### BOBBY JINDAL GOVERNOR

# ~tate 

# of JI..ouisiana DEPARTMENT OFENVIRONMENTAL QUALITY 

## ENVIRONMENTAL SERVICES Certified Mail No.: 7005 1820 0002 2092 4244

Mr. Charles Cost Plant Manager Caluniet Lubricants Company, L.P. P.O. Box 97 Cotton Valley, LA 71018 PEGGY 

### M. HATCH SECRETARY.



### Agency Interest No.: 312 ActivityNo.: PER20!20002

RE: Operating permit modification, Calumet Cotton Valley, Calumet Lubricants Company L.P., Cotton Valley, Webster Parish, Louisiana DearMr. Charles Cost: This is to inform you that the permit modification for the above referenced facility has been approved under LAC 33:III.501. The permit is both a state preconstruction and Part 70 Operating Penni!. The submittal was approved on the basis ofthe emissions reported and the approval in no way guarantees the design scheme presented will be capable of controlling the emissions as to the types and quantities stated. A new application must be submitted ifthe reported emissions are exceeded after operations begin. The synopsis, data sheets and conditions are attached herewith. It 

### will be considered a violation ofthe permit ifall proposed control measures and/or equipment are not installed and properly operated and maintained as specified in the application. Operation ofthis facility is hereby authorized under the terms and conditions ofthis permit. This authorization shall expire at midnight on the**~** 

### of January , 2015, unlessa timely and complete renewal application has been submitted six months prior to expiration. Terms and conditions ofthis permit shall remain in effect until such time as the permitting authority takes final action on the application for permit renewal. The permit number and agency interest numbercited above shouldbereferenced in future correspondenceregarding this facility. Please be advised that pursuant to provisions ofthe Environmental.Quality Act and the Administrative Procedure Act, the Department may initiate review of a· permit during its term. However, before it takes any action to modify, suspend or revoke a permit, the Department shall, in accordance with applicable statutes and regulations, notify the permittee by mail ofthe facts or operational conduct that warrant the intended action and provide the permittee with the opportunity to demonstrate compliance with all lawful requirements for the retention of the effective permit. Done this__j_2__day

# o$~ PerrnitNo.: 3080-00010-V6

# ::J?t~ Sam L. Philhps Assistant Secretary SLP:fjh

c: EPA Region VI '2012.

PoSt Office Box 4313 • Baton**Roug~.** Louisiana 70821-4313 • Phone 225-219-3181 • Fax 225-219-3309 WW\\'.deq.louislana.gov

## AIR PERMIT BRIEFING SHEET PERMITS DIVISION LOUISIANA DEPARTMENT OFENVIRONMENTAL QUALITY

I. BACKGROUND Calumet Cotton Valley Agency Interest 

## No.: 312 Calumet Lubricants Company,L.P. Cotton Valley, Webster Parish, Louisiana 

# '

Calumet Cotton Valley Facility has been in operation prior to 1969. The facility Permit No. 3080-00010-VS was issued January 8, 2010. The site is located at 1756 Old Highway 7 in Cotton Valley, Louisiana.

II. ORIGIN 

## A permit application and Emission Inventory Questionnaire (EIQ) dated July 27, 2012, were received requesting a Part 70 Operating Permit Modification.

III. DESCRIPTION 

## Calumet Cotton Valley Facility is a small refinery which uses atmospheric distillation and hydrotreating to refine "sweet" local crude oil into various petroleum products, including but not limited to aliphatic and hydrotreated low aromatic solvents, light straight run, and diesel. The facility is primarily dedicated to manufacturing aliphatic solvents. The product range ofthe aliphatic solvents includes hydrotreating low aromatic solvents as well as conventionally refined products. These specialty solvents find applications in a wide variety ofmarkets including paints and coating, inks, extraction, and mining. The proposed modifications ofthe facility are as follows: I. 

## Address and satisfy Condition 62 of the Consent Decree [SA-MM-10-0090], effective January 31, 2012; 2. Revise S02 

## emissions for the heaters that are now subject to 40 CFR 60 Subpart J

## in accordance with the Consent Decree [SA-MM-10-0090]; and 3. Incorporate the case-by-case dated December II, 2012 into the permit; Increase the loading throughput ofthe existing product known as 50 Fuel.

2

## IV. AIR PERMIT BRIEFING SHEET PERMITS DIVISION LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana Estimated emissions in tons per year are as follows:

Pollutant Before After PM1o 25.98 25.98 

# so2 31.43 42.02 NOx 127.58 127.58 

# co 139.07 139.07 

# voc. 428.53 428.95 

# •voc LAC 33:111 Chapter 51 Toxic Air Pollutants (TAPs): Pollutant Before After Benzene 6.17 6.17 Cumene <0.01 <0.01. Ethylbenzene 1.23 1.23 Lead Compounds <0.01 <0.01 Methyl Isobutyl Ketone <0.01 <0.01 Naphthalene <0.01 <0.01 Toluene 5.44 5.44 Xylene (mixed Isomers) 6.85 6.97 n-Hexane 4.72 4.72 Total 24.45 24.57 TYPE OF REVIEW Change

+I0.59

+0.42

Change

+0.12
+0.12

This application was reviewed for compliance with the Louisiana Part 70 operating permit program, Louisiana Air Quality Regulations, NSPS, and NESHAP. Prevention of Significant Deterioration does not apply. The refinery is a minor source oftoxic airpollutants.

3

### AIR PERMIT BRIEFING SHEET. PERMITS DIVISION LOUISIANA DEPARTMENT OFENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, WebsterParish, Louisiana V. Credible Evidence Notwithstanding any other provisions ofany applicable rule or regulation or requirement of this permit that state specific 'methods that may be used to assess compliance with applicable requirements, pursuant to 40 CFR Part 70 and EPA's Credible Evidence Rule, 62 Fed. Reg. 8314 (Feb
.. 24, 1997), any credible evidence or information relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed shall be considered for purposes ofTitle V compliance certifications. Furthermore, for purposes of establishing whether or not a person has violated or is in violation ofany emissions limitation or standard or permit condition, nothing in this permit shall preclude the use, including the exclusive use, by any person ofany such credible evidence or information. VI. Public Notice Public notice is not required for minor modification to a Part 70 operating permit.

VII. General Condition XVII Activities: Activity Frequency 

# I VOC Emissions TPY Sample Collection 150/day 2.11 Tank Gauging/Sampling 45 tanks/month 1.30 Equipment Startup/Shutdown 200 times/yr 1.46 Pump Maintenance 400 times/yr 0.29 Changing Fihers 200 times/yr 2.92 Pump Evacuation/Priming 16,425 times/yr 4.80 Misc. Equipment Maintenance & 

### Preparation 150 times/yr 0.44

4

## AIR PERMIT BRIEFING SHEET PERMITS DIVISION LOUISIANA DEPARTMENT OFENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana IX. InsignificantActivities:

IDNo.: Description Capacity

Totes Portable Totes (number varies) <250 gals Tank ProcessTreatment Chemical 1,000 gals Tank Process Treatment Chemical 1,000 gals Tank Process Treatment Chemical 1,000 gals Tank Process Treatment Chemical 1,000 gals Tank Process Treatment Chemical 1,350 gals Tank Process Treatment Chemical 1,350 gals Tank Diesel StorageTank 1,000 gals Tank Diesel Storage Tank 1,000 gals Tank Diesel Storage Tank 9,000 gals Tank Diesel Storage Tank 500 gals Laboratory Equipment NA Truck Loading Dock Sump NA North Separator 11,340 gals Citation LAC 33:111.501.8.5.A.2 LAC 33:111.501.8.5.A.3 LAC 33:111.501.8.5.A.3 LAC 33:111.501.B.5.A.3 LAC 33:111.501.8.5.A.3 LAC 33:111.501.8.5.A.3 LAC 33:111.501B.5.A.3 LAC 33:111.501.B.5.A.3 LAC 33:111.5018.5.A.3 LAC 33:111.501B.5.A.3 LAC 33:111.501.8.5.A.3 LAC 33:111.5018.5.A.6 LAC 33:111.5018.5.0 LAC 33:111.501.8.5.0

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 

## 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana X. Applicable Louisiana and Federal Air Quality Requirements LAC 33:111 Chapter

IDNo. Description 

### 5
.. 9 II 13 

### IS 2103 2107 2109 2111 2113 2115 2121 UNFOOOI 

### Entire Facility I I I I I 3 EQTOI9 HFR Storage Tank EQT020 10 • 500 BBL HFR Storage Tank 3 IO_QT021 II

- 500 BBL HFR StorageTank 3 EQT022 14 • 2,000 BBL VFR Storage Tank' 3 EQT023 15-2,000 BBL VFR Storage Tank 3 EQT024 16- 2,000 BBL VFR Storage Tank 3 

### EQT025 17- 2,000 BBL VFR Storage Tank 3 

### EQT026 18- 2,000 BBL VFR Storage Tank 3 

### IO_QT027 19 • 2,000 BBL VFR Storage Tank 3 

### EQT028

- 500 BBL HFR Storage Tank 3 

### EQT029 0- 2,000 BBL VFR Storage Tank 3 

### EQT030 I

- 2,000 BBL VFR Storage Tank 3 EQT031 2- 5,000 BBL VFR Storage Tank 3 EQT032 3

- 5,000 BBL VFR Storage Tank 3 EQT033 4 • 5,000 BBL VFR Storage Tank 3 EQT034 5

- 5,000 BBL VFR Storage Tank 3 

### EQT035 6- 5,000 BBL VFR Storage Tank 3 EQT036 7- 5,000 BBL VFR Storage Tank 3, EQT037 8- 6,000 BBL VFR StorageTank 3 EQT038 9- 50,000 BBL IFR Storage Tank I EQT039 • 500 BBL HFR Storage Tank 3

·- 

### 6 2147 29* 51* 56 59* I I I

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Colton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Colton Valley, Webster Parish, Louisiana 

# pc Applicable Louisiana and Federal Air Quality Requirements LAC 33:111 Chapter

ID !'"o. Dcscriplion 

## s• 9 II 13 

### 15 ltOJ 2107 2109 2111 2113 2115 2121 'QT040 0 • 6.500 BBL VFR Storage Tank 3 

### lf:QT041 I • 6,500 BBL VFR Storage Tank 3

### ~QT042 2 • 20.000 BBL VfR Storage Tank 3

### ~QT043 3 - 20.000 BBL IFR Storage Tank I

### ~QT044 4- 10,000 BBL VFR Storage Tank 3 

### lf:QT045 

### 5- 10.000 BBL VFR Storage Tank 3 

### IEQT046

- 500 BBL HFR Storage Tank 3 

### EQT047 7- 80,000 BBL IFR Storage Tank I IEOT048 • 500 BBL HFR Storage Tank 3**~QT049** 

### 4 - I0.000 BBL IFR sw·rage Tank I lf:QT050 

### 5- I0,000 BBL IFR Storage Tank I "'QT051 6- 10,000 BBL IFR Storage Tank I

### ~QT052 7- 80.000 BflL VFR Storage Tank 3 

### IEOT053 8 • 500 BBL llfR Storage Tank 3 

### IEOT054 • 500 BilL HfR Storage Tank 3 

### fsQT055 0 • 5,000 BBL IFR Storage Tank I IEOT056 6 • I0.000 BBL VFR Storage Tank 3 

### f.QT057 7- 10,000 BBL VFR Storage Tank 3**~QT058** 

### 9-700 BBL HFR StorageTank 3 

### );QT059 • 500 BBL HFR Storage Tank 3 

### EQT060 I -900 BBL HFR Storage Tank 3 

### .QT061 

## t72- 5.500 BBL VFR Storage Tank 3

---- 

### 7 2147 29· 

### sJ• S6 

### 59•

- - --

## LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY 

## CalumetCotton Valley Agency InterestNo.: 312 Calumet Lubricants Company,L.P. Cotton Valley, WebsterParish, Louisiana 

# IX· Applicable Louisiana and FederalAirQuality Requirements LAC 33:111 Chapter

IDNo. loescription 

## s'" 9 II 13 IS 2103 2107 2109 2111 2113**~QT062 ~3**  • 5,000 BBL VFR Storage Tank 3**~QT063 ~6**  • 10,000 BBL VFR Storage Tank 3

### ~QT064**~9** • 5,500 BBL VFR Storage Tank 3

### ~QT065 8 • 500 BBL HFR Storage Tank 

### , 3**~QT066** 

# r·500 BBL HFR Storage Tank 3

### ~QT067**~-1401** ·No. I Boiler I I I

### ~QT068**~-1402** ·No.2 Boiler I I I**~QT069 ~D**  ·BlueDrum

### ~QT070**~T-** 

### Cooling Tower**~QT071** 

# FL2 ·Flare 

# - I I I**~QT072** 

### fp - Emergency Firewater Pumps**~QT073** pEN- Backup Generator I I I

### ~QT074**~-101-** 100 Crude Unit Process Heater I I I**~QT075 ~-201A-**  1100 Crude Unit Process Heater I I I**~QT076** )i-202

- Hot Oil Process HeaterNo. I I I I

### ~QT077 H-203 -Hot Oil Process HeaterNo. 2 I I I

### ~QT078 H-204- Solvents Unit Heater I I I EQT079 

## H.:.zos - Hydrotreater Heater I I I EQT080 H-30I -No. I Hydrotreater Heater I I I EQT081 H-601 -Solvent Train Process Heater I I I /'QT082 l"f-602/1 000- Utility Fractionator Process

### ~eater I I I 

### 8 2115 2121

3 3

3 3 3 3 3 3 3 3 3 2147 29* 

## st• 56 59*

--

## LOUISIANA DEPARTMENTOF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana**~-** 

### Applicable Louisiana and Federal Air Quality Requirements I.AC JJ:IIJ Chapter IDNo. !Description 

## s• 9 II 

### 13 IS 

### 2103 2107 2109 2111 2113 2115 2121**~QT083** 

### IJ-i-701 -700 Unit Process Heater I I I 3**~QT084** lfi-90I -Hydrogen Plant Reformer I I I 3 FQT085 f.-0

- Loading Operations I I f'QT086

### ~~~-Air Dryer (OOS) I I I 3 EQT087 

# fww- Wastewater Emissions · 2 )'UG002 

### tFE ·Fugitive Emissions I I FUGOOJ rt-JR- Unpaved Road Emissions £QT088 

### IA -Pressurized Storage Tank I EQT089**~7** -Pressurized Storage Tank I EQT090**~8** -Pressurized Storage Tank I EQT091**~9** -Pressurized Storage Tank I FQT092

### ~0 

### -Pressuri7...cd Storage Tank I "'QT093

### ~I -Pressurized Storage Tank I**~QT094 ~4**  -Pressurized Storage Tank I**~QT095 ~6**  -Pressuril..Cd Stora.ge Tank I EQT096 170 -Pressurized Storage Tank I EQT097 

### 12 -Pressurized Storage Tank I .QT098 

### 2 -Pressurized Storage Tank I**~QT099** 

### 43 -Pressuri7.cd Storage Tank I -QTtOO 

### 5 -Pressuri7.ed Storage Tank I EQTIOI 

### 9 -Pressurized Storage Tank I EQTJ02 

### 62 -Pressurized Storage Tank I 

### 9 2147 29· SJ• 

### 56 59•

## LOillSIANA DEPARTMENT OFENVIRONMENTAL QUALITY Calumet Cotton Valley Agency InterestNo.: 312 CalumetLubricants Company, L.P. Cotton Valley, WebsterParish,Louisiana · 

# IX· Applicable Louisiana and FederalAir QualityRequirements LAC 33:III Chapter

IDNo. Descriotion 

## s• 9 II 13 15 2103 2107 2109 2111 2113 EQT103 

### 3 -Pressurized Storage Tank I cQTI04 

### 4 -Pressurized Storage Tank I. EQTIOS 5 -Pressurized Storage Tank I 1:.QTI06 

### 8 -Pressurized Storage Tank I**~;,QTI07** 

### OPE- Dual Phase Extraction System EQT108 OPE OWS Dual Phase Extraction System 2 Oil/Water Separator


### • The regulations indicated aboye are State Only regulations. 2115 2121 2147 29* 51* 56 59*

• All I.;AC 33:III Chapter 5 citations are federally enforceable including LAC 33:111.50l.C.6 citations, except when the requirement found in the "Specific

### Requireme~t~" report specifically states that the regulation is State Only.


## KEY TO MATRIX -The regulations have applicable requirements which apply to this particularemission source. -Theemission source·may have an exemptiOn from control stated in the regulation. The emission source rimy not have to be coiltrolled but may have monitoring,

recordkeeping, orreporting requirements. ' , 2 -The regulations have applicable requirements which apply to this particular emission source but the source is currently exempt from these requirements due to meeting a specific criteria, such as it has not been constructed, modified orreconstructed since the regulations have been in place. Ifthe specific criteria changes the source will have to comply at a future date. 3 -Theregulations apply to this general type ofemission source (i.e. vents, furnaces, towers, and fugitives) butdo not apply to thiS particularemission source. Blank- Theregulations clearly do not app!Y_!Q_1t_lis type ofemission source.



### 10

### -------------------.------------------



### LOUISIANA DEPARTMEJ\'T OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana X. Applicable Louisiana and Federal Air Quality Requirements
:'iSPS 40 CFR 60 1D No. Description A 

### ll lla llb llc K Ka Kb J 

### GGG UNFOOOI :ntire Facility 

### I I EQT019 

### HFR Storage Tank IEQT020 10- 500 

### flBL HFR Storage Tank 

### 3 3 3 IEQT021 

### II

- 500 

### BBL HFR Storage Tank 

### 3 3 3 !EOT022 14- 2,000 

### BBL VFR Storage Tank 

### 3 3 3 

### IEQT023 15

- 2,000 

### BBL VFR Storage Tank 3 3 

### 3 'QT024 16-2.000 

### BilL VFR Storage Tank 3 3 3 IEQT025 17- 2,000 

### BBL VFR Storage Tank 3 J 3 

### "'QT026 18- 2,000 

### BBL VFR Storage Tank 3 

### 3 3 i"QT027 19- 2,000 

### BBL VFR Storage Tank 3 3 3 

### IEQT028**~-** 

### 500 

### BBL HFR Storage Tank 3 3 3 IEQT029**~0-** 

### 2,000 

### BBL VFR StorageTank 3 3 3 

### IEQT030**~I** 

### - 2,000 

### BBL VFR StorageTank 3 3 3 IEQT031**~2-** 

### 5,000 

### BBL VFR Storage Tank 3 3 3 IEQT032 123

- 5,000 

### BRL VFR Storage Tank 3 3 3 lr,QT033 124- 5,000 

### BBL VFR Storage Tank 

### 3 3 

### 3 i"QT034**~5** - 5,000 

### BBL VFR Storage Tank 

### 3 3 3 

### IEQT035**~6-** 

### 5.000 

### BRL VFR Storage Tank 3 3 

### 3 IEQT036**~7-** 

### 5,000 

### BRL VFR Storage Tank 3 3 3 "'QT037 128**~** 

### 6,000 

### BBL VFR StorageTank 

### 3 

### I 

### 11

/ 

### St:SHAP 40CFR61 000 

### A**~t** FF 

### I I 

### I



# . St:SHAP 40 40 40 CFR 63 i"GG O'R CFR A 

## cc 0 

### lc;c; 64 82 2 

### 3



# I**--~---~-~--------------------------**



## LOUISIANA DEPARTMENT OFENVIRONMENTAL QUALITY Calumet Cotton Valley Agency InterestNo.: 312 Calumet Lubricants Company, L.P. Cotton Valley, WebsterParish,Louisiana**~-** 

## Applicable Louisiana and Federal Air Quality Requirements
NSPS 40 CFR60 IDNo. lnescription A 

### D Da Db De K Ka Kb J 

### GGG !EQT038**~9-** 

### 50,000 BBL IFR Storage Tank I !EOT039 p - 500 BBL HFR StorageTank 3 3 '3 

### !EQT040**~0-** 

### 6,500 BBL VFR Storage Tank 3 

### I IEQT041**~I** 

### - 6,500 BBL VFR Storage Tank 3 3 3 

### !EQT042**~2-** 

### 20,000 BBL VFR Storage Tank t IEQT043**~3** 

### - 20,000 BBL IFR Storage Tank t IEQT044**~4-** 

### 10,000 BBL VFR Storage Tank 3 3 3 

### !EOT045 p5- 10,000 BBL VFR Storage Tank 3 3 3 

### IEQT046**~-** 

### 500 BBL HFR StorageTank 3 

### 3 3 

### IEQT047**~7-** 

### 80,000 BBL IFR Storage Tank t !EQT048**~** 

### - 500 BBL HFR StorageTank 3 3 

### 3 !J'QT049**~4-** 

### 10,000 BBL IFR Storage Tank I IEQT050**~5-** 

### 10,000 BBL IFR Storage Tank I EQT051**~6-** 

### I0,000 BBL IFR Storage T-ank I [EQT052**~7-** 

### 80,000 BBL VFR Storage Tank 3 3 3 !EQT053**~8-** 

### 500 BBL HFR Storage Tank 3 3 3 

### IEQT054**~-** 

### 500 BBL HFR StorageTank 3 3 3 

### IEQT055**~0-** 

### 5,000 BBL IFR Storage Tank I [EQT056**~6-** 

### 10,000 BBL VFR StorageTank 3 

### I [EQT057
.**~7-** 

### 10,000 BBL**\fF~Storage** 

### Tank**~3** 

### I

---- 

### 12 NESHAP 40 CFR 61 

## looo A M 

### FF



### - NESHAP 40 CFR63**~GG** A 

## cc 0 k;G 40 40 CFR CFR

64 

### 82



# .

# •·

LOUISIAl"JA DEPART;\1ENT OF ENVIRONI\1ENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parisb, Louisiana X. Applicable Louisiana and Federal Air Quality Requirements NESIIAP 

### :-;sps 40 CFR 60 40 CFR 61 

### ID No. 

### Description A ll 

### Da Db De K Ka Kb J 

### CGG

# looo A**~I** FF EQT058 69 • 700 BBL HFR Storage Tank 3 3 3 'QT059 • 500 BBL HFR Storage Tank 3 3 3 .QT060 71 • 900 BBL HFR Storage Tank 3 3 3 .QT061 

### 172 • 5,500 BBl. VFR Storage Tank 3 I cQT062**~3** • 5,000 BilL Vf'R Storage Tank 3 I iQT063 76 • 10,000 IIBL VFR Storage Tank 3 I**~QT064** 79 • 5,500 BBL VFR Storage Tank 3 I EQT065 8 • 500 BBL HFR Storage Tank 3 3 3 'QT066 9 • 500 BilL HFR StorageTank 3 3 3 cQT067 1!-1401 ·No. I Boiler 3 3 3 3 I '0T068 B-1402. No.2 Boiler 3 3 3 3 I EQT069 RD -Blue Drum 3 I £QT070 CT- CoolingTower oQT07I 

### FL2- Flare I ·QT072 

### FP- Emergency Firewater Pumps EQT073 GEN- Backup Generator ·QT074 1·10I • I00 Crude Unit Process Heater 3 3 3 3 I iQT075 H-201A- 1100 Crude L:nit Process Heater I 'QT076 

### H-202- Hot Oil Process Heater**~o.** 

### 1 3 3 

# I 3 3 I EQT077 H-203 -Hot Oil Process Heater No.2 

# I I I 

### 13 NESIIAP 40 40 400"R63 

### GGG CFR CFR A 

## cc Q 

### GG 64 

### 82

3 

### 2

## LOillSIANA DEPARTMENT OFENVIRONMENTALQUALITY CalumetCotton Valley Agency InterestNo.: 312 CalumetLubricants Company, L.P. 

## Cotton Valley, WebsterParish, Louisiana 

# IX· Applicable Louisiana and FederalAir QualityRequirements
NSPS 40 CFR60 ID No. Description 

### A 

### D Da Db De K Ka Kb J 

### GGG EQT078 

### IH-204 - Solvents Unit Heater 3 3 3 3

. I 

### EQT079 

### IH-205 - Hydrotreater Heater 3 3 3 3 I 

### EQT080 IJ-I-301- 

### No. 1 Hydrotreater Heater 

### 3 3 3 3 I 

### loQTOSI H-60I -Solvent Train Process Heater 

### I EQT082 H-602/1000- Utility Fractionator Process 

### 3 3 3 3 I Heater-

- 

### EQT083 H-701 -700 Unil Process Heater 3 3 3 3 I EQT084 H-90I -Hydrogen Plant Reformer 3 3 3 3 I EQT085 LO

- LoadingOperations EQT086 H-Air Dryer (OOS) 3 3 3 3 3 EQT087 

### WW- Wastewater Emissions · FUG002 

### E - Fugitive Emissions I FUG003 UR- Unpaved Road Emissions**~QT088** 

### lA -Pressurized Storage Tank EQT089 

### 7 -Pressurized Storage Tank EQT090 

### 8 -Pressurized Storage Tank

. 

### EQT091 

### 9 -Pressurized Storage Tank EQT092 

### 0 -Pressurized Storage Tank IoQT093 

### 1-Pressurized Storage Tank EQT094 

### 4 -Pressurized Storage Tank


### 14 NESHAP 40 CFR61 

### IQQQ A M 

### FF

3 I NESHAP 40 40 40 CFR63 

### Q

# ~gG CFR CFR A 

## cc 64 82

.

.

2 2 

### I

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana 

# pc Applicable Louisiana and Federal Air Quality Requirements**~SPS** 40 CFR 60

ID No. 

### Dtscription ·A D Da Db De K Ka Kb J 

### GGG IEQT095 6 -Pressurized Storage Tank

### ~QT096 

### 0 -Pressurized Storage Tank IEQT097 

### 12 -Pressurized Storage Tank IEOT098 

### 2 -Pressurized Storage Tank I"QT099**~3** -Pressurized StoragC Tank lr.QTIOO**~5** -Pressurized Storage Tank · ii;QTIOI**~9** -Pressurized Stomge Tank**~QTI02 ~2**  -Pressurized Storage Tank lEOTIOJ p3 -Pressurized Storage Tank**~QT104** 

### ts4 -Pressurized Storage Tank i"QT105**~5** 

### -Pressurized Storage Tank !EOTI06

### ~8 

### -Pressurized Storage Tank IEOT 107 

### loPE - Dual Phase Extraction System IEOT 108 fDPE OWS- Dual Phase Extraction System Oil/Water Separator



## 15 NESIIAP 40 CFR61 QQQ A M FF

3 I NESHAP 40 40 40 CFR 63 .GG CFR CFR A 

## cc Q 

### lr;c; 64 

### 82



# I

3

## LOUISIANADEPARTMENT OFENVIRONMENTAL QUALITY

KEY TO MATRIX CalumetCotton Valley Agency InterestNo,: 312 CalumetLubricants Company, L.P. Cotton Valley, WebsterParish, Louisiana

-Theregulations have applicable requirements which apply to this particular emission source. -The emission source may have an exemption from control stated in the regulation. The emission source may not have to be controlled but may have monitoring,

recordkeeping, or reporting requirements. 2 -The regulations have applicable requirements which apply to this particularemission source but the source is currently exempt from these requirements due to meeting a specific criteria, such as it has not been constructed, modified or reconstructed since the regulations have been in place. Ifthe specific criteria changes the source wi

### II have to comply at a future date. 3 -The**reg~Jations** 

### apply to this general type ofemission source (i.e. vents, furnaces, towers. and fugitives) but do not appl)t to this particularemission source. Blank- The**~ulations** 

### clearly do not apply to thistype ofemission source.



### 16

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana XI. Explanation for Exemption Status or Non-Applicability ofa Source

DNo: Requirement Notes ftnlire Facility Lontrol ofEmissions ofCarbon Monoxide· DOES NOT APPLY. Does not have catalyst regeneration

### ~FOOOI ,etroleum Refinery Emissions LAC 33:111.1705] jWaste Gas Disposal .OXEMPT. VOC in the waste gas less than 30,000 ppm.

LAC 33:111.2115] r'ESIIAP, Subpart CC- NESIIAPs for

### ~efincrics DOES NOT APPLY. Not a major source ofHAPs. 40 CFR 63.640] EQT028. EQT039, EQT046, EQT048, EQT054, EQT059,**~to**rage ofVolatile Organic Compounds lOES NOT APPLY. Vapor Pressure <1.5 psia. oQT065. EQT066. EQT020, EQT021, EQT053, EQT058, LAC 33:111.2103] jEQT060

FR Storage Tanks) r-:sPS Subpart K, Ka, Kb li>r Storage Tanks ilJOES l'OT APPL.Y. All tanks except 58, 69, 70, 71 were 40CFR60.110, IlOa, IlOb] 

### ·onstructed prior to 1973; Tanks 58, 69, 70, and 71- vapor**~ressure** <I

### SkPa. EQT022. EQT023, EQT024, EQT025, EQT026, EQT027,**~to**rage ofVolatile Organic Compounds poES NOT APPLY. Vapor Pressure <1.5 pSia. 1'QT029. EQT030, EQT031, EQT032, EQT033, EQT034, I.AC 33:111.2103] EQTOJS. EQT036, EQT041' EQT044, EQT045, EQT052 P'SPS Subpart K. Ka, Kb for Storage Tanks !DOES :-<OT APPLY. Constructed prior <o 1973. (FR S<orage Tanks) 40CFR60.110, I lOa, !lOb]



### 17

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 · Calumet Lubricants Company, L.P. Cotton Valley, WebsterParish, Louisiana**~1.** 

### Explanation for Exemption Status orNon-Applicability ofa Source 

# liD No: 

### Requirement Notes fEQT037, EQT040, EQT042, EQT056, EQT057.EQT061, poQT062, EQT063, EQT064**~torage** ofVolatile Organic Compounds 

### DOES NOT APPLY. Vapor Pressure <1.5 psia. [LAC 33:IIl.2103] FR Storage Tanks) NSPS Subpart K for Storage Tanks DOES NOT APPLY. Constructed prior to 1973. [40CFR60.110, IlOa, IlOb] fEQT067, EQT068 NSPS Subpart D for Boilers DOES NOT APPLY. Maximum heat input rate <250 MM

Boilers) 

### 40 CFR 60.40] BTU/hr. "SPS Subpart Da for Boilers DOES NOT APPLY. Not Electric Utility Steam Generating 40 CFR 60.40a] Units.**~SPS** 

### Subpart Db for Boilers DOES NOT APPLY. Maximum heat input rate <100 MM 40 CFR 60.40b] BTU/hr.**~SPS** 

### Subpart De for Boilers DOES NOT APPLY. Constructed prior to 1989. 40 CFR 60.40c] 

### lWaste Gas Disposal 

### pOES NOT APPLY. Do not bum a waste gas stream [LAC 33:IIl.2115]**~ontaining** 

### VOCs. 

### EQT074, EQT075, EQT076, EQT077, EQT078, · 1'/SPS Subpart D, Da, Db, De for Boilers pOESNOT APPLY. Constructed prior to applicable dates, EQT081EQT086 [40 CFR 60.40,40a,40b,40c]**~nd/or** 

### Heaters, Air Dryer) <100 MM BTU/hr, 3nd are not steam generating units 

### "SPS Subpart J 

### Standards ofPerformance for 

### !Petroleum Refineries pOES NOT APPLY. Constructed prior to 1973 or do not burn

### ~el gas. 40 CFR 60. 100] 

### jWaste Gas Disposal poESNOT APPLY. Do not bum a waste gas stream [LAC 33:1ll.2115] ontaining VOCs.



### 18

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana -- - ·-- 

### ------



### !XI. Explanation for Exemption Status or Non-Applicability ofa Source

DNo: Requirement Notes EQT079, EQT080. EQT083 NSPS Subpart D. Da. Db. De for Boilers !DOES NOT APPLY. These are no steam generating units. Heaters) 

### 40 CFR 60.40, 40a. 40b, 40c]
Waste Gas Disposal 

### pOESl'OTAPPLY. Do not bum a waste gas stream LAC 33:111.2115] Fontaining VOCs. 

### cQT084 NSPS Subpart D, Da, Db, De lor Boilers 

## poES NOT APPLY. These are not steam generating units. Hydrogen Reformer) 

### 40 CFR 60.40, 40a, 40b, 40c] Waste Gas Disposal poES NOT APPLY. Does not bum a waste gas stream 

### LAC 33:111.2115] ontaining VOCs.**~tandards** ofPerformance for Petroleum**~XEMPT.** Fuel gas stream is inherently low in sulfur content Refineries 

### 40 CFR 60. 105(a)(4)(iv)(C)]**~QT070** NESHAP, Subpart 

### Q- Chromium emissions poES NOT APPLY. Facility is not a major source ofHAPs Cooling Tower) rom Industrial Process Cooling Towers 

### pnd 40 CFR 63.402] hromium-based treatment chemicals are not used. 

### t:QT069 NSPS, Subpart • QQQ VOC Standards for )QES NOT APPLY. Facility was not constructed, Blue Drum) Petroleum Refinery Wastewater**Syst~ms** econstructed. or modified after May 4, 1987. 

### 40 CFR 60.690] NESHAP, Subpart FF- Benzene Waste !Shall comply with the requirements of40 CFR 61.343.**Opera~ions** 

### 40 CFR 61.340]



### 19 I**~-------------------------------------------------------------------------------------------------------------------------------------------------------------------------------~ ----~** 



## LOUISIANADEPARTMENT OFENVffiONMENTAL QUALITY Calumet Cotton Valley Agency InterestNo.: 312 CalumetLubricants Company, L.P. Cotton Valley, WebsterParish, Louisiana**~1.** 

## Explanation for Exemption Status or Non-Applicability ofa Source DNo: !Requirement Notes**~QT087 ~SPS,**  Subpart

- QQQ VOC Standards for pOES NOT APPLY. Facility was notconstructed, 

### Wastewater Emissions) !Petroleum Refinery Wastewater Systerns 

### econstructed. or modified after May 4, 1987. 40 CFR 60.690] 

### pii!Water·Separation fEXEMPT. Emits <100 tons peryear regulated hydrocarbons. LAC 33:111.2109]**~QT071** 

### r-ompliance Assurance Monitoring**~XEMPT.** Subject to NSPS SubpartA. Flare) 40 CFR 64] !Waste Gas Disposal poES NOT APPLY. This regulation is not applicable to LAC 33:111.2115] jwaste gas stfeams which must comply with a control device equirement as stated in LAC 33:111.2115.**~QT107** !National Emissions Standards for Hazardous facility is not a major source ofHAP's. 

