ii

NOTICE

Mention of a commercial company, or product does not constitute an endorsement by

NOAA/AOML. Use of information from this publication concerning proprietary products

or the tests of such products for publicity or advertising purposes is not authorized.

ELECTRONIC ACCESS TO DATA LISTED IN THIS REPORT

The data presented in this report is available on the World Wide Web (WWW) at the

following sites:

Bottle and CTD data: http://www.aoml.noaa.gov/ocd/oaces/24n98.html

UWpCO2 data: http://www.aoml.noaa.gov/ocd/oaces/1998data.html

ADCP data: http://ilikai.soest.hawaii.edu/sadcp/woce.html

LADCP data: http://www.nodc.noaa.gov/General/NODC-About/NODCoverview.html#services

For further information regarding the data sets contact:

Ms. Betty E. Huss

Data Manager, OACES/GCC

at: U.S. Dept. of Commerce

NOAA/AOML/OCD

4301 Rickenbacker Causeway

Miami, Florida 33149-1026

Telephone: (305) 361-4395

Email address: huss@aoml.noaa.gov
iii

PRINCIPAL INVESTIGATORS

Project Name Institution

CTD/O2, LADCP, ADCP Molly Baringer AOML

Salinity, Oxygen

CTD/O2 Gregory Johnson PMEL

pCO2 Richard Wanninkhof AOML

Total CO2 Richard Feely PMEL

Chlorofluorocarbons (CFCs) John Bullister PMEL

Nutrients Calvin Mordy PMEL/JISAO

Nutrients Jia-Zhong Zhang NOAA/CIMAS

13C/12C Paul Quay UW

Total Alkalinity, pH Frank Millero UM

TOC, TN, and TP Dennis Hansell BBSR

M-AERI Peter Minnett UM
iv

LIST OF PARTICIPANTS

Leg 1:

Function Name Institution

Chief Scientist Gregg Thomas AOML

pCO2 Dana Greeley PMEL

Total Alkalinity Mary Roche UM

M-AERI Jennifer Hanafin UM

M-AERI Erica Key UM

Leg 2:

Function Name Institution

Chief Scientist Kitack Lee AOML/CIMAS

Co-Chief Scientist David Bitterman AOML

CTD Christiane Fleurant AOML/CIMAS

CTD/ET Douglas Anderson AOML

CTD Kristene McTaggart PMEL

Salinity Gregg Thomas AOML

Oxygen/ET Robert Roddy AOML

Oxygen George Berberian AOML

LADCP Ryan Smith AOML/CIMAS

LADCP Richard Sikorski UM

LADCP Deanna Spindler UM

DIC Marilyn Roberts PMEL

DIC Esa Peltola AOML/CIMAS

pCO2 Dana Greeley PMEL

pCO2 Hua Chen AOML

CFC David Wisegarver PMEL

CFC Fredrick Menzia PMEL

Nutrients Calvin Mordy PMEL/JISAO

Nutrients Charles Fisher AOML

Total Alkalinity Cindy Moore UM

Total Alkalinity Xiaorong Zhu UM

pH Jason Joliff UM

pH Xuewn Liu UM

TOC/TN, and TP Rachel Parsons BBSR

TOC/TN, and TP Amy Richie BBSR

13C/12C Tania Westby UW

The Chief Survey Technician aboard the R/V RONALD BROWN for the cruise was

Jonathan Shannahoff.
v

Institutional Institution Address

Abbreviation

AOML Atlantic Oceanographic and 4301 Rickenbacker Cwy,

Meteorological Laboratory, Miami, FL 33149-1098

BBSR Bermuda Biological Station St. Georges, GE-01,

for Research Bermuda

PMEL Pacific Marine Environmental 7600 Sand Point Way NE,

Laboratory Seattle, WA 98115-0070

UM University of Miami/Rosenstiel 4600 Rickenbacker Cwy,

School of Marine and Atmospheric Miami, FL 33149-1098

Science

- CIMAS Cooperative Institute for Marine

and Atmospheric Studies

UW University of Washington Box 357940, Seattle,

WA 98195-7940

- JISAO Joint Institute for Study of the

Atmosphere and Ocean
vi

CONTENTS

ABSTRACT........................................................................................................................1

1. INTRODUCTION......................................................................................................... 2

1.1. DESCRIPTION OF STUDY AREA ........................................................................ 3

2. DATA COLLECTION AND ANALYTICAL METHODS ...................................... 3

2.1. HYDROGRAPHIC METHODS .............................................................................. 4

2.1.1. CTD AND HYDROGRAPHIC OPERATIONS................................................ 4

2.1.2. NUTRIENT ANALYSIS METHODS ............................................................... 6

 2.2. CARBON PARAMETERS .....................................................................................7

2.2.1. TOTAL DISSOLVED INORGANIC CARBON (DIC) .................................... 7

2.2.2. FUGACITY OF CO2 (fCO2)............................................................................ 10

2.2.3. TOTAL ALKALINITY (TA)........................................................................... 10

2.2.4. pH..................................................................................................................... 12

2.2.5. TOTAL ORGANIC CARBON, TOTAL NITROGEN AND TOTAL

 PHOSPHORUS................................................................................................ 12

2.2.6. 13C/12C OF DISSOLVED INORGANIC CARBON.........................................14

2.2.7. CHLOROFLUOROCARBONS (CFC)............................................................ 15

 2.3. UNDERWAY MEASUREMENT METHODS.................................................... 19

2.3.1. UNDERWAY fCO2......................................................................................... 19

3. ACKNOWLEDGMENTS.......................................................................................... 19

4. REFERENCES............................................................................................................ 20

FIGURES

1. Cruise track for the Atlantic Ocean A5R(epeat) cruise in January and

 February 1998............................................................................................................... 24

2. All parameters measured vs. depth............................................................................... 25

3. The results of the CRM measurements ........................................................................ 30

4. The results of the DIC duplicates during the course of the cruise................................ 31
vii

TABLES

1. Station locations ........................................................................................................... 32

2. Results of the certified reference material, CRM ........................................................ 36

3. Dissolved inorganic carbon duplicates ........................................................................ 41

4. Replicate pCO2 analyses .............................................................................................. 45

5. Correction factors applied to raw data based upon carbonate parameters for

 Certified Reference Materials....................................................................................... 49

6. Replicate dissolved CFC-11 and CFC-12 analyses ..................................................... 50

7. Replicate dissolved CFC-113 and CCl4 analyses ........................................................ 54

8. CFC air measurements ................................................................................................. 59

9. CFC air values (interpolated to station locations) ........................................................ 63

APPENDICES

A. WOCE quality control flags ........................................................................................ 67

B. Bottle data ................................................................................................................... 69
1

CHEMICAL AND HYDROGRAPHIC MEASUREMENTS ON A

CLIMATE AND GLOBAL CHANGE CRUISE ALONG 24 °N IN THE

ATLANTIC OCEAN WOCE SECTION A5R(EPEAT) DURING

JANUARY-FEBRUARY, 1998

E. Peltola, K. Lee, R. Wanninkhof R. Feely, M. Roberts, D. Greeley, M.

Baringer, G. Johnson, J. Bullister, C. Mordy, J.-Z. Zhang, P. Quay, F.

Millero, D. Hansell, and P. Minnett

ABSTRACT

This document contains data and metadata from a zonal cruise along nominally 24.5 °N

in the Atlantic Ocean from Las Palmas, Canary Islands in Spain to Miami, Florida. The

cruise took place from January 23 to February 24, 1998 aboard the NOAA Ship

RONALD H. BROWN under auspices of the National Oceanic and Atmospheric

Administration (NOAA). This report presents the analytical and quality control

procedures performed during the cruise and bottle data from the cruise. The research was

sponsored by the NOAA Climate and Global Change Program under: (i) The OceanAtmosphere Carbon Exchange Study (OACES); and (ii) the World Ocean Circulation

Experiment (WOCE) repeat hydrography program. Samples were taken from up to 36

depths at 130 stations.

The data presented in this report includes the analyses of water samples for: salinity,

nutrients, total dissolved inorganic carbon dioxide (DIC), fugacity of carbon dioxide

(fCO2), total alkalinity (TA), pH, total organic carbon (TOC), total nitrogen (TN), total

phosphorus (TP), chlorofluorocarbons, and stable carbon isotopic ratio of DIC (13C/12C).

Basic hydrographic parameters, pressure, CTD salinity, temperature and the calculated

potential temperature, and potential density are included as well.
2

1. INTRODUCTION

Since the world's oceans have a large capacity to sequester heat and carbon dioxide it is

imperative that the oceans are studied in a comprehensive fashion to elucidate changes in

the Earth's climate. An overall goal of the research is to observe and model the ocean

sufficiently well to understand quantitatively how the ocean effects present climate, and

how the ocean might change under a changing atmosphere. Thus, a long-term objective

is to provide reliable predictions of climate change and associated regional implications

on time scales ranging from seasons to centuries. Current predictions are uncertain, in

part, because of poor understanding of source and sink patterns of greenhouse gases like

carbon dioxide and the role of the ocean in mitigating or changing the timing of regional

patterns associated with warmer climate.

This cruise was designed to support research sponsored by the National Oceanic and

Atmospheric Administration (NOAA) Climate and Global Change Program under:

(i) the Ocean-Atmosphere Carbon Exchange Study (OACES); and (ii) the World Ocean

Circulation Experiment (WOCE) repeat hydrography program. The second leg of the

cruise was conducted aboard the NOAA Ship RONALD H. BROWN from January 23 to

February 24, 1998. The OACES objective of the cruise was to determine the fluxes of

CO2 in the North Atlantic during the winter. A baseline of total carbon inventory in this

region was established such that the uptake rate of atmospheric CO2 can be determined in

future cruises. The objective of the WOCE (repeat) hydrography component was to

understand the general circulation of the global ocean well enough to be able to model its

present state and predict its evolution. The data presented in this report includes:

hydrography, nutrients, total dissolved inorganic carbon dioxide (DIC), fugacity/partial

pressure of carbon dioxide (fCO2/pCO2)

1

, total alkalinity (TA), pH, total organic carbon

(TOC), total nitrogen (TN), total phosphorus (TP), chlorofluorocarbons, and stable

carbon isotopic ratio of DIC (13C/12C).

Detailed information of the CTD operations can be found in NOAA Data Report, ERL

PMEL-68 (McTaggart et al, 1999).

 

1

 The fCO2 takes into account the non-ideality of CO2 gas and is the thermodynamic quantity mostly used in

calculations. It is approximately 0.4 to 0.6 % lower than the corresponding pCO2. In this report we used the

terms interchangeably. However, all reported values are fugacity values.
3

1.1. DESCRIPTION OF STUDY AREA

A total of 130 full water column CTD stations were occupied, complete with water

samples analyzed for salinity, oxygen and chlorofluorocarbon (CFC) content. A large

amount of high quality measurements of all the carbonate parameters including

underway surface water pCO2 and nutrients were also made.

The majority of the data were collected along 24.5o

N from 23.5oW to 69oW. Completing

the transatlantic section were data collected along a NE-SW dogleg off the coast of Africa

, and along a second, short, zonal section along 26.5o

N off the coast of Abaco Island from

69o

W to 77oW, jogging north along 27oN in the Straits of Florida to 80oW. The cruise

track and station locations are presented in Figure 1 and Table 1. The leg 1 followed this

same trackline in the opposite direction, deploying XBTs to sample the temperature in the

upper 750 m, and collecting underway pCO2.

2. DATA COLLECTION AND ANALYTICAL METHODS

One hundred and thirty CTD (Conductivity-Temperature- Depth) hydrographic stations

were occupied to collect discrete water samples and hydrographic data. A CTD/Rosette

unit with a Seabird-911 CTD instrument equipped with 36, specially designed 10-L

samples bottles was utilized for these casts. These bottles have the same outer dimensions

as standard Niskin bottles, but are modified to reduce chlorofluorocarbon sample

contamination. Water samples were collected for salinity, oxygen, nutrients,

chlorofluorocarbons, 13C/12C, as well as carbon related parameters including total

dissolved inorganic CO2 (DIC), discrete fugacity of CO2 (fCO2), total alkalinity (TA), pH,

total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) on all casts

during the cruise using these modified ìNiskinî style bottles. In the data tables the

missing values are assigned a value of -9.0. The WOCE quality control flags have been

listed in Appendix A. All the parameters plotted versus depth are shown in Figure 2 and

in tabular form Appendix B. Detailed information on individual data collection, and

analysis procedures may be found in the following method sections.
4

2.1. HYDROGRAPHIC METHODS

2.1.1. CTD AND HYDROGRAPHIC OPERATIONS

Description of Measurement Techniques and Calibrations

CTD and in situ O2

Depth profiles were obtained with a Seabird 911 plus CTD, deck unit, and rosette pylon.

The CTD included dual temperature sensors, dual conductivity sensors, two Beckman

oxygen sensors, one Paroscientific pressure transducer, and two pumps to decrease the

response time. Thirty-six 10-l "Niskin" bottles were mounted on the frame, along with

the CTD, pinger, Lowered Acoustic Doppler Current Profiler (LADCP), and LADCP

external battery pack. The bottles were specially designed to reduce chlorofluorocarbon

contamination. These bottles have the same outer dimensions as standard 10-l "Niskin"

bottles, but use a modified end-cap design to minimize the contact of the water sample

with the end-cap O-rings after closing. The O-rings used in these water sample bottles

were vacuum-baked prior to the first station. Stainless steel springs covered with a nylon

powder coat were substituted for the internal elastic tubing standardly used to close

"Niskin" bottles. Seabird software was used to acquire, plot, and process the CTD data

on PC's. Raw data were stored on VHS tapes, PC hard drives, and SyQuest drives.

Typically each cast sampled to within 10 meters of the sea floor as indicated by the pinger

signal. The CTD/O2 data were processed and calibrated following Seabird

recommendations (CTD Data Acquisition Software and Technical Notes, Sea-Bird

Electronics, Inc., 1808 - 136th Place NE, Bellevue, Washington 98005). Exceptional

items are noted below. Details can be found in NOAA Data Report, ERL PMEL-68

(McTaggart et al, 1999).

Pre- and post-cruise pressure, temperature, and conductivity sensor calibrations were

performed at Sea-Bird Electronics, Inc. in Bellevue, Washington. Secondary sensor pair

T1075 and C1347 were selected for final data reduction for all stations.

The oxygen sensor was calibrated by using the pre- and post-cruise laboratory calibration.

Secondary oxygen data from sensor s/n 353 was retained for stations 1-32 and 34;

primary oxygen data from sensor s/n 381 was retained for stations 33 and 35-130.

Post-cruise calibrations were applied to CTD data associated with bottle data using the

PMEL program CALBOT. WOCE quality flags were appended to bottle data records

using the PMEL program FLAG. Quality flags were determined by plotting the absolute

value of sample residuals versus pressure and selecting a cutoff value for bad flags.
5

Values which were 2.8 standard deviations from the mean were considered bad. Of the

4313 sample salinities, 0.4% were flagged as bad and 3.6% were flagged as questionable.

Of the 4130 sample oxygens, 1.2% were flagged as bad and 4.9% were flagged as

questionable.

Measurement of Currents

A hull-mounted RD Instruments 150 kHz narrowband acoustic Doppler current profiler

(ADCP) operated continuously during the cruise. Velocity data, averaged in earth

coordinates using gyrocompass heading, were logged in three-minute (approximately 180

pings) ensembles using RDI Data Acquisition Software (DAS) version 2.48. Vertical bin

size was 8 meters. The center of the first bin was located at 16 meters. Range varied from

200 to 400 meters, depending primarily on sea state. A user exit program (UE4, provided

by Eric Firing, U. Hawaii) was used to interface navigation and heading equipment.

Position was logged at the beginning and end of each ensemble from a Trimble Centurion

P-code GPS receiver (estimated position accuracy of 5 - 10 meters). Mean gyrocompass

corrections for each ensemble were recorded from an Ashtech 3DF GPS attitude

determination system; 3DF array orientation was calibrated using P-code GPS and ADCP

bottom track comparison. These data are used in post-processing to calculate mean ship

velocity to reference ensemble means, and to compensate for dynamic gyrocompass

errors. Estimated errors for an ensemble are 1-2 cm/s for relative velocity and 3-4 cm/s

for ship speed errors due to position inaccuracy; errors induced by heading inaccuracies

are reduced to less than 1 cm/s using GPS heading data. This total error of 4-6 cm/s over

a three minute ensemble is reduced further by averaging during postprocessing; the

fifteen minute averages commonly used represent an average over five kilometers at

cruising speed, and should be accurate to 1-3 cm/s. The ADCP data will be available

through internet address http://ilikai.soest.hawaii.edu/sadcp/woce.html

On-station velocity profiles were obtained using a RDI 150 kHz Narrowband ADCP

(Lowered or LADCP) mounted looking downward from the CTD frame. This technique

measures and records velocity shear profiles extending 150 to 350 meters below the

instrument approximately once per second. In postprocessing, the individual shear

profiles are averaged by depth to produce a full-depth shear profile, which is integrated to

estimate the depth dependent (baroclinic) component of the velocity field. The depthindependent (barotropic) component of velocity can be recovered if positions at the start

and end of the cast are known; positions were logged on this cruise using a Trimble

Centurion P-code GPS receiver, accurate to 5 - 10 meters. Readers are advised to refer to

Fischer and Visbeck (1993) for a full explanation of methods and standard processing

procedures. The LADCP data will be available through internet address

http://www.nodc.noaa.gov/General/NODC-About/NODC-overview.html#services
6

Salinity Analyses

A Guildline 8400B autosal was used for the salinity analysis with batch P125 standard

water. The autosal room was maintained at 22 °C, and the autosal was set at 24 °C. A

total of 4380 samples were measured and 37 of them were rejected.

Oxygen Technique

An automatic titration system was used for the oxygen analysis with the Carpenter

modification of the Winkler method using a photometric determined endpoint. Reagents

for the Carpenter method titration were mixed by the AOML/OCD Group of George

Berberian as specified in Friederich's MBARI Technical Report #91-6 (Friederich et al,

1991). Apparent oxygen utilization (AOU) is defined as O2 measured- O2 sat., where O2

sat. is the saturation value at potential temperature and salinity of the sample determined

according to Weiss (1970). A total of 4310 samples were measured and 52 of them were

rejected.

2.1.2. NUTRIENT ANALYSIS METHODS

Sampling and analytical methods

Nutrient samples were collected from 10-L "Niskin" bottles in acid washed 25-ml linear

polyethylene bottles after three complete seawater rinses and analyzed within 1 hour of

sample collection. Measurements were made in a temperature-controlled laboratory (20 ±

2 oC). Concentrations of nitrite (NO2

-

), nitrate (NO3

-

), phosphate (PO4

3-) and silicic acid

(H4SiO4) were determined using an Alpkem Flow Solution Auto-Analyzer aboard the

ship. The following analytical methods were employed:

Nitrate and Nitrite:

Nitrite was determined by diazotizing with sulfanilamide and coupling with N-1 naphthyl

ethylenediamine dihydrochloride to form an azo dye. The color produced is measured at

540 nm (Zhang et al., 1997a). Samples for nitrate analysis were passed through a home

made cadmium column (Zhang et al., 2000), which reduced nitrate to nitrite and the

resulting nitrite concentration was then determined as described above. Nitrate

concentrations were determined from the difference of nitrate + nitrite and nitrite.
7

Phosphate:

Phosphate in the samples was determined by reacting with molybdenum (VI) and

antimony (III) in an acidic medium to form an antimonyphosphomolybdate complex at

room temperature. This complex was subsequently reduced with ascorbic acid to form

a blue complex and the absorbance was measured at 710 nm (Grasshoff et al. ,1983).

A total of 4306 samples were measured and 1248 of them were rejected.

Silicic Acid:

Silicic acid in the sample was analyzed by reacting the aliquote with molybdate in a

acidic solution to form β-molybdosilicic acid . The β-molybdosilicic acid was then

reduced by ascorbic acid to form molybdenum blue (Zhang et al., 1997b). The absorbance

of the molybdenum blue was measured at 660 nm.

Calibration and standards:

Stock standard solutions were prepared by dissolving high purity standard materials

(KNO3 , NaNO2 , KH2PO4 and Na2SiF6 ) in deionized water. Working standards were

freshly made at each station by diluting the stock solutions in low nutrient seawater. The

low nutrient seawater used for the preparation of working standards, determination of

blank, and wash between samples was filtered seawater obtained from the surface of the

Gulf Stream. Standardizations were performed prior to each sample run with working

standard solutions. Two or three replicate samples were collected from the "Niskin" bottle

sampled at deepest depth at each cast. The relative standard deviation from the results of

these replicate samples were used to estimate the overall precision obtained by the

sampling and analytical procedures. The precisions of these samples were 0.04 μmol/kg

for nitrate, 0.01 μmol/kg for phosphate and 0.1 μmol/kg for silicic acid.

2.2. CARBON PARAMETERS

2.2.1. TOTAL DISSOLVED INORGANIC CARBON (DIC)

The DIC analytical equipment was set up in a seagoing laboratory van. The analysis was

done by coulometry with two analytical systems (PMEL-1 and PMEL-2) used

simultaneously on the cruise. Each system consisted of a coulometer (UIC, Inc.) coupled

with a SOMMA (Single Operator Multiparameter Metabolic Analyzer) inlet system

developed by Kenneth Johnson (Johnson et al., 1985,1987,1993; Johnson, 1992) formerly
8

of Brookhaven National Laboratory (BNL). In the coulometric analysis of DIC, all

carbonate species are converted to CO2 (gas) by addition of excess hydrogen ion (acid)

to the seawater sample, and the evolved CO2 gas is swept into the titration cell of the

coulometer with compressed nitrogen, where it reacts quantitatively with a proprietary

reagent based on ethanolamine to generate hydrogen ions. These are subsequently titrated

with coulometrically generated OH-. CO2 is thus measured by integrating the total charge

required to achieve this.

The coulometers were calibrated by injecting aliquots of pure CO2 (99.995%) by means

of an 8-port valve outfitted with two sample loops that had been calibrated at BNL

(Wilke, 1993). The CO2 gas volumes bracketed the amount of CO2 extracted from the

water samples for the two PMEL systems. All DIC values were corrected for dilution by

0.2 ml of HgCl2 used for sample preservation. The total water volume was 540 ml. The

correction factor used for dilution was 1.00037. The instruments were calibrated at the

beginning, middle, and end of each coulometer cell solution with a set of the gas loop

injections. The coulometer cell solution was replaced after 25 mg of carbon was titrated,

typically after 9-12 hours of continuous use. Sample titration times were 9-16 minutes.

Certified Reference Materials (CRMs), consisting of poisoned, filtered, and UV irradiated

seawater supplied by Dr. A. Dickson of Scripps Institution of Oceanography (SIO), were

run on each cell. The results were close to the values determined manometrically by Dr.

Charles D. Keeling at SIO as shown below. The CRM results have been presented in

Figure 3 and Table 2. The overall accuracy and precision for the CRMs on both

instruments combined was -0.1 +/-2.1 (n=125). DIC data reported for this cruise have

been corrected to the Batch 40 CRM value by adding the difference between the certified

value and the mean shipboard CRM value (certified value - shipboard analyses) on a per

instrument/per leg basis.

Av. value of CRMs run on PMEL-1: 1987.3 ±2.0 μmol/kg (n = 59)

Av. value of CRMs run on PMEL-2: 1984.6±1.2 μmol/kg (n = 66)

Manometric value [SIO reference material batch #40] was 1985.8±0.7 μmol/kg (n=10)

Samples were drawn from the "Niskin" bottles into cleaned, precombusted 500-ml Pyrex

bottles using Tygon tubing according to procedures outlined in the Handbook of Methods

for CO2 Analysis (DOE, 1994). Bottles were rinsed once and filled from the bottom,

overflowing half a volume. Care was taken not to entrain any bubbles. The tube was

pinched off and withdrawn, creating a 5-ml headspace, and 0.2 ml of saturated HgCl2

solution was added as a preservative. The sample bottles were sealed with glass stoppers

lightly covered with Apiezon-L grease, and were stored at room temperature for a

maximum of 12 hours prior to analysis.
9

Replicate seawater samples were taken from both the surface and 1000 m "Niskin"

sample bottles and run at different times during the cell. The first replicate of the surface

water was used at the start of the cell with fresh coulometer solution, the second surface

water replicate in the middle of the cell after about 12 mg of C were titrated. The first one

of the 1000 m replicates was run at the end of the cell after about 25 mg of C were

titrated, while the second one of the 1000 replicate samples was run using a new

coulometer cell solution. No systematic difference between the replicates was observed.

As example, the 1000m replicate samples run on both PMEL1 and PMEL2 combined had

a standard deviation of 1.3 μmol/kg for 32 sets of duplicates, and the results of the

surface replicates yielded a standard deviation of 0.9 μmol/kg for 98 sets of duplicates.

The deviation is very similar to that observed for the CRMs and suggest no strong

dependency of results with amount of carbon titrated for a particular cell. The results of

the duplicate samples have been presented in Figure 4 and Table 3.

Calculations

Calculation of the amount of CO2 injected was according to the Department of Energy

(DOE) CO2 handbook [DOE, 1994]. The gas loops yielded a calibration factor for the

instrument defined as:

The concentration of CO2 ([CO2]) in the samples was determined according to:

 (2) pipette volume* density of sample

(Counts - Blank * Run Time)* K mol/count [CO2 ] = Cal. factor * μ

where "Counts" is the instrument reading at the end of the analysis, "Blank" is the

counts/minute determined from blank runs performed at least once for each cell of the

solution, "Run Time" is the length of coulometric titration (in minutes), and K is the

conversion factor from counts to μmol which is dependent on the slope and intercept

relation between instrument response and charge. For a unit with Ecal slope of 1 and

intercept of 0, the constant is 2.0728 * 10-4.

The pipette volume was determined by taking aliquots at known temperature of distilled

water from the volumes prior to, during, and after the cruise. The weights with the

appropriate densities were used to determine the volume of the syringes and pipette.

Calculation of pipette volumes, density, and final CO2 concentration were performed

according to procedures outlined in the DOE CO2 handbook (DOE, 1994).

Cal. factor = calculated moles of CO injected from gas loop

actual moles of CO injected (1) 2

2
10

2.2.2. FUGACITY OF CO2 (fCO2)

Gas Chromatographic (GC) Method

A total of 1463 discrete fCO2 samples from 130 stations were taken and analyzed on the

cruise using an analysis system based on gas chromatography (Neill et al., 1997).

Sampling from the "Niskin" bottles occurred immediately after O2 samples were drawn.

Samples were drawn into 120 ml Pyrex septum bottles after rinsing the bottles several

times. On the final fill water was drawn into the bottom of the bottle and overflowed at

least one half volume. A Teflon lined septum was crimp sealed on the bottle ensuring

that no headspace was present.

Prior to analysis 5-ml water was withdrawn and replaced with a headspace of known CO2

concentration that was expected to closely match that of the water. The remaining water

and headspace were equilibrated by rotating the bottles for at least 40 minutes in a

constant temperature bath at 20 °C. The fCO2 of the headspace was measured in a flame

ionization detector (FID) after quantitative conversion of the CO2 to methane. The

analyses were referenced against a series of six gas standards with the following mole

fractions: 198.09, 348.16, 977.79, 508.35, 1479.46, 717.4. The standards, which were run

after each dozen samples, bracketed most of the concentrations measured in the water

column. The precision of the fCO2 measurements was estimated at 0.86% of the signal

based on 89 replicate samples (see Table 4). The fCO2 measurements had a data gap midcruise because of a catastrophic instrument failure caused by water being injected onto

the column and catalyst. Good, full water column, coverage was obtained at the Eastern

and Western side of the basin.

The surface water measurements showed that the water undersaturated for most of the

transect except at the boundaries. The undersaturation reaches its greatest value of -45 to -

50 μatm between 60 and 75 °E. The fCO2 in the deep water showed a strong trend with

lower concentrations in the West due to better ventilation of the Western half of the

basin.

2.2.3. TOTAL ALKALINITY (TA)

Seawater samples were drawn from the "Niskin" bottles with a 40-cm length of silicon

tubing. One end of the tubing was fit over the petcock of the "Niskin" bottle and the

other end was inserted into the bottom of a 500-ml Corning glass-stoppered sample

bottle. The sample bottle was rinsed three times with approximately 300 ml of seawater.

The sample bottle was slowly filled from the bottom. Once filled, the sample bottles

were kept in a constant water bath at 25°C for half-hour before analysis.
11

The titration system used to determine TA consisted of a Metrohm 665 Dosimat titrator

and an Orion 720A pH meter controlled by a personal computer (Millero et al., 1993).

The acid titrant, in a water-jacketed burette, and the seawater sample, in a water-jacketed

cell, were kept at 25±0.1°C with a Neslab constant-temperature bath. The plexiglass

water-jacketed cells were similar to those used by Bradshaw et al. (1988), except that a

larger volume (200 ml) was used to increase the precision. The cells had fill and drain

valves with zero dead-volume to increase the reproducibility of the cell volume.

The HCl solutions used throughout the cruise were made, standardized, and stored in

500-ml glass bottles in the laboratory for use at sea. The 0.2489 M HCl solutions (Batch

9601) were prepared by dilution of concentrated HCl in 0.45 M NaCl to yield an ionic

strength equivalent to that of average seawater (0.7 M). The acid was independently

standardized using a coulometric technique (Taylor and Smith, 1959; Marinenko and

Taylor, 1968) by the University of Miami and by Dr. Dickson of Scripps Institution of

Oceanography (SIO). The two standardization techniques agreed to +/-0.0001 N.

The volume of HCl delivered to the cell is traditionally assumed to have a small

uncertainty (Dickson, 1981) and is equated with the digital output of the titrator.

Calibrations of the Dosimat burettes with Milli Q water at 25°C indicated that the

systems deliver 3.000 ml (the value for a titration of seawater) to a precision of 0.0004

ml. This uncertainty resulted in an error of 0.4 μmol/kg in TA.

The titrators were calibrated in the laboratory before the cruise. Certified standard

Reference Material (CRM) Batch 40 prepared by Dr. Dickson was used at sea to monitor

the performance of the titrators. All TA data have been corrected based on CRM values

for each cell and each leg (see Table 5) (Millero et al, 2000).

Carbonate parameters of surface waters indicate the occurrence of upwelling near the

African coast. The surface carbonate parameters are consistent with those collected

during the WOCE (World Ocean Circulation Experiment) 1992 cruise that sampled

stations along the same latitude (24oN). Both studies yield values for normalized TA

(TA*35/S) of 2291±6 μmol kg-1. The values of TA for the deep water are in good

agreement (± 3.8 μmol/kg). Crossover comparison with OACES 1993 study also showed

good agreement (±3 μmol/kg in TA). The pH is on average 0.004 higher than those made

on the 1993 cruise.

Kitack Lee from AOML/OCD calculated total alkalinity (TA) from spectroscopic pH

(25oC) and coulometric total dissolved inorganic carbon (DIC) using the carbonic acid

dissociation constants of Mehrbach et al. (1973) as refit by Dickson and Millero (1987).

A value of 1.2 μmol kg-1 has been subtracted from calculated TA values because

calculated values are 1.2 μmol kg-1 higher than measured values.
12

2.2.4. pH

Seawater samples were drawn from the "Niskin" bottles with a 20-cm length of silicon

tubing. One end of the tubing was fit over the petcock of the "Niskin" bottle and the

other end was attached over the opening of a 10-cm glass spectrophotometric cell. The

spectrophotometric cell was rinsed three to four times with a total volume of

approximately 200 ml of seawater; the Teflon endcaps were also rinsed and then used to

seal a sample of seawater in the glass cell. While drawing the sample, care was taken to

make sure that no air bubbles were trapped within the cell. The sample cells were kept in

a waterbath at 25°C for a half an hour before analysis.

Seawater pH was measured using the spectrophotometric procedure (Byrne, 1987) and

the indicator calibration of Clayton and Byrne (1993). The indicator was an 8.0-mM

solution of Kodak m-cresol purple sodium salt (C21H17O5Na) in MilliQ water. The

absorbance ratio of the concentrated indicator solution (RI = 578A/434A) was 0.95. All

absorbance ratio measurements were obtained in the thermostatted (25.0±0.05°C) cell

compartments of HP 8453 UV-visible Diode Array Spectrophotometers. Measurements

of pH were taken at 25°C on the total hydrogen ion concentration ([H+]T) scale, in mol/kg

solution, and converted to seawater scale ([H+]sw). The overall precision of the pH

measurements obtained from the duplicate samples was ±0.0006. A total of 1997 samples

were measured and 24 of them were rejected.

2.2.5. TOTAL ORGANIC CARBON, TOTAL NITROGEN AND TOTAL

 PHOSPHORUS

Total Organic Carbon Analyses

TOC samples were analyzed by a high-temperature combustion (HTC) method using

custom made instruments. Samples were analyzed with a furnace divided into two

temperature zones (Hansell and Peltzer, 1998; Carlson et al., 1999). Ultra high purity O2

flowed through the instrument at 175 ml/min. Samples were acidified (10 μl of 85%

H3PO4 per 10 ml of sample) and sparged with CO2 free oxygen for at least 10 minutes to

remove inorganic carbon. One hundred μl of sample was injected manually through a

septumless port into the quartz combustion tube packed with Pt gauze (Aldrich), 7% Pt

on alumina catalyst (Shimadzu), Sulfix (Wako Pure Chemical Industries, Inc.) and CuO

wire (Leeman Labs). The Pt gauze and Pt beads were heated to 800°C in the upper zone

while the remaining packing material was heated to 600°C in the lower zone. The

resulting CO2 flowed through two water traps and a final copper halide trap then detected

with a LiCor 6252 CO2 analyzer. The signal was integrated with chromatographic

software (Dynamax Macintegrator I version 1.3; Rainin Inst.).
13

Extensive conditioning of the combustion tube was essential to minimize the machine

blank. The system blank (<10 μM) was assessed daily with ampoulated low carbon

waters (LCW). The system response was standardized daily with a four point calibration

curve of glucose solution in LCW. Deep Sargasso Sea water (>2000 m), which had been

acidified and ampoulated, served as a daily reference material. Analyzing low carbon

water and reference deep seawater several times a day allowed us to assess the system

stability from run-to-run and day-to-day, ensuring confidence in our analysis. Both the

low carbon and the deep Sargasso Sea references waters are part of an international

certified reference material program for marine DOC measurement, run by the laboratory

of Dr. Hansell. As such, the TOC analyses from the 24°N line are referenced to the

international community of DOC laboratories using the CRMís.

Total Nitrogen Analyses

Concentrations of TN (total nitrogen, or the sum or organic and inorganic N) were

determined by high temperature combustion and detection of the nitric oxide produced.

Samples had been collected into 60 ml polyethylene bottles for frozen storage until

analysis in the shore laboratory. In the high temperature system, a 1⁄2î quartz combustion

tube was held at 900 °C in the upper zone and 800-900 °C in the lower zone of a 2-zone

Thermcraft tube furnace. The combustion tube has a 12 cm head space, 2-3 screens of

pure Pt (52 mesh), an 8 cm bed of 7% Pt on alumina (Shimadzu, Inc.), and a 10 cm bed of

quartz beads. 100 μl injections of seawater were made into the combustion tube by

syringe through a septum. The carrier gas (UHP oxygen) flowed at a rate of 200 ml/min.

Recovery of known standards (glycine, urea, EDTA, etc.) was >90%. Detection of NO

was done with an Antek Model 7020 chemiluminescence detector.

Oxygen flow through the ozone generator was 28 ml/min. Standardization was

performed daily with potassium nitrate in Milli-Q water. Q water was used as the system

blank, and it was assumed to have zero N content. The system blank was normally <1

μM. Low nutrient sea water, collected at the surface of the Sargasso Sea, was used as a

reference material for daily use. The coefficient of variation in low nutrient surface water

(4-5 μM TN) was 3-4%, while in deep water (>20 μM TN) it was 1%. Data acquisition

was performed on a Dynamax Macintegrator I version 1.3, produced by Rainin

Instruments.

Total Phosphorus Analyses

Concentrations of TP (total phosphorus; organic plus inorganic P) were determined by

UV photo-oxidation. Samples had been stored frozen in 60 ml polyethylene bottles until

shore based analysis. A 6 ml aliquot was removed from each sample bottle and placed in

a 20 ml fused quartz tube equipped with a Pyrex ground stopper (Quartz Scientific, Inc.).

One hundred μl of 30% hydrogen peroxide was added to each tube and placed in a
14

homemade irradiation unit (2 hours). The irradiation unit contained a 1200 W UV lamp

(Hanovia) protected by a quartz jacket. A 2-tiered aluminum tube holder (40 tubes total)

fitted around the lamp and held the samples 7 cm from the lamp. A fan placed at the

bottom of the unit blew air across the samples for cooling. A hinged aluminum cylinder,

open at the top and bottom, was fitted around the samples to keep stray UV light from

leaving the system. This entire unit was placed in a fume hood, the front of which was

covered with a black curtain while in use (again to collect stray UV light).

After irradiation, aliquots of the samples that had not been oxidized, and the photooxidized aliquots, were analyzed for phosphate using a colorimetric method on a

Technicon Autoanalyzer II (Knap et al. 1997). Daily calibration was achieved from 4

point calibration curves using KH2PO4. Low nutrient seawater (Sargasso Sea surface

water) was always processed with the samples as a daily quality control measure.

Coefficients of variation for the measurement was X and X% for shallow and deep water

samples.

2.2.6. 13C/12C OF DISSOLVED INORGANIC CARBON

Shipboard Sample Collection Methods

Samples were collected in pre-washed and baked (450 oC) 500 ml ground glassstoppered bottles using the following method. A length of Tygon tubing was attached to

the "Niskin" bottle or seawater line and flushed for a few seconds. The end of the tubing

was then placed at the bottom of the upright sample bottle and the bottle was filled, then

overflowed with an amount equal to its volume if "Niskin" water volume permitted,

otherwise with at least half its volume. Flow was stopped as the Tygon tubing was

removed from the top of the bottle to avoid any splashing in the top. Using a syringe or

turkey baster, 10 to 20 ml were withdrawn off the top of the sample to lower the water

level to approximately 1 ml below the neck of the bottle, avoiding backwash of water

from the turkey baster into the sample. The ground glass joint of the bottle was wiped dry

with Kimwipes. Then 100 μl of a saturated HgCl2 solution (per 250 ml of seawater) was

injected beneath the surface of the sample using an Eppendorf pipet. The ground-glass

stopper, which had been pre-greased with Apiezon M grease, was then inserted straight

into the bottle without twisting. If any air streaks in the grease seal were visible, the

stopper was removed, cleaned, and regreased, and the bottle was resealed. Clips (if

required for the bottle neck-type) were placed on the necks of the bottles, and two heavy

rubber bands were placed around the stopper and bottle to prevent leakage. The sample

bottle was then inverted a couple of times to mix the HgCl2 throughout the sample.
15

Laboratory Methods

CO2 is extracted from the DIC seawater sample using a modification of the helium

stripping technique described by Kroopnick (1974) as described in Quay et al (1992).

The stripper is comprised of a glass tube with a stainless steel fitting and silicone-greased

glass stopcock at the bottom (which connects to the He line), a glass frit which the He

passes through, and a stainless steel fitting containing a 3-layer silicone rubber septum at

the top. Approximately 1 ml phosphoric acid is injected into the stripper and bubbled

with He for 10 minutes. The gas is then evacuated out of the stripper and the stripper is

weighed. Then 80 to 125 ml of the sample is drawn into the stripper and it is weighed

again to calculate the weight of water analyzed. A stainless steel needle pierces the

septum and connects the stripper to the extraction line, which has been evacuated and

filled with helium. The sample is stripped with 99.997% pure He at a flow rate of 200

ml/min for 20 minutes. Water is trapped out in two glass traps submerged in Dewars

containing a slush mixture of dry ice and isopropanol at -70oC. CO2 is collected at -196oC

in glass loop traps submerged in liquid N2. The δ13C is then measured on a Finnigan

MAT 251 mass spectrometer. The efficiency of the extraction method is 100 ± 0.5

percent based on gravimetrically prepared Na2CO3 standards. The precision of the

13C/12C analysis is ± 0.02 0

/00 based on a replicate analysis of standards and seawater

samples.

2.2.7. CHLOROFLUOROCARBONS (CFC)

As described above specially designed 10-l water sample bottles were used on the cruise

to reduce CFC contamination.

Samples for the analysis of dissolved CFC-11, CFC-12 and CFC-113 were drawn from

approximately 1700 of the 4300 water samples collected during the expedition. Samples

for carbon tetrachloride (CCl4 or CFC-10) analysis were drawn from approximately 430

samples. When taken, water samples for CFC analysis were usually the first samples

drawn from the 10-l bottles. Care was taken to co-ordinate the sampling of CFCs with

other samples to minimize the time between the initial opening of each bottle and the

completion of sample drawing. In most cases, dissolved oxygen, fCO2, total CO2,

alkalinity and pH samples were collected within several minutes of the initial opening of

each bottle. To minimize contact with air, the CFC samples were drawn directly through

the stopcocks of the 10-l bottles into 100-ml precision glass syringes equipped with 2-

way metal stopcocks. The syringes were immersed in a holding tank of clean surface

seawater until analyzed.
16

To reduce the possibility of contamination from high levels of CFCs frequently present in

the air inside research vessels, the CFC extraction/analysis system and syringe holding

tank were housed in a modified 20' laboratory van on the aft deck of the ship.

For air sampling, a 100 meter length of 3/8" OD Dekaron tubing was run from the CFC

lab van to the bow of the ship. A flow of air was drawn through this line into the CFC van

using an Air Cadet pump. The air was compressed in the pump, with the downstream

pressure held at 1.5 atm using a back-pressure regulator. A tee allowed a flow (100 cc

min-1) of the compressed air to be directed to the gas sample valves, while the bulk flow

of the air (>7 l min-1) was vented through the back pressure regulator. Air samples were

only analyzed when the relative wind direction was within 60 degrees of the bow of the

ship to reduce the possibility of shipboard contamination. The Air Cadet pump was run

for at least 60 minutes prior to analyzing each batch of air samples to insure that the air

inlet lines and pump were thoroughly flushed

Concentrations of CFC-11, CFC-12 and CFC-113 in air samples, seawater and gas

standards on the cruise were measured by shipboard electron capture gas chromatography

(EC-GC), using techniques similar to those described by Bullister and Weiss (1988). For

seawater analyses, a 30-ml aliquot of seawater from the glass syringe was transferred into

the glass sparging chamber. The dissolved CFCs in the seawater sample were extracted

by passing a supply of CFC-free purge gas through the sparging chamber for a period of 4

minutes at 70 cc min-1. Water vapor was removed from the purge gas during passage

through an 18 cm long x 3/8 inch diameter glass tube packed with the desiccant

magnesium perchlorate. The sample gases were concentrated on a cold-trap consisting of

a 1/8 inch OD stainless steel tube with an about 7 cm section packed tightly with

Porapak N (60-80 mesh). To cool the trap, isopropanol cooled by a Neslab Cryocool

refrigeration system was forced from a reservoir beneath the trap to a level above the

packing with a stream of compressed nitrogen. After quickly bringing the isopropanol to

the top of the trap, a low flow of nitrogen was bubbled through the bath to reduce

gradients and maintained a temperature of -20 o

C. After 4 minutes of purging the

seawater sample, the sparging chamber was closed and the trap was held open for an

additional 1 minute to allow nitrous oxide (N20) to pass through the trap and thereby

minimize its interference with CFC-12. The trap was isolated, the cold isopropanol in the

bath was drained, and the trap was heated electrically to 125 o

C. The sample gases held in

the trap were then injected onto a precolumn (30 cm of 1/8 inch O.D. stainless steel

tubing packed with 80-100 mesh Porasil C, held at 90 o

C), for the initial separation of the

CFCs and other rapidly eluting gases from the more slowly eluting compounds. The

CFCs then passed into the main analytical column (about 183 cm of 1/8 inch OD stainless

steel tubing packed with Carbograph 1AC, 80-100 mesh, held at 90oC) for final

separation, and into the EC detector for quantification.
17

The analysis of carbon tetrachloride was made on a separate, but nearly identical

apparatus to the electron capture-gas chromatography system used in the analysis of CFC11, CFC-12 and CFC-113 (Bullister and Weiss, 1988). Samples were drawn in the same

type of syringes used for the CFC analysis. In the CCl4 system, the sample injection port

was flushed with 30-40 ml of sample before injecting sample into a calibrated loop (about

30 ml). After filling, an additional 30 ml of water was pushed through the loop and

allowed to overflow. For analysis, a valve was switched and the water sample held in the

loop was pushed into the stripper with the same CCl4 free nitrogen that was used to strip

the sample. The gases removed from the sample were dried while passing through an ~18

cm x 3/8 inch OD tube of magnesium perchlorate and concentrated on a trap packed with

four inches of Porapak N and held at -30 °C during trapping. At the conclusion of

stripping, the trap was heated electrically and the contents swept onto the precolumn

(0.53mm I. D. x 30 meters, DB624 capillary column, 45 °C)) with clean nitrogen. The

desired gases passed on to the main analytical column (0.53mm I. D. x 30 meters, DB624

capillary column, 45 °C), before the precolumn vented the later peaks. All other aspects

of the analysis were the same as the CFC analysis.

Both of the analytical systems were calibrated frequently using a standard gas of known

CFC composition. Gas sample loops of known volume were thoroughly flushed with

standard gas and injected into the system. The temperature and pressure was recorded so

that the amount of gas injected could be calculated. The procedures used to transfer the

standard gas to the trap, precolumn, main chromatographic column and EC detector were

similar to those used for analyzing water samples. Two sizes of gas sample loops were

present in the CFC analytical system, while four calibrated sample loops were used in the

CCl4 system. Multiple injections of these loop volumes could be made to allow the

system to be calibrated over a relatively wide range of concentrations. Air samples and

system blanks (injections of loops of CFC-free gas) were injected and analyzed in a

similar manner. The typical analysis time for a seawater, air, standard or blank sample

was 12 minutes on the CFC system and 20 minutes on the CCl4 system.

Concentrations of the CFC's and CCl4 in air, seawater samples and gas standards are

reported relative to the SIO93 calibration scale (Cunnold, et. al., 1994). Concentrations in

air and standard gas are reported in units of mole fraction CFC in dry gas, and are

typically in the parts-per-trillion (ppt) range. Dissolved CFC and CCl4 concentrations are

given in units of picomoles per kg seawater (pmol kg-1). CFC and CCl4 concentrations in

air and seawater samples were determined by fitting their chromatographic peak areas to

multi-point calibration curves, generated by injecting multiple sample loops of gas from a

working standard (PMEL cylinder 33790 for CFC-11, CFC-12 and CFC-113; PMEL

cylinder 33780 for CCl4) into the analytical instrument. The concentrations of CFC-11

and CFC-12 in this working standard were calibrated before and after the cruise versus a

primary standard (36743) (Bullister, 1984). No measurable drift in the concentrations of

CFC-11 and CFC-12 in the working standard could be detected during this interval. Full

range calibration curves were run at intervals of 3 days during the cruise. Single

injections of a fixed volume of standard gas at one atmosphere were run much more
18

frequently (at intervals of 1 to 2 hours) to monitor short term changes in detector

sensitivity.

Extremely low (<0.01 pmol kg-1) CFC concentrations were measured in deep water

(>3000 meters) in the Eastern Basin of the North Atlantic between 25 oW and 45 oW

along this section. Based on the median of CFC concentration measurements in the deep

water of this region, which is believed to be nearly CFC-free, blank corrections of 0.003

to 0.015 pmol kg-1 for CFC-11, 0.006 to 0.007 pmol kg-1 for CFC-12 and 0.006 to 0.011

pmol kg-1 for CFC-113 have been applied to the data set. If the measured CFC

concentration for a sample is very low, subtracting a blank can result in a very small

negative number reported (see Figure 2). No blank corrections were required for the

CCl4 data.

On this expedition, we estimate precision (1 standard deviation) of 1% or 0.005 pmol

kg-1 (whichever is greater) for dissolved CFC-11, 2% or 0.005 pmol kg-1 (whichever is

greater) for dissolved CFC-12 measurements (see listing of replicate samples given in

Table 6), 4.4% or 0.002 pmol kg-1 for CFC-113 and 1.4% or 0.006 pmol kg-1 for CCl4

(Table 7). The results of the CFC air measurements are reported in Tables 8 and 9.

A number of water samples had clearly anomalous concentrations relative to adjacent

samples for one or more of the trace gases. These anomalous samples appeared to occur

more or less randomly during the cruise, and were not clearly associated with other

features in the water column (e.g. elevated oxygen concentrations, salinity or temperature

features, etc.). This suggests that the high values were due to individual, isolated lowlevel CFC contamination events. Measured concentrations for these samples are included

in this report, but are given a quality flag of either 3 (questionable measurement) or 4

(bad measurement). A total of 4 analyses of CFC-11, 8 analyses of CFC-12, 3 analyses of

CFC-113 and 2 analyses of CCl4 were assigned a flag of 3. A total of 9 analyses of CFC11, 8 analyses of CFC-12, 18 analyses of CFC-113 and 4 analyses of CCl4 were assigned

a value of 4.
19

2.3. UNDERWAY MEASUREMENT METHODS

2.3.1. UNDERWAY fCO2

Underway pCO2 system version 2.5 (analogous to those described in Ho et al. 1997, and

Feely et al. 1998) was used to determine the pCO2 of surface water and overlaying air on

a continuous basis (Keeling 1965, Wanninkhof and Thoning 1993). When in operation,

seawater is drawn from the uncontaminated seawater intake from the bow intake

approximately 6 meters below the water line to a 30-l shower head equilibrator located in

the main laboratory, where the headspace and seawater reach equilibrium on a short time

scale. At specific times during an hourly cycle, the content of the headspace is measured

by an infrared CO2 analyzer. Uncontaminated air from the marine boundary layer is

drawn continuously from the bow mast to the underway pCO2 system. At a designated

time, air is analyzed by a the infrared CO2 analyzer, otherwise the air is bled off through a

vent .

The CO2 measurements are made by a Li-Cor differential, non-dispersive, infrared

(NDIR) CO2 analyzer (model 6251), and the result is based on the difference in

absorption of infrared (IR) radiation passing through two gas cells. The reference cell is

continuously flushed with a gas of known CO2 concentration using the lowest

concentration of three reference gas standards. During the hourly cycle the sample cell is

flushed with one of three reference gas standards, marine boundary layer air, or

headspace gas from the equilibrator.

The data may be downloaded via WWW site:

http://www.aoml.noaa.gov/ocd/oaces/1998data.html

3. ACKNOWLEDGMENTS

The dedication and assistance of the officers and crew of the NOAA Ship RONALD H.

BROWN is gratefully appreciated and hereby acknowledged. This research was

supported by the Ocean Atmospheric Carbon Exchange Study (OACES) and the World

Ocean Circulation Experiment (WOCE). We wish to acknowledge the OACES program

managers Drs. James Todd and Lisa Dilling for supporting the field program.
20

4. REFERENCES

Bradshaw, A. L. and Brewer, P. G., 1988. High precision measurements of alkalinity and

total carbon dioxide in seawater by potentiometric titration-1. Presence of 

unknown protolyte(s)?, Mar. Chem., 23, 69-86.

Bullister, J.L. and R.F. Weiss, 1988. Determination of CCl3F and CCl2F2 in seawater

and air. Deep-Sea Research, 35 (5), 839-853.

Bullister, J.L., 1984. Anthropogenic Chlorofluoromethanes as Tracers of Ocean

Circulation and Mixing Processes: Measurement and Calibration Techniques and

Studies in the Greenland and Norwegian Seas, Ph.D. dissertation, Univ. Calif. San

Diego, 172 pp.

Byrne, R. H., 1987. Standardization of standard buffers by visible spectrometry. Anal.

Chem., 59, 1479-1481.

Carlson, C.A., Bates, N.R., Ducklow, H.W. and Hansell, D.A.. 1999. Estimations of

bacterial respiration and growth efficiencies in the Ross Sea, Antarctica. Aquatic

Microbial Ecology 19: 229-244.

Clayton T. and Byrne, R. H., 1993. Calibration of m-cresol purple on the total 

hydrogen ion concentration scale and its application to CO2-system

characteristics in seawater, Deep Sea Res., 40, 2115-2129.

Cunnold, D.M., Fraser, P.J., Weiss, R.F., Prinn, R.G., Simmonds, P.G., Miller, B.R.,

Alyea, F.N., and Crawford, A.J., 1994. Global trends and annual releases of CCl3F

and CCl2F2 estimated from ALE/GAGE and other measurements from July 1978

to June 1991. J. Geophys. Res., 99, 1107-1126.

Dickson, A.G. and Millero, F.J., 1987. A comparison of the equilibrium constants for the

dissociation of carbonic acid in seawater media, Deep-Sea Res., 34, 1733-1743

Dickson, A.G., 1981. An exact definition of total alkalinity and a procedure for the

estimation of alkalinity and total CO2 from titration data. Deep-Sea Res., 28, 609ñ

623.

DOE, 1994. Handbook of methods for the analysis of the various parameters of the

carbon dioxide system in sea water, version 2.0 (A. Dickson and C. Goyet, eds.).

Feely, R.A., Wanninkhof, R., Milburn, H.B., Cosca, C.E., Stapp, M., and Murphy, P.P.,

1998. A new automated underway system for making high precision pCO2

measurements aboard research ships. Anal. Chim. Acta, 377, 185 - 191.
21

Friederich, G.E., Codispoti, L.A., and Sakamoto, C.M., 1991. An easy-to-construct

automated Winkler titration system. MBARI Tech. Rep. 91-6.

Grasshoff, K., Ehrhardt, M, and Kremling, K., 1983. Methods of seawater analysis.

Weinheim, Verlag Chemie.

Hansell, D.A. and Peltzer, E.T., 1998. Spatial and temporal variations of total organic

carbon in the Arabian Sea. Deep-Sea Research II 45: 2171-2193.

Ho, D. T., Wanninkhof, R., Masters, J., Feely, R.A., Cosca, C., 1997. Measurements of

Underway fCO2, in the Eastern Equatorial Pacific on NOAA Ships MALCOLM

BALDRIGE and DISCOVERER from February to September, 1994. NOAA

Data Report ERL AOML-30, 52pp.

Johnson, K.M., Wills, K.D., Butler, D.B., Johnson, W.K., and Wong C.S., 1993.

Coulometric total carbon dioxide analysis for marine studies: Maximizing the

performance of an automated continuous gas extraction system and coulometric

detector. Mar. Chem., 44, 167ñ189.

Johnson, K.M., 1992 Operatorís manual: Single operator multiparameter metabolic

analyzer (SOMMA) for total carbon dioxide (CT) with coulometric detection.

Brookhaven National Laboratory, Brookhaven, N.Y., 70 pp.

Johnson, K.M., Williams, P.J., Brandstrom, L., and Sieburth J. McN., 1987. Coulometric

total carbon analysis for marine studies: Automation and calibration. Mar. Chem.,

21, 117ñ133.

Johnson, K.M., King, A.E., and Sieburth, J. McN., 1985. Coulometric DIC analyses

 formarine studies: An introduction. Mar. Chem., 16, 61ñ82.

Keeling C. D., 1965. Carbon dioxide in surface waters of the Pacific Ocean 2.

Calculation of the exchange with the atmosphere. J. Geophys. Res. 70, 6099-

6102.

Knap, A. H., Michaels, A.F., Steinberg, D., Bahr, F., Bates, N.R., Bell, S., Countway, P.,

Close, A., Doyle, A., Howse, F., Gundersen, K., Johnson, R., Little, R., Orcutt,

K., Parsons, R., Rathbun, C., Sanderson, M., Stone, S., 1997. BATS methods

manual. U.S. JGOFS Planning Office, Woods Hole.
22

Kroopnick, P., 1974. The dissolved O2-CO2-

13C system in the equatorial Pacific,

Deep-Sea Res., 21, 211-227.

Marinenko, G., and Taylor, J.K., 1968. Electrochemical equivalents of benzoic and oxalic

acid. Anal. Chem., 40, 1645ñ1651.

McTaggart, K.E., Johnson, G.C., Fleurant, C.I., and Baringer, M.O., 1999. CTD/O2

measurements collected on a Climate and Global Change cruise along 24°N in

the Atlantic Ocean (WOCE section A62

) during January-February 1998. NOAA

Data Report, ERL PMEL-68 (PB99-155194), 368 pp.

Mehrbach, C., Culberson, C.H., Hawley, J.E., and Pytkowicz, R.M., 1973. Measurements

of the apparent dissociation constants of carbonic acid in seawater at atmospheric

pressure, Limnol. Oceanogr., 18, 897-907.

Millero, F. J., Zhu, X., Liu, X., Roche, M. P., Moore, C., Jolliff, J., 2000. The pH and TA

along 24  ̊North in the Atlantic Ocean. University of Miami Technical Report No.

RSMAS-2000-03, 41 pp.

Millero, F. J., Zhang, J. Z., Lee, K., and Campbell, D. M., 1993. Titration alkalinity of 

seawater, Mar. Chem., 44, 153-16.

Neill, C., Johnson, K.M., Lewis, E., and Wallace, D.W.R., 1997. Accurate

headspace analysis of fCO2 in discrete water samples using batch equilibration.

Limnol. Oceanogr., 42(8), 1774-1783

Quay P.D., Tilbrook, B., and Wong, C.S., 1992. Ocean uptake of fossil fuel CO2: Carbon13 evidence, Science, 256, 74-79.

Taylor, J.K., and Smith S.W., 1959. Precise coulometric titration of acids and bases. J.

Res. Natl. Bur. Stds., 69A, 153ñ159.

Wanninkhof R. and Thoning K., 1993. Measurement of fugacity of CO2 in surface water

using continuous and discrete sampling methods. Mar. Chem., 44, 189-205.

Weiss, R.F., 1970. The solubility of nitrogen, oxygen and argon in water and seawater.

Deep-Sea Res., 17, 721-735.

Wilke, R.J., Wallace, D.W.R., and Johnson, K.M., 1993. Water-based gravimetric

method for the determination of gas loop volume. Anal. Chem. 65, 2403ñ2406.

 

2

 Note, the WOCE designation in the report title is incorrect.
23

Zhang, J-Z., Fischer C., and Ortner, P. B., 2000. Comparison of open tubular cadmium

reactor and packed cadmium column in automated gas-segmented continuous

flow nitrate analysis. International Journal of Environmental Analytical

Chemistry, 76(2):99-113.

Zhang, J-Z., Ortner P. B., and Fischer, C., 1997a. Determination of nitrite and nitrate in

estuarine and coastal waters by gas segmented continuous flow colorimetric

analysis. EPA's manual " Methods for the determination of Chemical Substances

in Marine and Estuarine Environmental Matrices - 2nd Edition". EPA/600/R97/072.

Zhang, J-Z., and Berberian, G. A., 1997b. Determination of dissolved silicate in

estuarine and coastal waters by gas segmented continuous flow colorimetric

analysis. EPA's manual " Methods for the determination of Chemical Substances

in Marine and Estuarine Environmental Matrices - 2nd Edition". EPA/600/R97/072.
24

 Figure 1. Cruise track for the Atlantic Ocean

 A5R(epeat) cruise in January and

 February 1998







 Table 1. Station locations

Station Cast Latitude Longitude Date

(

oN) (oW)

1 1 27.917 13.370 1/24/1998

2 1 27.965 13.404 1/24/1998

3 1 27.883 13.417 1/24/1998

4 1 27.849 13.417 1/24/1998

5 1 27.799 13.816 1/24/1998

6 1 27.617 14.235 1/24/1997

7 1 27.433 14.851 1/24/1998

8 1 27.232 15.596 1/25/1998

9 1 27.032 16.115 1/25/1998

10 1 26.833 16.668 1/25/1998

11 1 26.667 17.199 1/25/1998

12 1 26.517 17.867 1/25/1998

13 1 26.498 18.335 1/26/1998

14 1 26.167 18.817 1/26/1998

15 1 25.983 19.365 1/26/1998

16 1 25.800 19.899 1/26/1998

17 1 25.617 20.433 1/26/1998

18 1 25.424 20.949 1/27/1998

19 1 25.250 21.484 1/27/1998

20 1 25.057 22.032 1/27/1998

21 1 24.783 22.800 1/28/1998

22 1 24.500 23.484 1/28/1998

23 1 24.499 24.216 1/28/1998

24 1 24.500 24.950 1/28/1998

25 1 24.500 25.683 1/28/1997

26 1 24.500 26.416 1/29/1998

27 1 24.499 27.150 1/29/1998

28 1 24.500 27.883 1/29/1998

29 1 24.499 28.617 1/30/1998

30 1 24.499 29.433 1/30/1998

31 1 24.500 30.267 1/30/1998

32 1 24.500 31.084 1/31/1998

33 1 24.500 31.916 1/31/1998

34 1 24.500 32.733 1/31/1998

35 1 24.498 33.567 2/1/1998

 32
 Table 1. Station locations (continued)

Station Cast Latitude Longitude Date

(

oN) (oW)

36 1 24.502 34.383 2/1/1998

37 1 24.500 35.217 2/1/1998

38 1 24.500 36.033 2/2/1998

39 1 24.500 36.867 2/2/1998

40 1 24.500 37.683 2/2/1998

41 1 24.500 38.513 2/2/1998

42 1 24.500 39.250 2/3/1998

43 1 24.500 39.983 2/3/1998

44 1 24.500 40.533 2/3/1998

45 1 24.500 41.083 2/4/1998

46 1 24.500 41.633 2/4/1998

47 1 24.500 42.183 2/4/1998

48 1 24.500 42.733 2/4/1998

49 1 24.500 43.284 2/4/1998

50 1 24.500 43.473 2/5/1998

51 1 24.500 44.386 2/5/1998

52 1 24.500 44.934 2/5/1998

53 1 24.500 45.484 2/5/1998

54 1 24.500 46.034 2/5/1998

55 1 24.500 46.584 2/6/1998

56 1 24.500 47.134 2/6/1998

57 1 24.501 47.684 2/6/1998

58 1 24.500 48.234 2/6/1998

59 1 24.500 48.782 2/7/1998

60 1 24.500 49.333 2/7/1998

61 1 24.491 49.883 2/7/1998

62 1 24.501 50.433 2/8/1998

63 1 24.501 50.984 2/8/1998

64 1 24.501 51.533 2/8/1998

65 1 24.500 51.149 2/9/1998

66 1 24.501 52.637 2/9/1998

67 1 24.499 53.183 2/9/1998

68 1 24.500 53.733 2/9/1998

69 1 24.499 54.467 2/10/1998

70 1 24.499 55.201 2/10/1998

 33
 Table 1. Station locations (continued)

Station Cast Latitude Longitude Date

(

oN) (oW)

71 1 24.500 55.933 2/10/1998

72 1 24.500 56.667 2/11/1998

73 1 24.500 57.400 2/11/1998

74 1 24.500 58.134 2/11/1998

75 1 24.500 58.867 2/12/1998

76 1 24.500 59.600 2/12/1998

77 1 24.500 60.332 2/12/1998

78 1 24.500 60.067 2/12/1998

79 1 24.500 61.801 2/13/1998

80 1 24.500 63.534 2/13/1998

81 1 24.499 63.264 2/13/1998

82 1 24.500 64.000 2/14/1998

83 1 24.500 64.667 2/14/1998

84 1 24.501 65.469 2/14/1998

85 1 24.500 65.200 2/15/1998

86 1 24.500 66.933 2/15/1998

87 1 24.500 67.667 2/15/1998

88 1 24.500 68.401 2/15/1998

89 1 24.500 69.133 2/16/1998

90 1 25.016 69.502 2/16/1998

91 1 25.383 69.867 2/16/1998

92 1 25.759 70.235 2/17/1998

93 1 26.141 70.615 2/17/1998

94 1 26.501 71.012 2/17/1998

95 1 26.500 71.351 2/17/1998

96 1 26.500 71.734 2/18/1998

97 1 26.501 72.100 2/18/1998

98 1 26.501 72.467 2/18/1998

99 1 26.500 72.850 2/18/1998

100 1 26.500 73.217 2/18/1998

101 1 26.500 73.583 2/19/1998

102 1 26.500 73.967 2/19/1998

103 1 26.500 74.251 2/19/1998

104 1 26.500 74.517 2/19/1998

105 1 26.500 74.800 2/19/1998

 34
 Table 1. Station locations (continued)

Station Cast Latitude Longitude Date

(

oN) (oW)

106 1 26.500 75.084 2/20/1998

107 1 26.500 75.300 2/20/1998

108 1 26.500 75.500 2/20/1998

109 1 26.500 75.701 2/20/1998

110 1 26.500 75.900 2/20/1998

111 1 26.500 76.083 2/20/1998

112 1 26.500 76.200 2/21/1998

113 1 26.483 76.300 2/21/1998

114 1 26.505 76.422 2/21/1998

115 1 26.500 76.517 2/21/1998

116 1 26.500 76.617 2/21/1998

117 1 26.500 76.683 2/22/1998

118 1 26.499 76.753 2/22/1998

119 1 26.500 76.784 2/22/1998

120 1 26.500 76.816 2/22/1998

121 1 26.520 76.901 2/22/1998

122 1 27.001 79.200 2/23/1998

123 1 27.002 79.283 2/23/1998

124 1 27.001 79.381 2/23/1998

125 1 27.038 79.481 2/23/1998

126 1 27.013 79.605 2/23/1998

127 1 27.020 79.674 2/23/1998

128 1 27.002 79.788 2/23/1998

129 1 27.006 79.857 2/23/1998

130 1 26.999 79.937 2/23/1998

 35
 Table 2. Results of the certified reference material, CRM

(Assigned value by SIO batch 40 = (1985.8 ± 0.7) μmol/kg)

Coulometer: PMEL-1

Date GMT Year Day DIC

(h:min) (μmol/kg)

24-Jan-98 16:02 24 1987.0

25-Jan-98 0:41 25 1981.2

25-Jan-98 4:47 25 1987.0

25-Jan-98 15:19 25 1986.7

26-Jan-98 4:29 26 1987.9

26-Jan-98 18:48 26 1987.3

27-Jan-98 7:36 27 1987.1

27-Jan-98 21:31 27 1987.9

28-Jan-98 9:37 28 1985.9

28-Jan-98 22:19 28 1985.6

29-Jan-98 9:02 29 1988.1

29-Jan-98 23:31 29 1986.4

30-Jan-98 22:36 30 1986.6

31-Jan-98 22:11 31 1985.8

1-Feb-98 9:06 32 1985.1

2-Feb-98 6:16 33 1986.2

2-Feb-98 21:23 33 1985.5

3-Feb-98 11:32 34 1988.3

4-Feb-98 4:54 35 1985.8

4-Feb-98 19:43 35 1988.0

5-Feb-98 7:07 36 1988.3

5-Feb-98 21:35 36 1986.7

6-Feb-98 8:47 37 1985.4

6-Feb-98 21:16 37 1986.3

7-Feb-98 7:48 38 1986.5

7-Feb-98 18:14 38 1988.1

8-Feb-98 5:50 39 1987.9

8-Feb-98 17:42 39 1990.8

8-Feb-98 18:36 39 1991.2

 36
 Table 2. Results of the certified reference material, CRM (continued)

(Assigned value by SIO batch 40 = (1985.8 ± 0.7) μmol/kg)

Coulometer: PMEL-1

Date GMT Year Day DIC

(h:min) (μmol/kg)

9-Feb-98 4:39 40 1983.6

9-Feb-98 17:46 40 1988.6

10-Feb-98 6:53 41 1985.9

10-Feb-98 22:02 41 1986.2

11-Feb-98 13:17 42 1984.9

12-Feb-98 4:52 43 1985.8

12-Feb-98 19:40 43 1985.1

13-Feb-98 9:40 44 1985.3

14-Feb-98 9:27 45 1994.2

14-Feb-98 10:25 45 1992.0

14-Feb-98 19:54 45 1988.4

15-Feb-98 4:46 46 1987.5

15-Feb-98 19:09 46 1986.8

16-Feb-98 17:09 47 1987.7

17-Feb-98 3:02 48 1988.4

17-Feb-98 12:21 48 1988.9

18-Feb-98 4:13 49 1987.5

18-Feb-98 18:30 49 1988.3

19-Feb-98 5:36 50 1989.1

19-Feb-98 14:48 50 1988.3

20-Feb-98 5:01 51 1987.7

20-Feb-98 13:07 51 1988.3

21-Feb-98 0:18 52 1987.0

21-Feb-98 13:12 52 1988.1

22-Feb-98 2:59 53 1988.4

22-Feb-98 16:47 53 1987.7

23-Feb-98 3:41 54 1987.4

23-Feb-98 10:54 54 1986.1

 37
 Table 2. Results of the certified reference material, CRM (continued)

(Assigned value by SIO batch 40 = (1985.8 ± 0.7) μmol/kg)

Coulometer: PMEL-2

Date GMT Year Day DIC

(h:min) (μmol/kg)

22-Jan-98 15:02 22 1984.2

22-Jan-98 15:16 22 1983.1

24-Jan-98 1:39 24 1986.2

24-Jan-98 6:19 24 1986.5

24-Jan-98 15:19 24 1985.3

25-Jan-98 1:02 25 1985.7

25-Jan-98 12:58 25 1986.7

25-Jan-98 23:54 25 1986.6

26-Jan-98 11:18 26 1985.9

26-Jan-98 22:56 26 1985.0

27-Jan-98 11:22 27 1986.6

27-Jan-98 23:46 27 1984.7

28-Jan-98 12:28 28 1985.7

28-Jan-98 21:53 28 1984.8

29-Jan-98 8:57 29 1984.2

29-Jan-98 23:35 29 1985.1

30-Jan-98 12:19 30 1985.4

30-Jan-98 23:14 30 1983.8

31-Jan-98 11:51 31 1983.9

1-Feb-98 4:27 32 1984.1

1-Feb-98 18:18 32 1984.7

2-Feb-98 8:21 33 1985.5

3-Feb-98 1:09 34 1985.5

3-Feb-98 13:40 34 1985.4

4-Feb-98 0:49 35 1984.5

4-Feb-98 13:06 35 1983.7

4-Feb-98 23:48 35 1984.6

5-Feb-98 13:50 36 1984.1

6-Feb-98 2:55 37 1984.2

 38
 Table 2. Results of the certified reference material, CRM (continued)

(Assigned value by SIO batch 40 = (1985.8 ± 0.7) μmol/kg)

Coulometer: PMEL-2

Date GMT Year Day DIC

(h:min) (μmol/kg)

6-Feb-98 16:49 37 1986.2

7-Feb-98 2:25 38 1983.6

7-Feb-98 9:08 38 1983.6

7-Feb-98 17:03 38 1984.2

8-Feb-98 3:00 39 1983.5

8-Feb-98 12:46 39 1987.5

9-Feb-98 4:50 40 1983.7

9-Feb-98 15:56 40 1985.3

10-Feb-98 7:15 41 1987.2

10-Feb-98 19:42 41 1984.3

11-Feb-98 13:58 42 1983.8

12-Feb-98 0:04 43 1983.8

12-Feb-98 19:06 43 1983.6

13-Feb-98 4:42 44 1984.4

13-Feb-98 16:36 44 1984.8

14-Feb-98 4:10 45 1983.7

14-Feb-98 13:23 45 1984.0

15-Feb-98 3:48 46 1984.6

15-Feb-98 14:02 46 1981.7

15-Feb-98 14:42 46 1982.8

16-Feb-98 0:12 47 1983.7

16-Feb-98 20:14 47 1984.1

17-Feb-98 7:55 48 1984.2

17-Feb-98 18:25 48 1982.8

18-Feb-98 2:52 49 1984.4

18-Feb-98 15:04 49 1983.8

19-Feb-98 2:04 50 1983.0

19-Feb-98 13:42 50 1985.3

19-Feb-98 21:50 50 1983.8

 39
 Table 2. Results of the certified reference material, CRM (continued)

(Assigned value by SIO batch 40 = (1985.8 ± 0.7) μmol/kg)

Coulometer: PMEL-2

Date GMT Year Day DIC

(h:min) (μmol/kg)

20-Feb-98 8:11 51 1984.3

20-Feb-98 20:36 51 1983.8

21-Feb-98 8:47 52 1986.8

21-Feb-98 18:37 52 1984.5

22-Feb-98 4:37 53 1984.1

22-Feb-98 16:08 53 1984.0

23-Feb-98 4:18 54 1985.9

 40
 Table 3. Dissolved inorganic carbon duplicates

Station# Bottle# Pressure/db DIC Stdev

μmol/kg

1 9 2 2119.7 0.26

3 20 2 2103.9 0.33

4 22 4 2100.8 0.47

5 7 995 2209.6 1.75

5 27 3 2105.0 0.47

6 30 3 2096.4 0.12

7 31 3 2096.4 0.95

9 32 4 2097.8 1.27

11 16 1001 2205.0 0.23

12 36 4 2098.4 0.95

13 17 1001 2212.5 0.69

13 35 4 2099.4 1.70

14 32 3 2100.1 0.98

15 17 1000 2209.1 0.82

15 36 4 2086.9 0.81

18 36 4 2100.1 1.52

19 18 1000 2212.8 0.44

19 36 5 2101.0 0.41

20 36 6 2099.1 0.06

21 19 1000 2207.9 0.16

21 36 6 2098.6 0.08

22 36 4 2096.7 0.45

23 36 5 2098.3 1.67

24 36 3 2096.2 0.18

25 36 4 2099.6 1.14

26 36 6 2098.6 0.98

30 18 1000 2200.1 1.39

31 18 1000 2200.6 1.88

32 36 6 2101.8 0.42

36 36 5 2094.6 0.13

37 20 1002 2200.4 0.40

 41
 Table 3. Dissolved inorganic carbon duplicates (continued)

Station# Bottle# Pressure/db DIC Stdev

(db) (μmol/kg)

38 36 4 2090.6 0.35

40 36 4 2087.9 0.84

41 19 999 2200.8 0.45

41 36 6 2085.0 0.76

42 36 3 2076.3 0.84

43 17 1000 2195.0 1.90

43 36 4 2080.1 0.86

46 36 4 2081.0 0.83

49 20 997 2194.9 1.15

50 36 5 2077.0 0.01

51 19 1001 2193.5 0.78

51 36 5 2073.1 0.37

53 18 1001 2197.6 1.10

55 36 5 2073.1 0.33

56 36 5 2075.5 0.07

57 36 5 2072.2 1.03

59 17 1000 2197.5 1.63

60 36 4 2075.7 0.90

61 36 4 2064.1 0.16

62 18 999 2194.8 1.41

62 36 3 2066.6 0.18

65 36 6 2065.9 0.46

67 36 5 2050.1 1.62

68 36 4 2056.2 0.03

69 36 4 2060.2 0.25

70 18 1000 2195.2 0.91

70 36 5 2056.3 1.32

71 36 6 2046.5 0.43

72 36 4 2046.1 0.08

73 17 1000 2195.1 0.01

73 36 4 2044.4 0.23

 42
 Table 3. Dissolved inorganic carbon duplicates (continued)

Station# Bottle# Pressure/db DIC Stdev

(db) (μmol/kg)

74 36 7 2033.7 1.69

75 36 5 2041.7 0.27

76 36 6 2038.2 0.99

77 36 5 2037.6 1.61

78 36 7 2035.3 0.39

79 36 5 2035.2 0.38

80 36 6 2023.7 0.07

81 36 4 2016.1 0.76

82 36 4 2036.6 0.48

83 36 4 2041.5 0.26

84 36 6 2036.9 1.46

85 36 4 2017.7 0.16

86 17 999 2202.1 0.01

86 36 4 2018.4 0.79

87 36 5 2028.5 0.73

88 36 5 2032.7 0.72

89 17 1001 2179.8 1.17

90 16 1001 2186.1 0.71

90 36 4 2037.9 0.34

94 36 4 2034.8 0.33

95 36 4 2035.4 0.54

98 36 4 2043.1 0.89

99 36 5 2042.8 0.93

101 18 1001 2191.6 1.88

101 36 4 2042.2 0.96

102 18 999 2187.3 0.54

102 36 5 2047.7 0.18

106 36 4 2041.5 0.79

107 36 4 2041.6 0.11

110 36 4 2037.3 0.85

111 36 4 2039.0 0.06

 43
 Table 3. Dissolved inorganic carbon duplicates (continued)

Station# Bottle# Pressure/db DIC Stdev

(db) (μmol/kg)

112 18 999 2190.4 1.20

113 36 3 2040.1 1.11

114 36 4 2040.5 1.41

117 36 3 2036.4 0.49

118 15 999 2185.3 1.56

121 18 5 2023.1 0.45

122 18 4 2014.1 0.45

123 20 3 2013.4 0.81

124 21 4 2006.8 0.63

125 23 4 2007.7 0.47

126 21 3 2011.0 0.04

127 20 4 2016.7 0.16

129 11 4 2026.3 0.13

 44
 Table 4. Replicate pCO2

 analyses

Station Bottle Latitude Longitude Depth Ave (fCO2,20C) Stdev(fCO2,20C)

 (oN) (oW) (m) (μatm) (μatm)

2 10 28 13 149 480.1 2.05

6 30 28 14 3 361.7 5.59

7 12 27 15 849 881.1 3.11

8 17 27 16 847 803.0 5.23

8 33 27 16 3 344.1 0.14

10 32 27 17 117 392.5 6.79

13 15 26 18 1201 863.0 0.71

14 17 26 19 800 950.8 3.11

18 16 25 21 1229 827.3 0.57

19 18 25 21 1000 953.0 4.60

21 3 25 23 4499 752.0 0.64

22 26 25 23 449 691.3 1.63

23 10 24 24 2879 743.1 7.14

24 36 25 25 3 338.1 4.17

25 13 25 26 2497 733.8 4.88

27 36 24 27 4 318.4 2.83

28 18 25 28 1201 854.9 5.52

30 18 24 29 1000 872.6 11.88

30 30 24 29 248 418.4 0.28

34 5 25 33 4589 531.7 318.83

34 12 25 33 2401 741.1 2.69

34 14 25 33 2002 746.4 3.61

38 17 25 36 1250 831.4 13.65

39 12 25 37 2096 735.1 0.71

40 36 25 38 4 312.2 8.56

42 14 25 39 1999 742.9 7.78

43 8 25 40 2949 680.4 13.08

45 5 25 41 4051 706.1 5.16

45 13 25 41 2050 685.9 10.82

46 4 25 42 4000 691.8 7.99

 45
 Table 4. Replicate pCO2

 analyses (continued)

Station Bottle Latitude Longitude Depth Ave (fCO2,20C) Stdev(fCO2,20C)

 (oN) (oW) (m) (μatm) (μatm)

47 5 25 42 3098 712.2 27.79

47 9 25 42 2092 676.5 7.07

48 36 25 43 7 289.9 29.63

49 5 25 43 3201 715.0 7.42

49 10 25 43 2198 698.2 2.97

50 5 25 43 3092 704.4 10.68

51 14 25 44 1500 743.3 25.24

51 34 25 44 100 253.7 0.64

52 36 25 45 7 316.9 44.90

53 8 25 45 2000 711.8 13.22

53 19 25 45 901 851.9 4.95

53 36 25 45 6 267.9 18.10

54 36 25 46 5 272.3 10.25

55 9 25 47 1999 726.2 8.13

56 36 25 47 5 283.8 1.41

57 36 25 48 5 278.4 0.71

58 20 25 48 902 844.0 15.06

58 21 25 48 802 777.8 17.96

58 22 25 48 700 689.0 20.36

58 29 25 48 276 385.5 11.74

58 36 25 48 5 262.5 18.60

59 36 25 49 4 277.7 1.84

60 36 25 49 4 278.2 25.31

61 36 24 50 4 274.1 2.40

62 36 25 50 3 274.1 2.26

64 1 25 52 5363 733.8 8.27

65 36 25 51 6 276.4 1.70

66 16 25 53 1248 809.2 5.16

67 6 24 53 3999 743.7 6.01

67 13 24 53 1951 725.5 15.77

 46
 Table 4. Replicate pCO2

 analyses (continued)

Station Bottle Latitude Longitude Depth Ave (fCO2,20C) Stdev(fCO2,20C)

 (oN) (oW) (m) (μatm) (μatm)

67 20 24 53 802 784.3 0.57

67 30 24 53 248 380.8 4.81

67 36 24 53 5 261.1 10.32

68 35 25 54 3 266.5 6.23

69 19 24 54 1051 848.9 5.80

70 1 24 55 6008 798.2 5.09

70 16 24 55 1402 743.8 1.20

70 36 24 55 5 260.2 4.24

71 2 25 56 6050 794.8 4.03

72 36 25 57 4 275.5 2.05

73 12 25 57 1900 721.2 7.35

74 6 25 58 3900 730.5 4.95

75 36 25 59 5 276.2 6.43

76 36 25 60 6 272.2 0.07

77 4 25 60 4698 691.1 67.18

79 1 25 62 5891 794.9 3.68

80 36 25 64 6 263.6 3.04

81 6 24 63 3966 736.2 2.40

82 1 25 64 5862 785.8 3.11

82 16 25 64 1049 840.5 1.48

83 13 25 65 1851 708.1 4.95

84 36 25 65 6 275.6 1.56

85 13 25 65 2101 720.4 8.41

86 1 25 67 5816 792.9 4.95

86 26 25 67 400 446.3 3.96

87 2 25 68 5291 784.6 4.81

88 36 25 68 5 275.1 0.35

89 1 25 69 5736 789.8 7.92

90 4 25 70 4450 740.8 9.55

91 36 25 70 5 283.8 0.49

 47
 Table 4. Replicate pCO2

 analyses (continued)

Station Bottle Latitude Longitude Depth Ave (fCO2,20C) Stdev(fCO2,20C)

 (oN) (oW) (m) (μatm) (μatm)

94 3 27 71 4840 733.1 7.78

94 30 27 71 225 374.2 5.87

95 36 27 71 4 282.4 3.61

97 11 27 72 1998 725.7 3.46

98 1 27 72 5263 762.5 5.37

99 36 27 73 5 285.4 1.84

101 36 27 74 4 294.5 0.28

102 25 27 74 349 376.2 2.19

103 36 27 74 4 297.7 1.56

107 36 27 75 4 292.8 3.32

108 1 27 76 4751 748.1 6.22

110 34 27 76 96 301.3 3.25

111 36 27 76 4 285.8 0.42

113 36 26 76 3 287.6 3.32

114 3 27 76 4100 735.0 3.11

115 36 27 77 4 289.3 1.06

116 3 27 77 4188 736.3 5.37

117 36 27 77 3 288.9 1.70

120 3 27 77 1300 765.7 9.69

121 3 27 77 351 412.4 3.75

123 20 27 79 3 282.8 5.30

124 21 27 79 4 276.3 2.19

126 21 27 80 3 278.2 1.91

127 20 27 80 4 281.4 1.48

130 6 28 80 3 304.9 2.62

 48
Table 5. Correction factors applied to raw data based upon carbonate 

 parameters for Certified Reference Materials

CRM TA pH

(μmol/kg)

Batch #40 2196.4 7.91

CELL TA pH

(μmol/kg)

Measured C.F. Measured C.F. N

2193.2 ± 1.2 1.001489 7.883 ± 0.004 0.026 12

2

a

2198.5 ± 1.3 0.999062 7.883 ± 0.005 0.027 19

2193.0 ± 1.3 1.001547 7.872 ± 0.004 0.039 11

12 2194.7 ± 2.7 1.000779 7.875 ± 0.006 0.035 4

18b

2200.3 ± 3.0 0.998228 7.874 ± 0.002 0.032 10

21 2198.9 ± 0.9 0.998863 7.859 ± 0.005 0.051 48

a. Three slightly different correction factors were applied to cell 2 due to the change in volume

 from a broken piston.

b. The weighted average was used

TAcorr = TAsample x C.F. (TA)

pHcorr = pHsample + C.F.(pH)

49
 Table 6. Replicate dissolved CFC-11 and CFC-12 analyses

Station Bottle CFC-11 CFC-11 CFC-12 CFC-12

(pmol/kg) Stdev (pmol/kg) Stdev

3 9 2.227 0.025 1.189 0.005

5 6 0.184 0.006 0.092 0.004

7 14 0.814 0.012 0.415 0.001

7 28 2.348 0.018 1.325 0.009

8 27 2.403 0.040 1.319 0.016

9 6 0.012 0.005 0.012 0.001

9 30 2.253 0.021 1.306 0.032

11 12 0.147 0.004 0.092 0.013

11 18 0.468 0.002 0.242 0.003

11 33 2.228 0.010 1.295 0.009

13 28 2.352 0.013 1.301 0.002

14 6 0.001 0.003 -9.000 -9.000

14 32 2.159 0.018 1.221 0.010

16 19 0.141 0.001 -9.000 -9.000

16 30 2.286 0.008 1.305 0.001

19 5 0.008 0.000 0.005 0.001

19 29 2.445 0.008 1.310 0.027

21 19 0.135 0.005 0.077 0.006

22 5 0.004 0.001 -0.001 0.003

22 17 0.030 0.006 0.010 0.004

22 34 2.088 0.004 1.401 0.003

24 1 0.003 0.001 0.001 0.001

24 18 0.054 0.001 0.031 0.004

24 22 0.144 0.000 0.085 0.003

24 35 2.247 0.030 1.407 0.013

26 2 -0.001 0.001 0.000 0.001

26 12 0.007 0.000 -9.000 -9.000

26 14 0.010 0.003 0.003 0.002

26 24 2.161 0.019 1.132 0.006

26 35 1.978 0.013 1.143 0.010

28 9 -0.002 0.001 -0.002 0.001

28 17 0.039 0.001 0.021 0.001

28 22 0.652 0.011 0.331 0.002

28 30 2.358 0.016 1.324 0.012

29 2 0.002 0.001 -0.004 0.006

29 23 1.609 0.001 0.827 0.001

30 1 0.000 0.000 -0.003 0.002

30 19 0.143 0.001 0.078 0.004

30 28 2.370 0.018 1.294 0.009

30 35 2.015 0.012 1.167 0.008

31 30 2.372 0.006 1.317 0.007

32 1 -0.002 0.000 -0.001 0.004

32 20 0.137 0.000 0.064 0.004

32 34 2.033 0.007 1.172 0.001

 50
 Table 6. Replicate dissolved CFC-11 and CFC-12 analyses (continued)

Station Bottle CFC-11 CFC-11 CFC-12 CFC-12

(pmol/kg) Stdev (pmol/kg) Stdev

34 21 0.367 0.001 0.171 0.002

34 34 1.962 0.012 1.137 0.005

35 4 -0.001 0.000 0.004 0.001

35 18 0.055 0.001 0.025 0.001

35 33 2.310 0.026 1.316 0.008

36 2 0.001 0.001 -0.001 0.001

36 14 0.005 0.001 -0.001 0.003

36 34 1.978 0.006 1.145 0.004

37 21 0.090 0.000 0.039 0.001

37 31 2.348 0.010 1.330 0.008

38 12 0.000 0.000 -0.004 0.001

38 22 0.766 0.001 0.361 0.006

38 30 2.375 0.013 1.315 0.008

39 7 0.001 0.000 -0.004 0.002

39 24 2.049 0.008 1.064 0.001

40 1 0.003 0.001 0.002 0.001

40 22 1.307 0.016 0.641 0.004

40 28 2.361 0.001 1.297 0.004

42 4 -0.001 0.002 -0.001 0.001

42 26 2.270 0.004 1.229 0.006

42 34 2.071 0.001 1.192 0.001

44 33 2.314 0.010 1.328 0.002

46 6 -0.001 0.001 -0.001 0.004

46 20 0.567 0.001 0.275 0.001

46 32 2.266 0.034 1.288 0.016

48 1 0.003 0.001 0.003 0.001

48 3 0.001 0.000 0.003 0.004

48 20 0.138 0.002 0.067 0.004

48 31 2.253 0.014 1.277 0.021

48 34 1.908 0.008 1.098 0.000

50 1 0.001 0.000 0.001 0.001

50 20 0.920 0.003 0.466 0.002

50 30 2.310 0.064 1.269 0.062

52 14 0.123 0.000 0.067 0.001

52 23 1.566 0.004 0.810 0.002

54 4 0.023 0.001 0.016 0.005

54 16 0.109 0.001 0.057 0.002

54 28 2.306 0.015 1.262 0.013

54 34 1.937 0.007 1.106 0.011

56 23 0.801 0.008 0.426 0.001

58 1 0.015 0.001 0.016 0.003

58 14 0.117 0.001 0.067 0.006

58 23 1.506 0.017 0.781 0.011

58 32 2.278 0.021 1.290 0.006

 51
 Table 6. Replicate dissolved CFC-11 and CFC-12 analyses (continued)

Station Bottle CFC-11 CFC-11 CFC-12 CFC-12

(pmol/kg) Stdev (pmol/kg) Stdev

60 2 0.010 0.001 0.012 0.004

60 16 0.245 0.007 0.136 0.006

60 26 2.298 0.028 1.244 0.011

62 2 0.012 0.001 0.007 0.001

62 14 0.098 0.000 0.056 0.001

62 28 2.316 0.004 1.291 0.008

64 18 0.168 0.003 0.091 0.003

66 1 0.019 0.001 0.014 0.001

66 20 0.524 0.004 0.276 0.002

66 30 2.336 0.001 1.308 0.004

68 33 2.090 0.002 1.182 0.001

70 1 0.026 0.002 0.021 0.000

70 20 0.211 0.001 0.114 0.001

70 22 0.748 0.001 0.386 0.002

70 32 2.308 0.006 1.283 0.001

72 21 0.334 0.004 0.180 0.005

74 5 0.033 0.001 0.018 0.001

74 16 0.355 0.003 0.184 0.003

74 32 2.286 0.000 1.284 0.001

76 34 2.105 0.001 1.193 0.005

78 2 0.031 0.002 0.023 0.001

78 16 0.219 0.003 0.122 0.001

78 27 2.338 0.000 1.295 0.005

80 28 2.327 0.001 1.284 0.006

81 8 0.073 0.001 0.039 0.003

82 6 0.062 0.001 0.029 0.000

82 13 0.219 0.001 0.115 0.003

82 21 0.952 0.003 0.488 0.000

82 32 2.334 0.001 1.306 0.000

84 5 0.151 0.001 0.080 0.001

86 5 0.121 0.001 0.068 0.001

86 14 0.793 0.009 0.390 0.001

86 30 2.295 0.004 1.265 0.005

88 17 0.712 0.005 0.352 0.006

88 31 2.221 0.009 1.223 0.004

90 7 0.150 0.000 0.081 0.001

90 20 0.708 0.002 0.364 0.004

92 14 0.216 0.006 0.113 0.003

92 16 0.302 0.000 0.159 0.001

92 26 2.207 0.003 1.188 0.000

92 32 2.222 0.003 1.248 0.004

94 5 0.324 0.003 0.165 0.001

94 15 0.770 0.002 0.381 0.001

94 26 2.312 0.003 1.261 0.006

 52
 Table 6. Replicate dissolved CFC-11 and CFC-12 analyses (continued)

Station Bottle CFC-11 CFC-11 CFC-12 CFC-12

(pmol/kg) Stdev (pmol/kg) Stdev

96 6 0.410 0.001 0.206 0.000

96 28 2.319 0.023 1.288 0.016

98 6 0.614 0.004 0.298 0.001

98 18 0.321 0.002 0.167 0.003

98 26 2.321 0.004 1.270 0.007

100 16 0.997 0.006 0.486 0.004

100 25 2.251 0.125 1.227 0.093

102 15 0.990 0.004 0.486 0.002

102 24 2.197 0.066 1.196 0.042

104 3 0.508 0.003 0.248 0.006

104 29 2.303 0.000 1.263 0.003

106 18 0.269 0.001 0.142 0.000

108 16 0.972 0.004 0.476 0.001

108 26 2.321 0.011 1.271 0.003

110 3 0.515 0.005 0.253 0.000

110 32 2.284 0.017 1.294 0.010

112 18 0.331 0.001 0.167 0.001

112 30 2.074 0.004 1.190 0.004

114 2 0.524 0.178 0.259 0.078

114 13 1.245 0.007 0.609 0.001

114 24 2.370 0.019 1.328 0.010

116 8 0.610 0.122 0.301 0.061

116 16 1.190 0.001 0.585 0.004

116 26 2.192 0.002 1.198 0.013

118 10 0.862 0.368 0.420 0.180

118 12 1.164 0.008 0.568 0.001

118 22 2.265 0.001 1.238 0.001

120 16 1.655 0.371 0.867 0.204

120 20 2.224 0.117 1.248 0.040

125 10 1.673 0.001 0.891 0.001

125 22 1.715 0.004 1.005 0.001

129 7 2.069 0.008 1.180 0.007

 53
 Table 7. Replicate dissolved CFC-113 and CCl4

 analyses

Station Bottle CFC-113 CFC-113 CCl4 CCl4

(pmol/kg) Stdev (pmol/kg) Stdev

3 9 0.043 0.024 -9.000 -9.000

5 6 0.002 0.006 -9.000 -9.000

7 14 0.018 0.006 -9.000 -9.000

7 28 0.178 0.008 -9.000 -9.000

8 27 0.056 0.006 -9.000 -9.000

9 6 0.000 0.000 -9.000 -9.000

9 30 0.174 0.008 -9.000 -9.000

11 12 -0.003 0.001 -9.000 -9.000

11 18 0.001 0.004 -9.000 -9.000

11 33 0.156 0.008 -9.000 -9.000

13 28 0.055 0.004 -9.000 -9.000

14 6 0.000 0.000 -9.000 -9.000

14 32 0.172 0.005 -9.000 -9.000

16 19 0.000 0.000 -9.000 -9.000

16 30 0.051 0.001 -9.000 -9.000

19 5 0.001 0.001 -9.000 -9.000

19 29 0.029 0.008 -9.000 -9.000

21 19 -0.004 0.000 -9.000 -9.000

22 5 0.001 0.001 -9.000 -9.000

22 17 -0.004 0.005 -9.000 -9.000

22 34 0.157 0.008 -9.000 -9.000

24 1 -0.002 0.001 -9.000 -9.000

24 18 -0.005 0.002 -9.000 -9.000

24 22 -0.001 0.006 -9.000 -9.000

24 35 0.163 0.007 -9.000 -9.000

26 2 -0.002 0.001 -9.000 -9.000

26 12 0.006 0.001 -9.000 -9.000

26 14 0.005 0.007 -9.000 -9.000

26 24 0.023 0.004 -9.000 -9.000

26 35 0.166 0.002 -9.000 -9.000

28 9 -0.006 0.001 -9.000 -9.000

28 17 0.001 0.002 -9.000 -9.000

28 22 0.004 0.002 -9.000 -9.000

28 30 0.059 0.004 -9.000 -9.000

29 2 -0.004 0.002 -9.000 -9.000

29 23 0.015 0.005 -9.000 -9.000

30 1 -0.003 0.004 -9.000 -9.000

30 19 -0.001 0.001 -9.000 -9.000

30 28 0.031 0.005 -9.000 -9.000

30 35 0.176 0.001 -9.000 -9.000

31 30 0.039 0.002 -9.000 -9.000

32 1 -0.005 0.001 -9.000 -9.000

32 20 -0.002 0.010 -9.000 -9.000

32 34 0.160 0.011 -9.000 -9.000

 54
 Table 7. Replicate dissolved CFC-113 and CCl4

 analyses (continued)

Station Bottle CFC-113 CFC-113 CCl4 CCl4

(pmol/kg) Stdev (pmol/kg) Stdev

33 1 -9.000 -9.000 0.031 0.001

33 26 -9.000 -9.000 0.451 0.002

33 35 -9.000 -9.000 1.912 0.046

34 21 0.004 0.004 -9.000 -9.000

34 34 0.169 0.006 -9.000 -9.000

35 4 -0.003 0.000 -9.000 -9.000

35 18 -0.009 0.002 -9.000 -9.000

35 33 0.140 0.004 -9.000 -9.000

36 2 -0.002 0.004 -9.000 -9.000

36 3 -9.000 -9.000 0.021 0.002

36 14 -0.004 0.000 -9.000 -9.000

36 18 -9.000 -9.000 0.086 0.006

36 33 -9.000 -9.000 1.095 0.032

36 34 0.154 0.003 -9.000 -9.000

37 21 0.002 0.005 -9.000 -9.000

37 31 0.067 0.001 -9.000 -9.000

38 12 0.002 0.001 -9.000 -9.000

38 22 0.011 0.005 -9.000 -9.000

38 30 0.038 0.003 -9.000 -9.000

39 7 -0.001 0.001 -9.000 -9.000

39 10 -9.000 -9.000 0.022 0.006

39 24 0.032 0.001 -9.000 -9.000

39 29 -9.000 -9.000 0.566 0.008

40 1 -0.001 0.001 -9.000 -9.000

40 22 0.021 0.002 -9.000 -9.000

40 28 0.031 0.001 -9.000 -9.000

42 4 0.001 0.001 -9.000 -9.000

42 26 0.029 0.001 -9.000 -9.000

42 34 0.182 0.012 -9.000 -9.000

43 1 -9.000 -9.000 0.035 0.001

43 19 -9.000 -9.000 0.227 0.013

43 34 -9.000 -9.000 1.036 0.016

44 33 0.154 0.001 -9.000 -9.000

46 6 -0.001 0.001 -9.000 -9.000

46 20 0.008 0.001 -9.000 -9.000

46 32 0.091 0.006 -9.000 -9.000

47 1 -9.000 -9.000 0.028 0.001

47 31 -9.000 -9.000 0.956 0.011

48 1 0.003 0.001 -9.000 -9.000

48 3 0.002 0.002 -9.000 -9.000

48 20 0.002 0.001 -9.000 -9.000

48 31 0.112 0.008 -9.000 -9.000

48 34 0.188 0.013 -9.000 -9.000

50 20 0.009 0.001 -9.000 -9.000

 55
 Table 7. Replicate dissolved CFC-113 and CCl4

 analyses (continued)

Station Bottle CFC-113 CFC-113 CCl4 CCl4

(pmol/kg) Stdev (pmol/kg) Stdev

50 30 0.023 0.033 -9.000 -9.000

51 1 -9.000 -9.000 0.067 0.013

51 17 -9.000 -9.000 0.230 0.009

51 26 -9.000 -9.000 0.442 0.042

52 14 0.005 0.005 -9.000 -9.000

52 23 0.017 0.004 -9.000 -9.000

54 4 0.001 0.002 -9.000 -9.000

54 16 0.005 0.001 -9.000 -9.000

54 28 0.031 0.004 -9.000 -9.000

54 34 0.182 0.025 -9.000 -9.000

56 23 0.010 0.006 -9.000 -9.000

56 27 -9.000 -9.000 0.451 0.012

58 1 0.002 0.003 -9.000 -9.000

58 14 0.008 0.002 -9.000 -9.000

58 23 0.020 0.000 -9.000 -9.000

58 32 0.081 0.003 -9.000 -9.000

60 2 0.002 0.001 -9.000 -9.000

60 5 -9.000 -9.000 0.130 0.008

60 16 0.007 0.001 -9.000 -9.000

60 26 0.035 0.003 -9.000 -9.000

60 33 -9.000 -9.000 1.077 0.017

62 2 0.006 0.001 -9.000 -9.000

62 14 0.005 0.001 -9.000 -9.000

62 28 0.035 0.001 -9.000 -9.000

64 1 -9.000 -9.000 0.127 0.006

64 2 -9.000 -9.000 0.131 0.003

64 18 0.006 0.002 -9.000 -9.000

64 33 -9.000 -9.000 0.844 0.039

66 1 0.006 0.002 -9.000 -9.000

66 20 0.008 0.002 -9.000 -9.000

66 30 0.035 0.006 -9.000 -9.000

68 1 -9.000 -9.000 0.199 0.004

68 3 -9.000 -9.000 0.190 0.001

68 33 0.162 0.008 -9.000 -9.000

70 1 -0.002 0.002 -9.000 -9.000

70 20 0.005 0.001 -9.000 -9.000

70 22 0.013 0.006 -9.000 -9.000

70 32 0.038 0.009 -9.000 -9.000

72 1 -9.000 -9.000 0.205 0.001

72 4 -9.000 -9.000 0.408 0.004

72 14 -9.000 -9.000 0.342 0.181

72 17 -9.000 -9.000 0.451 0.011

72 21 0.006 0.001 -9.000 -9.000

72 35 -9.000 -9.000 1.935 0.043

 56
 Table 7. Replicate dissolved CFC-113 and CCl4

 analyses (continued)

Station Bottle CFC-113 CFC-113 CCl4 CCl4

(pmol/kg) Stdev (pmol/kg) Stdev

74 4 -9.000 -9.000 0.327 0.008

74 5 0.012 0.001 -9.000 -9.000

74 16 0.011 0.001 -9.000 -9.000

74 32 0.078 0.007 -9.000 -9.000

76 2 0.007 0.001 -9.000 -9.000

76 4 -9.000 -9.000 0.294 0.004

76 8 -9.000 -9.000 0.143 0.005

76 25 -9.000 -9.000 0.436 0.003

78 2 0.007 0.001 -9.000 -9.000

78 16 0.008 0.001 -9.000 -9.000

78 27 0.035 0.000 -9.000 -9.000

80 13 -9.000 -9.000 0.944 0.016

80 28 0.039 0.005 -9.000 -9.000

80 33 -9.000 -9.000 0.822 0.010

81 8 0.006 0.001 -9.000 -9.000

82 6 0.004 0.002 -9.000 -9.000

82 13 0.008 0.002 -9.000 -9.000

82 21 0.012 0.001 -9.000 -9.000

82 32 0.056 0.001 -9.000 -9.000

84 4 -9.000 -9.000 0.455 0.006

84 5 0.010 0.006 -9.000 -9.000

84 34 -9.000 -9.000 1.751 0.012

86 5 0.005 0.003 -9.000 -9.000

86 14 0.030 0.001 -9.000 -9.000

86 30 0.024 0.003 -9.000 -9.000

88 4 -9.000 -9.000 0.533 0.011

88 17 0.022 0.002 -9.000 -9.000

88 31 0.030 0.006 -9.000 -9.000

88 33 -9.000 -9.000 0.463 0.006

90 4 -9.000 -9.000 0.865 0.006

90 7 0.006 0.005 -9.000 -9.000

90 20 0.010 0.000 -9.000 -9.000

92 5 -9.000 -9.000 0.654 0.294

92 14 0.005 0.003 -9.000 -9.000

92 16 0.008 0.003 -9.000 -9.000

92 26 0.026 0.004 -9.000 -9.000

92 32 0.055 0.005 -9.000 -9.000

94 5 0.020 0.001 -9.000 -9.000

94 6 -9.000 -9.000 0.884 0.002

94 15 0.033 0.002 -9.000 -9.000

94 26 0.027 0.003 -9.000 -9.000

96 4 -9.000 -9.000 0.988 0.001

96 6 0.018 0.001 -9.000 -9.000

96 28 0.037 0.001 -9.000 -9.000

 57
 Table 7. Replicate dissolved CFC-113 and CCl4

 analyses (continued)

Station Bottle CFC-113 CFC-113 CCl4 CCl4

(pmol/kg) Stdev (pmol/kg) Stdev

98 4 -9.000 -9.000 1.169 0.028

98 6 0.024 0.000 -9.000 -9.000

98 18 0.010 0.006 -9.000 -9.000

98 26 0.033 0.008 -9.000 -9.000

100 4 -9.000 -9.000 1.051 0.006

100 16 0.036 0.001 -9.000 -9.000

100 25 0.037 0.008 -9.000 -9.000

102 6 -9.000 -9.000 1.135 0.006

102 15 0.043 0.001 -9.000 -9.000

102 24 0.041 0.004 -9.000 -9.000

104 3 0.032 0.007 -9.000 -9.000

104 4 -9.000 -9.000 1.105 0.007

104 29 0.021 0.001 -9.000 -9.000

104 32 -9.000 -9.000 0.607 0.318

104 34 -9.000 -9.000 2.017 0.059

106 12 -9.000 -9.000 1.044 0.000

106 18 0.003 0.001 -9.000 -9.000

108 16 0.039 0.006 -9.000 -9.000

108 26 0.022 0.003 -9.000 -9.000

110 3 0.028 0.001 -9.000 -9.000

110 5 -9.000 -9.000 1.249 0.013

110 26 -9.000 -9.000 0.639 0.012

110 32 0.103 0.005 -9.000 -9.000

112 18 0.006 0.007 -9.000 -9.000

112 30 0.164 0.004 -9.000 -9.000

114 2 0.028 0.001 -9.000 -9.000

114 4 -9.000 -9.000 1.241 0.020

114 6 -9.000 -9.000 1.129 0.028

114 13 0.055 0.001 -9.000 -9.000

114 24 0.059 0.001 -9.000 -9.000

116 8 0.021 0.007 -9.000 -9.000

116 10 -9.000 -9.000 0.996 0.002

116 16 0.052 0.001 -9.000 -9.000

116 26 0.030 0.001 -9.000 -9.000

118 4 -9.000 -9.000 1.128 0.026

118 10 0.049 0.017 -9.000 -9.000

118 12 0.058 0.007 -9.000 -9.000

118 22 0.033 0.002 -9.000 -9.000

120 16 0.017 0.005 -9.000 -9.000

120 20 0.045 0.035 0.429 0.015

125 8 -9.000 -9.000 0.270 0.008

125 22 0.145 0.003 -9.000 -9.000

129 7 0.136 0.003 -9.000 -9.000

130 6 -9.000 -9.000 2.107 0.021

 58
 Table 8. CFC air measurements

Date GMT Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(hhmm) (

oN) (oW) (ppt) (ppt) (ppt) (ppt)

24-Jan-98 1840 27.433 14.850 259.836 535.550 79.192 -9.000

24-Jan-98 1851 27.433 14.851 260.321 537.726 79.103 -9.000

24-Jan-98 1902 27.433 14.851 261.361 534.915 77.644 -9.000

24-Jan-98 1913 27.433 14.851 261.377 536.906 77.760 -9.000

24-Jan-98 1924 27.424 14.891 262.772 537.277 77.314 -9.000

27-Jan-98 1946 24.909 22.448 262.927 540.885 79.736 -9.000

27-Jan-98 1956 24.876 22.532 263.902 543.954 82.513 -9.000

27-Jan-98 2006 24.871 22.547 263.581 547.197 78.311 -9.000

27-Jan-98 2026 24.840 22.632 263.681 548.454 79.922 -9.000

27-Jan-98 2036 24.834 22.646 264.611 549.683 78.559 -9.000

27-Jan-98 2046 24.834 22.646 265.075 549.246 77.953 -9.000

28-Jan-98 2106 24.500 24.961 263.434 537.866 79.534 -9.000

28-Jan-98 2116 24.501 25.026 262.535 538.353 77.246 -9.000

28-Jan-98 2126 24.503 25.062 263.367 540.686 78.619 -9.000

28-Jan-98 2146 24.504 25.080 262.361 538.433 78.813 -9.000

28-Jan-98 2156 24.503 25.182 259.377 534.339 79.203 -9.000

28-Jan-98 2206 24.503 25.199 259.908 536.414 77.986 -9.000

29-Jan-98 1239 24.500 26.755 265.207 539.051 77.299 -9.000

29-Jan-98 1309 24.499 26.869 264.325 543.569 81.042 -9.000

29-Jan-98 1319 24.501 26.932 265.751 543.250 81.041 -9.000

29-Jan-98 1329 24.501 26.966 261.947 539.318 81.010 -9.000

29-Jan-98 1339 24.500 26.983 264.225 543.042 78.873 -9.000

29-Jan-98 1420 24.500 27.146 265.708 542.256 81.572 -9.000

31-Jan-98 2100 24.500 32.733 260.684 533.662 80.721 -9.000

31-Jan-98 2110 24.500 32.733 262.469 537.215 80.101 -9.000

31-Jan-98 2120 24.500 32.733 260.907 533.539 78.561 -9.000

31-Jan-98 2150 24.500 32.750 258.837 532.814 77.423 -9.000

31-Jan-98 2200 24.500 32.784 263.848 541.865 77.622 -9.000

31-Jan-98 2210 24.500 32.801 259.333 532.263 77.621 -9.000

1-Feb-98 1413 24.502 34.383 -9.000 -9.000 -9.000 89.351

1-Feb-98 1433 24.502 34.383 -9.000 -9.000 -9.000 85.866

1-Feb-98 1453 24.502 34.383 -9.000 -9.000 -9.000 84.658

3-Feb-98 1515 24.500 39.983 262.053 536.784 79.448 -9.000

3-Feb-98 1525 24.498 39.996 262.736 536.844 78.944 -9.000

3-Feb-98 1535 24.498 40.029 261.965 536.178 78.790 -9.000

3-Feb-98 1545 24.498 40.029 261.492 536.176 79.798 -9.000

3-Feb-98 1615 24.501 40.143 262.094 539.114 77.696 -9.000

3-Feb-98 1625 24.501 40.240 261.884 539.831 78.942 -9.000

3-Feb-98 1803 24.500 40.533 -9.000 -9.000 -9.000 94.672

3-Feb-98 1823 24.500 40.533 -9.000 -9.000 -9.000 93.793

4-Feb-98 734 41.633 40.533 -9.000 -9.000 -9.000 92.265

4-Feb-98 754 41.633 40.533 -9.000 -9.000 -9.000 94.492

4-Feb-98 834 41.633 40.533 -9.000 -9.000 -9.000 91.098

4-Feb-98 854 41.633 40.533 -9.000 -9.000 -9.000 93.565

 59
 Table 8. CFC air measurements (continued)

Date GMT Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(hhmm) (

oN) (oW) (ppt) (ppt) (ppt) (ppt)

6-Feb-98 1137 24.500 47.134 -9.000 -9.000 -9.000 94.687

6-Feb-98 1157 24.500 47.134 -9.000 -9.000 -9.000 92.685

6-Feb-98 1237 24.500 47.134 -9.000 -9.000 -9.000 91.974

6-Feb-98 1257 24.500 47.134 -9.000 -9.000 -9.000 93.088

7-Feb-98 1224 24.500 49.333 262.958 538.920 79.104 -9.000

7-Feb-98 1234 24.500 49.333 261.579 540.095 80.068 -9.000

7-Feb-98 1244 24.500 49.333 261.338 538.346 79.588 -9.000

7-Feb-98 1314 24.500 49.333 265.800 540.404 81.139 -9.000

7-Feb-98 1324 24.500 49.333 262.774 539.189 79.657 -9.000

7-Feb-98 1334 24.500 49.333 262.934 539.476 79.559 -9.000

7-Feb-98 1531 24.500 49.461 258.404 531.774 78.156 -9.000

8-Feb-98 1914 24.501 51.533 261.171 537.612 80.509 -9.000

8-Feb-98 1924 24.500 51.533 262.143 538.129 79.696 -9.000

8-Feb-98 1934 24.499 51.546 265.034 538.779 80.208 -9.000

8-Feb-98 2004 24.500 51.636 262.012 536.424 80.017 -9.000

8-Feb-98 2014 24.500 51.636 261.953 537.730 79.940 -9.000

8-Feb-98 2024 24.499 51.699 263.807 538.928 79.901 -9.000

8-Feb-98 2056 24.501 51.533 -9.000 -9.000 -9.000 95.090

8-Feb-98 2116 24.501 51.533 -9.000 -9.000 -9.000 93.306

8-Feb-98 2156 24.501 51.533 -9.000 -9.000 -9.000 93.817

8-Feb-98 2216 24.501 51.533 -9.000 -9.000 -9.000 91.694

9-Feb-98 2244 24.502 53.784 261.719 537.661 81.545 -9.000

9-Feb-98 2254 24.504 53.851 262.597 539.557 80.872 -9.000

9-Feb-98 2304 24.504 53.880 261.726 537.667 79.912 -9.000

9-Feb-98 2324 24.503 53.956 264.344 541.163 80.720 -9.000

9-Feb-98 2334 24.502 53.987 262.269 536.927 80.020 -9.000

9-Feb-98 2344 24.502 53.987 262.205 536.721 80.565 -9.000

10-Feb-98 2032 24.500 55.933 -9.000 -9.000 -9.000 94.388

10-Feb-98 2052 24.500 55.933 -9.000 -9.000 -9.000 93.208

10-Feb-98 2112 24.500 55.933 -9.000 -9.000 -9.000 92.775

10-Feb-98 2132 24.500 55.933 -9.000 -9.000 -9.000 91.823

11-Feb-98 339 24.500 56.667 -9.000 -9.000 -9.000 94.978

11-Feb-98 359 24.500 56.667 -9.000 -9.000 -9.000 95.100

11-Feb-98 439 24.500 56.667 -9.000 -9.000 -9.000 93.361

11-Feb-98 459 24.500 56.667 -9.000 -9.000 -9.000 94.658

11-Feb-98 2204 24.500 58.134 -9.000 -9.000 -9.000 96.657

11-Feb-98 2224 24.500 58.134 -9.000 -9.000 -9.000 96.483

11-Feb-98 2244 24.500 58.134 -9.000 -9.000 -9.000 96.476

13-Feb-98 115 24.500 61.067 262.315 536.445 81.119 -9.000

13-Feb-98 125 24.500 61.067 262.475 538.298 82.255 -9.000

13-Feb-98 135 24.500 61.067 261.623 538.645 80.140 -9.000

13-Feb-98 155 24.506 61.071 261.686 538.295 79.729 -9.000

13-Feb-98 205 24.505 61.105 262.698 538.700 80.228 -9.000

13-Feb-98 215 24.505 61.105 261.676 536.758 79.115 -9.000

 60
 Table 8. CFC air measurements (continued)

Date GMT Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(hhmm) (

oN) (oW) (ppt) (ppt) (ppt) (ppt)

13-Feb-98 229 24.500 61.801 -9.000 -9.000 -9.000 93.299

13-Feb-98 249 24.500 61.801 -9.000 -9.000 -9.000 94.033

13-Feb-98 329 24.500 61.801 -9.000 -9.000 -9.000 94.533

13-Feb-98 349 24.500 61.801 -9.000 -9.000 -9.000 95.347

14-Feb-98 1944 24.500 65.468 262.707 539.047 80.631 -9.000

14-Feb-98 1954 24.500 65.467 262.465 538.199 81.209 -9.000

14-Feb-98 2004 24.501 65.467 262.275 536.354 80.125 -9.000

14-Feb-98 2024 24.500 65.467 262.132 536.824 80.285 -9.000

14-Feb-98 2034 24.501 65.467 262.028 537.808 80.243 -9.000

14-Feb-98 2044 24.501 65.467 262.004 537.114 80.121 -9.000

16-Feb-98 146 24.504 68.440 262.523 540.348 80.763 -9.000

16-Feb-98 156 24.503 68.544 263.901 539.621 81.137 -9.000

16-Feb-98 206 24.502 68.562 261.984 538.864 79.805 -9.000

16-Feb-98 226 24.498 68.666 263.276 540.683 79.877 -9.000

16-Feb-98 236 24.498 68.684 263.034 541.216 79.900 -9.000

16-Feb-98 246 24.498 68.684 263.002 541.274 80.052 -9.000

16-Feb-98 250 24.500 69.133 -9.000 -9.000 -9.000 94.950

16-Feb-98 310 24.500 69.133 -9.000 -9.000 -9.000 95.214

16-Feb-98 330 24.500 69.133 -9.000 -9.000 -9.000 93.795

19-Feb-98 25 26.500 73.216 262.293 538.847 80.539 -9.000

19-Feb-98 35 26.500 73.217 262.142 538.710 80.844 -9.000

19-Feb-98 45 26.500 73.217 261.824 539.329 80.451 -9.000

19-Feb-98 55 26.501 73.309 262.074 540.199 80.325 -9.000

19-Feb-98 110 26.500 73.583 -9.000 -9.000 -9.000 96.505

19-Feb-98 130 26.500 73.583 -9.000 -9.000 -9.000 96.064

19-Feb-98 150 26.500 73.583 -9.000 -9.000 -9.000 95.901

19-Feb-98 210 26.500 73.583 -9.000 -9.000 -9.000 94.810

20-Feb-98 1324 26.500 75.500 -9.000 -9.000 -9.000 96.687

20-Feb-98 1344 26.500 75.500 -9.000 -9.000 -9.000 95.869

20-Feb-98 1424 26.500 75.500 -9.000 -9.000 -9.000 95.886

20-Feb-98 1444 26.500 75.500 -9.000 -9.000 -9.000 95.399

20-Feb-98 2333 26.500 75.900 -9.000 -9.000 -9.000 96.398

20-Feb-98 2353 26.500 75.900 -9.000 -9.000 -9.000 95.629

21-Feb-98 1549 26.510 76.427 262.483 540.744 80.515 -9.000

21-Feb-98 1559 26.510 76.428 262.273 539.635 80.446 -9.000

21-Feb-98 1609 26.511 76.428 262.793 541.135 80.816 -9.000

21-Feb-98 1629 26.514 76.431 262.827 538.937 79.301 -9.000

21-Feb-98 1639 26.516 76.434 263.024 538.655 78.736 -9.000

21-Feb-98 1649 26.508 76.482 262.900 538.355 79.284 -9.000

22-Feb-98 108 26.500 76.617 261.254 537.878 79.587 -9.000

22-Feb-98 152 26.500 76.683 260.123 536.113 78.455 -9.000

22-Feb-98 234 26.500 76.683 -9.000 -9.000 -9.000 96.873

22-Feb-98 254 26.500 76.683 -9.000 -9.000 -9.000 96.657

23-Feb-98 237 26.111 78.494 264.570 540.167 81.155 -9.000

 61
 Table 8. CFC air measurements (continued)

Date GMT Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(hhmm) (

oN) (oW) (ppt) (ppt) (ppt) (ppt)

23-Feb-98 247 26.111 78.494 264.310 539.409 80.459 -9.000

23-Feb-98 257 26.163 78.587 262.826 539.090 79.707 -9.000

23-Feb-98 307 26.168 78.606 262.319 538.885 79.498 -9.000

23-Feb-98 337 26.171 78.731 262.246 539.018 79.676 -9.000

23-Feb-98 539 27.001 79.200 -9.000 -9.000 -9.000 93.798

23-Feb-98 559 27.001 79.200 -9.000 -9.000 -9.000 93.073

23-Feb-98 619 27.001 79.200 -9.000 -9.000 -9.000 93.724

23-Feb-98 1401 27.038 79.481 -9.000 -9.000 -9.000 97.231

23-Feb-98 1421 27.038 79.481 -9.000 -9.000 -9.000 96.196

23-Feb-98 1441 27.038 79.481 -9.000 -9.000 -9.000 95.753

24-Feb-98 250 26.999 79.937 -9.000 -9.000 -9.000 97.861

24-Feb-98 310 26.999 79.937 -9.000 -9.000 -9.000 97.393

 62
 Table 9. CFC air values (interpolated to station locations)

Station Date Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(

oN) (oW) (ppt) (ppt) (ppt) (ppt)

6 24-Jan-98 27.433 14.850 259.836 535.550 79.192 -9.000

7 24-Jan-98 27.433 14.851 260.321 537.726 79.103 -9.000

7 24-Jan-98 27.433 14.851 261.361 534.915 77.644 -9.000

7 24-Jan-98 27.433 14.851 261.377 536.906 77.760 -9.000

7 24-Jan-98 27.424 14.891 262.772 537.277 77.314 -9.000

20 27-Jan-98 24.909 22.448 262.927 540.885 79.736 -9.000

20 27-Jan-98 24.876 22.532 263.902 543.954 82.513 -9.000

20 27-Jan-98 24.871 22.547 263.581 547.197 78.311 -9.000

20 27-Jan-98 24.840 22.632 263.681 548.454 79.922 -9.000

20 27-Jan-98 24.834 22.646 264.611 549.683 78.559 -9.000

20 27-Jan-98 24.834 22.646 265.075 549.246 77.953 -9.000

24 28-Jan-98 24.500 24.961 263.434 537.866 79.534 -9.000

24 28-Jan-98 24.501 25.026 262.535 538.353 77.246 -9.000

24 28-Jan-98 24.503 25.062 263.367 540.686 78.619 -9.000

24 28-Jan-98 24.504 25.080 262.361 538.433 78.813 -9.000

24 28-Jan-98 24.503 25.182 259.377 534.339 79.203 -9.000

24 28-Jan-98 24.503 25.199 259.908 536.414 77.986 -9.000

26 29-Jan-98 24.500 26.755 265.207 539.051 77.299 -9.000

26 29-Jan-98 24.499 26.869 264.325 543.569 81.042 -9.000

26 29-Jan-98 24.501 26.932 265.751 543.250 81.041 -9.000

26 29-Jan-98 24.501 26.966 261.947 539.318 81.010 -9.000

26 29-Jan-98 24.500 26.983 264.225 543.042 78.873 -9.000

26 29-Jan-98 24.500 27.146 265.708 542.256 81.572 -9.000

34 31-Jan-98 24.500 32.733 260.684 533.662 80.721 -9.000

34 31-Jan-98 24.500 32.733 262.469 537.215 80.101 -9.000

34 31-Jan-98 24.500 32.733 260.907 533.539 78.561 -9.000

34 31-Jan-98 24.500 32.750 258.837 532.814 77.423 -9.000

34 31-Jan-98 24.500 32.784 263.848 541.865 77.622 -9.000

34 31-Jan-98 24.500 32.801 259.333 532.263 77.621 -9.000

36 1-Feb-98 24.502 34.383 -9.000 -9.000 -9.000 89.351

36 1-Feb-98 24.502 34.383 -9.000 -9.000 -9.000 85.866

36 1-Feb-98 24.502 34.383 -9.000 -9.000 -9.000 84.658

42 3-Feb-98 24.500 39.983 262.053 536.784 79.448 -9.000

42 3-Feb-98 24.498 39.996 262.736 536.844 78.944 -9.000

42 3-Feb-98 24.498 40.029 261.965 536.178 78.790 -9.000

42 3-Feb-98 24.498 40.029 261.492 536.176 79.798 -9.000

42 3-Feb-98 24.501 40.143 262.094 539.114 77.696 -9.000

42 3-Feb-98 24.501 40.240 261.884 539.831 78.942 -9.000

44 3-Feb-98 24.500 40.533 -9.000 -9.000 -9.000 94.672

44 3-Feb-98 24.500 40.533 -9.000 -9.000 -9.000 93.793

44 4-Feb-98 41.633 40.533 -9.000 -9.000 -9.000 92.265

44 4-Feb-98 41.633 40.533 -9.000 -9.000 -9.000 94.492

44 4-Feb-98 41.633 40.533 -9.000 -9.000 -9.000 91.098

44 4-Feb-98 41.633 40.533 -9.000 -9.000 -9.000 93.565

 63
 Table 9. CFC air values (interpolated to station locations, continued)

Station Date Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(

oN) (oW) (ppt) (ppt) (ppt) (ppt)

56 6-Feb-98 24.500 47.134 -9.000 -9.000 -9.000 94.687

56 6-Feb-98 24.500 47.134 -9.000 -9.000 -9.000 92.685

56 6-Feb-98 24.500 47.134 -9.000 -9.000 -9.000 91.974

56 6-Feb-98 24.500 47.134 -9.000 -9.000 -9.000 93.088

60 7-Feb-98 24.500 49.333 262.958 538.920 79.104 -9.000

60 7-Feb-98 24.500 49.333 261.579 540.095 80.068 -9.000

60 7-Feb-98 24.500 49.333 261.338 538.346 79.588 -9.000

60 7-Feb-98 24.500 49.333 265.800 540.404 81.139 -9.000

60 7-Feb-98 24.500 49.333 262.774 539.189 79.657 -9.000

60 7-Feb-98 24.500 49.333 262.934 539.476 79.559 -9.000

60 7-Feb-98 24.500 49.461 258.404 531.774 78.156 -9.000

64 8-Feb-98 24.501 51.533 261.171 537.612 80.509 -9.000

64 8-Feb-98 24.500 51.533 262.143 538.129 79.696 -9.000

64 8-Feb-98 24.499 51.546 265.034 538.779 80.208 -9.000

64 8-Feb-98 24.500 51.636 262.012 536.424 80.017 -9.000

64 8-Feb-98 24.500 51.636 261.953 537.730 79.940 -9.000

64 8-Feb-98 24.499 51.699 263.807 538.928 79.901 -9.000

64 8-Feb-98 24.501 51.533 -9.000 -9.000 -9.000 95.090

64 8-Feb-98 24.501 51.533 -9.000 -9.000 -9.000 93.306

64 8-Feb-98 24.501 51.533 -9.000 -9.000 -9.000 93.817

64 8-Feb-98 24.501 51.533 -9.000 -9.000 -9.000 91.694

58 9-Feb-98 24.502 53.784 261.719 537.661 81.545 -9.000

58 9-Feb-98 24.504 53.851 262.597 539.557 80.872 -9.000

58 9-Feb-98 24.504 53.880 261.726 537.667 79.912 -9.000

58 9-Feb-98 24.503 53.956 264.344 541.163 80.720 -9.000

58 9-Feb-98 24.502 53.987 262.269 536.927 80.020 -9.000

58 9-Feb-98 24.502 53.987 262.205 536.721 80.565 -9.000

71 10-Feb-98 24.500 55.933 -9.000 -9.000 -9.000 94.388

71 10-Feb-98 24.500 55.933 -9.000 -9.000 -9.000 93.208

71 10-Feb-98 24.500 55.933 -9.000 -9.000 -9.000 92.775

71 10-Feb-98 24.500 55.933 -9.000 -9.000 -9.000 91.823

72 11-Feb-98 24.500 56.667 -9.000 -9.000 -9.000 94.978

72 11-Feb-98 24.500 56.667 -9.000 -9.000 -9.000 95.100

72 11-Feb-98 24.500 56.667 -9.000 -9.000 -9.000 93.361

72 11-Feb-98 24.500 56.667 -9.000 -9.000 -9.000 94.658

74 11-Feb-98 24.500 58.134 -9.000 -9.000 -9.000 96.657

74 11-Feb-98 24.500 58.134 -9.000 -9.000 -9.000 96.483

74 11-Feb-98 24.500 58.134 -9.000 -9.000 -9.000 96.476

79 13-Feb-98 24.500 61.067 262.315 536.445 81.119 -9.000

79 13-Feb-98 24.500 61.067 262.475 538.298 82.255 -9.000

79 13-Feb-98 24.500 61.067 261.623 538.645 80.140 -9.000

79 13-Feb-98 24.506 61.071 261.686 538.295 79.729 -9.000

79 13-Feb-98 24.505 61.105 262.698 538.700 80.228 -9.000

79 13-Feb-98 24.505 61.105 261.676 536.758 79.115 -9.000

 64
 Table 9. CFC air values (interpolated to station locations, continued)

Station Date Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(

oN) (oW) (ppt) (ppt) (ppt) (ppt)

79 13-Feb-98 24.500 61.801 -9.000 -9.000 -9.000 93.299

79 13-Feb-98 24.500 61.801 -9.000 -9.000 -9.000 94.033

79 13-Feb-98 24.500 61.801 -9.000 -9.000 -9.000 94.533

79 13-Feb-98 24.500 61.801 -9.000 -9.000 -9.000 95.347

84 14-Feb-98 24.500 65.468 262.707 539.047 80.631 -9.000

84 14-Feb-98 24.500 65.467 262.465 538.199 81.209 -9.000

84 14-Feb-98 24.501 65.467 262.275 536.354 80.125 -9.000

84 14-Feb-98 24.500 65.467 262.132 536.824 80.285 -9.000

84 14-Feb-98 24.501 65.467 262.028 537.808 80.243 -9.000

84 14-Feb-98 24.501 65.467 262.004 537.114 80.121 -9.000

88 16-Feb-98 24.504 68.440 262.523 540.348 80.763 -9.000

88 16-Feb-98 24.503 68.544 263.901 539.621 81.137 -9.000

88 16-Feb-98 24.502 68.562 261.984 538.864 79.805 -9.000

88 16-Feb-98 24.498 68.666 263.276 540.683 79.877 -9.000

88 16-Feb-98 24.498 68.684 263.034 541.216 79.900 -9.000

88 16-Feb-98 24.498 68.684 263.002 541.274 80.052 -9.000

89 16-Feb-98 24.500 69.133 -9.000 -9.000 -9.000 94.950

89 16-Feb-98 24.500 69.133 -9.000 -9.000 -9.000 95.214

89 16-Feb-98 24.500 69.133 -9.000 -9.000 -9.000 93.795

100 19-Feb-98 26.500 73.216 262.293 538.847 80.539 -9.000

100 19-Feb-98 26.500 73.217 262.142 538.710 80.844 -9.000

100 19-Feb-98 26.500 73.217 261.824 539.329 80.451 -9.000

100 19-Feb-98 26.501 73.309 262.074 540.199 80.325 -9.000

101 19-Feb-98 26.500 73.583 -9.000 -9.000 -9.000 96.505

101 19-Feb-98 26.500 73.583 -9.000 -9.000 -9.000 96.064

101 19-Feb-98 26.500 73.583 -9.000 -9.000 -9.000 95.901

101 19-Feb-98 26.500 73.583 -9.000 -9.000 -9.000 94.810

108 20-Feb-98 26.500 75.500 -9.000 -9.000 -9.000 96.687

108 20-Feb-98 26.500 75.500 -9.000 -9.000 -9.000 95.869

108 20-Feb-98 26.500 75.500 -9.000 -9.000 -9.000 95.886

108 20-Feb-98 26.500 75.500 -9.000 -9.000 -9.000 95.399

110 20-Feb-98 26.500 75.900 -9.000 -9.000 -9.000 96.398

110 20-Feb-98 26.500 75.900 -9.000 -9.000 -9.000 95.629

114 21-Feb-98 26.510 76.427 262.483 540.744 80.515 -9.000

114 21-Feb-98 26.510 76.428 262.273 539.635 80.446 -9.000

114 21-Feb-98 26.511 76.428 262.793 541.135 80.816 -9.000

114 21-Feb-98 26.514 76.431 262.827 538.937 79.301 -9.000

114 21-Feb-98 26.516 76.434 263.024 538.655 78.736 -9.000

114 21-Feb-98 26.508 76.482 262.900 538.355 79.284 -9.000

116 22-Feb-98 26.500 76.617 261.254 537.878 79.587 -9.000

117 22-Feb-98 26.500 76.683 260.123 536.113 78.455 -9.000

117 22-Feb-98 26.500 76.683 -9.000 -9.000 -9.000 96.873

117 22-Feb-98 26.500 76.683 -9.000 -9.000 -9.000 96.657

122 23-Feb-98 26.111 78.494 264.570 540.167 81.155 -9.000

 65
 Table 9. CFC air values (interpolated to station locations, continued)

Station Date Latitude LongitudeCFC-11 CFC-12 CFC-113 CCl4

(

oN) (oW) (ppt) (ppt) (ppt) (ppt)

122 23-Feb-98 26.111 78.494 264.310 539.409 80.459 -9.000

122 23-Feb-98 26.163 78.587 262.826 539.090 79.707 -9.000

122 23-Feb-98 26.168 78.606 262.319 538.885 79.498 -9.000

122 23-Feb-98 26.171 78.731 262.246 539.018 79.676 -9.000

122 23-Feb-98 27.001 79.200 -9.000 -9.000 -9.000 93.798

122 23-Feb-98 27.001 79.200 -9.000 -9.000 -9.000 93.073

122 23-Feb-98 27.001 79.200 -9.000 -9.000 -9.000 93.724

125 23-Feb-98 27.038 79.481 -9.000 -9.000 -9.000 97.231

125 23-Feb-98 27.038 79.481 -9.000 -9.000 -9.000 96.196

125 23-Feb-98 27.038 79.481 -9.000 -9.000 -9.000 95.753

130 24-Feb-98 26.999 79.937 -9.000 -9.000 -9.000 97.861

130 24-Feb-98 26.999 79.937 -9.000 -9.000 -9.000 97.393

 66
67

Appendix A. WOCE Quality Control Flags
68

WOCE quality flag definitions for water bottles.

 

Flag Definition

1 Bottle information unavailable

2 No problems noted

3 Leaking

4 Did not trip correctly

5 Not reported

7 Unknown problem

9 Samples not drawn from this bottle

WOCE water quality flag definitions.

 

Flag Definition

1 Sample drawn but analysis not received

2 Acceptable measurement

3 Questionable measurement

4 Bad measurement

5 Not reported

6 Mean of replicate measurements

9 Sample not drawn for measurement
69

Appendix B. Bottle Data
A5R

NOAA Ship Ronald H. Brown

STATION 1 DATE 1/24/1998 LATITUDE 27.917° N

LONGITUDE 13.370° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F** Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

9 2 2.2 36.528 36.529 2 18.055 18.055 26.431 227.8 2 231.9 2 -0.9 9 9 9 9 9 9 0.14 2 9 419.6 387.3 2 2119.7 6 9 9 9 9

8 2 28.2 36.526 36.526 2 18.057 18.052 26.431 229.2 2 230.5 2 0.5 9 9 9 9 9 9 9 9 421.1 388.6 2 2121.5 2 9 9 9 9

7 2 39.1 36.524 36.517 2 18.052 18.045 26.431 228.9 2 228.8 2 2.3 9 9 9 9 9 9 9 9 9 2124.7 2 9 9 9 9

6 2 47.8 36.501 36.500 2 17.905 17.897 26.451 226.3 2 225.0 2 6.7 9 9 9 9 9 9 9 9 446.6 409.7 2 2130.9 2 9 9 9 9

5 2 58.5 36.495 36.495 2 17.862 17.852 26.458 223.2 2 220.6 2 11.3 9 9 9 9 9 9 0.14 2 9 9 2132.9 2 9 9 9 9

4 3 70.0 36.478 36.478 2 17.727 17.715 26.479 216.6 2 213.9 2 18.7 9 9 9 9 9 9 9 9 469.9 427.8 2 2139.8 2 9 9 9 9

3 2 89.9 36.410 36.405 2 17.166 17.151 26.565 198.2 2 196.1 2 39.1 9 9 9 9 9 9 9 9 466.1 414.6 2 2135.1 2 9 9 9 9

2 2 108.1 36.318 36.317 2 16.395 16.377 26.679 187.7 2 189.8 2 49.0 9 9 9 9 9 9 9 9 9 2137.2 2 9 9 9 9

1 2 125.7 36.296 36.296 2 16.231 16.211 26.702 187.9 2 189.8 2 49.9 9 9 9 9 9 9 0.06 2 9 489.3 418.2 2 2137.1 2 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

70
A5R

NOAA Ship Ronald H. Brown

STATION 2 DATE 1/24/1998 LATITUDE 27.965° N

LONGITUDE 13.404° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

16 3 3.0 36.579 36.578 2 18.318 18.317 26.404 233.8 2 235.9 2 -6.1 9 9 9 9 9 9 9 9 9 9 9 9 9 9

15 2 40.6 36.578 36.577 2 18.327 18.320 26.404 234.8 2 235.0 2 -5.2 9 9 9 9 9 9 9 9 387.3 361.8 2 2108.5 6 7.9846 2 2396 2 2397 60.5 2 9

14 2 59.9 36.489 36.491 2 17.758 17.748 26.479 204.1 2 203.0 2 29.4 9 9 9 9 9 9 9 9 438.0 399.9 2 2128.5 2 7.9415 2 2388 2 2392 9 9

13 2 77.6 36.469 36.471 2 17.536 17.523 26.520 196.7 2 197.8 2 35.6 9 9 9 9 9 9 9 9 9 2129.9 2 7.9341 2 2386 2 2388 51.6 2 9

12 2 98.6 36.375 36.376 2 16.769 16.753 26.634 190.4 2 192.5 2 44.5 9 9 9 9 9 9 9 9 462.6 405.2 2 2132.5 2 7.9164 2 9 2380 51.5 2 9

11 2 127.3 36.315 36.315 2 16.334 16.313 26.693 188.8 2 191.2 2 47.9 9 9 9 9 9 9 9 9 9 2136.3 2 7.9049 2 2374 2 2377 9 9

10 2 149.1 36.293 36.283 2 16.209 16.185 26.707 188.3 2 189.0 2 50.8 9 9 9 9 9 9 9 9 480.1 410.8 6 2140.3 2 7.9014 2 2375 2 2379 49.3 2 9

9 3 178.4 36.202 36.205 2 15.606 15.578 26.777 186.5 2 186.8 2 56.0 9 9 9 9 9 9 9 9 9 2144.5 2 7.8885 2 2369 3 2376 9 9

8 2 196.8 36.155 36.154 2 15.336 15.305 26.802 184.5 2 185.5 2 58.7 9 9 9 9 9 9 9 9 9 2141.8 2 7.8786 2 2368 2 2367 47.6 2 9

7 2 229.7 36.105 36.108 2 15.016 14.981 26.837 182.5 2 182.4 2 63.4 9 9 9 9 9 9 9 9 523.8 426.3 2 2144.0 2 7.8670 2 2362 2 2363 9 9

6 2 237.3 36.075 36.074 2 14.835 14.799 26.854 182.8 2 182.3 2 64.5 9 9 9 9 9 9 9 9 9 2144.5 2 7.8564 2 2358 2 2357 9 9

5 2 299.2 35.958 35.957 2 14.088 14.044 26.928 174.9 2 173.8 2 76.9 9 9 9 9 9 9 9 9 9 2155.4 2 7.8287 2 2354 2 2354 46.6 2 9

4 2 338.2 35.931 35.931 2 13.895 13.846 26.951 175.4 2 173.2 2 78.6 9 9 9 9 9 9 9 9 604.2 468.7 2 2155.2 2 7.8257 2 2356 2 2352 9 9

3 2 399.0 35.861 35.861 2 13.419 13.362 26.999 173.0 2 170.4 2 84.0 9 9 9 9 9 9 9 9 9 2161.1 2 7.8086 2 2350 2 2349 47.1 2 9

2 2 463.6 35.774 35.772 2 12.830 12.766 27.054 166.8 2 165.2 2 92.5 9 9 9 9 9 9 9 9 9 2167.3 2 7.7867 2 2348 2 2345 45.8 2 9

1 2 517.6 35.532 35.532 2 11.028 10.963 27.209 146.6 2 146.2 2 ### 9 9 9 9 9 9 9 9 774.7 532.5 2 2188.0 2 7.7185 2 2337 2 2334 45.9 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

71
A5R

NOAA Ship Ronald H. Brown

STATION 3 DATE 1/24/1998 LATITUDE 27.883° N

LONGITUDE 13.417° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

20 2 1.9 36.584 36.585 2 18.398 18.398 26.387 239.8 2 9 0.08 2 0.39 2 0.08 2 1.00 2 2.41 2 1.36 2 0.16 2 9 381.3 357.4 2 2103.9 6 7.9923 2 9 2398 9 9

19 2 24.4 36.586 36.585 2 18.416 18.412 26.386 239.7 2 9 0.08 2 0.29 2 4 0.90 2 9 9 9 9 9 2103.2 2 7.9950 2 5 2398 9 9

18 2 49.8 36.562 36.562 2 18.315 18.306 26.395 234.4 2 228.9 2 1.0 0.12 2 1.46 2 0.15 2 1.30 2 9 9 9 9 9 2109.4 2 7.9799 2 9 2396 9 9

17 2 74.3 36.465 36.470 2 17.435 17.422 26.541 197.9 2 196.0 2 37.9 0.03 2 5.46 2 0.32 2 2.30 2 9 9 9 9 9 9 7.9163 2 2401 2 9 9

16 2 96.9 36.379 36.399 2 16.814 16.798 26.626 192.8 2 191.3 2 45.5 0.02 2 6.63 2 0.39 2 2.50 2 2.39 2 1.31 2 0.29 4 9 461.8 406.0 2 2131.9 6 7.9184 2 9 2381 9 9

15 2 122.5 36.293 36.295 2 16.177 16.157 26.712 189.5 2 189.7 2 50.2 0.02 2 7.80 2 0.45 2 2.70 2 9 9 9 9 9 2134.8 2 7.8951 2 2383 3 2370 9 9

14 2 147.8 36.205 36.209 2 15.607 15.584 26.776 187.8 2 187.0 2 55.7 0.01 2 8.88 2 0.51 2 2.80 2 9 9 9 9 9 2137.8 2 7.8868 2 9 2368 9 9

13 2 175.1 36.134 36.134 2 15.211 15.184 26.813 186.3 2 181.2 2 63.6 0.00 2 10.34 2 0.59 2 3.50 2 9 9 9 9 9 2190.3 3 7.8648 2 5 2412 9 9

12 3 197.3 36.119 2 15.129 15.099 26.820 181.5 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

11 2 223.6 36.058 36.062 2 14.737 14.703 26.861 183.4 2 180.2 2 67.1 0.00 2 11.22 2 0.64 2 3.80 2 2.33 2 1.24 2 0.03 2 9 9 2185.1 3 7.8565 2 5 2402 9 9

10 2 248.3 36.028 36.025 2 14.518 14.481 26.887 179.4 2 179.9 2 68.5 0.01 2 11.71 2 0.69 2 4.20 2 9 9 9 9 545.6 435.9 2 2183.9 3 7.8516 2 9 2397 9 9

9 2 300.0 35.970 35.971 2 14.160 14.116 26.923 177.9 2 176.3 2 74.0 0.00 2 12.68 2 0.73 2 4.60 2 2.23 6 1.19 6 0.04 6 9 9 2175.4 3 7.8378 2 5 2381 9 9

8 2 349.1 35.902 35.906 2 13.702 13.652 26.969 173.7 2 172.4 2 80.4 0.01 2 13.86 2 0.81 2 5.30 2 9 9 9 9 9 2180.3 3 7.8226 2 9 2378 9 9

7 2 399.6 35.833 35.830 2 13.245 13.189 27.012 169.9 2 168.7 2 86.7 0.01 2 15.03 2 0.89 2 5.90 2 2.05 2 1.06 2 0.03 2 9 9 2183.6 3 7.8038 2 5 2372 9 9

6 2 450.4 35.743 35.743 2 12.609 12.547 27.072 164.4 2 162.6 2 96.3 0.00 2 16.69 2 1.00 2 6.70 2 9 9 9 9 9 2189.2 3 7.7823 2 9 2367 9 9

5 2 498.5 35.653 35.652 2 11.965 11.899 27.129 156.3 2 156.4 2 106.2 0.00 2 18.54 2 1.13 2 7.80 2 1.64 2 0.86 2 0.02 2 9 9 2193.4 3 7.7548 2 5 2358 9 9

4 2 548.8 35.552 35.548 2 11.206 11.136 27.194 147.7 2 147.4 2 119.7 0.00 2 20.79 2 1.27 2 9.60 2 9 9 9 9 9 2199.0 3 7.7245 2 9 2349 9 9

3 2 575.0 35.504 35.504 2 10.836 10.764 27.224 145.7 2 144.9 2 124.4 0.00 2 21.77 2 1.35 2 10.40 2 1.21 2 0.62 2 0.01 2 9 9 2198.7 3 7.7083 2 2348 2 2342 9 9

2 2 641.0 35.433 35.430 2 10.206 10.129 27.281 139.6 2 139.7 2 133.5 0.00 2 23.43 2 1.46 2 12.30 2 9 9 9 9 9 2202.2 3 7.6901 2 9 2338 9 9

1 2 654.8 35.409 35.413 2 9.992 9.914 27.300 137.9 2 137.6 2 136.9 0.00 2 23.82 2 1.48 2 12.80 2 0.90 2 0.46 2 0.01 2 9 843.9 559.6 2 2200.4 3 7.6834 2 2334 2 2333 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

72
A5R

NOAA Ship Ronald H. Brown

STATION 4 DATE 1/24/1998 LATITUDE 27.849° N

LONGITUDE 13.417° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

22 2 4.3 36.706 36.707 2 19.034 19.033 26.319 234.1 2 9 0.11 2 0.20 2 0.07 2 0.90 2 9 9 9 9 375.2 361.0 2 2100.8 6 8.0044 2 2404 2 2403 9 9

21 2 10.6 36.705 36.697 2 19.034 19.032 26.319 233.7 2 9 0.13 2 0.29 2 0.08 2 1.00 2 9 9 9 9 9 9 9 9 9 9

20 2 28.7 36.657 36.657 2 18.769 18.764 26.351 233.5 2 9 0.19 2 0.29 2 0.09 2 0.90 2 9 9 9 9 9 9 9 9 9 9

19 2 60.0 36.494 36.494 2 17.894 17.884 26.449 229.6 2 9 0.19 2 4.49 2 0.31 2 2.00 2 9 9 9 9 9 9 9 9 9 9

18 2 90.4 36.398 36.399 2 16.994 16.979 26.597 193.5 2 9 0.03 2 6.93 2 0.41 2 2.30 2 9 9 9 9 9 9 9 9 9 9

17 2 120.2 36.273 36.272 2 16.057 16.038 26.724 184.1 2 9 0.01 2 8.20 2 0.46 2 2.50 2 9 9 9 9 9 9 9 9 9 9

16 2 149.4 36.152 36.164 2 15.381 15.358 26.787 184.4 2 9 0.00 2 10.64 2 0.61 2 3.50 2 9 9 9 9 9 9 9 9 9 9

15 2 177.3 36.071 36.063 2 14.966 14.939 26.818 162.1 2 9 0.00 2 13.37 2 0.76 2 4.70 2 9 9 9 9 9 9 9 9 9 9

14 2 210.6 36.037 36.036 2 14.656 14.624 26.862 167.3 2 9 0.00 2 12.78 2 0.74 2 4.60 2 9 9 9 9 9 9 9 9 9 9

13 2 250.3 36.002 36.003 2 14.361 14.324 26.902 174.1 2 9 0.00 2 12.59 2 0.72 2 4.60 2 9 9 9 9 9 9 9 9 9 9

12 2 298.0 35.889 35.886 2 13.607 13.564 26.975 174.0 2 9 0.00 2 14.35 2 0.82 2 5.40 2 9 9 9 9 9 9 9 9 9 9

11 2 346.8 35.805 35.805 2 13.047 12.999 27.027 172.4 2 9 0.00 2 15.42 2 0.90 2 5.90 2 9 9 9 9 9 9 9 9 9 9

10 2 399.8 35.737 35.736 2 12.570 12.515 27.072 168.8 2 9 0.00 2 16.79 2 0.98 2 6.50 2 9 9 9 9 9 9 9 9 9 9

9 2 447.1 35.645 35.660 2 11.971 11.912 27.119 156.5 2 9 0.00 2 18.65 2 1.10 2 7.70 2 9 9 9 9 9 9 9 9 9 9

8 2 499.0 35.608 35.600 2 11.649 11.584 27.153 154.7 2 9 0.00 2 19.82 2 1.18 2 8.70 2 9 9 9 9 9 9 9 9 9 9

7 2 548.5 35.526 35.525 2 11.041 10.972 27.204 148.5 2 9 0.00 2 21.58 2 1.30 2 10.30 2 9 9 9 9 9 9 9 9 9 9

6 2 595.5 35.448 35.450 2 10.437 10.364 27.252 140.8 2 9 0.00 2 23.53 2 1.42 2 12.20 2 9 9 9 9 9 9 9 9 9 9

5 2 702.4 35.362 35.360 2 9.618 9.536 27.327 132.6 2 9 0.00 2 25.58 2 1.57 2 14.50 2 9 9 9 9 9 9 9 9 9 9

4 2 800.1 35.302 35.301 2 8.876 8.786 27.404 133.4 2 9 0.00 2 26.66 2 1.65 2 16.60 2 9 9 9 9 9 9 9 9 9 9

3 2 898.9 35.289 35.289 2 8.329 8.231 27.481 142.2 2 9 0.01 2 26.56 2 1.66 2 17.40 2 9 9 9 9 9 9 9 9 9 9

2 2 999.5 35.245 35.243 2 7.711 7.606 27.540 147.2 2 9 0.01 2 26.95 2 1.70 2 18.70 2 9 9 9 9 9 9 9 9 9 9

1 2 1080.6 35.236 35.234 2 7.410 7.299 27.578 152.0 2 9 0.00 2 26.66 2 1.68 2 18.70 2 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

73
A5R

NOAA Ship Ronald H. Brown

STATION 5 DATE 1/24/1998 LATITUDE 27.799° N

LONGITUDE 13.816° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

27 2 2.5 36.642 36.641 2 18.694 18.694 26.357 232.8 2 232.1 2 -4.0 0.17 2 0.59 2 4 4 2.39 2 1.35 2 0.17 2 9 381.0 361.4 2 2105.0 6 7.9955 2 2403 2 2401 9 9

26 2 9.1 36.642 36.641 2 18.696 18.694 26.357 232.7 2 232.3 2 -4.2 0.17 2 0.59 2 4 4 2.39 2 1.35 2 0.17 2 9 9 9 9 9 9 9

25 2 68.6 36.530 36.542 2 18.237 18.225 26.392 228.2 2 211.1 2 19.1 0.24 2 3.12 2 4 4 9 9 9 9 9 9 9 9 9 9

24 2 92.5 36.447 36.430 2 17.607 17.591 26.487 193.5 2 192.1 2 41.1 0.03 2 5.95 2 4 4 2.39 2 1.35 2 0.14 2 9 9 9 9 9 9 9

23 2 127.6 36.315 36.310 2 16.451 16.430 26.665 183.3 2 185.3 2 53.3 0.01 2 8.10 2 4 4 9 9 9 9 9 9 9 9 9 9

22 2 151.5 36.214 36.195 2 15.711 15.687 26.760 181.0 2 182.8 2 59.5 0.00 2 9.46 2 4 4 2.37 2 1.30 2 0.04 2 9 9 9 9 9 9 9

21 3 186.4 36.123 2 15.125 15.096 26.824 180.1 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

20 2 217.7 36.061 36.061 2 14.757 14.724 26.859 176.7 2 178.1 2 69.1 0.00 2 11.41 2 4 4 9 9 9 9 9 9 9 9 9 9

19 2 245.7 35.987 35.993 2 14.304 14.268 26.901 170.6 2 172.5 2 77.0 0.00 2 12.68 2 4 4 2.24 2 1.20 2 0.03 2 9 9 9 9 9 9 9

18 2 299.7 35.909 35.909 2 13.754 13.711 26.961 174.4 2 173.4 2 79.1 0.00 2 13.66 2 4 4 9 9 9 9 9 9 9 9 9 9

17 2 397.4 35.705 35.705 2 12.322 12.268 27.096 165.9 2 162.9 2 97.6 0.00 2 17.08 2 4 4 1.83 2 0.96 2 0.04 2 9 9 9 9 9 9 9

16 2 497.6 35.554 35.547 2 11.236 11.173 27.188 150.4 2 148.2 2 118.7 0.00 2 20.69 2 4 4 9 9 9 9 9 9 9 9 9 9

15 2 598.0 35.416 35.414 2 10.106 10.034 27.283 137.6 2 136.6 2 137.2 0.00 2 23.72 2 4 4 0.91 2 0.47 2 0.01 2 9 9 9 9 9 9 9

14 2 699.0 35.333 35.331 2 9.235 9.155 27.367 133.5 2 134.1 2 145.2 0.00 2 25.48 2 4 4 9 9 9 9 9 9 9 9 9 9

13 2 799.5 35.281 35.279 2 8.528 8.441 27.441 136.2 2 136.0 2 147.9 0.00 2 26.45 2 4 4 0.38 2 0.20 2 0.00 2 9 9 9 9 9 9 9

12 2 898.1 35.268 35.269 2 8.092 7.996 27.499 141.7 2 142.7 2 144.0 0.00 2 26.26 2 4 4 9 9 9 9 9 9 9 9 9 9

11 2 995.6 35.225 35.224 2 7.503 7.400 27.554 147.5 2 9 0.00 2 26.65 2 4 4 9 9 9 9 913.3 544.5 2 2208.2 3 9 9 9 9

10 2 995.7 35.225 35.225 2 7.502 7.399 27.554 147.5 2 9 0.00 2 26.55 2 4 4 9 9 9 9 9 2211.1 3 9 9 9 9

9 2 995.7 35.225 35.225 2 7.502 7.399 27.554 147.5 2 9 0.00 2 26.46 2 4 4 9 9 9 9 914.3 544.6 2 2212.4 3 9 9 9 9

8 2 995.3 35.225 35.225 2 7.502 7.399 27.555 147.5 2 9 0.00 2 26.36 2 4 4 9 9 9 9 9 2206.8 6 9 9 9 9

7 2 995.2 35.225 35.226 2 7.502 7.399 27.555 147.5 2 9 0.00 2 26.36 2 4 4 9 9 9 9 919.6 547.5 2 2208.6 6 7.6523 2 5 2326 9 9

6 2 995.5 35.225 35.225 2 7.503 7.400 27.554 147.5 2 147.4 2 143.3 0.00 2 26.26 2 4 4 0.18 6 0.09 6 0.00 6 9 9 9 9 9 9 9

5 2 1098.8 35.241 35.240 2 7.116 7.005 27.624 160.7 2 160.7 2 132.7 0.00 2 25.19 2 4 4 9 9 9 9 9 9 9 9 9 9

4 2 1199.0 35.248 35.248 2 6.747 6.628 27.682 171.3 2 171.7 2 124.2 0.00 2 24.41 2 4 4 0.14 2 0.07 2 0.00 2 9 9 9 9 9 9 9

3 2 1284.2 35.295 35.295 2 6.726 6.598 27.724 181.4 2 181.1 2 114.9 0.00 2 23.33 2 4 4 9 9 9 9 9 9 9 9 9 9

2 2 1395.0 35.223 35.225 2 5.861 5.730 27.779 193.8 2 193.7 2 108.6 0.01 2 23.04 2 4 4 0.09 2 0.05 2 0.01 2 9 9 9 9 9 9 9

1 2 1507.4 35.179 35.188 2 5.348 5.211 27.808 203.6 2 9 0.00 2 22.55 2 4 4 0.07 2 0.04 2 0.00 2 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

74
A5R

NOAA Ship Ronald H. Brown

STATION 6 DATE 1/24/1998 LATITUDE 27.617° N

LONGITUDE 14.235° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

31 2 2.9 36.751 36.750 2 19.559 19.558 26.216 230.6 2 230.4 2 -6.1 0.02 2 0.10 2 0.00 2 0.60 2 9 9 9 9 9 9 8.0175 2 2408 2 9 9

30 2 2.5 36.751 36.750 2 19.554 19.554 26.218 230.6 2 231.7 2 -7.4 0.02 2 0.10 2 4 0.60 2 9 9 9 9 361.6 355.3 6 2096.4 6 8.0172 2 2413 2 2407 62.6 2 4.3 2

29 2 19.7 36.750 36.749 2 19.548 19.544 26.220 230.4 2 231.5 2 -7.1 0.02 2 0.10 2 0.00 2 0.50 2 9 9 9 9 9 9 8.0175 6 9 63.0 2 4.4 2

28 2 40.0 36.750 36.750 2 19.548 19.541 26.222 230.7 2 231.5 2 -7.1 0.02 2 0.10 2 0.00 2 0.50 2 9 9 9 9 9 9 8.0174 6 9 63.5 2 9

27 2 58.1 36.749 36.749 2 19.542 19.531 26.224 229.8 2 231.0 2 -6.6 0.01 2 0.10 2 0.01 2 0.50 2 9 9 9 9 9 9 9 9 64.5 2 4.2 2

26 2 81.0 36.748 36.748 2 19.540 19.525 26.227 229.7 2 231.3 2 -6.9 0.02 2 0.10 2 0.01 2 0.40 2 9 9 9 9 9 9 9 9 65.1 2 4.3 2

25 2 99.6 36.745 36.747 2 19.532 19.514 26.228 230.4 2 230.8 2 -6.3 0.02 2 0.10 2 0.03 2 0.60 2 9 9 9 9 9 9 9 9 62.5 2 4.9 2

