## p. 1 

# TECHNOLOGY' SCIENCES GROUP INC
WASHINGTON 1150 18th Street, N.IN.

Suite 1000 Washington, D.C. 20036 Telephone 202 223-4392 Fax 202 872-0745

SACRAMENTO 712 Fifth Street

Suite A Davis, CA 95616 Telephone 530 757-1298 Fax 530 757-1299 

## February 4, 2008 3

Document Control Officer Office of Pollution Prevention and Toxic Substances, 7407 U.S. EPA 1201 Constitution Ave. NW Washington, DC 20460 

# Re: Significant New Use Notice (SNUN) TS

- 

# 08PIN1 Dear Sir or Madam: On behalf of the[ ], Technology Sciences Group, Inc. (TSG) is hereby submitting in accordance with 40 CFR Section 721.25 the attached Significant New Use Notice (SNUN) TS-08PIN1 for review. The SNUN substance is regulated at 40 CFR 721.5575. The SNUR limits use to industrial use. The intended use is non-industrial or commercial. In accordance with 40 CFR Section 700.45(b), the fee of $2500.00 has been submitted (see attached copy of check). This SNUN does contain confidential business information (CBI). The original SNUN, two copies and a sanitized copy are enclosed for EPA review.

CANADA 275 Slater Street Suite 900 Ottawa, Ontario K1 P 5H9 Telephone 613 247-6285 Fax 613 236-3754 

## If there are any questions regarding this submission, please do not hesitate

to contact me at 202-828-8992. Sincerely,

Richard A. Jourdenais, Ph.D. Director, Chemicals Division Attachments

E-mail tsg@tsgusa.com 

# -3 

# o http://www.tsgusa.com

# e•PPA PREMANUFACTURE NOTICE

LVE Modification • LOREX ModifiCatibn 

### p. 

## 2 Form Approved. 0.M.B. No. 2070-0012. Approval Expires 10-31-96 

### U.S. ENVIRONMENTAL PROTECTION AGENCY 

# AGENCY USE ONLY Date of receipt



### CES 

# Company Sanitized 

# l! 

# i!{ ill! 11 I[

GENERAL INSTRUCTIONS 

# TS - 0 P I N

• You must provide all information requested in this form to the extent that it is known to or reasonably ascertainable by you. Make teasonable estimates if you do not have actual data.

• Before you complete this form, you should read the "Instructions Manual for Premanufacture Notification" (the Instructions Manual is available from the Toxic Substances Control Act (TSCA) Information Service by calling 202-554-1404, or faxing 202-554-5603).

• If a user fee has been remitted for this notice (40 CFR 700.45), indicate in the boxes above the TS-user fee identification number you have generated. Remember, your user fee ID number must also appear on your corresponding fee remittance, which is sent to EPA, HQ Accounting Operations Branch (PM-226), P.O. 360399M, Pittsburgh, PA 15251-6399, Attn. TSCA User fee.

Part I — GENERAL INFORMATION You must provide the currently correct Chemical Abstracts (CA) Name of the new chemical substance, even if you claim the identity as confidential. You may authorize another person to submit chemical identity information for you, but your submission will not be complete and the review will not begin until EPA receives this information. A letter in support of your submission should reference your TS user fee identification number. You must submit an original and two copies of this notice including all test data. If you claimed any information as confidential, a single sanitized copy must also be submitted.
Part 11— HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE If there are several manufacture, processing, or use operations to be described in Part II, sections A and B of this notice, reproduce the sections as needed.

Part III — LIST OF ATTACHMENTS Attach additional sheets if there is not enough space to answer a question fully. Label each continuation sheet with the corresponding section heading. In Part III, list these attachments, any test data or other data and any optional information included in the notice.

OPTIONAL INFORMATION You may include any information that you want EPA to consider in evaluating the new substance. On page I I of this form, space has been provided for you to described pollution prevention and recycling information you may have regarding the new substance. So-called "binding" boxes are included throughout this form for you to indicate your willingness to be bound to certain statements you make in this section, such as use, production volume, protective equipment .. . This option is intended to reduce delays that routinely accompany the development of consent orders or Significant New Use Rules. Except in the case of exemption applications (such as TMEA, LVE, LOREX) where certain information provided in such notification is binding on the submitter when the Agency approves the exemption application, checking a binding box in this notice does not by itself prohibit the submitter from later deviating from the information (except chemical identity) reported in the form.
CONFIDENTIALITY CLAIMS You may claim any information in this notice as confidential. To assert a claim on the form, mark (X) the confidential box next to the information that you claim as confidential. To assert a claim in an attachment, circle or bracket the information you claim as confidential. If you claim information in the notices as confidential, you must also provide a sanitized version of the notice, (including attachments). For additional instructions on claiming information as confidential, read the Instructions Manual.

Mark (x) if any information in this notice is claimed as confidential. TEST DATA AND OTHER DATA You are required to submit all test data in your possession or control and to provide a description of all other data known to or reasonably ascertainable by you, if these data are related to the health and environmental effects on the manufacture, processing, distribution in commerce, use, or disposal of the new chemical substance. Standard literature citations may be submitted for data in the open scientific literature. Complete test data (written in English), not summaries of data, must be submitted if they do not appear in the open literature. You should clearly identify whether test data is on the substance or on an analog. Also, the chemical composition of the tested material should be characterized. Following are examples of test data and other data. Data should be submitted according to the requirements of §720.50 of the Premanufacture Notification Rule (40 CFR Part 720).

Test Data (Check Below any included in this notice)

• Environmental fate data 

### El Yes • Other data 

### El Yes

• Health effects data 0 Yes Risk assessments Environmental effects data 0 Yes Structure/activity relationships

• Physical/Chemical Properties* 

### x El Yes Test data not in the possession or control of the submitter

* A physical and chemical properties worksheet is located on the last page of this form. TYPE OF NOTICE (Check Only One)

PMN (Premanufacture Notice) INTERMEDIATE PMN (submitted in sequence with final product PMN) SNUN (Significant New Use Notice) TMEA (Test Marketing Exemption Application) INE (Low Volume Exemption) @ 40 CFR 723.50(c)(l) LOREX (Low Release/Low Exposure Exemption) @ 40 CFR : 723.50(c)(2)

IS THIS A CONSOLIDATED PMN? Yes # of chemicals (Prenotice Communication # required, enter # on page 3) Hnter tne total number ot pages in the Premanufacture Notice fly 

# ifiToic io EPA c mbe 

### 37 

# •

EPA FORM 7710

- 25 (Rev. 5-95) Replaces previous editions of EPA Form 7710-25. 

# .30764

### .-- -

Public reporting burden for this collection of information is estimated to average 110 hours per response, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden, to Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 

### 401 M. St., S.W., Washington, D.C. 20460; and to the Office of Management and Budget, Paperwork Reduction Act (2070-0012), Washington, D.C. 20503. 

# CERTIFICATION I certify that to the best of my knowledge and belief: 1. The company named in Part I, section A, subsection la of this notice form commercial purpose, other than in small quantities solely for research and Section B. 2. All information provided in this notice is complete and truthful as of the 3. I am submitting with this notice all test data in my possession or control reasonably ascertainable by me as required by §720.50 of the Premanufacture
Additional Certification Statements: If you are submitting a PMN, Intermediate PMN, Consolidated PMN, or SNUN, statement that applies: intends to manufacture or import development, the substance identified
date of submission. and a description of all other data known Notification Rule.

check the following user fee certification specified in 40 CFR 700.45(b), or for an Intermediate PMN (defined @
40 CFR 700.43 and has remitted with 40 CFR 723.50(c)(1) or a 723.50(c)(2), check the following

• the new chemical substance for commercial under the terms of 40 CFR 723.50. with those terms; and applicable exemption conditions. the manufacturer intends to commence 1 year of the date of the expiration of

ed facts regarding the chemical substance USC 1001. 

