November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 103

9 Peach Tree Hill Road

Formosa Plastics Corporation USA

302.836.2256

kbennett@fdde.fpcusa.com

Formosa Plastics Corporation DE

780 Schoolhouse Road

Delaware City

Kim Bennett

Livingston 
ers (PVC) Production Process Wastewater

State: NJ Zip Code: 7039

hes, and related establishments owned):

State: DE Zip Code: 19706
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: P1 E2 Plant

Process Equipment ID: U27

Wastewater Feed Rate (lb/hr):

Feed Temperature (°F):

Feed Inlet Pressure (psia):

Liquid Loading Rate (liters/m2):

Steam Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater):

Operating Temperature (°F): 160

Operating Pressure (psig): 15

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent):

Number of Actual Trays:

Column Height (meters):

Year Equipment Installed:

Equipment Currently Regulated Under (cite regulations):

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: liters/hour

26,495 liters

m design rate or capacity, please provide those values:

 liters/hour (max design)

44,285 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: S2 Plant 

Process Equipment ID: U63

Wastewater Feed Rate (lb/hr):

Feed Temperature (°F):

Feed Inlet Pressure (psia):

Liquid Loading Rate (liters/m2):

Steam Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater):

Operating Temperature (°F): 170

Operating Pressure (psig): 15

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent):

Number of Actual Trays:

Column Height (meters):

Year Equipment Installed:

Equipment Currently Regulated Under (cite regulations):

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: liters/hour

18,925 liters

m design rate or capacity, please provide those values:

 liters/hour (max design)

31,542 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production fa

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wa

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for e

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3

P1 E2 Plant

S2 Plant

2

Pump seal water (non VCM contact)

Pump seal water (non VCM contact)

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

PVC Process 

Wastewater 

Stream ID
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6

Min

P1 E2 Plant E2 Production Unit Steam Stripping Batch E2WW-1 0

S2 Plant S2 Production Steam Stripping Batch S2WW-1 0

Table 3. PVC Process Wastewater Destination Codes Table

Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment S

2 3

Min Max

PVC Process Wastewate

Process Wastewater Stream Flow Rate 

(gallons per day)

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Type of Process 

Wastewater 

Treatment System

Source of Process Wastewater Stream

1

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

VC) Production Process Wastewater

hin the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process waste

VC production process wastewater treatment system.

ter treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC prod

tment System

4 5 6 7 8

Min Max Average

0 10080 8880 Estimated 360

0 17280 17280 Estimated 360

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days Per 

Year
7 8 9 10 11

Max Average

7000 7000 Estimated 60 WWT

5000 5000 Estimated 96 WWT

Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

Wastewater Treatment System

4 5 6 7

Average

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

VC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

water Stream Flow Rate 

ons per day)

Process Wastewater Destination D

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Operating Days 

Per Year

eated by a PVC production process wastewater treatment system.

hat does not originate from the PVC production facility.

9 10

DP501A&B Various process pumps

SC302A&B, SC304A&B, SP303A&B, SP503A&B Various process pumps

Originating PVC Process 

Equipment ID

Originating PVC Process 

Equipment Description
12 13

Site WWT Yes

Site WWT Yes

e of the wastewater treatment system

ere in the process the stream is recycled

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Associated Destination 

Information

(Refer to Table 3 below)

11 12

WWT Site WWT

WWT Site WWT

Associated Destination Information

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)
able 1 and Column 11 of Table 2

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

14

13

Yes

Yes

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?
de a description of the process wastewaetr 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID m

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determina

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in th

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

Resin Type (suspension, dispersion, bulk, etc.) -->
74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
yl Chloride and Copolymers (PVC) Production Process Wastewater

ng and Analysis Data

astewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single s

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

 date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab s

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

 such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

o the sampling or analysis.

Formosa Plastics Corporation USA

Formosa Plastics Corporation DE

P1 E2 Plant

1/11/2013 - 1/14/2013

01-E2-A-01-07-2013

JB25020-1

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 10 Non-detect

SW-846-8015C 13.2

SW-846-8315A 2.38

SW-846-8315A 4.11

SW-846-8270D 0.017 Non-detect

SW-846-8270D 0.00029 Non-detect

SW-846-8270D 0.0006 Non-detect

SW-846-8270D R

SW-846-8270D 0.0013 Non-detect

SW-846-8260B 0.0021 Non-detect

SW-846-8260B 0.019 Non-detect

SW-846-8260B 0.0023 Non-detect

SW-846-8260B 0.0024 Non-detect

SW-846-8260B 0.0023 Non-detect

SW-846-8260B 0.002 Non-detect

SW-846-8260B 0.0021 Non-detect

SW-846-8260B 0.0045 Non-detect

SW-846-8260B 0.0147

SW-846-8260B 0.0023 Non-detect

SW-846-8260B 0.0026 Non-detect

SW-846-8260B 0.0011 Non-detect

Analysis Date -->

Lab Sample ID -->

Lab Report ID -->

Stream Temperature (degrees F) --> 179.3

Flow Rate Determination Method --> Estimated

Stream Flow Rate (gallons per minute) --> 140.1

Sample Date --> 01/07/13

Resin Type (suspension, dispersion, bulk, etc.) --> emulsion
SW-846-8260B 0.0147

SW-846-8260B 0.007 Non-detect

SW-846-8260B 0.0046 Non-detect

SW-846-8260B 0.0023 Non-detect

SW-846-8260B 0.0024 Non-detect

SW-846-8260B 0.0029 Non-detect

SW-846-8260B 0.011 Non-detect

SW-846-8260B 0.0027 Non-detect

EPA Method 107 0.4639

SW-846-8260B 0.0019 Non-detect

SW-846-8260B 0.0024 Non-detect
 and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

rature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

w, in the "Concentration (ppmw)" column.

