Evaporative Emissions from In-Use 

Vehicles: Test Fleet Expansion 

(CRC E-77-2b) 

Final Report 
Evaporative Emissions from In-Use 


Vehicles: Test Fleet Expansion
 

(CRC E-77-2b)
 

Final Report
 

Assessment and Standards Division 

Office of Transportation and Air Quality 

U.S. Environmental Protection Agency 

Prepared for EPA by
 

Harold Haskew & Associates, Inc.
 

EPA Contract No. EP-C-07-028
 

Work Assignment No. 2-05
 

for
 

Southwest Research Institute
 

NOTICE 

This technical report does not necessarily represent final EPA decisions or 

positions. It is intended to present technical analysis of issues using data 

that are currently available. The purpose in the release of such reports is to 

facilitate the exchange of technical information and to inform the public of 

technical developments. 

EPA-420-R-10-025 

October 2010 
EVAPORATIVE EMISSIONS FROM IN-USE VEHICLES: TEST 

FLEET EXPANSION

FINAL REPORT

EPA Report EPA-420-R-10-025

SwRI® Project No. 03.14936.05

CRC Report CRC E-77-2b

Prepared for:

Environmental Protection Agency

26 West Martin Luther King Drive

Cincinnati, OH 45268

EPA Contract EP-C-07-028

Work Assignment 2-05

Prepared by:

Harold M. Haskew, P.E.

Thomas F. Liberty

Harold Haskew & Associates, Inc.

425 W. Huron, Suite 230

Milford, MI 48381

Reviewed and Submitted by:

Martin J. Heimrich

Southwest Research Institute

June 2010

SOUTHWEST RESEARCH INSTITUTE 

SAN ANTONIO, TX ● HOUSTON, TX ● WASHINGTON, DC
EVAPORATIVE EMISSIONS FROM IN-USE VEHICLES: TEST 

FLEET EXPANSION

FINAL REPORT

EPA Report EPA-420-R-10-025

SwRI® Project No. 03.14936.05

CRC Report CRC E-77-2b

Prepared for:

Environmental Protection Agency

26 West Martin Luther King Drive

Cincinnati, OH 45268

EPA Contract EP-C-07-028

Work Assignment 2-05

Prepared by:

Harold M. Haskew, P.E.

Thomas F. Liberty

Harold Haskew & Associates, Inc.

425 W. Huron, Suite 230

Milford, MI 48381

June 2010

Reviewed & Submitted by: Approved by:

_________________________________ ________________________________

Martin J. Heimrich, Manager Jeff J. White, Director

DEPARTMENT OF EMISSIONS RESEARCH AND DEVELOPMENT

ENGINE, EMISSIONS AND VEHICLE RESEARCH DIVISION

This report shall not be reproduced, except in full, without the written approval of Southwest Research Institute®.

Results and discussion given in this report relate only to the test items described in this report.
SwRI Final Report 03.14936.05 ii CRC E-77-2b

FOREWORD

This project was conducted for the US Environmental Protection Agency (EPA) under 

contract with Southwest Research Institute® (SwRI®). This report is submitted in fulfillment of 

Work Assignments 1-05 and 2-05 of EPA Contract EP-C-07-028 by Southwest Research 

Institute, 6220 Culebra Road, San Antonio, Texas 78238. Work Assignment 1-05 was initiated 

on June 28, 2008, and this project continued with Work Assignment 2-05 and was contractually 

completed on June 27, 2010. The program was identified within SwRI as project 03.14175.05 

for Work Assignment 1-05 and as project 03.14936.05 for Work Assignment 2-05.

This report is identified by EPA as EPA-420-R-10-025.

This project was also identified by the Coordinating Research Council (CRC) as project 

E-77-2b. The work reported herein is a part of a continuing series of CRC E-77 evaporative 

emission/permeation test programs.

Harold Haskew and Associates (HH&A) was subcontracted by SwRI to lead the 

laboratory work under SwRI Subcontract Nos. A99099X and A99184X. The evaporative 

emissions and permeation emissions test work was performed at Automotive Testing Laboratory 

(ATL) in Mesa, Arizona.

The EPA Work Assignment Manager was Ms. Constance Hart of the Assessment and 

Standards Division, Office of Transportation and Air Quality, Ann Arbor, Michigan. The project 

contract was managed by the Department of Emissions Research and Development in the 

Engine, Vehicle and Emissions Research Division of SwRI, under the supervision of Mr. Jeff 

White, Director. Mr. Patrick Merritt managed EPA Contract EP-C-07-028, and Mr. Martin 

Heimrich managed Work Assignments 1-05 and 2-05. Mr. Harold Haskew of HH&A was the 

principal technical investigator for the project, and Mr. Gregory Barton of ATL managed the 

emissions test laboratory.
SwRI Final Report 03.14936.05 iii CRC E-77-2b

ABSTRACT

This report describes an ongoing investigation into the evaporative emission performance 

of aging light-duty vehicles. The objective of this study was to add additional data to the 

Coordinating Research Council’s (CRC) E-77-2 evaporative emission/permeation test program. 

This was done to enhance the statistical power of the test program and hence the usability of the

data. The sponsor selected eight vehicles for evaluation on four gasoline fuel blends spanning 

three levels of vapor pressure (7, 9 and 10 psi) and two levels of ethanol (zero and 10 volume 

percent designated as E0 and E10, respectively). The selected vehicles were prepared for test, 

preconditioned for a minimum of four weeks on the test fuel when the ethanol level was 

changed, and then subjected to the test sequence. The evaporative emission test sequence 

consisted of the following four parts:

• Static Permeation Rate Measurements at 86 and 105°F (Includes leak checks)

• Dynamic (Running Loss) Permeation and Canister Loss Measurement at 86°F

• Hot Soak (“True” or Net Value) following the Dynamic Test at 86°F 

• Three Day Diurnal (65°F to 105°F) Permeation and Canister Loss Measurement

The E-77-2b test program was a continuation of the earlier E-77 test program. The permeation 

trends previously shown were again present. The small sample size and limited number of tests 

preclude making statements about statistical validity, but in general:

• Increasing ethanol content (0% to 10%) increased permeation in the “enhanced” 

vehicles tested. 

• “Near zero” and “zero evap” vehicles were less sensitive (or insensitive) to ethanol 

level. This may be due to the permeation control materials used to achieve the lower 

emission levels, or perhaps the limited sample size.

• Increased fuel volatility increased permeation levels for “enhanced” vehicles.
SwRI Final Report 03.14936.05 iv CRC E-77-2b

ACKNOWLEDGEMENTS

The authors would like to recognize the many contributions made by the E-77-2b Project 

Panel and CRC. The E-77-2b CRC Project Panel and CRC staff are identified below:

E-77-2b CRC Project Panel

Name Company

David Brzezinski US Environmental Protection Agency

Wendy Clark National Renewable Energy Laboratory

Dominic DiCicco Ford Motor Company

King Eng Shell Global Solutions (US)

Jim Frusti Chrysler LLC

Pam Graham Inergy Automotive

Benjamin Hancock California Air Resources Board

Constance Hart US Environmental Protection Agency

Phil Heirigs Chevron Global Downstream

Jeff Jetter Honda R&D Americas Inc.

Keith Knoll National Renewable Energy Laboratory

John Koupal US Environmental Protection Agency

David Lax American Petroleum Institute

Jeffrey Long California Air Resources Board

Hector Maldonado California Air Resources Board

Mani Natarajan Marathon Oil Company

David Patterson Mitsubishi Motors R&D of America

Charles Schleyer ExxonMobil Research & Engineering

Jenny Sigelko Chrysler LLC

Nakia Simon Chrysler Group LLC 

James Uihlein Chevron Global Downstream

Michael Viola General Motors R&D Center

Ken Wright ConocoPhillips

CRC Staff

Name Company

Brent Bailey CRC

Chris Tennant CRC

Jane Beck CRC

These individuals met on a regular basis throughout the program to discuss the progress and 

make recommendations. The Steering Committee and CRC contributed significantly to this 

project.
SwRI Final Report 03.14936.05 v CRC E-77-2b

TABLE OF CONTENTS

Page

FOREWORD.................................................................................................................................. ii

ABSTRACT................................................................................................................................... iii

ACKNOWLEDGEMENTS........................................................................................................... iv

LIST OF FIGURES ...................................................................................................................... vii

LIST OF TABLES....................................................................................................................... viii

ACRONYMS................................................................................................................................. ix

EXECUTIVE SUMMARY .............................................................................................................x

1.0 INTRODUCTION ...............................................................................................................1

1.1 Background..........................................................................................................................1

1.2 Period of Performance .........................................................................................................2

2.0 TEST PROGRAM OVERVIEW.........................................................................................3

2.1 Vehicle Selection .................................................................................................................3

2.2 Vehicle Fleet ........................................................................................................................3

2.3 Test Fuels.............................................................................................................................5

2.4 Adaption Period for Test Fuel Changes...............................................................................5

3.0 DISCUSSION OF TEST RESULTS...................................................................................6

3.1 Results..................................................................................................................................6

3.1.1 Static Permeation Rate (Constant Temperature (86°F)).....................................................9

3.1.2 Static Permeation Rate (Constant Temperature (105°F))...................................................9

3.1.3 Dynamic (Running Loss) Permeation................................................................................10

3.1.4 Hot Soak ("True Hot Soak") Permeation Rate ..................................................................11

3.1.5 Diurnal Permeation Performance .....................................................................................12

3.1.6 Temperature Impact on Steady-State Permeation .............................................................15

3.1.7 Special Cases: Fuel System Leak under Pressure .............................................................15

3.1.8 Carbon Canister Breakthrough .........................................................................................19

3.2 Speciation...........................................................................................................................20

3.3 Reactivity ...........................................................................................................................21

3.4 Summary of Findings and Results.....................................................................................28

3.5 Looking Ahead...................................................................................................................28
SwRI Final Report 03.14936.05 vi CRC E-77-2b

TABLE OF CONTENTS (CONT'D)

APPENDICES No. of Pages

A - E-77 TEST CONCEPT AND THEORY .............................................................................5

B - TEST PROCEDURES.........................................................................................................9

C - FUEL INSPECTIONS.........................................................................................................2

D - SUMMARY OF E-77-2b PROGRAM TEST RESULTS AND INDIVIDUAL

VEHICLE EVAPORATIVE TEST RESULTS.................................................................29

E - COMPLETE SPECIATION RESULTS – ALL E-77-2b VEHICLES ...........................262
SwRI Final Report 03.14936.05 vii CRC E-77-2b

LIST OF FIGURES

Figure Page

 1 Period of Performance ......................................................................................................2

 2 86°F Static Performance ...................................................................................................9

 3 105°F Static Performance ...............................................................................................10

 4 Running Loss Performance.............................................................................................11

 5 True Hot Soak Performance............................................................................................12

 6 Day One Diurnal Performance........................................................................................13

 7 Day Two Diurnal Performance.......................................................................................13

 8 Day Three Diurnal Performance.....................................................................................14

 9 Total (3 Day) Diurnal Performance ................................................................................14

 10 Temperature Effect on Static Permeation.......................................................................15

 11 Vehicle 220b Static Performance....................................................................................16

 12 Vehicle 221b Static Performance....................................................................................16

 13 Canister Breakthrough ....................................................................................................19
SwRI Final Report 03.14936.05 viii CRC E-77-2b

LIST OF TABLES

Table Page

 1 E-77-2b Fleet Composition...............................................................................................3

 2 E-77 Composite Fleet – All Programs..............................................................................4

 3 Test Fuel Target Values....................................................................................................5

 4 Enhanced Evap (Tier 1) Certified Data ............................................................................7

 5 Near Zero (Tier 2) Evap Certified Data............................................................................8

 6 Zero Evap Certified Data ..................................................................................................8

 7 Vehicle 220b Data Summary..........................................................................................17

 8 Vehicle 221b Data Summary..........................................................................................18

 9 Speciation Results – Vehicle 210c – 72-Hour Diurnal Test...........................................20

 10 Mass Sorted Speciation Results – Vehicle 210c – 72-Hour Diurnal Test ......................21

 11 Reactivity Results ...........................................................................................................23

 12 Vehicle Reactivity Summaries – Vehicle 206b ..............................................................24

 13 Vehicle Reactivity Summaries – Vehicle 208b ..............................................................24

 14 Vehicle Reactivity Summaries – Vehicle 209b ..............................................................25

 15 Vehicle Reactivity Summaries – Vehicle 210b ..............................................................25

 16 Vehicle Reactivity Summaries – Vehicle 213b ..............................................................26

 17 Vehicle Reactivity Summaries – Vehicle 220b ..............................................................26

 18 Vehicle Reactivity Summaries – Vehicle 221b ..............................................................27

 19 Vehicle Reactivity Summaries – Vehicle 222b ..............................................................27
SwRI Final Report 03.14936.05 ix CRC E-77-2b

ACRONYMS

API.................American Petroleum Institute

ARB ...............California Air Resources Board

ASTM ............ASTM International – a standards organization

ATL................Automotive Testing Laboratory, Inc.

AQIRP............Air Quality Improvement Research Program (Auto/Oil)

CAS................Chemical Abstract Service

CFR................Code of Federal Regulations

CRC................Coordinating Research Council, Inc.

CVS................Constant Volume Sampler

DHB...............Diurnal Heat Build

DVPE.............Dry Vapor Pressure Equivalent

EPA................(US) Environmental Protection Agency

FID .................Flame Ionization Detector

FTTP ..............Fuel Tank Temperature Profile 

GC..................Gas Chromatograph

HC..................Hydrocarbon

HH&A............Harold Haskew & Associates

LA-92.............Unified Driving Cycle

MIR................Maximum Incremental Reactivity

MOVES..........Motor Vehicle Emissions Simulator – EPA model to simulate emissions

from mobile sources

MTBE ............Methyl Tertiary Butyl Ether

NBR ...............Nitrile Rubber or Acrylonitrile Butadiene Rubber

OBD2 .............On-Board Diagnostics Level 2

ORVR ............Onboard Refueling Vapor Recovery

PFI..................Port Fuel Injection

psi...................Pounds per Square Inch

PZEV..............Partial Zero Emission Vehicle (California)

RL SHED.......Running Loss Sealed Housing for Evaporative Determination

RVP................Reid Vapor Pressure

SAE................Society of Automotive Engineers

SHED.............Sealed Housing for Evaporative Determination

SwRI ..............Southwest Research Institute

TEFVO...........Transient Emission Following Vehicle Operation (True Hot Soak)

THC................Total Hydrocarbon

VOC...............Volatile Organic Compound

VT SHED.......Variable Temperature Sealed Housing for Evaporative Determination
SwRI Final Report 03.14936.05 x CRC E-77-2b

EXECUTIVE SUMMARY

This report describes an ongoing investigation into the evaporative emission performance 

of aging light-duty vehicles. Evaporative emissions are, in this context, the fuel-related 

emissions that escape from the vehicle at rest and during vehicle operation (omitting those that 

come from the tailpipe). The CRC E-77-2b Evaporative Emission Test Program, the subject of 

this report, evolved from the “CRC E-77 Pilot Study” and the recently published CRC E-77-2 

report, “Enhanced Evaporative Emissions Vehicles.” This series of studies used test procedures 

and insight borrowed from other CRC test programs, including E-65, “Fuel Permeation from 

Automotive Systems.”

The objective of this study was to add additional data to the Coordinating Research 

Council’s (CRC) E-77-2 permeation test program. This was done to enhance the statistical 

power of the test program and hence the usability of the data. The sponsor selected eight 

vehicles for evaluation on four gasoline fuel blends spanning three levels of vapor pressure (7, 9 

and 10 psi) and two levels of ethanol (zero and 10 volume percent designated as E0 and E10, 

respectively). The selected vehicles were prepared for test, preconditioned for a minimum of four 

weeks on the test fuel when the ethanol level was changed, and then subjected to the test 

sequence. The evaporative emission test sequence consisted of the following four parts:

• Static Permeation Rate Measurement at 86°F and 105°F (Includes leak checks)

• Dynamic (Running Loss) Permeation and Canister Loss Measurement at 86°F

• Hot Soak (“True” or Net Value) following the Dynamic Test at 86°F 

• Three Day Diurnal (65°F to 105°F) Permeation and Canister Loss Measurement

Eight vehicles, each selected to represent a high volume nationwide model, were tested 

under this work assignment:

• Five of the vehicles were owned by CRC and were approved for use in this test 

program. They include: 2002 Nissan Altima, 2002 Chevy Trailblazer, 2004 Chrysler 

Stratus, 2004 Chevy Impala, and 2004 Dodge Ram Pickup. 

• Three vehicles were leased for the duration of the testing. The vehicle types were two 

enhanced evaporative emission certified models (2000 Chevrolet Malibu, and 2000 

Mitsubishi Galant) and one PZEV (2004 Ford Focus). 

Each vehicle started the evaluation with a four week preconditioning on 10 psi E10 fuel, 

and then ran the 10 psi E10 evaporative emission test sequence (static, running loss, hot soak, 

and diurnal). The four week period is thought to be appropriate for the permeation rate to restabilize following the fuel change. After validation and committee approval of these data, the 

fuel was changed to a lower vapor pressure (7 psi) E10 fuel, allowed to re-stabilize for up to one 

week, and then re-evaluated on the emission test sequence. The shorter stabilization period is 

thought appropriate to allow the system to respond to a fuel with equivalent ethanol content but 

lower vapor pressure.

The fuel comparisons selected for this project were two levels of ethanol content with 

vapor pressure varied as listed on the following page.
SwRI Final Report 03.14936.05 xi CRC E-77-2b

TEST FUEL TARGET VALUES

Fuel Reid Vapor Pressure

E0 7 psi, 9 psi

E10 7 psi, 10 psi

It seemed logical to combine as much of the previous E-77 data with the newly gathered 

data into the discussion of results as possible. The "enhanced emission" vehicles gave, on 

average, increasing permeation rates with increasing volatility and with increasing ethanol level. 

The small sample of “near zero” emission vehicles did not indicate the same trend, except for the 

diurnal test results. The authors suggest that this might be due to the permeation emission 

control materials used in the newer vehicles, or it may be an artifact of the smaller sample size.

The project plan included the “speciation” of the evaporative emission results for each of 

the vehicles and test fuels. A sample of the ambient hydrocarbon (HC) concentration in the VTSHED was collected in a TedlarTM bag during each test, and later analyzed for HC species using 

the laboratory’s VarianTM chromatograph, and the “Auto-Oil Test Procedure.” The results of this 

“speciation” allowed the calculation of the average reactivity of the permeate for each of the 

vehicles and fuels.

The E-77-2b test program was a continuation of the earlier E-77 test program which 

added eight vehicles to be tested on four fuels to increase the size of the knowledge base. The 

permeation trends previously shown were again present. The small sample size and limited 

number of tests preclude making statements about statistical validity, but in general:

• Increasing ethanol content (0% to 10%) increased permeation in the "enhanced"

vehicles tested. 

• "Near zero" and "zero evap" vehicles were less sensitive (or insensitive) to ethanol 

level. This may be due to the materials used to achieve the lower emission levels, or 

perhaps the limited sample size.

• Increased fuel volatility increased permeation levels for "enhanced" vehicles.

• The lower emitting "near zero" and "zero evap" vehicles did not exhibit a clear trend 

with increasing volatility level. Again, this may be due to the permeation control

materials used for the vehicles tested, or the small sample size.

• "Near zero" and "zero evap" vehicles had lower emissions than the "enhanced"

vehicles.

• The two vehicles identified with "leaks" were not included in the analysis for the 

permeation trends, but were interesting in that they may suggest deterioration with 

time for the vehicles at eight or more years of age.
SwRI Final Report 03.14936.05 1 of 28 CRC E-77-2b

1.0 INTRODUCTION

1.1 Background

This report describes an ongoing investigation into the evaporative emission performance 

of aging light-duty vehicles. Evaporative emissions are, in this context, the fuel-related 

emissions that escape from the vehicle at rest and during vehicle operation (omitting those that 

come from the tailpipe). The CRC E-77-2b Evaporative Emission Test Program, the subject of 

this report, evolved from the “CRC E-77 Pilot Study” and the recently published CRC E-77-2 

report, “Enhanced Evaporative Emissions Vehicles.” This series of studies used test procedures 

and insight borrowed from other CRC test programs, including E-65, “Fuel Permeation from 

Automotive Systems.” Three reports preceded this study:

• A New Approach to Modeling On-Road Vehicle Evaporative Emissions

(A report to EPA by HH&A - Measure “Mechanisms” June 2, 2005)

• Vehicle Evaporative Emission Mechanisms: A Pilot Study - CRC E-77 

(Ten Vehicle Concept Demonstration - Published June 24, 2008)

• Enhanced Evaporative Emission Vehicles - CRC E-77-2

(Eight vehicle continuation of the pilot study – Published April 9, 2010)

The test work for all these programs was conducted at the Automotive Testing 

Laboratory, Inc. (ATL) facilities in Mesa, AZ1

 1

 ATL, 263 S. Mulberry Street, Mesa, AZ (480) 649 7906, 

, where unique experience and facilities exist to 

conduct evaporative emission programs of this nature.

The objective of this study was to add additional data to the Coordinating Research 

Council (CRC) E-77-2 permeation test program. This was done to enhance the statistical power 

of the test program and hence the usability of the data. The sponsor selected eight vehicles for 

evaluation on four gasoline fuel blends spanning three levels of vapor pressure (7, 9 and 10 psi) 

and two levels of ethanol (zero and 10 volume percent designated as E0 and E10, respectively). 

The selected vehicles were prepared for test, preconditioned for a minimum of four weeks on the 

test fuel when the ethanol level was changed, and then subjected to the test sequence. The 

evaporative emission test sequence consisted of the following four parts:

• Static Permeation Rate Measurement at 86°F and 105°F (Includes leak checks)

• Dynamic (Running Loss) Permeation and Canister Loss Measurement at 86°F

• Hot Soak (“True” or Net Value) following the Dynamic Test at 86°F 

• Three Day Diurnal (65°F to 105°F) Permeation and Canister Loss Measurement

While the main objective of this project was to measure the evaporative emission 

performance of the selected vehicles, a second objective was to develop and refine the test 

procedures and analysis methods. We have included comprehensive documentation of these test 

procedures in Appendix A (E-77 Test Concept and Theory) and Appendix B (Test Procedures).

www.ATL-AZ.com, Greg Barton, President
SwRI Final Report 03.14936.05 2 of 28 CRC E-77-2b

Each vehicle started the evaluation with a four week preconditioning on 10 psi E10 fuel, 

and then ran the 10 psi E10 evaporative emission test sequence (static, running loss, hot soak, 

and diurnal). The four week period is thought to be appropriate for the permeation rate to restabilize following the fuel change. After validation and committee approval of these data, the 

fuel was changed to a lower vapor pressure (7 psi) E10 fuel, allowed to re-stabilize for up to one 

week, and then re-evaluated on the emission test sequence. The shorter stabilization period is 

thought appropriate to allow the system to respond to a fuel with equivalent ethanol content but 

lower vapor pressure.

Once the ethanol fuel test results were approved, the vehicle was refueled with 9 psi E0 

fuel, and again subjected to a four week minimum re-stabilization. The evaporative performance 

test sequence was then repeated, and repeated again with a 7 psi E0 fuel after a one week 

stabilization period. 

1.2 Period of Performance

The vehicle emission testing started during the week of November 17, 2008. Procedural 

errors were identified, and the data was discarded. The vehicle testing was restarted in January 

2009 with procedural corrections, and continued through October of 2009. No erroneous data 

were included in the project data set. The period of performance by vehicle number is given in 

Figure 1. Fifty-four (54) weekly progress reports were made.

FIGURE 1. PERIOD OF PERFORMANCE

206b

208b

209b

210b

213b

220b

221b

222b

Vehicle Test ID 

E-77-2b Testing Period of Vehicles
SwRI Final Report 03.14936.05 3 of 28 CRC E-77-2b

2.0 TEST PROGRAM OVERVIEW

2.1 Vehicle Selection

Eight vehicles, each selected to represent a high volume nationwide model, were tested 

under this work assignment:

• Five of the vehicles were owned by CRC and were approved for use in this test 

program. They include: 2002 Nissan Altima, 2002 Chevy Trailblazer, 2004 

Chrysler Stratus, 2004 Chevy Impala, and 2004 Dodge Ram Pickup. 

• Three vehicles were leased for the duration of the testing. The vehicle types were 

two enhanced evaporative emission certified models (2000 Chevrolet Malibu, and 

2000 Mitsubishi Galant) and one PZEV2

All candidate vehicles for this program received a thorough inspection before beginning 

the test preparation sequence. This included inspection of the engine, transmission, axles, 

exhaust system and tires, and verification that no OBD2 faults were present. 

Each candidate vehicle was checked at the start of the test program to make sure that 

there were no system leaks, to verify system purge was present, and to generally establish that 

the vehicles were safe to operate. Each vehicle had to be registered and insured for road 

operation to accomplish the many road preconditioning drives.

2.2 Vehicle Fleet

Table 1 below lists and describes the eight vehicles studied in this program. The 

odometers (Odo.) in the following tables are the indicated odometer readings at the time of the 

vehicle’s initial inspection into the testing program.

TABLE 1. E-77-2b FLEET COMPOSITION

(2004 Ford Focus). 

 2

 Partial Zero Emission Vehicle – a California certification class with very low exhaust emission and a “zero 

evaporative emission system.”

Fuel Tank

Veh Evap Standards Tank Plastic

No. Yr Make Model Odo. Evap Family (all are ORVR) Size Metal

220b 2000 Chevrolet Malibu 69,367 YGMXR0124919 Tier 1 14.2 Plastic

221b 2000 Mitsubishi Galant ES 97,875 YDSXR0165A1F Tier 1 16.3 Plastic

206b 2002 Nissan Altima 110,399 2NSXR0120RCB Tier 1 20.0 Plastic

208b 2002 Chevrolet Trailblazer 60,233 2GMXR0175922 Tier 1 18.6 Plastic

209b 2004 Chrysler Stratus 63,778 4CRXR0130GBA Tier 1 16.0 Plastic

210b 2004 Chevrolet Impala 63,157 4GMXR0124919 Near Zero 17.0 Plastic

213b 2004 Dodge Ram 1500 99,372 4CRXR0218GDH Near Zero 35.0 Plastic

222b 2004 Ford Focus ZX3 71,633 4FMXR0120GCX Zero Evap 14.0 Metal

 
SwRI Final Report 03.14936.05 4 of 28 CRC E-77-2b

As stated previously, the E-77-2b program added eight vehicles to the E-77 program 

database. Table 2 below lists the “composite E-77 vehicle fleet,” sorted by vehicle model year, 

with the 2b vehicles highlighted in light blue. Not all data from the composite fleet are usable for 

later analysis, as the use of the INNOVA analyzer for identification of methanol and refrigerant 

(R-134a) leaks did not become available until the latter part of the Pilot Program. Pre INNOVA 

data tests that were not used in the analysis are indicated with the yellow shading. 

TABLE 2. E-77 COMPOSITE FLEET – ALL PROGRAMS

___________________________

Light blue – E-77-2b program vehicles

Yellow – Pre-INNOVA tests not used in the analysis

Tank Fuel Tank

Veh Evap Standards Size Plastic

No. Yr Make Model Odo. Evap Family gal. Metal

003 1992 Honda Accord 71,129 92FG Tier 0 17.0 Metal

010 1992 Toyota Camry 162,838 EV-E Tier 0 18.5 Metal

009 1995 Plymouth Neon 106,220 SCR1050AYM02 Tier 0 11.2 Metal

001 1996 Chevrolet S-10 68,420 TGM1082AYMEA Tier 1 19.0 Metal

006 1996 Chevrolet Cavalier 112,768 TGM1089AYMEA Tier 1 15.3 Metal

007 1996 Chevrolet Cavalier 113,125 TGM1089AYMEA Tier 1 15.3 Metal

008 1996 Ford Explorer 114,822 TFM1120AYMED Tier 1 21.0 Metal

202b 1996 Ford Taurus 86,538 TFM1115AYMEB Tier 1 16.0 Metal

216b 1996 Ford Taurus 88,820 TFM1115AYMEB Tier 1 16.0 Metal

004 1999 Dodge Grand Caravan SE 98,765 XCRXE0101G2A Tier 0 20.0 Plastic

204b 1999 Honda Accord 100,418 XHNXR0130AAA Tier 1 17.1 Metal

002 2000 Toyota Tacoma 80,557 YTYXE0095AE0 Tier 1 15.1 Metal

220b 2000 Chevrolet Malibu 69,367 YGMXR0124919 Tier 1 14.2 Plastic

221b 2000 Mitsubishi Galant ES 97,875 YDSXR0165A1F Tier 1 16.3 Plastic

205b 2001 Toyota Corolla 92,047 1TYXR0115AK1 Tier 1 13.2 Metal

207b 2001 Dodge Caravan 92,740 1CRXR0165XAA Tier 1 20.0 Plastic

206b 2002 Nissan Altima 2NSXR0120RCB Tier 1 20.0 Plastic

208b 2002 Chevrolet Trailblazer 60,233 2GMXR0175922 Tier 1 18.6 Plastic

209b 2004 Chrysler Stratus 63,778 4CRXR0130GBA Tier 1 16.0 Plastic

210b 2004 Chevrolet Impala 63,157 4GMXR0124919 Tier 2 17.0 Plastic

211b 2004 Toyota Camry LE 43,588 4TYXR0130A11 Tier 2 18.5 Plastic

213b 2004 Dodge Ram 1500 99,372 4CRXR0218GDH Tier 2 35.0 Plastic

214b 2004 Ford Escape 40,188 4FMXR0110BBE Tier 2 16.0 Plastic

215b 2004 Toyota High Lander 88,693 4TYXR0165PZ1 Tier 2 19.1 Plastic

222b 2004 Ford Focus ZX3 71,633 4FMXR0120GCX Zero Evap 14.0 Metal

212b 2006 Ford Taurus 28,354 6FMXR0185GAK Tier 2 18.0 Metal

005 2007 Ford Taurus 6,916 7FMXR0185GAR Tier 2 18.0 Metal

E-77 Composite Fleet - All Programs
SwRI Final Report 03.14936.05 5 of 28 CRC E-77-2b

2.3 Test Fuels

The fuel comparisons selected for this project were two levels of ethanol content with 

vapor pressure varied as listed in Table 3. 

TABLE 3. TEST FUEL TARGET VALUES

7 psi 9 psi 10 psi

E0 X X

E10 X X

CRC had fuels remaining from Project E-74 in quantities sufficient to conduct this 

program, e.g., 7 psi E0 and E10. Inspection records of the base fuels are located in Appendix C,

using their E-74b identifications, fuels 6 and 7, respectively. The nominal 7 psi fuels, both E0 

and E10, were locally blended with commercial butane to make the higher volatility 9 psi E0, 

and the 10 psi E10. The blends were done in drum batches, approximately 50 gallons at a time, 

by adding small amounts of butane, circulating for a brief period, then sampling and determining 

the new volatility with a “Grabner”3

 3

 

instrument, using test procedures described in ASTM 

D5191. The higher (10 psi instead of 9 psi) vapor pressure of the E10 fuel was specified because 

many localities permit “splash blending” of ethanol to gasoline and allow a 1 psi exemption for 

their vapor pressure limits.

2.4 Adaption Period for Test Fuel Changes

Many areas of the United States were required to use an oxygenated fuel to improve 

vehicle emissions, especially during the summer season. While Methyl Tertiary Butyl Ether 

(MTBE) was the most common oxygenate, ethanol was also used. Project E-65 demonstrated 

that the permeation of vehicle fuel systems increased with the use of fuels containing ethanol, 

compared to fuels with MTBE, or no oxygenate. Project E-65 also demonstrated that if ethanol 

had been previously used, and the fuel replaced with a non-ethanol blend, it could take two to 

four weeks for the ethanol increase to dissipate (the “ethanol carry-over effect”). 

The protocols adopted for this test program were to require a minimum of four weeks of 

vehicle exposure to a new fuel when first introducing ethanol to the vehicle, and the same period 

of time when moving to an ethanol-free (E0) fuel.

www.grabner-instruments.com, MINIVAP VPS / VPSH Vapor Pressure Tester. The portable MINIVAP VPS 

and VPSH vapor pressure testers are the worldwide accepted standard instruments for the determination of the vapor 

pressure of gasoline according to ASTM D5191, ASTM D6377, ASTM D6378 and EN 13016 1+2.
SwRI Final Report 03.14936.05 6 of 28 CRC E-77-2b

3.0 DISCUSSION OF TEST RESULTS

3.1 Results

The results from the E-77-2b vehicle tests are summarized in Appendix D. It seemed 

logical to combine as much of the previous E-77 data with the newly gathered data into the 

discussion of results as possible. Not all of the data were comparable, and the following 

summary is offered to explain the various choices. 

• While not part of the contracted E-77 Pilot Study, the laboratory found that the vehicle 

tests needed to be corrected for the presence of the non-fuel contributors methanol and 

the refrigerant R134a. The INNOVA analyzer that the laboratory purchased and used to 

make these corrections was not available for testing until vehicle 006. Of the remaining 

vehicles tested, only 006 and 008 were Tier 1 models (vehicle 007 was an implanted leak 

test, and vehicles 009 and 010 were pre-enhanced, Tier 0 models). The Pilot Study only 

ran a one day diurnal, rather than the three day test that became the norm.

• The 105oF static tests were first introduced in the E-77-2b test sequence to enhance the 

evidence that permeation is directly affected by temperature. The earlier test programs 

did not have that information.

Emission results are presented below for each of the four evaporative emission elements 

(static, running loss, hot soak and diurnal), with data averaged for selected and representative 

vehicles tested in the E-77, E-77-2 and E-77-2b programs that were tested on the four fuels used 

in this (2b) study. A list of the data used in the following plots is tabulated in Tables 4, 5, and 6. 
SwRI Final Report 03.14936.05 7 of 28 CRC E-77-2b

TABLE 4. ENHANCED EVAP (Tier 1) CERTIFIED DATA

86 Static 105 Static RL Tru-HS

Veh. Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

06 7E0 --- --- --- --- 375.6 --- --- ---

9E0 --- --- --- --- 468.5 --- --- --- E-77

08 7E0 --- --- --- --- 133.1 --- --- ---

9E0 --- --- --- --- 150.4 --- --- ---

204 10E10 84.3 --- 316.4 0.4 1547.9 1779.9 1771.1 5099.0

7E10 66.4 --- 287.9 29.7 1260.2 1165.2 1165.2 3590.6

9E0 33.8 --- 249.2 44.3 628.3 581.0 577.0 1786.4

7E0 12.9 --- 222.6 18.7 367.2 287.7 293.6 948.5

205 10E10 41.6 --- 191.6 29.5 1794.1 1730.9 1741.7 5266.6

7E10 59.6 --- 232.8 71.9 1783.4 1715.0 1523.9 5022.3

9E0 19.5 --- 103.1 1.0 499.5 481.0 507.2 1487.8

7E0 9.9 --- 67.1 0.0 383.0 365.4 367.0 1115.4

207 10E10 78.7 --- 858.1 237.7 1406.4 1264.4 1223.7 3894.5

7E10 64.4 --- 812.2 122.2 1086.5 812.0 823.6 2722.0

9E0 32.5 --- 833.9 5.8 406.4 337.3 308.0 1051.7 E-77-2

7E0 40.1 --- 842.5 0.0 397.5 302.6 268.9 969.1

214 10E10 24.4 --- 133.1 57.4 492.0 839.4 11373.8 12705.2

7E10 23.9 --- 105.7 32.9 524.2 397.4 394.4 1315.9

9E0 10.7 --- 96.7 52.1 455.9 358.5 1101.7 1916.1

7E0 25.2 --- 36.3 3.3 494.3 319.0 281.5 1094.8

215 10E10 10.4 --- 71.9 1.6 319.2 260.2 237.0 816.4

7E10 12.2 --- 97.9 0.0 224.7 231.7 267.5 724.0

9E0 8.5 --- 81.1 25.1 202.1 165.9 176.3 544.3

7E0 8.7 --- 79.7 22.5 248.3 294.1 288.8 831.1

206b 10E10 124.9 314.1 546.5 165.1 2776.6 31004.6 43028.2 76809.3

7E10 149.3 307.9 436.7 174.9 2582.6 2258.5 2144.0 6985.0

9E0 61.1 178.8 365.6 102.5 1500.0 1285.6 1250.8 4036.4

7E0 52.0 118.1 245.1 68.8 1171.9 931.2 890.3 2993.3

208b 10E10 37.5 61.2 329.5 36.0 795.0 561.4 495.8 1852.2

7E10 27.2 51.8 254.7 77.3 780.6 510.4 449.4 1740.5

9E0 37.2 55.0 228.0 37.9 778.0 567.2 519.4 1864.6 E-77-2b

7E0 24.8 64.5 124.9 75.0 422.1 419.4 476.0 1317.5

209b 10E10 28.8 73.3 323.6 113.7 535.5 423.5 475.5 1434.5

7E10 28.6 54.1 205.7 24.5 383.1 349.1 323.5 1055.7

9E0 23.4 29.5 144.4 5.0 327.8 250.5 224.3 802.6

7E0 16.8 28.8 166.2 16.8 354.1 249.7 218.1 821.9

86 Static 105 Static RL Tru-HS

Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

7psi E0 23.8 70.5 223.1 25.6 434.7 396.1 385.5 1261.4

9psi E0 28.3 87.8 262.7 34.2 541.7 503.4 583.1 1686.2

7psi E10 54.0 137.9 304.2 66.7 1078.2 929.9 886.4 2894.5

10psi E10 53.8 149.5 346.3 80.2 1208.3 4733.0 7543.4 13484.7

Diurnal Emissions- mg

Diurnal Emissions- mg

Average Values for the Tier 1 Vehicle Tests
SwRI Final Report 03.14936.05 8 of 28 CRC E-77-2b

TABLE 5. NEAR ZERO (Tier 2) EVAP CERTIFIED DATA

TABLE 6. ZERO EVAP CERTIFIED DATA

An observation is present in the following analysis. The "enhanced emission" vehicles 

gave, on average, increasing permeation rates with increasing volatility and with increasing 

ethanol level. The small sample of “near zero” emission vehicles did not indicate the same trend, 

except for the diurnal test results. The authors suggest that this might be due to the permeation 

control materials used in the newer vehicles, or it may be an artifact of the smaller sample size.

86 Static 105 Static RL Tru-HS

Veh. Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

211 10E10 19.9 138.3 0.0 337.0 226.8 217.9 781.6

7E10 9.4 56.3 13.8 243.8 183.8 184.3 611.9

9E0 10.1 83.7 15.3 130.3 115.8 100.6 346.7

7E0 9.1 104.6 0.7 207.1 100.2 87.4 394.7 E-77-2

212 10E10 10.6 148.9 0.0 124.3 87.9 102.8 315.1

7E10 21.8 201.2 0.0 184.8 100.2 75.8 360.8

9E0 3.2 115.8 0.4 100.5 70.8 57.4 228.7

7E0 0.9 184.5 1.8 101.6 71.2 57.0 229.7

210b 10E10 19.9 70.1 147.5 60.6 486.5 458.3 441.3 1386.1

7E10 29.9 51.9 218.3 61.8 445.1 388.3 359.1 1192.5

9E0 21.2 33.5 171.1 19.8 407.8 377.4 358.3 1143.4

7E0 18.7 35.5 216.0 49.0 270.6 266.6 221.1 758.3 E-77-2b

213b 10E10 39.2 106.8 130.9 0.9 650.6 615.4 700.7 1966.7

7E10 29.6 82.2 243.1 60.5 602.8 577.7 588.9 1769.4

9E0 14.7 34.5 203.1 14.5 346.3 328.4 292.8 967.5

7E0 21.1 35.3 135.1 12.2 357.8 283.3 276.5 917.5

86 Static 105 Static RL Tru-HS

Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

7psi E0 12.5 35.4 160.1 15.9 234.2 180.3 160.5 575.1

9psi E0 12.3 34.0 143.4 12.5 246.2 223.1 202.3 671.6

7psi E10 22.7 67.0 179.7 34.0 369.1 312.5 302.0 983.6

10psi E10 22.4 88.4 141.4 15.4 399.6 347.1 365.7 1112.4

Diurnal Emissions- mg

Average Values for Tier 2 Vehicle Tests

Diurnal Emissions- mg

86 Static 105 Static RL Tru-HS

Veh. Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

222b 7E0 3.38 6.36 128.79 5.44 58.6 39.0 38.8 136.4

9E0 3.10 5.75 45.55 0.00 77.4 41.9 57.9 177.2 E-77-2b

7E10 12.10 16.29 61.68 0.00 99.6 104.0 84.0 287.6

10E10 3.75 7.36 73.08 0.0 104.1 79.7 73.4 257.2

Diurnal Emissions- mg
SwRI Final Report 03.14936.05 9 of 28 CRC E-77-2b

3.1.1 Static Permeation Rate (Constant Temperature (86°F))

Average permeation rates are compared by fuel specification for three vehicle groups:

“enhanced,” “near zero,” and “zero evap” evaporative emissions. 

Figure 2 shows the 86oF static permeation rate performance for the average of eight 

“enhanced” and four “near zero” vehicles tested on the four fuels in this test program. This 

composite result confirms the trend shown in the earlier programs of increasing permeation rate 

with increasing ethanol content and increasing vapor pressure of the fuel. The “zero evap” 

vehicle is shown only for reference. Due to a sample size of only one, no statistical significance 

can be implied. 

FIGURE 2. 86°F STATIC PERFORMANCE

3.1.2 Static Permeation Rate (Constant Temperature (105°F))

Average permeation rates are compared by fuel specification for two vehicle groups: 

“enhanced” and the “near zero” evaporative emissions at an elevated test temperature (105oF).

0

10

20

30

40

50

60

7psi E0 9psi E0 7psi E10 10psi E10

Static Permeation Rate - mg/hr

Test Fuel

86o F Static Performance

All E77 Programs

Enhanced - 8 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle
SwRI Final Report 03.14936.05 10 of 28 CRC E-77-2b

Figure 3 shows the 105oF static permeation rate performance for the average of three 

“enhanced” and two “near zero” vehicles tested on the four fuels in this test program. Again, 

this composite result confirms the trends shown in the earlier programs of increasing permeation 

rate with increasing ethanol content and increasing vapor pressure of the fuel for the enhanced 

vehicles, albeit at a higher test temperature. The “zero evap” vehicle is shown for reference.

FIGURE 3. 105°F STATIC PERFORMANCE

3.1.3 Dynamic (Running Loss) Permeation

In a similar presentation, Figure 4 shows the average “Running Loss” permeation rate for 

the vehicle types and the fuels tested. “Running Loss” permeation as described here is the 

permeation measured during a “cold start” 48-minute drive in a Running Loss Sealed Housing 

for Evaporative Determination (RL-SHED) at 86°F.

Figure 4 presents the running loss permeation rates for eight “enhanced” and four “near 

zero” vehicles tested. The “enhanced” vehicles displayed a similar increase in permeation with 

ethanol content and vapor pressure as was seen in the static tests, but the “near zero” vehicles 

appear to be insensitive within the small sample size available (4).

0

20

40

60

80

100

120

140

160

7psi E0 9psi E0 7psi E10 10psi E10

Static Permeation Rate - mg/hr

Test Fuel

105o F Static Performance

All E77 Programs

Enhanced - 3 Vehicles

Near Zero - 2 Vehicles

Zero Evap - 1 Vehicle
SwRI Final Report 03.14936.05 11 of 28 CRC E-77-2b

FIGURE 4. RUNNING LOSS PERFORMANCE

3.1.4 Hot Soak (“True Hot Soak”) Permeation

The Hot Soak emissions as defined in this report are the net increase in permeation rates 

following vehicle operation. The mass increase was measured in the SHED for one hour 

immediately following vehicle operation, and the previously measured static (or normal) 

permeation at the same temperature was subtracted. Although this is not the traditional CFR 

definition, the justification for the new definition is shown in Appendix B (the "True" Hot Soak, 

page B-7) of this report.

The “True Hot Soak” performance for the average of the vehicles is summarized in 

Figure 5. There was a large increase (~2.5:1) in the hot soak value with the E10 fuel compared 

to the E0 for the “enhanced” vehicles, but no clear trend is present for the “near zero” vehicles 

due in part to the small sample size and relatively low levels attained. There may be an 

indication that hot soak permeation may decrease on the Near Zero vehicles with increasing 

vapor pressure.

0

50

100

150

200

250

300

350

400

7psi E0 9psi E0 7psi E10 10psi E10

Running Loss Permeation Rate - mg/hr

Test Fuel

Running Loss Performance

All E77 Programs

Enhanced - 8 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle
SwRI Final Report 03.14936.05 12 of 28 CRC E-77-2b

FIGURE 5. TRUE HOT SOAK PERFORMANCE

3.1.5 Diurnal Permeation Performance

Figure 6 presents the diurnal permeation results for the first day of the three-day diurnal 

test (65° to 105°F). A similar performance trend can be made for days 2 and 3, and for the total 

emission for all three days

Figure 6 shows that the average day 1 diurnal permeation for the “enhanced” vehicles

increased as ethanol content increased. The “near zero” vehicles showed a slight increasing 

higher trend with increasing volatility. The one “zero evap” vehicle run shows considerably

lower diurnal performance.

Figures 7, 8, and 9 display the diurnal performance obtained for days two, three, and the 

total of the 3-day diurnal tests run (E77-2 and E77-2b). The trends observed for day 1 hold true 

for the entire test. The averages for the 10 psi E10 fuel are highly dominated by one vehicle.

0

10

20

30

40

50

60

70

80

90

7psi E0 9psi E0 7psi E10 10psi E10

True Hot Soak Permeation Rate - mg/hr

Test Fuel

True Hot Soak Performance

All E77 Programs

Enhanced - 8 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle
SwRI Final Report 03.14936.05 13 of 28 CRC E-77-2b

FIGURE 6. DAY ONE DIURNAL PERFORMANCE

FIGURE 7. DAY TWO DIURNAL PERFORMANCE

0

200

400

600

800

1000

1200

1400

7psi E0 9psi E0 7psi E10 10psi E10

Diurnal Permeation Rate - mg/day

Test Fuel

Day 1 Diurnal Performance

All E77 Programs

Enhanced - 8/10 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle

8 Vehicles

8 Vehicles

10 Vehicles

10 Vehicles

0

200

400

600

800

1000

1200

1400

1600

1800

2000

7psi E0 9psi E0 7psi E10 10psi E10

Diurnal Permeation Rate - mg/day

Test Fuel

Day 2 Diurnal Performance

All E77 Programs

Enhanced - 8 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle

4733
SwRI Final Report 03.14936.05 14 of 28 CRC E-77-2b

FIGURE 8. DAY THREE DIURNAL PERFORMANCE

FIGURE 9. TOTAL (3 DAY) DIURNAL PERFORMANCE

0

200

400

600

800

1000

1200

1400

1600

1800

2000

7psi E0 9psi E0 7psi E10 10psi E10

Diurnal Permeation Rate - mg/day

Test Fuel

Day 3 Diurnal Performance

All E77 Programs

Enhanced - 8 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle

7543

0

500

1000

1500

2000

2500

3000

7psi E0 9psi E0 7psi E10 10psi E10

Diurnal Permeation Rate - mg

Test Fuel

Total (3 Days) Diurnal Performance

All E77 Programs

Enhanced - 8 Vehicles

Near Zero - 4 Vehicles

Zero Evap - 1 Vehicle

13485
SwRI Final Report 03.14936.05 15 of 28 CRC E-77-2b

3.1.6 Temperature Impact on Steady-State Permeation

For many years, and from many test programs, it has been suggested and confirmed that a 

10oC increase (18°F) in ambient temperature approximately doubles the steady-state (static) 

permeation rate. The results of this latest program reconfirm that temperature impact. Figure 10 

cross-plots the 86oF static permeation against the 105o F static permeation for six vehicles run on 

four different fuels, with the 2:1 line shown for reference. Vehicles 206b, 208b, and 209b are 

certified to Tier 1 standards. Vehicles 210b and 213b are Tier 2, while vehicle 222b is a Zero 

Evap model.

FIGURE 10. TEMPERATURE EFFECT ON STATIC PERMEATION

3.1.7 Special Cases: Fuel System Leak Under Pressure

Vehicles 220b (2000 Chevrolet Malibu) and 221b (2000 Mitsubishi Galant) both 

exhibited significant leaks when the fuel system was pressurized during the static test. This 

procedure (Appendix B – Test Procedures) is utilized to check for fuel system leaks. The effect 

of this leak can be seen in Figures 11 and 12. 

0

50

100

150

200

250

300

350

0 20 40 60 80 100 120 140 160

105 deg F Static Permeation 

-

mg/hr

86 deg F Static Permeation - mg/hr

Temperature Effect on Static Permeation

SwRI E-77-2b Program Vehicles

10E10 Fuel

7E10 Fuel

9E0 Fuel

7E0 Fuel

206b - Large Square

208b - Small Diamond

209b - Small Circle

210b - Small Triangle

213b - Small Square

222b - Large Triangle
SwRI Final Report 03.14936.05 16 of 28 CRC E-77-2b

FIGURE 11. VEHICLE 220b STATIC PERFORMANCE

FIGURE 12. VEHICLE 221b STATIC PERFORMANCE

0

5000

10000

15000

20000

25000

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 220b - 2000 Chevrolet Malibu 

10 psi E10 - 7537

7 psi E10 - 7564

9 psi E0 - 7644

7 psi E0 - 7677

0

200

400

600

800

1000

1200

1400

1600

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 221b - 2000 Mitsubishi Galant

10 psi E10 - 7557

7 psi E10 - 7571

9 psi E0 - 7650

7 psi E0 - 7691
SwRI Final Report 03.14936.05 17 of 28 CRC E-77-2b

While this leak shows up very dramatically on the static leak check test, there is no 

reason to think the effect is not present in all testing (static, dynamic and diurnal). For this 

reason, these two vehicles were removed from all analyses in Section 3.1. The reactivity results 

are presented for reference in section 3.3, but should be used with care, as there are permeation 

and leaks present in the analysis. Tables 7 and 8 display the actual test results.

TABLE 7. VEHICLE 220b DATA SUMMARY

2000 Chevrolet Malibu SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

220b 10.0/E10 Static (86) Perm 05/05/09 7537 68.1 0.00

Press. Incr. 20127.5

Prs+Fuel Incr. 23281.0

Static (105) Perm 05/06/09 7541 214.3 0.00

Press. Incr. 33978.6

Prs+Fuel Incr. 40776.4

Dynamic RL 05/07/09 25774 134.0 0.00

TEFVO 5.1 0.00

72 DHB 65-105 05/12/09 7546

Day 1 1306.1 0.30

Day 2 1889.7 10.40

Day 3 2055.8 24.30

7.0/E10 Static (86) Perm 06/03/09 7564 50.4 0.00

Press. Incr. 9122.4

Prs+Fuel Incr. 15723.6

Static (105) Perm 06/04/09 7565 182.0 0.00

Press. Incr. 23090.2

Prs+Fuel Incr. 28945.5

Dynamic RL 06/05/09 25781 697.9 0.00

TEFVO 76.8 0.00

72 DHB 65-105 06/09/09 7569

Day 1 1177.6 0.00

Day 2 1612.1 0.00

Day 3 1483.1 0.00

9.0/E0 Static (86) Perm 08/18/09 7644 102.3 0.00

Press. Incr. 23180.8

Prs+Fuel Incr. 28272.5

Static (105) Perm 08/19/09 7647 1858.1 0.00

Press. Incr. 35297.9

Prs+Fuel Incr. 51362.4

Dynamic RL 08/20/09 25789 2417.0 0.00

"True" HS 352.5 0.00

72 DHB 65-105 08/25/09 7657

Day 1 6733.3 0.00

Day 2 5884.8 0.00

Day 3 7049.9 0.00

7.0/E0 Static (86) Perm 09/09/09 7677 62.7 0.00

Press. Incr. 13514.7

Prs+Fuel Incr. 16556.8

Static (105) Perm 09/10/09 7680 279.2 0.00

Press. Incr. 22735.8

Prs+Fuel Incr. 30081.7

Dynamic RL 09/11/09 25794 3447.3 0.00

"True" HS 707.1 0.00

72 DHB 65-105 09/15/09 7686

Day 1 6218.7 0.00

Day 2 6214.7 0.00

Day 3 7041.9 0.00
SwRI Final Report 03.14936.05 18 of 28 CRC E-77-2b

TABLE 8. VEHICLE 221b DATA SUMMARY

The leak in vehicle 220 was later determined to be a deteriorating crack in the fuel vapor 

vent elbow on the fuel sending unit on the top of the tank The vehicle was dropped from further 

testing in the later E-77-2c program.