### for a in Part I,

to or

40 CFR
a fee of $100 in
Low release certification

the 30 day 0 The Company named in Part I, Section A has remitted the fee of $2500 

# EJ The Company named in Part I, Section A has remitted the fee of $1000 700.43) in accordance with 40 CFR 700.45(b), or The Company named in Part I Section A is a small business concern under accordance with 40 CFR 700.45(b). If you are submitting a low volume exemption (LVE) application in accordance and low exposure exemption (LoRex) application in accordance with 40 CFR statements: 

# fl The manufacturer submitting this notice intends to manufacture or import purposes, other than in small quantities solely for research and development, The manufacturer is familiar with the terms of this section and will comply The new chemical substance for which the notice is submitted meets all If this application is for an LVE in accordance with 40 CFR 723.50(c)(1), manufacture of the exempted substance for commercial purposes within review period. The accuracy of the statements you make in this notice should reflect your best prediction of the anticipa described herein. Any knowing and willful misinterpretation is subject to criminal penalty pursuant to 18 Confidential Signature and title of Authorized Official (Original Signature Required) Date 

### X Signature of agent - (if applicable) Date

EPA FORM 7710-25 (Rev. 5-95) Page 2

### Part I -- GENERAL INFORMATION

Section A -- SUBMITTER IDENTIFICATION Con(' Mark () the "Confidential" box next to any subsection you claim as confidential den ti a I Ia. Person Name of authorized official Submitting Notice (in U.S.) Position X

Company Mailing address (number and street) City, State, ZIP Code

Position b. Agent (if Name of authorized official applicable) Company

Mailing address (number and street) City, State, ZIP Code Telephone Area Code Number

c. If you are submitting this notice as part of a joint submission, mark (X) this box. Joint Submitter (if Name of authorized official applicable) Position

Company Mailing address (number and street) City, State, ZIP Code relephone Area Code Number

2. Technical Name of authorized official Contact (in U.S.) Position X

Company Mailing address (number and street) City, State, ZIP Code Telephone Area Code Nunthei

3. If you have had a prenotice communication (PC) concerning this notice and EPA assigned a PC Number to the notice, enter the number. Mark (X) if none

. If you previously submitted an exemption application for the chemical substance covered by this notice, enter the exemption number assigned by EPA. If you previously submitted a PMN for this substance enter the Mark (X) if none PMN number assigned by EPA (i.e. withdrawn or incomple

.

. If you have submitted a notice of Bona fide intent to manufacture or import for the chemical substance covered by this notice, enter the notice number assigned by EPA. Mark

### ■ (X) if none I. Manufacture 6. Type of Notice - Mark (X) Only Binding Option Import Only Binding Option Mark (X) 3. Both
EPA FORM 7710-25 (Rev. 5-95) Page 3

## P. 5 Part I -- GENERAL INFORMATION -- Continued Section B -- CHEMICAL IDENTITY INFORMATION: You must provide a currently correct Chemical Abstracts (CA) name of the substance based on the ninth Collective Index (9C1) of CA nomenclature rules and conventions. Mark (X) the "Confidential" box next to any item you claim as confidential Complete either item 1 (Class 1 or 2 substances) or 2 (Polymers) If another person will submit chemical identity information for Identify the name, company, and address of that person in a continuation as appropriate. Complete all other items. you (for either Item 1 or 2), mark (X) the box at the right. Confidential • • sheet. I Class a. 1 or 2 chemical substances (for definitions of class 1 and class 2 substances, see the Instructions Manual) or 2 Class 2 Class of substance - Mark (X) 1 

## 1 Class 1 b. Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar substances. For Class 1 substances a CA Index Name must be provided. For Class 2 substances either a CA Index Name or CA Preferred Name must be provided, which ever is appropriate based on CA 9CI nomenclature rules and conventions).

### Oxirane, 2,2'41,6-hexanediyIbis(oxyrnethylene)]bisc Please identify which method you used to develop or obtain the

Method 1 (CAS Inventory Expert Service - a copy of the report obtained from the CAS Inventory Expert Services submitted as an attachment to this notice) specified chemical identity information reported in this notice check one). Identification 0. Method 2 (Other Source) must be d. Molecular formula and CAS Registry Number (if a number already


### C12 H22 04 exists for the substance)


### cAs# 16096-31-4

X e. For a class 1 substance, provide a complete and correct chemica structure diagram. For a class 2 substance - (1) List the immediate

precursor substances with their respective CAS Registry Numbers. (2) Describe the nature of the reaction or process. (3) Indicate the range of composition and the typical composition (where appropriate). (4) Provide a correct representative or partial chemical structure diagram, as complete as can be known, if one can be reasonably ascertained.



## See page 4a

Mark (X) this box if you attach a continuation sheet.
EPA FORM 7710-25 (Rev. 5-95) Page 4

### Display without Links Return to Results 

# Display from REGISTRY ANSWER 1 © 

### 2007 ACS on STN Structure Diagram 

## f o x CH 2 0 (CH 2 f

), 0—CH 2 

### CAS Registry Number 16096-31-4 

### REGISTRY Chemical Name 

### Oxirane, 2,2'41,6-hexanediyIbis(oxymethylene)]bis- (9CI) (CA INDEX NAME) Hexane, 1,6-bis(2,3-epoxypropoxy)- (6CI, 8CI) 1,6-Bis(glycidyloxy)hexane 1,6-Hexamethylenediol diglycidyl ether 1,6-Hexanediol diglycidyl ether Hexamethylene diglycidyl ether Hexamethylene glycol diglycidyl ether Hexanediol diglycidyl ether NPEK 051 ZH 16 Molecular Formula 

### C12 H22 04 

# CAS REGISTRY Search for information related to CAS RN 16096-31-4 

### in these categories:
• Agriculture [$2.00]

• Biotechnology [$2.00]

• Chemical Catalogs [$2.00]

• Chemistry References [$2.00] Restricted to: NO RESTRICTIONS

Preparation Industrial Manufacture Synthetic Preparation Formation, Nonpreparative Purification

• General Science [$2.00]

• Life Sciences [$2.00]
• Material Safety (MSDS) [$2.00]
• Patents [$2.00]
• Patents, Full Text [$2.00]

• Patents, National [$2.00]

Page 4a 

### p. 6

## P. 7 Part I -- GENERAL INFORMATION -- Continued Section B -- CHEMICAL IDENTITY INFORMATION -- Continued 2. Polymers (For a definition of polymer, see the Instructions Manual.)

a. Indicate the number-average weight of the lowest molecular weight composition of the polymer you intend Indicate maximum weight percent of low molecular weight species (not including residual monomers, reactants, below 1,000 absolute molecular weight of that composition. Describe the methods of measurement or the basis for your estimates: GPC Other : (Specify) i) lowest number average molecular weight: to manufacture. or solvents) below 500 and 

### not applicable Confidential

ii) maximum weight % below 500 molecular weight: iii) maximum weight % below 1000 molecular weight: Mark (X) this box if you attach a continuation sheet. b. You must make separate confidentiality claims for monomer or other reactant identity, composition information, and residual information. Mark (X) the "Confidential" box next to any item you claim as confidential
(1) - Provide the specific chemical name and CAS Registry Number (if a number exists) of each monomer or other reactant used in the manufacture of

the polymer. (2) - Mark (X) this column if entry in column (1) is confidential. (3) - Indicate the typical weight percent of each monomer or other reactant in the polymer. (4) - Mark (X) the identity column if you want a monomer or other reactant used at two weight percent or less to be listed as part of the polymer

description on the TSCA Chemical Substance Inventory. (5) - Mark (X) this column if entries in columns (3) and (4) are confidential. (6) - Indicate the maximum weight percent of each monomer or other reactant that may be present as a residual in the polymer as manufactured for

commercial purposes. (7) - Mark (X) this column if entry in column (6) is confidential. Monomer or other reactant and CAS Registry Number (I) Confidential (2) Typical composition (3) Identity

Mark (X) (4) Confidential (5) Maximum

residual (6) Confidential (7) % % % % % % % % % % % % % % Mark (X) this box if you attach a continuation sheet. c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this notice (check one).