24 2 127.9 36.517 36.514 2 18.025 18.003 26.441 204.7 2 199.2 2 32.0 0.03 2 4.58 2 0.27 2 1.70 2 9 9 9 9 9 9 9 9 54.7 2 8.0 2

23 2 160.0 36.451 36.442 2 17.258 17.231 26.581 193.4 2 194.9 2 39.9 0.01 2 5.95 2 0.31 2 1.90 2 9 9 9 9 9 9 9 9 52.4 2 8.4 2

22 2 187.8 36.327 36.319 2 16.410 16.379 26.689 188.6 2 189.6 2 49.2 0.01 2 7.61 2 0.41 2 2.40 2 9 9 9 9 9 9 9 9 9 9

21 3 228.2 36.226 36.224 2 15.779 15.743 26.760 185.0 2 9 0.00 2 9.27 2 0.50 2 3.00 2 9 9 9 9 9 9 9 9 9 9

20 2 266.2 36.131 36.129 2 15.175 15.134 26.825 181.4 2 184.3 2 60.7 0.01 2 10.15 2 0.58 2 3.30 2 9 9 9 9 9 9 9 9 9 9

19 2 304.3 36.041 36.039 2 14.599 14.553 26.884 184.3 2 184.3 2 63.7 0.01 2 10.83 2 0.64 2 3.80 2 9 9 9 9 9 9 9 9 49.0 2 9

18 2 359.8 35.892 35.890 2 13.650 13.598 26.972 178.9 2 169.6 2 83.5 0.00 2 14.15 2 0.82 2 5.10 2 9 9 9 9 9 9 9 9 9 9

17 2 404.2 35.827 35.826 2 13.209 13.152 27.015 169.7 2 169.0 2 86.6 0.00 2 14.93 2 0.87 2 5.60 2 9 9 9 9 9 9 9 9 48.9 2 17.5 2

16 2 451.0 35.717 35.717 2 12.451 12.390 27.083 163.8 2 161.5 2 98.3 0.00 2 16.88 2 1.01 2 6.80 2 9 9 9 9 9 9 9 9 9 9

15 2 500.1 35.625 35.624 2 11.776 11.710 27.143 158.3 2 155.9 2 107.8 0.00 2 18.94 2 1.14 2 8.40 2 9 9 9 9 9 9 9 9 44.6 2 9

14 2 553.7 35.553 35.554 2 11.177 11.106 27.201 159.0 2 153.3 2 114.0 0.00 2 20.11 2 1.23 2 9.60 2 9 9 9 9 9 9 9 9 9 9

13 2 594.8 35.474 35.475 2 10.596 10.523 27.245 145.7 2 142.9 2 127.9 0.00 2 22.35 2 1.37 2 11.60 2 9 9 9 9 9 9 9 9 44.3 2 24.6 2

12 2 649.8 35.371 35.370 2 9.824 9.747 27.298 132.4 2 129.4 2 146.2 0.00 2 25.28 2 1.56 2 14.40 2 9 9 9 9 9 9 9 9 9 9

11 2 701.4 35.324 35.323 2 9.420 9.339 27.331 124.7 2 126.4 2 151.8 0.00 2 26.26 2 1.63 2 15.50 2 9 9 9 9 9 9 9 9 43.8 2 28.2 2

10 2 789.6 35.241 35.240 2 8.477 8.391 27.417 123.4 2 127.8 2 156.5 0.00 2 27.63 2 1.75 2 17.60 2 9 9 9 9 9 9 9 9 43.2 2 29.3 2

9 2 849.9 35.221 35.219 2 8.119 8.028 27.457 130.1 2 131.8 2 154.8 0.00 2 27.63 2 1.76 2 18.00 2 9 9 9 9 9 9 9 9 9 29.5 2

8 2 922.4 35.204 35.203 2 7.708 7.612 27.506 137.1 2 138.0 2 151.4 0.00 2 27.24 2 1.76 2 18.40 2 9 9 9 9 9 9 9 9 42.7 2 9

7 2 998.3 35.236 35.235 2 7.484 7.381 27.565 148.6 2 149.7 2 141.2 0.01 2 25.97 2 1.71 2 18.60 2 9 9 9 9 9 9 9 9 42.2 2 28.1 2

6 2 1096.6 35.267 35.267 2 7.221 7.109 27.630 161.5 2 162.0 2 130.6 0.00 2 24.80 2 1.61 2 18.90 2 9 9 9 9 9 9 9 9 42.4 2 27.0 2

5 2 1200.0 35.272 35.274 2 6.757 6.638 27.699 174.5 2 175.7 2 120.1 0.00 2 23.82 2 1.55 2 19.80 2 9 9 9 9 9 9 9 9 42.7 2 26.2 2

4 2 1402.5 35.264 35.264 2 6.090 5.956 27.784 196.4 2 196.0 2 104.6 0.00 2 22.36 2 1.46 2 21.40 2 9 9 9 9 9 9 9 9 42.5 2 25.1 2

3 2 1597.5 35.230 35.229 2 5.419 5.272 27.843 213.8 2 213.3 2 92.3 0.00 2 21.38 2 1.40 2 22.60 2 9 9 9 9 9 9 9 9 42.5 2 23.7 2

2 2 1800.3 35.128 35.129 2 4.565 4.409 27.861 222.2 2 221.1 2 91.1 0.00 2 21.58 2 1.45 2 26.20 2 9 9 9 9 9 9 9 9 42.7 2 23.9 2

1 2 2035.1 35.047 35.048 2 3.898 3.728 27.868 223.5 2 223.8 2 93.8 0.00 2 22.07 2 1.49 2 30.40 2 9 9 9 9 9 9 9 9 43.0 2 24.8 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

75
A5R

NOAA Ship Ronald H. Brown

STATION 7 DATE 1/24/1998 LATITUDE 27.433° N

LONGITUDE 14.851° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

31 2 3.1 36.758 36.759 2 19.512 19.511 26.234 235.3 2 234.7 2 -10.2 0.00 2 0.00 2 0.00 2 0.70 2 2.35 2 1.31 2 0.19 2 9 357.1 350.2 2 2096.4 6 8.0162 2 2406 2 2407 9 9

30 2 20.2 36.751 36.751 2 19.486 19.482 26.237 233.8 2 232.9 2 -8.3 0.00 2 0.10 2 0.01 2 0.40 2 2.33 2 1.31 2 0.17 2 9 357.8 350.5 2 2095.5 2 8.0150 2 2405 2 2405 9 9

29 2 41.2 36.743 36.742 2 19.447 19.439 26.244 233.4 2 233.8 2 -9.0 0.01 2 0.10 2 0.02 2 0.40 2 9 9 9 9 359.7 351.8 2 2096.0 2 8.0120 2 2408 2 2403 9 9

28 2 56.1 36.736 36.735 2 19.388 19.378 26.254 232.8 2 233.6 2 -8.5 0.02 2 0.20 2 0.03 2 0.40 2 2.35 6 1.32 6 0.18 6 9 362.4 353.6 2 2097.4 2 8.0133 2 2404 2 2406 9 9

27 2 76.9 36.725 36.717 2 19.342 19.328 26.261 231.3 2 232.0 2 -6.7 0.07 2 0.20 2 0.04 2 0.50 2 9 9 9 9 366.9 357.4 2 2104.6 2 8.0076 2 2406 2 2409 9 9

26 2 100.1 36.612 36.613 2 18.706 18.688 26.340 227.2 2 229.5 2 -1.4 0.30 2 0.78 2 0.12 2 0.70 2 2.41 2 1.35 2 0.19 2 9 390.0 370.2 2 2122.5 2 7.9862 2 9 2414 9 9

25 2 125.2 36.528 36.529 2 17.963 17.941 26.464 197.4 2 202.3 2 29.2 0.04 6 4.39 6 0.27 6 1.70 6 9 9 9 9 436.2 402.0 2 2125.3 2 7.9450 2 2389 2 2391 9 9

24 2 151.4 36.424 36.402 2 17.000 16.975 26.621 192.4 2 194.8 2 41.2 0.01 2 6.34 2 0.35 2 2.00 2 2.46 2 1.35 2 0.08 2 9 462.3 409.5 2 2130.7 2 7.9236 2 2382 2 2383 9 9

23 2 166.6 36.344 36.339 2 16.503 16.476 26.678 190.3 2 192.5 2 45.9 0.01 2 7.12 2 0.40 2 2.00 2 9 9 9 9 464.1 402.8 2 2135.6 2 9 2377 2 9 9

22 2 198.4 36.251 36.250 2 15.921 15.889 26.744 186.8 2 188.3 2 52.9 0.00 2 8.39 2 0.48 2 2.40 2 2.41 2 1.30 2 0.05 2 9 485.3 411.5 2 2142.2 2 7.8960 2 2375 3 2379 9 9

21 2 250.2 36.115 36.116 2 15.059 15.021 26.837 183.5 2 183.8 2 61.8 0.00 2 10.15 2 0.59 2 3.10 2 9 9 9 9 520.4 425.5 2 9 7.8699 2 9 9 9

20 2 297.8 35.971 35.964 2 14.109 14.065 26.934 182.5 2 183.3 2 67.3 0.00 2 11.91 2 0.70 2 4.00 2 2.33 2 1.24 2 0.04 2 9 551.8 433.7 2 2147.4 2 7.8444 2 9 2354 9 9

19 2 350.0 35.860 35.865 2 13.375 13.325 27.004 179.9 2 179.7 2 74.9 0.00 2 13.47 2 0.79 2 4.80 2 9 9 9 9 558.1 425.3 2 2153.1 2 7.8246 2 9 2350 9 9

18 2 399.9 35.766 35.765 2 12.742 12.687 27.061 175.4 2 173.3 2 84.8 0.00 2 15.32 2 0.91 2 5.90 2 2.08 2 1.08 2 0.03 2 9 626.6 465.4 2 2159.0 2 7.7986 2 2347 2 2343 9 9

17 2 473.7 35.650 35.660 2 11.925 11.862 27.133 166.5 2 164.4 2 98.4 0.00 2 17.57 2 1.05 2 7.40 2 9 9 9 9 685.0 492.0 2 2166.6 2 7.7662 2 9 2335 9 9

16 2 550.3 35.553 35.554 2 11.199 11.129 27.196 156.0 2 153.9 2 113.2 0.00 2 20.11 2 1.22 2 9.30 2 1.44 2 0.74 2 0.02 2 9 731.5 509.7 2 2178.1 2 7.7329 2 9 2331 9 9

15 2 620.2 35.460 35.459 2 10.448 10.372 27.260 146.6 2 143.9 2 127.8 0.00 2 22.55 2 1.39 2 11.20 2 9 9 9 9 796.5 538.2 2 2187.4 2 7.7022 2 2335 2 2327 9 9

14 2 698.3 35.392 35.394 2 9.782 9.700 27.324 142.9 2 140.5 2 135.3 0.00 2 23.82 2 1.49 2 12.60 2 0.81 6 0.41 6 0.02 6 9 837.2 550.3 2 2193.1 2 7.6838 2 9 2325 9 9

13 2 773.3 35.289 35.292 2 8.880 8.794 27.392 130.5 2 131.6 2 150.0 0.00 2 26.26 2 1.67 2 15.20 2 9 9 9 9 920.3 582.9 2 2204.8 2 7.6510 2 9 2324 9 9

12 2 849.1 35.297 35.307 2 8.409 8.317 27.473 143.1 2 143.1 2 141.5 0.00 2 25.29 2 1.63 2 15.80 2 0.39 2 0.19 2 0.00 2 9 881.1 545.5 6 2203.9 2 7.6644 2 2333 2 2328 9 9

11 2 949.5 35.293 35.291 2 7.989 7.888 27.536 149.6 2 150.5 2 136.9 0.00 2 25.29 2 1.63 2 17.30 2 9 9 9 9 880.6 535.0 3 2205.5 2 7.6670 2 9 2331 9 9

10 2 1049.2 35.304 35.305 2 7.500 7.391 27.619 161.9 2 162.8 2 127.8 0.00 2 24.51 2 1.59 2 18.00 2 0.22 2 0.12 2 0.00 2 9 850.1 504.5 2 2202.9 6 7.6806 2 9 2334 9 9

9 2 1150.3 35.316 35.320 2 7.237 7.119 27.668 172.3 2 171.8 2 120.6 0.00 2 23.73 2 1.54 2 18.40 2 9 9 9 9 836.6 490.1 2 2203.6 2 7.6896 2 2341 2 2339 9 9

8 2 1248.2 35.330 35.329 2 6.908 6.783 27.726 183.9 2 183.1 2 111.6 0.00 2 22.85 2 1.49 2 18.60 2 0.20 2 0.10 2 0.00 2 9 799.8 460.8 2 2200.9 2 7.7027 2 2350 2 2341 9 9

7 2 1399.4 35.333 35.334 2 6.510 6.372 27.785 197.7 2 196.1 2 101.4 0.00 2 21.68 2 1.41 2 18.60 2 9 9 9 9 770.7 435.5 2 2197.7 2 7.7158 2 9 2343 9 9

6 2 1549.5 35.277 35.280 2 5.840 5.693 27.829 208.8 2 207.3 2 95.1 0.00 2 21.09 2 1.40 2 19.60 2 0.14 2 0.09 2 0.01 2 9 761.4 416.8 2 2193.6 2 7.7214 2 2348 2 2341 9 9

5 2 1699.0 35.211 35.209 2 5.243 5.088 27.850 217.1 2 216.2 2 90.8 0.00 2 21.09 2 1.41 2 21.80 2 9 9 9 9 761.3 405.2 3 2192.6 2 7.7200 2 2349 2 2340 9 9

4 2 1899.3 35.125 35.125 2 4.458 4.293 27.872 225.8 2 225.4 2 87.7 0.00 2 20.99 2 1.42 2 24.80 2 0.05 2 0.03 2 0.00 2 9 760.8 389.9 2 2192.0 2 7.7213 2 2344 2 2339 9 9

3 2 2100.2 35.066 35.064 2 3.956 3.779 27.879 229.6 2 229.3 2 87.9 9 9 9 9 9 9 9 9 767.9 381.9 2 2194.1 2 7.7190 2 2338 2 2338 9 9

2 2 2298.4 35.012 35.012 2 3.507 3.318 27.882 230.2 2 229.8 2 91.1 0.00 2 21.78 2 1.49 2 32.10 2 0.03 2 0.00 2 0.00 2 9 774.6 379.1 2 2198.3 2 7.7128 2 9 2342 9 9

1 2 2608.0 34.967 34.968 2 3.080 2.868 27.889 231.8 2 231.8 2 92.9 9 9 9 9 0.01 2 0.01 2 0.00 2 9 788.1 375.6 2 2204.2 2 7.7126 2 9 2345 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

76
A5R

NOAA Ship Ronald H. Brown

STATION 8 DATE 1/25/1998 LATITUDE 27.232° N

LONGITUDE 15.596° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

33 2 3.0 36.965 36.967 2 20.566 20.565 26.111 229.0 2 226.8 2 -6.9 0.00 2 0.00 2 0.00 2 0.30 2 2.22 2 1.27 2 0.17 2 9 344.1 352.1 6 2099.9 2 8.0276 2 2417 2 2420 9 9

32 2 23.1 36.963 36.963 2 20.568 20.564 26.111 227.2 2 226.8 2 -6.9 0.00 2 0.10 2 0.00 2 0.60 2 9 9 9 9 9 9 8.0233 2 2419 2 9 9

31 2 47.9 36.964 36.965 2 20.578 20.569 26.111 226.7 2 226.8 2 -6.9 0.00 2 0.00 2 0.01 2 0.30 2 9 9 9 9 9 2098.9 2 8.0290 2 2417 2 2420 9 9

30 2 73.5 36.965 36.966 2 20.581 20.567 26.114 226.0 2 226.8 2 -6.9 0.00 2 0.10 2 0.01 2 0.60 2 9 9 9 9 343.8 351.9 2 9 9 9 9 9

29 2 94.8 36.961 36.964 2 20.583 20.565 26.113 226.5 2 226.9 2 -7.0 0.00 2 0.10 2 0.02 2 0.40 2 9 9 9 9 9 2098.4 2 8.0226 2 2419 2 2415 9 9

28 2 144.5 36.514 36.519 2 17.710 17.685 26.517 192.9 2 200.3 2 32.3 0.01 2 4.68 2 0.26 2 1.30 2 9 9 9 9 433.1 395.1 2 2124.8 2 7.9433 2 2389 2 2389 9 9

27 2 196.8 36.328 36.323 2 16.401 16.369 26.692 192.8 2 192.5 2 46.4 0.01 2 7.22 2 0.41 2 2.00 2 2.40 6 1.32 6 0.06 6 9 9 2131.6 2 7.9082 2 2377 2 2375 9 9

26 2 247.4 36.152 36.154 2 15.297 15.259 26.812 190.1 2 192.9 2 51.5 0.00 2 8.88 2 0.50 2 2.50 2 9 9 9 9 494.1 407.9 2 2135.3 2 7.8899 2 2366 2 2367 9 9

25 2 298.5 36.016 36.023 2 14.520 14.475 26.881 177.9 2 176.2 2 72.3 0.00 2 11.91 2 0.69 2 4.00 2 2.31 2 1.22 2 0.03 2 9 9 9 9 9 9 9

24 2 349.3 35.909 35.901 2 13.759 13.708 26.962 181.1 2 177.7 2 74.8 0.00 2 13.08 2 0.77 2 4.30 2 9 9 9 9 576.6 446.9 2 2152.5 2 7.8285 2 2353 2 2351 9 9

23 2 384.2 35.855 35.854 2 13.366 13.311 27.004 180.0 2 183.7 2 71.0 0.00 2 12.98 2 0.76 2 4.20 2 9 9 9 9 9 9 9 9 9 9

22 2 474.4 35.687 35.685 2 12.196 12.132 27.110 172.8 2 173.0 2 88.3 0.00 2 16.11 2 0.97 2 6.00 2 1.95 2 1.03 2 0.03 2 9 9 2163.5 2 7.7836 2 2342 2 2340 9 9

21 2 527.7 35.591 35.602 2 11.515 11.447 27.167 169.8 2 164.8 2 100.4 0.00 2 18.06 2 1.09 2 7.50 2 9 9 9 9 695.7 490.9 2 2171.5 2 7.7589 2 2338 2 2336 9 9

20 2 623.8 35.511 35.516 2 10.727 10.649 27.252 162.1 2 158.7 2 111.3 0.00 2 20.11 2 1.23 2 9.10 2 9 9 9 9 9 9 9 9 9 9

19 2 691.5 35.448 35.453 2 10.122 10.039 27.310 152.8 2 151.2 2 122.5 0.00 2 21.67 2 1.36 2 10.70 2 0.99 2 0.52 2 0.02 2 9 9 9 9 9 9 9

18 2 771.6 35.456 35.455 2 9.681 9.590 27.394 155.6 2 159.3 2 117.1 0.00 2 21.67 2 1.35 2 11.80 2 9 9 9 9 9 9 9 9 9 9

17 2 846.6 35.404 35.410 2 9.044 8.948 27.459 158.9 2 154.7 2 125.7 0.00 2 23.04 2 1.45 2 13.80 2 9 9 9 9 803.0 510.1 6 2197.0 2 7.6978 2 2338 2 2335 9 9

16 2 936.7 35.361 35.360 2 8.342 8.240 27.537 151.8 2 155.1 2 129.9 0.00 2 24.12 2 1.54 2 15.60 2 0.38 2 0.20 2 0.00 2 9 9 9 9 9 9 9

15 2 946.4 35.374 35.373 2 8.291 8.188 27.555 153.4 2 158.6 2 126.7 0.00 2 23.82 2 1.52 2 15.20 2 9 9 9 9 823.5 506.0 2 2202.2 6 7.6886 2 2338 2 2337 9 9

14 2 1037.5 35.371 35.374 2 7.948 7.837 27.606 165.4 2 164.4 2 123.2 0.00 2 23.34 2 1.50 2 15.30 2 9 9 9 9 9 9 9 9 9 9

13 2 1139.1 35.350 35.349 2 7.368 7.250 27.676 172.3 2 173.0 2 118.5 0.00 2 23.04 2 1.50 2 16.20 2 0.22 2 0.12 2 -0.01 2 9 806.8 475.1 2 2200.9 2 7.6911 2 2341 2 2336 9 9

12 2 1238.4 35.318 35.327 2 6.868 6.744 27.722 184.2 2 181.5 2 113.5 0.00 2 22.55 2 1.48 2 17.20 2 9 9 9 9 9 9 9 9 9 9

11 2 1337.8 35.288 35.290 2 6.320 6.191 27.773 191.5 2 192.6 2 106.3 0.00 2 22.16 2 1.46 2 18.50 2 9 9 9 9 788.4 442.0 2 2197.3 2 7.7055 2 2344 2 2338 9 9

10 2 1498.5 35.205 35.205 2 5.606 5.467 27.799 199.1 2 199.5 2 104.7 0.00 2 22.46 2 1.49 2 21.30 2 0.08 2 0.05 2 -0.01 2 9 9 9 9 9 9 9

9 2 1647.6 35.150 35.152 2 4.981 4.835 27.830 208.3 2 209.5 2 99.5 0.00 2 22.17 2 1.48 2 23.40 2 9 9 9 9 9 9 9 9 9 9

8 2 1799.5 35.114 35.115 2 4.579 4.423 27.848 215.6 2 215.8 2 96.3 0.00 2 22.07 2 1.48 2 25.30 2 9 9 9 9 9 9 9 9 9 9

7 2 1941.3 35.082 35.083 2 4.242 4.076 27.860 220.5 2 220.1 2 94.8 0.00 2 21.97 2 1.48 2 27.10 2 0.03 2 0.02 2 -0.01 2 9 777.4 394.6 2 2194.7 2 7.7103 2 2341 2 2337 9 9

6 2 2098.2 35.045 35.045 2 3.864 3.689 27.872 224.7 2 226.6 2 91.3 0.00 2 21.88 2 1.48 2 28.80 2 9 9 9 9 9 9 9 9 9 9

5 2 2297.6 35.009 35.009 2 3.524 3.335 27.878 228.3 2 228.7 2 92.1 0.00 2 21.97 2 1.49 2 30.80 2 9 9 9 9 9 9 9 9 9 9

4 2 2499.8 34.985 34.984 2 3.267 3.062 27.886 230.9 2 230.9 2 92.2 0.00 2 21.97 2 1.50 2 32.50 2 0.02 2 0.00 3 0.00 2 9 781.4 378.2 2 2199.9 2 7.7122 2 2348 2 2343 9 9

3 2 2694.8 34.964 34.963 2 3.047 2.827 27.891 233.3 2 232.9 2 92.1 0.00 2 21.88 2 1.51 2 34.80 2 9 9 9 9 9 9 9 9 9 9

2 2 2895.5 34.949 34.950 2 2.902 2.664 27.896 234.4 2 234.0 2 92.4 0.00 2 22.07 2 1.52 2 37.00 2 9 9 9 9 9 2204.7 2 7.7141 2 2355 2 2349 9 9

1 2 3173.2 34.927 34.927 2 2.660 2.399 27.901 234.3 2 234.3 2 94.3 0.00 2 22.46 2 1.52 2 41.20 2 0.01 2 0.02 3 0.00 2 9 786.9 369.0 2 2213.6 2 7.7166 2 2362 2 2359 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

77
A5R

NOAA Ship Ronald H. Brown

STATION 9 DATE 1/25/1998 LATITUDE 27.032° N

LONGITUDE 16.115° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

32 2 3.7 36.900 36.900 2 20.469 20.468 26.088 234.0 2 227.3 2 -6.9 0.01 2 0.10 2 0.01 2 0.10 2 2.26 2 1.30 2 0.18 2 9 364.4 371.3 2 2097.8 6 8.0278 2 9 2417 9 9

31 2 27.9 36.901 36.901 2 20.477 20.472 26.088 224.5 2 227.4 2 -7.0 0.02 2 0.10 2 0.01 2 0.10 2 2.28 2 1.32 2 0.20 2 9 9 9 9 9 9 9

30 2 56.3 36.900 36.901 2 20.480 20.469 26.090 225.6 2 227.5 2 -7.1 0.02 2 0.10 2 0.02 2 0.10 2 2.25 6 1.31 6 0.17 6 9 9 9 9 9 9 9

29 2 84.2 36.900 36.901 2 20.486 20.470 26.092 225.7 2 227.3 2 -6.9 0.01 2 0.10 2 0.02 2 0.10 2 2.27 2 1.30 2 0.19 2 9 9 9 9 9 9 9

28 2 107.2 36.894 36.898 2 20.479 20.459 26.091 225.7 2 227.0 2 -6.5 0.02 2 0.10 2 0.02 2 0.10 2 2.24 2 1.31 2 0.17 2 9 9 9 9 9 9 9

27 2 147.9 36.620 36.621 2 18.457 18.431 26.413 194.7 2 196.4 2 32.8 0.02 2 4.49 2 0.26 2 1.00 2 2.37 2 1.35 2 0.11 2 9 9 9 9 9 9 9

26 2 174.8 36.485 36.478 2 17.402 17.372 26.573 191.7 2 193.8 2 40.3 0.01 2 5.95 2 0.34 2 1.40 2 2.43 2 1.38 2 0.08 2 9 9 9 9 9 9 9

25 2 209.4 36.365 36.368 2 16.590 16.556 26.677 192.6 2 193.4 2 44.5 0.01 2 6.83 2 0.39 2 1.80 2 2.43 2 1.38 2 0.07 2 9 9 9 9 9 9 9

24 2 247.8 36.243 36.216 2 15.868 15.829 26.754 192.9 2 194.7 2 46.9 0.01 2 8.10 2 0.48 2 2.20 2 2.47 2 1.37 2 0.05 2 9 9 9 9 9 9 9

23 2 299.1 36.066 36.070 2 14.742 14.697 26.872 190.5 2 188.3 2 59.0 0.00 2 10.25 2 0.61 2 3.10 2 2.42 2 1.34 2 0.03 2 9 9 9 9 9 9 9

22 2 351.9 35.938 35.935 2 13.896 13.845 26.956 186.0 2 181.9 2 69.9 0.00 2 12.49 2 0.75 2 4.00 2 9 9 0.05 2 9 9 9 9 9 9 9

21 2 398.2 35.835 35.838 2 13.263 13.207 27.011 181.1 2 176.6 2 78.7 0.00 2 14.06 2 0.84 2 4.70 2 2.19 2 1.18 2 0.03 2 9 9 9 9 9 9 9

20 2 496.8 35.632 35.635 2 11.884 11.818 27.128 160.7 2 155.7 2 107.4 0.00 2 18.65 2 1.15 2 7.50 2 1.67 2 0.89 2 0.02 2 9 9 9 9 9 9 9

19 2 599.6 35.515 35.513 2 10.954 10.878 27.213 150.6 2 147.3 2 121.3 0.00 2 21.19 2 1.33 2 9.80 2 1.29 2 0.68 2 0.02 2 9 9 9 9 9 9 9

18 2 698.8 35.347 35.348 2 9.582 9.501 27.321 132.5 2 128.6 2 148.5 0.00 2 25.49 2 4 13.80 2 0.69 2 0.35 2 0.01 2 9 9 9 9 9 9 9

17 2 799.4 35.290 35.290 2 8.881 8.791 27.393 129.4 2 130.7 2 150.9 0.00 2 26.37 2 1.70 2 15.70 2 0.47 2 0.24 2 0.01 2 9 9 9 9 9 9 9

16 2 899.6 35.253 35.255 2 8.137 8.041 27.481 136.8 2 139.7 2 146.8 0.00 2 26.56 2 1.73 2 17.50 2 0.28 2 0.14 2 0.00 2 9 9 9 9 9 9 9

15 2 1001.7 35.255 35.254 2 7.556 7.452 27.570 149.7 2 152.1 2 138.2 0.00 2 25.98 2 1.70 2 18.60 2 0.21 2 0.11 2 0.00 2 9 9 9 9 9 9 9

14 2 1098.4 35.282 35.282 2 7.332 7.219 27.626 161.4 2 161.3 2 130.5 0.00 2 24.80 2 1.64 2 18.60 2 0.18 2 0.10 2 0.00 2 9 9 9 9 9 9 9

13 2 1199.0 35.268 35.268 2 6.745 6.626 27.698 172.7 2 174.0 2 121.9 0.00 2 23.92 2 1.59 2 19.10 2 0.14 2 0.08 2 0.00 2 9 9 9 9 9 9 9

12 2 1398.8 35.229 35.228 2 5.883 5.752 27.782 195.0 2 194.7 2 107.4 0.00 2 22.75 2 1.52 2 20.40 2 0.10 2 0.06 2 0.00 2 9 9 9 9 9 9 9

11 2 1597.1 35.187 35.183 2 5.249 5.104 27.828 207.4 2 208.7 2 98.2 0.00 2 22.07 2 1.48 2 21.70 2 9 9 9 9 9 9 9 9 9 9

10 2 1800.9 35.114 35.114 2 4.512 4.356 27.855 219.5 2 218.9 2 93.7 0.00 2 21.97 2 1.48 2 24.20 2 0.03 2 0.02 2 0.00 2 9 9 9 9 9 9 9

9 2 1999.1 35.069 35.069 2 4.083 3.914 27.867 224.8 2 224.3 2 91.8 0.00 2 21.68 2 1.48 2 26.60 2 9 9 9 9 9 9 9 9 9 9

8 2 2192.4 35.028 35.030 2 3.695 3.513 27.876 226.8 2 227.3 2 92.1 0.00 2 21.78 2 1.49 2 30.20 2 0.02 2 0.01 2 0.00 2 9 9 9 9 9 9 9

7 2 2398.1 34.999 34.998 2 3.406 3.209 27.883 229.3 2 229.4 2 92.5 0.00 2 21.88 2 1.50 2 33.10 2 9 9 9 9 9 9 9 9 9 9

6 2 2598.7 34.971 34.971 2 3.130 2.918 27.889 232.7 2 232.8 2 91.5 0.00 2 21.98 2 1.51 2 35.90 2 0.01 6 0.01 6 0.00 6 9 9 9 9 9 9 9

5 2 2799.8 34.955 34.955 2 2.964 2.735 27.893 234.1 2 233.9 2 91.9 0.00 2 22.17 2 1.51 2 38.40 2 9 9 9 9 9 9 9 9 9 9

4 2 2988.9 34.937 34.937 2 2.769 2.524 27.898 234.5 2 235.1 2 92.5 0.00 2 22.46 2 1.53 2 40.70 2 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

3 2 3200.0 34.924 34.925 2 2.647 2.383 27.901 235.0 2 235.0 2 93.8 0.00 2 22.56 2 1.54 2 42.10 2 9 9 9 9 9 9 9 9 9 9

2 2 3399.8 34.917 34.918 2 2.570 2.287 27.904 234.7 2 233.8 2 95.8 0.00 2 22.66 2 1.55 2 43.00 2 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

1 2 3524.5 34.916 34.916 2 2.579 2.282 27.905 234.6 2 234.1 2 95.5 0.00 6 22.56 6 1.55 6 43.70 6 0.01 2 0.00 2 0.00 2 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

78
A5R

NOAA Ship Ronald H. Brown

STATION 10 DATE 1/25/1998 LATITUDE 26.833° N

LONGITUDE 16.668° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

35 2 28.9 36.890 36.889 2 20.521 20.516 26.069 222.2 2 223.6 2 -3.4 0.02 2 0.10 2 0.01 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 351.1 358.6 2 2097.5 6 8.0239 2 2417 2 2414 65.0 2 -9.0 9

34 2 58.0 36.890 36.890 2 20.526 20.515 26.070 221.8 2 224.0 2 -3.8 0.02 2 0.10 2 0.01 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 351.9 359.5 2 2098.0 2 8.0217 2 -9 9 2413 61.1 2 -9.0 9

33 2 83.4 36.889 36.890 2 20.528 20.512 26.072 222.8 2 223.6 2 -3.3 0.02 2 0.10 2 0.02 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 353.2 360.7 2 2098.3 2 8.0224 2 2416 2 2414 65.9 2 -9.0 9

32 2 116.9 36.764 36.749 2 19.832 19.810 26.166 221.7 2 207.2 2 16.1 0.06 2 2.24 2 0.15 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 392.5 389.9 6 2113.5 2 7.9868 2 2410 2 2406 56.6 2 -9.0 9

31 2 159.5 36.531 36.530 2 17.744 17.717 26.523 189.9 2 194.2 2 38.3 0.01 2 4.97 2 0.29 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 437.0 398.9 2 2127.3 2 -9.0000 9 -9 9 -9 51.8 2 -9.0 9

30 2 200.0 36.382 36.374 2 16.706 16.673 26.662 194.7 2 194.8 2 42.6 0.01 2 6.15 2 0.36 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 452.2 395.6 2 2129.1 2 7.9233 2 2378 2 2381 48.6 2 -9.0 9

29 2 248.8 36.190 36.196 2 15.538 15.499 26.788 188.0 2 185.9 2 57.3 0.00 2 8.78 2 0.51 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 493.5 411.3 2 2138.3 2 7.8960 2 2369 2 2374 -9.0 9 -9.0 9

28 2 300.4 35.972 35.968 2 14.269 14.224 26.901 166.5 2 162.3 2 87.5 0.00 2 13.56 2 0.80 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 583.1 461.3 2 2159.1 2 -9.0000 4 -9 9 -9 46.9 2 -9.0 9

27 2 348.8 35.913 35.914 2 13.804 13.753 26.956 171.3 2 171.5 2 80.8 0.00 2 13.37 2 0.79 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 580.9 450.7 2 2153.2 2 7.8266 2 2353 2 2351 -9.0 9 -9.0 9

26 2 400.8 35.818 35.813 2 13.145 13.089 27.021 174.0 2 172.2 2 83.7 0.00 2 14.54 2 0.86 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 605.1 456.7 2 2156.2 2 7.8102 2 2347 2 2345 45.7 2 -9.0 9

25 2 450.9 35.709 35.705 2 12.364 12.303 27.093 173.0 2 172.7 2 87.6 0.00 2 15.91 2 0.95 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 642.0 469.0 2 2159.1 2 7.7906 2 -9 9 2338 -9.0 9 -9.0 9

24 2 499.1 35.604 35.609 2 11.651 11.586 27.150 167.2 2 159.9 2 104.5 0.00 2 18.54 2 1.12 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 688.9 488.5 2 2170.2 2 7.7572 2 2339 2 2334 46.4 2 -9.0 9

23 2 548.8 35.532 35.530 2 11.134 11.064 27.191 153.5 2 149.8 2 117.7 0.00 2 20.69 2 1.25 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 742.4 515.7 2 2178.4 2 7.7291 2 -9 9 2330 -9.0 9 -9.0 9

22 2 598.1 35.477 35.477 2 10.640 10.566 27.239 146.9 2 145.4 2 125.1 0.00 2 21.77 2 1.34 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 771.6 524.7 2 2183.3 2 7.7141 2 -9 9 2328 43.4 2 -9.0 9

21 2 649.8 35.451 35.449 2 10.282 10.203 27.283 148.1 2 145.0 2 127.7 0.00 2 22.35 2 1.39 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 793.1 531.4 2 2188.0 2 7.7052 2 2331 2 2329 -9.0 9 -9.0 9

20 2 694.4 35.374 35.375 2 9.691 9.610 27.324 141.4 2 135.1 2 141.3 0.00 2 24.50 2 1.54 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 852.6 557.8 2 2199.1 6 7.6767 2 2332 2 2328 42.6 2 -9.0 9

19 2 749.0 35.349 35.349 2 9.300 9.214 27.372 138.3 2 136.8 2 142.1 0.00 2 24.89 2 1.58 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 867.4 558.1 2 2205.4 2 7.6724 2 -9 9 2333 -9.0 9 -9.0 9

18 2 799.9 35.305 35.303 2 8.735 8.646 27.428 134.9 2 135.5 2 147.0 0.00 2 25.87 2 1.64 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 894.1 561.8 2 2204.4 2 7.6629 2 2333 2 2328 49.7 2 -9.0 9

17 2 900.6 35.318 35.312 2 8.275 8.178 27.512 146.7 2 145.7 2 139.8 0.00 2 25.28 2 1.61 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 877.9 539.9 2 2201.9 2 7.6701 2 2334 2 2328 -9.0 9 -9.0 9

16 2 1000.1 35.346 35.346 2 7.929 7.823 27.589 156.7 2 158.4 2 129.3 0.00 2 24.21 2 1.54 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 822.5 496.8 2 2200.5 2 7.6849 2 -9 9 2333 42.4 2 -9.0 9

15 2 1098.5 35.362 35.363 2 7.591 7.476 27.653 169.7 2 168.9 2 121.1 0.00 2 23.43 2 1.50 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 795.7 472.7 2 2201.1 2 7.6976 2 2342 2 2339 -9.0 9 -9.0 9

14 2 1198.1 35.287 35.288 2 6.829 6.710 27.701 173.8 2 173.4 2 121.9 0.00 2 23.92 2 1.55 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 813.8 467.2 2 2202.4 2 -9.0000 4 2341 2 -9 42.5 2 -9.0 9

13 2 1298.2 35.304 35.304 2 6.602 6.474 27.747 185.2 2 184.1 2 112.8 0.00 2 22.84 2 1.48 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 781.0 443.1 2 2198.9 2 7.7040 2 -9 9 2339 -9.0 9 -9.0 9

12 2 1399.1 35.238 35.237 2 5.957 5.825 27.780 193.2 2 191.3 2 110.3 0.00 2 22.75 2 1.50 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 802.6 442.4 2 2198.0 2 7.7005 2 2338 2 2337 42.1 2 -9.0 9

11 2 1500.5 35.213 35.216 2 5.591 5.452 27.807 200.8 2 199.4 2 104.9 0.00 2 22.26 2 1.47 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 794.4 430.4 2 2194.5 2 7.7075 2 -9 5 2336 -9.0 9 -9.0 9

10 2 1600.1 35.192 35.191 2 5.309 5.163 27.825 207.4 2 204.9 2 101.5 0.00 2 21.97 2 1.46 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 777.4 415.2 2 2193.3 2 7.7097 2 -9 9 2335 42.4 2 -9.0 9

9 2 1799.0 35.110 35.111 2 4.533 4.377 27.850 217.2 2 215.5 2 97.0 0.00 2 21.77 2 1.46 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 785.9 404.8 2 2189.1 2 7.7116 2 2337 2 2331 -9.0 9 -9.0 9

8 2 1998.7 35.074 35.074 2 4.147 3.977 27.865 222.5 2 221.3 2 94.3 0.00 2 21.77 2 1.47 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 774.8 391.3 2 2190.7 2 7.7141 2 2344 2 2334 42.3 2 -9.0 9

7 2 2201.0 35.036 35.035 2 3.763 3.579 27.876 226.3 2 225.4 2 93.4 0.00 2 21.77 2 1.48 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 775.8 384.4 2 2193.7 2 7.7135 2 -9 9 2337 -9.0 9 -9.0 9

6 2 2450.4 34.990 34.991 2 3.327 3.126 27.884 229.1 2 228.7 2 93.8 0.00 2 21.97 2 1.50 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 777.9 377.2 2 2197.1 2 7.7137 2 2344 2 2340 41.8 2 -9.0 9

5 3 2632.8 34.966 34.964 2 3.072 2.857 27.890 231.9 2 230.1 2 94.7 0.00 2 22.07 2 1.51 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 777.6 372.1 2 2199.6 2 7.7137 2 -9 9 2342 -9.0 9 -9.0 9

4 2 2947.3 34.940 34.939 2 2.810 2.569 27.897 233.4 2 231.9 2 95.3 0.00 2 22.26 2 1.54 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 776.2 366.4 2 2205.4 2 7.7163 2 -9 9 2350 41.6 2 -9.0 9

3 2 3147.2 34.929 34.929 2 2.689 2.430 27.900 233.5 2 232.7 2 95.7 0.00 2 22.17 2 1.53 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 775.2 363.6 2 2209.0 2 -9.0000 4 2360 2 -9 41.3 2 -9.0 9

2 2 3391.7 34.918 34.918 2 2.587 2.304 27.904 233.0 2 233.0 2 96.4 0.00 2 22.56 2 1.54 2 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 774.5 361.4 2 2214.6 2 7.7186 2 2364 2 2360 42.2 2 -9.0 9

1 2 3658.1 34.909 34.910 2 2.516 2.206 27.907 234.2 2 233.9 2 96.4 0.00 6 22.56 6 1.55 6 -9.00 4 -9.00 9 -9.00 9 -9.00 9 -9.00 9 770.9 358.3 2 2215.3 2 7.7177 2 -9 9 2360 42.1 2 -9.0 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS-90 scale

79
A5R

NOAA Ship Ronald H. Brown

STATION 11 DATE 1/25/1998 LATITUDE 26.667° N

LONGITUDE 17.199° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.0 36.986 36.986 2 20.701 20.700 26.090 224.8 2 223.7 2 -4.3 0.00 2 0.00 2 0.00 2 4 2.26 2 1.32 2 0.19 2 9 343.6 353.4 2 2098.0 6 8.0316 2 2421 6 2421 9 9

35 2 27.2 36.986 36.986 2 20.705 20.700 26.092 222.5 2 219.1 2 0.3 0.00 2 0.00 2 0.00 2 4 1 1 0.19 2 9 346.1 356.1 2 2096.3 2 8.0297 2 2420 2 2418 9 9

34 2 58.2 36.983 36.981 2 20.700 20.689 26.094 221.9 2 223.4 2 -4.0 0.01 2 0.10 2 0.01 2 4 2.22 2 1.27 2 0.17 2 9 9 9 9 9 9 9

33 2 90.1 36.869 36.831 2 20.222 20.205 26.140 206.5 2 211.8 2 9.8 0.09 2 1.66 2 0.08 2 4 2.23 6 1.29 6 0.16 6 9 376.2 379.8 2 2107.0 2 7.9984 2 2408 2 2407 9 9

32 2 120.1 36.402 36.392 2 17.776 17.755 26.413 145.7 2 149.4 2 83.1 0.01 2 10.63 2 0.67 2 4 2.09 2 1.20 2 0.09 2 9 9 9 9 9 9 9

31 2 160.4 36.358 36.364 2 16.915 16.888 26.591 162.1 2 163.8 2 72.6 0.01 2 9.56 2 0.58 2 4 9 9 9 9 9 2146.5 2 4 2379 2 9 9

30 2 201.3 36.324 36.313 2 16.305 16.272 26.712 196.4 2 196.9 2 42.4 0.00 2 6.63 2 0.35 2 4 2.48 2 1.40 2 0.05 2 9 457.8 393.7 2 2126.3 2 7.9190 2 2378 2 2375 9 9

29 2 251.0 36.167 35.991 2 15.397 15.358 26.802 193.9 2 194.6 2 49.6 0.00 2 8.39 2 0.45 2 4 2.50 2 1.40 2 0.05 2 9 9 9 9 9 9 9

28 2 300.9 35.997 35.990 2 14.368 14.323 26.899 179.1 2 174.2 2 75.1 0.00 2 12.20 2 0.69 2 4 2.33 2 1.28 2 0.03 2 9 558.2 443.0 2 2148.7 2 7.8414 2 5 2354 9 9

27 2 350.3 35.885 35.886 2 13.722 13.671 26.952 157.3 2 157.4 2 95.4 0.00 2 15.13 2 0.89 2 4 2.08 2 1.13 2 0.03 2 9 9 9 9 9 9 9

26 2 400.9 35.803 35.805 2 12.998 12.942 27.039 178.4 2 179.7 2 77.0 0.00 2 13.86 2 0.80 2 4 2.24 2 1.21 2 0.04 2 9 594.4 445.7 2 2152.4 2 7.8174 2 2352 2 2345 9 9

25 2 449.6 35.740 35.738 2 12.516 12.455 27.088 185.0 2 181.9 2 77.5 0.00 2 14.64 2 0.85 2 4 9 9 9 9 9 9 9 9 9 9

24 2 500.5 35.672 35.668 2 12.008 11.941 27.136 181.6 2 178.1 2 84.3 0.00 2 15.91 2 0.94 2 4 1.98 2 1.07 2 0.04 2 9 9 2160.0 2 7.7896 2 2348 2 2339 9 9

23 2 550.1 35.607 35.607 2 11.492 11.421 27.184 175.4 2 171.7 2 93.7 0.00 2 17.38 2 1.04 2 4 9 9 9 9 9 9 9 9 9 9

22 2 600.2 35.539 35.537 2 10.894 10.819 27.242 166.6 2 162.8 2 106.1 0.00 2 19.33 2 1.17 2 4 1.41 2 0.75 2 0.02 2 9 721.7 495.8 2 2174.4 2 7.7437 2 9 2332 9 9

21 2 648.1 35.453 35.452 2 10.195 10.117 27.299 154.6 2 148.3 2 124.9 0.00 2 21.97 2 1.36 2 4 9 9 9 9 9 9 9 9 9 9

20 2 700.9 35.414 35.421 2 9.675 9.593 27.359 148.7 2 147.9 2 128.5 0.00 2 22.75 2 1.42 2 4 0.79 2 0.42 2 0.01 2 9 9 2190.7 2 7.7010 2 9 2330 9 9

19 2 751.0 35.354 35.353 2 9.239 9.153 27.385 140.3 2 138.9 2 140.3 0.00 2 24.60 2 1.55 2 4 9 9 9 9 9 9 9 9 9 9

18 2 799.8 35.340 35.343 2 8.906 8.816 27.428 140.6 2 142.7 2 138.7 0.00 2 24.70 2 1.56 2 4 0.47 6 0.24 6 0.00 6 9 855.4 540.7 2 2200.0 2 7.6761 2 2332 2 2329 9 9

17 2 896.9 35.236 35.235 2 7.921 7.826 27.500 145.3 2 138.1 2 149.8 0.00 2 26.66 2 1.72 2 4 9 9 9 9 9 9 9 9 9 9

16 2 1001.1 35.261 35.265 2 7.587 7.483 27.571 153.7 2 151.1 2 139.0 0.00 2 25.58 2 1.66 2 4 0.16 2 0.08 2 0.00 2 9 875.1 521.5 2 2205.0 6 7.6662 2 9 2330 9 9

15 2 1100.2 35.258 35.262 2 7.120 7.009 27.637 163.3 2 157.2 2 136.1 0.00 2 25.00 2 1.64 2 4 9 9 9 9 9 9 9 9 9 9

14 3 1200.0 35.345 35.340 2 7.097 6.975 27.712 179.0 2 176.2 2 117.2 0.00 2 22.94 2 1.50 2 4 0.17 2 0.09 2 0.00 2 9 801.5 465.7 2 2197.2 2 7.7007 2 2341 2 2336 9 9

13 2 1299.8 35.320 35.320 2 6.673 6.544 27.751 186.8 2 185.4 2 110.9 0.00 2 22.26 2 1.47 2 4 9 9 9 9 9 9 9 9 9 9

12 2 1399.8 35.300 35.301 2 6.229 6.094 27.795 196.3 2 196.3 2 103.2 0.00 2 21.68 2 1.44 2 4 0.15 6 0.09 6 0.00 6 9 775.2 432.2 2 2193.5 2 7.7132 2 2345 2 2338 9 9

11 2 1500.8 35.267 35.269 2 5.806 5.665 27.824 204.9 2 205.7 2 96.9 0.00 2 21.19 2 1.41 2 4 9 9 9 9 9 9 9 9 9 9

10 2 1600.2 35.223 35.223 2 5.375 5.229 27.843 211.7 2 210.3 2 95.6 0.00 2 21.09 2 1.39 2 4 0.09 2 0.04 2 -0.01 2 9 9 9 9 9 9 9

9 2 1800.4 35.138 35.139 2 4.606 4.449 27.864 219.9 2 219.2 2 92.7 0.00 2 21.09 2 1.41 2 4 9 9 9 9 9 9 9 9 9 9

8 2 2002.6 35.083 35.083 2 4.135 3.965 27.873 223.4 2 224.1 2 91.6 0.00 2 21.29 2 1.43 2 4 0.05 2 0.00 2 0.00 2 9 766.7 386.7 2 2191.7 2 7.7196 2 9 2337 9 9

7 2 2179.7 35.038 35.037 2 3.743 3.561 27.879 225.5 2 225.7 2 93.3 0.00 2 21.58 2 1.45 2 4 9 9 9 9 9 9 9 9 9 9

6 2 2449.7 34.990 34.992 2 3.303 3.102 27.886 229.7 2 229.0 2 93.7 0.00 2 21.78 2 1.47 2 4 0.01 2 -0.01 2 0.00 2 9 9 9 9 9 9 9

5 2 2648.1 34.970 34.970 2 3.096 2.879 27.891 232.2 2 231.4 2 93.2 0.00 2 21.88 2 1.48 2 4 9 9 9 9 773.4 370.5 2 2199.9 2 7.7155 2 2351 2 2344 9 9

4 2 2901.3 34.947 34.948 2 2.861 2.623 27.897 233.8 2 233.0 2 93.7 0.00 2 21.97 2 1.50 2 4 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

3 2 3150.8 34.931 34.931 2 2.704 2.444 27.901 233.6 2 233.3 2 94.9 0.00 2 22.17 2 1.51 2 4 9 9 9 9 776.1 364.5 2 2206.9 2 7.7167 2 2364 2 2351 9 9

2 2 3400.2 34.917 34.917 2 2.568 2.285 27.904 233.1 2 233.9 2 95.7 0.00 2 22.37 2 1.52 2 4 9 9 9 9 9 9 9 9 9 9

1 2 3703.9 34.904 34.904 2 2.457 2.143 27.908 237.5 2 238.7 2 92.1 0.00 6 22.27 6 1.51 6 4 0.00 2 0.00 4 0.00 2 9 772.8 358.2 2 2206.7 2 7.7217 2 9 2353 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

80
A5R

NOAA Ship Ronald H. Brown

STATION 12 DATE 1/25/1998 LATITUDE 26.517° N

LONGITUDE 17.867° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* CTA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.5 37.082 37.085 2 21.020 21.019 26.076 224.2 2 221.7 2 -3.7 0.00 4 0.00 2 4 4 9 9 9 9 339.8 354.0 2 2098.4 6 8.0368 6 2423 2 2426 9 9

35 2 21.1 37.081 37.081 2 21.032 21.028 26.074 222.9 2 222.9 2 -4.9 0.00 2 0.00 2 4 4 9 9 9 9 9 9 9 9 9 9

34 2 44.4 37.081 37.080 2 21.030 21.021 26.077 221.3 2 222.3 2 -4.3 0.00 2 0.00 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

33 2 68.0 37.080 37.081 2 21.031 21.018 26.078 221.2 2 222.4 2 -4.4 0.00 2 0.10 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

32 2 99.4 37.066 37.045 2 20.981 20.962 26.085 218.0 2 221.5 2 -3.2 0.01 2 0.20 2 4 0.50 2 9 9 9 9 9 9 9 9 9 9

31 2 149.5 36.521 36.520 2 17.701 17.675 26.525 207.2 2 210.6 2 22.1 0.01 2 2.63 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

30 2 198.6 36.365 36.368 2 16.772 16.739 26.634 193.0 2 171.0 2 66.1 0.01 2 8.88 2 4 2.80 2 9 9 9 9 9 9 9 9 9 9

29 2 250.2 36.245 36.244 2 15.868 15.828 26.756 195.7 2 196.2 2 45.3 0.01 2 7.42 2 4 2.30 2 9 9 9 9 9 9 9 9 9 9

28 2 299.2 36.089 36.085 2 14.901 14.855 26.855 191.5 2 194.1 2 52.4 0.00 2 9.17 2 4 3.00 2 9 9 9 9 9 9 9 9 9 9

27 2 350.8 35.958 35.957 2 14.046 13.994 26.940 189.9 2 187.2 2 63.8 0.00 2 11.32 2 4 3.90 2 9 9 9 9 9 9 9 9 9 9

26 2 398.2 35.872 35.865 2 13.490 13.433 26.992 186.7 2 184.3 2 69.7 0.00 2 12.59 2 4 4.50 2 9 9 9 9 9 9 9 9 9 9

25 2 448.8 35.759 35.753 2 12.806 12.744 27.046 174.6 2 163.4 2 94.5 0.00 2 15.91 2 4 6.20 2 9 9 9 9 9 9 9 9 9 9

24 2 500.1 35.646 35.643 2 12.021 11.954 27.113 158.2 2 158.8 2 103.5 0.00 2 17.86 2 4 7.10 2 9 9 9 9 9 9 9 9 9 9

23 2 550.2 35.548 35.545 2 11.295 11.224 27.175 157.3 2 148.5 2 118.1 0.00 2 20.21 2 4 8.70 2 9 9 9 9 9 9 9 9 9 9

22 2 623.8 35.458 35.458 2 10.489 10.412 27.252 150.5 2 142.8 2 128.6 0.00 2 22.07 2 4 10.70 2 9 9 9 9 9 9 9 9 9 9

21 2 699.4 35.394 35.396 2 9.762 9.680 27.329 141.5 2 140.4 2 135.5 0.00 2 23.53 2 4 12.90 2 9 9 9 9 9 9 9 9 9 9

20 2 774.4 35.319 35.318 2 8.949 8.862 27.405 136.4 2 135.1 2 146.0 0.00 2 25.49 2 4 15.00 2 9 9 9 9 9 9 9 9 9 9

19 2 850.5 35.248 35.247 2 8.275 8.183 27.455 136.6 2 133.8 2 151.8 0.00 2 26.76 2 4 17.10 2 9 9 9 9 9 9 9 9 9 9

18 2 923.5 35.229 35.227 2 7.820 7.723 27.509 138.3 2 140.7 2 147.9 0.00 2 26.66 2 4 18.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1025.0 35.252 35.252 2 7.486 7.380 27.578 149.4 2 152.0 2 138.8 0.00 2 25.68 2 4 18.60 2 9 9 9 9 9 9 9 9 9 9

16 2 1125.3 35.294 35.293 2 7.249 7.134 27.648 161.3 2 163.7 2 128.7 0.00 2 24.12 2 4 18.50 2 9 9 9 9 9 9 9 9 9 9

15 2 1224.4 35.311 35.306 2 6.982 6.858 27.701 175.1 2 174.7 2 119.5 0.00 2 23.34 2 4 18.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1325.9 35.248 35.249 2 6.289 6.161 27.745 183.8 2 182.2 2 117.0 0.00 2 23.34 2 4 19.70 2 9 9 9 9 9 9 9 9 9 9

13 2 1450.0 35.192 35.192 2 5.665 5.531 27.780 193.6 2 192.0 2 111.8 0.00 2 23.14 2 4 20.60 2 9 9 9 9 9 9 9 9 9 9

12 2 1574.5 35.168 35.170 2 5.204 5.062 27.818 204.5 2 203.6 2 103.6 0.00 2 22.07 2 4 21.80 2 9 9 9 9 9 9 9 9 9 9

11 2 1699.5 35.154 35.153 2 4.936 4.785 27.840 212.0 2 211.0 2 98.3 0.00 2 21.78 2 4 22.90 2 9 9 9 9 9 9 9 9 9 9

10 2 1823.7 35.124 35.123 2 4.555 4.397 27.859 218.0 2 218.0 2 94.3 0.00 2 21.48 2 4 24.60 2 9 9 9 9 9 9 9 9 9 9

9 2 1999.5 35.085 35.086 2 4.172 4.002 27.871 223.1 2 223.3 2 92.1 0.00 2 21.29 2 4 26.70 2 9 9 9 9 9 9 9 9 9 9

8 2 2167.7 35.047 35.049 2 3.807 3.626 27.880 227.0 2 227.4 2 91.0 0.00 2 21.49 2 4 29.10 2 9 9 9 9 9 9 9 9 9 9

7 2 2348.1 35.010 35.011 2 3.471 3.277 27.885 229.2 2 229.9 2 91.4 0.00 2 21.49 2 4 32.00 2 9 9 9 9 9 9 9 9 9 9

6 2 2549.9 34.980 34.982 2 3.188 2.979 27.890 231.7 2 231.8 2 91.9 0.00 2 21.78 2 4 34.80 2 9 9 9 9 9 9 9 9 9 9

5 2 2747.3 34.958 34.958 2 2.965 2.741 27.895 232.9 2 219.7 4 106.0 0.00 2 21.88 2 4 4 9 9 9 9 9 9 9 9 9 9

4 2 2949.7 34.940 34.942 2 2.798 2.557 27.898 233.8 2 234.0 2 93.3 0.00 2 21.88 2 4 40.00 2 9 9 9 9 9 9 9 9 9 9

3 2 3198.2 34.925 34.926 2 2.646 2.382 27.901 233.5 2 234.0 2 94.8 0.00 2 22.27 2 4 41.20 2 9 9 9 9 9 9 9 9 9 9

2 2 3448.1 34.914 34.916 2 2.543 2.255 27.905 233.6 2 234.4 2 95.4 0.00 2 22.37 2 4 43.30 2 9 9 9 9 9 9 9 9 9 9

1 2 3701.7 34.903 34.904 2 2.446 2.133 27.908 237.5 2 238.8 2 92.1 0.00 6 22.37 6 4 45.00 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

81
A5R

NOAA Ship Ronald H. Brown

STATION 13 DATE 1/26/1998 LATITUDE 26.498° N

LONGITUDE 18.335° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

35 2 3.7 37.015 37.014 2 21.327 21.326 25.940 222.4 2 220.3 2 -3.4 0.03 2 0.10 2 4 1.20 2 2.12 2 1.22 2 0.17 2 9 345.7 364.5 3 2099.4 6 8.0328 2 2420 2 2423 9 9

34 2 23.8 37.013 37.012 2 21.322 21.317 25.942 219.8 2 220.7 2 -3.8 0.03 2 0.10 2 4 1.10 2 9 9 9 9 343.7 362.3 2 2101.4 2 8.0313 2 2422 2 2425 9 9

33 2 49.8 37.013 37.014 2 21.334 21.324 25.941 218.1 2 220.5 2 -3.6 0.03 2 0.10 2 4 1.20 2 2.14 2 1.24 2 0.16 2 9 9 9 9 9 9 9

32 2 73.8 37.037 37.047 2 21.390 21.376 25.947 217.8 2 219.5 2 -2.8 0.03 2 0.10 2 4 1.00 2 9 9 9 9 341.8 361.3 2 2101.8 2 8.0335 2 2429 2 2427 9 9

31 2 100.1 37.111 37.117 2 21.516 21.496 25.971 218.3 2 215.9 2 0.2 0.06 2 0.20 2 4 1.00 2 2.12 2 1.25 2 0.16 2 9 9 9 9 9 9 9

30 2 122.8 36.658 36.666 2 19.035 19.013 26.293 196.4 2 186.2 2 40.5 0.04 2 4.98 2 4 2.00 2 9 9 9 9 436.5 420.3 2 2132.2 2 7.9414 2 2396 2 2397 9 9

29 2 149.3 36.513 36.521 2 17.867 17.841 26.478 174.1 2 171.0 2 60.9 0.01 2 7.61 2 4 2.70 2 9 9 9 9 9 2143.6 2 7.9047 2 9 2386 9 9

28 2 199.5 36.456 36.440 2 17.224 17.190 26.595 171.9 2 179.4 2 55.5 0.01 2 7.42 2 4 2.40 2 2.35 6 1.30 6 0.06 6 9 467.3 417.7 2 2136.6 2 7.9090 2 2383 2 2381 9 9

27 2 246.1 36.189 36.194 2 15.813 15.774 26.725 151.4 2 156.9 2 85.0 0.00 2 11.81 2 4 4.00 2 9 9 9 9 9 9 9 9 9 9

26 2 300.6 36.063 36.072 2 14.786 14.740 26.860 175.2 2 180.4 2 66.7 0.00 2 10.74 2 4 3.80 2 2.37 2 1.29 2 0.02 2 9 527.7 426.3 2 2143.5 2 7.8640 2 2359 2 2361 9 9

25 2 341.5 35.973 35.977 2 14.219 14.168 26.915 177.5 2 175.9 2 74.2 0.00 2 12.10 2 4 4.40 2 9 9 9 9 9 9 9 9 9 9

24 2 399.3 35.875 35.871 2 13.599 13.542 26.973 175.7 2 169.1 2 84.3 0.00 2 13.96 2 4 5.20 2 2.17 2 1.17 2 0.02 2 9 9 2155.1 2 7.8169 2 2350 2 2347 9 9

23 2 501.3 35.676 35.676 2 12.191 12.124 27.104 170.0 2 168.0 2 93.3 0.00 2 16.50 2 4 6.50 2 9 9 9 9 657.8 477.3 2 2163.6 2 7.7821 2 2342 2 2338 9 9

22 2 551.6 35.608 35.610 2 11.654 11.582 27.155 166.7 2 164.8 2 99.7 0.00 2 17.77 2 4 7.40 2 9 9 9 9 9 9 9 9 9 9

21 2 598.3 35.548 35.547 2 11.164 11.088 27.201 161.9 2 158.5 2 108.9 0.00 2 19.33 2 4 8.70 2 1.43 2 0.76 2 0.01 2 9 9 2176.9 2 7.7440 2 9 2334 9 9

20 2 694.6 35.406 35.404 2 10.008 9.925 27.296 139.2 2 136.1 2 138.3 0.00 2 23.63 2 4 12.20 2 9 9 9 9 9 9 9 9 9 9

19 2 794.6 35.309 35.310 2 8.961 8.872 27.395 133.3 2 131.8 2 149.3 0.00 2 25.78 2 4 15.10 2 0.38 2 0.20 2 0.00 2 9 889.9 564.6 2 2204.0 2 7.6615 2 2329 2 2325 9 9

18 2 890.6 35.248 35.245 2 8.267 8.171 27.457 133.6 2 132.8 2 152.9 0.00 2 26.76 2 4 17.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1001.0 35.157 35.157 2 7.298 7.196 27.529 140.7 2 138.4 2 153.9 0.00 2 27.64 2 4 19.60 2 0.10 2 0.06 2 0.00 2 9 955.2 564.2 2 2212.5 6 7.6370 2 2329 2 2324 9 9

16 2 1098.1 35.236 35.235 2 7.182 7.071 27.611 157.3 2 155.1 2 137.8 0.00 2 25.59 2 4 18.90 2 9 9 9 9 9 9 9 9 9 9

15 2 1200.6 35.223 35.224 2 6.729 6.610 27.665 165.4 2 165.7 2 130.4 0.00 2 25.10 2 4 19.80 2 0.09 3 0.08 3 0.00 2 9 863.0 494.6 6 2203.3 2 7.6695 2 2334 2 2328 9 9

14 2 1296.0 35.188 35.186 2 6.090 5.967 27.721 176.8 2 175.7 2 125.0 0.00 2 24.42 2 4 20.60 2 9 9 9 9 9 9 9 9 9 9

13 2 1399.0 35.269 35.269 2 6.204 6.069 27.774 191.0 2 189.2 2 110.6 0.00 2 22.36 2 4 19.20 2 0.11 2 0.05 2 0.00 2 9 795.9 443.8 2 2195.4 2 7.7008 2 2337 2 2333 9 9

12 2 1499.7 35.181 35.184 2 5.416 5.279 27.802 199.1 2 197.7 2 107.9 0.00 2 22.36 2 4 21.00 2 9 9 9 9 9 9 9 9 9 9

11 2 1603.9 35.178 35.176 2 5.173 5.029 27.830 207.2 2 206.5 2 101.0 0.00 2 21.88 2 4 21.60 2 9 9 9 9 9 9 9 9 9 9

10 2 1702.3 35.148 35.151 2 4.885 4.734 27.841 211.2 2 210.7 2 99.0 0.00 2 21.78 2 4 22.70 2 9 9 9 9 9 9 9 9 9 9

9 2 1901.3 35.082 35.082 2 4.260 4.098 27.858 218.6 2 218.9 2 95.8 0.00 2 21.68 2 4 25.30 2 9 9 9 9 780.1 396.4 2 2190.9 2 7.7107 2 2341 2 2332 9 9

8 2 2100.3 35.057 35.057 2 3.938 3.761 27.874 224.4 2 225.0 2 92.4 0.00 2 21.59 2 4 27.60 2 0.03 2 0.01 2 0.00 2 9 9 9 9 9 9 9

7 2 2300.8 35.025 35.025 2 3.616 3.425 27.883 229.5 2 229.2 2 90.9 0.00 2 21.49 2 4 30.20 2 9 9 9 9 9 9 9 9 9 9

6 2 2499.0 34.994 34.995 2 3.317 3.111 27.889 232.5 2 231.3 2 91.3 0.00 2 21.68 2 4 32.90 2 9 9 9 9 767.2 371.7 2 2195.1 2 7.7187 2 2344 2 2339 9 9

5 2 2700.7 34.969 34.969 2 3.081 2.859 27.893 232.8 2 233.2 2 91.5 0.00 2 21.78 2 4 35.70 2 9 9 9 9 9 9 9 9 9 9

4 2 2885.2 34.950 34.951 2 2.897 2.660 27.896 234.5 2 234.0 2 92.4 0.00 2 21.98 2 4 38.30 2 0.00 2 -0.01 2 0.00 2 9 9 9 9 9 9 9

3 2 3093.5 34.934 34.935 2 2.743 2.488 27.900 234.2 2 234.3 2 93.6 0.00 2 22.17 2 4 41.00 2 9 9 9 9 772.6 363.4 3 2205.7 2 7.7183 2 9 2350 9 9

2 2 3334.7 34.922 34.922 2 2.618 2.340 27.903 232.5 2 232.4 2 96.7 0.00 2 22.47 2 4 43.90 2 9 9 9 9 9 9 9 9 9 9

1 2 3595.2 34.907 34.908 2 2.469 2.167 27.907 234.9 2 236.4 2 94.2 0.00 6 22.56 6 4 45.70 6 0.00 2 0.01 2 0.00 2 9 776.6 360.1 2 2212.5 2 7.7222 2 2363 2 2359 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

82
A5R

NOAA Ship Ronald H. Brown

STATION 14 DATE 1/26/1998 LATITUDE 26.167° N

LONGITUDE 18.817° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

32 2 3.0 36.843 36.844 2 21.040 21.039 25.888 225.3 2 220.3 2 -2.0 0.14 2 0.59 2 0.09 2 0.90 2 2.16 6 1.22 6 0.17 6 9 353.9 368.9 2 2100.1 6 8.0189 2 2417 2 2413 64.4 2 5.2 2

31 2 29.5 36.840 36.841 2 21.029 21.023 25.892 217.4 2 218.7 2 -0.4 0.13 2 0.49 2 0.09 2 0.80 2 2.15 2 1.22 2 0.16 2 9 354.4 369.3 2 2099.5 2 8.0204 2 2412 2 2414 61.4 2 4.8 2

30 2 54.5 36.846 36.848 2 21.030 21.019 25.899 216.4 2 220.9 2 -2.6 0.10 2 0.59 2 0.11 2 0.80 2 2.20 2 1.23 2 0.17 2 9 354.0 368.8 2 2102.0 2 8.0196 2 9 2416 60.6 2 4.8 2

29 2 89.3 36.770 36.730 2 20.630 20.613 25.954 186.9 2 200.0 2 20.1 0.07 2 3.61 2 0.27 2 1.30 2 2.19 2 1.26 2 0.17 2 9 403.7 414.1 2 2120.8 3 4 2410 2 58.5 2 7.8 2

28 2 146.0 36.526 36.532 2 17.974 17.949 26.461 161.5 2 159.3 2 72.2 0.01 2 8.59 2 0.50 2 2.60 2 2.22 2 1.21 2 0.10 2 9 488.6 450.4 2 2149.4 2 4 2391 2 53.6 2 11.5 2

27 2 145.0 36.526 36.520 2 18.022 17.997 26.450 161.0 2 160.2 2 71.1 0.01 2 8.68 2 0.51 2 2.70 2 2.24 2 1.23 2 0.08 2 9 490.9 453.5 2 2150.0 2 4 9 48.3 2 12.0 2

26 2 179.5 36.419 36.413 2 17.192 17.162 26.573 157.2 2 163.5 2 71.6 0.01 2 9.46 2 0.55 2 2.90 2 2.26 2 1.22 2 0.06 2 9 508.7 454.3 2 2149.3 2 4 2382 2 46.9 2 12.2 2

25 2 209.1 36.189 36.197 2 16.079 16.045 26.661 136.6 2 138.5 2 102.1 0.01 2 13.76 2 0.80 2 4.50 2 2.05 2 1.13 2 0.03 2 9 576.7 492.6 2 2167.1 3 4 2368 2 47.1 2 16.3 2

24 2 247.7 36.048 36.050 2 15.350 15.312 26.721 117.4 2 120.4 2 123.9 0.01 2 16.79 2 0.98 2 5.50 2 1.95 2 1.06 2 0.02 2 9 649.4 538.7 2 2179.2 3 4 9 9 19.6 2

23 2 299.5 36.051 36.054 2 14.907 14.861 26.825 153.9 2 149.8 2 96.7 0.01 2 14.05 2 0.81 2 4.60 2 2.15 2 1.14 2 0.02 2 9 587.7 478.1 2 2162.7 2 4 2367 2 47.3 2 16.6 2

22 2 350.5 35.986 35.985 2 14.316 14.264 26.905 170.4 2 179.8 2 69.8 0.01 2 12.49 2 0.73 2 4.40 2 2.28 2 1.19 2 0.02 2 9 559.1 443.7 2 2151.8 2 7.8399 2 9 2357 9 9

21 2 400.5 35.877 35.878 2 13.609 13.551 26.972 180.3 2 179.5 2 73.9 0.01 2 12.98 2 0.77 2 4.70 2 2.24 2 1.14 2 0.03 2 9 569.5 438.7 2 2149.1 2 7.8302 2 9 2348 46.3 2 15.6 2

20 2 499.0 35.672 35.664 2 12.307 12.240 27.079 143.5 2 148.2 2 112.5 0.00 2 18.94 2 1.21 2 7.60 2 1.69 2 0.88 2 0.02 2 9 699.4 510.8 2 2174.7 2 7.7504 2 5 2336 9 9

19 2 598.5 35.496 35.503 2 10.937 10.862 27.201 145.0 2 144.2 2 124.5 0.00 2 21.38 2 1.32 2 10.00 2 1.21 2 0.59 2 0.01 2 9 766.1 528.6 2 2183.4 2 7.7177 2 2333 2 2330 44.7 2 23.7 2

18 2 698.8 35.371 35.374 2 9.858 9.775 27.294 127.0 2 128.6 2 146.8 0.00 2 24.90 2 1.55 2 13.30 2 0.67 2 0.34 2 0.00 2 9 870.0 574.5 2 2201.3 2 7.6704 2 2334 2 2328 9 9

17 2 799.9 35.267 35.264 2 8.824 8.735 27.384 124.8 2 122.6 2 159.4 0.00 2 27.34 2 1.73 2 16.30 2 0.33 2 0.16 2 0.00 2 9 950.8 601.6 6 2211.4 2 7.6355 2 2327 2 2324 42.2 2 29.2 2

16 2 899.4 35.252 35.241 2 8.340 8.242 27.450 129.3 2 132.3 2 152.9 0.00 2 27.25 2 1.74 2 17.60 2 0.23 2 0.11 2 0.00 2 9 928.4 574.2 2 2209.9 2 7.6433 2 2330 2 2326 9 9

15 2 1001.8 35.259 35.259 2 7.733 7.628 27.549 147.0 2 148.7 2 140.5 0.00 2 25.78 2 1.67 2 18.40 2 0.17 2 0.08 2 0.00 2 9 882.4 529.9 2 2209.5 6 7.6591 2 2336 2 2332 42.1 2 27.7 2

14 2 1098.5 35.253 35.250 2 7.227 7.115 27.618 156.9 2 157.4 2 135.2 0.00 2 25.49 2 1.65 2 19.20 2 0.12 2 0.06 2 0.00 2 9 868.0 509.1 2 2204.8 2 9 2335 2 9 9

13 2 1199.0 35.303 35.302 2 7.015 6.894 27.689 171.1 2 172.0 2 122.0 0.00 2 23.83 2 1.55 2 18.90 2 0.14 2 0.07 2 0.00 2 9 820.6 475.7 2 2200.8 2 7.6916 2 9 2336 42.1 2 25.7 2

12 2 1292.3 35.282 35.281 2 6.555 6.428 27.737 180.4 2 181.1 2 116.1 0.00 2 23.34 2 1.52 2 19.60 2 0.09 2 0.05 2 0.00 2 9 9 2201.4 2 7.6967 2 2342 2 2339 9 9

11 2 1498.9 35.198 35.200 2 5.485 5.348 27.807 200.3 2 199.8 2 105.3 0.00 2 22.56 2 1.49 2 21.70 2 0.05 2 0.03 2 0.00 2 9 787.0 424.3 2 2192.7 2 7.7049 2 2336 2 2333 42.1 2 24.6 2

10 2 1699.7 35.121 35.122 2 4.735 4.587 27.835 212.1 2 210.7 2 100.2 0.00 2 22.27 2 1.49 2 24.00 2 0.02 2 0.02 2 0.00 2 9 9 2191.4 2 7.7078 2 2336 2 2333 9 9

9 2 1900.6 35.095 35.095 2 4.390 4.226 27.855 218.4 2 217.9 2 95.8 0.00 2 21.68 2 1.48 2 25.50 2 9 9 9 9 777.9 397.8 2 2191.2 2 7.7132 2 9 2335 41.5 2 23.6 2

8 2 2101.1 35.059 35.059 2 3.986 3.808 27.871 224.3 2 224.4 2 92.6 0.00 2 21.59 2 1.47 2 27.80 2 9 9 9 9 9 2188.9 2 7.7169 2 2338 2 2334 9 9

7 2 2283.6 35.029 35.031 2 3.673 3.482 27.880 228.8 2 227.9 2 91.7 0.00 2 21.49 2 1.47 2 30.10 2 9 9 9 9 773.0 381.6 2 2193.2 2 9 2340 2 42.7 2 23.4 2

6 2 2497.8 34.990 34.989 2 3.289 3.084 27.888 231.6 2 231.8 2 91.1 0.00 2 21.59 2 1.48 2 33.50 2 0.00 6 0.00 2 0.00 6 9 9 2196.8 2 7.7197 2 2347 2 2343 41.6 2 23.5 2

5 2 2697.8 34.972 34.972 2 3.109 2.887 27.893 233.8 2 233.3 2 91.2 0.00 2 21.88 2 1.49 2 35.50 2 9 9 9 9 771.6 370.1 2 2200.5 2 7.7192 2 2346 2 2347 42.2 2 23.5 2

4 2 2894.7 34.951 34.951 2 2.906 2.668 27.896 234.9 2 234.1 2 92.2 0.00 2 21.88 2 1.51 2 38.30 2 0.01 2 0.01 2 0.00 2 9 9 2201.8 2 7.7182 2 2349 2 2347 42.1 2 23.8 2

3 2 3099.6 34.935 34.935 2 2.748 2.492 27.900 234.3 2 234.9 2 92.9 0.00 2 22.08 2 1.52 2 41.00 2 9 9 9 9 780.1 367.3 2 2205.8 2 7.7195 2 2357 2 2352 41.9 2 24.0 2

2 2 3285.2 34.923 34.924 2 2.630 2.357 27.902 233.6 2 233.4 2 95.6 0.00 2 22.37 2 1.53 2 43.90 2 0.00 2 0.00 2 0.00 2 9 9 2210.0 2 7.7202 2 2359 2 2357 41.9 2 24.4 2

1 2 3532.0 34.905 34.906 2 2.446 2.151 27.906 236.3 2 237.9 2 92.8 0.00 6 22.76 6 1.54 6 47.50 6 0.00 2 -0.01 2 0.00 2 9 771.8 357.2 2 2212.2 2 7.7234 2 2362 2 2361 41.8 2 24.7 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

83
A5R

NOAA Ship Ronald H. Brown

STATION 15 DATE 1/26/1998 LATITUDE 25.983° N

LONGITUDE 19.365° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 36.694 36.691 2 20.710 20.709 25.865 232.8 2 233.7 2 -13.9 0.03 2 0.10 2 0.09 2 0.70 3 9 9 9 9 344.1 354.0 2 2086.9 6 8.0294 2 2403 2 2405 9 9

35 2 23.8 36.692 36.701 2 20.702 20.697 25.868 232.5 2 233.2 2 -13.4 0.03 2 0.10 2 0.08 2 1.10 3 9 9 9 9 9 9 9 9 9 9

34 2 49.0 37.058 37.061 2 21.438 21.428 25.947 220.7 2 222.5 2 -6.1 0.00 2 0.00 2 0.02 2 1.30 3 9 9 9 9 339.3 359.3 2 2096.6 2 8.0369 2 9 2424 9 9

33 2 70.5 37.077 37.078 2 21.482 21.468 25.951 220.1 2 218.7 2 -2.4 0.00 2 0.00 2 0.03 2 2.20 3 9 9 9 9 9 9 9 9 9 9

32 2 99.2 37.012 37.010 2 21.232 21.213 25.974 218.8 2 215.0 2 2.4 0.03 2 0.78 2 0.07 2 2.10 3 9 9 9 9 9 2104.1 2 8.0228 2 2420 2 2422 9 9

31 2 124.3 36.702 36.708 2 18.943 18.921 26.350 182.7 2 191.2 2 35.8 0.02 2 4.19 2 0.25 2 2.40 3 9 9 9 9 425.4 407.7 2 2127.1 2 7.9528 2 2402 2 2399 9 9

30 2 169.4 36.575 36.561 2 17.884 17.855 26.523 189.6 2 186.4 2 45.4 0.01 2 5.75 2 0.33 2 2.70 3 9 9 9 9 9 2130.5 2 7.9335 2 2393 2 2390 9 9

29 3 197.9 36.440 36.431 2 17.148 17.115 26.601 176.6 2 175.7 2 59.6 0.01 2 8.00 2 0.45 2 3.40 3 9 9 9 9 9 9 9 9 9 9

28 2 222.1 36.345 36.334 2 16.585 16.549 26.664 174.1 2 175.7 2 62.3 0.01 2 8.78 2 0.51 2 3.50 3 9 9 9 9 488.2 425.4 2 2139.7 2 7.8937 2 9 2375 9 9

27 2 274.3 36.179 36.175 2 15.542 15.499 26.780 173.2 2 174.5 2 68.7 0.00 2 10.34 2 0.60 2 4.10 3 9 9 9 9 519.8 433.6 2 2143.1 2 7.8718 2 2375 2 2366 9 9

26 2 322.6 36.053 36.051 2 14.718 14.669 26.868 184.3 2 183.7 2 63.7 0.00 2 10.54 2 0.62 2 4.40 3 9 9 9 9 9 9 9 9 9 9

25 2 368.9 35.950 35.946 2 14.064 14.010 26.932 186.7 2 185.0 2 65.9 0.00 2 11.51 2 0.68 2 4.70 3 9 9 9 9 550.8 431.9 2 2143.5 2 7.8527 2 9 2355 9 9

24 2 424.2 35.802 35.802 2 13.073 13.013 27.024 181.8 2 180.0 2 76.3 0.00 2 13.66 2 0.81 2 5.70 3 9 9 9 9 9 9 9 9 9 9

23 2 473.7 35.704 35.705 2 12.418 12.354 27.080 174.6 2 169.3 2 90.7 0.00 2 16.01 2 0.96 2 6.90 3 9 9 9 9 632.6 462.9 2 2162.4 2 7.7897 2 2347 2 2342 9 9

22 2 525.0 35.630 35.632 2 11.902 11.832 27.124 167.7 2 164.7 2 98.3 0.00 2 17.47 2 1.06 2 4 9 9 9 9 9 9 9 9 9 9

21 2 586.0 35.512 35.519 2 10.980 10.906 27.205 155.4 2 151.7 2 116.8 0.00 2 20.40 2 1.25 2 10.20 3 9 9 9 9 735.1 506.6 2 2179.7 2 7.7313 2 9 2332 9 9

20 2 694.4 35.351 35.358 2 9.749 9.667 27.297 125.0 2 125.3 2 150.8 0.00 2 25.48 2 1.60 2 14.40 2 9 9 9 9 9 9 9 9 9 9

19 2 800.0 35.244 35.244 2 8.501 8.414 27.416 125.9 2 126.3 2 157.8 0.00 2 27.44 2 1.77 2 17.80 2 9 9 9 9 949.2 591.4 2 2209.7 2 7.6399 2 2329 2 2324 9 9

18 2 903.6 35.181 35.182 2 7.829 7.734 27.470 128.8 2 130.0 2 158.6 0.00 2 28.02 2 1.83 2 19.60 2 9 9 9 9 9 9 9 9 9 9

17 2 999.7 35.182 35.182 2 7.393 7.291 27.536 141.7 2 141.0 2 150.6 0.00 2 27.34 2 1.79 2 20.40 2 9 9 9 9 938.2 555.9 2 2209.1 6 7.6422 2 2336 3 2324 9 9

16 2 1097.8 35.179 35.174 2 6.912 6.803 27.602 153.9 2 153.8 2 141.1 0.00 2 26.66 2 1.75 2 20.40 2 9 9 9 9 9 9 9 9 9 9

15 2 1197.1 35.241 35.235 2 6.767 6.648 27.673 167.2 2 168.4 2 127.4 0.00 2 24.70 2 1.64 2 19.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1299.1 35.252 35.254 2 6.446 6.320 27.727 179.8 2 179.4 2 118.6 0.00 2 23.43 2 1.57 2 19.80 2 9 9 9 9 9 9 9 9 9 9

13 2 1400.2 35.252 35.252 2 6.117 5.983 27.771 190.9 2 189.4 2 111.0 0.00 2 22.55 2 1.52 2 20.30 2 9 9 9 9 9 9 9 9 9 9

12 2 1499.4 35.230 35.229 2 5.793 5.652 27.796 197.9 2 194.1 2 108.7 0.00 2 22.26 2 1.50 2 20.80 2 9 9 9 9 784.0 427.3 2 2193.7 2 7.7061 2 9 2335 9 9

11 2 1697.5 35.167 35.166 2 4.984 4.833 27.844 212.7 2 212.2 2 96.7 0.00 2 21.48 2 1.47 2 23.40 2 9 9 9 9 9 9 9 9 9 9

10 2 1901.2 35.107 35.107 2 4.376 4.212 27.866 222.0 2 221.4 2 92.4 0.00 2 21.29 2 1.46 2 25.70 2 9 9 9 9 9 2189.7 2 7.7186 2 2339 2 2336 9 9

9 2 2099.2 35.054 35.054 2 3.888 3.712 27.876 226.8 2 227.7 2 90.0 0.00 2 21.38 2 1.48 2 27.90 2 9 9 9 9 9 9 9 9 9 9

8 2 2300.9 35.016 35.016 2 3.565 3.374 27.880 232.8 2 168.5 4 152.0 0.00 2 21.29 2 1.47 2 29.50 2 9 9 9 9 9 9 9 9 9 9

7 2 2502.2 34.987 34.988 2 3.270 3.065 27.888 234.7 2 233.8 2 89.2 0.00 2 21.39 2 1.49 2 32.90 2 9 9 9 9 763.6 368.0 2 2194.3 2 7.7197 2 5 2340 9 9

6 2 2657.6 34.971 34.972 2 3.104 2.886 27.892 236.8 2 235.8 2 88.7 0.00 2 21.39 2 1.50 2 34.60 2 9 9 9 9 9 9 9 9 9 9

5 2 2898.4 34.950 34.950 2 2.893 2.655 27.897 237.8 2 237.0 2 89.5 0.00 2 21.68 2 1.52 2 37.50 2 9 9 9 9 9 9 9 9 9 9

4 2 3097.9 34.933 34.934 2 2.726 2.471 27.900 235.4 2 234.7 2 93.3 0.00 2 21.97 2 1.54 2 41.40 2 9 9 9 9 768.4 360.2 2 2206.5 2 7.7187 2 2358 2 2353 9 9

3 2 3299.0 34.923 34.925 2 2.632 2.358 27.903 235.1 2 235.5 2 93.5 0.00 2 22.17 2 1.55 2 42.80 2 9 9 9 9 9 9 9 9 9 9

2 2 3499.0 34.914 34.916 2 2.548 2.254 27.905 234.6 2 235.0 2 94.9 0.00 2 22.36 2 1.57 2 44.30 2 9 9 9 9 9 2212.1 2 7.7212 2 9 2360 9 9

1 2 3764.3 34.900 34.900 2 2.414 2.095 27.909 238.5 2 238.4 2 92.8 0.00 6 22.46 6 1.58 6 46.30 6 9 9 9 9 767.4 353.5 2 2213.9 2 7.7234 2 2366 2 2362 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

84
A5R

NOAA Ship Ronald H. Brown

STATION 16 DATE 1/26/1998 LATITUDE 25.800° N

LONGITUDE 19.899° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.5 36.548 36.552 2 20.578 20.577 25.790 239.2 2 243.5 2 -23.0 0.07 2 0.20 2 0.13 2 4 2.17 2 1.25 2 0.19 2 9 353.5 361.8 2 2083.4 6 8.0279 6 2402 2 2399 9 9

35 2 25.2 36.847 36.856 2 21.003 20.998 25.904 233.3 2 223.4 2 -5.0 0.04 2 0.10 2 0.06 2 4 9 9 9 9 9 9 9 9 9 9

34 2 50.9 36.889 36.896 2 21.089 21.079 25.915 224.1 2 221.6 2 -3.6 0.06 2 0.00 2 0.06 2 4 2.06 2 1.22 2 0.17 2 9 9 9 9 9 9 9

33 2 75.2 36.899 36.900 2 21.104 21.089 25.921 222.6 2 220.2 2 -2.2 0.10 2 0.20 2 0.08 2 4 9 9 9 9 9 9 9 9 9 9

32 2 101.6 36.827 36.777 2 20.066 20.047 26.150 218.0 2 201.3 2 21.0 0.10 2 3.22 2 0.21 2 4 2.15 2 1.27 2 0.17 2 9 9 9 9 9 9 9

31 2 148.1 36.649 36.649 2 18.199 18.173 26.500 202.8 2 199.5 2 30.8 0.02 2 3.61 2 0.19 2 4 9 9 9 9 9 9 9 9 9 9

30 2 198.8 36.456 36.463 2 17.120 17.087 26.620 188.5 2 189.3 2 46.1 0.01 2 6.34 2 0.35 2 4 2.29 6 1.30 6 0.05 6 9 9 9 9 9 9 9

29 2 248.5 36.235 36.236 2 15.833 15.794 26.756 197.2 2 197.6 2 44.1 0.01 2 7.42 2 0.42 2 4 9 9 9 9 9 9 9 9 9 9

28 2 297.7 36.146 36.145 2 15.306 15.260 26.809 197.3 2 197.9 2 46.5 0.01 2 8.30 2 0.48 2 4 2.38 2 1.30 2 0.03 2 9 9 9 9 9 9 9

27 2 348.4 36.006 36.005 2 14.414 14.362 26.900 194.0 2 193.5 2 55.6 0.01 2 10.15 2 0.59 2 4 9 9 9 9 9 9 9 9 9 9

26 2 399.3 35.877 35.859 2 13.572 13.515 26.980 191.0 2 186.9 2 66.7 0.00 2 12.49 2 0.74 2 4 2.24 2 1.18 2 0.00 2 9 9 9 9 9 9 9

25 2 447.0 35.729 35.727 2 12.569 12.508 27.069 178.0 2 173.2 2 86.0 0.00 2 15.33 2 0.92 2 4 9 9 9 9 9 9 9 9 9 9

24 2 499.6 35.653 35.644 2 12.030 11.963 27.117 174.4 2 170.4 2 91.9 0.00 2 16.79 2 1.01 2 4 1.86 2 0.91 2 0.00 2 9 9 9 9 9 9 9

23 2 599.5 35.455 35.453 2 10.546 10.472 27.238 142.2 2 140.0 2 131.1 0.00 2 22.17 2 1.38 2 4 0.94 2 0.46 2 0.01 2 9 9 9 9 9 9 9

22 2 699.6 35.300 35.298 2 9.291 9.211 27.332 120.1 2 121.1 2 157.9 0.00 2 26.66 2 1.68 2 4 0.41 2 0.18 3 0.00 2 9 9 9 9 9 9 9

21 2 799.4 35.184 35.181 2 8.220 8.134 27.411 117.8 2 120.0 2 166.0 0.00 2 28.71 2 1.86 2 4 0.21 2 0.09 2 0.00 2 9 9 9 9 9 9 9

20 2 898.4 35.155 35.153 2 7.709 7.616 27.467 125.4 2 127.2 2 162.3 0.00 2 28.52 2 1.86 2 4 9 9 9 9 9 9 9 9 9 9

19 2 999.5 35.173 35.170 2 7.277 7.176 27.545 140.0 2 143.5 2 148.9 0.01 2 27.25 2 1.78 2 4 0.14 6 0.05 2 0.00 6 9 9 9 9 9 9 9

18 2 1151.8 35.285 35.284 2 7.151 7.034 27.655 166.2 2 167.0 2 126.1 0.01 2 23.93 2 1.59 2 4 9 9 9 9 9 9 9 9 9 9

17 2 1300.5 35.240 35.237 2 6.358 6.232 27.728 182.0 2 9 0.01 2 23.34 2 1.56 2 4 0.11 2 0.03 2 0.00 2 9 9 9 9 9 9 9

16 2 1444.8 35.223 35.219 2 5.878 5.742 27.779 196.4 2 194.2 2 108.0 0.00 2 22.36 2 1.51 2 4 9 9 9 9 9 9 9 9 9 9

15 2 1598.9 35.189 35.187 2 5.270 5.125 27.827 208.7 2 208.2 2 98.5 0.00 2 21.97 2 1.45 2 4 0.09 2 0.02 3 0.02 4 9 9 9 9 9 9 9

14 3 1750.0 35.140 35.139 2 4.755 4.601 27.849 215.8 2 216.6 2 94.1 0.00 2 21.58 2 1.44 2 4 9 9 9 9 9 9 9 9 9 9

13 2 1902.1 35.082 35.083 2 4.233 4.071 27.861 220.9 2 223.1 2 91.8 0.00 2 21.59 2 1.46 2 4 9 9 9 9 9 9 9 9 9 9

12 2 2048.0 35.057 35.056 2 3.966 3.794 27.870 226.4 2 227.3 2 89.8 0.00 2 21.49 2 1.45 2 4 9 9 9 9 9 9 9 9 9 9

11 2 2197.3 35.029 35.028 2 3.686 3.504 27.877 229.2 2 231.7 2 87.7 0.00 2 21.49 2 1.46 2 4 0.03 2 0.01 2 0.00 2 9 9 9 9 9 9 9

10 2 2349.0 35.012 35.011 2 3.517 3.323 27.882 232.0 2 233.5 2 87.4 0.00 2 21.39 2 1.46 2 4 9 9 9 9 9 9 9 9 9 9

9 2 2497.7 34.993 34.993 2 3.334 3.128 27.887 234.5 2 235.8 2 86.7 0.00 2 21.49 2 1.46 2 4 9 9 9 9 9 9 9 9 9 9

8 2 2651.4 34.979 34.978 2 3.199 2.980 27.890 235.9 2 237.0 2 86.7 0.00 2 21.59 2 1.50 2 4 0.02 2 0.01 2 0.00 2 9 9 9 9 9 9 9

7 3 2793.2 34.969 34.968 2 3.075 2.844 27.895 238.8 2 239.2 2 85.7 0.00 2 21.39 2 1.48 2 4 9 9 9 9 9 9 9 9 9 9

6 2 2998.4 34.945 34.944 2 2.852 2.605 27.898 237.4 2 238.8 2 88.1 0.00 2 21.69 2 1.50 2 4 9 9 9 9 9 9 9 9 9 9

5 2 3199.6 34.931 34.930 2 2.713 2.448 27.901 235.4 2 237.2 2 91.0 0.00 2 21.98 2 1.52 2 4 0.02 2 0.00 3 0.00 2 9 9 9 9 9 9 9

4 2 3400.5 34.917 34.916 2 2.585 2.301 27.904 232.6 2 235.2 2 94.3 0.00 2 22.37 2 1.55 2 4 9 9 9 9 9 9 9 9 9 9

3 2 3602.0 34.908 34.907 2 2.490 2.187 27.907 234.3 2 237.0 2 93.4 0.00 2 22.57 2 1.58 2 4 9 9 9 9 9 9 9 9 9 9

2 2 3800.8 34.901 34.901 2 2.429 2.105 27.909 237.7 2 239.2 2 91.9 0.00 2 22.47 2 1.55 2 4 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

1 2 4064.2 34.894 34.894 2 2.384 2.032 27.911 245.1 2 244.9 2 86.9 0.00 6 22.37 6 1.54 6 4 0.01 2 0.00 3 0.07 4 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

85
A5R

NOAA Ship Ronald H. Brown

STATION 17 DATE 1/24/1998 LATITUDE 25.617° N

LONGITUDE 20.433° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 37.072 37.072 2 21.434 21.433 25.954 224.2 2 225.1 2 -8.7 9 9 9 9 9 9 9 9 333.1 352.7 2 2096.2 6 8.0444 2 2424 6 2429 9 9

35 2 38.5 37.246 37.252 2 21.817 21.809 25.983 221.3 2 221.6 2 -6.9 9 9 9 9 9 9 9 9 9 9 8.0475 2 9 9 9

34 2 80.1 37.263 37.253 2 21.816 21.800 26.001 219.8 2 220.7 2 -5.9 9 9 9 9 9 9 9 9 331.1 355.9 2 2100.3 2 8.0310 2 2433 2 2425 9 9

33 2 128.1 36.786 36.786 2 18.892 18.869 26.428 210.6 2 212.3 2 14.8 9 9 9 9 9 9 9 9 9 9 9 9 9 9

32 2 180.8 36.513 36.513 2 17.549 17.518 26.559 204.7 2 201.0 2 32.4 9 9 9 9 9 9 9 9 425.2 385.1 2 2118.3 2 7.9521 2 2391 2 2387 9 9

31 2 230.4 36.337 36.333 2 16.489 16.451 26.681 197.7 2 202.2 2 36.3 9 9 9 9 9 9 9 9 9 9 9 9 9 9

30 2 279.8 36.113 36.111 2 15.180 15.137 26.810 200.2 2 200.9 2 44.2 0.00 2 8.29 2 0.48 2 2.70 2 9 9 9 9 476.8 391.6 2 9 7.9002 2 2366 2 9 9

29 2 330.9 36.004 36.011 2 14.397 14.348 26.900 194.4 2 194.3 2 54.8 0.00 2 10.15 2 0.59 2 3.30 2 9 9 9 9 9 2125.5 2 9 9 9 9

28 2 378.1 35.890 35.891 2 13.663 13.608 26.969 177.0 2 177.2 2 75.9 0.00 2 13.37 2 0.78 2 4.60 2 9 9 9 9 577.8 445.8 2 2150.0 2 7.8209 2 2350 2 2345 9 9

27 2 431.4 35.778 35.780 2 12.915 12.855 27.038 177.1 2 175.7 2 81.5 0.00 2 14.74 2 0.87 2 5.30 2 9 9 9 9 9 9 9 9 9 9

26 2 481.2 35.690 35.690 2 12.303 12.238 27.092 180.3 2 176.9 2 83.8 0.00 2 15.71 2 0.94 2 6.00 2 9 9 9 9 625.6 456.0 2 2156.6 2 7.7912 2 2338 2 2336 9 9

25 2 580.7 35.521 35.520 2 10.933 10.860 27.221 162.8 2 150.8 2 117.9 0.00 2 19.82 2 1.21 2 8.80 2 9 9 9 9 9 9 9 9 9 9

24 2 680.3 35.371 35.377 2 9.674 9.594 27.324 139.7 2 136.0 2 140.5 0.00 2 24.31 2 1.52 2 12.50 2 9 9 9 9 852.3 557.6 2 2196.6 2 7.6800 2 2333 2 2327 9 9

23 2 780.8 35.227 35.231 2 8.396 8.311 27.418 129.5 2 126.5 2 158.3 0.00 2 27.43 2 1.77 2 16.10 2 9 9 9 9 9 9 9 9 9 9

22 2 881.3 35.201 35.199 2 7.755 7.663 27.496 132.8 2 135.8 2 153.3 0.00 2 27.24 2 1.78 2 17.50 2 9 9 9 9 936.4 564.5 2 2208.5 2 7.6386 2 2327 2 2322 9 9

21 2 980.9 35.193 35.193 2 7.471 7.370 27.533 143.0 2 142.1 2 148.9 0.00 2 26.95 2 1.77 2 18.10 2 9 9 9 9 9 9 9 9 9 9

20 2 1100.4 35.214 35.209 2 6.888 6.779 27.633 159.2 2 162.0 2 133.0 0.00 2 25.48 2 1.68 2 18.50 2 9 9 9 9 871.0 503.2 2 2204.0 6 9 2331 2 9 9

19 2 1219.6 35.217 35.217 2 6.421 6.303 27.700 173.0 2 175.6 2 122.6 0.00 2 24.31 2 1.61 2 18.60 2 9 9 9 9 9 9 9 9 9 9

18 2 1341.0 35.199 35.197 2 5.889 5.764 27.756 184.7 2 190.1 2 112.0 0.00 2 23.33 2 1.56 2 19.50 2 9 9 9 9 9 9 9 9 9 9

17 2 1501.0 35.184 35.184 2 5.417 5.280 27.804 200.4 2 202.2 2 103.4 0.00 2 22.46 2 1.51 2 20.80 2 9 9 9 9 787.4 423.2 2 9 7.7063 2 2338 2 9 9

16 2 1650.0 35.123 35.123 2 4.814 4.670 27.827 209.3 2 210.7 2 99.5 0.00 2 22.16 2 1.51 2 22.60 2 9 9 9 9 9 2191.9 2 9 9 9 9

15 2 1818.7 35.098 35.097 2 4.488 4.331 27.845 216.8 2 217.7 2 95.2 0.00 2 21.68 2 1.49 2 24.10 2 9 9 9 9 9 2188.4 2 7.7118 2 2334 2 2331 9 9

14 2 1979.6 35.067 35.066 2 4.092 3.925 27.865 223.2 2 224.9 2 91.2 0.00 2 21.58 2 1.48 2 26.30 2 9 9 9 9 9 9 9 9 9 9

13 2 2140.8 35.040 35.041 2 3.819 3.640 27.872 227.2 2 228.8 2 89.5 0.00 2 21.58 2 1.47 2 27.70 2 9 9 9 9 9 2188.8 2 7.7185 2 2336 2 2334 9 9

12 2 2300.1 35.020 35.020 2 3.612 3.421 27.879 231.6 2 232.3 2 87.8 0.00 2 21.48 2 1.48 3 28.30 2 9 9 9 9 9 9 9 9 9 9

11 2 2459.6 34.997 34.999 2 3.389 3.186 27.884 234.4 2 234.8 2 87.2 0.00 2 21.39 2 1.43 2 29.70 2 9 9 9 9 762.8 371.2 2 2191.5 2 7.7207 2 2342 2 2338 9 9

10 2 2620.0 34.983 34.983 2 3.228 3.012 27.890 236.7 2 237.5 2 86.0 0.00 2 21.29 2 1.44 2 31.20 2 9 9 9 9 9 9 9 9 9 9

9 2 2777.6 34.964 34.965 2 3.027 2.799 27.895 241.0 2 241.1 2 84.1 0.00 2 21.09 2 1.42 2 32.60 2 9 9 9 9 9 2192.9 2 4 2340 2 9 9

8 2 2940.1 34.950 34.950 2 2.892 2.650 27.898 239.1 2 234.8 3 91.7 0.00 2 21.39 2 1.45 2 35.40 2 9 9 9 9 9 9 9 9 9 9

7 2 3098.8 34.938 34.939 2 2.765 2.509 27.901 240.2 2 234.6 3 93.1 0.00 2 21.48 2 1.46 2 37.20 2 9 9 9 9 759.9 358.0 2 2199.0 2 7.7222 2 2348 2 2346 9 9

6 2 3299.6 34.926 34.926 2 2.644 2.370 27.904 241.0 2 241.6 2 87.3 0.00 2 21.68 2 1.47 2 39.50 2 9 9 9 9 9 9 9 9 9 9

5 2 3499.0 34.915 34.914 2 2.535 2.242 27.907 242.6 2 242.7 2 87.3 0.00 2 21.97 2 1.48 2 42.20 2 9 9 9 9 9 9 9 9 9 9

4 2 3698.5 34.908 34.907 2 2.475 2.161 27.910 245.2 2 244.7 2 86.0 0.00 2 22.07 2 1.50 2 43.50 2 9 9 9 9 756.9 350.9 2 2203.7 2 7.7256 2 2358 2 2353 9 9

3 2 3900.2 34.901 34.899 2 2.414 2.079 27.911 246.2 2 245.9 2 85.5 0.00 2 22.17 2 1.51 2 44.80 2 9 9 9 9 9 9 9 9 9 9

2 2 4098.8 34.895 34.897 2 2.393 2.036 27.912 247.6 2 245.9 2 85.8 0.00 2 22.17 2 1.51 2 45.60 2 9 9 9 9 9 2203.4 2 7.7284 2 2355 2 2354 9 9

1 2 4363.5 34.892 34.892 2 2.388 2.000 27.914 248.6 2 247.9 2 84.2 0.00 2 22.17 2 1.50 2 46.30 2 9 9 9 9 751.4 346.5 2 2203.5 2 9 2354 2 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

86
A5R

NOAA Ship Ronald H. Brown

STATION 18 DATE 1/27/1998 LATITUDE 25.424° N

LONGITUDE 20.949° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.9 37.247 37.250 2 21.912 21.911 25.953 223.6 2 220.4 2 -6.1 0.00 2 0.00 2 0.00 2 0.30 3 9 9 9 9 328.2 354.2 2 2100.1 6 8.0476 2 2441 2 2437 68.1 2 9

35 2 42.8 37.250 37.249 2 21.930 21.921 25.954 216.2 2 220.2 2 -5.9 0.00 2 0.00 2 0.00 2 0.00 3 9 9 9 9 329.3 355.6 2 2103.1 2 8.0482 2 9 2440 68.2 2 9

34 2 89.7 37.243 37.236 2 21.924 21.906 25.956 216.3 2 220.3 2 -5.9 0.01 2 0.10 2 0.01 2 0.00 3 9 9 9 9 331.9 358.2 2 2101.6 2 8.0444 2 2435 2 2436 69.4 2 9

33 2 123.0 36.892 36.896 2 19.788 19.765 26.275 213.6 2 217.7 2 5.6 0.07 2 0.68 2 0.04 2 0.00 3 9 9 9 9 372.8 369.7 2 2109.3 2 8.0026 2 2416 2 2413 60.0 2 9

32 2 138.5 36.848 36.835 2 19.310 19.285 26.368 204.2 2 209.8 2 15.5 0.02 2 1.46 2 0.08 2 0.00 3 9 9 9 9 388.3 377.8 2 2114.2 2 8.0025 2 9 2418 59.9 2 9

31 2 172.9 36.648 36.643 2 18.148 18.118 26.515 194.7 2 202.7 2 27.8 0.01 2 3.41 2 0.18 2 0.00 3 9 9 9 9 413.1 383.3 2 2118.8 2 7.9640 2 2398 2 2396 60.5 2 9

30 2 206.7 36.402 36.405 2 16.786 16.752 26.660 196.7 2 200.8 2 36.2 0.01 2 5.56 2 0.31 2 0.40 3 9 9 9 9 443.7 389.6 2 2119.6 2 7.9391 2 2385 2 2380 60.9 2 9

29 2 235.6 36.359 36.359 2 16.551 16.512 26.684 208.4 2 200.3 2 37.9 0.00 2 5.95 2 0.34 2 0.50 3 9 9 9 9 9 2120.6 2 7.9310 2 9 2376 57.6 2 9

28 2 272.5 36.202 36.190 2 15.650 15.607 26.773 200.8 2 199.3 2 43.4 0.01 2 7.71 2 0.44 2 1.00 3 9 9 9 9 469.9 393.6 2 2125.0 2 7.9080 2 2372 2 2366 9 9

27 2 320.6 36.051 36.056 2 14.723 14.674 26.866 196.6 2 195.5 2 51.9 0.00 2 9.37 2 0.55 2 1.50 3 9 9 9 9 9 2131.8 2 7.8838 2 2369 2 2359 49.9 2 9

26 2 354.9 35.940 35.951 2 13.994 13.942 26.938 195.4 2 191.8 2 59.5 0.00 2 10.73 2 0.64 2 2.00 3 9 9 9 9 530.2 414.5 2 2140.1 2 7.8623 2 2357 2 2356 9 9

25 2 396.9 35.821 35.827 2 13.232 13.176 27.005 190.3 2 183.2 2 72.2 0.01 2 12.88 2 0.78 2 3.10 3 9 9 9 9 9 2157.1 2 7.8271 2 2351 2 2355 47.6 2 9

24 2 438.9 35.729 35.730 2 12.580 12.520 27.067 182.5 2 179.6 2 79.5 0.00 2 14.15 2 0.87 2 3.80 3 9 9 9 9 606.5 447.1 2 2154.1 2 7.8065 2 2349 2 2341 9 9

23 2 500.3 35.609 35.613 2 11.725 11.659 27.140 175.9 2 166.2 2 97.8 0.00 2 16.98 2 1.06 2 5.50 3 9 9 9 9 9 2166.4 2 7.7680 2 2337 2 2335 46.9 2 9

22 2 550.5 35.530 35.527 2 11.142 11.072 27.188 166.7 2 152.4 2 115.1 0.00 2 19.43 2 1.22 2 7.20 2 9 9 9 9 739.6 514.4 2 2176.8 2 7.7317 2 9 2329 9 9

21 2 647.7 35.360 35.361 2 9.792 9.716 27.295 131.3 2 127.7 2 148.1 0.01 2 23.92 2 1.56 2 11.40 2 9 9 9 9 884.4 582.3 2 2200.1 2 7.6621 2 5 2323 44.9 2 9

20 2 745.2 35.246 35.249 2 8.733 8.651 27.380 120.6 2 121.4 2 161.2 0.00 2 25.97 2 1.74 2 14.50 2 9 9 9 9 964.5 608.0 2 2208.4 2 7.6333 2 2327 2 2320 9 9

19 2 844.5 35.177 35.176 2 7.865 7.777 27.459 128.5 2 130.1 2 158.3 0.00 2 28.02 2 1.80 2 16.70 2 9 9 9 9 978.0 593.4 2 2220.3 3 7.6284 2 9 2330 9 9

18 2 941.2 35.167 35.167 2 7.394 7.298 27.522 140.0 2 141.0 2 150.6 0.00 2 27.44 2 1.78 2 17.50 2 9 9 9 9 953.5 565.9 2 2211.4 6 7.6389 2 2328 2 2325 9 9

17 2 1121.1 35.261 35.260 2 7.017 6.904 27.653 163.5 2 165.3 2 128.7 0.00 2 24.70 2 1.60 2 17.20 2 9 9 9 9 860.4 499.8 2 2200.0 2 7.6769 2 2335 2 2329 42.9 2 9

16 2 1229.4 35.262 35.265 2 6.632 6.511 27.709 174.3 2 176.3 2 120.4 0.00 2 23.82 2 1.55 2 17.40 2 9 9 9 9 827.3 471.5 6 2200.7 2 7.6847 2 2337 2 2333 9 9

15 2 1445.3 35.223 35.221 2 5.723 5.589 27.798 196.0 2 198.6 2 104.7 0.00 2 22.46 2 1.47 2 19.30 2 9 9 9 9 790.0 430.7 2 2194.9 2 7.6985 2 2336 2 2333 42.9 2 9

14 2 1647.9 35.146 35.148 2 4.910 4.765 27.835 209.7 2 211.4 2 98.1 0.00 2 21.97 2 1.46 2 21.60 2 9 9 9 9 9 2190.8 2 7.7095 2 2335 2 2333 9 9

13 2 1849.1 35.087 35.086 2 4.342 4.184 27.853 219.2 2 220.5 2 93.5 0.00 2 21.87 2 1.46 2 23.50 2 9 9 9 9 778.0 397.1 2 2189.7 2 7.7116 2 2332 2 2332 9 9

12 2 2051.3 35.043 35.044 2 3.881 3.710 27.868 225.4 2 227.5 2 90.3 0.00 2 21.78 2 1.46 2 25.70 2 9 9 9 9 9 2189.9 2 7.7143 2 2339 2 2334 9 9

11 2 2250.3 35.021 35.021 2 3.614 3.428 27.879 230.8 2 231.8 2 88.3 0.00 2 21.39 2 1.45 2 27.30 2 9 9 9 9 771.1 379.6 2 2190.1 2 7.7158 2 2337 2 2334 42.0 2 9

10 2 2448.3 34.999 34.999 2 3.391 3.189 27.885 234.8 2 234.7 2 87.3 0.00 2 21.39 2 1.46 2 29.20 2 9 9 9 9 9 2190.6 2 7.7209 2 2338 2 2337 9 9

9 2 2647.8 34.978 34.978 2 3.175 2.957 27.891 239.1 2 238.3 2 85.6 0.00 2 21.29 2 1.45 2 31.10 2 9 9 9 9 758.2 364.8 2 2192.5 2 7.7221 2 2346 2 2339 41.6 2 9

8 2 2848.3 34.958 34.959 2 2.966 2.732 27.897 241.5 2 241.6 2 84.2 0.00 2 21.19 2 1.45 2 33.10 2 9 9 9 9 9 2193.7 2 7.7239 2 2343 2 2341 9 9

7 2 3022.4 34.942 34.944 2 2.797 2.548 27.900 242.2 2 241.7 2 85.6 0.00 2 21.48 2 1.47 2 36.20 2 9 9 9 9 757.7 357.5 2 2197.3 2 7.7242 2 2344 2 2345 42.3 2 9

6 2 3272.0 34.927 34.929 2 2.646 2.374 27.904 243.1 2 242.9 2 85.9 0.00 2 21.78 2 1.48 2 39.00 2 9 9 9 9 9 2200.7 2 7.7231 2 2353 2 2348 9 9

5 2 3526.3 34.917 34.917 2 2.550 2.253 27.908 245.8 2 244.9 2 85.0 0.00 2 21.88 2 1.49 2 40.90 2 9 9 9 9 756.7 352.2 2 2204.6 2 7.7269 2 2352 2 2354 41.8 2 9

4 2 3758.1 34.907 34.908 2 2.472 2.152 27.910 247.4 2 246.3 2 84.4 0.00 2 22.07 2 1.50 2 42.90 2 9 9 9 9 9 2202.5 2 7.7235 2 2351 2 2350 42.0 2 9

3 2 4026.8 34.899 34.900 2 2.420 2.071 27.912 248.0 2 245.6 2 85.8 0.00 2 22.27 2 1.52 2 45.30 2 9 9 9 9 754.5 348.6 3 2205.2 2 7.7253 2 2356 2 2354 41.9 2 9

2 2 4244.2 34.894 34.895 2 2.393 2.019 27.913 248.0 2 246.4 2 85.5 0.00 2 22.36 2 1.52 2 46.30 2 9 9 9 9 9 2203.1 2 7.7285 2 2353 2 2353 42.4 2 9

1 2 4527.4 34.891 34.892 2 2.401 1.993 27.916 249.3 2 248.6 2 83.5 0.00 6 22.36 6 1.52 6 46.90 6 9 9 9 9 761.2 351.4 2 2203.8 2 7.7272 2 9 2353 42.4 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

87
A5R

NOAA Ship Ronald H. Brown

STATION 19 DATE 1/27/1998 LATITUDE 25.250° N

LONGITUDE 21.484° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.8 37.301 37.300 2 21.973 21.972 25.977 225.0 2 220.1 2 -6.1 0.00 2 0.10 2 0.01 2 0.60 2 2.10 2 1.43 2 0.18 2 9 323.6 350.1 2 2101.0 6 8.0488 2 2442 2 2439 9 9

35 2 50.5 37.300 37.301 2 21.985 21.975 25.978 217.2 2 219.8 2 -5.8 0.00 2 0.10 2 0.01 2 0.60 2 2.11 2 1.41 2 0.19 2 9 9 9 9 9 9 9

34 2 98.6 37.292 37.277 2 21.986 21.966 25.977 217.5 2 219.9 2 -5.8 0.00 2 0.10 2 0.02 2 0.60 2 2.07 2 1.42 2 0.15 2 9 330.4 357.6 2 2101.6 2 8.0459 2 2434 2 2437 9 9

33 2 150.8 36.788 36.800 2 18.894 18.867 26.431 208.7 2 211.9 2 15.2 0.02 2 1.17 2 0.07 2 0.60 2 9 9 9 9 9 9 9 9 9 9

32 2 198.0 36.610 36.607 2 17.930 17.896 26.542 202.4 2 203.9 2 27.7 0.01 2 3.61 2 0.20 2 1.10 2 2.43 2 1.34 2 0.07 2 9 9 9 9 9 9 9

31 2 239.0 36.384 36.382 2 16.750 16.711 26.657 199.6 2 200.9 2 36.3 0.01 2 5.76 2 0.33 2 1.60 2 9 9 9 9 439.5 385.1 2 2119.7 2 7.9480 2 2385 2 2386 9 9

30 2 278.7 36.229 36.229 2 15.808 15.764 26.759 198.7 2 197.9 2 44.0 0.00 2 7.42 2 0.44 2 2.10 2 9 9 9 9 9 9 9 9 9 9

29 2 319.0 36.116 36.117 2 15.097 15.048 26.834 195.5 2 195.2 2 50.3 0.00 2 8.88 2 0.53 2 2.70 2 2.44 6 1.31 6 0.03 6 9 9 9 9 9 9 9

28 2 338.7 36.067 36.061 2 14.785 14.734 26.866 194.5 2 193.7 2 53.4 0.00 2 9.56 2 0.57 2 2.80 2 9 9 9 9 9 9 9 9 9 9

27 2 399.8 35.922 35.922 2 13.890 13.832 26.948 183.8 2 183.2 2 68.7 0.00 2 12.01 2 0.73 2 3.90 2 9 9 9 9 9 9 9 9 9 9

26 2 446.7 35.769 35.777 2 12.863 12.801 27.042 180.1 2 173.8 2 83.7 0.00 2 14.54 2 0.87 2 5.10 2 2.10 2 1.08 2 0.03 2 9 9 9 9 9 9 9

25 2 499.5 35.641 35.660 2 12.007 11.941 27.112 161.5 2 163.7 2 98.7 0.00 2 17.28 2 1.03 2 6.50 2 9 9 9 9 9 9 9 9 9 9

24 2 560.2 35.551 35.555 2 11.333 11.261 27.171 150.6 2 153.6 2 112.8 0.00 2 19.72 2 1.19 2 8.00 2 1.43 2 0.71 2 0.02 2 9 725.9 508.5 2 2177.9 2 7.7365 2 2331 2 2333 9 9

23 2 623.4 35.415 35.427 2 10.393 10.317 27.235 126.3 2 126.7 2 145.4 0.01 2 24.12 2 1.50 2 11.20 2 9 9 9 9 9 9 9 9 9 9

22 2 698.5 35.350 35.353 2 9.810 9.727 27.286 114.5 2 122.9 2 152.8 0.00 2 25.68 2 1.59 2 12.80 2 0.64 2 0.32 2 0.01 2 9 9 9 9 9 9 9

21 2 776.6 35.266 35.268 2 8.868 8.781 27.375 121.1 2 123.4 2 158.3 0.01 2 27.05 2 1.70 2 15.40 2 9 9 9 9 943.7 597.9 2 2210.5 2 7.6383 2 2330 2 2324 9 9

20 2 845.2 35.220 35.221 2 8.319 8.228 27.426 126.8 2 126.3 2 159.0 0.00 2 27.73 2 1.76 2 17.10 2 0.24 2 0.12 2 0.00 2 9 9 9 9 9 9 9

19 2 923.6 35.161 35.158 2 7.596 7.501 27.488 136.4 2 131.3 2 158.9 0.00 2 28.13 2 1.82 2 18.80 2 9 9 9 9 9 9 9 9 9 9

18 2 999.7 35.158 35.157 2 7.164 7.064 27.549 146.3 2 143.0 2 150.1 0.00 2 27.44 2 1.78 2 19.50 2 0.12 2 0.16 4 0.00 2 9 953.0 559.3 6 2212.8 6 7.6370 2 2331 2 2326 9 9

17 2 1100.6 35.174 35.171 2 6.800 6.692 27.613 158.8 2 156.0 2 139.6 0.00 2 26.37 2 1.71 2 4 9 9 9 9 9 9 9 9 9 9

16 2 1288.1 35.210 35.208 2 6.237 6.114 27.720 183.5 2 180.6 2 119.0 0.00 2 24.02 2 1.58 2 19.90 2 0.07 2 0.04 2 0.00 2 9 9 9 9 9 9 9

15 2 1498.1 35.165 35.164 2 5.334 5.199 27.799 201.8 2 202.1 2 104.1 0.00 2 22.56 2 1.51 2 20.90 2 9 9 9 9 9 9 9 9 9 9

14 2 1691.0 35.105 35.106 2 4.648 4.502 27.832 212.7 2 214.8 2 96.8 0.00 2 21.88 2 1.47 2 22.50 2 0.02 2 0.01 2 0.02 3 9 9 9 9 9 9 9

13 2 1896.9 35.065 35.065 2 4.141 3.981 27.856 223.3 2 224.0 2 91.6 0.00 2 21.49 2 1.45 2 24.30 2 9 9 9 9 774.1 390.4 2 2189.6 2 7.7103 2 2338 2 2332 42.0 2 9

12 2 2098.6 35.028 35.029 2 3.741 3.568 27.869 230.3 2 230.5 2 88.4 0.00 2 21.29 2 1.45 2 26.60 2 9 9 9 9 9 9 9 9 9 9

11 2 2300.4 35.009 35.009 2 3.507 3.318 27.880 232.7 2 233.9 2 87.1 0.00 2 21.29 2 1.45 2 28.80 2 0.01 2 0.00 2 0.00 2 9 9 9 9 9 9 9

10 2 2495.1 34.988 34.988 2 3.279 3.074 27.887 236.4 2 236.9 2 86.1 0.00 2 21.20 2 1.45 2 31.00 2 9 9 9 9 9 9 9 9 9 9

9 2 2698.5 34.969 34.969 2 3.093 2.871 27.892 237.6 2 237.6 2 87.1 0.00 2 21.29 2 1.47 2 33.60 2 9 9 9 9 9 9 9 9 9 9

8 2 2900.3 34.953 34.953 2 2.916 2.677 27.897 239.7 2 240.1 2 86.2 0.00 2 21.29 2 1.47 2 35.80 2 0.01 2 0.00 2 0.00 2 9 764.8 362.6 2 2197.5 2 7.7208 2 4 2344 9 9

7 2 3125.8 34.936 34.936 2 2.756 2.497 27.900 237.4 2 238.7 2 89.1 0.00 2 21.59 2 1.49 2 39.30 2 9 9 9 9 9 9 9 9 9 9

6 2 3372.6 34.924 34.924 2 2.629 2.347 27.905 238.4 2 239.9 2 89.2 0.00 2 21.78 2 1.50 2 41.40 2 9 9 9 9 9 9 9 9 9 9

5 2 3647.9 34.913 34.913 2 2.509 2.200 27.910 244.6 2 246.0 2 84.3 0.00 2 21.78 2 1.50 2 42.30 2 0.01 6 0.01 6 0.00 6 9 9 9 9 9 9 9

4 2 3903.6 34.903 34.904 2 2.440 2.104 27.912 247.5 2 247.6 2 83.5 0.00 2 21.88 2 1.50 2 43.20 2 9 9 9 9 752.9 347.7 2 2200.4 2 7.7288 2 2351 2 2351 9 9

3 2 4153.1 34.898 34.897 2 2.406 2.043 27.914 248.6 2 249.0 2 82.7 0.00 2 21.98 2 1.51 2 43.60 2 9 9 9 9 9 9 9 9 9 9

2 2 4399.6 34.892 34.894 2 2.396 2.004 27.915 248.0 2 247.9 2 84.1 0.00 2 22.17 2 1.52 2 44.40 2 0.00 2 0.01 2 0.00 2 9 9 9 9 9 9 9

1 2 4646.1 34.891 34.891 2 2.411 1.989 27.917 248.7 2 248.8 2 83.3 0.00 6 22.17 6 1.52 6 45.60 6 0.00 2 0.02 4 0.00 2 9 762.2 351.1 2 2201.7 2 7.7264 2 5 2351 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

88
A5R

NOAA Ship Ronald H. Brown

STATION 20 DATE 1/27/1998 LATITUDE 25.057° N

LONGITUDE 22.032° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.0 37.111 37.110 2 22.014 22.013 25.821 219.2 2 220.5 2 -6.3 0.00 2 0.10 2 4 0.70 2 9 9 9 9 341.2 369.7 2 2099.1 6 8.0411 6 2434 2 2430 9 9

35 2 41.8 37.109 37.109 2 22.027 22.019 25.820 216.5 2 221.8 2 -7.7 0.00 2 0.10 2 4 0.70 2 9 9 9 9 9 9 9 9 9 9

34 2 70.8 37.109 37.109 2 22.033 22.019 25.821 217.5 2 216.2 2 -2.1 0.00 2 0.10 2 4 0.80 2 9 9 9 9 9 9 9 9 9 9

33 2 110.3 36.782 36.907 2 20.290 20.269 26.056 214.0 2 194.8 2 26.4 0.06 2 3.71 2 4 1.50 2 9 9 9 9 9 9 9 9 9 9

32 2 139.8 36.758 36.776 2 19.042 19.017 26.368 178.3 2 190.5 2 36.0 0.02 2 4.19 2 4 1.50 2 9 9 9 9 9 9 9 9 9 9

31 2 180.4 36.538 36.500 2 17.688 17.657 26.544 180.7 2 171.8 2 61.0 0.01 2 8.00 2 4 2.60 2 9 9 9 9 9 9 9 9 9 9

30 2 229.0 36.354 36.351 2 16.620 16.582 26.663 181.1 2 184.8 2 53.0 0.01 2 8.00 2 4 2.30 2 9 9 9 9 9 9 9 9 9 9

29 2 279.8 36.184 36.182 2 15.585 15.541 26.775 173.4 2 179.9 2 63.1 0.00 2 10.05 2 4 3.30 2 9 9 9 9 9 9 9 9 9 9

28 2 331.2 36.052 36.049 2 14.754 14.704 26.861 181.3 2 177.7 2 69.6 0.00 2 11.42 2 4 3.80 2 9 9 9 9 9 9 9 9 9 9

27 2 380.1 35.927 35.930 2 14.017 13.961 26.924 163.9 2 160.5 2 90.7 0.00 2 14.35 2 4 4.80 2 9 9 9 9 9 9 9 9 9 9

26 2 409.0 35.824 35.825 2 13.370 13.312 26.980 162.0 2 154.8 2 99.9 0.00 2 16.11 2 4 5.60 2 9 9 9 9 9 9 9 9 9 9

25 2 480.6 35.665 35.666 2 12.268 12.203 27.079 150.1 2 154.0 2 106.9 0.00 2 18.16 2 4 7.00 2 9 9 9 9 9 9 9 9 9 9

24 2 528.5 35.595 35.597 2 11.736 11.667 27.129 147.0 2 151.0 2 113.0 0.00 2 19.33 2 4 7.70 2 9 9 9 9 9 9 9 9 9 9

23 2 582.2 35.492 35.492 2 10.998 10.925 27.186 137.5 2 136.1 2 132.3 0.00 2 22.36 2 4 10.00 2 9 9 9 9 9 9 9 9 9 9

22 2 679.4 35.347 35.349 2 9.718 9.638 27.299 127.1 2 125.4 2 150.9 0.00 2 25.58 2 4 13.60 2 9 9 9 9 9 9 9 9 9 9

21 2 773.5 35.224 35.224 2 8.632 8.547 27.380 118.3 2 121.0 2 162.3 0.00 2 28.22 2 4 16.90 2 9 9 9 9 9 9 9 9 9 9

20 2 875.9 35.128 35.130 2 7.682 7.591 27.448 124.3 2 125.7 2 164.0 0.00 2 29.10 2 4 19.30 2 9 9 9 9 9 9 9 9 9 9

19 2 981.0 35.127 35.130 2 7.161 7.063 27.524 139.7 2 141.2 2 152.0 0.00 2 27.93 2 4 20.00 2 9 9 9 9 9 9 9 9 9 9

18 2 1079.7 35.142 35.142 2 6.788 6.682 27.589 152.2 2 154.2 2 141.6 0.00 2 26.37 2 4 20.30 2 9 9 9 9 9 9 9 9 9 9

17 2 1278.3 35.182 35.182 2 6.210 6.088 27.701 176.7 2 176.5 2 123.3 0.00 2 24.71 2 4 20.30 2 9 9 9 9 9 9 9 9 9 9

16 2 1474.3 35.162 35.163 2 5.432 5.298 27.785 197.5 2 198.1 2 107.4 0.00 2 23.05 2 4 21.30 2 9 9 9 9 9 9 9 9 9 9

15 2 1686.2 35.103 35.108 2 4.675 4.529 27.827 211.4 2 214.5 2 96.8 0.00 2 22.36 2 4 23.00 2 9 9 9 9 9 9 9 9 9 9

14 2 1878.9 35.072 35.072 2 4.207 4.048 27.855 220.9 2 224.4 2 90.7 0.00 2 21.68 2 4 24.80 2 9 9 9 9 9 9 9 9 9 9

13 2 2082.5 35.046 35.047 2 3.883 3.709 27.870 227.6 2 231.0 2 86.8 0.00 2 21.39 2 4 27.00 2 9 9 9 9 9 9 9 9 9 9

12 2 2242.9 35.022 35.023 2 3.625 3.439 27.878 230.6 2 233.2 2 86.8 0.00 2 21.39 2 4 28.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2478.6 34.993 34.994 2 3.331 3.127 27.887 234.4 2 236.8 2 85.7 0.00 2 21.39 2 4 31.30 2 9 9 9 9 9 9 9 9 9 9

10 2 2675.6 34.971 34.971 2 3.110 2.890 27.892 236.5 2 240.4 2 84.1 0.00 2 21.29 2 4 34.00 2 9 9 9 9 9 9 9 9 9 9

9 2 2881.7 34.953 34.954 2 2.916 2.679 27.897 241.9 2 242.8 2 83.5 0.00 2 21.39 2 4 35.70 2 9 9 9 9 9 9 9 9 9 9

8 2 3079.9 34.939 34.939 2 2.760 2.506 27.901 242.1 2 243.3 2 84.4 0.00 2 21.59 2 4 38.50 2 9 9 9 9 9 9 9 9 9 9

7 2 3280.8 34.929 34.929 2 2.656 2.383 27.906 244.0 2 244.2 2 84.6 0.00 2 21.59 2 4 40.10 2 9 9 9 9 9 9 9 9 9 9

6 2 3500.1 34.920 34.919 2 2.565 2.271 27.909 246.0 2 247.1 2 82.6 0.00 2 21.68 2 4 41.70 2 9 9 9 9 9 9 9 9 9 9

5 2 3757.8 34.909 34.909 2 2.482 2.162 27.911 247.0 2 248.5 2 82.1 0.00 2 21.88 2 4 44.00 2 9 9 9 9 9 9 9 9 9 9

4 2 4018.2 34.901 34.900 2 2.422 2.074 27.913 249.0 2 250.4 2 81.0 0.00 2 22.07 2 4 45.70 2 9 9 9 9 9 9 9 9 9 9

3 2 4278.9 34.894 34.894 2 2.388 2.010 27.915 249.6 2 249.5 2 82.5 0.00 2 21.88 3 4 47.20 2 9 9 9 9 9 9 9 9 9 9

2 2 4539.1 34.891 34.892 2 2.395 1.986 27.916 249.2 2 248.1 2 84.1 0.00 2 22.37 2 4 48.20 2 9 9 9 9 9 9 9 9 9 9

1 2 4809.4 34.889 34.889 2 2.421 1.978 27.918 249.5 2 248.8 2 83.4 0.00 6 22.37 6 4 48.00 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

89
A5R

NOAA Ship Ronald H. Brown

STATION 21 DATE 1/28/1998 LATITUDE 24.783° N

LONGITUDE 22.800° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.3 37.218 37.217 2 22.256 22.255 25.834 222.5 2 218.0 2 -4.9 0.00 2 0.00 2 4 0.80 2 2.05 2 1.39 2 0.17 2 9 331.1 362.2 2 2098.6 6 9 2434 2 9 9

35 2 50.2 37.214 37.214 2 22.256 22.246 25.835 216.2 2 218.0 2 -4.9 0.00 2 0.00 2 4 0.70 2 2.05 2 1.45 2 0.17 2 9 330.9 361.9 2 2099.9 2 8.0469 2 2440 2 2436 9 9

34 2 101.5 37.219 37.218 2 22.186 22.166 25.866 215.7 2 217.8 2 -4.4 0.02 2 0.10 2 4 0.70 2 2.06 2 1.42 2 0.16 2 9 333.2 363.6 2 2101.0 2 8.0457 2 2432 2 2436 9 9

33 2 149.3 36.909 36.917 2 19.749 19.721 26.302 202.5 2 202.1 2 21.3 0.02 2 1.95 2 4 0.80 2 9 9 9 9 9 9 9 9 9 9

32 2 201.1 36.608 36.607 2 18.022 17.987 26.517 190.6 2 193.4 2 37.8 0.00 2 4.68 2 4 1.30 2 2.36 2 1.34 2 0.06 2 9 423.1 391.0 2 2123.3 2 7.9574 2 2393 2 2397 9 9

31 2 227.3 36.503 36.495 2 17.410 17.371 26.589 195.5 2 200.4 2 33.7 0.00 2 4.78 2 4 1.40 2 9 9 9 9 9 9 9 9 9 9

30 2 251.8 36.400 36.401 2 16.836 16.794 26.649 196.4 2 199.7 2 37.1 0.00 2 5.66 2 4 1.60 2 9 9 9 9 9 9 9 9 9 9

29 2 278.0 36.295 36.304 2 16.237 16.192 26.711 196.3 2 197.4 2 42.3 0.00 2 6.83 2 4 2.10 2 9 9 9 9 9 9 9 9 9 9

28 2 302.5 36.217 36.225 2 15.779 15.731 26.758 194.8 2 195.9 2 46.1 0.00 2 7.71 2 4 2.10 2 2.41 2 1.32 2 0.00 2 9 472.5 397.9 2 2128.1 2 7.9172 2 2368 2 2375 9 9

27 2 352.2 36.063 36.064 2 14.829 14.775 26.854 193.8 2 192.4 2 54.5 0.00 2 9.56 2 4 2.80 2 9 9 9 9 9 9 9 9 9 9

26 2 399.6 35.930 35.931 2 13.953 13.894 26.942 187.5 2 184.5 2 67.0 0.00 2 11.81 2 4 3.90 2 2.29 2 1.20 2 0.02 2 9 9 9 9 9 9 9

25 2 452.3 35.807 35.813 2 13.144 13.080 27.016 176.7 2 174.3 2 81.7 0.00 2 14.25 2 4 4.90 2 9 9 9 9 9 9 9 9 9 9

24 2 499.5 35.718 35.718 2 12.518 12.450 27.073 175.6 2 157.7 2 101.8 0.00 2 16.30 2 4 6.10 2 1.92 2 0.99 2 0.02 2 9 652.2 479.9 2 2162.1 2 7.7846 2 2346 2 2338 9 9

23 2 600.7 35.522 35.520 2 11.092 11.016 27.193 153.8 2 148.9 2 118.9 0.00 2 20.70 2 4 9.10 2 1.26 2 0.65 2 0.02 2 9 9 9 9 9 9 9

22 2 701.9 35.350 35.355 2 9.713 9.631 27.302 140.1 2 126.8 2 149.5 0.00 2 25.48 2 4 13.50 2 9 9 9 9 9 9 9 9 9 9

21 2 800.1 35.245 35.245 2 8.657 8.569 27.393 121.7 2 124.1 2 159.0 0.00 2 27.34 2 4 15.90 2 0.29 2 0.14 2 0.00 2 9 9 9 9 9 9 9

20 2 901.0 35.192 35.194 2 7.840 7.745 27.477 135.0 2 121.5 2 167.0 0.00 2 27.44 2 4 17.20 2 9 9 9 9 9 9 9 9 9 9

19 2 999.5 35.191 35.191 2 7.342 7.240 27.550 147.5 2 125.9 2 166.0 0.00 2 26.36 2 4 17.70 2 0.13 6 0.08 6 0.00 6 9 908.7 536.8 2 2207.9 6 7.6516 2 2327 2 2325 9 9

18 2 1198.2 35.243 35.242 2 6.704 6.586 27.683 170.0 2 171.1 2 125.1 0.00 2 24.22 2 4 18.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1400.2 35.219 35.219 2 5.922 5.790 27.769 190.0 2 191.6 2 110.3 0.00 2 22.85 2 4 19.10 2 0.07 2 0.04 2 0.00 2 9 9 9 9 9 9 9

16 2 1601.3 35.171 35.171 2 5.200 5.056 27.821 207.5 2 204.5 2 102.8 0.00 2 21.97 2 4 20.70 2 9 9 9 9 9 9 9 9 9 9

15 2 1800.2 35.111 35.113 2 4.545 4.389 27.849 219.2 2 220.2 2 92.2 0.00 2 21.09 3 4 22.70 2 0.03 2 0.00 2 -0.01 2 9 768.9 396.0 2 2187.8 2 7.7130 2 2333 2 2329 9 9

14 2 1999.3 35.053 35.054 2 4.001 3.833 27.863 228.1 2 228.4 2 88.4 0.00 2 21.39 2 4 24.80 2 9 9 9 9 9 9 9 9 9 9

13 2 2195.7 35.023 35.023 2 3.675 3.493 27.874 233.8 2 231.8 2 87.7 0.00 2 21.29 2 4 27.20 2 9 9 9 9 9 9 9 9 9 9

12 2 2399.7 35.001 35.001 2 3.413 3.215 27.884 237.5 2 236.8 2 85.0 0.00 2 21.19 2 4 29.60 2 0.01 2 0.01 2 -0.01 2 9 9 9 9 9 9 9

11 2 2599.7 34.976 34.978 2 3.151 2.938 27.891 240.0 2 236.5 2 87.6 0.00 2 21.19 2 4 32.70 2 9 9 9 9 9 9 9 9 9 9

10 2 2799.0 34.959 34.958 2 2.955 2.726 27.897 241.7 2 241.3 2 84.6 0.00 2 21.39 3 4 35.00 2 9 9 9 9 9 9 9 9 9 9

9 2 3000.2 34.941 34.941 2 2.778 2.532 27.901 243.8 2 243.0 2 84.5 0.00 2 21.49 3 4 36.90 2 0.01 2 0.01 2 0.00 2 9 756.7 356.6 2 2195.7 2 7.7237 2 2346 2 2342 9 9

8 2 3250.7 34.930 34.931 2 2.667 2.397 27.905 247.7 2 247.0 2 81.6 0.00 2 21.29 2 4 37.70 2 9 9 9 9 9 9 9 9 9 9

7 2 3502.1 34.920 34.921 2 2.580 2.285 27.908 247.5 2 236.8 4 92.8 0.00 2 21.49 2 4 39.10 2 0.01 3 0.01 2 -0.01 2 9 9 9 9 9 9 9

6 2 3749.8 34.911 34.910 2 2.490 2.170 27.911 245.0 2 248.9 2 81.7 0.00 2 21.68 2 4 40.80 2 9 9 9 9 9 9 9 9 9 9

5 2 4000.1 34.901 34.902 2 2.429 2.083 27.913 246.5 2 249.5 2 81.8 0.00 2 21.78 2 4 42.80 2 0.00 2 0.00 2 0.00 2 9 751.6 347.6 2 2195.8 2 9 2354 2 9 9

4 2 4250.7 34.895 34.895 2 2.390 2.016 27.915 245.8 2 249.4 2 82.5 0.00 2 21.88 2 4 44.40 2 9 9 9 9 9 9 9 9 9 9

3 2 4498.6 34.892 34.891 2 2.389 1.985 27.916 244.7 2 249.2 2 83.0 0.00 2 22.07 2 4 45.60 2 0.00 2 0.00 2 0.00 2 9 752.0 346.9 6 2198.9 2 7.7265 2 2351 2 2346 9 9

2 2 4752.2 34.889 34.891 2 2.410 1.975 27.917 244.5 2 248.2 2 84.1 0.00 2 22.17 2 4 46.40 2 0.00 2 -0.01 2 0.00 2 9 9 9 9 9 9 9

1 2 4968.8 34.888 34.889 2 2.431 1.968 27.919 244.4 2 249.0 2 83.3 0.00 2 22.17 2 4 46.80 2 0.00 2 0.00 2 0.00 2 9 758.1 350.5 2 2200.5 2 7.7264 2 2345 2 2348 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

90
A5R

NOAA Ship Ronald H. Brown

STATION 22 DATE 1/28/1998 LATITUDE 24.500° N

LONGITUDE 23.484° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.2 37.121 37.120 2 22.034 22.033 25.823 221.8 2 218.6 2 -4.5 0.01 2 0.00 2 4 0.80 2 2.06 2 1.39 2 0.17 2 9 333.9 362.0 2 2096.7 6 8.0433 2 2437 2 2429 65.1 2 6.3 2

35 2 49.2 37.120 37.121 2 22.042 22.032 25.825 215.6 2 218.9 2 -4.8 0.01 2 0.00 2 4 0.70 2 2.09 2 1.39 2 0.16 2 9 333.1 361.4 2 2099.5 2 8.0403 2 2438 2 2430 63.5 2 4.3 2

34 2 99.2 37.120 37.121 2 22.056 22.036 25.826 215.4 2 218.7 2 -4.6 0.01 2 0.00 2 4 0.70 2 2.09 6 1.40 6 0.16 6 9 333.8 362.3 2 2101.0 2 8.0400 2 2428 2 2431 62.9 2 4.3 2

33 2 130.5 37.085 37.105 2 21.886 21.860 25.852 202.8 2 218.1 2 -3.4 0.01 2 0.19 2 4 0.70 2 9 9 9 9 336.7 363.1 2 2100.8 2 8.0366 2 9 2428 63.1 2 4.5 2

32 2 161.5 36.917 36.921 2 19.855 19.825 26.281 192.7 2 205.4 2 17.6 0.03 2 1.95 2 4 1.00 2 9 9 9 9 386.6 384.2 2 2121.3 2 7.9883 2 2414 2 2417 58.1 2 9

31 2 199.9 36.570 36.581 2 18.037 18.002 26.484 175.5 2 182.6 2 48.5 0.01 2 6.24 2 4 2.00 2 2.30 2 1.30 2 0.08 2 9 456.8 421.8 2 2140.1 3 4 9 51.8 2 9.4 2

30 2 249.8 36.407 36.407 2 16.933 16.891 26.631 189.7 2 194.1 2 42.3 0.01 2 6.34 2 4 2.00 2 9 9 9 9 438.3 387.0 2 2128.6 2 7.9331 2 2382 2 2386 50.9 2 9

29 2 302.1 36.207 36.208 2 15.931 15.883 26.716 155.5 2 157.4 2 83.9 0.01 2 11.90 2 4 3.70 2 2.19 2 1.22 2 0.02 2 9 542.0 459.7 2 2156.7 2 4 2377 2 50.5 2 15.5 2

28 2 350.9 36.118 36.118 2 15.232 15.178 26.808 168.8 2 166.1 2 78.7 0.01 2 11.81 2 4 3.70 2 9 9 9 9 541.8 446.4 2 2152.2 2 7.8516 2 2366 2 2363 9 9

27 2 401.2 35.989 35.995 2 14.347 14.287 26.904 172.0 2 175.9 2 73.5 0.00 2 12.00 2 4 4.10 2 2.25 2 1.18 2 0.02 2 9 549.4 436.0 2 2149.1 2 7.8465 2 2367 2 2357 46.7 2 14.9 2

26 2 448.9 35.797 35.795 2 13.302 13.238 26.976 136.7 2 135.3 2 119.9 0.00 2 18.25 2 4 6.30 2 9 9 9 9 691.3 526.3 6 2178.5 3 4 9 9 9

25 2 500.3 35.722 35.725 2 12.650 12.581 27.051 160.1 2 162.7 2 96.1 0.00 2 16.30 2 4 6.10 2 9 9 9 9 649.1 480.4 2 2165.2 2 7.7822 2 2342 2 2340 46.2 2 19.4 2

24 2 548.0 35.597 35.603 2 11.834 11.762 27.113 148.6 2 143.6 2 119.9 0.00 2 19.81 2 4 7.80 2 9 9 9 9 737.2 528.0 2 2180.1 2 7.7352 2 2341 2 2333 9 9

23 2 652.2 35.466 35.468 2 10.639 10.558 27.233 142.9 2 142.5 2 128.1 0.00 2 21.96 2 4 9.90 2 0.93 2 0.48 2 -0.01 2 9 783.5 533.5 2 2186.1 2 7.7067 2 2328 2 2326 43.6 2 9

22 2 750.1 35.349 35.351 2 9.548 9.461 27.331 130.6 2 130.6 2 146.7 0.01 2 25.09 2 4 13.40 2 9 9 9 9 870.1 566.6 2 2197.8 2 7.6675 2 2331 2 2322 9 27.6 2

21 2 848.6 35.248 35.248 2 8.482 8.389 27.424 130.4 2 130.2 2 154.1 0.01 2 27.04 2 4 16.70 2 0.22 2 0.10 2 0.00 2 9 931.6 579.7 2 2205.8 2 7.6442 2 5 2320 42.7 2 9

20 2 951.4 35.204 35.204 2 7.701 7.602 27.508 141.3 2 140.4 2 149.1 0.00 2 26.85 2 4 18.30 2 9 9 9 9 926.2 556.5 2 2207.5 6 7.6457 2 9 2322 9 9

19 2 1146.9 35.226 35.225 2 6.995 6.880 27.629 166.3 2 163.9 2 130.3 0.00 2 25.09 2 4 18.70 2 0.11 2 0.05 2 0.00 2 9 862.1 500.2 2 2199.5 2 7.6734 2 5 2325 42.0 2 28.2 2

18 2 1348.6 35.239 35.239 2 6.256 6.126 27.742 184.6 2 185.6 2 113.8 0.00 2 23.24 2 4 19.40 2 9 9 9 9 814.1 455.5 2 2194.5 2 9 2335 2 9 9

17 2 1548.8 35.180 35.181 2 5.351 5.210 27.810 205.8 2 204.8 2 101.3 0.00 2 22.26 2 4 20.70 2 0.03 6 0.01 6 0.00 6 9 791.5 423.9 2 2188.8 2 7.7068 2 9 2328 41.6 2 25.0 2

16 2 1750.7 35.121 35.121 2 4.688 4.535 27.842 218.2 2 217.9 2 93.4 0.00 2 21.48 2 4 21.90 2 9 9 9 9 9 2185.8 2 7.7124 2 2340 3 2327 9 9

15 2 2050.0 35.044 35.045 2 3.909 3.738 27.866 229.2 2 229.9 2 87.7 0.00 2 21.29 2 4 25.10 2 0.01 2 -0.01 2 0.00 2 9 765.8 382.4 2 2185.2 2 7.7208 2 2335 2 2330 41.6 2 24.0 2

14 2 2150.2 35.035 35.035 2 3.773 3.594 27.873 232.8 2 233.3 2 85.4 0.00 2 21.09 2 4 25.80 2 9 9 9 9 9 2184.6 2 7.7189 2 2338 2 2328 9 9

13 2 2349.7 35.011 35.011 2 3.524 3.329 27.881 237.0 2 236.5 2 84.4 0.00 2 20.99 2 4 27.60 2 0.01 2 -0.01 2 0.00 2 9 762.3 373.5 2 2185.4 2 9 2333 2 42.0 2 9

12 2 2542.0 34.991 34.992 2 3.305 3.095 27.889 243.0 2 241.6 2 81.2 0.00 2 20.80 2 4 29.20 2 9 9 9 9 9 2185.7 2 7.7251 2 2335 2 2332 41.5 2 9

11 2 2750.4 34.969 34.969 2 3.052 2.826 27.896 244.5 2 246.0 2 79.0 0.00 2 20.70 2 4 31.40 2 0.00 2 0.00 2 0.00 2 9 747.1 357.1 2 2186.5 2 7.7236 2 2342 2 2332 41.4 2 9

10 2 2946.9 34.950 34.951 2 2.862 2.620 27.901 248.7 2 246.8 2 79.9 0.00 2 21.00 2 4 34.60 2 9 9 9 9 9 2192.0 2 7.7296 2 2342 2 2341 9 9

9 2 3200.3 34.934 34.934 2 2.695 2.430 27.905 250.3 2 249.6 2 78.8 0.00 2 21.09 2 4 36.80 2 0.00 2 0.00 2 0.00 2 9 747.1 350.4 2 2194.5 2 7.7304 2 2345 2 2344 41.3 2 9

8 2 3445.9 34.919 34.919 2 2.553 2.265 27.908 249.6 2 249.4 2 80.4 0.00 2 21.48 2 4 40.50 2 9 9 9 9 9 2194.7 2 7.7298 2 2346 2 2344 41.4 2 9

7 2 3699.1 34.909 34.909 2 2.475 2.161 27.910 250.1 2 249.7 2 81.0 0.00 2 21.78 2 4 43.10 2 0.01 2 0.02 4 0.00 2 9 749.4 347.3 2 2194.7 2 7.7275 2 2352 2 2342 9 9

6 2 3950.3 34.902 34.902 2 2.426 2.085 27.912 250.1 2 249.6 2 81.7 0.00 2 21.88 2 4 44.70 2 9 9 9 9 9 2196.4 2 7.7289 2 2348 2 2345 41.4 2 9

5 2 4200.5 34.895 34.895 2 2.392 2.024 27.914 249.7 2 250.2 2 81.6 0.00 2 22.27 3 4 45.20 2 0.00 6 0.00 6 0.00 6 9 752.5 347.2 2 2197.6 2 7.7271 2 2351 2 2345 9 9

4 2 4451.2 34.891 34.891 2 2.380 1.982 27.916 249.1 2 249.8 2 82.4 0.00 2 21.97 2 4 45.80 2 9 9 9 9 9 2202.5 2 9 2355 2 41.6 2 9

3 2 4598.3 34.889 34.889 2 2.382 1.966 27.917 249.4 2 249.8 2 82.5 0.00 2 21.78 3 4 45.90 2 9 9 9 9 756.9 349.0 2 2202.4 2 7.7259 2 2354 2 2350 9 9

2 2 4815.8 34.889 34.888 2 2.399 1.956 27.919 249.9 2 248.8 2 83.6 0.00 2 21.97 2 4 46.10 2 0.01 2 0.00 2 -0.01 2 9 9 2201.9 2 7.7266 2 2358 2 2350 41.8 2 9

1 2 5091.0 34.888 34.889 2 2.435 1.956 27.921 249.9 2 250.0 2 82.4 0.00 6 22.07 6 4 46.50 6 0.01 2 0.00 2 -0.01 2 9 760.5 351.7 2 2201.8 2 7.7256 2 2358 2 2349 41.5 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

91
A5R

NOAA Ship Ronald H. Brown

STATION 23 DATE 1/28/1998 LATITUDE 24.499° N

LONGITUDE 24.216° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.4 37.141 37.141 2 22.276 22.275 25.769 217.9 2 218.8 2 -5.7 0.01 2 0.10 2 4 0.10 2 9 9 9 9 331.8 363.2 2 2098.3 6 8.0434 6 2429 6 2431 9 9

35 2 39.4 37.138 37.138 2 22.265 22.257 25.774 215.0 2 219.2 2 -6.0 0.01 2 0.10 2 4 0.00 2 9 9 9 9 331.9 363.1 2 2096.8 2 8.0419 2 2427 2 2428 9 9

34 2 89.5 37.137 37.138 2 22.262 22.244 25.780 215.4 2 218.2 2 -4.9 0.01 2 0.10 2 4 0.00 2 9 9 9 9 334.1 365.5 2 2098.0 2 8.0421 2 2430 2 2429 9 9

33 2 140.8 36.982 36.964 2 20.623 20.596 26.122 212.9 2 209.7 2 10.1 0.03 2 1.76 2 4 0.00 2 9 9 9 9 9 9 9 9 9 9

32 2 191.0 36.501 36.490 2 17.948 17.915 26.452 165.2 2 191.7 2 40.0 0.01 2 10.34 2 4 1.80 2 9 9 9 9 9 9 9 9 9 9

31 2 220.1 36.266 36.272 2 16.812 16.776 26.550 127.1 2 125.9 2 111.2 0.00 2 16.39 2 4 3.00 2 9 9 9 9 602.4 530.1 2 2172.5 3 7.8142 2 2369 2 2367 9 9

30 2 251.0 36.105 36.084 2 15.926 15.886 26.634 118.3 2 112.5 2 129.0 0.00 2 17.08 2 4 4.00 2 9 9 9 9 9 9 9 9 9 9

29 2 280.4 35.992 35.992 2 15.209 15.166 26.711 105.1 2 108.1 2 137.0 0.00 2 18.74 2 4 4.60 2 9 9 9 9 705.8 582.6 2 2187.4 3 7.7506 2 2358 2 2350 9 9

28 2 340.6 35.910 35.909 2 14.339 14.288 26.841 99.1 2 112.3 2 137.3 0.00 2 19.13 2 4 5.00 2 9 9 9 9 9 9 9 9 9 9

27 2 402.8 35.821 35.826 2 13.528 13.470 26.945 126.4 2 128.1 2 125.8 0.00 2 18.45 2 4 5.00 2 9 9 9 9 9 9 9 9 9 9

26 2 459.7 35.732 35.733 2 12.835 12.771 27.020 141.4 2 138.6 2 119.1 0.00 2 18.74 2 4 5.50 2 9 9 9 9 9 9 9 9 9 9

25 2 520.3 35.611 35.615 2 11.978 11.909 27.095 136.4 2 138.1 2 124.5 0.00 2 20.31 2 4 6.50 2 9 9 9 9 747.8 539.3 2 2181.7 2 7.7280 2 2336 2 2332 9 9

24 2 579.5 35.525 35.535 2 11.276 11.202 27.162 146.8 2 143.5 2 123.2 0.00 2 20.89 2 4 7.50 2 9 9 9 9 9 9 9 9 9 9

23 2 679.9 35.310 35.315 2 9.739 9.659 27.265 102.0 2 107.6 2 168.6 0.00 2 27.63 2 4 12.70 2 9 9 9 9 9 9 9 9 9 9

22 2 770.3 35.195 35.201 2 8.636 8.551 27.356 112.9 2 112.9 2 170.4 0.00 2 29.20 2 4 15.60 2 9 9 9 9 9 9 9 9 9 9

21 2 881.4 35.094 35.099 2 7.536 7.446 27.443 123.5 2 125.2 2 165.5 0.00 2 29.40 2 4 18.40 2 9 9 9 9 9 9 9 9 9 9

20 2 978.4 35.167 35.138 2 7.424 7.324 27.519 144.0 2 139.9 2 151.5 0.00 2 27.93 2 4 18.50 2 9 9 9 9 958.6 569.7 2 2210.6 6 7.6329 6 5 2320 9 9

19 2 1082.1 35.221 35.212 2 7.229 7.119 27.592 159.0 2 156.8 2 135.9 0.00 2 25.88 2 4 17.70 2 9 9 9 9 9 9 9 9 9 9

18 2 1270.7 35.221 35.222 2 6.378 6.255 27.711 181.8 2 181.0 2 117.6 0.00 2 24.12 2 4 18.30 2 9 9 9 9 9 9 9 9 9 9

17 2 1471.5 35.174 35.175 2 5.567 5.432 27.778 200.0 2 199.6 2 104.9 0.00 2 22.75 2 4 19.20 2 9 9 9 9 800.8 433.9 2 2190.9 2 7.7009 2 5 2328 9 9

16 2 1675.6 35.124 35.125 2 4.854 4.707 27.824 213.8 2 213.3 2 96.7 0.00 2 22.07 2 4 20.90 2 9 9 9 9 9 9 9 9 9 9

15 2 1872.2 35.096 35.095 2 4.413 4.252 27.853 223.0 2 224.0 2 89.5 0.00 2 21.49 2 4 22.50 2 9 9 9 9 9 9 9 9 9 9

14 2 2078.3 35.038 35.038 2 3.883 3.709 27.863 232.4 2 232.6 2 85.2 0.00 2 21.19 2 4 23.70 2 9 9 9 9 760.5 379.4 2 2183.6 2 7.7193 2 2333 2 2328 9 9

13 2 2280.7 35.020 35.020 2 3.621 3.432 27.878 232.9 2 234.0 2 86.0 0.00 2 21.19 2 4 26.70 2 9 9 9 9 9 9 9 9 9 9

12 2 2479.7 34.998 34.997 2 3.371 3.166 27.887 239.0 2 239.3 2 82.9 0.00 2 20.90 2 4 28.40 2 9 9 9 9 9 9 9 9 9 9

11 2 2676.7 34.975 34.976 2 3.124 2.904 27.894 246.0 2 245.5 2 78.9 0.00 2 20.80 2 4 30.10 2 9 9 9 9 9 9 9 9 9 9

10 2 2879.3 34.956 34.956 2 2.895 2.659 27.901 252.5 2 250.6 2 75.8 0.00 2 20.80 2 4 31.70 2 9 9 9 9 743.0 352.4 6 2186.2 2 7.7334 2 2341 2 2336 9 9

9 2 3141.9 34.934 34.934 2 2.699 2.440 27.904 248.9 2 248.2 2 80.1 0.00 2 21.29 2 4 36.60 2 9 9 9 9 9 9 9 9 9 9

8 2 3401.0 34.920 34.920 2 2.560 2.277 27.907 248.2 2 248.8 2 80.9 0.00 2 21.68 2 4 39.70 2 9 9 9 9 9 9 9 9 9 9

7 2 3660.7 34.910 34.909 2 2.481 2.171 27.910 249.3 2 249.9 2 80.7 0.00 2 21.59 2 4 41.80 2 9 9 9 9 9 9 9 2354 2 9 9

6 2 3918.7 34.902 34.901 2 2.424 2.087 27.912 249.7 2 249.9 2 81.4 0.00 2 21.78 2 4 44.00 2 9 9 9 9 9 9 9 9 9 9

5 2 4180.5 34.896 34.895 2 2.396 2.030 27.914 249.8 2 250.0 2 81.8 0.00 2 21.78 2 4 45.50 2 9 9 9 9 9 9 9 9 9 9

4 2 4401.8 34.892 34.892 2 2.380 1.988 27.916 249.5 2 246.2 2 86.0 0.00 2 21.98 2 4 46.70 2 9 9 9 9 9 9 9 9 9 9

3 2 4700.1 34.889 34.890 2 2.386 1.958 27.918 249.5 2 249.9 2 82.5 0.00 2 22.47 3 4 47.60 2 9 9 9 9 754.2 347.7 2 2201.5 2 7.7278 2 2357 2 2350 9 9

2 2 4960.1 34.887 34.889 2 2.417 1.955 27.919 249.9 2 248.3 2 84.1 0.00 2 22.08 2 4 47.90 2 9 9 9 9 9 9 9 9 9 9

1 2 5222.4 34.888 34.888 2 2.451 1.955 27.922 250.0 2 249.5 2 82.9 0.00 6 22.27 6 4 46.90 6 9 9 9 9 763.0 353.2 2 2201.5 2 7.7265 2 9 2349 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

