# EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -003

PARTICULATE MATTER, SULFUR DIOXIDE, AND, VISIBLE EMISSIONS EVALUATION April 5, 2007

Prepared For: Tampa Electric Company Polk Power Station P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Environmental Services Air Services Group

Environmental Services Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Jorge A. Varino Environmental Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1
2.0 DISCUSSION OF RESULTS 2
3.0 SOURCE DESCRIPTION/TEST PROCEDURES 3
4.0 TEST RESULTS PARTICULATE TEST SUMMARY (SOOT BLOWING) 6 PARTICULATE TEST SUMMARY (NON-SOOT BLOWING) 7
SULFUR DIOXIDE DATA SUMMARY 8
VISIBLE EMISSIONS DATA SU MMARY (SOOT BLOWING) 9
VISIBLE EMISSIONS DATA SU MMARY (NON-SOOT BLOWING) 10
HEAT INPUT AND FUEL CONSUMPTION SUMMARY 11
5.0 FIGURES
SAMPLING LOCATION DIAGRAM 13

APPENDICIES

A PARTICULTE TEST CALCULATIONS
B DAILY SULFUR DIOXIDE DATA SUMMARY
C PARTICULATE LABORATORY ANALYTICAL DATA
D BOILER/PRECIPITATOR OPERATIONAL DATA
E FUEL ANALYSIS
F FIELD DATA SHEETS
G SAMPLING EQUIPMENT CALIBRATIONS
H CHAIN OF CUSTODY
I TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION
On April 5, 2007, the Envi ronmental Services, Air Services Group of Tampa Electric Company, performed source emi ssion tests at the Big Bend Station, Boiler No. 3, emissions unit I.D.# 0570039-003. Testing was conducted according to procedures stipulated by t he Florida Department of Environmental Protection (FDEP) for fossil fuel steam generators, and requir ements in Title V
Permit # 0570039-017-AV.

### 2 

## 2.0 DISCUSSION OF RESULTS
The particulate matter emission rate under sootblowing conditions was derived from three United States Environment al Protection Agency (USEPA) Reference Method 5-B test runs. The average of t he three test runs was 0.02 lb/mmBtu.
The FDEP allowable emission rate under soot blowing conditions is 0.03 lb/MMBtu, as listed in condition A.7.

The particulate matter emission rate under non-sootblowing conditions was derived from three USEPA Refe rence Method 5-B test runs. The average of the
three test runs was 0.02 lb/MMBtu. The FDEP allowable emission rate under non-sootblowing conditions is 0.03 lb/ MMBtu, as listed in condition A.7.

The sulfur dioxide emission rate wa s determined using data provided by the Continuous Emissions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was
determined to be 319 lbs/hr. The FDEP a llowable emission rate is 3374 lbs/hr,
based on scenario 3 as listed in condition A.9.e.

Visible emissions were evaluated usi ng a Teledyne Instruments/Monitor Labs, LightHawk 560 transmissometer syst em (S/N 5600448/5600446), during both sootblowing and non-sootblowing testing. The 1-hour average opacity under sootblowing conditions was 4.4%. The 1-hour average opacity under nonsootblowing conditions was 4.3%. The FD EP allowable emission rate is 20%, as
listed in condition A.6.

During the tests performed on April 5, 2007, Boiler No. 3 was operated at an average heat input rate of 3735 mmB tu/hr and an average load of 369 megawatts. The average quantity of f uel burned was 158.5 tons per hour.

### 3 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The common stack 3 (CS003) source sampling location consists of a circular stack 28.83 feet in diameter with four sample ports located 90 degrees apart on t he stack circumference. Upstream and downstream gas flow disturbances were determined to be 8.51 and 2.99 stack diameters from the test ports, respec tively. Using these criteria, a total of 24 sampling points were chosen for particu late sampling, as stipulated in USEPA Method 1 – “Sample and Velocity Traverse s for Stationary Sour ces”. A diagram of the stack sampling location is incl uded in Figure 1 along with other pertinent
information on the test site.

Boiler No. 3 is serviced by an electrostatic precipitator for the control of flyash emissions and a flue gas desulfurization (FGD) system for control of sulfur
dioxide emissions.

Particulate matter sampling was perfo rmed according to USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources". Particulate matter was collected on a high purity, borosilicate mi crofiber filter measuring 82mm in diameter. This dat a is included as Appendix A, and summarized on pages 6 (soot blowing c onditions), and 7 (non-soot blowing conditions) of this report.

Diluent gas sampling and analysis was performed according to USEPA Method 3 "Gas Analysis for Determination of Emi ssion Rate Correction Factor, or Excess Air”. Gas analysis was performed on-site using an Orsat analyzer.

Sulfur Dioxide (SO 2 

### ) and Carbon Dioxide (CO 2 

### ) data were provided by the Continuous Emissions Monitoring S ystem (CEMS), Data Acquisition and Handling System (DAHS). Averages were derived from the time frame of 9:15 through 18:25 EST, corresponding to the time frame of the particulate matter

### 4 

### test. This data is included as Appendix B, and summarized on page 8 of this report.

Visible emissions were assessed using t he installed Continuous Opacity Monitor (COM) system. This data is summariz ed on pages 9 (soot blowing conditions), and 10 (non-soot blowing conditions).

### 5 

## 4.0 TEST RESULTS

## BIG BEND STATION PARTICULATE MATTER DATA SUMMAR Y

Run 1s Run 2s Run 3s V m(std) 

### , scf 36.793 37.451 35.667

B ws 

### , ratio 0.14306 0.14285 0.15378

O 2 

### , % volume 6 66

. 5

M

d 

### , lb/lb - mole 30.48 30.48 30.42

M

s 

### , lb/lb - mole 28.69 28.70 28.51

Q s 

### , acf/min 1189417.1 1212887.6 1155639.9

Q s(std) 

### , dscf/min 912311.6 929634.6 873659.2

I, % 100.5 100.4 101.7

C, lbs/dscf 1.18E-06 1.10E-06 1.29E-06

E r 

### , lb/mmBtu 0.02 0.02 0.02

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) 

### 100.87

1.1890E-06

0.02 30.460

28.634

1185981.51

905201.79 

### T est Summary 36.637

0.146563

6.17 

### Boiler # 3 WET-BOTTOM UTILITY BOILE R April 5, 2007 SOOT BLOWING

6

## BIG BEND STATION PARTICULATE MATTER DATA SUMMAR Y

Run 1 Run 2 Run 3 V m(std) 

### , scf 36.793 37.203 34.606

B ws 

### , ratio 0.14306 0.14718 0.15290

O 2 

### , % volume 6 66

. 5

M

d 

### , lb/lb - mole 30.48 30.48 30.42

M

s 

### , lb/lb - mole 28.69 28.64 28.52

Q s 

### , acf/min 1189493.4 1203808.1 1120107.7

Q s(std) 

### , dscf/min 912253.1 918237.0 848467.2

I, % 100.5 100.9 101.6

C, lbs/dscf 1.25E-06 1.03E-06 1.91E-06

E r 

### , lb/mmBtu 0.02 0.01 0.03

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) 

### 1.3951E-06

0.02 

### NON - SOOT BLOWING

28.620

1171136.38

892985.77

101.00 36.201

0.147712

6.17

30.460 

### Boiler # 3 WET-BOTTOM UTILITY BOILE R April 5, 2007

T est Summary

7

## BIG BEND STATION SULFUR DIOXIDE DATA from CEMs

T est Period Information Start Time 9:15:00 Eastern Standard Time (EST) Stop Time 18:25:00 Eastern Standard Time (EST) T otal Time 9:10:00 Correspondin g to the time frame for the PM test.

