Instructions for filling the Emission Test Template

This Information Collection Request (ICR) spreadsheet is intended to collect information about emission data from fossil fuel burning power plants and which test methods were used to do so for cases where the test methods are not currently supported by the Electronic Reporting Tool (ERT). This spreadsheet should only be used if the method is not in the ERT or if you do not have access to a lab which performs methods that are in the ERT. Constituents of concern are: Carbon Monoxide, Formaldehyde, Methane, Speciated Volatile Hazardous Air Pollutants (HAPs), Speciated Semi

- Volatile Organic HAPs, Sulfur Dioxide, Oxygen, Carbon Dioxide, Hydrogen Cyanide, Nitrogen Oxides, Total Dissolved Solids (TDS), and Total Suspended Solids (TSS). You must complete 3 separate sampling events for each of the requested constituents. This spreadsheet is intended to be used for one boiler of one facility. Data for multiple boilers should be handled by using separate copies of this spreadsheet. Fields shaded in yellow are required. All cells that are shaded in light green are populated using drop

- down lists. You do not need to populate cells shaded in gray, as they are automatically populated from the Boiler Information worksheet. Please Do Not modify the structure of this spreadsheet by adding or subtracting
rows, columns, cells. Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_EmisTestMethods.xls (example: 8100_Unit_2_EmisTestMethods.xls).

Please refer to the following steps when using these spreadsheets.

Boiler Information Worksheet

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the control device configuration.

Emission Data Worksheets

The emission data worksheets are provided for each constituent or constituent family required for this analysis. On each spreadsheet, you must enter boiler operating information during sampling, fuel input information, and emission test results. There are generally 1 to 3 emission test results records to be entered depending on the constituent or constituent family. For example, CO only requires 1 record with 3 sample events, while Mercury requires that you enter both Hg 0 and Hg +2 , or if the Ontario

- Hydro Method was used, you would need to enter Hg 0 , HgP, and Hg +2 . However, both the Speciated Volatile Organic HAP and Speciated Semi

- Volatile Organic HAP worksheets allow you to use a drop

- down provided in the Constituent field to define as many records as needed to record each HAP that you have results for. General instructions follow for these worksheets:

Boiler Operation Information

1. Please determine which units of measure (acfm or dscfm) were used for Exhaust Flow Rate and which units of measure (deg C or deg F) were used for Exhaust Temperature. Fill these units of measure into the Units of Measure field. 2. Please provide the values of all requested parameters for each of the 3 sample testing periods in the Sample 1, Sample 2, and Sample 3 fields

. 3. Please provide any other supporting information or comments in the Other Supporting Information field.

Fuel Information

1. Please enter what types of fuel are being used in your boiler using the drop

- downs in the Fuel Type Selection field. You may enter up to 4 fuel types. Then, enter the input rate of each fuel in the Sample 1, Sample 2, and Sample 3 fields. If you are not burning one or more of the fuel types entered in one or more samples, then enter an input rate of zero. 2. Please enter the unit of measure using the drop down provided. 3. Please enter the test method used to determine the fuel input rate. 4. Please provide any other information that you feel may be important in the Other Supporting Information field.

Emission Data

1. Some constituents ask for the emission rate results of each of the 3 samples in two different units of measure, while others do not. If emission rate results are requested in two different units of measure (ex. lb/MMBtu (Pounds per million BTU) and ppmvd @ 7% O 2 (parts per million by volume dry basis at 7 percent oxygen)), you are required to provide both. 2. Please provide the test method used. This may or may not match the example given in the Test Method Used field. Please ensure that the name includes the owning organization of the test method (ex. U.S. EPA Method 0010). 3. Please provide any other information that you feel may be important in the Other Supporting Information field. 4. If data sheets and QA/QC documentation tables are provided for the test method you are entering data for please also enter these data.EIA

Facility Code Facility Name Boiler ID

628 Crystal River Unit 1Control Device Configuraton

Listed (by

boiler) in Question 16 (page 17) of the questionnaireEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Sample 3 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate

Sample 2 Fuel Input Rate

Sample 3

Emission Test Results CO Emission Rate Sample 1 (lb/MMBtu) CO Emission Rate Sample 1 (ppmvd @ 7% O2) CO Emission Rate Sample 2 (lb/MMBtu)Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Unit of Measure Fuel Flow Me asurement Me thod Other Supporting

Information

CO Emission Rate Sample 2 (ppmvd @ 7% O2) CO Emission Rate Sample 3 (lb/MMBtu) CO Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA Me thod 10A) Other Supporting InformationEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Sample 3 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate

Sample 2 Fuel Input Rate

Sample 3

Emission Test Results Formaldehyde Emission Rate Sample 1 (lb/MMBtu) Formaldehyde

Emission Rate Sample 1 (ppmvd @ 7% O2) Formaldehyde Emission Rate Sample 2 (lb/MMBtu)Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Unit of Measure Fuel Flow Me asurement Me thod Other Supporting

Information

Formaldehyde Emission Rate Sample 2 (ppmvd @ 7% O2) Formaldehyde Emission Rate Sample 3 (lb/MMBtu) Formaldehyde

Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA Me thod 320)Other Supporting

InformationEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Date of Testing 3/26/2010 3/26/2010 Steam Output (1000 lb/hr) 2061 2009 Total Heat Input (MMBtu/hr) 3765 3630 Basis (W et/Dry) We t We t Exhaust Steam % Moisture 6.29 4.87 Exhaust Flow Rate (acfm or dscfm) 1,38,596 1,370,578 Exhaust Temperature (deg C or deg F) 223 223

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 bitum inous 3765 3630

Emission Test Results Me thane Emission Rate Sample 1 (lb/MMBtu) Me thane Emission Rate Sample 1 (ppmvd @ 7% O2) 0.00031 0.472Sample 3 Unit of Measure Other Supporting Information 3/26/2010 2011 1000 lb/hr 3601 MMBtu/hr We t N/A 4.83 % 1,362,005 acfm 223 deg F

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Me thod Other Supporting Information 3601 MMBtu/hr F-Factor CEMS Data

Me thane Emission Rate Sample 2 (lb/MMBtu) Me thane Emission Rate Sample 2 (ppmvd @ 7% O2) Me thane Emission Rate Sample 3 (lb/MMBtu) Me thane Emission Rate Sample 3 (ppmvd @ 7% O2) 0.0003 0.468 0.0003 0.465Test Method Used

(ex. U.S. EPA Me thod 18) Other Supporting Information U.S. EPA Method 18 Run 1 BDL, Run 2 BDL, Run 3 BDLEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Sample 3 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3

Emission Test Results SO2 Emission Rate Sample 1 (lb/MMBtu) SO2 Emission Rate Sample 1 (ppmvd @ 7% O2) SO2 Emission Rate Sample 2 (lb/MMBtu)Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Unit of Measure Fuel Flow Me asurement Method Other Supporting Information

SO2 Emission Rate Sample 2 (ppmvd @ 7% O2) SO2 Emission Rate Sample 3 (lb/MMBtu) SO2 Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA Me thod 6)Other Supporting

InformationEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 3 Date of Testing 3/23/2010 3/23/2010 Steam Output (1000 lb/hr) 2027.546 2015.931 Total Heat Input (MMBtu/hr) 3606.197 3599.339 Basis (W et/Dry) Dry Dry Exhaust Steam % Moisture 5.5 6.5 Exhaust Flow Rate (acfm or dscfm) 867953 843587 Exhaust Temperature (deg C or deg F) 65 58

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 bitum inous 3606.197 3599.339

Run 1 Run 3

Emission Test Results Total Vapor Phase Me rcury Emission Rate Sample 1 (lb/MMBtu) Total Vapor Phase

Me rcury Emission Rate Sample 2 (lb/MMBtu) 3.37E-06 3.53E-06



### Data Sheets and QA

/QC Documentation

trap ID Section 1 1A AU 007975 256.1 1B AU 007837 548.7 3A AU007999 282.5 3B AU007806 546.5 5A AU007956 242.4 5B AU007984 515.9

Start 1A 3/23/2010 9:00 1B 3/23/2010 9:00 3A 3/23/2010 15:15 3B 3/23/2010 15:15 Summary of Hg Collected on Sorbent Traps via Method 30B

Run ID Appartioned Mass (ng)

Individual Sorbent Tube Emission Summary, Method 30B

Run ID Test Date Run Time5A 3/24/2010 10:15

5B 3/24/2010 10:15 Averages

Average R Vol. diff (%) 1A 1B 62.412 -1.12% 3A 3B 62.412 0.43% 5A 5B 62.412 0.39%

% Lim it 1A 1.171417415 1B 0.546746856 3A 0.991150442 3B 0.512351327 5A 1.031353135 5B 0.387672029 Summary of M30B Quality A ssurance Checks

Run ID Volum e Sam pled (dscm)

Run ID Sorbent Trap Breakthrough (B)

≤10% of Section 1 Hg

ma ss for Hg conc. >1
μ g/dscm: or ≤20% of Section 1 for Hg conc. ≤1 μg/dscmSample 5 Unit of Measure Other Supporting Information 3/24/2010 2007.338 1000 lb/hr 3576.488 MMBtu/hr Dry N/A 6.1 % 852628 dscfm 76 deg F

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Me asurement Me thod Other Supporting

Information 3576.488 MMBtu/hr F-Factor From CEMS

Run 5

Total Vapor Phase Me rcury Emission Rate Sample 3 (lb/MMBtu) Test Method Used

(ex. U.S. EPA

Method 30B) Other Supporting

Information 3.21E-06 U.S. EPA Method 30B ADL, Run 1- 3.37E-06, ADL, Run 3- 3.53E-06, ADL, Run 5- 3.21E-06 5 runs were performed but runs 1, 3, and 5 were reported

Total Mass (ng) Section 2 Sections 1+2 (ng)

3 259.1 0 259.1 3 551.7 302.13 249.57 2.8 285.3 0 285.3 2.8 549.3 302.13 247.17 2.5 244.9 0 244.9 2 518 302.13 215.87

Stop per tube per run per tube

11:00 4.1 4.1 11:00 3.95 3.95 17:19 4.5 4.5 17:19 3.93 3.93 Summary of Hg Collected on Sorbent Traps via Method 30B Initial Spike (ng) Total Non-spike

Individual Sorbent Tube Emission Summary, Method 30B Run Time Hg Emissions(lb/Tbtu) Hg Emissions (lb/hr)12:15 3.96 3.96 12:15 3.51 3.51 3.991666667

Lim it Abs. diff. % Lim it

C rec R (%) by Run R (%) by

program Lim it 1.863354037 ≥ 10 % RD mass for

Hg conc. >1 μg/dscm: or ≤ 20% RD or ≤ 0.2 μg/dscm abs.diff. for Hg conc.
≤1 μg/dscm 0.57 6.761565836

91.94 Average Recovery

,

between 85 and 115% 4.22 88.01 Summary of M30B Quality A ssurance Checks Paired Trap Agreement (RD)

≤ 20% of field recovery

test 0.15

4.46 90.84 0.45 6.024096386

Measured Spike Recovery ( R )

4.63 96.97ADL, Run 1- 3.37E-06, ADL, Run 3- 3.53E-06, ADL, Run 5- 3.21E-06 5 runs were performed but runs 1, 3, and 5 were reported

(ug) 0.2591 0.24957 0.2853 0.24717 0.2449 0.21587

per run per tube per run Hg Emissions (lb/y r)* Total Non-spike

Hg Emissions (lb/hr)#DIV/0! #DIV/0!