Method 1 (CAS Inventory Expert Service - a copy of the identification report Method 2 (other source) obtained from CAS Inventory Expert Service must be submitted as as attachment to this notice) d. The currently correct Chemical Abstracts (CA) name for the polymer that is consistent with TSCA Inventory listings for similar polymers.

e. Provide a correct representative or partial chemical structure diagram, as complete as can be known, if one can be reasonably ascertained.



# Eli Mark (X) this box if you attach a continuation sheet. EPA FORM 7710-25 (Rev. 5-95) Page 5

### p. 8 

# Part I -- GENERAL INFORMATION -- Continued Sect ion li -- CHEMICAL IDENTITY INFORMATION -- Continued 3. I nip uri ties (a) - Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial purpose. Provide the

CAS Registry Number if available. If there are unidentified impurities, enter "unidentified." (b) - Estimate the maximum weight % of each impurity. If there are unidentified impurities, estimate their total weight %. Impurity and CAS Registry Number

(a) Maximum percent (b) Confidential 

## none %

%

%

%

%

% Mark (X) this box if you attach a continuation sheet. 4. Synonyms - Enter any chemical synonyms for the new chemical identified in subsection 1 or 2.


### see 

### page 

### 4a 

# I 

# I Mark (X) this box if you attach a continuation sheet. Confidential

Trade identification - List trade names for the new chemical substance identified in subsection 1 or 2.

Mark (X) this box if you attach a continuation sheet. 

### X

(■ Generic chemical name - If you claim chemical identify as confidential, you must provide a generic name for your substance that reveals the specific chemical identity of the new chemical substance to the maximum extent possible. Refer to the TSCA Chemical Substance Inventory, 1985 Edition, Appendix B for guidance on developing generic names. 

### not applicable

Mark (X) this box if you attach a continuation sheet. 7. Byproducts - Describe any byproducts resulting from the manufacture, processing, use, or disposal of the new chemical substance. Provide the CAS Registry

Number if available. Byproduct (I) CAS Registry Number (2) Contidential 

### none

Mark (X) this box if you attach a continuation sheet. EPA FORM 7710-25 (Rev. 5-95) Page 6

### P. 9 

# Part I -- GENERAL INFORMATION -- Continued Section C -- PRODUCTION, IMPORT, AND USE INFORMATION:

Mark (X) the "Confidential" box next to any item you claim as confidential. 1. Production volume -- Estimate the 

### maximum production volume during the first 12 months of production. Also estimate the maximum production volume for any consecutive 12-month period during the first three years of production. Estimates should be on 100% new chemical substance basis. For a Low Volume Exemption application, if you choose to have your notice reviewed at a lower production volume than 10,000 kg/yr, specify the volume and mark (x) in the binding box. If granted, you are bound to this volume 

### Maximum first 12-month production (kg/yr) (100% new chemical substance basis) Maximum 12-month production (kg/yr) (100% new chemical substance basis) dential Confi- Binding

Option Mark (x)
X 

### 2. Use Information -- You must make separate confidentiality claims for the description of the category of use, the percent of production volume devoted to each category, the formulation of the new substance, and other use information. Mark (X) the "Confidential" Box next to any item you claim as confidential. a. (1) -- Describe each intended category of use of the new chemical substance by function and application.. (2) -- Mark (X) this column if entry column (1) is confidential business information (CBI). (3) -- Indicate your willingness to have the information provided in column (1) binding. (4) -- Estimate the percent of total production for the first three years devoted to each category of use. (5) -- Mark (X) this column if entry in column (4) is confidential business information (CBI). (6) -- Estimate the percent of the new substance as formulated in mixtures, suspensions, emulsions, solutions, or gels as manufactured for commercial purposes at sites under your control associated with each category of use. (7) -- Mark (X) this column if entry in column (6) is confidential business information (CBI). (8) -- Indicate % of product volume expected for the listed "use" sectors. Mark more than one box if appropriate. Mark (X) to indicate your willingness to have the use type provided in (8) binding. (9) -- Mark (X) this column if entry(ies) in column (8) is (are) confidential business information (CBI). Category of use (1)

( by function and application i.e. a dispersive dye for finishing polyester fibers) CBI (2) Binding

Option Mark (x) (3) Production % (4) CBI
(5) % inFormulation (6) CBI (7) % of substance expected per use (8) CBI (9)Sitelimited Con-*

sumer Industrial Cornmercial Binding

Option X 100 % % X X

y,

% % % % % % * If you have identified a "consumer" use, please provide on a continuation sheet a detailed description of the use(s) of this chemical substance in consumer products. In addition include estimates of the concentration of the new chemical substance as expected in consumer products and describe the chemical reactions by which this substance loses its identity in the consumer product. Mark (X) this box if you attach a continuation sheet. 

### b. Generic If you claim any category of use description in subsection 2a as confidential, enter a generic description of that category. Read the 

### use Instructions Manual for examples of generic use descriptions. 

### description 

## Coating additive 

# 1 I Mark (X) this box if you attach a continuation sheet. 3. Hazard Information -- Include in the notice a copy of reasonable facsimile of any hazard warning statement, label, material safety data sheet, or other information which will be provided to any person who is reasonably likely to be exposed to this substance regarding protective equipment or practices for the safe handing, transport, use, or disposal of the new substance. List in part III hazard information you include. Mark (X) this box if you attach hazard information. Binding Option Mark (x)

EPA FORM 7710-25 (Rev. 5-95) Page 7

## p. 10

Part II-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Section A -- INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER Mark (X) the "Confidential" box next to any item you claim as confidential 

### Complete section A for each type of manufacture, processing, or use operation involving the new chemical substance at industrial sites you control. Importers do not have to complete this section for operations outside the U.S.; however, you may still have reporting requirements if there are further industrial processing or use operations after import. You must describe these operations. See instructions manual 1. Operation description a. Identity -- Enter the identity of the site at which the operation will occur. Confidential Name 

# X Site address (number and street) City, County, State, ZIP code 

### If the same operation will occur at more than one site, enter the number additional sites on a continuation sheet, and if any of the sites have production rates or operations, include all the information requested sites as attachments. of sites. Identify the significantly different in this section for those . 

# N/A

Mark (X) this box if you attach a continuation sheet. 

### b. Type -- Mark (X) Manufacturing Use Processing c. Amount and Duration -- Complete 1 or 2 as appropriate X

1. Batch Maximum kg/batch (100% new chemical substance) Hours/batch Batches/year

2. Continuous Maximum kg/batch (100% new chemical substance) Hours/batch Batches/yea!

d. Process description Mark (X) to indicate your willingness to have your process description binding. (1) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specify- e.g. 5 gallon pails, 55 drum, rail car, tank truck, etc.). (2) Provide the identity , the approximate weight (by kg/day or kg/batch on a 100% new chemical substance basis), and entry point of all starting materials feedstocks (including reactants, solvents, catalysts, etc.), and of all products, recycle streams, and wastes. Include cleaning chemicals (note frequency used daily or per batch.). (3) Identify by number the points of release, including small or intermittent releases, to the environment of the new chemical substance. X gallon and if not

EPA FORM 7710-25 (Rev. 5-95) Page 8

### X X X X X Worker activity (i.e., bag dumping, filling drums)

(1) Protective Equipment/ Engineering Controls (3) Physical forms(s) and % new substance ( 5 ) CBI

(2) Binding Option Mark (x) (4) Binding # of Worker Expose (8) CBI

(9) Maximu duration CBI Option Mark (x) (6) CBI

(7) Firs/day (10) Days/yr

(11) (12) 

## p. 11



# ri Mark (X) this box if you attach a continuation sheet.



# Part II-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE -- Continued Section A -- INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER -- Continued 2. Occupational Exposure -- You must make separate confidentiality claims for the description of worker activity, physical form of the new chemical substance, number of works exposed, and duration of activity. Mark (X) the "Confidential" box next to any item you claim as confidential. (1) -- Describe the activities (i.e. bag dumping, tote filling, unloading drums, sampling, cleaning, etc.) in which workers may be exposed to the substance. (2) -- Mark (X) this column if entry in column (1) is confidential business information (CBI). (3) -- Describe any protective equipment and engineering controls used to protect workers. (4) and (6) -- Indicate your willingness to have the information provided in column (3) or (5) binding. (5) -- Indicate the physical form(s) of the new chemical substance (e.g., solid: crystal, granule, powder, or dust) and % new chemical substance (if part of a mixture) at the time of exposure. (7) -- Mark (X) this column if entry in column (5) is confidential business information (CBI). (8) -- Estimate the maximum number of workers involved in each activity for all sites combined. (9) -- Mark (X) this column if entry in column (8) is confidential business information (CBI). (10) and (11) -- Estimate the maximum duration of the activity for any worker in hours per day and days per year. (12) -- Mark (X) this column if entries in columns (10) and (11) are confidential business information (CBI).

