.13

0.15

a "ND" = No data; sample not sent.

b Certain LLDs not reached due to age of sample; received 01-16-07.

10-1
PALISADES

Table 11. Bottom sediment, analyses for gamma-emitting isotopes.

Collection: Semiannually

Units: pCi/g dry

Location Palisades North Property

Lab Code

Date Collected

PABS-3122

4/19/2006

PABS-8803

11/9/2006 Req. LLD

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

Cs-I 34

Cs-1 37

< 0.017

< 0.052

< 0.025

< 0.013

< 0.052

< 0.035

< 0.029

< 0.015

< 0.020

< 0.061

< 0.019

< 0.022

* 0.061

< 0.025

< 0.019

* 0.017

0.08

0.10

0.08

0.05

0.10

0.10

0.15

0.18

Location Ludington Control

Lab Code

Date Collected

PABS-4480

6/16/2006

PABS-9577

12/27/2006 Req. LLD

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

Cs-1 34

Cs-137

* 0.014

< 0.025

< 0.014

< 0.012

* 0.042

< 0.031

< 0.017

* 0.016

< 0.014

< 0.029

< 0.013

* 0.013

< 0.033

< 0.020

< 0.017

* 0.015

0.08

0.10

0.08

0.05

0.10

0.10

0.15

0.18

11-1
PALISADES

Table 12.1. Liquid Radwaste, analyses for gross alpha, tritium, strontium-89, strontium-90,

plutonium-239 and gamma emitting isotopes.

Collection: Monthly

Units: uCi/ml

Lab Code

Date Collected

Gross Alpha

Required

LLD

1.0 E-07

PARW-471

01-01-06

NSa

02-01-06 03-01-06

NSa

2.3 ± 0.5 E-08

H-3 1.0 E-05 5.19 ± 0.01 E-01

5.0 E-08 3.85 ± 0.8 E-08

5.0 E-08 3.61 ± 0.3 E-08

Sr-89

Sr-90

Pu-239

Cr-51

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-95

Nb-95

Ag-1 1Om

Sb-124

Cs-134

Cs-137

Ba-140

La-140

Ce-141

Ce-144

5.0 E-08

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

< 3.23 E-10

< 7.41

< 7.21

<1.11

1.87 + 0.20

7.91 ± 0.05

2.80 + 0.46

< 6.94

1.07 ± 0.36

5.83 ± 0.24

9.50 ± 1.00

8.52 ± 3.13

2.54 ± 0.21

< 7.86

< 6.94

< 9.46

<2.30

E-07

E-07

E-07

E-07

E-06

E-08

E-08

E-07

E-07

E-07

E-08

E-07

E-07

E-08

E-08

E-07

a No sample received.

12.1-1
PALISADES

Table 12.1. Liquid Radwaste, analyses for gross alpha, tritium, strontium-89, strontium-90,

plutonium-239 and gamma emitting isotopes.

Collection: Monthly

Units: uCi/ml

Lab Code

Date Collected

Gross Alpha

H-3

Sr-89

Sr-90

Pu-239

Cr-51

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-95

Nb-95

Ag-110m

Sb-1 24

Cs-134

Cs-137

Ba-140

La-140

Ce-141

Ce-144

Required

LLD

1.0 E-07

1.0 E-05

5.0 E-08

5.0 E-08

5.0 E-08

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

5.0 E-07

NSa

04-30-06

NSa

05-31-06

a No sample received.

12.1-2
PALISADES

Table 12.2. Stack Filters, analyses for gross alpha, plutonium-239, strontium-89 and strontium-90.

Collection: Continuous, monthly exchange.

Units: pCi/filter

Location Palisades

Date Collected Lab Code Gross Alpha Sr-89 Sr-90 Pu-239

Required LLD 10 10 10 10

01-31-06

02-28-06

03-31-06

04-30-06

05-31-06

PASP -548

NSa

NSa

NSa

NSa

< 0.5 < 6.7 < 3.4 < 4.8

"'NS" = No sample; sample not sent.

12.2-1
- •i• Environmental, Inc.

Midwest Laboratory an Allegheny Technologies Co.

700 Landwehr Road • Northbrook, IL 60062-2310

ph. (847) 564-0700 • fax (847) 564-4517

APPENDIX A

INTERLABORATORY COMPARISON PROGRAM RESULTS

NOTE: Environmental Inc., Midwest Laboratory participates in intercomparison studies administered by

Environmental Resources Associates, and serves as a replacement for studies conducted previously

by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. Results are

reported in Appendix A. TLD Intercomparison results, in-house spikes, blanks, duplicates and

mixed analyte performance evaluation program results are also reported. Appendix A is updated

four times a year; the complete Appendix is included in March, June, September and December

monthly progress reports only.

October, 2005 through September, 2006
APPENDIX B

DATA REPORTING CONVENTIONS.

B-1
Data Reporting Conventions

1.0. All activities, except gross alpha and gross beta, are decay corrected to collection time or the end of

the collection period.

2.0. Single Measurements

Each single measurement is reported as follows: x _ s

where: x = value of the measurement;

s =2s counting uncertainty (corresponding to~the,95%.confidence level).

.In cases where the activity is less than the lower limit of detection.L, 'it ,is reported as: <L,

where L = the lower limit of detection based on 4.66s uncertainty for'a background -sample.,

3.0. Duplicate analyses

3.1 Individual results: For two analysis results; xi ± sl and X2 ±s2

Reported result: x ±-s; where x = (1/2) (xi + x2) and s = /(1i2) 21 2

3.2. Individual results: <L1 , <L2 Reported result:!<L;,whereL=.lower of.-Ll andL2

3.3. Individual results: x +s, <L Reported result: . x ± sifx _>L;,<otherwise.

4.0. Computation of Averaaes and-Standard Deviations

4.1 Averages and standard deviations listed in the tables are computed from all of the individual

measurements over the period averaged; for example, an annual standard deviation would not be the

average of quarterly standard deviations. The average x and standard deviation s of a set of n

numbers x1 , x2 ... xn are defined as follows:

n= x~ n-1

4.2 Values below the highest lower limit of detection are not included in the average.

4.3 If all values in the averaging group are less than the highest LLD, the highest LLD is reported.

4.4 If all but one of the values are less than the highest LLD, the single value x and associated two sigma

error is reported.

4.5 In rounding off, the following rules are followed:

4.5.1. If the number following those to be retained is less than 5, the number is dropped, and the

retained number s are kept unchanged. As an example, 11.443 is rounded off to 11.44.

4.5.2. If the number following those to be retained is equal to or greater than 5, the number is dropped

and the last retained number is raised by 1. As an example, 11.445 is rounded off to 11.45.

B-2
PALISADES

APPENDIX C

SPECIAL ANALYSES

C-1
PALISADES

Appendix C: Gamma isotopic

Units: pCi/L

Lab Code

Date Collected

K-40

Mn-54

Fe-59

Co-58

Co-60

Zn-65

Zr-Nb-95

Cs-134

Cs-137

Ce-141

Ce-144

PAWW-5775

08-22-06

< 70.6

< 2.3

<8.1

< 4.8

< 2.3

< 5.4

< 11.4

< 3.5

< 3.0

< 19.7

< 25.1

C-2
ATTACHMENT E

ENVIRONMENTAL, INC, MIDWEST LABORATORY,

INTERLABORATORY COMPARISON PROGRAM RESULTS

17 Pages Follow
- • Environmental, Inc.

Midwest Laboratory an Allegheny Technologies Co.

700 Landwehr Road ° Northbrook, IL 60062-2310

ph. (847) 564-0700 • fax (847) 564-4517

APPENDIX A

INTERLABORATORY COMPARISON PROGRAM RESULTS

NOTE: Environmental Inc., Midwest Laboratory participates in intercomparison studies administered by

Environmental Resources Associates, and serves as a replacement for studies conducted previously

by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. Results are

reported in Appendix A. TLD Intercomparison results, in-house spikes, blanks, duplicates and

mixed analyte performance evaluation program results are also reported. Appendix A is updated

four times a year; the complete Appendix is included in March, June, September and December

monthly progress reports only.

January, 2006 through December, 2006
Appendix A

Interlaboratory Comparison Proqram Results

Environmental, Inc., Midwest Laboratory has participated in interlaboratory comparison (crosscheck)

programs since the formulation of it's quality control program in December 1971. These programs are

operated by agencies which supply environmental type samples containing concentrations of radionuclides

known to the issuing agency but not to participant laboratories. The purpose of such a program is to provide

an independent check on a laboratory's analytical procedures and to alert it of any possible problems.