1/11/2013 - 1/14/2013

01-E2-B-01-07-2013

JB25020-2

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

21.5

4.02

2.94

0.017 Non-detect

0.00029 Non-detect

0.0015

Rejected R Rejected

0.0013 Non-detect

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0265

0.0023 Non-detect

0.0026 Non-detect

0.0011 Non-detect

179.3

Estimated Estimated

140.1

01/07/13

emulsion

1 2
0.008

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

3.99

0.0027 Non-detect

1.276

0.0019 Non-detect

0.0024 Non-detect
1/14/2013 - 1/22/2013 1/14/2013 - 1/17/2013

02-E2-A-01-10-2013 02-E2-B-01-10-2013

JB25021-1 JB25021-2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

66 J-Estimated Value 65.2

7.04 7.74

0.19 J-Estimated Value 0.272

0.66 Non-detect R

0.011 Non-detect 0.0014 Non-detect

0.023 Non-detect 0.0029 Non-detect

R Rejected R

0.051 Non-detect 0.0064 Non-detect

0.0021 Non-detect 0.0054 Non-detect

0.019 Non-detect 0.048 Non-detect

0.0023 Non-detect 0.0056 Non-detect

0.0024 Non-detect 0.0059 Non-detect

0.0023 Non-detect 0.0057 Non-detect

0.002 Non-detect 0.0051 Non-detect

0.0021 Non-detect 0.0052 Non-detect

0.0045 Non-detect 0.011 Non-detect

0.0227 0.018

0.0023 Non-detect 0.0057 Non-detect

0.0026 Non-detect 0.0065 Non-detect

0.0011 Non-detect 0.0027 Non-detect

159.2 159.2

Estimated Estimated

103 103

01/10/13

emulsion emulsion

01/10/13

3
0.015 0.0132

0.007 Non-detect 0.018 Non-detect

0.0046 Non-detect 0.012 Non-detect

0.0023 Non-detect 0.0057 Non-detect

0.0024 Non-detect 0.0059 Non-detect

0.0029 Non-detect 0.0072 Non-detect

4.2 6.28

0.0027 Non-detect 0.0067 Non-detect

1.5788 1.2314

0.0019 Non-detect 0.0048 Non-detect

0.0024 Non-detect 0.006 Non-detect
1/16/2013 - 1/21/2013

03-E2-A-01-14-2013

JB25022-1

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

0.045 Non-detect

9.14

J-Estimated Value 0.013 J-Estimated Value

0.017 Non-detect

0.00029 Non-detect

0.00059 Non-detect

Rejected R Rejected

0.0013 Non-detect

0.0054 Non-detect

0.048 Non-detect

0.0056 Non-detect

0.0059 Non-detect

0.0057 Non-detect

0.0051 Non-detect

0.0052 Non-detect

0.011 Non-detect

0.0066 Non-detect

0.0057 Non-detect

0.0065 Non-detect

0.0027 Non-detect

156.8

Estimated Estimated

92.3

emulsion

01/14/13

4 5
0.0285

0.018 Non-detect

0.012 Non-detect

0.0057 Non-detect

0.0059 Non-detect

0.0072 Non-detect

0.0408

0.0067 Non-detect

Non-detect

0.0048 Non-detect

0.006 Non-detect
1/16/2013 - 1/21/2013 1/29/2013 - 2/5/2013

03-E2-B-01-14-2013 04-E2-A-01-23-2013

JB25022-2 JB25023-4

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

0.045 Non-detect 93

9.08 7.04

0.0246 J-Estimated Value 0.228

0.017 Non-detect 0.17 Non-detect

0.00029 Non-detect 0.0029 Non-detect

0.00059 Non-detect 0.0059 Non-detect

R Rejected R

0.0013 Non-detect 0.013 Non-detect

0.0054 Non-detect 0.0021 Non-detect

0.048 Non-detect 0.019 Non-detect

0.0056 Non-detect 0.0023 Non-detect

0.0059 Non-detect 0.0024 Non-detect

0.0057 Non-detect 0.0023 Non-detect

0.0051 Non-detect 0.002 Non-detect

0.0052 Non-detect 0.0021 Non-detect

0.011 Non-detect 0.0045 Non-detect

0.0066 Non-detect 0.0026 Non-detect

0.0057 Non-detect 0.0023 Non-detect

0.0065 Non-detect 0.0026 Non-detect

0.0027 Non-detect 0.0011 Non-detect

156.8 159.1

Estimated Estimated

92.3 113.4

emulsion emulsion

01/14/13 01/23/13

6
0.0099 0.0118

0.018 Non-detect 0.007 Non-detect

0.012 Non-detect 0.0046 Non-detect

0.0057 Non-detect 0.0023 Non-detect

0.0059 Non-detect 0.0024 Non-detect

0.0072 Non-detect 0.0029 Non-detect

0.86 0.011 Non-detect

0.0067 Non-detect 0.0027 Non-detect

Non-detect 0.1344

0.0048 Non-detect 0.0019 Non-detect

0.006 Non-detect 0.0024 Non-detect
1/29/2013 - 2/5/2013

04-E2-B-01-23-2013

JB25023-5

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

96.9

J-Estimated Value 7.87 J-Estimated Value

0.241

0.17 Non-detect

0.0029 Non-detect

0.0059 Non-detect

Rejected R Rejected

0.013 Non-detect

0.0021 Non-detect

R Rejected

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0119

0.0023 Non-detect

0.0026 Non-detect

0.0011 Non-detect

159.1

Estimated Estimated

113.4

emulsion

01/23/13

7 8
0.0021 Non-detect

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

0.011 Non-detect

0.0027 Non-detect

0.4777

0.0019 Non-detect

0.0024 Non-detect
2/4/2013 - 2/7/2013 2/4/2013 - 2/7/2013

05-E2-A-01-31-2013 05-E2-B-01-31-2013

JB25024-4 JB25024-5

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 0.01 Non-detect

47.9 56

3.82 J-Estimated Value 3.42

0.219 J-Estimated Value 0.268

0.017 Non-detect 0.017 Non-detect

0.00029 Non-detect 0.00029 Non-detect

0.00059 Non-detect 0.00059 Non-detect

R Rejected R

