# April 20, 2012

Mr. Howard Gilberg 

# Guida, Slavich and Flores, P.C. 750 North St. Paul Street, Suite 200 Dallas, Texas 75201

Re: Emissions Testing Report – Tile MACT ICR Report - American Marazzi Tile - Multiple Sources - Methods 1, 2, 3, 3A, 4, 5, 23 and 29 Sunnyvale, Texas Entec Project No.: 210269

Dear Mr. Gilberg, Please find the attached two (2) hard copies and a CD with a PDF copy of the Tile MACT ICR Emissions Testing for Spray Dryer No. 3, Kiln No. 4, Kiln 5 - Upper Chamber and Press Dryer No. 10

. Testing was conducted at the American Marazzi Tile facility located in Sunnyvale, Texas on December 2-3 and 6-7, 2010. A PDF copy of this report has been or will be sent to you by email for your records.
This report is the sole property of Guida, Slavich and Flores, P.C. and no additional copies have been sent to any other entity.
We appreciate the opportunity to perform this project for you and hope to be of assistance to you in the future. If you have any questions please call 205-358-1011.
Sincerely, 

# Entec Services, Inc.

John T. Sutton

# EMISSIONS TESTING TILE MACT ICR
ON SPRAY DRYER NO. 3, ROLLER KILN NO. 4, ROLLER KILN 5–UPPER CHANNEL AND PRESS DRYER NO. 10 

# AMERICAN MARAZZI TILE, INC.
DECEMBER 2-3 AND 6-7, 2010 PROJECT NO.: 210269

Prepared for 

# GUIDA, SLAVICH & FLORES, P.C.
750 North St. Paul Street, Suite 200 Dallas, Texas 75201 

# ENTEC SERVICES, INC.

30 Monroe Drive Pelham, Alabama 35124 (205) 358-1011

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 2 of 29 

# EMISSIONS TESTING TILE MACT ICR
ON SPRAY DRYER NO. 3, KILN NO. 4, ROLLER KILN 5 – UPPER CHANNEL AND PRESS DRYER NO. 10 

# AMERICAN MARAZZI TILE, INC.

CONDUCTED ON DECEMBER 2-3 AND 6-7, 2010 I certify that I have personally examined and am familiar with the information contained herein. Based on my inquiries of the individuals immediately responsible for obtaining the information, I believe the contents of this report deliverable to be true, accurate, and complete, to the best of my knowledge.

Entec Project No. 210269 Report Submitted: April 20, 2012 Completed By: Reviewed By:

________________________________ ___________________________________ 

# W. Keith Poole Manager, Reporting Division Troy Burrows QA / QC Manager

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 3 of 29 TABLE OF CONTENTS
SECTION PAGE
1.0 EXECUTIVE SUMMARY ....................................................................................... 6
2.0 SUMMARY OF TEST RESULTS .......................................................................... 7
2.1 SAMPLING ISSUES AND METHOD DEVIATIONS .................................. 7
3.0 PROCESS DESCRIPTION ................................................................................. 17
3.1 CONTROL EQUIPMENT DESCRIPTION ............................................... 18
4.0 REFERENCE METHOD TEST PROCEDURES ................................................. 19
4.1 US EPA REFERENCE TEST METHOD 1 – TRAVERSE POINT LAYOUT .................................................................. 19 4.2 US EPA REFERENCE TEST METHOD 2 – VELOCITY ......................... 19 4.3 US EPA REFERENCE TEST METHOD 3 – DRY GAS MOLECULAR WEIGHT .................................................................................................. 19 4.4 US EPA REFERENCE TEST METHOD 3A – DRY GAS MOLECULAR WEIGHT .................................................................................................. 20 4.5 US EPA REFERENCE TEST METHOD 4 – MOISTURE CONTENT ..... 20 4.6 US EPA REFERENCE TEST METHOD 23 – DIOXINS FURANS DETERMINATION ................................................................................... 20 4.7 US EPA REFERENCE TEST METHOD 5 WITH 29- PARTICULATE AND METALS. ................................................................................................ 20
5.0 QA / QC PROCEDURES..................................................................................... 29
6.0 CALIBRATION PROCEDURES .......................................................................... 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 4 of 29 LIST OF APPENDICES

APPENDIX PAGE

A RAW TEST DATA AND EMISSIONS CALCULATION SPRAY DRYER NO. 3 – US EPA METHODS 1 - 4 AND 23 ................................ 1
B RAW TEST DATA AND EMISSIONS CALCULATION KILN NO. 4 – US EPA METHODS 1 – 4 AND 29 ............................................... 16
C RAW TEST DATA AND EMISSIONS CALCULATION KILN 5-UPPER CHANNEL .................................................................................. 30 C.1 US EPA METHODS 1 - 4, 5 AND 29 ......................................................... 31 C.2 US EPA METHODS 1 – 4 and 23 .............................................................. 43
D RAW TEST DATA AND EMISSIONS CALCULATION PRESS DRYER NO. 10 – US EPA METHODS 1 – 4 AND 23 ............................ 61
E OPERATIONAL AND PRODUCTION DATA ....................................................... 76
F QA/QC DOCUMENTS AND CHECKLISTS ......................................................... 78
G LABORATORY CHAINS OF CUSTODY ........................................................... 108
H LABORATORY DATA ....................................................................................... 116
H.1 PARTICULATE MATTER AND MULTIPLE METALS ............................ 117 H.2 DIOXINS/FURANS ................................................................................ 128
I CALIBRATION DATA ........................................................................................ 144
J QSTI CERTIFICATIONS ................................................................................... 162
K EXAMPLE CALCULATIONS AND NOMENCLATURE ..................................... 166
L EPA ICR DOCUMENTS .................................................................................... 178
L.1 EPA LETTER AND ENCLOSURES 1 AND 2 ........................................ 179 L.2 ENCLOSURES 3 through 9 AND TABLE 1.1 ........................................ 186

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 5 of 29 LIST OF TABLES

TABLE PAGE

2-1 EMISSIONS SU MMARY – SPRAY DRYER NO. 3 – METHODS 1-4 AND 23 ...... 8
2-2 EMISSIONS SUMMARY – ROLLER KILN NO. 4 – METHODS 1-4 AND 23 ...... 10 2-3 EMISSIONS SUMMARY – KILN 5 UPPER CHANNEL – METHODS 1-4, 5 AND 29 ................................................................................................................ 12
2-4 EMISSIONS SUMMARY – KILN 5 UPPER CHANNEL – METHODS 1-4 AND 23 ................................................................................................................. 14
2-5 EMISSIONS SU MMARY – PRESS DRYER NO. 10 – METHODS 1-4 AND 23 .. 15

LIST OF FIGURES

FIGURE PAGE

4-1 TRAVERSE POINT LAYOUT – SPRAY DRYER NO. 3 ...................................... 23
4-2 TRAVERSE POINT LAYOUT – ROLLER KILN NO. 4 ........................................ 24
4-3 TRAVERSE POINT LAYOUT – KILN 5 UPPER CHANNEL ............................... 25
4-4 TRAVERSE POINT LAYOUT – PRESS DRYER NO. 10 .................................... 26
4-5 METHOD 23 SAMPLE TRAIN DIAGRAM ........................................................... 27
4-6 METHOD 5 / 29 SAMPLE TRAIN DIAGRAM ...................................................... 28

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 6 of 29 1.0 EXECUTIVE SUMMARY

On March 12, 2010 the U. S. Environment al Protection Agency (US EPA) issued an Information Collection Request (the Tile ICR) to American Marazzi Tile, Inc. Within the Tile ICR, Enclosure 2 specified the emission sources and pollutants that were required to be tested and Enclosure 3, Table 1.1 Summary of Ceramic Tile Source Test Methods and Alternate Methods, specified the test methods and parameters for each pollutant to be tested. These enclosures are included as attachments to this report and can be located in Appendix L.

Although the ICR requested that testing be performed for PM 2.5 and condensable PM, these tests were not performed due to an agreement reached between the tile industry and the US EPA. The Test Protocol that was submitted and approved reflects this, as there is no discussion of these tests. Additionally, because of production issues, Kiln 4 (RK-4) was tested in lieu of Kiln 1 (RK-1) and the upper channel of the double layer kiln (RK-5U) was tested in lieu of the lower channel (RK-5L). These changes were coordinated with the EPA prior to the testing.

On April 13, 2010, the Tile Council of North America (TCNA), through the offices of Guida, Slavich and Flores contracted with Entec Services to perform this testing at all TCNA member companies who had received the ICR.

Testing was conducted at American Marazzi Tile on December 2-3 and 6-7, 2010 by Mr. Lynn Beane, Mr. Kevin Rosenberg, Mr. Chuck Duncan IV, Mr. Eric Groth, Mr. Lalan Kirby and Mr. Ryan Fogg of Entec Services, Inc. Repres enting American Marazzi Tile was Mr. Steve Wiederwax who coordinated testing with plant production personnel.

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 7 of 29 2.0 SUMMARY OF TEST RESULTS

Emission testing was conducted on the following sources utilizing US EPA methods 1, 2, 3, 3A, 4, 5, 23 and 29 of 40 CFR 60, Appendix A as indicated in the table below.

ICR ID Source Name/Control Device Test Methods SD-3 Spray Dryer No. 3/Fabric Filter 1, 2, 3, 3a, 4, 23 RK-4 Kiln No. 4/No control device 1, 2, 3, 3a, 4, 5, 29 RK-5U Roller Kiln 5-Upper channel /No control device 1, 2, 3, 3a, 4, 5, 23, 29 DC-10 Press Dryer No. 10/ No control device 1, 2, 3, 3a, 4, 23

2.1 SAMPLING ISSUES AND METHOD DEVIATIONS

No difficulties or problems were encountered during sampling on the above sources. The emissions test summaries on the following pages gives a detailed summary of each test. No process data was provided thus emissions are not reported in kg/MG of product. The Company will submit process data and corresponding calculations as CBI (confidential business information) under separate cover.

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 8 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 9 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 10 of 29



# Table 2-2 

# Emissions Summary

Test Performed For: Testing Performed By: Sunnyvale, TX Birmingham Division
Source(s) Tested: Roller Kiln No. 4 (RK-4) Project Manager: Test Condition: Operating Conditions - ICR Tile MACT Lynn Beane Test(s) Performed:

Run Number Run 1 Run 2 Run 3 Average 

## Date of Run 12/6/10 12/7/10 12/7/10 3 Runs 

## Times, Pollutant Runs (Began - Ended) 1230-1635 0735 - 1137 1210 - 1613

- 

## Oxygen Conc., % (dry basis) 

## 13.3 13.1 13.2 13.2 

## Carbon Dioxide Conc. % (dry basis) 

## 4

. 8 4

. 9 4

. 8 4

. 8 

## Molecular Weight Of Stack Gas 29.29 29.30 29.29 29.30 

## Molecular Weight Of Stack Gas 28.01 27.98 27.96 27.98 

## Isokinetic Sampling Rate % 

## 102.71 99.48 98.67

- 

## Stack Temperature o 

## F 480.3 473.4 473.2 475.6 

## Stack Temperature o 

### C 

## 249.1 245.2 245.1 246.5 

## Moisture Content %, v / v 

## 11.33 11.63 11.85 11.60 

## Average Stack Gas Velocity mps 

## 11.91 12.20 11.80 11.97 

## Stack Gas Flow @ Actual Conditions acmm 

## 348 356 345 350 

## Stack Gas Flow @ Standard Conditions scmm 

## 195 200 194 197 

## Stack Gas Flow @ Dry Standard Conditions dscmm 

## 173 177 171 174



## Particulate Conc. @ STP mg / dscm 12.01 10.93 14.56 12.50 

## Antimony Conc. @ STP mg / dscm 4.73E-04 3.98E-04 5.70E-04 4.80E-04 

## Arsenic Conc. @ STP mg / dscm 2.01E-02 1.77E-02 2.34E-02 2.04E-02 

## Beryllium Conc. @ STP mg / dscm 4.78E-05 1.02E-04 6.39E-05 7.12E-05 

## Cadmium Conc. @ STP mg / dscm 3.04E-03 3.98E-03 5.65E-03 4.22E-03 

## Chromium Conc. @ STP mg / dscm 1.86E-02 1.60E-02 2.80E-02 2.09E-02 

## Cobalt Conc. @ STP mg / dscm 3.59E-04 4.81E-04 1.78E-04 3.39E-04 

## Lead Conc. @ STP mg / dscm 3.84E-02 1.94E-02 6.89E-02 4.22E-02 

## Manganese Conc. @ STP mg / dscm 7.23E-03 2.47E-02 7.75E-03 1.32E-02 

## Mercury Conc. @ STP mg / dscm 1.08E-02 1.17E-02 1.18E-02 1.14E-02 

## Nickel Conc. @ STP mg / dscm 1.53E-03 1.85E-03 1.34E-03 1.57E-03 

## Selenium Conc. @ STP mg / dscm 2.80E-01 2.59E-01 4.01E-01 3.14E-01 

## Total Metals Conc. @ STP mg / dscm 3.81E-01 3.56E-01 5.49E-01 4.29E-01 

## American Marazzi Tile

Methods 1-4, 5 and 29 (Metric)

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 11 of 29 

# Table 2-2 , continued 

# Emissions Summary

Test Performed For: Testing Performed By: Sunnyvale, TX Birmingham Division Source(s) Tested: Roller Kiln No. 4 (RK-4) Project Manager: Test Condition: Operating Conditions - ICR Tile MACT Lynn Beane Test(s) Performed:

Run Number Run Run Run Average 

## Date of Run 12/6/10 12/7/10 12/7/10 3 Runs 

## Particulate Conc. @ 7% Oxygen mg / dscmc 22.1 19.4 26.3 22.58 

## Antimony Conc. @ 7% Oxygen mg / dscmc 8.70E-04 7.04E-04 1.03E-03 8.68E-04 

## Arsenic Conc. @ 7% Oxygen mg / dscmc 3.70E-02 3.14E-02 4.23E-02 3.69E-02 

## Beryllium Conc. @ 7% Oxygen mg / dscmc 8.79E-05 1.81E-04 1.16E-04 1.28E-04 

## Cadmium Conc. @ 7% Oxygen mg / dscmc 5.59E-03 7.04E-03 1.02E-02 7.62E-03 

## Chromium Conc. @ 7% Oxygen mg / dscmc 3.42E-02 2.84E-02 5.06E-02 3.77E-02 

## Cobalt Conc. @ 7% Oxygen mg / dscmc 6.60E-04 8.52E-04 3.22E-04 6.11E-04 

## Lead Conc. @ 7% Oxygen mg / dscmc 7.06E-02 3.43E-02 1.24E-01 7.65E-02 

## Manganese Conc. @ 7% Oxygen mg / dscmc 1.33E-02 4.38E-02 1.40E-02 2.37E-02 

## Mercury Conc. @ 7% Oxygen mg / dscmc 1.99E-02 2.07E-02 2.13E-02 2.06E-02 

## Nickel Conc. @ 7% Oxygen mg / dscmc 2.81E-03 3.27E-03 2.41E-03 2.83E-03 

## Selenium Conc. @ 7% Oxygen mg / dscmc 5.16E-01 4.59E-01 7.26E-01 5.67E-01 

## Total Metals Conc. @ 7% Oxygen mg / dscmc 7.01E-01 6.30E-01 9.92E-01 7.74E-01 

## Particulate Emissions kg / hr 1.25E-01 1.16E-01 1.49E-01 1.30E-01 

## Antimony Emissions kg / hr 4.92E-06 4.22E-06 5.84E-06 5.00E-06 

## Arsenic Emissions kg / hr 2.09E-04 1.88E-04 2.40E-04 2.12E-04 

## Beryllium Emissions kg / hr 4.97E-07 1.08E-06 6.55E-07 7.45E-07 

## Cadmium Emissions kg / hr 3.16E-05 4.22E-05 5.79E-05 4.39E-05 

## Chromium Emissions kg / hr 1.93E-04 1.70E-04 2.87E-04 2.17E-04 

## Cobalt Emissions kg / hr 3.73E-06 5.11E-06 1.83E-06 3.56E-06 

## Lead Emissions kg / hr 4.00E-04 2.06E-04 7.06E-04 4.37E-04 

## Manganese Emissions kg / hr 7.52E-05 2.63E-04 7.95E-05 1.39E-04 

## Mercury Emissions kg / hr 1.13E-04 1.24E-04 1.21E-04 1.19E-04 

## Nickel Emissions kg / hr 1.59E-05 1.96E-05 1.37E-05 1.64E-05 

## Selenium Emissions kg / hr 2.92E-03 2.75E-03 4.11E-03 3.26E-03 

## Total Metals Emissions kg / hr 3.96E-03 3.78E-03 5.63E-03 4.46E-03 

# American Marazzi Tile

Methods 1-4, 5 and 29 (Metric)

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 12 of 29



# Table 2-3 

# Emissions Summary

Test Performed For: Testing Performed By: Sunnyvale, TX Birmingham Division
Source(s) Tested: Roller Kiln 5 Upper Channel (RK-5U) Project Manager: Test Condition: Operating Conditions - ICR Tile MACT Lynn Beane Test(s) Performed:

Run Number Run 1 Run 2 Run 3 Average 

## Date of Run 12/6/10 12/7/10 12/7/10 3 Runs 

## Times, Pollutant Runs (Began - Ended) 1000-1410 0737-1151 1255-1701

- 

## Oxygen Conc., % (dry basis) 

## 19.3 19.3 19.0 19.2 

## Carbon Dioxide Conc. % (dry basis) 

## 0

. 9 0

. 9 1

. 0 0

. 9 

## Molecular Weight Of Stack Gas g/g-mole 

## 28.91 28.92 28.92 28.92 

## Molecular Weight Of Stack Gas g/g-mole 

## 28.59 28.55 28.57 28.57 

## Isokinetic Sampling Rate % 

## 93.93 99.12 98.85

- 

## Stack Temperature o 

## F 231.8 224.5 236.8 231.1 

## Stack Temperature o 

### C 

## 111.0 107.0 113.8 110.6 

## Moisture Content %, v / v 

## 2.98 3.37 3.20 3.18 

## Average Stack Gas Velocity mps 

## 16.75 16.36 16.87 16.66 

## Stack Gas Flow @ Actual Conditions acmm 

## 795 776 800 790 

## Stack Gas Flow @ Standard Conditions scmm 

## 602 601 609 604 

## Stack Gas Flow @ Dry Standard Conditions dscmm 

## 585 581 589 585


## Particulate Conc. @ STP mg / dscm 2.20 3.41 2.81 2.81 

## Antimony Conc. @ STP mg / dscm 8.86E-05 1.01E-04 1.67E-04 1.19E-04 

## Arsenic Conc. @ STP mg / dscm 6.91E-03 9.58E-03 7.54E-03 8.01E-03 

## Beryllium Conc. @ STP mg / dscm 7.68E-05 5.88E-05 5.81E-05 6.46E-05 

## Cadmium Conc. @ STP mg / dscm 1.86E-04 1.25E-04 1.82E-04 1.64E-04 

## Chromium Conc. @ STP mg / dscm 8.47E-03 9.46E-03 9.00E-03 8.98E-03 

## Cobalt Conc. @ STP mg / dscm 6.69E-05 4.12E-05 5.15E-05 5.32E-05 

## Lead Conc. @ STP mg / dscm 5.68E-03 5.10E-03 5.01E-03 5.26E-03 

## Manganese Conc. @ STP mg / dscm 2.11E-03 9.43E-04 1.02E-03 1.36E-03 

## Mercury Conc. @ STP mg / dscm 4.82E-03 8.21E-03 6.07E-03 6.36E-03 

## Nickel Conc. @ STP mg / dscm 1.73E-03 7.96E-04 9.14E-04 1.15E-03 

## Selenium Conc. @ STP mg / dscm 2.39E-01 3.23E-01 2.75E-01 2.79E-01 

## Total Metals Conc. @ STP mg / dscm 2.69E-01 3.57E-01 3.05E-01 3.10E-01 

## American Marazzi Tile

Methods 1-4, 5 and 29 (Metric)

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 13 of 29 

# Table 2-3 , continued 

# Emissions Summary

Test Performed For: Testing Performed By: Sunnyvale, TX Birmingham Division
Source(s) Tested: Roller Kiln 5 Upper Channel (RK-5U) Project Manager: Test Condition: Operating Conditions - ICR Tile MACT Lynn Beane Test(s) Performed:

Run Number Run Run Run Average 

## Date of Run 12/6/10 12/7/10 12/7/10 3 Runs 

## Particulate Conc. @ 7% Oxygen mg / dscmc 19.1 29.1 20.7 22.96 

## Antimony Conc. @ 7% Oxygen mg / dscmc 7.70E-04 8.61E-04 1.23E-03 9.53E-04 

## Arsenic Conc. @ 7% Oxygen mg / dscmc 6.00E-02 8.17E-02 5.54E-02 6.57E-02 

## Beryllium Conc. @ 7% Oxygen mg / dscmc 6.68E-04 5.02E-04 4.27E-04 5.32E-04 

## Cadmium Conc. @ 7% Oxygen mg / dscmc 1.62E-03 1.07E-03 1.34E-03 1.34E-03 

## Chromium Conc. @ 7% Oxygen mg / dscmc 7.36E-02 8.06E-02 6.62E-02 7.35E-02 

## Cobalt Conc. @ 7% Oxygen mg / dscmc 5.81E-04 3.51E-04 3.79E-04 4.37E-04 

## Lead Conc. @ 7% Oxygen mg / dscmc 4.93E-02 4.35E-02 3.69E-02 4.32E-02 

## Manganese Conc. @ 7% Oxygen mg / dscmc 1.83E-02 8.04E-03 7.51E-03 1.13E-02 

## Mercury Conc. @ 7% Oxygen mg / dscmc 4.18E-02 7.00E-02 4.46E-02 5.22E-02 

## Nickel Conc. @ 7% Oxygen mg / dscmc 1.50E-02 6.79E-03 6.72E-03 9.52E-03 

## Selenium Conc. @ 7% Oxygen mg / dscmc 2.08E+00 2.75E+00 2.02E+00 2.28E+00 

## Total Metals Conc. @ 7% Oxygen mg / dscmc 2.34E+00 3.05E+00 2.24E+00 2.54E+00 

## Particulate Emissions kg / hr 7.73E-02 1.19E-01 9.93E-02 9.85E-02 

## Antimony Emissions kg / hr 3.11E-06 3.52E-06 5.90E-06 4.18E-06 

## Arsenic Emissions kg / hr 2.42E-04 3.34E-04 2.67E-04 2.81E-04 

## Beryllium Emissions kg / hr 2.70E-06 2.05E-06 2.06E-06 2.27E-06 

## Cadmium Emissions kg / hr 6.54E-06 4.36E-06 6.43E-06 5.78E-06 

## Chromium Emissions kg / hr 2.97E-04 3.29E-04 3.18E-04 3.15E-04 

## Cobalt Emissions kg / hr 2.34E-06 1.43E-06 1.82E-06 1.87E-06 

## Lead Emissions kg / hr 1.99E-04 1.78E-04 1.77E-04 1.85E-04 

## Manganese Emissions kg / hr 7.40E-05 3.29E-05 3.61E-05 4.77E-05 

## Mercury Emissions kg / hr 1.69E-04 2.86E-04 2.15E-04 2.23E-04 

## Nickel Emissions kg / hr 6.07E-05 2.77E-05 3.23E-05 4.03E-05 

## Selenium Emissions kg / hr 8.38E-03 1.13E-02 9.72E-03 9.79E-03 

## Total Metals Emissions kg / hr 9.44E-03 1.25E-02 1.08E-02 1.09E-02 

# American Marazzi Tile

Methods 1-4, 5 and 29 (Metric)

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 14 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 15 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 16 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 17 of 29 3.0 PROCESS DESCRIPTION

No production data is included in this report. The Company will submit process data and corresponding calculations as CBI (confidential business information) under separate cover.
Nonmetallic Mineral Processing

This includes the receipt of the raw materials by truck (shale, clay, nepheline syenite, feldspar, talc, recycled glass, and sand) and their storage in the raw material storage area. These materials are moved by a front-end loader to the appropriate plant and loaded into a feed hopper. For Plant 1 with the exception of the shale and clay, these materials are metered directly out onto a conveyor system that transport s the material to storage silos. The shale and clay material is processed through a crusher prio r to being conveyed to a storage silo. From the storage silos, raw materials are transported by conveyors to surge hoppers that feed the individual continuous mills. Within Plant 2 these materials are loaded into a feed hopper and then metered directly onto a conveyor belt and transported to surge hoppers that feed the continuous mill. Once fed into a continuous ball mill water is added and then milled to the desired consistency and viscosity creating a mud like slurry called “slip.” Upon completion of the milling process, the slip is pumped in to a concrete slip tank where it is stored before spray drying

Spray Drying

The slip is then pumped, at high pressure, into one of three spray dryers (atomizer) through a series of nozzles that cause the slip to be sprayed as a fine mist into an enclosed hot air stream that dries the slip to a fine powder with low moisture content. This prill is transported via conveyor systems to the prill silos. The spray dryers are fueled by natural gas.

Tile Drying

The individual pressed tiles are transported by roller conveyor to either a horizontal or vertical five channel roller dryer to further reduce the moisture content of individual pressed tiles. These dried tiles are referred to as “green tile” and this drying process provides the green tiles with sufficient strength to undergo glazing and transfer to the kilns. Press dryers are fueled by natural gas.

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 18 of 29 Firing

This step involves heating of the tiles to vitrify (make glass-like) and fuse (bond) the glaze material permanently to the surface of the tile body. The green tiles are fed into a fast fire roller kiln and fired according to a predetermined temperature curve that exposes the tiles to a maximum temperature of approximately 2,000°F and then cooled rapidly by an indirect cooling system. This process results in the formation of an attractive product in which the glazing materials and tile body are fused permanently together. Natural gas is used as fuel to heat the kilns.
3.1 Control Equipment Description

Spray Dryer 3 (SD-3) is controlled by a Eurofilter Model FD 1080-18-3000 Dust Collector. The Press Dryer (DC-10), Kiln RK-4 (RK-4) and Roller Kiln 5 Upper Chamber (RK-5U) are uncontrolled sources.

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 19 of 29 4.0 REFERENCE METHOD TEST PROCEDURES

Emission rates were determined using US EPA Reference Test Methods 1, 2, 3, 3A, 4, 5, 23 and 29 of US EPA 40 CFR 60, Appendix A. Calibration and quality assurance procedures of US EPA 40 CFR Part 60, Appendix A and the “Quality Assurance Handbook for Air Pollution Measurement System” Volume III Stationary Source-Specific Methods were followed throughout the duration of field and laboratory testing for all methods. The most current version for each method (as described in the Federal Register) was used.

4.1 US EPA REFERENCE TEST METHOD 1 - TRAVERSE POINT LAYOUT

For Information on stack dimensions, traverse points, distance to disturbance and other relevant data, refer to the drawings presented in Figures 4-1 through 4-4, “Stack Drawing and Traverse Point Location”.

4.2 US EPA REFERENCE TEST METHOD 2 - VELOCITY

The velocity of each gas stream was determined according to USEPA Reference Method 2 by reading the instantaneous velocity head with an inclined manometer at each sampling point with a calibrated S-type pitot. The stack pressure was measured with the static side of an S-type pitot tube. A calibrated pyrometer was used to measure stack temperature at each sampling point. All test data, worksheets, and spreadsheets presenting the calculations are included in Appendices A - D. Calibration procedures for the velocity equipment are located in Section 6.0 of this report. Pitot tube, thermocouple, and other measurement device calibration worksheets used for the test series are presented in Appendix I.

4.3 US EPA REFERENCE TEST METHOD 3 - DRY GAS MOLECULAR WEIGHT-CARBON DIOXIDE
Dry Gas molecular weight (carbon dioxide) was determined using US EPA Reference Test Method 3 (Fyrite Method). A sample of the flue gas was extracted from the gas stream during each test. These samples were analyzed with a Fyrite gas analyzer. The molecular weight of the gas was calculated using the moisture, oxygen and carbon dioxide content, and the measured stack gas temperature.

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 20 of 29 4.4 US EPA REFERENCE TEST METHOD 3A - MOLECULAR WEIGHT DETERMINATION-INSTRUMENTAL ANALYSIS- OXYGEN The oxygen concentration was determined usi ng US EPA Reference Test Method 3A. A sample of the flue gas was extracted from the gas stream during each test. Moisture was removed from the sample and the dry sample was then analyzed with an instrumental gas analyzer. The molecular weight of the gas was calculated using the moisture, oxygen and carbon dioxide content and the measured stack gas temperature.