EPA FORM 7710-25 (Rev. 5-95) Replaces previous editions of EPA Form 7710-25.X X X X

X X X X X

Mark (X) this box if you attach a continuation sheet. 3. Environmental Release and Disposal -- You must make separate confidentiality claims for the release number and the amount of the new chemical substance released and other release and disposal information. Mark (X) the "Confidential" box next to each item you claim as confidential. (1) -- Enter the number of each release point identified in the process description, part II, section A, subsection I d(3). (2) -- Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch). (3) -- Mark (X) this column if entries in columns (1) and (2) are confidential business information (CBI). (4) -- Identify the media (stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration, POTW, or other (specify)) to which the new substance will be released from that release point. (5) -- a. Describe control technology, if any, and control efficiency that will be used to limit the release of the new substance to the environment. For releases disposed of on land, characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste. On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to secondary or tertiary on-site treatment. b. Estimate the amount released to the environment after control technology (in kg/day). (6) -- Mark (X) this column if entries in columns (4) and (5) are confidential business information (CBI). (7) -- Identify the destination(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct discharges or NPDES numbers of the POTW (Publicly Owned Treatment Works). Mark (X) if the POTW name or NPDES # is confidential business information (CBI). Release Amount of new substance CBI Media of Control technology and efficiency (you may wish to optionally attach efficiency data) CBI Number ( I ) released release e.g. stack air (2a) (2b) Binding (3) (4) (5a) Mark (X) 01)) ( () I X X X

(7) Mark X) the POTW provide name(s) below: CB I Navigable Other - Specify provide NPDES # CBI

EPA FORM 7710-25 (Rev. 5-95) Page 10

### p. 13

destination(s) of waterway releases to water. 

### N/A Mark (X) this box if you attach a continuation sheet.

EPA FORM 7710-25 (Rev. 5-95) Page 11

## p. 14



# Part II-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE -- Continued Section B -- INDUSTRIA L SITES CONTROLLED BY OTHERS Complete section B for typical processing or use operations involving the new chemical substance at sites you do not control. Importers do not have to complete this section for operations outside the U.S.; however, you must report any processing or use activities after import. See the Instructions Manual. 

### Complete a separate section B for each type of processing, or use operation involving the new chemical substance. If the same operation is performed at more than one site describe the typical operation common to these sites. Identify additional sites on a continuation sheet. 

### 1. Operation Description -- To claim information in this section as confidential, circle or bracket the specific information that you claim as confidential. (1) -- Diagram the major unit operation steps and chemical conversions, including interim storage and transport containers (specify - e.g. 5 gallon pails, 55 gallon drums, rail cars, tank trucks, etc). On the diagram, identify by letter and briefly describe each worker activity. (2) -- Provide the identity, the approximate weight (by kg/day or kg/batch, on an 100% new chemical substance basis), and entry point of all feedstocks (including reactants, solvents and catalysts, etc) and all products, recycle streams, and wastes. Include cleaning chemicals (note frequency if not used daily or per batch). (3) -- Identify by number the points of release, including small or intermittent releases, to the environment of the new chemical substance. (4) Please enter the # of sites (remember to identify the locations of these sites on a continuation sheet):



### f ] # of sites [

1 Mark (X) this box if you attach a continuation sheet. 2. Worker Exposure/Environmental Release (1 ) -- From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described. (2) -- Estimate the number of workers exposed for all sites combined. (4) -- Estimate the typical duration of exposure per worker in (a) hours per day and (b) days per year. (6) -- Describe physical form of exposure and % new chemical substance (if in mixture), and any protective equipment and engineering controls, if any, used to protect workers. (7) -- Estimate the percent of the new substance as formulated when packaged or used as a final product. (9) -- From the process diagram above, enter the number of each release point. Complete 9-13 for each release point identified. (10) -- Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology to the environment (in kg/day or kg/batch). (12) -- Describe media of release i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration, POTW, or other (specify) and control technology, if any, that will be used to limit the release of the new substance to the environment. (14) -- Identify byproducts which may result from the operation. (3), (5), (8), (11 ), (13) and (15) -- Mark (X) this column if any of the proceeding entries are confidential business information (CBI). Letter # of CBI Duration ( 'III Protective Equip. / % in CBI Release Amount of CBI Media of Release CBI ofActivity Workers Exposed of

Exposure Engineering Controls/ Physical Form and % new substance Formulation Number New Substance Released & Control Technology (1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) (10a) I (l0b) (11) (12) (13)

EPA FORM 7710-25 (Rev. 5-95) Page 12

### p. 

## 15 X X x

X X x x x

( 14) -- Byproducts: 

### none (15) 

# 1 I Mark (X) this box if you attach a continuation sheet, 

# OPTIONAL POLLUTION PREVENTION INFORMATION To claim information in this section as confidential circle or bracket the specific information that you claim as confidential.

EPA FORM 7710-25 (Rev. 5-95) Page 13

## In this section you may provide information not reported elsewhere in this form regarding your efforts to reduce

or minimize potential risks associated with activities surrounding manufacturing, processing, use and disposal of the PMN substance. Please include new information pertinent to pollution prevention, including source reduction, recycling activities and safer processes or products available due to the new chemical substance. Source reduction includes the reduction in the amount or toxicity of chemical wastes by technological modification, process and procedure modification, product reformulation, raw materials substitution, and/or inventory control. Recycling refers to the reclamation of useful chemical components from wastes that would otherwise be treated or released as air emissions or water discharges, or land disposal. Descriptions of pollution prevention, source reduction and recycling should emphasize potential risk reduction subsequent to compliance with existing regulatory requirements and can be either quantitative or qualitative. The EPA is interested in the information to assess overall net reductions in toxicity or environmental releases and exposures, not the shifting of risks to other environmental media or non-environmental areas (e.g., occupational or consumer exposure). In addition, information on the relative cost or performance characteristics of the PMN substance to potential alternatives may be provided. All information provided in this section will be taken into consideration during the review of this substance. See Instructions Manual and Pollution Prevention Guidance manual for guidance and examples. Describe the expected net benefits, such as (1) an overall reduction in risk to human health or the environment; (2) 

### a reduction in the volume manufactured; (3) a reduction in the generation of waste materials through recycling, source reduction or other means; (4) a reduction in potential toxicity or human exposure and/or environmental release; (5) an increase in product performance, a decrease in the cost of production and/or improved operation efficiency of the new chemical substance in comparison to existing chemical substances used in similar application; or (6) the extent to which the new chemical substance may be a substitute for an existing substance that 

