Ony xEnvironmenta l Service s Sauget , I L

Performanc e Tes tResult s fo rth e Fixe d Heart h an d Rotar yKil n Incinerator s - Ma y200 4 ^



## ENS R Corporatio n Jul y2004 Documen tNumbe r10002-011-40 0\lNTERAIAnONAL CONTENT S

1
. 0 INTRODUCTIO N 1- 1 1. 1 Progra m Summar y1- 1 2. 0 SUMMAR YO FRESULT S . 2- 1 2. 1 Introductio n 2- 1 2. 2 Stac k

Emissio n Result s fo rPCDDs/PCDF s 2- 1 2. 3 Stac k

Emissio n result s fo rTarge tMetal s 2- 1 3. 0 SAMPLIN G AN D ANALYTICA LPROCEDURE S 3- 1 3. 1 Samplin g Procedure s 3- 1 3.1. 1 Velocity , Moistur e an d Fixe d Ga s Determination s 3- 1 3.1. 2 PCDD/PCD FSamplin g 3- 1 3.1. 3 Metal s Samplin g 3- 1 3. 2 Analytica l Procedure s 3- 1 3.2. 1 PCDD/PCD FAnalyse s 3- 1 3.2. 2 Metal s Analyse s 3- 2 3. 3 Proces s Operatin g Condition s 3- 2 4. 0 QUALIT YASSURANC E 4- 1 4. 1 Introductio n 4- 1 4.1. 1 Pre-Samplin g Activitie s 4- 1 4.1. 2 Equipmen tCalibratio n 4- 1 4.1. 3 Glasswar e Preparatio n 4- 2 4. 2 Chai n o fCustod y4- 3 4. 3 Analytica l QA/Q C 4- 3 4.3. 1 Analysi s fo rPCDDs/PCDF s 4- 3 4.3. 2 Analysi s fo rMetal s 4- 3

J:\Air_Tox\ProjectFiles\Onyx\Onyx2004\Ma yi July , 2004 2004\050 4 Fina l Report.do cINTERNATIONAL LIS TO F TABLE S Tabl e 2- 1 ONY XFixe d Heart h Incinerato rUni t2 PCDD/PCD FEmissio n Result s - 2- 2 Tabl e 2- 2 ONY XFixe d Heart h Incinerato rUni t2 PCDD/PCD FEmissio n Result s - 2- 3 Tabl e 2- 3 ONY XFixe d Heart h Incinerato rUni t2 PCDD/PCD FEmissio n Result s - 2^ 1 Tabl e 2- 4 ONY XRotar yKil n Uni t2 Mercur yEmissio n Result s 2- 5 Tabl e 2- 5 ONY XFixe d Heart h Incinerato rUni t4 Mercur yEmissio n Result s 2- 6

J:\Air_Tox\ProjectHles\Onyx\Onyx2004\Ma yi i July . 2004 2004\0504 Fina l Report.do clAirERMAr/ON/IL. 1. 0 INTRODUCTIO N
1. 1 Progra m Summary ENS R Internationa l wa s retaine d b yOny xEnvironmenta l Services , Sauget , Illinoi s t o conduc t stac k ga s emissio n samplin g durin g th e wee k o fMa y3 , 200 4 o n tw o incinerator s a tth e facility
. Th e purpos e o fthi s Performanc e Tes twa s t o validat e th e performanc e leve l o fth e incinerato ragains t th e requirement s i n 4 0 CF R Par t63 , Subpar tEEE
. T o thi s end , th e specifi cobjective s o fthi s Performanc e Tes twer e to :

•Demonstrat e tha tthe mercury , dioxin s an d furan s emission s fro m th e Fixe d Heart h an d mercur yemission s fro m th e Rotar yKil n mee tth e HW C MAC Temissio n limit s whil e treatin g hazardou s waste .
•Collec tmonitorin g data , t o b e use d i n conjunctio n wit h previou s tes tdata , i n orde rt o se t operatin g limit s o n ke yincinerato rsyste m parameter s tha twil l ensur e tha tth e incinerato r operate s withi n th e HW C MAC Temissio n limit s whil e treatin g hazardou s waste . Th e Performanc e Tes tinclude d feedin g certai n type s o fwaste s an d material s int o eac h incinerator , samplin g an d analyzin g thes e feedstreams , monitorin g certai n proces s parameter s whil e conductin g emission s testing
.

J:\Air_Tox\ProjectFiles\Onyx\Onyx2004\May 2004\050 4 Fina l Report.do c 1- 1 July , 2004

## EreJI
. | INTERNATIONAL 2. 0 SUMMAR YO FRESULT S
2. 1 Introductio n Thi s sectio n summarize s th e tes tprogra m results
. Appendi xApresent s copie s o fENSR' s fiel d dat a sheets
. Emissio n dat ai s summarize d i n thi s sectio n an d fee d an d proces s operatin g dat aar e include d i n Appendi xB
. 2. 2 Stac k

Emissio n Result s fo rPCDDs/PCDF s Stac k emission s fro m Uni t2 wer e teste d fo rPCDDs/PCDF s vi aMetho d 0023A
. Thi s require d separat e analysi s o fth e front-hal fan d back-hal fsampl e trai n fractions
. Progra m sample s wer e submitte d t o Alt aAnalytica l Laboratorie s i n E l Dorad o Hills , C Afo ral l analysi s o fal l targe tparameters . Th e secon d ru n o n Uni t2 wa s voide d du e t o aC O spik e an d afourt h samplin g ru n wa s conducted
. Th e PCDD/PCD Femission s fo rUnit2 (averag e emission s fo rrun s 1 , 3 an d 4 wer e 0.05 4 ng/m 3 @ 7 % 0 2 ) ar e belo wth e HW C MAC Temissio n standar d o f0. 4 ng/m 3@ 7 % 0 2 . Asummar yo fthe PCDD/PCD Femissio n result s o n aTE Q basi s fo rUni t2 ar e include d i n Table s 2-1
. 2. 3 Stac k

Emissio n result s fo rTargetMetal s Stac k emission s from bot h Uni t2 an d Uni t4 wer e teste d fo rmetal s i n accordanc e wit h Metho d 29
. Durin g th e secon d samplin g ru n o n Uni t4 , th e uni texperience d a n AWFCO
. ENS R sample d throug h duratio n o fth e AWFCO
. A s aresul to fsamplin g whil e th e uni twa s no tburnin g waste , th e samplin g ru n wa s voide d an d afourt h samplin g ru n wa s conducted
. Th e secon d ru n o n Uni t2 wa s voide d du e t o aC O spik e an d afourt h samplin g ru n wa s conducted
. Asummar yo fth e mercuryemission s fo rUni t 2 an d Uni t4 ar e include d i n table s 2- 3 an d 2-4
. Mercur yresult s indicat e that :

•Th e mercuryemission s fo rUni t2 (averag e fo rrun s 1 , 3 an d 4 wer e 13. 5 pg/m 3@ 7 % 0 2 ) wer e belo wth e ne wHW C MAC Temissio n standar d o f13 0 pg/m 3@ 7 % 0 2 ;
•Th e mercuryemission s fo rUni t4 (averag e fo rrun s 1 , 3 an d 4 wer e 1 7
. 9 pg/m 3@ 7 % 0 2 ) wer e belo wth e ne wHW C MAC Temissio n standar d o f13 0 pg/m 3@ 7 % 0 2 .

J:\Air_Tox\ProjectFiles\Onyx\Onyx2004\May 2004\050 4 Fina l Reportdo c 2- 1 July , 2004

# E M S /A/TERNATIONAL Tabl e 2- 1 ONYXFixe d Heart h Incinerato rUni t2 PCDD/PCD FEmissio n Result s - T OTA LTEQ' s
Ru n No . Ru n 1 Ru n 3 Ru n 4 Date . 05