62.921 62.145 62.17 Spiked 62.4120 Average R

63.109 62.28 62.352 62.5803 Non SpikedEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Me rcury Species Me rcury Emission Rate Sample 1 (lb/MMBtu) Hg 0
Hg +2 Hg PSample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Me asurement Me thod Other Supporting

Information

Me rcury Emission Rate Sample 2 (lb/MMBtu) Me rcury Emission Rate Sample 3 (lb/MMBtu) Test Method Used

(ex. ASTM Method D6784) Other Supporting InformationEIA Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Sample 3 Unit of Measure Other Supporting Information Date of Testing 3/26/2010 3/26/2010 3/26/2010 Steam Output (1000 lb/hr) 2060 2008 2011 1000 lb/hr Total Heat Input (MMBtu/hr) 3765 3629 3601 MMBtu/hr Basis (W et/Dry) Dry Dry Dry N/A Exhaust Steam % Moisture 6.34 4.91 4.86 % Exhaust Flow Rate (acfm or dscfm) 1372494 1374789 1372135 acfm Exhaust Temperature (deg C or deg F) 342 343 343 deg F

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method Other Supporting

Information bituminous 3765 3629 3601 MMBtu/hr F-Factor From CEMS

Compound (use drop down to define for as many

rows as needed) Volatile Organic HAP Emission Rate Sample

1 (lb/MMBtu) Volatile Organic HAP

Emission Rate Sample

1 (ug/dscm @ 7%

O2) Volatile Organic HAP Emission Rate Sample 2 (lb/MMBtu) Volatile Organic

HAP Emission Rate Sample 2 (ug/dscm @ 7% O2) Volatile Organic

HAP Emission Rate Sample 3 (lb/MMBtu) Volatile Organic

HAP Emission Rate Sample 3 (ug/dscm @ 7% O2) Test Method Used Other Supporting Information Dichlorodifluoromethane 1.295E-06 1.434 1.041E-06 1.167 1.524E-06 1.703 U.S. EPA Method 0031 with SW -846 Method 8260B DDL Run 1,25.4,49.01,20.38,24.82,[<3] DLL Run 2, 32.4,13.65,13.14,37.91,[<3] DLL Run 3 39.48,14.82,22.43,68.46,[<3] 1,2-Chloro-1,1,2,2-Tetrafluoroethane 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Chloromethane 5.521E-05 42.453 1.152E-04 90.326 1.913E-03 1504.640 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1, 2864.34,1287.34,604.98,467.66,[<3] DLL Run 2, 7795.47,1241.92,921.82,1120.96,[<3] DLL Run 3 105178.6,78009.23,1553.02,1260.92,[<3] Vinyl chloride 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1,3-Butadiene 3.099E-07 0.238 5.773E-07 0.452 1.804E-05 14.193 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1, 12.62,9.56,1.16,[<3],[<3] Run 2, 24.78,[<3],15.09,9.65,[<3] DLL Run 3 202.33,1516.55,15.72,16.96,[<3] Bromomethane 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Chloroethane 3.660E-07 0.281 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],22.65,[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Trichloromonofluoromethane 1.615E-06 1.242 2.173E-06 1.703 6.522E-07 0.513 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1, 19.44,73.81,18.21,38.47,[<3] DLL Run 2, 116.19,17.04,9.19,63.58,[<3] DLL Run 3 23.19,4.61,23.52,9.1,[<3] 1,1-Dichloroethane 1.271E-06 0.978 4.375E-06 3.429 1.595E-06 1.254 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1, 7.9,14.43,27.65,67.39,[<3] DLL Run 2, 91.7,97.95,75.79,152.33,[<3] DLL Run 3 71.24,3.89,14.42,62.53,[<3] 1-1,2-trichloro-1,2,2-trifluoroethane 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Ethanol 2.273E-05 17.475 4.420E-05 34.641 1.832E-05 14.414 U.S. EPA Method 0031 with SW -846 Method 8260B ADL Run 1, 354.4, 640.48, 570.57, 584.24, 2.08 ADL Run 2, 2161.2,491.41,504.77,1089.47, 4.68 ADL Run 3 508.87,412.22,535.45,322.65,2.68 Carbon disulfide 1.489E-05 11.447 3.991E-05 31.286 8.095E-06 6.367 U.S. EPA Method 0031 with SW -846 Method 8260B ADL Run 1 152.53, 603.29, 235.67, 414.87, 3.18 DLL Run 2, 2757.91,[<3],126.95,943.81,7.13 ADL Run 3 310.06,41.26,352.09,80.35,3.37 Isopropyl alcohol 1.465E-07 0.113 1.783E-06 1.398 2.062E-07 0.162 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1, [<3],[<3],[<3],[<3],1.87 BDL Run 2, [<3],156.18,[<3],[<3],6.3 DLL Run 3, [<3],[<3],[<3],[<3],8.05 Methylene chloride 1.855E-04 142.593 2.396E-04 187.805 8.356E-05 65.729 U.S. EPA Method 0031 with SW -846 Method 8260B ADL Run 1 2525.04,8697.07,3538.05,2794.64,3.04 ADL Run 2 12120.39,1700.84,872.76,8323.5,26.48 ADL Run 3 3083.24,990.17,3085.42,931.99,34.65 Acetone 1.867E-04 143.559 1.850E-04 145.017 1.195E-04 93.976 U.S. EPA Method 0031 with SW -846 Method 8260B ADL Run 1 3522.58,6596.2,4526.24,3017.65,14.22 ADL Run 2 6574.33,1817.87,3143.67,6209.02,48.98 ADL Run 3 3793.2,3363.9,2997.86,1411.91,50.52 trans-1,2-Dichloroethene 1.603E-07 0.123 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 [<3],3.18,[<3], [<3],[<3]BDL Run 2 [<3],[<3],[<3],[<3][<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] Hexane 1.584E-07 0.122 3.871E-06 3.034 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2 282.69,80.6,[<3],[<3],[<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] Methyl-t-butyl either (MTBE) 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1,1-Dichloroethene 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Vinyl acetate 1.182E-05 9.086 2.493E-06 1.954 1.095E-05 8.616 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1, 369.55,52.54,680.35,13.37,[<3] ADL Run 2 70.64,30.26,79.86,56.0,[<3] DLL Run 3 94.2,413.14,545.36,9.4,[<3] cis-1,2-dichloroethene 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Cyclohexane 1.953E-07 0.150 5.814E-07 0.456 2.306E-07 0.181 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 [<3],6.49,[<3], [<3] ,[<3] DLL Run 235.92,[<3],4.44,9.56,[<3] DLL Run 3 [<3],6.57,6.85,[<3],[<3] Chloroform 1.135E-07 0.087 3.921E-07 0.307 1.276E-07 0.100 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 1.74,2.53,1.77,1.71,[<3] DLL Run 2 27.29,2.08,1.52,3.82,[<3] DLL Run 3 2.15,1.7,2.56,[<3],[<3] Ethyl acetate 3.575E-06 2.749 6.130E-06 4.805 2.285E-06 1.797 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 82.19,74.74,59.17,119.35,[<3] DLL Run 2 236.17,143.07,96.46,110.86,[<3] DLL Run 3 79.25,16.95,69.69,53.26,[<3] Teteahydrofuran 9.597E-07 0.738 1.583E-06 1.240 1.080E-06 0.849 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 23.68,18.43,22.74,23.03,[<3], Run 2 78.41,14.65,30.94,25.21,[<3] DLL Run 3 36.62,21.25,26.17,17.94,[<3] 1,1,1-Trichloroethane 1.584E-07 0.122 2.556E-07 0.200 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1 [<3],[<3],[<3],[<3][<3] DLL Run 2 12.58,[<3],[<3],[<3],[<3], BDL Run 3 [<3],[<3],[<3],[<3],[<3] Carbon tetrachloride 1.797E-07 0.138 1.928E-07 0.151 1.445E-07 0.114 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 5.47,2.8,2.55,3.19,[<3] DLL Run 2 5.87,[<3],2.85,3.82,[<3] DLL Run 3 3.42,[<3],2.67,1.96,[<3] 2-Butanone (MEK) 6.211E-06 4.776 1.085E-05 8.506 5.699E-06 4.483 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 148.98,138.77,[<3],294.3,[<3] DLL Run 2 472.39,382.83,182.45,[<3],[<3] DLL Run 3 202.42,137.99,126.41,83.97,[<3] Heptane 1.584E-07 0.122 1.560E-07 0.122 5.024E-07 0.395 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1 [<3],[<3],[<3],[<3],[<3] BDL Run 2 [<3],[<3],[<3],[<3],[<3] DLL Run 3 [<3],36.85,[<3],[<3],[<3] Benzene 8.951E-06 6.882 1.110E-05 8.700 1.755E-05 13.803 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 165.13,123.22,391.62,164.44,[<3] DLL Run 2 391.33,140.57,390.27,142.31,[<3] DLL Run 3 240.37,1028.9,318.57,115.44,[<3] 1,2-Dichloroethane 1.651E-06 1.269 2.182E-06 1.711 3.946E-06 3.104 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 [<3],[<3],6.72,140.58,[<3] DLL Run 2 17.55,43.41,128.19,17.74,[<3] DLL Run 3 [<3],[<3],132.0,242.75,[<3] Tetrachloroethylene 1.420E-07 0.109 1.759E-07 0.138 1.350E-07 0.106 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 1.44,[<3],[<3],[<3],[<3] DLL Run 2 [<3],[<3],4.92,[<3],[<3] DLL Run 3 1.13,[<3],[<3],[<3],[<3] 1,2-Dichloropropane 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Bromodichloromethane 1.745E-07 0.134 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 [<3],[<3],4.52,[<3],[<3] BDL Run 2 [<3],[<3],[<3],[<3],[<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] 1,4-Dioxane 1.366E-04 105.007 1.366E-04 107.084 1.216E-04 95.669 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 2841.41,2551.49,3822.14,3711.71,[<3] DLL Run 2 4381.59,2756.56,3104.15,2894.16,[<3] DLL 4217.52,1020.63,3856.55,2729.02,[<3] cis-1,3-Dichloropropene 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Toluene 3.798E-06 2.920 1.233E-05 9.663 1.769E-06 1.392 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 25.17,39.41,44.54,247.44,[<3] DLL Run 2 540.37,316.17,43.62,282.45,[<3] DLL Run 3 51.93,57.75,42.8,16.55,[<3] 4-Methyl-2-pentanone (MIBK) 7.996E-07 0.615 2.156E-06 1.690 5.145E-07 0.405 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 40.98,18.65,10.07,[<3],[<3] DLL Run 2 145.47,43.38,12.54,[<3],[<3] DLL Run 3 23.62,[<3],17.41,[<3],[<3] 1-1,3-dichloropropene 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Tetrachloroethylene 1.584E-07 0.122 1.855E-07 0.145 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1 [<3],[<3],[<3],[<3],[<3] DLL Run 2 6.07,2.77,[<3],[<3],[<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] 1,1,2-Trichloroethane 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Dibromochloromethane 1.584E-07 0.122 1.570E-07 0.123 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1 [<3],[<3],[<3],[<3],[<3] DLL Run 2 [<3],2.25,[<3],3.85,[<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] 1,2-Dichloroethane 2.418E-07 0.186 1.967E-07 0.154 1.574E-07 0.124 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 [<3],[<3],[<3],10.89,[<3] DLL Run 2 [<3],[<3],6.92,[<3],[<3] DLL Run 3 [<3],[<3],[<3],3.31,[<3] 2-Hexanone 7.517E-06 5.780 5.735E-06 4.495 2.446E-06 1.924 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 189.19,60.09,210.97,248.42,[<3] DLL Run 2 202.81,200.96,88.6,56.16,[<3] DLL Run 3 69.32,66.12,56.29,43.13,[<3] Ethylbenzene 8.762E-07 0.674 1.804E-06 1.414 3.801E-07 0.299 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 10.71,16.75,14.8,37.7,[<3] DLL Run 2 81.95,41.91,13.03,33.59,[<3] DLL Run 3 12.55,1.32,13.26,6.83,[<3] Chlorobenzene 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] m/p-Xylene 1.584E-07 0.122 4.727E-07 0.370 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1 [<3],[<3],[<3],[<3],[<3] DLL Run 2 33.46,[<3],[<3],[<3],[<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] o-Xylene 6.807E-07 0.523 1.928E-06 1.511 3.712E-07 0.292 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 6.2,11.9,8.8,34.55,[<3] DLL Run 2 100.1,41.42,8.28,32.6,[<3] DLL Run 3 8.04,13.74,7.84,3.48,[<3] Styrene 1.593E-07 0.122 3.714E-07 0.291 1.726E-06 1.358 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 [<3],[<3],[<3],3.08,[<3] DLL Run 2 23.51,1.46,21.9,5.85,[<3] DLL Run 3 8.01,130.99,20.67,5.19,[<3] Tribromomethane 1.584E-07 0.122 1.691E-07 0.133 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1,1,2,2-Tetrachloroethane 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1-ethyl-4-methybenzene 1.584E-07 0.122 7.179E-07 0.563 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1 [<3],[<3],[<3],[<3],[<3] DLL Run 2 43.06,16.98,[<3],[<3],[<3] BDL Run 3 [<3],[<3],[<3],[<3],[<3] 1,3,5-trimethylbenzene 3.139E-07 0.241 5.974E-07 0.468 2.335E-07 0.184 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 3.71,3.43,4.51,15.07,[<3] DLL Run 2 26.26,11.26,5.75,11.19,[<3] DLL Run 3 5.99,4.86,5.35,3.51,[<3] 1,2,4-trimethlbenzene 4.621E-07 0.355 1.309E-06 1.026 1.502E-07 0.118 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 2.82,3.19,3.4,31.34,[<3] DLL Run 2 68.58,26.79,3.56,23.96,[<3] DLL Run 3 3.62,2.65,3.47,1.87,[<3] 1,3-Dichlorobenzene 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1,4-Difluorobenzene (IS) 1.584E-07 0.122 1.560E-07 0.122 1.543E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] Benzyl chloride 2.919E-06 2.244 3.777E-06 2.960 1.531E-05 12.041 U.S. EPA Method 0031 with SW -846 Method 8260B DLL Run 1 62.43,40.87,167.05,[<3],[<3] DLL Run 2 96.25,[<3],258.0,[<3],[<3] DLL Run 3 71.76,1222.28,151.18,40.34,[<3] 1,2-Dichlorobenzene 1.584E-07 0.122 1.560E-07 0.122 1.557E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1,1,2,3,4-hexachloro-1,3-butadiene 1.584E-07 0.122 1.560E-07 0.122 1.557E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3] 1,2,4-Trichlorobenzene 1.584E-07 0.122 1.560E-07 0.122 1.557E-07 0.121 U.S. EPA Method 0031 with SW -846 Method 8260B BDL Run 1, [<3],[<3],[<3],[<3],[<3] BDL Run 2, [<3],[<3],[<3],[<3],[<3] BDL Run 3, [<3],[<3],[<3],[<3],[<3]EIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Date of Testing 3/26/2010 3/26/2010 Steam Output (1000 lb/hr) 2060 2008 Total Heat Input (MMBtu/hr) 3765 3629 Basis (W et/Dry) Dry Dry Exhaust Steam % Moisture 6.34 4.91 Exhaust Flow Rate (acfm or dscfm) 1372494 1374789 Exhaust Temperature (deg C or deg F) 342 343