0.0013 Non-detect 0.0013 Non-detect

0.0021 Non-detect 0.0021 Non-detect

0.019 Non-detect 0.019 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.002 Non-detect 0.002 Non-detect

0.0021 Non-detect 0.0021 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0026 Non-detect 0.0097

0.0023 Non-detect 0.0023 Non-detect

0.0026 Non-detect 0.0026 Non-detect

0.0011 Non-detect 0.0011 Non-detect

157.1 157.1

Estimated Estimated

178.8 178.8

emulsion emulsion

01/31/13 01/31/13

9
0.0021 Non-detect 0.0021 Non-detect

0.007 Non-detect 0.007 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0029 Non-detect 0.0029 Non-detect

0.011 Non-detect 0.011 Non-detect

0.0027 Non-detect 0.0027 Non-detect

1.6468 0.4591

0.0019 Non-detect 0.0019 Non-detect

0.0024 Non-detect 0.0024 Non-detect
2/11/2013 - 2/23/2013

06-E2-A-02-07-2013

JB25025-1

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

0.045 Non-detect

J-Estimated Value 8.47 J-Estimated Value

J-Estimated Value 0.0756 J-Estimated Value

0.017 Non-detect

0.00029 Non-detect

0.0052

Rejected R Rejected

0.0013 Non-detect

0.00021 Non-detect

0.0019 Non-detect

0.00023 Non-detect

0.00024 Non-detect

0.00023 Non-detect

0.0002 Non-detect

0.00021 Non-detect

0.00045 Non-detect

0.00026 Non-detect

0.00023 Non-detect

0.00026 Non-detect

0.00011 Non-detect

158.6

Estimated Estimated

171.3

emulsion

02/07/13

10 11
0.0094

0.0007 Non-detect

0.00046 Non-detect

0.00023 Non-detect

0.00024 Non-detect

0.00029 Non-detect

0.251

0.00027 Non-detect

0.3055

0.00019 Non-detect

0.00024 Non-detect
2/11/2013 - 2/23/2013 2/14/2013 - 2/23/2013

06-E2-B-02-07-2013 07-E2-A-02-12-2013

JB25025-2 JB25026-6

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

0.045 Non-detect 0.045 Non-detect

9.69 J-Estimated Value 6.46

0.0881 J-Estimated Value 0.0209

0.017 Non-detect 0.017 Non-detect

0.00029 Non-detect 0.00029 Non-detect

0.00059 Non-detect 0.00059 Non-detect

R Rejected R

0.0013 Non-detect 0.0013 Non-detect

0.00021 Non-detect 0.011 Non-detect

0.0019 Non-detect 0.095 Non-detect

0.00023 Non-detect 0.011 Non-detect

0.00024 Non-detect 0.012 Non-detect

0.00023 Non-detect 0.011 Non-detect

0.0002 Non-detect 0.01 Non-detect

0.00021 Non-detect 0.01 Non-detect

0.00045 Non-detect 0.022 Non-detect

0.0297 0.0637

0.00023 Non-detect 0.011 Non-detect

0.0041 0.013 Non-detect

0.00011 Non-detect 0.0053 Non-detect

158.6 158.8

Estimated Estimated

171.3 183.9

emulsion emulsion

02/07/13 02/12/13

12
0.0154 0.0491

0.0007 Non-detect 0.035 Non-detect

0.00046 Non-detect 0.023 Non-detect

0.00023 Non-detect 0.011 Non-detect

0.00024 Non-detect 0.012 Non-detect

0.00029 Non-detect 0.014 Non-detect

3.76 39.9

0.00027 Non-detect 0.013 Non-detect

1.0615 2.1305

0.00019 Non-detect 0.0096 Non-detect

0.00024 Non-detect 0.012 Non-detect
2/14/2013 - 2/24/2013

07-E2-B-02-12-2013

JB25026-7

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

0.045 Non-detect

J-Estimated Value 6.11 J-Estimated Value

0.0175

0.017 Non-detect

0.00029 Non-detect

0.00059 Non-detect

Rejected R Rejected

0.0013 Non-detect

0.011 Non-detect

0.095 Non-detect

0.011 Non-detect

0.012 Non-detect

0.011 Non-detect

0.01 Non-detect

0.01 Non-detect

0.022 Non-detect

0.0487

0.011 Non-detect

0.013 Non-detect

0.0053 Non-detect

158.8

Estimated Estimated

183.9

emulsion

02/12/13

13 14
0.0484

0.035 Non-detect

0.023 Non-detect

0.011 Non-detect

0.012 Non-detect

0.014 Non-detect

38.5

0.013 Non-detect

1.9344

0.0096 Non-detect

0.012 Non-detect
2/18/2013 - 2/27/2013 2/18/2013 - 2/28/2013

08-E2-A-02-14-2013 08-E2-B-02-14-2013

JB25027-4 JB25027-5

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

0.045 Non-detect 0.045 Non-detect

58.4 60.3

0.6 J-Estimated Value 0.61

R 0.17 Non-detect

3.08 2.56

0.0059 Non-detect 0.0059 Non-detect

R Rejected R

0.013 Non-detect 0.013 Non-detect

2.1 Non-detect 2.1 Non-detect

19 Non-detect 19 Non-detect

2.3 Non-detect 2.3 Non-detect

2.4 Non-detect 2.4 Non-detect

2.3 Non-detect 2.3 Non-detect

2 Non-detect 2 Non-detect

2.1 Non-detect 2.1 Non-detect

4.5 Non-detect 4.5 Non-detect

2.6 Non-detect 2.6 Non-detect

2.3 Non-detect 2.3 Non-detect

2.6 Non-detect 2.6 Non-detect

1.1 Non-detect 1.1 Non-detect

160.5 160.5

Estimated Estimated

113.6 113.6

02/14/13

emulsion emulsion

02/14/13

15
2.1 Non-detect 2.1 Non-detect 7 Non-detect 7 Non-detect

4.6 Non-detect 4.6 Non-detect

2.3 Non-detect 2.3 Non-detect

2.4 Non-detect 2.4 Non-detect

2.9 Non-detect 2.9 Non-detect

10700 10900

2.7 Non-detect 2.7 Non-detect

Non-detect Non-detect

1.9 Non-detect 1.9 Non-detect

2.4 Non-detect 2.4 Non-detect
2/27/2013 - 3/25/2013

09-E2-A-02-25-2013

JB25028-4