92
A5R

NOAA Ship Ronald H. Brown

STATION 24 DATE 1/28/1998 LATITUDE 24.500° N

LONGITUDE 24.950° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.3 37.110 37.114 2 22.051 22.050 25.809 221.1 2 221.3 2 -7.3 0.01 2 0.00 2 4 0.80 2 2.23 2 1.44 2 0.16 2 9 338.1 366.8 6 2096.2 6 8.0412 6 2429 6 2427 9 9

35 2 48.8 37.106 37.108 2 22.030 22.020 25.818 217.3 2 218.8 2 -4.7 0.00 2 0.00 2 4 0.60 2 2.25 6 1.41 6 0.16 6 9 9 9 9 9 9 9

34 2 100.9 37.144 37.146 2 22.127 22.107 25.825 214.2 2 188.6 3 25.2 0.01 2 0.10 2 4 0.60 2 2.22 2 1.42 2 0.16 2 9 9 9 9 9 9 9

33 2 150.6 36.834 36.832 2 19.222 19.195 26.382 197.2 2 198.3 2 27.4 0.02 2 2.54 2 4 1.10 2 2.53 2 1.48 4 0.13 2 9 9 9 9 9 9 9

32 2 201.4 36.609 36.596 2 17.981 17.946 26.528 191.9 2 194.7 2 36.7 0.01 2 4.39 2 4 1.40 2 2.60 2 1.31 2 0.05 2 9 9 9 9 9 9 9

31 2 224.4 36.448 36.437 2 17.192 17.154 26.599 185.6 2 185.3 2 49.8 0.01 2 6.63 2 4 2.00 2 2.62 2 1.29 2 0.06 2 9 9 9 9 9 9 9

30 2 272.4 36.170 36.169 2 15.877 15.834 26.697 142.1 2 150.5 2 91.1 0.01 2 12.49 2 4 3.90 2 2.30 2 1.15 2 0.03 2 9 9 9 9 9 9 9

29 2 300.3 36.028 36.028 2 15.110 15.064 26.762 134.1 2 127.5 2 118.0 0.00 2 16.30 2 4 5.30 2 2.11 2 1.05 2 0.02 2 9 9 9 9 9 9 9

28 2 346.2 35.977 35.977 2 14.495 14.443 26.859 127.3 2 142.7 3 106.0 0.00 2 15.42 2 4 4 2.20 2 1.12 2 0.02 2 9 9 9 9 9 9 9

27 2 400.1 35.818 35.808 2 13.471 13.414 26.955 113.7 2 125.8 2 128.4 0.00 2 18.94 2 4 6.80 2 1.90 2 0.91 2 0.01 2 9 9 9 9 9 9 9

26 2 447.8 35.748 35.754 2 12.845 12.783 27.029 155.2 2 153.6 2 104.0 0.00 2 16.89 2 4 6.10 2 1.94 2 0.92 2 0.02 2 9 9 9 9 9 9 9

25 2 499.0 35.620 35.620 2 12.017 11.951 27.094 149.6 2 139.8 2 122.6 0.00 2 20.01 2 4 7.90 2 1.53 2 0.72 2 0.01 2 9 9 9 9 9 9 9

24 2 600.6 35.437 35.427 2 10.649 10.575 27.206 118.5 2 119.3 2 151.3 0.00 2 24.80 2 4 11.40 2 0.76 2 0.38 2 0.00 2 9 9 9 9 9 9 9

23 2 701.2 35.322 35.324 2 9.567 9.485 27.305 114.0 2 120.7 2 156.6 0.00 2 26.46 2 4 13.80 2 0.41 2 0.23 2 0.00 2 9 9 9 9 9 9 9

22 2 799.2 35.173 35.177 2 8.389 8.303 27.378 114.1 2 115.6 2 169.3 0.00 2 28.90 2 4 16.90 2 0.14 6 0.09 6 0.00 6 9 9 9 9 9 9 9

21 2 900.3 35.217 35.212 2 8.049 7.953 27.466 133.9 2 135.3 2 151.8 0.00 2 4 4 17.00 2 0.14 2 0.08 2 0.00 2 9 9 9 9 9 9 9

20 2 999.2 35.211 35.211 2 7.543 7.440 27.538 147.2 2 146.4 2 144.1 0.00 2 26.37 2 4 17.50 2 0.13 2 0.07 2 0.00 2 9 9 9 9 9 9 9

19 2 1199.8 35.233 35.233 2 6.702 6.584 27.675 173.5 2 172.2 2 124.1 0.00 2 24.31 2 4 18.00 2 9 9 9 9 9 9 9 9 9 9

18 2 1401.2 35.217 35.218 2 5.978 5.845 27.761 195.2 2 191.1 2 110.4 0.00 2 22.75 2 4 18.50 2 0.05 6 0.03 6 -0.01 6 9 9 9 9 9 9 9

17 2 1598.9 35.147 35.148 2 5.119 4.976 27.812 210.2 2 207.5 2 100.4 0.00 2 22.17 2 4 20.20 2 9 9 9 9 9 9 9 9 9 9

16 2 1798.0 35.098 35.099 2 4.512 4.357 27.843 221.2 2 220.3 2 92.4 0.00 2 21.48 2 4 22.10 2 9 9 9 9 9 9 9 9 9 9

15 2 2000.5 35.056 35.056 2 4.032 3.864 27.862 229.2 2 229.2 2 87.4 0.00 2 21.09 2 4 24.10 2 0.01 2 0.01 2 -0.01 2 9 9 9 9 9 9 9

14 2 2197.4 35.023 35.023 2 3.660 3.478 27.875 232.2 2 233.9 2 85.8 0.00 2 21.00 2 4 26.80 2 9 9 9 9 9 9 9 9 9 9

13 2 2402.5 35.000 35.000 2 3.395 3.197 27.885 239.9 2 238.4 2 83.5 0.00 2 21.00 2 4 28.40 2 9 9 9 9 9 9 9 9 9 9

12 2 2593.4 34.980 34.980 2 3.178 2.965 27.892 245.3 2 242.8 2 81.1 0.00 2 20.90 2 4 30.00 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

11 2 2798.2 34.961 34.961 2 2.957 2.728 27.898 251.4 2 249.7 2 76.1 0.00 2 20.80 2 4 32.00 2 9 9 9 9 9 9 9 9 9 9

10 2 3001.4 34.941 34.942 2 2.770 2.524 27.902 250.1 2 248.0 2 79.6 0.00 2 21.00 2 4 35.70 2 9 9 9 9 9 9 9 9 9 9

9 2 3300.7 34.923 34.923 2 2.583 2.310 27.907 250.7 2 248.6 2 80.8 0.00 2 21.49 2 4 39.30 2 0.00 2 0.01 2 -0.01 2 9 9 9 9 9 9 9

8 2 3550.7 34.912 34.913 2 2.500 2.202 27.909 249.2 2 249.7 2 80.6 0.00 2 21.59 2 4 40.50 2 9 9 9 9 9 9 9 9 9 9

7 2 3801.4 34.904 34.904 2 2.439 2.115 27.911 249.4 2 249.2 2 81.9 0.00 2 21.68 2 4 42.00 2 9 9 9 9 9 9 9 9 9 9

6 2 4050.0 34.898 34.898 2 2.404 2.053 27.913 250.5 2 249.4 2 82.2 0.00 2 21.68 2 4 43.10 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

5 2 4301.4 34.894 34.894 2 2.384 2.004 27.915 250.4 2 249.4 2 82.6 0.00 2 21.88 2 4 44.40 2 9 9 9 9 9 9 9 9 9 9

4 2 4550.1 34.891 34.890 2 2.381 1.971 27.917 249.4 2 248.8 2 83.5 0.00 2 21.98 2 4 45.30 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

3 2 4797.9 34.889 34.888 2 2.397 1.956 27.919 249.3 2 248.5 2 83.9 0.00 2 21.88 2 4 45.90 2 9 9 9 9 9 9 9 9 9 9

2 2 5050.6 34.888 34.889 2 2.426 1.953 27.920 249.8 2 247.1 2 85.4 0.00 2 22.17 2 4 45.70 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

1 2 5330.7 34.887 34.887 2 2.459 1.948 27.923 249.4 2 248.8 2 83.7 0.01 6 22.07 6 4 46.50 6 0.00 6 0.00 6 0.00 6 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

93
A5R

NOAA Ship Ronald H. Brown

STATION 25 DATE 1/28/1998 LATITUDE 24.500° N

LONGITUDE 25.683° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.4 37.276 37.278 2 22.167 22.166 25.903 227.3 2 219.5 2 -6.2 0.00 2 0.00 2 4 0.40 2 9 9 9 9 335.3 365.4 2 2099.7 6 9 2430 2 9 9

35 2 73.4 37.429 37.430 2 22.452 22.437 25.946 216.6 2 215.8 2 -3.7 0.00 2 0.00 2 4 0.40 2 9 9 9 9 9 9 9 9 9 9

34 2 120.5 36.937 36.940 2 19.901 19.879 26.280 217.5 2 218.1 2 4.6 0.06 2 0.29 2 4 0.60 2 9 9 9 9 361.5 360.1 2 2102.6 2 8.0119 2 2412 2 2412 9 9

33 2 148.9 36.786 36.794 2 18.896 18.869 26.429 210.0 2 210.3 2 16.8 0.02 2 1.27 2 4 0.70 2 9 9 9 9 9 9 9 9 9 9

32 3 199.4 36.529 36.532 2 17.569 17.535 26.568 204.5 2 200.8 2 32.5 0.01 2 4.39 2 4 1.40 2 9 9 9 9 416.7 377.7 2 2114.2 2 9 2387 2 9 9

31 2 224.7 36.389 36.400 2 16.842 16.805 26.637 206.6 2 198.6 2 38.2 0.01 2 5.76 2 4 1.80 2 9 9 9 9 9 9 9 9 9 9

30 2 268.9 36.289 36.287 2 16.273 16.229 26.698 204.3 2 197.5 2 42.1 0.00 2 7.03 2 4 2.10 2 9 9 9 9 452.1 388.5 2 2119.0 2 9 9 9 9

29 2 349.6 36.089 36.090 2 14.965 14.911 26.844 190.4 2 186.2 2 60.0 0.01 2 10.05 2 4 3.30 2 9 9 9 9 9 9 9 9 9 9

28 2 401.3 35.941 35.945 2 14.000 13.941 26.940 182.4 2 178.3 2 73.0 0.01 2 12.40 2 4 4.20 2 9 9 9 9 555.4 434.6 2 2145.5 2 7.8428 2 2352 2 2351 9 9

27 2 450.9 35.802 35.801 2 13.132 13.069 27.014 179.0 2 173.2 2 82.8 0.00 2 14.35 2 4 5.20 2 9 9 9 9 9 9 9 9 9 9

26 2 499.9 35.679 35.682 2 12.299 12.231 27.086 174.5 2 168.4 2 92.3 0.00 2 16.30 2 4 6.20 2 9 9 9 9 642.3 468.2 2 2160.8 2 9 9 9 9

25 2 553.5 35.597 35.600 2 11.683 11.611 27.141 167.2 2 161.8 2 102.5 0.00 2 18.16 2 4 7.30 2 9 9 9 9 9 9 9 9 9 9

24 2 601.2 35.534 35.536 2 11.171 11.094 27.189 164.4 2 159.9 2 107.5 0.00 2 19.04 2 4 8.40 2 9 9 9 9 699.1 485.8 2 2172.4 2 7.7469 2 2333 2 2330 9 9

23 2 650.0 35.451 35.454 2 10.466 10.386 27.251 150.6 2 143.3 2 128.3 0.00 2 21.97 2 4 10.70 2 9 9 9 9 9 9 9 9 9 9

22 2 699.1 35.383 35.383 2 9.827 9.744 27.310 140.7 2 135.9 2 139.7 0.00 2 4 4 12.80 2 9 9 9 9 849.4 559.4 2 2193.9 2 9 9 9 9

21 2 798.5 35.280 35.281 2 8.743 8.654 27.407 133.5 2 133.5 2 149.0 0.00 2 25.68 2 4 15.80 2 9 9 9 9 900.9 566.8 2 2203.0 2 7.6593 2 2328 2 2323 9 9

20 2 900.8 35.216 35.216 2 7.881 7.786 27.490 139.0 2 139.8 2 148.4 0.00 2 26.66 2 4 18.00 2 9 9 9 9 9 9 9 9 9 9

19 2 1101.4 35.214 35.212 2 6.882 6.773 27.634 165.3 2 166.9 2 128.1 0.00 2 24.81 2 4 18.80 2 9 9 9 9 853.0 492.3 2 2200.4 6 9 9 9 9

18 2 1299.9 35.239 35.237 2 6.203 6.079 27.748 185.1 2 191.2 2 108.6 0.00 2 4 4 18.70 2 9 9 9 9 9 9 9 9 9 9

17 2 1500.9 35.197 35.198 2 5.455 5.318 27.810 205.4 2 207.3 2 98.0 0.00 2 21.88 2 4 20.10 2 9 9 9 9 773.4 416.2 2 2187.1 2 7.7141 2 2333 2 2330 9 9

16 2 1702.1 35.130 35.131 2 4.732 4.583 27.843 217.3 2 218.9 2 92.0 0.00 2 21.39 2 4 22.40 2 9 9 9 9 9 9 9 9 9 9

15 2 1902.7 35.079 35.077 2 4.166 4.005 27.865 228.5 2 231.2 2 84.2 0.00 2 20.90 2 4 23.90 2 9 9 9 9 9 2181.7 2 9 9 9 9

14 2 2297.3 35.007 35.007 2 3.420 3.232 27.886 245.0 2 244.8 2 76.8 0.00 2 4 4 27.40 2 9 9 9 9 9 9 9 9 9 9

13 2 2497.3 34.980 34.980 2 3.130 2.928 27.894 250.4 2 249.0 2 75.2 9 9 9 9 9 9 9 9 733.8 351.7 6 2182.7 2 7.7334 2 2334 2 2332 9 9

12 2 2701.1 34.959 34.959 2 2.920 2.701 27.898 252.2 2 249.3 2 76.8 0.01 2 20.51 2 4 32.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2902.2 34.944 34.944 2 2.775 2.539 27.901 251.7 2 249.4 2 78.0 0.00 2 20.71 2 4 34.90 2 9 9 9 9 9 2189.3 2 9 9 9 9

10 2 3147.6 34.928 34.929 2 2.630 2.372 27.905 250.8 2 250.7 2 78.1 0.00 2 21.10 2 4 37.90 2 9 9 9 9 9 9 9 9 9 9

9 2 3398.7 34.918 34.919 2 2.541 2.258 27.908 249.8 2 248.8 2 81.0 0.00 2 21.88 3 4 40.40 2 9 9 9 9 748.5 348.3 2 2194.8 2 7.7294 2 2345 2 2343 9 9

8 2 3651.3 34.909 34.910 2 2.478 2.170 27.910 249.2 2 248.7 2 81.9 0.00 2 21.69 2 4 42.50 2 9 9 9 9 9 9 9 9 9 9

7 3 3902.0 34.903 2 2.435 2.100 27.912 248.9 2 248.4 2 82.8 0.00 2 21.59 2 4 44.20 2 9 9 9 9 9 9 9 9 9 9

6 2 4151.4 34.898 34.898 2 2.400 2.037 27.914 248.3 2 248.3 2 83.4 0.00 2 4 4 45.50 2 9 9 9 9 9 9 9 9 9 9

5 2 4335.8 34.894 34.895 2 2.389 2.005 27.916 249.6 2 248.9 2 83.1 0.00 2 21.88 2 4 46.50 2 9 9 9 9 749.3 345.5 2 2199.4 2 7.7289 2 2351 2 2348 9 9

4 3 4652.3 34.889 2 2.386 1.964 27.918 249.4 2 248.8 2 83.6 0.00 2 22.18 2 4 47.60 2 9 9 9 9 9 9 9 9 9 9

3 2 4884.0 34.889 34.889 2 2.404 1.952 27.920 249.8 2 248.6 2 83.9 0.00 2 4 4 48.20 2 9 9 9 9 9 2202.2 2 9 9 9 9

2 2 5147.4 34.887 34.888 2 2.430 1.944 27.922 250.2 2 247.7 2 84.8 0.00 2 22.27 2 4 48.80 2 9 9 9 9 9 9 9 9 9 9

1 2 5409.3 34.886 34.887 2 2.463 1.942 27.923 250.0 2 248.6 2 84.0 0.00 6 22.37 6 4 48.90 6 9 9 9 9 755.4 349.5 2 2203.0 2 7.7279 2 2358 2 2351 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

94
A5R

NOAA Ship Ronald H. Brown

STATION 26 DATE 1/29/1998 LATITUDE 24.500° N

LONGITUDE 26.416° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.4 37.411 37.410 2 22.639 22.638 25.870 214.7 2 215.7 2 -4.3 0.00 2 0.00 2 4 0.90 2 1.97 2 1.15 2 0.15 2 9 317.6 352.8 2 2098.6 6 8.0608 2 2447 2 2446 67.2 2 9

35 2 6.5 37.410 37.410 2 22.638 22.637 25.870 214.7 2 215.8 2 -4.4 0.00 2 0.00 2 4 1.00 2 1.98 6 1.14 6 0.17 6 9 317.2 352.3 2 2097.6 2 8.0599 2 2454 2 2444 66.3 2 9

34 2 51.0 37.410 37.410 2 22.644 22.634 25.873 215.0 2 215.9 2 -4.5 0.00 2 0.00 2 4 1.00 2 1.97 2 1.15 2 0.16 2 9 317.3 352.6 2 2097.9 2 8.0603 2 2451 2 2445 65.7 2 9

33 2 100.6 37.436 37.439 2 22.494 22.474 25.943 215.0 2 217.4 2 -5.4 0.01 2 0.00 2 4 0.80 2 2.03 2 1.17 2 0.16 2 9 318.3 351.5 2 2099.5 2 8.0592 2 9 2446 67.1 2 9

32 2 152.1 36.914 36.918 2 19.753 19.725 26.304 213.3 2 216.7 2 6.7 0.04 2 0.49 2 4 1.20 2 2.30 2 1.32 2 0.16 2 9 366.2 362.1 2 2106.6 2 8.0068 2 2420 2 2413 57.0 2 9

31 2 200.3 36.679 36.681 2 18.406 18.371 26.476 203.4 2 197.0 2 32.4 0.02 2 3.80 2 4 1.30 2 2.30 2 1.29 2 0.06 2 9 410.3 384.5 2 2118.6 2 7.9631 2 5 2396 52.0 2 9

30 2 225.4 36.568 36.568 2 17.821 17.782 26.538 192.0 2 193.6 2 38.5 0.01 2 4.88 2 4 1.60 2 2.35 2 1.31 2 0.06 2 9 427.4 391.3 2 2120.7 2 7.9505 2 2395 2 2389 50.9 2 9

29 2 250.6 36.443 36.447 2 17.103 17.061 26.619 191.3 2 189.2 2 46.3 0.01 2 6.25 2 4 1.70 2 2.36 2 1.31 2 0.04 2 9 448.5 398.9 2 2126.6 2 7.9286 2 2394 2 2381 50.0 2 9

28 2 274.3 36.346 36.352 2 16.539 16.494 26.680 187.0 2 183.4 2 54.8 0.01 2 8.00 2 4 2.20 2 2.31 2 1.28 2 0.04 2 9 480.5 417.8 2 2132.0 2 7.9064 2 2379 2 2374 9 9

27 2 298.7 36.253 36.252 2 16.029 15.981 26.728 182.8 2 174.0 2 66.8 0.01 2 9.76 2 4 2.90 2 2.26 2 1.22 2 0.03 2 9 504.7 429.9 2 2140.0 2 7.8815 2 5 2368 47.5 2 9

26 2 352.0 36.123 36.130 2 15.183 15.129 26.822 148.5 2 183.0 2 62.1 0.01 2 10.05 2 4 3.10 2 2.29 2 1.22 2 0.04 2 9 505.1 414.7 2 2140.2 2 7.8788 2 2366 2 2365 9 9

25 2 400.5 35.998 36.010 2 14.377 14.317 26.904 185.9 2 185.8 2 63.5 0.01 2 11.03 2 4 3.50 2 2.31 2 1.22 2 0.03 2 9 525.7 418.2 2 2136.1 2 7.8621 2 5 2351 46.8 2 9

24 2 450.3 35.846 35.854 2 13.429 13.365 26.988 178.4 2 181.3 2 73.1 0.00 2 13.08 2 4 4.50 2 2.16 6 1.13 6 0.02 6 9 566.1 432.4 2 2143.2 2 7.8335 2 2351 2 2343 9 9

23 2 501.1 35.722 35.727 2 12.593 12.524 27.061 184.1 2 183.1 2 76.0 0.00 2 14.35 2 4 5.20 2 1.99 2 1.03 2 0.02 2 9 593.8 437.6 2 2146.8 2 7.8143 2 2350 3 2336 46.5 2 9

22 2 553.0 35.638 35.641 2 11.965 11.891 27.120 186.4 2 184.0 2 78.7 0.00 2 15.43 2 4 6.20 2 1.84 2 0.94 2 0.02 2 9 616.0 442.1 2 2151.4 2 7.8009 2 2339 2 2334 9 9

21 2 599.3 35.567 35.570 2 11.351 11.274 27.182 183.0 2 174.7 2 91.6 0.00 2 17.38 2 4 7.50 2 1.53 2 0.79 2 0.02 2 9 660.8 462.2 2 2160.6 2 7.7724 2 2342 2 2330 43.4 2 9

20 2 702.5 35.435 35.439 2 10.138 10.053 27.298 156.8 2 151.9 2 121.7 0.00 2 21.78 2 4 11.00 2 0.76 2 0.39 2 0.00 2 9 771.3 513.4 2 2182.1 2 7.7157 2 2333 2 2326 9 9

19 2 798.3 35.334 35.336 2 9.038 8.948 27.403 145.8 2 145.0 2 135.5 0.00 2 24.42 2 4 13.80 2 0.33 2 0.17 2 0.00 2 9 840.0 533.8 2 2193.7 2 7.6842 2 5 2324 42.6 2 9

18 2 902.1 35.237 35.240 2 7.922 7.827 27.501 148.2 2 148.5 2 139.4 0.00 2 25.59 2 4 16.50 2 0.16 2 0.09 2 -0.01 2 9 9 2199.2 2 7.6661 2 2331 2 2322 9 9

17 2 1091.0 35.204 35.203 2 6.785 6.678 27.639 166.7 2 168.9 2 126.8 0.00 2 24.52 2 4 18.30 2 0.08 2 0.04 2 0.01 2 9 851.8 489.1 2 2199.6 6 7.6752 2 2334 2 2326 41.7 2 9

16 2 1302.2 35.199 35.198 2 5.971 5.849 27.745 190.9 2 191.0 2 110.5 0.00 2 23.05 2 4 18.90 2 0.04 2 0.02 2 -0.01 2 9 9 2191.2 2 7.6958 2 2335 2 2326 9 9

15 2 1502.0 35.172 35.173 2 5.262 5.127 27.812 208.4 2 207.9 2 98.9 0.00 2 21.88 2 4 19.90 2 9 9 9 9 775.7 413.6 2 2187.4 3 7.7103 2 5 2328 41.6 2 9

14 2 1700.3 35.118 35.119 2 4.635 4.488 27.844 219.9 2 221.0 2 90.6 0.00 2 21.29 2 4 21.30 2 0.01 6 0.00 6 0.01 6 9 9 2183.5 2 7.7175 2 2336 2 2327 9 9

13 2 1900.0 35.084 35.085 2 4.229 4.068 27.863 230.9 2 230.2 2 84.7 0.00 2 20.81 2 4 22.70 2 9 9 9 9 751.1 380.6 2 2181.9 2 7.7235 2 2334 2 2328 42.0 2 9

12 2 2097.8 35.050 35.049 2 3.849 3.674 27.877 238.1 2 238.7 2 79.4 0.00 2 20.51 2 4 24.20 2 0.01 6 0.00 2 0.01 6 9 9 2181.2 2 7.7269 2 2334 2 2328 9 9

11 2 2301.6 35.016 35.017 2 3.504 3.314 27.886 244.3 2 245.7 2 75.3 0.00 2 20.22 2 4 25.90 2 9 9 9 9 733.6 358.5 2 2180.4 2 7.7317 2 2343 3 2330 41.9 2 9

10 2 2501.8 34.985 34.985 2 3.186 2.982 27.893 249.6 2 249.1 2 74.6 0.00 2 20.22 2 4 28.80 2 0.00 2 0.00 2 0.00 2 9 9 2181.4 2 7.7323 2 2342 3 2331 9 9

9 2 2694.8 34.961 34.963 2 2.957 2.738 27.897 250.6 2 249.9 2 75.8 0.00 2 20.81 2 4 31.90 2 9 9 9 9 734.6 349.1 2 2185.2 2 7.7309 2 2347 3 2334 42.0 2 9

8 2 2896.4 34.944 34.944 2 2.777 2.542 27.901 250.8 2 249.9 2 77.5 0.00 2 20.71 2 4 34.50 2 0.00 2 0.00 2 0.00 2 9 9 2186.9 2 7.7313 2 2343 2 2336 9 9

7 2 3201.6 34.926 34.926 2 2.600 2.337 27.906 249.3 2 248.4 2 80.7 0.00 2 21.59 2 4 38.40 2 9 9 9 9 744.0 347.1 2 2191.8 2 7.7284 2 2354 3 2340 42.0 2 9

6 2 3499.4 34.913 34.913 2 2.498 2.206 27.909 248.3 2 248.6 2 81.7 0.00 2 21.49 2 4 40.70 2 0.00 2 0.00 2 0.00 2 9 9 2192.8 2 7.7286 2 2346 2 2341 9 9

5 2 3899.7 34.902 34.902 2 2.420 2.085 27.912 247.5 2 248.6 2 82.7 0.00 2 21.98 2 4 43.30 2 9 9 9 9 750.5 346.8 2 2195.8 2 7.7273 2 5 2344 41.6 2 9

4 2 4300.3 34.893 34.893 2 2.379 1.999 27.915 248.2 2 248.4 2 83.7 0.00 2 21.98 2 4 45.90 2 0.00 2 0.00 2 0.00 2 9 9 2198.1 2 7.7259 2 2356 2 2345 9 9

3 2 4699.5 34.889 34.889 2 2.386 1.958 27.918 247.7 2 248.8 2 83.6 0.00 2 21.98 2 4 46.80 2 0.00 2 0.00 2 0.00 2 9 753.9 347.5 2 2199.8 2 7.7259 2 2359 3 2347 41.6 2 9

2 2 5098.3 34.887 34.887 2 2.420 1.941 27.921 248.3 2 249.1 2 83.5 0.00 2 22.08 2 4 47.40 2 0.00 6 0.00 6 0.00 6 9 9 2202.7 2 7.7263 2 2358 2 2350 41.8 2 9

1 2 5499.0 34.886 34.886 2 2.467 1.934 27.924 249.3 2 248.9 2 83.7 0.00 6 22.18 6 4 47.80 6 0.00 2 0.00 2 0.00 2 9 758.2 350.9 2 2205.3 2 7.7257 2 2366 2 2353 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

95
A5R

NOAA Ship Ronald H. Brown

STATION 27 DATE 1/29/1998 LATITUDE 24.499° N

LONGITUDE 27.150° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.7 37.404 37.404 2 22.624 22.623 25.869 218.1 2 217.4 6 -5.9 0.00 2 0.00 2 4 1.20 2 9 9 9 9 318.4 353.4 6 2097.3 2 8.0646 2 2443 2 2447 9 9

35 2 50.5 37.413 37.416 2 22.551 22.541 25.903 216.5 2 218.3 2 -6.5 0.00 2 0.00 2 4 0.90 2 9 9 9 9 315.2 348.9 2 2099.2 6 8.0645 2 2445 2 2449 9 9

34 2 99.6 37.415 37.417 2 22.252 22.232 25.996 217.8 2 219.8 2 -6.9 0.00 2 0.00 2 4 0.80 2 9 9 9 9 320.1 350.1 2 2099.7 2 8.0584 2 2443 2 2445 9 9

33 2 149.5 36.830 36.834 2 19.403 19.376 26.331 209.6 2 216.0 2 8.9 0.04 2 0.39 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

32 2 199.7 36.594 36.589 2 17.989 17.954 26.515 202.4 2 206.2 2 25.1 0.00 2 3.32 2 4 1.20 2 9 9 9 9 400.8 369.3 2 2108.7 2 7.9742 2 2387 2 2391 9 9

31 2 225.0 36.481 36.474 2 17.360 17.322 26.584 203.2 2 205.4 2 28.9 0.00 2 4.59 2 4 1.50 2 9 9 9 9 9 9 9 9 9 9

30 2 252.3 36.378 36.377 2 16.807 16.765 26.640 202.6 2 202.1 2 34.9 0.00 2 5.56 2 4 1.70 2 9 9 9 9 9 2115.5 2 7.9462 2 2377 2 2380 9 9

29 2 274.3 36.328 36.327 2 16.491 16.446 26.677 202.1 2 202.1 2 36.4 0.00 2 6.05 2 4 1.90 2 9 9 9 9 9 9 9 9 9 9

28 2 300.2 36.272 36.272 2 16.157 16.109 26.713 201.5 2 200.5 2 39.7 0.00 2 6.83 2 4 2.00 2 9 9 9 9 450.2 384.9 2 2120.6 2 7.9265 2 2371 2 2373 9 9

27 2 352.3 36.131 36.130 2 15.289 15.234 26.805 195.8 2 195.3 2 49.3 0.00 2 8.69 2 4 4 9 9 9 9 9 9 9 9 9 9

26 2 400.9 35.968 35.975 2 14.276 14.216 26.903 195.0 2 192.6 2 57.2 0.00 2 10.45 2 4 3.50 2 9 9 9 9 9 2134.9 2 7.8720 2 2355 2 2355 9 9

25 2 450.1 35.846 35.846 2 13.461 13.397 26.982 193.5 2 190.5 2 63.7 0.00 2 12.11 2 4 4.10 2 9 9 9 9 9 9 9 9 9 9

24 2 500.4 35.731 35.730 2 12.686 12.617 27.051 192.8 2 188.4 2 70.2 0.00 2 13.86 2 4 5.10 2 9 9 9 9 585.1 432.9 2 2148.7 2 7.8243 2 9 2343 9 9

23 2 550.4 35.645 35.646 2 12.037 11.964 27.112 190.0 2 184.6 2 77.7 0.00 2 15.23 2 4 6.10 2 9 9 9 9 9 9 9 9 9 9

22 2 652.2 35.512 35.512 2 10.827 10.745 27.235 177.6 2 172.6 2 96.8 0.00 2 18.46 2 4 8.30 2 9 9 9 9 691.1 473.1 2 2168.8 2 7.7597 2 2331 2 2332 9 9

21 2 751.6 35.393 35.393 2 9.517 9.430 27.371 162.0 2 156.9 2 120.6 0.00 2 22.46 2 4 4 9 9 9 9 9 9 9 9 9 9

20 2 852.8 35.310 35.310 2 8.526 8.432 27.466 153.2 2 153.4 2 130.4 0.00 2 24.03 2 4 14.50 2 9 9 9 9 9 9 9 9 9 9

19 2 917.8 35.271 35.270 2 7.985 7.888 27.518 156.8 2 156.3 2 131.1 0.00 2 24.51 2 4 15.80 2 9 9 9 9 841.7 510.4 2 2198.1 6 7.6804 2 9 2327 9 9

18 2 1051.6 35.246 35.246 2 7.218 7.111 27.612 169.0 2 166.3 2 126.3 0.00 2 23.83 2 4 16.90 2 9 9 9 9 9 9 9 9 9 9

17 2 1151.8 35.250 35.252 2 6.875 6.760 27.665 181.2 2 176.7 2 118.3 0.00 2 23.54 2 4 17.00 2 9 9 9 9 817.2 470.6 2 2196.1 2 7.6921 2 2334 2 2330 9 9

16 2 1351.6 35.213 35.212 2 5.941 5.814 27.761 200.9 2 198.9 2 102.8 0.00 2 22.17 2 4 17.90 2 9 9 9 9 9 9 9 9 9 9

15 2 1601.1 35.158 35.159 2 5.012 4.870 27.832 219.3 2 219.9 2 88.8 0.00 2 4 4 19.50 2 9 9 9 9 9 2184.5 2 7.7208 2 2340 2 2330 9 9

14 2 1848.3 35.096 35.095 2 4.318 4.160 27.862 228.7 2 231.5 2 82.7 0.00 2 20.71 2 4 22.00 2 9 9 9 9 9 9 9 9 9 9

13 2 2101.9 35.038 35.038 2 3.733 3.559 27.879 238.3 2 242.0 2 77.0 0.00 2 20.22 2 4 24.40 2 9 9 9 9 738.6 365.2 2 2180.0 2 7.7312 2 2332 2 2329 9 9

12 2 2353.3 34.999 34.999 2 3.338 3.146 27.889 245.8 2 247.3 2 75.1 0.00 2 20.12 2 4 27.60 2 9 9 9 9 9 9 9 9 9 9

11 2 2599.8 34.970 34.971 2 3.050 2.839 27.895 249.6 2 249.7 2 75.2 0.00 2 20.42 2 4 31.00 2 9 9 9 9 9 2184.0 2 7.7327 2 5 2334 9 9

10 2 2799.5 34.952 34.951 2 2.853 2.626 27.900 250.3 2 250.5 2 76.2 0.00 2 20.52 2 4 34.00 2 9 9 9 9 9 9 9 9 9 9

9 2 3098.4 34.932 34.931 2 2.657 2.403 27.904 249.1 2 250.2 2 78.4 0.00 2 21.20 2 4 38.00 2 9 9 9 9 744.2 348.2 2 2191.7 2 7.7309 2 9 2341 9 9

8 2 3399.4 34.918 34.918 2 2.541 2.258 27.908 248.5 2 248.9 2 80.9 0.00 2 21.39 2 4 40.40 2 9 9 9 9 9 9 9 9 9 9

7 2 3699.3 34.909 34.908 2 2.464 2.151 27.911 247.5 2 249.0 2 81.7 0.00 2 21.59 2 4 42.60 2 9 9 9 9 9 9 9 9 9 9

6 2 4001.2 34.901 34.900 2 2.413 2.067 27.914 247.2 2 248.7 2 82.8 9 9 9 9 9 9 9 9 750.5 346.5 2 2198.1 2 7.7283 2 5 2345 9 9

5 2 4302.0 34.894 34.893 2 2.387 2.007 27.915 246.7 2 249.5 2 82.5 0.00 2 21.98 2 4 45.90 2 9 9 9 9 9 9 9 9 9 9

4 2 4601.9 34.890 34.889 2 2.382 1.966 27.917 249.1 2 249.6 2 82.7 0.00 2 21.98 2 4 47.10 2 9 9 9 9 9 9 9 9 9 9

3 2 4898.7 34.887 34.887 2 2.398 1.945 27.919 248.6 2 250.1 2 82.4 0.00 2 22.18 2 4 47.80 2 9 9 9 9 754.2 347.8 2 2201.9 2 7.7270 2 2358 2 2350 9 9

2 2 5202.2 34.886 34.886 2 2.428 1.935 27.921 249.8 2 249.4 2 83.2 0.00 2 22.08 2 4 48.10 2 9 9 9 9 9 9 9 9 9 9

1 2 5628.0 34.885 34.925 2 2.482 1.931 27.925 250.7 2 249.0 2 83.6 0.00 2 21.30 3 4 39.60 3 9 9 9 9 754.5 350.3 2 2194.1 2 7.7281 2 9 2342 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

96
A5R

NOAA Ship Ronald H. Brown

STATION 28 DATE 1/29/1998 LATITUDE 24.500° N

LONGITUDE 27.883° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 2.9 37.506 37.506 2 22.482 22.481 25.988 220.1 2 218.1 2 -6.2 0.00 2 0.00 2 4 0.60 2 9 9 9 9 313.9 346.4 2 9 8.0647 2 2448 2 9 9

35 2 3.6 37.506 37.505 2 22.488 22.487 25.986 220.1 2 217.1 6 -5.3 0.00 2 0.00 2 4 0.60 2 2.03 2 1.18 2 0.17 2 9 9 2100.1 6 9 9 66.5 2 9

34 2 70.4 37.503 37.502 2 22.496 22.482 25.989 215.0 2 217.4 6 -5.5 0.00 2 0.00 2 4 0.60 2 1.99 2 1.16 2 0.17 2 9 9 9 8.0636 2 2448 2 66.0 2 9

33 2 118.5 37.497 37.499 2 22.478 22.454 25.996 215.0 2 217.1 2 -5.1 0.00 2 0.00 2 4 0.60 2 2.05 2 1.19 2 0.16 2 9 313.2 345.6 2 9 9 9 65.8 2 9

32 2 170.6 36.918 36.907 2 19.644 19.613 26.338 203.7 2 207.9 2 16.0 0.02 2 0.88 2 4 0.80 2 2.26 2 1.30 2 0.13 2 9 9 9 8.0019 2 2410 2 55.5 2 9

31 2 199.3 36.735 36.730 2 18.804 18.768 26.418 202.5 2 208.5 2 19.1 0.01 2 1.56 2 4 0.90 2 2.34 2 1.32 2 0.11 2 9 395.8 377.4 2 9 9 9 50.7 2 9

30 2 224.4 36.612 36.608 2 18.148 18.109 26.491 199.1 2 202.7 2 27.9 0.01 2 3.51 2 4 1.30 2 2.36 6 1.32 6 0.06 6 9 9 9 9 9 9 9

29 2 250.6 36.489 36.490 2 17.542 17.499 26.548 197.2 2 201.1 2 32.4 0.00 2 4.78 2 4 1.60 2 2.38 2 1.32 2 0.04 2 9 9 9 7.9638 2 2385 2 47.1 2 9

28 2 268.2 36.429 36.427 2 17.212 17.167 26.583 198.4 2 200.1 2 35.0 0.00 2 5.46 2 4 1.80 2 2.34 2 1.30 2 0.04 2 9 9 9 9 9 9 9

27 2 301.4 36.345 36.343 2 16.731 16.681 26.636 198.2 2 198.3 2 39.1 0.00 2 6.34 2 4 2.00 2 2.35 2 1.29 2 0.04 2 9 449.9 393.9 2 9 9 9 46.4 2 9

26 2 380.4 36.111 36.110 2 15.278 15.219 26.794 194.7 2 194.3 2 50.4 0.00 2 8.98 2 4 3.00 2 2.28 2 1.21 2 0.03 2 9 9 9 7.9013 2 2362 2 9 9

25 2 440.9 35.947 35.950 2 14.201 14.136 26.905 191.6 2 191.0 2 59.3 0.00 2 10.83 2 4 3.80 2 2.27 2 1.20 2 0.03 2 9 513.7 404.9 2 9 9 9 9 9

24 2 500.3 35.776 35.778 2 13.005 12.935 27.022 186.5 2 184.9 2 71.9 0.00 2 13.37 2 4 5.00 2 2.05 2 1.06 2 0.02 2 9 9 9 9 9 45.3 2 9

23 2 600.1 35.579 35.580 2 11.493 11.415 27.165 179.3 2 174.0 2 91.4 0.00 2 17.08 2 4 7.20 2 1.50 2 0.76 2 0.02 2 9 647.9 455.9 2 9 7.7767 2 2334 2 42.8 2 9

22 2 701.3 35.435 35.426 2 10.144 10.059 27.296 159.2 2 151.7 2 121.9 0.00 2 21.97 2 4 11.40 2 0.65 6 0.33 6 0.00 6 9 9 9 9 9 9 9

21 2 794.2 35.319 35.320 2 9.004 8.914 27.397 144.0 2 143.0 2 137.8 0.00 2 24.60 2 4 14.50 2 0.31 2 0.16 2 0.00 2 9 881.7 561.2 2 9 9 9 42.4 2 9

20 2 900.5 35.247 35.245 2 8.041 7.945 27.491 147.7 2 149.5 2 137.6 0.00 2 25.48 2 4 16.70 2 0.16 2 0.08 2 0.00 2 9 9 9 7.6704 2 2328 2 9 9

19 2 1001.8 35.182 35.183 2 7.119 7.019 27.573 158.3 2 159.2 2 134.2 0.00 2 25.58 2 4 18.40 2 0.08 2 0.05 2 0.00 2 9 9 9 9 9 42.5 2 9

18 2 1200.8 35.202 35.201 2 6.457 6.341 27.683 179.6 2 180.5 2 117.5 0.00 2 23.83 2 4 18.40 2 0.06 2 0.04 2 0.00 2 9 854.9 484.2 6 9 9 9 9 9

17 2 1401.3 35.213 35.213 2 5.852 5.721 27.773 200.0 2 198.5 2 103.9 0.00 2 22.36 2 4 18.40 2 0.04 6 0.02 6 0.00 6 9 9 9 7.7119 2 2334 2 9 9

16 2 1600.9 35.176 35.177 2 5.199 5.055 27.825 212.7 2 213.2 2 94.1 0.00 2 21.48 2 4 19.50 2 9 9 9 9 781.5 415.5 2 9 9 9 9 9

15 2 1800.7 35.119 35.119 2 4.592 4.435 27.851 222.5 2 222.5 2 89.5 0.00 2 21.09 2 4 21.40 2 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

14 2 2001.9 35.075 35.077 2 4.141 3.971 27.867 230.9 2 232.9 2 82.8 0.00 2 20.61 2 4 22.40 2 9 9 9 9 757.5 382.2 2 9 7.7302 2 2331 2 9 9

13 2 2202.2 35.031 35.031 2 3.678 3.495 27.880 239.4 2 241.4 2 78.1 0.00 2 20.31 2 4 24.30 2 9 9 9 9 9 9 9 9 9 9

12 2 2401.4 35.000 35.000 2 3.365 3.168 27.888 244.5 2 246.0 2 76.2 0.00 2 20.22 2 4 26.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2601.4 34.974 34.975 2 3.090 2.878 27.894 247.2 2 248.5 2 76.1 0.00 2 20.31 2 4 29.60 2 0.00 2 0.00 2 -0.01 2 9 744.5 356.3 2 9 9 9 9 9

10 2 2799.5 34.954 34.954 2 2.877 2.649 27.900 248.8 2 248.6 2 77.9 0.00 2 20.61 2 4 32.60 2 9 9 9 9 9 9 9 9 9 9

9 2 3003.2 34.939 34.940 2 2.730 2.485 27.903 248.6 2 248.6 2 79.3 0.00 2 20.90 2 4 35.50 2 0.00 6 0.00 6 -0.01 6 9 744.6 349.7 2 9 7.7312 2 2344 2 9 9

8 2 3251.9 34.925 34.926 2 2.602 2.334 27.906 248.5 2 248.1 2 81.1 0.00 2 21.29 2 4 38.60 2 9 9 9 9 9 9 9 9 9 9

7 3 3551.3 34.914 34.915 2 2.508 2.210 27.910 247.3 2 248.8 2 81.4 0.00 2 21.68 2 4 41.30 2 0.00 2 0.00 2 0.00 2 9 747.2 346.8 2 9 9 9 9 9

6 2 3851.2 34.904 34.905 2 2.435 2.105 27.912 247.5 2 248.9 2 82.2 0.00 2 21.97 2 4 43.50 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

5 2 4149.1 34.898 34.899 2 2.402 2.039 27.915 247.0 2 248.3 2 83.4 0.00 2 22.07 2 4 44.50 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

4 2 4445.5 34.893 34.893 2 2.387 1.990 27.916 246.5 2 248.2 2 83.9 0.00 2 22.07 2 4 45.20 2 9 9 9 9 756.0 348.5 2 9 9 9 9 9

3 2 4800.2 34.888 34.889 2 2.394 1.953 27.919 247.2 2 249.4 2 83.1 0.00 2 22.07 2 4 45.60 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

2 2 5150.3 34.886 34.886 2 2.421 1.935 27.921 248.1 2 249.0 2 83.6 0.00 2 22.07 2 4 46.20 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

1 2 5513.7 34.886 34.886 2 2.465 1.930 27.925 248.4 2 249.4 2 83.3 0.00 6 22.07 6 4 46.80 6 9 9 9 9 755.7 348.8 2 9 7.7254 2 2352 2 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

97
A5R

NOAA Ship Ronald H. Brown

STATION 29 DATE 1/30/1998 LATITUDE 24.499° N

LONGITUDE 28.617° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.8 37.523 37.523 2 22.567 22.566 25.976 220.4 2 217.0 6 -5.5 0.00 2 0.00 2 4 0.60 2 9 9 9 9 9 2101.5 6 8.0648 2 2449 2 2453 9 9

35 2 3.5 37.523 37.524 2 22.564 22.563 25.977 221.7 2 216.9 2 -5.4 0.00 2 0.00 2 4 0.60 2 1.98 2 1.14 2 0.18 2 9 9 9 9 9 9 9

34 2 38.8 37.522 37.524 2 22.570 22.562 25.979 214.6 2 216.7 2 -5.2 0.00 2 0.00 2 4 0.70 2 2.02 2 1.17 2 0.17 2 9 9 9 9 9 9 9

33 2 89.9 37.517 37.522 2 22.576 22.558 25.979 214.1 2 216.8 2 -5.2 0.00 2 0.00 2 4 0.70 2 9 9 9 9 9 2099.8 2 8.0640 2 2447 2 2451 9 9

32 2 159.7 36.829 36.835 2 19.234 19.205 26.375 200.4 2 206.7 2 18.9 0.02 2 1.27 2 4 0.90 2 2.33 2 1.32 2 0.12 2 9 9 9 9 9 9 9

31 2 200.7 36.620 36.628 2 18.173 18.138 26.489 198.3 2 201.9 2 28.6 0.01 2 3.51 2 4 1.30 2 9 9 9 9 9 2108.5 2 7.9749 2 2392 2 2392 9 9

30 2 220.8 36.529 36.527 2 17.747 17.709 26.526 198.2 2 200.6 2 31.9 0.01 2 4.49 2 4 1.60 2 2.36 2 1.32 2 0.04 2 9 9 9 9 9 9 9

29 2 249.4 36.453 36.452 2 17.363 17.321 26.564 197.3 2 199.6 2 34.7 0.01 2 5.27 2 4 1.80 2 9 9 9 9 9 9 9 9 9 9

28 2 274.3 36.365 36.362 2 16.834 16.789 26.625 196.0 2 198.0 2 38.9 0.01 2 6.34 2 4 2.10 2 9 9 9 9 9 9 9 9 9 9

27 2 300.0 36.306 36.307 2 16.447 16.398 26.672 194.5 2 195.1 2 43.7 0.01 2 7.22 2 4 2.40 2 2.37 2 1.29 2 0.03 2 9 9 2120.1 2 7.9262 2 2374 2 2372 9 9

26 2 350.4 36.209 36.205 2 15.758 15.702 26.760 186.7 2 187.6 2 54.6 0.01 2 8.98 2 4 2.90 2 9 9 9 9 9 9 9 9 9 9

25 2 399.1 36.066 36.071 2 14.879 14.818 26.849 184.5 2 184.5 2 62.2 0.00 2 10.44 2 4 3.50 2 2.25 2 1.20 2 0.03 2 9 9 2138.3 2 7.8747 2 2360 2 2361 9 9

24 2 500.1 35.773 35.781 2 12.977 12.907 27.025 180.3 2 178.8 2 78.1 0.00 2 14.06 2 4 5.20 2 9 9 9 9 9 9 9 9 9 9

23 2 598.3 35.586 35.591 2 11.557 11.479 27.158 179.2 2 177.2 2 87.9 0.00 2 16.69 2 4 7.00 2 1.61 6 0.83 6 0.02 6 9 9 2160.5 2 7.7799 2 2336 2 2333 9 9

22 2 698.6 35.432 35.433 2 10.234 10.149 27.279 151.4 2 146.0 2 127.0 0.00 2 22.26 2 4 11.20 2 9 9 9 9 9 9 9 9 9 9

21 2 800.3 35.288 35.295 2 8.885 8.795 27.391 135.6 2 135.5 2 146.1 0.00 2 25.68 2 4 15.10 2 0.27 2 0.13 2 0.00 2 9 9 2203.2 2 7.6668 2 2327 2 2327 9 9

20 2 899.9 35.200 35.199 2 7.875 7.780 27.478 137.1 2 140.6 2 147.7 0.00 2 26.85 2 4 17.80 2 9 9 9 9 9 9 9 9 9 9

19 2 999.2 35.167 35.164 2 7.212 7.111 27.549 150.4 2 153.5 2 139.3 0.00 2 26.27 2 4 18.70 2 0.08 2 0.04 2 -0.01 2 9 9 9 9 2327 2 9 9

18 2 1149.5 35.171 35.170 2 6.530 6.419 27.648 172.5 2 173.2 2 124.3 0.00 2 24.80 2 4 18.80 2 9 9 9 9 9 2199.8 6 7.6693 2 9 2324 9 9

17 2 1299.7 35.177 35.177 2 5.986 5.864 27.726 189.7 2 189.9 2 111.5 0.00 2 23.34 2 4 18.90 2 0.04 2 0.02 2 0.00 2 9 9 9 9 9 9 9

16 2 1500.8 35.168 35.169 2 5.360 5.224 27.798 207.7 2 207.5 2 98.6 0.00 2 22.07 2 4 19.60 2 9 9 9 9 9 2189.4 2 9 9 9 9

15 2 1697.9 35.120 35.119 2 4.726 4.578 27.835 220.9 2 221.0 2 90.0 0.00 2 21.48 2 4 21.20 2 9 9 9 9 9 9 9 9 9 9

14 2 1896.5 35.073 35.036 2 4.221 4.060 27.855 229.9 2 229.6 2 85.5 0.00 2 21.19 2 4 23.00 2 9 9 9 9 9 2183.8 2 7.7217 2 2330 2 2329 9 9

13 2 2101.3 35.036 35.012 2 3.785 3.611 27.872 237.3 2 237.8 2 80.8 0.00 2 20.61 3 4 24.90 2 0.00 2 -0.01 2 0.00 2 9 9 9 9 9 9 9

12 2 2298.3 35.011 35.011 2 3.496 3.307 27.883 242.8 2 242.3 2 78.7 0.01 2 20.80 2 4 26.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2500.2 34.987 34.988 2 3.233 3.029 27.890 245.5 2 245.8 2 77.5 0.01 2 20.70 2 4 28.80 2 9 9 9 9 9 2184.5 2 9 9 9 9

10 2 2699.0 34.969 34.970 2 3.034 2.813 27.897 249.7 2 248.7 2 76.4 0.01 2 20.61 2 4 30.60 2 9 9 9 9 9 9 9 9 9 9

9 2 2901.3 34.949 34.949 2 2.829 2.592 27.901 249.6 2 248.9 2 78.1 0.00 2 20.90 2 4 33.80 2 9 9 9 9 9 2189.7 2 7.7319 2 2343 2 2339 9 9

8 2 3097.8 34.934 34.934 2 2.680 2.426 27.905 249.1 2 248.8 2 79.6 0.00 2 21.10 2 4 36.60 2 0.00 2 -0.01 2 0.00 2 9 9 9 9 9 9 9

7 2 3401.7 34.919 34.919 2 2.541 2.258 27.908 248.5 2 248.4 2 81.4 0.00 2 21.59 2 4 40.20 2 9 9 9 9 9 2195.4 2 9 9 9 9

6 2 3699.8 34.908 34.909 2 2.466 2.152 27.910 248.2 2 248.7 2 82.0 0.00 2 21.78 2 4 42.70 2 9 9 9 9 9 9 9 9 9 9

5 2 3997.4 34.901 34.901 2 2.424 2.078 27.913 247.6 2 248.9 2 82.5 0.00 2 21.98 2 4 44.40 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

4 2 4298.4 34.895 34.895 2 2.393 2.013 27.916 248.3 2 248.3 2 83.6 0.00 2 22.17 2 4 46.30 2 9 9 9 9 9 2201.7 2 7.7269 2 2350 2 2350 9 9

3 2 4689.5 34.889 34.889 2 2.386 1.959 27.918 248.3 2 249.0 2 83.4 0.00 2 22.27 2 4 47.80 2 9 9 9 9 9 9 9 9 9 9

2 2 5197.4 34.886 34.886 2 2.427 1.935 27.922 249.5 2 249.6 2 83.0 0.01 2 22.27 2 4 48.60 2 0.00 6 0.00 6 0.00 6 9 9 9 9 9 9 9

1 2 5759.6 34.885 34.885 2 2.494 1.925 27.927 250.7 2 249.9 2 82.8 0.01 6 22.37 6 4 49.00 6 0.00 2 0.00 2 0.00 2 9 9 2204.6 2 7.7260 2 2355 2 2352 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

98
A5R

NOAA Ship Ronald H. Brown

STATION 30 DATE 1/30/1998 LATITUDE 24.499° N

LONGITUDE 29.433° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.2 37.440 37.446 2 22.483 22.482 25.937 216.6 2 218.7 6 -6.8 0.00 2 0.00 2 4 0.30 2 1.99 2 1.16 2 0.17 2 9 316.5 349.3 2 2097.5 2 8.0622 2 2453 2 2446 68.0 2 3.6 2

35 2 46.8 37.420 37.422 2 22.316 22.307 25.975 216.5 2 217.0 2 -4.4 0.00 2 0.00 2 4 0.30 2 2.02 6 1.17 6 0.18 6 9 317.5 348.2 2 2098.8 6 8.0604 2 2449 2 2446 67.3 2 3.8 2

34 2 98.7 37.403 37.404 2 22.267 22.247 25.982 216.9 2 218.2 2 -5.3 0.00 2 0.00 2 4 0.30 2 2.01 2 1.16 2 0.17 2 9 319.5 349.6 2 2097.6 2 8.0582 2 2443 2 2443 67.6 2 3.8 2

33 2 148.3 37.035 37.029 2 20.238 20.210 26.267 207.7 2 210.7 2 10.6 0.02 2 0.49 2 4 0.30 2 2.24 2 1.28 2 0.15 2 9 361.9 365.2 2 2108.9 2 8.0135 2 2425 2 2421 59.0 2 4.3 2

32 2 202.5 36.652 36.653 2 18.313 18.277 26.478 201.3 2 202.8 2 27.0 0.00 2 3.22 2 4 0.90 2 2.34 2 1.31 2 0.06 2 9 393.1 367.3 2 2109.6 2 7.9796 2 2399 2 2396 53.9 2 6.5 2

31 2 222.1 36.575 36.575 2 17.953 17.915 26.511 201.1 2 202.3 2 29.2 0.00 2 3.90 2 4 1.00 2 2.38 2 1.32 2 0.04 2 9 401.7 369.8 2 2108.8 2 7.9737 2 2397 2 2391 50.8 2 9

30 2 248.3 36.510 36.514 2 17.586 17.544 26.553 195.7 2 198.6 2 34.7 0.00 2 4.78 2 4 1.30 2 2.35 2 1.30 2 0.03 2 9 418.4 379.4 6 2115.2 2 7.9580 2 2391 2 2387 54.6 2 8.3 2

29 2 272.0 36.454 36.447 2 17.236 17.190 26.597 200.7 2 195.1 2 39.8 0.00 2 5.85 2 4 1.40 2 2.40 2 1.31 2 0.03 2 9 9 2120.4 2 7.9420 2 2387 2 2383 9 9

28 2 299.0 36.318 36.318 2 16.433 16.384 26.685 197.7 2 192.8 2 46.0 0.00 2 7.32 2 4 2.00 2 2.37 6 1.29 6 0.03 6 9 453.9 392.7 2 2127.1 2 7.9218 2 2382 2 2377 48.0 2 9

27 2 349.3 36.145 36.156 2 15.390 15.335 26.793 187.4 2 190.1 2 53.9 0.00 2 9.08 2 4 2.60 2 2.34 2 1.26 2 0.03 2 9 483.0 400.3 2 2131.6 2 7.8946 2 2372 2 2365 9 9

26 2 400.7 35.996 35.990 2 14.441 14.381 26.889 184.3 2 186.3 2 62.7 0.00 2 11.22 2 4 3.50 2 2.27 2 1.20 2 0.03 2 9 519.3 413.8 2 2140.2 2 7.8632 2 2363 2 2356 46.3 2 9

25 2 476.6 35.827 35.816 2 13.367 13.299 26.988 196.6 2 194.3 2 60.5 0.00 2 12.40 2 4 4.20 2 2.24 2 1.18 2 0.04 2 9 9 2141.3 2 7.8479 2 2356 2 2348 44.7 2 9

24 2 551.5 35.666 35.659 2 12.184 12.110 27.100 189.7 2 184.8 2 76.6 0.00 2 15.23 2 4 5.70 2 1.90 2 0.97 2 0.02 2 9 605.1 439.0 2 2152.0 2 7.8073 2 2341 2 2338 9 9

23 2 626.4 35.546 35.542 2 11.212 11.132 27.192 175.5 2 167.7 2 99.4 0.00 2 18.75 2 4 7.80 2 1.30 2 0.67 2 0.02 2 9 9 2168.6 2 7.7602 2 2341 2 2332 42.9 2 21.1 2

22 2 700.4 35.399 35.399 2 9.915 9.832 27.307 151.7 2 143.6 2 131.4 0.00 2 23.53 2 4 11.60 2 0.52 2 0.26 2 0.00 2 9 791.2 522.1 2 2187.9 2 7.6993 2 2333 2 2325 9 9

21 2 771.1 35.351 35.352 2 9.311 9.222 27.372 145.2 2 144.8 2 134.0 0.00 2 24.22 2 4 13.00 2 0.39 2 0.18 2 0.00 2 9 9 2193.6 2 7.6901 2 2332 2 2327 41.6 2 9

20 2 848.8 35.266 35.267 2 8.383 8.291 27.453 144.9 2 144.1 2 140.7 0.00 2 25.59 2 4 15.30 2 0.20 2 0.10 2 0.00 2 9 862.7 533.2 2 2200.5 2 7.6690 2 2335 2 2325 9 9

19 2 922.6 35.234 35.237 2 7.860 7.763 27.508 148.5 2 151.3 2 137.0 0.00 2 25.78 2 4 16.30 2 0.14 6 0.08 6 0.00 6 9 9 2198.9 2 7.6705 2 2327 2 2324 41.7 2 9

18 2 1000.2 35.176 35.171 2 7.094 6.994 27.573 157.5 2 160.4 2 133.2 0.00 2 25.88 2 4 17.80 2 0.08 2 0.04 2 0.00 2 9 872.6 509.1 6 2200.1 6 7.6679 2 2332 2 2323 9 9

17 2 1201.9 35.195 35.196 2 6.367 6.252 27.690 179.8 2 182.2 2 116.4 0.00 2 23.83 2 4 17.90 2 0.05 2 0.03 2 0.00 2 9 826.4 465.3 2 2194.8 2 7.6887 2 2332 2 2327 41.7 2 25.9 2

16 2 1399.6 35.202 35.202 2 5.778 5.648 27.773 199.9 2 200.8 2 102.1 0.00 2 22.27 2 4 18.10 2 0.03 2 0.02 2 0.00 2 9 783.4 428.4 2 2188.7 2 7.7078 2 2331 2 2329 9 9

15 2 1600.0 35.152 35.153 2 5.120 4.977 27.815 216.2 2 215.8 2 92.1 0.00 2 21.58 2 4 19.10 2 0.01 2 0.00 2 0.00 2 9 764.6 405.1 2 2184.4 2 7.7169 2 2335 2 2328 41.6 2 9

14 2 1799.6 35.113 35.113 2 4.552 4.396 27.850 229.5 2 226.0 2 86.3 0.00 2 21.19 2 4 21.00 2 0.01 2 0.00 2 0.00 2 9 752.9 387.9 2 2182.4 2 7.7237 2 2336 2 2329 9 9

13 2 2001.3 35.070 35.069 2 4.092 3.923 27.867 236.5 2 235.7 2 80.4 0.00 2 20.71 3 4 22.60 2 0.00 2 0.00 2 0.00 2 9 741.5 373.4 2 2180.4 2 7.7290 2 5 2329 41.5 2 9

12 2 2251.4 35.024 35.024 2 3.600 3.414 27.883 244.6 2 244.6 2 75.6 0.00 2 20.71 2 4 25.10 2 0.00 2 0.00 2 0.00 2 9 738.8 363.2 2 2179.4 2 7.7321 2 9 2329 9 9

11 2 2500.8 34.988 34.988 2 3.228 3.024 27.892 248.9 2 247.6 2 75.8 0.00 2 20.51 2 4 28.50 2 0.00 2 0.00 2 0.00 2 9 739.5 356.8 2 2181.8 2 7.7335 2 2341 2 2332 41.5 2 22.8 2

10 2 2749.4 34.961 34.961 2 2.947 2.723 27.898 250.2 2 251.0 2 74.9 0.00 2 20.71 2 4 31.60 2 0.00 2 0.00 2 0.00 2 9 741.2 352.5 2 2185.6 2 7.7336 2 9 2336 9 9

9 2 3000.1 34.939 34.939 2 2.724 2.479 27.903 250.4 2 249.2 2 78.7 0.00 2 21.00 2 4 35.30 2 0.00 2 0.00 2 0.00 2 9 749.0 352.2 2 2189.8 2 7.7315 2 2347 2 2339 41.5 2 9

8 2 3283.5 34.926 34.925 2 2.598 2.326 27.907 249.9 2 248.6 2 80.6 0.00 2 21.20 2 4 38.10 2 0.00 2 0.00 2 -0.01 2 9 744.1 347.3 2 2192.8 2 7.7311 2 9 2342 9 9

7 2 3700.5 34.910 34.910 2 2.470 2.156 27.911 248.7 2 248.6 2 82.1 0.00 2 21.49 2 4 41.60 2 0.00 2 0.00 2 -0.01 2 9 746.7 346.1 2 2195.9 2 7.7287 2 9 2344 41.7 2 23.6 2

6 2 4000.8 34.901 34.900 2 2.414 2.068 27.914 248.1 2 248.3 2 83.2 0.00 2 22.17 3 4 43.90 2 0.00 2 0.00 2 0.00 2 9 757.8 350.3 2 2196.9 2 7.7289 2 9 2345 9 9

5 2 4299.8 34.894 34.894 2 2.385 2.005 27.915 247.6 2 248.5 2 83.5 0.00 2 22.57 3 4 45.40 2 0.00 2 0.00 2 0.00 2 9 750.6 346.2 2 2198.5 2 7.7278 2 2357 2 2346 41.4 2 9

4 3 4699.7 34.889 34.888 2 2.383 1.955 27.918 248.3 2 248.9 2 83.5 0.00 2 22.66 3 4 46.70 2 0.00 2 0.00 2 0.00 2 9 752.8 347.1 2 2199.4 2 7.7280 2 9 2348 41.5 2 9

3 2 4999.5 34.886 34.886 2 2.400 1.934 27.920 249.1 2 248.9 2 83.7 0.00 2 22.66 3 4 47.40 2 0.00 2 0.00 2 0.00 2 9 754.0 347.9 2 2200.2 2 7.7257 2 9 2347 41.7 2 9

2 2 5297.6 34.886 34.885 2 2.433 1.928 27.923 249.7 2 249.9 2 82.8 0.00 2 22.18 2 4 47.50 2 0.00 2 0.00 2 0.00 2 9 755.8 349.4 2 2199.2 2 7.7265 2 9 2347 41.6 2 9

1 2 5645.1 34.884 34.886 2 2.471 1.918 27.925 250.6 2 249.7 2 83.1 0.00 6 22.66 3 4 48.20 6 0.00 6 0.00 6 0.00 6 9 758.5 351.2 3 2199.0 2 7.7245 2 2355 2 2346 41.9 2 24.4 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

99
A5R

NOAA Ship Ronald H. Brown

STATION 31 DATE 1/30/1998 LATITUDE 24.500° N

LONGITUDE 30.267° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.2 37.550 37.550 2 22.954 22.953 25.885 214.9 2 215.7 2 -5.6 0.00 2 0.00 2 4 1.40 2 1.99 2 1.15 2 0.16 2 9 309.9 348.5 2 2100.9 2 8.0689 2 5 2456 9 9

35 2 40.3 37.548 37.549 2 22.916 22.908 25.898 212.2 2 215.6 2 -5.4 0.00 2 0.00 2 4 1.20 2 1.98 2 1.14 2 0.18 2 9 308.8 346.8 2 2101.5 6 8.0703 2 5 2458 9 9

34 2 91.5 37.542 37.542 2 22.895 22.876 25.906 211.8 2 215.5 2 -5.1 0.00 2 0.00 2 4 1.20 2 1.96 2 1.13 2 0.16 2 9 312.3 350.4 2 2102.5 2 8.0674 2 5 2456 9 9

33 2 140.3 37.029 37.013 2 20.260 20.234 26.256 204.5 2 209.2 2 12.0 0.03 2 0.68 2 4 1.20 2 2.25 2 1.28 2 0.15 2 9 365.8 369.6 2 2110.8 2 8.0062 2 2416 2 2418 9 9

32 2 201.4 36.662 36.663 2 18.380 18.345 26.469 198.0 2 202.9 2 26.6 0.01 2 3.12 2 4 1.60 2 2.32 2 1.31 2 0.06 2 9 395.2 370.0 2 2110.3 2 7.9813 2 5 2398 9 9

31 2 225.0 36.561 36.551 2 17.877 17.838 26.519 198.5 2 202.4 2 29.5 0.01 2 4.20 2 4 1.70 2 9 9 9 9 9 9 9 9 9 9

30 2 250.7 36.479 36.475 2 17.465 17.422 26.559 199.9 2 202.5 2 31.4 0.01 2 4.78 2 4 2.00 2 2.37 6 1.32 6 0.04 6 9 415.5 374.8 2 2111.9 2 7.9614 2 2383 2 2386 9 9

29 2 260.5 36.456 36.456 2 17.323 17.279 26.576 200.3 2 204.1 2 30.4 9 9 9 9 9 9 9 9 9 9 9 9 9 9

28 2 299.4 36.360 36.357 2 16.794 16.744 26.633 200.0 2 199.2 2 37.9 0.01 2 6.05 2 4 2.20 2 2.39 2 1.32 2 0.03 2 9 440.8 387.0 2 2117.4 2 7.9425 2 2376 2 2379 9 9

27 2 352.4 36.221 36.222 2 15.965 15.909 26.723 198.1 2 199.0 2 42.2 0.00 2 7.51 2 4 2.70 2 9 9 9 9 9 9 9 9 9 9

26 2 400.4 36.129 36.119 2 15.389 15.326 26.785 196.4 2 196.8 2 47.3 0.01 2 8.59 2 4 3.10 2 2.34 2 1.27 2 0.03 2 9 473.3 392.0 2 2126.7 2 7.9083 2 2364 2 2368 9 9

25 2 450.8 35.993 35.985 2 14.480 14.412 26.882 198.8 2 196.6 2 52.2 0.00 2 10.05 2 4 3.80 2 9 9 9 9 9 9 9 9 9 9

24 2 501.4 35.839 35.842 2 13.482 13.410 26.975 195.6 2 194.9 2 59.3 0.00 2 11.91 2 4 4.60 2 2.29 2 1.19 2 0.03 2 9 539.7 413.0 2 2140.5 2 7.8508 2 2347 2 2349 9 9

23 2 551.3 35.721 35.719 2 12.630 12.554 27.057 189.7 2 186.7 2 72.2 0.00 2 14.06 2 4 5.40 2 9 9 9 9 9 9 9 9 9 9

22 2 601.7 35.623 35.618 2 11.865 11.785 27.130 186.6 2 181.6 2 81.7 0.00 2 16.01 2 4 6.30 2 9 9 9 9 9 2155.1 2 7.8013 2 2336 2 2338 9 9

21 2 698.9 35.459 35.460 2 10.294 10.209 27.290 165.9 2 159.6 2 113.0 0.00 2 20.70 2 4 10.20 2 0.85 2 0.41 2 0.01 2 9 738.1 494.2 2 2177.6 2 7.7322 2 2332 2 2329 9 9

20 2 800.8 35.335 35.335 2 9.085 8.994 27.397 147.3 2 146.8 2 133.5 0.00 2 24.32 2 4 13.90 2 9 9 9 9 9 9 9 9 9 9

19 2 901.2 35.217 35.215 2 7.874 7.779 27.492 146.8 2 147.8 2 140.5 0.00 2 26.08 2 4 16.90 2 9 9 9 9 9 9 9 9 9 9

18 2 1000.3 35.141 35.142 2 6.952 6.853 27.564 154.8 2 159.1 2 135.5 0.00 2 26.37 2 4 18.60 2 0.06 2 0.03 2 0.00 2 9 885.5 513.3 2 2200.6 6 7.6553 2 2325 2 2319 9 9

17 2 1102.7 35.134 35.133 2 6.456 6.350 27.627 167.9 2 170.8 2 127.3 0.00 2 25.39 2 4 18.70 2 9 9 9 9 9 9 9 9 9 9

16 2 1300.6 35.177 35.175 2 6.004 5.882 27.723 189.7 2 191.7 2 109.6 0.00 2 23.44 2 4 18.10 2 9 9 9 9 9 9 9 9 9 9

15 2 1501.1 35.171 35.171 2 5.409 5.272 27.795 208.8 2 208.9 2 96.8 0.00 2 22.17 2 4 18.60 2 9 9 9 9 9 2185.0 2 7.7127 2 2332 2 2327 9 9

14 2 1700.1 35.129 35.129 2 4.768 4.619 27.838 224.1 2 223.6 2 87.0 0.00 2 21.39 2 4 20.30 2 9 9 9 9 9 9 9 9 9 9

13 2 1897.7 35.086 35.086 2 4.279 4.117 27.859 233.1 2 231.8 2 82.7 0.00 2 21.10 2 4 22.00 2 0.02 2 0.01 2 0.00 2 9 9 9 9 9 9 9

12 2 2098.1 35.048 35.047 2 3.845 3.670 27.876 239.9 2 240.3 2 77.8 0.00 2 20.90 2 4 23.80 2 0.00 2 0.00 2 0.00 2 9 739.4 367.7 2 2176.8 2 7.7320 2 2330 2 2326 9 9

11 2 2301.3 35.011 35.011 2 3.475 3.286 27.885 244.1 2 244.8 2 76.4 0.00 2 20.80 2 4 26.00 2 9 9 9 9 9 9 9 9 9 9

10 2 2501.6 34.988 34.993 2 3.232 3.027 27.891 247.0 2 246.2 2 77.1 0.00 2 20.71 2 4 27.40 2 9 9 9 9 9 2179.8 2 7.7322 2 2334 2 2329 9 9

9 2 2700.6 34.968 34.968 2 3.023 2.802 27.897 248.5 2 248.8 2 76.4 0.00 2 20.90 2 4 30.80 2 9 9 9 9 9 9 9 9 9 9

8 2 2899.2 34.949 34.948 2 2.827 2.590 27.901 248.5 2 248.7 2 78.3 0.00 2 21.00 2 4 34.00 2 9 9 9 9 744.9 351.9 2 2186.0 2 7.7308 2 2342 2 2335 9 9

7 2 3297.4 34.923 34.923 2 2.579 2.306 27.907 248.8 2 248.4 2 81.0 0.00 2 21.49 2 4 39.10 2 9 9 9 9 9 9 9 9 9 9

6 2 3700.2 34.908 34.907 2 2.450 2.137 27.911 247.3 2 249.3 2 81.6 0.00 2 22.08 3 4 43.10 2 9 9 9 9 9 9 9 9 9 9

5 2 4099.6 34.897 34.897 2 2.389 2.032 27.914 247.1 2 248.7 2 83.1 0.00 2 22.27 3 4 45.40 2 9 9 9 9 754.6 348.1 2 2197.0 2 7.7282 2 5 2345 9 9

4 3 4475.4 34.891 34.891 2 2.377 1.976 27.917 246.4 2 248.3 2 84.0 0.00 2 22.47 3 4 46.80 2 9 9 9 9 9 9 9 9 9 9

3 2 4900.6 34.886 34.886 2 2.390 1.937 27.919 248.2 2 249.2 2 83.4 0.00 2 22.57 3 4 47.80 2 9 9 9 9 9 9 9 9 9 9

2 2 5300.0 34.885 34.885 2 2.433 1.927 27.923 249.1 2 249.8 2 82.9 0.00 2 22.76 3 4 48.20 2 9 9 9 9 9 9 9 9 9 9

1 2 5715.3 34.884 34.885 2 2.484 1.921 27.926 249.4 2 249.0 2 83.7 0.00 6 22.47 6 4 48.10 6 9 9 9 9 708.9 327.3 3 2199.2 2 7.7234 2 2357 2 2345 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

100
A5R

NOAA Ship Ronald H. Brown

STATION 32 DATE 1/31/1998 LATITUDE 24.500° N

LONGITUDE 31.084° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.8 37.539 37.539 2 22.709 22.708 25.948 211.9 2 216.6 2 -5.6 0.00 2 0.00 2 4 0.20 3 3.14 4 1.16 2 0.16 2 9 324.4 361.2 2 2101.8 6 8.0637 2 2450 2 2453 9 9

35 2 48.4 37.535 37.536 2 22.709 22.699 25.950 213.5 2 216.9 2 -5.9 0.00 2 0.00 2 4 0.10 3 2.01 2 1.16 2 0.17 2 9 9 9 9 9 9 9

34 2 100.9 37.532 37.499 2 22.693 22.672 25.958 213.9 2 216.3 2 -5.1 0.00 2 0.10 2 4 0.00 3 2.03 6 1.17 6 0.16 6 9 9 9 9 9 9 9

33 2 143.0 37.053 37.033 2 20.411 20.384 26.234 212.1 2 211.3 2 9.3 0.04 2 0.49 2 4 0.00 3 2.25 2 1.28 2 0.16 2 9 9 9 8.0131 2 2418 2 9 9

32 2 179.5 36.813 36.804 2 19.136 19.103 26.390 201.2 2 205.7 2 20.4 0.01 2 1.76 2 4 0.00 3 2.33 2 1.32 2 0.10 2 9 9 9 9 9 9 9

31 2 223.0 36.569 36.570 2 17.937 17.898 26.510 198.2 2 204.4 2 27.2 0.00 2 4.00 2 4 0.20 3 2.39 2 1.33 2 0.04 2 9 9 9 9 2390 2 9 9

30 2 249.7 36.475 36.475 2 17.454 17.412 26.559 198.4 2 201.8 2 32.1 0.00 2 4.78 2 4 0.30 3 2.40 2 1.33 2 0.04 2 9 9 9 9 9 9 9

29 2 275.4 36.358 36.368 2 16.811 16.765 26.625 198.2 2 201.3 2 35.7 0.00 2 5.85 2 4 0.30 3 9 9 9 9 9 9 9 9 9 9

28 2 299.8 36.281 36.280 2 16.408 16.359 26.662 199.2 2 201.8 2 37.2 0.00 2 6.64 2 4 0.30 3 2.35 2 1.29 2 0.02 2 9 9 9 7.9325 2 2371 2 9 9

27 2 349.4 36.148 36.151 2 15.570 15.515 26.756 199.0 2 198.7 2 44.5 0.00 2 8.20 2 4 0.90 3 2.39 2 1.29 2 0.04 2 9 9 9 9 9 9 9

26 2 401.7 36.017 36.021 2 14.692 14.631 26.852 193.4 2 193.9 2 53.8 0.00 2 9.96 2 4 1.50 3 2.30 2 1.22 2 0.02 2 9 9 9 9 9 9 9

25 2 448.6 35.900 35.910 2 13.844 13.779 26.944 188.6 2 186.2 2 66.0 0.00 2 11.91 2 4 2.10 3 9 9 9 9 9 9 7.8489 2 2351 2 9 9

24 2 500.1 35.774 35.776 2 13.009 12.939 27.020 189.2 2 186.0 2 70.8 0.00 2 13.37 2 4 2.60 3 2.09 2 1.09 2 0.03 2 9 9 9 9 9 9 9

23 2 601.5 35.592 35.592 2 11.592 11.513 27.157 181.3 2 180.1 2 84.8 0.00 2 16.70 2 4 4.60 3 1.61 2 0.80 2 0.02 2 9 9 9 9 9 9 9

22 2 701.4 35.464 35.464 2 10.335 10.249 27.286 163.9 2 159.2 2 113.2 0.00 2 20.60 2 4 8.00 3 0.87 2 0.43 2 0.02 2 9 9 9 9 2333 2 9 9

21 2 752.7 35.361 35.366 2 9.502 9.414 27.348 145.0 2 142.7 2 134.9 0.00 2 23.83 2 4 10.80 3 0.45 2 0.21 2 0.00 2 9 9 9 9 9 9 9

20 2 850.2 35.208 35.209 2 8.137 8.046 27.444 132.1 2 134.6 2 151.9 0.00 2 27.15 2 4 14.90 3 0.14 6 0.06 6 0.00 6 9 9 9 9 9 9 9

19 2 949.8 35.140 35.142 2 7.318 7.222 27.512 142.8 2 143.5 2 148.6 0.00 2 27.35 2 4 16.80 3 0.08 2 0.04 2 -0.01 2 9 9 9 9 9 9 9

18 2 1048.6 35.131 35.130 2 6.890 6.786 27.566 157.4 2 155.1 2 140.0 0.00 2 26.57 2 4 17.30 3 0.06 2 0.03 2 0.00 2 9 9 9 7.6532 2 2326 2 9 9

17 2 1245.6 35.170 35.166 2 6.127 6.009 27.701 182.8 2 183.8 2 116.6 0.00 2 24.03 2 4 16.90 3 0.04 2 0.02 2 -0.01 2 9 9 9 9 9 9 9

16 2 1442.9 35.174 35.173 2 5.523 5.391 27.783 201.5 2 202.6 2 102.2 0.00 2 22.46 2 4 17.50 2 0.02 2 0.01 2 -0.01 2 9 9 9 9 9 9 9

15 2 1640.4 35.137 35.137 2 4.920 4.775 27.826 214.8 2 215.9 2 93.5 0.00 2 4 4 18.90 2 0.01 4 0.01 2 -0.01 2 9 9 9 9 9 9 9

14 2 1845.5 35.071 35.072 2 4.222 4.066 27.852 227.9 2 230.2 2 84.8 0.00 2 21.10 2 4 20.40 2 9 9 9 9 9 9 9 9 9 9

13 2 1992.5 35.047 35.048 2 3.940 3.774 27.864 233.4 2 234.8 2 82.5 0.00 2 20.81 2 4 21.70 2 9 9 9 9 9 9 7.7118 2 2330 2 9 9

12 2 2193.8 35.022 35.020 2 3.637 3.456 27.876 238.4 2 241.0 2 78.8 0.00 2 20.71 2 4 23.40 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

11 2 2452.5 34.991 34.990 2 3.267 3.067 27.890 246.0 2 246.0 2 77.0 0.00 2 20.51 2 4 26.80 2 9 9 9 9 9 9 9 9 9 9

10 2 2698.6 34.964 34.963 2 2.977 2.758 27.898 248.8 2 248.4 2 77.2 0.00 2 20.51 2 4 30.40 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

9 2 3101.1 34.935 34.934 2 2.696 2.441 27.904 249.1 2 249.4 2 78.9 0.00 2 21.20 2 4 35.40 2 9 9 9 9 9 9 7.7302 2 2344 2 9 9

8 2 3502.4 34.917 34.915 2 2.529 2.236 27.909 248.3 2 249.0 2 81.0 0.00 2 21.59 2 4 39.70 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

7 2 3900.7 34.903 34.902 2 2.436 2.101 27.912 247.8 2 248.7 2 82.5 0.00 2 21.98 2 4 42.50 2 9 9 9 9 9 9 9 9 9 9

6 2 4281.7 34.896 34.895 2 2.401 2.023 27.915 247.6 2 248.6 2 83.2 0.00 2 22.18 2 4 44.50 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

5 2 4698.8 34.889 34.889 2 2.395 1.967 27.918 247.4 2 249.3 2 83.0 0.00 2 22.18 2 4 46.00 2 9 9 9 9 9 9 7.7247 2 2352 2 9 9

4 2 5097.5 34.887 34.885 2 2.411 1.932 27.922 249.2 2 249.9 2 82.7 0.00 2 22.27 2 4 46.90 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

3 2 5497.5 34.884 34.883 2 2.448 1.916 27.924 249.6 2 250.0 2 82.8 0.00 2 22.27 2 4 47.30 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

2 9 6106.8 34.884 2 2.526 1.908 27.930 250.5 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 6107.5 34.883 34.882 2 2.526 1.908 27.930 250.5 2 250.2 6 82.6 0.00 6 22.27 6 4 47.70 6 0.00 6 0.00 6 -0.01 6 9 9 9 7.7201 2 2354 2 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

101
A5R

NOAA Ship Ronald H. Brown

STATION 33 DATE 1/31/1998 LATITUDE 24.500° N

LONGITUDE 31.916° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.2 37.566 37.565 2 23.078 23.077 25.860 214.1 2 215.5 2 -5.9 0.00 2 0.00 2 4 0.50 2 9 9 9 1.96 2 308.6 348.6 2 2100.3 2 8.0717 2 2459 2 2457 9 9

35 2 61.0 37.551 37.552 2 22.931 22.918 25.899 218.4 2 215.4 2 -5.2 0.00 2 0.00 2 4 0.50 2 9 9 9 1.91 6 310.1 348.2 2 2100.6 6 8.0698 2 2464 2 2456 9 9

34 2 110.5 37.516 37.513 2 22.767 22.744 25.926 217.6 2 216.1 2 -5.2 0.00 2 0.00 2 4 0.50 2 9 9 9 1.83 2 312.8 349.1 2 2101.3 2 8.0651 2 2454 2 2453 9 9

33 2 150.9 37.083 37.080 2 20.537 20.508 26.224 212.7 2 215.4 2 4.6 0.04 2 0.29 2 4 0.60 2 9 9 9 9 354.1 361.8 2 2107.1 2 8.0214 2 2431 2 2425 9 9

32 2 200.0 36.759 36.760 2 18.824 18.788 26.431 201.9 2 204.1 2 23.4 0.01 2 2.44 2 4 1.00 2 9 9 9 0.94 2 389.2 370.4 2 2111.8 2 7.9855 2 2406 2 2403 9 9

31 2 225.6 36.656 36.658 2 18.308 18.268 26.485 201.7 2 202.2 2 27.7 0.01 2 3.41 2 4 1.10 2 9 9 9 9 9 9 9 9 9 9

30 2 248.6 36.550 36.554 2 17.793 17.750 26.534 200.0 2 200.8 2 31.5 0.00 2 4.29 2 4 1.50 2 9 9 9 0.70 2 410.3 375.3 2 2112.1 2 7.9655 2 2395 2 2389 9 9

29 2 268.8 36.477 36.478 2 17.404 17.358 26.574 195.1 2 199.0 2 35.1 0.00 2 5.07 2 4 1.60 2 9 9 9 9 9 9 9 9 9 9

28 2 298.9 36.416 36.417 2 16.984 16.934 26.631 191.8 2 193.2 2 42.9 0.00 2 6.24 2 4 1.90 2 9 9 9 0.56 2 448.5 397.0 2 2123.6 2 7.9348 2 2389 2 2382 9 9

27 2 348.0 36.230 36.230 2 15.949 15.893 26.733 184.1 2 192.4 2 48.8 0.00 2 8.10 2 4 2.50 2 9 9 9 9 9 9 9 9 9 9

26 2 400.2 36.124 36.119 2 15.262 15.200 26.809 188.1 2 178.4 2 66.3 0.00 2 10.54 2 4 3.40 2 9 9 9 0.45 6 514.7 424.4 2 2140.9 2 7.8740 6 2370 2 2364 9 9

25 2 452.1 35.931 35.936 2 14.063 13.996 26.923 191.7 2 183.5 2 67.5 0.00 2 11.81 2 4 4.10 2 9 9 9 9 9 9 9 9 9 9

24 2 499.4 35.801 35.804 2 13.171 13.100 27.008 191.3 2 186.4 2 69.5 0.00 2 12.98 2 4 4.80 2 9 9 9 0.52 2 9 2144.6 2 7.8366 2 2354 2 2346 9 9

23 2 552.0 35.699 35.697 2 12.450 12.375 27.075 188.3 2 184.3 2 75.6 0.00 2 14.64 2 4 5.60 2 9 9 9 9 9 9 9 9 9 9

22 2 601.2 35.613 35.613 2 11.804 11.725 27.134 183.8 2 180.9 2 82.8 0.00 2 16.11 2 4 6.50 2 9 9 9 0.50 2 635.4 453.8 2 2156.4 2 7.7904 2 5 2334 9 9

21 2 699.2 35.475 35.483 2 10.511 10.425 27.265 162.6 2 162.1 2 109.2 0.00 2 20.11 2 4 9.60 2 9 9 9 9 9 9 9 9 9 9

20 2 800.5 35.304 35.307 2 8.977 8.887 27.389 145.2 2 141.7 2 139.3 0.00 2 25.00 2 4 14.20 2 9 9 9 0.11 2 853.0 541.4 2 2195.5 2 7.6778 2 5 2323 9 9

19 2 900.2 35.179 35.177 2 7.672 7.579 27.491 146.9 2 148.6 2 141.1 0.00 2 26.27 2 4 17.10 2 9 9 9 9 9 9 9 9 9 9

18 2 1049.0 35.110 35.111 2 6.599 6.498 27.588 164.8 2 166.0 2 131.1 0.00 2 25.78 2 4 18.60 2 9 9 9 9 884.6 504.9 2 2199.0 6 7.6632 2 5 2320 9 9

17 2 1252.0 35.132 35.131 2 5.917 5.801 27.697 192.7 2 190.9 2 111.1 0.00 2 23.64 2 4 18.20 2 9 9 9 0.07 2 9 9 9 9 9 9

16 2 1451.0 35.155 35.153 2 5.458 5.326 27.775 210.8 2 208.9 2 96.4 0.00 2 21.88 2 4 18.10 2 9 9 9 9 9 2183.8 2 7.7104 2 5 2324 9 9

15 2 1651.4 35.140 35.137 2 4.899 4.753 27.831 224.5 2 222.4 2 87.2 0.00 2 21.00 2 4 19.40 2 9 9 9 9 9 9 9 9 9 9

14 2 1851.4 35.090 35.090 2 4.334 4.176 27.856 232.4 2 232.0 2 82.1 0.00 2 20.80 2 4 21.10 2 9 9 9 9 9 9 9 9 9 9

13 2 2046.5 35.055 35.055 2 3.931 3.760 27.872 240.8 2 239.6 2 77.8 0.00 2 20.32 2 4 22.80 2 9 9 9 0.06 2 740.4 370.0 2 2177.5 2 7.7311 2 9 2326 9 9

12 2 2252.2 35.020 35.021 2 3.567 3.381 27.883 247.6 2 245.3 2 75.1 0.00 2 20.32 2 4 24.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2450.8 34.988 34.988 2 3.223 3.024 27.891 251.1 2 249.4 2 74.0 0.00 2 20.32 2 4 27.80 2 9 9 9 9 9 2179.1 2 7.7336 2 5 2329 9 9

10 2 2650.8 34.965 34.964 2 2.984 2.769 27.897 250.8 2 248.6 2 76.9 0.00 2 20.71 2 4 31.50 2 9 9 9 9 9 9 9 9 9 9

9 2 2851.7 34.947 34.946 2 2.811 2.579 27.900 252.1 2 249.0 2 78.1 0.00 2 20.90 2 4 34.40 2 9 9 9 0.02 2 9 9 9 9 9 9

8 2 3049.4 34.935 34.934 2 2.686 2.437 27.904 251.3 2 248.5 2 79.8 0.00 2 21.20 2 4 36.80 2 9 9 9 9 748.4 351.1 2 2189.8 2 7.7316 2 5 2339 9 9

7 3 3539.3 34.914 34.913 2 2.502 2.205 27.910 251.6 2 249.7 2 80.6 0.00 2 21.59 2 4 41.00 2 9 9 9 9 9 9 9 9 9 9

6 2 3948.8 34.903 34.903 2 2.437 2.096 27.912 248.4 2 249.2 2 82.0 0.00 2 21.88 2 4 42.90 2 9 9 9 9 755.4 349.7 2 2195.8 2 7.7277 2 5 2344 9 9

5 2 4348.5 34.894 34.893 2 2.395 2.009 27.915 248.6 2 248.8 2 83.2 0.00 2 21.88 2 4 44.70 2 9 9 9 0.01 2 9 9 9 9 9 9

4 2 4735.3 34.889 34.888 2 2.393 1.960 27.918 249.0 2 248.6 2 83.8 0.00 2 4 4 45.80 2 9 9 9 9 9 9 9 9 9 9

3 2 5099.0 34.886 34.884 2 2.408 1.929 27.921 248.1 2 249.3 2 83.4 0.00 2 21.98 2 4 46.50 2 9 9 9 9 9 9 9 9 9 9

2 2 5498.7 34.884 34.883 2 2.446 1.914 27.924 251.0 2 249.9 2 82.9 0.00 2 22.08 2 4 47.00 2 9 9 9 9 9 9 9 9 9 9

1 2 6043.5 34.882 34.883 2 2.511 1.902 27.929 251.3 2 250.7 6 82.2 0.00 6 22.17 6 4 47.30 6 9 9 9 0.03 6 770.1 357.7 2 2199.0 2 7.7225 2 5 2345 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

102
A5R

NOAA Ship Ronald H. Brown

STATION 34 DATE 1/31/1998 LATITUDE 24.500° N

LONGITUDE 32.733° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.9 37.544 37.545 2 23.279 23.278 25.785 221.3 2 243.8 2 -34.9 0.00 2 0.00 2 4 1.00 2 1.93 2 1.12 2 0.16 2 9 302.9 345.0 2 2096.8 2 9 2452 2 71.2 2 9

35 2 56.5 37.565 37.566 2 23.214 23.202 25.827 219.7 2 214.8 2 -5.6 0.00 2 0.00 2 4 0.90 2 1.93 2 1.12 2 0.18 2 9 9 2099.1 2 8.0747 2 5 2458 71.3 2 9

34 2 105.5 37.559 37.547 2 23.041 23.019 25.878 220.3 2 215.4 2 -5.6 0.00 2 0.00 2 4 0.70 2 1.96 6 1.14 6 0.17 6 9 314.5 354.8 2 2101.2 2 8.0567 2 2451 2 2447 70.4 2 9

33 2 156.0 36.984 36.977 2 20.049 20.020 26.280 214.9 2 215.3 2 6.8 0.03 2 0.68 2 4 0.60 2 2.26 2 1.29 2 0.15 2 9 371.6 372.2 2 2110.4 2 7.9989 2 2414 2 2412 58.7 2 9

32 2 206.2 36.709 36.698 2 18.543 18.506 26.465 203.7 2 209.7 2 19.1 0.01 2 3.12 2 4 1.00 2 2.35 2 1.32 2 0.09 2 9 399.1 376.4 2 2113.4 2 7.9743 2 2395 2 2397 53.9 2 9

31 2 228.6 36.538 36.540 2 17.753 17.714 26.532 202.6 2 200.9 2 31.6 0.00 2 4.59 2 4 1.20 2 9 9 9 9 414.3 379.1 2 2113.7 2 7.9613 2 2386 2 2388 51.3 2 9

30 2 256.2 36.385 36.372 2 16.977 16.934 26.604 204.7 2 199.4 2 36.8 0.00 2 5.56 2 4 1.60 2 2.38 2 1.31 2 0.04 2 9 424.4 375.4 2 2113.0 2 7.9473 2 2376 2 2378 54.4 2 9

29 2 280.4 36.324 36.319 2 16.614 16.568 26.645 204.3 2 201.5 2 36.5 0.00 2 6.44 2 4 1.70 2 9 9 9 9 439.2 382.7 2 2117.2 2 7.9290 2 2374 2 2371 49.9 2 9

28 2 316.1 36.238 36.234 2 16.103 16.052 26.701 204.2 2 199.9 2 40.6 0.00 2 7.32 2 4 1.90 2 2.35 2 1.28 2 0.03 2 9 449.5 383.5 2 2118.5 2 7.9273 2 2371 2 2371 9 9

27 2 366.6 36.108 36.105 2 15.287 15.230 26.789 201.8 2 199.2 2 45.4 0.00 2 8.69 2 4 4 2.35 2 1.26 2 0.04 2 9 476.0 392.8 2 2124.2 2 7.9008 2 2362 2 2360 46.9 2 9

26 2 415.4 35.956 35.961 2 14.309 14.247 26.888 202.2 2 197.1 2 52.6 0.00 2 10.35 2 4 4 2.30 2 1.22 2 0.03 2 9 507.7 402.0 2 2130.6 2 7.8792 2 2355 2 2354 9 9

25 2 465.9 35.825 35.825 2 13.403 13.336 26.978 197.3 2 195.6 2 59.0 0.00 2 12.49 2 4 4.30 2 2.14 2 1.11 2 0.03 2 9 554.1 422.5 2 2140.7 2 7.8428 2 2348 2 2345 45.4 2 9

24 2 513.6 35.683 35.685 2 12.329 12.259 27.084 191.8 2 189.2 2 71.4 0.00 2 15.13 2 4 5.50 2 1.82 2 0.93 2 0.02 2 9 602.2 439.0 2 2152.5 2 7.8057 2 2339 2 2338 9 9

23 2 600.7 35.563 35.566 2 11.362 11.285 27.177 183.1 2 180.4 2 85.8 0.00 2 17.57 2 4 7.20 2 1.42 2 0.71 2 0.02 2 9 658.2 460.8 2 2162.7 2 7.7719 2 2334 2 2332 44.6 2 9

22 2 701.1 35.444 35.444 2 10.179 10.094 27.297 170.4 2 173.1 2 100.3 0.00 2 21.09 2 4 10.20 2 0.75 2 0.36 2 0.01 2 9 736.6 490.6 2 2179.1 2 7.7263 2 2331 2 2328 9 9

21 2 801.1 35.352 35.349 2 9.202 9.110 27.391 155.7 2 157.8 2 121.7 0.00 2 23.44 2 4 13.20 2 0.37 6 0.17 6 0.00 6 9 802.4 513.0 2 2189.4 2 7.6945 2 2331 2 2324 43.3 2 9

20 2 900.3 35.227 35.232 2 7.930 7.835 27.492 154.2 2 152.1 2 135.8 0.00 2 24.90 2 4 15.90 2 0.15 2 0.07 2 0.01 2 9 840.9 508.7 2 2195.7 2 7.6724 2 2328 2 2321 9 9

19 2 1001.0 35.158 35.155 2 7.111 7.011 27.556 162.8 2 162.0 2 131.5 0.00 2 25.39 2 4 17.80 2 0.07 2 0.04 2 0.00 2 9 862.3 503.2 2 2201.9 2 7.6703 2 2327 2 2326 42.5 2 9

18 2 1201.2 35.164 35.163 2 6.137 6.024 27.694 188.6 2 188.5 2 111.8 0.00 2 23.34 2 4 17.70 2 0.04 2 0.02 2 0.01 2 9 814.5 453.4 2 2194.4 2 7.6927 2 2328 2 2328 9 9

17 2 1400.1 35.160 35.159 2 5.570 5.442 27.765 206.0 2 205.1 2 99.4 0.00 2 22.07 2 4 17.70 2 0.02 2 0.01 2 -0.01 2 9 779.9 422.1 2 2189.1 2 7.7073 2 2328 2 2329 41.9 2 9

16 2 1601.1 35.127 35.126 2 4.953 4.812 27.814 220.6 2 219.8 2 89.4 0.00 2 21.19 2 4 18.80 2 0.01 2 0.00 2 0.00 2 9 761.8 400.0 2 2183.7 2 7.7190 2 2328 2 2328 9 9

15 2 1801.2 35.088 35.088 2 4.393 4.239 27.847 231.3 2 229.6 2 84.0 0.00 2 20.71 2 4 20.70 2 0.00 2 0.00 2 0.00 2 9 755.9 386.4 2 2181.7 2 4 2329 2 42.2 2 9

14 2 2001.7 35.060 35.060 2 4.021 3.853 27.866 236.9 2 236.1 2 80.5 0.00 2 20.61 2 4 22.60 2 0.00 2 0.00 2 0.00 2 9 746.4 374.5 6 2180.9 2 7.7287 2 2330 2 2329 9 9

13 2 2198.3 35.023 35.022 2 3.593 3.412 27.881 244.5 2 243.9 6 76.3 0.00 2 20.32 2 4 24.80 2 0.00 2 0.00 2 -0.01 2 9 9 2180.8 2 7.7318 2 2331 2 2330 41.5 2 9

12 2 2401.3 34.998 34.998 2 3.346 3.149 27.888 248.1 2 246.0 2 76.3 0.00 2 20.32 2 4 27.00 2 9 9 9 9 741.1 359.6 6 9 7.7308 2 9 9 9

11 2 2601.1 34.973 34.972 2 3.072 2.861 27.895 248.4 2 247.6 2 77.1 0.00 2 20.41 2 4 30.60 2 9 9 9 9 9 2185.8 2 7.7316 2 2336 2 2335 41.7 2 9

10 2 2799.1 34.954 34.955 2 2.886 2.658 27.899 249.7 2 247.9 2 78.5 0.00 2 20.90 2 4 33.20 2 0.00 2 0.00 2 -0.01 2 9 750.0 355.4 2 2189.7 2 7.7309 2 9 2339 9 9

9 2 3000.3 34.940 34.940 2 2.740 2.495 27.903 249.3 2 248.3 2 79.5 0.00 2 21.10 2 4 35.80 2 9 9 9 9 752.7 354.0 2 2191.4 2 7.7299 2 2342 2 2340 41.9 2 9

8 2 3384.8 34.920 34.920 2 2.554 2.273 27.908 247.9 2 247.2 2 82.5 0.00 2 21.39 2 4 39.70 2 0.00 2 0.00 2 0.00 2 9 750.0 349.2 2 2195.3 2 7.7313 2 9 2345 9 9

7 2 3800.8 34.905 34.904 2 2.438 2.114 27.912 248.0 2 248.2 2 82.9 0.00 2 21.69 2 4 42.60 2 9 9 9 9 750.7 347.3 2 2195.7 2 7.7283 2 2348 2 2344 41.3 2 9

6 2 4201.5 34.896 34.897 2 2.398 2.029 27.914 248.2 2 248.7 2 83.1 0.00 2 21.88 2 4 44.40 2 0.00 2 0.00 2 0.00 2 9 756.9 349.5 2 2197.2 2 7.7226 2 9 2343 9 9

5 2 4589.4 34.891 34.890 2 2.390 1.975 27.917 248.5 2 249.0 2 83.3 0.00 2 21.98 2 4 45.80 2 9 9 9 9 757.1 349.3 2 2198.7 2 7.7228 2 2351 2 2345 41.3 2 9

4 2 5001.2 34.887 34.886 2 2.400 1.934 27.921 249.9 2 249.2 2 83.4 0.00 2 21.98 2 4 46.70 2 0.00 2 0.00 2 0.00 2 9 760.2 350.9 2 2199.1 2 7.7250 2 9 2346 41.9 2 9

3 2 5394.5 34.884 34.883 2 2.423 1.905 27.924 253.0 2 250.3 2 82.6 0.00 2 22.17 2 4 47.40 2 9 9 9 9 763.7 352.9 2 2198.5 2 7.7213 2 5 2344 41.2 2 9

2 2 5799.8 34.881 34.880 2 2.464 1.891 27.927 253.6 2 251.1 2 81.9 0.00 2 22.17 2 4 48.00 2 0.00 2 0.00 2 0.00 2 9 764.2 353.9 2 2197.8 2 7.7233 2 9 2344 41.4 2 9

1 2 6276.0 34.880 34.882 2 2.526 1.884 27.931 256.0 2 252.0 2 81.1 0.00 6 22.17 6 4 48.30 6 0.00 2 0.00 2 0.00 2 9 766.8 356.2 2 2197.7 2 7.7205 2 2356 3 2342 41.9 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

103
A5R

NOAA Ship Ronald H. Brown

STATION 35 DATE 2/1/1998 LATITUDE 24.498° N

LONGITUDE 33.567° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 37.386 37.386 2 22.664 22.663 25.844 217.9 2 219.0 2 -7.6 0.00 2 0.00 2 4 0.70 2 2.04 2 1.17 2 0.16 2 9 305.6 339.7 2 2088.8 2 8.0701 2 2440 2 2442 9 9

35 2 39.2 37.390 37.392 2 22.685 22.677 25.846 218.8 2 216.1 2 -4.8 0.00 2 0.00 2 4 0.60 2 9 9 9 9 305.4 339.8 2 2089.9 6 8.0704 2 2440 2 2443 9 9

34 2 78.1 37.316 37.243 2 22.343 22.327 25.891 218.4 2 218.4 2 -5.6 0.00 2 0.00 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

33 2 120.0 36.812 36.829 2 19.421 19.399 26.310 210.8 2 211.3 2 13.6 0.02 2 0.59 2 4 0.70 2 2.31 6 1.32 6 0.14 6 9 361.3 352.9 2 2099.0 2 8.0097 2 2404 2 2406 9 9

32 2 158.6 36.670 36.670 2 18.671 18.643 26.399 204.3 2 205.7 2 22.6 0.01 2 2.24 2 4 0.80 2 9 9 9 9 9 9 9 9 9 9

31 2 202.1 36.549 36.553 2 18.046 18.011 26.467 202.3 2 204.6 2 26.5 0.01 2 3.80 2 4 1.20 2 2.33 2 1.30 2 0.04 2 9 390.8 361.1 2 2103.4 2 7.9748 2 2385 2 2385 9 9

30 2 221.8 36.485 36.493 2 17.682 17.644 26.509 201.3 2 202.9 2 29.9 0.00 2 4.49 2 4 1.50 2 9 9 9 9 9 9 9 9 9 9

29 2 250.1 36.410 36.409 2 17.241 17.199 26.561 200.5 2 201.3 2 33.7 0.00 2 5.46 2 4 1.60 2 9 9 9 9 417.6 373.4 2 2110.4 2 7.9531 2 2379 2 2379 9 9

28 2 275.3 36.358 36.355 2 16.933 16.887 26.596 200.0 2 200.7 2 35.7 0.00 2 6.05 2 4 1.90 2 9 9 9 9 9 9 9 9 9 9

27 2 301.5 36.286 36.291 2 16.467 16.418 26.652 199.2 2 199.4 2 39.3 0.00 2 6.73 2 4 2.00 2 2.32 2 1.28 2 0.03 2 9 439.0 380.4 2 2114.5 2 7.9319 2 2372 2 2369 9 9

26 2 350.1 36.173 36.185 2 15.757 15.701 26.732 196.8 2 197.9 2 44.3 0.01 2 8.00 2 4 2.50 2 9 9 9 9 9 9 9 9 9 9

25 2 399.1 36.053 36.059 2 15.029 14.968 26.806 193.6 2 193.9 2 52.1 0.00 2 9.47 2 4 2.90 2 2.25 2 1.20 2 0.03 2 9 486.9 397.4 2 2128.2 2 7.8914 2 2358 2 2359 9 9

24 2 500.7 35.753 35.757 2 12.965 12.895 27.012 186.3 2 184.3 2 72.7 0.00 2 13.67 2 4 5.20 2 9 9 9 9 576.8 431.9 2 2143.7 2 7.8276 2 2345 2 2340 9 9

23 2 599.8 35.588 35.588 2 11.651 11.572 27.143 177.7 2 176.1 2 88.5 0.00 2 16.60 2 4 7.10 2 1.48 2 0.75 2 0.02 2 9 636.3 450.9 2 2155.3 2 7.7854 2 2336 2 2330 9 9

22 2 699.8 35.448 35.453 2 10.315 10.230 27.277 162.7 2 163.1 2 109.4 0.00 2 20.02 2 4 9.80 2 9 9 9 9 9 9 9 9 9 9

21 2 799.2 35.353 35.351 2 9.309 9.217 27.375 154.4 2 154.1 2 124.7 0.00 2 22.85 2 4 12.70 2 0.40 2 0.19 2 0.00 2 9 789.8 507.6 2 2186.4 2 7.7043 2 2329 2 2325 9 9

20 2 899.0 35.256 35.260 2 8.337 8.239 27.454 150.0 2 151.0 2 134.2 0.00 2 24.80 2 4 15.20 2 9 9 9 9 9 9 9 9 9 9

19 2 1051.1 35.170 35.169 2 7.004 6.899 27.582 167.4 2 167.3 2 126.9 0.00 2 24.90 2 4 17.40 2 0.09 2 0.04 2 0.00 2 9 850.8 493.9 2 2195.6 6 7.6739 2 2326 2 2321 9 9

18 2 1250.3 35.203 35.204 2 6.267 6.147 27.710 190.6 2 189.1 2 110.3 0.00 2 22.95 2 4 17.50 2 0.06 6 0.03 6 -0.01 6 9 9 9 9 9 9 9

17 2 1449.3 35.196 35.197 2 5.617 5.483 27.789 206.8 2 208.6 6 95.5 0.00 2 21.58 2 4 17.80 2 0.04 2 0.02 2 0.00 2 9 9 9 9 9 9 9

16 9 1642.9 35.123 35.126 2 4.797 4.653 27.829 220.9 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

15 2 1848.1 35.078 35.078 2 4.210 4.054 27.859 231.5 2 234.6 2 80.4 0.00 2 20.51 2 4 21.60 2 9 9 9 9 9 9 9 9 9 9

14 2 2048.9 35.041 35.040 2 3.806 3.636 27.873 237.0 2 241.1 2 77.3 0.00 2 20.41 2 4 23.50 2 0.00 2 0.00 2 -0.01 2 9 737.6 366.2 2 2175.8 2 7.7269 2 2331 2 2323 9 9

13 2 2298.9 35.001 35.000 2 3.376 3.189 27.885 243.3 2 246.2 2 75.8 0.00 2 20.51 2 4 27.00 2 9 9 9 9 9 9 9 9 9 9

12 2 2550.1 34.976 34.975 2 3.120 2.913 27.892 245.0 2 246.7 2 77.6 0.00 2 20.71 2 4 30.30 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

11 2 2800.1 34.953 34.954 2 2.889 2.661 27.897 246.1 2 247.1 2 79.3 0.00 2 21.10 2 4 33.30 2 9 9 9 9 9 9 9 9 9 9

10 2 3041.4 34.936 34.936 2 2.717 2.468 27.903 246.3 2 248.8 2 79.2 0.00 2 21.29 2 4 36.00 2 0.00 2 0.00 2 -0.01 2 9 743.6 349.3 2 2190.7 2 7.7281 2 2348 2 2339 9 9

9 2 3301.5 34.924 34.924 2 2.599 2.325 27.906 245.9 2 247.3 2 81.9 0.00 2 21.39 2 4 38.40 2 9 9 9 9 9 9 9 9 9 9

8 2 3549.8 34.915 34.914 2 2.526 2.227 27.909 247.6 2 248.2 2 81.9 0.00 2 21.59 2 4 40.20 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

7 2 3948.7 34.901 34.901 2 2.431 2.090 27.912 249.0 2 249.1 2 82.2 0.00 2 21.68 2 4 42.70 2 9 9 9 9 748.3 346.1 2 2195.6 2 7.7228 2 2347 2 2341 9 9

6 2 4338.8 34.894 34.894 2 2.402 2.017 27.915 249.5 2 249.1 2 82.8 0.00 2 21.98 2 4 44.50 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

5 2 4748.8 34.889 34.888 2 2.391 1.957 27.918 249.7 2 249.7 2 82.7 0.00 2 22.17 2 4 46.10 2 9 9 9 9 9 9 9 9 9 9

4 3 5150.6 34.882 34.882 2 2.386 1.901 27.920 250.3 2 250.9 2 82.0 0.00 2 4 4 46.90 2 0.00 6 0.00 6 0.00 6 9 761.1 351.2 2 2197.8 2 7.7215 2 2351 2 2343 9 9

3 2 5521.0 34.881 34.879 2 2.416 1.882 27.924 251.8 2 251.3 2 81.8 0.00 2 22.07 2 4 47.30 2 9 9 9 9 9 9 9 9 9 9

2 2 5943.6 34.879 34.878 2 2.467 1.874 27.928 252.5 2 251.9 2 81.2 0.00 2 22.07 2 4 47.70 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

1 2 6361.9 34.879 34.878 2 2.525 1.871 27.932 254.2 2 252.0 2 81.2 0.00 6 22.17 6 4 47.80 6 0.00 2 0.00 2 0.00 2 9 768.6 357.2 2 2197.2 2 7.7214 2 2347 2 2342 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

104
A5R

NOAA Ship Ronald H. Brown

STATION 36 DATE 2/1/1998 LATITUDE 24.502° N

LONGITUDE 34.383° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.9 37.521 37.520 2 23.025 23.024 25.842 216.4 2 216.4 2 -6.5 0.00 2 0.00 2 0.00 2 0.30 2 1.96 2 1.13 2 0.16 2 1.79 2 317.3 357.6 2 2094.6 6 8.0842 2 2463 2 2460 69.6 2 9

35 2 25.2 37.518 37.518 2 22.968 22.963 25.859 216.4 2 216.7 2 -6.6 0.00 2 0.00 2 0.00 2 0.30 2 1.97 2 1.14 2 0.16 2 9 9 9 8.0754 2 9 68.3 2 9

34 2 51.4 37.514 37.513 2 22.939 22.928 25.868 216.6 2 217.3 2 -7.1 0.00 2 0.00 2 0.01 2 0.30 2 1.98 6 1.15 6 0.15 6 1.88 2 9 9 8.0747 2 2459 2 67.9 2 9

33 2 99.8 37.087 37.082 2 20.591 20.572 26.207 207.2 2 208.1 2 11.6 0.03 2 0.78 2 0.03 2 0.50 2 2.22 2 1.27 2 0.15 2 1.10 6 9 9 8.0124 2 9 56.9 2 9

32 2 147.7 36.677 36.653 2 18.737 18.711 26.385 203.0 2 206.5 2 21.5 0.01 2 2.34 2 0.07 2 0.80 2 2.33 2 1.32 2 0.08 2 9 9 9 7.9939 2 2408 2 53.2 2 9

31 2 202.0 36.516 36.512 2 17.866 17.831 26.485 204.0 2 204.8 2 27.2 0.01 2 4.20 2 0.17 2 1.20 2 2.38 2 1.31 2 0.06 2 0.63 2 9 9 7.9785 2 9 52.3 2 9

30 2 216.5 36.486 36.485 2 17.701 17.664 26.504 204.4 2 204.0 2 28.8 0.01 2 4.49 2 0.19 2 1.40 2 9 9 9 9 9 9 7.9734 2 2407 2 50.6 2 9

29 2 250.2 36.423 36.419 2 17.328 17.286 26.549 204.0 2 202.6 2 32.0 0.01 2 5.27 2 0.24 2 1.60 2 2.33 2 1.28 2 0.04 2 9 9 9 9 9 50.7 2 9

28 2 276.2 36.359 36.359 2 16.937 16.891 26.596 203.4 2 202.4 6 34.0 0.01 2 5.95 2 0.29 2 1.80 2 9 9 9 0.59 2 9 9 7.9526 2 2392 2 9 9

27 2 300.4 36.310 36.309 2 16.648 16.599 26.628 203.4 2 9 0.01 2 6.44 2 0.32 2 2.00 2 2.33 2 1.27 2 0.04 2 9 9 9 9 9 50.5 2 9

26 2 349.6 36.180 36.174 2 15.863 15.807 26.714 199.4 2 199.9 2 41.8 0.01 2 7.91 2 0.42 2 2.60 2 9 9 9 9 9 9 7.9225 2 2380 2 9 9

25 2 400.6 36.021 36.011 2 14.824 14.763 26.826 194.7 2 191.7 2 55.3 0.00 2 10.25 2 0.57 2 3.50 2 2.19 2 1.18 2 0.03 2 0.52 2 9 9 9 9 49.6 2 9

24 2 500.8 35.773 35.772 2 13.128 13.057 26.996 189.2 2 185.3 2 70.9 0.00 2 13.47 2 0.77 2 5.10 2 1.96 2 1.02 2 0.02 2 9 9 9 7.8348 2 2357 2 9 9

23 2 600.5 35.614 35.610 2 11.822 11.743 27.131 180.8 2 177.5 2 86.1 0.00 2 16.50 2 0.96 2 6.70 2 1.57 2 0.80 2 0.02 2 0.45 2 9 9 9 9 48.6 2 9

22 2 700.0 35.472 35.472 2 10.528 10.442 27.259 165.5 2 161.8 2 109.4 0.00 2 20.31 2 1.22 2 9.90 2 0.89 2 0.42 2 0.00 2 9 9 9 7.7398 2 2341 2 9 9

21 2 798.8 35.360 35.359 2 9.403 9.310 27.365 155.4 2 151.1 2 127.2 0.01 2 23.24 2 1.43 2 13.10 2 0.41 2 0.18 2 0.00 2 0.18 2 9 9 9 9 46.1 2 9

20 2 901.0 35.248 35.247 2 8.271 8.174 27.458 151.4 2 147.4 2 138.2 0.00 2 25.49 2 1.61 2 15.80 2 0.17 2 0.07 2 0.00 2 9 9 9 7.6754 2 2331 2 9 9

19 2 999.3 35.189 35.188 2 7.414 7.312 27.538 161.4 2 156.9 2 134.5 0.00 2 25.69 2 1.65 2 17.10 2 0.10 2 0.04 2 0.00 2 9 9 9 9 9 9 9

18 2 1149.7 35.174 35.173 2 6.618 6.506 27.639 181.6 2 175.4 2 121.5 0.00 2 24.42 2 1.59 2 17.90 2 0.06 2 0.03 2 -0.01 2 0.09 6 9 9 7.6805 2 2337 2 9 9

17 2 1301.4 35.172 35.172 2 6.031 5.908 27.716 198.0 2 193.0 2 108.1 0.00 2 23.05 2 1.50 2 17.70 2 9 9 9 9 9 9 9 9 9 9

16 2 1400.9 35.141 35.139 2 5.503 5.376 27.758 209.2 2 205.8 2 99.2 0.00 2 22.27 2 1.46 2 18.10 2 0.02 2 0.01 2 0.00 2 9 9 9 7.7071 2 2337 2 9 9

15 2 1601.0 35.126 35.127 2 4.952 4.811 27.813 223.4 2 220.3 2 88.9 0.00 2 21.19 2 1.39 2 18.90 2 9 9 9 9 9 9 9 9 9 9

14 2 1799.3 35.099 35.100 2 4.489 4.334 27.846 233.2 2 230.6 2 82.2 0.00 2 20.80 2 1.36 2 20.20 2 0.00 6 0.00 6 0.00 6 9 9 9 7.7269 2 9 9 9

13 2 2000.3 35.049 35.049 2 3.925 3.758 27.867 240.3 2 238.9 2 78.5 0.00 2 20.61 2 1.35 2 22.70 2 9 9 9 9 9 9 9 9 9 9

12 2 2198.8 35.014 35.012 2 3.535 3.355 27.879 245.6 2 244.0 2 76.7 0.00 2 20.51 2 1.36 2 25.30 2 0.00 2 0.00 2 -0.01 2 0.03 2 9 9 9 9 9 9

11 2 2400.6 34.988 34.988 2 3.265 3.070 27.887 248.1 2 246.3 2 76.7 0.00 2 20.71 2 1.37 2 28.10 2 9 9 9 9 9 9 9 9 9 9

10 2 2600.5 34.966 34.966 2 3.034 2.823 27.893 249.1 2 247.3 2 77.7 0.00 2 20.90 2 1.39 2 31.20 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

9 2 2799.6 34.951 34.950 2 2.864 2.637 27.898 248.5 2 247.0 2 79.6 0.00 2 21.20 2 1.41 2 34.00 2 9 9 9 9 9 9 7.7282 2 2350 2 9 9

8 2 2999.4 34.937 34.937 2 2.725 2.480 27.902 248.5 2 246.9 2 81.0 0.01 2 21.39 2 1.43 2 36.70 2 0.00 2 0.00 2 -0.01 2 0.00 2 9 9 9 9 9 9

7 2 3296.4 34.925 34.937 2 2.614 2.341 27.905 250.2 2 246.9 2 82.2 0.01 2 21.59 2 1.44 2 39.50 2 9 9 9 9 9 9 9 9 9 9

6 2 3600.7 34.913 34.912 2 2.516 2.212 27.909 251.5 2 248.5 2 81.7 0.01 2 21.88 2 1.46 2 41.50 2 0.00 3 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9

5 2 3890.1 34.902 34.902 2 2.438 2.104 27.911 251.0 2 249.2 2 82.0 0.01 2 21.98 2 1.46 2 43.30 2 9 9 9 9 9 9 9 9 9 9

4 2 4199.6 34.896 34.895 2 2.403 2.034 27.913 252.1 2 249.5 2 82.3 0.01 2 22.08 2 1.48 2 44.20 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

3 2 4497.9 34.891 34.891 2 2.391 1.987 27.916 252.2 2 249.6 2 82.6 0.01 2 22.08 2 1.49 2 44.70 2 0.00 2 0.00 2 -0.01 2 0.02 6 9 9 9 9 9 9

2 2 4899.0 34.882 34.882 2 2.360 1.908 27.918 254.3 2 251.9 2 81.0 0.01 2 22.18 2 1.49 2 46.30 2 0.00 6 0.00 6 0.00 6 0.04 2 9 9 9 9 9 9

1 2 5232.2 34.881 34.881 2 2.390 1.895 27.921 254.1 2 251.5 2 81.5 0.01 6 22.18 6 1.50 6 46.40 6 0.00 2 0.00 2 -0.01 2 0.09 3 9 9 7.7245 2 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

105
A5R

NOAA Ship Ronald H. Brown

STATION 37 DATE 2/1/1998 LATITUDE 24.500° N

LONGITUDE 35.217° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 37.491 37.491 2 23.216 23.215 25.763 215.4 2 215.3 2 -6.1 0.00 2 0.00 2 4 0.90 2 1.95 2 1.13 2 0.16 2 9 304.5 345.9 2 2091.5 2 8.0795 2 2447 2 2453 9 9

35 2 28.6 37.495 37.495 2 23.177 23.171 25.781 216.0 2 215.5 2 -6.1 0.00 2 0.00 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 71.6 37.480 37.479 2 23.134 23.119 25.787 216.3 2 215.5 2 -5.9 0.00 2 0.00 2 4 0.90 2 9 9 9 9 301.7 341.6 2 2089.8 6 8.0777 2 2447 2 2449 9 9

33 2 113.2 37.426 37.410 2 22.928 22.905 25.811 217.7 2 216.4 2 -6.0 0.00 2 0.00 2 4 0.50 2 1.98 2 1.15 2 0.16 2 9 306.9 344.7 2 2091.3 2 8.0729 2 2442 2 2447 9 9

32 3 160.7 36.861 36.860 2 19.723 19.693 26.273 203.2 2 210.6 2 13.0 0.03 2 0.59 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

31 2 208.4 36.604 36.603 2 18.375 18.338 26.427 202.4 2 9 0.01 2 2.93 2 4 0.90 2 2.35 6 1.33 6 0.07 6 9 379.8 355.7 2 2099.9 2 7.9922 2 2389 2 2393 9 9

30 2 225.1 36.556 36.556 2 18.116 18.077 26.456 202.7 2 203.0 2 27.9 0.01 2 3.61 2 4 1.00 2 9 9 9 9 9 9 9 9 9 9

29 2 260.3 36.459 36.462 2 17.568 17.524 26.520 200.7 2 201.3 2 32.1 0.01 2 4.78 2 4 1.10 2 9 9 9 9 402.9 365.4 2 2105.5 2 7.9686 2 2380 2 2383 9 9

28 2 286.1 36.422 36.423 2 17.312 17.264 26.555 199.3 2 199.8 2 34.8 0.01 2 5.37 2 4 1.40 2 9 9 9 9 9 9 9 9 9 9

27 2 316.6 36.359 36.364 2 16.933 16.880 26.600 198.2 2 192.6 2 43.9 0.00 2 6.05 2 4 1.70 2 2.32 2 1.28 2 0.04 2 9 426.8 376.8 2 2112.2 2 7.9505 2 2380 2 2378 9 9

26 2 411.9 36.093 36.103 2 15.179 15.115 26.805 190.4 2 182.9 2 62.3 0.00 2 9.27 2 4 2.80 2 9 9 9 9 488.4 401.0 2 2131.0 2 7.8952 2 2361 2 2365 9 9

25 2 511.6 35.773 35.772 2 13.025 12.953 27.016 184.0 2 174.4 2 82.3 0.00 2 13.76 2 4 4.80 2 2.00 2 1.03 2 0.03 2 9 583.6 438.2 2 2148.6 2 7.8270 2 2344 2 2345 9 9

24 2 622.7 35.592 35.594 2 11.653 11.571 27.146 178.0 2 145.4 2 119.1 0.00 2 16.99 2 4 6.70 2 9 9 9 9 9 2161.9 2 7.7815 2 2336 2 2336 9 9

23 2 724.5 35.419 35.412 2 10.240 10.152 27.269 147.2 2 141.3 2 131.8 0.00 2 22.65 2 4 11.40 2 0.57 2 0.26 2 0.01 2 9 9 9 9 9 9 9

22 2 825.7 35.228 35.225 2 8.474 8.384 27.408 142.5 2 148.0 2 136.3 0.00 2 25.98 2 4 16.00 2 9 9 9 9 877.1 544.4 2 2199.9 2 7.6650 2 2325 2 2322 9 9

21 2 923.1 35.133 35.134 2 7.502 7.407 27.479 149.1 2 157.1 2 133.8 0.00 2 26.76 2 4 17.90 2 0.09 6 0.04 6 0.00 6 9 9 9 9 9 9 9

20 2 1001.7 35.085 35.084 2 6.840 6.742 27.535 159.4 2 185.8 2 109.7 0.00 2 26.57 2 4 18.40 2 9 9 9 9 908.3 524.6 2 2200.4 6 7.6534 2 5 2318 9 9

19 2 1198.8 35.099 35.097 2 5.971 5.860 27.663 187.3 2 207.5 2 94.1 0.00 2 24.12 2 4 18.20 2 0.03 2 0.02 2 0.00 2 9 9 9 9 9 9 9

18 2 1389.6 35.110 35.109 2 5.378 5.253 27.747 208.7 2 222.9 2 83.1 0.00 2 22.27 2 4 17.90 2 9 9 9 9 9 9 9 9 9 9

17 2 1597.6 35.106 35.107 2 4.869 4.729 27.807 224.7 2 231.2 2 78.6 0.00 2 21.10 2 4 18.50 2 9 9 9 9 758.0 396.5 2 9 7.7171 2 2337 2 9 9

16 2 1802.6 35.078 35.078 2 4.355 4.201 27.843 232.7 2 238.6 2 75.3 0.00 2 20.71 2 4 20.50 2 9 9 9 9 9 2178.6 2 9 9 9 9

15 2 2000.5 35.050 35.050 2 3.966 3.799 27.864 238.5 2 242.4 2 74.7 0.00 2 20.41 2 4 22.10 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

14 2 2201.5 35.024 35.023 2 3.654 3.472 27.877 244.4 2 245.9 2 73.8 0.00 2 20.41 2 4 24.30 2 9 9 9 9 9 2177.9 2 7.7318 2 5 2327 9 9

13 2 2400.5 34.992 34.992 2 3.329 3.133 27.884 247.0 2 245.7 6 76.8 0.00 2 20.51 2 4 27.10 2 9 9 9 9 9 9 9 9 9 9

12 2 2601.0 34.969 34.970 2 3.093 2.881 27.890 247.2 2 247.0 2 77.6 0.00 2 20.81 2 4 30.60 2 9 9 9 9 9 9 9 9 9 9

11 2 2790.2 34.959 34.958 2 2.967 2.739 27.896 246.5 2 246.3 2 79.4 0.00 2 20.90 2 4 32.40 2 0.00 2 0.00 2 0.00 2 9 740.6 352.4 2 2185.3 2 7.7304 2 5 2334 9 9

10 2 3000.6 34.947 34.946 2 2.835 2.588 27.901 245.3 2 246.7 2 80.3 0.00 2 21.20 2 4 34.90 2 9 9 9 9 9 9 9 9 9 9

9 2 3250.1 34.932 34.931 2 2.683 2.413 27.905 245.8 2 247.2 2 81.3 0.00 2 21.29 2 4 38.10 2 9 9 9 9 9 2192.1 2 7.7295 2 5 2341 9 9

8 2 3491.5 34.919 34.918 2 2.573 2.280 27.907 247.6 2 247.8 2 81.8 0.00 2 21.78 2 4 40.40 2 0.00 2 0.00 2 0.02 4 9 9 9 9 9 9 9

7 2 3747.9 34.909 34.909 2 2.486 2.167 27.910 246.8 2 249.4 2 81.2 0.00 2 21.78 2 4 42.90 2 9 9 9 9 749.3 347.5 2 2194.6 2 7.7277 2 5 2342 9 9

6 2 4000.2 34.902 34.901 2 2.445 2.098 27.912 246.4 2 248.6 2 82.6 0.00 2 21.88 2 4 43.50 2 9 9 9 9 9 9 9 9 9 9

5 2 4247.8 34.897 34.896 2 2.416 2.041 27.914 247.4 2 249.6 2 82.1 0.00 2 21.88 2 4 44.20 2 0.00 2 0.00 2 -0.01 2 9 9 9 9 9 9 9

4 2 4497.4 34.892 34.891 2 2.400 1.996 27.916 249.6 2 249.9 2 82.2 0.00 2 21.98 2 4 44.80 2 9 9 9 9 9 2196.9 2 7.7264 2 9 2344 9 9

3 2 4683.1 34.888 34.888 2 2.380 1.954 27.917 250.8 2 250.3 2 82.1 0.00 2 22.08 2 4 45.70 2 9 9 9 9 9 9 9 9 9 9

2 2 4999.7 34.884 34.885 2 2.385 1.919 27.920 250.7 2 251.4 9 81.4 9 9 9 9 0.00 2 0.00 2 0.00 2 9 767.1 353.4 2 2198.4 2 7.7227 2 5 2343 9 9

1 2 5242.3 34.881 34.881 2 2.394 1.897 27.921 252.9 2 251.3 2 81.6 0.00 6 22.08 6 4 47.10 6 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

106
A5R

NOAA Ship Ronald H. Brown

STATION 38 DATE 2/2/1998 LATITUDE 24.500° N

LONGITUDE 36.033° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.5 37.514 37.514 2 23.345 23.344 25.743 215.4 2 214.6 2 -5.9 0.00 2 0.00 2 4 0.20 2 1.92 2 1.12 2 0.15 2 9 301.0 343.6 2 2090.6 6 8.0797 2 2462 2 2452 70.1 2 4.4 2

35 2 49.5 37.499 37.501 2 23.237 23.227 25.769 213.9 2 214.9 2 -5.7 0.00 2 0.00 2 4 0.20 2 1.94 2 1.11 2 0.16 2 9 300.4 341.5 2 2093.5 2 8.0796 2 2453 2 2455 70.3 2 4.5 2

34 2 99.8 37.337 37.347 2 22.644 22.624 25.824 215.0 2 217.5 2 -5.9 0.00 2 0.00 2 4 0.30 2 2.03 2 1.15 2 0.17 2 9 307.6 341.5 2 2088.8 2 8.0680 2 2438 2 2440 69.9 2 4.5 2

33 2 150.4 36.967 36.966 2 20.060 20.032 26.264 209.3 2 209.9 2 12.2 0.02 2 0.59 2 4 0.40 2 2.26 2 1.29 2 0.14 2 9 360.8 361.7 2 2104.8 2 8.0028 2 2414 2 2408 58.7 2 4.7 2

32 2 198.2 36.746 36.747 2 18.772 18.737 26.434 185.9 2 182.9 2 44.8 0.01 2 5.07 2 4 1.10 2 2.26 2 1.27 2 0.06 2 9 425.5 405.0 2 2128.5 2 7.9490 2 2399 2 2398 55.1 2 8.5 2

31 2 222.7 36.644 36.643 2 18.209 18.170 26.500 190.6 2 194.1 2 36.2 0.01 2 4.49 2 4 1.10 2 9 9 9 9 419.9 390.6 2 2119.1 2 7.9586 2 2394 2 2393 54.0 2 8.1 2

30 2 247.1 36.535 36.540 2 17.619 17.577 26.564 189.6 2 193.4 2 39.7 0.01 2 5.27 2 4 1.40 2 2.38 6 1.32 6 0.04 6 9 424.8 385.7 2 2119.5 2 7.9488 2 2387 2 2387 53.4 2 8.8 2

29 2 273.4 36.427 36.425 2 17.075 17.029 26.615 176.9 2 181.1 2 54.6 0.01 2 7.71 2 4 1.90 2 9 9 9 9 461.1 409.6 2 2133.6 2 7.9141 2 2380 2 2380 52.0 2 11.2 2

28 2 300.5 36.336 36.337 2 16.525 16.476 26.677 175.2 2 179.5 2 58.9 0.00 2 8.59 2 4 2.20 2 2.32 2 1.26 2 0.03 2 9 478.6 415.9 2 2135.3 2 7.9018 2 2375 2 2375 9 9

27 2 352.2 36.171 36.184 2 15.577 15.522 26.772 179.4 2 183.1 2 60.0 0.00 2 9.57 2 4 2.70 2 2.28 2 1.22 2 0.03 2 9 492.8 411.6 2 2136.2 2 7.8898 2 2367 2 2368 49.9 2 12.9 2

26 2 401.0 36.011 36.015 2 14.671 14.610 26.851 189.7 2 185.4 2 62.4 0.00 2 10.84 2 4 3.40 2 2.16 2 1.15 2 0.03 2 9 514.6 413.6 2 2137.5 2 7.8727 2 2357 2 2358 9 9

25 2 448.6 35.877 35.857 2 13.753 13.688 26.945 172.2 2 174.2 2 78.5 0.00 2 13.67 2 4 4.50 2 9 9 9 9 573.8 444.1 2 2148.1 2 7.8314 2 2348 2 2347 47.9 2 16.7 2

24 2 499.3 35.730 35.730 2 12.759 12.690 27.035 173.6 2 171.2 2 87.0 0.00 2 15.43 2 4 5.50 2 1.75 2 0.89 2 0.03 2 9 617.2 458.6 2 2155.8 2 7.8044 2 2340 2 2341 9 9

23 2 548.7 35.629 35.629 2 12.010 11.937 27.105 163.7 2 162.6 2 99.9 0.00 2 17.48 2 4 6.70 2 1.41 2 0.71 2 0.02 2 9 657.9 473.6 2 2164.6 2 7.7677 2 2337 2 2332 45.9 2 20.5 2

22 2 649.1 35.474 35.465 2 10.703 10.622 27.228 154.7 2 150.7 2 119.5 0.00 2 21.39 2 4 9.80 2 0.77 6 0.36 6 0.01 6 9 746.6 509.3 2 2178.6 2 7.7252 2 2330 2 2327 9 9

21 2 750.1 35.340 35.338 2 9.488 9.401 27.333 142.8 2 143.6 2 134.1 0.00 2 23.93 2 4 12.90 2 0.37 2 0.16 2 0.01 2 9 818.0 530.2 2 2189.4 2 7.6871 2 2326 2 2321 43.8 2 26.4 2

20 2 848.4 35.200 35.199 2 8.137 8.046 27.438 143.9 2 143.9 2 142.7 0.00 2 26.28 2 4 16.10 2 0.14 2 0.06 2 0.00 2 9 887.0 542.7 2 2198.8 2 7.6602 2 2324 2 2319 9 9

19 2 938.8 35.113 35.116 2 7.192 7.098 27.508 151.5 2 154.6 2 138.4 0.00 2 26.47 2 4 17.80 2 0.08 2 0.03 2 0.00 2 9 896.4 525.9 2 2198.1 2 7.6571 2 2322 2 2317 42.2 2 29.0 2

18 2 1046.9 35.067 35.067 2 6.553 6.452 27.560 161.3 2 162.1 2 135.4 0.00 2 26.47 2 4 19.00 2 0.04 2 0.02 2 0.01 2 9 9 2198.3 6 7.6540 2 2321 2 2316 9 9

17 2 1249.8 35.061 35.060 2 5.636 5.523 27.675 188.7 2 191.8 2 112.3 0.00 2 23.84 2 4 18.30 2 0.03 2 0.01 2 0.00 2 9 831.4 452.8 6 2189.5 2 7.6813 2 2322 2 2318 42.1 2 26.6 2

16 2 1444.2 35.069 35.068 2 5.179 5.051 27.739 211.6 2 210.2 2 97.4 0.00 2 22.47 2 4 18.00 2 0.02 2 0.00 2 0.01 2 9 9 2182.6 2 7.7016 2 2323 2 2319 9 9

15 2 1645.4 35.101 35.101 2 4.770 4.627 27.815 223.9 2 224.0 2 86.6 0.00 2 21.20 2 4 18.90 2 0.01 2 0.00 2 0.00 2 9 765.2 398.8 2 2178.9 2 7.7164 2 2326 2 2322 41.8 2 23.3 2

14 2 1948.2 35.066 35.066 2 4.144 3.979 27.858 234.3 2 235.9 2 79.7 0.00 2 20.52 2 4 21.30 2 0.00 2 0.00 2 0.00 2 9 9 2176.3 2 7.7282 2 2330 2 2324 9 9

13 2 2047.3 35.050 35.049 2 3.953 3.781 27.866 236.5 2 239.4 2 77.8 0.00 2 20.42 2 4 22.20 2 9 9 9 9 740.8 370.6 2 2176.8 2 7.7263 2 9 2324 41.5 2 22.3 2

12 2 2245.2 35.021 35.020 2 3.620 3.434 27.878 244.6 2 244.2 2 75.8 0.00 2 20.52 2 4 24.20 2 0.00 6 0.00 6 0.00 6 9 9 2176.8 2 7.7260 2 9 2323 9 9

11 2 2451.4 34.989 34.990 2 3.280 3.080 27.887 244.6 2 246.6 2 76.3 0.00 2 20.61 2 4 27.50 2 9 9 9 9 736.1 356.0 2 2179.0 2 7.7320 2 2333 2 2328 41.9 2 22.5 2

10 2 2648.9 34.970 34.969 2 3.077 2.861 27.893 246.1 2 246.9 2 77.8 0.00 2 20.61 2 4 30.00 2 0.00 2 0.00 2 0.00 2 9 9 2181.8 2 7.7259 2 9 2328 9 9

9 2 2853.7 34.953 34.953 2 2.900 2.666 27.898 247.3 2 247.2 2 79.2 0.00 2 21.01 2 4 32.80 2 9 9 9 9 741.7 351.8 2 2185.8 2 7.7301 2 9 2334 41.7 2 23.4 2

8 2 3039.7 34.940 34.940 2 2.769 2.519 27.901 243.7 2 246.6 2 81.0 0.00 2 21.20 2 4 35.30 2 0.00 2 -0.01 2 0.00 2 9 9 2192.1 2 7.7267 2 9 2339 9 9

7 2 3424.1 34.922 34.921 2 2.589 2.303 27.907 244.8 2 247.5 2 81.9 0.00 2 21.49 2 4 39.00 2 9 9 9 9 747.6 348.8 2 2194.8 2 7.7284 2 2345 2 2343 41.5 2 24.1 2

6 2 3750.9 34.910 34.909 2 2.499 2.179 27.910 246.7 2 248.8 2 81.7 0.00 2 21.69 2 4 41.00 2 0.00 2 0.00 2 0.00 2 9 9 2195.3 2 7.7273 2 9 2343 9 9

5 2 4030.1 34.902 34.901 2 2.445 2.095 27.913 247.6 2 249.5 2 81.7 0.00 2 21.79 2 4 42.60 2 9 9 9 9 749.7 347.0 2 2195.4 2 7.7196 2 2347 2 2340 41.6 2 24.5 2

4 2 4446.0 34.893 34.893 2 2.405 2.007 27.915 248.5 2 249.3 2 82.7 0.00 2 21.98 2 4 44.60 2 0.00 2 0.00 2 0.00 2 9 9 2198.3 2 7.7258 2 9 2345 41.5 2 24.6 2

3 2 4846.2 34.886 34.886 2 2.391 1.945 27.918 249.5 2 250.4 2 82.1 0.00 2 22.28 2 4 45.50 2 0.00 2 0.00 2 0.00 2 9 759.1 350.4 2 2198.2 2 7.7196 2 2350 2 2343 41.4 2 24.6 2

2 2 5249.1 34.882 34.881 2 2.401 1.903 27.921 250.3 2 250.9 2 82.0 0.00 2 4 4 46.50 2 0.00 2 0.00 2 0.00 2 9 9 2198.1 2 7.7230 2 9 2344 41.7 2 25.0 2

1 2 5768.6 34.879 34.878 2 2.433 1.865 27.926 252.1 2 252.2 2 81.0 0.00 2 22.08 2 4 47.50 2 0.00 2 0.00 2 0.00 2 9 768.2 355.4 2 2196.5 2 7.7167 2 2346 2 2340 41.9 2 24.5 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

107
A5R

NOAA Ship Ronald H. Brown

STATION 39 DATE 2/2/1998 LATITUDE 24.500° N

LONGITUDE 36.867° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 37.575 37.574 3 23.817 23.816 25.650 214.3 3 212.8 2 -5.8 0.00 2 0.00 2 4 1.00 3 1.87 2 1.09 2 0.15 2 1.75 2 295.5 343.5 2 2090.3 6 8.0834 2 9 2455 9 9

35 2 49.5 37.569 37.567 3 23.787 23.777 25.659 212.2 3 213.2 2 -6.1 0.00 2 0.00 2 4 1.10 3 9 9 9 9 9 9 9 9 9 9

34 2 89.7 37.338 37.315 3 22.632 22.614 25.827 216.8 3 217.6 2 -6.0 0.00 2 0.00 2 4 1.20 3 2.08 2 1.19 2 0.16 2 9 324.0 363.1 2 2099.3 2 8.0504 2 9 2438 9 9

33 2 150.3 36.991 36.983 3 20.133 20.105 26.262 203.2 3 207.1 2 14.6 0.02 2 0.88 2 4 1.40 3 2.24 2 1.28 2 0.14 2 1.13 2 362.5 364.5 2 2107.4 2 8.0105 2 9 2417 9 9

32 2 200.2 36.735 36.726 3 18.774 18.738 26.425 200.2 3 200.2 2 27.6 0.00 2 2.93 2 4 1.80 3 9 9 9 9 389.4 370.4 2 2110.6 2 7.9823 2 9 2399 9 9

31 2 225.5 36.629 36.625 3 18.266 18.226 26.474 200.5 3 200.8 2 29.3 0.00 2 3.61 2 4 2.00 3 2.32 2 1.31 2 0.05 2 0.73 2 9 9 9 9 9 9

30 2 250.3 36.540 36.544 3 17.752 17.709 26.536 198.6 3 194.8 2 37.7 0.00 2 5.07 2 4 2.50 3 9 9 9 9 418.3 383.2 2 2116.1 2 7.9506 2 9 2384 9 9

29 2 265.0 36.482 36.471 3 17.479 17.434 26.559 196.7 3 196.4 2 37.4 0.00 2 5.56 2 4 2.60 3 2.32 2 1.28 2 0.03 2 0.57 6 9 9 9 9 9 9

28 2 302.5 36.364 36.360 3 16.733 16.683 26.650 198.2 3 197.3 2 40.1 0.00 2 6.54 2 4 3.10 3 9 9 9 9 439.5 385.4 2 2119.3 2 7.9365 2 9 2378 9 9

27 2 350.3 36.298 36.284 3 16.280 16.223 26.709 199.2 3 193.6 2 46.0 0.00 2 7.61 2 4 3.70 3 2.36 2 1.27 2 0.03 2 0.49 2 9 9 9 9 9 9

26 2 397.2 36.098 36.102 3 15.184 15.122 26.806 193.1 3 190.1 2 55.0 0.00 2 9.57 2 4 4.50 3 9 9 9 9 493.7 405.6 2 2132.1 2 7.8864 2 9 2361 9 9

25 2 450.3 35.935 35.924 3 14.116 14.049 26.914 192.0 3 188.4 2 62.4 0.00 2 11.52 2 4 5.40 3 9 9 9 9 9 9 9 9 9 9

24 2 499.1 35.819 35.813 3 13.338 13.267 26.988 189.6 3 185.9 2 69.1 0.00 2 12.99 2 4 6.00 3 2.05 6 1.06 6 0.03 6 0.52 2 567.0 431.4 2 2144.6 2 7.8380 2 9 2347 9 9

23 2 549.2 35.711 35.715 3 12.598 12.522 27.055 187.7 3 180.9 2 78.2 0.00 2 14.65 2 4 6.70 3 9 9 9 9 9 9 9 9 9 9

22 2 600.4 35.603 35.589 3 11.764 11.685 27.133 177.9 3 166.6 2 97.3 0.00 2 17.87 2 4 8.60 3 9 9 9 9 666.1 475.5 2 2163.7 2 7.7663 2 9 2330 9 9

21 2 649.4 35.501 35.494 3 10.900 10.818 27.214 165.3 3 156.8 2 112.2 0.00 2 20.31 2 4 10.50 3 9 9 9 9 9 9 9 9 9 9

20 2 700.1 35.435 35.429 3 10.312 10.227 27.267 157.0 3 151.7 2 120.9 0.00 2 21.88 2 4 11.90 3 0.66 2 0.30 2 0.01 2 0.23 2 9 9 9 9 9 9

19 2 799.9 35.336 35.334 3 9.291 9.199 27.364 149.0 3 147.8 2 131.2 0.00 2 23.74 2 4 14.60 3 9 9 9 9 810.3 520.4 2 2189.3 2 7.6914 2 9 2323 9 9

18 2 899.8 35.211 35.211 3 8.131 8.035 27.449 149.7 3 148.5 2 138.1 0.00 2 25.69 2 4 17.50 3 0.15 2 0.06 2 0.00 2 9 9 9 9 9 9 9

17 2 1097.7 35.077 35.076 3 6.426 6.321 27.586 170.3 3 163.1 2 135.3 0.00 2 25.89 2 4 20.10 3 0.04 2 0.02 2 0.00 2 0.08 2 877.8 496.9 2 2197.5 6 7.6608 2 9 2317 9 9

16 2 1298.5 35.103 35.102 3 5.712 5.593 27.700 199.0 3 196.1 2 107.4 0.00 2 23.45 2 4 19.10 3 0.03 2 0.01 2 0.01 2 9 9 9 9 9 9 9

15 2 1499.5 35.116 35.116 3 5.199 5.065 27.775 215.0 3 214.3 2 93.0 0.00 2 21.79 2 4 18.10 3 9 9 9 9 773.9 411.7 2 2181.0 2 7.7057 2 9 2319 9 9

14 2 1697.7 35.097 35.096 3 4.662 4.515 27.824 230.3 3 228.3 2 83.2 0.00 2 20.91 2 4 17.90 2 9 9 9 9 9 9 9 9 9 9

13 2 1898.5 35.081 35.081 3 4.316 4.154 27.851 235.9 3 232.9 2 81.4 0.00 2 20.81 2 4 19.60 2 0.00 2 0.00 2 0.00 2 0.06 2 9 9 9 9 9 9

12 2 2096.9 35.043 35.044 3 3.872 3.697 27.869 241.9 3 241.1 2 76.8 0.00 2 20.52 2 4 21.70 2 9 9 9 9 735.1 366.4 6 2174.5 2 7.7310 2 9 2323 9 9

11 2 2303.9 35.008 35.009 3 3.495 3.305 27.881 245.9 3 244.6 2 76.5 0.00 2 20.61 2 4 24.40 2 9 9 9 9 9 9 9 9 9 9

10 2 2502.3 34.984 34.986 3 3.235 3.030 27.888 246.9 3 246.2 2 77.1 0.00 2 20.81 2 4 27.40 2 0.00 2 0.00 2 0.00 2 0.02 6 9 9 9 9 9 9

9 2 2700.7 34.962 34.961 3 2.993 2.773 27.895 247.8 3 246.5 2 79.0 0.00 2 21.01 2 4 30.80 2 9 9 9 9 9 9 9 9 9 9

8 2 3101.9 34.937 34.938 3 2.737 2.481 27.903 247.4 3 246.8 2 81.1 0.00 2 21.30 2 4 35.30 2 9 9 9 9 9 2189.8 2 7.7246 2 9 2336 9 9

7 2 3496.1 34.914 34.916 3 2.546 2.253 27.905 250.1 3 247.9 2 82.0 0.00 2 21.79 2 4 39.30 2 0.00 6 0.00 6 0.00 6 -0.01 2 9 9 9 9 9 9

6 2 3995.1 34.900 34.902 3 2.441 2.095 27.911 251.1 3 249.4 2 81.8 0.00 2 21.98 2 4 42.00 2 9 9 9 9 754.7 349.5 2 2195.4 2 7.7274 2 9 2343 9 9

5 2 4601.1 34.889 34.889 3 2.386 1.970 27.917 252.4 3 250.5 2 81.8 0.00 2 22.08 2 4 44.70 2 0.00 2 0.00 2 0.00 2 0.03 2 9 9 9 9 9 9

4 2 5405.4 34.882 34.882 3 2.418 1.899 27.923 251.8 3 251.3 2 81.6 0.00 2 22.28 2 4 47.80 3 9 9 9 9 9 9 9 9 9 9

3 2 5405.6 34.882 34.883 3 2.418 1.899 27.923 251.8 3 251.5 2 81.4 0.00 2 22.18 2 4 46.80 2 9 9 9 9 9 9 9 9 9 9

2 2 5405.4 34.882 34.881 3 2.418 1.899 27.923 251.8 3 252.0 2 80.9 0.00 2 22.18 2 4 47.00 2 9 9 9 9 9 9 9 9 9 9

1 2 5405.8 34.883 34.882 3 2.418 1.899 27.924 251.8 3 251.4 2 81.5 0.00 6 22.18 6 4 47.10 6 0.00 2 0.01 2 0.00 2 0.03 2 771.4 356.7 2 2199.8 2 7.7222 2 9 2345 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

108
A5R

NOAA Ship Ronald H. Brown

STATION 40 DATE 2/2/1998 LATITUDE 24.500° N

LONGITUDE 37.683° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.8 37.535 37.537 2 24.064 24.063 25.545 208.2 2 214.2 2 -8.0 0.00 2 0.00 2 4 0.50 2 1.89 2 1.08 2 0.15 2 9 312.1 366.3 3 2087.9 6 8.0901 2 2463 2 2457 71.5 2 9

35 3 51.9 37.546 37.546 2 23.989 23.978 25.582 211.8 2 212.6 2 -6.2 0.00 2 0.00 2 4 0.50 2 1.88 2 1.08 2 0.18 2 9 9 9 8.0895 2 2460 2 70.5 2 9

34 2 99.9 37.499 37.468 2 23.774 23.753 25.617 212.2 2 210.0 2 -2.7 0.02 2 0.00 2 4 0.50 2 1.94 2 1.12 2 0.15 2 9 9 9 9 9 64.7 2 9

33 2 140.4 37.151 37.155 2 21.163 21.136 26.104 212.5 2 212.8 2 4.6 0.06 2 0.29 2 4 0.50 2 2.19 2 1.25 2 0.16 2 9 9 9 8.0289 2 2437 2 55.5 2 9

32 2 177.3 36.993 36.993 2 20.003 19.970 26.301 198.2 2 213.6 2 8.7 0.02 2 1.95 2 4 0.80 2 2.26 2 1.28 2 0.12 2 9 9 9 9 9 53.6 2 9

31 2 210.1 36.828 36.852 2 19.125 19.087 26.408 195.3 2 197.3 2 28.8 0.01 2 2.05 2 4 0.90 2 9 9 9 9 9 9 7.9876 2 2421 2 51.0 2 9

30 2 233.4 36.613 36.614 2 18.141 18.100 26.494 198.3 2 199.7 2 31.0 0.01 2 3.81 2 4 1.30 2 2.33 2 1.30 2 0.05 2 9 9 9 9 9 9 9

29 2 260.9 36.512 36.499 2 17.642 17.597 26.542 195.8 2 199.2 2 33.8 0.00 2 4.78 2 4 1.50 2 9 9 9 9 9 9 7.9619 2 2398 2 47.4 2 9

28 2 285.1 36.437 36.438 2 17.173 17.125 26.600 193.8 2 199.1 2 36.1 0.00 2 5.66 2 4 1.60 2 2.36 6 1.30 6 0.03 6 9 9 9 9 9 9 9

27 2 325.2 36.356 36.352 2 16.729 16.675 26.647 195.1 2 196.1 2 41.3 0.00 2 6.64 2 4 2.00 2 9 9 9 9 9 9 7.9333 2 2385 2 45.3 2 9

26 2 376.3 36.187 36.192 2 15.746 15.686 26.747 194.3 2 194.3 2 48.0 0.00 2 8.20 2 4 2.60 2 2.31 2 1.24 2 0.03 2 9 9 9 9 9 9 9

25 2 425.2 36.057 36.058 2 14.951 14.886 26.827 192.2 2 193.7 2 52.7 0.00 2 9.66 2 4 3.30 2 9 9 9 9 9 9 7.8899 2 2373 2 44.7 2 9

24 2 476.5 35.925 35.927 2 14.148 14.077 26.901 188.0 2 191.3 2 59.3 0.00 2 11.32 2 4 4.00 2 2.14 2 1.12 2 0.03 2 9 9 9 9 9 9 9

23 2 550.7 35.717 35.717 2 12.685 12.609 27.042 183.5 2 187.7 2 70.9 0.00 2 14.45 2 4 5.60 2 9 9 9 9 9 9 7.8175 2 2351 2 44.8 2 9

22 2 648.5 35.553 35.553 2 11.300 11.217 27.182 174.6 2 180.8 2 85.8 0.00 2 17.87 2 4 7.60 2 1.31 6 0.64 6 0.02 6 9 9 9 9 9 9 9

21 2 750.6 35.448 35.453 2 10.293 10.201 27.283 160.8 2 170.4 2 102.3 0.00 2 20.61 2 4 10.20 2 9 9 9 9 9 9 7.7314 2 2342 2 42.2 2 9

20 2 850.3 35.329 35.330 2 9.115 9.018 27.389 152.5 2 159.6 2 120.5 0.00 2 23.44 2 4 13.60 2 0.35 2 0.15 2 0.01 2 9 9 9 9 9 9 9

19 2 949.0 35.238 35.236 2 8.037 7.936 27.486 158.8 2 151.1 2 136.1 0.00 2 25.00 2 4 15.90 2 9 9 9 9 9 9 7.6768 2 2336 2 9 9

18 2 1051.3 35.146 35.146 2 6.845 6.741 27.584 171.1 2 9 0.00 2 25.01 2 4 17.70 2 0.08 2 0.03 2 0.00 2 9 9 9 9 9 9 9

17 2 1248.7 35.121 35.120 2 5.865 5.749 27.695 193.6 2 186.4 2 116.0 0.00 2 23.44 2 4 17.90 2 0.03 2 0.02 2 0.00 2 9 9 9 7.6919 2 2336 3 9 9

16 2 1448.6 35.125 35.124 2 5.238 5.109 27.777 214.8 2 213.9 6 93.1 0.00 2 21.59 2 4 17.90 2 9 9 9 9 9 9 9 9 9 9

15 2 1651.8 35.106 35.105 2 4.711 4.568 27.825 228.5 2 226.9 2 84.2 0.00 2 20.71 2 4 18.90 2 0.01 2 0.01 2 0.01 2 9 9 9 7.7244 2 2335 3 9 9

14 2 1850.8 35.067 35.068 2 4.197 4.041 27.851 238.2 2 237.4 2 77.8 0.00 2 20.22 2 4 20.30 2 9 9 9 9 9 9 9 9 9 9

13 2 2048.0 35.033 35.033 2 3.840 3.670 27.863 243.9 2 242.5 2 75.6 0.00 2 20.22 2 4 22.30 2 0.01 2 0.00 2 0.00 2 9 9 9 7.7314 2 2339 3 9 9

12 2 2251.0 35.001 35.000 2 3.479 3.295 27.875 245.9 2 244.6 2 76.6 0.00 2 20.42 2 4 25.40 2 9 9 9 9 9 9 9 9 9 9

11 2 2448.2 34.981 34.980 2 3.239 3.040 27.884 246.8 2 245.4 2 77.9 0.00 2 20.71 2 4 28.10 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

10 2 2649.0 34.965 34.963 2 3.043 2.827 27.892 247.2 2 247.8 2 77.2 0.00 2 20.81 2 4 30.90 2 9 9 9 9 9 9 9 9 9 9

9 2 2848.8 34.950 34.949 2 2.865 2.633 27.898 247.0 2 246.4 2 80.2 0.00 2 21.00 2 4 33.70 2 9 9 9 9 9 9 9 9 9 9

8 2 3051.7 34.937 34.937 2 2.740 2.489 27.902 247.2 2 246.5 2 81.4 0.00 2 21.20 2 4 35.50 2 0.00 2 0.00 2 0.01 2 9 9 9 7.7288 2 2352 3 9 9

7 2 3419.4 34.919 34.919 2 2.566 2.281 27.907 247.9 2 247.3 2 82.3 0.00 2 21.39 2 4 39.20 2 9 9 9 9 9 9 9 9 9 9

6 2 3741.5 34.907 34.907 2 2.478 2.160 27.909 248.5 2 248.3 2 82.4 0.00 2 21.49 2 4 41.00 2 9 9 9 9 9 9 9 9 9 9

5 2 4050.7 34.900 34.900 2 2.430 2.078 27.912 249.1 2 248.8 2 82.6 0.00 2 21.69 2 4 43.00 2 0.00 2 0.00 2 0.00 2 9 9 9 7.7266 2 9 9 9

4 2 4298.7 34.895 34.895 2 2.402 2.022 27.914 249.1 2 249.2 2 82.7 0.00 2 21.69 2 4 44.50 2 9 9 9 9 9 9 9 9 9 9

3 2 4752.0 34.887 34.886 2 2.378 1.944 27.918 250.7 2 250.5 2 82.0 0.00 2 21.88 2 4 45.80 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

2 2 5151.2 34.883 34.883 2 2.396 1.911 27.921 252.6 2 250.6 2 82.2 0.00 2 21.88 2 4 46.70 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

1 2 5555.2 34.879 34.879 2 2.410 1.871 27.924 252.1 2 251.4 2 81.8 0.00 6 21.98 6 4 47.40 6 0.00 6 0.00 6 0.00 6 9 9 9 7.7203 2 2354 3 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

109
A5R

NOAA Ship Ronald H. Brown

STATION 41 DATE 2/2/1998 LATITUDE 24.500° N

LONGITUDE 38.513° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.9 37.460 37.459 2 23.388 23.387 25.689 220.2 2 214.4 2 -5.8 0.00 2 0.00 2 4 0.80 2 9 9 9 9 295.2 337.5 2 2085.0 6 8.0801 2 2444 2 2446 9 9

35 3 51.2 37.467 37.471 2 23.403 23.392 25.696 215.1 2 214.4 2 -5.8 0.00 2 0.00 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 99.5 37.425 37.436 2 22.877 22.857 25.823 214.7 2 215.1 2 -4.5 0.00 2 0.00 2 4 0.90 2 9 9 9 9 307.7 344.6 2 2093.1 2 8.0679 2 9 2445 9 9

33 2 151.3 36.921 36.897 2 19.898 19.870 26.271 207.6 2 206.1 2 16.7 0.02 2 0.98 2 4 0.80 2 9 9 9 9 365.6 364.3 2 2105.1 2 8.0068 2 2407 2 2411 9 9

32 2 199.5 36.620 36.616 2 18.355 18.320 26.443 203.8 2 203.2 2 26.5 0.01 2 3.22 2 4 1.30 2 9 9 9 9 386.2 361.5 2 2103.9 2 7.9836 2 9 2392 9 9