### loPE- Dual Phase Extraction System**~ir** 

### Pollutants: Site Remediation- Subpart jGGGGG ·

40CFR6U
. jEQTJ08
. '**~tandards** 

### for Petroleum Refinery Wastewater his equipment does not come·in contact with orstore oily joPE OWS- Dual Phase Extraction System- Oil/Water

### ~ystems- Subpart QQQ 

### vastewater. Separator [40 CFR 60.690] 

### ' pii/Water Separation jrLAC 33:111.2109] jEXEMT. Emits 

### <lOO tons peryear regulated hydrogen Farbons.



# -

----**-----------~**



### 20

### LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY Calumet Cotton Valley Agency Interest No.: 312 Calumet Lubricants Company, L.P. Cotton Valley, Webster Parish, Louisiana 

# jx:I. Explanation for Exemption Status or Non-Applicability ofa Source ID No: !Requirement Notes EQT082/ll60211000 NSPS Subpart D. Da. Db. De for Boilers 

### )QES NOT APPLY. These arc no steam generating units. Fractionator Process Heater) 

### 40 CFR 60.40. 40a. 40b. 40c) [Waste Gas Disposal )OES NOT APPLY. Do not bum a waste gas stream LAC 33:111.2115) ontain.ing VOCs.**~SPS** 

### SubpartJ 

### StandardsofPerformance forpOES NOT APPLY. Heater converted from ercfinery fuel 

### gas 

### Petroleum Refineries o natural gas. 

### 40 CFR 60.1 00)



## 21Also Known As: ID 2211900010 3080-00010 7205811 73-0974954 LAD000225805 LAD000225805 LA0005312 WP0400 

### General Information AJID: 312 Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VG Air- Title V Regular Permit Minor Mod Name UserGroUp AFS (EPAAir Facility Syslem) AFS (EPAAir Facility Syslem) CDS Number COS Number EPA EIS Facility Site ID EPA EIS Facility Site 10 Kerr McGee Refining Corp Federal Tax 10 Calumet Cotton Valley. Hazardous Waste Notification Site 10 # Inactive & Abandoned Sites LPDES Permit# LPDES Permit # WPC State Permit Number LWDPS Permit# · Priority 1 Emergency Site

.Priority 1 Emergency Site Start Date 01-01-2000 08-05-2002 01-01-2008 11-21-1999 04-11-2000 06-09-1981 05-22-2003 06-25-2003 07-18-2006 7295 X-Ray Registration Number Radiation X-ray Registration Number 11-21-1999 1000005936 Cotton Valley Refinery Risk Management Plan EPA ID GD-119-1791 Solid Waste Facility No. Solid Waste Facility No. P-0196 Standard Permit Solid Waste Permitting 36528 Kerr McGee Refining Corp TEMPO Merge 47229 Kerr McGee Corp CottonValley Ref TEMPO Merge 71018KRRMCLA7SO TRI# Toxic Release Inventory Physical Location: 1756 Old Hwy 7 Cotton Valley. LA 71018 Mailing Address: PO Box 97 Cotton Valley, LA 710180097 Location of Front Gate: 32.7972671atitude, -93.4146891ongitude, Coordinate Method: l,.at.\Long.- OMS, Coordinate Datum: NA083 Related People: Name LarryAllen· Charles Cost Charles Cost Fred Holt Fritz Howes Jeff Lang R Murray Lynn Shearer

. Meridith Sheets**K~p** Southerland · Mailing Address

PO Box 97 Cotton Valley, LA 710180097 PO Box 97 Cotton Valley, LA 710180097
PO Box 3099 Shreveport, LA 71**~333099** 2780 Waterfront Pkwy E Sle 200 lndianaplois, IN 46214 PO Box 97 Cotton Valley, LA 71018
PO Box 97 Cotton Valley, LA 710180097 Page 1 of2 Phone (Type) 3188324236 (WP) 3188324236 (WP) charles.cost@calurn 3188324236 (WP) 3186324103 (WP)

3188324236 (WP) 3188324236 (WP) 3188324236 (WP) 01-01-2001 08-21-2001 03-01-1989 06-09-2002 10-02-2001 07-09-2004
Main Phone: 3188324236

Relationship Employed by Responsible Official for Responsible Official for Employed by Accident Prevention Billing Party for Accident Prevention Contactfor Water Billing Party for Radiation·contact For Employed by Emission Inventory Facility Contact for

TPOR0148**Rel~ted** People: Name Kep Southertand 

### General Information AIID: 312 Calumet Lubricants Co. Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080..00010-V& Air·Title V Regular Permit Minor Mod Mailing Address Phone (Type) PO Box 97 Cotton Valley, LA 710180097 kep.souther1and@ca 

### ---------

Relationship Ennsion Inventory FaC:ility Contact for Related Organlutlona: Name Addresa Phone (Type) Relationship

NAJC Codu: Calumet Lubricants Co Calumet Lubricants Co Calumet lubricants Co LP G.llumet Lubricants Co LP Calumet Lubricants Co LP Calumet lubricants Co LP Calumet Lubricants Co LP Calumet Lubricants Co LP Kerr-McGee Refining Corp
32411, Petroleum Refineries 324110, Petroleum R8finerles PO Box 97 Cotton Valley, LA 710180097 PO Box 97 Cotton Valley. LA 710180097 2780 Waterfront Pkwy Ste 200 lnd•anapolis, IN 46214 2780 Waterfront Pk'Ny Ste 200 Indianapolis, IN 46214 2780 Waterfront Pkwy Ste 200 Indianapolis. IN 46214 2780 Waterfront Pkwy Sle 200 Indianapolis. IN 48214 2780 Waterfront Pkvly Ste 200 Indianapolis. IN 46214 2780 Waterfront Pkvly Ste 200 Indianapolis. IN 46214 PO Box 25861 Oklahoma C•ty. OK 73125 3188324236 (WP) 3188324236 (WP) kep.southertand@ca 3188324236 (WP) kep.southertand@CG 3188324236 (WP) kep.souther1and@c:G 3188324236 (WP) 4052702071 (WP) Air Billing Party for Radiation Registration Billing Party for Sohd Waste Billing Partyfor Sol•d Waste Billing Party for Ef'nlssion Inventory Billing Party Owns Owns Emission Inventory B•lling Party Agent of Service for

Note: This report entJUed "General Information" contains a summary offacility-level Information contained In LDEQ'a TEMPO database for this facility and Is not considered a part ofthe permit. Please review the Information contained In this document for accuracyand completeness. Ifany changes are required or ifyou have questions re93rding this document, you may email your ch•nges to facupdate@la.gov.

Page 2 of 2 TPOR01"4Subject Item Inventory: 10 Description Entire Facility EQT 0019 HFR- HFR Storage Tank EQT 0020 10
- 500 BBL HFR Storage Tank EQT 0021 11
- 500 BBL HFR Storage Tank EQT 0022 14- 2,000 BBL VFR Storage Tank EQT 0023 15-2,000 BBL VFR Storage Tank EQT 0024 16-2,000 BBL VFR Storage Tank EQT 0025 17- 2,000 BBL VFR Storage Tank EQT 0026 18-2,000 BBL VFR Storage Tank



### -- EQT 0027 19-2,000 BBL VFR Storage Tank EQT 0028 2- 500 BBL HFR Storage Tank EQT 0029 20-2.000 BBL VFR Storage Tank EQT 0030 21 -2,000 BBL VFR Storage Tank EQT 0031 22-5,000 BBL VFR Storage Tank EQT 0032 23
- 5,000 BBL VFR Storage Tank



## - EQT 0033 24-5,000 BBL VFR Storage Tank EOT 0034 25
- 5,000 BBL VFR Storage Tank EQT 0035 26
- 5,000 BBL VFR Storage Tank EQT 0036 27
- 5,000 BBL VFR Storage Tank EQT 0037 28
- 6,000 BBL VFR Storage Tank EQT 0038 29- 50,000 BBL IFR Storage Tank EaT 0039 3- 500 BBL HFR Storage Tank EQT 0040 30- 6,500 BBL VFR Storage Tank EQT0041 31 -6,500 BBL VFR Storage Tank EQT 0042 32-20.000 BBL VFR Storage Tank EQT 0043 33
- 20,000 BBL IFR Storage Tank EQT 0044 34- 10,000 BBLVFR Storage Tank EQT 0045 35- 10,000 BBLVFR Storage Tank EQT 0046 4 - 500 BBL HFR StorageTank EQT 0047 47- 80,000 BBL IFR Storage Tank EQT0048 5- 500 BBL HFR Storage Tank EQT0049 54- 10,000 BBL IFR Storage Tank EQT 0050 55- 10,000 BBL IFR Storage )"ank EQT 0051 56- 10,000 BBL IFR Storage Tank EQT 0052 57-80,000 BBL VFR Storage Tank EQT 0053 58-500 BBL HFR Slorage Tank EQT 0054 6- 500 BBL HFR Storage Tank EQT 0055 60
- 5,000 BBL IFR Storage Tank EOT 0056 [66- 10,000 BBL VFR Storage Tank EQT 0057 167- 10,000 BBL VFR Storage Tank 

### INVENTORIES AIID: 312 ·Calumet Lubricants Co·Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air.Title V Regular Permit Minor Mod

Tank Volume Max. Operating Rate Nonnal Operating Rate

21000 gallons 21000 gallons 84000 gallons 84000 gallons 84000 gallons 84000 gallons 

### _J 84000 gallons 

### I 84000 gallons

21000 gallons 

### I 84000 gallons 

# r-- 84000 gallons 

### I 210000 ga11ons 

### L_

### ~=-----~ 210000 gallons

210000 ga11ons

--·------ 210000 gallons 210000 ga11ons '210000 gallons

252000 gallons



### ---- 50000 bbl 21000 gallons 273000 ga11ons 273000 ga11ons 

## 1 840000 ga11ons

840000 gallons 40000 bbl/yr 40000 bbl/yr



## - 420000 ga11ons 420000 ga11ons



### - 21000 gallons

80000 bbl

., 21000 gallons 420000 gallons 420000 ga11ons 420000 ga11ons

80000 bbl 21000 ga11ons 

## T2'fooo ga11ons 

# I

[ 210000 gallons

420000 gallons



### _______ _j_ 420000 gallons Page 1 of a Contents 

# I Operating Time

### -~

8760 hrlyr 1 8760 hrlyr

# ~ 8760 hrlyr 8760 hrlyr 

## I 8760 hrlyr 

# =.=] 8760 hrlyr 1 8760 hrlyr 1 8760 hrlyr 

# j 8760 hrlyr 

# i 8760 hrlyr _J 

### I 8760 hrlyr 

### i 8760 hrlyr 1 8760 hrlyr 

# j -· 8760 hrlyr 8760 hr/yr

### ~ -· 8760 hr/yr



### - 

## - 8760 hrlyr 

### i 8760 hrlyr I



# --- 8760 hrlyr 

### 1



# --- 8760 hrlyr 

# --j 8760 hrlyr 8760 hr/yr 

# 1 8760 hr/yr

_____

## j

---- 8760 hrlyr

__

### 1 8760 hr/yr 8760 hr/yr , 8760 hrlyr 

### I 8760 hrlyr I I



### --- 8760 hrlyr 8760 hrlyr 8760 hrlyr 8760 hrlyr 8760 hrlyr 8760 hrlyr

### ~-- 8760 hr/yr 

### -- 8760 hrlyr 8760 hrlyr 8760 hrlyr 8760 hrlyr 

### _j

TPOR0149Subject Item Inventory: .10 

### -··DB&ciiPilon INVENTORIES AIID: 312 ·Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air·Title V Regular Permit Minor Mod

1 Tank

### V01lime·

## M~::~~~-~~tihg Rate 

# INormal Operating

## Ra~e

# r Contents

___Lperatlng

## nme 

# "1

------- j 294oO

# gall?~'--:_ -. ---- .. )-

# -~ _

# 876oi>,;y;--~~ 

# tHE;**:9~:~:**

# l=-=
-----**---~-~-:- ~-t_--_];~6**  1Entire Facility 

## lEar 0058 69 · 700 BBL HFR Storage Tank - 

### --- f"EOT 0059 7- 500 BBL HFR Storage Tank

··-- ;·Ear·aoso 71 -900 BBL HFR Storage Tank IEar·oasT

### 72- 5,500 BBL VFR Storage Tank -· ·-

----- 210000 gallons : 1 8760 hrfyr 

### i 420000 gallons 

# r-·--·· -·-.·-· ·-·-·· --------------1 --8760hr;yf"' 

## i 223111 gallons

# ·r-··---- --·-···- ····· ····---- -------·----·-- 8760 hrlyr
- --, 

# l 21DOO_gallons 

# !
- __-_ ---**~=~-----** 1 ·a_?GOhiiyi

### ~

-

# ~-~=a~l:~~**-~~~ _3~:48**  MMBTtlhir--f-3:t48MM BTUfllr ·--

# -----~----.-~==·JJ :;:

# ~;~; -l i 16.74 MM BTU/hr 16.74 MM BTU/hr 8760

### t-·"- 1EOT 0069 lBO
- Blue Drum _ . 

## l 30 gallons/min 30 gallons/min 1 

### B!_6E_!
J EOT 0070 

# ICT- Cooling Tower ··-· _ _ 

# I

__ _;___ 1500 gallonslmm

__

### l 1500 gallons/min -·--·- .. _···-··J_

__ 8760 hrtyr 

# ·I**[EO~** 0071 .FL2- Flare

_ __ -·· 

### I 15.9 MM

### ft"3ty~ ---=r------r5.9 MM ft"3tyr

___ .. _________

## L

__ 8_760

### ~r!fr __ _ 

# l**E~! -~~?3__!FP**  ·**Emergen~ Fir~t.I!~-~~!'"Ps**  ........._ _ :...__ 5_:3_5_**-~~~~power** 1 535 horsepower 

# 1 ____________...____!._

__**--~2** hrlyr 1 

### 1 EOT 0073 IGEN
- Backup Generator · 241 horsepower i 241 horsepower 

### j 500 hrlyr 

### j j EOT 0074 IH- 101 · 100 Crude Umt Process Heater

.. 1**··----1~2-MM** BTUth_r

___

## ··1 30.52 MM BTU/hr 

## I Natural Gas·
--- · · -.-.,----·-·8760 hr,Yr**~ EOT**  0075 !H-201A- t**10~** Crude Umt Process Heater

__ _ ______j 10.18 MM**B~~~~--1_**____**1_~~!..** MM BTU/hr 1 Fuel Gas

____ . 

## ··----L 8760**h~"f!.**___ l 

## 02:**OO?~.!H-202-** Hot Od**Proces~ ~~a_ter**  No 1

__ __:. . 37**~M ~TU/hr**  

### ! 37 MM**BTU/h~--!** Natural Gas-----·-

.. ____1 _____ 8760 hr/'yr -··- . .

### ! OT 0077 IH-203- Hot 01l Process Heater No 2 ! 26.56 MM BTUihr i 26.56 MM BTU/hr I Fuel Gas i 8760 hrtyr : I

### E:Qf 00i8.1H-204- Solvents UM Heater
--- ··: ·---18. MMBTUthi-"--i- 18 MM-BH}/hr Natural Gas
-- -· ..• -·

# r-·-... 8760 hrfyr

.; 

## iEOT 0079H-205 · Hydro"'ir8Bi8r Healer
- - ---)- 35.7-M·M-BTUihi 

## ···-i 35.7 MM BTUihr Natural Gas 

### &"FUen;as --1 ---8i60 hrryr·--! 

## IEOT 0080 H-301- No.1 Hydrotreater Heater · -- -- · · -i --13 32 MM BTU/hr ! t3 32 MM BTU/hr 

## I Fuel Gas
-- · 1 8760 hr/yr**---~** 

# :ecn 0081 H-601 ·Solvent Train**Pr~~.!".** Heater
-- ·- ·-· .

# -·L---**8---~~** 8Tlflhr····-·-·i- 8 MM B!U!tu Fuel Gas

______**~--·~~~~~-=**

## _J**~-hr,Yi** 

### ---1 : EOT 0082**H-602f1000_:_~Iillty** Fractionator**P~~~**Heater 1
.. __ _ 1
.. __ 9 MM**~~~-~r** .._____

## !..... 9 MM BTU!hr Natural Gas --· ··--·- 1 8760**-~rty~__j** EOT 0083 IH-701- 700 Uml Process Heater 

### I 

# I 18.49 MM BTU/hr j 18.49 MM BTU/hr Fuel gas 

## I 8760 hr/yr 1**~EaT** 0064 IH-901
- HydfOgen·Piant Reformer --------·- 

### 1 ··-- - 33-.**7~EH-Lilh-r**

### -r--33.74--MM BTU!hr Natural & Waste

## G-a·s**----·---~----8760** 

### ht,yr--1 :-Ear 0085 iLO- Loading Operations 1 ··· · · ·**··~6807** "t)bl;y;.--·---·i---- ---·- ----··-j·---·-8766 hrlyr 

### j rEQT 0086

### :~H ·Air Dryer (OOS)

_ _ _____ 

### ! -·-·**~--~=-=** 8

### ~~ BTi.Jihf··----, 8 MM BTU!hr Natural Gas

### --~**~ ·:~~-~L-~.:**  lfi6o

### n.~~~--~· LE9_**!..~~'!!_.ww-** Wastewater Em1ssions ..• . ... ___**2_1~ ~a_llonsl~** ___l 1**~0** gallonsln\ln ·-·-· .... __[**876~** hr/yr II 

# lEOT 0088 lA- Pressunzed Storage Tank • 36750 gallons J 

### i · 8760 hrtyr

1EQT"i:i089 ·37- Pressunzod Storage Tank --· ·-·· 28266 gallons ,-- -- 

### -----i ·- ------**·---~**

### ·- ··- -8-iSO"hi/Yr 0090 38- Pressunzed Storage Tar\k---·--·---- "28266. 

### Q811onS
.....**-----~-** 

### ----···----·. -j-- 8760 hr/yr 

## IEOT 0091 ,39. Pressurized Storage

# tank

____ - ---- 398874--gallons 

## ·1··- ··----··-·---··--1
---- ·· ·· -·-..

# -··-r·· -·-·arso hr/yr · [Eat oos2 73- 5.000 BBL VFR Storage Tank ·-··-**LE~T 00~3**  76. 10.000

### BBLVFR Stor.tgerank 

# f EQT 0064 79- 5.500 BBL VFR Storage Tank ea'roos5 8-500 BBL HFR Storage"Tank [EQT 0086 9 - 500 BBL HFFfStorage Tank

·-··-- 

### IEQT 0067 B-1401- No.1 Boiler**i"i~ar** ooss B-1402- No.2 Boiler

[-EOT-Oi592-

### 40- Pressurized Storag0"i'80k

... -·- .398496 gallons 

# r··.--- -·----· --- ·-·-·..---; 8760 hrtyr--

.EOT 0093 41 -Pressurized Storage Tank

__________ -·-- 398748 gallons : ··· ··-··-·-- ···---·--- -·- ···- ---· ··- · · ·· ·8760 hr/yr ··· 

# ----· 

# ---- ···--· --····----·-· ··-- -· 

### -----·-··----------··---·· ----· .50T 0094 44-**Pre~~-unzod** Storage !_ank**__j_~_0084_2** ___**g~l!~.':~--~----·-·** ---·----· ---··· --··-·-· 8760**h_r_~~-----** EOT 0095 46- Pressunzed Storage Tank : 116634 gallons 8760 hrlyr

### ~?!6_j70-PressurizedStorageTank ______

### ---~------j 26334 gallons : ··--··-- __

### ····-·----8-~60hrlyr 

## ! Page 2 of 8 TPOROt•tSubject Item Inventory: 10 Description
Entire Facility EQT 0097 12- Pressurized Storage Tank EQT 0098 42 • Pressurized Storage Tank EOT 0099 43- Pressurized Storage Tank EQT 0100 45- Pressurized Storage Tank EOT 0101 59
- Pressurized Storage Tank EQT 0102 62
- Pressurized Storage Tank EOT 0103 63- Pressurized Storage Tank EQT 0104 64
- Pressurized Storage Tank EQT 0105 65
- Pressurized StOrage Tank EOT 0106 68- Pressurized Storage Tank EQT 0107 OPE- Dual Phase Extraction System 

### INVENTORIES AIID: 312 ·Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080..()001 O·V6 Air·Title V Regular Permit Minor Mod

Tank Volume Max. Operating Rate 

# INormal Operating Rate

21672 gallons 

# r-- 190512 gallons 

# --l 191016 gallons 

# -=± 116676 gallons 22008 gallons



### __ ___j

__**~-** 21084 gallons 

# ' 21084 gallons 

# '

- 23436 gallons 

### I 23436 gallons 

### I 23436 gallons 

# -r

--- 1600 ft"3/min 

# r- 1600 ft"3/min EQT 0108 OPE OWS
- Dual PhasB Extraction System- Oil/Water 

### - 50 gallons/miri 

### - 

## ! 50 gallons/min Separator j___ FE- Fugitive Emissions- 

### - ; FUG 0002 

### I I



### - FUG 0003 UR- Unpaved Road Emissions 

### I _ _j

___ Stack Information· 10 Description Velocity Flow Rate Diameter (fUsee) (cubic fUmin-actual) (feet) Entire Facility EQT 0019 HFR • HFR Storage Tank EQT 0020 10-500 BBL HFR Storage Tank 1 6 .3



### -- EQT 0021 11 • 500 BBL HFR Storage Tank 1 6 .3 EQT 0022 14-2,000 BBLVFR Storage Tank 1 6 _3 EQT 0023 15 • 2,QOO BBLVFR Storage Tank 1 6 .3 EQT 0024 16 • 2,000 BBL VFR Stoiage Tank 1 6 .3**-~-------** EOT 0025 17 • 2,000 BBL VFR Storage Tank 1 6 .3 EQT 0026 18 • 2,000 BBL VFR StoraQe Tank 1 6 .3 EQT 0027 19 • 2,000 BBL VFR Storage Tank 1 6 .3 EQT 0028 2 • 500 BBL HFR Storage Tank 1 6 .3 EQT 0029 20 • 2,000 BBL VFR Storage Tank 1 6 .3 EQT 0030 21 • 2,000 BBLVFR Storage Tank 0
..01 .3 EQT 0031 22- 5,000 BBLVFR Storage Tank 1 6 .3 EQT 0032 23 • 5,000 BBLVFR Storage Tank 1 6 .3 EQT 0033 24 • 5,000 BBLVFR Storage Tank 1 6 .3 Page 3 of 8 Contents Operating Time

8760 hr/yr 8760 hr/yr



# -- 8760 hr/yr 8760 hr/yr 8760 hr/yr 8760 hr/yr 8760 hr/yr 8760 hr/yr

· 8760 hr/yr 8760 hr/yr 8760 hr/yr 

### I 8760 hr/yr**-~·-** 8760 hr/yr 8760 hr/yr _J Discharge Area Height Temperature

(square feet) (feet) (oF)



### -- 

# -- 40 40 77 40 77 

## _j 24 77 

## i 24 77

## ~ 24 77 

## I 24 77 

# j 24 77 I 24 77 

# I 40 77 24 77 

### I 24 77 

## I 30 77 

# __,

# I 30 77 

# --1 30 77 __j

TPOR0149Stack Information: 

# c:=--- Oeacrlptlon

:Entire Facility 

### INVENTORIES
- AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
Velocity (f11sec) Flow Rate (cub1c fUmin-actual) Diameter (feel) Discharge Area (square feet)



### --- Height (feet) Temperature (oF) i EQT 0034 25-5.000 BBL VFR

.. 

### Si0r_a.Q8 Tank ----,- ------6··--·-·-·---- .3 --.-- -------- ... 30
--- __ 7_7

____ 

### -EQ'f003526': s.oaa·ssLVF·R-StOrage

## ra-nk

_____ ·-- 1 

### s ··-- ·.3 · -- 

### Jo 11 

## I EOT 0036 27- 's.OOO-BBL VFR s!oiage-tank
- 1
---**-s·=~:~. -~y-**  30**,,-~: :=~-j**  1 EOT 0037 26-6,000 BBL VFR Slmage Tank 1 6 .3 25 77 

## ! 

# I EQT 0038 29

### :·'S'Q.Ooo BBLIFR Storage Tank i 6 3
-- 40 77

. EQT 0039 3-500 BBL HFR Storage Tank

. --------------· 1
-- 

# --·-·e-···---- .3 

### ----40
. -----77----- -i

EQT 0040 30

- 6.500 BBI'VFR Storage Tank 1

--- 

# s--------- .3 25 77**~** 1 EOT0041**31-s:sOOeslVF-RStoiiQeT~-------** 

### ..... 1 6 -··**---~3--** 

### -----------25



# -------**-;;----~~~--~1**

EQT 0042 32-20.000 BBL-VFR Storage Tank ,-- --·-- ...

### if··-···--·--- .3 36 EOT0043 33-20.000BBCLFRStoraQeTank ,-- --· .. 

## ·····s··*--------- 3 36.5 77 

## I 

# i EQT 0044 34- 10.000 BBL vFR Storage Tank 

### 1--

-----**---~**

### _**.:~-~-~~---~~:-** 

### ...**--~3-** __ _ 30**~----·** 

### 77 EQT 0045 35 · 10,000 BBL VFR Storage Tank EQT 0046 4

- 500 BBL

### HF-R Storage Tank EQT 0047 

### 4'f- 80,000 

### BBl.IFfnii0fiQ8filiik""

_____ --



### - EQT 0048 5- 500 BBL HFR Storage Tank EOT 0049 54- 10,000**~sCi**FR. Storage Tank -E-6T 0050 55. 10.000 BEfL I FR. si0i-8ge Tank 

## ear 0051 56- 10.0-tio·e:eL··IFR SiOrage Tank EQT 0052 57- 80.000.BBL VFR SlOrage Tank EOT 0053**Sa-~**

### ·saO ·aBL H.FFfStorage Tank 

# ---- --**~T**

## oos4-6·:

## Soo eBCHFR

# storage T3nk EOT 0055 60-5,000 BBLIFR Storage Tank EOT 0056 66- HJ.oo(fsel VFR Storage Tank -- 

### - .. -· EOT 0057 67- 10.000 BBL VFR Storage Tank**~cn----·----·** 

# -- . -----·-----·------ EOT 0058 69- 700 BBL HFR Storage Tank 

# ' 1

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- 900 BBL HFR Storage Tank 1 ---6-------

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### ---,8 77 

# ---i Earoosf· 72- s.ScXfBBL VFR**Storag8T~-----** . -------------1·----

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# i EOT 0062 73 · 5.000 BBL VFR Storage Tank 

### ---- ---- 1 

### - -- - ----6----·----- 

### y- -- j2 77 

# ! EOT 0063 76- 10.000 BBL VFR Storage Tank .

### --- ------ 1 

## -s-···- ------ · .3 1a 77-----; f-gar 0064

### -·:;g-.-5.500 BBLVFffStorage

# tanr-------·· -- ---·- 1 

### --s··---------- 

### ·----:3· ---,8**-----~----·** 

## • --- [ EOT 0065

### ~~-~**~~~-H~~-~~orage** Tank -·--··-- ___ 

### --. ·--6-- ·-- ----- - 3 40 77



### ------------------ Page 4 of 8 TPORD 148----- -------------------------- 

### INVENTORIES AIID: 312 ·Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080..00010-VS Air·Title V Regular Permit Minor Mod
Stack Information· 10 Description Velocity Flow Rate Diameter (fUsee) (cubic tumi_n·actual) (feet) Entire Facility EQT 0066 9-500 BBL HFR Storage Tank 1 6 .3 EOT 0067 B-1401- NO.1 BoiTiif

___ 51.7 12882 2.3 EQT 0068 B-1402- No.2 Boi19r 68.3 12870 2 EOT 0069 BD - Blue Drum-··· 

### - .2 EQT 0070 CT- Cooling Tower EOT 0071 FL2 - Flare 197 20880 1.5 EQT0072 FP- Emergency Firewater Pumps 339.1 1440 .3 EQT 0073 GEN- Backup Generator 190 2238 .5 EQT 0074 H-101- 100 Crude Unit Process Heater 15.1 14400 4.5 

### .• EQT 0075 H-201A- 1100 Crude Unit Process Heater 61.5 18102 2.5 EOT 0076 H-202 - Hot Oii-Pra·ce·ss Heciter No. 1 17 12810 4 EQT 0077 H-203 - Hot Oil ProceSs Heater No. 2 48.8 14364 

### - 2.5 EOT 0076 H-204- Solvents Unit Heater 48.8 26568 3.4 EQT u079 H-205 - Hydrotreater Heater 12.9 12306

# . ---------u EQT 0080 H-301 -No.1 Hydrotreater Heater 46.26 19621 3 EQT 0081 H-601- Solvent Train Process Heater 25 18840 4 EQT 0082 H-602/1000- Utility Fractionator Process Heater 19.3 14544 4 EQT 0083 H-701 - 700 Unit Prociss Heater 42.5 12510 2.5 EQT 0084 H-901 - Hydrogen Plant**Refo~mer** 24.7 7272 2.5 EQT 0085 LO- Loading Operations EQT 0086 SH -Air Dryer (OOS) 21.06 15875 4 EQT 0087 WW- Wastewater Emissions EOT 0107 OPE- Dual Phase EXtraction System 1 FUG 0002 FE- Fugitive Emissions FUG 0003 UR- Unpaved Road Emissions GRP 0010 Crude-Cap- Crude Cap (Capped Tank 47) 80.000 BBL IFR STORAGE TANK GRP 0011 HEAVY CAP-1 • Heavy VOL Cap-1 (Capped Tank 57) 80,000 BBL VFR STORAGE TANK GRP 0012 HEAVY CAP-2 ·Heavy VOL Cap-2 (Capped Tank 57) 80,000 BBL VFR STORAGE TANK GRP 0013 UH VOL IFR CAP· UH VOL tFR Cap (Capped Tank 54) 10,000 BBL tFR STORAGE TANK



### - GRP 0014 VFR/HFR CAP· LighUHeavy VOL VFRIHFR Cap (Capped Tank 16) 2,000 BBL VFR STORAGE TANK Page 5 of 8 Discharge Area (square feet) Height Temperature (feet) (oF)

40 77 19.6 400 19.6 400 13 120 20 60 1100 10 840 15 854 40 500



# -- 25 750 88 380 40 500 57.2 500 106.5 500 

# . I 29.5 850 ·-· 

# l 60 800

# ~ 60 800



### ---- 37 350 •--'- 65 300 20 60 600 20 20 70 20



# -- 20 40 

# I 40 

# I 40 

# I 36.5 

# I I 24



# __

# __]

TPOR01o49Stack Information: 

### .INVENTORIES AIID: 312- Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air·Title V Regular Permit Minor Mod 

## [ io

# '-""==---------;;:D.,-oa'"c:-:crlpti~~------ _·-**y;,~~~tY·-···** 

# ... -**"flo~**

### Rate Diameter Discharge

### Area Height**---T-e~Peratur~--l**

## (N~_c_l____ (cub•c

## N~n-a~ual) (feel) (square feel)

## _':;~)**-~~~~~-~oF) ~j**  .Entire Facility

## l.~RP 001

## ~---""~"'~**"P~""~""b ~~~~:_s_P_s_K_B_F_R--C~P** **(CA~.~~~-·r_AN_K_7~:.1~.-6~~---a_·** B_L

_____ _ Relationships: Subject Item Groups:

### ~-- 

### iii- --,-1--=---------,GroupTypo**~-CRG** 0001·

..

### ,CQmn;QrlR&qliiremeniSGfOU·p -------,--- - - ···------- ·· ···- Group Description
---- ------ ·•··

## ~--:**CQiiSeniOicre·e~e~~~~=nO'Isr:f;:o:;;r**-;Bc;oi'Cie 0 r 0 ann«dnHceca;;-le 0 r<s

# "'"""""'"'=..,-----------· --,! 

## _I**~5'RP** 0010 

# I Equipment Group**l?R~ ~~2._1** _ _jEquipment Group**~-~p** 0012

_**.J~~~i~~~-Gr~u~ ~~~-0?.~~--JEaurpment**  Group 

# ICrude-Cap· Crude Cap (Capped Tank 47) 80.000 BBL IFR STORAGE TANK ---------+"'HEAVYCAP-1

-

### He~~~LCap-1 (Capi>e_d_Tank_:;7J 80.000

### ~Bl VFR_ST""O"'RA'"""G"'E'"T'-AN""K,-----

### ~ 

## I HEAVY CAP-2- Heavy VOL Cap-2(Cappcd Tank 57) 80.000 BBL VFR STORAGE TANK :



## .. ---.·-· ----p.iH**v"(:}C-iF_~ ~~**  

### -.uH VOL

### I~R Cap (Capped Tank 54) 10.000 BBL IFR STORAGE T A_NK

-------- 

# j**RP** 00.14

___:_Equipment Group GRP 0015 Equrpment Group 

### GRP-0017- 'eauroment Group j VFRIHFR CAP-**LrghVHea~** VOL**VFRIHF~** Cap**(C~_P_Ped Ta~~-~~_:~~~~L**  VFR**~~?~~~ !~-----**  

# __ j 

## i.**N~PS_**l<_b CAP- NSPS KB FR CAP (CAPPED TANK 76)**~~~~~0** BBL STORAGE TANK --·----- ·-· 

### -1 1 PST
- Pressunzed Slorttge Tanks**~-0~~~~~** or Facility Wide


## ____ j EF-

### E~~~ Facll1ty ------.. .... ·--·- ] Group Membership:

## ~~-oo**~o** ·--..--htr-·sao sBLHFRSiO'raQe

## ;~~~~-~~~..

## --~~-crip.tlon**-~_:·~~- ==--~----~---**  

# - GRPoooodOOo11 MemberotGrOUps
------- -.-- :Earo02f

___

### "j""1T:s·aa BBL HFR Storage

### l'irik

___ -- ----· ---- 

### -GRF,-OOoOOOoO;l------- 1 EQT

### 0022 I 14- 2,000 BBL VFR Storag8-Tci·n·k ·---------- . - .•. _ ..__ GRP0000000011

EOT 0023 115-2.000 BBL VFR Storage Tci.ik

..________ ·· ·- ·-- ------·**·e;:OR~P"o:;,o;;oo;:o"o"oo;c.o;c.1;;1-------------------···---··-·-** ---- EbT 0024

# ---;Ts:2.ooo·aBL vFffStC:ir3Qe·rank____ ·- · ---------- · ·-·- GRP·ooaooo"o"'o'"1'4

_____ _ EQT 0025 j17 · 2,000 BBL VFR Storage Tank______ ·-- GRP0000000011 

### !EQT 0026 

### i 18-2,000 BBL VFR StorageTaii"k ··--- ·---· 

### IGRPOOoQjjo:C.0;;0;-.1-.4

______ ----- :·E6T.002i 

### ···---·r--;g-:-2.000 

### a·BIVFRSiOrage·**Tel~---·-·** . -· . -··-·· ··---·· : GRPOOoooooo11 : EQT 

### ooi8

____ 2-500 BBL HFR Storage Tank GRPOOOOO·i<o-<ooic1;-;1;---- :-EQT 0029 20-2,000 BBL VFR Storoige Tank--
.-·- GRPOOOOOOoi<o<1<1

-----**~-E-ar** oojQ---·:F-2.000BBlVFR Sto·raQe Tcin_k______
... ·-------------.- .. -·; GRP0000000011 /'i:ar 00j1---; 22-5.000 BBL VFR SiOr.age rank· ·-------·. 

