UNITED STATES ENVIRONMENTAL PROTECTION AGENCY QUICKLOOK CRITERIA PARAMETERS Nov. 25, 2014 Report Request ID: 1272090 Report Code: AMP450

Selection Criteria Page 1 User ID:AEH
State County City Site Parameter POC AQCR UAR CBSA CSA EPA Region 46 88101 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration QUICK LOOK SELECTED OPTIONS WORKFILE DELIMITER MERGE PDF FILES EVENTS PROCESSING AGENCY ROLE Option Type Option Value , YES EXCLUDE REGIONALLY CONCURRED EVENTS

PQAO SORT ORDER 1 2 3 4 5 6 7 Order Column

PARAMETER_CODE STATE_CODE COUNTY_CODE SITE_ID POC DATES EDT_ID DATE CRITERIA 2009 Start Date End Date 2013 Tribal Code

APPLICABLE STANDARDS Standard Description CO 1-hour 1971 CO 8-hour 1971 Lead 3-Month 2009 Lead 3-Month PM10 Surrogate 2009

NO2 1-hour NO2 Annual 1971 Ozone 1-hour Daily 2005 Ozone 8-Hour 2008 PM10 24-hour 2006 PM25 24-hour 2013 PM25 Annual 2013 SO2 1-hour 2010 SO2 24-hour 1971 SO2 3-hour 1971 SO2 Annual 1971Nov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 1 of 7 EXCEPTIONAL DATA TYPES EDT DESCRIPTION 0 1 2 5 NO EVENTS EVENTS EXCLUDED EVENTS INCLUDED EVENTS WITH CONCURRENCE EXCLUDEDNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 2 of 7 PM2.5 - Local Conditions (88101) South Dakota Micrograms/cubic meter (LC) (105)
SITE ID P

O C PQAOCITY COUNTY ADDRESS YEAR METHNUM CRED DAYS 4TH MAX CERT and EVAL EDT 46-011-0002 46-011-0002 46-011-0002 46-011-0002 46-011-0002 46-013-0003 46-013-0003 46-013-0003 46-013-0003 46-013-0003 1

1 1 1 1 1 1 1 1 10973 0973 0973 0973 0973 0973 0973 0973 0973 0973 Brookings Brookings Brookings Brookings Brookings Aberdeen Aberdeen Aberdeen Aberdeen Aberdeen Brookings

Brookings Brookings Brookings Brookings Brown
Brown
Brown
Brown
Brown BROOKINGS CITY HALL BUILDING BROOKINGS CITY HALL BUILDING BROOKINGS CITY HALL BUILDING BROOKINGS CITY HALL BUILDING BROOKINGS CITY HALL BUILDING 111 2ND AVE SE FIRE STATION #1 ABERDEEN 111 2ND AVE SE FIRE STATION #1 ABERDEEN 111 2ND AVE SE FIRE STATION #1 ABERDEEN 111 2ND AVE SE FIRE STATION #1 ABERDEEN 111 2ND AVE SE FIRE 2009

2010 2011 2012 2013 2009 2010 2011 2012 2013 000 153 000 143 143 000 153 000 143 143 39.0

26.3 20.0 28.3 26.5 30.2 30.9 18.2 24.5 23.3 Y Y

Y
Y 0 0 0 0 0 0 0 0 0 0 24-HOUR 98TH PERCENTILE VALUE 25.7 25.7 18.4 20.6 22.9 23.0 26.2 15.6 22.6 21.1 120 118 120 121 121 120 116 120 109 120 1ST

MAX 2ND

MAX 3RD

MAX 31.2 26.2 19.6 24.4 24.3 23.4 27.2 17.7 23.3 22.0 25.7

25.7 18.4 20.6 22.9 23.0 26.2 15.6 22.6 21.1 25.1

23.0 18.1 19.2 21.8 20.7 21.1 15.4 17.9 20.3 8.58 8.64 7.91 8.63 8.23 8.11 8.69 7.07 7.52* 7.33 WTD ARITH MEANNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 3 of 7 PM2.5 - Local Conditions (88101) South Dakota Micrograms/cubic meter (LC) (105)
SITE ID P

O C PQAOCITY COUNTY ADDRESS YEAR METHNUM CRED DAYS 4TH MAX CERT and EVAL EDT 46-029-0002 46-029-0002 46-029-0002 46-029-0002 46-029-0002 46-033-0132 46-033-0132 46-033-0132 46-033-0132 1

