I ' 

## UNITE D STATE S DEPARTMEN T OFTRANSPORTAflONTh^cj T O r OFFIC EOFHEARING S • i *ANSPOFi!AT!Oi \ WASHINGTON , D.C . ''^L-UKL ! 

## 0!-!:nAllUN b ?0! i OC T 1 2 P \'-^ 0 F NTH EMATTERO F 

# npnFi\/P n TG I FREIGH T pi.u—'*^^3— J V B^L J FA A DOCKE T NO . CPI0NM001 2 SE P3 0 201 1 (Civi l Penalt

y Action ) HEARIN G DOCKE T DMSNO . FAA-2010-107 9

DECLARATIO NO FJEFFRE Y L . DEIT Z I , Jeffrey L . Deitz . declar e under penalty o f

perjur y tha t th e followin g i s true : 1 . I a maHazardou s Material s Specialis t employe db

y th e Federal Aviatio n Administration , AlaskanRegion . I hav e serve di nthi s positio nsinc e January 1997 . 2 . Part s o f

m y dutie s whil e employe da s aHazardou s Material s Specialis t consis t o f conductin g investigation s base dupo nincident respons e andincident

reports . 3 . Onor abou t Friday , February 19 , 2010 , ou r offic e receive da

nemai l fromAlask a Airline s concernin g undeclare dhazma t foun di nashipmen t

onai r waybil l number 027-337 1 9873 , whic hcontaine d4 boxe s o f UNITEX Pro-Pox y 400 . Th e shipper wa s Parsons . 4 . I nadditio nto th e email . I receive dacop y o f th e Hazardou s Material s Inciden t Report , For mDO T F5800. 1 (01-2004) . FA A Propose dExhibit s A- 1 and8 . Thi s repor t indicate s tha

t undeclare dhazma

t wa s foun dwhil e screening . Th e report goe s o nto indicate tha

t th e rope r shippin g nam e o f

th e hazardou s material i s "Adhesives ,

## containin g aflammabl e liquid . Th e prope r Hazar dClas s i s 3 an dth e U Nnumbe r i s 1133 . 5 . I wa s assigne dt o investigat e th e matter . A s part o f my investigation , I pulle dth e MSD S for

th e Pro-Pox y 40 0 fro mth e internet . Se e FA A Propose dExhibi t A-19 . Th e MSD S wa s prepare db y UNITEX , th e manufacture r o f th e product . A s th e manufacturer , UNITE X prepare s aMateria l Safet y Dat aShee t ("MSDS'' ) for

Pro Pox y 40 0 a s require db y Federa l OSH A Communicatio nStandar d2 9 CF R1910.1200 . 6 . Fro mth e MSDS . I wa s abl e t o verif y tha t Pro-Pox y 40 0 consist s o f tw o components. . Componen t

A i s a nAcrylat e Blen dan dSiJica . crystalline , an dha s aflashpoin t o f 65°F . Componen t

B i s Benzoy l Peroxide , Calciu mcarbonate , an dEpox y Resi nan d ha s aflashpoin t

o f 315°F . Th e MSD S indicate s tha t bot ho f thes e flashpoint s wer e determine db y usin g th e Pensk y Marten s Close dCu p metho da s require dunde r 4 9 CF R173.120(a ) an d(c) . 7 . Fro mth e MSD S fo r th e Pro-Pox y 400 . I note dtha t UNITE X provide s it s customer s an dth e publi c ingenera l wit hinformatio nsuc ha s th e fac t tha t Pro-Pox y 40 0 i s a "Flammabl e Liquid " an dtha t a nexplosio nhazar dexist s whe nth e produc t i s expose d to heat o r flame . Se e Sectio n5 , Fir e Fightin g Measures . I naddition , th e MSD S als o provide s transpor t

informatio nunde r

Sectio n14 . Specifically , customer s an dth e genera l publi c ca neasil y locat e th e prope r shippin g nam e (Adhesive) , th e hazar dclas s (3) , th e identificatio nnumbe r (UN I 133) , an dth e packin g grou p (PGIII) . for Pro-Pox y 400 . Finally , I note dtha t th e MSD S als o specifie dtha t th e Pro-Pox y 40 0 mus t b e labele d"Flammabl e Liqui d3 " whe nbein g shippe db y ai r o r water . Declaratio no f Jeffre y L . Deiiz I nth e Matte r o f TG I Freitzh t Docke t No . CPI0NM00I 2 Paae2of 31 ' \ 

## 8 . A s part o f hi s investigation . 1 sen t aLette r ofhivestigatio n("LOI" ) t o th e shipper . Parson s Corporatio no nFebruar y 19 . 2010 . Se e attache dFA A Propose dExhibi t A-8 . 9 . I nrespons e t o thi s LO LI receive dalette r fro mTG I Freigh t

date dMarc h18 , 2010 . explainin g tha t

TG I Freigh t

ha s bee ninvolve da s adangerou s good s agen t for Parson s Corporatio ndatin g bac k t o Jun e o f