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

3050

6.7 J-Estimated Value

J-Estimated Value R Rejected

0.083 Non-detect

0.0014 Non-detect

0.0029 Non-detect

Rejected 0.025 Non-detect

0.0064 Non-detect

0.21 Non-detect

1.9 Non-detect

0.23 Non-detect

0.24 Non-detect

0.23 Non-detect

0.2 Non-detect

0.21 Non-detect

0.45 Non-detect

1.28

0.23 Non-detect

0.26 Non-detect

0.11 Non-detect

160.6

Estimated

159.1

Estimated

02/25/13

emulsion

16 17
0.798

0.7 Non-detect

0.46 Non-detect

0.23 Non-detect

0.24 Non-detect

0.29 Non-detect

176

0.27 Non-detect

18.1496

0.19 Non-detect

0.24 Non-detect
2/27/2013 - 3/8/2013 3/11/2013 - 3/16/2013

09-E2-B-02-25-2013 10-E2-A-03-07-2013

JB25028-5 JB25029-4

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

2700 82.8

7.19 J-Estimated Value 6.19

0.0074 J-Estimated Value 0.14

0.017 Non-detect 0.017 Non-detect

0.00029 Non-detect 0.00029 Non-detect

0.00059 Non-detect 0.0013

0.005 Non-detect R

0.0013 Non-detect 0.0013 Non-detect

0.21 Non-detect 0.0021 Non-detect

1.9 Non-detect 0.019 Non-detect

0.23 Non-detect 0.0023 Non-detect

0.24 Non-detect 0.0024 Non-detect

0.23 Non-detect 0.0023 Non-detect

0.2 Non-detect 0.002 Non-detect

0.21 Non-detect 0.0021 Non-detect

0.45 Non-detect 0.0045 Non-detect

1.37 0.0026 Non-detect

0.23 Non-detect 0.0023 Non-detect

0.26 Non-detect 0.006

0.11 Non-detect 0.0011 Non-detect

160.6 159.2

159.1 181

Estimated Estimated

emulsion

02/25/13 03/07/13

emulsion

18
0.765 0.0101

0.7 Non-detect 0.007 Non-detect

0.46 Non-detect 0.0046 Non-detect

0.23 Non-detect 0.0023 Non-detect

0.24 Non-detect 0.0024 Non-detect

0.29 Non-detect 0.0029 Non-detect

197 2.28

0.27 Non-detect 0.0027 Non-detect

15.4083 Non-detect

0.19 Non-detect 0.0019 Non-detect

0.24 Non-detect 0.0024 Non-detect
3/11/2013 - 3/16/2013

10-E2-B-03-07-2013

JB25029-5

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

76.3 J-Estimated Value

6.95

J-Estimated Value 0.126 J-Estimated Value

0.017 Non-detect

0.00029 Non-detect

0.0093

Rejected R Rejected

0.0013 Non-detect

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0101

0.0023 Non-detect

0.0089

0.0011 Non-detect

159.2

Estimated Estimated

emulsion

181

03/07/13

19 20
0.0231

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

6.38

0.0027 Non-detect

0.5051

0.0019 Non-detect

0.0024 Non-detect
3/15/2013 - 3/18/2013 3/15/2013 - 3/18/2013

11-E2-A-03-12-2013 11-E2-B-03-12-2013

JB25030-4 JB25030-5

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

102 76.9

7.35 6.26

0.295 0.259

0.17 Non-detect 0.17 Non-detect

0.0029 Non-detect 0.0029 Non-detect

0.0059 Non-detect 0.0059 Non-detect

R Rejected R

0.013 Non-detect 0.013 Non-detect

0.0021 Non-detect 0.0021 Non-detect

0.019 Non-detect 0.019 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.002 Non-detect 0.002 Non-detect

R Rejected R

0.0045 Non-detect 0.0045 Non-detect

0.0252 0.0266

0.0023 Non-detect 0.0023 Non-detect

0.0078 0.0085

0.0011 Non-detect 0.0011 Non-detect

165.1 165.1

Estimated Estimated

emulsion emulsion

174.6 174.6

03/12/13 03/12/13

21
0.0171 0.0181

0.007 Non-detect 0.007 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0029 Non-detect 0.0029 Non-detect

2.2 2.79

0.0027 Non-detect 0.0027 Non-detect

Non-detect 0.304

0.0019 Non-detect 0.0019 Non-detect

0.0024 Non-detect 0.0024 Non-detect
3/21/2013 - 4/4/2013

12-E2-A-03-18-2013

JB25031-4

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

J-Estimated Value 0.045 Non-detect

7.14 J-Estimated Value

0.0406 J-Estimated Value

0.033 Non-detect

1.47

0.0012 Non-detect

Rejected R Rejected

0.0026 Non-detect

0.0043 Non-detect

0.038 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0046 Non-detect

0.0041 Non-detect

Rejected 0.0042 Non-detect

0.0089 Non-detect

0.0475

0.0046 Non-detect

0.0102

0.0021 Non-detect

158.9

Estimated Estimated

emulsion

58.4

03/18/13

22 23
0.0274

0.014 Non-detect

0.0093 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0057 Non-detect

112

0.0054 Non-detect

0.8333

0.0038 Non-detect

0.0048 Non-detect
3/21/2013 - 4/4/2013 4/1/2013 - 4/8/2013

12-E2-B-03-18-2013 13-E2-A-03-27-2013

JB25031-5 JB25032-4

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

0.045 Non-detect 22.4

6.41 J-Estimated Value 3.1

0.0434 J-Estimated Value 0.161

0.033 Non-detect 0.017 Non-detect

1.29 0.00029 Non-detect

0.0012 Non-detect 0.00059 Non-detect

R Rejected R

0.0026 Non-detect 0.0013 Non-detect

0.0043 Non-detect 0.0043 Non-detect

0.038 Non-detect 0.038 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0047 Non-detect 0.0047 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0041 Non-detect 0.0041 Non-detect

