P2695 - TEQ

Project ID: P-10124 

Sample Summary

Part 1 Method 23

Analyte 0_8210_

MB001

Plant 5 

Inlet-R1

Plant 5 

Inlet-R2

Plant 5 

Inlet-R3

Plant 5 

OutletR1

Plant 5 

OutletR2

Plant 5 

OutletR3

Plant 5 

Oven-R1

Plant 5 

Oven-R2

Plant 5 

Oven-R3

pg pg pg pg pg pg pg pg pg pg

2,3,7,8-TCDD (1.79) 50.1 45.2 34.3 60.2 29.4 [33.8] (1.77) (2.7) (2.03)

1,2,3,7,8-PeCDD (2.12) 75.2 63.9 66.4 92.3 42.6 61.7 (1.76) (2.75) (2.31)

1,2,3,4,7,8-HxCDD (2.09) 32 21.6 23.4 28 16.8 20.6 (1.77) (3.16) (1.87)

1,2,3,6,7,8-HxCDD (2.06) 49.2 32.1 31.3 [36.6] 20.4 29.4 (1.68) (3.25) (1.81)

1,2,3,7,8,9-HxCDD (2.14) 60.6 44.3 38 49.5 29.2 41.3 (1.88) (3.09) (1.99)

1,2,3,4,6,7,8-HpCDD (2.48) 247 162 139 135 91 108 13.4 [8.43] 9.41

OCDD (4.95) 1500 1030 809 563 421 549 37.8 [27.5] [26.2]

2,3,7,8-TCDF (1.3) 14.4 10.7 [5.02] 4.29 5.58 [3.02] [3] [3.49] (2.26)

1,2,3,7,8-PeCDF (1.43) 15.1 17.7 7.81 [2.36] [3.4] [2.68] 3.72 (3.61) (2.46)

2,3,4,7,8-PeCDF (1.32) 9.13 [8.37] 6 5.98 6.89 5.68 5.89 (3.61) (2.08)

1,2,3,4,7,8-HxCDF (1.38) 11.5 12.7 8.14 4.19 [3.98] 3.74 6.01 (2.02) 3.86

1,2,3,6,7,8-HxCDF (1.27) 11.6 14.5 [6.55] 4.37 [5] [2.63] 5.4 (2.06) 3.2

2,3,4,6,7,8-HxCDF (1.26) 9.5 9.99 [4.9] 4.85 5.76 [4.22] [5.4] (2.05) 5.01

1,2,3,7,8,9-HxCDF (1.66) (2.18) (1.85) (1.66) (1.48) (1.82) (2.73) (1.86) (2.63) (2.77)

1,2,3,4,6,7,8-HpCDF (1.5) 27.4 32.8 19.2 11.6 12.2 12 11.4 (2.31) 8.79

1,2,3,4,7,8,9-HpCDF (2.08) 4.56 4.2 (1.99) (1.76) (2.27) (3.31) (2.63) (3.29) (1.9)

OCDF (3.57) [10.3] 14.8 (3.07) [6.56] 6.95 [6.83] [3.15] (2.96) [4.26]

ITEF TEQ (ND=0; EMPC=0) 0.00 116 95.6 83.4 121 63.4 45.0 4.56 0.00 1.39

ITEF TEQ (ND=0; EMPC=EMPC) 0.00 116 99.8 85.0 125 64.5 79.9 5.40 0.461 1.42

ITEF TEQ (ND=DL/2; EMPC=0) 2.48 116 96.1 83.7 121 63.7 47.2 6.42 4.16 4.11

ITEF TEQ (ND=DL/2; EMPC=EMPC) 2.48 116 99.9 85.1 125 64.6 80 7.10 4.43 4.14

ITEF TEQ (ND=DL; EMPC=EMPC) 4.96 116 100 85.2 125 64.7 80.2 8.79 8.41 6.85

Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-960 876-500 591-982

Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_8210_007 P2695_8210_008 P2695_8210_009