-May -0 4 06-May-0 4 06

-May -0 4 Star tTime 09:3 5 10:1 0 14:1 5 Stop Time 12:3 8 13:3 0 17:2 3 Unit s Sampl e Volum e dsc f 125.48 2 126.93 1 128.30 2 Sampl e Volum e m 3 3.5 5 3.5 9 3.6 3 Moistur e Conten t % v/ v 43. 0 44. 7 43. 4 0 2Concentratio n %v/ v(dry ) 10.4 0 10.5 0 10.5 0 C 0 2Concentratio n %v/ v(dry ) 4.5 0 4.2 0 4.3 0 Isokinetic s % 10 2 10 5 10 2 Stac k Flowrat e dscf m 5,74 7 5,56 4 5,77 6 PCD D / PCD F P 9 ng/m 3 p g ng/m 3 p g ng/m 3 Parameter s TE F(a) TE Q TE Q TE Q 2,3,7,8-TCD D 1.00 5.1 6 1.5E-0 3 (6.47 ) O.OE+0 0 5.3 3 1.5E-0 3 1,2,3,7,8-PeCD D 0.5 0 34. 2 4.8E-0 3 33. 5 4.7E-0 3 20. 3 2.8E-0 3 1,2,3,4,7,8-HxCD D 0.1 0 31. 7 8.9E-0 4 27. 8 7.7E-0 4 19. 7 5.4E-0 4 1,2,3,6,7,8-HxCD D 0.1 0 87. 2 2.5E-0 3 62. 5 1.7E-0 3 44. 3 1.2E-0 3 1,2,3,7,8,9-HxCD D 0.1 0 46. 4 1.3E-0 3 56. 6 1.6E-0 3 35. 7 9.8E-0 4 1,2,3,4,6,7,8-HpCD D 0.0 1 437. 6 1.2E-0 3 28 7 8.0E-0 4 166. 0 4.6E-0 4 OCD D 0.00 1 368. 6 1.0E-04 222. 2 6.2E-0 5 135. 1 3.7E-0 5 2,3,7,8-TCD F 0.1 0 50. 0 1.4E-0 3 64. 3 1.8E-0 3 45. 6 1.3E-0 3 1,2,3,7,8-PeCD F 0.0 5 72. 7 1.OE-03 68. 3 9.5E-0 4 41. 8 5.8E-0 4 2,3,4,7,8-PeCD F 0.5 0 153. 0 2.2E-0 2 166. 0 2.3E-0 2 88. 0 1.2E-0 2 1,2,3,4,7,8-HxCD F 0.1 0 116. 0 3.3E-0 3 85. 8 2.4E-0 3 48. 2 1.3E-0 3 1,2,3,6,7,8-HxCD F 0.1 0 85. 5 2.4E-0 3 63. 3 1.8E-0 3 36. 4 1.OE-0 3 2,3,4,6,7,8-HxCD F 0.1 0 226. 0 6.4E-0 3 151. 0 4.2E-0 3 71. 1 2.0E-0 3 1,2,3,7,8,9-HxCD F 0.1 0 52. 1 1.5E-0 3 32. 0 8.9E-0 4 18. 5 5. 1 E-0 4 1,2,3,4,6,7,8-HpCD F 0.0 1 220. 0 6.2E-0 4 131. 0 3.6E-0 4 64. 4 1.8E-0 4 1,2,3,4,7,8,9-HpCD F 0.0 1 69. 6 2.0E-0 4 21. 6 6.0E-0 5 (14.4 ) 0.0E+0 0 OCD F 0.00 1 120. 6 3.4E-0 5 45. 9 1.3E-0 5 31. 4 8.6E-0 6 TOTA LTEQ s (ng/m 3) 0.05 1 0.04 5 0.02 6 TOTA LTEQ s (ng/m 3@ 7 % 0 2 ) = 0.06 7 0.06

0 0.03

5 TOTA LTEQ s (g/s) = 1.4E-1 0 1.2E-1 0 7.2E-1 1 (a) U.S.EP A(1989) Toxi cEquivalenc yFacto r Note : "Non-detect " value s ar e shown i n parentheses an d treated a s zer o i n th e calculatio n o fconcentratio n o n aTE Q basis
.

J:\Air_Tox\ProjectFiles\Onyx\Onyx2004\May

2 004\050 4 Fina l Reportdo c 2- 2 July , 2004ENSR . Tabl e 2- 2 ONY XFixe d Heart h Incinerato rUni t2 PCDD/PCD FEmissio n Result s -

Fron tHalfFractio n Total s
Ru n No . Ru n 1 Ru n 3 Ru n 4 Dat e 05-May-O 4 06-May-0 4 06-Mav-0 4 Star tTim e 09:3 5 10:1 0 14:1 5 Sto p Tim e 12:3 8 13:3 0 17:2 3 Sampl e Volum e unii s dscf 125.48 2 126.93 1 128.30 2 Sampl e Volum e m 3 3.5 5 3.5 9 3.6 3 Moistur e Conten t % v/ v 43. 0 44. 7 43. 4 0 2Concentratio n %v/ v(dry ) 10.4 0 10.5 0 10.5 0 C 0 2Concentratio n %v/ v(dry ) 4.5 0 4.2 0 4.3 0 Isokinetic s % 10 2 10 5 10 2 Stac k Flowrat e dscf m 5,74 7 5,56 4 5,77 6 PCDD/PCD F Parameter s TE F(a ) P9 ng/m 3 TE Q p g ng/m 3

TE Q pg ng/m 3

TE Q 2,3,7,8-TCD D 1.00 (2.28 ) O.0E+O0 (1.89 ) 0.0E+0 0 (3.21 ) O.OE+00 1,2,3,7,8-PeCD D 0.5 0 (3.85 ) O.0E+O0 (5.07 ) 0.0E+0 0 (5.06 ) O.OE+00 1,2,3,4,7,8-HxCD D 0.1 0 ..(2.74)
. O.OE+00 (4.92 ) O.OE+O O (3.61 ) O.OE+00 1,2,3,6,7,8-HxCD D 0.1 0 ..(2,53)
. 0.0E+0 0 (4.55 ) O.OE+0 0 (3.33 ) O.OE+00 1,2,3,7,8,9-HxCD D 0.1 0 (2.59 ) 0.0E+0 0 (4.65 ) O.OE+0 0 (3.40 ) O.OE+00 1,2,3,4,6,7,8-HpCD D 0.0 1 4.6 3 1.3E-0 5 3.8 2 1. 1 E-0 5 (8.38 ) O.OE+00 OCD D 0.00 1 19. 6 5.5E-0 6 16. 2 4.5E-0 6 21. 1 5.8E-0 6 2,3,7,8-TCD F 0.1 0 (3.11 ) 0.0E+0 0 (3.67 ) O.OE+O O 6.4 6 1.8E-0 4 1,2,3,7,8-PeCD F 0.0 5 (3.75 ) 0.0E+0 0 (4.07 ) O.OE+O O (2.85 ) O.OE+00 2,3,4,7,8-PeCD F 0.5 0 (3.46 ) 0.0E+0 0 (3.75 ) O.OE+O O {2.62 ) O.OE+00 1,2,3,4,7,8-HxCD F 0.1 0 .(2,77)
. O.OE+00 (2.65 ) O.OE+0 0 (341 ) O.OE+00 1,2,3,6,7,8-HxCD F 0.1 0 .(2- 5 9)
. O.OE+00 (2.39 ) O.OE+0 0 (3.08 ) O.OE+00 2,3,4,6,7,8-HxCD F 0.1 0 (2.98 ) 0.0E+0 0 (2.85 ) O.OE+0 0 (1.74 ) O.OE+00 1,2,3,7,8,9-HxCD F 0.1 0 _.(?.-2T L 0.0E+0 0 (3.13)
. O.OE+0 0 (1.90 ) O.OE+00 1,2,3,4,6,7,8-HpCD F 0.0 1 ( 4 .-73)
. O.OE+00 (6.55 ) O.OE+0 0 7.34 2.0E-0 5 1,2,3,4,7,8,9-HpCD F 0.0 1 

## .&P7.L 0.0E+0 0 (2.78 ) O.OE+0 0 (2.71 ) O.OE+O

O OCD F 0.00 1 (18.8 ) 0.0E+0 0 15. 3 4.3E-0 6 16. 3 4.5E-0 6 TOTA LTEQ s (ng/m 3) = 1.9E-0 5 1.9E-0 5 2. 1 E-0 4 TOTA LTEQ s (ng/m 3@ 7 % 0 2 ) 2.4E-05 2.6E-0 5 2.8E-0 4 TOTA LTEQ s (g/s ) 5.0E-1 4 5. 1 E-1 4 5.7E-1 3 (a) U.S.EP A(1989) Toxi cEquivalenc yFacto r Note : "Non-detect " value s ar e shown i n parentheses an d treated as zer o i n th e calculatio n o fconcentratio n o n aTE Q basis
.

J:\Air_Tox\ProjectFiles\0nyx\0ny x2004\May

2 0O4\050 4 Fina l Repor tdo c 2- 3 July , 2004BUSK . /AITERUAT/OAIAL Tabl e 2- 3 ONY XFixe d Heart h Incinerato rUni t2 PCDD/PCD FEmissio n Results Bac k Hal fFractio n Total s

Ru n No . Dat e Ru n 1

05 -May -0 4 flQ.O C Ru n 3

06 -May -0 4 -irv m Ru n 4

06 -May -0 4 14-1 ^ Star tTim e Sto p Tim e uy.o o 12:3 8 IU
. 1 u

13:3 0 17:2 3 Unit s Sampl e Volum e dsc f 125.48 2 126.93 1 128.30 2 Sampl e Volum e m 3 3.5 5 3.5 9 3.6 3 Moistur e Conten t % v/ v 43. 0 44. 7 43. 4 0 2Concentratio n %v/ v(dry ) 10.4 0 10.5 0 10.5 0 C 0 2Concentratio n %v/ v(dry ) 4.5 0 4.2 0 4.3 0 Isokinetic s % 10 2 10 5 10 2 Stac k Flowrat e dscf m 5,74 7 5,56 4 5,77 6 PCDD/PCD F Parameter s TE F(a) p g ng/m 3 TE Q p g ng/m 3