4.5 US EPA REFERENCE TEST METHOD 4 - MOISTURE CONTENT

The moisture content used for calculating the gas stream flow rate was determined by measuring the moisture in a series of glass impi ngers and silica gel impin ger gravimetrically with an analytical balance with a tolerance of 0.1 g. The volume of gas drawn was corrected to dry standard conditions. The dry gas meter and thermocouple calibration forms are contained in Appendix I.

4.6 US EPA REFERENCE TEST METHOD 23 - DIOXIN-FURAN DETERMINATION
This method is applicable to the determination of polychlorinated dibenzo-p-dioxins (PCDD's) and polychlorinated dibenzofurans (PCDF's ) from stationary sources. A sample is withdrawn from the gas stream isokinetically and collected in the sample probe, on a glass fiber filter, and on a packed column of adsorbent material. The sample cannot be separated into a particle vapor fraction. The PCDD's and PCDF's are extracted from the sample, separated by high resolution gas chromatography, and measur ed by high resolution mass spectrometry.

4.7 US EPA REFERENCE TEST METHOD 5 WITH METHOD 29 – PARTICULATE AND METALS DETERMINATION

The particulate/multiple metals sample train consisted of a heated stainless steel sample probe with a glass liner equipped with an S-type pitot tube and thermocouple. The probe was attached to a sample module consisting of a heated filter compartment, which houses the in-line filter holder equipped with a pre-weighed quartz filter for the collection of the particulate, and a series of glass impingers to collect metals and determine moisture. The sample module was connected to a control module by means of an um bilical cord. The control module consisted of a dry gas meter, calibrated orifice, leak free pump, two inclined manometers, and temperature

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 21 of 29 controllers for the heated filter compartment, the probe, and a thermocouple indicator to monitor the required temperatures during the testing.

Gas samples were collected as follows: the sample gas was drawn through the sampling probe isokinetically and passed through a 3-inch quartz filter on to which particulate matter was deposited. The sample gas was then passed through a series of ice-cooled impingers. The first and second impingers contained exactly 100 ml each of an absorbing solution (5% HNO 3 

# 10% H 2 

# O 2 

# ). The third impinger was empty. The fourth and fifth impingers contained exactly 100 ml each of acidic KMnO 4 

# absorbing solution. The sixth impinger contained exactly 250 g of silica gel, which absorbs any remaining moisture. These impingers were placed in an ice-bath to maintain a maximum exit temperature of 68 o 

# F. The sample gas then passed through a vacuum pump followed by a dry gas meter. The dry gas meter integrated the sample gas flow throughout the duration of the test. A calibrated orifice attached to the outlet of the dry gas meter provided real time flow rate data.

A representative gas sample was acquired by sampling for equal periods of time at the centroid of a number of equal area regions in the exhaust stack. The sampling rate was adjusted at each test point maintaining an isokinetic sampling condition.

After the sampling was complete, the filter was removed and placed in a storage container. The nozzle, probe liner, and inlet side of the filter holder were quantitatively washed with exactly 100 ml of reagent grade acetone and stored in a marked and sealed container. The nozzle, probe liner, and inlet side of the filter holder were rinsed again with 0.1N HNO 3 

# and placed into another marked and sealed container. The nozzle and probe liner were then rinsed with DI water and followed by another acetone rinse. These rinses were not retained and were a QA/QC step to ensure clean glassware prior to starting another run. The liquids from the first and second impingers were weighed and added to a third marked and sealed container. The back half of the filter holder and these two impi ngers were rinsed with exactly 100 ml of 0.1N HNO 3 

# and the rinses were added to the same container. The contents of the third impinger were weighed and then rinsed with exactly 100 ml of 0.1N HNO 3 

# and the rinses were placed in a fourth marked and sealed container. The liquids from the fourth and fifth impingers were weighed and added to a fifth marked and sealed container. These impingers were first rinsed with exactly 100 ml of fresh KMnO 4, 

# and then exactly 100 ml of distilled water and the rinses were added to the sample container. All the samples were transferred to our laboratory for particulate determination and shipment to ALS Laboratory Group for metals analysis. The fourth

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 22 of 29 and fifth impingers were then rinsed with a total of 25ml of 8N HCI; this was added to 200ml of DI 

# water in a sixth marked container and sealed. The sixth impinger was weighed to determine moisture catch of the silica gel.

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 23 of 29 Client: American Marazzi Tile Job No. : Source: Spray Dryer 3 (SD-3) Input By:

P Port Type Nipple Port Diameter Stack Properties: Inches Feet Stack Diameter (inside), inches: 71.75 5.98 Stack Height (grade to test platform), feet: 50.00 Stack Diameters 

### 740.0 10.31
320.0 4.46 12 12

Point No. 1 1.5 8.0 2 4.8 11.3 3 8.5 15.0 4 12.7 19.2 5 17.9 24.4 6 25.5 32.0 7 46.2 52.7 8 53.8 60.3 9 59.1 65.6 10 63.3 69.8 11 66.9 73.4 12 70.2 76.7

* Adjusted points diameter > 24" no point closer than 1.0 inch * Adjusted points diameter < 24" no point closer than 0.5 inch

Stack Diameters between 12-24 inches minimum points are 8 ; 4 points per port if the 8 / 2 diameters downstream and upstream criteria is met. 

# Fi g ure 4-1 Entec Services, Inc 30 Monroe Drive, Pelham, Alabama 35124

Type of Traverse: Velocity (V) or Particulate (P):

2 

## STACK DRAWING & TRAVERSE POINT LOCATION

Total Number of Traverse Points: 6
28.078

'After' Flow Disturbance, Distance (A) : Stack Area, Ft 2 

### :

24 Length of Port, inches:

Inches Inside Stack 'Before' Flow Disturbance, Distance (B) : 

### 210269

Chuck Duncan IV



### Outside Nipple Number of Points per port / traverse: Number of Ports:

Inches 6.50

INCHES 

# 71.75 INCHES

INCHES



# 320.0 740.0

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 24 of 29 Client: American Marazzi Tile Job No. : Source: Roller Kiln No. 4 (RK-4) Input By:

P Port Type Flange Port Diameter Stack Properties: Inches Feet Stack Diameter (inside), inches: 31 2.58 Stack Height (grade to test platform), feet: 50.00 Stack Diameters 

### 240.0 7.74
129.0 4.16 12 12 * The port length was different from A side to B side. Therefore, the test crew established probe markings flush with stack wa ll.

Point No. 1 1.0 *adjusted 1.0 2 2.1 2.1 3 3.7 3.7 4 5.5 5.5 5 7.8 7.8 6 11.0 11.0 7 20.0 20.0 8 23.3 23.3 9 25.5 25.5 10 27.3 27.3 11 28.9 28.9 12 30.0 *adjusted 30.0

* Adjusted points diameter > 24" no point closer than 1.0 inch * Adjusted points diameter < 24" no point closer than 0.5 inch

Stack Diameters between 12-24 inches minimum points are 8 ; 4 points per port if the 8 / 2 diameters downstream and upstream criteria is met. 24

INCHES 

### Outside Nipple Inches 0.00 Length of Port, inches:*



# 31.0 INCHES

INCHES



# 129.0 240.0 Inches Inside Stack 'Before' Flow Disturbance, Distance (B) : 5.241 

## STACK DRAWING & TRAVERSE POINT LOCATION

'After' Flow Disturbance, Distance (A) : Type of Traverse: Velocity (V) or Particulate (P):

2

Total Number of Traverse Points: Number of Points per port / traverse: Number of Ports: Stack Area, Ft 2 

### : 

## 210269

Chuck Duncan IV



### 6 

# Fi g ure 4-2 Entec Services, Inc 30 Monroe Drive, Pelham, AL 35124

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 25 of 29 Client: American Marazzi Tile Job No. : Source: Roller Kiln 5 Upper Channel (RK-5U) Input By:

P Port Type Flange Port Diameter Stack Properties: Inches Feet Stack Diameter (inside), inches: 39.5 3.29 Stack Height (grade to test platform), feet: 100.00 Stack Diameters 

### 600.0 15.19 300.0 7.59 12 12

Point No. 1 1.0 *adjusted 7.0 2 2.6 8.6 3 4.7 10.7 4 7.0 13.0 5 9.9 15.9 6 14.1 20.1 7 25.4 31.4 8 29.6 35.6 9 32.5 38.5 10 34.8 40.8 11 36.9 42.9 12 38.5 *adjusted 44.5

* Adjusted points diameter > 24" no point closer than 1.0 inch * Adjusted points diameter < 24" no point closer than 0.5 inch

Stack Diameters between 12-24 inches minimum points are 8 ; 4 points per port if the 8 / 2 diameters downstream and upstream criteria is met. 

# Fi g ure 4-3 Entec Services, Inc 30 Monroe Drive, Pelham, AL 35124

Type of Traverse: Velocity (V) or Particulate (P):

2 

## STACK DRAWING & TRAVERSE POINT LOCATION

Total Number of Traverse Points: 6
8.510

'After' Flow Disturbance, Distance (A) : Stack Area, Ft 2 

### :

24 Length of Port, inches:

Inches Inside Stack 'Before' Flow Disturbance, Distance (B) : 

## 210269 Kevin Rosenberg

Outside Nipple Number of Points per port / traverse: Number of Ports:

Inches 6.00

INCHES 

# 39.5 INCHES

INCHES



# 300.0 600.0

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 26 of 29 Client: American Marazzi Tile Job No. : Source: Press Dryer 10 (DC-10) Input By:

P Port Type Nipple Port Diameter Stack Properties: Inches Feet Stack Diameter (inside), inches: 19.0 1.58 Stack Height (grade to test platform), feet: 50.00
Stack Diameters 

### 600.0 31.58
42.0 2.21 12 12

Point No. 1 0.5 adjusted 5.3 2 1.3 6.0 3 2.2 7.0 4 3.4 8.1 5 4.8 9.5 6 6.8 11.5 7 12.2 17.0 8 14.3 19.0 9 15.6 20.4 10 16.8 21.5 11 17.7 22.5 12 18.5 adjusted 23.3

* Adjusted points diameter > 24" no point closer than 1.0 inch * Adjusted points diameter < 24" no point closer than 0.5 inch

Stack Diameters between 12-24 inches minimum points are 8 ; 4 points per port if the 8 / 2 diameters downstream and upstream criteria is met. 

# Fi g ure 4-4 Entec Services, Inc 30 Monroe Drive, Pelham, AL 35124

Type of Traverse: Velocity (V) or Particulate (P):

2 

## STACK DRAWING & TRAVERSE POINT LOCATION

Total Number of Traverse Points: 3
1.969

'After' Flow Disturbance, Distance (A) : Stack Area, Ft 2 

### :

24 Length of Port, inches:

Inches Inside Stack 'Before' Flow Disturbance, Distance (B) : 

### 210269
Kevin Rosenberg



### Outside Nipple Number of Points per port / traverse: Number of Ports:

Inches 4.75

INCHES 

# 19.0 INCHES

INCHES



# 42.0 600.0

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 27 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 28 of 29

# American Marazzi Tile, Inc. – Sunnyvale, TX Project No. 210269 Page 29 of 29 5.0 QA / QC PROCEDURES

Specific Quality Assurance / Quality Control (QA / QC) procedures were adhered to during this test project to provide valid and scientifically defensible data. For any environmental field and laboratory measurement, a degree of uncertainty exists in the data due to inherent limitations of the measurement sy stems employed. Entec Services, Inc. objective of the QA / QC program is to produce data of known precis ion, accuracy, representation, completeness, and comparability. Special Entec-designed QA/QC checklists are contained in Appendix F.

6.0 CALIBRATION PROCEDURES

All of the emission testing equipment used was calibrated according to the procedures outlined in the EPA 40 CFR Part 60 Appendix “A” and the Quality Assurance Handbook for Air Pollution Measurement Systems, Volume III, EPA- 600/4-94-038c. Complete calibration records are located in the appendix of this report.

