Ony x Environmenta l Service s 

Sauget , Illmoi s « 

Evaluation of Metals, and 

PCDD/PCDF Emissions for 

Incinerators 2 and 4 

ENSR Corporation 

January 2004 

Document Number 10002-008-100 
E N H 

CONTENT S 

1.0 INTRODUCTION 1-1 

1.1 Program Summary 1-1 

1.2 Field Program Schedule 1-1 

2.0 SUMMARY OF RESULTS 2-1 

2.1 Introduction 2-1 

2.2 Stack Emission Results for Unit 4, Condition 1 2-1 

2.3 Stack Emission Results for Unit 4, Condition 2 2-1 

2.4 Stack Emission Results for Unit 2 2-2 

3.0 SAMPLING AND ANALYTICAL PROCEDURES 3-1 

3.1 Sampling Procedures 3-1 

3.1.1 Velocity, Moisture and Fixed Gas Determinations 3-1 

3.1.2 PCDD/PCDF Sampling 3-1 

3.1.3 Metals Sampling .3-1 

3.2 Analytical Procedures 3-2 

3.2.1 PCDD/PCDF Analyses ... 3-2 

3.2.2 Metals Analyses 3-2 

4.0 QUALITY ASSURANC E 4-1 

4.1 Introduction 4-1 

4.2 Stack Sampling QA/QC 4-1 

4.3 Chain-of-Custody 4-2 

4.4 Analytical QA/QC 4-2 

4.4.1 Analysis for Metals 4-2 

4.4.2 Analysis for PCDDs/PCDFs 4-3 

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CONTENTS - CONTINUED 

APPENDICES 

A - Field Data Sheets 

B - Process Feed and Operating Conditions 

C - Field Equipment Calibration Forms 

D - Analytical Data Reports 

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LIST O F TABLE S 

Table 2-1 Summary of PCDD/PCDF Emissions for Unit 4, Condition 1, TEQ Basis 2-3 

Table 2-2 Summary of Metals Emissions for Unit 4, Condition 1 -Target Metals 2-4 

Table 2-3 Summary of PCDD/PCDF Emissions for Unit 4, Condition 2, TEQ Basis 2-6 

Table 2-4 Summary of Metals Emissions for Unit 4, Condition 2 -Target Metals 2-7 

Table 2-5 Summary of PCDD/PCDF Emissions for Unit 2, TEQ Basis 2-9 

Table 2-6 Summary of Metals Emissions for Unit 2 -Target Metals 2-10 

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mrERNAT/OAIAL 

1.0 INTRODUCTION 

1.1 Program Summary 

ENS R International was retained by Onyx Environmental Services, Sauget, Illinois to conduct 

stack gas emission sampling during the week of September 15, 2003, on two incinerators at the 

facility. The Unit 4 test program was intended to evaluate incinerator performance while varying 

the mercury and powdered activated carbon feedrates. Therefore, Unit 4 was tested under two 

separate operating conditions, a low-mercury/low-carbon feedrate condition and a highmercury/high-carbon feedrate condition. For the first Unit 4 test condition (Mode 1), mercury was 

fed at 0.055 Ibs/hr and 6 Ibs/hr for activated carbon. For the second Unit 4 test condition, mercury 

was fed at 0.186 Ibs/hr and 20 Ibs/hr for activated carbon. 

Unit 2 and Unit 4 were both tested for dioxins and furans in accordance with EPA Method 0023, 

and six (6) metals1 in accordance with EPA Method 29. Stack flows were determined by pitot 

tube/water manometer as part of the actual sampling process. Stack moisture was determined by 

measuring the volume gained in the sampling train during sampling. Oxygen and carbon dioxide 

were determined by collecting a Tediar bag sample followed by ORSAT analysis. 

Method 0023A samples were labeled, packaged and shipped following accepted protocols to Alta 

Analytical, El Dorado Hills, C A for the dioxin and furan analysis. Method 29 samples were 

labeled, packaged and shipped following accepted protocols to Severn & Trent Laboratories of 

Sacramento, CA. In addition to program samples, ENSR prepared two field blanks for analysis, 

one for each sample train. 

1.2 Field Program Schedule 

The test was completed over a five-day time frame as follows: 

September 15 - Travel to the site and set up on stack of Unit 4; 

September 16 - Completed Run 1 & 2 on Unit 4 Condition 1 ; 

September 17 - Completed Run 3 on Unit 4 Condition 1, and Runs 2 & 3, on Unit 4, Condition 2; 

September 16 - Completed Run 3 on Unit 4 Condition 2, and Run 1 onTJnit 2; 

September 19 - Completed Run 2 & 3 on Unit 2, prepared samples for shipment, departed site. 

1

 These metals included: arsenic, beryllium, cadmium, chromium, lead, and mercury. 

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2.0 SUMMAR Y O F RESULT S 

2.1 Introduction 

This section summarizes the test program results. The data presented here includes only, stack 

emissions data. Waste feed and process data related to this program are included in Appendix B of 

this report. 

2.2 Stack Emission Results for Unit 4, Condition 1 

A summary of the PCDD/PCDF and Metals emission results for Units 4, Condition 1 are included in 

Tables 2-1 and 2-2, respectively. These results indicate that: 

The PCDD/PCDF emissions for Unit 4, Condition 1 (average emissions for the three test run set 

were 0.05 ng/m3) are below the HWC MACT emission standard of 0.2 ng/m3 (corrected to 7% 02 ); 

The LVM and SVM metals emissions for Unit 4, Condition 1 (average emissions for the three test 

run set were <31 pg/m3 for LVMs and 199 pg/m3 for SVMs) were lower than the new HWC MACT 

emission standards of 97 pg/m3 and 240 pg/m3 (corrected to 7% 02 ) for LVMs and SVMs 

respectively; 

« The mercury emissions for Unit 4, Condition 1 (average for the three test run set were 267 pg/m3) 

were higher than the new HWC MACT emission standard of 130 pg/m3. 

2.3 Stack Emission Results for Unit 4, Condition 2 

A summary of the PCDD/PCDF and Metals emission results for Units 4, Condition 2 are included in 

Tables 2-3 and 2-4, respectively. These results indicate that: 

• The PCDD/PCDF emissions for Unit 4, Condition 2 (average emissions for the three test run set 

were 0.04 ng/m3) are below the HWC MACT emission standard of 0.2 ng/m3 (corrected to 7% 02 ); 

. The LVM and SVM metals emissions for Unit 4, Condition 2 (average emissions for the three test 

run set were <36 pg/m3 for LVMs and 220 pg/m3 for SVMs) were lower than the new HWC MACT 

emission standards of 97 pg/m3 and 240 pg/m3 (corrected to 7% 02 ) for LVMs and SVMs 

respectively; 

• The mercury emissions for Unit 4, Condition 2 (average for the three test run set were 553 pg/m3) 

were higher than the new HWC MACT emission standard of 130 pg/m3. 

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2.4 Stack Emission Results for Unit 2 

A summary ofthe PCDD/PCDF and Metals emission results for Units 2 are included in Tables 2-5 and 

2-6, respectively. These results indicate that: 

• The PCDD/PCDF emissions for Unit 2 (average emissions for the three test run set were 0.22 

ng/m3) are higher than the HWC MACT emission standard of 0.20 ng/m3 (corrected to 7% 02 ); 

• The LVM and SVM metals emissions for Unit 2 (average emissions for the three test run set were 

<2.7 pg/m3 for LVMs and 3.7 pg/m3 for SVMs) were lower than the new HWC MACT emission 

standards of 97 pg/m3 and 240 pg/m3 (corrected to 7% 02 ) for LVMs and SVMs respectively; 

• The mercury emissions for Unit 2 (average for the three test run set were 58 pg/m3) were lower 

than the new HWC MACT emission standard of 130 pg/m3. 

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Table 2-1 Summary of PCDD/PCDF Emissions for Unit 4, Condition 1, TEQ Basis 

Run No. C1-R1 C1-R2 C1-R3 

Date 16-Sep-03 16-Sep-03 17-Sep-03 

Start Time 1015 1645 800 

Stop Time 1353 1953 1109 

Units 

Sample Volume dscf 126.784 117.634 114.383 

Sample Volume m

3 3.59 3.33 3.24 

Moisture Content % v/v 37.9 39.8 40.0 

02 Cone. % v/v (dry) 13.00 13.00 12.70 

C02 Cone. % v/v (dry) 5.00 5.20 5.50 

Isokinetics % 102 102 99 

Stack Flowrate dscfm 18,879 18,796 18,797 

PCDD / PCDF Parameters TEF (a) pg/sample ng/m TEQ3 pg/sample ng/mTEQ pg/'iampl ng/mTEQ 

2,3,7,8-TCDD 1.00 8 2.3E-03 13 3.9E-03 12 3.7E-03 

1,2,3,7,8-PeCDD 0.50 42 5.8E-03 35 5.3E-03 27 4.2E-03 

1,2,3,4,7,8-HxCDD 0.10 45 1.2E-03 44 1.3E-03 31 9.6E-04 

1,2,3,6,7,8-HxCDD 0.10 59 1.7E-03 66 2.0E-03 45 1.4E-03 

1,2,3,7,8,9-HxCDD 0.10 49 1.4E-03 35 1.OE-03 28 8.7E-04 

1,2,3,4,6,7,8-HpCDD 0.01 264 7.3E-04 249 7.5E-04 157 4.8E-04 

OCDD 0.00 225 6.3E-05 189 5.7E-05 150 4.6E-05 

2,3,7,8-TCDF 0.10 30 8.2E-04 28 8.4E-04 24 7.3E-04 

1,2,3,7,8-PeCDF 0.05 50 7.0E-04 30 4.5E-04 27 4.2E-04 

2,3,4,7,8-PeCDF 0.50 61 8.6E-03 46 6.9E-03 39 6.1 E-03 

1,2,3,4,7,8-HxCDF 0.10 101 2.8E-03 50 1.5E-03 31 9.5E-04 

1,2,3,6,7,8-HxCDF 0.10 98 2.7E-03 42 1.3E-03 29 9.0E-04 

2,3,4,6,7,8-HxCDF 0.10 102 2.8E-03 47 1.4E-03 32 9.8E-04 

1,2,3,7,8,9-HxCDF 0.10 25 7.0E-04 18 5.4E-04 16 4.9E-04 

1,2,3,4,6,7,8-HpCDF 0.01 463 1.3E-03 139 4.2E-04 104 3.2E-04 

1,2,3,4,7,8,9-HpCDF 0.01 100 2.8E-04 26 7.9E-05 16 4.9E-05 

OCDF 0.00 320 8.9E-05 59 1.8E-05 69 2.1 E-05 

TOTAL TCDD 0.00 1,366 0.0E+O0 1,451 O.OE+00 910 O.OE+00 

TOTAL PeCDD 0.00 1,417 0.0E+00 1,510 O.OE+00 1,019 O.OE+00 

TOTAL HxCDD 0.00 1,542 0.0E+00 1,648 O.OE+00 1,000 O.OE+00 

TOTAL HpCDD 0.00 557 O.OE+00 512 0.0E+00 336 O.OE+00 

TOTALTCDF 0.00 3,526 0.0E+00 4,457 O.OE+00 3,149 0.0E+00 

TOTAL PeCDF 0.00 846 O.OE+00 801 O.OE+00 519 0.0E+00 

TOTAL HxCDF 0.00 895 0.0E+00 394 O.OE+00 238 0.0E+00 

TOTAL HpCDF 0.00 842 0.0E+00 180 0.0E+00 147 O.0E+00 

TOTAL TEQs (ng/m3) 0.03 0.03 0.02 

TOTAL TEQs (ng/m3 @ 7 % 02) 0.06 0.05 0.04 

TOTAL TEQs (g/s) = 3.0E-10 2.5E-10 2.0E-10 

(a) U.S.EPA (1989) Toxic Equivalency Factor 

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Table 2-2 Summary of Metals Emissions for Unit 4, Condition 1 -Target Metals 

L o w Volatile Metal s Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

As 35.7 21.3 15.2 24.1 

Be <0.19 <0.19 <0.19 <0.19 

Cr 6.07 8.92 5.26 6.75 

Total LVM <42.0 <30.4 <20.7 <31.0 

LVM Regulatory Standard = 97 micrograms/m 3 

Semi-Volatile Metal Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

Pb 135.8 253.7 202.8 197.4 

Cd 2.54 1.15 0.32 1.33 

Total SVM 138.3 254.8 203.1 198.7 

SVM Regulatory Standard = 240 micrograms/m3 

Mercur y Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

Hg 212.6 358.5 228.5 266.6 

Mercury Regulatory Standard = 130 micrograms/m3 

— ., , , , 

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Table 2-2, Continued Summary of Metals Emissions for Unit 4 Condition 1 

Run No. ' U4-C1-R1 U4-C1-R2 U4-C1-R3 

Date 16-Sep-03 16-Sep-03 17-Sep-03 

Start Time Units 1015 1645 800 

Stop Time 1309 1923 1039 AVGS 

SamDlinq Parameters -

Barometric Pressure in. Hg 29.70 29.70 29.70 29.70 

Volume Metered dcf 108.713 105.734 99.986 104.811 

Sample Volume dscf 100.851 99.059 96.247 98.719 

Moisture % v/v 38.8 39.1 39.4 39.1 

02 at Stack %dry 13.00 13.00 12.70 12.90 

Avg. Stack Temp. °F 409 407 401 405 

Stack Flowrate dscfm 18,757 18,563 18,813 18,711 

Isokinetics % 104 103 99 102 

Arsenic (As) - LVM 

Quantity Collected pg 58.30 34.10 24.60 39.00 

Stack Cone. @ 7% 02 pg/m3 35.73 21.27 15.22 24.07 

Stack Emission Rate Ib/hr 1.43E-03 8.45E-04 6.36E-04 9.72E-04 

Beryllium (Be) - LVM 

Quantity Collected pg < 0.31 < 0.31 < 0.31 < 0.31 

Stack Cone. @ 7% 02 pg/m3 < 0.19 < 0.19 < 0.19 < 0.19 

Stack Emission Rate Ib/hr 7.63E-06 < 7.68E-06 < 8.01 E-06 < 7.78E-06 

Total Chromium ier) •- LVM 

Quantity Collected pg 9.90 14.30 8.50 10.90 

Stack Cone. @ 7% 0 2 pg/m3 6.07 8.92 5.26 6.75 

Stack Emission Rate ib/hr 2.44E-04 3.54E-04 2.20E-04 2.73E-04 

Cadmium (Cd) - SVM 

Quantity Collected pg 4.14 1.84 0.51 2.16 

Stack Cone. @ 7% 02 pg/m3 2.54 1.15 0.32 1.33 

Stack Emission Rate Ib/hr 1.02E-04 4.56E-05 1.32E-05 5.35E-05 

Lead (Pb)- SVM 

Quantity Collected pg 221.61 406.61 327.61 318.61 

Stack Cone. @ 7% 02 pg/m3 135.80 253.67 202.75 197.41 

Stack Emission Rate Ib/hr 5.45E-03 1.01 E-02 8.47E-03 8.00E-03 

Mercury (Hq) - VM 

Quantity Collected pg 347.0 574.6 369.3 430.3 — 

Stack Cone. @ 7% 02 pg/m3 212.6 358.5 228.5 266.6 

Stack Emission Rate Ib/hr 8.54E-03 1.42E-02 9.55E-03 1.08E-02 

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Table 2-3 Summary of PCDD/PCDF Emissions for Unit 4, Condition 2, TEQ Basis 

Run No. C2-R1 C2-R2 C2-R3 

Date 17-Sep-03 17-Sep-03 18-Sep-03 

Start Time 1145 1540 810 

Stop Time 1504 1849 1118 

Units 

Sample Volume dscf 111.251 111.673 112.929 

Sample Volume m

3 3.15 3.16 3.20 

Moisture Content % v/v 40.0 40.7 39.2 

O2 Cone. % v/v (dry) 12.50 12.10 13.00 

C02 Cone. % v/v (dry) 5.20 5.50 4.20 

Isokinetics % 99 101 99 

Stack Flowrate dscfm 18,394 18,088 18,616 

PCDD / PCDF Parameters TEF (a) pg/sample ng/nrTEQ pg/sample ng/mTEQ pg/sample ng/nfTEQ 