( ) = DL

[ ] = EMPC
0

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pg

WHO-2005-TEQ

Project ID: P-10124

P2695

ND=0; EMPC=0

ND=0; EMPC=EMPC

ND=DL/2; EMPC=0

ND=DL/2; EMPC=EMPC

ND=DL; EMPC=EMPC
 P2695 - WHO-2005-TEQ

Project ID: P-10124 

Sample Summary

Part 1 Method 23

Analyte 0_8210_

MB001

Plant 5 

Inlet-R1

Plant 5 

Inlet-R2

Plant 5 

Inlet-R3

Plant 5 

OutletR1

Plant 5 

OutletR2

Plant 5 

OutletR3

Plant 5 

Oven-R1

Plant 5 

Oven-R2

Plant 5 

Oven-R3

pg pg pg pg pg pg pg pg pg pg

2,3,7,8-TCDD (1.79) 50.1 45.2 34.3 60.2 29.4 [33.8] (1.77) (2.7) (2.03)

1,2,3,7,8-PeCDD (2.12) 75.2 63.9 66.4 92.3 42.6 61.7 (1.76) (2.75) (2.31)

1,2,3,4,7,8-HxCDD (2.09) 32 21.6 23.4 28 16.8 20.6 (1.77) (3.16) (1.87)

1,2,3,6,7,8-HxCDD (2.06) 49.2 32.1 31.3 [36.6] 20.4 29.4 (1.68) (3.25) (1.81)

1,2,3,7,8,9-HxCDD (2.14) 60.6 44.3 38 49.5 29.2 41.3 (1.88) (3.09) (1.99)

1,2,3,4,6,7,8-HpCDD (2.48) 247 162 139 135 91 108 13.4 [8.43] 9.41

OCDD (4.95) 1500 1030 809 563 421 549 37.8 [27.5] [26.2]

2,3,7,8-TCDF (1.3) 14.4 10.7 [5.02] 4.29 5.58 [3.02] [3] [3.49] (2.26)

1,2,3,7,8-PeCDF (1.43) 15.1 17.7 7.81 [2.36] [3.4] [2.68] 3.72 (3.61) (2.46)

2,3,4,7,8-PeCDF (1.32) 9.13 [8.37] 6 5.98 6.89 5.68 5.89 (3.61) (2.08)

1,2,3,4,7,8-HxCDF (1.38) 11.5 12.7 8.14 4.19 [3.98] 3.74 6.01 (2.02) 3.86

1,2,3,6,7,8-HxCDF (1.27) 11.6 14.5 [6.55] 4.37 [5] [2.63] 5.4 (2.06) 3.2

2,3,4,6,7,8-HxCDF (1.26) 9.5 9.99 [4.9] 4.85 5.76 [4.22] [5.4] (2.05) 5.01

1,2,3,7,8,9-HxCDF (1.66) (2.18) (1.85) (1.66) (1.48) (1.82) (2.73) (1.86) (2.63) (2.77)

1,2,3,4,6,7,8-HpCDF (1.5) 27.4 32.8 19.2 11.6 12.2 12 11.4 (2.31) 8.79

1,2,3,4,7,8,9-HpCDF (2.08) 4.56 4.2 (1.99) (1.76) (2.27) (3.31) (2.63) (3.29) (1.9)

OCDF (3.57) [10.3] 14.8 (3.07) [6.56] 6.95 [6.83] [3.15] (2.96) [4.26]

WHO-2005 TEQ (ND=0; EMPC=0) 0.00 151 126 115 165 83.0 74.3 3.28 0.00 1.39

WHO-2005 TEQ (ND=0; EMPC=EMPC) 0.00 151 129 116 169 84.0 109 4.12 0.442 1.40

WHO-2005 TEQ (ND=DL/2; EMPC=0) 2.86 151 127 115 166 83.3 76.5 5.58 4.45 4.45

WHO-2005 TEQ (ND=DL/2; EMPC=EMPC) 2.86 151 129 116 169 84.1 109 6.26 4.70 4.46

WHO-2005 TEQ (ND=DL; EMPC=EMPC) 5.73 151 129 117 169 84.2 109 8.39 8.97 7.52

Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-960 876-500 591-982

Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_8210_007 P2695_8210_008 P2695_8210_009

( ) = DL

[ ] = EMPC
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Totals

Project ID: P-10124

P2695

Total PCDD/Fs (ND=0; EMPC=0)

Total PCDD/Fs (ND=0; EMPC=EMPC)

Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC)
 P2695 - Totals

Project ID: P-10124 

Sample Summary

Part 2 Method 23

Analyte 0_8210_

MB001

Plant 5 

Inlet-R1

Plant 5 

Inlet-R2

Plant 5 

Inlet-R3

Plant 5 

OutletR1

Plant 5 

OutletR2

Plant 5 

OutletR3

Plant 5 

Oven-R1

Plant 5 

Oven-R2

Plant 5 

Oven-R3

pg pg pg pg pg pg pg pg pg pg

Totals

TCDDs 0 2070 2290 1670 2310 1170 1430 28 59 0

PeCDDs 0 1300 1260 1180 1600 820 1040 56.7 62.6 17.2

HxCDDs 0 910 642 664 782 439 545 63 90.3 20.7

HpCDDs 0 578 385 334 336 221 268 40.8 27.8 9.41

OCDD 0 1500 1030 809 563 421 549 37.8 27.5 26.2

TCDFs 0 247 337 158 208 207 94 82.7 36 21.5

PeCDFs 0 90.6 111 50.7 60.5 53.7 42.1 44.7 0 5.73

HxCDFs 0 78.1 88 36.9 31.4 12.8 3.74 26.4 4.43 14.8

HpCDFs 0 38.6 43.3 27.8 14.3 15.7 12 11.4 0 8.79

OCDF 0 10.3 14.8 0 6.56 6.95 6.83 3.15 0 4.26

Total PCDD/Fs (ND=0; EMPC=0) 0.00 6,810 6,200 4,930 5,900 3,370 3,990 391 280 98.1

Total PCDD/Fs (ND=0; EMPC=EMPC) 0.00 6,910 6,240 5,040 6,000 3,480 4,160 465 383 187

Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC) 34.4 6,910 6,240 5,050 6,010 3,490 4,170 479 423 209

Total 2378s (ND=0; EMPC=0) 0.00 2,120 1,520 1,180 963 688 831 83.6 0.00 30.3

Total 2378s (ND=0.5; EMPC=0) 17.2 2,120 1,520 1,190 968 693 843 92.9 25.4 43.4

Total 2378s (ND=1; EMPC=0) 34.4 2,120 1,520 1,190 972 697 854 102 50.9 56.6

Total 2378s (ND=0; EMPC=1) 0.00 2,130 1,530 1,200 1,010 700 885 95.1 39.4 60.7

Total 2378s (ND=0.5; EMPC=1) 17.2 2,130 1,530 1,200 1,010 702 888 102 59.1 71.5

Total 2378s (ND=1; EMPC=1) 34.4 2,130 1,530 1,210 1,010 704 891 108 78.9 82.2

Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-960 876-500 591-982

Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_8210_007 P2695_8210_008 P2695_8210_009

( ) = DL

[ ] = EMPC
 P2695 - Others

Project ID: P-10124 

Sample Summary

Part 3 Method 23

Analyte 0_8210_

MB001

Plant 5 

Inlet-R1

Plant 5 

Inlet-R2

Plant 5 

Inlet-R3

Plant 5 

OutletR1

Plant 5 

OutletR2

Plant 5 

OutletR3

Plant 5 

Oven-R1

Plant 5 

Oven-R2

Plant 5 

Oven-R3

pg pg pg pg pg pg pg pg pg pg

Other PCDD/Fs (ND=0, EMPC=0)

Other TCDD 0 2020 2240 1640 2250 1140 1430 28 59 0

Other PeCDD 0 1230 1200 1110 1510 777 983 56.7 62.6 17.2

Other HxCDD 0 768 544 571 705 372 454 63 90.3 20.7

Other HpCDD 0 331 223 195 202 130 161 27.4 27.8 0

Other TCDF 0 232 327 158 204 202 94 82.7 36 21.5

Other PeCDF 0 66.4 93.3 36.9 54.6 46.8 36.4 35.1 0 5.73

Other HxCDF 0 41.6 50.8 26.8 18 7.08 0 15 4.43 2.68

Other HpCDF 0 6.58 6.28 8.61 2.77 3.48 0 0 0 0

Other PCDD/Fs (ND=0, EMPC=EMPC)

Other TCDD 0 2020 2240 1660 2250 1140 1450 40.9 72.4 13.6

Other PeCDD 0 1230 1200 1110 1510 777 983 63.1 81.2 17.2

Other HxCDD 0 768 544 571 705 397 477 63 90.3 31.7

Other HpCDD 0 331 223 195 202 130 161 27.4 27.8 12.7

Other TCDF 0 280 332 198 239 227 154 106 67.6 27.8

Other PeCDF 0 89.6 104 61.8 71.5 78.6 46.6 50.8 0 10.4

Other HxCDF 0 48.2 60.2 29.2 18 24.9 12.7 18.8 4.43 13.1

Other HpCDF 0 11.5 11.4 8.61 5.81 5.38 0 0 0 0

Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-960 876-500 591-982

Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_8210_007 P2695_8210_008 P2695_8210_009