Sulfur Dioxide Data: RM - 19 SO 2 

### CO 2 

### SO 2 

### SO 2 

### ppmvw %, wet lb/mmBtu lbs/hr 33.817996 11.84668 0.085 319.26

Calculation Details SO 2 

### , lb/mmBtu = SO 2 

### , ppmvw x C f 

### x F c 

### x (100 / CO2 %, wet)
where: C f



### = 1.6635E-07 (lb/scf)/ppm SO 2 

### F c



### = 1800 scf/mmBtu SO 2 

### , lbs/hr = SO 2 

### , lb/mmBtu x Heat Input, mmBtu/hr where: Heat Input = 3735 mmBtu/hr, from Heat Input Calculation 

### Boiler #3 WET-BOTTOM UTILITY BOILER April 5, 2007

CEM DATA

8

## BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY3 Record# DATE TIME OPACITY3 1 04/05/07 9:15 4.300 31 04/05/07 9:45 4.600 2 04/05/07 9:16 4.200 32 04/05/07 9:46 4.600 3 04/05/07 9:17 4.500 33 04/05/07 9:47 4.300 4 04/05/07 9:18 4.200 34 04/05/07 9:48 4.400 5 04/05/07 9:19 4.200 35 04/05/07 9:49 4.200 6 04/05/07 9:20 4.400 36 04/05/07 9:50 4.500 7 04/05/07 9:21 4.200 37 04/05/07 9:51 4.600 8 04/05/07 9:22 4.600 38 04/05/07 9:52 4.200 9 04/05/07 9:23 4.500 39 04/05/07 9:53 4.300 10 04/05/07 9:24 4.500 40 04/05/07 9:54 4.300 11 04/05/07 9:25 4.500 41 04/05/07 9:55 4.400 12 04/05/07 9:26 4.300 42 04/05/07 9:56 4.300 13 04/05/07 9:27 4.300 43 04/05/07 9:57 4.400 14 04/05/07 9:28 4.500 44 04/05/07 9:58 4.300 15 04/05/07 9:29 4.400 45 04/05/07 9:59 4.200 16 04/05/07 9:30 4.400 46 04/05/07 10:00 4.400 17 04/05/07 9:31 4.500 47 04/05/07 10:01 4.200 18 04/05/07 9:32 4.600 48 04/05/07 10:02 4.100 19 04/05/07 9:33 4.500 49 04/05/07 10:03 4.200 20 04/05/07 9:34 4.700 50 04/05/07 10:04 4.300 21 04/05/07 9:35 4.600 51 04/05/07 10:05 4.300 22 04/05/07 9:36 4.700 52 04/05/07 10:06 4.200 23 04/05/07 9:37 4.900 53 04/05/07 10:07 4.100 24 04/05/07 9:38 4.600 54 04/05/07 10:08 4.300 25 04/05/07 9:39 4.500 55 04/05/07 10:09 4.200 26 04/05/07 9:40 4.600 56 04/05/07 10:10 4.400 27 04/05/07 9:41 4.700 57 04/05/07 10:11 4.200 28 04/05/07 9:42 4.400 58 04/05/07 10:12 4.500 29 04/05/07 9:43 4.200 59 04/05/07 10:13 4.400 30 04/05/07 9:44 4.600 60 04/05/07 10:14 4.300

Test Average: 4.397 % Minimum One Minute Average: 4.100 % Maximum One Minute Average: 4.900 %

Maximum Six Minute Average: 4.667 % 

### Boiler #3 WET BOTTOM UTILITY BOILE R

SOOTBLOWING CONDITIONS

9

## BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY3 Record# DATE TIME OPACITY3 1 04/05/07 11:08 4.400 31 04/05/07 11:38 4.000 2 04/05/07 11:09 4.300 32 04/05/07 11:39 4.500 3 04/05/07 11:10 4.400 33 04/05/07 11:40 4.200 4 04/05/07 11:11 4.400 34 04/05/07 11:41 4.500 5 04/05/07 11:12 4.400 35 04/05/07 11:42 4.500 6 04/05/07 11:13 4.300 36 04/05/07 11:43 4.500 7 04/05/07 11:14 4.400 37 04/05/07 11:44 4.600 8 04/05/07 11:15 4.200 38 04/05/07 11:45 4.700 9 04/05/07 11:16 4.300 39 04/05/07 11:46 4.600 10 04/05/07 11:17 4.200 40 04/05/07 11:47 4.300 11 04/05/07 11:18 4.100 41 04/05/07 11:48 4.300 12 04/05/07 11:19 4.300 42 04/05/07 11:49 4.200 13 04/05/07 11:20 4.100 43 04/05/07 11:50 4.000 14 04/05/07 11:21 4.100 44 04/05/07 11:51 4.600 15 04/05/07 11:22 4.300 45 04/05/07 11:52 4.200 16 04/05/07 11:23 4.400 46 04/05/07 11:53 4.100 17 04/05/07 11:24 4.200 47 04/05/07 11:54 4.100 18 04/05/07 11:25 4.200 48 04/05/07 11:55 4.200 19 04/05/07 11:26 4.100 49 04/05/07 11:56 4.400 20 04/05/07 11:27 4.200 50 04/05/07 11:57 4.200 21 04/05/07 11:28 4.100 51 04/05/07 11:58 4.300 22 04/05/07 11:29 4.000 52 04/05/07 11:59 4.200 23 04/05/07 11:30 4.200 53 04/05/07 12:00 4.300 24 04/05/07 11:31 3.800 54 04/05/07 12:01 4.500 25 04/05/07 11:32 3.900 55 04/05/07 12:02 4.400 26 04/05/07 11:33 4.200 56 04/05/07 12:03 4.300 27 04/05/07 11:34 4.100 57 04/05/07 12:04 4.400 28 04/05/07 11:35 4.400 58 04/05/07 12:05 4.500 29 04/05/07 11:36 4.500 59 04/05/07 12:06 4.600 30 04/05/07 11:37 4.400 60 04/05/07 12:07 4.600

Test Average: 4.295 % Minimum One Minute Average: 3.800 % Maximum One Minute Average: 4.700 %

Maximum Six Minute Average: 4.567 % 

### Boiler #3 WET BOTTOM UTILITY BOILE R NON-SOOTBLOWING CONDITIONS

10

## BIG BEND GENERATING STATION HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (March): 10127 KMBtu/MWh 1.0127E+07 MMBtu/MWh



## Me g aWatt Hour Inte g rator Information Initial Inte g rator Readin g : 562541 MWh

Final Inte g rator Readin g : 565923 MWh T otal: 3382 MWh



## T est Time Information T estin g Start Time: 9:15

T estin g End Time: 18:25

T otal Test Time: 9.17 hours


## Calculated Heat Input Avera g e Unit Load, MW = MWh / hours: 368.8 MW Heat Input, MMBtu/h = MMBtu/MWh x MW: 3734.8 mmBtu/hr


## Fuel Consumption Calculation

Laboratory Sample ID: AA87307 Btu as received: 11783 Btu/lb T ons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 158.5 T ons/hour 

## Coal Fired Boiler Number 3 Apr il 5, 2007

11

### 12 

## 5.0 FIGURESFIGURE 1 EXHAUST STACK 245 FT. BIG BEND STATION CS003

PARTICULATE TRAVERSE POINTS

OUTLET 

# N A

B C D

PORT LOCATION

REVISED 12-31-96 BOILER NO. 3 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 8.5

STACK DIAMETER = 28.8333 FT. STACK AREA = 652.948 SQ.

PORT LENGTH’S = 14 IN. TRAVERSE POINT

1

2

3

4

5

6 % OF STACK DIAMETER IN. FROM STACK WALL

2.1%

6.7%

11.8%

17.7%

25.0%

35.6% 7.27 IN.

23.18 IN.

40.83 IN.

61.24 IN.

86.50 IN.

123.18 IN. 499 FT.

254 FT.

168 FT. 86 FT.

FGD

PRESSURIZED ANNULUS



### 13

## APPENDIX A PARTICULTE TEST CALCULATIONS

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 1s Date: 04/05/07

Sample Time, θ : 60 minutes Nozzle Diameter, D n 

### : 0.283 inches Barometric Pressure, P b 

### : 29.82 "Hg Nozzle Area, A n 

### : 0.000437 ft 2 

### Stack Pressure, P s 

### : 29.79 "Hg Average Orifice Meter, Δ H: 1.301 "H 2 

### O Effective Stack Area, A s 

### : 652.948 ft 2 

### Sample Volume, V m 

### : 39.592 ft 3 

### Pitot Coefficient, Cp: 0.84 dimensionless 

### Average Meter Temp., T m 

### : 100.1 o 

### F Gas Analysis: 14.0 % CO 2 

### Average Stack Temp., T s 

### : 127.3 o 

### F 6.0 % O 2 

### Average √ Δ p: 0.510 "H 2 

### O 0.0 % CO Condensate Volume, V lc 

### : 130.3 ml 80.0 % N 2 

### Meter Box Y: 0.986 dimensionless 

### F-factor, F d 

### , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) 

### = 4.714E-02 x V lc 

### 6.142 scf V m ( std ) 

### = 17.647 x V m 

### x Y x (P b 

### + ( Δ H / 13.6)) / (T m 

### +460) 36.793 dscf B w s 

### = V w ( std ) 

### / (V m ( std ) 

### + V w ( std ) 

### ) 0.143 % FDA = 1.0 - B w s 

### 0.857 % M d 

### = (0.44 x %CO 2 

### ) + (0.32 x %O 2 

### ) + (0.28 x (%N 2 

### + % CO)) 30.48 lb./lb. mole M s 

### = (M d 

### x FDA) + (18.0 x B w s 

### ) 28.69 lb./lb. mole

v s 

### = 85.49 x C p 

### x ( √Δ p) x ( √ (T s 

### + 460) / (M s 

### x P s 

### )) 30.36 ft/second Q s 

### = v s 

### x A s 

### x 60 1189417.1 acf/minute Q s ( std ) 

### = Q s 

### x FDA x (528 / (T s 

### + 460)) x (P s 

### / 29.92)) 912311.6 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 

### 100.5 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01965 grams

Calculated Concentration and Emission Rate Data:

c s 

### = (15.432 x grams) / V m(std) 

### 0.008 grains/dscf grains/acf = c s 

### x 17.647 x P s 

### x (FDA / (T s 

### + 460) 0.006 grains/acf C = c s 

### / 7000 1.177E-06 lbs/dscf E M 

### = C x Q s(std) 

### x 60 64.4 lbs/hr E R 

### = C x F d 

### x (20.9 /(20.9 - %O 2 

### ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 2s Date: 04/05/07

Sample Time, θ : 60 minutes Nozzle Diameter, D n 

### : 0.283 inches Barometric Pressure, P b 

### : 29.82 "Hg Nozzle Area, A n 

### : 0.000437 ft 2 

### Stack Pressure, P s 

### : 29.79 "Hg Average Orifice Meter, Δ H: 1.353 "H 2 

### O Effective Stack Area, A s 

### : 652.948 ft 2 

### Sample Volume, V m 

### : 40.313 ft 3 

### Pitot Coefficient, Cp: 0.84 dimensionless 

### Average Meter Temp., T m 

### : 100.4 o 

### F Gas Analysis: 14.0 % CO 2 

### Average Stack Temp., T s 

### : 127.8 o 

### F 6.0 % O 2 

### Average √ Δ p: 0.520 "H 2 

### O 0.0 % CO Condensate Volume, V lc 

### : 132.4 ml 80.0 % N 2 

### Meter Box Y: 0.986 dimensionless 

### F-factor, F d 

### , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) 

### = 4.714E-02 x V lc 

### 6.241 scf V m ( std ) 

### = 17.647 x V m 

### x Y x (P b 

### + ( Δ H / 13.6)) / (T m 

### +460) 37.451 dscf B w s 

### = V w ( std ) 

### / (V m ( std ) 

### + V w ( std ) 

### ) 0.143 % FDA = 1.0 - B w s 

### 0.857 % M d 

### = (0.44 x %CO 2 

### ) + (0.32 x %O 2 

### ) + (0.28 x (%N 2 

### + % CO)) 30.48 lb./lb. mole M s 

### = (M d 

### x FDA) + (18.0 x B w s 

### ) 28.70 lb./lb. mole

v s 

### = 85.49 x C p 

### x ( √Δ p) x ( √ (T s 

### + 460) / (M s 

### x P s 

### )) 30.96 ft/second Q s 

### = v s 

### x A s 

### x 60 1212887.6 acf/minute Q s ( std ) 

### = Q s 

### x FDA x (528 / (T s 

### + 460)) x (P s 

### / 29.92)) 929634.6 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 

### 100.4 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01870 grams

Calculated Concentration and Emission Rate Data:

c s 

### = (15.432 x grams) / V m(std) 

### 0.008 grains/dscf grains/acf = c s 

### x 17.647 x P s 

### x (FDA / (T s 

### + 460) 0.006 grains/acf C = c s 

### / 7000 1.101E-06 lbs/dscf E M 

### = C x Q s(std) 

### x 60 61.4 lbs/hr E R 

### = C x F d 

### x (20.9 /(20.9 - %O 2 

### ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 3s Date: 04/05/07

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.283 inches Barometric Pressure, P b : 29.80 "Hg Nozzle Area, A n : 0.000437 ft 2 Stack Pressure, P s : 29.77 "Hg Average Orifice Meter, Δ H: 1.215 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 38.478 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 100.4 o F Gas Analysis: 13.5 % CO 2 Average Stack Temp., T s : 128.0 o F 6.5 % O 2 Average √ Δ p: 0.493 "H 2 O 0.0 % CO Condensate Volume, V l c : 137.5 ml 80.0 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.482 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 35.667 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.154 % FDA = 1.0 - B ws 0.846 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.42 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.51 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 29.50 ft/second Q s = v s x A s x 60 1155639.9 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 873659.2 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.7 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02085 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.009 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.007 grains/acf C = c s / 7000 1.289E-06 lbs/dscf E M = C x Q s(std) x 60 67.6 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 1 Date: 04/05/07

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.283 inches Barometric Pressure, P b : 29.82 "Hg Nozzle Area, A n : 0.000437 ft 2 Stack Pressure, P s : 29.79 "Hg Average Orifice Meter, Δ H: 1.301 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.592 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 100.1 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 127.3 o F 6.0 % O 2 Average √ Δ p: 0.510 "H 2 O 0.0 % CO Condensate Volume, V l c : 130.3 ml 80.0 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.142 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 36.793 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.143 % FDA = 1.0 - B ws 0.857 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.48 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.69 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 30.36 ft/second Q s = v s x A s x 60 1189493.4 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 912253.1 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.5 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02080 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.009 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.007 grains/acf C = c s / 7000 1.246E-06 lbs/dscf E M = C x Q s(std) x 60 68.2 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 2 Date: 04/05/07

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.283 inches Barometric Pressure, P b : 29.80 "Hg Nozzle Area, A n : 0.000437 ft 2 Stack Pressure, P s : 29.76 "Hg Average Orifice Meter, Δ H: 1.333 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 40.083 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 100.5 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 127.3 o F 6.0 % O 2 Average √ Δ p: 0.516 "H 2 O 0.0 % CO Condensate Volume, V l c : 136.2 ml 80.0 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.420 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 37.203 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.147 % FDA = 1.0 - B ws 0.853 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.48 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.64 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 30.73 ft/second Q s = v s x A s x 60 1203808.1 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 918237.0 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.9 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01740 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.007 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.031E-06 lbs/dscf E M = C x Q s(std) x 60 56.8 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.01 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 3 Date: 04/05/07

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.283 inches Barometric Pressure, P b : 29.80 "Hg Nozzle Area, A n : 0.000437 ft 2 Stack Pressure, P s : 29.77 "Hg Average Orifice Meter, Δ H: 1.151 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 37.321 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 100.8 o F Gas Analysis: 13.5 % CO 2 Average Stack Temp., T s : 127.4 o F 6.5 % O 2 Average √ Δ p: 0.479 "H 2 O 0.0 % CO Condensate Volume, V l c : 132.5 ml 80.0 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.246 scf V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 34.606 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.153 % FDA = 1.0 - B ws 0.847 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.42 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.52 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 28.59 ft/second Q s = v s x A s x 60 1120107.7 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 848467.2 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.6 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02995 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0134 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0101 grains/acf C = c s / 7000 1.908E-06 lbs/dscf E M = C x Q s(std) x 60 97.1 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.03 lbs/MMBtu