2,3,7,8-TCDD 1.00 11 3.4E-03 15 4.6E-03 14 4.2E-03 

1,2,3,7,8-PeCDD 0.50 27 4.3E-03 38 6.0E-03 45 7.1E-03 

1,2,3,4,7,8-HxCDD 0.10 32 1.OE-03 30 9.6E-04 25 7.7E-04 

1,2,3,6,7,8-HxCDD 0.10 42 1.3E-03 27 8.4E-04 40 1.2E-03 

1,2,3,7,8,9-HxCDD 0.10 32 1.OE-03 34 1.1 E-03 27 8.4E-04 

1,2,3,4,6,7,8-HpCDD 0.01 181 5.8E-04 237 7.5E-04 176 5.5E-04 

OCDD 0.00 134 4.3E-05 156 4.9E-05 41 1.3E-05 

2,3,7,8-TCDF 0.10 19 6.1 E-04 27 8.5E-04 20 6.4E-04 

1,2,3,7,8-PeCDF 0.05 24 3.8E-04 36 5.7E-04 30 4.7E-04 

2,3,4,7,8-PeCDF 0.50 40 6.3E-03 46 7.3E-03 40 6.2E-03 

1,2,3,4,7,8-HxCDF 0.10 24 7.7E-04 33 1.1 E-03 46 1.4E-03 

1,2,3,6,7,8-HxCDF 0.10 28 9.0E-04 37 1.2E-03 36 1.1E-03 

2,3,4,6,7,8-HxCDF 0.10 32 1.OE-03 41 1.3E-03 49 1.5E-03 

1,2,3,7,8,9-HxCDF 0.10 7 2.1 E-04 11 3.4E-04 9 3.0E-04 

1,2,3,4,6,7,8-HpCDF 0.01 35 1.1 E-04 118 3.7E-04 43 1.3E-04 

1,2,3,4,7,8,9-HpCDF 0.01 14 4.6E-05 17 5.3E-05 16 4.9E-05 

OCDF 0.00 53 1.7E-05 60 1.9E-05 90 2.8E-05 

TOTALTCDD 0.00 1,128 0.0E+00 1,489 0.0E+00 978 0.0E+00 

TOTAL PeCDD 0.00 1,198 0.0E+00 1,598 O.OE+00 981 0.0E+00 

TOTAL HxCDD 0.00 1,257 0.0E+00 1,565 O.0E+00 1,085 0.0E+00 

TOTAL HpCDD 0.00 381 O.OE+00 524 0.0E+00 363 0.0E+00 

TOTALTCDF 0.00 3,798 0.0E+00 4,899 0.0E+00 3,510 0.0E+0O 

TOTAL PeCDF 0.00 665 0.0E+00 866 0.0E+00 674 O.OE+00 

TOTAL HxCDF 0.00 264 0.0E+00 353 O.OE+00 389 O.OE+00 

TOTAL HpCDF 0.00 74 0.0E+00 147 0.0E+00 178 O.OE+00 

TOTAL TEQs (ng/m') = 0.02 0.03 0.03 

TOTAL TEQs (ng/m3 @ 7 % 02) = 0.04 0.04 0.05 

TOTAL TEQs (g/s) = 1.9E-10 2.3E-10 2.3E-10 | 

(a) U.S.EPA (1989) Toxic Equivalency Factor 

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Table 2-4 Summary of Metals Emissions for Unit 4, Condition 2 -Target Metals 

L o w Volatile Metals Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

As 12.4 11.1 63.9 29.1 

Be <0.24 <0.23 <0.25 <0.24 

Cr 6.06 6.25 7.53 6.62 

Total LVM <18.7 <17.5 <71.7 <36.0 

LVM Regulatory Standard = 97 micrograms/m 3 

Semi-Volatile Metal Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

Pb 210.1 249.9 198.5 219.5 

Cd 0.31 0.27 0.51 0.36 

Total SVM 210.4 250.1 199.0 219.8 

SVM Regulatory Standard = 240 micrograms/m3 

Mercur y Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

Hg 468.5 902.1 288.7 553.1 

Mercury Regulatory Standard = 130 micrograms/m3 

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Table 2-4, Continued Summary of Metals Emissions for Unit 4 Condition 2-

Run No. Run 1 Run 2 Run 3 

Date 17-Sep-03 17-Sep-03 18-Sep-03 

Start Time Units 1145 1540 0810 

Stop Time 1434 1819 1048 AVGS 

Samolina Parameters -

Barometric Pressure in. Hg 29.60 29.60 29.55 29.58 

Volume Metered dcf 81.452 82.629 81.278 81.786 

Sample Volume dscf 75.764 76.390 77.096 76.417 

Moisture % v/v 39.8 40.7 38.9 39.8 

02 at Stack %dry 12.50 12.10 13.00 12.53 

Avg. Stack Temp. °F 404 409 405 406 

Stack Flowrate dscfm 18,410 17,867 18,708 18,328 

Isokinetics % 99 103 100 101 

Arsenic (As) - LVM 

Quantity Collected pg 16.10 15.20 79.70 37.00 

Stack Cone. @ 7% 0 2 pg/m3 12.36 11.05 63.89 29.10 

Stack Emission Rate Ib/hr 5.17E-04 4.70E-04 2.56E-03 1.18E-03 

Beryllium (Be) - LVM 

Quantity Collected pg < 0.31 < 0.31 < 0.31 < 0.31 

Stack Cone. @ 7% 02 pg/m3 < 0.24 < 0.23 < 0.25 < 0.24 

Stack Emission Rate lb/hr 9.96E-06 < 9.59E-06 < 9.95E-06 < 9.84E-06 

Total Chromium (Cr) — LVM 

Quantity Collected P9 7.90 8.60 9.40 8.63 

Stack Cone. @ 7% 02 pg/m3 6.06 6.25 7.53 6.62 

Stack Emission Rate Ib/hr 2.54E-04 2.66E-04 3.02E-04 2.74E-04 

Cadmium (Cd) - SVM 

Quantity Collected P9 0.40 0.37 0.63 0.47 

Stack Cone. @ 7% 02 pg/m3 0.31 0.27 0.51 0.36 

Stack Emission Rate Ib/hr 1.29E-05 1.14E-05 2.02E-05 1.48E-05 

Lead (Pb) - SVM 

Quantity Collected P9 273.61 343.61 247.61 288.28 

Stack Cone. @ 7% 02 pg/m3 210.05 249.87 198.48 219.47 

Stack Emission Rate Ib/hr 8.79E-03 1.06E-02 7.95E-03 9.12E-03 

Mercury (Hq) - VM 

Quantity Collected pg 610.3 1240.5 3S0.1 737.0 

Stack Cone. @ 7% 02 pg/m3 468.5 902.1 288.7 553.1 

Stack Emission Rate Ib/hr 1.96E-02 3.84E-02 1.16E-02 2.32E-02 

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Table 2-5 Summary of PCDD/PCDF Emissions for Unit 2, TEQ Basis 

Run No. R1 R2 R3 

Date 18-Sep-03 19-Sep-03 19-Sep-03 

Start Time 1445 830 1250 

Stop Time 1849 1142 1601 

Units 

Sample Volume dscf 109.373 120.219 112.854 

Sample Volume m

3 3.10 3.40 3.20 

Moisture Content % v/v 45.6 42.8 43.9 

02 Cone. % v/v (dry) 12.10 12.10 11.50 

C02 Cone. % v/v (dry) 6.70 6.70 6.70 

Isokinetics % 99 96 97 

Stack Flowrate dscfm 7,628 8,685 8,057 

PCDD / PCDF Parameters TEF (a) pg/sample ng/m TEQ pg/sample ng/m TEQ3 pg/sample ng/m3

 TEQ 

2,3,7,8-TCDD 1.00 20 6.6E-03 13 3.7E-03 15 4.7E-03 

1,2,3,7,8-PeCDD 0.50 107 1.7E-02 45 6.6E-03 43 6.7E-03 

1,2,3,4,7,8-HxCDD 0.10 106 3.4E-03 53 1.6E-03 40 1.3E-03 

1,2,3,6,7,8-HxCDD 0.10 198 6.4E-03 88 2.6E-03 84 2.6E-03 

1,2,3,7,8,9-HxCDD 0.10 126 4.1 E-03 67 2.0E-03 11 3.5E-04 

1,2,3,4,6,7,8-HpCDD 0.01 656 2.1 E-03 383 1.1 E-03 352 1.1E-03 

OCDD 0.00 468 1.5E-04 314 9.2E-05 309 9.7E-05 

2,3,7,8-TCDF 0.10 260 8.4E-03 128 3.8E-03 94 2.9E-03 

1,2,3,7,8-PeCDF 0.05 407 6.6E-03 159 2.3E-03 129 2.0E-03 

2,3,4,7,8-PeCDF 0.50 794 1.3E-01 369 5.4E-02 266 4.2E-02 

1,2,3,4,7,8-HxCDF 0.10 535 1.7E-02 235 6.9E-03 164 5.1E-03 

1,2,3,6,7,8-HxCDF 0.10 420 1.4E-02 184 5.4E-03 140 4.4E-03 

2,3,4,6,7,8-HxCDF 0.10 733 2.4E-02 281 8.3E-03 199 6.2E-03 

1,2,3,7,8,9-HxCDF 0.10 196 6.3E-03 76 2.2E-03 58 1.8E-03 

1,2,3,4,6,7,8-HpCDF 0.01 811 2.6E-03 451 1.3E-03 353 1.1E-03 

1,2,3,4,7,8,9-HpCDF 0.01 170 5.5E-04 61 1.8E-04 61 1.9E-04 

OCDF 0.00 206 6.7E-05 101 3.0E-05 117 3.7E-05 

TOTALTCDD 0.00 4,563 0.0E+00 1,973 O.OE+00 1,543 0.0E+00 

TOTAL PeCDD 0.00 5,034 0.0E+00 2,024 0.0E+00 1,706 0.0E+00 

TOTALHxCDD 0.00 6,161 0.0E+00 2,578 0.0E+00 2,550 0.0E+00 

TOTAL HpCDD 0.00 1,415 0.0E+00 823 0.0E+00 739 O.OE+00 

TOTALTCDF 0.00 10,504 0.0E+00 5.103 O.OE+00 3,894 0.0E+00 

TOTAL PeCDF 0.00 10,106 0.0E+00 4,025 O.OE+00 2,844 0.0E+00 

TOTAL HxCDF 0.00 7,735 0.0E+00 2,565 O.OE+00 1,833 O.OE+00 

TOTAL HpCDF 0.00 1,849 0.0E+00 634 0.0E+00 626 O.OE+00 

TOTAL TEQs (ng/m5) 0.25 0.10 0.08 

TOTAL TEQs (ng/m3 @ 7 % 02) - = 0.39 0.16 0.12 

TOTAL TEQs (y/s) = 8.9E-10 4.2E-10 3.1E-10 

(a) U.S.EPA (1989) Toxic Equivalency Factor 

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H MIMIC., 

\ INTERNATIONAL 

Table 2-6, Continued Summary of Metals Emissions for Unit 2 

Run No. Run 1 Run 2 Run 3 

Date 18-Sep-03 19-Sep-03 19-Sep-03 

Start Time Units 1445 830 1250 

Stop Time 1810 1112 1531 AVGS 

Samolinq Parameters -

Barometric Pressure in. Hg 29.55 29.60 29.60 29.58 

Volume Metered dcf 85.391 84.763 82.288 84.147 

Sample Volume dscf 78.120 83.405 79.852 80.459 

Moisture % v/v 44.5 42.4 43.4 43.4 

02 at Stack %dry 12.10 12.10 11.50 11.90 

Avg. Stack Temp. °F 382 368 372 374 

Stack Flowrate dscfm 5,381 5,840 5,549 5,590 

Isokinetics % 99 97 98 98 

Arsenic (As) - LVM 

Quantity Collected M9 1.90 2.30 0.96 1.72 

Stack Cone. @ 7% 02 pg/m' 1.35 1.53 0.63 1.17 

Stack Emission Rate Ib/hr 1.73E-05 2.13E-05 8.82E-06 1.58E-05 

Beryllium (Be) - LVM 

Quantity Collected P9 < 0.31 < 0.31 < 0.31 < 0.31 

Stack Cone. @ 7% 02 pg/m3 < 0.22 < 0.21 < 0.20 < 0.21 

Stack Emission Rate Ib/hr 2.82E-06 < 2.87E-06 < 2.85E-06 < 2.85E-06 

Total Chromium (Cr) - LVM 

Quantity Collected pg 1.60 1.90 2.30 1.93 

Stack Cone. @ 7% 02 pg/m3 1.14 1.27 1.50 1.30 

Stack Emission Rate Ib/hr 1.46E-05 1.76E-05 2.11 E-05 1.78E-05 

Cadmium (Cd) - SVM 

Quantity Collected pg 0.31 0.28 0.16 0.25 

Stack Cone. @ 7% 02 pg/m3 0.22 0.19 0.10 0.17 

Stack Emission Rate lb/hr 2.82E-06 2.59E-06 1.47E-06 2.30E-06 

Lead (Pb) - SVM 

Quantity Collected pg 4.01 6.01 5.81 5.28 

Stack Cone. @ 7% 02 pg/m3 2.85 4.00 3.79 3.55 

Stack Emission Rate Ib/hr 3.65E-05 5.57E-05 5.34E-05 4.85E-05 

Mercury (Hq) - VM 

Quantity Collected pg 118.4, 104.0 32.8 85.1 

Stack Cone. @ 7% 02 pg/m3 84.2 69.3 21.4 58.3 

Stack Emission Rate Ib/hr 1.08E-03 9.63E-04 3.01 E-04 7.81 E-04 

g/sec 1.36E-04 1.21 E-04 3.80E-05 9.84E-05 

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datat>903 Onyx Test Program.doc January, 2004 
EHS R 

/HTERAMrrOHAL 

Table 2-6 Summary of Metals Emissions for Unit 2 -Target Metals 

L o w Volatile Metal s Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

As 1.4 1.5 0.63 1.2 

Be <0.22 <0.21 <0.20 <0.21 

Cr 1.14 1.27 1.50 1.30 

Total LVM <2.7 <3.0 <2.3 <2.7 

LVM Regulatory Standard = 97 micrograms/m 3 

Semi-Volatile Metal Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

Pb 2.9 4.0 3.8 3.5 

Cd 0.22 0.19 0.10 0.17 

Total SVM 3.1 4.2 3.9 3.7 

SVM Regulatory Standard = 240 micrograms/m3 

Mercur y Emissions - micrograms/m 3 

Metals Runl Run2 Run3 Average 

Hg 84.2 69.3 21.4 58.3 

Mercury Regulatory Standard = 130 micrograms/m3 

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ENSR . 

MTeRNATIONAL 

3.0 SAMPLIN G AN D ANALYTICA L PROCEDURE S 

3.1 Sampling Procedures 

Several different sampling and monitoring techniques were used to provide the required data to meet 

the goals of this test program. Triplicate runs were conducted on Unit 4 at two conditions established 

by Onyx. Triplicate testing was also conducted on Unit 2 at process conditions established by Onyx. 

The sampling activities described below were conducted during all runs. All field activities were 

documented in accordance with EPA accepted procedures and copies of all field notes and data 

sheets are included in Appendix A of this report. 

3.1.1 Velocity, Moisture and Fixed Gas Determinations 

Gas stream velocity and temperature were determined in conjunction with each manual sampling 

method. A type "S" pitot tube connected to an inclined water manometer was used to determine 

velocity head of the flue gas at each duct traverse point as specified in EPA Reference Method 2. The 

temperature profile of the flue gas at each duct traverse point was obtained by taking readings with a 

thermocouple and pyrometer concurrent with the velocity head measurements. Moisture content was 

determined as specified in EPA Method 4. Velocity and temperature measurement profiles were 

established prior to testing to aid in sample train set-up. Samples for the determination of the fixed gas 

composition (02 and C02 ) were collected using the integrated bag technique detailed in EPA 

Reference Method 3. 

3.1.2 PCDD/PCDF Sampling 

Sampling for dioxins and furans was completed in accordance with EPA Method 0023A (EPA SW846). Samples were collected for separate front half and back half analysis. On Unit #4, each 

sampling run was 3 hours in duration covering 12 sampling points at 15 minutes per point. On Unit #2, 

each sampling run was 3 hours in duration covering 12 sampling points at 15 minutes per point. Setup and recovery schematics for the Method 0023A train are included in Appendix B. 

3.1.3 Metals Sampling 

The EPA Multiple Metals Train (EPA Method 29 as specified in 40 CFR 60 Appendix A) was utilized 

during the testing program for the collection of the following metals: arsenic, beryllium, cadmium, 

chromium, lead, mercury). Each run was 2-hr in duration covering 12 sampling points at 10 minutes 

per point. Set-up and recovery schematics forthe multimetals train are included in Appendix B. 

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3-1 January, 2004 
/NTERNAT/ONAL 

3.2 Analytical Procedures 

3.2.1 PCDD/PCDF Analyses 

Method 0023 samples were analyzed by EPA Method 8290 (high resolution GC/MS). The train 

fractions recovered for analysis of PCDDs/PCDFs include the front half rinses, the particulate filter and 

the XAD resin trap. While separate front half and back analytical results were obtained, the results for 

each sample fraction were combined into a single analytical result for each run. PCDD/PCDF 

analyses were performed by Alta Analytical Laboratory, Inc. in El Dorado Hills, CA. 

3.2.2 Metals Analyses 

Metals analyses for the waste feed samples were completed using two separate procedures. First, 

samples were prepared and analyzed for arsenic, beryllium, cadmium, chromium, and lead as 

specified in EPA Method 6020 (ICP-MS), SW846, 3r d Edition. Mercury was analyzed via method 

7471A. Metals analyses were performed by Severn & Trent Laboratories, Sacramento, CA. 

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3-2 January, 2004 
INTERNA TIONAL 

4.0 QUALIT Y ASSURANC E 

4.1 Introduction 

This section presents the results of all QA/QC measures implemented during the field sampling 

program and all phases of subsequent analysis. Data generated for the program are judged to be 

valid as overall accuracy and precision results are consistent with general objectives. Analytical 

QA/QC data are presented to support all sample results used for determining compliance with 

performance criteria or emission standards. 