( ) = DL

[ ] = EMPC
 P2695 - TEQ overview

Project ID: P-10124 

TEQ Summary

Part 4

( ) = DL

[ ] = EMPC
Method Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F = fail)

0

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80

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100

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Mean Recoveries of Extraction Standards (N=10)

Project ID: P-10124

P2695 Mean Std. Dev.
Method Specification Limits: Tetra-Octa SS: 70-130% (F = fail)

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Mean Recoveries of Sampling Standards (N=10)

Project ID: P-10124

P2695 Mean Std. Dev.
0_8210_MB001 95.3 95.1 88.6 88 92.5 89.9 83.9 96.3 91.6 92.6 86.1

Plant 5 Inlet-R1 85.1 84.3 84.1 83.5 90.8 83.9 82.3 82.9 81 80 84.1

Plant 5 Inlet-R2 91.5 88.7 86.7 87.5 93.1 94.5 89.6 87.1 84.9 85 91.8

Plant 5 Inlet-R3 76.7 80.9 78.6 77.7 79.5 79.1 72.2 75.8 77.9 76.5 77.6

Plant 5 Outlet-R1 98.1 95.9 96 93.3 97.6 100 94 96.2 94.3 91.7 97.8

Plant 5 Outlet-R2 96.2 95.8 94.2 93.7 96.8 93.5 88 93.7 91.9 91.5 92.4

Plant 5 Outlet-R3 82.3 86.7 88.6 90.3 91.6 91.7 85.9 80.8 82.8 83.5 88.5

Plant 5 Oven-R1 90.1 89.8 86.5 89.2 92.5 91.6 87.3 86.4 85.2 84.1 87.8

Plant 5 Oven-R2 98.8 94.8 89.6 91.1 95.6 93.4 87.5 96.1 92.8 92.7 94.9

Plant 5 Oven-R3 104 102 95 95 101 95.5 94.3 101 96.6 96.8 95.5

Average 92 91 89 89 93 91 87 90 88 87 90

SD 8 6 5 5 6 6 6 8 6 7 6

Min 76.7 80.9 78.6 77.7 79.5 79.1 72.2 75.8 77.9 76.5 77.6

Max 104 102 96 95 101 100 94.3 101 96.6 96.8 97.8

Within M23 QC TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE

13COCDD13CTCDF13CHxCDF13CHxCDD13CHxCDD13CHpCDD

Sample Number 13CTCDD

13CPeCDD13CHxCDD

Extraction Standard Percent Recoveries, %

13CPeCDF13CPeCDF
88.3 88.2 87.4 89.4 84.1 80.8 0_8210_MB001 98.3 97.8 101 99.9 96.9

84.2 81.4 85.5 83.8 82.9 79.2 Plant 5 Inlet-R1 96.1 98.5 97.8 98.8 96.5

90.4 92.2 91.9 90.7 91.3 84.6 Plant 5 Inlet-R2 99.1 98.8 101 102 101

79.1 75.4 77.9 78.6 73.8 71.2 Plant 5 Inlet-R3 98.3 99.5 98.9 101 97.6

97.7 93.2 97 97.7 97.3 92.1 Plant 5 Outlet-R1 96.6 98.9 96.7 99.1 96.6

92.5 92.3 94.7 92.4 90.4 87 Plant 5 Outlet-R2 98 97.8 99.1 101 98.4

86.6 85.2 89.1 89.2 87.7 85.2 Plant 5 Outlet-R3 99.8 98.3 98 102 101

86.5 88.8 88.8 89.4 89.6 84.4 Plant 5 Oven-R1 98.1 101 98.2 103 98.5

92.2 88.6 94.1 94.2 91.2 83.4 Plant 5 Oven-R2 97.1 97.4 99.2 100 98.8

96.1 93.3 96 99.4 97 90.7 Plant 5 Oven-R3 98.7 95.5 102 98.8 97.5

89 88 90 90 89 84 Average 98 98 99 101 98

6 6 6 6 7 6 SD 1 1 2 1 2

79.1 75.4 77.9 78.6 73.8 71.2 Min 96.1 95.5 96.7 98.8 96.5

97.7 93.3 97 99.4 97.3 92.1 Max 99.8 101 102 103 101

TRUE TRUE TRUE TRUE TRUE TRUE Min within M23 QC TRUE TRUE TRUE TRUE TRUE

Sample Number

CS/SS Percent Recoveries, %

37ClTCDD13CPeCDD13CHxCDF13CHpCDF13CPeCDF13CHpCDF13COCDF13CHxCDF13CHxCDF13CHxCDF13CHpCDF
 P2695 Page 1 of 5
 P2695 Page 2 of 5
 P2695 Page 3 of 5
 P2695 Page 4 of 5
 P2695 Page 5 of 5
 P2695 - DLs