31 2 221.8 36.565 36.561 2 18.058 18.019 26.477 203.5 2 202.0 2 29.1 0.01 2 3.90 2 4 1.40 2 9 9 9 9 9 9 9 9 9 9

30 2 250.3 36.541 36.534 2 17.884 17.841 26.504 202.3 2 200.2 2 31.7 0.01 2 4.39 2 4 1.60 2 9 9 9 9 403.6 370.5 2 2109.1 2 7.9648 2 2386 2 2385 9 9

29 2 270.6 36.447 36.454 2 17.355 17.309 26.563 201.0 2 198.5 2 35.9 0.01 2 5.27 2 4 1.90 2 9 9 9 9 9 9 9 9 9 9

28 2 297.1 36.392 36.393 2 16.988 16.938 26.610 199.7 2 194.9 2 41.3 0.01 2 6.25 2 4 2.00 2 9 9 9 9 436.6 386.5 2 2118.3 2 7.9410 2 9 2380 9 9

27 2 349.3 36.258 36.261 2 16.162 16.106 26.706 194.3 2 191.3 2 48.9 0.00 2 7.81 2 4 2.40 2 9 9 9 9 9 9 9 9 9 9

26 2 400.3 36.112 36.123 2 15.285 15.223 26.795 192.5 2 191.1 2 53.5 0.00 2 9.08 2 4 3.00 2 9 9 9 9 9 2129.8 2 7.8976 2 2363 2 2365 9 9

25 2 450.7 35.986 35.985 2 14.459 14.391 26.881 189.6 2 188.0 2 60.9 0.00 2 10.74 2 4 4.10 2 9 9 9 9 9 9 9 9 9 9

24 2 500.5 35.834 35.836 2 13.467 13.395 26.974 186.3 2 184.4 2 69.9 0.00 2 12.69 2 4 4.80 2 9 9 9 9 561.5 429.6 2 2142.2 2 7.8430 2 9 2347 9 9

23 2 600.3 35.621 35.618 2 11.911 11.831 27.120 174.0 2 165.2 2 97.9 0.00 2 17.38 2 4 7.30 2 9 9 9 9 9 9 9 9 9 9

22 2 697.3 35.492 35.491 2 10.856 10.768 27.217 151.6 2 149.8 2 119.5 0.00 2 20.90 2 4 9.70 2 9 9 9 9 748.7 514.2 2 2180.4 2 7.7274 2 2332 2 2330 9 9

21 2 800.8 35.325 35.328 2 9.341 9.249 27.347 141.2 2 140.1 2 138.6 0.00 2 24.51 2 4 13.60 2 9 9 9 9 9 9 9 9 9 9

20 2 898.3 35.197 35.198 2 8.142 8.046 27.436 143.3 2 142.2 2 144.4 0.00 2 26.18 2 4 16.40 2 9 9 9 9 9 9 9 9 9 9

19 2 998.6 35.105 35.106 2 7.152 7.052 27.509 157.3 2 153.0 2 140.3 0.01 2 26.67 2 4 18.50 2 9 9 9 9 903.6 529.3 2 2200.8 6 7.6553 2 9 2319 9 9

18 2 1198.0 35.127 35.127 2 6.171 6.058 27.661 185.9 2 185.0 2 115.2 0.00 2 23.93 2 4 18.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1400.7 35.140 35.140 2 5.556 5.428 27.751 209.3 2 207.8 2 96.8 0.00 2 21.88 2 4 17.60 2 9 9 9 9 9 2181.8 2 9 9 9 9

16 2 1592.3 35.129 35.129 2 4.971 4.830 27.813 224.1 2 223.4 2 85.6 0.00 2 20.81 2 4 18.30 2 9 9 9 9 753.1 396.0 2 2176.9 2 7.7248 2 2328 2 2323 9 9

15 2 1801.3 35.091 35.091 2 4.393 4.239 27.849 234.8 2 233.7 2 79.9 0.00 2 20.32 2 4 20.00 2 9 9 9 9 9 9 9 9 9 9

14 2 1999.3 35.058 35.060 2 4.017 3.849 27.865 240.4 2 239.7 2 77.0 0.00 2 20.22 2 4 21.60 2 9 9 9 9 9 2175.7 2 7.7323 2 9 2325 9 9

13 2 2190.6 35.016 35.016 2 3.574 3.394 27.877 243.6 2 244.4 6 75.9 0.00 2 20.22 2 4 24.70 2 9 9 9 9 9 9 9 9 9 9

12 2 2400.3 34.987 34.987 2 3.266 3.071 27.886 247.2 2 246.6 2 76.4 0.00 2 20.42 2 4 27.90 2 9 9 9 9 733.8 354.5 2 2181.5 2 9 9 9 9

11 2 2600.4 34.967 34.966 2 3.045 2.834 27.892 248.5 2 247.0 2 78.0 0.00 2 20.71 2 4 31.00 2 9 9 9 9 9 9 9 9 9 9

10 2 2801.9 34.949 34.948 2 2.850 2.623 27.898 247.1 2 246.0 2 80.7 0.00 2 21.10 2 4 34.30 2 9 9 9 9 9 2190.0 2 9 9 9 9

9 2 3001.8 34.938 34.937 2 2.737 2.492 27.901 246.8 2 246.5 2 81.3 0.00 2 21.30 2 4 36.00 2 9 9 9 9 9 9 9 9 9 9

8 2 3201.5 34.929 34.928 2 2.648 2.384 27.905 247.3 2 246.5 2 82.2 0.00 2 21.39 2 4 38.00 2 9 9 9 9 748.3 350.3 2 2193.4 2 7.7273 2 2345 2 2341 9 9

7 2 3401.6 34.920 34.919 2 2.573 2.289 27.907 247.6 2 247.0 2 82.6 0.00 2 21.49 2 4 39.70 2 9 9 9 9 9 9 9 9 9 9

6 2 3599.5 34.912 34.912 2 2.506 2.203 27.909 248.3 2 247.7 2 82.6 0.00 2 21.59 2 4 41.00 2 9 9 9 9 9 9 9 9 9 9

5 2 3800.9 34.906 34.905 2 2.460 2.135 27.910 249.1 2 248.4 2 82.5 0.00 2 21.69 2 4 42.30 2 9 9 9 9 9 9 9 9 9 9

4 2 4098.7 34.898 34.898 2 2.414 2.057 27.913 248.9 2 248.7 2 82.9 0.00 2 21.79 2 4 43.90 2 9 9 9 9 769.2 355.9 2 2197.7 2 7.7273 2 9 2345 9 9

3 2 4400.6 34.892 34.891 2 2.390 1.998 27.915 249.4 2 248.7 2 83.4 0.00 2 21.98 2 4 45.10 2 9 9 9 9 9 9 9 9 9 9

2 2 4699.0 34.888 34.888 2 2.386 1.958 27.918 249.0 2 248.4 2 84.0 0.00 2 22.08 2 4 46.00 2 9 9 9 9 763.9 352.7 2 2198.9 2 9 2347 2 9 9

1 2 4862.4 34.886 34.885 2 2.382 1.934 27.918 250.0 2 249.9 2 82.7 0.00 6 22.08 2 4 46.40 6 9 9 9 9 9 9 7.7244 2 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

110
A5R

NOAA Ship Ronald H. Brown

STATION 42 DATE 2/3/1998 LATITUDE 24.500° N

LONGITUDE 39.250° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.4 37.498 37.499 2 24.164 24.163 25.487 210.5 2 210.4 2 -4.5 0.00 2 0.00 2 4 0.10 2 1.84 2 1.07 2 0.15 2 9 309.4 364.4 3 2076.3 6 8.0973 2 2459 2 2449 72.6 2 9

35 2 49.2 37.495 37.498 2 24.183 24.172 25.485 210.0 2 210.6 6 -4.8 0.00 2 0.00 2 4 0.10 2 1.85 2 1.07 2 0.17 2 9 231.5 273.3 2 2076.8 2 8.0977 2 2460 2 2450 72.6 2 9

34 2 101.0 37.288 37.278 2 22.756 22.735 25.754 212.1 2 214.8 2 -3.6 0.01 2 0.00 2 4 0.10 2 2.07 6 1.19 6 0.18 6 9 269.4 300.8 2 2094.1 2 8.0622 2 9 2441 66.3 2 9

33 2 150.2 37.009 37.029 2 20.580 20.551 26.156 214.3 2 213.3 2 6.6 0.07 2 0.10 2 4 0.10 2 2.22 2 1.27 2 0.15 2 9 291.9 298.5 2 2098.8 2 8.0285 2 2431 2 2420 55.4 2 9

32 2 191.1 36.856 36.863 2 19.499 19.464 26.331 201.0 2 203.6 2 20.9 0.01 2 1.46 2 4 0.20 2 2.26 2 1.30 2 0.13 2 9 317.2 310.8 2 2105.9 2 7.9978 2 9 2405 55.0 2 9

31 2 220.9 36.695 36.711 2 18.543 18.504 26.455 195.3 2 190.5 2 38.3 0.01 2 3.30 2 4 0.70 2 2.30 2 1.30 2 0.05 2 9 339.3 319.5 2 2110.5 2 7.9797 2 9 2398 51.8 2 9

30 2 249.4 36.589 36.589 2 18.026 17.983 26.506 194.6 2 197.3 2 33.9 0.00 2 4.27 2 4 0.80 2 2.31 2 1.30 2 0.03 2 9 356.4 329.2 2 2109.9 2 7.9688 2 2402 2 2389 51.0 2 9

29 2 270.1 36.520 36.524 2 17.700 17.654 26.535 195.4 2 197.1 2 35.7 0.00 2 4.95 2 4 1.00 2 2.31 2 1.30 2 0.03 2 9 411.9 375.3 2 2112.1 2 7.9570 2 5 2384 9 9

28 2 297.9 36.435 36.443 2 17.259 17.209 26.579 195.1 2 195.8 2 39.1 0.00 2 5.73 2 4 1.30 2 2.33 2 1.29 2 0.03 2 9 425.4 380.4 2 2114.5 2 7.9459 2 5 2379 50.2 2 9

27 2 351.2 36.293 36.303 2 16.474 16.417 26.660 196.0 2 196.4 2 42.3 0.00 2 7.09 2 4 1.70 2 2.31 2 1.26 2 0.03 2 9 444.0 384.8 2 2116.7 2 7.9226 2 5 2366 9 9

26 2 400.8 36.172 36.171 2 15.688 15.624 26.751 190.5 2 190.4 2 52.2 0.00 2 8.84 2 4 2.30 2 2.27 6 1.23 6 0.03 6 9 475.9 399.4 2 2126.9 2 7.9039 2 2371 2 2366 49.5 2 9

25 2 447.0 36.023 36.171 2 14.748 14.680 26.847 187.2 2 187.2 2 60.0 0.00 2 10.49 2 4 2.90 2 2.17 2 1.16 2 0.03 2 9 507.6 409.6 2 2131.3 2 7.8773 2 5 2355 48.6 2 9

24 2 499.1 35.895 35.889 2 13.882 13.809 26.936 183.0 2 182.4 2 69.6 0.00 2 12.44 2 4 3.70 2 2.09 2 1.09 2 0.03 2 9 549.1 427.6 3 2142.2 2 7.8468 2 2362 2 2349 9 9

23 2 598.6 35.675 35.675 2 12.317 12.236 27.085 180.4 2 176.6 2 84.1 0.00 2 15.65 2 4 5.20 2 1.77 2 0.89 2 0.02 2 9 625.0 456.0 2 2153.1 2 7.7977 2 2347 2 2335 46.0 2 9

22 2 700.3 35.522 35.519 2 11.055 10.966 27.205 169.9 2 165.5 2 102.6 0.00 2 18.96 2 4 7.80 2 1.11 2 0.55 2 0.02 2 9 689.4 476.8 2 2165.1 2 7.7557 2 5 2327 9 9

21 2 798.8 35.329 35.332 2 9.375 9.283 27.345 150.3 2 148.0 2 130.5 0.00 2 23.53 2 4 12.40 2 0.39 2 0.18 2 0.00 2 9 805.3 519.6 2 2184.6 2 7.6979 2 2332 2 2321 44.3 2 9

20 2 900.2 35.243 35.240 2 8.329 8.231 27.445 150.5 2 152.4 2 132.9 0.00 2 24.80 2 4 14.80 2 0.22 2 0.09 2 0.00 2 9 841.0 518.3 2 2190.2 2 7.6800 2 5 2318 9 9

19 2 1001.2 35.090 35.090 2 6.863 6.765 27.536 162.6 2 163.8 2 131.5 0.00 2 25.87 2 4 17.50 2 0.08 2 0.04 2 0.00 2 9 875.9 506.1 2 2194.4 6 7.6680 2 2322 2 2317 42.1 2 9

18 2 1200.1 35.080 35.078 2 5.830 5.720 27.665 186.8 2 192.8 2 109.9 0.00 2 23.73 2 4 17.30 2 0.06 2 0.03 2 0.00 2 9 828.0 455.3 2 2183.8 2 7.6866 2 9 2314 9 9

17 2 1397.8 35.098 35.097 2 5.224 5.100 27.756 211.2 2 214.6 2 92.5 0.00 2 21.79 2 4 16.80 2 9 9 9 9 9 2175.7 2 7.7073 2 2323 2 2314 42.1 2 9

16 2 1599.6 35.139 35.139 2 5.007 4.865 27.817 223.9 2 223.3 2 85.5 0.00 2 20.81 2 4 17.60 2 0.03 2 0.01 2 0.00 2 9 750.3 395.3 2 2174.6 2 7.7252 2 2330 2 2321 9 9

15 2 1800.5 35.092 35.092 2 4.435 4.281 27.846 232.9 2 233.8 2 79.5 0.00 2 20.42 2 4 19.20 2 9 9 9 9 9 2173.3 2 7.7302 2 2331 2 2322 41.8 2 9

14 2 1999.4 35.041 35.040 2 3.884 3.718 27.864 242.0 2 242.5 2 75.2 0.00 2 20.23 2 4 21.50 2 0.00 2 0.00 2 0.00 2 9 742.9 370.7 6 2171.3 2 7.7331 2 2325 2 2321 9 9

13 2 2200.6 35.005 35.006 2 3.569 3.388 27.869 244.6 2 244.8 2 75.6 0.00 2 20.52 2 4 23.90 2 9 9 9 9 9 2173.4 2 9 9 42.3 2 9

12 2 2400.4 34.984 34.985 2 3.291 3.095 27.882 243.5 2 246.7 2 76.1 0.00 2 20.72 2 4 26.70 2 0.00 2 0.00 2 0.00 2 9 736.9 356.7 2 2177.2 2 9 9 9 9

11 2 2597.7 34.968 34.970 2 3.101 2.889 27.889 245.1 2 245.8 2 78.7 0.00 2 20.91 2 4 29.40 2 9 9 9 9 9 2181.4 2 7.7305 2 9 2330 41.7 2 9

10 2 2799.8 34.957 34.958 2 2.968 2.739 27.895 244.8 2 246.2 2 79.5 0.00 2 21.01 2 4 31.80 2 0.00 2 0.00 2 0.00 2 9 742.3 353.5 2 2183.2 2 9 9 9 9

9 2 2999.4 34.945 34.946 2 2.839 2.592 27.899 244.6 2 246.2 2 80.8 0.00 2 21.20 2 4 33.70 2 9 9 9 9 9 2186.2 2 7.7285 2 2344 2 2334 41.7 2 9

8 2 3223.9 34.934 34.934 2 2.717 2.449 27.904 245.3 2 246.7 2 81.5 0.00 2 21.40 2 4 35.90 2 0.00 2 0.00 2 0.00 2 9 748.3 351.7 2 2188.4 2 9 9 9 9

7 2 3496.3 34.918 34.919 2 2.573 2.279 27.907 248.3 2 248.1 2 81.5 0.00 2 21.59 2 4 38.80 2 9 9 9 9 9 2190.7 2 7.7266 2 2345 2 2338 41.9 2 9

6 2 3750.1 34.909 34.909 2 2.496 2.176 27.910 249.2 2 248.1 2 82.4 0.00 2 21.79 2 4 40.70 2 0.00 2 0.00 2 0.00 2 9 749.9 348.3 2 2191.8 2 9 9 9 9

5 2 3999.4 34.903 34.903 2 2.458 2.111 27.911 249.1 2 249.2 2 81.9 0.00 2 21.79 2 4 41.80 2 0.00 2 0.00 2 0.00 2 9 9 2193.3 2 7.7271 2 2345 2 2341 41.8 2 9

4 2 4299.9 34.895 34.894 2 2.399 2.019 27.915 249.4 2 249.5 2 82.4 0.00 2 21.98 2 4 43.70 2 0.00 6 0.00 6 0.00 6 9 754.6 348.6 2 2193.6 2 9 9 41.8 2 9

3 2 4599.1 34.890 34.889 2 2.389 1.973 27.917 249.1 2 250.1 2 82.2 0.00 2 22.08 2 4 44.60 2 0.00 2 0.00 2 0.00 2 9 9 2195.6 2 7.7235 2 2346 2 2342 41.4 2 9

2 2 4900.3 34.886 34.885 2 2.389 1.936 27.919 248.8 2 250.3 2 82.3 0.00 2 22.18 2 4 45.50 2 0.00 2 0.00 2 0.00 2 9 9 2197.8 2 9 9 41.8 2 9

1 2 5259.6 34.883 34.883 2 2.406 1.906 27.922 250.3 2 250.7 2 82.2 0.00 6 22.18 6 4 46.10 6 0.00 2 0.00 2 0.00 2 9 766.8 354.4 2 2197.0 2 7.7257 2 2347 2 2344 41.8 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

111
A5R

NOAA Ship Ronald H. Brown

STATION 43 DATE 2/3/1998 LATITUDE 24.500° N

LONGITUDE 39.983° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.0 37.504 37.505 2 24.238 24.237 25.469 211.1 2 210.9 2 -5.3 0.00 2 0.00 2 4 0.50 2 1.86 2 1.08 2 0.15 2 1.82 2 248.7 294.1 3 2080.1 6 8.0982 6 2453 2 2454 9 9

35 2 36.6 37.506 37.505 2 24.125 24.117 25.509 209.8 2 211.1 2 -5.1 0.00 2 0.00 2 4 0.40 2 9 9 9 1.86 2 9 9 9 9 9 9

34 2 79.4 37.264 37.265 2 22.339 22.323 25.853 212.2 2 210.3 2 2.5 0.03 2 0.20 2 4 0.30 2 9 9 9 1.04 6 298.4 327.2 3 2103.9 2 8.0414 2 2447 2 2437 9 9

33 2 119.3 37.182 37.182 2 21.233 21.210 26.106 204.2 2 204.7 2 12.4 0.04 2 0.78 2 4 0.20 2 9 9 9 9 321.7 338.1 3 2111.4 2 8.0215 2 2427 2 2430 9 9

32 2 159.5 36.967 36.953 2 19.953 19.923 26.292 195.2 2 193.3 2 29.2 0.02 2 2.54 2 4 0.30 2 9 9 9 9 9 2118.4 2 7.9897 2 5 2415 9 9

31 2 199.8 36.693 36.688 2 18.628 18.592 26.430 198.7 2 201.0 2 27.4 0.01 2 3.02 2 4 0.90 2 2.31 2 1.31 2 0.05 2 0.77 2 354.5 335.4 3 2107.2 2 7.9867 2 2395 2 2398 9 9

30 2 221.5 36.599 36.598 2 18.193 18.154 26.469 198.8 2 201.1 2 29.4 0.00 2 3.81 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 250.5 36.535 36.535 2 17.828 17.785 26.514 197.8 2 199.6 2 32.6 0.00 2 4.49 2 4 0.90 2 9 9 9 9 377.6 345.8 3 2109.9 2 7.9688 2 2395 2 2389 9 9

28 2 272.6 36.486 36.478 2 17.605 17.558 26.532 199.5 2 200.0 2 33.2 0.00 2 4.98 2 4 1.00 2 9 9 9 0.62 2 9 9 9 9 9 9

27 2 301.0 36.408 36.404 2 17.204 17.153 26.572 202.5 2 201.1 2 34.1 0.00 2 5.56 2 4 1.20 2 9 9 9 9 423.6 378.2 3 2110.6 2 7.9594 2 2389 2 2383 9 9

26 2 350.3 36.274 36.275 2 16.375 16.318 26.668 198.0 2 198.0 2 41.2 0.00 2 7.12 2 4 1.70 2 9 9 9 9 9 9 9 9 9 9

25 2 400.0 36.169 36.169 2 15.655 15.592 26.756 192.6 2 192.4 2 50.4 0.00 2 8.59 2 4 2.00 2 9 9 9 0.53 2 9 2127.3 2 7.9070 2 2367 2 2368 9 9

24 2 450.6 36.038 36.031 2 14.850 14.781 26.837 190.0 2 189.9 2 57.0 0.00 2 10.15 2 4 2.80 2 9 9 9 9 9 9 9 9 9 9

23 2 500.4 35.852 35.843 2 13.740 13.667 26.931 186.5 2 186.4 2 66.5 0.00 2 12.40 2 4 4.00 2 9 9 9 9 498.7 385.5 3 2139.8 2 7.8508 2 2349 2 2348 9 9

22 2 550.8 35.733 35.732 2 12.894 12.817 27.014 183.8 2 182.4 6 75.1 0.00 2 14.16 2 4 4.90 2 1.84 2 0.95 2 0.03 2 0.51 2 9 9 9 9 9 9

21 2 600.9 35.660 35.659 2 12.300 12.219 27.076 179.5 2 179.3 2 81.6 0.00 2 15.33 2 4 5.80 2 9 9 9 9 562.5 409.3 3 2151.3 2 7.8076 2 5 2337 9 9

20 2 701.2 35.471 35.471 2 10.617 10.530 27.243 170.0 2 166.7 2 104.0 0.00 2 19.34 2 4 8.80 2 9 9 9 9 9 9 9 9 9 9

19 2 800.8 35.319 35.317 2 9.216 9.124 27.363 159.0 2 156.8 2 122.7 0.00 2 22.85 2 4 12.60 2 9 9 9 0.23 6 9 2184.3 2 7.7064 2 5 2324 9 9

18 2 899.0 35.219 35.217 2 8.115 8.019 27.458 156.6 2 157.3 2 129.4 0.00 2 24.32 2 4 14.90 2 9 9 9 9 9 9 9 9 9 9

17 2 1000.3 35.185 35.187 2 7.387 7.285 27.539 163.7 2 164.1 2 127.5 0.00 2 24.52 2 4 16.00 2 9 9 9 9 782.4 460.8 3 2195.0 6 7.6798 2 5 2323 9 9

16 2 1151.0 35.119 35.120 2 6.325 6.215 27.634 183.8 2 183.1 2 116.0 0.00 2 23.93 2 4 17.00 2 0.08 2 0.03 2 0.00 2 0.18 2 9 9 9 9 9 9

15 2 1350.2 35.101 35.100 2 5.494 5.372 27.726 208.6 2 207.9 2 97.2 0.00 2 22.08 2 4 16.60 2 9 9 9 9 9 9 9 9 9 9

14 2 1550.7 35.096 35.096 2 4.908 4.772 27.793 224.5 2 224.8 2 84.8 0.00 2 20.90 2 4 17.10 2 9 9 9 9 700.1 366.1 3 2177.0 2 7.7204 2 5 2321 9 9

13 2 1751.6 35.077 35.076 2 4.490 4.340 27.828 234.6 2 234.2 2 78.7 0.00 2 20.22 2 4 18.20 2 0.03 2 0.01 2 0.00 2 0.26 2 9 9 9 9 9 9

12 2 1951.3 35.043 35.041 2 4.011 3.848 27.853 240.3 2 240.9 2 75.8 0.00 2 20.12 2 4 20.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2200.4 35.008 35.008 2 3.563 3.382 27.872 244.3 2 245.7 2 74.7 0.00 2 20.22 2 4 23.90 2 9 9 9 9 9 2176.9 2 7.7332 2 2332 2 2327 9 9

10 2 2447.9 34.981 34.981 2 3.267 3.067 27.882 245.6 2 246.5 2 76.5 0.00 2 20.42 2 4 27.40 2 0.00 2 0.01 2 0.00 2 0.06 2 9 9 9 9 9 9

9 2 2701.1 34.961 34.960 2 3.013 2.793 27.892 244.5 2 246.6 2 78.7 0.00 2 20.81 2 4 31.00 2 9 9 9 9 9 9 9 9 9 9

8 2 2948.7 34.946 34.946 2 2.848 2.606 27.898 244.7 2 246.4 2 80.5 0.00 2 20.91 2 4 33.70 2 0.00 2 0.00 2 0.00 2 0.01 2 680.4 320.4 3 2188.7 2 7.7299 2 2344 2 2337 9 9

7 2 3198.9 34.932 34.931 2 2.689 2.424 27.904 244.7 2 247.3 2 81.1 0.00 2 21.20 2 4 36.50 2 9 9 9 9 9 9 9 9 9 9

6 2 3552.3 34.915 34.915 2 2.542 2.243 27.907 248.8 2 248.2 2 81.7 0.00 2 21.40 2 4 39.70 2 0.00 2 0.00 4 0.00 2 0.01 2 9 9 9 9 9 9

5 2 3800.1 34.906 34.905 2 2.463 2.138 27.910 249.3 2 248.9 2 82.0 0.00 2 21.59 2 4 41.70 2 9 9 9 0.01 2 9 2194.7 2 7.7282 2 5 2343 9 9

4 2 4099.8 34.897 34.896 2 2.408 2.051 27.912 249.6 2 249.5 2 82.1 0.00 2 21.79 2 4 43.40 2 0.00 2 0.00 2 0.00 2 0.01 2 9 9 9 9 9 9

3 2 4457.3 34.892 34.891 2 2.393 1.994 27.915 248.9 2 250.4 2 81.7 0.00 2 21.79 2 4 44.60 2 0.00 2 0.00 2 0.00 2 0.02 2 699.5 321.7 3 2197.2 2 7.7257 2 9 2344 9 9

2 2 4800.1 34.889 34.887 2 2.402 1.961 27.918 249.0 2 250.0 2 82.4 0.00 2 21.88 2 4 45.40 2 0.00 2 0.00 2 0.00 2 0.03 2 9 9 9 9 9 9

1 2 5171.5 34.886 34.887 2 2.435 1.946 27.921 248.2 2 250.3 2 82.2 0.00 6 21.98 6 4 46.10 6 0.00 2 0.00 2 0.00 2 0.04 6 705.0 324.9 3 2197.9 2 7.7232 2 5 2344 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

112
A5R

NOAA Ship Ronald H. Brown

STATION 44 DATE 2/3/1998 LATITUDE 24.500° N

LONGITUDE 40.533° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 37.336 37.345 2 23.481 23.480 25.568 215.0 2 215.1 2 -6.6 0.00 2 0.00 2 4 0.50 2 1.93 2 1.11 2 0.16 2 9 9 9 8.0878 2 9 69.1 2 9

35 3 51.4 37.354 37.355 2 23.267 23.256 25.650 214.7 2 215.8 2 -6.5 0.00 2 0.00 2 4 0.50 2 1.95 2 1.13 2 0.17 2 9 9 9 9 9 67.4 2 9

34 2 101.7 37.319 37.299 2 22.965 22.944 25.718 214.8 2 217.3 2 -6.8 0.00 2 0.00 2 4 0.30 2 9 9 9 9 9 9 8.0750 2 2430 2 65.3 2 9

33 2 150.9 36.707 36.694 2 19.065 19.038 26.325 209.8 2 213.7 6 12.9 0.02 2 0.68 2 4 0.60 2 2.31 6 1.33 6 0.15 6 9 9 9 9 9 55.7 2 9

32 2 187.1 36.625 36.623 2 18.603 18.570 26.383 210.9 2 213.1 2 15.5 0.01 2 1.95 2 4 0.70 2 2.35 2 1.34 2 0.09 2 9 9 9 8.0048 2 2372 2 50.2 2 9

31 2 228.1 36.559 36.551 2 18.226 18.186 26.432 210.1 2 210.9 2 19.5 0.01 2 3.02 2 4 0.80 2 2.36 2 1.34 2 0.06 2 9 9 9 9 9 48.9 2 9

30 2 254.9 36.517 36.509 2 17.987 17.943 26.461 207.4 2 208.9 2 22.6 0.01 2 3.71 2 4 1.10 2 2.34 2 1.33 2 0.05 2 9 9 9 7.9883 2 2377 2 9 9

29 2 278.1 36.455 36.455 2 17.573 17.525 26.517 206.9 2 206.2 2 27.2 0.01 2 4.59 2 4 1.30 2 9 9 9 9 9 9 9 9 48.9 2 9

28 2 304.5 36.407 36.403 2 17.261 17.210 26.557 205.0 2 204.3 2 30.6 0.01 2 5.17 2 4 1.50 2 2.33 2 1.30 2 0.04 2 9 9 9 7.9635 2 2377 2 9 9

27 2 354.9 36.283 36.282 2 16.451 16.393 26.658 200.7 2 200.7 2 38.1 0.01 2 6.83 2 4 2.00 2 9 9 9 9 9 9 9 9 47.4 2 9

26 2 405.9 36.123 36.135 2 15.466 15.402 26.764 197.7 2 196.3 2 47.4 0.01 2 8.59 2 4 3.00 2 2.23 2 1.22 2 0.04 2 9 9 9 7.9113 2 2361 2 9 9

25 2 452.6 36.030 36.031 2 14.883 14.814 26.824 190.4 2 190.6 2 56.2 0.01 2 10.05 2 4 3.20 2 9 9 9 9 9 9 9 9 47.1 2 9

24 2 505.4 35.907 35.903 2 14.038 13.963 26.912 185.8 2 185.1 2 66.1 0.01 2 11.91 2 4 3.90 2 2.06 2 1.08 2 0.04 2 9 9 9 7.8576 2 2360 2 9 9

23 2 602.8 35.709 35.707 2 12.549 12.466 27.066 177.9 2 180.2 2 79.2 0.01 2 14.74 2 4 5.20 2 1.84 2 0.94 2 0.02 2 9 9 9 9 9 44.0 2 9

22 2 705.2 35.506 35.502 2 10.878 10.789 27.224 161.5 2 161.8 2 107.4 0.01 2 19.53 2 4 8.70 2 9 9 9 9 9 9 7.7460 2 2339 2 9 9

21 2 805.8 35.360 35.357 2 9.524 9.430 27.346 150.1 2 149.1 2 128.4 0.01 2 23.34 2 4 12.40 2 0.41 2 0.19 2 0.01 2 9 9 9 9 9 42.0 2 9

20 2 905.6 35.211 35.211 2 8.080 7.983 27.457 148.5 2 150.4 2 136.5 0.01 2 25.39 2 4 15.80 2 9 9 9 9 9 9 7.6722 2 2338 2 9 9

19 2 1000.2 35.114 35.113 2 7.119 7.019 27.520 161.6 2 159.4 2 134.1 0.01 2 25.88 2 4 17.60 2 0.09 2 0.04 2 0.00 2 9 9 9 9 9 9 9

18 2 1199.0 35.067 35.065 2 5.991 5.879 27.636 189.6 2 186.1 2 115.5 0.01 2 24.12 2 4 17.80 2 9 9 9 9 9 9 7.6796 2 2332 2 9 9

17 2 1401.9 35.052 35.052 2 5.159 5.035 27.727 213.8 2 212.4 2 95.3 0.01 2 22.17 2 4 17.20 2 0.05 2 0.02 2 0.00 2 9 9 9 9 9 9 9

16 2 1600.2 35.071 35.071 2 4.792 4.653 27.787 226.3 2 225.6 2 84.9 0.01 2 21.00 2 4 17.50 2 9 9 9 9 9 9 7.7173 2 2327 2 9 9

15 2 1799.2 35.057 35.057 2 4.334 4.181 27.829 236.5 2 235.8 2 78.3 0.01 2 20.41 2 4 18.80 2 9 9 9 9 9 9 9 9 9 9

14 9 2000.3 35.015 2 3.836 3.671 27.849 242.8 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

13 2 2200.9 34.998 34.998 2 3.551 3.371 27.866 245.9 2 246.2 2 74.4 0.01 2 20.41 2 4 23.80 2 0.01 2 0.00 2 0.00 2 9 9 9 7.7324 2 2336 2 9 9

12 9 2399.8 34.982 2 3.312 3.116 27.878 246.6 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

11 2 2576.3 34.969 34.968 2 3.125 2.915 27.887 247.0 2 247.2 2 77.1 0.01 2 20.61 2 4 29.00 2 9 9 9 9 9 9 7.7309 2 2342 2 9 9

10 9 2799.6 34.955 2 2.959 2.730 27.894 246.5 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

9 2 2999.6 34.943 34.943 2 2.814 2.567 27.899 246.3 2 247.3 2 79.9 0.01 2 21.10 2 4 34.40 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

8 2 3200.2 34.931 34.931 2 2.687 2.422 27.903 247.3 2 248.8 2 79.6 0.01 2 21.29 2 4 36.90 2 9 9 9 9 9 9 9 9 9 9

7 2 3395.3 34.920 34.920 2 2.590 2.307 27.906 249.2 2 247.8 2 81.6 0.01 2 21.39 2 4 39.00 2 9 9 9 9 9 9 7.7277 2 9 9 9

6 2 3556.3 34.914 34.913 2 2.525 2.226 27.908 249.7 2 248.6 2 81.5 0.01 2 21.49 2 4 40.40 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

5 2 3799.8 34.906 34.905 2 2.464 2.139 27.910 250.6 2 249.7 2 81.2 0.01 2 21.68 2 4 42.00 2 9 9 9 9 9 9 9 9 9 9

4 2 3999.5 34.900 34.899 2 2.427 2.081 27.912 251.3 2 249.6 2 81.7 0.01 2 21.78 2 4 43.30 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

3 2 4200.4 34.896 34.895 2 2.409 2.040 27.913 251.0 2 250.3 2 81.4 0.01 2 21.78 2 4 44.10 2 9 9 9 9 9 9 9 9 9 9

2 2 4499.8 34.890 34.889 2 2.388 1.984 27.915 251.3 2 250.7 2 81.5 0.01 2 21.98 2 4 45.40 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

1 2 4859.0 34.885 34.884 2 2.382 1.934 27.918 251.5 2 242.4 3 90.2 0.01 6 21.98 6 4 46.40 6 0.00 2 0.00 2 0.00 2 9 9 9 7.7190 2 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

113
A5R

NOAA Ship Ronald H. Brown

STATION 45 DATE 2/4/1998 LATITUDE 24.500° N

LONGITUDE 41.083° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.7 37.409 37.408 2 23.564 23.563 25.598 216.0 2 214.8 2 -6.7 0.00 2 0.00 2 4 0.60 2 9 9 9 9 244.0 281.2 3 2080.2 6 8.0904 2 5 2448 9 9

35 2 30.0 37.410 37.410 2 23.571 23.565 25.600 213.5 2 213.0 6 -4.9 0.00 2 0.00 2 4 0.50 2 9 9 9 9 9 9 9 9 9 9

34 2 78.7 37.390 37.391 2 23.443 23.427 25.629 213.7 2 214.4 2 -5.8 0.00 2 0.00 2 4 0.50 2 9 9 9 9 253.2 290.4 3 2082.8 2 8.0865 2 2440 2 2447 9 9

33 2 127.5 37.303 37.299 2 21.401 21.376 26.153 204.6 2 206.5 2 9.8 0.03 2 0.49 2 4 0.40 2 9 9 9 9 303.5 321.0 3 2115.6 2 8.0234 2 2431 2 2437 9 9

32 2 164.9 36.935 36.926 2 19.787 19.756 26.313 203.7 2 202.8 2 20.4 0.02 2 1.37 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

31 2 198.1 36.799 36.800 2 19.052 19.016 26.403 197.3 2 198.8 2 27.7 0.01 2 2.63 2 4 0.60 2 9 9 9 9 344.4 331.5 3 2112.5 2 7.9888 2 2402 2 2406 9 9

30 2 224.4 36.644 36.637 2 18.285 18.246 26.481 198.8 2 197.5 2 32.5 0.01 2 3.90 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 250.2 36.569 36.572 2 17.906 17.863 26.520 197.0 2 196.3 2 35.5 0.00 2 4.59 2 4 1.00 2 9 9 9 9 374.0 343.5 3 2113.2 2 9 9 9 9

28 2 275.9 36.475 36.472 2 17.410 17.363 26.572 192.8 2 193.5 2 40.6 0.00 2 5.66 2 4 1.30 2 9 9 9 9 9 9 9 9 9 9

27 2 298.9 36.383 36.391 2 16.873 16.823 26.632 191.2 2 190.5 2 46.2 0.00 2 6.73 2 4 1.60 2 9 9 9 9 410.3 361.2 3 2121.3 2 7.9344 2 2376 2 2379 9 9

26 2 350.1 36.270 36.279 2 16.211 16.154 26.703 193.4 2 189.0 2 50.9 0.00 2 7.90 2 4 2.00 2 9 9 9 9 9 9 9 9 9 9

25 2 399.5 36.085 36.095 2 15.091 15.029 26.817 193.5 2 190.5 2 55.1 0.00 2 9.37 2 4 2.50 2 9 9 9 9 475.6 389.3 3 2129.9 2 9 2361 2 9 9

24 2 449.0 35.956 35.954 2 14.252 14.185 26.902 190.0 2 187.3 2 62.7 0.00 2 10.93 2 4 3.30 2 9 9 9 9 9 9 9 9 9 9

23 2 498.5 35.845 35.847 2 13.499 13.427 26.975 188.4 2 185.1 2 69.0 0.00 2 12.40 2 4 3.80 2 9 9 9 9 504.3 386.0 3 2143.3 2 7.8379 2 2346 2 2345 9 9

22 2 598.9 35.642 35.642 2 12.020 11.940 27.116 180.4 2 177.1 2 85.3 0.00 2 15.82 2 4 5.60 2 9 9 9 9 9 2157.5 2 9 9 9 9

21 2 699.9 35.472 35.475 2 10.571 10.484 27.252 163.4 2 157.9 2 113.1 0.00 2 4 4 8.90 2 9 9 9 9 9 9 9 9 9 9

20 2 800.7 35.348 35.354 2 9.406 9.313 27.355 148.2 2 145.1 2 133.1 0.00 2 23.44 2 4 12.10 2 9 9 9 9 749.9 483.1 3 2191.0 2 7.6935 2 2329 2 2325 9 9

19 2 900.2 35.219 35.215 2 8.215 8.118 27.443 146.8 2 147.3 2 138.8 0.00 2 25.20 2 4 15.00 2 9 9 9 9 9 9 9 9 9 9

18 2 1050.7 35.101 35.105 2 6.827 6.724 27.551 165.7 2 164.4 2 131.2 0.00 2 25.49 2 4 17.10 2 9 9 9 9 806.1 463.1 3 2198.0 6 7.6633 2 5 2319 9 9

17 2 1248.6 35.038 35.037 2 5.513 5.401 27.671 195.1 2 196.3 2 108.8 0.00 2 23.44 2 4 17.30 2 9 9 9 9 9 9 9 9 9 9

16 2 1443.7 35.046 35.046 2 5.054 4.927 27.735 212.9 2 213.6 2 94.9 0.00 2 22.07 2 4 16.80 2 9 9 9 9 9 2180.6 2 7.7003 2 2320 2 2316 9 9

15 2 1650.6 35.036 35.035 2 4.455 4.315 27.797 228.5 2 229.9 2 83.2 0.00 2 21.10 2 4 17.80 2 9 9 9 9 9 9 9 9 9 9

14 2 1848.9 35.028 35.028 2 4.122 3.967 27.827 236.4 2 237.8 2 78.0 0.00 2 20.51 2 4 19.10 2 9 9 9 9 9 9 9 9 9 9

13 2 2050.1 35.007 35.008 2 3.736 3.567 27.853 242.6 2 244.0 2 75.0 0.00 2 20.32 2 4 21.70 2 9 9 9 9 685.9 338.5 3 2173.7 2 7.7287 2 2321 2 2321 9 9

12 2 2249.8 34.990 34.990 2 3.448 3.265 27.870 246.2 2 246.4 2 75.0 0.00 2 20.22 2 4 24.20 2 9 9 9 9 9 9 9 9 9 9

11 2 2448.5 34.978 34.977 2 3.276 3.076 27.878 248.4 2 248.2 2 74.8 0.00 2 20.22 2 4 26.10 2 9 9 9 9 9 9 9 9 9 9

10 2 2648.8 34.963 34.963 2 3.079 2.863 27.887 248.9 2 251.1 2 73.6 0.00 2 20.41 2 4 28.60 2 9 9 9 9 9 9 9 9 9 9

9 2 2850.5 34.951 34.950 2 2.911 2.678 27.895 249.8 2 249.8 2 76.5 0.00 2 4 4 31.60 2 9 9 9 9 9 9 9 9 9 9

8 2 3145.5 34.935 34.935 2 2.747 2.486 27.901 249.5 2 249.4 2 78.5 0.00 2 20.90 2 4 34.60 2 9 9 9 9 9 2188.2 2 7.7308 2 2339 2 2337 9 9

7 2 3448.1 34.916 34.916 2 2.557 2.269 27.906 250.2 2 249.1 2 80.6 0.00 2 21.29 2 4 38.60 2 9 9 9 9 9 9 9 9 9 9

6 2 3749.6 34.907 34.906 2 2.475 2.156 27.909 251.0 2 249.5 2 81.2 0.00 2 21.49 2 4 40.50 2 9 9 9 9 9 9 9 9 9 9

5 2 4050.8 34.898 34.899 2 2.427 2.075 27.911 250.4 2 250.1 2 81.3 0.00 2 21.59 2 4 42.30 2 9 9 9 9 706.0 325.6 3 2196.4 2 7.7287 2 2342 2 2345 9 9

4 2 4350.4 34.895 34.895 2 2.419 2.032 27.915 250.4 2 250.2 2 81.6 0.00 2 21.69 2 4 43.30 2 9 9 9 9 9 9 9 9 9 9

3 2 4650.5 34.892 34.891 2 2.420 1.997 27.917 250.8 2 250.3 2 81.8 0.00 2 21.78 2 4 44.00 2 9 9 9 9 9 9 9 9 9 9

2 2 4950.2 34.889 34.889 2 2.431 1.970 27.919 250.5 2 250.3 2 82.0 0.00 2 21.88 2 4 44.60 2 9 9 9 9 9 9 9 9 9 9

1 2 5240.9 34.889 34.888 2 2.467 1.968 27.922 250.2 2 250.7 2 81.6 0.00 6 21.88 6 4 44.90 6 9 9 9 9 731.9 338.5 3 2197.2 2 7.7229 2 2347 2 2343 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

114
A5R

NOAA Ship Ronald H. Brown

STATION 46 DATE 2/4/1998 LATITUDE 24.500° N

LONGITUDE 41.633° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 37.504 37.503 2 24.192 24.191 25.483 214.2 2 210.4 2 -4.6 0.00 2 0.00 2 4 0.30 2 9 9 9 9 243.4 287.4 3 2081.0 6 8.0968 2 2468 2 2454 70.4 2 9

35 2 48.8 37.520 37.520 2 24.215 24.205 25.494 209.2 2 210.4 6 -4.7 0.00 2 0.00 2 4 0.30 2 1.88 2 1.08 2 0.16 2 9 9 2082.6 2 8.0945 2 2464 2 2454 71.0 2 9

34 2 99.1 37.461 37.443 2 23.946 23.925 25.537 209.0 2 212.0 2 -5.2 0.01 2 0.00 2 4 0.30 2 1.94 2 1.10 2 0.19 2 9 255.3 298.4 3 2085.9 2 8.0828 2 2458 2 2448 70.2 2 9

33 2 149.4 37.258 37.256 2 21.521 21.492 26.087 208.3 2 211.2 2 4.7 0.05 2 0.29 2 4 0.30 2 2.15 2 1.24 2 0.16 2 9 302.9 321.8 3 2107.0 2 8.0341 2 2443 2 2435 59.4 2 9

32 2 197.6 36.977 36.977 2 19.857 19.820 26.330 200.4 2 202.0 2 20.9 0.01 2 1.66 2 4 0.50 2 2.27 6 1.29 6 0.09 6 9 335.7 333.7 3 2111.9 2 8.0028 2 2426 2 2416 54.2 2 9

31 2 223.9 36.843 36.844 2 19.216 19.175 26.397 198.7 2 199.3 2 26.5 0.01 2 2.44 2 4 0.60 2 2.26 2 1.28 2 0.07 2 9 9 2112.2 2 7.9913 2 2413 2 2408 52.3 2 9

30 2 252.1 36.667 36.677 2 18.412 18.367 26.470 196.9 2 197.8 2 31.6 0.00 2 3.61 2 4 0.90 2 2.32 2 1.30 2 0.05 2 9 369.5 346.7 3 2109.5 2 7.9763 2 2400 2 2394 51.5 2 9

29 2 273.1 36.521 36.525 2 17.668 17.621 26.544 196.5 2 195.3 2 37.6 0.00 2 5.07 2 4 1.20 2 2.32 2 1.28 2 0.03 2 9 9 2112.8 2 7.9564 2 5 2384 50.8 2 9

28 2 299.6 36.437 36.433 2 17.196 17.146 26.595 194.4 2 192.5 2 42.7 0.00 2 6.24 2 4 1.60 2 2.32 2 1.28 2 0.03 2 9 457.6 408.8 3 2117.6 2 7.9411 2 2391 2 2379 9 9

27 2 350.1 36.331 36.337 2 16.534 16.477 26.675 188.1 2 188.8 2 49.6 0.00 2 7.51 2 4 2.00 2 2.30 2 1.26 2 0.03 2 9 9 2127.5 2 7.9220 2 2385 2 2378 48.3 2 9

26 2 400.2 36.154 36.161 2 15.470 15.407 26.786 186.4 2 184.9 2 58.8 0.00 2 9.47 2 4 2.60 2 2.24 2 1.19 2 0.04 2 9 449.1 373.3 3 2134.6 2 7.8908 2 2372 2 2366 9 9

25 2 449.5 36.002 36.010 2 14.539 14.471 26.876 183.7 2 185.7 2 62.8 0.00 2 10.83 2 4 3.20 2 2.18 2 1.17 2 0.03 2 9 9 2138.7 2 7.8715 2 2367 2 2359 47.9 2 9

24 2 470.4 35.945 35.947 2 14.167 14.097 26.913 185.2 2 185.8 2 64.7 0.00 2 11.42 2 4 3.50 2 2.16 2 1.13 2 0.04 2 9 478.7 376.7 3 2138.9 2 7.8607 2 2357 2 2353 9 9

23 2 527.3 35.798 35.805 2 13.168 13.093 27.008 185.2 2 184.1 2 71.8 0.00 2 13.18 2 4 4.30 2 2.07 2 1.07 2 0.03 2 9 9 2146.4 2 7.8335 2 2352 2 2346 47.6 2 9

22 2 599.8 35.694 35.696 2 12.443 12.361 27.075 180.0 2 180.2 2 79.8 0.00 2 14.94 2 4 5.30 2 1.85 2 0.95 2 0.03 2 9 553.0 404.7 3 2155.5 2 7.8070 2 2346 2 2342 9 9

21 2 697.6 35.538 35.538 2 11.164 11.075 27.198 166.3 2 166.7 2 100.8 0.00 2 18.55 2 4 7.70 2 1.24 2 0.62 2 0.02 2 9 9 2168.0 2 7.7600 2 9 2332 47.6 2 9

20 2 798.9 35.410 35.409 2 10.014 9.918 27.303 146.5 2 148.0 2 126.5 0.00 2 22.46 2 4 11.10 2 0.57 6 0.28 6 0.01 6 9 718.5 474.7 3 2189.0 2 7.7077 2 2336 2 2330 47.4 2 9

19 2 887.8 35.276 35.276 2 8.700 8.601 27.414 140.9 2 141.7 2 141.1 0.00 2 25.29 2 4 14.50 2 0.22 2 0.10 2 0.01 2 9 794.8 496.6 3 2200.5 2 7.6712 2 2335 2 2326 43.2 2 9

18 2 1001.7 35.166 35.173 2 7.420 7.317 27.520 153.4 2 153.5 2 137.9 0.00 2 25.78 2 4 16.80 2 0.10 2 0.04 2 0.00 2 9 817.7 483.0 3 2201.1 6 7.6633 2 9 2323 9 9

17 2 1201.8 35.037 35.037 2 5.750 5.640 27.641 187.8 2 188.3 2 115.0 0.00 2 24.32 2 4 17.90 2 0.05 2 0.02 2 0.00 2 9 814.2 445.4 3 2188.5 2 7.6744 2 2321 2 2314 43.1 2 9

16 2 1399.9 35.043 35.041 2 5.158 5.035 27.720 209.8 2 209.4 2 98.3 0.00 2 22.56 2 4 17.40 2 0.04 2 0.02 2 0.00 2 9 737.7 391.0 3 2183.4 2 7.6985 2 5 2318 9 9

15 2 1600.0 35.043 35.042 2 4.662 4.524 27.779 225.6 2 226.4 2 85.1 0.00 2 21.19 2 4 17.50 2 9 9 9 9 9 2176.3 2 7.7132 2 2325 2 2317 41.8 2 9

14 2 1794.6 35.029 35.029 2 4.201 4.050 27.819 235.7 2 236.7 2 78.5 0.00 2 20.61 2 4 19.10 2 0.02 2 0.01 2 0.00 2 9 9 2173.1 2 7.7233 2 2322 2 2318 9 9

13 2 1998.9 35.017 35.017 2 3.892 3.726 27.845 241.6 2 242.4 2 75.3 0.00 2 20.31 2 4 21.00 2 9 9 9 9 676.9 336.4 3 2172.8 2 7.7294 2 2327 2 2320 41.6 2 9

12 2 2202.1 34.998 34.998 2 3.573 3.392 27.864 245.7 2 245.7 2 74.7 0.00 2 20.31 2 4 23.50 2 0.00 2 0.01 2 0.00 2 9 9 2175.3 2 9 9 9 9

11 2 2400.7 34.981 34.981 2 3.334 3.138 27.875 249.4 2 248.4 2 74.1 0.00 2 20.41 3 4 25.90 2 9 9 9 9 9 2176.8 2 7.7315 2 2329 2 2326 41.6 2 9

10 2 2597.1 34.971 34.973 2 3.194 2.981 27.883 251.5 2 251.3 2 72.4 0.00 2 20.22 2 4 27.30 2 0.02 4 0.01 2 0.00 2 9 675.8 324.2 3 2177.6 2 9 9 9 9

9 2 2798.2 34.957 34.956 2 2.993 2.763 27.892 251.1 2 251.0 2 74.6 0.00 2 20.61 2 4 30.50 2 9 9 9 9 9 2181.3 2 7.7276 2 9 2328 41.4 2 9

8 2 2989.4 34.941 34.942 2 2.821 2.575 27.897 250.1 2 250.6 2 76.5 0.00 2 20.80 2 4 33.50 2 0.01 4 0.00 2 0.00 2 9 9 2184.5 2 9 9 41.4 2 9

7 2 3249.0 34.927 34.928 2 2.663 2.393 27.903 250.0 2 249.4 2 79.3 0.00 2 21.19 2 4 36.70 2 9 9 9 9 687.1 320.6 3 2190.4 2 7.7289 2 2342 2 2339 9 9

6 2 3495.6 34.918 34.918 2 2.569 2.275 27.907 250.4 2 249.6 2 80.1 0.00 2 21.39 2 4 38.90 2 0.00 6 0.00 6 0.00 6 9 9 2191.5 2 9 9 41.4 2 9

5 2 3747.2 34.907 34.907 2 2.485 2.166 27.909 250.2 2 250.0 2 80.6 0.00 2 21.49 2 4 40.90 2 9 9 9 9 9 2194.8 2 7.7284 2 2350 2 2343 9 9

4 2 3999.7 34.902 34.902 2 2.459 2.112 27.911 250.4 2 250.3 2 80.8 0.00 2 21.59 2 4 41.90 2 0.00 2 0.00 2 0.00 2 9 691.8 319.1 3 2196.3 2 9 9 41.2 2 9

3 2 4250.2 34.897 34.897 2 2.431 2.056 27.913 251.3 2 251.0 2 80.6 0.00 2 21.68 2 4 43.10 2 0.00 2 0.00 2 0.00 2 9 9 2196.5 2 7.7262 2 2344 2 2344 9 9

2 2 4497.8 34.893 34.893 2 2.415 2.011 27.916 250.7 2 251.3 2 80.7 0.00 2 21.78 2 4 44.10 2 0.00 2 0.00 2 0.00 2 9 9 2198.9 2 9 9 41.0 2 9

1 2 4779.5 34.890 34.889 2 2.422 1.983 27.918 250.1 2 251.3 2 80.9 0.00 6 21.88 6 4 44.80 6 9 9 9 9 731.4 337.5 3 2199.5 2 7.7268 2 2346 2 2347 41.0 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

115
A5R

NOAA Ship Ronald H. Brown

STATION 47 DATE 2/4/1998 LATITUDE 24.500° N

LONGITUDE 42.183° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.7 37.511 37.510 2 24.144 24.143 25.503 213.2 2 210.6 2 -4.7 0.00 2 0.00 2 4 0.40 2 1.85 2 1.08 2 0.15 2 1.75 2 246.2 290.2 3 2081.3 2 8.0953 2 2461 2 2453 9 9

35 3 45.6 37.508 37.508 2 24.137 24.127 25.508 208.9 2 210.5 2 -4.5 0.00 2 0.00 2 4 0.30 2 9 9 9 1.83 2 246.2 290.1 3 2080.3 6 8.0930 2 2461 2 2451 9 9

34 2 89.3 37.505 37.507 2 24.130 24.111 25.514 208.5 2 211.0 2 -5.0 0.00 2 0.00 2 4 0.20 2 9 9 9 9 247.8 291.9 3 2079.3 2 8.0941 2 5 2450 9 9

33 2 135.7 37.304 37.301 2 21.707 21.680 26.069 210.0 2 197.0 2 18.1 0.05 2 0.20 2 4 0.20 2 9 9 9 1.13 2 298.3 319.7 3 2108.1 2 8.0378 2 5 2439 9 9

32 2 182.1 37.060 37.073 2 20.397 20.362 26.248 196.7 2 199.3 2 21.3 0.02 2 1.85 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

31 2 199.2 36.923 36.929 2 19.706 19.669 26.328 196.0 2 202.1 2 21.5 0.01 2 1.95 2 4 0.60 2 9 9 9 0.96 6 340.7 336.7 3 2112.0 2 7.9978 2 5 2413 9 9

30 2 223.7 36.737 36.740 2 18.846 18.806 26.411 201.0 2 199.6 2 27.9 0.01 2 2.44 2 4 0.70 2 9 9 9 9 9 9 9 9 9 9

29 2 251.8 36.659 36.646 2 18.444 18.399 26.456 200.8 2 200.1 2 29.2 0.01 2 3.61 2 4 0.80 2 9 9 9 9 361.2 339.1 3 9 7.9798 2 2393 2 9 9

28 2 269.4 36.562 36.564 2 17.979 17.932 26.499 199.1 2 197.5 2 34.0 0.00 2 4.20 2 4 1.00 2 9 9 9 9 9 2106.9 2 9 9 9 9

27 2 300.2 36.475 36.476 2 17.477 17.426 26.558 195.1 2 192.8 2 41.0 0.00 2 5.37 2 4 1.30 2 9 9 9 0.61 2 370.9 334.7 3 2112.3 2 7.9576 2 2390 2 2384 9 9

26 2 349.8 36.319 36.327 2 16.545 16.488 26.663 191.3 2 187.8 2 50.5 0.00 2 7.22 2 4 1.90 2 9 9 9 9 9 9 9 9 9 9

25 2 400.9 36.173 36.182 2 15.639 15.576 26.763 186.6 2 189.8 2 53.0 0.00 2 9.08 2 4 2.40 2 9 9 9 0.50 2 431.6 361.2 3 2129.6 2 7.9012 2 5 2367 9 9

24 2 452.3 36.061 36.068 2 14.952 14.883 26.833 188.7 2 186.6 2 59.8 0.00 2 9.86 2 4 2.90 2 9 9 9 9 9 9 9 9 9 9

23 2 502.3 35.899 35.906 2 13.868 13.795 26.941 184.1 2 181.4 2 70.7 0.00 2 11.81 2 4 3.70 2 9 9 9 9 483.4 375.6 3 2139.1 2 7.8557 2 5 2350 9 9

22 2 551.6 35.745 35.756 2 12.846 12.769 27.032 181.2 2 170.1 2 87.6 0.00 2 14.06 2 4 4.70 2 9 9 9 9 9 9 9 9 9 9

21 2 599.7 35.645 35.656 2 12.128 12.047 27.097 175.4 2 159.2 2 102.6 0.00 2 16.40 2 4 6.00 2 9 9 9 0.45 2 582.0 420.3 3 2159.0 2 7.7889 2 5 2336 9 9

20 2 648.8 35.557 35.559 2 11.398 11.314 27.167 160.5 2 160.1 2 106.0 0.00 2 18.94 2 4 7.50 2 9 9 9 9 9 9 9 9 9 9

19 2 702.3 35.513 35.507 2 10.952 10.863 27.216 155.6 2 147.8 2 120.9 0.00 2 19.72 2 4 8.50 2 9 9 9 9 9 9 9 9 9 9

18 2 749.9 35.430 35.434 2 10.253 10.162 27.276 148.3 2 143.8 2 129.2 0.00 2 21.97 2 4 10.50 2 9 9 9 9 9 2182.6 2 7.7152 2 2334 2 2326 9 9

17 2 797.9 35.370 35.373 2 9.758 9.664 27.315 143.6 2 144.9 2 131.2 0.00 2 23.34 2 4 12.00 2 9 9 9 0.21 2 9 9 9 9 9 9

16 2 815.4 35.352 35.352 2 9.554 9.459 27.334 145.1 2 146.4 2 131.0 0.00 2 23.53 2 4 12.40 2 9 9 9 9 746.4 483.9 3 2188.6 2 7.6945 2 2332 2 2323 9 9

15 2 899.4 35.248 35.248 2 8.444 8.346 27.431 145.3 2 169.2 2 115.3 0.00 2 25.29 2 4 15.00 2 9 9 9 9 9 9 9 9 9 9

14 2 1099.9 35.105 35.108 2 6.613 6.506 27.584 168.7 2 201.0 2 96.1 0.00 2 25.30 2 4 17.80 2 9 9 9 0.10 2 9 2195.2 6 7.6693 2 2325 2 2319 9 9

13 2 1300.7 35.028 35.027 2 5.405 5.289 27.677 201.7 2 221.4 2 84.5 0.00 2 23.34 2 4 17.50 2 9 9 9 9 9 9 9 9 9 9

12 2 1500.6 35.045 35.044 2 4.881 4.751 27.754 224.7 2 232.8 2 77.0 0.00 2 21.58 2 4 17.10 2 9 9 9 9 9 2176.3 2 7.7103 2 9 2316 9 9

11 2 1681.7 35.040 35.040 2 4.465 4.322 27.799 235.1 2 243.8 2 69.3 0.00 2 20.71 2 4 17.90 2 9 9 9 0.22 2 9 9 9 9 9 9

10 2 1901.7 35.035 35.034 2 4.122 3.962 27.835 244.0 2 249.0 2 66.8 0.00 2 20.02 2 4 19.00 2 9 9 9 9 9 9 9 9 9 9

9 2 2091.6 35.016 35.016 2 3.756 3.583 27.859 250.1 2 251.2 2 67.6 0.00 2 19.73 2 4 21.60 2 9 9 9 9 676.5 334.1 3 2171.8 2 7.7348 2 5 2322 9 9

8 2 2343.0 34.984 34.985 2 3.329 3.138 27.877 251.2 2 251.0 2 71.5 0.00 2 19.93 2 4 25.70 2 0.03 4 0.02 2 0.01 2 0.19 2 9 9 9 9 9 9

7 2 2601.4 34.959 34.960 2 3.016 2.806 27.889 252.1 2 250.3 2 74.9 0.00 2 20.41 2 4 30.20 2 9 9 9 9 9 2180.7 2 7.7323 2 5 2330 9 9

6 2 2837.0 34.946 34.945 2 2.853 2.622 27.895 250.8 2 248.0 2 78.7 0.00 2 20.71 2 4 33.10 2 0.01 2 0.00 2 0.00 2 0.10 2 9 9 9 9 9 9

5 2 3098.4 34.932 34.932 2 2.700 2.445 27.902 247.6 2 248.7 2 79.5 0.00 2 21.20 2 4 36.50 2 9 9 9 9 712.1 333.5 3 2189.0 2 7.7305 2 5 2338 9 9

4 2 3344.4 34.921 34.922 2 2.597 2.319 27.905 249.5 2 249.5 2 79.8 0.00 2 21.39 2 4 38.80 2 0.00 2 0.00 2 0.01 2 0.02 2 9 9 9 9 9 9

3 2 3596.6 34.913 34.913 2 2.529 2.225 27.908 249.2 2 250.2 2 79.9 0.00 2 21.59 2 4 40.50 2 0.00 2 0.00 2 0.00 2 0.02 2 9 9 9 9 9 9

2 9 4037.2 34.901 2 2.463 2.111 27.911 246.5 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 4037.4 34.902 34.903 2 2.463 2.111 27.912 246.4 2 250.3 6 80.8 0.00 6 21.68 6 4 42.80 6 0.00 2 0.00 2 0.00 2 0.03 6 729.2 337.4 3 2193.1 2 7.7263 2 9 2340 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

116
A5R

NOAA Ship Ronald H. Brown

STATION 48 DATE 2/4/1998 LATITUDE 24.500° N

LONGITUDE 42.733° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.5 37.511 37.513 2 24.051 24.050 25.531 216.0 2 211.1 2 -4.9 0.00 2 0.00 2 4 0.50 2 1.87 2 1.08 2 0.15 2 9 289.9 340.1 3 2079.1 6 8.0977 2 2448 2 2453 9 9

35 2 51.6 37.508 37.506 2 24.055 24.044 25.533 214.0 2 211.2 2 -4.9 0.00 2 0.00 2 4 0.40 2 1.89 2 1.08 2 0.17 2 9 9 9 9 9 9 9

34 2 100.9 37.451 37.450 2 23.811 23.790 25.569 214.6 2 213.0 2 -5.8 0.00 2 0.00 2 4 0.40 2 1.91 6 1.10 6 0.19 6 9 9 9 8.0900 2 2443 2 9 9

33 2 151.3 37.259 37.252 2 21.491 21.461 26.097 214.4 2 211.6 2 4.5 0.05 2 0.20 2 4 0.50 2 2.15 2 1.23 2 0.16 2 9 9 9 9 9 9 9

32 2 185.2 37.054 37.054 2 20.280 20.245 26.275 204.3 2 203.5 2 17.6 0.02 2 1.07 2 4 0.60 2 2.22 2 1.26 2 0.14 2 9 9 9 9 9 9 9

31 2 205.2 36.985 36.982 2 19.938 19.900 26.315 200.3 2 201.9 2 20.7 0.01 2 1.56 2 4 0.60 2 2.25 6 1.28 6 0.11 6 9 9 9 8.0040 2 2429 2 9 9

30 2 231.2 36.722 36.722 2 18.718 18.677 26.433 199.3 2 199.6 2 28.4 0.01 2 3.02 2 4 1.10 2 2.30 2 1.29 2 0.06 2 9 9 9 9 9 9 9

29 2 253.6 36.554 36.555 2 17.893 17.849 26.512 199.7 2 199.5 2 32.3 0.00 2 4.29 2 4 1.60 2 2.32 2 1.29 2 0.04 2 9 9 9 9 9 9 9

28 2 280.9 36.472 36.476 2 17.481 17.433 26.553 199.1 2 198.5 2 35.3 0.00 2 5.17 2 4 1.70 2 2.37 2 1.30 2 0.03 2 9 9 9 7.9616 2 2386 2 9 9

27 2 322.6 36.357 36.361 2 16.828 16.774 26.624 197.5 2 196.4 2 40.6 0.00 2 6.34 2 4 2.10 2 2.32 2 1.27 2 0.03 2 9 9 9 9 9 9 9

26 2 359.0 36.271 36.277 2 16.254 16.196 26.695 188.5 2 188.4 2 51.3 0.00 2 8.10 2 4 2.50 2 2.28 2 1.24 2 0.03 2 9 9 9 9 9 9 9

25 2 450.2 36.004 36.007 2 14.611 14.543 26.862 176.0 2 180.7 2 67.4 0.00 2 11.32 2 4 4.00 2 2.14 2 1.12 2 0.03 2 9 9 9 7.8666 2 2362 2 9 9

24 2 551.7 35.695 35.699 2 12.497 12.422 27.062 173.7 2 170.6 2 89.1 0.00 2 15.81 2 4 6.10 2 1.67 2 0.85 2 0.02 2 9 9 9 9 9 9 9

23 2 649.4 35.545 35.550 2 11.270 11.187 27.182 165.7 2 164.0 2 102.8 0.00 2 18.55 2 4 8.00 2 1.17 2 0.59 2 0.01 2 9 9 9 9 9 9 9

22 2 751.5 35.414 35.413 2 10.133 10.042 27.284 151.5 2 9 0.00 2 22.26 2 4 11.20 2 0.57 2 0.28 2 0.01 2 9 9 9 7.6834 2 2339 2 9 9

21 2 850.3 35.296 35.298 2 8.923 8.827 27.393 146.6 2 152.0 2 129.4 0.00 2 24.51 2 4 14.50 2 0.27 2 0.13 2 0.00 2 9 9 9 9 9 9 9

20 2 950.9 35.140 35.154 2 7.681 7.582 27.461 153.1 2 163.6 2 126.1 0.00 2 25.88 2 4 17.10 2 0.14 6 0.07 6 0.00 6 9 9 9 9 9 9 9

19 2 1051.7 35.041 35.041 2 6.614 6.512 27.532 164.6 2 171.4 2 125.8 0.00 2 26.27 2 4 18.90 2 0.07 2 0.04 2 0.00 2 9 9 9 7.6573 2 2328 3 9 9

18 2 1102.3 35.019 35.020 2 6.249 6.145 27.562 171.5 2 190.1 2 109.7 0.00 2 25.88 2 4 19.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1202.5 35.025 35.024 2 5.758 5.648 27.631 191.6 2 203.1 2 100.2 0.00 2 24.22 2 4 18.70 2 0.09 2 0.04 2 0.01 2 9 9 9 9 9 9 9

16 2 1301.6 35.036 35.035 2 5.465 5.348 27.677 204.4 2 217.9 2 87.5 0.00 2 22.95 2 4 17.90 2 9 9 9 9 9 9 7.6918 2 2330 3 9 9

15 2 1402.2 35.056 35.055 2 5.200 5.076 27.725 219.7 2 226.1 2 81.3 0.00 2 21.49 2 4 16.90 2 0.11 2 0.06 2 0.00 2 9 9 9 9 9 9 9

14 2 1500.6 35.060 35.060 2 4.946 4.815 27.759 228.5 2 231.9 2 77.4 0.00 2 20.90 2 4 17.00 2 9 9 9 9 9 9 9 9 9 9

13 2 1602.5 35.070 35.070 2 4.772 4.633 27.789 233.8 2 238.2 2 72.4 0.00 2 20.41 2 4 17.90 2 9 9 9 9 9 9 7.7235 2 2344 3 9 9

12 2 1703.2 35.063 35.064 2 4.518 4.372 27.812 241.0 2 241.6 2 71.0 0.00 2 20.02 2 4 18.50 2 0.10 2 0.05 2 0.01 2 9 9 9 9 9 9 9

11 2 1848.0 35.052 35.052 2 4.245 4.089 27.835 244.8 2 245.5 2 69.3 0.00 2 19.83 2 4 19.70 2 9 9 9 9 9 9 9 9 9 9

10 2 1999.3 35.038 35.037 2 4.008 3.840 27.850 249.6 2 249.2 2 67.6 0.00 2 19.73 2 4 20.80 2 0.07 2 0.03 2 0.01 2 9 9 9 7.7340 2 2341 3 9 9

9 2 2151.4 35.012 35.013 2 3.695 3.517 27.863 251.5 2 250.4 2 69.0 0.00 2 19.73 2 4 22.80 2 9 9 9 9 9 9 9 9 9 9

8 2 2301.3 34.992 34.993 2 3.422 3.234 27.875 250.7 2 250.5 2 71.2 0.00 2 19.83 2 4 25.40 2 0.04 2 0.02 2 0.00 2 9 9 9 9 9 9 9

7 2 2448.4 34.976 34.975 2 3.215 3.016 27.882 249.7 2 247.5 2 76.0 0.00 2 20.22 2 4 27.80 2 9 9 9 9 9 9 9 9 9 9

6 2 2600.7 34.964 34.964 2 3.070 2.859 27.888 248.2 2 247.3 2 77.5 0.00 2 20.71 2 4 30.30 2 0.00 2 0.00 2 0.00 2 9 9 9 7.7315 2 2345 3 9 9

5 2 2802.5 34.949 34.949 2 2.877 2.649 27.896 248.2 2 247.7 2 78.8 0.00 2 20.90 2 4 33.30 2 9 9 9 9 9 9 9 9 9 9

4 2 3002.8 34.936 34.936 2 2.735 2.490 27.900 248.5 2 248.9 2 78.9 0.00 2 21.20 2 4 35.90 2 0.00 2 0.00 2 0.00 2 9 9 9 9 9 9 9

3 2 3201.9 34.926 34.927 2 2.649 2.385 27.902 251.4 2 249.7 2 79.0 0.00 2 21.20 2 4 37.70 2 0.00 6 0.00 6 0.00 6 9 9 9 9 9 9 9

2 2 3398.2 34.915 2 2.540 2.258 27.905 251.6 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 3514.8 34.913 34.912 2 2.526 2.231 27.907 252.2 2 249.8 2 80.3 0.00 6 21.49 6 4 40.50 6 0.00 6 0.00 6 0.00 6 9 9 9 7.7276 2 2352 3 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

117
A5R

NOAA Ship Ronald H. Brown

STATION 49 DATE 2/4/1998 LATITUDE 24.500° N

LONGITUDE 43.284° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 8.3 37.513 37.514 2 24.306 24.304 25.457 207.4 2 210.0 2 -4.7 0.00 2 0.00 2 4 0.60 2 9 9 9 9 254.6 301.9 3 2079.6 6 8.0835 2 2448 2 2443 9 9

35 2 31.6 37.513 37.514 2 24.309 24.302 25.458 209.3 2 208.8 2 -3.5 0.00 2 0.00 2 4 0.60 2 9 9 9 9 255.6 303.2 3 2081.3 2 9 2447 2 9 9

34 2 61.3 37.513 37.513 2 24.286 24.273 25.469 208.2 2 209.8 2 -4.3 0.00 2 0.00 2 4 0.50 2 9 9 9 9 255.8 303.1 3 2079.4 2 8.0935 2 2448 2 2450 9 9

33 2 110.4 37.470 37.459 2 23.981 23.958 25.534 208.9 2 208.1 2 -1.5 0.01 2 0.00 2 4 0.40 2 9 9 9 9 268.9 314.9 3 2084.7 2 8.0846 2 5 2449 9 9

32 2 161.0 37.119 37.110 2 20.914 20.883 26.151 193.8 2 192.5 2 26.0 0.02 2 1.95 2 4 0.70 2 9 9 9 9 349.9 362.9 3 2120.5 2 8.0013 2 2422 2 2426 9 9

31 2 209.9 36.879 36.882 2 19.443 19.405 26.364 190.7 2 193.3 2 31.5 0.01 2 2.93 2 4 0.70 2 9 9 9 9 367.0 359.0 3 2122.3 2 7.9838 2 5 2414 9 9

30 2 225.8 36.753 36.752 2 18.811 18.771 26.432 191.0 2 194.0 2 33.6 0.01 2 3.61 2 4 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 250.8 36.662 36.655 2 18.369 18.325 26.476 190.1 2 190.6 2 39.0 0.01 2 4.39 2 4 1.00 2 9 9 9 9 391.6 366.7 3 2120.0 2 7.9661 2 2392 2 2399 9 9

28 2 275.3 36.553 36.554 2 17.830 17.782 26.529 191.4 2 195.0 2 37.1 0.00 2 4.97 2 4 1.20 2 9 9 9 9 9 9 9 9 9 9

27 2 303.8 36.438 36.442 2 17.209 17.158 26.594 189.2 2 189.3 2 45.8 0.00 2 6.54 2 4 1.50 2 9 9 9 9 9 2136.4 2 7.9390 2 5 2398 9 9

26 2 401.9 36.156 36.144 2 15.541 15.478 26.772 184.3 2 182.8 2 60.6 0.00 2 9.85 2 4 2.70 2 9 9 9 9 510.0 425.5 3 2137.0 2 7.8885 2 2363 2 2367 9 9

25 2 502.0 35.795 35.795 2 13.290 13.219 26.980 180.1 2 179.8 2 75.5 0.00 2 13.66 2 4 4.60 2 9 9 9 9 9 9 9 9 9 9

24 2 601.8 35.625 35.627 2 11.989 11.909 27.108 173.1 2 173.6 2 89.0 0.00 2 16.40 2 4 6.10 2 9 9 9 9 595.5 427.8 3 2158.5 2 7.7935 2 2331 2 2338 9 9

23 2 693.6 35.492 35.490 2 10.810 10.723 27.225 166.2 2 164.4 2 105.2 0.00 2 19.33 2 4 8.50 2 9 9 9 9 9 9 9 9 9 9

22 2 799.6 35.352 35.351 2 9.473 9.380 27.348 159.4 2 158.2 2 119.6 0.00 2 22.06 2 4 11.60 2 9 9 9 9 727.1 469.3 3 2182.2 2 7.7146 2 9 2325 9 9

21 2 900.6 35.226 35.223 2 8.163 8.066 27.456 156.6 2 158.1 2 128.3 0.00 2 24.31 2 4 14.70 2 9 9 9 9 9 9 9 9 9 9

20 2 997.4 35.131 35.130 2 7.051 6.952 27.543 163.6 2 167.5 2 126.5 0.00 2 24.90 2 4 16.40 2 9 9 9 9 9 2194.9 6 7.6755 2 2322 2 2321 9 9

19 2 1100.0 35.075 35.074 2 6.291 6.187 27.602 180.9 2 179.8 2 119.6 0.00 2 24.51 2 4 17.20 2 9 9 9 9 9 9 9 9 9 9

18 2 1201.4 35.047 35.047 2 5.739 5.629 27.650 199.3 2 194.4 2 109.0 0.00 2 23.53 2 4 17.00 2 9 9 9 9 9 9 9 9 9 9

17 2 1301.3 35.050 35.050 2 5.309 5.194 27.706 212.9 2 209.9 2 96.6 0.00 2 22.26 2 4 16.20 2 9 9 9 9 750.3 400.9 3 2180.0 2 7.7006 2 2320 2 2316 9 9

16 2 1400.6 35.055 35.055 2 5.078 4.955 27.738 222.1 2 219.7 2 88.6 0.00 2 21.39 2 4 15.80 2 9 9 9 9 9 9 9 9 9 9

15 2 1500.4 35.069 35.069 2 4.913 4.782 27.770 229.5 2 227.9 2 81.6 0.00 2 20.60 2 4 15.70 2 9 9 9 9 9 9 9 9 9 9

14 2 1599.3 35.069 35.069 2 4.711 4.573 27.794 236.0 2 234.1 2 77.0 0.00 2 20.12 2 4 15.90 2 9 9 9 9 9 2171.5 2 7.7250 2 2325 2 2317 9 9

13 2 1701.0 35.055 35.054 2 4.416 4.272 27.816 240.9 2 238.9 2 74.5 0.00 2 19.92 2 4 17.10 2 9 9 9 9 9 9 9 9 9 9

12 2 1799.6 35.031 35.030 2 4.082 3.933 27.833 240.0 2 239.7 2 76.4 0.00 2 20.31 2 4 19.40 2 9 9 9 9 9 9 9 9 9 9

11 2 1997.8 35.009 35.009 2 3.725 3.562 27.855 245.4 2 244.4 2 74.6 0.00 2 20.21 2 4 21.80 2 9 9 9 9 9 2172.4 2 7.7304 2 2326 2 2321 9 9

10 2 2197.5 34.995 34.995 2 3.507 3.328 27.867 245.9 2 246.9 2 74.0 0.00 2 20.21 2 4 23.70 2 9 9 9 9 698.2 340.8 3 9 9 9 9 9

9 2 2391.2 34.977 34.977 2 3.252 3.058 27.880 247.4 2 248.1 2 75.0 0.00 2 20.41 2 4 26.70 2 9 9 9 9 9 9 9 9 9 9

8 2 2601.2 34.962 34.962 2 3.055 2.844 27.888 247.7 2 248.4 2 76.5 0.00 2 20.61 2 4 29.50 2 9 9 9 9 9 2181.2 2 7.7310 2 2337 2 2330 9 9

7 2 2800.2 34.952 34.952 2 2.917 2.689 27.895 247.5 2 247.7 2 78.5 0.00 2 20.90 2 4 31.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3001.0 34.937 34.936 2 2.748 2.503 27.899 249.0 2 248.9 2 78.8 0.00 2 21.00 2 4 35.00 2 9 9 9 9 9 9 9 9 9 9

5 2 3200.6 34.925 34.925 2 2.629 2.365 27.903 251.0 2 249.5 2 79.4 0.00 2 21.19 2 4 37.40 2 9 9 9 9 715.0 333.6 3 2189.8 2 7.7297 2 2343 2 2338 9 9

4 2 3400.5 34.918 34.917 2 2.569 2.286 27.905 251.0 2 249.6 2 80.0 0.00 2 21.29 2 4 38.90 2 9 9 9 9 9 9 9 9 9 9

3 2 3600.1 34.914 34.914 2 2.554 2.249 27.907 249.9 2 250.1 2 79.8 0.00 2 21.29 2 4 39.60 2 9 9 9 9 9 9 9 9 9 9

2 2 3761.5 34.912 2 2.543 2.221 27.909 248.6 2 9 9 9 9 9 1 1 1 1 9 9 9 9 9 9

1 2 3762.6 34.912 34.913 2 2.542 2.219 27.909 248.6 2 250.7 6 79.5 0.00 6 21.39 6 4 40.00 6 9 9 9 9 767.1 357.5 3 2191.5 2 7.7279 2 2342 2 2339 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

118
A5R

NOAA Ship Ronald H. Brown

STATION 50 DATE 2/5/1998 LATITUDE 24.500° N

LONGITUDE 43.473° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.2 37.495 37.494 2 24.030 24.029 25.525 214.0 2 213.1 2 -6.8 0.00 2 0.00 2 4 0.40 2 1.89 2 1.09 2 0.15 2 9 256.0 300.3 3 2077.0 6 8.0909 2 2447 2 2445 83.0 2 5.8 2

35 2 44.9 37.494 37.496 2 24.045 24.035 25.525 210.3 2 210.3 2 -4.0 0.00 2 0.00 2 4 0.40 2 1.88 2 1.08 2 0.18 2 9 9 2077.3 2 8.0922 2 2457 2 2446 82.8 2 4.6 2

34 2 90.6 37.239 37.229 2 22.748 22.729 25.718 209.9 2 216.4 2 -5.1 0.01 2 0.00 2 4 0.40 2 2.06 2 1.17 2 0.19 2 9 282.6 316.2 3 2082.6 2 8.0652 2 2425 2 2430 79.5 2 4.2 2

33 2 137.2 36.926 36.923 2 20.254 20.228 26.179 212.9 2 206.7 2 14.6 0.05 2 0.68 2 4 0.60 2 2.26 2 1.28 2 0.14 2 9 329.9 333.2 3 2100.4 2 8.0148 2 9 2411 65.8 2 4.4 2

32 2 181.5 36.777 36.798 2 19.241 19.208 26.336 192.7 2 199.9 2 25.8 0.01 2 2.15 2 4 0.80 2 2.27 2 1.28 2 0.09 2 9 9 2105.6 2 7.9951 2 2405 2 2403 63.3 2 5.4 2

31 2 225.5 36.609 36.607 2 18.340 18.300 26.441 200.4 2 204.3 2 25.5 0.00 2 3.32 2 4 1.00 2 2.27 2 1.22 2 0.00 2 9 359.8 336.5 3 2099.7 2 7.9876 2 9 2390 61.8 2 9

30 2 249.1 36.524 36.524 2 17.899 17.856 26.488 202.8 2 205.3 2 26.6 0.00 2 4.10 2 4 1.30 2 2.31 6 1.27 6 0.02 6 9 9 2100.5 2 7.9848 2 2399 2 2389 60.5 2 7.3 2

29 2 275.1 36.490 36.490 2 17.683 17.636 26.517 201.3 2 200.2 2 32.7 0.00 2 4.68 2 4 1.40 2 2.40 2 1.33 2 0.04 2 9 9 2103.7 2 7.9704 2 9 2383 59.7 2 7.9 2

28 2 301.8 36.468 36.467 2 17.516 17.465 26.542 196.8 2 199.7 2 34.0 0.00 2 5.17 2 4 1.50 2 2.35 2 1.28 2 0.04 2 9 385.4 348.3 3 2108.4 2 7.9627 2 5 2383 9 9

27 2 344.0 36.326 36.343 2 16.645 16.588 26.645 195.8 2 195.7 2 42.1 0.00 2 6.73 2 4 2.00 2 2.32 2 1.27 2 0.04 2 9 9 2116.0 2 7.9368 2 9 2374 57.1 2 9.9 2

26 2 397.9 36.230 36.236 2 16.040 15.976 26.716 193.0 2 193.2 2 47.6 0.00 2 8.00 2 4 2.40 2 2.31 2 1.24 2 0.03 2 9 9 2121.3 2 7.9190 2 2369 2 2369 9 9

25 2 449.4 36.018 36.019 2 14.772 14.704 26.838 189.8 2 188.1 2 59.2 0.00 2 10.54 2 4 3.50 2 2.17 2 1.15 2 0.03 2 9 474.6 383.2 3 2129.1 2 7.8776 2 9 2352 9 9

24 2 500.7 35.921 35.920 2 14.107 14.033 26.908 187.1 2 186.2 2 64.7 0.00 2 11.81 2 4 4.00 2 2.12 2 1.11 2 0.03 2 9 9 2135.5 2 7.8603 2 2348 2 2349 9 9

23 2 548.2 35.816 35.818 2 13.363 13.285 26.984 184.4 2 184.5 2 70.4 0.00 2 13.18 2 4 4.60 2 2.00 2 1.03 2 0.02 2 9 9 2140.9 2 7.8311 2 9 2339 56.0 2 16.2 2

22 2 600.8 35.705 35.712 2 12.531 12.449 27.067 181.9 2 180.5 2 79.0 0.00 2 14.74 2 4 5.50 2 1.80 2 0.91 2 0.02 2 9 573.6 421.7 3 2151.2 2 7.8144 2 2340 2 2341 9 9

21 2 648.7 35.581 35.593 2 11.605 11.520 27.148 178.1 2 174.9 2 89.9 0.00 2 16.89 2 4 6.90 2 1.46 2 0.74 2 0.03 2 9 9 2158.6 2 9 9 9 9

20 2 700.6 35.483 35.483 2 10.746 10.658 27.230 162.8 2 162.3 2 107.7 0.00 2 19.82 2 4 9.20 2 0.92 6 0.47 6 0.01 6 9 707.3 482.9 3 2171.1 2 7.7481 2 2329 2 2329 9 9

19 2 753.2 35.404 35.410 2 9.961 9.871 27.306 161.2 2 154.6 2 120.2 0.00 2 21.29 2 4 10.80 2 0.66 2 0.33 2 0.01 2 9 697.4 459.7 3 2178.1 2 9 9 9 23.6 2

18 2 801.9 35.311 35.315 2 9.117 9.026 27.373 155.4 2 154.5 2 125.6 0.00 2 23.24 2 4 13.10 2 0.39 2 0.19 2 0.01 2 9 747.9 475.4 3 2188.1 2 7.6993 2 2330 2 2325 9 9

17 2 853.4 35.251 35.252 2 8.550 8.456 27.416 153.6 2 153.9 2 129.9 0.00 2 24.22 2 4 14.60 2 0.27 2 0.14 2 0.02 2 9 9 2188.4 2 7.6861 2 9 2319 9 9

16 2 902.4 35.197 35.195 2 8.033 7.937 27.452 156.0 2 155.9 2 131.4 0.00 2 24.91 2 4 15.70 2 0.19 2 0.09 2 0.01 2 9 795.9 482.8 3 2192.2 2 7.6770 2 2319 2 2319 43.9 2 9

15 2 1101.1 35.062 35.062 2 6.190 6.087 27.604 181.4 2 180.3 2 119.8 0.00 2 24.81 2 4 18.00 2 0.08 2 0.04 2 0.00 2 9 9 2191.4 6 9 9 9 9

14 2 1302.7 35.047 35.046 2 5.305 5.190 27.704 212.5 2 210.1 2 96.5 0.00 2 22.37 2 4 16.80 2 0.10 2 0.05 2 0.00 2 9 9 2179.4 2 7.6998 2 2321 2 2315 9 9

13 2 1500.1 35.073 35.072 2 4.947 4.816 27.770 231.7 2 229.0 2 80.3 0.00 2 20.61 2 4 16.00 2 9 9 9 9 712.3 373.5 3 2173.2 2 9 9 42.3 2 23.4 2

12 2 1700.7 35.067 35.066 2 4.476 4.331 27.820 242.5 2 239.5 2 73.4 0.00 2 19.93 2 4 17.50 2 0.10 2 0.05 2 0.00 2 9 9 2170.5 2 7.7284 2 2319 2 2318 9 9

11 2 1900.4 35.040 35.040 2 4.051 3.892 27.846 247.2 2 246.0 2 70.4 0.00 2 19.83 2 4 19.60 2 9 9 9 9 9 2170.5 2 9 9 9 9

10 2 2099.4 35.006 35.006 2 3.591 3.420 27.866 250.1 2 251.5 2 68.7 0.00 2 19.93 2 4 23.00 2 0.04 2 0.02 2 0.00 2 9 694.1 340.3 3 2171.9 2 7.7318 2 2326 2 2321 9 9

9 2 2300.2 34.984 34.985 2 3.330 3.144 27.876 249.5 2 251.0 2 71.4 0.00 2 20.12 2 4 25.90 2 0.02 2 0.01 2 0.00 2 9 9 2173.5 2 9 9 42.0 2 9

8 9 2499.5 34.967 2 3.103 2.901 27.886 251.3 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

7 2 2700.2 34.951 34.952 2 2.903 2.685 27.893 250.2 2 249.8 2 76.4 0.00 2 20.71 2 4 32.20 2 9 9 9 9 9 2183.0 2 9 9 9 9

6 2 2900.1 34.939 34.938 2 2.755 2.520 27.899 249.3 2 248.7 2 78.9 0.00 2 21.10 2 4 35.10 2 0.00 2 0.00 2 0.00 2 9 9 2186.7 2 7.7293 2 5 2335 9 9

5 2 3091.6 34.927 34.928 2 2.652 2.399 27.901 250.8 2 249.7 2 78.9 0.00 2 21.20 2 4 37.20 2 9 9 9 9 704.4 328.9 3 2187.9 2 9 9 41.7 2 9

4 2 3349.5 34.919 34.918 2 2.574 2.296 27.904 248.2 2 250.0 2 79.5 0.00 2 21.39 2 4 39.20 2 0.00 2 0.00 2 0.00 2 9 9 2189.9 2 7.7353 2 2342 2 2341 9 9

3 2 3595.4 34.914 34.914 2 2.550 2.246 27.907 247.1 2 251.5 2 78.4 0.00 2 21.39 2 4 40.00 2 0.00 2 0.00 2 0.00 2 9 9 2190.3 2 9 9 9 9

2 2 3799.7 34.911 2 2.542 2.215 27.909 245.5 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 3799.5 34.910 34.911 2 2.543 2.216 27.908 245.4 2 250.5 6 79.7 0.00 6 21.49 6 4 40.50 6 0.00 6 0.00 6 0.00 2 9 764.4 356.2 3 2191.5 2 9 2348 2 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

119
A5R

NOAA Ship Ronald H. Brown

STATION 51 DATE 2/5/1998 LATITUDE 24.500° N

LONGITUDE 44.386° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.2 37.496 37.495 2 24.282 24.281 25.450 211.0 2 210.7 2 -5.3 0.00 2 0.00 2 4 0.10 2 1.86 2 1.09 2 0.15 2 1.90 2 257.5 305.1 3 2073.1 6 8.1021 2 2452 2 2449 9 9

35 2 48.5 37.496 37.495 2 24.290 24.280 25.453 210.5 2 210.9 2 -5.4 0.00 2 0.00 2 4 0.10 2 9 9 9 1.76 2 9 9 9 9 9 9

34 2 100.0 37.481 37.482 2 24.229 24.208 25.467 210.3 2 211.0 2 -5.3 0.00 2 0.00 2 4 0.10 2 9 9 9 9 253.7 299.9 3 2072.5 2 8.1006 2 2450 2 2447 9 9

33 2 139.6 37.170 37.180 2 21.584 21.556 26.002 202.6 2 207.4 2 8.4 0.04 2 0.39 2 4 0.10 2 9 9 9 1.09 2 9 2101.2 2 8.0333 2 5 2427 9 9

32 2 201.3 36.835 36.861 2 19.448 19.411 26.329 193.2 2 194.9 2 29.9 0.01 2 2.44 2 4 0.40 2 9 9 9 0.78 2 365.5 357.4 3 2112.0 2 7.9921 2 2417 2 2408 9 9

31 2 225.5 36.766 36.753 2 19.078 19.037 26.374 192.9 2 194.6 2 31.9 0.01 2 3.22 2 4 0.60 2 9 9 9 9 9 9 9 9 9 9

30 2 248.9 36.597 36.598 2 18.220 18.176 26.464 193.1 2 194.7 2 35.7 0.01 2 4.39 2 4 1.00 2 9 9 9 0.57 2 414.2 385.5 3 2108.9 2 7.9708 2 2403 3 2389 9 9

29 2 272.9 36.528 36.532 2 17.821 17.774 26.512 193.0 2 194.1 2 38.1 0.01 2 5.07 2 4 1.10 2 9 9 9 9 9 9 9 9 9 9

28 2 299.3 36.464 36.465 2 17.475 17.424 26.549 192.8 2 192.3 2 41.6 0.01 2 5.95 2 4 1.30 2 9 9 9 0.49 2 397.6 358.9 3 2114.2 2 7.9496 2 2389 2 2381 9 9

27 2 352.0 36.362 36.358 2 16.859 16.800 26.623 185.5 2 187.9 2 48.9 0.01 2 7.32 2 4 1.70 2 9 9 9 9 9 9 9 9 9 9

26 2 400.4 36.226 36.227 2 16.035 15.971 26.714 181.3 2 183.5 2 57.4 0.00 2 8.98 2 4 2.20 2 9 9 9 0.44 6 452.1 384.5 3 2128.5 2 7.9041 2 2372 2 2368 9 9

25 2 450.2 36.044 36.047 2 14.922 14.853 26.826 172.9 2 173.7 2 72.8 0.00 2 11.62 2 4 3.20 2 9 9 9 9 9 9 9 9 9 9

24 2 500.6 35.902 35.901 2 14.001 13.927 26.916 179.9 2 176.7 2 74.7 0.00 2 12.79 2 4 3.90 2 9 9 9 0.42 2 9 2142.2 2 7.8449 2 2357 2 2348 9 9

23 2 601.5 35.698 35.696 2 12.572 12.489 27.053 172.6 2 170.6 2 88.7 0.00 2 15.82 2 4 5.50 2 9 9 9 9 589.0 433.7 3 2155.3 2 7.8001 2 2352 3 2338 9 9

22 2 699.3 35.481 35.486 2 10.848 10.760 27.210 159.4 2 156.7 2 112.7 0.00 2 20.12 2 4 8.80 2 9 9 9 0.26 2 9 9 9 9 9 9

21 2 815.4 35.289 35.289 2 9.201 9.108 27.343 149.9 2 148.9 2 130.7 0.00 2 23.83 2 4 13.00 2 9 9 9 9 763.4 487.4 3 2186.0 2 7.6941 2 5 2320 9 9

20 2 902.1 35.176 35.173 2 8.219 8.122 27.408 149.5 2 149.7 6 136.4 0.00 2 25.49 2 4 15.30 2 9 9 9 0.11 2 9 9 9 9 9 9

19 2 1000.8 35.105 35.112 2 7.018 6.919 27.527 160.6 2 163.5 2 130.7 0.00 2 25.40 2 4 16.80 2 9 9 9 9 818.2 474.4 3 2193.5 6 7.6690 2 5 2317 9 9

18 2 1100.2 35.042 35.045 2 6.121 6.018 27.597 179.1 2 179.1 2 121.5 0.00 2 25.01 2 4 17.70 2 9 9 9 9 9 9 9 9 9 9

17 2 1200.7 35.027 35.026 2 5.681 5.572 27.642 190.7 2 191.2 6 112.6 0.00 2 24.23 2 4 17.50 2 9 9 9 0.23 6 9 9 9 9 9 9

16 2 1300.5 35.039 35.038 2 5.331 5.216 27.694 207.6 2 206.7 2 99.7 0.00 2 22.76 2 4 16.70 2 9 9 9 9 9 9 9 9 9 9

15 2 1398.8 35.044 35.044 2 5.135 5.012 27.724 217.9 2 214.9 2 93.0 0.00 2 21.98 2 4 16.20 2 9 9 9 9 9 9 9 9 9 9

14 2 1500.1 35.047 35.049 2 4.820 4.690 27.763 225.9 2 225.7 2 84.6 0.00 2 21.10 2 4 16.30 2 9 9 9 9 743.3 388.1 3 2172.4 2 7.7131 2 2326 3 2313 9 9

13 2 1600.7 35.052 35.051 2 4.631 4.494 27.789 232.4 2 231.2 2 80.5 0.00 2 20.71 2 4 16.80 2 9 9 9 9 9 9 9 9 9 9

12 2 1799.8 35.035 35.035 2 4.187 4.036 27.826 238.6 2 240.2 2 75.1 0.00 2 20.22 2 4 18.40 2 9 9 9 9 9 9 9 9 9 9

11 2 2000.9 35.013 35.013 2 3.785 3.620 27.852 246.3 2 245.9 2 72.7 0.00 2 20.03 2 4 20.90 2 9 9 9 9 9 9 9 9 9 9

10 2 2201.2 34.995 34.994 2 3.467 3.288 27.871 250.2 2 249.3 2 71.9 0.00 2 20.03 2 4 23.40 2 9 9 9 9 9 9 9 9 9 9

9 2 2400.0 34.977 34.978 2 3.242 3.047 27.881 250.8 2 250.8 2 72.4 0.00 2 20.03 2 4 26.10 2 0.02 2 0.01 2 0.00 2 0.15 2 9 9 9 9 9 9

8 2 2601.5 34.957 34.958 2 2.978 2.768 27.890 250.1 2 250.8 2 74.7 0.00 2 20.52 2 4 29.90 2 9 9 9 9 703.1 334.1 3 2179.8 2 7.7319 2 5 2329 9 9

7 2 2801.4 34.947 34.949 2 2.875 2.647 27.895 249.1 2 249.9 2 76.6 0.00 2 20.71 2 4 31.90 2 0.01 2 0.01 2 0.00 2 0.08 2 9 9 9 9 9 9

6 2 2999.5 34.935 34.935 2 2.731 2.486 27.899 249.4 2 250.4 2 77.5 0.00 2 20.91 2 4 34.60 2 9 9 9 9 9 9 9 9 9 9

5 2 3250.1 34.926 34.926 2 2.654 2.385 27.903 250.7 2 250.6 2 78.1 0.00 2 21.10 2 4 36.50 2 0.01 2 0.00 2 0.00 2 0.08 2 9 9 9 9 9 9

4 2 3473.5 34.921 34.921 2 2.616 2.323 27.905 250.0 2 250.5 2 78.8 0.00 2 21.20 2 4 37.60 2 9 9 9 0.07 2 9 9 9 9 9 9

3 2 3741.1 34.914 34.914 2 2.567 2.246 27.908 252.1 2 252.5 2 77.4 0.00 2 21.20 2 4 38.40 2 0.00 2 0.00 2 0.00 2 0.08 2 9 9 9 9 9 9

2 2 4012.1 34.910 2 2.563 2.211 27.910 251.0 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 4013.3 34.910 34.911 2 2.563 2.211 27.910 251.0 2 251.4 6 78.8 0.00 6 21.40 6 4 39.40 6 0.00 2 0.00 2 0.00 2 0.07 6 750.2 349.7 3 2188.9 2 7.7288 2 5 2337 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

120
A5R

NOAA Ship Ronald H. Brown

STATION 52 DATE 2/5/1998 LATITUDE 24.500° N

LONGITUDE 44.934° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.7 37.501 37.502 2 24.339 24.338 25.437 210.5 2 212.1 2 -6.9 9 9 9 9 1.86 2 1.07 2 0.15 2 9 316.9 375.6 3 2074.4 6 8.1021 2 2457 6 2451 70.0 2 9

35 3 35.7 37.500 37.500 2 24.329 24.321 25.443 210.5 2 211.2 2 -5.9 0.00 2 0.00 2 4 1.20 2 1.87 2 1.07 2 0.17 2 9 9 9 9 9 70.6 2 9

34 2 70.2 37.496 37.496 2 24.319 24.304 25.447 210.6 2 210.9 2 -5.5 0.00 2 0.00 2 4 1.10 2 9 9 9 9 9 9 9 9 69.3 2 9

33 2 110.9 37.488 37.488 2 24.224 24.200 25.475 217.0 2 211.3 2 -5.6 0.00 2 0.00 2 4 1.10 2 1.88 2 1.09 2 0.15 2 9 9 9 9 9 68.1 2 9

32 2 161.2 37.055 37.046 2 20.580 20.549 26.192 192.7 2 195.2 2 24.7 0.02 2 1.66 2 4 1.30 2 2.14 2 1.23 2 0.13 2 9 9 9 9 9 55.6 2 9

31 2 211.3 36.810 36.809 2 19.233 19.195 26.366 187.5 2 185.2 2 40.5 0.01 2 4.10 2 4 1.60 2 2.24 2 1.27 2 0.06 2 9 9 9 9 9 52.4 2 9

30 2 235.5 36.706 36.698 2 18.694 18.652 26.427 184.0 2 187.3 2 40.9 0.01 2 4.68 2 4 1.80 2 2.28 2 1.26 2 0.04 2 9 9 9 9 9 51.7 2 9

29 2 254.6 36.600 36.598 2 18.165 18.120 26.480 191.5 2 194.0 2 36.6 0.00 2 4.59 2 4 1.70 2 2.31 2 1.29 2 0.04 2 9 9 9 9 9 49.0 2 9

28 2 273.0 36.548 36.555 2 17.894 17.847 26.509 193.6 2 196.1 2 35.8 0.00 2 4.78 2 4 1.70 2 9 9 9 9 9 9 9 9 9 9

27 2 313.8 36.459 36.456 2 17.438 17.385 26.555 195.8 2 194.7 2 39.3 0.00 2 5.76 2 4 2.00 2 2.31 2 1.27 2 0.03 2 9 9 9 9 9 44.8 2 9

26 2 366.1 36.313 36.312 2 16.550 16.490 26.659 186.9 2 184.7 2 53.6 0.00 2 8.20 2 4 2.50 2 2.27 2 1.24 2 0.03 2 9 9 9 9 9 9 9

25 2 425.0 36.108 36.129 2 15.332 15.266 26.783 183.8 2 179.3 2 65.1 0.00 2 10.35 2 4 3.40 2 2.16 2 1.16 2 0.03 2 9 9 9 9 9 9 9

24 2 484.0 35.903 35.913 2 14.039 13.968 26.908 176.5 2 174.1 2 77.1 0.00 2 12.98 2 4 4.50 2 1.91 2 1.00 2 0.03 2 9 9 9 9 9 9 9

23 2 550.6 35.728 35.740 2 12.836 12.759 27.021 170.0 2 168.1 2 89.7 0.00 2 15.62 2 4 5.90 2 1.57 6 0.81 6 0.02 6 9 9 9 9 9 44.1 2 9

22 2 648.8 35.567 35.566 2 11.602 11.517 27.138 160.3 2 159.3 6 105.6 0.00 2 18.85 2 4 8.10 2 1.07 2 0.55 2 0.02 2 9 9 9 9 9 9 9

21 3 751.8 35.379 35.380 2 10.043 9.953 27.272 147.2 2 147.7 2 126.6 0.00 2 22.66 2 4 11.60 2 0.53 2 0.28 2 0.01 2 9 9 9 9 9 9 9

20 2 849.2 35.219 35.218 2 8.695 8.601 27.368 147.0 2 146.7 2 136.3 0.00 2 25.20 2 4 14.90 2 0.25 2 0.13 2 0.00 2 9 9 9 9 9 9 9

19 2 951.8 35.069 35.070 2 7.272 7.176 27.462 152.1 2 151.8 2 140.8 0.00 2 26.96 2 4 18.20 2 0.10 2 0.05 2 0.00 2 9 9 9 9 9 42.0 2 9

18 2 1050.6 35.012 35.011 2 6.345 6.246 27.543 164.9 2 164.0 2 135.1 0.00 2 26.77 2 4 19.40 2 0.06 2 0.03 2 0.01 2 9 9 9 9 9 9 9

17 2 1146.9 35.001 35.000 2 5.842 5.737 27.600 176.4 2 177.5 2 125.2 0.00 2 25.79 2 4 19.30 2 9 9 9 9 9 9 9 9 9 9

16 2 1249.9 35.014 35.014 2 5.513 5.401 27.652 196.8 2 194.6 2 110.5 0.00 2 24.13 2 4 18.20 2 0.07 2 0.03 2 0.01 2 9 9 9 9 9 41.8 2 9

15 2 1349.3 35.039 35.038 2 5.255 5.135 27.704 213.5 2 212.2 2 94.8 0.00 2 22.18 2 4 16.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1451.6 35.055 35.051 2 5.008 4.881 27.747 227.9 2 225.9 2 82.9 0.00 2 21.00 2 4 15.70 2 0.12 6 0.07 6 0.01 6 9 9 9 9 9 9 9

13 2 1551.0 35.069 35.069 2 4.891 4.756 27.773 231.9 2 230.3 2 79.4 0.00 2 20.52 2 4 15.90 2 9 9 9 9 9 9 9 9 43.0 2 9

12 2 1649.7 35.065 35.065 2 4.568 4.427 27.807 238.6 2 238.0 2 74.2 0.00 2 20.03 2 4 16.80 2 0.09 2 0.05 2 0.01 2 9 9 9 9 9 9 9

11 2 1850.9 35.043 35.043 2 4.131 3.976 27.839 244.2 2 244.2 2 71.5 0.00 2 19.93 2 4 19.10 2 0.08 2 0.04 2 0.00 2 9 9 9 9 9 9 9

10 2 2051.7 35.018 35.018 2 3.757 3.588 27.860 249.4 2 248.8 2 70.0 0.00 2 19.83 2 4 21.40 2 0.07 2 0.04 2 0.00 2 9 9 9 9 9 9 9

9 2 2250.3 34.992 34.991 2 3.421 3.238 27.873 248.9 2 250.0 2 71.6 0.00 2 20.13 2 4 25.00 2 0.02 2 0.02 2 0.01 2 9 9 9 9 9 42.1 2 9

8 2 2449.4 34.976 34.976 2 3.224 3.025 27.882 249.3 2 250.1 2 73.3 0.00 2 20.32 2 4 27.50 2 0.01 2 0.01 2 0.01 2 9 9 9 9 9 9 9

7 2 2651.8 34.954 34.953 2 2.935 2.721 27.892 249.8 2 250.2 2 75.7 0.00 2 20.71 2 4 31.80 2 0.01 2 0.00 2 0.01 2 9 9 9 9 9 9 9

6 2 2850.3 34.940 34.939 2 2.781 2.550 27.897 250.7 2 250.2 2 77.1 0.00 2 20.91 2 4 34.50 2 0.01 2 0.00 2 0.00 2 9 9 9 9 9 9 9

5 2 3050.3 34.931 34.930 2 2.693 2.444 27.900 253.6 2 249.3 2 78.9 0.00 2 21.10 2 4 36.10 2 9 9 9 9 9 9 9 9 41.9 2 9

4 2 3251.9 34.927 34.926 2 2.672 2.402 27.902 253.4 2 251.3 2 77.3 0.00 2 21.10 2 4 36.90 2 0.01 2 0.00 2 0.00 2 9 9 9 9 9 9 9

3 2 3449.6 34.923 34.922 2 2.640 2.349 27.905 253.8 2 236.8 4 92.3 0.00 2 21.20 2 4 37.70 2 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

2 2 3634.4 34.920 2 2.628 2.317 27.906 253.4 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 3633.2 34.919 34.919 2 2.627 2.317 27.906 253.3 2 251.9 6 77.4 0.00 6 21.20 6 4 38.20 6 0.00 2 0.00 2 0.00 2 9 9 9 9 9 41.5 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

121
A5R

NOAA Ship Ronald H. Brown

STATION 53 DATE 2/5/1998 LATITUDE 24.500° N

LONGITUDE 45.484° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.2 37.452 37.452 2 24.180 24.179 25.448 211.2 2 211.7 2 -5.8 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 267.9 316.1 3 2071.9 2 8.1034 2 2444 2 2449 9 9

35 3 51.7 37.454 37.454 2 24.188 24.177 25.453 211.1 2 211.6 2 -5.7 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 258.9 305.5 3 2071.3 6 8.1024 2 2444 2 2447 9 9

34 2 102.1 37.433 37.419 2 24.072 24.050 25.478 211.9 2 212.5 2 -6.2 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

33 2 149.6 36.929 36.928 2 20.172 20.144 26.204 201.0 2 201.9 2 19.8 0.02 2 1.07 2 0.04 2 0.90 2 9 9 9 9 9 9 9 9 9 9

32 2 201.0 36.646 36.653 2 18.557 18.521 26.413 196.5 2 199.5 2 29.3 0.01 2 3.22 2 0.12 2 1.30 2 9 9 9 9 365.7 344.8 3 2101.7 2 7.9906 2 2392 2 2395 9 9

31 2 225.9 36.569 36.568 2 18.139 18.100 26.460 198.1 2 200.1 2 30.6 0.00 2 4.10 2 0.17 2 1.50 2 9 9 9 9 9 9 9 9 9 9

30 2 250.5 36.495 36.496 2 17.716 17.673 26.510 198.0 2 197.9 2 34.8 0.00 2 4.98 2 0.24 2 1.80 2 9 9 9 9 391.3 356.7 3 2106.1 2 7.9675 2 2380 2 2384 9 9

29 2 276.1 36.444 36.434 2 17.408 17.361 26.548 197.7 2 196.7 2 37.5 0.00 2 5.76 2 0.28 2 2.00 2 9 9 9 9 9 9 9 9 9 9

28 2 300.6 36.366 36.359 2 16.942 16.892 26.602 195.5 2 196.4 2 40.0 0.00 2 6.44 2 0.33 2 2.20 2 9 9 9 9 444.2 392.5 3 9 7.9435 2 2374 2 9 9

27 2 351.7 36.235 36.238 2 16.147 16.090 26.691 194.9 2 193.9 2 46.4 0.00 2 7.90 2 0.42 2 2.70 2 9 9 9 9 9 9 9 9 9 9

26 2 401.2 36.112 36.110 2 15.413 15.350 26.766 190.2 2 186.8 2 57.2 0.00 2 9.76 2 0.54 2 3.50 2 9 9 9 9 462.1 383.3 3 2129.0 2 7.8955 2 2357 2 2363 9 9

25 2 451.1 35.978 35.975 2 14.579 14.511 26.849 179.1 2 176.8 2 71.6 0.00 2 12.10 2 0.68 2 4.40 2 9 9 9 9 9 9 9 9 9 9

24 2 501.3 35.819 35.819 2 13.523 13.451 26.951 175.9 2 174.2 2 79.8 0.00 2 14.06 2 0.80 2 5.50 2 9 9 9 9 9 9 9 9 9 9

23 2 552.0 35.707 35.707 2 12.717 12.641 27.029 174.5 2 172.7 2 85.8 0.00 2 15.52 2 0.90 2 6.40 2 9 9 9 9 9 9 9 9 9 9

22 2 600.9 35.621 35.621 2 12.056 11.976 27.092 172.7 2 170.2 2 92.1 0.00 2 16.89 2 0.99 2 7.30 2 9 9 9 9 600.2 432.5 3 2158.6 2 7.7917 2 2337 2 2338 9 9

21 2 680.3 35.482 35.482 2 10.910 10.824 27.199 165.5 2 163.9 2 105.1 0.00 2 19.43 2 1.17 2 9.40 2 9 9 9 9 9 9 9 9 9 9

20 2 799.0 35.266 35.267 2 9.034 8.944 27.350 153.0 2 152.6 2 128.1 0.00 2 23.63 2 1.48 2 13.90 2 9 9 9 9 768.2 486.9 3 2187.4 2 7.6966 2 9 2324 9 9

19 2 900.5 35.094 35.094 2 7.575 7.482 27.438 151.5 2 151.4 2 139.1 0.00 2 26.37 2 1.69 2 17.60 2 9 9 9 9 851.9 507.3 3 2197.6 2 7.6590 2 9 2319 9 9

18 2 1000.8 35.031 35.033 2 6.677 6.580 27.514 163.2 2 163.2 6 133.5 0.00 2 26.27 2 1.70 2 18.80 2 9 9 9 9 855.7 489.5 3 2197.6 6 7.6550 2 2325 2 2317 9 9

17 2 1101.3 34.999 34.999 2 5.872 5.771 27.594 181.5 2 181.3 2 121.2 0.00 2 25.00 2 1.65 2 19.00 2 9 9 9 9 9 9 9 9 9 9

16 2 1201.1 35.016 35.017 2 5.630 5.522 27.639 193.9 2 193.8 2 110.4 0.00 2 23.93 2 1.57 2 18.30 2 9 9 9 9 802.4 436.2 3 2187.9 2 7.6769 2 5 2316 9 9

15 2 1298.4 35.030 35.031 2 5.271 5.156 27.694 209.8 2 210.4 2 96.5 0.00 2 22.37 2 1.47 2 17.20 2 9 9 9 9 9 9 9 9 9 9

14 2 1400.3 35.055 35.054 2 4.989 4.867 27.748 225.7 2 226.2 2 82.7 0.00 2 20.80 2 1.36 2 16.20 2 9 9 9 9 9 9 9 9 9 9

13 2 1499.4 35.066 35.065 2 4.809 4.680 27.779 232.7 2 233.3 2 77.0 0.00 2 20.22 2 1.33 2 16.10 2 9 9 9 9 713.8 371.8 3 2173.5 2 7.7221 2 2330 2 2320 9 9

12 2 1601.9 35.074 35.074 2 4.684 4.546 27.801 236.4 2 236.7 2 74.6 0.00 2 19.92 2 1.31 2 16.80 2 9 9 9 9 9 9 9 9 9 9

11 2 1700.6 35.063 35.063 2 4.412 4.268 27.824 240.9 2 241.0 2 72.4 0.00 2 19.73 2 1.30 2 17.90 2 9 9 9 9 9 9 9 9 9 9

10 2 1798.9 35.037 35.037 2 4.074 3.925 27.839 243.4 2 243.4 2 72.7 0.00 2 19.92 2 1.31 2 19.70 2 9 9 9 9 9 9 9 9 9 9

9 2 1900.4 35.026 35.026 2 3.887 3.731 27.851 246.9 2 247.0 2 70.7 0.00 2 19.73 2 1.30 2 20.90 2 9 9 9 9 9 9 9 9 9 9

8 2 1999.5 35.016 35.017 2 3.747 3.583 27.858 248.2 2 248.0 2 70.8 0.00 2 19.73 2 1.31 2 22.10 2 9 9 9 9 711.8 352.1 3 2172.3 2 7.7333 2 2330 2 2323 9 9

7 2 2099.8 35.001 35.001 2 3.539 3.369 27.867 249.6 2 249.9 2 70.7 0.00 2 19.83 2 1.32 2 23.80 2 9 9 9 9 9 9 9 9 9 9

6 2 2299.8 34.985 34.985 2 3.328 3.142 27.877 248.6 2 249.7 2 72.7 0.00 2 20.12 2 1.35 2 26.50 2 9 9 9 9 9 9 9 9 9 9

5 2 2500.2 34.966 34.965 2 3.078 2.876 27.887 250.7 2 250.6 2 74.0 0.00 2 20.32 2 1.36 2 29.70 2 9 9 9 9 9 9 9 9 9 9

4 2 2702.0 34.947 34.947 2 2.858 2.641 27.894 250.3 2 250.9 2 75.7 0.00 2 20.61 2 1.39 2 33.20 2 9 9 9 9 9 9 9 9 9 9

3 2 2901.6 34.939 34.939 2 2.780 2.544 27.897 251.2 2 251.6 2 75.8 0.00 2 20.71 2 1.40 2 34.80 2 9 9 9 9 9 9 9 9 9 9

2 2 3100.0 34.932 34.932 2 2.724 2.469 27.900 251.7 2 251.0 2 77.0 0.00 2 20.81 2 1.41 2 36.10 2 9 9 9 9 9 9 9 9 9 9

1 2 3344.1 34.929 34.930 2 2.719 2.438 27.901 251.6 2 251.5 2 76.8 0.00 6 21.00 6 1.41 6 36.70 6 9 9 9 9 719.9 337.6 3 2187.0 2 7.7303 2 2344 2 2337 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

122
A5R

NOAA Ship Ronald H. Brown

STATION 54 DATE 2/5/1998 LATITUDE 24.500° N

LONGITUDE 46.034° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.9 37.456 37.456 2 24.178 24.177 25.451 214.5 2 211.6 2 -5.7 0.00 2 0.00 2 0.00 2 1.10 2 1.87 2 1.08 2 0.15 2 9 272.3 321.1 3 2075.1 2 8.0977 2 9 2448 73.5 2 9

35 2 39.8 37.456 37.461 2 24.187 24.178 25.453 211.5 2 211.7 2 -5.9 0.00 2 0.00 2 0.01 2 1.00 2 1.89 2 1.08 2 0.16 2 9 9 2072.8 6 8.1014 2 2445 2 2448 72.0 2 9

34 2 80.7 37.472 37.401 2 24.172 24.155 25.475 215.2 2 212.8 2 -6.8 0.00 2 0.00 2 0.01 2 0.80 2 1.94 6 1.11 6 0.18 6 9 278.9 328.8 3 2080.4 2 8.0857 2 2441 2 2444 69.1 2 9

33 2 120.8 37.086 37.087 2 21.437 21.413 25.977 208.7 2 213.2 2 3.3 0.06 2 0.10 2 0.02 2 0.80 2 2.19 2 1.23 2 0.15 2 9 316.1 334.7 3 2097.8 2 8.0362 2 9 2425 59.0 2 9

32 2 170.6 36.828 36.822 2 19.479 19.448 26.312 197.8 2 199.8 2 24.9 0.01 2 1.95 2 0.08 2 1.00 2 2.31 2 1.28 2 0.09 2 9 9 2109.7 2 9 2399 2 54.3 2 9

31 2 216.3 36.621 36.621 2 18.426 18.388 26.427 198.7 2 200.6 2 28.8 0.01 2 3.41 2 0.15 2 1.20 2 2.32 2 1.30 2 0.04 2 9 365.8 343.0 3 2106.4 2 9 9 53.5 2 9

30 2 230.0 36.579 36.582 2 18.195 18.155 26.454 198.7 2 200.9 2 29.6 0.01 2 3.80 2 0.17 2 1.20 2 2.35 2 1.30 2 0.04 2 9 9 2106.6 2 9 2387 2 9 9

29 2 260.2 36.511 36.510 2 17.807 17.762 26.501 200.0 2 200.2 2 32.1 0.01 2 4.68 2 0.23 2 1.50 2 2.31 2 1.28 2 0.04 2 9 9 2110.0 2 9 9 51.3 2 9

28 2 285.4 36.450 36.458 2 17.412 17.364 26.552 199.2 2 196.6 2 37.5 0.00 2 5.56 2 0.28 2 1.60 2 2.31 6 1.26 6 0.03 6 9 396.5 356.9 3 2114.6 2 7.9622 2 5 2389 9 9

27 2 320.3 36.352 36.360 2 16.804 16.751 26.625 193.8 2 190.0 2 47.1 0.00 2 7.22 2 0.37 2 2.00 2 2.29 2 1.24 2 0.03 2 9 9 2122.7 2 9 9 47.1 2 9

26 2 369.7 36.198 36.204 2 15.941 15.882 26.711 186.7 2 181.7 2 59.6 0.00 2 9.37 2 0.51 2 2.70 2 2.11 2 1.12 2 0.03 2 9 9 2131.7 2 7.9001 2 2368 2 2369 9 9

25 2 420.5 36.097 36.097 2 15.333 15.267 26.774 181.5 2 179.7 2 64.8 0.00 2 10.64 2 0.59 2 3.10 2 2.07 2 1.08 2 0.03 2 9 486.4 402.2 3 2137.0 2 9 9 46.3 2 9

24 2 471.4 35.951 35.953 2 14.416 14.345 26.865 178.0 2 176.5 2 72.7 0.00 2 12.30 2 0.70 2 4.10 2 1.95 2 1.01 2 0.02 2 9 9 2140.0 2 7.8549 2 2359 2 2352 9 9

23 2 515.9 35.816 35.831 2 13.559 13.485 26.942 175.7 2 174.6 2 79.2 0.00 2 13.76 2 0.80 2 4.90 2 1.75 2 0.92 2 0.02 2 9 9 2145.8 2 9 9 44.9 2 9

22 2 620.7 35.579 35.584 2 11.724 11.642 27.123 171.6 2 168.5 2 95.7 0.00 2 17.47 2 1.04 2 7.20 2 1.21 2 0.62 2 0.02 2 9 654.9 466.1 3 2157.3 2 7.7773 2 2335 2 2330 9 9

21 3 718.7 35.397 35.401 2 10.205 10.118 27.257 160.5 2 158.6 2 114.7 0.00 2 21.09 2 1.29 2 10.30 2 0.65 2 0.34 2 0.01 2 9 9 2173.9 2 9 9 44.4 2 9

20 2 819.1 35.196 35.200 2 8.426 8.337 27.390 151.3 2 150.6 2 134.1 0.00 2 24.90 2 1.58 2 14.70 2 0.25 2 0.13 2 0.00 2 9 826.9 511.3 2 2189.8 2 7.6764 2 2327 2 2318 9 9

19 2 919.9 35.060 35.059 2 7.133 7.041 27.473 155.3 2 155.6 2 137.9 0.00 2 26.56 2 1.72 2 17.90 2 0.10 2 0.06 2 0.01 2 9 899.5 526.3 2 2195.3 2 7.6549 2 9 2315 41.5 2 9

18 2 1018.5 35.003 35.002 2 6.365 6.269 27.533 165.6 2 165.4 2 133.5 0.00 2 26.56 2 1.73 2 18.80 2 0.07 2 0.04 2 0.00 2 9 905.8 512.1 2 2196.6 6 7.6490 2 2318 2 2313 9 9

17 2 1119.1 35.008 35.006 2 5.843 5.741 27.605 182.0 2 184.2 2 118.5 0.00 2 24.81 2 1.64 2 17.90 2 9 9 9 9 9 2190.6 2 7.6697 2 9 2315 41.7 2 9

16 2 1211.7 35.024 35.024 2 5.499 5.391 27.661 201.2 2 200.7 2 104.5 0.00 2 23.24 2 1.53 2 16.70 2 0.11 6 0.06 6 0.01 6 9 799.4 432.1 3 2183.5 2 7.6864 2 2321 2 2315 9 9

15 2 1317.8 35.038 35.036 2 5.160 5.045 27.713 218.5 2 217.5 2 90.2 0.00 2 21.68 2 1.42 2 15.80 2 9 9 9 9 9 2175.3 2 9 9 41.6 2 9

14 3 1421.0 35.071 35.070 2 5.011 4.887 27.759 227.0 2 226.6 2 82.2 0.00 2 20.70 2 1.35 2 15.50 2 0.12 2 0.07 2 0.01 2 9 9 2173.1 2 7.7146 2 2320 2 2316 9 9

13 2 1520.1 35.079 35.079 2 4.773 4.642 27.794 233.8 2 233.9 2 76.7 0.00 2 20.12 2 1.31 2 16.00 2 9 9 9 9 9 2171.1 2 9 9 44.6 3 9

12 2 1620.7 35.071 35.071 2 4.560 4.422 27.812 237.3 2 237.6 2 74.6 0.00 2 19.92 2 1.31 2 16.80 2 0.11 2 0.06 2 0.01 2 9 719.1 370.4 3 2171.0 2 7.7194 2 2325 2 2316 9 9

11 2 1717.4 35.061 35.061 2 4.350 4.205 27.828 241.1 2 239.7 2 74.2 0.00 2 19.83 2 1.30 2 17.40 2 9 9 9 9 9 2170.8 2 9 9 41.6 2 9

10 2 1821.8 35.045 35.047 2 4.121 3.969 27.841 243.9 2 243.5 2 72.3 0.00 2 19.83 2 1.31 2 18.80 2 0.07 2 0.04 2 0.01 2 9 9 2170.6 2 7.7311 2 2323 2 2320 9 9

9 2 1920.4 35.028 35.028 2 3.898 3.739 27.851 245.5 2 246.0 2 71.6 0.00 2 19.83 2 1.32 2 20.00 2 9 9 9 9 9 2171.6 2 9 9 41.4 2 9

8 2 2017.7 35.013 35.014 2 3.719 3.554 27.859 247.6 2 247.4 2 71.7 0.00 2 19.92 2 1.33 2 21.40 2 0.04 2 0.02 2 0.01 2 9 9 2171.8 2 7.7367 2 9 2324 9 9

7 2 2109.1 35.006 35.006 2 3.632 3.459 27.863 248.4 2 248.1 2 71.7 0.00 2 19.92 2 1.33 2 22.50 2 9 9 9 9 9 2172.5 2 9 9 41.4 2 9

6 2 2213.7 34.992 34.992 2 3.412 3.233 27.873 249.2 2 249.2 2 72.5 0.00 2 20.02 2 1.34 2 24.80 2 0.02 2 0.02 2 0.01 2 9 714.2 347.4 3 2174.1 2 7.7331 2 2328 2 2325 41.5 2 9

5 2 2319.4 34.977 34.977 2 3.214 3.028 27.881 249.9 2 250.2 2 73.2 0.00 2 20.22 2 1.35 2 27.00 2 9 9 9 9 9 2176.3 2 9 9 41.3 2 9

4 2 2413.1 34.967 34.967 2 3.088 2.895 27.885 251.5 2 251.1 2 73.4 0.00 2 20.31 2 1.36 2 28.90 2 0.02 6 0.02 6 0.00 6 9 9 2178.2 2 7.7319 2 9 2329 41.3 2 9

3 2 2517.8 34.961 34.961 2 3.031 2.829 27.887 251.7 2 251.3 2 73.7 0.00 2 20.31 2 1.37 2 29.60 2 9 9 9 9 9 2180.3 2 9 9 41.4 2 9

2 2 2620.1 34.952 34.952 2 2.926 2.715 27.891 251.9 2 251.4 2 74.6 0.00 2 20.51 2 1.38 2 31.30 2 0.02 2 0.01 2 0.01 2 9 9 2182.7 2 9 9 41.3 2 9

1 2 2765.2 34.945 34.946 2 2.855 2.631 27.894 251.8 2 251.9 2 74.8 0.00 6 20.61 2 1.38 6 32.50 6 0.02 2 0.01 2 0.00 2 9 739.0 349.7 3 2183.3 2 7.7333 2 2336 2 2335 41.3 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

123
A5R

NOAA Ship Ronald H. Brown

STATION 55 DATE 2/6/1998 LATITUDE 24.500° N

LONGITUDE 46.584° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.5 37.465 37.467 2 24.137 24.136 25.470 213.5 2 213.8 2 -7.8 0.00 2 0.00 2 0.00 2 1.10 2 9 9 9 9 281.1 331.0 2 2073.1 6 8.0777 2 5 2431 9 9

35 2 51.0 37.463 37.466 2 24.156 24.145 25.469 210.2 2 210.3 2 -4.3 0.00 2 0.00 2 0.00 2 1.10 2 9 9 9 9 272.9 321.7 2 9 9 9 9 9

34 2 102.4 37.117 37.131 2 21.645 21.625 25.940 216.9 2 214.9 2 0.7 0.03 2 0.10 2 0.01 2 0.50 2 9 9 9 9 9 9 9 9 9 9

33 2 140.8 36.877 36.849 2 19.746 19.720 26.277 206.6 2 201.7 2 21.8 0.01 2 1.66 2 0.05 2 0.90 2 9 9 9 9 368.7 364.8 2 2106.0 2 7.9990 2 2411 2 2406 9 9

32 3 179.3 36.681 36.672 2 18.770 18.738 26.383 198.4 2 200.2 2 27.7 0.01 2 2.93 2 0.11 2 1.20 2 9 9 9 9 9 9 9 9 9 9

31 2 201.0 36.588 36.585 2 18.279 18.244 26.438 198.3 2 201.1 2 29.0 0.00 2 3.81 2 0.16 2 0.90 2 9 9 9 9 9 9 9 9 9 9

30 2 226.4 36.532 36.532 2 17.932 17.893 26.483 199.2 2 200.4 2 31.3 0.00 2 4.49 2 0.20 2 1.30 2 9 9 9 9 393.3 361.7 2 2104.4 2 7.9758 2 2382 2 2387 9 9

29 2 244.2 36.513 36.517 2 17.801 17.759 26.503 198.4 2 199.4 2 32.9 0.00 2 4.68 2 0.22 2 1.60 2 9 9 9 9 9 9 9 9 9 9

28 2 274.9 36.487 36.483 2 17.656 17.609 26.521 198.5 2 198.3 2 34.7 0.00 2 5.17 2 0.25 2 1.30 2 9 9 9 9 9 9 9 9 9 9

27 3 298.1 36.455 36.456 2 17.433 17.382 26.552 196.3 2 196.1 2 38.0 0.00 2 5.66 2 0.28 2 1.40 2 9 9 9 9 9 9 9 9 9 9

26 2 349.1 36.338 36.342 2 16.722 16.664 26.637 190.2 2 190.2 2 47.3 0.00 2 7.42 2 0.37 2 1.90 2 9 9 9 9 452.3 396.0 2 2121.8 2 7.9276 2 2380 2 2375 9 9

25 2 398.2 36.174 36.177 2 15.753 15.690 26.738 186.8 2 184.0 2 58.3 0.00 2 9.47 2 0.52 2 2.50 2 9 9 9 9 9 9 9 9 9 9

24 2 450.2 36.020 36.019 2 14.810 14.741 26.831 179.2 2 178.5 2 68.6 0.00 2 11.42 2 0.64 2 3.40 2 9 9 9 9 9 9 9 9 9 9

23 2 498.3 35.862 35.864 2 13.841 13.768 26.918 177.0 2 177.1 2 75.2 0.00 2 13.28 2 0.76 2 4.60 2 9 9 9 9 9 9 9 9 9 9

22 2 603.1 35.663 35.667 2 12.378 12.296 27.063 170.5 2 170.0 2 90.4 0.00 2 16.21 2 0.95 2 6.20 2 9 9 9 9 608.4 444.6 2 2155.1 2 7.7995 2 2331 2 2338 9 9

21 2 700.0 35.448 35.450 2 10.623 10.536 27.224 154.5 2 154.3 6 116.4 0.00 2 20.90 2 1.26 2 9.50 2 9 9 9 9 9 9 9 9 9 9

20 2 749.1 35.322 35.328 2 9.536 9.449 27.311 150.5 2 149.1 2 128.4 0.00 2 23.24 2 1.43 2 11.90 2 9 9 9 9 9 9 9 9 9 9

19 2 786.3 35.256 35.261 2 9.006 8.917 27.347 148.5 2 148.5 2 132.4 0.00 2 24.32 2 1.52 2 13.30 2 9 9 9 9 813.2 515.9 2 2187.0 2 7.6883 2 2325 2 2320 9 9

18 2 849.1 35.162 35.164 2 8.188 8.097 27.400 149.0 2 148.5 2 137.8 0.00 2 25.59 2 1.62 2 15.10 2 9 9 9 9 9 9 9 9 9 9

17 2 883.2 35.124 35.125 2 7.807 7.715 27.427 149.8 2 150.3 2 138.6 0.00 2 26.08 2 1.66 2 15.70 2 9 9 9 9 874.1 527.0 2 2195.5 2 7.6612 2 2317 2 2318 9 9

16 2 1000.8 35.041 35.040 2 6.701 6.604 27.519 163.8 2 162.7 2 133.8 0.00 2 26.28 2 1.69 2 17.60 2 9 9 9 9 9 9 9 9 9 9

15 2 1100.1 35.033 35.033 2 6.121 6.018 27.590 181.6 2 180.7 2 119.9 0.00 2 24.91 2 1.62 2 16.90 2 9 9 9 9 855.2 476.9 2 2191.6 6 7.6678 2 2316 2 2316 9 9

14 2 1201.2 35.052 35.051 2 5.735 5.626 27.654 198.3 2 196.6 2 106.8 0.00 2 23.35 2 1.52 2 15.90 2 9 9 9 9 9 9 9 9 9 9

13 2 1400.5 35.078 35.078 2 5.178 5.054 27.746 223.1 2 221.3 2 86.2 0.00 2 21.20 2 1.37 2 14.80 2 9 9 9 9 9 9 9 9 9 9

12 2 1499.2 35.111 35.112 2 5.145 5.012 27.777 227.4 2 225.9 2 81.8 0.00 2 20.51 2 1.33 2 14.70 2 9 9 9 9 9 9 9 9 9 9

11 2 1649.3 35.080 35.080 2 4.608 4.466 27.815 237.6 2 237.6 2 74.3 0.00 2 19.93 2 1.30 2 15.60 2 9 9 9 9 9 9 9 9 9 9

10 2 1850.7 35.041 35.042 2 4.079 3.925 27.842 244.7 2 245.9 2 70.2 0.00 2 19.83 2 1.30 2 18.00 2 9 9 9 9 9 9 9 9 9 9

9 2 1998.6 35.019 35.019 2 3.768 3.604 27.858 246.9 2 246.0 2 72.7 0.00 2 19.83 2 1.31 2 20.20 2 9 9 9 9 726.1 360.0 6 2172.6 2 7.7348 2 5 2324 9 9

8 2 2146.6 35.000 35.000 2 3.515 3.340 27.869 247.0 2 249.9 2 70.9 0.00 2 19.93 2 1.31 2 22.40 2 9 9 9 9 9 9 9 9 9 9

7 2 2283.7 34.981 34.981 2 3.267 3.083 27.879 252.7 2 252.9 2 70.0 0.00 2 19.83 3 1.32 2 24.70 2 9 9 9 9 9 9 9 9 9 9

6 2 2440.7 34.965 34.966 2 3.087 2.891 27.885 253.1 2 253.2 2 71.3 0.00 2 20.12 2 1.33 2 27.10 2 9 9 9 9 9 9 9 9 9 9

5 2 2599.9 34.959 34.959 2 3.017 2.807 27.888 253.8 2 253.7 2 71.5 0.00 2 20.22 2 1.35 2 28.40 2 9 9 9 9 9 9 9 9 9 9

4 2 2751.4 34.949 34.949 2 2.914 2.691 27.892 253.1 2 253.8 2 72.4 0.00 2 20.42 2 1.36 2 30.10 2 9 9 9 9 9 9 9 9 9 9

3 2 2899.7 34.938 34.938 2 2.793 2.557 27.895 253.5 2 253.6 2 73.7 0.00 2 20.61 2 1.38 2 32.40 2 9 9 9 9 9 9 9 9 9 9

2 2 3049.8 34.932 34.933 2 2.736 2.486 27.898 254.4 2 254.0 2 73.9 0.00 2 20.71 2 1.39 2 33.90 2 9 9 9 9 9 9 9 9 9 9

1 2 3211.5 34.926 34.927 2 2.672 2.406 27.900 254.8 2 254.0 2 74.6 0.00 6 20.81 6 1.40 6 35.30 6 9 9 9 9 745.9 349.8 2 2185.0 2 7.7310 2 2335 2 2335 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

124
A5R

NOAA Ship Ronald H. Brown

STATION 56 DATE 2/6/1998 LATITUDE 24.500° N

LONGITUDE 47.134° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.8 37.468 37.468 2 24.030 24.029 25.505 214.7 2 212.3 2 -5.9 0.00 2 0.00 2 0.00 2 0.70 2 1.88 2 1.09 2 0.15 2 1.81 2 283.8 332.7 6 2075.5 6 8.1004 2 9 2450 9 9

35 2 50.4 37.465 37.466 2 24.024 24.013 25.510 211.6 2 211.9 2 -5.5 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 8.0978 2 2448 2 9 9

34 2 99.8 37.455 37.452 2 23.995 23.974 25.517 211.7 2 212.4 2 -5.8 0.00 2 0.00 2 0.01 2 0.60 2 1.89 2 1.09 2 0.18 2 9 9 9 8.0961 2 9 9 9

33 2 149.5 37.094 37.096 2 21.120 21.091 26.073 208.0 2 206.4 2 11.3 0.04 2 0.49 2 0.03 2 0.50 2 9 9 9 9 9 9 9 9 9 9

32 3 195.2 36.961 36.953 2 20.065 20.028 26.262 196.0 2 197.5 2 24.6 0.01 2 1.46 2 0.06 2 0.70 2 9 9 9 1.06 2 9 9 9 9 9 9

31 3 211.1 36.888 36.879 2 19.666 19.627 26.313 195.9 2 197.6 2 26.2 0.01 2 2.05 2 0.09 2 0.80 2 2.22 2 1.27 2 0.12 2 0.87 2 9 9 9 9 9 9

30 2 227.5 36.737 36.718 2 18.868 18.827 26.405 192.4 2 193.5 2 33.9 0.00 2 3.71 2 0.17 2 1.10 2 9 9 9 9 9 9 9 9 9 9

29 2 241.5 36.629 36.642 2 18.299 18.257 26.468 191.0 2 191.2 2 38.7 0.00 2 4.59 2 0.22 2 1.10 2 9 9 9 9 9 9 9 9 9 9

28 2 299.4 36.401 36.405 2 17.093 17.043 26.593 188.5 2 190.5 2 45.2 0.00 2 6.73 2 0.34 2 2.00 2 2.28 2 1.25 2 0.03 2 9 9 9 9 9 9 9

27 2 349.8 36.288 36.288 2 16.433 16.376 26.666 186.2 2 188.3 2 50.6 0.00 2 8.30 2 0.43 2 2.20 2 9 9 9 0.45 6 9 9 9 9 9 9

26 2 401.5 36.113 36.110 2 15.413 15.350 26.767 183.8 2 182.3 2 61.7 0.00 2 10.25 2 0.55 2 3.10 2 9 9 9 9 9 9 9 9 9 9

25 2 499.0 35.839 35.840 2 13.620 13.548 26.946 176.2 2 173.8 2 79.7 0.00 2 13.86 2 0.77 2 4.80 2 1.90 2 0.99 2 0.02 2 9 9 9 9 9 9 9

24 2 599.3 35.627 35.627 2 12.076 11.996 27.093 165.9 2 163.1 2 99.0 0.00 2 17.58 2 1.01 2 7.00 2 9 9 9 0.35 2 9 9 9 9 9 9

23 2 696.0 35.473 35.475 2 10.785 10.698 27.215 155.8 2 155.0 2 114.7 0.00 2 20.51 2 1.18 2 9.40 2 0.80 6 0.43 6 0.01 6 9 9 9 9 9 9 9

22 2 799.8 35.276 35.269 2 9.114 9.023 27.346 152.5 2 151.9 2 128.3 0.00 2 23.83 2 1.46 2 13.50 2 9 9 9 0.14 2 9 9 9 9 9 9

21 2 849.9 35.171 35.169 2 8.095 8.005 27.421 152.2 2 152.1 2 134.8 0.00 2 25.40 2 1.58 2 15.60 2 9 9 9 9 9 9 9 9 9 9

20 2 900.6 35.133 35.140 2 7.731 7.637 27.446 155.2 2 153.7 2 135.7 0.00 2 25.69 2 1.60 2 16.30 2 0.16 2 0.09 2 0.00 2 9 9 9 9 9 9 9

19 2 948.5 35.068 35.073 2 6.985 6.891 27.501 159.2 2 159.5 2 135.0 0.00 2 26.18 2 1.65 2 18.90 3 9 9 9 0.11 2 9 9 9 9 9 9

18 2 1001.4 35.042 35.041 2 6.628 6.531 27.529 165.4 2 166.8 2 130.2 0.00 2 25.98 2 1.66 2 18.60 2 9 9 9 9 9 9 9 9 9 9

17 2 1100.0 35.036 35.035 2 6.040 5.938 27.603 179.9 2 182.6 2 118.6 0.00 2 24.81 2 1.59 2 18.60 2 0.09 2 0.05 2 0.00 2 9 9 9 9 9 9 9

16 2 1199.5 35.038 35.039 2 5.631 5.523 27.656 196.3 2 198.3 2 105.9 0.00 2 23.45 2 1.51 2 17.70 2 9 9 9 0.25 2 9 9 9 9 9 9

15 2 1300.3 35.057 35.057 2 5.296 5.181 27.713 212.8 2 213.5 2 93.1 0.00 2 21.88 2 1.41 2 16.50 2 0.11 2 0.07 2 0.00 2 9 9 9 9 9 9 9

14 2 1398.8 35.059 35.058 2 5.074 4.951 27.742 222.0 2 222.0 2 86.3 0.00 2 21.30 2 1.36 2 16.00 2 9 9 9 0.36 2 9 9 9 9 9 9

13 2 1499.0 35.076 35.075 2 4.894 4.764 27.777 230.6 2 229.8 2 79.9 0.00 2 20.61 2 1.32 2 16.30 2 9 9 9 9 9 9 9 9 9 9

12 2 1597.8 35.072 35.073 2 4.647 4.510 27.804 236.1 2 236.6 2 75.0 0.00 2 20.03 2 1.29 2 16.70 2 0.11 2 0.06 2 0.00 2 9 9 9 9 9 9 9

11 2 1701.5 35.066 35.066 2 4.439 4.294 27.823 239.6 2 240.5 2 72.7 0.00 2 19.83 2 1.29 2 17.50 2 9 9 9 0.32 2 9 9 9 9 9 9

10 2 1797.9 35.048 35.048 2 4.172 4.021 27.838 242.9 2 240.8 2 74.6 0.00 2 19.93 2 1.29 2 19.10 2 9 9 9 9 9 9 9 9 9 9

9 2 2001.7 35.015 35.014 2 3.696 3.533 27.861 247.2 2 248.0 2 71.2 0.00 2 19.93 2 1.31 2 22.40 2 9 9 9 9 9 9 9 9 9 9

8 2 2001.3 35.013 35.014 2 3.686 3.523 27.861 247.2 2 248.2 2 71.1 0.00 2 19.93 2 1.30 2 22.40 2 0.04 2 0.02 2 0.00 2 9 9 9 9 9 9 9

7 2 2200.9 34.989 34.989 2 3.357 3.180 27.876 251.8 2 252.7 2 69.4 0.00 2 19.83 2 1.30 2 25.00 2 9 9 9 0.24 2 9 9 9 9 9 9

6 2 2601.6 34.957 34.956 2 2.990 2.780 27.890 253.2 2 253.0 2 72.4 0.00 2 20.32 2 1.35 2 30.40 2 9 9 9 9 9 9 9 9 9 9

5 2 2799.1 34.944 34.944 2 2.859 2.632 27.893 253.3 2 253.1 2 73.6 0.00 2 20.42 2 1.37 2 32.50 2 0.02 2 0.02 2 0.00 2 9 9 9 9 9 9 9

4 2 2999.1 34.936 34.936 2 2.766 2.520 27.897 252.7 2 252.3 2 75.3 0.00 2 20.71 2 1.38 2 34.70 2 9 9 9 0.12 2 9 9 9 9 9 9

3 2 3199.6 34.929 34.928 2 2.700 2.435 27.901 252.7 2 253.3 2 75.0 0.00 2 20.81 2 1.40 2 36.00 2 9 9 9 9 9 9 9 9 9 9

2 2 3393.1 34.918 34.917 2 2.586 2.303 27.904 254.9 2 256.2 2 73.2 0.00 2 20.81 2 1.40 2 37.00 2 0.01 2 0.01 2 0.00 2 0.13 2 9 9 9 9 9 9

1 2 3626.6 34.906 34.905 2 2.453 2.148 27.908 256.7 2 257.0 2 73.8 0.00 6 20.91 6 1.41 6 39.10 6 0.01 2 0.01 2 0.00 2 0.13 2 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

125
A5R

NOAA Ship Ronald H. Brown

STATION 57 DATE 2/6/1998 LATITUDE 24.501° N

LONGITUDE 47.684° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.0 37.472 37.472 2 24.194 24.193 25.458 212.0 2 212.1 2 -6.3 0.00 4 4 4 4 9 9 9 9 278.4 329.9 6 2072.2 6 8.1010 2 2454 2 2447 9 9

35 2 40.5 37.471 37.472 2 24.183 24.174 25.465 213.6 2 212.6 2 -6.8 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 9 9 9 9 9 9

34 2 91.7 37.287 37.284 2 22.919 22.900 25.705 213.4 2 215.4 2 -4.8 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 9 2086.3 2 8.0674 6 5 2436 9 9

33 2 142.3 37.110 37.109 2 20.962 20.935 26.128 202.9 2 200.2 2 18.1 0.03 2 0.98 2 0.04 2 0.80 2 9 9 9 9 9 9 9 9 9 9

32 2 190.7 36.947 36.932 2 19.980 19.944 26.273 194.5 2 195.6 2 26.9 0.02 2 2.15 2 0.08 2 1.00 2 9 9 9 9 9 9 9 9 9 9

31 2 215.0 36.779 36.773 2 19.080 19.041 26.383 196.1 2 190.6 2 35.8 0.01 2 3.71 2 0.16 2 1.30 2 9 9 9 9 9 9 9 9 9 9

30 2 235.6 36.670 36.667 2 18.517 18.475 26.444 187.3 2 188.3 2 40.7 0.01 2 4.68 2 0.22 2 1.60 2 9 9 9 9 9 2120.0 2 7.9639 2 2397 2 2398 9 9

29 2 265.1 36.537 36.532 2 17.861 17.815 26.508 185.6 2 190.3 2 41.7 0.00 2 5.56 2 0.27 2 1.80 2 9 9 9 9 9 9 9 9 9 9

28 2 291.8 36.455 36.456 2 17.370 17.321 26.567 184.0 2 182.3 6 52.0 0.00 2 7.22 2 0.37 2 2.10 2 9 9 9 9 9 9 9 9 9 9

27 2 341.9 36.307 36.307 2 16.550 16.494 26.653 179.4 2 185.3 2 53.0 0.00 2 8.10 2 0.43 2 2.60 2 9 9 9 9 9 2126.5 2 7.9183 2 2376 2 2375 9 9

26 2 390.2 36.164 36.166 2 15.661 15.599 26.750 178.2 2 174.9 2 67.8 0.00 2 10.44 2 0.58 2 3.40 2 9 9 9 9 9 9 9 9 9 9

25 2 440.6 35.990 36.023 2 14.646 14.579 26.843 181.3 2 9 0.00 2 11.52 2 0.65 2 4.00 2 9 9 9 9 9 9 9 9 9 9

24 2 551.1 35.745 35.741 2 12.948 12.871 27.012 169.8 2 167.8 2 89.4 0.01 2 15.62 2 0.90 2 6.10 2 9 9 9 9 9 2155.6 2 7.8069 2 2348 2 2343 9 9

23 2 650.3 35.540 35.542 2 11.407 11.323 27.153 165.9 2 163.8 2 102.2 0.00 2 18.36 2 1.11 2 8.50 2 9 9 9 9 9 9 9 9 9 9

22 2 750.0 35.347 35.336 2 9.710 9.622 27.302 157.2 2 153.2 2 123.2 0.00 2 22.66 2 1.41 2 12.60 2 9 9 9 9 9 9 9 9 9 9

21 2 851.1 35.192 35.201 2 8.360 8.268 27.398 152.6 2 151.0 2 134.1 0.01 2 24.81 2 1.58 2 15.40 2 9 9 9 9 9 9 9 9 9 9

20 2 951.2 35.089 35.087 2 7.228 7.132 27.484 159.1 2 157.8 2 135.0 0.01 2 26.18 2 1.69 2 18.10 2 9 9 9 9 9 9 9 9 9 9

19 2 1050.5 35.045 35.047 2 6.358 6.258 27.568 175.9 2 172.7 2 126.2 0.00 2 25.40 2 1.66 2 18.60 2 9 9 9 9 9 2193.9 6 7.6655 2 2327 2 2317 9 9

18 2 1150.7 35.026 35.025 2 5.748 5.643 27.631 192.4 2 190.5 2 112.8 0.00 2 24.13 2 1.58 2 18.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1250.9 35.039 35.039 2 5.363 5.252 27.690 209.9 2 209.1 2 97.0 0.00 2 22.66 2 1.48 2 17.20 2 9 9 9 9 9 2183.4 2 7.6949 2 9 2318 9 9

16 2 1352.0 35.058 35.057 2 5.149 5.030 27.731 221.1 2 219.2 2 88.5 0.00 2 21.49 2 1.40 2 16.30 2 9 9 9 9 9 9 9 9 9 9

15 2 1449.5 35.055 35.054 2 4.854 4.729 27.765 230.3 2 229.4 2 80.6 0.00 2 20.71 2 1.35 2 16.30 2 9 9 9 9 9 2175.1 2 7.7170 2 9 2319 9 9

14 2 1551.2 35.075 35.074 2 4.798 4.664 27.789 235.0 2 233.0 2 77.4 0.00 2 20.22 2 1.33 2 16.50 2 9 9 9 9 9 9 9 9 9 9

13 2 1650.4 35.074 35.074 2 4.502 4.361 27.822 240.3 2 240.9 2 71.8 0.00 2 19.64 2 1.29 2 17.80 2 9 9 9 9 9 2173.5 2 7.7300 2 2327 2 2323 9 9

12 2 1851.1 35.041 35.041 2 4.000 3.847 27.850 248.9 2 248.1 2 68.6 0.00 2 19.44 2 1.28 2 19.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2050.9 35.010 35.010 2 3.618 3.451 27.866 250.9 2 251.0 2 68.9 0.00 2 19.64 2 1.31 2 23.10 2 9 9 9 9 9 2174.2 2 7.7336 2 5 2325 9 9

10 2 2250.3 34.984 34.984 2 3.309 3.128 27.878 251.8 2 251.7 2 70.8 0.00 2 20.03 2 1.35 3 26.40 2 9 9 9 9 9 9 9 9 9 9

9 2 2450.1 34.970 34.970 2 3.147 2.949 27.884 252.4 2 252.7 2 71.3 0.00 2 20.13 2 1.35 2 28.50 2 9 9 9 9 9 9 9 9 9 9

8 2 2648.1 34.954 34.954 2 2.962 2.748 27.890 252.7 2 253.3 2 72.4 0.00 2 20.32 2 1.37 2 31.20 2 9 9 9 9 9 9 9 9 9 9

7 2 2850.6 34.946 34.946 2 2.882 2.649 27.893 253.3 2 253.2 2 73.3 0.00 2 20.42 2 1.38 2 32.40 2 9 9 9 9 9 9 9 9 9 9

6 2 3050.4 34.935 34.935 2 2.774 2.523 27.897 253.4 2 252.7 2 74.9 0.00 2 20.52 2 1.38 2 32.60 2 9 9 9 9 9 2185.9 2 7.7314 2 2339 2 2336 9 9

5 2 3248.9 34.927 34.926 2 2.680 2.410 27.901 256.5 2 256.5 2 72.0 0.00 2 20.52 2 1.39 2 35.20 2 9 9 9 9 9 9 9 9 9 9

4 2 3450.4 34.916 34.916 2 2.573 2.284 27.905 256.9 2 256.6 2 73.0 0.00 2 20.71 2 1.38 3 37.00 2 9 9 9 9 9 2185.2 2 7.7314 2 2332 3 2336 9 9

3 2 3649.9 34.906 34.905 2 2.466 2.158 27.907 257.8 2 257.8 2 72.9 0.00 2 20.91 2 1.42 2 39.20 2 9 9 9 9 9 9 9 9 9 9

2 2 3848.0 34.896 34.895 2 2.356 2.029 27.911 258.1 2 258.1 2 73.7 0.00 2 20.91 2 1.43 2 40.90 2 9 9 9 9 9 2188.0 2 7.7283 2 2343 2 2337 9 9

1 2 4117.3 34.888 34.888 2 2.294 1.938 27.913 258.4 2 258.7 2 73.9 0.00 6 21.10 6 1.45 6 42.70 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

126
A5R

NOAA Ship Ronald H. Brown

STATION 58 DATE 2/6/1998 LATITUDE 24.500° N

LONGITUDE 48.234° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.7 37.476 37.475 2 24.195 24.194 25.461 212.7 2 212.7 2 -6.9 0.00 2 0.00 2 0.01 2 2 1.90 2 1.09 2 0.15 2 9 262.4 310.0 3 2077.1 6 9 2447 2 75.0 2 4.5 2

35 2 49.9 37.469 37.470 2 24.136 24.125 25.480 212.8 2 212.8 2 -6.8 0.00 2 0.00 2 0.01 2 1.10 2 1.89 2 1.08 2 0.17 2 9 9 2079.3 2 9 2441 2 74.5 2 4.7 2

34 2 100.3 37.415 37.381 2 23.823 23.802 25.538 212.4 2 213.6 2 -6.3 0.00 2 0.00 2 0.02 2 1.00 2 1.96 2 1.12 2 0.18 2 9 9 2085.4 2 9 2439 2 71.0 2 4.5 2

33 2 150.5 37.084 37.079 2 20.887 20.858 26.130 204.2 2 202.8 2 15.8 0.02 2 0.88 2 0.04 2 1.00 2 2.20 2 1.26 2 0.13 2 9 9 2112.7 2 9 2423 2 58.1 2 5.0 2

32 2 201.0 36.830 36.829 2 19.474 19.437 26.317 197.4 2 199.6 2 25.1 0.01 2 2.05 2 0.07 2 1.10 2 2.28 6 1.29 6 0.08 6 9 9 2111.0 2 7.9934 2 2405 2 2408 54.5 2 5.5 2

31 2 224.1 36.694 36.695 2 18.790 18.750 26.392 197.3 2 199.8 2 28.0 0.00 2 3.02 2 0.11 2 1.30 2 9 9 9 9 9 2110.3 2 7.9886 2 5 2403 52.9 2 6.4 2

30 2 250.1 36.577 36.576 2 18.187 18.143 26.457 197.6 2 200.2 6 30.3 0.00 2 4.10 2 0.16 2 1.50 2 2.32 2 1.29 2 0.05 2 9 9 2108.3 2 7.9781 2 2388 2 2393 9 7.3 2

29 2 275.9 36.521 36.520 2 17.871 17.823 26.494 198.6 2 199.8 2 32.2 0.00 2 4.78 2 0.20 2 1.70 2 9 9 9 9 385.5 353.6 3 2107.1 2 7.9728 2 5 2388 51.4 2 8.1 2

28 2 298.7 36.477 36.478 2 17.610 17.559 26.527 193.3 2 197.6 2 35.6 0.00 2 5.37 2 0.24 2 1.70 2 2.31 2 1.28 2 0.04 2 9 9 2112.1 2 7.9578 2 2382 2 2384 9 9

27 2 350.5 36.329 36.331 2 16.676 16.618 26.641 188.4 2 188.1 2 49.6 0.00 2 7.81 2 0.38 2 2.20 2 2.27 2 1.23 2 0.03 2 9 9 2126.9 2 7.9244 2 5 2379 49.6 2 10.6 2

26 2 402.8 36.153 36.155 2 15.626 15.562 26.750 182.0 2 182.9 2 60.0 0.00 2 9.86 2 0.51 2 2.90 2 2.15 2 1.15 2 0.03 2 9 9 2133.9 2 7.8949 2 2364 2 2368 9 9

25 2 453.0 36.020 36.019 2 14.766 14.697 26.841 181.6 2 181.1 2 66.3 0.00 2 11.32 2 0.60 2 3.50 2 2.08 2 1.11 2 0.03 2 9 9 2139.7 2 7.8720 2 2356 2 2361 47.4 2 9

24 2 500.6 35.880 35.884 2 13.941 13.868 26.912 175.7 2 174.6 2 77.2 0.00 2 13.37 2 0.73 2 4.50 2 1.87 2 0.98 2 0.02 2 9 9 2146.8 2 7.8417 2 2350 2 2352 9 9

23 2 602.1 35.679 35.678 2 12.464 12.382 27.059 172.8 2 169.3 2 90.6 0.00 2 16.31 2 0.92 2 6.20 2 1.51 6 0.78 6 0.02 6 9 9 2156.8 2 7.7983 2 2337 2 2340 45.5 2 18.8 2

22 2 699.5 35.488 35.485 2 10.930 10.842 27.201 159.9 2 160.4 2 108.5 0.00 2 19.92 2 1.17 2 8.90 2 0.84 2 0.44 2 0.02 2 9 689.0 473.8 3 2170.7 2 7.7497 2 2333 2 2331 9 9

21 2 801.8 35.308 35.307 2 9.392 9.299 27.326 152.4 2 151.6 2 126.8 0.00 2 23.34 2 1.44 2 12.50 2 0.39 2 0.21 2 0.00 2 9 777.8 500.9 3 2186.3 2 7.7090 2 2325 2 2328 42.9 2 9

20 2 901.7 35.145 35.145 2 7.877 7.782 27.435 153.3 2 153.2 2 135.2 0.00 2 25.59 2 1.63 2 15.80 2 0.16 2 0.09 2 0.01 2 9 844.0 509.4 3 2195.8 2 7.6731 2 2322 2 2323 9 9

19 2 999.7 35.086 35.088 2 7.095 6.995 27.502 160.8 2 161.4 2 132.4 0.00 2 25.98 2 1.66 2 17.00 2 0.12 2 0.07 2 0.00 2 9 9 2197.3 2 9 9 42.7 2 28.1 2

18 2 1094.9 35.057 35.056 2 6.201 6.098 27.599 176.9 2 181.7 2 118.3 0.00 2 24.71 2 1.60 2 17.10 2 0.10 2 0.06 2 0.00 2 9 9 2191.2 6 7.6720 2 2321 2 2317 9 9

17 2 1201.7 35.068 35.066 2 5.830 5.720 27.656 196.3 2 194.7 2 108.0 0.00 2 23.15 2 1.50 2 16.20 2 0.12 2 0.07 2 0.01 2 9 9 2187.6 2 7.6900 2 9 2321 42.6 2 9

16 2 1300.5 35.063 35.060 2 5.395 5.279 27.706 214.5 2 211.6 2 94.3 0.00 2 22.08 2 1.43 2 15.80 2 0.11 2 0.07 2 0.01 2 9 9 2183.8 2 7.7008 2 2319 2 2321 9 9