0.0042 Non-detect 0.0042 Non-detect

0.0089 Non-detect 0.0089 Non-detect

0.0476 0.0479

0.0046 Non-detect 0.0046 Non-detect

0.009 0.0109

0.0021 Non-detect 0.0021 Non-detect

158.9 154.7

196.2

Estimated Estimated

emulsion emulsion

58.4

03/27/13

24

03/18/13
0.0281 0.0329

0.014 Non-detect 0.014 Non-detect

0.0093 Non-detect 0.0093 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0047 Non-detect 0.0047 Non-detect

0.0057 Non-detect 0.0057 Non-detect

114 0.022 Non-detect

0.0054 Non-detect 0.0054 Non-detect

0.6553 0.5743

0.0038 Non-detect 0.0038 Non-detect

0.0048 Non-detect 0.0048 Non-detect
4/1/2013 - 4/8/2013

13-E2-B-03-27-2013

JB25032-5

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

47

4.19

J-Estimated Value 0.252

0.017 Non-detect

0.00029 Non-detect

0.00059 Non-detect

Rejected R Rejected

0.0013 Non-detect

0.0043 Non-detect

0.038 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0046 Non-detect

0.0041 Non-detect

0.0042 Non-detect

0.0089 Non-detect

0.0467

0.0046 Non-detect

0.0105

0.0021 Non-detect

154.7

Estimated Estimated

emulsion

196.2

25

03/27/13

26
0.0295

0.014 Non-detect

0.0093 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0057 Non-detect

0.022 Non-detect

0.0054 Non-detect

0.5793

0.0038 Non-detect

0.0048 Non-detect
4/4/2013 - 4/8/2013 4/4/2013 - 4/8/2013

14-E2-A-04-01-2013 14-E2-B-04-01-2013

JB25033-4 JB25033-5

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

36.5 37.2

4.01 4.88

0.342 0.444

0.017 Non-detect 0.017 Non-detect

0.00029 Non-detect 0.00029 Non-detect

0.00059 Non-detect 0.00059 Non-detect

0.005 Non-detect 0.005 Non-detect

0.0013 Non-detect 0.0013 Non-detect

0.0011 Non-detect 0.0011 Non-detect

0.0095 Non-detect 0.0095 Non-detect

0.0011 Non-detect 0.0011 Non-detect

0.0012 Non-detect 0.0012 Non-detect

0.0011 Non-detect 0.0011 Non-detect

0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect

0.0022 Non-detect 0.0022 Non-detect

0.0013 Non-detect 0.0108

0.0011 Non-detect 0.0011 Non-detect

0.0013 Non-detect 0.0013 Non-detect

0.00053 Non-detect 0.00053 Non-detect

159.8 159.8

133.7

Estimated Estimated

emulsion emulsion

133.7

04/01/13 04/01/13

27
0.001 Non-detect 0.0031

0.0035 Non-detect 0.0035 Non-detect

0.0023 Non-detect 0.0023 Non-detect

0.0011 Non-detect 0.0011 Non-detect

0.0012 Non-detect 0.0012 Non-detect

0.0014 Non-detect 0.0014 Non-detect

0.0056 Non-detect 0.0056 Non-detect

0.0013 Non-detect 0.0013 Non-detect

0.4078 0.5673

0.00096 Non-detect 0.00096 Non-detect

0.0012 Non-detect 0.0012 Non-detect
4/12/13-4/24/13

15-E2-A-04-08-2013

JB25034-4

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

53.1

2.67

0.137

0.017 Non-detect

0.00029 Non-detect

0.0018J

0.005 Non-detect

0.0098

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0026 Non-detect

0.0023 Non-detect

4.6J

0.0011 Non-detect

159.6

128.1

Estimated Estimated

emulsion

04/08/13

28 29
0.0021 Non-detect

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

0.011 Non-detect

0.0027 Non-detect

0.1639

0.0019 Non-detect

0.0024 Non-detect
4/12/13-4/24/13

15-E2-B-04-08-2013

JB25034-5

Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

30.7

2.63

0.156

0.017 Non-detect

0.00029 Non-detect

0.00059 Non-detect

0.005 Non-detect

0.0013 Non-detect

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0026 Non-detect

0.0023 Non-detect

4.5J

0.0011 Non-detect

159.6

128.1

Estimated

emulsion

04/08/13

30
0.0021 Non-detect

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

0.011 Non-detect

0.0027 Non-detect

0.1591

0.0019 Non-detect

0.0024 Non-detect
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID m

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determina

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in th

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

Resin Type (suspension, dispersion, bulk, etc.) -->
74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
yl Chloride and Copolymers (PVC) Production Process Wastewater

ng and Analysis Data

astewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single s

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

 date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab s

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

 such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

o the sampling or analysis.

Formosa Plastics Corporation USA

Formosa Plastics Corporation DE

S2 Plant

1/21/2013 - 1/30/2013

01-S2-A-01-17-2013

JB26756-1

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 10 Non-detect

SW-846-8015C 2.61

SW-846-8315A 0.0985

SW-846-8315A 0.0661

SW-846-8270D 0.17 Non-detect

SW-846-8270D 0.0029 Non-detect

SW-846-8270D 0.0059 Non-detect

SW-846-8270D R

SW-846-8270D 0.013 Non-detect

SW-846-8260B 0.0054 Non-detect

SW-846-8260B 0.048 Non-detect

SW-846-8260B 0.0056 Non-detect

SW-846-8260B 0.0059 Non-detect

SW-846-8260B 0.0057 Non-detect

SW-846-8260B 0.0051 Non-detect

SW-846-8260B 0.0052 Non-detect

SW-846-8260B 0.011 Non-detect

SW-846-8260B 0.0066 Non-detect

SW-846-8260B 0.0057 Non-detect

SW-846-8260B 0.0065 Non-detect

SW-846-8260B 0.0027 Non-detect

Sample Date --> 01/17/13

Resin Type (suspension, dispersion, bulk, etc.) --> emulsion

Stream Flow Rate (gallons per minute) --> 104.5

Flow Rate Determination Method --> Estimated

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) --> 184.2
SW-846-8260B 0.0052 Non-detect

SW-846-8260B 0.018 Non-detect

SW-846-8260B 0.012 Non-detect

SW-846-8260B 0.0057 Non-detect

SW-846-8260B 0.0059 Non-detect

SW-846-8260B 0.0072 Non-detect

SW-846-8260B 0.028 Non-detect

SW-846-8260B 0.0067 Non-detect

EPA Method 107 Non-detect

SW-846-8260B 0.0048 Non-detect

SW-846-8260B 0.006 Non-detect
 and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

rature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

w, in the "Concentration (ppmw)" column.

1/21/2013 - 1/30/2013

01-S2-B-01-17-2013

JB26756-2

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

2.82

0.161

0.0971

0.17 Non-detect

0.0029 Non-detect

0.0059 Non-detect

Rejected R Rejected

0.013 Non-detect

0.0011 Non-detect

0.0095 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0011 Non-detect

0.001 Non-detect

0.001 Non-detect

0.0022 Non-detect

0.0013 Non-detect

0.0011 Non-detect

0.0013 Non-detect

0.00053 Non-detect

1 2

01/17/13

emulsion

104.5

Estimated Estimated

184.2
0.001 Non-detect

0.0035 Non-detect

0.0023 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0014 Non-detect

0.0056 Non-detect

0.0013 Non-detect

Non-detect

0.00096 Non-detect

0.0012 Non-detect
1/21/2013 - 1/30/2013 1/21/2013 - 1/30/2013

02-S2-A-01-17-2013 02-S2-B-01-17-2013

JB25021-5 JB25021-6

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

5.85 6.96

0.983 1.06

0.361 0.366

0.017 Non-detect 0.017 Non-detect

0.00029 Non-detect 0.00029 Non-detect

0.00059 Non-detect 0.00059 Non-detect

R Rejected R

0.0013 Non-detect 0.0013 Non-detect

0.00021 Non-detect 0.00021 Non-detect

0.0019 Non-detect 0.0019 Non-detect

0.00023 Non-detect 0.00023 Non-detect

0.00026 0.00029

0.00023 Non-detect 0.00023 Non-detect

0.0002 Non-detect 0.0002 Non-detect

0.00021 Non-detect 0.00021 Non-detect

0.00045 Non-detect 0.00045 Non-detect

0.002 0.0022

0.00023 Non-detect 0.00023 Non-detect

0.00026 Non-detect 0.00026 Non-detect

0.00011 Non-detect 0.00011 Non-detect

3

01/17/13 01/17/13

emulsion emulsion

124.7 124.7

Estimated Estimated

182.4 182.4
0.00046 0.00021 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00023 Non-detect 0.00023 Non-detect