Participant laboratories measure the concentration of specified radionuclides and report them to the issuing

agency. Several months later, the agency reports the known values to the participant laboratories and

specifies control limits. Results consistently higher or lower than the known values or outside the control

limits indicate a need to check the instruments or procedures used.

Results in Table A-1 were obtained through participation in the environmental sample crosscheck program

administered by Environmental Resources Associates, serving as a replacement for studies conducted

previously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada.

The results in Table A-2 list results for thermoluminescent dosimeters (TLDs), via International

Intercomparison of Environmental Dosimeters, when available, and internal laboratory testing.

Table A-3 lists results of the analyses on in-house "spiked" samples for the past twelve months. All samples

are prepared using NIST traceable sources. Data for previous years available upon request.

Table A-4 lists results of the analyses on in-house "blank" samples for the past twelve months. Data for

previous years available upon request.

Table A-5 list results of the in-house "duplicate" program for the past twelve months. Acceptance is based

on the difference of the results being less than the sum of the errors. Data for previous years available upon

request.

The results in Table A-6 were obtained through participation in the Mixed Analyte Performance Evaluation

Program.

Attachment A lists acceptance criteria for "spiked" samples.

Out-of-limit results are explained directly below the result.

Al
Attachment A

ACCEPTANCE CRITERIA FOR "SPIKED" SAMPLES

LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSESa

One standard deviation

Analysis Level for single determination

Gamma Emitters

Strontium-89b

Strontium-90b

Potassium-40

Gross alpha

5 to 100 pCi/liter or kg

> 100 pCi/liter or kg

5 to 50 pCi/liter or kg

> 50 pCi/liter or kg

2 to 30 pCi/liter or kg

> 30 pCi/liter or kg

Gross beta

> 0.1 g/liter or kg

< 20 pCi/liter

> 20 pCi/liter

< 100 pCi/liter

> 100 pCi/liter

< 4,000 pCi/liter

> 4,000 pCi/liter

Tritium

5.0 pCi/liter

5% of known value

5.0 pCi/liter

10% of known value

5.0 pCi/liter

10% of known value

5% of known value

5.0 pCi/liter

25% of known value

5.0 pCi/liter

5% of known value

1 1a = (pCi/liter) =

169.85 x (known)0 0 933

10% of known value

15% of known value

10% of known value

6.0 pCi/liter

10% of known value

6.0 pCi/liter

15% of known value

10 pCi/liter

10% of known value

20% of known value

Radium-226,-228 a 0.1 pCi/liter

Plutonium > 0.1 pCi/liter, gram, or sample

Iodine-1 31,

Iodine-1 2 9 b

Uranium-238,

Nickel-63b

Technetium-99b

< 55 pCi/liter

> 55 pCi/liter

< 35 pCi/liter

> 35 pCi/liter

Iron-55b 50 to 100 pCi/liter

> 100 pCi/liter

Othersb

a From EPA publication, "Environmental Radioactivity Laboratory Intercomparison Studies

Program, Fiscal Year, 1981-1982, EPA-600/4-81-004.

b Laboratory limit.

A2
TABLE A-1. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.

Concentration (pCi/L)

Lab Code Date Analysis Laboratory ERA Control

Resultb Resultc Limits Acceptance

STW-1 078

STW-1 078

STW-1 079

STW-1079

STW-1079

STW-1 079

STW-1 079

STW-1080

STW-1 080

STW-1081

01/16/06

01/16/06

01/16/06

01/16/06

01/16/06

01/16/06

01/16/06

01/16/06

01/16/06

01/16/06

Sr-89

Sr-90

Ba-133

Co-60

Cs-134

Cs-137

Zn-65

Gr. Alpha

Gr. Beta

Ra-226

STW-1081 01/16/06 Ra-228

STW-1081 01/16/06 Uranium

STW-1 088

STW-1 088

STW-1089

STW-1089

STW-1 089

STW-1089

STW-1 089

STW-1 090

STW-1090

STW-1091

STW-1 092

STW-1 092

STW-1 092

STW-1092

STW- 1094

STW-1094

STW-1 095

STW-1 095

STW-1095

STW-1 095

STW-1095

STW-1096

STW-1 096

STW-1 097

STW-1 097

STW-1097

04/10/06

04/10/06

04/10/06

04/10/06

.04/10/06

04/10/06

04/10/06

04/10/06

04/10/06

04/10/06

04/10/06

04/10/06

04/10/06

04/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

07/10/06

Sr-89

Sr-90

Ba-1 33

Co-60

Cs-1 34

Cs-1 37

Zn-65

Gr. Alpha

Gr. Beta

1-131

H-3

Ra-226

Ra-228

Uranium

Sr-89

Sr-90

Ba-133

Co-60

Cs-1 34

Cs-1 37

Zn-65

Gr. Alpha

Gr. Beta

Ra-226

Ra-228

Uranium

49.9 ± 3.5

31.5 ± 1.5

86.5 ± 4.1

96.3 ± 4.1

22.6 ± 3.0

109.0 ± 5.9

198.0 ± 11.2

10.8 ± 1.4

56.9 ± 1.9

4.3 ± 0.4

7.1 ± 1.8

20.7 ± 0.5

29.0 ± 1.8

8.7 ± 1.0

10.3 ± 0.4

114.0 ±2.8

41.9 ± 1.4

208.0 ± 1.1

154.0 ± 0.8

13.4 ± 1.1

27.7 ± 2.1

22.0 ± 0.3

7960.0 ± 57.0

2.9 ± 0.4

20.9 ± 1.2

68.6 ± 3.4

15.9 ± 0.7

24.3 ± 0.4

94.9 ± 8.9

104.0 ± 1.8

48.7 ± 1.3

236.0 ± 3.0

126.0 ± 8.0

10.9 ± 1.0

9.7 ± 0.4

11.0 ±0.5

12.2 ± 0.8

43.4 ± 0.1

50.2

30.7

95.0

95.3

23.1

111.0

192.0

9.6

61.9

4.6

6.6

22.1

32.4

9.0

10.0

113.0

43.4

214.0

152.0

21.3

23.0

19.1

8130.0

3.0

19.1

69.1

19.7

25.9

88.1

99.7

54.1

238.0

121.0

10.0

8.9

10.7

10.7

40.3

41.5

22.0

78.6

86.6

14.4

101.0

159.0

1.0

44.6

3.4

- 58.9

- 39.4

-111.0

-104.0

-31.8

-121.0

- 225.0

- 18.3

- 79.2

-5.8

3.7 - 9.5

16.9 -27.3

23.7 -41.1

0.3 - 17.7

1.3 -18.7

103.0 - 123.0

34.7 - 52.1

195.0 -233.0

126.0 - 178.0

12.1 -30.5

14.3 -31.7

13.9 -24.3

6720.0 - 9540.0

2.2 - 3.8

10.8 -27.4

57.1 -81.1

11.0 -28.4

17.2 -34.6

72.9 - 103.0

91.0 -108.0

45.4 - 62.8

217.0 -259.0

100.0 - 142.0

1.3 -18.6

0.2 -17.5

7.9 - 13.5

6.1 -15.3

33.3 - 47.3

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Al-1
TABLE A-1. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.

Concentration (pCi/L)

Lab Code Date Analysis Laboratory ERA Control

Resultb Resultc Limits Acceptance

STW-1104

STW-1104

STW-1105

STW-1105

STW-1105

STW-1105

STW-1105

STW-1106

STW-1106

STW-1107 d

STW-1108

STW-1108

STW-1108

STW-1109

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

10/06/06

Sr-89

Sr-90

Ba-1 33

Co-60

Cs-1 34

Cs-1 37

Zn-65

Gr. Alpha

Gr. Beta

1-131

Ra-226

Ra-228

Uranium

H-3

38.4 ± 1.3

15.5 ± 0.5

64.9 ± 2.8

61.6 ± 1.0

29.0 ± 0.9

77.8 ± 2.4

293.0 ± 2.4

23.9 ± 2.5

23.7 t 1.4

28.4 ± 1.2

14.5 ± 0.5

6.6 ± 0.4

2.9 ± 0.1

3000.0 ± 142.0

39.9

16.0

70.2

62.3

29.9

78.2

277.0

28.7

20.9

22.1

14.4

5.9

3.2

3050.0

31.2 -45.7

7.3 - 24.7

58.1 - 82.3

53.6 - 71.0

21.2 -38.6

69.5 - 86.9

229.0 - 325.0

16.3 -41.1

12.2 - 29.6

16.9 - 27.3

10.7 -18.1

3.3 - 8.4

0.0 - 8.4

2430.0 - 3670.0

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Fail

Pass

Pass

Pass

Pass

a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency

testing in drinking water conducted by Environmental Resources Associates (ERA).

b Unless otherwise indicated, the laboratory result is given as the mean ± standard deviation for three determinations.

c Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits

as provided by ERA.

d The reported result was an average of three analyses, results ranged from 25.36 to 29.23 pCi/L.