200 9 an dserve da s thei r shippin g agen t

o n Februar y 19 , 2010 . Se e attache dFA A Propose dExhibi t A-23 . 10 . I nit s Marc h18,2010 , letter , TG I Freigh t admitte dtha t

i t prepare dth e Pro-Pox y 40 0 o nai r waybil l 027-337 1 987 3 an dtha t i t looke dfor

consume r

warnings , bu t

tha t becaus e it

di dno t findany , tha t

th e compan y di dno t

follo w it s standar dprocedur e an d obtai namateria l safet y dat asheet . TG I Freigh t the nstate dtha t

ha dth e MSD S bee n pulled , th e compan y "woul dhav e declare dthi s produc t an dinclude dit

o nth e hazardou s materia l declaratio naccompanyin g ai r waybil l //027-3371-9740. " 11 . Unde r 4 9 CF R§173.120(a ) aflammable liqui di s aliqui dhavin g afiashpoin t o f no t mor e tha n140°F . Becaus e Pro-Pox y 40 0 i s aflammable liqui dan dtherefor e regulate d b y th e Departmen t

o f Transportatio nHazardou s Material s Regulation s ("HMR" ) [Titl e 4 9 Cod e o f

Federa l Regulation s (C.F.R. ) 171. 1 t?/.vtY/.] . prope r procedure s mus t

b e followe dwheneve r

it i s shipped .

Date: f/^^/^

^ Signature : Pri mNam e •M'it^e : ' T<itf, . . _( ) V^IT . 

## ^I^ ^ ZMA T 

## f/i^c/,fc/j>- 7 Declaration s hav e th e sam e lega l forc e a s affidavits . 28^U.S.C . § 1746 . Declaratio no f Jeffre y L . Deit z I nth e Matte r o f TG I Fremh t Docke t No . CPI0NM00I 2 Pag e 3 of3"Kerr t Kelz " T o Gar yMeaders/AALVFAAiSFA A <Kerr i Ket2@ataskaair.cam >

^ c cJef f Deitz/AAUFAA@FA A 02/19/201 0 10:3 9 A M bc c Subjec t Fwd : aw b 027-3371987 3 uncJeclare d hazma t



### O r LC I i p.a l Messaf'j e ' rL-cm : Ke-jc i Ket z Fri-dav , Februar y 19 , 201 0 10-.3?:2C i Subject : aw b 02'?-j37 1 98'' 3 undeclare dhazmat : T o : C ary . m e acIei--s0faa.yov,Jeff.deicz 0 I aa.go v C c : ANCFK MO D ANCF FCS A Lead.' J Mik e Tobi n Hell o rlveryone . . Undeclcirec i hazma t Loun dI n shipment . . AW E027-33 7 L':'37 3 S'r. Lpoe r

: Par:5on s 10 0 WW

aLnu t S t Fasadera , C

A 9112 4 907-440-200 0 4 boxe s o f

un i ce: < pro-pox y 4 0 0 ' I cardboar dbo:-'.e 3 Shipmen c i s stage di n outboun dhazma t area . F.ecj ard s Ke r r i

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iO P

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) A n iimlctlarci J ^hipuie m wit h n o riilciia e <_• ) A•ij)i.-i.-i(iiat[o n faig u ijii k l,l)iK. l L:.lll"ll ^

o r^rcati Tfi'iiiai n an yhj/ajilou' . inaiu'riiil s ilia i i l ) j(.fi:ivfi J itrucmra l darna^' cl o ihu " ladinj j rt-ifiuio n •.j^it' m o rJaiiLig t (ha i reiiuirc s rci'ji rl o a •.ysltr m [iiii'ndi'i J \ vproii-'i; ! \U cladin g iciijniio n svMei n an d i 2 ) di d nu l tiavi - a rL'liMse . Tlii- ; I' M ii ' iv:i)i> n

lndii.-3[ cv^liL'lhi'Uhi s is : ] X | A n Initia l Rcpo n A'.irppleitiL'nia l Qollon'-up ) rcpo n | ] Addiliona l Page s P A R I I I - f;KNi:KAl , INCIDK M rMOKMATIO N > . 5 . f i . 7 . H . V . HI . Dal e ollnuideiii : ;;l".';i)ll ) 4 . Tinii - u t Inciden i (us e 24-hou rlime cl>»3 y TiEiie rNaiiona l Re.-pmii e Cenit TRepor t Nunihe i lifappliCablel : Il'yo u iirbrniiie d a repor t l o anothe rteden l DO Tagency , enie riheajjene yan d rcpm t nutnher . TA A• V^^AI.T^X. W Ciiv . ANOIORAG H Loiaijo n o t Inciden t Stale : A KO'untiy . U S .Siiee i Address/Mil e Marker/V.iriliianie/Airpori/FJodvo l W;iiei/Rjve rMile : 4l()iU)l d Intemaiiiina l Couiiiy : ANCHORAG E ZipOvie' . '.i'J50 2 Mod e o l TriinsiJOiKiTion . Tran^poilaiio n Phase . 

### [ X ] A, r 1 I I n Transi t Highwa y 1 i Loadin g Rai l Unloadin g Canier/Reponc i Nam e Ala'ik a rViilute s Stieei : 4|()0Ol J Iniern.iliona l Ciiy . ANCHORAG E Stale : A K Federa l DO TID/Nunibcr : Shipper/Ollero rName : Parson s Sireei : MX

) W . Walnu t S i Ciiy : PA.SAOrN A Slate ; C A WayhillfShippin g Paper : 027;VNC3.'\71'J!i'7: * Country : U S [ '" ' [ Waic r I X I I n Transi t Storag e 7,ipCfxJe : 9^50 2 Hn/nu i RegiMratin n Number ;

Coiiniry : U S Zi p U"dc : fMI2 4

Haziiia i Regisiraiio n Nunibef : 12 .