TE Q p g ng/m 3

TE Q 2,3,7,8-TCD D 1.0 0 5.1 6 1.5E-0 3 (4.58 ) O.OE+00 5.3 3 1.5E-0 3 1,2,3,7,8-PeCD D 0.5 0 34. 2 4.8E-0 3 33. 5 4.7E-0 3 20. 3 2.8E-0 3 1,2,3,4,7,8-HxCD D 0.1 0 31. 7 8.9E-0 4 27. 8 7.7E-0 4 19. 7 5.4E-0 4 1,2,3,6,7,8-HxCD D 0.1 0 87. 2 2.5E-0 3 62. 5 1.7E-0 3 44. 3 1.2E-0 3 1,2,3,7,8,9-HxCD D 0.1 0 46. 4 1.3E-0 3 56. 6 1.6E-0 3 35. 7 9.8E-0 4 1,2,3,4,6,7,8-HpCD D 0.0 1 43 3 1.2E-0 3 28 3 7.9E-04 16 6 4.6E-0 4 OCD D 0.00 1 34 9 9.8E-0 5 20 6 5.7E-0 5 11 4 3. 1 E-0 5 2,3,7,8-TCD F 0.1 0 50. 0 1.4E-0 3 64. 3 1.8E-0 3 39. 1 1. 1 E-0 3 1,2,3,7,8-PeCD F 0.0 5 72. 7 1.OE-0 3 68. 3 9.5E-0 4 41. 8 5.8E-0 4 2,3,4,7,8-PeCD F 0.5 0 15 3 2.2E-0 2 16 6 2.3E-0 2 88. 0 1.2E-0 2 1,2,3,4,7,8-HxCD F 0.1 0 11 6 3.3E-0 3 85. 8 2.4E-0 3 48. 2 1.3E-0 3 1,2,3,6,7,8-HxCD F 0.1 0 85. 5 2.4E-0 3 63. 3 1.8E-0 3 36. 4 1 .OE-0 3 2,3,4,6,7,8-HxCD F 0.1 0 22 6 6.4E-0 3 15 1 4.2E-0 3 71. 1 2.0E-0 3 i,2j,7,8\9^HxCD F 0.1 0 52. 1 1.5E-0 3 32. 0 8.9E-0 4 18. 5 5. 1 E-0 4 1,2,3,4,6,7,8-HpCD F 0.0 1 22 0 6.2E-0 4 13 1 3.6E-0 4 57. 1 1.6E-0 4 1,2,3,4,7,8,9-HpCD F 0.0 1 69. 6 2.0E-0 4 21. 6 6.0E-0 5 (11,7).
. O.OE+00 OCD F TOTA I TF.O s inolm 0.00 1

n 120 ^ 3.4E-0 5 0.05 1 30. 6 8.5E-0 6

0.04 5 15. 1 4.2E-0 6

0.02 6 TOTA LTEQ s (ng/m 3@ 7 % 0 2 ) = TOTA LTEQ s (g/s) 0.06 7 1.4E-1 0 0.06 0

1.2E-1 0 0.03 5

7. 1 E-1 1 (a ) U.S.EP A(1989) Toxi cEquivalenc yFacto r Note : "Non-detect " value s ar e show n i n parenthese s an d treate d a s zer o i n th e calculatio n o fconcentratio n o n aTE Q basis
.

J:\Air_Tox\ProjectFiles\0nyx\Onyx20D4\May 2004\050 4 Fina l Reportdo c 2- 4 July . 2004

# ENkR . INTERNAT/OMAL Tabl e 2- 4 ONYXRoia^4€S n Uni t2 Mercur yEmissio n Result s Ru n No
. Ru n 1 Ru n 3 Ru n 4 Dat e 05-May-04 06-May-0 4 06-May-0

4 StartTim e Unit s 9:3 5 10:1 0 14:1 5 Sto p Tim e 12:1 1 13:0 0 16:5 3 AVG S Samplin g Parameters — Barometri cPressur e in
. H g 29.5 5 29.5 5 29.5 2 Volum e Metere d dcf 80.78 1 90.37 9 92.51 6 87.89 2 Sampl e Volum e dsc f 74.58 7 82.73 0 83.26 0 80.19 2 Moistur e % v/ v 44. 5 45. 6 44. 4 44. 8 O za tStac k %dr y 10.4 0 10.5 0 10.5 0 10.4 7 Avg
. Stac k

Temp
. o p 36 4 37 0 37 1 36 8 Stac k Flowrat e dscf m 5,11 2 5,56 5 5,70 9 5,46 2 Isokinetic s % 10 0 10 2 10 0 10 1 Mercur v(He) — V M QuantityCollecte d u g 25. 3 23. 8 19. 6 22. 9 Stac k Cone
. @ 7 % 0 2 pg/m 3 15. 8 13. 5 11. 1 13. 5 Stac k Emissio n Rat e Ib/h r 2.29E-0 4 2.12E-0 4 1.78E-0 4 2.06E-0 4 g/se c 2.89E-0 5 2.67E-0 5 2.24E-0 5 2.60E-0 5

J:\Air_Tox\ProjectFiles\Onyx\Onyx 2 004\Ma y 2004\050 4 Fina l Reportdo c 2- 5 July . 2004

# EPKB . INTERNATIONAL Tabl e 2- 5 0N¥X-FixW1Heart h Incinerato rUni t4 Mercur yEmissio n Results Ru n No
. Ru n 1 Ru n 3 Ru n 4 Dat e 5/4/2004 5/4/200 4 5/4/200

4 StartTim e Unit s 8:4 5 12:3 2 14:4 8 Sto p Tim e 10:4 6 14:3 3 16:4 9 AVG S Samplin g Parameter s — Barometri cPressur e in
. H g 29.4 5 29.4 5 29.4 5 Volum e Metere d dc f 81.63 3 79.63 3 78.46 6 79.91 1 Sampl e Volum e dsc f 78.14 6 74.41 6 73.49 8 75.35 3 Moistur e % v/ v 42. 0 41. 7 42. 9 42. 2 O zatStac k %dr y 12.9 0 12.8 0 12.8 0 12.8 3 Avg
. Stac k

Temp
. ° F 38 4 39 2 39 3 39 0 Stac k Flowrat e dscf m 17,70 8 17,78 8 17,82 8 17,77 5 Isokinetic s % 10 6 10 0 9 9 10 2 Mercur y(He ) — V M Quantit yCollecte d M 9 8. 4 22. 2 35. 5 22. 1 Stac k Cone
. @ 7 % 0 2 Mg/m 3 6. 6 18. 0 29. 1 17. 9 Stac k Emissio n Rat e Ib/h r 2.53E-0 4 7.0 3 E-0 4 1.14E-0 3 6.98E-0 4 g/se c 3.19E-0 5 8.86E-0 5 1.43E-0 4 8.80E-0 5

J:\Air_Tox\ProjectFiles\Onyx\Onyx2004\Ma y 2004\050 4 Fina l Report.do c 2- 6 July , 20043. 0 SAMPLIN G AN D ANALYTICA L PROCEDURE S

3. 1 Samplin g Procedure s Severa l differen tsamplin g an d monitorin g technique s wer e use d t o provid e th e require d dat at o mee t th e goal s ofthi s tes tprogram . Thre e run s wer e conducte d o n Unit2 an d Uni t4 a ton e operatin g conditio n establishe d b yOnyx
. Th e samplin g activitie s describe d belo wwer e conducte d durin g al l runs . Al l fiel d activitie s wer e documente d i n accordanc e wit h EP Aaccepte d procedure s an d copie s o f al l fiel d note s an d dat asheet s ar e include d i n Appendi xAo fthi s repor t 3.1. 1 Velocity , Moistur e an d Fixe d Ga s Determination s Ga s strea m velocit yan d temperatur e wer e determine d i n conjunctio n wit h eac h manua l samplin g method
. Atyp e "S " pito ttub e connecte d t o a n incline d wate rmanomete rwa s use d t o determin e velocit yhea d o fth e flu e ga s a teac h duc ttravers e poin ta s specifie d i n EP AReferenc e Metho d 2
. Th e temperatur e profil e o fth e flu e ga s a teac h travers e poin twa s obtaine d b ytakin g reading s with a thermocoupl e an d pyromete rconcurren twit h th e velocit yhea d measurements . Moistur e conten twa s determine d a s specifie d i n EP AMetho d 4
. Sample s fo rth e determinatio n o fth e fixe d ga s compositio n wer e collecte d usin g a n integrate d ba g techniqu e a s detaile d i n EP AReferenc e Metho d 3
. 3.1. 2 PCDD/PCD FSamplin g Samplin g fo rdioxin s an d furan s wa s complete d i n accordanc e wit h EP AMetho d 23 A(4 0 CF R 60 , Appendi xA)
. Thre e isokineti csamplin g run s wer e conducte d o n Uni t2
. Eac h samplin g ru n wa s 3 hour s i n duratio n coverin g 1 2 samplin g point s a t1 5 minute s pe rpoin t 3.1. 3 Metal s Samplin g Amodifie d EP AMultipl e Metal s Trai n (EP AMetho d 29,4 0 CF R 6 0 Appendi xA ) wa s utilize d durin g th e testin g progra m fo rth e collectio n o fmercury . Th e samplin g trai n consiste d o fa glas s butto n hoo k nozzle , a glas s liner , a filterhousin g an d a serie s o ffou rglas s impinger s tha tcontaine d 25 0 m l o f acidifie d potassiu m permanganate . Ru n time s wer e 12 0 minute s i n duratio n an d involve d isokineti c samplin g a t1 2 samplin g point s ( 6 point s pe rtraverse , 1 0 minute s pe rpoint)
.