## Client:
Source: Spray Dryer 3 (SD-3) 

## Symbol Units Test Data QC'd by Keith Poole



### - - 

### 1 2 3A V E R A G E


## Test Date

- - 

### 12/02/10 12/02/10 12/03/10 All Runs 

## Times, Pollutant Runs (Began - Ended) - Military Time 

### 0821-1229 1422-1829 0802-1207

- 

## Sampling Time  minutes 

### 240 240 240 240 

## Stack Area A s 

### Ft 2 

### 28.08 28.08 28.08

- 

## Barometric Pressure P bar 

### in. Hg 

### 29.75 29.75 30.07 29.910 

## Stack Static Pressure P g 

### in. H 2 

### 0 

### -0.40 -0.40 -0.40 -0.40 

## Pitot Tube Correction factor C p 

### - 

### 0.84 0.84 0.84

- 

## Meter Correction Factor Y - 

### 1.010 1.010 1.010

- 

## Meter Delta H @  H@ in. H 2 

### 0 

### 1.905 1.905 1.905 1.905


## Nozzle Diameter D n 

### inches 

### 0.243 0.243 0.243

- 

## Meter Volume V m 

### dcf 

### 149.195 157.492 151.328 152.672 

## Meter Temperature t m o 

### F 

### 67.4 81.0 69.8 72.7 

## Avg. Orifice Delta H  H in. H 2 

### 0 

### 1.34 1.47 1.37 1.39 

## Impingers Weight Gain (Moisture) W imp 

### grams 

### 587.5 586.8 596.2 590.2 

## Silica Gel Impinger Weight Gain (Moisture) W sg 

### grams 

### 40.4 36.4 42.6 39.8 

## Oxygen Concentration, % (dry basis) O 2 

### % 

### 18.5 18.6 19.3 18.80 

## Carbon Dioxide Concentration, % (dry basis) CO 2 

### % 

### 1.2 1.1 1.1 1.14 

## Avg. Sq. Rt. of Delta P sqrt  P 

### in. H20 1/2 

### 0.754 0.781 0.764 0.766 

## Stack Temperature t s o 

### F 

### 215.1 215.6 214.8 215.2 

## 2, 3, 7, 8 - TCDD pg 

### 4.1 4.7 3.0 3.9 

## 1, 2, 3, 7, 8 - PeCDD pg 

### 1.2 1.5 1.2 1.3 

## 1, 2, 3, 4, 7, 8 - HxCDD pg 

### 1.9 1.4 1.3 1.5 

## 1, 2, 3, 6, 7, 8 - HxCDD pg 

### 1.7 1.2 1.2 1.4 

## 1, 2, 3, 7, 8, 9 - HxCDD pg 

### 1.8 1.3 1.3 1.5 

## 1, 2, 3, 4, 6, 7, 8 - HpCDD pg 

### 5.5 3.9 3.0 4.1


## OCDD pg 

### 59 71 44 57.8 

## 2, 3, 7, 8 - TCDF pg 

### 1.4 1.8 2.0 1.7 

## 1, 2, 3, 7, 8 - PeCDF pg 

### 0.84 1.10 0.92 0.95 

## 2, 3, 4, 7, 8 - PeCDF pg 

### 0.87 1.10 0.9 0.96 

## 210269
Chuck Duncan IV Job No.: American Marazzi Tile, Inc 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

# INPUT DATA

Run Number 

## Field Data Data Input By:

## Client:
Source: Spray Dryer 3 (SD-3) 

## Symbol Units Test Data QC'd by Keith Poole



### - - 

### 1 2 3A V E R A G E


## Test Date

- - 

### 12/02/10 12/02/10 12/03/10 All Runs 

## 210269
Chuck Duncan IV Job No.: American Marazzi Tile, Inc 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

# INPUT DATA

Run Number 

## Field Data Data Input By:

1, 2, 3, 4, 7, 8 - HxCDF pg 

### 0.74 0.97 0.57 0.76 

## 1, 2, 3, 6, 7, 8 - HxCDF pg 

### 0.66 0.87 0.51 0.68 

## 2, 3, 4, 6, 7, 8 - HxCDF pg 

### 0.70 0.92 0.54 0.72 

## 1, 2, 3, 7, 8, 9 - HxCDF pg 

### 0.81 1.10 0.62 0.84 

## 1, 2, 3, 4, 6, 7, 8 - HpCDF pg 

### 0.85 0.94 1.10 0.96 

## 1, 2, 3, 4, 7, 8, 9 - HpCDF pg 

### 1.0 0.81 0.86 0.9


## OCDF pg 

### 1.6 2.1 0.9 1.6


## Other - TCDD pg 

### 29.8 29.6 3.6 21.0


## Other - PeCDD pg 

### 4.8 3.2 1.7 3.2


## Other - HxCDD pg 

### 3.2 1.8 2.0 2.3 

## Other - HpCDD pg 

### 5.0 1.3 4.9 3.8


## Other - TCDF pg 

### 1.4 1.8 2.0 1.7


## Other - PeCDF pg 

### 2.28 1.10 0.92 1.43


## Other - HxCDF pg 

### 0.81 1.10 0.62 0.84 

## Other - HpCDF pg 

### 1.0 0.81 0.9 0.9


## Total Dioxans pg 

### 117.6 120.7 23.2 87.2 

## Total Furans pg 

### 15.0 16.5 13.4 15.0 

## Total Dioxans and Furans pg 

### 132.5 137.3 36.6 102.1
Indicates values below the detection limit (BDL).

### Client: Source: Spray Dryer 3 (SD-3) Formulas Symbol Units 

### Calculated Data QC'd by Keith Poole 

### Run Numbers

- - 1 2 3 AVERAGE 

### Test Date(s)

- - 12/02/10 12/02/10 12/03/10 All Runs 

### Times, Pollutant Runs (Began - Ended)

- Military Time 0821-1229 1422-1829 0802-1207 - 

### 1. Stack Pressure = Pbar + Pg / 13.6 Ps in. Hg 29.72 29.72 30.04 29.83 

### 2. Meter Pressure = Pbar + DH / 13.6 Pm in. Hg 29.85 29.86 30.17 29.96 

### 3. Standard Meter Volume = 17.64* Y* (Vm/Tm)* (Pbar + DH / 13.6) Vm(std) dscf 150.503 154.933 153.591 153.009 

### 4a. Standard Volume of Water Vapor Condensed =0.04706*Wimp Vwc(std) scf 27.648 27.615 28.057 27.773 

### 4b. Standard Volume of Water Collected in Silica Gel =0.04715*Wsg Vwsg(std) scf 1.905 1.716 2.009 1.877 

### 5. Moisture Fraction =(Vwc(std) + Vwsg(std))/(Vwc(std) + Vwsg(std) + Vm(std)) Bws fraction 0.1641 0.1592 0.1637 0.1623 

### 6. Moisture Fraction @ Saturation (Theoretical) =10[6.6911-(3144/(ts+390.86)]/Ps TBws fraction 1.0000 1.0000 1.0000 1.0000 

### 7. Standard Water Volume @ Saturation (Theoretical) =Vm(std) * (TBws)/(1-TBws) TVW(std) scf 150.50 154.93 153.59 153.01 

### 8. Volume of Water @ Saturation (Theoretical) =TVw(std)/0.04707 TVlc ml 3197.4 3291.6 3263.0 3250.7 

### 9. Molecular Weight of Stack Gas (dry) = 0.32*(O2)+ 0.44*(CO2)+0.28*(100-(O2)-(CO2)) Md lb / lb-mole 28.932 28.922 28.948 28.934 

### 10. Molecular Weight of Stack Gas (wet) = Md*(1-Bws)+18.0*(Bws) Ms lb / lb-mole 27.138 27.183 27.156 27.159 

### 11. Average Stack Gas Velocity = 85.49*Cp*(sqrt DP)avg*SQRT((Ts) / (Ps*Mw)) vs ft / s 49.555 51.28 49.92 50.25 

### 12. Stack Gas Flow @ Actual Conditions = 60*vs*As Qa acfm 83,486 86,387 84,107 84,660 

### 13. Stack Gas Flow @ Standard Conditions = Qa*(Tstd/Ts)*(Ps/Pstd) Qs scfm 64,831 67,034 66,050 65,972 

### 14. Stack Gas Flow @ Dry Standard Conditions = Qa*(1-Bws)*(Tstd/Ts)*(Ps/Pstd) Qstd dscfm 54,190 56,364 55,237 55,264 

### 15 2 3 7 8 TCDD C t ti *( / 12 )/ ( ) C /d f 4 20E 13 4 68E 13 3 01E 13 3 97E 13 

# ENTEC Services, Inc.
30 Monroe Drive, Pelham, AL 35124 

## CALCULATED TEST DATA - English Units

Description 

### Data Input By: Chuck Duncan IV Job No.: 210269 American Marazzi Tile, Inc

15 a. 2 , 3 , 7 , 8 - TCDD C oncen t ra ti ons =15.43 *( m n / 10e 12 )/ Vm ( std ) C s gr / d sc f 4

. 20E

- 13 4

. 68E

- 13 3

. 01E

- 13 3

. 97E

- 13 

### 15b. 1, 2, 3, 7, 8 - PeCDD C oncentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.23E-13 1.49E-13 1.21E-13 1.31E-13 

### 15c. 1, 2, 3, 4, 7, 8 - HxCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.95E-13 1.39E-13 1.31E-13 1.55E-13 

### 15d. 1, 2, 3, 6, 7, 8 - HxCDD C oncentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.74E-13 1.20E-13 1.21E-13 1.38E-13 

### 15e. 1, 2, 3, 7, 8, 9 - HxCDD C oncentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.85E-13 1.29E-13 1.31E-13 1.48E-13 

### 15f. 1, 2, 3, 4, 6, 7, 8 - HpCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 5.62E-13 3.88E-13 3.01E-13 4.17E-13 

### 15g. OCDD C oncentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 6.01E-12 7.06E-12 4.40E-12 5.82E-12 

### 15h. 2, 3, 7, 8 - TCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.44E-13 1.79E-13 2.01E-13 1.75E-13 

### 15i. 1, 2, 3, 7, 8 - PeCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 8.61E-14 1.10E-13 9.24E-14 9.60E-14 

### 15j. 2, 3, 4, 7, 8 - PeCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 8.92E-14 1.10E-13 9.04E-14 9.64E-14 

### 15k. 1, 2, 3, 4, 7, 8 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.59E-14 9.66E-14 5.73E-14 7.66E-14 

### 15l. 1, 2, 3, 6, 7, 8 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 6.77E-14 8.66E-14 5.12E-14 6.85E-14 

### 15m. 2, 3, 4, 6, 7, 8 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.18E-14 9.16E-14 5.42E-14 7.25E-14 

### 15n. 1, 2, 3, 7, 8, 9 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 8.30E-14 1.10E-13 6.23E-14 8.50E-14 

### 15o. 1, 2, 3, 4, 6, 7, 8 - HpCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 8.71E-14 9.36E-14 1.11E-13 9.71E-14 

### 15p. 1, 2, 3, 4, 7, 8, 9 - HpCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.03E-13 8.07E-14 8.64E-14 8.99E-14 

### 15q. OCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.64E-13 2.11E-13 9.34E-14 1.56E-13 

### 15r. Other - TCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 3.06E-12 2.95E-12 3.58E-13 2.12E-12 

### 15s. Other - PeCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 4.88E-13 3.14E-13 1.69E-13 3.23E-13 

### 15t. Other - HxCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 3.29E-13 1.75E-13 2.04E-13 2.36E-13 

### 15u. Other - HpCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 5.15E-13 1.29E-13 4.95E-13 3.80E-13 

### 15v. Other - TCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.44E-13 1.79E-13 2.01E-13 1.75E-13

### Client: Source: Spray Dryer 3 (SD-3) Formulas Symbol Units 

### Calculated Data QC'd by Keith Poole 

### Run Numbers

- - 1 2 3 AVERAGE 

### Test Date(s)

- - 12/02/10 12/02/10 12/03/10 All Runs 

### Times, Pollutant Runs (Began - Ended)

- Military Time 0821-1229 1422-1829 0802-1207 - 

# ENTEC Services, Inc.
30 Monroe Drive, Pelham, AL 35124 

## CALCULATED TEST DATA - English Units

Description 

### Data Input By: Chuck Duncan IV Job No.: 210269 American Marazzi Tile, Inc

15w. Other - PeCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 2.34E-13 1.10E-13 9.24E-14 1.45E-13 

### 15x. Other - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 8.30E-14 1.10E-13 6.23E-14 8.50E-14 

### 15y. Other - HpCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.03E-13 8.07E-14 8.64E-14 8.99E-14 

### 15z. Total Dioxans Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.21E-11 1.20E-11 2.33E-12 8.80E-12 

### 15aa. Total Furans Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.53E-12 1.65E-12 1.34E-12 1.51E-12 

### 15ab. Total Dioxans and Furans Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.36E-11 1.37E-11 3.67E-12 1.03E-11 

### 20a. 2, 3, 7, 8 - TCDD concent ration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 2.43E-12 2.83E-12 2.62E-12 2.63E-12 

### 20b. 1, 2, 3, 7, 8 - PeCDD c oncentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 7.13E-13 9.03E-13 1.05E-12 8.88E-13 

### 20c. 1, 2, 3, 4, 7, 8 - HxCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.13E-12 8.43E-13 1.13E-12 1.04E-12 

### 20d. 1, 2, 3, 6, 7, 8 - HxCDD concentrati on adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.01E-12 7.22E-13 1.05E-12 9.26E-13 

### 20e. 1, 2, 3, 7, 8, 9 - HxCDD concentrati on adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.07E-12 7.82E-13 1.13E-12 9.95E-13 

### 20f. 1, 2, 3, 4, 6, 7, 8 - HpCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 3.25E-12 2.35E-12 2.62E-12 2.74E-12 

### 20g. OCDD c oncentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 3.48E-11 4.27E-11 3.82E-11 3.86E-11 

### 20h. 2, 3, 7, 8 - TCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 8.31E-13 1.08E-12 1.75E-12 1.22E-12 

### 20i. 1, 2, 3, 7, 8 - PeCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.99E-13 6.62E-13 8.03E-13 6.55E-13 

### 20j 2 3 4 7 8 P CDF t ti dj t d t 7% O2 C * ((20 9 7)/(20 9 %O2)) /d f 5 17E 13 6 62E 13 7 85E 13 6 55E 13 

### 20j

. 2 , 3 , 4 , 7 , 8 - P e CDF concen t ra ti on a dj us t e d t o 7% O2 = C s * ((20

. 9
- 7)/(20

. 9
- %O2)) c %O2 gr sc c 5

. 17E

- 13 6

. 62E

- 13 7

. 85E

- 13 6

. 55E

- 13 

### 20k. 1, 2, 3, 4, 7, 8 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.39E-13 5.84E-13 4.97E-13 5.07E-13 

### 20l. 1, 2, 3, 6, 7, 8 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 3.92E-13 5.24E-13 4.45E-13 4.54E-13 

### 20m. 2, 3, 4, 6, 7, 8 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.16E-13 5.54E-13 4.71E-13 4.80E-13 

### 20n. 1, 2, 3, 7, 8, 9 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.81E-13 6.62E-13 5.41E-13 5.61E-13 

### 20o. 1, 2, 3, 4, 6, 7, 8 - HpCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.05E-13 5.66E-13 9.60E-13 6.77E-13 

### 20p. 1, 2, 3, 4, 7, 8, 9 - HpCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.94E-13 4.88E-13 7.51E-13 6.11E-13 

### 20q. OCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 9.50E-13 1.28E-12 8.12E-13 1.01E-12 

### 20r. Other - TCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.77E-11 1.78E-11 3.11E-12 1.29E-11 

### 20s. Other - PeCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 2.83E-12 1.90E-12 1.47E-12 2.06E-12 

### 20t. Other - HxCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.91E-12 1.06E-12 1.77E-12 1.58E-12 

### 20u. Other - HpCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 2.98E-12 7.82E-13 4.30E-12 2.69E-12 

### 20v. Other - TCDF concent ration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 8.31E-13 1.08E-12 1.75E-12 1.22E-12 

### 20w. Other - PeCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.35E-12 6.62E-13 8.03E-13 9.40E-13 

### 20x. Other - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.81E-13 6.62E-13 5.41E-13 5.61E-13 

### 20y. Other - HpCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.94E-13 4.88E-13 7.51E-13 6.11E-13 

### 20z. Total Dioxans concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 6.98E-11 7.27E-11 2.02E-11 5.42E-11


### 20aa. Total Furans concent ration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 8.88E-12 9.96E-12 1.17E-11 1.02E-11 

### 20ab. Total Dioxans and Furans concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 7.87E-11 8.26E-11 3.19E-11 6.44E-11 