15 2 1400.2 35.058 35.058 2 5.019 4.897 27.747 225.2 2 224.8 2 83.9 0.00 2 21.00 2 1.36 2 15.50 2 0.10 2 0.06 2 0.00 2 9 9 2177.4 2 7.7158 2 2321 2 2321 42.0 2 9

14 2 1499.9 35.083 35.083 2 4.878 4.748 27.785 230.2 2 230.4 2 79.4 0.00 2 20.22 2 1.31 2 15.50 2 0.12 6 0.07 6 0.01 6 9 9 2175.7 2 7.7236 2 2322 2 2323 9 9

13 2 1600.3 35.078 35.079 2 4.581 4.444 27.816 236.6 2 236.8 2 75.3 0.00 2 19.93 2 1.28 2 16.30 2 0.12 2 0.07 2 0.00 2 9 9 2174.1 2 7.7276 2 2318 2 2323 42.1 2 22.4 2

12 2 1801.3 35.043 35.042 2 4.112 3.962 27.840 244.8 2 245.5 2 70.3 0.00 2 19.73 2 1.28 2 18.50 2 0.07 2 0.04 2 0.01 2 9 726.4 366.1 2 2174.1 2 7.7316 2 2324 2 2324 9 9

11 2 2000.8 35.017 35.017 2 3.728 3.564 27.861 249.4 2 250.4 2 68.6 0.00 2 19.73 2 1.28 2 21.10 2 0.11 2 0.05 2 0.02 2 9 9 2176.5 2 7.7378 2 2323 3 2329 42.2 2 9

10 2 2198.8 34.992 34.993 2 3.400 3.222 27.875 251.8 2 252.3 2 69.5 0.00 2 19.93 2 1.29 2 24.00 2 0.05 2 0.03 2 0.01 2 9 9 2178.2 2 7.7370 2 2330 2 2331 9 9

9 2 2401.4 34.968 34.969 2 3.124 2.931 27.883 252.1 2 252.9 2 71.3 0.00 2 20.22 2 1.32 2 27.50 2 9 9 9 9 9 2181.2 2 7.7336 2 2329 2 2332 41.9 2 9

8 2 2599.6 34.954 34.955 2 2.964 2.755 27.889 252.3 2 253.5 2 72.1 0.00 2 20.42 2 1.34 2 29.80 2 0.02 2 0.02 2 0.00 2 9 9 2179.8 2 7.7338 2 2333 2 2331 9 9

7 2 2801.4 34.944 34.945 2 2.856 2.629 27.894 251.7 2 253.2 2 73.5 0.00 2 20.61 2 1.36 2 31.80 2 9 9 9 9 9 2182.5 2 7.7333 2 2333 2 2334 42.2 2 9

6 2 2999.7 34.934 34.934 2 2.760 2.514 27.897 255.4 2 254.2 2 73.5 0.00 2 20.71 2 1.37 2 33.40 2 0.01 2 0.01 2 0.01 2 9 9 2182.5 2 7.7280 2 2336 2 2331 42.0 2 9

5 2 3200.8 34.923 34.923 2 2.640 2.376 27.901 258.6 2 257.2 2 71.6 0.00 2 20.61 2 1.36 2 34.40 2 9 9 9 9 9 2181.2 2 7.7333 2 9 2332 41.9 2 9

4 2 3400.4 34.916 34.915 2 2.558 2.275 27.904 259.0 2 257.2 2 72.5 0.00 2 20.71 2 1.37 2 35.90 2 0.01 2 0.01 2 0.00 2 9 9 2182.9 2 7.7331 2 2337 2 2334 41.8 2 9

3 2 3601.1 34.904 34.905 2 2.444 2.142 27.907 260.0 2 258.6 2 72.2 0.00 2 20.81 2 1.38 2 37.50 2 9 9 9 9 9 2184.1 2 7.7332 2 2337 2 2335 42.3 2 9

2 2 3800.2 34.898 34.897 2 2.370 2.048 27.910 261.1 2 258.4 2 73.2 0.00 2 20.81 2 1.39 2 39.20 2 0.01 2 0.02 2 0.00 2 9 9 2184.7 2 7.7293 2 2337 2 2334 42.0 2 9

1 2 3975.9 34.893 34.895 2 2.345 2.004 27.912 261.6 2 260.0 2 72.0 0.00 6 21.10 6 1.40 6 39.70 6 0.01 6 0.02 6 0.00 6 9 9 2185.7 2 7.7278 2 2337 2 2334 41.9 2 22.9 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

127
A5R

NOAA Ship Ronald H. Brown

STATION 59 DATE 2/7/1998 LATITUDE 24.500° N

LONGITUDE 48.782° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.2 37.469 37.470 2 24.138 24.137 25.473 213.7 2 212.6 6 -6.6 0.00 2 0.00 2 0.01 2 0.60 2 9 9 9 9 277.7 327.1 6 2076.1 6 8.0953 2 2456 2 2447 9 9

35 2 39.4 37.468 37.470 2 24.142 24.134 25.476 213.5 2 212.8 2 -6.8 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 276.5 325.7 2 9 9 9 9 9

34 2 80.6 37.462 37.407 2 24.122 24.105 25.482 213.0 2 212.4 2 -6.2 0.00 2 0.00 2 0.01 2 0.50 2 9 9 9 9 295.4 347.6 3 2077.1 2 8.0847 2 2447 2 2440 9 9

33 2 120.3 37.040 37.047 2 21.300 21.277 25.979 215.4 2 211.8 2 5.3 0.06 2 0.10 2 0.02 2 0.50 2 9 9 9 9 9 2091.4 2 8.0301 2 2421 2 2413 9 9

32 2 156.5 36.872 36.888 2 20.129 20.100 26.173 200.5 2 203.1 2 18.8 0.03 2 0.88 2 0.04 2 0.60 2 9 9 9 9 9 9 9 9 9 9

31 2 199.5 36.732 36.733 2 19.083 19.047 26.344 197.6 2 200.9 2 25.6 0.01 2 2.24 2 0.07 2 0.70 2 9 9 9 9 9 2106.6 2 9 2404 2 9 9

30 2 221.8 36.656 36.654 2 18.639 18.600 26.401 197.9 2 200.8 2 27.7 0.01 2 3.12 2 0.11 2 0.90 2 9 9 9 9 9 9 7.9863 2 2397 2 9 9

29 2 249.5 36.593 36.596 2 18.262 18.218 26.450 199.3 2 201.7 2 28.5 0.00 2 3.71 2 0.14 2 0.90 2 9 9 9 9 9 9 9 9 9 9

28 2 274.8 36.538 36.535 2 17.959 17.911 26.486 201.7 2 202.0 2 29.6 0.00 2 4.39 2 0.18 2 1.00 2 9 9 9 9 9 9 9 9 9 9

27 2 294.6 36.511 36.512 2 17.758 17.707 26.516 200.2 2 198.5 2 34.0 0.00 2 4.98 2 0.22 2 1.20 2 9 9 9 9 9 2111.8 2 7.9573 2 9 2383 9 9

26 2 349.0 36.388 36.390 2 17.066 17.007 26.593 194.9 2 192.3 2 43.6 0.00 2 6.34 2 0.30 2 1.50 2 9 9 9 9 9 9 9 9 9 9

25 2 401.3 36.218 36.233 2 16.012 15.947 26.713 193.5 2 192.9 2 48.1 0.00 2 8.10 2 0.40 2 2.00 2 9 9 9 9 9 2126.0 2 7.9103 2 2373 2 2369 9 9

24 2 450.8 36.050 36.047 2 14.947 14.878 26.825 188.9 2 185.3 2 61.1 0.00 2 10.54 2 0.56 2 2.90 2 9 9 9 9 9 9 9 9 9 9

23 2 498.9 35.926 35.929 2 14.161 14.087 26.901 186.1 2 183.2 2 67.4 0.00 2 11.81 2 0.65 2 3.50 2 9 9 9 9 9 9 9 9 9 9

22 2 549.7 35.805 35.805 2 13.315 13.237 26.985 185.9 2 182.8 2 72.4 0.00 2 13.28 2 0.74 2 4.30 2 9 9 9 9 9 9 9 9 9 9

21 2 598.9 35.662 35.666 2 12.271 12.190 27.083 180.5 2 177.6 2 83.4 0.00 2 15.43 2 0.89 2 5.60 2 9 9 9 9 9 2153.8 2 7.7984 2 5 2336 9 9

20 2 701.1 35.444 35.452 2 10.532 10.445 27.237 168.1 2 160.5 2 110.8 0.00 2 20.12 2 1.21 2 9.30 2 9 9 9 9 9 9 9 9 9 9

19 2 801.9 35.273 35.280 2 9.051 8.960 27.353 153.7 2 153.0 2 127.6 0.00 2 23.34 2 1.46 2 12.90 2 9 9 9 9 9 9 7.6883 2 2336 2 9 9

18 2 900.8 35.134 35.136 2 7.674 7.581 27.456 154.1 2 157.0 2 132.7 0.00 2 25.10 2 1.63 2 16.00 2 9 9 9 9 9 9 9 9 9 9

17 2 999.6 35.052 35.054 2 6.696 6.599 27.528 163.5 2 164.4 2 132.1 0.00 2 25.59 2 1.68 2 17.70 2 9 9 9 9 9 2197.5 6 7.6543 2 9 2316 9 9

16 2 1100.4 35.069 35.068 2 6.267 6.163 27.600 180.3 2 182.6 2 116.9 0.00 2 23.74 2 1.58 2 16.70 2 9 9 9 9 9 9 9 9 9 9

15 2 1304.2 35.089 35.088 2 5.485 5.368 27.716 213.5 2 212.0 2 93.2 0.00 2 21.49 2 1.41 2 15.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1499.2 35.066 35.066 2 4.788 4.659 27.781 235.3 2 236.5 2 74.0 0.00 2 19.54 2 1.28 2 14.70 2 9 9 9 9 9 2171.1 2 7.7225 2 5 2317 9 9

13 2 1700.1 35.049 35.050 2 4.335 4.192 27.820 245.9 2 247.4 2 66.6 0.00 2 18.85 2 1.25 2 15.50 2 9 9 9 9 9 9 9 9 9 9

12 2 1899.1 35.032 35.033 2 3.942 3.785 27.850 249.6 2 250.6 2 66.6 0.00 2 19.15 2 1.25 2 18.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2100.7 35.003 35.002 2 3.533 3.363 27.870 252.3 2 252.5 2 68.1 0.00 2 19.24 2 1.27 2 22.50 2 9 9 9 9 9 2173.5 2 7.7301 2 9 2323 9 9

10 2 2300.6 34.977 34.976 2 3.237 3.052 27.878 253.2 2 254.5 2 68.7 0.00 2 19.64 2 1.30 2 25.70 2 9 9 9 9 9 9 9 9 9 9

9 2 2499.5 34.962 34.961 2 3.054 2.853 27.886 252.2 2 255.4 2 69.4 0.00 2 19.73 2 1.31 2 28.20 2 9 9 9 9 9 9 9 9 9 9

8 2 2700.1 34.951 34.950 2 2.931 2.712 27.891 253.8 2 255.2 2 70.8 0.00 2 19.83 2 1.33 2 30.20 2 9 9 9 9 9 9 9 9 9 9

7 2 2899.7 34.940 34.939 2 2.817 2.580 27.895 254.5 2 255.4 2 71.7 0.00 2 20.03 2 1.35 2 32.20 2 9 9 9 9 9 9 9 9 9 9

6 2 3141.5 34.928 34.928 2 2.689 2.430 27.900 255.1 2 256.3 2 72.1 0.00 2 20.22 2 1.36 2 34.40 2 9 9 9 9 9 2177.7 2 7.7307 2 5 2327 9 9

5 2 3276.9 34.918 34.917 2 2.581 2.310 27.903 256.0 2 257.4 2 72.0 0.00 2 20.22 2 1.37 2 36.00 2 9 9 9 9 9 9 9 9 9 9

4 2 3547.6 34.905 34.905 2 2.442 2.146 27.907 257.0 2 258.3 2 72.5 0.00 2 20.32 2 1.38 2 38.30 2 9 9 9 9 9 2185.3 2 7.7292 2 5 2335 9 9

3 2 3800.8 34.896 34.896 2 2.362 2.040 27.910 257.4 2 259.2 2 72.5 0.00 2 20.42 2 1.39 2 40.10 2 9 9 9 9 9 9 9 9 9 9

2 2 4049.1 34.890 34.889 2 2.297 1.949 27.913 257.6 2 259.4 2 73.1 0.00 2 20.52 2 1.39 2 41.50 2 9 9 9 9 9 9 9 9 9 9

1 2 4311.8 34.880 34.880 2 2.225 1.848 27.915 257.0 2 259.2 2 74.2 0.00 2 21.01 2 1.43 2 44.10 2 9 9 9 9 9 2191.0 2 7.7221 2 5 2338 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

128
A5R

NOAA Ship Ronald H. Brown

STATION 60 DATE 2/7/1998 LATITUDE 24.500° N

LONGITUDE 49.333° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 37.398 37.400 2 23.619 23.618 25.574 214.8 2 216.0 2 -8.1 9 9 9 9 1.94 2 1.10 2 0.15 2 1.87 2 278.2 321.1 3 2075.7 6 8.0929 6 2444 6 2444 9 9

35 2 46.3 37.390 37.385 2 23.576 23.566 25.585 215.5 2 213.5 2 -5.4 0.00 2 0.00 2 0.01 2 0.40 2 1.96 2 1.12 2 0.17 2 1.85 2 9 9 9 9 69.8 2 9

34 2 90.0 37.359 37.356 2 23.489 23.470 25.593 216.0 2 215.3 2 -6.8 0.00 2 0.00 2 0.01 2 0.40 2 1.94 2 1.11 2 0.17 2 1.90 2 293.3 336.7 2 9 9 9 70.1 2 9

33 2 136.1 37.038 37.031 2 20.801 20.775 26.117 208.9 2 209.3 2 9.7 0.05 2 0.49 2 0.03 2 0.50 2 2.22 2 1.26 2 0.14 2 1.08 6 9 9 9 9 57.9 2 9

32 2 180.5 36.801 36.793 2 19.289 19.256 26.342 199.3 2 200.5 2 25.0 0.01 2 2.15 2 0.08 2 0.70 2 9 9 9 9 9 9 9 9 52.7 2 9

31 2 200.5 36.749 36.744 2 18.941 18.905 26.394 198.7 2 199.3 2 27.7 0.01 2 2.73 2 0.12 2 0.90 2 2.31 2 1.29 2 0.07 2 0.75 2 9 9 9 9 50.3 2 9

30 2 225.1 36.629 36.628 2 18.342 18.302 26.456 198.5 2 199.5 2 30.3 0.01 2 3.71 2 0.19 2 1.20 2 9 9 9 9 9 9 9 9 9 9

29 2 251.3 36.558 36.502 2 17.979 17.935 26.494 198.2 2 199.7 2 31.8 0.01 2 4.49 2 0.25 2 1.20 2 2.32 2 1.28 2 0.04 2 9 9 9 9 9 49.5 2 9

28 2 274.9 36.506 36.549 2 17.745 17.698 26.514 199.4 2 200.3 2 32.2 0.00 2 4.88 2 0.29 2 1.40 2 2.30 2 1.26 2 0.04 2 0.57 2 9 9 9 9 9 9

27 2 300.1 36.459 36.456 2 17.461 17.410 26.549 197.9 2 198.3 2 35.6 0.00 2 5.46 2 0.25 3 1.60 2 2.31 2 1.27 2 0.04 2 9 9 9 9 9 48.2 2 9

26 2 359.9 36.321 36.320 2 16.639 16.580 26.644 197.1 2 195.3 2 42.6 0.00 2 7.03 2 0.36 2 2.00 2 2.30 6 1.24 6 0.04 6 0.53 2 9 9 9 9 9 9

25 2 420.7 36.169 36.169 2 15.742 15.675 26.738 190.5 2 189.3 2 53.1 0.00 2 8.98 2 0.48 2 2.80 2 2.19 2 1.18 2 0.03 2 9 9 9 9 9 45.8 2 9

24 2 480.4 35.991 35.989 2 14.636 14.563 26.849 184.7 2 184.1 2 64.0 0.00 2 11.23 2 0.63 2 3.80 2 9 9 9 9 9 9 9 9 9 9

23 2 540.4 35.837 35.836 2 13.596 13.518 26.952 177.7 2 178.0 2 75.6 0.00 2 13.47 2 0.77 2 4.80 2 1.91 2 0.99 2 0.03 2 0.45 2 9 9 9 9 45.8 2 9

22 2 600.4 35.695 35.695 2 12.596 12.513 27.046 174.3 2 174.5 2 84.7 0.00 2 15.33 2 0.89 2 6.00 2 9 9 9 9 9 9 9 9 9 9

21 2 701.2 35.485 35.483 2 10.805 10.717 27.221 169.3 2 166.7 2 102.9 0.00 2 19.04 2 1.15 2 9.20 2 0.98 2 0.50 2 0.01 2 0.34 2 9 9 9 9 42.9 2 9

20 2 800.6 35.318 35.312 2 9.318 9.226 27.346 157.9 2 154.9 2 124.0 0.00 2 22.76 2 1.42 2 13.00 2 0.41 2 0.22 2 0.00 2 9 9 9 9 9 9 9

19 2 899.9 35.077 35.082 2 7.333 7.242 27.459 155.4 2 156.3 2 135.8 0.00 2 25.89 2 1.67 2 17.50 2 0.14 2 0.08 2 0.01 2 0.13 2 9 9 9 9 43.2 2 9

18 2 1000.3 35.056 35.055 2 6.507 6.411 27.556 171.6 2 175.7 2 122.1 0.00 2 24.71 2 1.60 2 17.70 2 0.13 2 0.07 2 0.00 2 9 9 9 9 9 9 9

17 2 1100.6 35.060 35.059 2 5.958 5.857 27.631 192.6 2 194.6 2 107.1 0.00 2 23.05 2 1.50 2 16.80 2 0.16 2 0.08 2 0.00 2 0.32 2 9 9 9 9 9 9

16 2 1299.8 35.052 35.051 2 5.077 4.964 27.733 229.9 2 230.4 2 77.8 0.00 2 20.12 2 1.31 2 14.50 2 0.25 6 0.14 6 0.01 6 9 9 9 9 9 9 9

15 2 1499.0 35.044 35.043 2 4.579 4.452 27.787 243.6 2 244.7 2 67.4 0.00 2 19.24 2 1.26 2 14.60 2 0.14 2 0.09 2 0.01 2 0.61 2 9 9 9 9 9 9

14 2 1699.6 35.029 35.028 2 4.168 4.027 27.821 248.5 2 246.3 2 69.1 0.00 2 19.54 2 1.28 2 17.50 2 9 9 9 9 9 9 9 9 9 9

13 2 1899.1 35.016 35.014 2 3.801 3.646 27.850 252.0 2 251.5 2 66.9 0.00 2 19.44 2 1.28 2 20.00 2 0.01 2 0.01 2 0.00 2 0.24 2 9 9 9 9 42.0 2 9

12 2 2099.7 34.992 34.993 2 3.479 3.310 27.866 253.3 2 253.2 2 67.9 0.00 2 19.54 2 1.30 2 23.30 2 9 9 9 9 9 9 9 9 9 9

11 2 2348.5 34.972 34.972 2 3.209 3.020 27.878 255.4 2 255.0 2 68.4 0.00 2 19.73 2 1.31 2 26.30 2 0.01 2 0.01 2 0.01 2 0.18 2 9 9 9 9 9 9

10 2 2599.4 34.956 34.954 2 3.001 2.791 27.887 255.3 2 258.1 2 67.2 0.00 2 19.83 2 1.33 2 28.80 2 9 9 9 9 9 9 9 9 9 9

9 2 2850.6 34.941 34.941 2 2.838 2.606 27.893 257.3 2 256.7 2 70.2 0.00 2 20.03 2 1.34 2 31.70 2 0.01 2 0.00 2 0.00 2 0.16 2 9 9 9 9 41.7 2 9

8 2 3098.2 34.928 34.928 2 2.684 2.430 27.899 258.2 2 256.8 6 71.6 0.00 2 20.32 2 1.37 2 34.60 2 9 9 9 9 9 9 9 9 9 9

7 2 3399.4 34.915 34.914 2 2.539 2.256 27.905 259.5 2 257.9 2 71.9 0.00 2 20.52 2 1.38 2 36.70 2 0.01 2 0.01 2 0.00 2 0.15 2 9 9 9 9 9 9

6 2 3700.2 34.900 34.899 2 2.382 2.071 27.910 259.9 2 259.1 2 72.3 0.00 2 20.61 2 1.40 2 39.60 2 0.01 2 0.01 2 0.01 2 0.14 2 9 9 9 9 9 9

5 2 4001.1 34.889 34.888 2 2.281 1.939 27.913 260.7 2 259.9 2 72.7 0.00 2 20.91 2 1.41 2 41.70 2 0.01 2 0.01 2 0.01 2 0.13 6 9 9 9 9 41.3 2 9

4 2 4300.0 34.882 34.881 2 2.226 1.851 27.916 260.8 2 259.6 2 73.7 0.00 2 21.00 2 1.43 2 43.70 2 0.03 4 0.02 2 0.01 2 0.13 2 9 9 9 9 9 9

3 2 4599.1 34.872 34.872 2 2.163 1.754 27.918 260.1 2 258.9 2 75.3 0.00 2 21.30 2 1.46 2 46.50 2 0.01 2 0.01 2 0.01 2 0.14 2 9 9 9 9 9 9

2 2 4898.8 34.860 34.859 2 2.085 1.642 27.918 257.6 2 257.0 2 78.2 0.00 2 22.08 2 1.50 2 51.00 2 0.01 6 0.01 6 0.00 6 0.14 2 9 9 9 9 9 9

1 2 5352.9 34.856 34.855 2 2.114 1.613 27.921 256.8 2 256.0 2 79.4 0.00 6 22.28 6 1.52 6 52.40 6 0.01 2 0.02 2 0.01 2 0.12 2 9 9 9 9 43.8 3 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

129
A5R

NOAA Ship Ronald H. Brown

STATION 61 DATE 2/7/1998 LATITUDE 24.491° N

LONGITUDE49.883° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F** PressureSalinity***Salinity***F*Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4F* CFC-11 F* CFC-12 F*CFC-113F* CCl4 F* at 20 oCINSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.7 37.345 37.346 2 24.321 #### #### 213.2 2 211.2 2 -5.7 0.00 2 0.00 2 0.00 2 0.80 2 9 9 9 9 274.1 325.1 6 2064.1 6 8.1164 2 5 2449 9 9

35 2 50.5 37.281 37.283 2 23.684 #### #### 214.2 2 215.3 6 -7.4 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 9 9 9 9 9 9

34 2 100.5 37.012 37.014 2 21.624 #### #### 214.0 2 217.0 2 -1.2 0.01 2 0.00 2 0.01 2 0.60 2 9 9 9 9 276.0 294.9 3 2084.8 2 8.0507 2 5 2420 9 9

33 2 150.6 36.877 36.877 2 20.265 #### #### 200.3 2 195.0 2 26.4 0.02 2 0.78 2 0.02 2 0.60 2 9 9 9 9 9 9 9 9 9 9

32 2 189.7 36.694 36.684 2 18.998 #### #### 198.2 2 199.7 2 27.2 0.01 2 2.34 2 0.08 2 0.80 2 9 9 9 9 9 2103.4 2 7.9925 2 2395 2 2398 9 9

31 2 224.9 36.585 36.586 2 18.368 #### #### 202.1 2 201.6 2 28.1 0.00 2 3.42 2 0.14 2 1.00 2 9 9 9 9 9 9 9 9 9 9

30 2 243.2 36.558 36.555 2 18.200 #### #### 202.6 2 203.2 2 27.3 0.00 2 3.81 2 0.17 2 1.20 2 9 9 9 9 9 2100.9 2 7.9844 2 2383 2 2389 9 9

29 2 267.6 36.529 36.528 2 18.020 #### #### 203.4 2 203.8 2 27.6 0.00 2 4.20 2 0.19 2 1.10 2 9 9 9 9 9 9 9 9 9 9

28 2 297.7 36.502 36.502 2 17.854 #### #### 202.6 2 203.1 2 29.0 0.00 2 4.59 2 0.21 2 1.20 2 9 9 9 9 9 2102.6 2 7.9787 2 9 2387 9 9

27 3 343.6 36.397 36.397 2 17.209 #### #### 196.0 2 195.8 2 39.4 0.00 2 6.25 2 0.32 2 1.70 2 9 9 9 9 9 9 9 9 9 9

26 2 392.5 36.295 36.287 2 16.594 #### #### 194.1 2 192.0 2 46.2 0.00 2 7.61 2 0.41 2 2.00 2 9 9 9 9 9 2121.1 2 7.9296 2 2373 2 2375 9 9

25 2 445.4 36.129 36.125 2 15.674 #### #### 189.8 2 186.9 2 55.9 0.00 2 9.57 2 0.54 2 2.80 2 9 9 9 9 9 9 9 9 9 9

24 2 488.4 36.027 36.023 2 15.018 #### #### 184.3 2 183.1 2 63.0 0.00 2 11.03 2 0.62 2 3.40 2 9 9 9 9 9 2132.4 2 7.8811 2 2357 2 2358 9 9

23 2 530.6 35.898 35.894 2 14.210 #### #### 178.4 2 178.7 2 71.7 0.00 2 12.69 2 0.73 2 4.20 2 9 9 9 9 9 9 9 9 9 9

22 2 628.0 35.575 35.580 2 11.941 #### #### 167.1 2 164.7 2 98.3 0.00 2 17.67 2 1.07 2 7.60 2 9 9 9 9 9 9 9 9 9 9

21 2 731.1 35.351 35.354 2 10.088 #### #### 156.8 2 156.8 2 117.3 0.00 2 21.58 2 1.34 2 10.90 2 9 9 9 9 9 2176.0 2 7.7252 2 2329 2 2325 9 9

20 2 830.5 35.180 35.190 2 8.648 8.556 #### 150.3 2 150.5 2 132.8 0.00 2 24.71 2 1.57 2 14.50 2 9 9 9 9 9 9 9 9 9 9

19 2 931.9 35.071 35.066 2 7.246 7.152 #### 158.5 2 159.2 2 133.5 0.00 2 25.98 2 1.69 2 17.50 2 9 9 9 9 9 9 9 9 9 9

18 2 1030.6 35.046 35.044 2 6.462 6.364 #### 172.0 2 172.6 2 125.6 0.00 2 25.50 2 1.67 2 18.00 2 9 9 9 9 9 2194.1 6 7.6611 2 2320 2 2316 9 9

17 2 1130.8 35.042 35.041 2 5.844 5.741 #### 193.3 2 194.6 2 108.0 0.00 2 23.64 2 1.55 2 16.90 2 9 9 9 9 9 9 9 9 9 9

16 2 1323.8 35.085 35.081 2 5.313 5.195 #### 224.7 2 221.3 2 85.2 0.00 2 20.51 2 1.34 2 14.40 2 9 9 9 9 9 2173.6 2 7.7131 2 9 2316 9 9

15 2 1529.5 35.099 35.099 2 4.834 4.701 #### 237.7 2 238.0 2 72.1 0.00 2 19.54 2 1.28 2 15.30 2 9 9 9 9 9 9 9 9 9 9

14 2 1729.2 35.069 35.069 2 4.350 4.204 #### 246.3 2 246.2 2 67.7 0.00 2 19.34 2 1.27 2 17.10 2 9 9 9 9 9 2169.1 2 7.7337 2 2327 2 2320 9 9

13 2 1929.2 35.032 35.031 2 3.858 3.699 #### 251.8 2 251.4 2 66.5 0.00 2 19.44 2 1.28 2 20.30 2 9 9 9 9 9 9 9 9 9 9

12 2 2132.2 35.001 35.000 2 3.496 3.323 #### 255.1 2 255.1 2 65.8 0.00 2 19.44 2 1.29 2 23.00 2 9 9 9 9 9 2171.7 2 7.7334 2 2329 2 2322 9 9

11 2 2329.6 34.980 34.980 2 3.267 3.079 #### 255.8 2 256.4 2 66.5 0.00 2 19.64 2 1.31 2 25.50 2 9 9 9 9 9 9 9 9 9 9

10 2 2531.6 34.965 34.965 2 3.106 2.901 #### 255.7 2 256.3 2 68.1 0.00 2 19.93 2 1.32 2 27.60 2 9 9 9 9 9 2177.4 2 7.7326 2 2336 2 2328 9 9

9 2 2731.6 34.951 34.951 2 2.945 2.723 #### 256.4 2 256.6 2 69.3 0.00 2 20.12 2 1.34 2 30.00 2 9 9 9 9 9 9 9 9 9 9

8 2 2924.7 34.940 34.940 2 2.818 2.579 #### 255.9 2 257.1 2 70.0 0.00 2 20.22 2 1.36 2 31.80 2 9 9 9 9 9 2180.1 2 7.7313 2 5 2330 9 9

7 2 3131.4 34.929 34.929 2 2.710 2.452 #### 260.4 2 256.8 2 71.4 0.00 2 20.52 2 1.38 2 33.90 2 9 9 9 9 9 9 9 9 9 9

6 2 3330.7 34.919 34.919 2 2.590 2.314 #### 262.2 2 258.2 2 71.2 0.00 2 20.52 2 1.39 2 35.60 2 9 9 9 9 9 2181.8 2 7.7288 2 5 2331 9 9

5 2 3529.2 34.905 34.905 2 2.436 2.142 #### 262.6 2 258.8 2 72.0 0.00 2 20.71 2 1.40 2 38.00 2 9 9 9 9 9 9 9 9 9 9

4 2 3729.3 34.896 34.896 2 2.344 2.030 #### 262.7 2 260.0 2 71.8 0.00 2 20.91 2 1.42 2 40.00 2 9 9 9 9 9 2185.1 2 7.7263 2 9 2333 9 9

3 2 4027.9 34.887 34.886 2 2.257 1.912 #### 263.6 2 259.5 2 73.3 0.00 2 21.00 2 1.43 2 41.90 2 9 9 9 9 9 2186.9 2 7.7258 2 5 2335 9 9

2 2 4329.9 34.880 34.879 2 2.213 1.835 #### 262.6 2 259.9 2 73.6 0.00 2 21.20 2 1.45 2 43.80 2 9 9 9 9 9 9 9 9 9 9

1 2 4630.9 34.871 34.871 2 2.163 1.750 #### 262.8 2 273.9 4 60.3 0.00 6 21.59 6 1.47 6 46.40 6 9 9 9 9 9 2191.6 2 7.7208 2 2346 2 2338 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

##
A5R

NOAA Ship Ronald H. Brown

STATION 62 DATE 2/8/1998 LATITUDE 24.501° N

LONGITUDE 50.433° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.2 37.352 37.354 2 24.578 24.577 25.251 213.2 2 210.9 2 -6.3 0.00 2 0.00 2 0.00 2 0.90 2 1.82 2 1.05 2 0.15 2 9 274.1 328.3 6 2066.6 6 8.1110 2 2452 2 2448 79.4 2 9

35 2 59.6 37.369 37.369 2 24.586 24.573 25.269 210.5 2 211.0 6 -6.4 0.00 2 0.00 2 0.00 2 0.90 2 1.84 2 1.06 2 0.17 2 9 9 2066.1 2 8.1111 2 2446 2 2447 79.7 2 9

34 3 121.9 37.190 37.197 2 22.699 22.674 25.699 213.7 2 211.6 2 0.0 0.05 2 0.10 2 0.01 2 0.70 2 2.08 2 1.17 2 0.17 2 9 9 2090.7 2 8.0577 2 5 2433 64.9 2 9

33 3 179.0 36.842 36.846 2 19.908 19.875 26.211 194.0 2 195.7 2 27.2 0.01 2 1.56 2 0.05 2 0.90 2 2.22 2 1.26 2 0.08 2 9 9 2108.9 2 8.0015 2 9 2411 54.5 2 9

32 2 199.6 36.741 36.739 2 19.336 19.300 26.286 193.8 2 196.5 2 28.9 0.01 2 2.05 2 0.07 2 1.00 2 2.26 2 1.27 2 0.05 2 9 9 2108.6 2 7.9941 2 5 2405 53.6 2 9

31 2 220.7 36.633 36.635 2 18.714 18.675 26.365 196.3 2 201.3 2 26.9 0.01 2 2.63 2 0.10 2 1.20 2 2.32 2 1.31 2 0.05 2 9 9 2103.4 2 7.9928 2 9 2398 51.4 2 9

30 3 248.5 36.580 36.580 2 18.393 18.349 26.407 200.9 2 204.0 2 25.6 0.01 2 3.32 2 0.13 2 1.30 2 2.31 2 1.29 2 0.03 2 9 9 2101.0 2 7.9901 2 2397 2 2393 49.5 2 9

29 3 274.7 36.556 36.556 2 18.230 18.182 26.432 203.3 2 203.8 2 26.6 0.01 2 3.71 2 0.16 2 1.40 2 2.25 4 1.27 4 0.04 4 9 9 2100.6 2 7.9933 2 2399 2 2395 47.8 2 9

28 2 299.5 36.524 36.526 2 18.006 17.954 26.465 203.8 2 204.7 2 26.7 0.01 2 4.29 2 0.19 2 1.50 2 2.32 6 1.29 6 0.04 6 9 9 2100.6 2 7.9826 2 9 2387 9 9

27 2 348.4 36.488 36.484 2 17.631 17.571 26.534 188.6 2 185.9 2 47.3 0.01 2 6.54 2 0.34 2 2.00 2 2.22 2 1.21 2 0.02 2 9 9 2122.1 2 7.9521 2 2386 2 2391 49.0 2 9

26 2 452.4 36.153 36.153 2 15.709 15.637 26.735 181.2 2 180.1 2 62.5 0.01 2 10.05 2 0.56 2 3.30 2 2.04 2 1.08 2 0.02 2 9 9 2133.1 2 7.8955 2 2367 2 2368 9 9

25 2 500.0 35.993 36.013 2 14.711 14.635 26.836 177.4 2 176.9 2 70.8 0.00 2 11.62 2 0.66 2 4.10 2 1.92 2 1.01 2 0.03 2 9 9 2139.3 2 7.8693 2 2360 2 2359 45.4 2 9

24 2 595.0 35.720 35.721 2 12.829 12.746 27.019 172.5 2 170.6 2 87.3 0.01 2 15.13 2 0.92 2 6.20 2 1.47 2 0.76 2 0.02 2 9 9 2154.2 2 7.8197 2 2348 2 2348 9 9

23 2 699.4 35.493 35.508 2 11.065 10.976 27.180 164.8 2 163.0 2 105.1 0.00 2 19.14 2 1.16 2 9.00 2 0.91 2 0.47 2 0.01 2 9 9 2168.4 2 7.7563 2 2333 2 2331 42.7 2 9

22 2 798.1 35.252 35.250 2 9.211 9.120 27.311 152.2 2 150.8 2 128.8 0.00 2 23.73 2 1.50 2 13.80 2 0.37 2 0.20 2 0.01 2 9 9 2186.4 2 7.6943 2 2324 2 2322 9 9

21 3 845.4 35.145 35.145 2 8.223 8.132 27.382 150.0 2 150.2 2 135.9 0.01 2 25.49 2 1.63 2 15.90 2 0.22 2 0.12 2 0.01 2 9 9 2195.0 2 7.6727 2 2322 2 2322 42.5 2 9

20 2 899.6 35.102 35.100 2 7.666 7.573 27.431 152.3 2 155.4 2 134.5 0.00 2 25.69 2 1.65 2 16.90 2 0.19 2 0.11 2 0.01 2 9 9 2198.0 2 7.6666 2 2322 2 2322 9 9

19 2 949.7 35.073 35.073 2 7.198 7.103 27.476 162.1 2 161.9 2 131.2 0.00 2 25.59 2 1.66 2 17.40 2 0.17 2 0.10 2 0.00 2 9 9 2198.4 2 7.6644 2 9 2322 41.7 2 9

18 2 999.3 35.054 35.052 2 6.661 6.564 27.534 171.2 2 172.9 2 123.9 0.00 2 25.10 2 1.63 2 17.50 2 0.17 2 0.09 2 0.01 2 9 9 2194.8 6 7.6690 2 9 2320 9 9

17 2 1150.2 35.039 35.039 2 5.710 5.606 27.646 200.1 2 199.6 2 104.0 0.00 2 23.05 2 1.51 2 17.00 2 0.15 2 0.08 2 0.01 2 9 9 2189.2 2 7.6893 2 2320 2 2322 41.8 2 9

16 2 1338.0 35.066 35.065 2 5.131 5.014 27.740 230.1 2 229.1 2 78.7 0.00 2 20.32 2 1.33 2 14.80 2 0.20 2 0.10 2 0.01 2 9 9 2177.2 2 7.7172 2 9 2321 9 9

15 2 1547.9 35.090 35.087 2 4.759 4.625 27.805 241.9 2 239.7 2 71.0 0.00 2 19.53 2 1.28 2 15.60 2 0.15 2 0.09 2 0.01 2 9 9 2175.0 2 7.7278 2 2322 2 2324 41.4 2 9

14 2 1747.8 35.066 35.066 2 4.282 4.135 27.840 247.7 2 246.5 2 67.9 0.00 2 19.44 2 1.27 2 18.00 2 0.10 6 0.06 6 0.01 6 9 9 2175.7 2 7.7336 2 2324 2 2327 9 9

13 2 1952.8 35.017 35.016 2 3.681 3.523 27.864 252.5 2 252.4 2 66.9 0.00 2 19.44 2 1.29 2 21.90 2 0.06 2 0.03 2 0.00 2 9 9 2177.8 2 7.7328 2 2326 2 2329 41.5 2 9

12 2 2152.7 34.992 34.991 2 3.392 3.219 27.874 254.6 2 255.2 2 66.6 0.00 2 19.54 2 1.30 2 24.30 2 0.06 2 0.04 2 0.01 2 9 9 2179.8 2 9 9 9 9

11 2 2347.2 34.975 34.976 2 3.209 3.020 27.881 255.9 2 255.9 2 67.5 0.00 2 19.73 2 1.31 2 26.60 2 0.05 2 0.03 2 0.01 2 9 9 2182.2 2 7.7350 2 2329 2 2334 42.0 2 9

10 2 2550.0 34.961 34.963 2 3.049 2.843 27.886 255.9 2 255.8 2 69.1 0.00 2 19.93 2 1.34 2 28.80 2 0.03 2 0.01 2 0.01 2 9 9 2182.5 2 9 9 9 9

9 2 2749.6 34.949 34.950 2 2.912 2.689 27.892 255.7 2 256.0 2 70.2 0.00 2 20.22 2 1.35 2 31.10 2 0.02 2 0.01 2 0.00 2 9 9 2184.3 2 7.7334 2 2332 2 2336 41.5 2 9

8 2 3000.2 34.934 34.934 2 2.741 2.496 27.898 257.2 2 256.8 2 71.0 0.00 2 20.32 2 1.38 2 33.60 2 0.02 2 0.01 2 0.01 2 9 9 2182.3 2 9 9 41.6 2 9

7 2 3249.1 34.921 34.921 2 2.602 2.334 27.903 258.8 2 258.3 2 70.9 0.00 2 20.51 2 1.38 2 35.70 2 0.01 2 0.00 2 0.01 2 9 9 2183.3 2 7.7335 2 2337 2 2335 42.0 2 9

6 2 3501.7 34.907 34.907 2 2.448 2.157 27.908 260.2 2 259.2 2 71.5 0.00 2 20.71 2 1.40 2 38.10 2 0.01 2 0.00 2 0.00 2 9 9 2185.9 2 9 9 41.7 2 9

5 2 3722.0 34.895 34.896 2 2.327 2.015 27.910 260.2 2 259.9 2 72.0 0.00 2 20.90 2 1.42 2 40.40 2 0.01 2 0.01 2 0.00 2 9 9 2187.2 2 7.7300 2 9 2337 41.7 2 9

4 2 4000.4 34.885 34.885 2 2.233 1.892 27.913 259.7 2 259.7 2 73.3 0.00 2 21.20 2 1.44 2 43.10 2 0.01 2 0.01 2 0.00 2 9 9 2189.2 2 9 9 41.4 2 9

3 2 4247.9 34.879 34.879 2 2.196 1.828 27.915 259.2 2 259.5 2 74.0 0.00 2 21.20 2 1.45 2 44.40 2 0.01 2 0.00 2 0.00 2 9 9 2191.4 2 7.7251 2 2341 2 2339 41.9 2 9

2 2 4487.3 34.872 34.872 2 2.148 1.753 27.917 258.5 2 258.8 2 75.4 0.00 2 21.49 2 1.47 2 46.70 2 0.01 6 0.01 6 0.01 6 9 9 2194.4 2 9 9 9 9

1 2 4821.0 34.867 34.866 2 2.136 1.701 27.919 257.4 2 257.8 2 76.9 0.00 6 21.88 6 1.49 6 48.90 6 9 9 9 9 9 2196.6 2 7.7157 2 9 2341 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

131
A5R

NOAA Ship Ronald H. Brown

STATION 63 DATE 2/8/1998 LATITUDE 24.501° N

LONGITUDE 50.984° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.2 37.388 37.387 2 24.858 24.857 25.193 211.9 2 210.1 2 -6.5 0.00 2 0.00 2 0.00 2 0.80 2 9 9 9 9 295.3 357.3 2 2062.6 2 8.1161 2 2446 2 2448 9 9

35 2 49.1 37.370 37.368 2 24.757 24.746 25.217 209.9 2 210.5 2 -6.5 0.00 2 0.00 2 0.00 2 0.80 2 9 9 9 9 9 9 9 9 9 9

34 2 98.3 37.310 37.312 2 24.460 24.439 25.267 211.6 2 211.9 2 -6.8 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 9 1981.2 3 8.1059 2 2443 2 2347 9 9

33 2 152.0 37.030 37.029 2 21.129 21.099 26.023 193.5 2 198.1 2 19.7 0.03 2 0.68 2 0.02 2 0.80 2 9 9 9 9 9 2063.3 3 8.0214 2 9 2376 9 9

32 2 200.7 36.795 36.804 2 19.508 19.471 26.282 182.9 2 185.8 6 38.8 0.01 2 3.22 2 0.13 2 1.20 2 9 9 9 9 9 2135.5 3 7.9757 2 2406 2 2423 9 9

31 2 228.8 36.692 36.701 2 18.804 18.763 26.387 183.7 2 184.7 2 43.0 0.00 2 4.39 2 0.20 2 1.50 2 9 9 9 9 9 9 9 9 9 9

30 2 251.9 36.616 36.622 2 18.367 18.323 26.442 184.9 2 187.7 2 42.0 0.00 2 4.88 2 0.23 2 1.70 2 9 9 9 9 9 2115.0 2 7.9629 2 2394 2 2391 9 9

29 2 275.5 36.570 36.571 2 18.087 18.039 26.479 185.1 2 186.0 2 45.0 0.00 2 5.56 2 0.28 2 1.80 2 9 9 9 9 9 9 9 9 9 9

28 2 301.6 36.511 36.505 2 17.746 17.694 26.520 184.0 2 185.2 2 47.4 0.00 2 6.34 2 0.33 2 2.00 2 9 9 9 9 9 2120.2 2 7.9444 2 2383 2 2385 9 9

27 3 352.0 36.357 36.371 2 16.836 16.777 26.624 181.9 2 181.9 2 55.0 0.00 2 7.81 2 0.42 2 2.40 2 9 9 9 9 9 9 9 9 9 9

26 2 399.9 36.208 36.205 2 16.011 15.947 26.705 180.8 2 180.7 2 60.3 0.00 2 9.37 2 0.53 2 3.10 2 9 9 9 9 9 2129.1 2 7.9003 2 2368 2 2367 9 9

25 2 449.3 36.048 36.048 2 15.161 15.091 26.777 181.4 2 181.0 2 64.4 0.00 2 10.64 2 0.61 2 3.90 2 9 9 9 9 9 2141.5 2 9 9 9 9

24 2 499.3 35.900 35.897 2 14.082 14.008 26.898 175.3 2 173.9 2 77.1 0.00 2 12.89 2 0.76 2 4.80 2 9 9 9 9 9 9 7.8458 2 9 9 9

23 2 550.5 35.813 35.812 2 13.487 13.408 26.957 170.7 2 171.2 2 83.0 0.00 2 14.06 2 0.84 2 5.40 2 9 9 9 9 9 9 9 9 9 9

22 2 586.5 35.739 35.741 2 12.970 12.888 27.005 170.3 2 169.6 2 87.5 0.00 2 15.23 2 0.91 2 6.10 2 9 9 9 9 9 2152.2 2 7.8120 2 2341 2 2342 9 9

21 2 645.4 35.610 35.610 2 11.992 11.906 27.099 167.9 2 168.1 2 94.6 0.00 2 16.99 2 1.03 2 7.40 2 9 9 9 9 9 9 9 9 9 9

20 2 738.3 35.387 35.398 2 10.177 10.088 27.255 158.3 2 157.3 2 116.2 0.00 2 20.80 2 1.32 2 11.00 2 9 9 9 9 9 9 9 9 9 9

19 2 848.6 35.181 35.179 2 8.412 8.320 27.382 150.9 2 150.5 2 134.3 0.00 2 24.52 2 1.61 2 15.50 2 9 9 9 9 9 2191.6 2 7.6758 2 2322 2 2320 9 9

18 2 901.9 35.121 35.118 2 7.763 7.669 27.432 154.2 2 153.9 2 135.3 0.00 2 25.30 2 1.68 2 16.80 2 9 9 9 9 9 9 9 9 9 9

17 2 1098.8 35.041 35.041 2 6.063 5.961 27.603 189.3 2 189.6 2 111.4 0.00 2 23.25 2 1.58 2 17.10 2 9 9 9 9 9 2189.4 6 7.6783 2 2312 2 2318 9 9

16 3 1299.6 35.059 35.058 2 5.243 5.128 27.720 223.7 2 222.7 2 84.3 0.00 2 20.42 2 1.39 2 15.20 2 9 9 9 9 9 9 9 9 9 9

15 2 1497.9 35.076 35.075 2 4.742 4.613 27.794 240.8 2 240.5 2 70.3 0.00 2 19.15 2 1.29 2 15.20 2 9 9 9 9 9 2168.9 2 7.7283 2 9 2317 9 9

14 2 1697.9 35.069 35.067 2 4.329 4.186 27.836 246.7 2 246.3 2 67.7 0.00 2 18.95 2 1.28 2 17.40 2 9 9 9 9 9 9 9 9 9 9

13 2 1896.7 35.035 35.035 2 3.905 3.749 27.856 249.6 2 250.8 2 66.7 0.00 2 19.05 2 1.29 2 19.90 2 9 9 9 9 9 9 9 9 9 9

12 2 2097.7 35.004 35.003 2 3.527 3.357 27.871 253.7 2 254.3 2 66.4 0.00 2 19.25 2 1.31 2 23.00 2 9 9 9 9 9 2174.7 2 7.7347 2 5 2326 9 9

11 2 2400.7 34.971 34.970 2 3.143 2.950 27.884 255.3 2 255.7 2 68.3 0.00 2 19.64 2 1.33 2 27.40 2 9 9 9 9 9 9 9 9 9 9

10 2 2699.5 34.949 34.949 2 2.913 2.695 27.891 254.8 2 255.7 2 70.4 0.00 2 20.03 2 1.36 2 30.60 2 9 9 9 9 9 9 9 9 9 9

9 2 2998.4 34.931 34.931 2 2.717 2.473 27.898 256.2 2 256.8 2 71.2 0.00 2 20.13 2 1.39 2 33.60 2 9 9 9 9 9 2184.7 2 7.7311 2 2337 2 2335 9 9

8 2 3297.0 34.916 34.916 2 2.557 2.285 27.903 258.4 2 257.7 2 71.9 0.00 2 20.52 2 1.40 2 36.10 2 9 9 9 9 9 9 9 9 9 9

7 2 3601.8 34.900 34.900 2 2.380 2.080 27.908 260.0 2 259.0 2 72.4 0.00 2 20.71 2 1.42 2 38.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3797.2 34.893 34.892 2 2.306 1.986 27.912 259.2 2 259.2 2 73.0 0.00 2 20.81 2 1.44 2 40.50 2 9 9 9 9 9 9 9 9 9 9

5 2 4000.8 34.886 34.884 2 2.234 1.893 27.914 259.6 2 259.4 2 73.6 0.00 2 21.01 2 1.45 2 42.40 2 9 9 9 9 9 9 7.7267 2 2338 2 9 9

4 2 4197.2 34.878 34.878 2 2.184 1.822 27.915 259.0 2 258.6 2 75.0 0.00 2 21.30 2 1.47 2 44.20 2 9 9 9 9 9 9 9 9 9 9

3 2 4799.2 34.864 34.864 2 2.112 1.681 27.918 257.9 2 257.5 2 77.3 0.00 2 21.79 2 1.51 2 48.90 2 9 9 9 9 9 9 9 9 9 9

2 2 5085.4 34.858 34.857 2 2.100 1.633 27.919 256.1 2 255.9 2 79.4 0.00 2 22.08 2 1.54 2 50.80 2 9 9 9 9 9 2191.2 2 9 9 9 9

1 2 5436.5 34.856 34.857 2 2.130 1.617 27.922 255.4 2 256.0 2 79.4 0.00 6 22.08 6 1.54 6 51.70 6 9 9 9 9 9 2201.1 2 7.7138 2 2347 2 2345 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

132
A5R

NOAA Ship Ronald H. Brown

STATION 64 DATE 2/8/1998 LATITUDE 24.501° N

LONGITUDE 51.533° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.1 37.246 37.247 2 23.414 23.413 25.520 214.2 2 216.2 2 -7.4 9 9 9 9 1.95 2 1.13 2 0.18 2 1.99 2 9 2069.1 2 8.0901 6 2429 6 2433 9 9

35 2 41.6 37.243 37.245 2 23.199 23.190 25.584 215.7 2 216.8 2 -7.2 0.00 2 0.00 2 0.00 2 4 1.97 2 1.13 2 0.17 2 2.01 2 9 9 9 9 9 9

34 2 91.2 36.895 36.891 2 20.671 20.654 26.038 214.6 2 215.2 2 4.5 0.00 2 0.00 2 0.00 2 4 2.23 2 1.28 2 0.15 2 9 9 9 9 9 9 9

33 2 140.6 36.684 36.687 2 19.127 19.102 26.291 200.5 2 203.9 2 22.4 0.02 2 1.17 2 0.02 2 4 2.31 2 1.30 2 0.12 2 0.84 6 9 9 9 9 9 9

32 2 190.7 36.593 36.588 2 18.401 18.367 26.410 203.8 2 204.7 2 24.9 0.00 2 3.12 2 0.12 2 4 2.33 2 1.32 2 0.05 2 9 9 9 9 9 9 9

31 2 214.3 36.553 36.554 2 18.208 18.171 26.430 207.7 2 207.5 2 23.0 0.00 2 3.42 2 0.14 2 4 2.34 2 1.32 2 0.05 2 9 9 9 9 9 9 9

30 2 239.2 36.534 36.536 2 18.056 18.014 26.456 207.4 2 209.2 2 22.0 0.00 2 3.61 2 0.15 2 4 2.35 2 1.32 2 0.05 2 0.66 2 9 9 9 9 9 9

29 2 263.9 36.521 36.519 2 17.951 17.905 26.474 211.2 2 211.4 2 20.3 0.00 2 3.71 2 0.16 2 4 9 9 9 9 9 9 9 9 9 9

28 2 288.9 36.501 36.501 2 17.807 17.757 26.495 211.1 2 212.5 2 19.8 0.00 2 3.90 2 0.18 2 4 2.35 2 1.32 2 0.07 2 9 9 9 9 9 9 9

27 2 358.4 36.368 36.371 2 17.081 17.021 26.575 199.6 2 199.9 2 35.9 0.00 2 6.05 2 0.31 2 4 2.24 2 1.24 2 0.05 2 0.60 2 9 9 9 9 9 9

26 2 430.2 36.195 36.193 2 16.004 15.935 26.699 191.9 2 189.6 2 51.5 0.00 2 8.49 2 0.47 2 4 2.18 2 1.17 2 0.04 2 9 9 9 9 9 9 9

25 2 500.8 35.950 35.956 2 14.407 14.332 26.867 188.0 2 184.8 2 64.5 0.00 2 11.33 2 0.66 2 4 2.00 2 1.06 2 0.03 2 9 9 9 9 9 9 9

24 2 599.0 35.690 35.689 2 12.626 12.543 27.036 174.3 2 174.4 2 84.6 0.00 2 15.23 2 0.92 2 4 1.53 2 0.79 2 0.03 2 0.40 2 9 9 9 9 9 9

23 2 699.1 35.420 35.418 2 10.590 10.503 27.207 161.9 2 160.1 2 110.9 0.00 2 20.22 2 1.27 2 4 9 9 9 9 9 9 9 9 9 9

22 2 800.4 35.201 35.203 2 8.736 8.647 27.346 151.0 2 150.4 2 132.3 0.00 2 24.23 2 1.57 2 4 0.30 2 0.16 2 0.01 2 0.17 2 9 9 9 9 9 9

21 2 899.9 35.096 35.094 2 7.625 7.532 27.432 152.8 2 152.3 2 137.8 0.00 2 25.89 2 1.70 2 4 9 9 9 9 9 9 9 9 9 9

20 2 1001.8 35.039 35.039 2 6.679 6.582 27.520 164.9 2 164.7 2 132.0 0.00 2 25.79 2 1.71 2 4 0.10 2 0.06 2 0.01 2 9 9 9 9 9 9 9

19 2 1203.1 35.038 35.039 2 5.565 5.457 27.664 205.2 2 204.5 2 100.1 0.00 2 22.37 2 1.50 2 4 0.14 2 0.08 2 0.00 2 0.37 2 9 9 9 9 9 9

18 2 1400.1 35.064 35.064 2 4.900 4.779 27.766 233.6 2 236.4 2 73.2 0.00 2 19.64 2 1.31 2 4 0.17 6 0.09 6 0.01 6 9 9 9 9 9 9 9

17 2 1598.8 35.060 35.060 2 4.496 4.361 27.810 247.1 2 247.3 2 65.4 0.00 2 18.86 2 1.26 2 4 0.17 2 0.09 2 0.01 2 9 9 9 9 9 9 9

16 2 1799.1 35.057 35.057 2 4.189 4.038 27.843 247.9 2 247.6 2 67.6 0.00 2 19.15 2 1.28 2 4 0.08 2 0.05 2 0.01 2 0.40 2 9 9 9 9 9 9

15 2 2000.5 35.018 35.019 2 3.699 3.536 27.864 251.8 2 252.5 2 66.7 0.00 2 19.15 2 1.29 2 4 0.06 2 0.04 2 0.01 2 9 9 9 9 9 9 9

14 2 2199.7 34.995 34.995 2 3.436 3.258 27.873 254.0 2 254.9 2 66.6 0.00 2 19.15 2 1.30 2 4 0.06 2 0.03 2 0.02 2 9 9 9 9 9 9 9

13 2 2399.2 34.974 34.974 2 3.195 3.001 27.881 255.2 2 255.4 2 68.2 0.00 2 19.44 2 1.33 2 4 0.04 2 0.03 2 0.00 2 0.33 2 9 9 9 9 9 9

12 2 2599.7 34.956 34.956 2 2.993 2.783 27.888 254.5 2 255.7 2 69.7 0.00 2 19.83 2 1.35 2 4 9 9 9 9 9 9 9 9 9 9

11 2 2799.3 34.943 34.943 2 2.856 2.629 27.893 255.0 2 256.0 2 70.7 0.00 2 20.03 2 1.37 2 4 9 9 9 9 9 9 9 9 9 9

10 2 2999.6 34.934 34.933 2 2.753 2.508 27.897 256.0 2 256.0 2 71.7 0.00 2 20.23 2 1.39 2 4 0.01 2 0.01 2 0.00 2 0.16 2 9 9 9 9 9 9

9 2 3199.3 34.924 34.924 2 2.645 2.381 27.901 254.8 2 256.8 2 72.0 0.00 2 20.32 2 1.40 2 4 9 9 9 9 9 9 9 9 9 9

8 2 3500.5 34.906 34.905 2 2.425 2.134 27.908 260.0 2 259.7 2 71.2 0.00 2 20.42 2 1.41 2 4 0.01 2 0.00 2 0.00 2 0.12 2 9 9 9 9 9 9

7 2 3800.9 34.894 34.892 2 2.311 1.990 27.912 260.1 2 259.2 2 72.9 0.00 2 20.72 2 1.43 2 4 9 9 9 9 9 9 9 9 9 9

6 2 4099.6 34.883 34.882 2 2.218 1.866 27.915 259.2 2 259.0 2 74.2 0.00 2 21.01 2 1.46 2 4 0.01 2 0.01 2 0.01 2 0.13 2 9 9 9 9 9 9

5 2 4391.8 34.871 34.871 2 2.144 1.761 27.915 258.0 2 258.4 2 75.7 0.00 2 21.40 2 1.49 2 4 0.01 2 0.00 2 0.01 2 0.12 2 9 9 9 9 9 9

4 2 4700.1 34.865 34.864 2 2.106 1.687 27.918 257.2 2 256.7 2 78.1 0.00 2 21.79 2 1.51 2 4 0.01 2 0.01 2 0.01 2 0.12 2 9 9 9 9 9 9

3 2 4997.3 34.859 34.858 2 2.092 1.637 27.919 255.9 2 257.1 6 78.1 0.00 2 21.99 2 1.53 2 4 0.01 2 0.01 2 0.01 2 9 9 9 9 9 9 9

2 2 5363.7 34.858 2 2.126 1.623 27.922 255.6 2 9 9 9 9 9 1 1 1 0.13 6 9 9 9 9 9 9

1 2 5363.1 34.857 34.855 2 2.126 1.623 27.921 255.6 2 256.0 2 79.4 0.00 6 22.08 6 1.54 6 4 0.01 2 0.01 2 0.01 2 0.13 6 733.8 333.0 6 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

133
A5R

NOAA Ship Ronald H. Brown

STATION 65 DATE 2/9/1998 LATITUDE 24.500° N

LONGITUDE 51.149° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.0 37.276 37.275 2 24.072 24.071 25.346 208.1 2 213.9 2 -7.4 0.00 2 0.00 2 0.00 2 0.80 2 9 9 9 9 276.4 324.6 6 2065.9 6 8.1033 2 5 2440 9 9

35 2 49.1 37.232 37.232 2 23.002 22.992 25.634 215.3 2 215.0 2 -4.6 0.00 2 0.00 2 0.00 2 0.60 2 9 9 9 9 9 9 9 9 9 9

34 2 100.4 37.221 37.212 2 22.966 22.945 25.642 215.4 2 216.3 2 -5.7 0.00 2 0.00 2 0.00 2 0.60 2 9 9 9 9 9 9 9 9 9 9

33 2 148.3 36.752 36.754 2 19.515 19.488 26.243 209.8 2 207.2 2 17.4 0.04 2 0.59 2 0.02 2 0.80 2 9 9 9 9 9 2098.5 2 8.0081 2 2401 2 2403 9 9

32 2 200.2 36.580 36.580 2 18.411 18.376 26.398 202.0 2 205.4 2 24.1 0.01 2 2.93 2 0.10 2 1.10 2 9 9 9 9 9 9 9 9 9 9

31 2 224.3 36.547 36.546 2 18.155 18.116 26.439 205.5 2 207.9 2 22.8 0.00 2 3.42 2 0.14 2 1.30 2 9 9 9 9 9 2096.6 2 9 9 9 9

30 2 241.6 36.533 36.530 2 18.063 18.021 26.453 207.1 2 208.6 2 22.5 0.00 2 3.61 2 0.15 2 1.40 2 9 9 9 9 9 9 7.9861 2 2387 2 9 9

29 2 268.3 36.517 36.517 2 17.949 17.902 26.471 209.4 2 208.8 2 22.9 0.00 2 3.81 2 0.16 2 1.40 2 9 9 9 9 9 9 9 9 9 9

28 2 298.2 36.493 36.491 2 17.775 17.724 26.498 210.7 2 209.6 2 22.9 0.00 2 4.10 2 0.18 2 1.50 2 9 9 9 9 9 9 9 9 9 9

27 2 347.1 36.418 36.424 2 17.369 17.310 26.544 207.7 2 201.5 2 32.9 0.00 2 5.27 2 0.26 2 1.90 2 9 9 9 9 9 2107.2 2 7.9664 2 9 2384 9 9

26 2 400.9 36.297 36.304 2 16.619 16.553 26.634 196.0 2 193.5 2 44.6 0.00 2 7.12 2 0.38 2 2.40 2 9 9 9 9 9 9 9 9 9 9

25 2 449.0 36.131 36.130 2 15.621 15.550 26.738 191.6 2 189.3 2 53.7 0.00 2 9.18 2 0.50 2 3.20 2 9 9 9 9 9 9 9 9 9 9

24 2 549.2 35.784 35.788 2 13.489 13.410 26.934 174.9 2 171.9 2 82.4 0.00 2 14.16 2 0.83 2 5.90 2 9 9 9 9 9 9 9 9 9 9

23 2 650.3 35.564 35.566 2 11.715 11.629 27.115 166.9 2 164.4 2 99.9 0.00 2 17.58 2 1.07 2 8.10 2 9 9 9 9 9 2163.4 2 7.7716 2 2335 2 2333 9 9

22 2 749.7 35.340 35.348 2 9.957 9.867 27.256 151.1 2 153.1 2 121.8 0.00 2 21.68 2 1.37 2 12.00 2 9 9 9 9 9 9 9 9 9 9

21 2 851.1 35.118 35.118 2 8.181 8.090 27.367 146.4 2 145.5 2 140.9 0.00 2 25.98 2 1.67 2 16.80 2 9 9 9 9 9 9 9 9 9 9

20 2 951.9 35.028 35.030 2 7.103 7.008 27.453 157.5 2 153.7 2 140.1 0.00 2 26.67 2 1.75 2 19.00 2 9 9 9 9 9 9 9 9 9 9

19 2 1050.5 35.019 35.018 2 6.335 6.236 27.550 175.7 2 173.5 2 125.6 0.00 2 25.20 2 1.67 2 18.90 2 9 9 9 9 9 2195.8 6 7.6599 2 2319 2 2317 9 9

18 2 1249.6 35.053 35.052 2 5.469 5.357 27.688 215.7 2 212.2 2 93.1 0.00 2 21.69 2 1.43 2 16.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1449.3 35.073 35.073 2 4.888 4.762 27.775 235.3 2 236.1 2 73.6 0.00 2 19.73 2 1.29 2 15.20 2 9 9 9 9 9 2172.6 2 7.7254 2 2320 2 2320 9 9

16 2 1650.2 35.060 35.061 2 4.437 4.297 27.817 246.9 2 246.4 2 66.8 0.00 2 19.15 2 1.26 2 16.10 2 9 9 9 9 9 9 9 9 9 9

15 2 1852.0 35.037 35.037 2 4.015 3.861 27.846 251.1 2 250.5 2 66.1 0.00 2 19.15 2 1.27 2 18.90 2 9 9 9 9 9 9 9 9 9 9

14 2 2050.7 35.006 35.007 2 3.622 3.455 27.863 254.0 2 253.6 2 66.3 0.00 2 19.25 2 1.28 2 21.80 2 9 9 9 9 9 2170.9 2 7.7373 2 2325 2 2323 9 9

13 2 2250.1 34.985 34.986 2 3.334 3.152 27.876 252.7 2 254.8 2 67.5 0.00 2 19.54 2 1.30 2 25.10 2 9 9 9 9 9 9 9 9 9 9

12 2 2452.5 34.967 34.968 2 3.129 2.931 27.883 254.1 2 254.8 2 69.4 0.00 2 19.73 2 1.33 2 27.80 2 9 9 9 9 9 2176.8 2 7.7312 2 2329 2 2327 9 9

11 2 2652.2 34.953 34.954 2 2.974 2.759 27.889 255.1 2 255.7 2 69.9 0.00 2 19.83 2 1.34 2 29.70 2 9 9 9 9 9 9 9 9 9 9

10 2 2849.3 34.941 34.941 2 2.831 2.599 27.894 255.9 2 258.3 2 68.6 0.00 2 20.03 2 1.35 2 31.70 2 9 9 9 9 9 9 9 9 9 9

9 2 3049.6 34.932 34.932 2 2.735 2.485 27.897 257.7 2 257.2 2 70.7 0.00 2 20.13 2 1.36 2 33.30 2 9 9 9 9 9 2180.2 2 7.7335 2 2334 2 2331 9 9

8 2 3348.6 34.915 34.916 2 2.551 2.274 27.904 258.8 2 258.2 2 71.5 0.00 2 20.32 2 1.38 2 36.10 2 9 9 9 9 9 9 9 9 9 9

7 2 3651.5 34.901 34.901 2 2.395 2.089 27.909 259.5 2 258.7 2 72.6 0.00 2 20.52 2 1.40 2 39.50 2 9 9 9 9 9 9 9 9 9 9

6 2 3952.1 34.888 34.887 2 2.261 1.925 27.913 258.4 2 258.1 2 74.6 0.00 2 20.81 2 1.43 2 42.70 2 9 9 9 9 9 2189.1 2 7.7266 2 2332 2 2338 9 9

5 2 4249.6 34.876 34.877 2 2.180 1.812 27.914 257.9 2 258.0 2 75.7 0.00 2 21.20 2 1.46 2 45.90 2 9 9 9 9 9 9 9 9 9 9

4 2 4541.1 34.868 34.868 2 2.129 1.728 27.916 256.6 2 257.3 2 77.1 0.00 2 21.49 2 1.48 2 48.50 2 9 9 9 9 9 9 9 9 9 9

3 2 4949.9 34.862 34.862 2 2.115 1.665 27.919 255.3 2 256.1 2 78.9 0.00 2 21.79 2 1.50 2 50.70 2 9 9 9 9 9 9 9 9 9 9

2 2 5307.4 34.857 2 2.114 1.619 27.921 255.1 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 5307.8 34.856 34.856 2 2.112 1.617 27.921 256.1 2 255.4 6 80.0 0.00 6 22.08 6 1.53 6 52.70 6 9 9 9 9 9 2200.1 2 7.7098 2 2345 2 2342 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

134
A5R

NOAA Ship Ronald H. Brown

STATION 66 DATE 2/9/1998 LATITUDE 24.501° N

LONGITUDE 52.637° W

CTD Bottle CTD Bottle fCO2 fCO2

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* CTA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.7 37.295 37.294 2 24.327 24.326 25.284 212.5 2 212.3 2 -6.7 0.00 2 0.00 2 0.00 2 0.70 2 1.85 2 1.07 2 0.15 2 9 275.0 326.2 2 2061.8 2 8.1064 2 5 2438 75.7 2 4.4 2

35 2 36.4 37.289 37.290 2 24.312 24.304 25.288 211.7 2 212.4 2 -6.8 0.00 2 0.00 2 0.01 2 0.70 2 1.88 2 1.09 2 0.16 2 9 9 2063.2 2 8.1050 2 5 2439 76.0 2 4.4 2

34 2 76.4 37.276 37.276 2 24.239 24.223 25.305 211.8 2 212.9 2 -7.0 0.00 2 0.00 2 0.01 2 0.70 2 1.88 2 1.07 2 0.19 2 9 9 2063.0 2 8.1059 2 5 2439 73.5 2 4.4 2

33 2 148.7 37.001 36.999 2 21.279 21.250 25.959 199.5 2 206.6 2 10.6 0.03 2 0.10 2 0.02 2 0.50 2 2.18 2 1.24 2 0.15 2 9 9 2093.7 2 8.0346 2 5 2418 57.3 2 4.3 2

32 2 200.0 36.707 36.708 2 19.363 19.326 26.253 195.9 2 198.6 2 26.7 0.01 2 0.88 2 0.04 2 0.80 2 2.28 2 1.29 2 0.06 2 9 9 2099.0 2 8.0005 2 5 2398 52.0 2 5.2 2

31 2 226.0 36.618 36.621 2 18.711 18.671 26.355 200.1 2 201.6 2 26.6 0.00 2 1.66 2 0.09 2 1.00 2 2.29 2 1.30 2 0.05 2 9 9 2095.7 2 7.9953 2 5 2391 50.3 2 5.9 2

30 2 250.9 36.571 36.576 2 18.362 18.318 26.408 201.9 2 203.9 2 25.9 0.00 2 2.34 2 0.13 2 1.20 2 2.34 6 1.31 6 0.04 6 9 9 2095.4 2 7.9929 2 5 2389 49.6 2 7.0 2

29 2 273.4 36.548 36.548 2 18.191 18.143 26.436 203.9 2 205.6 2 25.0 0.00 2 2.63 2 0.16 2 1.20 2 2.31 2 1.30 2 0.03 2 9 9 2096.2 2 7.9886 2 5 2387 47.1 2 7.2 2

28 2 297.7 36.531 36.532 2 18.066 18.014 26.456 206.4 2 205.6 2 25.6 0.00 2 2.83 2 0.18 2 1.30 2 2.34 2 1.31 2 0.03 2 9 9 2097.0 2 7.9907 2 9 2389 9 9

27 2 349.4 36.470 36.472 2 17.677 17.617 26.509 203.4 2 199.7 2 33.3 0.00 2 4.00 2 0.25 2 1.70 2 2.25 2 1.25 2 0.03 2 9 9 2104.4 2 7.9699 2 5 2383 46.7 2 8.5 2

26 2 398.7 36.339 36.337 2 16.861 16.795 26.608 193.6 2 189.6 2 47.3 0.00 2 6.05 2 0.38 2 2.20 2 2.16 2 1.16 2 0.03 2 9 9 2117.5 2 7.9348 2 9 2375 9 9

25 2 449.5 36.206 36.218 2 16.073 16.000 26.693 188.4 2 186.9 2 53.9 0.00 2 7.52 2 0.47 2 2.80 2 2.10 2 1.13 2 0.03 2 9 9 2124.5 2 7.9063 2 2372 2 2365 45.1 2 11.7 2

24 2 497.5 36.060 36.065 2 15.238 15.161 26.772 183.4 2 182.6 2 62.4 0.00 2 9.37 2 0.59 2 3.60 2 1.95 2 1.04 2 0.02 2 9 9 2129.2 2 7.8872 2 2362 2 2359 9 9

23 2 549.9 35.842 35.846 2 13.835 13.755 26.907 176.2 2 174.9 2 77.5 0.00 2 12.50 2 0.79 2 5.20 2 1.67 2 0.88 2 0.02 2 9 9 2141.3 2 7.8435 2 2356 2 2347 44.5 2 16.2 2

22 2 599.2 35.718 35.727 2 12.951 12.867 26.994 172.8 2 171.4 2 85.8 0.00 2 14.25 2 0.91 2 6.20 2 1.46 2 0.75 2 0.02 2 9 9 2149.2 2 7.8153 2 2347 2 2340 9 9

21 2 647.6 35.615 35.622 2 12.130 12.043 27.076 169.8 2 167.6 2 94.3 0.00 2 15.82 2 1.02 2 7.20 2 1.23 2 0.63 2 0.01 2 9 9 2161.2 2 7.7921 2 2341 2 2341 45.2 2 19.5 2

20 2 750.1 35.359 35.352 2 10.185 10.094 27.232 153.8 2 151.7 2 121.8 0.00 2 21.49 2 1.39 2 11.70 2 0.52 6 0.28 6 0.01 6 9 9 2188.7 2 7.7162 2 2333 2 2334 9 9

19 2 850.3 35.130 35.136 2 8.241 8.150 27.367 145.9 2 146.9 2 139.1 0.00 2 25.40 2 1.67 2 16.20 2 0.21 2 0.12 2 0.02 2 9 9 2197.5 2 7.6653 2 5 2321 42.4 2 27.5 2

18 2 950.0 35.035 35.035 2 7.149 7.054 27.453 152.1 2 153.7 2 139.8 0.00 2 26.38 2 1.76 2 18.50 2 0.11 2 0.06 2 0.00 2 9 9 2198.5 2 7.6465 2 5 2314 9 9

17 2 1049.6 35.016 35.014 2 6.450 6.350 27.533 168.0 2 167.6 2 130.8 0.00 2 25.59 2 1.72 2 18.80 2 0.09 2 0.05 2 0.01 2 9 9 2197.4 6 7.6536 2 5 2316 41.9 2 28.1 2

16 2 1248.0 35.051 35.046 2 5.525 5.413 27.680 211.6 2 211.6 2 93.3 0.00 2 21.10 2 1.44 2 15.80 2 0.22 2 0.11 2 0.00 2 9 809.1 438.3 6 2179.4 2 7.6935 2 9 2314 9 9

15 2 1449.4 35.080 35.079 2 5.007 4.880 27.767 232.8 2 233.1 2 75.7 0.00 2 19.05 2 1.32 2 14.90 2 0.16 2 0.09 2 0.00 2 9 756.1 398.7 2 2173.9 2 7.7207 2 2324 2 2319 42.3 2 22.4 2

14 2 1650.7 35.077 35.079 2 4.504 4.363 27.824 242.6 2 243.9 2 68.8 0.00 2 18.36 2 1.28 2 16.70 2 0.11 2 0.06 2 0.00 2 9 9 2168.8 2 7.7324 2 2323 2 2319 9 9

13 2 1903.2 35.032 35.032 2 3.915 3.758 27.853 250.1 2 250.7 2 66.7 0.00 2 18.46 2 1.29 2 19.80 2 0.04 2 0.02 2 0.00 2 9 9 2172.8 2 7.7359 2 9 2325 41.5 2 9

12 2 2145.7 34.998 34.999 2 3.482 3.308 27.871 252.9 2 253.7 2 67.4 0.00 2 18.76 2 1.31 2 23.60 2 0.03 2 0.01 2 0.01 2 9 9 2173.7 2 9 9 9 9

11 2 2399.7 34.972 34.972 2 3.186 2.992 27.881 254.5 2 255.5 2 68.2 0.00 2 18.95 2 1.33 2 26.90 2 0.01 2 0.01 2 0.00 2 9 9 2193.3 2 7.7332 2 2336 2 2345 41.5 2 21.6 2

10 2 2649.2 34.953 34.953 2 2.966 2.752 27.889 254.2 2 256.2 2 69.5 0.00 2 19.25 2 1.35 2 29.80 2 0.01 2 0.00 2 0.00 2 9 9 2180.2 2 9 9 9 9

9 2 2899.7 34.939 34.939 2 2.809 2.573 27.895 255.9 2 257.8 2 69.4 0.00 2 19.25 2 1.36 2 31.60 2 0.00 2 0.00 2 0.00 2 9 9 2201.5 2 7.7340 2 2336 2 2354 9 22.4 2

8 2 3198.8 34.925 34.924 2 2.640 2.376 27.902 259.1 2 258.7 2 70.1 0.00 2 19.44 2 1.38 2 34.40 2 0.00 2 0.01 2 0.00 2 9 9 2180.4 2 9 9 41.6 2 23.0 2

7 2 3499.9 34.909 34.908 2 2.474 2.182 27.907 259.6 2 258.9 2 71.6 0.00 2 19.73 2 1.41 2 37.80 2 0.00 2 0.01 2 0.00 2 9 9 2177.2 2 7.7323 2 9 2328 9 9

6 2 3799.8 34.894 34.894 2 2.327 2.006 27.911 259.4 2 259.5 2 72.5 0.00 2 20.03 2 1.43 2 41.00 2 0.00 2 0.00 2 0.00 2 9 9 2186.1 2 9 9 41.7 2 23.6 2

5 2 4100.4 34.884 34.883 2 2.229 1.877 27.914 260.4 2 259.4 2 73.7 0.00 2 20.32 2 1.45 2 43.60 2 0.01 2 0.01 2 0.03 4 9 9 2188.2 2 7.7269 2 2342 2 2337 9 23.5 2

4 2 4399.1 34.871 34.872 2 2.133 1.749 27.915 257.9 2 257.9 2 76.3 0.00 2 20.81 2 1.49 2 47.50 2 0.01 2 0.01 2 0.00 2 9 9 2193.0 2 9 9 41.7 2 23.7 2

3 2 4588.5 34.866 34.865 2 2.106 1.700 27.916 257.6 2 257.6 2 77.1 0.00 2 21.10 2 1.51 2 49.40 2 0.01 2 0.01 2 0.00 2 9 9 2194.8 2 7.7188 2 2345 2 2340 42.0 2 24.5 2

2 2 5366.6 34.850 2 2.059 1.558 27.920 255.1 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 5368.7 34.849 34.850 2 2.059 1.558 27.919 254.3 2 254.8 6 81.1 0.00 6 21.88 6 1.56 6 54.80 6 0.02 6 0.01 6 0.01 6 9 9 2199.5 2 7.7082 2 2346 2 2341 41.9 2 24.1 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

135
A5R

NOAA Ship Ronald H. Brown

STATION 67 DATE 2/9/1998 LATITUDE 24.499° N

LONGITUDE 53.183° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.0 37.040 37.041 2 24.385 24.384 25.073 212.5 2 212.1 2 -6.4 0.00 2 0.00 2 0.01 2 2 9 9 9 9 261.1 310.5 3 2050.1 6 8.1114 2 2426 2 2426 9 9

35 2 40.8 37.186 37.187 2 24.462 24.453 25.166 211.3 2 212.1 2 -6.8 0.00 2 0.00 2 0.01 2 2 9 9 9 9 9 9 8.1109 2 9 9 9

34 2 80.9 37.276 37.263 2 24.476 24.459 25.235 210.8 2 212.3 2 -7.2 0.00 2 0.00 2 0.01 2 2 9 9 9 9 268.2 320.0 2 2063.8 2 8.1055 2 2440 2 2439 9 9

33 2 142.4 37.050 37.047 2 21.607 21.579 25.904 206.4 2 207.4 2 8.5 0.04 2 0.10 2 0.02 2 2 9 9 9 9 9 9 8.0424 2 9 9 9

32 2 199.4 36.762 36.764 2 19.585 19.548 26.237 196.3 2 197.3 2 27.0 0.01 2 0.98 2 0.05 2 2 9 9 9 9 9 2105.9 2 7.9989 2 2406 2 2405 9 9

31 2 224.5 36.679 36.682 2 18.984 18.944 26.331 195.1 2 195.4 2 31.6 0.00 2 1.95 2 0.09 2 2 9 9 9 9 9 9 7.9898 2 9 9 9

30 2 247.5 36.617 36.618 2 18.582 18.538 26.388 196.0 2 198.5 2 30.3 0.00 2 2.73 2 0.14 2 2 9 9 9 9 380.8 359.6 6 2105.2 2 7.9853 2 2394 2 2395 9 9

29 2 273.3 36.582 36.578 2 18.316 18.268 26.430 199.9 2 198.1 2 31.9 0.00 2 3.42 2 0.19 2 2 9 9 9 9 9 9 7.9781 2 9 9 9

28 2 301.2 36.529 36.527 2 18.011 17.959 26.468 200.5 2 201.3 2 30.1 0.00 2 3.71 2 0.21 2 2 9 9 9 9 9 2105.5 2 7.9761 2 2389 2 2389 9 9

27 2 349.5 36.410 36.413 2 17.283 17.224 26.558 195.5 2 192.5 2 42.3 0.00 2 5.56 2 0.32 2 2 9 9 9 9 9 9 7.9473 2 9 9 9

26 2 399.9 36.269 36.269 2 16.430 16.365 26.655 190.9 2 177.6 3 61.4 0.00 2 7.32 2 0.44 2 2 9 9 9 9 438.9 379.6 2 2124.8 2 7.9208 2 2377 2 2374 9 9

25 2 450.0 36.165 36.164 2 15.788 15.716 26.727 187.4 2 183.2 2 59.0 0.00 2 8.69 2 0.53 2 2 9 9 9 9 9 9 7.8993 2 9 9 9

24 2 498.0 35.988 35.993 2 14.694 14.618 26.835 182.7 2 178.6 2 69.2 0.00 2 10.84 2 0.67 2 2 9 9 9 9 9 2140.2 2 7.8684 2 2359 2 2360 9 9

23 2 550.3 35.877 35.865 2 13.979 13.898 26.905 179.6 2 176.1 2 75.5 0.00 2 12.50 2 0.77 2 2 9 9 9 9 9 9 7.8483 2 9 9 9

22 2 652.5 35.593 35.607 2 11.947 11.860 27.094 168.8 2 167.2 2 95.7 0.00 2 16.51 2 1.04 2 2 9 9 9 9 626.1 449.1 2 2160.5 2 7.7858 2 2345 2 2337 9 9

21 2 751.5 35.372 35.379 2 10.287 10.195 27.225 155.2 2 152.3 2 120.6 0.00 2 21.30 2 1.36 2 2 9 9 9 9 9 9 7.7237 2 9 9 9

20 2 801.8 35.287 35.287 2 9.612 9.518 27.274 151.9 2 149.7 2 127.4 0.00 2 22.86 2 1.48 2 2 9 9 9 9 784.3 510.0 6 2187.5 2 7.7030 2 2331 2 2327 9 9

19 2 849.9 35.202 35.196 2 8.760 8.665 27.345 153.1 2 150.8 2 131.8 0.00 2 24.23 2 1.58 2 14.70 3 9 9 9 9 9 9 7.6829 2 9 9 9

18 2 951.4 35.055 35.055 2 7.170 7.075 27.465 159.3 2 160.2 2 133.1 0.00 2 25.50 2 1.71 2 17.50 2 9 9 9 9 9 9 7.6586 2 9 9 9

17 2 1151.1 35.057 35.056 2 5.860 5.754 27.642 197.4 2 201.2 2 101.3 0.00 2 22.08 2 1.50 2 16.00 2 9 9 9 9 815.8 448.8 2 2185.1 6 7.6918 2 2322 2 2319 9 9

16 2 1350.4 35.080 35.079 2 5.239 5.119 27.739 231.2 2 228.2 2 78.8 0.00 2 19.74 2 1.34 2 14.50 2 9 9 9 9 9 9 7.7174 2 9 9 9

15 2 1547.8 35.059 35.060 2 4.614 4.482 27.795 247.1 2 246.3 2 65.5 0.00 2 18.56 2 1.27 2 14.60 2 9 9 9 9 9 2169.1 2 7.7299 2 2323 2 2318 9 9

14 2 1749.0 35.062 35.062 2 4.215 4.069 27.843 247.6 2 248.1 2 66.9 0.00 2 18.86 2 1.28 2 18.10 2 9 9 9 9 9 9 7.7360 2 9 9 9

13 2 1951.0 35.026 35.025 2 3.769 3.609 27.862 252.7 2 252.6 2 66.0 0.00 2 18.96 2 1.29 2 20.80 2 9 9 9 9 725.5 359.6 6 2173.6 2 7.7371 2 2333 2 2326 9 9

12 2 2198.4 34.986 34.985 2 3.331 3.154 27.875 255.1 2 255.5 2 66.8 0.00 2 19.05 2 1.32 2 24.80 2 9 9 9 9 9 9 7.7360 2 9 9 9

11 2 2448.6 34.964 34.964 2 3.090 2.893 27.884 255.9 2 256.2 2 68.3 0.00 2 19.45 2 1.34 2 27.90 2 9 9 9 9 9 2179.3 2 7.7361 2 9 2332 9 9

10 2 2699.5 34.950 34.950 2 2.945 2.726 27.889 256.6 2 256.4 2 69.5 0.00 2 19.54 2 1.36 2 29.80 2 9 9 9 9 9 9 7.7356 2 9 9 9

9 2 2947.7 34.936 34.935 2 2.771 2.531 27.897 259.0 2 258.2 2 69.3 0.00 2 19.64 2 1.38 2 32.20 2 9 9 9 9 9 2181.5 2 7.7349 2 2341 2 2333 9 9

8 3 3197.5 34.923 34.923 2 2.629 2.366 27.901 259.6 2 258.7 2 70.2 0.00 2 19.84 2 1.39 2 34.60 2 9 9 9 9 9 9 7.7337 2 9 9 9

7 2 3598.3 34.902 34.901 2 2.403 2.102 27.908 261.3 2 259.8 2 71.4 0.00 2 20.13 2 1.42 2 39.00 2 9 9 9 9 9 9 7.7297 2 9 9 9

6 2 3999.4 34.887 34.886 2 2.251 1.910 27.914 260.7 2 251.9 4 80.9 0.00 2 20.42 2 1.45 2 42.50 2 9 9 9 9 743.6 340.9 6 2191.9 2 7.7273 2 2342 2 2341 9 9

5 2 4399.1 34.871 34.870 2 2.131 1.747 27.916 259.7 2 257.0 2 77.3 0.00 2 21.11 2 1.49 2 46.90 2 9 9 9 9 9 9 7.7212 2 9 9 9

4 2 4797.1 34.860 34.859 2 2.074 1.644 27.917 257.6 2 257.1 2 78.1 0.00 2 21.50 2 1.53 2 50.80 2 9 9 9 9 9 9 7.7157 2 9 9 9

3 2 5188.1 34.852 34.852 2 2.055 1.577 27.919 256.3 2 255.6 2 80.2 0.00 2 22.09 2 1.56 2 53.60 2 9 9 9 9 9 9 7.7107 2 9 9 9

2 2 5604.4 34.849 2 2.084 1.551 27.922 255.8 2 9 9 9 9 9 1 1 1 1 9 9 9 9 9 9

1 2 5605.2 34.850 34.851 2 2.083 1.550 27.922 255.8 2 255.2 6 80.8 0.00 6 22.28 6 1.58 6 54.80 6 9 9 9 9 783.4 356.0 2 2204.0 2 7.7106 2 9 2346 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

136
A5R

NOAA Ship Ronald H. Brown

STATION 68 DATE 2/9/1998 LATITUDE 24.500° N

LONGITUDE 53.733° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 37.137 37.140 2 24.450 24.449 25.127 214.6 2 212.1 2 -6.8 0.00 2 0.00 2 0.01 2 0.50 2 1.85 2 1.07 2 0.16 2 1.93 2 266.7 317.9 2 2056.2 6 8.1100 6 2431 6 2433 9 9

35 2 3.4 37.137 37.137 2 24.448 24.447 25.128 214.5 2 212.0 2 -6.7 0.00 2 0.00 2 0.01 2 0.50 2 9 9 9 9 266.5 317.6 3 9 9 9 9 9

34 2 50.6 37.232 37.232 2 24.450 24.439 25.205 211.9 2 212.7 2 -7.5 0.00 2 0.00 2 0.01 2 0.40 2 1.86 2 1.07 2 0.20 2 9 9 9 9 9 9 9

33 2 100.2 37.130 37.130 2 22.692 22.672 25.653 215.7 2 217.0 2 -5.3 0.00 2 0.00 2 0.02 2 0.20 2 2.09 6 1.18 6 0.16 6 9 9 9 9 9 9 9

32 2 150.4 36.889 36.882 2 20.543 20.514 26.075 198.6 2 200.3 2 20.0 0.02 2 0.49 2 0.03 2 0.30 2 2.21 2 1.25 2 0.12 2 0.88 2 9 9 9 9 9 9

31 2 210.7 36.609 36.606 2 18.590 18.553 26.377 201.1 2 203.8 2 24.9 0.01 2 2.44 2 0.11 2 0.70 2 2.35 2 1.31 2 0.04 2 9 9 9 9 9 9 9

30 2 236.0 36.574 36.572 2 18.368 18.326 26.408 205.6 2 207.2 2 22.6 0.00 2 2.83 2 0.14 2 0.80 2 2.35 2 1.30 2 0.05 2 9 9 9 9 9 9 9

29 2 261.4 36.554 36.553 2 18.222 18.176 26.431 206.3 2 208.2 2 22.2 0.00 2 3.03 2 0.15 2 0.90 2 2.38 2 1.31 2 0.04 2 0.53 2 9 9 9 9 9 9

28 2 285.6 36.540 36.538 2 18.123 18.073 26.447 207.8 2 208.7 2 22.2 0.00 2 3.22 2 0.17 2 1.00 2 2.37 2 1.31 2 0.04 2 9 9 9 9 9 9 9

27 2 355.3 36.489 36.487 2 17.791 17.730 26.496 204.4 2 205.4 2 27.1 0.00 2 4.10 2 0.23 2 1.20 2 2.32 2 1.27 2 0.04 2 9 9 9 9 9 9 9

26 2 422.7 36.324 36.324 2 16.784 16.714 26.617 189.0 2 189.3 2 48.0 0.00 2 6.93 2 0.41 2 2.00 2 2.16 2 1.15 2 0.03 2 0.45 2 9 9 9 9 9 9

25 2 500.6 36.058 36.052 2 15.172 15.094 26.785 186.1 2 183.2 2 62.2 0.00 2 10.06 2 0.61 2 3.40 2 1.99 2 1.05 2 0.02 2 9 9 9 9 9 9 9

24 2 598.6 35.775 35.784 2 13.280 13.195 26.972 172.1 2 169.0 2 86.4 0.00 2 14.35 2 0.88 2 5.40 2 1.53 2 0.79 2 0.03 2 9 9 9 9 9 9 9

23 2 701.1 35.504 35.502 2 11.287 11.197 27.149 160.6 2 159.7 2 107.1 0.00 2 18.85 2 1.19 2 8.80 2 0.89 2 0.45 2 0.02 2 9 9 9 9 9 9 9

22 2 800.2 35.267 35.276 2 9.317 9.225 27.306 153.6 2 152.1 2 126.8 0.00 2 22.76 2 1.48 2 13.00 2 0.43 2 0.22 2 0.01 2 0.18 2 9 9 9 9 9 9

21 2 900.6 35.110 35.102 2 7.807 7.713 27.417 154.3 2 154.3 2 134.6 0.00 2 25.20 2 1.66 2 16.60 2 0.20 2 0.11 2 0.00 2 9 9 9 9 9 9 9

20 2 1001.5 35.043 35.043 2 6.666 6.569 27.525 166.0 2 171.2 2 125.6 0.00 2 24.82 2 1.68 2 17.70 2 0.16 2 0.09 2 0.01 2 9 9 9 9 9 9 9

19 2 1198.4 35.099 35.098 2 5.776 5.666 27.687 211.3 2 213.4 2 89.6 0.00 2 20.61 2 1.40 2 14.70 2 0.29 2 0.15 2 0.01 2 0.58 2 9 9 9 9 9 9

18 2 1399.2 35.099 35.100 2 5.055 4.933 27.776 236.6 2 235.2 2 73.2 0.00 2 19.15 2 1.31 2 14.70 2 0.23 2 0.12 2 0.24 4 9 9 9 9 9 9 9

17 2 1598.5 35.064 35.063 2 4.440 4.305 27.819 246.4 2 247.0 2 66.2 0.00 2 18.66 2 1.29 2 15.90 2 0.11 2 0.06 2 0.00 2 9 9 9 9 9 9 9

16 2 1797.8 35.039 35.038 2 4.050 3.901 27.843 251.6 2 251.3 2 65.0 0.00 2 18.76 2 1.29 2 18.00 2 0.04 2 0.03 2 0.01 2 0.34 2 9 9 9 9 9 9

15 2 1899.2 35.028 35.027 2 3.846 3.690 27.856 252.6 2 252.0 2 66.0 0.00 2 18.95 2 1.30 2 19.90 2 0.03 2 0.02 2 0.00 2 9 9 9 9 9 9 9

14 2 1999.5 35.017 35.016 2 3.686 3.523 27.864 253.8 2 254.1 2 65.2 0.00 2 18.86 2 1.29 2 21.30 2 9 9 9 9 9 9 9 9 9 9

13 2 2399.6 34.970 34.970 2 3.155 2.962 27.882 255.5 2 256.4 2 67.5 0.00 2 19.25 2 1.32 2 27.00 2 0.04 2 0.02 2 0.00 2 0.28 2 9 9 9 9 9 9

12 2 2599.9 34.956 34.957 2 3.008 2.798 27.887 255.7 2 256.6 2 68.7 0.00 2 19.54 2 1.36 2 29.30 2 9 9 9 9 9 9 9 9 9 9

11 2 2800.5 34.944 34.944 2 2.862 2.635 27.893 256.0 2 257.3 2 69.3 0.00 2 19.83 2 1.38 2 31.70 2 9 9 9 9 9 9 9 9 9 9

10 2 3000.8 34.934 34.934 2 2.753 2.507 27.897 257.1 2 257.2 6 70.5 0.00 2 19.93 2 1.39 2 33.10 2 0.00 2 0.01 2 0.00 2 0.13 2 9 9 9 9 9 9

9 2 3298.7 34.917 34.916 2 2.558 2.286 27.904 259.3 2 259.3 2 70.3 0.00 2 20.03 2 1.41 2 36.10 2 9 9 9 9 9 9 9 9 9 9

8 2 3599.2 34.902 34.902 2 2.404 2.103 27.908 260.1 2 260.4 2 70.8 0.00 2 20.13 2 1.42 2 38.20 2 0.01 2 0.00 2 0.00 2 0.11 2 9 9 9 9 9 9

7 2 3899.5 34.890 34.890 2 2.276 1.945 27.913 261.5 2 261.5 2 71.0 0.00 2 20.23 2 1.43 2 40.90 2 0.01 2 0.01 2 0.00 2 0.13 2 9 9 9 9 9 9

6 2 4297.5 34.877 34.877 2 2.177 1.804 27.916 260.6 2 260.5 2 73.3 0.00 2 20.71 2 1.46 2 44.50 2 0.02 2 0.02 2 0.00 2 0.19 2 9 9 9 9 9 9

5 2 4699.8 34.861 34.860 2 2.064 1.646 27.917 257.6 2 257.5 2 77.6 0.00 2 21.59 2 1.53 2 51.00 2 0.02 2 0.02 2 0.01 2 0.19 2 9 9 9 9 9 9

4 2 5098.8 34.850 34.849 2 2.019 1.554 27.918 254.6 2 255.1 2 80.9 0.00 2 22.18 2 1.57 2 54.90 2 0.02 2 0.02 2 0.00 2 0.18 2 9 9 9 9 9 9

3 2 5500.1 34.846 34.845 2 2.034 1.517 27.921 254.0 2 254.5 2 81.8 0.00 2 22.38 2 1.59 2 56.80 2 0.03 2 0.02 2 0.00 2 0.19 6 9 9 9 9 9 9

2 2 6076.4 34.845 2 2.107 1.510 27.925 255.3 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 6076.6 34.844 34.844 2 2.107 1.510 27.925 255.3 2 254.2 6 82.2 0.00 6 22.47 6 1.59 6 57.20 6 0.02 2 0.02 2 0.00 2 0.20 6 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

137
A5R

NOAA Ship Ronald H. Brown

STATION 69 DATE 2/10/1998 LATITUDE 24.499° N

LONGITUDE 54.467° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.7 37.208 37.207 2 23.640 23.639 25.423 189.2 2 214.2 2 -6.1 0.00 2 0.00 2 0.01 2 0.40 2 9 9 9 9 276.8 319.8 2 2060.3 6 8.1000 2 2429 2 2431 9 9

35 2 40.8 37.267 37.267 2 23.546 23.537 25.501 213.4 2 215.4 2 -7.0 0.00 2 0.00 2 0.01 2 0.40 2 9 9 9 9 9 9 9 9 9 9

34 2 87.7 37.214 37.224 2 23.025 23.007 25.619 215.0 2 216.8 2 -6.5 0.00 2 0.00 2 0.01 2 0.40 2 9 9 9 9 288.6 325.5 2 2070.9 2 8.0831 2 2428 2 2430 9 9

33 2 139.3 36.865 36.866 2 20.341 20.315 26.109 199.7 2 203.1 2 18.0 0.02 2 0.59 2 0.03 2 0.40 2 9 9 9 9 351.0 355.8 2 2092.9 2 8.0182 2 2407 2 2405 9 9

32 2 198.3 36.634 36.630 2 18.734 18.699 26.358 199.9 2 201.4 2 26.7 0.01 2 2.34 2 0.10 2 0.80 2 9 9 9 9 374.5 355.8 2 2098.9 2 7.9930 2 2390 2 2393 9 9

31 2 224.5 36.575 36.575 2 18.349 18.310 26.413 201.0 2 202.7 2 27.1 0.00 2 3.32 2 0.15 2 1.00 2 9 9 9 9 9 9 9 9 9 9

30 2 247.9 36.553 36.552 2 18.191 18.148 26.438 204.7 2 203.4 2 27.2 0.00 2 3.61 2 0.18 2 1.10 2 9 9 9 9 385.2 358.0 2 2101.5 2 7.9880 2 9 2392 9 9

29 2 273.2 36.519 36.519 2 17.960 17.913 26.471 201.9 2 204.2 2 27.4 0.00 2 4.00 2 0.20 2 1.20 2 9 9 9 9 9 9 9 9 9 9

28 2 299.4 36.493 36.493 2 17.790 17.738 26.495 197.6 2 197.8 2 34.6 0.00 2 4.88 2 0.26 2 1.40 2 9 9 9 9 389.1 355.8 2 2109.3 2 7.9672 2 2383 2 2387 9 9

27 2 349.9 36.404 36.407 2 17.268 17.209 26.557 195.4 2 195.8 2 39.1 0.00 2 5.85 2 0.32 2 1.80 2 9 9 9 9 9 9 9 9 9 9

26 2 394.9 36.244 36.250 2 16.309 16.245 26.664 186.9 2 184.7 2 54.9 0.00 2 8.30 2 0.48 2 2.50 2 9 9 9 9 473.0 407.3 2 2126.3 2 7.9147 2 2369 2 2372 9 9

25 2 451.5 36.062 36.077 2 15.169 15.099 26.785 187.1 2 180.5 2 64.8 0.00 2 10.35 2 0.61 2 3.40 2 9 9 9 9 9 9 9 9 9 9

24 2 552.3 35.813 35.816 2 13.502 13.423 26.953 175.2 2 173.2 2 81.0 0.00 2 13.67 2 0.84 2 5.10 2 9 9 9 9 580.9 445.0 2 2146.5 2 7.8214 2 2347 2 2341 9 9

23 2 650.8 35.584 35.581 2 11.842 11.756 27.106 162.2 2 159.9 2 103.6 0.00 2 18.06 2 1.11 2 7.80 2 9 9 9 9 9 9 9 9 9 9

22 2 757.8 35.292 35.300 2 9.726 9.637 27.258 154.2 2 146.5 2 129.9 0.00 2 23.05 2 1.47 2 12.60 2 9 9 9 9 784.2 513.2 2 2181.2 2 7.7006 2 2324 2 2320 9 9

21 2 851.8 35.114 35.117 2 8.058 7.968 27.382 149.2 2 149.5 2 137.7 0.00 2 25.59 2 1.68 2 16.40 2 9 9 9 9 9 9 9 9 9 9

20 2 949.8 35.041 35.041 2 7.077 6.983 27.467 159.0 2 158.0 2 135.9 0.00 2 26.08 2 1.74 2 18.20 2 9 9 9 9 9 9 9 9 9 9

19 2 1050.5 35.030 35.027 2 6.211 6.113 27.575 179.6 2 180.9 2 119.1 0.00 2 24.32 2 1.63 2 17.80 2 9 9 9 9 848.9 475.1 6 2188.1 6 7.6699 2 2320 2 2313 9 9

18 2 1149.8 35.046 35.047 2 5.782 5.677 27.643 202.6 2 203.0 2 100.0 0.00 2 22.17 2 1.50 2 16.40 2 9 9 9 9 9 9 9 9 9 9

17 2 1350.7 35.083 35.085 2 5.133 5.014 27.753 234.9 2 230.8 2 77.0 0.00 2 19.73 2 1.33 2 14.70 2 9 9 9 9 9 9 9 9 9 9

16 2 1548.6 35.084 35.084 2 4.681 4.548 27.808 244.5 2 244.1 2 67.2 0.00 2 18.85 2 1.27 2 15.10 2 9 9 9 9 718.3 372.2 2 2165.6 2 7.7303 2 2322 2 2315 9 9

15 2 1748.6 35.058 35.057 2 4.191 4.045 27.843 247.7 2 248.9 2 66.3 0.00 2 18.85 2 1.28 2 18.10 2 9 9 9 9 9 9 9 9 9 9

14 2 1949.0 35.026 35.027 2 3.807 3.647 27.859 252.0 2 252.3 2 66.0 0.00 2 18.95 2 1.30 2 20.50 2 9 9 9 9 722.4 358.7 2 2166.4 2 7.7371 2 2324 2 2319 9 9

13 2 2148.0 34.993 34.992 2 3.411 3.238 27.873 253.9 2 254.5 2 67.1 0.00 2 19.24 2 1.32 2 24.20 2 9 9 9 9 9 9 9 9 9 9

12 2 2342.6 34.976 34.975 2 3.204 3.016 27.881 254.1 2 255.5 2 68.0 0.00 2 19.44 2 1.34 2 26.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2546.7 34.958 34.958 2 3.009 2.804 27.887 255.6 2 254.0 2 71.2 0.00 2 19.64 2 1.36 2 29.00 2 9 9 9 9 9 9 9 9 9 9

10 2 2750.2 34.946 34.945 2 2.872 2.650 27.892 255.6 2 256.4 2 70.1 0.00 2 19.73 2 1.37 2 31.00 2 9 9 9 9 9 9 9 9 9 9

9 2 2948.0 34.936 34.935 2 2.758 2.518 27.897 256.6 2 257.6 2 70.0 0.00 2 19.83 2 1.38 2 32.70 2 9 9 9 9 721.7 339.6 2 2176.5 2 7.7303 2 2334 2 2326 9 9

8 2 3248.4 34.918 34.917 2 2.556 2.289 27.904 258.8 2 258.9 2 70.7 0.00 2 20.12 2 1.40 2 36.00 2 9 9 9 9 9 9 9 9 9 9

7 2 3547.9 34.905 34.903 2 2.407 2.112 27.909 260.5 2 260.6 2 70.5 0.00 2 20.12 2 1.41 2 37.60 2 9 9 9 9 9 2178.7 2 9 9 9 9

6 2 3893.0 34.889 34.890 2 2.268 1.938 27.913 259.7 2 261.0 2 71.6 0.00 2 20.42 2 1.44 2 40.80 2 9 9 9 9 742.6 340.9 2 2183.0 2 7.7278 2 2337 2 2332 9 9

5 2 4346.7 34.877 34.877 2 2.169 1.790 27.918 261.4 2 261.3 2 72.6 0.00 2 20.61 2 1.45 2 43.70 2 9 9 9 9 9 9 9 9 9 9

4 2 4742.7 34.861 34.860 2 2.074 1.651 27.918 256.9 2 257.1 2 78.0 0.00 2 21.49 2 1.52 2 50.40 2 9 9 9 9 9 9 9 9 9 9

3 2 5141.1 34.849 34.848 2 2.016 1.545 27.918 254.0 2 254.9 2 81.1 0.00 2 22.27 2 1.57 2 55.00 2 9 9 9 9 9 9 9 9 9 9

2 2 5241.7 34.848 2 2.019 1.535 27.919 253.2 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 5244.0 34.848 34.849 2 2.019 1.535 27.919 253.3 2 254.8 6 81.3 0.00 6 22.37 6 1.57 6 55.70 6 9 9 9 9 784.8 355.5 2 2199.0 2 7.7076 2 2345 2 2340 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

138
A5R

NOAA Ship Ronald H. Brown

STATION 70 DATE 2/10/1998 LATITUDE 24.499° N

LONGITUDE 55.201° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.8 37.121 37.121 2 23.724 23.723 25.333 214.5 2 215.0 2 -7.1 0.00 2 0.00 2 0.00 2 0.40 2 1.91 2 1.11 2 0.15 2 9 260.2 301.6 6 2056.3 6 8.1015 2 2432 2 2427 76.8 2 9

35 2 46.8 37.180 37.181 2 23.692 23.682 25.392 213.9 2 212.6 2 -4.6 0.00 2 0.00 2 0.00 2 0.40 2 1.91 2 1.11 2 0.19 2 9 9 2059.5 2 8.0994 2 2436 2 2429 72.3 2 9

34 2 91.2 37.225 37.222 2 23.193 23.174 25.578 215.5 2 216.4 2 -6.7 0.00 2 0.00 2 0.01 2 0.30 2 2.02 2 1.19 2 0.21 2 9 286.5 325.3 2 2071.2 2 8.0847 2 2441 2 2432 73.1 2 9

33 2 135.6 36.933 36.935 2 20.675 20.649 26.071 205.3 2 201.9 2 17.8 0.02 2 0.39 2 0.02 2 0.40 2 2.20 2 1.25 2 0.13 2 9 341.9 351.0 2 2095.6 2 8.0226 2 2422 2 2412 57.8 2 9

32 2 201.5 36.669 36.661 2 18.937 18.901 26.333 193.4 2 195.9 2 31.3 0.01 2 2.44 2 0.11 2 0.70 2 2.31 6 1.28 6 0.04 6 9 389.0 372.7 2 2101.4 2 7.9880 2 2398 2 2393 53.4 2 9

31 2 226.0 36.588 36.591 2 18.398 18.358 26.411 199.8 2 200.0 2 29.6 0.00 2 3.12 2 0.16 2 0.90 2 2.32 2 1.28 2 0.03 2 9 376.3 352.8 2 2098.7 2 7.9861 2 2392 2 2388 52.1 2 9

30 2 249.0 36.565 36.564 2 18.249 18.205 26.432 198.8 2 200.1 2 30.2 0.00 2 3.61 2 0.19 2 1.10 2 2.32 2 1.27 2 0.03 2 9 9 2100.6 2 7.9834 2 2390 2 2388 50.2 2 9

29 2 274.6 36.539 36.538 2 18.067 18.019 26.460 198.7 2 199.8 2 31.3 0.00 2 3.90 2 0.21 2 1.10 2 2.30 2 1.26 2 0.03 2 9 384.5 355.5 2 2101.8 2 7.9768 2 5 2385 50.0 2 9

28 2 301.5 36.508 36.511 2 17.871 17.819 26.487 197.5 2 198.5 2 33.6 0.00 2 4.39 2 0.24 2 1.30 2 2.28 2 1.24 2 0.03 2 9 9 2105.2 2 7.9725 2 2388 2 2386 9 9

27 2 351.9 36.427 36.426 2 17.398 17.338 26.544 190.7 2 191.9 2 42.4 0.00 2 5.76 2 0.33 2 1.70 2 2.21 2 1.20 2 0.02 2 9 422.8 380.7 2 2112.2 2 7.9493 2 2382 2 2379 47.9 2 9

26 2 399.0 36.276 36.284 2 16.470 16.405 26.652 190.5 2 184.4 2 54.4 0.00 2 7.71 2 0.46 2 2.20 2 2.12 2 1.13 2 0.03 2 9 9 2123.8 2 7.9191 2 5 2372 9 9

25 2 451.3 36.091 36.097 2 15.396 15.325 26.758 187.1 2 184.7 2 59.5 0.00 2 9.37 2 0.57 2 3.10 2 2.03 2 1.07 2 0.02 2 9 477.8 395.9 2 2128.8 2 7.8933 2 5 2362 46.9 2 9

24 2 500.4 35.940 35.954 2 14.394 14.319 26.863 176.9 2 174.2 2 75.2 0.00 2 11.81 2 0.73 2 4.00 2 1.83 2 0.95 2 0.03 2 9 9 2140.7 2 7.8565 2 2357 2 2354 9 9

23 2 600.9 35.724 35.718 2 12.880 12.796 27.012 164.0 2 161.9 2 95.7 0.00 2 15.81 2 0.97 2 6.10 2 1.34 2 0.69 2 0.01 2 9 626.5 468.0 2 2157.4 2 7.7953 2 2346 2 2339 46.1 2 9

22 2 699.2 35.434 35.441 2 10.744 10.657 27.191 155.7 2 156.6 2 113.5 0.00 2 19.92 2 1.27 2 9.80 2 0.75 6 0.39 6 0.01 6 9 9 2171.8 2 7.7420 2 5 2328 9 9

21 2 800.2 35.214 35.220 2 9.043 8.953 27.309 148.6 2 147.1 2 133.6 0.00 2 24.12 2 1.56 2 14.10 2 0.33 2 0.17 2 0.00 2 9 817.9 519.5 2 2188.5 2 7.6855 2 2324 2 2321 42.1 2 9

20 2 847.1 35.144 35.143 2 8.292 8.201 27.371 149.1 2 148.9 2 136.8 0.00 2 25.29 2 1.66 2 15.80 2 0.21 6 0.11 6 0.01 6 9 866.6 533.6 2 2194.1 2 7.6676 2 5 2319 9 9

19 2 901.0 35.065 35.068 2 7.463 7.371 27.431 150.6 2 151.3 2 140.0 0.00 2 26.08 2 1.73 2 17.50 2 9 9 9 9 888.5 527.5 2 2207.4 2 7.6544 2 2327 2 2327 9 9

18 2 1000.2 35.020 35.019 2 6.583 6.487 27.517 167.7 2 168.8 2 128.6 0.00 2 25.49 2 1.70 2 18.20 2 0.14 2 0.07 2 0.13 4 9 884.5 504.6 2 2195.2 6 7.6565 2 9 2315 9 9

17 2 1199.8 35.056 35.054 2 5.568 5.460 27.678 210.5 2 212.6 2 92.0 0.00 2 21.19 2 1.44 2 15.40 2 0.22 2 0.12 2 0.01 2 9 9 2180.5 2 7.6994 2 9 2317 42.0 2 9

16 2 1402.0 35.058 35.058 2 4.879 4.758 27.763 238.7 2 239.8 2 69.9 0.00 2 19.05 2 1.30 2 13.90 2 0.22 2 0.12 2 0.00 2 9 743.8 389.8 6 2165.2 3 7.7230 2 9 2311 9 9

15 2 1595.1 35.051 35.051 2 4.476 4.341 27.805 251.2 2 250.1 2 62.8 0.00 2 18.36 2 1.26 2 14.30 2 0.18 2 0.09 2 0.02 2 9 9 2184.8 2 7.7328 2 5 2336 9 9

14 2 1791.0 35.038 35.038 2 4.126 3.977 27.835 254.4 2 254.0 2 61.7 0.00 2 18.36 2 1.26 2 16.20 2 0.06 2 0.04 2 0.00 2 9 707.4 356.8 2 2160.2 2 7.7376 2 5 2312 9 9

13 2 1999.7 35.018 35.018 2 3.763 3.599 27.858 254.6 2 253.8 2 64.9 0.00 2 18.75 2 1.29 2 20.20 2 0.01 2 0.02 2 0.00 2 9 9 2191.2 2 7.7369 2 9 2344 9 9

12 2 2199.6 34.996 34.996 2 3.466 3.287 27.871 255.4 2 255.0 2 66.2 0.00 2 18.85 2 1.31 2 23.30 2 0.01 2 0.01 2 0.01 2 9 717.6 350.2 2 2172.6 2 9 9 9 9

11 2 2497.0 34.965 34.965 2 3.102 2.900 27.884 256.0 2 256.1 2 68.3 0.00 2 19.34 2 1.34 2 27.60 2 0.00 2 0.01 2 0.00 2 9 9 2177.0 2 7.7346 2 9 2328 41.5 2 9

10 2 2799.7 34.946 34.947 2 2.894 2.666 27.892 257.8 2 259.1 2 67.3 0.00 2 19.44 2 1.36 2 30.30 2 0.00 2 0.00 2 0.00 2 9 729.4 345.9 2 2178.8 2 9 9 9 9

9 2 3098.0 34.932 34.931 2 2.729 2.474 27.899 260.2 2 258.9 2 69.1 0.00 2 19.63 2 1.37 2 32.40 2 0.00 2 0.00 2 0.00 2 9 9 2172.7 2 7.7338 2 9 2324 9 9

8 2 3495.7 34.912 34.912 2 2.498 2.206 27.907 262.8 2 262.1 2 68.2 0.00 2 19.73 2 1.38 2 35.00 2 0.01 2 0.01 2 0.00 2 9 723.3 336.0 2 2180.1 2 9 9 9 9

7 2 3899.4 34.897 34.898 2 2.330 1.998 27.914 266.0 2 263.9 2 68.2 0.00 2 19.63 2 1.38 2 36.80 2 0.02 2 0.01 2 0.00 2 9 9 2181.6 2 7.7314 2 2339 2 2332 9 9

6 2 4300.9 34.890 34.890 2 2.247 1.871 27.921 268.6 2 268.1 2 65.0 0.00 2 19.24 2 1.36 2 36.40 2 0.05 2 0.03 2 0.00 2 9 736.5 338.0 2 2181.1 2 9 9 9 9

5 2 4699.9 34.869 34.869 2 2.134 1.714 27.919 261.1 2 260.1 2 74.4 0.00 2 20.90 2 1.48 2 46.70 2 0.02 2 0.02 2 0.00 2 9 9 2192.6 2 7.7190 2 2346 2 2338 45.7 3 9

4 2 5098.0 34.853 34.853 2 2.036 1.570 27.920 258.4 2 256.5 2 79.3 0.00 2 21.88 2 1.54 2 52.70 2 0.03 2 0.02 2 0.00 2 9 782.6 355.0 2 2199.5 2 9 9 9 9

3 2 5597.1 34.844 34.844 2 2.028 1.498 27.921 255.5 2 254.3 2 82.2 0.00 2 22.37 2 1.59 2 56.60 2 0.02 2 0.02 2 0.00 2 9 792.5 359.2 2 2204.1 2 7.7028 2 9 2343 9 9

2 2 6006.6 34.843 2 2.077 1.490 27.924 254.8 2 9 9 9 9 9 1 1 1 9 9 9 9 9 9 9

1 2 6007.9 34.842 34.844 2 2.077 1.490 27.924 254.8 2 253.9 6 82.6 0.00 6 22.47 6 1.59 2 57.00 2 0.03 6 0.02 6 0.00 6 9 798.2 362.8 6 2204.1 2 7.7040 2 2349 2 2344 41.4 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

139
A5R

NOAA Ship Ronald H. Brown

STATION 71 DATE 2/10/1998 LATITUDE 24.500° N

LONGITUDE 55.933° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.8 36.973 36.972 2 24.146 24.145 25.095 213.1 2 212.9 2 -6.3 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 282.2 332.3 2 2046.5 6 8.1083 2 2418 2 2419 9 9

35 2 51.7 36.978 36.979 2 24.121 24.110 25.112 212.5 2 213.2 2 -6.5 0.00 2 0.00 2 0.00 2 1.00 2 9 9 9 9 9 9 8.1077 2 9 9 9

34 2 99.4 37.052 37.054 2 23.132 23.111 25.466 216.5 2 216.6 2 -6.4 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 300.3 340.0 2 2064.4 2 8.0850 2 2418 2 2423 9 9

33 2 151.3 36.932 36.937 2 20.843 20.814 26.026 200.5 2 201.8 2 17.2 0.02 2 0.49 2 0.02 2 0.70 2 9 9 9 9 9 9 8.0238 2 9 9 9

32 2 211.7 36.720 36.719 2 19.198 19.160 26.306 194.0 2 195.7 2 30.3 0.01 2 2.24 2 0.08 2 1.00 2 9 9 9 9 396.3 383.7 2 2107.0 2 7.9902 2 2396 2 2401 9 9

31 2 235.0 36.637 36.637 2 18.681 18.639 26.378 200.0 2 197.7 2 30.6 0.00 2 3.12 2 0.13 2 1.30 2 9 9 9 9 394.9 374.4 2 2105.0 2 7.9863 2 2392 2 2395 9 9

30 2 250.8 36.587 36.586 2 18.430 18.386 26.404 204.8 2 201.6 2 27.9 0.00 2 3.32 2 0.15 2 1.10 2 9 9 9 9 388.0 364.3 2 2099.0 2 4 2388 2 9 9

29 2 285.5 36.544 36.544 2 18.136 18.086 26.447 203.1 2 203.9 2 26.9 0.00 2 3.80 2 0.19 2 1.40 2 9 9 9 9 392.4 363.9 2 2099.4 2 7.9864 2 2392 2 2389 9 9

28 2 335.8 36.483 36.480 2 17.762 17.704 26.497 195.8 2 197.6 2 35.0 0.00 2 5.07 2 0.26 2 1.70 2 9 9 9 9 9 9 9 9 9 9

27 2 386.1 36.324 36.344 2 16.743 16.679 26.624 190.0 2 187.8 2 49.6 0.00 2 7.32 2 0.40 2 2.30 2 9 9 9 9 9 9 9 9 9 9

26 2 436.9 36.212 36.217 2 16.098 16.027 26.691 186.4 2 184.3 6 56.3 0.00 2 8.78 2 0.50 2 2.90 2 9 9 9 9 9 9 9 9 9 9

25 2 482.2 36.081 36.083 2 15.320 15.245 26.769 181.5 2 180.0 2 64.6 0.00 2 10.44 2 0.61 2 3.60 2 9 9 9 9 498.6 411.7 2 2134.3 2 7.8843 2 2365 2 2363 9 9

24 2 580.8 35.754 35.748 2 13.131 13.049 26.984 168.4 2 168.0 2 88.2 0.00 2 15.03 2 0.92 2 6.10 2 9 9 9 9 9 9 9 9 9 9

23 2 683.4 35.510 35.505 2 11.369 11.281 27.138 159.6 2 159.6 2 106.7 0.00 2 19.04 2 1.19 2 9.00 2 9 9 9 9 677.6 474.7 2 2169.2 2 7.7582 2 2338 2 2333 9 9

22 2 786.6 35.317 35.303 2 9.732 9.639 27.277 157.3 2 155.4 2 121.0 0.00 2 22.36 2 1.43 2 12.50 2 9 9 9 9 769.4 503.2 2 2182.6 2 7.7112 2 2331 2 2326 9 9

21 2 850.5 35.163 35.159 2 8.360 8.268 27.376 153.3 2 152.3 2 132.9 0.00 2 25.00 2 1.62 2 15.50 2 9 9 9 9 860.3 531.3 2 2191.1 2 7.6761 2 2327 2 2319 9 9

20 2 949.5 35.043 35.043 2 7.175 7.080 27.455 156.8 2 157.5 2 135.8 0.00 2 26.17 2 1.73 2 18.20 2 9 9 9 9 9 9 9 9 9 9

19 2 1049.3 35.028 35.025 2 6.276 6.177 27.565 176.2 2 178.7 2 120.8 0.00 2 24.80 2 1.66 2 18.30 2 9 9 9 9 876.1 492.6 2 2190.8 6 7.6667 2 2318 2 2315 9 9

18 2 1246.9 35.070 35.069 2 5.423 5.312 27.707 221.3 2 222.5 2 83.1 0.00 2 20.41 2 1.37 2 14.80 2 9 9 9 9 9 9 9 9 9 9

17 2 1451.8 35.058 35.059 2 4.774 4.650 27.776 244.8 2 244.0 2 66.6 0.00 2 19.04 2 1.28 2 14.10 2 9 9 9 9 748.2 390.2 2 2165.8 2 7.7286 2 2317 2 2314 9 9

16 2 1650.5 35.046 35.046 2 4.330 4.192 27.817 252.8 2 252.1 2 62.0 0.00 2 18.75 2 1.26 2 15.20 2 9 9 9 9 9 9 9 9 9 9

15 2 1848.4 35.033 35.032 2 4.006 3.853 27.843 254.4 2 254.9 2 61.8 0.00 2 18.75 2 1.27 2 17.40 2 9 9 9 9 9 9 9 9 9 9

14 2 2047.8 35.010 35.009 2 3.679 3.511 27.860 256.8 2 257.3 2 62.1 0.00 2 18.95 2 1.28 2 20.10 2 9 9 9 9 9 9 9 9 9 9

13 2 2249.0 34.990 34.990 2 3.412 3.229 27.872 256.9 2 256.8 2 64.9 0.00 2 19.34 2 1.31 2 23.30 2 9 9 9 9 9 2170.8 2 7.7390 2 2327 2 2324 9 9

12 2 2449.4 34.969 34.969 2 3.159 2.961 27.882 257.4 2 257.2 2 66.7 0.00 2 19.63 2 1.34 2 26.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2648.1 34.955 34.957 2 2.998 2.783 27.887 257.8 2 258.2 2 67.2 0.00 2 19.83 2 1.35 2 28.60 2 9 9 9 9 719.8 343.0 2 2172.5 2 7.7373 2 2334 2 2325 9 9

10 2 2949.4 34.938 34.938 2 2.801 2.560 27.896 260.3 2 259.8 2 67.5 0.00 2 19.83 2 1.36 2 31.00 2 9 9 9 9 9 9 9 9 9 9

9 2 3254.0 34.925 34.926 2 2.660 2.390 27.902 261.4 2 261.0 2 67.7 0.00 2 19.92 2 1.37 2 32.70 2 9 9 9 9 9 2175.1 2 7.7375 2 2337 2 2328 9 9

8 2 3549.0 34.911 34.911 2 2.495 2.197 27.908 263.4 2 241.0 4 89.3 0.00 2 20.02 2 1.37 2 34.90 2 9 9 9 9 9 9 9 9 9 9

7 2 3849.9 34.901 34.900 2 2.368 2.040 27.914 266.1 2 265.5 2 66.2 0.00 2 19.73 2 1.36 2 35.30 2 9 9 9 9 9 9 9 9 9 9

6 2 4249.7 34.894 34.896 2 2.294 1.923 27.921 270.7 2 268.4 2 64.3 0.00 2 19.44 2 1.35 2 34.60 2 9 9 9 9 724.4 333.1 2 2174.8 2 7.7353 2 2338 2 2326 9 9

5 2 4545.8 34.887 34.886 2 2.249 1.844 27.923 268.6 2 266.7 2 66.7 0.00 2 19.83 2 1.37 2 37.50 2 9 9 9 9 9 9 9 9 9 9

4 2 5050.2 34.858 34.859 2 2.073 1.612 27.921 259.4 2 255.8 2 79.6 0.00 2 21.78 2 1.52 2 50.60 2 9 9 9 9 784.7 356.9 2 2193.4 2 7.7157 6 5 2338 9 9

3 2 5547.7 34.843 34.842 2 2.014 1.491 27.920 253.7 2 254.5 2 82.0 0.00 2 22.76 2 1.59 2 57.40 2 9 9 9 9 9 9 9 9 9 9

2 2 6049.7 34.842 34.842 2 2.079 1.486 27.924 254.6 2 252.7 2 83.9 0.00 2 22.85 2 1.60 2 57.70 2 9 9 9 9 794.8 361.1 6 9 9 9 9 9

1 2 6594.1 34.842 34.843 2 2.159 1.487 27.929 255.5 2 254.4 2 82.2 0.00 6 22.85 6 1.60 6 57.70 2 9 9 9 9 793.4 361.9 2 2202.7 2 7.7046 2 5 2342 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

140
A5R

NOAA Ship Ronald H. Brown

STATION 72 DATE 2/11/1998 LATITUDE 24.500° N

LONGITUDE 56.667° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 36.974 36.976 2 23.907 23.906 25.167 213.9 2 212.9 2 -5.4 0.00 2 0.00 2 0.00 2 0.60 2 1.89 2 1.10 2 0.16 2 2.07 2 275.4 321.4 6 2046.1 6 8.1043 2 2415 2 2416 78.9 2 9

35 2 50.4 37.050 37.070 2 23.991 23.980 25.205 214.6 2 213.1 2 -6.0 0.00 2 0.00 2 0.00 2 0.60 2 9 9 9 1.93 6 9 9 9 9 77.8 2 9

34 2 101.2 37.010 36.999 2 22.502 22.481 25.616 218.6 2 218.6 2 -6.0 0.01 2 0.00 2 0.01 2 0.40 2 2.10 2 1.20 2 0.18 2 9 9 9 9 9 65.9 2 9

33 2 152.0 36.797 36.802 2 20.037 20.009 26.140 209.2 2 208.1 2 14.3 0.03 2 0.39 2 0.02 2 0.50 2 2.27 2 1.28 2 0.14 2 1.04 2 9 9 9 9 57.9 2 9

32 2 200.1 36.682 36.679 2 18.960 18.924 26.338 189.9 2 193.5 2 33.6 0.01 2 2.73 2 0.11 2 0.90 2 2.31 2 1.28 2 0.03 2 9 9 9 9 9 51.2 2 9

31 2 224.5 36.600 36.602 2 18.464 18.424 26.403 192.5 2 198.1 2 31.2 0.00 2 3.32 2 0.15 2 1.10 2 2.32 2 1.29 2 0.02 2 0.44 2 9 9 9 9 9 9

30 2 248.7 36.569 36.567 2 18.263 18.219 26.431 198.6 2 198.9 2 31.3 0.00 2 3.81 2 0.18 2 1.20 2 2.32 2 1.28 2 0.03 2 9 9 9 9 9 49.0 2 9

29 2 272.8 36.544 36.544 2 18.119 18.071 26.450 199.4 2 200.9 2 30.0 0.00 2 3.90 2 0.19 2 1.30 2 2.31 2 1.28 2 0.03 2 0.45 2 9 9 9 9 9 9

28 2 302.2 36.517 36.521 2 17.930 17.878 26.479 200.4 2 198.4 2 33.4 0.00 2 4.49 2 0.23 2 1.40 2 2.29 2 1.25 2 0.03 2 9 9 9 9 9 9 9

27 2 350.1 36.432 36.439 2 17.411 17.351 26.544 190.4 2 188.4 2 45.8 0.00 2 6.05 2 0.33 2 1.90 2 2.21 2 1.19 2 0.02 2 9 9 9 9 9 47.6 2 9

26 2 399.1 36.318 36.318 2 16.740 16.674 26.621 185.3 2 183.4 2 54.1 0.00 2 7.71 2 0.44 2 2.30 2 2.11 2 1.12 2 0.02 2 9 9 9 9 9 9 9

25 2 448.6 36.170 36.170 2 15.815 15.743 26.724 184.0 2 184.1 2 58.0 0.00 2 8.98 2 0.53 2 3.00 2 2.09 2 1.11 2 0.02 2 0.43 2 9 9 9 9 9 9

24 2 500.0 36.014 36.016 2 14.874 14.797 26.816 177.7 2 179.6 2 67.3 0.00 2 10.93 2 0.65 2 3.80 2 1.99 2 1.05 2 0.02 2 9 9 9 9 9 9 9

23 2 597.1 35.735 35.736 2 13.036 12.952 26.990 169.1 2 168.4 2 88.4 0.00 2 15.13 2 0.92 2 6.10 2 1.43 2 0.74 2 0.01 2 9 9 9 9 9 45.0 2 9

22 2 698.5 35.489 35.486 2 11.136 11.047 27.165 161.5 2 158.4 2 109.3 0.00 2 19.24 2 1.21 2 9.20 2 0.85 2 0.44 2 0.01 2 0.28 2 9 9 9 9 9 9

21 3 798.8 35.208 35.217 2 9.014 8.924 27.308 148.7 2 147.0 2 133.9 0.00 2 24.22 2 1.56 2 14.40 2 0.33 6 0.18 6 0.01 6 9 9 9 9 9 9 9

20 2 900.6 35.020 35.023 2 7.379 7.288 27.407 147.0 2 146.4 2 145.5 0.00 2 27.25 2 1.79 2 18.40 2 0.14 2 0.08 2 0.01 2 9 9 9 9 9 9 9

19 2 999.6 35.041 35.044 2 6.806 6.708 27.505 165.1 2 167.1 2 128.7 0.00 2 25.20 2 1.67 2 17.70 2 0.16 2 0.09 2 0.01 2 9 9 9 9 9 43.3 2 9

18 2 1101.7 35.054 35.052 2 6.055 5.953 27.615 186.5 2 193.4 2 107.7 0.00 2 22.86 2 1.53 2 16.50 2 0.23 2 0.13 2 0.00 2 9 9 9 9 9 9 9

17 2 1199.7 35.088 35.087 2 5.734 5.625 27.683 211.1 2 209.5 2 93.8 0.00 2 21.29 2 1.43 2 15.60 2 0.21 2 0.11 2 0.00 2 0.45 6 9 9 9 9 9 9

16 2 1397.6 35.071 35.070 2 4.943 4.822 27.766 239.9 2 238.4 2 70.8 0.00 2 19.15 2 1.28 2 14.20 2 0.29 2 0.15 2 0.01 2 9 9 9 9 9 9 9

15 2 1604.5 35.060 35.060 2 4.467 4.331 27.813 251.3 2 248.9 2 64.1 0.00 2 18.56 2 1.25 2 15.00 2 0.18 2 0.10 2 0.01 2 9 9 9 9 9 41.4 2 9

14 2 1795.6 35.035 35.034 2 4.058 3.909 27.839 255.5 2 254.1 2 62.2 0.00 2 18.46 2 1.25 2 16.90 2 0.07 2 0.04 2 0.01 2 0.34 6 9 9 9 9 9 9

13 2 1996.3 35.019 35.019 2 3.779 3.615 27.857 254.2 2 253.1 2 65.5 0.01 2 18.95 2 1.29 2 20.30 2 0.02 2 0.01 2 0.01 2 9 9 9 9 9 9 9

12 2 2200.0 34.996 34.996 2 3.463 3.284 27.872 254.8 2 253.8 2 67.5 0.01 2 19.24 2 1.32 2 23.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2395.5 34.975 34.975 2 3.212 3.018 27.881 254.9 2 254.7 2 68.7 0.01 2 19.44 2 1.34 2 26.80 2 0.01 2 0.01 2 -0.01 2 0.23 2 9 9 9 9 41.1 2 9

10 2 2597.2 34.957 34.957 2 3.013 2.803 27.887 256.6 2 256.7 2 68.5 0.01 2 19.54 2 1.35 2 28.60 2 9 9 9 9 9 9 9 9 9 9

9 2 2800.7 34.946 34.945 2 2.875 2.647 27.893 257.0 2 257.6 2 68.9 0.01 2 19.64 2 1.36 2 30.50 2 0.01 2 0.00 2 0.00 2 0.17 2 9 9 9 9 9 9

8 2 3000.2 34.935 34.935 2 2.766 2.520 27.897 259.9 2 259.8 2 67.8 0.01 2 19.44 2 1.35 2 30.90 2 0.01 2 0.01 2 0.00 2 0.17 2 9 9 9 9 9 9

7 2 3398.9 34.915 34.915 2 2.531 2.249 27.906 262.6 2 262.4 2 67.5 0.01 2 19.54 2 1.36 2 33.60 2 0.02 2 0.01 2 0.01 2 0.19 2 9 9 9 9 41.3 2 9

6 2 3783.2 34.902 34.901 2 2.378 2.058 27.913 263.5 2 263.9 2 67.6 0.01 2 19.54 2 1.37 2 35.70 2 0.03 2 0.02 2 0.00 2 0.23 2 9 9 9 9 9 9

5 2 4198.2 34.897 34.896 2 2.302 1.936 27.922 270.3 2 269.0 2 63.6 0.01 2 18.76 2 1.32 2 33.10 2 0.09 2 0.06 2 0.01 2 0.42 2 9 9 9 9 9 9

4 2 4598.2 34.889 34.887 2 2.261 1.849 27.925 269.2 2 266.6 2 66.7 0.01 2 19.34 2 1.36 2 36.70 2 0.08 2 0.05 2 0.00 2 0.41 6 9 9 9 9 9 9

3 2 4999.1 34.868 34.865 2 2.136 1.679 27.923 260.5 2 259.6 2 75.2 0.01 2 21.01 2 1.48 2 47.10 2 0.04 2 0.03 2 0.00 2 0.25 2 9 9 9 9 41.1 2 9

2 9 5499.1 34.843 2 2.008 1.492 27.920 252.0 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

1 2 6127.9 34.842 34.842 2 2.085 1.481 27.925 253.0 2 252.8 6 83.8 0.01 6 22.67 6 1.60 6 58.30 6 0.03 2 0.03 2 0.00 2 0.20 6 9 9 9 2353 2 41.2 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

141
A5R

NOAA Ship Ronald H. Brown

STATION 73 DATE 2/11/1998 LATITUDE 24.500° N

LONGITUDE 57.400° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 36.914 36.913 2 23.608 23.607 25.209 217.5 2 213.9 2 -5.3 0.00 2 0.00 2 0.01 2 0.40 2 9 9 9 9 275.8 318.1 2 2044.4 6 8.1046 2 5 2414 9 9

35 2 49.1 36.912 36.916 2 23.623 23.613 25.210 215.4 2 214.2 6 -5.6 0.00 2 0.00 2 0.01 2 0.30 2 9 9 9 9 9 9 9 9 9 9

34 2 99.9 37.012 37.040 2 22.966 22.945 25.484 215.8 2 212.4 2 -1.6 0.01 2 0.10 2 0.01 2 0.20 2 9 9 9 9 303.8 341.7 2 2070.7 2 8.0688 2 2424 2 2417 9 9

33 2 149.7 36.845 36.848 2 20.359 20.331 26.090 199.4 2 201.6 2 19.4 0.02 2 0.68 2 0.03 2 0.20 2 9 9 9 9 350.1 355.1 2 2093.2 2 8.0193 2 2418 2 2406 9 9

32 2 199.9 36.684 36.685 2 19.070 19.034 26.311 193.1 2 198.2 2 28.4 0.01 2 1.85 2 0.07 2 0.40 2 9 9 9 9 377.1 363.2 2 2100.3 2 7.9946 2 2404 2 2396 9 9

31 2 226.0 36.611 36.612 2 18.602 18.562 26.377 201.2 2 202.9 2 25.8 0.01 2 2.44 2 0.09 2 0.50 2 9 9 9 9 9 9 9 9 9 9

30 2 241.6 36.577 36.583 2 18.380 18.337 26.408 203.2 2 204.4 2 25.3 0.01 2 3.02 2 0.13 2 0.60 2 9 9 9 9 377.3 353.2 2 2097.6 2 7.9921 2 2404 2 2391 9 9

29 2 274.5 36.532 36.533 2 18.070 18.022 26.453 206.2 2 206.8 2 24.3 0.00 2 3.61 2 0.17 2 0.70 2 9 9 9 9 9 9 9 9 9 9

28 2 300.6 36.504 36.502 2 17.882 17.830 26.480 208.6 2 204.7 2 27.3 0.01 2 4.20 2 0.21 2 0.90 2 9 9 9 9 398.6 365.9 2 2099.1 2 7.9814 2 2389 2 2385 9 9

27 2 352.2 36.442 36.446 2 17.479 17.419 26.536 204.5 2 197.5 2 36.4 0.00 2 5.37 2 0.28 2 1.30 2 9 9 9 9 9 9 9 9 9 9

26 2 401.1 36.334 36.329 2 16.837 16.770 26.611 189.6 2 185.4 2 51.6 0.00 2 7.51 2 0.41 2 1.90 2 9 9 9 9 448.0 394.0 2 2118.0 2 7.9295 2 5 2372 9 9

25 2 449.6 36.187 36.183 2 15.949 15.877 26.706 185.1 2 182.9 2 58.5 0.00 2 9.08 2 0.51 2 2.60 2 9 9 9 9 9 9 9 9 9 9

24 2 500.4 36.002 35.998 2 14.803 14.727 26.822 180.6 2 177.1 2 70.2 0.00 2 11.42 2 0.66 2 3.70 2 9 9 9 9 9 9 9 9 9 9

23 2 549.5 35.881 35.887 2 14.047 13.966 26.893 173.8 2 172.2 2 79.0 0.00 2 13.08 2 0.77 2 4.60 2 9 9 9 9 551.9 432.6 2 2140.6 2 7.8454 2 5 2347 9 9

22 2 649.7 35.609 35.600 2 12.101 12.014 27.077 165.1 2 162.7 2 99.4 0.00 2 17.28 2 1.06 2 7.30 2 9 9 9 9 9 9 9 9 9 9

21 2 748.6 35.316 35.325 2 10.024 9.934 27.226 150.7 2 147.6 2 126.9 0.00 2 22.56 2 1.42 2 11.70 2 9 9 9 9 9 9 9 9 9 9

20 2 800.7 35.212 35.215 2 9.098 9.007 27.298 148.6 2 146.0 2 134.4 0.00 2 24.22 2 1.56 2 14.00 2 9 9 9 9 823.1 524.6 2 2186.0 2 7.6841 2 2327 2 2317 9 9

19 2 849.8 35.172 35.170 2 8.660 8.566 27.337 147.1 2 147.3 2 136.0 0.00 2 25.00 2 1.61 2 15.00 2 9 9 9 9 9 9 9 9 9 9

18 2 898.9 35.149 35.150 2 8.212 8.115 27.388 150.5 2 148.5 2 137.7 0.00 2 25.40 2 1.65 2 15.80 2 9 9 9 9 9 9 9 9 9 9

17 2 1000.2 35.025 35.023 2 6.721 6.624 27.503 163.1 2 161.4 2 135.0 0.00 2 25.98 2 1.74 2 18.50 2 9 9 9 9 896.3 514.9 2 2195.1 6 7.6506 2 5 2313 9 9

16 2 1099.6 35.040 35.032 2 6.133 6.030 27.593 186.8 2 184.7 2 115.9 0.00 2 23.84 2 1.60 2 17.40 2 9 9 9 9 9 9 9 9 9 9

15 2 1301.7 35.063 35.063 2 5.250 5.135 27.723 230.0 2 227.9 2 79.0 0.00 2 19.83 2 1.33 2 14.10 2 9 9 9 9 9 9 9 9 9 9

14 2 1500.2 35.048 35.049 2 4.664 4.536 27.781 248.8 2 247.7 2 63.7 0.00 2 18.56 2 1.24 2 13.40 2 9 9 9 9 9 9 9 9 9 9

13 2 1694.5 35.049 35.049 2 4.309 4.167 27.823 252.2 2 251.9 2 62.3 0.00 2 18.46 2 1.24 2 15.20 2 9 9 9 9 9 9 9 9 9 9

12 2 1900.3 35.026 35.026 2 3.908 3.751 27.848 255.9 2 255.4 2 62.1 0.00 2 18.56 2 1.26 2 17.80 2 9 9 9 9 721.2 360.2 6 2162.7 2 7.7380 2 5 2315 9 9

11 2 2174.5 34.993 34.993 2 3.468 3.292 27.869 257.2 2 257.5 2 63.7 0.00 2 18.85 2 1.28 2 21.60 2 9 9 9 9 9 9 9 9 9 9

10 2 2500.8 34.965 34.965 2 3.123 2.921 27.883 257.7 2 257.0 2 67.3 0.00 2 19.24 2 1.32 2 26.20 2 9 9 9 9 9 9 9 9 9 9

9 2 2798.9 34.950 34.949 2 2.927 2.698 27.892 256.8 2 257.4 2 68.7 0.00 2 19.73 2 1.36 2 29.60 2 9 9 9 9 9 2173.8 2 7.7342 2 5 2325 9 9

8 2 3182.2 34.928 34.928 2 2.693 2.430 27.900 262.8 2 261.6 2 66.8 0.00 2 19.34 2 1.33 2 29.90 2 9 9 9 9 9 9 9 9 9 9

7 2 3598.6 34.911 34.911 2 2.483 2.180 27.910 262.3 2 265.1 2 65.4 0.00 2 19.25 2 1.34 2 31.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3991.4 34.898 34.898 2 2.341 1.998 27.916 266.5 2 265.2 2 66.8 0.00 2 19.44 2 1.35 2 34.90 2 9 9 9 9 728.4 335.8 2 2175.7 2 7.7329 2 2337 2 2326 9 9

5 2 4399.2 34.889 34.889 2 2.272 1.884 27.921 267.8 2 266.0 2 67.0 0.00 2 19.44 2 1.36 2 36.20 2 9 9 9 9 9 9 9 9 9 9

4 2 4898.0 34.870 34.869 2 2.149 1.704 27.922 261.4 2 260.0 2 74.6 0.00 2 20.81 2 1.44 2 45.20 2 9 9 9 9 9 2187.6 2 7.7220 2 2343 2 2334 9 9

3 2 5277.9 34.849 34.848 2 2.018 1.530 27.920 255.6 2 255.0 2 81.2 0.00 2 22.08 2 1.56 2 54.60 2 9 9 9 9 9 9 9 9 9 9

2 2 5799.6 34.842 34.842 2 2.043 1.486 27.922 253.1 2 252.9 2 83.7 0.00 2 22.67 2 1.59 2 57.30 2 9 9 9 9 9 9 9 9 9 9

1 2 6392.4 34.842 34.842 2 2.122 1.480 27.927 253.9 2 253.3 2 83.3 0.00 6 22.67 6 1.60 6 57.90 6 9 9 9 9 796.0 362.4 2 2202.2 2 7.6967 2 9 2339 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

142
A5R

NOAA Ship Ronald H. Brown

STATION 74 DATE 2/11/1998 LATITUDE 24.500° N

LONGITUDE 58.134° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.9 36.812 36.812 2 24.612 24.611 24.833 211.3 2 212.4 2 -7.2 0.00 2 0.00 2 0.01 2 0.80 2 1.85 2 1.07 2 0.16 2 9 265.5 318.4 2 2033.7 6 8.1146 2 2405 2 2408 73.5 2 4.2 2

35 2 40.9 36.834 36.834 2 24.474 24.465 24.895 210.8 2 212.4 2 -6.7 0.00 2 0.00 2 0.01 2 0.80 2 1.84 2 1.06 2 0.15 2 9 267.4 319.0 2 2034.6 2 8.1094 2 2402 2 2405 73.2 2 4.3 2

34 2 90.8 36.941 36.953 2 24.181 24.162 25.071 215.1 2 216.0 2 0.4 0.00 2 0.00 2 0.01 2 0.60 2 1.94 2 1.11 2 0.18 2 9 277.5 327.3 2 2049.2 2 8.1012 2 2413 2 2417 70.8 2 4.2 2

33 2 139.8 37.074 37.065 2 21.834 21.806 25.859 197.5 2 200.9 2 14.1 0.03 2 0.49 2 0.02 2 0.50 2 2.14 2 1.22 2 0.13 2 9 304.3 327.4 3 2096.2 2 8.0369 2 2418 2 2423 55.9 2 4.2 2

32 2 190.4 36.740 36.740 2 19.496 19.461 26.242 197.7 2 201.0 2 23.7 0.01 2 1.27 2 0.04 2 0.70 2 2.29 6 1.28 6 0.08 6 9 369.3 361.8 2 2098.0 2 8.0047 2 2399 2 2400 53.1 2 4.6 2

31 2 211.5 36.671 36.671 2 19.012 18.974 26.316 197.4 2 201.0 2 25.9 0.01 2 1.95 2 0.07 2 0.80 2 2.32 2 1.30 2 0.05 2 9 353.2 339.4 3 2099.3 2 7.9987 2 2393 2 2397 51.1 2 5.3 2

30 2 240.4 36.602 36.604 2 18.556 18.513 26.383 200.1 2 203.9 2 25.0 0.00 2 2.83 2 0.12 2 1.00 2 2.35 2 1.31 2 0.06 2 9 353.4 333.3 3 2096.7 2 7.9953 2 2389 2 2392 49.9 2 6.8 2

29 2 265.1 36.563 36.565 2 18.300 18.253 26.419 203.6 2 206.6 2 23.5 0.00 2 3.32 2 0.15 2 1.10 2 2.37 2 1.32 2 0.04 2 9 9 2096.0 2 7.9930 2 2386 2 2389 48.0 2 9

28 2 288.5 36.542 36.542 2 18.146 18.096 26.444 204.5 2 206.7 2 24.1 0.00 2 3.71 2 0.17 2 1.20 2 2.34 2 1.30 2 0.03 2 9 384.3 356.6 2 2093.2 2 7.9918 2 2385 2 2385 9 9

27 2 355.6 36.477 36.476 2 17.720 17.659 26.505 201.1 2 201.3 2 31.5 0.00 2 4.88 2 0.25 2 1.60 2 2.28 2 1.24 2 0.03 2 9 9 2103.3 2 7.9709 2 2381 2 2383 47.4 2 7.9 2

26 2 416.1 36.316 36.317 2 16.717 16.648 26.626 192.4 2 191.4 2 46.2 0.00 2 7.32 2 0.40 2 2.30 2 2.19 2 1.17 2 0.03 2 9 438.5 384.0 2 2118.2 2 7.9330 2 2374 2 2375 9 9

25 2 475.7 36.130 36.134 2 15.582 15.507 26.748 187.4 2 184.7 2 58.5 0.00 2 9.66 2 0.55 2 3.20 2 2.09 2 1.11 2 0.03 2 9 9 2128.1 2 7.8946 2 2363 2 2362 45.4 2 9

24 2 551.0 35.935 35.952 2 14.309 14.227 26.880 178.2 2 177.6 2 72.2 0.00 2 12.10 2 0.71 2 4.30 2 1.89 2 0.99 2 0.02 2 9 534.2 423.3 2 2137.4 2 7.8592 2 2353 2 2352 9 9

23 2 640.0 35.710 35.711 2 12.841 12.752 27.011 170.6 2 169.1 2 88.8 0.00 2 15.62 2 0.93 2 6.30 2 1.39 2 0.72 2 0.02 2 9 603.4 449.8 2 2152.0 2 7.8078 2 5 2339 43.6 2 9

22 2 750.5 35.383 35.387 2 10.547 10.454 27.189 150.2 2 149.5 2 121.8 0.00 2 21.68 2 1.36 2 11.20 2 0.62 2 0.33 2 0.01 2 9 744.8 504.6 2 2175.8 2 7.7247 2 5 2325 9 9

21 2 799.6 35.318 35.319 2 9.922 9.826 27.247 153.4 2 151.2 2 124.0 0.00 2 22.56 2 1.43 2 12.50 2 9 9 9 9 765.0 504.5 2 2180.4 2 7.7125 2 2329 2 2324 42.5 2 24.5 2

20 2 850.2 35.271 35.262 2 9.326 9.228 27.310 152.5 2 154.2 2 124.8 0.00 2 23.15 2 1.48 2 13.80 2 0.39 2 0.21 2 0.01 2 9 792.9 509.8 2 2182.5 2 7.7006 2 2325 2 2321 9 9

19 2 924.6 35.130 35.126 2 7.958 7.860 27.412 155.2 2 155.9 2 132.0 0.00 2 25.00 2 1.63 2 16.60 2 0.22 2 0.12 2 0.01 2 9 846.6 513.1 2 2189.7 2 7.6708 2 2323 2 2315 41.7 2 9

18 2 1001.0 35.065 35.066 2 6.961 6.862 27.503 166.0 2 167.3 2 127.4 0.00 2 25.10 2 1.66 2 17.80 2 0.17 2 0.09 2 0.01 2 9 865.8 502.1 2 2188.8 6 7.6667 2 5 2313 9 9

17 2 1199.5 35.076 35.076 2 5.801 5.691 27.666 208.1 2 206.7 6 96.2 0.00 2 21.68 2 1.45 2 16.10 2 0.21 2 0.11 2 0.01 2 9 793.5 434.9 2 2178.4 2 7.6997 2 9 2315 41.5 2 23.6 2

16 2 1399.1 35.066 35.066 2 4.963 4.842 27.760 241.0 2 240.3 2 68.8 0.00 2 19.05 2 1.27 2 14.00 2 0.36 6 0.18 6 0.01 6 9 739.6 388.9 2 2167.6 2 7.7263 2 9 2315 9 9

15 2 1599.2 35.054 35.055 2 4.489 4.354 27.806 251.6 2 251.4 2 61.4 0.00 2 18.56 2 1.24 2 14.70 2 0.22 2 0.12 2 0.01 2 9 717.0 368.2 2 2165.2 2 7.7338 2 9 2316 41.9 2 9

14 2 1802.7 35.047 35.047 2 4.167 4.016 27.837 253.4 2 253.4 2 62.0 0.00 2 18.66 2 1.25 2 17.20 2 0.10 2 0.06 2 0.01 2 9 720.7 364.4 2 2164.7 2 7.7382 2 9 2317 9 9

13 2 1998.3 35.019 35.019 2 3.745 3.581 27.860 254.3 2 255.4 2 63.5 0.00 2 18.95 2 1.28 2 20.80 2 0.02 2 0.02 2 0.01 2 9 716.5 354.6 2 2169.8 2 7.7375 2 9 2322 45.1 3 9

12 2 2248.0 34.990 34.991 2 3.411 3.228 27.873 256.1 2 257.1 2 64.6 0.00 2 19.24 2 1.30 2 23.70 2 0.01 2 0.01 2 0.00 2 9 721.8 351.4 2 2170.1 2 7.7382 2 9 2323 9 9

11 2 2500.2 34.966 34.966 2 3.128 2.926 27.883 257.0 2 257.9 2 66.3 0.00 2 19.54 2 1.33 2 27.00 2 0.01 2 0.01 2 0.00 2 9 718.9 344.9 2 2174.3 2 7.7377 2 2332 2 2327 41.0 2 21.4 2

10 2 2761.2 34.949 34.950 2 2.932 2.707 27.890 257.2 2 258.2 2 67.8 0.00 2 19.73 2 1.35 2 29.70 2 0.00 2 0.00 2 0.00 2 9 726.4 345.1 2 2176.0 2 7.7364 2 9 2328 9 9

9 2 3000.3 34.938 34.937 2 2.800 2.553 27.897 259.2 2 259.7 2 67.6 0.00 2 19.73 2 1.36 2 31.60 2 0.01 2 0.00 2 0.01 2 9 714.2 336.7 2 2176.8 2 7.7345 2 9 2328 41.2 2 9

8 2 3300.1 34.922 34.922 2 2.614 2.340 27.904 260.2 2 261.5 2 67.6 0.00 2 19.93 2 1.37 2 34.30 2 0.01 2 0.00 2 0.00 2 0.13 2 725.5 339.0 2 2179.1 2 7.7363 2 9 2331 9 9

7 2 3599.6 34.910 34.911 2 2.485 2.182 27.909 261.3 2 263.6 2 66.9 0.00 2 19.73 2 1.36 2 34.80 2 0.03 2 0.01 2 0.00 2 9 728.4 338.3 2 2176.2 2 7.7336 2 5 2327 41.1 2 9

6 2 3900.0 34.899 34.899 2 2.365 2.032 27.914 264.0 2 264.3 2 67.5 0.00 2 19.83 2 1.37 2 37.00 2 0.02 2 0.02 2 0.00 2 0.20 2 730.5 337.1 6 2177.2 2 7.7334 2 9 2328 9 9

5 2 4201.7 34.891 34.892 2 2.294 1.928 27.918 264.1 2 265.1 2 67.6 0.00 2 19.83 2 1.37 2 37.90 2 0.03 6 0.02 6 0.01 6 0.24 2 9 2179.5 2 7.7313 2 5 2330 42.9 2 9

4 2 4500.0 34.887 34.887 2 2.248 1.848 27.922 266.5 2 266.1 2 67.3 0.00 2 19.73 2 1.37 2 38.50 2 0.06 2 0.04 2 0.00 2 0.33 6 9 2180.2 2 7.7306 2 9 2330 9 9

3 2 4898.5 34.868 34.868 2 2.130 1.686 27.922 260.8 2 261.1 2 73.7 0.00 2 21.00 2 1.46 2 46.70 2 0.04 2 0.02 2 0.01 2 0.25 2 764.6 348.6 2 2188.0 2 7.7212 2 5 2334 41.3 2 9

2 2 5401.7 34.845 34.845 2 2.006 1.502 27.920 252.9 2 254.3 2 82.1 0.00 2 22.57 2 1.58 2 57.00 2 0.02 2 0.02 2 0.01 2 0.19 2 790.7 357.9 2 2202.1 2 7.7070 2 9 2343 9 9

1 2 5931.6 34.841 34.842 2 2.056 1.480 27.922 252.1 2 253.6 2 83.0 0.00 6 22.76 6 1.60 6 58.10 6 0.03 2 0.02 2 0.00 2 0.21 2 794.3 360.4 2 2204.2 2 7.7043 2 5 2344 41.0 2 24.6 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

143
A5R

NOAA Ship Ronald H. Brown

STATION 75 DATE 2/12/1998 LATITUDE 24.500° N

LONGITUDE 58.867° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.3 36.855 36.855 2 23.745 23.744 25.125 213.7 2 215.8 2 -7.6 0.00 2 0.39 2 0.01 2 0.70 2 9 9 9 9 276.1 320.3 6 2041.7 6 8.1043 2 2407 2 2410 9 9

35 2 48.0 36.853 36.854 2 23.758 23.748 25.125 214.2 2 213.7 6 -5.5 0.00 2 0.39 2 0.02 2 0.70 2 9 9 9 9 9 9 9 9 9 9

34 3 103.1 36.993 36.999 2 22.638 22.617 25.565 215.5 2 219.1 2 -7.0 0.00 2 0.39 2 0.02 2 0.50 2 9 9 9 9 307.6 341.5 2 2070.0 2 8.0692 2 2412 2 2417 9 9

33 2 150.0 36.854 36.855 2 20.377 20.349 26.092 195.6 2 198.7 2 22.3 0.02 2 1.07 2 0.03 2 0.50 2 9 9 9 9 360.4 365.7 2 2098.4 2 8.0130 2 2406 2 2407 9 9

32 2 198.3 36.716 36.716 2 19.209 19.173 26.299 191.8 2 194.1 2 31.9 0.01 2 2.44 2 0.07 2 0.90 2 9 9 9 9 9 9 9 9 9 9

31 2 226.3 36.647 36.643 2 18.780 18.740 26.359 195.0 2 196.6 2 31.3 0.01 2 3.22 2 0.10 2 1.00 2 9 9 9 9 388.6 370.0 2 2103.9 2 7.9867 2 2391 2 2394 9 9

30 2 250.7 36.595 36.597 2 18.469 18.425 26.400 198.2 2 199.5 2 29.8 0.00 2 3.61 2 0.13 2 1.10 2 9 9 9 9 9 9 9 9 9 9

29 2 274.5 36.556 36.556 2 18.219 18.171 26.435 200.5 2 201.2 2 29.3 0.00 2 4.20 2 0.16 2 1.30 2 9 9 9 9 388.2 361.2 2 2101.6 2 7.9823 2 2390 2 2388 9 9

28 2 300.1 36.527 36.524 2 18.032 17.980 26.462 202.1 2 201.9 2 29.4 0.00 2 4.59 2 0.19 2 1.30 2 9 9 9 9 9 9 9 9 9 9

27 2 347.3 36.457 36.466 2 17.608 17.548 26.516 198.5 2 195.8 2 37.5 0.00 2 5.76 2 0.25 2 1.60 2 9 9 9 9 415.1 376.7 2 2109.8 2 7.9623 2 2381 2 2384 9 9

26 2 395.9 36.338 36.339 2 16.885 16.819 26.602 192.7 2 190.7 2 46.1 0.00 2 7.42 2 0.35 2 2.00 2 9 9 9 9 9 9 9 9 9 9

25 2 448.7 36.185 36.203 2 15.949 15.877 26.705 188.7 2 187.0 2 54.4 0.00 2 9.08 2 0.46 2 2.70 2 9 9 9 9 467.3 395.5 2 2125.4 2 7.9113 2 2367 2 2369 9 9

24 2 499.4 36.053 36.050 2 15.129 15.052 26.791 183.1 2 181.8 2 63.8 0.00 2 10.93 2 0.59 2 3.50 2 9 9 9 9 9 9 9 9 9 9

23 3 599.4 35.749 35.751 2 13.107 13.022 26.986 171.8 2 170.8 2 85.6 0.00 2 15.23 2 0.86 2 5.80 2 9 9 9 9 9 9 9 9 9 9

22 2 697.5 35.476 35.479 2 11.165 11.076 27.149 161.1 2 158.9 2 108.7 0.00 2 19.92 2 1.18 2 9.30 2 9 9 9 9 684.0 474.6 2 2168.3 2 7.7532 2 2332 2 2330 9 9

21 2 794.1 35.328 35.336 2 9.823 9.729 27.271 155.6 2 155.9 2 119.9 0.00 2 22.46 2 1.36 2 11.80 2 9 9 9 9 9 2178.8 2 9 9 9 9