2000 Mitsubishi Galant SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

221b 10.0/E10 Static (86) Perm 05/27/09 7557 38.9 0.00

Press. Incr. 1568.7

Prs+Fuel Incr. 1693.9

Static (105) Perm 05/28/09 7559 80.2 0.00

Press. Incr. 1932.6

Prs+Fuel Incr. 2147.1

Dynamic RL 05/29/09 25778 116.2 0.00

TEFVO 26.9 0.00

72 DHB 65-105 06/02/09 7562

Day 1 827.9 2.00

Day 2 724.1 5.40

Day 3 702.4 21.80

7.0/E10 Static (86) Perm 06/10/09 7571 22.7 0.00

Press. Incr. 930.7

Prs+Fuel Incr. 971.0

Static (105) Perm 06/11/09 7572 61.4 0.00

Press. Incr. 1282.3

Prs+Fuel Incr. 1408.5

Dynamic RL 06/12/09 25783 102.0 0.00

TEFVO 40.5 0.00

72 DHB 65-105 06/16/09 7579

Day 1 894.7 0.00

Day 2 676.7 0.00

Day 3 618.0 0.00

9.0/E0 Static (86) Perm 08/20/09 7650 55.6 0.00

Press. Incr. 1348.8

Prs+Fuel Incr. 1406.0

Static (105) Perm 08/21/09 7652 94.8 0.00

Press. Incr. 1646.7

Prs+Fuel Incr. 1788.2

Dynamic RL 08/24/09 25790 135.2 0.00

"True" HS 29.0 0.00

72 DHB 65-105 09/01/09 7667

Day 1 706.4 0.30

Day 2 543.7 2.60

Day 3 538.3 9.30

7.0/E0 Static (86) Perm 09/17/09 7691 35.9 0.00

Press. Incr. 988.8

Prs+Fuel Incr. 961.8

Static (105) Perm 09/18/09 7692 66.8 0.00

Press. Incr. 1215.9

Prs+Fuel Incr. 1343.8

Dynamic RL 09/22/09 25797 189.8 0.00

"True" HS 42.5 0.00

72 DHB 65-105 10/07/09 7716

Day 1 603.0 0.00

Day 2 503.1 0.00

Day 3 487.0 0.00
SwRI Final Report 03.14936.05 19 of 28 CRC E-77-2b

3.1.8 Carbon Canister Breakthrough

Canister breakthrough is measured by the weight change recorded for the trap canister 

outside the SHED. It quantifies the amount of vapors that overwhelm the evaporative system 

storage canister. Figure 13 displays the breakthrough resulting from testing of 9 psi E0 fuel. 

FIGURE 13. CANISTER BREAKTHROUGH

Of the six vehicles for which useable data were obtained for subsequent analysis in this 

program, no breakthrough occurred when tested on summer grade 7 psi fuel, only two showed 

some breakthrough on 9 psi transitional grade fuels (shown in Figure 13), but all six exhibited 

significant breakthrough when tested with 10 psi winter grade fuel.

The lack of canister breakthrough for the 7 psi fuels (summer grade) indicates that the 

storage capacity of these six systems is appropriately sized. 

60

65

70

75

80

85

90

95

100

105

110

0

5

10

15

20

25

30

35

40

45

50

0 10 20 30 40 50 60 70

SHED Temperature - deg F

Canister Breakthrough - mg

Test Time - hrs.

Canister Breakthrough

9 psi E0 Fuel - 65 F to 105 F Diurnal

206b - 2002 Nissan Altima

210b - 2004 Chevrolet Impala
SwRI Final Report 03.14936.05 20 of 28 CRC E-77-2b

3.2 Speciation

The project plan included the “speciation” of the evaporative emission results for each of 

the vehicles and test fuels. A sample of the ambient hydrocarbon (HC) concentration in the VTSHED was collected in a TedlarTM bag during each test, and later analyzed for HC species using 

the laboratory’s VarianTM chromatograph, and the “Auto-Oil Test Procedure.” The results of this 

“speciation” allowed the calculation of the average reactivity of the permeate for each of the 

vehicles and fuels. Appendix B contains a full description of ATL’s Speciation Method.

An example of the speciation results is shown in Table 9 below. This table shows just the 

first 25 of 172 hydrocarbons that are identified using the “Auto-Oil” test method, as reported by 

the lab.

TABLE 9. SPECIATION RESULTS – VEHICLE 210b – 72-HOUR DIURNAL TEST

Table 9 shows the “Detailed Hydrocarbon Speciation Results,” listed in the order that 

they appear, or “elute.” Second column is the species name, and the third is the CAS number4

 4

 The CAS number is the Chemical Abstract Service registry number assigned to each specific molecule. CAS 

registry numbers are copyrighted by the American Chemical Society. Redistribution rights for CAS registry 

numbers are reserved by the American Chemical Society. “CAS registry” is a registered trademark of the American 

Chemical Society. The CAS REGISTRY mostly covers substances identified from the scientific literature from 

1957 to the present with some classes (fluorine- and silicon-containing compounds) going back to the early 1900s. 

Each substance in REGISTRY is identified by a unique numeric identifier called a CAS Registry Number.

. 

The “net” values shown are the values after the initial, or time-zero SHED mass values have 

been subtracted.

Detailed Hydrocarbon Speciation Results

Net mass Net conc.

Species Name CAS # (mg) (ppmC) (mg) (ppmC)

1 Methane 00074-82-8 0.000 0.000 0% 0%

2 Ethylene 00074-85-1 0.000 0.000 0% 0%

3 Acetylene (Ethyne) 00074-86-2 0.000 0.000 0% 0%

4 Ethane 00074-84-0 0.000 0.000 0% 0%

5 Propene 00115-07-1 0.000 0.000 0% 0%

6 Propane 00074-98-6 2.567 0.080 0% 0%

7 Allene (Propadiene) 00463-49-0 0.000 0.000 0% 0%

8 Propyne 00074-99-7 0.000 0.000 0% 0%

9 2-Methylpropane 00075-28-5 6.877 0.218 0% 1%

10 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 4.323 0.142 0% 0%

11 1,3-Butadiene 00106-99-0 0.748 0.025 0% 0%

12 n-Butane 00106-97-8 150.105 4.763 11% 12%

13 2,2-Dimethylpropane 00463-82-1 0.000 0.000 0% 0%

14 t-2-Butene 00624-64-6 9.424 0.310 1% 1%

15 1-Butyne 00107-00-6 0.000 0.000 0% 0%

16 c-2-Butene 00590-18-1 6.054 0.199 0% 0%

17 3-Methyl-1-butene 00563-45-1 0.000 0.000 0% 0%

18 2-Methylbutane (Isopentane) 00078-78-4 119.321 3.812 9% 9%

19 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 8.829 0.301 1% 1%

20 2-Methyl-1-butene 00563-46-2 13.520 0.444 1% 1%

21 n-Pentane 00109-66-0 28.890 0.923 2% 2%

22 2-Methyl-1,3-butadiene 00078-79-5 0.535 0.018 0% 0%

23 t-2-Pentene 00646-04-8 27.079 0.890 2% 2%

24 3,3-Dimethyl-1-butene 00558-37-2 0.000 0.000 0% 0%

25 c-2-Pentene 00627-20-3 14.071 0.462 1% 1%

72DHB

% total
SwRI Final Report 03.14936.05 21 of 28 CRC E-77-2b

A more useful presentation is shown in Table 10, where the results have been sorted by 

net mass, bringing the largest mass species to the top. In this case, the largest mass present was 

ethanol, at 221.0 mg, or 16% of the identified mass. The complete data set for the speciations 

can be found in Appendix E.

TABLE 10. MASS SORTED SPECIATION RESULTS – VEHICLE 210b – 72-HOUR

DIURNAL TEST

3.3 Reactivity

Previous E-77 test programs had not included speciation in the test evaluation, and this 

program E-77-2b, was the first that allowed average reactivity to be calculated. EPA along with 

CRC has collected the data in this study to be used in the Motor Vehicle Emissions Simulator

(MOVES) model. EPA handles its estimates of ozone formation in both their rulemakings and in 

State Implementation Plans by air quality modeling. The modeling requires inventories such as 

from MOVES and NONROAD models for HC, CO, NOX and PM. For HC, the exhaust and 

evaporative HC (VOC) emissions are speciated using speciation profiles that break HC down 

into individual chemical constituents. These profiles are typically obtained from an EPA tool 

called SPECIATE (http://www.epa.gov/ttn/chief/software/speciate/index.html). SPECIATE 

generally has over 100 different compounds (paraffins, olefins, alkynes, alcohols, and aldehydes) 

for both exhaust and evaporative emissions. The component hydrocarbons are then used in air 

Detailed Hydrocarbon Speciation Results

Net mass Net conc.

Species Name CAS # (mg) (ppmC) (mg) (ppmC)

Ethanol 00064-17-5 220.954 4.417 16% 11%

12 n-Butane 00106-97-8 150.105 4.763 11% 12%

18 2-Methylbutane (Isopentane) 00078-78-4 119.321 3.812 9% 9%

81 Toluene 00108-88-3 111.734 3.912 8% 10%

40 n-Hexane 00110-54-3 85.020 2.730 6% 7%

36 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 50.765 1.630 4% 4%

38 3-Methylpentane 00096-14-0 37.109 1.191 3% 3%

63 2,2,4-TriMePentane (IsoOctane) 00540-84-1 34.009 1.098 2% 3%

26 2-Methyl-2-butene 00513-35-9 32.366 1.064 2% 3%

21 n-Pentane 00109-66-0 28.890 0.923 2% 2%

53 Benzene 00071-43-2 27.841 0.985 2% 2%

23 t-2-Pentene 00646-04-8 27.079 0.890 2% 2%

49 Methylcyclopentane 00096-37-7 24.806 0.815 2% 2%

56 Cyclohexane 00110-82-7 22.521 0.740 2% 2%

34 2,3-Dimethylbutane 00079-29-8 20.899 0.671 2% 2%

25 c-2-Pentene 00627-20-3 14.071 0.462 1% 1%

57 2-Methylhexane 00591-76-4 14.030 0.452 1% 1%

74 Methylcyclohexane 00108-87-2 13.577 0.446 1% 1%

20 2-Methyl-1-butene 00563-46-2 13.520 0.444 1% 1%

66 n-Heptane 00142-82-5 12.843 0.413 1% 1%

79 2,3,4-Trimethylpentane 00565-75-3 12.580 0.406 1% 1%

59 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 12.194 0.393 1% 1%

50 2,4-Dimethylpentane 00108-08-7 10.867 0.350 1% 1%

14 t-2-Butene 00624-64-6 9.424 0.310 1% 1%

42 t-2-Hexene 04050-45-7 8.954 0.294 1% 1%

72DHB

% total
SwRI Final Report 03.14936.05 22 of 28 CRC E-77-2b

quality models to predict ozone formation. A recent example of this modeling is discussed in the 

Regulatory Impact Analysis for the Renewable Fuels Standards which uses the CMAQ 

(Community Multi-scale Air Quality) model (http://www.epa.gov/AMD/CMAQ/). An example 

of an EPA rulemaking package is the Regulatory Impact Analysis for the recent RFS2 

rulemaking:

“Draft Regulatory Impact Analysis: Changes to Renewable Fuel Standard Program,” EPA420-D-09-001, May 2009, http://www.epa.gov/otaq/renewablefuels/420d09001.pdf.

A more simplified approach to assessing ozone formation potential is use of reactivity 

factors. Hydrocarbons are one of the precursors to the formation of atmospheric ozone. Each of 

the individual species of hydrocarbons in gasoline may have differing reaction rates in the ozoneforming process. In 1994, Dr. William Carter of the University of California published a set of 

“ozone forming potential” factors known as the Maximum Incremental Reactivity (MIR) scale. 

The applicability of these factors is a subject of debate, but ARB has used the Carter Factors in 

their atmospheric predictions. These factors have been updated over the years, and the CY 2008

values used in this analysis were taken from the ARB website at:

http://www.arb.ca.gov/fuels/gasoline/premodel/pmdevelop.htm

The MIR is the ratio of the mass of ozone that would be formed under ideal conditions by 

a similar mass of the Volatile Organic Compound (VOC). For example, one mg of ethanol is 

predicted to form 1.45 mg of ozone. One can estimate the average reactivity of an ambient 

mixture by summing the predicted ozone result for all the identified species, and then dividing by 

the sum of the measured VOC mass. 

A sample chart, using the data from the three-day diurnal on Vehicle 210b is shown in 

Table 11, illustrating how the average reactivity of the various fuels was calculated. Again, the 

various species are sorted by decreasing order of their mass in the measured SHED sample. The 

left column is the species name, with its CAS number at the next right. The Carter factor (MIR) 

is next, and then the mass of the species, as VOC in mg.

The sum of the predicted ozone for this test (Table 11) was 3812.8 mg, from 1298.2 mg 

of VOC. Dividing the total ozone mass by the total VOC mass gives the average reactivity of 

this test of 2.937. The summary of reactivities for all eight vehicles is shown in Tables 12 

through 19.
SwRI Final Report 03.14936.05 23 of 28 CRC E-77-2b

TABLE 11. REACTIVITY RESULTS

Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462

Non Zero Mass Species Sorted By VOC

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 220.95 320.157

n-Butane 00106-97-8 1.08 150.10 161.650

2-Methylbutane (Isopentane) 00078-78-4 1.35 119.32 161.666

Toluene 00108-88-3 3.93 111.73 438.558

n-Hexane 00110-54-3 1.13 85.02 96.470

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 50.76 70.959

3-Methylpentane 00096-14-0 1.69 37.11 62.747

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 34.01 40.781

2-Methyl-2-butene 00513-35-9 14.20 32.37 459.437

n-Pentane 00109-66-0 1.21 28.89 35.099

Benzene 00071-43-2 0.69 27.84 19.331

t-2-Pentene 00646-04-8 10.47 27.08 283.609

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.36 4.244

Unknown #22 . 2.94 0.34 0.989

1-Heptene 00592-76-7 4.29 0.33 1.428

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.94 0.32 0.933

1-Nonene 00124-11-8 2.49 0.32 0.786

Isopropylbenzene (Cumene) 00098-82-8 2.94 0.28 0.835

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.28 1.744

Indan 00496-11-7 3.23 0.27 0.886

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.17 0.186

Total 1298.2 3812.8 2.937

No MIR available, use weighted average of 2.9369
SwRI Final Report 03.14936.05 24 of 28 CRC E-77-2b

TABLE 12. VEHICLE REACTIVITY SUMMARIES

Vehicle 206b

Test Fuel

Test 

No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7456 247.0 100.8 249.1 885.1 3.553 71

Static E10 - 7 psi 7484 279.7 79.6 222.7 796.1 3.575 60

E0 - 9 psi 7539 123.3 99.5 122.8 511.2 4.164 55

E0 - 7 psi 7561 97.3 80.1 78.0 284.8 3.651 56

105° F E10 - 10 psi 7459 630.7 93.1 587.4 2085.4 3.550 86

Static E10 - 7 psi 7487 606.2 125.3 759.4 2686.3 3.538 84

E0 - 9 psi 7545 366.7 72.9 267.3 814.4 3.047 30

E0 - 7 psi 7563 234.6 85.9 201.5 854.3 4.241 30

Dynamic E10 - 10 psi 25753 727.2 87.3 634.7 2191.6 3.453 66

E10 - 7 psi 25760 673.6 90.0 606.0 2158.5 3.562 59

E0 - 9 psi 25775 456.1 76.8 350.1 1316.4 3.760 54

E0 - 7 psi 25780 316.9 78.8 249.7 987.9 3.956 52

DHB E10 - 10 psi 7476 76809.3 82.4 63303.9 148993.1 2.354 123

Total E10 - 7 psi 7495 6985.0 88.6 6189.7 21304.5 3.442 108

E0 - 9 psi 7551 4036.4 91.1 3677.3 11381.0 3.095 107

E0 - 7 psi 7567 2993.3 93.4 2797.0 8687.2 3.106 105

TABLE 13. VEHICLE REACTIVITY SUMMARIES

Vehicle 208b

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7413 75.6 127.7 96.6 413.8 4.284 42

Static E10 - 7 psi 7478 50.5 102.6 51.9 136.0 2.623 40

E0 - 9 psi 7530 74.2 121.3 90.0 287.6 3.195 52

E0 - 7 psi 7568 49.6 102.0 50.6 159.2 3.146 55

105° F E10 - 10 psi 7415 115.2 110.4 127.1 415.6 3.268 59

Static E10 - 7 psi 7480 105.4 104.1 109.7 391.9 3.572 76

E0 - 9 psi 7532 112.7 102.4 115.4 370.1 3.207 60

E0 - 7 psi 7570 123.9 94.4 117.0 403.3 3.448 63

Dynamic E10 - 10 psi 25744 337.0 95.8 322.8 1369.5 4.242 56

E10 - 7 psi 25759 308.3 132.8 409.4 1718.9 4.198 72

E0 - 9 psi 25771 257.5 159.1 409.6 1853.2 4.524 52

E0 - 7 psi 25782 199.7 51.9 103.6 353.6 3.413 40

DHB E10 - 10 psi 7463 1852.2 103.6 1919.2 5628.6 2.933 107

Total E10 - 7 psi 7489 1740.5 89.3 1554.4 5099.2 3.281 107

E0 - 9 psi 7556 1864.6 93.2 1737.6 4606.5 2.651 98

E0 - 7 psi 7575 1317.5 88.6 1167.2 3392.4 2.906 86
SwRI Final Report 03.14936.05 25 of 28 CRC E-77-2b

TABLE 14. VEHICLE REACTIVITY SUMMARIES

Vehicle 209b

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7423 52.1 165.6 86.2 276.2 3.205 63

Static E10 - 7 psi 7466 54.4 130.9 71.2 262.9 3.692 78

E0 - 9 psi 7501 44.8 83.4 37.3 76.3 2.043 19

E0 - 7 psi 7524 38.8 120.5 46.8 161.0 3.441 51

105° F E10 - 10 psi 7424 160.9 117.8 189.4 593.2 3.131 65

Static E10 - 7 psi 7467 102.4 98.8 101.2 340.7 3.368 57

E0 - 9 psi 7504 55.8 86.1 48.1 186.9 3.886 52

E0 - 7 psi 7527 62.4 101.5 63.3 245.8 3.885 50

Dynamic E10 - 10 psi 25742 401.4 111.9 449.1 1629.8 3.629 74

E10 - 7 psi 25755 217.1 85.1 184.7 701.1 3.796 58

E0 - 9 psi 25761 140.9 102.9 145.0 658.3 4.541 45

E0 - 7 psi 25768 166.6 87.9 146.4 543.1 3.708 31

DHB E10 - 10 psi 7461 1434.5 93.8 1345.1 3821.9 2.841 110

Total E10 - 7 psi 7472 1055.7 93.7 989.6 2879.4 2.909 89

E0 - 9 psi 7508 802.6 59.6 478.6 1316.0 2.749 65

E0 - 7 psi 7533 821.9 94.5 776.5 2515.6 3.239 81

TABLE 15. VEHICLE REACTIVITY SUMMARIES

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7449 51.6 89.7 46.3 143.2 3.096 49

Static E10 - 7 psi 7468 63.0 96.2 60.6 186.3 3.072 56

E0 - 9 psi 7523 46.2 121.3 56.1 208.1 3.712 53

E0 - 7 psi 7547 37.5 90.0 33.7 108.4 3.214 40

105° F E10 - 10 psi 7451 147.3 102.1 150.3 473.4 3.150 62

Static E10 - 7 psi 7471 117.5 92.6 108.8 346.6 3.186 69

E0 - 9 psi 7525 69.8 132.1 92.3 296.6 3.215 62

E0 - 7 psi 7549 74.0 104.9 77.6 270.6 3.486 48

Dynamic E10 - 10 psi 25749 198.4 85.9 170.5 569.7 3.342 52

E10 - 7 psi 25756 189.1 100.1 189.2 710.5 3.754 48

E0 - 9 psi 25767 178.0 74.9 133.2 328.8 2.468 41

E0 - 7 psi 25776 234.9 84.5 198.4 848.9 4.278 32

DHB E10 - 10 psi 7462 1386.1 93.7 1298.2 3812.8 2.937 95

Total E10 - 7 psi 7482 1192.5 87.0 1037.4 3101.2 2.989 86

E0 - 9 psi 7531 1143.4 88.3 1010.2 2351.6 2.328 32

E0 - 7 psi 7550 758.3 87.7 665.0 1927.4 2.898 86

Vehicle 210b
SwRI Final Report 03.14936.05 26 of 28 CRC E-77-2b

TABLE 16. VEHICLE REACTIVITY SUMMARIES

TABLE 17. VEHICLE REACTIVITY SUMMARIES

Caution: These measurements include known leaks as well as permeation

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7442 74.9 84.5 63.3 229.3 3.620 59

Static E10 - 7 psi 7464 60.4 77.3 46.7 118.1 2.531 12

E0 - 9 psi 7506 34.8 88.3 30.7 102.3 3.329 41

E0 - 7 psi 7526 40.9 86.2 35.3 104.0 2.947 38

105° F E10 - 10 psi 7446 228.3 105.1 239.8 761.0 3.174 78

Static E10 - 7 psi 7465 159.2 87.2 138.9 440.2 3.169 64

E0 - 9 psi 7507 71.1 82.7 58.8 173.0 2.943 32

E0 - 7 psi 7528 66.8 106.3 71.0 251.7 3.546 50

Dynamic E10 - 10 psi 25750 144.8 124.2 179.8 839.7 4.669 48

E10 - 7 psi 25754 284.5 88.3 251.3 879.7 3.500 60

E0 - 9 psi 25764 191.7 52.9 101.4 314.8 3.105 38

E0 - 7 psi 25769 141.4 69.4 98.1 381.1 3.885 59

DHB E10 - 10 psi 7429 1966.7 101.3 1992.2 5290.8 2.656 92

Total E10 - 7 psi 7473 1769.4 67.1 1187.5 4082.1 3.438 80

E0 - 9 psi 7516 967.5 88.7 858.6 2298.5 2.677 73

E0 - 7 psi 7538 917.6 94.2 864.0 2571.4 2.976 80

Vehicle 213b

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7537 21249.9 91.1 19364.6 45551.4 2.352 87

Static E10 - 7 psi 7564 11657.5 81.0 9442.0 28464.0 3.015 96

E0 - 9 psi 7644 24378.7 96.6 23556.0 50039.7 2.124 93

E0 - 7 psi 7677 14347.6 99.7 14299.8 35390.0 2.475 114

105° F E10 - 10 psi 7541 36851.0 78.1 28779.5 70524.0 2.450 105

Static E10 - 7 psi 7565 24424.1 91.8 22427.0 66555.4 2.968 127

E0 - 9 psi 7647 44422.3 90.3 40098.4 88163.2 2.199 108

E0 - 7 psi 7680 25952.5 105.4 27348.3 68042.1 2.488 120

Dynamic E10 - 10 psi 25774 180.3 74.0 133.5 501.4 3.756 45

E10 - 7 psi 25781 685.5 64.2 440.2 1445.3 3.283 69

E0 - 9 psi 25789 2388.4 99.7 2380.7 6653.4 2.795 55

E0 - 7 psi 25794 3527.7 104.6 3689.9 12792.2 3.467 114

DHB E10 - 10 psi 7546 5251.6 91.5 4805.1 12517.4 2.605 107

Total E10 - 7 psi 7569 4272.9 91.7 3916.7 11477.1 2.930 125

E0 - 9 psi 7657 19668.0 103.4 20327.8 49439.0 2.432 128

E0 - 7 psi 7686 19475.3 103.9 20242.7 51559.2 2.547 134

Vehicle 220b
SwRI Final Report 03.14936.05 27 of 28 CRC E-77-2b

TABLE 18. VEHICLE REACTIVITY SUMMARIES

Caution: These measurements include known leaks as well as permeation

TABLE 19. VEHICLE REACTIVITY SUMMARIES

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7557 1592.1 85.9 1367.1 3249.9 2.377 57

Static E10 - 7 psi 7571 951.42 75.9 722.3 2179.9 3.018 65

E0 - 9 psi 7650 1390.71 89.8 1248.3 2750.8 2.204 66

E0 - 7 psi 7691 979.48 114.5 1121.8 2764.8 2.465 72

105° F E10 - 10 psi 7559 2131.5 92.0 1960.1 4768.7 2.433 79

Static E10 - 7 psi 7572 1354.2 93.7 1268.7 3796.8 2.993 76

E0 - 9 psi 7652 1823.3 100.0 1824.1 3993.6 2.189 66

E0 - 7 psi 7692 1351.9 115.3 1558.2 4073.8 2.614 103

Dynamic E10 - 10 psi 25778 158.8 97.8 155.3 519.8 3.347 54

E10 - 7 psi 25783 144.6 118.7 171.6 578.9 3.373 59

E0 - 9 psi 25790 192.8 161.7 311.8 851.8 2.732 55

E0 - 7 psi 25797 230.2 88.6 204.1 877.0 4.298 49

DHB E10 - 10 psi 7562 2254.5 86.6 1952.6 5269.2 2.699 90

Total E10 - 7 psi 7579 2189.4 85.0 1860.2 5643.5 3.034 104

E0 - 9 psi 7667 1788.4 90.9 1625.8 4353.4 2.678 83

E0 - 7 psi 7716 1593.2 103.2 1644.2 4729.0 2.876 92

Vehicle 221b

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7552 12.2 212.7 26.0 76.7 2.953 21

Static E10 - 7 psi 7576 28.2 95.7 27.0 73.7 2.729 29

E0 - 9 psi 7655 6.4 79.8 5.1 28.5 5.617 10

E0 - 7 psi 7712 7.0 215.7 15.1 59.6 3.957 24

105° F E10 - 10 psi 7554 20.6 163.4 33.7 119.6 3.545 32

Static E10 - 7 psi 7578 28.9 111.3 32.1 134.5 4.189 41

E0 - 9 psi 7659 11.7 180.8 21.2 100.3 4.734 46

E0 - 7 psi 7715 14.0 228.9 32.1 165.4 5.146 43

Dynamic E10 - 10 psi 25779 73.3 30.1 22.1 54.9 2.488 22

E10 - 7 psi 25785 51.6 66.8 34.5 81.1 2.351 21

E0 - 9 psi 25791 33.5 145.1 48.6 231.3 4.759 19

E0 - 7 psi 25808 97.2 72.7 70.6 220.5 3.122 39

DHB E10 - 10 psi 7558 257.2 70.4 181.0 525.8 2.905 68

Total E10 - 7 psi 7580 287.6 93.6 269.1 853.3 3.171 66

E0 - 9 psi 7696 177.2 95.4 169.1 728.2 4.307 64

E0 - 7 psi 7742 136.4 67.5 92.1 286.4 3.111 47

Vehicle 222b
SwRI Final Report 03.14936.05 28 of 28 CRC E-77-2b

3.4 Summary of Findings and Results

The E-77-2b test program was a continuation of the earlier E-77 test program which added 

eight vehicles to be tested on four fuels to increase the size of the knowledge base. The 

permeation trends previously shown were again present. The small sample size and limited 

number of tests preclude making statements about statistical validity, but in general:

• Increasing ethanol content (0% to 10%) increased permeation in the “enhanced” 

vehicles tested. 

• “Near zero” and “zero evap” vehicles were less sensitive (or insensitive) to ethanol 

level. This may be due to the materials used to achieve the lower emission levels, or 

perhaps the limited sample size.

• Increased fuel volatility increased permeation levels for “enhanced” vehicles.

• The lower emitting “near zero” and zero evap” vehicles did not exhibit a clear trend 

with increasing volatility level. Again, this may be due to the materials used for the 

vehicles tested, or the small sample size.

• “Near zero” and “zero evap” vehicles had lower emissions than the “enhanced” 

vehicles.

• The two vehicles identified with “leaks” were not included in the analysis for the 

permeation trends, but were interesting in that they may suggest deterioration with time 

for the vehicles at eight or more years of age.

3.5 Looking Ahead

Additional test work is suggested to increase the knowledge base (particularly concerning 

the newer designs). Since losing two vehicles to leak conditions, the knowledge base contains a 

total of eight “enhanced” vehicles, four “near zero” vehicles and only one “zero evap” vehicle –

hardly enough to make any statistical evaluation of trends. Consideration should be given to 

additional testing.
APPENDIX A

E-77 TEST CONCEPT AND THEORY
A-1

The Test Concept: Measuring Leaks, Permeation and Diurnal Vapor Losses

CRC’s E-77 emission test programs have developed (and strive to continually improve) new 

methodologies for understanding and quantifying vehicle evaporative emission rates. The 

concept partitions and assigns the vehicle’s contribution to the evaporative emission inventory 

into three mechanisms:

1. Permeation

2. Tank vapor venting

3. Leaks (with two subsets - Liquid and Vapor)

Permeation is the migration of HC through the various elastomers in a vehicle fuel system5

Figure A-1. Control System Schematic

. 

Previous testing has shown that permeation rate is strongly affected by the material’s 

temperature, doubling for each 10oC (18oF) increase in the range of normal summer temperatures

(See, among others, CRC Project E-65-3 report.) It is also strongly affected by gasoline 

composition, especially with ethanol-containing fuels.

Tank vapor venting emissions are controlled by fitting a carbon canister to the atmospheric tank 

vent. Figure A1 is a schematic of a typical early control system. During a daily heating period, 

the temperature of the vehicle’s fuel tank increases, forcing HC vapors from the tank. Excess 

emissions, exceeding the carbon canister’s capacity, are vented to the atmosphere. 

 5

 “Fuel Permeation from Automotive Systems: Final Report CRC Project E-65,” Haskew, Liberty and McClement, 

September 2004, available on the CRC and California Air Resources Board websites.
A-2

Leaks can be liquid or vapor. Mass emissions are 

measured in a VT SHED or Variable Temperature 

Sealed Housing for Evaporative Determination. The 

SHED test method combines all three emission 

mechanisms (leaks, diurnal venting, and permeation) 

into a single test result.

The SHED technique involves placing the vehicle in 

a sealed enclosure (Figure A2), and calculating the 

mass in the enclosure from the volume, density and 

concentration in the enclosure at the start and end of a 

time period. The difference between the mass at the 

start and end of test is the emission rate, e.g., grams 

per unit time. 

 

Permeation and tank venting losses are strongly 

driven by fuel composition, ambient temperature, and ambient temperature change. Liquid leaks 

are not strongly affected by normal summer temperatures, and they are thought to have two 

components:

1. Static leaks occurring while the engine is turned off and the vehicle is stationary. 

2. Increase in leak rate caused by the system pressure increase during engine operation.

A Test Method for Separating Permeation from Tank Venting and Leaks – In a previous

CRC Project (E-65), the canister loss was separated from the permeation measurement by 

venting the losses from the carbon canister outside 

the SHED. For Project E-77, the canister vent 

losses were collected and measured in a separate 

“trap canister” on a scale outside the SHED, as 

shown in Figure A3. This vent line was capped 

off, i.e., sealed during the Static Test, but 

connected as shown in the figure for the Dynamic 

and the Diurnal Tests. The ambient temperature 

in the SHED was constant during the static test, 

and there was no vapor created at constant 

temperature. This vent was closed to pressurize 

the system for the leak evaluations. The resulting 

SHED increase in HC mass was permeation6

 6 This is a simplification. There are other HC sources present that are not fuel permeation. These include tire, paint, 

adhesives and vinyl emissions, and the possibility of fuel leaks from the fuel injectors. The authors believe these 

to be a minor component of the emissions measured in this study. 

. 

The last mechanism that needed to be evaluated was leaks. Leaks can be both vapor and liquid. 

A liquid leak can have significant mass, currently undetected by the vehicle’s on-board 

diagnostic system. Considerable thought and effort have gone into the creation of a simple and 

effective liquid leak detection methodology, without success. The techniques used in this project 

Figure A-2. Sealed Housing for 

Evaporative Determination

Figure A-3. Trap Canister
A-3

required the use of a SHED for measurements. The techniques were not simple, but they proved 

effective.

Based on experience, a vehicle’s permeation rate is expected to lie between 4 to 90 mg/hour 

range. The presence of a static liquid leak is expected to overwhelm this value; such a leak 

would (or could) be apparent by inspection. Leaks from the vehicles were quantified in a threestep test process. The first step was to measure the static permeation rate of the vehicle at 86oF. 

The vehicle was allowed to stabilize at 86oF in the SHED and the permeation rate was calculated 

from the mass increase in the SHED. The second part of the test, looking for pressure driven 

leaks in the vapor system, was performed by pressurizing the vehicle’s tank to 5” H2O through a 

special fuel cap and tubing from outside the SHED (Figure A4). The special fuel cap, the hose 

and the pressurization apparatus was installed before the start of the sequence. The HC 

concentration in the SHED was monitored, and the increase in the mass of HC in the SHED was 

compared to the static permeation rate. If there was no (or insignificant) rate of increase, it was 

deduced that no vapor leak is present.

The third and final part of the test was to energize the vehicle’s fuel pump and pressurize the 

system up to and including the injectors (Figure A-5). If there were a pressure leak in the liquid 

system, an increase in the SHED mass over time would be seen, i.e., the leak would be additive 

to the permeation rate. 

Figure A-4. Static Test – Tank 
A-4

Figure A-5. Static Test – Fuel Pump Energized

Other Tests (Dynamic, Hot Soak, and Diurnal) - A similar configuration is used to isolate the 

tank venting losses from the permeation measurements determined by other test procedures. The 

vehicle’s canister vent is connected with a low permeation hose (TeflonTM) to a bulk-head fitting 

in the SHED wall and then to a separate “trap canister” on a top-loading scale. Any HC 

emissions that escape from the vehicle’s canister are captured in the trap canister, and measured 

at a 0.01 g (10 milligram) precision. The trap canister (a 1 Liter Ford model) is periodically 

purged and maintained at a “dry” condition so that it captures all of the vehicle’s escaping 

emissions. This assumption is probably violated during the high volatility tests where there are 

30 grams of daily emissions, but this is not a concern at this time.

Test Elements for E-77-2 - The following flowchart (Figure A-6) displays the various elements 

utilized during the testing of the various vehicles and fuels during this program. Details of each 

of the four basic tests follow the flow chart.
A-5

Drain and 40% Fill

with 10 psi E10 Test Fuel

Road Preconditioning

Four LA-4’s or Equivalent

Drain and 40% Fill

with 10psi E10 Test Fuel

Overnight Park at 86°F

Move to SHED

Connect Test Instrumentation

Stabilize at 86°F

Perform Constant Temperature 

Permeation Series (86°F)

1 hour Permeation Rate Test

1⁄2 hour Tank Pressurized Test

1⁄2 hour Pump Energized Test

Transfer to RL SHED

Connect Test Instrumentation

Stabilize at 86°F

Perform Dynamic Permeation Test

Two LA92 Driving Cycles &

One Hour Hot Soak

Drain and 40% Fill

With 10 psi E10 Test Fuel

Road Preconditioning

Four LA-4’s or Equivalent

Move to VT-SHED

Connect Test Instrumentation

Stabilize at 65°F for 6 hrs. Minimum 

Perform 3-Day Diurnal Evaluation

72 hr 65° to 105°F VT Test

Drain and 40% Fill

with 7 psi E10 Test Fuel

Condition Fuel System

By Driving for One Day

Repeat Steps 1 – 12

On 7 psi E10 Test Fuel

Drain and Fill with 9 psi E0 Test Fuel

Condition Fuel System by 4 weeks Driving

Repeat Steps 1 – 12

On 9 and 7 psi E0 

Precondition Fuel System

With 4 Weeks Driving on

10 psi E10 Test Fuel

1

2

3

4

5

6

7

8

9

10

11

12

Figure A-6. Testing Flow Chart
APPENDIX B

TEST PROCEDURES
B-1

Test Procedures – There are four basic tests in the E-77-2 test protocol.

1. Static Permeation Rate (Includes checks for vapor and liquid leaks)

2. Running Emissions (Dynamic Test)

3. Hot Soak

4. Diurnal

Each is described in detail below.

1. Static Permeation Testing

The constant temperature (static) permeation rate is measured in a traditional SHED (constant 

temperature) in the following manner.

A. The fuel tank is drained and filled to 40% tank capacity with the test fuel.

B. The day before testing, the vehicle is driven over four road trips of 7.5 miles each 

to precondition the canister.

7

C. Upon return from the road pre-conditioning, the fuel tank is drained and filled to 

40% tank capacity with the test fuel.

(These drives are similar to the LA-4.)

8

D. Vehicle is parked for 18-22 hours in a controlled temperature environment at test 

temperature (86oF).

E. The vehicle is then moved (without starting) into the test (86oF) SHED.

F. The canister vent is connected to the SHED bulkhead fitting which routes the 

vapor to the trap canister outside the SHED.

G. The tank system pressurization hose is connected.

H. The fuel pump electrical connection is connected.

I. The SHED is sealed, the inside temperature is allowed to stabilize and the test is 

started. Continuous total hydrocarbon (THC) measurements are made using a 

FID. Ethanol, methanol and R134a concentrations are measured using an

INNOVA analyzer. All measurements are made at least every minute for one 

hour to determine the stabilized permeation rate.

J. At the end of the static test (60 minutes), the vehicle’s vapor system is pressurized 

to 5 inches of water for thirty minutes. Measurements are made to quantify vapor 

leaks as determined by a change in the SHED uncorrected mass.

K. The fuel pump is then energized for 30 minutes while maintaining the 5 inches of 

water on the vapor system. Liquid leaks are quantified as determined by a change 

in the SHED concentrations.

The purpose of steps J and K above is to validate that the permeation rate measurement was 

made without the presence of any leak – either liquid or vapor. 

 7

 This conditioning can be done in the laboratory on a chassis dynamometer if proper attention is paid to underbody 

cooling and unrepresentative fuel tank temperatures are avoided.

8

 Vehicles with ORVR systems will add the refueling vapors to the canister. This is OK.
B-2

2. Running Loss Test (Dynamic Test)

A. The vehicle is placed in the RL-SHED and prepared for test. (The fuel level and 

condition for the dynamic test is the fuel remaining after completion of the static test –

40% fresh fill of the appropriate test fuel.)

B. Outside air source for the engine is connected.

C. Vehicle exhaust is connected. 

D. Fuel tank thermocouple is connected.

E. Canister vent is connected to the SHED bulkhead fitting which routes the vapor to the 

trap canister outside the SHED.

F. Vehicle is allowed to stabilize in the RL-SHED at test temperature (86°F) for a minimum 

of 12 hours – preferably overnight.

G. Two cycles of the Unified Cycle (LA-92) driving schedule (48 min.) are driven while 

measuring the mass emissions in the SHED. Vehicle is allowed to idle (in drive) for 30 

seconds between the two cycles. Ambient air temperature is maintained (to the extent 

possible) at 86°F. Fuel tank surface temperature is monitored during vehicle operation. It 

should increase during the drive from 10 to 18°F to simulate expected on-road 

temperature increase. Measured mass emissions are corrected using the INNOVA data 

for the ethanol, methanol and refrigerant emissions.

3. Hot Soak9

A. Engine is turned off, transmission selector is placed in park, and driver exits the 

enclosure, using the double door air lock, taking care to minimize any air exchange 

between the laboratory and the SHED. This starts the one hour “hot soak” period.

This procedure is executed immediately following the Running Loss Test procedure 

described above.

B. Measurement of mass emissions in the SHED are continued for another 60 minutes (until 

time = 108 minutes), correcting for the ethanol, methanol and refrigerant mass using the 

INNOVA instrument data. This ends the hot soak. Hot soak emissions are calculated as 

the net difference for the one hour hot soak (CorrMass108 – CorrMass48 minus the 86°F 

static hourly rate, all mass rates in mg/hour). 

4. Diurnal Test

A. The fuel tank is drained and filled to 40% tank capacity with the test fuel.

B. The day before testing, the vehicle is to be driven over four road trips of 7.5 miles each to 

precondition the vehicle and the canister.

C. Upon return from the road pre-conditioning, the fuel tank is drained and filled to 40% 

tank capacity with the test fuel.

D. The vehicle is parked for 18-22 hours in a controlled temperature environment at the 

initial diurnal test temperature (65oF).

E. The SHED is sealed, allowed to stabilize at the 65°F temperature and the 3-day 

California Diurnal Test is started. 

F. “Continuous” (every 30 seconds) total hydrocarbon measurements are made using a 

Flame Ionization Detector (FID). Ethanol, methanol and R134a (refrigerant) 

 9

 As defined here, the “hot soak” is the temporary increase in emission rate caused by the vehicle’s immediately 

preceding operation. It is the increase in the SHED mass (corrected for EtOH, MeOH and R-134a) over the one 

hour period minus the previously established “static” permeation rate.
B-3

concentrations are measured using an INNOVA analyzer, at least every 10 minutes for 

the duration of the test (72 hours).

Static Permeation Test – Leak Validation 

If a leak is detected during either the vapor system pressure portion (Step J) or the pump 

energized portion (Step K) of the Static Permeation Test procedure, it calls into question whether 

the permeation rate measurement accurately reflects fuel system permeation or if instead a 

combination of permeation and the implied leak was measured. If a leak is confirmed, the 

permeation rate measurement is called into question, and an investigation, possible remedy, and 

retest is indicated.

The permeation rate measurement must be corrected for the FID’s ethanol misrepresentation, and 

the presence of non-fuel HC (methanol and refrigerant). The leak check, however, is made using 

the change in mass increase in the SHED using the uncorrected FID mass calculation as the 

determinate. The corrections for ethanol, methanol and refrigerant were found to be introducing 

“noise” into the trace that was being misinterpreted as leak(s). 

Figure A-7 above represents the calculations made during the inspection of data from a 

successful test. EXCEL’s© “SLOPE” function is used to calculate the linear regression values 

based on the FID calculation for mass for: Time 0 to 60 minutes, Time 64 to 90 minutes, and 

Time 94 to 120 minutes. A four- minute gap was included between each sequence to establish 

the new mass emission rate during the “pressure on,” (T60 to T90), and the “pump energized” 

periods.

The slope of 0.47 for the “Tank Pressurized” period in the example above is compared to the 

slope of 0.62 calculated for the permeation rate (or hot soak) period. Since the “Tank 

Pressurized” slope is not more than 10% higher than the hot soak permeation rate, it is assumed 

y = 0.62x - 1.9

y = 0.47x + 6.7

y = 0.55x - 0.1

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

SHED Mass - mg

Test Time - minutes

Leak Test

Vehicle 204 - 1999 Honda Accord - 9 psi E0

Test 7028

Tank Pressurized Pump Activated

Figure A-7. Leak Test
B-4

that there is no leak present. A similar comparison is made for the slope determined during the 

“pump on” period. The choice of a 10% allowance is arbitrary and is used here to allow for 

normal and unavoidable test variation.

For tests in which the above procedure determines that no leak is present, a value of zero is 

reported in the test summary for the leak results. If a positive value is reported, it calls that test 

into question, and an investigation, possible repair, and retest is indicated.

Static Permeation Rate Determination

The static permeation rate is determined based on a linear regression through the individual data 

points (30 second data) corrected fuel results from the first 60 minutes of testing, as illustrated in 

Figure A-8.

In this example, the static permeation rate is 33.8 mg/hr.

Dynamic (Running Loss) and Hot Soak Test

The preceding section addressed the concepts of separating the permeation emissions from the 

tank venting emissions, and establishing the presence or absence of leaks. The second part of 

this study includes a dynamic test to measure the permeation and tank venting emissions during 

vehicle operation (“running losses”) and the temporary condition following vehicle operation 

known as the “hot soak.”

This is considered a “dynamic” test because the vehicle is driven and the fuel and vapor system 

temperatures rise during the test. The ambient temperature in the Running Loss SHED during 

y = 0.5636x + 0.505

0

5

10

15

20

25

30

35

40

45

0 10 20 30 40 50 60

Permeation - mgs.

Test Time - mins.

Static Permeation Determination

Vehicle 204 - 1999 Honda Accord - 9 psi E0 Fuel

Raw SHED 

Corrected Fuel

Permeation Rate Based on Corrected Results

Permeation Rate = .5636 x Time = 33.8 mgs/hr

Figure A-8. Static Permeation Determination
B-5

test was held constant at 86°F, while the vehicle’s fuel system temperature rose during the test. 

Two 1435 second (23.9-minute) LA-92 driving cycles were performed consecutively during the 

running loss measurements with a 30-second idle in between. During this test, tank fuel 

temperature was expected to rise by an average approximately 18°F above the initial ambient 

temperature. The running loss air handling system included a proportional speed under-car 

blower operated as a slave to dynamometer speed. This apparatus was used during running loss 

testing with minor tuning for specific vehicles. It is capable of reasonable fuel tank temperature 

control without additional input. Each vehicle was fitted with a surface-mount thermocouple at 

the front of the fuel tank, located at approximately the 1/8th fill level to measure the fuel liquid 

temperature. No attempt was made to follow a predefined fuel tank temperature profile (FTTP) 

in this program. Fuel temperatures were recorded, and results are available in the real-time 

records. 

Vehicle running loss emissions are measured in a special version of a SHED known as a 

Running Loss SHED (RL-SHED), shown in Figure A-9. Special features of the RL-SHED 

include a sealed chassis dynamometer for simulating vehicle driving loads, a sealed outside air 

supply for engine intake, a sealed exhaust conduit for engine exhaust, and an under-chassis fan 

for simulating underbody air flow as described above. A vehicle is operated inside the RL-SHED 

over a chosen driving cycle. The increase in HC emissions inside the enclosure are measured 

and calculated as mass emissions per 40 CFR §86.163-96. Vehicle testing in an RL-SHED is 

complicated by several factors, including:

1. The engine must be supplied with external induction air.

2. The exhaust must be conducted externally without any leaks.

3. The load supplied to the vehicle through the chassis dynamometer must not create or 

allow external leaks.

4. The internal SHED temperature must be maintained while sizable heat is rejected to 

the ambient by the running engine and exhaust.

Figure A-9. Running Loss SHED
B-6

5. The cooling air supplied to the radiator must be modulated to represent the vehicle’s 

road speed.

6. The underbody (and especially the fuel system) temperature should represent the rate 

of rise experienced by a real road-drive.

Canister vent losses were isolated from permeation emissions using the technique described 

previously. The vehicle’s carbon canister fresh air vent was connected to the outside of the RLSHED using a leak-tight Teflon® hose connected to a small carbon “trap” canister located on a 

top-loading precision scale. The scale precision was 0.01 grams (10 milligrams). There were no 

tank venting emissions measured on any of the running loss test measurements. All of the 

vehicles appeared to be actively “purging” the vehicle’s control canister and drawing fresh air 

during the test. If there were any emissions from the vehicle’s canister, as might have occurred 

if there were no vehicle purge or if very high volatility fuels with excessive vapor generation 

were used, it would have been measured.

The Running Loss Driving Cycle consisted of two cycles of the “Unified Driving Cycle,” 

otherwise known as the LA-92. A velocity versus time plot for one cycle is shown in Figure A10.

The LA-92 cycle takes 24 minutes to complete, and covers 9.8 miles, with many speed changes. 

Two back-to-back cycles were driven, the first as a “cold start,” and the second following a 30 

second vehicle idle. The “cold start” condition was created by soaking the vehicle for a 

minimum of 18 hours at 86°F, moving it to the stabilized 86°F RL-SHED, making the test 

connections, and then waiting a minimum of one hour before the initial start and run.

The SHED emissions were measured during the 48 minutes of engine operation, and then 

continuously for one hour after the engine was turned off. This one hour, engine-off duration 

was the “hot soak” period. The total test time is 1 hour and 48 minutes.

Figure A-10. Running Loss Driving Cycle

Unified Cycle (LA-92)

0

10

20

30

40

50

60

70

80

0 5 10 15 20 25

Test Time - minutes

Speed - mph

Cycle Time (min) 23.9

Maximum Speed (mph) 67.2

Average Speed (mph) 24.6

Average Non-Zero Speed (mph) 29.4

Time @ Zero Speed (%) 16.2

Distance (miles) 9.82
B-7

Figure A-11 shows results from the 9 psi E0 fuel test on Vehicle 204. The horizontal axis is test 

time in minutes, and the vertical axis is the HC mass measured in the RL-SHED during the test 

period. 

The engine was shut off at the end of the second LA92 drive cycle (~48 minutes), and the 

analysis system continued to measure the HC emissions in the SHED for the next 60 minutes. 

This represented the “hot soak” portion of the test. 

The “True” Hot Soak

The traditional hot soak is determined from the increase in SHED emissions as measured for one 

hour following a prescribed drive to heat up the vehicle (2 LA-92 cycles during the Running 

Loss Test). Hot soak emissions, however, have two components: that caused by the elevated 

temperature resulting from the drive, and that resulting from one hour of static permeation.

To separate these two components and determine the “true” hot soak emissions, the following 

procedure was used. “Traditional” hot soak emissions were first calculated by subtracting the 

“start of hot soak” cumulative SHED HC value (i.e., 199 mg @ t = 48 minutes) from the final 

cumulative SHED HC value (i.e., 277.4 mg @ t = 108 min.). This resulted in a cumulative 

SHED HC value of 78 mg for the 1 hour hot soak. The previously determined static permeation 

value (i.e., 33.8 mg for a 1 hour hot soak test- see Figure A-8) was then subtracted to arrive at the 

“true” hot soak value of 44.2 mg. 

In Figure A-11, the static permeation rate is superimposed as a solid blue line on the plot from 

the starting point of the hot soak until its end (one hour). While the “traditional” hot soak would 

0

50

100

150

200

250

300

0 20 40 60 80 100 120

Corrected Total Fuel Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 204 - 1999 Honda Accord - 9 psi E0 Fuel

Test 25668

Running Loss Hot Soak

Running Loss Std. =0.05 g/mi

This Test = 0.010 g/mi



RL = 249 mg/hr

277.4

233.2

Tru HS = 44.2

199.0 

Figure A-11. Running Loss Test 
B-8

be calculated as 78 mg (277 mg – 199 mg), the “true” hot soak is determined as 44.2 mg (277.4 

mg - 233.2 mg). True hot soak values reported here were determined in this manner.

Diurnal Test

Diurnal permeation was determined by subjecting the vehicle to a three-day period in a 

temperature-controlled SHED while continuously recording the total HC every 30 seconds. The 

SHED environmental temperature was varied from 65°F to 105°F per the California Diurnal Test 

protocol. Canister vent losses were isolated from permeation emissions using the technique 

described previously. The vehicle’s carbon canister fresh air vent was connected to the outside 

of the RL-SHED using a leak-tight Teflon® hose connected to a small carbon “trap” canister 

located on a top-loading precision scale. The scale precision was 0.01 grams (10 milligrams). 

ATL’s Speciation Method

ATL has developed a hydrocarbon speciation method that is functionally equivalent to 

the dual-gas chromatograph (GC) AQIRP method. The AQIRP, or “Auto/Oil Program,” test 

method was first documented in two SAE papers,

1. SAE 920320, Advanced Emission Speciation Methodologies for the Auto/Oil Air Quality 

Improvement Research Program -I. Hydrocarbons and Ethers; and 

2. SAE 920321, Advanced Emissions Speciation Methodologies for the Auto/Oil Air 

Quality Improvement Research Program – II. Aldehydes, Ketones, and Alcohols

A later update to the HC and Oxygenates procedures was published as:

SAE 930142, Improved Emissions Speciation Methodology for Phase II of the Auto/Oil 

Air Quality Improvement Research Program--Hydrocarbons and Oxygenates

(See also, for reference, ARB’s SOP NO. MLD 115, “Procedure for the Determination of Ethers 

and Alcohols in Gasoline by Gas Chromatography”, January 2003, and SOP NO. MLD 118, 

“Procedures for the Detailed Hydrocarbon Analysis of Gasolines by Single Column High 

Efficiency (Capillary) Column Gas Chromatography”, August 1997).

Instrumentation demands are simplified, and overall analysis time is shortened; yet high 

resolution and sensitivity are still achieved. In this single-GC/dual column method, all 

components are separated using on column type and temperature program. Analysis time for a 

cycle is 65 minutes. Each exhaust or evaporative gas sample is simultaneously injected (using a 

single sampling from the bag) into two identical columns present in the GC. A Varian Model 

3400 GC is used for HC analysis. The GC is equipped with a dual temperature-controlled Valco 

6-port valve injector; dual flame ionization detectors (FID), and dual 60 meter x 0.32-mm ID 

fused silica capillary columns with 1.0μ polydimethylsiloxane stationary phase (J&W DB-1). 