### 21a. 2, 3, 7, 8 - TCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.95E-10 2.26E-10 1.43E-10 1.88E-10 

### 21b. 1, 2, 3, 7, 8 - PeCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 5.71E-11 7.22E-11 5.71E-11 6.21E-11 

### 21c. 1, 2, 3, 4, 7, 8 - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 9.05E-11 6.74E-11 6.18E-11 7.32E-11

### Client: Source: Spray Dryer 3 (SD-3) Formulas Symbol Units 

### Calculated Data QC'd by Keith Poole 

### Run Numbers

- - 1 2 3 AVERAGE 

### Test Date(s)

- - 12/02/10 12/02/10 12/03/10 All Runs 

### Times, Pollutant Runs (Began - Ended)

- Military Time 0821-1229 1422-1829 0802-1207 - 

# ENTEC Services, Inc.
30 Monroe Drive, Pelham, AL 35124 

## CALCULATED TEST DATA - English Units

Description 

### Data Input By: Chuck Duncan IV Job No.: 210269 American Marazzi Tile, Inc

21d. 1, 2, 3, 6, 7, 8 - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 8.10E-11 5.77E-11 5.71E-11 6.53E-11 

### 21e. 1, 2, 3, 7, 8, 9 - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 8.57E-11 6.25E-11 6.18E-11 7.00E-11 

### 21f. 1, 2, 3, 4, 6, 7, 8 - HpCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 2.61E-10 1.88E-10 1.43E-10 1.97E-10 

### 21g. OCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 2.79E-09 3.41E-09 2.08E-09 2.76E-09 

### 21h. 2, 3, 7, 8 - TCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 6.67E-11 8.66E-11 9.51E-11 8.28E-11 

### 21i. 1, 2, 3, 7, 8 - PeCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 4.00E-11 5.29E-11 4.38E-11 4.56E-11 

### 21j. 2, 3, 4, 7, 8 - PeCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 4.14E-11 5.29E-11 4.28E-11 4.57E-11 

### 21k. 1, 2, 3, 4, 7, 8 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.52E-11 4.67E-11 2.71E-11 3.63E-11 

### 21l. 1, 2, 3, 6, 7, 8 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.14E-11 4.19E-11 2.43E-11 3.25E-11 

### 21m. 2, 3, 4, 6, 7, 8 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.33E-11 4.43E-11 2.57E-11 3.44E-11 

### 21n. 1, 2, 3, 7, 8, 9 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.86E-11 5.29E-11 2.95E-11 4.03E-11 

### 21o. 1, 2, 3, 4, 6, 7, 8 - HpCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 4.05E-11 4.52E-11 5.23E-11 4.60E-11 

### 21p. 1, 2, 3, 4, 7, 8, 9 - HpCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 4.76E-11 3.90E-11 4.09E-11 4.25E-11 

### 21q. OCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 7.62E-11 1.02E-10 4.42E-11 7.41E-11 

### 21r. Other - TCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.42E-09 1.42E-09 1.69E-10 1.00E-09 

### 21 Oth P CDD M E i i (60/7000)* *Q d PMR lb / h 2 27E 10 1 52E 10 7 99E 11 1 53E 10 

### 21 s. Oth er - P e CDD M ass E m i ss i ons = (60/7000)* cs *Q s d s r 2

. 27E

- 10 1

. 52E

- 10 7

. 99E

- 11 1

. 53E

- 10 

### 21t. Other - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.53E-10 8.47E-11 9.66E-11 1.11E-10 

### 21u. Other - HpCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 2.39E-10 6.25E-11 2.34E-10 1.79E-10 

### 21v. Other - TCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 6.67E-11 8.66E-11 9.51E-11 8.28E-11 

### 21w. Other - PeCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.09E-10 5.29E-11 4.38E-11 6.84E-11 

### 21x. Other - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.86E-11 5.29E-11 2.95E-11 4.03E-11 

### 21y. Other - HpCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 4.76E-11 3.90E-11 4.09E-11 4.25E-11


### 21z. Total Dioxans Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 5.60E-09 5.81E-09 1.10E-09 4.17E-09


### 21aa. Total Furans Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 7.12E-10 7.96E-10 6.35E-10 7.14E-10


### 21ab. Total Dioxans and Furans Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 6.31E-09 6.60E-09 1.74E-09 4.88E-09 

### 22. Volume collected through nozzle =Ts/Ps*[0.002669*Vlc+ Vm*Y*Pm/Tm] Vn acf 231.800 237.393 233.801 234.331 

### 23. Particulate Matter (FH Filterable PM Conc., actual cond.) =0.01543*mn/Vn ca gr / acf 0.00000 0.00000 0.00000 0.00000 

### 24. Isokinetic Sampling Rate, Percent = 100*Vn / (60*vs*An*q) I % 100.86 99.83 100.98 100.56


### Post Meter Orifice Cal. (EMC ALT-009 Yqa) y qa 1.0122 1.0173 1.0093 1.013 

### % Difference , ( Calibration must be within 5% of ori g inal Y-factor ) -0.29% Indicates values below the detection limit (BDL).

### Client:
Source: Roller Kiln 5 Upper Channel (RK-5U) 

### Symbol Units Test Data QC'd by Keith Poole

- - 1 2 3A V E R A G E


### Test Date

- - 12/06/10 12/07/10 12/07/10 All Runs 

### Times, Pollutant Runs (Began - Ended) - Military Time 1000-1410 0737-1151 1255-1701 - 

### Sampling Time  minutes 240 240 240 240 

### Stack Area A s Ft 2 8.51 8.51 8.51

- 

### Barometric Pressure P bar in. Hg 29.75 30.08 30.08 29.998 

### Stack Static Pressure P g in. H 2 0 -0.42 -0.52 -0.51 -0.49 

### Pitot Tube Correction factor C p - 0.84 0.84 0.84

- 

### Meter Correction Factor Y - 1.002 1.002 1.002 - 

### Meter Delta H @  H@ in. H 2 0 1.878 1.878 1.878 1.878


### Nozzle Diameter D n inches 0.215 0.240 0.240 -


### Meter Volume V m dcf 135.062 174.487 181.913 163.821 

### Meter Temperature t m o F 56.8 57.6 73.1 62.5 

### Avg. Orifice Delta H  H in. H 2 0 1.11 1.77 1.85 1.58 

### Impingers Weight Gain (Moisture) W imp grams 69.2 103.0 94.0 88.7 

### Silica Gel Impinger Weight Gain (Moisture) W sg grams 20.8 30.4 34.0 28.4 

### Oxygen Concentration, % (dry basis) O 2 % 19.30 19.27 19.01 19.19 

### Carbon Dioxide Concentration, % (dry basis) CO 2 % 0.87 0.92 1.01 0.93 

### Avg. Sq. Rt. of Delta P sqrt  P in. H20 1/2 0.848 0.837 0.856 0.847 

### Stack Temperature t s o F 231.8 224.5 236.8 231.1 

### Particulate Matter Mass (FH Filterable PM) m n mg 8.6 17.4 14.5 13.5

M Sb μg 0.55 0.52 0.86 0.64

M As μg 27.0 48.9 38.9 38.2

M Be μg 0.3 0.3 0.3 0.3

M Cd μg 0.73 0.69 0.94 0.79

M Cr μg 33.1 48.2 46.5 42.6

M Co μg 0.46 0.41 0.47 0.45

M Pb μg 22.2 26.0 25.9 24.7

M Mn μg 8.24 4.81 5.27 6.11

M Hg μg 18.8 41.9 31.3 30.7

M Ni μg 6.76 4.06 4.72 5.18

Mse μg 933 1647 1419 1333

μg 1,050.8 1,823.0 1,574.5 1482.75
*Beryllium was not detected on this source. The number above repr esents the summation of the detection limits. 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

## INPUT DATA

Antimony (Sb) Arsenic (As) Run Number 

### Field Data Data Input By: 210269 Kevin Rosenberg Job No.: American Marazzi Tile, Inc.



### Beryllium (Be)*

Total Metals collected Selenium (Se) Mercury (Hg) Nickel (Ni) Cadmium (Cd) Chromium (Cr, total)

Lead (Pb) Manganese (Mn) Cobalt (Co)Client:Source:Roller Kiln 5 Upper Channel (RK-5U)FormulasSymbol UnitsCalculated DataQC'd by Keith PooleRun Number- -1 23AVERAGETest Date- -12/06/10 12/07/10 12/07/10 All RunsTimes, Pollutant Runs (Began - Ended)- Military Time1000-1410 0737-1151 1255-1701 -1. Stack Pressure= Ps*25.4Psmm. Hg754.9 763.1 763.1 760.32. Meter Pressure= Pm*25.4Pmmm. Hg757.7 767.3 767.5 764.23. Standard Meter Volume=Vm(std) * 0.02831685Vm(std)dscm3.904 5.099 5.163 4.7224a. Standard Volume of Water Vapor Condensed=0.04706*WimpVwc(std)scm0.092 0.137 0.125 0.1184b. Standard Volume of Water Collected in Silica Gel=0.04715*WsgVwsg(std)scm0.028 0.041 0.045 0.0385. Moisture Fraction=(Vwc(std) + Vwsg(std))/(Vwc(std) + Vwsg(std) + Vm(std))Bwsfraction0.0298 0.0337 0.0320 0.03189. Molecular Weight of Stack Gas (dry)= 0.32*(O2)+ 0.44*(CO2)+0.28*(100-(O2)-(CO2))Mdg / g-mole28.91 28.92 28.92 28.9210. Molecular Weight of Stack Gas (wet)= Md*(1-Bws)+18.0*(Bws)Msg / g-mole28.59 28.55 28.57 28.5711. Average Stack Gas Velocity= 85.49*Cp*(sqrt DP)avg*SQRT((Ts) / (Ps*Mw))vsm / s16.75 16.36 16.87 16.6612. Stack Gas Flow @ Actual Conditions= vs*AsQaacmm795 776 800 79013. Stack Gas Flow @ Standard Condition= Qa*(Tstd/Ts)*(Ps/Pstd)Qsscmm602 601 609 60414. Stack Gas Flow @ Dry Standard Condition= Qa*(1-Bws)*(Tstd/Ts)*(Ps/Pstd)Qstd, ddscmm585 581 589 58515. Particulate Matter (FH Filterable PM Conc. @ STP)=mn/Vm(std)csmg / dscm2.20 3.41 2.81 2.8115. Antimony Conc. @ STP=0.001*mn/Vm(std)cSbmg / dscm1.40E-04 1.01E-04 1.67E-04 1.36E-0415. Arsenic Conc. @ STP=0.001*mn/Vm(std)cAsmg / dscm6.91E-03 9.58E-03 7.54E-03 8.01E-0315. Beryllium Conc. @ STP=0.001*mn/Vm(std)cBemg / dscm7.68E-05 5.88E-05 5.81E-05 6.46E-0515. Cadmium Conc. @ STP=0.001*mn/Vm(std)cCdmg / dscm1.86E-04 1.35E-04 1.82E-04 1.68E-0415. Chromium Conc. @ STP=0.001*mn/Vm(std)cCrmg / dscm8.47E-03 9.46E-03 9.00E-03 8.98E-0315. Cobalt Conc. @ STP=0.001*mn/Vm(std)cComg / dscm1.18E-04 8.04E-05 9.03E-05 9.62E-0515. Lead Conc. @ STP=0.001*mn/Vm(std)cPbmg / dscm5.68E-03 5.10E-03 5.01E-03 5.26E-0315. Manganese Conc. @ STP=0.001*mn/Vm(std)cMnmg / dscm2.11E-03 9.43E-04 1.02E-03 1.36E-0315. Mercury Conc. @ STP=0.001*mn/Vm(std)cHgmg / dscm4.82E-03 8.21E-03 6.07E-03 6.37E-0315. Nickel Conc. @ STP=0.001*mn/Vm(std)cNimg / dscm1.73E-03 7.96E-04 9.14E-04 1.15E-0315. Selenium Conc. @ STP=0.001*mn/Vm(std)cSemg / dscm2.39E-01 3.23E-01 2.75E-01 2.79E-0115.Total Metals Conc. @ STP=0.001*mn/Vm(std)cTSMmg / dscm0.2692 0.3575 0.3050 0.310515. Particulate Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cs7mg / dscmc1.91E+01 2.91E+01 2.07E+01 2.30E+0115. Antimony Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cSbmg / dscmc0.0012 0.0009 0.0012 1.10E-0315. Arsenic Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cAsmg / dscmc0.0600 0.0817 0.0554 6.57E-0215. Beryllium Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cBemg / dscmc0.0007 0.0005 0.0004 5.32E-0415. Cadmium Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cCdmg / dscmc0.0016 0.0012 0.0013 1.37E-03DescriptionKevin RosenbergCALCULATED TEST DATA - Metric UnitsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124210269American Marazzi Tile, Inc.Data Input By:Job No.:Client:Source:Roller Kiln 5 Upper Channel (RK-5U)FormulasSymbol UnitsCalculated DataQC'd by Keith PooleRun Number- -1 23AVERAGETest Date- -12/06/10 12/07/10 12/07/10 All RunsDescriptionKevin RosenbergCALCULATED TEST DATA - Metric UnitsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124210269American Marazzi Tile, Inc.Data Input By:Job No.:15. Chromium Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cCrmg / dscmc0.0736 0.0806 0.0662 7.35E-0215. Cobalt Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cComg / dscmc0.0010 0.0007 0.0007 7.92E-0415. Lead Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cPbmg / dscmc0.0493 0.0435 0.0369 4.32E-0215. Manganese Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cMnmg / dscmc0.0183 0.0080 0.0075 1.13E-0215. Mercury Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cHgmg / dscmc0.0419 0.0700 0.0446 5.22E-0215. Nickel Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cNimg / dscmc0.0150 0.0068 0.0067 9.52E-0315. Selenium Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cSemg / dscmc2.0755 2.7547 2.0218 2.28E+0015.Total Metals Conc. @ 7% Oxygen=Cs * ((20.9-7)/(20.9-%O2))cTSMmg / dscmc2.3382 3.0486 2.2428 2.54E+0021. Particulate Emissions= (0.000001)*cs*QsdPMRkg / hr0.0773 0.1189 0.0993 0.098517. Antimony Emissions= (0.000001)*CSb*QsdSb-kg/hrkg / hr4.905E-06 3.519E-06 5.898E-06 4.774E-0617. Arsenic Emissions= (0.000001)*CAs*QsdAs-kg/hrkg / hr2.423E-04 3.338E-04 2.666E-04 0.0002817. Beryllium Emissions= (0.000001)*CBe*QsdBe-kg/hrkg / hr2.695E-06 2.050E-06 2.055E-06 0.00000217. Cadmium Emissions= (0.000001)*CCd*QsdCd-kg/hrkg / hr6.540E-06 4.701E-06 6.433E-06 0.00000617. Chromium Emissions= (0.000001)*CCr*QsdCr-kg/hrkg / hr2.972E-04 3.294E-04 3.183E-04 0.0003117. Cobalt Emissions= (0.000001)*CCo*QsdCo-kg/hrkg / hr4.141E-06 2.801E-06 3.192E-06 0.0000017. Lead Emissions= (0.000001)*CPb*QsdPb-kg/hrkg / hr1.992E-04 1.775E-04 1.773E-04 0.0001817. Manganese Emissions= (0.000001)*CMn*QsdMn-kg/hrkg / hr7.402E-05 3.286E-05 3.610E-05 0.0000517. Mercury Emissions= (0.000001)*CHg*QsdHg-kg/hrkg / hr1.691E-04 2.861E-04 2.147E-04 0.0002217. Nickel Emissions= (0.000001)*CNi*QsdNi-kg/hrkg / hr6.073E-05 2.774E-05 3.233E-05 0.0000417. Selenium Emissions= (0.000001)*CSe*QsdSe-kg/hrkg / hr8.379E-03 1.125E-02 9.723E-03 0.0097917. Total Metals Emissions= (0.000001)*CTSM*QsdTSM-kg/hrkg / hr0.00944 0.01246 0.01079 0.0108922. Volume collected through nozzle=Ts/Ps*[0.002669*Vlc+ Vm*Y*Pm/Tm]Vnacm5.308 6.814 7.010 6.37824. Isokinetic Sampling Rate, Percent= 100*Vn / (60*vs*An*q)I%93.93 99.12 98.85 97.30Post Meter Orifice Cal. (EMC ALT-009 Yqa)yqa1.0172 0.9886 0.9831 0.996% Difference, (Calibration must be within 5% of original Y-factor)0.57%Beryllium was not detected in any of the three samples. Results are calculated at the detection limit.