14 . 15 . 16 . Ut . 21 . Origi n Slri-ei : (i t dilleten i Imii i City : Anchorag e Shippii raddress ) State : A KCountry . U S Prope r.Shippin g Nam e o f Hazardou s Material . .ADHESIVHS . containin g a llaminabl e li^iiii d Teehnica l I'rad e Name : H.i/ardou s Clas s 17 , IdeniitiLaiio n 18 . P.iekin g /Division : .' D Nuniher : UNM3 3 Group Zi p CINJC .

19 . Ou-i'"il y Released : Wa s th e materia l -.hippe d a s a hazardou s \saiie' ' | | Ve s ( S ] N o I I yes . provid e lit e CP. AManifes t Numlier : I s ihi s , 1 Tosr e b yInhal.iito n iTIH ) Mi:iieiiar. ' | [ Ve s | \ ' ) N o Ifye-. , piovid e th e Ha/ar d Zone : Wa s th e inaieiia l .shippe d unde ra n Lveitipiiun . Appioval . o rCompeten t Authorii yCeiiifiiMlc'. ' \ \ Vc s ) \ ' 1 N o h yes . piovid e ih e r.veiiiplion . .Approval , n rC, \ nuniher : 2^ . Wa s thi s .i n uiideclaie J ha/anloi cniateri:il s -hipmeiu V 

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Ri'im n Nuniher : K-2(M(in,W14« , TiiKKint ; iNiunlur : JSVai S / J Q / 

# VPAR T M l - PACKA(;IN( , I.MORM AJIO N 13 . De-ti)i.iiioi i .SiKe l City : Keithika n Sine . .\ KCoiaitry - U S ' Zi p C.:Je . 24 . Chee k

Paekiutiii ; Typ e lehee k onl yon e - i(iTii)r ctha n one , lis i t)]i e o f pa^'kajimg , eop yP. m III , an d eornplet e to re,icJ i t)i)e . 

## \ Non-bal k C\liiKle r 

### in c R A M 

# B Carg o T,in k Moto rVehi c PoiiableT:in k

. leiCT.MV ) I I Tan k Ca r I I Oilie r 25 . Se e in-;tniLtion- ; .mi l ente rth e apprnpnat e f,iilur clOiJe s toun d a i th e en d o f th e insiruilions . R e sun- ' loenie i tlieiode s frnn i th e lis t tha t j(>iie-.po',isl s w tl wpiinlcvila vp.icliau'.ny . 'Lyp e eheeVe d ibovc . Enie i th e nuiiibo ro f cixle; . ,i ^ 7,)ip)opri,u e t o ,le'%iTib e ih cineiJi;ii i Unve rth e mo-. l imporian i i.nlur e poin t i n lin e 1 . I f ther e ar e mor e th. m Iw n failur e points , provid e i n ihi s forma l i n pa n VI . lOii . Pri n :J e ih e paekayini ; ideiiiificatio n rnarkin^s . i f .iv,iilable . UleniilieaiiiM i Ma!l;in'j.s' . 1 Singl e 2hb .

27 .

2« . Purkag e o r(liile rPackuning :

Pnikugin g Type : 4 .Materia l o t ci'iisirtieimn ; G Hea d Typ e if.iniiTi.- . oiilv) : [ I f<ciii,-^:ih!, - 1 1 S'on-Rfi>hi\,d>l f P.i.Lk.i'.i e C'ap;icn yan d th e i|uamu y P.iekat e Capacity : Ainoim i II I P.iekage . .S'liriibe ri n -rhipmeni : Numbe rFailed : Paekaiiiiii : CoiisiniLiio n an d Tes t Inloniiation .

Manuf:iLiuier : Maniii'.ieiur e Dale . SiTia l Number : Las t Tes t Dale' . Materia l o f Consttue i ion .

Desig n IVessua- : Shel l Ttiieliiiess : Hea d Thickness : Setvis e Pressure ; I f Valv e o rdevic e faiU'd : 1 ype : .Manulaeiuier . Model . Inne r 26h .

27 ,

28 . Packag e lifuii^) : I

Packa^mjiTyp e Materia l o f construction : Packag e Capautt yanr | th e tjoatnil y Paeka[; e Capacity . .Amoun t m P:ickapc Numbe ri n shipment . Numbe r1 ailed ; Paekaginj. ' Coiislructio n an d Tes t lnlorni,iiion .

Manufaeturer ; M:inulJi"lur e Dale Seria l Number : Las i Tes t Date ; Maicnn I o f destruction .

29 . I f th e pnckaym yi s fo rRadio.iciiv e Matenals . complet e ih clolluwing ;

P.iekaitin^C.negory : ( [ Typ e A j [ Typ e B ) | Type C | | E^copie J | | Induslria l P.\\:l^a)^'in;;Cert^l",c,»ion | \ S^lfCenilie J | | U S Cer^^ricai.o n Cenir.e,itio n Number ; Nuchde(s ) I'lesent : Tianspor t Iiide.^ : .Aciivity . Criiiea l Safel ylnde\ .