One of the injectors uses an 85 μL sampling loop for low sensitivity analysis of C1-C12 while the 

other injector either uses a 1000 μL loop for high sensitivity analysis of C4-C12 (for simultaneous 

low/high sensitivity analysis of a single bag sample). Column A contains an 85μl sample loop 

(splitless injection) that provides an injection volume that is small enough to allow resolution of 

the C1 through C4 hydrocarbons while large enough to retain the highest sensitivity possible. 
B-9

Column B receives a 1000μl splitless injection, providing higher sensitivity for components 

eluting after isobutane. Quantitative comparison of two overlap components (butane and 

isopentane) provides a quality control measure. Data from Column A is used to detect and 

quantitate the 12 earliest eluting hydrocarbons with detection limits of 15-25 ppbvC 

corresponding to 0.2-0.3 mg/mi hydrocarbon for FTP stages 1 and 3, and 0.3-0.5 mg/mi for FTP 

stage 2. Data from Column B gives detection limits 0.017-0.04 mg/mi HC for components 

eluting after isopentane (18th in elution order). The components eluting between the 9th and 18th

in elution order have detection limits ranging between the levels listed above for each column.

The advantage of this approach is that, even for relatively clean vehicles, essentially all of the 

first 12 species are typically present at levels exceeding the Column A detection limit. Those 

speciated components that are below the first column detection limit tend to be in the molecular 

weight range best suited for the 1000μl injection analysis, which provides the limits 0.017-0.04 

mg/mi HC for components eluting after isopentane (18th in elution order), where additional 

sensitivity is needed. In previous work that applied this analysis approach, detection limits were 

determined to be between 0.02-0.06 mg/mi for the toxics 1,3-butadiene and benzene.

ATL’s hydrocarbon method uses Varian 3600 GCs with dual injectors, columns, and flame 

ionization detectors, allowing two similar analyses to be run simultaneously, as mentioned 

above. A Varian Star PC-based (using Microsoft WindowsTM) data system is used for data 

acquisition. Custom-made software is used for peak identification and converting data into a 

Microsoft ExcelTM spreadsheet format. A comparison of the total hydrocarbon determined using 

the GC versus the CVS (“speciation recovery”) is used as a quality control measure, and ATL 

routinely achieves hydrocarbon speciation recoveries ranging from 93% to 105% for lower 

emitting vehicles. A 23 hydrocarbon component standard mixture is analyzed at the start of each 

day on each GC to provide quantifying coefficients and a quality control check on daily 

reproducibility of instrument performance.
APPENDIX C

FUEL INSPECTIONS
C-1

TABLE C-2. CRC E-77-2b FUEL INSPECTIONS

E0 E10

Inspection Units Fuel 6 Fuel 7

API Gravity °API 60.2 58.5

Relative Density 60/60°F 0.7381 0.7447

DVPE psi 6.95 7.30

Oxygenates--D4815

MTBE vol % 0.00 0.00

ETBE vol % 0.00 0.00

EtOH vol % 0.00 9.54

O2 wt % 0.00 3.53

Hydrocarbon Composition

 Aromatics vol % 22.1 24.4

 Olefins vol % 8.0 8.8

 Saturates vol % 70.0 57.3

D86 Distillation

 IBP °F 99.9 104.0

 5% Evaporated °F 131.9 128.0

 10% Evaporated °F 142.4 133.0

 20% Evaporated °F 156.5 141.0

 30% Evaporated °F 170.6 145.0

 40% Evaporated °F 184.3 153.0

 50% Evaporated °F 197.9 195.0

 60% Evaporated °F 212.4 219.0

 70% Evaporated °F 231.1 241.0

 80% Evaporated °F 259.4 271.0

 90% Evaporated °F 313.6 317.0

 95% Evaporated °F 331.7 330.0

 EP °F 361.0 360.0

Recovery vol % 97.8 97.8

Residue vol % 1.3 1.0

Loss vol % 1.0 1.2

Driveability Index 1120.7 1101.5

CRC E-77-2b Fuel Inspections

Data from CRC E-74
C-2

TABLE C-2 (CONT'D). CRC E-77-2b FUEL INSPECTIONS

Fuel Units Fuel 6 Fuel 7

Sulfur Content ppm 29 27

Estimated C/H Ratio 6.2090 6.3323

Est. Net Heat of Combustion btu/lb 18573 18514

Benzene vol % 0.90 1.00

Research Octane Number 93.2 94.0

Motor Octane Number 83.8 83.8

(R+M)/2 88.5 88.9

Fuel Units Fuel 6 Fuel 7

Aromatics vol % 23.86 24.81

Olefins vol % 7.52 8.92

Saturates vol % 67.43 56.21

Unclassified vol % 1.15 0.86

Ethanol vol % 0.00 9.20

Benzene vol % 0.89 1.06

C/H Ratio 6.200 6.092

Oxygen wt. % 0.008 1 3.40

Net Heat of Combustion btu/lb 18,703 18,016

1

 Contains 0.04 vol % MTBE

Fuel Units Fuel 6 Fuel 7

Oxygen wt. % 0.008 3.396

C+H wt. % 99.99 96.60

H wt. % 13.89 13.62

C wt. % 86.10 82.98

Fuel Units 6 7

Haltermann D3338 Btu/lb 18,573 18,514

Average D3338 Btu/lb 18,578 18,514

Oxygen Corrected D3338 Btu/lb 18,578 17,860

DHA Btu/lb 18,703 18,016

Carbon, Hydrogen, and Oxygen

Net Heat of Combusion -- Btu/lb

Suppliers Additional Inspections

Detailed Hydrocarbon Analysis
APPENDIX D

SUMMARY OF E-77-2B PROGRAM TEST RESULTS AND

INDIVIDUAL VEHICLE EVAPORATIVE TEST RESULTS
D-1

TABLE D-1. CRC E-77-2b PROGRAM TEST RESULTS

Vehicle Day 1 Day 2 Day 3

No. Fuel 86o F Leaks 105o F Leaks RL TEFVO Perm (Brkthru) Perm (Brkthru) Perm (Brkthru)

E10 - 10 psi 124.9 0.0 314.1 0.0 546.5 165.1 2777 (20.0) 31005 (14.7) 43028 (8.6)

E10 - 7 psi 149.3 0.0 307.9 0.0 436.7 174.9 2582.6 (0.0) 2258.5 (0.0) 2144.0 (1.87)

E0 - 9 psi 61.1 0.0 178.8 0.0 365.6 102.5 1500.0 (0.0) 1285.6 (14.6) 1250.8 (30.7)

E0 - 7 psi 52.0 0.0 118.1 0.0 245.1 68.8 1171.9 (0.0) 931.2 (0.0) 890.3 (1.3)

E10 - 10 psi 37.5 0.0 61.2 0.0 329.5 36.0 794.0 (0.0) 561.4 (5.1) 495.8 (21.7)

E10 - 7 psi 27.2 0.0 51.8 0.0 254.7 77.3 780.6 (0.0) 510.4 (0.0) 449.4 (0.0)

E0 - 9 psi 37.2 0.0 55.0 9.1 228.0 37.9 777.0 (0.0) 567.2 (0.0) 519.4 (0.0)

E0 - 7 psi 24.8 0.0 64.5 0.0 124.9 75.0 422.1 (11.3) 419.4 (9.7) 476.0 (9.2)

E10 - 10 psi 28.8 0.0 73.3 0.0 323.6 113.7 535.5 (0.0) 423.5 (0.0) 475.5 (13.0)

E10 - 7 psi 28.6 0.0 54.1 0.0 205.7 24.5 383.1 (0.0) 349.1 (0.0) 323.5 (0.0)

E0 - 9 psi 23.4 5.8 29.5 0.0 144.4 5.0 327.8 (0.0) 250.5 (0.0) 224.3 (0.0)

E0 - 7 psi 16.8 1.9/7.9 28.8 0.0 166.2 16.8 354.1 (0.0) 249.7 (0.0) 218.1 (0.0)

E10 - 10 psi 19.9 0.0 70.1 34.1 147.5 60.6 486.5 (8.0) 458.3 (28.3) 441.3 (34.8)

E10 - 7 psi 29.9 0.0 51.9 23.2 218.3 61.8 445.1 (0.0) 388.3 (0.0) 359.1 (0.0)

E0 - 9 psi 21.2 4.0 33.5 4.8 171.1 19.8 407.8 (0.0) 377.4 (0.0) 358.3 (30.9)

E0 - 7 psi 18.7 0.0 35.5 0.0 216.0 49.0 270.6 (0.0) 266.6 (0.0) 221.1 (0.1)

E10 - 10 psi 39.2 0.0 106.8 0.0 130.9 0.9 650.6 (0.0) 615.4 (0.0) 700.7 (1.6)

E10 - 7 psi 29.6 0.0 82.2 0.0 243.1 60.5 602.8 (0.0) 577.7 (0.0) 588.9 (0.0)

E0 - 9 psi 14.7 0.0 34.5 0.0 203.1 14.5 346.3 (0.0) 328.4 (0.0) 292.8 (0.0)

E0 - 7 psi 21.1 0.0 35.3 0.0 135.1 12.2 357.8 (0.0) 283.3 (0.0) 276.5 (0.0)

E10 - 10 psi 3.7 0.0 7.4 8.3 73.1 0.0 104.1 (1.7) 79.7 (16.0) 73.4 (30.2)

E10 - 7 psi 12.1 0.0 16.3 0.0 67.1 0.0 99.6 (0.0) 104.0 (0.0) 84.0 (0.0)

E0 - 9 psi 3.1 0.0 5.8 0.0 45.5 0.0 77.4 (0.0) 41.9 (0.0) 57.9 (0.0)

E0 - 7 psi 3.4 0.0 6.4 0.0 128.8 5.4 58.6 (0.0) 39.0 (0.0) 38.8 (0.0)

Tier 1 Vapor Leak

Near Zero Liquid Leak

Zero Evap

206b

2002

Nisan

Altima

208b

2002

Chevrolet

Trailblazer

209b

2004

Chrysler

Stratus

210b

2004

Chevrolet

Impala

213b

2004

Dodge

Ram 1500

222b

2004

Ford

Focus

 

Diurnal (65o to 105o) - mg/day

Static Permeation - mg/hr Dynamic Perm. - mg/hr
D-2

Individual Vehicle Evaporative Performance on the Various Fuels

Vehicle 206b – 2002 Nissan Altima

SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

206b 10.0/E10 Static (86) Perm 01/28/09 7456 124.9 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 01/29/09 7459 314.1 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 01/30/09 25753 546.5 0.00

TEFVO 165.1 10.59

72 DHB 65-105 03/03/09 7476

Day 1 2776.6 20.00

Day 2 31004.6 14.70

Day 3 43028.2 8.60

7.0/E10 Static (86) Perm 03/11/09 7484 149.3 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 03/12/09 7487 307.9 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 03/13/09 25760 436.7 0.00

TEFVO 174.9 0.31

72 DHB 65-105 03/24/09 7495

Day 1 2582.6 0.00

Day 2 2258.5 0.00

Day 3 2144.0 1.87

9.0/E0 Static (86) Perm 05/06/09 7539 61.1 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 05/07/09 7545 178.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 05/08/09 25775 365.6 0.00

TEFVO 102.5 0.00

72 DHB 65-105 05/19/09 7551

Day 1 1500.0 0.00

Day 2 1285.6 14.60

Day 3 1250.8 30.70
D-3

7.0/E0 Static (86) Perm 06/02/09 7561 52.0 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 06/03/09 7563 118.1 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 06/04/09 25780 245.1 0.00

"True" HS 68.8 0.13

72 DHB 65-105 06/09/09 7567

Day 1 1171.9 0.00

Day 2 931.2 0.00

Day 3 890.3 1.30
D-4

Vehicle 206b – 2002 Nissan Altima

0

50

100

150

200

250

300

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 206b - 2002 Nissan Altima

10 psi E10 - 7456

7 psi E10 - 7484

9 psi E0 - 7539

7 psi E0 - 7561

0

100

200

300

400

500

600

700

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 206b - 2002 Nissan Altima

10 psi E10 - 7459

7 psi E10 - 7487

9 psi E0 - 7545

7 psi E0 - 7563
D-5

Vehicle 206b – 2002 Nissan Altima (cont.)

0

100

200

300

400

500

600

700

800

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 206b - 2002 Nissan Altima

10 psi E10 - 25753

7 psi E10 - 25760

9 psi E0 -7545

7 psi E0

Running Loss Hot Soak

0

10000

20000

30000

40000

50000

60000

70000

80000

90000

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 206b - 2002 Nissan Altima

10 psi E10 - 7476

7 psi E10 - 7495

9 psi E0 - 7551

7 psi E0 - 7567
D-6

Vehicle 208b – 2002 Chevrolet Trailblazer

SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

208b 10.0/E10 Static (86) Perm 12/18/08 7413 37.5 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 12/19/08 7415 61.2 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 01/16/09 25744 329.5 0.00

TEFVO 36.0 0.00

72 DHB 65-105 02/10/09 7463

Day 1 795.0 0.00

Day 2 561.4 5.10

Day 3 495.8 21.70

7.0/E10 Static (86) Perm 03/04/09 7478 27.2 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 03/05/09 7480 51.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 03/06/09 25759 254.7 0.00

TEFVO 77.3 0.00

72 DHB 65-105 03/17/09 7489

Day 1 780.6 0.00

Day 2 510.4 0.00

Day 3 449.4 0.00

9.0/E0 Static (86) Perm 04/28/09 7530 37.2 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 04/29/09 7532 55.0 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 9.1

Dynamic RL 05/01/09 25771 228.0 0.00

TEFVO 37.9 0.00

72 DHB 65-105 05/27/09 7556

Day 1 778.0 0.00

Day 2 567.2 0.00

Day 3 519.4 0.00
D-7

7.0/E0 Static (86) Perm 06/09/09 7568 24.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 06/10/09 7570 64.5 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 06/11/09 25782 124.9 0.00

TEFVO 75.0 0.00

72 DHB 65-105 06/16/09 7575

Day 1 422.1 11.30

Day 2 419.4 9.70

Day 3 476.0 9.20
D-8

Vehicle 208b – 2002 Chevrolet Trailblazer

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 208b - 2002 Chevrolet Trailblazer

10 psi E10 - 7413

7 psi E10 - 7578

9 psi E0 - 7530

7 psi E0 - 7568

0

20

40

60

80

100

120

140

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 208b - 2002 Chevrolet Trailblazer

10 psi E10 - 7415

7 psi E10 - 7480

9 psi E0 - 7532

7 psi E0 - 7570
D-9

Vehicle 208b – 2002 Chevrolet Trailblazer (cont.)

0

50

100

150

200

250

300

350

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 208b - 2002 Chevrolet Trailblazer

10 psi E10 - 25744

7 psi E10 - 25759

9 psi E0 - 25771

7 psi E0 - 25782

Running Loss Hot Soak

0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 208b - 2002 Chevrolet Trailblazer

10 psi E10 - 7463

7 psi E10 - 7489

9 psi E0 - 7556

7 psi E0 - 7575
D-10

Vehicle 209b – 2004 Chrysler Stratus

SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

209b 10.0/E10 Static (86) Perm 12/30/08 7423 28.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 12/31/08 7424 73.3 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 01/08/09 25742 323.6 0.00

TEFVO 113.7 0.00

72 DHB 65-105 02/03/09 7461

Day 1 535.5 0.00

Day 2 423.5 0.00

Day 3 475.5 13.01

7.0/E10 Static (86) Perm 02/12/09 7466 28.6 0

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 02/13/09 7467 54.1 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 02/17/09 25755 205.7 0.14

TEFVO 24.5 0.00

72 DHB 65-105 02/24/09 7472

Day 1 383.1 0.00

Day 2 349.1 0.00

Day 3 323.5 0.00

9.0/E0 Static (86) Perm 04/01/09 7501 23.4 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 5.8

Static (105) Perm 04/02/09 7504 29.5 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 04/03/09 25761 144.4 0.00

TEFVO 5.0 0.00

72 DHB 65-105 04/07/09 7508

Day 1 327.8 0.00

Day 2 250.5 0.00

Day 3 224.3 0.00
D-11

7.0/E0 Static (86) Perm 04/22/09 7524 16.8 0.00

Press. Incr. 1.9

Prs+Fuel Incr. 7.9

Static (105) Perm 04/23/09 7527 28.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 04/24/09 25768 166.2 0.00

TEFVO 16.8 0.00

72 DHB 65-105 04/29/09 7533

Day 1 354.1 0.00

Day 2 249.7 0.00

Day 3 218.1 0.00
D-12

Vehicle 209b – 2004 Chrysler Stratus

0

10

20

30

40

50

60

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 209b - 2004 Chrysler Stratus

10 psi E10 - 7423

7 psi E10 - 7466

9 psi E0 - 7501

7 psi E0 - 7524

0

20

40

60

80

100

120

140

160

180

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 209b - 2004 Chrysler Stratus

10 psi E10 - 7424

7 psi E10 - 7467

9 psi E0 - 7504

7 psi E0 - 7527
D-13

Vehicle 209b – 2004 Chrysler Stratus (cont.)

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 209b - 2004 Chrysler Stratus

10 psi E10 - 25742

7 psi E10 - 25755

9 psi E0 - 25761

7 psi E0 - 25768

Running Loss Hot Soak

0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 209b - 2004 Chrysler Stratus

10 psi E10 - 7461

7 psi E10 - 7472

9 psi E0 - 7508

7 psi E0 - 7533

7 psi E0 Test : SharedInnova - Permeation shown is raw SHED.
D-14

Vehicle 210b – 2004 Chevrolet Impala

SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

210b 10.0/E10 Static (86) Perm 01/20/09 7449 19.9 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 01/21/09 7451 70.1 2.87

Press. Incr. 0.0

Prs+Fuel Incr. 34.1

Dynamic RL 01/23/09 25749 147.5 0.00

TEFVO 60.6 0.00

72 DHB 65-105 02/04/09 7462

Day 1 486.5 8.00

Day 2 458.3 28.30

Day 3 441.3 34.80

7.0/E10 Static (86) Perm 02/18/09 7468 29.9 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 02/19/09 7471 51.9 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 23.2

Dynamic RL 02/23/09 25756 218.3 0.14

TEFVO 61.8 0.03

72 DHB 65-105 03/10/09 7482

Day 1 445.1 0.00

Day 2 388.3 0.00

Day 3 359.1 0.00

9.0/E0 Static (86) Perm 04/21/09 7523 21.2 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 4.0

Static (105) Perm 04/22/09 7525 33.5 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 4.8

Dynamic RL 04/23/09 25767 171.1 0.00

TEFVO 19.8 0.00

72 DHB 65-105 04/28/09 7531

Day 1 407.8 0.00

Day 2 377.4 0.00

Day 3 358.3 30.91
D-15

7.0/E0 Static (86) Perm 05/13/09 7547 18.7 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 05/14/09 7549 35.5 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 04/15/09 25776 216.0 0.00

TEFVO 49.0 0.00

72 DHB 65-105 05/19/09 7550

Day 1 270.6 0.00

Day 2 266.6 0.00

Day 3 221.1 0.11
D-16

Vehicle 210b – 2004 Chevrolet Impala

0

10

20

30

40

50

60

70

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 210b - 2004 Chevrolet Impala

10 psi E10 - 7449

7 psi E10 - 7468

9 psi E0 - 7523

7 psi E0 - 7547

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 210b - 2004 Chevrolet Impala

10 psi E10 - 7451

7 psi E10 - 7471

9 psi E0 - 7525

7 psi E0 - 7549
D-17

Vehicle 210b – 2004 Chevrolet Impala (cont.)

0

50

100

150

200

250

300

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 210b - 2004 Chevrolet Impala

10 psi E10 - 25749

7 psi E10 - 25756

9 psi E0- -25767

7 psi E0 - 25776

Running Loss Hot Soak

0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 210b - 2004 Chevrolet Impala

10 psi E10 - 7462

7 psi E10 - 7482

9 psi E0 - 7531

7 psi E0 - 7550
D-18

Vehicle 213b – 2004 Dodge Ram 1500

SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

213b 10.0/E10 Static (86) Perm 01/14/09 7442 39.2 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 01/15/09 7446 106.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 01/26/09 25750 130.9 0.00

TEFVO 0.9 0.00

72 DHB 65-105 01/06/09 7429

Day 1 650.6 0.00

Day 2 615.4 0.00

Day 3 700.7 1.60

7.0/E10 Static (86) Perm 02/11/09 7464 29.6 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 02/12/09 7465 82.2 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 02/13/09 25754 243.1 0.00

TEFVO 60.5 0.00

72 DHB 65-105 02/25/09 7473

Day 1 602.8 0.00

Day 2 577.7 0.00

Day 3 588.9 0.00

9.0/E0 Static (86) Perm 04/07/09 7506 14.7 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 04/08/09 7507 34.5 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 04/09/09 25764 203.1 0.61

TEFVO 14.5 0.00

72 DHB 65-105 04/14/09 7516

Day 1 346.3 0.00

Day 2 328.4 0.00

Day 3 292.8 0.00
D-19

7.0/E0 Static (86) Perm 04/23/09 7526 21.1 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 04/24/09 7528 35.3 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 04/27/09 25769 135.1 0.00

TEVFO 12.2 0.00

72 DHB 65-105 05/05/09 7538

Day 1 357.8 0.00

Day 2 283.3 0.00

Day 3 276.5 0.00
D-20

Vehicle 213b – 2004 Dodge Ram 1500

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 213b - 2004 Dodge Ram 1500

10 psi E10 - 7442

7 psi E10 - 7464

9 psi E0 - 7506

7 psi E0 - 7526

0

50

100

150

200

250

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 213b - 2004 Dodge Ram 1500

10 psi E10 - 7446

7 psi E10 - 7465

9 psi E0 - 7507

7 psi E0 - 7528
D-21

Vehicle 213b – 2004 Dodge Ram 1500 (cont.)

0

50

100

150

200

250

300

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 213b - 2004 Dodge Ram 1500

10 psi E10 - 25750

7 psi E10 - 25754

9 psi E0 - 25764

7 psi E0 - 25769

Running Loss Hot Soak

0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 213b - 2004 Dodge Ram 1500

10 psi E10 - 7429

7 psi E10 - 7473

9 psi E0 - 7516

7 psi E0 - 7538
D-22

Vehicle 221b - 2000 Mitsubishi Galant

2000 Mitsubishi Galant SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

221b 10.0/E10 Static (86) Perm 05/27/09 7557 38.9 0.00

Press. Incr. 1568.7

Prs+Fuel Incr. 1693.9

Static (105) Perm 05/28/09 7559 80.2 0.00

Press. Incr. 1932.6

Prs+Fuel Incr. 2147.1

"True" HS 26.9 0.00

72 DHB 65-105 06/02/09 7562

Day 1 827.9 2.00

Day 2 724.1 5.40

Day 3 702.4 21.80

7.0/E10 Static (86) Perm 06/10/09 7571 22.7 0.00

Press. Incr. 930.7

Prs+Fuel Incr. 971.0

Static (105) Perm 06/11/09 7572 61.4 0.00

Press. Incr. 1282.3

Prs+Fuel Incr. 1408.5

Dynamic RL 06/12/09 25783 102.0 0.00

"True" HS 40.5 0.00

Day 1 894.7 0.00

Day 2 676.7 0.00

Day 3 618.0 0.00

9.0/E0 Static (86) Perm 08/20/09 7650 55.6 0.00

Prs+Fuel Incr. 1406.0

Static (105) Perm 08/21/09 7652 94.8 0.00

Press. Incr. 1646.7

Prs+Fuel Incr. 1788.2

Dynamic RL 08/24/09 25790 135.2 0.00

"True" HS 29.0 0.00

72 DHB 65-105 09/01/09 7667

Day 1 706.4 0.30

Day 2 543.7 2.60

Day 3 538.3 9.30
D-23

7.0/E0 Static (86) Perm 09/17/09 7691 35.9 0.00

Press. Incr. 988.8

Prs+Fuel Incr. 961.8

Static (105) Perm 09/18/09 7692 66.8 0.00

Press. Incr. 1215.9

Prs+Fuel Incr. 1343.8

Dynamic RL 09/22/09 25797 189.8 0.00

"True" HS 42.5 0.00

72 DHB 65-105 10/07/09 7716

Day 1 603.0 0.00

Day 2 503.1 0.00

Day 3 487.0 0.00
D-24

0

200

400

600

800

1000

1200

1400

1600

0 20 40 60 80 100 120

5 min Running Avg.

Corrected SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 221b - 2000 Mitsubishi Galant

10 psi E10 - 7557

7 psi E10 - 7571

9 psi E0 - 7650

7 psi E0 - 7691

0

500

1000

1500

2000

0 20 40 60 80 100 120

5 min Running Avg.

Corrected SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 221b - 2000 Mitsubishi Galant

10 psi E10 - 7559

7 psi E10 - 7572

9 psi E0 - 7652

7 psi E0 - 7692
D-25

0

50

100

150

200

250

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 221b - 2000 Mitsubishi Galant

10 psi E10 - 25778

7 psi E10 - 25783

9 psi E0 - 25790

7 psi E0 - 25797

Running Loss Hot Soak

0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 221b - 2000 Mitsubishi Galant

10 psi E10 - 7562

7 psi E10 - 7579

9 psi E0 - 7667

7 psi E0 - 7716
D-26

Vehicle 222b – 2004 Ford Focus

SHED

Corrected Results Canister

Fuel Permeation mg/day Loss

Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g

222b 10.0/E10 Static (86) Perm 05/20/09 7552 3.7 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 05/21/09 7554 7.4 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 8.3

Dynamic RL 06/03/09 25779 73.1 0.00

TEFVO 0.0 0.00

72 DHB 65-105 05/27/09 7558

Day 1 104.1 1.70

Day 2 79.7 16.00

Day 3 73.4 30.20

7.0/E10 Static (86) Perm 06/17/09 7576 12.1 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 06/18/09 7578 16.3 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 07/01/09 25785 61.7 0.00

TEFVO 0.0 0.00

72 DHB 65-105 06/23/09 7580

Day 1 99.6 0.00

Day 2 104.0 0.00

Day 3 84.0 0.00

9.0/E0 Static (86) Perm 08/25/09 7655 3.1 0.00

Press. Incr. 0.5

Prs+Fuel Incr. 4.0

Static (105) Perm 08/26/09 7659 5.8 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.5

Dynamic RL 08/27/09 25791 45.5 0.00

"True" HS 0.0 0.00

72 DHB 65-105 09/22/09 7696

Day 1 77.4 0.00

Day 2 41.9 0.00

Day 3 57.9 0.00
D-27

7.0/E0 Static (86) Perm 10/06/09 7712 3.4 0.60

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Static (105) Perm 10/07/09 7715 6.4 0.00

Press. Incr. 0.0

Prs+Fuel Incr. 0.0

Dynamic RL 10/23/09 25808 128.8 0.00

"True" HS 5.4 0.00

72 DHB 65-105 10/27/09 7742

Day 1 58.6 0.00

Day 2 39.0 0.00

Day 3 38.8 0.00
D-28

Vehicle 222b – 2004 Ford Focus

0

5

10

15

20

25

30

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 86 F Permeation

Vehicle 222b - 2004 Ford Focus

10 psi E10 - 7552

7 psi E10 - 7576

9 psi E0 - 7655

7 psi E0 - 7712

0

5

10

15

20

25

30

0 20 40 60 80 100 120

5 min Running Avg.

Cumulative SHED Mass - mg

Test Time - minutes

Static 105 F Permeation

Vehicle 222b - 2004 Ford Focus

10 psi E10 - 7554

7 psi E10 - 7578

9 psi E0 - 7659

7 psi E0 - 7715
D-29

Vehicle 222b – 2004 Ford Focus (cont.)

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100

5 min Running Avg.

Cumulative Permeation - mg

Test Time - minutes

Running Loss and Hot Soak

Vehicle 222b - 2004 Ford Focus

10 psi E10 - 25779

7 psi E10 - 25785

9 psi E0 - 25791

7 psi E0 - 25808

Running Loss Hot Soak

0

50

100

150

200

250

300

350

0 10 20 30 40 50 60 70

Cumulative Permeation - mg.

Test Time - hrs.

Three Day Diurnal

Vehicle 222b - 2004 Ford Focus

10 psi E10 - 7558

7 psi E10 - 7580

9 psi E0 - 7696

7 psi E0 - 7742
APPENDIX E

COMPLETE SPECIATION TEST RESULTS – ALL E-77-2b VEHICLES
E-1

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7456 247.0 100.8 249.1 885.1 3.553 71

Static E10 - 7 psi 7484 279.7 79.6 222.7 796.1 3.575 60

E0 - 9 psi 7539 123.3 99.5 122.8 511.2 4.164 55

E0 - 7 psi 7561 97.3 80.1 78.0 284.8 3.651 56

105° F E10 - 10 psi 7459 630.7 93.1 587.4 2085.4 3.550 86

Static E10 - 7 psi 7487 606.2 125.3 759.4 2686.3 3.538 84

E0 - 9 psi 7545 366.7 72.9 267.3 814.4 3.047 30

E0 - 7 psi 7563 234.6 85.9 201.5 854.3 4.241 30

Dynamic E10 - 10 psi 25753 727.2 87.3 634.7 2191.6 3.453 66

E10 - 7 psi 25760 673.6 90.0 606.0 2158.5 3.562 59

E0 - 9 psi 25775 456.1 76.8 350.1 1316.4 3.760 54

E0 - 7 psi 25780 316.9 78.8 249.7 987.9 3.956 52

DHB E10 - 10 psi 7476 76809.3 82.4 63303.9 148993.1 2.354 123

Total E10 - 7 psi 7495 6985.0 88.6 6189.7 21304.5 3.442 108

E0 - 9 psi 7551 4036.4 91.1 3677.3 11381.0 3.095 107

E0 - 7 psi 7567 2993.3 93.4 2797.0 8687.2 3.106 105

Vehicle 206b
E-2

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 48.01 188.431

n-Butane 00106-97-8 1.08 28.79 31.008

Ethanol 00064-17-5 1.45 27.48 39.815

2-Methylbutane (Isopentane) 00078-78-4 1.35 16.98 23.013

n-Hexane 00110-54-3 1.13 11.59 13.154

Benzene 00071-43-2 0.69 8.67 6.020

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.40 49.622

2-Methyl-2-butene 00513-35-9 14.20 5.73 81.281

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.55 29.779

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.53 7.729

t-2-Pentene 00646-04-8 10.47 5.38 56.317

n-Pentane 00109-66-0 1.21 5.20 6.318

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.59 33.912

3-Methylpentane 00096-14-0 1.69 3.73 6.304

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.47 4.157

Methylcyclopentane 00096-37-7 2.05 2.99 6.132

c-2-Pentene 00627-20-3 10.28 2.89 29.663

Cyclohexane 00110-82-7 1.14 2.55 2.901

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.45 10.769

2,3-Dimethylbutane 00079-29-8 0.90 2.40 2.158

2-Methyl-1-butene 00563-46-2 6.38 2.26 14.412

n-Heptane 00142-82-5 0.97 2.05 1.976

Methylcyclohexane 00108-87-2 1.56 2.03 3.158

ortho-Xylene 00095-47-6 7.58 1.74 13.178

2-Methylpropane 00075-28-5 1.18 1.65 1.944

2,3-Dimethylpentane 00565-59-3 1.25 1.49 1.865

2,3,4-Trimethylpentane 00565-75-3 0.95 1.49 1.414

t-2-Hexene 04050-45-7 8.55 1.46 12.466

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.42 16.728

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.42 16.626

1-Methylcyclopentene 00693-89-0 12.45 1.40 17.471

2,4-Dimethylpentane 00108-08-7 1.46 1.35 1.964

c-2-Butene 00590-18-1 14.26 1.31 18.701

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.30 7.178

2-Methylhexane 00591-76-4 1.09 1.26 1.365

2-Methylheptane 00592-27-8 0.97 1.19 1.148

t-2-Butene 00624-64-6 15.20 1.13 17.156

n-Octane 00111-65-9 0.80 1.11 0.887

Ethylbenzene 00100-41-4 2.96 1.11 3.279

Cyclopentene 00142-29-0 6.69 1.08 7.194

3-Methyl-t-2-pentene 00616-12-6 11.66 1.03 11.983

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.99 3.172

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.95 6.256

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.89 7.065

Vehicle 206b - Fuel 10 psi E10 - 86°F Static - Test 7456

Non Zero Mass Species Sorted By VOC
E-3

continued

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 10 psi E10 - 86°F Static - Test 7456

Non Zero Mass Species Sorted By VOC

Indan 00496-11-7 3.23 0.87 2.825

3-Methyl-c-2-pentene 00922-62-3 12.52 0.84 10.507

2,4-Dimethylhexane 00589-43-5 1.61 0.84 1.341

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.80 4.248

2-Methyl-2-pentene 00625-27-4 11.03 0.77 8.489

Unknown #22 . 3.55 0.75 2.668

2,2,5-Trimethylhexane 03522-94-9 1.05 0.75 0.786

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.71 8.495

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.70 1.117

3-Methylheptane 00589-81-1 1.12 0.67 0.759

t-1,2-Dimethylcyclopentane 00822-50-4 3.55 0.67 2.393

1,4-Diethylbenzene 00105-05-5 4.39 0.67 2.943

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.65 5.111

c-1,3-Dimethylcyclohexane 00638-04-0 3.55 0.65 2.316

2,2-DiMeHexane 00590-73-8 0.94 0.63 0.595

n-Nonane 00111-84-2 0.68 0.60 0.409

c-1,3-Dimethylcyclopentane 02532-58-3 3.55 0.55 1.950

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.49 2.816

2,3,5-Trimethylhexane 01069-53-0 1.12 0.44 0.497

n-Decane 00124-18-5 0.59 0.43 0.256

2,2-Dimethylpentane 00590-35-2 1.04 0.41 0.424

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.40 2.857

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.37 0.405

2,2-Dimethylbutane 00075-83-2 1.11 0.34 0.378

Isopropylbenzene (Cumene) 00098-82-8 3.55 0.25 0.883

Unknown #1 3.55 0.20 0.728

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.18 1.861

Total 249.1 885.1 3.553

No MIR available, use weighted average of 3.5531
E-4

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 109.41 429.434

Ethanol 00064-17-5 1.45 79.67 115.437

n-Butane 00106-97-8 1.08 60.47 65.121

2-Methylbutane (Isopentane) 00078-78-4 1.35 38.51 52.170

n-Hexane 00110-54-3 1.13 25.70 29.162

Benzene 00071-43-2 0.69 18.23 12.655

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 16.75 129.906

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.86 79.761

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 13.07 18.270

2-Methyl-2-butene 00513-35-9 14.20 12.49 177.237

t-2-Pentene 00646-04-8 10.47 11.85 124.115

n-Pentane 00109-66-0 1.21 11.80 14.341

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.54 77.838

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 8.58 10.285

3-Methylpentane 00096-14-0 1.69 8.57 14.486

Methylcyclopentane 00096-37-7 2.05 7.71 15.795

Cyclohexane 00110-82-7 1.14 6.66 7.578

2,3-Dimethylbutane 00079-29-8 0.90 5.96 5.355

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.80 25.486

c-2-Pentene 00627-20-3 10.28 5.69 58.531

2-Methyl-1-butene 00563-46-2 6.38 5.09 32.497

n-Propylbenzene 00103-65-1 1.96 4.72 9.255

ortho-Xylene 00095-47-6 7.58 4.50 34.080

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.25 49.981

2,3,4-Trimethylpentane 00565-75-3 0.95 4.19 3.978

t-2-Butene 00624-64-6 15.20 4.15 63.096

n-Heptane 00142-82-5 0.97 4.01 3.876

2,3-Dimethylpentane 00565-59-3 1.25 3.98 4.972

Methylcyclohexane 00108-87-2 1.56 3.95 6.147

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.62 42.314

2-Methylhexane 00591-76-4 1.09 3.59 3.897

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.40 18.850

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.37 10.766

2,4-Dimethylpentane 00108-08-7 1.46 3.25 4.738

t-2-Hexene 04050-45-7 8.55 3.22 27.547

1-Methylcyclopentene 00693-89-0 12.45 2.97 37.042

2-Methylpropane 00075-28-5 1.18 2.90 3.408

Ethylbenzene 00100-41-4 2.96 2.70 8.013

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.46 13.032

c-2-Butene 00590-18-1 14.26 2.43 34.700

Cyclopentene 00142-29-0 6.69 2.41 16.094

n-Octane 00111-65-9 0.80 2.22 1.771

3-Methyl-t-2-pentene 00616-12-6 11.66 2.22 25.834

2,4-Dimethylhexane 00589-43-5 1.61 2.02 3.242

Vehicle 206b - Fuel 10 psi E10 - 105°F Static - Test 7459

Non Zero Mass Species Sorted By VOC
E-5

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 10 psi E10 - 105°F Static - Test 7459

Non Zero Mass Species Sorted By VOC

3-Methyl-c-2-pentene 00922-62-3 12.52 1.96 24.488

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.90 22.685

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.71 11.279

2-Methyl-2-pentene 00625-27-4 11.03 1.64 18.090

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.47 2.354

1,4-Diethylbenzene 00105-05-5 4.39 1.35 5.927

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.30 10.350

n-Decane 00124-18-5 0.59 1.30 0.768

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.20 1.315

2,2-DiMeHexane 00590-73-8 0.94 1.19 1.118

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 1.14 8.556

2,3,5-Trimethylhexane 01069-53-0 1.12 1.07 1.200

3-Methylheptane 00589-81-1 1.12 1.06 1.195

Indan 00496-11-7 3.23 1.02 3.303

Unknown #22 . 3.55 0.91 3.248

2-Methylheptane 00592-27-8 0.97 0.86 0.834

t-1,2-Dimethylcyclopentane 00822-50-4 3.55 0.85 3.026

n-Nonane 00111-84-2 0.68 0.81 0.553

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.74 5.261

Ethylcyclohexane 01678-91-7 1.35 0.72 0.975

2,2,5-Trimethylhexane 03522-94-9 1.05 0.69 0.729

4-Methyloctane 02216-34-4 0.85 0.67 0.571

Isopropylbenzene (Cumene) 00098-82-8 3.55 0.66 2.350

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.61 2.367

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.57 4.492

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.53 3.086

3,3-Dimethylpentane 00562-49-2 1.12 0.52 0.587

Unknown #5 3.55 0.47 1.684

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.45 0.532

t-1,4-Dimethylcyclohexane 02207-04-7 3.55 0.43 1.513

c-1,3-Dimethylcyclopentane 02532-58-3 3.55 0.42 1.492

2,2-Dimethylbutane 00075-83-2 1.11 0.38 0.419

c-2-Heptene 06443-92-1 7.08 0.37 2.621

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.35 2.629

1,3-Diethylbenzene 00141-93-5 7.08 0.33 2.338

c-1,3-Dimethylcyclohexane 00638-04-0 3.55 0.33 1.154

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.30 2.294

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.30 3.100

Styrene 00100-42-5 1.66 0.24 0.406

2,2-Dimethylpentane 00590-35-2 1.04 0.22 0.226

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.55 0.21 0.738

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.18 1.487

Total 587.4 2085.4 3.550

No MIR available, use weighted average of 3.5503

continued
E-6

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 117.87 462.653

Ethanol 00064-17-5 1.45 77.41 112.160

n-Butane 00106-97-8 1.08 49.17 52.950

2-Methylbutane (Isopentane) 00078-78-4 1.35 26.52 35.927

n-Hexane 00110-54-3 1.13 24.76 28.090

Benzene 00071-43-2 0.69 22.18 15.398

n-Propylbenzene 00103-65-1 1.96 20.00 39.201

Unknown #22 . 3.45 17.66 60.998

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 17.56 94.271

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 17.10 132.635

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 12.68 93.657

2-Methyl-2-butene 00513-35-9 14.20 12.20 173.135

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 12.09 14.503

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 12.00 16.775

n-Pentane 00109-66-0 1.21 9.49 11.533

t-2-Pentene 00646-04-8 10.47 8.90 93.256

3-Methylpentane 00096-14-0 1.69 8.83 14.937

Methylcyclopentane 00096-37-7 2.05 8.46 17.345

Cyclohexane 00110-82-7 1.14 7.60 8.643

1,3,5-Trimethylbenzene 00108-67-8 11.75 7.59 89.211

2-Methylpropane 00075-28-5 1.18 6.46 7.604

2,3-Dimethylbutane 00079-29-8 0.90 6.33 5.693

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 6.11 26.866

2,3,4-Trimethylpentane 00565-75-3 0.95 5.96 5.657

2,3-Dimethylpentane 00565-59-3 1.25 5.65 7.054

ortho-Xylene 00095-47-6 7.58 5.23 39.602

c-2-Pentene 00627-20-3 10.28 5.20 53.457

Methylcyclohexane 00108-87-2 1.56 5.15 8.003

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 5.07 16.180

n-Heptane 00142-82-5 0.97 5.00 4.828

2-Methylhexane 00591-76-4 1.09 4.75 5.153

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.59 25.446

n-Octane 00111-65-9 0.80 4.51 3.591

2-Methyl-1-butene 00563-46-2 6.38 4.51 28.743

Cyclopentene 00142-29-0 6.69 3.91 26.172

2,4-Dimethylpentane 00108-08-7 1.46 3.80 5.550

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.29 12.566

2,4-Dimethylhexane 00589-43-5 1.61 3.27 5.247

2,2-DiMeHexane 00590-73-8 0.94 3.23 3.036

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.10 24.626

Ethylbenzene 00100-41-4 2.96 2.96 8.781

3-Methyl-t-2-pentene 00616-12-6 11.66 2.84 33.133

3-Methyl-c-2-pentene 00922-62-3 12.52 2.78 34.781

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.78 32.521

Vehicle 206b - Fuel 10 psi E10 - Dynamic - Test 25753

Non Zero Mass Species Sorted By VOC
E-7

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 10 psi E10 - Dynamic - Test 25753

Non Zero Mass Species Sorted By VOC

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.73 2.979

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.61 17.244

2,2,5-Trimethylhexane 03522-94-9 1.05 2.52 2.659

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.46 13.049

t-2-Hexene 04050-45-7 8.55 2.40 20.514

t-2-Butene 00624-64-6 15.20 2.38 36.190

2-Methyl-2-pentene 00625-27-4 11.03 2.36 26.010

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.30 16.259

c-2-Butene 00590-18-1 14.26 1.82 25.931

n-Nonane 00111-84-2 0.68 1.80 1.230

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.76 2.825

c-1,3-Dimethylcyclopentane 02532-58-3 3.45 1.75 6.033

2-Methylheptane 00592-27-8 0.97 1.65 1.596

t-1,2-Dimethylcyclopentane 00822-50-4 3.45 1.58 5.472

3-Methylheptane 00589-81-1 1.12 1.58 1.781

2,2-Dimethylbutane 00075-83-2 1.11 1.51 1.676

Indan 00496-11-7 3.23 1.36 4.390

c-1,3-Dimethylcyclohexane 00638-04-0 3.45 0.82 2.836

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.80 6.011

Isopropylbenzene (Cumene) 00098-82-8 3.45 0.78 2.702

Ethylcyclohexane 01678-91-7 1.35 0.61 0.814

t-1,4-Dimethylcyclohexane 02207-04-7 3.45 0.52 1.791

Total 634.7 2191.6 3.453

No MIR available, use weighted average of 3.4531

continued
E-8

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 22238.67 23949.113

2-Methylbutane (Isopentane) 00078-78-4 1.35 14866.21 20142.039

2-Methylpropane 00075-28-5 1.18 3913.84 4605.038

Ethanol 00064-17-5 1.45 2333.12 3380.625

n-Pentane 00109-66-0 1.21 1930.18 2345.041

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1422.57 1988.449

Toluene 00108-88-3 3.93 1379.64 5415.108

n-Hexane 00110-54-3 1.13 1341.84 1522.557

2-Methyl-2-butene 00513-35-9 14.20 1323.52 18787.299

t-2-Pentene 00646-04-8 10.47 1248.37 13074.803

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1137.90 1364.475

2-Methyl-1-butene 00563-46-2 6.38 922.81 5886.165

3-Methylpentane 00096-14-0 1.69 844.25 1427.512

c-2-Butene 00590-18-1 14.26 834.12 11894.362

2,3-Dimethylbutane 00079-29-8 0.90 705.81 634.310

c-2-Pentene 00627-20-3 10.28 644.03 6621.505

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 585.08 6848.147

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 570.01 4526.514

2,3-Dimethylpentane 00565-59-3 1.25 429.33 535.941

Methylcyclopentane 00096-37-7 2.05 339.04 694.969

2,4-Dimethylpentane 00108-08-7 1.46 336.49 491.047

Benzene 00071-43-2 0.69 335.00 232.607

2,3,4-Trimethylpentane 00565-75-3 0.95 287.60 272.885

Propane 00074-98-6 0.46 266.68 121.904

Cyclohexane 00110-82-7 1.14 237.51 270.139

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 219.54 700.548

2-Methylhexane 00591-76-4 1.09 216.38 234.811

n-Heptane 00142-82-5 0.97 193.59 186.959

2,4-Dimethylhexane 00589-43-5 1.61 136.50 219.158

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 131.06 694.428

Methylcyclohexane 00108-87-2 1.56 127.17 197.793

Cyclopentene 00142-29-0 6.69 125.09 836.329

t-2-Hexene 04050-45-7 8.55 123.48 1055.588

2,2-Dimethylbutane 00075-83-2 1.11 111.28 123.658

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 98.95 158.848

3-Methyl-t-2-pentene 00616-12-6 11.66 93.97 1095.679

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 93.85 727.823

2-Methyl-2-pentene 00625-27-4 11.03 78.27 863.564

3-Methyl-c-2-pentene 00922-62-3 12.52 75.32 942.829

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 70.98 410.108

2,2,5-Trimethylhexane 03522-94-9 1.05 70.44 74.173

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 66.30 438.014

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 63.49 69.333

1-Methylcyclopentene 00693-89-0 12.45 56.66 705.719

Vehicle 206b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7476

Non Zero Mass Species Sorted By VOC
E-9

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7476

Non Zero Mass Species Sorted By VOC

2,2,3-Trimethylbutane 00464-06-2 1.05 19.23 20.263

Ethylbenzene 00100-41-4 2.96 18.93 56.077

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 17.25 75.806

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 13.57 52.421

c-1,3-Dimethylcyclohexane 00638-04-0 2.35 13.53 31.844

Ethane 00074-84-0 0.26 13.03 3.424

2-Methyl-1,3-butadiene 00078-79-5 10.48 12.67 132.793

3,5-Dimethylheptane 00926-82-9 1.42 12.58 17.904

Unknown #5 2.35 12.10 28.475

1,3,5-Trimethylbenzene 00108-67-8 11.75 12.05 141.695

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 11.81 92.502

3,3-Dimethylhexane 00563-16-6 1.15 9.90 11.401

2,2-DiMeHexane 00590-73-8 0.94 9.62 9.051

n-Propylbenzene 00103-65-1 1.96 9.45 18.519

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 9.16 50.746

2,3,5-Trimethylhexane 01069-53-0 1.12 8.71 9.758

4-Methyloctane 02216-34-4 0.85 8.01 6.791

t-1,4-Dimethylcyclohexane 02207-04-7 2.35 5.76 13.550

Unknown #8 2.35 5.75 13.537

c-2-Heptene 06443-92-1 7.08 5.66 40.019

3-Methyloctane 02216-33-3 0.88 5.08 4.493

1,3-Butadiene 00106-99-0 12.45 5.07 63.201

n-Nonane 00111-84-2 0.68 4.89 3.337

t-3-Heptene 14686-14-7 6.17 4.65 28.721

Unknown #13 2.35 4.28 10.072

1-Nonene 00124-11-8 2.49 4.09 10.201

2,4-Dimethylheptane 02213-23-2 1.26 3.95 4.993

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.93 46.913

Ethylene 00074-85-1 8.88 3.78 33.601

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 3.70 3.163

Isopropylbenzene (Cumene) 00098-82-8 2.35 3.64 8.578

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.59 22.613

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 3.57 23.383

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.35 3.56 8.390

t-4-Octene 14850-23-8 4.69 3.28 15.386

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 3.23 27.020

1-Heptene 00592-76-7 4.29 2.76 11.818

1-Butyne 00107-00-6 6.05 2.49 15.065

Indan 00496-11-7 3.23 2.25 7.265

Unknown #16 2.35 2.23 5.250

Unknown #3 2.35 2.21 5.197

continued
E-10

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7476

Non Zero Mass Species Sorted By VOC

1,1-Dimethylcyclohexane 00590-66-9 1.12 2.10 2.337

Unknown #9 2.35 2.05 4.819

t-2-Nonene 06434-78-2 2.35 1.71 4.031

c-2-Octene 07642-04-8 2.35 1.67 3.936

Unknown #6 . 2.35 1.53 3.608

3-Ethyl-c-2-Pentene 00816-79-5 9.76 1.46 14.297

1,4-Diethylbenzene 00105-05-5 4.39 1.34 5.879

2,2-Dimethyloctane 15869-87-1 0.76 1.34 1.011

Unknown #10 2.35 1.16 2.725

n-Decane 00124-18-5 0.59 1.16 0.683

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 1.15 1.356

Unknown #7 2.35 1.11 2.612

c- & t-4-Nonene 02198-23-4 4.42 0.88 3.897

t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 7.43 0.77 5.695

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.69 4.872

c-1,2-Dimethylcyclohexane 02207-01-4 2.35 0.65 1.527

Unknown #11 2.35 0.59 1.388

sec-Butylbenzene 00135-98-8 2.29 0.59 1.345

1,3-Diethylbenzene 00141-93-5 7.08 0.59 4.158

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.59 4.424

4-Methyl-t-2-pentene 00674-76-0 8.04 0.58 4.700

Isobutylbenzene 00538-93-2 2.35 0.48 1.131

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.45 1.729

Styrene 00100-42-5 1.66 0.44 0.739

1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 0.32 2.954

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.29 2.212

Unknown #14 2.35 0.24 0.570

Unknown #4 2.35 0.20 0.469

Total 63303.9 148993.1 2.354

No MIR available, use weighted average of 2.3536

continued
E-11

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 47.17 185.157

Ethanol 00064-17-5 1.45 29.29 42.448

n-Butane 00106-97-8 1.08 18.20 19.599

2-Methylbutane (Isopentane) 00078-78-4 1.35 13.25 17.958

n-Hexane 00110-54-3 1.13 10.81 12.261

Benzene 00071-43-2 0.69 8.83 6.131

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.10 38.104

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 7.01 54.340

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.15 38.067

2-Methyl-2-butene 00513-35-9 14.20 5.01 71.131

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 4.98 6.966

t-2-Pentene 00646-04-8 10.47 4.96 51.966

n-Pentane 00109-66-0 1.21 3.94 4.790

3-Methylpentane 00096-14-0 1.69 3.27 5.526

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.02 3.620

Methylcyclopentane 00096-37-7 2.05 3.01 6.163

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.76 12.130

Cyclohexane 00110-82-7 1.14 2.69 3.056

c-2-Pentene 00627-20-3 10.28 2.19 22.522

2,3-Dimethylbutane 00079-29-8 0.90 2.17 1.953

n-Heptane 00142-82-5 0.97 1.99 1.923

2-Methyl-1-butene 00563-46-2 6.38 1.89 12.052

ortho-Xylene 00095-47-6 7.58 1.87 14.160

Methylcyclohexane 00108-87-2 1.56 1.65 2.565

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.65 9.132

t-2-Hexene 04050-45-7 8.55 1.53 13.101

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.44 16.896

n-Propylbenzene 00103-65-1 1.96 1.37 2.692

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.36 15.948

2,3,4-Trimethylpentane 00565-75-3 0.95 1.33 1.266

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.32 4.211

2,3-Dimethylpentane 00565-59-3 1.25 1.24 1.546

2,4-Dimethylpentane 00108-08-7 1.46 1.24 1.807

Indan 00496-11-7 3.23 1.17 3.788

2-Methylhexane 00591-76-4 1.09 1.12 1.214

3-Methyl-t-2-pentene 00616-12-6 11.66 1.09 12.719

Ethylbenzene 00100-41-4 2.96 1.02 3.022

c-2-Butene 00590-18-1 14.26 0.96 13.734

Cyclopentene 00142-29-0 6.69 0.95 6.331

n-Octane 00111-65-9 0.80 0.87 0.695

3-Methyl-c-2-pentene 00922-62-3 12.52 0.83 10.391

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.77 6.136

3-Methylheptane 00589-81-1 1.12 0.76 0.850

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.73 8.760

Vehicle 206b - Fuel 7 psi E10 - 86°F Static - Test 7484

Non Zero Mass Species Sorted By VOC
E-12

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E10 - 86°F Static - Test 7484

Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.73 1.165

2-Methyl-2-pentene 00625-27-4 11.03 0.68 7.456

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.64 4.254

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.62 3.270

n-Nonane 00111-84-2 0.68 0.61 0.420

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.59 4.196

2-Methylheptane 00592-27-8 0.97 0.50 0.484

2,2,5-Trimethylhexane 03522-94-9 1.05 0.50 0.526

t-1,2-Dimethylcyclopentane 00822-50-4 3.58 0.44 1.562

2,2-DiMeHexane 00590-73-8 0.94 0.43 0.409

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.621

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.38 0.413

c-1,3-Dimethylcyclopentane 02532-58-3 3.58 0.35 1.256

n-Decane 00124-18-5 0.59 0.32 0.189

2,2-Dimethylbutane 00075-83-2 1.11 0.32 0.355

Unknown #1 3.58 0.19 0.685

Total 222.7 796.1 3.575

No MIR available, use weightedaverage of 3.5752

continued
E-13

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 147.65 579.528

Ethanol 00064-17-5 1.45 114.05 165.262

n-Butane 00106-97-8 1.08 45.54 49.041

2-Methylbutane (Isopentane) 00078-78-4 1.35 43.06 58.343

n-Hexane 00110-54-3 1.13 34.97 39.680

Benzene 00071-43-2 0.69 26.02 18.067

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 21.06 163.325

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 19.46 104.460

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 18.52 25.884

n-Propylbenzene 00103-65-1 1.96 16.82 32.957

2-Methyl-2-butene 00513-35-9 14.20 15.88 225.363

n-Pentane 00109-66-0 1.21 15.41 18.723

t-2-Pentene 00646-04-8 10.47 15.13 158.417

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.80 109.346

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 12.66 15.180

3-Methylpentane 00096-14-0 1.69 12.32 20.830

Methylcyclopentane 00096-37-7 2.05 10.73 21.986

Cyclohexane 00110-82-7 1.14 9.05 10.289

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.91 34.771

c-2-Pentene 00627-20-3 10.28 7.71 79.250

2,3-Dimethylbutane 00079-29-8 0.90 7.11 6.388

2-Methyl-1-butene 00563-46-2 6.38 7.09 45.221

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.40 74.888

1,3,5-Trimethylbenzene 00108-67-8 11.75 5.85 68.792

ortho-Xylene 00095-47-6 7.58 5.83 44.143

2,3,4-Trimethylpentane 00565-75-3 0.95 5.79 5.496

n-Heptane 00142-82-5 0.97 5.79 5.594

Methylcyclohexane 00108-87-2 1.56 5.69 8.843

2-Methylhexane 00591-76-4 1.09 5.12 5.559

2,3-Dimethylpentane 00565-59-3 1.25 5.03 6.283

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.92 15.710

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.60 25.482

t-2-Hexene 04050-45-7 8.55 4.48 38.337

2,4-Dimethylpentane 00108-08-7 1.46 4.46 6.504

Ethylbenzene 00100-41-4 2.96 3.71 10.987

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.64 19.270

c-2-Butene 00590-18-1 14.26 3.52 50.172

2-Methylpropane 00075-28-5 1.18 3.30 3.880

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.27 39.092

Cyclopentene 00142-29-0 6.69 3.18 21.255

3-Methyl-c-2-pentene 00922-62-3 12.52 3.08 38.581

3-Methyl-t-2-pentene 00616-12-6 11.66 3.08 35.876

n-Octane 00111-65-9 0.80 2.80 2.232

2,4-Dimethylhexane 00589-43-5 1.61 2.74 4.399

Vehicle 206b - Fuel 7 psi E10 - 105°F Static - Test 7487

Non Zero Mass Species Sorted By VOC
E-14

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E10 - 105°F Static - Test 7487

Non Zero Mass Species Sorted By VOC

1-Methylcyclopentene 00693-89-0 12.45 2.67 33.297

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.53 16.697

2-Methyl-2-pentene 00625-27-4 11.03 2.52 27.769

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.15 3.447

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.85 14.700

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.70 1.853

2,2-Dimethylbutane 00075-83-2 1.11 1.46 1.624

2-Methylheptane 00592-27-8 0.97 1.45 1.402

Cyclopentane 00287-92-3 2.24 1.42 3.170

2,2,5-Trimethylhexane 03522-94-9 1.05 1.37 1.444

Indan 00496-11-7 3.23 1.32 4.285

t-1,2-Dimethylcyclopentane 00822-50-4 3.54 1.27 4.477

n-Nonane 00111-84-2 0.68 1.23 0.841

1,4-Diethylbenzene 00105-05-5 4.39 1.22 5.372

2,2-DiMeHexane 00590-73-8 0.94 1.14 1.073

3-Methylheptane 00589-81-1 1.12 1.04 1.165

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.98 5.651

Isopropylbenzene (Cumene) 00098-82-8 3.54 0.92 3.268

c-1,3-Dimethylcyclopentane 02532-58-3 3.54 0.90 3.198

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.89 6.282

2,3,5-Trimethylhexane 01069-53-0 1.12 0.88 0.990

3,3-Dimethylpentane 00562-49-2 1.12 0.80 0.892

c-1,3-Dimethylcyclohexane 00638-04-0 3.54 0.79 2.799

n-Decane 00124-18-5 0.59 0.70 0.413

2,2-Dimethylpentane 00590-35-2 1.04 0.67 0.700

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.67 5.234

4-Methyloctane 02216-34-4 0.85 0.64 0.546

3-Methyloctane 02216-33-3 0.88 0.53 0.472

1-Nonene 00124-11-8 2.49 0.52 1.297

Unknown #1 3.54 0.51 1.795

Ethylcyclohexane 01678-91-7 1.35 0.50 0.667

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.49 1.887

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.45 3.360

2,2,3-Trimethylbutane 00464-06-2 1.05 0.37 0.392

Unknown #5 3.54 0.35 1.250

1,3-Diethylbenzene 00141-93-5 7.08 0.34 2.397

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.31 3.284

t-1,4-Dimethylcyclohexane 02207-04-7 3.54 0.26 0.914

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.23 1.703

1,2-Diethylbenzene 00135-01-3 5.43 0.12 0.648

Total 759.4 2686.3 3.538

No MIR available, use weighted average of 3.5376

continued
E-15

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 127.65 501.023

Ethanol 00064-17-5 1.45 83.31 120.716

n-Butane 00106-97-8 1.08 43.76 47.129

2-Methylbutane (Isopentane) 00078-78-4 1.35 33.21 44.997

n-Hexane 00110-54-3 1.13 27.16 30.820

Benzene 00071-43-2 0.69 24.00 16.665

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.12 156.011

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 18.50 99.305

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 16.26 120.071

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 13.02 18.193

2-Methyl-2-butene 00513-35-9 14.20 11.93 169.328

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 10.31 12.362

n-Pentane 00109-66-0 1.21 10.02 12.172

t-2-Pentene 00646-04-8 10.47 9.93 104.038

Methylcyclopentane 00096-37-7 2.05 9.15 18.758

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.28 31.989

Cyclohexane 00110-82-7 1.14 6.92 7.872

ortho-Xylene 00095-47-6 7.58 6.76 51.232

3-Methylpentane 00096-14-0 1.69 6.72 11.365

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 6.47 24.707

2,3-Dimethylbutane 00079-29-8 0.90 6.40 5.753

Ethylene 00074-85-1 8.88 5.85 51.939

2-Methylpropane 00075-28-5 1.18 5.82 6.846

c-2-Pentene 00627-20-3 10.28 5.19 53.381

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.90 57.606

n-Heptane 00142-82-5 0.97 4.76 4.601

2-Methyl-1-butene 00563-46-2 6.38 4.55 29.012

2,3,4-Trimethylpentane 00565-75-3 0.95 4.42 4.196

Methylcyclohexane 00108-87-2 1.56 4.42 6.879

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.84 21.282

2,3-Dimethylpentane 00565-59-3 1.25 3.74 4.675

n-Octane 00111-65-9 0.80 3.68 2.932

Indan 00496-11-7 3.23 3.45 11.169

Ethylbenzene 00100-41-4 2.96 3.43 10.176

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.37 39.471

t-2-Hexene 04050-45-7 8.55 3.27 27.979

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.21 10.252

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.05 24.212

2,4-Dimethylpentane 00108-08-7 1.46 3.04 4.440

2-Methylhexane 00591-76-4 1.09 2.57 2.794

3-Methyl-c-2-pentene 00922-62-3 12.52 2.56 32.096

3-Methyl-t-2-pentene 00616-12-6 11.66 2.46 28.681

c-2-Butene 00590-18-1 14.26 2.38 33.934

2,4-Dimethylhexane 00589-43-5 1.61 2.18 3.497

Vehicle 206b - Fuel 7 psi E10 - Dynamic - Test 25760

Non Zero Mass Species Sorted By VOC
E-16

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E10 - Dynamic - Test 25760

Non Zero Mass Species Sorted By VOC

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.18 3.497

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.11 13.910

2-Methyl-2-pentene 00625-27-4 11.03 2.06 22.768

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.01 14.257

c-1,3-Dimethylcyclopentane 02532-58-3 3.56 1.88 6.682

2,2-DiMeHexane 00590-73-8 0.94 1.80 1.699

n-Nonane 00111-84-2 0.68 1.74 1.188

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.42 7.511

t-1,2-Dimethylcyclopentane 00822-50-4 3.56 1.41 5.009

3-Methylheptane 00589-81-1 1.12 1.18 1.323

2,2,5-Trimethylhexane 03522-94-9 1.05 1.11 1.168

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.00 1.094

2-Methylheptane 00592-27-8 0.97 0.44 0.421

Methane 00074-82-8 0.01 0.43 0.006

Cyclopentene 00142-29-0 6.69 0.21 1.393

Total 606.0 2158.5 3.562

No MIR available, use weighted average of 3.5618

continued
E-17

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 938.92 3685.272

Ethanol 00064-17-5 1.45 876.24 1269.651

2-Methylbutane (Isopentane) 00078-78-4 1.35 561.05 760.158

n-Hexane 00110-54-3 1.13 430.31 488.263

n-Butane 00106-97-8 1.08 402.75 433.722

Benzene 00071-43-2 0.69 238.37 165.516

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 208.48 291.415

2-Methyl-2-butene 00513-35-9 14.20 201.15 2855.258

t-2-Pentene 00646-04-8 10.47 191.91 2010.007

n-Pentane 00109-66-0 1.21 168.04 204.158

3-Methylpentane 00096-14-0 1.69 140.20 237.064

Methylcyclopentane 00096-37-7 2.05 118.13 242.150

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 103.84 124.515

Cyclohexane 00110-82-7 1.14 98.63 112.179

c-2-Pentene 00627-20-3 10.28 93.76 964.026

2-Methyl-1-butene 00563-46-2 6.38 80.98 516.533

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 77.52 601.227

2,3-Dimethylbutane 00079-29-8 0.90 72.95 65.561

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 55.79 653.040

n-Heptane 00142-82-5 0.97 55.25 53.357

t-2-Hexene 04050-45-7 8.55 52.42 448.132

Methylcyclohexane 00108-87-2 1.56 51.82 80.605

2-Methylhexane 00591-76-4 1.09 47.45 51.496

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 44.04 140.517

2,3,4-Trimethylpentane 00565-75-3 0.95 43.48 41.253

2,4-Dimethylpentane 00108-08-7 1.46 43.09 62.880

c-2-Butene 00590-18-1 14.26 43.00 613.201

2,3-Dimethylpentane 00565-59-3 1.25 41.65 51.995

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 39.05 206.928

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 38.62 207.348

Cyclopentene 00142-29-0 6.69 38.47 257.197

3-Methyl-t-2-pentene 00616-12-6 11.66 36.34 423.683

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 36.31 268.204

1-Methylcyclopentene 00693-89-0 12.45 35.58 443.119

3-Methyl-c-2-pentene 00922-62-3 12.52 32.31 404.403

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 28.33 187.184

2-Methyl-2-pentene 00625-27-4 11.03 28.26 311.775

2-Methylpropane 00075-28-5 1.18 23.43 27.573

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 21.96 174.381

2,4-Dimethylhexane 00589-43-5 1.61 21.71 34.862

n-Octane 00111-65-9 0.80 20.58 16.388

ortho-Xylene 00095-47-6 7.58 19.14 145.003

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 18.58 81.632

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 15.64 25.102

Vehicle 206b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7495

Non Zero Mass Species Sorted By VOC
E-18

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7495

Non Zero Mass Species Sorted By VOC

Cyclopentane 00287-92-3 2.24 14.32 32.040

Ethylbenzene 00100-41-4 2.96 13.32 39.465

1,3,5-Trimethylbenzene 00108-67-8 11.75 12.80 150.415

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 12.40 13.541

t-1,2-Dimethylcyclopentane 00822-50-4 3.44 11.43 39.328

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 11.11 61.570

n-Propylbenzene 00103-65-1 1.96 10.37 20.327

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 9.93 57.400

2,2,5-Trimethylhexane 03522-94-9 1.05 9.88 10.407

2-Methylheptane 00592-27-8 0.97 9.65 9.336

2,2-DiMeHexane 00590-73-8 0.94 9.40 8.851

c-1,3-Dimethylcyclopentane 02532-58-3 3.44 9.15 31.502

2,2-Dimethylbutane 00075-83-2 1.11 8.93 9.920

3-Methylheptane 00589-81-1 1.12 8.65 9.726

2,2-Dimethylpentane 00590-35-2 1.04 5.95 6.207

2,3,5-Trimethylhexane 01069-53-0 1.12 5.83 6.525

c-1,3-Dimethylcyclohexane 00638-04-0 3.44 5.46 18.800

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 5.14 40.310

1,2,3-Trimethylbenzene 00526-73-8 11.94 4.82 57.560

Ethylcyclohexane 01678-91-7 1.35 4.60 6.188

2,2,3-Trimethylbutane 00464-06-2 1.05 4.56 4.808

n-Nonane 00111-84-2 0.68 4.00 2.731

Propane 00074-98-6 0.46 3.83 1.751

3,3-Dimethylpentane 00562-49-2 1.12 3.82 4.276

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 3.12 12.065

n-Decane 00124-18-5 0.59 2.99 1.769

t-1,4-Dimethylcyclohexane 02207-04-7 3.44 2.60 8.939

Indan 00496-11-7 3.23 2.53 8.194

4-Methyloctane 02216-34-4 0.85 2.52 2.138

2-Methyl-1,3-butadiene 00078-79-5 10.48 2.51 26.290

Isopropylbenzene (Cumene) 00098-82-8 3.44 2.43 8.367

Unknown #5 3.44 2.39 8.239

c-2-Heptene 06443-92-1 7.08 2.25 15.947

t-3-Heptene 14686-14-7 6.17 2.09 12.898

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.44 1.80 6.193

1,4-Diethylbenzene 00105-05-5 4.39 1.77 7.774

Unknown #16 3.44 1.75 6.008

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.71 12.126

Cyclopentadiene 00542-92-7 6.89 1.71 11.786

3,3-Dimethylhexane 00563-16-6 1.15 1.54 1.769

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.48 12.428

Unknown #8 3.44 1.40 4.829

continued
E-19

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7495

Non Zero Mass Species Sorted By VOC

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.34 8.743

3-Methyloctane 02216-33-3 0.88 1.22 1.078

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.15 1.278

2,4-Dimethylheptane 02213-23-2 1.26 1.10 1.390

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.06 0.902

1-Heptene 00592-76-7 4.29 0.94 4.023

1-Nonene 00124-11-8 2.49 0.89 2.222

sec-Butylbenzene 00135-98-8 2.29 0.81 1.846

Unknown #3 3.44 0.80 2.746

1,3-Diethylbenzene 00141-93-5 7.08 0.70 4.951

Unknown #9 3.44 0.70 2.396

Unknown #13 3.44 0.69 2.386

Isobutylbenzene 00538-93-2 3.44 0.63 2.182

t-2-Nonene 06434-78-2 3.44 0.63 2.178

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.58 4.371

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.53 0.628

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.52 2.000

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.50 4.927

c- & t-4-Nonene 02198-23-4 4.42 0.48 2.117

t-4-Octene 14850-23-8 4.69 0.35 1.632

c-1,2-Dimethylcyclohexane 02207-01-4 3.44 0.29 1.014

Unknown #6 3.44 0.25 0.848

Total 6189.7 21304.5 3.442

No MIR available, use weighted average of 3.4419

continued
E-20

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 28.42 111.564

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.52 55.563

2-Methylbutane (Isopentane) 00078-78-4 1.35 7.13 9.666

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.19 48.014

Benzene 00071-43-2 0.69 5.88 4.082

n-Hexane 00110-54-3 1.13 5.87 6.664

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.07 27.215

Cyclohexane 00110-82-7 1.14 4.60 5.235

Ethanol 00064-17-5 1.45 4.09 5.920

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.96 4.138

2-Methyl-2-butene 00513-35-9 14.20 2.81 39.831

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.47 10.839

t-2-Pentene 00646-04-8 10.47 2.06 21.590

3-Methylpentane 00096-14-0 1.69 1.98 3.343

n-Pentane 00109-66-0 1.21 1.96 2.379

Methylcyclopentane 00096-37-7 2.05 1.90 3.886

n-Butane 00106-97-8 1.08 1.81 1.948

ortho-Xylene 00095-47-6 7.58 1.78 13.522

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.76 2.108

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.73 20.357

2,3-Dimethylbutane 00079-29-8 0.90 1.49 1.337

Ethylbenzene 00100-41-4 2.96 1.26 3.726

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.23 6.812

c-2-Pentene 00627-20-3 10.28 1.12 11.502

n-Propylbenzene 00103-65-1 1.96 1.09 2.135

2,3,4-Trimethylpentane 00565-75-3 0.95 1.01 0.954

Methylcyclohexane 00108-87-2 1.56 0.98 1.525

n-Heptane 00142-82-5 0.97 0.96 0.928

2-Methyl-1-butene 00563-46-2 6.38 0.88 5.615

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.87 5.756

2,4-Dimethylhexane 00589-43-5 1.61 0.86 1.384

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.80 4.257

t-2-Hexene 04050-45-7 8.55 0.80 6.807

2,2,5-Trimethylhexane 03522-94-9 1.05 0.73 0.771

2,3-Dimethylpentane 00565-59-3 1.25 0.72 0.896

2,4-Dimethylpentane 00108-08-7 1.46 0.71 1.042

2-Methylhexane 00591-76-4 1.09 0.70 0.763

3-Methyl-c-2-pentene 00922-62-3 12.52 0.70 8.716

2-Methyl-2-pentene 00625-27-4 11.03 0.64 7.012

3-Methyl-t-2-pentene 00616-12-6 11.66 0.63 7.327

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.61 7.312

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.60 1.907

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.59 6.955

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.55 0.879

Cyclopentene 00142-29-0 6.69 0.52 3.502

Vehicle 206b - Fuel 9 psi E0 - 86°F Static - Test 7539

Non Zero Mass Species Sorted By VOC
E-21

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 9 psi E0 - 86°F Static - Test 7539

Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 0.52 0.416

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.49 0.533

2,2-DiMeHexane 00590-73-8 0.94 0.43 0.404

Indan 00496-11-7 3.23 0.40 1.304

t-1,2-Dimethylcyclopentane 00822-50-4 4.16 0.37 1.551

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.36 2.879

c-2-Butene 00590-18-1 14.26 0.33 4.698

c-1,3-Dimethylcyclopentane 02532-58-3 4.16 0.29 1.219

2-Methylheptane 00592-27-8 0.97 0.29 0.282

2,3,5-Trimethylhexane 01069-53-0 1.12 0.24 0.266

Total 122.8 511.2 4.164

No MIR available, use weighted average of 4.1644

continued
E-22

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 56.24 220.748

2-Methylbutane (Isopentane) 00078-78-4 1.35 31.47 42.640

n-Butane 00106-97-8 1.08 27.75 29.885

Ethanol 00064-17-5 1.45 18.75 27.170

n-Hexane 00110-54-3 1.13 14.82 16.814

Cyclohexane 00110-82-7 1.14 14.24 16.195

Benzene 00071-43-2 0.69 11.97 8.310

3-Methylpentane 00096-14-0 1.69 9.31 15.741

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.95 69.388

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 8.75 12.227

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.68 41.259

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 6.63 7.955

2-Methyl-2-butene 00513-35-9 14.20 6.51 92.459

n-Pentane 00109-66-0 1.21 5.80 7.045

t-2-Pentene 00646-04-8 10.47 5.17 54.128

Methylcyclopentane 00096-37-7 2.05 4.89 10.023

c-2-Pentene 00627-20-3 10.28 2.88 29.587

2,3,4-Trimethylpentane 00565-75-3 0.95 2.79 2.644

2-Methyl-1-butene 00563-46-2 6.38 2.61 16.619

ortho-Xylene 00095-47-6 7.58 2.50 18.977

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.17 6.934

2,4-Dimethylpentane 00108-08-7 1.46 2.16 3.155

2,3-Dimethylpentane 00565-59-3 1.25 2.08 2.600

2-Methylhexane 00591-76-4 1.09 1.85 2.008

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.83 8.034

t-2-Hexene 04050-45-7 8.55 1.76 15.011

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.52 17.837

2,3-Dimethylbutane 00079-29-8 0.90 1.52 1.367

3-Methyl-t-2-pentene 00616-12-6 11.66 1.41 16.427

n-Heptane 00142-82-5 0.97 1.26 1.219

Total 267.3 814.4 3.047

Vehicle 206b - Fuel 9 psi E0 - 105°F Static - Test 7545

Non Zero Mass Species Sorted By VOC
E-23

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 64.08 251.497

2-Methylbutane (Isopentane) 00078-78-4 1.35 26.84 36.363

n-Butane 00106-97-8 1.08 24.36 26.232

Ethanol 00064-17-5 1.45 20.34 29.475

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.47 112.251

Benzene 00071-43-2 0.69 14.46 10.043

n-Hexane 00110-54-3 1.13 12.90 14.640

Cyclohexane 00110-82-7 1.14 12.33 14.027

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.79 63.296

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 9.26 12.942

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.15 67.583

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 7.41 8.883

3-Methylpentane 00096-14-0 1.69 7.05 11.922

2,3-Dimethylbutane 00079-29-8 0.90 6.92 6.221

2-Methyl-2-butene 00513-35-9 14.20 5.98 84.864

1,3,5-Trimethylbenzene 00108-67-8 11.75 5.80 68.169

Methylcyclopentane 00096-37-7 2.05 5.38 11.030

n-Pentane 00109-66-0 1.21 5.37 6.527

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.99 21.931

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.33 50.669

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.75 19.859

c-2-Butene 00590-18-1 14.26 3.62 51.692

ortho-Xylene 00095-47-6 7.58 3.60 27.299

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.45 41.143

t-2-Pentene 00646-04-8 10.47 3.28 34.359

n-Propylbenzene 00103-65-1 1.96 3.27 6.414

2,2-DiMeHexane 00590-73-8 0.94 3.27 3.080

n-Heptane 00142-82-5 0.97 3.24 3.129

2,3,4-Trimethylpentane 00565-75-3 0.95 3.20 3.034

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.89 22.970

Indan 00496-11-7 3.23 2.83 9.149

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.74 8.729

Methylcyclohexane 00108-87-2 1.56 2.68 4.173

2-Methyl-1-butene 00563-46-2 6.38 2.68 17.071

Ethylbenzene 00100-41-4 2.96 2.61 7.747

2,3-Dimethylpentane 00565-59-3 1.25 2.59 3.228

2,2,5-Trimethylhexane 03522-94-9 1.05 2.54 2.674

2,4-Dimethylpentane 00108-08-7 1.46 2.27 3.306

2-Methylhexane 00591-76-4 1.09 2.24 2.435

Unknown #22 3.76 2.06 7.762

2-Methyl-2-pentene 00625-27-4 11.03 2.05 22.639

Cyclopentene 00142-29-0 6.69 1.87 12.476

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.72 11.343

c-2-Pentene 00627-20-3 10.28 1.51 15.533

Vehicle 206b - Fuel 9 psi E0 - Dynamic - Test 25775

Non Zero Mass Species Sorted By VOC
E-24

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 9 psi E0 - Dynamic - Test 25775

Non Zero Mass Species Sorted By VOC

3-Methyl-c-2-pentene 00922-62-3 12.52 1.49 18.609

t-2-Hexene 04050-45-7 8.55 1.42 12.172

3-Methyl-t-2-pentene 00616-12-6 11.66 1.24 14.404

2,2-Dimethylbutane 00075-83-2 1.11 1.22 1.350

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.16 6.454

n-Octane 00111-65-9 0.80 1.13 0.901

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.99 10.330

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.94 1.021

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.83 1.339

Methane 00074-82-8 0.01 0.50 0.007

Total 350.1 1316.4 3.760

No MIR available, use weighted average of 3.7602

continued
E-25

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 482.40 1893.416

2-Methylbutane (Isopentane) 00078-78-4 1.35 480.37 650.844

n-Butane 00106-97-8 1.08 442.07 476.067

Cyclohexane 00110-82-7 1.14 212.89 242.139

n-Hexane 00110-54-3 1.13 209.35 237.545

Ethanol 00064-17-5 1.45 189.89 275.142

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 139.65 195.200

Benzene 00071-43-2 0.69 117.42 81.533

2-Methyl-2-butene 00513-35-9 14.20 98.71 1401.233

3-Methylpentane 00096-14-0 1.69 94.97 160.588

n-Pentane 00109-66-0 1.21 85.36 103.713

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 82.11 98.461

Methylcyclopentane 00096-37-7 2.05 76.82 157.466

t-2-Pentene 00646-04-8 10.47 75.24 788.046

2,3-Dimethylbutane 00079-29-8 0.90 66.61 59.861

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 53.35 413.777

c-2-Pentene 00627-20-3 10.28 40.05 411.810

2-Methyl-1-butene 00563-46-2 6.38 39.72 253.383

2,3,4-Trimethylpentane 00565-75-3 0.95 34.59 32.824

2,4-Dimethylpentane 00108-08-7 1.46 31.16 45.466

2-Methylhexane 00591-76-4 1.09 29.55 32.072

2,3-Dimethylpentane 00565-59-3 1.25 28.32 35.350

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 28.01 89.386

t-2-Hexene 04050-45-7 8.55 26.19 223.900

Methylcyclohexane 00108-87-2 1.56 24.94 38.791

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 24.14 282.494

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 24.07 177.752

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 23.79 127.748

n-Heptane 00142-82-5 0.97 22.63 21.858

3-Methyl-t-2-pentene 00616-12-6 11.66 22.01 256.629

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 21.78 115.424

1-Methylcyclopentene 00693-89-0 12.45 20.29 252.744

Cyclopentene 00142-29-0 6.69 19.34 129.339

3-Methyl-c-2-pentene 00922-62-3 12.52 19.22 240.649

2-Methyl-2-pentene 00625-27-4 11.03 17.22 189.990

2,4-Dimethylhexane 00589-43-5 1.61 16.53 26.536

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 15.36 101.470

c-2-Butene 00590-18-1 14.26 14.11 201.260

ortho-Xylene 00095-47-6 7.58 13.88 105.180

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 11.63 18.678

2,2-DiMeHexane 00590-73-8 0.94 11.02 10.376

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.52 46.229

Ethylbenzene 00100-41-4 2.96 10.44 30.930

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 9.22 73.213

Vehicle 206b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7551

Non Zero Mass Species Sorted By VOC
E-26

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7551

Non Zero Mass Species Sorted By VOC

2,2-Dimethylbutane 00075-83-2 1.11 9.08 10.085

2,2,5-Trimethylhexane 03522-94-9 1.05 8.92 9.390

n-Octane 00111-65-9 0.80 8.35 6.647

1,3,5-Trimethylbenzene 00108-67-8 11.75 8.33 97.916

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.23 8.991

t-1,2-Dimethylcyclopentane 00822-50-4 3.09 7.69 23.786

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.20 39.925

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 6.84 39.518

c-1,3-Dimethylcyclopentane 02532-58-3 3.09 6.24 19.303

n-Propylbenzene 00103-65-1 1.96 5.57 10.911

3-Methylheptane 00589-81-1 1.12 5.23 5.876

2-Methylheptane 00592-27-8 0.97 5.03 4.870

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.89 30.472

2,2-Dimethylpentane 00590-35-2 1.04 3.87 4.038

3,3-Dimethylpentane 00562-49-2 1.12 3.73 4.175

2,2,3-Trimethylbutane 00464-06-2 1.05 3.60 3.798

c-1,3-Dimethylcyclohexane 00638-04-0 3.09 3.17 9.825

2-Methylpropane 00075-28-5 1.18 3.12 3.672

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.03 36.182

Unknown #5 3.09 2.11 6.544

c-2-Heptene 06443-92-1 7.08 2.11 14.958

Ethylcyclohexane 01678-91-7 1.35 2.02 2.715

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.97 7.620

Unknown #16 3.09 1.72 5.322

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.65 11.656

Isopropylbenzene (Cumene) 00098-82-8 3.09 1.60 4.963

2,3,5-Trimethylhexane 01069-53-0 1.12 1.56 1.748

1,3-Butadiene 00106-99-0 12.45 1.54 19.233

Indan 00496-11-7 3.23 1.46 4.717

t-3-Heptene 14686-14-7 6.17 1.43 8.832

1,4-Diethylbenzene 00105-05-5 4.39 1.41 6.209

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.35 14.151

Ethylene 00074-85-1 8.88 1.32 11.722

Unknown #8 3.09 1.30 4.009

t-1,4-Dimethylcyclohexane 02207-04-7 3.09 1.29 3.993

4-Methyloctane 02216-34-4 0.85 1.27 1.080

n-Nonane 00111-84-2 0.68 1.27 0.864

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.09 1.25 3.877

3,5-Dimethylheptane 00926-82-9 1.42 1.22 1.734

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.15 1.277

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.13 7.421

3,3-Dimethylhexane 00563-16-6 1.15 1.10 1.263

continued
E-27

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7551

Non Zero Mass Species Sorted By VOC

Unknown #13 3.09 1.10 3.390

2,4-Dimethylheptane 02213-23-2 1.26 1.09 1.382

3-Methyloctane 02216-33-3 0.88 1.07 0.950

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.03 8.638

1-Nonene 00124-11-8 2.49 0.95 2.364

4-Methyl-t-2-pentene 00674-76-0 8.04 0.91 7.338

1-Heptene 00592-76-7 4.29 0.82 3.498

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.81 0.690

Unknown #3 3.09 0.75 2.322

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.72 5.457

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.66 5.010

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.61 0.726

1,3-Diethylbenzene 00141-93-5 7.08 0.61 4.323

n-Decane 00124-18-5 0.59 0.61 0.360

Unknown #6 . 3.09 0.60 1.872

t-4-Octene 14850-23-8 4.69 0.55 2.561

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.50 4.857

sec-Butylbenzene 00135-98-8 2.29 0.48 1.111

3-Methylnonane 005911-04-6 0.66 0.44 0.287

t-2-Nonene 06434-78-2 3.09 0.33 1.012

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.28 1.056

Total 3677.3 11381.0 3.095

No MIR available, use weighted average of 3.0950

continued
E-28

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 15.58 61.151

n-Butane 00106-97-8 1.08 6.84 7.366

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.87 7.949

n-Hexane 00110-54-3 1.13 3.78 4.289

Cyclohexane 00110-82-7 1.14 3.76 4.273

Ethanol 00064-17-5 1.45 3.54 5.131

Benzene 00071-43-2 0.69 2.82 1.959

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.58 19.984

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.19 3.056

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.10 15.524

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.02 10.860

2-Methyl-2-butene 00513-35-9 14.20 1.67 23.717

t-2-Pentene 00646-04-8 10.47 1.65 17.267

n-Pentane 00109-66-0 1.21 1.54 1.867

3-Methylpentane 00096-14-0 1.69 1.38 2.341

Methylcyclopentane 00096-37-7 2.05 1.36 2.795

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.35 1.624

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.32 5.782

ortho-Xylene 00095-47-6 7.58 1.25 9.434

2,3-Dimethylbutane 00079-29-8 0.90 1.01 0.904

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.97 11.459

2,3,4-Trimethylpentane 00565-75-3 0.95 0.90 0.852

2-Methyl-1-butene 00563-46-2 6.38 0.74 4.693

c-2-Pentene 00627-20-3 10.28 0.70 7.167

2,3,5-Trimethylhexane 01069-53-0 1.12 0.61 0.679

2-Methylheptane 00592-27-8 0.97 0.59 0.566

t-2-Hexene 04050-45-7 8.55 0.57 4.910

3-Methyl-t-2-pentene 00616-12-6 11.66 0.52 6.070

2,4-Dimethylpentane 00108-08-7 1.46 0.51 0.744

2,4-Dimethylhexane 00589-43-5 1.61 0.49 0.789

Cyclopentene 00142-29-0 6.69 0.49 3.270

Ethylbenzene 00100-41-4 2.96 0.49 1.439

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.48 1.538

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.47 3.085

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.43 3.442

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.43 4.996

n-Propylbenzene 00103-65-1 1.96 0.40 0.791

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.40 4.801

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.39 2.161

Methylcyclohexane 00108-87-2 1.56 0.38 0.596

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.38 0.414

n-Heptane 00142-82-5 0.97 0.38 0.362

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.36 1.934

2-Methyl-2-pentene 00625-27-4 11.03 0.35 3.908

2,3-Dimethylpentane 00565-59-3 1.25 0.31 0.390

Vehicle 206b - Fuel 7 psi E0 - 86°F Static - Test 7561

Non Zero Mass Species Sorted By VOC
E-29

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E0 - 86°F Static - Test 7561

Non Zero Mass Species Sorted By VOC

2,2-DiMeHexane 00590-73-8 0.94 0.30 0.287

3-Methylheptane 00589-81-1 1.12 0.29 0.326

3-Methyl-c-2-pentene 00922-62-3 12.52 0.26 3.292

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.25 0.395

n-Octane 00111-65-9 0.80 0.13 0.107

Indan 00496-11-7 3.23 0.12 0.388

2,2,5-Trimethylhexane 03522-94-9 1.05 0.09 0.100

c-2-Butene 00590-18-1 14.26 0.08 1.104

c-1,3-Dimethylcyclopentane 02532-58-3 3.65 0.06 0.235

t-1,2-Dimethylcyclopentane 00822-50-4 3.65 0.06 0.230

2-Methylhexane 00591-76-4 1.09 0.02 0.024

Total 78.0 284.8 3.651

No MIR available, use weighted average of 3.6506

continued
E-30

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 38.00 149.142

2-Methylbutane (Isopentane) 00078-78-4 1.35 19.36 26.230

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 18.15 134.070

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.53 112.710

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.41 77.345

Cyclohexane 00110-82-7 1.14 10.72 12.197

n-Butane 00106-97-8 1.08 10.60 11.418

n-Hexane 00110-54-3 1.13 9.62 10.917

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.96 8.332

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.36 23.532

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.71 55.405

t-2-Hexene 04050-45-7 8.55 4.53 38.693

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.38 5.253

3-Methylpentane 00096-14-0 1.69 4.29 7.258

ortho-Xylene 00095-47-6 7.58 4.10 31.052

Benzene 00071-43-2 0.69 4.08 2.834

2-Methyl-2-butene 00513-35-9 14.20 3.95 56.048

n-Pentane 00109-66-0 1.21 3.62 4.399

Methylcyclopentane 00096-37-7 2.05 3.55 7.277

t-2-Pentene 00646-04-8 10.47 2.90 30.371

2,3,4-Trimethylpentane 00565-75-3 0.95 2.10 1.990

2-Methyl-1-butene 00563-46-2 6.38 1.62 10.340

c-2-Pentene 00627-20-3 10.28 1.59 16.337

2-Methylhexane 00591-76-4 1.09 1.57 1.708

2,3-Dimethylpentane 00565-59-3 1.25 1.54 1.925

2,4-Dimethylpentane 00108-08-7 1.46 1.50 2.196

n-Heptane 00142-82-5 0.97 1.37 1.326

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.36 4.345

2,3-Dimethylbutane 00079-29-8 0.90 1.23 1.108

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.73 8.575

Total 201.5 854.3 4.241

Vehicle 206b - Fuel 7 psi E0 - 105°F Static - Test 7563

Non Zero Mass Species Sorted By VOC
E-31

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 52.27 205.169

2-Methylbutane (Isopentane) 00078-78-4 1.35 21.18 28.691

n-Butane 00106-97-8 1.08 17.56 18.909

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.14 86.374

Benzene 00071-43-2 0.69 10.11 7.019

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.16 49.186

n-Hexane 00110-54-3 1.13 8.99 10.198

Cyclohexane 00110-82-7 1.14 8.66 9.847

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.69 56.815

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 6.08 8.496

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.09 6.101

3-Methylpentane 00096-14-0 1.69 4.86 8.217

2,3-Dimethylbutane 00079-29-8 0.90 4.66 4.187

2-Methyl-2-butene 00513-35-9 14.20 4.53 64.340

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.27 18.778

n-Pentane 00109-66-0 1.21 4.27 5.185

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.25 49.992

Methylcyclopentane 00096-37-7 2.05 4.24 8.698

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.37 39.442

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.70 14.330

ortho-Xylene 00095-47-6 7.58 2.62 19.839

2,3,4-Trimethylpentane 00565-75-3 0.95 2.58 2.444

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.54 30.367

c-2-Butene 00590-18-1 14.26 2.49 35.498

2,2-DiMeHexane 00590-73-8 0.94 2.49 2.341

n-Heptane 00142-82-5 0.97 2.40 2.314

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.30 18.263

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.30 7.336

t-2-Pentene 00646-04-8 10.47 2.28 23.914

n-Propylbenzene 00103-65-1 1.96 2.19 4.300

Ethylbenzene 00100-41-4 2.96 2.13 6.323

Indan 00496-11-7 3.23 2.08 6.717

Methylcyclohexane 00108-87-2 1.56 2.04 3.168

2,2,5-Trimethylhexane 03522-94-9 1.05 1.99 2.097

2,3-Dimethylpentane 00565-59-3 1.25 1.96 2.444

2-Methyl-1-butene 00563-46-2 6.38 1.91 12.175

2-Methylhexane 00591-76-4 1.09 1.74 1.885

2,4-Dimethylpentane 00108-08-7 1.46 1.68 2.456

2-Methyl-2-pentene 00625-27-4 11.03 1.53 16.928

Unknown #22 . 3.96 1.44 5.705

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.40 9.255

Cyclopentene 00142-29-0 6.69 1.27 8.475

c-2-Pentene 00627-20-3 10.28 1.26 12.931

t-2-Hexene 04050-45-7 8.55 1.20 10.235

Vehicle 206b - Fuel 7 psi E0 - Dynamic - Test 25780

Non Zero Mass Species Sorted By VOC
E-32

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E0 - Dynamic - Test 25780

Non Zero Mass Species Sorted By VOC

3-Methyl-c-2-pentene 00922-62-3 12.52 1.13 14.097

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.00 5.542

3-Methyl-t-2-pentene 00616-12-6 11.66 0.91 10.619

2,2-Dimethylbutane 00075-83-2 1.11 0.90 0.997

n-Octane 00111-65-9 0.80 0.88 0.701

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.73 0.797

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.65 6.780

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.61 0.986

Total 249.7 987.9 3.956

No MIR available, use weighted average of 3.9564

continued
E-33

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 418.45 566.959

Toluene 00108-88-3 3.93 354.98 1393.317

n-Butane 00106-97-8 1.08 206.12 221.975

Cyclohexane 00110-82-7 1.14 199.31 226.692

n-Hexane 00110-54-3 1.13 164.51 186.670

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 118.19 165.211

Ethanol 00064-17-5 1.45 107.80 156.198

Benzene 00071-43-2 0.69 84.73 58.835

3-Methylpentane 00096-14-0 1.69 80.52 136.149

2-Methyl-2-butene 00513-35-9 14.20 75.59 1072.971

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 72.16 86.528

n-Pentane 00109-66-0 1.21 67.66 82.200

Methylcyclopentane 00096-37-7 2.05 63.94 131.069

2,3-Dimethylbutane 00079-29-8 0.90 57.89 52.025

t-2-Pentene 00646-04-8 10.47 55.50 581.294

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 42.28 327.932

2,3,4-Trimethylpentane 00565-75-3 0.95 31.57 29.955

2-Methyl-1-butene 00563-46-2 6.38 30.98 197.581

c-2-Pentene 00627-20-3 10.28 30.32 311.693

2,4-Dimethylpentane 00108-08-7 1.46 26.70 38.957

2-Methylhexane 00591-76-4 1.09 25.34 27.500

2,3-Dimethylpentane 00565-59-3 1.25 23.93 29.876

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 23.58 75.240

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 20.51 110.102

Methylcyclohexane 00108-87-2 1.56 20.37 31.681

t-2-Hexene 04050-45-7 8.55 19.96 170.626

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 18.36 214.937

3-Methyl-t-2-pentene 00616-12-6 11.66 17.54 204.459

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 17.54 92.912

n-Heptane 00142-82-5 0.97 17.48 16.882

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 16.23 119.835

1-Methylcyclopentene 00693-89-0 12.45 15.37 191.440

3-Methyl-c-2-pentene 00922-62-3 12.52 15.18 190.024

Cyclopentene 00142-29-0 6.69 14.82 99.067

2,4-Dimethylhexane 00589-43-5 1.61 14.18 22.763

2-Methyl-2-pentene 00625-27-4 11.03 14.12 155.789

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 12.02 79.430

ortho-Xylene 00095-47-6 7.58 11.39 86.265

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 10.87 17.454

c-2-Butene 00590-18-1 14.26 10.65 151.850

2,2-DiMeHexane 00590-73-8 0.94 9.27 8.730

2,2,5-Trimethylhexane 03522-94-9 1.05 8.74 9.207

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 8.43 37.046

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.27 9.027

Vehicle 206b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7567

Non Zero Mass Species Sorted By VOC
E-34

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7567

Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 8.16 24.176

2,2-Dimethylbutane 00075-83-2 1.11 7.90 8.782

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.86 54.489

1,3,5-Trimethylbenzene 00108-67-8 11.75 6.74 79.229

n-Octane 00111-65-9 0.80 6.54 5.207

t-1,2-Dimethylcyclopentane 00822-50-4 3.11 6.35 19.727

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 6.09 33.755

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 5.52 31.865

c-1,3-Dimethylcyclopentane 02532-58-3 3.11 5.27 16.373

2-Methylheptane 00592-27-8 0.97 4.81 4.654

3-Methylheptane 00589-81-1 1.12 4.54 5.110

n-Propylbenzene 00103-65-1 1.96 4.54 8.898

2,2-Dimethylpentane 00590-35-2 1.04 3.35 3.496

2,2,3-Trimethylbutane 00464-06-2 1.05 3.25 3.425

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.18 24.924

3,3-Dimethylpentane 00562-49-2 1.12 3.16 3.534

2-Methylpropane 00075-28-5 1.18 3.06 3.600

c-1,3-Dimethylcyclohexane 00638-04-0 3.11 2.75 8.529

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.49 29.713

Unknown #5 3.11 1.98 6.152

2,3,5-Trimethylhexane 01069-53-0 1.12 1.89 2.120

Indan 00496-11-7 3.23 1.83 5.910

3,3-Dimethylhexane 00563-16-6 1.15 1.68 1.936

c-2-Heptene 06443-92-1 7.08 1.67 11.836

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.65 6.357

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.51 10.682

3,5-Dimethylheptane 00926-82-9 1.42 1.42 2.020

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.11 1.41 4.373

n-Decane 00124-18-5 0.59 1.33 0.787

Isopropylbenzene (Cumene) 00098-82-8 3.11 1.32 4.094

t-1,4-Dimethylcyclohexane 02207-04-7 3.11 1.20 3.724

t-3-Heptene 14686-14-7 6.17 1.19 7.312

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.13 1.265

Unknown #13 3.11 1.12 3.470

n-Nonane 00111-84-2 0.68 1.09 0.743

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.07 11.233

4-Methyloctane 02216-34-4 0.85 1.06 0.897

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.02 6.648

4-Methyl-t-2-pentene 00674-76-0 8.04 0.84 6.747

Unknown #16 3.11 0.81 2.525

1-Nonene 00124-11-8 2.49 0.80 1.983

1-Heptene 00592-76-7 4.29 0.77 3.322

continued
E-35

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 206b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7567

Non Zero Mass Species Sorted By VOC

2,4-Dimethylheptane 02213-23-2 1.26 0.76 0.956

Unknown #3 3.11 0.74 2.297

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.73 6.103

3-Methylnonane 005911-04-6 0.66 0.72 0.470

3-Methyloctane 02216-33-3 0.88 0.67 0.593

Unknown #8 3.11 0.58 1.812

t-4-Octene 14850-23-8 4.69 0.50 2.360

Unknown #6 . 3.11 0.46 1.413

1,3-Diethylbenzene 00141-93-5 7.08 0.45 3.221

sec-Butylbenzene 00135-98-8 2.29 0.45 1.028

1,4-Diethylbenzene 00105-05-5 4.39 0.45 1.964

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.43 4.156

Isobutylbenzene 00538-93-2 3.11 0.42 1.320

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.40 1.538

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.38 2.877

t-2-Nonene 06434-78-2 3.11 0.38 1.168

c-2-Octene 07642-04-8 3.11 0.32 0.981

Unknown #9 3.11 0.26 0.798

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.23 0.194

Total 2797.0 8687.2 3.106

No MIR available, use weighted average of 3.1059

continued
E-36

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7413 75.6 127.7 96.6 413.8 4.284 42

Static E10 - 7 psi 7478 50.5 102.6 51.9 136.0 2.623 40

E0 - 9 psi 7530 74.2 121.3 90.0 287.6 3.195 52

E0 - 7 psi 7568 49.6 102.0 50.6 159.2 3.146 55

105° F E10 - 10 psi 7415 115.2 110.4 127.1 415.6 3.268 59

Static E10 - 7 psi 7480 105.4 104.1 109.7 391.9 3.572 76

E0 - 9 psi 7532 112.7 102.4 115.4 370.1 3.207 60

E0 - 7 psi 7570 123.9 94.4 117.0 403.3 3.448 63

Dynamic E10 - 10 psi 25744 337.0 95.8 322.8 1369.5 4.242 56

E10 - 7 psi 25759 308.3 132.8 409.4 1718.9 4.198 72

E0 - 9 psi 25771 257.5 159.1 409.6 1853.2 4.524 52

E0 - 7 psi 25782 199.7 51.9 103.6 353.6 3.413 40

DHB E10 - 10 psi 7463 1852.2 103.6 1919.2 5628.6 2.933 107

Total E10 - 7 psi 7489 1740.5 89.3 1554.4 5099.2 3.281 107

E0 - 9 psi 7556 1864.6 93.2 1737.6 4606.5 2.651 98

E0 - 7 psi 7575 1317.5 88.6 1167.2 3392.4 2.906 86

Vehicle 208b
E-37

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 11.06 43.423

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.50 51.027

Ethanol 00064-17-5 1.45 8.80 12.744

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.88 58.214

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.52 50.528

2,3,4-Trimethylpentane 00565-75-3 0.95 6.12 5.809

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.78 7.827

n-Butane 00106-97-8 1.08 4.61 4.969

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.24 14.225

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.10 36.422

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.81 15.597

n-Hexane 00110-54-3 1.13 2.69 3.057

ortho-Xylene 00095-47-6 7.58 2.58 19.561

Methylcyclopentane 00096-37-7 2.05 1.93 3.948

Benzene 00071-43-2 0.69 1.76 1.221

n-Propylbenzene 00103-65-1 1.96 1.58 3.099

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.45 1.744

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.44 17.177

Ethylbenzene 00100-41-4 2.96 1.24 3.660

n-Pentane 00109-66-0 1.21 1.19 1.449

Cyclohexane 00110-82-7 1.14 1.18 1.343

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.11 1.548

2-Methyl-2-butene 00513-35-9 14.20 1.04 14.692

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.94 1.514

3-Methylpentane 00096-14-0 1.69 0.88 1.490

3-Methyl-t-2-pentene 00616-12-6 11.66 0.74 8.623

t-2-Pentene 00646-04-8 10.47 0.59 6.160

Methylcyclohexane 00108-87-2 1.56 0.54 0.834

n-Heptane 00142-82-5 0.97 0.49 0.475

2-Methyl-1-butene 00563-46-2 6.38 0.44 2.778

2-Methylpropane 00075-28-5 1.18 0.42 0.489

n-Octane 00111-65-9 0.80 0.41 0.327

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.38 4.469

3-Methyl-c-2-pentene 00922-62-3 12.52 0.37 4.629

2-Methylhexane 00591-76-4 1.09 0.35 0.379

t-2-Hexene 04050-45-7 8.55 0.31 2.689

c-2-Pentene 00627-20-3 10.28 0.29 2.966

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.26 0.845

2,3-Dimethylpentane 00565-59-3 1.25 0.25 0.309

2,2,5-Trimethylhexane 03522-94-9 1.05 0.17 0.176

c-2-Butene 00590-18-1 14.26 0.09 1.292

2,4-Dimethylpentane 00108-08-7 1.46 0.08 0.123

Total 96.6 413.8 4.284

Vehicle 208b - Fuel 10 psi E10 - 86°F Static - Test 7413

Non Zero Mass Species Sorted By VOC
E-38

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 23.14 33.536

Toluene 00108-88-3 3.93 19.45 76.343

2-Methylbutane (Isopentane) 00078-78-4 1.35 10.42 14.119

n-Butane 00106-97-8 1.08 7.49 8.064

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.05 27.126

n-Hexane 00110-54-3 1.13 4.57 5.181

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.70 28.705

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.14 4.383

Benzene 00071-43-2 0.69 2.84 1.974

n-Pentane 00109-66-0 1.21 2.46 2.983

2-Methyl-2-butene 00513-35-9 14.20 2.36 33.500

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.17 2.601

t-2-Pentene 00646-04-8 10.47 1.99 20.809

3-Methylpentane 00096-14-0 1.69 1.90 3.216

Methylcyclopentane 00096-37-7 2.05 1.69 3.469

2,3-Dimethylbutane 00079-29-8 0.90 1.63 1.468

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.59 18.644

Methylcyclohexane 00108-87-2 1.56 1.55 2.413

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.50 8.314

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.50 6.592

n-Heptane 00142-82-5 0.97 1.49 1.436

Cyclohexane 00110-82-7 1.14 1.39 1.584

2-Methylhexane 00591-76-4 1.09 1.27 1.376

ortho-Xylene 00095-47-6 7.58 1.22 9.263

2-Methylpropane 00075-28-5 1.18 1.21 1.422

2-Methyl-1-butene 00563-46-2 6.38 1.14 7.282

c-2-Pentene 00627-20-3 10.28 1.03 10.608

2,2-DiMeHexane 00590-73-8 0.94 0.98 0.922

2,3,4-Trimethylpentane 00565-75-3 0.95 0.97 0.920

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.95 3.018

2,3-Dimethylpentane 00565-59-3 1.25 0.84 1.051

3-Methylheptane 00589-81-1 1.12 0.79 0.889

n-Octane 00111-65-9 0.80 0.77 0.616

n-Decane 00124-18-5 0.59 0.77 0.455

Cyclopentene 00142-29-0 6.69 0.77 5.133

n-Propylbenzene 00103-65-1 1.96 0.76 1.488

2,4-Dimethylpentane 00108-08-7 1.46 0.72 1.053

Ethylbenzene 00100-41-4 2.96 0.65 1.934

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.65 7.749

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.64 7.434

t-2-Hexene 04050-45-7 8.55 0.63 5.402

2,3,5-Trimethylhexane 01069-53-0 1.12 0.60 0.677

2,4-Dimethylhexane 00589-43-5 1.61 0.58 0.937

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.56 2.979

Vehicle 208b - Fuel 10 psi E10 - 105°F Static - Test 7424

Non Zero Mass Species Sorted By VOC
E-39

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 10 psi E10 - 105°F Static - Test 7424