1 1 3 3 1 1 3 30973 0973 0973 0973 0973 0973 0973 0973 0973 Watertown Watertown Watertown Watertown Watertown Not in a city Not in a city Not in a city Not in a cityCodington

Codington Codington Codington Codington Custer Custer Custer Custer STATION #1 ABERDEEN 801 4TH AVE SW - WATERTOWN 801 4TH AVE SW - WATERTOWN 801 4TH AVE SW - WATERTOWN 801 4TH AVE SW - WATERTOWN 801 4TH AVE SW - WATERTOWN WIND CAVE NATIONAL PARK, SOUTH DAKOTA WIND CAVE NATIONAL PARK, SOUTH DAKOTA WIND CAVE NATIONAL PARK, SOUTH DAKOTA WIND CAVE NATIONAL PARK, SOUTH DAKOTA 2009

2010 2011 2012 2013 2009 2010 2009 2010 153 153 153 170 170 119 119 170 170 37.8

28.5 19.6 31.2 26.8 120.5 111.8 303.6 115.0 Y Y 0 0 0 0 0 5 0 5 0 24-HOUR 98TH PERCENTILE VALUE 23.1 23.9 18.4 21.5 21.0 9.6 12.4 15.2 11.5 118 116 118 336 340 107 113 339 346 1ST

MAX 2ND

MAX 3RD

MAX 32.4 27.4 18.5 26.8 26.4 17.4 17.8 121.8 54.5 23.1

23.9 18.4 26.3 24.3 9.6 12.4 112.6 27.4 18.8

22.8 17.8 25.9 23.4 8.3 10.4 37.8 19.9 8.49 8.91 8.06 10.96 9.67 4.69* 4.65 6.46 4.24 WTD ARITH MEANNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 4 of 7 PM2.5 - Local Conditions (88101) South Dakota Micrograms/cubic meter (LC) (105)
SITE ID P

O C PQAOCITY COUNTY ADDRESS YEAR METHNUM CRED DAYS 4TH MAX CERT and EVAL EDT 46-033-0132 46-033-0132 46-033-0132 46-071-0001 46-071-0001 46-071-0001 46-071-0001 46-071-0001 46-099-0006 46-099-0006 3

3 3 3 3 3 3 3 1 10973 0973 0973 0973 0973 0973 0973 0973 0973 0973 Not in a city Not in a city Not in a city Not in a city Not in a city Not in a city Not in a city Not in a city Sioux Falls Sioux Falls Custer

Custer Custer Jackson Jackson Jackson Jackson Jackson Minnehaha Minnehaha WIND CAVE NATIONAL PARK, SOUTH DAKOTA WIND CAVE NATIONAL PARK, SOUTH DAKOTA WIND CAVE NATIONAL PARK, SOUTH DAKOTA BADLANDS PO BOX 6 HEADQUARTERS BADLANDS PO BOX 6 HEADQUARTERS BADLANDS PO BOX 6 HEADQUARTERS BADLANDS PO BOX 6 HEADQUARTERS BADLANDS PO BOX 6 HEADQUARTERS 500 S. PHILLIPS KELO SITE 500 S. PHILLIPS KELO SITE 2011

2012 2013 2009 2010 2011 2012 2013 2009 2010 170 170 170 170 170 170 170 170 000 153 12.9

22.3 14.7 17.0 21.6 18.8 16.7 17.0 42.7 33.1 Y
Y

Y Y 0 0 0 0 0 0 0 0 0 0 24-HOUR 98TH PERCENTILE VALUE 11.5 14.9 9.4 10.4 13.6 10.0 12.9 13.9 22.2 27.8 350 352 359 343 358 337 363 345 121 121 1ST

MAX 2ND

MAX 3RD

MAX 12.4 20.4 11.2 16.4 20.1 12.4 15.2 17.0 30.2 30.2 12.4

18.5 11.0 15.9 18.0 11.5 13.3 15.7 22.2 27.8 12.0

16.2 10.8 14.0 14.8 11.0 13.2 15.3 21.1 27.0 3.69 4.91 3.05 3.97 3.87 3.45 4.14 5.31 9.12 9.16 WTD ARITH MEANNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 5 of 7 PM2.5 - Local Conditions (88101) South Dakota Micrograms/cubic meter (LC) (105)
SITE ID P

O C PQAOCITY COUNTY ADDRESS YEAR METHNUM CRED DAYS 4TH MAX CERT and EVAL EDT 46-099-0006 46-099-0006 46-099-0006 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-099-0008 46-103-0020 46-103-0020 46-103-0020 46-103-0020 1