20 2 847.3 35.205 35.204 2 8.722 8.628 27.353 153.6 2 152.2 2 130.6 0.00 2 24.81 2 1.54 2 14.60 2 9 9 9 9 815.0 510.0 2 2187.7 2 9 2317 2 9 9

19 2 901.0 35.111 35.115 2 7.771 7.677 27.423 155.7 2 155.9 2 133.2 0.00 2 25.78 2 1.63 2 16.50 2 9 9 9 9 9 9 9 9 9 9

18 2 1049.2 35.055 35.058 2 6.503 6.402 27.557 178.0 2 178.2 2 119.7 0.00 2 24.81 2 1.58 2 17.40 2 9 9 9 9 855.4 485.0 2 2189.7 6 7.6720 2 2321 2 2316 9 9

17 2 1249.1 35.073 35.072 2 5.448 5.336 27.707 221.9 2 221.1 2 84.4 0.00 2 20.80 2 1.34 2 14.70 2 9 9 9 9 9 9 9 9 9 9

16 2 1449.5 35.078 35.077 2 4.925 4.799 27.775 243.1 2 241.0 2 68.4 0.00 2 18.85 2 1.24 2 14.00 2 9 9 9 9 730.0 381.9 2 2167.0 2 7.7263 2 2319 2 2315 9 9

15 2 1652.9 35.054 35.054 2 4.402 4.262 27.816 252.2 2 252.3 2 61.2 0.00 2 18.17 2 1.21 2 14.80 2 9 9 9 9 9 9 9 9 9 9

14 2 1848.6 35.039 35.039 2 4.056 3.902 27.843 253.1 2 254.3 2 62.0 0.00 2 18.17 2 1.23 2 17.30 2 9 9 9 9 9 9 9 9 9 9

13 2 1999.5 35.021 35.020 2 3.768 3.604 27.860 254.2 2 255.3 2 63.4 0.00 2 18.17 2 1.26 2 20.00 2 9 9 9 9 720.8 356.1 2 2167.5 2 7.7346 2 2323 2 2319 9 9

12 2 2187.6 34.998 34.999 2 3.491 3.313 27.871 254.0 2 254.9 2 66.1 0.00 2 18.26 2 1.28 2 23.40 2 9 9 9 9 9 9 9 9 9 9

11 2 2390.7 34.978 34.978 2 3.246 3.052 27.880 254.8 2 256.1 2 67.1 0.00 2 18.56 2 1.30 2 26.20 2 9 9 9 9 9 9 9 9 9 9

10 2 2601.1 34.961 34.961 2 3.049 2.838 27.887 255.5 2 258.1 2 66.8 0.00 2 18.75 2 1.32 2 28.90 2 9 9 9 9 9 9 9 9 9 9

9 2 2948.4 34.939 34.940 2 2.816 2.575 27.895 256.4 2 257.9 2 69.2 0.00 2 18.85 2 1.34 2 32.00 2 9 9 9 9 730.6 344.2 2 2178.8 2 7.7344 2 2333 2 2330 9 9

8 2 3249.2 34.925 34.924 2 2.639 2.370 27.903 261.4 2 261.8 2 67.1 0.00 2 18.56 2 1.32 2 32.20 2 9 9 9 9 9 9 9 9 9 9

7 2 3650.4 34.907 34.906 2 2.438 2.131 27.910 262.0 2 261.9 2 69.0 0.00 2 18.85 2 1.36 2 36.30 2 9 9 9 9 9 9 9 9 9 9

6 2 4051.0 34.899 34.899 2 2.329 1.980 27.918 267.6 2 268.2 2 64.0 0.00 2 18.36 2 1.30 2 33.20 2 9 9 9 9 9 2174.8 2 7.7352 2 2330 2 2326 9 9

5 2 4400.9 34.891 34.891 2 2.281 1.892 27.922 267.7 2 267.6 2 65.4 0.00 2 18.75 2 1.34 2 35.80 2 9 9 9 9 727.6 333.2 2 2176.7 2 9 9 9 9

4 2 4750.2 34.882 34.882 2 2.232 1.803 27.924 265.4 2 264.8 2 68.9 0.00 2 19.44 2 1.39 2 40.30 2 9 9 9 9 9 2182.4 2 7.7272 2 2335 2 2331 9 9

3 2 5001.3 34.865 34.866 2 2.131 1.674 27.922 260.4 2 260.5 2 74.4 0.00 2 20.71 2 1.46 2 47.20 2 9 9 9 9 9 9 9 9 9 9

2 2 5499.6 34.845 34.846 2 2.024 1.507 27.920 253.9 2 254.5 2 81.9 0.00 2 22.08 2 1.57 2 56.60 2 9 9 9 9 9 9 9 9 9 9

1 2 6014.3 34.841 34.843 2 2.069 1.482 27.924 252.2 2 253.6 2 83.0 0.00 6 22.27 6 1.58 6 57.80 6 9 9 9 9 795.2 361.0 2 2203.1 2 7.7027 2 2348 2 2342 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

144
A5R

NOAA Ship Ronald H. Brown

STATION 76 DATE 2/12/1998 LATITUDE 24.500° N

LONGITUDE 59.600° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.5 36.830 36.833 2 24.202 24.201 24.969 212.8 2 212.5 2 -5.9 0.00 2 0.00 2 0.02 2 1.30 3 1.87 2 1.09 2 0.15 2 1.97 2 272.1 321.3 6 2038.2 6 8.1115 2 2406 2 2411 73.3 2 9

35 3 60.3 36.854 36.861 2 24.018 24.005 25.049 212.3 2 214.8 6 -7.5 0.00 2 0.00 2 0.02 2 1.20 3 1.90 2 1.10 2 0.15 2 9 9 9 9 9 72.8 2 9

34 2 120.5 37.167 37.169 2 22.311 22.287 25.792 203.1 2 209.4 2 3.7 0.07 2 0.10 2 0.03 2 1.00 3 2.11 6 1.19 6 0.41 4 1.03 2 9 9 9 9 61.3 2 9

33 3 178.9 36.785 36.787 2 19.739 19.706 26.212 194.2 2 198.4 2 25.3 0.01 2 1.27 2 0.05 2 1.10 3 1 1 1 0.69 2 9 9 9 9 51.4 2 9

32 2 199.5 36.673 36.673 2 19.093 19.057 26.296 198.1 2 200.6 2 25.9 0.01 2 1.85 2 0.07 2 1.30 3 2.30 2 1.29 2 0.06 2 9 9 9 9 9 50.1 2 9

31 2 224.3 36.633 36.637 2 18.785 18.745 26.347 200.7 2 198.7 2 29.2 0.00 2 2.63 2 0.10 2 1.50 3 2.32 2 1.30 2 0.04 2 9 9 9 9 9 9 9

30 2 251.2 36.575 36.575 2 18.390 18.346 26.404 196.8 2 203.5 2 26.2 0.00 2 3.32 2 0.14 2 1.70 3 2.33 2 1.29 2 0.03 2 0.47 2 9 9 9 9 50.6 2 9

29 2 275.6 36.551 36.553 2 18.217 18.169 26.432 202.5 2 203.6 2 26.9 0.00 2 3.71 2 0.16 2 1.80 3 2.33 2 1.28 2 0.02 2 9 9 9 9 9 9 9

28 2 302.2 36.534 36.530 2 18.088 18.035 26.453 204.0 2 204.4 2 26.7 0.00 2 4.00 2 0.18 2 2.00 3 2.32 2 1.28 2 0.04 2 0.47 2 9 9 9 9 9 9

27 2 351.1 36.486 36.486 2 17.771 17.710 26.498 202.9 2 200.4 2 32.2 0.00 2 4.88 2 0.23 2 2.30 3 2.25 2 1.23 2 0.02 2 9 9 9 9 9 50.0 2 9

26 2 397.6 36.391 36.382 2 17.224 17.157 26.562 193.6 2 192.6 2 42.6 0.00 2 6.54 2 0.33 2 2.80 3 2.15 2 1.16 2 0.03 2 9 9 9 9 9 9 9

25 2 436.5 36.287 36.277 2 16.627 16.555 26.627 189.8 2 188.3 2 49.8 0.00 2 7.90 2 0.42 2 3.30 3 1 1 0.03 2 0.44 6 9 9 9 9 47.7 2 9

24 2 499.6 36.083 36.086 2 15.387 15.309 26.757 184.3 2 182.8 2 61.5 0.00 2 10.15 2 0.56 2 4.30 3 1.99 2 1.05 2 0.02 2 9 9 9 9 9 9 9

23 2 598.8 35.743 35.753 2 13.202 13.117 26.963 171.8 2 170.1 2 85.8 0.00 2 14.84 2 0.88 2 6.90 3 1.48 2 0.77 2 0.03 2 9 9 9 9 9 43.5 2 9

22 2 700.0 35.487 35.491 2 11.140 11.051 27.163 163.2 2 161.3 2 106.4 0.00 2 19.04 2 1.17 2 10.10 3 0.88 2 0.46 2 0.01 2 0.28 2 9 9 9 9 9 9

21 2 790.6 35.301 35.304 2 9.607 9.514 27.285 154.6 2 153.9 2 123.2 0.00 2 22.46 2 1.43 2 13.50 3 0.47 2 0.25 2 0.00 2 9 9 9 9 9 41.4 2 9

20 2 849.1 35.170 35.177 2 8.604 8.511 27.344 152.4 2 149.5 2 134.1 0.00 2 24.61 2 1.60 2 16.10 3 9 9 9 9 9 9 9 9 9 9

19 2 902.0 35.029 35.026 2 7.465 7.373 27.403 145.7 2 149.1 2 142.2 0.00 2 26.76 2 1.78 2 19.40 3 0.17 2 0.10 2 0.00 2 9 9 9 9 9 41.8 2 9

18 2 1001.9 35.003 34.999 2 6.626 6.529 27.499 163.0 2 165.6 2 131.5 0.00 2 25.88 2 1.73 2 19.80 3 0.19 2 0.10 2 0.01 2 0.21 2 9 9 9 9 9 9

17 2 1089.2 35.051 35.051 2 6.358 6.255 27.573 182.1 2 182.3 2 116.6 0.00 2 24.12 2 1.60 2 16.60 2 0.16 2 0.09 2 0.00 2 9 9 9 9 9 41.1 2 9

16 2 1298.9 35.069 35.077 2 5.353 5.237 27.716 227.2 2 223.2 2 83.0 0.00 2 20.31 2 1.35 2 14.10 2 0.26 2 0.13 2 0.00 2 0.63 2 9 9 9 9 9 9

15 2 1500.8 35.063 35.062 2 4.758 4.629 27.782 246.8 2 245.5 2 65.2 0.00 2 18.75 2 1.24 2 13.20 2 0.28 2 0.15 2 0.01 2 9 9 9 9 9 9 9

14 2 1699.4 35.052 35.052 2 4.355 4.212 27.821 252.5 2 253.0 2 60.9 0.00 2 18.46 2 1.22 2 14.50 2 0.17 2 0.10 2 0.01 2 0.65 2 9 9 9 9 9 9

13 2 1897.9 35.033 35.033 2 3.969 3.812 27.848 253.4 2 255.0 2 62.0 0.00 2 18.75 2 1.24 2 17.30 2 0.03 2 0.03 2 0.00 2 9 9 9 9 9 9 9

12 2 2100.2 35.008 35.008 2 3.628 3.456 27.865 254.5 2 256.3 2 63.6 0.00 2 18.85 2 1.27 2 20.60 2 0.02 2 0.02 2 0.00 2 9 9 9 9 9 9 9

11 2 2299.2 34.987 34.987 2 3.364 3.177 27.876 256.0 2 256.9 2 65.2 0.00 2 19.34 2 1.30 2 23.50 2 9 9 9 0.27 2 9 9 9 9 9 9

10 2 2597.8 34.962 34.962 2 3.085 2.874 27.886 256.7 2 257.8 2 66.8 0.00 2 19.53 2 1.32 2 26.90 2 0.01 2 0.01 2 0.00 2 9 9 9 9 9 9 9

9 2 2898.8 34.946 34.945 2 2.890 2.652 27.894 257.2 2 258.9 2 67.6 0.00 2 19.73 2 1.34 2 29.60 2 9 9 9 9 9 9 9 9 9 9

8 2 3193.9 34.929 34.930 2 2.715 2.450 27.900 260.4 2 261.2 2 67.0 0.00 2 19.63 2 1.34 2 30.90 2 0.01 2 0.01 2 0.00 2 0.14 6 9 9 9 9 9 9

7 2 3598.0 34.910 34.910 2 2.485 2.182 27.909 262.3 2 263.3 2 67.2 0.00 2 19.63 2 1.34 2 34.10 2 0.02 2 0.02 2 0.01 2 0.16 2 9 9 9 9 9 9

6 2 3997.7 34.897 34.897 2 2.337 1.994 27.916 263.9 2 265.0 2 67.1 0.00 2 19.73 2 1.36 2 36.10 2 0.03 2 0.02 2 -0.01 2 0.22 2 9 9 9 9 9 9

5 2 4396.2 34.888 34.888 2 2.262 1.874 27.921 264.5 2 265.9 2 67.2 0.00 2 19.63 2 1.36 2 37.30 2 0.05 2 0.03 2 0.00 2 0.30 2 9 9 9 9 9 9

4 2 4597.3 34.883 34.883 2 2.228 1.817 27.922 264.7 2 264.5 2 69.1 0.00 2 20.02 2 1.38 2 39.40 2 0.05 2 0.03 2 0.00 2 0.29 6 9 9 9 9 9 9

3 2 5093.3 34.854 34.854 2 2.043 1.577 27.919 254.7 2 257.2 2 78.6 0.00 2 21.88 2 1.52 2 52.00 2 0.58 4 0.02 2 0.00 2 0.22 2 9 9 9 9 9 9

2 2 5595.7 34.842 34.843 2 2.018 1.489 27.920 251.4 2 253.7 2 82.8 0.00 2 22.66 2 1.58 2 57.00 2 0.03 2 0.03 2 0.01 6 0.18 2 9 9 9 9 9 9

1 2 5912.1 34.842 34.843 2 2.057 1.484 27.923 253.6 2 253.9 2 82.7 0.00 6 22.76 6 1.59 6 57.40 6 0.03 2 0.02 2 0.00 2 0.20 2 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

145
A5R

NOAA Ship Ronald H. Brown

STATION 77 DATE 2/12/1998 LATITUDE 24.500° N

LONGITUDE 60.332° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.0 36.806 36.806 2 23.890 23.889 25.044 217.7 2 213.6 2 -5.9 0.00 2 0.00 2 0.02 2 0.90 2 9 9 9 9 270.9 316.0 2 2037.6 6 8.1100 2 2420 2 2409 9 9

35 2 50.6 36.793 36.793 2 23.779 23.768 25.073 213.2 2 214.3 2 -6.1 0.00 2 0.00 2 0.02 2 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 99.9 36.781 36.781 2 23.188 23.167 25.244 216.2 2 216.8 2 -6.4 0.00 2 0.00 2 0.03 2 0.70 2 9 9 9 9 284.2 322.5 2 2043.6 2 8.0945 2 2408 2 2404 9 9

33 2 150.8 36.947 36.954 2 21.818 21.788 25.768 206.9 2 208.7 2 6.5 0.05 2 0.20 2 0.03 2 0.50 2 9 9 9 9 9 9 9 9 9 9

32 2 200.2 36.802 36.795 2 19.773 19.736 26.218 187.4 2 191.7 2 31.8 0.01 2 1.76 2 0.07 2 0.80 2 9 9 9 9 378.6 375.3 2 2107.1 2 7.9936 2 2406 2 2404 9 9

31 2 224.5 36.700 36.695 2 19.090 19.049 26.320 193.0 2 193.4 2 33.1 0.00 2 2.73 2 0.10 2 0.90 2 9 9 9 9 9 9 9 9 9 9

30 2 250.1 36.642 36.638 2 18.682 18.637 26.383 194.5 2 194.3 2 34.0 0.00 2 3.51 2 0.15 2 1.10 2 9 9 9 9 9 9 9 9 9 9

29 2 276.0 36.586 36.584 2 18.361 18.312 26.422 198.2 2 198.4 2 31.4 0.00 2 3.81 2 0.17 2 1.10 2 9 9 9 9 386.8 362.0 2 2103.3 2 7.9807 2 2392 2 2390 9 9

28 2 325.4 36.517 36.516 2 17.953 17.896 26.475 199.0 2 201.5 2 30.2 0.00 2 4.39 2 0.21 2 1.30 2 9 9 9 9 9 2103.6 2 7.9775 2 2387 2 2387 9 9

27 2 351.0 36.472 36.471 2 17.652 17.592 26.517 198.1 2 193.8 2 39.3 0.00 2 5.56 2 0.27 2 1.60 2 9 9 9 9 419.3 381.4 2 2111.3 2 7.9531 2 2387 2 2380 9 9

26 2 399.5 36.350 36.354 2 16.896 16.829 26.608 189.0 2 186.4 2 50.3 0.00 2 7.32 2 0.38 2 2.10 2 9 9 9 9 9 9 9 9 9 9

25 2 450.4 36.214 36.214 2 16.083 16.010 26.697 183.0 2 182.7 2 58.0 0.00 2 8.98 2 0.48 2 2.70 2 9 9 9 9 9 9 9 9 9 9

24 2 501.4 36.053 36.047 2 15.102 15.024 26.797 179.9 2 177.1 2 68.6 0.00 2 11.03 2 0.62 2 3.60 2 9 9 9 9 508.4 416.4 2 2137.4 2 7.8741 2 2363 2 2360 9 9

23 2 549.5 35.908 35.914 2 14.196 14.114 26.883 178.5 2 176.4 2 74.1 0.00 2 12.50 2 0.71 2 4.30 2 9 9 9 9 9 9 9 9 9 9

22 2 596.1 35.794 35.796 2 13.365 13.280 26.969 175.6 2 173.8 2 81.1 0.00 2 14.06 2 0.82 2 5.20 2 9 9 9 9 9 9 9 9 9 9

21 3 650.1 35.679 35.683 2 12.539 12.450 27.047 173.5 2 171.3 2 88.3 0.00 2 15.62 2 0.93 2 6.20 2 9 9 9 9 9 9 9 9 9 9

20 2 723.6 35.522 35.523 2 11.248 11.155 27.171 165.9 2 163.5 6 103.5 0.00 2 18.55 2 1.13 2 8.50 2 9 9 9 9 674.6 470.3 2 2166.8 2 7.7614 2 2336 2 2332 9 9

19 2 848.5 35.299 35.303 2 9.436 9.337 27.314 153.4 2 152.2 2 126.0 0.00 2 22.85 2 1.46 2 12.90 2 9 9 9 9 791.7 511.2 2 2184.7 2 7.7014 2 2330 2 2324 9 9

18 2 920.5 35.150 35.154 2 8.194 8.095 27.392 150.3 2 148.9 2 137.4 0.00 2 25.30 2 1.65 2 15.90 2 9 9 9 9 858.0 525.8 2 2194.1 2 7.6695 2 9 2320 9 9

17 2 1000.0 35.028 35.029 2 6.995 6.896 27.469 157.4 2 156.9 2 137.7 0.00 2 26.28 2 1.75 2 18.50 2 9 9 9 9 904.3 526.2 2 2195.9 6 7.6493 2 5 2313 9 9

16 2 1199.2 35.053 35.053 2 5.801 5.691 27.647 211.4 2 207.2 2 95.7 0.00 2 21.59 2 1.44 2 15.30 2 9 9 9 9 796.2 436.5 2 2180.6 2 7.6952 2 2323 2 2316 9 9

15 2 1401.1 35.059 35.059 2 4.952 4.831 27.756 241.8 2 241.3 2 67.9 0.00 2 18.85 2 1.25 2 13.20 2 9 9 9 9 9 9 9 9 9 9

14 2 1600.7 35.048 35.047 2 4.480 4.345 27.802 252.5 2 251.6 2 61.3 0.00 2 18.46 2 1.23 2 14.00 2 9 9 9 9 715.2 367.1 2 2162.2 2 7.7348 2 9 2313 9 9

13 2 1800.3 35.044 35.043 2 4.156 4.005 27.836 254.5 2 254.2 2 61.3 0.00 2 18.66 2 1.23 2 16.30 2 9 9 9 9 9 9 9 9 9 9

12 2 2000.9 35.020 35.020 2 3.805 3.640 27.856 256.5 2 256.1 2 62.3 0.00 2 18.76 2 1.26 2 19.10 2 9 9 9 9 9 9 7.7389 2 9 9 9

11 2 2297.1 34.986 34.985 2 3.348 3.162 27.876 257.0 2 257.1 2 65.2 0.00 2 19.24 2 1.30 2 24.10 2 9 9 9 9 9 9 9 9 9 9

10 2 2500.5 34.967 34.969 2 3.148 2.945 27.882 257.7 2 258.1 2 65.9 0.00 2 19.44 2 1.31 2 26.20 2 0.01 2 0.01 2 0.00 2 9 720.7 346.2 2 2172.0 2 7.7383 2 9 2325 9 9

9 2 2800.6 34.948 34.948 2 2.917 2.689 27.892 258.6 2 259.5 2 66.7 0.00 2 18.95 3 1.33 2 29.20 2 9 9 9 9 9 9 9 9 9 9

8 2 3101.1 34.931 34.931 2 2.715 2.460 27.899 262.9 2 261.9 2 66.2 0.00 2 19.25 2 1.33 2 30.80 2 9 9 9 9 9 9 7.7376 2 9 9 9

7 2 3500.5 34.915 34.915 2 2.528 2.235 27.908 268.0 2 266.7 2 63.3 0.00 2 18.86 2 1.31 2 30.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3889.9 34.902 34.903 2 2.373 2.041 27.915 270.2 2 268.3 2 63.4 0.00 2 18.86 2 1.31 2 32.70 2 9 9 9 9 726.5 335.6 2 2172.7 2 7.7361 2 9 2324 9 9

5 2 4301.1 34.891 34.891 2 2.282 1.905 27.920 268.9 2 266.9 2 66.0 0.00 2 19.34 2 1.36 2 37.10 2 0.05 2 0.03 2 0.00 2 9 9 2177.2 2 7.7318 2 9 2327 9 9

4 2 4698.1 34.883 34.883 2 2.234 1.811 27.924 268.5 2 266.0 2 67.7 0.00 2 19.54 2 1.38 2 39.60 2 9 9 9 9 691.1 315.8 3 2180.6 2 7.7290 2 5 2330 9 9

3 2 5100.4 34.858 34.858 2 2.075 1.607 27.921 260.6 2 258.6 2 76.9 0.00 2 21.49 2 1.50 2 51.10 2 9 9 9 9 9 9 9 9 9 9

2 2 5500.1 34.844 34.845 2 2.023 1.506 27.920 255.5 2 254.7 2 81.7 0.00 2 22.37 2 1.57 2 56.40 2 0.02 2 0.02 2 0.00 2 9 9 9 9 9 9 9

1 2 5958.0 34.842 34.842 2 2.064 1.485 27.923 254.8 2 254.1 2 82.5 0.00 6 22.67 6 1.59 6 57.90 6 9 9 9 9 792.3 359.6 2 2202.3 2 7.7051 6 2352 2 2342 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

146
A5R

NOAA Ship Ronald H. Brown

STATION 78 DATE 2/12/1998 LATITUDE 24.500° N

LONGITUDE 60.067° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.8 36.819 36.818 2 24.413 24.412 24.898 214.0 2 212.7 2 -6.8 0.00 2 0.00 2 0.00 2 1.00 2 1.86 2 1.08 2 0.16 2 9 269.0 320.2 2 2035.3 6 8.1146 2 2404 2 2410 74.5 2 9

35 2 46.5 36.821 36.821 2 24.415 24.405 24.904 211.6 2 212.6 2 -6.7 0.00 2 0.00 2 0.01 2 0.90 2 1.86 2 1.08 2 0.15 2 9 267.3 318.2 3 2035.6 2 8.1167 2 5 2412 74.0 2 9

34 2 94.9 37.181 37.186 2 23.433 23.413 25.475 221.9 2 218.6 2 0.7 0.00 2 0.00 2 0.01 2 0.60 2 2.05 2 1.16 2 0.21 2 9 299.6 343.1 2 2073.9 2 8.0786 2 5 2430 67.0 2 9

33 2 130.9 37.176 37.173 2 22.238 22.212 25.821 211.7 2 213.8 2 -0.5 0.08 2 0.00 2 0.02 2 0.50 2 2.14 2 1.22 2 0.16 2 9 318.0 347.6 3 2083.6 2 8.0575 2 2425 2 2425 62.9 2 9

32 2 172.3 36.943 36.936 2 20.669 20.636 26.084 201.5 2 203.9 2 15.8 0.02 2 0.59 2 0.03 2 0.60 2 2.24 2 1.27 2 0.14 2 9 351.2 360.7 2 2095.4 2 8.0270 2 2411 2 2414 56.6 2 9

31 2 205.5 36.768 36.766 2 19.636 19.598 26.229 200.5 2 202.5 2 21.6 0.01 2 1.17 2 0.04 2 0.80 2 2.28 2 1.29 2 0.09 2 9 370.8 365.5 2 2097.0 2 8.0088 2 2397 2 2402 54.1 2 9

30 2 235.8 36.657 36.657 2 18.904 18.862 26.336 199.9 2 201.5 2 25.9 0.01 2 2.24 2 0.08 2 0.90 2 2.34 2 1.32 2 0.05 2 9 374.0 357.8 2 2098.7 2 7.9967 2 2392 2 2395 50.9 2 9

29 2 261.3 36.592 36.593 2 18.485 18.439 26.395 202.3 2 204.5 2 24.7 0.00 2 2.93 2 0.12 2 1.00 2 2.36 2 1.31 2 0.04 2 9 375.1 352.9 3 2097.4 2 7.9932 2 2387 2 2391 49.7 2 9

28 2 284.9 36.556 36.555 2 18.255 18.205 26.427 204.4 2 206.7 2 23.6 0.00 2 3.41 2 0.15 2 1.10 2 2.35 2 1.32 2 0.04 2 9 379.3 353.5 2 2096.8 2 7.9970 2 2386 2 2393 9 9

27 2 346.6 36.515 36.515 2 17.951 17.891 26.476 207.2 2 207.6 2 24.1 0.00 2 3.90 2 0.19 2 1.30 2 2.34 6 1.29 6 0.04 6 9 386.0 355.3 3 2096.6 2 7.9885 2 2382 2 2387 50.9 2 9

26 2 395.6 36.439 36.435 2 17.482 17.414 26.537 202.5 2 197.7 6 36.3 0.00 2 5.56 2 0.29 2 1.80 2 2.25 2 1.23 2 0.03 2 9 413.1 373.1 2 2108.0 2 7.9625 2 2378 2 2382 9 9

25 2 456.1 36.279 36.279 2 16.493 16.418 26.653 193.2 2 190.5 2 48.2 0.00 2 7.61 2 0.42 2 2.30 2 2.18 2 1.18 2 0.03 2 9 449.5 389.9 2 2120.3 2 7.9261 2 2369 2 2372 44.3 2 9

24 2 503.7 36.139 36.138 2 15.641 15.561 26.744 188.0 2 184.7 2 58.3 0.00 2 9.47 2 0.54 2 3.10 2 2.09 2 1.11 2 0.02 2 9 483.6 404.8 2 2129.1 2 7.8951 2 2364 2 2363 9 9

23 2 606.1 35.848 35.848 2 13.799 13.710 26.923 168.3 2 168.7 2 83.9 0.00 2 13.86 2 0.84 2 5.20 2 1.60 2 0.83 2 0.02 2 9 567.0 439.6 2 2147.7 2 7.8322 2 2347 2 2348 43.9 2 9

22 2 707.1 35.549 35.547 2 11.744 11.651 27.100 158.9 2 158.7 2 105.5 0.00 2 18.36 2 1.14 2 8.60 2 0.96 2 0.50 2 0.01 2 9 673.8 479.9 2 2164.4 2 7.7683 2 5 2333 9 9

21 2 801.0 35.349 35.349 2 10.120 10.023 27.237 152.2 2 152.3 2 121.7 0.00 2 21.78 2 1.39 2 11.80 2 0.54 2 0.29 2 0.01 2 9 764.0 508.2 2 2178.9 2 7.7186 2 2327 2 2325 42.4 2 9

20 2 902.8 35.124 35.123 2 8.315 8.217 27.354 145.4 2 145.7 2 139.9 0.00 2 25.59 2 1.68 2 16.40 2 0.23 2 0.12 2 0.01 2 9 881.2 543.5 2 2193.9 2 7.6637 2 2320 2 2317 9 9

19 2 1004.3 35.046 35.047 2 7.221 7.120 27.453 158.3 2 155.0 2 138.0 0.00 2 26.18 2 1.74 2 18.40 2 0.14 2 0.08 2 0.01 2 9 894.0 525.1 2 2197.1 2 7.6522 2 2318 2 2315 41.6 2 9

18 2 1250.2 35.050 35.050 2 5.684 5.570 27.661 208.9 2 206.8 2 97.0 0.00 2 21.78 2 1.47 2 16.20 2 0.22 2 0.12 2 0.00 2 9 802.0 437.4 2 2181.4 6 7.6960 2 2318 2 2317 9 9

17 2 1450.3 35.058 35.058 2 4.995 4.868 27.751 240.6 2 239.7 2 69.2 0.00 2 18.85 2 1.27 2 13.50 2 0.46 2 0.24 2 0.01 2 9 747.5 393.9 2 2169.7 2 7.7241 2 2316 2 2316 41.9 2 9

16 2 1647.0 35.049 35.050 2 4.513 4.373 27.801 252.0 2 250.8 2 61.9 0.00 2 18.36 2 1.24 2 14.10 2 0.22 6 0.12 6 0.01 6 9 727.8 374.5 2 2165.9 2 7.7358 2 2317 2 2317 9 9

15 2 1849.9 35.037 35.037 2 4.155 4.000 27.832 255.3 2 255.2 2 60.3 0.00 2 18.36 2 1.24 2 15.90 2 0.10 2 0.06 2 0.01 2 9 715.5 361.5 2 2165.4 2 7.7429 2 2318 2 2320 41.5 2 9

14 2 2050.5 35.022 35.023 2 3.796 3.626 27.859 254.7 2 255.1 2 63.4 0.00 2 18.75 2 1.28 2 19.80 2 0.04 2 0.03 2 0.01 2 9 9 2169.4 2 7.7404 2 2323 2 2323 9 9

13 2 2250.0 34.993 34.994 2 3.439 3.256 27.873 256.3 2 256.7 2 64.8 0.00 2 19.05 2 1.30 2 23.10 2 0.02 2 0.01 2 0.00 2 9 722.5 352.3 2 2171.8 2 7.7391 2 2322 2 2325 41.8 2 9

12 2 2452.0 34.975 34.976 2 3.240 3.040 27.880 256.4 2 257.3 2 66.0 0.00 2 19.14 2 1.32 2 25.70 2 0.01 2 0.01 2 0.01 2 9 9 2174.6 2 7.7387 2 9 2328 9 9

11 2 2600.2 34.965 34.965 2 3.105 2.893 27.886 255.2 2 257.2 2 67.3 0.00 2 19.34 2 1.33 2 27.70 2 0.01 2 0.01 2 0.00 2 9 717.5 343.7 2 2176.5 2 7.7379 2 2330 2 2329 41.7 2 9

10 2 2846.7 34.949 34.949 2 2.922 2.689 27.893 256.6 2 257.4 2 68.8 0.00 2 19.44 2 1.35 2 30.30 2 0.00 2 0.00 2 0.00 2 9 724.8 344.1 2 2178.5 2 7.7345 2 9 2330 9 9

9 2 3047.6 34.937 34.937 2 2.790 2.539 27.898 259.4 2 259.7 2 67.7 0.00 2 19.54 2 1.36 2 31.40 2 0.01 2 0.01 2 0.00 2 0.16 2 722.4 340.6 2 2177.6 2 7.7369 2 2332 2 2330 41.8 2 9

8 2 3350.5 34.923 34.923 2 2.621 2.342 27.904 263.7 2 263.5 2 65.6 0.00 2 19.15 2 1.33 2 31.30 2 0.04 2 0.02 2 0.00 2 9 721.5 337.4 2 2177.0 2 7.7385 2 9 2330 9 9

7 2 3644.0 34.911 34.911 2 2.469 2.162 27.911 266.2 2 266.7 2 63.9 0.00 2 18.85 2 1.32 2 31.90 2 0.07 2 0.04 2 0.01 2 0.29 2 715.2 331.8 2 2176.1 2 4 2329 2 41.7 2 9

6 2 3950.9 34.902 34.901 2 2.356 2.017 27.917 268.2 2 268.9 2 63.0 0.00 2 18.76 2 1.31 2 32.50 2 0.09 2 0.05 2 0.00 2 0.39 2 715.4 330.1 2 2176.4 2 7.7363 2 9 2328 9 9

5 2 4249.2 34.895 34.895 2 2.299 1.928 27.921 268.8 2 269.9 2 62.8 0.00 2 18.76 2 1.31 2 33.30 2 0.11 2 0.06 2 0.00 2 0.44 2 721.6 332.0 2 2176.7 2 7.7345 2 2328 2 2328 41.6 2 9

4 2 4550.3 34.890 34.890 2 2.272 1.866 27.924 268.2 2 268.3 2 64.9 0.00 2 19.05 2 1.34 2 35.50 2 0.10 2 0.06 2 0.01 2 0.46 2 721.2 331.2 2 2179.3 2 7.7334 2 9 2330 9 9

3 2 4948.7 34.873 34.874 2 2.178 1.726 27.923 262.6 2 262.6 2 71.8 0.00 2 20.42 2 1.44 2 44.30 2 0.05 2 0.03 2 0.00 2 0.26 2 746.7 341.0 2 2188.8 2 7.7280 2 2338 2 2338 41.8 2 9

2 2 5449.4 34.847 34.848 2 2.032 1.521 27.920 254.4 2 254.6 2 81.7 0.00 2 22.27 2 1.57 2 55.80 2 0.03 6 0.02 6 0.01 6 0.19 2 776.3 351.7 2 2201.3 2 7.7100 2 9 2343 9 9

1 2 5970.4 34.842 34.843 2 2.066 1.485 27.923 253.0 2 253.7 2 82.9 0.00 6 22.57 6 1.60 6 58.00 6 0.03 2 0.03 2 0.00 2 0.19 2 789.9 358.5 2 2204.6 2 7.7048 2 2346 2 2345 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

147
A5R

NOAA Ship Ronald H. Brown

STATION 79 DATE 2/13/1998 LATITUDE 24.500° N

LONGITUDE 61.801° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.9 36.801 36.803 2 24.307 24.306 24.916 215.6 2 212.4 2 -6.1 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 268.2 317.9 2 2035.2 6 8.1059 2 2407 2 2403 9 9

35 2 49.1 36.808 36.809 2 24.333 24.322 24.919 212.4 2 212.1 6 -5.9 0.00 2 0.00 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 124.4 37.123 37.121 2 22.193 22.168 25.793 205.3 2 205.7 2 7.9 0.04 2 0.20 2 0.01 2 0.60 2 9 9 9 9 326.4 356.1 2 2090.1 2 8.0449 2 2424 2 2423 9 9

33 2 175.9 36.909 36.900 2 20.489 20.456 26.107 201.6 2 203.7 2 16.8 0.02 2 0.59 2 0.02 2 0.50 2 9 9 9 9 350.9 358.0 2 2096.4 2 8.0219 2 2412 2 2412 9 9

32 2 197.4 36.770 36.767 2 19.656 19.620 26.224 201.6 2 203.2 2 20.8 0.01 2 1.07 2 0.04 2 0.60 2 9 9 9 9 9 9 9 9 9 9

31 2 222.6 36.658 36.655 2 18.922 18.882 26.331 201.1 2 203.8 2 23.5 0.01 2 2.05 2 0.07 2 0.80 2 9 9 9 9 370.1 354.5 2 2096.4 2 7.9995 2 2396 2 2395 9 9

30 2 248.1 36.607 36.609 2 18.593 18.549 26.378 204.1 2 204.8 2 23.9 0.01 2 2.63 2 0.10 2 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 274.3 36.557 36.555 2 18.256 18.208 26.426 208.1 2 208.4 2 21.9 0.01 2 3.32 2 0.14 2 1.10 2 9 9 9 9 9 9 9 9 9 9

28 2 298.9 36.536 36.535 2 18.115 18.063 26.448 209.7 2 210.1 2 20.9 0.01 2 3.61 2 0.16 2 1.20 2 9 9 9 9 375.2 347.7 2 2094.1 2 7.9912 2 2395 2 2386 9 9

27 3 351.5 36.515 36.513 2 17.937 17.876 26.480 212.0 2 210.2 2 21.6 0.01 2 3.80 2 0.18 2 1.30 2 9 9 9 9 9 2092.8 2 9 9 9 9

26 2 400.4 36.477 36.477 2 17.719 17.650 26.509 208.7 2 207.1 2 25.7 0.00 2 4.49 2 0.22 2 1.50 2 9 9 9 9 9 9 9 9 9 9

25 2 450.0 36.383 36.379 2 17.157 17.081 26.576 202.7 2 199.4 2 36.1 0.01 2 6.15 2 0.32 2 2.00 2 9 9 9 9 415.9 370.8 2 2108.0 2 7.9536 2 2377 2 2376 9 9

24 2 500.5 36.230 36.236 2 16.228 16.147 26.680 194.8 2 190.5 2 49.5 0.00 2 8.39 2 0.45 2 2.60 2 9 9 9 9 9 9 9 9 9 9

23 2 550.0 36.092 36.094 2 15.371 15.285 26.771 186.9 2 184.1 2 60.3 0.00 2 10.34 2 0.58 2 3.40 2 9 9 9 9 9 9 9 9 9 9

22 2 600.0 35.904 35.900 2 14.159 14.070 26.891 180.1 2 177.4 2 73.3 0.00 2 13.08 2 0.74 2 4.70 2 9 9 9 9 548.2 431.9 2 2139.5 2 7.8474 2 2358 2 2347 9 9

21 2 636.2 35.815 35.838 2 13.615 13.523 26.937 177.6 2 175.7 2 77.9 0.00 2 13.96 2 0.79 2 5.20 2 9 9 9 9 9 9 9 9 9 9

20 2 748.9 35.489 35.490 2 11.196 11.100 27.156 164.7 2 157.7 2 109.7 0.00 2 20.31 2 1.21 2 9.50 2 9 9 9 9 9 9 9 9 9 9

19 2 851.0 35.290 35.294 2 9.540 9.440 27.290 150.5 2 149.8 2 127.8 0.00 2 24.12 2 1.47 2 13.20 2 9 9 9 9 793.6 515.2 2 2182.1 2 7.7021 2 5 2321 9 9

18 2 904.3 35.187 35.185 2 8.636 8.536 27.354 146.5 2 146.9 2 136.5 0.00 2 26.17 2 1.62 2 15.70 2 9 9 9 9 9 9 9 9 9 9

17 2 998.7 35.055 35.059 2 7.310 7.209 27.447 150.9 2 152.5 2 139.9 0.00 2 27.74 2 1.74 2 18.50 2 9 9 9 9 896.5 528.6 2 2195.8 6 7.6522 2 5 2314 9 9

16 2 1099.1 35.004 35.005 2 6.473 6.368 27.522 166.5 2 166.1 2 132.1 0.00 2 27.44 2 1.74 2 19.50 2 9 9 9 9 9 9 9 9 9 9

15 2 1300.8 35.054 35.052 2 5.572 5.454 27.678 213.8 2 212.4 2 92.2 0.00 2 22.56 2 1.43 2 15.90 2 9 9 9 9 799.8 433.9 2 2176.0 2 7.6989 2 2318 2 2312 9 9

14 2 1498.4 35.060 35.061 2 4.832 4.702 27.772 242.7 2 242.0 2 68.2 0.00 2 18.17 2 1.27 2 14.40 2 9 9 9 9 9 9 9 9 9 9

13 2 1700.1 35.051 35.052 2 4.431 4.287 27.812 251.2 2 251.2 2 62.1 0.00 2 17.48 2 1.24 2 15.20 2 9 9 9 9 9 9 9 9 9 9

12 2 1898.0 35.039 2 4.100 3.941 27.840 253.3 2 254.2 2 61.8 0.00 2 17.68 2 1.25 2 17.20 2 9 9 9 9 9 9 9 9 9 9

11 2 2199.1 35.003 35.004 2 3.562 3.382 27.868 253.9 2 255.3 2 65.2 0.00 2 18.17 2 1.29 2 22.60 2 9 9 9 9 719.5 352.9 2 2167.5 2 7.7398 2 2332 2 2321 9 9

10 2 2500.1 34.974 34.974 2 3.201 2.997 27.883 255.2 2 256.6 2 67.0 0.00 2 18.46 2 1.32 2 26.50 2 9 9 9 9 9 9 9 9 9 9

9 2 2798.9 34.952 34.953 2 2.975 2.745 27.890 255.5 2 257.6 2 68.1 0.00 2 18.85 2 1.35 2 29.80 2 9 9 9 9 9 9 9 9 9 9

8 2 3100.8 34.934 34.934 2 2.760 2.504 27.898 259.1 2 259.9 2 67.8 0.00 2 18.95 2 1.35 2 31.80 2 9 9 9 9 9 9 9 9 9 9

7 2 3400.1 34.919 34.919 2 2.587 2.303 27.905 262.1 2 262.5 2 66.9 0.00 2 18.85 2 1.35 2 33.00 2 9 9 9 9 731.3 341.5 2 2173.4 2 7.7384 2 9 2326 9 9

6 2 3700.3 34.908 34.908 2 2.446 2.133 27.912 265.3 2 266.1 2 64.8 0.00 2 18.56 2 1.33 2 33.00 2 9 9 9 9 9 9 9 9 9 9

5 2 4043.5 34.898 34.898 2 2.336 1.987 27.918 266.4 2 267.5 2 64.6 0.00 2 18.66 2 1.34 2 34.70 2 9 9 9 9 9 9 9 9 9 9

4 2 4491.2 34.889 34.889 2 2.271 1.872 27.922 268.7 2 266.5 2 66.6 0.00 2 18.75 2 1.36 2 37.20 2 9 9 9 9 9 9 9 9 9 9

3 2 4898.7 34.874 34.874 2 2.190 1.744 27.923 262.0 2 262.6 2 71.7 0.00 2 19.83 2 1.43 2 43.70 2 9 9 9 9 9 9 9 9 9 9

2 2 5394.3 34.847 34.847 2 2.022 1.519 27.920 254.3 2 254.9 2 81.4 0.00 2 21.78 2 1.57 2 56.00 2 9 9 9 9 9 9 9 9 9 9

1 2 5890.5 34.842 34.842 2 2.055 1.485 27.923 252.0 2 254.1 2 82.5 0.01 6 22.17 6 1.59 6 57.90 6 9 9 9 9 794.9 360.8 6 2201.3 2 7.7047 2 5 2341 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

148
A5R

NOAA Ship Ronald H. Brown

STATION 80 DATE 2/13/1998 LATITUDE 24.500° N

LONGITUDE 63.534° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 3 6.3 36.636 36.648 2 24.875 24.874 24.619 206.1 2 211.5 2 -7.0 9 9 9 9 1.81 2 1.05 2 0.16 2 2.00 2 263.6 319.3 6 2023.7 6 8.1186 6 2401 6 2398 74.8 2 9

35 2 49.8 36.651 36.769 2 24.887 24.876 24.633 208.7 2 210.6 2 -6.2 0.00 2 0.10 2 0.01 2 1.10 2 1.84 2 1.07 2 0.16 2 1.80 2 9 9 9 9 74.6 2 9

34 2 70.9 37.174 37.184 2 25.070 25.054 24.975 217.0 2 219.7 2 -16.5 0.00 2 0.00 2 0.01 2 0.90 2 1.95 2 1.10 2 0.18 2 9 9 9 9 9 65.2 2 9

33 2 151.8 37.133 37.127 2 21.767 21.737 25.924 196.0 2 195.6 2 19.6 0.02 2 0.68 2 0.02 2 0.80 2 2.12 2 1.21 2 0.12 2 0.82 6 9 9 9 9 55.5 2 9

32 2 199.1 36.865 36.861 2 20.031 19.994 26.198 186.7 2 188.8 2 33.6 0.01 2 1.85 2 0.06 2 1.00 2 2.21 2 1.25 2 0.05 2 9 9 9 9 9 52.5 2 9

31 2 220.1 36.685 36.678 2 19.129 19.089 26.298 186.0 2 199.9 2 26.5 0.01 2 1.85 2 0.06 2 1.10 2 2.32 2 1.30 2 0.05 2 9 9 9 9 9 51.2 2 9

30 2 250.6 36.611 36.606 2 18.615 18.570 26.376 190.9 2 203.6 2 25.1 0.01 2 2.83 2 0.11 2 1.30 2 2.35 2 1.32 2 0.05 2 0.52 2 9 9 9 9 9 9

29 2 270.1 36.577 36.577 2 18.390 18.342 26.408 195.3 2 204.6 2 25.1 0.00 2 3.03 2 0.13 2 1.40 2 9 9 9 9 9 9 9 9 48.7 2 9

28 2 300.9 36.542 36.538 2 18.129 18.076 26.449 196.7 2 203.2 2 27.7 0.00 2 3.90 2 0.18 2 1.70 2 2.33 6 1.28 6 0.04 6 9 9 9 9 9 9 9

27 2 351.3 36.495 36.496 2 17.813 17.752 26.495 193.7 2 198.4 2 34.0 0.00 2 4.88 2 0.23 2 1.90 2 2.27 2 1.24 2 0.02 2 9 9 9 9 9 47.3 2 9

26 2 399.5 36.422 36.421 2 17.304 17.236 26.566 187.9 2 186.7 2 48.1 0.00 2 6.73 2 0.35 2 2.20 2 2.21 2 1.19 2 0.02 2 9 9 9 9 9 9 9

25 2 450.7 36.286 36.278 2 16.465 16.391 26.665 177.7 2 176.5 2 62.3 0.00 2 9.08 2 0.50 2 3.00 2 9 9 9 9 9 9 9 9 42.8 2 9

24 2 499.4 36.111 36.111 2 15.446 15.367 26.765 179.7 2 178.1 2 65.8 0.00 2 10.35 2 0.58 2 3.60 2 1.99 2 1.05 2 0.03 2 0.40 2 9 9 9 9 9 9

23 2 599.4 35.826 35.830 2 13.658 13.571 26.934 168.7 2 168.3 2 85.1 0.00 2 14.16 2 0.83 2 5.60 2 1.59 2 0.81 2 0.01 2 9 9 9 9 9 43.4 2 9

22 2 700.8 35.570 35.572 2 11.855 11.762 27.096 159.6 2 160.9 2 102.6 0.00 2 17.97 2 1.10 2 8.30 2 1.02 2 0.53 2 0.02 2 9 9 9 9 9 9 9

21 2 800.1 35.299 35.303 2 9.788 9.693 27.255 149.4 2 149.0 2 127.0 0.00 2 22.66 2 1.45 2 12.90 2 0.45 2 0.24 2 0.01 2 9 9 9 9 9 46.6 2 9

20 2 850.0 35.211 35.212 2 8.965 8.869 27.320 145.9 2 148.6 2 132.7 0.00 2 24.03 2 1.56 2 14.70 2 0.32 2 0.17 2 0.01 2 0.17 2 9 9 9 9 9 9

19 2 898.4 35.120 35.121 2 8.210 8.113 27.366 144.5 2 146.6 2 139.7 0.00 2 25.59 2 1.68 2 16.70 2 9 9 9 9 9 9 9 9 9 9

18 2 950.5 35.033 35.030 2 7.389 7.292 27.418 154.2 2 151.3 2 140.6 0.00 2 26.08 2 1.75 2 18.60 2 0.17 2 0.09 2 0.01 2 9 9 9 9 9 9 9

17 2 1051.0 35.022 35.021 2 6.586 6.485 27.520 176.1 2 171.7 6 125.7 0.00 2 24.52 2 1.66 2 18.30 2 0.20 2 0.11 2 0.01 2 9 9 9 9 9 9 9

16 2 1150.2 35.060 35.061 2 6.029 5.922 27.624 201.6 2 198.8 2 102.5 0.00 2 21.69 2 1.47 2 16.10 2 0.29 2 0.15 2 0.01 2 0.49 2 9 9 9 9 9 9

15 2 1339.3 35.078 35.078 2 5.205 5.087 27.741 235.4 2 233.4 2 73.9 0.00 2 19.05 2 1.28 2 14.10 2 0.38 2 0.18 2 0.02 2 9 9 9 9 9 41.8 2 9

14 2 1550.8 35.042 35.043 2 4.475 4.344 27.797 250.2 2 253.0 2 59.9 0.00 2 18.27 2 1.22 2 13.90 2 0.37 2 0.19 2 0.01 2 9 9 9 9 9 9 9

13 2 1748.3 35.019 35.019 2 4.098 3.953 27.821 258.3 2 260.0 2 56.0 0.00 2 17.98 2 1.20 2 14.80 2 0.31 2 0.17 2 0.01 2 0.94 6 9 9 9 9 9 9

12 2 1949.8 35.016 35.016 2 3.856 3.695 27.847 257.9 2 258.5 2 59.5 0.00 2 18.37 2 1.23 2 17.70 2 0.11 2 0.06 2 0.01 2 9 9 9 9 9 9 9

11 2 2200.2 34.986 34.987 2 3.464 3.285 27.864 260.2 2 248.9 4 72.4 0.00 2 18.37 2 1.24 2 20.10 2 0.07 2 0.04 2 0.01 2 9 9 9 9 9 9 9

10 2 2449.9 34.967 34.967 2 3.186 2.987 27.878 259.3 2 263.8 2 59.9 0.00 2 18.56 2 1.27 2 23.10 2 0.07 2 0.04 2 0.01 2 0.39 2 9 9 9 9 9 9

9 2 2693.8 34.954 34.954 2 3.002 2.783 27.888 260.3 2 261.4 2 64.0 0.00 2 18.95 2 1.30 2 26.30 2 0.05 2 0.02 2 0.01 2 9 9 9 9 9 9 9

8 2 2999.4 34.938 34.937 2 2.800 2.554 27.897 260.8 2 261.8 2 65.5 0.00 2 19.25 2 1.32 2 29.20 2 0.04 2 0.02 2 0.01 2 0.21 2 9 9 9 9 9 9

7 2 3399.0 34.919 34.920 2 2.566 2.283 27.906 268.5 2 268.5 2 61.1 0.00 2 18.47 2 1.27 2 28.10 2 0.15 2 0.08 2 0.01 2 0.48 2 9 9 9 9 9 9

6 2 3799.8 34.905 34.905 2 2.405 2.082 27.914 266.4 2 267.5 2 63.8 0.00 2 18.95 2 1.32 2 32.90 2 0.07 2 0.04 2 0.01 2 0.33 2 9 9 9 9 9 9

5 2 4201.0 34.897 34.898 2 2.327 1.960 27.920 268.1 2 268.2 2 64.2 0.00 2 18.95 2 1.32 2 33.90 2 0.09 2 0.05 2 0.01 2 0.38 2 9 9 9 9 9 9

4 2 4599.0 34.889 34.890 2 2.281 1.868 27.924 267.2 2 267.4 2 65.8 0.00 2 19.25 2 1.34 2 36.10 2 0.09 2 0.05 2 0.01 2 0.43 2 9 9 9 9 9 9

3 2 4998.2 34.879 34.879 2 2.228 1.768 27.926 265.7 2 264.7 2 69.4 0.00 2 19.93 2 1.39 2 40.70 2 0.11 2 0.06 2 0.01 2 0.41 2 9 9 9 9 9 9

2 2 5499.6 34.848 34.849 2 2.056 1.538 27.921 254.8 2 255.4 2 80.7 0.00 2 22.28 2 1.55 2 54.80 2 0.03 2 0.02 2 0.01 2 0.19 2 9 9 9 9 9 9

1 2 5968.3 34.842 34.842 2 2.070 1.489 27.923 252.4 2 253.7 2 82.8 0.00 6 22.77 6 1.59 6 57.70 6 0.03 2 0.03 2 0.01 2 0.23 2 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

149
A5R

NOAA Ship Ronald H. Brown

STATION 81 DATE 2/13/1998 LATITUDE 24.499° N

LONGITUDE 63.264° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.2 36.435 36.435 2 24.974 24.973 24.436 207.3 2 209.9 2 -5.4 0.00 2 0.10 2 0.00 2 0.90 2 9 9 9 9 263.4 320.4 2 2016.1 6 8.1166 2 2381 2 2386 9 9

35 2 41.5 36.771 36.793 2 24.436 24.427 24.859 210.6 2 209.9 2 -4.0 0.00 2 0.10 2 0.00 2 0.70 2 9 9 9 9 9 9 9 9 9 9

34 2 82.6 36.763 36.743 2 23.640 23.623 25.096 216.6 2 214.2 2 -5.4 0.00 2 0.10 2 0.00 2 0.70 2 9 9 9 9 275.7 318.4 2 2038.9 2 8.1007 2 2399 2 2403 9 9

33 2 121.0 36.894 36.898 2 22.044 22.020 25.661 200.9 2 209.6 2 4.8 0.03 2 0.20 2 0.01 2 0.50 2 9 9 9 9 318.2 345.1 2 2076.0 2 8.0552 2 2408 2 2412 9 9

32 2 169.3 36.815 36.829 2 20.108 20.076 26.137 194.0 2 197.3 2 24.8 0.01 2 0.88 2 0.03 2 0.50 2 9 9 9 9 9 9 9 9 9 9

31 2 203.8 36.677 36.677 2 19.133 19.096 26.289 195.4 2 200.4 2 25.9 0.01 2 1.66 2 0.06 2 0.70 2 9 9 9 9 371.6 358.8 2 2097.4 2 8.0009 2 2395 2 2397 9 9

30 2 241.4 36.588 36.587 2 18.485 18.442 26.390 200.4 2 203.3 2 25.9 0.00 2 2.93 2 0.12 2 1.00 2 9 9 9 9 9 9 9 9 9 9

29 2 269.8 36.562 36.562 2 18.297 18.250 26.420 202.2 2 204.5 2 25.6 0.00 2 3.22 2 0.15 2 1.00 2 9 9 9 9 9 9 9 9 9 9

28 2 295.2 36.544 36.545 2 18.145 18.093 26.446 205.6 2 207.9 2 22.9 0.00 2 3.32 2 0.16 2 1.10 2 9 9 9 9 378.9 351.4 2 2094.2 2 7.9948 2 2385 2 2388 9 9

27 2 355.3 36.489 36.486 2 17.796 17.735 26.495 209.0 2 203.1 2 29.4 0.00 2 4.29 2 0.22 2 1.60 2 9 9 9 9 9 9 9 9 9 9

26 2 416.5 36.358 36.358 2 17.048 16.978 26.580 197.8 2 190.3 2 45.7 0.00 2 6.54 2 0.36 2 2.00 2 9 9 9 9 9 9 9 9 9 9

25 2 477.5 36.205 36.197 2 16.045 15.968 26.701 183.3 2 180.1 2 60.8 0.00 2 9.08 2 0.52 2 2.90 2 9 9 9 9 475.0 404.5 2 2130.1 2 7.9002 2 2368 2 2368 9 9

24 2 575.0 35.868 35.869 2 13.988 13.903 26.897 180.7 2 174.5 2 77.1 0.00 2 12.89 2 0.77 2 4.80 2 9 9 9 9 9 9 9 9 9 9

23 2 673.3 35.537 35.554 2 11.708 11.619 27.096 158.8 2 157.5 2 106.9 0.00 2 18.36 2 1.12 2 8.30 2 9 9 9 9 670.0 476.3 2 2165.7 2 7.7702 2 2334 2 2335 9 9

22 2 774.8 35.259 35.256 2 9.583 9.492 27.256 145.4 2 146.3 2 131.0 0.00 2 23.54 2 1.49 2 13.30 2 9 9 9 9 9 9 9 9 9 9

21 2 873.9 35.101 35.103 2 8.051 7.958 27.374 145.6 2 148.5 2 138.8 0.00 2 25.59 2 1.66 2 16.40 2 9 9 9 9 884.8 539.5 2 2195.1 2 7.6625 2 2324 2 2318 9 9

20 2 974.6 35.039 35.037 2 7.017 6.920 27.474 164.9 2 163.4 2 131.0 0.00 2 25.40 2 1.67 2 17.60 2 9 9 9 9 9 9 9 9 9 9

19 2 1076.6 35.030 35.031 2 6.241 6.140 27.572 185.5 2 185.4 6 114.4 0.00 2 23.64 2 1.57 2 17.10 2 9 9 9 9 855.3 479.8 2 2189.0 6 7.6758 2 2319 2 2316 9 9

18 2 1275.6 35.052 35.053 2 5.137 5.026 27.726 234.1 2 233.9 2 73.9 0.00 2 19.24 2 1.28 2 13.50 2 9 9 9 9 9 9 9 9 9 9

17 2 1473.2 35.027 35.027 2 4.526 4.402 27.778 253.1 2 253.3 2 59.2 0.00 2 18.07 2 1.20 2 12.80 2 9 9 9 9 9 9 9 9 9 9

16 2 1673.7 35.009 35.009 2 4.117 3.979 27.810 260.0 2 261.4 2 54.4 0.00 2 17.78 2 1.19 2 13.70 2 9 9 9 9 9 2162.3 2 7.7351 2 2313 2 2313 9 9

15 2 1872.4 35.001 35.000 2 3.853 3.700 27.833 262.7 2 263.6 2 54.4 0.00 2 17.78 2 1.20 2 15.20 2 9 9 9 9 9 9 9 9 9 9

14 2 2076.5 34.996 34.997 2 3.617 3.448 27.855 260.1 2 261.5 2 58.5 0.00 2 18.07 2 1.23 2 18.20 2 9 9 9 9 718.6 353.8 2 2165.1 2 7.7405 2 2319 2 2319 9 9

13 2 2275.6 34.985 34.986 2 3.391 3.206 27.871 258.2 2 258.9 2 63.0 0.00 2 18.66 2 1.27 2 21.90 2 9 9 9 9 9 9 9 9 9 9

12 2 2476.9 34.972 34.973 2 3.209 3.007 27.881 257.3 2 258.1 2 65.4 0.00 2 19.05 2 1.30 2 25.00 2 9 9 9 9 9 9 9 9 9 9

11 2 2676.2 34.950 34.951 2 2.976 2.759 27.887 261.4 2 263.1 2 62.5 0.00 2 18.66 2 1.27 2 25.00 2 9 9 9 9 9 2171.2 2 7.7399 2 2324 2 2325 9 9

10 2 2875.9 34.941 34.941 2 2.850 2.615 27.893 262.1 2 263.9 2 62.9 0.00 2 18.76 2 1.28 2 26.30 2 9 9 9 9 9 9 9 9 9 9

9 2 3075.4 34.931 34.931 2 2.723 2.470 27.898 264.4 2 266.1 2 61.9 0.00 2 18.56 2 1.27 2 27.10 2 0.11 2 0.06 2 0.00 2 9 720.4 339.0 2 2170.4 2 7.7386 2 2328 2 2323 9 9

8 2 3375.7 34.918 34.918 2 2.555 2.275 27.906 266.1 2 266.1 2 63.6 0.00 2 18.95 2 1.30 2 30.10 2 0.07 6 0.04 6 0.01 6 9 9 9 9 9 9 9

7 2 3677.6 34.910 34.909 2 2.433 2.123 27.914 270.6 2 271.0 2 60.0 0.00 2 18.17 2 1.25 2 28.10 2 0.19 2 0.10 2 0.01 2 9 9 9 9 9 9 9

6 2 3965.8 34.903 34.904 2 2.358 2.018 27.918 271.7 2 271.8 2 60.1 0.00 2 18.17 2 1.26 2 28.90 2 0.21 2 0.11 2 0.02 2 9 736.2 340.6 6 2170.4 2 7.7376 2 2324 2 2323 9 9

5 2 4374.6 34.894 34.894 2 2.296 1.910 27.923 268.4 2 268.6 2 64.2 0.00 2 18.95 2 1.31 2 33.90 2 9 9 9 9 9 2175.6 2 9 9 9 9

4 2 4775.6 34.885 34.885 2 2.252 1.819 27.926 267.7 2 266.5 2 67.1 0.00 2 19.34 2 1.34 2 37.00 2 9 9 9 9 9 2180.8 2 7.7301 2 2336 2 2330 9 9

3 2 5131.7 34.863 34.863 2 2.123 1.650 27.922 259.4 2 259.6 2 75.5 0.00 2 21.10 2 1.47 2 48.30 2 9 9 9 9 9 9 9 9 9 9

2 2 5571.4 34.845 34.845 2 2.034 1.507 27.921 253.0 2 254.4 2 82.0 0.00 2 22.47 2 1.57 2 56.30 2 9 9 9 9 9 9 9 9 9 9

1 2 5912.2 34.842 34.842 2 2.060 1.487 27.922 251.9 2 253.7 2 82.9 0.00 6 22.67 6 1.58 6 57.50 6 9 9 9 9 788.6 357.8 2 2204.6 2 7.7056 2 2351 2 2345 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

150
A5R

NOAA Ship Ronald H. Brown

STATION 82 DATE 2/14/1998 LATITUDE 24.500° N

LONGITUDE 64.000° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 36.797 36.797 2 24.046 24.045 24.991 216.3 2 214.2 2 -7.0 0.00 2 0.10 2 0.01 2 0.80 2 1.89 2 1.10 2 0.16 2 9 273.0 320.3 2 2036.6 6 8.1049 2 2408 2 2404 71.2 2 4.4 2

35 2 37.6 36.794 36.794 2 24.029 24.021 24.998 213.7 2 214.5 6 -7.2 0.00 2 0.10 2 0.01 2 0.80 2 1.89 2 1.10 2 0.16 2 9 274.4 321.8 2 2037.8 2 9 2407 2 71.3 2 4.4 2

34 2 79.3 37.031 37.031 2 23.194 23.178 25.430 218.0 2 218.8 2 -8.8 0.00 2 0.10 2 0.01 2 0.50 2 2.08 2 1.18 2 0.18 2 9 303.1 343.8 2 2071.1 2 8.0727 2 2427 2 2421 62.0 2 4.5 2

33 2 119.0 36.945 36.954 2 21.363 21.340 25.890 205.5 2 208.1 2 8.8 0.04 2 0.39 2 0.02 2 0.50 2 2.16 2 1.23 2 0.14 2 9 336.5 355.4 2 2088.7 2 8.0403 2 2419 2 2416 57.6 2 5.1 2

32 2 200.0 36.640 36.632 2 18.912 18.876 26.318 200.1 2 204.1 2 23.2 0.01 2 2.44 2 0.09 2 0.80 2 2.33 6 1.31 6 0.06 6 9 373.3 357.3 2 2096.4 2 7.9990 2 2396 2 2394 49.7 2 5.9 2

31 2 224.8 36.599 36.599 2 18.560 18.520 26.378 204.4 2 205.2 2 23.7 0.01 2 2.93 2 0.12 2 1.00 2 2.36 2 1.31 2 0.05 2 9 378.7 357.3 2 2095.3 2 7.9948 2 2393 2 2390 49.2 2 6.7 2

30 2 248.4 36.577 36.578 2 18.404 18.360 26.403 202.2 2 204.5 2 25.1 0.01 2 3.32 2 0.14 2 1.10 2 2.36 2 1.30 2 0.04 2 9 9 2095.7 2 8.0006 2 9 2394 48.7 2 7.0 2

29 2 274.8 36.553 36.553 2 18.228 18.180 26.430 204.1 2 205.2 2 25.2 0.00 2 3.71 2 0.16 2 1.20 2 2.34 2 1.29 2 0.04 2 9 385.1 358.5 2 2096.7 2 7.9921 2 9 2389 48.0 2 7.3 2

28 2 300.0 36.528 36.526 2 18.041 17.989 26.460 205.0 2 204.7 2 26.6 0.00 2 4.20 2 0.20 2 1.30 2 2.32 2 1.27 2 0.03 2 9 9 2099.4 2 7.9884 2 2391 2 2390 9 9

27 2 347.4 36.470 36.468 2 17.675 17.615 26.510 202.7 2 200.2 2 32.8 0.00 2 5.17 2 0.26 2 1.60 2 2.25 2 1.22 2 0.04 2 9 406.5 370.0 2 2105.7 2 7.9636 2 9 2381 48.2 2 8.8 2

26 2 400.2 36.364 36.361 2 17.067 17.000 26.579 199.3 2 193.3 2 42.6 0.00 2 6.73 2 0.36 2 2.00 2 2.18 2 1.16 2 0.03 2 9 9 2113.7 2 7.9422 2 2385 2 2375 9 9

25 2 448.1 36.242 36.252 2 16.332 16.259 26.661 189.7 2 187.6 2 51.9 0.00 2 8.30 2 0.45 2 2.60 2 2.11 2 1.12 2 0.03 2 9 455.6 392.5 3 2119.6 2 9 2380 2 45.8 2 12.0 2

24 2 499.6 36.067 36.068 2 15.265 15.187 26.771 186.8 2 182.5 2 62.4 0.00 2 10.44 2 0.60 2 3.60 2 1.97 2 1.03 2 0.03 2 9 9 2130.3 2 7.8860 2 2364 2 2359 9 9

23 2 551.1 35.892 35.905 2 14.153 14.071 26.880 181.0 2 179.3 2 71.4 0.00 2 12.40 2 0.73 2 4.60 2 1.80 2 0.93 2 0.02 2 9 539.9 425.3 2 2137.9 2 7.8524 2 9 2348 44.4 2 15.2 2

22 2 598.3 35.723 35.732 2 13.048 12.964 26.978 178.4 2 168.9 2 87.8 0.00 2 15.23 2 0.92 2 6.30 2 1.45 2 0.75 2 0.03 2 9 9 2150.2 2 7.8158 2 2345 2 2342 9 9

21 2 697.7 35.505 35.510 2 11.358 11.268 27.137 168.2 2 162.8 2 103.6 0.00 2 18.65 2 1.16 2 8.90 2 0.95 6 0.49 6 0.01 6 9 686.3 480.8 3 2163.6 2 9 2340 2 44.0 2 9

20 2 800.4 35.289 35.293 2 9.595 9.501 27.278 156.7 2 153.2 2 124.0 0.00 2 22.66 2 1.44 2 12.70 2 0.48 2 0.25 2 0.01 2 9 9 2180.6 2 7.7051 2 2328 2 2321 9 9

19 2 846.5 35.191 35.192 2 8.757 8.663 27.337 152.8 2 151.5 2 131.1 0.00 2 24.22 2 1.56 2 14.70 2 0.34 2 0.18 2 0.00 2 9 830.6 521.2 2 2187.2 2 7.6772 2 2323 2 2316 41.6 2 26.9 2

18 2 901.9 35.111 35.111 2 7.897 7.802 27.405 155.4 2 155.0 2 133.3 0.00 2 25.20 2 1.64 2 16.30 2 0.25 2 0.13 2 0.01 2 9 868.8 525.7 2 2187.3 2 7.6674 2 5 2311 9 9

17 2 901.6 35.105 35.108 2 7.797 7.703 27.415 155.4 2 155.7 2 133.3 0.00 2 25.20 2 1.64 2 16.40 2 0.25 2 0.13 2 0.00 2 9 869.2 524.0 2 9 7.6661 2 2320 2 41.7 2 9

16 2 1048.6 35.065 35.063 2 6.458 6.358 27.570 184.2 2 184.4 2 113.8 0.00 2 23.54 2 1.57 2 16.70 2 0.24 2 0.12 2 0.00 2 9 840.5 475.8 6 2187.9 6 7.6770 2 2322 2 2316 9 9

15 2 1244.5 35.088 35.088 2 5.449 5.338 27.718 225.8 2 225.0 2 80.4 0.00 2 20.12 2 1.34 2 14.30 2 0.34 2 0.18 2 0.01 2 9 753.4 405.6 2 2173.6 2 9 2319 2 41.7 2 22.7 2

14 2 1450.1 35.071 35.071 2 4.779 4.655 27.785 247.2 2 245.9 2 64.6 0.00 2 18.85 2 1.25 2 13.90 2 0.32 2 0.16 2 0.01 2 9 724.2 377.3 2 2166.5 2 7.7295 2 2319 2 2315 9 9

13 2 1625.6 35.058 35.059 2 4.440 4.303 27.815 254.2 2 251.9 2 61.3 0.00 2 18.66 2 1.24 2 14.90 2 0.22 6 0.12 6 0.01 6 9 9 2165.1 2 7.7354 2 2320 2 2317 41.4 2 9

12 2 1848.9 35.035 35.036 2 4.017 3.864 27.844 255.4 2 255.3 2 61.3 0.00 2 18.76 2 1.26 2 17.60 2 0.07 2 0.04 2 0.01 2 9 9 2166.0 2 4 2323 2 9 9

11 2 2046.8 35.012 35.013 2 3.665 3.498 27.863 256.6 2 256.9 2 62.6 0.00 2 19.05 2 1.28 2 20.70 2 0.03 2 0.02 2 0.00 2 9 714.5 352.2 2 2169.4 2 7.7400 2 2325 2 2323 41.9 2 21.3 2

10 2 2231.1 34.990 34.991 2 3.397 3.216 27.874 257.4 2 257.5 2 64.3 0.00 2 19.24 2 1.31 2 23.70 2 0.02 2 0.01 2 0.00 2 9 9 9 9 9 9 9

9 2 2545.7 34.960 34.962 2 3.068 2.862 27.884 260.2 2 260.8 2 63.9 0.00 2 19.24 2 1.31 2 26.10 2 0.03 2 0.02 2 0.00 2 9 9 2171.5 2 7.7371 2 2328 2 2324 41.5 2 22.2 2

8 2 2844.2 34.941 34.942 2 2.839 2.608 27.893 262.7 2 263.9 2 63.0 0.00 2 19.15 2 1.31 2 27.60 2 0.07 2 0.03 2 0.01 2 9 717.2 339.3 2 2170.7 2 9 9 9 9

7 2 3147.4 34.927 34.928 2 2.656 2.397 27.902 265.5 2 264.8 2 63.8 0.00 2 19.44 2 1.33 2 30.40 2 0.05 2 0.02 2 0.01 2 9 9 2171.4 2 9 2329 2 43.2 2 9

6 2 3449.1 34.915 34.915 2 2.500 2.213 27.909 267.9 2 267.1 2 63.1 0.00 2 19.25 2 1.33 2 31.50 2 0.06 6 0.03 6 0.00 6 9 9 2173.9 2 9 9 9 9

5 2 3837.9 34.904 34.905 2 2.360 2.034 27.917 273.3 2 271.6 2 60.1 0.00 2 18.66 2 1.30 2 30.60 2 0.14 2 0.07 2 0.01 2 9 724.2 334.6 2 2171.1 2 7.7381 2 2328 2 2324 41.9 2 9

4 2 4341.1 34.894 34.894 2 2.283 1.901 27.923 271.9 2 270.8 2 62.1 0.00 2 18.85 2 1.31 2 33.00 2 0.16 2 0.08 2 0.01 2 9 9 2174.9 2 9 9 9 9

3 2 4847.2 34.873 34.874 2 2.169 1.730 27.923 264.8 2 263.4 2 71.0 0.00 2 20.61 2 1.44 2 44.00 2 0.06 2 0.03 2 0.01 2 9 9 2187.8 2 7.7232 2 2339 2 2335 41.9 2 23.5 2

2 2 5349.6 34.848 34.850 2 2.027 1.529 27.920 255.0 2 256.2 2 80.0 0.00 2 22.27 2 1.57 2 55.40 2 0.03 2 0.02 2 0.01 2 9 786.5 356.4 2 2200.7 2 9 9 9 9

1 2 5861.6 34.843 34.844 2 2.065 1.499 27.922 255.1 2 254.8 2 81.6 0.00 6 22.57 6 1.59 6 57.50 6 0.03 2 0.02 2 0.00 2 9 785.8 356.6 6 2203.8 2 7.7048 2 2348 2 2344 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

151
A5R

NOAA Ship Ronald H. Brown

STATION 83 DATE 2/14/1998 LATITUDE 24.500° N

LONGITUDE 64.667° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.1 36.815 36.815 2 23.810 23.809 25.075 215.0 2 215.1 2 -7.1 0.00 2 0.10 2 0.00 2 0.70 2 9 9 9 9 273.0 317.4 2 2041.5 6 8.1065 2 2421 2 2411 9 9

35 2 46.3 36.809 36.810 2 23.795 23.785 25.080 214.6 2 214.9 6 -6.8 0.00 2 0.10 2 0.01 2 0.60 2 9 9 9 9 9 9 9 9 9 9

34 2 88.7 36.780 36.814 2 23.062 23.044 25.279 217.8 2 218.3 2 -7.5 0.00 2 0.10 2 0.01 2 0.50 2 9 9 9 9 287.8 324.9 2 2052.6 2 8.0874 2 2415 2 2409 9 9

33 2 134.8 36.883 36.916 2 21.026 21.000 25.937 211.3 2 206.7 2 11.6 0.05 2 0.39 2 0.02 2 0.40 2 9 9 9 9 340.3 354.5 2 2091.4 2 8.0319 2 2415 2 2413 9 9

32 2 169.5 36.775 36.767 2 19.881 19.849 26.166 196.8 2 198.8 2 24.3 0.01 2 1.46 2 0.04 2 0.50 2 9 9 9 9 367.9 366.1 2 2102.4 2 8.0076 2 2412 2 2407 9 9

31 2 224.2 36.626 36.626 2 18.737 18.697 26.354 200.2 2 200.6 2 27.5 0.00 2 3.03 2 0.08 2 0.80 2 9 9 9 9 9 9 9 9 9 9

30 2 249.3 36.611 36.607 2 18.623 18.579 26.373 201.0 2 201.1 2 27.5 0.00 2 3.32 2 0.10 2 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 273.6 36.583 36.582 2 18.451 18.403 26.398 204.4 2 204.3 2 25.1 0.00 2 3.51 2 0.12 2 0.90 2 9 9 9 9 381.2 358.1 2 2100.0 2 7.9911 2 2402 2 2392 9 9

28 2 300.8 36.548 36.548 2 18.185 18.132 26.440 208.2 2 207.2 2 23.4 0.00 2 3.81 2 0.15 2 1.00 2 9 9 9 9 9 9 9 9 9 9

27 2 351.4 36.494 36.502 2 17.820 17.759 26.492 206.7 2 203.9 2 28.4 0.00 2 4.69 2 0.19 2 1.30 2 9 9 9 9 9 9 9 9 9 9

26 2 409.1 36.403 36.405 2 17.299 17.230 26.554 197.2 2 194.8 2 40.0 0.00 2 6.44 2 0.29 2 1.80 2 9 9 9 9 421.4 377.3 2 2114.6 2 7.9534 2 2384 2 2383 9 9

25 2 459.6 36.267 36.267 2 16.496 16.421 26.643 190.9 2 188.1 2 50.6 0.00 2 8.30 2 0.40 2 2.30 2 9 9 9 9 9 9 9 9 9 9

24 2 510.2 36.133 36.133 2 15.669 15.588 26.733 181.1 2 179.6 2 63.3 0.00 2 10.25 2 0.53 2 3.10 2 9 9 9 9 9 9 9 9 9 9

23 2 545.2 36.025 36.030 2 14.979 14.895 26.805 184.3 2 181.6 2 64.8 0.00 2 11.04 2 0.58 2 3.50 2 9 9 9 9 513.5 418.2 2 2135.1 2 7.8768 2 5 2359 9 9

22 2 599.4 35.884 35.882 2 14.086 13.997 26.891 179.3 2 176.4 2 74.7 0.00 2 13.19 2 0.72 2 4.50 2 9 9 9 9 9 9 9 9 9 9

21 2 700.5 35.604 35.607 2 12.065 11.971 27.083 170.8 2 169.0 2 93.3 0.00 2 17.10 2 0.99 2 7.10 2 9 9 9 9 9 9 9 9 9 9

20 2 800.8 35.377 35.382 2 10.246 10.148 27.238 160.9 2 159.6 2 113.6 0.00 2 21.10 2 1.28 2 10.60 2 9 9 9 9 737.2 492.6 2 2176.9 2 7.7307 2 2339 2 2328 9 9

19 2 861.5 35.193 35.197 2 8.734 8.638 27.342 153.0 2 152.5 2 130.3 0.00 2 24.33 2 1.52 2 14.10 2 9 9 9 9 9 9 9 9 9 9

18 2 911.0 35.133 35.133 2 8.087 7.990 27.395 154.8 2 156.8 2 130.3 0.00 2 24.92 2 1.58 2 15.20 2 9 9 9 9 840.9 511.7 2 2192.0 2 7.6739 2 5 2319 9 9

17 2 1042.6 35.082 35.080 2 6.722 6.620 27.549 182.1 2 181.3 2 115.0 0.00 2 23.65 2 1.51 2 15.70 2 9 9 9 9 839.5 481.1 2 2188.9 6 7.6796 2 9 2318 9 9

16 2 1249.9 35.069 35.071 2 5.435 5.323 27.705 228.9 2 226.0 2 79.5 0.00 2 20.23 2 1.29 2 14.00 2 9 9 9 9 767.9 413.5 2 2173.2 2 7.7100 2 5 2314 9 9

15 2 1448.7 35.043 35.044 2 4.793 4.669 27.762 250.4 2 247.5 2 62.9 0.00 2 18.86 2 1.19 2 12.60 2 9 9 9 9 9 9 9 9 9 9

14 2 1648.9 35.011 35.014 2 4.319 4.181 27.791 260.3 2 259.3 2 54.9 0.00 2 18.28 2 1.16 2 12.50 2 9 9 9 9 9 9 9 9 9 9

13 2 1850.8 34.986 34.987 2 3.691 3.542 27.836 267.4 2 267.1 2 52.1 0.00 2 18.08 2 1.16 2 15.00 2 9 9 9 9 708.1 350.0 6 2161.4 2 7.7408 2 5 2315 9 9

12 2 2049.0 34.992 34.992 2 3.502 3.337 27.862 261.9 2 262.5 2 58.3 0.00 2 18.67 2 1.22 2 19.30 2 9 9 9 9 9 9 9 9 9 9

11 2 2349.9 34.964 34.963 2 3.178 2.989 27.874 265.2 2 267.0 2 56.7 0.00 2 18.57 2 1.20 2 20.20 2 9 9 9 9 9 9 9 9 9 9

10 2 2549.3 34.958 34.958 2 3.041 2.835 27.885 261.0 2 262.3 2 62.7 0.00 2 19.35 2 1.24 2 24.80 2 9 9 9 9 9 9 9 9 9 9

9 2 2742.9 34.947 34.948 2 2.905 2.683 27.891 260.1 2 262.1 2 64.1 0.00 2 19.65 2 1.30 2 27.60 2 9 9 9 9 719.4 341.3 2 2174.1 2 7.7364 2 2331 2 2326 9 9

8 2 2992.9 34.935 34.935 2 2.758 2.513 27.897 263.7 2 263.5 2 64.2 0.00 2 19.55 2 1.28 2 28.20 2 9 9 9 9 9 9 9 9 9 9

7 2 3299.5 34.921 34.921 2 2.592 2.319 27.905 264.6 2 265.7 2 63.6 0.00 2 19.55 2 1.29 2 29.90 2 9 9 9 9 9 9 9 9 9 9

6 2 3599.6 34.910 34.910 2 2.459 2.157 27.911 266.2 2 267.3 2 63.4 0.00 2 19.55 2 1.29 2 31.50 2 9 9 9 9 9 9 9 9 9 9

5 2 3900.7 34.902 34.902 2 2.359 2.026 27.916 269.8 2 270.4 2 61.4 0.00 2 19.25 2 1.28 2 31.20 2 9 9 9 9 724.4 334.6 2 2174.1 2 7.7337 2 2336 3 2325 9 9

4 2 4391.7 34.891 34.891 2 2.266 1.879 27.923 268.8 2 268.3 2 64.8 0.00 2 19.65 2 1.31 2 34.90 2 9 9 9 9 9 9 9 9 9 9

3 2 4893.1 34.873 34.873 2 2.173 1.728 27.923 263.8 2 263.8 2 70.6 0.00 2 20.92 2 1.41 2 43.70 2 9 9 9 9 9 9 9 9 9 9

2 2 5399.9 34.850 34.851 2 2.052 1.547 27.921 256.5 2 256.7 2 79.3 0.00 2 22.48 2 1.54 2 53.00 2 9 9 9 9 9 9 9 9 9 9

1 2 5837.8 34.844 34.845 2 2.067 1.504 27.923 254.6 2 255.0 2 81.4 0.00 6 22.77 6 1.57 6 55.50 6 9 9 9 9 789.0 358.3 2 2204.9 2 7.7075 2 5 2346 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

152
A5R

NOAA Ship Ronald H. Brown

STATION 84 DATE 2/14/1998 LATITUDE 24.501° N

LONGITUDE 65.469° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 6.4 36.726 36.730 2 23.883 23.882 24.986 213.2 2 214.3 2 -6.4 0.01 2 0.20 2 0.01 2 0.80 2 1.91 2 1.11 2 0.17 2 1.83 2 275.6 321.3 6 2036.9 6 8.1077 6 2410 6 2406 9 9

35 2 50.5 36.734 36.735 2 23.778 23.767 25.029 214.3 2 214.6 2 -6.3 0.01 2 0.20 2 0.01 2 0.70 2 1.90 2 1.10 2 0.17 2 9 9 9 9 9 9 9

34 2 101.1 36.789 36.797 2 23.459 23.438 25.171 216.1 2 216.2 2 -6.8 0.00 2 0.20 2 0.00 2 0.60 2 1.96 2 1.12 2 0.16 2 1.75 6 9 9 9 9 9 9

33 2 150.1 36.902 36.898 2 20.904 20.875 25.986 202.1 2 202.7 2 16.1 0.04 2 0.78 2 0.02 2 0.50 2 2.20 2 1.24 2 0.12 2 9 9 9 9 9 9 9

32 2 199.3 36.681 36.678 2 19.197 19.161 26.276 197.4 2 202.6 2 23.5 0.02 2 2.05 2 0.06 2 0.70 2 2.30 2 1.30 2 0.07 2 9 9 9 9 9 9 9

31 2 220.2 36.629 36.626 2 18.834 18.795 26.331 202.7 2 206.2 2 21.5 0.01 2 2.54 2 0.09 2 0.80 2 2.36 2 1.31 2 0.05 2 9 9 9 9 9 9 9

30 2 247.9 36.589 36.588 2 18.476 18.432 26.393 207.7 2 210.4 2 18.9 0.01 2 3.03 2 0.12 2 1.00 2 2.35 2 1.31 2 0.05 2 9 9 9 9 9 9 9

29 2 273.6 36.569 36.566 2 18.296 18.248 26.425 209.4 2 212.0 2 18.1 0.01 2 3.32 2 0.14 2 1.00 2 9 9 9 9 9 9 9 9 9 9

28 2 298.0 36.559 36.557 2 18.206 18.154 26.443 211.1 2 213.0 2 17.5 0.01 2 3.42 2 0.14 2 1.10 2 2.38 2 1.33 2 0.05 2 9 9 9 9 9 9 9

27 3 349.4 36.541 36.541 2 18.046 17.985 26.473 215.0 2 214.1 2 17.2 0.02 2 3.61 2 0.15 2 1.10 2 9 9 9 9 9 9 9 9 9 9

26 2 399.7 36.506 36.506 2 17.848 17.779 26.499 210.5 2 211.5 2 20.7 0.01 2 4.20 2 0.20 2 1.30 2 2.34 2 1.30 2 0.06 2 0.67 2 9 9 9 9 9 9

25 2 449.3 36.401 36.401 2 17.302 17.226 26.555 200.6 2 190.9 2 43.9 0.01 2 6.25 2 0.32 2 1.90 2 9 9 9 9 9 9 9 9 9 9

24 2 499.6 36.239 36.238 2 16.377 16.295 26.652 191.7 2 190.2 6 49.2 0.01 2 8.49 2 0.46 2 2.70 2 2.08 2 1.12 2 0.04 2 9 9 9 9 9 9 9

23 2 602.4 35.954 35.952 2 14.546 14.455 26.847 181.3 2 179.7 2 69.0 0.01 2 12.11 2 0.70 2 4.20 2 9 9 9 9 9 9 9 9 9 9

22 2 701.0 35.673 35.675 2 12.588 12.491 27.036 174.3 2 172.2 2 87.1 0.01 2 15.92 2 0.96 2 6.50 2 1.39 2 0.71 2 0.02 2 0.32 2 9 9 9 9 9 9

21 2 800.7 35.407 35.408 2 10.541 10.442 27.211 158.9 2 159.0 2 112.4 0.01 2 20.71 2 1.29 2 10.50 2 9 9 9 9 9 9 9 9 9 9

20 2 901.3 35.183 35.183 2 8.610 8.510 27.355 153.3 2 153.3 2 130.3 0.01 2 24.52 2 1.57 2 14.90 2 0.32 2 0.17 2 0.00 2 9 9 9 9 9 9 9

19 2 997.5 35.099 35.102 2 7.327 7.226 27.480 169.6 2 169.7 2 122.5 0.01 2 24.23 2 1.59 2 16.10 2 0.32 2 0.16 2 0.01 2 9 9 9 9 9 9 9

18 2 1199.7 35.080 35.081 2 5.714 5.605 27.680 215.7 2 214.7 2 88.8 0.01 2 21.10 2 1.40 2 14.80 2 0.31 2 0.16 2 0.01 2 9 9 9 9 9 9 9

17 2 1401.0 35.052 35.052 2 4.799 4.679 27.767 248.5 2 246.8 2 63.6 0.01 2 18.95 2 1.26 2 13.30 2 0.48 2 0.24 2 0.01 2 0.98 2 9 9 9 9 9 9

16 2 1599.9 35.017 35.019 2 4.229 4.097 27.804 261.2 2 260.2 2 54.6 0.01 2 18.27 2 1.22 2 13.60 2 0.46 2 0.23 2 0.01 2 9 9 9 9 9 9 9

15 2 1799.9 35.012 35.011 2 3.962 3.814 27.830 262.8 2 262.4 2 54.6 0.01 2 18.27 2 1.22 2 15.10 2 0.25 2 0.13 2 0.01 2 9 9 9 9 9 9 9

14 2 1993.7 35.003 35.002 2 3.733 3.570 27.848 262.3 2 262.8 2 56.2 0.00 2 18.56 2 1.25 2 17.30 2 0.12 2 0.06 2 0.00 2 9 9 9 9 9 9 9

13 2 2199.5 34.990 34.990 2 3.481 3.302 27.866 261.7 2 261.7 2 59.4 0.00 2 18.86 2 1.27 2 20.40 2 9 9 9 9 9 9 9 9 9 9

12 2 2399.5 34.970 34.972 2 3.227 3.033 27.876 263.3 2 263.3 2 60.0 0.01 2 18.95 2 1.29 2 22.70 2 0.07 2 0.04 2 0.00 2 0.40 2 9 9 9 9 9 9

11 2 2593.3 34.960 34.960 2 3.076 2.865 27.884 261.2 2 261.4 2 63.3 0.01 2 19.35 2 1.31 2 25.60 2 0.04 2 0.02 2 0.01 2 9 9 9 9 9 9 9

10 2 2798.3 34.947 34.947 2 2.907 2.679 27.891 260.0 2 261.9 2 64.4 0.01 2 19.64 2 1.33 2 27.80 2 0.04 2 0.02 2 0.01 2 9 9 9 9 9 9 9

9 2 3049.4 34.935 34.935 2 2.766 2.515 27.898 263.3 2 263.1 2 64.5 0.01 2 19.64 2 1.34 2 29.60 2 0.03 2 0.02 2 0.00 2 0.23 2 9 9 9 9 9 9

8 2 3348.1 34.922 34.922 2 2.597 2.318 27.905 266.5 2 266.9 2 62.4 0.01 2 19.54 2 1.33 2 30.60 2 0.06 2 0.03 2 0.00 2 0.28 2 9 9 9 9 9 9

7 2 3623.6 34.910 34.910 2 2.452 2.147 27.912 268.5 2 268.3 2 62.5 0.01 2 19.25 2 1.32 2 31.50 2 0.07 2 0.04 2 0.00 2 0.34 2 9 9 9 9 9 9

6 2 3949.1 34.902 34.902 2 2.355 2.017 27.918 271.2 2 270.6 2 61.3 0.01 2 19.05 2 1.31 2 31.70 2 0.10 2 0.05 2 0.01 2 0.44 2 9 9 9 9 9 9

5 2 4198.4 34.897 34.897 2 2.301 1.935 27.922 272.1 2 271.9 2 60.7 0.01 2 18.96 2 1.30 2 31.80 2 0.15 6 0.08 6 0.01 6 0.56 2 9 9 9 9 9 9

4 2 4499.7 34.889 34.889 2 2.259 1.859 27.924 270.8 2 269.1 2 64.2 0.01 2 19.54 2 1.34 2 35.50 2 0.10 2 0.06 2 0.01 2 0.46 6 9 9 9 9 9 9

3 2 4800.3 34.875 34.876 2 2.179 1.745 27.923 266.5 2 265.5 2 68.8 0.00 2 20.62 2 1.42 2 42.40 2 0.06 2 0.04 2 0.01 2 0.32 2 9 9 7.7266 6 9 9 9

2 2 5183.5 34.856 34.857 2 2.076 1.598 27.921 259.6 2 258.9 2 76.7 0.01 2 21.98 2 1.52 2 51.10 2 0.04 2 0.03 2 0.01 2 0.22 2 9 9 7.7153 6 9 9 9

1 2 5649.6 34.847 34.847 2 2.062 1.524 27.922 256.2 2 255.7 2 80.5 0.01 6 22.67 6 1.58 6 55.80 6 0.02 2 0.02 2 0.00 2 0.19 2 9 9 7.7095 6 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

153
A5R

NOAA Ship Ronald H. Brown

STATION 85 DATE 2/15/1998 LATITUDE 24.500° N

LONGITUDE 65.200° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 36.446 36.454 2 24.998 24.997 24.438 207.7 2 211.4 2 -7.0 0.00 2 0.20 2 0.01 2 0.90 2 9 9 9 9 271.0 329.8 2 2017.7 6 8.1160 2 5 2388 9 9

35 2 36.2 36.557 36.564 2 24.707 24.699 24.614 208.7 2 210.0 6 -4.8 0.00 2 0.20 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 71.3 36.706 36.708 2 24.372 24.357 24.833 209.8 2 211.6 2 -5.4 0.01 2 0.20 2 0.01 2 0.80 2 9 9 9 9 275.7 327.5 2 2034.5 2 8.1000 2 2397 2 2397 9 9

33 2 104.9 37.004 37.009 2 23.689 23.667 25.267 198.2 2 202.0 2 6.3 0.10 2 0.49 2 0.02 2 0.60 2 9 9 9 9 308.7 357.2 2 2074.3 2 8.0590 2 2416 2 2414 9 9

32 2 159.1 37.005 36.981 2 21.738 21.706 25.836 184.5 2 191.2 2 24.3 0.02 2 1.27 2 0.04 2 0.60 2 9 9 9 9 346.6 371.6 2 2100.3 2 8.0265 2 5 2420 9 9

31 2 208.5 36.919 36.923 2 20.534 20.494 26.106 176.1 2 178.0 2 42.3 0.01 2 3.22 2 0.13 2 0.90 2 9 9 9 9 9 9 9 9 9 9

30 2 232.6 36.779 36.792 2 19.670 19.627 26.231 187.2 2 185.2 2 38.8 0.01 2 3.02 2 0.12 2 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 260.7 36.685 36.693 2 19.015 18.968 26.331 185.9 2 188.0 2 38.9 0.01 2 3.80 2 0.15 2 1.00 2 9 9 9 9 395.5 380.0 2 2112.8 2 7.9727 2 2395 2 2396 9 9

28 2 285.2 36.627 36.628 2 18.626 18.575 26.388 188.6 2 191.6 2 37.0 0.01 2 4.29 2 0.18 2 1.10 2 9 9 9 9 9 9 9 9 9 9

27 3 310.2 36.559 36.565 2 18.239 18.185 26.435 192.5 2 186.5 2 43.9 0.01 2 5.66 2 0.28 2 1.60 2 9 9 9 9 9 9 9 9 9 9

26 2 369.7 36.464 36.460 2 17.591 17.528 26.527 188.9 2 184.2 2 49.2 0.01 2 7.03 2 0.36 2 1.90 2 9 9 9 9 9 9 9 9 9 9

25 2 429.9 36.287 36.298 2 16.583 16.512 26.636 180.7 2 177.0 2 61.3 0.01 2 9.08 2 0.50 2 2.60 2 9 9 9 9 467.7 407.2 2 2131.3 2 7.9082 2 2371 2 2374 9 9

24 2 489.3 36.100 36.095 2 15.528 15.451 26.738 171.6 2 162.2 2 81.4 0.01 2 12.30 2 0.72 2 3.90 2 9 9 9 9 9 9 9 9 9 9

23 2 586.9 35.786 35.809 2 13.591 13.506 26.917 167.6 2 159.6 2 94.2 0.01 2 15.42 2 0.92 2 5.80 2 9 9 9 9 9 9 9 9 9 9

22 2 691.2 35.525 35.532 2 11.650 11.559 27.098 166.3 2 160.8 2 103.9 0.01 2 18.65 2 1.16 2 8.60 2 9 9 9 9 660.9 468.3 2 2166.7 2 7.7619 2 2335 2 2332 9 9

21 2 790.4 35.303 35.313 2 9.879 9.785 27.241 150.4 2 151.3 2 124.2 0.00 2 22.46 2 1.44 2 12.20 2 9 9 9 9 9 9 9 9 9 9

20 2 889.6 35.100 35.100 2 8.199 8.104 27.351 147.4 2 147.2 2 139.2 0.00 2 25.88 2 1.71 2 16.50 2 9 9 9 9 884.8 543.0 2 2197.8 2 7.6572 2 2319 2 2318 9 9

19 2 989.2 35.060 35.061 2 7.094 6.995 27.481 165.4 2 163.9 2 129.9 0.00 2 25.30 2 1.67 2 17.30 2 9 9 9 9 864.7 504.5 2 2195.7 6 7.6634 2 2321 2 2318 9 9

18 2 1097.6 35.058 35.057 2 6.330 6.226 27.583 186.9 2 187.5 2 111.6 0.00 2 23.44 2 1.56 2 16.60 2 9 9 9 9 826.1 464.6 2 2190.4 2 7.6795 2 2320 2 2319 9 9

17 2 1299.8 35.060 35.032 2 5.195 5.081 27.727 233.3 2 233.0 2 74.4 0.00 2 19.63 2 1.31 2 13.60 2 9 9 9 9 9 9 9 9 9 9

16 2 1498.7 35.031 35.032 2 4.558 4.431 27.778 253.7 2 253.6 2 58.7 0.00 2 18.46 2 1.22 2 12.80 2 9 9 9 9 730.5 376.8 2 2166.3 2 7.7297 2 2314 2 2315 9 9

15 2 1696.3 35.009 35.009 2 4.134 3.994 27.808 263.0 2 262.3 2 53.4 0.00 2 18.07 2 1.21 2 13.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1900.9 35.006 35.007 2 3.896 3.739 27.834 263.1 2 262.9 2 54.7 0.00 2 18.17 2 1.22 2 15.40 2 9 9 9 9 9 9 9 9 9 9

13 2 2100.6 35.002 35.003 2 3.663 3.491 27.857 260.9 2 260.9 2 58.7 0.00 2 18.66 2 1.26 2 18.70 2 9 9 9 9 720.4 355.4 6 2166.8 2 7.7398 2 2322 2 2320 9 9

12 2 2300.2 34.987 34.988 2 3.433 3.245 27.870 261.9 2 261.3 2 60.3 0.00 2 18.75 2 1.27 2 21.00 2 9 9 9 9 9 9 9 9 9 9

11 2 2499.4 34.972 34.972 2 3.218 3.014 27.880 260.4 2 260.3 2 63.2 0.00 2 19.15 2 1.30 2 24.30 2 9 9 9 9 9 9 9 9 9 9

10 2 2690.7 34.959 34.959 2 3.046 2.826 27.887 260.0 2 262.2 2 62.8 0.00 2 19.44 2 1.33 2 26.70 2 9 9 9 9 9 9 9 9 9 9

9 2 2903.4 34.946 34.947 2 2.897 2.658 27.893 259.9 2 260.6 2 65.8 0.01 2 19.54 2 1.34 2 28.70 2 9 9 9 9 729.4 346.1 2 2175.9 2 7.7387 2 2331 2 2329 9 9

8 2 3102.0 34.934 34.933 2 2.751 2.495 27.899 262.8 2 262.7 2 65.1 0.00 2 19.44 2 1.33 2 29.70 2 9 9 9 9 9 9 9 9 9 9

7 2 3399.7 34.920 34.920 2 2.585 2.301 27.906 265.0 2 265.2 2 64.3 0.01 2 19.34 2 1.33 2 30.90 2 9 9 9 9 9 9 9 9 9 9

6 2 3699.8 34.910 34.909 2 2.438 2.125 27.913 269.9 2 268.5 2 62.5 0.01 2 18.85 2 1.31 2 30.50 2 9 9 9 9 9 9 9 9 9 9

5 2 4000.1 34.902 34.902 2 2.351 2.007 27.919 268.7 2 271.5 2 60.5 0.01 2 18.76 2 1.30 2 30.80 2 9 9 9 9 723.3 333.8 2 9 7.7396 2 2327 2 9 9

4 2 4301.1 34.896 34.896 2 2.304 1.926 27.922 271.1 2 270.7 2 62.0 0.01 2 19.05 2 1.32 2 32.90 2 9 9 9 9 9 9 9 9 9 9

3 2 4600.9 34.886 34.887 2 2.248 1.836 27.924 268.9 2 268.0 2 65.5 0.01 2 19.54 2 1.36 2 36.80 2 9 9 9 9 9 9 9 9 9 9

2 2 5000.2 34.867 34.868 2 2.143 1.686 27.922 262.7 2 261.8 2 73.0 0.01 2 21.00 2 1.46 2 46.10 2 9 9 9 9 9 2174.4 3 9 9 9 9

1 2 5428.0 34.852 34.853 2 2.078 1.568 27.922 257.1 2 257.1 2 78.7 0.01 6 22.18 6 1.55 6 53.30 6 9 9 9 9 774.2 351.5 2 2200.5 2 7.7141 2 2349 2 2344 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

154
A5R

NOAA Ship Ronald H. Brown

STATION 86 DATE 2/15/1998 LATITUDE 24.500° N

LONGITUDE 66.933° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.6 36.502 36.502 2 24.874 24.873 24.517 211.3 2 210.6 2 -5.9 0.00 2 0.20 2 0.00 2 0.90 2 1.81 2 1.05 2 0.14 2 9 265.3 323.6 2 2018.4 6 8.1133 2 2393 2 2392 71.0 2 9

35 2 29.8 36.550 36.554 2 24.804 24.798 24.579 209.6 2 210.7 2 -5.8 0.00 2 0.20 2 0.00 2 0.80 2 9 9 9 9 9 2020.9 2 9 2397 2 71.7 2 9

34 2 79.8 36.668 36.715 2 24.712 24.695 24.703 209.8 2 210.6 2 -5.5 0.00 2 0.20 2 0.00 2 0.70 2 1.88 2 1.08 2 0.16 2 9 276.7 333.0 2 2034.5 2 8.0993 2 2406 2 2397 68.8 2 9

33 2 152.1 36.880 36.888 2 21.334 21.304 25.852 194.7 2 197.6 2 19.6 0.02 2 0.98 2 0.02 2 0.50 2 2.15 2 1.22 2 0.08 2 9 343.3 362.6 2 2088.5 2 8.0297 2 2416 2 2408 56.5 2 9

32 2 202.3 36.741 36.741 2 19.707 19.670 26.189 192.6 2 194.1 2 29.8 0.01 2 2.05 2 0.05 2 0.70 2 2.26 2 1.26 2 0.05 2 9 372.1 367.6 2 2097.1 2 8.0004 2 5 2397 51.6 2 9

31 2 224.9 36.676 36.676 2 19.133 19.092 26.291 192.0 2 193.7 2 32.7 0.01 2 2.93 2 0.09 2 0.80 2 2.28 2 1.27 2 0.02 2 9 9 2100.5 2 7.9914 2 5 2394 51.2 2 9

30 2 251.4 36.618 36.619 2 18.691 18.646 26.361 194.1 2 196.7 2 31.6 0.01 2 3.61 2 0.13 2 1.10 2 2.30 6 1.27 6 0.02 6 9 381.4 361.6 2 2099.0 2 7.9885 2 5 2390 51.4 2 9

29 2 264.8 36.599 36.599 2 18.540 18.493 26.386 196.3 2 198.3 2 30.7 0.00 2 3.81 2 0.14 2 1.00 2 2.29 2 1.26 2 0.02 2 9 9 2097.1 2 9 2408 2 48.6 2 9

28 2 302.0 36.554 36.556 2 18.233 18.180 26.432 202.1 2 201.7 2 28.7 0.01 2 4.20 2 0.17 2 1.20 2 2.32 2 1.28 2 0.02 2 9 384.6 357.9 2 2096.2 2 7.9848 2 5 2384 9 9

27 3 335.4 36.504 36.510 2 17.905 17.847 26.478 200.5 2 199.4 2 32.5 0.01 2 4.98 2 0.23 2 1.40 2 2.26 2 1.23 2 0.02 2 9 9 2101.0 2 7.9716 2 5 2381 47.1 2 9

26 2 400.1 36.344 36.347 2 16.961 16.894 26.589 183.5 2 185.5 2 50.9 0.00 2 7.81 2 0.40 2 2.20 2 2.11 2 1.12 2 0.03 2 9 446.3 394.4 6 2117.3 2 7.9322 2 2377 2 2373 9 9

25 2 449.5 36.199 36.206 2 16.092 16.019 26.683 184.3 2 181.4 2 59.3 0.00 2 9.47 2 0.51 2 2.80 2 2.01 2 1.06 2 0.02 2 9 9 2126.5 2 9 2383 2 42.6 2 9

24 2 498.8 36.012 36.017 2 14.967 14.890 26.794 178.0 2 174.2 2 72.2 0.01 2 12.01 2 0.68 2 4.00 2 1.77 2 0.93 2 0.02 2 9 519.4 423.1 2 2136.5 2 7.8684 2 2360 2 2356 9 9

23 2 548.6 35.838 35.842 2 13.880 13.800 26.895 166.3 2 163.2 2 89.0 0.00 2 14.84 2 0.86 2 5.40 2 9 9 9 9 9 2149.3 2 9 2348 2 42.4 2 9

22 2 600.2 35.675 35.679 2 12.813 12.729 26.988 158.2 2 158.8 2 99.3 0.00 2 17.09 2 1.03 2 6.80 2 1.26 2 0.65 2 0.02 2 9 629.6 469.0 2 2157.5 2 7.7904 2 2343 2 2337 9 9

21 2 698.6 35.397 35.395 2 10.745 10.658 27.163 151.5 2 149.0 2 121.1 0.00 2 21.69 2 1.34 2 10.70 2 0.68 2 0.36 2 0.02 2 9 9 2175.7 2 9 2326 2 41.4 2 9

20 2 798.6 35.161 35.174 2 8.812 8.723 27.303 142.1 2 142.2 2 140.1 0.00 2 25.50 2 1.62 2 14.90 2 0.28 2 0.16 2 0.00 2 9 861.1 543.5 2 2192.3 2 7.6715 2 2323 2 2318 9 9

19 2 850.0 35.040 35.042 2 7.920 7.831 27.344 142.1 2 141.4 2 146.9 0.00 2 27.46 2 1.77 2 17.60 2 0.20 2 0.11 2 0.00 2 9 934.4 567.8 2 2199.1 2 7.6423 2 9 2313 41.5 2 9

18 2 900.8 35.010 35.008 2 7.425 7.334 27.392 146.1 2 145.9 2 145.7 0.00 2 27.66 2 1.80 2 18.60 2 0.16 2 0.09 2 0.01 2 9 937.3 556.8 2 2201.2 2 7.6386 2 9 2314 9 9

17 2 999.0 34.934 34.941 2 6.421 6.326 27.471 160.7 2 157.7 2 141.0 0.00 2 27.75 2 1.83 2 20.30 2 0.13 2 0.07 2 0.00 2 9 962.8 547.5 2 2202.1 6 7.6303 2 9 2311 41.6 2 9

16 2 1100.3 34.996 35.004 2 6.125 6.022 27.560 177.2 2 181.2 2 119.5 0.00 2 24.92 2 1.64 2 18.00 2 0.25 2 0.13 2 0.01 2 9 864.7 482.3 2 2192.2 2 7.6648 2 2323 2 2315 9 9

15 2 1300.8 35.057 35.059 2 5.246 5.131 27.719 233.2 2 231.6 2 75.4 0.00 2 19.74 2 1.30 2 13.40 2 0.61 2 0.30 2 0.02 2 9 9 2173.1 2 7.7129 2 9 2316 42.7 2 9

14 2 1499.3 35.019 35.020 2 4.477 4.351 27.777 256.4 2 256.7 2 56.2 0.00 2 18.37 2 1.21 2 12.50 2 0.79 6 0.39 6 0.03 6 9 738.3 379.5 2 2164.8 2 7.7278 2 5 2313 9 9

13 2 1748.5 34.994 34.996 2 4.006 3.863 27.810 265.4 2 265.2 2 51.5 0.00 2 17.98 2 1.19 2 13.30 2 0.64 2 0.32 2 0.02 2 9 9 2160.8 2 7.7352 2 5 2312 44.4 3 9

12 2 2000.4 34.984 34.986 2 3.722 3.558 27.835 266.7 2 266.9 2 52.2 0.00 2 18.08 2 1.20 2 15.00 2 0.39 2 0.20 2 0.01 2 9 717.8 355.6 2 2161.7 2 7.7364 2 9 2313 9 9

11 2 2249.6 34.977 34.979 2 3.449 3.266 27.859 263.4 2 267.0 2 54.4 0.00 2 18.27 2 1.22 2 17.90 2 0.19 2 0.10 2 0.01 2 9 9 2163.7 2 7.7381 2 2318 2 2316 41.7 2 9

10 2 2499.1 34.960 34.961 2 3.193 2.990 27.872 264.1 2 268.2 2 55.5 0.00 2 18.27 2 1.22 2 19.50 2 0.20 2 0.11 2 0.01 2 9 719.2 347.1 2 2164.9 2 7.7390 2 9 2317 9 9

9 9 2747.5 34.952 2 2.997 2.772 27.887 262.4 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

8 2 2997.6 34.941 34.941 2 2.840 2.593 27.895 263.6 2 263.9 2 63.1 0.00 2 19.35 2 1.31 2 27.30 2 0.07 2 0.03 2 0.01 2 9 718.1 340.4 2 2173.0 2 7.7378 2 9 2325 9 9

7 2 3399.8 34.919 34.921 2 2.583 2.299 27.905 268.5 2 269.1 2 60.4 0.00 2 18.96 2 1.29 2 28.00 2 0.13 2 0.07 2 0.00 2 9 9 2171.5 2 9 2327 2 41.4 2 9

6 2 3798.6 34.908 34.908 2 2.417 2.094 27.915 270.6 2 271.2 2 60.0 0.00 2 18.86 2 1.29 2 29.50 2 0.14 2 0.07 2 0.00 2 9 730.8 339.0 2 2172.2 2 7.7367 2 9 2324 9 9

5 2 4196.4 34.899 34.899 2 2.328 1.962 27.921 271.2 2 271.5 2 60.9 0.00 2 18.96 2 1.30 2 31.40 2 0.12 6 0.07 6 0.01 6 9 9 2174.3 2 7.7357 2 2328 2 2326 41.5 2 9

4 2 4581.9 34.890 34.890 2 2.276 1.866 27.924 269.6 2 269.3 2 63.9 0.00 2 19.45 2 1.34 2 34.80 2 0.11 2 0.06 2 0.01 2 9 741.0 341.2 2 2178.1 2 9 9 9 9

3 2 4997.5 34.873 34.874 2 2.184 1.726 27.924 264.0 2 263.7 2 70.7 0.00 2 20.72 2 1.43 2 43.10 2 0.06 2 0.04 2 0.01 2 9 9 2187.7 2 7.7230 2 2341 2 2334 41.4 2 9

2 2 5385.6 34.855 34.856 2 2.089 1.584 27.922 257.6 2 257.8 2 77.9 0.01 2 22.09 2 1.53 2 51.70 2 0.03 2 0.03 2 0.01 2 9 782.8 356.9 2 2198.3 2 7.7142 2 9 2342 9 9

1 2 5815.6 34.847 34.847 2 2.088 1.527 27.923 254.6 2 255.7 6 80.5 0.00 6 22.67 6 1.56 6 55.30 6 0.03 2 0.02 2 0.00 2 9 792.9 360.8 6 2202.6 2 7.7085 2 2352 2 2344 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

155
A5R

NOAA Ship Ronald H. Brown

STATION 87 DATE 2/15/1998 LATITUDE 24.500° N

LONGITUDE 67.667° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.8 36.614 36.614 2 24.552 24.551 24.700 211.8 2 211.7 2 -6.0 0.00 2 0.20 2 0.01 2 1.10 2 9 9 9 9 276.9 331.2 2 2028.5 6 8.1072 2 2396 2 2395 9 9

35 2 50.4 36.638 36.639 2 24.507 24.496 24.738 209.9 2 211.5 2 -5.7 0.01 2 0.20 2 0.01 2 1.10 2 9 9 9 9 9 9 9 9 9 9

34 2 101.6 36.892 36.895 2 23.690 23.669 25.181 206.9 2 205.6 2 2.8 0.04 2 0.39 2 0.02 2 1.00 2 9 9 9 9 307.2 355.4 2 2066.5 2 8.0704 2 2412 2 2413 9 9

33 2 149.4 36.847 36.849 2 20.938 20.909 25.935 192.5 2 194.6 2 24.2 0.02 2 1.27 2 0.04 2 1.10 2 9 9 9 9 354.8 367.8 2 2098.1 2 8.0186 2 2408 2 2411 9 9

32 2 190.9 36.748 36.748 2 19.711 19.676 26.192 191.5 2 193.2 2 30.6 0.01 2 2.15 2 0.07 2 1.10 2 9 9 9 9 9 9 7.9993 2 9 9 9

31 2 212.3 36.673 36.673 2 19.105 19.067 26.294 194.5 2 194.1 2 32.4 0.01 2 3.03 2 0.11 2 1.30 2 9 9 9 9 9 9 7.9921 2 9 9 9

30 2 240.6 36.611 36.610 2 18.650 18.607 26.366 198.0 2 198.2 2 30.3 0.01 2 3.51 2 0.14 2 1.40 2 9 9 9 9 380.0 359.9 2 2103.0 2 7.9899 2 2393 2 2395 9 9

29 2 266.2 36.584 36.582 2 18.447 18.400 26.398 201.7 2 201.4 2 28.0 0.01 2 3.71 2 0.16 2 1.40 2 9 9 9 9 9 9 7.9896 2 9 9 9

28 2 290.5 36.560 36.559 2 18.267 18.216 26.427 203.2 2 203.3 2 27.0 0.01 2 4.00 2 0.18 2 1.40 2 9 9 9 9 9 9 7.9868 2 9 9 9

27 2 342.6 36.511 36.511 2 17.946 17.887 26.474 197.9 2 201.3 2 30.5 0.01 2 4.78 2 0.23 2 1.50 2 9 9 9 9 9 9 7.9780 2 9 9 9

26 2 393.6 36.412 36.413 2 17.369 17.302 26.543 186.1 2 190.6 2 43.9 0.01 2 6.73 2 0.34 2 2.10 2 9 9 9 9 424.4 381.4 2 2115.9 2 7.9497 2 2384 2 2383 9 9

25 2 432.1 36.297 36.299 2 16.697 16.625 26.617 183.3 2 184.4 2 53.3 0.01 2 8.39 2 0.45 2 2.70 2 9 9 9 9 9 9 9 9 9 9

24 2 491.6 36.092 36.092 2 15.444 15.367 26.751 175.2 2 178.4 2 65.6 0.01 2 10.84 2 0.61 2 3.80 2 9 9 9 9 9 9 7.8870 2 9 9 9

23 2 540.5 35.942 35.946 2 14.487 14.406 26.847 172.2 2 174.0 2 74.9 0.01 2 12.69 2 0.73 2 4.70 2 9 9 9 9 534.5 426.2 2 2143.6 2 7.8567 2 2367 2 2357 9 9

22 2 589.6 35.763 35.770 2 13.327 13.243 26.953 167.6 2 164.0 2 91.2 0.01 2 15.53 2 0.92 2 6.20 2 9 9 9 9 9 9 9 9 9 9

21 2 689.0 35.496 35.480 2 11.438 11.349 27.115 157.8 2 158.6 2 107.4 0.01 2 19.53 2 1.21 2 9.70 2 9 9 9 9 684.7 480.6 2 2171.4 2 7.7572 2 2336 2 2335 9 9

20 2 795.7 35.165 35.170 2 8.648 8.560 27.332 149.7 2 151.1 2 132.2 0.01 2 24.62 2 1.59 2 15.10 2 9 9 9 9 847.3 529.3 2 2190.6 2 7.6792 2 2327 2 2320 9 9

19 2 886.2 35.024 35.025 2 7.231 7.142 27.430 155.3 2 154.9 2 138.0 0.01 2 26.67 2 1.75 2 18.60 2 9 9 9 9 917.9 539.6 2 2198.0 2 7.6492 2 5 2315 9 9

18 2 982.0 35.019 35.019 2 6.492 6.398 27.528 176.0 2 175.3 2 122.7 0.01 2 25.01 2 1.66 2 18.20 2 9 9 9 9 9 2193.4 6 7.6642 2 9 2316 9 9

17 2 1100.2 35.057 35.057 2 5.795 5.695 27.649 208.2 2 208.9 2 94.0 0.01 2 21.59 2 1.42 2 15.40 2 9 9 9 9 9 9 7.6975 2 9 9 9

16 2 1300.7 35.049 35.050 2 4.910 4.799 27.751 245.6 2 244.6 2 64.9 0.01 2 18.95 2 1.25 2 13.10 2 9 9 9 9 753.6 394.4 2 2167.4 2 7.7232 2 5 2313 9 9

15 2 1500.7 35.011 35.010 2 4.313 4.189 27.788 260.6 2 259.6 2 54.6 0.01 2 18.17 2 1.20 2 13.10 2 9 9 9 9 9 9 7.7290 2 9 9 9

14 2 1699.9 34.988 34.989 2 3.947 3.809 27.810 266.4 2 266.7 2 50.4 0.01 2 17.88 2 1.19 2 13.80 2 9 9 9 9 9 9 7.7353 2 9 9 9

13 2 1886.8 34.984 34.984 2 3.741 3.588 27.831 266.8 2 267.5 2 51.4 0.01 2 17.88 2 1.20 2 15.10 2 9 9 9 9 717.9 354.1 2 9 7.7364 2 9 9 9

12 2 2099.4 34.976 34.976 2 3.521 3.351 27.849 268.0 2 268.6 2 52.2 0.01 2 17.78 2 1.21 2 16.80 2 9 9 9 9 9 2159.8 2 7.7393 2 9 2312 9 9

11 2 2300.3 34.971 34.970 2 3.346 3.159 27.864 266.4 2 267.9 2 54.4 0.01 2 18.17 2 1.22 2 18.90 2 9 9 9 9 9 9 7.7402 2 9 9 9

10 2 2499.3 34.967 34.967 2 3.199 2.995 27.877 263.0 2 264.8 2 58.8 0.01 2 18.66 2 1.26 2 22.30 2 9 9 9 9 9 9 7.7399 2 9 9 9

9 2 2700.5 34.950 34.951 2 2.990 2.770 27.886 264.6 2 266.0 2 59.5 0.01 2 18.76 2 1.27 2 24.20 2 9 9 9 9 9 9 7.7394 2 9 9 9

8 2 2949.8 34.938 34.940 2 2.814 2.572 27.895 261.3 2 263.0 2 64.2 0.01 2 19.44 2 1.33 2 29.40 2 9 9 9 9 723.7 340.6 2 2174.2 2 7.7381 2 2337 3 2327 9 9

7 2 3299.7 34.923 34.923 2 2.619 2.345 27.904 267.2 2 268.1 2 61.0 0.01 2 19.05 2 1.30 2 29.10 2 9 9 9 9 9 9 9 9 9 9

6 2 3700.8 34.908 34.908 2 2.418 2.106 27.914 270.3 2 272.0 6 59.1 0.01 2 18.66 2 1.28 2 29.50 2 9 9 9 9 9 9 7.7379 2 9 9 9

5 2 4099.6 34.899 34.900 2 2.322 1.967 27.920 273.0 2 273.3 2 59.0 0.01 2 18.17 2 1.27 2 30.20 2 9 9 9 9 736.7 338.3 2 2170.6 2 7.7355 2 9 2322 9 9

4 2 4497.5 34.892 34.892 2 2.285 1.885 27.924 270.9 2 271.3 2 61.7 0.01 2 18.86 2 1.30 2 32.80 2 9 9 9 9 9 2176.1 2 7.7324 2 5 2326 9 9

3 2 4901.2 34.877 34.876 2 2.204 1.757 27.924 265.1 2 265.0 2 69.2 0.01 2 20.42 2 1.41 2 41.80 2 9 9 9 9 9 9 9 9 9 9

2 2 5290.7 34.852 34.853 2 2.051 1.560 27.921 255.4 2 257.4 2 78.5 0.01 2 22.18 2 1.54 2 53.50 2 9 9 9 9 784.6 356.1 6 2199.2 2 7.7120 2 9 2342 9 9

1 2 5803.0 34.845 34.846 2 2.074 1.515 27.923 253.5 2 256.1 2 80.2 0.01 6 22.57 6 1.58 6 56.20 6 9 9 9 9 784.9 356.2 2 2202.3 2 7.7085 2 2351 2 2344 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

156
A5R

NOAA Ship Ronald H. Brown

STATION 88 DATE 2/15/1998 LATITUDE 24.500° N

LONGITUDE 68.401° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.9 36.648 36.657 2 24.298 24.297 24.802 207.9 2 211.7 2 -5.2 0.00 2 0.29 2 0.01 2 1.00 2 1.87 2 1.08 2 0.15 2 1.90 2 275.1 325.9 6 2032.7 6 8.1039 6 5 2398 71.0 2 9

35 2 35.9 36.646 36.648 2 24.316 24.308 24.800 210.8 2 211.7 2 -5.2 0.00 2 0.29 2 0.01 2 1.00 2 9 9 9 9 9 9 9 9 71.3 2 9

34 2 70.1 36.657 36.659 2 24.067 24.052 24.887 210.0 2 212.9 2 -5.5 0.00 2 0.29 2 0.01 2 0.90 2 1.91 2 1.10 2 0.17 2 9 9 9 9 9 68.1 2 9

33 2 110.5 37.010 37.018 2 22.788 22.765 25.535 191.5 2 188.0 2 23.5 0.03 2 1.95 2 0.08 2 1.00 2 2.02 2 1.15 2 0.09 2 0.46 6 9 9 9 9 59.2 2 9

32 2 162.9 36.888 36.885 2 20.530 20.499 26.078 179.4 2 179.1 2 41.2 0.01 2 3.32 2 0.13 2 1.20 2 2.15 2 1.20 2 0.04 2 9 9 9 9 9 52.9 2 9

31 2 196.1 36.722 36.716 2 19.363 19.327 26.264 183.3 2 184.1 2 41.2 0.01 2 3.90 2 0.16 2 1.40 2 2.22 6 1.22 6 0.03 6 9 9 9 9 9 50.3 2 9

30 2 225.3 36.646 36.640 2 18.781 18.741 26.358 182.8 2 185.8 2 42.1 0.01 2 4.68 2 0.21 2 1.60 2 9 9 9 9 9 9 9 9 47.9 2 9

29 2 250.8 36.593 36.589 2 18.400 18.356 26.416 187.8 2 185.9 2 43.7 0.01 2 5.56 2 0.26 2 1.70 2 2.24 2 1.22 2 0.02 2 0.36 2 9 9 9 9 9 9

28 2 275.8 36.541 36.542 2 18.097 18.049 26.453 194.8 2 195.3 2 35.7 0.01 2 5.07 2 0.24 2 1.70 2 9 9 9 9 9 9 9 9 9 9

27 2 302.4 36.496 36.496 2 17.845 17.793 26.484 190.2 2 195.4 2 36.8 0.01 2 5.56 2 0.27 2 1.80 2 2.24 2 1.22 2 0.03 2 9 9 9 9 9 45.6 2 9

26 2 350.4 36.328 36.327 2 16.861 16.803 26.596 181.4 2 179.2 2 57.7 0.01 2 8.59 2 0.46 2 2.70 2 9 9 9 9 9 9 9 9 9 9

25 2 399.9 36.133 36.140 2 15.704 15.641 26.717 176.2 2 173.7 2 68.9 0.00 2 10.83 2 0.61 2 3.60 2 1.93 2 1.02 2 0.02 2 0.38 2 9 9 9 9 45.0 2 9

24 2 451.3 35.942 35.942 2 14.617 14.549 26.813 154.4 2 158.7 6 89.5 0.01 2 14.25 2 0.84 2 5.20 2 9 9 9 9 9 9 9 9 9 9

23 2 500.9 35.851 35.850 2 13.856 13.783 26.907 174.0 2 175.2 2 77.1 0.00 2 13.57 2 0.79 2 5.20 2 1.67 2 0.87 2 0.03 2 9 9 9 9 9 43.9 2 9

22 2 600.0 35.531 35.538 2 11.703 11.624 27.089 157.1 2 157.1 2 107.3 0.00 2 18.84 2 1.16 2 8.80 2 1.01 2 0.52 2 0.02 2 9 9 9 9 9 9 9

21 2 694.6 35.307 35.307 2 10.001 9.918 27.220 149.1 2 147.9 2 126.8 0.00 2 22.75 2 1.45 2 12.50 2 9 9 9 9 9 9 9 9 41.7 2 9

20 2 800.0 35.111 35.109 2 8.155 8.070 27.364 149.7 2 150.8 2 135.8 0.01 2 25.59 2 1.67 2 16.40 2 0.28 2 0.15 2 0.01 2 0.22 2 9 9 9 9 9 9

19 2 900.1 35.074 35.075 2 6.986 6.897 27.504 172.0 2 173.1 2 121.4 0.01 2 24.22 2 1.59 2 16.40 2 0.33 2 0.17 2 0.01 2 9 9 9 9 9 41.4 2 9

18 2 1000.2 35.081 35.080 2 6.069 5.977 27.631 203.8 2 204.6 2 96.2 0.00 2 21.58 2 1.43 2 14.70 2 0.48 2 0.24 2 0.01 2 9 9 9 9 9 9 9

17 2 1200.0 35.045 35.046 2 4.888 4.786 27.747 244.1 2 243.3 2 66.3 0.00 2 18.85 2 1.26 2 13.10 2 0.71 6 0.35 6 0.02 6 9 9 9 9 9 41.6 2 9

16 2 1400.1 35.005 35.006 2 4.268 4.154 27.786 260.8 2 260.2 2 54.2 0.00 2 18.16 2 1.21 2 12.80 2 0.80 2 0.39 2 0.03 2 9 9 9 9 9 9 9

15 2 1601.6 34.984 34.984 2 3.934 3.805 27.807 266.6 2 266.8 2 50.4 0.00 2 17.87 2 1.19 2 13.40 2 0.75 2 0.37 2 0.02 2 1.45 2 9 9 9 9 9 9

14 2 1800.0 34.981 34.981 2 3.720 3.576 27.828 267.7 2 267.7 2 51.3 0.00 2 17.87 2 1.20 2 14.70 2 9 9 9 9 9 9 9 9 9 9

13 2 2001.9 34.976 34.977 2 3.539 3.378 27.846 267.3 2 267.5 2 53.1 0.00 2 17.87 2 1.21 2 16.30 2 0.34 2 0.17 2 0.01 2 9 9 9 9 9 9 9

12 2 2201.2 34.965 34.966 2 3.305 3.129 27.861 267.3 2 268.3 2 54.3 0.00 2 17.87 2 1.22 2 18.10 2 0.27 2 0.14 2 0.01 2 9 9 9 9 9 9 9

11 2 2400.4 34.971 34.970 2 3.208 3.014 27.878 260.6 2 261.1 2 62.4 0.00 2 19.04 2 1.29 2 23.30 2 0.05 2 0.03 2 0.01 2 0.37 2 9 9 9 9 42.7 2 9

10 2 2598.9 34.952 34.952 2 2.999 2.789 27.884 264.9 2 264.9 2 60.5 0.00 2 18.75 2 1.27 2 23.40 2 0.13 2 0.07 2 0.01 2 9 9 9 9 9 9 9

9 2 2797.6 34.936 34.937 2 2.833 2.607 27.889 270.0 2 271.3 2 55.6 0.00 2 18.07 2 1.23 2 21.60 2 0.31 2 0.16 2 0.01 2 9 9 9 9 9 9 9

8 2 3001.2 34.930 34.931 2 2.724 2.479 27.896 268.2 2 268.5 2 59.5 0.01 2 18.56 2 1.27 2 25.00 2 0.20 2 0.10 2 0.01 2 0.56 2 9 9 9 9 9 9

7 2 3401.3 34.915 34.915 2 2.508 2.226 27.907 270.9 2 272.4 2 57.7 0.01 2 18.26 2 1.25 2 25.90 2 0.31 2 0.16 2 0.02 2 0.74 2 9 9 9 9 9 9

6 2 3800.6 34.904 34.904 2 2.363 2.041 27.916 271.3 2 272.5 2 59.2 0.00 2 18.46 2 1.27 2 28.50 2 0.22 2 0.11 2 0.01 2 0.68 2 9 9 9 9 9 9

5 2 4199.4 34.897 34.896 2 2.297 1.931 27.922 271.6 2 271.5 2 61.1 0.01 2 18.75 2 1.29 2 30.90 2 0.18 2 0.10 2 0.01 2 0.64 2 9 9 9 9 9 9

4 2 4600.7 34.888 34.888 2 2.256 1.844 27.924 268.6 2 268.0 2 65.4 0.01 2 19.44 2 1.34 2 35.50 2 0.14 2 0.08 2 0.01 2 0.53 6 9 9 9 9 9 9

3 2 5001.6 34.868 34.869 2 2.154 1.696 27.922 261.6 2 262.1 2 72.6 0.01 2 21.00 2 1.46 2 45.20 2 0.03 2 0.02 2 0.01 2 0.28 2 9 9 9 9 9 9

2 2 5400.5 34.850 34.851 2 2.055 1.550 27.921 254.9 2 255.7 2 80.3 0.01 2 22.27 2 1.55 2 53.90 2 0.03 2 0.03 2 0.01 2 0.18 2 9 9 9 9 9 9

1 2 5813.6 34.845 34.846 2 2.071 1.511 27.923 253.0 2 254.3 2 82.0 0.01 6 22.76 6 1.59 6 56.20 6 0.06 3 0.04 3 0.01 3 0.18 2 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

157
A5R

NOAA Ship Ronald H. Brown

STATION 89 DATE 2/16/1998 LATITUDE 24.500° N

LONGITUDE 69.133° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.9 36.530 36.530 2 24.785 24.784 24.566 210.8 2 209.2 2 -4.2 0.00 2 0.10 2 0.00 2 1.10 2 9 9 9 9 268.8 324.5 2 2020.7 2 8.1044 2 2386 2 2383 9 9

35 2 55.9 36.593 36.608 2 24.802 24.790 24.615 207.9 2 209.0 2 -4.1 0.00 2 0.10 2 0.01 2 1.10 2 9 9 9 9 9 9 9 9 9 9

34 2 87.8 36.943 36.967 2 24.016 23.997 25.121 202.9 2 199.0 2 8.2 0.08 2 0.49 2 0.02 2 0.90 2 9 9 9 9 310.3 363.2 2 2074.8 2 8.0577 2 2413 2 2413 9 9

33 2 128.9 36.972 36.959 2 22.231 22.205 25.668 179.0 2 178.4 2 35.3 0.02 2 2.93 2 0.14 2 1.30 2 9 9 9 9 365.9 399.3 2 2108.0 3 8.0050 2 2414 2 2414 9 9

32 2 169.3 36.852 36.853 2 20.467 20.435 26.069 167.0 2 184.8 3 35.8 0.01 2 2.44 2 0.09 2 1.10 2 9 9 9 9 9 9 9 9 9 9

31 2 200.5 36.696 36.708 2 19.351 19.314 26.247 182.8 2 168.6 2 56.8 0.01 2 5.76 2 0.28 2 1.90 2 9 9 9 9 431.7 420.7 2 2128.1 3 7.9466 2 2397 2 2396 9 9

30 2 225.1 36.633 36.632 2 18.719 18.679 26.363 185.7 2 187.0 2 41.2 0.01 2 4.49 2 0.19 2 1.50 2 9 9 9 9 9 9 9 9 9 9

29 2 249.4 36.574 36.577 2 18.353 18.309 26.413 183.7 2 200.7 2 29.1 0.01 2 3.80 2 0.16 2 1.30 2 9 9 9 9 9 9 4 2385 2 9 9

28 2 274.1 36.533 36.529 2 18.070 18.022 26.454 188.6 2 200.8 2 30.3 0.01 2 4.59 2 0.21 2 1.60 2 9 9 9 9 389.6 360.2 2 2102.1 2 9 9 9 9

27 2 299.6 36.483 36.488 2 17.771 17.719 26.492 186.0 2 188.0 2 44.5 0.01 2 6.24 2 0.31 2 2.00 2 9 9 9 9 9 9 9 9 9 9

26 2 349.8 36.321 36.315 2 16.803 16.745 26.604 174.8 2 182.7 2 54.5 0.01 2 8.29 2 0.44 2 2.60 2 9 9 9 9 9 9 9 9 9 9

25 2 400.0 36.157 36.157 2 15.871 15.807 26.698 168.3 2 172.7 2 69.1 0.01 2 10.73 2 0.61 2 3.60 2 9 9 9 9 9 9 9 9 9 9

24 2 450.0 36.008 36.013 2 14.938 14.869 26.794 169.7 2 172.8 2 73.7 0.01 2 12.00 2 0.69 2 4.30 2 9 9 9 9 529.4 430.7 2 2139.7 2 7.8650 2 2356 2 2357 9 9

23 2 499.8 35.852 35.858 2 13.929 13.856 26.892 171.0 2 170.1 2 81.8 0.00 2 13.86 2 0.82 2 5.40 2 9 9 9 9 9 9 9 9 9 9

22 2 600.7 35.487 35.490 2 11.505 11.427 27.091 146.8 2 147.4 2 118.1 0.01 2 20.41 2 1.26 2 9.50 2 9 9 9 9 9 9 9 9 9 9

21 2 650.6 35.361 35.366 2 10.649 10.568 27.149 142.9 2 141.7 2 129.0 0.01 2 22.65 2 1.41 2 11.30 2 9 9 9 9 778.6 530.3 2 2179.9 2 7.7101 2 2328 2 2323 9 9

20 2 699.2 35.246 35.241 2 9.724 9.642 27.219 138.0 2 139.2 2 137.3 0.01 2 24.51 2 1.56 2 13.60 2 9 9 9 9 9 9 9 9 9 9

19 2 798.9 35.166 35.170 2 8.359 8.273 27.376 158.0 2 158.1 2 127.1 0.01 2 23.93 2 1.55 2 14.70 2 9 9 9 9 839.8 518.1 2 2186.5 2 7.6856 2 2321 2 2318 9 9

18 2 892.3 35.090 35.093 2 7.158 7.069 27.493 173.3 2 171.7 2 121.5 0.00 2 23.93 2 1.58 2 16.00 2 9 9 9 9 848.8 496.4 2 2186.9 2 7.6771 2 2320 2 2315 9 9

17 2 1001.0 35.074 35.074 2 6.004 5.912 27.634 203.0 2 205.2 2 96.1 0.00 2 21.58 2 1.43 2 14.90 2 9 9 9 9 800.7 443.2 2 2179.8 6 7.6905 2 2320 2 2313 9 9

16 2 1145.2 35.081 35.077 2 5.284 5.184 27.730 233.2 2 231.8 2 74.7 0.01 2 19.63 2 1.30 2 13.70 2 9 9 9 9 9 9 9 9 9 9

15 2 1350.5 35.055 35.055 2 4.622 4.509 27.787 250.9 2 250.1 2 61.5 0.00 2 18.56 2 1.24 2 13.60 2 9 9 9 9 732.5 379.0 2 2162.6 2 7.7315 2 2318 2 2312 9 9

14 2 1531.5 34.994 34.996 2 4.003 3.880 27.807 262.1 2 264.7 2 51.9 0.00 2 17.87 2 1.20 2 13.60 2 9 9 9 9 9 9 9 9 9 9

13 2 1698.7 34.982 34.983 2 3.778 3.642 27.823 267.6 2 267.3 2 51.2 0.00 2 17.78 2 1.20 2 14.40 2 9 9 9 9 9 9 9 9 9 9

12 2 1950.0 34.975 34.976 2 3.529 3.373 27.845 267.1 2 267.7 2 52.9 0.00 2 17.87 2 1.21 2 16.40 2 9 9 9 9 722.2 354.4 2 2158.3 2 7.7387 2 2315 2 2310 9 9

11 2 2198.4 34.968 34.968 2 3.315 3.139 27.863 266.9 2 267.5 2 55.0 0.00 2 18.07 2 1.22 2 18.50 2 9 9 9 9 9 9 9 9 9 9

10 2 2440.3 34.965 34.964 2 3.143 2.946 27.880 261.5 2 262.0 2 62.1 0.00 2 18.85 2 1.29 2 23.70 2 9 9 9 9 9 9 9 9 9 9

9 2 2701.0 34.944 34.945 2 2.914 2.696 27.887 267.4 2 267.9 2 58.2 0.00 2 18.36 2 1.25 2 22.90 2 9 9 9 9 728.3 346.5 2 2165.2 2 7.7395 2 9 2318 9 9

8 2 3000.1 34.928 34.928 2 2.700 2.456 27.897 273.0 2 273.1 2 55.0 0.01 2 17.78 2 1.22 2 22.20 2 9 9 9 9 9 9 9 9 9 9

7 2 3296.6 34.918 34.917 2 2.533 2.262 27.906 274.8 2 274.3 2 55.5 0.01 2 17.78 2 1.22 2 23.40 2 9 9 9 9 9 9 9 9 9 9

6 2 3592.8 34.908 34.910 2 2.417 2.117 27.912 274.7 2 274.3 2 56.7 0.01 2 17.87 2 1.23 2 25.60 2 9 9 9 9 9 9 9 9 9 9

5 2 3999.6 34.901 34.901 2 2.330 1.986 27.919 274.4 2 274.3 2 57.8 0.01 2 18.17 2 1.25 2 27.50 2 9 9 9 9 733.2 338.7 2 2169.0 2 7.7339 2 2323 2 2319 9 9

4 2 4397.4 34.894 34.894 2 2.296 1.907 27.923 272.7 2 272.0 2 60.8 0.01 2 18.56 2 1.28 2 30.60 2 9 9 9 9 9 9 9 9 9 9

3 2 4798.3 34.888 34.888 2 2.282 1.845 27.926 269.9 2 269.1 2 64.3 0.00 2 19.15 2 1.33 2 34.30 2 9 9 9 9 9 9 9 9 9 9

2 2 5197.3 34.870 34.871 2 2.194 1.710 27.925 262.9 2 262.6 2 72.0 0.01 2 20.71 2 1.44 2 43.80 2 9 9 9 9 9 9 9 9 9 9

1 2 5735.8 34.846 34.847 2 2.065 1.515 27.923 253.0 2 254.9 6 81.4 0.01 6 22.66 2 1.58 6 56.00 6 9 9 9 9 789.8 358.6 6 2202.1 2 7.7079 2 2348 2 2343 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

158
A5R

NOAA Ship Ronald H. Brown

STATION 90 DATE 2/16/1998 LATITUDE 25.016° N

LONGITUDE 69.502° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.5 36.723 36.722 2 23.980 23.979 24.955 216.3 2 213.5 2 -6.0 0.00 2 0.10 2 0.00 2 0.80 2 1.88 2 1.08 2 0.15 2 9 278.5 325.9 2 2037.9 6 8.1080 2 5 2407 69.1 2 9

35 2 51.4 36.717 36.717 2 23.729 23.718 25.031 212.5 2 211.0 2 -2.5 0.00 2 0.10 2 0.00 2 0.80 2 1.91 2 1.11 2 0.15 2 9 275.4 319.2 2 2039.6 2 9 2398 2 70.1 2 9

34 2 99.4 36.698 36.704 2 23.463 23.442 25.101 213.4 2 213.2 2 -3.7 0.00 2 0.10 2 0.01 2 0.80 2 1.93 2 1.11 2 0.17 2 9 276.3 316.9 2 2038.6 2 8.1037 2 5 2404 67.0 2 9

33 2 150.8 36.911 36.908 2 21.851 21.821 25.731 203.3 2 202.5 2 12.7 0.04 2 0.49 2 0.02 2 0.50 2 2.14 2 1.21 2 0.13 2 9 331.9 357.3 2 2085.9 2 8.0439 2 5 2415 53.2 2 9

32 2 199.6 36.714 36.712 2 19.532 19.495 26.214 197.4 2 200.5 2 24.1 0.01 2 1.46 2 0.04 2 0.70 2 2.29 2 1.28 2 0.08 2 9 366.9 360.1 2 2098.6 2 8.0085 2 2399 2 2403 49.8 2 9

31 2 224.8 36.660 36.656 2 19.053 19.012 26.299 193.9 2 201.8 2 24.9 0.01 2 2.15 2 0.07 2 0.80 2 2.30 2 1.28 2 0.05 2 9 371.9 357.9 2 2098.5 2 8.0041 2 9 2400 48.1 2 9

30 2 249.4 36.605 36.601 2 18.638 18.594 26.365 195.8 2 203.0 2 25.6 0.01 2 3.02 2 0.12 2 1.00 2 2.34 2 1.30 2 0.04 2 9 377.6 357.4 2 2098.7 2 7.9979 2 5 2396 46.8 2 9

29 2 272.3 36.586 36.584 2 18.442 18.394 26.402 201.9 2 199.6 2 29.8 0.01 2 3.71 2 0.15 2 1.10 2 2.35 2 1.30 2 0.03 2 9 9 2102.9 2 7.9879 2 9 2394 46.9 2 9

28 2 298.1 36.558 36.560 2 18.225 18.173 26.437 206.6 2 199.3 2 31.1 0.01 2 4.20 2 0.19 2 1.20 2 2.32 2 1.27 2 0.03 2 9 389.3 362.3 2 2103.6 2 7.9796 2 2398 2 2389 9 9

27 2 350.9 36.489 36.486 2 17.786 17.725 26.497 205.8 2 197.6 2 34.9 0.00 2 5.27 2 0.25 2 1.60 2 2.25 2 1.22 2 0.02 2 9 9 2108.1 2 7.9702 2 2396 2 2387 43.6 2 9

26 2 399.4 36.369 36.367 2 17.096 17.029 26.576 198.0 2 190.9 2 44.9 0.00 2 6.93 2 0.36 2 2.00 2 2.18 2 1.16 2 0.03 2 9 437.4 389.0 2 2117.3 2 7.9443 2 5 2381 9 9

25 2 450.5 36.197 36.189 2 16.112 16.039 26.677 189.2 2 185.3 2 55.3 0.00 2 9.08 2 0.50 2 2.90 2 2.05 2 1.08 2 0.02 2 9 9 2126.8 2 9 2388 2 43.3 2 9

24 2 501.3 36.022 36.017 2 15.017 14.940 26.791 184.8 2 178.7 2 67.5 0.00 2 11.32 2 0.65 2 3.90 2 1.90 2 0.98 2 0.03 2 9 511.2 417.3 2 2136.3 2 7.8771 2 2371 2 2360 9 9

23 2 550.5 35.815 35.822 2 13.634 13.554 26.928 179.5 2 173.8 2 79.7 0.00 2 13.96 2 0.82 2 5.30 2 1.61 2 0.83 2 0.02 2 9 9 2148.4 2 7.8377 2 2349 2 2351 42.1 2 9

22 2 604.6 35.602 35.595 2 12.361 12.279 27.019 171.2 2 147.0 2 113.6 0.00 2 19.04 2 1.15 2 8.00 2 1.09 2 0.56 2 0.01 2 9 688.0 503.4 2 2172.3 2 7.7628 2 2347 2 2339 9 9

21 2 650.1 35.483 35.481 2 11.492 11.407 27.093 149.9 2 146.0 2 119.7 0.00 2 20.60 2 1.27 2 9.50 2 0.85 2 0.44 2 0.01 2 9 9 2176.7 2 9 9 41.9 2 9

20 2 691.6 35.411 35.413 2 10.962 10.875 27.135 147.6 2 144.0 2 124.8 0.00 2 21.68 2 1.35 2 10.50 2 0.71 6 0.36 6 0.01 6 9 747.4 515.3 2 2179.2 2 7.7262 2 2332 2 2329 9 9

19 2 750.3 35.328 35.327 2 10.050 9.960 27.231 153.2 2 149.6 2 124.8 0.01 2 22.56 2 1.42 2 12.10 2 0.54 2 0.28 2 0.01 4 9 776.9 515.4 2 2182.5 2 7.7138 2 2328 2 2327 42.4 2 9

18 2 848.8 35.103 35.104 2 8.093 8.003 27.368 148.8 2 149.6 2 137.4 0.01 2 25.78 2 1.67 2 16.40 2 0.29 2 0.15 2 0.01 2 9 880.0 537.3 2 2195.9 2 7.6653 2 9 2320 9 9

17 2 899.8 35.082 35.086 2 7.400 7.309 27.453 163.3 2 163.1 2 128.5 0.01 2 24.81 2 1.63 2 16.40 2 0.32 2 0.16 2 0.01 2 9 872.1 516.0 2 2192.6 2 7.6706 2 2324 2 2318 41.0 2 9

16 2 1001.2 35.075 35.076 2 6.430 6.335 27.581 190.9 2 190.8 2 107.5 0.01 2 22.85 2 1.50 2 15.50 2 0.38 2 0.20 2 0.01 2 9 826.7 467.2 2 2186.1 6 7.6890 2 2321 2 2319 9 9

15 2 1197.7 35.071 35.072 2 5.224 5.119 27.730 233.7 2 232.5 6 74.5 0.01 2 19.63 2 1.30 2 13.50 2 0.53 2 0.26 2 0.02 2 9 9 2171.9 2 7.7171 2 2318 2 2316 41.4 2 9

14 2 1400.6 35.043 35.043 2 4.569 4.452 27.785 253.5 2 251.5 2 60.6 0.01 2 18.56 2 1.23 2 13.30 2 0.56 2 0.28 2 0.02 2 9 737.4 380.7 2 2165.8 2 7.7314 2 2315 2 2315 9 9

13 2 1593.3 35.039 35.040 2 4.260 4.128 27.818 256.0 2 255.4 2 59.2 0.01 2 18.56 2 1.23 2 14.80 2 0.25 2 0.13 2 0.01 2 9 9 2165.1 2 7.7373 2 2318 2 2317 41.5 2 9

12 2 1798.2 35.020 35.020 2 3.885 3.738 27.844 258.1 2 257.4 2 60.2 0.00 2 18.56 2 1.25 2 17.20 2 0.09 2 0.05 2 0.00 2 9 721.4 359.9 2 2166.4 2 7.7397 2 9 2320 9 9

11 2 1952.3 34.994 34.995 2 3.596 3.439 27.854 261.4 2 261.5 2 58.5 0.00 2 18.56 2 1.24 2 18.30 2 0.12 2 0.07 2 0.01 2 9 9 2165.8 2 7.7393 2 2322 2 2319 41.3 2 9

10 2 2249.5 34.977 34.977 2 3.291 3.110 27.873 260.3 2 262.5 2 60.2 0.01 2 18.95 2 1.28 2 22.20 2 0.06 2 0.03 2 0.01 2 9 716.6 346.9 2 2169.8 2 7.7400 2 2331 2 2323 9 9

9 2 2552.8 34.956 34.958 2 3.025 2.819 27.885 259.3 2 260.0 2 65.1 0.01 2 19.44 2 1.31 2 26.30 2 0.03 2 0.02 2 0.00 2 9 9 2174.4 2 7.7392 2 9 2328 41.5 2 9

8 2 2842.4 34.939 34.941 2 2.832 2.601 27.892 263.9 2 262.6 2 64.3 0.01 2 19.24 2 1.31 2 27.30 2 0.10 2 0.08 2 0.01 2 0.32 2 721.1 341.0 2 2173.2 2 7.7387 2 9 2326 9 9

7 2 3246.7 34.920 34.920 2 2.571 2.304 27.905 268.5 2 267.8 2 61.6 0.01 2 18.85 2 1.28 2 27.70 2 0.15 6 0.08 6 0.01 6 9 721.8 337.1 2 2172.3 2 9 2340 3 41.2 2 9

6 2 3634.8 34.908 34.908 2 2.398 2.093 27.914 275.0 2 273.2 2 58.0 0.01 2 18.07 2 1.24 2 26.30 2 0.39 2 0.19 2 0.02 2 0.91 2 729.9 338.3 2 2169.6 2 7.7351 2 9 2321 9 9

5 2 4047.9 34.899 34.900 2 2.321 1.972 27.919 272.8 2 271.9 2 60.4 0.01 2 18.36 2 1.26 2 29.00 2 0.33 2 0.17 2 0.02 2 0.84 2 727.5 335.7 2 2172.9 2 7.7346 2 5 2324 41.4 2 9

4 2 4450.2 34.894 34.893 2 2.295 1.900 27.924 271.6 2 271.0 2 61.9 0.01 2 18.66 2 1.28 2 31.40 2 0.36 2 0.18 2 0.02 2 0.87 6 740.8 341.4 6 2175.7 2 9 9 9 9

3 2 4849.8 34.886 34.887 2 2.273 1.830 27.926 268.8 2 267.0 2 66.5 0.01 2 19.54 2 1.34 2 36.10 2 0.20 2 0.11 2 0.02 2 0.61 2 738.0 339.2 2 2182.2 2 7.7297 2 2339 2 2332 41.5 2 9

2 3 5248.8 34.869 34.871 2 2.194 1.703 27.925 263.6 2 261.5 2 73.1 0.01 2 20.90 2 1.44 2 44.50 2 0.12 2 0.07 2 0.02 2 0.40 2 754.2 344.8 2 2191.0 2 7.7222 2 9 2338 9 9

1 2 5708.1 34.845 34.846 2 2.064 1.518 27.921 254.0 2 252.5 2 83.8 0.01 6 22.86 6 1.58 6 56.20 6 0.02 2 0.02 2 0.01 2 0.18 2 795.8 361.4 2 2204.3 2 7.7086 2 2348 2 2346 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

159
A5R

NOAA Ship Ronald H. Brown

STATION 91 DATE 2/16/1998 LATITUDE 25.383° N

LONGITUDE 69.867° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.5 36.727 36.727 2 23.904 23.903 24.980 215.5 2 212.6 2 -4.8 0.00 2 0.10 2 0.00 2 0.60 2 9 9 9 9 283.8 331.0 6 2038.1 6 8.1051 6 2404 6 2405 9 9

35 2 60.4 36.722 36.724 2 23.630 23.617 25.065 212.9 2 213.0 2 -4.2 0.00 2 0.10 2 0.01 2 0.60 2 9 9 9 9 9 9 9 9 9 9

34 2 91.0 36.720 36.720 2 23.497 23.478 25.106 213.6 2 213.4 2 -4.1 0.00 2 0.10 2 0.01 2 0.60 2 9 9 9 9 9 9 9 9 9 9

33 2 130.3 36.737 36.748 2 22.956 22.929 25.282 200.4 2 214.4 3 -3.1 0.01 2 0.10 2 0.01 2 0.50 2 9 9 9 9 9 9 9 9 9 9

32 2 170.2 36.923 36.903 2 21.561 21.527 25.823 204.5 2 207.0 2 9.3 0.03 2 0.49 2 0.02 2 0.40 2 9 9 9 9 9 9 9 9 9 9

31 2 201.6 36.764 36.754 2 19.769 19.732 26.191 198.0 2 196.4 2 27.2 0.01 2 1.66 2 0.05 2 0.60 2 9 9 9 9 9 9 9 9 9 9

30 2 226.1 36.679 36.666 2 19.168 19.127 26.284 196.9 2 198.6 2 27.6 0.01 2 2.34 2 0.07 2 0.70 2 9 9 9 9 9 9 9 9 9 9

29 2 249.5 36.612 36.611 2 18.688 18.644 26.358 200.6 2 202.8 2 25.5 0.01 2 2.83 2 0.11 2 0.80 2 9 9 9 9 9 9 9 9 9 9

28 2 270.3 36.579 36.579 2 18.431 18.383 26.399 202.4 2 204.7 2 24.8 0.01 2 3.41 2 0.14 2 1.00 2 9 9 9 9 9 9 9 9 9 9

27 2 299.6 36.553 36.554 2 18.169 18.117 26.447 206.7 2 209.8 2 20.9 0.01 2 3.51 2 0.15 2 1.10 2 9 9 9 9 9 9 9 9 9 9

26 2 350.6 36.520 36.520 2 17.946 17.885 26.481 211.7 2 208.7 6 23.0 0.01 2 4.00 2 0.19 2 1.20 2 9 9 9 9 9 9 9 9 9 9

25 2 400.3 36.440 36.437 2 17.510 17.442 26.531 206.7 2 198.6 2 35.2 0.01 2 5.76 2 0.29 2 1.70 2 9 9 9 9 9 9 9 9 9 9

24 2 493.4 36.169 36.161 2 15.927 15.848 26.701 186.9 2 177.0 2 64.6 0.01 2 10.25 2 0.57 2 3.20 2 9 9 9 9 9 9 9 9 9 9

23 2 600.5 35.764 35.771 2 13.460 13.374 26.927 154.7 2 152.5 2 102.0 0.01 2 16.40 2 0.98 2 6.10 2 9 9 9 9 9 9 9 9 9 9

22 2 700.8 35.557 35.560 2 11.758 11.665 27.104 164.7 2 162.6 2 101.5 0.01 2 18.16 2 1.11 2 8.00 2 9 9 9 9 9 9 9 9 9 9

21 2 800.0 35.296 35.297 2 9.849 9.754 27.242 153.8 2 151.5 2 124.2 0.01 2 22.66 2 1.44 2 12.20 2 9 9 9 9 9 9 9 9 9 9

20 2 900.3 35.145 35.149 2 8.047 7.951 27.410 162.1 2 161.3 2 126.0 0.01 2 24.03 2 1.56 2 14.70 2 9 9 9 9 9 9 9 9 9 9

19 2 995.4 35.057 35.056 2 6.753 6.656 27.524 173.3 2 173.1 2 123.0 0.01 2 24.81 2 1.63 2 16.80 2 9 9 9 9 9 9 9 9 9 9

18 2 1096.8 35.078 35.075 2 6.071 5.969 27.631 198.7 2 198.5 2 102.4 0.01 2 22.46 2 1.48 2 15.30 2 9 9 9 9 9 9 9 9 9 9

17 2 1299.6 35.100 35.099 2 5.278 5.163 27.749 234.0 2 231.6 2 75.1 0.01 2 19.63 2 1.30 2 13.50 2 9 9 9 9 9 9 9 9 9 9

16 2 1499.5 35.044 35.045 2 4.514 4.388 27.793 252.9 2 252.1 2 60.5 0.00 2 18.56 2 1.23 2 13.00 2 9 9 9 9 9 9 9 9 9 9

15 2 1698.6 35.019 35.018 2 4.090 3.950 27.821 259.9 2 259.3 2 56.7 0.00 2 18.36 2 1.22 2 14.20 2 9 9 9 9 9 9 9 9 9 9

14 2 1896.9 35.007 35.007 2 3.824 3.669 27.841 260.1 2 261.1 2 57.1 0.01 2 18.46 2 1.23 2 16.10 2 9 9 9 9 9 9 9 9 9 9

13 2 2099.8 34.995 34.995 2 3.565 3.394 27.860 260.5 2 260.5 2 59.9 0.01 2 18.75 2 1.25 2 18.70 2 9 9 9 9 9 9 9 9 9 9

12 2 2298.7 34.979 34.979 2 3.334 3.148 27.872 260.3 2 260.8 2 61.6 0.01 2 18.95 2 1.28 2 21.30 2 9 9 9 9 9 9 9 9 9 9

11 2 2488.8 34.965 34.965 2 3.153 2.951 27.880 260.5 2 261.5 2 62.5 0.01 2 19.14 2 1.31 2 23.40 2 9 9 9 9 9 9 9 9 9 9

10 2 2689.9 34.953 34.953 2 2.992 2.773 27.888 258.4 2 259.7 2 65.8 0.01 2 19.54 2 1.32 2 26.50 2 9 9 9 9 9 9 9 9 9 9

9 2 2899.1 34.941 34.942 2 2.852 2.615 27.893 260.1 2 260.8 2 66.0 0.01 2 19.63 2 1.33 2 28.10 2 9 9 9 9 9 9 9 9 9 9

8 2 3199.3 34.927 34.926 2 2.663 2.399 27.902 264.7 2 265.2 2 63.4 0.01 2 19.24 2 1.31 2 28.00 2 9 9 9 9 9 9 9 9 9 9

7 2 3501.6 34.915 34.915 2 2.493 2.201 27.910 271.5 2 271.8 2 58.5 0.01 2 18.17 2 1.25 2 25.50 2 9 9 9 9 9 9 9 9 9 9

6 2 3798.0 34.906 34.906 2 2.384 2.062 27.916 273.8 2 273.6 2 57.9 0.01 2 18.07 2 1.24 2 26.10 2 9 9 9 9 9 9 9 9 9 9

5 2 4098.5 34.901 34.900 2 2.331 1.976 27.921 273.5 2 272.8 2 59.4 0.01 2 18.27 2 1.26 2 28.00 2 9 9 9 9 9 9 9 9 9 9

4 2 4399.1 34.895 34.896 2 2.301 1.912 27.924 272.0 2 270.7 2 62.1 0.01 2 18.56 2 1.28 2 30.30 2 9 9 9 9 9 9 9 9 9 9

3 2 4798.4 34.885 34.884 2 2.248 1.812 27.926 268.2 2 266.0 2 67.7 0.01 2 19.63 2 1.36 2 36.50 2 9 9 9 9 9 9 9 9 9 9

2 2 5198.8 34.865 34.865 2 2.147 1.664 27.923 260.2 2 259.4 2 75.6 0.01 2 21.30 2 1.48 2 46.70 2 9 9 9 9 9 9 9 9 9 9

1 2 5619.4 34.846 34.846 2 2.055 1.521 27.921 252.0 2 253.6 2 82.7 0.01 6 22.66 2 1.58 6 55.50 2 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

160
A5R

NOAA Ship Ronald H. Brown

STATION 92 DATE 2/17/1998 LATITUDE 25.759° N

LONGITUDE 70.235° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 7.1 36.608 36.607 2 24.269 24.267 24.782 215.1 2 210.7 2 -4.0 0.00 2 0.10 2 0.00 2 0.90 2 1.86 2 1.09 2 0.15 2 1.94 2 268.1 317.3 2 2028.5 2 8.1115 2 2392 2 2398 72.6 2 9