Non Zero Mass Species Sorted By VOC

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.54 3.538

c-2-Butene 00590-18-1 14.26 0.53 7.599

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.52 4.101

3-Methyl-c-2-pentene 00922-62-3 12.52 0.50 6.302

t-1,2-Dimethylcyclopentane 00822-50-4 3.27 0.48 1.564

n-Nonane 00111-84-2 0.68 0.44 0.301

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.41 0.653

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.39 2.790

3-Methyl-t-2-pentene 00616-12-6 11.66 0.36 4.246

2-Methyl-2-pentene 00625-27-4 11.03 0.33 3.663

2,2,5-Trimethylhexane 03522-94-9 1.05 0.32 0.336

2-Methylheptane 00592-27-8 0.97 0.27 0.260

c-1,3-Dimethylcyclopentane 02532-58-3 3.27 0.26 0.858

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.19 0.208

2,2-Dimethylbutane 00075-83-2 1.11 0.07 0.081

Total 127.1 415.6 3.268

No MIR available, use weighted average of 3.2684

continued
E-40

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 43.48 170.672

n-Propylbenzene 00103-65-1 1.96 31.22 61.185

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 28.49 152.962

Ethanol 00064-17-5 1.45 20.14 29.185

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 19.58 144.613

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.37 88.165

n-Butane 00106-97-8 1.08 10.88 11.720

1,3,5-Trimethylbenzene 00108-67-8 11.75 10.32 121.351

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.53 41.872

2-Methylbutane (Isopentane) 00078-78-4 1.35 8.30 11.251

n-Hexane 00110-54-3 1.13 8.20 9.301

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.69 42.632

Benzene 00071-43-2 0.69 7.47 5.186

2-Methylpropane 00075-28-5 1.18 7.08 8.325

n-Decane 00124-18-5 0.59 6.26 3.702

1,2,3-Trimethylbenzene 00526-73-8 11.94 5.96 71.104

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.97 39.448

ortho-Xylene 00095-47-6 7.58 4.95 37.537

Unknown #22 4.24 4.48 19.024

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.38 5.256

1,3-Butadiene 00106-99-0 12.45 3.93 48.972

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.62 5.061

2,3-Dimethylbutane 00079-29-8 0.90 3.47 3.114

Indan 00496-11-7 3.23 3.32 10.737

n-Octane 00111-65-9 0.80 3.11 2.478

3-Methylpentane 00096-14-0 1.69 2.93 4.958

Methylcyclohexane 00108-87-2 1.56 2.75 4.275

n-Nonane 00111-84-2 0.68 2.74 1.872

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.64 18.726

t-2-Pentene 00646-04-8 10.47 2.62 27.487

2,3,5-Trimethylhexane 01069-53-0 1.12 2.52 2.818

2,4-Dimethylhexane 00589-43-5 1.61 2.47 3.970

Methylcyclopentane 00096-37-7 2.05 2.19 4.493

Cyclohexane 00110-82-7 1.14 2.11 2.394

Ethylbenzene 00100-41-4 2.96 2.10 6.233

t-2-Hexene 04050-45-7 8.55 1.82 15.585

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.74 20.334

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.64 1.786

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.63 2.611

n-Pentane 00109-66-0 1.21 1.60 1.946

2,3,4-Trimethylpentane 00565-75-3 0.95 1.54 1.465

2-Methylheptane 00592-27-8 0.97 1.39 1.340

2,3-Dimethylpentane 00565-59-3 1.25 1.35 1.687

2-Methyl-2-pentene 00625-27-4 11.03 1.30 14.366

Vehicle 208b - Fuel 10 psi E10 - Dynamic - Test 25744

Non Zero Mass Species Sorted By VOC
E-41

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 10 psi E10 - Dynamic - Test 25744

Non Zero Mass Species Sorted By VOC

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.22 3.888

3-Methyl-t-2-pentene 00616-12-6 11.66 1.19 13.917

c-2-Butene 00590-18-1 14.26 1.18 16.826

3-Methyl-c-2-pentene 00922-62-3 12.52 1.15 14.398

c-2-Pentene 00627-20-3 10.28 1.13 11.662

2-Methyl-1-butene 00563-46-2 6.38 1.11 7.093

n-Heptane 00142-82-5 0.97 1.02 0.987

2-Methylhexane 00591-76-4 1.09 0.95 1.034

2,2,5-Trimethylhexane 03522-94-9 1.05 0.95 1.002

Cyclopentene 00142-29-0 6.69 0.78 5.200

2-Methyl-2-butene 00513-35-9 14.20 0.71 10.103

2,4-Dimethylpentane 00108-08-7 1.46 0.11 0.162

Total 322.8 1369.5 4.242

No MIR available, use weighted average of 4.2422

continued
E-42

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 304.65 441.435

n-Butane 00106-97-8 1.08 222.82 239.960

Toluene 00108-88-3 3.93 203.31 798.007

2-Methylbutane (Isopentane) 00078-78-4 1.35 151.53 205.313

n-Hexane 00110-54-3 1.13 127.32 144.463

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 67.88 94.875

3-Methylpentane 00096-14-0 1.69 49.21 83.206

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 48.37 58.050

2-Methyl-2-butene 00513-35-9 14.20 45.52 646.141

Benzene 00071-43-2 0.69 44.28 30.747

n-Pentane 00109-66-0 1.21 40.33 48.994

t-2-Pentene 00646-04-8 10.47 38.38 401.979

Methylcyclopentane 00096-37-7 2.05 34.84 71.406

Cyclohexane 00110-82-7 1.14 32.56 37.029

2,3-Dimethylbutane 00079-29-8 0.90 26.99 24.254

n-Propylbenzene 00103-65-1 1.96 21.68 42.492

Methylcyclohexane 00108-87-2 1.56 21.43 33.332

2,3,4-Trimethylpentane 00565-75-3 0.95 21.05 19.972

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.11 155.988

n-Heptane 00142-82-5 0.97 20.08 19.391

c-2-Pentene 00627-20-3 10.28 19.50 200.531

2-Methylhexane 00591-76-4 1.09 19.22 20.858

2-Methyl-1-butene 00563-46-2 6.38 18.36 117.083

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 17.73 56.577

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 16.26 87.281

2,4-Dimethylpentane 00108-08-7 1.46 14.54 21.214

t-2-Hexene 04050-45-7 8.55 12.79 109.358

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.98 140.179

n-Octane 00111-65-9 0.80 10.30 8.203

2,3-Dimethylpentane 00565-59-3 1.25 10.15 12.665

2,4-Dimethylhexane 00589-43-5 1.61 9.90 15.898

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 9.78 51.836

3-Methyl-t-2-pentene 00616-12-6 11.66 9.52 111.028

1-Methylcyclopentene 00693-89-0 12.45 8.82 109.908

3-Methyl-c-2-pentene 00922-62-3 12.52 8.70 108.885

2-Methyl-2-pentene 00625-27-4 11.03 7.77 85.668

c-2-Butene 00590-18-1 14.26 7.76 110.587

Cyclopentene 00142-29-0 6.69 7.56 50.547

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 7.19 11.539

2,2,5-Trimethylhexane 03522-94-9 1.05 7.05 7.428

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.97 46.030

1,3,5-Trimethylbenzene 00108-67-8 11.75 6.90 81.131

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 6.69 29.395

ortho-Xylene 00095-47-6 7.58 6.06 45.874

Vehicle 208b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7463

Non Zero Mass Species Sorted By VOC
E-43

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7463

Non Zero Mass Species Sorted By VOC

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 6.04 33.447

2,2-DiMeHexane 00590-73-8 0.94 5.82 5.476

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 5.58 6.095

2-Methylheptane 00592-27-8 0.97 5.35 5.177

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.30 42.092

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.84 35.784

3-Methylheptane 00589-81-1 1.12 4.34 4.885

t-1,2-Dimethylcyclopentane 00822-50-4 2.93 4.26 12.501

Ethylbenzene 00100-41-4 2.96 4.03 11.926

c-1,3-Dimethylcyclohexane 00638-04-0 2.93 3.64 10.664

c-1,3-Dimethylcyclopentane 02532-58-3 2.93 3.42 10.033

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.34 19.320

n-Nonane 00111-84-2 0.68 3.07 2.099

2,2-Dimethylpentane 00590-35-2 1.04 3.03 3.159

2,2-Dimethylbutane 00075-83-2 1.11 2.92 3.248

Unknown #16 2.93 2.90 8.514

3,3-Dimethylpentane 00562-49-2 1.12 2.57 2.870

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.40 28.710

n-Decane 00124-18-5 0.59 2.35 1.391

Ethylcyclohexane 01678-91-7 1.35 2.00 2.687

2,2,3-Trimethylbutane 00464-06-2 1.05 1.88 1.980

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.85 14.502

4-Methyloctane 02216-34-4 0.85 1.74 1.474

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.62 6.275

1,4-Diethylbenzene 00105-05-5 4.39 1.56 6.852

t-1,4-Dimethylcyclohexane 02207-04-7 2.93 1.52 4.444

Indan 00496-11-7 3.23 1.39 4.500

3,3-Dimethylhexane 00563-16-6 1.15 1.27 1.464

2,3,5-Trimethylhexane 01069-53-0 1.12 1.26 1.414

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.25 8.853

Unknown #8 2.93 1.25 3.659

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.93 1.24 3.644

Unknown #5 2.93 1.22 3.565

c-2-Heptene 06443-92-1 7.08 1.20 8.479

3-Methyloctane 02216-33-3 0.88 1.11 0.979

Unknown #13 2.93 1.07 3.130

3,5-Dimethylheptane 00926-82-9 1.42 1.05 1.494

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.92 1.027

Isopropylbenzene (Cumene) 00098-82-8 2.93 0.89 2.597

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.88 1.044

1,3-Butadiene 00106-99-0 12.45 0.84 10.453

2,4-Dimethylheptane 02213-23-2 1.26 0.79 1.004

continued
E-44

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7463

Non Zero Mass Species Sorted By VOC

t-3-Heptene 14686-14-7 6.17 0.79 4.845

sec-Butylbenzene 00135-98-8 2.29 0.73 1.683

1-Nonene 00124-11-8 2.49 0.70 1.755

2,2-Dimethyloctane 15869-87-1 0.76 0.70 0.532

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.57 6.012

1,3-Diethylbenzene 00141-93-5 7.08 0.57 4.028

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.55 3.571

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.52 3.891

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.51 4.271

Isobutylbenzene 00538-93-2 2.93 0.50 1.477

1-Heptene 00592-76-7 4.29 0.49 2.099

Unknown #9 2.93 0.47 1.382

t-2-Nonene 06434-78-2 2.93 0.47 1.372

4-Methyl-t-2-pentene 00674-76-0 8.04 0.41 3.270

c- & t-4-Nonene 02198-23-4 4.42 0.39 1.703

Unknown #15 2.93 0.38 1.113

Unknown #3 2.93 0.35 1.025

Unknown #14 2.93 0.35 1.017

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.34 1.295

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.31 0.267

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.24 2.389

Total 1919.2 5628.6 2.933

No MIR available, use weighted average of 2.9328

continued
E-45

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 13.42 19.440

Toluene 00108-88-3 3.93 12.66 49.684

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.73 7.768

n-Butane 00106-97-8 1.08 4.23 4.558

n-Pentane 00109-66-0 1.21 1.94 2.362

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.44 10.670

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.27 1.777

2,4-Dimethylpentane 00108-08-7 1.46 1.10 1.611

2,3-Dimethylbutane 00079-29-8 0.90 1.00 0.899

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.90 1.080

Unknown #16 2.62 0.57 1.507

2,3,4-Trimethylpentane 00565-75-3 0.95 0.57 0.540

n-Decane 00124-18-5 0.59 0.54 0.317

n-Hexane 00110-54-3 1.13 0.52 0.591

c-2-Butene 00590-18-1 14.26 0.52 7.382

3-Methylpentane 00096-14-0 1.69 0.45 0.768

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.39 4.539

t-2-Pentene 00646-04-8 10.47 0.38 3.958

2-Methylhexane 00591-76-4 1.09 0.36 0.387

Indan 00496-11-7 3.23 0.32 1.041

2,4-Dimethylhexane 00589-43-5 1.61 0.32 0.515

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.31 1.203

2,3-Dimethylpentane 00565-59-3 1.25 0.28 0.350

Methylcyclopentane 00096-37-7 2.05 0.28 0.574

2,2,5-Trimethylhexane 03522-94-9 1.05 0.27 0.282

t-1,2-Dimethylcyclopentane 00822-50-4 2.62 0.27 0.696

2-Methyl-2-butene 00513-35-9 14.20 0.24 3.374

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.22 2.571

2-Methyl-1-butene 00563-46-2 6.38 0.21 1.355

3-Methylheptane 00589-81-1 1.12 0.20 0.220

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.19 0.209

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.18 0.777

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.17 1.190

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.10 0.640

Cyclopentene 00142-29-0 6.69 0.09 0.619

2,2-Dimethylbutane 00075-83-2 1.11 0.08 0.092

2,3,5-Trimethylhexane 01069-53-0 1.12 0.06 0.072

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.05 0.083

c-2-Pentene 00627-20-3 10.28 0.03 0.315

ortho-Xylene 00095-47-6 7.58 0.00 0.018

Total 51.9 136.0 2.623

No MIR available, use weighted average of 2.6226

Vehicle 208b - Fuel 7 psi E10 - 86°F Static - Test 7466

Non Zero Mass Species Sorted By VOC
E-46

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 18.17 26.321

Toluene 00108-88-3 3.93 15.73 61.725

n-Hexane 00110-54-3 1.13 6.45 7.317

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.34 7.233

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.62 5.056

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.34 24.682

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.99 16.036

n-Butane 00106-97-8 1.08 2.46 2.653

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.25 2.693

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.15 16.664

2-Methyl-2-butene 00513-35-9 14.20 2.05 29.124

3-Methylpentane 00096-14-0 1.69 1.99 3.370

Methylcyclopentane 00096-37-7 2.05 1.92 3.928

t-2-Pentene 00646-04-8 10.47 1.85 19.379

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.82 21.352

n-Pentane 00109-66-0 1.21 1.77 2.153

Benzene 00071-43-2 0.69 1.70 1.178

2-Methylpropane 00075-28-5 1.18 1.58 1.861

Cyclohexane 00110-82-7 1.14 1.48 1.687

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.41 6.191

Unknown #16 3.57 1.38 4.935

2-Methylhexane 00591-76-4 1.09 1.34 1.449

2,3-Dimethylbutane 00079-29-8 0.90 1.33 1.199

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.14 6.292

Methylcyclohexane 00108-87-2 1.56 1.07 1.661

1-Methylcyclopentene 00693-89-0 12.45 0.99 12.341

2,4-Dimethylpentane 00108-08-7 1.46 0.94 1.373

t-1,2-Dimethylcyclopentane 00822-50-4 3.57 0.92 3.274

2-Methyl-1-butene 00563-46-2 6.38 0.88 5.614

ortho-Xylene 00095-47-6 7.58 0.84 6.374

2,3,5-Trimethylhexane 01069-53-0 1.12 0.80 0.891

c-1,3-Dimethylcyclohexane 00638-04-0 3.57 0.79 2.834

2,3,4-Trimethylpentane 00565-75-3 0.95 0.73 0.690

c-2-Pentene 00627-20-3 10.28 0.72 7.413

n-Heptane 00142-82-5 0.97 0.69 0.665

t-2-Hexene 04050-45-7 8.55 0.68 5.813

3-Methylheptane 00589-81-1 1.12 0.64 0.720

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.62 7.437

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.58 1.862

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.58 6.822

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.58 0.629

2-Methylheptane 00592-27-8 0.97 0.55 0.536

4-Methyloctane 02216-34-4 0.85 0.53 0.450

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.52 3.403

Vehicle 208b - Fuel 7 psi E10 - 105°F Static - Test 7480

Non Zero Mass Species Sorted By VOC
E-47

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E10 - 105°F Static - Test 7480

Non Zero Mass Species Sorted By VOC

c-2-Butene 00590-18-1 14.26 0.51 7.328

2,3-Dimethylpentane 00565-59-3 1.25 0.50 0.630

2,2-Dimethylpentane 00590-35-2 1.04 0.48 0.499

Unknown #18 3.57 0.47 1.664

3-Methyl-t-2-pentene 00616-12-6 11.66 0.46 5.406

2-Methyl-2-pentene 00625-27-4 11.03 0.42 4.603

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.41 2.389

n-Octane 00111-65-9 0.80 0.40 0.322

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.634

Isopropylbenzene (Cumene) 00098-82-8 3.57 0.38 1.368

1,4-Diethylbenzene 00105-05-5 4.39 0.38 1.657

n-Propylbenzene 00103-65-1 1.96 0.37 0.730

n-Decane 00124-18-5 0.59 0.37 0.220

Indan 00496-11-7 3.23 0.35 1.130

Cyclopentene 00142-29-0 6.69 0.33 2.238

2,2-DiMeHexane 00590-73-8 0.94 0.33 0.314

c-1,3-Dimethylcyclopentane 02532-58-3 3.57 0.32 1.141

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.31 1.186

2,2,5-Trimethylhexane 03522-94-9 1.05 0.30 0.311

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.29 2.183

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.28 1.474

t-1,4-Dimethylcyclohexane 02207-04-7 3.57 0.25 0.907

Unknown #1 3.57 0.24 0.852

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.23 0.875

3,3-Dimethyl-1-butene 00558-37-2 5.68 0.20 1.115

Ethylbenzene 00100-41-4 2.96 0.20 0.579

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.18 1.836

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.17 1.302

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.13 1.041

2,4-Dimethylhexane 00589-43-5 1.61 0.10 0.156

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.08 0.539

2,2-Dimethylbutane 00075-83-2 1.11 0.02 0.024

Total 109.7 391.9 3.572

No MIR available, use weighted average of 3.5716

continued
E-48

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 44.29 47.694

Toluene 00108-88-3 3.93 40.01 157.028

Ethanol 00064-17-5 1.45 31.03 44.959

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 29.45 217.541

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 18.29 98.224

2-Methylbutane (Isopentane) 00078-78-4 1.35 15.90 21.542

n-Hexane 00110-54-3 1.13 13.82 15.678

Benzene 00071-43-2 0.69 10.84 7.524

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.61 42.209

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.62 66.887

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 8.37 98.005

1,3,5-Trimethylbenzene 00108-67-8 11.75 8.19 96.312

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 7.91 11.057

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.39 40.969

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 7.01 8.406

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.29 49.968

2-Methyl-2-butene 00513-35-9 14.20 5.96 84.605

3-Methylpentane 00096-14-0 1.69 5.74 9.698

n-Pentane 00109-66-0 1.21 5.51 6.698

2,3,3-Trimethylpentane 00560-21-4 0.95 5.46 5.168

2,3-Dimethylbutane 00079-29-8 0.90 5.31 4.771

n-Decane 00124-18-5 0.59 5.12 3.023

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.79 37.502

Cyclohexane 00110-82-7 1.14 4.17 4.739

Ethylbenzene 00100-41-4 2.96 4.06 12.017

Methylcyclopentane 00096-37-7 2.05 3.85 7.900

t-2-Pentene 00646-04-8 10.47 3.84 40.194

Cyclopentene 00142-29-0 6.69 3.69 24.647

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.67 23.104

Unknown #23 4.20 3.63 15.257

c-2-Pentene 00627-20-3 10.28 3.60 37.032

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 3.53 15.550

n-Propylbenzene 00103-65-1 1.96 3.49 6.849

2-Methyl-1-butene 00563-46-2 6.38 3.49 22.291

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.44 10.991

1,3-Butadiene 00106-99-0 12.45 3.15 39.249

c-2-Butene 00590-18-1 14.26 3.08 43.992

ortho-Xylene 00095-47-6 7.58 3.03 22.950

2,4-Dimethylhexane 00589-43-5 1.61 2.76 4.427

3-Methyl-c-2-pentene 00922-62-3 12.52 2.67 33.377

Unknown #16 4.20 2.52 10.589

n-Octane 00111-65-9 0.80 2.39 1.907

Ethane 00074-84-0 0.26 2.39 0.628

t-2-Hexene 04050-45-7 8.55 2.15 18.343

Vehicle 208b - Fuel 7 psi E10 - Dynamic - Test 25759

Non Zero Mass Species Sorted By VOC
E-49

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E10 - Dynamic - Test 25759

Non Zero Mass Species Sorted By VOC

2-Methylhexane 00591-76-4 1.09 2.08 2.261

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.08 14.750

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.03 3.261

1-Octene 00111-66-0 3.14 1.97 6.182

3-Methylheptane 00589-81-1 1.12 1.74 1.959

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.65 8.720

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.59 6.140

3-Methyl-t-2-pentene 00616-12-6 11.66 1.56 18.216

2,3,5-Trimethylhexane 01069-53-0 1.12 1.52 1.704

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.46 1.593

Indan 00496-11-7 3.23 1.41 4.569

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.37 9.083

2,3-Dimethylpentane 00565-59-3 1.25 1.32 1.646

2-Methyl-2-pentene 00625-27-4 11.03 1.31 14.479

2,2-DiMeHexane 00590-73-8 0.94 1.26 1.190

1-Methyl-2-Propylbenzene 01074-17-5 5.43 1.17 6.364

c-2-Heptene 06443-92-1 7.08 1.16 8.215

n-Nonane 00111-84-2 0.68 1.16 0.791

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.15 12.008

4-Methyloctane 02216-34-4 0.85 1.03 0.871

2,2-Dimethylbutane 00075-83-2 1.11 0.97 1.073

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.94 1.108

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.84 6.332

t-1,2-Dimethylcyclopentane 00822-50-4 4.20 0.84 3.506

Unknown #18 4.20 0.79 3.313

1,3-Diethylbenzene 00141-93-5 7.08 0.57 4.023

Cyclopentadiene 00542-92-7 6.89 0.53 3.622

2,2-Dimethylpentane 00590-35-2 1.04 0.40 0.421

Total 409.4 1718.9 4.198

No MIR available, use weighted average of 4.1985

continued
E-50

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 272.11 394.281

Toluene 00108-88-3 3.93 180.22 707.380

2-Methylbutane (Isopentane) 00078-78-4 1.35 131.81 178.590

n-Hexane 00110-54-3 1.13 115.21 130.730

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 59.52 83.203

Benzene 00071-43-2 0.69 47.52 32.995

3-Methylpentane 00096-14-0 1.69 43.72 73.931

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 43.69 52.394

2-Methyl-2-butene 00513-35-9 14.20 40.42 573.824

n-Pentane 00109-66-0 1.21 36.90 44.826

t-2-Pentene 00646-04-8 10.47 35.21 368.761

n-Butane 00106-97-8 1.08 34.54 37.199

Methylcyclopentane 00096-37-7 2.05 31.08 63.707

Cyclohexane 00110-82-7 1.14 29.67 33.748

2,3-Dimethylbutane 00079-29-8 0.90 23.40 21.034

2,3,3-Trimethylpentane 00560-21-4 0.95 20.16 19.061

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 19.18 120.861

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 18.65 144.643

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 18.28 143.250

c-2-Pentene 00627-20-3 10.28 17.84 183.408

2-Methylhexane 00591-76-4 1.09 17.45 18.938

2-Methyl-1-butene 00563-46-2 6.38 16.93 108.012

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 15.35 48.985

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.64 108.113

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 13.76 73.861

2,4-Dimethylpentane 00108-08-7 1.46 12.81 18.699

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.54 135.123

t-2-Hexene 04050-45-7 8.55 11.24 96.084

n-Octane 00111-65-9 0.80 9.92 7.899

2,4-Dimethylhexane 00589-43-5 1.61 9.52 15.290

2,3-Dimethylpentane 00565-59-3 1.25 9.08 11.339

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.60 45.544

3-Methyl-c-2-pentene 00922-62-3 12.52 8.60 107.599

3-Methyl-t-2-pentene 00616-12-6 11.66 8.35 97.416

c-2-Butene 00590-18-1 14.26 7.37 105.100

1-Octene 00111-66-0 3.14 7.22 22.695

2-Methyl-2-pentene 00625-27-4 11.03 7.10 78.373

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 7.01 11.248

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.56 43.336

Cyclopentene 00142-29-0 6.69 6.46 43.182

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.78 45.866

ortho-Xylene 00095-47-6 7.58 5.45 41.303

1,3,5-Trimethylbenzene 00108-67-8 11.75 5.41 63.568

2,3,5-Trimethylhexane 01069-53-0 1.12 5.38 6.030

Vehicle 208b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7489

Non Zero Mass Species Sorted By VOC
E-51

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7489

Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.34 23.450

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 5.19 5.670

2,2-DiMeHexane 00590-73-8 0.94 4.77 4.492

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.67 25.903

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 4.58 17.712

2-Methylpropane 00075-28-5 1.18 4.38 5.158

3-Methylheptane 00589-81-1 1.12 4.17 4.688

t-1,2-Dimethylcyclopentane 00822-50-4 3.28 3.69 12.089

t-1,4-Dimethylcyclohexane 02207-04-7 3.28 3.40 11.162

n-Propylbenzene 00103-65-1 1.96 3.17 6.214

Ethylbenzene 00100-41-4 2.96 3.12 9.246

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.12 37.225

2,2-Dimethylpentane 00590-35-2 1.04 2.84 2.965

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.79 16.094

c-1,3-Dimethylcyclopentane 02532-58-3 3.28 2.58 8.449

2,2-Dimethylbutane 00075-83-2 1.11 2.52 2.800

n-Nonane 00111-84-2 0.68 2.45 1.671

Unknown #16 3.28 2.25 7.379

4-Methyloctane 02216-34-4 0.85 2.03 1.718

3,5-Dimethylheptane 00926-82-9 1.42 2.00 2.852

3,3-Dimethylpentane 00562-49-2 1.12 1.97 2.206

n-Decane 00124-18-5 0.59 1.90 1.125

Ethylene 00074-85-1 8.88 1.59 14.130

Ethane 00074-84-0 0.26 1.50 0.395

Unknown #13 3.28 1.46 4.783

2,2,3-Trimethylbutane 00464-06-2 1.05 1.39 1.470

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.26 8.930

Unknown #5 3.28 1.24 4.074

Indan 00496-11-7 3.23 1.12 3.633

3-Methyloctane 02216-33-3 0.88 1.00 0.883

Unknown #8 3.28 0.97 3.192

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.97 1.079

1,3-Butadiene 00106-99-0 12.45 0.95 11.892

1-Nonene 00124-11-8 2.49 0.93 2.313

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.28 0.92 3.015

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.90 0.767

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.86 1.021

3,3-Dimethylhexane 00563-16-6 1.15 0.85 0.984

t-4-Octene 14850-23-8 4.69 0.76 3.555

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.75 7.901

2,4-Dimethylheptane 02213-23-2 1.26 0.74 0.939

c-2-Heptene 06443-92-1 7.08 0.74 5.252

continued
E-52

1,3-Diethylbenzene 00141-93-5 7.08 0.72 5.097

Unknown #9 3.28 0.65 2.116

t-3-Heptene 14686-14-7 6.17 0.62 3.853

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.61 3.986

t-2-Nonene 06434-78-2 3.28 0.61 1.993

Isopropylbenzene (Cumene) 00098-82-8 3.28 0.59 1.950

1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.59 3.198

sec-Butylbenzene 00135-98-8 2.29 0.56 1.281

1,4-Diethylbenzene 00105-05-5 4.39 0.50 2.190

Unknown #14 3.28 0.49 1.613

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.45 1.734

4-Methyl-t-2-pentene 00674-76-0 8.04 0.43 3.493

Unknown #3 3.28 0.43 1.408

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.38 3.215

1-Heptene 00592-76-7 4.29 0.37 1.580

2,3,4-Trimethylpentane 00565-75-3 0.95 0.37 0.348

c- & t-4-Nonene 02198-23-4 4.42 0.33 1.465

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.32 2.411

Isobutylbenzene 00538-93-2 3.28 0.29 0.956

1-Methylcyclopentene 00693-89-0 12.45 0.26 3.247

3-Methylnonane 005911-04-6 0.66 0.23 0.149

Total 1554.4 5099.2 3.281

No MIR available, use weighted average of 3.2806

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7489

Non Zero Mass Species Sorted By VOC

continued
E-53

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 11.13 11.987

Toluene 00108-88-3 3.93 10.03 39.373

2-Methylbutane (Isopentane) 00078-78-4 1.35 7.82 10.589

Cyclohexane 00110-82-7 1.14 7.12 8.097

Ethanol 00064-17-5 1.45 4.65 6.745

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.56 33.649

n-Hexane 00110-54-3 1.13 3.83 4.349

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.46 4.149

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.82 3.936

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.29 17.789

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.76 9.464

Benzene 00071-43-2 0.69 1.75 1.215

2,3-Dimethylbutane 00079-29-8 0.90 1.74 1.567

3-Methylpentane 00096-14-0 1.69 1.72 2.901

Methylcyclopentane 00096-37-7 2.05 1.66 3.403

2,3,4-Trimethylpentane 00565-75-3 0.95 1.46 1.387

n-Pentane 00109-66-0 1.21 1.44 1.751

2-Methyl-2-butene 00513-35-9 14.20 1.18 16.745

2,4-Dimethylhexane 00589-43-5 1.61 1.16 1.864

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.09 6.016

t-2-Pentene 00646-04-8 10.47 1.06 11.079

2,4-Dimethylpentane 00108-08-7 1.46 0.89 1.305

2,2,5-Trimethylhexane 03522-94-9 1.05 0.89 0.933

2-Methylhexane 00591-76-4 1.09 0.81 0.875

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.77 3.377

t-2-Hexene 04050-45-7 8.55 0.76 6.477

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.74 8.746

3-Methyl-c-2-pentene 00922-62-3 12.52 0.66 8.273

n-Propylbenzene 00103-65-1 1.96 0.65 1.271

2,3-Dimethylpentane 00565-59-3 1.25 0.64 0.794

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.61 3.217

3-Methyl-t-2-pentene 00616-12-6 11.66 0.61 7.079

Unknown #22 3.19 0.56 1.792

2-Methyl-1-butene 00563-46-2 6.38 0.56 3.568

Ethylbenzene 00100-41-4 2.96 0.55 1.628

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.52 6.262

ortho-Xylene 00095-47-6 7.58 0.52 3.946

n-Heptane 00142-82-5 0.97 0.50 0.482

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.49 5.688

2-Methyl-2-pentene 00625-27-4 11.03 0.45 4.920

Indan 00496-11-7 3.23 0.44 1.436

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.44 1.400

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.43 2.840

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.43 0.469

Vehicle 208b - Fuel 9 psi E0 - 86°F Static - Test 7530

Non Zero Mass Species Sorted By VOC
E-54

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 9 psi E0 - 86°F Static - Test 7530

Non Zero Mass Species Sorted By VOC

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.618

3-Methylheptane 00589-81-1 1.12 0.38 0.427

2-Methylheptane 00592-27-8 0.97 0.34 0.329

c-2-Pentene 00627-20-3 10.28 0.31 3.189

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.30 2.403

Cyclopentene 00142-29-0 6.69 0.29 1.942

c-2-Butene 00590-18-1 14.26 0.26 3.711

2,2-Dimethylbutane 00075-83-2 1.11 0.12 0.132

Total 90.0 287.6 3.195

No MIR available, use weighted average of 3.1946

continued
E-55

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 15.66 61.452

n-Butane 00106-97-8 1.08 11.72 12.625

Cyclohexane 00110-82-7 1.14 9.05 10.291

2-Methylbutane (Isopentane) 00078-78-4 1.35 8.80 11.921

Ethanol 00064-17-5 1.45 8.28 11.996

n-Hexane 00110-54-3 1.13 4.60 5.215

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.91 4.690

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.64 28.201

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.52 4.921

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.12 16.775

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.86 21.113

Benzene 00071-43-2 0.69 2.49 1.726

3-Methylpentane 00096-14-0 1.69 2.40 4.061

2,3-Dimethylbutane 00079-29-8 0.90 2.00 1.800

2,3,4-Trimethylpentane 00565-75-3 0.95 1.83 1.733

Methylcyclopentane 00096-37-7 2.05 1.80 3.680

2-Methyl-2-butene 00513-35-9 14.20 1.69 24.058

n-Pentane 00109-66-0 1.21 1.64 1.991

t-2-Pentene 00646-04-8 10.47 1.47 15.391

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.31 5.735

ortho-Xylene 00095-47-6 7.58 1.28 9.660

2,4-Dimethylpentane 00108-08-7 1.46 1.19 1.744

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.06 12.427

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.98 5.183

2,4-Dimethylhexane 00589-43-5 1.61 0.92 1.480

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.80 9.383

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.79 4.386

2-Methylhexane 00591-76-4 1.09 0.78 0.847

2,3-Dimethylpentane 00565-59-3 1.25 0.70 0.868

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.68 1.089

Ethylbenzene 00100-41-4 2.96 0.67 1.986

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.67 2.135

2-Methyl-1-butene 00563-46-2 6.38 0.66 4.208

t-1,2-Dimethylcyclopentane 00822-50-4 3.21 0.66 2.105

c-2-Pentene 00627-20-3 10.28 0.65 6.727

2-Methylheptane 00592-27-8 0.97 0.64 0.622

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.63 7.474

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.62 4.125

2,2-Dimethylbutane 00075-83-2 1.11 0.61 0.683

2,2,5-Trimethylhexane 03522-94-9 1.05 0.59 0.625

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.55 0.602

t-2-Hexene 04050-45-7 8.55 0.54 4.582

n-Propylbenzene 00103-65-1 1.96 0.54 1.049

Cyclopentene 00142-29-0 6.69 0.49 3.274

Vehicle 208b - Fuel 9 psi E0 - 105°F Static - Test 7532

Non Zero Mass Species Sorted By VOC
E-56

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 9 psi E0 - 105°F Static - Test 7532

Non Zero Mass Species Sorted By VOC

2-Methyl-2-pentene 00625-27-4 11.03 0.48 5.339

Methylcyclohexane 00108-87-2 1.56 0.48 0.744

2,2-DiMeHexane 00590-73-8 0.94 0.48 0.449

Unknown #16 3.21 0.46 1.472

3-Methyl-c-2-pentene 00922-62-3 12.52 0.45 5.667

1-Methylcyclopentene 00693-89-0 12.45 0.45 5.568

3-Methylheptane 00589-81-1 1.12 0.43 0.480

c-2-Butene 00590-18-1 14.26 0.42 6.040

n-Octane 00111-65-9 0.80 0.42 0.331

n-Heptane 00142-82-5 0.97 0.39 0.376

c-1,3-Dimethylcyclopentane 02532-58-3 3.21 0.33 1.051

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.33 2.591

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.32 2.270

n-Nonane 00111-84-2 0.68 0.24 0.165

2,4-Dimethylheptane 02213-23-2 1.26 0.21 0.266

3-Methyl-t-2-pentene 00616-12-6 11.66 0.05 0.607

Total 115.4 370.1 3.207

No MIR available, use weighted average of 3.2066

continued
E-57

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 49.24 193.287

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 28.61 211.333

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 24.19 129.907

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 23.46 181.972

n-Hexane 00110-54-3 1.13 22.68 25.733

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 19.89 23.856

Cyclohexane 00110-82-7 1.14 19.72 22.424

3-Me-1-Hexene 03404-61-3 4.27 13.55 57.915

1,3,5-Trimethylbenzene 00108-67-8 11.75 12.44 146.274

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.63 46.701

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 9.20 12.855

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 9.20 53.133

Benzene 00071-43-2 0.69 9.16 6.362

2,3,4-Trimethylpentane 00565-75-3 0.95 8.61 8.171

3-Methylpentane 00096-14-0 1.69 8.01 13.547

ortho-Xylene 00095-47-6 7.58 6.97 52.783

n-Pentane 00109-66-0 1.21 6.76 8.212

Methylcyclopentane 00096-37-7 2.05 6.65 13.629

2-Methylhexane 00591-76-4 1.09 6.57 7.132

n-Heptane 00142-82-5 0.97 6.43 6.208

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 5.90 32.693

1-Methylcyclopentene 00693-89-0 12.45 5.55 69.091

2,3-Dimethylbutane 00079-29-8 0.90 5.47 4.916

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 5.09 16.242

4-Methyl-t-2-pentene 00674-76-0 8.04 4.94 39.753

Ethylbenzene 00100-41-4 2.96 4.88 14.467

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.78 37.998

Unknown #22 4.52 4.76 21.530

2,2,5-Trimethylhexane 03522-94-9 1.05 4.54 4.777

2-Methyl-2-butene 00513-35-9 14.20 4.45 63.114

n-Butane 00106-97-8 1.08 4.42 4.764

2-Methylbutane (Isopentane) 00078-78-4 1.35 3.73 5.048

Indan 00496-11-7 3.23 3.59 11.626

n-Propylbenzene 00103-65-1 1.96 3.56 6.975

2,4-Dimethylpentane 00108-08-7 1.46 3.33 4.858

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.32 39.635

2-Methyl-1,3-butadiene 00078-79-5 10.48 3.10 32.468

3-Methyl-t-2-pentene 00616-12-6 11.66 3.05 35.574

2,3-Dimethylpentane 00565-59-3 1.25 2.92 3.646

t-2-Pentene 00646-04-8 10.47 2.91 30.439

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.84 33.293

2,4-Dimethylhexane 00589-43-5 1.61 2.68 4.305

2,2-Dimethylpentane 00590-35-2 1.04 2.58 2.688

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.45 2.673

Vehicle 208b - Fuel 9 psi E0 - Dynamic - Test 25771

Non Zero Mass Species Sorted By VOC
E-58

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 9 psi E0 - Dynamic - Test 25771

Non Zero Mass Species Sorted By VOC

t-2-Hexene 04050-45-7 8.55 2.10 17.988

2,3,5-Trimethylhexane 01069-53-0 1.12 2.01 2.248

2-Methyl-1-butene 00563-46-2 6.38 1.91 12.174

c-2-Pentene 00627-20-3 10.28 1.80 18.508

1,3-Butadiene 00106-99-0 12.45 1.49 18.584

c-2-Butene 00590-18-1 14.26 1.47 21.026

Cyclopentene 00142-29-0 6.69 1.14 7.607

3-Methyl-c-2-pentene 00922-62-3 12.52 0.88 11.062

Total 409.6 1853.2 4.524

No MIR available, use weighted average of 4.5241

continued
E-59

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 226.83 307.323

n-Butane 00106-97-8 1.08 223.98 241.202

Cyclohexane 00110-82-7 1.14 192.86 219.354

Toluene 00108-88-3 3.93 167.30 656.673

n-Hexane 00110-54-3 1.13 94.18 106.869

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 82.44 98.861

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 72.60 101.472

3-Methylpentane 00096-14-0 1.69 49.77 84.157

2,3-Dimethylbutane 00079-29-8 0.90 35.98 32.338

2,3,4-Trimethylpentane 00565-75-3 0.95 34.51 32.747

n-Pentane 00109-66-0 1.21 34.15 41.485

2-Methyl-2-butene 00513-35-9 14.20 33.96 481.993

Methylcyclopentane 00096-37-7 2.05 33.50 68.663

Benzene 00071-43-2 0.69 32.27 22.407

Ethanol 00064-17-5 1.45 30.56 44.275

t-2-Pentene 00646-04-8 10.47 26.47 277.198

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.03 155.313

2,4-Dimethylpentane 00108-08-7 1.46 19.99 29.167

2-Methylhexane 00591-76-4 1.09 17.93 19.453

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 16.52 52.723

2,3-Dimethylpentane 00565-59-3 1.25 15.96 19.917

2,4-Dimethylhexane 00589-43-5 1.61 15.36 24.658

2,2,5-Trimethylhexane 03522-94-9 1.05 13.89 14.624

c-2-Pentene 00627-20-3 10.28 13.64 140.198

2-Methyl-1-butene 00563-46-2 6.38 12.87 82.116

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 11.31 18.150

t-2-Hexene 04050-45-7 8.55 10.72 91.658

3-Methyl-t-2-pentene 00616-12-6 11.66 9.78 114.064

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 8.94 104.661

n-Heptane 00142-82-5 0.97 8.88 8.578

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.85 46.887

3-Methyl-c-2-pentene 00922-62-3 12.52 8.64 108.144

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.04 8.777

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.97 42.775

2,3,5-Trimethylhexane 01069-53-0 1.12 7.52 8.424

1-Methylcyclopentene 00693-89-0 12.45 6.91 86.056

2-Methyl-2-pentene 00625-27-4 11.03 6.89 75.985

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.99 39.576

2,2-Dimethylbutane 00075-83-2 1.11 5.76 6.402

ortho-Xylene 00095-47-6 7.58 5.74 43.500

Cyclopentene 00142-29-0 6.69 5.74 38.349

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.33 39.403

Methylcyclohexane 00108-87-2 1.56 5.14 7.996

c-2-Butene 00590-18-1 14.26 4.32 61.588

Vehicle 208b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7556

Non Zero Mass Species Sorted By VOC
E-60

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7556

Non Zero Mass Species Sorted By VOC

t-1,2-Dimethylcyclopentane 00822-50-4 2.65 4.26 11.303

Ethylbenzene 00100-41-4 2.96 4.04 11.966

2,2-DiMeHexane 00590-73-8 0.94 4.03 3.795

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.66 16.090

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.51 41.294

c-1,3-Dimethylcyclopentane 02532-58-3 2.65 3.46 9.164

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.43 27.267

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.78 16.057

2,2-Dimethylpentane 00590-35-2 1.04 2.71 2.826

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.64 14.650

2-Methylheptane 00592-27-8 0.97 2.64 2.556

3-Methylheptane 00589-81-1 1.12 2.47 2.775

n-Propylbenzene 00103-65-1 1.96 2.32 4.556

n-Octane 00111-65-9 0.80 2.26 1.796

Ethylene 00074-85-1 8.88 2.22 19.715

Unknown #16 2.65 2.05 5.438

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 2.05 16.040

2,2,3-Trimethylbutane 00464-06-2 1.05 1.80 1.896

Unknown #5 2.65 1.75 4.627

3,5-Dimethylheptane 00926-82-9 1.42 1.58 2.252

3,3-Dimethylpentane 00562-49-2 1.12 1.50 1.677

Unknown #13 2.65 1.44 3.829

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.39 5.303

Indan 00496-11-7 3.23 1.14 3.694

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.01 3.894

1-Nonene 00124-11-8 2.49 1.00 2.500

c-2-Heptene 06443-92-1 7.08 0.95 6.717

1,3-Diethylbenzene 00141-93-5 7.08 0.90 6.400

1,3-Butadiene 00106-99-0 12.45 0.90 11.231

3,3-Dimethylhexane 00563-16-6 1.15 0.81 0.938

4-Methyloctane 02216-34-4 0.85 0.73 0.615

t-3-Heptene 14686-14-7 6.17 0.70 4.305

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.69 4.499

c-1,3-Dimethylcyclohexane 00638-04-0 2.65 0.66 1.760

2,4-Dimethylheptane 02213-23-2 1.26 0.66 0.839

Isopropylbenzene (Cumene) 00098-82-8 2.65 0.61 1.623

Unknown #8 2.65 0.59 1.575

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.54 5.671

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.65 0.54 1.433

t-2-Nonene 06434-78-2 2.65 0.50 1.329

Unknown #3 2.65 0.43 1.140

1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.43 2.325

continued
E-61

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7556

Non Zero Mass Species Sorted By VOC

continued

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.43 3.567

n-Nonane 00111-84-2 0.68 0.41 0.283

1-Heptene 00592-76-7 4.29 0.39 1.672

3-Methyloctane 02216-33-3 0.88 0.36 0.318

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.32 0.352

2,2-Dimethyloctane 15869-87-1 0.76 0.30 0.230

1c-2t-3-TriMeCyPentane 15890-40-1 2.65 0.29 0.780

sec-Butylbenzene 00135-98-8 2.29 0.29 0.658

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.28 1.746

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.27 0.232

Isobutylbenzene 00538-93-2 2.65 0.25 0.651

t-1,4-Dimethylcyclohexane 02207-04-7 2.65 0.18 0.483

Total 1737.6 4606.5 2.651

No MIR available, use weighted average of 2.6511
E-62

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 8.61 11.665

Toluene 00108-88-3 3.93 5.61 22.020

n-Butane 00106-97-8 1.08 5.20 5.598

Cyclohexane 00110-82-7 1.14 3.19 3.630

n-Hexane 00110-54-3 1.13 2.08 2.355

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.65 2.310

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.55 1.860

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.45 11.249

n-Pentane 00109-66-0 1.21 1.44 1.755

t-2-Pentene 00646-04-8 10.47 1.20 12.565

3-Methylpentane 00096-14-0 1.69 1.19 2.005

Benzene 00071-43-2 0.69 1.08 0.751

Indan 00496-11-7 3.23 0.87 2.828

c-2-Pentene 00627-20-3 10.28 0.84 8.640

2,3,4-Trimethylpentane 00565-75-3 0.95 0.81 0.767

2,3-Dimethylbutane 00079-29-8 0.90 0.77 0.691

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.68 3.661

3-Methyl-c-2-pentene 00922-62-3 12.52 0.66 8.258

Unknown #16 3.15 0.66 2.072

2-Methyl-2-butene 00513-35-9 14.20 0.65 9.182

Methylcyclopentane 00096-37-7 2.05 0.64 1.308

1-Butyne 00107-00-6 6.05 0.60 3.611

c-2-Butene 00590-18-1 14.26 0.51 7.330

2,3,5-Trimethylhexane 01069-53-0 1.12 0.50 0.561

2,4-Dimethylhexane 00589-43-5 1.61 0.47 0.754

Isopropylbenzene (Cumene) 00098-82-8 3.15 0.45 1.402

2,3-Dimethylpentane 00565-59-3 1.25 0.41 0.506

2-Methylhexane 00591-76-4 1.09 0.40 0.434

2,4-Dimethylpentane 00108-08-7 1.46 0.39 0.575

t-2-Hexene 04050-45-7 8.55 0.39 3.347

n-Octane 00111-65-9 0.80 0.38 0.302

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.34 1.819

c-1,3-Dimethylcyclopentane 02532-58-3 3.15 0.33 1.029

2-Methyl-1-butene 00563-46-2 6.38 0.33 2.081

Ethanol 00064-17-5 1.45 0.31 0.446

Ethylbenzene 00100-41-4 2.96 0.26 0.781

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.26 1.451

ortho-Xylene 00095-47-6 7.58 0.25 1.859

2,2,5-Trimethylhexane 03522-94-9 1.05 0.24 0.258

3-Methyl-t-2-pentene 00616-12-6 11.66 0.24 2.752

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.23 0.377

2,2-Dimethylbutane 00075-83-2 1.11 0.23 0.258

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.23 1.017

2-Methyl-2-pentene 00625-27-4 11.03 0.23 2.485

Vehicle 208b - Fuel 7 psi E0 - 86°F Static - Test 7568

Non Zero Mass Species Sorted By VOC
E-63

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E0 - 86°F Static - Test 7568

Non Zero Mass Species Sorted By VOC

n-Propylbenzene 00103-65-1 1.96 0.22 0.426

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.21 2.496

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.21 1.382

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.21 0.664

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.19 0.207

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.18 1.300

2-Methylheptane 00592-27-8 0.97 0.18 0.172

3-Methylheptane 00589-81-1 1.12 0.17 0.188

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.10 0.815

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.06 0.727

t-1,2-Dimethylcyclopentane 00822-50-4 3.15 0.06 0.182

Total 50.6 159.2 3.146

No MIR available, use weighted average of 3.1461

continued
E-64

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 15.30 60.052

2-Methylbutane (Isopentane) 00078-78-4 1.35 13.66 18.514

Cyclohexane 00110-82-7 1.14 11.04 12.558

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.47 55.201

n-Butane 00106-97-8 1.08 6.68 7.192

n-Hexane 00110-54-3 1.13 4.95 5.616

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.44 5.321

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.72 5.196

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.56 27.572

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.77 14.863

3-Methylpentane 00096-14-0 1.69 2.62 4.427

Ethanol 00064-17-5 1.45 2.23 3.235

Benzene 00071-43-2 0.69 2.21 1.532

2,3,4-Trimethylpentane 00565-75-3 0.95 2.05 1.943

2,3-Dimethylbutane 00079-29-8 0.90 1.97 1.766

n-Pentane 00109-66-0 1.21 1.76 2.139

2-Methyl-2-butene 00513-35-9 14.20 1.68 23.915

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.58 18.554

Methylcyclopentane 00096-37-7 2.05 1.43 2.935

t-2-Pentene 00646-04-8 10.47 1.40 14.676

2-Methylhexane 00591-76-4 1.09 1.12 1.213

2,4-Dimethylpentane 00108-08-7 1.46 1.10 1.608

ortho-Xylene 00095-47-6 7.58 0.98 7.450

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.96 4.218

2,4-Dimethylhexane 00589-43-5 1.61 0.93 1.501

2,3-Dimethylpentane 00565-59-3 1.25 0.90 1.124

Methylcyclohexane 00108-87-2 1.56 0.88 1.366

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.88 10.477

2,2-DiMeHexane 00590-73-8 0.94 0.79 0.744

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.78 2.501

2,2,5-Trimethylhexane 03522-94-9 1.05 0.76 0.804

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.75 1.211

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.70 3.884

t-2-Hexene 04050-45-7 8.55 0.69 5.899

1-Butyne 00107-00-6 6.05 0.66 3.993

n-Heptane 00142-82-5 0.97 0.65 0.630

2-Methylheptane 00592-27-8 0.97 0.64 0.615

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.63 4.444

c-2-Pentene 00627-20-3 10.28 0.59 6.104

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.58 3.079

1-Methylcyclopentene 00693-89-0 12.45 0.57 7.067

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.57 0.618

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.57 3.736

Ethylbenzene 00100-41-4 2.96 0.55 1.617

Vehicle 208b - Fuel 7 psi E0 - 105°F Static - Test 7570

Non Zero Mass Species Sorted By VOC
E-65

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E0 - 105°F Static - Test 7570

Non Zero Mass Species Sorted By VOC

2-Methyl-1-butene 00563-46-2 6.38 0.53 3.377

Indan 00496-11-7 3.23 0.51 1.649

3-Methyl-c-2-pentene 00922-62-3 12.52 0.48 5.975

3-Methyl-t-2-pentene 00616-12-6 11.66 0.48 5.566

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.44 5.191

n-Undecane 01120-21-4 0.52 0.43 0.223

c-2-Butene 00590-18-1 14.26 0.39 5.566

2-Methyl-2-pentene 00625-27-4 11.03 0.37 4.064

n-Octane 00111-65-9 0.80 0.37 0.292

3-Methylheptane 00589-81-1 1.12 0.33 0.376

2,2-Dimethylbutane 00075-83-2 1.11 0.30 0.335

Unknown #22 . 3.45 0.26 0.899

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.24 1.815

2,2-Dimethylpentane 00590-35-2 1.04 0.23 0.238

t-1,2-Dimethylcyclopentane 00822-50-4 3.45 0.20 0.700

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.20 1.591

Cyclopentene 00142-29-0 6.69 0.18 1.181

2,3,5-Trimethylhexane 01069-53-0 1.12 0.17 0.193

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.12 0.919

Total 117.0 403.3 3.448

No MIR available, use weighted average of 3.4476

continued
E-66

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 28.20 55.259

Toluene 00108-88-3 3.93 13.03 51.131

Cyclohexane 00110-82-7 1.14 10.16 11.555

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.81 41.960

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.84 56.854

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.82 37.344

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.71 5.652

n-Butane 00106-97-8 1.08 3.05 3.281

Ethane 00074-84-0 0.26 2.47 0.650

ortho-Xylene 00095-47-6 7.58 2.26 17.147

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.03 8.899

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.79 9.903

Benzene 00071-43-2 0.69 1.69 1.176

2-Methylbutane (Isopentane) 00078-78-4 1.35 1.45 1.960

2,3-Dimethylbutane 00079-29-8 0.90 1.27 1.139

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.25 1.742

2,3,4-Trimethylpentane 00565-75-3 0.95 1.20 1.138

Methylcyclopentane 00096-37-7 2.05 1.09 2.237

2,4-Dimethylpentane 00108-08-7 1.46 1.07 1.563

3-Methylpentane 00096-14-0 1.69 1.01 1.707

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.00 11.947

2,2,5-Trimethylhexane 03522-94-9 1.05 0.96 1.008

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.76 7.932

2,4-Dimethylhexane 00589-43-5 1.61 0.73 1.174

2,2-Dimethylbutane 00075-83-2 1.11 0.66 0.738

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.63 1.006

Ethylbenzene 00100-41-4 2.96 0.62 1.835

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.47 3.720

2,3-Dimethylpentane 00565-59-3 1.25 0.41 0.508

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.40 2.113

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.33 0.357

Cyclopentene 00142-29-0 6.69 0.29 1.967

3-Methyl-t-2-pentene 00616-12-6 11.66 0.23 2.692

n-Heptane 00142-82-5 0.97 0.21 0.202

2-Methyl-2-butene 00513-35-9 14.20 0.17 2.457

Methylcyclohexane 00108-87-2 1.56 0.16 0.255

2-Methylhexane 00591-76-4 1.09 0.13 0.139

n-Undecane 01120-21-4 0.52 0.11 0.058

c-2-Pentene 00627-20-3 10.28 0.11 1.112

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.02 0.068

Total 103.6 353.6 3.413

Vehicle 208b - Fuel 7 psi E0 - Dynamic - Test 25782

Non Zero Mass Species Sorted By VOC

continued
E-67

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 166.23 225.216

Cyclohexane 00110-82-7 1.14 133.72 152.087

Toluene 00108-88-3 3.93 125.86 494.015

n-Butane 00106-97-8 1.08 74.60 80.336

n-Hexane 00110-54-3 1.13 71.28 80.879

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 53.08 74.200

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 50.19 60.179

3-Methylpentane 00096-14-0 1.69 35.73 60.417

Benzene 00071-43-2 0.69 27.27 18.934

2-Methyl-2-butene 00513-35-9 14.20 27.25 386.746

n-Pentane 00109-66-0 1.21 26.97 32.769

2,3-Dimethylbutane 00079-29-8 0.90 25.95 23.320

Ethanol 00064-17-5 1.45 25.83 37.429

Methylcyclopentane 00096-37-7 2.05 24.26 49.718

t-2-Pentene 00646-04-8 10.47 22.05 230.932

2,3,4-Trimethylpentane 00565-75-3 0.95 19.36 18.369

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.93 115.821

2,4-Dimethylpentane 00108-08-7 1.46 13.76 20.080

2-Methylhexane 00591-76-4 1.09 12.45 13.509

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 11.33 36.151

c-2-Pentene 00627-20-3 10.28 10.95 112.570

2,3-Dimethylpentane 00565-59-3 1.25 10.41 13.000

2-Methyl-1-butene 00563-46-2 6.38 10.03 63.975

2,4-Dimethylhexane 00589-43-5 1.61 9.09 14.597

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 8.94 66.052

t-2-Hexene 04050-45-7 8.55 8.50 72.690

3-Methyl-t-2-pentene 00616-12-6 11.66 7.46 86.970

3-Methyl-c-2-pentene 00922-62-3 12.52 7.23 90.547

2,2,5-Trimethylhexane 03522-94-9 1.05 7.23 7.615

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.82 36.159

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.81 10.940

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.72 78.603

n-Heptane 00142-82-5 0.97 6.41 6.190

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.71 30.658

1-Methylcyclopentene 00693-89-0 12.45 5.48 68.258

2-Methyl-2-pentene 00625-27-4 11.03 5.30 58.508

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.99 5.451

2,2-DiMeHexane 00590-73-8 0.94 4.84 4.552

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.82 31.813

Cyclopentene 00142-29-0 6.69 4.58 30.623

ortho-Xylene 00095-47-6 7.58 4.14 31.338

2,2-Dimethylbutane 00075-83-2 1.11 3.56 3.954

c-2-Butene 00590-18-1 14.26 3.49 49.718

Methylcyclohexane 00108-87-2 1.56 3.31 5.155

Vehicle 208b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7575

Non Zero Mass Species Sorted By VOC
E-68

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 208b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7575

Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 3.14 9.307

t-1,2-Dimethylcyclopentane 00822-50-4 2.91 2.98 8.649

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.65 11.642

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.49 19.786

c-1,3-Dimethylcyclopentane 02532-58-3 2.91 2.32 6.754

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.19 25.686

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.09 12.090

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.00 11.087

3-Methylheptane 00589-81-1 1.12 1.94 2.181

n-Propylbenzene 00103-65-1 1.96 1.92 3.763

2,2-Dimethylpentane 00590-35-2 1.04 1.87 1.955

2-Methylheptane 00592-27-8 0.97 1.81 1.755

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.54 12.100

n-Octane 00111-65-9 0.80 1.36 1.085

2,2,3-Trimethylbutane 00464-06-2 1.05 1.31 1.377

2,3,5-Trimethylhexane 01069-53-0 1.12 1.20 1.346

3,3-Dimethylpentane 00562-49-2 1.12 1.12 1.258

Unknown #16 2.91 1.11 3.235

c-2-Heptene 06443-92-1 7.08 0.96 6.789

Unknown #5 2.91 0.93 2.692

1,3-Butadiene 00106-99-0 12.45 0.84 10.459

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.75 5.298

n-Decane 00124-18-5 0.59 0.74 0.438

1-Nonene 00124-11-8 2.49 0.67 1.671

c-1,3-Dimethylcyclohexane 00638-04-0 2.91 0.66 1.929

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.65 4.264

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.65 7.748

3,3-Dimethylhexane 00563-16-6 1.15 0.63 0.722

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.62 2.400

Indan 00496-11-7 3.23 0.60 1.932

t-3-Heptene 14686-14-7 6.17 0.56 3.482

4-Methyloctane 02216-34-4 0.85 0.51 0.432

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.47 3.954

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.43 2.684

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.42 4.405

t-2-Nonene 06434-78-2 2.91 0.39 1.140

n-Nonane 00111-84-2 0.68 0.38 0.260

1-Heptene 00592-76-7 4.29 0.36 1.540

Unknown #8 2.91 0.33 0.949

2,4-Dimethylheptane 02213-23-2 1.26 0.28 0.351

Isopropylbenzene (Cumene) 00098-82-8 2.91 0.22 0.649

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.18 0.151

Total 1167.2 3392.4 2.906

No MIR available, use weighted average of 2.9065

continued
E-69

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7423 52.1 165.6 86.2 276.2 3.205 63

Static E10 - 7 psi 7466 54.4 130.9 71.2 262.9 3.692 78

E0 - 9 psi 7501 44.8 83.4 37.3 76.3 2.043 19

E0 - 7 psi 7524 38.8 120.5 46.8 161.0 3.441 51

105° F E10 - 10 psi 7424 160.9 117.8 189.4 593.2 3.131 65

Static E10 - 7 psi 7467 102.4 98.8 101.2 340.7 3.368 57

E0 - 9 psi 7504 55.8 86.1 48.1 186.9 3.886 52

E0 - 7 psi 7527 62.4 101.5 63.3 245.8 3.885 50

Dynamic E10 - 10 psi 25742 401.4 111.9 449.1 1629.8 3.629 74

E10 - 7 psi 25755 217.1 85.1 184.7 701.1 3.796 58

E0 - 9 psi 25761 140.9 102.9 145.0 658.3 4.541 45

E0 - 7 psi 25768 166.6 87.9 146.4 543.1 3.708 31

DHB E10 - 10 psi 7461 1434.5 93.8 1345.1 3821.9 2.841 110

Total E10 - 7 psi 7472 1055.7 93.7 989.6 2879.4 2.909 89

E0 - 9 psi 7508 802.6 59.6 478.6 1316.0 2.749 65

E0 - 7 psi 7533 821.9 94.5 776.5 2515.6 3.239 81

Vehicle 209b
E-70

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 14.30 20.721

Toluene 00108-88-3 3.93 10.09 39.602

2-Methylbutane (Isopentane) 00078-78-4 1.35 8.82 11.956

n-Butane 00106-97-8 1.08 8.71 9.383

n-Propylbenzene 00103-65-1 1.96 3.96 7.758

n-Hexane 00110-54-3 1.13 3.17 3.600

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.00 16.083

Benzene 00071-43-2 0.69 2.16 1.498

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.76 2.462

2-Methyl-2-butene 00513-35-9 14.20 1.46 20.779

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.46 11.302

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.39 10.247

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.30 1.559

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.24 6.850

n-Pentane 00109-66-0 1.21 1.23 1.497

3-Methylpentane 00096-14-0 1.69 1.23 2.081

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.19 5.209

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.09 12.824

t-2-Pentene 00646-04-8 10.47 0.87 9.116

Unknown #16 3.20 0.86 2.759

Methylcyclohexane 00108-87-2 1.56 0.84 1.305

2-Methylpropane 00075-28-5 1.18 0.83 0.976

Methylcyclopentane 00096-37-7 2.05 0.82 1.673

2,3-Dimethylbutane 00079-29-8 0.90 0.75 0.670

Unknown #22 . 3.20 0.73 2.353

Cyclohexane 00110-82-7 1.14 0.63 0.721

ortho-Xylene 00095-47-6 7.58 0.61 4.652

3-Methyl-c-2-pentene 00922-62-3 12.52 0.58 7.318

c-2-Pentene 00627-20-3 10.28 0.58 5.985

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.57 3.789

3-Methyl-t-2-pentene 00616-12-6 11.66 0.57 6.623

t-2-Hexene 04050-45-7 8.55 0.56 4.809

n-Octane 00111-65-9 0.80 0.55 0.441

2-Methyl-1-butene 00563-46-2 6.38 0.53 3.389

n-Decane 00124-18-5 0.59 0.52 0.306

2,3,4-Trimethylpentane 00565-75-3 0.95 0.51 0.482

2-Methyl-2-pentene 00625-27-4 11.03 0.50 5.476

2,2-DiMeHexane 00590-73-8 0.94 0.48 0.456

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.44 5.270

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.43 5.040

c-2-Butene 00590-18-1 1.12 0.37 0.420

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.36 1.929

c-1,3-Dimethylcyclohexane 00638-04-0 3.20 0.36 1.145

t-2-Butene 00624-64-6 15.20 0.31 4.729

Vehicle 209b - Fuel 10 psi E10 - 86°F Static - Test 7423

Non Zero Mass Species Sorted By VOC
E-71

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 10 psi E10 - 86°F Static - Test 7423

Non Zero Mass Species Sorted By VOC

Indan 00496-11-7 3.23 0.31 1.003

Ethylbenzene 00100-41-4 2.96 0.30 0.882

2,4-Dimethylpentane 00108-08-7 1.46 0.29 0.419

2,2-Dimethylpentane 00590-35-2 1.04 0.29 0.299

n-Heptane 00142-82-5 0.97 0.27 0.256

Cyclopentene 00142-29-0 6.69 0.25 1.689

t-1,2-Dimethylcyclopentane 00822-50-4 3.20 0.23 0.729

2-Methylheptane 00592-27-8 0.97 0.21 0.207

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.17 1.346

2,4-Dimethylhexane 00589-43-5 1.61 0.16 0.257

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.15 0.248

2,2,5-Trimethylhexane 03522-94-9 1.05 0.14 0.152

n-Nonane 00111-84-2 0.68 0.14 0.097

c-1,3-Dimethylcyclopentane 02532-58-3 3.20 0.13 0.407

2-Methylhexane 00591-76-4 1.09 0.12 0.128

2,2-Dimethylbutane 00075-83-2 1.11 0.10 0.116

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.08 0.584

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.05 0.050

2,3-Dimethylpentane 00565-59-3 1.25 0.05 0.056

Total 86.2 276.2 3.205

No MIR available, use weighted average of 3.2047

continued
E-72

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 36.10 38.874

Ethanol 00064-17-5 1.45 27.85 40.352

Toluene 00108-88-3 3.93 21.91 85.991

2-Methylbutane (Isopentane) 00078-78-4 1.35 13.86 18.776

n-Hexane 00110-54-3 1.13 6.99 7.932

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.75 25.498

n-Propylbenzene 00103-65-1 1.96 4.23 8.287

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.93 5.492

Benzene 00071-43-2 0.69 3.89 2.702

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.37 24.854

2-Methyl-2-butene 00513-35-9 14.20 3.33 47.232

t-2-Pentene 00646-04-8 10.47 3.27 34.277

n-Pentane 00109-66-0 1.21 3.24 3.939

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.83 21.981

3-Methylpentane 00096-14-0 1.69 2.77 4.687

2-Methylpropane 00075-28-5 1.18 2.54 2.989

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.25 2.694

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.74 7.634

Methylcyclopentane 00096-37-7 2.05 1.70 3.486

n-Heptane 00142-82-5 0.97 1.66 1.605

c-2-Pentene 00627-20-3 10.28 1.64 16.908

Cyclohexane 00110-82-7 1.14 1.64 1.868

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.50 8.311

t-2-Butene 00624-64-6 15.20 1.50 22.773

2,3-Dimethylbutane 00079-29-8 0.90 1.44 1.290

2-Methyl-1-butene 00563-46-2 6.38 1.42 9.061

Propane 00074-98-6 0.46 1.33 0.608

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.31 15.407

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.18 3.751

2,3,4-Trimethylpentane 00565-75-3 0.95 1.17 1.106

c-2-Butene 00590-18-1 14.26 1.14 16.299

ortho-Xylene 00095-47-6 7.58 1.06 8.040

n-Decane 00124-18-5 0.59 1.04 0.614

1-Methylcyclopentene 00693-89-0 12.45 1.04 12.902

Methylcyclohexane 00108-87-2 1.56 1.02 1.588

2-Methylhexane 00591-76-4 1.09 1.02 1.104

Indan 00496-11-7 3.23 1.00 3.220

n-Octane 00111-65-9 0.80 0.98 0.782

Unknown #16 3.13 0.91 2.847

n-Nonane 00111-84-2 0.68 0.87 0.592

t-2-Hexene 04050-45-7 8.55 0.83 7.064

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.82 4.322

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.80 9.374

c-1,3-Dimethylcyclohexane 00638-04-0 3.13 0.80 2.506

Vehicle 209b - Fuel 10 psi E10 - 105°F Static - Test 7424

Non Zero Mass Species Sorted By VOC
E-73

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 10 psi E10 - 105°F Static - Test 7424

Non Zero Mass Species Sorted By VOC

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.78 6.191

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.77 5.468

2,2-DiMeHexane 00590-73-8 0.94 0.67 0.632

2,4-Dimethylpentane 00108-08-7 1.46 0.65 0.945

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.64 4.227

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.60 7.132

3-Methyl-t-2-pentene 00616-12-6 11.66 0.59 6.900

2,4-Dimethylhexane 00589-43-5 1.61 0.58 0.932

2,3-Dimethylpentane 00565-59-3 1.25 0.54 0.679

3-Methylheptane 00589-81-1 1.12 0.54 0.609

Cyclopentene 00142-29-0 6.69 0.48 3.194

3-Methyl-c-2-pentene 00922-62-3 12.52 0.47 5.940

2,2,5-Trimethylhexane 03522-94-9 1.05 0.47 0.492

2-Methyl-2-pentene 00625-27-4 11.03 0.44 4.882

Ethylbenzene 00100-41-4 2.96 0.38 1.136

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.34 0.547

2,2-Dimethylbutane 00075-83-2 1.11 0.24 0.267

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.22 0.244

c-1,3-Dimethylcyclopentane 02532-58-3 3.13 0.20 0.618

t-1,2-Dimethylcyclopentane 00822-50-4 3.13 0.15 0.475

2-Methylheptane 00592-27-8 0.97 0.04 0.043

Total 189.4 593.2 3.131

No MIR available, use weighted average of 3.1310

continued
E-74

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 44.55 174.871

n-Butane 00106-97-8 1.08 43.19 46.507

Ethanol 00064-17-5 1.45 37.14 53.809

Methane 00074-82-8 0.01 35.35 0.490

2-Methylbutane (Isopentane) 00078-78-4 1.35 31.49 42.661

n-Hexane 00110-54-3 1.13 15.57 17.672

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.73 62.985

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.83 72.625

t-2-Butene 00624-64-6 15.20 9.53 144.815

Benzene 00071-43-2 0.69 9.51 6.604

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 8.85 12.365

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.29 64.294

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 7.58 9.088

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.90 80.773

1,3,5-Trimethylbenzene 00108-67-8 11.75 6.65 78.216

3-Methylpentane 00096-14-0 1.69 6.35 10.743

Cyclohexane 00110-82-7 1.14 6.29 7.158

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.14 48.787

n-Pentane 00109-66-0 1.21 6.13 7.452

2,3-Dimethylbutane 00079-29-8 0.90 5.63 5.056

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.42 23.823

2,3,5-Trimethylhexane 01069-53-0 1.12 5.38 6.026

n-Decane 00124-18-5 0.59 5.30 3.133

Methylcyclopentane 00096-37-7 2.05 5.11 10.470

Methylcyclohexane 00108-87-2 1.56 4.95 7.701

t-2-Pentene 00646-04-8 10.47 4.90 51.356

2-Methyl-2-butene 00513-35-9 14.20 4.68 66.468

2-Methylhexane 00591-76-4 1.09 4.20 4.560

1,3-Butadiene 00106-99-0 12.45 4.02 50.073

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.00 12.776

Cyclopentene 00142-29-0 6.69 3.80 25.392

n-Heptane 00142-82-5 0.97 3.67 3.546

2-Methyl-1-butene 00563-46-2 6.38 3.40 21.696

2,3,4-Trimethylpentane 00565-75-3 0.95 3.34 3.167

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.28 17.358

n-Octane 00111-65-9 0.80 3.20 2.550

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.15 17.481

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.06 36.483

3-Methyl-c-2-pentene 00922-62-3 12.52 2.84 35.612

c-2-Pentene 00627-20-3 10.28 2.72 27.932

t-2-Hexene 04050-45-7 8.55 2.65 22.663

Unknown #16 3.63 2.56 9.299

2,4-Dimethylhexane 00589-43-5 1.61 2.54 4.080

3-Methyl-t-2-pentene 00616-12-6 11.66 2.35 27.391

Vehicle 209b - Fuel 10 psi E10 - Dynamic - Test 25742

Non Zero Mass Species Sorted By VOC
E-75

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 10 psi E10 - Dynamic - Test 25742

Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 2.21 16.710

2-Methyl-2-pentene 00625-27-4 11.03 2.20 24.253

2,3-Dimethylpentane 00565-59-3 1.25 2.16 2.691

c-2-Butene 00590-18-1 14.26 2.01 28.689

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.01 2.192

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.98 13.100

c-1,3-Dimethylcyclopentane 02532-58-3 3.63 1.85 6.726

n-Nonane 00111-84-2 0.68 1.80 1.229

1-Methylcyclopentene 00693-89-0 12.45 1.75 21.755

2,4-Dimethylpentane 00108-08-7 1.46 1.69 2.472

2-Methylpropane 00075-28-5 1.18 1.62 1.908

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.62 12.212

2-Methylheptane 00592-27-8 0.97 1.53 1.483

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.51 10.702

Styrene 00100-42-5 1.66 1.50 2.493

3-Methylheptane 00589-81-1 1.12 1.49 1.674

3,3-Dimethylpentane 00562-49-2 1.12 1.47 1.649

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.42 2.282

t-1,2-Dimethylcyclopentane 00822-50-4 3.63 1.40 5.068

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.37 7.912

2,2-DiMeHexane 00590-73-8 0.94 1.18 1.115

2,2,5-Trimethylhexane 03522-94-9 1.05 1.15 1.209

Ethylbenzene 00100-41-4 2.96 1.14 3.382

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.05 11.022

Unknown #22 3.63 0.86 3.108

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.56 2.178

Indan 00496-11-7 3.23 0.44 1.411

2,2-Dimethylpentane 00590-35-2 1.04 0.42 0.436

n-Propylbenzene 00103-65-1 1.96 0.26 0.510

2,2-Dimethylbutane 00075-83-2 1.11 0.20 0.226

Total 449.1 1629.8 3.629

No MIR available, use weighted average of 3.6290

continued
E-76

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 218.98 317.298

n-Butane 00106-97-8 1.08 198.76 214.048

Toluene 00108-88-3 3.93 124.89 490.191

2-Methylbutane (Isopentane) 00078-78-4 1.35 122.86 166.463

n-Hexane 00110-54-3 1.13 69.89 79.304

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 39.64 55.408

2-Methyl-2-butene 00513-35-9 14.20 29.68 421.352

Benzene 00071-43-2 0.69 29.49 20.479

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 28.71 34.431

3-Methylpentane 00096-14-0 1.69 28.66 48.453

n-Pentane 00109-66-0 1.21 27.93 33.927

t-2-Pentene 00646-04-8 10.47 26.84 281.076

Methylcyclopentane 00096-37-7 2.05 20.34 41.693

Cyclohexane 00110-82-7 1.14 18.50 21.039

Methanol 00067-56-1 0.66 18.21 11.971

2,3-Dimethylbutane 00079-29-8 0.90 16.56 14.882

2-Methylpropane 00075-28-5 1.18 14.35 16.889

c-2-Pentene 00627-20-3 10.28 13.97 143.652

Methylcyclohexane 00108-87-2 1.56 13.00 20.214

2-Methyl-1-butene 00563-46-2 6.38 12.92 82.403

2,3,4-Trimethylpentane 00565-75-3 0.95 12.54 11.901

n-Heptane 00142-82-5 0.97 11.91 11.506

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.62 90.139

2-Methylhexane 00591-76-4 1.09 11.28 12.236

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 10.24 32.662

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.39 50.443

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 9.15 107.105

t-2-Hexene 04050-45-7 8.55 8.29 70.836

2,4-Dimethylpentane 00108-08-7 1.46 8.26 12.061

c-2-Butene 00590-18-1 14.26 7.59 108.280

n-Octane 00111-65-9 0.80 6.59 5.245

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.49 34.394

2,4-Dimethylhexane 00589-43-5 1.61 6.16 9.885

3-Methyl-t-2-pentene 00616-12-6 11.66 6.03 70.364

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.03 47.921

2,3-Dimethylpentane 00565-59-3 1.25 5.76 7.188

1-Methylcyclopentene 00693-89-0 12.45 5.51 68.669

Cyclopentene 00142-29-0 6.69 5.38 35.956

3-Methyl-c-2-pentene 00922-62-3 12.52 5.33 66.740

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.98 36.797

2-Methyl-2-pentene 00625-27-4 11.03 4.93 54.363

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.75 7.629

2,2,5-Trimethylhexane 03522-94-9 1.05 4.72 4.974

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.70 31.029

Vehicle 209b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7461

Non Zero Mass Species Sorted By VOC
E-77

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7461

Non Zero Mass Species Sorted By VOC

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.99 46.921

n-Decane 00124-18-5 0.59 3.97 2.348

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.89 17.096

ortho-Xylene 00095-47-6 7.58 3.68 27.884

2,2-Dimethylbutane 00075-83-2 1.11 3.67 4.073

2,2-DiMeHexane 00590-73-8 0.94 3.59 3.377

2,3,5-Trimethylhexane 01069-53-0 1.12 3.49 3.905

2-Methylheptane 00592-27-8 0.97 3.41 3.300

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.41 18.899

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.15 3.444

3-Methylheptane 00589-81-1 1.12 3.05 3.435

t-1,2-Dimethylcyclopentane 00822-50-4 2.84 2.79 7.916

c-1,3-Dimethylcyclohexane 00638-04-0 2.84 2.43 6.905

n-Nonane 00111-84-2 0.68 2.32 1.583

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.29 13.231

c-1,3-Dimethylcyclopentane 02532-58-3 2.84 2.20 6.263

Ethylbenzene 00100-41-4 2.96 2.01 5.961

n-Propylbenzene 00103-65-1 1.96 1.96 3.833

2,2-Dimethylpentane 00590-35-2 1.04 1.82 1.900

Unknown #16 2.84 1.63 4.620

3,3-Dimethylpentane 00562-49-2 1.12 1.62 1.816

Indan 00496-11-7 3.23 1.50 4.849

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.35 16.144

3,5-Dimethylheptane 00926-82-9 1.42 1.33 1.893

4-Methyloctane 02216-34-4 0.85 1.28 1.088

Isopropylbenzene (Cumene) 00098-82-8 2.84 1.28 3.625

2,2,3-Trimethylbutane 00464-06-2 1.05 1.26 1.327

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.21 9.487

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.11 4.280

t-1,4-Dimethylcyclohexane 02207-04-7 2.84 1.05 2.970

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.03 7.734

Unknown #14 2.84 0.97 2.769

Unknown #13 2.84 0.95 2.690

3-Methyloctane 02216-33-3 0.88 0.94 0.831

Unknown #5 2.84 0.91 2.588

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.91 1.077

c-2-Heptene 06443-92-1 7.08 0.90 6.354

3,3-Dimethylhexane 00563-16-6 1.15 0.88 1.016

1-Nonene 00124-11-8 2.49 0.85 2.112

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.74 6.232

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.73 0.811

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.69 0.591

continued
E-78

Unknown #8 2.84 0.68 1.945

2,2-Dimethyloctane 15869-87-1 0.76 0.67 0.510

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.84 0.67 1.914

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.66 4.687

t-3-Heptene 14686-14-7 6.17 0.64 3.925

4-Methyl-t-2-pentene 00674-76-0 8.04 0.60 4.852

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.60 6.270

Unknown #9 2.84 0.57 1.623

t-4-Octene 14850-23-8 4.69 0.51 2.401

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.45 2.955

Isobutylbenzene 00538-93-2 2.84 0.45 1.271

c- & t-4-Nonene 02198-23-4 4.42 0.43 1.910

2,4-Dimethylheptane 02213-23-2 1.26 0.42 0.533

n-Undecane 01120-21-4 0.52 0.41 0.213

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.41 1.555

1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.40 2.161

1-Heptene 00592-76-7 4.29 0.39 1.672

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.34 2.562

t-2-Nonene 06434-78-2 2.84 0.34 0.960

1,3-Diethylbenzene 00141-93-5 7.08 0.30 2.111

sec-Butylbenzene 00135-98-8 2.29 0.28 0.642

1,4-Diethylbenzene 00105-05-5 4.39 0.28 1.210

Unknown #3 2.84 0.25 0.716

c-2-Octene 07642-04-8 2.84 0.24 0.674

Total 1345.1 3821.9 2.841

No MIR available, use weighted average of 2.8415

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7461

Non Zero Mass Species Sorted By VOC

continued
E-79

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 8.03 11.636

Toluene 00108-88-3 3.93 7.65 30.015

n-Propylbenzene 00103-65-1 1.96 5.24 10.263

2-Methylbutane (Isopentane) 00078-78-4 1.35 3.82 5.174

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.37 18.069

n-Hexane 00110-54-3 1.13 3.23 3.663

n-Butane 00106-97-8 1.08 2.21 2.375

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.06 15.189

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.47 17.298

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.44 2.015

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.40 10.885

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.29 1.549

2,3,5-Trimethylhexane 01069-53-0 1.12 1.17 1.309

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.09 4.770

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.07 5.949

3-Methylpentane 00096-14-0 1.69 1.05 1.782

Cyclohexane 00110-82-7 1.14 0.95 1.080

Benzene 00071-43-2 0.69 0.95 0.659

Methylcyclopentane 00096-37-7 2.05 0.89 1.827

1,4-Diethylbenzene 00105-05-5 4.39 0.87 3.834

Unknown #16 3.69 0.87 3.204

c-2-Butene 00590-18-1 14.26 0.83 11.816

2-Methyl-2-butene 00513-35-9 14.20 0.81 11.538

2,3,4-Trimethylpentane 00565-75-3 0.95 0.77 0.730

3-Methylheptane 00589-81-1 1.12 0.72 0.809

n-Pentane 00109-66-0 1.21 0.69 0.844

Methylcyclohexane 00108-87-2 1.56 0.68 1.055

Unknown #5 3.69 0.67 2.468

2,3-Dimethylbutane 00079-29-8 0.90 0.64 0.574

Isobutylbenzene 00538-93-2 3.69 0.61 2.261

1-Methylcyclopentene 00693-89-0 12.45 0.58 7.268

n-Octane 00111-65-9 0.80 0.58 0.462

t-2-Pentene 00646-04-8 10.47 0.53 5.579

ortho-Xylene 00095-47-6 7.58 0.53 3.979

2-Methyl-1-butene 00563-46-2 6.38 0.52 3.328

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.50 3.736

n-Heptane 00142-82-5 0.97 0.47 0.458

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.46 2.665

c-1,3-Dimethylcyclohexane 00638-04-0 3.69 0.43 1.598

n-Decane 00124-18-5 0.59 0.42 0.247

3-Methyl-c-2-pentene 00922-62-3 12.52 0.40 5.010

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.39 4.680

t-2-Butene 00624-64-6 15.20 0.39 5.921

2-Methylheptane 00592-27-8 0.97 0.38 0.367

Vehicle 209b - Fuel 7 psi E10 - 86°F Static - Test 7466

Non Zero Mass Species Sorted By VOC
E-80

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E10 - 86°F Static - Test 7466

Non Zero Mass Species Sorted By VOC

3,3-Dimethylpentane 00562-49-2 1.12 0.37 0.414

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.35 0.378

2-Methylhexane 00591-76-4 1.09 0.34 0.372

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.34 2.404

Ethylcyclohexane 01678-91-7 1.35 0.32 0.428

t-2-Hexene 04050-45-7 8.55 0.31 2.691

3-Methyl-t-2-pentene 00616-12-6 11.66 0.30 3.484

2,4-Dimethylhexane 00589-43-5 1.61 0.30 0.477

1,3-Diethylbenzene 00141-93-5 7.08 0.30 2.104

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.29 0.938

Indan 00496-11-7 3.23 0.29 0.940

Isopropylbenzene (Cumene) 00098-82-8 3.69 0.29 1.069

2,4-Dimethylpentane 00108-08-7 1.46 0.29 0.421

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.29 1.904

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.28 3.285

n-Nonane 00111-84-2 0.68 0.26 0.179

2,2-DiMeHexane 00590-73-8 0.94 0.26 0.245

Ethylbenzene 00100-41-4 2.96 0.26 0.758

2,2-Dimethylbutane 00075-83-2 1.11 0.24 0.262

2,2,3-Trimethylbutane 00464-06-2 1.05 0.23 0.247

t-1,4-Dimethylcyclohexane 02207-04-7 3.69 0.23 0.850

3-Methyloctane 02216-33-3 0.88 0.22 0.197

c-2-Pentene 00627-20-3 10.28 0.22 2.259

2-Methyl-2-pentene 00625-27-4 11.03 0.22 2.414

2,3-Dimethylpentane 00565-59-3 1.25 0.20 0.252

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.17 0.273

Unknown #22 . 3.69 0.17 0.615

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.15 0.792

t-1,2-Dimethylcyclopentane 00822-50-4 3.69 0.14 0.520

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.13 0.488

2,2-Dimethylpentane 00590-35-2 1.04 0.12 0.125

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.10 0.808

c-1,3-Dimethylcyclopentane 02532-58-3 3.69 0.10 0.374

2,2,5-Trimethylhexane 03522-94-9 1.05 0.02 0.018

Total 71.2 262.9 3.692

No MIR available, use weighted average of 3.6921

continued
E-81

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 20.03 29.021

Toluene 00108-88-3 3.93 14.57 57.186

n-Propylbenzene 00103-65-1 1.96 5.69 11.143

n-Hexane 00110-54-3 1.13 5.12 5.811

2-Methylbutane (Isopentane) 00078-78-4 1.35 4.65 6.294

n-Butane 00106-97-8 1.08 3.45 3.712

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.38 18.131

Benzene 00071-43-2 0.69 2.96 2.053

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.62 19.375

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.50 3.491

2-Methyl-2-butene 00513-35-9 14.20 2.46 34.890

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.19 2.620

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.18 16.910

t-2-Pentene 00646-04-8 10.47 1.98 20.783

Methylcyclopentane 00096-37-7 2.05 1.86 3.814

3-Methylpentane 00096-14-0 1.69 1.83 3.095

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.48 5.654

Cyclohexane 00110-82-7 1.14 1.46 1.658

n-Pentane 00109-66-0 1.21 1.46 1.768

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.27 7.026

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.16 5.109

2,3,5-Trimethylhexane 01069-53-0 1.12 1.16 1.298

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.03 12.087

Methylcyclohexane 00108-87-2 1.56 1.01 1.564

2,3-Dimethylbutane 00079-29-8 0.90 0.95 0.851

c-2-Pentene 00627-20-3 10.28 0.93 9.572

ortho-Xylene 00095-47-6 7.58 0.83 6.264

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.82 5.781

2-Methyl-1-butene 00563-46-2 6.38 0.75 4.785

2,3,4-Trimethylpentane 00565-75-3 0.95 0.71 0.672

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.69 2.189

2-Methylhexane 00591-76-4 1.09 0.64 0.699

2,4-Dimethylpentane 00108-08-7 1.46 0.53 0.770

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.52 2.739

2,2-DiMeHexane 00590-73-8 0.94 0.50 0.470

t-2-Hexene 04050-45-7 8.55 0.49 4.198

n-Heptane 00142-82-5 0.97 0.46 0.448

n-Octane 00111-65-9 0.80 0.46 0.366

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.44 5.164

Indan 00496-11-7 3.23 0.41 1.338

3-Methyl-t-2-pentene 00616-12-6 11.66 0.41 4.761

c-2-Butene 00590-18-1 14.26 0.33 4.700

Cyclopentene 00142-29-0 6.69 0.33 2.177

2,3-Dimethylpentane 00565-59-3 1.25 0.32 0.395

Vehicle 209b - Fuel 7 psi E10 - 105°F Static - Test 7467

Non Zero Mass Species Sorted By VOC
E-82

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E10 - 105°F Static - Test 7467

Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.30 0.479

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.24 0.266

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.23 0.363

2-Methyl-2-pentene 00625-27-4 11.03 0.22 2.452

n-Nonane 00111-84-2 0.68 0.22 0.151

t-1,2-Dimethylcyclopentane 00822-50-4 3.37 0.21 0.715

2-Methylheptane 00592-27-8 0.97 0.21 0.199

c-1,3-Dimethylcyclopentane 02532-58-3 3.37 0.19 0.644

Ethylbenzene 00100-41-4 2.96 0.15 0.459

t-2-Butene 00624-64-6 15.20 0.12 1.777

2,2-Dimethylbutane 00075-83-2 1.11 0.06 0.067

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.04 0.273

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.01 0.044

Total 101.2 340.7 3.368

No MIR available, use weighted average of 3.3679

continued
E-83

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 35.12 50.894

n-Propylbenzene 00103-65-1 1.96 30.30 59.383

Toluene 00108-88-3 3.93 23.82 93.488

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.43 50.651

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.30 39.116

Benzene 00071-43-2 0.69 4.86 3.375

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.07 31.564

1,3-Butadiene 00106-99-0 12.45 3.50 43.606

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.46 13.217

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.41 27.114

n-Hexane 00110-54-3 1.13 3.36 3.814

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.31 3.963

2-Methyl-2-butene 00513-35-9 14.20 2.45 34.840

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.39 27.945

2,3,5-Trimethylhexane 01069-53-0 1.12 2.38 2.664

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.29 3.202

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.20 12.185

t-2-Pentene 00646-04-8 10.47 2.13 22.323

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.07 14.643

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.03 8.934

Methylcyclohexane 00108-87-2 1.56 1.86 2.895

3-Methyl-c-2-pentene 00922-62-3 12.52 1.76 21.996

n-Nonane 00111-84-2 0.68 1.59 1.085

n-Decane 00124-18-5 0.59 1.56 0.923

ortho-Xylene 00095-47-6 7.58 1.54 11.700

Indan 00496-11-7 3.23 1.49 4.814

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.48 15.567

3-Methylpentane 00096-14-0 1.69 1.31 2.208

2,3,4-Trimethylpentane 00565-75-3 0.95 1.29 1.224

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.26 8.292

2-Methyl-1-butene 00563-46-2 6.38 1.25 7.965

2-Methyl-2-pentene 00625-27-4 11.03 1.21 13.386

2,4-Dimethylpentane 00108-08-7 1.46 1.20 1.745

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.18 6.842

2,2-Dimethylpentane 00590-35-2 1.04 1.15 1.203

3-Methylheptane 00589-81-1 1.12 1.14 1.278

t-1,2-Dimethylcyclopentane 00822-50-4 3.80 1.06 4.037

3-Methyl-t-2-pentene 00616-12-6 11.66 1.03 11.951

2-Methylhexane 00591-76-4 1.09 1.02 1.112

2,2-DiMeHexane 00590-73-8 0.94 0.98 0.921

Methylcyclopentane 00096-37-7 2.05 0.94 1.930

Unknown #22 3.80 0.88 3.354

2,3-Dimethylbutane 00079-29-8 0.90 0.84 0.750

Vehicle 209b - Fuel 7 psi E10 - Dynamic - Test 25755

Non Zero Mass Species Sorted By VOC
E-84

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E10 - Dynamic - Test 25755

Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.77 1.237

t-2-Hexene 04050-45-7 8.55 0.73 6.259

Cyclopentene 00142-29-0 6.69 0.67 4.475

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.66 2.112

c-2-Pentene 00627-20-3 10.28 0.65 6.641

n-Pentane 00109-66-0 1.21 0.64 0.780

Cyclohexane 00110-82-7 1.14 0.61 0.690

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.55 0.597

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.54 0.869

2,2-Dimethylbutane 00075-83-2 1.11 0.48 0.539

c-1,3-Dimethylcyclopentane 02532-58-3 3.80 0.46 1.747

2,3-Dimethylpentane 00565-59-3 1.25 0.34 0.426

n-Heptane 00142-82-5 0.97 0.29 0.282

n-Octane 00111-65-9 0.80 0.26 0.209

2,2,5-Trimethylhexane 03522-94-9 1.05 0.11 0.115

Total 184.7 701.1 3.796

No MIR available, use weighted average of 3.7962

continued
E-85

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 221.56 321.030

Toluene 00108-88-3 3.93 99.93 392.229

2-Methylbutane (Isopentane) 00078-78-4 1.35 90.34 122.396

n-Hexane 00110-54-3 1.13 68.20 77.380

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 36.80 51.441

n-Butane 00106-97-8 1.08 29.36 31.623

3-Methylpentane 00096-14-0 1.69 26.53 44.862

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 25.38 30.437

Benzene 00071-43-2 0.69 25.06 17.398

2-Methyl-2-butene 00513-35-9 14.20 24.20 343.459

n-Pentane 00109-66-0 1.21 22.72 27.605

t-2-Pentene 00646-04-8 10.47 21.34 223.528

Methylcyclopentane 00096-37-7 2.05 19.37 39.708

Cyclohexane 00110-82-7 1.14 18.08 20.563

2,3-Dimethylbutane 00079-29-8 0.90 14.93 13.421

Methanol 00067-56-1 0.66 14.65 9.632

Methylcyclohexane 00108-87-2 1.56 11.07 17.215

c-2-Pentene 00627-20-3 10.28 10.84 111.430

2-Methyl-1-butene 00563-46-2 6.38 10.46 66.727

2-Methylhexane 00591-76-4 1.09 10.09 10.946

n-Heptane 00142-82-5 0.97 9.85 9.514

2,3,4-Trimethylpentane 00565-75-3 0.95 9.77 9.270

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 9.31 29.715

2,4-Dimethylpentane 00108-08-7 1.46 7.99 11.665

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 7.48 58.032

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.27 85.077

t-2-Hexene 04050-45-7 8.55 7.16 61.179

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.50 29.524

2,3-Dimethylpentane 00565-59-3 1.25 5.29 6.599

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.24 27.745

2,4-Dimethylhexane 00589-43-5 1.61 5.21 8.367

3-Methyl-t-2-pentene 00616-12-6 11.66 5.12 59.714

2,2-DiMeHexane 00590-73-8 0.94 5.11 4.812

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.95 39.318

n-Octane 00111-65-9 0.80 4.63 3.688

1-Methylcyclopentene 00693-89-0 12.45 4.63 57.639

2-Methyl-2-pentene 00625-27-4 11.03 4.36 48.134

Cyclopentene 00142-29-0 6.69 4.36 29.130

c-2-Butene 00590-18-1 14.26 4.23 60.377

3-Methyl-c-2-pentene 00922-62-3 12.52 4.09 51.143

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.08 6.552

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.86 25.506

2-Methylpropane 00075-28-5 1.18 3.80 4.467

2,2,5-Trimethylhexane 03522-94-9 1.05 3.51 3.694

Vehicle 209b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7472

Non Zero Mass Species Sorted By VOC
E-86

Propane 00074-98-6 0.46 2.77 1.268

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.50 10.963

2-Methylheptane 00592-27-8 0.97 2.42 2.343

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.37 2.585

ortho-Xylene 00095-47-6 7.58 2.36 17.866

c-1,3-Dimethylcyclohexane 00638-04-0 2.91 2.35 6.845

t-1,2-Dimethylcyclopentane 00822-50-4 2.91 2.07 6.012

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.06 11.914

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.00 23.561

2,2-Dimethylpentane 00590-35-2 1.04 1.99 2.072

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.98 10.977

c-1,3-Dimethylcyclopentane 02532-58-3 2.91 1.87 5.449

Ethylcyclohexane 01678-91-7 1.35 1.82 2.450

3-Methylheptane 00589-81-1 1.12 1.62 1.826

n-Nonane 00111-84-2 0.68 1.47 1.001

3,3-Dimethylpentane 00562-49-2 1.12 1.45 1.625

n-Propylbenzene 00103-65-1 1.96 1.36 2.667

2,2,3-Trimethylbutane 00464-06-2 1.05 1.27 1.339

Unknown #16 2.91 1.22 3.559

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.20 9.418

2,3,5-Trimethylhexane 01069-53-0 1.12 1.12 1.253

Isopropylbenzene (Cumene) 00098-82-8 2.91 1.11 3.242

2,2-Dimethylbutane 00075-83-2 1.11 0.89 0.986

t-1,4-Dimethylcyclohexane 02207-04-7 2.91 0.79 2.297

4-Methyloctane 02216-34-4 0.85 0.72 0.613

4-Methyl-t-2-pentene 00674-76-0 8.04 0.72 5.804

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.72 2.767

Unknown #5 2.91 0.71 2.079

Indan 00496-11-7 3.23 0.70 2.257

n-Decane 00124-18-5 0.59 0.66 0.391

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.65 4.630

c-2-Heptene 06443-92-1 7.08 0.54 3.800

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.50 6.000

Unknown #8 2.91 0.48 1.407

2,4-Dimethylheptane 02213-23-2 1.26 0.47 0.600

1-Nonene 00124-11-8 2.49 0.41 1.018

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.41 4.277

3-Methyloctane 02216-33-3 0.88 0.39 0.347

t-3-Heptene 14686-14-7 6.17 0.37 2.272

1,4-Diethylbenzene 00105-05-5 4.39 0.35 1.515

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.91 0.34 0.985

3,3-Dimethylhexane 00563-16-6 1.15 0.32 0.372

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.19 0.216

Unknown #22 2.91 0.11 0.307

Ethylbenzene 00100-41-4 2.96 0.10 0.294

Total 989.6 2879.4 2.909

No MIR available, use weighted average of 2.9095

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7472

Non Zero Mass Species Sorted By VOC

continued
E-87

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 11.10 15.044

Toluene 00108-88-3 3.93 7.07 27.752

n-Butane 00106-97-8 1.08 5.84 6.286

n-Hexane 00110-54-3 1.13 3.60 4.079

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.11 2.944

3-Methylpentane 00096-14-0 1.69 1.45 2.453

n-Pentane 00109-66-0 1.21 1.41 1.708

Methylcyclopentane 00096-37-7 2.05 0.93 1.897

Benzene 00071-43-2 0.69 0.93 0.643

n-Heptane 00142-82-5 0.97 0.78 0.755

2-Methyl-1-butene 00563-46-2 6.38 0.47 3.021

2-Methylhexane 00591-76-4 1.09 0.35 0.381

2,3-Dimethylpentane 00565-59-3 1.25 0.32 0.404

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.32 3.748

2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.370

t-2-Pentene 00646-04-8 10.47 0.16 1.711

2-Methyl-2-butene 00513-35-9 14.20 0.14 2.009

c-2-Pentene 00627-20-3 10.28 0.07 0.728

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.05 0.383

Total 37.3 76.3 2.043

Vehicle 209b - Fuel 9 psi E0 - 86°F Static - Test 7501

Non Zero Mass Species Sorted By VOC
E-88

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 7.46 29.293

Ethanol 00064-17-5 1.45 3.73 5.410

n-Butane 00106-97-8 1.08 3.03 3.268

2-Methylbutane (Isopentane) 00078-78-4 1.35 2.65 3.585

Cyclohexane 00110-82-7 1.14 2.64 3.007

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.25 16.583

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.78 13.818

n-Hexane 00110-54-3 1.13 1.71 1.944

Benzene 00071-43-2 0.69 1.51 1.046

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.50 8.037

2,4-Dimethylhexane 00589-43-5 1.61 1.11 1.780

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.04 1.244

2-Methylhexane 00591-76-4 1.09 1.01 1.097

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.99 1.388

2-Methyl-2-butene 00513-35-9 14.20 0.89 12.599

3-Methyl-c-2-pentene 00922-62-3 12.52 0.88 11.052

t-2-Butene 00624-64-6 15.20 0.86 13.078

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.84 3.671

3-Methylpentane 00096-14-0 1.69 0.78 1.324

2,2,5-Trimethylhexane 03522-94-9 1.05 0.66 0.699

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.64 7.502

Methylcyclopentane 00096-37-7 2.05 0.50 1.021

2,3-Dimethylpentane 00565-59-3 1.25 0.48 0.602

2,2-DiMeHexane 00590-73-8 0.94 0.48 0.452

3,3-Dimethylpentane 00562-49-2 1.12 0.48 0.533

n-Heptane 00142-82-5 0.97 0.46 0.445

n-Pentane 00109-66-0 1.21 0.45 0.541

2,3,4-Trimethylpentane 00565-75-3 0.95 0.44 0.417

n-Undecane 01120-21-4 0.52 0.42 0.218

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.42 2.747

c-2-Butene 00590-18-1 14.26 0.40 5.721

Methylcyclohexane 00108-87-2 1.56 0.40 0.617

t-2-Pentene 00646-04-8 10.47 0.40 4.150

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.38 2.122

Ethylbenzene 00100-41-4 2.96 0.37 1.109

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.35 1.120

ortho-Xylene 00095-47-6 7.58 0.33 2.480

2,4-Dimethylpentane 00108-08-7 1.46 0.32 0.466

2,3-Dimethylbutane 00079-29-8 0.90 0.32 0.283

Cyclopentene 00142-29-0 6.69 0.31 2.093

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.31 0.500

2-Methyl-2-pentene 00625-27-4 11.03 0.30 3.341

3-Methyl-t-2-pentene 00616-12-6 11.66 0.30 3.471

n-Propylbenzene 00103-65-1 1.96 0.24 0.465

Vehicle 209b - Fuel 9 psi E0 - 105°F Static - Test 7504

Non Zero Mass Species Sorted By VOC
E-89

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 9 psi E0 - 105°F Static - Test 7504

Non Zero Mass Species Sorted By VOC

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.23 2.771

t-2-Hexene 04050-45-7 8.55 0.22 1.843

2-Methyl-1-butene 00563-46-2 6.38 0.19 1.213

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.17 1.239

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.16 0.870

c-2-Pentene 00627-20-3 10.28 0.12 1.195

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.11 1.312

2,3,5-Trimethylhexane 01069-53-0 1.12 0.07 0.084

Total 48.1 186.9 3.886

continued
E-90

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 21.51 158.891

Toluene 00108-88-3 3.93 13.47 52.857

Ethanol 00064-17-5 1.45 9.01 13.058

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 8.09 43.456

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.35 49.266

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.79 6.939

Cyclohexane 00110-82-7 1.14 5.44 6.189

n-Pentane 00109-66-0 1.21 4.53 5.504

n-Hexane 00110-54-3 1.13 4.30 4.884

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.19 18.426

n-Butane 00106-97-8 1.08 4.19 4.516

Unknown #22 4.54 4.16 18.872

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 4.13 5.769

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.52 41.408

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.15 24.983

3-Methylpentane 00096-14-0 1.69 3.03 5.116

Benzene 00071-43-2 0.69 2.79 1.939

2,3,4-Trimethylpentane 00565-75-3 0.95 2.57 2.441

2-Methyl-2-butene 00513-35-9 14.20 2.10 29.813

Methylcyclopentane 00096-37-7 2.05 1.95 4.006

1,3-Butadiene 00106-99-0 12.45 1.95 24.239

2,3-Dimethylbutane 00079-29-8 0.90 1.84 1.650

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.83 10.148

ortho-Xylene 00095-47-6 7.58 1.80 13.626

n-Heptane 00142-82-5 0.97 1.78 1.716

2,4-Dimethylpentane 00108-08-7 1.46 1.64 2.395

Ethylbenzene 00100-41-4 2.96 1.62 4.793

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.60 5.116

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.41 16.855

2-Methylbutane (Isopentane) 00078-78-4 1.35 1.37 1.863

2,3-Dimethylpentane 00565-59-3 1.25 1.30 1.623

t-2-Pentene 00646-04-8 10.47 1.27 13.332

2-Methylhexane 00591-76-4 1.09 1.16 1.260

n-Propylbenzene 00103-65-1 1.96 1.14 2.240

c-2-Pentene 00627-20-3 10.28 1.08 11.124

2,2,5-Trimethylhexane 03522-94-9 1.05 1.06 1.114

2,4-Dimethylhexane 00589-43-5 1.61 1.03 1.660

2-Methyl-1-butene 00563-46-2 6.38 0.90 5.765

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.90 1.442

Methylcyclohexane 00108-87-2 1.56 0.80 1.241

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.79 5.573

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.74 7.778

t-2-Butene 00624-64-6 15.20 0.67 10.245

c-2-Butene 00590-18-1 14.26 0.57 8.162

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.43 5.028

Total 145.0 658.3 4.541

No MIR available, use weighted average of 4.5409

Vehicle 209b - Fuel 9 psi E0 - Dynamic - Test 25761

Non Zero Mass Species Sorted By VOC
E-91

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 77.44 104.928

n-Butane 00106-97-8 1.08 62.23 67.019

Toluene 00108-88-3 3.93 43.02 168.863

Cyclohexane 00110-82-7 1.14 35.66 40.563

Ethanol 00064-17-5 1.45 33.17 48.065

n-Hexane 00110-54-3 1.13 24.59 27.898

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 18.99 26.550

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 14.89 17.849

3-Methylpentane 00096-14-0 1.69 12.42 21.008

n-Pentane 00109-66-0 1.21 10.84 13.168

2-Methyl-2-butene 00513-35-9 14.20 10.26 145.619

2,3-Dimethylbutane 00079-29-8 0.90 9.84 8.842

Benzene 00071-43-2 0.69 9.41 6.534

Methylcyclopentane 00096-37-7 2.05 8.50 17.425

t-2-Pentene 00646-04-8 10.47 8.46 88.597

2,3,4-Trimethylpentane 00565-75-3 0.95 6.48 6.148

c-2-Pentene 00627-20-3 10.28 4.71 48.428

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.61 35.780

2-Methyl-1-butene 00563-46-2 6.38 4.30 27.407

2,4-Dimethylpentane 00108-08-7 1.46 4.23 6.172

2-Methylhexane 00591-76-4 1.09 4.00 4.341

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.26 10.402

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.18 37.221

2,4-Dimethylhexane 00589-43-5 1.61 3.14 5.036

t-2-Hexene 04050-45-7 8.55 3.12 26.678

2,3-Dimethylpentane 00565-59-3 1.25 2.99 3.737

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.73 4.377

3-Methyl-t-2-pentene 00616-12-6 11.66 2.55 29.754

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.48 13.134

2,2,5-Trimethylhexane 03522-94-9 1.05 2.37 2.499

2,2-DiMeHexane 00590-73-8 0.94 2.31 2.170

Methylcyclohexane 00108-87-2 1.56 2.26 3.508

n-Heptane 00142-82-5 0.97 2.24 2.168

3-Methyl-c-2-pentene 00922-62-3 12.52 2.05 25.607

2-Methylpropane 00075-28-5 1.18 2.04 2.399

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.02 10.862

2-Methyl-2-pentene 00625-27-4 11.03 1.96 21.648

Cyclopentene 00142-29-0 6.69 1.82 12.175

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.81 1.978

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.77 13.069

ortho-Xylene 00095-47-6 7.58 1.74 13.179

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.73 11.412

1-Methylcyclopentene 00693-89-0 12.45 1.62 20.182

c-2-Butene 00590-18-1 14.26 1.59 22.730

Vehicle 209b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7508

Non Zero Mass Species Sorted By VOC
E-92

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7508

Non Zero Mass Species Sorted By VOC

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.48 11.771

t-2-Butene 00624-64-6 15.20 1.35 20.554

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.34 7.452

Ethylbenzene 00100-41-4 2.96 1.19 3.520

2,2-Dimethylbutane 00075-83-2 1.11 1.18 1.307

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.10 12.896

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.00 4.406

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.96 5.555

Unknown #16 2.75 0.95 2.623

t-1,2-Dimethylcyclopentane 00822-50-4 2.75 0.89 2.455

n-Octane 00111-65-9 0.80 0.87 0.695

c-1,3-Dimethylcyclopentane 02532-58-3 2.75 0.83 2.281

2,2-Dimethylpentane 00590-35-2 1.04 0.79 0.822

3-Methylheptane 00589-81-1 1.12 0.73 0.822

n-Propylbenzene 00103-65-1 1.96 0.69 1.356

2-Methylheptane 00592-27-8 0.97 0.59 0.575

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.49 5.845

2,3,5-Trimethylhexane 01069-53-0 1.12 0.38 0.421

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.37 2.878

2,2,3-Trimethylbutane 00464-06-2 1.05 0.32 0.337

3,3-Dimethylpentane 00562-49-2 1.12 0.29 0.328

Total 478.6 1316.0 2.749

No MIR available, use weighted average of 2.7495

continued
E-93

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 5.83 22.894

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.54 7.499

n-Butane 00106-97-8 1.08 4.28 4.604

Cyclohexane 00110-82-7 1.14 2.83 3.223

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.23 16.498

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.62 1.937

n-Hexane 00110-54-3 1.13 1.54 1.742

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.49 7.996

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.33 1.862

Ethanol 00064-17-5 1.45 1.24 1.803

Benzene 00071-43-2 0.69 1.14 0.792

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.10 6.088

2-Methyl-2-butene 00513-35-9 14.20 1.06 15.026

3-Methylpentane 00096-14-0 1.69 0.90 1.526

2,3-Dimethylbutane 00079-29-8 0.90 0.90 0.806

2,3,4-Trimethylpentane 00565-75-3 0.95 0.82 0.779

2,4-Dimethylhexane 00589-43-5 1.61 0.79 1.263

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.73 0.793

n-Propylbenzene 00103-65-1 1.96 0.71 1.397

n-Pentane 00109-66-0 1.21 0.63 0.762

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.62 7.318

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.58 2.548

Methylcyclopentane 00096-37-7 2.05 0.56 1.146

Methylcyclohexane 00108-87-2 1.56 0.54 0.843

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.50 3.864

2,2-DiMeHexane 00590-73-8 0.94 0.47 0.438

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.46 2.450

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.46 5.380

2,4-Dimethylpentane 00108-08-7 1.46 0.44 0.641

3-Methyl-t-2-pentene 00616-12-6 11.66 0.42 4.890

c-2-Pentene 00627-20-3 10.28 0.40 4.160

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.40 1.278

c-2-Butene 00590-18-1 14.26 0.39 5.610

t-2-Hexene 04050-45-7 8.55 0.37 3.126

ortho-Xylene 00095-47-6 7.58 0.36 2.706

Ethylbenzene 00100-41-4 2.96 0.34 1.018

2,2-Dimethylbutane 00075-83-2 1.11 0.32 0.359

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.32 2.259

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.27 0.438

2-Methyl-1-butene 00563-46-2 6.38 0.27 1.732

2-Methyl-2-pentene 00625-27-4 11.03 0.25 2.788

2-Methylhexane 00591-76-4 1.09 0.24 0.262

t-2-Butene 00624-64-6 15.20 0.23 3.452

3-Methylheptane 00589-81-1 1.12 0.21 0.232

Vehicle 209b - Fuel 7 psi E0 - 86°F Static - Test 7524

Non Zero Mass Species Sorted By VOC
E-94

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E0 - 86°F Static - Test 7524