A fourth analysis was performed, result of analysis, 24.89 pCi/L.

A1-2
TABLE A-2. Crosscheck program results; Thermoluminescent Dosimetry, (TLD, CaSO4: Dy Cards).

mR

Lab Code Date Known Lab Result Control

Description Value ± 2 sigma Limits Acceptance

Environmental, Inc.

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

2006-1 6/5/2006

Environmental, Inc.

30 cm

60 cm

60 cm

90 cm

120 cm

120 cm

150 cm

150 cm

180 cm

30 cm.

40 cm.

50 cm.

60 cm.

75 cm.

90 cm.

120 cm.

150 cm.

180 cm.

54.81

13.70

13.70

6.09

3.43

3.43

2.19

2.19

1.52

55.61

31.28

20.02

13.90

8.90

6.18

3.48

2.22

1.54

70.73 ± 0.69

16.71 ± 1.89

16.69 ± 0.94

6.57 ± 0.82

3.65 ± 0.22

3.09 ± 0.33

2.35 ± 0.38

1.98 ± 0.10

1.56 ± 0.26

60.79 ± 1.32

35.93 ± 3.70

21.55 ± 1.20

14.90 ± 1.42

8.03 ± 0.51

6.88 ± 0.68

2.90 ± 0.20

1.99 ± 0.07

1.79 ± 0.94

38.37 -71.25

9.59 - 17.81

9.59 - 17.81

4.26 - 7.92

2.40 - 4.46

2.40 - 4.46

1.53 - 2.85

1.53 - 2.85

1.06 - 1.98

38.93 - 72.29

21.90 - 40.66

14.01 - 26.03

9.73 -18.07

6.23 - 11.57

4.33 - 8.03

2.44 - 4.52

1.55 -2.89

1.08 -2.00

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

2006-2

2006-2

2006-2

2006-2

2006-2

2006-2

2006-2

2006-2

2006-2

11/6/2006

11/6/2006

11/6/2006

11/6/2006

11/6/2006

11/6/2006

11/6/2006

11/6/2006

11/6/2006

A2-1
TABLE A-3. In-House "Spike" Samples

Concentration (pCi/L)a

Lab Code b Date Analysis Laboratory results Known Control

2s, n=1 c Activity Limits d Acceptance

SPW-301

SPAP-1 224

SPAP-1224

SPAP-1 224

SPW-1228

SPW-1230

SPW-1230

SPMI-1232

SPMI-1232

W-30906

W-30906

SPW-2750

SPW-2869

SPAP-2871

SPAP-2871

SPW-2875

STSO-3155

STSO-3155

STSO-3155

SPAP-2873

SPF-3183

SPF-3183

SPW-3460

W-60606

W-60606

SPW-3988

SPW-3988

SPW-3988

SPW-3988

SPW-3988

SPMI-3990

SPMI-3990

SPMI-3990

SPMI-3991

SPW-4356

W-90506

W-90506

SPAP-6950

SPAP-6950

SPAP-6952

1/20/2006

3/7/2006

3/7/2006

3/7/2006

3/7/2006

3/7/2006

3/7/2006

3/7/2006

3/7/2006

3/9/2006

3/9/2006

4/27/2006

5/1/2006

5/1/2006

5/1/2006

5/1/2006

5/1/2006

5/1/2006

5/1/2006

5/2/2006

5/10/2006

5/10/2006

5/26/2006

6/6/2006

6/6/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

7/5/2006

9/5/2006

9/5/2006

9/30/2006

9/30/2006

9/30/2006

Fe-55

Cs-1 34

Cs-137

Gr. Beta

H-3

Cs-134

Cs-1 37

Cs-1 34

Cs-1 37

Gr. Alpha

Gr. Beta

Ni-63

Fe-55

Cs-1 34

Cs-1 37

H-3

Co-60

Cs-1 34

Cs-1 37

Gr. Beta

Cs-1 37

Cs-1 34

C-14

Gr. Alpha

Gr. Beta

Cs-1 34

Cs-1 37

1-131(G)

Sr-89

Sr-90

Cs-1 34

Cs-1 37

1-131(G)

1-131

1-131

Gr. Alpha

Gr. Beta

Cs-1 34

Cs-1 37

Gr. Beta

2700.10 ± 70.00

37.13 ± 3.70

118.25 ± 8.97

520.32 ± 7.42

70891.00 ± 719.00

38.58 ± 2.10

59.44 ± 4.51

41.20 ± 1.33

57.82 ± 3.96

24.24 ± 0.47

63.79 ± 0.48

116.00 ± 2.49

19473.00 ± 188.00

33.97 ± 1.10

114.44 ± 2.81

71057.00 ± 730.20

7950.80 ± 67.29

12.49 ± 0.13

14.10 ± 0.12

1724.80 ± 4.51

2.47 ± 0.03

0.73 ± 0.01

4009.60 ± 14.43

21.94 ± 0.46

58.17 ± 0.49

35.56 ± 1.40

60.23 ± 2.72

94.01 ± 4.38

52.40 ± 4.23

45.35 ± 1.95

35.52 ± 5.05

56.78 ± 3.86

95.04 ± 5.05

96.55 ± 0.87

80.88 ± 1.09

23.11 ± 0.45

65.01 ± 0.51

28.93 ± 1.56

116.62 ± 2.97

52.96 ± 0.14

2502.50

39.52

119.30

455.00

75394.00

39.51

59.65

39.51

59.65

20.08

65.73

100.00

23332.00

37.50

118.90

75394.00

7750.00

11.59

11.63

1744.00

2.38

0.74

4741.00

20.08

65.73

36.00

59.27

99.30

58.16

41.21

36.00

59.27

99.30

99.30

77.23

20.08

65.73

32.65

117.75

53.50

2002.00 - 3003.00

29.52 - 49.52

107.37 -131.23

364.00 - 637.00

60315.20 - 90472.80

29.51 -49.51

49.65 - 69.65

29.51 - 49.51

49.65 - 69.65

10.04 -30.12

55.73 - 75.73

60.00 - 140.00

18665.60 -27998.40

27.50 - 47.50

107.01 - 130.79

60315.20 -90472.80

6975.00 - 8525.00

1.59 -21.59

1.63 -21.63

1395.20 -2441.60

1.43 -3.33

0.44-1.04

2844.60 - 6637.40

10.04 -30.12

55.73 - 75.73

26.00 - 46.00

49.27 - 69.27

89.30 - 109.30

46.53 - 69.79

32.97 - 49.45

26.00 - 46.00

49.27 - 69.27

89.30 - 109.30

79.44 - 119.16

61.78 - 92.68

10.04 -30.12

55.73 - 75.73

22.65 - 42.65

105.98 - 129.53

42.80 - 74.90

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

A3-1
TABLE A-3. In-House "Spike" Samples

Concentration (pCi/L)