J:\Air_Tox\ProjectFBes\Onyx\Onyx2004\May 2004\050 4 Fina l Report.do c 3- 1 July , 2004E M S \/A/r£RNATIOMAL 3. 2 Analytica l Procedure s 3.2. 1 PCDD/PCD FAnalyse s PCDD/PCD Fanalyse s wer e performe d b yAlt aAnalytica l Laboratory , Inc
. i n E l Dorad o Hills , CA
. Sampl e fraction s wer e extracted , concentrate d an d analyze d b yEP AMetho d 829 0 (Hig h Resolutio n Ga s Chromatograp h / Hig h Resolutio n Mas s Spectrophotomete r(HRGC/HRMS))
. Th e trai n fraction s recovere d fo ranalysi s o fPCDDs/PCDF s includ e th e fronthal frinse, th e particulat e filter , th e bac k hal f rinse an d th e XA D resi n trap . Th e analytica l result s fo reac h sampl e fractio n wer e combine d int o a singl e analytica l resul tfo reac h run . 3.2. 2 Metal s Analyse s Result s fo rmercuryfro m th e Metho d 006 0 samplin g train s wer e reporte d b ySever n Tren tLaboratorie s i n Wes tSacramento , CA
. I n addition , ENS R performe d blank-correctio n o n th e dat afo rfiel d blan k reagen tcontaminatio n t o th e maximu m exten tallowe d b yMetho d 0060/29
. Mercur ywa s analyze d vi a Metho d 7470 Ab yGraphit e Fumace/Atomi cAbsorptio n Spectrophotometer
. 3. 3 Proces s Operatin g Condition s Throughou tth e fiel d program , detaile d proces s informatio n wa s collecte d continuousl yb yth e facility' s proces s contro l computer s an d dat aacquisitio n syste m (DAS)
. Proces s dat aincludin g minimum , maximu m an d averag e value s fo rke yproces s variable s recorde d durin g eac h tes tcondition
. I n general , target-operatin g condition s specifie d i n th e tria l bu m pla n wer e achieved
.

J:\Air_Tox\ProjectFJes\Onyx\Onyx2004\May 2O04\05O4 Fina l Report.do c 3- 2 July , 20044. 0 QUALIT YASSURANC E

4. 1 Introductio n Thi s sectio n present s th e result s ofal l QA/Q C measure s implemente d durin g th e fiel d samplin g progra m an d al l phase s ofsubsequen tanalysis
. Dat agenerate d fo rth e progra m ar e judge d t o b e vali d a s overal l accurac yan d precisio n result s ar e consisten twit h genera l objectives
. Analytica l QA/Q C dat aar e presente d t o supportal l sampl e result s use d fo rdeterminin g complianc e wit h perfonnanc e criteri ao remissio n standards
. Throughou tth e overal l program , al l samplin g wa s performe d usin g samplin g protocol s describe d herei n an d approve d b yUSEP Aan d the Illinoi s Environmenta l Protectio n Agency
. 4.1. 1 Pre-Samplin g Activitie s Pre-samplin g activitie s include d equipmen tcalibration , sampl e medi apreparation , cleanin g ofsampl e trai n glassware , preparatio n o fcomputer-generate d sampl e label s an d othe rmiscellaneou s tasks
. Eac h o fthes e activitie s ar e describe d o rreference d i n th e followin g subsections
. Othe rpre-samplin g activitie s include d suc h detail s a s tea m meetings , equipmen tpackin g an d shipment , equipmen tsetup , an d finalizatio n o fal l detail s leadin g u p t o th e coordinate d initiatio n ofth e samplin g program . 4.1. 2 Equipmen tCalibratio n Amos timportan taspec to fpre-samplin g preparation s wa s th e inspectio n an d calibratio n o fal l equipmen tuse d fo rthe fiel d effort
. Equipmen twa s inspecte d fo rprope roperatio n an d durabilit yprio r t o calibration
. Calibratio n o fequipmen twa s conducte d i n accordanc e with th e procedure s outline d i n th e EP Adocumen tentitle d "Qualit yAssuranc e Handboo k fo rAi rPollutio n Measuremen tSystems ; Volum e III—StationarySourc e Specifi cMethods " (EPA-600/4-77-027b)
. Equipmen tcalibratio n wa s performe d i n accordanc e wit h EP Aguideline s and/o rmanufacturer' s recommendations
. Example s o f fiel d equipmen tuse d an d typica l calibratio n requirement s follows :



### • PROB E NOZZLE S(Q AHandboo k Sectio n 3.4.2 , pg . 19 ) - measurement s o fthe nozzl e I D (t o th e neares t0.001-in. ) alon g thre e differen tdiameter s wit h a micrometer
. Differenc e betwee n th e hig h an d lo wvalue s shoul d no texcee d 0.00 4 in
. Post-tes tcheck s - inspec t fo rdamage
. 

### • PITO T TUBE S(Q AHandboo k Sectio n 3.1.2 , pp . 1-13 ) - measure d fo rappropriat e spacin g an d dimension s o rcalibrat e i n a win d tunnel
. Rejectio n criteri agive n o n th e calibratio n sheet
. Post-tes tcheck s - inspec tfo rdamage
.

J:\Air_Tox\Projec tFiles\Onyx\Onyx2004\May 2004\050 4 Fina l Report.do c 4- 1 July , 200 4| /NrERNAriOAlAL

•T HERMOCOUPLE S(Q AHandboo k Sectio n 3.4.2 , pp . 15-18 ) - verit yagains ta mercury-in glas s thermomete ra ttw o o rmor e point s includin g the anticipate d measuremen trange . Acceptanc e limit s - impinge r±2°F ; DG M ±5.4°F ; stac k ±1. 5 percen to fstac k

temperature . 

### • DR Y GA S METER S(Q AHandboo k Sectio n 3.4.2 , pp . 1-12 ) - calibrat e agains ta we ttes t meter . Acceptanc e criteri a- pretes tY i = Y±0.2 ; pos ttes tY= ±0.0 5 Yi
. 

### • FIEL D BAROMETER S(Q AHandboo k Sectio n 3.4.2 , pp . 18-19 ) - compar e agains tamercury in-glas s baromete ro rus e Airpor tStatio n B P an d correc tfo relevation
. Acceptanc e criteri a

- ±0.0 2 in
. Hg ; post-tes tcheck s - same . 4.1. 3 Glasswar e Preparatio n Sampl e trai n glasswar e an d sampl e container s require d specialize d pre-cleanin g t o avoi d contaminatio n ofth e sampl e fro m the collectio n containe ro rdevices
. Cleaning/storag e procedure s fo r sampl e trai n glasswar e ar e summarize d below
. Not e tha tal l bottl e cap s ar e fitte d wit h Teflo n liners , whic h wer e cleane d i n th e sam e manne ra s th e bottle s themselves
. Sampl e container s use d fo rwast e fee d stream s ar e purchase d pre-cleane d an d seale d t o specifie d EP Aprotocols
.

•EP A METHO D001 0 / 0023A GLASSWAR EAN D CONTAINER S(PCDDs/PCDFs ) - washe d wit h soa p an d water , rinsed thre e time s wit h deionize d (DI ) water , bake d a t400° C fo r2-hours , rinse d thre e time s wit h pesticid e grad e methylen e chloride , rinse d thre e time s wit h pesticid e grad e toluen e an d ai rdry
.
•EP A METHO D2 9 / 0060 GLASSWAR EAN D CONTAINER S (METALS )- washe d wit h soa p an d water , rinse d wit h ho tta p wate ran d rinsed thre e time s wit h reagen twater . Th e glasswar e wa s soake d i n a 10 % nitri caci d solutio n fo ra minimu m o f4-hours , rinsed thre e time s with reagen twater , rinsed a fina l tim e wit h aceton e an d air-dried
. Al l glasswar e opening s wher e contaminatio n ca n occu rar e covere d wit h Parafil m unti l the samplin g trai n wa s assemble d priort o sampling
. 4.1.3. 1 Samplin g Medi a Preparatio n Al l reagent s wer e checke d i n accordanc e wit h ENSR' s existin g Q C Progra m t o minimiz e th e probabilit y o fusin g contaminate d solvents
. Thi s include d th e us e o fth e prope rgrad e reagents/solvent s a s specifie d i n th e tes tmethod , selectio n o freagent s fro m the sam e lo tan d collectio n an d analysi s o fth e appropriat e blanks
. Samplin g medi awa s procure d an d prepare d i n accordanc e wit h th e appropriat e tes tmethod s a s describe d below :

•XA D resi n use d i n th e Metho d 0023 Atrai n wa s purchase d ne wan d packe d i n speciall ydesigne d sorben ttraps . Al l glas s cleanin g an d sorben tpackin g procedure s followe d th e protocol s specifie d i n EP AMetho d 0023A
.