F > 1(11 1 l)Oll-::Si.>U. ( lO l 2()UJ ) Pas c2 Repo'Jiiilioi i o f ilii s foii n I S peiniille d Repi.r l iNumhtr : K-2()l(KM(il4S . Trackin; ; Niinilu-r : 48'M: H 

# 5 ^ -<-!PA R rI V - C().N.si-:(jui!:NCK S

3» . Resiil i i. f liii.ideii i Uheek .il l tliat [ipplyV . Spillage ) j i'lr e i j ll.splosjo n | j M,iieiia l I'mtete d Wuiei'vauJStorii i Sewe t V.ipo riGab ) Dispersio n | | nnvironiiienia l Damag e | . V [ N o Releas e 3 1 . Emergenc yRespons e Tli e lollowinj ; entitie s lespoiuk- d M i h e incident . i Chec k ;il l iha i apjily ) ) I rne/II.M S Repoi l « f | Polic e Repoi i N ) _ j In-huus e cleanu p ' | ] Othe rCleanu p 32 . Daui.i'^es : Wa s th e mtn l Jamae ccos t mor e tha n S50J' ' | \ Ye s [ X \

N o I f ves . Cille rI'l e folliivian g inlormaiion - I f no . g o t o cjue.stio n 33 . .Materia l Loss ; Carrie rDamage ; Propett yDamage ; Respons e Cost : Rcmi-d i a t ion/Cleanu p Cost . i U S O %>i) ' S U S O (Se e damai^ e deliniiiDn s i n th e insiruetiuns ) J3J . Di d ih e hazardou s materia l caus e o rcontribut e l o a huma n laialiiy ' | ] Vc s \ S ] N o I f yes , cnic rili e nuinbc i o f fatalitie s fCboltin g fro m th e hazaidoo s material' . Paialities - CiTiplojecs . 0 Rcsponders : 0 Genera l Public - l ) J3b . Wer e ther e huma n fatalitie s tha t di J no t resul t fro m hazardou s maierial'. ' | | Ve s [ .\ ' J N o I f yes , ho wmany' ' 0 J4 . Di d th e hazardou s iri;iieriaK-aiis e o rconiribui ct o persuna l injury ' | | Vc s | . V ] N o

I f yes , eiile rth e niniihe ro l injune s resultin g fro m th e ha/arJou s niaterijl ; Hospitalize d (Admitte d Only) - Employees : 0 Rcsponders : 0 Genera l Public : 0 Non-Hospiialized ; rmpioyecs : I ) Kesptindcrs . 0 Genera l Public ; f ) fe. g O n sit e lirs t ai d o rFmergenc yR'Kn n observatio n ;in d release ) 35 . . Di J th e ha/arJou. s materia l caus e o rcontribut e loa n evacuation ? ] ) Ve s | X ] N o

I f ses . pTOviil e ih cfollowin g infotmaiion ; Tota l numbe ro f genera l publi cevacuated . U Tota l numbe rit f employee s evacuated " 0 Tota l Evacuated : 0 Duratio n o f ih e ev,ieuation - (l ( hours ) Jft . Wa s a majo rlr:iii.s|)on,iiio n aner yo rfacilit yclosed' ^ 37 . Wa s th e maieria l involve d i n a cras h o rdei-ailment' '

I f yes , provid e th e lollowin j iiilormalion ; Estmialc J spee d (mph) : D Vehicl e overturn ? Vehicl e lef t roadwav/track '



# 1 1

v/track' ' ^'e s Ve s ( X 1 N o I f yes , ho wman y 1 X 1 N o Weathe rcondition s 1 1 Vc

s 1 I V. S 

## 1 1 N o

1 1 N o P.\R TV - AI R I.NCIDKN'I ' INFORMATIO N I pleas e refe rl o ^17 5 3 I t o repor t a discrepanc yfu rai rshipments ) iR . \V-.\ith e shipmeji t v) » apa^seii^c i jivei.ifi'. ' | | Ye s 1 X | N o

I l ycs . vv.i s i l tendere d a s c;irgo , o ra s passenge rbaggage ? I I C;ii^ o I [ P.issetigc i baggage * 3V . Wher e di d th e inciden t occu r(i f unknown , chec k ih cappropriat e bo s fo rth e locatio n \^her e th e inciden t '-vas disiovercd). ' I . X I .Ai l canie rc;iig o laeiht y\ ] Sor t Cciiic r| | flagg.ig e .Are. i I I R \

snifae cto/im m aiipo n j ^ ^ Purin g llioh t ] | Durin g loading/unlo.tdin g o f aircral t 40 . Wha t pliasci.s' ) h.t d (h e -hipmen t ;ili..'ad yiindetgon e prio rt o ih e incidc m ?'I'-'liee k al l rh: n apply ) j . X I Shtpmen i li.i d iio i bee n iraiispoiie d \ [ Transporte d b yai rMirs t tlight ) | | Tiansporte d h yai r(."^uh^ieijuen i llights ) ) ) hinia l iran-poi i b yhighwa yl o c:ng o faciln y[ | Tran.sfe ra t so n cciitei/cjrg o lacihi y h'or m IJt.' l K^HIJ' I 1 ;Ul-2'Jli n Pai: c3 ReproJuclio n o f llii ; loni i i s pcfiniite d Repor l Ntimber : i:-2IH(l03lli4S . Trjckin yNiimbt-r : 4«'I42 8 ' Z j - O "