## APPENDIX B DAILY SULFUR DIOXIDE DATA SUMMARY

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 1 04/05/07 9:15 11.81 47.8 

### 2 04/05/07 9:16 11.73 52.6 

### 3 04/05/07 9:17 11.83 56.9 

### 4 04/05/07 9:18 11.76 52.2 

### 5 04/05/07 9:19 11.77 48.9 

### 6 04/05/07 9:20 11.74 43.1 

### 7 04/05/07 9:21 11.67 38 

### 8 04/05/07 9:22 11.79 35.3 

### 9 04/05/07 9:23 11.89 34.8 

### 10 04/05/07 9:24 11.87 36 

### 11 04/05/07 9:25 11.77 33.1 

### 12 04/05/07 9:26 11.84 34.1 

### 13 04/05/07 9:27 11.89 38.9 

### 14 04/05/07 9:28 11.85 40.6 

### 15 04/05/07 9:29 11.83 42 

### 16 04/05/07 9:30 11.91 44.3 

### 17 04/05/07 9:31 11.84 43.6 

### 18 04/05/07 9:32 11.73 44.4 

### 19 04/05/07 9:33 11.82 47.9 

### 20 04/05/07 9:34 11.82 55.7 

### 21 04/05/07 9:35 11.89 59.5 

### 22 04/05/07 9:36 11.77 56.9 

### 23 04/05/07 9:37 11.76 52.2 

### 24 04/05/07 9:38 11.79 42.1 

### 25 04/05/07 9:39 11.77 37.1 

### 26 04/05/07 9:40 11.76 40.5 

### 27 04/05/07 9:41 11.78 44.1 

### 28 04/05/07 9:42 11.74 45.5 

### 29 04/05/07 9:43 11.76 43.2 

### 30 04/05/07 9:44 11.82 37.8 

### 31 04/05/07 9:45 11.84 37.6 

### 32 04/05/07 9:46 11.82 36.5 

### 33 04/05/07 9:47 11.79 34.3 

### 34 04/05/07 9:48 11.86 35 

### 35 04/05/07 9:49 11.86 40.8 

### 36 04/05/07 9:50 11.74 42.9 

### 37 04/05/07 9:51 11.78 46.1 

### 38 04/05/07 9:52 11.85 48.5 

### 39 04/05/07 9:53 11.83 50.3



### 1 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 40 04/05/07 9:54 11.82 47.3 

### 41 04/05/07 9:55 11.78 42 

### 42 04/05/07 9:56 11.79 40.9 

### 43 04/05/07 9:57 11.91 48.6 

### 44 04/05/07 9:58 11.84 49.2 

### 45 04/05/07 9:59 11.88 43.9 

### 46 04/05/07 10:00 11.81 37.4 

### 47 04/05/07 10:01 11.78 37.5 

### 48 04/05/07 10:02 

### 49 04/05/07 10:03 

### 50 04/05/07 10:04 

### 51 04/05/07 10:05 

### 52 04/05/07 10:06 

### 53 04/05/07 10:07 

### 54 04/05/07 10:08 11.82 42.6 

### 55 04/05/07 10:09 11.87 42.7 

### 56 04/05/07 10:10 11.79 44.1 

### 57 04/05/07 10:11 11.83 46.5 

### 58 04/05/07 10:12 11.78 43.2 

### 59 04/05/07 10:13 11.95 40.1 

### 60 04/05/07 10:14 11.89 40.5 

### 61 04/05/07 10:15 11.91 41.6 

### 62 04/05/07 10:16 11.85 40.3 

### 63 04/05/07 10:17 11.79 40.1 

### 64 04/05/07 10:18 11.79 32.4 

### 65 04/05/07 10:19 11.79 30.9 

### 66 04/05/07 10:20 11.87 34.6 

### 67 04/05/07 10:21 11.93 37.1 

### 68 04/05/07 10:22 11.92 37.6 

### 69 04/05/07 10:23 11.87 36.1 

### 70 04/05/07 10:24 11.85 34.2 

### 71 04/05/07 10:25 11.82 37.7 

### 72 04/05/07 10:26 11.85 37 

### 73 04/05/07 10:27 11.84 39.5 

### 74 04/05/07 10:28 11.86 41.6 

### 75 04/05/07 10:29 11.87 45.2 

### 76 04/05/07 10:30 11.88 46.6 

### 77 04/05/07 10:31 11.89 45.3 

### 78 04/05/07 10:32 11.81 46 Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back



### 2 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 79 04/05/07 10:33 11.84 48.1 

### 80 04/05/07 10:34 11.84 50.2 

### 81 04/05/07 10:35 11.77 43.7 

### 82 04/05/07 10:36 11.82 36.7 

### 83 04/05/07 10:37 11.78 31.7 

### 84 04/05/07 10:38 11.79 29.3 

### 85 04/05/07 10:39 11.83 29.7 

### 86 04/05/07 10:40 11.72 30.2 

### 87 04/05/07 10:41 11.81 32.6 

### 88 04/05/07 10:42 11.86 32.2 

### 89 04/05/07 10:43 11.87 32.2 

### 90 04/05/07 10:44 11.84 33.9 

### 91 04/05/07 10:45 11.82 37 

### 92 04/05/07 10:46 11.89 39.3 

### 93 04/05/07 10:47 11.91 39.3 

### 94 04/05/07 10:48 11.92 41.5 

### 95 04/05/07 10:49 11.91 40.8 

### 96 04/05/07 10:50 11.75 39.9 

### 97 04/05/07 10:51 11.85 41.5 

### 98 04/05/07 10:52 11.86 38.1 

### 99 04/05/07 10:53 11.81 34.9 

### 100 04/05/07 10:54 11.83 35.4 

### 101 04/05/07 10:55 11.89 33.1 

### 102 04/05/07 10:56 12 30.4 

### 103 04/05/07 10:57 11.93 31.1 

### 104 04/05/07 10:58 12.01 31.9 

### 105 04/05/07 10:59 11.9 30 

### 106 04/05/07 11:00 11.88 29.8 

### 107 04/05/07 11:01 11.92 33.5 

### 108 04/05/07 11:02 11.89 34.3 

### 109 04/05/07 11:03 11.78 33.2 

### 110 04/05/07 11:04 11.84 31.5 

### 111 04/05/07 11:05 11.82 34.5 

### 112 04/05/07 11:06 11.88 38.7 

### 113 04/05/07 11:07 11.88 37.9 

### 114 04/05/07 11:08 11.86 36.9 

### 115 04/05/07 11:09 11.86 39.7 

### 116 04/05/07 11:10 11.93 42.9 

### 117 04/05/07 11:11 12.07 40.2



### 3 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 118 04/05/07 11:12 12.09 34.6 

### 119 04/05/07 11:13 11.89 34.5 

### 120 04/05/07 11:14 11.94 38.5 

### 121 04/05/07 11:15 11.84 37.7 

### 122 04/05/07 11:16 11.81 35.4 

### 123 04/05/07 11:17 11.79 35.6 

### 124 04/05/07 11:18 11.74 37.8 

### 125 04/05/07 11:19 11.94 35.7 

### 126 04/05/07 11:20 11.94 36.2 

### 127 04/05/07 11:21 11.98 36.9 

### 128 04/05/07 11:22 11.93 35 

### 129 04/05/07 11:23 11.85 33.9 

### 130 04/05/07 11:24 11.83 32.8 

### 131 04/05/07 11:25 11.91 28.6 

### 132 04/05/07 11:26 11.84 26.2 

### 133 04/05/07 11:27 11.87 26.6 

### 134 04/05/07 11:28 11.85 27 

### 135 04/05/07 11:29 11.74 27.8 

### 136 04/05/07 11:30 11.88 32.1 

### 137 04/05/07 11:31 11.91 32.6 

### 138 04/05/07 11:32 11.9 32 

### 139 04/05/07 11:33 11.95 34.9 

### 140 04/05/07 11:34 12.01 37.6 

### 141 04/05/07 11:35 11.95 38.2 

### 142 04/05/07 11:36 11.98 39.9 

### 143 04/05/07 11:37 12.01 40.9 

### 144 04/05/07 11:38 11.95 44.7 

### 145 04/05/07 11:39 11.84 45.6 

### 146 04/05/07 11:40 11.85 45.7 

### 147 04/05/07 11:41 11.77 41.3 

### 148 04/05/07 11:42 11.79 38.4 

### 153 04/05/07 11:43 11.8 35 

### 154 04/05/07 11:44 11.94 32.4 

### 155 04/05/07 11:45 11.96 34.2 

### 156 04/05/07 11:46 11.92 33 

### 157 04/05/07 11:47 11.94 35.7 

### 158 04/05/07 11:48 11.84 34.8 

### 159 04/05/07 11:49 11.82 38.4 

### 160 04/05/07 11:50 11.85 39



### 4 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 161 04/05/07 11:51 11.94 39.9 

### 162 04/05/07 11:52 11.81 39.4 

### 163 04/05/07 11:53 11.78 37.5 

### 164 04/05/07 11:54 11.78 36 

### 165 04/05/07 11:55 11.84 36.4 

### 166 04/05/07 11:56 11.77 38 

### 167 04/05/07 11:57 11.75 40 

### 168 04/05/07 11:58 11.84 42.1 

### 169 04/05/07 11:59 11.92 45.2 

### 170 04/05/07 12:00 11.96 39.1 

### 171 04/05/07 12:01 11.92 31.7 

### 172 04/05/07 12:02 11.97 25.1 

### 173 04/05/07 12:03 11.88 25 

### 174 04/05/07 12:04 11.9 26.5 

### 175 04/05/07 12:05 11.97 28.6 

### 176 04/05/07 