### --j-GRPooOOOOOOff______ --·----·--·- -· ------ ··---·--··--:

# ~~;_;~~~~~-=I.~-~-~~-:~~:~~~~i~~-~:-~-:~---· 

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# ·-·-. ·- -----------**-~-j ~**  EOT 0034 

### I 25- 5,000 BBL VFR Storage Tank GRP0000000011 

### i 

## -----!

.. __J



# ··eat**oOJs·---~000** BBL VFR Storage T3nk ·------·- ----- GRP0000000011 --··--i -EQT 

### 0036 :27 · S.060"esL VFR**Storage~** Tank GRP0000000011 "EQTQ()37 I 28
- 6.060 BBL VFR

### Stor£i9~**!_.in_~_** 

## ·-·-·----·· -----· -+G;;R"'-P"ooooo""'""'o"oo;c1"5;_

_________ -_------ .....

### ·------=~j Page 6 of8**TPOR01~g** 

### "Group Membership: 10 EQT 0038 29
- 50,000 BBL IFR Storaga Tank EQT 0039 3 - 500 BBL HFR Storage Tank EQT 0040 30 • 6,500 BBL VFR Storage Tank EQT 0041 31
- 6,500 BBL VFR Storage Tank EQT 0042 32- 20,000 BBL VFR Storage Tank EQT 0044 34- 10,000 BBL VFR Storage Tank EQT 0045 35- 10,000 BBL VFR Storage Tank EQT 0046 4 - 500 BBL HFR Storage Tank EQT 0047 47
- 80,000 BBL IFR Storage Tank EaT 0048 5- 500 BBL HFR Storage Tank EQT 0049 54- 10,000 BBL IFR Storage Tank EaT 0050 55- 10,000 BBL IFR Storags Tank EQT 0052 57- 60,000 BBL VFR Storage Tank EQT 0053 58
- 500 BBL HFR Storage Tank EQT 0054 6 - 500 BBL HFR Storage Tank EQT 0055 60- 5,000 BBL IFR StorageTank EQT 0056 66- 10,000 BBL VFR Storage Tank EQT 0057 67- 10,000 BBL VFR Storage Tank EQT 0058


## - 69- 700 BBL HFR Storage Tank EQT 0059 7- 500 BBL HFR Storage Tank EQT 0062 73- 5,000 BBL VFR Storage Tank EQT 0063 76- 10,000 BBL VFR Storage Tank EQT 0064 79
- 5,500 BBL VFR Storage Tank 

## I EOT 0065 8-500 BBL HFR Storage Tank iEOT0066 9
- 500 BBL HFR Storage Tank 

## IEQT 0067 B-1401 -No.1 Boiler EQT 0068 B-1402- No.2 Boiler EQT 0074 H-101 -100 Crude Unit Process Heater EQT 0075 H-201A-1100 Crude Unit Process Heater EQT 0076 H-202
- Hot Oil Process Heater No. 1 EQT 0077 H-203- Hot Oil Process Heater No. 2 EQT 0078 H-204- Solvents Unit Heater EQT 0079 H-205
- Hydrotreater Heater EQT0080 H-301 -No. 1 Hydrotreater Heater EQT 0081 H-601- SolventTrain Process Heater 

### INVENTORIES AIID: 312 ·Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permil Number: 3080-00010-VS, Air.Tille V Regular Permit Minor Mod

Description GRPOOOOOOOO 1 0 :.GRP0000000011. : 

### ,. '", GRP0000000015 GRP0000000011 GRP0000000011 GRPOOOOOOOO11 GRP0000000011 GRP0000000011 GRPOOOOOOOO 10 GRPOOOOOOOO11 GRP0000000013 GRP0000000013 Member of Groups



## --

--

·-



### - GRPOOOOOOOO11 , GRPOOOOOOOO 12**----·---~·-** GRPOOOOOOOO11 GRP0000000011



### - - GRPOOOOOOOO 13 GRP0000000015



### ---- GRPOOOOOOOO 15 GRPOOOOOOOO11



### ----- GRP0000000014



### - GRP0000000015 GRP0000000015 GRP0000000015 GRP0000000011



# - ----- GRP0000000011 CRGOOOOOOOOO 1 CRGOOOOOOOOO 1



### ·----- CRGOOOOOOOOO 1 CRG0000000001 CRG0000000001 CRG0000000001 CRG0000000001 CRG0000000001 CRG0000000001



## .. CRG0000000001 EQT 0082 H-602/1000- Utility Fractionator Process Heater CRG0000000001 EQT 0083 H-701
- 700 Unit Process Heater CRG0000000001 EQT 0084 H-901 -Hydrogen Plant Reformer 

### - CRG0000000001 EQT 0088. 1A- Pressurized Storage Tank '• GRP0000000017 EQT 0089 37- Pressurized Storage Tank GRP0000000017 EQT 0090 38-**Pressuriz~~ _§_!~~age**  Tank GRP0000000017

----- ---- -- -- Page 7 ofB 

### ,·.



# --

--

I
TPOR0149Group**Members~lp:** 

### INVENTORIES AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080.()001O-V6 Air- Title V Regular Permit Minor Mod



# ------"l

I 

# IEOT

## 00**~1** 

# ! 39"- Pressurized Storage Tank' -· 

### O.scr1ptiOrl

___ - ...... ·-- li

## GRPOOOO~~~~;··-·-· Member of Groups

# i~~**~~ ---~--1** **~: ~=:~~~~** **~:::~ ~=~:-**  

# -----------**-~-** 

# -- - -- ---------**~:::~~~~~~-~-** 

# ------------·- ·------- . -· ···-··-·----1 ----1

EOT 0095 ·-·-- - i"46 · Pressunzed Storage Tank --------------· ·-- ---- 

# I GRP0000000017 ·- -------- 

### -·-·····i 1EQT 0096**~7"0·--Pressurized** Storage Tank

____ ·· · · ·-**:--~-------** GRP000000001!.

__ ----- _____ -··-· ---···- ___j

· EQT 0097 ! 12- Pressurized Storage Tank 1 GRP0000000017**-~-~!!___** 

### _**-~~---PressurizedStorageTaiik___** ----- --··-- __ i**GRPOOOO_~~~~?.** --·---- --- -· _______]

# ~~~-**:r::~L~~~E~-- ~:~--**  

# ___**~-------:~:::=~~:---=~~=-** 

# __**---~--- ~-:~~-~~:j**  I EQT 0102 ·--·-· 62

### ~Pressurized**Storag!_Ta~~--------** ____

### GR~0000017_____ _ ______ _J EQT 0103 63- Pressurized Storage Tank GRP0000000017 : 

# -ear 0104

___· 

### 64. -·Pressurized Storage-Tank.
- -----· GRP0000000017 ··· ··------- 

### EOT0'10s -··· 65"- Pressurized Storage Tank ·--- . ·-· GRP0000000017 ----···· EQT**010~** 68- Pressurized Srorage Tank -·--·**G~~~~~~~~~!~_--**__----------------- 

# -**-~~**

# _:-=-:J NOTE: The UNF group relationship Is not printed in this table. Every subject item is a member ofthe UNF group

Annual Maintenance FH: 

# I FHNU.Tiber· I ··-AJr**c~~~aminant** Source**c-·--~_ultiPrier·~ Units~**  Measure 

## "l 0720 10720 Petroleum Refimng**(~-~t~~-CapaCJty)** 12 

## IM**bblfd~¥.** i



# -- SIC Codes: [ --rPetrOioum refin-;-ri"g---·-· --·-·-·- -----: AI 312 

# J



# ---==[**~~r~leum re~nl'2_~--** **--~ ~=~~~** **-=·~--~F** 001

_________::

Page 8 of 8 TPQR01•9

## co Subject Item Avg lb/hr Max lb/hr Entire F.aclllty

EQT 0020 \0 EQT 0021 

# , EQT 0022 14 EQT 0023 15 EQT 0024 16 EQT 0025

# ~F 17 EQT 0026 18 EQT 0027 18 EQT 0028 2 EQT 0029 20 

# . EQT 0030 

### 1-- 21 EQT 0031 22 EQT 0032 23 EQT 0033 24 EQT 0034 25 EQT 0035 26 EQT 0036 27 EQT 0037 28 . EQT 0038 ' 29 EQT 0039 J EQT 0040 JO

. EQT 0041


# __=±

" EQT 0042 J2 

## .EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-V6 Air -Title

## v Regular Permit Minor Mod

·-·-- NOx PM10. 502 Tons/Year Avg lb/hr Max lb/hr Tons/Year Avg lb/hr Max lb/hr Tons/Year Avg lb/hr



### - - 

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TPOR0145

### EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Penni! Number:**3080~0010-VG** 

### Air·Tille V Regular Penni! Minor Mod 

## I Subloct ttom

# ~~~=/hr Max lblhr 

### i

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----------· Page 2 of 8 TPQR01•S

## co Subject Item Avg lb/hr Max lb/hr Entire Facility 

# r EQT 0043 33 EQT 0044 

# " EQT 0045 35 EQT 0046 4 EQT 0047 

# " 

# I EQT 0048 5 EQT 0049

# ~ 54 EQT 0050 55 EQT 0051 56 EQT 0052 57 EQT 0053 58 EQT 0054 6 EQT 0055 60 EQT 0056 66 EOT 0057 67 EQT 0058 

# " EQT 0059 7 EQT 0060 71 EQT 0062 73 EQT 0063 76 EQT 0064 79 EQT 0065 B EQT 0066 9 

## EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312 -Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
NOx PM10 502 Tons/Year Avg lblhr Max Jb/hr Tons/Year Avg lb/hr Max lb/hr Tons/Year Avg lblhr



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------ · - 

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### 1

# ---r- --=--1

__ _!_

________

# I

# ~QT 0055 

## --i--- 

# I 0 ,. ___ 

# I

___ 

# _L

____

# j___ 

# --1----

# ---1**~:~-::::--**

# ---.**~ ~-----~;~::** 

# --1----L**--=--=:L=:~- _]_-=~-----** **-~** EQT 0058 

### --! 

### ! 2 4 

## ! i !

# .!~QT 0059··----:

---- 

# -·-;0-- )

___**--'-----i------~---==·~** , L 

# ! 

# I I
----- = ---- 

## ·-iEar 

## oo6o I 0

_ 35 : 24.8 , 1.5 : _ _ ___ J 

# ------,

,. . ------ I

...,.... --ass [____

_ _ 2 9 

## I_

______ !_

_ __ ._____ ___ _ _ __ 1

# ~0066 --'---------- 19 _]_ 

# _t-
___ Page 4 of 8**TPQR()I~S**

## co Subject Item Avg lb/hr Max lb/hr Entire Facility

EQT 0067 2.80 2.80 B-1401 EQT 0068 1.40 1.40 8·1402 EQT 0069 80 EQT 0070 CT 

# f---iat 0071 0.15 0.15 FL2 EQT 0072 FP 3.57 3.57

### ~QT 0073 1.61 1.61 GEN -· EQT 0074 H-101 2.50 2.50 EQT 0075 0.84 0.84 l:l·201A EOT 0076 3.05 3.05 H-202 EQT 0077 H-203 2.20 2.20 EQT 0078 1.50 1.50 H-20< EOT 0079 2.94 2.94 H-205 EOT 0080 1.10 1.10 H-301 EQT 0081 H-601 0.66 0.66 EQT 0082 H-602/1000 0.69 0.69 EQT 0083 H-701 1.50 1.50 EQT 0084 9.60 9.60 H-901 EQT 0085 LO EQT 0086 SH 0.66 0.66 EQT 0087 

### ww EQT 0107 OPE

. EQT 0108 OPE OWS 

## EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312 -Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-0001O-V6 Air- Title V Regular Permit Minor Mod

- NOx PM10 Tons/Year Avg lb/hr Max lb/hr Tons/Year Avg lb/hr Max lb/hr Tons/Year

12.07 3.30 3.30 14.37 

## ! 0.25 0.25 1.09

# --t-o~-- 6.04 1.60 1.60 7.19 0.12 0.55

# ~ I 

# T 1.70 1.70 7.49 

### I 

## ' 0.67 

# _j 0.18 0.18 0.80 

# ·r 0.01 0.01 0.06 I __i

_____ 0.18 0.54 

### i 16.59 16.59 2.49



### ______

### )._

___1.18 1.18 j 0.40 

## i 7.47 '7.47 1.87 

# I 0.53 

# I 0.53 0.13 

### ' 

# I ' 11.01 3.00 3.00 13.1, 

## I 0.23 0.23 1.00 

## -; 

# r 3.67 1.00 1.00 4.37 0.08 0.08 0.33 

### i 13.35 3.63 3.63 15.89 

# :-· 0.28 0.28 1.21 

# -I 9.58 2.60 2.60 11.41 I 0.20 0.20 0.87



### - L 

### ' 6.49 1.80 1.80 ·7.73 I 0.13 0.13 0.59 

# ' 12.88 

### I 3.50 3.50 15.33 

# L 0.27 0.27 1.17 4.60 1.30 1.30 5.72 

# _l 0.10 0.10 0.43



### -- 2.89 0.78 0.78 3.44 

# I 0.06 0.06 0.26 

## , __ 3.01 0.82 0.82 3.58 0.06 0.06 0.27

- 6.67 1.80 1.80 7.94 

# I 0.14 0.14 0.60 42.11 2.00 2.00 8.90 

### 1 ·: o.s7 • 0.87 3.81 

# ·r---

- ! 

# L0.78 i 2.89 0.78 3.44 ! 0.06 0.06 0.26 

# J I
' I ! 

# r I 

## i 

# T PageS**of~** 502 Avg lb/hr Max lb/hr Tons/Year

0.82 0.82 3.58
-----·-· 0.41 0.41 1.79

_J 

### I 

## _j 0.001 0.001 0.01 

### I



# - :::----1 1.10 1.10 0.49 0.49

# 3~:.:.---1 0.80 0.80

- --- 0.25 0.29 1.09 0.98 0.98 4.27. 

# I I**--~-,** 0.65 0.65 2.84 

# j 0.47 0.47 2.08 

### I 0.87 0.87 3.82 

## 1

# ~ 0.33 0.33 1.43 0.20 0.20 0.86 

# -j 0.22 0.22 0.96 0.45 0.45 1.98 

# I 3.10 3.10 13.48 

# -!**---~**

# I 0.01 0.01 0.02 

# JI I 

### I

### ' 

# I

TPOR0145

### ------- --- ----- ·------ ------------------- -----------· --· 

### --- -



# -Eatoon , 0.14 1-(.JI)J •.i --.-------- EQT 0078 I 0. '"

EQT**-~~** H-701 

### EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Pennit Number: 3080-00010-VS Air·Title V Regular Permit Minor Mod 

# I ;--

. <0.01

..**~**

___J 

## ! '



# -! <0.001 <0.0 <0.01 <0 0

Page 6 of8 TPQI=t014S

# I [ Subject Item 

# 1 Entire Facility _J__

FUG 0002 

## ' ' FE 

# ' EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod

ron NOx PM10 

## I 502

...._,_ --..----- wv Avg lb/hr Max lb/hr TonsfYear Avg lb/hr 

## I Max lblhr 

## I Tons/Year 

## I Avg lblhr 

## I Max lblhr 

## I Tons/Year 

## I Avg lb/hr Max lb/hr 

## jTOOsiYW 

# ' I
- 

# ----·--1------
FUG 0003 

### ------ UR GRP 0010 Crude-Gap GRP 0011 

### I HEAVYCAP-1**-~1** GRP 0012 

# I**~~; ~~~-~**  -- - . 

# ----t--r= i
--- 

# 1 1 

# I 

# =1 

# _F

__-, I I I I

# ~-!--_==

- 

# ---,- I 

# __, ' 5.30 I 

# c I 1.so I 5.68 

# _j_ 

# L_._l

I 

## . _I tJH VOLIFR CAP 

### j GRP 0014··
---- VFRIHFR CAP ' GRP -0015

______ NSPS Kb CAP 

# __[ i 

# ____i

____ ---- ---t---l----+---+---+-----+----l----+---1----lc---**]---~~~-=1**

Page 7 of 8 TPOR0145

## EMISSION RATES FOR CRITERIA POLLUTANTS AND C02e AIID: 312- Calumet lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod


## -·-voc·**~----** Lead

# -~ono/Yoar 

# I Subject Item 

### ·j-AV9riilhf. 

# r· ·.;fait lblhr**To~a/Year** 

## j --.A:::v:::g-,lb"'lh=r-ri--.:M.-:a::x;-;l;.,blhr· EnUre Facility ' , 

## I 1

# ---~**-~EUG_0_00_2----~--;-6_8_1**___

# t··**26_~-~--** 117.45 

### -f 

# r

FUG 0003**·---~** .. ·····.

# -·-·····r-- -- . -·i UR : 

## I**~'** I 3.52 

# I GRP 0010**··-!·--~--~~-- ----~------** 

# ~~~~-~**_L_~~~~~;i~----~L.**

# ______""""

__ _ GRP 0012 

# I 9 54 I• 15929 

# r··· - 1

... 1 I 41.77 

# ·r 

# I _ ·-, -4 1.96 ,______ 

### 1

_ -

# --~=**1** HE.\VV CAP-2

. 

### I

# t~~~~~k_**---r~~~-~~~L-~-~**

# [},;~~---~--~~----\-- ..

# ~~**~~** 

# ...J**·---~~~~--** 

# ,,. I_- _J

- [ 35.91 

### 1

--- . . 

# !

. ,

.. .··-··· --- !

# --~ I

------ ... i Note: Emlsalon rates in bold ara from altern•te &cenarios and are not Included In pennitted totals unless otherwise noted in a footnote.

Page 8 of 8 TPQR0\•5Emission Pl I EQT 0020 10

EOT 0021 1\

EOT 0022 14

EQT 0023 15

EQT 0024 

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod·

Pollutant 

# I Avg lb/hr 

# I Max lblhr Ethyl benzene

# ~ 0.01 Toluene O.Q1 Xylene (mixed isomers) 0.02 n-Hexane 0.01 Ethyl benzene 0.01 Toluene O.Q1 Xylene (mixed isomers) 0.03 n-Hexane 0.02 Ethyl benzene O.Q1 Toluene O.Q1 Xylene (mixed isomers) O.Q3 n-Hexane 0.02 Ethyl benzene O.Q3 Toluene 0.02 Xylene (mixed isomers) 0.15 n-Hexane 0.09 Ethyl benzene 0.06 TonsNear 

# !



# _____j I 

# I



# I I" ----------·t---------1 -- _ _.J

# ~---------------!

# ___**~**

# __j

__ o_.o_4

___ 

# -+------------J ' 

# I I 1 xytene (mixed isomers) 

# [


# ___ 0.29 

### In-Hexane 

### --- 0.76 EQT 0025 Ethyl benzene 0.03 17 Toluene 0.02 Xylene (mixed isomers) 0.14 n-Hexane 0.09 EOT 0026 Ethyl benzene 0.06 16 Toluene 

# I 

# _j_ 0.04 

# -------l
I 

# l I

Xylene (mixed isomers) 0.29 n-Hexane 

# I 0.76 

# I EOT 0027 Ethyl benzene 

# I 0.01 19 Toluene 0.01 Xylene (rruxed 1somers) 0.01 

# L ·- 0.01 

# .

------ -------------- --+----- 

# I**~QT** 0028 IEthyl"benzene 0.01 

# J

Page 1 of 8 • TPOR0146

### EMISSION RATES FOR TAP/HAP & 

### OTHER POLLUTANTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080.()001O-V6 Air
- Title V Regular Permit Minor Mod



### ----,---------··- Pollutant : Emlsolon Pt. 

# I IEOT**00~---·** 

### ----+-----'---- TonsNear Avg lb/hr Max lb/hr 

### !2 

# I Toluene ·----· 1Xy1ene (rrixed isomers_)--- jn-Hexane 0.01 002 I I


# .-·=i-

..---_-_-_- __-, -0-.0-1 

# --+-1

___ _____,

·- 

# ·---- EOT 0029 

# ,.

··--·-· EQT 0030 

# ,,

L._

__----·-----. 

# I;,01 0031
' I 

# I
---- 1EQT 0032



# "

EOT 0033 

# ,.



# I EOT 003ot 

# "

1-EOT 0035 

# .,. ]Ethyl benzene I 001 

# I



# ___t=·-----**--~~-~:~---± ---~11**  I a.a1**------~-** 

### · ------- 

# ----1"**-----~---** 

### o.o3 1

_____ __J

---,-·-··-- II

# ~-----1 0.02 

# ------ -. Toluene 

## jxy1ene**(rrix~ iso:~-~** 

## _______ r;-Hexane ;Ethyl benzene**Jh;~eno** 

### --- 

## ' 

# ------r·------- i
-**-~;,-** 

# I**·n--He_xa_n~---------** -- -----..**~** 0.09

# --~~~-benzene ___

# ---:~~~--------!,_ 

# -----**--~--**

# __**-;0~---** __ .._-_-

# _T

1 

### f-----_·

# _---~~~---------1 ·Toluene 1 I 0.02**~**

### ---- !Xylene (rrixod isomers)



# i 0.14 1

----- T--0-.09---+i

____ __, 

# ·---r-·-_-____________ -o_o-3_-_ -_

-_-



# -r_-_-**-----~~-=-____,** ------------+-------,--o._o2

# -~- _

. 1 'Xylene (rrjxed

## isomer~>_______ 

# ! 0.14 

# =1
n-Hexane

__, ____________

### o.og

# -----=1~. Xylene (rrixod isomers)



### --- jn-Hoxano 

### ' 1Elh)i benzene



### ----- .Toluene



### :E1hyt bcnzen_o_____

_ ________ 

### o_.o_3

____

# i J

# jTolucn~---,-------- 

# -----j' o.o2 

# L I**[~~-~no** (mxod tsomerS)

_____ 0_1•_

# ----~-- .. ----- _: !n-Hexano 1 0 09 

# L

# ::~.'-~-~-is-ome-rs-)-- 

# -1**~**

# ..-!-:;;u-.

# ------~-fl-.·_· ---------------1 jn-Hexano
----- 1 J 0.09 [ j



# .

# ---~£~~~~~-.. - __

# -~-------:~~~:-- ..________!__ . ---

# ~-------~-!'.---~~~

, Toluene ., 

### -·----t-
..

Toluene 

# ··--t-..

. --- ,.

Pago 2 of8 0.09 0.03 0.02 I I 

# --·-r- --·---1

TPOR0146Emission Pt. EOT 0036 27
EQT 0037 

# "

- EOT 0038 

# "'

EOT 0039 

# ' '

EOT 0040 

# "'

EQT 0041 

# " 

# .

EOT 0042 

# " 

# I

EOT 0043 

# " EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
Pollutant Avg lb/hr Max lb/hr Xylene (mixed isomers) 0.14 n·Hexane 0.09 Ethyt benzene 0.03 Toluene 0.02 Xylene (mixed isomers) 0.15 n-Hexane 0.09 

### !Benzene 0.01 lcumene <0.001 Ethyl benzene 0.001 Naphthalene <0.001 Toluene 0.01 Xylene {mixed isomers) 0.01 n-Hexane c 0.01

.

.. Ethyl benzene 0.01

Toluene 0.01 Xylene (mixed isomers) 0.02 n-Hexane 

### !_

___ 0.01

# -~ I Ethyl benzene 0.03 

### --· Toluene 

# I 0.02 

## I I

. 

### .. ---- Xylene (mixed isomers) 

# I 0.15 n-Hexane 0.09 Ethyl benzene 0.03 Toluene 0.02 Xylene (mixed isomers} 0.14 n-Hexane 0.09 Ethyl benzene O.D3


### .------- 

# i Toluene 

# I 0.02 

# I ' I Xylene (mixed isomers) 0.14 

# l I n-Hexane 0.09 Benzene 

## ' 0.002 0.002 Toluene <0.001 <0.001 Xylene (mixed isomers) <0.001 <0.001 n-Hexane 0.001 0.001

Page 3 of 8 Tons/Year



## ! 

# ! ·---j 

# J

i



# ______ji**~** 

### ' 

## I 

## ' 0.01 <0.01 <0.01 <0.01'

TPOR0146

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod

# ~~:,**::~-~ion** Pt_ --·--·

# ·\E;~~ be_n.z_e_n_o

_____

# :•_'~~·~~- ____[__

__

# ~·~-~~~'.. : :::

# lblhr

_**-'L·----~** ;,.

## ;r~u-e-ne _____________ -------;---0-.0-2

____[_ ·-· -.·. _·

## ---~ 

# [_____

# :::::~~xed**iso~rs)** ::: 

# I

... ·- -

_ 1 EOT 0045 Ethyt benzene 

# " 0.03 Toluene 

# I 0.02 

# I I-X_y1_e_no_(_mr_·x_ed_iso_mcr_s_l

_______ 

# +-------·--:_j1 _-_--_··_o_.1_4

____

### .!_

___

## i"·~exane 

# ____[_______ 0.09 j 

### IEOT""""i)()46--------.

."""i
..... --- 

### --------i
; 4 !Ethyt benzeno

### ~ i 0.01 !**!~~;~;~-~--------------** 

# ---------!

----------------- _1, ' ' 0 01 

# ' ···-·-· ---- t•••• I 

# ..........._.**-··--·---------~---** 

# ··---·-----,--..........·--. i**f~~~n-e** (rrixed isomers)

__________

## i_____

_____ . 0.02

________

### _j

______ ---i 

# I ln-Hoxane 1 ·. 

# I 0.01 

# I**~~~~~,~~~,~----~1-Bc-"-,-.-".------------+~-------** 

# ..

# r·-- a_o, 

# t-------------+-------+-------11----···-- 1 <0001 Cumene Ethyt bonzono 1 o.oo1 

# _____!

# I-N_•_P"_tha_'"-""-----------+------~~--_-LI__ <_o_:oo_1

____

# !__

# ~-~______·: -·.-- ! Toluene 0.01



## =c==·- ·---·- ---

# ~~~;;~~~~50~~·~~-:====:1-~~--~:~-

# ---·----·--**~~:**

# - . ...... -!
. --·-----. EOT 0048 IEthyt benzene 

## ! 0.01

# !:~~=~::~~~~~)--

# --·---·--:-------·**--~-~~~--~~-** 

# - -----------------1 

# k**f:::;::~ene ~------** **~----_-** ___

# -:-:-2-1----i~---1-------1 I;:.··

# -~- :roluone 0.001 

# j----·-··----

1 

# j;y1ene(n>xedis=ers) [

__

# -=[-~~~~-----~~~~~c--------1 1 

# r>-Hexane 

# I 0 01 J 

# I . ECT 0050 

# " Elhyt benzene

# [Tolu~-""----- 

# r0.001 

### ·-'--- 0.001 :xytene (rnxod isomors) 

# I 0.01**~** 

# '"in--H-e_xa_n_o--------------1 

# l 0.004

--

# --~

# ~c;;a:;-T-;;005='--~----+~n---H-exa_n_e________ -_-_-_-_-_-_-_-_-_-_-_-_-

# t-~~~~<~0~.00=~01 ___ -

# i

1_·

_<_o_.ooo __ 1

___

### 1 __

# <_o_.~~- -----· EOT 0052 jethyt benzene 

# 0.02 

# " ----'-- Page 4 of 8Emission Pt. EQT 0052 57 

# I
EQT 0053 58

EOT 0054 

# • '

EQT 0055 60

EQT 0056 

# "

EOT 0057 67 

# I '--- I EQT 0058 

## I"

EQT 0059 7

EQT 0060 71 

### EMISSION RATES FOR'TAP/HAP 

## & OTHER POLLUTANTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002

. . Permit Number: 3080-0001O-V6 Air- Title V Regular Permil Minor Mod

Pollutant Avg lb/hr Max lb/hr Toluene 

# I 0.01 1 xyrene (mixed isomers) 

# I 0.11 n·Hexane 0.06 Ethyl benzene 0.01 Toluene 0.01 Xylene (mixed isomers) 0.01 n-Hexane O.Q1 Ethyl benzene 0.01 Toluene 

# I 0:01 _......L_ Xylene {mixed isomers) 

# I 0.02 n-Hexane
. 0.01 Ethyl benzene 0.001 Toluene 0.001 Xylene (mixed isomers) O.Q1 n-Hexane 0.01 Ethyl benzene ' 0.03 Toluene 0.02 Xylene (mixed isomers) 0.15 n-Hexane 

# I 0.09 Ethyl benzene 

# I 0.03 Toluene 

# i 0.02 

### ' !Xylene (mixed isomers) 

# i 0.15 n-Hexane 

## ! 0.09 Ethyl benzene 0.01 Toluene 0.01 Xylene (mixed isomers) · 0.02 n-Hexane O.Q1 Ethyl benzene 

# I 0.01 Toluene 0.01 Xylene (mixed isomers) . 0.02

. n-Hexane 0.05 

### Benzene 0.001 O.Q7



# ------------- Ethyl benzene 0.0002 0.02

Page 5 of 8 Tons/Year 

## ! 

# I i '

r----------------' 

# I 

# ] '



# I -- 

# I -;

## I 

# ___jI

I

0.004 0.001

TPOR0146

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AI 10: 

### 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-0001O-V6 Air- Title V Regular Permit Minor Mod 

# i Emisslo_n

# ~-- _ -- :··

# ~~~~~----p~~~~~~;~~~-~-~=~----=-_A•g**lb~'-~_:**___

# -~~--~-·-~~; __ ...J...

# ~~,ar··oooo iToluene_____________________________

# --~~-~~--- o11 

## i Tons/Year 0.01 

## ' 

## r=-=---0062 jXytene (mixed isomers) 0.002 011 073 I I 0.01 1 0.05 ----- i-----

... . ··----,-



### - --"------------

----

## ~n-He)lane . _______

# j

____ 0.01

_______

# l**~Ethyl** benzene___ 

# I 003

# ~1:-:-:-::-·-(~-.-ed-.~-- ..

# -)-------;---------+_--~~~:-:-:-_-__ -_

# ~----1 I 

# I I"Ei:H 0063
. 

# I" I

EOT CICl6A



# "

EOT 0065

EOT 0066 9 

## jn-Hexane 0.09

.. ···:·

# ~:~c:"~"-""------------;-- 

# ----- -----1-----------t----------1 

# ! Xylene

__ (nlx_e_d_ isomers) -----;-··----------- 

# j
-- 003 0.02 0 15 

### -------------'---------- 

# I

# ]--~· n-Hoxano 0.09 O.oJ 

# J

---- 

## I

# ----~-E~th~yl~bc~~n-z_e~ne~~~~~~~~~~-=---------_-___,i,_·~-=---- -_ -_ -_

-_-_-_-_-,-_----- 

## ! 

# I Toluene Xylene (rrlxod isomers) n-Hexane

## ~yt benzene 

### ' :Toluene**~----** !xytcno (mxod isomers) 'n-Hoxano ;Ethyl bcnzono 0.02 I 0.15 

# i ' 0.09 

## ' I 0.01 

## ---1 I --! 

## -------·--·--------t------- 1 001 

## ----·------· -·---- __T

__________J

_______ - 1 0.03 :


# ---- -- ----- --- -- i .-002
. . 0.01 

## , 

# __ --------------------- Toluene 0.01 

# 1-----------+----- -------·------------------1 Xylene (rrlxod isomors) 0.02 n-Hoxano 0.01 

# I

# ~i 006

- 9

--

# ------~~f-~~th~:~:~~nz~o~n~o~~~~~~~~~~~~~~~~~~~~:~~~~:-:_: ________

# ------.~~~~-:--:-~--**---------+~--:-.-=---_-_**-----1
IToiueno 0.49 

# I**----oo-.~**

# 6 ____ . 

# I**7------~**

EOT 0071 

# "' ixyleno (mixod isomors) 0.16**-------~---** 

### ----------

# t.~~~~------ 0.01 

# I 0 01 

# I 0 02 I

# ~~E-1h_Y'_bc_n_zc_n_• _______

# ~~-----~~~~--------l-~----_-:,_~_-_oo_-1-_--_--_- __ +j 1 -_-_<_0_oo_1

___ __,·f--<-O._o_1_ 

# ---l-- ·INaphthaleno <0.001 

# I <0.001 <0.01

### ~~T_ol_u_e_ne------------+--<0 ___

00_1

____ 

# fj-- <0.001 

# -i· <001

### ------~ lxytcno (rrlxod

### i~rs) <0 001 <0.001 

# I

.. _------·· jLJ,n_·H_o_xa_n_•

____________, __ o_o7___ --!

# -0-~7 

# r <0.01 I 

## -J



# I 0.32
Page 6 of 8 TPOR0146Emission Pt. EQT 0085 LO

EOT 0087 

### ww

EQT 0107 OPE

EOT 0108 OPE OWS

FUG 0002 FE 

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AI ID: 312
- Calumel Lubricants Co
- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-0001O·V6 Air·Title V Regular Permit Minor Mod

Pollutant Avg lb/hr Max lblhr Benzene 0.004 0.004 Ethyl benzene 0.01 0.01 Toluene 0.03 0.03

. 0.08 Xylene (mixed isomers) 0.08 n-Hexane O.Q1 0.01 Benzene 0.92 0.92 Ethyl benzene 0.03 0.03 0.31 Xylene (mixed isomers) 0.24 0.24 Benzene 0.06 0.06 Ethyl benzene 0.001 0.001 Toluene 0.01 0.01 Xylene (mixed isomers) 0.01 0.01 n-Hexane 0.02 0.02 Benzene 0.002 0.002 Ethyl benzene <0.001 <0.001 Toluene 

## I <0.001 <0.001 Xylene (mixed isomers) 

# l <0.001 <0.001 n-Hexane 0.001 0.001 Benzene 0.07 0.07 Cumene <0.001 <0.001 Ethyl benzene 0.02 0.02 Methyl isobutyl ketone <0.001 <0.001 Tons/Year 0.02 0.05 0.12 0.35 0.04 4.03 0.13



### -- 1.36 1.04 

# I
0.25 <0.01

0.06 0.02 0.09 0.01 <0.01 

# i <0.01 

### I <0.01 

# I <0.01

0.30 <0.01

0.07 <0.01 Naphthalene 

## j <0.001 

## j 1 <0.001 <0.01 

## f---------------·---- -------··-**-----------~-------------1** Xylene (mixed isomers) 

### Toluene 

# :._!

1 ____ 0 0
..1

15 7 _______

1 1

__ 0 0
..1

17 5

__

### 11 

# !

__ 0 

## o

..

# 74**~** _

# ---~~·

# f-;;;;;;-=.-------·~ln_-H_e_x_a_n• _____ ------------. 0.56 

# ·r 0.56 

# r.. 2.47 

# I GRP 0010 Benzene Crud&-Cao

GRP 0011 HEAVYCAP·1 Cumene Ethyl benzene Ethyl benzene Toluene 

### f--------------- Xylene (mixed isomers)

Page 7 of 8 0.02 0.08 <0.001 <0.01 <0.001 <0.01

0.09 0.40 0.05 0.20 0.37 1.60

TPOR0146

### EMISSION RATES FOR TAP/HAP 

## & OTHER POLLUTANTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-V& Air- Title V Regular Permit Minor Mod -· 

### --·----------------

1 - ---· ---------- -----· Emission Pt. 1--- Pollutant ···-----·-·· 

## I 

# ., Avg lb/hr Max lb/hr Tons/Year 

## IGRP 0011

. HEAWCAP-1 

### IGAP 0012 

## IHE.A\IY CAP·2 

### i n-Hexano ,Benzene**[~thy1_** benzene iToluene 0 23 0.03 0.05 016 i 1.00

.___j

______·-··-···-· _; 010 

# o;o____J .!·---------:

I

-------- 

## o.1o 1 

# I I

# r 0013 !Xylene (ll"¥xed isomers) :n-Hexane 

## ! Ethyl benzene 

### __ -_-----i_

- _-- :::__

# ~o~:-_-----+1

# __ :_:_o_ ----1-

_ 0.001 

### 1 <0.01 ! . iTolucnc <0.01 

# ' ""'"CAl'
i !----------·----·-- !Xylene (mixed isomers) 1-------· ! 

## o001 1 

# --=---,-- 0004

__

# +l_--_-- 0.02 ' GAP 0014 VfRJHFR CloP

GAP 0015 

## INSPS K.b CAP I I I In-Hexane Elhy1 benzene Toluene Xylene (mixed 1somers) n-Hexane Bonzeno Ethyl benzene

### IT~~cno I ·---- !Xylene (ll"¥xcd isomers) 

# r :n-Hexane 

# ' ------;_;,_--nz_-**~-.--_--_--**

# __ _ Cumcnc



### ------ ------- 1Elhy1 benzene



### --- Methyl isobutyt ketone



### -------------

# \~~~~~~~~~-- !Toluene 

# , I**[~~~~ne ~~~~rs)** 

[

________ __ji_n_-_H_e_xane

__ ---'----- j_ I 0 02 1 005 0 01 O.Q2 0003 001 0 10
.

## ------1 -·----__j, 

## o30 

# I 002 006



### .. ---------! 0005 0 02


### -------. 0 02 0 11 0 03 ; 

## ----! 0 15

__ 

## , 0 13 

### i 060 0.05 020 6.17 <0.01

1.23

-- --"j I <0.01 j 

# ---+----- -·- I 1 <0 01 1 

# r- 544

___

# j

____i_ -------· 

# I 

# I 6.s_5--=---1 -------j--- 

# '**-----~1**

# __ 4_.7_2 

### J

. Nole: Emission rates In bok:t are from attemate scenarios and are not Included In piNmltted totals unless otherwise noted in a footnote. Emission rates attributed tothe UNF reflect the sum ofthe TAP/HAP limits ofthe lndlvldualemlaaioo p<Mnts (or ca.ps) underthis permit, but do not constitute an emission cap.

Page 8 of 8 Tf'CR014&

### EQT 0037 28
- 6,000 BBLVFR Storage Tank 

### SPECIFIC REQUIREMENTS AI 

### 10: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod

I [40 CFR 60.116b(b)] Equipment/operational data recordkeeping by electronic or hard copy at the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacityofthe storage vessel. Keep copies ofall records for the· life ofthe source as specified by40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)]
. 