# 3 'i i /P\R TV ] - DKSCKIP I IO N o rKVtNJ S & 1'ACKA(; KlAlLURt : Oesciih e ihi : sei.|iiiji.: e o l CVLTII S tha t le d ': ) 'li e iiwijiji u .wi i (h e a>:U.m - V.iite n a t th e iim e [< . vas'listoveicd . De^enli e th-> - p,ieki'.i: e l;u!ui-e . Liicl'idini^'.h e siv t an d UK,'ar,sr i o l holes , ciacks . et cPhot.i^raph s .in d diuj;r:im s sliuiil d b e .•.Lbmitic d i f neede d lo rclaiilicaiion . I:siijiiat e th e duratio n o l ih e release . i J p.i;.•-ible . Desciih e \'.ha i i^a s dun e l o tniiiu:i' cth e ettcct s o l th e releas e Corninu e u n aildiiiona l sheet s i l nece-.-ary . Un.leelaie d hazni.i i loun d whd e -neenin g .Nonhe d loca l l-'A Ah.izma t :igeiiis .

PAR TVl l - KllCOMMKNDATIONS/ACTION S TAKF N T O PRtVKN TKKCURKKNCE : Wlvji f yo' a iio j abl e ( o J o so . sue-^es i -. M desciib e chimge s isuc h -i s -.'.Jditioii'i l training , u^e o t tx'tic rpi'.s-t.igiiii; . m impiove J s'peintio n proceJucci ) u i hel p preven i recuirence . Provid e reconirneiidalion s lo riinproveme m l o hazardou s material s ir,ai.sponalio n beyon d ih e contro l o t you rmdividua l company . Continu e o n additiona l sheet s i f necessarv .

PAR TVlll-CO M AC TINFORMATIO N CoiiLict' s Name : Mik e Hgelan d Coniaci' i Title . Cargi i Superviso r Busmei s Name - Alask. i Aijhiic s AJJies s Slice i iKJriOl d Intcin.iiinda l City : ANCHORAGF . State . .A K Omntts ; U S Telephon e Numbe r')l)7-2(i6-7SL' i Fai ; Nuniher Hazma t Reei.strnuo n Nmnbc r(i f no t alread vproviJcd) -

7-i p CCKIC - 90511 2 i;-iiiai l Address . inike.cj:eljiidi'?:i!askaai rcci m Piep;'.f,: i ;s . | \ \ CAir.ei- | j Shi^>pe i \ \ Facilit y| | Othe r D.ne : 3/10/201 0

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thi s IcttcT a s a nexplanatio nofou r action s regardin g th e .AlaskaAirline s shipmen t o f I'ehruar y l^^th . 201 0 airua y hil l ^ 027-3J7I-'^S73 . 

## Tg i I reigh t

ha s bee ninvolve da s adangerou s good s agen t for Parson s Ci>rporatio ndatin g bac k to Jun e o t

200'^ . .Attache dyo u wil l tln ddocumentatio nKoralir e extinguishe r that w e shippe do nai r

vsavbil l H 027-3371-^)82 5 (LATA ) an d(^RM- D materials{CFR-49 | tha t w e shippe do nai r

waybil l 027-3371-9740 . Thes e tw o shipment s wer e tendere dl o u s a t th e sam e lim e a s th e Pro-po\ y 40 0 o nai r waybil l 027-3371-9873 , Ha dParson s requeste dan y othe r airline , ai l package s mentione dabo\ e woul dhav e bee n tendere dt o th e airlin e o non e ai r waybill . I h e .shipment s wer e divide dont o separat e hill s a s arequiremen t

o f Alask a.Airlines . i amalsi> includin g trainin g record s To r JetTJueneman . .lel T i s employe dat Tg i Freigh t

a s iHi r Warehous e Manager /

Hazardou s Material s Specialis t an di,s th e perso ntha i prepare d ihi s shipment , Il i s ou r standar dprocedur e to inspec t eac hpackag e for

an y indicatio no f hazardou s material . I

nthi s cas e Jef

f firs t identitle dth e tir e extinguisher . Ff e marke dan d labele di t an dlogge dit

for dt>cumeniation . Nex t

h e identitle dcarton s o f consume r commoditie s an dcartridge s powe r device . H e confirme dtha i th e inne r container s t) f

th e liquid s me t

th e requirement s o f

173.27 . an dlabele deac ha s (.iRM-[)-Air . Bothwer e [ouL2e dfor documentation . 