4.2 Stack Sampling QA/QC 

The stack sampling program incorporated a variety of measures to ensure that sound data would be 

obtained. All samples were collected at the stack sampling locations as planned and in accordance 

with applicable method procedures. One field blank for each pollutant was also submitted for analysis 

along with program samples. 

Sampling QA/QC measure for this program included calibration of all applicable sampling equipment 

used as described below. Field equipment were calibrated according to EPA procedures specified in 

EPA-600/4-77-027b (August 1977) and 40 CFR 60, Methods 1-5, as well as manufacturer's 

specifications. 

1) Dry Gas Meters and Orifice Meters (EPA Method 5 Type). The dry gas meters for all sampling 

trains were calibrated against a wet test meter that had been calibrated against a spirometer. The 

orifice meters were calibrated against the wet test meter and checked against the dry gas meter to 

which they were attached. Meter boxes are calibrated annually and then verified by use of the 

alternative Method 5 post-test calibration procedure. This procedure is based on the principals of 

the optional pretest orifice meter coefficient check outlined in Section 4.4.1 of Method 5. The 

average Y-value obtained by this method must be within 5% of the initial Y-value. The 

calculations provided with the data sheets in Appendix C show that this criterion was met for each 

isokinetic sampling train used on this program. All annual calibration forms are provided in 

Appendix C. 

2) Sampling Nozzles. Each glass nozzle is calibrated with a micrometer prior to testing and 

identified with a unique identification number. The intemal diameter of each nozzle is measured 

to 0.001 inches along three points of the circumference with a dial vernier caliper and the three 

measurements are then averaged. 

3) Balance. The analytical balance used in the field to determine initial and final silica gel weights is 

calibrated against Class M weights provided by the Mettler Corporation. 

4) Thermocouples. Type K thermocouples in each meter control box, heated sample box, impinger 

umbilical connector and sample probes are calibrated against ASTM mercury-in-glass 

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EN5 R 

INTERNATIONAL. 

thermometers at three points: an ice bath, ambient temperature and a boiling water bath. 

Calibration data are provided in Appendix C. 

5) Pitot Tube. Each S-type stainless steel pitot tube used is designed to meet geometric 

configurations as defined in EPA Method 2. Data sheets are provided in Appendix C. 

4.3 Chain-of-Custody 

Chain-of-custody procedures were followed for all samples as follows: 

• Each isokinetic train was set-up and recovered in a clean area adjacent to the incinerators. 

» Samples were collected, sealed and labeled appropriately. 

• All samples were packed in bubble wrap or other absorbent material and placed in either 

sample coolers or appropriate DOT shipping packages (dangerous goods items). 

• All samples were subsequently shipped via Priority Overnight Fed. Ex service to the 

designated laboratory. 

4.4 Analytical QA/QC 

Data Quality Indicators (DQI's) were utilized throughout the program to assess the validity of analytical 

data. This section provides a review of these indicators and the subsequent impact on the analytical 

data. 

4.4.1 Analysis for Metals 

Evaluation of the validity of metals data resulting from the analysis of the Method 0060 sampling train 

samples was based on the following two sets of DQI's: 

• Recoveries of internal, pre-spike and alternate recovery standards added to the samples prior 

to sampling. Recoveries of these standards are included with other Severn & Trent 

Laboratories data in Appendix D. 

• Results of analyses of field and method blank samples for metals. These results are included 

in Appendix D. 

On the basis of these QC results, no sample analyses were rejected and all the data were determined 

to be valid. Completeness was therefore determined to be 100% for all metals results from all 

samples. 

Data quality indicators (DQIs) were utilized throughout the program to assess the validity of the 

analytical data. This section provides a review of these indicators and the subsequent impact on the 

analytical data. 

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4.4.2 Analysis for PCDDs/PCDFs 

Evaluation of the validity of the PCDD/PCDF data resultant from the analysis of the Method 23 

sampling train samples was based on four sets of DQIs. These were: 

• Recoveries of intemal, pre-spike and alternate recovery standards added to the samples prior to 

sampling. 

• Results of analysis of Laboratory Control Samples (LCS) for the 17 PCDD/PCDF isomers listed in 

EPA Method 23. 

• Results of analyses of field and method blank samples for PCDD/PCDFs. 

These results are included with the Alta Analytical Data Report included in Appendix D. Based on 

these QC results, recoveries of two native analytes (2,3,6,7,8-HxCDF and 1,2,3,7,8,9-HxCDF) were 

outside of Alta's limit in the Ongoing Precision and Recovery (OPR) sample. These limits are 

recommended only, and are not designated by the method. No sample analyses were rejected, and 

all data were determined to be valid. 

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INTERNA TIONAL 

APPENDIX A 

FIELD DATA SHEETS 

C:\Doctments and Sstinos\cdoolit!!e\My DocumenB\Ony>;\0903 testfncAOnyx O903 d3taWppendix Covere.doc January 2004 
Unit 4, Condition 1 

PCDD/PCDF FIELD DATA 

S:\STACKU0B\20D3tonyxRP\repoiWly sheets.**: November 2003 
Metho d 0023 A Samplin g Parameter s 

UNI T 4 - Conditio n 1-R M 0023 A 

Run No. C1-R1 C1-R2 C1-R3 

Date 16-Sep-03 16-Sep-03 17-Sep-03 

Start Time Units 1015 1645 800 

Stop Time 1353 1953 1109 AVG S 

Nozzle Diameter inches 0.291 0.280 0.280 0.284 

Barometric Pressure in. Hg 29.70 29.70 29.60 29.67 

Net Sampling Time min. 180.0 180.0 180.0 180.0 

Volume Metered dcf 136.256 125.632 119.066 126.985 

Avg. DG M Temp. °F 95.8 91.8 75.8 87.8 

Avg Delta H in H 2 0 2.16 1.80 1.63 1.86 

Avg Delta H in. Hg 0.1587 0.1324 0.1201 0.1371 

D G M Calibration Factor — 0.9814 0.9814 0.9814 0.9814 

G as Sample Volume dscf 126.784 117.634 114.383 119.600 

Total Water Collected mL 1639.5 1648.1 1620.6 1636.1 

Volume of Water Vapor scf 77.302 77.708 76.411 77.141 

Moisture (measured) % v/v 37.9 39.8 40.0 39.2 

Moisture (@ saturation) % v/v 100.8 100.9 101.2 101.0 

Dry Mole Fraction, 100-%M ~ 0.6212 0.6022 0.5995 0.6076 

C 0 2 at Stack %dry 5.00 5.20 5.50 5.23 

0 2 at Stack %dry 13.00 13.00 12.70 12.90 

C O + N 2 % dry 82.00 81.80 81.80 81.87 

Dry Molecular Weight Ib/lb-mole 29.32 29.35 29.39 29.35 

Wet Molecular Weight Ib/lb-mole 25.03 24.84 24.83 24.90 

Excess Air at Stack % 150.3 151.2 142.8 148.1 

Stack Diameter inches 48.0 48.0 48.0 48.0 

Stack Area sq. in. 1809.6 1809.6 1809.6 1809.6 

Static Pressure in H 2 0 -0.42 -0.52 -0.52 -0.49 

Stack Pressure in. Hg 29.67 29.66 29.56 29.63 

Avg. Stack Temp. 406.4 408.3 400.7 405.1 

Avg. Sqroot of Delta P — 0.8598 0.8807 0.8821 0.8742 

S D E Average ~ 25.309 25.953 25.879 25.714 

Pitot Coefficient - 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 4,002 4,120 4,116 4,080 

Stack Flowrate wet acfm 50,289 51,779 51,728 51,266 

Stack Flowrate wet scfm 30,390 31,213 31,354 30,986 

Stack Flowrate dscfm 18,879 18,796 18,797 18,824 

Isokinetics % 102 102 99 101 

Meter Box No. ~ 80102 80102 80102 -

Delta H @ in. Hg 2.0590 2.0590 2.0590 

Field QA Yqc — 1.036 1.023 1.014 1.025 

[Deviation] Pre-Y % 5.6% 4.2% 3.4% 4.4% 

S:\STACK\JOB\2003\onyxRP\xldala\Sept 03\[M23 U4 Cl .xlsJTOTALDFS 
UNI

T 4 - Condition 1-RM 0023A 

PT 

RUN 1AVGS

-

- PCDDs/1 >CDFs RU

N 2 AVGS -

- PCDDs/PCDFs RU

N 3 AVGS -

- PCDDs/PCDFs 

PT 

DP SQRT DP 

DGM IN 

DGM 

OUT 

DH STACK 

TEMP 

DP SQRT DP 

DGM IN 

DGM 

OUT 

DH STACK 

TEMP 

DP SQRT DP 

DGM IN 

DGM 

OUT 

DH STACK 

TEMP 

a1 0.65 0.8062 67 

65 2.50 399 0.61 0.7810 

96 

95 1.50 399 0.59 0.7681 

63 

62 1.20 390 

a2 0.73 0.8544 

91 

82 2.70 405 0.77 0.8775 

93 

93 1.80 401 0.73 0.8544 

69 

65 1.50 392 

a3 0.85 0.9220 93 

85 3.10 412 0.85 0.9220 

92 

91 2.00 408 0.85 0.9220 

73 

67 1.80 403 

a4 0.85 0.9220 

96 

88 3.10 413 0.84 0.9165 

93 

91 2.00 408 0.90 0.9487 

76 

70 1.90 407 

a5 0.74 0.8602 94 

93 1.80 412 0.87 0.9327 

93 

90 2.10 407 0.80 0.8944 

78 

72 1.70 406 

a6 0.63 0.7937 106 

94 1.60 406 0.85 0.9220 

92 

89 2.00 407 0.75 0.8660 

80 

74 1.60 404 

a7 0.60 0.7746 103 

97 

1.40 406 0.57 0.7550 

92 

92 1.40 402 0.59 0.7681 

76 

75 1.20 391 

a8 0.70 0.8367 109 

98 

1.80 405 0.71 0.8426 

92 

88 1.60 408 0.75 0.8660 

81 

76 1.60 400 

a9 0.78 0.8832 110 101 2.00 408 0.86 0.9274 

95 

89 1.90 413 0.82 0.9055 

83 

78 1.70 400 

alO 0.85 0.9220 111 103 2.10 410 0.88 0.9381 

94 

89 1.90 415 0.90 0.9487 

85 

80 1.90 404 

a11 0.72 0.8485 103 102 1.80 401 0.82 0.9055 

94 

88 1.80 416 0.88 0.9381 

86 

81 1.80 406 

a12 0.80 0.8944 105 102 2.00 400 0.72 0.8485 

94 

88 1.60 416 0.82 0.9055 

86 

83 1.70 405 

AVG 0.74 0.8598 95.8 2.16 406 0.78 0.8807 91.8 1.80 408 0.78 0.8821 75.8 1.63 401 
P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

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E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

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Barometric Pressure Jl°l.'}C> 

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1 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Client 

Facility Location 

Source 

Dale 

Operator 

Stack Dia. 

Start Time 

Stop Time 

Barometric Pressure j?9v^ C> 

Static Pressure (+/-) — O m T*A . 

Sachet XC 

Probe/Pitot Number X-/ S 

Pltot Coemcleiit 

Filter Box No. 

Meter Box No. 

o.-zy 

LEA K CHECKS In "Hg 

INITIAL VAC. / & In. 

MID VAC. In. 

FINAL VAC. / 6 In. 

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Nozzle Size/No. t?,£gT> 

FILTER DATA 

XAD Thermocouple ID: p'/ J?jy 

KN UMBER* mmm 

IMI INGLK VOl S 

USlfr 

a 

PINAL 

•3-

SILICA GE L Final Purge Rate_ 

VUIPI I. 

I'OIN r 

CLOCK 

TIM E 

VEtocrrv 

11EA& 

I»elllP inwt 

ORIFICE 

MI.IfeR\OI 

l>ill»H in we 

HASMI-TF R TEMPERATURE READINGS. "F 

v 1 - ""ii'iriimnr 

PUMP 

VACOOM COMMENTS 

VUIPI I. 

I'OIN r 

CLOCK 

TIM E 

VEtocrrv 

11EA& 

I»elllP inwt 

ORIFICE 

MI.IfeR\OI 

l>ill»H in we 

TfOJLUME 

w .STACK. PROBE OVEN 

ORGANIC 

MOtrtJLE 

GASMETgft 

""ii'iriimnr 

PUMP 

VACOOM COMMENTS 

VUIPI I. 

I'OIN r 

CLOCK 

TIM E 

VEtocrrv 

11EA& 

I»elllP inwt 

ORIFICE 

MI.IfeR\OI 

l>ill»H in we 

TfOJLUME 

w .STACK. PROBE OVEN 

ORGANIC 

MOtrtJLE IMl- IN OUT 

""ii'iriimnr 

PUMP 

VACOOM COMMENTS 

A / o.;r? /.A 6SA 777 ,7*£> v . o 

X AT 0,7 J Ar ,2Y7 j/. a 

$ O, 5ks" A 8 f/tfn"/. (£> YoS AST) «#5C> ,5"7 7 3 - f- 0 7 /Z,£> 

J.<\ CO S 'O , / 

l

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RlHsfc 

Orsat 

02 

sx 

i-i' 
Unit 4, Condition 1 

MULTI-METALS FIELD DATA 

S:VSTACKJOB\2003\onyxBP\repoiWly sheels.doc 
Method 29 Metals Sampling Parameters 

UNIT 4 - Condition 1 

Run No. U4-C1-R1 U4-C1-R2 U4-C1-R3 

Date 16-Sep-03 16-Sep-03 17-Sep-03 

Start Time Units 1015 1645 800 

Stop Time 1309 1923 1039 AVGS 

Nozzle Diameter inches 0.315 0.315 0.315 0.315 

Barometric Pressure in. Hg 29.70 29.70 29.70 29.70 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 108.713 105.734 99.986 104.811 

Avg. DGM Temp. °F 94.9 89.3 74.3 86.1 

Avg Delta H in H 2 0 2.83 2.69 2.45 2.66 

Avg Delta H in. Hg 0.2077 0.1979 0.1801 0.1953 

DGM Calibration Factor -

0.9753 0.9753 0.9753 0.9753 

Gas Sample Volume dscf 100.851 99.059 96.247 98.719 

Total Water Collected mL 1355.5 1350.3 1327.0 1344.3 

Volume of Water Vapor scf 63.912 63.667 62.568 63.382 

Moisture (measured) % V/V 38.8 39.1 39.4 39.1 

Moisture (@ saturation) % v/v 100.8 100.9 100.9 100.9 

Dry Mole Fraction, 100-%N 0.6121 0.6087 0.6060 0.6090 

C 0 2 at Stack %dry 5.00 5.20 5.50 5.23 

0 2 at Stack %dry 13.00 13.00 12.70 12.90 

C O + N2 % dry 82.00 81.80 81.80 81.87 

Dry Molecular Weight Ib/lb-mole 29.32 29.35 29.39 29.35 

Wet Molecular Weight Ib/lb-mole 24.93 24.91 24.90 24.91 

Excess Air at Stack % 150.3 151.2 142.8 148.1 

Stack Diameter inches 48.0 48.0 48.0 48.0 

Stack Area sq. in. 1809.6 1809.6 1809.6 1809.6 

Static Pressure in H 2 0 -0.42 -0.52 -0.52 -0.49 

Stack Pressure in. Hg 29.67 29.66 29.66 29.66 

Avg. Stack Temp. °F 408.7 406.8 400.8 405.4 

Avg. Sqroot of Delta P — 0.8663 0.8610 0.8733 0.8669 

SDE Average 25.533 25.349 25.622 25.501 

Pitot Coefficient — 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 4,046 4,018 4,063 4,042 

Stack Flowrate wet acfm 50,841 50,498 51,051 50,797 

Stack Flowrate wet scfm 30,643 30,493 31,042 30,726 

Stack Flowrate dscfm 18,757 18,563 18,813 18,711 

Isokinetics % 104 103 99 102 

Meter Box No. ~ 80604 80604 80604 — 

Delta H @ in H2 0 2.0047 2.0047 2.0047 -

Field QA Yqc ~ 1.0025 1.0007 0.9954 0.9995 

[Deviation] Pre-Y % 2.79% 2.60% 2.06% 2.48% 

S:\STACK\JOB\2003\onyxRP\xldata\Sept 03\[M29 U4 C1 .xlsJEMISSpgl 
Unit 4 - Condition 1-RM29 

RUN I AVGS -- METAL S RUN 2 AVGS -- METALS RUN3 AVGS--METAL S 

PT Delta P SQRT 

Delia P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delia P SQRT 

Delia P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

a1 0.76 0.8718 68 67 2.80 406 0.67 0.8185 92 91 2.50 402 0.74 0.8602 63 62 2.40 395. 

a2 0.82 0.9055 93 83 3.00 407 0.82 0.9055 91 90 3.00 404 0.81 0.9000 70 65 2.60 397 

a3 0.92 0.9592 96 85 3.40 409 0.94 0.9695 91 89 3.50 408 0.87 0.9327 73 67 2.80 401 

a4 0.92 0.9592 98 87 3.40 410 0.83 0.9110 92 89 3.10 409 0.84 0.9165 74 68 2.70 404 

a5 0.75 0.8660 102 90 2.80 410 0.48 0.6928 93 90 1.80 409 0.76 0.8718 76 70 2.40 404 

a6 0.62 0.7874 102 91 2.30 405 0.58 0.7616 92 90 2.10 405 0.60 0.7746 77 71 1.90 400 

a7 0.63 0.7937 94 92 2.30 409 0.78 0.8832 86 85 2.90 400 0.66 0.8124 75 74 2.10 402 

a8 0.75 0.8660 99 94 2.80 406 0.80 0.8944 87 85 3.00 408 0.81 0.9000 78 75 2.60 401 

a9 0.82 0.9055 106 96 3.10 408 0.86 0.9274 90 86 2.90 413 0.85 0.9220 80 76 2.70 402 

a10 0.80 0.8944 110 98 3.10 410 0.88 0.9381 91 86 3.00 413 0.83 0.9110 82 78 2.70 403 

a11 0.75 0.8660 112 101 2.90 412 0.72 0.8485 91 86 2.40 411 0.76 0.8718 84 79 2.40 401 

at2 0.52 0.7211 111 102 2.00 412 0.61 0.7810 92 87 2.10 400 0.65 0.8062 85 80 2.10 400 

bl 0.0000 0.0000 0.0000 

b2 0.0000 0.0000 0.0000 

b3 0.0000 0.0000 0.0000 

b4 0.0000 0.0000 0.0000 

b5 0.0000 0.0000 0.0000 

b6 0.0000 0.0000 0.0000 

b7 0.0000 0.0000 0.0000 

b8 0.0000 0.0000 0.0000 

b9 0.0000 0.0000 0.0000 

b10 0.0000 0.0000 0.0000 

bl 1 0.0000 0.0000 0.0000 

b12 0.0000 0.0000 0.0000 

A VG 0.76 0.8663 94.9 2.83 409 0.75 0.8610 89.3 2.69 407 0.77 0.8733 74.3 2.45 401 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Traiii 

Run Number £J V" C ^ 

Client t3 -^y> t 

Facility Location vS^^-fig:/- 7~£-

Soui-ce 

Date _ 

Operator £1$ 

Slack Dia. - In. ¥ff " 

Start Time 

Stop Time 

&3L 

Barometric Pressure /c v 

Static Pressure (+/•) — ^>,y2 

Probe/Pitot Number ^ r*--^ » 

Pltot Coemdent £>. fpV 

Filter Box No. /y^ 7 / 

Meter Box No. "g&Ccl'/ 

LEA K CHECK S in "Hg 

INITIAL VAC. /S" In. 