### EQT 0038 29
- 50,000 BBL IFR Storage Tank 2 [40.CFR 60.112b(a)(l)(i)) 

### Equip with a fixed roofin combination with an internal floating roof. The internal floating roofshall rest or float on the liquid surface (but not necessarily in complete contact 

### with it) 

### inside a storage vessel that has a fixed roof. The internal floating roofshall be floating on the liquid surface at all times, except during initial fill and during those intervals when**t~e** 

### storage vessel is completely.emptied or subsequentlY emptied and refilled. When the roofis resting on the leg suppo1:1s, the process offilling, emptying, orrefilling shall be continuous and shall be accomplished as rapidly as possible. Subpart Kb. [40 CFR 60.112b(a)(l)(i)] 3 [40 

### CFR 60.112b(a)(l)(ii)(A)] 

### Equip internal floating roofwith a liquid mounted seaLconsisting ofa foam- or liquid-filled seal mounted in contact with 

### the liquid betweenthe wall ofthe storage vessel and the floating roofcontinuously around the circumference ofthe tank. Subpart Kb. [40 CFR 60.I 12b(a)(I)(ii)(A)J 4 [40 CFR 60.112b(a)(l)(ii)(B)] Equip internal floating roofwith two seals mounted secondaryabove the primary so that each fonnsa continuous closure that completelycovers the space between the wall ofthe storage vessel and the edge ofthe internal floating roo[ The primary seal maybe vapor-mounted, but both must be continuous. Subpart Kb. [40 CFR 60.1 I2b(a)(l)(ii)(B)] 5 [40 

### CFR 60.112b(a)(l)] 

### Eachopening in a noncontact internal floating roofexcept for automatic bleedervents (vacuum breaker vents) and the rim spacevents is to provide a projection below the liquid surface. Equip each opening in the internal floating roofexcept for leg sleeves, automatic bleeder vents,
. rim space vents, column wells, ladder wells, samplewells, and slub drains with a coveror lid and maintain in a closed position at all times (i.e.• rio visible gap) exceptwhen the device is in actual use. Equip the coveror lid with a gasket. Bolt covers on each access hatch and automatic gauge float well except when they are in 

### use. Equip automatic bleedervents with a gasket and closeat all times when the roofis floating except when the roofis being floated offor is being landed on the roofleg supports. Equip rim space vents with a gasket and set to open only when the internal floating roofis not floating orat the manufacturer's recommended setting. Each penetration ofthe internal floating rooffor 

### the purpose ofsampling shall be a sample well. The sample well shall have a slit fabric cover that covers at least 90 percent ofthe opening. Each penetration ofthe internal floating roofthat allows for passage ofa column supporting the fixed roofshall have a flexible fabric sleeve seal ora gasketed sliding cover. Each penetration ofthe internal floating roofthat allows for passage ofa ladder shall have a gasketed slidingcover. Subpart.Kb. [40 CFR 60.112b(a)(l)] 6 [40 

### CFR 60.113b(a)(l)] 

### Tankroofand seals monitored by visual inspection/detennination at the regulation's specified frequency. Inspect the internal floating roof, the primary seal, and the secondary seal (ifone is in service), priorto filling the storage vessel with 

### VOL Ifthere are holes, tears, or otheropenings in the primary seal, the secondary seal, or the_seal fabric or defects in the internal floating roof, orboth, repair the items before filling the storage vessel. Subpart Kb. [40 CFR 60.1 I3b(a)(l)] Which Months: All Year Statistical Basis: None specified

Page 1of49 TPOR0147

### -SPECIFIC-REQUIREMENTS
- AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
EQT 0038 29
- 50,000 BBL IFR Storage Tank 7 [40CFR60.11Jb(a)(2))

8 [40 CFR 60.113b(a)(2))



### 9 [40 CFR 60.11Jb(a)(J)(i))

10 [40 CFR 60.11Jb(a)(3)(11))


### II [40 CFR 60.11 lb(a)(4))

12 [40CFR60.11Jb(a)(4)J

13 [40CFR60.11Jb(a)(5))

14 [40CFR60.115b(a)(l)) Ifthe internal floating roofis not resting on the surface ofthe VOL inside the storage vessel, or there is liquid accumulated on the roof, or the seal is detached, or there arc holes or tears in the seal fabric, repair the items or empty and remove the storage vessel from service within 45 days. Ifa failure that is detected during inspections required in this paragraph cannot be repaired within 45 days and.ifthe vessel cannot be emptied 

### within 45 days, request a 30-day extension from DEQ mthe inspection report required in 40 CFR 60.115b(a)(3). Document in the request for extension that 

### alternate storage capacity is Wlavailable and specify a schedule ofactions the company will take that will asswc that the control equipment will be repaired or lhe vessel will he emplied as soon as possible. Subpart Kb. (40 

### CFR 60.113b{a)(2)) 

### Tank roofand seals monitored by visual inspcctionldctcnnination annually. Inspect the internal floating roofand the primary seal or the secondary seal (1fone is in service) through manholes and roofhatches on the fixed roofat least once every 12 months after initial filL Ifa failure is detected during inspections required in th1s parat.rraph initiate repair provisions. Subpart Kb. [40 CFR 60.113b(a)(2)] Which Months: All Year Statistical Rasis: l\"one spec1fled Tank roofand seals monilored by visual inspectlon/dctermmalion once every five years as specified in 40 

### CFR 60.113b(a)(4). Subpart Kb. (40 

### CFR 60.113b(a)(3)(t)] 

### Which Months: All Year Statistical Rasis: None specified Tank roofand seals momlured by vtsual mspeclionidclerminalion annually

### as specified in 40 

### CFR 60.113b(a)(2) Subpart Kb. (40 

### CFR 60.11 Jb(a)(J)(ti)) 

### Which Months: All Ycar Statistical Basis: None specified Ifthe internal noating roofhas defects. the primary seal has holes, tears, or other openings in the seal or the seal fabric. or the secondary seal has holes. tears, or other openings in the seal or the seal fabric. or the gaskets no longer close oflthe liquid swfaces from the atmosphere, or the sloned membrane has more than I0 percent open area, repair the items as necessary So that none ofthe conditions specified in this

### paragr~ph exist before refilling the storage vessel with 

### VOL In no event shall inspections conducted in accordance with this provision occw at intervals greater than 10 years in the case ofvessels conductmg the annual visual inspection as specified in 40 CFR 60. 113b(a)(2) and (a)(3)(ii) and at intervals no greater than 

### 5 years in lhe case ofvessels spCCJiied in paragraph 40 

### CFR 60.

### IIlb(a)(J)(i) ofthis secuon. Subpart Kb. [40 

### CfR 60.113b(a)(4)] 

### Tank roofand seals monitored by visual inspcctionldctennination at the regulation's specified frequency. Inspect the internal floating roof, the primary seal, the secondary seal (ifone is in service), gaskets, slotted membranes and sleeve seals (ifany) each time the storage vessel is emptied and degassed. Ifa failure is detected dwing inspections required in this paragraph initiate repair provisions. Subpart Kb. [40 CFR 60.113b(a)(4)) 

### Which Months: All Ycar Statistical Basis: None specified Submit notification in writing: Due at least 30 days pnor to the filling orrefilling ofeach storage vessel for which an inspection is required by 40 

### CFR 60.113b(a)(l) and (a)(4) to afford DEQ an opportunily lo have an observer presenl. lflhe inspcelion required byparab'Taph 40 

### CFR 60.11 3b(a)(4) is not planned and the owner or operatorcould not have knOwn about the inspection 30 days in advance or refilling the tank, notify DEQ at least 7 days prior to the refilling ofthe storage vessel. Notify by telephone immediately followed by \loTitten documentation demonstrating why the mspcction wa.-. unplanned. Alternatively, submit notification in writing including the written documentation and send by express mail so that 11 is received by DEQ at leas! 7 days pnor to the refilling. Subpart Kb. (40 CFR 60.lllb(a)(5)) Submil a report: Due lo DEQ as an allachmenllo lhe notificalion required by40 

### CFR 60.7(a)(3). Th1s report shall describe the control equipment and certify thallhe conlroi equtpment meets the specificalions of40 

### CFR 60.112b(a)(I) and 60.11Jb(a)(I). Keep coptes ofall reports for at leas! two years. Subpart Kb. (40 

### CFR 60.115b(a)(I)) Page 2 ol49 TPQR01.c7

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-o0010-V6 Air- Title V Regular Permit Minor Mod
EQT 0038 29
- 50,000 BBL IFR Storage Tank

15 [40CFR60.l15b(a)(2))

16 [40CFR60.115b(a)(3))

17 [40 CFR 60.115b(a)(4)]

18 [40CFR60.116b(b)]

!9 [40CFR60.116b(c))

20 [40 CFR 60.116b(d)] 21 [LAC 33:I!L2103.B] 22 [LAC 33:l!T.2103.C.I.a] 23 [LAC 33:I!L2103.C]

24 [LAC 33:l!T.2103.E.l]

25 [LAC 33:1!1.2103.H.3] 26 [LAC 33:l!T.2103.1] 

### Inspection records recordkeeping by 

### electronic orhard copyupon each 

### occurrence ofinspection,

### per40 CFR 60.!!3b(a)(l) through (4). Each record shall identifythe storage vessel on which the inspection was performed and shall contain the date the vessel was inspected and the 

### observed condition ofeach component ofthe control equipment (seals, internal floating roof, and fittings). Keep copies ofall records for at least two years. Subpart Kb. (40 CFR 

### 60.115b(a)(2)] Submita report: 

### Due to DEQ within 30 days ofthe annual visual inspection required by40 CFR 60.!13b(a)(2) that 

### detects any ofthe conditions described 

### in

# 4o CFR60.113b(a)(2). Each report shall identifythe storage vessel, the nature ofthe defects, and the date the storage vessel was emptied orthe nature ofand date the repair was made. Keep copies ofall reports for at least two years. Subpart Kb. (40 CFR 60.115b(a)(3)] Submit a report: Due to DEQ within 30 days ofeach inspection required by 40 CFR 60.!13b(a)(3) that finds holes or tears in the seal or seal fabric, ordefects in the internal floating roof, orother control equipment defects listed in 40 CFR 60.113b(a)(3)(ii). The report shall identifythe storage vessel and the reason it did not meet the specifications of40 CFR 61.112b(a)(l) or40 CFR. 60.!13b(a)(3) and list each repair made. 

### Keep copies ofall reports for at least two years. Subpart Kb. (40 CFR 60.115b(a)(4)] Equipment/operational data recordkeeping byelectronic orhard copyat the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an aflalysis showing'the capacityofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)] 

### VOL storage data reCordkeeping by electronic orhard copyat the approved frequency. Records consist ofthe 

### VOL stored,.the period ofstorage, and the maximum true vapor pressure ofthat 

### VOL during'the respective storage period. Keep.copies ofall records for at least two years... Subpart Kb. (40 CFR 60.116b(c)] Submit notification: Due within 30 days whenthe maximumtrue vapor pressure ofthe liquid exceeds the respective maximum true vapor pressure values for each volume range. Subpart Kb. [40 CFR60.116b(d)] Equip with a submerged fill pipe. Equip internal floating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted 

### in contact with the liquid between the Wall ofthe storage vessel and the floating roofcontinuously around the circumference ofthe tank Equip with an internal floating roofconsistingofa pontoon type roof, double deck roof, or internal floating coverwhich will rest or float on the surface ofthe liquid**c~ntents** 

### and is equippedwith a closure seal to close the space between the roofedge and tank wall'. All**t~nk** 

### gauging and samplingdevices will be gas-tight except when gauging or sampling is taking place. 

### VOC, Total>= 95% control efficiency using a vapor loss control system. This limitation does not apply during periods ofplanned rqutine maintenance which may notexceed 240 hours peryear. Which Months: All Year Statistical Basis: None specified 

### Determine VOC maximum 

### true vaporpressure using the methods in LAC 33:1!1.2103.H.3.a-e. Equiprilent/operational data recordkeeping byelectronic orhard copyat the regulation's specified frequency. Keep records ofthe information specified in LAC 

### 33:111.2103.1.1

- 7, as applicable. · 

### EQT 0040 30
- 6,500 BBLVFR Storage Tank

27 [40CFR60.116b(b)] 

### Equipment/operational data recordkeeping by electronic or**har~** 

### copyat the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by40 CFR 60.!!6b(a). Subpart Kb. (40 CFR 60.116b(b)] Page 3 of49 TPOR0147

### ·- SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-{)0010-V& Alr- Title V Regular Permit Minor Mod
EQT 0042 32
- 20,000 BBL VFR Storage Tank

28 [40 CFR 60.116b(b)j 

### Equipment/operational data rccordkeeping 

### by electronic or hard copyat the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity

### ofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by 40 CFR 60.116b(a). Subpan Kb. [40 CFR 60.116b(b)] 

### EQT 0043 33
- 20,000 BBL IFR Storage Tank

29 [40 CFR 60.112a(a)(2)}



### 30 [40CFR60.115aj


### 31 [LAC 33:111.2103.!!} 

### 32 [LAC lliii.2103.BI 

### 33 [LACJ31112103CJ


### 34 [LAC lliii2103.E I}

35 [LAC ll:III.2103.H.3J 

### 36 [LAC 33:111.21031} 

### Equip with a fixed roofand an internal floating type cover having a continuous Closwe device between the tank wall and the cover edge. The cover is to be floating at all times, (i.e., ofTthe leg supports) except during initial fill and when the tank is completelyemptied and subsequently refilled. The process ofemptying and refilling when the cover is resting on the leg supports shall be continuous and shall be accomplished as rapidly as possible. Each opening in the cover except for automatic bleeder vents and the rim space vents is to provide a proJection below the .liquid surface. Equip each opening in the cover except for automatic bleeder vents, rim space vents, stub drains and leg sleeves wtth a cover, seal, or lid and maintain in a closed position at all times (i.e., no visible gap) except when the device is in actual usc. Close automatic bleeder vents at all times when the cover is floating except when the cover is being floated ofTor is being landed on the leg support.;;. Set rim vents to open only when the cover is being floated ofTthe leg supports or at the manufacturer's recommended setting. Subpart 

### K.a. (40 CFR 60.112a(a)(2)] Petroleum liquid storage data 

### recordkeeping by electronic or hard copy at the approved frequency. Maintain a record ofthe petroleum liquid stored, the period ofstorage, and the maximum true vapor pressure ofthat liquid during the respective storage period,'except as provided m40 CFR 60.1 ISa(d). Subpan Ka. Equip with a submerged fill pipe. Maintain working pressures sufficient at all times under normal operatingconditions to prevent vapor or gas loss to the atmosphere. Equip with an internal floating roofconsisting ofa pontoon type roof, double deck roof, or internal floating cover which will rest or float on the surface ofthe liquid contents and is equipped with a closure seal to close the space between the roofedge and tank wall_ All tank gauging and sampling devices will be gas-tight except when gauging or sampling is taking place. VOC. Total >.. 

### 95 %control efftctencyusing a vapor loss control system. This limitation docs not apply during periods ofplanned routine maintenance which may not exceed 240 hours per year. Which Months: All Year Statistical Basis: None specified Determine VOC maximum true vapor pressure using the methods iO LAC 33:1li.2103.H.3.a-e. Equipment/operational data recordkeeping by electronic or hard copy at the regulation's specified frequency. Keep records ofthe information specified in LAC 33:111.2103.l.i

- 7. as applicable. 

### EQT 0047 47
- 80,000 BBL IFR Storage Tank

37 [40 CfR 60 112b(a)(l)(i)j 

### Equip with a fixed roofin combination with an internal noating roof. The internal floating roofshall rest or float on the liquid surface (but not necessarily in complete contact with it) inside a storage vessel that 

### has a fixed roof. The internal floating roofshall be floating on the liquid

### ~urface al all times, except during iniual fill and during those intervals when the storage vessclts completelyemptied orsubsequently emptied and refilled. When the roofis resting on the leg suppons, the process offilling, emptying, or refilling shall be 

### continuous and shall be accomphshed as rapidly as possible. Subpan Kb. [40 CFR 60.il2b(a)(l)(i)] Page 4 of49 TPOR0141

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 • Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
EQT 0047 47- 80,000 BBL IFR Storage Tank

38 [40 CFR 60.112b(a)(J)(ii)(A)) Equip internal floating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in contact with the liquid between the wall ofthe storage vessel and the floating roofcontinuously around the circumference ofthe tank. Subpart Kb. [40 CFR 

### 60.112b(a)(l)(ii)(A)] 39 [40 CFR 60.112b(a)(l )(ii)(B)) Equip internal floating roofwith two seals mounted secondary above the primary so that each forms a continuous closure that completelycovers the space between the wall ofthe storage vessel and the edge ofthe internal floating roof. The primary seal may be vapor-mounted, but both must be continuous. Subpart Kb. [40 CFR 

### 60.112b(a)(I)(ii)(B)] 40 [40 CFR 60.112b(a)(l)] Each opening in a noncontact internal floating roofexcept for automatic bleedervents (vacuumbreaker vents) and the rim space vents is to provide a projection below the liquid surface. Equip each opening in the internal floating roofexcept for leg sleeves, automatic bleeder vents, rim space vents, colU11U1 wells, ladder wells, sample'wells, and stub drains with a cover or lid and maintain in a closed

### posit~on at all

### tim~s (i.e., no visible gap) except when the device is in actual use. Equip the coveror lid with a gasket. Boltcovers on each access hatch and automatic gauge float well except when they are in use. Equip automaticbleeder vents with a gasket and close at all times when the roofis floating except when the roofis being floated offor is being landed on the roofleg supports
.. Equip rim space vents with a gasket and set to open only when the internal floating roofis not floating or at the manufacturer's recorrunended setting. Each penetration ofthe internal floating rooffor the purpose ofsampling shall be a samplewell. The sample well shall have a slit fabric coverthat 

### covers at least 90percent ofthe opening. Each penetration ofthe internal floating roofthat allows for passage ofa column supporting the fixed roofshall have a flexible fabric sleeve seal or a gasketed slidingcover. Each penetration ofthe internal floating roofthat allows for passage ofa ladder shall have a gasketed sliding cover. Subpart Kb. [40 CFR 

### 60.112b(a)(I)] 41 [40 CFR 60.113b(a)(l}] Tank roofand seals monitored by visual inspection/determination at the regulation's specified frequency. Inspect the internal floating roof. the primary seal, and the secondary se31 (ifone is in service), prior to filling the storage vessel with VOL. Ifthere are holes, tears, orother openings in the primary seal, the secondary seal, or the seal fabric ordefects in the internal floating roof, orboth, repair the items before filling the storage vessel. Subpart Kb. [40 CFR 

### 60.113b(a)(l)] Which Months: All Year ·Statistical Basis: None specified 42 [40 CFR 60.113b(a)(2)] ·Ifthe internal floating roofis notresting on the surface ofthe VOL inside the storagevessel, orthere is liquid accumulated on the roof, or the seal is detached, orthere are holes or tears 

### inthe seal fabric, repair the items orempty and remove the storage vessel from service within 45 days. Ifa failure that is detected during inspections required in this paragraph cannotbe repaired within 45 dayS and ifthe vessel cannot be emptied within 45 days, request a 30-day extension from DEQ in the inspection report required in 40 CFR 

### 60.115b(a)(3). Document in the request for extension that alternate storage capacity is unavailable and specify a schedule ofactions the companywill take that will assure that the control equipment"will be repaired or the vessel will be emptied as soon as possible. SubpartKb. [40 CFR

### 60.113b(a)(2)] 43 [40 CFR 60.113b(a)(2)) Tank roofand seals monitored byvisual inspection/determination annually. Inspect the internal floating roofand the primary seal or the secondary seal (ifone is in service) through manholes and roofhatches on the fixed roofat least once every 12 months after initial 

### fill. Ifa failure is detected during inspections required in this.paragraph initiate repairprovisions. Subpart Kb. [40 CFR 

### 60.113b(a)(2)] Which Months: All Year Statistical Basis: None specified · 44 [40 CFR 60.113b(a)(3)(i)) Tank roofand seals monitored byvisual inspection/determination once every five years as speCified in 40 CFR 

### 60.113b(a)(4). Subpart Kb. [40 CFR 

### 60.113b(a)(3)(i)] Which Mo.nths: All Year
.Statistical Basis: None specified. 45 [40 CFR 60.113b(a)(3)(ii)) Tank roofand seals monitored by visual inspection/determination annually as specified in 40 CFR 

### 60.113b(a)(2). Subpart Kb. [40 CFR 

### 60.113b(a)(3)(ii)] Which Months: All Year Statistical Basis: None specified Page 5 of 49 TPOR0147 

# '
/

### SPECIFIC REQUIREMENTS AIID: 312 -Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air- Title V Regular Permit Minor Mod 

### --- ---- -------·



### EQT 0047 47
- 80,000 BBL IFR Storage Tank

46 (40 CFR 60.lllb(a)(4)]

47 (40 CFR 60.lllb(a)(4)]

48 [40 CFR 60.11 lb(a)(S)]

49 [40 CFR 60.115b(a)(I)]

50 [40 CFR 60.115b(a)(2)]

51 (40 CFR 60.115b(a)(l)]

52 [40 CFR 60.115b(a)(4)]

53 [40 CFR 60.116b(b)] Ifthe internal floating roofhas defects, the primary seal has holes, tears, or other openings in the seal or the seal Iabrie, or the secondary seal has holes, tears, or other openings in the seal or the seal fabric, or the gaskets no longer close ofTthe liquid surfaces from the atmosphere, or the stoned membrane has more than I0 percent open area, repairthe items as necessary so that none ofthe conditions specifted in this paragraph 

### exist before refilling the storage vessel with VOL In no event shall mspections conducted in accordance with this provision occurat intervals greater !han 10 years in lhe case ofvessels conducting lhe annual visual inspection as specified in 40 CFR 60.113b(a)(2) and (a)(3)(ii) and al intervals no greater !ban 5 years m lhe case ofvesselsspecified in paragraph40 CFR 60.113b(a)(3)(i) ofthis section. Subpart Kb. [40 CFR 60.113b(a)(4)] Tank roofand seals monitored by visual inspection/determination at the regulation's specified frequency. Inspect the internal lloating roof, the primary seal, the secondary seal (ifone is in service), gaskets, slotted membranes and sleeve seals (ifany) each time the storage vessel is emptied and degassed. 

### Ifa failure is detected during inspections required in this paragraph initiate repair prov1sions. Subpart Kb. !40 

### CFR 60.113b(a)(4)] Which Months: 

### All Year Statistical Basis: None specif1ed Submit notification in writing: Due at least 30 days prior to the fill.ing or refilling ofeach storage vessel for which an inspection is required by 40 CFR 60.113b(a)(l) and (a)(4) lo afford DEQ an opportunity 10 have an observerpresent lflhe inspection required by paragraph 40 CFR 60.113b(a)(4) is not planned and the owner or operator could not have known about the inspection 30 days in advance or refilling the tank, notify DEQ at least 7 days prior to the refillmg ofthe storage vessel.**~oufy** 

### by telephone immediately followed by wrincn documentation demonstrating why the inspectionwas unplanned. Alternatively, submit notification in writing including the written dOcumentation and send by express mali so lhal il is received by DEQ alleasl 7 days prior 10 the refilling. Subpart Kb. [40 CFR 60.113b(a)(5)] Submit a report: Due to DEQ as an anachment to the notification reqmred by 40 

### CFR 60.7(a)(3). This report shall describe the control eqmpmenl and certify lhallhe control equipment meels lhe spcc1fical!Ons of40 CFR 60.112b(a)(I) and 60.113b(a)(I). Keep copies ofall reporl.< for al leasllWo years. Subpart Kb. [40 CFR 60.115b(a)(I)] Inspection records recordkecpingbyelectronic or hard copyupon each occurrence ofinspection, per 40 

### CFR 60.1 I

### 3b(a)(1) through (4): 

### Each record shall identify the storage vessel on which the inspection was 

### performed and shall contain the date the vCssel was inspected and the observed condition ofeach component ofthe control equipment (seals, internal noating roof. and fittings). Keep copies of

### all records for at least two years. Subpart Kb. [40 CFR 60.115b(a)(2)] Submit a report: Due lo DEQ wnhin 30 days oflhe annual visual inspection reqUired by40 CFR 60.113b(a)(2) !hal deleciS any oflhe condillons described in 40 CFR 60.113h(a)(2). Each report shall identify the storage vessel, the nature ofthe defects, and the dale the storage vessel was emptied or lhe nature ofand dale lhe repair was made. Keep copies ofall reports for al leas! lwo years. Subpart Kb. [40 CFR 60.115b(a)(3)] Submit a report: Due lo DEQ within 30 days ofeach inspection required by 40 CFR 60.113b(a)(3) lhal finds holes or tears in the seal orseal fabric, or defects in the internal floating roof, orother control equipment dCfects listed in 40 

### CFR 60.113b(a)(3)(ii). The report shall identify lhe storage vessel and the reason 11 did nol meel lhe specifications of40 CFR 61.112b(a)(I) or 40 CFR. 60.113b(a)(3) and list each repair made. Keep copies ofall reports**fo~** 

### al leas! lwo years. Subpart Kb. [40 CFR 60.115b(a)(4)] Equipment/operational data recordkeeping by electronic or hard copy at the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and 

### an analysis showing the capacityofthe storage vesseL Keep copies ofall records for the life ofthe sowee as specified by40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)]
Page 6C?f

### 49 TPQA01
..7

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 • Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
EQT 0047 47- 80,000 BBL IFR Storage Tank

54 [40 CFR 60.116b(c)]

55 [ 40 CFR 60.116b(d)] 56 [LAC 33:111.2103.8] 57 [LAC 33:111.2103.C.I.a] 58 [LAC 33:111.2103.CJ

59 [LAC 33:lii.2103.E.I]

60 [LAC 33:lii.2103.H.3] 61 [LAC 33:111.2103.1] VOL storage data recordkeeping 

### by electronic or hard copyat the approved frequency. Records consistofthe VOL stored, the period ofstorage, and the maximum true vaporpressure ofthat VOL during·the respective storage period. Keep copies ofallrecords for at least two years. Subpart Kb. [40 CFR 60.116b(c)] Submit notification: Due within 30 days when the maximum true vapor pressure ofthe liquid exceeds the respective maximum true vapor pressure values for each volume range. Subpart Kb. [40 CFR60.116b(d)] Equip with a submerged fill pipe. Equip internal floating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in contactwith the liquid between the wan ofthe storage vessel and the floating roofcontinuously arowtd the circumference ofthe tank. ·Equip with

### a~ internalfloating roofconsisting ofa pontoon'type·roof,'dOuble deck roof, or internal floating coverwhich will rest or float on the surface ofthe liquid contents and is equipped with a closure.seal to close the space between the roofedge and tank wall. All tank gauging and sampling devices will be gas-tight exceptwhen gauging orsampling is taking place.
..... VOC, Total>= 95% control efficiency using a vapor loss control system. This limitation does not apply during periods ofplanned routine maintenancewhich maynot exceed 240 hours peryear. Which Months: All Year Statistical Basis: None specified
. Determine VOC**maxirnu~** true vapor**pr~ssure** usingthe methodS in LAC 33:III.2103.H.3.a-e. Equipment/operational data recordkeeping by electronic orh_ard copyat the regulation's specified frequency. Keep records ofthc information

.specified in LAC 33:III.2103.1.1 -7, as applicable. 

# "'· J,, 

### EQT 0049 54- 10,000 BBL IFR Storage Tank

62 [40 CFR 60.112b(a)(I)(i)] Equip with a fixed roofin combination with an internal floating roof. The internal floating roofshall rest or float on the liquid surface (butnot necessarilyin complete contactwith it} inside a storage vessel that has a fixed roof. The internal flOating roofshall be floatingon the liquid surface at all times, except during initial fill and during·those intervals when the storage vessel is completely emptied orsubsequentlyemptied andrefilled. Whenthe roofis resting onthe leg supports, the process offilling, emptying, or refilling shallbe continuous and shall be accomplished as rapidly as possible. Subpart Kb. [40 CFR 60.112b(a)(l)(i)] 63 [40 CFR 60.112b(a)(l)(ii)(A)] Equip internal floating roofwitha liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in contactwith the liquid between the wall ofthe storage vessel and the floating roofcontinuouslyaround the circumference ofthe tank. SubpartKb. [40 CFR 60.II2b(a)(l)(ii)(A)] 64 [40 CFR 60.112b(a)(l)(ii)(B)J Equip internal floating roofwith tWo**se~ls** mounted secondaryabove the primary so that each forms a continuous closure that completelycovers the space between the wall ofthe storage vessel and the edge ofthe internal floating roof. The primary sealmaybe vapor-molfnted. butboth mustbe continuous. Subpart Kb. [40 CFR60.112b(a)(l)(ii)(B)]

Page 7 of49 TPOR0147

### - -SPECIFIC.REQUIREMENTSAIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
EQT 0049 54- 10,000 BBL IFR Storage Tank

65 (40 CFR 60.112b(a)(I)J



### 66 (40 CFR 60.11lb(a)(I)J

67 [40CFR 60.11lb(a)(2)J



### 68 (40 CfR 60 lllb(a)(2))



### 69 (40 CfR 60.113b(a)(3)(1))

70 [40 CFR 6U.IIlb(aXJXii)J Each opening in a noncontact internal floating roofexcept for automatic bleeder vent.:; (vacuwn breaker vents) and the urn space vents is to provide a projection belowthe liquid surface. Equip each opening in the mtcmal floating roofexcept for leg sleeves, automatic bleeder vents, nm space vents, column wells, ladderwells, sample wells, and stub drains with a cover or lid and maintain in a closed position at all times (i.e., no visible gap) except when the device is in acrual use. Equip the cover or lid with a gasket. Bolt covers on each access hatch and automatic gauge float well except when they are in usc. Equip automatic bleedervents with a gasket and close at all times when the roofis floating except when the roofis being floated offor is being landed on the roofleg supports. Equip rim space vents with a gasket and set to open only when the internal floatmg roofis not floating orat the manufacturer's recommended setting_ Each penetration ofthe internal floating rooffor the purpose ofSampling shall be a sample welL The sample well shall have a slit fabric cover that covers at least 90 percent ofthe opening_ Each penetration ofthe internal floatmg roofthat allows for passage ofa column supporting the fixed roofshall have a flex1ble fabric sleeve seal ora gasketed sliding cover. Each penetration ofthe internal floating roofthat allows for passage ofa ladder shall have a gaskcted shdingcover 

### Subpart Kb. (40 CFR 60.!!2b(a)(!)) Tank roofand seals monitored by visual inspection/determination at the_ regulation's specified frequency. Inspect the mtcrnal floatmg roof, the prima:ry seal, and the secondary seal {ifone is in service). prior to filling the storage vessel with VOL. Ifthere arc holes, tears. or other openings in the primary seal, the secondary seal, or the seal fabric ordefects in the intemal floating roof, or both, repair the items before filhng the storage 

### vessel. Subpart Kb. [40 CFR 

### 60.!!3b(a)(l)) Which Months: All Year Statistical Basis: None specified Ifthe internal floating roofis not resting on the surface ofthe VOL inside the storage vessel. or there is liquid accumulated on the roof. or the scal1s detached, or there are holes or tears in the seal fabric, repair the items or emplyand remove the storage vessel from scrv1cc within 45 days. Ifa failure that IS detected during mspections required in this paragraph cannot be repaued within 45 days and 1fthe vessel cannot 

### be empt1ed wlthm 45 days. request a 30·day extension from DEQ in the mspection report required 10 40 CFR 60. II5b(a)(3). Document m the request for extension that alternate storage capacity is unavailable a:nd specify a schedule ofactions the companywill take that will assure that the control 

### eqlllpmenl Will 

### be repaired or the vessel will be emplicd as soon as pomble. Subpart Kb (40 CFR 60.1!3b(a)(2)] Tank roofand seals monitored by visual inspectionldctennination annually. Inspect the internal floating roofand the primary seal or the secondary seal (ifone is in service) through manholes and roofhatches on the fixed roofat least once every I2 months after initial fill · Ifa failure is detectedduring inspections required in this paragraph imtiate repair provisions. Subpan Kb. 

### [40 C.FR 

### 60.11Jb(a)(2)J Which Months: All Year Statisucal Basis: None specified 

### Tank roofand seals monitored by v1sual inspccllon/dclcrminalion once every five years as specified in 40 CFR 60.!13b(a)(4). Subpart Kb. (40 CFR 60.113b(a)(3)(i)] Which Months: All Year Statistical Basis: !\:one specified 

### Tank roofand seals moni10red by visual inspecllon/delermination annually as specified in 40 CFR 60.!!3b(a)(2). Subpart Kb. (40 

### CFR 60.113b(a)(3)(ii)] Which Months: All Ycar Statistical Bas1s: None specified

Page 8 of 49 TPOA0147

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery ' Activity Number: PER20120002 Permit Number: 3080-Q0010-V6 Air- Title V Regular Permit Minor Mod
EQT 0049 54- 10,000 BBL IFR Storage Tank

71 [40 CFR 60.113b(a)(4))

72 [40 CFR 60.113b(a)(4))

73 [40 CFR 60.11Jb(a)(5))

74 [40 CFR 60.115b(a)(l))

75 [ 40 CFR 60.115b(a)(2))

76 [40 CFR 60.115b(a)(J))

77 [40 CFR 60.115b(a)(4))

78 [40 CFR 60.116b(b)) Ifthe internal floating roofhas defects, the primary seal has holes, tears, orotheropenings in the seal or the seal fabric, or the secondary seal has holes, tears, or otheropenings in the seal or the seal fabric, orthe gaskets no longer close offthe.liquid surfaces from the atmosphere, or the slotted membrane has more than I0 percent open area, repair the items as necessary so that none ofthe conditions specified in this paiagraph exist before refilling the storage vessel with VOL. In no event shall inspections.conducted in accordance with this provision occurat intervals greater than 10 years in the case ofvessels conducting the annual visual inspection as specified in 40 CFR 60.!13b(a)(2) and (a)(3)(ii) and at intervals no greater than 5 years in the case ofvessels specified in paragraph 40 CFR 60.113b(a)(J)(i) ofthis section. Subpart Kb. [40 CFR 60.113b(a)(4)] Tankroofand seals monitored by visual inspectionldetennination at the regulation's specified frequency. Inspect the internal floating roof, the primary seal, the secondary seal 

### (ifone is in service), gaskets, slotted membranes and sleeve seals 

### (ifany) each time the storage vessel is emptied 

### and degassed. Ifa failure is**detec~ed** 

### during inspections required in this**pa~agraph** 

### initiate repairprovisions. Subpart Kb. [40 CFR 60.!!3b(a)(4)] Which Months: All Year Statistical Basis: None specified
. . Submit notification in writing: Due at least 30 days prior to the filling'or refilling ofeach storage vessel for which an inspection is required by 40 CFR 60.113b(a)(I) and (a)(4) to afford DEQ an opportunityto have an observerpresent. Ifthe inspection required byparagraph 40 CFR 60.1!3b(a)(4) is notplanned and the owneroroperator could not have known aboutthe inspection 30 days in advance or refillingthe tank, notifY 

### bEQ at 

### least 7 days prior to the refilling ofthe storage vessel. 1'J'otify by

### telephone immediately followed by written documentation demonstratingwhythe inspection was unplanned. Alternatively, submit notification in writing including the written documentation and send by express mail so that it is received by DEQ at least7 days priorto the refilling. Subpart Kb. [40 CFR 60.!!3b(a)(5)] Submita report: Due to DEQ as an attachmentto the notification required by 40 CFR 60.7(a)(3). This report shall describe the control equipmentand certifY that the control equipmentmeets the specifications of40 CFR 60.!!2b(a)(l) and 60.113b(a)(l). Keep copies ofall reports for at leasttwo years. Subpart Kb. [40 CFR 60.115b(a)(!)] '· Inspection records recordkeepingbyelectronic or hard copyupon each occurrence ofinspection, per40 CFR 60.113b(a)(l) through (4). Each record shall identifythe storagevessel onwhich the inspection.was performed and shall contain the date the vessel was inspected and the observed condition ofeach component ofthe control equipment (seals, internal floating roof, and fittings). Keep copies ofall records for at least two years. Subpart Kb. [40 CFR 60.115b(a)(2)] · Submit a report: Due to DEQ within 30 days ofthe annual visual inspection required by40 CFR 60.113b(a)(2) that detects anyofthe conditions described in 40 CFR 60.113b(a)(2). Each report shall identifY the storage vessel, the nature ofthe defects, and the date the slorage vessel was emptied or the nature ofand date the repair was made. Keep copies ofall reports for at least two years. Subpart Kb. [40 CFR 60.115b(a)(3)] Submit a report: Due to DEQ within 30 days ofeach inspection required by40 CFR 60.113b(a)(3) that finds holes orteafs in the seal o,r seal fabric, ordefects in the internal floating roof, orother control equipment defects listed in 40 CFR 60.113b(a)(3)(ii). The report shall identifY the storage vessel and the reason it did not meetthe specifications of40 CFR 6!.!12b(a)(I) or40 CFR. 60.113b(a)(3) and list each repairmade. Keep copies ofall reports for at least two years. Subpart Kb. [40 CFR 60.115b(a)(4)] Equipment/operational data**recordke~ping** by electronic orhard copyat the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vessel. Keep copies ofall recordS for the life ofthe source as specified by40 CFR 60.!!6b(a). Subpart Kb. [40 CFR 60.116b(b)]

Page 9 of 49 TPOR0147

### SPECIFIC REQUIREMENTS AIID: 312 -Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-V&** 

### Air- Title V Regular Permit Minor Mod
EQT 0049 54- 10,000 BBL IFR Storage Tank

79 [40 CFR 60.116b(c)]
80 [40 CFR 60.116b(d)] 81 [LAC 33:111.2103.8] 

### 82 (LAC 33:111.2103.C.J.a] 83 (LAC Jl"lll2103 C]

84 (LAC 33:111.2103.£ 1

### I

85 [LAC 33:111.2!03.H.3] 86 [LAC 33111.21031] VOL storage data rccordkecping by electronic or hard copy at the approved frequency. Records consist ofthe VOL stored, the period ofstorage, and the maximum true vapor pressure ofthat VOL during the respective storage period. Keep copies ofall records for at least two years. Subpart Kb.(40 CFR 60.116b(c)] Submit notification: Due within 30 days when the f!ta:<imum true vapor pressure ofthe liquid exceeds the respective maximum hUe vapor pressure values for each volume range. Subpart Kb. [40 CFR 60.1 16b(d)] Equip 

### with a submerged fill pipe. · Equip internal noating roofwith a liqmd mounted seal consisting ofa foam- or liquid-filled seal mounted in contact with the liquid between the wall ofthe storage vessel and the floating roofcontinuously around the circumference ofthe tank. Equip with an internal floatmg roofconsisting ofa pontoon type roof, double deck roof, or internal floating cover which will rest or float on the surface ofthe hquid contents and is equipped with a closure seal to close the space bctv.·ecn the roofedge and tank wall. All tank gaugmg and sampling devices will be gas-tight except when gauging or sampling JS taking place. VOC, Total >= 95 %control efficiency

### using a vapor loss control system. This limitation docs not apply during periods ofplanned routine maintenance which may not exceed 240 hours per year. Which Months: All Year Statistical Basis:**~one** specified Determine VOC maximum true vapor pressure using.the methods in LAC 33:ll1.2103.11.3.a-e. Equipment/operational data recordkeeping by electronic_or hard copyat the regulation's specified frequency. Keep records ofthe information speCified in LAC 33:111.2103.1.1

- 7. as applicable. 