0.00024 Non-detect 0.00024 Non-detect

0.00029 Non-detect 0.00029 Non-detect

0.0011 Non-detect 0.0011 Non-detect

0.00027 Non-detect 0.00027 Non-detect

0.1313 0.1124

0.00019 Non-detect 0.00019 Non-detect

0.00024 Non-detect 0.00024 Non-detect
1/24/2013 - 1/30/2013

03-S2-A-01-21-2013

JB25022-3

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

3.19

1.1 Non-detect

J-Estimated Value 2 Non-detect

1.7 Non-detect

0.029 Non-detect

0.059 Non-detect

Rejected R Rejected

0.13 Non-detect

0.0054 Non-detect

0.048 Non-detect

0.0056 Non-detect

0.0059 Non-detect

0.0057 Non-detect

0.0051 Non-detect

0.0052 Non-detect

0.011 Non-detect

0.0066 Non-detect

0.0057 Non-detect

0.0065 Non-detect

0.0027 Non-detect

4 5

01/21/13

emulsion

108.3

Estimated Estimated

185.2
0.0052 Non-detect

0.018 Non-detect

0.012 Non-detect

0.0057 Non-detect

0.0059 Non-detect

0.0072 Non-detect

0.028 Non-detect

0.0067 Non-detect

0.1111

0.0048 Non-detect

0.006 Non-detect
1/24/2013 - 1/30/2013 1/24/2013 - 1/30/2013

03-S2-B-01-21-2013 04-S2-A-01-21-2013

JB25022-4 JB25023-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

2.66 13.4

0.18 Non-detect 4.42

0.34 Non-detect 0.111

1.7 Non-detect 1.7 Non-detect

0.029 Non-detect 0.029 Non-detect

0.059 Non-detect 0.059 Non-detect

R Rejected R

0.13 Non-detect 0.13 Non-detect

0.0054 Non-detect 0.0011 Non-detect

0.048 Non-detect 0.0095 Non-detect

0.0056 Non-detect 0.0011 Non-detect

0.0059 Non-detect 0.0012 Non-detect

0.0057 Non-detect 0.0011 Non-detect

0.0051 Non-detect 0.001 Non-detect

0.0052 Non-detect 0.001 Non-detect

0.011 Non-detect 0.0022 Non-detect

0.0066 Non-detect 0.0013 Non-detect

0.0057 Non-detect 0.0011 Non-detect

0.0065 Non-detect 0.0013 Non-detect

0.0027 Non-detect 0.00053 Non-detect

6

01/21/13 01/21/13

emulsion emulsion

108.3 176.5

Estimated Estimated

185.2 184.1
0.0052 Non-detect 0.001 Non-detect

0.018 Non-detect 0.0035 Non-detect

0.012 Non-detect 0.0023 Non-detect

0.0057 Non-detect 0.0011 Non-detect

0.0059 Non-detect 0.0012 Non-detect

0.0072 Non-detect 0.0014 Non-detect

0.028 Non-detect 0.0056 Non-detect

0.0067 Non-detect 0.0013 Non-detect

0.1004 0.1018

0.0048 Non-detect 0.00096 Non-detect

0.006 Non-detect 0.0012 Non-detect
1/24/2013 - 1/30/2013

04-S2-B-01-21-2013

JB25023-2

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

12.1

3.74

0.1

1.7 Non-detect

0.029 Non-detect

0.178

Rejected R Rejected

0.13 Non-detect

0.0011 Non-detect

0.0095 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0011 Non-detect

0.001 Non-detect

0.001 Non-detect

0.0022 Non-detect

0.0013 Non-detect

0.0011 Non-detect

0.0013 Non-detect

0.00053 Non-detect

7 8

01/21/13

emulsion

176.5

Estimated Estimated

184.1
0.001 Non-detect

0.0035 Non-detect

0.0023 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0014 Non-detect

0.0056 Non-detect

0.0013 Non-detect

0.0969

0.00096 Non-detect

0.0012 Non-detect
2/1/2013 - 2/5/2013 2/1/2013 - 2/5/2013

05-S2-A-01-29-2013 05-S2-B-01-29-2013

JB25024-1 JB25024-2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

26.1 21

23.3 26.5

0.179 0.212

17 Non-detect 17 Non-detect

0.29 Non-detect 0.29 Non-detect

0.59 Non-detect 0.59 Non-detect

5 Non-detect 5 Non-detect

1.3 Non-detect 1.3 Non-detect

0.0054 Non-detect 0.0054 Non-detect

0.048 Non-detect 0.048 Non-detect

0.0056 Non-detect 0.0056 Non-detect

0.0059 Non-detect 0.0059 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.0051 Non-detect 0.0051 Non-detect

0.0052 Non-detect 0.0052 Non-detect

0.011 Non-detect 0.011 Non-detect

0.0066 Non-detect 0.0066 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.0065 Non-detect 0.0065 Non-detect

0.0027 Non-detect 0.0027 Non-detect

9

01/29/13 01/29/13

emulsion emulsion

109.3 109.3

Estimated Estimated

175.2 175.2
0.0052 Non-detect 0.0052 Non-detect

0.018 Non-detect 0.018 Non-detect

0.012 Non-detect 0.012 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.0059 Non-detect 0.0059 Non-detect

0.0072 Non-detect 0.0072 Non-detect

0.028 Non-detect 0.028 Non-detect

0.0067 Non-detect 0.0067 Non-detect

2.1224 1.7713

0.0048 Non-detect 0.0048 Non-detect

0.006 Non-detect 0.006 Non-detect
2/4/2013 - 2/11/2013

06-S2-A-02-01-2013

JB25026-1

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

5.54

1.01

0.0728

1.7 Non-detect

0.029 Non-detect

0.059 Non-detect

R Rejected

0.13 Non-detect

0.0043 Non-detect

0.038 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0046 Non-detect

0.0041 Non-detect

0.0042 Non-detect

0.0089 Non-detect

0.0052 Non-detect

0.0046 Non-detect

0.0052 Non-detect

0.0021 Non-detect

10 11

02/01/13

emulsion

133.4

Estimated Estimated

185.2
0.0041 Non-detect

0.014 Non-detect

0.0093 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0057 Non-detect

0.022 Non-detect

0.0054 Non-detect

0.3329

0.0038 Non-detect

0.0048 Non-detect
2/4/2013 - 2/11/2013 2/11/2013 - 2/20/2013

06-S2-B-02-01-2013 07-S2-A-02-06-2013

JB25026-2 JB25026-4

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

5.16 1.22

0.55 Non-detect 0.87 Non-detect

1 Non-detect 1.6 Non-detect

1.7 Non-detect 17 Non-detect

0.029 Non-detect 0.29 Non-detect

0.059 Non-detect 0.59 Non-detect

R Rejected R

0.13 Non-detect 1.3 Non-detect

0.0043 Non-detect 0.0021 Non-detect

0.038 Non-detect 0.019 Non-detect

0.0045 Non-detect 0.0023 Non-detect

0.0047 Non-detect 0.0024 Non-detect

0.0046 Non-detect 0.0023 Non-detect

0.0041 Non-detect 0.002 Non-detect

0.0042 Non-detect 0.0021 Non-detect

0.0089 Non-detect 0.0045 Non-detect

0.0052 Non-detect 0.0026 Non-detect

0.0046 Non-detect 0.0023 Non-detect

0.0052 Non-detect 0.0026 Non-detect

0.0021 Non-detect 0.0011 Non-detect

12

02/01/13 02/06/13

emulsion emulsion

133.4 144.5

Estimated Estimated

185.2 157.8
0.0041 Non-detect 0.0021 Non-detect

0.014 Non-detect 0.007 Non-detect

0.0093 Non-detect 0.0046 Non-detect

0.0045 Non-detect 0.0023 Non-detect

0.0047 Non-detect 0.0024 Non-detect

0.0057 Non-detect 0.0029 Non-detect

0.022 Non-detect 0.011 Non-detect