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 bitum inous 3765 3629

Compound (use drop down to define for as many rows as needed) Semi-Volatile Organic HAP Emission Rate Sample 1 (lb/MMBtu) Semi-Volatile Organic HAP Emission Rate Sample 1 (ug/dscm @ 7% O2) Naphthalene 5.474E-09 0.0042 2-Methylnaphthalene 1.446E-09 0.0011 Acenaphthylene 1.446E-09 0.0011 Acenaphthylene (CCC) 1.446E-09 0.0011 Fluorene 1.446E-09 0.0011 Phenanthrene 1.446E-09 0.0011 Anthracene 1.446E-09 0.0011 Fluoranthene 1.446E-09 0.0011 Pyrene 1.446E-09 0.0011 Benz(a)anthracene 1.446E-09 0.0011 Chrysene 1.446E-09 0.0011 Benzo(b)fluoranthene 1.446E-09 0.0011 Benzo(k)fluoranthene 1.446E-09 0.0011 Benzo(e)pyrene 1.446E-09 0.0011 Benzo(a)pyrene CCC 1.446E-09 0.0011 Perylene 1.446E-09 0.0011 Indeno(1,2,3-cd)pyrene 1.446E-09 0.0011 Dibenz(a,h)anthracene 1.446E-09 0.0011 Benzo(g,h,i)perylene 1.446E-09 0.0011 N-Nitrosodimethylam ine 1.116E-07 0.1238 Phenol 1.427E-07 0.1099 Aniline 1.003E-07 0.0772 Bis(2-chloroisopropyl) ether 1.139E-07 0.0877 2-Chlorophenol 9.021E-08 0.0694 1,3-Dichlorobenzene 8.067E-08 0.06211,4-Dichlorobenzene 7.633E-08 0.0588

Benzyl alcohol 1.012E-07 0.0779 1,2-Dichlorobenzene 8.067E-08 0.0621 2-Methylphenol 9.801E-08 0.0755 3/4-Methylphenol 8.529E-08 0.0657 N-Nitrosodi-n-propy lam ine 1.203E-07 0.0926 Hexachloroethane 9.136E-08 0.0703 Nitrobenzene 1.180E-07 0.0908 Isophorone 1.081E-07 0.0832 2,4-Dimethylphenol 1.052E-07 0.0810 2-Nitrophenol 9.686E-08 0.0746 Bis(2-chloroethoxy)methane 1.058E-07 0.0815 2,4-Dichlorophenol 9.425E-08 0.0726 1,2,4-Trichlorobenzene 8.934E-08 0.0688 4-Chloroaniline 1.226E-07 0.0944 Hexachlorobutadiene 8.818E-08 0.0679 4-Chloro-3-methy lphenol 9.570E-08 0.0737 1-Methylnaphthalene 8.876E-08 0.0683 Hexachlorocyclopentadiene 1.174E-06 0.9037 2,4,6-Trichlorophenol 1.067E-07 0.0821 2,4,5-Trichlorophenol 7.806E-08 0.0601 2-Chloronaphthalene 9.425E-08 0.0726 1,4-Dinitrobenzene 9.715E-08 0.0748 Dim ethyl phthalate 1.171E-07 0.0901 1,3-Dinitrobenzene 1.183E-07 0.0910 2,6-Dinitrotoluene 1.122E-07 0.0864 1,2-Dinitrobenzene 1.125E-07 0.0866 2,4-Dinitrophenol 7.315E-07 0.5631 4-Nitrophenol 8.356E-07 0.6433 2,4-Dinitrotoluene 1.162E-07 0.0895 Dibenzofuran 9.946E-08 0.0766 2,3,5,6-Tetrachlorophenol 1.099E-07 0.0846 2,3,4,6-Tetrachlorophenol 1.012E-07 0.0779 Diethyl phthalate 1.475E-07 0.1135 4-Chlorophenyl phenyl ether 1.090E-07 0.0839 4,6-Dinitro-2-methy lphenol 7.459E-07 0.5743 N-Nitrosodiphenylam ine 1.035E-07 0.0797 Azobenzene 1.434E-07 0.1104 4-Bromopheny l phenyl ether 9.686E-08 0.0746 Hexachlorobenzene 7.893E-08 0.0608 Pentachlorophenol 8.182E-08 0.0630 Carbazole 1.021E-07 0.0786 Di-n-butyl phthalate 1.501E-07 0.1155 Benzidine 3.296E-06 2.5374 Butyl benzyl phthalate 1.171E-07 0.0901 3,3'-Dimethoxy benzidine 1.558E-06 1.1997 Bis(2-ethylhexyl) phthalate 1.073E-07 0.0826 3,3'-Dichlorobenzidine 1.353E-06 1.0417 Di-n-octyl phthalate 9.310E-08 0.0717Sample 3 Unit of Measure Other Supporting Information 3/26/2010 2011 1000 lb/hr 3601 MMBtu/hr Dry N/A 4.86 % 1372135 acfm 343 deg F