1 1 1 1 1 1 1 3 3 3 3 3 1 1 3 30973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Sioux Falls Rapid City Rapid City Rapid City Rapid City Minnehaha

Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Minnehaha Pennington Pennington Pennington Pennington 500 S. PHILLIPS KELO SITE 500 S. PHILLIPS KELO SITE 500 S. PHILLIPS KELO SITE 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St 2001 E 8th St CREDIT UNION SITE, 106 KINNEY AVE. CREDIT UNION SITE, 106 KINNEY AVE. CREDIT UNION SITE, 106 KINNEY AVE. CREDIT UNION SITE, 106 2011

2012 2013 2009 2010 2011 2012 2013 2009 2010 2011 2012 2013 2009 2010 2009 2010 143 143 143 142 000 143 143 143 170 170 170 170 170 000 153 170 170 25.3

31.6 34.7 42.0 30.3 24.5 19.2 34.4 43.9 44.0 33.9 25.1 33.1 16.1 26.6 22.3 18.9 Y Y

Y Y

Y Y 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 24-HOUR 98TH PERCENTILE VALUE 21.5 20.8 21.8 21.9 27.9 21.6 18.3 22.0 23.3 29.0 19.4 17.3 23.4 14.3 15.6 15.1 14.0 121 122 118 121 122 120 111 117 349 358 352 363 351 122 114 357 327 1ST

MAX 2ND

MAX 3RD

MAX 22.5 22.0 22.8 28.1 30.2 21.8 18.5 25.1 32.6 34.2 25.8 23.0 30.1 15.2 19.3 18.4 16.8 21.5

20.8 21.8 21.9 27.9 21.6 18.3 22.0 27.4 31.8 24.4 22.3 26.6 14.3 15.6 17.5 16.0 21.3

18.9 21.8 21.5 27.8 21.1 17.0 21.9 25.8 31.1 24.1 21.4 25.3 14.0 15.2 16.8 15.0 8.67 8.74 8.58 9.04 9.66 8.88 7.93 8.64 8.98 10.29 8.02 6.01 8.89 6.65 7.47 6.10 5.18 WTD ARITH MEANNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 6 of 7 PM2.5 - Local Conditions (88101) South Dakota Micrograms/cubic meter (LC) (105)
SITE ID P

O C PQAOCITY COUNTY ADDRESS YEAR METHNUM CRED DAYS 4TH MAX CERT and EVAL EDT 46-103-0020 46-103-0020 46-103-0020 46-103-1001 46-103-1001 46-103-1001 46-103-1001 46-103-1001 46-127-0001 46-127-0001 46-127-0001 46-127-0001 3

3 3 1 1 1 1 1 3 3 3 30973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 0973 Rapid City Rapid City Rapid City Rapid City Rapid City Rapid City Rapid City Rapid City Not in a city Not in a city Not in a city Not in a cityPennington

Pennington Pennington Pennington Pennington Pennington Pennington Pennington Union Union Union Union KINNEY AVE. CREDIT UNION SITE, 106 KINNEY AVE. CREDIT UNION SITE, 106 KINNEY AVE. CREDIT UNION SITE, 106 KINNEY AVE. CITY LIBRARY 6TH AND QUINCY CITY LIBRARY 6TH AND QUINCY CITY LIBRARY 6TH AND QUINCY CITY LIBRARY 6TH AND QUINCY CITY LIBRARY 6TH AND QUINCY 31986 475th Ave 31986 475th Ave 31986 475th Ave 31986 475th 2011

2012 2013 2009 2010 2011 2012 2013 2009 2010 2011 2012 170 170 170 000 153 153 000 143 170 170 170 170 19.1

23.6 17.4 19.8 31.4 14.8 19.8 18.1 39.3 46.0 32.4 31.7 Y Y

Y Y

Y 0 0 0 0 0 0 0 0 0 0 0 0 24-HOUR 98TH PERCENTILE VALUE 13.1 17.1 15.3 13.1 20.7 12.3 14.5 14.2 21.3 27.8 23.1 19.7 348 353 352 121 120 116 113 118 353 354 361 359 1ST