J:\Air_Tox\Projec tFiles\Onyx\Onyx20O4\Ma y 2004\050 4 Fina l Reportdo c 4- 2 July , 2004•Quart z filter s use d i n th e Metho d 2 9 / 006 0 samplin g trai n wer e purchase d fro m Pallfle xProduct s Co
. wh o pre-scree n filters fo rmetal s content . 4. 2 Chai n o fCustod y Chain-of-custod yprocedure s wer e followe d fo ral l sample s a s follows :

•Eac h isokineti ctrai n wa s set-u p an d recovere d i n a clea n are aadjacen tt o th e incinerators
. •Sample s wer e collected , seale d an d labele d accordingly
. •Sample s wer e packe d i n bubbl e wra p o rothe rabsorben tmateria l an d place d i n sampl e cooler s o rappropriat e DO Tshippin g package s (dangerou s good s items)
. •Associate d chain-of-custody' s wer e place d i n eac h shippin g container
. •Al l sample s wer e subsequentl yshippe d vi aPriorit yOvernigh tFedE xservic e t o the designate d laboratory
. 4. 3 Analytica l QA/Q C Dat aQualit yIndicator s (DQI's ) wer e utilize d throughou tthe progra m t o asses s the validit yo fanalytica l data
. Thi s sectio n provide s a revie wo fthes e indicator s an d th e subsequen timpac to n th e analytica l data
. 4.3. 1 Analysi s fo rPCDDs/PCDF s Evaluatio n o fth e validit yo fth e PCDD/PCD Fdat aresultan tfro m th e analysi s o fth e Metho d 23 A samplin g trai n sample s wa s base d o n fou rset s o fDQIs
. Thes e were :

•Recoverie s o fintemal , pre-spik e surrogate s an d alternat e recover ystandard s adde d t o th e sample s prio rt o sampling ;

- Result s o fanalysi s o fLaboratoryContro l Sample s (LCS ) fo rth e 1 7 PCDD/PCD Fisomer s liste d i n EP AMetho d 23 ;

•Result s o fanalyse s o ffiel d an d metho d blan k sample s fo rPCDD/PCDFs
. Thes e result s ar e include d wit h th e Alt aAnalytica l Dat aRepor tinclude d i n Appendi xD
. O n th e basi s o fthes e Q C results , n o sampl e analyse s wer e rejecte d an d al l th e dat awer e determine d t o b e valid
. 4.3. 2 Analysi s fo rMetal s Evaluatio n o fth e validit yo fmetal s dat aresultin g fro m the analysi s o fthe Metho d 2 9 samplin g trai n sample s wa s base d o n th e followin g tw o set s ofDQI's :

J:\Air_Tox\Projec tFiles\Onyx\Onyx2004\May 2004\050 4 Fina l Repor tdo c 4- 3 July , 2004

# E*H t \//iT£Flt/AT/OAIAL

•Recoverie s o finternal , pre-spik e an d alternat e recover ystandard s adde d t o th e sample s prio r t o sampling
. Recoverie s o fthes e standard s ar e include d wit h othe ranalytica l dat ai n Appendi xD
. •Result s o fanalyse s o ffiel d an d metho d blan k sample s fo rmetals
. Thes e result s ar e include d i n Appendi xD
. O n th e basi s o fthes e Q C results , n o sampl e analyse s wer e rejecte d an d al l th e dat awer e determine d t o b e valid
. Completenes s wa s therefor e determine d t o b e 100 % fo ral l metal s result s fro m al l samples
.

J:\Air_Tox\Projec tFiles\Onyx\Onyx2004\May 2004V050

4 Fina l Reportdo c 

## 4-4 July , 200 4APPENDI XA FIEL D DAT ASHEET S

J:\Ar_T0K\Projec tFiles\OnyxV0ny x2004\Ma y2O04VApperK &Covera.do c Jul y200 4PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T FO R MOISTUR E DETERMINATIO N Sample Train: Recovered by: 

## Run No. Ut9

- ~ ggt e

## • [Run No. &f Date: S~ XAD Module No. \XAD Module No.: FilterNo., FilterNo.: 3 Impinge r No
. Initia l

Volum e (mL ) Fina l

Volum e (mL )

iff - Rins e Volum e (mL) Impinge r

No
. Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL )



## f (ffi J H 

## /av /so

DIF F DIFF : Total s Total s

Initia l Weigh t (9 ) Fina l

Weigh t (9 ) DIFF : Initia l Weigh t (9 ) Fina l

Weigh t (9 ) DIFF :

### Metho d 0023 ASamplin g Parameter s Uni t2 Ru n No . U2-R 1 Ru n 3 Ru n 4 Dat e 05-May-0 4 06-May-0

4 06-May-04 

### StartTim e Unit s 9:3 5 10:1 0 14:1 5 Sto p Tim e 12:3 8 11:4 3 17:2 3 AVG S Nozzl e Diamete r inche s 0.42 9 0.42 9 0.42 9 0.42 9 Barometri cPressur e in
. H g 29.4 5 29.5 5 29.5 5 29.5 2 Ne tSamplin g Tim e min
. 176. 7 180. 0 180. 0 178. 9 Volum e Metere d dc f 133.77 0 135.72 0 138.89 7 136.12 9 Avg
. DG M Temp
. ° F 81. 2 84. 9 91. 8 85. 9 Av g Delt aH i n H 2 

### 0 1.78 1.74 1.8 0 1.7 7 Av g Delt aH in
. H g 0.130 5 0.128 1 0.132 4 0.130 3 DG M Calibratio n Facto r — 

### 0.973 0 0.973 0 0.973 0 0.973 0 Ga s Sampl e Volum e dsc f 125.541 126.93 1 128.30 2 126.925 Tota l Wate rCollecte d m L 1960. 9 2178. 1 2083. 1 2074. 0 Volum e o fWate rVapo r sc f 92.45 6 102.69 7 98.21 8 97.79 1 Moistur e (measured ) % v/ v 42. 4 44. 7 43. 4 43. 5 Moistur e ( @ saturation ) % v/ v 101. 5 101. 2 101. 2 101. 3 Dr yMol e Fraction , 100-% M — 

### 0.575 9 0.552 8 0.566 4 0.565 0 C 0 2

### a tStac k %dr y 4.5 0 4.2 0 4.3 0 4.3 3 0 2

### a tStac k %dr y 10.4 0 10.5 0 10.5 0 10.4 7 C O + N 2 

### %dr y 85.1 0 85.3 0 85.2 0 85.2 0 Di yMolecula rWeigh t Ib/lb-mole 

### 29.1 4 29.0 9 29.1 1 29.1 1 We tMolecula rWeigh t Ib/lb-mole 

### 24.4 1 24.1 3 24.2 9 24.2 8 Exces s Ai ra tStac k % 86. 2 87. 4 87. 6
. 87. 0 Stac k Diamete r inche s C"39.0 } ) 39. 0 / 39. 0 39. 0 Stac k Are a sq . in
. :ir94 ^ 1194:6 ' 1194. 6 1194. 6 Stati cPressur e i n H 2 

### 0 r 

### 0.3 0 "~ ~ 073 1 —031 5 Stac k Pressur e in
. H g 29.4 7 29.5 7 29.5 7 29.5 4 Avg
. Stac k

Temp
. ° F 363. 3 377. 8 377. 7 372. 9 Avg
. Sqroo to fDelt aP — 

### 0.417 1 0.417 2 0.424 0 0.419 4 SD E Averag e — 

### 11.96 6 12.07 7 12.27 3 12.10 5 Pito tCoefficien t — 

### 0.8 4 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocit y afp m 1,922^ 1,94 8 1,97 3 1,94 8 Stac k Flowrat e we tacf m 15,94 8 16,16 1 16,36 9 16,15 9 Stac k Flowrat e we tscf m 10,07 5 10,06 7 10,19 8 10,11 3 Stac k Flowrat e dscf m 5,80 2 5,56