# /I-. 2 4 J P.O . E o •: ^

;O-IS , An.:hcr:„i e AK , 0S5'."2 ' 1C-V 9 ;000', V 50''A-.':. . '*7;-;Anrh:ir,n^^ . A K-y^^O' }

## (.\'niinue dfrc> mpag e 1 Wlie nidentifyin g th e i'ro-pol y 40 0 h e firs t examine d(h e tntlsid c o f ih e factor y canon. ' I li e carto nappeare dt o Jef f l o h e a;shippin g container . Nowher e o nth e carto nwa s an y indicatio n-.'

f ha>:ardou s material , Ther e wa s n o U Nnumber , prope r

shippin g nam e o r hazar dlabels . Clo.se r

e.xaniinalio no f

label s o nth e carto nreveale dn o consume r warning s iha t woul dindicat e th e content s bein g hazardous , (Se e attache dpicUires) . .A s a n additiiMial precautio nJef f opene dth e bo. x t o examin e th e inne r container s for

an y consume r

warning s dia l migh l indicat e iha l th e prtvdvie t ma y b e ilamniable . corrosiv e o r loxic . fypica l consume r

warning s tha t

w c loo k for ar e "Kee p awa y fro mhea t o r tlame" . " D o no t us e inenclose dareas" . "Fume s ma y ignite" , "Contac t wit hski no r

eye s ma y caus e hum s (^ r blindness" . "Poison , kee p ou t o f th e reac ho f

children" . Man y manufacturer s no w choos e to prin t

mim'aturc s o f

th e diamon dshape dhazar dlabel s o neac hinne r c»>nlainer . Nowher e o nth e inne r container s wa s ther e eve nth e slightes t indicatio ntha i ih e produc t presente dan y dange r

t o th e u.ser . .A t thi s stag e Jef

f wa s confiden t

tha t th e produc t

wa s no nregulate da s ahazardou s materia l an didentitle di t a s suc ho nth e ai r

waybill . Becaus e h e foun dn o warning s lik e thos e memione dabove , h e wa s satistle dtha i asearc hfor amateria l safet y dat ashee t wa s unnecessar\' . We hav e sinc e the nprinte daMSD S for th e Pro-po.\ y an dhav e discovere da di.screpancy . f

nsectio n5 th e MSD S list s th e produc t a s havin g aHas hpoin t o f 6 5 degree s Fahrenheit . However , i nsectio n1 4 th e MSD S contradict s itsel f b y stalin g tha t th e produc t

i s apackin g grou p (( ( tlammable . f na nattemp t

to determin e tha t

th e carton s tha t

w e receive dan dshippe dwer e ashippin g container . I calle dUnite x i nKansa s City . M O Phon e ^ (816-231-7700) . I lirs t spok e wit h Muliani nth e chemistrv - department . H e conHrme dtha t th e flashpoin t

for par i A i s 6 5 degree s Fan dwen t

o nt o explai ntha t

the y lis t th e produc t

a s apackin g grou p 111 . H e the ndirecte dm e t o .laso nHarris . Jaso nmad e referenc e l o I 73.12 1 (b ) (I ) (i ) (ii ) (iii ) t o explai nth e reaso nfor a6 5 degre e [lackin g grou p fll . H e the nprovide dth e followin g exampl e a s atypica l shipmen t o f Pro pox y 400 . Th e unmarke dwhit e displa y boxe s (a s picuirc di nthi s packet ) ar c stacke do na palle t ihe nstretc hwriipped . Thi s confirm s tha t th e whit e carton s tha t

w e shippe dar e a n oute r c\MUaine

r a s describe di n! 7 ! .8 . 

# /I- J3

## ('(Muinue dtVtu npag e 2

I h e produc t

i s the nliste dIM

Ith e bil l o f

ladin g a s Adhesive . I.' n1 133 . p g III . I t i s Ijnitex' s incorrec t bolieflha t

173.15 0 (b ) 172.30 1 la ) (I ) relieve s the mfro mal l markin g an d labelin g requirement s for surfac e shipment . I l e adde dtha t asmalle r

shipmen t

o f on e \> r iw o o\ ' th e sam e carton s woul dreceiv e aConsume r commodit y label . Ou r researc hha s determine dtha t th e manufacture r

doe s shi p thi s produc t fro mthei r facilit y inth e package s a s w e receive dthem . Inaddition , the y hav e faile dt o mar k thos e oute r package s a s require db y 172.30 0 an d172.301 . Thes e fact s combine dwit hth e lac k o f an y consume r

warnin g o f

flammabilit y o nth e inne r container s le du s to shi p th e produc t a s ano nregulate ditem . I t i s ou r stanc e at

Tg i Freigh t

tha t w e acte daccordingl y base do nth e inforinatio n provide du s o nth e manufacture' s .shippin g containers . Ha dth e carton s bee nmarke da s require do r

th e inne r

container s marke dwit hatlammabl e warnin g w e woul dhav e followe dou r

standar dprocedur e an dobtaine damateria l .safet y dat asheet . W e woul d hav e the ndeclare dthi s produc t an dinclude di t

o nth e hazardou s maieria l declaratio n accompanyin g ai r

waybil l t

i 027-3371-9740 , I hop e tha i thi s correspondenc e adequatel y explain s th e reason s for ou r action s involvin g thi s particula r

shipment , it' I ca nprovid e an y furthe r informatio npleas e fee l fre e l o contac t me . Sincerelv . Tod dClar k President . Tii i Co . In c