### EQT 0050 55- 10,000 BBL IFR Storage Tank

87 [40 CFR 60.112b(a)(I)(i)] Equip with a fixed roofin combination with an internal floating roof. The internal floating roofshall rest or float on the liquid surface (but not necessarily in complete contact with it) inside a storage vessel that 

### has a fixed roof. The internal floating roofshall be floatingon the liquid surface at all times, except during initial fill and during those intervals when the storage vessel is completely emptied or subsequently emptied and refilled. When the roofis resting on the leg supports, the process offilling, emptying, or refilling shall be continuous and shall be

. accomplished as rapidly

# a.• pombie. Subpart Kb. [40 CFR 60. I 12b(a)(I)(i)] 88 [40 CFR 60.112b(a)(l)(•i)(A)] Equip internal floating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in conlact with the liquid between the wail ofthe storage vessel and the floaling roofcontinuously around !he circumferenceoflhe lank. Subpart Kb. [40 CFR 60. I 12b(a)(l)(ii)(A)] 89 [40 CFR 60.112b(n)(l)(ii)(B)) Equip intcm_al floating roofwith two seals mounted secondary above the primary so that each forms a continuous closure that completelycovers the space between the wall ofthe storage vessel and the edge ofthe internal floating roof. The 

### primary seal 

### may be vapor-mounted, but both musl be conlinuous. Subpart Kb. [40 CFR 60.1 12b(a)(l)(ii)(B)]

Page 10 of49**rPQR01~1**

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS. Air- Title V Regular Permit Mi.nor**Mo~** 

### EQT 0050 55- 10,000 BBL IFR Storage Tank

90 [40 CFR 60.112b(a)(ll]

91 [40CFR60.113b(a)(l)]

92. [40 CFR 60.113b(a)(2)]

93 [40 CFR 60.113b(a)(2)]

94 [40 CFR 60.113b(a)(3)(i)]

95 . · [40 CFR 60.113b(a)(3)(ii)] Eachopening in a noncontact internal floating roofexcept for automatic'bleeder vents (vacuum breaker**ven~s)** and the rim space vents is to provide a projection below the liquid surface. Equip each opening in the internal floating roofexcept for leg sleeves, automatic bleeder vents, rim space vents, column wells, ladder wells, sample wells, and stub drains with a coveror lid and maintain in a closed position at all times (i.e., 

### no visible gap) except when the device is in actual use. Equip the coveror lid with a gasket. Boltcovers on each access hatch and automatic gauge float well except when they are in.use. Equip automatic bleeder vents with a gasket and close at all times when the roofis floating except when the roofis being floated offor is being landed on the rooflegsuppOrts. Equip rim space vents with a gasket and set to open onlyWhen the internal floating roofis .not floating orat the manufacturer's recommended setting. Each penetration ofthe internal floating rooffor the purpose ofsampling shall be a sample well. The sample well shall have a slit fabric coverthatcovers at least 90 percent ofthe opening. Each penetration ofthe internal floating roofthat allows for passage ofa column supporting the fixed roofshall have a flexible fabric sleeve seal ora gasketed sliding cover. Each penetration ofthe internal floating roofthat allows for passage ofa ladder shall have a gasketed sliding cover. Subpart Kb. [40 CFR 60.112b(a)(l)] Tankroofand seals monitored 

### by visual inspection/determination at the regulation's specified frequency. Inspectthe internal floating roof, the primary seal, and the secondary seal (ifone is in service), priorto filling the storage vessel with VOL. Ifthere are holes, tears, orotheropenings in the primary seal, the secondary seal, orthe seal fabric ordefects in the internal floating roof, or both, repair the items before filling the storage vessel. Subpart Kb. [40 CFR 60.113b(a)(l)] Which Months: All Year Statistical Basis: None specified Ifthe internal floating roofis notresting onthe surface ofthe VOL inside the storage vessel, or there is liquid accumulated on the roof, or the seal is detached, or there are holes ortears 

### in the seal fabric, repair the items or emptyand remove the storage vessel from service within 45 days. Ifa failure that is detectedduring inspections required in this paragraph cannotbe repaired within 45 days and ifthe vessel cannot be emptied within 45 days, request a 30-dayextension from DEQ in the inspection report required in 40 CFR 60.115b(a)(3). Document in the request for extensionthat alternate storage capacity is unavailable and specifya schedule ofactions the company will take that will assure that the control equipmentwill be repaired orthe vessel will be emptied

### ~s soon as possible. Subpart Kb. [40 CFR 60.113b(a)(2)] Tankroofand seals monitored by visual inspection/determination annually. Inspect the internal floating roofand the primary seal or the secondary seal (ifone is in service) through manholes and roofhatches on the fixed roofat least once every 12 months after initial fill. Ifa failure is detected during inspections required in this paragraph initiate repairprovisions. Subpart Kb. [40 CFR 60.113b(a)(2)] Which Months: All Year Statistical Basis: None specified Tankroofand seals monitored by visuaUnspectionidetermination once every five years as specified in 40 CFR 60.113b(a)(4). Subpart Kb. [40 CFR60.113b(a)(3)(i)]
. Which Months: All Year Statistical Basis: None specified Tankroofand seals monitored byvisual inspection/determination annually as specified in 40 CFR60.113b(a)(2). Subpart Kb. [40 CFR 60.113b(a)(3)(ii)] Which Months: All Year Statistical Basis: None specified ,

Page 11 of49 TPOR0147

### SPECIFIC REQUIREMENTS AIID: 312 ·Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002· Permit Number: 3080-00010·V6 Air·Title V Regular Permit Minor Mod
EQT 0050 55 ·10,000 BBL IFR Storage Tank

96 (40CFR60,11lb(a)(4)]

97 (40 CFR 60 113b(a)(4)]

98 (40 CFR 60.113b(a)(5)]

99 (40CFR60.115b(a)(l)]

100 [40CFR60.11Sb(a)(2)]

101 (40 CFR 60.11Sb(aX3)]

102 (40CFR60.11Sb(a)(4)]

103 [40CFR60.116b(b)] Ifthe internal floatmg roofhas defects, the primary seal has holes, tears, or other openings in the seal or the seal fabric, or the secondary seal ha<> holes, tears, orother openings in the seal orthe seal fabric, or the gaskets no longer close ofTthe liquid surfaces from the atmosphere, or the 

### slotted membrane has more than I0 percent open area, repair the items as necessary so that none ofthe conditions specified in this paragraph exist before refilling the storage vessel with VOL In no event shall inspections conducted in accordance with this provision occur at intervals greater than 10 years in the case ofvessels conductmg the annual visual inspection as spec1fied m 40 CFR 60.1 i3b(a)(2) and (a)())(li) and at intervals no greater than 

### 5years in the case ofvessels specified in paragraph40 CFR 60.113b(a)(3)(i) ofthis section. Subpart Kb. (40 CFR 60.113b(a)(4)J Tank 

### roofand seals monitored 

### by visual inspection/determination at the regulation's specified frequency. lrL'ipect the internal floating roof, the primary seal, the secondary seal (ifone is in service), gaskets, slorted membranes and sleeve seals 

### (ifany) each time the storage vessel is emptJcd and degassed. Ifa failure is detected during inspections required in this paragraph initiate repair provisions. Subpart Kb. [40 CFR 60.113b(a)(4)) Which Months: All Year Statistical Basis: None specified Submit notification in writing: Due at least 30 days prior to the filling or refilling ofeach storage vessel for which an inspection is required by 40 CFR 60.113b(a)(I) and (a)(4) to afford DEQ an opporrunity to have an observer present. Ifthe mspection reqmred by paragraph 40 CFR 60. I 13b(a)(4) is not planned and the owner or operatorcould nOt h3vc known about the inspection 30 days in advance or refilling the tank. notifY DEQ at least 7 days prior to the refilling ofthe storage vesseL !':otify by telephone immediately followed by wrinen documentation demonstrating why the inspection VIaS unplanned. Alternatively. submit notification in writing including the wrinen documentation and send by express mail so that it is received by DEQ alleast 7 days prior to the refilling. Subpart Kb. (40 CFR 60.113b(a)(5)) Submit a report: Due to DEQ as an anachment to the notification required by 40 CfR 60.7(a)(3). This report shall describe the control equipment and certify that the control equipment meet< the specificallons of40 CFR 60.112b(a)(I) and 60.113b(a)(I). Keep cop1es ofall reports for at leasIlwo years. Subpart Kb. (40 CFR 60.115b(a)(I)) Inspection records recordkeepingby electronic orhard copy upon each occurrence ofinspection, per40 CFR 60.113b(a)(I) through (4)_ Each record shall identify the storage vessel on which the inspection was performed and shall contain the date the vessel was inspected and the**ob~erved** condition ofeach component ofthe control equipment (seals, internal floating roof. and fittings). Keep copies ofall records for at least two years. Subpart Kb. (40 CFR 60.115b(a)(2)) Submit a report: Due to DEQ Within 30 days ofthe annual visual mspect1on reqmred by40 CFR 60.113b(a)(2) that delect< any ofthe cond1t1ons described in 40 CFR 60.113b(a)(2). Each report shall1dentify the storage vessel. the narure ofthe defects, and the date the storage vessel was emptied or the narure ofand date the repair 

### was made. Keep copies ofaH reports for at least two years. Subpart Kb. [ 40 CFR 60.115h(a)(3)

## I Submit a report: Due to DEQ within 30 days ofeach inspection required by40 CFR 60.113b(a)(3) thai finds holes or tears in the seal or seal fabric, or defects in the internal floating roof, or other control equipment defects listed m 40 CFR 60.113b(a)(3)(1i). The report shall identify the storage vessel and the reason It did not meet the spec1ficalions of40 CFR 61.112b(a)(I) or 40 ct"R. 60.113b(a)(3) and list each repa!T made. Keep copies ofall reports for at least two years. Subpart Kb. (40 CFR 60.115b(a)(4)) Equipment/operational data recordkeepingby electronic or hard copy at the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by40 CFR 60.116b(a). Subpart Kb. (40 CFR 60.116b(b))

Page 12 of 49 TPOA0147

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cottori Valley Refinery Activity Number: PER20120002 Permit Number: 3080-o0010-VG Air- Title V Regular Permit Minor Mod
EQT 0050 55- 10,000 BBL IFR Storage Tank 104 [40 CFR 60.116b(c)]

IOS [40 CFR 60.116b(d)] I06 [LAC 33:11!.2 103.8] 107 [LAC33:11!.2103.C.I.a] 108 [LAC 33:111.2103.C]
109 [LAC 33:11!.2103.E.I]



### I 10 [LAC 33:11!.2103.H.3] Ill [LAC 33:lll.2103.1] VOL storage data recordkeeping 

### by electronic or hard copy at the approved frequency. Records consist ofthe VOL stored, the period ofstorage, and.the maximum true vaporpressure ofthat VOL during the respective·storage period. Keep copies ofall records for at least two years. 

### Subpart Kb. [40 CFR 60.116b(c)] Submit notification: Due within 30 days when the maximum true vapor pressure ofthe liquid exceeds the respective maximum true vapor pressure values for each volume range. Subpart Kb. [40 CFR 60.!16b(d)] Equip with a submerged fill pipe. · Equip internal floating roofwith a liquid mounted seal consisting

## ofa foam- or liquid-filled seal mounted in contact with the liquid between the wall ofthe storage vessel and the floating**roofcontinuoll:~ly ar~und**  

### the circumference o(the tank.
. Equip with ail internal floating roofconsisting ofa poritoon type roof, Oouble deck roof, or internal floating coverwhich will rest or float on the surface ofthe liquid contents arid is equippedwith a closure seal to close the space between the roofedge and tank wall. All tank gauging and samplingdevices will be gas-tightexceptwhen gauging orsampling is takingplace. VOC, 

### Total>= 95%control efficiencyusing a vapor loss control system. This limitation does not apply during periods ofplanned routine maintenance which may not exceed 240 hours peryear.· Which Months: All Year Statistical Basis: None specified Determine VOC 

### maximum true vaporpressure using the methods in LAC 

### 33:JII.2103.H.3.a-e. Equipment/operational data 

### recordkeeping by electronic orhard copy at the regulation's specified frequency. Keep records ofthe infonnation 

### specified in LAC 33:111.2103.1.1 -7, as applicable. 

### EQT 0051 56- 10,000 BBL IFR Storage Tank 112 [40 CFR 60.1 12b(a)(l)(i)] Equip with a fixed roofin combination with an internal floating roof. The internal floating roofshall rest or float on the liquid surface (but not necessarily in complete contactwith it) inside a storage vessel thathas a fixed roof. The internal floating roofshall be floating on the liquid surface at all times, except during initial fill and during those**inte~als** 

### when the storage vessel.is completelyemptied orsubsequentlyemptied and refilled. When the roofis resting onthe leg supports, the process offil1ing, emptying, or refilling shall be continuous and shall be 

### accomplished as rapidly as possible. Subpart Kb. [ 40 CFR60.112b(a)(J)(i)] 113 [40 CFR 60.112b(a)(I)(ii)(A)] Equip internal floating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in contact with the liquid between the wall ofthe storage vessel and the floating roofcontinuously around the circumference ofthe tank. Subpart Kb. [40 CFR 60.112b(a)(l)(ii)(A)] 114 [40 CFR 60.112b(a)(l)(ii)(B)] Equip internal floating roofwith two seals mounted secondary above the primary so**th~t** 

### each forms a continuous closure that completely covers**th~** 

### space between the wall ofthe storage vessel"and the edge ofthe internal floating roof. The primary seal may be vapor-mounted, but both 

### mustbe continuous. Subpart Kb. [40 CFR60.112b(a)(I)(ii)(B)) ·

Page 13 of49 TPOR0147

### SPECIFIC REQUIREMENTS . - AliD: 312- Calume1 Lubrlcan1s Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air- Title V Regular Permit Minor Mod
EQT 0051 56 -10,000 BBL IFR Storage Tank

115 [40CFR60.112b(a)(l)l

116 (40CFR60.11Jb(a)(l))

117 [40 CFR 60.113b(a)(2))

118 (40 CFR 60.113b(aX2l)

119 (40 CFR 60 113b(a)(J)(o)]
120 (40CFR60.11Jb(a)(J)(ii)] Each opening 

### in a noncontact internal floating roofexcept for automatic bleeder vents (vacuum breaker vents) and the rim space vents is to provide a projection belowthe liquid surface. Equip each opening in the internal floating roofexcept for leg sleeves, automatic bleeder vents, rim space vents, column wells, ladder wells. sample wells, and stub drains with a cover or lid and maintain in a closed position at all times (i.e., no visible gap) except when the device is in actual usc. Equip the cover or lid with a gasket. Bolt covers on each access hatch and automatic gauge float well except when they are in use. Equip'automatic bleeder vents with a gasket and close at all times when the roofis floating except when the roofis being floated ofTor is being landed on the roofleg supports. Equip rim space vents with a gasket and set to open only when the internal floating roofis not floating or at the manufacturer's recomffiended setting. Each penetration ofthe mternal floating rooffOr the purpose ofsampling shall 

### be a sample welL The sample well shall have a slit fabric cover that covers at least 90 percent ofthe opening. Each penetration ofthe internal floating roofthat allows for pac;sage ofa column supporting the fixed roofshall have a flexible f3bric sleeve seal or a gac;keted sliding cover. Each penetration ofthe internal floating roofthat allows for passage ofa ladder shall have a gasketed sliding cover. 

### Subpan Kb. [40 CFR 60.112b(a)(l)) Tank roofand seals monitored by visual inspection/determination at the regulation's specified frequency. Inspect the internal floating roof. the primary seal, and the secondary seal (ifone is in service), prior to filling the storage vessel with 

### VOL Ifthere are holes. tears, or other openings in the primary seal, the secondary seal, or the seal fabric or defects in the internal floating roof, or both, repair the items before filling the storage 

### vessel. Subpan Kb. [40 CFR 60.113b(a)(l)) Which Months: All Year Statistic,al Basis· None specified Ifthe internal floating roofis not resting on the swface ofthe VOL 

### inside the storage vessel, or there is liquid accumulated on 

### the roof. or the seal is detached, orthere are holes or tears in the seal fabric, repair the items or emptyand remove the storage vessel from serv1ce within 45 days. Ifa failure that is detected during inspections required in th1s paragraph cannot be repaired w1thin 45 days and ifthe vessel cannot be 

### emptied within 45 days. request a 30-dayextension from DEQ in the inspection report required in 40 CFR 60.11 Sh(a)(3). Document in the request for extension that alternate storage capacity is unavailable and specify a schedule ofactions the company will rake that will assure that the control 

### equipment Wlll be repaired or the vessel will be 

### empllcd as soon as possible: Subpan Kb. [40 CFR 60.113b(a)(2)] Tank roofand seals monitored by visual inspection/determination annually. Inspect the internal floating roofand the primary seal or the secondary seal (ifone is in service) through manholes and roofhatches on the fixed roofat least once every 12 months after initial filL Ifa 

### failure is detected during inspections required on this paragraph onitiate repaor provisions. Subpan Kb. [40 CFR 60.113b(a)(2)] Which Months: All Year Statistical Basis: None specified 

### Tank roofand seals monitored by visual inspecllonidctcmunation once every five years as specified in 40 CFR 60.113b(a)(4). Subpan Kb. [40 CFR 60.113b(a)(3)(i)] Which Months: All Year Statistical Ba.c;is: None specified 

### Tank roofand seals monitored by visual inspectoon/determination annually._, specified on 40 CFR 60.113b(a)(2). Subpart Kb. [40 CFR 60.113b(a)(3)(ii)] Which Months: All Year Statistical Basis: None specified

Page 14 of 49 TPOR0\•7

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002
- Permit Number: 3080-00010-V6 Air- Title V Regular Permit Minor Mod
EQT 0051 56
- 10,000 BBL IFR Storage Tank 121 [40 CFR 60.113b(a)(4)]

122 [40CFR60.113b(a)(4)]

123 [40 CFR 60.113b(a)(S)]

124 [40 CFR 60.115b(a)(l)]

125 [40 CFR 60.115b(a)(2)]

126 [40 CFR 60.115b(a)(3)]

127 [40CFR60.115b(a)(4)]

128 [40CFR60.116b(b)J Ifthe internal floating roofhas defects, the primary seal has holes, tears, or other openings in the seal or the seal fabric, or the secondary seal has holes, tears, or otheropenings in the seal or the seal fabric, or the gaskets no longer close offthe liquid surfaces from the atmosphere, orthe slotted membrane has more than I0 percent open area, repairthe items as necessary so that none ofthe conditions specified in this paragraph exist before refilling the storage vessel with VOL. In no event shall inspections conducted in accordance with this provision occur at intervals greater than 10 years in the case ofvessels conducting the annual visual inspection as specified in 40 CFR 60.113b(a)(2) and (a)(3)(ii) and at intervals no greater than 5 years in the case ofvessels specified in paragraph 40 CFR 60.113b(a)(3)(i) ofthis section. Subpart Kb. [40 CFR 60.1!3b(a)(4)] Tankroofand seals monitored

### by visual inspection/determinatlon at the regulation's specified frequency. Inspect the internal floating roof, the primary seal, the secondary seal (ifone is in service), gaskets,

### slott~d membranes and sleeve seals (ifany) each time'ihe storage vessel is emptied and degassed. Ifa failure is detected during inspections required in this paragraph initiate repair provisions. Subpart Kb. [40 CFR 60.113b(a)(4)] Which Months: All Year Statistical Basis: None specified Submit notification in writing: Due at least 30 days priorto the filling or refilling ofeach storage vessel for which an inspection is required 

### by 40 CFR 60.113b(a)(l) and (a)(4) to afford DEQ an opportunityto have an observer present. Ifthe inspection required by paragraph 40 CFR 60.113b(a)(4) is not planned and the owner or operatorCould not have known about the inspection 30 days in advance or refil1ing the tank, notify DEQ at least 7 days prior to the refilling ofthe storage vessel. Notifybytelephone immediately followed bywritten documentation demonstrating whythe inspection was unplanned. Alternatively, submit"notification in writing including the written documentation and send by express mail so that it is received by DEQ at least 7 days priorto tjle refilling. Subpart Kb. [40 CFR 60.113b(a)(S)] Submita report: Due to DEQ as an attachment to the notification required by40 CFR 60.7(a)(3). This report shall describe the control· equipment and certify that the control equipment meets

### th~ specifications of40 CFR 60.1!2b(a)(l) and·60.113b(a)(l). Keep copies ofall reports for at least two years. Subpart Kb. [40 CFR60.11Sb(a)(l)] Inspection records recordkeeping by electronic orhard copyupon eachoccurrenceofinspection, per40 CFR 60.113b(a)(l) through (4). Each record shall identifythe storage vessel on which the inspection was_performed and shall containthe date the vessel was inspected and the ·observed condition ofeach component Ofthe control equipment**(s~als,** internal floating roof, and fittings). Keep copies ofall records for at least two years. Subpart Kb. [40 CFR 60.!1Sb(a)(2)] Submita report: Due to DEQ within 30 days ofthe annual visual inspection required by40 CFR 60.1!3b(a)(2) that detects any ofthe conditions described in 40 CFR 60.113b(a)(2). Each report shall identifythe storage vessel, the nature ofthe defects, and the date the storage vessel was emptied or the nature ofand date the repairwas**ma~e.** Keep copies ofall reports for at least two years. Subpart Kb. [40 CFR 60.11Sb(a)(3)] Submit a report: Due to DEQ within 30 days ofeach inspection required by40 CFR 60.113b(a)(3) that finds holes or tears in the seal orseal fabric, or defects in the internal floating roof, or other control equipment defects listed in 40 CFR 60.113b(a)(3)(ii). The report shall identify the storage vessel and the reason it did not meet the specifications of40 CFR 6l.ll2b(a)(I) or 40 CFR. 60.113b(a)(3) and list each repair made. Keep copies ofall reports for at least two years. Subpart Kb. [40 CFR 60.11Sb(a)(4)]**Equipment/ope~ational** data recordkeeping byelectronic or**ha~d** copyat the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the cap_acity ofthe storage vessel. Keep copi-es ofall records for the life ofthe source as specified by40 CFR 60.116b(a). Subpart Kb. [40 CFR60.116b(b)]

Page 15 of49 TPQR0147

### SPECIFIC REQUIREMENTS AIIO: 312- Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod
EQT 0051 56- 10,000 BBL IFR Storage Tank 129 (40CFR 60.116b(c)l

130 (40 CFR 60.116b(d)] 131 (LAC 33:1111103.8] 132 (LAC 33:1111103.C.I.a] 133 (LAC JJ 111.210J.C]

134 (LAC ll IIUIOJ.E.I]

135 (LAC J1111210J.IU] 136 [LAC JJIII110J I) VOL storage data recordkeeping 

### by electronic or hard copy at the approved frequency. Records consist ofthe VOL stored, the period ofstorage, and the maximum true vapor pressure ofthat VOL dunng the respective storage period. Keep copies ofall records for at least two years. Subpart Kb. (40 CFR 60.116b(c)) Submit notification: Due within 30 days when the maximum true vapor pressure ofthe liquid exceeds the respective maximum true vapor pressure values for each volume range. Subpart Kb. (40 CrR 60.116b(d)) Equip wilh a submerged fill pipe. Equip internal noating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in contact with the liquid between the wall ofthe storage vessel and the floating roofcontinuously around the circwnference ofthe tank. Equip with an internal floating roofconsisting ofa pontoon**typ~** roof, double deck roof, or internal floating cover which will rest or float on the surface ofthe liquid contents and is equipped with a closure seal to close the space between the roofedge and 

### lank waiL All tank gauging and sampling devices 

### wlll be gas-tight except when gauging or sampling is taking place. 

### VOC, Total>= 

### 95% cnnlrol efficiencyusing a vapor loss control system. This limitation does not apply during periods ofplanned routine maintenance which may not exceed 240 hours per year. Which Months: All Year Stat.islical Basis: None specified Detennine 

### VOC maximum true vapor pressure using the methods in 

### LAC 33:111.2103.H.3.a-e. Equipment/operational data recordkeeping by electronic or hard copy at the regulation's specified frequency. Keep records ofthe infonnation spec1fied in LAC 33:!11.2103.1.I

- 7, as applicable. · 

### EQT 0055 60
- 5,000 BBL IFR Storage Tank I37 (40 CFR 60.112b(a)( I)(i)] Equip with 

### a fixed roofin combination with an internal floatmg roof. The internal lloating roofshall rest or float on the liquid surface (but not nccessanly in complete contact with it) mstde a storage vessel that has a fixed roof. The internal floating roofshall be floating on the liquid surface at all times. except during initial fill and during those mtervals when the storage vessel is completely emptted orsubsequently emptied and refilled. \\'hen the roofis resting on the leg supports, the process offilling, emptying, or refilling shall be continuous and shall be accomplished as rapidly as possible. Subpart Kb. (40 CFR 60.112b(a)(l)(1)) 138 (40 CFR 60. 112b(a)(l)(il)(A)) Equip internal noating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted 

### in contact with the liquid between the wall of1he Slorage vessel and !he floa<ing rnofcnnlinuouslyaround !he circumference of !he lank. Subpart Kb. [40 CFR 60.112b(a)(I)(ii)(A)) I39 [40 CFR 60. 112b(a)(l)(i1)(B)) EquiP internal floating roofwith two seals**mount~d** secondaryabove the primary so that each forms a continuous closure that completelycovers the space between the wall ofthe storage vessel and rhe edge**oft~e** internal floating roof. The primary seal may be vapor-mounted, but both mus< be con<inuous. Subpart Kb. [40 CFR 60.1!2b(a)(l)(ii)(B)]

Page t6of49 TPOR01•7

## --------------------------------------------------------------------------------------------------------------------------------------------------------

·SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080..00010-VS Air- Title V Regular Permit Minor Mod 

## •·. EQT 0055 60
- 5,000 BBL IFR Storage Tank 140 [40CFR60.112b(a)(l)]

141 [40 CFR 60.113b(a)(l)]

142 [40 CFR 60.113b(a)(2)]

143 [40 CFR 60.113b(a)(2)]

144 [40CFR60.113b(a)(3)(i)]

145 [40CFR60.113b(a)(3)(ii)] Each opening in a noncontact internal floating roofexcept for automatic bleeder vents (vacuum breaker vents) and the rim space vents is to provide a projection below the liquid surface. Equip each opening in the internal floating roofexcept for leg sleeves, automatic bleeder vents, rim space vents, column wells, ladderwells, sample wells, <ind stub drains with a cover or lid and maintain in a closed position at all times (i.e., no visible gap) except when the device is in actual use. Equip the coveror lid with a gasket. Bolt covers on each access hatch and automatic gauge float well except when they are in use. Equip automatic bleeder vents with a gasket and close at all times when the roofis floating except when the roofis being floated offor is being landed on the roofleg supports. Equip rim space vents with a gasket and set to open onlywhen the internal floating roofis not floating orat the manufacturer's'recominendC:d'setting. Each penetration ofthe internal floating rooffor the purpose ofsampling shall be a sample well. The sample well sh'all have a slit fatiric cover that cove"rs at least 90 percent ofthe opening. Each· penetration ofthe internal floating roofthat**~illows** for passage ofa column supporting the fixed roofshall have a flexible fabric sleeve seal ora gasketed sliding cover. Each penetration ofthe internal floating roofthat allows for passage ofa ladder shall have a gasketed sliding cover. Subpart Kb. [40 CFR 60.112b(a)(l)]
. . ., .. , Tankroofand seals monitoied by visual inspection/determination

### ~t the regulation's specified frequency. Inspect the internal floating roof, the primaryseal, and the secondary seal (ifone is in service), priorto filling the storage vessel with VOL. Ifthere**a~e** holes, tears, orother openings in the primary seal, the secondary seal, orthe seal fabric or defects in the internal floating roof, or both, repair the items before filling the storage vessel. Subpart Kb. [40 CFR 60.113b(a)(I)] Which Months: All Year Statistical Ba.o;;is: None specified Ifthe internal floating roofis notresting onthe surface ofthe VOL inside the storagevessel, orthere is liquid accumulated on the roof, or the.· seal is dC:tached, orthere are holes ortears 

### in the seal fabric, repair the items or emptyand remove the storage vessel from service within45 days. Ifa failure that is detected during inspections required in this paragraph cannotbe repairedwithin 45 days and ifthe vessel cannotbe emptied within45 days. request a 30-day extension from DEQ in the inspection

### r~port required in 40 CFR 60.115b(a)(3). Document in the request for extension that alternate storage capacity is unavailable and sPecify a schedule ofactions the companywill take that 

### will assure that the control equipmentwill be repaired orthe vessel will be emptied as soon as possible. Subpart Kb. [40 CFR 60.113b(a)(2)] Tankroofand'seals monitored byvisual inspection/determination annually. Inspect the internal floating roofand the primary seal or the secondary seal (ifone is in service) through manholes and roofhatches on the fixed roofat least once every 12 months after initial f.ill. Ifa failure is detectedduring inspections required in this paragraph initiate repair provisions. Subpart Kb. [40 CFR 60.113b(a)(2)] Which Months: All Year Statistical Basis: None specified Tankroofand seals monitored byvisual inspection/determination once every five years as specified in 40 CFR 60.113b(a)(4). Subpart Kb. [40 CFR 60.113b(a)(3)(i)]
. . . . Which Months: All Year Statistical Basis: None specified Tank roofand seals monitoredby visual inspection/determination annually as specified in 40 CFR 60.113b(a)(2). Subpart Kb. [40 CFR 60.113b(a)(3)(ii)] · Which Months: All Year Statistical Basis: None specified

Page 17 of49 TPOR0147

### SPECIFIC.REQUIREMENTSAIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-V& Air- Title V Regular Permit Minor Mod
EQT 0055 60
- 5,000 BBL IFR Storage Tank 146 (40CFR60.113b(o)(4))

147 (40CFR 60.113b(a)(4)]

148 )40 CFR 60.113b(a)(5))

149 (40 CFR 60.115b(a)(l))

I

### 50 [40 CFR 60.115b(a)(2)]

151 (40CFR60.115b(a)(3))

152 (40 CFR 60 115b(a)(4)]

153 [40 CFR 60.116b(b)) Ifthe internal floating roofh.as defects, the primary seal has holes, tears, or other openings in the seal or the seal fabric, or the secondary seal has holes, tears, orother openings in the seal or the seal fabric, or the gasket<; no longer close offthe liquid surfaces from the atmosphere, or the stoned membrane has more than 10 percent open area, repair the Items as necessary so that none ofthe conditions specified in this paragraph exist before refilling the storage vessel wlth VOL. In no event shall inspections conducted in accordance with this provision occurat intervals grealer !han 10 years 

### in !he case ofvessels conductmg !he armuai visual inspection as specified in 40 CFR 60. I 13b(a)(2) and (a)(3)(ii) and at inlervais no greater !han 

### 5 years in !he case ofvessels spec1fied in paragraph 40 CFR 60. I 13b(a)(3)(i) ofth1s section. Subpan Kb. (40 CFR 60.1 13b(a)(4)] · Tank 

### roofand seals monitored by visual inspection/determination at the regulation's specified frequency. Inspect the internal floating roof, the primary seal, the secondary seal (ifone is in service), gaskets, sloned membranes and sleeve seals (ifany) each time the storage vessel is emptied and degassed. Ifa failure is detected during inspections required in this paragraph initiate repair provisions Subpart Kh. (40 CFR 60.1 13b(a)(4)) Which Months: All Year Statis!lcal Basis: None specified Submit notification in writing: Due at least 30 days prior to the filling or refilling 