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Me thod 3601 MMBtu/hr F-Factor

Semi-Volatile Organic HAP Emission Rate Sample 2 (lb/MMBtu) Semi-Volatile Organic HAP Emission Rate Sample 2 (ug/dscm @ 7% O2) Semi-Volatile Organic HAP Emission Rate Sample 3 (lb/MMBtu) 5.202E-09 0.0041 4.693E-09 1.418E-09 0.0011 1.454E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.426E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.418E-09 0.0011 1.413E-09 1.095E-07 0.1230 1.091E-07 1.407E-07 0.1104 1.342E-07 9.841E-08 0.0772 9.806E-08 1.117E-07 0.0877 1.113E-07 8.849E-08 0.0694 8.817E-08 7.913E-08 0.0621 7.885E-087.487E-08 0.0588 7.461E-08 9.927E-08 0.0779 9.891E-08 7.913E-08 0.0621 7.885E-08 9.615E-08 0.0755 9.580E-08 8.367E-08 0.0657 8.337E-08 1.180E-07 0.0926 1.176E-07 8.962E-08 0.0703 8.930E-08 1.157E-07 0.0908 1.153E-07 1.061E-07 0.0832 1.057E-07 1.032E-07 0.0810 1.029E-07 9.501E-08 0.0746 9.467E-08 1.038E-07 0.0815 1.034E-07 9.246E-08 0.0726 9.213E-08 8.764E-08 0.0688 8.733E-08 1.203E-07 0.0944 1.198E-07 8.650E-08 0.0679 8.619E-08 9.388E-08 0.0737 9.354E-08 8.707E-08 0.0683 8.676E-08 1.151E-06 0.9037 1.147E-06 1.047E-07 0.0821 1.043E-07 7.658E-08 0.0601 7.630E-08 9.246E-08 0.0726 9.213E-08 9.529E-08 0.0748 9.496E-08 1.149E-07 0.0901 1.145E-07 1.160E-07 0.0910 1.156E-07 1.100E-07 0.0864 1.097E-07 1.103E-07 0.0866 1.099E-07 7.175E-07 0.5631 7.150E-07 8.196E-07 0.6433 8.167E-07 1.140E-07 0.0895 1.136E-07 9.756E-08 0.0766 9.722E-08 1.078E-07 0.0846 1.074E-07 9.927E-08 0.0779 9.891E-08 1.446E-07 0.1135 1.441E-07 1.069E-07 0.0839 1.065E-07 7.317E-07 0.5743 7.291E-07 1.015E-07 0.0797 1.012E-07 1.407E-07 0.1104 1.402E-07 9.501E-08 0.0746 9.467E-08 7.743E-08 0.0608 7.715E-08 8.026E-08 0.0630 7.998E-08 1.001E-07 0.0786 9.976E-08 1.472E-07 0.1155 1.467E-07 3.233E-06 2.5374 3.222E-06 1.149E-07 0.0901 1.145E-07 1.529E-06 1.1997 1.523E-06 2.573E-07 0.2020 1.048E-07 1.327E-06 1.0417 1.323E-06 9.132E-08 0.0717 9.100E-08Other Supporting Information

Plant Data

Semi-Volatile Organic HAP Emission Rate Sample 3 (ug/dscm @ 7% O2) Test Method Used

0.0037 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0011 U.S. EPA Method 0010 with SW -846 Method 8270D 0.1222 U.S. EPA Method 0010 with SW -846 Method 8270D 0.1057 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0772 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0877 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0694 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0621 U.S. EPA Method 0010 with SW -846 Method 8270D0.0588 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0779 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0621 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0755 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0657 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0926 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0703 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0908 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0832 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0810 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0746 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0815 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0726 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0688 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0944 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0679 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0737 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0683 U.S. EPA Method 0010 with SW -846 Method 8270D 0.9037 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0821 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0601 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0726 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0748 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0901 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0910 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0864 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0866 U.S. EPA Method 0010 with SW -846 Method 8270D 0.5631 U.S. EPA Method 0010 with SW -846 Method 8270D 0.6433 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0895 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0766 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0846 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0779 U.S. EPA Method 0010 with SW -846 Method 8270D 0.1135 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0839 U.S. EPA Method 0010 with SW -846 Method 8270D 0.5743 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0797 U.S. EPA Method 0010 with SW -846 Method 8270D 0.1104 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0746 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0608 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0630 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0786 U.S. EPA Method 0010 with SW -846 Method 8270D 0.1155 U.S. EPA Method 0010 with SW -846 Method 8270D 2.5374 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0901 U.S. EPA Method 0010 with SW -846 Method 8270D 1.1997 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0826 U.S. EPA Method 0010 with SW -846 Method 8270D 1.0417 U.S. EPA Method 0010 with SW -846 Method 8270D 0.0717 U.S. EPA Method 0010 with SW -846 Method 8270DOther Supporting Information

DLL Run 1, FH 1.55,BH .937,Cond [.050] DLL Run 2, FH .079,BH .995,Cond [.050] DLL Run 3, FH .082,BH .94,Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] DLL Run 3, FH [.050],BH .054,Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] DLL Run 3, FH [.050],BH .051,Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [3.86],BH [3.86],Cond [3.86] BDL Run 2, FH [3.86],BH [3.86],Cond [3.86] BDL Run 3, FH [3.86],BH [3.86],Cond [3.86] DLL Run 1, FH [3.25],BH 8.31,Cond [3.25] DLL Run 2, FH [3.25],BH 8.38,Cond [3.25] DLL Run 3, FH [3.25],BH 7.75,Cond [3.25] BDL Run 1, FH [3.47],BH [3.47],Cond [3.47] BDL Run 2, FH [3.47],BH [3.47],Cond [3.47] BDL Run 3, FH [3.47],BH [3.47],Cond [3.47] BDL Run 1, FH [3.94],BH [3.94],Cond [3.94] BDL Run 2, FH [3.94],BH [3.94],Cond [3.94] BDL Run 3, FH [3.94],BH [3.94],Cond [3.94] BDL Run 1, FH [3.12],BH [3.12],Cond [3.12] BDL Run 2, FH [3.12],BH [3.12],Cond [3.12] BDL Run 3, FH [3.12],BH [3.12],Cond [3.12] BDL Run 1, FH [2.79],BH [2.79],Cond [2.79] BDL Run 2, FH [2.79],BH [2.79],Cond [2.79] BDL Run 3, FH [2.79],BH [2.79],Cond [2.79]BDL Run 1, FH [2.64],BH [2.64],Cond [2.64] BDL Run 2, FH [2.64],BH [2.64],Cond [2.64] BDL Run 3, FH [2.64],BH [2.64],Cond [2.64]