### poses a greater overall risk to human health or the environment.



# n Mark (X) this box if you attach a continuation sheet. 

## p. 16

EPA FORM 7710-25 (Rev. 5-95) Page 14

## p. 17



# Part III -- LIST OF ATTACHMENTS Attach continuation sheets for sections of the form and test data and other data (including physical/chemical properties and structure/activity information), and optional information after this page. Clearly identify the attachment and the section of the form to which it relates, if appropriate. Number consecutively the pages of the attachments. In the column below, enter the inclusive page numbers of each attachment. Mark (X) the "Confidential" box next to any attachment name you claim as confidential. Read the Instructions Manual for guidance on how to claim any information in an attachment as confidential. You must include with the sanitized copy of the notice form a sanitized version of any attachment in which you claim information as confidential. Attachment name Attachment page number(s) Confidential X
X
X
X X
X X

EPA FORM 7710-25 (Rev. 5-95) Page 15

### p. 18 

# I E Mark (X) this box if you attach a continuation sheet. Enter the attachment name and number.

EPA FORM 7710-25 (Rev. 5-95) Page 16

## p. 19 PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET To assist EPA's review of physical and chemical properties data, please complete the following worksheet for data you provide and include it in the notice. Identify the property measured, the page of the notice on which the property appears, the value of the property, the units in which the property is measured (as necessary), and whether or not the property is claimed as confidential. The physical state of the neat substance should be provided. These measured properties should be for the neat (100% pure) chemical substance. Properties that are measured for mixtures or formulations should be so noted (% PMN substance in __). You are not required to submit this worksheet; however, EPA strongly recommends that you do so, as it will simplify review and ensure that confidential information is properly protected. You should submit this worksheet as a supplement to your submission of test data. This worksheet is not a substitute for submission of test data. Property (a) Mark (X) if provided Page number (b) Value (C) Measured Of Estimate (M or E) Contidential Mark (X) (d) 

### l'hysical state of neat substance (s) (1) 

### _ (g) Vapor pressure @ Temperature 20°C X <1.0mbar (of the KX6544) M


### Density/relative density g/cm3 Solubility @ Temperature °C 

## O. Solvent Solubility in water @ Temperature °C gil, 

### Melting temperature Boiling / sublimation temperature@ torr pressure Spectra Dissociation constant Particle size distribution Octanol / water partition coefficient Henry's Law constant Volitalization from water Volitalization from soil pH@ concentration Flammability Explodability Adsorption / coefficient Other - Specify

ATTACHMENT PAGE 17

### p. 20

EPA FORM 7710-25 (Rev. 5-95) Page 18Irritant

HEALTH FIRE 

# 7 REACTIVITY 

## 3 Hazards identification Hazard description:

• Information pertaining to particular dangers for man and environment: Irritating to eyes and skin. May cause sensitization by skin contact. Contains epoxy constituents. See information supplied by the manufacturer. . Classification system: . NFPA ratings (scale 0 - 4)

Health = 1 Fire = 1 Reactivity= 0 . HMIS-rafngs (scale 0 - 4)

Health = 1 Fire = 1 Reactivity = 0
A — 

## I Identification of substance . Product details . Trade name: GRILONIT RV 1812

• Article number: 160989

• Manufacturer/Supplier: EMS-PRIMID CH-7013 Domat/Ems Tel.:++41(0)81 - 632-6111 Fax:++41(0)81 - 632-7464

• Emergency information: EMS-CHEMIE AG CH-7013 Domat/Ems, Phone:++41 (0) 81-632-6111 Fax:++41 (0) 81 - 632-7401 Poison centre Switzerland Zurich, Phone:++41 (0)1-251 51 51 USA : Chemtrec hotline 1-800-424-9300 

## 2 Composition/Data on components

• Chemical characterization: . CAS No. Description 16096-31-4 1,6-Hexandiglycidylether

• Identification number(s)

• EINECS Number: 2402604 

### p. 

### 21



# t.MS EMS-PRIMID

Page 1/5 

## Material Safety Data Sheet acc. 

### to ISO/DIS 11014 Printing date 07/19/2006 Reviewed on 07/08/2005

(Contd. on page 2)



### 19

### p. 

### 22

Page 2/5 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/19/2006 Reviewed on 07/08/2005 Trade name: GRILONIT RV 1812 (Contd. of page 1) 

### 4 First aid measures

• General Information: Immediately remove any clothing soiled by the product.

• After inhalation: Seek medical treatment in case of complaints. In case of unconsciousness place patient stably in side position for transportation. . After skin contact: Immediately wash with water and soap and rinse thoroughly. . After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. . After swallowing: If symptoms persist consult doctor. 

## 5 Fire fighting measures . Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. . Special hazards caused by the material, Its products of combustion or resulting gases: In case of fire, the following can be released: Carbon monoxide (CO) . Protective equipment: No special measures required. 

## 6 Accidental release measures . Person-related safety precautions: Not required. . Measures for environmental protection: Prevent seepage into sewage system, workpits and cellars. . Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. 

### 7 Handling and storage . Handling: . Information for safe handling: No special measures required. . Information about protection against explosions and fires: No special measures required. . Storage: . Requirements to be met by storerooms and receptacles: No special requirements. . Information about storage in one common storage facility: Not required. . Further information about storage conditions: Keep receptacle tightly sealed. 

## 8 Exposure controls and personal protection . Additional information about design of technical systems: No further data; see item 7.

• Components with limit values that require monitoring at the workplace: Not required.

• Personal protective equipment: . General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. (Contd on page 3)



### 20(Contd. of page 2) Immediately remove all soiled and contaminated Wash hands before breaks and at the end of work Avoid contact Kith the eyes and skin.

• Breathing equipment: Not required.

• Protection of hands: Protective gloves

• Material of gloves The selection of the suitable gloves does not only of quality and varies from manufacturer to manufa

• Penetration time of glove material The exact break trough time has to be found out has to be observed.

• Eye protection: Safety glasses clothing.

by the manufacturer of the protective gloves and depend on the material, but also on further marks cturer.



### 11 Toxicological information Acute toxicity: . LD/LC50 values that are relevant for classification: 16096-31-4 1,6-Hexandiglycidylether OralILD5012900 mg/kg (rat) (Contd on page 4 USA — 

## 9 Physical and chemical properties . General Information Form: Fluid Color: Clear Odor: Nearly odorless

• Change in condition Bolling point/Boillng range: > 200°C (> 392°F)

• Flash point: > 100°C (> 212°F)

• Danger of explosion: Product does not present an explosion hazard.

• Vapor pressure at 20°C (68°F): < 1 hPa (<1 mm Hg)

• Density at 20°C (68°F): 1.06 g/cm3

• Solubility In / Miscibility with Water: Insoluble.

. Viscosity: Dynamic at 25°C (77°F): 14 mPas 

### 10 Stability and reactivity

• Thermal decomposition /conditions to be avoided: To avoid thermal decomposition do not overheat. . Dangerous reactions No dangerous reactions known. . Dangerous products of decomposition: No dangerous decomposition products known. 

### p. 

### 23

Page 3/5 

## Material Safety Data Sheet acc. 

### to ISO/DIS 11014 Printing date 07/19/2006 Reviewed on 07/08/2005 Trade name: GRILONIT RV 1812



### 21(Contd. on page 5) (Contd. of page 3) • Primary Irritant effect:
• on the skin: Irritant to skin and mucous membranes.
• on the eye: Irritating effect.
• Sensitization: Sensitization possible through skin contact. . Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant



## 15 Regulations . Sara . Section 355 (extremely hazardous substances): Substance is not listed. . Section 313 (Specific toxic chemical listings): Substance is not listed. 

### 14 Transport information

• DOT regulations: . Hazard class: -
• Land transport ADRIRID (cross-border):
• ADR/RID class: -
• Maritime transport IMDG:
• IMDG Class: -
• Air transport ICAO-TI and IATA-DGR:
• ICACVIATA Class: - . TransporVAdditional information: Not dangerous according to the above specifications. 

## 12 Ecological information . General notes: Water hazard class 1 (Assessment by list): slightly hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. 

### 13 Disposal considerations . Product: . Recommendation: Hand over to hazardous waste disposers. . Uncleaned packagings: . Recommendation: Disposal must be made according to official regulations. 