0.0054 Non-detect 0.0027 Non-detect

0.3831 0.3223

0.0038 Non-detect 0.0019 Non-detect

0.0048 Non-detect 0.0024 Non-detect
2/11/2013 - 2/20/2013

07-S2-B-02-06-2013

JB25026-5

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

1.13

1.3 Non-detect

2.4 Non-detect

17 Non-detect

0.29 Non-detect

0.59 Non-detect

Rejected R Rejected

1.3 Non-detect

0.0011 Non-detect

0.0095 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0011 Non-detect

0.001 Non-detect

0.001 Non-detect

0.0022 Non-detect

0.0013 Non-detect

0.0011 Non-detect

0.0013 Non-detect

0.00053 Non-detect

13 14

02/06/13

emulsion

144.5

Estimated Estimated

157.8
0.001 Non-detect

0.0035 Non-detect

0.0023 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0014 Non-detect

0.0056 Non-detect

0.0013 Non-detect

0.2677

0.00096 Non-detect

0.0012 Non-detect
2/14/2013 - 2/23/2013 2/14/2013 - 2/23/2013

08-S2-A-02-11-2013 08-S2-B-02-11-2013

JB25027-1 JB25027-2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

7.11 9.21

1.15 J-Estimated Value 1.12

0.0565 0.0515

0.17 Non-detect 0.17 Non-detect

0.0029 Non-detect 0.0029 Non-detect

0.0059 Non-detect 0.0059 Non-detect

R Rejected R

0.013 Non-detect 0.013 Non-detect

0.0043 Non-detect 0.0043 Non-detect

0.038 Non-detect 0.038 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0047 Non-detect 0.0047 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0041 Non-detect 0.0041 Non-detect

0.0042 Non-detect 0.0042 Non-detect

0.0089 Non-detect 0.0089 Non-detect

0.0052 Non-detect 0.0052 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0052 Non-detect 0.0052 Non-detect

0.0021 Non-detect 0.0021 Non-detect

15

02/11/13 02/11/13

emulsion emulsion

88.3 88.3

Estimated Estimated

184.3 184.3
0.0041 Non-detect 0.0041 Non-detect

0.014 Non-detect 0.014 Non-detect

0.0093 Non-detect 0.0093 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0047 Non-detect 0.0047 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.022 Non-detect 0.022 Non-detect

0.0054 Non-detect 0.0054 Non-detect

0.137 0.1321

0.0038 Non-detect 0.0038 Non-detect

0.0048 Non-detect 0.0048 Non-detect
2/21/2013 - 3/4/2013

09-S2-A-02-19-2013

JB25028-1

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

19

J-Estimated Value 9.16

0.144 J-Estimated Value

3.3 Non-detect

0.057 Non-detect

0.12 Non-detect

Rejected 1 Non-detect

0.26 Non-detect

0.0043 Non-detect

0.038 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0046 Non-detect

0.0041 Non-detect

0.0042 Non-detect

0.0089 Non-detect

0.0279

0.0046 Non-detect

0.0052 Non-detect

0.0021 Non-detect

16 17

02/19/13

emulsion

185.3

Estimated Estimated

185.4
0.0041 Non-detect

0.014 Non-detect

0.0093 Non-detect

0.0045 Non-detect

0.0047 Non-detect

0.0057 Non-detect

0.022 Non-detect

0.0054 Non-detect

0.6792

0.0038 Non-detect

0.0048 Non-detect
2/21/2013 - 3/4/2013 3/4/2013 - 3/13/2013

09-S2-B-02-19-2013 10-S2-A-02-27-2013

JB25028-2 JB25029-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

14.4 4.85

9.68 0.597

0.159 J-Estimated Value R

3.3 Non-detect R

0.057 Non-detect 0.00033 Non-detect

0.12 Non-detect 0.00067 Non-detect

1 Non-detect R

0.26 Non-detect R

0.0043 Non-detect 0.0011 Non-detect

0.038 Non-detect 0.0095 Non-detect

0.0045 Non-detect 0.0011 Non-detect

0.0047 Non-detect 0.0012 Non-detect

0.0046 Non-detect 0.0011 Non-detect

0.0041 Non-detect 0.001 Non-detect

0.0042 Non-detect 0.001 Non-detect

0.0089 Non-detect 0.0022 Non-detect

0.0052 Non-detect 0.0013 Non-detect

0.0046 Non-detect 0.0011 Non-detect

0.0052 Non-detect 0.0013 Non-detect

0.0021 Non-detect 0.00053 Non-detect

18

02/19/13 02/27/13

emulsion emulsion

185.3 181.4

Estimated Estimated

185.4 184.7
0.0041 Non-detect 0.001 Non-detect

0.014 Non-detect 0.0035 Non-detect

0.0093 Non-detect 0.0023 Non-detect

0.0045 Non-detect 0.0011 Non-detect

0.0047 Non-detect 0.0012 Non-detect

0.0057 Non-detect 0.0014 Non-detect

0.022 Non-detect 0.0056 Non-detect

0.0054 Non-detect 0.0013 Non-detect

0.2911 0.244

0.0038 Non-detect 0.00096 Non-detect

0.0048 Non-detect 0.0012 Non-detect
3/4/2013 - 3/13/2013

10-S2-B-02-27-2013

JB25029-2

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

5.02

J-Estimated Value 0.59 J-Estimated Value

Rejected R Rejected

Rejected R Rejected

R Rejected

R Rejected

Rejected R Rejected

Rejected R Rejected

0.0011 Non-detect

0.0095 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0011 Non-detect

0.001 Non-detect

0.001 Non-detect

0.0022 Non-detect

0.0013 Non-detect

0.0011 Non-detect

0.0013 Non-detect

0.00053 Non-detect

19 20

02/27/13

emulsion

181.4

Estimated Estimated

184.7
0.001 Non-detect

0.0035 Non-detect

0.0023 Non-detect

0.0011 Non-detect

0.0012 Non-detect

0.0014 Non-detect

0.0056 Non-detect

0.0013 Non-detect

0.1863

0.00096 Non-detect

0.0012 Non-detect
3/4/2013 - 3/13/2013 3/4/2013 - 3/13/2013

11-S2-A-02-28-2013 11-S2-B-02-28-2013

JB25030-1 JB25030-2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

6.14 5.17

5.95 J-Estimated Value 6.24

0.0421 J-Estimated Value 0.0507

0.17 Non-detect 0.17 Non-detect

0.0029 Non-detect 0.0029 Non-detect

0.0109 0.0059 Non-detect

R Rejected R

0.013 Non-detect 0.013 Non-detect

0.0043 Non-detect 0.0043 Non-detect

0.038 Non-detect 0.038 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0047 Non-detect 0.0047 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0041 Non-detect 0.0041 Non-detect

0.0042 Non-detect 0.0042 Non-detect

0.0089 Non-detect 0.0089 Non-detect

0.0052 Non-detect 0.0052 Non-detect

0.0046 Non-detect 0.0046 Non-detect

0.0052 Non-detect 0.0052 Non-detect

0.0021 Non-detect 0.0021 Non-detect

21

02/28/13 0/28/2013

emulsion emulsion

149.2 149.2

Estimated Estimated

184.5 184.5
0.0041 Non-detect 0.0041 Non-detect

0.014 Non-detect 0.014 Non-detect

0.0093 Non-detect 0.0093 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.0047 Non-detect 0.0047 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.022 Non-detect 0.022 Non-detect