### ofeach storage vessel for which an inspection IS required 

### by 40 CFR 60.1 I3b(a)(I) and (a)(4) to afford DEQ an opportunity to have an observer present. if !he inspeclion reqUired by paragraph 40 CFR 60.I 13b(a)(4) is not planned and the owner oroperatorcould not have known about the inspection 30 days in advance or refilling the tank. notify DEQ at least 7 days prior to the refilling ofthe storage vessel. !'Jotify by telephone immediately followed by written documentation demonstrating why the inspection \\'aS unplanned. Allematively, submit notification in writing including the written documentation and send by express mali so !hat 11 IS rece1ved by DEQ at least 7 days prior to the refilling. Subpan Kb. (40 CFR 60.113b(a)(S)) Submit a report: Due to DEQ as an attachment to the notification reqwrcd by 40 CFR 60.7(a){3). This report shall describe the control equipment and cenify that the control equipment meetsthe specifications of40 CFR 60.112b(a)(I) and 60.113b(a)(I). Keep cop1es ofail repons for at least two years. Subpan Kb [40 CFR 60. IISb(a)(l)) Inspection records recordkeeping by electronic or hard copy upon each occunence ofinspection, per40 CFR 60.1 I3b(a)(I) through (4). Each record shall identify the storage vessel on which the inspection was performed and shall contain the date the vessel was inspected and the observed condition ofeach component ofthe control e"'uiprnent (seals. internal floating roof, and fittings). Keep copies ofall records for at least two years. Subpan Kb. [40 CFR 60.1 I5b(a)(2)] ' Submit a rcpon: Due to DEQ 10.ithin 30 days ofthe annual viSual mspection required by 40 CFR 60.I 13b(a)(2) that detects any ofthe conditions described in 40 CFR 60.1 I3b(a)(2). Each report shall identify the storage vessel. the nature ofthe defects, and the date the storage vessel was emptied or !he nature ofand date !he repair was made. Keep copies ofail reports for at least two years. Subpan Kb. (40 CFR 60.11 Sb(a)(3)) Submit a repon: Due to DEQ within 30 days ofeach inspection required by40 CFR 60.1 13b(a)(3) that finds holes or tears in the seal or seal fabric, or defects in the internal floating roof, orother control equipment defects listed in 40 CFR 60.I I3b(a)(3)(ii). The repon shall identify the storage vessel and the reason it did not meet the specifications of40 CFR 61.112b(a)(I) or40 CFR. 60.I I3b(a)(3) and hst each repair made. Keep cop1es ofali rcpons for at least two years. Subpan Kb. [40 CFR 60.115b(a)(4)] Equiprnent/opemtional dala recordkeepingbyelectronic or hard copy at the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacityofthe storage vesseL Keep copies ofall records for the life ofthe source as spec1fied by40 CFR 60 I 16b(a). Subpan Kb. (40 CFR 60. 116b(b))

Page 18 of49 TPOROI.-1

## ---------------------------------------------------------------------------------------------------------------------------------------------------------------------------

------- 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery ActivitY Number: PER20120002 Permit Number: 3080-00010-V6 Air- Title V Regular Permit Minor Mod
EQT 0055 60
- 5,000 BBL IFR Storage Tank IS4 [40 CFR 60.116b(c)]

ISS [40 CFR 60.116b(d)] IS6 [LAC 33:111.2103.8] IS7 [LAC 33:111.2103.C.I.a] ISS [LAC 33:111.2103.C]

IS9 [LAC 33:111.2103.E.1]

160 [LAC 33:111.2103.11.3] 161 [LAC 33:111.2103.1] VOL 

### stOrage data recordkeeping 

### by electronic orhard copy at the approved frequency. Records consist ofthe VOL stored, the period ofstorage, 

### and the maximum true vaporpressure ofthat VOL during the respective storage period. Keep copies ofall records for at least two years. Subpart Kb. [40 CFR 60.116b(c)] Submit notification: Due within 30 days when the**rnaximum.tr':Ie.~apor** 

### pressure ofthe liquid exceeds the respective maximum true vapor pressure values for each volume range. Subpart Kb: [40 CFR 60.116b(d)] Equip with a submerged fill pipe. · Equip internal floating roofwith a liquid mounted seal consisting ofa foam- or liquid-filled seal mounted in contact with the liquid between the wall ofthe storage vessel and the floating roofcontinuously around the circumference ofthe tank. Equip with an internal floating roofconsisting ofa pontoon type roof, double deck roof, or internal floating coverwhich will rest or float on the surface ofthe liquid contetits and is equipped with a closure seal to close the space between the roofedge and tank wall. All tank gauging and sampling devices will be gas-tight exCept when gauging or sampling is takingplace. VOC, Total>= 95% control efficiencyusing a vapor loss control system. This limitation does not apply during periods ofplanned routine maintenance which may not exceed 240 hours peryear. . . Which Months: All 

### Year Statistical Basis: None sPecified Determine VOC maximum true vaporpressure using the methods in LAC 33:111.2103.H.3.a-e. Equipment/operational data recordkeeping by electronic or hard copyat the regulation's specified frequency. Keep records ofthe information specified in 

### LAC 33:111.2103.1.1 -7, as applicable. 

### EQT 0056 66- 10,000 BBLVFR Storage Tank 162 [40CFR60.116b(b)] Equipment/Operational data recordkeeping by electronic or

## ha~d copyat the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis Showing the capacityofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by 40 CFR60.116b(a). Subpart Kb. [40 CFR 60.116b(b)] 

### EQT 0057 67- 10,000 BBLVFR Storage Tank 163 [40 CFR 60.116b(b)] Equipment/operational data recordkeeping by electronic or hard copyat the-approved frequency. Keep readily accessible records showing 

### the dimension ofthe storage vessel and an analysis showing 

### the capacity ofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)] 

### EQT 0061 72
- 5,500 BBL VFR Storage Tank 164 [40 CFR60.116b(b)j Equipment/operational data recordkeepingb)relectronic or hard copyat the approved frequency. Keep readily accessible;records showing the dimension ofthe storage vessel and an analysis showing the capacityofthe storagevessel. Keep copies ofall records for the life ofthe source as specified by40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)] 

### EQT 0062 73
- 5,000 BBL VFR Storage Tank

..·,. · · · Page ,9 of49 TPOR0147**~**

### SPECIFIC REQUIREMENTS AIIO: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-40010-V6 Air- Title V Regular Permit Minor Mod
EQT 0062 73 • 5,000 BBL VFR Storage Tank

165 (40 CFR 60.116b(b)] Equipment/operational data rccordkceping 

### by electronic or hard copy at the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by 40 CFR 60.116b(a). Subpart Kb. (40 CFR 60.116b(b)). EQT 0063 76 • 10,000 BBL VFR Storage Tank

166 (40CFR60.116b(b)] Equipment/operational data record.keeping 

### by electronic or hard copy at the approved frequency. Keep readily accessible records showing the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vesseL Keep copies ofall records for the life ofthe source as specified by 40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)) EQT 0064 79 • 5,500 BBL VFR Storage Tank

167 (40CFR60.116b(b))

EQT 0067 B-1401 ·No. 1 Boiler t6R (40CFR 60.104(o)(l)] 169 (40 CFR 60.105(a)(3)(11)] 170 (40 CFR 60.105(a)(3)]

171 (40 CFR 60.105(a)(4))

172 (40 CFR 60.106(a)] 173 140 CFR 60.106] 174 (LAC 33111.1101.8]

175 (LAC 33:111.1313 C) Equipment/operational data rccordkeepmg

### by electronic or hard copy at the approved frequency. Keep readily acccssJblc records showmg the dimension ofthe storage vessel and an analysis showing the capacity ofthe storage vessel. Keep copies ofall records for the life ofthe source as specified by 40 CFR 60.116b(a). Subpart Kb. [40 CFR 60.116b(b)]

Fuel gas: Hydrogen sulfide<= 0.1 gridscf(230 mg/dscm). Subpari 

### J. [40 CFR 60.104(a)(I)) Which Months: All Year Statistical Basis:**Three~hour** rolling average Fuel gas: Sulfur dioxide<= 20 ppm dry basis, 0% excess air. Subpart

### J. [40 CFR 60.105(a)(3)(ii)] 

### Which Months: All Year Statistical Basis: Three·hour rolling average Sulfurdioxide monitored by continuous emission monitor (CEM) continuously Include an oxygen monitor for correctmg the data for excess air Subpart J. [40 CFR 60.105(a)(J)j Which Months: All Year Statistical Basis: None spec1fied Hydrogen sulfide monitored bycontinuous emission monitor (CEM) continuously. Monitor Lhe H2S in fuel gases**be~orc** being burned in any fuel gas combustion device. Subpart

### J. [40 CFR 60.105(a)(4)) Which Months: All Year Statistical Rasis: None specified Usc

### as reference methods and procedures the test methods in 40 CFR 60 appendix A or other methods and procedures as specified in 40 CFR 60.106, except as provided in 40 CFR 60 8(b), in conductmg the performance tests required in 40 CFR 60.8. SubpartJ. [40 CFR 60.106(a)] Detennme compliance with standards using the test methods and procedures specified in 40 CFR 60.106(a) through (k). Subpart J. Opacity<= 20 percent, except during the cleaning ofa fire box or building ofa new f1re, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitator.;, which mayhave an opacity in excess of20 percent for not more than one six-minute period 

### in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0.6 lb/MMBTU ofheat input. Which Months: All Year Statistical Basis: None specified Page 20 of 49 TPQR01•7EQT 0067 B-1401 ·No. 1 Boiler 176 [LAC 33:1Il.l513]

EQT 0068 B-1402 -No.2 Boller

177 [40 CFR 60.104(a)(l)] 178 [40 CFR 60.105(a)(3)(ii)] 179 [40 CFR 60.105(a)(3)]

180 [40 CFR 60.105(a)(4)]

181 [40 CFR 60.106(a)]" 182 [40 CFR 60.106] 183 [LAC33:l!T.II0I:B]

184 [LAC33:111.1313.CJ 185 [LAC33:l!T.1513]

EQT 0069 BD • Blue Drum

186 [40CFR61.355] 187 [40CFR61.356] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet lubricants Co- Cotton Valley Refinery Activity Number: ·PER20120002 Permit Number: 3080-0001O-V6 Air- Title V Regular Permit Minor Mod

Equipment/operational data recordkeepingby electronic orhard copy at the approved frequency. Record and keep on site for at least two years 

### the data required to demonstrate exemption from the provisions ofLAC 33:III.Chapter 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to?**re~resentative** ofDEQ or the U.S. EPA on request.

Fuel gas: Hydrogen sulfide<= 0.1 gr/dscf(230 mg/dscm). Subpart

### J. (40 CFR 60.104(a)(l)] Which Months: All Year Statistical Basis: Three-hour rolling average Fuel gas: Sulfur dioxide<= 20 ppm dry basis. 0% excess air. Subpart

### J. [40 CFR 60.105(a)(3)(ii)] Which Months: All Year Statistical Basis: Three-hourrolling average Sulfurdioxide monitored bycontinuous emission monitor (CEM) continuously. Include an oxygen monitor for correctingthe data for excess air. SubpartJ. [40 CFR 60.105(a)(3)] Which Months: All Yea:r Statistical Basis: None specified Hydrogen sulfide monitored bycontinuous emission monitor (CEM) continuously. Monitorthe H2S in fuel gasesbeforebeingburned in any fuel gas combustion device. Subpart

### J. [40 CFR 60.105(a)(4)] · Which Months: All Year Statistical Basis: None specified Use as reference methods and procedures the test methods in 40 CFR 60 appendix A or other methods and procedures as specified in 40 CFR 60.106, excepl as provided in 40 CFR 60.8(b), in conducting theperformance tests required in 40 CFR 60.8. Subpart

### J. [40 CFR 60.106(a)] Determine

### ~ompliance with standards using the test methods andprocedures specified in 40 CFR 60.106(a) through (k). SubpartJ.**Opacity<~** 20 percent, except during the cleaning ofa fire box orbuildingofa new fue, soot blowingor lancing, charging ofan incinerator, equipmentchanges, ash removal orrapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0.6 lb/MMBTU ofheal input. Which Months: All Year Statistical Basis: None specified EqUipment/operational data recordkeepingbyelectronic or hard copyat the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:1II.Chapter 15. Record all emissions data in the units ofthe standard usingthe averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPA on request.

Determine compliance with 40 CFR 61 Subpart FF using the test methods and procedures specified in 40 CFR 61.355(a) through (i). as applicable. Subpart FF. Equipment/operational data recordkeeping by electronic or hard copy at the regulation's specified frequency Maintain records as specified 

### in 40 CFR 61.356(a) through (n), as applicable. Maintain each record in a readilyaccessible location at the facilily site for a period not less lhan two years from the date the inforination is recorded unless otherwise sp,ecified. Subpart FF.
Page21 of 49 TPOR0147

### EQT 0071 Fl2 • Flare 188 [40 CFR 60.104(a)(l)] 189 [40 CFR 60.106(a)] 190 [40CFR60.1J(i)]

191 (40 CFR 60.18(c)(I)] 192 [40 CFR 60.18(c)(2)] 193 [40 CFR 60.18(c)(J)(ii))

194 [40 CFR 60.18(c)(5)) 195 [40 CFR 60.18(d)) 196 [40 CFR 60.18(e)) 197 [40 CFR 60.18(1)(2))

198 [40 CFR 60.18] 199 [LAC JJ:III.IIOS]

200 [LAC JJ:IIL 1105]

201 [LAC JJ:IlllJII 

## CJ

202 [LAC JHILISIJ] 

### SPECIFIC REQUIREMENTS AIID: 312. Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air.Title V Regular Permit Minor Mod

Fuel gas: Hydrogen sulfide<= 0.1 gr/dscf(230 mgldscm). Subpan 

### J. (40 CFR 60.i04(a)(i)] 

### Which Months: All Year Statistical Basis: Three-hour rolling average Use ao; reference methods and procedures the test methods in 40 CFR 60 

### appendix A or other methods 

### and procedures 

### as specified in 40 CFR 60.106, except as provided in 40 CFR 60.8(b), m conductmg the perfonnance tests reqUired m 40 CFR 60.8. Subpan J. (40 CFR 60 i06(a)] Calwnct's alternative method uses ASTM D 4952-02, "Standard Test Method for Qualitative Analysis for Active Sulfur Spcc1es in Fuels and 

### Solvents (Doctor's Test)". A Doctor's Test is performed once per day ifLSR loading has occurred durmg the day. An additional Doctor's Test is performed on a daily ba.-.is on the combined product stream that leaves the hydrotreater. Results ofeach test, the associated 

### QAJQC data, and the product being loaded during sampling are recorded and retained onsite for a minimumof3 years. Calumet will submit reports indicating instances offailed Doctor's Tests as pan ofCotton Valley's semiannual repon. (40 CFR 60. I3(i)] Design and operate for no visible emissions, as determined by the methods specified in 40 CFR 60.18(f), except for periods not to exceed a total of

### 5 mmutes dunng any two consecu!lve hours. Subpan A. [40 CFR 60 I8(c)(1)] Operate with a flame present at ali times, as dctcrmmed by the methods specified in 40 CFR 60.18(1)(2). Subpan A. (40 CFR 60. I8(c)(2)] Heat content>= 300 BTU/scf( 11.2 MJ/scm). Determine the net heating value ofthe ga.o; being combusted by the methods specified in 40 CFR 60.i8(1)(3). Subpan A. (40 CFR 60. i8(c)(3)(ii)] Which Months: All Year Statistical Basis: None specttied Exll VelocJty < 194 ftlsec (Vmax). Determine Vmax using the method spec1fied m 40 CFR 60.18(1)(6) Subpart A (40 CFR 60.18(c)(5)] Which Months: All Year Statistical Basis: None specified Monitor flares to ensure that they are operated and maintained in conformance with their designs. Applicable subparts will provide provisions statmg how to monitor flares. Subpart A. (40 CFR 60.18(d)] Operate at ali t1mes when emisstons may be vented to the flare. Subpan A. (40 CFR 60.18(e)] Presence ofa flame monitored by flame monitor continuously. Use a thermocouple oranyother equivalent device to detect the presence ofa flare pilot flame. Subpan A. (40 CFR 60.18(1)(2)] Which Months: All Year Statistical Basis: None specified Permittee shall comply with ali applicable provistons of40 CFR 60.I8. Opacity<= 20 percent, except for a combined total ofsix hours in any 10 consecutive day period, for burning in connection with pressure valve releases for control over process upsets. Which Months: All Year Statistical Basis: None specified Submit notification: Due to the Office ofEnvironmental Compliarlce, Emergencyand Radiological Services Division. Single Point ofContact (SPOC). as soon as possible after the start ofburningofpi"essure valve releases for control over process upsets. Notify in accordance with LAC 33:1.3923. Notification is required only ifthe upset cannot be controlled in six hows. Opacity<= 20 percent; except emissions may have an average opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: Six-minute average Equipment/operational data rccordkeeping byelectronic or hard copyat the approved frequency. Record and keep on site for at least two years the data reguired to demonstrate exemption from the provisions ofLAC 33:111.Chaptcr 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPA on request. Page 22 of 49 TPOR01•7

### EQT 0071 FL2 -Flare 203 [LAC JJ:Ili.501.C.6]

204 [LAC JJ:III.501.C.6]

205 [LAC JJ:III.501.C.6]

206 [LAC JJ:III.501.C.6] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod

Compiiance with the Emission Limit at 40 C.F.R. 

### § 60.104(a)(l). 

### a. Continuous or Intermittent, Routinely-Generated Refinery Fuel Gases. Forcontinuous or intermittent, routinely-generated refinery fuel gases that are combusted in any ofthe Flaring Devices identified in Appendix A, Calwnet shall either take the Flaring Device that is associated with such a gas stream out ofservice or shall complywith the emission limit at 40 C.F.R. 

### § 60.104(a)(l) bythe dates specified in Appendix A in the Consent Decree [SA-MM-10-0090] b. Non-Routinely Generated Gases. The combustion ofgases generatedbythe startup, shutdown, or Malfunctionofa refineryprocess unit or released to a Flaring Device as a result ofreliefvalve leakage caused

### by excessive pressure build-up orother emergencyMalfunction shall be exempt from the requirement to complywith 40 C.F.R. § 

### 60.104(a)(l) [SA-MM-10-0090]. 

### GoodAirPollution Control Practices.
. For all Flaring Devices identified in Appendix A in the Conseitt Decree, Calumet shall complywith the NSPS obligation to**imp]eme~t** 

### good air pollution control practices as required by40 C.F.R. 

### § 60.ll(d) to minimize HC and AG Flaring Incidents. [SA-MM-10-0090]. Identification ofand NSPS Applicability for Flaring Devices. 

### Calumet owns and operates the Flaring Devices identified iri.Apperidix A ofthe Consent Decree. Consistent with the terms ofthis Section V.D in the Consent Decree and the schedule in Appendix A, the Flaring Devices in Appendix A in the COnsent Decree shall be affected facilities, as that termis used in NSPS, 40 C.F.R. Part 60, and shall be subject to and complywith therequirements of40 C.F.R. Part 60, Subparts A and 

### J for fuel gas combustion devices [SA-MM-10-0090]. · 

### Monitoringthe Flaring Devices and Reporting. Byno later than the dates identified in Appendix A ofthe Consent Decree, all Flaring Devices identified in AppendixA that Calumet keeps in service to combust continuous or intennittent, routinely-generated refinery.fuel gases, shall either (a) be equipped with a CEMS as required by 40 C.F.R. 

### § 60.105(a)(4); (b) have submittedto or complywith an alternativemonitoringplan approvedbyEPA under40 C.F.R. 

### § 60.13(i); or (c) demonstrate that the fuel gas streams combusted in the fuel gas combustion device are inherently low in sulfurcontentin accordance with 40 C.F.R. 

### § 60.105(a)(4)(iv) or40 C.F.R. 

### § 60.105(b). Use ofa properly-sized and operated flare gas recovery systemon a flare mayobviate the need to continuously monitor the emissions as otherwise required by40 C.F.R. 60.105(a)(4) and40 C.F.R. 60.7. Calumet shall complywith the applicablereportingrequirements of40 C.F.R. Part 60 Subpart 

### J for all such flaring devices [SA-MM-10-0090]. · 

### EQT 0073 GEN
- Backup Generator 207 [LAC 33:IIT.llOI.B] 

### Opacity<= 20 percent, except during the_cleaning ofa fire box or building ofa new fire, soot blowing or lancing, chargingofan incinerator, equipment changes, ash removal orrapping ofprecipitators, which.may have an opacity in excess of20percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified 208 [LAC 33:JII.1305] Preventparticulate matter from becoming airborne by taking.all reasonable precautions. These precautions shall include, but not be limited to, those specified in LAC 33:111.1305.A.I-7. 209 [LAC 33:III.13ll.C] Opacity <= 20 percent; except emissions mayhave an average opacityin excess of20 percent for not more than one six-minute period in any 60 consecutive minutes (Complies byusing sweet natural gas as fuel). · Which Months: All Year Statistical Basis: Six-minute average
Page 23 of49 TPQR0147

### -SPECIFIC REQUIREMENTS
-- AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air- Title V Regular Permit Minor Mod
EQT 0073 GEN -Backup Generator 210 [LAC 33:TII1313 C[ 211 [LAC 33:111.151 3] Tolal suspended particulate<= 0.6 lb/MMBTU ofheat inpul. Which Months: All Year Statistical Basis: None spccifit:d Equipmcnllopcrational**~ala** recordkccping byelectronic or hard copy at the approved frequency. Record and keep on site for at least two years 

### the data 

### required to demonstrate exemption from the provisions 

### ofLAC 33:III.Chaptcr 15. Record all emissions data in the units ofthe standard using the**av~raging** 

### time ofthe standard. Make records avaJiablc to a representative ofDEQ or the lj_S, EPA on request. 

### EQT 0074 H-101 -100 Crude Unit**Proces~** 

### Heater 212 [LAC3.1:TIIIIOI Bl

213 [LAC 33:1111305] 214 [LACJ31111313CI 215 [LAC 331111513] 

### Opacity<= 20 percent, except during the cleaning ofa fire box or building ofa new fire, soot blowingor lancing, charging ofan incmerator. equipment changes, ash removal or rapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one s1x-minute period in any 60 consecutive minutes Which Months: All Year Statistical Basis: l'o:one specified Prevent particulate matter from becoming airborne by taking all reasonable precautions These precautions shall include, but not be limited to. those specified in LAC 33:111.1 305.A.i-7. 

### Total suspended particulate<= 0.6 lb/MMBTU ofheat input Which Months: All Year Statistical Basis: None specified Equipmenlloperational data recordkeepmg by

### electronic or hard copy at the approved frequency Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:Ili.Chapter 15. 

### Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the lJ.S. EPA on request. 

### EQT 0075 H-201A- 1100 Crude Unit Process Heater 216 [LAC lllll 1101.8]

217 [LAC 33 llii313.C] 218 [LAC 33:1l11Sil] 

### Opacity<= 20 percent, except during the cleaning ofa fire box or building ofa new fue, soot blowmg or lancmg, charging ofan mcinerator, equipment changes, ash removal or rapping ofprecipitators, y,:hich may have an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: 'f\:one specified Total suspendedparticulate<= 0.6 lb/MMBTU ofheat input. Which Months: All Year Statistical Basis: None specified Equipment/operational data recordkeeping by electronic or hard copy at the approved frequency. Record and keep on site for at least two years the data required to demonstrate exempllon from the provisions ofLAC 33:111.Chapter IS. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available.to a reprcsentallvc ofDEQ or the U.S. EPA on request. 

### EgT0076 H-202
- Hot

### 011 Process Heater No. 1 219 [LAC 33:111.11011l] 

### Opacity<= 20 percent, except during the cleaning ofa fire box or building ofa new fire, soot blowingor lancing, charging ofan mcmerator. equipment changes, ash removal or rapping ofprecipitators, which may have an opacity in excess of20percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specif1ed Page 24 of49 TPQR01A7

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-V6 Air- Title V Regular Permit Minor Mod
EQT 0076 H-202
- Hot Oil Process Heater No. 1 220 [LAC33:ii1.1313.CJ 221 [LAC33:iii.t513] Total suspended particulate<=0.6 ib/MMBTU ofheat input. 

### Which Months: All Year Statistical Basis: None specified Equipment/operational data recordkeeping 

### by electronic or hard copy at the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the 

### provisions ofLAC 33:1JI.Chapter 15. Record all emissions data in the units ofthe standard 

### using the averaging time ofthe standard. Make records available to a representative ofDEQor the U.S. EPA on request. EQT 0077 H-203
- Hot Oil Process Heater No. 2 

### 2i2 [LAC 33:1ii.IIOI.B]

223 [LAC 33:111.1313.C] 224 [LAC33:1ll.l513] Opacity <= 

### 20 percent, except during the cleaning ofa fire box or buildingofa new fire, soot blowing or lancing, charging ofan incinerator, 

### equipment changes, ash removal orrapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<=0.6 ib/MMBTU ofheat input. 

### Which Months: All Year Statistical Basis: None specified Equipment/operational data recordkeeping by electronic or hard copy at the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:1U.Chapter 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQorthe U.S. EPA on request. EQT 0078 H-204
- Solvents Unit Heater 225 [LAC 33:1li.IIOI.B]

226 [LAC33:111.1313.CJ 227 [LAC 33:111.1513] 

### Opacity <,;, 

### 20 percent, except during the cleaning ofa fire boxorbuilding ofa new fire, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<=0.6 lb/MMBTU ofheat·input. 

### Which Months: All Year Statistical Basis: None sPecified' Equipment/operational data recordkeeping byelectronic orhard copy at the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:III.Chapter 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available tO a representative ofDEQ orthe U.S. EPA on request. EQT 0079 H-205
- Hydrotreater Heater 228 (40CFR60.t04(a)(l)] Fuel gas: Hydrogensuifide<=O.i gr/dscf(230mgldscm). SubpartJ. [40CFR60.104(a)(i)] 

### Which Months: All Year Statistical Basis: Three-hourrolling average 229 [40 CFR 60.105(a)(3)(ii)] Fuel gas: Sulfurdioxide<= 20 ppmdry 

### basis, 0% excess air. Subpart 1. [40 CFR60.105(a)(3)(ii)] 

### Which Months: All Year Statistical Basis: Three-hourrolling average

Page 25 of 49 TPOR0147

### EQT 0079 H-205
- Hydrotreater Heater 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080.()0010-VS Air- Title 

### V Regular Permit Minor Mod



### 230 (40 CFR 60.JOS(a)(J)] Sulfur 

### dioxide monitored by continuous emission monitor (CEM) 

### continuously. Include an oxygen monitor for correcting the data for excess air. Subpart J. [40 CFR 60.105(a)(3)] Which Months: All Year Statistical Basis: None specified 231 (40 CFR 60.105(a)(4)) Hydrogen sulfide monitored bycontinuous emission monitor (CEM) continuously. Mon.itor the H2S in fuel gases before being burned many fuel gas combustion device. Subpart J. [40 CFR 60.105(a)(4)] 

### Which Months: All Year Statistical Basis. None specified 232 [40 CFR 60.106(a)] Use as reference methods and procedures the test methods in 40 CFR 60 appendix A or other methods and procedures as specified in 40 CFR 60.106, exceptas provided in 40 CFR 60.8(b), m conductmg the performance tests rcqmrcd in 40 CFR 60.8. Subpart 

### J. [40 CrR 60.106(a)] 233 [40 CFR 60 106] Determine compliance with standards using the test methods and procedures specified m 40 CFR 60.106(a) through (k). Subpart 

### J 234 [LAC JJ:IIIt tOI.B) Opacity<"" 20 percent, except during the cleaning ofa fire box or building ofa new fire, soot blowing or lancing, chargingofan incinerator. equipmentchanges, ash removal or rapping ofprecipitators, which may have an opacuy in excess of20 percent for not more than one six-minute 

### period in any 60 consecutive minutes. 235 (LAC JJ:III.t3t3.C) 

### Which Months: All Year Statistical Basis: None spcc1ficd Total suspended paniculate <= 0.6**lb/M~BTU** ofheat input. 

### Which Months: All Year Statistical Basis_ None specified 236 [LAC JJ:III.tStl) Equipment/operational data recordkecping 

### by electronic or hard copyat the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:1II.Chaptcr 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPA on request. 

### EQT 0080 H-301
- No. 1 Hydrotreater Heater 237 [40 CFR 60. t04(a)(l

### )J Fuel gas: Hydrogen sulfide<= 0.1 gridscf(230 mg/dscm). Subpart

### J. [40 CFR 60.104(a)(I)] Which Months: All Year Statistical Basis: Three-hour rolling average 238 [40 CFR 60.tOS(a)(lX1i)) Fuel gas: Sulfur dioxide<= 20 ppm drybas1s, 0% excess air. Subpart J. [40 CFR 60.105(a)(3)(u)] Which Months: All Year Statistical Basis: Three-how rolling average 239 (40 CFR 60.105(a)(3)] Sulfur dioxide monitored bycontinuous emission monitor (CEM) continuously. Include an oxygen monitor for correcting the data for excess a1r. Subpart J. [40 CrR 60.105(a)(3)] Which Months: All Year Statistical Baliis: None specified 240 (40 CFR 60. J05(aX4)) Hydrogen sulfide'monitored bycontinuous emission monitor (CEM) continuously. Monitor the H2S in fuel gases before being burned in any fuel gas combustion device. Subpart

### J. [40 CFR 60.105(a)(4)] · Which Months: 

### All Ycar Statistical Basis: None specified 241 [40 CFR 60. 106(a)) Use as reference methods and procedures the test methods in 40 CFR 60 appendix A orother methods and procedures as specified m 40 CFR 60.106, except as prov1ded in 40 CFR 60.8(b), in conducting the performance tests required in 40 CFR 60.8. Subpart

### J. [40 CFR 60.106(a)] 242 [40 CFR 60.t06) Detennine compliance with standards using the test methods and procedures specified in 40 CFR 60.106(a) through (k). Subpart J.

Page 26 of 49 TPORCP•7

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-Q0010-V6 Air- Title V Regular Permit Minor Mod
EQT 0080 H-301 -No. 1 Hydrotreater Heater 243 [LAC 33:111.1101.8]

244 [LAC 33:lli.I313.C] 245 [LAC33:llLI513] Opacity<= 20 percent, except during the cleaning ofa fire box or building ofa new fire, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitators, which may have an opacity in excess of20 percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<=0.6 lb/MMBTU ofheatinput. Which Months: All Year Statistical Basis: None**specifie~** Equipment/operational data recordkeeping by electronic or hard copy at the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from theprovisions ofLAC 33:Ill.Chapter 15. Record all emissions data in the unitS ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ orthe U.S. EPA on request. 

### EQT 0081 H-601 -Solvent Train Process Heater 246 [LAC 33:Ill.IIOI.B]

247 [LAC 33:11!.1313.C] 248 [LAC 33:lll.l513] Opacity <= 20 percent, except duringthe cleaning ofa fire box orbuilding ofa new fire, soot blowingor lancing, charging ofan incinerator, equipmentchanges, ash removal or rapping ofprecipitators, whichmay have an opacity in excess of20 percent for not more thanonesix-minute period in any 60 consecutive minutes. · '' · Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0.61b/MMBTU ofheatinput. Which Months: All Year Statistical Basis: None specified · Equipment/operational 

### data recordkeeping by electronic or hardcopy at the approved frequency. Record and keep on site for at leasttwo years the data required to demonstrate exemption from the provisions ofLAC 33:Ili.Chapter 15. Record all emissions data in the units ofthe standard usingthe averaging time ofthe standard. Make records available to a representative ofDEQ orthe U.S. EPA on request. 

### EQT 0082 H-60211 000
- Utility Fractionator Process Heater 249 [LAC 33:III.1101.B] Opacity<= 20 percent, exceptduring the cleaning ofa fire box'or buildingofa newfrre, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitators, which mayhave an opacity in excess of20 percent fOr not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis:.None specified 250 [LAC 33:lll.l313.C] Total suspended particulate<= 0.61b/MMBTU ofheat input. Which Months: All Year Statistical Basis: None specified 251 [LAC 33:111.15131 Equipment/operational data recordkeeping by electronic or hard copyat the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:lll.Chapter 15. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPAon request. 

### EQT 0083 H-701
- 700 Unit Process Heater 252 [40 CFR 60.!04(a)(I)] Fuel gas: Hydrogen sulfide<= 0.1 gr/dscf(230 mg!dscm). SubpartJ. [40 CFR 60.104(a)(l)) Which Months: All Year Statistical Basis: Three-houfrolling average Page 27 of49



### . •:' TPOR0147

### ------------------- -- - 

### ------- ----- ·---·-----



### .SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-V& Air- Title V Regular Permit Minor Mod
EQT 0083 H-701 • 700 Unit Process Heater 253 (40 CFR 60.105(a)(l)(II)J 254 (40 CFR 60.105(a)(l)J
255 [40 CFR 60.105(a)(4))

256 (40 CFR 60.106(a)) 257 (40 CFR 60.106] 258 [LAC 33:111 110\.B)

25Q [LAC JJ:III.J J

### IJ 

### CJ 260 [LAC JJ.\11.1513) Fuel gas: Sulfur dioxide<= 20 ppm dry basis, 0%excess air_ Subpart J. [40 CFR 60.105(a)(J)(ii)]**~ich** 

### Months: All Year Statistical Basis: Three-hour rolling average Sulfur dioxide monitored by 

### continuous em1ssion rnoni10r 

### (CEM) continuously. Include an oxygen monitor for corrcctmg the data for excess air Subpart J. 

### [40 CFR 60.105(a)(J)] Which Months: All Year Statistical Basis: None specified Hydrogen sulfide monitored 

### by continuous emission monitor (CEM) continuously. Monitor the H2S in fuel gases before being burned in any fuel gas combustion device. Subpart J. (40 CFR 60.105(a)(4)] Which Months: All Year Statistical Basis: None specified 

### Use as reference methods and procedures the test methods in 40 CFR 60 appendix A orother methods and procedures as specified in 40 CFR 60.106, except as prov1ded in 40 CFR 60.8(b), m conducting the performance tests required m 40 CFR 60.8 Subpart J. 

### (40 CFR 60.106(a)] Determine compliance with standards using the test methods and procedures specified m40 CfR 60.106(a) through (k). Subpart

### J_ Opaciry <= 

### 20 percent, except during the cleaning ofa fire box or building ofa new fire, soot blowing or lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitators, which may have an opaciry in excess of20percent for not more than one six-minute period in any 60 consecutive minutes Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0 6 lh/MMRTU ofhea! input. Which Months: All Year Statistical Bas1s: None specified Equipmenu'operational data recordkeeping by electronic or hard copy at the approved frequency. Record and keep on site for at least rwo years the data required to demonstrate: exemption from the provisions ofLAC 33:111.Chapter 15. 

### Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPA on request. 

### EQT 0084 H-901 • Hydrogen Plant Reformer 261 [LAC JJ:\11 ttoLB)

262 [LAC JJ.I\\.1 J

### IJ.C) 263 [LAC JJ:\11.1513) Opaciry 

### <= 20 percent, except during the cleaning ofa fire box or building ofa new fire, soot blowingor lancing, charging ofan incinerator, equipment changes, ash removal or rapping ofprecipitators, which may have an opacity in excess of20percent for not more than one six-minute period in any 60 consecutive minutes. Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0.6 lb/MMBTU ofheat input Which Months: All Year Statistical Rasis: None specified Equipment/operational data 

### recordkeeping by electronic or hard copyat the approved frequency. Record and keep on site for at least two years the data 

### required to demonstrate exemption from the provisions ofLAC 3 3:III.Chapter 15. 

### Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available to a representative ofDEQ or the U.S. EPA on request. 