## Client:
Source: Roller Kiln 5 Upper Channel (RK-5U) 

## Symbol Units Test Data QC'd by Keith Poole



### - - 

### 1 2 3A V E R A G E


## Test Date

- - 

### 12/06/10 12/07/10 12/07/10 All Runs 

## Times, Pollutant Runs (Began - Ended) - Military Time 

### 1000-1411 0739-1153 1257-1700

- 

## Sampling Time  minutes 

### 240 240 240 240 

## Stack Area A s 

### Ft 2 

### 8.51 8.51 8.51

- 

## Barometric Pressure P bar 

### in. Hg 

### 29.75 30.08 30.08 29.998 

## Stack Static Pressure P g 

### in. H 2 

### 0 

### -0.42 -0.51 -0.51 -0.49 

## Pitot Tube Correction factor C p 

### - 

### 0.84 0.84 0.84

- 

## Meter Correction Factor Y - 

### 0.977 0.977 0.977

- 

## Meter Delta H @  H@ in. H 2 

### 0 

### 1.725 1.725 1.725 1.725


## Nozzle Diameter D n 

### inches 

### 0.235 0.235 0.235

- 

## Meter Volume V m 

### dcf 

### 165.079 173.963 172.930 170.657 

## Meter Temperature t m o 

### F 

### 56.0 52.3 65.5 57.9 

## Avg. Orifice Delta H  H in. H 2 

### 0 

### 1.45 1.63 1.57 1.55 

## Impingers Weight Gain (Moisture) W imp 

### grams 

### 66.5 86.2 83.4 78.7 

## Silica Gel Impinger Weight Gain (Moisture) W sg 

### grams 

### 34.1 36.3 39.4 36.6 

## Oxygen Concentration, % (dry basis) O 2 

### % 

### 19.30 19.27 19.01 19.19 

## Carbon Dioxide Concentration, % (dry basis) CO 2 

### % 

### 0.87 0.92 1.01 0.93 

## Avg. Sq. Rt. of Delta P sqrt  P 

### in. H20 1/2 

### 0.838 0.841 0.827 0.835 

## Stack Temperature t s o 

### F 

### 232.4 226.4 237.4 232.1 

## 2, 3, 7, 8 - TCDD pg 

### 160.0 208.0 199.0 189.0 

## 1, 2, 3, 7, 8 - PeCDD pg 

### 258.0 332.0 348.0 312.7 

## 1, 2, 3, 4, 7, 8 - HxCDD pg 

### 119.0 144.0 141.0 134.7 

## 1, 2, 3, 6, 7, 8 - HxCDD pg 

### 220.0 267.0 236.0 241.0 

## 1, 2, 3, 7, 8, 9 - HxCDD pg 

### 478.0 639.0 561.0 559.3 

## 1, 2, 3, 4, 6, 7, 8 - HpCDD pg 

### 2,780.0 3,940.0 3,280.0 3333.3


## OCDD pg 

### 40,500 57,600 53,100 50400.0 

## 2, 3, 7, 8 - TCDF pg 

### 45.8 67.9 61.2 58.3 

## 1, 2, 3, 7, 8 - PeCDF pg 

### 8.88 12.50 12.20 11.19 

## 2, 3, 4, 7, 8 - PeCDF pg 

### 38.40 44.90 41.7 41.67 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

# INPUT DATA

Run Number 

## Field Data Data Input By: 210269 Kevin Rosenberg Job No.: American Marazzi Tile, Inc.

## Client:
Source: Roller Kiln 5 Upper Channel (RK-5U) 

## Symbol Units Test Data QC'd by Keith Poole



### - - 

### 1 2 3A V E R A G E


## Test Date

- - 

### 12/06/10 12/07/10 12/07/10 All Runs 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

# INPUT DATA

Run Number 

## Field Data Data Input By: 210269 Kevin Rosenberg Job No.: American Marazzi Tile, Inc.



## 1, 2, 3, 4, 7, 8 - HxCDF pg 

### 9.03 10.90 12.00 10.64 

## 1, 2, 3, 6, 7, 8 - HxCDF pg 

### 4.80 5.30 5.93 5.34 

## 2, 3, 4, 6, 7, 8 - HxCDF pg 

### 7.30 8.66 9.75 8.57 

## 1, 2, 3, 7, 8, 9 - HxCDF pg 

### 1.00 1.70 2.11 1.60 

## 1, 2, 3, 4, 6, 7, 8 - HpCDF pg 

### 5.60 8.00 6.64 6.75 

## 1, 2, 3, 4, 7, 8, 9 - HpCDF pg 

### 1.2 1.70 2.20 1.7


## OCDF pg 

### 10.2 13.1 15.9 13.1


## Other - TCDD pg 

### 1,620.0 1,922.0 1,761.0 1767.7


## Other - PeCDD pg 

### 3,312.0 4,048.0 3,642.0 3667.3


## Other - HxCDD pg 

### 4,713.0 6,080.0 5,352.0 5381.7 

## Other - HpCDD pg 

### 4,050.0 5,540.0 4,950.0 4846.7


## Other - TCDF pg 

### 191.2 272.1 270.8 244.7


## Other - PeCDF pg 

### 102.72 111.60 124.10 112.81


## Other - HxCDF pg 

### 34.07 30.84 43.31 36.07 

## Other - HpCDF pg 

### 0.9 4.73 4.3 3.3 

## Total Target Analytes Dibenzo-p-dioxins pg 

### 58,210 80,720 73,570 70,833 

## Total Target Analytes Dibenzofurans pg 

### 461 594 612 556 

### Total Target Analytes Dibenzo-p-dioxins and Dibenzofurans pg 

### 58,671 81,314 74,182 71,389 Indicates values below the detection limit (BDL).Client:Source:Roller Kiln 5 Upper Channel (RK-5U)Formulas Symbol UnitsCalculated DataQC'd by Keith PooleRun Numbers- -123 AVERAGETest Date(s)-- 12/06/10 12/07/10 12/07/10 All RunsTimes, Pollutant Runs (Began - Ended)-Military Time 1000-1411 0739-1153 1257-1700 -1. Stack Pressure= Pbar + Pg / 13.6Psin. Hg 29.72 30.04 30.04 29.932. Meter Pressure= Pbar + DH / 13.6Pmin. Hg 29.86 30.20 30.20 30.083. Standard Meter Volume= 17.64* Y* (Vm/Tm)* (Pbar + DH / 13.6)Vm(std)dscf 164.697 176.813 171.305 170.9384a. Standard Volume of Water Vapor Condensed=0.04706*WimpVwc(std)scf 3.129 4.057 3.925 3.7044b. Standard Volume of Water Collected in Silica Gel=0.04715*WsgVwsg(std)scf 1.608 1.712 1.858 1.7265. Moisture Fraction=(Vwc(std) + Vwsg(std))/(Vwc(std) + Vwsg(std) + Vm(std))Bwsfraction 0.0280 0.0316 0.0327 0.03079. Molecular Weight of Stack Gas (dry)= 0.32*(O2)+ 0.44*(CO2)+0.28*(100-(O2)-(CO2))Mdg / g-mole 28.911 28.918 28.922 28.91710. Molecular Weight of Stack Gas (wet)= Md*(1-Bws)+18.0*(Bws)Msg / g-mole 28.606 28.573 28.565 28.58211. Average Stack Gas Velocity= 85.49*Cp*(sqrt DP)avg*SQRT((Ts) / (Ps*Mw))vsft / s 54.296 54.03 53.52 53.9512. Stack Gas Flow @ Actual Conditions= 60*vs*AsQaacfm 27,723 27,586 27,325 27,54513. Stack Gas Flow @ Standard Conditions= Qa*(Tstd/Ts)*(Ps/Pstd)Qsscfm 20,990 21,298 20,764 21,01714. Stack Gas Flow @ Dry Standard Conditions= Qa*(1-Bws)*(Tstd/Ts)*(Ps/Pstd)Qstddscfm 20,403 20,625 20,086 20,37115a. 2, 3, 7, 8 - TCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 1.50E-11 1.82E-11 1.79E-11 1.70E-1115b. 1, 2, 3, 7, 8 - PeCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 2.42E-11 2.90E-11 3.13E-11 2.82E-1115c. 1, 2, 3, 4, 7, 8 - HxCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 1.11E-11 1.26E-11 1.27E-11 1.21E-1115d. 1, 2, 3, 6, 7, 8 - HxCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 2.06E-11 2.33E-11 2.13E-11 2.17E-1115e. 1, 2, 3, 7, 8, 9 - HxCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 4.48E-11 5.58E-11 5.05E-11 5.04E-1115f. 1, 2, 3, 4, 6, 7, 8 - HpCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 2.60E-10 3.44E-10 2.95E-10 3.00E-10ENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124CALCULATED TEST DATA - English UnitsDescriptionData Input By:Kevin RosenbergJob No.:210269American Marazzi Tile, Inc.Client:Source:Roller Kiln 5 Upper Channel (RK-5U)Formulas Symbol UnitsCalculated DataQC'd by Keith PooleRun Numbers- -123 AVERAGETest Date(s)-- 12/06/10 12/07/10 12/07/10 All RunsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124CALCULATED TEST DATA - English UnitsDescriptionData Input By:Kevin RosenbergJob No.:210269American Marazzi Tile, Inc.15g. OCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 3.79E-09 5.03E-09 4.78E-09 4.53E-0915h. 2, 3, 7, 8 - TCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 4.29E-12 5.93E-12 5.51E-12 5.24E-1215i. 1, 2, 3, 7, 8 - PeCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 8.32E-13 1.09E-12 1.10E-12 1.01E-1215j. 2, 3, 4, 7, 8 - PeCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 3.60E-12 3.92E-12 3.76E-12 3.76E-1215k. 1, 2, 3, 4, 7, 8 - HxCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 8.46E-13 9.51E-13 1.08E-12 9.59E-1315l. 1, 2, 3, 6, 7, 8 - HxCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 4.50E-13 4.63E-13 5.34E-13 4.82E-1315m. 2, 3, 4, 6, 7, 8 - HxCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 6.84E-13 7.56E-13 8.78E-13 7.73E-1315n. 1, 2, 3, 7, 8, 9 - HxCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 9.37E-14 1.48E-13 1.90E-13 1.44E-1315o. 1, 2, 3, 4, 6, 7, 8 - HpCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 5.25E-13 6.98E-13 5.98E-13 6.07E-1315p. 1, 2, 3, 4, 7, 8, 9 - HpCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 1.12E-13 1.48E-13 1.98E-13 1.53E-1315q. OCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 9.56E-13 1.14E-12 1.43E-12 1.18E-1215r. Other - TCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 1.52E-10 1.68E-10 1.59E-10 1.59E-1015s. Other - PeCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 3.10E-10 3.53E-10 3.28E-10 3.31E-1015t. Other - HxCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 4.42E-10 5.31E-10 4.82E-10 4.85E-1015u. Other - HpCDD Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 3.79E-10 4.83E-10 4.46E-10 4.36E-1015v. Other - TCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 1.79E-11 2.37E-11 2.44E-11 2.20E-1115w. Other - PeCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 9.62E-12 9.74E-12 1.12E-11 1.02E-1115x. Other - HxCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 3.19E-12 2.69E-12 3.90E-12 3.26E-1215y. Other - HpCDF Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 8.53E-14 4.13E-13 3.84E-13 2.94E-13Client:Source:Roller Kiln 5 Upper Channel (RK-5U)Formulas Symbol UnitsCalculated DataQC'd by Keith PooleRun Numbers- -123 AVERAGETest Date(s)-- 12/06/10 12/07/10 12/07/10 All RunsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124CALCULATED TEST DATA - English UnitsDescriptionData Input By:Kevin RosenbergJob No.:210269American Marazzi Tile, Inc.15z. Total Dioxans Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 5.45E-09 7.04E-09 6.63E-09 6.37E-0915aa. Total Furans Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 4.32E-11 5.18E-11 5.51E-11 5.01E-1115ab. Total Dioxans and Furans Concentrations=15.43*(mn/10e12)/Vm(std)Csgr / dscf 5.50E-09 7.10E-09 6.68E-09 6.42E-0920a. 2, 3, 7, 8 - TCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 1.30E-10 1.55E-10 1.32E-10 1.39E-1020b. 1, 2, 3, 7, 8 - PeCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 2.10E-10 2.47E-10 2.31E-10 2.29E-1020c. 1, 2, 3, 4, 7, 8 - HxCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 9.69E-11 1.07E-10 9.34E-11 9.91E-1120d. 1, 2, 3, 6, 7, 8 - HxCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 1.79E-10 1.99E-10 1.56E-10 1.78E-1020e. 1, 2, 3, 7, 8, 9 - HxCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.89E-10 4.76E-10 3.72E-10 4.12E-1020f. 1, 2, 3, 4, 6, 7, 8 - HpCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 2.26E-09 2.93E-09 2.17E-09 2.46E-0920g. OCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.30E-08 4.29E-08 3.52E-08 3.70E-0820h. 2, 3, 7, 8 - TCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.73E-11 5.05E-11 4.05E-11 4.28E-1120i. 1, 2, 3, 7, 8 - PeCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 7.23E-12 9.30E-12 8.08E-12 8.20E-1220j. 2, 3, 4, 7, 