4 5,77

6 5,71 * Isokinetic s % 10 1 10

5 10

2 10

3 Mete rBo xNo
. — 

### 8075 4 8075 4 8075 4 — 

### Delt aH @ in
. H g 1.915 1 1.915 1 1.915 1 — 

### Fiel d QAYq c — 

### 0.96 9 0.96 6 0.96 6 0.96 7 [Deviation ] Pre- Y % 0.4 % 0.7 % 0.8 % 0.6 % J:\Air_Tox\Projec

tFiles\Onyx\Ony

x2CKM\Ma

y2004\[U 2 M 0O23

AisojdsJDAT

AMetho d 2 9 Metal s Samplin g Parameter s UNI T4 Ru n No
. Ru n 1 Ru n 3 Ru n 4 Dat e 5/4/200 4 5/4/200 4 5/4/200 4 Star tTim e Unit s 84 5 123 2 144 8 Sto p Tim e 104 6 143 3 164 9 AVG S Nozzl e Diamete r inche s 0.28 3 0.28 3 0.28 3 0.28 3 Barometri cPressur e in
. H g 29.4 5 29.4 5 29.4 5 29.4 5 NetSamplin g Tim e min
. 120. 0 120. 0 120. 0 120. 0 Volum e Metere d dc f 81.63 3 79.63 3 78.46 6 79.91 1 Avg
. DG M Temp
. op 70. 2 83. 0 81. 7 78. 3 Av g Delt aH i n H 2 0 1.5 0 1.39 1.38 1.42 Av g Delt aH in
. H g 0.109 9 0.102 0 0.101 1 0.104 4 DG M Calibratio n Facto r - - 0.973 0 0.973 0 0.973 0 0.973 0 Ga s Sampl e Volum e dscf 78.14 6 74.41 6 73.49 8 75 .353 Tota l Wate rCollected m L 1198. 5 1129. 3 1118. 1 1148. 6 Volum e ofWate rVapo r scf 56.50 9 53.24 6 52.71 8 54.15 8 Moisture (measured ) %v/v 42. 0 41. 7 41. 8 41. 8 Moisture ( @ saturation ) %vA/ 101. 7 101. 7 101. 7 101. 7 Dr yMol e Fraction , 100-% h — 0.580 3 0.582 9 0.582 3 0.581 9 C 0 2atStac k %dry 4.6 0 4.0 0 4.3 0 4.3 0 0 2atStac k %dry 12.9 0 12.8 0 12.8 0 12.8 3 C O + N 2 %dry 82.5 0 83.2 0 82.9 0 82.8 7 Dr yMolecula rWeigh t Ib/lb-mol e 29.2 5 29.1 5 29.2 0 29.2 0 WetMolecula rWeigh t Ib/lb-mol e 24.5 3 24.5 0 24.5 2 24.5 2 Exces s Ai ratStac k % 145. 3 139. 7 140. 9 141. 9 Stac k Diamete r inche s V
. 48.0 > 48. 0 48. 0 48. 0 Stac k Are a sq . in
. 1809. 6 1809. 6 1809. 6 1809. 6 Stati cPressur e i n H 2 0 -0.4 4 -0.4 6 -0.4 4 -0.4 5 Stac k Pressur e in
. H g 29.4 2 29.4 2 29.4 2 29.4 2 Avg
. Stac k

Temp
. op 384. 0 392. 1 393. 1 389. 7 Avg
. Sqroo tofDelt aP 

# - 0.847 1 0.850 7 0.868 7 0.855 5 SD E Averag e ~ 24.60 9 24.83 3 25.37 2 24.93 8 PitotCoefficien t — 0.8 4 0.8 4 0.8 4 0.8 4 Stac k Ga s Velocity afp m 3,94 8 3,98 6 4,07 1 4,00 1 Stac k Flowrat e wetacf m 49,60 8 50,08 9 51,15 4 50,28 4 Stac k Flowrat e wetscf m 30,51 3 30,51 6 31,12 9 30,71 9 Stac k Flowrat e dscf m 17,70 8 17,78

8 18,12

7 17,87

4 Isokinetics % 10 ® ' 10

0 ' 9

7 " 10

1 \ Mete rBo xNo
. — 8075 4 8075 4 8075 4 - - Delt aH @ i n Hj O 1.915 1 1.915 1 1.915 1 — Field Q AYq c — 0.978 2 0.979 4 0.987 5 0.981 7 [Deviation ] Pre- Y % 0.53 % 0.66 % 1 .49 % 0.90 % J:\Air_TOK\Projsc

tRles\On)nAOny

s 2004\Ma

y2004\[U4 M2

8 Iso.xIsJDAT

AORSA TANALYSI S (EP AMETHO D 3) PLANT : On ^a DATE : J T SOURCE : 

### SAMPL ETYP E OPERATOR : PRE-LEA KCHECK : POST-LEA KCHECK : NOTE : • <i/ai d Leak

Check : Liqui

d level mus

tno tfal l ^beio wbotto m o fcapillar ytubin g i n 4 minute

s an d meniscu

s mus tno tchang e b ymor e tha n 0. 2 m L i n 4 minutes

. NOTES / DAT ACRITERIA- C 0 2 : Whe n greate rtha n 4% , difference betwee n reading s shal l b e 0.3 % o rless
. Whe n les s tha n 4% , difference betwee n reading s shal l b e 0.2 % o rless
. O z: Whe n greate rtha n o requa l to 15% , difference betwee n reading s shal l b e 0.2 % o rless
. Whe n les s tha n 15% , difference betwee n reading s shal l b e 0.3 % o rless
. Run#^H - ft. 1 Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net co 2 O z 13- 0 17,4- Run *U H -r t^-Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net c o 2 tf -. o o 2 />.s Ru n #U M (If

Readin g A Readin g B Readin g C Avg
. Net GA S Actua l Ne t Actua l Net Actua l Net Avg
. Net C 0 2 f . v 

### + f V- 3 0 2 17. 0 f7. 0 Ru n # Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net co 2 o 2 Ru n # VAR

- R 1 Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net co 2 

# %< t-< 

# ^< y . r Oa 

### ISCO /©•< " 

### IS~° jo- y Run *U> - &3

Readin g A Readin g B Readin g C Avg
. Net GA S Actua l Net Actua l Net Actua l Net Avg
. Net co 2 

### f r \ r Hz

### 7- o 2 

### i i i 10$ Run *U > 

### -

<l>f Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net co 2 

### 1.3 o 2 

### /Y.t /t>. ^ If.7 /». r Run * Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net C 0 2 o 2 Run * Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net c o 2 o 2 Run * Readin g A Readin g B Readin g C Avg
. GA S Actua l Net Actua l Net Actua l Net C 0 2 o 2

# ENSR . PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train: Recovered by: Ji ^

r\of-r\% Run No. U3i-^ i Date: f-S~-of Run No. U 9 —Date : S~S~°T XAD Module No.: XAD Module No.: 1 FilterNo. : Q^^^l^- FilterNo.: <?(A«M-4 -1
_ Impinge r No
. Initia l

Volum e (mL ) Fina l

Volum e (mL ) Rins e

Volum e (mL ) impinge r

No
. Initia l

Volum e (mL) Fina l

Volum e (mL ) Rins e

Volum e (mL )
1 XO 

## ^~ 1
2 /oa 2 /(TO 

### J/J .
3 /

o 0 f 3 / o D / o - 4 0 4 O 

## r 5 5
6 6 

# V r 7 7 DIF F : DIFF : Total s Total s

Initia l Weigh t (g ) Fina l

Weigh t (g ) Initia l Weigh t (g ) Fina l

Weigh t (9 ) Initia l Weigh t (g ) Fina l

Weigh t (g ) DIF F : Initia l Weigh t (g ) Fina l

Weigh t (9 ) DIFF : Silic a Ge l Impinge r 

# \ ^ Silic a Ge l Impinge r Ne tH 2 0 Gain , m L Ne tH 2 0 Gain , m L

# lil . E P AISOKINETI C SAMPLIN G - FIEL B BAT ASHEE T ::-:tMPif«sEHVoL > s;:: j Orsa

t Samplin g Trai n M

21 Barometri c Pressur e J*). JTy *// * LEA

KCHECK S I n "H g :-:»irr.:':-: - •:FINAL:-:-:-: ' 3UNS E :co2 : •:-:o2:- Ru n Numbe rRUL/I

H Stati c Pressur e (4/- ) 

## o.?a ' INITIA

L VA C /<f in

. CF M 0 ,OC^L <<t

> 

## io/st (O.f Clien t 

## MY* Probe/Pito tNumbe r

## jj.K-H'ti MI

D VAC . - — in

. CF M , (O.f Facilit yLocatio n So u Pito tCc*fflclen t FINA L VA C 7 in

. CF M 0. ddc l ft ? /O.S Sourc e Filte rBo xNo . + • + - o & ft ? /O.S Dot e Mete rBo zNo . 