12:06 11.88 31.1 

### 177 04/05/07 12:07 11.93 33.4 

### 178 04/05/07 12:08 11.92 39.5 

### 179 04/05/07 12:09 11.83 41.1 

### 180 04/05/07 12:10 11.8 36.5 

### 181 04/05/07 12:11 11.87 34.9 

### 182 04/05/07 12:12 11.78 32.4 

### 183 04/05/07 12:13 11.86 32.8 

### 184 04/05/07 12:14 11.85 35.1 

### 185 04/05/07 12:15 11.91 38.6 

### 186 04/05/07 12:16 11.95 43 

### 187 04/05/07 12:17 11.97 45 

### 188 04/05/07 12:18 11.9 45.5 

### 189 04/05/07 12:19 11.98 45.4 

### 190 04/05/07 12:20 11.92 37.5 

### 191 04/05/07 12:21 11.92 27 

### 192 04/05/07 12:22 11.92 24.7 

### 193 04/05/07 12:23 11.96 26.7 

### 194 04/05/07 12:24 11.87 30.1 

### 195 04/05/07 12:25 12 33.7 

### 196 04/05/07 12:26 11.9 35 

### 197 04/05/07 12:27 11.91 38.1 

### 198 04/05/07 12:28 11.87 37.4 

### 199 04/05/07 12:29 11.97 37.7



### 5 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 200 04/05/07 12:30 11.88 35.4 

### 201 04/05/07 12:31 11.91 35.1 

### 202 04/05/07 12:32 11.76 34 

### 203 04/05/07 12:33 11.92 35.5 

### 204 04/05/07 12:34 11.94 36.2 

### 205 04/05/07 12:35 12.01 41.3 

### 206 04/05/07 12:36 11.93 44 

### 207 04/05/07 12:37 11.89 48.1 

### 208 04/05/07 12:38 11.93 51.7 

### 209 04/05/07 12:39 12.04 45.9 

### 210 04/05/07 12:40 11.91 37 

### 211 04/05/07 12:41 11.89 32.3 

### 212 04/05/07 12:42 11.83 32.3 

### 213 04/05/07 12:43 11.81 33.5 

### 214 04/05/07 12:44 11.78 32.2 

### 215 04/05/07 12:45 11.91 33.6 

### 216 04/05/07 12:46 11.94 32.7 

### 217 04/05/07 12:47 11.91 35.2 

### 218 04/05/07 12:48 11.77 38.4 

### 219 04/05/07 12:49 11.81 39.4 

### 220 04/05/07 12:50 11.88 42.3 

### 221 04/05/07 12:51 11.89 38.7 

### 222 04/05/07 12:52 11.94 36.4 

### 223 04/05/07 12:53 11.9 40.3 

### 224 04/05/07 12:54 11.74 37.7 

### 225 04/05/07 12:55 11.84 42.5 

### 226 04/05/07 12:56 11.81 45.1 

### 227 04/05/07 12:57 11.8 44.7 

### 228 04/05/07 12:58 11.9 45.9 

### 229 04/05/07 12:59 11.88 42.1 

### 230 04/05/07 13:00 11.82 41.1 

### 231 04/05/07 13:01 11.81 36.2 

### 232 04/05/07 13:02 11.83 31.6 

### 233 04/05/07 13:03 11.8 33.4 

### 234 04/05/07 13:04 11.8 35.2 

### 235 04/05/07 13:05 11.91 37.2 

### 236 04/05/07 13:06 12.01 35 

### 237 04/05/07 13:07 12.04 32.4 

### 238 04/05/07 13:08 11.97 29.5



### 6 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 239 04/05/07 13:09 12.02 29.3 

### 240 04/05/07 13:10 12.02 27.4 

### 241 04/05/07 13:11 12.03 33.4 

### 242 04/05/07 13:12 11.99 34.8 

### 243 04/05/07 13:13 11.91 39.1 

### 244 04/05/07 13:14 11.95 39.1 

### 245 04/05/07 13:15 11.87 43 

### 246 04/05/07 13:16 11.86 42.8 

### 247 04/05/07 13:17 11.83 42 

### 248 04/05/07 13:18 11.85 38 

### 249 04/05/07 13:19 11.8 35.6 

### 250 04/05/07 13:20 11.67 36.1 

### 251 04/05/07 13:21 11.78 37.7 

### 252 04/05/07 13:22 11.84 34.3 

### 253 04/05/07 13:23 11.95 33.7 

### 254 04/05/07 13:24 11.81 36.2 

### 255 04/05/07 13:25 11.81 35.5 

### 256 04/05/07 13:26 11.8 34.8 

### 257 04/05/07 13:27 11.96 34.5 

### 258 04/05/07 13:28 11.85 34.3 

### 259 04/05/07 13:29 11.78 32.1 

### 260 04/05/07 13:30 11.83 32.6 

### 261 04/05/07 13:31 11.76 35.1 

### 262 04/05/07 13:32 11.82 36.8 

### 263 04/05/07 13:33 11.76 37.2 

### 264 04/05/07 13:34 11.82 36.7 

### 265 04/05/07 13:35 11.85 40 

### 266 04/05/07 13:36 11.87 40.9 

### 267 04/05/07 13:37 11.94 40.6 

### 268 04/05/07 13:38 11.92 42.6 

### 269 04/05/07 13:39 11.86 45.8 

### 270 04/05/07 13:40 11.8 44.2 

### 271 04/05/07 13:41 11.72 43.7 

### 272 04/05/07 13:42 11.69 44.5 

### 273 04/05/07 13:43 11.64 41.3 

### 274 04/05/07 13:44 11.76 39.8 

### 275 04/05/07 13:45 11.86 36.9 

### 276 04/05/07 13:46 11.85 35 

### 277 04/05/07 13:47 11.85 31.8



### 7 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 278 04/05/07 13:48 11.93 34.5 

### 279 04/05/07 13:49 11.91 35.1 

### 280 04/05/07 13:50 11.83 39.7 

### 281 04/05/07 13:51 11.8 40.8 

### 282 04/05/07 13:52 11.82 36.4 

### 283 04/05/07 13:53 11.83 34.6 

### 284 04/05/07 13:54 11.76 34.2 

### 285 04/05/07 13:55 11.69 33.2 

### 286 04/05/07 13:56 11.8 32.7 

### 287 04/05/07 13:57 11.8 35 

### 288 04/05/07 13:58 11.81 39.2 

### 289 04/05/07 13:59 11.84 41.3 

### 290 04/05/07 14:00 11.97 43.8 

### 291 04/05/07 14:01 11.96 45.6 

### 292 04/05/07 14:02 11.89 48.4 

### 293 04/05/07 14:03 11.83 43 

### 294 04/05/07 14:04 11.78 41.4 

### 295 04/05/07 14:05 11.81 42.9 

### 296 04/05/07 14:06 11.78 40.5 

### 297 04/05/07 14:07 11.79 37.1 

### 298 04/05/07 14:08 11.8 38.8 

### 299 04/05/07 14:09 11.83 38.8 

### 300 04/05/07 14:10 11.77 37.5 

### 301 04/05/07 14:11 11.83 36 

### 302 04/05/07 14:12 11.87 39 

### 303 04/05/07 14:13 11.87 38.6 

### 304 04/05/07 14:14 11.79 38.7 

### 305 04/05/07 14:15 11.82 35.8 

### 306 04/05/07 14:16 11.89 33.5 

### 307 04/05/07 14:17 11.89 34.7 

### 308 04/05/07 14:18 11.86 38.8 

### 309 04/05/07 14:19 11.82 38.1 

### 310 04/05/07 14:20 11.77 35.7 

### 311 04/05/07 14:21 11.8 36.8 

### 312 04/05/07 14:22 11.84 37.1 

### 313 04/05/07 14:23 11.88 35.9 

### 314 04/05/07 14:24 11.9 34.2 

### 315 04/05/07 14:25 11.85 35.5 

### 316 04/05/07 14:26 11.92 36.7



### 8 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 317 04/05/07 14:27 11.92 39 

### 318 04/05/07 14:28 12.02 38.2 

### 319 04/05/07 14:29 11.94 34.7 

### 320 04/05/07 14:30 11.95 31.1 

### 321 04/05/07 14:31 11.98 30.2 

### 322 04/05/07 14:32 12.05 30.1 

### 323 04/05/07 14:33 12 31.7 

### 324 04/05/07 14:34 12 33.8 

### 325 04/05/07 14:35 11.96 35.1 

### 326 04/05/07 14:36 11.85 34.7 

### 327 04/05/07 14:37 11.88 39 

### 328 04/05/07 14:38 11.85 37.3 

### 329 04/05/07 14:39 11.91 32.1 

### 330 04/05/07 14:40 11.88 30.5 

### 331 04/05/07 14:41 12 32.1 

### 332 04/05/07 14:42 11.93 31.9 

### 333 04/05/07 14:43 11.93 32.1 

### 334 04/05/07 14:44 11.95 32.8 

### 335 04/05/07 14:45 11.85 34.4 

### 336 04/05/07 14:46 11.81 35.6 

### 337 04/05/07 14:47 11.83 37.6 

### 338 04/05/07 14:48 11.85 40.8 

### 339 04/05/07 14:49 11.92 41.5 

### 340 04/05/07 14:50 11.96 36.5 

### 341 04/05/07 14:51 11.93 29.8 

### 342 04/05/07 14:52 11.93 24.7 

### 343 04/05/07 14:53 11.9 22.8 

### 344 04/05/07 14:54 11.82 22.4 

### 345 04/05/07 14:55 11.85 23.2 

### 346 04/05/07 14:56 11.89 25.3 