8 - PeCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.13E-11 3.34E-11 2.76E-11 3.08E-1120k. 1, 2, 3, 4, 7, 8 - HxCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 7.35E-12 8.11E-12 7.95E-12 7.80E-1220l. 1, 2, 3, 6, 7, 8 - HxCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.91E-12 3.94E-12 3.93E-12 3.93E-1220m. 2, 3, 4, 6, 7, 8 - HxCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 5.94E-12 6.44E-12 6.46E-12 6.28E-1220n. 1, 2, 3, 7, 8, 9 - HxCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 8.14E-13 1.27E-12 1.40E-12 1.16E-1220o. 1, 2, 3, 4, 6, 7, 8 - HpCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 4.56E-12 5.95E-12 4.40E-12 4.97E-1220p. 1, 2, 3, 4, 7, 8, 9 - HpCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 9.77E-13 1.27E-12 1.46E-12 1.23E-12Client:Source:Roller Kiln 5 Upper Channel (RK-5U)Formulas Symbol UnitsCalculated DataQC'd by Keith PooleRun Numbers- -123 AVERAGETest Date(s)-- 12/06/10 12/07/10 12/07/10 All RunsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124CALCULATED TEST DATA - English UnitsDescriptionData Input By:Kevin RosenbergJob No.:210269American Marazzi Tile, Inc.20q. OCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 8.30E-12 9.75E-12 1.05E-11 9.53E-1220r. Other - TCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 1.32E-09 1.43E-09 1.17E-09 1.31E-0920s. Other - PeCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 2.70E-09 3.01E-09 2.41E-09 2.71E-0920t. Other - HxCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.84E-09 4.52E-09 3.55E-09 3.97E-0920u. Other - HpCDD concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.30E-09 4.12E-09 3.28E-09 3.57E-0920v. Other - TCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 1.56E-10 2.02E-10 1.79E-10 1.79E-1020w. Other - PeCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 8.36E-11 8.31E-11 8.22E-11 8.30E-1120x. Other - HxCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 2.77E-11 2.30E-11 2.87E-11 2.65E-1120y. Other - HpCDF concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 7.41E-13 3.52E-12 2.82E-12 2.36E-1220z. Total Dioxans concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 4.74E-08 6.01E-08 4.87E-08 5.21E-0820aa. Total Furans concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 3.75E-10 4.42E-10 4.05E-10 4.08E-1020ab. Total Dioxans and Furans concentration adjusted to 7% O2=Cs * ((20.9-7)/(20.9-%O2))C7%O2gr / dscfc 4.78E-08 6.05E-08 4.91E-08 5.25E-0821a. 2, 3, 7, 8 - TCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 2.70E-09 3.31E-09 3.19E-09 3.07E-0921b. 1, 2, 3, 7, 8 - PeCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 4.35E-09 5.29E-09 5.58E-09 5.07E-0921c. 1, 2, 3, 4, 7, 8 - HxCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 2.01E-09 2.29E-09 2.26E-09 2.19E-0921d. 1, 2, 3, 6, 7, 8 - HxCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 3.71E-09 4.25E-09 3.78E-09 3.92E-0921e. 1, 2, 3, 7, 8, 9 - HxCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 8.06E-09 1.02E-08 8.99E-09 9.08E-0921f. 1, 2, 3, 4, 6, 7, 8 - HpCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 4.69E-08 6.28E-08 5.26E-08 5.41E-0821g. OCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 6.83E-07 9.18E-07 8.51E-07 8.17E-07Client:Source:Roller Kiln 5 Upper Channel (RK-5U)Formulas Symbol UnitsCalculated DataQC'd by Keith PooleRun Numbers- -123 AVERAGETest Date(s)-- 12/06/10 12/07/10 12/07/10 All RunsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124CALCULATED TEST DATA - English UnitsDescriptionData Input By:Kevin RosenbergJob No.:210269American Marazzi Tile, Inc.21h. 2, 3, 7, 8 - TCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 7.72E-10 1.08E-09 9.81E-10 9.45E-1021i. 1, 2, 3, 7, 8 - PeCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.50E-10 1.99E-10 1.96E-10 1.81E-1021j. 2, 3, 4, 7, 8 - PeCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 6.47E-10 7.15E-10 6.68E-10 6.77E-1021k. 1, 2, 3, 4, 7, 8 - HxCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.52E-10 1.74E-10 1.92E-10 1.73E-1021l. 1, 2, 3, 6, 7, 8 - HxCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 8.09E-11 8.44E-11 9.51E-11 8.68E-1121m. 2, 3, 4, 6, 7, 8 - HxCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.23E-10 1.38E-10 1.56E-10 1.39E-1021n. 1, 2, 3, 7, 8, 9 - HxCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.69E-11 2.71E-11 3.38E-11 2.59E-1121o. 1, 2, 3, 4, 6, 7, 8 - HpCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 9.44E-11 1.27E-10 1.06E-10 1.09E-1021p. 1, 2, 3, 4, 7, 8, 9 - HpCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 2.02E-11 2.71E-11 3.53E-11 2.75E-1121q. OCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.72E-10 2.09E-10 2.55E-10 2.12E-1021r. Other - TCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 2.73E-08 3.06E-08 2.82E-08 2.87E-0821s. Other - PeCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 5.58E-08 6.45E-08 5.84E-08 5.96E-0821t. Other - HxCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 7.94E-08 9.69E-08 8.58E-08 8.74E-0821u. Other - HpCDD Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 6.83E-08 8.83E-08 7.94E-08 7.86E-0821v. Other - TCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 3.22E-09 4.33E-09 4.34E-09 3.97E-0921w. Other - PeCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.73E-09 1.78E-09 1.99E-09 1.83E-0921x. Other - HxCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 5.74E-10 4.91E-10 6.94E-10 5.87E-1021y. Other - HpCDF Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 1.53E-11 7.54E-11 6.83E-11 5.30E-1121z. Total Dioxans Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 9.81E-07 1.29E-06 1.18E-06 1.15E-06Client:Source:Roller Kiln 5 Upper Channel (RK-5U)Formulas Symbol UnitsCalculated DataQC'd by Keith PooleRun Numbers- -123 AVERAGETest Date(s)-- 12/06/10 12/07/10 12/07/10 All RunsENTEC Services, Inc.30 Monroe Drive, Pelham, AL 35124CALCULATED TEST DATA - English UnitsDescriptionData Input By:Kevin RosenbergJob No.:210269American Marazzi Tile, Inc.21aa. Total Furans Mass Emissions= (60/7000)*cs*QsdPMRlbs / hr 7.77E-09 9.46E-09 9.81E-09 9.02E-0921ab. Total Dioxans and Furans Emissions= (60/7000)*cs*QsdPMRlbs / hr 9.89E-07 1.30E-06 1.19E-06 1.16E-0622. Volume collected through nozzle=Ts/Ps*[0.002669*Vlc+ Vm*Y*Pm/Tm]Vn acf223.698 236.395 232.956 231.01624. Isokinetic Sampling Rate, Percent= 100*Vn / (60*vs*An*q)I %94.99 100.88 100.36 98.74Post Meter Orifice Cal. (EMC ALT-009 Yqa)yqa0.9912 0.9884 0.9873 0.989% Difference, (Calibration must be within 5% of original Y-factor)-1.23%Indicates values below the detection limit (BDL).

## Client:
Source: Press Dryer 10 (DC-10) 

## Symbol Units Test Data QC'd by Keith Poole



### - - 

### 1 2 3A V E R A G E


## Test Date

- - 

### 12/02/10 12/02/10 12/03/10 All Runs 

## Times, Pollutant Runs (Began - Ended) - Military Time 

### 0735-1139 1255-1700 0735-1138

- 

## Sampling Time  minutes 

### 240 240 240 240 

## Stack Area A s 

### Ft 2 

### 1.97 1.97 1.97

- 

## Barometric Pressure P bar 

### in. Hg 

### 29.75 29.75 30.07 29.910 

## Stack Static Pressure P g 

### in. H 2 

### 0 

### -0.18 -0.18 -0.20 -0.19 

## Pitot Tube Correction factor C p 

### - 

### 0.84 0.84 0.84

- 

## Meter Correction Factor Y - 

### 1.002 1.002 1.002

- 

## Meter Delta H @  H@ in. H 2 

### 0 

### 1.878 1.878 1.878 1.878


## Nozzle Diameter D n 

### inches 

### 0.300 0.300 0.300

- 

## Meter Volume V m 

### dcf 

### 167.103 168.552 163.954 166.536 

## Meter Temperature t m o 

### F 

### 58.2 80.6 65.1 68.0 

## Avg. Orifice Delta H  H in. H 2 

### 0 

### 1.57 1.48 1.48 1.51 

## Impingers Weight Gain (Moisture) W grams 

### 351 9 408 2 433 1 397 7 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

# INPUT DATA

Run Number 

## Field Data Data Input By: 210269 Kevin Rosenberg Job No.: American Marazzi Tile, Inc.

Impingers Weight Gain (Moisture) W imp 

### grams 

### 351

. 9 408

. 2 433

. 1 397

. 7 

## Silica Gel Impinger Weight Gain (Moisture) W sg 

### grams 

### 43.1 38.8 35.6 39.2 

## Oxygen Concentration, % (dry basis) O 2 

### % 

### 18.80 18.80 18.72 18.77 

## Carbon Dioxide Concentration, % (dry basis) CO 2 

### % 

### 0.95 0.95 0.99 0.96 

## Avg. Sq. Rt. of Delta P sqrt  P 

### in. H20 1/2 

### 0.507 0.493 0.496 0.499 

## Stack Temperature t s o 

### F 

### 216.5 222.1 218.5 219.0 

## 2, 3, 7, 8 - TCDD pg 

### 2.5 2.2 1.5 2.1 

## 1, 2, 3, 7, 8 - PeCDD pg 

### 1.6 1.6 1.5 1.6 

## 1, 2, 3, 4, 7, 8 - HxCDD pg 

### 1.8 1.7 1.3 1.6 

## 1, 2, 3, 6, 7, 8 - HxCDD pg 

### 1.6 1.5 1.2 1.4 

## 1, 2, 3, 7, 8, 9 - HxCDD pg 

### 1.7 2.2 2.0 2.0 

## 1, 2, 3, 4, 6, 7, 8 - HpCDD pg 

### 8.3 10.4 10.1 9.6


## OCDD pg 

### 215 233 210 219.3 

## 2, 3, 7, 8 - TCDF pg 

### 1.2 1.6 1.8 1.5 

## 1, 2, 3, 7, 8 - PeCDF pg 

### 0.84 0.92 0.74 0.83 

## 2, 3, 4, 7, 8 - PeCDF pg 

### 0.82 0.90 1.0 0.91

## Client:
Source: Press Dryer 10 (DC-10) 

## Symbol Units Test Data QC'd by Keith Poole



### - - 

### 1 2 3A V E R A G E


## Test Date

- - 

### 12/02/10 12/02/10 12/03/10 All Runs 

# ENTEC Services, Inc.

30 Monroe Drive, Pelham, AL 35124 

# INPUT DATA

Run Number 

## Field Data Data Input By: 210269 Kevin Rosenberg Job No.: American Marazzi Tile, Inc.



## 1, 2, 3, 4, 7, 8 - HxCDF pg 

### 0.81 0.81 0.56 0.73 

## 1, 2, 3, 6, 7, 8 - HxCDF pg 

### 0.72 0.73 0.50 0.65 

## 2, 3, 4, 6, 7, 8 - HxCDF pg 

### 0.76 0.77 0.53 0.69 

## 1, 2, 3, 7, 8, 9 - HxCDF pg 

### 0.88 0.88 0.61 0.79 

## 1, 2, 3, 4, 6, 7, 8 - HpCDF pg 

### 1.42 0.60 1.40 1.14 

## 1, 2, 3, 4, 7, 8, 9 - HpCDF pg 

### 1.7 0.74 0.61 1.0


## OCDF pg 

### 3.3 1.3 1.3 2.0


## Other - TCDD pg 

### 1.6 5.4 3.4 3.5


## Other - PeCDD pg 

### 1.5 7.4 4.4 4.4


## Other - HxCDD pg 

### 1.8 1.7 12.4 5.3 

## Other - HpCDD pg 

### 13.8 1.3 13.2 9.4


## Other - TCDF pg 

### 1.2 1.6 2.9 1.9


## Other

- PeCDF pg 

### 0.84 0.92 0.74 0.83


## Other - HxCDF pg 

### 0.88 0.88 0.61 0.79 

## Other - HpCDF pg 

### 1.5 0.74 1.5 1.2


## Total Dioxans pg 

### 252.4 270.1 263.8 262.1 

## Total Furans pg 

### 16.9 5.4 7.0 9.8 

## Total Dioxans and Furans pg 

### 269.3 275.5 270.8 271.9

Indicates values below the detection limit (BDL).