MID VAC. In. 

In. 

C F M a>coz 

C F M 

FINAL VAC. /J j 

INIT. PITOT . 

CFMC. gtf < 

FINAL PITOTi^T--n 

Orifice Coefriclent (V)Q, *7 V^ J 

Delta H @ ^.OP y ? 

Nozzle Size/No. _ 

XAD Thermocouplc ID: 

Imp Outlet TC ID: 

FILTER DATA 

AN'tlMnER TARE 

* , 

IMPINGER VOL'S. 

INIT, 

0 

SCO 

FINAL, . 

SILICA GEL 

3IZ I 

VACUUM 

RiHsKl 

I S 

/ O D 

7 « H 

Orsat 

-Co 

Co /3.t> 

Inal Purge Rate 

'Inal PH 

SAMPLE 

POINT 

CLOCK 

TIME 

•VELOCITY 

De'LiP ln*c 

ORIFICE 

METtR VOL 

ijeltaH, nine 

UASMETSR 

VOV'MK 

ft*' STACK 

TEMPERATURE READINGS. »F 

PROBE OVEN 

ORGANIC 

MODULE IMP 

GAS METER ^ 

IN OUT 

COMMENTS 

o77T< ,A&L &5L 4JL 

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7 9 a .go . 4 , / 'Ye ? Sr 

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& P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Client 

Facility Location 

Source 

Dale 

Operator 

StackDIa,-In. ~ l/ $ " 

Start Time 

Stop Tim? 

Barometric Pressure »29. Co O 

Static Pressure (+/-) - (lb. SSL 

Probe/Pitot Number yCfJ'-^~-X 

Pilot Coemdent Q t ft/ 

Filter Boi No. Wff-J. I 

Meter Box No. &Qtt Q>l( 

LEA K CHECK S In "Hg 

INITIAL VAC. /s T 

MID VAC. 

FINAL VAC. J<i 

CFM 0.00 3 

CFM 

CFMO.OfU 

INIT. PITOT / FINAL PlTOTi ^C 

Orifice Coefndent (Y) c> 

Delta II @ 

Nozzle Size/No. 

-ml- FILTER DATA 

Q.3/J 

XAD Thermocouple ID: /( 

NUMBE R TARE 

IMPINGER VOL'S . 

INIT. FINAL „ 

4 3 3 

Z E E 

SILICA GEL 

Orsat 

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ia-7 

Final Purge Rate 

1 AM P II. 

i oir. 1 

CLOC K 

TIM E 

V M OT n 

HEA D 

Dell it*, 111 wt 

ouiru K 

MfI*R\O I 

IMl iH.lnwc 

OA<- MI IfR TEMPERATURE READINGS. °F POMP 

VACl'O M COMMENTS 

1 AM P II. 

i oir. 1 

CLOC K 

TIM E 

V M OT n 

HEA D 

Dell it*, 111 wt 

ouiru K 

MfI*R\O I 

IMl iH.lnwc 

VOLUM E 

(V STA< K PROBE OVEN 

ORGANIC 

MODULE 

GA&M.Ktl-H 

POMP 

VACl'O M COMMENTS 

1 AM P II. 

i oir. 1 

CLOC K 

TIM E 

V M OT n 

HEA D 

Dell it*, 111 wt 

ouiru K 

MfI*R\O I 

IMl iH.lnwc 

VOLUM E 

(V STA< K PROBE OVEN 

ORGANIC 

MODULE IMP It* 

POMP 

VACl'O M COMMENTS 

O o.7Y J.Y /oa. ?xo £V/ -?jr r .M/A <S>.5 

/•J A . 87 <J.Y& \ 7c3 6vT <Z.(S 

3 ,.?-<3 (S.U 7 St.* //7. v5" 2Y? -,57 •2? 6 7 9 . 0 

H 3 o O. ft V .0 .7 /,2C>.3 •/£></ 2STs> 7 V ^ 8 - Q.O 

S O , 7Co a,H y o y <3CT3 ' sz, 7G 7£5 

L Sn «. CoO / , 9 V V ^ JIY 6 « r & 7 / 7 . 0 

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v

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t ) ~ /Od 0 . 7 ^ /8Y. K ^ Y 7 fiY 7 9 s.«r " 

G / / o 7 . / /«?.? , O Yco c ? y r 5?.5~ 3 . 0 

/olO — — 

I 
i 

E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Client 

Facility Location 

Source 

Date 

Operator 

Barometric Pressure J9.7Q 

Static Pressure (+/-) — Q.^SH. 

Probe/Pitot Number 

Pltot Coefficient O & </ 

Filter Box No. /7?fi~J/ 

Meter Box No. gfcVSO <f 

LEAK CHECKS In "Hg 

INITIAL VAC. SS~ In. 

MIU VAC. In. 

FINAL VAC. /Q In. 

CFM 

INIT. PITOT "FINAL PITCHf-V 

FILTERDATA 

Slack Din. - In. Yt" Delta II @ a o V 7 NUMBER TARE 

Start Time Nozzle Size/No. Ot-QlQ 6? 

Stop Time XAD Thermocouple ID: ^SyCA 

IWI'lNl.FR VOL'S 

INIT. 

-o o» 

sa>a> 

FTNAL . 

O k 

£10 

SILICA PEL 

SAMPI1. 

roini 

( i Of K 

TIME 

vi i ocnv 

III \\) 

HellaP nt Vrc 

OriFICE 

Ml IER VOI 

Dfllall.in-wc 

GAS. METER TEMPERATURE READINGS. °F PUM;P 

VACUUM COMMA S 

SAMPI1. 

roini 

( i Of K 

TIME 

vi i ocnv 

III \\) 

HellaP nt Vrc 

OriFICE 

Ml IER VOI 

Dfllall.in-wc 

VOLUME 

«» STACK. PROBE OVEN 

ORGANIC 

MODULI! IMP 

GAS METER 

PUM;P 

VACUUM COMMA S 

SAMPI1. 

roini 

( i Of K 

TIME 

vi i ocnv 

III \\) 

HellaP nt Vrc 

OriFICE 

Ml IER VOI 

Dfllall.in-wc 

VOLUME 

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ORGANIC 

MODULI! IMP IN OUT 

PUM;P 

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Unit 4, Condition 2 

PCDD/PCDF FIELD DATA 
Metho d 0023 A Samplin g Parameter s 

Uni t 4 - Conditio n 2-R M 0023 A 

Run No. C2-R1 C2-R2 C2-R3 

Date 17-Sep-03 17-Sep-03 18-Sep-03 

Start Time Units 1145 1540 810 

Stop Time 1504 1849 1118 AVG S 

Nozzle Diameter inches 0.280 0.280 0.280 0.280 

Barometric Pressure in. Hg 29.60 29.60 29.55 29.58 

Net Sampling Time min. 180.0 180.0 180.0 180.0 

Volume Metered dcf 119.506 120.295 118.759 119.520 

Avg. DG M Temp. °F 92.9 94.5 80.3 89.2 

Avg Delta H in H 2 0 1.61 1.63 1.60 1.61 

Avg Delta H in. Hg 0.1183 0.1201 0.1176 0.1187 

D G M Calibration Factor ~ 0.9814 0.9814 0.9814 0.9814 

G as Sample Volume dscf 111.251 111.673 112.929 111.951 

Total Water Collected mL 1571.0 1626.7 1542.1 1579.9 

Volume of Water Vapor scf 74.073 76.699 72.710 74.494 

Moisture (measured) % v/v 40.0 40.7 39.2 40.0 

Moisture (@ saturation) % v/v 101.2 101.2 101.4 101.3 

Dry Mole Fraction, 100-%M — 0.6003 0.5928 0.6083 0.6005 

C 0 2 at Stack %dry 5.20 5.50 4.20 4.97 

0 2 at Stack %dry 12.50 12.10 13.00 12.53 

C O + N 2 % dry 82.30 82.40 82.80 82.50 

Dry Molecular Weight Ib/lb-mole 29.33 29.36 29.19 29.30 

Wet Molecular Weight Ib/lb-mole 24.80 24.74 24.81 24.78 

Excess Air at Stack % 135.5 125.3 146.7 135.9 

Stack Diameter inches 48.0 48.0 48.0 48.0 

Stack Area sq. in. 1809.6 1809.6 1809.6 1809.6 

Static Pressure in H 2 0 -0.51 -0.54 -0.50 -0.52 

Stack Pressure in. Hg 29.56 29.56 29.51 29.55 

Avg. Stack Temp. °F 404.7 408.3 404.3 405.7 

Avg. Sqroot of Delta P -- 0.8636 0.8607 0.8631 0.8625 

S D E Average - 25.396 25.360 25.375 25.377 

Pitot Coefficient ~ 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 4,041 4,041 4,041 4,041 

Stack Flowrate wet acfm 50,786 50,785 50,780 50,784 

Stack Flowrate wet scfm 30,642 30,512 30,602 30,585 

Stack Flowrate dscfm 18,394 18,088 18,616 18,366 

Isokinetics % 99 101 99 100 

Meter Box No. — 80102 80102 80102 ~ 

Delta H @ in. Hg 2.0590 2.0590 2.0590 ~ 

Field QA Yqc — 1.020 1.022 1.015 1.019 

[Deviation] Pre-Y % 3.9% 4.i % 3.4% 3.8% 

S:\STACKVIOB\2003\onyxRP\xldata\Sept 03\[M23 U4 C2.xls]AVGS 
PT a6 b3 b5 b6 

AVG 

DP 

0.62 

0.69 

0.82 

0.86 

0.81 

0.75 

0.60 

0.75 

0.80 

0.33 

0.80 

0.65 

0.75 

Unit 4 - Condition 2-RM 0023A 

RUN 1 AVGS -- PCDDs/PCDFs 

SQRT DP 

0,7874 

0.8307 

0.9055 

0.9274 

0.9000 

0.8660 

0.7746 

0.8660 

0.8944 

0.9110 

0.8944 

0.8062 

0.8636 

DGM IN 83 87 92 93 95 98 97 98 99 99 99 

92.9 

DGM 

OUT 83 84 87 89 90 92 94 94 95 95 95 95 

DH 

1.30 

1.40 

1.70 

1.80 

1.70 

1.60 

1.30 

1.70 

1.80 

1.80 

1.80 

1.40 

1.61 

STACK 

TEMP 

400 

400 

404 

405 

406 

408 

398 

403 

405 

409 

411 

407 

405 

DP 

0.63 

0.74 

0.82 

0.83. 

0.83 

0.68 

0.46 

0.65 

0.86 

0.84 

0.86 

0.75 

RUN 2 AVGS -- PCDDs/PCDFs 

0.75 

SQRT DP 

0.7937 

0.8602 

0.9055 

0.9110 

0.9110 

0.8246 

0.6782 

0.8062 

0.9274 

0.9165 

0.9274 

0.8660 

0.8607 

DGM IN 92 95 97 97 97 97 94 96 97 _ 96 97 97 

94.5 

DGM 

OUT 92 92 93 94 94 94 94 93 93 92 92 92 

DH 

1.40 

1.60 

1.80 

1.80 

1.80 

1.50 

1.00 

1.40 

1.90 

1.80 

1.90 

1.70 

1.63 

STACK 

TEMP 

400 

407 

411 

412 

412 

412 

402 

403 

410 

412 

410 

408 

408 

DP 

0.45 

0.68 

0.80 

0.86 

0.91 

0.85 

0.55 

0.70 

0.84 

0.84 

0.84 

0.70 

0.75 

RUN 3 AVGS -- PCDDs/PCDFs 

SQRT DP 

0.6708 

0.8246 

0.8944 

0.9274 

0.9539 

0.9220 

0.7416 

0.8367 

0.9165 

0.9165 

0.9165 

0.8367 

0.8631 

DGM IN 67 76 78 79 83 84 81 87 86 88 90 91 

80.3 

DGM 

OUT 66 70 72 74 76 78 80 84 82 83 85 86 

DH 

1.00 

1.40 

1.70 

1.80 

1.90 

1.80 

1.20 

1.50 

1.80 

1.80 

1.80 

1.50 

1.60 

STACK 

TEMP 

400 

402 

403 

404 

404 

405 

400 

400 

407 

408 

409 

409 

404 
P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Client 

Facility Location 

Source 

Date 

Operator 

Slack Ola. - lu. 

Start Time 

Stop Time 

Barometric Pressure oj *?. t^ji Q 

•7T — 

Sialic Pressure (+/-) — O. S'I 

Scrtcifl <••»/•• TL 

Probe/Pilot Number_ 

Pilot Coeriicicut 

Filter Box No. _ 

Meter Box No. 

LEA K CHECKS In "Hg 

INITIAL VAC. 

MIU VAC. 

FINAL VAC. /$ ~ 

+ 

INIT. PITOT 

C F M -

CFMfl.tSO/ 

//yrAte' Y 

Orifice Coefficient (Y)C?. 9?/* ^ 

Delta H ® J?.j>S?'a 

Noule Slie/No. &,J.8C> 

FINAL PITOT><^-T 

FILTER DATA 

XAD Thermocouple II): XAf?- £S~ 

Inip Outlet TCID: 

NUMBE R STARK;: 

)MHN<.lH\OL S 

INIT, 

C3 

FINAL. . 

i 

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3 £ 

SILICA PE L 

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OA. 

£> 

Final Purge Rnte_ 

Final PH 

SAMI'lt 

POINI 

< H X h 

TIME 

VKLQC1TV 

HEAD 

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ORIFICE 

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O AS M nu t 

VOLUME 

SlACk 

TEMPERATURE READINGS. °F 

PROBE 0V£N 

ORtiANIC 

MODULE I MP 

GASMETER 

IN O W 

PUMP 

YACOUM roMMFNrs 

o <3.6 2 Ma ~3vo TTT gv3 7 Q 

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E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Barometric Pressure $frS S*"" Train 

Run Number 

Client CX^VX 

Facility Location 

Source 

Date 

Operator 

Stack Dia.-Iii. 

Start Time 

Stop Time 

Static Pressure «/-) — d ,J"fc> 

Probe/Pilot Number C'.S'""/ — 

Pitot Coefficient 0. ' 

Filter Boi No. 

Meter Box No. 

CFM 

LEA K CHECKS In "Hg 

INITIAL VAC, / S~ InMID VAC. ^ - In. 

FINAL VAC. I In, 

+ 

INIT. PITOT -^FINAL P1TC 

CFMQ.QC K 

CFMfl. CC f 

Orifice Coefncient (Y) CP.^y/ y 

Dtl u 1 1

 @ Ag>.Ty<=> 

Nozzle Size/No. C.?.^?y^> 

FILTER DATA 

XAD Tliermocouple ID;^C4^p. eg. 

IDit. 

€> 

/OO 

m m . 

FINAli 

7 92* 

176 

SILICA GEL 

RlNsR. 