35 2 50.5 36.631 36.631 2 24.296 24.285 24.796 211.1 2 210.7 2 -4.1 0.01 2 0.10 2 0.01 2 0.90 2 1.87 2 1.08 2 0.15 2 9 9 2029.3 2 8.1086 2 2393 2 2397 73.2 2 9

34 2 99.3 36.989 37.010 2 24.075 24.054 25.140 199.6 2 199.6 2 7.3 0.02 2 0.39 2 0.02 2 0.70 2 1.96 2 1.12 2 0.17 2 9 303.5 356.3 2 2070.0 2 8.0751 2 2416 2 2421 66.2 2 9

33 3 150.2 37.007 37.009 2 22.029 21.999 25.754 190.1 2 197.9 2 16.5 0.05 2 0.78 2 0.03 2 0.60 2 2.11 2 1.20 2 0.11 2 9 9 2092.5 2 8.0336 2 2414 2 2416 59.3 2 9

32 2 201.1 36.837 36.827 2 20.121 20.083 26.152 178.5 2 188.0 2 34.1 0.02 2 1.95 2 0.07 2 0.80 2 2.22 6 1.25 6 0.06 6 9 378.8 380.5 2 2108.7 2 7.9949 2 2404 2 2406 52.8 2 9

31 2 225.2 36.707 36.704 2 19.270 19.229 26.279 186.7 2 184.3 2 41.4 0.01 2 3.61 2 0.15 2 1.10 2 2.23 2 1.24 2 0.02 2 9 9 9 9 9 49.4 2 9

30 2 249.8 36.629 36.632 2 18.785 18.740 26.346 182.1 2 194.0 2 33.9 0.01 2 3.32 2 0.13 2 1.00 2 2.30 2 1.27 2 0.02 2 9 9 9 9 9 49.0 2 9

29 2 275.6 36.592 36.594 2 18.493 18.444 26.394 194.9 2 195.2 2 34.0 0.01 2 4.00 2 0.17 2 1.20 2 2.29 2 1.26 2 0.02 2 9 388.6 365.6 2 2103.0 2 7.9845 2 2388 2 2392 47.7 2 9

28 2 300.1 36.563 36.566 2 18.287 18.234 26.426 197.8 2 199.2 2 31.0 0.01 2 4.00 2 0.18 2 1.20 2 2.32 2 1.28 2 0.02 2 9 9 9 9 9 9 9

27 2 350.8 36.510 36.509 2 17.939 17.878 26.476 199.0 2 198.6 2 33.2 0.01 2 4.88 2 0.23 2 1.50 2 2.28 2 1.24 2 0.03 3 9 396.0 364.4 2 2102.2 2 7.9843 2 2385 2 2390 47.4 2 9

26 2 401.4 36.445 36.445 2 17.549 17.480 26.526 192.6 2 193.0 2 40.6 0.01 2 6.05 2 0.30 2 1.80 2 2.21 6 1.19 6 0.03 6 9 9 9 9 9 9 9

25 2 450.0 36.333 36.339 2 16.904 16.829 26.598 188.0 2 189.1 2 47.6 0.01 2 7.32 2 0.39 2 2.20 2 2.15 2 1.14 2 0.03 2 9 9 9 9 9 45.1 2 9

24 2 501.9 36.194 36.196 2 16.065 15.984 26.690 183.7 2 184.5 2 56.4 0.01 2 9.08 2 0.50 2 2.90 2 2.06 2 1.09 2 0.03 2 9 469.6 400.2 2 2125.4 2 9 2365 2 9 9

23 2 551.3 36.027 36.026 2 15.063 14.978 26.789 181.4 2 179.1 2 66.9 0.01 2 11.22 2 0.64 2 3.90 2 1.88 2 0.98 2 0.03 2 9 9 9 9 9 43.2 2 9

22 2 650.9 35.721 35.723 2 13.032 12.940 26.983 167.6 2 164.9 2 92.0 0.01 2 15.81 2 0.95 2 6.40 2 1.38 2 0.71 2 0.03 2 9 608.0 457.1 2 2153.3 2 7.8112 2 2343 2 2343 9 9

21 2 750.8 35.437 35.443 2 11.007 10.912 27.150 154.0 2 151.9 2 116.7 0.01 2 20.70 2 1.28 2 10.20 2 0.77 2 0.39 2 0.02 2 9 724.2 500.4 2 2173.5 2 9 9 41.7 2 9

20 2 851.3 35.226 35.224 2 9.111 9.014 27.309 154.4 2 152.8 2 127.6 0.01 2 23.34 2 1.50 2 13.80 2 0.51 2 0.26 2 0.01 2 9 9 9 7.7404 2 2331 2 9 9

19 2 953.1 35.129 35.130 2 7.645 7.546 27.457 163.0 2 167.5 2 122.5 0.01 2 23.73 2 1.55 2 15.40 2 0.40 2 0.20 2 0.01 2 9 837.0 500.1 2 2188.5 6 7.6818 2 2321 2 2319 41.2 2 9

18 2 1150.9 35.070 35.071 2 5.873 5.767 27.651 205.4 2 204.8 2 97.5 0.01 2 21.98 2 1.45 2 15.50 2 0.27 2 0.14 2 0.00 2 9 794.0 436.8 2 2181.5 2 7.6983 2 2320 2 2318 9 9

17 2 1351.6 35.075 35.075 2 5.065 4.947 27.755 236.8 2 237.5 2 70.8 0.01 2 19.24 2 1.28 2 13.60 2 0.44 2 0.23 2 0.01 2 9 9 9 9 9 41.3 2 9

16 2 1551.6 35.063 35.063 2 4.588 4.456 27.801 248.7 2 248.8 2 63.2 0.01 2 18.75 2 1.24 2 14.30 2 0.30 6 0.16 6 0.01 6 9 731.3 377.7 2 2166.3 2 7.7351 2 2317 2 2318 9 9

15 2 1743.9 35.031 35.032 2 4.155 4.010 27.825 256.7 2 255.5 2 60.0 0.01 2 18.46 2 1.23 2 15.20 2 0.24 2 0.13 2 0.01 2 9 9 9 9 9 9 9

14 2 1953.1 34.999 34.999 2 3.748 3.589 27.843 260.1 2 261.9 2 56.9 0.01 2 18.26 2 1.22 2 16.50 2 0.22 6 0.11 6 0.01 6 9 716.4 355.1 2 2162.6 2 7.7407 2 2315 2 2316 9 9

13 9 2142.2 34.990 34.991 2 3.511 3.337 27.862 260.0 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

12 2 2350.6 34.974 34.975 2 3.281 3.091 27.873 260.6 2 261.0 6 61.9 0.01 2 18.85 2 1.27 2 22.00 2 0.08 2 0.04 2 0.01 2 9 726.9 352.0 2 2167.3 2 7.7393 2 2323 2 2320 9 9

11 2 2549.2 34.960 34.961 2 3.090 2.883 27.882 259.0 2 259.9 2 64.7 0.01 2 19.24 2 1.30 2 25.20 2 0.05 2 0.03 2 0.00 2 9 9 2171.9 2 7.7391 2 2326 2 2325 41.4 2 9

10 2 2747.4 34.949 34.949 2 2.935 2.712 27.890 257.6 2 259.2 2 66.8 0.01 2 19.63 2 1.33 2 28.00 2 0.02 2 0.01 2 0.01 2 0.24 2 9 9 9 9 9 9

9 2 2950.1 34.938 34.938 2 2.794 2.553 27.896 259.7 2 261.2 2 66.1 0.01 2 19.54 2 1.33 2 29.00 2 0.04 2 0.02 2 0.00 2 0.24 2 719.4 339.4 2 2173.4 2 7.7383 2 2329 2 2326 9 9

8 2 3116.3 34.928 34.928 2 2.688 2.432 27.900 264.0 2 264.8 2 63.5 0.01 2 19.05 2 1.31 2 28.20 2 0.10 2 0.05 2 0.01 2 0.36 2 9 2171.3 2 4 2327 2 9 9

7 2 3415.9 34.915 34.915 2 2.512 2.228 27.908 271.7 2 271.1 2 59.0 0.01 2 18.36 2 1.26 2 26.20 2 0.25 2 0.12 2 0.01 2 0.67 2 9 2167.2 2 7.7368 2 2322 2 2319 9 9

6 2 3751.7 34.906 34.906 2 2.378 2.061 27.916 274.4 2 273.1 2 58.4 0.01 2 18.07 2 1.24 2 26.50 2 0.39 2 0.19 2 0.01 2 0.92 2 725.7 336.0 2 2169.2 2 7.7371 2 2323 2 2321 9 9

5 2 4049.5 34.899 34.900 2 2.324 1.975 27.919 273.7 2 272.3 2 59.9 0.01 2 18.36 2 1.26 2 28.90 2 0.32 2 0.17 2 0.02 2 0.65 6 9 2170.5 2 7.7360 2 2325 2 2322 9 9

4 2 4452.8 34.894 34.894 2 2.294 1.899 27.924 272.3 2 270.7 2 62.2 0.01 2 18.75 2 1.29 2 31.60 2 0.34 2 0.17 2 0.03 2 0.84 2 9 2174.8 2 7.7328 2 2328 2 2325 9 9

3 2 4849.3 34.886 34.885 2 2.273 1.830 27.926 269.2 2 266.9 2 66.6 0.01 2 19.44 2 1.34 2 36.00 2 0.22 2 0.11 2 0.02 2 0.62 2 9 9 9 9 9 9

2 2 5250.2 34.868 34.868 2 2.179 1.689 27.924 260.6 2 260.1 2 74.7 0.01 2 21.10 2 1.46 2 46.10 2 0.07 2 0.05 2 0.02 2 9 9 9 9 9 9 9

1 2 5605.9 34.847 34.848 2 2.068 1.535 27.921 251.8 2 253.8 6 82.3 0.01 6 22.57 6 1.57 6 55.80 6 0.03 2 0.03 2 0.01 2 0.19 2 793.3 360.4 2 2202.0 2 7.7105 2 2349 2 2344 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

161
A5R

NOAA Ship Ronald H. Brown

STATION 93 DATE 2/17/1998 LATITUDE 26.141° N

LONGITUDE 70.615° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.9 36.654 36.653 2 24.281 24.280 24.812 214.7 2 211.0 6 -4.4 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 269.1 318.7 2 2028.4 2 8.1010 2 9 2391 9 9

35 2 70.7 36.751 36.748 2 23.666 23.651 25.077 212.4 2 212.7 2 -4.0 0.00 2 0.00 2 0.00 2 0.80 2 9 9 9 9 9 9 9 9 9 9

34 2 71.3 36.750 36.747 2 23.654 23.639 25.080 213.2 2 212.9 2 -4.2 0.01 2 0.00 2 0.01 2 0.80 2 9 9 9 9 273.9 316.6 2 2036.4 2 8.1049 2 5 2403 9 9

33 2 104.2 36.775 36.779 2 23.298 23.276 25.208 212.7 2 213.6 2 -3.6 0.01 2 0.00 2 0.01 2 0.70 2 9 9 9 9 280.5 319.7 2 9 8.0999 2 2428 2 9 9

32 2 150.6 37.017 37.018 2 21.784 21.754 25.831 203.5 2 200.7 2 14.6 0.04 2 0.39 2 0.02 2 0.60 2 9 9 9 9 333.2 357.7 2 2090.1 2 8.0395 2 2416 2 2418 9 9

31 2 199.3 36.828 36.835 2 20.020 19.983 26.173 189.2 2 189.6 2 32.9 0.02 2 1.56 2 0.05 2 0.70 2 9 9 9 9 9 9 9 9 9 9

30 2 223.8 36.723 36.722 2 19.302 19.261 26.283 187.1 2 190.1 2 35.5 0.01 2 2.54 2 0.08 2 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 274.7 36.620 36.619 2 18.620 18.571 26.383 191.9 2 196.0 2 32.6 0.01 2 3.51 2 0.14 2 1.10 2 9 9 9 9 393.4 372.1 2 2102.9 2 7.9840 2 2391 2 2391 9 9

28 2 276.1 36.609 36.612 2 18.567 18.518 26.388 193.4 2 196.8 2 32.1 0.01 2 3.51 2 0.15 2 1.10 2 9 9 9 9 9 9 9 9 9 9

27 2 298.7 36.572 36.574 2 18.341 18.288 26.419 197.1 2 199.9 2 30.0 0.01 2 3.80 2 0.17 2 1.20 2 9 9 9 9 9 9 9 9 9 9

26 2 347.3 36.531 36.532 2 18.013 17.953 26.473 197.7 2 195.3 2 36.1 0.01 2 4.88 2 0.24 2 1.50 2 9 9 9 9 9 9 9 9 9 9

25 2 398.4 36.455 36.455 2 17.564 17.496 26.529 186.9 2 190.4 2 43.2 0.01 2 6.15 2 0.32 2 1.90 2 9 9 9 9 426.7 386.7 2 2112.6 2 7.9525 2 2381 2 2381 9 9

24 2 450.0 36.321 36.339 2 16.824 16.749 26.607 187.3 2 184.9 2 52.2 0.01 2 7.61 2 0.41 2 2.30 2 9 9 9 9 9 9 9 9 9 9

23 2 499.5 36.187 36.192 2 16.014 15.934 26.696 181.3 2 183.4 2 57.7 0.01 2 9.17 2 0.51 2 2.90 2 9 9 9 9 9 9 9 9 9 9

22 2 601.7 35.845 35.851 2 13.893 13.805 26.901 171.3 2 167.5 2 84.6 0.01 2 14.06 2 0.84 2 5.30 2 9 9 9 9 572.9 446.5 2 2146.5 2 7.8351 2 2350 2 2348 9 9

21 2 698.9 35.613 35.614 2 12.120 12.026 27.079 172.4 2 167.6 2 94.4 0.01 2 16.89 2 1.03 2 7.30 2 9 9 9 9 9 9 9 9 9 9

20 2 799.5 35.372 35.392 2 10.285 10.187 27.227 158.9 2 156.3 2 116.6 0.01 2 20.90 2 1.32 2 10.70 2 9 9 9 9 734.6 491.4 2 2175.1 2 7.7347 2 2329 2 2328 9 9

19 2 850.7 35.206 35.206 2 8.907 8.811 27.326 152.5 2 150.8 2 130.9 0.01 2 24.03 2 1.55 2 14.20 2 9 9 9 9 830.9 525.1 2 2187.5 2 7.6898 2 2323 2 2321 9 9

18 2 900.4 35.141 35.140 2 8.203 8.106 27.384 154.4 2 154.0 2 132.3 0.01 2 24.71 2 1.61 2 15.40 2 9 9 9 9 854.3 523.5 2 2190.4 6 7.6765 2 2320 2 2319 9 9

17 2 997.6 35.069 35.066 2 7.002 6.903 27.500 169.2 2 169.8 2 124.6 0.01 2 24.42 2 1.63 2 16.60 2 9 9 9 9 9 9 9 9 9 9

16 2 1151.0 35.078 35.078 2 5.865 5.759 27.658 210.3 2 208.8 2 93.6 0.01 2 21.29 2 1.42 2 14.60 2 9 9 9 9 797.7 438.8 2 2178.8 2 7.7006 2 2322 2 2316 9 9

15 2 1351.4 35.070 35.069 2 5.044 4.926 27.753 241.1 2 239.1 2 69.4 0.01 2 19.05 2 1.27 2 13.10 2 9 9 9 9 9 9 9 9 9 9

14 2 1548.4 35.027 35.028 2 4.421 4.291 27.791 258.2 2 255.8 2 57.5 0.01 2 18.07 2 1.22 2 12.90 2 9 9 9 9 726.1 372.1 2 2164.5 2 7.7324 2 2316 2 2314 9 9

13 2 1827.7 35.006 35.005 2 3.944 3.794 27.828 262.4 2 261.9 2 55.3 0.01 2 17.97 2 1.21 2 14.70 2 9 9 9 9 9 9 9 9 9 9

12 2 2050.1 34.988 34.990 2 3.615 3.448 27.849 264.5 2 263.7 2 56.3 0.01 2 18.17 2 1.22 2 16.80 2 9 9 9 9 718.8 354.0 2 2163.4 2 7.7373 2 2319 2 2315 9 9

11 2 2273.5 34.972 34.971 2 3.342 3.158 27.865 264.6 2 265.3 2 57.0 0.01 2 18.07 2 1.23 2 18.80 2 9 9 9 9 9 9 9 9 9 9

10 2 2547.5 34.957 34.957 2 3.092 2.886 27.879 263.2 2 264.8 2 59.8 0.01 2 18.66 2 1.26 2 21.70 2 9 9 9 9 9 9 9 9 9 9

9 2 2799.4 34.946 34.946 2 2.922 2.694 27.889 261.8 2 263.2 2 62.9 0.01 2 19.05 2 1.29 2 25.10 2 9 9 9 9 9 9 9 9 9 9

8 2 3099.9 34.928 34.928 2 2.708 2.453 27.898 272.5 2 270.6 2 57.6 0.01 2 18.07 2 1.23 2 22.60 2 9 9 9 9 9 9 9 9 9 9

7 2 3450.2 34.916 34.916 2 2.523 2.235 27.908 273.1 2 273.4 2 56.6 0.01 2 17.78 2 1.22 2 23.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3800.9 34.906 34.907 2 2.395 2.072 27.916 274.4 2 273.0 2 58.4 0.01 2 18.17 2 1.24 2 26.40 2 9 9 9 9 9 9 9 9 9 9

5 2 4108.7 34.901 34.901 2 2.337 1.981 27.921 274.5 2 272.6 2 59.6 0.01 2 18.27 2 1.26 2 28.30 2 9 9 9 9 9 9 9 9 9 9

4 2 4497.7 34.894 34.894 2 2.306 1.905 27.924 273.0 2 270.1 2 62.7 0.01 2 18.66 2 1.29 2 30.80 2 9 9 9 9 9 9 9 9 9 9

3 2 4848.7 34.888 34.887 2 2.289 1.846 27.927 270.6 2 267.9 2 65.5 0.01 2 19.24 2 1.33 2 34.10 2 9 9 9 9 9 9 9 9 9 9

2 2 5230.4 34.874 34.874 2 2.227 1.738 27.926 264.4 2 262.1 2 72.2 0.01 2 20.42 2 1.42 2 41.70 2 9 9 9 9 9 9 9 9 9 9

1 2 5595.6 34.848 34.849 2 2.072 1.541 27.922 252.5 2 254.2 2 81.9 0.01 6 22.47 6 1.57 6 54.30 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

162
A5R

NOAA Ship Ronald H. Brown

STATION 94 DATE 2/17/1998 LATITUDE 26.501° N

LONGITUDE 71.012° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.4 36.757 36.756 2 23.775 23.774 25.041 214.7 2 212.9 2 -4.7 0.00 2 0.10 2 0.00 2 0.80 2 1.90 2 1.10 2 0.16 2 1.97 2 276.9 321.5 2 2034.8 6 8.1051 2 2403 2 2402 67.7 2 9

35 2 41.5 36.766 36.767 2 23.684 23.675 25.080 211.5 2 213.4 2 -4.8 0.00 2 0.00 2 0.00 2 0.60 2 1.92 2 1.10 2 0.17 2 9 278.2 321.8 2 2037.5 2 8.1038 2 2411 2 2404 67.9 2 9

34 2 77.2 36.886 36.884 2 23.436 23.420 25.248 212.6 2 213.2 2 -3.9 0.00 2 0.00 2 0.00 2 0.50 2 1.98 2 1.13 2 0.17 2 9 292.6 335.2 2 2053.5 2 8.0865 2 2418 2 2410 61.8 2 9

33 2 115.6 36.801 36.855 2 22.704 22.680 25.401 213.8 2 213.0 2 -1.0 0.02 2 0.00 2 0.01 2 0.40 2 2.01 2 1.16 2 0.16 2 9 298.0 331.8 2 2056.1 2 8.0813 2 2409 2 2409 58.8 2 9

32 2 157.3 37.000 36.996 2 21.570 21.539 25.878 197.7 2 195.4 2 20.7 0.02 2 0.59 2 0.02 2 0.40 2 2.15 2 1.22 2 0.11 2 9 347.8 370.3 2 2096.4 2 8.0285 2 2418 2 2417 56.3 2 9

31 2 201.1 36.790 36.791 2 19.928 19.891 26.168 193.3 2 193.7 2 29.2 0.00 2 1.37 2 0.04 2 0.50 2 2.25 2 1.26 2 0.07 2 9 373.9 372.8 2 2100.5 2 8.0035 2 2410 2 2403 52.6 2 9

30 2 224.6 36.728 36.726 2 19.489 19.448 26.238 198.3 2 197.1 2 27.7 0.00 2 1.56 2 0.04 2 0.60 2 2.29 2 1.28 2 0.05 2 9 374.1 366.6 6 2098.6 2 8.0032 2 9 2400 50.5 2 9

29 2 245.9 36.710 36.709 2 19.197 19.152 26.302 190.4 2 190.4 2 35.7 0.00 2 2.73 2 0.08 2 0.70 2 2.29 2 1.27 2 0.03 2 9 391.0 378.6 2 2107.0 2 7.9858 2 5 2398 49.1 2 9

28 2 269.8 36.611 36.612 2 18.652 18.604 26.368 192.9 2 197.3 2 31.2 0.00 2 3.22 2 0.11 2 0.90 2 2.32 2 1.27 2 0.03 2 9 388.5 368.0 2 2100.0 2 9 9 9 9

27 2 299.6 36.573 36.573 2 18.360 18.307 26.415 198.5 2 200.1 2 29.7 0.00 2 3.71 2 0.14 2 1.00 2 2.32 2 1.27 2 0.03 2 9 384.1 359.5 2 2098.6 2 7.9890 2 2396 2 2390 47.8 2 9

26 2 349.8 36.533 36.530 2 18.085 18.024 26.457 201.4 2 202.2 2 28.9 0.00 2 4.20 2 0.18 2 1.20 2 2.31 6 1.26 6 0.03 6 9 390.7 361.6 2 2098.8 2 7.9846 2 9 2387 9 9

25 2 401.1 36.476 36.478 2 17.735 17.666 26.504 196.2 2 196.7 2 36.1 0.00 2 5.27 2 0.24 2 1.40 2 2.32 2 1.25 2 0.03 2 9 403.3 368.0 2 2105.3 2 9 2392 2 44.6 2 9

24 2 497.8 36.240 36.240 2 16.329 16.248 26.664 185.8 2 184.2 2 55.4 0.00 2 8.59 2 0.43 2 2.50 2 2.08 2 1.10 2 0.03 2 9 462.2 398.1 2 2123.0 2 7.9163 2 2377 2 2369 9 9

23 2 598.5 35.911 35.911 2 14.369 14.279 26.852 173.4 2 170.6 2 79.0 0.00 2 13.08 2 0.73 2 4.60 2 1.66 2 0.86 2 0.02 2 9 545.9 433.8 2 2140.5 2 7.8516 2 2361 2 2351 42.5 2 9

22 2 698.3 35.639 35.638 2 12.438 12.342 27.038 166.9 2 163.0 2 97.2 0.00 2 16.89 2 0.99 2 7.00 2 1.19 2 0.62 2 0.02 2 9 634.7 465.3 2 2154.9 2 7.7938 2 5 2335 9 9

21 2 798.5 35.376 35.374 2 10.494 10.395 27.195 153.1 2 152.4 2 119.3 0.00 2 21.29 2 1.32 2 10.80 2 0.68 2 0.36 2 0.02 2 9 737.7 498.9 2 2175.4 2 9 2356 3 42.1 2 9

20 2 849.6 35.252 35.258 2 9.485 9.386 27.269 149.4 2 148.9 2 129.1 0.00 2 23.34 2 1.46 2 12.90 2 0.49 2 0.26 2 0.01 2 9 791.1 512.3 2 2185.6 2 7.6989 2 5 2323 9 9

19 2 900.0 35.168 35.169 2 8.627 8.527 27.341 150.2 2 151.1 2 132.4 0.00 2 24.42 2 1.55 2 14.60 2 0.37 2 0.20 2 0.01 2 9 837.6 523.2 2 2190.9 2 7.6807 2 5 2321 41.3 2 9

18 2 951.5 35.102 35.103 2 7.848 7.748 27.407 155.3 2 155.2 2 133.5 0.00 2 25.00 2 1.62 2 15.90 2 0.30 2 0.16 2 0.01 2 9 862.7 520.7 2 2192.9 6 7.6683 2 5 2318 9 9

17 2 1049.3 35.071 35.070 2 6.747 6.645 27.537 177.8 2 178.4 2 117.8 0.00 2 23.73 2 1.54 2 15.90 2 0.31 2 0.16 2 0.01 2 9 838.0 480.8 2 2190.0 2 7.6778 2 9 2318 41.7 2 9

16 2 1218.1 35.080 35.079 2 5.597 5.487 27.694 220.2 2 220.4 2 83.9 0.00 2 20.31 2 1.31 2 13.60 2 0.51 2 0.26 2 0.01 2 9 761.9 413.2 2 2175.5 2 7.7105 2 5 2317 9 9

15 2 1449.6 35.037 35.036 2 4.630 4.507 27.774 251.1 2 251.1 2 60.6 0.00 2 18.46 2 1.19 2 12.50 2 0.77 6 0.38 6 0.03 6 9 739.2 382.9 2 2161.5 2 7.7298 2 9 2310 41.3 2 9

14 2 1649.3 34.992 34.992 2 4.094 3.959 27.798 263.7 2 263.7 2 52.3 0.00 2 17.87 2 1.16 2 12.70 2 0.81 2 0.40 2 0.03 2 9 9 2160.9 2 7.7333 2 2314 2 2311 9 9

13 2 1850.1 34.988 34.989 2 3.863 3.712 27.822 265.5 2 265.4 2 52.5 0.00 2 17.87 2 1.16 2 14.00 2 0.57 2 0.28 2 0.03 2 9 713.8 355.8 2 2160.8 2 7.7365 2 2321 2 2312 41.5 2 9

12 2 2051.5 34.971 34.970 2 3.588 3.422 27.838 268.2 2 268.2 2 52.0 0.00 2 17.78 2 1.16 2 15.10 2 0.55 2 0.27 2 0.03 2 9 9 2161.2 2 7.7372 2 2315 2 2313 9 9

11 2 2298.0 34.964 34.965 2 3.348 3.162 27.858 268.2 2 267.8 2 54.5 0.00 2 17.87 2 1.17 2 17.20 2 0.35 2 0.18 2 0.02 2 9 9 2162.2 2 7.7400 2 2324 3 2315 41.9 2 9

10 2 2549.1 34.956 34.956 2 3.132 2.925 27.875 267.0 2 267.1 2 57.1 0.00 2 18.17 2 1.20 2 19.90 2 0.20 2 0.10 2 0.01 2 0.63 2 706.4 339.4 2 2163.0 2 7.7417 2 9 2317 9 9

9 2 2800.4 34.942 34.942 2 2.905 2.677 27.887 266.2 2 268.8 2 57.5 0.00 2 18.07 2 1.20 2 21.50 2 0.23 2 0.12 2 0.01 2 0.65 2 9 2163.7 2 7.7405 2 2323 2 2317 41.3 2 9

8 2 3040.7 34.931 34.931 2 2.737 2.488 27.897 270.1 2 269.6 2 58.3 0.00 2 18.17 2 1.20 2 23.10 2 0.25 2 0.13 2 0.01 2 0.64 2 720.9 339.8 2 2166.2 2 7.7406 2 9 2319 9 9

7 2 3350.3 34.919 34.919 2 2.559 2.281 27.906 273.3 2 271.8 2 57.8 0.00 2 17.97 2 1.20 2 23.80 2 0.32 2 0.16 2 0.01 2 0.78 2 715.6 334.2 2 2167.6 2 9 2334 3 41.2 2 9

6 2 3648.3 34.910 34.910 2 2.430 2.123 27.913 272.4 2 273.2 2 57.8 0.00 2 17.88 2 1.20 2 25.30 2 0.42 2 0.20 2 0.02 2 0.88 6 9 2167.0 2 7.7385 2 9 2319 9 9

5 2 4050.2 34.902 34.903 2 2.353 2.003 27.920 274.3 2 272.4 2 59.6 0.00 2 18.07 2 1.22 2 27.50 2 0.32 6 0.17 6 0.02 6 0.84 2 9 2171.1 2 7.7362 2 2330 2 2323 41.8 2 9

4 2 4448.7 34.896 34.896 2 2.322 1.926 27.924 273.3 2 270.9 2 61.8 0.00 2 18.56 2 1.25 2 29.80 2 0.29 2 0.15 2 0.02 2 0.77 2 9 2173.2 2 9 9 9 9

3 2 4840.3 34.890 34.889 2 2.306 1.863 27.927 271.7 2 268.9 2 64.3 0.00 2 18.95 2 1.28 2 32.70 2 0.32 2 0.16 2 0.03 2 0.78 2 733.1 337.8 6 2177.7 2 7.7321 2 2335 2 2328 41.5 2 9

2 2 5248.1 34.876 34.875 2 2.238 1.746 27.927 265.2 2 262.8 2 71.5 0.01 2 20.42 2 1.38 2 41.30 2 0.16 2 0.09 2 0.02 2 0.47 2 746.6 342.3 2 2186.9 2 7.7271 2 9 2335 9 9

1 2 5579.3 34.853 34.853 2 2.105 1.575 27.923 254.2 2 255.9 6 79.9 0.01 6 22.17 6 1.52 6 52.70 6 0.03 2 0.03 2 0.01 2 0.20 2 778.3 354.2 2 2199.1 2 7.7151 2 5 2343 41.1 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

163
A5R

NOAA Ship Ronald H. Brown

STATION 95 DATE 2/17/1998 LATITUDE 26.500° N

LONGITUDE 71.351° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.6 36.770 36.770 2 23.716 23.715 25.069 209.4 2 213.7 2 -5.3 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 282.4 327.1 6 2035.4 6 8.1060 6 2408 6 2403 9 9

35 2 50.9 36.774 36.775 2 23.641 23.630 25.100 211.1 2 211.6 2 -2.9 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 75.6 36.946 36.937 2 23.501 23.485 25.275 213.4 2 213.0 2 -4.0 0.01 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

33 2 100.7 36.794 36.805 2 22.720 22.699 25.389 212.9 2 214.2 2 -2.2 0.02 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

32 2 151.0 37.088 37.061 2 22.156 22.126 25.780 201.6 2 197.7 2 16.1 0.04 2 0.59 2 0.02 2 0.60 2 9 9 9 9 9 9 9 9 9 9

31 2 200.7 36.792 36.778 2 20.008 19.970 26.149 196.2 2 197.7 2 24.9 0.02 2 1.27 2 0.04 2 0.70 2 9 9 9 9 9 9 9 9 9 9

30 2 224.5 36.685 36.681 2 19.294 19.253 26.256 195.9 2 198.7 2 27.0 0.01 2 1.95 2 0.06 2 0.90 2 9 9 9 9 9 9 9 9 9 9

29 2 250.8 36.623 36.622 2 18.791 18.746 26.340 196.9 2 199.6 2 28.3 0.01 2 2.93 2 0.10 2 1.00 2 9 9 9 9 9 9 9 9 9 9

28 2 274.7 36.600 36.600 2 18.625 18.576 26.367 196.2 2 200.2 2 28.4 0.01 2 3.22 2 0.12 2 1.10 2 9 9 9 9 9 9 9 9 9 9

27 2 297.6 36.581 36.578 2 18.448 18.395 26.398 200.5 2 202.0 2 27.5 0.01 2 3.51 2 0.13 2 1.20 2 9 9 9 9 9 9 9 9 9 9

26 2 399.0 36.517 36.517 2 17.955 17.886 26.481 204.7 2 205.4 2 26.3 0.01 2 4.20 2 0.18 2 1.40 2 9 9 9 9 9 9 9 9 9 9

25 2 451.2 36.441 36.443 2 17.549 17.472 26.527 195.2 2 196.7 2 37.0 0.01 2 5.66 2 0.26 2 1.80 2 9 9 9 9 9 9 9 9 9 9

24 2 498.8 36.336 36.335 2 16.970 16.886 26.589 190.2 2 189.2 2 47.3 0.01 2 7.42 2 0.36 2 2.30 2 9 9 9 9 9 9 9 9 9 9

23 2 550.8 36.147 36.160 2 15.802 15.714 26.717 183.7 2 182.9 2 59.3 0.01 2 9.56 2 0.50 2 3.10 2 9 9 9 9 9 9 9 9 9 9

22 2 600.2 35.972 35.979 2 14.715 14.623 26.825 178.2 2 176.4 2 71.4 0.01 2 11.91 2 0.65 2 4.20 2 9 9 9 9 9 9 9 9 9 9

21 2 701.2 35.651 35.657 2 12.575 12.478 27.021 167.2 2 162.4 2 97.1 0.01 2 16.99 2 1.00 2 7.20 2 9 9 9 9 9 9 9 9 9 9

20 2 796.2 35.386 35.385 2 10.565 10.466 27.190 156.1 2 152.3 2 119.0 0.01 2 21.38 2 1.31 2 10.90 2 9 9 9 9 9 9 9 9 9 9

19 2 901.1 35.183 35.188 2 8.751 8.651 27.333 149.2 2 150.4 2 132.3 0.01 2 24.51 2 1.55 2 14.70 2 9 9 9 9 9 9 9 9 9 9

18 2 1001.8 35.084 35.085 2 7.455 7.352 27.450 161.3 2 161.5 2 129.9 0.01 2 25.10 2 1.62 2 16.50 2 9 9 9 9 9 9 9 9 9 9

17 2 1200.0 35.079 35.079 2 5.766 5.656 27.673 218.0 2 215.3 2 87.8 0.01 2 20.80 2 1.34 2 14.00 2 9 9 9 9 9 9 9 9 9 9

16 2 1390.5 35.049 35.050 2 4.935 4.815 27.750 245.7 2 243.1 6 66.2 0.01 2 18.95 2 1.22 2 12.70 2 9 9 9 9 9 9 9 9 9 9

15 2 1601.2 35.011 35.011 2 4.240 4.107 27.797 260.4 2 259.6 2 55.2 0.01 2 18.17 2 1.18 2 13.10 2 9 9 9 9 9 9 9 9 9 9

14 2 1772.6 35.011 35.013 2 4.067 3.920 27.818 260.1 2 260.5 2 55.7 0.01 2 18.17 2 1.18 2 14.20 2 9 9 9 9 9 9 9 9 9 9

13 2 2051.2 34.988 34.989 2 3.684 3.516 27.842 263.3 2 264.6 2 54.8 0.01 2 18.17 2 1.19 2 16.00 2 9 9 9 9 9 9 9 9 9 9

12 2 2251.0 34.977 34.978 2 3.455 3.271 27.858 264.4 2 264.8 2 56.6 0.01 2 18.26 2 1.21 2 18.00 2 9 9 9 9 9 9 9 9 9 9

11 2 2449.4 34.962 34.962 2 3.226 3.027 27.870 266.1 2 267.3 2 56.1 0.01 2 18.27 2 1.20 2 19.20 2 9 9 9 9 9 9 9 9 9 9

10 2 2650.6 34.950 34.950 2 3.047 2.831 27.880 267.5 2 270.7 2 54.3 0.01 2 18.27 2 1.21 2 20.30 2 9 9 9 9 9 9 9 9 9 9

9 2 2848.7 34.941 34.941 2 2.892 2.659 27.889 264.6 2 270.0 2 56.4 0.01 2 18.17 2 1.21 2 21.10 2 9 9 9 9 9 9 9 9 9 9

8 2 3050.7 34.931 34.930 2 2.750 2.499 27.896 269.9 2 270.7 2 57.1 0.01 2 18.07 2 1.21 2 22.10 2 9 9 9 9 9 9 9 9 9 9

7 2 3346.6 34.918 34.919 2 2.557 2.280 27.906 271.6 2 272.6 2 57.0 0.01 2 18.07 2 1.21 2 23.90 2 9 9 9 9 9 9 9 9 9 9

6 2 3649.7 34.910 34.910 2 2.440 2.133 27.913 273.4 2 274.7 2 56.2 0.01 2 17.88 2 1.20 2 24.50 2 9 9 9 9 9 9 9 9 9 9

5 2 3950.3 34.903 34.903 2 2.369 2.030 27.917 272.4 2 273.7 2 58.1 0.01 2 18.07 2 1.21 2 26.40 2 9 9 9 9 9 9 9 9 9 9

4 2 4350.1 34.897 34.897 2 2.328 1.944 27.922 271.2 2 272.3 2 60.2 0.01 2 18.56 2 1.24 2 29.30 2 9 9 9 9 9 9 9 9 9 9

3 2 4750.0 34.892 34.892 2 2.315 1.883 27.926 269.6 2 270.3 2 62.7 0.01 2 18.85 2 1.27 2 31.80 2 9 9 9 9 9 9 9 9 9 9

2 2 5150.7 34.882 34.883 2 2.288 1.807 27.927 265.0 2 265.9 2 67.8 0.01 2 19.73 2 1.34 2 37.20 2 9 9 9 9 9 9 9 9 9 9

1 2 5579.8 34.853 34.861 2 2.106 1.575 27.923 250.5 2 258.6 2 77.2 0.01 6 21.49 3 1.47 3 47.90 3 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

164
A5R

NOAA Ship Ronald H. Brown

STATION 96 DATE 2/18/1998 LATITUDE 26.500° N

LONGITUDE 71.734° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.3 36.768 36.766 2 23.265 23.264 25.200 214.5 2 214.5 2 -4.5 0.00 2 0.00 2 0.00 2 0.60 2 1.94 2 1.12 2 0.15 2 1.98 2 280.7 319.5 2 2040.5 2 8.1022 2 5 2406 9 9

35 2 40.3 36.765 36.767 2 23.231 23.223 25.212 214.1 2 214.0 2 -3.8 0.00 2 0.00 2 0.00 2 0.60 2 9 9 9 9 9 2040.9 2 8.0981 2 2404 2 2403 9 9

34 2 91.5 36.760 36.759 2 23.145 23.126 25.239 214.0 2 213.7 2 -3.2 0.01 2 0.00 2 0.00 2 0.60 2 1.95 2 1.13 2 0.16 2 9 279.6 316.8 2 2043.1 2 8.0671 2 5 2383 9 9

33 2 118.8 36.755 36.756 2 23.100 23.075 25.253 214.3 2 213.9 2 -3.2 0.00 2 0.00 2 0.00 2 0.60 2 9 9 9 9 9 9 9 9 9 9

32 2 162.1 36.862 36.861 2 21.541 21.509 25.782 205.9 2 202.9 2 13.5 0.04 2 0.49 2 0.01 2 0.50 2 2.14 2 1.21 2 0.12 2 9 9 2084.8 2 8.0284 2 2405 2 2403 9 9

31 2 201.2 36.771 36.770 2 20.058 20.020 26.119 197.3 2 198.0 2 24.4 0.02 2 1.27 2 0.03 2 0.60 2 2.25 2 1.26 2 0.07 2 9 361.4 362.1 2 2095.9 2 8.0146 2 5 2405 9 9

30 2 222.1 36.712 36.709 2 19.541 19.500 26.213 198.0 2 198.2 2 26.4 0.01 2 1.76 2 0.04 2 0.70 2 9 9 9 9 9 9 9 9 9 9

29 2 251.4 36.639 36.636 2 18.953 18.908 26.311 197.1 2 200.0 2 27.2 0.01 2 2.63 2 0.08 2 0.80 2 9 9 9 9 9 9 9 9 9 9

28 2 272.7 36.609 36.608 2 18.681 18.632 26.359 198.0 2 201.8 2 26.6 0.01 2 2.93 2 0.11 2 0.90 2 2.32 6 1.29 6 0.04 6 9 374.3 354.9 2 2096.4 2 8.0013 2 5 2396 9 9

27 2 300.2 36.586 36.584 2 18.470 18.417 26.397 200.4 2 202.7 2 26.6 0.01 2 3.32 2 0.13 2 0.90 2 9 9 9 9 9 9 9 9 9 9

26 2 350.3 36.573 36.572 2 18.287 18.225 26.438 202.1 2 196.6 2 33.6 0.01 2 4.29 2 0.19 2 1.20 2 2.30 2 1.26 2 0.02 2 9 393.5 367.2 2 2106.1 2 7.9656 2 2385 2 2383 9 9

25 2 400.3 36.512 36.511 2 17.931 17.861 26.484 203.8 2 200.9 2 31.0 0.01 2 4.68 2 0.22 2 1.40 2 9 9 9 9 9 9 9 9 9 9

24 2 442.1 36.469 36.469 2 17.694 17.618 26.512 202.8 2 199.8 2 33.2 0.01 2 5.17 2 0.25 2 1.60 2 2.24 2 1.22 2 0.04 2 9 404.3 368.3 2 2105.0 2 7.9687 2 2382 2 2383 9 9

23 2 550.2 36.158 36.177 2 15.847 15.759 26.715 188.0 2 181.7 2 60.3 0.00 2 9.46 2 0.52 2 2.90 2 2.00 2 1.05 2 0.03 2 9 9 2129.2 2 7.9023 2 2368 2 2368 9 9

22 2 649.3 35.846 35.853 2 13.940 13.844 26.895 177.2 2 173.8 2 78.1 0.01 2 13.57 2 0.80 2 5.10 2 9 9 9 9 9 9 9 9 9 9

21 2 750.5 35.573 35.581 2 11.939 11.839 27.085 164.3 2 161.3 2 101.8 0.01 2 17.86 2 1.08 2 7.90 2 1.06 2 0.55 2 0.01 2 9 645.6 463.1 2 2162.6 2 7.7793 2 2338 2 2336 9 9

20 2 850.6 35.309 35.299 2 9.906 9.804 27.244 152.2 2 151.0 2 124.4 0.01 2 22.55 2 1.43 2 12.30 2 0.54 2 0.28 2 0.01 2 9 783.0 516.3 2 2182.4 2 7.7104 2 2326 2 2325 9 9

19 2 950.4 35.138 35.140 2 8.296 8.193 27.369 154.8 2 153.2 2 132.5 0.01 2 24.61 2 1.60 2 15.30 2 0.33 2 0.17 2 0.01 2 9 850.9 523.8 2 2192.5 6 9 2321 2 9 9

18 2 1049.2 35.066 35.064 2 6.964 6.860 27.505 169.3 2 170.5 2 124.2 0.01 2 24.41 2 1.61 2 16.60 2 0.28 2 0.15 2 0.01 2 9 9 9 7.6721 2 9 9 9

17 2 1251.3 35.072 35.071 2 5.341 5.230 27.718 228.0 2 229.4 2 76.8 0.01 2 19.63 2 1.29 2 13.20 2 0.58 2 0.29 2 0.01 2 9 9 2171.1 2 7.7166 2 2318 2 2315 9 9

16 2 1450.6 35.031 35.031 2 4.602 4.480 27.773 254.8 2 252.5 2 59.4 0.00 2 18.26 2 1.21 2 12.20 2 0.90 2 0.44 2 0.03 2 9 747.0 386.6 2 2164.5 2 7.7192 2 2315 2 2309 9 9

15 2 1651.1 34.987 34.988 2 4.080 3.945 27.796 264.0 2 264.2 2 51.9 0.01 2 17.77 2 1.18 2 12.40 2 0.94 2 0.46 2 0.04 2 9 9 9 9 9 9 9

14 2 1850.3 34.986 34.987 2 3.880 3.729 27.818 266.9 2 266.0 2 51.8 0.00 2 17.77 2 1.18 2 13.70 2 0.62 2 0.31 2 0.02 2 9 724.8 362.0 2 2161.0 2 7.7369 2 2313 2 2312 9 9

13 2 2020.8 34.991 34.992 2 3.736 3.570 27.839 264.0 2 264.0 2 55.0 0.01 2 17.97 2 1.20 2 15.50 2 9 9 9 9 9 9 9 9 9 9

12 2 2201.6 34.982 34.982 2 3.532 3.352 27.855 265.6 2 264.6 2 56.2 0.01 2 18.07 2 1.21 2 17.30 2 0.20 2 0.11 2 0.02 2 9 716.2 351.2 2 2163.5 2 7.7378 2 2318 2 2316 9 9

11 2 2400.7 34.963 34.963 2 3.292 3.096 27.865 268.3 2 267.5 2 55.3 0.01 2 17.97 2 1.21 2 18.30 2 0.26 2 0.13 2 0.02 2 0.74 2 9 2163.3 2 7.7403 2 2317 2 2316 9 9

10 2 2599.2 34.954 34.954 2 3.112 2.900 27.876 264.6 2 267.9 2 56.5 0.01 2 17.97 2 1.22 2 19.70 2 0.24 2 0.12 2 0.01 2 9 9 9 9 9 9 9

9 2 2799.8 34.940 34.940 2 2.918 2.690 27.885 269.0 2 270.5 2 55.7 0.01 2 17.77 2 1.21 2 20.30 2 0.35 2 0.17 2 0.02 2 0.80 2 715.6 340.4 2 2164.7 2 7.7401 2 2320 2 2318 9 9

8 2 3000.2 34.932 34.932 2 2.767 2.521 27.894 272.6 2 271.3 2 56.3 0.00 2 17.87 2 1.21 2 21.60 2 0.36 2 0.18 2 0.01 2 9 9 9 9 9 9 9

7 2 3201.3 34.922 34.923 2 2.636 2.372 27.900 275.3 2 272.9 2 56.0 0.01 2 17.68 2 1.21 2 21.80 2 0.44 2 0.22 2 0.02 2 0.93 2 9 2166.0 2 7.7407 2 2319 2 2319 9 9

6 2 3481.7 34.913 34.915 2 2.489 2.199 27.909 275.7 2 274.1 2 56.2 0.01 2 17.77 2 1.21 2 23.40 2 0.41 6 0.21 6 0.02 6 9 728.4 339.4 2 2167.2 2 7.7381 2 2321 2 2319 9 9

5 2 3801.0 34.906 34.906 2 2.385 2.062 27.916 276.0 2 274.3 2 57.2 0.01 2 17.87 2 1.22 2 25.20 2 0.43 2 0.22 2 0.02 2 0.98 2 9 2169.5 2 7.7380 2 2322 2 2322 9 9

4 2 4198.5 34.898 34.898 2 2.322 1.956 27.921 274.6 2 272.5 2 59.9 0.01 2 18.17 2 1.24 2 27.70 2 0.45 2 0.22 2 0.02 2 0.99 6 9 2173.6 2 7.7335 2 2325 2 2324 9 9

3 2 4600.6 34.892 34.892 2 2.299 1.886 27.925 272.3 2 270.2 2 62.8 0.01 2 18.75 2 1.28 2 31.10 2 0.38 2 0.19 2 0.04 2 9 735.4 338.9 2 2177.6 2 7.7324 2 2328 2 2328 9 9

2 2 4999.8 34.884 34.883 2 2.273 1.811 27.927 267.9 2 266.2 2 67.5 0.01 2 19.53 2 1.34 2 36.80 2 0.22 2 0.12 2 0.03 2 0.60 2 9 9 9 9 9 9

1 2 5465.3 34.853 34.854 2 2.101 1.586 27.922 252.5 2 255.3 6 80.4 0.01 6 22.07 2 1.53 6 52.30 6 0.04 2 0.03 2 0.01 2 0.22 2 780.2 355.0 2 2201.9 2 9 2350 2 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

165
A5R

NOAA Ship Ronald H. Brown

STATION 97 DATE 2/18/1998 LATITUDE 26.501° N

LONGITUDE 72.100° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.0 36.786 36.785 2 23.140 23.139 25.250 213.5 2 214.4 2 -3.9 0.00 2 0.00 2 0.00 2 0.60 2 9 9 9 9 280.1 317.3 2 2039.3 2 8.0918 2 5 2397 9 9

35 2 45.6 36.787 36.786 2 23.151 23.142 25.253 212.9 2 214.6 2 -4.2 0.00 2 0.00 2 0.01 2 0.60 2 9 9 9 9 9 9 9 9 9 9

34 2 88.0 36.774 36.774 2 23.071 23.053 25.272 213.2 2 214.6 2 -3.8 0.00 2 0.00 2 0.01 2 0.60 2 9 9 9 9 280.5 316.9 2 2039.8 2 8.0981 2 2397 2 2402 9 9

33 2 133.8 36.970 36.963 2 22.289 22.262 25.651 210.7 2 205.5 2 7.9 0.05 2 0.29 2 0.01 2 0.50 2 9 9 9 9 323.4 354.2 2 2076.6 2 8.0407 2 2412 2 2403 9 9

32 2 179.6 36.815 36.814 2 20.492 20.458 26.035 195.9 2 198.7 2 21.9 0.02 2 0.98 2 0.03 2 0.50 2 9 9 9 9 9 9 9 9 9 9

31 2 200.2 36.741 36.742 2 19.808 19.771 26.162 196.2 2 198.7 2 24.8 0.02 2 1.37 2 0.04 2 0.60 2 9 9 9 9 9 9 9 9 9 9

30 2 223.9 36.672 36.674 2 19.183 19.142 26.275 193.9 2 197.6 2 28.6 0.01 2 2.15 2 0.07 2 0.80 2 9 9 9 9 9 9 9 9 9 9

29 2 250.1 36.616 36.619 2 18.729 18.684 26.351 195.7 2 200.9 2 27.3 0.01 2 2.83 2 0.11 2 0.90 2 9 9 9 9 376.2 357.3 2 2093.1 2 7.9990 2 2390 2 2390 9 9

28 2 271.7 36.592 36.590 2 18.529 18.481 26.384 198.7 2 204.4 2 24.7 0.01 2 3.12 2 0.12 2 0.90 2 9 9 9 9 9 9 9 9 9 9

27 2 298.9 36.571 36.571 2 18.357 18.304 26.414 201.7 2 206.1 2 23.8 0.01 2 3.32 2 0.14 2 1.00 2 9 9 9 9 9 9 9 9 9 9

26 2 348.5 36.541 36.541 2 18.119 18.058 26.455 204.6 2 207.0 2 24.0 0.01 2 3.80 2 0.17 2 1.20 2 9 9 9 9 9 9 9 9 9 9

25 2 400.1 36.508 36.509 2 17.898 17.829 26.489 205.8 2 205.6 2 26.4 0.01 2 4.29 2 0.20 2 1.30 2 9 9 9 9 388.1 356.4 2 2096.2 2 7.9839 2 2384 2 2383 9 9

24 2 450.3 36.383 36.390 2 17.195 17.119 26.567 195.0 2 191.3 2 44.0 0.01 2 6.73 2 0.34 2 2.00 2 9 9 9 9 9 9 9 9 9 9

23 2 500.0 36.256 36.252 2 16.491 16.409 26.639 187.3 2 182.8 2 56.0 0.01 2 8.68 2 0.47 2 2.60 2 9 9 9 9 9 9 9 9 9 9

22 2 543.6 36.123 36.116 2 15.719 15.632 26.716 180.8 2 177.7 2 65.0 0.01 2 10.44 2 0.59 2 3.40 2 9 9 9 9 488.8 410.7 2 2129.2 2 7.8941 2 2364 2 2363 9 9

21 2 600.8 35.949 35.955 2 14.536 14.445 26.846 178.1 2 176.2 2 72.5 0.01 2 12.20 2 0.71 2 4.20 2 9 9 9 9 9 9 9 9 9 9

20 2 700.2 35.671 35.672 2 12.695 12.598 27.013 164.3 2 164.8 2 94.0 0.01 2 16.49 2 1.00 2 6.80 2 9 9 9 9 9 9 9 9 9 9

19 2 748.9 35.576 35.581 2 11.902 11.802 27.094 163.1 2 165.1 2 98.2 0.01 2 17.67 2 1.08 2 7.70 2 9 9 9 9 647.3 464.0 2 2158.4 2 7.7828 2 2336 2 2334 9 9

18 2 801.5 35.419 35.422 2 10.838 10.737 27.168 149.3 2 150.8 2 118.8 0.01 2 20.89 2 1.31 2 10.30 2 9 9 9 9 9 9 9 9 9 9

17 2 848.5 35.318 35.317 2 10.069 9.966 27.224 149.0 2 146.9 2 127.5 0.01 2 22.84 2 1.44 2 12.20 2 9 9 9 9 780.6 518.4 2 2178.5 2 7.7107 2 2326 2 2321 9 9

16 2 899.1 35.191 35.194 2 8.924 8.823 27.312 148.1 2 149.8 6 131.8 0.01 2 24.31 2 1.56 2 14.40 2 9 9 9 9 830.1 524.9 2 2187.4 6 7.6855 2 2322 2 2319 9 9

15 3 998.3 35.074 2 7.320 7.219 27.461 159.8 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

14 2 1249.5 35.072 35.073 2 5.430 5.318 27.708 228.6 2 227.7 2 77.9 0.01 2 19.72 2 1.31 2 13.30 2 9 9 9 9 770.9 415.1 2 2171.2 2 9 2320 2 9 9

13 2 1498.2 35.012 35.011 2 4.398 4.273 27.780 255.7 2 257.1 2 56.4 0.01 2 18.16 2 1.21 2 12.60 2 9 9 9 9 733.7 375.8 2 2160.6 2 7.7294 2 5 2309 9 9

12 2 1749.5 34.982 34.982 2 3.957 3.814 27.806 264.6 2 266.0 2 51.1 0.01 2 17.87 2 1.19 2 13.20 2 9 9 9 9 9 9 9 9 9 9

11 2 1998.0 35.001 35.001 2 3.812 3.647 27.840 260.1 2 262.2 2 56.2 0.01 2 18.26 2 1.22 2 15.90 2 9 9 9 9 725.6 361.1 6 2161.1 2 9 2326 2 9 9

10 2 2299.1 34.967 34.968 2 3.367 3.180 27.860 265.3 2 267.2 2 55.0 0.01 2 18.16 2 1.21 2 17.80 2 9 9 9 9 9 9 9 9 9 9

9 2 2596.6 34.950 34.951 2 3.069 2.858 27.877 266.0 2 268.5 2 56.3 0.01 2 18.16 2 1.23 2 19.70 2 9 9 9 9 9 9 9 9 9 9

8 2 2950.3 34.934 34.934 2 2.794 2.553 27.893 268.2 2 270.5 2 56.8 0.01 2 18.16 2 1.23 2 21.70 2 9 9 9 9 9 9 9 9 9 9

7 2 3248.6 34.921 34.920 2 2.574 2.307 27.904 271.0 2 272.4 2 57.0 0.01 2 18.07 2 1.23 2 23.40 2 9 9 9 9 9 9 9 9 9 9

6 2 3599.5 34.908 34.908 2 2.418 2.117 27.912 274.1 2 275.1 2 55.9 0.01 2 17.67 2 1.21 2 23.70 2 9 9 9 9 9 9 9 9 9 9

5 2 3946.8 34.901 34.900 2 2.334 1.996 27.918 273.1 2 274.4 2 57.7 0.01 2 17.97 2 1.24 2 26.30 2 9 9 9 9 9 9 9 9 9 9

4 2 4298.8 34.897 34.895 2 2.306 1.929 27.923 270.4 2 272.2 2 60.4 0.01 2 18.36 2 1.27 2 29.20 2 9 9 9 9 9 9 9 9 9 9

3 2 4648.4 34.891 34.890 2 2.291 1.872 27.925 268.5 2 269.5 2 63.6 0.01 2 18.85 2 1.31 2 32.20 2 9 9 9 9 9 9 9 9 9 9

2 2 4997.8 34.880 34.880 2 2.249 1.788 27.926 263.8 2 265.3 2 68.6 0.01 2 19.82 2 1.37 2 37.90 2 9 9 9 9 9 9 9 9 9 9

1 2 5352.3 34.855 34.855 2 2.093 1.593 27.922 251.0 2 256.6 2 79.0 0.01 6 21.97 6 1.54 6 51.20 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

166
A5R

NOAA Ship Ronald H. Brown

STATION 98 DATE 2/18/1998 LATITUDE 26.501° N

LONGITUDE 72.467° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.0 36.781 36.780 2 23.201 23.200 25.229 216.3 2 215.4 2 -5.2 0.00 2 0.00 2 0.01 2 4 1.97 2 1.13 2 0.16 2 1.96 2 276.8 314.3 2 2043.1 6 8.0972 2 2413 2 2405 68.7 2 4.4 2

35 2 30.0 36.781 36.781 2 23.171 23.165 25.240 216.1 2 215.0 2 -4.6 0.00 2 0.00 2 0.01 2 4 9 9 9 9 278.2 315.6 2 2043.0 2 9 2413 2 68.5 2 4.2 2

34 2 100.2 36.779 36.780 2 23.124 23.103 25.261 217.1 2 214.9 2 -4.3 0.00 2 0.00 2 0.01 2 4 1.96 2 1.12 2 0.16 2 9 279.1 316.0 2 2045.8 2 8.0981 2 5 2409 67.3 2 4.3 2

33 2 129.2 36.892 36.883 2 22.105 22.079 25.643 207.0 2 206.7 2 7.5 0.06 2 0.20 2 0.02 2 4 9 9 9 9 318.8 346.7 2 2079.3 2 8.0527 2 2409 2 2414 56.8 2 4.2 2

32 2 170.8 36.837 36.831 2 20.473 20.441 26.055 197.7 2 198.9 2 21.7 0.02 2 0.98 2 0.03 2 4 2.22 2 1.25 2 0.10 2 9 356.7 363.3 2 2095.7 2 8.0172 2 2407 2 2407 51.9 2 9

31 2 200.7 36.705 36.709 2 19.502 19.465 26.215 197.3 2 201.5 2 23.3 0.01 2 1.46 2 0.05 2 0.80 2 2.28 2 1.28 2 0.07 2 9 9 2095.1 2 8.0081 2 2398 2 2399 51.3 2 5.2 2

30 2 225.7 36.665 36.665 2 19.178 19.137 26.271 197.5 2 198.9 2 27.3 0.01 2 2.24 2 0.07 2 0.80 2 9 9 9 9 370.7 358.3 2 2097.3 2 8.0013 2 2395 2 2397 50.0 2 9

29 2 250.0 36.625 36.625 2 18.766 18.721 26.348 198.4 2 199.9 2 28.1 0.01 2 2.93 2 0.10 2 0.90 2 2.29 2 1.27 2 0.03 2 9 9 2098.7 2 7.9946 2 9 2394 48.1 2 9

28 2 270.9 36.593 36.592 2 18.553 18.505 26.379 198.6 2 201.1 2 27.9 0.01 2 3.32 2 0.13 2 0.80 2 2.35 2 1.28 2 0.03 2 9 376.7 355.4 2 2099.7 2 7.9947 2 2392 2 2395 9 9

27 2 300.5 36.568 36.572 2 18.348 18.295 26.414 200.8 2 203.2 2 26.7 0.01 2 3.51 2 0.14 2 0.80 2 2.34 2 1.28 2 0.03 2 9 9 2095.8 2 7.9930 2 2390 2 2389 46.5 2 7.1 2

26 2 350.3 36.534 36.533 2 18.098 18.037 26.455 203.3 2 203.6 2 27.5 0.01 2 4.20 2 0.18 2 1.00 2 2.32 6 1.27 6 0.03 6 9 387.0 358.3 2 2099.7 2 7.9864 2 2387 2 2389 9 9

25 2 399.5 36.478 36.491 2 17.742 17.673 26.503 196.1 2 201.1 2 31.6 0.01 2 4.88 2 0.23 2 1.30 2 2.27 2 1.24 2 0.04 2 9 9 2104.0 2 9 2385 2 46.0 2 9

24 2 449.2 36.395 36.398 2 17.253 17.177 26.562 194.1 2 190.4 2 44.7 0.01 2 6.73 2 0.33 2 1.70 2 2.17 2 1.16 2 0.02 2 9 429.4 384.2 2 2113.6 2 7.9464 2 2380 2 2378 9 9

23 2 501.1 36.227 2 16.266 16.184 26.669 187.2 2 9 9 9 9 9 9 9 9 9 9 9 9 9 45.0 2 12.2 2

22 2 599.8 35.926 35.938 2 14.390 14.300 26.859 177.3 2 174.4 6 75.1 0.01 2 12.59 2 0.71 2 4.20 2 1.74 2 0.90 2 0.03 2 9 535.0 425.4 2 2140.3 2 7.8578 2 2356 2 2354 9 9

21 2 649.1 35.788 35.798 2 13.486 13.392 26.944 173.9 2 170.9 2 83.5 0.01 2 14.45 2 0.83 2 6.00 2 1.52 2 0.79 2 0.02 2 9 9 2148.6 2 9 2348 2 44.4 2 9

20 2 749.0 35.510 35.512 2 11.513 11.415 27.115 160.2 2 156.2 2 109.4 0.00 2 19.34 2 1.17 2 8.80 2 0.89 2 0.46 2 0.02 2 9 684.9 483.1 2 2167.4 2 7.7603 2 5 2332 9 9

19 2 849.6 35.259 35.253 2 9.565 9.465 27.262 153.3 2 149.0 2 128.5 0.01 2 23.54 2 1.49 2 13.20 2 0.48 2 0.25 2 0.01 2 9 809.3 526.0 2 2185.4 2 7.6966 2 2330 2 2322 41.4 2 25.4 2

18 2 950.6 35.108 35.109 2 7.902 7.802 27.403 152.5 2 156.2 2 132.1 0.00 2 25.01 2 1.62 2 15.90 2 0.32 6 0.17 6 0.01 6 9 857.0 518.7 2 2193.6 2 7.6701 2 2324 2 2319 9 9

17 2 1048.2 35.079 35.079 2 6.904 6.800 27.523 178.0 2 177.2 2 117.9 0.00 2 23.84 2 1.56 2 15.80 2 0.34 2 0.17 2 0.01 2 9 846.3 489.2 2 2189.0 6 7.6783 2 5 2317 41.4 2 9

16 2 1248.7 35.072 35.073 2 5.343 5.232 27.718 231.8 2 230.2 2 76.0 0.00 2 19.63 2 1.28 2 12.80 2 0.63 2 0.31 2 0.02 2 9 768.3 411.9 2 2174.2 2 7.7161 2 2325 2 2318 9 9

15 2 1450.4 35.019 35.019 2 4.487 4.366 27.776 256.6 2 255.0 2 57.8 0.01 2 18.37 2 1.20 2 12.10 2 0.90 2 0.44 2 0.04 2 9 9 2165.7 2 7.7287 2 2320 2 2314 41.2 2 20.2 2

14 2 1643.2 34.986 34.988 2 4.047 3.913 27.798 265.9 2 264.8 2 51.5 0.01 2 17.88 2 1.17 2 12.40 2 9 9 9 1.57 2 734.4 370.0 2 2162.5 2 7.7319 2 2317 2 2312 9 9

13 2 1849.1 34.981 34.982 2 3.824 3.673 27.819 268.7 2 267.1 2 51.1 0.01 2 17.78 2 1.18 2 13.60 2 0.68 2 0.34 2 0.03 2 1.36 2 9 2161.8 2 7.7353 2 9 2313 42.6 2 9

12 2 2048.6 34.982 34.983 2 3.644 3.477 27.841 267.1 2 266.1 2 53.7 0.01 2 18.07 2 1.19 2 15.40 2 0.35 2 0.18 2 0.02 2 9 726.6 358.7 2 2160.2 2 7.7380 2 9 2312 9 9

11 2 2252.1 34.962 34.963 2 3.379 3.197 27.853 269.4 2 269.4 2 52.6 0.01 2 17.88 2 1.18 2 16.30 2 0.47 2 0.23 2 0.02 2 1.04 2 9 2161.0 2 7.7385 2 9 2313 41.5 2 19.9 2

10 2 2449.2 34.957 34.959 2 3.283 3.083 27.862 269.6 2 269.5 2 53.5 0.01 2 17.78 2 1.19 2 17.10 2 0.44 2 0.22 2 0.02 2 9 9 2161.0 2 7.7380 2 9 2313 9 9

9 2 2631.9 34.953 34.954 2 3.142 2.926 27.874 268.5 2 269.1 2 55.1 0.01 2 17.98 2 1.20 2 19.10 2 0.30 2 0.15 2 0.01 2 0.80 2 718.1 345.5 2 2161.9 2 7.7399 2 2317 2 2315 41.4 2 9

8 2 2826.8 34.940 34.940 2 2.932 2.701 27.884 270.2 2 271.3 2 54.8 0.01 2 17.88 2 1.19 2 19.90 2 0.41 2 0.20 2 0.01 2 9 724.4 345.1 2 2162.7 2 7.7390 2 9 2315 9 9

7 2 3049.2 34.930 34.929 2 2.766 2.515 27.894 272.8 2 274.3 2 53.4 0.01 2 17.59 2 1.18 2 20.30 2 0.51 2 0.25 2 0.02 2 1.02 2 9 2161.0 2 9 9 41.4 2 19.5 2

6 2 3349.8 34.916 34.916 2 2.548 2.271 27.904 274.8 2 276.0 2 53.7 0.01 2 17.49 2 1.18 2 21.70 2 0.61 6 0.30 6 0.02 6 9 725.5 339.2 2 2162.8 2 7.7363 2 9 2314 9 9

5 2 3649.6 34.907 34.906 2 2.400 2.094 27.913 275.9 2 276.1 2 55.1 0.01 2 17.59 2 1.20 2 24.00 2 0.67 2 0.33 2 0.03 2 1.24 2 9 2165.1 2 7.7316 2 2320 2 2314 41.4 2 9

4 2 3935.6 34.901 34.901 2 2.341 2.004 27.918 273.4 2 274.5 2 57.5 0.01 2 17.88 2 1.21 2 26.30 2 0.60 2 0.29 2 0.03 2 1.17 6 730.3 337.6 2 2168.3 2 9 9 9 9

3 2 4348.8 34.895 34.894 2 2.295 1.912 27.923 272.4 2 272.3 2 60.5 0.01 2 18.37 2 1.26 2 29.50 2 0.49 2 0.24 2 0.03 2 0.99 2 9 2173.1 2 7.7281 2 9 2321 41.4 2 9

2 2 4730.6 34.889 34.889 2 2.280 1.851 27.925 268.9 2 268.6 2 64.7 0.01 2 19.05 2 1.31 2 33.60 2 0.31 2 0.16 2 0.02 2 0.78 2 744.6 342.8 2 2178.1 2 7.7290 2 9 2327 9 9

1 2 5262.9 34.869 34.870 2 2.193 1.701 27.925 259.1 2 261.0 2 73.7 0.01 6 20.81 6 1.44 6 43.90 6 0.13 2 0.07 2 0.02 2 0.39 2 762.5 348.9 6 2191.6 2 7.7213 2 2347 2 2338 42.7 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

167
A5R

NOAA Ship Ronald H. Brown

STATION 99 DATE 2/18/1998 LATITUDE 26.500° N

LONGITUDE 72.850° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 5.4 36.781 36.780 2 23.575 23.574 25.119 212.9 2 214.7 2 -5.8 0.00 2 0.00 2 0.01 2 4 9 9 9 9 285.4 328.8 6 2042.8 6 8.0997 6 2423 3 2407 9 9

35 2 51.0 36.788 36.788 2 23.314 23.303 25.206 214.5 2 214.9 2 -5.0 0.00 2 0.00 2 0.01 2 4 9 9 9 9 9 9 9 9 9 9

34 2 99.8 36.804 36.811 2 23.159 23.138 25.270 212.7 2 213.6 2 -3.2 0.01 2 0.00 2 0.02 2 4 9 9 9 9 9 9 9 9 9 9

33 2 152.7 36.856 36.853 2 20.940 20.911 25.941 199.5 2 201.3 2 17.4 0.03 2 0.59 2 0.03 2 4 9 9 9 9 9 9 9 9 9 9

32 2 201.3 36.706 36.698 2 19.533 19.496 26.208 198.1 2 199.0 2 25.6 0.01 2 1.76 2 0.06 2 1.70 3 9 9 9 9 9 9 9 9 9 9

31 2 224.5 36.643 36.642 2 18.971 18.931 26.307 198.8 2 199.6 2 27.5 0.01 2 2.44 2 0.09 2 1.80 3 9 9 9 9 9 9 9 9 9 9

30 2 250.6 36.609 36.606 2 18.657 18.612 26.363 199.5 2 200.7 2 27.8 0.01 2 2.93 2 0.11 2 1.80 3 9 9 9 9 9 9 9 9 9 9

29 2 275.3 36.585 36.584 2 18.474 18.425 26.393 205.4 2 204.4 2 24.9 0.01 2 3.12 2 0.12 2 1.80 3 9 9 9 9 9 9 9 9 9 9

28 2 301.1 36.562 36.563 2 18.311 18.258 26.419 207.2 2 207.2 2 22.9 0.01 2 3.22 2 0.14 2 1.80 3 9 9 9 9 9 9 9 9 9 9

27 2 350.1 36.535 36.534 2 18.079 18.018 26.461 207.6 2 208.3 2 22.8 0.01 2 3.61 2 0.17 2 2.00 3 9 9 9 9 9 9 9 9 9 9

26 2 401.0 36.468 36.468 2 17.691 17.622 26.508 203.8 2 199.7 2 33.3 0.01 2 5.07 2 0.24 2 2.00 3 9 9 9 9 9 9 9 9 9 9

25 2 450.6 36.383 36.377 2 17.194 17.118 26.567 193.9 2 192.0 2 43.4 0.01 2 6.63 2 0.33 2 2.40 3 9 9 9 9 9 9 9 9 9 9

24 2 500.3 36.245 36.245 2 16.358 16.276 26.661 183.4 2 182.6 2 56.8 0.01 2 8.68 2 0.47 2 2.80 3 9 9 9 9 9 9 9 9 9 9

23 2 540.7 36.133 36.129 2 15.686 15.600 26.731 183.7 2 179.7 2 63.1 0.01 2 10.05 2 0.56 2 3.40 3 9 9 9 9 9 9 9 9 9 9

22 2 599.7 35.928 35.915 2 14.449 14.359 26.848 174.8 2 172.9 2 76.3 0.01 2 12.79 2 0.74 2 4.90 3 9 9 9 9 9 9 9 9 9 9

21 2 700.4 35.632 35.628 2 12.421 12.325 27.037 159.7 2 160.2 2 100.1 0.01 2 17.38 2 1.04 2 7.50 2 9 9 9 9 9 9 9 9 9 9

20 2 799.3 35.362 35.367 2 10.379 10.281 27.204 151.5 2 152.2 2 120.2 0.01 2 21.58 2 1.34 2 11.10 2 9 9 9 9 9 9 9 9 9 9

19 2 901.8 35.149 35.149 2 8.420 8.322 27.358 153.9 2 152.0 2 132.9 0.01 2 24.71 2 1.59 2 15.40 2 9 9 9 9 9 9 9 9 9 9

18 2 1001.0 35.104 35.102 2 7.262 7.161 27.493 170.1 2 174.5 2 118.1 0.01 2 23.44 2 1.53 2 15.50 2 9 9 9 9 9 9 9 9 9 9

17 2 1199.8 35.078 35.078 2 5.512 5.405 27.702 222.7 2 225.6 2 79.3 0.01 2 19.73 2 1.30 2 13.30 2 9 9 9 9 9 9 9 9 9 9

16 2 1398.5 35.031 35.031 2 4.641 4.523 27.767 250.6 2 251.5 2 60.1 0.00 2 18.26 2 1.21 2 12.50 2 9 9 9 9 9 9 9 9 9 9

15 2 1600.9 34.990 34.991 2 4.097 3.966 27.796 262.1 2 264.0 2 51.9 0.01 2 17.78 2 1.17 2 12.70 2 9 9 9 9 9 9 9 9 9 9

14 2 1801.3 34.974 34.974 2 3.854 3.708 27.810 268.6 2 268.3 2 49.7 0.00 2 17.58 2 1.17 2 13.20 2 9 9 9 9 9 9 9 9 9 9

13 2 2000.0 34.970 34.969 2 3.656 3.494 27.829 268.4 2 269.2 2 50.5 0.01 2 17.58 2 1.17 2 14.50 2 9 9 9 9 9 9 9 9 9 9

12 2 2200.0 34.969 34.970 2 3.506 3.327 27.847 266.6 2 268.5 2 52.5 0.01 2 17.68 2 1.18 2 15.90 2 9 9 9 9 9 9 9 9 9 9

11 2 2400.0 34.960 34.959 2 3.284 3.089 27.863 268.1 2 269.0 2 53.9 0.01 2 17.68 2 1.19 2 17.50 2 9 9 9 9 9 9 9 9 9 9

10 2 2600.7 34.950 34.949 2 3.101 2.889 27.874 270.7 2 270.1 2 54.4 0.01 2 17.68 2 1.19 2 18.90 2 9 9 9 9 9 9 9 9 9 9

9 2 2799.2 34.941 34.941 2 2.939 2.710 27.884 270.1 2 271.3 2 54.7 0.01 2 17.68 2 1.20 2 20.00 2 9 9 9 9 9 9 9 9 9 9

8 2 3000.3 34.932 34.932 2 2.785 2.539 27.893 271.8 2 272.9 2 54.6 0.01 2 17.58 2 1.19 2 20.60 2 9 9 9 9 9 9 9 9 9 9

7 2 3291.5 34.919 34.918 2 2.582 2.310 27.904 272.5 2 274.9 2 54.5 0.01 2 17.39 2 1.19 2 21.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3593.7 34.908 34.908 2 2.433 2.132 27.911 277.5 2 276.1 2 54.8 0.01 2 17.39 2 1.19 2 23.30 2 9 9 9 9 9 9 9 9 9 9

5 2 3900.4 34.902 34.901 2 2.344 2.011 27.917 280.2 2 275.5 2 56.4 0.01 2 17.68 2 1.21 2 25.70 2 9 9 9 9 9 9 9 9 9 9

4 2 4198.8 34.897 34.897 2 2.313 1.947 27.921 272.3 2 276.0 2 56.5 0.01 2 17.97 2 1.24 2 28.10 2 9 9 9 9 9 9 9 9 9 9

3 2 4499.8 34.892 34.891 2 2.288 1.887 27.923 272.3 2 271.6 2 61.4 0.01 2 18.46 2 1.27 2 30.90 2 9 9 9 9 9 9 9 9 9 9

2 2 4900.1 34.880 34.879 2 2.232 1.784 27.924 269.7 2 265.4 2 68.5 0.01 2 19.73 2 1.37 2 38.80 2 9 9 9 9 9 9 9 9 9 9

1 2 5214.9 34.855 34.853 2 2.070 1.588 27.920 254.5 2 256.4 6 79.3 0.01 6 21.88 6 1.53 6 52.00 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

168
A5R

NOAA Ship Ronald H. Brown

STATION 100 DATE 2/18/1998 LATITUDE 26.500° N

LONGITUDE 73.217° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.0 36.685 36.685 2 23.837 23.836 24.968 210.9 2 215.1 2 -7.0 0.00 2 0.00 2 0.01 2 0.90 2 1.93 2 1.12 2 0.15 2 1.96 2 280.6 326.5 2 2036.7 2 8.0970 2 2393 2 2397 9 9

35 2 40.8 36.756 36.759 2 23.486 23.477 25.131 212.9 2 212.3 2 -3.0 0.00 2 0.00 2 0.01 2 1.00 2 9 9 9 9 278.7 320.0 2 2038.2 2 8.1022 2 2398 2 2403 9 9

34 2 90.6 36.803 36.816 2 23.022 23.003 25.308 213.9 2 213.3 2 -2.4 0.01 2 0.10 2 0.01 2 0.80 2 2.00 2 1.14 2 0.15 2 9 289.9 326.8 2 2050.4 2 8.0875 2 2401 2 2407 9 9

33 2 141.4 36.843 36.844 2 20.901 20.874 25.941 193.7 2 200.4 2 18.5 0.03 2 0.78 2 0.03 2 0.90 2 2.26 2 1.28 2 0.12 2 9 9 9 9 9 9 9

32 2 200.6 36.663 36.661 2 19.123 19.087 26.281 195.4 2 198.5 2 27.9 0.01 2 2.34 2 0.07 2 0.80 2 2.29 2 1.28 2 0.04 2 9 374.9 361.9 2 2096.2 2 8.0005 2 2392 2 2395 9 9

31 2 225.2 36.618 36.617 2 18.753 18.713 26.343 198.7 2 202.9 2 25.1 0.01 2 2.73 2 0.09 2 1.20 2 2.34 2 1.31 2 0.04 2 9 9 9 9 9 9 9

30 2 251.2 36.590 36.587 2 18.521 18.476 26.383 202.6 2 203.0 2 26.1 0.01 2 3.22 2 0.12 2 1.00 2 9 9 9 9 9 9 9 9 9 9

29 2 272.9 36.570 36.568 2 18.358 18.310 26.410 206.3 2 205.0 2 24.8 0.01 2 3.41 2 0.13 2 1.10 2 2.34 2 1.30 2 0.03 2 9 376.5 352.2 2 2093.9 2 7.9951 2 2386 2 2388 9 9

28 2 299.8 36.558 36.557 2 18.238 18.185 26.434 207.1 2 207.9 2 22.5 0.01 2 3.41 2 0.14 2 1.10 2 9 9 9 9 9 9 9 9 9 9

27 2 350.6 36.540 36.540 2 18.073 18.012 26.465 206.8 2 209.8 2 21.4 0.01 2 3.61 2 0.16 2 1.10 2 2.34 2 1.30 2 0.04 2 9 371.9 344.0 2 2092.7 2 7.9946 2 2387 2 2387 9 9

26 2 400.8 36.501 36.496 2 17.865 17.796 26.491 203.9 2 203.7 2 28.5 0.01 2 4.58 2 0.21 2 1.30 2 9 9 9 9 9 9 9 9 9 9

25 2 451.1 36.393 36.396 2 17.277 17.201 26.555 191.1 2 193.7 2 41.3 0.01 2 6.34 2 0.31 2 1.70 2 2.25 6 1.23 6 0.04 6 9 9 2111.2 2 7.9534 2 2376 2 2380 9 9

24 2 500.3 36.253 36.255 2 16.487 16.405 26.638 187.6 2 185.9 2 52.9 0.01 2 8.39 2 0.43 2 2.40 2 9 9 9 9 9 9 9 9 9 9

23 2 550.0 36.104 36.101 2 15.597 15.510 26.730 180.3 2 179.8 2 63.5 0.01 2 10.24 2 0.56 2 3.00 2 1.95 2 1.03 2 0.03 2 9 492.8 412.1 2 2128.6 2 7.8954 2 9 2363 9 9

22 3 648.3 35.721 35.723 2 13.117 13.025 26.966 167.6 2 166.4 2 90.0 0.01 2 15.62 2 0.91 2 6.00 2 1.44 2 0.74 2 0.03 2 9 9 9 9 2362 2 9 9

21 3 752.0 35.393 35.394 2 10.657 10.563 27.177 153.3 2 152.2 2 118.5 0.01 2 21.18 2 1.30 2 10.20 2 0.74 2 0.38 2 0.01 2 9 735.7 500.7 2 2174.6 2 7.7318 2 2331 2 2326 9 9

20 2 850.9 35.177 35.181 2 8.753 8.658 27.327 151.6 2 149.1 2 133.6 0.01 2 24.51 2 1.56 2 14.20 2 0.37 2 0.19 2 0.01 2 9 838.1 526.1 2 2189.1 6 7.6814 2 2326 2 2319 9 9

19 2 950.3 35.071 35.071 2 7.360 7.264 27.452 161.9 2 159.8 2 132.2 0.01 2 25.29 2 1.65 2 16.50 2 0.23 2 0.12 2 0.01 2 9 879.4 519.6 2 2193.7 2 7.6641 2 2322 2 2317 9 9

18 2 1100.0 35.075 35.075 2 6.148 6.045 27.619 197.0 2 199.1 2 101.3 0.01 2 22.07 2 1.44 2 14.70 2 0.39 2 0.19 2 0.01 2 9 809.9 451.5 2 2182.7 2 7.6948 2 2323 2 2318 9 9

17 2 1300.9 35.047 35.048 2 4.932 4.820 27.746 242.0 2 242.3 2 67.0 0.01 2 18.75 2 1.22 2 12.10 2 0.84 2 0.41 2 0.03 2 9 9 9 9 9 9 9

16 2 1499.4 34.997 34.998 2 4.263 4.140 27.782 260.7 2 260.4 2 54.2 0.01 2 17.97 2 1.17 2 11.90 2 1.00 6 0.49 6 0.04 6 9 736.5 374.9 2 2162.6 2 7.7282 2 2316 2 2310 9 9

15 2 1700.0 34.986 34.987 2 3.985 3.846 27.805 265.6 2 265.3 2 51.6 0.01 2 17.77 2 1.16 2 12.60 2 0.80 2 0.39 2 0.03 2 9 9 9 9 9 9 9

14 2 1900.9 34.975 34.975 2 3.757 3.603 27.823 268.2 2 268.0 2 50.8 0.01 2 17.67 2 1.16 2 13.50 2 0.70 2 0.35 2 0.03 2 9 9 2159.1 2 7.7361 2 2318 2 2310 9 9

13 2 2099.7 34.970 34.970 2 3.578 3.407 27.839 268.3 2 268.8 2 51.5 0.01 2 17.67 2 1.16 2 14.70 2 0.54 2 0.27 2 0.02 2 9 716.4 352.4 2 2159.3 2 7.7374 2 2317 2 2311 9 9

12 2 2296.1 34.960 34.960 2 3.374 3.187 27.853 270.1 2 269.1 2 53.0 0.01 2 17.67 2 1.17 2 16.00 2 0.50 2 0.25 2 0.02 2 9 9 2159.0 2 7.7373 2 2319 2 2310 9 9

11 9 2498.5 34.952 2 3.178 2.975 27.867 269.5 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

10 2 2699.6 34.944 34.945 2 3.015 2.795 27.879 270.2 2 271.8 6 53.5 0.01 2 17.67 2 1.18 2 18.70 2 0.39 2 0.19 2 0.02 2 0.90 2 9 2161.3 2 7.7391 2 2323 2 2314 9 9

9 2 2900.6 34.934 34.935 2 2.839 2.602 27.889 272.2 2 272.0 2 54.9 0.01 2 17.48 2 1.18 2 19.80 2 0.44 2 0.21 2 0.02 2 0.94 2 9 9 9 9 9 9

8 2 3100.1 34.925 34.926 2 2.685 2.431 27.897 274.9 2 273.8 2 54.6 0.01 2 17.58 2 1.18 2 20.60 2 0.53 2 0.26 2 0.03 2 9 712.6 335.2 2 2162.2 2 7.7384 2 2321 2 2314 9 9

7 2 3298.7 34.916 34.916 2 2.571 2.298 27.902 277.5 2 275.6 2 53.9 0.01 2 17.28 2 1.16 2 20.70 2 0.75 2 0.36 2 0.03 2 1.32 2 9 9 9 9 9 9

6 2 3499.4 34.911 34.911 2 2.469 2.177 27.909 277.2 2 275.4 2 55.1 0.01 2 17.48 2 1.18 2 22.60 2 0.59 2 0.29 2 0.03 2 1.19 2 9 2164.0 2 7.7366 2 5 2315 9 9

5 2 3799.8 34.904 34.904 2 2.366 2.044 27.916 276.1 2 274.6 2 57.0 0.01 2 17.68 2 1.21 2 25.30 2 0.49 2 0.24 2 0.02 2 1.08 2 9 2167.1 2 7.7353 2 5 2318 9 9

4 2 4098.5 34.898 34.898 2 2.312 1.958 27.920 275.1 2 273.4 2 59.0 0.01 2 18.07 2 1.23 2 27.60 2 0.49 2 0.25 2 0.02 2 1.05 6 9 2170.0 2 7.7334 2 2329 2 2320 9 9

3 2 4401.9 34.893 34.893 2 2.283 1.894 27.923 272.7 2 271.2 2 61.7 0.01 2 18.55 2 1.27 2 30.70 2 0.41 2 0.21 2 0.02 2 0.91 2 738.2 340.1 2 2174.7 2 7.7317 2 5 2324 9 9

2 3 4699.2 34.887 34.887 2 2.262 1.838 27.925 269.7 2 268.0 2 65.4 0.01 2 19.14 2 1.31 2 34.60 2 0.31 2 0.16 2 0.03 2 0.76 2 9 9 9 9 9 9

1 2 5146.1 34.858 34.858 2 2.097 1.623 27.920 257.4 2 257.4 2 78.0 0.01 6 21.68 6 1.50 6 50.00 6 0.07 2 0.05 2 0.01 2 0.27 2 773.4 351.9 2 2195.3 2 7.7164 2 2347 2 2340 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

169
A5R

NOAA Ship Ronald H. Brown

STATION 101 DATE 2/19/1998 LATITUDE 26.500° N

LONGITUDE 73.583° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.9 36.657 36.657 2 22.271 22.270 25.403 216.3 2 219.8 2 -6.0 0.00 2 0.00 2 0.01 2 0.50 2 9 9 9 9 294.5 322.4 6 2042.2 6 8.0823 2 2394 2 2392 9 9

35 2 48.8 36.653 36.652 2 21.917 21.907 25.505 220.0 2 220.3 6 -5.1 0.01 2 0.00 2 0.02 2 0.50 2 9 9 9 9 295.4 318.9 2 9 8.0837 2 2390 2 9 9

34 2 100.6 36.564 36.574 2 21.247 21.227 25.629 220.7 2 221.1 2 -3.2 0.01 2 0.10 2 0.02 2 0.50 2 9 9 9 9 303.6 319.1 2 2044.9 2 8.0795 2 2392 2 2392 9 9

33 2 149.1 36.701 36.699 2 19.673 19.646 26.162 202.1 2 202.8 2 21.2 0.03 2 1.46 2 0.05 2 0.50 2 9 9 9 9 360.5 355.9 2 2090.0 2 8.0112 2 2394 2 2396 9 9

32 2 198.9 36.621 36.619 2 18.749 18.713 26.344 203.0 2 203.8 2 24.2 0.01 2 2.63 2 0.10 2 0.80 2 9 9 9 9 9 9 9 9 9 9

31 2 223.4 36.595 36.596 2 18.549 18.509 26.378 206.4 2 205.9 2 23.0 0.01 2 2.93 2 0.11 2 0.90 2 9 9 9 9 9 9 9 9 9 9

30 2 249.5 36.574 36.573 2 18.368 18.324 26.409 208.1 2 209.4 2 20.4 0.01 2 3.12 2 0.13 2 1.00 2 9 9 9 9 376.4 352.3 2 2091.3 2 8.0019 2 2392 2 2390 9 9

29 2 274.2 36.566 36.565 2 18.261 18.213 26.433 211.0 2 211.6 2 18.7 0.01 2 3.12 2 0.13 2 1.00 2 9 9 9 9 9 9 9 9 9 9

28 2 299.4 36.561 36.561 2 18.210 18.158 26.443 212.6 2 211.7 2 18.8 0.01 2 3.12 2 0.14 2 1.00 2 9 9 9 9 9 9 9 9 9 9

27 2 373.8 36.529 36.531 2 17.990 17.925 26.480 216.6 2 210.9 2 20.7 0.01 2 3.71 2 0.17 2 1.20 2 9 9 9 9 9 9 9 9 9 9

26 2 448.6 36.408 36.411 2 17.354 17.278 26.548 200.2 2 196.0 2 38.6 0.01 2 6.05 2 0.30 2 1.80 2 9 9 9 9 416.0 373.6 2 2108.1 2 9 2377 2 9 9

25 2 496.3 36.278 36.287 2 16.640 16.558 26.621 190.7 2 187.2 2 50.9 0.01 2 7.90 2 0.42 2 2.40 2 9 9 9 9 9 9 9 9 9 9

24 2 549.4 36.137 36.144 2 15.765 15.677 26.717 180.0 2 179.7 2 62.7 0.01 2 9.95 2 0.55 2 3.20 2 9 9 9 9 9 9 9 9 9 9

23 2 601.0 35.971 35.983 2 14.726 14.634 26.822 171.8 2 173.9 2 73.8 0.01 2 12.10 2 0.70 2 4.20 2 9 9 9 9 9 9 9 9 9 9

22 2 649.8 35.809 35.827 2 13.644 13.550 26.927 165.1 2 168.2 2 85.3 0.01 2 14.25 2 0.85 2 5.40 2 9 9 9 9 568.5 437.9 2 2146.6 2 7.8326 2 2352 2 2347 9 9

21 2 693.1 35.673 35.679 2 12.731 12.635 27.008 159.6 2 162.8 2 95.8 0.01 2 16.49 2 0.99 2 6.80 2 9 9 9 9 9 9 9 9 9 9

20 2 791.8 35.384 35.394 2 10.567 10.469 27.188 150.2 2 151.3 2 119.9 0.01 2 21.09 2 1.33 2 10.70 2 9 9 9 9 737.8 500.2 2 2175.1 2 7.7243 2 2329 2 2324 9 9

19 2 898.5 35.169 35.165 2 8.629 8.530 27.341 150.7 2 149.8 2 133.7 0.01 2 24.51 2 1.59 2 14.90 2 9 9 9 9 841.1 525.4 2 2188.4 2 7.6784 2 2325 2 2317 9 9

18 2 1000.5 35.072 35.077 2 7.257 7.156 27.468 168.6 2 165.3 2 127.4 0.01 2 24.61 2 1.62 2 16.40 2 9 9 9 9 866.4 509.2 2 2191.6 6 7.6653 2 2318 2 2315 9 9

17 2 1197.9 35.078 35.078 2 5.562 5.454 27.696 227.2 2 223.7 2 80.9 0.01 2 19.92 2 1.32 2 13.30 2 9 9 9 9 9 9 9 9 9 9

16 2 1397.2 35.033 35.034 2 4.669 4.551 27.766 251.6 2 250.2 2 61.2 0.01 2 18.36 2 1.22 2 12.50 2 9 9 9 9 744.0 386.2 2 2164.1 2 7.7249 2 2319 2 2311 9 9

15 2 1597.7 34.988 34.990 2 4.101 3.971 27.793 264.8 2 263.7 2 52.2 0.01 2 17.87 2 1.18 2 12.60 2 9 9 9 9 9 9 9 9 9 9

14 2 1797.1 34.976 34.976 2 3.836 3.690 27.813 269.0 2 268.1 2 50.0 0.01 2 17.58 2 1.18 2 13.40 2 9 9 9 9 9 9 9 9 9 9

13 2 1996.0 34.971 34.973 2 3.661 3.499 27.830 268.6 2 268.1 2 51.5 0.01 2 17.48 2 1.18 2 14.50 2 9 9 9 9 725.4 358.4 2 2159.6 2 7.7362 2 2312 2 2311 9 9

12 2 2199.2 34.971 34.971 2 3.496 3.317 27.849 267.7 2 267.7 2 53.4 0.01 2 17.77 2 1.19 2 16.20 2 9 9 9 9 9 9 9 9 9 9

11 2 2399.2 34.964 34.964 2 3.323 3.127 27.862 268.4 2 268.1 2 54.5 0.01 2 17.87 2 1.21 2 17.90 2 9 9 9 9 9 9 9 9 9 9

10 2 2598.2 34.952 34.953 2 3.139 2.927 27.873 269.5 2 269.2 2 55.0 0.01 2 17.77 2 1.21 2 18.70 2 9 9 9 9 9 9 9 9 9 9

9 2 2796.2 34.946 34.946 2 2.995 2.765 27.883 268.3 2 268.9 2 56.7 0.01 2 17.97 2 1.22 2 20.50 2 9 9 9 9 9 9 9 9 9 9

8 2 2999.9 34.931 34.931 2 2.803 2.556 27.891 274.2 2 273.4 2 53.9 0.01 2 17.48 2 1.19 2 19.90 2 9 9 9 9 9 9 9 9 9 9

7 2 3176.2 34.924 34.924 2 2.684 2.422 27.897 275.9 2 274.5 2 53.9 0.01 2 17.38 2 1.18 2 20.60 2 9 9 9 9 9 9 9 9 9 9

6 2 3397.9 34.916 34.916 2 2.543 2.260 27.906 276.2 2 275.5 2 54.3 0.01 2 17.28 2 1.19 2 21.80 2 9 9 9 9 9 9 9 9 9 9

5 2 3598.0 34.910 34.911 2 2.458 2.156 27.911 276.7 2 275.1 2 55.6 0.01 2 17.48 2 1.20 2 23.30 2 9 9 9 9 9 9 9 9 9 9

4 2 3799.0 34.904 34.905 2 2.373 2.051 27.916 276.3 2 274.7 2 56.9 0.01 2 17.68 2 1.21 2 25.00 2 9 9 9 9 9 9 9 9 9 9

3 2 4197.9 34.895 34.895 2 2.282 1.917 27.921 273.8 2 272.2 2 60.5 0.01 2 18.26 2 1.26 2 29.30 2 9 9 9 9 9 9 9 9 9 9

2 2 4600.1 34.886 34.886 2 2.244 1.833 27.923 269.2 2 267.7 2 65.8 0.01 2 19.14 2 1.32 2 34.90 2 9 9 9 9 9 9 9 9 9 9

1 2 5005.3 34.864 34.864 2 2.122 1.665 27.921 258.3 2 258.6 2 76.4 0.01 6 21.19 6 1.47 6 47.30 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

170
A5R

NOAA Ship Ronald H. Brown

STATION 102 DATE 2/19/1998 LATITUDE 26.500° N

LONGITUDE 73.967° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.6 36.672 36.668 2 21.985 21.984 25.495 218.3 2 220.3 2 -5.4 0.00 2 0.00 2 0.00 2 0.70 2 2.09 2 1.20 2 0.17 2 2.14 2 297.1 321.5 2 2047.7 6 8.0789 2 5 2396 63.4 2 9

35 2 17.2 36.675 36.674 2 21.865 21.862 25.533 219.9 2 220.5 2 -5.2 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 9 2046.4 2 9 2411 2 63.7 2 9

34 2 50.2 36.645 36.644 2 21.308 21.298 25.669 220.5 2 219.8 2 -2.3 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 299.3 315.4 2 2050.3 2 8.0740 2 2395 2 2395 60.8 2 9

33 2 75.1 36.641 36.640 2 21.193 21.178 25.700 220.8 2 219.8 2 -1.8 0.01 2 0.00 2 0.00 2 0.70 2 2.13 2 1.21 2 0.16 2 9 304.6 319.5 2 2050.6 2 8.0713 2 2395 2 2393 56.4 2 9

32 2 99.6 36.780 36.777 2 20.972 20.953 25.869 216.4 2 202.5 2 16.2 0.05 2 0.78 2 0.02 2 0.70 2 2.18 2 1.24 2 0.11 2 9 340.5 353.9 2 2080.6 2 8.0360 2 2403 2 2403 53.3 2 9

31 2 124.3 36.739 36.743 2 19.958 19.935 26.114 197.8 2 202.1 2 20.7 0.02 2 1.27 2 0.04 2 0.70 2 2.27 2 1.29 2 0.10 2 9 355.3 354.6 2 2090.1 2 8.0141 2 2400 2 2398 51.4 2 9

30 2 150.1 36.710 36.648 2 19.496 19.468 26.215 202.9 2 201.5 2 23.3 0.02 2 1.56 2 0.04 2 0.80 2 2.29 2 1.29 2 0.08 2 9 364.0 356.7 2 2093.5 6 8.0108 2 2398 2 2399 48.5 2 9

29 2 176.0 36.647 36.648 2 18.974 18.942 26.305 197.9 2 200.2 2 26.8 0.01 2 2.44 2 0.08 2 0.90 2 2.30 2 1.29 2 0.05 2 9 380.0 364.4 2 9 7.9997 2 2396 2 48.9 2 9

28 2 200.4 36.614 36.615 2 18.708 18.672 26.350 204.5 2 205.0 2 23.2 0.01 2 2.73 2 0.10 2 1.00 2 2.32 2 1.29 2 0.05 2 9 9 2089.9 2 8.0026 2 2392 2 2389 9 9

27 2 245.3 36.572 36.571 2 18.330 18.287 26.417 207.0 2 209.3 2 20.6 0.01 2 3.12 2 0.12 2 1.10 2 2.36 2 1.31 2 0.05 2 9 368.4 344.3 2 2089.7 2 8.0032 2 2390 2 2389 47.0 2 9

26 2 299.4 36.551 36.550 2 18.144 18.092 26.452 211.2 2 210.1 2 20.7 0.01 2 3.51 2 0.15 2 1.20 2 2.35 2 1.31 2 0.05 2 0.60 2 9 2091.2 2 7.9974 2 2388 2 2387 9 9

25 2 349.1 36.530 36.532 2 18.000 17.939 26.476 212.7 2 210.3 2 21.2 0.01 2 3.80 2 0.17 2 1.30 2 2.34 2 1.30 2 0.05 2 9 376.1 346.9 6 2092.2 2 9 2397 2 45.7 2 9

24 2 398.7 36.454 36.455 2 17.603 17.535 26.519 205.6 2 199.8 2 33.6 0.01 2 5.36 2 0.26 2 1.80 2 2.20 6 1.20 6 0.04 6 9 9 2101.8 2 7.9705 2 5 2381 9 9

23 2 500.8 36.237 36.246 2 16.364 16.282 26.654 185.4 2 183.9 2 55.5 0.01 2 8.68 2 0.47 2 2.80 2 2.03 2 1.08 2 0.03 2 9 457.4 394.2 2 2121.0 2 7.9197 2 5 2369 43.6 2 9

22 2 599.4 35.942 35.939 2 14.532 14.441 26.841 174.3 2 173.4 2 75.4 0.01 2 12.69 2 0.73 2 4.60 2 9 9 9 9 9 2139.1 2 7.8588 2 5 2353 9 9

21 2 694.0 35.650 35.654 2 12.563 12.467 27.022 163.1 2 162.3 2 97.2 0.01 2 16.98 2 1.03 2 7.10 2 1.21 2 0.62 2 0.01 2 9 629.6 463.2 2 2158.1 2 9 2359 2 42.5 2 9

20 2 800.0 35.336 35.341 2 10.174 10.077 27.218 149.5 2 150.1 2 123.6 0.01 2 22.06 2 1.40 2 11.70 2 0.61 2 0.32 2 0.01 2 9 764.9 509.5 2 2178.7 2 7.7176 2 5 2324 9 9

19 2 900.5 35.146 35.148 2 8.508 8.409 27.342 148.3 2 148.4 2 135.9 0.00 2 25.00 2 1.62 2 15.50 2 0.31 2 0.17 2 0.01 2 0.22 2 859.9 533.7 2 2191.3 2 7.6693 2 2324 2 2317 42.1 2 9

18 2 998.5 35.105 35.108 2 7.409 7.307 27.473 167.3 2 168.9 2 122.7 0.01 2 23.73 2 1.56 2 15.60 2 0.39 2 0.21 2 0.02 2 9 844.0 498.2 2 2187.3 6 7.6799 2 2323 2 2316 9 9

17 2 1199.2 35.083 35.082 2 5.513 5.406 27.706 223.6 2 224.1 2 80.8 0.01 2 19.92 2 1.32 2 13.80 2 0.51 2 0.26 2 0.02 2 9 762.1 410.7 2 2173.8 2 7.7147 2 5 2317 42.0 2 9

16 2 1400.3 35.034 35.034 2 4.672 4.554 27.766 250.3 2 250.1 2 61.2 0.01 2 18.45 2 1.23 2 12.70 2 0.84 2 0.42 2 0.03 2 1.40 2 9 2166.4 2 7.7258 2 2322 2 2314 9 9

15 2 1597.1 34.990 34.992 2 4.149 4.018 27.790 263.4 2 262.6 2 52.9 0.01 2 17.87 2 1.19 2 12.70 2 0.99 6 0.49 6 0.04 6 9 723.3 364.4 2 2160.8 2 7.7326 2 2311 2 2310 41.1 2 9

14 2 1793.2 34.975 34.976 2 3.873 3.727 27.809 267.9 2 267.5 2 50.3 0.01 2 17.67 2 1.18 2 13.40 2 0.88 2 0.43 2 0.04 2 9 9 2159.9 2 7.7355 2 2316 2 2311 9 9

13 2 1999.5 34.974 34.976 2 3.707 3.544 27.828 267.9 2 268.0 2 51.2 0.01 2 17.77 2 1.19 2 14.60 2 0.63 2 0.32 2 0.03 2 1.27 2 717.3 353.4 2 2159.9 2 7.7379 2 2312 2 2312 40.8 2 9

12 2 2200.8 34.970 34.970 2 3.514 3.334 27.846 268.3 2 268.3 2 52.6 0.01 2 17.77 2 1.20 2 16.00 2 9 9 9 9 9 2160.1 2 7.7377 2 9 2312 9 9

11 2 2400.8 34.960 34.961 2 3.300 3.104 27.862 268.4 2 268.7 2 54.1 0.01 2 17.77 2 1.21 2 17.70 2 0.38 2 0.20 2 0.02 2 9 717.5 346.3 2 2160.4 2 7.7392 2 9 2313 41.0 2 9

10 2 2599.7 34.951 34.952 2 3.149 2.936 27.871 269.0 2 270.1 2 54.1 0.01 2 17.77 2 1.20 2 18.60 2 0.39 2 0.20 2 0.02 2 0.90 2 9 2161.7 2 7.7380 2 9 2314 9 9

9 2 2799.8 34.941 34.943 2 2.970 2.741 27.881 270.6 2 271.6 2 54.2 0.01 2 17.67 2 1.20 2 19.50 2 0.41 2 0.20 2 0.02 2 9 720.5 341.9 2 2162.0 2 9 2315 2 41.0 2 9

8 2 2999.0 34.933 34.934 2 2.824 2.577 27.891 271.1 2 272.7 2 54.4 0.01 2 17.68 2 1.20 2 20.40 2 0.46 2 0.23 2 0.02 2 0.95 2 9 2161.8 2 7.7389 2 9 2314 9 9

7 2 3249.3 34.922 34.923 2 2.645 2.376 27.901 274.1 2 274.5 2 54.3 0.01 2 17.58 2 1.20 2 21.40 2 0.47 2 0.24 2 0.02 2 9 725.5 338.7 2 2162.2 2 9 2322 2 41.0 2 9

6 2 3498.0 34.911 34.912 2 2.465 2.174 27.909 275.3 2 275.6 2 54.9 0.01 2 17.58 2 1.20 2 23.00 2 0.57 2 0.28 2 0.02 2 1.14 6 9 2163.7 2 7.7370 2 9 2315 9 9

5 2 3746.9 34.903 34.904 2 2.360 2.044 27.915 274.6 2 275.3 2 56.3 0.01 2 17.68 2 1.22 2 25.30 2 0.58 2 0.29 2 0.02 2 1.14 2 9 2165.6 2 7.7350 2 2321 2 2316 41.6 2 9

4 2 3999.3 34.897 34.898 2 2.297 1.954 27.919 273.6 2 273.6 2 58.8 0.01 2 18.07 2 1.24 2 27.70 2 0.56 2 0.28 2 0.03 2 1.11 2 736.9 337.9 2 2169.6 2 9 9 9 9

3 2 4248.1 34.893 34.894 2 2.270 1.900 27.921 270.9 2 271.5 2 61.4 0.01 2 18.55 2 1.27 2 30.60 2 0.42 2 0.21 2 0.02 2 9 9 2173.0 2 7.7308 2 5 2322 41.6 2 9

2 2 4492.2 34.887 34.888 2 2.244 1.845 27.923 268.4 2 268.3 2 65.1 0.01 2 19.04 2 1.31 2 34.00 2 0.37 2 0.19 2 0.03 2 0.81 2 9 2177.9 2 7.7310 2 9 2328 9 9

1 2 4712.7 34.880 34.881 2 2.212 1.788 27.923 263.3 2 264.5 2 69.4 0.01 6 19.92 6 1.38 6 38.80 6 0.24 2 0.14 2 0.02 2 0.60 2 748.4 341.2 2 2184.2 2 7.7262 2 2337 2 2332 41.5 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

171
A5R

NOAA Ship Ronald H. Brown

STATION 103 DATE 2/19/1998 LATITUDE 26.500° N

LONGITUDE 74.251° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.7 36.639 36.638 2 21.938 21.937 25.483 220.7 2 222.4 6 -7.3 0.00 2 0.00 2 0.00 2 0.70 2 9 9 9 9 297.7 321.6 6 2045.9 2 8.0772 6 2400 2 2392 9 9

35 2 49.9 36.633 36.632 2 21.562 21.552 25.589 221.6 2 220.7 2 -4.1 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

34 2 99.6 36.682 36.682 2 21.132 21.113 25.751 218.5 2 213.1 2 5.1 0.12 2 0.39 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

33 2 145.4 36.770 36.769 2 20.250 20.223 26.062 199.0 2 197.8 2 23.8 0.02 2 1.37 2 0.04 2 0.70 2 9 9 9 9 9 9 9 9 9 9

32 2 200.5 36.665 36.662 2 19.038 19.002 26.304 193.6 2 192.8 2 34.0 0.01 2 2.93 2 0.09 2 0.90 2 9 9 9 9 9 9 9 9 9 9

31 2 224.8 36.617 36.616 2 18.694 18.654 26.357 195.5 2 196.3 2 32.0 0.01 2 3.32 2 0.12 2 1.00 2 9 9 9 9 9 9 9 9 9 9

30 2 247.4 36.581 36.580 2 18.439 18.395 26.397 198.1 2 201.6 2 27.8 0.01 2 3.61 2 0.14 2 1.10 2 9 9 9 9 9 9 9 9 9 9

29 2 274.9 36.564 36.563 2 18.292 18.244 26.423 208.3 2 207.0 2 23.1 0.01 2 3.51 2 0.14 2 1.10 2 9 9 9 9 9 9 9 9 9 9

28 2 299.4 36.556 36.556 2 18.203 18.151 26.441 209.9 2 208.9 2 21.6 0.01 2 3.41 2 0.14 2 1.10 2 9 9 9 9 9 9 9 9 9 9

27 2 349.1 36.533 36.533 2 18.035 17.974 26.469 209.9 2 208.2 2 23.1 0.01 2 3.80 2 0.18 2 1.30 2 9 9 9 9 9 9 9 9 9 9

26 2 400.0 36.488 36.490 2 17.793 17.724 26.499 204.2 2 202.5 2 30.0 0.01 2 4.78 2 0.22 2 1.50 2 9 9 9 9 9 9 9 9 9 9

25 2 449.3 36.389 36.398 2 17.250 17.174 26.558 191.6 2 192.3 2 42.8 0.01 2 6.54 2 0.33 2 2.00 2 9 9 9 9 9 9 9 9 9 9

24 2 499.6 36.205 36.213 2 16.193 16.112 26.668 186.0 2 182.8 2 57.4 0.01 2 9.07 2 0.49 2 2.90 2 9 9 9 9 9 9 9 9 9 9

23 2 550.3 36.063 36.072 2 15.348 15.262 26.754 180.7 2 178.1 2 66.4 0.01 2 10.83 2 0.61 2 3.70 2 9 9 9 9 9 9 9 9 9 9

22 2 599.4 35.926 35.920 2 14.506 14.415 26.834 173.6 2 173.5 2 75.4 0.01 2 12.69 2 0.74 2 4.80 2 9 9 9 9 9 9 9 9 9 9

21 2 649.8 35.742 35.747 2 13.258 13.165 26.954 168.2 2 167.6 2 88.0 0.01 2 15.23 2 0.91 2 6.20 2 9 9 9 9 9 9 9 9 9 9

20 2 699.9 35.625 35.630 2 12.378 12.282 27.039 160.3 2 160.6 2 100.0 0.00 2 17.28 2 1.05 2 7.40 2 9 9 9 9 9 9 9 9 9 9

19 2 749.4 35.467 35.468 2 11.185 11.089 27.141 156.5 2 154.8 2 112.7 0.00 2 19.91 2 1.23 2 9.60 2 9 9 9 9 9 9 9 9 9 9

18 2 798.3 35.331 35.338 2 10.170 10.073 27.215 151.6 2 150.7 2 123.0 0.00 2 22.06 2 1.38 2 11.70 2 9 9 9 9 9 9 9 9 9 9

17 2 900.3 35.158 35.162 2 8.418 8.320 27.364 154.6 2 154.6 2 130.3 0.00 2 24.02 2 1.56 2 14.80 2 9 9 9 9 9 9 9 9 9 9

16 2 1100.3 35.085 35.088 2 6.210 6.107 27.619 199.1 2 201.6 2 98.3 0.00 2 21.58 2 1.41 2 14.50 2 9 9 9 9 9 9 9 9 9 9

15 2 1300.6 35.068 35.068 2 5.116 5.003 27.742 237.1 2 237.5 2 70.4 0.00 2 19.04 2 1.26 2 13.00 2 9 9 9 9 9 9 9 9 9 9

14 2 1500.2 35.017 35.017 2 4.410 4.285 27.782 254.2 2 256.7 2 56.7 0.00 2 18.16 2 1.20 2 12.60 2 9 9 9 9 9 9 9 9 9 9

13 2 1697.4 34.980 34.979 2 3.981 3.843 27.801 266.4 2 266.5 2 50.4 0.00 2 17.68 2 1.18 2 12.70 2 9 9 9 9 9 9 9 9 9 9

12 2 1899.2 34.973 34.974 2 3.793 3.638 27.817 268.4 2 268.3 2 50.2 0.00 2 17.68 2 1.18 2 13.60 2 9 9 9 9 9 9 9 9 9 9

11 2 2098.7 34.968 34.968 2 3.600 3.429 27.835 268.6 2 269.5 2 50.7 0.00 2 17.97 2 1.20 2 16.90 2 9 9 9 9 9 9 9 9 9 9

10 2 2290.8 34.972 34.971 2 3.462 3.274 27.854 266.9 2 267.2 2 54.2 0.01 2 17.68 2 1.18 2 14.80 2 9 9 9 9 9 9 9 9 9 9

9 2 2491.3 34.958 34.958 2 3.252 3.048 27.866 268.2 2 269.1 2 54.1 0.00 2 17.68 2 1.20 2 17.90 2 9 9 9 9 9 9 9 9 9 9

8 2 2699.8 34.947 34.947 2 3.043 2.822 27.878 269.1 2 270.1 2 55.0 0.01 2 17.77 2 1.20 2 19.20 2 9 9 9 9 9 9 9 9 9 9

7 2 2898.4 34.938 34.937 2 2.869 2.632 27.889 269.1 2 271.3 2 55.4 0.01 2 17.68 2 1.21 2 20.70 2 9 9 9 9 9 9 9 9 9 9

6 2 3197.7 34.920 34.921 2 2.611 2.348 27.901 275.0 2 274.5 2 54.6 0.01 2 17.38 2 1.19 2 21.40 2 9 9 9 9 9 9 9 9 9 9

5 2 3496.2 34.909 34.908 2 2.418 2.128 27.911 274.4 2 275.4 2 55.5 0.01 2 17.58 2 1.20 2 23.70 2 9 9 9 9 9 9 9 9 9 9

4 2 3799.8 34.901 34.900 2 2.310 1.990 27.917 273.2 2 274.1 2 58.0 0.01 2 17.77 2 1.23 2 26.40 2 9 9 9 9 9 9 9 9 9 9

3 2 4099.3 34.895 34.894 2 2.266 1.913 27.921 272.6 2 272.3 2 60.5 0.01 2 18.26 2 1.26 2 29.50 2 9 9 9 9 9 9 9 9 9 9

2 2 4388.9 34.888 34.889 2 2.237 1.851 27.922 269.5 2 268.9 2 64.4 0.01 2 18.95 2 1.31 2 33.40 2 9 9 9 9 9 9 9 9 9 9

1 2 4605.0 34.880 34.881 2 2.202 1.791 27.922 263.9 2 264.6 2 69.3 0.01 6 19.73 6 1.38 6 38.50 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

172
A5R

NOAA Ship Ronald H. Brown

STATION 104 DATE 2/19/1998 LATITUDE 26.500° N

LONGITUDE 74.517° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.4 36.636 36.635 2 22.293 22.292 25.381 220.5 2 220.1 2 -6.3 0.00 2 0.00 2 0.00 2 0.40 2 2.07 2 1.19 2 0.16 2 2.09 2 289.9 317.5 2 2044.7 2 8.0789 2 2396 2 2392 64.1 2 9

35 2 40.8 36.635 36.631 2 21.635 21.627 25.569 220.7 2 220.8 6 -4.5 0.00 2 0.00 2 0.01 2 0.40 2 2.08 2 1.19 2 0.16 2 9 293.0 312.8 2 2045.6 2 8.0736 2 2393 2 2389 62.9 2 9

34 2 90.4 36.644 36.643 2 21.592 21.574 25.593 221.2 2 218.9 2 -2.4 0.03 2 0.10 2 0.01 2 0.30 2 2.10 2 1.20 2 0.18 2 2.02 6 9 9 9 9 60.9 2 9

33 2 120.4 36.638 36.610 2 21.217 21.194 25.696 218.6 2 217.2 2 0.8 0.18 2 0.10 2 0.02 2 0.30 2 2.14 2 1.22 2 0.16 2 9 305.2 320.5 2 2052.7 2 8.0652 2 2391 2 2391 57.9 2 9

32 2 182.0 36.767 36.763 2 19.964 19.930 26.139 193.6 2 194.0 2 28.8 0.01 2 1.56 2 0.05 2 0.40 2 2.28 2 1.30 2 0.06 2 0.61 6 9 9 9 9 52.0 2 9

31 2 210.3 36.698 36.696 2 19.337 19.299 26.254 192.6 2 192.6 2 32.9 0.01 2 2.34 2 0.08 2 0.60 2 2.28 2 1.27 2 0.04 2 9 373.8 364.0 2 2100.6 2 7.9950 2 2396 2 2396 49.9 2 9

30 2 235.7 36.656 36.656 2 19.017 18.974 26.306 194.1 2 194.5 2 32.4 0.01 2 2.73 2 0.13 2 0.70 2 9 9 9 9 9 9 9 9 9 9

29 2 260.3 36.617 36.617 2 18.688 18.642 26.363 197.2 2 195.0 2 33.3 0.01 2 3.51 2 0.14 2 0.80 2 2.30 6 1.26 6 0.02 6 9 9 9 9 9 47.2 2 9

28 2 279.1 36.590 36.590 2 18.507 18.458 26.389 195.7 2 199.1 2 30.1 0.01 2 3.61 2 0.17 2 0.80 2 2.31 2 1.27 2 0.03 2 9 375.8 353.9 2 2097.9 2 7.9909 2 2391 2 2390 9 9

27 2 315.4 36.561 36.560 2 18.284 18.229 26.426 199.8 2 199.2 2 31.0 0.01 2 4.10 2 0.25 3 1.00 2 2.29 2 1.25 2 0.03 2 9 9 9 9 9 45.3 2 9

26 2 373.8 36.498 36.500 2 17.872 17.807 26.485 201.1 2 200.1 2 32.0 0.01 2 4.78 2 0.24 2 1.20 2 2.26 2 1.23 2 0.04 2 0.46 2 9 2101.6 2 7.9775 2 2395 2 2385 9 9

25 2 450.8 36.380 36.392 2 17.219 17.143 26.559 191.3 2 190.1 2 45.1 0.00 2 6.73 2 0.36 2 1.80 2 2.12 2 1.14 2 0.03 2 9 424.0 378.5 2 2113.0 2 7.9487 2 2379 2 2379 44.5 2 9

24 2 500.0 36.260 36.256 2 16.528 16.446 26.633 186.4 2 185.5 2 53.1 0.00 2 8.39 2 0.46 2 2.40 2 2.06 2 1.10 2 0.03 2 9 9 9 9 9 9 9

23 2 547.8 36.118 36.121 2 15.669 15.582 26.724 182.3 2 182.4 2 60.5 0.00 2 9.95 2 0.57 2 3.10 2 9 9 9 9 9 9 9 9 48.0 2 9

22 2 600.1 35.942 35.937 2 14.633 14.542 26.820 176.5 2 174.9 2 73.4 0.00 2 12.40 2 0.74 2 4.40 2 1.77 2 0.92 2 0.03 2 0.41 2 538.6 432.7 2 2138.4 2 7.8613 2 2366 2 2354 9 9

21 2 650.4 35.781 35.794 2 13.539 13.445 26.927 168.1 2 168.6 2 85.5 0.00 2 14.54 2 0.89 2 5.60 2 9 9 9 9 9 9 9 9 43.1 2 9

20 2 749.4 35.495 35.503 2 11.431 11.333 27.118 162.1 2 161.4 2 104.7 0.00 2 18.65 2 1.18 2 8.70 2 1.16 2 0.60 2 0.02 2 9 669.7 470.7 2 2164.4 2 7.7653 2 2335 2 2331 9 9

19 2 851.0 35.254 35.257 2 9.428 9.329 27.279 151.4 2 150.7 2 127.6 0.00 2 23.05 2 1.48 2 13.00 2 9 9 9 9 797.3 514.9 2 2182.0 2 7.7008 2 2326 2 2320 42.3 2 9

18 2 950.7 35.075 35.073 2 7.598 7.500 27.421 155.1 2 154.9 2 135.5 0.00 2 25.59 2 1.69 2 16.80 2 0.25 2 0.13 2 0.01 2 0.25 2 878.7 524.8 2 2196.8 2 7.6612 2 5 2319 9 9

17 2 1049.5 35.079 35.081 2 6.701 6.599 27.550 182.4 2 182.4 2 114.1 0.00 2 23.05 2 1.55 2 15.80 2 9 9 9 9 830.4 475.0 2 2190.3 6 7.6826 2 5 2321 9 9

16 2 1249.8 35.075 35.075 2 5.294 5.184 27.727 233.3 2 231.5 2 75.1 0.00 2 19.44 2 1.29 2 13.40 2 0.59 2 0.30 2 0.02 2 9 9 9 9 9 9 9

15 2 1449.8 35.025 35.026 2 4.509 4.388 27.778 253.1 2 254.1 2 58.5 0.00 2 18.17 2 1.22 2 12.80 2 0.80 2 0.40 2 0.03 2 9 738.0 379.9 2 2166.8 2 7.7311 2 2328 3 2316 41.8 2 9

14 2 1644.8 34.982 34.983 2 4.038 3.904 27.796 265.6 2 265.2 2 51.2 0.00 2 17.68 2 1.19 2 12.80 2 0.99 2 0.48 2 0.05 2 1.69 2 9 9 9 9 9 9

13 2 1849.3 34.979 34.980 2 3.844 3.693 27.817 267.7 2 267.1 2 51.0 0.00 2 17.58 2 1.19 2 13.90 2 0.73 2 0.36 2 0.03 2 9 721.4 359.5 2 2162.3 2 7.7351 2 5 2313 9 9

12 2 2050.4 34.970 34.971 2 3.616 3.449 27.834 268.0 2 268.6 2 51.4 0.00 2 17.58 2 1.19 2 14.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2249.1 34.967 34.968 2 3.434 3.251 27.852 267.6 2 268.1 2 53.5 0.00 2 17.78 2 1.21 2 16.70 2 0.37 2 0.19 2 0.02 2 0.94 2 9 2164.6 2 7.7389 2 2323 2 2317 9 9

10 2 2451.0 34.956 34.957 2 3.234 3.035 27.865 269.0 2 269.6 2 53.7 0.00 2 17.68 2 1.21 2 17.90 2 9 9 9 9 9 9 9 9 9 9

9 2 2650.3 34.947 34.949 2 3.047 2.831 27.877 268.8 2 269.7 2 55.3 0.00 2 17.78 2 1.23 2 19.40 2 0.35 2 0.17 2 0.01 2 0.84 2 9 2167.6 2 7.7396 2 9 2321 9 9

8 2 2850.6 34.935 34.936 2 2.860 2.628 27.887 270.4 2 271.7 2 55.0 0.00 2 17.58 2 1.21 2 20.20 2 9 9 9 9 9 9 9 9 9 9

7 2 3098.8 34.925 34.925 2 2.663 2.409 27.898 273.9 2 273.9 2 54.7 0.00 2 17.48 2 1.21 2 21.60 2 0.45 2 0.22 2 0.02 2 9 718.3 337.5 2 2166.9 2 7.7393 2 2327 2 2320 9 9

6 2 3314.8 34.914 34.915 2 2.490 2.218 27.907 274.9 2 275.5 2 54.7 0.00 2 17.39 2 1.21 2 23.00 2 0.54 2 0.27 2 0.02 2 1.08 2 9 2167.9 2 7.7371 2 2330 2 2320 9 9

5 2 3595.7 34.905 34.905 2 2.350 2.051 27.914 274.8 2 275.2 2 56.4 0.00 2 17.68 2 1.22 2 25.60 2 0.53 2 0.26 2 0.03 2 9 9 9 7.7352 2 9 9 9

4 2 3873.1 34.897 34.898 2 2.279 1.951 27.918 273.3 2 274.9 2 57.6 0.00 2 17.97 2 1.24 2 28.20 2 0.56 2 0.28 2 0.03 2 1.11 6 9 2174.2 2 7.7327 2 9 2324 9 9

3 2 4050.4 34.894 34.894 2 2.260 1.913 27.920 270.8 2 272.1 2 60.7 0.00 2 18.27 2 1.26 2 30.10 2 0.51 6 0.25 6 0.03 6 9 9 9 9 9 9 9

2 2 4301.1 34.888 34.889 2 2.232 1.856 27.921 269.1 2 268.9 2 64.4 0.00 2 18.75 2 1.31 2 33.70 2 0.38 2 0.19 2 0.02 2 9 735.3 337.4 2 2181.4 2 7.7301 2 2339 2 2331 9 9

1 2 4561.6 34.879 34.879 2 2.188 1.783 27.921 262.9 2 264.4 2 69.5 0.01 6 19.73 6 1.38 6 39.80 2 0.23 2 0.13 2 0.03 2 0.59 2 743.5 340.0 2 2189.5 2 7.7272 2 5 2338 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

173
A5R

NOAA Ship Ronald H. Brown

STATION 105 DATE 2/19/1998 LATITUDE 26.500° N

LONGITUDE 74.800° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.8 36.651 36.650 2 22.181 22.180 25.424 219.2 2 221.6 2 -7.4 0.00 2 0.00 2 0.01 2 0.40 2 2.09 2 1.19 2 0.17 2 2.08 2 296.8 323.7 2 2046.6 2 8.0791 2 2398 2 2395 9 9

35 2 50.8 36.646 36.644 2 21.665 21.655 25.570 220.0 2 218.7 2 -2.5 0.00 2 0.00 2 0.01 2 0.40 2 9 9 9 9 9 9 9 9 9 9

34 2 100.7 36.646 36.644 2 21.583 21.563 25.599 220.5 2 217.4 2 -0.9 0.09 2 0.00 2 0.02 2 0.40 2 9 9 9 9 301.2 320.8 2 9 8.0736 2 2395 2 9 9

33 2 151.7 36.591 36.602 2 20.965 20.936 25.732 218.3 2 216.5 2 2.5 0.20 2 0.10 2 0.02 2 0.40 2 9 9 9 9 9 9 9 9 9 9

32 2 201.6 36.791 36.783 2 20.168 20.130 26.105 200.9 2 195.9 2 26.0 0.02 2 1.27 2 0.04 2 0.40 2 9 9 9 9 354.2 356.6 2 9 8.0114 2 2400 2 9 9

31 2 226.3 36.714 36.706 2 19.496 19.454 26.226 199.4 2 197.6 2 27.2 0.01 2 1.85 2 0.06 2 0.50 2 9 9 9 9 9 9 9 9 9 9

30 2 251.4 36.657 36.657 2 19.129 19.083 26.280 195.6 2 199.6 2 26.8 0.01 2 2.15 2 0.08 2 0.60 2 9 9 9 9 9 9 9 9 9 9

29 2 276.1 36.622 36.617 2 18.744 18.695 26.354 195.1 2 196.7 2 31.4 0.01 2 3.22 2 0.13 2 0.70 2 9 9 9 9 9 9 9 9 9 9

28 2 300.1 36.593 36.589 2 18.521 18.468 26.390 199.1 2 197.5 2 31.6 0.01 2 3.51 2 0.16 2 0.80 2 9 9 9 9 383.5 361.3 2 9 7.9893 2 2393 2 9 9

27 2 330.0 36.564 36.563 2 18.317 18.259 26.421 200.9 2 201.1 2 29.0 0.01 2 3.80 2 0.17 2 0.90 2 9 9 9 9 9 9 9 9 9 9

26 2 359.9 36.542 36.540 2 18.160 18.097 26.446 202.7 2 200.8 2 30.0 0.01 2 4.10 2 0.20 2 1.00 2 9 9 9 9 9 9 9 9 9 9

25 2 396.9 36.511 36.510 2 17.958 17.889 26.476 201.3 2 200.9 2 30.8 0.01 2 4.59 2 0.22 2 1.20 2 9 9 9 9 9 9 9 9 9 9

24 2 448.9 36.431 36.435 2 17.500 17.423 26.531 192.6 2 192.4 2 41.5 0.01 2 6.05 2 0.31 2 1.60 2 9 9 9 9 9 9 9 9 9 9

23 2 499.9 36.349 36.347 2 17.023 16.939 26.586 186.0 2 185.8 2 50.4 0.01 2 7.32 2 0.40 2 2.00 2 9 9 9 9 440.7 390.6 2 9 7.9386 2 2390 2 9 9

22 2 550.2 36.194 36.196 2 16.110 16.021 26.683 180.8 2 180.5 2 60.2 0.01 2 9.27 2 0.53 2 2.70 2 9 9 9 9 9 9 9 9 9 9

21 3 600.3 36.053 36.052 2 15.255 15.161 26.770 176.5 2 175.9 2 69.1 0.01 2 11.22 2 0.65 2 3.50 2 9 9 9 9 9 9 9 9 9 9

20 2 700.1 35.722 35.714 2 13.152 13.053 26.962 167.8 2 167.5 2 88.8 0.00 2 15.52 2 0.95 2 6.20 2 9 9 9 9 9 9 9 9 9 9

19 2 797.4 35.462 35.456 2 11.187 11.084 27.139 161.9 2 161.0 2 106.6 0.00 2 19.23 2 1.21 2 9.20 2 9 9 9 9 700.4 487.6 2 9 7.7547 2 2343 3 9 9

18 2 893.2 35.200 35.232 2 8.927 8.826 27.319 152.3 2 155.3 2 126.2 0.00 2 22.85 2 1.48 2 12.80 2 9 9 9 9 793.1 501.2 2 9 7.7003 2 2327 2 9 9

17 2 1002.0 35.088 35.087 2 7.317 7.215 27.473 168.9 2 167.5 2 124.8 0.00 2 24.22 2 1.60 2 15.70 2 9 9 9 9 851.8 502.3 2 9 7.6743 2 2333 2 9 9

16 2 1099.5 35.090 35.089 2 6.390 6.285 27.600 193.7 2 195.8 6 102.8 0.00 2 21.87 2 1.45 2 14.40 2 9 9 9 9 9 9 9 9 9 9

15 2 1288.7 35.068 35.068 2 5.166 5.053 27.736 237.5 2 235.6 2 71.9 0.00 2 19.14 2 1.28 2 12.70 2 9 9 9 9 9 9 9 9 9 9

14 2 1500.3 35.029 35.029 2 4.501 4.375 27.783 257.6 2 253.9 2 58.8 0.00 2 18.16 2 1.22 2 12.50 2 9 9 9 9 736.6 379.2 2 9 7.7297 2 2328 3 9 9

13 2 1701.3 34.981 34.980 2 3.958 3.820 27.804 267.3 2 266.1 2 51.0 0.00 2 17.58 2 1.19 2 12.60 2 9 9 9 9 9 9 9 9 9 9

12 2 1899.5 34.973 34.972 2 3.740 3.586 27.822 268.7 2 268.3 2 50.6 0.00 2 17.58 2 1.20 2 13.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2100.3 34.974 34.973 2 3.574 3.403 27.842 267.1 2 267.5 2 52.9 0.00 2 17.77 2 1.20 2 15.40 2 9 9 9 9 9 9 9 9 9 9

10 2 2289.4 34.969 34.969 2 3.394 3.208 27.858 268.1 2 269.2 2 52.7 0.00 2 17.87 2 1.21 2 17.20 2 9 9 9 9 9 9 9 9 9 9

9 2 2499.3 34.956 34.955 2 3.168 2.965 27.871 268.6 2 268.5 2 55.4 0.00 2 17.87 2 1.22 2 18.60 2 9 9 9 9 724.9 349.4 2 9 7.7392 2 2330 3 9 9

8 2 2699.9 34.947 34.946 2 3.001 2.781 27.882 268.8 2 268.9 2 56.5 0.00 2 17.97 2 1.22 2 20.20 2 9 9 9 9 9 9 9 9 9 9

7 2 2899.8 34.937 34.936 2 2.839 2.602 27.891 270.5 2 270.8 2 56.1 0.00 2 17.78 2 1.24 3 21.00 2 9 9 9 9 9 9 9 9 9 9

6 2 3099.9 34.926 34.925 2 2.670 2.416 27.898 273.6 2 273.9 2 54.6 0.00 2 17.48 2 1.20 2 21.20 2 9 9 9 9 9 9 9 9 9 9

5 2 3398.2 34.915 34.913 2 2.477 2.196 27.910 275.9 2 275.0 2 55.4 0.00 2 17.48 2 1.21 2 22.90 2 9 9 9 9 9 9 9 9 9 9

4 2 3698.7 34.905 34.902 2 2.336 2.026 27.917 274.9 2 274.7 2 57.1 0.00 2 17.87 2 1.23 2 25.80 2 9 9 9 9 725.6 335.1 2 9 7.7356 6 2341 3 9 9

3 2 3999.2 34.897 34.895 2 2.260 1.918 27.921 272.7 2 272.0 2 60.7 0.01 2 18.26 2 1.28 2 29.30 2 9 9 9 9 9 9 9 9 9 9

2 2 4299.8 34.889 34.887 2 2.216 1.841 27.922 269.4 2 268.1 2 65.3 0.01 2 19.05 2 1.32 2 34.00 2 9 9 9 9 9 9 9 9 9 9

1 2 4602.2 34.873 34.871 2 2.136 1.728 27.921 261.4 2 261.2 2 73.2 0.01 6 20.51 6 1.43 6 43.00 6 9 9 9 9 762.2 347.8 2 9 7.7246 2 2354 3 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

174
A5R

NOAA Ship Ronald H. Brown

STATION 106 DATE 2/20/1998 LATITUDE 26.500° N

LONGITUDE 75.084° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.6 36.669 36.667 2 22.376 22.375 25.382 217.8 2 218.3 2 -4.9 0.00 2 0.00 2 0.01 2 0.70 2 2.05 2 1.17 2 0.16 2 2.12 4 287.1 315.5 2 2041.5 6 8.0742 2 2393 9 2386 65.6 2 9

35 2 29.2 36.662 36.661 2 22.235 22.229 25.420 218.7 2 218.1 6 -4.1 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 291.6 318.7 2 2042.5 2 9 2391 9 65.0 2 9

34 2 79.0 36.664 36.663 2 21.924 21.908 25.515 219.1 2 218.7 2 -3.5 0.00 2 0.00 2 0.02 2 0.70 2 2.06 2 1.18 2 0.16 2 9 293.2 316.6 2 2045.3 2 8.0843 2 2393 9 2397 63.4 2 9

33 2 129.7 36.649 36.650 2 21.730 21.704 25.563 216.8 2 216.6 2 -0.6 0.04 2 0.10 2 0.02 2 0.70 2 9 9 9 9 300.8 322.3 2 2048.0 2 9 2391 9 61.6 2 9

32 2 180.4 36.777 36.788 2 21.255 21.220 25.798 198.7 2 201.2 2 16.4 0.05 2 0.78 2 0.03 2 0.70 2 2.16 2 1.23 2 0.11 2 9 335.0 352.1 2 2079.4 2 8.0373 2 2400 9 2403 56.5 2 9

31 2 209.8 36.794 36.774 2 20.480 20.440 26.025 192.0 2 198.0 2 22.7 0.02 2 1.17 2 0.05 2 0.80 2 2.23 2 1.26 2 0.08 2 9 357.6 364.4 2 2092.6 2 8.0157 2 2400 9 2402 54.2 2 9

30 2 232.3 36.718 36.714 2 19.551 19.508 26.215 194.2 2 192.8 2 31.8 0.01 2 2.05 2 0.07 2 0.90 2 9 9 9 9 382.5 375.5 2 2102.1 2 7.9987 2 2398 9 2401 52.9 2 9

29 2 259.5 36.663 36.663 2 19.084 19.037 26.296 192.4 2 195.1 2 31.5 0.01 2 2.54 2 0.10 2 1.00 2 2.29 2 1.27 2 0.03 2 9 9 2100.1 2 7.9958 2 2392 9 2396 51.3 2 9

28 2 285.3 36.611 36.608 2 18.691 18.640 26.360 194.0 2 197.8 2 30.6 0.01 2 3.12 2 0.13 2 1.10 2 2.31 2 1.28 2 0.03 2 9 386.2 366.3 2 9 7.9919 2 2389 9 9 9

27 2 324.3 36.567 36.566 2 18.357 18.300 26.413 199.0 2 201.6 2 28.3 0.01 2 3.61 2 0.16 2 1.20 2 2.35 2 1.29 2 0.03 2 9 384.0 359.4 2 2096.9 6 7.9919 2 2386 9 2390 48.8 2 9

26 2 375.1 36.532 36.531 2 18.098 18.032 26.455 202.8 2 203.2 2 27.9 0.01 2 4.10 2 0.20 2 1.40 2 2.32 2 1.27 2 0.02 2 9 382.4 354.0 2 2097.0 2 7.9879 2 2386 9 2387 9 9

25 2 449.3 36.440 36.449 2 17.547 17.470 26.526 194.7 2 194.4 2 39.3 0.01 2 5.66 2 0.30 2 1.90 2 9 9 9 9 412.9 373.9 2 2107.8 2 9 2379 9 47.3 2 9

24 2 499.9 36.328 36.330 2 16.905 16.821 26.598 186.3 2 185.0 2 51.8 0.01 2 7.61 2 0.42 2 2.40 2 2.07 2 1.10 2 0.02 2 9 441.9 389.7 2 2118.1 2 7.9362 2 2376 9 2376 9 9

23 2 549.4 36.212 36.215 2 16.238 16.149 26.668 181.3 2 180.8 2 59.3 0.01 2 9.07 2 0.51 2 3.00 2 9 9 9 9 9 2124.6 2 7.9109 2 2368 9 2368 45.9 2 9

22 2 599.8 36.038 36.048 2 15.164 15.071 26.778 175.5 2 174.9 2 70.6 0.01 2 11.32 2 0.66 2 4.00 2 1.82 2 0.95 2 0.02 2 9 508.9 418.0 2 2134.4 2 7.8788 2 2361 9 2360 9 9

21 2 648.8 35.898 35.906 2 14.260 14.163 26.868 170.7 2 169.6 2 80.6 0.01 2 13.27 2 0.79 2 5.10 2 1.64 2 0.85 2 0.02 2 9 9 2142.0 2 9 2351 9 45.1 2 9

20 2 746.8 35.600 35.608 2 12.312 12.210 27.035 164.8 2 163.6 2 97.4 0.01 2 17.08 2 1.06 2 7.80 2 1.34 2 0.69 2 0.03 2 9 637.8 464.6 2 2157.2 2 7.7893 2 2342 9 2336 9 9

19 2 849.7 35.308 35.311 2 9.839 9.738 27.255 159.1 2 157.9 2 117.8 0.01 2 21.58 2 1.38 2 11.90 2 9 9 9 9 754.1 495.6 2 2176.2 2 7.7210 2 2326 9 2323 42.8 2 9

18 2 950.0 35.087 35.089 2 7.765 7.666 27.407 155.5 2 154.3 2 135.0 0.01 2 25.49 2 1.67 2 16.80 2 0.27 6 0.14 6 0.00 6 9 874.9 526.4 2 2192.6 6 9 2322 9 9 9

17 2 1048.1 35.077 35.076 2 6.872 6.769 27.526 175.8 2 176.0 2 119.3 0.01 2 23.83 2 1.58 2 16.30 2 0.33 2 0.17 2 0.01 2 9 847.3 488.8 2 2188.5 2 7.6783 2 2319 9 2317 42.9 2 9

16 2 1198.5 35.080 35.080 2 5.622 5.514 27.690 220.1 2 221.6 2 82.5 0.01 2 20.12 2 1.34 2 13.70 2 9 9 9 9 772.3 419.6 2 2173.7 2 7.7132 2 2322 9 2316 9 9

15 2 1400.7 35.051 35.052 2 4.777 4.657 27.768 248.0 2 246.7 2 63.8 0.01 2 18.55 2 1.25 2 13.00 2 0.68 2 0.34 2 0.02 2 9 9 2164.9 2 7.7292 2 2316 9 2313 42.9 2 9

14 2 1600.4 34.999 35.000 2 4.211 4.079 27.791 262.3 2 261.6 2 53.4 0.01 2 17.87 2 1.21 2 12.90 2 0.88 2 0.43 2 0.04 2 9 726.1 368.4 2 2160.3 2 7.7341 2 2318 9 2311 9 9

13 2 1800.6 34.973 34.975 2 3.859 3.713 27.809 266.8 2 267.6 2 50.3 0.01 2 17.68 2 1.19 2 13.40 2 0.90 2 0.44 2 0.04 2 9 9 2159.4 2 7.7358 2 2317 9 2310 43.0 2 9

12 2 2000.8 34.986 34.987 2 3.751 3.587 27.834 265.6 2 265.3 2 53.6 0.01 2 17.87 2 1.21 2 15.20 2 0.42 2 0.21 2 0.02 2 1.04 6 9 2159.6 2 7.7375 2 2321 9 2311 9 9

11 2 2200.3 34.974 34.974 2 3.531 3.351 27.848 266.4 2 267.2 2 53.6 0.01 2 17.77 2 1.21 2 16.50 2 9 9 9 0.95 2 714.5 350.4 2 2160.0 2 7.7387 2 2315 9 2312 43.0 2 9

10 2 2399.8 34.965 34.966 2 3.335 3.139 27.862 267.8 2 267.6 2 54.9 0.01 2 17.87 2 1.22 2 18.00 2 0.31 2 0.16 2 0.01 2 9 9 2161.1 2 7.7393 2 9 2314 9 9

9 2 2589.2 34.954 34.953 2 3.139 2.928 27.874 268.9 2 269.2 2 55.0 0.01 2 17.77 2 1.22 2 19.00 2 0.33 2 0.16 2 0.01 2 0.81 2 9 2161.5 2 9 2320 9 42.9 2 9

8 2 2799.3 34.939 34.938 2 2.907 2.679 27.885 271.2 2 271.9 2 54.4 0.01 2 17.58 2 1.21 2 19.90 2 9 9 9 9 716.7 341.0 2 2160.4 2 7.7367 2 9 2312 9 9

7 2 3000.7 34.929 34.929 2 2.734 2.489 27.895 273.6 2 273.5 2 54.4 0.01 2 17.48 2 1.20 2 20.60 2 0.52 2 0.25 2 0.02 2 1.04 2 9 2160.6 2 9 2316 9 43.0 2 9

6 2 3201.0 34.921 34.922 2 2.601 2.338 27.902 274.6 2 274.3 2 54.8 0.01 2 17.38 2 1.21 2 22.00 2 9 9 9 1.01 2 9 2161.6 2 4 9 9 9

5 2 3501.7 34.910 34.910 2 2.426 2.135 27.912 275.9 2 275.5 2 55.4 0.01 2 17.38 2 1.22 2 23.60 2 0.62 2 0.30 2 0.03 2 1.19 2 720.7 334.6 2 2163.9 2 7.7362 2 2324 9 2315 42.9 2 9

4 2 3799.3 34.903 34.902 2 2.337 2.016 27.917 275.0 2 274.5 2 57.4 0.01 2 17.58 2 1.23 2 25.90 2 9 9 9 9 9 2167.1 2 9 9 9 9

3 2 4100.9 34.895 34.894 2 2.267 1.914 27.920 271.5 2 271.4 2 61.4 0.01 2 18.17 2 1.29 2 30.50 2 0.52 2 0.25 2 0.03 2 1.02 2 9 2173.2 2 7.7319 2 2326 9 2323 43.2 2 9

2 2 4390.0 34.886 34.884 2 2.207 1.822 27.922 266.8 2 266.5 2 67.1 0.01 2 19.24 2 1.36 2 36.40 2 0.32 2 0.16 2 0.03 2 0.71 2 739.0 338.6 2 2181.0 2 7.7292 2 9 2330 9 9

1 2 4675.7 34.875 34.905 2 2.162 1.744 27.922 262.0 2 272.6 3 61.6 0.01 6 17.87 3 1.26 6 27.20 3 0.51 4 0.26 4 0.03 4 1.03 2 730.8 334.8 2 2169.6 3 7.7342 2 2325 9 2320 44.5 3 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

175
A5R

NOAA Ship Ronald H. Brown

STATION 107 DATE 2/20/1998 LATITUDE 26.500° N

LONGITUDE 75.300° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.6 36.666 36.665 2 22.439 22.438 25.362 218.1 2 218.1 2 -4.9 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 292.8 322.6 6 2041.6 6 8.0876 6 2394 6 2395 9 9

35 2 32.8 36.663 36.662 2 22.165 22.158 25.441 218.7 2 218.9 2 -4.7 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

34 2 67.7 36.643 36.642 2 21.926 21.913 25.497 217.8 2 218.9 2 -3.7 0.01 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

33 2 104.2 36.657 36.652 2 21.760 21.739 25.558 215.1 2 216.3 2 -0.5 0.07 2 0.00 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

32 2 140.6 36.692 36.695 2 21.421 21.393 25.683 215.0 2 214.3 2 2.8 0.10 2 0.20 2 0.01 2 0.70 2 9 9 9 9 9 9 9 9 9 9

31 2 174.2 36.817 36.807 2 20.807 20.774 25.950 205.1 2 203.5 2 15.9 0.04 2 0.78 2 0.03 2 0.70 2 9 9 9 9 9 9 9 9 9 9

30 2 199.7 36.778 36.780 2 20.101 20.064 26.113 199.6 2 194.5 2 27.7 0.02 2 1.46 2 0.05 2 0.70 2 9 9 9 9 9 9 9 9 9 9

29 2 213.8 36.721 36.716 2 19.705 19.665 26.175 191.3 2 196.9 2 27.0 0.02 2 1.85 2 0.06 2 0.80 2 9 9 9 9 9 9 9 9 9 9

28 2 249.2 36.660 36.655 2 19.057 19.012 26.301 194.3 2 194.5 2 32.2 0.01 2 2.83 2 0.10 2 0.90 2 9 9 9 9 9 9 9 9 9 9

27 2 271.3 36.613 36.614 2 18.680 18.632 26.362 195.8 2 196.8 2 31.6 0.01 2 3.32 2 0.13 2 1.00 2 9 9 9 9 9 9 9 9 9 9

26 2 297.2 36.581 36.576 2 18.438 18.385 26.401 203.0 2 200.2 2 29.3 0.01 2 3.71 2 0.16 2 1.20 2 9 9 9 9 9 9 9 9 9 9

25 2 343.7 36.553 36.552 2 18.236 18.176 26.434 206.7 2 202.5 2 27.9 0.01 2 4.00 2 0.18 2 1.20 2 9 9 9 9 9 9 9 9 9 9

24 2 397.4 36.523 36.524 2 18.029 17.960 26.468 203.1 2 201.8 2 29.6 0.01 2 4.49 2 0.21 2 1.40 2 9 9 9 9 9 9 9 9 9 9

23 2 448.5 36.455 36.459 2 17.626 17.549 26.518 197.0 2 197.2 2 36.1 0.01 2 5.56 2 0.28 2 1.70 2 9 9 9 9 9 9 9 9 9 9

22 2 499.3 36.315 36.319 2 16.825 16.742 26.606 187.9 2 184.9 2 52.3 0.01 2 7.90 2 0.42 2 2.40 2 9 9 9 9 9 9 9 9 9 9

21 2 550.2 36.174 36.180 2 15.993 15.904 26.695 182.3 2 179.7 2 61.6 0.01 2 9.66 2 0.54 2 3.10 2 9 9 9 9 9 9 9 9 9 9

20 2 651.5 35.870 35.870 2 14.081 13.984 26.884 172.4 2 168.8 2 82.4 0.01 2 13.86 2 0.82 2 5.20 2 9 9 9 9 9 9 9 9 9 9

19 2 748.6 35.563 35.565 2 11.996 11.896 27.067 163.9 2 162.4 2 100.4 0.01 2 17.76 2 1.10 2 8.20 2 9 9 9 9 9 9 9 9 9 9

18 2 849.0 35.304 35.315 2 9.795 9.694 27.259 159.7 2 158.0 2 118.0 0.01 2 21.48 2 1.37 2 11.70 2 9 9 9 9 9 9 9 9 9 9

17 2 949.1 35.130 35.132 2 8.008 7.907 27.405 158.3 2 157.7 2 129.9 0.01 2 24.31 2 1.59 2 15.40 2 9 9 9 9 9 9 9 9 9 9

16 2 1146.3 35.085 35.083 2 6.077 5.970 27.637 202.1 2 203.5 2 97.4 0.01 2 21.58 2 1.43 2 14.70 2 9 9 9 9 9 9 9 9 9 9

15 2 1341.6 35.045 35.045 2 4.913 4.798 27.747 242.0 2 242.8 2 66.7 0.01 2 18.75 2 1.25 2 12.70 2 9 9 9 9 9 9 9 9 9 9

14 2 1548.2 35.000 34.999 2 4.287 4.159 27.783 260.7 2 260.2 6 54.2 0.01 2 17.97 2 1.20 2 12.50 2 9 9 9 9 9 9 9 9 9 9

13 9 1744.7 34.980 34.982 2 3.978 3.835 27.802 266.1 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

12 2 1941.8 34.972 34.971 2 3.758 3.600 27.820 268.1 2 268.8 2 50.0 0.01 2 17.58 2 1.19 2 13.90 2 9 9 9 9 9 9 9 9 9 9

11 2 2147.4 34.975 34.974 2 3.600 3.424 27.841 267.3 2 267.8 2 52.4 0.01 2 17.77 2 1.20 2 15.50 2 9 9 9 9 9 9 9 9 9 9

10 2 2348.8 34.964 34.964 2 3.379 3.187 27.857 268.5 2 268.8 2 53.3 0.01 2 17.77 2 1.21 2 17.00 2 9 9 9 9 9 9 9 9 9 9

9 2 2547.3 34.955 34.955 2 3.177 2.969 27.871 268.6 2 269.2 2 54.7 0.01 2 17.77 2 1.22 2 18.70 2 9 9 9 9 9 9 9 9 9 9

8 2 2749.4 34.944 34.943 2 2.987 2.762 27.881 269.9 2 271.2 2 54.4 0.01 2 17.67 2 1.21 2 19.50 2 9 9 9 9 9 9 9 9 9 9

7 2 2932.1 34.932 34.932 2 2.807 2.567 27.890 272.2 2 273.3 2 53.9 0.01 2 17.48 2 1.20 2 20.10 2 9 9 9 9 9 9 9 9 9 9

6 2 3194.3 34.923 34.922 2 2.640 2.377 27.900 274.9 2 274.9 2 53.9 0.01 2 17.28 2 1.20 2 21.10 2 9 9 9 9 9 9 9 9 9 9

5 2 3539.8 34.910 34.908 2 2.425 2.130 27.912 275.4 2 275.1 2 55.8 0.01 2 17.48 2 1.22 2 24.10 2 9 9 9 9 9 9 9 9 9 9

4 2 3798.5 34.902 34.902 2 2.329 2.008 27.917 274.5 2 274.4 2 57.6 0.01 2 17.77 2 1.24 2 26.30 2 9 9 9 9 9 9 9 9 9 9

3 2 4131.3 34.894 34.894 2 2.265 1.908 27.921 272.6 2 271.8 2 61.0 0.01 2 18.16 2 1.27 2 29.90 2 9 9 9 9 9 9 9 9 9 9

2 2 4395.3 34.888 34.888 2 2.235 1.848 27.922 269.3 2 268.6 2 64.8 0.01 2 18.94 2 1.32 2 34.00 2 9 9 9 9 9 9 9 9 9 9

1 2 4705.3 34.875 34.875 2 2.175 1.753 27.922 262.5 2 262.8 6 71.4 0.01 6 20.12 6 1.42 6 41.60 6 9 9 9 9 9 9 4 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

176
A5R

NOAA Ship Ronald H. Brown

STATION 108 DATE 2/20/1998 LATITUDE 26.500° N

LONGITUDE 75.500° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.8 36.668 36.667 2 22.425 22.424 25.367 218.0 2 218.5 2 -5.3 0.01 2 0.00 3 0.01 2 0.40 2 2.05 2 1.18 2 0.17 2 2.10 2 289.3 318.6 2 2042.2 2 8.0860 2 2397 2 2395 9 9

35 2 48.0 36.672 36.676 2 22.114 22.104 25.464 218.0 2 218.2 6 -3.8 0.01 2 0.00 3 0.01 2 0.40 2 2.04 2 1.17 2 0.16 2 9 9 9 9 9 9 9

34 2 74.8 36.682 36.682 2 21.886 21.871 25.538 217.6 2 215.8 2 -0.5 0.04 2 0.10 3 0.02 2 0.40 2 2.05 2 1.18 2 0.16 2 9 304.7 328.5 2 2048.8 2 8.0777 2 2410 2 2396 9 9

33 2 100.8 36.670 36.670 2 21.675 21.655 25.591 214.5 2 216.0 2 0.1 0.07 2 0.00 3 0.02 2 0.40 2 2.08 2 1.19 2 0.16 2 9 299.2 320.1 2 2049.7 2 8.0753 2 2397 2 2396 9 9

32 2 150.7 36.782 36.789 2 21.169 21.140 25.822 207.4 2 207.0 2 11.0 0.05 2 0.59 3 0.03 2 0.30 2 2.18 2 1.24 2 0.13 2 9 327.2 343.0 2 2076.7 2 8.0429 2 9 2403 9 9

31 2 173.5 36.805 36.793 2 20.332 20.299 26.070 206.6 2 200.1 2 21.2 0.02 2 0.88 3 0.04 2 0.30 2 2.23 2 1.26 2 0.09 2 9 9 9 9 9 9 9

30 2 200.6 36.723 36.723 2 19.558 19.521 26.214 195.7 2 196.0 2 28.5 0.02 2 1.46 3 0.06 2 0.50 2 2.26 2 1.26 2 0.06 2 9 9 9 9 9 9 9

29 2 224.9 36.672 36.672 2 19.135 19.094 26.287 192.1 2 196.7 2 29.7 0.01 2 2.05 3 0.09 2 0.60 2 9 9 9 9 372.0 359.3 2 2101.5 2 7.9983 2 5 2399 9 9

28 2 249.9 36.633 36.632 2 18.849 18.804 26.333 196.4 2 199.0 2 28.6 0.01 2 2.44 3 0.11 2 0.60 2 2.32 2 1.29 2 0.03 2 9 9 9 9 9 9 9

27 2 269.6 36.604 36.607 2 18.637 18.589 26.366 198.1 2 200.3 2 28.3 0.01 2 2.73 3 0.13 2 0.70 2 9 9 9 9 9 2098.3 2 7.9964 2 2392 2 2394 9 9

26 2 300.1 36.586 36.586 2 18.468 18.415 26.398 198.0 2 198.3 2 31.1 0.01 2 3.32 3 0.16 2 0.80 2 2.32 6 1.27 6 0.02 6 9 9 9 9 9 9 9

25 2 349.7 36.549 36.547 2 18.204 18.143 26.440 203.8 2 201.6 2 29.0 0.01 2 3.61 3 0.19 2 1.00 2 9 9 9 9 389.2 362.0 2 2100.4 2 7.9877 2 2388 2 2391 9 9

24 2 400.1 36.515 36.516 2 17.976 17.906 26.474 201.9 2 202.5 2 29.2 0.01 2 4.00 3 0.22 2 1.10 2 2.29 2 1.25 2 0.02 2 9 9 9 9 9 9 9

23 2 448.9 36.445 36.457 2 17.580 17.503 26.522 192.7 2 194.6 2 38.9 0.01 2 5.17 3 0.29 2 1.50 2 9 9 9 9 9 9 9 9 9 9

22 2 550.3 36.196 36.192 2 16.130 16.041 26.680 179.5 2 179.5 2 61.1 0.01 2 8.78 3 0.53 2 2.70 2 1.95 2 1.03 2 0.03 2 9 471.2 402.6 2 2129.1 2 7.9062 2 2369 2 2370 9 9

21 2 649.7 35.859 35.871 2 14.031 13.935 26.886 170.3 2 169.0 2 82.4 0.01 2 12.78 3 0.82 2 5.00 2 1.60 2 0.83 2 0.03 2 9 9 2146.6 2 7.8405 2 2353 2 2351 9 9

20 2 749.1 35.626 35.614 2 12.439 12.336 27.031 162.6 2 160.6 2 99.7 0.01 2 16.30 3 1.07 2 7.50 2 9 9 9 9 651.1 477.5 2 2161.3 2 7.7854 2 5 2338 9 9

19 2 849.3 35.311 35.315 2 9.879 9.778 27.250 155.7 2 154.3 2 121.2 0.01 2 20.50 3 1.39 2 11.70 2 0.73 2 0.37 2 0.02 2 9 758.8 499.4 2 2180.1 2 7.7176 2 2328 2 2326 9 9

18 2 990.0 35.120 35.117 2 7.609 7.506 27.456 169.0 2 167.3 2 123.0 0.01 2 22.36 3 1.56 2 15.30 2 0.42 2 0.22 2 0.01 2 9 835.2 498.1 2 2188.8 6 7.6811 2 2325 2 2319 9 9

17 2 1199.5 35.088 35.090 2 5.728 5.619 27.684 215.7 2 217.2 2 86.2 0.01 2 19.23 3 1.35 2 13.80 2 0.55 2 0.28 2 0.02 2 9 775.8 423.6 2 2176.9 2 7.7090 2 5 2318 9 9

16 2 1399.5 35.031 35.031 2 4.736 4.617 27.757 248.6 2 248.5 2 62.4 0.01 2 17.57 3 1.24 2 12.60 2 0.97 6 0.48 6 0.04 6 9 9 9 9 9 9 9

15 2 1599.6 35.009 35.006 2 4.264 4.131 27.794 259.8 2 260.4 2 54.2 0.01 2 17.09 3 1.20 2 12.90 2 0.81 2 0.40 2 0.03 2 9 733.2 373.1 2 2163.7 2 7.7307 2 2324 2 2313 9 9

14 2 1800.5 34.990 34.990 2 3.951 3.803 27.813 265.5 2 264.9 2 52.3 0.01 2 16.99 3 1.20 2 13.80 2 0.67 2 0.33 2 0.03 2 9 9 2162.0 2 7.7359 2 2320 2 2313 9 9

13 2 2000.0 34.968 34.968 2 3.663 3.500 27.827 267.7 2 269.4 2 50.2 0.01 2 16.89 3 1.19 2 14.50 2 0.74 2 0.36 2 0.03 2 9 9 9 9 9 9 9

12 2 2200.7 34.980 34.979 2 3.561 3.381 27.850 266.1 2 265.9 2 54.6 0.01 2 17.38 3 1.21 2 16.80 2 9 9 9 9 9 2163.2 2 7.7388 2 5 2316 9 9

11 2 2398.8 34.967 34.968 2 3.350 3.154 27.863 266.4 2 267.4 2 55.0 0.01 2 17.28 3 1.23 2 18.20 2 0.25 2 0.13 2 0.01 2 0.76 2 722.1 351.0 2 2162.5 2 7.7396 2 9 2315 9 9