### p. 24

Page 4/5 

## Material Safeiy Data Sheet acc. to ISO/DIS 11014 Printing date 07/19/2006 Reviewed on 07/08/2005 Trade name: GRILONIT RV 1812



## 22Irritant (Contd. of page 4) . TSCA (Toxic Substances Control Act): 16096-31-411,6-Hexandiglycidylether . Proposition 65 . Chemicals known to cause cancer: Substance is not fisted. . Cancerogenity categories • EPA (Environmental Protection Agency) Substance is not listed.

• IARC (International Agency for Research on Cancer) Substance is not listed.

• NTP (National Toxicology Program) Substance is not listed. . NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed.

• OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed. . Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. . Hazard symbols:

. Risk phrases: Irritating to eyes and skin. May cause sensitization by skin contact. . Safety phrases: After contact with skin, wash immediately with plenty of ... . Wear suitable gloves and eye/face protection. . Special labeling of certain preparations: Contains epoxy constituents. See information supplied by the manufacturer. . National regulations: . Water hazard class: Water hazard class 1 (Assessment by list): slightly hazardous for water. 

### 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

• Department issuing MSDS: Environment and safety department(U+S) . Contact: Doris LOdi,Produktesicherheit Tel.+41 81-632-6526, Fax +41 81-632-7470 * Data compared to the previous version altered. USA 

### p. 25

Page 5/5 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/19/2006 Reviewed on 07/08/2005 Trade name: GRILONIT RV 1812



### 23

### p. 

## 26



# ffe 

# Your Health A guide to using epoxy resin based fillers

Guidance provided by: 

# X.Interne

n nL 

# a , X.Interiux. richtPlintcom 

# RIOLGRIP

24

## p. 27



# Your Health A guide to using epoxy resin based fillers Introduction Two-pack epoxy fillers are widely used for filling and fairing in the yacht industry. They are extremely robust and versatile products, suitable for use above and below the waterline. As with any chemicals, care should be taken whilst using these products. Always read the label before use. Up to date information and the relevant Safety Data Sheet can be found on our website. This brochure outlines some basic precautions to take whilst applying any epoxy based filler product. 

## Epoxies and Amines: Health & Safety information Epoxy fillers are usually supplied as two components, a base and a curing agent. The epoxy resin is usually in the base component, and the curing agent is usually based on an amine, which will react with the epoxy when the two components are mixed. Epoxies do not easily pass through the skin so they are not normally toxic to people internally. However they are irritants and will cause red, itchy rashes. These can be treated with soothing cream and normally heal after about three days. Amine and amide based curing agents have similar properties as epoxies. They can cause irritant rashes. Some are also corrosive; they could cause skin burns. In certain circumstances, epoxies and amines can also have a more dangerous effect. If they penetrate the skin into the bloodstream and cause the production of antibodies. If this happens, then the person concerned will react to the smallest presence of epoxies or amines in the workshop and could break out with a severe irritant rash. A person sensitised to epoxies or amines should seek medical advice, but may be permanently restricted from working with these materials again. In such a case, the individual is likely to be unable to work in a building where they are used without having an adverse reaction. The best way to avoid any such sensitisation is through proper use of recommended Personal Protective Equipment. Irritation from material is common in the workplace if protective equipment is not properly worn. In contrast, actual instances of true sensitisation are relatively rare.



## 25Safety glasses

Half face mask cartridge Full face mask cartridge 

# saA

Chemical resistant gloves
Full face mask air fed

Disposable overall

Cotton overall

Safety boots Goggles 

### p. 28 

## Protective equipment you may need for applicators, filler mixers and all others involved in the application of epoxy based materials

Hard hat



### 26

# X.Intemational 

# KINterlux. yachtpaint.corn yachtpaInteom 

# A W LGIRIP •• •4' 4



## Mixing and application of two-pack epoxies Although fillers are generally a lot thicker than standard two-pack epoxy paints and do not splash as easily, care must still be taken to avoid direct contact with these materials. It is not enough just to avoid splashing product onto bare skin or into eyes, contamination of overalls, or any clothing being worn, should be avoided due to the risk of the materials soaking into the garments and coming into contact with the skin. The mixing and application of fillers is usually a very hands-on operation, and as such is physically demanding work. Due to the heavy work and the working conditions which may take place in hot weather and/or under tarpaulins or plastic sheeting, the skin can become saturated with sweat. This will allow much better contact with the filler and irritant rashes/sensitisation are more likely in these conditions. Take care in these situations to avoid contact with the fillers.
T::altZakalfigtMgEA't'ZEMf.MiZrs:TL'MMF .ZrZEEU?,22;:SF.4.,TEE'aiaTZ'O.EiZi:'MKF;::ZEENZEEUZEIEEEPlfia:;E:,Ea 

## Recommended clothing / skin and eye protection when mixing two-pack epoxies

• A long sleeve, long leg cotton overall (preferably a minimum of 60% cotton), in white for hotter climates.

• Chemical resistant gloves with long sleeves which overlap the overalls.

• Safety boots that are anti-static with steel toe caps and should at least cover the ankles.

• Safety goggles or glasses.

• Barrier cream should be worn to protect face skin, or else a full face mask or visor. Barrier cream should not be used in place of protective clothing such as gloves.

• A half face respirator may also be worn to avoid the inhalation of unpleasant and potentially harmful vapours from some amine curing agents.

Guidance provided by:



## 27

### P. 30



## Sanding of cured filler The hazards presented by epoxy based sanding dust are much less than for the wet product. Chemically, the base and curing agent should be largely reacted with each other. However the dusts still contain some active materials and are potentially a health and safety hazard. Dust can easily coat the skin and you should therefore be protected against it. As mentioned above for application and mixing, sanding of fillers is often a hands-on process. Sweating caused by the heavy work can lead to dust more easily sticking to skin and accumulating, especially in the fold of the elbow joint. Fine dust particles of all sorts (eg. wood, GRP etc.), including fillers, are also potentially harmful if breathed into the lungs. 

## Recommended clothing / skin and eye protection when sanding epoxy fillers

• At the minimum, a half face respirator capable of filtering out particulate matter (like sanding dust).

• A long sleeve. long leg cotton overall (preferably a minimum of 60% cotton), in white for hotter climates, preferably with a hood.

• Long sleeve gloves.

• Safety boots that are anti-static with steel toe caps and should at least cover the ankles (to avoid drop hazards).

• The overall/glove and overall/boot overlaps can be sealed with tape to stop dust getting in.

• Safety goggles or glasses.

• Barrier cream should be worn to protect face skin, or else a full face mask or visor. Barrier cream should not be used in place of protective clothing such as gloves. 

# Summary Epoxy based fillers are extremely useful products, offered by a large number of coatings companies. When care is taken in their use these materials can be used safely with little risk to the applicator. .1



## 28

### p. 31

Further information about the use of Epoxy resin based coatings can be found at the following sites: www.yachtpaint.com www.awlgrip.com

The information enclosed in this booklet is relevant to all epoxy based products, which include; laminating resins, glues, primers, fillers, gelcoat repair resins 

### AKZO NOBEL



### 29

# A' GRUB PRODUCTbiliA SHEET AWL@FAIR L.W. FAIRING COMPOUND 08200 / D7200

Features & Uses Awlfair L.W is a premium trowelable filler product for fairing, leveling or smoothing surface imperfections due to gouges, pitting, dents or weld seams. The Awlfair LW formulation brings you the latest technology with super smooth finish and easy sanding. Awlfair LW is suitable for both manual and automatic mixing. Leading industry applicators rave about it's application attributes. Backed by extensive laboratory research and development, Awlfair LW has been tested and approved for a multitude of systems. May be used above or below the waterline. Specification Data Type: Two-component epoxy. Color: White base, red converter. Pink - after mixing components Packaging: Available in 1 Quart, 1 Gallon (US only) ,2 Gallon pails, 6OLT pails (EU only) and 20011 containers (EU only). Theoretical Coverage - Sq. Feet/Gallon; 6.8 Sq. Feet (0.63 m`) at 240 mils (6000 microns) DFT. Coverage calculations are based on theoretical transfer efficiency of 100%. Actual coverage rate obtained will vary according to equipment choice, application techniques, part size, and application environment. Recommended Wet Film Thickness: 240 mils (6000 microns) per coat . Maximum 400 mils (1 cm). Number of coats: As required Anticipated Cure Time at 75 2 F/25°C/50% R.H: 8 hours touch dry; 24 hours resistance to foot/tread; 7 days full cure. Recoatability: AWLFAIR L.W. must 