BDL Run 1, FH [3.50],BH [3.50],Cond [3.50] BDL Run 2, FH [3.50],BH [3.50],Cond [3.50] BDL Run 3, FH [3.50],BH [3.50],Cond [3.50] BDL Run 1, FH [2.79],BH [2.79],Cond [2.79] BDL Run 2, FH [2.79],BH [2.79],Cond [2.79] BDL Run 3, FH [2.79],BH [2.79],Cond [2.79] BDL Run 1, FH [3.39],BH [3.39],Cond [3.39] BDL Run 2, FH [3.39],BH [3.39],Cond [3.39] BDL Run 3, FH [3.39],BH [3.39],Cond [3.39] BDL Run 1, FH [2.95],BH [2.95],Cond [2.95] BDL Run 2, FH [2.95],BH [2.95],Cond [2.95] BDL Run 3, FH [2.95],BH [2.95],Cond [2.95] BDL Run 1, FH [4.16],BH [4.16],Cond [4.16] BDL Run 2, FH [4.16],BH [4.16],Cond [4.16] BDL Run 3, FH [4.16],BH [4.16],Cond [4.16] BDL Run 1, FH [3.16],BH [3.16],Cond [3.16] BDL Run 2, FH [3.16],BH [3.16],Cond [3.16] BDL Run 3, FH [3.16],BH [3.16],Cond [3.16] BDL Run 1, FH [4.08],BH [4.08],Cond [4.08] BDL Run 2, FH [4.08],BH [4.08],Cond [4.08] BDL Run 3, FH [4.08],BH [4.08],Cond [4.08] BDL Run 1, FH [3.74],BH [3.74],Cond [3.74] BDL Run 2, FH [3.74],BH [3.74],Cond [3.74] BDL Run 3, FH [3.74],BH [3.74],Cond [3.74] BDL Run 1, FH [3.64],BH [3.64],Cond [3.64] BDL Run 2, FH [3.64],BH [3.64],Cond [3.64] BDL Run 3, FH [3.64],BH [3.64],Cond [3.64] BDL Run 1, FH [3.35],BH [3.35],Cond [3.35] BDL Run 2, FH [3.35],BH [3.35],Cond [3.35] BDL Run 3, FH [3.35],BH [3.35],Cond [3.35] BDL Run 1, FH [3.66],BH [3.66],Cond [3.66] BDL Run 2, FH [3.66],BH [3.66],Cond [3.66] BDL Run 3, FH [3.66],BH [3.66],Cond [3.66] BDL Run 1, FH [3.26],BH [3.26],Cond [3.26] BDL Run 2, FH [3.26],BH [3.26],Cond [3.26] BDL Run 3, FH [3.26],BH [3.26],Cond [3.26] BDL Run 1, FH [3.09],BH [3.09],Cond [3.09] BDL Run 2, FH [3.09],BH [3.09],Cond [3.09] BDL Run 3, FH [3.09],BH [3.09],Cond [3.09] BDL Run 1, FH [4.24],BH [4.24],Cond [4.24] BDL Run 2, FH [4.24],BH [4.24],Cond [4.24] BDL Run 3, FH [4.24],BH [4.24],Cond [4.24] BDL Run 1, FH [3.05],BH [3.05],Cond [3.05] BDL Run 2, FH [3.05],BH [3.05],Cond [3.05] BDL Run 3, FH [3.05],BH [3.05],Cond [3.05] BDL Run 1, FH [3.31],BH [3.31],Cond [3.31] BDL Run 2, FH [3.31],BH [3.31],Cond [3.31] BDL Run 3, FH [3.31],BH [3.31],Cond [3.31] BDL Run 1, FH [3.07],BH [3.07],Cond [3.07] BDL Run 2, FH [3.07],BH [3.07],Cond [3.07] BDL Run 3, FH [3.07],BH [3.07],Cond [3.07] BDL Run 1, FH [40.60],BH [40.60],Cond [40.60] BDL Run 2, FH [40.60],BH [40.60],Cond [40.60] BDL Run 3, FH [40.60],BH [40.60],Cond [40.60] BDL Run 1, FH [3.69],BH [3.69],Cond [3.69] BDL Run 2, FH [3.69],BH [3.69],Cond [3.69] BDL Run 3, FH [3.69],BH [3.69],Cond [3.69] BDL Run 1, FH [2.70],BH [2.70],Cond [2.70] BDL Run 2, FH [2.70],BH [2.70],Cond [2.70] BDL Run 3, FH [2.70],BH [2.70],Cond [2.70] BDL Run 1, FH [3.26],BH [3.26],Cond [3.26] BDL Run 2, FH [3.26],BH [3.26],Cond [3.26] BDL Run 3, FH [3.26],BH [3.26],Cond [3.26] BDL Run 1, FH [3.36],BH [3.36],Cond [3.36] BDL Run 2, FH [3.36],BH [3.36],Cond [3.36] BDL Run 3, FH [3.36],BH [3.36],Cond [3.36] BDL Run 1, FH [4.05],BH [4.05],Cond [4.05] BDL Run 2, FH [4.05],BH [4.05],Cond [4.05] BDL Run 3, FH [4.05],BH [4.05],Cond [4.05] BDL Run 1, FH [4.09],BH [4.09],Cond [4.09] BDL Run 2, FH [4.09],BH [4.09],Cond [4.09] BDL Run 3, FH [4.09],BH [4.09],Cond [4.09] BDL Run 1, FH [3.88],BH [3.88],Cond [3.88] BDL Run 2, FH [3.88],BH [3.88],Cond [3.88] BDL Run 3, FH [3.88],BH [3.88],Cond [3.88] BDL Run 1, FH [3.89],BH [3.89],Cond [3.89] BDL Run 2, FH [3.89],BH [3.89],Cond [3.89] BDL Run 3, FH [3.89],BH [3.89],Cond [3.89] BDL Run 1, FH [25.30],BH [25.30],Cond [25.30] BDL Run 2, FH [25.30],BH [25.30],Cond [25.30] BDL Run 3, FH [25.30],BH [25.30],Cond [25.30] BDL Run 1, FH [28.90],BH [28.90],Cond [28.90] BDL Run 2, FH [28.90],BH [28.90],Cond [28.90] BDL Run 3, FH [28.90],BH [28.90],Cond [28.90] BDL Run 1, FH [4.02],BH [4.02],Cond [4.02] BDL Run 2, FH [4.02],BH [4.02],Cond [4.02] BDL Run 3, FH [4.02],BH [4.02],Cond [4.02] BDL Run 1, FH [3.44],BH [3.44],Cond [3.44] BDL Run 2, FH [3.44],BH [3.44],Cond [3.44] BDL Run 3, FH [3.44],BH [3.44],Cond [3.44] BDL Run 1, FH [3.80],BH [3.80],Cond [3.80] BDL Run 2, FH [3.80],BH [3.80],Cond [3.80] BDL Run 3, FH [3.80],BH [3.80],Cond [3.80] BDL Run 1, FH [3.50],BH [3.50],Cond [3.50] BDL Run 2, FH [3.50],BH [3.50],Cond [3.50] BDL Run 3, FH [3.50],BH [3.50],Cond [3.50] BDL Run 1, FH [5.10],BH [5.10],Cond [5.10] BDL Run 2, FH [5.10],BH [5.10],Cond [5.10] BDL Run 3, FH [5.10],BH [5.10],Cond [5.10] BDL Run 1, FH [3.77],BH [3.77],Cond [3.77] BDL Run 2, FH [3.77],BH [3.77],Cond [3.77] BDL Run 3, FH [3.77],BH [3.77],Cond [3.77] BDL Run 1, FH [25.80],BH [25.80],Cond [25.80] BDL Run 2, FH [25.80],BH [25.80],Cond [25.80] BDL Run 3, FH [25.80],BH [25.80],Cond [25.80] BDL Run 1, FH [3.58],BH [3.58],Cond [3.58] BDL Run 2, FH [3.58],BH [3.58],Cond [3.58] BDL Run 3, FH [3.58],BH [3.58],Cond [3.58] BDL Run 1, FH [4.96],BH [4.96],Cond [4.96] BDL Run 2, FH [4.96],BH [4.96],Cond [4.96] BDL Run 3, FH [4.96],BH [4.96],Cond [4.96] BDL Run 1, FH [3.35],BH [3.35],Cond [3.35] BDL Run 2, FH [3.35],BH [3.35],Cond [3.35] BDL Run 3, FH [3.35],BH [3.35],Cond [3.35] BDL Run 1, FH [2.73],BH [2.73],Cond [2.73] BDL Run 2, FH [2.73],BH [2.73],Cond [2.73] BDL Run 3, FH [2.73],BH [2.73],Cond [2.73] BDL Run 1, FH [2.83],BH [2.83],Cond [2.83] BDL Run 2, FH [2.83],BH [2.83],Cond [2.83] BDL Run 3, FH [2.83],BH [2.83],Cond [2.83] BDL Run 1, FH [3.53],BH [3.53],Cond [3.53] BDL Run 2, FH [3.53],BH [3.53],Cond [3.53] BDL Run 3, FH [3.53],BH [3.53],Cond [3.53] BDL Run 1, FH [5.19],BH [5.19],Cond [5.19] BDL Run 2, FH [5.19],BH [5.19],Cond [5.19] BDL Run 3, FH [5.19],BH [5.19],Cond [5.19] BDL Run 1, FH [114.0],BH [114.0],Cond [114.0] BDL Run 2, FH [114.0],BH [114.0],Cond [114.0] BDL Run 3, FH [114.0],BH [114.0],Cond [114.0] BDL Run 1, FH [4.05],BH [4.05],Cond [4.05] BDL Run 2, FH [4.05],BH [4.05],Cond [4.05] BDL Run 3, FH [4.05],BH [4.05],Cond [4.05] BDL Run 1, FH [53.9],BH [53.9],Cond [53.9] BDL Run 2, FH [53.9],BH [53.9],Cond [53.9] BDL Run 3, FH [53.9],BH [53.9],Cond [53.9] BDL Run 1, FH [8.71],BH [8.71],Cond [8.71] DLL Run 2, FH [8.71],BH 24.8,Cond [8.71] BDL Run 3, FH [8.71],BH [8.71],Cond [8.71] BDL Run 1, FH [46.8],BH [46.8],Cond [46.8] BDL Run 2, FH [46.8],BH [46.8],Cond [46.8] BDL Run 3, FH [46.8],BH [46.8],Cond [46.8] BDL Run 1, FH [3.22],BH [3.22],Cond [3.22] BDL Run 2, FH [3.22],BH [3.22],Cond [3.22] BDL Run 3, FH [3.22],BH [3.22],Cond [3.22]DLL Run 1, FH 1.55,BH .937,Cond [.050] DLL Run 2, FH .079,BH .995,Cond [.050] DLL Run 3, FH .082,BH .94,Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] DLL Run 3, FH [.050],BH .054,Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] DLL Run 3, FH [.050],BH .051,Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [.050],BH [.050],Cond [.050] BDL Run 2, FH [.050],BH [.050],Cond [.050] BDL Run 3, FH [.050],BH [.050],Cond [.050] BDL Run 1, FH [3.86],BH [3.86],Cond [3.86] BDL Run 2, FH [3.86],BH [3.86],Cond [3.86] BDL Run 3, FH [3.86],BH [3.86],Cond [3.86] DLL Run 1, FH [3.25],BH 8.31,Cond [3.25] DLL Run 2, FH [3.25],BH 8.38,Cond [3.25] DLL Run 3, FH [3.25],BH 7.75,Cond [3.25] BDL Run 1, FH [3.47],BH [3.47],Cond [3.47] BDL Run 2, FH [3.47],BH [3.47],Cond [3.47] BDL Run 3, FH [3.47],BH [3.47],Cond [3.47] BDL Run 1, FH [3.94],BH [3.94],Cond [3.94] BDL