### 347 04/05/07 14:57 11.9 27 

### 348 04/05/07 14:58 11.91 28.1 

### 349 04/05/07 14:59 11.98 30.3 

### 350 04/05/07 15:00 12.06 32 

### 351 04/05/07 15:01 12.02 34 

### 352 04/05/07 15:02 11.91 34.1 

### 353 04/05/07 15:03 11.92 33.4 

### 354 04/05/07 15:04 11.79 30.1 

### 355 04/05/07 15:05 11.84 32.6



### 9 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 356 04/05/07 15:06 11.85 34.7 

### 357 04/05/07 15:07 11.96 31 

### 358 04/05/07 15:08 11.99 24.4 

### 359 04/05/07 15:09 12.02 26.1 

### 360 04/05/07 15:10 12 25.6 

### 361 04/05/07 15:11 11.99 25 

### 362 04/05/07 15:12 11.88 22.9 

### 363 04/05/07 15:13 11.89 23.6 

### 364 04/05/07 15:14 11.83 24 

### 365 04/05/07 15:15 11.8 25.5 

### 366 04/05/07 15:16 11.89 25.1 

### 367 04/05/07 15:17 11.88 29.9 

### 368 04/05/07 15:18 11.88 32.2 

### 369 04/05/07 15:19 11.9 31.8 

### 370 04/05/07 15:20 11.96 32.1 

### 371 04/05/07 15:21 12 32 

### 372 04/05/07 15:22 11.88 31.5 

### 373 04/05/07 15:23 11.89 27.6 

### 374 04/05/07 15:24 11.85 25.7 

### 375 04/05/07 15:25 11.87 28.5 

### 376 04/05/07 15:26 11.93 31.1 

### 377 04/05/07 15:27 11.91 31.6 

### 378 04/05/07 15:28 11.83 30.8 

### 379 04/05/07 15:29 11.81 33.5 

### 380 04/05/07 15:30 11.86 35.2 

### 381 04/05/07 15:31 11.87 31.9 

### 382 04/05/07 15:32 11.86 27.3 

### 383 04/05/07 15:33 11.86 27.6 

### 384 04/05/07 15:34 11.81 28.9 

### 385 04/05/07 15:35 11.8 30 

### 386 04/05/07 15:36 11.79 26.2 

### 387 04/05/07 15:37 11.84 25.7 

### 388 04/05/07 15:38 11.86 23.9 

### 389 04/05/07 15:39 11.8 24.4 

### 390 04/05/07 15:40 11.91 23.8 

### 391 04/05/07 15:41 11.87 26.9 

### 392 04/05/07 15:42 11.83 28.6 

### 393 04/05/07 15:43 11.85 28.6 

### 394 04/05/07 15:44 11.78 28.3



### 10 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 395 04/05/07 15:45 11.86 30.9 

### 396 04/05/07 15:46 11.83 31.7 

### 397 04/05/07 15:47 11.79 33.5 

### 398 04/05/07 15:48 11.75 34.8 

### 399 04/05/07 15:49 11.9 36 

### 400 04/05/07 15:50 11.91 39 

### 401 04/05/07 15:51 11.85 39.9 

### 402 04/05/07 15:52 11.88 36.5 

### 403 04/05/07 15:53 11.81 32.5 

### 404 04/05/07 15:54 11.88 31.8 

### 405 04/05/07 15:55 11.88 27.5 

### 406 04/05/07 15:56 11.77 25.1 

### 407 04/05/07 15:57 11.81 24.5 

### 408 04/05/07 15:58 11.81 26.9 

### 409 04/05/07 15:59 11.83 28.8 

### 410 04/05/07 16:00 11.77 27.4 

### 411 04/05/07 16:01 11.75 26.4 

### 412 04/05/07 16:02 

### 413 04/05/07 16:03 

### 414 04/05/07 16:04 

### 415 04/05/07 16:05 

### 416 04/05/07 16:06 

### 417 04/05/07 16:07 

### 418 04/05/07 16:08 11.7 37.2 

### 419 04/05/07 16:09 11.66 33.5 

### 420 04/05/07 16:10 11.62 27.3 

### 421 04/05/07 16:11 11.62 27 

### 422 04/05/07 16:12 11.7 28.8 

### 423 04/05/07 16:13 11.74 29.4 

### 424 04/05/07 16:14 11.75 29.5 

### 425 04/05/07 16:15 11.87 27.9 

### 426 04/05/07 16:16 11.93 25.7 

### 427 04/05/07 16:17 11.9 25.4 

### 428 04/05/07 16:18 11.91 25.6 

### 429 04/05/07 16:19 11.93 28.8 

### 430 04/05/07 16:20 11.82 27.8 

### 431 04/05/07 16:21 11.73 25.9 

### 432 04/05/07 16:22 11.73 24.9 

### 433 04/05/07 16:23 11.71 25 Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back Unit Probe in blow-back



### 11 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 434 04/05/07 16:24 11.65 24.5 

### 435 04/05/07 16:25 11.7 25.7 

### 436 04/05/07 16:26 11.73 26.9 

### 437 04/05/07 16:27 11.77 27.8 

### 438 04/05/07 16:28 11.78 31.2 

### 439 04/05/07 16:29 11.84 32.3 

### 440 04/05/07 16:30 11.8 29.8 

### 441 04/05/07 16:31 11.83 32.1 

### 442 04/05/07 16:32 11.84 33.2 

### 443 04/05/07 16:33 11.64 32.6 

### 444 04/05/07 16:34 11.67 31 

### 445 04/05/07 16:35 11.73 26.3 

### 446 04/05/07 16:36 11.73 24.9 

### 447 04/05/07 16:37 11.64 23 

### 448 04/05/07 16:38 11.8 23.4 

### 449 04/05/07 16:39 11.81 25.6 

### 450 04/05/07 16:40 11.8 26.7 

### 451 04/05/07 16:41 11.79 26.3 

### 452 04/05/07 16:42 11.98 24.2 

### 453 04/05/07 16:43 11.88 25 

### 454 04/05/07 16:44 11.87 27.8 

### 455 04/05/07 16:45 11.78 27.2 

### 456 04/05/07 16:46 11.86 25.4 

### 457 04/05/07 16:47 11.81 26.4 

### 458 04/05/07 16:48 11.71 26.4 

### 459 04/05/07 16:49 11.76 30.5 

### 460 04/05/07 16:50 11.78 35.6 

### 461 04/05/07 16:51 11.76 40.3 

### 462 04/05/07 16:52 11.81 41.2 

### 463 04/05/07 16:53 11.85 36.8 

### 464 04/05/07 16:54 11.79 34.1 

### 465 04/05/07 16:55 11.7 29.1 

### 466 04/05/07 16:56 11.71 25.1 

### 467 04/05/07 16:57 11.76 26.2 

### 468 04/05/07 16:58 11.81 27 

### 469 04/05/07 16:59 11.82 25.3 

### 470 04/05/07 17:00 11.83 24.4 

### 471 04/05/07 17:01 11.86 24.7 

### 472 04/05/07 17:02 11.81 25.1



### 12 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 473 04/05/07 17:03 11.81 25.8 

### 474 04/05/07 17:04 11.9 26.7 

### 475 04/05/07 17:05 11.92 26.4 

### 476 04/05/07 17:06 11.81 24 

### 477 04/05/07 17:07 11.9 25.3 

### 478 04/05/07 17:08 11.78 26.4 

### 479 04/05/07 17:09 11.79 27.2 

### 480 04/05/07 17:10 11.82 29.1 

### 481 04/05/07 17:11 11.75 32.5 

### 482 04/05/07 17:12 11.79 31.5 

### 483 04/05/07 17:13 11.75 28.2 

### 484 04/05/07 17:14 11.81 25.1 

### 485 04/05/07 17:15 11.83 22.3 

### 486 04/05/07 17:16 11.88 21.4 

### 487 04/05/07 17:17 11.8 21.5 

### 488 04/05/07 17:18 11.79 21 

### 489 04/05/07 17:19 11.75 23.1 

### 490 04/05/07 17:20 11.76 24.9 

### 491 04/05/07 17:21 11.8 25.8 

### 492 04/05/07 17:22 11.72 25.6 

### 493 04/05/07 17:23 11.78 26.7 

### 494 04/05/07 17:24 11.75 27.9 

### 495 04/05/07 17:25 11.84 26.3 

### 496 04/05/07 17:26 11.83 25.3 

### 497 04/05/07 17:27 11.87 27 

### 498 04/05/07 17:28 11.79 30 

### 499 04/05/07 17:29 11.84 31.8 

### 500 04/05/07 17:30 11.79 33.4 

### 501 04/05/07 17:31 11.83 34.8 

### 502 04/05/07 17:32 11.75 32.8 

### 503 04/05/07 17:33 11.86 27.2 

### 504 04/05/07 17:34 11.82 21.6 

### 505 04/05/07 17:35 11.89 21 

### 506 04/05/07 17:36 11.77 20.8 

### 507 04/05/07 17:37 11.76 20.8 

### 508 04/05/07 17:38 11.86 20.8 

### 509 04/05/07 17:39 11.82 22.9 

### 510 04/05/07 17:40 11.8 24.4 

### 511 04/05/07 17:41 11.82 24.9



### 13 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 512 04/05/07 17:42 11.78 25.3 

### 513 04/05/07 17:43 11.82 27.6 

### 514 04/05/07 17:44 11.85 28.3 

### 515 