# 0. 1

# MSD S '^^*®''*^ ' Safet yDat a Shee t PRO-POX Y40 0 MSD S Number - 100 3 Revisio n Date : 7/2/200 8 Pag e o f 4 

### PRODUC TAN D COMPAN YiDENTlFlCATlO N IVIanufacture r UNITE X 310 1 Gardne rAv e Kans.i s City . M O 6412 0 Contact : Technica l Service s Telephon e Number : 816-23 1 -770 0 FA X Number : 816-483-314 9 E-Mail : mail@unitex-chemical s co m We b www.unitex-chemicals-co m Produc t Name ; Revisio n Date : MSD S Number : Produc t Code : Chemica l Family : Produc t Use : PRO-POX Y40 0 7/2/200 8 100 3 PRO-POX Y40 0 Epox yResin . Epox yAcrylat e Blen d All-weathe repox yacrylat e hybn d anchorin g ge l Chemtre cEmergenc yTelephon e N o 800-424-930 0 Rout e o f Entry : Targe t Organs : Inhalation : Ski n Contact : Ey e Contact : Ingestion : 

### HAZARD S IDENTIFICATIO N Eyes . Skin , Swallowing , Inhalatio n Eyes , Skin , Uppe rRespirator ySystem . Medica l condition s aggravate d b yexposur e (non e identified ) Ma yproduc e irritation , sensitization . Ma yproduc e irritation , sensitization . Ma ycaus e irritation . Symptom s includ e stinging , tearing , an d redness . Ma yproduc e irritation , sensitization . 

### COMPOSITION/INFORMATIO N O N INGREDIENT S Ingredients ; Ga s # chemica l Nam e Perc . Componen t A 8062 6 901086 2 1480860 7 Acrylat e Blen d



# I I ! silica , crystallin e Componen t B 9436 0 I Benzoy l peroxid e 6851540 2 ! 47125 1 I Calciumcarbonat e 2506838 6 I Epox yResi n 30-50 % 40-60 % 10-25 % 10- 2 5 % 20-50 % 10-25 %

# MSD S Materia l Safet yDat a Shee t PRO-POX Y40 0 MSD S Number : 100 3 Revisio n Dale : 7/2/200 8

Inhalation : Ski n Contact : Ey e Contact : Ingestion : Pag e 2 o f 4



### FIRS TAI D MEASURE S I f respirator yirritatio n occurs , g o t o fres h air . Floo d wor k are a wit h fres h air . I f irritatio n continue s see k medica l attention . Remov e contaminate d clothin g an d shoes . Remov e produc t fro m ski n immediatel ywit h a dr yclot h o rpape rtowe l Was h affecte d area(s ) thoroughl ywit h soa p an d water . SOLVENT S SHOUL D NO TB E USE D becaus e the ycarr yth e irritan t int o th e skin . I f irritatio n persists , see k medica l attention . Flus h th e eye s wit h plent yo f wate rfo ra t leas t 1 5 minutes . I f necessary , gentl yhol d eyelid s ope n durin g th e flush . Immediatel ysee k medica l attention . Obtai n immediat e medica l attention . Drin k larg e amount s o f water . D O NO TINDUC E VOMITIN G 

### FIR E FIGHTIN G MEASURE S Flas h Point : Flas h Poin t Method : Burnin g Rate : Autoignitio n Temperature : LEL : UEL : Flammabilit yClassification : A-65F/B-315 F Pensk yMarten s Close d Cu p N o dat a availabl e N o dat a availabl e A : 2.1 % B . n/ a - A - 12.5 % 8 - n/ a Flammabl e Liqui d Trea t a s flammabl e liquid , wit h explosiv e vapor s Sel f containe d breathin g apparatu s ma yb e required . Protec t agains t ey e an d ski n contact . Figh t fir e fro m distanc e a s hea t ma yruptur e container s Avoi d breathin g vapors . Explosio n hazar d whe n expose d t o hea t o rflame . Coo l expose d container s wit h water . Vapo ri s heavie rtha n ai ran d ca n trave l a considerabl e distanc e t o a sourc e o f ignitio n an d flashback . NFP AClas s B- C extinguishe r(dr ychemica l o rfoam ) fo rclas s 1 cfires . Wate rspra yma yb e ineffectiv e o n fir e bu t ca n protec t fir e fighter s an d coo l close d containers . Us e fo g nozzle s i f wate ri s used . Us e supplie d breathin g masks .



### ACCIDENTA L RELEAS E MEASURE S Eliminat e al l ignitio n source s (flares , flames includin g pilo t lights , electrica l sparks ) Us e anti-sparitin g tool s Person s no t wearin g protectiv e equipmen t shoul d b e e'<clude d fro m are a o runti l spil l clean-u p ha s bee n complete d Slo p sp' H a t source . Preven t fro m enterin g drains , sewers , stream s o rothe rbodie s o f wate rPreven t fro m spreading . Tr yl o preven t part s A& B fro m mixin g Collec t wit h absorben t materia l an d plac e i n containo rfo rprope rdisposal . Fo rlarg e spill , transfe rt o salvag e vessel s an d dispos e o f accordin g t o slate , loca l an d federa l regulation s Flus h are a wit h wate rt o remov e residue . D O NO TCONFIN E Neve rretur n spillag e t o origina l conlaine rfo rreus e



### HANDLIN G AN D STORAG E Handlin g Precautions : Storag e Requirements : Fo rprofessiona l us e only . Avoi d eye/ski n contact . Was h afte rusin g an d befor e eatin g o r smoking . Avoi d breathin g vapors . Us e a s directed . Avoi d uncontrolle d mixin g wit h othe r mixture s (stron g acids , base s an d amines) . Hazardou s polymerizatio n ma yoccu rwit h excessiv e heat . Stor e i n a cool/dr ylocation . D o no t allo wmateria l t o freeze , a s produc t ma yb e damaged . Stor e awa yfro m spark s an d ope n flames . 