Lab Code Date Analysis Laboratory results Known Control

2s, n=1 b Activity Limitsc Acceptance

SPW-6954

SPW-6954

SPMI-6956

SPMI-6956

W-1 20106

W-120106

SPAP-9476

SPAP-9478

SPAP-9478

SPW-9480

SPW-9483

SPW-9488

SPW-9488

SPMI-9490

SPMI-9490

SPF-9492

SPF-9492

9/30/2006

9/30/2006

9/30/2006

9/30/2006

12/1/2006

12/1/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

Cs-134

Cs-137

Cs-1 34

Cs-1 37

Gr. Alpha

Gr. Beta

Gr. Beta

Cs-1 34

Cs-1 37

H-3

Tc-99

Cs-1 34

Cs-1 37

Cs-1 34

Cs-137

Cs-134

Cs-137

63.29 ± 8.24

60.41 ± 7.53

69.26 ± 4.85

61.35 ± 7.62

22.40 ± 1.03

63.70 ± 1.14

57.51 ±0.14

26.84 ± 1.23

110.54 ± 3.12

68972.20 ± 748.00

29.43 ± 0.84

61.35 ± 1.65

60.30 ± 2.76

58.99 ± 5.43

54.16 ± 7.85

0.64 ± 0.01

2.61 ± 0.03

65.30

58.87

65.31

58.87

20.08

65.73

53.16

30.06

117.10

72051.60

32.98

60.10

56.80

60.10

56.80

0.60

2.34

55.30 - 75.30

48.87 - 68.87

55.31 - 75.31

48.87 - 68.87

10.04 -30.12

55.73 - 75.73

42.53 - 74.42

20.06 - 40.06

105.39 - 128.81

57641.28 - 86461.92

20.98 - 44.98

50.10 -70.10

46.80 - 66.80

50.10 - 70.10

46.80 - 66.80

0.36 - 0.84

1.40 - 3.28

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

a Liquid sample results are reported in pCi/Liter, air filters( pCi/filter), charcoal (pCi/m 3

), and solid samples (pCi/g).

b Laboratory codes as follows: W (water), Ml (milk), AP (air filter), SO (soil), VE (vegetation),

CH (charcoal canister), F (fish).

c Results are based on single determinations.

d Control limits are based on Attachment A, Page A2 of this report.

NOTE: For fish, Jello is used for the Spike matrix. For Vegetation, cabbage is used for the Spike matrix.

A3-2
TABLE A-4. In-House "Blank" Samples

Concentration (pCi/L)a

Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance

Type LLD Activityc Criteria (4.66 a)

SPW-302

SPAP-1225

SPW-1231

SPW-1231

W-30906

W-30906

SPW-2751

SPW-2868

SPW-2874

SPAP-2872

SPF-3154

SPF-3154

SPW-3461

W-60606

W-60606

SPW-3989

SPW-3989

SPW-3989

SPW-3989

SPW-3989

SPW-3989

SPMI-3991

SPMI-3991

SPMI-3991

SPMI-3991

SPMI-3991

SPMI-3991 d

W-90506

W-90506

SPMI-6383

SPMI-6383

SPAP-6949

SPAP-6949

SPAP-6951

SPW-6953

SPW-6953

SPW-6953

SPW-6953

water

Air Filter

water

water

water

water

water

water

water

Air Filter

Fish

Fish

water

water

water

water

water

water

water

water

water

Milk

Milk

Milk

Milk

Milk

Milk

water

water

Milk

Milk

Air Filter

Air Filter

Air Filter

water

water

water

water

1/20/2006

3/7/2006

3/7/2006

3/7/2006

3/9/2006

3/9/2006

4/27/2006

5/1/2006

5/1/2006

5/2/2006

5/10/2006

5/10/2006

5/26/2006

6/6/2006

6/6/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

6/16/2006

9/5/2006

9/5/2006

9/14/2006

9/14/2006

9/30/2006

9/30/2006

9/30/2006

9/30/2006

9/30/2006

9/30/2006

9/30/2006

Fe-55

Gr. Beta

Cs-1 34

Cs-1 37

Gr. Alpha

Gr. Beta

Ni-63

Fe-55

H-3

Gr. Beta

Cs-1 34

Cs-1 37

C-14

Gr. Alpha

Gr. Beta

Cs-134

Cs-1 37

1-131

1-131(G)

Sr-89

Sr-90

Cs-1 34

Cs-1 37

1-131

1-131(G)

Sr-89

Sr-90

Gr. Alpha

Gr. Beta

Sr-89

Sr-90

Cs-1 34

Cs-1 37

Gr. Beta

Cs-1 34

Cs-137

Sr-89

Sr-90

1061

1.16

2.71

2.05

0.037

0.076

1.48

18.07

166.00

1.18

16.4

13.7

10.20

0.05

0.16

3.00

3.65

0.21

8.34

0.54

0.58

4.42

3.88

0.28

3.76

0.61

0.52

0.06

0.16

0.97

0.57

0.89

0.91

1.12

3.91

5.61

0.79

0.60

-91 ± 637

-0.512 ± 51.20

0.005 ± 0.026

-0.016 ± 0.052

0.37 ± 0.91

4.33 ± 11.27

-8.3 ± 86.9

-3.65 ± 0.64

-7.9 ± 5.20

0.013 ± 0.037

-0.044 ± 0.11

0.045 ± 0.14

0.005 ± 0.45

-0.079 ± 0.26

-0.22 ± 0.19

-0.25 ± 0.76

0.88 ± 0.34

0.00 ± 0.04

0.05 ±_0.11

-0.18 ± 0.92

0.65 ± 0.33

-0.54 ± 0.64

-0.14 ± 0.64

0.11 ± 0.29

1000

3.2

10

10

1

3.2

20

1000

200

3.2

100

100

200

1

3.2

10

10

0.5

20

5

1

10

10

0.5

20

5

1

1

3.2

5

1

100

100

3.2

10

10

5

1

A4-1
TABLE A-4. In-House "Blank" Samples

Concentration (pCi/L)a

Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance

Type LLD Activityc Criteria (4.66 a)

SPMI-6955

SPMI-6955

SPMI-6955

W-120106

W-120106

SPAP-9477

SPAP-9479

SPW-9481

SPW-9483

SPW-9489

SPMI-9491

SPMI-9491

SPMI-9491

SPF-9493

SPF-9493

Milk

Milk

Milk

water

water

Air Filter

Air Filter

water

water

water

Milk

Milk

Milk

Fish

Fish

9/30/2006

9/30/2006

9/30/2006

12/1/2006

12/1/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

12/29/2006

Cs-134

Cs-137

1-131(G)

Gr. Alpha

Gr. Beta

Gr. Beta

Cs-1 37

H-3

Tc-99

Cs-134

Cs-134

Cs-137

1-131(G)

Cs-1 34

Cs-1 37

2.86

2.39

9.98

0.11

0.30

1.13

0.87

146.2

0.95

2.30

3.10

2.90

8.00

7.6

7.9

0.066 ± 0.072

0.093 ± 0.16

-0.37 ± 0.66

63.2 ± 80.1

-1.20 ± 0.56

10

10

0.5

1

3.2

3.2

100

200

10

10

10

10

20

100

100

a Liquid sample results are reported in pCi/Liter, air filters( pCi/filter), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).

b 1-131 (G); iodine-131 as analyzed by gamma spectroscopy.

c Activity reported is a net activity result. For gamma spectroscopic analysis, activity detected below the LLD value is not reported

d Low levels of Sr-90 are still detected in the environment. A concentration of (1-5 pCi/L) in milk is not unusual.