Run 2, FH [3.94],BH [3.94],Cond [3.94] BDL Run 3, FH [3.94],BH [3.94],Cond [3.94] BDL Run 1, FH [3.12],BH [3.12],Cond [3.12] BDL Run 2, FH [3.12],BH [3.12],Cond [3.12] BDL Run 3, FH [3.12],BH [3.12],Cond [3.12] BDL Run 1, FH [2.79],BH [2.79],Cond [2.79] BDL Run 2, FH [2.79],BH [2.79],Cond [2.79] BDL Run 3, FH [2.79],BH [2.79],Cond [2.79]BDL Run 1, FH [2.64],BH [2.64],Cond [2.64] BDL Run 2, FH [2.64],BH [2.64],Cond [2.64] BDL Run 3, FH [2.64],BH [2.64],Cond [2.64] BDL Run 1, FH [3.50],BH [3.50],Cond [3.50] BDL Run 2, FH [3.50],BH [3.50],Cond [3.50] BDL Run 3, FH [3.50],BH [3.50],Cond [3.50] BDL Run 1, FH [2.79],BH [2.79],Cond [2.79] BDL Run 2, FH [2.79],BH [2.79],Cond [2.79] BDL Run 3, FH [2.79],BH [2.79],Cond [2.79] BDL Run 1, FH [3.39],BH [3.39],Cond [3.39] BDL Run 2, FH [3.39],BH [3.39],Cond [3.39] BDL Run 3, FH [3.39],BH [3.39],Cond [3.39] BDL Run 1, FH [2.95],BH [2.95],Cond [2.95] BDL Run 2, FH [2.95],BH [2.95],Cond [2.95] BDL Run 3, FH [2.95],BH [2.95],Cond [2.95] BDL Run 1, FH [4.16],BH [4.16],Cond [4.16] BDL Run 2, FH [4.16],BH [4.16],Cond [4.16] BDL Run 3, FH [4.16],BH [4.16],Cond [4.16] BDL Run 1, FH [3.16],BH [3.16],Cond [3.16] BDL Run 2, FH [3.16],BH [3.16],Cond [3.16] BDL Run 3, FH [3.16],BH [3.16],Cond [3.16] BDL Run 1, FH [4.08],BH [4.08],Cond [4.08] BDL Run 2, FH [4.08],BH [4.08],Cond [4.08] BDL Run 3, FH [4.08],BH [4.08],Cond [4.08] BDL Run 1, FH [3.74],BH [3.74],Cond [3.74] BDL Run 2, FH [3.74],BH [3.74],Cond [3.74] BDL Run 3, FH [3.74],BH [3.74],Cond [3.74] BDL Run 1, FH [3.64],BH [3.64],Cond [3.64] BDL Run 2, FH [3.64],BH [3.64],Cond [3.64] BDL Run 3, FH [3.64],BH [3.64],Cond [3.64] BDL Run 1, FH [3.35],BH [3.35],Cond [3.35] BDL Run 2, FH [3.35],BH [3.35],Cond [3.35] BDL Run 3, FH [3.35],BH [3.35],Cond [3.35] BDL Run 1, FH [3.66],BH [3.66],Cond [3.66] BDL Run 2, FH [3.66],BH [3.66],Cond [3.66] BDL Run 3, FH [3.66],BH [3.66],Cond [3.66] BDL Run 1, FH [3.26],BH [3.26],Cond [3.26] BDL Run 2, FH [3.26],BH [3.26],Cond [3.26] BDL Run 3, FH [3.26],BH [3.26],Cond [3.26] BDL Run 1, FH [3.09],BH [3.09],Cond [3.09] BDL Run 2, FH [3.09],BH [3.09],Cond [3.09] BDL Run 3, FH [3.09],BH [3.09],Cond [3.09] BDL Run 1, FH [4.24],BH [4.24],Cond [4.24] BDL Run 2, FH [4.24],BH [4.24],Cond [4.24] BDL Run 3, FH [4.24],BH [4.24],Cond [4.24] BDL Run 1, FH [3.05],BH [3.05],Cond [3.05] BDL Run 2, FH [3.05],BH [3.05],Cond [3.05] BDL Run 3, FH [3.05],BH [3.05],Cond [3.05] BDL Run 1, FH [3.31],BH [3.31],Cond [3.31] BDL Run 2, FH [3.31],BH [3.31],Cond [3.31] BDL Run 3, FH [3.31],BH [3.31],Cond [3.31] BDL Run 1, FH [3.07],BH [3.07],Cond [3.07] BDL Run 2, FH [3.07],BH [3.07],Cond [3.07] BDL Run 3, FH [3.07],BH [3.07],Cond [3.07] BDL Run 1, FH [40.60],BH [40.60],Cond [40.60] BDL Run 2, FH [40.60],BH [40.60],Cond [40.60] BDL Run 3, FH [40.60],BH [40.60],Cond [40.60] BDL Run 1, FH [3.69],BH [3.69],Cond [3.69] BDL Run 2, FH [3.69],BH [3.69],Cond [3.69] BDL Run 3, FH [3.69],BH [3.69],Cond [3.69] BDL Run 1, FH [2.70],BH [2.70],Cond [2.70] BDL Run 2, FH [2.70],BH [2.70],Cond [2.70] BDL Run 3, FH [2.70],BH [2.70],Cond [2.70] BDL Run 1, FH [3.26],BH [3.26],Cond [3.26] BDL Run 2, FH [3.26],BH [3.26],Cond [3.26] BDL Run 3, FH [3.26],BH [3.26],Cond [3.26] BDL Run 1, FH [3.36],BH [3.36],Cond [3.36] BDL Run 2, FH [3.36],BH [3.36],Cond [3.36] BDL Run 3, FH [3.36],BH [3.36],Cond [3.36] BDL Run 1, FH [4.05],BH [4.05],Cond [4.05] BDL Run 2, FH [4.05],BH [4.05],Cond [4.05] BDL Run 3, FH [4.05],BH [4.05],Cond [4.05] BDL Run 1, FH [4.09],BH [4.09],Cond [4.09] BDL Run 2, FH [4.09],BH [4.09],Cond [4.09] BDL Run 3, FH [4.09],BH [4.09],Cond [4.09] BDL Run 1, FH [3.88],BH [3.88],Cond [3.88] BDL Run 2, FH [3.88],BH [3.88],Cond [3.88] BDL Run 3, FH [3.88],BH [3.88],Cond [3.88] BDL Run 1, FH [3.89],BH [3.89],Cond [3.89] BDL Run 2, FH [3.89],BH [3.89],Cond [3.89] BDL Run 3, FH [3.89],BH [3.89],Cond [3.89] BDL Run 1, FH [25.30],BH [25.30],Cond [25.30] BDL Run 2, FH [25.30],BH [25.30],Cond [25.30] BDL Run 3, FH [25.30],BH [25.30],Cond [25.30] BDL Run 1, FH [28.90],BH [28.90],Cond [28.90] BDL Run 2, FH [28.90],BH [28.90],Cond [28.90] BDL Run 3, FH [28.90],BH [28.90],Cond [28.90] BDL Run 1, FH [4.02],BH [4.02],Cond [4.02] BDL Run 2, FH [4.02],BH [4.02],Cond [4.02] BDL Run 3, FH [4.02],BH [4.02],Cond [4.02] BDL Run 1, FH [3.44],BH [3.44],Cond [3.44] BDL Run 2, FH [3.44],BH [3.44],Cond [3.44] BDL Run 3, FH [3.44],BH [3.44],Cond [3.44] BDL Run 1, FH [3.80],BH [3.80],Cond [3.80] BDL Run 2, FH [3.80],BH [3.80],Cond [3.80] BDL Run 3, FH [3.80],BH [3.80],Cond [3.80] BDL Run 1, FH [3.50],BH [3.50],Cond [3.50] BDL Run 2, FH [3.50],BH [3.50],Cond [3.50] BDL Run 3, FH [3.50],BH [3.50],Cond [3.50] BDL Run 1, FH [5.10],BH [5.10],Cond [5.10] BDL Run 2, FH [5.10],BH [5.10],Cond [5.10] BDL Run 3, FH [5.10],BH [5.10],Cond [5.10] BDL Run 1, FH [3.77],BH [3.77],Cond [3.77] BDL Run 2, FH [3.77],BH [3.77],Cond [3.77] BDL Run 3, FH [3.77],BH [3.77],Cond [3.77] BDL Run 1, FH [25.80],BH [25.80],Cond [25.80] BDL Run 2, FH [25.80],BH [25.80],Cond [25.80] BDL Run 3, FH [25.80],BH [25.80],Cond [25.80] BDL Run 1, FH [3.58],BH [3.58],Cond [3.58] BDL Run 2, FH [3.58],BH [3.58],Cond [3.58] BDL Run 3, FH [3.58],BH [3.58],Cond [3.58] BDL Run 1, FH [4.96],BH [4.96],Cond [4.96] BDL Run 2, FH [4.96],BH [4.96],Cond [4.96] BDL Run 3, FH [4.96],BH [4.96],Cond [4.96] BDL Run 1, FH [3.35],BH [3.35],Cond [3.35] BDL Run 2, FH [3.35],BH [3.35],Cond [3.35] BDL Run 3, FH [3.35],BH [3.35],Cond [3.35] BDL Run 1, FH [2.73],BH [2.73],Cond [2.73] BDL Run 2, FH [2.73],BH [2.73],Cond [2.73] BDL Run 3, FH [2.73],BH [2.73],Cond [2.73] BDL Run 1, FH [2.83],BH [2.83],Cond [2.83] BDL Run 2, FH [2.83],BH [2.83],Cond [2.83] BDL Run 3, FH [2.83],BH [2.83],Cond [2.83] BDL Run 1, FH [3.53],BH [3.53],Cond [3.53] BDL Run 2, FH [3.53],BH [3.53],Cond [3.53] BDL Run 3, FH [3.53],BH [3.53],Cond [3.53] BDL Run 1, FH [5.19],BH [5.19],Cond [5.19] BDL Run 2, FH [5.19],BH [5.19],Cond [5.19] BDL Run 3, FH [5.19],BH [5.19],Cond [5.19] BDL Run 1, FH [114.0],BH [114.0],Cond [114.0] BDL Run 2, FH [114.0],BH [114.0],Cond [114.0] BDL Run 3, FH [114.0],BH [114.0],Cond [114.0] BDL Run 1, FH [4.05],BH [4.05],Cond [4.05] BDL Run 2, FH [4.05],BH [4.05],Cond [4.05] BDL Run 3, FH [4.05],BH [4.05],Cond [4.05] BDL Run 1, FH [53.9],BH [53.9],Cond [53.9] BDL Run 2, FH [53.9],BH [53.9],Cond [53.9] BDL Run 3, FH [53.9],BH [53.9],Cond [53.9] BDL Run 1, FH [8.71],BH [8.71],Cond [8.71] DLL Run 2, FH [8.71],BH 24.8,Cond [8.71] BDL Run 3, FH [8.71],BH [8.71],Cond [8.71] BDL Run 1, FH [46.8],BH [46.8],Cond [46.8] BDL Run 2, FH [46.8],BH [46.8],Cond [46.8] BDL Run 3, FH [46.8],BH [46.8],Cond [46.8] BDL Run 1, FH [3.22],BH [3.22],Cond [3.22] BDL Run 2, FH [3.22],BH [3.22],Cond [3.22] BDL Run 3, FH [3.22],BH [3.22],Cond [3.22]EIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Sample 3 Date of Testing 3/24/2010 3/25/2010 3/25/2010 Steam Output (1000 lb/hr) 2009.764 2006.384 2013.48 Total Heat Input (MMBtu/hr) 3585.775 3515.212 3487.327 Basis (W et/Dry) Dry Dry Dry Exhaust Steam % Moisture 11.12 11.07 10.98 Exhaust Flow Rate (acfm or dscfm) 1,381,510 1,366,012 1,376,386 Exhaust Temperature (deg C or deg F) 344 334 343