3 7 

Orsat 

C o i 

13- ° 

\>.r 

Final Purge Rate 

J.U1PI t 

pons i 

' !.(){ K 

11MK 

VMoci n 

HEA D 

Dtl'lP llfct 

ORiriLL 

MI'.IFR \ OI 

Dell til. In ITC 

LASMHU t 

^-i— " ^ 

TEMPERATURE REA 3INGS. °F • H I 

f MiWimuL 

PUM P 

VACUU M 

> « * 

, COMMENTS , ' 

J.U1PI t 

pons i 

' !.(){ K 

11MK 

VMoci n 

HEA D 

Dtl'lP llfct 

ORiriLL 

MI'.IFR \ OI 

Dell til. In ITC 

•VOLIIMT 

fl' STAC K PROB E OVF N 

ORGANI C 

MODUL E I MP 

I I ..GAS M 

IN 

BTE R 

O U T 

f MiWimuL 

PUM P 

VACUU M 

> « * 

, COMMENTS , ' 

/? / O .</.*- /. O / / . 7*1 jyy ^ (nCs> 8 , a 

/ . r /.</ / I . n Y£>£ JW2. ,2</7 •SXo ^•y 7C 70s 

3 o Sto /. 7 %.& St? 7& 7J? w o 

V O Bio A ? ' 3 7 . ( .2</9J ,<r/> J^2 '79 • ?y /£". O 

a / 7.9- Yew 2V2 ^7 "

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i 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Ac-/-, y c 

Sampling Train M.X&A 

Run Number - C-Z- 'R.JL 

<•'»«»< O^H-K 

Facility Localion'~S< <-Lft;|< 

Source 

Dale _ _ 

Operalor fjQ 

SlackDia. - in. •'' 

SlartTlme /'f/ l 

Slop Time /'/V p /ft</9 

Us?/*? 

Barometric Pressure J?-1?. & O 

Static Pressure (+/-) Q . v g~V 

Probe/Pitot Number ,JU,T'£-£ 

Pltol Coefficient d). ^ 

Filter Box No. Hj$-iT~ 

Meter Box No. 

LEAK CHECKS In "Hg 

INITIAL VAC. /J ~ In. CFM 0.003. 

MID VAC. •— In, CFM 

FINAL VAC. /O in. CFM fri CO 3 

Orince Coefficient (V) Q , 9 g/ y 

Delia H@ ^.0,Sf<i 

Nozzle Size/No. tf.-Zff- D 

SZO/GZ- lNIT.PITOIV. FINAL PITO*-"^-

FILTER DATA 

XAD Thermocouple ID: 

Imp Pullet TC ID; £-2\2S~ 

IMPINGER VOL'S. 

.INIT, 

0 

'Ci O 

FINAL; BINSE 

"7 co 

SILICA GEL 

Final PH 

4 ^ 

Orsat 

ycb'ii: 

p . / 

e 

SU1I(t 

I'OINI 

CLOCK 

TIMS 

VELOCITY 

HEAD 

Dell il'. In wt! 

ORIFICE 

Ml If R YOl 

l>ellulf.iri<rc 

CASMF.IEK 

YOl.VMR 

«» 

TEMPERATURE READINGS. °F 

STACK, PROBE OVEN 

ORCANIC 

MODULE IMP IN 

PUMP 

VACUUM COMMENTS 

z o : wt/ cv ?r ) •/too A S P 2 2 1 3 T 

SI? 

3£ 7/Q r & tLLL 2X1 MS 

X £ L 

66 

7<sr 

/o<\ 

/AQ 

L&SL 

/ &?. r 

i t / . y 

/. o 

i t 

92.0,1 

i?/Vv 

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£V7 

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6LL. 

6?6 

tt-

<£><e 

M l 

S z 

£ 2 _ 

'.M'l'MIMMIl Mill It'll Ull Hit 11! U111 tl III I III • 11 
Unit 4, Condition 2 

MULTI METALS FIELD DATA 

S:\STACKUOB\2003\onyxRP\repolMlysheels.dK; 

November 2003 
Method 29 Metals Sampling Parameters 

UNIT 4 - Condition 2 

Run No. Run 1 Run 2 Run 3 

Date 17-Sep-03 17-Sep-03 18-Sep-03 

Start Time Units 1145 1540 0810 

Stop Time 1434 1819 1048 AVGS 

Nozzle Diameter inches 0.282 0.282 0.282 0.282 

Barometric Pressure in. Hg 29.60 29.60 29.55 29.58 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 81.452 82.629 81.278 81.786 

Avg. DGM Temp. °F 89.9 93.3 78.3 87.1 

Avg Delta H in H2 0 1.60 1.60 1.58 1.59 

Avg Delta H in. Hg 0.1176 0.1176 0.1164 0.1172 

DGM Calibration Factor — 0.9753 0.9753 0.9753 0.9753 

Gas Sample Volume dscf 75.764 76.390 77.096 76.417 

Total Water Collected mL 1060.8 1113.9 1041.5 1072.1 

Volume of Water Vapor scf 50.017 52.520 49.107 50.548 

Moisture (measured) % v/v 39.8 40.7 38.9 39.8 

Moisture (@ saturation) % v/v 101.2 101.2 101.4 101.3 

Dry Mole Fraction, 100-%rv - 0.6023 0.5926 0.6109 0.6019 

C 0 2 at Stack %dry 5.20 5.50 4.20 4.97 

0 2 at Stack % dry 12.50 12.10 13.00 12.53 

CO + N2 % dry 82.30 82.40 82.80 82.50 

Dry Molecular Weight Ib/lb-mole 29.33 29.36 29.19 29.30 

Wet Molecular Weight Ib/lb-mole 24.83 24.73 24.84 24.80 

Excess Air at Stack o/ 

10 

135.5 125.3 146.7 135.9 

Stack Diameter inches 48.0 48.0 48.0 48.0 

Stack Area sq. in. 1809.6 1809.6 1809.6 1809.6 

Static Pressure in H2 0 -0.51 -0.54 -0.50 -0.52 

Stack Pressure in. Hg 29.56 29.56 29.51 29.55 

Avg. Stack Temp. °F 404.3 408.8 404.8 406.0 

Avg. Sqroot of Delta P - 0.8617 0.8507 0.8646 0.8590 

SDE Average - 25.333 25.074 25.425 25.277 

Pitot Coefficient - 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 4,030 3,996 4,047 4,024 

Stack Flowrate wet acfm 50,638 50,213 50,852 50,568 

Stack Flowrate wet scfm 30,564 30,151 30,624 30,446 

Stack Flowrate dscfm 18,410 17,867 18,708 18,328 

Isokinetics % 99 103 100 101 

Meter Box No. - 80604 80604 80604 — 

Delta H @ in H2 0 2.0047 2.0047 2.0047 -

Field QA Yqc ~ 1.0055 0.9936 0.9950 0.9980 

[Deviation] Pre-Y % 3.09% 1.88% 2.02% 2.33% 

S:\STACKUOB\2003\onyxRP\xldata\Sept 03\[M29 U4 C2.xls)EMISSpg1 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train °l 

Hun Number 

Cllcnl 

Facility Location 

Source 

Dnle 

Operator 

SlackPla. - lu. 

Start Time 

Stop TliiH' 

0 ,0 VX 

JLLY. 

9 fr// a :i 

JU1 

Barometric Pressure (j> Q 

Static Pressure (+/-) "-Q.<S"I 

Probe/Pilot Mumber ^AlS; S~~ Z. 

Pltot Coefficient C*,,^ f 

Filter Box No. h/B~Xl 

Meier Box No. 20(i>0'/ 

LEA K CHECKS In "Hg 

INITIAL VAC. In. 

MH) VAC. 111.. 

FINAL VAC. ^. O In. 

+ 

INIT. PITOT 

CFMQ.Oo l 

CFM(I> ,OC I 

CFM O .O i I 

"FINAL PITOTv^ -

tlSL 

//v,i ~ iZT? /& V 

t2t? y/M.G /f.i<j 

OriUce Coefnclenl (Y)Qt <37tC 7 

Delta II ® J?.0O</Y 

Nozzle Size/No. C^ff X 

FILTERDATA 

NUMBER ; mmm 

IMPlNUltVOI S 

1NIT, FlNAli 

CJ 

SCO 

J2J- T 

Final Purge Rale 

S AM Pi t 

I'DIN I 

CLOC K 

1IMT 

VIIOCH V 

HEA D 

Ucllll litti 

ORIFICE 

M l IfRUl l 

Htlt«H,lii<Tc 

HAS M r i tit TEMPERATURE READINGS. °F PUM P 

VACy« M 

tnlltf 

COMMENTS 

S AM Pi t 

I'DIN I 

CLOC K 

1IMT 

VIIOCH V 

HEA D 

Ucllll litti 

ORIFICE 

M l IfRUl l 

Htlt«H,lii<Tc 

WI.l'V L 

rr STAC K PBO IIP OVkN 

ORGANIC 1 

MODULI- j r\IP . IN 

KXER 

O C T 

PUM P 

VACy« M 

tnlltf 

COMMENTS 

A | O O. (oX / V 

2 /<•> 0.79 /, 7 ,<CJZ ? y 

<3 -Vo ) 

V 0..&V- sir" 

-xi 

• -4?— 

, — » • • 

<:/ & 

.... T~.h*.l ^(? w

/ 0 «-d.rtrf < 

— • — , , — 

, ,223.2 VJT , - r. . — • 

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9 o 7.7 YQb ^ y <>y (*.o 

<T /<DO 0.7J ' J/7 270, i yo 7 o?y? its 9 y IS 6 0 

(r> / / a 0.5*7 /.:< 27 7. X y o / V r 

283,339 . — — 

1 4 

mm 

7W 

7^-

Orsat 

I>.< 
Unit 4 - Condition 2-Multi Metals 

RUN 1 AVGS -- METALS RUN 2 AVGS -- METALS RUN 3 AVGS -- METALS 

PT Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delia H STACK 

TEMP 

Delta P SQRT 

Delia P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delia P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

al 0.68 0.8246 82 81 1.40 401 0.72 0.8485 91 91 1.60 401 0.68 0.8246 69 67 1.50 402 

a2 0.79 0.8888 84 83 1.70 400 0.77 0.8775 93 91 1.70 410 0.78 0.8832 74 70 1.60 403 

a3 0.82 0.9055 86 84 1.70 401 0.82 0.9055 95 92 1.80 410 0.86 0.9274 76 72 1.80 404 

a4 0.82 0.9055 88 85 1.70 404 0.82 0.9055 98 93 1.80 412 0.84 0.9165 78 73 1.80 404 

a5 0.76 0.8718 91 89 1.60 409 0.70 0.8367 100 94 1.50 413 0.70 0.8367 79 74 1.50 406 

a6 0.59 0.7681 93 90 1.20 404 0.57 0.7550 101 96 1.30 406 0.58 0.7616 80 76 1.20 404 

a7 0.76 0.8718 94 93 1.60 404 0.63 0.7937 92 91 1.40 408 0.80 0.8944 78 78 1.70 403 

aB 0.82 0.9055 94 93 1.80 408 0.72 0.8485 92 91 1.60 410 0.80 0.8944 82 79 1.70 406 

a9 0.80 0.8944 95 93 1.80 407 0.84 0.9165 93 91 1.80 411 0.81 0.9000 84 81 1.70 405 

a10 0.78 0.8832 94 92 1.70 406 0.84 0.9165 93 91 1.80 412 0.83 0.9110 85 82 1.70 407 

a11 0.75 0.8660 94 93 1.70 407 0.71 0.8426 93 91 1.60 412 0.78 0.8832 87 83 1.60 409 

a12 0.57 0.7550 94 92 1.30 401 0.58 0.7616 94 91 1.30 400 0.55 0.7416 88 84 1.20 405 

b1 0.0000 0.0000 0.0000 

b2 0.0000 0.0000 0.0000 

b3 0.0000 0.0000 0.0000 

b4 0.0000 0.0000 0.0000 

b5 0.0000 0.0000 0.0000 

b6 0.0000 0.0000 0.0000 

b7 0.0000 0.0000 0.0000 

b8 0.0000 0.0000 0.0000 

b9 0.0000 0.0000 0.0000 

b10 0.0000 0.0000 0.0000 

b11 0.0000 0.0000 0.0000 

b12 0.0000 0.0000 0.0000 

AVG 0.75 0.8617 89.9 1.60 404 0.73 0.8507 93.3 1.60 409 || 0.75 0.8646 78.3 1.58 405 
: P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train .sL1<2c} 

Run Number 

Client 0, 0 YX 

0*4-CA-RSL 

Facility Location Ci>\n.c1> f TLUH1 Source 

Dnle 

Optrnlor 

Stack Din.-In, 

Start lime 

Barometric Pressure ,Q>Q 

Static Pressure (+/-) *• Q,S¥ 

Probe/Pitot Number .X-(J~-,^~-~Z. 

Pltot Coemdent Q 

Filter Box No. /// j -J / 

Meter Box No. f£&(W 

LEA K CHECKS lu "Hg 

INITIAL VAC. In. 

MID VAC. III.. 

lu. 

CFMO.OQ 3 

C F M * 

FINAL VAC. CFM<3,t36 ( 

INIT. PITOT 

Jill 

/<T¥o u/t 

Orifice Coefficient ,9 AS? ? 

Delta H @ .2.06'/7 

Noule Size/No. 

+ 

FINAL PlTO'g^ 

FILTER DATA 

IS UMBER: STARES 

IMl INI.LR VOL 1 

INIT. 

J2_ 

z o o 

V tS Cl 

FIN At 

I f 

Juv> 

uro-

/oo 

Orsat 

mm 

I*? 

Imp Outlet TC ID: 1 f Final P H 

SAMPL E 

roir, i 

( I OC K 

HMfc 

VELOCITY 

HEA D 

Dtlnl litwc 

OriFlCE 

MlIMtVO L 

DrltnH.lu wc 

OAS M T I fit TEMPERATURE READINGS. °F niM P 

VACUU M 

h-m . 

COMMENT S 

SAMPL E 

roir, i 

( I OC K 

HMfc 

VELOCITY 

HEA D 

Dtlnl litwc 

OriFlCE 

MlIMtVO L 

DrltnH.lu wc 

VOLUM E 

ff SI U k rjioiii. OVEN 

ORGANIC 

MODULE 

...\.GAS.MET.;ER. 

niM P 

VACUU M 

h-m . 

COMMENT S 

SAMPL E 

roir, i 

( I OC K 

HMfc 

VELOCITY 

HEA D 

Dtlnl litwc 

OriFlCE 

MlIMtVO L 

DrltnH.lu wc 

VOLUM E 

ff SI U k rjioiii. OVEN 

ORGANIC 

MODULE I MP IN otrr 

niM P 

VACUU M 

h-m . 

COMMENT S 

,3 / O O./J i J s t 'fi «•/&/ AJ/ A 4 / 

a /£> cb.~77 7 Y / O ,<rv ^/ 

c\. V3L / . fr ^7/7 Y / o .QSV s y ck.o 

."KO Ci. 82 / . ,?<W . V Y/JL J V Y ? f r § 3 ci. o 

YO a.T' o 3/J. Y Y l Z Z l Y & a / o o 9<Y 

G> n,<?7 / . 3 C ?/9 . / VOCr> a m J O T S~3 

A / GO n . (oC? / y YCW XYCs a s 7 s . O 

c2 7 0 r \ , 7 J i 7- 6 3*/ , 7 H/<5 a s z <s*v 9 / / . , 0 

S O 6 , W /.£ V / / 

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V 

E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

iMPlNOfcR VOL'S, Orsat 

Sampling Traill AiZtl Barometric Pressure tS /iOO I EAK CHECK S In "He 

S1TIALVAC. /J T In. CF M 1 

lNH. I I INAL RlNSE COZ I 02. 

Kun Number (V V - C i! - AL? Static Pressure W-) - ft. <7i V 

EAK CHECK S In "He 

S1TIALVAC. /J T In. CF M 1 

CHenl O. OyX Probe/Pilot Number ^US'S'"2. MID VAC. In, CF M • -• •?4 r 

Facility Location S'W,,; { , T i Pilot Coefficient d>.^Y FINAL VAC. ( n lit. CFMrt.rtrtt 

Source C" / FlllerBoxNo. M&~Jll + 

NIT, PITOT c.— FINAL PIT( 

+ C3 

D«le Illti/oS Meter BoxNo. jfCY„r>V' 1 

+ 

NIT, PITOT c.— FINAL PIT( /OO 

Operntor /\i5 Orifice Coefficient (Y) 0.°ll<;3 FILTE R DAT A ^ « /OQ 

Slack Dia.-In. Vft " Delto H @ ,?.00 ' / 7 MUMBER TARE 

Start Time CTSlQ Nozzle Size/No. 0.2.9JL . . 

. 

