## Support Documents for Significant New Use Rule (SNUR) on
Premanufacture Notice (PMN)

P-11-33

EPA Docket EPA-HQ-OPPT-2011-0942

## Index A-001 Structure Activity Team (SAT) Report for PMN P-11-33 A-002 Initial Review Engineering Report for PMN P-11-33 A-003 Initial Review Exposure Report for PMN P-11-33

## A-001 Structure Activity Team (SAT) Report

for PMN P-11-33

### SAT Report PMN Number: P-11-0033 SAT Date: 10/29/2010 Print Date: 8/31/2011

Related cases : Health related cases: Ecotox related cases :

Concern levels : Type of Concern: Health Eco Comments Level of Concern: 2 2

Persistence Bioaccum Toxicity Comments 3 11

Exposure Based Review : Health: Ecotox: N o
Routes of exposure : Health: Dermal Inhalation Ecotox: All releases to water Fate: ;
Keywords : Keywords: IRR/CORR-E,S,MM,L; SENS-S; AQUATOX
Summary of Assessment :

Fate : Fate Summary: P-11-0033 FATE: Estimations for low weight with one equivalent of each monomer MW 291 C17H29 N 3O Liquid with MP < 25 C (E) log Kow = 2.04 (E) S > 10 g/L at 25 C (E) VP < 1.0E-6 torr at 25 C (E) BP > 400 C (E) H < 1.00E-8 (E) log Koc = 4.21 (E) log Fish BCF = 1.01 (E) log Fish BAF = 0.86 (E)POTW removal (%) = 90 via sorption Time for complete ultimate aerobic biodeg > mo Sorption to soils/sediments = v.strong PBT Potential: P3B1 *CEB FATE: Migration to ground water = negl

Health : Health Summary: N ot absorbed from the skin, p oor absorption from the GI tract and good absorption from the lung ( p che m ). Concern for irritation and possible corrosion to all tissues and dermal sensitization.

Ecotox :

Test Organism Test Type Test End Point Predicted Measured Comments

fish 96-h LC50 5.8 p henol-amine SAR daphnid 48-h LC50 1.2 p henol-amine SAR green algal 96-h EC50 1.2 aliphatic amine SAR fish

_ chronic value 0.19 p henol-amine SAR daphnid

_ chronic value 0.17 p henol-amine SAR algal

_ chronic value 0.41 aliphatic amine SAR Sewage Sludge 3-h EC50

_ Sewage Sludge

_ Chronic Value

_ Ecotox Values Comments: Predictions are based on SARs for aliphatic amines and p henol-amines; SAR chemical class = aliphatic amine, p henol-amine; MW 209 with 100% < 500; log Kow = 2.55 (EPI, representative structure); liquid (M); S = 122 g/L (P); p H7; effective concentrations based on 100% active ingredients and mean measured concentrations; hardness <150.0 mg/L as CaCO3; and TOC <2.0 mg/L;

Factors Values Comments Assessment Factor 10 Concentration of Concern ( p pb) 17 p henol-amine SAR

SARs aliphatic amines and p henol-amines SAR Class aliphatic amine, p henol-amine

Ecotox Factors Comments:

SAT Chair: L Keifer 564-8916

## A-002 Initial Review Engineering Report

for PMN P-11-33file:///J|/SNURS/SNUR%20SANITIZATION/AUG%202011/P-11-0033/p110033en1.txt[9/12/2011 9:53:07 AM] INITIAL REVIEW ENGINEERING REPORT PMN: 11-0033 Post-Focus Draft Revision 1 7/27/2011

ENGINEER: Prothero \ JAS PV (kg/yr): 9,860 Import Only

SUBMITTER:

USE:

OTHER USES:

MSDS: Label:

TLV/PEL: none established.

CRSS : Chemical Name: Formaldehyde, polymer with 4-(1, 1-dimethylethyl)phenol, reaction products with 1-piperazineethanamine (TMR) S-H20: 122 g/L @ VP: 1.0E-6 torr @ MW: 209.00 100.00%<500 100.00%<1000 Physical State and Misc CRSS Info: Neat: Liquid Mfg: NK: Import Proc/Form: Solution: 50-55% PMN material, then Solution: 13.6% PMN material End Use: Destroyed. NAVG = 209 with 100% < 500 and 100% < 1000 by GPC. Submitted Data: Viscosity = 400 Ps; Relative Density = 1.0. Estimated Data: BP = 411 °C (EPI); VP = 8. 7E-7 torr (EPI); WS = 122 g/L (EPI); logP = 2.04 (EPI).The EPI estimations were performed on the component consisting of one equivalent of each feedstock, having a molecular weight of 291 g/mole and a molecular formula of C17 H29 O. Amine FGEW = [(129.21)(100)]/[(51)(3)] = 84.

Consumer Use: No

SAT (concerns) (10/29/2010): Related Cases and Related Cases and Misc SAT Info: Analogs: Migration to groundwater: Negligible PBT rating: P3B1T1 ' Health: 2 Dermal, Inhalation Eco: 2 Water (All releases to water with a CC = 17 ppb.)

OCCUPATIONAL EXPOSURE RATING: 1C

NOTES & KEY ASSUMPTIONS: Generated by the 06/07/2005 version of ChemSTEER.

POLLUTION PREVENTION CONSIDERATIONS: None.

EXPOSURE-BASED REVIEW: No

INITIAL REVIEW ENGINEERING REPORT PMN: 11-0033

Use:

Number of Sites/ Location:

Days/yr: Basis:Process Description:

ENVIRONMENTAL RELEASES ESTIMATE SUMMARY Air: not expected (low VP); IRER Note: The submission estimates that there will be releases from cleaning brushes or rollers, mixing blades or mixing pails (0.03 kg/batch). In the case of helical paint mixers, a small amount of solvent is used to wipe on the cloth. The submission indicates that the resin is allowed to cure in the air over several days so that the PMN no longer exists at the time it is sent off for waste. These releases, which are far below assessment thresholds for incineration and land, are not assessed below (consistent with same-submitter past case P10-0566).

Incineration or Landfill High End: 3.4E+0 kg/site-day over 9 days/yr from 10 sites or 3.1E+2 kg/yr to: incineration or landfill (July 2011 amend - LM Windpower disposes via hazardous waste handler and Vestas Blade via land or incineration - and future SNUR) from: Cleaning Liquid Residuals from Drums Used to Transport the Raw Material basis: EPA/OPPT Drum Residual Model, CEB standard 3% residual. The submission indicated that the residue in the shipping container is less than 1.6%. The submission estimatesd 3.19 kg/day total from all sites (media of release not indicated). CEB std model assessed as conservative.

RELEASE TOTAL 3.1E+2 kg/yr - all sites

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY Tot. # of workers exposed via assessed routes: Basis:

Inhalation:

Dermal:

## A-003 Initial Review Exposure Report

for PMN P-11-337/27/2011 Page of POSTFOCUS EXPOSURE REPORT

Case Number: P110033 Assessor: Delpire

ENVIRONMENTAL RELEASES

Scenario#: Number of Release Sites:
Release Activity:

Release Description: WATER LANDFILL INCINER LAND/INCIN FUGITIVE

Total Releases:
(kg/yr) (kg/yr) (kg/yr) (kg/yr) (kg/yr)
Release Days/yr:

Per Site Release:
(kg/day) (kg/yr) (kg/yr) (kg/yr) (kg/day)

Remarks: EAB DROP: Release information for this compound does not meet criteria for preparation of an exposure assessment in the Exposure Assessment Branch’s (EAB) Initial Review Exposure Report (this report).