### EQT 0085 LO • Loading Operations 264 (40 CFR 64.3(b)(3)] Specific QA/QC Procedures: Calibrate, operate, and mamtain instrumentation using procedures that take into account manufacturer's specifications_ (40 CFR 64.3(b)(3)] Page 28 of 49 Tl'QROI•7

### SPECIFIC REQUIREMENTS AI 10: 

### 312 -Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-{)0010-VS Air- Title V Regular Permit Minor Mod
EQT 0085 LO
- Loading Operations 265 [40 CFR 64.4(e))

266 [40 CFR 64.6(c)(l)]

267 [40 CFR 64.6(c)(2)] 268 [40 CFR 64.6(c)(2)] 269 [40 CFR 64.6(c)(4)] 270 [40 CFR 64.6(d)] 271 [40CFR64.7(a)] 272 [40 CFR 64.7(b)] 273 [40 CFR 64.7(c)]

274 [40 CFR 64.7(d)(l)]

275 [40 CFR 64.7(e)]

276 [40 CFR 64.8(a)] Complywith. the submitted implementation plan and schedule for

### i~stalling, testing and pefforrning any other appropriate activities prior to use 

### ofthe monitoring, if

### any ofthe approved monitoring in this pennitrequires installation, testing, or other necessary activities priorto use ofthe monitoring for purpOses of40 CFR 64. Implementmonitoring as expeditiously as practicable after approval ofthe monitoring pursuant to 40 CFR 64.6, but in no .case shall the period for completing installation and 

### beginning operation ofthe monitoring exceed 180 days after approval of thepennit. (40 CFR64.4(e)] Equipment/operational data monitored by technically sound method continuously Monitor the temperature at the flare tip whichwill detennine the continuous presense ofa flame in the flare and maintain records Ofteinperature at the flare tip. [40 CFR 64.6(c){l)] Which Months: All Year Statistical Basis: None specified An excursion orexceedance is defined as the absence ofa flame. (40 CFR 64.6(c)(2)] SubmjtNotification: Due at the DEQ upon the establisliment or

### reesb.bti~hment ofany exceedance orexcursion level, fOr purposes ofresponding to and reporting exceedances or excursions under40 CFR 64.7 and 64.8. (40 CFR 64.6(c)(2)] Equipment/operational data recordkeepingby electronic orhard copyat the approved frequency. (40 CFR 64.6(c)(4)] Schedule for installation,testing or final verification•ofoperational status: (40 CFR64.6(d)] Conduct the monitoring required under40 CPR 64 upon issuance ofa part 70 or71 permitthat includes such monitoring, orby such later date specified in the pennit pursuant to 40 CFR 64.6(d). (40 CFR64.7(a)] Maintain the monitoringrequired under40 CFR 64 at all tiines,. includingbut not limited to maintaining necessaryparts for routine repairs ofthe monitoring equipment [40 CFR 64.7(b)] Conductall monitoring required under40 CPR64 in continuousoperation (orcollect data at all required intervals) at all times that the pollutantspecific emissions unit is operating, except for, as applicable, monitoring malfunctions, associated repairs, and required quality assurance or control activities (including, as applicable, calibration checks and required zero and span adjustments). Do not use data recorded during monitoring malfunctions, associated repairs, and required quality assurance or control activities for purposes of40 CFR64, including data averages and calcul<itions. or for fulfilling a minimum data availability requirement, ifapplicable. Use all the data collected during all other periods in assessing the operation ofthe control device and associated control system. (40 CFR 64.7(c)] Restore operation ofthe pollutant-specific emissions unit (includingthe control device and associated capture system) to its normal or usual manner ofoperation as expeditiouslyas practicable upon detecting an excursion or exceci:dance, in accordance with good air pollution control practices for minimizing en:issions. Minimize the period ofany startup, shutdown or malfunction, and take any necessarycorrective actions to restore normal operation and prevent the likelyrecurrence ofthe c"ause ofan excursion or exceedance (other than those caused byexcused startup or shutdown conditions). [40 CFR64.7(d)(l)] Submit written notification: Due to the Office ofEnvironmental Compliance within 72 hours upon identifying a failu_re to achieve compliance with the " emission limitation orthe " standard for which, after approval ofmonitoring under40 CFR 64, the approved monitoring did not provide an indication ofan excursion orexceedance while providingvalid data, orthe results ofcoinplianceorperformance testing document a need to modify the existing indicatorranges ordesignated conditions. Ifnecessary, submit a proposed modification to 

### the part 70 or 71 pennit to address the necessary monitoringchanges. [40 CFR 64.7(e)] '. An absence ofa flame at the flare, as indicated when the temperature at the flare tip drops below 550 degrees F, occurring 6 times in any 12- month periods is the threshold limit ofexcursions**o~** exceedances at**~hich** implementation ofa QIP is required. [40 CFR 64.8(a)]
Page 29 of49 TPOR0147

### SPECIFIC REQUIREMENTS
- AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-40010-VS Air- Title V Regular Permit Minor Mod
EQT 0085 LO -Loading Operations 277 (40 CFR 64.8(b)]
278 [40 CFR 64.8(c)] 279 [40 CFR 64.8(c)] 280 (40 CFR 64.8(d)] 281 (40 CfR 64.9(a)]

282 [40 CFR 64.9(b)(J)] 283 (40 CrR 64.9(b)(J)]

284 (40 CrR 64.9(b)(l)] 285 [LAC 33:111.2107 B] 286 [LAC 33:111.2107.0] 287 [LAC JJ:IIL2107.E] 288 [LAC J3:11L50LC.6]

289 [LAC J3:IIL50LC.6] 290 [LAC J3:IIL50LC.6]

291 [LAC JJ:IIL50LC.6] Maintain a written Quality Improvement Plan (QIP) and 

### have it available for inspection. Include initially in the plan procedures for evaluating the control performance problems and, bao;cd on the results ofthe evaluation procedwes, modify the plan to mcludc procedures for conducting 

### one or more ofthe acuons specified in 40 CFR 64.8(b)(2)(i) through (b)(2)(v), as appropnale_ [40 CFR 64.8(b)] Develop and implemenl a QualiJy Improvement Plan (QIP) as expcduiously as practicable [40 CFR 64.8(c)) Submit notification: Noufy the DEQ 

### ifthe period for completing the Improvements 

### contained in the Quality Improvement Plan (QJP) exceeds 180 days from the dale on which the need 10 Implement the QIP was determined. [40 CFR 64.8(c)) Make reasonable changes to the Quality Improvement Plan (QJP) as the DEQ requires, upon any determination pursuant to 40 CFR 64.7(d)(2) subsequent lo implementalion. [40 CFR 64.8(d)) Submit report: Due on and after the date specified in 40 CFR 64.7(a) by which the owner or operator must use monitoring that meets the requirements of40 CFR 64. Submit momtoring repons to the: DEQ in accordance 'Nlth 40 CFR 70.6(a)(3)(iil). Include in a report for monitoring under 40 CFR 64, at a minimum, the infonnation required under40 CFR 70.6(a)(3)(iii) and the information specified in 40 CFR 64.9(a)(2)(1) through (a)(2)(1il), as applicable_ [40 CFR 64.9(a)] Comply wuh the recordkeepmg reqUirements spec1fied in 40 CFR 70.6(a)(3)(ii).[40 CfR 64.9(h)(l)) Equipment/operational data recordkeeprng by electronic or hard copy at the approved frequency. Maintain records ofmonitor performance data, corrective actions taken, any Mitten quality improvement plan required pursuant to 40 CFR 64.8 and any activities undertaken to implement a quality improvement plan, and other supporting information required to be maintained under 40 CFR 64 (such as data used to document the adequacy ofmonitoring, or records ofmonitoring maintenance or corrective actions). Maintain these records for a period ofat least five years [40 CFR 64.9(b)(l)) Monitoring data recordkccping by

### electronic or hard copy at the approved frequency.**~aintam** 

### these records for a period ofat least five years [40 CFR 64.9(b)(l)) VOC, Total >• 

### 90 % 

### DRE. Which Months: All Year Statistical Basis: None specified Equipment/operational data record.Jceeping by 

### electronic or hard copy at the regvlation's specified frequency. Keep records ofthe information specified in LAC 33:11L2107.D.3-4. Delennine compliance with LAC 33:11L2107.B using the methods in LAC 33:111.2107.E.I through 5, as appropriate. EquiP.menlloperational data<= 6.05 MM bbVyr. Noncompliance with this limitation is a reportable violation ofthe permit. Notify the Office of Environmental Compliance, EnfOrcement Division ifthroughput exceeds the maximum listed in this specific condition for any twelve consecutive month period. Which Months: All Year Statistical Basis: None specified Equipment/operational data monitored by technically sound method continuously. Which Months: All Year Statistical Basis: None specified Equipment/operational data recordkeeping by electronic or hard copy monihly. Keep records ofthe Jype ofproducts and quantily (throughput) through the loading faciliJy each month, as well as the total Jype ofproducts and quanlily (throughput) through the loadmg facility for the last twelve months. Make records**av~ilable** 

### for inspection by DEQ personneL Submit report: Due annually, by 

### the 3Ist ofMarch. Report the type ofproduct and total throughput for the preceding calendar year to the Office ofEnvironmental Compliance, Enforcement Division Page 30 of 49 TPQR01<H

## ' EQT 0086 SH -Air Dryer 

### (005) 292 [LAC 33:lli.IIOI.B]

293 [LAC 33:lll.l3I3.C] 294 [LAC 33:lll.l513] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-Q0010-V6 Air- Title V Reguiar Permit Minor Mod

Opacity<= 20 percent, exceptduring the cleaning ofa fire box orbuilding ofa new fire, soot blowing or lancing, charging ofan incinerator, 

### equipmentchanges, ash removal orrapping ofprecipitators, which mayhave an opacity in excess of20percent for not more than one six-minute period in any 60 

### consecutive minutes.
. Which Months: All Year Statistical Basis: None specified Total suspended particulate<= 0.6 lb/MMBTU ofheat input. Which Months: All Year Statistical Basis: None specified Equipment/operational data recordkeeping byelectronic orhard copyat the approved frequency. Record and keep on site for at least two years the data required to demonstrate exemption from the provisions ofLAC 33:lii.Chapter 15
.. Record all emissions data in the units ofthe standard using the averaging time ofthe standard. Make records available tO a representative ofDEQ or the 

### U.S. EPA on request. ' 

### EQT 0087 WW
- Wastewater Emissions 295 (40 CFR 61.355] 296 [40 CFR 61.356] Detennine compliance with 40 CFR 61 Subpart FF using the test methods and procedures specified in 40 CFR 61.355(a) through (i). as applicable. Subpart FF. Equipment/operational data recordkeeping byelectronic orhard copyat the regulation's specified frequency Maintain records as specified in 40 CFR.61.356(a) through (n), as applicable. Maintain eachrecord in a readily accessible location at the facility site for a period not less than two years from the date the information is recorded unless otherwise specified. SUbpart FF. 

### EQT 0108 OPE OWS- Dual Phase Extraction System- Oil/Water Separator 297 (40 CFR 61.355] Detennine compliance with 40 CFR 61 Subpart FF using the test methods and procedures specified in 40 CFR 61.355(a) through (i), as applicable. Subpart FF. 298 [40 CFR 61.356] Equipment/operational data recordkeeping byelectronic or hard copyat the regulation's specified frequency Maintain records as specified in 40 CFR 61.356(a) through (n), as applicable. Maintain each record in a readily accessible location at the facility site for a period not less than two years from the date the information is recorded WIIess otherwise specified. Subpart FF. 

### FUG 0002 FE
- Fugitive Emissions 299 (40 CFR 60.592(a)] 300 [40 CFR li0.592(d)] 301 (40 CFR 60.592(e)] 302 [LAC 33:111.2111] 303 [LAC 33:111.2121.8.1] Comply with the requirements of40 CFR 60.482-I to 482- I0 as soon as practicable, but no laterthan I80 days after initial startup. Subpart GGG. (40 CFR 60.592(a)] Complywith the provisions of40 CFR 60.485 except as provided in 40 CFR 60.593. Subpart GGG. [40 CFR 60.592(d)] Complywith the provisions of40 CFR 60.486 and 60.487. Subpart GGG. (40 CFR 60.592(e)] Equip all rotary pumps and compressors handling volatile organic compounds having a true vapor pressure of I.5 psia orgreaterat handling conditions with mechanical seals or other equivalent equipment. · Repair according to LAC 33:Ill.212i.B.3 any regulated component observed leaking by sight, sound, or smell, regardless ofthe leak's concentration.

Page 31 of 49 TPOR0147**~·**

### --- 

### -,------ 

### SPECIFIC REQUIREMENTS AIID: 312 ·Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-V& Air- Title V Regular Permit Minor Mod
FUG 0002 FE -Fugitive Emissions 304 [LAC JJJIL2121.B.2]

305 [LAC 33:111.2121.B.J] 306 (LAC JJ:IIL2121.C l.a.1]

307 [LAC ll:IIL2121.CI a.uJ

308 [LAC JJ:III.2121.C I ajii]

309 (LAC]] 111.2121.C.I.b.IJ

310 [LAC 33:111.2121.C l.b.1i]

311 [LAC JJJIL2121.CJ.bjii]

312 [LACJJ:lii.2121.C.IcJ 313 [LAC Jl:IIL2121.Cl.aJ

314 [LAC JJJIL2121CJ.b]

315 [LAC JJ:III.2121.C.4.c] Do not locate any valve, except safety pressure reliefvalves, valves on sample lines, valves on drain lines and valves that can be removed and replaced without a shutdown, at the end ofa pipe or line containing VOC unless the end ofsuch line is sealed with a second valve, a blind flange, a plug, or a cap. Remove such scaling dcv1ces only when the line is in use, for example, when a sample is bcmg taken. When the line has been 

### used and is subsequently resealed. close the upstream valve first, followed by

### the scaling device. Make every reasonable effort to repair a leakingcomponent, as described in LAC 33:111.2121.8, within 15 days, except as provided. Pump seals: VOC, Total monitored by40 CFR 60, Appendix A,**~ethod** 21 annually (one time per year). Ifa readmg of 10,000 ppmv or greater is recorded, a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:111.2121.8.3 Which Months: All Year Statistical Basis: None specified Valves m hqUJd service: VOC, Total momtored by 40 CFR 60, Appendix A, Method 21 annually (one ume per year) !fa readmg of 10,000 ppmv or greater is recorded, a leak is detected. 

### Ifa leak is detected. initiate repair provisions specified 

### m LAC 33:111.2121_8.3 Which Months: All Year Statistical Basis: None specified Process drains: VOC, Total monitored by40 CFR 60, Appendix A, Method 21 annually (one time per year). Ifa readmg of I0,000 ppmv or b"TCatcr is recorded, a leak is detected. 

### Ifa leak is detected, initiate repair provisions specified in LAC 33:111.2121.8.3 Which Months: All Year Statistical Basis· }.;one specified Compressor seals: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 quancrly (four times per year). Ifa readmg of I0,000 ppmv or greater is recorded, a leak is detected_ Ifa leak is detected, initiate repair provisions specified in LAC 33:111.2121.8.3. Which Months: All Year Statistical Bao;is: None specified Valves in gas service: VOC, Total monitored by40 CFR 60, Appendix A, Method 21 quarterly (four times per year). Ifa reading of I0,000 ppmv or greater is recorded, 

### a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:111.2121.8.3. Permittee may elect to comply withthe alternate standards for valves in LAC 33:111.2121.0 (skip period prov1s1ons). Which Months: 

### All Year Statistical Basis: None spec1f1ed Presswe reliefvalves in gas service: VOC, Total monitored by 40 CFR 

### 60, Appendix A. Method 21 quarterly (four times per year) Ifa reading of 10,000ppmv or greater is recorded, 

### a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:111.2121.8.3 Which Months: 

### All Y

### car Statistical Basis: None specified Pwnps: Seal or closure mechanism monitored by visual inspection/determination weekly (52 times peryear). Which Months: 

### All Year Statistical Basis: None specified Pressure reliefvalves: VOC, Total monitored by

### 40 CFR 

### 60, Appendix A, Method 21 within 

### 24 hours after venting to the atmosphere. If

### a reading of I0,000 ppmv or greater is recorded, a leak is detected. Ifa leak is detected, initiate repair provisions specified in LAC 33:111.2121.8.3. Which Months: All Year Statistical Basis: None specified All components: VOC, Total monitored by40 CFR 60, Appendix A, Method 21 upon each occurrence ofa leak detected by sight, smell, or sound,**u~less** electing to implement actions 

### as specif1ed in LAC 33:III.2121
..B.3. Which Months: 

### All Year Statistical Basis: None specified Inaccessible valves: VOC, Total monitored by 40 CFR 60, Appendix A, Method 21 annually (at a minimum). Which Months: 

### All Year Statistical Basis: None specified

Page 32 of49 rPOJ{01H

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: .PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Mln.or Mod
FUG 0002 FE -Fugitive Emissions 316 (LAC 33:Ill.2121.C.4.c]

317 (LAC 33:l!L2121.E.l] 318 (LAC33:!!1.2121.E]

319 (LAC 33:l!L212I.F] 320 ·(LAC 33:l!LSOI.C.6]

321 (LAC 33:l!LSOI.C.6]

322 (LAC 33:l!LSOI.C.6] Unsafe-to-monitor valves: VOC, Total monitored 

### by 40 CFR 60,**Appendix~** 

### Method 21 upon each occurrence.ofconditions allowing these 

### valves to be monitored safely. Which Months: All Year Statistical Basis: None specified When a leak that caimot be repaired on-line and in-place is located, affix to the leaking component a weatherproofand readily visible tag bearing an identification number and the date the leak is located. Date and remove the tag after the leak is repaired. Equipf11ent/operational data recordkeeping by 

### survey log upon each occurrence ofa leak. Include the leaking component information specified in LAC 33:111.2121.E.2. Retain the survey log for two years after the latter date specified in LAC 33:111.2121.E.2 and make said log available to DEQ upon request. Submit report: Due semiannually, 

### by the 31st ofJanuaryand July, to the Office ofEnvironmental Assessment, Air Quality Assessment Division. Include the information specified in LAC 33 :lll.212l.F.I through 4 for each calendar quarter during the reporting period. · Adding New Valves and Pumps.
. By no laterthan one hundred and twenty (120) days from the Effective Date ofthe Consent Decree, Calumet shall establish a tracking program for maintenance records (e.g., a Management ofChange program) to ensure that valves and pumps added to the Refinery during maintenance and construction are integrated into the LDAR program.[SA-MM-10-0090]. Calibration/Calibration Drift Assessment. 

### a. Calibration. Calumet shall conduct all calibrations ofLDARmonitoring equipment using methane as the calibration gas, in accordance with 40 C.F.R. Part 60, EPA Reference Test Method 21. 

### b. Calibration Drift Assessment. Beginningno later than the

### Effe~tive Date ofthe Consent Decree, Calumet shall conduct calibration drift ·. · 

### assessments ofLDAR monitoring equipment at the end ofeach monitoring shift, at a minimum. Calumet shall conduct the calibration drift assessment using, at a minimum, a 500 ppm calibration gas. Ifanycalibration drift assessment after the initial calibration shows a negative drift ofmore than I0% from the previous calibration, Calumetshall remonitor al1 valves that were monitored since the last calibration that had a reading greaterthan 100 ppm and shall remonitor all pumpsthat were monitored since

### tht last calibration that had a reading greaterthan 500 ppm.[SA-MM-10-0090]. Delay ofRepair. Beginning no laterthan the Effective Date ofthe ConsentDecree, for any equipment for which Calumet is allo:wed, under the applicable regulations, to place on the "delay ofrepair" list for repair: a. For all equipment, Calumet shall: i. 

### Require sign offby the unit supervisor/lead opera.tor.that the piece ofequipment is technically infeasible to repair without a process nnit shutdown, before the component is eligible for inclusion on the "delayofrepair" list; and ii. Include equipment that is placed on the "delay ofrepair" list in Caiumet(.S regular LDAR monitoring.[SA-MM-10-0090].

Page 33 of49 TPOR0147 

### '

### --SPECIFIC REQUIREMENTS AJ 

### 10: 312 -Calumet Lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-V&** 

### Alr- Title V Regular Permit Minor Mod

FUG 0002 FE

- Fugitive Emissions 323 (LAC 33 III.SOI.C6)

324 (LAC 33:111.SOI.C6)

325 (LAC 33:iii.SOI.C6)

326 (LAC 33JII.SOI.C6) Electronic Monitoring, Storing, and Reporting ofLDAR 

### DaHl. a. Electronic Storing and Reporting ofLDAR Data. Calumet ha.o:; and will continue to maintain an electronic database for storing and reporting LDAR data. By no later than six months after the EfTcctivc Date ofthe consent Decree, the electronic database shall include data identifying the date and time ofthe monitored event, and the operator and instrument used in the monitored event. 

### b. Electronic Data Collection During LDAR Monitoring and Transfer Thereafter. 

### By no later than 180 days after the Effective Date ofthe 

### Consent Decree, Calumet shall submit to the LDEQ operational specifications for the data logger, software, and monitoring equipment. By no later than the Effective Date ofthe Consent Decree, Calumet shall use dataloggers and/or electronic data collection devices during alll..DAR monitoring. Calumet, or its designated contractor, shall use its/their best efforts to transfer, on a daily basis, electronic data from electronic datalogging devices to the electronic database ofParagraph 55.o ofthe Consent Decree. For all monitoring events in which an electronic data 

### collection device is used, the collected monitoring data shall include a time and date stamp. Calumet may usc paper logs where necessary or more feasible (e.g., small rounds, rcmonitoring, or when dataloggers are not available or broken). and shall record, at a minimum. the identification ofthe t_echnician undertaking the monitoring, the date, and the identification ofthe monitoring equipment Calumet shall use 1ts best efforts to transfer any manually recorded monitoring data to the electronic databac;e ofParagraph 55.a ofthe Consent Decree within seven days ofmoniloring.[SA-MM- 10-0090). LDAR Aud1ts. 

### Commencing upon the Effective Date ofthe Consent Decree. Calumet shall implement at the Refinery wlde audits set forth in Paragraph 50 of the Consent Decree, to enswe theRefinery's compliance wnh all applicable LDAR regulations. The LDAR audits shall include but not be 

### limited to, comparative monitoring, records review, tagging, data management, and observation ofthe LDAR technicians(. calibration and monitoring lechniques [SA-MM-10-0090]1. LDAR Personnel By 

### no later than 30 days after the Effective Date ofthe Consent pecree, Calumet shall establish aprogram that will hold LDAR personnel accountable for LDAR performance. Calumet shall maintain a position within the Refinery responsible for LDAR management with the aulhorityto implement**improvements.[SA-M~-1**

### 0-0090). 

### Leak Detection and Repair (LDAR) Program Enhancements. In order to minimize or eliminate fugitive emissions ofvolat1le organic compounds (VOCs). benzene, volatile hazardous air pollutants (VHAPs). and organic hazardous airpollutants (HAPs) from equipment i1_1light liquid and/or in gas/vapor service, Calumet shall undertake the enhancements in this Section 

### J to the Refinery's LDAR program underTitle 40 ofthe Code ofFederal Regulations, Part 60, Subparts VV and GGG; Part 61, 

### Subparts

### J and V; Part 63, 

### Subpart CC: and applicable LDEQ LDAR regulations. The terms "equipmcnl," "m i•ghlliqUld 

### service" and "in gas/vapor service" shall have the definitions set fonh in the applicable provisions ofTitle 40 ofthe Code ofFederal Regulations. Part 60, Subparts VV and GGG; Part 61. 

### Subparts 

### Jand V; Part 63, 

### Subpart CC; and applicable LDEQ LDAR reguialions. Nolhing in lhis 

### Section

### J shall be construed to require Calumet to include in the enhancCd program described herein any equipment or units not otherwise subject 10 

### any applicable federal or slale LDAR regulalion [SA-MM- I0-0090).

Page 34 of 49 rPQR01C7

### FUG 0002 FE
- Fugitive Emissions 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-D0010-V6 Air- Title V Regular Permit Minor Mod

327 [LAC 33:111.501.C.6] 

### QNQC ofLDAR Data. Byno laterthan ninety (90) days after

### the Effective Date ofthe Consent Decree, Calumet, ora third partycontractor retained by Calumet, shall develop and implement a procedure to ensure a qualityassurance/quality control (QA/QC) review ofall data generated by LDAR monitoring technicians. Calumet shall ensure that monitoring dataprovided to Calumetby

### its contractors is reviewed for QA/QC before the contractor submits the data to Calumet. At leastonce per calendarquarter, Calwnet shall perform

### QAJQC ofthe contractor's monitoring data which shall include, butnot be limited to: numberofcomponents monitored per teclmician, time between monitoring events, and abnormal data patterns. 

### [SA-MM-I0-0090].

Page 35 of49 TPOR0147

### SPECIFIC REQUIREMENTS AJID: 312- Calumet Lubricants Co- Conori Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air- Title V Regular Permit Minor Mod
FUG 0002 FE
- Fugitive Emissions 328 [LAC JJIIISOJC.6] 

### Rccordkccping and Reporting Requirements. a. Wrincn Refinery-Wide LDAR Program No later than I80 days after the Effective Date ofthe Consent Decree. Calumet shall submit a copy to 

### LDEQ oftheRefincry's LDAR Program developed pursuant to Paragraph 47 in the Consent Decree. b. Submission ofOperational Specifications for Electronic Data Collection during LDAR Monitoring and Certification ofUsc ofElectronic Data Collection during LDAR Monitonng. By no later than 180 days after the Effective Date ofthe consent Decree, Calumet shall submit to LDEQ operational specifications designed to minimize the use ofany form ofdata collection and data transfer during and after LDAR monitoring other than electronic data collection and transfer c. As Part ofEither the Reports Required under the Refinery's applicable LnAR program or the Semi-annual Progress Report Procedures of Section IX (Recordkeeping and Reporting) ofthe Consent Decree. Consistent with the requirements ofSection IX (Recordkeepingand Reponing) ofConsent Decree, Calumet shall include the following information, at the following times, in its semi-annual progress reports: 

### L First Semi-annual Progress Report Due unde the Consent Decree. At the later of: the first semi-annual progress report due under the Consent Decree or the first semi-annual progress report for which the requirement becomes due, Calumet shall include the following: ( 1) A certification ofthe implementation of

### QNQC procedures for review ofdata generated by LDAR technicians as required by Paragraph 56 in the Consent Decree; (2) An identification ofthe mdividual at each Refinery responsible for LDAR perfonnance as required by Paragraph 57 in the Consent Decree; (3) A certification ofthe development ofa tracking program for new valves and pumps added during maintenance and construction as required by Para1:,"Taph 58 in the Consent Decree; (4) A certification ofthe implementation ofthe calibration drift assessment procedures ofParagraph 59 in the Consent Decree; (5) A certification ofthe implementation ofthe "delay ofrepair" procedures ofParagraph 60 in the Consent Decree, and

. (6) Information identifying the training measures that Calumet toOk to comply with the provisions ofParagraph 48 in the Consent Decree.

ii. Semi-annual Progress Report for the First Semi-Annual Reporting Period. Until termination ofthe Consent Decree, in the semi-annual progress report that Calwnet submits pursuant to Section IX ofthe Consent Decree for the first semi-annual reporting period ofeach year, Calumet shall include an identification ofeach audit that was conducted pursuant to the requirements ofParagraph 50 in the Consent Decree tn the previous calendar year including, for the Covered Refinery, an identification ofthe auditors, a summaryofthe audit results, and a summary ofthe actions that Calumet took or intends to take to correct all deficiencies identified in the audits. 

### iii. ln Each Report due under the Refinery's Applicable LDAR Program. ln each report due under the Refinery's applicable LDAR program, Calumet shall include: ' Monitoring. The following information on LDAR monitoring: (a) a list ofthe process units monitored during the quarter; (b) the number ofvalves and pumps monitored in each process unit; 

### (c) the number ofvalves and pumps found leaking; (d) the number of"difficult to monitor' pieces ofequipment monitored; (e) the projected month ofthe next monitoring event for that unit; and (I) a list ofall equipment currentlyon the "delay ofrepair" list and the date 

### each component

# wa• placed on the list. [SA-MM-10-0090).

Page 36 of 49 TPQA01•7

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-Q0010-V6 Air- Title V Regular Permit Minor Mod
FUG 0002 FE· Fugitive Emissions 329 (LAC 33:111.501.C.6]

330 [LAC 33:111.501.C.6] 

### Reporting, Recording, Tracking, Repairing and Remonitoring Leaks

### ~rYalves and Pumps Based on the Internal Leak Definitions. 

### a. Reporting. Forregulatory reporting purposes, Calumet may continue to report leak rates in valves and pumps againstthe applicable regulatory leak definition, or may use the lower, internal leak definitions specified in Paragraph 52 ofthe Consent Decree. 

### b. Recording, Tracking, Repairing and Remonitoring Leaks. Calumet shall record, track, repair and remonitor all leaks in excess ofthe internal leak definitions ofParagraph 52 ofthe ConsentDecree at such time as !hose definitions become applicable, in accordance with the applicable LDARprogram for the Refinery. [SA-MM-10-0090]. Written Refinery-Wide LDAR Program. By no later than 120 days after the Effective Date ofthe Consent Decree; Calumet shall develop and maintain a written facility wide program for compliance with all applicable federal and state LDAR regulations. Until termination ofthe Consent Decree, Calumet shall implement this program on a Refinery wide basis, and Calumet shall update the Refinery's program as necessary to ensure continuing compliance. The Facilitywide program shall include at a minimum: a. An overall. Refmery-wide leak rate goal that will be a target for achievement on a process unit-by-processunitbasis; b. An identification ofall equipment in light liquid and/or in gas/vapor service that has the potential to leak VOCs, HAPs, VHAPs, and benzene within process units that are owned and**main~ined** 

### bythe Refinery; c. Procedures for identifying leaking equipmentwithin process units that are oWned and maintained by the Refinery; d. Procedures for repairing and keeping track ofleaking equipment; e. Procedures for identifying and including in the LDAR program new equipment; and f. 

### A process for evaluating new and replacement equipmentto promote consideration**~nd** 

### installation Ofequipment that will minimize leaks and/or eliminate chronic leakers.[SA-MM-10-0090]. · 

### GRP 0010 Crude-Cap· Crude Cap (Capped Tank 47) 80,000 BBL IFR STORAGE TANK Group Members: EQT 0038EQT 0047 331 [LAC 33:Ill.501.C.6]

332 [LAC 33:111.50J.C.6] 333 [LAC 33:111.50l.C.6] 334 [LAC 33:Ill.50J.C.6] 

### Equipment/operational data<= 8.76 MM bbVyr. Noncompliance with this limitation is a reportable violation of

### the permit. Notify the Office of Environmental Compliance, Enforcement Division ifthe throughput exceeds the maximum listed in this specific condition for anytwelve consecutive month Period.
.. Which Months: All Year Statistical Basis: None specified · Equipment/operational data monitored bytechnically sound method continuously. Which Months: All Year Statistical Basis: None specified Equipment/operational data recordkeeping.by electronic or hard copy monthly. Keep records ofthe throughput**~ach** 

### month, aS well as the total throughput for the last twelve months. Make records available for inspection by DEQ personnel. Submit report: Due annually. bythe 31st ofMarch. Report the throughput for the preceding calendar year to the Office ofEnvironmental Compliance, Enforcement Division. · 

### GRP 0011 HEAVY CAP-1- Heavy VOL Cap-1 (Capped Tank 57) 80,000 BBLVFR S,TORAGE TANK Group Members: EQT0020EQT 0021 EQT 0022EQT0023EQT0025EQT0027EQT 0028EQT 0029EQT0030EQT 0031 E,QT 0032EQT0033EQT 0034EQT 0035EQT 0036EQT0039EQT 0041 EQT0042

, • I ,• ' Page 37 of49 TP0R0147

### SPECIFIC REQUIREMENTS AIIO: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-40010-VS Air- Title V Regular Permit Minor Mod
GRP 0011 HEAVY CAP-1- HeavyVOL Cap-1 (Capped Tank 57) 80,000 BBLVFR STORAGE TANK**~~E~~~~~~E~~~~~~~~~~~~** 335 [LAC 33:1li.501.C.6] Equipment/operational data<= 5.60 MM bbl/yr. Noncompliance with th1s limitation is a reportable violation ofthe pcrmtt Notify the Office of Environmental Compliance, Enforcement Division ifthe throughpUt exceeds the maximum listed in th1s specific condition for any twelve 

### consecutive month period. Which Months: All Year Statistical Basis: None specified 336 [LAC JJ:III.SOI_C.6] Equipment/operational data monitored 

### by technically sound method continuously. 

### Which Months: All Year Statistical Basis: None specified 337 [LAC 33:1I1.50l.C.6] Equipmcnlloperational data rccordkecping by 

### electronic or hard copy monthly. Keep records ofthe throughput each month, as well as the total throughput for the last twelve months. Make recordc; ava1lablc for inspection by DEQ personneL 338 [LAC 33:111.501.C.6] Submit report: Due annually, by the 3Ist ofMarch. Report the throughput for the preceding calendar year to the Office ofEnvironmental Compliance, Enforcement Division 

### GRP 0012 HEAVY CAP-2- HeavyVOL Cap-2 (Capped Tank 57) 80,000 BBLVFR STORAGE TANK Group !\1rmbcrs: F.QT 0052 339 (LAC 33:111.SOJ.C.6)
.

340 (LAC 33:IILSOI.C.6) 34i (LAC 33:111.SOJ.C.61 

### Equipment/operational data<== 720000 MM bbUyr. Noncompliance with this limitation is a reportable violation ofthe permit. Notify the Office ofEnvironmental Compliance. Enforcement Division ifthe throughput exceeds the maximum listed in this specific condition for any twelve consecutive month period. · Which Months: All Year Statistical Basis: None specified Equipment/operational data monitored by technically sound method continuously. Which Months: All Year Statistical Basis: None specified Submit report: Due annually, by the 31st ofMarch. Report the throughput for the preceding calendar year to the Office ofEnvironmental Compliance, Enforcement Division. 

### GRP 0013 UH VOL IFR CAP- UH VOL IFR Cap (Capped Tank 54) 10,000 BBL IFR STORAGE TANK Group Mrmbrrs: EQT 0049EQT 0050EQTOOSS 342 (LAC ll:IILSOI.C.6}

343 (LAC 33:11LSOJ.C.6) 344 (LAC 33 IILSOJ.C.6) 

### EqUJpmenl/operational data<= 

### 1.14 MM bbUyr. Noncompliance with this limitation is a reportable violation ofthe permit. Notify the Office of Environmental Compliance, Enforcement Division ifthe throughput exceeds the maximum listed in this specific condition for any twelve consecutive month period. Which Months: All Year Statistical Basis: None specified Equipment/operational data monitored by technically sound method continuously. Which Months: All Year Statistical Basis: None specified Equipment/operational data rccordkccping by electronic or hard copy monthly. Keep records ofthe throughput each month, as well as the total throughput for the last twelve months. Make records available for-inspection by DEQ personnel.
Page 38 of49 TPQR0\•7

### SPECIFIC REQUIREMENTS AIID: 312 ·Calumet Lubricants Co· Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~001**

### O·V6 Air·Title V Regular Permit Minor Mod
GRP 0013 UH VOL IFR CAP· UH VOL IFR Cap (Capped Tank 54) 10,000 BBL IFR STORAGE TANK 345 '[LAC JJ:II!.501.C.6] 

### Submit report: Due annually, by the 31st ofMarch. Report the throughput for the preceding calendaryear to the Office ofEnvironmental Compliance. Enforcement Division. 

### GRP 0014 VFR/HFR CAP· Light/Heavy VOL VFR/HFR Cap (Capped Tank 16) 2,000 BBLVFR STORAGE TANK**Gr~p** Members: EQT0024EQT0026EQTOOS9 346 (LAC J3:lll.501.C.6]

347 (LAC 33:lll.501.C.6] 348 (LAC 33:1I!.501.C.6] 349 [LAC 33:111.501.C.6] 

### Equipment/operational data<= 354120 bbVyr.

### Non~ompliru;c·e

## With**thi~** limitation is a reportable violation ofthe permit. Notifythe Office of Environmental Compliance, Enforcement Division 

### ifthe throughput exceeds the maximum listed in this specific condition for any twelve consecutive month period. WhichMonths: All Year Statistical Basis: None specified Equipment/operational data monitored 

### by technically sound method continuously. Which Months: All Year Statistical Basis: None specified , ... Equipment/operational data recordkeeping 

### by electronic or**har~** 

### copymonthly. Keep records ofthe throughput each month, as well as the total throughput for the last twelve months. Make records available "for inspection by DEQ personnel. Submit report: Due annually, bythe 31st ofMarch. Report the throughput for the preceding calendar year to the Office ofEnvironmental Compliance. Enforcement Division. · · 

### GRP 0015 NSPS Kb CAP· NSPS KB FR CAP (CAPPED TANK 76) 10,000 BBL STORAGE TANK Group Members: EQT 0003EQT0037EQT0040EQT 0056EQT 0057EQT 0062EQT0063EQT 0064 350 (LAC 33:lll.50l.C.6]

351 [LAC 33:111.501.C.6] 352 (LAC 33:111.501.C.6] 353 (LAC 33:111.501.C.6] 

### Equipment/operational data<= 1.53 MM bbl/yr. Noncompliance with this limitation is a reportable violation ofthe pennit. Notifythe Office of Environmental Compliance, Enforcement Division ifthe throughput exceeds the maximum listed in this specific condition for any twelve consecUtive month period. Which Months: All Year Statistical Basis: None specified Equipment/operational data monitored bytechnically sound metho'd continuously. Which Months: All Year Statistical Basis: None specified

- . · Equipment/operational data recordkeeping by electronic or hard copymonthly. Keep records ofthe throughput each month, as well as the total throughput for the last twelve months. Make records available for inspection by DEQ personnel. Submit report: Due annually, by the 31st ofMarch. Report the throughput for the preceding calendar year to the Office ofEnvironmental Compliance, Enforcement Division. 