A4-2
TABLE A-5. In-House "Duplicate" Samples

Concentration (pCi/L)a

Averaged

Lab Code Date Analysis First Result Second Result Result Acceptance

AP-7466, 7467

AP-7513, 7514

AP-7555, 7556

MI-154, 155

MI-217, 218

MI-217, 218

MI-287, 288

MI-287, 288

WW-314, 315

WW-314, 315

SWT-577, 578

SWU-598, 599

SWU-598, 599

F-3311, 3312 b

F-3311, 3312

SW-780, 781

SW-780, 781

DW-934, 935

DW-1024, 1025

MI-1078, 1079

F-1357, 1358

F-1357, 1358

MI-1469, 1470

CF-1538, 1539

WW-1583, 1584

DW-1955, 1956

MI-1760, 1761

AP-2603, 2604

E-1997, 1998

E-1997, 1998

AP-2818, 2819

SWU-2863, 2864

SS-2389, 2390

SS-2389, 2390

DW-2773, 2774

SL-2932, 2933

SL-2932, 2933

SL-2932, 2933

BS-3103, 3104

BS-3103, 3104

MI-3037, 3038

MI-3037, 3038

1/3/2006

1/3/2006

1/3/2006

1/10/2006

1/11/2006

1/11/2006

1/17/2006

1/17/2006

1/19/2006

1/19/2006

1/31/2006

1/31/2006

1/31/2006

2/9/2006

2/9/2006

2/14/2006

2/14/2006

2/17/2006

2/24/2006

3/1/2006

3/10/2006

3/10/2006

3/14/2006

3/21/2006

3/22/2006

3/27/2006

3/29/2006

3/29/2006

4/3/2006

4/3/2006

4/3/2006

4/3/2006

4/11/2006

4/11/2006

4/21/2006

5/1/2006

5/1/2006

5/1/2006

5/1/2006

5/1/2006

5/2/2006

5/2/2006

Be-7

Be-7

Be-7

K-40

K-40

Sr-90

K-40

Sr-90

Gr. Beta

H-3

Gr. Beta

Gr. Beta

H-3

Gr. Beta

K-40

Gr. Alpha

Gr. Beta

1-131

1-131

Sr-90

Gr. Beta

K-40

K-40

K-40

Gr. Beta

Gr. Beta

K-40

Be-7

Gr. Beta

K-40

Be-7

Gr. Beta

Gr. Beta

K-40

1-131

Be-7

Gr. Beta

K-40

Gr. Beta

K-40

K-40

Sr-90

0.053 ± 0.015

0.033 ± 0.008

0.053 ± 0.007

1254.20 ± 87.75

1258.00 ± 118.00

1.27 ± 0.37

1383.10 ± 110.90

0.74 ± 0.38

9.21 ± 1.72

168.64 ± 94.94

3.06 ± 0.66

2.03 ± 0.39

260.10 ± 98.20

4.12 ± 0.14

2.68 ± 0.37

4.09 ± 1.52

5.91 ± 0.90

0.35 ± 0.22

0.24 ± 0.26

1.42 ± 0.39

3.77 ± 0.07

2.46 ± 0.32

1396.30 ± 120.80

13.66 ± 0.81

7.66 ± 0.73

2.25 ± 0.60

1271.00 ± 89.00

0.067 ± 0.015

1.82 ± 0.07

1.28 ± 0.15

0.06 ± 0.01

3.20 ± 1.26

10.53 ± 0.96

5.51 ± 0.42

0.74 ± 0.23

1.28 ± 0.19

6.09 ± 0.33

3.13 ± 0.41

8.27 ± 1.46

6288.20 ± 585.20

1238.90 ± 98.59

1.76 ± 0.42

0.057

0.036

0.054

1369.60

1313.00

0.92

1457.80

0.94

11.52

_ 0.011

* 0.008

± 0.008

± 102.80

* 98.00

* 0.33

± 119.10

± 0.37

* 1.93

210.12 ± 96.51

3.68 ± 0.64

1.97 ± 0.40

134.10 ± 93.50

3.82 ± 0.13

2.76 ± 0.39

3.22 ± 1.37

5.89 ± 0.92

0.31 ± 0.25

0.53 ± 0.24

1.30 ± 0.62

3.71 ± 0.07

2.32 ± 0.44

1335.60 ± 113.80

13.97 ± 0.68

8.87 ± 0.75

3.15 ± 0.59

1378.00 ± 113.00

0.056 ± 0.010

1.87 ± 0.07

1.24 ± 0.21

0.06 ± 0.01

4.77 ± 1.30

9.38 ± 0.84

5.79 ± 0.40

0.53 ± 0.40

1.27 ± 0.17

5.65 ± 0.31

3.09 ± 0.36

9.03 ± 1.59

5643.70 ± 599.80

1301.00 ± 103.90

1.48 ± 0.42

0.055 ± 0.009

0.035 ± 0.006

0.053 ± 0.005

1311.90 ± 67.58

1285.50 ± 76.69

1.10 ±0.25

1420.45 ± 81.37

0.84 ± 0.27

10.37 ± 1.29

189.38 ± 67.69

3.37 ± 0.46

2.00 ± 0.28

197.10 ± 67.80

3.97 ± 0.10

2.72 ± 0.27

3.66 ± 1.03

5.90 ± 0.64

0.33 ± 0.16

0.39 ± 0.18

1.36 ± 0.37

3.74 ± 0.05

2.39 ± 0.27

1365.95 ± 82.98

13.81 ± 0.53

8.26 ± 0.52

2.70 ± 0.42

1324.50 ± 71.92

0.062 ± 0.009

1.85 ± 0.05

1.26 ± 0.13

0.06 ± 0.01

3.99 ± 0.91

9.96 ± 0.64

5.65 ± 0.29

0.63 ± 0.23

1.28 ± 0.13

5.87 ± 0.23

3.11 ± 0.27

8.65 ± 1.08

5965.95 ± 418.99

1269.95 ± 71.62

1.62 ± 0.29

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Fail

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

A5-1
TABLE A-5. In-House "Duplicate" Samples

Concentration (pCi/L)a

Averaged

Lab Code Date Analysis First Result Second Result Result Acceptance

MI-3124, 3125

SW-3145, 3146

SW-3145, 3146

MI-3236, 3237

F-3422, 3423

G-3491,3492

G-3491, 3492

SO-3539, 3540

SO-3539, 3540

WW-3751, 3752

F-3617, 3618

SL-3641, 3642

SL-3641, 3642

SL-3641, 3642

MI-3886, 3887

VE-3949, 3950

VE-3949, 3950

VE-3949, 3950

BS-4016, 4017

BS-4016, 4017

BS-4016, 4017

MI-3992, 3993

LW-4175, 4176

W-4130, 4131

AV-4330, 4331

SWU-4489, 4490

AP-4909, 4910

AP-4952, 4953

AP-4930, 4931

E-4399, 4400

E-4399, 4400

G-4420, 4421

G-4420, 4421

G-4420, 4421

5/9/2006

5/9/2006

5/9/2006

5/10/2006

5/19/2006

5/24/2006

5/24/2006

5/24/2006

5/24/2006

5/25/2006

5/30/2006

6/1/2006

6/1/2006

6/1/2006

6/12/2006

6/13/2006

6/13/2006

6/13/2006

6/13/2006

6/13/2006

6/13/2006

6/14/2006

6/16/2006

6/21/2006

6/26/2006

6/27/2006

6/29/2006

6/29/2006

7/3/2006

7/5/2006

7/5/2006

7/5/2006

7/5/2006

7/5/2006

K-40

Gr. Alpha

Gr. Beta

K-40

H-3

Gr. Beta

K-40

Gr. Beta

K-40

Gr. Beta

K-40

Be-7

Gr. Beta

K-40

K-40

Gr. Alpha

Gr. Beta

K-40

Co-60

Cs-137

K-40

K-40

H-3

H-3

K-40

Gr. Beta

Be-7

Be-7

Be-7

Gr. Beta

K-40

Be-7

Gr. Beta

K-40

Gr. Alpha

Gr. Alpha

Gr. Alpha

K-40

Sr-90

K-40

Gr. Beta

1032.30 ± 91.12

4.85 ± 1.68

8.94 ± 1.46

1412.40 ± 119.10

8175.00 ± 252.00

8.89 ± 0.18

5.60 ± 0.71

19.57 ± 1.99

12.55 ± 0.89

9.85 ± 0.79

2.42 ± 0.38

1.41 ± 0.19

5.03 ± 0.18

2.21 ± 0.26

1424.20 ± 118.20

0.13 ± 0.06

4.53 ± 0.19

6.02 ± 0.66

0.18 ± 0.03

1.97 ± 0.09

11.03 ± 0.76

1358.50 ± 166.40

482.11 ± 90.25

401.50 ± 87.85

1717.10 ± 244.30

1.70 ± 0.38

0.11 ± 0.01

0.08 ± 0.02

0.08 ± 0.02

1.85 ± 0.05

1.25 ± 0.19

0.82 ± 0.20

13.20 ± 0.40

9.96 ± 0.44

3.24 ± 1.35