### Client: Source: Press Dryer 10 (DC-10) Formulas Symbol Units 

### Calculated Data QC'd by: Keith Poole 

### Run Numbers

- - 1 2 3A V E R A G E 

### Test Date(s)

- - 12/02/10 12/02/10 12/03/10 All Runs 

### Times, Pollutant Runs (Began - Ended)

- Military Time 0735-1139 1255-1700 0735-1138 - 

### 1. Stack Pressure = Pbar + Pg / 13.6 Ps in. Hg 29.74 29.74 30.06 29.84 

### 2. Meter Pressure = Pbar + DH / 13.6 Pm in. Hg 29.87 29.86 30.18 29.97 

### 3. Standard Meter Volume = 17.64* Y* (Vm/Tm)* (Pbar + DH / 13.6) Vm(std) dscf 170.291 164.621 166.610 167.174 

### 4a. Standard Volume of Water Vapor Condensed =0.04706*Wimp Vwc(std) scf 16.560 19.210 20.382 18.717 

### 4b. Standard Volume of Water Collected in Silica Gel =0.04715*Wsg Vwsg(std) scf 2.032 1.829 1.679 1.847 

### 5. Moisture Fraction =(Vwc(std) + Vwsg(std))/(Vwc(std) + Vwsg(std) + Vm(std)) Bws fraction 0.0984 0.1133 0.1169 0.1096 

### 9. Molecular Weight of Stack Gas (dry) = 0.32*(O2)+ 0.44*(CO2)+0.28*(100-(O2)-(CO2)) Md lb / lb-mole 28.904 28.904 28.907 28.905 

### 10. Molecular Weight of Stack Gas (wet) = Md*(1-Bws)+18.0*(Bws) Ms lb / lb-mole 27.831 27.668 27.632 27.710 

### 11. Average Stack Gas Velocity = 85.49*Cp*(sqrt DP)avg*SQRT((Ts) / (Ps*Mw)) vs ft / s 32.944 32.23 32.18 32.45 

### 12. Stack Gas Flow @ Actual Conditions = 60*vs*As Qa acfm 3,892 3,808 3,801 3,834 

### 13. Stack Gas Flow @ Standard Conditions = Qa*(Tstd/Ts)*(Ps/Pstd) Qs scfm 3,018 2,928 2,971 2,972 

### 14. Stack Gas Flow @ Dry Standard Conditions = Qa*(1-Bws)*(Tstd/Ts)*(Ps/Pstd) Qstd dscfm 2,721 2,597 2,623 2,647 15a. 2, 3, 7, 8 - TCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 2.27E-13 2.06E-13 1.39E-13 1.91E-13 15b. 1, 2, 3, 7, 8 - PeCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.45E-13 1.53E-13 1.39E-13 1.46E-13 15c. 1, 2, 3, 4, 7, 8 - HxCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.63E-13 1.59E-13 1.20E-13 1.48E-13 15d. 1, 2, 3, 6, 7, 8 - HxCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.45E-13 1.41E-13 1.11E-13 1.32E-13 15e. 1, 2, 3, 7, 8, 9 - HxCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.54E-13 2.06E-13 1.85E-13 1.82E-13 15f 1 2 3 4 6 7 8 - HpCDD Concentrations =15 43 * (m /10e 12 )/Vm(std) C gr / dscf 7 52E-13 9 75E-13 9 35E-13 8 87E-13 Description 

### Data Input By: Kevin Rosenberg Job No.: 210269 American Marazzi Tile, Inc. 

# ENTEC Services, Inc.
30 Monroe Drive, Pelham, AL 35124 

## CALCULATED TEST DATA - English Units

15f

. 1 , 2 , 3 , 4 , 6 , 7 , 8

- HpCDD Concentrations =15

. 43 (m n /10e )/Vm(std) C s gr / dscf 7

. 52E-13 9

. 75E-13 9

. 35E-13 8

. 87E-13 15g. OCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.95E-11 2.18E-11 1.94E-11 2.03E-11 15h. 2, 3, 7, 8 - TCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.09E-13 1.50E-13 1.67E-13 1.42E-13 15i. 1, 2, 3, 7, 8 - PeCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.61E-14 8.62E-14 6.85E-14 7.70E-14 15j. 2, 3, 4, 7, 8 - PeCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.43E-14 8.44E-14 9.26E-14 8.38E-14 15k. 1, 2, 3, 4, 7, 8 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.34E-14 7.59E-14 5.19E-14 6.71E-14 15l. 1, 2, 3, 6, 7, 8 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 6.52E-14 6.84E-14 4.63E-14 6.00E-14 15m. 2, 3, 4, 6, 7, 8 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 6.89E-14 7.22E-14 4.91E-14 6.34E-14 15n. 1, 2, 3, 7, 8, 9 - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.97E-14 8.25E-14 5.65E-14 7.29E-14 15o. 1, 2, 3, 4, 6, 7, 8 - HpCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.29E-13 5.62E-14 1.30E-13 1.05E-13 15p. 1, 2, 3, 4, 7, 8, 9 - HpCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.54E-13 6.94E-14 5.65E-14 9.33E-14 15q. OCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 2.99E-13 1.22E-13 1.20E-13 1.80E-13 15r. Other - TCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.45E-13 5.08E-13 3.14E-13 3.22E-13 15s. Other - PeCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.35E-13 6.95E-13 4.03E-13 4.11E-13 15t. Other - HxCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.63E-13 1.59E-13 1.15E-12 4.90E-13 15u. Other - HpCDD Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.25E-12 1.22E-13 1.22E-12 8.65E-13 15v. Other - TCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.09E-13 1.50E-13 2.65E-13 1.75E-13 15w. Other - PeCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.61E-14 8.62E-14 6.85E-14 7.70E-14 15x. Other - HxCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 7.97E-14 8.25E-14 5.65E-14 7.29E-14 15y. Other - HpCDF Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.36E-13 6.94E-14 1.39E-13 1.15E-13 15z. Total Dioxans Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 2.29E-11 2.53E-11 2.44E-11 2.42E-11 15aa. Total Furans Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 1.53E-12 5.10E-13 6.49E-13 8.96E-13 15ab. Total Dioxans and Furans Concentrations =15.43*(m n /10e 12 )/Vm(std) C s gr / dscf 2.44E-11 2.58E-11 2.51E-11 2.51E-11 20a. 2, 3, 7, 8 - TCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.50E-12 1.36E-12 8.86E-13 1.25E-12

### Client: Source: Press Dryer 10 (DC-10) Formulas Symbol Units 

### Calculated Data QC'd by: Keith Poole 

### Run Numbers

- - 1 2 3A V E R A G E 

### Test Date(s)

- - 12/02/10 12/02/10 12/03/10 All Runs 

### Times, Pollutant Runs (Began - Ended)

- Military Time 0735-1139 1255-1700 0735-1138 - Description 

### Data Input By: Kevin Rosenberg Job No.: 210269 American Marazzi Tile, Inc. 

# ENTEC Services, Inc.
30 Monroe Drive, Pelham, AL 35124 

## CALCULATED TEST DATA - English Units

20b. 1, 2, 3, 7, 8 - PeCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 9.60E-13 1.01E-12 8.86E-13 9.52E-13 20c. 1, 2, 3, 4, 7, 8 - HxCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.08E-12 1.05E-12 7.68E-13 9.67E-13 20d. 1, 2, 3, 6, 7, 8 - HxCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 9.60E-13 9.31E-13 7.09E-13 8.66E-13 20e. 1, 2, 3, 7, 8, 9 - HxCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.02E-12 1.36E-12 1.18E-12 1.19E-12 20f. 1, 2, 3, 4, 6, 7, 8 - HpCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.98E-12 6.45E-12 5.96E-12 5.80E-12 20g. OCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.29E-10 1.45E-10 1.24E-10 1.33E-10 20h. 2, 3, 7, 8 - TCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 7.20E-13 9.93E-13 1.06E-12 9.25E-13 20i. 1, 2, 3, 7, 8 - PeCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.04E-13 5.71E-13 4.37E-13 5.04E-13 20j. 2, 3, 4, 7, 8 - PeCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.92E-13 5.58E-13 5.91E-13 5.47E-13 20k. 1, 2, 3, 4, 7, 8 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.86E-13 5.03E-13 3.31E-13 4.40E-13 20l. 1, 2, 3, 6, 7, 8 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.32E-13 4.53E-13 2.95E-13 3.93E-13 20m. 2, 3, 4, 6, 7, 8 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 4.56E-13 4.78E-13 3.13E-13 4.15E-13 20n. 1, 2, 3, 7, 8, 9 - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.28E-13 5.46E-13 3.60E-13 4.78E-13 20o. 1, 2, 3, 4, 6, 7, 8 - HpCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 8.52E-13 3.72E-13 8.27E-13 6.84E-13 20p. 1, 2, 3, 4, 7, 8, 9 - HpCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.02E-12 4.59E-13 3.60E-13 6.13E-13 20q. OCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.98E-12 8.07E-13 7.68E-13 1.18E-12 20r. Other - TCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 9.60E-13 3.36E-12 2.00E-12 2.11E-12 20s Other - PeCDD concentration adjusted to 7% O2 =Cs * ((20 9-7)/(20 9-%O2)) c %O2 gr / dscfc 8 94E-13 4 60E-12 2 57E-12 2 69E-12 20s

. Other

- PeCDD concentration adjusted to 7% O2 ((20

. 9-7)/(20

. 9-%O2)) gr / dscfc 8

. 94E-13 4

. 60E-12 2

. 57E-12 2

. 69E-12 20t. Other - HxCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.08E-12 1.05E-12 7.32E-12 3.15E-12 20u. Other - HpCDD concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 8.28E-12 8.07E-13 7.79E-12 5.63E-12 20v. Other - TCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 7.20E-13 9.93E-13 1.69E-12 1.13E-12 20w. Other - PeCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.04E-13 5.71E-13 4.37E-13 5.04E-13 20x. Other - HxCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 5.28E-13 5.46E-13 3.60E-13 4.78E-13 20y. Other - HpCDF concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 9.00E-13 4.59E-13 8.86E-13 7.48E-13 20z. Total Dioxans concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.51E-10 1.68E-10 1.56E-10 1.58E-10 20aa. Total Furans concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.01E-11 3.38E-12 4.14E-12 5.88E-12 20ab. Total Dioxans and Furans concentration adjusted to 7% O2 =Cs * ((20.9-7)/(20.9-%O2)) c %O2 gr / dscfc 1.61E-10 1.71E-10 1.60E-10 1.64E-10 21a. 2, 3, 7, 8 - TCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 5.28E-12 4.59E-12 3.12E-12 4.33E-12 21b. 1, 2, 3, 7, 8 - PeCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.38E-12 3.40E-12 3.12E-12 3.30E-12 21c. 1, 2, 3, 4, 7, 8 - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.80E-12 3.55E-12 2.71E-12 3.35E-12 21d. 1, 2, 3, 6, 7, 8 - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.38E-12 3.13E-12 2.50E-12 3.00E-12 21e. 1, 2, 3, 7, 8, 9 - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.59E-12 4.59E-12 4.16E-12 4.12E-12 21f. 1, 2, 3, 4, 6, 7, 8 - HpCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.75E-11 2.17E-11 2.10E-11 2.01E-11 21g. OCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 4.54E-10 4.86E-10 4.37E-10 4.59E-10 21h. 2, 3, 7, 8 - TCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 2.54E-12 3.34E-12 3.75E-12 3.21E-12 21i. 1, 2, 3, 7, 8 - PeCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.77E-12 1.92E-12 1.54E-12 1.75E-12 21j. 2, 3, 4, 7, 8 - PeCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.73E-12 1.88E-12 2.08E-12 1.90E-12 21k. 1, 2, 3, 4, 7, 8 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.71E-12 1.69E-12 1.17E-12 1.52E-12 21l. 1, 2, 3, 6, 7, 8 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.52E-12 1.52E-12 1.04E-12 1.36E-12 21m. 2, 3, 4, 6, 7, 8 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.61E-12 1.61E-12 1.10E-12 1.44E-12 21n. 1, 2, 3, 7, 8, 9 - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.86E-12 1.84E-12 1.27E-12 1.66E-12

### Client: Source: Press Dryer 10 (DC-10) Formulas Symbol Units 

### Calculated Data QC'd by: Keith Poole 

### Run Numbers

- - 1 2 3A V E R A G E 

### Test Date(s)

- - 12/02/10 12/02/10 12/03/10 All Runs 

### Times, Pollutant Runs (Began - Ended)

- Military Time 0735-1139 1255-1700 0735-1138 - Description 

### Data Input By: Kevin Rosenberg Job No.: 210269 American Marazzi Tile, Inc. 

# ENTEC Services, Inc.
30 Monroe Drive, Pelham, AL 35124 

## CALCULATED TEST DATA - English Units

21o. 1, 2, 3, 4, 6, 7, 8 - HpCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.00E-12 1.25E-12 2.92E-12 2.39E-12 21p. 1, 2, 3, 4, 7, 8, 9 - HpCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.59E-12 1.54E-12 1.27E-12 2.14E-12 21q. OCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 6.97E-12 2.71E-12 2.71E-12 4.13E-12 21r. Other - TCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.38E-12 1.13E-11 7.06E-12 7.25E-12 21s. Other - PeCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.15E-12 1.55E-11 9.06E-12 9.22E-12 21t. Other - HxCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.80E-12 3.55E-12 2.58E-11 1.11E-11 21u. Other - HpCDD Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 2.92E-11 2.71E-12 2.75E-11 1.98E-11 21v. Other - TCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 2.54E-12 3.34E-12 5.96E-12 3.94E-12 21w. Other - PeCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.77E-12 1.92E-12 1.54E-12 1.75E-12 21x. Other - HxCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 1.86E-12 1.84E-12 1.27E-12 1.66E-12 21y. Other - HpCDF Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.17E-12 1.54E-12 3.12E-12 2.61E-12
21z. Total Dioxans Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 5.33E-10 5.63E-10 5.49E-10 5.49E-10
21aa. Total Furans Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 3.56E-11 1.13E-11 1.46E-11 2.05E-11
21ab. Total Dioxans and Furans Mass Emissions = (60/7000)*cs*Qsd PMR lbs / hr 5.69E-10 5.75E-10 5.64E-10 5.69E-10 

### 22. Volume collected through nozzle =Ts/Ps*[0.002669*Vlc+ Vm*Y*Pm/Tm] Vn acf 243.514 241.338 241.362 242.071 

### 24. Isokinetic Sampling Rate, Percent = 100*Vn / (60*vs*An*q) I % 104.57 105.93 106.12 105.54


### Post Meter Orifice Cal. (EMC ALT-009 Yqa) y qa 0.9795 0.9625 0.9697 0.971 

### % Difference, (Calibration must be within 5% of original Y-factor) 3.14%
Indicates values below the detection limit (BDL).

# This is the last page of this report.