04/05/07 17:45 11.9 26.7 

### 516 04/05/07 17:46 11.84 24.6 

### 517 04/05/07 17:47 11.85 26.2 

### 518 04/05/07 17:48 11.79 29.1 

### 519 04/05/07 17:49 11.83 29.2 

### 520 04/05/07 17:50 11.86 26.4 

### 521 04/05/07 17:51 11.98 28.5 

### 522 04/05/07 17:52 11.95 27.4 

### 523 04/05/07 17:53 11.95 24.6 

### 524 04/05/07 17:54 11.86 21.5 

### 525 04/05/07 17:55 11.77 19.7 

### 526 04/05/07 17:56 11.69 20.3 

### 527 04/05/07 17:57 11.69 20.6 

### 528 04/05/07 17:58 11.65 21.7 

### 529 04/05/07 17:59 11.63 22.9 

### 530 04/05/07 18:00 11.74 24.9 

### 531 04/05/07 18:01 11.8 27 

### 532 04/05/07 18:02 11.81 29.7 

### 533 04/05/07 18:03 11.77 30 

### 534 04/05/07 18:04 11.73 28.1 

### 535 04/05/07 18:05 11.79 27 

### 536 04/05/07 18:06 11.76 26.3 

### 537 04/05/07 18:07 11.69 26.5 

### 538 04/05/07 18:08 11.77 24.7 

### 539 04/05/07 18:09 11.73 22.9 

### 540 04/05/07 18:10 11.86 24.1 

### 541 04/05/07 18:11 11.79 22 

### 542 04/05/07 18:12 11.77 20.1 

### 543 04/05/07 18:13 11.73 19.1 

### 544 04/05/07 18:14 11.76 20.1 

### 545 04/05/07 18:15 11.74 20.8 

### 546 04/05/07 18:16 11.78 20.5 

### 547 04/05/07 18:17 11.9 20.6 

### 548 04/05/07 18:18 11.92 22.6 

### 549 04/05/07 18:19 11.83 24.7 

### 550 04/05/07 18:20 11.84 25.6



### 14 of 15

### SO2 Data Big Bend 3.xls

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 551 04/05/07 18:21 11.89 27.1 

### 552 04/05/07 18:22 11.87 28.8 

### 553 04/05/07 18:23 11.83 28.8 

### 554 04/05/07 18:24 11.82 26.6 

### 555 04/05/07 18:25 11.83 25.4



### 15 of 15

## APPENDIX C PARTICULATE LABORATORY ANALYTICAL DATACustomer Air Services Plant Big Bend Unit3Method 5B Stack Test Completion Date04/05/2007Analyst gahSample NumberACETONE BEAKER1st weighingDate 04/11/2007 Time 11:00 % RH 48.0%2nd weighing Date 04/13/2007 Time 11:10 % RH 42.0%3rd weighing Date 04/16/2007 Time 10:35 % RH 36.0%4th weighing Date 04/16/2007 Time 16:35 % RH 39.0%***Blank***Run 1 Run 2 Run 3 (NOTE 1) Run 1S Run 2S Run 3S(NOTE 2)Acetone Container IDAir 87 Air 20 Air 18 Air 10 Air 14 Air 24 Air 5Acetone Rinse Vol.(Va), mls 200.0000 200 200 200 200 200 2001st Gross Wt., grams 101.3277 106.1842 103.3149 110.4900 107.3081 97.4103 101.45422nd Gross Wt., grams 101.3269 106.1838 103.3136 110.4892 107.3071 97.4100 101.45293rd Gross Wt., grams 101.3272 103.3150 110.4925 107.3074 101.45554th Gross Wt., grams 103.3155 110.4923 101.4557Avg. Gross Wt., grams 101.32705 106.18400 103.31525 110.49240 107.30725 97.41015 101.45560Tare Wt., grams 101.32575 106.17595 103.30660 110.47300 107.30000 97.40545 101.44680Acetone Blank Wt.,mg1.30 1.30 1.30 1.30 1.30 1.30 1.30Acetone Particulate Wt.,mg6.75 7.35 18.10 5.95 3.40 7.50Acetone Residue, mg/g0.0082Acetone Blank CriteriaFILTER1st weighingDate 04/10/2007 Time 16:35 % RH 47.0%Date 04/11/2007 Time 11:10 % RH 48.0%3rd weighing Date Time % RH4th weighing Date Time % RHFilter/Thimble ID 203058 203036 203054 203035 203042 203045 2030551st Gross Wt., grams 0.2508 0.2827 0.2626 0.2823 0.2824 0.2820 0.26632nd Gross Wt., grams 0.2509 0.2824 0.2626 0.2822 0.2821 0.2819 0.26643rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams 0.25085 0.28255 0.26260 0.28225 0.28225 0.28195 0.26635Tare Wt., grams 0.25065 0.26850 0.25255 0.27040 0.26855 0.26665 0.25300Filter Particulate Wt.,mg14.05 10.05 11.85 13.70 15.30 13.35Difference, milligrams0.2Total Sample Particulate Wt.,mg20.80 17.40 29.95 19.65 18.70 20.85Note 1: Air 10 weight on the 4th reading did not stablize so the beaker was placed into the dessicator again and additional readingstaken on 4/17/07 at 8:55 46% 110.4902 g, againon 4/17/17 at 15:25 at 40% 110.4925 g and on 4/18/07 at 10:50 110.4923 g. The last two readings used above for calculations.Note 2: Air 5 weight on the 4th reading did not stablize so the beaker was placed into the dessicator again and additional readings taken on 4/17/07 at 8:55 46% 101.4555g and on4/17/07 at 15:25 40% 101.4557 g. The last two readings used above for the calculations.OK to subtract acetone blankStart Here

## APPENDIX D BOILER/PRECIPITATOR OPERATIONAL DATA

## APPENDIX E FUEL ANALYSIS

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 Report For: 

## Laboratory ID: AA87628

Date and Time Collected: Sampled By: 

### Sample Information
ASG/BB W&F Description 

### Location Code: 5/8/2007 Report Date:

Big Bend 3 Compliance 

### TE_BB_3_COMP_COAL

Project Account Code: 4/10/2007 Date of Sample Receipt: Sample Collection Method: 

### Laboratory Results 4/10/2007 12:00:00 AM

Result PARAMETER Qualifier Code Test

Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower

Limit
60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 3.97 4/16/2007 12:10:00 PM

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 8.65 4/17/2007 2:31:00 PM
Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 9.62 4/17/2007 2:31:00 PM

BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 11885 4/24/2007 12:04:00 PM
BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 13219 4/24/2007 12:04:00 PM

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14626 4/24/2007 12:04:00 PM
Calculated Heat Input, mmBtu/hr mmBtu/hr KARAM 3735 5/8/2007 3:35:00 PM

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 EPA Method 5B/17 KARAM 6.75 5/8/2007 3:35:00 PM

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 EPA Method 5B/17 KARAM 7.35 5/8/2007 3:35:00 PM

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 EPA Method 5B/17 KARAM 18.10 5/8/2007 3:35:00 PM

Particulate Wt., Acetone Beaker, Run 4 mg 0.0001 EPA Method 5B/17 KARAM 5.95 5/8/2007 3:35:00 PM

Particulate Wt., Acetone Beaker, Run 5 mg 0.0001 EPA Method 5B/17 KARAM 3.4 5/8/2007 3:35:00 PM

Particulate Wt., Acetone Beaker, Run 6 mg 0.0001 EPA Method 5B/17 KARAM 7.5 5/8/2007 3:35:00 PM

Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 EPA Method 5B/17 KARAM 14.05 5/8/2007 3:35:00 PM

Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 EPA Method 5B/17 KARAM 10.05 5/8/2007 3:35:00 PM

Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 EPA Method 5B/17 KARAM 11.85 5/8/2007 3:35:00 PM

Particulate Wt., Filter/Thimble, Run 4 mg 0.0001 EPA Method 5B/17 KARAM 13.70 5/8/2007 3:35:00 PM

Particulate Wt., Filter/Thimble, Run 5 mg 0.0001 EPA Method 5B/17 KARAM 15.30 5/8/2007 3:35:00 PM