Project ID: P-10124 

Sample Summary

Part 5 (DLs) Method 23

Analyte 0_8210_

MB001

Plant 5 

Inlet-R1

Plant 5 

Inlet-R2

Plant 5 

Inlet-R3

Plant 5 

OutletR1

Plant 5 

OutletR2

Plant 5 

OutletR3

Plant 5 

Oven-R1

Plant 5 

Oven-R2

Plant 5 

Oven-R3

pg pg pg pg pg pg pg pg pg pg

2,3,7,8-TCDD 1.79 2.19 1.95 2.02 1.63 2.46 3.33 1.77 2.7 2.03

1,2,3,7,8-PeCDD 2.12 3.48 4.48 4.43 3.76 3.34 5.11 1.76 2.75 2.31

1,2,3,4,7,8-HxCDD 2.09 2.31 1.89 1.62 1.68 2.39 2.61 1.77 3.16 1.87

1,2,3,6,7,8-HxCDD 2.06 2.34 1.77 1.72 1.71 2.16 2.66 1.68 3.25 1.81

1,2,3,7,8,9-HxCDD 2.14 2.42 2.09 1.76 1.96 2.5 2.78 1.88 3.09 1.99

1,2,3,4,6,7,8-HpCDD 2.48 4.14 4.28 3.68 2.81 3.85 4.7 2.05 2.71 2.22

OCDD 4.95 4.04 3.2 4.05 3.17 3.74 5.76 3.02 5.28 2.84

2,3,7,8-TCDF 1.3 1.74 1.53 1.56 1.21 1.46 2.59 1.83 3.39 2.26

1,2,3,7,8-PeCDF 1.43 1.69 1.41 1.35 1.34 2.9 2.78 1.86 3.61 2.46

2,3,4,7,8-PeCDF 1.32 1.51 1.38 1.37 1.25 2.67 2.4 1.74 3.61 2.08

1,2,3,4,7,8-HxCDF 1.38 1.63 1.41 1.21 1.09 1.42 2.23 1.34 2.02 2.26

1,2,3,6,7,8-HxCDF 1.27 1.58 1.41 1.1 1.03 1.35 2.08 1.37 2.06 2.17

2,3,4,6,7,8-HxCDF 1.26 1.81 1.38 1.28 1.19 1.45 2.28 1.42 2.05 2.19

1,2,3,7,8,9-HxCDF 1.66 2.18 1.85 1.66 1.48 1.82 2.73 1.86 2.63 2.77

1,2,3,4,6,7,8-HpCDF 1.5 1.83 1.95 1.4 1.21 1.53 2.14 1.88 2.31 1.35

1,2,3,4,7,8,9-HpCDF 2.08 2.41 2.4 1.99 1.76 2.27 3.31 2.63 3.29 1.9

OCDF 3.57 3.39 3.14 3.07 2.56 3.09 3.91 2.14 2.96 2.04

Total TCDD 1.79 2.19 1.95 2.02 1.63 2.46 3.33 1.77 2.7 2.03

Total PeCDD 2.12 3.48 4.48 4.43 3.76 3.34 5.11 1.76 2.75 2.31

Total HxCDD 2.09 2.35 1.91 1.69 1.78 2.34 2.67 1.77 3.15 1.88

Total HpCDD 2.48 4.14 4.28 3.68 2.81 3.85 4.7 2.05 2.71 2.22

Total TCDF 1.3 1.74 1.53 1.56 1.21 1.46 2.59 1.83 3.39 2.26

Total PeCDF 1.37 1.6 1.39 1.36 1.29 2.78 2.59 1.8 3.61 2.27

Total HxCDF 1.38 1.78 1.5 1.3 1.18 1.5 2.31 1.48 2.17 2.33

Total HpCDF 1.76 2.09 2.15 1.66 1.45 1.86 2.66 2.22 2.74 1.59

Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-960 876-500 591-982

Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_8210_007 P2695_8210_008 P2695_8210_009