## 86CfX INIT . PITO T FINA

L PITO T 

## 76. < Operato r li^^is Chine e Coefficien t0 0 Q . 0, f7 J FILTE RDAT A 

## 76. < Stac k Dia.-in. 2<J"

' Delt a H @ 

## •y,mm&;-:- ^ • ^ 

## /o.) Star tTim e Nozzl e Size/No . Sto p Tim e XT75 //-<?

% XA D Thermocoupl

e ID : Jl JjA : .:.:. : .:.SlWCAfiEi>::::-:- Fina

l Purg e Rat e Im p Outle tT C ID : 

## Mo Fina l P H
. wtocrr v iiiiiiii^fiE^iiii i TEMPERATUR E REAilNGS , 0 F jiilliwHijpiiiiil TOI1VC TIM S BEAK Msswvtut, ; 

## warn iiiYioljiji ^j ; OOMMEJST

S beuaELintfi ! MODIft E iiiiiiiiiii ; iijiiiiist^riiiii i jiiiii&i ;itti :i;i ; 1 O 

## o./<> / . 9 J6 ? s§/ /A 9J. ? d 

## a./st J.O /v\7. o 36,9 ~JSJ S7 ? 0 

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0 83.26

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# ENS ? PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T

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# mmmmmmm

MMUni t4

P T RU N 1 AVG S - METAL S RU N 3 AVG S - METAL S RU N 4 AVG S - METAL S P T Delt

a P SQR

T Delt a P DGM

I N DGM OU T Delt

a H STAC K TEM P Delt

a P SQR

T Delt a P DGM

I N DGM OU T Delt

a H STAC K TEM P Delt

a P SQR

T Delt a P DGM

I N DGM

OU T Delt

a H STAC K TEM P a 1 0.4

5 0.6708 58 58 0.9 2 350 0.7

6 0.871 8 8

2 7

7 1.6

0 38

5 0.8

2 0.905

5 79 77 1.5 0 387 a 2 0.6

2 0.787

4 66 6

2 1.3

0 37

4 0.7

6 0.871 8 8

6 78 1.6

0 389 0.8

8 0.9381 8

5 79 1.6

0 392 a 3 0.7

7 0.877

5 7

1 6

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5 8

8 79 1.7

0 391 0.8

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5 8

6 79 1.5

0 392 a 4 0.7

7 0.877

5 73 6

5 1.6

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9 0.7

8 0.883

2 91 8

1 1.6

0 39

5 0.7

5 0.8660 8

5 78 1.4

0 393 a 5 0.8

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0 38

4 0.71 0.8426 9 0 8

2 1.3

0 39

7 0.7

0 0.8367 8

6 79 1.3

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8 0.883

2 74 67 1.6 0 38

5 0.59 0.7681 8 9 8

2 1.1 0 39

6 0.59 0.768 1 87 80 1.1 0 39 5 b 1 0.4

5 0.6708 74 68 0.9 2 37

5 0.7

7 0.877

5 8

4 79 1.4

0 38

7 0.7

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2 87 8

0 1.4

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3 0.854

4 77 7

0 1.5

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5 7

9 1.5

0 391 0.7

4 0.860

2 8

8 81 1.3

0 39

2 b 3 0.7

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5 8

0 7

2 1.6

0 39

5 0.8

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5 79 1.5

0 39

0 0.8

2 0.9055 86 79 1.5 0 390 

## iA 0.86 0.927 4 79 71 1.8 0 39

6 0.7

7 0.877

5 8

8 8

0 1.4

0 39

5 0.7

9 0.888

8 86 78 1.4 0 39

3 b 5 0.8

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4 0.61 0.781 0 8 6 79 1.1 0 39 6 0.7

4 0.860

2 8

2 76 1.3

0 39

7 b 6 0.8

2 0.9055 79 71 1.7 0 39

3 0-4

7 0.6856 8

5 7

8 0.8

5 39

3 0.6

5 0.806

2 8

2 76 1.2

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3 0.8471 70. 2 1.5 0 38 4 0.7 3 0.850

7 83. 0 1.3 9 39 2 0.76 I 0.868

7 81. 7 1.3 8 39 3Uni t2

P T RUNl / LVGS-PCD ] Ds/PCDF s RU N 3 AVG S - PCDDs/PCDFs RU N 4 AVG S - PCDDs/PCDF s P T D P SQR T

D P DG M

IN DG M OU T D H STAC K

TEM P D P SQR T

D P DG M

IN DG M OU T D H STAC K

TEM P D P SQR T D P DG M

IN DG M OU T D H STAC K

TEM P a 1 0.1 9 0.4359 54 53 1.9 0 34

2 0.1 8 0.424

3 7 5 7 4 1.8 0 37

5 0.1 8 0.424 3 66 8

5 1.8

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3 6 5 5 5 1.8

0 356 0.1 7 0.4123 8 2 7 5 1.7

0 37

5 0.1 9 0.4359 9 2 8 6 1.8

0 37

9 a 3 0.1 8 0.424

3 70 60 1.8 0 357 0.1 8 0.424 3 8 6 77 1.8

0 37

7 0.1 9 0.4359 9 4 8 8 1.9

0 37

9 a 4 0.1 8 0.424

3 7 5 64 1.8

0 357 0.1 8 0.424 3 8 8 8 1 1.8 0 37

7 0.1 5 0.387 3 9 5 8 9 1.5

0 378 a s 0.1 9 0.4359 79 6 8 1.9 0 35

7 0.1 8 0.424

3 89 8

0 1.8 0 37

8 0.1 9 0.4359 96 9 0 1.9

0 37

8 a 6 0.1 7 0.4123 8 2 7 1 1.7 0 358 0.1 7 0.4123 9 0 8 1 1.7 0 37

8 0.1 7 0.4123 9 6 8 9 1.7

0 37

6 b 1 0.1 7 0.4123 9 4 8 6 1.7 0 357 0.1 6 0.400 0 8 4 8 2 1.6 0 37

7 0.1 8 0.424 3 9 4 8 9 1.8

0 37

7 b 2 0.1 6 0.400

0 99 89 1.6 0 37

3 0.1 8 0.424

3 9 0 8 3 1.8 0 379 0.1 8 0.424 3 9 5 89 1.8

0 376 b 3 0.1 7 0.4123 10 1 9 1 1.8 0 37

4 0.1 8 0.424

3 9 3 8 4 1.8 0 38

0 0.1 9 0.4359 9 7 9 0 1.9

0 37

7 b 4 0.1 6 0.400

0 10 3 9 3 1.7 0 37 5 0.1 6 0.400

0 9 4 8 6 1.6 0 38

0 0.1 8 0.424 3 9 6 9 1 1.8

0 37

9 b 5 0.1 9 0.4359 10 4 9 5 2.0

0 37

6 0.1 7 0.4123 9 5 8 6 1.7 0 37

9 0.1 7 0.4123 9 8 9 1 1.7

0 37

9 b e 0.1 5 0.387

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7 0.1 8 0.424

3 9 5 8 7 1.8 0 37

9 0.1 9 0.4359 9 6 9 0 1.9

0 37

7 AV G 0.1 7 0.4171 81. 2 1.7 8 36 3 0.1 7 0.417

2 84. 9 1.7

4 37 8 0.1 8 0.424

0 91. 8 1.

8 37 8Samplin g Trai n

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### PRELIMINAR YSAMPL E TRAI N RECOVER YDATASHEE T

FO R MOISTUR E DETERMINATIO N Sample Train : U - * V Recovered by : \J\

r*-\ j

^-i. « r^.f 2 l S Run No. Q^-j ^ \

Date: ^ t

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### PRELIMINAR YSAMPL E TRAI N RECOVER YDAT ASHEE T FO R MOISTUR E DETERMINATIO N Sample Train : 

## - < a 

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3, Date ; Run No. 

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1 

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7 7 DIFF : DIFF : Total s Total s

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Weigh t (g ) DIFF : Silic a Ge l Impinge r 

## 3

3 Silic a Ge l Impinge r Ne tH 2 0 Gain , m L — Ne tH 2 0 Gain , m L —APPENDI XB PROCES S FEE D AN D OPERATIN G CONDITION S

J:\AJr_Tox\Prajec

tFites\OtiyrfOny » 20O4\Ma y2004\Appa«li xCoventdo c Jul y200 4y'Ony xEnvironmenta l Services , Sauget , I L uni t 2 Proces s Operatin g Dat a - May200 4 Tes t Progra m

Operatin g Paramete r R 1 R 3 R 4 Averag e Pumpabl e Wast e (Ib/hr

) 305 1 313 1 282 7 300 3 Non-pumpabl e Wast e (Ib/hr ) 109 8 132 7 110 9 117 8 Tota l Wast e (Ib/hr

) 414 9 445 8 393 6 418 1 Stackflo w(acfm ) 1511 0 1581 1 1594 9 1562 3 PC C Tem p (de g F ) 173 9 170 6 169 1 171 2 SC C Tem p (de g F ) 184 6 184 0 183 5 184 0 B.H
. InletTem p (de g F ) 42 1 42 0 42 0 42 0 Mercury(Ib/hr

) 0.0004 7 0.0017 0 0.0006 7 0.0009 5 Chlorin e (Ib/hr

) 26 2 24 7 24 2 25 0 As h (Ib/hr

) 229 5 252 9 206 0 229 5

## Ony xEnvironmenta l Services , Sauget , I L

Uni t4 Proces s Operatin g Dat a - May2004 Tes tProgra m

Operatin g Paramete r R 1 R 3 R 4 Averag e Pumpabl e Wast e (Ib/hr ) 328 6 329 8 329 1 329 2 Non-pumpabl e Wast e (Ib/hr ) 1088 7 1102 6 924 7 1038 7 Tota l Wast e (Ib/hr

) 1417 3 1432 4 1253 8 1367 8 Stackflo w(acfm ) 4047 2 3977 9 3993 4 4006 2 PC C Tem p (de g F ) 151 2 148 1 149 5 149 6 SC C Tem p (de g F ) 193 7 189 2 189 4 190 8 B.H
. InletTem p (de g F ) 41 9 41 9 42 0 41 9 Mercury(Ib/hr