Particulate Wt., Filter/Thimble, Run 6 mg 0.0001 EPA Method 5B/17 KARAM 13.35 5/8/2007 3:35:00 PM
Particulate Wt., Total Sample, Run 1 mg 0.0001 EPA Method 5B/17 KARAM 20.80 5/8/2007 3:35:00 PM
Particulate Wt., Total Sample, Run 2 mg 0.0001 EPA Method 5B/17 KARAM 17.40 5/8/2007 3:35:00 PM
Particulate Wt., Total Sample, Run 3 mg 0.0001 EPA Method 5B/17 KARAM 29.95 5/8/2007 3:35:00 PM
Particulate Wt., Total Sample, Run 4 mg 0.0001 EPA Method 5B/17 KARAM 19.65 5/8/2007 3:35:00 PM
Particulate Wt., Total Sample, Run 5 mg 0.0001 EPA Method 5B/17 KARAM 18.70 5/8/2007 3:35:00 PM
Particulate Wt., Total Sample, Run 6 mg 0.0001 EPA Method 5B/17 KARAM 20.85 5/8/2007 3:35:00 PM

Report Number: Page 1 of 2 "General Report"

AA87628-050807-16 All of the results presented in this report pertain to results for sample AA87628

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test

Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower

Limit PM non-sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.02 5/8/2007 3:35:00 PM
PM sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.02 5/8/2007 3:35:00 PM

Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated KAPXJ 4.98 4/24/2007 12:04:00 PM

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KARAM 319 5/8/2007 3:35:00 PM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 3.12 4/17/2007 2:28:00 PM
Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.47 4/17/2007 2:28:00 PM

Total Moisture % 0.1 ASTM D-3173 KAPXJ 10.09 4/17/2007 2:28:00 PM



### Comments

Robert Dorey, Manager, Laboratory Services All results calculated on a wet to wet basis, unless otherwise indicated. Should there be any questions regarding this report, please contact:

(813) 630-7878

Report Number: Page 2 of 2 "General Report"

AA87628-050807-16 All of the results presented in this report pertain to results for sample AA87628

## APPENDIX F FIELD DATA SHEETS

## APPENDIX G SAMPLING EQUIPMENT CALIBRATIONS

### Environmental Service s A ir Services Grou p



## SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS
CONSOLE (MB 07) USEPA RM 5 INITIA L 04/03/2007 (ORIFICE) 0.983 POST TEST 04/09/2007 0.978
NOZZLE (SN 19) INITIA L 04/03/2007 CALIPER 0.281 POST TEST 04/09/2007 MEASUREMENTS 0.282

PYROMETER (PY 09) 04/02/2007 ASTM THERMOMETER + 2 o 

### F
PITOT TUBE (PT 05) 04/04/2007 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 06) 04/02/2007 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Blue Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30.16 "Hg Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.23 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.60 15 316.900 323.813 6.913 78 77 77 76 1.10 15 304.500 313.726 9.226 78 78 78 77 1.90 15 292.050 303.965 11.915 84 80 83 78 3.50 15 271.800 288.080 16.280 86 80 88 80

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3455 22.0 72 72 72.0 55 0.4592 20.5 72 72 72.0 63 0.5877 19.0 72 72 72.0 73 0.8022 16.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.859 6.777 6.776 0.988 0.005 1.639 -0.078 9.152 9.007 9.006 0.984 0.001 1.699 -0.019 11.766 11.527 11.527 0.980 -0.003 1.780 0.062 16.072 15.734 15.734 0.979 -0.004 1.752 0.035 Averages: 0.983 1.717

Review/Approval:

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2.



### 10-Apr-07 Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures 04/03/2007

SEG

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

### Environmental Services Air Services Group

Manufacturer: THERMO Calibration Date: Model Number:MST Barometric Pressure: 30.1 "Hg Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.20 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: BLUE

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF

1.1 10 604.100 610.312 6.212 84 77 83 76 1.1 10 610.312 616.532 6.220 83 76 84 77 1.1 10 616.532 622.756 6.224 83 77 84 77

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4592 22.0 72 72 72.0 55 0.4592 22.0 72 72 72.0 55 0.4592 22.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.124 5.993 6.004 0.978 0.001 1.695 0.000 6.132 5.993 6.004 0.977 0.000 1.695 0.000 6.133 5.993 6.004 0.977 -0.001 1.694 -0.001 Averages: 0.978 1.695 Prior Y: 0.983 % Difference: 0.55%

Review/Approval: Date: BB UNIT 3 IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

SEG 04/09/2007 

### POST - TEST CALIBRATION CHECK

12-Apr-07 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Service s A ir Services Grou p

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET Calibration Date: 04/03/2007 Responsible Party: SEG

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average
I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.289 0.295 0.294 0.002 0.115 ^SN04 0.321 0.322 0.322 0.000 0.127 ^SN05 0.377 0.383 0.380 0.002 0.150 ^SN06 0.496 0.497 0.498 0.001 0.196 ^SN09 0.691 0.697 0.693 0.002 0.273 ^SN10 0.752 0.754 0.755 0.001 0.297 ^SN12 0.985 0.986 0.986 0.000 0.388 ^SN15 0.418 0.419 0.419 0.000 0.165 ^SN16 0.500 0.501 0.502 0.001 0.197 ^SN19 0.711 0.716 0.715 0.002 0.281 ^SN22 0.931 0.932 0.931 0.000 0.367 ^SN30 0.796 0.795 0.794 0.001 0.313 ^SN36 0.474 0.477 0.476 0.001 0.187 ^SN37 0.533 0.530 0.531 0.001 0.209 ^SN38 0.635 0.635 0.634 0.000 0.250 ^SN46 0.483 0.484 0.483 0.000 0.190 ^SN47 0.516 0.517 0.516 0.000 0.203 ^SN48 0.636 0.635 0.634 0.001 0.250 ^SN50 0.789 0.787 0.788 0.001 0.310 ^SN58 0.610 0.616 0.610 0.002 0.241 ^SN68 0.624 0.626 0.629 0.002 0.247 ^SN69 0.954 0.952 0.955 0.001 0.375 ^SN70 1.561 1.561 1.562 0.000 0.615 ^SN71 1.555 1.559 1.559 0.002 0.613 ^SN72 0.957 0.958 0.955 0.001 0.377 ^SN73 1.282 1.285 1.285 0.001 0.506 ^SN74 1.238 1.239 1.237 0.001 0.487 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by: 10-Apr-07

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 04/09/2007 

### Calibration Personnel: SEG 

### Test Designation: BB unit 3



### Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN 19 0.715 0.717 0.717 0.001 0.282

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN 19 was 0.281

Difference (Pre-test/Post-test) is: -0.001

QA/QC Review by: 10-Apr-07

### Environmental Services A ir Services Group Pyrometer Calibration Blue Team Pyrometer Under Tes t Pyrometer Number: ^PY09 Labworks Sample # n/a Calibration Date: 04/02/2007

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 01/03/2007 Calibration Personnel (Typed and Signature): J.A.Varino

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 398 2 2 

### 212 211 1 3 

### 32 32 0

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: 

### 10-Apr-07Environmental Services Air Services Group

_ _

s PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT05 Calibration Dat e 04/04/2007 Operating Quarter/Year: 07-Apr Red Team Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.6 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 1.1 degrees Pass α < 10 degrees β 1 0.3 degrees Pass ( α 1 measured across top impact openings) β 2 1 degrees Pass ( α 2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α
, Ζ
, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.1 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.292 cm W < 0.08 cm (Asin ο )
Ζ 0.004 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 1.3 degrees ψ angle between tips W 0.052 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by: SEG/GB

Quality Assurance Review / Approval:

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR06 Calibration Date: 04/02/2007 Calibration Personnel: JA V Labworks #: n/a Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 10:55 30.25 30.19 0.06 11:55 30.25 30.17 0.08 12:55 30.23 30.16 0.07

Avera g e Difference: 0.07

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: Date: 10-Apr-07

## APPENDIX H CHAIN OF CUSTODY

## APPENDIX I TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL SERVICES AIR SERVICES GROUP – TEST TEAM Jorge Varino Environmental Technician – Team Lead Gary Barber Associate Technician Scott Given Associate Technician

PROCESS DATA Curtis Seebaran Engin eer – Big Bend Station

FUEL ANALYSIS Patrice Jackson Envi ronmental Technician

PARTICULATE LABORATORY Gail Harrison Senior Environmental Technician

ANCILLARY DATA COLL ECTION AND ANALYSIS R.A. McDarby Senior Environmental Technician

PROJECT QUALITY OBJECTIVES & REPORTING R.A. McDarby Senior Environmental Technician

TEST COORDINATION Curtis Seebaran Engin eer – Big Bend Station David A. Smith Coordinator –Air Services Group