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2 Fuel Input Rate Sample 3 bitum inous 464 485 480

Emission Test Results Hydrogen Cyanide Emission Rate Sample 1 (lb/MMBtu) Hydrogen Cyanide

Emission Rate Sample 2 (lb/MMBtu) Hydrogen Cyanide

Emission Rate Sample 3 (lb/MMBtu) [<1.56E-05] [<3.61E-05] [<3.57E-05]Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A % acfm deg F

Unit of Measure Fuel Flow Me asurement Me thod MMBtu/hr F-Factor

Test Method Used (ex. U.S. EPA

Conditional Test Method 033) Other Supporting Information U.S. EPA Conditional Test Method 033 (CTM-033) BDL Run 1, [<1.56E-05], BDL Run 2, [<3.61E-05], BDL Run 3, [<3.57E-05] pH Run 1@15 min 11.5, @30 min 14.0, @ 45 min 13.5, @ 60 min 13.0 pH Run 2@15 min 14.0, @30 min 14.0, @ 45 min 14.0, @ 60 min 14.0 pH Run 3@15 min 11.4, @30 min 14.0, @ 45 min 12.4, @ 60 min 11.4 The HCN was sampled using CTM 033 with 6 normal NaOH and an additional impinger for one hour per the clarification given by the USEPA in FAQ Number 10. http://www.epa.gov/ttn/emc/ctm/ctm-033.pdfOther Supporting Information

Plant Data

BDL Run 1, [<1.56E-05], BDL Run 2, [<3.61E-05], BDL Run 3, [<3.57E-05] pH Run 1@15 min 11.5, @30 min 14.0, @ 45 min 13.5, @ 60 min 13.0 pH Run 2@15 min 14.0, @30 min 14.0, @ 45 min 14.0, @ 60 min 14.0 pH Run 3@15 min 11.4, @30 min 14.0, @ 45 min 12.4, @ 60 min 11.4 The HCN was sampled using CTM 033 with 6 normal NaOH and an additional impinger for one hour per the clarification given by the USEPA in FAQ Number 10. http://www.epa.gov/ttn/emc/ctm/ctm-033.pdfEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Constituent Consitutent Emission Rate Sample 1 (%)
O 2 CO 2Sample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Me asurement Method Other Supporting Information

Consitutent Emission Rate

Sample 2 (%) Consitutent Emission Rate Sample 3 (%) Test Method Used

(ex. U.S. EPA

Method 3B) Other Supporting InformationEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Constituent Nitrogen Oxides Emission Rate Sample 1 (lb/MMBtu) NO NO 2Sample 3 Unit of Measure Other Supporting Information

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure Fuel Flow Measurement Method

Nitrogen Oxides Emission Rate

Sample 1 (ppmvd @ 7% O2) Nitrogen Oxides Emission Rate Sample 2 (lb/MMBtu) Nitrogen Oxides Emission Rate Sample 2 (ppmvd @ 7% O2)Other Supporting Information

Nitrogen Oxides Emission Rate

Sample 3 (lb/MMBtu) Nitrogen Oxides Emission Rate Sample 3 (ppmvd @ 7% O2) Test Method Used (ex. U.S. EPA

Method 7)Other Supporting

InformationEIA

Facility Code Facility Name Boiler ID 628 Crystal River Unit 1

Parameter Sample 1 Sample 2 Date of Testing Steam Output (1000 lb/hr) Total Heat Input (MMBtu/hr) Basis (W et/Dry) Exhaust Steam % Moisture Exhaust Flow Rate (acfm or dscfm) Exhaust Temperature (deg C or deg F)

Fuel Type Selection Fuel Input Rate Sample 1 Fuel Input Rate Sample 2

Emission Test Results Constituent Constituent Emission Rate Sample 1 (mg solids/liter) Total Dissolved Solids (TDS) Total Suspended Solids (TSS)Sample 3 Unit of Measure

1000 lb/hr MMBtu/hr N/A %

Fuel Input Rate Sample 3 Unit of Measure

Constituent Emission Rate

Sample 2 (mg solids/liter) Constituent Emission Rate Sample 3 (mg solids/liter)Other Supporting Information

Fuel Flow Measurement Method

Test Method Used (ex. Standard Test Method for Filterable and Nonfilterable Matter in Water ASTM D5907)Other Supporting

Information

Other Supporting InformationFuel

anthracite bitum inous subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C)

sy nfuel petroleum coke other

Relative to Control Device Upstream Downstream

Fuel Input Units of Measure MMBtu/hr standard cubic feet per minute (scfm)

gallon/m inute lb/hour ton/day

Exhaust Flow Rate Units of Measure acfm dscfm

Exhaust Temperature Units of Measure deg C deg F

Test Method Used for Fuel Input Rate

F-Factor gas fuel meter boiler efficiency

calculation Other

CO Test Method U.S. EPA Method 10A U.S. EPA Method 10BFormaldehyde Test Method

U.S. EPA Method 320

CH4 Test Method U.S. EPA Method 18 U.S. EPA Method 320

SO2 Test Method U.S. EPA Method 6

Hg Test Method U.S. EPA Method 30B

Speciated Volatile Organic HAP M ethod

U.S. EPA Method 0031 with SW -846 Method 8260B

Speciated Semi-Volatile Organic HAP M ethod U.S. EPA Method 0010 with SW -846 Method 8270D

HCN Test Method U.S. EPA Conditional Test Method 033 (CTM-033)

O2/CO2 Test Method U.S. EPA Method 3B

NOX Test Method U.S. EPA Method 7 U.S. EPA Method 7A U.S. EPA Method 7B U.S. EPA Method 7C U.S. EPA Method 7D

TDS/TSS Test Method Standard Test Method for Filterable and Nonfilterable Matter in W ater ASTM D5907 Standard Methods of the Examination of W ater and W astewater Method 2540B

Control Configuration

### Listed (by boiler) in Question 16 (page 17) of the questionnaire

Listed (by boiler) in the Configuration Order Section of the Facility Unit Configurations Section of the Electronic ICR

Hg Ontario Hydro Test Method ASTM Method D6784Constituent CAS Acetone 67-64-1 Acetonitrile 75-05-8 Acrolein (Propenal) 107-02-8 Acrylonitrile 107-13-1 Allyl alcohol 107-18-6 Allyl chloride 107-05-1 Azobenzene Benzene 71-43-2 Benzyl chloride 100-44-7 Bis(2-chloroethyl)sulfide 505-60-2 Bromoacetone 598-31-2 Bromochloromethane 74-97-5 Bromodichloromethane 75-27-4 4-Bromofluorobenzene (surr) 460-00-4 Bromoform 75-25-2 Bromomethane 74-83-9 1,3-Butadiene 106-99-0 n-Butanol 71-36-3 2-Butanone (MEK) 78-93-3 t-Butyl alcohol 75-65-0 Carbazole Carbon disulfide 75-15-0 Carbon tetrachloride 56-23-5 Chloral hydrate 302-17-0 1,2-Chloro-1,1,2,2-Tetrafluoroethane 76-14-2 Chlorobenzene 108-90-7 Chlorobenzene-d (IS) Chlorodibromomethane 124-48-1 Chloroethane 75-00-3 2-Chloroethanol 107-07-3 2-Chloroethyl vinyl ether 110-75-8 Chloroform 67-66-3 Chloromethane 74-87-3 Chloroprene 126-99-8 3-Chloropropionitrile 542-76-7 Crotonaldehyde 4170-30-3 Cyclohexane 110-82-7 1,2-Dibromo-3-chloropropane 96-12-8 1,2-Dibromoethane 106-93-4 Dibromochloromethane 124-48-1 Dibromomethane 74-95-3 1,2-Dichlorobenzene 95-50-1 1,3-Dichlorobenzene 541-73-1 1,4-Dichlorobenzene 106-46-7 1,4-Dichlorobenzene-d (IS) cis-1,4-Dichloro-2-butene 1476-11-5 trans-1,4-Dichloro-2-butene 110-57-6 Dichlorodifluoromethane 75-71-8 1,1-Dichloroethane 75-34-3 1,2-Dichloroethane 107-06-2 1,2-Dichloroethane-d (surr) Speciated Volatile Organic HAPs1,1-Dichloroethene 75-35-4 cis-1,2-dichloroethene 156-59-2 trans-1,2-Dichloroethene 156-60-5 1,2-Dichloropropane 78-87-5 1,3-Dichloro-2-propanol 96-23-1 1-1,3-dichloropropene 1006-02-6 cis-1,3-Dichloropropene 10061-01-5 trans-1,3-Dichloropropene 10061-02-6 1,2,3,4-Diepoxybutane 1464-53-5 Diethyl ether 60-29-7 1,4-Difluorobenzene (IS) 540-36-3 1,4-Dioxane 123-91-1 Epichlorohydrin 106-89-8 Ethanol 64-17-5 1-ethyl-4-methy benzene 622-96-8 Ethyl acetate 141-78-6 Ethylbenzene 100-41-4 Ethylene oxide 75-21-8 Ethyl m ethacrylate 97-63-2 Fluorobenzene (IS) 462-06-6 Heptane 142-82-5 Hexachlorobutadiene 87-68-3 1,1,2,3,4-hexachloro-1,3-butadiene 87-68-3 Hexachloroethane 67-72-1 Hexane 11/5/2003 2-Hexanone 591-78-6 2-Hydroxy propionitrile 78-97-7 Iodomethane 74-88-4 Isobutyl alcohol 78-83-1 Isopropyl alcohol 67-63-0 Isopropylbenzene 98-82-8 Malononitrile 109-77-3 Methacrylonitrile 126-98-7 Methanol 67-56-1 Methylene chloride 75-09-2 Methyl m ethacrylate 80-62-6 Methyl-t-butyl either (MTBE) 1634-04-4 4-Methyl-2-pentanone (MIBK) 108-10-1 Naphthalene 91-20-3 Nitrobenzene 98-95-3 2-Nitropropane 79-46-9 N-Nitroso-di-n-butylam ine 924-16-3 Paraldehyde 123-63-7 Pentachloroethane 76-01-7 2-Pentanone 107-87-9 2-Picoline 109-06-8 1-Propanol 71-23-8 2-Propanol 67-63-0 Propargyl alcohol 107-19-7 $-Propiolactone 57-57-8 Propionitrile (ethyl cyanide) 107-12-0 n-Propylam ine 107-10-8 Pyridine 110-86-1 Styrene 100-42-51,1,1,2-Tetrachloroethane 630-20-6 

### Listed (by boiler) in the Configuration Order Section of the Facility Unit Configurations Section of the Electronic ICR 1,1,2,2-Tetrachloroethane 79-34-5 Tetrachloroethylene 127-18-4 Teteahydrofuran 109-99-9 2,3,4,6-Tetrchlorophenol Toluene 108-88-3 Toluene-d (surr) 2037-26-5 o-Toluidine 95-53-4 Tribromomethane 75-25-2 1-1,2-trichloro-1,2,2-trifluoroethane 76-13-1 1,2,4-Trichlorobenzene 120-82-1 1,1,1-Trichloroethane 71-55-6 1,1,2-Trichloroethane 79-00-5 Trichloroethylene 79-01-6 Trichlorofluoromethane 75-69-4 Trichloromonofluoromethane 75-69-4 1,2,3-Trichloropropane 96-18-4 1,3,5-trimethylbenzene 108-67-8 1,2,4-trimethlbenzene 95-63-6 Vinyl acetate 108-05-4 Vinyl chloride 75-01-4 m/p-Xylene 95-47-6 o-Xylene 95-47-6 m-Xylene 108-38-3 p-Xylene 106-42-3Speciated Semi-volatile Organic HAPs