MAX 2ND

MAX 3RD

MAX 18.6 22.3 17.4 14.0 26.6 13.2 18.5 16.8 30.6 36.4 25.4 27.6 14.5

20.8 16.6 13.1 20.7 12.3 14.5 14.2 28.5 34.9 25.4 27.2 14.1

20.7 16.5 11.7 19.0 11.4 14.2 14.2 24.7 31.1 24.1 25.3 4.49 6.26 7.87 5.86 6.57 5.42 5.84 6.12 7.42 9.56 9.29 9.88 WTD ARITH MEANNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450)



### Page 7 of 7 PM2.5 - Local Conditions (88101) South Dakota Micrograms/cubic meter (LC) (105)
SITE ID P

O C PQAOCITY COUNTY ADDRESS YEAR METHNUM CRED DAYS 4TH MAX CERT and EVAL EDT 46-127-0001 46-127-0002 46-127-0002 46-127-0002 46-127-0002 46-127-0002 46-127-0002 46-127-0002 46-127-0002 3

1 1 1 3 3 3 3 30973 0973 0973 0973 0973 0973 0973 0973 0973 Not in a city Not in a city Not in a city Not in a city Not in a city Not in a city Not in a city Not in a city Not in a cityUnion

Union Union Union Union Union Union Union Union Ave 31986 475th Ave 31307 473rd Ave 31307 473rd Ave 31307 473rd Ave 31307 473rd Ave 31307 473rd Ave 31307 473rd Ave 31307 473rd Ave 31307 473rd Ave 2013

2009 2010 2011 2009 2010 2011 2012 2013 170 000 153 153 170 170 170 170 170 40.6

42.1 34.8 26.4 35.9 41.7 31.3 28.9 39.7 Y

Y Y 0 0 0 0 0 0 0 0 0 24-HOUR 98TH PERCENTILE VALUE 22.8 23.3 29.7 22.1 21.0 29.2 21.0 20.8 23.5 360 120 115 120 356 341 364 350 364 1ST

MAX 2ND

MAX 3RD

MAX 34.8 24.2 32.5 22.3 28.8 34.8 27.1 27.8 32.3 28.8

23.3 29.7 22.1 28.7 33.6 26.4 27.5 27.3 24.0

21.6 27.8 19.7 24.3 33.1 21.9 27.0 24.5 8.89 8.68 9.73 8.21 8.42 9.59 8.06 7.50 10.46 WTD ARITH MEANNov. 25, 2014

Note: These reported values do not reflect the combination of 14129 and 85129 and validation substitution tests utilized for Design Value Calculations UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450) Lead (TSP) LCNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450 END)

88101 88101 88101 88101 88101 88101 000

119 142 143 153 170 MULTIPLE METHODS

Andersen RAAS2.5-100 PM2.5 SAM w/WINS BGI Models PQ200-VSCC or PQ200A-VSCC R & P Model 2000 PM-2.5 Air Sampler w/VSCC Thermo Electron Model RAAS2.5-100 w/VSCC Met One BAM-1020 Mass Monitor w/VSCC MULTIPLE METHODS GRAVIMETRIC Gravimetric Gravimetric Gravimetric Beta Attenuation PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORTNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450 END) PQAOS USED IN THIS REPORT PQAO AGENCY DESCRIPTION 0973 South Dakota Dept Environmental Protection Air Quality ProgNov. 25, 2014

Note: The * indicates that the mean does not satisfy summary criteria. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM QUICK LOOK REPORT (AMP450 END)

M N

S
U
X Y The monitoring organization has revised data from this monitor since the

most recent certification letter received from the state. The certifying agency has submitted the certification letter and required summary reports, but the certifying agency and/or EPA has determined that issues regarding the quality of the ambient concentration data cannot be resolved due to data completeness, the lack of performed quality assurance checks or the results of uncertainty statistics shown in the AMP255 report or the certification and quality assurance report. The certifying agency has submitted the certification letter and required summary reports. A value of "S" conveys no Regional assessment regarding data quality per se. This flag will remain until the Region provides an "N" or "Y" concurrence flag. Uncertified. The certifying agency did not submit a required certification letter and summary reports for this monitor even though the due date has passed, or the state's certification letter specifically did not apply the certification to this monitor. Certification is not required by 40 CFR 58.15 and no conditions apply to be the basis for assigning another flag value The certifying agency has submitted a certification letter, and EPA has no unresolved reservations about data quality (after reviewing the letter, the attached summary reports, the amount of quality assurance data submitted to AQS, the quality statistics, and the highest reported concentrations). MEANING CERTIFICATION EVALUATION AND CONCURRENCE FLAG MEANINGS FLAG