### be sanded before recoating with itself or any other primer. It must be over coated with an epoxy primer such as HIGH BUILD, EPDXY SPRAYABLE FAIRING COMPOUND, HULLGARD, ULTRA BUILD or STD E Trowelable Filler (Europe only) before applying the finishing system. AWLFAIR LW is sandable after 48 hrs at 55 9 F /13°C , 17hrs at 77 2 F/25°C & 6.5 hrs at 95°F/ 35°C. Shore D hardness development after 7 days: >60 at 77 2 F/25°C. VOC: 

### Base (D8200) - 0 g/I or 0 lbs/gal Converter (D7200) - 84 g/I or 0.70 lbs/gal Mixed (1:1 by volume) - 42g/I or 0.35 lbs/gal
Product Components, Reducers, Additives, and Auxiliary Components
Base - AWLFAIR L.W. BASE WHITE D8200 Converter — AWLFAIR L.W. CONV RED D7200 Equipment Cleaning T0006 or 10002 or M.E.K. Application Equipment Longboard battens, trowels, Spatulas or Putty Knives. Surface Preparation Only apply over properly applied and prepared Awlgrip primers. Hullgard Extra Epoxy Primer (EU only), Hullgard Epoxy Primer and High Build are recommended substrate primers. Awlfair LW may be applied direct to Hullgard Extra or Hullgard Epoxy Primer without the need for sanding. See the relevant primer product datasheet for details. High Build must be sanded prior to application of Awlfair LW.

East Water Street, Waukegan, Illinois 60085 • USA • Tel: 847.599.6212 • Fax: 847.599.6209 Bannerlaan 54 • B-2280 Grobbendonk • Belgium • Intl. Tel: 32.14.257770 • Intl. Fax: 32.14.230880 76 Waterway Drive • Coomera • Queensland 4209 • Australia • Tel: 61.7.5529.9766 

### or 1 800.007.866 • Fax: 61.7.5529.9329 449 Tagore Industrial Avenue • 01-03 Hong Joo Industrial Building • Singapore 787820 • Tel: 65.6453.1981 • Fax: 65.6453.1778
Page 1 of 2 • Rev 1 — APRIL 07 AWLFAIR LW FAIRING COMPOUND 

### 30

# WI GRIP PRODUCT 15BA SHEET AWL@FAIR LW. FAIRING COMPOUND D8200 / D7200 Mixing and Reduction 

### Mix 1:1 

### by volume (as supplied). Mix ratio by weight: 1.59 :1.0 D8200 : D7200 Induction time after mixing: None Anticipated Pot Life at 50% RH:

55 2 F/ 13 2 C : 3 hours 75°F/ 25°C : 11/

2 - 2 hours 95°F/ 35°C : 45 mins — 1 hr Mix the two components thoroughly to a uniform pink colour with no streaks or lumps. Warning: Do not add any thinners or reducers to AWLFAIR L.W. Application Instructions 

### Properly prepare and prime the surface with the recommended primer before starting any filling or fairing. Apply Awlfair L.W. by trowel to an area you can work in 20 to 30 minutes. Pot life and working time is dependent upon temperature. Warmer climates will decrease pot life. Start with thin coats in low areas and build out to high areas. Allow to cure. Several applications may be necessary to fill large areas. Block and machine sand with 36 to 60 grit paper. Remove sanding dust and residue before applying more Awlfair L.W. Stop when the faired surface has a uniform surface which meets the fairing quality specified for the project. Note: 

### AWLFAIR L.W. must be sealed with Hullgard Epoxy Primer (D6070/D3707) when used below the waterline Note: 

### AWLFAIR L.W. must be sealed with an Awlgrip Epoxy Primer such as High Build when used above the waterline. This will maximize gloss and colour holdout in the Awlgrip top coat system.

Warning: 

### Do not use unless mixed thoroughly with the curing agent at specified ratio. Do not use below 13°C/55°F or warmer than 40 2 C/104°F. Proper application and/or cure results may be more difficult to achieve when conditions are outside this range. Do not thin. Do not wipe down cured filler with reducers. 

### Avoid conditions of low temperature with high humidity as this can result in the formation of a surface by-product that must be removed by either detergent wash followed by fresh water wash or by sanding.

The information in this Product Data Sheet is not intended to be exhaustive. Any person using the product without first making further enquiries as to the suitability of the product for the intended purpose does so at their own risk and, to the extent permitted by law, we can accept no responsibility for the performance of the product or for any loss or damage arising out of such use. The information contained in this Product Data Sheet is liable to modification from time to time in the light of experience and our policy of continuous product development. 

### Awlgrip®, Awl® and all products mentioned in this Product Data Sheet are trademarks of, or licensed to, Akzo Nobel. Akzo Nobel. 2007
East Water Street, Waukegan, Illinois 60085 • USA • Tel: 847.599.6212 • Fax: 847.599.6209 Bannerlaan 54 • 8-2280 Grobbendonk • Belgium • Intl. Tel: 32.14.257770 • Intl. Fax: 32.14.230880 76 Waterway Drive • Coomera • Queensland 4209 • Australia • Tel: 61.7.5529.9766 or 1 800.007.866 • Fax: 61.7.5529.9329 449 Tagore Industrial Avenue • 01-03 Hong Joo Industrial Building • Singapore 787820 • Tel: 65.6453.1981 • Fax: 65.6453.1778
Page 2 of 2 • Rev 1 — APRIL 07 AWLFAIR LW FAIRING COMPOUND 

### 31

### Attachment # Awlfair L. W. Fairing compound This product is supplied in two packs — base and converter. These are mixed in a 1:1 volume ratio shortly before application. The SNUN substance is contained in only one of the packs. Hence the concentration of the SNUN substance is diluted following mixing to give a lower percentage of SNUN substance in the product during application. This lower value is therefore appropriate for risk assessment during the application of the filler. Details of the quantities of SNUN substance are as follows: Base: 10-13% SNUN substance Converter: 0% SNUN substance Mixed product as applied : 6-8% SNUN substance p. 

### 34

32

### p. 35 

# EMORIP PRODUCT DATA SHEET AWL®-FAIR L.W. & AWL®-FAIR L.W.T. Epoxy Trowelable Fairing Compound

08020/010191D70071D7010

Features & Uses AWL-FAIR L.W. and AWL-FAIR L.W.T. are two component, premium trowelable fillers for fairing, leveling, or smoothing surface imperfections due to gouges, pitting, dents, or weld seams. May be used above or below the waterline.

Specification Data Type: Two Component Epoxy Packaging: Available in 1 Gallon containers, 1 quart containers, and 2 gallon pails. Theoretical Coverage: Sq. Feet/Gallon: 1,604 Sq. Feet (149m 2 ) at one mil dry (25 microns). 6.4 Sq. Feet (0.6m 2 ); % inch; 250 mils (6,250 microns) DFT Coverage calculations are based on theoretical transfer efficiency of 100%. Recoatability: All AWL-FAIR products must be sanded before recoating with itself or other Awlgrip Products. They must be overcoated with an epoxy primer such as 545 Epoxy Primer, HIGH BUILD, AWL-QUIK, or ULTRA-BUILD, or Sprayable Fairing Compound before topcoating.