Slop Time Cfl/O SO</51 XAD Thermocouple ID: ^Cj/SJ Sti ICAGL L Final Pure' Rate *" 

_M , ImpOulletTCID: CZ- ? Filial PH 

JtAMl'I I 

W I M 

C l OCIv 

TIME 

Vr I OCI IV 

HEA D 

l»ell IP, in 1V1 

ORIHCP 

MI.IH? VOL 

DelliH.iiinc 

UAS Mr lilt TEMPERATURE READINGS. °F I PUMP 

v' COMMENTS , ; 

JtAMl'I I 

W I M 

C l OCIv 

TIME 

Vr I OCI IV 

HEA D 

l»ell IP, in 1V1 

ORIHCP 

MI.IH? VOL 

DelliH.iiinc 

U>LUMF 

ft' S1A< K PROim OMtORGANIC MODULE 

llllllll l mmmmmm VACUOM v' COMMENTS , ; 

JtAMl'I I 

W I M 

C l OCIv 

TIME 

Vr I OCI IV 

HEA D 

l»ell IP, in 1V1 

ORIHCP 

MI.IH? VOL 

DelliH.iiinc 

U>LUMF 

ft' S1A< K PROim OMtORGANIC MODULE IMP j IN OUT | m. a* 

v' COMMENTS , ; 

A 1 CJ o.Wii 7.S yoj. ,2<W Cn<7 

SL. ./<.> . . r>.7V /, (a 3?X. 7 JVC, K Y7 7V 70 . r . o 

J. zs-o.sj- 3iT2- 3 y y \ Yy 76, 7JZ 

H ;?f??- 7 <yoY Yl 75? 7R 

o~ y o t T ? y . Y<?6> £Z> 79 7Y 

L> A -? <Yo</ J2Y? y<? 7& v..«r 

R 1 CoO 7.7 Yo?. Y/j2 AYY CoY ? * 

A •70 0 . s o J.7 VA/ , / ;3Y8 Y<% 

SO 7. 7 yj?/ y <7dsST ,ar, ? 

<]o /. 7 ^s* . </ Yo? fr.r 0^ j? 

/oo / , ci V £.r . Y Yd>9 2 S-7 ayc S3 2? 

,<f> .. 

//£ > /.a m.- s YtiST as? J2S* 

•Ma p /JLO 1 - — 

\ 

•

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~ 
INTERNATIONAL 

Unit 2 

PCDD/PCDF FIELD DATA 

S:\STACKVJOB\2003VonyxRP\repoilMlysheels.doc 

November 2003 
Metho d 0023 A Samplin g Parameter s 

Uni t 2 

Run No. R1 R2 R3 

Date 18-Sep-03 19-Sep-03 19-Sep-03 

Start Time Units 1445 830 1250 

Stop Time 1849 1142 1601 AVG S 

Nozzle Diameter inches 0.430 0.430 0.430 0.430 

Barometric Pressure in. Hg 29.55 29.60 29.60 29.58 

Net Sampling Time min. 180.0 180.0 180.0 180.0 

Volume Metered dcf 121.062 121.479 116.108 119.550 

Avg. DG M Temp. °F 108.7 60.3 69.5 79.5 

Avg Delta H in H 2 0 1.59 1.74 1.56 1.63 

Avg Delta H in. Hg 0.1170 0.1281 0.1146 0.1199 

D G M Calibration Factor — 0.9814 0.9814 0.9814 0.9814 

G as Sample Volume dscf 109.373 120.219 112.854 114.149 

Total Water Collected mL 1944.1 1910.7 1875.2 1910.0 

Volume of Water Vapor scf 91.664 90.090 88.416 90.057 

Moisture (measured) % v/v 45.6 42.8 43.9 44.1 

Moisture (@ saturation) % v/v 101.1 101.1 101.0 101.1 

Dry Mole Fraction, 100-%M -- 0.5440 0.5716 0.5607 0.5588 

C 0 2 at Stack %dry 6.70 6.70 6.70 6.70 

0 2 at Stack % dry 12.10 12.10 11.50 11.90 

C O + N 2 %dry 81.20 81.20 81.80 81.40 

Dry Molecular Weight Ib/lb-mole 29.56 29.56 29.53 29.55 

Wet Molecular Weight Ib/lb-mole 24.29 24.61 24.47 24.45 

Excess Air at Stack % 129.6 129.6 113.9 124.4 

Stack Diameter inches 48.0 48.0 48.0 48.0 

Stack Area sq. in. 1809.6 1809.6 1809.6 1809.6 

Static Pressure in H 2 0 0.45 0.11 0.20 0.25 

Stack Pressure in. Hg 29.58 29.61 29.61 29.60 

Avg. Stack Temp. °F 381.8 367.1 372.1 373.7 

Avg. Sqroot of Delta P ~ 0.3857 0.4168 0.3942 0.3989 

S D E Average — 11.192 11.988 11.372 11.518 

Pitot Coefficient ~ 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,799 1,914 1,821 1,845 

Stack Flowrate wet acfm 22,610 24,051 22,878 23,180 

Stack Flowrate wet scfm 14,022 15,194 14,369 14,528 

Stack Flowrate dscfm 7,628 8,685 8,057 8,124 

Isokinetics % 99 96 97 97 

Meter Box No. ~ 80102 80102 80102 ~ 

Delta H @ in. Hg 2.0590 2.0590 2.0590 — 

Field QA Yqc — 1.013 1.009 1.008 1.010 

[Deviation] Pre-Y % 3.2% 2.8% 2.7% 2.9% 

S:\STACKUOB\2003\onyxRP\xldata\Sept 03\[M23 U2.xls]TEQS 
Unit 2 

PT 

RUN 1 AVGS -- PCDDs/PCDFs RUN 2 AVGS -- PCDDs/PCDFs RUN 3 AVGS - PCDDs/PCDFs 

PT DP SQR T 

DP 

DGM 

IN 

DGM 

O UT 

DH STACK 

TEM P 

DP SQR T 

DP 

DGM 

IN 

DGM 

OUT 

DH STACK 

TEMP 

DP SQRT 

DP 

DGM 

IN 

D G M 

O U T 

DH STACK 

TEM P 

a1 0.17 0.4123 95 95 1.80 382 0.19 0.4359 59 58 1.90 367 0.14 0.3742 63 62 1.40 367 

aZ 0.18 0.4243 103 97 1.90 382 0.18 0.4243 63 60 1.80 370 0.14 0.3742 67 63 1.40 373 

a3 0.15 0.3873 107 103 1.60 382 0.19 0.4359 60 58 1.90 369 0.16 0.4000 67 65 1.60 375 

a4 0.13 0.3606 111 107 1.40 383 0.19 0.4359 61 58 1.90 368 0.18 0.4243 68 65 1.80 373 

a5 0.16 0.4000 112 109 1.70 383 0.20 0.4472 63 59 2.00 367 0.16 0.4000 69 66 1.60 374 

a6 0.15 0.3873 114 109 1.60 383 0.18 0.4243 63 59 1.80 367 0.17 0.4123 69 66 1.70 373 

a7 0.15 0.3873 114 111 1.60 382 0.14 0.3742 60 59 1.40 367 0.16 0.4000 67 67 1.60 372 

a6 0.13 0.3606 115 112 1.40 383 0.16 0.4000 61 59 1.60 367 0.17 0.4123 71 67 1.70 372 

a9 0.14 0.3742 117 112 1.50 383 0.17 0.4123 61 59 1.70 366 0.16 0.4000 73 69 1.60 372 

a10 0.15 0.3873 118 110 1.60 378 0.17 0.4123 62 59 1.70 366 0.16 0.4000 77 72 1.60 372 

a11 0.15 0.3873 113 109 1.60 381 0.16 0.4000 63 60 1.60 366 0.12 0.3464 80 75 1.20 371 

a12 0.13 0.3606 109 107 1.40 380 0.16 0.4000 62 60 1.60 365 0.15 0.3873 81 78 1.50 371 

AVG 0.15 0.3857 108.7 1.59 382 0.17 0.4168 60.3 1.74 367 0.16 0.3942 69.5 1.56 372 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

iJ 

Sampling Train 

Run Number i >.2 - C. t - /H^i,' 

Clk"!

 rb^yx 

Facility Locallon ^Sct tf-ff P / 'J-£~ 

Source 

Dale 

Operator 

SlackDia. - iu. 

Start Time 

Stop Time 

Ilarometrlc treasure ^2 7 < Cj 0 

Static Pressure (+/-) ••/•' ,/f 

Probe/Pilot Number .yCf,fS^-/~ 

Pitol Coefficient Q . g"-/ 

Filter Bo* No. - ft* 

Meter BOJI No. 

LEA K CHECKS in "Hg 

INITIAL VAC. IS" In. CFM t<JjS 

MIDVAC. <~" III., CF M —-

FINAL VAC. / V "in. CF M '00 7 

INIT. PITOT FINAL PITOT 

3 9 ^ 

/0'iCO / il . 

SAM PI I 

POINI 

CLOCK VELOCITY 

UEAD 

Ddi-iP, In. « 

ORIFICE 

M l JFK VOL 

DriltH in IYC 

Orince Coefliclent (Y) (VQff/t- / 

Delia II @ ,.3.,OS9Q 

Nozzle Size/No. , i/J Q 

XAD Thermocouple ID: 

Imp Outlet TC. U): 

FILTE R DAT A 

NUMBERS mum 

IMI'INOI R \ OL"> 

INIT, 

o 

7 C o 

_S2_ 

FlrtAL 

7 W 

^ 7 2 

SILICA GE L 

tlASMUM t 

YDI.UM1 

W . 

TEMPERATURE READINGS. °F /t. 7 

MAC K IKOIll OVEN 

OIIUAMC 

MODULE IMP 

iin jl^METEft i||i ; 

'"IN"" )"' wr ' 

Orsat 

COZ p i 

)>.>• 

Final PH 

POMP 

VACUU M 

'"HD 

lHI'.linM'.M'Wl 

CUMMFNTS 

•U- Z Z 

2 21 4 ^ - 4 a 

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UK 7l-"L Ml. 5% Ml ILL. 

d L . iM. &1L2. 

J L Z . MSL 6/ 

1 2 . 3 V y . ^ 4 ^ -

i£JL 

(JL I L LA. i l l &.V6' £*± 

Slop 

Z L 

2JL 

lk. L L ikii . 1^0 
E F A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train ,,CQ3 SA 

Run Number 

Client 

Facility Location 

Source 

Date 

Operator //2« I 

Barometric Pressure 

Static Pressure (+/-) -j-t?, 3,0 

o,ayy. Probe/Pitot Num ber ^ C-. 

Pilot Coefficient tf, 'cf </ 

Filter Box No. A// ? - fr* 

Meter Box No. ft,V£x,2. 

LEA K CHECKS In "Hg 

INITIAL VAC. j In. 

111., 

III. 

M P VAC. _ J 

FINAL VAC. 

CFM _ 

C F M 

,00 / 

INIT. PITOT FINAL PITO X>^ ~ 

StackDIa.-

Slart Time 

in. 

i!i ,:i'0 //V-\L L 

Orifice Coefficient (Y) ^B. 757'V 

Delta II @ ^.<^5"fei> 

Nozile Slie/No. 0:^/^0 

FILTER DATA 

J NOMBER S STAKES 

lMPINCUUO I "3 

jam . 

/CO 

o 

FINAL RINS M 

Orsat 

toi l 

/ Imp Outlet TC ID: C.JC - Z^T [ 1 Final PH ^ , , .l^ ^ 

SAMPLE 

POINI 

CLOC K 

TIME 

VELOCITY 

HEAD 

llrUll' 'IM'C 

ORIFICE 

M" rut MM 

')ell ill lu TC 

<}ASMI IHt TEMPERATURE REA DlNGS.^Ffe 7 

VACUUM 

ln-Ht; 

COMMENTS 

SAMPLE 

POINI 

CLOC K 

TIME 

VELOCITY 

HEAD 

llrUll' 'IM'C 

ORIFICE 

M" rut MM 

')ell ill lu TC 

un.i'Mr / 

SI \( IC PttQBE OVEN 

OHiMNIC 

MOflliLF 

,igA$.P.E5CER VACUUM 

ln-Ht; 

COMMENTS 

SAMPLE 

POINI 

CLOC K 

TIME 

VELOCITY 

HEAD 

llrUll' 'IM'C 

ORIFICE 

M" rut MM 

')ell ill lu TC 

un.i'Mr / 

SI \( IC PttQBE OVEN 

OHiMNIC 

MOflliLF IMP IN 00 r 

VACUUM 

ln-Ht; 

COMMENTS 

ft 1 ,/</ X</ 1 li,n 

/ . r , / V 'IP..!, <? JSV r r vi /.,'"> 11,0 

./ v 0 i AS •pil any 

'/,<r h$ </-0 1 . 7 . c r (J W.o 

i to 0 V/,x. 0 & ?> (i .r« v 

-?.r !; -/ ' I ; 4'<i 1'

 f i ,*.rt> )3..T 

• ? o 4i/.9 i 1 . 

f\f r 0 ."ll iiL '0,3. 

.. .... fa ^ > ;A, r 

j. ; V n i 7 1-7 Y / 

3 .10 73 vii i l o 

v 4.S" /. L? '/ 1, / . S '•i }r9k j ..r o 7 c?-

'/,0 ' ; T 

). a . 47/ . L S o 7 5" li-0 

7,> 1— W o , V MX r W r 

Si'OO 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train _ 

Rim Number 

Client 

-U?.?. A Barometric Presmre <p%sS 

Static Pressure (+/-) •/• 

Facility Location Squc,ef , T C 

Source 

Dale 

Operator 

SUck Dia. 

j^Ag s l °

p T "n

' j^trO/Ttn/mifr ) 

Probe/Pilot Number j/ Cf,C->'PPltot Coemdent Q.fr't ' 

Filter Box No. A/R-£rh<3' 

Meter Box No. $f@t]i0^f4&CA.mT. PITOT 

Orifice Coefficient (Y) Q.^sy ^ 

Delta H @ J.CXTf^ 

NozileSlie/No. Q,y.?< S 

LEA K CHECKS In "Hg 

INITIAL VAC. /,f~~ In. 

MID VAC. 111. 

FINAL VAC. /2 * S In. 

CFM_ 

C F M 

FINAL PITO 

XAD Thermocouple IDi XjLD JlZ" 

Imp Outlet TC ID: 

FILTE R DAT A 

IMPlNGKIl VOL'S. 

INIT. 

/OO 

/ao 

M N A X , 

2221 

32JL 232* 

SlUCACE L Final Purge Rate_ 

Final PH 

RINSE* 

Orjat ;j 

mm mm 

a i 

1 
Uni t 2 

MULT I METAL S FIEL D DAT A 

S:\SfACKUOB\2003\onyxRP\repoilMlysheels.cloc 

November 2003 
Method 29 Metals Sampling Parameters 

UNI T 2 

Run No. Run 1 Run 2 Run 3 

Date 18-Sep-03 19-Sep-03 19-Sep-03 

Start Time Units 1445 830 1250 

Stop Time 1810 1112 1531 AVGS 

Nozzle Diameter inches 0.431 0.431 0.431 0.431 

Barometric Pressure in. Hg 29.55 29.60 29.60 29.58 

Net Sampling Time min. 120.0 120.0 120.0 120.0 

Volume Metered dcf 85.391 84.763 82.288 84.147 

Avg. DGM Temp. °F 98.3 60.0 67.2 75.2 

Avg Delta H in H2 0 1.74 1.78 1.67 1.73 

Avg Delta H in. Hg 0.1281 0.1311 0.1225 0.1272 

DGM Calibration Factor -0.9753 0.9753 0.9753 0.9753 

Gas Sample Volume dscf 78.120 83.405 79.852 80.459 

Total Water Collected mL 1326.0 1304.4 1298.0 1309.5 

Volume of Water Vapor scf 62.521 61.502 61.201 61.741 

Moisture (measured) % v/v 44.5 42.4 43.4 43.4 

Moisture (@ saturation) %v/v 101.1 101.1 101.0 101.1 

Dry Mole Fraction, 100-%ri 0.5555 0.5756 0.5661 0.5657 

C 02 at Stack %dty 6.70 6.70 6.70 6.70 

02 at Stack %-dry 12.10 12.10 11.50 11.90 

CO + N2 %dry 81.20 81.20 81.80 81.40 

Dry Molecular Weight Ib/lb-mole 29.56 29.56 29.53 29.55 

Wet Molecular Weight Ib/lb-mole 24.42 24.65 24.53 24.53 

Excess Air at Stack % 129.6 129.6 113.9 124.4 

Stack Diameter. inches 39.0 39.0 39.0 39.0 

Stack Area sq. in. 1194.6 1194.6 1194.6 1194.6 

Static Pressure in H2 0 0.45 0.11 0.20 0.25 

Stack Pressure in. Hg 29.58 29.61 29.61 29.60 

Avg. Stack Temp. 381.7 .; 367.8 372.3 373.9 

Avg. Sqroot of Delta P -0.4047 0.4222 0.4080 0.4116 

SDE Average -

11.742 12.147 11.769 11.886 

Pitot Coefficient ~ 0.84 0.84 0.84 0.84 

Stack Gas Velocity afpm 1,883 1,938 1,882 1,901 

Stack Flowrate wet acfm 15,617 16,074 15,611 15,767 

Stack Flowrate wet scfm 9,687 10,146 9,802 9,878 

Stack Flowrate dscfm 5,381 5,840 5,549 5,590 

Isokinetics % 99 97 98 98 

Meter Box No. - 80604 80604 80604 — 

Delta H @ in H2 0 2.0047 2.0047 2.0047 

Field QAYqc . 1.0051 0.9880 0.9911 0.9947 

[Deviation] Pre-Y % 3.06% 1.30% 1.62% 1.99% 

S:\STACK\JOB\2003\onyxRPWciata\Sep! 03\[Metals Blank Correction Unit 2.xls]RUN 1 
Unit 2 