0.0054 Non-detect 0.0054 Non-detect

0.3659 0.4436

0.0038 Non-detect 0.0038 Non-detect

0.0048 Non-detect 0.0048 Non-detect
3/18/2013 - 4/12/2013

12-S2-A-03-14-2013

JB25031-1

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

6.09

J-Estimated Value 3.56 Resample value lab ID: JB25031-7

J-Estimated Value 1.11 Resample value lab ID: JB25031-7

0.17 Non-detect

0.0029 Non-detect

0.0059 Non-detect

Rejected R Rejected

0.013 Non-detect

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0026 Non-detect

0.0023 Non-detect

0.0026 Non-detect

0.0011 Non-detect

22 23

03/14/13

emulsion

193.1

Estimated Estimated

182.7
0.0021 Non-detect

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

0.011 Non-detect

0.0027 Non-detect

0.2036

0.0019 Non-detect

0.0024 Non-detect
3/18/2013 - 4/12/2013 3/21/2013 - 4/9/2013

12-S2-B-03-14-2013 13-S2-A-03-19-2013

JB25031-2 JB25032-1

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

6.04 5.72

3.63 Resample value lab ID: JB25031-8 0.73 Non-detect

1.12 Resample value lab ID: JB25031-8 1.4 Non-detect

0.17 Non-detect 0.83 Non-detect

0.0029 Non-detect 0.014 Non-detect

0.0059 Non-detect 0.029 Non-detect

R Rejected R

0.013 Non-detect 0.064 Non-detect

0.0021 Non-detect 0.0054 Non-detect

0.019 Non-detect 0.048 Non-detect

0.0023 Non-detect 0.0056 Non-detect

0.0024 Non-detect 0.0059 Non-detect

0.0023 Non-detect 0.0057 Non-detect

0.002 Non-detect 0.0051 Non-detect

0.0021 Non-detect 0.0052 Non-detect

0.0045 Non-detect 0.011 Non-detect

0.0026 Non-detect 0.0066 Non-detect

0.0023 Non-detect 0.0057 Non-detect

0.0026 Non-detect 0.0065 Non-detect

0.0011 Non-detect 0.0027 Non-detect

24

03/14/13 03/19/13

emulsion emulsion

193.1 162.3

Estimated Estimated

182.7 158.2
0.0021 Non-detect 0.0052 Non-detect

0.007 Non-detect 0.018 Non-detect

0.0046 Non-detect 0.012 Non-detect

0.0023 Non-detect 0.0057 Non-detect

0.0024 Non-detect 0.0059 Non-detect

0.0029 Non-detect 0.0072 Non-detect

0.011 Non-detect 0.028 Non-detect

0.0027 Non-detect 0.0067 Non-detect

0.1892 0.2229

0.0019 Non-detect 0.0048 Non-detect

0.0024 Non-detect 0.006 Non-detect
3/21/2013 - 4/9/2013

13-S2-B-03-19-2013

JB25032-2

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

5.29

1.07

0.0373

0.83 Non-detect

0.014 Non-detect

0.029 Non-detect

Rejected R Rejected

0.064 Non-detect

0.0054 Non-detect

0.048 Non-detect

0.0056 Non-detect

0.0059 Non-detect

0.0057 Non-detect

0.0051 Non-detect

0.0052 Non-detect

0.011 Non-detect

0.0066 Non-detect

0.0057 Non-detect

0.0065 Non-detect

0.0027 Non-detect

25 26

03/19/13

emulsion

162.3

Estimated Estimated

158.2
0.0052 Non-detect

0.018 Non-detect

0.012 Non-detect

0.0057 Non-detect

0.0059 Non-detect

0.0072 Non-detect

0.028 Non-detect

0.0067 Non-detect

0.1304

0.0048 Non-detect

0.006 Non-detect
4/1/2013 - 4/8/2013 4/1/2013 - 4/8/2013

14-S2-A-03-27-2013 14-S2-B-03-27-2013

JB25033-1 JB25033-2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

10 Non-detect 10 Non-detect

11.1 9.11

6.13 5.95

0.068 Non-detect 0.068 Non-detect

R Rejected R

0.0029 Non-detect 0.0029 Non-detect

0.0059 Non-detect 0.0059 Non-detect

R Rejected R

R Rejected R

0.0054 Non-detect 0.0054 Non-detect

0.048 Non-detect 0.048 Non-detect

0.0056 Non-detect 0.0056 Non-detect

0.0059 Non-detect 0.0059 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.0051 Non-detect 0.0051 Non-detect

0.0052 Non-detect 0.0052 Non-detect

0.011 Non-detect 0.011 Non-detect

0.0066 Non-detect 0.0066 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.0065 Non-detect 0.0065 Non-detect

0.0027 Non-detect 0.0027 Non-detect

27

03/27/13 03/27/13

emulsion emulsion

169.6 169.6

Estimated Estimated

185.4 185.4
0.0052 Non-detect 0.0052 Non-detect

0.018 Non-detect 0.018 Non-detect

0.012 Non-detect 0.012 Non-detect

0.0057 Non-detect 0.0057 Non-detect

0.0059 Non-detect 0.0059 Non-detect

0.0072 Non-detect 0.0072 Non-detect

0.028 Non-detect 0.028 Non-detect

0.0067 Non-detect 0.0067 Non-detect

0.0865 0.0899

0.0048 Non-detect 0.0048 Non-detect

0.006 Non-detect 0.006 Non-detect
4/4/2013-4/8/2013

15-S2-A-04-01-2013

JB25034-1

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

5.73

0.501

0.0868

Rejected 1.7 Non-detect

0.029 Non-detect

0.059 Non-detect

Rejected 0.5 Non-detect

Rejected 0.13 Non-detect

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0026 Non-detect

0.0023 Non-detect

0.0026 Non-detect

0.0011 Non-detect

28 29

04/01/13

emulsion

166.5

Estimated Estimated

185
0.0021 Non-detect

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

0.011 Non-detect

0.0027 Non-detect

Non-detect

0.0019 Non-detect

0.0024 Non-detect
4/4/2013-4/8/2013

15-S2-B-04-01-2013

JB25034-2

Concentration 

(ppmw) Non-Detect? Note(s)

10 Non-detect

6.71

0.54

0.0887

1.7 Non-detect

0.029 Non-detect

0.059 Non-detect

0.5 Non-detect

0.13 Non-detect

0.0021 Non-detect

0.019 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0023 Non-detect

0.002 Non-detect

0.0021 Non-detect

0.0045 Non-detect

0.0026 Non-detect

0.0023 Non-detect

0.0026 Non-detect

0.0011 Non-detect

30

04/01/13

emulsion

166.5

Estimated

185
0.0021 Non-detect

0.007 Non-detect

0.0046 Non-detect

0.0023 Non-detect

0.0024 Non-detect

0.0029 Non-detect

0.011 Non-detect

0.0027 Non-detect

Non-detect

0.0019 Non-detect

0.0024 Non-detect