VOC: White Base (D8020) — 3 g/It or 0.02 lbs/gallon

Thick Base (D1019) — 3 g/It or 0.02 lbs/gallon Standard Converter (D7007)— 70 g/It or 0.6 lbs/gallon Fast Converter (D7010)— 64 g/It or 0.5 lbs/gallon Product Components, Reducers, Additives, and Auxiliary Components AWL-FAIR L.W. Base — White D8020 AWL-FAIR L.W.T. Base - Gray D1019 AWL-FAIR L.W. Converter- Red D7007 AWL-FAIR L.W. Converter - Red Fast D7010 Equipment Cleaning T0006 , T0002 Reducers or M.E.K. Application Equipment Trowels, Spatulas, longboard or Putty Knives. Surface Preparation Only apply over properly applied and prepared Awlgrip Primers. 545 Epoxy Primer or HIGH BUILD Epoxy Primer are preferred.
Mixing and Reduction First shake or stir D7007/D7010 to a uniform consistency. Mix by volume 1 part D8020 or D1019 with 1 part D7007 or D7010. Thoroughly mix material to a uniform pink color with no streaks or lumps in the mix. Do not add thinners or reducers to AWL-FAIR Products. Induction Time after Mixing: None 1 East Water Street • Waukegan, Illinois 60085 • USA • Tel: 847.599.6212 • Fax: 847.599.6209 Bannerlaan 54 • B-2280 Grobbendonk • Belgium • Intl. Tel: 32.14.257770 • Intl. Fax: 32.14.230880 76 Waterway Drive • Coomera • QLD 4209 • Australia • Tel: 61.7.5573.9600 or 1800.007.866 • Fax: 61.7.5573.9677 449 Tagore Industrial Avenue • 01 03 Hong Joo Industrial Building • Singapore 787820 • Tel: 65.6453.1981 • Fax: 65.6453.1778
Page 1 of 2 • Rev 2
- APRIL 2005 • AWL

- FAIR L.W. & AWL

- FAIR L.WT 

### 33

### p. 36 

# $W 

# GRIP PRODUCT DATA SHEET AWL®-FAIR L.W. & AWL®-FAIR L.W.T. Epoxy Trowelable Fairing Compound

D8020/D10191D70071D7010 Anticipated Pot Life at 77°F/25°C, 50% RH: D8020 or D1019/D7007 = 30-45 minutes Anticipated Pot Life at 77°F/25°C, 50% RH: D8020 or D1019/D7010 = 20-30 minutes
Application Instructions Apply by trowel in thin layers to avoid air pockets to an area you can work in 15 to 20 minutes at 77°F/25°C, 50% RH when using D7007. When using D7010 work time is reduced to 5 to 10 minutes at 77°F/25°C, 50% RH. Start application in low areas and build out into high areas. Allow to cure. Several applications may be required to fill large areas. Block sand with 30 to 60 grit and blow off sanding dust and residue before applying more AWL-FAIR. Shape materials with tools of your choice. NOTE: AWL-FAIR Products must be sealed with 545 Epoxy Primer. NOTE: Filler primer, fairing materials, and sanding surfacers should be sealed with 545 Epoxy Primer before applying AWLGRIPO or

AWLCRAFT@ 2000 Topcoats. This will maximize gloss and color hold-out in the topcoat. NOTE: Application techniques should be mastered to avoid insertion of air pockets within this product. Air pockets are not covered

under the Awlgrip warranty and are considered an application characteristic. Application of AWL-FAIR@ Products in thin layers will help avoid air pockets. Remember to feather all edges and holes at 6 to 1 or 6 times the fill thickness for the feathered edge. Do not apply paint materials to surfaces warmer than 105°F or colder than 55°F. Do not attempt to cure products at

temperatures below 55°F. IMPORTANT Before mixing, read Material Safety Data Sheet for health hazard and safety information. For further information regarding health and safety recommendations go to www.awlqrip.com WARNING! DO NOT incorporate into this Awlgrip Coating System, any thinner, additive, modifier, converter, or related product produced by any manufacturer other than Awlgrip. Any such substitution carjeopardize the unique chemical characteristics provided by each of the Awlgrip Coating systems. FOR INDUSTRIAL USE ONLY This product is for use by professional, trained, personnel using proper equipment and is not intended for sale to or use by, the general public. Warning: Do not apply paint materials to surfaces less than 3°C (5° F) above dew point, or to surfaces warmer than 41°C (105°F). Ambient temperature should be minimum 13°C (55°F) and maximum 41°C (1 05°F).

The information in this Product Data Sheet is not intended to be exhaustive. Any person using the product without first making further enquiries as to the suitability of the product for the intended purpose does so at their own risk and, to the extent permitted by law, we can accept no responsibility for the performance of the product or for any loss or damage arising out of such use. The information contained in this Product Data Sheet is liable to modification from time to time in the light of experience and our policy of continuous product development. AwlgripO and all products mentioned in this Product Data Sheet are trademarks of, or licensed to, Akzo Nobel. ©Akzo Nobel, 2005 1 East Water Street • Waukegan, Illinois 60085 • USA • Tel: 847.599.6212 • Fax: 847.599.6209 Bannerlaan 54 • B-2280 Grobbendonk • Belgium • Intl. Tel: 32.14.257770 • Intl. Fax: 32.14.230880 76 Waterway Drive • Coomera • QLD 4209 • Australia • Tel: 61.7.5573.9600 or 1800.007.866 • Fax: 61.7.5573.9677 449 Tagore Industrial Avenue • 01 03 Hong Joo Industrial Building • Singapore 787820 • Tel: 65.6453.1981 • Fax: 65.6453.1778
Page 2 of 2 • Rev 2 — APRIL 2005 • AWL-FAIR L.W. & AWL-FAIR L.W.T. 

### 34

### $2,500.00

6. 4 VOID AFTER 180 kYS

W GENERAL ACCOUNT 

### p. 37 Technology Sciences Group Inc. BANK ACCOUNT: Wachovia Bank N.A., Washington, DC DATE: 02-01-08 PAYEE: EPA Ha ACCOUNTING OPERATIONS BRANCVRQ 20004 

### CHECK # 3129 REF. # GL # INVOICE # INVOICE DATE DESCRIPTION AMT. PAID 208 20000000000000)00013108 01/31/08 TS-08PIN1 2,500.00

TOTAL 2,500.00 

### e" — Technology Sciences Group Inc. 1150 18th Street N.W., Suite 1000 Washington, DC 20036 (202) 828-8942 

### CHECK # 3129 CHECK DATE 02/01/08

Wachovia Bank N.A. 1300 I Street, N.W. 15-122/540 Washington, D.C. 20005 CHECK AMOUNT 

# EXACTLYEF 

# 2 500 dols 00 cts

.s too fire zero zero zero MO tents

PAY TO THE 

### EPA HQ ACCOUNTING OPERATIONS BRANCH (PM226) ORDER OF 

### P.O. BOX 360 399M

PITTSBURGH, PA 15251-6399

ii' 

## 3 L 29• 05400 L 220 206670046 2980

Technology Sciences Group Inc. BANK ACCOUNT: Wachovia Bank N.A., Washington DC DATE: 02-01-08 PAYEE: EPA HQ ACCOUNTING OPERATIONS BRANCVEW2F16y: 20004 

### CHECK # 3129 REF. # GL # INVOICE # INVOICE DATE DESCRIPTION AMT. PAID 208 20000000000000 )00013108 01/31/08 TS-08PIN1 2,500.00

flEGUARD HTHO USA SFSL2GS CK7S08112S VENDOR REFERENCE #: TOTAL 2,500.00

# PreManufacture Notice and

Notice of Commencement Forms EPA Form 7710-25 (Rev. 5-95) EPA Form 7710-56 (Rev. -96)



# Installation and Use Instructions MS Word 6.0 for Windows

U.S. EPA Approved December 12, 1996 by Anthony Cheatham TSCA Data Administration Section 

# CM

' 

# 4



# W Responsible Care® A Public Commitment p. 38