# s

# MSD S Materia l Safet yDat a Shee t PRO-POX Y40 0 MSD S Number : 1003 - Revisio n Date : 7/2/200 8 Pag e 3 o f J 

### EXPOSUR E CONTROLS/PERSONA L PROTECTIO N Engineerin g Controls : Protectiv e Equipment :

Exposur e Guidelines/Other : Respirator yProtection : NIOS H approve d respirato rfo remergencyus e o rwhe n inadequat e ventilatio n ma yexist . Loca l exhaus t i s preferable . Mechanica l equipmen t i s acceptable . Protectiv e chemica l resistan t glove s (recommende d buty l rubbe rsolven t resistan t gloves) , safetygoggles/fac e shiel d an d splas h bi b Othe requipmen t a s require d t o preven t prolonge d contact . Writte n respirato rprogra m i s outline d i n 2 9 CF R 1910.134 , an d i s require d b yOSHA . 

### Thi s materia l i s no t liste d byth e internationa l Agenc yfo r Researc h o n Cancer , th e Nationa l Toxicolog yProgram , o r th e Occupationa l Safet yan d Healt h Administration , 

# \£WS^^^ ^ Appearance : Physica l State : Odor ; PH : Vapo rPressure : Vapo rDensity : VOC : Evap . Rate : 1 PHYSICA L AN D CHEMICA L PROPERTIE S A - Whit e Gel , distinctiv e odo r Ge l A:Distinctiv e B:Sligh t odo r N D N/ E A : 3. 5 8 : n/

a A . n/ a B . n/ a Ether= 1 A< 3 B > B-Blac k Gel , sligh t odo r Boilin g Point : Freezing/Meltin g Pt, : Solubility : Spe cGrav./Density : N D ND/N E ni l A:1.5 6 B:1.6 4 

# KUW^B g 1 STABILIT YAN D REACTIVIT Y Stability : Condition s t o avoid : n/taterial s t o avoi d (incompatabillty) : Hazardou s Decompositio n products : Hazardou s Polymerization : Stabl e Heat , sparks an d ope n flames . Hazardou s polymerizatio n ma yoccu rwit h heat . Isolat e fro m stron g oxidizers , acids , base s an d amines . CO , C02 , hydrocarbon s A : Occur s wit h heat , absenc e of inhibitor , additio n of catalyst . B : Doe s not occu r TOXICOLOGICA L INFORMATIO N No dat a availabl e ECOLOGICA L INFORMATIO N N o dat a available . 

# n?mmmsi ' DISPOSA L CONSIDERATION S Dispos e o f i n accordanc e wit h al l applicabl e local , stat e an d federa l regulations . 

# 3 ^

# MSD S ^^*^''*^ ' Safet yDat a Shee t PRO-POX Y40 0 MSD S Numbe r100 3 Revisio n Date ; 7/2/200 8 Pag e J o f 4 

### TRANSPOR TINFORMATIO N Shippin g Name : Adhesive , 3, . UN1133 , PGIII , Emergenc yRespons e Guid e NO . 2 7 Labe l Flammabl e Liqui d 3 (onl ywhe n shippin g b yai r o r water ) Canad a EPA : Al l ingredient s liste d o n DSL . WHMIS : An/ a B : clas s C REGULATOR YINFORMATIO N THi s MSD

S ha s bee n prepare d i n accordanc e wit h federa l OSH AHazar d Communicatio n standar d 2 9 CF R1910.1200 . HMi s Codes : Health(2 ) Flammability(3 ) Reactivity(2 ) PPECJ ) WHMIS" . A : n/ a B : clas s c Hazar d clas s 3 , Flammabl e Liqui d Adhesive , 3 , UN1133 , PGiii , Emergenc yRespons e Guid e No . 2 1 Canad a EPA : Al l ingredient s liste d o n DS L TSC AInventor yStatus : chemica l component s ar e liste d o n TSC Ainventor ySAR ATitl e ill . Sectio n 313 . Thi s produc t contain s mercapta n whic h i s subjec t t o reportin g unde r sectio n 31 3 o r SAR ATitl e II I (40CF R Par t 372) .

OTHE R INFORMATIO N Th e informatio n an d vecommendEilion s i n thi s docLimne t ar e base d or . th e bes t irformatio n availabl e t o u s a i ih e tim e o ( preparation . W e mak e n o othe rwarranty , expresse d o rimplied , a s t o it s correctnes s o rcompletness , o ra s t o th e result s o rrelianc e o f thi s product . Thi s produc t ha s bee n classifie d accordin g t o th e hazar d criteri a o f th e CP R an d th e MSD S contain s al l th e informatio n require d b yth e CPR . 

### EN D O F MSD S DOCUMEN T



# (\'l' ] H - ^