RUN 1 AVGS -- METALS RUN 2 AVGS - METALS RUN 3 AVGS -- METALS 

PT Delia P SQRT 

Delia P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delia P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

Delta P SQRT 

Delta P 

DGM 

IN 

DGM 

OUT 

Delta H STACK 

TEMP 

a1 0.19 0.4359 96 96 2.00 376 0.19 0.4359 59 59 1.90 370 0.15 0.3873 63 63 1.50 370 

a2 0.15 0.3873 97 95 1.60 381 0.19 0.4359 63 59 1.90 370 0.17 0.4123 66 64 1.70 373 

a3 0.17 0.4123 94 94 1.80 380 0.18 0.4243 61 59 1.80 369 0.17 0.4123 66 64 1.70 374 

a4 0.18 0.4243 97 96 1.90 383 0.17 0.4123 60 58 1.70 368 0.17 0.4123 66 64 1.70 376 

a5 0.15 0.3873 99 97 1.60 383 0.17 0.4123 60 58 1.70 368 0.18 0.4243 67 65 1.80 375 

a6 0.14 0.3742 101 98 1.50 383 0.18 0.4243 61 59 1.80 367 0.18 0.4243 68 65 1.80 375 

a7 0.16 0.4000 102 102 1.70 381 0.17 0.4123 61 60 1.70 367 0.17 0.4123 66 66 1.70 370 

a8 0.17 0.4123 101 101 1.80 381 0.18 0.4243 61 59 1.80 367 0.17 0.4123 69 67 1.70 371 

a9 0.19 0.4359 100 99 2.00 384 0.17 0.4123 61 59 1.70 367 0.18 0.4243 70 67 1.80 372 

a10 0.16 0.4000 102 100 1.70 386 0.18 0.4243 62 59 1.80 367 0.17 0.4123 72 69 1.70 373 

a11 0.15 0.3873 100 99 1.60 383 0.18 0.4243 62 59 1.80 367 0.15 0.3873 73 70 1.50 371 

a12 0.16 0.4000 97 97 1.70 379 0.18 0.4243 62 60 1.80 366 0.14 0.3742 72 70 1.40 368 

b1 0.0000 0.0000 0.0000 

b2 0.0000 0.0000 0.0000 

b3 0.0000 0.0000 0.0000 

b4 0.0000 0.0000 0.0000 

b5 0.0000 0.0000 0.0000 

b6 0.0000 0.0000 0.0000 

b7 0.0000 0.0000 0.0000 

b8 0.0000 0.0000 0.0000 

b9 0.0000 0.0000 0.0000 

b10 0.0000 0.0000 0.0000 

bl 1 0.0000 0.0000 0.0000 

. b12 0.0000 0.0000 0.0000 

• 

AVG 0.16 0.4047 98.3 1.74 382 0.18 0.4222 60.0 1.78 368 0.17 0.4080 67.2 1.67 372 
E P A ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Client 

Facility Location 

Source 

Date 

Operator 

Stack Dia.-In. 

Start Time 

Slop Time 

Sialic Pressure (+/-) + 

Barometric Pressure 

Probe/Fltot Number 

Pilot Coemdent 

Filter Box No. ~ 

Meter Box No. 

LEA K CHECK S In "Hg 

INITIAL VAC. / 5 

MID VAC. _ 

FINAL VAC. 

C F M 

INIT. PITOT 

Orince Coemdent (Y) Q.9yj\ J 

Delta H ( 

Nozzle Size/No. 

fe 

CFM0<30 | 

FINAL VlTOTtyC 

FILTER DATA 

NUMBER TAR E 

• — — 

<Vu.i)vl"7*-

lMl'JNOKtt VOX'S.; 

/OO 

FlNAt 

/ OA 

SILICA GEL Final Purge R«te_ 

Final PH ' 

Orsat 

mm 

67 

£>7 

1T& 

TEMPERATURE READINGS. "F 

j ORGANIC 

OVKN I MOIHILF 

22£ 

IMP 

VACUO M COMMENTS 

S t y J5K Ah7F 

S I 

3Z 
E P A -ISOKINETI C SAMPLIN G - FIEL D DAT A SHEE T 

Sampling Train 

Run Number 

Clltnl 

Facility Location 

Source 

Dale 

Operator 

Slack Dia. 

Start Time 

Stop Time 

llaroiuetrlc Pressure 

Static Pressure {+/-) -f" Q ,-\ I 

Probe/Pitot Number yC\ fZ-A"' 2. 

Pltot CoelTlcleut Q. % 

Filter Box No. 

Meter Box No. 

LEA K CHECK S In "Hg 

INITIAL VAC. /4 In. 

MID YAC. In.. 

III. 

lMPlNtUKVOI'S. 

FINAL VAC. ? 

C F M O.cVaj] 

CFM_ 

CFM" 

1) 

• iu. 

SAMPL E 

POlNI 

rr--. 

CLOC K 

TIMK 

VELOCITY 

III Wl 

0*11 il'.iil wt 

OIMF1CE 

MIlfKNOI 

ttcllnfl In ire 

Oririce Coetnclent (Y) £ > 9 7^ 3 

Delta II ® 

Nozzle Size/No. Q ..L/3 I 

XAD Thermocouple ID; 

Imp Outlet TC ID: 

8'CVx»<V/ 1N1T.PIT0T_ • FINAL PIT0«n- O 

FTLTERDATA 

liASMT IER 

v o n Mr. 

ft' 

SNUMBEIV : 

INIT. 

yc>c> 

FINAL,. 

WL 

7 

- SILICA PEL 

TEMPERATURE READINGS. °F 

? I* I ; i^rftiiSif!l!!'W;i 

.RlNSgjj 

,/ifO 

Orsat 

LP 

IP-.I 

Final Purge Rale_ 

Final PH 

STAC K PROBE OVE N 

OIU3V.MC 

MODUL E IMP 

CAS METER 

IN OtlT 

VACUUM 

tn Hg 

COMMENT^ 

B 1 a 

7LJ 7 

T5 ZSLL EK t 5 ~ 

I 

10 

SUT 

2 i l IT 

± Z 2 

ISO u n 

HO f t 

u i 

T\ . ' i 5 2 1 

So £ 2 _ £ 2 0 • f T O T J o. 

5. 

m . 

ZkHL" E E ML 

^ 7 0 'tea. ISO 2 ^ 

jte — o • n 

O H ' S t 

3 k _ 
EPA ISOKINETIC SAMPLING - FIELD DATA SHEET 

Sampling Train 

Run Number 

Client 

Facility Location 

Source 

Date 

Optrnlor 

Slack Dia. - In. 

Start Time 

Stop Time 

(7J--CJ ^A*: ? 

" 3 ? 

XJ1 

YlSO 

Unromefrlt Pressure •21, UO 

Static Pressure (+/-) -j-d ' 2.Q 

Probe/Pitot Number ^j/l^S"' <ZL 

Pltot Coerncieut O • g 

Filler Box No. ^ 

Meter Box No. /fo^/i? <r»<7 

Orince Coefficient (Y) 7^7"? 

Delta H @ e?.Q*V? 

Nonlf. Slie/No. 

LEA K CHECKS In "Hg 

INITIAL VAC. / 5 In. CBbld'OC'l 

MID VAC.

 1 lu. CF M 

FINAL VAC. ~7 In. cniQtQO) 

INIT. PITOT FINAL PITOT 

FILTE R DAT A 

\Sb\ XAD Thermocouple ID; ^e/ySi 

Imp Outlet TC ID: C^T-^l 

•NUMByu I TAKE ; 

lMlljiGlRVO l S 

• INIT, I . FINAL.. 

/G>0 TTT 

TTo~ 

J. 

SIL1CAGEL 

RlNSE. 

4-

Orsat 

G-Si //. 

S I 

SOii 

IL 

Final Purge Rate 

Final PH r 

SAMPL E 

POINT 

r*r r 

J1MK 

VELOCITY 

HEAD 

Old] 111 1ft 

ORIFICE 

MUHUO l 

Drlli'l, In >TC 

KiWi M n i It 

,(JL!'Mr 

w KTACK 

TEMPERATUR E READINGS . ° F 

PROS E OVEN 

OKI WU 

MODULE IMP IN 

POMP 

VACUUM 

..ill * 

COMMENTS 

O y ~T7o 1p} 7. 0/?.?- J7U WT MA. <7T L 

a . Q7YT -cr 

I T ML 

30. QTT7 4 

Hi. 5HX S 3. 9 

III . I L Ml LL. 

r;0 L MS ILL M l 

uo 2 . 

10 s2_ lob"?'" TTT ZL X<5 

5L, 0 - >y s: ZLLL 10 ft 

j t If 

•15 41 TTTT 

)0& 

1*0 -14-

LL 

z n 
APPENDIX B 

WASTE FEED AND OPERATING CONDITIONS 

C:\Documents and Seffingstatoo!Me\My Documents\Onyx\0903 teslingranpc 0903 dauAAppendix Coveis.doc 

January 2004 
Onyx Environmental Services - Sauget, IL 

Unit 2 and Unit 4 Process Operating Data 

ll 

Unit 4 • / \l .„ Unit 2 

Sept. 2003 - "' Tp ^ 

>° ^ 

Sept. 2003 

1 

Units R1C1 R2C1 R3C1 Average R1C2 R2C2 R3C2 Average R1 R2 R3 Average 

Pumpable Waste Ibs/hr 4,259 4,270 4,256 4,262 4,245 4,051 4,269 4,188 3,865 3,823 3,838 3,842 

Total Waste Ibs/hr 14,675 15,553 14,179 14,802 14,464 14,902 14,687 14,684 4,662 4,787 4,860 4,770 

Stackflow XI aVm 43.4 43.9 44.3 43.9 43.2 43.4 43.6 43.4 15.4 15.6 15.6 15.5 

PCC Temp Deg F 1,517 1,497 1,506 1,507 1,516 1,515 1,497 1.509 1,668 1,659 1,649 1,659 

SCC Temp - Deg F 1,887- 1,883 1,889 1,886 1,891 1,892 1,885 1,889 1,851 1,849 1,872 1,857 

B.H 425 . tnletTemp Deg F 434 439 432 435 436 439 436 437 425 425 425 425 

LVM Ibs/hr 48 49 48 48 44 47 49 47 44 41 48 44 

SVM 67" " Ibs/hr 111 111 128 117 118 128 116 12JU-. 61 70 71 67" " 

— — 

Mercury Ibs/hr 0.056 0.054 0.054 f 0.055 , ) 0.173 0.193 0.192 { 0.186 ^ 0.00035 0.00026 0.00043(' 0.00035 

Chlorine Ibs/hr 272 281 269 274 272 283 287 281 255 275 282 271 

Ash Ibs/hr 8,219 6,768 7,691 7,559 8,208 7,974 9,324 8,502 1,301 1,763 1,766 1,610 
Onyx Environmental Services - Sauget, IL 

Unit 2 Feed Data 

Unit #2 

Run #1 

Date: 09/18/03 

Test Time: 14:45 to 18:49 

P P M P P M P P M P P M P P M P P M Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 13370 0.54 14.7 0.228 9.96 0.86 33.6 0.025 3.13 822 

P C C Low Btu 500 0.5 10 0.0316 0.4 0.268 0.766 0.01 0.312 1806 

(Chromium Spike) 500 0.5 75.2 0.08 20 1 358 0.5 199000 222 

P C C Sp Fdr 500 0.5 56.5 0.0042 0.4 0.038 0.25 0.01 0.425 468 

(Chlorine Spike) 500 83.5 0.05 0.009 8.11 0.17 2.12 0.08 0.85 179 

P C C Solid Charges 500 0.5 96.7 0.162 38.3 1.36 28.3 0.09 11.4 519 

P C C Labpack Charges 

(Lead Spike) 500 0.5 65.6 0.009 639000 13.3 4.31 0.17 172 96 

(Chlorine Spike) 500 89.8 2.7 0.01 7.69 0.38 4.81 0.19 1.92 94 

S C C High Btu 13370 0.54 0.5 0.004 1 0.05 0.625 0.025 0.25 234 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 2 Feed Data 

Unit #2 

Run#1 

Date: 09/18/03 

Test Time: 14:45 to 18:49 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 10.99 4.44 120.83 0.000187 0.01 0.00 0.03 0.00 0.00 

P C C Low Btu 0.90 9.03 180.60 0.000057 0.00 0.00 0.00 0.00 0.00 

(Chromium Spike) 0.11 1.11 .166.94 0.000018 0.00 0.00 0.08 0.00 44.18 

P C C Sp Fdr 0.23 2.34 264.42 0.000002 0.00 0.00 0.00 0.00 0.00 

(Chlorine Spike) 0.09 149.47 0.09 0.000002 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.26 2.60 501.87 0.000084 0.02 0.00 0.01 0.00 0.01 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.05 0.48 62.98 0.000001 61.34 0.00 0.00 0.00 0.00 

(Chlorine Spike) 0.05 84.41 2.54 0.000001 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 3.13 1.26 1.17 0.000001 0.00 0.00 0.00 0.00 0.00 

Totals 15.81 255.13 1301.44 0.000353 61.38 0.00 0.12 0.00 44.19 

2 of 2 
Onyx Environmental Services - Sauget IL 

Unit 2 Feed Data 

Unit #2 

Run #2 

Date: 09/19/03 

Test Time: 08:30 to 11:42 

P P M P P M P P M P P M P P M P P M Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 10870 1.2 9.8 0.0716 1.75 0.463 5.65 0.025 0.732 870 

P C C Low Btu 500 0.5 23 0.0556 0.4 0.755 7.18 0.01 0.102 1824 

(Chromium Spike) 500 0.5 75 0.016 15 0.29 262 0.16 182000 223 

P C C Sp Fdr 500 0.5 74 0.0016 0.4 0.05 0.25 0.01 0.527 426 

(Chlorine Spike) 500 83.5 0.05 0.01 3.39 0.17 2.12 0.08 0.85 181 

P C C Solid Charges 500 0.5 95.7 0.137 43.6 1.1 22.4 0.1 8.99 629 

P C C Labpack Charges 

(Lead Spike) 500 0.5 65.8 0.01 639000 7.44 5 0.2 2 110 

(Chlorine Spike) 500 89.8 88.5 0.01 8.7 0.43 5.43 0.22 2.17 107 

S C C High Btu 13370 0.54 3.1 0.01 3.57 0.18 2.23 0.09 0.89 222 

Totals 

1 of 2 
Onyx Environmental Services - Sauget IL 

Unit 2 Feed Data 

Unit #2 

Run #2 

Date: 09/19/03 

Test Time: 08:30 to 11:42 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 9.46 10.44 85.26 0.000062 0.00 0.00 0.00 0.00 0.00 

P C C Low Btu 0.91 9.12 419.52 0.000101 0.00 0.00 0.01 0.00 0.00 

(Chromium Spike) 0.11 1.12 167.25 0.000004 0.00 0.00 0.06 0.00 40.59 

P C C Sp Fdr 0.21 2.13 315.24 0.000001 0.00 0.00 0.00 0.00 0.00 

(Chlorine Spike) 0.09 151.14 0.09 0.000002 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.31 3.15 601.95 0.000086 0.03 0.00 0.01 0.00 0.01 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.06 0.55 72.38 0.000001 70.29 0.00 0.00 0.00 0.00 

(Chlorine Spike) 0.05 96.09 94.70 0.000001 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 2.97 1.20 6.88 0.000002 0.00 0.00 0.00 0.00 0.00 

Totals 14.18 274.92 1763.27 0.000260 70.33 0.00 0.09 0.00 40.59 

2 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 2 Feed Data 

Unit #2 

Run #3 

Date: 09/19/03 

Test Time: 12:50 to 16:01 

PPM PPM PPM PPM PPM PPM Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

PCC High Btu 10870 1.2 7.4 0.05 3.77 0.44 2.36 0.09 0.94 990 

PCC Low Btu 500 0.5 20 0.101 3.7 0.8 4.2 0.09 0.93 1722 

(Chromium Spike) 500 0.5 75 0.016 15 0.3 299 0.17 213000 224 

PCC Sp Fdr 500 0.5 78.4 0.0016 0.4 0.02 0.25 0.01 1.39 438 

(Chlorine Spike) 500 83.5 0.05 0.01 3.57 0.18 2.23 0.09 0.89 181 

PCC Solid Charges 500 0.5 94.8 0.275 41.8 1.85 63.4 0.1 12.1 719 

PCC Labpack Charges 

(Lead Spike) 500 0.5 66.5 0.009 608000 9.99 3.83 0.1 1 116 

(Chlorine Spike) 500 89.8 67.2 0.01 8 0.4 5 0.2 2 113 

SCC High Btu 13370 0.54 1.5 0.01 4 0.2 2.5 0.1 1 180 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 2 Feed Data 

Unit #2 

Run #3 

Date: 09/19/03 

Test Time: 12:50 to 16:01 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) " (lb/hr) ' " 

Loading 

" (lb/hr) ' " 