3.70 ± 1.12

6.87 ± 1.26

1403.50 ± 118.80

0.59 ± 0.34

1286.60 ± 92.62

1.75 ± 0.60

1103.60 ± 120.50

4.12 ± 1.62

9.14 ± 1.36

1427.90 ± 127.70

8268.00 ± 253.00

9.03 ± 0.19

6.30 ± 0.78

18.98 ± 1.91

11.49 ± 0.59

8.96 ± 0.74

2.53 ± 0.37

1.31 ± 0.27

5.30 ± 0.19

2.14 ± 0.37

1318.80 ± 110.50

0.16 ± 0.07

4.47 ± 0.18

5.33 ± 0.66

0.15 ± 0.03

2.01 ± 0.09

10.45 ± 0.78

1395.80 ± 122.70

397.50 ± 86.88

236.28 ± 80.89

1893.10 ± 223.30

1.93 ± 0.38

0.11 ±_0.02

0.10 ± 0.02

0.07 ± 0.01

1.85 ± 0.05

1.24 ± 0.18

0.61 ±-0.14

14.00 ± 0.40

10.06 ± 0.82

2.49 ± 1.33

3.09 ± 1.16

4.77 ± 1.09

1330.40 ± 116.50

0.70 ± 0.35

1358.60 ± 158.40

2.51 ± 0.59

1067.95 ± 75.54

4.48 ± 1.17

9.04 ± 1.00

1420.15 ± 87.31

8221.50 ± 178.54

8.96 ± 0.13

5.95 ± 0.53

19.27 ± 1.38

12.02 ± 0.53

9.41 ± 0.54

2.47 ± 0.27

1.36 ± 0.17

5.17 ± 0.13

2.18 ± 0.23

1371.50 ± 80.90

0.15 ± 0.05

4.50 ± 0.13

5.67 ± 0.47

0.16 ± 0.02

1.99 ± 0.06

10.74 ± 0.54

1377.15 ± 103.37

439.81 ± 62.63

318.89 ± 59.71

1805.10 ± 165.49

1.82 ± 0.27

0.11 ± 0.01

0.09 ± 0.01

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

0.08 ± 0.01

DW-60432, 60433 7/6/2006

DW-60514, 60515 7/10/2006

DW-60449, 60450 7/11/2006

MI-4599, 4600 7/12/2006

MI-4599, 4600 7/12/2006

MI-4667, 4668 7/12/2006

LW-4823, 4824 7/14/2006

1.85

1.25

0.72

13.60

10.01

2.87

3.40

5.82

1366.95

0.65

1322.60

2.13

± 0.04

* 0.13

* 0.12

± 0.28

± 0.47

± 0.95

± 0.81

* 0.83

± 83.20

± 0.24

± 91.75

* 0.42

A5-2
TABLE A-5. In-House "Duplicate" Samples

Concentration (pCi/L)a

Averaged

Lab Code Date Analysis First Result Second Result Result Acceptance

DW-60502, 60503 7/19/2006

DW-60526, 60527 7/21/2006

DW-60539, 60540 7/21/2006

MI-5125, 5126 7/25/2006

DW-60609, 60610 7/26/2006

DW-60621, 60622 7/31/2006

SL-5265, 5266

SL-5265, 5266

SL-5265, 5266

SL-5265, 5266

VE-5286, 5287

VE-5286, 5287

VE-5286, 5287

SW-5383, 5384

SW-5383,5384

SW-5971, 5972

VE-5404, 5405

VE-5404, 5405

DW-5480,5481

8/1/2006

8/1/2006

8/1/2006

8/1/2006

8/1/2006

8/1/2006

8/1/2006

8/8/2006

8/8/2006

8/8/2006

8/10/2006

8/10/2006

8/11/2006

DW-60645, 60646 8/15/2006

W-5602,5603 8/16/2006

DW-60634, 60635 8/18/2006

DW-60634, 60635 8/18/2006

MI-5793, 5794 8/22/2006

SWU-6150, 6151 8/29/2006

DW-60657, 60658 8/29/2006

CF-7450, 7451 9/5/2006

SL-6085, 6086 9/5/2006

SL-6085, 6086 9/5/2006

SL-6085, 6086 9/5/2006

DW-60695, 60696 9/11/2006

LW-6266, 6267 9/13/2006

MI-6424, 6425 9/19/2006

DW-60715, 60716 9/19/2006

SO-6597, 6598 9/22/2006

SO-6597, 6598 9/22/2006

SWU-6718,6719 9/26/2006

SO-6668, 6669 9/27/2006

SO-6668,6669 9/27/2006

Gr. Alpha

Gr. Alpha

Gr. Alpha

K-40

Gr. Alpha

Gr. Alpha

Be-7

Sr-90

Gr. Beta

K-40

Be-7

Gr. Beta

K-40

Gr. Alpha

Gr. Beta

H-3

Be-7

K-40

H-3

Gr. Alpha

H-3

Gr. Alpha

Gr. Beta

K-40

Gr. Beta

Gr. Alpha

Be-7

Co-60

Gr. Beta

K-40

Gr. Alpha

Gr. Beta

Sr-90

Gr. Alpha

Cs-137

K-40

Gr. Beta

Cs-1 37

K-40

16.27 ± 2.49

14.06 ± 1.82

5.09 ± 0.95

1480.60 ± 118.30

1.00 ± 1.10

3.70 ± 1.00

1.10 ± 0.46

0.10 ± 0.03

4.41 ± 0.41

1.19 ± 0.52

1.21 ± 0.30

9.67 ± 0.35

6.25 ± 0.81

3.24 ± 1.35

4.86 ± 0.86

119.90 ±_78.14

0.77 ± 0.24

4.71 ± 0.63

169.08 ± 85.52

10.41 ± 1.78

2118.79 ± 151.55

12.99 ± 1.84

10.51 ± 1.33

1264.00 ± 115.00

1.84 ± 0.28

2.33 ± 0.80

0.78 ± 0.45

0.22 ± 0.03

5.47 ± 0.69

1.91 ± 0.28

3.93 ± 1.17

3.09 ± 0.48

0.78 ± 0.38

1.30 ± 1.00

0.18 ± 0.04

10.25 ± 0.66

3.45 ± 1.21

0.13 ± 0.04

13.04 ± 0.90

21.41 ± 3.21

15.57 ± 1.77

6.23 ± 1.05

1402.60 ± 120.80

2.70 ± 1.30

1.90 ± 0.80

1.38 ± 0.52

0.16 ± 0.03

3.46 ± 0.57

0.87 ± 0.52

1.32 ± 0.20

9.37 ± 0.35

6.50 ± 0.48

2.94 ± 1.35

5.46 ± 0.87

144.41 ± 79.23

1.01 ± 0.26

4.01 ± 0.58

133.65 ± 83.96

10.97 ± 1.85

2181.82 ± 153.09

9.67 ± 1.61

8.61 ± 1.18

1377.00 ± 121.00

1.81 ± 0.28

2.90 ± 0.78

0.78 ± 0.27

0.21 ± 0.02

4.63 ± 0.58

2.06 ± 0.41

4.62 ± 1.12

2.98 ± 0.48

1.11 ±_0.37

2.23 ± 1.01

0.18 ± 0.04

10.11 ±0.64

2.78 ± 1.19

0.13 ± 0.02

12.41 ± 0.54

18.84 ± 2.03

14.82 ± 1.27

5.66 ± 0.71

1441.60 ± 84.54

1.85 ± 0.85

2.80 ± 0.64

1.24 ± 0.35

0.13 ± 0.02

3.94 ± 0.35

1.03 ± 0.37

1.27 ± 0.18

9.52 ± 0.25

6.38 ± 0.47

3.09 ± 0.96

5.16 ± 0.61

132.15 ± 55.64

0.89 ± 0.18

4.36 ± 0.43

151.36 ± 59.92

10.69 ± 1.28

2150.30 ± 107.71

11.33 ± 1.22

9.56 ± 0.89

1320.50 ± 83.47

1.82 ± 0.20

2.62 ± 0.56

0.78 ± 0.26

0.22 ± 0.02

5.05 ± 0.45

1.99 ± 0.25

4.28 ± 0.81

3.03 ± 0.34

0.95 ± 0.27

1.77 ± 0.71

0.18 ± 0.03

10.18 ± 0.46

3.12 ± 0.85

0.13 ± 0.02

12.72 ± 0.53

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

A5-3
TABLE A-5. In-House "Duplicate" Samples

Concentration (pCi/L)a

Averaged

Lab Code Date Analysis First Result Second Result Result Acceptance

MI-6760, 6761

G-6797, 6798

G-6797, 6798

G-6797, 6798 b

AP-7531, 7532

AP-7552, 7553

AP-7573, 7574

SO-7103, 7104

SO-7103, 7104

10/2/2006

10/2/2006

10/2/2006

10/2/2006

10/3/2006

10/3/2006

10/3/2006

10/4/2006

10/4/2006

DW-60759, 60760 10/5/2006

MI-7037, 7038

VE-7058, 7059

VE-7058, 7059

VE-7058, 7059

SS-7079, 7080

SS-7079, 7080

SS-7079, 7080

MI-7208, 7209

CF-7450, 7451

LW-7945, 7946

F-7971, 7972

SWU-8194, 8195

BS-8017, 8018

BS-8017, 8018