Constituent CAS Acenaphthene 83-32-9 Acenaphthylene 208-96-8 Acetophenone 98-86-2 2-Acetylam inofluorene 53-96-3 1-Acetyl-2-thiourea 591-08-2 Aldrin 309-00-2

2-Aminoanthraquinone 117-79-3 Am inoazobenzene 60-09-3 4-Aminobiphenyl 92-67-1 3-Amino-9-ethylcarbazole 132-32-1 Anilazine 101-05-3 Aniline 62-53-3 o-Anisidine 90-04-0 Anthracene 120-12-7 Aramite 140-57-8 Aroclor 1016 12674-11-2 Aroclor 1221 11104-28-2 Aroclor 1232 11141-16-5 Aroclor 1242 53469-21-9

Aroclor 1248 12672-29-6 Aroclor 1254 11097-69-1 Aroclor 1260 11096-82-5

Azinphos-m ethyl 86-50-0 Barban 101-27-9 Benzidine 92-87-5 Benzoic acid 65-85-0 Benz(a)anthracene 56-55-3 Benzo(b)fluoranthene 205-99-2 Benzo(k)fluoranthene 207-08-9 Benzo(g,h,i)perylene 191-24-2 Benzo(a)pyrene 50-32-8 p-Benzoquinone 106-51-4 Benzyl alcohol 100-51-6

α-BHC 319-84-6 β-BHC 319-85-7

δ-BHC 319-86-8 γ-BHC (Lindane) 58-89-9 Bis(2-chloroethoxy)methane 111-91-1 Bis(2-chloroethyl) ether 111-44-4 Bis(2-chloroisopropyl) ether 39638-32-9 Bis(2-ethylhexyl) phthalate 117-81-7 4-Bromopheny l phenyl ether 101-55-3 Bromoxy nil 1689-84-5 Butyl benzyl phthalate 85-68-7 Captafol 2425-06-1 Captan 133-06-2Carbaryl 63-25-2

Carbofuran 1563-66-2 Carbophenothion 786-19-6 Chlordane (NOS) 57-74-9

Chlorfenvinphos 470-90-6 4-Chloroaniline 106-47-8 Chlorobenzilate 510-15-6 5-Chloro-2-methy laniline 95-79-4 4-Chloro-3-methy lphenol 59-50-7 3-(Chloromethyl)pyridine hydrochloride 6959-48-4 1-Chloronaphthalene 90-13-1 2-Chloronaphthalene 91-58-7

2-Chlorophenol 95-57-8 4-Chloro-1,2-phenylenediam ine 95-83-0 4-Chloro-1,3-phenylenediam ine 5131-60-2 4-Chlorophenyl phenyl ether 7005-72-3 Chrysene 218-01-9

Coumaphos 56-72-4

p-Cresidine 120-71-8

Crotoxy phos 7700-17-6 2-Cyclohexyl-4,6-dinitro-phenol 131-89-5 4,4'-DDD 72-54-8 4,4'-DDE 72-55-9

4,4'-DDT 50-29-3 Demeton-O 298-03-3 Demeton-S 126-75-0 Diallate (cis or trans) 2303-16-4 2,4-Diaminotoluene 95-80-7 Dibenz(a,j)acridine 224-42-0

Dibenz(a,h)anthracene 53-70-3 Dibenzofuran 132-64-9 Dibenzo(a,e)pyrene 192-65-4 1,2-Dibromo-3-chloropropane 96-12-8 Di-n-butyl phthalate 84-74-2 Dichlone 117-80-6 1,2-Dichlorobenzene 95-50-1 1,3-Dichlorobenzene 541-73-1 1,4-Dichlorobenzene 106-46-7 3,3'-Dichlorobenzidine 91-94-1 2,4-Dichlorophenol 120-83-2 2,6-Dichlorophenol 87-65-0 Dichlorovos 62-73-7 Dicrotophos 141-66-2 Dieldrin 60-57-1 Diethyl phthalate 84-66-2 Diethylstilbestrol 56-53-1Diethyl sulfate 64-67-5

Dim ethoate 60-51-5 3,3'-Dimethoxy benzidine 119-90-4

Dim ethylam inoazobenzene 60-11-7 7,12-Dimethylbenz(a)-anthracene 57-97-6 3,3'-Dimethylbenzidine 119-93-7

α,α-Dimethylphenethylam ine 122-09-8 2,4-Dimethylphenol 105-67-9 Dim ethyl phthalate 131-11-3 1,2-Dinitrobenzene 528-29-0 1,3-Dinitrobenzene 99-65-0

1,4-Dinitrobenzene 100-25-4

4,6-Dinitro-2-methy lphenol 534-52-1 2,4-Dinitrophenol 51-28-5

2,4-Dinitrotoluene 121-14-2 2,6-Dinitrotoluene 606-20-2 Dinocap 39300-45-3 Dinoseb 88-85-7 Diphenylam ine 122-39-4 5,5-Diphenylhydantoin 57-41-0 1,2-Diphenylhydrazine 122-66-7 Di-n-octyl phthalate 117-84-0 Disulfoton 298-04-4 Endosulfan I 959-98-8 Endosulfan II 33213-65-9 Endosulfan sulfate 1031-07-8 Endrin 72-20-8 Endrin aldehyde 7421-93-4 Endrin ketone 53494-70-5 X X ND X X 53494-70-5 EPN 2104-64-5 Ethion 563-12-2 Ethyl carbamate 51-79-6 Ethyl m ethanesulfonate 62-50-0 Famphur 52-85-7 Fensulfothion 115-90-2 Fenthion 55-38-9 Fluchloralin 33245-39-5 Fluoranthene 206-44-0 Fluorene 86-73-7 2-Fluorobiphenyl (surr) 321-60-8 2-Fluorophenol (surr) 367-12-4 Heptachlor 76-44-8 Heptachlor epoxide 1024-57-3 Hexachlorobenzene 118-74-1 Hexachlorobutadiene 87-68-3 Hexachlorocyclopentadiene 77-47-4Hexachloroethane 67-72-1

Hexachlorophene 70-30-4 Hexachloropropene 1888-71-7 Hexamethylphosphoramide 680-31-9 Hydroquinone 123-31-9 Indeno(1,2,3-cd)pyrene 193-39-5 Isodrin 465-73-6 Isophorone 78-59-1 Isosafrole 120-58-1 Kepone 143-50-0 Leptophos 21609-90-5 Malathion 121-75-5 Maleic anhydride 108-31-6 Mestranol 72-33-3 Methapyrilene 91-80-5 Methoxychlor 72-43-5 3-Methylcholanthrene 56-49-5 4,4'-Methylenebis (2-chloroaniline) 101-14-4 4,4'-Methylenebis(N,N-dimethy laniline) 101-61-1 Methyl m ethanesulfonate 66-27-3 2-Methylnaphthalene 91-57-6 Methyl parathion 298-00-0 2-Methylphenol 95-48-7 3-Methylphenol 108-39-4 4-Methylphenol 106-44-5 Mevinphos 7786-34-7 Mexacarbate 315-18-4 Mirex 2385-85-5 Monocrotophos 6923-22-4 Naled 300-76-5 Naphthalene 91-20-3 1,4-Naphthoquinone 130-15-4 1-Naphthylam ine 134-32-7 2-Naphthylam ine 91-59-8 Nicotine 54-11-5 5-Nitroacenaphthene 602-87-9 2-Nitroaniline 88-74-4 3-Nitroaniline 99-09-2 4-Nitroaniline 100-01-6 5-Nitro-o-anisidine 99-59-2 Nitrobenzene 98-95-3 4-Nitrobiphenyl 92-93-3 Nitrofen 1836-75-5 2-Nitrophenol 88-75-5 4-Nitrophenol 100-02-7 5-Nitro-o-toluidine 99-55-8 Nitroquinoline-1-oxide 56-57-5 N-Nitrosodi-n-buty lam ine 924-16-3 N-Nitrosodiethylam ine 55-18-5 N-Nitrosodimethylam ine 62-75-9 N-Nitrosodiphenylam ine 86-30-6 N-Nitrosodi-n-propy lam ine 621-64-7 N-Nitrosomethylethylam ine 10595-95-6 N-Nitrosomorpholine 59-89-2 N-Nitrosopiperidine 100-75-4N-Nitrosopy rrolidine 930-55-2

Octamethyl pyrophosphoramide 152-16-9 4,4'-Oxydianiline 101-80-4 Parathion 56-38-2 Pentachlorobenzene 608-93-5 Pentachloronitrobenzene 82-68-8 Pentachlorophenol 87-86-5 Phenacetin 62-44-2 Phenanthrene 85-01-8 Phenobarbital 50-06-6 Phenol 108-95-2 1,4-Phenylenediam ine 106-50-3 Phorate 298-02-2 Phosalone 2310-17-0 Phosmet 732-11-6 Phosphamidon 13171-21-6 Phthalic anhydride 85-44-9 2-Picoline (2-Methylpyridine) 109-06-8 Piperonyl sulfoxide 120-62-7 Pronamide 23950-58-5 Propylthiouracil 51-52-5 Pyrene 129-00-0 Resorcinol 108-46-3 Safrole 94-59-7 Strychnine 57-24-9 Sulfallate 95-06-7 Terbufos 13071-79-9 1,2,4,5-Tetrachlorobenzene 95-94-3 2,3,4,6-Tetrachlorophenol 58-90-2 Tetrachlorvinphos 961-11-5 Tetraethyl dithiopyrophosphate 3689-24-5 Tetraethyl pyrophosphate 107-49-3 Thionazine 297-97-2 Thiophenol (Benzenethiol) 108-98-5 Toluene diisocyanate 584-84-9 o-Toluidine 95-53-4 Toxaphene 8001-35-2 1,2,4-Trichlorobenzene 120-82-1 2,4,5-Trichlorophenol 95-95-4 2,4,6-Trichlorophenol 88-06-2 Trifluralin 1582-09-8 2,4,5-Trimethylaniline 137-17-7 Trimethyl phosphate 512-56-1 1,3,5-Trinitrobenzene 99-35-4 Tris(2,3-dibromopropy l) phosphate 126-72-7 Tri-p-tolyl phosphate 78-32-0 O,O,O-Triethyl phosphorothioate 126-68-1