10 2 2593.0 34.954 34.953 2 3.152 2.940 27.873 268.9 2 269.0 2 55.1 0.01 2 17.19 3 1.22 2 18.90 2 9 9 9 9 9 9 9 9 9 9

9 2 2798.2 34.942 34.941 2 2.954 2.725 27.884 270.4 2 271.4 2 54.5 0.01 2 16.99 3 1.21 2 19.70 2 9 9 9 0.87 2 9 2162.2 2 7.7392 2 5 2315 9 9

8 2 3000.7 34.933 34.933 2 2.789 2.543 27.894 271.6 2 272.5 2 54.9 0.01 2 16.99 3 1.21 2 20.80 2 0.40 2 0.20 2 0.01 2 1.00 2 9 9 9 9 9 9

7 2 3249.0 34.922 34.922 2 2.619 2.351 27.902 274.8 2 274.5 2 54.5 0.01 2 16.99 3 1.20 2 21.80 2 0.46 2 0.23 2 0.02 2 1.10 2 9 2163.5 2 7.7387 2 5 2316 9 9

6 2 3496.7 34.913 34.911 2 2.454 2.163 27.912 274.4 2 275.3 2 55.3 0.01 2 16.99 3 1.21 2 23.50 2 0.52 2 0.26 2 0.03 2 1.12 2 722.0 335.7 2 2165.3 2 7.7365 2 2328 2 2317 9 9

5 2 3747.6 34.904 34.903 2 2.340 2.025 27.917 274.9 2 274.9 2 56.9 0.01 2 17.28 3 1.23 2 25.90 2 0.55 2 0.27 2 0.03 2 1.12 2 9 2168.5 2 7.7345 2 9 2319 9 9

4 2 3968.7 34.899 34.899 2 2.302 1.963 27.920 273.6 2 273.4 2 58.9 0.01 2 17.58 3 1.24 2 27.70 2 0.54 2 0.27 2 0.03 2 1.09 2 9 9 9 9 9 9

3 2 4248.6 34.894 34.892 2 2.267 1.897 27.922 272.1 2 271.8 2 61.1 0.01 2 18.16 3 1.28 2 30.80 2 0.46 2 0.23 2 0.03 2 0.98 2 9 2174.3 2 7.7324 2 2331 2 2324 9 9

2 2 4476.1 34.890 34.889 2 2.251 1.854 27.924 269.4 2 268.9 2 64.4 0.01 2 18.75 3 1.31 2 33.70 2 0.34 2 0.18 2 0.03 2 0.81 2 9 2178.4 2 7.7314 2 9 2328 9 9

1 2 4751.4 34.880 34.880 2 2.215 1.786 27.924 264.0 2 262.9 2 71.0 0.01 6 19.72 3 1.38 6 39.20 6 0.23 2 0.13 2 0.02 2 0.60 2 748.1 342.8 6 2187.4 2 7.7278 2 5 2336 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

177
A5R

NOAA Ship Ronald H. Brown

STATION 109 DATE 2/20/1998 LATITUDE 26.500° N

LONGITUDE 75.701° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.2 36.661 36.661 2 22.363 22.362 25.379 217.7 2 219.7 2 -6.2 0.00 2 0.00 2 0.00 2 0.30 2 9 9 9 9 295.5 324.6 2 2047.1 6 8.0819 2 2398 6 2397 9 9

35 2 33.4 36.670 36.666 2 21.923 21.916 25.514 219.0 2 219.1 2 -4.0 0.00 2 0.00 2 0.00 2 0.30 2 9 9 9 9 9 9 9 9 9 9

34 2 70.0 36.663 36.664 2 21.662 21.648 25.587 216.6 2 219.3 2 -3.1 0.01 2 0.00 2 0.01 2 0.20 2 9 9 9 9 300.3 320.9 2 9 8.0717 2 9 9 9

33 2 104.6 36.673 36.678 2 21.535 21.514 25.633 212.2 2 215.7 2 1.0 0.07 2 0.00 2 0.01 2 0.20 2 9 9 9 9 9 9 9 9 9 9

32 2 140.4 36.822 36.820 2 20.543 20.516 26.022 204.9 2 190.5 3 29.9 0.02 2 0.49 2 0.03 2 0.20 2 9 9 9 9 9 9 9 9 9 9

31 2 188.7 36.680 36.672 2 19.372 19.338 26.229 197.1 2 201.0 2 24.3 0.02 2 1.07 2 0.06 2 0.30 2 9 9 9 9 368.4 359.3 2 9 8.0059 2 9 9 9

30 2 213.0 36.649 36.642 2 19.002 18.964 26.302 197.5 2 199.1 2 27.8 0.01 2 1.76 2 0.09 2 0.50 2 9 9 9 9 373.4 358.7 2 9 7.9979 2 9 9 9

29 2 240.5 36.619 36.617 2 18.729 18.686 26.352 196.5 2 189.8 3 38.4 0.01 2 2.15 2 0.12 2 0.50 2 9 9 9 9 380.3 361.3 2 9 7.9941 2 9 9 9

28 2 264.9 36.596 36.591 2 18.564 18.517 26.378 198.0 2 200.7 2 28.2 0.01 2 2.44 2 0.14 2 0.60 2 9 9 9 9 9 9 9 9 9 9

27 2 291.3 36.575 36.574 2 18.404 18.353 26.405 201.6 2 202.4 2 27.2 0.01 2 2.63 2 0.15 2 0.70 2 9 9 9 9 9 9 9 9 9 9

26 2 340.2 36.549 36.547 2 18.183 18.123 26.444 204.8 2 205.9 2 24.8 0.01 2 2.83 2 0.17 2 0.80 2 9 9 9 9 9 9 9 9 9 9

25 2 401.0 36.518 36.518 2 17.974 17.904 26.478 204.7 2 206.5 2 25.2 0.01 2 3.22 2 0.20 2 0.90 2 9 9 9 9 9 9 9 9 9 9

24 2 448.8 36.459 36.456 2 17.648 17.571 26.516 200.1 2 197.5 2 35.7 0.01 2 4.59 2 0.29 2 1.30 2 9 9 9 9 9 9 9 9 9 9

23 2 500.0 36.359 36.356 2 17.094 17.010 26.577 190.6 2 189.2 2 46.7 0.01 2 6.34 2 0.39 2 1.80 2 9 9 9 9 9 9 9 9 9 9

22 2 599.6 36.092 36.090 2 15.532 15.437 26.739 183.6 2 9 0.01 2 9.66 2 0.59 2 3.10 2 9 9 9 9 9 9 9 9 9 9

21 2 699.8 35.800 35.797 2 13.620 13.518 26.929 166.6 2 166.1 2 87.6 0.01 2 14.64 2 0.92 2 5.50 2 9 9 9 9 582.9 449.1 2 9 7.8247 2 9 9 9

20 2 800.4 35.505 35.504 2 11.580 11.475 27.101 156.9 2 156.5 6 108.8 0.01 2 19.43 2 1.19 2 8.90 2 9 9 9 9 692.1 489.9 2 9 7.7599 2 9 9 9

19 2 899.4 35.273 35.273 2 9.479 9.374 27.289 158.2 2 158.6 2 119.4 0.01 2 22.65 2 1.40 2 12.20 2 9 9 9 9 768.2 497.2 2 9 7.7117 2 9 9 9

18 2 1000.9 35.107 35.107 2 7.390 7.288 27.477 169.6 2 169.9 2 121.8 0.01 2 24.51 2 1.54 2 15.20 2 9 9 9 9 838.8 496.0 2 9 7.6811 2 9 9 9

17 2 1098.8 35.090 35.090 2 6.323 6.219 27.609 194.3 2 198.6 2 100.5 0.00 2 22.46 2 1.43 2 14.60 2 9 9 9 9 9 9 9 9 9 9

16 2 1303.1 35.075 35.075 2 5.283 5.168 27.729 235.3 2 232.9 2 73.8 0.00 2 19.73 2 1.29 2 13.10 2 9 9 9 9 9 9 9 9 9 9

15 2 1487.1 35.025 35.025 2 4.539 4.414 27.775 255.3 2 254.0 2 58.4 0.01 2 18.46 2 1.22 2 12.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1700.4 34.995 34.996 2 4.085 3.945 27.802 263.7 2 261.5 2 54.6 0.01 2 17.97 2 1.20 2 12.90 2 9 9 9 9 735.9 371.4 2 9 7.7332 2 9 9 9

13 2 1900.4 34.981 34.982 2 3.843 3.687 27.819 266.2 2 266.8 2 51.3 0.01 2 17.97 2 1.19 2 13.60 2 9 9 9 9 9 9 9 9 9 9

12 2 2099.3 34.973 34.973 2 3.645 3.473 27.835 267.7 2 268.1 2 51.7 0.01 2 17.78 2 1.21 2 14.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2302.1 34.976 34.976 2 3.505 3.316 27.854 266.6 2 265.1 2 56.0 0.01 2 18.07 2 1.26 2 16.80 2 9 9 9 9 9 9 9 9 9 9

10 2 2501.3 34.959 34.960 2 3.265 3.060 27.866 267.6 2 268.5 2 54.6 0.01 2 17.97 2 1.21 2 17.80 2 9 9 9 9 9 9 9 9 9 9

9 2 2700.9 34.948 34.948 2 3.063 2.842 27.878 268.9 2 269.5 2 55.4 0.01 2 17.78 2 1.21 2 19.20 2 9 9 9 9 9 9 9 9 9 9

8 2 2900.8 34.940 34.940 2 2.903 2.665 27.888 269.7 2 269.4 2 57.0 0.01 2 17.87 2 1.22 2 20.60 2 9 9 9 9 9 9 9 9 9 9

7 2 3100.0 34.929 34.929 2 2.739 2.483 27.896 272.9 2 269.2 2 58.7 0.01 2 17.58 2 1.20 2 21.10 2 9 9 9 9 730.3 344.7 2 9 7.7392 6 0 2 9 9

6 2 3299.0 34.920 34.920 2 2.586 2.313 27.904 274.7 2 274.3 2 55.1 0.01 2 17.48 2 1.20 2 22.30 2 9 9 9 9 9 9 9 9 9 9

5 2 3500.8 34.912 34.912 2 2.454 2.163 27.911 274.6 2 274.8 2 55.8 0.01 2 17.58 2 1.22 2 24.00 2 9 9 9 9 9 9 9 9 9 9

4 2 3799.0 34.900 34.900 2 2.312 1.992 27.917 274.5 2 274.6 2 57.5 0.01 2 17.68 2 1.23 2 26.30 2 9 9 9 9 9 9 9 9 9 9

3 2 4095.6 34.896 34.895 2 2.277 1.924 27.921 272.6 2 272.6 2 60.1 0.01 2 18.17 2 1.36 3 29.10 2 9 9 9 9 9 9 9 9 9 9

2 2 4400.4 34.889 34.888 2 2.251 1.863 27.922 269.3 2 269.6 2 63.6 0.01 2 18.66 2 1.32 2 32.70 2 9 9 9 9 9 9 9 9 9 9

1 2 4763.2 34.876 34.876 2 2.188 1.758 27.922 262.7 2 263.2 2 70.9 0.01 6 20.22 6 1.44 6 41.40 6 9 9 9 9 752.2 344.2 2 9 7.7260 2 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

178
A5R

NOAA Ship Ronald H. Brown

STATION 110 DATE 2/20/1998 LATITUDE 26.500° N

LONGITUDE 75.900° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 36.646 36.644 2 23.095 23.094 25.157 209.3 2 217.6 2 -6.8 0.01 2 0.00 2 0.01 2 0.70 2 1.97 2 1.14 2 0.16 2 2.03 2 283.9 321.0 2 2037.3 6 8.0935 2 5 2395 65.6 2 4.3 2

35 2 50.0 36.673 36.673 2 22.520 22.510 25.349 214.6 2 215.5 2 -2.6 0.01 2 0.00 2 0.00 2 0.70 2 9 9 9 9 288.9 319.3 2 2011.3 3 9 2392 2 64.1 2 4.2 2

34 2 96.2 36.656 36.671 2 22.034 22.015 25.479 214.3 2 213.9 2 0.9 0.10 2 0.00 2 0.01 2 0.70 2 2.05 2 1.18 2 0.16 2 1.82 2 301.3 326.7 6 2051.7 2 8.0763 2 5 2399 61.2 2 4.5 2

33 2 150.5 36.809 36.810 2 20.481 20.452 26.030 204.1 2 208.8 2 11.8 0.03 2 0.39 2 0.02 2 0.60 2 2.22 2 1.26 2 0.13 2 9 342.7 349.3 2 2088.8 2 8.0314 2 5 2409 55.0 2 9

32 2 200.2 36.749 36.733 2 19.659 19.622 26.208 208.5 2 202.2 2 21.9 0.02 2 0.88 2 0.03 2 0.60 2 2.28 6 1.29 6 0.10 6 9 356.5 351.7 2 2107.0 3 8.0168 2 9 2418 51.2 2 5.1 2

31 2 221.9 36.693 36.691 2 19.291 19.251 26.262 209.1 2 205.2 2 20.5 0.02 2 1.27 2 0.05 2 0.70 2 9 9 9 9 360.6 350.5 2 2092.8 2 8.0132 2 9 2400 50.7 2 5.2 2

30 2 249.8 36.641 36.638 2 18.901 18.856 26.326 208.5 2 206.2 2 21.2 0.01 2 1.76 2 0.08 2 0.80 2 2.32 2 1.30 2 0.05 2 0.57 2 363.5 347.7 2 2093.6 2 8.0082 2 5 2397 48.9 2 5.9 2

29 2 270.6 36.614 36.611 2 18.707 18.659 26.356 205.2 2 203.9 2 24.4 0.01 2 2.15 2 0.10 2 0.90 2 9 9 9 9 9 2094.4 2 8.0031 2 9 2394 47.8 2 6.1 2

28 2 300.3 36.592 36.591 2 18.541 18.488 26.384 208.6 2 206.7 2 22.3 0.01 2 2.44 2 0.12 2 0.90 2 2.33 2 1.30 2 0.04 2 9 377.6 356.0 2 2094.2 2 8.0030 2 5 2394 9 9

27 2 350.8 36.562 36.561 2 18.245 18.183 26.439 212.6 2 210.5 2 19.9 0.01 2 2.63 2 0.19 3 1.10 2 9 9 9 9 9 2092.5 2 8.0006 2 2387 2 2391 46.9 2 6.7 2

26 2 399.9 36.550 36.550 2 18.134 18.064 26.463 215.6 2 212.3 2 18.6 0.01 2 2.83 2 0.15 2 1.20 2 2.36 2 1.31 2 0.07 2 0.64 6 369.4 342.6 2 2093.9 2 8.0004 2 2387 2 2392 9 9

25 2 450.1 36.519 36.519 2 17.952 17.874 26.488 210.4 2 208.7 2 23.1 0.01 2 3.41 2 0.19 2 1.30 2 9 9 9 9 9 2097.1 2 9 2383 2 45.2 2 7.6 2

24 2 499.8 36.423 36.422 2 17.445 17.360 26.542 194.4 2 195.7 2 38.5 0.01 2 5.46 2 0.31 2 1.90 2 9 9 9 9 413.4 372.8 2 2109.2 2 7.9605 2 2382 2 2382 9 9

23 2 548.4 36.279 36.279 2 16.616 16.525 26.631 188.8 2 181.1 6 57.1 0.01 2 7.90 2 0.45 2 2.50 2 2.05 2 1.09 2 0.03 2 0.41 2 9 2119.7 2 7.9251 2 5 2371 43.9 2 11.4 2

22 2 649.9 35.935 35.933 2 14.542 14.443 26.837 176.1 2 174.2 2 74.6 0.01 2 12.39 2 0.75 2 4.50 2 9 9 9 9 530.8 424.9 2 2139.0 2 7.8599 2 2353 2 2354 9 9

21 3 748.4 35.670 35.666 2 12.748 12.644 27.005 162.5 2 160.8 2 97.7 0.01 2 16.98 2 1.03 2 7.00 2 1.26 2 0.65 2 0.02 2 0.34 2 626.8 465.4 2 2158.7 2 9 2339 2 45.6 2 19.9 2

20 2 849.3 35.354 35.354 2 10.298 10.194 27.214 149.1 2 155.7 2 117.2 0.01 2 21.67 2 1.34 2 11.10 2 9 9 9 9 740.7 496.1 2 2176.1 2 7.7268 2 5 2326 9 9

19 2 950.2 35.129 35.128 2 8.174 8.072 27.380 151.5 2 153.4 2 133.1 0.01 2 25.77 2 1.64 2 15.50 2 0.31 2 0.16 2 0.01 2 9 849.0 519.6 2 2190.2 2 7.6727 2 2320 2 2317 41.1 2 27.5 2

18 2 1043.4 35.069 35.069 2 6.955 6.852 27.509 170.5 2 171.8 2 123.0 0.01 2 24.99 2 1.60 2 16.40 2 0.29 2 0.15 2 0.01 2 0.34 2 862.0 499.7 2 2191.2 6 7.6728 2 5 2317 9 9

17 2 1201.5 35.085 35.085 2 5.782 5.672 27.675 218.2 2 217.1 2 85.9 0.01 2 20.79 2 1.35 2 13.60 2 9 9 9 9 9 2175.5 2 7.7089 2 2321 2 2316 41.1 2 22.7 2

16 2 1399.3 35.044 35.045 2 4.767 4.648 27.764 248.5 2 247.3 2 63.3 0.01 2 18.84 2 1.23 2 12.60 2 0.74 2 0.37 2 0.03 2 9 738.8 385.1 2 2165.5 2 7.7266 2 2322 2 2313 9 9

15 2 1600.6 34.995 34.996 2 4.191 4.059 27.790 262.0 2 260.2 2 55.0 0.01 2 18.06 2 1.19 2 12.40 2 0.97 2 0.47 2 0.04 2 1.62 2 9 2164.7 2 7.7317 2 2325 2 2314 41.2 2 20.2 2

14 2 1799.8 34.976 34.977 2 3.882 3.735 27.809 268.3 2 267.4 2 50.3 0.01 2 17.87 2 1.18 2 13.10 2 0.90 2 0.44 2 0.04 2 9 734.9 367.3 2 2161.2 2 7.7346 2 2322 2 2312 9 9

13 2 1998.6 34.982 34.982 2 3.737 3.573 27.832 267.7 2 266.6 2 52.4 0.01 2 18.06 2 1.21 2 14.50 2 0.52 2 0.26 2 0.02 2 9 9 2163.3 2 7.7378 2 9 2315 41.2 2 20.2 2

12 2 2198.7 34.974 34.972 2 3.539 3.359 27.848 267.5 2 267.4 2 53.3 0.01 2 17.96 2 1.21 2 16.00 2 9 9 9 9 719.6 353.2 2 2161.9 2 7.7383 2 9 2314 9 9

11 2 2400.1 34.966 34.967 2 3.360 3.163 27.861 268.1 2 267.6 2 54.7 0.01 2 18.16 2 1.21 2 17.60 2 0.30 2 0.15 2 0.01 2 0.81 2 9 2164.4 2 7.7399 2 9 2317 41.2 2 20.3 2

10 2 2600.5 34.955 34.954 2 3.134 2.921 27.875 269.4 2 270.7 2 53.6 0.01 2 18.16 2 1.22 2 19.00 2 9 9 9 9 723.3 348.0 2 2161.5 2 7.7407 2 2322 2 2315 9 9

9 2 2800.7 34.941 34.941 2 2.954 2.725 27.883 271.6 2 271.3 2 54.6 0.01 2 17.87 2 1.20 2 19.60 2 0.39 2 0.20 2 0.01 2 0.87 2 9 2163.6 2 9 9 41.5 2 20.1 2

8 2 3000.0 34.931 34.930 2 2.773 2.527 27.893 274.7 2 273.3 2 54.3 0.01 2 17.77 2 1.20 2 20.20 2 9 9 9 9 730.3 345.3 2 2165.2 2 7.7400 2 9 2318 9 9

7 2 3199.8 34.922 34.922 2 2.623 2.360 27.901 276.5 2 273.9 2 55.1 0.01 2 17.57 2 1.19 2 21.00 2 0.57 2 0.28 2 0.02 2 1.09 2 9 2164.3 2 9 9 41.4 2 19.4 2

6 2 3400.4 34.914 34.913 2 2.495 2.213 27.908 277.3 2 275.8 2 54.4 0.01 2 17.38 2 1.23 3 21.90 2 9 9 9 9 9 2166.8 2 7.7369 2 5 2318 9 9

5 2 3599.6 34.908 34.907 2 2.398 2.097 27.913 277.2 2 275.7 2 55.5 0.01 2 17.67 2 1.22 2 23.60 2 0.69 2 0.33 2 0.03 2 1.25 6 726.0 336.7 2 2168.1 2 7.7348 2 2323 2 2319 41.6 2 19.7 2

4 2 3829.8 34.902 34.901 2 2.327 2.003 27.918 276.3 2 274.7 2 57.3 0.01 2 17.87 2 1.24 2 25.90 2 0.64 2 0.31 2 0.04 2 1.19 2 9 2170.5 2 9 9 9 9

3 2 4201.4 34.896 34.894 2 2.280 1.915 27.922 274.3 2 272.3 2 60.5 0.01 2 18.45 2 1.34 3 29.30 2 0.52 6 0.25 6 0.03 6 9 740.8 341.4 2 2171.8 2 7.7328 2 5 2322 41.5 2 9

2 3 4497.3 34.890 34.888 2 2.253 1.854 27.924 269.9 2 269.1 2 64.2 0.01 2 19.23 2 1.33 2 33.20 2 0.37 2 0.19 2 0.03 2 0.83 2 745.2 342.6 2 2178.0 2 7.7311 2 9 2328 9 9

1 2 4817.4 34.879 34.878 2 2.209 1.772 27.924 264.5 2 263.6 2 70.4 0.01 6 20.41 6 1.40 6 39.60 6 0.21 2 0.12 2 0.04 3 0.56 2 755.9 346.4 2 2189.1 2 7.7275 2 2341 2 2338 45.3 3 21.2 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

179
A5R

NOAA Ship Ronald H. Brown

STATION 111 DATE 2/20/1998 LATITUDE 26.500° N

LONGITUDE 76.083° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.2 36.645 36.648 2 22.888 22.887 25.217 215.9 2 216.0 2 -4.4 0.01 2 0.00 2 0.00 2 0.60 2 9 9 9 9 285.8 320.4 6 2039.0 6 8.0916 6 2392 6 2395 9 9

35 2 41.2 36.673 36.672 2 22.554 22.546 25.338 216.5 2 216.9 2 -4.1 0.01 2 0.00 2 0.00 2 0.60 2 9 9 9 9 9 9 9 9 9 9

34 2 91.2 36.658 36.658 2 22.166 22.148 25.443 216.0 2 213.7 2 0.6 0.02 2 0.10 2 0.01 2 0.60 2 9 9 9 9 9 9 9 9 9 9

33 2 140.8 36.712 36.707 2 21.538 21.510 25.666 213.8 2 209.1 2 7.5 0.10 2 0.20 2 0.01 2 0.50 2 9 9 9 9 9 9 9 9 9 9

32 2 192.3 36.806 36.803 2 20.090 20.054 26.136 209.1 2 187.2 2 35.0 0.03 2 0.68 2 0.03 2 0.50 2 9 9 9 9 9 9 9 9 9 9

31 2 219.0 36.743 36.734 2 19.658 19.618 26.205 204.1 2 189.1 2 35.0 0.02 2 1.37 2 0.05 2 0.60 2 9 9 9 9 9 9 9 9 9 9

30 2 245.3 36.674 36.672 2 19.146 19.102 26.288 207.0 2 189.1 2 37.2 0.02 2 1.76 2 0.07 2 0.70 2 9 9 9 9 9 9 9 9 9 9

29 2 270.1 36.645 36.641 2 18.922 18.873 26.326 207.7 2 203.8 2 23.5 0.01 2 1.95 2 0.08 2 0.70 2 9 9 9 9 9 9 9 9 9 9

28 2 295.0 36.599 36.596 2 18.592 18.540 26.376 206.1 2 200.9 2 27.9 0.01 2 2.63 2 0.12 2 0.90 2 9 9 9 9 9 9 9 9 9 9

27 2 346.3 36.570 36.569 2 18.281 18.220 26.436 207.3 2 211.2 2 19.0 0.01 2 2.93 2 0.14 2 1.00 2 9 9 9 9 9 9 9 9 9 9

26 2 395.3 36.536 36.536 2 18.074 18.005 26.466 207.1 2 205.7 2 25.5 0.01 2 3.51 2 0.18 2 1.20 2 9 9 9 9 9 9 9 9 9 9

25 2 450.8 36.466 36.465 2 17.700 17.622 26.509 200.9 2 196.6 2 36.4 0.01 2 5.07 2 0.27 2 1.60 2 9 9 9 9 9 9 9 9 9 9

24 2 500.2 36.394 36.392 2 17.291 17.206 26.557 193.4 2 190.9 2 44.0 0.01 2 6.44 2 0.35 2 2.00 2 9 9 9 9 9 9 9 9 9 9

23 2 599.6 36.070 36.070 2 15.396 15.302 26.752 185.1 2 177.5 2 66.8 0.01 2 10.24 2 0.60 2 3.50 2 9 9 9 9 9 9 9 9 9 9

22 3 699.5 35.730 35.715 2 13.194 13.094 26.960 167.3 2 166.6 2 89.5 0.01 2 15.32 2 0.95 2 6.50 2 9 9 9 9 9 9 9 9 9 9

21 3 801.0 35.464 35.456 2 11.198 11.095 27.139 155.3 2 154.9 2 112.6 0.01 2 19.82 2 1.25 2 9.70 2 9 9 9 9 9 9 9 9 9 9

20 2 900.3 35.193 35.192 2 8.941 8.839 27.311 148.7 2 148.7 2 132.8 0.01 2 24.02 2 1.57 2 14.40 2 9 9 9 9 9 9 9 9 9 9

19 2 999.7 35.102 35.100 2 7.471 7.368 27.462 164.4 2 160.5 2 130.7 0.01 2 23.82 2 1.58 2 15.70 2 9 9 9 9 9 9 9 9 9 9

18 2 1100.7 35.074 35.073 2 6.479 6.373 27.577 188.8 2 188.5 2 109.6 0.01 2 22.55 2 1.51 2 15.70 2 9 9 9 9 9 9 9 9 9 9

17 2 1301.1 35.057 35.059 2 5.132 5.018 27.732 238.0 2 237.5 2 70.3 0.01 2 18.75 2 1.26 2 12.70 2 9 9 9 9 9 9 9 9 9 9

16 2 1500.7 35.009 35.009 2 4.393 4.268 27.778 258.1 2 257.5 2 56.1 0.01 2 17.67 2 1.20 2 12.40 2 9 9 9 9 9 9 9 9 9 9

15 2 1699.9 34.985 34.984 2 4.047 3.908 27.798 266.6 2 265.2 2 51.2 0.01 2 17.48 2 1.18 2 12.50 2 9 9 9 9 9 9 9 9 9 9

14 2 1899.0 34.973 34.973 2 3.841 3.686 27.813 268.7 2 261.1 3 57.0 0.01 2 17.28 2 1.18 2 13.20 2 9 9 9 9 9 9 9 9 9 9

13 2 2099.5 34.973 34.974 2 3.644 3.472 27.835 268.7 2 267.9 2 51.9 0.01 2 17.38 2 1.19 2 14.70 2 9 9 9 9 9 9 9 9 9 9

12 2 2299.9 34.969 34.970 2 3.443 3.255 27.854 268.3 2 267.9 2 53.7 0.01 2 17.58 2 1.20 2 16.80 2 9 9 9 9 9 9 9 9 9 9

11 2 2501.0 34.958 34.958 2 3.235 3.031 27.867 268.5 2 263.8 3 59.6 0.01 2 17.38 2 1.20 2 18.10 2 9 9 9 9 9 9 9 9 9 9

10 2 2701.0 34.947 34.947 2 3.048 2.827 27.878 269.8 2 268.8 2 56.3 0.01 2 17.38 2 1.20 2 19.10 2 9 9 9 9 9 9 9 9 9 9

9 2 2899.3 34.934 34.934 2 2.834 2.597 27.889 272.5 2 272.8 2 54.2 0.01 2 17.19 2 1.19 2 19.90 2 9 9 9 9 9 9 9 9 9 9

8 2 3098.3 34.925 34.925 2 2.677 2.423 27.898 275.1 2 274.0 6 54.4 0.01 2 16.99 2 1.18 2 20.60 2 9 9 9 9 9 9 9 9 9 9

7 2 3300.9 34.916 34.916 2 2.535 2.263 27.905 277.1 2 273.8 2 56.0 0.01 2 16.99 2 1.19 2 21.70 2 9 9 9 9 9 9 9 9 9 9

6 2 3497.9 34.909 34.910 2 2.425 2.135 27.911 277.3 2 275.9 2 55.0 0.01 2 17.19 2 1.20 2 23.20 2 9 9 9 9 9 9 9 9 9 9

5 2 3700.0 34.903 34.903 2 2.348 2.038 27.915 276.3 2 275.6 2 56.1 0.01 2 17.28 2 1.21 2 25.30 2 9 9 9 9 9 9 9 9 9 9

4 2 3981.1 34.899 34.898 2 2.301 1.960 27.919 275.2 2 270.2 2 62.2 0.01 2 17.77 2 1.24 2 27.50 2 9 9 9 9 9 9 9 9 9 9

3 2 4300.6 34.893 34.894 2 2.283 1.906 27.922 273.0 2 252.6 4 80.2 0.01 2 18.16 2 1.27 2 30.20 2 9 9 9 9 9 9 9 9 9 9

2 2 4600.2 34.886 34.887 2 2.250 1.838 27.924 269.1 2 268.2 2 65.2 0.01 2 18.94 2 1.32 2 34.80 2 9 9 9 9 9 9 9 9 9 9

1 2 4875.4 34.877 34.877 2 2.210 1.766 27.923 263.6 2 263.3 2 70.8 0.01 6 19.92 6 1.40 6 40.60 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

180
A5R

NOAA Ship Ronald H. Brown

STATION 112 DATE 2/21/1998 LATITUDE 26.500° N

LONGITUDE 76.200° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.2 36.645 36.644 2 22.773 22.772 25.250 218.1 2 217.0 2 -5.0 0.00 2 0.00 2 0.00 2 0.90 2 1.99 2 1.15 2 0.16 2 2.12 2 283.8 316.8 2 2038.8 2 8.0822 2 5 2388 63.8 2 9

35 2 23.9 36.650 36.651 2 22.762 22.757 25.259 217.3 2 217.4 6 -5.4 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 9 9 9 9 64.2 2 9

34 2 49.5 36.658 36.659 2 22.161 22.151 25.440 219.0 2 217.1 2 -2.8 0.01 2 0.00 2 0.01 2 0.90 2 2.03 2 1.17 2 0.17 2 9 292.0 318.3 2 2042.3 2 8.0830 2 2393 2 2393 66.4 2 9

33 2 75.4 36.652 36.652 2 22.075 22.060 25.462 217.2 2 217.1 2 -2.5 0.01 2 0.00 2 0.01 2 1.00 2 9 9 9 9 9 9 9 9 64.9 2 9

32 2 100.0 36.657 36.658 2 21.955 21.935 25.503 217.0 2 217.7 2 -2.6 0.01 2 0.00 2 0.01 2 1.00 2 2.04 2 1.18 2 0.16 2 9 295.5 319.5 2 2044.9 2 8.0822 2 2401 2 2395 61.3 2 9

31 2 127.0 36.652 36.655 2 21.773 21.748 25.553 217.7 2 218.4 2 -2.6 0.01 2 0.10 2 0.02 2 1.00 2 9 9 9 9 298.4 320.4 2 2045.3 2 8.0795 2 9 2394 59.2 2 9

30 2 149.2 36.652 36.653 2 21.613 21.584 25.601 217.6 2 218.5 2 -2.1 0.01 2 0.00 2 0.02 2 1.00 2 2.07 6 1.19 6 0.16 6 9 299.1 318.9 2 1845.0 3 8.0777 2 2409 2 2169 9 9

29 2 174.7 36.787 36.773 2 21.267 21.233 25.802 212.0 2 210.9 2 6.7 0.07 2 0.29 2 0.02 2 1.00 2 9 9 9 9 9 9 9 9 54.3 2 9

28 2 200.2 36.830 36.823 2 20.105 20.067 26.152 210.7 2 210.5 2 11.6 0.02 2 0.59 2 0.04 2 1.00 2 2.25 2 1.28 2 0.15 2 9 9 2087.8 2 8.0331 2 5 2409 9 9

27 2 249.0 36.731 36.735 2 19.514 19.468 26.236 208.3 2 205.4 2 19.3 0.01 2 1.17 2 0.06 2 1.30 2 9 9 9 9 355.0 347.3 2 2086.8 2 8.0189 2 2397 2 2398 49.1 2 9

26 2 299.7 36.585 36.589 2 18.489 18.436 26.392 199.1 2 199.9 2 29.4 0.01 2 3.32 2 0.14 2 1.50 2 2.32 2 1.28 2 0.03 2 9 9 9 9 9 9 9

25 2 349.8 36.552 36.553 2 18.217 18.156 26.439 205.3 2 204.4 2 26.1 0.01 2 3.61 2 0.17 2 1.60 2 9 9 9 9 9 2094.4 2 7.9940 2 2388 2 2388 9 9

24 2 399.0 36.541 36.542 2 18.088 18.018 26.467 212.8 2 209.3 2 21.8 0.01 2 3.51 2 0.18 2 1.60 2 2.33 2 1.29 2 0.06 2 9 9 9 9 9 9 9

23 2 498.8 36.380 36.380 2 17.204 17.120 26.566 191.7 2 191.2 2 44.2 0.00 2 6.63 2 0.36 2 2.40 2 9 9 9 9 430.7 384.6 2 2110.9 2 7.9474 2 2376 2 2376 43.8 2 9

22 2 600.4 36.047 36.048 2 15.232 15.138 26.770 175.9 2 179.2 2 66.0 0.00 2 10.73 2 0.63 2 4.10 2 1.89 2 1.00 2 0.02 2 9 9 2131.0 2 7.8851 2 2362 2 2359 9 9

21 2 700.4 35.730 35.735 2 13.104 13.005 26.978 166.2 2 162.9 2 93.6 0.00 2 15.52 2 0.94 2 6.50 2 9 9 9 9 9 2152.6 2 7.8124 2 2343 2 2343 9 9

20 2 791.4 35.416 35.422 2 10.744 10.645 27.182 157.3 2 154.5 2 115.7 0.00 2 20.31 2 1.28 2 10.40 2 0.76 2 0.39 2 0.01 2 9 9 2171.9 2 9 2332 2 9 9

19 2 901.4 35.152 35.155 2 8.552 8.453 27.340 149.3 2 148.2 2 135.8 0.00 2 24.61 2 1.61 2 15.40 2 9 9 9 9 727.3 450.5 3 2189.3 2 7.6753 2 2320 2 2317 41.5 2 9

18 2 999.4 35.091 35.094 2 7.453 7.351 27.456 167.7 2 162.9 2 128.4 0.00 2 24.41 2 1.61 2 16.30 2 0.33 6 0.17 6 0.01 6 9 857.5 508.6 2 2190.4 6 7.6698 2 2320 2 2316 9 9

17 2 1200.0 35.085 35.085 2 5.759 5.649 27.678 217.1 2 214.0 2 89.2 0.00 2 20.31 2 1.37 2 14.50 2 0.44 2 0.22 2 0.01 2 9 778.2 425.7 2 2176.0 2 7.7072 2 2318 2 2316 9 9

16 2 1401.0 35.026 35.026 2 4.671 4.553 27.760 250.8 2 248.5 2 62.9 0.00 2 18.16 2 1.22 2 12.80 2 0.97 2 0.48 2 0.04 2 9 9 9 9 9 41.6 2 9

15 2 1598.9 34.992 34.994 2 4.188 4.056 27.788 261.9 2 261.8 2 53.4 0.00 2 17.68 2 1.19 2 12.80 2 1.04 2 0.51 2 0.04 2 9 740.6 375.9 2 2160.1 2 7.7323 2 2306 2 2310 41.6 2 9

14 2 1800.2 34.979 34.979 2 3.944 3.797 27.805 266.8 2 258.8 4 58.5 0.00 2 17.48 2 1.18 2 13.30 2 9 9 9 9 9 9 9 9 41.2 2 9

13 2 2000.2 34.973 34.972 2 3.723 3.560 27.826 269.0 2 268.7 2 50.4 0.00 2 17.38 2 1.18 2 14.40 2 0.74 2 0.37 2 0.03 2 1.41 2 9 9 9 9 9 9

12 2 2194.9 34.973 34.974 2 3.566 3.386 27.844 266.8 2 267.5 2 53.0 0.00 2 17.48 2 1.20 2 16.00 2 9 9 9 9 730.9 359.7 2 2159.1 2 7.7382 2 2314 2 2311 9 9

11 2 2400.0 34.966 34.966 2 3.370 3.173 27.860 267.8 2 267.8 2 54.4 0.00 2 17.78 2 1.20 2 17.70 2 0.33 2 0.17 2 0.01 2 0.86 2 9 9 9 9 9 9

10 2 2599.8 34.954 34.955 2 3.165 2.952 27.872 267.9 2 269.2 2 54.8 0.00 2 17.68 2 1.21 2 18.90 2 0.29 2 0.15 2 0.01 2 0.78 2 9 9 9 9 9 9

9 2 2800.7 34.941 34.942 2 2.954 2.725 27.883 270.5 2 271.5 2 54.4 0.00 2 17.48 2 1.20 2 19.70 2 9 9 9 9 727.1 347.0 2 2161.8 2 7.7396 2 2318 2 2314 9 9

8 2 3001.8 34.931 34.932 2 2.784 2.538 27.892 273.8 2 273.4 2 54.1 0.00 2 17.38 2 1.19 2 20.30 2 0.47 2 0.23 2 0.02 2 0.97 2 9 9 9 9 9 9

7 2 3250.8 34.919 34.919 2 2.576 2.308 27.903 276.1 2 275.5 2 53.9 0.00 2 17.29 2 1.19 2 21.60 2 9 9 9 9 9 9 9 9 9 9

6 2 3495.2 34.909 34.909 2 2.422 2.132 27.911 276.1 2 275.7 2 55.2 0.00 2 17.29 2 1.20 2 23.40 2 0.64 2 0.32 2 0.03 2 1.22 2 9 9 9 9 41.4 2 9

5 2 3731.0 34.904 34.905 2 2.360 2.046 27.915 275.1 2 275.4 2 56.2 0.00 2 17.39 2 1.21 2 25.20 2 0.63 2 0.30 2 0.03 2 1.22 2 733.4 339.7 2 2166.5 2 7.7334 2 2319 2 2317 41.4 2 9

4 2 3998.1 34.898 34.898 2 2.312 1.969 27.919 274.8 2 274.3 2 58.0 0.00 2 17.78 2 1.23 2 27.20 2 0.63 2 0.31 2 0.04 2 1.21 2 9 9 9 9 41.6 2 9

3 2 4211.7 34.896 34.896 2 2.293 1.926 27.921 273.8 2 272.9 2 59.8 0.00 2 18.07 2 1.26 2 28.90 2 0.55 2 0.27 2 0.02 2 1.08 2 9 2171.2 2 7.7304 2 2328 2 2320 9 9

2 2 4493.9 34.890 34.891 2 2.272 1.872 27.923 270.8 2 270.3 2 62.8 0.00 2 18.56 2 1.29 2 32.10 2 0.44 2 0.22 2 0.03 2 0.91 2 9 9 9 9 9 9

1 2 4888.7 34.877 34.877 2 2.210 1.764 27.923 263.0 2 263.7 2 70.4 0.01 6 20.02 6 1.40 6 40.60 6 0.20 2 0.11 2 0.02 2 0.54 2 752.7 344.9 2 2188.7 2 7.7258 2 2341 2 2337 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

181
A5R

NOAA Ship Ronald H. Brown

STATION 113 DATE 2/21/1998 LATITUDE 26.483° N

LONGITUDE 76.300° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.3 36.656 36.655 2 22.694 22.693 25.280 221.0 2 217.2 2 -4.9 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 287.6 320.0 6 2040.1 6 9 2393 6 9 9

35 2 49.7 36.651 36.650 2 22.064 22.054 25.462 218.2 2 218.4 2 -3.8 0.00 2 0.00 2 0.00 2 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 100.3 36.658 36.660 2 21.968 21.948 25.500 216.5 2 218.0 2 -3.0 0.00 2 0.00 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

33 2 123.2 36.655 36.655 2 21.811 21.787 25.544 217.7 2 218.5 2 -2.8 0.01 2 0.00 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

32 2 150.0 36.653 36.655 2 21.655 21.625 25.590 218.5 2 218.9 2 -2.6 0.01 2 0.00 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

31 2 200.5 36.815 36.818 2 20.802 20.763 25.953 207.5 2 211.5 2 7.9 0.04 2 0.49 2 0.02 2 0.80 2 9 9 9 9 9 9 9 9 9 9

30 2 225.4 36.828 36.828 2 20.152 20.110 26.141 203.8 2 211.7 2 10.3 0.02 2 0.49 2 0.03 2 0.80 2 9 9 9 9 9 9 9 9 9 9

29 2 251.0 36.738 36.727 2 19.552 19.506 26.233 194.0 2 206.7 2 17.9 0.01 2 1.37 2 0.05 2 0.90 2 9 9 9 9 9 9 9 9 9 9

28 2 274.7 36.645 36.645 2 18.938 18.889 26.322 196.6 2 196.5 2 30.8 0.00 2 2.73 2 0.10 2 1.20 2 9 9 9 9 9 9 9 9 9 9

27 2 298.1 36.624 36.623 2 18.795 18.742 26.344 202.3 2 198.3 2 29.6 0.00 2 2.93 2 0.11 2 1.20 2 9 9 9 9 9 9 9 9 9 9

26 2 344.9 36.569 36.569 2 18.338 18.277 26.422 207.8 2 206.3 2 23.7 0.00 2 3.41 2 0.15 2 1.30 2 9 9 9 9 9 9 9 9 9 9

25 2 398.7 36.544 36.545 2 18.105 18.035 26.465 202.6 2 210.1 2 21.0 0.00 2 3.51 2 0.17 2 1.40 2 9 9 9 9 9 9 9 9 9 9

24 2 499.3 36.392 36.400 2 17.286 17.201 26.556 190.7 2 191.1 2 43.9 0.00 2 6.54 2 0.34 2 2.20 2 9 9 9 9 9 9 9 9 9 9

23 2 600.1 36.036 36.040 2 15.202 15.108 26.769 180.7 2 176.6 2 68.7 0.00 2 11.22 2 0.65 2 4.20 2 9 9 9 9 9 9 9 9 9 9

22 2 699.8 35.640 35.653 2 12.501 12.405 27.027 161.6 2 161.0 2 98.9 0.00 2 16.89 2 1.03 2 7.60 2 9 9 9 9 9 9 9 9 9 9

21 2 799.7 35.398 35.404 2 10.695 10.595 27.177 150.9 2 150.8 2 119.7 0.00 2 21.19 2 1.33 2 11.10 2 9 9 9 9 9 9 9 9 9 9

20 2 900.2 35.189 35.189 2 8.872 8.771 27.319 150.4 2 148.4 2 133.5 0.00 2 24.32 2 1.58 2 15.10 2 9 9 9 9 9 9 9 9 9 9

19 2 999.3 35.071 35.075 2 7.301 7.200 27.461 165.6 2 163.7 2 128.7 0.00 2 24.90 2 1.64 2 17.30 2 9 9 9 9 9 9 9 9 9 9

18 2 1150.6 35.087 35.088 2 5.963 5.857 27.653 205.6 2 206.1 2 95.6 0.00 2 21.29 2 1.42 2 15.20 2 9 9 9 9 9 9 9 9 9 9

17 2 1298.8 35.061 35.065 2 5.110 4.997 27.738 236.5 2 236.5 2 71.5 0.00 2 19.14 2 1.28 2 13.60 2 9 9 9 9 9 9 9 9 9 9

16 2 1449.3 35.019 35.021 2 4.542 4.420 27.769 253.5 2 253.7 2 58.7 0.00 2 18.26 2 1.22 2 13.00 2 9 9 9 9 9 9 9 9 9 9

15 2 1596.6 34.991 34.992 2 4.186 4.055 27.787 261.7 2 262.8 2 52.4 0.00 2 17.87 2 1.20 2 13.20 2 9 9 9 9 9 9 9 9 9 9

14 2 1749.0 34.982 34.982 2 3.974 3.831 27.804 266.8 2 266.4 2 50.6 0.00 2 17.78 2 1.19 2 13.70 2 9 9 9 9 9 9 9 9 9 9

13 2 1892.7 34.974 34.974 2 3.817 3.662 27.816 267.6 2 268.6 2 49.7 0.00 2 17.68 2 1.19 2 14.30 2 9 9 9 9 9 9 9 9 9 9

12 2 2044.5 34.973 34.974 2 3.692 3.525 27.830 267.4 2 268.5 2 50.9 0.00 2 17.68 2 1.20 2 15.20 2 9 9 9 9 9 9 9 9 9 9

11 2 2198.5 34.970 34.970 2 3.541 3.361 27.844 268.5 2 268.5 2 52.2 0.00 2 17.68 2 1.21 2 16.50 2 9 9 9 9 9 9 9 9 9 9

10 2 2394.1 34.965 34.966 2 3.365 3.169 27.859 267.7 2 268.0 2 54.3 0.00 2 17.78 2 1.22 2 18.30 2 9 9 9 9 9 9 9 9 9 9

9 2 2596.9 34.953 34.952 2 3.148 2.936 27.873 268.5 2 269.9 2 54.3 0.00 2 17.78 2 1.22 2 19.40 2 9 9 9 9 9 9 9 9 9 9

8 2 2798.4 34.941 34.941 2 2.948 2.719 27.884 270.5 2 271.2 2 54.8 0.00 2 17.68 2 1.22 2 20.60 2 9 9 9 9 9 9 9 9 9 9

7 2 3098.2 34.927 34.926 2 2.693 2.439 27.898 273.7 2 274.6 2 53.7 0.00 2 17.48 2 1.20 2 21.70 2 9 9 9 9 9 9 9 9 9 9

6 2 3394.4 34.915 34.914 2 2.497 2.216 27.908 276.4 2 276.1 2 54.1 0.00 2 17.29 2 1.20 2 23.30 2 9 9 9 9 9 9 9 9 9 9

5 2 3699.2 34.906 34.905 2 2.375 2.064 27.915 275.3 2 275.7 2 55.8 0.00 2 17.48 2 1.22 2 25.80 2 9 9 9 9 9 9 9 9 9 9

4 2 3998.9 34.900 34.899 2 2.311 1.968 27.920 274.8 2 274.1 2 58.2 0.00 2 17.87 2 1.25 2 28.70 2 9 9 9 9 9 9 9 9 9 9

3 2 4298.2 34.895 34.894 2 2.286 1.909 27.922 272.5 2 272.4 2 60.4 0.00 2 18.27 2 1.28 2 31.50 2 9 9 9 9 9 9 9 9 9 9

2 2 4597.5 34.890 34.888 2 2.266 1.854 27.925 268.5 2 268.8 2 64.5 0.00 2 18.95 2 1.33 2 35.90 2 9 9 9 9 9 9 9 9 9 9

1 2 4909.2 34.877 34.876 2 2.206 1.758 27.925 261.6 2 263.0 6 71.1 0.01 6 20.22 2 1.45 2 44.00 6 9 9 9 9 9 9 8.0896 6 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

182
A5R

NOAA Ship Ronald H. Brown

STATION 114 DATE 2/21/1998 LATITUDE 26.505° N

LONGITUDE 76.422° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.5 36.662 36.663 2 22.647 22.646 25.299 215.0 2 217.4 2 -5.0 0.00 2 0.00 2 0.00 2 0.60 2 2.01 2 1.16 2 0.17 2 2.12 2 285.0 316.6 2 2040.5 6 8.0895 2 2397 2 2396 65.9 2 9

35 2 35.7 36.656 36.656 2 22.518 22.511 25.335 215.8 2 207.0 4 5.9 0.00 2 0.00 2 0.00 2 0.60 2 2.01 2 1.16 2 0.16 2 9 9 2038.8 2 9 2392 2 65.3 2 9

34 2 69.5 36.660 36.659 2 22.167 22.153 25.442 217.1 2 202.5 4 11.8 0.00 2 0.00 2 0.01 2 0.60 2 9 9 9 9 289.8 315.9 2 2047.4 2 8.0844 2 2399 2 2399 64.7 2 9

33 2 103.9 36.672 36.672 2 22.071 22.050 25.482 217.6 2 214.6 2 0.0 0.00 2 0.00 2 0.01 2 0.50 2 2.09 2 1.20 2 0.17 2 9 291.5 316.6 2 2045.0 2 8.0814 2 2398 2 2395 63.2 2 9

32 2 139.3 36.685 36.683 2 21.970 21.942 25.525 217.6 2 214.3 2 0.7 0.01 2 0.00 2 0.01 2 0.50 2 9 9 9 9 9 2047.5 2 8.0786 2 2394 2 2396 62.7 2 9

31 2 176.0 36.685 36.687 2 21.554 21.519 25.645 212.2 2 210.0 2 6.6 0.06 2 0.00 2 0.03 2 0.50 2 2.09 2 1.20 2 0.16 2 9 302.9 322.3 2 2052.5 2 8.0709 2 9 2396 61.9 2 9

30 2 211.6 36.785 36.783 2 20.318 20.278 26.061 198.1 2 201.9 2 19.5 0.02 2 0.98 2 0.03 2 0.50 2 9 9 9 9 351.3 355.8 2 2088.8 2 8.0215 2 2405 2 2402 55.0 2 9

29 2 225.6 36.766 36.764 2 19.943 19.901 26.148 196.3 2 198.3 2 24.6 0.02 2 1.37 2 0.05 2 0.40 2 2.25 2 1.27 2 0.08 2 9 358.6 357.8 2 2093.3 2 8.0112 2 9 2400 52.8 2 9

28 2 251.7 36.688 36.685 2 19.293 19.247 26.262 193.2 2 191.5 2 34.2 0.01 2 2.24 2 0.07 2 0.50 2 9 9 9 9 9 2096.3 2 9 2403 2 9 9

27 2 275.5 36.612 36.621 2 18.696 18.647 26.358 193.0 2 200.6 2 27.7 0.01 2 2.83 2 0.10 2 0.70 2 2.30 2 1.29 2 0.04 2 9 372.0 353.0 2 2095.0 2 7.9980 2 9 2392 47.6 2 9

26 2 299.7 36.583 36.582 2 18.457 18.404 26.398 203.8 2 200.2 2 29.2 0.01 2 3.12 2 0.12 2 0.70 2 2.34 2 1.31 2 0.04 2 9 375.4 352.7 2 2090.9 2 8.0012 2 2390 2 2389 9 9

25 2 350.9 36.578 36.578 2 18.290 18.228 26.441 212.7 2 209.1 2 21.1 0.01 2 2.83 2 0.12 2 0.70 2 2.35 2 1.32 2 0.06 2 9 9 2088.6 2 9 2395 2 46.0 2 9

24 2 400.8 36.552 36.554 2 18.121 18.051 26.467 211.3 2 209.8 2 21.2 0.01 2 3.22 2 0.14 2 0.80 2 2.37 6 1.33 6 0.06 6 9 370.4 343.3 2 2091.2 2 8.0002 2 2386 2 2389 9 9

23 2 446.6 36.506 36.511 2 17.890 17.812 26.493 210.1 2 206.3 2 25.8 0.01 2 4.10 2 0.20 2 1.10 2 2.31 2 1.28 2 0.05 2 9 9 2096.8 2 7.9856 2 2391 2 2385 41.9 2 9

22 3 501.4 36.350 36.350 2 17.037 16.953 26.583 190.6 2 185.2 2 51.0 0.00 2 7.22 2 0.38 2 2.00 2 9 9 9 9 438.3 388.7 2 2114.4 2 7.9407 2 2374 2 2375 9 9

21 3 550.5 36.212 36.214 2 16.210 16.120 26.674 180.6 2 179.0 2 61.2 0.00 2 9.07 2 0.50 2 2.60 2 1.99 2 1.05 2 0.02 2 9 9 2122.9 2 9 2378 2 41.6 2 9

20 2 650.6 35.802 35.802 2 13.602 13.508 26.930 168.6 2 157.0 3 96.7 0.01 2 14.74 2 0.87 2 5.50 2 9 9 9 9 586.1 451.3 2 2147.3 2 7.8250 2 9 2344 9 9

19 2 748.1 35.481 35.485 2 11.336 11.239 27.125 161.3 2 154.6 2 112.0 0.00 2 19.62 2 1.21 2 9.20 2 0.89 2 0.47 2 0.01 2 9 695.5 486.8 2 2165.5 2 7.7528 2 5 2327 41.3 2 9

18 2 849.3 35.264 35.264 2 9.513 9.414 27.274 151.1 2 149.6 2 128.2 0.00 2 23.24 2 1.47 2 13.00 2 9 9 9 9 801.1 519.6 2 2181.2 2 7.7008 2 5 2320 9 9

17 2 951.5 35.094 35.095 2 7.732 7.633 27.417 157.3 2 156.7 2 132.8 0.00 2 25.10 2 1.63 2 16.40 2 0.30 2 0.15 2 0.01 2 9 864.8 519.4 2 2182.0 3 7.6671 2 5 2306 9 9

16 2 1052.9 35.074 35.075 2 6.601 6.499 27.560 183.8 2 184.3 2 112.9 0.00 2 23.15 2 1.51 2 15.50 2 9 9 9 9 834.5 475.5 2 2187.8 6 7.6838 2 2326 2 2318 9 9

15 2 1149.8 35.079 35.082 2 5.954 5.848 27.648 206.1 2 207.0 2 94.7 0.00 2 21.29 2 1.39 2 14.40 2 0.43 2 0.22 2 0.01 2 9 9 2177.0 2 7.7040 2 9 2316 41.6 2 9

14 2 1349.7 35.040 35.043 2 4.828 4.713 27.753 246.3 2 242.2 2 67.9 0.00 2 18.65 2 1.23 2 12.40 2 9 9 9 9 744.0 389.1 2 2167.5 2 7.7235 2 9 2314 9 9

13 2 1546.3 34.986 34.987 2 4.182 4.055 27.782 262.7 2 253.8 2 61.4 0.00 2 17.87 2 1.17 2 12.20 2 1.25 6 0.61 6 0.06 6 9 9 2163.4 2 7.7274 2 2310 2 2311 41.9 2 9

12 2 1746.4 34.980 34.982 2 3.974 3.831 27.802 267.7 2 234.3 4 82.7 0.00 2 17.78 2 1.17 2 12.90 2 0.94 2 0.46 2 0.04 2 9 730.5 366.6 2 2161.0 2 7.7326 2 2319 2 2311 9 9

11 2 1948.3 34.974 34.974 2 3.755 3.596 27.823 268.3 2 257.5 4 61.3 0.00 2 17.78 2 1.17 2 14.10 2 9 9 9 9 9 2159.9 2 7.7350 2 2311 2 2310 41.5 2 9

10 2 2148.7 34.971 34.972 2 3.587 3.411 27.839 267.1 2 267.8 2 52.5 0.01 2 17.87 2 1.18 2 15.40 2 0.53 2 0.26 2 0.02 2 9 714.8 351.6 2 2161.2 2 7.7370 2 9 2313 9 9

9 2 2399.5 34.962 34.962 2 3.326 3.130 27.861 267.3 2 250.0 4 72.6 0.00 2 17.97 2 1.19 2 17.60 2 9 9 9 9 9 2162.7 2 9 9 42.0 2 9

8 2 2649.9 34.949 34.950 2 3.079 2.863 27.876 268.5 2 256.7 4 68.1 0.01 2 17.87 2 1.19 2 19.00 2 0.34 2 0.17 2 0.01 2 0.85 2 714.6 342.8 2 2163.2 2 7.7398 2 9 2316 9 9

7 2 2900.9 34.937 34.936 2 2.866 2.628 27.888 271.1 2 269.6 2 57.1 0.01 2 17.68 2 1.18 2 19.40 2 9 9 9 9 9 2163.8 2 9 2317 2 41.5 2 9

6 2 3200.7 34.922 34.924 2 2.637 2.373 27.900 274.6 2 260.6 4 68.2 0.01 2 17.29 2 1.18 2 20.00 2 0.56 2 0.28 2 0.02 2 1.13 6 9 2157.6 2 7.7370 2 9 2309 9 9

5 2 3496.6 34.912 34.911 2 2.455 2.164 27.911 275.7 2 272.7 2 57.9 0.01 2 17.39 2 1.19 2 22.00 2 9 9 9 1.24 2 724.3 337.1 2 2164.7 2 7.7354 2 2325 2 2315 9 9

4 2 3789.8 34.903 34.903 2 2.342 2.022 27.917 275.2 2 268.4 4 63.4 0.01 2 17.68 2 1.23 2 24.40 2 0.67 2 0.33 2 0.03 2 1.24 6 9 2171.0 2 9 9 9 9

3 2 4099.6 34.898 34.898 2 2.301 1.947 27.921 273.1 2 272.7 2 59.8 0.01 2 18.07 2 1.25 2 27.30 2 0.59 2 0.29 2 0.03 2 1.12 2 735.0 339.1 6 2174.1 2 7.7327 2 5 2324 41.7 2 9

2 2 4496.3 34.891 34.891 2 2.268 1.868 27.924 270.3 2 266.1 2 67.1 0.01 2 18.75 2 1.29 2 31.80 2 0.52 6 0.26 6 0.03 6 0.88 2 732.7 337.0 2 2180.0 2 7.7310 2 9 2330 9 9

1 2 4910.5 34.875 34.876 2 2.188 1.740 27.924 261.2 2 260.2 2 74.1 0.01 2 20.41 2 1.41 2 41.50 2 0.17 2 0.10 2 0.02 2 0.48 2 758.4 347.1 2 2191.9 2 7.7248 2 9 2340 41.8 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

183
A5R

NOAA Ship Ronald H. Brown

STATION 115 DATE 2/21/1998 LATITUDE 26.500° N

LONGITUDE 76.517° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 36.443 36.448 2 23.579 23.578 24.861 211.0 2 215.7 2 -6.4 0.00 2 0.00 2 0.00 2 1.40 3 9 9 9 9 289.3 333.4 6 2035.5 2 8.0843 6 2388 6 2384 9 9

35 2 47.7 36.595 36.613 2 23.051 23.041 25.137 208.0 2 211.1 6 -0.1 0.08 2 0.00 2 0.00 2 4 9 9 9 9 9 9 9 9 9 9

34 2 101.1 36.656 36.657 2 22.103 22.083 25.461 214.6 2 216.4 2 -1.9 0.02 2 0.10 2 0.00 2 1.60 3 9 9 9 9 9 9 9 9 9 9

33 2 126.5 36.662 36.662 2 21.907 21.882 25.523 213.0 2 218.7 2 -3.4 0.00 2 0.00 2 0.02 2 1.60 3 9 9 9 9 9 9 9 9 9 9

32 2 173.7 36.900 36.902 2 21.445 21.411 25.838 198.1 2 198.4 2 18.3 0.02 2 0.68 2 0.02 2 1.50 3 9 9 9 9 9 9 9 9 9 9

31 2 216.3 36.742 36.746 2 19.802 19.762 26.166 196.0 2 197.5 2 26.0 0.01 2 1.37 2 0.03 2 1.70 3 9 9 9 9 9 9 9 9 9 9

30 2 241.3 36.687 36.682 2 19.299 19.255 26.258 197.2 2 199.3 2 26.4 0.01 2 1.85 2 0.05 2 1.70 3 9 9 9 9 9 9 9 9 9 9

29 2 266.8 36.612 36.608 2 18.692 18.644 26.358 199.6 2 203.3 2 25.0 0.01 2 2.83 2 0.10 2 1.70 3 9 9 9 9 9 9 9 9 9 9

28 2 290.8 36.577 36.575 2 18.394 18.343 26.409 201.8 2 206.5 2 23.2 0.01 2 3.22 2 0.12 2 1.90 3 9 9 9 9 9 9 9 9 9 9

27 2 319.6 36.560 36.561 2 18.233 18.177 26.438 206.6 2 209.4 2 21.0 0.01 2 3.22 2 0.14 2 2.50 3 9 9 9 9 9 9 9 9 9 9

26 2 351.5 36.553 36.551 2 18.155 18.093 26.456 208.6 2 211.0 2 19.8 0.01 2 3.32 2 0.15 2 3.20 3 9 9 9 9 9 9 9 9 9 9

25 2 402.4 36.536 36.537 2 18.034 17.964 26.477 211.0 2 210.7 2 20.7 0.01 2 3.61 2 0.16 2 3.20 3 9 9 9 9 9 9 9 9 9 9

24 2 450.1 36.475 36.474 2 17.704 17.626 26.515 204.4 2 204.0 2 29.0 0.00 2 4.78 2 0.23 2 3.40 3 9 9 9 9 9 9 9 9 9 9

23 2 499.9 36.299 36.312 2 16.735 16.652 26.616 186.7 2 185.6 2 52.0 0.00 2 7.80 2 0.42 2 4.30 3 9 9 9 9 9 9 9 9 9 9

22 2 601.8 35.961 35.962 2 14.671 14.579 26.826 170.3 2 168.1 2 79.9 0.00 2 12.88 2 0.75 2 6.40 3 9 9 9 9 9 9 9 9 9 9

21 2 700.6 35.568 35.575 2 11.998 11.904 27.067 157.1 2 154.1 2 108.6 0.00 2 18.54 2 1.14 2 10.10 3 9 9 9 9 9 9 9 9 9 9

20 2 800.3 35.322 35.329 2 10.128 10.031 27.215 148.7 2 149.7 2 124.3 0.00 2 22.25 2 1.41 2 13.80 3 9 9 9 9 9 9 9 9 9 9

19 2 900.2 35.148 35.148 2 8.366 8.268 27.364 153.9 2 153.0 2 132.2 0.00 2 24.60 2 1.60 2 17.30 3 9 9 9 9 9 9 9 9 9 9

18 2 997.8 35.085 35.080 2 6.888 6.790 27.528 174.1 2 175.3 2 119.9 0.00 2 23.82 2 1.57 2 17.80 3 9 9 9 9 9 9 9 9 9 9

17 2 1201.9 35.066 35.066 2 5.334 5.228 27.713 229.1 2 230.9 2 75.4 0.00 2 19.33 2 1.30 2 14.90 3 9 9 9 9 9 9 9 9 9 9

16 2 1400.8 35.010 35.010 2 4.481 4.365 27.768 255.0 2 255.1 2 57.7 0.00 2 18.06 2 1.21 2 14.40 3 9 9 9 9 9 9 9 9 9 9

15 2 1599.7 34.997 34.998 2 4.181 4.049 27.793 262.3 2 231.6 4 83.7 0.00 2 17.77 2 1.19 2 14.80 3 9 9 9 9 9 9 9 9 9 9

14 2 1801.9 34.991 34.991 2 4.003 3.855 27.809 264.0 2 216.6 4 100.2 0.00 2 17.77 2 1.19 2 15.40 3 9 9 9 9 9 9 9 9 9 9

13 2 2000.9 34.952 34.953 2 3.636 3.474 27.817 271.7 2 255.1 4 64.8 0.00 2 17.38 2 1.17 2 15.60 3 9 9 9 9 9 9 9 9 9 9

12 2 2201.2 34.965 34.953 2 3.520 3.340 27.842 269.3 2 267.9 2 53.0 0.00 2 17.57 2 1.19 2 17.40 2 9 9 9 9 9 9 9 9 9 9

11 2 2400.4 34.965 34.966 2 3.381 3.184 27.859 267.4 2 254.2 4 67.9 0.00 2 17.77 2 1.20 2 18.90 2 9 9 9 9 9 9 9 9 9 9

10 2 2600.8 34.954 34.954 2 3.169 2.956 27.872 268.4 2 244.9 4 79.1 0.00 2 17.77 2 1.21 2 20.00 2 9 9 9 9 9 9 9 9 9 9

9 2 2798.9 34.939 34.939 2 2.954 2.725 27.881 270.9 2 244.6 4 81.3 0.00 2 17.48 2 1.19 2 20.40 2 9 9 9 9 9 9 9 9 9 9

8 2 2984.5 34.932 34.933 2 2.811 2.566 27.891 272.5 2 245.2 4 82.0 0.00 2 17.48 2 1.19 2 21.30 2 9 9 9 9 9 9 9 9 9 9

7 2 3199.8 34.923 34.923 2 2.658 2.394 27.900 274.7 2 269.9 2 58.8 0.00 2 17.38 2 1.19 2 21.90 2 9 9 9 9 9 9 9 9 9 9

6 2 3395.7 34.915 34.914 2 2.513 2.231 27.907 275.9 2 260.8 4 69.3 0.00 2 17.28 2 1.19 2 22.80 2 9 9 9 9 9 9 9 9 9 9

5 2 3699.7 34.905 34.905 2 2.382 2.071 27.914 274.6 2 252.9 4 78.5 0.00 2 17.48 2 1.21 2 25.00 2 9 9 9 9 9 9 9 9 9 9

4 2 3998.9 34.900 34.900 2 2.325 1.982 27.919 274.5 2 264.1 4 68.1 0.00 2 17.77 2 1.23 2 27.10 2 9 9 9 9 9 9 9 9 9 9

3 2 4299.0 34.896 34.895 2 2.305 1.928 27.922 272.9 2 271.4 2 61.3 0.00 2 18.16 2 1.25 2 29.30 2 9 9 9 9 9 9 9 9 9 9

2 2 4600.4 34.892 34.892 2 2.296 1.883 27.925 270.9 2 245.1 4 87.9 0.00 2 18.55 2 1.28 2 31.70 2 9 9 9 9 9 9 9 9 9 9

1 2 4918.5 34.875 34.876 2 2.199 1.750 27.924 261.8 2 261.9 2 72.3 0.01 6 20.21 6 1.41 6 41.70 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

184
A5R

NOAA Ship Ronald H. Brown

STATION 116 DATE 2/21/1998 LATITUDE 26.500° N

LONGITUDE 76.617° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.3 36.548 36.547 2 23.302 23.301 25.023 212.1 2 215.2 2 -5.0 0.00 2 0.00 2 0.01 2 0.90 2 1.99 2 1.15 2 0.16 2 2.04 2 284.0 323.7 2 2037.2 2 8.0885 2 5 2390 66.5 2 4.2 2

35 2 39.0 36.578 36.583 2 23.099 23.091 25.108 213.3 2 212.0 2 -1.1 0.06 2 0.00 2 0.02 2 0.90 2 9 9 9 9 9 9 9 9 66.4 2 4.4 2

34 2 91.5 36.684 36.696 2 22.849 22.830 25.268 201.1 2 207.1 2 4.6 0.09 2 0.19 2 0.02 2 0.90 2 1.97 2 1.14 2 0.16 2 9 299.0 334.8 2 2052.0 2 8.0759 2 5 2399 62.3 2 4.4 2

33 2 141.0 36.879 36.880 2 21.823 21.795 25.713 193.3 2 196.1 2 19.2 0.03 2 0.97 2 0.04 2 0.80 2 9 9 9 9 335.6 360.8 2 2087.1 2 8.0356 2 2406 2 2411 58.1 2 4.5 2

32 2 201.4 36.776 36.768 2 20.107 20.069 26.110 192.5 2 193.0 2 29.2 0.01 2 1.75 2 0.05 2 0.90 2 2.23 2 1.25 2 0.05 2 9 363.7 365.3 2 2100.0 2 8.0064 2 5 2404 52.0 2 5.5 2

31 2 227.7 36.702 36.696 2 19.434 19.392 26.233 192.6 2 195.6 2 29.5 0.01 2 2.14 2 0.07 2 1.00 2 2.29 2 1.28 2 0.05 2 9 9 9 9 9 50.4 2 5.6 2

30 2 250.3 36.651 36.642 2 19.003 18.958 26.307 191.7 2 197.2 2 29.8 0.01 2 2.73 2 0.10 2 1.10 2 2.29 2 1.28 2 0.04 2 9 9 9 9 9 9 9

29 2 273.5 36.611 36.608 2 18.664 18.615 26.365 190.2 2 196.8 2 31.7 0.01 2 3.41 2 0.13 2 1.20 2 2.31 2 1.28 2 0.03 2 9 376.9 357.1 2 2100.8 2 7.9889 2 2389 2 2392 47.8 2 7.1 2

28 2 299.8 36.588 36.582 2 18.469 18.416 26.399 192.4 2 195.8 2 33.6 0.01 2 4.00 2 0.18 2 1.40 2 2.27 2 1.25 2 0.02 2 9 9 9 9 9 9 9

27 2 351.9 36.544 36.541 2 18.175 18.113 26.444 193.7 2 195.3 2 35.4 0.01 2 4.58 2 0.22 2 1.60 2 2.29 2 1.25 2 0.03 2 9 391.9 364.1 2 2105.3 2 7.9766 2 5 2389 45.8 2 8.0 2

26 2 402.1 36.479 36.477 2 17.769 17.700 26.498 193.1 2 193.7 2 38.9 0.00 2 5.56 2 0.27 2 1.90 2 2.19 6 1.20 6 0.03 6 9 9 9 9 9 9 9

25 2 450.9 36.385 36.384 2 17.227 17.151 26.560 185.0 2 187.2 2 48.0 0.01 2 7.02 2 0.37 2 2.30 2 1 1 0.03 2 9 428.3 382.9 2 2117.3 2 7.9428 2 2376 2 2380 43.9 2 10.4 2

24 2 502.6 36.202 36.201 2 16.151 16.070 26.676 181.1 2 179.3 2 61.2 0.00 2 9.46 2 0.53 2 3.30 2 1.93 2 1.03 2 0.02 2 9 9 9 9 9 9 9

23 2 548.7 36.066 36.057 2 15.327 15.241 26.761 174.1 2 172.9 2 71.7 0.00 2 11.51 2 0.66 2 4.20 2 9 9 9 9 9 9 9 9 42.6 2 9

22 2 652.1 35.701 35.698 2 12.950 12.858 26.984 161.5 2 160.2 2 97.1 0.00 2 16.68 2 1.02 2 7.20 2 1.28 2 0.67 2 0.01 2 9 9 9 9 9 9 9

21 2 749.9 35.417 35.406 2 10.877 10.782 27.157 149.2 2 150.4 2 119.0 0.00 2 21.27 2 1.33 2 11.10 2 9 9 9 9 731.5 502.9 2 2177.1 2 7.7320 2 2329 2 2329 41.8 2 23.7 2

20 2 849.9 35.190 35.189 2 8.872 8.777 27.318 149.0 2 149.1 2 132.8 0.00 2 24.60 2 1.58 2 15.00 2 0.35 2 0.19 2 0.00 2 9 828.7 522.9 2 2189.7 2 7.6831 2 2322 2 2321 9 9

19 2 950.2 35.065 35.067 2 7.125 7.030 27.479 164.8 2 165.4 2 128.2 0.00 2 24.99 2 1.65 2 17.40 2 9 9 9 9 872.1 510.0 2 2193.0 6 7.6673 2 2317 2 2317 9 9

18 2 1102.5 35.089 35.089 2 5.923 5.822 27.659 214.2 2 213.1 2 88.8 0.00 2 20.60 2 1.36 2 14.10 2 9 9 9 9 784.3 432.3 2 2180.8 2 7.7060 2 2318 2 2320 9 9

17 2 1301.1 35.029 35.029 2 4.662 4.553 27.761 251.9 2 250.2 2 61.1 0.00 2 18.55 2 1.23 2 12.90 2 9 9 9 9 9 2169.0 2 9 9 9 9

16 2 1499.7 34.977 34.980 2 4.037 3.916 27.790 265.5 2 264.8 2 51.5 0.00 2 17.86 2 1.19 2 13.00 2 1.19 6 0.59 6 0.05 6 9 741.9 373.7 2 2163.3 2 7.7289 2 2318 2 2311 9 9

15 2 1700.7 34.966 34.967 2 3.902 3.764 27.797 267.8 2 268.0 2 49.5 0.00 2 17.67 2 1.18 2 13.20 2 1.24 2 0.61 2 0.06 2 9 9 9 9 9 9 9

14 2 1896.8 34.963 34.963 2 3.809 3.654 27.808 267.6 2 269.7 2 48.7 0.00 2 17.67 2 1.18 2 13.50 2 9 9 9 9 724.8 360.8 2 2161.6 2 7.7321 2 2310 2 2311 9 9

13 2 2101.9 34.981 34.983 2 3.802 3.627 27.827 265.5 2 266.1 2 52.5 0.00 2 17.86 2 1.21 2 14.70 2 0.63 2 0.32 2 0.03 2 9 722.6 359.4 2 2161.9 2 7.7357 2 2307 3 2313 9 9

12 2 2299.8 34.958 34.959 2 3.486 3.297 27.842 269.4 2 270.7 2 50.5 0.00 2 17.67 2 1.20 2 15.70 2 9 9 9 9 9 9 9 9 9 9

11 2 2499.8 34.958 34.958 2 3.295 3.090 27.862 268.0 2 269.3 2 53.6 0.00 2 17.77 2 1.21 2 17.90 2 0.43 2 0.22 2 0.02 2 9 727.8 353.1 2 2160.1 2 7.7385 2 2314 2 2312 41.0 2 9

10 2 2700.0 34.945 34.945 2 3.051 2.830 27.876 269.7 2 270.8 2 54.2 0.00 2 17.67 2 1.20 2 19.00 2 0.50 2 0.24 2 0.02 2 1.00 6 9 2161.2 2 7.7379 2 2317 2 2313 9 9

9 2 2897.8 34.939 34.938 2 2.943 2.704 27.884 270.0 2 271.9 2 54.2 0.00 2 17.57 2 1.20 2 19.50 2 9 9 9 9 9 9 9 9 9 9

8 2 3101.5 34.929 34.929 2 2.759 2.503 27.894 272.4 2 273.3 2 54.5 0.00 2 17.57 2 1.19 2 20.80 2 0.61 6 0.30 6 0.02 6 1.05 2 9 2162.3 2 7.7382 2 2316 2 2314 9 9

7 2 3302.3 34.919 34.919 2 2.603 2.329 27.902 274.6 2 274.8 6 54.4 0.00 2 17.47 2 1.22 2 21.80 2 9 9 9 9 9 9 9 9 9 9

6 2 3501.6 34.912 34.913 2 2.487 2.195 27.909 275.6 2 275.5 2 54.9 0.00 2 17.48 2 1.20 2 23.00 2 0.64 2 0.31 2 0.03 2 1.23 2 9 2165.5 2 7.7349 2 2323 2 2316 9 9

5 2 3696.4 34.906 34.906 2 2.394 2.083 27.914 274.8 2 275.7 2 55.6 0.00 2 17.57 2 1.21 2 24.70 2 9 9 9 9 9 2167.6 2 7.7343 2 2319 2 2318 9 9

4 2 3901.8 34.902 34.901 2 2.347 2.014 27.917 274.3 2 274.0 2 57.9 0.00 2 17.87 2 1.22 2 26.40 2 0.66 2 0.32 2 0.03 2 1.21 2 9 9 9 9 9 9

3 2 4187.9 34.897 34.898 2 2.318 1.953 27.920 273.1 2 273.1 2 59.3 0.00 2 18.06 2 1.25 2 28.30 2 9 9 9 9 736.3 339.9 6 2171.7 2 7.7317 2 2325 2 2321 9 9

2 3 4500.6 34.892 34.893 2 2.295 1.894 27.924 270.0 2 270.3 2 62.6 0.00 2 18.55 2 1.29 2 31.70 2 0.48 2 0.24 2 0.03 2 0.96 2 9 2175.3 2 7.7309 2 2328 2 2325 9 9

1 2 4805.9 34.890 34.891 2 2.305 1.866 27.926 268.7 2 268.8 2 64.4 0.01 6 18.94 6 1.31 6 33.60 6 0.41 2 0.21 2 0.02 2 0.87 2 736.3 339.2 2 2177.7 2 7.7300 2 2332 2 2327 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

185
A5R

NOAA Ship Ronald H. Brown

STATION 117 DATE 2/22/1998 LATITUDE 26.500° N

LONGITUDE 76.683° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 3.1 36.516 36.521 2 23.253 23.252 25.012 218.3 2 214.9 2 -4.5 0.00 2 0.00 2 0.01 2 0.90 2 9 9 9 9 288.9 328.6 6 2036.4 6 8.0877 2 5 2388 9 9

35 2 49.5 36.644 36.646 2 22.945 22.935 25.205 214.1 2 214.3 2 -2.9 0.00 2 0.00 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

34 2 99.6 36.709 36.719 2 22.792 22.772 25.304 210.5 2 208.2 2 3.7 0.07 2 0.19 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 9 9

33 2 142.5 36.909 36.914 2 21.639 21.611 25.788 192.6 2 193.3 2 22.7 0.02 2 1.07 2 0.03 2 0.80 2 9 9 9 9 9 9 9 9 9 9

32 2 195.9 36.770 36.772 2 20.068 20.031 26.115 190.7 2 192.2 2 30.2 0.01 2 1.85 2 0.06 2 0.90 2 9 9 9 9 9 9 9 9 9 9

31 2 223.3 36.716 36.702 2 19.508 19.467 26.224 192.1 2 193.0 2 31.8 0.01 2 2.34 2 0.08 2 1.00 2 9 9 9 9 9 9 9 9 9 9

30 2 247.7 36.641 36.639 2 18.917 18.872 26.321 195.0 2 196.5 2 30.8 0.01 2 2.83 2 0.10 2 1.10 2 9 9 9 9 9 9 9 9 9 9

29 2 272.8 36.595 36.594 2 18.565 18.517 26.378 199.0 2 200.5 2 28.4 0.01 2 3.32 2 0.13 2 1.20 2 9 9 9 9 9 9 9 9 9 9

28 2 300.4 36.569 36.569 2 18.350 18.297 26.414 199.1 2 203.2 2 26.7 0.00 2 3.51 2 0.15 2 1.30 2 9 9 9 9 9 9 9 9 9 9

27 2 349.6 36.536 36.536 2 18.092 18.031 26.458 204.7 2 204.8 2 26.3 0.00 2 3.90 2 0.18 2 1.40 2 9 9 9 9 9 9 9 9 9 9

26 2 397.9 36.498 36.490 2 17.858 17.789 26.490 197.2 2 202.0 2 30.2 0.00 2 4.78 2 0.23 2 1.70 2 9 9 9 9 9 9 9 9 9 9

25 2 449.4 36.353 36.358 2 17.022 16.947 26.585 183.8 2 184.4 2 51.8 0.00 2 7.51 2 0.40 2 2.50 2 9 9 9 9 9 9 9 9 9 9

24 2 500.3 36.196 36.196 2 16.141 16.060 26.674 179.1 2 178.9 2 61.6 0.00 2 9.56 2 0.53 2 3.30 2 9 9 9 9 9 9 9 9 9 9

23 2 547.8 36.016 36.038 2 15.017 14.932 26.790 171.4 2 172.7 2 73.5 0.00 2 11.61 2 0.67 2 4.30 2 9 9 9 9 9 9 9 9 9 9

22 2 588.6 35.913 35.920 2 14.358 14.270 26.855 167.8 2 167.5 2 82.2 0.00 2 13.36 2 0.78 2 5.20 2 9 9 9 9 9 9 9 9 9 9

21 2 697.9 35.517 35.523 2 11.610 11.518 27.100 155.0 2 154.0 2 111.0 0.00 2 19.22 2 1.19 2 9.30 2 9 9 9 9 9 9 9 9 9 9

20 2 788.7 35.265 35.267 2 9.579 9.487 27.261 149.5 2 148.8 2 128.6 0.00 2 23.03 2 1.48 2 13.40 2 9 9 9 9 9 9 9 9 9 9

19 2 895.3 35.100 35.101 2 7.686 7.593 27.426 158.7 2 158.4 2 131.3 0.00 2 24.79 2 1.63 2 16.40 2 9 9 9 9 9 9 9 9 9 9

18 2 996.4 35.065 35.064 2 6.609 6.513 27.550 176.8 2 180.8 2 116.3 0.00 2 23.62 2 1.56 2 16.70 2 9 9 9 9 9 9 9 9 9 9

17 2 1199.4 35.025 35.025 2 4.701 4.601 27.752 243.2 2 247.1 2 63.9 0.00 2 18.64 2 1.24 2 13.20 2 9 9 9 9 9 9 9 9 9 9

16 2 1399.5 34.998 34.998 2 4.281 4.167 27.779 260.2 2 258.7 6 55.7 0.00 2 18.06 2 1.20 2 13.00 2 9 9 9 9 9 9 9 9 9 9

15 3 1599.6 34.979 2 4.038 3.908 27.793 264.6 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

14 2 1799.6 34.965 34.965 2 3.854 3.708 27.803 267.7 2 268.8 2 49.2 0.00 2 17.67 2 1.18 2 13.30 2 9 9 9 9 9 9 9 9 9 9

13 2 1996.4 34.959 34.958 2 3.692 3.529 27.817 269.9 2 270.5 2 48.9 0.00 2 17.57 2 1.18 2 13.90 2 9 9 9 9 9 9 9 9 9 9

12 2 2199.5 34.956 34.956 2 3.545 3.365 27.832 269.2 2 270.8 2 49.9 0.00 2 17.57 2 1.18 2 14.90 2 9 9 9 9 9 9 9 9 9 9

11 2 2393.1 34.959 34.959 2 3.365 3.169 27.854 268.5 2 269.4 2 52.9 0.00 2 17.67 2 1.20 2 17.00 2 9 9 9 9 9 9 9 9 9 9

10 2 2598.8 34.949 34.949 2 3.131 2.919 27.871 269.1 2 270.5 2 53.8 0.00 2 17.67 2 1.20 2 18.50 2 9 9 9 9 9 9 9 9 9 9

9 2 2796.6 34.942 34.942 2 2.998 2.768 27.880 269.1 2 271.1 2 54.5 0.00 2 17.57 2 1.20 2 19.40 2 9 9 9 9 9 9 9 9 9 9

8 2 2998.5 34.934 34.934 2 2.842 2.595 27.890 270.7 2 272.3 2 54.7 0.00 2 17.47 2 1.20 2 20.40 2 9 9 9 9 9 9 9 9 9 9

7 2 3197.5 34.924 34.925 2 2.687 2.422 27.898 273.5 2 274.1 2 54.3 0.00 2 17.47 2 1.19 2 21.10 2 9 9 9 9 9 9 9 9 9 9

6 2 3366.0 34.917 34.916 2 2.542 2.263 27.906 274.5 2 275.0 2 54.8 0.00 2 17.38 2 1.19 2 22.30 2 9 9 9 9 9 9 9 9 9 9

5 2 3598.0 34.908 34.907 2 2.414 2.113 27.912 274.8 2 276.2 2 54.9 0.01 2 17.47 2 1.20 2 24.10 2 9 9 9 9 9 9 9 9 9 9

4 2 3801.6 34.903 34.903 2 2.356 2.034 27.916 274.0 2 274.7 2 57.0 0.00 2 17.57 2 1.22 2 25.70 2 9 9 9 9 9 9 9 9 9 9

3 2 4001.2 34.897 34.897 2 2.292 1.949 27.919 271.1 2 272.4 2 60.1 0.01 2 18.06 2 1.25 2 28.70 2 9 9 9 9 9 9 9 9 9 9

2 2 4301.2 34.893 34.893 2 2.277 1.900 27.922 269.3 2 270.4 2 62.5 0.00 2 18.65 2 1.28 2 31.50 2 9 9 9 9 9 9 9 9 9 9

1 2 4659.6 34.893 34.893 2 2.316 1.895 27.925 269.6 2 270.0 6 62.9 0.01 6 18.65 6 1.29 6 32.10 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

186
A5R

NOAA Ship Ronald H. Brown

STATION 118 DATE 2/22/1998 LATITUDE 26.499° N

LONGITUDE 76.753° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 4.0 36.450 36.450 2 23.360 23.359 24.931 212.8 2 214.3 2 -4.2 0.00 2 0.00 2 0.00 2 0.70 2 1.94 2 1.12 2 0.16 2 1.95 2 288.5 329.5 2 2032.8 6 8.0808 2 2379 2 2379 9 4.6 2

35 2 24.0 36.450 36.453 2 23.361 23.356 24.933 214.3 2 213.1 2 -3.0 0.00 2 0.00 2 0.00 2 0.70 2 1.93 2 1.12 2 0.16 2 9 9 2030.8 2 8.0852 2 2391 2 2380 9 9

34 2 49.1 36.551 36.552 2 23.126 23.116 25.081 214.1 2 178.8 3 32.1 0.04 2 0.10 2 0.01 2 0.70 2 9 9 9 9 9 2035.5 2 8.0845 2 2386 2 2385 9 4.7 2

33 2 74.1 36.645 36.645 2 22.952 22.937 25.206 212.8 2 203.9 2 7.5 0.00 2 0.00 2 0.01 2 0.70 2 1.97 2 1.14 2 0.16 2 9 289.0 324.9 2 2038.5 2 8.0888 2 2403 2 2393 9 9

32 2 99.7 36.663 36.663 2 22.895 22.875 25.239 211.9 2 211.5 2 0.1 0.00 2 0.00 2 0.01 2 0.70 2 9 9 9 9 286.2 321.1 2 2040.2 2 9 2392 2 9 9

31 2 125.2 36.766 36.780 2 22.713 22.687 25.373 202.6 2 201.9 2 10.2 0.06 2 0.29 2 0.02 2 0.70 2 2.03 2 1.16 2 0.14 2 1.14 2 306.9 341.7 2 2060.1 2 8.0653 2 2399 2 2401 9 9

30 2 146.6 36.886 36.881 2 21.921 21.892 25.692 193.9 2 194.2 2 20.7 0.03 2 0.97 2 0.03 2 0.70 2 9 9 9 9 9 2083.3 2 9 9 9 4.8 2

29 2 172.8 36.863 36.866 2 20.814 20.781 25.983 189.4 2 190.1 2 29.1 0.01 2 1.37 2 0.05 2 0.70 2 2.15 2 1.21 2 0.06 2 9 9 2095.9 2 9 9 9 5.4 2

28 2 198.3 36.778 36.778 2 20.009 19.972 26.138 186.4 2 188.4 2 34.2 0.01 2 2.05 2 0.07 2 0.70 2 9 9 9 9 369.3 369.4 2 2100.4 2 8.0017 2 5 2401 9 6.1 2

27 2 221.1 36.710 36.711 2 19.483 19.442 26.226 186.6 2 177.3 3 47.6 0.00 2 2.54 2 0.09 2 0.80 2 2.19 2 1.22 2 0.04 2 9 9 2099.9 2 9 9 9 6.3 2

26 2 248.2 36.642 36.643 2 18.946 18.901 26.315 197.5 2 197.0 2 30.2 0.01 2 2.73 2 0.10 2 0.90 2 2.33 2 1.29 2 0.04 2 0.47 2 9 2095.2 2 9 9 9 9

25 2 272.9 36.610 36.612 2 18.635 18.586 26.372 190.5 2 187.1 2 41.5 0.00 2 3.51 2 0.15 2 1.10 2 2.31 2 1.27 2 0.03 2 9 387.7 367.0 2 2098.8 2 7.9875 2 2391 2 2389 9 7.6 2

24 2 300.2 36.570 36.569 2 18.361 18.308 26.412 199.8 2 190.3 2 39.5 0.00 2 3.71 2 0.16 2 1.20 2 2.32 2 1.28 2 0.03 2 9 9 2095.1 2 9 9 9 9

23 2 350.0 36.534 36.534 2 18.087 18.026 26.458 206.9 2 197.3 2 33.8 0.00 2 4.10 2 0.19 2 1.20 2 9 9 9 9 9 2095.6 2 9 9 9 7.6 2

22 2 390.7 36.493 36.491 2 17.829 17.761 26.493 203.1 2 191.1 2 41.2 0.00 2 4.78 2 0.24 2 1.50 2 2.27 6 1.24 6 0.03 6 9 398.6 365.0 2 2099.2 2 7.9750 2 2390 2 2381 9 9

21 2 443.9 36.353 36.365 2 17.027 16.952 26.584 184.9 2 176.0 2 60.1 0.00 2 7.41 2 0.40 2 2.30 2 9 9 9 9 9 2116.8 2 9 9 9 10.7 2

20 2 499.0 36.165 36.169 2 15.916 15.836 26.701 179.6 2 176.9 2 64.7 0.00 2 10.05 2 0.56 2 3.40 2 1.90 2 1.00 2 0.03 2 0.40 2 9 2130.8 2 9 2365 2 9 9

19 2 599.1 35.797 35.796 2 13.586 13.499 26.927 160.4 2 161.1 2 92.7 0.00 2 15.22 2 0.91 2 6.20 2 9 9 9 9 587.7 452.1 2 2151.4 2 7.8127 2 9 2342 9 17.5 2

18 2 697.0 35.475 35.482 2 11.309 11.219 27.122 154.9 2 150.1 2 116.6 0.00 2 19.81 2 1.23 2 10.00 2 0.93 2 0.48 2 0.01 2 9 9 9 9 2332 2 9 9

17 2 794.6 35.240 35.253 2 9.358 9.266 27.278 151.5 2 150.8 2 127.9 0.00 2 23.14 2 1.48 2 13.70 2 9 9 9 9 793.3 510.4 2 2196.5 2 7.6998 2 5 2335 9 25.2 2

16 2 897.8 35.126 35.131 2 7.788 7.694 27.433 164.5 2 164.2 2 124.8 0.00 2 23.92 2 1.56 2 15.40 2 0.45 2 0.23 2 0.01 2 0.39 2 825.0 495.8 2 2188.5 2 7.6817 2 2313 2 2319 9 9

15 2 998.8 35.086 35.085 2 6.620 6.524 27.565 188.8 2 186.9 2 110.1 0.00 2 22.75 2 1.51 2 15.60 2 9 9 9 9 820.8 467.7 2 2185.3 6 7.6880 2 2318 2 2318 9 25.1 2

14 2 1199.2 35.030 35.031 2 4.830 4.729 27.742 241.5 2 243.3 2 66.7 0.00 2 18.84 2 1.26 2 13.00 2 0.96 2 0.47 2 0.04 2 9 754.4 394.7 2 2168.7 2 7.7199 2 2312 2 2313 9 9

13 2 1399.3 35.002 35.002 2 4.347 4.232 27.775 255.7 2 247.9 3 65.9 0.00 2 18.16 2 1.21 2 12.80 2 9 9 9 9 9 2164.9 2 9 9 9 20.7 2

12 2 1598.8 34.976 34.976 2 3.995 3.866 27.794 264.7 2 263.3 2 53.4 0.00 2 17.67 2 1.19 2 13.00 2 1.16 6 0.57 6 0.06 6 9 737.7 370.8 2 2160.9 2 7.7292 2 2309 2 2309 9 9

11 2 1792.7 34.967 34.967 2 3.864 3.718 27.804 267.2 2 268.3 2 49.6 0.00 2 17.57 2 1.18 2 13.00 2 1.17 2 0.57 2 0.06 2 1.84 2 9 2160.7 2 9 9 9 20.4 2

10 2 1998.4 34.959 34.959 2 3.706 3.543 27.816 268.3 2 266.3 2 53.0 0.00 2 17.57 2 1.18 2 13.50 2 0.86 6 0.42 6 0.05 6 9 9 2160.2 2 9 9 9 9

9 2 2199.2 34.960 34.961 2 3.526 3.346 27.837 268.5 2 257.6 4 63.3 0.00 2 17.57 2 1.19 2 15.00 2 9 9 9 9 728.9 357.9 2 2157.7 2 7.7357 2 2312 2 2308 9 20.0 2

8 2 2399.0 34.955 34.956 2 3.284 3.089 27.859 268.1 2 264.5 2 58.4 0.00 2 17.67 2 1.20 2 17.10 2 0.51 2 0.25 2 0.02 2 1.07 2 9 2160.6 2 7.7388 2 2316 2 2313 9 9

7 2 2600.7 34.948 34.949 2 3.131 2.919 27.870 269.0 2 270.4 2 53.9 0.00 2 17.58 2 1.20 2 18.10 2 9 9 9 9 9 2161.4 2 7.7385 2 2314 2 2314 9 20.2 2

6 2 2797.8 34.942 34.943 2 3.006 2.776 27.880 269.3 2 271.0 2 54.5 0.00 2 17.58 2 1.20 2 18.90 2 0.49 2 0.24 2 0.02 2 0.99 2 9 2161.1 2 9 9 9 9

5 2 2997.8 34.933 34.933 2 2.830 2.583 27.890 270.7 2 271.5 2 55.6 0.00 2 17.58 2 1.20 2 20.00 2 9 9 9 9 726.1 344.3 2 2161.9 2 7.7409 2 2318 2 2315 9 9

4 2 3199.6 34.923 34.923 2 2.647 2.383 27.900 273.4 2 274.2 2 54.6 0.00 2 17.48 2 1.19 2 20.80 2 0.60 2 0.29 2 0.03 2 1.13 6 9 2162.5 2 9 9 9 9

3 2 3298.0 34.919 34.918 2 2.574 2.301 27.904 273.9 2 275.0 2 54.5 0.00 2 17.38 2 1.20 2 21.70 2 9 9 9 9 9 2162.6 2 9 9 9 20.0 2

2 2 3397.0 34.913 34.913 2 2.507 2.225 27.906 274.2 2 274.7 2 55.4 0.00 2 17.38 2 1.20 2 22.60 2 0.66 2 0.32 2 0.04 2 1.23 2 9 2164.4 2 9 9 9 9

1 2 3910.2 34.899 34.898 2 2.305 1.972 27.918 271.3 2 269.8 2 62.5 0.00 6 18.06 6 1.25 6 27.90 6 9 9 9 1.11 2 740.5 341.8 2 2170.6 2 7.7310 2 2322 2 2320 9 20.3 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

187
A5R

NOAA Ship Ronald H. Brown

STATION 119 DATE 2/22/1998 LATITUDE 26.500° N

LONGITUDE 76.784° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

36 2 2.8 36.243 36.243 2 24.154 24.153 24.539 217.3 2 210.9 2 -3.3 0.00 2 0.00 2 0.00 2 0.80 2 9 9 9 9 9 9 8.0912 2 2381 6 9 9

35 2 68.1 36.509 36.500 2 23.202 23.188 25.029 209.9 2 213.0 2 -2.3 0.03 2 0.10 2 0.00 2 0.60 2 9 9 9 9 9 9 9 9 9 9

34 2 105.7 36.643 36.644 2 23.002 22.980 25.194 210.5 2 210.5 2 0.7 0.08 2 0.00 2 0.00 2 0.60 2 9 9 9 9 9 9 9 9 9 9

33 2 104.5 36.642 36.645 2 23.003 22.982 25.193 210.4 2 211.8 2 -0.6 0.04 2 0.10 2 0.01 2 0.60 2 9 9 9 9 9 9 9 9 9 9

32 2 139.0 36.685 36.688 2 22.851 22.823 25.273 210.4 2 211.3 2 0.4 0.03 2 0.10 2 0.01 2 0.50 2 9 9 9 9 9 9 9 9 9 9

31 2 175.0 36.845 36.849 2 21.447 21.413 25.796 192.5 2 194.2 2 22.6 0.03 2 1.17 2 0.04 2 0.50 2 9 9 9 9 9 9 9 9 9 9

30 2 211.4 36.806 36.803 2 20.302 20.262 26.082 189.4 2 190.3 2 31.1 0.01 2 1.76 2 0.06 2 0.50 2 9 9 9 9 9 9 9 9 9 9

29 2 245.2 36.655 36.658 2 19.031 18.987 26.303 190.4 2 195.1 2 31.7 0.00 2 2.73 2 0.10 2 0.70 2 9 9 9 9 9 9 9 9 9 9

28 2 279.1 36.605 36.605 2 18.631 18.581 26.370 196.0 2 198.3 2 30.3 0.00 2 3.32 2 0.13 2 0.80 2 9 9 9 9 9 9 9 9 9 9

27 2 307.4 36.579 36.578 2 18.432 18.378 26.402 200.7 2 201.1 2 28.4 0.00 2 3.51 2 0.15 2 0.90 2 9 9 9 9 9 9 9 9 9 9

26 2 360.5 36.538 36.538 2 18.114 18.051 26.455 204.6 2 204.5 2 26.5 0.00 2 3.90 2 0.18 2 1.00 2 9 9 9 9 9 9 9 9 9 9

25 2 396.1 36.499 36.499 2 17.868 17.799 26.488 199.8 2 201.2 2 31.0 0.00 2 4.68 2 0.23 2 1.30 2 9 9 9 9 9 9 9 9 9 9

24 2 420.8 36.451 36.442 2 17.603 17.531 26.519 193.6 2 193.1 2 40.3 0.00 2 5.95 2 0.30 2 1.60 2 9 9 9 9 9 9 9 9 9 9

23 2 451.2 36.344 36.340 2 16.987 16.911 26.587 183.8 2 183.3 2 53.1 0.00 2 7.71 2 0.41 2 2.10 2 9 9 9 9 9 9 9 9 9 9

22 2 500.2 36.140 36.142 2 15.773 15.693 26.715 179.1 2 177.7 2 64.6 0.00 2 10.15 2 0.57 2 3.10 2 9 9 9 9 9 9 9 9 9 9

21 2 552.0 35.978 35.976 2 14.793 14.709 26.809 171.7 2 171.3 2 76.1 0.00 2 12.39 2 0.72 2 4.20 2 9 9 9 9 9 9 9 9 9 9

20 2 600.5 35.763 35.774 2 13.404 13.318 26.938 164.2 2 164.3 2 90.5 0.00 2 15.22 2 0.91 2 5.90 2 9 9 9 9 9 9 9 9 9 9

19 2 650.7 35.619 35.632 2 12.371 12.282 27.033 159.4 2 157.8 2 102.8 0.00 2 17.37 2 1.06 2 7.40 2 9 9 9 9 9 9 9 9 9 9

18 2 698.3 35.478 35.478 2 11.341 11.251 27.119 152.3 2 152.1 2 114.5 0.00 2 19.91 2 1.24 2 9.50 2 9 9 9 9 9 9 9 9 9 9

17 2 747.7 35.340 35.352 2 10.223 10.132 27.211 150.3 2 150.4 2 122.9 0.00 2 21.67 2 1.37 2 11.50 2 9 9 9 9 9 9 9 9 9 9

16 2 799.7 35.205 35.206 2 9.009 8.919 27.307 148.6 2 150.4 2 130.6 0.00 2 23.82 2 1.54 2 14.20 2 9 9 9 9 9 9 9 9 9 9

15 2 899.7 35.115 35.114 2 7.347 7.256 27.486 170.0 2 172.9 2 119.0 0.00 2 23.34 2 1.52 2 15.00 2 9 9 9 9 9 9 9 9 9 9

14 2 999.9 35.091 35.091 2 6.227 6.134 27.619 200.4 2 201.4 2 98.3 0.00 2 21.38 2 1.41 2 14.40 2 9 9 9 9 9 9 9 9 9 9

13 2 1099.3 35.055 35.056 2 5.308 5.212 27.706 229.5 2 228.8 2 77.6 0.00 2 19.72 2 1.30 2 13.40 2 9 9 9 9 9 9 9 9 9 9

12 2 1200.5 35.036 35.036 2 4.950 4.848 27.733 240.9 2 240.3 2 68.8 0.00 2 19.04 2 1.26 2 13.20 2 9 9 9 9 9 9 9 9 9 9

11 2 1297.8 35.026 35.026 2 4.720 4.611 27.753 249.2 2 247.1 2 63.8 0.00 2 18.75 2 1.24 2 13.10 2 9 9 9 9 9 9 9 9 9 9

10 2 1399.0 35.005 35.006 2 4.400 4.285 27.772 256.3 2 255.2 2 58.2 0.00 2 18.26 2 1.21 2 13.00 2 9 9 9 9 9 9 9 9 9 9

9 2 1498.9 34.980 34.982 2 4.066 3.945 27.789 264.3 2 263.9 2 52.2 0.00 2 17.87 2 1.18 2 12.90 2 9 9 9 9 9 9 9 9 9 9

8 2 1601.4 34.975 34.975 2 3.980 3.851 27.795 266.0 2 265.6 2 51.2 0.00 2 17.87 2 1.19 2 13.10 2 9 9 9 9 9 9 9 9 9 9

7 2 1699.3 34.965 34.965 2 3.864 3.727 27.800 268.2 2 269.1 2 48.7 0.00 2 17.68 2 1.18 2 12.90 2 9 9 9 9 9 9 9 9 9 9

6 2 1798.9 34.963 34.964 2 3.793 3.648 27.808 268.7 2 268.3 2 50.2 0.00 2 17.48 2 1.18 2 13.10 2 9 9 9 9 9 9 9 9 9 9

5 2 1899.3 34.962 34.962 2 3.770 3.616 27.810 269.0 2 269.7 2 49.0 0.00 2 17.48 2 1.18 2 13.00 2 9 9 9 9 9 9 9 9 9 9

4 2 1999.9 34.958 34.959 2 3.703 3.540 27.816 269.6 2 281.5 4 37.8 0.00 2 17.48 2 1.18 2 13.40 2 9 9 9 9 9 9 9 9 9 9

3 2 2100.6 34.957 34.957 2 3.643 3.471 27.822 269.9 2 270.9 2 49.0 0.00 2 17.48 2 1.18 2 13.80 2 9 9 9 9 9 9 9 9 9 9

2 2 2197.2 34.955 34.956 2 3.489 3.310 27.837 270.0 2 270.8 2 50.3 0.00 2 17.48 2 1.18 2 15.00 2 9 9 9 9 9 9 9 9 9 9

1 2 2322.6 34.955 34.955 2 3.359 3.170 27.851 269.2 2 270.5 6 51.8 0.00 6 17.58 6 1.19 6 16.40 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

188
A5R

NOAA Ship Ronald H. Brown

STATION 120 DATE 2/22/1998 LATITUDE 26.500° N

LONGITUDE 76.816° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

32 2 3.9 36.286 36.285 2 24.120 24.119 24.581 211.3 2 211.5 2 -3.9 0.00 2 0.00 2 0.00 2 1.20 2 1.85 2 1.09 2 0.14 2 1.85 2 286.4 337.0 2 2025.1 2 8.0902 2 2374 2 2376 64.9 2 9

31 2 25.5 36.293 36.293 2 24.094 24.089 24.597 214.3 2 211.5 2 -3.8 0.00 2 0.00 2 0.01 2 1.20 2 1.88 2 1.10 2 0.15 2 9 9 9 9 9 65.3 2 4.6 2

30 2 50.5 36.333 36.347 2 23.753 23.742 24.732 213.6 2 210.4 2 -1.5 0.08 2 0.00 2 0.01 2 1.10 2 1.89 2 1.10 2 0.14 2 9 294.8 341.9 2 2032.0 2 8.0854 2 5 2380 64.4 2 9

29 2 74.7 36.431 36.444 2 23.395 23.379 24.915 215.6 2 212.1 2 -2.0 0.08 2 0.00 2 0.01 2 1.00 2 9 9 9 9 9 9 9 9 63.9 2 9

28 2 99.4 36.512 36.532 2 23.298 23.277 25.008 217.0 2 213.9 2 -3.6 0.01 2 0.00 2 0.01 2 1.00 2 1.96 2 1.13 2 0.15 2 9 288.5 328.7 2 2038.6 2 8.0865 2 2390 2 2390 62.7 2 4.4 2

27 2 125.2 36.590 36.593 2 23.097 23.071 25.128 217.8 2 213.4 2 -2.4 0.02 2 0.00 2 0.01 2 1.00 2 9 9 9 9 290.3 328.2 2 2039.4 2 8.0880 2 9 2393 63.4 2 9

26 2 151.3 36.651 36.674 2 22.932 22.901 25.226 216.4 2 212.0 2 -0.5 0.02 2 0.10 2 0.01 2 1.00 2 1.97 2 1.14 2 0.14 2 1.72 2 292.3 328.3 2 2045.6 2 8.0827 2 2398 2 2396 60.2 2 9

25 2 174.4 36.794 36.803 2 22.123 22.088 25.569 207.2 2 199.4 2 14.9 0.06 2 0.68 2 0.04 2 0.90 2 9 9 9 9 9 9 9 9 55.7 2 9

24 2 199.6 36.849 36.848 2 21.011 20.972 25.922 196.6 2 192.5 2 26.0 0.02 2 1.27 2 0.05 2 1.00 2 9 9 9 9 9 9 9 9 9 9

23 2 225.3 36.776 36.783 2 20.014 19.972 26.137 193.1 2 191.0 2 31.6 0.01 2 1.76 2 0.06 2 1.00 2 9 9 9 9 368.7 368.9 2 2102.0 2 8.0022 2 2400 3 2404 9 9

22 2 248.6 36.672 36.672 2 19.193 19.148 26.275 197.6 2 196.5 2 29.6 0.01 2 2.34 2 0.09 2 1.20 2 2.25 2 1.26 2 0.03 2 9 9 9 9 9 9 9

21 2 273.1 36.609 36.610 2 18.666 18.617 26.363 198.9 2 199.1 2 29.4 0.00 2 3.12 2 0.13 2 1.30 2 9 9 9 9 9 2097.9 2 7.9946 2 2396 2 2393 47.6 2 6.3 2

20 2 302.8 36.581 36.581 2 18.431 18.377 26.404 199.3 2 200.1 2 29.4 0.00 2 3.51 2 0.16 2 1.40 2 2.22 6 1.25 6 0.05 6 0.43 6 9 9 9 9 9 9

19 2 348.2 36.544 36.543 2 18.137 18.076 26.452 203.8 2 205.3 2 25.6 0.00 2 3.80 2 0.18 2 1.60 2 9 9 9 9 381.0 353.3 2 2094.6 2 7.9915 2 2388 2 2387 9 9

18 2 399.8 36.504 36.507 2 17.903 17.834 26.484 202.9 2 203.0 2 29.0 0.00 2 4.39 2 0.22 2 1.80 2 2.29 2 1.26 2 0.03 2 9 9 9 9 9 9 9

17 2 453.5 36.356 36.359 2 17.051 16.975 26.581 189.0 2 186.4 2 49.6 0.00 2 7.22 2 0.39 2 2.60 2 9 9 9 9 9 9 9 9 43.9 2 9

16 2 507.2 36.111 36.126 2 15.578 15.498 26.737 179.5 2 175.9 2 67.4 0.00 2 10.44 2 0.59 2 3.80 2 1.66 6 0.87 6 0.02 6 9 496.4 414.6 2 2130.7 2 7.8911 2 5 2363 9 9

15 2 548.8 35.927 35.927 2 14.471 14.388 26.839 172.2 2 169.8 2 79.3 0.00 2 12.98 2 0.76 2 5.20 2 9 9 9 9 9 9 9 9 9 9

14 2 595.6 35.763 35.765 2 13.379 13.294 26.942 167.6 2 164.6 2 90.3 0.00 2 15.23 2 0.92 2 6.40 2 9 9 9 9 9 9 9 9 9 9

13 2 640.5 35.645 35.664 2 12.591 12.503 27.010 162.4 2 159.4 2 99.9 0.00 2 16.89 2 1.04 2 7.50 2 9 9 9 0.34 2 633.3 467.5 2 2157.2 2 7.7932 2 2340 2 2338 42.2 2 19.5 2

12 2 692.6 35.484 35.495 2 11.395 11.305 27.113 157.6 2 153.8 2 112.4 0.00 2 19.52 2 1.22 2 9.70 2 9 9 9 9 9 9 9 9 9 9

11 2 749.6 35.335 35.336 2 10.196 10.105 27.212 153.3 2 149.9 2 123.6 0.00 2 22.06 2 1.40 2 12.20 2 9 9 9 9 773.9 516.8 2 2178.2 6 7.7168 2 9 2324 9 9

10 2 801.3 35.181 35.182 2 8.708 8.619 27.334 153.0 2 151.1 2 131.8 0.00 2 24.31 2 1.57 2 15.00 2 0.36 2 0.19 2 0.00 2 9 9 9 9 9 9 9

9 2 846.9 35.133 35.126 2 7.925 7.836 27.416 162.0 2 165.8 2 122.3 0.00 2 23.73 2 1.55 2 15.40 2 9 9 9 9 851.0 515.2 2 2185.6 2 7.6814 2 2320 2 2315 41.6 2 9

8 2 900.8 35.087 35.084 2 6.698 6.611 27.553 176.4 2 183.0 2 113.4 0.00 2 23.05 2 1.52 2 15.80 2 0.40 2 0.20 2 0.01 2 0.47 2 839.1 480.4 2 2183.1 2 7.6847 2 9 2314 9 9

7 2 945.3 35.095 35.094 2 6.542 6.452 27.581 194.1 2 194.1 2 103.4 0.00 2 22.07 2 1.44 2 14.70 2 9 9 9 9 814.1 462.3 2 2179.7 2 7.6948 2 2321 2 2315 9 9

6 2 999.8 35.088 35.089 2 6.035 5.943 27.641 208.2 2 208.2 2 92.9 0.00 2 20.70 2 1.38 2 14.20 2 0.67 2 0.32 2 0.02 2 9 795.6 441.1 2 2177.7 2 7.7028 2 9 2316 9 9

5 2 1101.7 35.051 35.051 2 5.291 5.195 27.704 230.7 2 230.3 2 76.2 0.00 2 19.53 2 1.30 2 13.60 2 9 9 9 1.30 2 776.9 415.8 2 2169.3 2 7.7138 2 2317 2 2311 41.5 2 22.0 2

4 2 1195.1 35.041 35.040 2 5.023 4.921 27.729 240.0 2 238.7 2 69.9 0.00 2 19.14 2 1.27 2 13.40 2 0.93 2 0.45 2 0.03 2 9 9 9 9 9 9 9

3 2 1299.7 35.035 35.036 2 4.906 4.795 27.740 243.2 2 242.1 2 67.4 0.00 2 18.94 2 1.25 2 13.20 2 0.94 2 0.45 2 0.03 2 9 765.6 402.3 6 2167.6 2 7.7200 2 9 2312 9 9

2 2 1349.7 35.005 35.006 2 4.409 4.298 27.770 254.3 2 255.5 6 57.8 0.00 2 18.36 2 1.21 2 13.00 2 9 9 9 9 9 9 9 9 9 9

1 2 1382.1 35.000 35.001 2 4.332 4.219 27.775 256.3 2 257.5 2 56.5 0.00 6 18.16 6 1.23 6 13.00 6 1.05 2 0.51 2 0.04 2 1.60 2 750.6 383.6 2 2162.4 2 7.7257 2 2314 2 2309 41.6 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

189
A5R

NOAA Ship Ronald H. Brown

STATION 121 DATE 2/22/1998 LATITUDE 26.520° N

LONGITUDE 76.901° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

18 2 5.0 36.265 36.264 2 24.098 24.097 24.573 215.2 2 211.8 2 -4.1 9 9 9 9 1.86 2 1.09 2 0.14 2 1.76 2 289.2 340.0 2 2023.1 6 8.0882 2 2370 2 2372 9 9

17 2 25.6 36.265 36.263 2 24.098 24.093 24.575 215.0 2 211.7 2 -4.0 0.04 2 0.10 2 0.00 2 1.00 2 1.87 2 1.09 2 0.15 2 1.76 2 289.7 340.4 2 2023.1 2 8.0924 2 5 2375 9 9

16 2 51.0 36.265 36.265 2 24.085 24.074 24.582 214.5 2 211.3 6 -3.5 0.05 2 0.10 2 0.00 2 1.00 2 9 9 9 9 9 9 8.0884 2 9 9 9

15 2 74.6 36.269 36.268 2 24.062 24.046 24.595 214.9 2 210.9 2 -3.0 0.06 2 0.00 2 0.00 2 1.00 2 1.84 2 1.08 2 0.14 2 9 287.6 337.6 2 2024.2 2 8.0869 2 2370 2 2372 9 9

14 2 100.6 36.277 36.278 2 23.996 23.975 24.624 214.0 2 209.7 2 -1.6 0.08 2 0.00 2 0.00 2 1.10 2 9 9 9 9 9 9 8.0859 2 9 9 9

13 2 124.7 36.434 36.449 2 23.361 23.335 24.933 213.0 2 209.8 2 0.4 0.19 2 0.00 2 0.01 2 1.00 2 1.91 2 1.12 2 0.15 2 1.77 2 296.1 338.2 2 2035.4 2 8.0819 2 2384 2 2382 9 9

12 2 152.5 36.498 36.500 2 23.230 23.198 25.023 212.9 2 210.1 2 0.5 0.19 2 0.00 2 0.01 2 1.00 2 9 9 9 9 9 9 8.0838 2 9 9 9

11 2 174.5 36.604 36.605 2 23.003 22.967 25.172 212.7 2 210.9 2 0.4 0.12 2 0.00 2 0.01 2 1.00 2 1.96 2 1.13 2 0.16 2 9 293.2 330.3 2 2041.1 2 8.0844 2 2392 2 2392 9 9

10 2 199.6 36.632 36.643 2 22.878 22.837 25.232 212.5 2 209.7 2 2.1 0.10 2 0.10 2 0.01 2 0.90 2 9 9 9 9 9 9 8.0815 2 9 9 9

9 2 215.7 36.807 36.808 2 21.668 21.625 25.710 198.4 2 197.3 2 18.8 0.05 2 0.98 2 0.03 2 0.90 2 2.12 2 1.21 2 0.09 2 0.69 2 9 2080.1 2 8.0384 2 2402 2 2404 9 9

8 2 233.8 36.683 36.686 2 19.273 19.230 26.261 191.7 2 193.2 2 32.6 0.01 2 2.73 2 0.10 2 1.20 2 9 9 9 9 9 9 7.9932 2 9 9 9

7 2 249.8 36.612 36.622 2 18.723 18.678 26.349 192.1 2 194.7 2 33.5 0.01 2 3.41 2 0.14 2 1.40 2 2.24 2 1.24 2 0.03 2 9 392.3 372.6 2 2101.3 2 7.9877 2 2403 2 2392 9 9

6 2 275.4 36.583 36.580 2 18.444 18.395 26.399 194.9 2 196.1 2 33.3 0.01 2 3.90 2 0.17 2 1.50 2 9 9 9 9 9 9 7.9831 2 9 9 9

5 2 301.8 36.542 36.542 2 18.165 18.112 26.440 196.1 2 196.4 2 34.3 0.01 2 4.39 2 0.20 2 1.60 2 2.24 2 1.23 2 0.02 2 0.43 2 397.7 369.1 2 2102.9 2 7.9772 2 2385 2 2387 9 9

4 2 324.4 36.502 36.499 2 17.920 17.864 26.472 195.4 2 195.1 2 36.8 0.01 2 5.07 2 0.24 2 1.80 2 9 9 9 9 9 9 7.9714 2 9 9 9

3 2 350.8 36.458 36.453 2 17.642 17.582 26.508 195.0 2 192.5 2 40.7 0.01 2 5.76 2 0.29 2 2.00 2 2.18 2 1.19 2 0.03 2 9 412.4 374.9 6 2108.5 2 7.9614 2 2388 2 2382 9 9

2 2 376.0 36.435 36.432 2 17.504 17.440 26.527 194.4 2 191.4 2 42.4 0.01 2 6.05 2 0.31 2 2.10 2 9 9 9 9 9 9 7.9562 2 9 9 9

1 2 407.0 36.378 36.375 2 17.155 17.086 26.569 192.2 2 188.0 2 47.5 0.01 6 6.93 6 0.37 6 2.40 6 2.13 2 1.14 2 0.02 2 0.43 2 430.6 383.7 2 2114.7 2 7.9426 2 2374 2 2377 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

190
A5R

NOAA Ship Ronald H. Brown

STATION 122 DATE 2/23/1998 LATITUDE 27.001° N

LONGITUDE 79.200° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

18 2 3.8 36.176 36.176 2 26.089 26.088 23.896 204.8 2 203.6 2 -2.5 0.00 2 0.00 2 0.00 2 1.20 2 1.73 2 1.01 2 0.14 2 1.75 2 273.8 348.8 2 2014.1 6 8.0967 2 2365 2 2367 61.6 2 9

17 2 24.5 36.176 36.175 2 26.092 26.087 23.897 204.4 2 203.5 2 -2.4 0.00 2 0.00 2 0.00 2 1.20 2 1.74 2 1.02 2 0.15 2 9 273.9 349.0 2 2013.5 2 8.0983 2 2362 3 2367 61.9 2 9

16 2 50.1 36.162 36.166 2 25.750 25.739 23.997 203.0 2 202.8 2 -0.6 0.04 2 0.00 2 0.01 2 1.10 2 9 9 9 9 9 9 9 9 62.6 2 9

15 2 74.2 36.155 36.156 2 25.423 25.407 24.097 202.5 2 203.4 2 0.0 0.10 2 0.00 2 0.01 2 1.00 2 1.76 2 1.03 2 0.15 2 9 279.0 346.6 2 2016.6 2 8.0979 2 2362 3 2370 61.1 2 9

14 2 97.6 36.174 36.155 2 25.126 25.105 24.205 201.8 2 202.7 2 1.7 0.24 2 0.10 2 0.02 2 1.00 2 9 9 9 9 9 9 9 9 55.7 2 9

13 2 121.7 36.493 36.494 2 25.089 25.062 24.461 184.7 2 183.7 2 20.4 0.08 2 1.37 2 0.08 2 1.10 2 1.82 2 1.06 2 0.09 2 9 314.6 385.6 2 2055.2 3 8.0562 2 2385 2 2386 9 9

12 2 148.6 36.724 36.711 2 23.663 23.632 25.067 172.7 2 171.8 2 37.0 0.05 2 2.93 2 0.14 2 1.30 2 9 9 9 9 9 9 9 9 9 9

11 2 174.1 36.819 36.825 2 23.047 23.011 25.323 164.7 2 163.7 2 47.2 0.02 2 3.71 2 0.18 2 1.50 2 1.94 2 1.10 2 0.05 2 9 369.9 418.7 2 2104.9 3 8.0016 2 2403 2 2407 51.2 2 9

10 2 199.5 36.831 36.832 2 21.924 21.884 25.655 166.0 2 170.5 2 44.5 0.02 2 3.61 2 0.17 2 1.40 2 9 9 9 9 9 9 9 9 9 9

9 2 222.8 36.799 36.829 2 20.759 20.716 25.955 177.3 2 176.6 2 43.0 0.01 2 3.22 2 0.15 2 1.30 2 2.07 2 1.17 2 0.05 2 9 376.4 389.6 2 2108.1 2 7.9991 2 2400 3 2409 50.1 2 9

8 2 247.7 36.746 36.745 2 19.753 19.707 26.185 173.9 2 180.1 2 43.6 0.01 2 3.71 2 0.17 2 1.30 2 9 9 9 9 9 9 9 9 9 9

7 2 275.9 36.687 36.695 2 19.263 19.213 26.270 177.2 2 181.4 2 44.4 0.01 2 4.19 2 0.19 2 1.40 2 2.20 2 1.21 2 0.02 2 9 399.4 387.5 2 2114.1 2 7.9760 2 2395 2 2399 47.0 2 9

6 2 297.5 36.661 36.650 2 19.115 19.061 26.291 175.4 2 176.5 2 50.0 0.01 2 4.97 2 0.24 2 1.70 2 9 9 9 9 9 9 9 9 9 9

5 2 323.4 36.547 36.545 2 18.361 18.304 26.397 170.0 2 174.2 2 55.7 0.01 2 6.54 2 0.33 2 2.10 2 2.10 2 1.15 2 0.02 2 9 431.8 403.7 2 2123.1 2 7.9472 2 2399 2 2390 45.8 2 9

4 2 9 9 9 0.00 2 8.78 2 0.47 2 3.00 2 9 9 9 9 9 9 9 9 9 9

3 2 398.7 36.302 36.299 2 16.793 16.727 26.596 166.5 2 168.2 2 69.1 0.01 2 9.56 2 0.53 2 3.30 2 1.95 2 1.05 2 0.03 2 9 479.6 419.8 2 2133.8 2 7.9040 2 2372 2 2375 9 9

2 2 449.8 36.108 36.099 2 15.760 15.688 26.689 153.4 2 151.1 2 91.3 0.01 2 13.17 2 0.77 2 5.00 2 9 9 9 9 9 9 9 9 9 9

1 2 470.9 36.075 36.071 2 15.547 15.473 26.713 152.3 2 151.0 6 92.5 0.01 6 13.47 6 0.79 6 5.10 6 1.64 2 0.87 2 0.02 2 9 554.2 460.5 2 2151.3 2 7.8471 2 2360 2 2361 43.1 2 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

191
A5R

NOAA Ship Ronald H. Brown

STATION 123 DATE 2/23/1998 LATITUDE 27.002° N

LONGITUDE 79.283° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

20 2 3.1 36.170 36.169 2 25.833 25.832 23.971 206.2 2 204.2 2 -2.3 0.00 2 0.00 2 0.00 2 1.30 2 9 9 9 9 282.8 356.1 6 2013.4 6 9 2370 2 9 9

19 2 23.8 36.170 36.170 2 25.839 25.834 23.972 206.1 2 204.2 2 -2.3 0.00 2 0.00 2 0.00 2 1.30 2 9 9 9 9 9 9 9 9 9 9

18 2 48.3 36.169 36.168 2 25.840 25.829 23.974 205.5 2 204.4 2 -2.5 0.01 2 0.00 2 0.01 2 1.30 2 9 9 9 9 9 9 9 9 9 9

17 2 72.9 36.160 36.164 2 25.723 25.707 24.007 204.5 2 203.5 2 -1.2 0.04 2 0.00 2 0.01 2 1.30 2 9 9 9 9 9 9 9 9 9 9

16 2 99.0 36.158 36.159 2 25.174 25.152 24.178 204.0 2 203.6 2 0.6 0.17 2 0.00 2 0.02 2 1.20 2 9 9 9 9 9 9 9 9 9 9

15 2 127.4 36.426 36.427 2 24.837 24.809 24.487 185.9 2 186.0 2 19.0 0.11 2 1.37 2 0.07 2 1.30 2 9 9 9 9 9 9 9 9 9 9

14 2 149.4 36.526 36.528 2 24.579 24.547 24.644 181.8 2 179.2 2 26.6 0.07 2 1.95 2 0.10 2 1.40 2 9 9 9 9 9 9 9 9 9 9

13 2 175.2 36.863 36.871 2 22.821 22.785 25.421 158.6 2 158.9 2 52.7 0.01 2 4.29 2 0.21 2 1.70 2 9 9 9 9 9 9 9 9 9 9

12 2 199.5 36.827 36.827 2 20.618 20.580 26.012 169.7 2 172.5 2 47.6 0.01 2 3.90 2 0.18 2 1.50 2 9 9 9 9 9 9 9 9 9 9

11 2 216.4 36.694 36.694 2 19.458 19.418 26.220 172.2 2 165.4 3 59.6 0.01 2 5.75 2 0.29 2 2.00 2 9 9 9 9 9 9 9 9 9 9

10 2 250.1 36.691 36.684 2 19.266 19.220 26.271 180.2 2 185.3 2 40.5 0.01 2 3.61 2 0.16 2 1.30 2 9 9 9 9 9 9 9 9 9 9

9 2 276.5 36.605 36.601 2 18.680 18.631 26.357 171.6 2 177.7 2 50.7 0.01 2 5.46 2 0.27 2 1.90 2 9 9 9 9 9 9 9 9 9 9

8 2 299.0 36.573 36.571 2 18.388 18.335 26.408 185.7 2 189.7 2 40.0 0.01 2 4.68 2 0.22 2 1.60 2 9 9 9 9 9 9 9 9 9 9

7 2 324.4 36.508 36.504 2 18.023 17.967 26.451 166.3 2 179.9 2 51.5 0.01 2 6.34 2 0.33 2 2.10 2 9 9 9 9 9 9 9 9 9 9

6 2 347.6 36.421 36.425 2 17.546 17.487 26.503 172.4 2 174.3 2 59.3 0.01 2 7.71 2 0.41 2 2.60 2 9 9 9 9 9 9 9 9 9 9

5 2 394.9 36.257 36.255 2 16.542 16.477 26.620 160.7 2 165.7 2 72.8 0.00 2 10.15 2 0.57 2 3.60 2 9 9 9 9 9 9 9 9 9 9

4 2 453.8 36.045 36.043 2 15.303 15.232 26.743 153.2 2 154.2 2 90.5 0.00 2 13.37 2 0.78 2 5.10 2 9 9 9 9 9 9 9 9 9 9

3 2 497.4 35.783 35.776 2 13.847 13.774 26.856 136.7 2 137.1 2 115.3 0.00 2 17.57 2 1.07 2 7.40 2 9 9 9 9 9 9 9 9 9 9

2 2 550.2 35.702 35.698 2 13.333 13.255 26.902 138.4 2 136.2 2 119.0 0.00 2 18.54 2 1.14 2 8.10 2 9 9 9 9 9 9 9 9 9 9

1 2 610.2 35.502 35.550 2 11.767 11.687 27.055 144.4 2 9 0.00 6 19.52 6 1.22 6 9.30 6 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

192
A5R

NOAA Ship Ronald H. Brown

STATION 124 DATE 2/23/1998 LATITUDE 27.001° N

LONGITUDE 79.381° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

21 2 3.9 36.079 36.078 2 26.275 26.274 23.764 205.5 2 204.1 2 -3.5 0.00 2 0.00 2 0.00 2 1.40 2 9 9 9 9 276.3 353.9 6 2006.8 6 8.0968 2 2363 6 2358 62.3 2 4.4 2

20 2 27.5 36.161 36.161 2 26.244 26.238 23.839 204.7 2 203.7 2 -3.1 0.00 2 0.00 2 0.01 2 1.40 2 9 9 9 9 9 9 9 9 9 9

19 2 50.5 36.175 36.176 2 25.757 25.746 24.005 204.4 2 203.9 2 -1.7 0.02 2 0.00 2 0.01 2 1.30 2 9 9 9 9 9 9 9 9 62.6 2 4.4 2

18 2 74.5 36.161 36.162 2 25.504 25.488 24.076 202.3 2 201.9 2 1.2 0.16 2 0.00 2 0.02 2 1.30 2 9 9 9 9 9 9 9 9 9 9

17 2 101.9 36.147 36.148 2 25.224 25.202 24.155 201.6 2 204.7 2 -0.6 0.09 2 0.00 2 0.02 2 1.20 2 9 9 9 9 9 9 9 9 59.5 2 4.6 2

16 2 124.6 36.223 36.227 2 24.985 24.958 24.289 198.7 2 198.6 2 6.2 0.22 2 0.39 2 0.04 2 1.20 2 9 9 9 9 9 9 9 9 9 9

15 2 151.6 36.868 36.871 2 23.084 23.053 25.346 161.4 2 161.6 2 49.1 0.02 2 3.80 2 0.19 2 1.60 2 9 9 9 9 9 9 9 9 51.6 2 8.0 2

14 2 173.5 36.886 36.892 2 21.967 21.932 25.682 159.6 2 165.6 2 49.2 0.01 2 3.90 2 0.19 2 1.60 2 9 9 9 9 9 9 9 9 9 9

13 2 199.7 36.789 36.794 2 20.599 20.561 25.988 158.2 2 159.2 2 61.0 0.01 2 5.56 2 0.28 2 2.00 2 9 9 9 9 9 9 9 9 47.5 2 9.4 2

12 2 224.4 36.614 36.621 2 18.958 18.918 26.288 164.2 2 159.9 2 67.3 0.01 2 7.12 2 0.37 2 2.50 2 9 9 9 9 9 9 9 9 9 9

11 2 249.5 36.504 36.498 2 18.189 18.145 26.400 150.6 2 160.2 2 70.5 0.01 2 8.39 2 0.44 2 2.90 2 9 9 9 9 9 9 9 9 46.1 2 12.9 2

10 2 271.0 36.454 36.455 2 17.921 17.874 26.430 151.7 2 156.6 2 75.3 0.01 2 9.27 2 0.50 2 3.30 2 9 9 9 9 9 9 9 9 9 9

9 2 302.0 36.372 36.365 2 17.417 17.366 26.493 147.8 2 153.1 2 81.2 0.00 2 10.44 2 0.58 2 3.80 2 9 9 9 9 9 9 9 9 9 9

8 2 313.2 36.309 36.313 2 17.038 16.986 26.536 147.6 2 151.4 2 84.7 0.00 2 10.93 2 0.62 2 3.90 2 9 9 9 9 9 9 9 9 9 9

7 2 352.8 36.251 36.251 2 16.670 16.612 26.582 148.5 2 150.6 2 87.3 0.00 2 11.61 2 0.66 2 4.40 2 9 9 9 9 9 9 9 9 44.6 2 16.0 2

6 2 396.7 36.001 35.994 2 15.243 15.181 26.719 140.9 2 141.4 2 103.6 0.00 2 15.13 2 0.89 2 6.10 2 9 9 9 9 9 9 9 9 9 9

5 2 444.7 35.668 35.674 2 13.209 13.146 26.894 131.0 2 131.9 2 124.0 0.00 2 19.33 2 1.18 2 8.90 2 9 9 9 9 9 9 9 9 9 9

4 2 499.8 35.517 35.515 2 12.279 12.212 26.963 128.2 2 127.0 2 134.2 0.00 2 21.48 2 1.33 2 10.30 2 9 9 9 9 9 9 9 9 9 9

3 2 549.4 35.412 35.408 2 11.578 11.507 27.016 126.9 2 126.1 2 139.2 0.00 2 22.94 2 1.44 2 11.50 2 9 9 9 9 9 9 9 9 42.1 2 9

2 2 565.0 35.352 35.339 2 11.220 11.148 27.036 126.0 2 123.4 2 144.0 0.00 2 23.92 2 1.50 2 12.40 2 9 9 9 9 9 9 9 9 9 9

1 2 662.4 35.098 35.100 2 8.848 8.775 27.243 132.0 2 128.6 6 153.5 0.00 6 26.95 6 1.71 6 16.60 6 9 9 9 9 9 9 9 9 41.4 2 29.8 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

193
A5R

NOAA Ship Ronald H. Brown

STATION 125 DATE 2/23/1998 LATITUDE 27.038° N

LONGITUDE 79.481° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

23 2 4.0 36.101 36.100 2 26.487 26.486 23.713 208.5 2 202.3 2 -2.5 0.01 2 0.10 2 0.00 2 1.30 2 1.69 2 1.00 2 0.15 2 1.69 2 272.9 352.2 2 2007.7 6 8.1011 2 2371 2 2362 9 9

22 2 25.5 36.109 36.117 2 26.454 26.448 23.733 203.9 2 202.6 2 -2.7 0.01 2 0.10 2 0.01 2 1.30 2 1.72 6 1.00 6 0.15 6 9 9 9 8.1006 2 9 9 9

21 2 51.6 36.153 36.154 2 25.330 25.319 24.121 206.5 2 205.7 2 -2.0 0.02 2 0.10 2 0.01 2 1.10 2 1.77 2 1.04 2 0.58 4 1.70 2 9 9 8.0944 2 9 9 9

20 2 75.5 36.141 36.142 2 25.160 25.143 24.167 202.5 2 204.2 2 0.1 0.12 2 0.10 2 0.02 2 1.10 2 1.76 2 1.04 2 0.14 2 9 283.0 347.3 2 2019.7 2 8.0911 2 2361 3 2369 9 9

19 2 99.9 36.148 36.150 2 25.125 25.103 24.186 199.3 2 202.5 2 1.9 0.28 2 0.10 2 0.03 2 1.10 2 1.76 2 1.04 2 0.14 2 9 9 9 8.0894 2 9 9 9

18 2 124.4 36.412 36.358 2 24.562 24.535 24.560 188.1 2 189.8 2 16.3 0.16 2 1.07 2 0.07 2 1.20 2 1.81 2 1.06 2 0.10 2 1.12 2 310.4 372.2 2 2043.9 3 8.0606 2 2382 2 2376 9 9

17 2 150.5 36.864 36.866 2 22.690 22.659 25.457 159.1 2 159.1 2 53.0 0.02 2 4.19 2 0.21 2 1.60 2 9 9 9 9 9 9 7.9906 2 9 9 9

16 2 175.3 36.856 36.836 2 21.030 20.996 25.919 155.7 2 160.2 2 58.2 0.01 2 5.07 2 0.25 2 1.80 2 1.98 2 1.12 2 0.04 2 9 415.3 432.7 2 2125.6 3 7.9665 2 2404 3 2407 9 9

15 2 200.7 36.750 36.752 2 19.631 19.594 26.216 162.9 2 185.7 3 38.5 0.01 2 3.02 2 0.12 2 1.10 2 9 9 9 9 9 9 4 9 9 9

14 2 225.5 36.536 36.540 2 18.445 18.405 26.358 152.5 2 155.6 2 73.9 0.01 2 8.39 2 0.45 2 2.80 2 1.96 2 1.07 2 0.02 2 0.23 2 9 9 7.9144 2 9 9 9

13 2 251.6 36.430 36.429 2 17.816 17.773 26.436 150.5 2 153.0 2 79.4 0.01 2 9.76 2 0.54 2 3.40 2 9 9 9 9 484.0 442.7 2 2142.6 2 7.8981 2 2387 2 2381 9 9

12 2 267.4 36.415 36.412 2 17.674 17.628 26.461 150.0 2 155.2 2 77.8 0.01 2 9.76 2 0.54 2 3.40 2 1.93 2 1.03 2 0.02 2 9 9 9 7.8996 2 9 9 9

11 2 298.7 36.299 36.296 2 16.992 16.942 26.539 149.0 2 151.6 2 84.7 0.01 2 11.22 2 0.63 2 4.00 2 1.82 2 0.98 2 0.01 2 0.25 2 505.6 446.9 2 2146.3 2 7.8783 2 2392 3 2373 9 9

10 2 325.1 36.135 36.135 2 16.010 15.958 26.644 145.2 2 145.2 2 95.9 0.01 2 13.37 2 0.78 2 5.00 2 1.67 6 0.89 6 0.02 2 9 9 9 7.8497 2 9 9 9

9 2 349.3 36.089 36.087 2 15.761 15.706 26.667 144.0 2 144.2 2 98.2 0.01 2 13.86 2 0.82 2 5.30 2 9 9 9 9 9 9 7.8393 2 9 9 9

8 2 397.9 35.762 35.761 2 13.804 13.746 26.843 135.4 2 134.5 2 118.1 0.01 2 18.06 2 1.10 2 7.60 2 1.28 2 0.68 2 0.01 2 0.27 6 650.1 503.2 2 2170.2 2 7.7778 2 2352 2 2345 9 9

7 2 449.1 35.414 35.410 2 11.614 11.556 27.006 126.5 2 124.8 2 140.2 0.01 2 22.75 2 1.44 2 11.00 2 9 9 9 9 9 9 7.7067 2 9 9 9

6 2 499.0 35.261 35.252 2 10.526 10.465 27.086 125.5 2 123.3 2 148.2 0.01 2 24.80 2 1.59 2 12.90 2 0.65 2 0.34 2 0.01 2 9 842.6 569.1 2 2190.9 2 7.6745 2 2317 2 2319 9 9

5 2 547.5 35.107 35.108 2 9.400 9.338 27.158 124.8 2 120.3 2 158.3 0.01 2 27.05 2 1.75 2 15.40 2 9 9 9 0.23 2 9 9 7.6424 2 9 9 9

4 2 598.4 34.985 34.983 2 8.193 8.130 27.252 126.9 2 123.1 2 163.4 0.01 2 28.81 2 1.89 2 18.40 2 0.24 2 0.13 2 0.01 2 9 980.0 600.3 2 2206.6 2 7.6151 2 2323 3 2310 9 9

3 2 647.6 34.936 34.935 2 7.522 7.457 27.313 132.5 2 128.8 2 162.2 0.01 2 29.11 2 1.94 2 19.90 2 9 9 9 9 9 9 7.6080 2 9 9 9

2 2 700.6 34.901 34.901 2 7.036 6.968 27.355 137.9 2 132.2 2 162.1 0.01 6 29.60 6 1.98 6 21.50 6 0.10 2 0.06 2 0.01 2 0.16 2 9 9 7.6024 2 9 9 9

1 2 738.3 34.898 34.897 2 6.624 6.554 27.409 145.3 2 139.4 6 157.8 9 9 9 9 0.08 2 0.04 2 0.01 2 0.16 2 1018.1 585.5 2 1987.1 3 7.6071 2 2326 2 2080 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

194
A5R

NOAA Ship Ronald H. Brown

STATION 126 DATE 2/23/1998 LATITUDE 27.013° N

LONGITUDE 79.605° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

21 2 3.3 36.131 2 26.589 26.588 23.704 211.0 2 201.9 2 -2.4 9 9 9 9 9 9 9 9 278.1 360.4 6 2011.0 6 8.1005 2 2362 6 63.1 2 4.4 2

20 2 25.3 36.129 36.131 2 26.590 26.584 23.705 201.1 2 201.7 2 -2.2 0.01 2 0.10 2 0.01 2 1.40 2 9 9 9 9 9 9 9 9 9 9

19 2 51.7 36.158 36.158 2 25.523 25.512 24.065 196.8 2 206.2 2 -3.2 0.00 2 0.10 2 0.01 2 1.30 2 9 9 9 9 9 9 9 9 62.9 2 4.3 2

18 2 76.0 36.179 36.175 2 25.264 25.247 24.164 189.1 2 202.7 2 1.2 0.16 2 0.10 2 0.02 2 1.30 2 9 9 9 9 9 9 9 9 9 9

17 2 100.1 36.306 36.334 2 24.894 24.872 24.376 175.0 2 190.0 2 15.0 0.14 2 1.17 2 0.06 2 1.30 2 9 9 9 9 9 9 9 9 56.9 2 5.7 2

16 2 124.6 36.876 36.880 2 23.604 23.578 25.197 165.0 2 168.8 2 40.0 0.02 2 3.02 2 0.16 2 1.60 2 9 9 9 9 9 9 9 9 9 9

15 3 150.9 36.931 36.932 2 21.970 21.940 25.713 158.4 2 164.4 2 50.3 0.02 2 4.19 2 0.21 2 1.80 2 9 9 9 9 9 9 9 9 54.3 2 6.8 2

14 2 175.3 36.834 36.836 2 20.566 20.533 26.029 155.9 2 161.1 2 59.2 0.01 2 5.36 2 0.27 2 2.00 2 9 9 9 9 9 9 9 9 9 9

13 2 200.2 36.681 36.677 2 19.311 19.275 26.246 154.0 2 158.6 2 67.0 0.01 2 7.02 2 0.36 2 2.40 2 9 9 9 9 9 9 9 9 50.7 2 10.7 2

12 2 225.2 36.462 36.463 2 17.859 17.820 26.448 151.4 2 162.3 4 69.8 0.01 2 8.68 2 0.46 2 3.00 2 9 9 9 9 9 9 9 9 9 9

11 2 250.8 36.333 36.333 2 17.105 17.063 26.534 150.2 2 156.9 2 78.8 0.01 2 10.34 2 0.58 2 3.70 2 9 9 9 9 9 9 9 9 48.7 2 13.9 2

10 2 273.6 36.209 36.210 2 16.414 16.369 26.604 145.1 2 149.8 2 89.3 0.01 2 12.20 2 0.70 2 4.50 2 9 9 9 9 9 9 9 9 9 9

9 2 300.1 36.085 36.083 2 15.693 15.646 26.675 141.0 2 145.3 2 97.4 0.00 2 13.86 2 0.81 2 5.30 2 9 9 9 9 9 9 9 9 9 9

8 2 325.9 35.886 35.886 2 14.541 14.492 26.778 126.9 2 133.1 2 115.5 0.01 2 17.08 2 1.02 2 7.20 2 9 9 9 9 9 9 9 9 9 9

7 2 352.6 35.704 35.704 2 13.441 13.391 26.870 123.2 2 130.0 2 124.5 0.01 2 19.13 2 1.18 2 8.50 2 9 9 9 9 9 9 9 9 45.4 2 22.7 2

6 2 400.8 35.458 35.450 2 11.893 11.840 26.986 124.1 2 124.9 2 138.4 0.00 2 22.45 2 1.41 2 10.80 2 9 9 9 9 9 9 9 9 9 9

5 2 452.1 35.241 35.239 2 10.465 10.410 27.079 122.2 2 123.2 6 148.7 0.01 2 25.29 2 1.60 2 13.30 2 9 9 9 9 9 9 9 9 9 9

4 2 502.6 35.030 35.024 2 8.634 8.580 27.217 123.0 2 122.5 2 161.0 0.01 2 28.42 2 1.85 2 17.50 2 9 9 9 9 9 9 9 9 9 9

3 2 543.8 34.961 34.962 2 7.939 7.883 27.269 126.2 2 126.4 2 161.7 0.01 2 29.20 2 1.91 2 19.00 2 9 9 9 9 9 9 9 9 42.8 2 9

2 2 599.3 34.906 34.907 2 6.412 6.357 27.440 145.9 2 148.0 2 150.5 0.01 2 4 1.92 2 22.80 2 9 9 9 9 9 9 9 9 9 9

1 2 666.0 34.901 34.899 2 6.052 5.992 27.483 153.0 2 151.6 2 149.5 0.01 6 28.42 6 1.91 6 23.80 6 9 9 9 9 9 9 9 9 41.9 2 32.4 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

195
A5R

NOAA Ship Ronald H. Brown

STATION 127 DATE 2/23/1998 LATITUDE 27.020° N

LONGITUDE 79.674° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

20 2 4.3 36.198 36.199 2 25.932 25.931 23.961 206.6 2 204.9 2 -3.4 0.00 2 0.00 2 0.00 2 1.20 2 9 9 9 9 281.4 355.7 6 2016.7 6 8.0959 2 2378 6 2370 9 9

19 2 25.6 36.213 36.214 2 25.734 25.728 24.037 205.3 2 205.5 2 -3.3 0.00 2 0.00 2 0.00 2 1.10 2 9 9 9 9 9 9 9 9 9 9

18 2 51.3 36.222 36.224 2 25.619 25.608 24.084 205.2 2 205.4 2 -2.8 0.00 2 0.00 2 0.01 2 1.10 2 9 9 9 9 9 9 9 9 9 9

17 2 75.8 36.555 36.568 2 25.227 25.210 24.459 202.8 2 180.2 3 23.3 0.11 2 1.66 2 0.08 2 1.30 2 9 9 9 9 9 9 9 9 9 9

16 2 100.3 36.800 36.800 2 24.463 24.441 24.880 168.2 2 168.2 2 37.6 0.03 2 2.54 2 0.11 2 1.30 2 9 9 9 9 9 9 9 9 9 9

15 2 100.6 36.798 36.803 2 24.456 24.434 24.881 168.2 2 168.4 2 37.4 0.03 2 2.54 2 0.12 2 1.30 2 9 9 9 9 9 9 9 9 9 9

14 2 125.3 36.525 36.256 2 21.550 21.525 25.519 200.4 2 206.3 2 10.9 0.49 2 1.27 2 0.10 2 1.30 2 9 9 9 9 9 9 9 9 9 9

13 2 150.1 36.859 36.860 2 21.105 21.076 25.898 155.8 2 159.1 2 59.0 0.01 2 5.46 2 0.26 2 2.00 2 9 9 9 9 9 9 9 9 9 9

12 2 175.6 36.686 36.687 2 19.522 19.490 26.193 151.7 2 155.6 2 69.1 0.01 2 7.32 2 0.37 2 2.40 2 9 9 9 9 9 9 9 9 9 9

11 2 198.5 36.593 36.599 2 18.767 18.732 26.318 150.8 2 154.2 2 73.8 0.01 2 8.19 2 0.42 2 2.70 2 9 9 9 9 9 9 9 9 9 9

10 2 220.2 36.507 36.520 2 18.138 18.100 26.413 152.6 2 159.1 2 71.7 0.01 2 8.49 2 0.44 2 2.80 2 9 9 9 9 9 9 9 9 9 9

9 2 250.1 36.298 36.296 2 17.065 17.023 26.517 142.2 2 148.1 2 87.8 0.01 2 11.61 2 0.64 2 4.40 2 9 9 9 9 9 9 9 9 9 9

8 2 274.5 36.061 36.062 2 15.619 15.576 26.672 131.4 2 134.1 2 108.9 0.01 2 15.22 2 0.88 2 6.20 2 9 9 9 9 9 9 9 9 9 9

7 2 301.2 35.853 35.868 2 14.346 14.301 26.792 126.8 2 130.2 2 119.4 0.01 2 17.57 2 1.05 2 7.70 2 9 9 9 9 9 9 9 9 9 9

6 2 325.4 35.744 35.732 2 13.676 13.629 26.851 127.2 2 130.5 2 122.7 0.01 2 18.94 2 1.14 2 8.50 2 9 9 9 9 9 9 9 9 9 9

5 2 352.0 35.556 35.554 2 12.498 12.450 26.943 124.6 2 127.6 2 132.2 0.00 2 21.19 2 1.30 2 10.20 2 9 9 9 9 9 9 9 9 9 9

4 2 401.1 35.298 35.286 2 10.558 10.509 27.105 123.1 2 127.3 6 143.9 0.01 2 24.90 2 1.57 2 14.50 2 9 9 9 9 9 9 9 9 9 9

3 2 452.0 35.049 35.048 2 8.520 8.472 27.248 125.6 2 127.7 2 156.4 0.01 2 28.03 2 1.81 2 18.70 2 9 9 9 9 9 9 9 9 9 9

2 2 501.3 34.901 34.899 2 6.181 6.136 27.463 149.7 2 149.0 2 151.1 0.00 2 28.81 2 1.92 2 24.30 2 9 9 9 9 9 9 9 9 9 9

1 2 530.4 34.900 34.899 2 5.979 5.932 27.489 155.3 2 152.7 2 148.8 0.01 6 28.42 6 1.92 6 24.50 2 9 9 9 9 9 9 9 9 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

196
A5R

NOAA Ship Ronald H. Brown

STATION 128 DATE 2/23/1998 LATITUDE 27.002° N

LONGITUDE 79.788° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

16 2 1.9 36.279 2 25.039 25.039 24.299 212.5 2 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9

15 2 20.5 36.277 36.279 2 25.032 25.028 24.302 209.9 2 208.5 2 -4.0 0.00 2 0.00 2 0.01 2 1.00 2 9 9 9 9 9 9 9 9 67.8 2 4.8 2

14 2 49.6 36.296 36.302 2 25.010 24.999 24.327 207.2 2 205.6 2 -1.0 0.03 2 0.20 2 0.03 2 1.00 2 9 9 9 9 9 9 9 9 65.9 2 5.7 2

13 2 76.3 36.324 36.329 2 22.271 22.256 25.157 197.8 2 202.3 2 12.0 0.32 2 1.27 2 0.08 2 1.10 2 9 9 9 9 9 9 9 9 65.8 2 6.2 2

12 2 100.6 36.142 36.145 2 20.851 20.832 25.416 208.9 2 217.0 6 3.1 0.41 2 0.29 2 0.06 2 1.00 2 9 9 9 9 9 9 9 9 9 9

11 2 124.8 36.146 36.152 2 20.068 20.045 25.631 192.5 2 195.4 2 27.8 0.09 2 3.42 2 0.20 2 1.90 2 9 9 9 9 9 9 9 9 60.4 2 8.1 2

10 2 150.1 36.404 36.418 2 19.057 19.030 26.096 152.1 2 148.7 2 78.3 0.02 2 8.98 2 0.48 2 3.30 2 9 9 9 9 9 9 9 9 9 9

9 2 174.2 36.248 36.245 2 17.265 17.236 26.424 135.3 2 135.1 2 100.0 0.02 2 12.88 2 0.73 2 5.00 2 9 9 9 9 9 9 9 9 50.6 2 13.6 2

8 2 200.2 35.983 36.000 2 15.188 15.157 26.703 131.6 2 131.8 2 113.3 0.02 2 16.01 2 0.94 2 6.60 2 9 9 9 9 9 9 9 9 9 9

7 2 224.5 35.830 35.821 2 14.266 14.233 26.787 130.2 2 130.7 2 119.3 0.02 2 18.06 2 1.09 2 8.20 2 9 9 9 9 9 9 9 9 48.2 2 20.0 2

6 2 251.2 35.497 35.493 2 11.949 11.916 26.999 126.5 2 126.7 2 136.1 0.02 2 22.16 2 1.39 2 11.70 2 9 9 9 9 9 9 9 9 9 9

5 2 273.3 35.220 35.232 2 10.078 10.046 27.122 122.3 2 123.4 2 150.7 0.01 2 25.39 2 1.63 2 14.20 2 9 9 9 9 9 9 9 9 47.1 2 27.4 2

4 2 300.8 35.138 35.136 2 9.543 9.509 27.149 119.7 2 120.9 2 156.6 0.01 2 26.76 2 1.72 2 15.20 2 9 9 9 9 9 9 9 9 9 9

3 2 324.9 35.108 35.107 2 9.196 9.160 27.183 123.2 2 124.1 2 155.6 0.01 2 26.95 2 1.75 2 16.30 2 9 9 9 9 9 9 9 9 43.5 2 9

2 2 348.7 34.948 34.946 2 7.575 7.540 27.306 129.4 2 128.9 2 161.5 0.00 2 29.11 2 1.93 2 20.10 2 9 9 9 9 9 9 9 9 9 9

1 2 374.3 34.907 34.909 2 6.686 6.651 27.399 138.4 2 138.0 2 158.5 0.01 6 29.11 6 1.94 6 22.40 6 9 9 9 9 9 9 9 9 43.2 2 20.9 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

197
A5R

NOAA Ship Ronald H. Brown

STATION 129 DATE 2/23/1998 LATITUDE 27.006° N

LONGITUDE 79.857° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

11 2 4.4 36.156 36.157 2 23.971 23.970 24.528 218.2 2 215.1 6 -6.8 0.00 2 0.10 2 0.00 2 1.00 2 1.90 2 1.12 2 0.16 2 9 291.8 342.5 2 2026.3 6 8.0840 2 2366 3 2371 9 9

10 2 26.7 36.178 36.172 2 23.873 23.867 24.576 217.1 2 214.9 2 -6.2 0.00 2 0.10 2 0.00 2 1.00 2 1.94 2 1.13 2 0.16 2 9 292.3 341.7 2 2027.4 2 8.0846 2 2382 2 2373 9 9

9 2 51.5 36.174 36.179 2 21.710 21.700 25.199 218.3 2 220.6 2 -3.9 0.02 2 0.10 2 0.02 2 1.10 2 2.07 2 1.19 2 0.17 2 9 311.0 333.5 2 2046.4 2 8.0641 2 2376 3 2380 9 9

8 2 75.4 36.189 36.193 2 21.280 21.265 25.332 216.5 2 217.9 2 0.4 0.14 2 0.29 2 0.04 2 1.20 2 2.11 2 1.21 2 0.17 2 9 318.1 335.2 2 2057.0 2 8.0550 2 2375 3 2385 9 9

7 2 98.8 36.160 36.158 2 20.329 20.310 25.570 194.4 2 196.1 2 26.0 0.12 2 3.22 2 0.18 2 2.00 2 2.07 6 1.18 6 0.14 6 9 364.5 369.4 2 2084.9 2 8.0123 2 2384 2 2387 9 9

6 2 123.9 36.352 36.340 2 19.141 19.119 26.032 152.9 2 151.6 2 75.2 0.03 2 8.88 2 0.48 2 3.70 2 1.89 2 1.05 2 0.06 2 9 455.1 441.1 2 2133.3 3 7.9212 2 2383 2 2384 9 9

5 2 150.1 35.884 35.880 2 15.556 15.533 26.540 143.9 2 145.1 2 98.4 0.06 2 14.84 2 0.89 2 7.50 2 1.41 2 0.78 2 0.05 2 9 561.4 468.6 2 2153.1 2 7.8398 2 2357 2 2358 9 9

4 2 173.9 35.575 35.547 2 12.692 12.668 26.910 130.0 2 129.3 2 129.3 0.03 2 21.19 2 1.31 2 11.10 2 0.97 2 0.52 2 0.02 2 9 730.9 540.4 2 2180.8 2 7.7383 2 2338 2 2337 9 9

3 2 195.6 35.356 35.349 2 11.019 10.995 27.059 127.0 2 125.1 2 143.2 0.01 2 24.12 2 1.52 2 13.20 2 0.73 2 0.38 2 0.01 2 9 819.6 564.6 2 2191.1 2 7.6918 2 2328 2 2326 9 9

2 2 220.9 35.191 35.189 2 9.890 9.864 27.129 125.9 2 122.1 2 153.1 0.01 2 26.07 2 1.67 2 14.60 2 0.53 2 0.28 2 0.01 2 9 896.1 589.1 2 2198.1 2 7.6572 2 2317 2 2319 9 9

1 2 267.5 35.114 35.115 2 9.084 9.055 27.203 131.3 2 125.1 2 155.2 0.01 6 26.95 6 1.75 6 16.60 6 0.42 2 0.23 2 0.01 2 9 935.3 594.0 2 2204.2 2 7.6443 2 2320 2 2320 9 9

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

  ITS0 scale

198
A5R

NOAA Ship Ronald H. Brown

STATION 130 DATE 2/23/1998 LATITUDE 26.999° N

LONGITUDE 79.937° W

CTD Bottle CTD Bottle fCO2 fCO2 Measured Calculated

Bottle F**  Pressure Salinity*** Salinity*** F* Temp**** Theta Sigma O2 F* O2 F* AOU NO2 F* NO3 F* PO4 F* Si(OH)4 F* CFC-11 F* CFC-12 F* CFC-113 F* CCl4 F* at 20 oC INSITU F* DIC F* pH F* TA F* TA TOC F* TON F*

Number db oC

oC Theta μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg pmol/kg pmol/kg pmol/kg pmol/kg μatm μatm μmol/kg μmol/kg μmol/kg μmol/kg μmol/kg

6 2 3.0 36.024 2 23.327 23.326 24.617 225.1 2 219.9 2 0.1 9 9 9 9 9 9 9 2.11 6 304.9 349.0 6 2040.7 3 8.0762 2 2385 2 66.3 2 10.3 2

5 2 24.9 36.147 36.149 2 22.386 22.381 24.985 222.2 2 221.6 2 -7.5 0.00 2 0.00 2 0.01 2 0.90 2 9 9 9 9 9 9 9 9 62.8 2 5.4 2

4 2 49.6 36.148 36.135 2 20.864 20.855 25.412 207.7 2 210.0 6 10.0 0.26 2 1.66 2 0.12 2 1.70 2 9 9 9 9 9 9 9 9 59.2 2 6.5 2

3 2 75.8 35.992 35.988 2 17.933 17.920 26.056 172.5 2 176.2 2 56.2 0.19 2 8.69 2 0.53 2 4.80 2 9 9 9 9 9 9 9 9 53.1 2 12.7 2

2 2 96.4 35.832 35.817 2 14.915 14.900 26.640 140.6 2 139.3 2 107.4 0.06 2 16.50 2 1.00 2 8.00 2 9 9 9 9 9 9 9 9 43.9 2 19.5 2

1 2 129.5 35.483 35.502 2 11.797 11.780 27.010 121.9 2 126.4 2 137.2 0.03 6 22.07 6 1.39 6 12.10 6 9 9 9 9 9 9 9 9 41.4 2 24.7 2

* WOCE water sample quality flag (F) for parameter for the previous column

** WOCE quality flag (F) for "Niskin" sample bottle

*** PSS-78 scale

**** ITS0 scale

199