LW-8215, 8216

F-8345, 8346

BS-8366, 8367

MI-8083, 8084

WW-8259,8260

M1-8484, 8485

SO-8619, 8620

SO-8619, 8620

SO-8619, 8620

SO-8619, 8620

SWT-8641, 8642

SWT-9436, 9437

10/10/2006

10/10/2006

10/10/2006

10/10/2006

10/10/2006

10/10/2006

10/10/2006

10/11/2006

10/18/2006

10/26/2006

10/29/2006

10/31/2006

11/1/2006

11/1/2006

11/1/2006

11/2/2006

11/2/2006

11/6/2006

11/7/2006

11/22/2006

11/27/2006

11/27/2006

11/27/2006

11/27/2006

11/29/2006

12/26/2006

K-40

Be-7

Gr. Beta

K-40

Be-7

Be-7

Be-7

Cs-1 37

K-40

Gr. Alpha

K-40

Gr. Alpha

Gr. Beta

K-40

Cs-1 37

Gr. Beta

K-40

K-40

K-40

Gr. Beta

K-40

Gr. Beta

Gr. Beta

K-40

Gr. Beta

K-40

K-40

K-40

H-3

K-40

Cs-137

Gr. Alpha

Gr. Beta

K-40

Gr. Beta

Gr. Beta

1413.10 ± 113.20

4.70 ± 0.31

6.89 ± 0.26

5.39 ± 0.35

0.07 ± 0.01

0.08 ± 0.02

0.08 ± 0.02

0.25 ± 0.05

12.95 ± 1.12

4.93 ± 0.97

1326.10 ± 115.20

0.18 ± 0.11

9.21 ± 0.34

10.90 ± 0.65

0.04 ± 0.01

12.23 ± 2.46

7.23

1295.20

20.40

1.30

3.63

1.84

10.54

10.00

2.23

2.84

13.69

1295.00

± 0.36

* 116.90

* 0.84

* 0.37

* 0.54

* 0.28

* 1.72

* 0.53

* 0.61

* 0.42

* 0.66

* 121.20

1187.30 ± 155.20

4.56 ± 0.41

7.04 ± 0.24

4.36 ± 0.47

0.08 ± 0.01

0.08 ± 0.01

0.08 ± 0.01

0.27 ± 0.06

12.22 ± 1.07

5.04 ± 1.03

1251.40 ± 115.70

0.32 ± 0.14

8.83 ± 0.36

10.42 ± 0.80

0.04 ± 0.02

11.76 ± 2.23

7.37 ± 0.40

1386.90 ± 119.10

19.54 ± 0.99

1.44 ± 0.36

3.33 ± 0.43

1.43 ± 0.28

10.17 ± 1.73

9.60 ± 0.69

1.64 ± 0.37

2.89 ± 0.40

13.61 ± 0.78

1374.80 ± 162.80

295.00 ± 93.00

1390.70 ± 103.60

0.69 ± 0.06

12.24 ± 4.90

28.66 ± 3.95

12.92 ± 0.83

2.89 ± 0.45

2.25 ± 0.60

1300.20 ± 96.05

4.63 ± 0.26

6.97 ± 0.18

4.88 ± 0.29

0.08 ± 0.01

0.08 ± 0.01

0.08 ± 0.01

0.26 ± 0.04

12.58 ± 0.77

4.99 ± 0.71

1288.75 ± 81.64

0.25 ± 0.09

9.02 ± 0.25

10.66 ± 0.52

0.04 ± 0.01

11.99 ± 1.66

7.30 ± 0.27

1341.05 ± 83.44

19.97 ± 0.65

1.37 ± 0.26

3.48 ± 0.34

1.64 ± 0.20

10.36 ± 1.22

9.80 ± 0.44

1.93 ± 0.35

2.86 ± 0.29

13.65 ± 0.51

1334.90 ± 101.48

316.00 ± 66.47

1398.25 ± 67.66

0.71 ± 0.05

14.39 ± 3.74

26.82 ± 2.77

12.57 ± 0.69

2.86 ± 0.33

2.32 ± 0.44

Pass

Pass

Pass

Fail

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

337.00 ± 95.00

1405.80 ± 87.06

0.74 ± 0.08

16.54 ± 5.65

24.99 ± 3.88

12.21 ± 1.11

2.83 ± 0.47

2.39 ± 0.64

Note: Duplicate analyses are performed on every twentieth sample received in-house. Results are not listed for those

analyses with activities that measure below the LLD. a Results are reported in units of pCi/L, except for air filters (pCi/Filter), food products, vegetation, soil, sediment (pCi/g).

b 200 minute count time or longer, resulting in lower error.

A5-4
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.

Concentration b

Known Control

Lab CodeC Date Analysis Laboratory result Activity Limits d Acceptance

STVE-1082

STVE-1082

STVE-1082

STVE-1082 e

STVE-1082

STVE-1082

STVE-1082

STVE-1082

STVE-1082

STVE-1082

STVE-1082

STVE-1082

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083 e

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083

STSO-1 083

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

Am-241

Co-57

Co-60

Cs-1 34

Cs-1 37

Mn-54

Pu-238

Pu-239/40

Sr-90

U-233/4

U-238

Zn-65

Am-241

Co-57

Co-60

Cs-1 34

Cs-1 37

K-40

Mn-54

Ni-63

Pu-238

Pu-239/40

U-233/4

U-238

Zn-65

0.16 ± 0.06

10.40 ± 0.20

5.00 ± 0.20

< 0.20

3.40 ± 0.20

6.90 ± 0.20

0.08 ± 0.03

0.17 ± 0.03

1.40 ± 0.20

0.24 ± 0.05

0.19 ± 0.04

11.10 ±_0.50

54.60 ± 5.50

762.90 ± 12.70

504.90 ± 3.10

< 1.70

406.50 ± 3.70

719.20 ± 18.40

415.60 ± 4.80

261.40 ± 14.70

14.60 ± 2.90

14.60 ± 2.40

13.50 ± 1.70

15.40 ± 1.80

783.40 ± 7.00

0.16

8.58

4.52

0.00

3.07

6.25

0.14

0.16

1.56

0.21

0.22

9.80

0.11 -0.20

6.00 -11.15

3.16 -5.88

2.15 -4.00

4.37 -8.12

0.10 -0.18

0.11 - 0.21

1.09 -2.03

0.15 -0.27

0.15 -0.28

6.86 - 12.74

57.08

656.29

447.10

0.00

339.69

604.00

346.77

323.51

61.15

45.85

37.00

38.85

657.36

39.96 - 74.20

459.40 -853.18

312.97 -581.23

237.78 - 441.60

422.80 - 785.20

242.74 - 450.80

226.46 - 420.56

42.81 - 79.50

32.09 - 59.61

25.90 -48.10

27.20 - 50.50

460.15 -854.57

Pass

Pass

Pass

Pass

Pass

Pass

Fail

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Fail

Fail

Fail

Fail

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Fail

Pass

Pass

Pass

Pass

Pass

STAP-1 084 01/01/06 Gr. Alpha

STAP-1084 01/01/06 Gr. Beta

STAP-1085

STAP-1 085

STAP-1 085

STAP-1 085

STAP-1085

STAP-1085

STAP-1085 e

STAP-1085

STAP-1085

STAP-1 085

STAP-1 085

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

Am-241

Co-57

Co-60

Cs-1 34

Cs-1 37

Pu-238

Pu-239/40

Sr-90

U-233/4

U-238

Zn-65

0.26 ± 0.02

0.51 ± 0.03

0.12 ± 0.02

4.32 ± 0.10

2.24 ± 0.16

2.96 ± 0.19

2.64 ± 0.20

0.03 ± 0.01

< 0.01

0.77 ± 0.21

0.03 ± 0.01

0.02 ± 0.01

3.94 ± 0.44

0.36

0.48

0.09

4.10

2.19

2.93

2.53

0.07

0.00

0.79

0.02

0.02

3.42

0.00 - 0.72

0.24 - 0.72

0.07 -0.12

2.87 - 5.32

1.53 -2.84

2.05 - 3.81

1.77 - 3.29

0.05 - 0.09

0.55 - 1.03

0.01 - 0.03

0.01 - 0.03

2.40 - 4.45

A6-1
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.