) 0.011 5 0.013 1 0.010 2 0.011 6 Chlorin e (Ib/hr

) 15 2 16 4 15 9 15 8 As h (Ib/hr

) 1013 0 1043 8 1006 3 1021 0 Carbo n (Ib/hr

) 6 6 6 6

### Ony xEnvironmenta l Services , Sauget , I L Uni t2 , Ru n 1 Wast e Fee d Dat a -Ma y200 4 Tes tProgra m

Uni t# 2 Run# 1 Date : 05/05/0 4 Tes tTime : 09:3 5 t o 12:3 8 Chlorin e As h Mercur y PP M Feedrat e Loadin g Loadin g Loadin g Wast e Typ e Btu/l b %Chlorin e %As h Mercur y (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) PC C Hig h Bt u 486 0 0. 5 5 3 0.4 6 84 7 4.2 4 448.9 1 0.00039 0 PC C Lo wBt u 166 0 0.8 8 4 4 0.0 2 179 9 15.8 3 791.5 6 0.00003 6 PC C S p Fd r 85 0 0. 5 8. 7 0.0 2 38 7 1.94 33.6 7 0.00000 8 (Chlorin e Spike ) 231 0 85. 5 3 3 0.02 1 11 9 101.7 5 39.2 7 0.00000 2 PC C Soli d Charge s 50 0 0. 5 9 8 0.03 2 86 6 4.3 3 848.6 8 0.00002 8 HC E (Chlorin e Spike ) 251 0 89. 9 8 9 0.0 2 14 9 133.9 5 132.6 1 0.00000 3 CaCI 2 (Chlorin e Spike ) 50 0 56. 9 0 0.0 0 0.0 0 0.00000 0 Total s 262.0 3 2294.7 0 0.00046 7

### Ony xEnvironmenta l Services , Sauget , I L Uni t2 , Ru n 3 Wast e Fee d Dat a -Ma y200 4 Tes tProgra m

Uni t# 2 Ru n # 3 Date : 05/06/0 4 Tes tTime : 10:1 0 t o 13:3 0 Chlorin e As h Mercur y PP M Feedrat e Loadin g Loadin g Loadin g Wast e Typ e Btu/l b %Chlorin e %As h Mercur y (lb/hr ) (Ib/hr) (Ib/hr) (Ib/hr) PC C Hig h Bt u 514 0 0. 5 5 2 1. 8 84 5 4.2 3 439.4 0 0.00152 1 PC C Lo wBt u 50 0 0. 5 5 8 0.0 6 177 5 8.8 8 1029.5 0 0.00010 7 PC C S p Fd r 88 0 0. 5 2. 6 0.0 2 46 5 2.3 3 12.0 9 0.00000 9 (Chlorin e Spike ) 308 0 85. 5 3 3 0.03 2 12 2 104.3 1 40.2 6 0.00000 4 PC C Soli d Charge s 50 0 0. 5 9 8 0.06 9 85 3 4.2 7 835.9 4 0.00005 9 HC E (Chlorin e Spike ) 310 0 89. 9 9 1 0.0 2 6 3 56.6 4 57.3 3 0.00000 1 CaCI 2 (Chlorin e Spike ) 50 0 56. 9 98 0.0 2 11 7 66.5 7 114.6 6 0.00000 2 Total s 247.2 1 2529.1 8 0.00170 3

### Ony xEnvironmenta l Services , Sauget , I L Uni t2 , Ru n 4 Wast e Fee d Dat a -Ma y200 4 Tes tProgra m

Uni t# 2 Ru n # 4 Date : 05/06/0 4 Tes tTime : 14:1 5 to 17:2 3 Chlorin e As h Mercur y PP M Feedrat e Loadin g Loadin g Loadin g Wast e Typ e Btu/l b %Chlorin e %As h Mercur y (lb/hr ) (Ib/hr) (Ib/hr) (Ib/hr) PC C Hig h Bt u 519 0 0. 5 5 1 0.7 7 77 8 3.8 9 396.7 8 0.00059 9 PC C Lo wBt u 70 0 0. 5 4 0 0.0 2 161 4 8.0 7 645.6 0 0.00003 2 PC C S p Fd r 61 0 0. 5 2 0.0 2 34 8 1.7 4 6.9 6 0.00000 7 (Chlorin e Spike ) 348 0 85. 5 3 3 0.02 5 11 9 101.7 5 39.2 7 0.00000 3 PC C Soli d Charge s 50 0 0. 5 9 7 0.03 5 82 7 4.1 4 802.1 9 0.00002 9 HC E (Chlorin e Spike ) 277 0 89. 9 9 2 0.0 2 6 3 56.6 4 57.9 6 0.00000 1 CaCI 2 (Chlorin e Spike ) 50 0 56. 9 9 7 0.0 2 11 5 65.4 4 111.5 5 0.00000 2 Total s 241.6 5 2060.3 1 0.00067 4

### Ony xEnvironmenta l Services , Sauget , I L Uni t4 , Ru n 1 Wast e Fee d Dat a - Ma y200 4 Tes tProgra m

Uni t# 4 Run# 1 Date : 05/04/0 4 Tes tTime-08:4 5 t o 10:4 6 Chlorin e As h Mercur y PP M Feedrat e Loadin g Loadin g Loadin g Wast e Typ e Btu/l b %Chlorin e %As h Mercur y (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) PC C Hig h Bt u 457 0 0. 5 5 3 0.0 2 101 5 5.0 8 537.9 5 0.00002 0 PC C Lo wBt u 192 0 0. 5 5 5 1. 3 145 8 7.2 9 801.9 0 0.00189 5 PC C Chlorin e Spik e (X-10 ) 268 0 85. 5 2 0.0 2 10 7 91.4 9 2.1 4 0.00000 2 PC C Soli d Charge s 50 0 0. 5 8 5 0.1 9 156 0 7.8 0 1326.0 0 0.00029 6 (MercurySpike ) 50 0 0. 5 2 490 0 1.84 0.0 1 0.0 4 0.00901 6 PC C Bul k

Solid s 50 0 0. 5 9 8 0.03 9 760 4 38.0 2 7451.9 2 0.00029 7 SC C Hig h Bt u 1033 0 0. 5 2 0.0 2 51 6 2.5 8 10.3 2 0.00001 0 Total s 12,26 2 152.2 6 10130.2 7 0.01153 7

### Ony xEnvironmenta l Services , Sauget , I L Uni t4 , Ru n 3 Wast e Fee d Dat a - Ma y200 4 Tes tProgra m

Uni t# 4 Ru n # 3 Date : 05/04/0 4 Tes tTime : 12:3 2 t o 14:3 3 Chlorin e As h Mercur y PP M Feedrat e Loadin g Loadin g Loadin g Wast e Typ e Btu/l b %Chlorin e %As h Mercur y (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) PC C Hig h Bt u 585 0 0. 5 5 2 0.1 2 106 1 5.3 1 551.7 2 0.00012 7 PC C Lo wBt u 206 0 0. 5 5 4 0.1 8 150 0 7.5 0 810.0 0 0.00027 0 PC C Chlorin e Spik e (X-10 ) 335 5 85. 5 3 6 0.0 2 11 9 101.7 5 42.8 4 0.00000 2 PC C Soli d Charge s 50 0 0. 5 9 8 0.02 5 153 6 7.6 8 1505.2 8 0.00003 8 (MercurySpike ) 50 0 0. 5 2 550 0 1.8 1 0.0 1 0.0 4 0.00995 5 PC C Bul k

Solid s 50 0 0. 5 9 8 0.3 5 766 9 38.3 5 7515.6 2 0.00268 4 SC C Hig h Bt u 1783 0 0. 5 2 0.0 2 61 0 3.0 5 12.2 0 0.00001 2 Total s 12,49 7 163.6 3 10437.7 0 0.01308 9



# " V

### Ony xEnvironmenta l Services , Sauget , I L Uni t4 , Ru n 4 Wast e Fee d Dat a - Ma y200 4 Tes tProgra m

Uni t# 4 Ru n # 4 Date : 05/04/0 4 Tes tTime : 14:4 8 t o 16:4 9 Chlorin e As h Mercur y PP M Feedrat e Loadin g Loadin g Loadin g Wast e Typ e Btu/l b %Chlorin e %As h Mercur y (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) PC C Hig h Bt u 349 0 0. 5 5 8 0.3 2 106 0 5.3 0 614.8 0 0.00033 9 PC C Lo wBt u 50 0 0. 5 5 7 0.1 3 150 1 7.5 1 855.5 7 0.00019 5 PC C Chlorin e Spik e (X-10 ) 403 0 85. 5 2 6 0.03 4 11 6 99.1 8 30.1 6 0.00000 4 PC C Soli d Charge s 50 0 0. 5 9 8 0.0 3 156 8 7.8 4 1536.6 4 0.00004 7 (MercurySpike ) 50 0 0. 5 2 490 0 1.84 0.0 1 0.0 4 0.00901 6 PC C Bul k

Solid s 50 0 0. 5 9 8 0.08 7 715 2 35.7 6 7008.9 6 0.00062 2 SC C Hig h Bt u 1525 0 0. 5 2. 8 0.0 2 60 6 3.0 3 16.9 7 0.00001 2 Total s 12,00 5 158.6 2 10063.1 3 0.01023 6



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