### GRP 0017 PST- Pressurized Storage Tanks G'oop Momb"" EQT 0088EQT 0089EQT 0090EQT 009t EQT 0092EQT 0093EQT 0094EQT009SEQT 0096EQT 0097EQT0098EQT 0099EQT OIOOEQT Otot EQTOt02EQT Ot03EQT Ot04EQTOtOS EQTOI06 354 [LAC JJ:lll.2103.B] 

### Maintain working

### pressur~s sufficient at all times under

### no~al operating conditions to prevent vaporor gas loss to the atmosphere. Page 39**of.4~** TPOR0147 

### ---1

### ·SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-V&** 

### Air- Title V Regular Permit Minor Mod

CRG 0001 CD -Consent Decree Requlrments for Boiler and Heaters Group Members: EQT0067F.QT 0068F.QT0074EQT 007SEQT 0076EQT0071t:QT0078EQT 0079EQT0080f.QT0081 EQT 0082Jo:Q·r 008JEQT 0084 355 [LAC 33.11LSOI.C.6] 356 [LAC ll:lll 50LC.6]

357 [LAC 33 111.50LC.6]



### UNF 0001 EF- Entire Facility 358 [40 CFR 60.] 359 (40 CFR 61.] 360 [40CFR68.12(b)(l)) 361 (40 CFR 68.12(b)(2)) 362 [40 CFR 68.12(b)(3)) 363 (40 CFR 68.12(bX4l) Calumet shall undertake measures to reduce 502 emissions from refinery heaters and boile_rs by restricting 1125 in refinery fuel gas and by agreeing not 10 conhnuc and/orcommence the burning offuel oil except under the provisions set forth herein**[SA-~M-** I0-0090]. Elimination ofFuel Oil Burning From the Effective Date ofthe Consent Decreet through termination, Calumet shall continue not to bum Fuel Oil in anyexisting heateror boiler,

.except dunng natural gas curtailment.(SA-MM-10-0090). NSPS Applicabilityoflleaters and Boilers. a. L"pon the Effective Date ofthe Consent Dccn:c, the existing heaters and boilers at the facility, as that term is used in 40 C F.R Pan 60, Subparts A and 

### J. and shall bc subject to and comply with the requirements ofNSPS Subparts A and J. Unless exempted 

### by regulation, 

### by no later than the Effective Date

## Ofthe Consent Decree,**Cal~met** shall install, ccnify, calibrate, maintain and operate a fuel gas CEMS at the Covered Refmcrics in accordance with the rcqUI_rements of40 C.F.R. 

### §§ 60.11, 60.13 and Part 60 Append1x A, and the applicable JXrformance specification test of

### 40 C.F.R. Part 60 Appcnd1ces R and F. These CEMS will be used to demonstrate compliance with emission limits. b. Compliance with the Consent Decree constitutes compliance with certain NSPS Subpart A requirements. for each fuel gas combustion device that becomes an "affected facility." as that term is used in 40 CF_R. Part 60, Subparts A and J, pursuant to this Paragraph 15 ofthe Consent Decree. compliance with the relevant monitoring requirements ofthis Consent Decree for such fuel gas combustion devices will satisfy the notice requirements of40 C.F.R. 60.7(a) and the initial performance test requiremenLc; of40 C.F.R. 60.8(a). c. If, prior to the tc:nnination ofthe Consent Decree, any heater, boiler or other fuel gas combustion device becomes subject to NSPS Subpart Ja for a particular pollutant due to a ''modification" (ac; that term is defined in the final Subpart Ja rule). the modified affected facility shall be subject to and comply with I'SPS Subpart Ja 10 lieu ofNSPS. Subpart 

### 1for that regulated pollutant Io wh1ch a standard applies as a result ofthe modification. d. If, prior to the termination ofthe Consent Decree, any heater, boiler or other fuel gas combll'ition device becomes subject to NSPS Subpart Ja due to a "reconstruction" (as that term is defined in the final SubpartJa rule), the**r~constructed** facility shall be subject to and comply with NSPS Subpart Ja for all pollutants in lieu ofSubpart J.[SA-MM-10-0090]

All affected facilities shall complyWlth all applicable provisions in 40 CFR 60 Subpart A. All affected facilities shall complywith all applicable provisions in 40 CFR 61 Subpart A. Equipment/operational data recordkeeping by electronic or hard copy continuoLtc;ly. Document that the nearest public receptor is beyond the distance to a toxic or flammable endpoint defined in 68.22. (40 CFR 68.12(b)(l)) Complete the five-year accident history for the process as providedin 68.42. (40 CFR 68.12(b)(2)] Ensure that response actions have been coordinated with local emergency planning and response agencies. (40 CFR 68.12(b)(3)] Include in the RMP the certification specified 10 68.12(b)(4). (40 CFR 68.12(h)(4)] Page 40 of 49 T'P()A01U

### UNF 0001 EF

- Entire Facility 364 [40 CFR 68.150]

365 [40 CFR 68.155] 366 [40CFR68.160] 367 [40 CFR 68.165] 368 [40 CFR 68.168] 369 [40 CFR 68.180] 370 [40 CFR 68.190(c)] 371 [40CFR68.190] 372 [40 CFR 68.200] 373 [40 CFR 68.22] 374 [40 CFR 68.25] 375 [40 CFR 68.28] 376 [40 CFR 68.30] 377 [40 CFR 68.33] 378 [40 CFR 68.36(b)] 379 [40 CFR 68.36]

380 [40 CFR 68.39] 381 · [40 CFR 68.42] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 ., Permit Number: 3080.00010-VS Air- Title V Regular Permit Minor. Mod



### Submit Risk ManagementPlan (RMP): Due no later than June 21, 1999, or three years after the date on which a regulated substance is first Jisted under 68.130, orthe date on which a regulated substance is first present above a threshold quailtity 

### in'.\ process. Submit in a method and format to a central point as specified by EPA prior to JW1e 21, 1999. Provide .in the RMP an executive sununary that includes a briefdescription ofthe elements listed in 68.155(a) through (g). Complete a single registration form and include in the RMP. Covel- all regulated substances handled in covered processes. lnclude in the registration the information specified in 68.160(b)(1) through (13). 

### Submit in the RMP information one worst-case release scenario for each Program 1process. Include the data specified in 68.165(b)(l) through (13). Submit in the RMP the information provided in 68.42(b) on each accidentcoveredby 68.42(a). Provide in the RMP the emergency response information listed in 68.180(a) through (c). 

### Submit revised registration to EPA: Due within 

### six months after a stationary source is no longer subject to 40 CFR 68. Indicatethat the stationary source is no longercovered. [40 CFR 68.190(c)] · 

### Review and update the RMP as specified in 68.190(b) and submit 

### it in a method and format to a central point specified 

### by EPA prior to Jun·e 21, 1999.
. 

### Maintairi records supporting the implementation of40 CFR 68 for five years unless otherwise provided. Use the endpoints specified in 

### 68.22(a) through (g) for analyses ofoffsite consequences. Analyze the release scenarios in 68.25, as specified in 68.25(a) through (h). 

### Identify and analyze at least one alternative release scenario for each regulated toxic substance held in a covered process(es} and at least one alternative release scenario to represent all flammable substances held in covered processes, as specified in 68.28(b} through (e). Estimate in the RMP the population within a cifcle with its center**~t** 

### the point ofthe release and a radius determined by the distance to the endpoint defined in 68.22(a). · List in the RMP environmental receptors within a circle' with its centerat the point ofthe release and a radius detennined by the distance to the endpointdefined in 68.22(a). Submit revised RMP: Due within six months after changes in processes, quantities stored orharldled. orany otheraspect ofthe stationary source increase ordecrease thedistance to the endpoint by a factor oftwo or more. [40 CFR 68.36(b)] Review and update the offsite consequence analyses at least once evyry five years. COmplete a revised analysis Within six months if.changes in processes, quantities storedor handled, orany other aspect ofthe stationary source might reasonably be expected to increase ordecrease the distance to the endpointbya factor oftwo or more. · Equipment/operational datarecordkeeping by electronic or hard copycontinuously. Maintain the records specified in 68.39(a) through (e) on the offsite consequence analyses. · . lnclude in the five-year accident history all accidental releases from covered processes that resulted in deaths, injuries, or significant property damage on site, or known offsite deaths, injuries, evacuations, sheltering in place, propertydamage, orenvironmental damage. Include the information specified in 68.42(b)(I) through (I0) for each accidental release
.. Page41of49, TPOR0147

### UNF 0001 EF
- Entire Facility 3R2 (LAC 33:1111103) 3X3 (LAC 331111303.8) 384 (LAC 33:1112113 A) 385 (LAC 33:111219]

386 (LAC 33:111.2901.0) 387 (LAC 33 IIL2901.F)

388 (LAC 33:111501.841

389 (LAC 33:111SOI.C.1 

### I

390 (LAC 33:111.501.C6] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cot1on Valley Refinery Activity Number: PER20120002 Permit Number: 3080-()0010-VS Air- Title V Regular Permit Minor Mod

Emissions ofsmoke which passonto or across a public road and create a traffic hazard by Impairment ofvisibility as defined in' LAC 33:IILIll or intensify an extsting traffic hazard condition are prohibited. Emissions ofparticulate matter which pass onto or across a public road and create a traflic hazard 

### by impairment ofvisibility or intensify an existing traffic hazard condition are prohibited. Maintain best practical housekeeping and maintenance 

### practices at the h1ghcst possJble standards to reduce the quantity oforganic compounds 

### emissions. Good housekeeping shall include, but not be. limited to, the practices listed in LAC 

### 33:111.2113.A.I-5. Failure to 

### pay the prescribed application fee or annual fee as provided herein, within 90 days after the due date, will constitute a violation of these regulations and shall subject the person to applicable enforcement actions under the Louisiana Environmental Quality Act including. but not limited to, revocation or suspension ofthe applicable permit, license, registration. or variance. Discharges ofodorous substances at or beyond property lines which cause a perceived odor intensity ofsix or greater on the specified eight point bulanol scale as dc1cnnmcd by Mc1hod 41 ofLAC 33:111.2901.G arc prohibllcd. 

### Jfrequested to monitor for odor intensity, take and transport samples in a manner wh1ch minimizes alteration ofthe samples either hy contamination or loss ofmaterial. Evaluate all samples as soon after collection as possible in accordance with the procedures set forth in LAC 33:111.290i.G. 

### The owner or operator ofany sowcc which IS 

### not a major sowce rn.ay apply for an cxcmphon from the penrunmg requirements ofthis Chapter provided each ofthe following criteria arc met i. the source emits and has the potential to emit no more than 

### 5 tons per year ofanyregulated air pollutant; ii. 

### the source emits and has the potential to emit less than the minimum emission rate listed in LAC 

### 33:111.51 I2, Table 

### 51.1, for each Louisiana toxic air pollutant; iii. no enforceable pcnnit conditions are necessary to ensure compliance with any applicable requirement; and IV. 

### no public notice is required for any permitting or other activity at the source. Any source to which an exemption is granted under this Paragraph shall be operated in accordance with any terms stated in the exemption and upon which the decision to grant the exemption was based. Failure to operate the source in accordance with the tenns ofthe exemption may tenninate such exemption and shall constitute a violation ofthe general duty to operate under a pennit established pwsuant to Subsection C ofthis Section. Submit permit application: Due prior to construction, reconstruction or modification unless otherwise provided in LAC 33:11J.Chapter 5. Submit a timely and complete pennit application to the Office ofEnvironmental Services, Air Pennits Division, as required in accordance with the procedures in 

### LAC 33:111.Chaptcr 5. Annual Program. By 

### no later than 180 

### days after the Effective Date ofthe Consent Decree, Calumet shall establish an annual program ofreviewing process information for the facility,**incl~ding** 

### but not limited to 

### construction projects, to enswe that all new benzene waste streams arc included in the facility's waste stream inventory (SA-MM-10-0090)

Page 42 of49 TPQR01C7

### UNF 0001 EF -Entire Facility 391 [LAC 33:111.501.C.6]

392 [LAC 33:111.50i.C.6]

393 [LAC 33:111.50i.C.6]

394 [LAC 33:111.50i.C.6] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-0001O-V6 Air- Title V Regular Permit Minor Mod

At Variable Times. As soonas practicable, but in no event later than 180 days afterthe effective date or establishment ofany surviving emission limits, standards and schedules under Section V ofthe Consent Decree, Calumet shall submit appliCations to LDEQ to incorporate those emission limitations, standards, and/or schedules into the Title V permitofthe Covered Refinery. Following submission ofthe permit applications, Calumet shall cooperate with LDEQ bypromptly submitting to LDEQ all information that LDEQ seeks following its receipt ofthe permitapplications.[SAMM-10-0090]. Benzene Spills.
. Foreach spill at the facility after the Effective Date of ofthe Consent Decree, Calumet·shall review such spills to delermine 

### ifbenzene waste was generated. Calumet shall include benzene generated bysuch spills in the TAB for for the facility. [SA-MM-10-0090].' · Benzene WasteNESHAP Program Enhancements. In addition to continuing to comply with all applicable ;equirements of40 C.F.R. Part 61, Subpart FF (Benzene Waste, NESHAP, or Subpart FF), Calumet agrees to undertake the measures set forth in Paragraphs 33 through 45 ofthe ConsentDecreeto ensure continuing compliance

_ with Subpart FF and to minimize or eliminate fugitiVe benzene.waste emissions.[SA-MM-10-0090]. cOmmercial UnavailabilityofControl Equipment. Calumet shall be solely responsible for compliance

### With anY deadline or the performance ofany work described in Sections 

### V and 

### VI ofthe Consent Decree that requires the acquisition and installation ofcontrol equipment. Ifit appears that the conunercial unavailability ofanycontrol equipmentmaydelay Calumet£,S performance ofwork according.to an applicable implementation schedule, Calumet shall notify LDEQ ofany such delays as soon as Calumet reasonablyconcludes that the delaycould affect its ability to complywlth the implementation schedule set forth in the Consent Decree. Calumet shall propose for approval byLDEQ a modification to the applicable schedule ofimplementation. Prior to the noticerequired by this Paragraph 

### VII in the Consent Decree,**Cal~et** must have contacted a reasonable number ofvendors ofsUch equipmentor additive and obtained a written representation (orequivalentcommunication to LDEQ) from the vendor thatthe equipment is commercially unavailable. In the notice, Calumet shall reference this Paragraph 

### VIII ofthe Consent Decree, identify the milestone date(s) it contends it will notbe able to meet, provide LDEQ with written correspondence to the vendor identifying efforts made to secure the**Cot:~trol** equipment, and describe the specific efforts Calumet has taken and will continue to take to find such equipment. Calumet maypropose a modified schedule or modification ofother requirements ofthe Consent Decree to address such commercial unavailability. Section XV ofthe**Cons~nt** Decree ("Dispute Resolution") shall govern the resolution ofany claim ofcommercial unavailability. LDEQ shall not unreasonably withhold its consent to requests for modifications ofschedules ofimplementation ifthe requirements ofthis Paragraph are met. All modifications to anydates initially set forth in the Consent Decree or in any approved schedule ofimplementation shall be signed in writing by LDEQ and Calwnet. Stipulated penalties shall not accrue nor be due and owingduring any period between an originally-scheduled implementation date and an approved modification to such date; provided however, that LDEQ shall retain the right tO seek stipulated penalties ifLDEQ does not approve a modification to a date or dates. The failure by Calumet to secure control equipment shall not constitute a force majeureevent triggeringthe requirements ofSection XIV ofthe Consent Decree; this Paragraph shall apply. [SA-MM-10-0090].

Page 43 of49 TPOR0147

." i•. • _"**~** I

### UNF 0001 EF -Entire Facility 395 [LAC 33JII.501.C6)

396 [LAC 331JL501.C6)

397 [LAC 331JL501.C6) 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number:**3080~0010-VS** 

### Air- Title V**Regul~r** 

### Pen\iii Minor''!'lod

Current Compliance Status and Refinery Compliance Slarus Changes As ofthe Effective Date ofthe Consent Decree Calumet believes that the facility has a Total Annual Benzene (TAB) ofless than 10 Mglyr. Calwnet will review and verify the TABs at the facilityis consistent with the requirements ofParagraph 35 ofthe Consent Decree. Ifal any time from the Effective Date ofthe Consent Decreet through 

### its termination is determined to have a TAB equal to or greater than 10 Mg/yr, Calumet shall comply with the compliance option set forth at 40 C.F.R. § 61.342(e) (heremafter referred to a< the "6 BQ compliance option") [SA-MM1 0-0090) 

### Exception to General Prohibition. a. Conditions Precedent to Utilization ofthe Exception to the General Prohibition against the Use or Generation ofthe Consent Decree Emissions Reductions. Utilization ofthe exception set forth in Paragraph 72.b in the Consent Decree to the general prohibition against the generation or utilization ofthe Consent Decree Emissions Reductions set forth in Paragraph 72 in the Consent Decree is subject to the followlng conditions: i. Under no circumstances shall Calumet use the Consent Decree**~missions** Reductions for netting and/or offsets prior to the time that acrual the Consent Decree Emissions Reductions have occUITed; ii. Consent Decree Emissions Reductions maybe used only at the Covered Refinery that generated them; iii. The Consent Decree Emissions Reductions provisions ofthis Consent Decree are for pw-poses ofthis Consent Decree only and neither Calumet, nor any other entity may use**t~e** Consent Decree Em1ssions Reductions for any purpose, including in any subsequent permitting or enforcement proccedmg, except

## as provided herein; and iv. Calumet still shall 

### be subject to all federal an.d state regulations applicable to the PSD, major non-attainment and/or minor NSR pennining process. b. Exception to General Prohibition. Notwithstanding the general prohibition set forth in Paragraph 71 in the Consent Decree Calumet may use 20 tons per yearofNOx and I0 tons per year ofVOCs from the Consent Decree Emissions Reductions ascredits or offsets in any PSD, major non-attainment and!or minor NSR permit or permit proceedingoccurring after the Effective Date ofthe Consent Decree, provided that the new or modifiedemissions unit is beingconstructed or nlodified for purposes ofcompliance with Tier II gasoline or low sulfur diesel requirements; and already has emissions limits at the time ofpermitting as follows: 

### i. Forheaters and boilers. a limit of0.020 lbs NOx permillion BTU or less on a 3-hourrolling average basis; ii. For heaters and boilers, a limit ofO.IO grams ofhydrogen sulfide perdry standard cubic foot offuel gas or 20 ppmvd S02 corrected to 0% 02 both on a 3-hourrolling average: · :·- _ · '· : . · •1 iii. Forheaters and boilers, no liquid or solid fuel fuing

### ~-~pabiiities! andi iv. For SRPs, NSPS Subpart

### J emission limits.[SA-MM-10-0090). General Prohibition.**Calum~t** shall not generate oruse any NOx, S02, PM, VOC. or CO emissions reductions that result from any projects conducted or controls required pursuant to the Consent Decree as nening reductions or emissions offsets in any PSD, major non-anainment anc.Vor minor New Sowce Review (NSR) pennit or pennit proceeding.[SA-MM-10-0090).

Page 44 of 49**T~DI•7**UNF 0001 EF -Entire Facility 398 [LAC 33:111.501.C.6]

399 [LAC 33:111.501.C.6]

400 [LAC 33:111.501.C.6] 

### SPECIFIC REQUIREMENTS AI 10: 312
- Calumet lubricants Co -Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-Q0010-V6 Air- Title V Regular Permit Minor Mod



### Outside the Scope ofthe General Prohibition. Nothing in the SectionVII in the ConsentDecree is intended to prohibit Calumet from seeking to: (1) utilize orgenerate emissions credits or reductions from refinery units that are covered bythe consent Decree to the extent that the proposed credits orreductions represent the difference between the emissions limitations set forth in the COnsent Decree for these refineryunits 

## and the more stringent emissions limitations that Calumet may elect to accept for these refineryunits in a permitting process; or (2) utilize orgenerate emissions credits or reductions on refinery**~}nits** that are not covered bythe Consent Decree.[SA-MM-10-0090). Securing Permits. Foranyworkunder Sections V orVI ofthe Consent Decree thatrequires a federal, state and/or local permit orapproval, Calumet shall be 

### responsible for submitting in 

### a timely fashion applications for federal, state and local pennits and approvals for work and activities required so thatpermit orapproval decisions can be made in a timely fashion. Calumet shall use its best efforts to: (I) submit permit applications (i.e., applications for permits to construct, operate, or their equivalent) that complywith all applicable requirements; and (2) secure approval of permits afterfiling the applications, includingtimely supplyingadditional information, 

### ifrequested. If

### it appears that thefailure ofa 

### governmental entity to act upon a timely-submitted permit application maydelay Calumet[.s performance of work according to an applicable implementation schedule, Calumet shall notifY LDEQ ofany such delays as soon as Calumet reasonablyconcludes that the delay could affect its 

### ability to complywith the implementation schedule set forth in the Consent Decree. Calumet shall propose for approval by LDEQ a modification to the applicable schedule ofimplementation. LDEQ shall not unreasonably withhold its consent to requests for modifications ofschedules of implementation ifthe requirements ofthis Paragraph are met. All modifications to any dates initially set forth in this Settlement or in any approved schedule ofimplementation shall be signed in writing by LDEQ and Calumet. Stipulated penalties shall not accrue nor be due and owing during anyperiod between an originally-scheduled impl.ementation date and an approved modification to such date; provided however, that 

### LDEQ shall retain the right to seek stipulated penalties ifLDEQ does not approve a modification to a date or dates. The failure ofa governmental entity to act upon a timely-submitted permit or approval application shall not constitute a force majeure event triggering the requirements ofSection XIV ofthe Consent Decree; this Paragraph shall apply.[SA-MM-10-0090]. 

### Tail Gas Incidents: a. Investigation, Reporting, Corrective Action and Stipulated Penalties. The Cotton Valley Refinery does not have Tail Gas Treatment Units; therefore, the Cotton Valleyhas not had any Tail Gas Incidents. The provisions ofthis Paragraph 30 ofthe Consent Decree are not applicable to the Cotton Valley unless the facility adds a Tilil Gas Treatment Unit. ForTail Gas Incidents shall follow the same investigative, reporting, corrective action and assessment ofstipulated·penalty procedures as those outlined 

### in Paragraphs 26

- 28 ofthe Consent Decree for Acid Gas Flaring Incidents. Those procedures shall be applied to TGTU shutdowns, bypasses ofa TGTU, unscheduled shutdowns ofa Sulfur Recovery Plant, orother miscellaneous unscheduled Sulfur RecoveryPlant events which result in a Tail Gas Incident (SA-MM-10-0090]
.

Page 45 of49 TPOR0147

### UNF 0001 EF • Entire Facility 401 [LAC ll:IILIOI.C.6}

402 [LAC JJ:IIL501.C.6J

403 (LAC Jl:lll 507.A.I.a} 404 (LAC 33 IIL507.A.I.b}



### 405 [LAC 33:111.507.A.I.c) 406 [LAC 3311L507.A.I.d} Training 

### -SPECIFIC REQUIREMENTS AI 10: 

### 312 ·Calumet Lubricants Co ·Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080.00010·V6 Air·Title V Regular Permit Minor Mod

a. Calumet currently has one employee who draws benzene waste samples for BenZene Waste r\ESHAP ptuposcs at the facility. 

### By no later than 

### I80 days after the Effective Date ofthe Consent Decree, Calumet shall develop and begin implementation ofannual (i.e.: once each**calcnd~** year) "refresher" training for that employee. Calumet shall also provide annual training to all other employees who draw beru:cne waste samples for Benzene Waste NESHAP purposes. b_ Ifand when the facility's TAB reaches 10 Mg!yr ormore, Calumet shall complete the development ofstandard operating procedures for all control equipment used to complywith the Benzene Waste NESHAP. Calumet shall complete an initial training program regarding these procedwes for all operators assigned to this equipment. Comparable trainiJlg shall be provided to any persons who subsequently become operators, prior to their assumption ofthis dury. "Refresher" training shall**b~** perfonned on a periodic basis. Calumet shall propose a schedule for the initial and refresher training at the same time that Calumet proposes a plan, pursuant to either Paragraph 36.b ot the Consent Decree, or Paragraph 4J.d ofthe Consent Decree, that identifieS the compliance strategy and schedule that Calumet will implement to come intocompliance with the 6 BQ compliance option. c. As part ofCalumet's training program, it must ensure that the employees ofany contractors htred to perfOrm the requirements ofthis 

### Paragraph are properlytratned to implement all provisions ofthas Paragraph at the facility_ [SA-MM-10--0090]. Within 180 Days After the Effective Date ofthe Consent Decree. As soon as practicable followmg the Effective Date ofthe Consept Decreet. but in no event later than 180 days followmg the Effective Date ofthe Consent Decree, Calumet shall submit applications to LDEQ to incorporate the surviving emission lim1ts, standards, and/or schedules required bythe Consent Decree: that are effective as ofthe Effective Date ofthe Consent Decree mto the Title V permit ofthe Covere.d Refinery. Following submission ofthe pennit applications, Calumet shall · 

### cooperate with LDEQ by promptly submitting to LDEQ all information that LDEQ S<eks following ats receipt ofthe permit applications.[SA· MM·l0-0090]_ Any maJor sowce as defined in LAC 33:111.502 is designated a Part 

### 70 sowce and is required to obtain a permit which will meet the 

### requirements ofLAC 33:111.507. Any nonmajor (area) source ofhazardous air**pollu~nts** required to obtain an operating permit pursuant to regulations promulgated under section 112 ofthe federal Clean Air Act is designated a Part 70 source and is required to obtain a permit which will meet the requirements ofLAC 

### 33:111.507. Any nopmajor sowce required to obtain an operating pennit pursuant to regulations promulgated under section I,II ofthe federal Clean Air Act 

### is designated a Part 70 source and is requtred Ia 

### obtaina permit which will meet the requirements ofLAC 33:111.507. Any affected source, as defined in LAC 33:111.502, pursuant to the acid rain provisions oftitle IV ofthe federal Clean Air Act is designated a Part 70 source and is required to obtain a permit whichwill meet the requirements ofLAC 

### 33:111.507.

Page 46 of49 Tl'QROI<H

### UNF 0001 EF- Entire Facility 407 [LAC 33:111.507.8.2]

408 [LAC 33:lll.507.C.I]

409 [LAC 33:111.507.C.3]

410 [LAC 33:111.507.E.4]

411 [LAC 33:111.511]

412 [LAC 33:111.517.A.1]

413 [LAC 33:111.517.A.2]

414 [LAC33:111.517.B.I] 

### SPECIFIC REQUIREMENTS AIID: 312- Calumet lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080-00010-VS Air- Title V Regular Permit Minor Mod

No Part 70 source may operate afterthe time that the owneror operator ofsuch source is required to submit a permit application under Subsection C ofthis Section, unless an application has been submitted by the submittal deadline and such application provides information addressingall applicable sections ofthe application form and has been certified as complete 

### in accordance with LAC 33:Ill.517.8.1. No Part 70 source mayoperateafter the deadline provided for supplying additional information requestedby the permitting authority under LAC 33:111.519, unless such additional informatio!l has been submitted within the time specified

### by the permitting authority. Permits issued to the Part 70 source under this Section shall include the elements required by40 CFR 70.6. The Louisiana Department ofEnvironmental Quality hereby adopts and incorporates byreference the provisions of40 CFR 70.6(a), as in effecton July21, 1992. Upon issuance ofthe permit, the Part 70 source shall be operated 

### in compliance with all terms and conditions ofthe

### perriut~ Noncompliance with any federally applicable term or condition ofthe permit shall constitute a violation ofthe Clean AirAct and shall be'grounds for enforcementaction; for permit termination, revocation and reissuance, or revision; or for denial ofa Permit rene'wal application. Any Part 70 source for which construction oroperation has begun priorto the effective date ofLAC 33:III.507 shall submitan application for an _initial Part 70 permit. Permit applications shall be prepared in accordance with LAC 33:111.517 and with forms and guidance provided byDEQ. and shall be submitted no laterthan one year afterthe. effectivedate ofthe Louisiana Part 70 program. Any source thatbecomes subject to the requirements ofLAC 33:lll.507 after the effectivedate ofthe Louisiana Part 70 programdue to regulations promulgated by the Environmental ProtectionAgency orbythe Department ofEnvironmental Quality shall submit an application to the Office ofEnvironmental Services, Air Permits Division, in accofdance with the requirements established by the applicable regulation. In 

### flO case shall the required application be submitted later than oneyearfrom the date on which the source first becomes subject to LAC 33:Ill.507. Any permitapplication to renewan existing pennit shall be submittedat least six months priorto the date ofpermit expiration, orat such earlier time as maybe requiredby the existingpermit orapproved bythe permitting authority. In no event shall the appliCation for permit renewal be submitted more than 18 months before the date ofpermit expiration. Submit notification: Due to the permitting authoritypriorto the initiation ofany project which will result in emission reductions. Include in the notification a description ofthe proposed action, a location map, a description ofthe composition ofaircontaminants involved, the rate and temperature ofthe emissions, the identity ofthe sources involved and the change in emissions. Make any appropriate permit revision reflecting the emission reduction no later than 180 days after commericement ofoperation and in accordance with the procedures ofLAC 33:JII.Chapter 5. Submit permit application: Due prior to commencement ofconstruction, reconstruction, or modification ofthe source, for new or modified sources. Do not commence construction, reconstruction, or modification ofany source required to be permitted under LAC 33:III.Chapter 

### 5prior to approval bythe permitting authority. ' Submit permit application: Due by the date established for'submittal in accordance with LAC 33:lll.507.C. The permit application is for an initial permit to be issued in accordance with LAC 33:IIi.507. Provide a copyofeach permit application pertaining to a major Part 70 source to EPA at the time ofapplication submittal to the permitting authority. Any application form, report, orcompliance certification submittedunderthis Chapter-shall contain certification by a responsible official of truth, accuracy, and completeness. The certification shall state that, based on information and beliefformed afterreasonable inquiry, the statements and information contained in the application are true, accurate, and complete.

Page 47 of49 TPOR0147

### UNF 0001 EF
- Entire Facility 415 [LAC 33:111517.CJ

416 (LAC 33:111.517.0] 417 (LAC Jl:111.517.E] 418 (LAC JJ:111517.GJ 419 (LAC 33 111535] 420 (LAC 33 111.5609AI.b] 421 (LAC 33 111 5609 A 2 b) 422 (LAC 33:1115609.A.3.b] 423 [LAC 33:111.5609.A) 424 (LAC 33:111.5611.A) 425 [LAC 33:1115611.B) 426 [LAC 33:111.5901.A] 427 (LAC 33:111.5907]

428 [LAC 33:111.5911.A) 429 [LAC 33:111.5911.C] 430 [LAC 33:111.919]

431 (LAC 33:111.927] ·- -· 

### -------·- ---------- 

### SPECIFIC REQUIREMENTSAIID: 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120002 Permit Number: 3080.00010-VS Air- Title V Regular Permit Minor Mod

Suhmit supplementary facts or corrected information: Due promptlyupon becoming aware off3ilurc to submit or incorrect submittal regarding permit applications. In add1tion, provide information as necessary to address any requirements that become applicable to the source after the 

### date oftiling a complete application but prior to release ofa proposed permit Submit applications for perrrUts in accordance with forms and guidance provided

### by the DEQ. At a mmimum, each permit application submitted under LAC 33:iii.Chaplcr

### 5 shall contain lhe mformalion spccJficd in LAC 33:111.517.D, subparagraphs 1-18. In addition to those elements listed under LAC 33:1Il.S17.D, include in each application pertaining to a Pan 70 source the information specified 

### in LAC 33:111.517 E. Subparagraphs I-8. Submit change ofovroership notification in accordance with LAC 33:l.Chaptcr 19. Complywith the Part 70 General Conditions as set forth in LAC 33:111.535 and the Louisiana General Conditions as set forth in LAC 33:111.537 [LAC 33 iii535. LAC 33 iii537] Activate the preplanned abatement strategy listed in LAC 33:111.5611.Table 

### 5 when the administrative authority declares**a~** Air Pollution Alert. Activate the preplanncd strategy listed in LAC 33:111.5611 Table 6 when the administrative authority declares an Air Pollution Warning Activate the preplanned abatement strategy listed in LAC 33:111.5611 .Table 7 when the administrative authoritydeclares an Air Pollution Emergency. Prepare standby plans fOr the reduction ofemissions during periods ofAir Pollution Alert, Air Pollution Warning and Air Pollution Emergency Design standby plans to reduce or eliminate emissions in accordance with the objectives as set forth m LAC 33:111.56JI.Tables 5, 6, and 7.

. Submit standby plan for the reduction orelimination ofemissions during an Air Pollution Alert. Air Pollution Warning, or Air Pollution

Emergency: Due within 30 days after requested by the administrative authority. During an Air Pollution Alert, Air Pollution Warningor Air Pollution Emergency, make the standby plan available on the premises to any person authorized bythe department to enforce these regulations. Complywith the provisions m 40 CFR 68, except as specified in LAC 33:111.5901. Identify hv.ards !hal may result from accidental releases ofthe substances listed in 40 CFR 68.I30, Table 59.0 ofLAC 33:iii.5907, or Table. 59.IofLAC 33:111.59I3 using appropriate hazard assessment techniques, design and maintain a safe facility, and minimize the ofT-site consequences ofacctdental releases ofsuch substances that do occur. Submit regtstration: Due January 31, 1998, or within 60 days after the source becomes subject to LAC 33:111.Chaptc:r 59, whichever is later. Include the informallon listed in LAC 33:111.59JI.B, and submit to the Department ofEnvironmental Compliance Submit amended registration: Due to the Office ofEnvironmental Compliance within 60 days after the information in the submined registration is no longer accurate. Submit Emission Inventory (El)/Annual Emissions Statement: Due annually, by the 30th ofApril to the Office ofEnvironmental Services, for the reponing period ofthe previous calendar year that coincides with 

### period ofownership or operatorship, unless otherwise: directed by DEQ. Submit**bo~** an emissions inventoryand the certification statement required by LAC 33:111.919.F.I.c, separately for each AI, in a format specified by DEQ. include the information specified in LAC 33:111.919.F.1.a through F. I.d. Report the unauthorized discharge ofany air pollutant into the atmosphere in accordance with LAC 33:1.Chapter 39, Notification Regulations and Procedures for Unauthorized Discharges. Submit written reports to the department pursuant to LAC 33:1.3925 Submit timely and appropriate follow-up reports detailing methods and procedures to be used to prevent similar atmospheric releases. Page :48 ol49 TPOA01•7

### SPECIFIC REQUIREMENTS AI 10: 

### 312- Calumet Lubricants Co- Cotton Valley Refinery Activity Number: PER20120.002· Permit Number: 3080-0001O-V6 Air- Title V Regular Permit Minor Mdd 

## :.

iii

t '•**~ Pag~e**  49 of.49
,'I**~,** TPOR0147