Concentration b

Known Control

Lab Codec Date Analysis Laboratory result Activity Limits d Acceptance

STW-1086

STW-1086

STW-1 086

STW-1086

STW-1 086 e

STW-1 086

STW-1086

STW-1 086

STW-1 086

STW-1086

STW-1086 e

STW-1086

STW- 1086

STW-1086

STW-1086

STW-1086

STW-1087

STW-1 087

STVE-1 098 e

STVE-1 098 g

STVE-1098

STVE-1098

STVE-1098

STVE-1098

STSO-1 099

STSO-1099

STSO-1099

STSO-1099

STSO-1099

STSO-1099

STSO-1099

STSO-1099

STSO-1099

STSO- 1099 e

STSO-1 099

STSO-1 099

STSO-1 099

STAP-1 100

STAP- 1100

STAP- 1100

STAP- 1100

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

01/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

Am-241

Co-57

Co-60

Cs-134

Cs-1 37

Fe-55

H-3

Mn-54

Ni-63

Pu-238

Pu-239/40

Sr-90

Tc-99

U-233/4

U-238

Zn-65

Gr. Alpha

Gr. Beta

Co-57

Co-60

Cs-1 34

Cs-1 37

Mn-54

Zn-65

Am-241

Co-57

Co-60

Cs-1 34

Cs-137

K-40

Mn-54

Ni-63

Pu-238

Pu-239/40

U-233/4

U-238

Zn-65

Am-241

Co-57

Co-60

Cs-1 34

1.29 ± 0.05

177.10 ± 1.00

158.30 ± 1.00

96.40 ± 1.50

< 0.80

102.50 ± 18.10

956.60 ± 16.50

335.30 ± 2.20

62.90 ± 3.60

0.96 ± 0.07

< 0.20

12.80 ± 1.60

22.30 ± 1.20

2'.02 ± 0.12

2.03 ± 0.12

249.50 ± 3.40

0.59 ± 0.10

1.69 ± 0.07

<0.14

6.89 ± 0.17

8.46 ± 0.16

6.87 ± 0.29

10.36 ± 0.29

7.46 ± 0.50

130.00 ± 11.60

784.90 ± 3.80

2.10 ± 0.90

500.70 ± 7.40

624.20 ± 4.90

701.30 ± 3.40

699.20 ± 5.20

614.40 ± 17.10

79.90 ± 5.80

< 0.70

150.50 ± 5.90

151.60 ± 6.00

1021.90 ± 9.20

0.16 ± 0.03

2.17 ± 0.06

1.38 ± 0.07

2.52 ± 0.13

1.30

166.12

153.50

95.10

0.00

129.60

952.01

315.00

60.34

0.91

0.00

13.16

23.38

2.09

2.17

228.16

0.58

1.13

0.00

5.81

7.49

5.50

8.35

5.98

105.47

676.33

1.98

452.13

525.73

604.00

594.25

672.30

82.00

0.00

152.44

158.73

903.61

0.14

2.58

1.58

3.15

0.91 -1.69

116.28 -215.96

107.45 - 199.55

66.57 - 123.63

90.72 -168.48

666.41 - 1238.00

220.50 - 409.50

42.24 - 78.44

0.70 - 1.30

9.21 -17.11

16.37 -30.39

1.46 -2.72

1.52 -2.82

159.71 -296.61

0.00 -1.16

0.56 -1.70

4.06 - 7.55

5.24 - 9.73

3.85 -7.14

5.85 - 10.86

4.19 -7.78

73.83 - 137.11

473.43 - 879.23

0.00 - 5.00

316.49 -587.77

368.01 -683.45

423.00 - 785.00

415.98 -772.52

470.60 - 874.00

57.00 - 107.00

106.71 -198.17

111.11 -206.35

632.53 -1175.00

0.10 -0.19

1.81 -3.36

1.10 -2.05

2.20 - 4.09

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

A6-2
TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.

Concentration b

Known Control

Lab Codec Date Analysis Laboratory result Activity Limits d Acceptance

STAP-i 100

STAP-1 100

STAP-1100

STAP-1 100

STAP-1 100

STAP-i 100

STAP- 1100 e

STAP-i 101

STAP-1101

STW-1102

STW-1102

STW-1103

STW-1103

STW-1103

STW-1103

STW- 1103

STW-i 103

STW-1103

STW-1103 e

STW-1103

STW-1103

STW-1103

STW-1 103

STW-1103

STW-i 103

STW-1103

STW-1 103

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

07/01/06

Cs-1 37

Mn-54

Pu-238

Sr-90

U-233/4

U-238

Zn-65

Gr. Alpha

Gr. Beta

Gr. Alpha

Gr. Beta

Am-241

Co-57

Co-60

Cs-1 34

Cs-137

Fe-55

H-3

Mn-54

Ni-63

Pu-238

Pu-239/40

Sr-90

Tc-99

U-233/4

U-238

Zn-65

1.64 ± 0.08

1.76 ± 0.18

0.09 ± 0.02

0.66 ± 0.21

0.15 ± 0.02

0.13 ± 0.02

< 0.07

0.08 ± 0.03

0.41 ± 0.05

1.81

1.92

0.12

0.62

0.13

0.14

0.00

0.29

0.36

1.26 -2.35

1.34 -2.50

0.08 -0.15

0.43 - 0.81

0.09 -0.17

0.10 -0.18

0.00 - 0.58

0.18 -0.54

0.76 ± 0.07

1.23 ± 0.06

1.86 ± 0.09

224.10 ± 1.20

49.40 ± 0.50

112.70 ± 0.90

206.60 ± 1.40

138.40 ± 5.40

446.50 ± 11.80

< 0.30

116.70 ± 3.60

1.27 ± 0.07

1.67 ± 0.08

16.40 ± 1.90

29.40 ± 1.10

1.97 ± 0.08

1.97 ± 0.08

192.50 ± 2.40

1.03

1.03

2.31

213.08

47.50

112.82

196.14

165.40

428.85

0.00

118.62

1.39

1.94

15.69

27.15

2.15

2.22

176.37

0.00 - 2.07

0.52 - 1.54

1.62 - 3.00

149.16 -277.00

33.20 - 61.80

78.97 - 146.66

137.30 -254.98

115.80 -215.00

300.20 - 557.50

83.03 - 154.21

0.97 - 1.81

1.36 -2.52

10.98 -20.40

19.00 - 35.29

1.50 - 2.80

1.55 - 2.89

123.46 -229.28

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

i

a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the Department of Energy's

Mixed Analyte Performance Evaluation Program, Idaho Operations office, Idaho Falls, Idaho

b Results are reported in units of Bq/kg (soil), Bq/L (water) or Bq/total sample (filters, vegetation).

c Laboratory codes as follows: STW (water), STAP (air filter), STSO (soil), STVE (vegetation).

d MAPEP results are presented as the known values and expected laboratory precision (1 sigma, 1 determination)

and control limits as defined by the MAPEP.

e Included in the MAPEP as a false positive.

Difficulties with the analyses for transuranics isotopes in solid samples (Filters, Soil and vegetation),

were attributed to incomplete dissolution of the samples. Soil samples were repeated, results of reanalyses:

Pu-238, 53.1 ± 5.3 bq/kg. Pu-239/240, 42.4 ± 4.7 bq/kg. U-233/4, 33.3 ± 3.5 bq/kg. U-238, 35.5 ± 3.6 bq/kg.

g The July vegetation sample was provided in two separate geometries, (100 ml. and 500 ml.). Results reported here

used the 500 ml. standard size geometry. Results for the 100 ml. geometry showed approximately a 15% higher bias.

A6-3
ATTACHMENT F

DATA GRAPHS

3 Pages Follow
Palisades Air Particulate

Gross Beta

Pre-Operational vs. Operational

0

Co

CE

C.)

0.08

0.07

0.06

0.05

0.04

0.03

0.02

0.01

0

1968-1969 2000 2001 2002 2003 2004 2005 2006

I Indicator U Control
Lake Water Gross Beta

2001 to 2006

2.5

2.0 -

1.5

1.0

0.5

0.0

2000 2001 2002 2003 2004 2005 2006

Year

E PAL Lake In E SH Raw O SH Treated 0 Ludington I
Palisades Quarterly Thermoluminescent Dosimeters

2000-2006

30.0

25.0--

E

E

10.01024

5.0--

1968-69 2000 2001 2002 2003 2004 2005 2006

N Inner Ring U Outer Ring 0 Control