PCC High Btu 10.76 11.88 73.26 0.000050 0.00 0.00 0.00 0.00 0.00 

PCC Low Btu 0.86 8.61 344.40 0.000174 0.01 0.00 0.01 0.00 0.00 

(Chromium Spike) 0.11 1.12 168.00 0.000004 0.00 0.00 0.07 0.00 47.71 

PCC Sp Fdr 0.22 2.19 343.39 0.000001 0.00 0.00 0.00 0.00 0.00 

(Chlorine Spike) o.os 151.14 0.09 0.000002 0.00 0.00 0.00 0.00 0.00 

PCC Solid Charges 0.36 3.60 681.61 0.000198 0.03 0.00 0.05 0.00 0.01 

PCC Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.06 0.58 77.14 0.000001 70.53 0.00 0.00 0.00 0.00 

(Chlorine Spike) 0.06 101.47 75.94 0.000001 0.00 0.00 0.00 0.00 0.00 

SCC High Btu 2.41 0.97 2.70 0.000002 0.00 0.00 0.00 0.00 0.00 

Totals 14.92 261.56 1766.53 0.000431 , 70.57 0.00 0.12 0.00 47.72 

2 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run#1 

Condition # 1 

Date: 09/16/03 

Test Time: 09:56 to 13:53 

P P M P P M P P M P P M P P M P P M Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 12030 2.14 10.3 0.052 2.18 0.825 2.76 0.025 0.25 1110 

P C C Low Btu 500 0.5 21.3 0.006 1.03 2.74 0.524 0.005 0.362 1705 

(Chromium Spike) 500 0.5 75.3 0.016 15 0.33 316 0.21 212000 226 

P C C Chlorine Spike (X-10) 2000 83.5 0.05 0.01 3.92 0.2 2.45 0.1 0.98 136 

P C C Solid Charges 500 0.5 93.9 1.19 19.7 1.4 16.7 0.1 8.68 1456 

P C C Labpack Charges 5000 0.5 

(Mercury Spike - Mode 1) 500 0.5 2.9 29800 0.2 0.01 0.125 0.005 0.442 1.64 

(Mercury Spike - Mode 2) 

(Lead Spike) 500 0.5 66.1 0.009 629000 401 5 0.2 2 176 

P C C Bulk Solids (w/hex) 1500 1.5 87.3 0.721 15.7 1.13 37.9 0.1 5.4 6948 

(Chlorine Spike) 

S C C High Btu 8660 1.29 2.2 0.0822 1.43 0.05 2.09 0.025 0.25 1003 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run#1 

Condition # 1 

Date: 09/16/03 

Test Time: 09:56 to 13:53 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 13.35 23.75 114.33 0.000058 0.00 0.00 0.00 0.00 0.00 

P C C Low Btu 0.85 8.53 363.17 0.000010 0.00 0.00 0.00 0.00 0.00 

(Chromium Spike) 0.11 1.13 170.18 0.000004 0.00 0.00 0.07 0.00 47.91 

P C C Chlorine Spike (X-10) 0.27 113.56 0.07 0.000001 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.73 7.28 1367.18 0.001733 0.03 0.00 0.02 0.00 0.01 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 1) 0.00 0.01 0.05 0.048872 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 2) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.09 0.88 116.34 0.000002 110.70 0.07 0.00 0.00 0,00 

P C C Bulk Solids (w/hex) 10.42 104.22 6065.60 0.005010 0.11 0.01 0.26 0.00 0.04 

(Chlorine Spike) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 8.69 12.94 22.07 0.000082 0.00 0.00 0.00 0.00 0.00 

Totals 34.52 272.30 8218.98 0.055771 110.85 0.09 0.37 0.00 47.96 

total SVM 110.94 48.33 total LVM 

2 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run #2 

Condition # 1 

Date: 09/16/03 

Test Time: 16:45 to 19:53 

P P M P P M P P M P P M P P M P P M Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 12030 2.14 8.1 0.0792 2.04 0.805 3.16 0.025 2.11 1110 

P C C Low Btu 500 0.5 29.4 0.0052 0.946 2.53 0.52 0.005 0.81 1710 

(Chromium Spike) 500 0.5 74.1 0.016 15 0.26 310 0.18 216000 227 

P C C Chlorine Spike (X-10) 2000 83.5 0.05 0.009 4 0.2 2.5 0.1 1 144 

P C C Solid Charges 500 0.5 95.9 0.066 15.6 0.61 2.66 0.1 7.07 1501 

P C C Labpack Charges 5000 0.5 

(Mercury Spike - Mode 1) 500 0.5 1.8 29500 0.403 0.01 0.125 0.005 0.492 1.66 

(Mercury Spike - Mode 2) 

(Lead Spike) 500 0.5 65.4 0.01 621000 6.35 4.81 0.19 1.92 179 

P C C Bulk Solids (w/hex) 1500 1.5 62.6 0.719 10.6 0.67 16.8 0.1 8.94 7062 

(Chlorine Spike) 

S C C High Btu 8660 1.29 3 0.068 1.18 0.05 1.71 0.025 0.25 1004 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run #2 

Condition # 1 

Date: 09/16/03 

Test Time: 16:45 to 19:53 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (lb/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 13.35 23.75 89.91 0.000088 0.00 0.00 0.00 0.00 0.00 

P C C Low Btu 0.86 8.55 502.74 0.000009 0.00 0.00 0.00 0.00 0.00 

(Chromium Spike) 0.11 1.14 168.21 0.000004 0.00 0.00 0.07 0.00 49.03 

P C C Chlorine Spike (X-10) 0.29 120.24 0.07 0.000001 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.75 7.51 1439.46 0.000099 0.02 0.00 0.00 0.00 0.01 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 1) 0.00 0.01 0.03 0.048970 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 2) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.09 0.90 117.07 0.000002 111.16 0.00 0.00 0.00 0.00 

P C C Bulk Solids (w/hex) 10.59 105.93 4420.81 0.005078 0.07 0.00 0.12 0.00 0.06 

(Chlorine Spike) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 8.69 12.95 30.12 ,0.000068 0.00 0.00 0.00 0.00 0.00 

Totals 34.74 280.97 6768.42 0.054318 111.27 0.01 0.20 0.00 49.11 

111.28 49.31 

2 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run #3 

Condition # 1 

Date: 09/17/03 

Test Time: 08:00 to 11:09 

... 

P P M P P M P P M P P M P P M P P M Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 12030 2.14 5.9 0.0786 1 0.742 0.625 0.025 0.25 1110 

P C C Low Btu 500 0.5 27.1 0.0138 1.44 2.71 0.882 0.005 0.05 1710 

(Chromium Spike) 500 0.5 74.4 0.016 15 0.35 307 0.25 217000 222 

P C C Chlorine Spike (X-10) 2000 83.5 0.05 0.023 3.85 0.19 2.4 0.1 0.96 135 

P C C Solid Charges 500 0.5 95.9 0.058 15.2 0.62 15.5 0.09 4.18 1555 

P C C Labpack Charges 5000 0.5 

(Mercury Spike - Mode 1) 500 0.5 0.3 29200 17 0.01 0.125 0.005 0.05 1.72 

(Mercury Spike - Mode 2) 

(Lead Spike) 500 0.5 65.9 0.01 668000 7.22 4.63 0.19 1.85 185 

P C C Bulk Solids (w/hex) 1500 1.5 78.4 0.525 668 0.96 36.6 0.1 8.31 6756 

(Chlorine Spike) 

S C C High Btu 8660 1.29 8.7 0.0934 1.38 0.065 2.09 0.025 0.25 1003 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run #3 

Condition #1 

Date: 09/17/03 

Test Time: 08:00 to 11:09 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 13.35 23.75 65.49 0.000087 0.00 0.00 0.00 0.00 0.00 

P C C Low Btu 0.86 8.55 463.41 0.000024 0.00 0.00 0.00 0.00 0.00 

(Chromium Spike) 0.11 1.11 165.17 0.000004 0.00 0.00 0.07 0.00 48.17 

P C C Chlorine Spike (X-10) 0.27 112.73 0.07 0.000003 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.78 7.78 1491.25 0.000090 0.02 0.00 0.02 0.00 0.01 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 1) 0.00 0.01 0.01 0.050224 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 2) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.09 0.93 121.92 0.000002 123.58 0.00 0.00 0.00 0.00 

P C C Bulk Solids (w/hex) 10.13 101.34 5296.70 0.003547 4.51 0.01 0.25 0.00 0.06 

(Chlorine Spike) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 8.69 12.94 87.26 0.000094 0.00 0.00 0.00 0.00 0.00 

Totals 34.28 269.13 7691.27 0.054074 128.13 0.01 0.35 0.00 48.24 

128.14 48.58 

2 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run#1 

Condition #2 

Date: 09/17/03 

Test Time: 11:45 to 15:04 

- • • • • • 

PPM PPM PPM PPM PPM PPM Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

PCC High Btu 12030 2.14 5.5 0.0688 1 0.7 1.41 0.025 0.25 1108 

PCC Low Btu 500 0.5 31 0.005 0.814 2.42 0.417 0.005 0.63 1709 

(Chromium Spike) 500 0.5 75 0.016 4 0.52 369 0.15 205000 213 

PCC Chlorine Spike (X-10) 2000 83.5 0.05 0.01 4 0.2 2.5 0.1 1 138 

PCC Solid Charges 500 0.5 96.4 0.09 17.7 0.79 10.3 0.1 6.27 1540 

PCC Labpack Charges 5000 0.5 

(Mercury Spike - Mode 1) 

(Mercury Spike - Mode 2) 500 0.5 1 30000 0.2 0.01 0.125 0.005 0.574 5.65 

(Lead Spike) 500 0.5 65.9 0.01 664000 7.8 5 0.2 2 176 

PCC Bulk Solids (w/hex) 1500 1.5 86.2 0.416 125 1.85 53.6 0.1 10.6 6786 

(Chlorine Spike) 

S CC High Btu 8660 1.29 0.7 0.0638 1 0.05 1.42 0.025 0.25 1003 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run# 1 

Condition # 2 

Date: 09/17/03 

Test Time: 11:45 to 15:04 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

PCC High Btu 13.33 23.71 60.94 0.000076 0.00 0.00 0.00 0.00 0.00 

PCC Low Btu 0.85 8.55 529.79 0.000009 0.00 0.00 0.00 0.00 0.00 

(Chromium Spike) 0.11 1.07 159.75 0.000003 0.00 0.00 0.08 0.00 43.67 

PCC Chlorine Spike (X-10) 0.28 115.23 0.07 0.000001 0.00 0.00 0.00 0.00 0.00 

PCC Solid Charges 0.77 7.70 1484.56 0.000139 0.03 0.00 0.02 0.00 0.01 

PCC Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 1) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 2) 0.00 0.03 0.06 0.169500 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.09 0.88 115.98 0.000002 116.86 0.00 0.00 0.00 0.00 

PCC Bulk Solids (w/hex) 10.18 101.79 5849.53 0.002823 0.85 0.01 0.36 0.00 0.07 

(Chlorine Spike) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

SCC High Btu 8.69 12.94 7.02 0.000064 0.00 0.00 0.00 0.00 0.00 

Totals 34.29 271.89 8207.70 0.172617 117.74 0.02 0.46 0.00 43.75 

117.76 44.21 

2 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run #2 

Condition # 2 

Date: 09/17/03 

Test Time: 15:40 to 18:49 

P P M P P M P P M P P M P P M PPM ' Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 12030 2.14 5.5 0.0514 1 0.71 0.912 0.025 0.25 880 

P C C Low Btu 500 0.5 26.6 0.01 0.685 1.99 0.446 0.005 0.432 1708 

(Chromium Spike) 500 0.5 74.3 0.016 4 0.51 372 0.1 211000 223 

P C C Chlorine Spike (X-10) 2000 83.5 0.05 0.01 4 0.2 2.5 0.1 1 144 

P C C Solid Charges 500 0.5 95.7 0.171 45.1 1.75 42.1 0.09 12.7 1520 

P C C Labpack Charges 5000 0.5 

(Mercury Spike - Mode 1) 

(Mercury Spike - Mode 2) 500 0.5 2.6 30900 0.2 0.01 0.125 0.005 0.598 6.11 

(Lead Spike) 500 0.5 66 0.011 666000 6.7 6.25 0.25 2.5 190 

P C C Bulk Solids (w/hex) 1500 1.5 76.2 0.54 175 4.4 218 0.1 23.1 7506 

(Chlorine Spike) 

S C C High Btu 8660 1.29 0.6 0.0634 1 0.052 1.09 0.025 0.25 1001 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run # 2 

Condition # 2 

Date: 09/17/03 

Test Time: 15:40 to 18:49 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 10.59 18.83 48.40 0.000045 0.00 0.00 0.00 0.00 0.00 

P C C Low Btu 0.85 8.54 454.33 0.000017 0.00 0.00 0.00 . 0.00 0.00 

(Chromium Spike) 0.11 1.12 165.69 0.000004 0.00 0.00 0.08 0.00 47.05 

P C C Chlorine Spike (X-10) 0.29 120.24 0.07 0.000001 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.76 7.60 1454.64 0.000260 0.07 0.00 0.06 0.00 0.02 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 1) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 2) 0.00 0.03 0.16 0.188799 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.10 0.95 125.40 0.000002 126.54 0.00 0.00 0.00 0.00 

P C C Bulk Solids (w/hex) 11.26 112.59 5719.57 0.004053 1.31 0.03 1.64 0.00 0.17 

(Chlorine Spike) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 8.67 12.91 6.01 0.000063 0.00 0.00 0.00 0.00 0.00 

Totals 32.63 282.81 7974.27 0.193245 127.93 0.04 1.79 0.00 47.25 

127.97 49.04 

2 of 2 
Onyx Environmental Services - Sauget, SL 

Unit 4 Feed Data 

Unit #4 

Run # 3 

Condition #2 

Date: 09/18/03 

Test Time: 08:10 to 11:18 

P P M P P M P P M P P M P P M P P M Feedrate 

Waste Type Btu/lb %Chlorine %Ash Mercury Lead Cadmium Arsenic Beryllium Chromium (Ib/hr) 

P C C High Btu 12030 2.14 16.9 0.195 1 1.06 0.625 0.025 0.65 1109 

• 

P C C Low Btu 500 0.5 27.2 0.0363 0.97 2.3 0.826 0.005 0.978 1711 

(Chromium Spike) 500 0.5 74.1 0.167 15 0.51 325 0.1 216000 226 

P C C Chlorine Spike (X-10) 2000 83.5 0.05 0.009 3.39 0.17 2.12 0.08 0.85 139 

P C C Solid Charges 500 0.5 93.8 0.261 56.2 2.06 42.5 0.09 10.6 1546 

P C C Labpack Charges 5000 0.5 

1546 

(Mercury Spike - Mode 1) 

(Mercury Spike - Mode 2) 500 0.5 0.05 31000 0.2 0.01 0.125 0.005 0.555 6.05 

(Lead Spike) 500 0.5 66.8 0.026 617000 0.45 5.68 0.23 2.27 188 

P C C Bulk Solids (w/hex) 1500 1.5 88.7 0.529 56.1 1.1 64.3 0.09 10.8 7722 

(Chlorine Spike) 

S C C High Btu 8660 1.29 7.8 0.079 1.29 0.078 1.85 0.025 0.37 1003 

Totals 

1 of 2 
Onyx Environmental Services - Sauget, IL 

Unit 4 Feed Data 

Unit #4 

Run #3 

Condition # 2 

Date: 09/18/03 

Test Time: 08:10 to 11:18 

Thermal Chlorine Ash Mercury Lead Cadmium Arsenic Beryllium Chromium 

Loading Loading Loading Loading Loading Loading Loading Loading Loading 

Waste Type (MMBtu/hr) (Ib/hr) (Ib/hr) (Ib/hr) (lb/hr) (Ib/hr) (Ib/hr) (Ib/hr) (Ib/hr) 

P C C High Btu 13.34 23.73 187.42 0.000216 0.00 0.00 0.00 0.00 0.00 

P C C Low Btu 0.86 8.56 465.39 0.000062 0.00 0.00 0.00 0.00 0.00 

(Chromium Spike) 0.11 1.13 167.47 0.000038 0.00 0.00 0.07 0.00 48.82 

P C C Chlorine Spike (X-10) 0.28 116.07 0.07 0.000001 0.00 0.00 0.00 0.00 0.00 

P C C Solid Charges 0.77 7.73 1450.15 0.000404 0.09 0.00 0.07 0.00 0.02 

P C C Labpack Charges 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 1) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

(Mercury Spike - Mode 2) 0.00 0.03 0.00 0.187550 0.00 0.00 0.00 0.00 0.00 

(Lead Spike) 0.09 0.94 125.58 0.000005 116.00 0.00 0.00 0.00 0,00 

P C C Bulk Solids (w/hex) 11.58 115.83 6849.41 0.004085 0.43 0.01 0.50 0.00 0.08 

(Chlorine Spike) 0.00 0.00 0.00 0.000000 0.00 0.00 0.00 0.00 0.00 

S C C High Btu 8.69 12.94 78.23 0.000079 0.00 0.00 0.00 0.00 0.00 

Totals 35.73 286.95 9323.73 0.192440 116.52 0.02 0.64 0.00 48.92 

| 116.54 49.56 

2 of 2 
APPENDIX C 

FIELD EQUIPMENT CALIBRATION FORMS 
ANALYTICAL DATA REPORTS 

C:\Doamrents and SeoingsVMi 

W W * r i * ^ 0903 datauppe* Covers.tJoc 

January 2004 
V