Non Zero Mass Species Sorted By VOC

Cyclopentene 00142-29-0 6.69 0.20 1.332

2,2,5-Trimethylhexane 03522-94-9 1.05 0.17 0.182

c- & t-4-Nonene 02198-23-4 4.42 0.08 0.371

n-Octane 00111-65-9 0.80 0.08 0.067

t-2-Pentene 00646-04-8 10.47 0.07 0.755

2,3-Dimethylpentane 00565-59-3 1.25 0.03 0.034

n-Heptane 00142-82-5 0.97 0.03 0.026

Total 46.8 161.0 3.441

continued
E-95

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 9.38 36.819

2-Methylbutane (Isopentane) 00078-78-4 1.35 7.23 9.800

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.46 32.909

Cyclohexane 00110-82-7 1.14 3.72 4.228

n-Butane 00106-97-8 1.08 2.88 3.103

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.72 14.588

Ethanol 00064-17-5 1.45 2.57 3.727

n-Hexane 00110-54-3 1.13 2.29 2.599

Benzene 00071-43-2 0.69 2.05 1.425

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.01 15.600

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.64 2.288

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.53 1.839

3-Methylpentane 00096-14-0 1.69 1.24 2.103

2-Methyl-2-butene 00513-35-9 14.20 1.20 17.094

n-Pentane 00109-66-0 1.21 1.17 1.418

t-2-Pentene 00646-04-8 10.47 1.05 11.043

2,3,4-Trimethylpentane 00565-75-3 0.95 1.05 0.998

Indan 00496-11-7 3.23 1.03 3.338

2,3-Dimethylbutane 00079-29-8 0.90 0.87 0.779

ortho-Xylene 00095-47-6 7.58 0.82 6.213

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.79 9.284

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.73 4.050

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.68 2.978

Methylcyclopentane 00096-37-7 2.05 0.68 1.384

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.62 7.388

n-Propylbenzene 00103-65-1 1.96 0.61 1.188

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.57 3.026

c-2-Pentene 00627-20-3 10.28 0.55 5.668

3-Methyl-t-2-pentene 00616-12-6 11.66 0.55 6.417

2,2-DiMeHexane 00590-73-8 0.94 0.51 0.477

2,4-Dimethylhexane 00589-43-5 1.61 0.50 0.805

Methylcyclohexane 00108-87-2 1.56 0.45 0.703

2-Methyl-1-butene 00563-46-2 6.38 0.43 2.765

2,4-Dimethylpentane 00108-08-7 1.46 0.42 0.611

t-2-Hexene 04050-45-7 8.55 0.42 3.551

2-Methyl-2-pentene 00625-27-4 11.03 0.41 4.468

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.39 2.573

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.37 0.589

3-Methyl-c-2-pentene 00922-62-3 12.52 0.34 4.290

t-2-Butene 00624-64-6 15.20 0.33 4.960

Cyclopentene 00142-29-0 6.69 0.31 2.086

2,2,5-Trimethylhexane 03522-94-9 1.05 0.31 0.323

c-2-Butene 00590-18-1 1.12 0.28 0.313

n-Heptane 00142-82-5 0.97 0.23 0.220

Vehicle 209b - Fuel 7 psi E0 - 105°F Static - Test 7527

Non Zero Mass Species Sorted By VOC
E-96

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E0 - 105°F Static - Test 7527

Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 0.21 0.620

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.19 2.235

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.17 0.541

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.15 0.165

2,3-Dimethylpentane 00565-59-3 1.25 0.12 0.146

2-Methylhexane 00591-76-4 1.09 0.05 0.058

Total 63.3 245.8 3.885

continued
E-97

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 23.40 172.811

Ethanol 00064-17-5 1.45 19.89 28.822

2-Methylbutane (Isopentane) 00078-78-4 1.35 15.24 20.645

n-Butane 00106-97-8 1.08 14.62 15.746

Toluene 00108-88-3 3.93 12.48 48.992

Cyclohexane 00110-82-7 1.14 7.61 8.651

1,3,5-Trimethylbenzene 00108-67-8 11.75 5.25 61.680

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.16 4.987

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.86 20.746

n-Hexane 00110-54-3 1.13 3.68 4.173

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.32 25.747

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.25 4.539

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.19 25.356

Ethylbenzene 00100-41-4 2.96 2.50 7.407

Benzene 00071-43-2 0.69 2.41 1.671

n-Propylbenzene 00103-65-1 1.96 2.12 4.155

Methylcyclopentane 00096-37-7 2.05 2.00 4.092

3-Methylpentane 00096-14-0 1.69 1.81 3.055

ortho-Xylene 00095-47-6 7.58 1.67 12.657

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.67 19.932

t-2-Pentene 00646-04-8 10.47 1.62 17.013

2,4-Dimethylpentane 00108-08-7 1.46 1.61 2.347

2,3,4-Trimethylpentane 00565-75-3 0.95 1.53 1.450

2-Methylhexane 00591-76-4 1.09 1.44 1.559

2,3-Dimethylpentane 00565-59-3 1.25 1.35 1.687

2,3-Dimethylbutane 00079-29-8 0.90 1.29 1.160

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.01 3.217

2-Methyl-2-butene 00513-35-9 14.20 0.84 11.990

2-Methyl-1-butene 00563-46-2 6.38 0.69 4.421

n-Pentane 00109-66-0 1.21 0.56 0.677

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.38 1.677

Total 146.4 543.1 3.708

Vehicle 209b - Fuel 7 psi E0 - Dynamic - Test 25768

Non Zero Mass Species Sorted By VOC
E-98

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 128.86 174.588

n-Butane 00106-97-8 1.08 76.34 82.212

Toluene 00108-88-3 3.93 75.66 296.949

Cyclohexane 00110-82-7 1.14 64.10 72.906

t-3-Hexene & c-3-Hexene 13269-52-8+07642-09-3 7.43 38.95 289.368

Ethanol 00064-17-5 1.45 31.56 45.726

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 30.89 43.183

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 29.15 34.954

3-Methylpentane 00096-14-0 1.69 21.20 35.842

Benzene 00071-43-2 0.69 18.26 12.680

n-Pentane 00109-66-0 1.21 17.87 21.715

2-Methyl-2-butene 00513-35-9 14.20 16.88 239.595

Unknown #2 3.24 16.23 52.569

t-2-Pentene 00646-04-8 10.47 13.99 146.569

Methylcyclopentane 00096-37-7 2.05 13.65 27.980

2,3,4-Trimethylpentane 00565-75-3 0.95 12.88 12.220

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 9.85 76.418

2,4-Dimethylpentane 00108-08-7 1.46 7.65 11.165

c-2-Pentene 00627-20-3 10.28 7.14 73.417

2-Methyl-1-butene 00563-46-2 6.38 7.06 45.029

2-Methylhexane 00591-76-4 1.09 6.85 7.429

2,2,5-Trimethylhexane 03522-94-9 1.05 6.30 6.638

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 6.23 19.874

2,4-Dimethylhexane 00589-43-5 1.61 6.06 9.728

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.95 43.923

2,3-Dimethylpentane 00565-59-3 1.25 5.43 6.776

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.94 57.832

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.88 7.835

t-2-Hexene 04050-45-7 8.55 4.62 39.527

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.62 24.814

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.00 31.363

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.97 21.015

3-Methyl-t-2-pentene 00616-12-6 11.66 3.91 45.631

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.43 3.741

2,2-DiMeHexane 00590-73-8 0.94 3.40 3.204

3-Methyl-c-2-pentene 00922-62-3 12.52 3.10 38.849

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 2.93 18.449

Cyclopentene 00142-29-0 6.69 2.87 19.158

c-2-Butene 00590-18-1 14.26 2.81 40.040

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.80 32.917

2-Methyl-2-pentene 00625-27-4 11.03 2.76 30.409

ortho-Xylene 00095-47-6 7.58 2.73 20.661

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.72 21.617

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.55 16.820

Vehicle 209b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7533

Non Zero Mass Species Sorted By VOC
E-99

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 209b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7533

Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.38 10.442

2,2-Dimethylbutane 00075-83-2 1.11 2.28 2.535

t-2-Butene 00624-64-6 15.20 2.27 34.435

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.01 11.151

t-1,2-Dimethylcyclopentane 00822-50-4 3.24 1.74 5.650

c-1,3-Dimethylcyclopentane 02532-58-3 3.24 1.73 5.606

Ethylbenzene 00100-41-4 2.96 1.69 5.011

n-Propylbenzene 00103-65-1 1.96 1.61 3.161

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.58 6.100

3-Methylheptane 00589-81-1 1.12 1.57 1.763

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.52 8.803

Unknown #16 3.24 1.49 4.835

2,3,5-Trimethylhexane 01069-53-0 1.12 1.45 1.625

n-Octane 00111-65-9 0.80 1.09 0.866

2,2-Dimethylpentane 00590-35-2 1.04 1.07 1.114

t-1,4-Dimethylcyclohexane 02207-04-7 3.24 0.97 3.130

2,2,3-Trimethylbutane 00464-06-2 1.05 0.94 0.996

2-Methylpropane 00075-28-5 1.18 0.92 1.083

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.89 10.621

3,3-Dimethylpentane 00562-49-2 1.12 0.87 0.973

Unknown #5 3.24 0.81 2.609

Indan 00496-11-7 3.23 0.80 2.602

Unknown #22 . 3.24 0.77 2.503

1-Nonene 00124-11-8 2.49 0.62 1.553

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.61 4.293

t-3-Heptene 14686-14-7 6.17 0.58 3.555

2,4-Dimethylheptane 02213-23-2 1.26 0.55 0.697

4-Methyl-t-2-pentene 00674-76-0 8.04 0.55 4.398

4-Methyloctane 02216-34-4 0.85 0.53 0.452

n-Undecane 01120-21-4 0.52 0.50 0.259

n-Nonane 00111-84-2 0.68 0.47 0.318

c-2-Heptene 06443-92-1 7.08 0.38 2.694

Isopropylbenzene (Cumene) 00098-82-8 3.24 0.35 1.129

3,5-Dimethylheptane 00926-82-9 1.42 0.33 0.466

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.28 2.982

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.17 1.707

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.16 0.137

Total 776.5 2515.6 3.239

No MIR available, use weighted average of 3.2395

continued
E-100

Test Fuel Test No.

Bag

THC

mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7449 51.6 89.7 46.3 143.2 3.096 49

Static E10 - 7 psi 7468 63.0 96.2 60.6 186.3 3.072 56

E0 - 9 psi 7523 46.2 121.3 56.1 208.1 3.712 53

E0 - 7 psi 7547 37.5 90.0 33.7 108.4 3.214 40

105° F E10 - 10 psi 7451 147.3 102.1 150.3 473.4 3.150 62

Static E10 - 7 psi 7471 117.5 92.6 108.8 346.6 3.186 69

E0 - 9 psi 7525 69.8 132.1 92.3 296.6 3.215 62

E0 - 7 psi 7549 74.0 104.9 77.6 270.6 3.486 48

Dynamic E10 - 10 psi 25749 198.4 85.9 170.5 569.7 3.342 52

E10 - 7 psi 25756 189.1 100.1 189.2 710.5 3.754 48

E0 - 9 psi 25767 178.0 74.9 133.2 328.8 2.468 41

E0 - 7 psi 25776 234.9 84.5 198.4 848.9 4.278 32

DHB E10 - 10 psi 7462 1386.1 93.7 1298.2 3812.8 2.937 95

Total E10 - 7 psi 7482 1192.5 87.0 1037.4 3101.2 2.989 86

E0 - 9 psi 7531 1143.4 88.3 1010.2 2351.6 2.328 32

E0 - 7 psi 7550 758.3 87.7 665.0 1927.4 2.898 86

Vehicle 210b
E-101

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 6.57 9.515

n-Butane 00106-97-8 1.08 6.22 6.701

Toluene 00108-88-3 3.93 5.87 23.037

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.65 7.657

n-Hexane 00110-54-3 1.13 2.63 2.979

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.51 2.107

n-Pentane 00109-66-0 1.21 1.17 1.426

t-2-Butene 00624-64-6 15.20 1.14 17.324

3-Methylpentane 00096-14-0 1.69 1.12 1.900

2-Methyl-2-butene 00513-35-9 14.20 1.11 15.724

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.01 1.206

Benzene 00071-43-2 0.69 0.94 0.651

t-2-Pentene 00646-04-8 10.47 0.84 8.831

2-Methylpropane 00075-28-5 1.18 0.75 0.879

2,3,5-Trimethylhexane 01069-53-0 1.12 0.63 0.701

2-Methyl-1-butene 00563-46-2 6.38 0.62 3.937

2,3-Dimethylbutane 00079-29-8 0.90 0.60 0.537

Methylcyclopentane 00096-37-7 2.05 0.55 1.120

c-2-Pentene 00627-20-3 10.28 0.46 4.759

Methylcyclohexane 00108-87-2 1.56 0.45 0.700

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.40 2.128

2-Methyl-2-pentene 00625-27-4 11.03 0.39 4.312

Cyclohexane 00110-82-7 1.14 0.37 0.426

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.37 1.186

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.35 2.715

2,2-Dimethylpentane 00590-35-2 1.04 0.34 0.353

3-Methyl-t-2-pentene 00616-12-6 11.66 0.33 3.871

2,4-Dimethylpentane 00108-08-7 1.46 0.33 0.479

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.31 2.434

3-Methylheptane 00589-81-1 1.12 0.29 0.327

2,3,4-Trimethylpentane 00565-75-3 0.95 0.27 0.260

t-2-Hexene 04050-45-7 8.55 0.26 2.197

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.24 1.592

n-Decane 00124-18-5 0.59 0.24 0.141

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.23 2.675

n-Octane 00111-65-9 0.80 0.20 0.160

2,2-DiMeHexane 00590-73-8 0.94 0.19 0.181

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.19 1.040

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.18 0.291

2-Methylhexane 00591-76-4 1.09 0.14 0.154

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.13 1.590

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.13 0.141

c-1,3-Dimethylcyclopentane 02532-58-3 3.10 0.12 0.365

Vehicle 210b - Fuel 10 psi E10 - 86°F Static - Test 7449

Non Zero Mass Species Sorted By VOC
E-102

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 10 psi E10 - 86°F Static - Test 7449

Non Zero Mass Species Sorted By VOC

Cyclopentene 00142-29-0 6.69 0.11 0.716

2,2-Dimethylbutane 00075-83-2 1.11 0.10 0.107

c-2-Butene 00590-18-1 14.26 0.09 1.335

2,3-Dimethylpentane 00565-59-3 1.25 0.09 0.116

n-Heptane 00142-82-5 0.97 0.03 0.026

3-Methyl-c-2-pentene 00922-62-3 12.52 0.02 0.201

Total 46.3 143.2 3.096

No MIR available, use weighted average of 3.0957

continued
E-103

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 26.13 37.866

n-Butane 00106-97-8 1.08 22.93 24.694

Toluene 00108-88-3 3.93 17.77 69.730

2-Methylbutane (Isopentane) 00078-78-4 1.35 10.04 13.603

n-Hexane 00110-54-3 1.13 6.79 7.701

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.67 34.461

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 4.35 6.083

Benzene 00071-43-2 0.69 3.49 2.427

2-Methyl-2-butene 00513-35-9 14.20 3.06 43.498

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.04 3.644

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.89 15.532

t-2-Pentene 00646-04-8 10.47 2.72 28.535

3-Methylpentane 00096-14-0 1.69 2.66 4.501

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.57 19.932

Methylcyclopentane 00096-37-7 2.05 2.02 4.136

Cyclohexane 00110-82-7 1.14 1.91 2.177

n-Pentane 00109-66-0 1.21 1.85 2.250

c-2-Pentene 00627-20-3 10.28 1.60 16.490

2,3-Dimethylbutane 00079-29-8 0.90 1.55 1.396

Methylcyclohexane 00108-87-2 1.56 1.47 2.291

n-Heptane 00142-82-5 0.97 1.36 1.318

2-Methylpropane 00075-28-5 1.18 1.30 1.525

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.22 14.397

2-Methyl-1-butene 00563-46-2 6.38 1.22 7.791

ortho-Xylene 00095-47-6 7.58 1.05 7.959

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.00 4.408

3-Methyl-c-2-pentene 00922-62-3 12.52 0.98 12.273

2-Methylhexane 00591-76-4 1.09 0.95 1.035

2,2-DiMeHexane 00590-73-8 0.94 0.92 0.870

2,3,4-Trimethylpentane 00565-75-3 0.95 0.91 0.865

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.86 2.756

2,4-Dimethylpentane 00108-08-7 1.46 0.80 1.168

Indan 00496-11-7 3.23 0.80 2.579

t-2-Hexene 04050-45-7 8.55 0.78 6.705

c-2-Butene 00590-18-1 14.26 0.70 9.989

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.69 8.092

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.66 4.330

Ethylbenzene 00100-41-4 2.96 0.64 1.908

2,2-Dimethylpentane 00590-35-2 1.04 0.63 0.659

3-Methyl-t-2-pentene 00616-12-6 11.66 0.63 7.340

t-1,2-Dimethylcyclopentane 00822-50-4 3.15 0.63 1.971

2-Methyl-2-pentene 00625-27-4 11.03 0.62 6.889

2,3,5-Trimethylhexane 01069-53-0 1.12 0.61 0.687

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.60 4.777

Vehicle 210b - Fuel 10 psi E10 - 105°F Static - Test 7451

Non Zero Mass Species Sorted By VOC
E-104

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 10 psi E10 - 105°F Static - Test 7451

Non Zero Mass Species Sorted By VOC

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.58 3.232

n-Octane 00111-65-9 0.80 0.56 0.442

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.49 2.597

n-Decane 00124-18-5 0.59 0.48 0.286

2,2,5-Trimethylhexane 03522-94-9 1.05 0.44 0.459

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.43 5.152

2,4-Dimethylhexane 00589-43-5 1.61 0.39 0.627

2,3-Dimethylpentane 00565-59-3 1.25 0.39 0.487

n-Propylbenzene 00103-65-1 1.96 0.38 0.752

3-Methylheptane 00589-81-1 1.12 0.37 0.412

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.35 0.561

n-Nonane 00111-84-2 0.68 0.34 0.230

c-1,3-Dimethylcyclopentane 02532-58-3 3.15 0.28 0.878

t-2-Butene 00624-64-6 15.20 0.21 3.145

2,2-Dimethylbutane 00075-83-2 1.11 0.14 0.157

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.14 0.153

2-Methylheptane 00592-27-8 0.97 0.13 0.125

Cyclopentene 00142-29-0 6.69 0.07 0.483

Total 150.3 473.4 3.150

No MIR available, use weighted average of 3.1499

continued
E-105

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 25.42 99.788

Ethanol 00064-17-5 1.45 25.37 36.763

Methane 00074-82-8 0.01 16.82 0.233

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.94 58.673

n-Butane 00106-97-8 1.08 7.24 7.798

n-Hexane 00110-54-3 1.13 6.62 7.507

Methanol 00067-56-1 0.66 5.82 3.824

Benzene 00071-43-2 0.69 4.96 3.443

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.67 54.675

2-Methylbutane (Isopentane) 00078-78-4 1.35 4.63 6.271

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.00 31.059

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.52 18.915

Methylcyclopentane 00096-37-7 2.05 3.01 6.175

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.90 3.474

2-Methyl-2-butene 00513-35-9 14.20 2.88 40.952

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.74 3.831

2-Methylpropane 00075-28-5 1.18 2.34 2.748

n-Pentane 00109-66-0 1.21 2.10 2.556

Cyclohexane 00110-82-7 1.14 2.09 2.379

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.03 23.901

3-Methylpentane 00096-14-0 1.69 1.67 2.824

3-Methyl-t-2-pentene 00616-12-6 11.66 1.61 18.781

Methylcyclohexane 00108-87-2 1.56 1.60 2.481

3-Methyl-c-2-pentene 00922-62-3 12.52 1.59 19.901

2,3-Dimethylbutane 00079-29-8 0.90 1.58 1.424

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.58 5.042

2,2-DiMeHexane 00590-73-8 0.94 1.56 1.470

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.54 6.753

t-2-Pentene 00646-04-8 10.47 1.53 16.010

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.49 11.796

ortho-Xylene 00095-47-6 7.58 1.36 10.282

2,3,4-Trimethylpentane 00565-75-3 0.95 1.29 1.224

n-Decane 00124-18-5 0.59 1.28 0.759

2-Methyl-1-butene 00563-46-2 6.38 1.23 7.828

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.16 6.420

2-Methylhexane 00591-76-4 1.09 1.15 1.251

2-Methylheptane 00592-27-8 0.97 1.14 1.100

n-Propylbenzene 00103-65-1 1.96 1.11 2.183

2,4-Dimethylhexane 00589-43-5 1.61 1.10 1.771

2,2,5-Trimethylhexane 03522-94-9 1.05 1.03 1.080

2-Methyl-2-pentene 00625-27-4 11.03 0.90 9.924

n-Octane 00111-65-9 0.80 0.81 0.644

c-2-Pentene 00627-20-3 10.28 0.80 8.190

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.61 7.339

Vehicle 210b - Fuel 10 psi E10 - Dynamic - Test 25749

Non Zero Mass Species Sorted By VOC
E-106

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 10 psi E10 - Dynamic - Test 25749

Non Zero Mass Species Sorted By VOC

2,3-Dimethylpentane 00565-59-3 1.25 0.60 0.746

Cyclopentene 00142-29-0 6.69 0.38 2.517

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.35 0.568

Indan 00496-11-7 3.23 0.35 1.128

2,4-Dimethylpentane 00108-08-7 1.46 0.34 0.499

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.25 1.330

n-Heptane 00142-82-5 0.97 0.23 0.222

t-2-Hexene 04050-45-7 8.55 0.15 1.252

Total 170.5 569.7 3.342

continued
E-107

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 220.95 320.157

n-Butane 00106-97-8 1.08 150.10 161.650

2-Methylbutane (Isopentane) 00078-78-4 1.35 119.32 161.666

Toluene 00108-88-3 3.93 111.73 438.558

n-Hexane 00110-54-3 1.13 85.02 96.470

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 50.76 70.959

3-Methylpentane 00096-14-0 1.69 37.11 62.747

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 34.01 40.781

2-Methyl-2-butene 00513-35-9 14.20 32.37 459.437

n-Pentane 00109-66-0 1.21 28.89 35.099

Benzene 00071-43-2 0.69 27.84 19.331

t-2-Pentene 00646-04-8 10.47 27.08 283.609

Methylcyclopentane 00096-37-7 2.05 24.81 50.848

Cyclohexane 00110-82-7 1.14 22.52 25.614

2,3-Dimethylbutane 00079-29-8 0.90 20.90 18.782

c-2-Pentene 00627-20-3 10.28 14.07 144.667

2-Methylhexane 00591-76-4 1.09 14.03 15.225

Methylcyclohexane 00108-87-2 1.56 13.58 21.118

2-Methyl-1-butene 00563-46-2 6.38 13.52 86.241

n-Heptane 00142-82-5 0.97 12.84 12.404

2,3,4-Trimethylpentane 00565-75-3 0.95 12.58 11.936

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 12.19 38.911

2,4-Dimethylpentane 00108-08-7 1.46 10.87 15.859

t-2-Butene 00624-64-6 15.20 9.42 143.219

t-2-Hexene 04050-45-7 8.55 8.95 76.543

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 8.83 103.340

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.39 65.050

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 7.37 39.025

2,3-Dimethylpentane 00565-59-3 1.25 7.06 8.810

2-Methylpropane 00075-28-5 1.18 6.88 8.091

3-Methyl-t-2-pentene 00616-12-6 11.66 6.78 79.092

2,2-DiMeHexane 00590-73-8 0.94 6.44 6.064

c-2-Butene 00590-18-1 14.26 6.05 86.334

1-Methylcyclopentene 00693-89-0 12.45 5.82 72.486

3-Methyl-c-2-pentene 00922-62-3 12.52 5.81 72.707

2,4-Dimethylhexane 00589-43-5 1.61 5.74 9.222

2-Methyl-2-pentene 00625-27-4 11.03 5.70 62.866

n-Propylbenzene 00103-65-1 1.96 5.60 10.970

Cyclopentene 00142-29-0 6.69 5.49 36.724

n-Octane 00111-65-9 0.80 5.29 4.214

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.07 33.491

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.74 25.450

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.35 6.976

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.32 34.326

Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462

Non Zero Mass Species Sorted By VOC
E-108

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462

Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.19 30.982

2,2,5-Trimethylhexane 03522-94-9 1.05 3.41 3.587

2-Methylheptane 00592-27-8 0.97 3.08 2.978

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.91 3.177

2,2-Dimethylbutane 00075-83-2 1.11 2.88 3.197

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.87 16.584

t-1,2-Dimethylcyclopentane 00822-50-4 2.94 2.84 8.354

ortho-Xylene 00095-47-6 7.58 2.72 20.614

Propane 00074-98-6 0.46 2.57 1.173

3-Methylheptane 00589-81-1 1.12 2.39 2.686

c-1,3-Dimethylcyclopentane 02532-58-3 2.94 2.36 6.944

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.19 9.607

c-1,3-Dimethylcyclohexane 00638-04-0 2.94 2.01 5.913

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.90 22.357

2,2-Dimethylpentane 00590-35-2 1.04 1.87 1.948

3,3-Dimethylpentane 00562-49-2 1.12 1.64 1.838

Ethylbenzene 00100-41-4 2.96 1.56 4.622

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.51 8.373

2,2,3-Trimethylbutane 00464-06-2 1.05 1.48 1.557

2,3,5-Trimethylhexane 01069-53-0 1.12 1.48 1.654

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.33 10.441

3,5-Dimethylheptane 00926-82-9 1.42 1.27 1.813

n-Nonane 00111-84-2 0.68 1.24 0.846

n-Decane 00124-18-5 0.59 1.10 0.649

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.94 3.641

t-1,4-Dimethylcyclohexane 02207-04-7 2.94 0.93 2.719

4-Methyloctane 02216-34-4 0.85 0.84 0.710

n-Undecane 01120-21-4 0.52 0.78 0.407

Unknown #16 2.94 0.77 2.266

1,3-Butadiene 00106-99-0 12.45 0.75 9.317

3,3-Dimethylhexane 00563-16-6 1.15 0.75 0.859

Unknown #8 2.94 0.71 2.071

Unknown #5 2.94 0.70 2.055

c-2-Heptene 06443-92-1 7.08 0.64 4.497

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.54 3.522

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.53 5.604

t-3-Heptene 14686-14-7 6.17 0.51 3.162

2,4-Dimethylheptane 02213-23-2 1.26 0.51 0.643

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.49 3.501

3-Methyloctane 02216-33-3 0.88 0.40 0.358

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.40 3.349

4-Methyl-t-2-pentene 00674-76-0 8.04 0.39 3.119

continued
E-109

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462

Non Zero Mass Species Sorted By VOC

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.36 4.244

Unknown #22 . 2.94 0.34 0.989

1-Heptene 00592-76-7 4.29 0.33 1.428

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.94 0.32 0.933

1-Nonene 00124-11-8 2.49 0.32 0.786

Isopropylbenzene (Cumene) 00098-82-8 2.94 0.28 0.835

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.28 1.744

Indan 00496-11-7 3.23 0.27 0.886

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.17 0.186

Total 1298.2 3812.8 2.937

No MIR available, use weighted average of 2.9369

continued
E-110

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 9.09 13.176

Toluene 00108-88-3 3.93 7.16 28.122

n-Propylbenzene 00103-65-1 1.96 6.76 13.254

n-Hexane 00110-54-3 1.13 3.69 4.183

2-Methylbutane (Isopentane) 00078-78-4 1.35 3.45 4.674

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.06 2.876

Benzene 00071-43-2 0.69 1.76 1.225

2-Methyl-2-butene 00513-35-9 14.20 1.70 24.198

3-Methylpentane 00096-14-0 1.69 1.66 2.811

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.63 1.952

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.40 7.514

t-2-Pentene 00646-04-8 10.47 0.99 10.400

Cyclohexane 00110-82-7 1.14 0.99 1.128

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.93 6.846

n-Butane 00106-97-8 1.08 0.91 0.984

c-2-Pentene 00627-20-3 10.28 0.90 9.302

2,3-Dimethylbutane 00079-29-8 0.90 0.90 0.809

n-Pentane 00109-66-0 1.21 0.86 1.048

Methylcyclopentane 00096-37-7 2.05 0.75 1.538

2-Methylheptane 00592-27-8 0.97 0.71 0.688

2,2,5-Trimethylhexane 03522-94-9 1.05 0.68 0.712

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.67 5.176

2,3,4-Trimethylpentane 00565-75-3 0.95 0.64 0.611

ortho-Xylene 00095-47-6 7.58 0.63 4.770

n-Heptane 00142-82-5 0.97 0.62 0.599

Methylcyclohexane 00108-87-2 1.56 0.61 0.946

2,2-DiMeHexane 00590-73-8 0.94 0.60 0.562

2-Methylhexane 00591-76-4 1.09 0.54 0.588

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.40 1.292

c-1,3-Dimethylcyclohexane 00638-04-0 3.07 0.40 1.234

2,4-Dimethylhexane 00589-43-5 1.61 0.39 0.634

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.38 1.677

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.38 4.415

3-Methylheptane 00589-81-1 1.12 0.38 0.422

2-Methyl-1-butene 00563-46-2 6.38 0.36 2.322

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.36 2.545

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.36 0.574

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.35 1.947

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.35 1.846

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.30 3.487

2,3,5-Trimethylhexane 01069-53-0 1.12 0.29 0.326

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.27 2.165

2,2-Dimethylpentane 00590-35-2 1.04 0.25 0.263

3-Methyl-t-2-pentene 00616-12-6 11.66 0.25 2.875

Vehicle 210b - Fuel 7 psi E10 - 86°F Static - Test 7468

Non Zero Mass Species Sorted By VOC
E-111

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 7 psi E10 - 86°F Static - Test 7468

Non Zero Mass Species Sorted By VOC

2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.359

n-Octane 00111-65-9 0.80 0.24 0.187

2,3-Dimethylpentane 00565-59-3 1.25 0.22 0.280

t-2-Hexene 04050-45-7 8.55 0.22 1.879

Cyclopentene 00142-29-0 6.69 0.18 1.182

2-Methyl-2-pentene 00625-27-4 11.03 0.17 1.892

Ethylbenzene 00100-41-4 2.96 0.17 0.492

Indan 00496-11-7 3.23 0.15 0.501

t-1,2-Dimethylcyclopentane 00822-50-4 3.07 0.13 0.402

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.07 0.073

c-1,3-Dimethylcyclopentane 02532-58-3 3.07 0.05 0.165

c-2-Butene 00590-18-1 14.26 0.01 0.157

Total 60.6 186.3 3.072

No MIR available, use weighted average of 3.0717

continued
E-112

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 19.89 28.827

Toluene 00108-88-3 3.93 14.19 55.715

n-Hexane 00110-54-3 1.13 6.43 7.298

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.86 7.933

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.47 4.855

3-Methylpentane 00096-14-0 1.69 2.92 4.939

Benzene 00071-43-2 0.69 2.82 1.956

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.80 3.358

Methanol 00067-56-1 0.66 2.75 1.806

Cyclohexane 00110-82-7 1.14 2.70 3.075

n-Butane 00106-97-8 1.08 2.33 2.512

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.24 12.029

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.17 16.849

2-Methyl-2-butene 00513-35-9 14.20 2.07 29.337

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.01 14.814

Methylcyclopentane 00096-37-7 2.05 1.97 4.031

t-2-Pentene 00646-04-8 10.47 1.83 19.185

n-Pentane 00109-66-0 1.21 1.81 2.202

2-Methylhexane 00591-76-4 1.09 1.63 1.770

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.48 4.732

2,3-Dimethylbutane 00079-29-8 0.90 1.47 1.322

n-Heptane 00142-82-5 0.97 1.28 1.240

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.24 14.615

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.07 4.690

c-2-Pentene 00627-20-3 10.28 1.04 10.707

2-Methyl-1-butene 00563-46-2 6.38 1.03 6.540

2,4-Dimethylpentane 00108-08-7 1.46 1.01 1.469

3,3-Dimethylpentane 00562-49-2 1.12 0.96 1.073

2,3,4-Trimethylpentane 00565-75-3 0.95 0.91 0.859

Methylcyclohexane 00108-87-2 1.56 0.82 1.270

2,3-Dimethylpentane 00565-59-3 1.25 0.73 0.912

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.68 3.770

Cyclopentene 00142-29-0 6.69 0.68 4.544

ortho-Xylene 00095-47-6 7.58 0.65 4.925

3-Methyl-c-2-pentene 00922-62-3 12.52 0.64 8.054

Unknown #16 8.55 0.64 5.476

Indan 00496-11-7 3.23 0.64 2.071

n-Octane 00111-65-9 0.80 0.63 0.505

2,4-Dimethylhexane 00589-43-5 1.61 0.62 0.995

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.60 7.052

Ethylbenzene 00100-41-4 2.96 0.48 1.412

t-2-Hexene 04050-45-7 8.55 0.47 3.992

2,2-Dimethylpentane 00590-35-2 1.04 0.47 0.486

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.45 3.215

Vehicle 210b - Fuel 7 psi E10 - 105°F Static - Test 7471

Non Zero Mass Species Sorted By VOC
E-113

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 7 psi E10 - 105°F Static - Test 7471

Non Zero Mass Species Sorted By VOC

n-Nonane 00111-84-2 0.68 0.43 0.296

2,2-DiMeHexane 00590-73-8 0.94 0.41 0.389

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.41 3.232

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.40 2.674

3-Methylheptane 00589-81-1 1.12 0.39 0.433

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.38 0.613

c-2-Butene 00590-18-1 14.26 0.38 5.403

3-Methyl-t-2-pentene 00616-12-6 11.66 0.37 4.356

n-Decane 00124-18-5 0.59 0.31 0.181

1,4-Diethylbenzene 00105-05-5 4.39 0.30 1.336

2-Methyl-2-pentene 00625-27-4 11.03 0.30 3.320

2,2,3-Trimethylbutane 00464-06-2 1.05 0.26 0.274

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.23 2.801

2,2,5-Trimethylhexane 03522-94-9 1.05 0.21 0.222

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.21 0.225

2,3,5-Trimethylhexane 01069-53-0 1.12 0.20 0.224

2,2-Dimethylbutane 00075-83-2 1.11 0.19 0.207

Unknown #5 3.19 0.18 0.577

Ethylcyclohexane 01678-91-7 1.35 0.15 0.208

t-1,4-Dimethylcyclohexane 02207-04-7 3.19 0.14 0.441

c-1,3-Dimethylcyclopentane 02532-58-3 3.19 0.11 0.364

3-Methyloctane 02216-33-3 0.88 0.11 0.098

c-1,3-Dimethylcyclohexane 00638-04-0 3.19 0.08 0.255

2-Methylheptane 00592-27-8 0.97 0.04 0.037

t-1,2-Dimethylcyclopentane 00822-50-4 3.19 0.01 0.016

Total 108.8 346.6 3.186

No MIR available, use weighted average of 3.1858

continued
E-114

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 49.37 96.738

Ethanol 00064-17-5 1.45 25.13 36.416

Toluene 00108-88-3 3.93 23.14 90.836

Methane 00074-82-8 0.01 12.96 0.180

Unknown #9 3.75 8.61 32.314

t-2-Butene 00624-64-6 15.20 6.42 97.600

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.35 28.739

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.81 35.510

Unknown #22 . 3.75 4.46 16.759

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.17 32.377

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.83 44.790

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.34 39.255

Benzene 00071-43-2 0.69 3.13 2.176

Methylcyclohexane 00108-87-2 1.56 2.62 4.079

2,4-Dimethylpentane 00108-08-7 1.46 2.59 3.777

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.37 10.407

Unknown #16 3.75 2.36 8.872

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.25 12.469

2-Methyl-2-butene 00513-35-9 14.20 2.22 31.533

2,3,4-Trimethylpentane 00565-75-3 0.95 1.66 1.579

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.49 8.598

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.33 15.834

t-1,2-Dimethylcyclopentane 00822-50-4 3.75 1.25 4.692

Methylcyclopentane 00096-37-7 2.05 1.17 2.405

ortho-Xylene 00095-47-6 7.58 1.15 8.702

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.14 1.366

n-Nonane 00111-84-2 0.68 1.10 0.750

n-Heptane 00142-82-5 0.97 1.05 1.010

c-1,3-Dimethylcyclohexane 00638-04-0 3.75 1.03 3.878

2,4-Dimethylhexane 00589-43-5 1.61 0.79 1.272

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.79 1.272

n-Octane 00111-65-9 0.80 0.77 0.610

c-2-Pentene 00627-20-3 10.28 0.75 7.761

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.57 0.622

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 3.82 0.57 2.162

n-Hexane 00110-54-3 1.13 0.54 0.608

1,4-Diethylbenzene 00105-05-5 4.39 0.51 2.247

3-Methyl-t-2-pentene 00616-12-6 11.66 0.42 4.887

3-Methyl-c-2-pentene 00922-62-3 12.52 0.40 4.984

c-2-Butene 00590-18-1 14.26 0.34 4.917

2,3-Dimethylpentane 00565-59-3 1.25 0.34 0.427

2-Methylhexane 00591-76-4 1.09 0.30 0.325

2-Methyl-2-pentene 00625-27-4 11.03 0.21 2.312

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.20 1.587

Vehicle 210b - Fuel 7 psi E10 - Dynamic - Test 25756

Non Zero Mass Species Sorted By VOC
E-115

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 7 psi E10 - Dynamic - Test 25756

Non Zero Mass Species Sorted By VOC

continued

2,2,5-Trimethylhexane 03522-94-9 1.05 0.09 0.092

Cyclopentene 00142-29-0 6.69 0.08 0.560

n-Undecane 01120-21-4 0.52 0.03 0.014

t-2-Hexene 04050-45-7 8.55 0.02 0.179

Total 189.2 710.5 3.754

No MIR available, use weighted average of 3.7545
E-116

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 189.14 274.057

Toluene 00108-88-3 3.93 105.48 414.004

2-Methylbutane (Isopentane) 00078-78-4 1.35 84.31 114.234

n-Hexane 00110-54-3 1.13 78.27 88.812

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 42.94 60.023

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 32.59 39.085

3-Methylpentane 00096-14-0 1.69 31.61 53.452

2-Methyl-2-butene 00513-35-9 14.20 25.77 365.852

Benzene 00071-43-2 0.69 25.76 17.885

n-Propylbenzene 00103-65-1 1.96 23.14 45.338

n-Pentane 00109-66-0 1.21 23.05 28.006

Methylcyclopentane 00096-37-7 2.05 21.91 44.904

t-2-Pentene 00646-04-8 10.47 21.33 223.407

Cyclohexane 00110-82-7 1.14 20.87 23.733

n-Butane 00106-97-8 1.08 19.35 20.836

2,3-Dimethylbutane 00079-29-8 0.90 17.41 15.642

Methylcyclohexane 00108-87-2 1.56 12.74 19.820

Methanol 00067-56-1 0.66 12.58 8.268

2-Methylhexane 00591-76-4 1.09 12.28 13.331

2,3,4-Trimethylpentane 00565-75-3 0.95 12.08 11.463

c-2-Pentene 00627-20-3 10.28 11.28 116.014

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 11.28 35.981

n-Heptane 00142-82-5 0.97 11.03 10.652

2-Methyl-1-butene 00563-46-2 6.38 10.29 65.662

2,4-Dimethylpentane 00108-08-7 1.46 9.90 14.447

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 9.44 73.237

t-2-Hexene 04050-45-7 8.55 7.58 64.823

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.47 87.416

2,3-Dimethylpentane 00565-59-3 1.25 6.60 8.243

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.45 34.196

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.40 34.345

3-Methyl-t-2-pentene 00616-12-6 11.66 5.93 69.157

2,2-DiMeHexane 00590-73-8 0.94 5.87 5.526

3-Methyl-c-2-pentene 00922-62-3 12.52 5.62 70.387

2,4-Dimethylhexane 00589-43-5 1.61 5.56 8.934

n-Octane 00111-65-9 0.80 5.51 4.384

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.36 39.610

c-2-Butene 00590-18-1 14.26 5.21 74.262

1-Methylcyclopentene 00693-89-0 12.45 4.83 60.185

2-Methyl-2-pentene 00625-27-4 11.03 4.76 52.523

Cyclopentene 00142-29-0 6.69 4.64 31.020

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.62 36.682

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.50 29.726

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.45 7.138

Vehicle 210b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7482

Non Zero Mass Species Sorted By VOC
E-117

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7482

Non Zero Mass Species Sorted By VOC

2,2,5-Trimethylhexane 03522-94-9 1.05 4.32 4.546

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.71 4.056

2-Methylpropane 00075-28-5 1.18 3.06 3.604

2-Methylheptane 00592-27-8 0.97 2.89 2.800

t-1,2-Dimethylcyclopentane 00822-50-4 2.99 2.84 8.492

ortho-Xylene 00095-47-6 7.58 2.58 19.575

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.55 29.924

2,2-Dimethylpentane 00590-35-2 1.04 2.40 2.504

c-1,3-Dimethylcyclopentane 02532-58-3 2.99 2.21 6.593

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.15 11.914

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.15 12.399

Ethylcyclohexane 01678-91-7 1.35 2.09 2.815

3-Methylheptane 00589-81-1 1.12 2.06 2.315

2,2-Dimethylbutane 00075-83-2 1.11 1.78 1.982

3,3-Dimethylpentane 00562-49-2 1.12 1.74 1.945

Ethylbenzene 00100-41-4 2.96 1.70 5.025

c-1,3-Dimethylcyclohexane 00638-04-0 2.99 1.65 4.941

Unknown #16 2.99 1.62 4.840

2,3,5-Trimethylhexane 01069-53-0 1.12 1.34 1.496

2,2,3-Trimethylbutane 00464-06-2 1.05 1.24 1.304

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.21 4.623

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.05 8.207

4-Methyloctane 02216-34-4 0.85 1.05 0.888

n-Nonane 00111-84-2 0.68 1.03 0.706

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.90 3.481

t-1,4-Dimethylcyclohexane 02207-04-7 2.99 0.80 2.390

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.76 0.650

3,3-Dimethylhexane 00563-16-6 1.15 0.75 0.862

Unknown #5 2.99 0.70 2.085

1,3-Diethylbenzene 00141-93-5 7.08 0.63 4.457

Unknown #8 2.99 0.63 1.877

t-3-Heptene 14686-14-7 6.17 0.62 3.814

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.99 0.53 1.572

c-2-Heptene 06443-92-1 7.08 0.52 3.652

n-Decane 00124-18-5 0.59 0.52 0.305

1-Nonene 00124-11-8 2.49 0.42 1.058

3-Methyloctane 02216-33-3 0.88 0.41 0.367

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.41 4.327

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.38 2.474

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.32 2.696

2,4-Dimethylheptane 02213-23-2 1.26 0.28 0.352

1-Octene 00111-66-0 3.14 0.19 0.590

Total 1037.4 3101.2 2.989

No MIR available, use weighted average of 2.9895

continued
E-118

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.96 8.079

Toluene 00108-88-3 3.93 5.77 22.658

Cyclohexane 00110-82-7 1.14 4.27 4.855

n-Butane 00106-97-8 1.08 3.06 3.297

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.95 14.395

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.95 2.336

Ethanol 00064-17-5 1.45 1.83 2.655

n-Hexane 00110-54-3 1.13 1.60 1.819

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.50 2.095

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.41 10.971

2,3-Dimethylbutane 00079-29-8 10.48 1.23 12.879

Methylcyclopentane 00096-37-7 2.05 1.22 2.493

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.21 6.495

Benzene 00071-43-2 0.69 1.21 0.838

Methylcyclohexane 00108-87-2 1.56 1.13 1.752

t-2-Butene 00624-64-6 15.20 1.12 17.027

2-Methyl-2-butene 00513-35-9 14.20 1.04 14.806

c-2-Butene 00590-18-1 1.12 0.98 1.098

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.92 4.027

n-Pentane 00109-66-0 1.21 0.91 1.102

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.90 4.977

2,4-Dimethylhexane 00589-43-5 1.61 0.89 1.437

3-Methylpentane 00096-14-0 1.69 0.88 1.481

Propane 00074-98-6 0.46 0.82 0.377

2,2,5-Trimethylhexane 03522-94-9 1.05 0.82 0.864

2,3,4-Trimethylpentane 00565-75-3 0.95 0.81 0.764

n-Propylbenzene 00103-65-1 1.96 0.76 1.492

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.75 3.993

2-Methylpropane 00075-28-5 1.18 0.69 0.813

Unknown #16 3.71 0.64 2.358

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.58 6.929

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.56 0.895

3-Methyl-c-2-pentene 00922-62-3 12.52 0.54 6.738

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.52 6.074

2,4-Dimethylpentane 00108-08-7 1.46 0.52 0.754

c-2-Pentene 00627-20-3 10.28 0.50 5.134

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.49 0.537

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.47 5.530

t-2-Pentene 00646-04-8 10.47 0.41 4.242

2,2-Dimethylbutane 00075-83-2 1.11 0.36 0.404

t-2-Hexene 04050-45-7 8.55 0.36 3.037

3-Methyl-t-2-pentene 00616-12-6 11.66 0.32 3.765

2-Methyl-2-pentene 00625-27-4 11.03 0.30 3.266

2-Methyl-1-butene 00563-46-2 6.38 0.29 1.876

Vehicle 210b - Fuel 9 psi E0 - 86°F Static - Test 7523

Non Zero Mass Species Sorted By VOC
E-119

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 9 psi E0 - 86°F Static - Test 7523

Non Zero Mass Species Sorted By VOC

2,3,5-Trimethylhexane 01069-53-0 1.12 0.29 0.325

Unknown #22 3.71 0.26 0.966

Cyclopentene 00142-29-0 6.69 0.23 1.513

n-Heptane 00142-82-5 0.97 0.21 0.208

2,3-Dimethylpentane 00565-59-3 1.25 0.19 0.240

2-Methylhexane 00591-76-4 1.09 0.14 0.155

Ethylbenzene 00100-41-4 2.96 0.13 0.392

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.09 0.280

ortho-Xylene 00095-47-6 7.58 0.08 0.622

Total 56.1 208.1 3.712

No MIR available, use weighted average of 3.7122

continued
E-120

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 11.62 45.627

2-Methylbutane (Isopentane) 00078-78-4 1.35 8.51 11.534

n-Butane 00106-97-8 1.08 7.76 8.352

Cyclohexane 00110-82-7 1.14 6.68 7.592

Ethanol 00064-17-5 1.45 5.88 8.523

n-Hexane 00110-54-3 1.13 3.70 4.199

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.00 4.200

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.92 3.502

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.12 11.380

Benzene 00071-43-2 0.69 1.98 1.372

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.97 15.278

3-Methylpentane 00096-14-0 1.69 1.92 3.241

2,3-Dimethylbutane 00079-29-8 0.90 1.69 1.517

Methylcyclopentane 00096-37-7 2.05 1.51 3.105

2-Methyl-2-butene 00513-35-9 14.20 1.46 20.719

n-Pentane 00109-66-0 1.21 1.35 1.644

2,3,4-Trimethylpentane 00565-75-3 0.95 1.28 1.217

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.24 14.603

Unknown #16 3.21 1.08 3.478

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.02 5.645

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.02 4.475

2,4-Dimethylhexane 00589-43-5 1.61 0.99 1.592

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.98 3.142

Ethylbenzene 00100-41-4 2.96 0.92 2.735

t-2-Pentene 00646-04-8 10.47 0.91 9.575

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.88 6.479

Indan 00496-11-7 3.23 0.80 2.585

2-Methylhexane 00591-76-4 1.09 0.78 0.850

2,2,5-Trimethylhexane 03522-94-9 1.05 0.76 0.804

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.69 1.102

2,4-Dimethylpentane 00108-08-7 1.46 0.67 0.973

2,2-DiMeHexane 00590-73-8 0.94 0.66 0.622

t-2-Hexene 04050-45-7 8.55 0.62 5.321

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.62 0.677

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.61 3.243

n-Propylbenzene 00103-65-1 1.96 0.61 1.197

3-Methyl-t-2-pentene 00616-12-6 11.66 0.57 6.652

Cyclopentene 00142-29-0 6.69 0.57 3.785

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.56 6.578

c-1,3-Dimethylcyclopentane 02532-58-3 3.21 0.56 1.801

Methylcyclohexane 00108-87-2 1.56 0.55 0.860

2,3,5-Trimethylhexane 01069-53-0 1.12 0.53 0.596

3-Methyl-c-2-pentene 00922-62-3 12.52 0.52 6.493

2-Methyl-1-butene 00563-46-2 6.38 0.51 3.274

Vehicle 210b - Fuel 9 psi E0 - 105°F Static - Test 7525

Non Zero Mass Species Sorted By VOC
E-121

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 9 psi E0 - 105°F Static - Test 7525

Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 0.51 3.852

2,3-Dimethylpentane 00565-59-3 1.25 0.50 0.621

c-2-Pentene 00627-20-3 10.28 0.50 5.112

n-Heptane 00142-82-5 0.97 0.50 0.480

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.49 5.904

c-2-Butene 00590-18-1 14.26 0.43 6.174

2,2-Dimethylbutane 00075-83-2 1.11 0.43 0.474

2-Methyl-2-pentene 00625-27-4 11.03 0.39 4.349

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.37 2.467

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.36 2.889

n-Octane 00111-65-9 0.80 0.36 0.287

n-Undecane 01120-21-4 0.52 0.34 0.176

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.33 2.347

1-Methylcyclopentene 00693-89-0 12.45 0.32 4.037

t-2-Butene 00624-64-6 15.20 0.28 4.224

n-Nonane 00111-84-2 0.68 0.23 0.157

1,4-Diethylbenzene 00105-05-5 4.39 0.16 0.685

2,4-Dimethylheptane 02213-23-2 1.26 0.14 0.177

Total 92.3 296.6 3.215

No MIR available, use weighted average of 3.2145

continued
E-122

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 23.02 45.118

Toluene 00108-88-3 3.93 18.28 71.734

Methane 00074-82-8 0.01 11.43 0.158

n-Butane 00106-97-8 1.08 10.27 11.057

Ethanol 00064-17-5 1.45 9.56 13.853

Cyclohexane 00110-82-7 1.14 8.21 9.341

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.39 7.302

n-Hexane 00110-54-3 1.13 4.73 5.367

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.65 5.579

Unknown #22 . 2.47 3.41 8.417

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.58 3.606

3-Methylpentane 00096-14-0 1.69 2.39 4.035

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.29 12.290

2,3,5-Trimethylhexane 01069-53-0 1.12 2.26 2.537

2,2,5-Trimethylhexane 03522-94-9 1.05 2.26 2.385

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.99 3.189

Benzene 00071-43-2 0.69 1.83 1.273

2,3-Dimethylbutane 00079-29-8 10.48 1.78 18.707

Methylcyclopentane 00096-37-7 2.05 1.64 3.358

2,3,4-Trimethylpentane 00565-75-3 0.95 1.55 1.470

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.52 12.053

t-2-Pentene 00646-04-8 10.47 1.04 10.885

Methylcyclohexane 00108-87-2 1.56 1.03 1.598

2,2-Dimethylbutane 00075-83-2 1.11 0.93 1.034

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.93 4.086

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.91 10.817

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.88 10.264

2,4-Dimethylhexane 00589-43-5 1.61 0.79 1.276

3-Methyl-t-2-pentene 00616-12-6 11.66 0.76 8.817

3-Methyl-c-2-pentene 00922-62-3 12.52 0.67 8.414

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.67 5.197

c-2-Butene 00590-18-1 14.26 0.65 9.260

2,4-Dimethylpentane 00108-08-7 1.46 0.56 0.813

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.45 5.325

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.45 2.510

2-Methyl-1-butene 00563-46-2 6.38 0.39 2.486

n-Pentane 00109-66-0 1.21 0.33 0.406

ortho-Xylene 00095-47-6 7.58 0.25 1.907

n-Heptane 00142-82-5 0.97 0.21 0.203

Ethylbenzene 00100-41-4 2.96 0.19 0.551

2,3-Dimethylpentane 00565-59-3 1.25 0.09 0.107

Total 133.2 328.8 2.468

No MIR available, use weighted average of 2.4679

Vehicle 210b - Fuel 9 psi E0 - Dynamic - Test 25767

Non Zero Mass Species Sorted By VOC
E-123

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 54.04 78.296

Benzene 00071-43-2 0.69 22.22 15.428

2-Methylbutane (Isopentane) 00078-78-4 1.35 144.00 195.102

2,3-Dimethylbutane 00079-29-8 0.90 21.42 19.250

3-Methylpentane 00096-14-0 1.69 29.96 50.665

Methylcyclopentane 00096-37-7 2.05 20.36 41.734

n-Butane 00106-97-8 1.08 155.08 167.008

2,4-Dimethylpentane 00108-08-7 1.46 11.61 16.947

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.63 90.175

Toluene 00108-88-3 3.93 102.96 404.127

n-Pentane 00109-66-0 1.21 22.14 26.902

n-Hexane 00110-54-3 1.13 57.31 65.027

Cyclohexane 00110-82-7 1.14 108.36 123.241

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.62 27.493

n-Heptane 00142-82-5 0.97 5.50 5.308

2-Methyl-2-butene 00513-35-9 14.20 22.23 315.503

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 46.07 55.239

2-Methyl-1-butene 00563-46-2 6.38 8.33 53.151

2,3-Dimethylpentane 00565-59-3 1.25 8.66 10.809

2,3,4-Trimethylpentane 00565-75-3 0.95 18.40 17.463

2,4-Dimethylhexane 00589-43-5 1.61 8.99 14.433

2,2-DiMeHexane 00590-73-8 0.94 5.68 5.350

2-Methylhexane 00591-76-4 1.09 10.00 10.857

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.51 10.452

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.74 30.392

3-Methyl-t-2-pentene 00616-12-6 11.66 6.25 72.822

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.21 16.338

c-2-Pentene 00627-20-3 10.28 9.61 98.755

t-2-Pentene 00646-04-8 10.47 17.57 184.018

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 43.96 61.453

2,2,5-Trimethylhexane 03522-94-9 1.05 7.84 8.251

t-2-Hexene 04050-45-7 8.55 6.97 59.590

Total 1010.2 2351.6 2.328

Vehicle 210b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7531

Non Zero Mass Species Sorted By VOC
E-124

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 2.37 3.428

Benzene 00071-43-2 0.69 1.75 1.218

2-Methylbutane (Isopentane) 00078-78-4 1.35 1.94 2.631

2,3-Dimethylbutane 00079-29-8 0.90 0.35 0.315

ortho-Xylene 00095-47-6 7.58 0.68 5.127

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.10 5.908

3-Methylpentane 00096-14-0 1.69 0.39 0.658

Methylcyclopentane 00096-37-7 2.05 0.54 1.098

Ethylbenzene 00100-41-4 2.96 0.16 0.468

n-Butane 00106-97-8 1.08 2.49 2.684

2,4-Dimethylpentane 00108-08-7 1.46 0.44 0.638

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.94 7.257

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.33 3.859

Toluene 00108-88-3 3.93 6.01 23.579

n-Pentane 00109-66-0 1.21 0.20 0.248

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.26 3.053

n-Hexane 00110-54-3 1.13 1.08 1.225

Cyclohexane 00110-82-7 1.14 3.28 3.734

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.31 0.994

Cyclopentene 00142-29-0 6.69 0.17 1.112

n-Heptane 00142-82-5 0.97 0.23 0.222

2-Methyl-2-butene 00513-35-9 14.20 0.47 6.740

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.15 1.742

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.33 1.600

2-Methyl-1-butene 00563-46-2 6.38 0.08 0.528

2,3-Dimethylpentane 00565-59-3 1.25 0.46 0.573

2,3,4-Trimethylpentane 00565-75-3 0.95 0.52 0.496

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.59 0.644

2,4-Dimethylhexane 00589-43-5 1.61 0.21 0.334

2-Methylhexane 00591-76-4 1.09 0.45 0.486

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.633

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.71 3.908

3-Methyl-t-2-pentene 00616-12-6 11.66 0.64 7.494

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.05 0.404

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.54 2.378

t-2-Butene 00624-64-6 15.20 0.18 2.684

c-2-Pentene 00627-20-3 10.28 0.36 3.746

t-2-Pentene 00646-04-8 10.47 0.28 2.891

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.81 1.126

2,2,5-Trimethylhexane 03522-94-9 1.05 0.49 0.514

Total 33.7 108.4 3.214

Vehicle 210b - Fuel 7 psi E0 - 86°F Static - Test 7547

Non Zero Mass Species Sorted By VOC
E-125

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 2.74 3.967

Benzene 00071-43-2 0.69 2.24 1.555

2-Methylbutane (Isopentane) 00078-78-4 1.35 8.05 10.900

2,3-Dimethylbutane 00079-29-8 0.90 1.59 1.431

ortho-Xylene 00095-47-6 7.58 0.51 3.895

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.81 9.736

3-Methylpentane 00096-14-0 1.69 1.74 2.944

Methylcyclopentane 00096-37-7 2.05 0.97 1.988

Ethylbenzene 00100-41-4 2.96 0.70 2.070

n-Propylbenzene 00103-65-1 1.96 0.36 0.704

n-Butane 00106-97-8 1.08 5.28 5.681

2,4-Dimethylpentane 00108-08-7 1.46 0.68 0.989

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.47 19.128

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.46 17.163

Methylcyclohexane 00108-87-2 1.56 0.57 0.884

Toluene 00108-88-3 3.93 10.95 42.984

n-Pentane 00109-66-0 1.21 1.36 1.650

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.34 3.983

n-Hexane 00110-54-3 1.13 2.93 3.325

Cyclohexane 00110-82-7 1.14 6.44 7.327

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.50 1.605

Cyclopentene 00142-29-0 6.69 0.72 4.827

n-Heptane 00142-82-5 0.97 0.48 0.465

2-Methyl-2-butene 00513-35-9 14.20 1.47 20.870

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.67 7.943

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.64 3.163

2-Methyl-1-butene 00563-46-2 6.38 0.51 3.240

2,3-Dimethylpentane 00565-59-3 1.25 0.51 0.634

2,3,4-Trimethylpentane 00565-75-3 0.95 1.15 1.094

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.73 0.794

2,4-Dimethylhexane 00589-43-5 1.61 0.52 0.829

c-2-Butene 00590-18-1 14.26 0.30 4.268

2,2-DiMeHexane 00590-73-8 0.94 0.83 0.783

2-Methylhexane 00591-76-4 1.09 0.55 0.592

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.45 0.721

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.54 2.886

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.81 4.503

3-Methyl-t-2-pentene 00616-12-6 11.66 0.58 6.713

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.43 25.352

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.95 4.191

t-2-Butene 00624-64-6 15.20 0.21 3.168

2-Methyl-2-pentene 00625-27-4 11.03 0.40 4.406

c-2-Pentene 00627-20-3 10.28 0.62 6.376

t-2-Pentene 00646-04-8 10.47 0.87 9.127

Vehicle 210b - Fuel 7 psi E0 - 105°F Static - Test 7549

Non Zero Mass Species Sorted By VOC
E-126

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 7 psi E0 - 105°F Static - Test 7549

Non Zero Mass Species Sorted By VOC

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.87 4.015

3-Methyl-c-2-pentene 00922-62-3 12.52 0.20 2.467

2,2,5-Trimethylhexane 03522-94-9 1.05 0.63 0.662

t-2-Hexene 04050-45-7 8.55 0.30 2.572

Total 77.6 270.6 3.486

continued
E-127

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 40.56 299.543

Ethanol 00064-17-5 1.45 21.41 31.027

Toluene 00108-88-3 3.93 19.77 77.583

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.52 77.953

n-Butane 00106-97-8 1.08 13.81 14.870

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 13.35 103.515

Cyclohexane 00110-82-7 1.14 13.23 15.048

Benzene 00071-43-2 0.69 12.44 8.636

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.50 32.943

Unknown #22 . 4.28 5.84 24.969

Methylcyclohexane 00108-87-2 1.56 4.61 7.177

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.57 19.785

2,2,5-Trimethylhexane 03522-94-9 1.05 2.96 3.113

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.52 3.017

Indan 00496-11-7 3.23 2.48 8.026

2-Methylpropane 00075-28-5 1.18 2.45 2.878

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.36 27.698

t-1,2-Dimethylcyclopentane 00822-50-4 4.28 2.21 9.475

2-Methyl-2-butene 00513-35-9 14.20 1.82 25.771

Methane 00074-82-8 0.01 1.74 0.024

2,3,4-Trimethylpentane 00565-75-3 0.95 1.39 1.323

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.36 16.196

2,3,5-Trimethylhexane 01069-53-0 1.12 1.33 1.485

2,4-Dimethylhexane 00589-43-5 1.61 1.09 1.743

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.67 4.433

t-2-Butene 00624-64-6 15.20 0.63 9.523

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.57 0.618

2-Methyl-2-pentene 00625-27-4 11.03 0.57 6.246

ortho-Xylene 00095-47-6 7.58 0.53 3.979

3-Methyl-t-2-pentene 00616-12-6 11.66 0.40 4.645

3-Methyl-c-2-pentene 00922-62-3 12.52 0.40 4.987

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.40 0.637

Total 198.4 848.9 4.278

No MIR available, use weighted average of 4.2779

Vehicle 210b - Fuel 7 psi E0 - Dynamic - Test 25776

Non Zero Mass Species Sorted By VOC
E-128

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 85.49 115.836

Toluene 00108-88-3 3.93 74.41 292.053

Cyclohexane 00110-82-7 1.14 67.10 76.315

n-Butane 00106-97-8 1.08 44.50 47.923

n-Hexane 00110-54-3 1.13 37.15 42.148

Ethanol 00064-17-5 1.45 29.71 43.055

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 27.65 38.648

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 25.39 30.442

3-Methylpentane 00096-14-0 1.69 19.28 32.594

Benzene 00071-43-2 0.69 16.17 11.230

2-Methyl-2-butene 00513-35-9 14.20 15.53 220.428

n-Pentane 00109-66-0 1.21 14.40 17.492

2,3-Dimethylbutane 00079-29-8 0.90 13.64 12.260

t-2-Pentene 00646-04-8 10.47 12.54 131.368

Methylcyclopentane 00096-37-7 2.05 12.54 25.696

2,3,4-Trimethylpentane 00565-75-3 0.95 10.55 10.007

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.43 65.411

2,4-Dimethylpentane 00108-08-7 1.46 6.88 10.036

c-2-Pentene 00627-20-3 10.28 6.84 70.290

2-Methylhexane 00591-76-4 1.09 6.27 6.806

2-Methyl-1-butene 00563-46-2 6.38 6.00 38.260

2,2-DiMeHexane 00590-73-8 0.94 5.41 5.089

2,3-Dimethylpentane 00565-59-3 1.25 5.23 6.525

2,4-Dimethylhexane 00589-43-5 1.61 5.20 8.345

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.82 15.364

t-2-Hexene 04050-45-7 8.55 4.64 39.655

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.51 7.237

2,2,5-Trimethylhexane 03522-94-9 1.05 4.41 4.639

Methane 00074-82-8 0.01 4.22 0.058

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.17 22.386

Methanol 00067-56-1 0.66 4.02 2.641

3-Methyl-t-2-pentene 00616-12-6 11.66 3.99 46.498

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.97 46.519

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.92 20.769

3-Methyl-c-2-pentene 00922-62-3 12.52 3.44 43.023

n-Heptane 00142-82-5 0.97 3.12 3.015

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.12 3.405

Cyclopentene 00142-29-0 6.69 2.84 18.970

2-Methyl-2-pentene 00625-27-4 11.03 2.76 30.451

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.62 17.299

1-Methylcyclopentene 00693-89-0 12.45 2.52 31.397

ortho-Xylene 00095-47-6 7.58 2.33 17.666

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.33 18.509

c-2-Butene 00590-18-1 14.26 2.31 33.002

Vehicle 210b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7550

Non Zero Mass Species Sorted By VOC
E-129

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 210b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7550

Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.28 10.024

Ethylbenzene 00100-41-4 2.96 2.17 6.436

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.96 10.860

Methylcyclohexane 00108-87-2 1.56 1.96 3.041

t-1,2-Dimethylcyclopentane 00822-50-4 2.90 1.75 5.072

2,2-Dimethylbutane 00075-83-2 1.11 1.74 1.938

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.60 18.834

2,3,5-Trimethylhexane 01069-53-0 1.12 1.45 1.627

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.42 8.188

c-1,3-Dimethylcyclopentane 02532-58-3 2.90 1.37 3.969

n-Propylbenzene 00103-65-1 1.96 1.27 2.482

3-Methylheptane 00589-81-1 1.12 1.25 1.410

Unknown #16 2.90 1.22 3.535

2,2-Dimethylpentane 00590-35-2 1.04 1.18 1.235

2,2,3-Trimethylbutane 00464-06-2 1.05 1.16 1.225

2-Methylheptane 00592-27-8 0.97 1.13 1.097

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.01 7.124

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.96 7.520

3,3-Dimethylpentane 00562-49-2 1.12 0.92 1.025

n-Octane 00111-65-9 0.80 0.87 0.694

Unknown #1 2.90 0.86 2.492

Ethylene 00074-85-1 8.88 0.84 7.462

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.68 8.106

Indan 00496-11-7 3.23 0.64 2.084

c-1,3-Dimethylcyclohexane 00638-04-0 2.90 0.64 1.847

Unknown #5 2.90 0.55 1.583

4-Methyl-t-2-pentene 00674-76-0 8.04 0.50 4.050

3,3-Dimethylhexane 00563-16-6 1.15 0.50 0.577

t-3-Heptene 14686-14-7 6.17 0.49 3.040

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.47 1.811

Isopropylbenzene (Cumene) 00098-82-8 2.90 0.47 1.354

c-2-Heptene 06443-92-1 7.08 0.45 3.160

1-Nonene 00124-11-8 2.49 0.41 1.019

1,3-Diethylbenzene 00141-93-5 7.08 0.34 2.375

Unknown #8 2.90 0.33 0.962

t-2-Nonene 06434-78-2 2.90 0.32 0.916

3,5-Dimethylheptane 00926-82-9 1.42 0.31 0.441

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.29 3.029

4-Methyloctane 02216-34-4 0.85 0.26 0.221

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.24 1.978

n-Nonane 00111-84-2 0.68 0.22 0.151

Unknown #10 2.90 0.21 0.605

Total 665.0 1927.4 2.898

No MIR available, use weighted average of 2.8982
E-130

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7442 74.9 84.5 63.3 229.3 3.620 59

Static E10 - 7 psi 7464 60.4 77.3 46.7 118.1 2.531 12

E0 - 9 psi 7506 34.8 88.3 30.7 102.3 3.329 41

E0 - 7 psi 7526 40.9 86.2 35.3 104.0 2.947 38

105° F E10 - 10 psi 7446 228.3 105.1 239.8 761.0 3.174 78

Static E10 - 7 psi 7465 159.2 87.2 138.9 440.2 3.169 64

E0 - 9 psi 7507 71.1 82.7 58.8 173.0 2.943 32

E0 - 7 psi 7528 66.8 106.3 71.0 251.7 3.546 50

Dynamic E10 - 10 psi 25750 144.8 124.2 179.8 839.7 4.669 48

E10 - 7 psi 25754 284.5 88.3 251.3 879.7 3.500 60

E0 - 9 psi 25764 191.7 52.9 101.4 314.8 3.105 38

E0 - 7 psi 25769 141.4 69.4 98.1 381.1 3.885 59

DHB E10 - 10 psi 7429 1966.7 101.3 1992.2 5290.8 2.656 92

Total E10 - 7 psi 7473 1769.4 67.1 1187.5 4082.1 3.438 80

E0 - 9 psi 7516 967.5 88.7 858.6 2298.5 2.677 73

E0 - 7 psi 7538 917.6 94.2 864.0 2571.4 2.976 80

Vehicle 213b
E-131

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 16.97 24.593

Toluene 00108-88-3 3.93 10.78 42.296

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.07 37.471

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.07 11.117

n-Butane 00106-97-8 1.08 2.01 2.169

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.96 15.195

Benzene 00071-43-2 0.69 1.62 1.123

Propane 00074-98-6 0.46 1.53 0.699

1,4-Diethylbenzene 00105-05-5 4.39 1.34 5.889

n-Hexane 00110-54-3 1.13 1.12 1.275

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.10 4.841

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.03 12.098

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.94 1.127

2,3,4-Trimethylpentane 00565-75-3 0.95 0.89 0.845

n-Heptane 00142-82-5 0.97 0.80 0.774

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.67 3.724

Methylcyclohexane 00108-87-2 1.56 0.67 1.043

t-2-Pentene 00646-04-8 10.47 0.65 6.813

2-Methyl-2-butene 00513-35-9 14.20 0.63 8.921

n-Decane 00124-18-5 0.59 0.58 0.343

n-Octane 00111-65-9 0.80 0.55 0.441

ortho-Xylene 00095-47-6 7.58 0.50 3.813

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.48 3.185

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.45 1.448

2-Methylpropane 00075-28-5 1.18 0.45 0.528

n-Nonane 00111-84-2 0.68 0.45 0.305

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.41 3.059

2-Methylhexane 00591-76-4 1.09 0.40 0.433

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.39 4.626

2,2,5-Trimethylhexane 03522-94-9 1.05 0.39 0.406

Ethylbenzene 00100-41-4 2.96 0.39 1.141

2,2-DiMeHexane 00590-73-8 0.94 0.37 0.351

n-Propylbenzene 00103-65-1 1.96 0.37 0.717

t-2-Hexene 04050-45-7 8.55 0.35 2.976

Cyclohexane 00110-82-7 1.14 0.34 0.390

c-2-Pentene 00627-20-3 10.28 0.33 3.401

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.33 0.361

Methylcyclopentane 00096-37-7 2.05 0.33 0.670

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.32 0.513

c-1,3-Dimethylcyclohexane 00638-04-0 3.62 0.32 1.155

3-Methyl-t-2-pentene 00616-12-6 11.66 0.29 3.373

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.29 2.026

3-Methylheptane 00589-81-1 1.12 0.29 0.321

2,4-Dimethylhexane 00589-43-5 1.61 0.28 0.445

Vehicle 213b - Fuel 10 psi E10 - 86°F Static - Test 7442

Non Zero Mass Species Sorted By VOC
E-132

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 10 psi E10 - 86°F Static - Test 7442

Non Zero Mass Species Sorted By VOC

2-Methyl-2-pentene 00625-27-4 11.03 0.24 2.600

2,3-Dimethylpentane 00565-59-3 1.25 0.22 0.280

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.20 2.364

t-1,2-Dimethylcyclopentane 00822-50-4 3.62 0.17 0.626

2,3-Dimethylbutane 00079-29-8 0.90 0.16 0.143

2,4-Dimethylpentane 00108-08-7 1.46 0.14 0.199

2-Methylheptane 00592-27-8 0.97 0.13 0.130

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.13 1.037

3-Methyl-c-2-pentene 00922-62-3 12.52 0.12 1.542

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.12 0.161

c-2-Butene 00590-18-1 14.26 0.09 1.335

3-Methylpentane 00096-14-0 1.69 0.07 0.121

Cyclopentene 00142-29-0 6.69 0.04 0.251

c-1,3-Dimethylcyclopentane 02532-58-3 3.62 0.01 0.039

2-Methyl-1-butene 00563-46-2 6.38 0.01 0.035

Total 63.3 229.3 3.620

No MIR available, use weighted average of 3.6201

continued
E-133

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 66.40 96.207

Toluene 00108-88-3 3.93 29.59 116.147

n-Butane 00106-97-8 1.08 19.17 20.643

2-Methylbutane (Isopentane) 00078-78-4 1.35 12.34 16.714

n-Hexane 00110-54-3 1.13 8.64 9.804

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 6.69 49.398

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.07 32.577

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.13 7.176

Benzene 00071-43-2 0.69 4.59 3.185

3-Methylpentane 00096-14-0 1.69 4.55 7.695

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.49 34.840

2-Methyl-2-butene 00513-35-9 14.20 3.78 53.673

n-Pentane 00109-66-0 1.21 3.39 4.119

t-2-Pentene 00646-04-8 10.47 3.37 35.301

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.15 3.774

Methylcyclopentane 00096-37-7 2.05 2.47 5.066

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.28 10.010

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.22 26.092

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.06 24.077

2,3-Dimethylbutane 00079-29-8 0.90 2.03 1.821

Cyclohexane 00110-82-7 1.14 2.02 2.298

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.93 10.678

Methylcyclohexane 00108-87-2 1.56 1.80 2.805

c-2-Pentene 00627-20-3 10.28 1.74 17.930

2-Methylpropane 00075-28-5 1.18 1.74 2.042

2,3,4-Trimethylpentane 00565-75-3 0.95 1.61 1.531

n-Heptane 00142-82-5 0.97 1.58 1.523

n-Decane 00124-18-5 0.59 1.50 0.888

t-2-Butene 00624-64-6 15.20 1.50 22.758

2-Methyl-1-butene 00563-46-2 6.38 1.48 9.423

2,2-DiMeHexane 00590-73-8 0.94 1.42 1.335

2-Methylhexane 00591-76-4 1.09 1.42 1.538

ortho-Xylene 00095-47-6 7.58 1.40 10.583

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.28 6.781

n-Octane 00111-65-9 0.80 1.22 0.970

n-Propylbenzene 00103-65-1 1.96 1.17 2.295

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.11 3.544

n-Nonane 00111-84-2 0.68 1.01 0.693

t-2-Hexene 04050-45-7 8.55 0.98 8.417

c-1,3-Dimethylcyclohexane 00638-04-0 3.17 0.98 3.107

1-Methylcyclopentene 00693-89-0 12.45 0.95 11.784

2,4-Dimethylpentane 00108-08-7 1.46 0.91 1.328

2,4-Dimethylhexane 00589-43-5 1.61 0.89 1.432

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.88 1.407

Vehicle 213b - Fuel 10 psi E10 - 105°F Static - Test 7446

Non Zero Mass Species Sorted By VOC
E-134

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 10 psi E10 - 105°F Static - Test 7446

Non Zero Mass Species Sorted By VOC

2,3-Dimethylpentane 00565-59-3 1.25 0.87 1.083

3-Methylheptane 00589-81-1 1.12 0.87 0.974

3-Methyl-c-2-pentene 00922-62-3 12.52 0.78 9.794

3-Methyl-t-2-pentene 00616-12-6 11.66 0.72 8.398

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.69 0.757

2,2,5-Trimethylhexane 03522-94-9 1.05 0.67 0.706

Ethylbenzene 00100-41-4 2.96 0.67 1.978

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.64 7.621

Unknown #16 3.17 0.61 1.933

2-Methyl-2-pentene 00625-27-4 11.03 0.57 6.288

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.55 4.361

Cyclopentene 00142-29-0 6.69 0.55 3.672

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.53 3.051

3,5-Dimethylheptane 00926-82-9 1.42 0.49 0.700

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.47 3.081

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.47 3.294

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.46 3.484

2-Methylheptane 00592-27-8 0.97 0.43 0.419

3,3-Dimethylpentane 00562-49-2 1.12 0.40 0.450

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.40 1.527

2,3,5-Trimethylhexane 01069-53-0 1.12 0.39 0.436

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.37 2.938

t-1,4-Dimethylcyclohexane 02207-04-7 3.17 0.37 1.165

c-2-Butene 00590-18-1 14.26 0.30 4.256

Indan 00496-11-7 3.23 0.25 0.801

t-1,2-Dimethylcyclopentane 00822-50-4 3.17 0.24 0.772

Propane 00074-98-6 0.46 0.21 0.097

2,2-Dimethylpentane 00590-35-2 1.04 0.19 0.199

n-Undecane 01120-21-4 0.52 0.17 0.087

3-Methyloctane 02216-33-3 0.88 0.15 0.133

2,2-Dimethylbutane 00075-83-2 1.11 0.13 0.140

c-1,3-Dimethylcyclopentane 02532-58-3 3.17 0.11 0.362

1,4-Diethylbenzene 00105-05-5 4.39 0.11 0.500

Unknown #22 . 3.17 0.05 0.151

Total 239.8 761.0 3.174

No MIR available, use weighted average of 3.1738

continued
E-135

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 48.10 355.240

Ethanol 00064-17-5 1.45 20.65 29.922

Toluene 00108-88-3 3.93 17.09 67.082

n-Butane 00106-97-8 1.08 12.30 13.248

Benzene 00071-43-2 0.69 7.28 5.056

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.21 33.338

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.64 7.641

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.32 7.443

n-Hexane 00110-54-3 1.13 4.88 5.535

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.05 47.553

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.92 30.394

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.87 22.769

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.40 28.641

2-Methyl-2-butene 00513-35-9 14.20 2.27 32.226

2,3-Dimethylbutane 00079-29-8 0.90 2.13 1.914

Cyclopentene 00142-29-0 6.69 2.10 14.050

ortho-Xylene 00095-47-6 7.58 2.10 15.872

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.00 8.784

n-Pentane 00109-66-0 1.21 1.96 2.382

2,2-DiMeHexane 00590-73-8 0.94 1.95 1.832

t-2-Pentene 00646-04-8 10.47 1.71 17.945

Cyclohexane 00110-82-7 1.14 1.69 1.917

Methylcyclopentane 00096-37-7 2.05 1.64 3.370

3-Methylpentane 00096-14-0 1.69 1.53 2.593

Methylcyclohexane 00108-87-2 1.56 1.38 2.152

n-Heptane 00142-82-5 0.97 1.29 1.243

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.24 1.485

2,4-Dimethylhexane 00589-43-5 1.61 1.18 1.895

c-2-Butene 00590-18-1 14.26 1.18 16.785

3-Methyl-t-2-pentene 00616-12-6 11.66 1.12 13.102

2-Methyl-2-pentene 00625-27-4 11.03 1.08 11.938

n-Octane 00111-65-9 0.80 1.07 0.849

2,3-Dimethylpentane 00565-59-3 1.25 1.06 1.326

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.93 2.982

2-Methylhexane 00591-76-4 1.09 0.85 0.922

t-2-Hexene 04050-45-7 8.55 0.77 6.582

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.70 8.219

2,3,4-Trimethylpentane 00565-75-3 0.95 0.63 0.598

Ethylbenzene 00100-41-4 2.96 0.60 1.785

2-Methylpropane 00075-28-5 1.18 0.58 0.683

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.50 0.798

2-Methyl-1-butene 00563-46-2 6.38 0.47 3.005

c-2-Pentene 00627-20-3 10.28 0.41 4.184

2,2-Dimethylbutane 00075-83-2 1.11 0.26 0.292

Vehicle 213b - Fuel 10 psi E10 - Dynamic - Test 25750

Non Zero Mass Species Sorted By VOC
E-136

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 10 psi E10 - Dynamic - Test 25750

Non Zero Mass Species Sorted By VOC

2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.372

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.21 1.173

Indan 00496-11-7 3.23 0.14 0.449

2,2,5-Trimethylhexane 03522-94-9 1.05 0.13 0.137

Total 179.8 839.7 4.669

continued
E-137

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 545.98 791.116

n-Butane 00106-97-8 1.08 196.96 212.113

2-Methylbutane (Isopentane) 00078-78-4 1.35 188.38 255.236

Toluene 00108-88-3 3.93 152.43 598.276

n-Hexane 00110-54-3 1.13 112.72 127.905

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 66.10 92.391

3-Methylpentane 00096-14-0 1.69 47.30 79.974

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 44.91 53.858

2-Methyl-2-butene 00513-35-9 14.20 42.05 596.841

n-Pentane 00109-66-0 1.21 41.19 50.042

Benzene 00071-43-2 0.69 36.90 25.618

t-2-Pentene 00646-04-8 10.47 35.47 371.500

Methylcyclopentane 00096-37-7 2.05 31.20 63.956

Cyclohexane 00110-82-7 1.14 30.10 34.240

2,3-Dimethylbutane 00079-29-8 0.90 28.27 25.405

c-2-Pentene 00627-20-3 10.28 18.47 189.858

Methylcyclohexane 00108-87-2 1.56 18.04 28.062

n-Propylbenzene 00103-65-1 1.96 17.85 34.974

n-Heptane 00142-82-5 0.97 17.59 16.983

2-Methylhexane 00591-76-4 1.09 17.47 18.958

2-Methyl-1-butene 00563-46-2 6.38 16.67 106.309

2,3,4-Trimethylpentane 00565-75-3 0.95 16.34 15.504

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 15.37 49.056

2,4-Dimethylpentane 00108-08-7 1.46 14.06 20.524

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 13.60 105.486

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.73 137.329

t-2-Hexene 04050-45-7 8.55 10.99 93.957

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 10.21 54.106

2,3-Dimethylpentane 00565-59-3 1.25 9.55 11.924

3-Methyl-t-2-pentene 00616-12-6 11.66 9.02 105.173

2,4-Dimethylhexane 00589-43-5 1.61 8.19 13.147

2,2-DiMeHexane 00590-73-8 0.94 8.05 7.572

3-Methyl-c-2-pentene 00922-62-3 12.52 7.86 98.410

2-Methyl-2-pentene 00625-27-4 11.03 7.65 84.351

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.60 40.822

c-2-Butene 00590-18-1 14.26 7.39 105.363

1-Methylcyclopentene 00693-89-0 12.45 7.27 90.514

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.25 53.551

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.85 45.279

Cyclopentene 00142-29-0 6.69 6.54 43.759

n-Octane 00111-65-9 0.80 6.43 5.122

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.75 45.673

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 5.63 9.044

2,2,5-Trimethylhexane 03522-94-9 1.05 5.33 5.615

Vehicle 213b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7429

Non Zero Mass Species Sorted By VOC
E-138

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7429

Non Zero Mass Species Sorted By VOC

2,2-Dimethylbutane 00075-83-2 1.11 5.25 5.837

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.25 4.640

ortho-Xylene 00095-47-6 7.58 3.89 29.499

2-Methylheptane 00592-27-8 0.97 3.84 3.714

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.83 16.839

t-1,2-Dimethylcyclopentane 00822-50-4 2.66 3.59 9.539

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.58 20.708

3-Methylheptane 00589-81-1 1.12 3.34 3.754

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.19 37.483

c-1,3-Dimethylcyclopentane 02532-58-3 2.66 3.09 8.205

Ethylbenzene 00100-41-4 2.96 2.93 8.676

2,2-Dimethylpentane 00590-35-2 1.04 2.89 3.011

c-1,3-Dimethylcyclohexane 00638-04-0 2.66 2.51 6.676

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.29 12.712

3,3-Dimethylpentane 00562-49-2 1.12 1.89 2.111

2,2,3-Trimethylbutane 00464-06-2 1.05 1.70 1.788

2,3,5-Trimethylhexane 01069-53-0 1.12 1.70 1.900

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.66 13.038

3,5-Dimethylheptane 00926-82-9 1.42 1.46 2.083

n-Nonane 00111-84-2 0.68 1.42 0.972

n-Decane 00124-18-5 0.59 1.37 0.810

t-1,4-Dimethylcyclohexane 02207-04-7 2.66 1.16 3.070

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.08 4.182

Unknown #16 2.66 0.96 2.559

4-Methyloctane 02216-34-4 0.85 0.96 0.816

1,3-Butadiene 00106-99-0 12.45 0.93 11.634

n-Undecane 01120-21-4 0.52 0.90 0.468

Unknown #8 2.66 0.88 2.338

Unknown #5 2.66 0.87 2.321

3,3-Dimethylhexane 00563-16-6 1.15 0.86 0.987

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.84 9.981

c-2-Heptene 06443-92-1 7.08 0.73 5.167

Indan 00496-11-7 3.23 0.70 2.274

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.67 6.998

t-3-Heptene 14686-14-7 6.17 0.64 3.949

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.62 4.046

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.62 4.372

2,4-Dimethylheptane 02213-23-2 1.26 0.58 0.739

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.50 4.182

3-Methyloctane 02216-33-3 0.88 0.46 0.411

4-Methyl-t-2-pentene 00674-76-0 8.04 0.45 3.583

1-Heptene 00592-76-7 4.29 0.42 1.784

continued
E-139

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7429

Non Zero Mass Species Sorted By VOC

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.66 0.40 1.053

Unknown #22 . 2.66 0.39 1.028

1-Nonene 00124-11-8 2.49 0.36 0.903

Isopropylbenzene (Cumene) 00098-82-8 2.66 0.33 0.868

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.32 2.004

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.19 0.214

Total 1992.2 5290.8 2.656

No MIR available, use weighted average of 2.6557

continued
E-140

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 10.30 14.920

Toluene 00108-88-3 3.93 8.66 33.974

2-Methylbutane (Isopentane) 00078-78-4 1.35 6.25 8.467

n-Hexane 00110-54-3 1.13 5.36 6.082

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.01 4.211

n-Butane 00106-97-8 1.08 2.98 3.204

n-Pentane 00109-66-0 1.21 2.45 2.977

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.29 2.743

3-Methylpentane 00096-14-0 1.69 1.95 3.291

2-Methyl-2-butene 00513-35-9 14.20 1.79 25.347

t-2-Pentene 00646-04-8 10.47 1.20 12.564

Benzene 00071-43-2 0.69 0.44 0.309

Total 46.7 118.1 2.531

Vehicle 213b - Fuel 7 psi E10 - 86°F Static - Test 7464

Non Zero Mass Species Sorted By VOC
E-141

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 44.26 64.134

Toluene 00108-88-3 3.93 18.17 71.299

n-Hexane 00110-54-3 1.13 6.19 7.025

2-Methylbutane (Isopentane) 00078-78-4 1.35 4.46 6.047

n-Propylbenzene 00103-65-1 1.96 4.44 8.705

Benzene 00071-43-2 0.69 3.67 2.548

Ethylene 00074-85-1 8.88 3.37 29.926

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.07 4.294

2-Methyl-2-butene 00513-35-9 14.20 2.71 38.429

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.62 3.148

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.56 19.822

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.46 13.214

n-Butane 00106-97-8 1.08 2.26 2.439

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.26 16.716

3-Methylpentane 00096-14-0 1.69 2.18 3.679

t-2-Pentene 00646-04-8 10.47 2.03 21.252

n-Pentane 00109-66-0 1.21 1.70 2.066

Cyclohexane 00110-82-7 1.14 1.57 1.786

n-Heptane 00142-82-5 0.97 1.53 1.473

Methylcyclohexane 00108-87-2 1.56 1.41 2.200

2,3-Dimethylbutane 00079-29-8 0.90 1.36 1.226

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.12 4.934

2,3,4-Trimethylpentane 00565-75-3 0.95 1.11 1.057

Cyclopentene 00142-29-0 6.69 0.97 6.504

2,4-Dimethylhexane 00589-43-5 1.61 0.95 1.530

Methylcyclopentane 00096-37-7 2.05 0.92 1.889

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.90 10.600

c-2-Pentene 00627-20-3 10.28 0.90 9.260

2-Methyl-1-butene 00563-46-2 6.38 0.88 5.610

2,2-DiMeHexane 00590-73-8 0.94 0.83 0.786

2-Methylhexane 00591-76-4 1.09 0.83 0.901

Indan 00496-11-7 3.23 0.81 2.610

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.77 4.256

ortho-Xylene 00095-47-6 7.58 0.74 5.628

3-Methylheptane 00589-81-1 1.12 0.73 0.823

t-2-Hexene 04050-45-7 8.55 0.70 5.985

2,3,5-Trimethylhexane 01069-53-0 1.12 0.69 0.776

n-Nonane 00111-84-2 0.68 0.68 0.463

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.65 7.710

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.62 1.003

c-2-Butene 00590-18-1 14.26 0.58 8.304

2,4-Dimethylpentane 00108-08-7 1.46 0.55 0.805

n-Octane 00111-65-9 0.80 0.53 0.424

t-1,2-Dimethylcyclopentane 00822-50-4 3.17 0.52 1.643

Vehicle 213b - Fuel 7 psi E10 - 105°F Static - Test 7465

Non Zero Mass Species Sorted By VOC
E-142

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 7 psi E10 - 105°F Static - Test 7465

Non Zero Mass Species Sorted By VOC

2,3-Dimethylpentane 00565-59-3 1.25 0.51 0.643

3-Methyl-t-2-pentene 00616-12-6 11.66 0.49 5.702

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.47 5.501

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.44 3.509

2-Methylheptane 00592-27-8 0.97 0.43 0.416

c-1,3-Dimethylcyclopentane 02532-58-3 3.17 0.42 1.338

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.41 2.182

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.37 2.651

c-1,3-Dimethylcyclohexane 00638-04-0 3.17 0.36 1.156

2,2-Dimethylpentane 00590-35-2 1.04 0.36 0.378

3-Methyl-c-2-pentene 00922-62-3 12.52 0.30 3.802

2,2,5-Trimethylhexane 03522-94-9 1.05 0.30 0.317

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.30 1.143

2-Methyl-2-pentene 00625-27-4 11.03 0.29 3.180

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.27 0.294

Ethylbenzene 00100-41-4 2.96 0.26 0.777

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.22 1.462

n-Decane 00124-18-5 2.49 0.19 0.479

2,2-Dimethylbutane 00075-83-2 1.11 0.14 0.151

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.07 0.218

Total 138.9 440.2 3.169

No MIR available, use weighted average of 3.1690

continued
E-143

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 47.19 68.379

n-Propylbenzene 00103-65-1 1.96 22.51 44.110

Toluene 00108-88-3 3.93 18.46 72.447

2-Methylbutane (Isopentane) 00078-78-4 1.35 15.85 21.474

n-Butane 00106-97-8 1.08 14.36 15.469

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 8.24 44.223

n-Hexane 00110-54-3 1.13 7.72 8.755

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.57 76.868

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.85 43.177

n-Pentane 00109-66-0 1.21 5.52 6.706

Methylcyclopentane 00096-37-7 2.05 5.03 10.302

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.28 5.127

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.91 45.905

Benzene 00071-43-2 0.69 3.90 2.708

3-Methylpentane 00096-14-0 1.69 3.60 6.089

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.51 27.847

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.45 4.824

t-2-Butene 00624-64-6 15.20 3.40 51.712

2-Methyl-2-butene 00513-35-9 14.20 3.36 47.725

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.17 13.935

Methylcyclohexane 00108-87-2 1.56 3.01 4.681

t-2-Pentene 00646-04-8 10.47 2.95 30.924

2,3-Dimethylbutane 00079-29-8 0.90 2.83 2.543

2,3,4-Trimethylpentane 00565-75-3 0.95 2.76 2.617

Cyclohexane 00110-82-7 1.14 2.51 2.858

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.41 18.705

2-Methylheptane 00592-27-8 0.97 2.36 2.286

c-2-Pentene 00627-20-3 10.28 2.31 23.709

Ethylbenzene 00100-41-4 2.96 2.13 6.319

2,2-DiMeHexane 00590-73-8 0.94 2.10 1.981

n-Octane 00111-65-9 0.80 2.08 1.656

n-Nonane 00111-84-2 0.68 1.99 1.361

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.97 6.275

n-Heptane 00142-82-5 0.97 1.94 1.877

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.92 10.624

2-Methyl-1-butene 00563-46-2 6.38 1.88 11.960

2,4-Dimethylpentane 00108-08-7 1.46 1.47 2.152

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.47 9.684

n-Decane 00124-18-5 0.59 1.44 0.849

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.42 1.554

3-Methyl-c-2-pentene 00922-62-3 12.52 1.40 17.563

3-Methylheptane 00589-81-1 1.12 1.31 1.477

ortho-Xylene 00095-47-6 7.58 1.29 9.761

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.28 9.098

Vehicle 213b - Fuel 7 psi E10 - Dynamic - Test 25754

Non Zero Mass Species Sorted By VOC
E-144

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 7 psi E10 - Dynamic - Test 25754

Non Zero Mass Species Sorted By VOC

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.28 15.258

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.21 12.730

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.21 1.940

2,3,5-Trimethylhexane 01069-53-0 1.12 1.16 1.297

2,2,5-Trimethylhexane 03522-94-9 1.05 1.14 1.196

2-Methylhexane 00591-76-4 1.09 1.13 1.229

2,4-Dimethylhexane 00589-43-5 1.61 1.13 1.807

c-2-Butene 00590-18-1 14.26 1.10 15.662

3-Methyl-t-2-pentene 00616-12-6 11.66 0.69 8.057

Cyclopentene 00142-29-0 6.69 0.67 4.479

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.65 3.440

2-Methyl-2-pentene 00625-27-4 11.03 0.63 6.931

t-2-Hexene 04050-45-7 8.55 0.46 3.938

2,3-Dimethylpentane 00565-59-3 1.25 0.38 0.480

Indan 00496-11-7 3.23 0.26 0.828

2,2-Dimethylbutane 00075-83-2 1.11 0.15 0.172

Total 251.3 879.7 3.500

continued
E-145

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 395.89 573.641

Toluene 00108-88-3 3.93 94.26 369.982

2-Methylbutane (Isopentane) 00078-78-4 1.35 88.04 119.281

n-Hexane 00110-54-3 1.13 70.01 79.440

1,3-Butadiene 00106-99-0 12.45 45.50 566.676

Unknown #2 3.44 41.56 142.858

2-Methyl-1-butene 00563-46-2 6.38 37.14 236.925

1-Methylcyclopentene 00693-89-0 12.45 31.23 388.904

3-Methylpentane 00096-14-0 1.69 28.27 47.799

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 26.08 31.278

2-Methyl-2-butene 00513-35-9 14.20 23.92 339.483

2-Methyl-1,3-butadiene 00078-79-5 10.48 21.51 225.440

Methylcyclopentane 00096-37-7 2.05 19.90 40.784

Cyclohexane 00110-82-7 1.14 18.54 21.082

Cyclopentane 00287-92-3 2.24 18.49 41.375

2,2-Dimethylpropane 00463-82-1 0.65 12.80 8.272

Methylcyclohexane 00108-87-2 1.56 11.70 18.206

3,3-Dimethyl-1-butene 00558-37-2 5.68 11.27 64.059

2-Methylhexane 00591-76-4 1.09 10.68 11.584

2,3,4-Trimethylpentane 00565-75-3 0.95 10.31 9.780

n-Heptane 00142-82-5 0.97 9.67 9.337

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 9.46 30.194

2,4-Dimethylpentane 00108-08-7 1.46 8.44 12.310

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.58 88.759

t-2-Hexene 04050-45-7 8.55 6.94 59.321

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.90 53.491

2,3-Dimethylpentane 00565-59-3 1.25 5.74 7.167

2,2-DiMeHexane 00590-73-8 0.94 5.53 5.204

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.29 28.010

2-Methylpropane 00075-28-5 1.18 5.24 6.168

2,4-Dimethylhexane 00589-43-5 1.61 5.17 8.301

1-Butyne 00107-00-6 6.05 5.05 30.569

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.89 21.466

3-Methyl-c-2-pentene 00922-62-3 12.52 4.86 60.816

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.69 37.221

n-Octane 00111-65-9 0.80 4.64 3.692

Cyclopentene 00142-29-0 6.69 4.16 27.845

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.15 27.435

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 3.98 6.384

2-Methyl-2-pentene 00625-27-4 11.03 3.96 43.704

2,2,5-Trimethylhexane 03522-94-9 1.05 3.43 3.610

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.37 18.074

Propane 00074-98-6 0.46 3.19 1.459

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.74 2.989

Vehicle 213b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7473

Non Zero Mass Species Sorted By VOC
E-146

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7473

Non Zero Mass Species Sorted By VOC

2,3,5-Trimethylhexane 01069-53-0 1.12 2.52 2.817

t-1,2-Dimethylcyclopentane 00822-50-4 3.44 2.33 8.004

2-Methylheptane 00592-27-8 0.97 2.21 2.137

3-Methylheptane 00589-81-1 1.12 2.01 2.263

2,2-Dimethylpentane 00590-35-2 1.04 1.88 1.962

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.81 21.240

c-1,3-Dimethylcyclopentane 02532-58-3 3.44 1.79 6.154

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.73 10.022

ortho-Xylene 00095-47-6 7.58 1.69 12.769

c-1,3-Dimethylcyclohexane 00638-04-0 3.44 1.68 5.775

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.47 8.143

Cyclopentadiene 00542-92-7 6.89 1.44 9.933

3,3-Dimethylpentane 00562-49-2 1.12 1.42 1.583

3,5-Dimethylheptane 00926-82-9 1.42 1.38 1.964

2,2,3-Trimethylbutane 00464-06-2 1.05 1.26 1.333

Ethylbenzene 00100-41-4 2.96 1.18 3.492

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.18 9.231

n-Decane 00124-18-5 0.59 1.13 0.666

Unknown #17 3.44 0.97 3.328

t-2-Nonene 06434-78-2 3.44 0.92 3.150

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.85 3.737

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.84 3.260

4-Methyloctane 02216-34-4 0.85 0.78 0.662

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.77 5.697

t-1,4-Dimethylcyclohexane 02207-04-7 3.44 0.68 2.348

3,3-Dimethylhexane 00563-16-6 1.15 0.64 0.733

Unknown #5 3.44 0.63 2.172

c-2-Heptene 06443-92-1 7.08 0.60 4.229

1,4-Diethylbenzene 00105-05-5 4.39 0.59 2.596

Isobutylbenzene 00538-93-2 3.44 0.57 1.966

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.44 0.54 1.846

Unknown #8 3.44 0.50 1.733

2,4-Dimethylheptane 02213-23-2 1.26 0.47 0.601

1-Nonene 00124-11-8 2.49 0.40 1.001

t-3-Heptene 14686-14-7 6.17 0.28 1.727

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.22 1.415

Total 1187.5 4082.1 3.438

No MIR available, use weighted average of 3.4375

continued
E-147

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 4.25 16.673

2-Methylbutane (Isopentane) 00078-78-4 1.35 3.29 4.456

n-Butane 00106-97-8 1.08 3.08 3.312

Cyclohexane 00110-82-7 1.14 2.13 2.418

Ethanol 00064-17-5 1.45 1.68 2.437

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.18 5.167

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.09 1.528

n-Hexane 00110-54-3 1.13 0.97 1.097

2,3-Dimethylbutane 00079-29-8 0.90 0.88 0.794

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.86 1.035

2-Methyl-2-butene 00513-35-9 14.20 0.79 11.210

2,4-Dimethylhexane 00589-43-5 1.61 0.68 1.095

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.59 3.258

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.56 3.025

3-Methylpentane 00096-14-0 1.69 0.52 0.878

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.51 5.963

Benzene 00071-43-2 0.69 0.50 0.345

c-2-Pentene 00627-20-3 10.28 0.49 5.089

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.48 3.687

2,2,5-Trimethylhexane 03522-94-9 1.05 0.44 0.465

n-Propylbenzene 00103-65-1 1.96 0.44 0.858

2,3,4-Trimethylpentane 00565-75-3 0.95 0.44 0.415

n-Pentane 00109-66-0 1.21 0.42 0.507

Methylcyclopentane 00096-37-7 2.05 0.42 0.852

2,3,5-Trimethylhexane 01069-53-0 1.12 0.39 0.432

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.38 2.805

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.33 0.355

c-2-Butene 00590-18-1 14.26 0.31 4.361

t-2-Hexene 04050-45-7 8.55 0.30 2.583

t-2-Pentene 00646-04-8 10.47 0.29 3.087

Methylcyclohexane 00108-87-2 1.56 0.26 0.402

2-Methyl-1-butene 00563-46-2 6.38 0.24 1.525

3-Methyl-t-2-pentene 00616-12-6 11.66 0.24 2.768

ortho-Xylene 00095-47-6 7.58 0.24 1.781

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.23 0.721

Cyclopentene 00142-29-0 6.69 0.22 1.481

2,3-Dimethylpentane 00565-59-3 1.25 0.19 0.241

t-2-Butene 00624-64-6 15.20 0.18 2.704

2-Methylhexane 00591-76-4 1.09 0.14 0.149

Ethylbenzene 00100-41-4 2.96 0.10 0.283

2,4-Dimethylpentane 00108-08-7 1.46 0.04 0.064

Total 30.7 102.3 3.329

Vehicle 213b - Fuel 9 psi E0 - 86°F Static - Test 7506

Non Zero Mass Species Sorted By VOC
E-148

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 9.69 38.049

n-Propylbenzene 00103-65-1 1.96 7.64 14.968

n-Butane 00106-97-8 1.08 5.48 5.902

2-Methylbutane (Isopentane) 00078-78-4 1.35 5.03 6.817

Cyclohexane 00110-82-7 1.14 4.65 5.285

3-Methylnonane 05911-04-6 0.66 3.79 2.486

n-Hexane 00110-54-3 1.13 2.83 3.214

2,2-DiMeHexane 00590-73-8 0.94 1.76 1.654

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.55 2.169

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.51 1.813

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.39 10.230

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.31 10.155

2-Methyl-2-butene 00513-35-9 14.20 1.29 18.309

Benzene 00071-43-2 0.69 1.26 0.873

3-Methylpentane 00096-14-0 1.69 1.25 2.112

t-2-Pentene 00646-04-8 10.47 1.10 11.491

n-Pentane 00109-66-0 1.21 1.09 1.324

2,3,4-Trimethylpentane 00565-75-3 0.95 0.99 0.937

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.94 11.016

Methylcyclopentane 00096-37-7 2.05 0.69 1.405

c-2-Pentene 00627-20-3 10.28 0.63 6.438

n-Heptane 00142-82-5 0.97 0.44 0.426

2-Methylhexane 00591-76-4 1.09 0.43 0.472

ortho-Xylene 00095-47-6 7.58 0.37 2.828

t-2-Hexene 04050-45-7 8.55 0.36 3.107

2-Methyl-1-butene 00563-46-2 6.38 0.34 2.185

3-Methyl-t-2-pentene 00616-12-6 11.66 0.26 3.088

2,4-Dimethylpentane 00108-08-7 1.46 0.23 0.340

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.18 2.114

2,3-Dimethylpentane 00565-59-3 1.25 0.14 0.172

c-2-Butene 00590-18-1 14.26 0.10 1.450

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.04 0.135

Total 58.8 173.0 2.943

Vehicle 213b - Fuel 9 psi E0 - 105°F Static - Test 7507

Non Zero Mass Species Sorted By VOC
E-149

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Cyclohexane 00110-82-7 1.14 10.76 12.234

Toluene 00108-88-3 3.93 9.38 36.829

n-Hexane 00110-54-3 1.13 5.02 5.696

2-Methylbutane (Isopentane) 00078-78-4 1.35 4.78 6.470

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.64 5.565

2,2,5-Trimethylhexane 03522-94-9 1.05 3.99 4.205

Methane 00074-82-8 0.01 3.99 0.055

2,3,5-Trimethylhexane 01069-53-0 1.12 3.95 4.424

Benzene 00071-43-2 0.69 3.77 2.620

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.75 27.705

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.58 27.777

t-2-Pentene 00646-04-8 10.47 3.17 33.177

n-Butane 00106-97-8 1.08 3.15 3.387

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.95 4.126

Ethylbenzene 00100-41-4 2.96 2.90 8.585

2,3,4-Trimethylpentane 00565-75-3 0.95 2.71 2.572

Ethanol 00064-17-5 1.45 2.38 3.441

2,2-DiMeHexane 00590-73-8 0.94 2.24 2.110

2,4-Dimethylpentane 00108-08-7 1.46 2.15 3.135

Methylcyclopentane 00096-37-7 2.05 2.15 4.401

t-2-Hexene 04050-45-7 8.55 2.00 17.095

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.88 14.920

n-Pentane 00109-66-0 1.21 1.79 2.169

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.58 8.739

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.55 8.339

2-Methyl-2-butene 00513-35-9 14.20 1.54 21.867

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.48 4.730

3-Methyl-t-2-pentene 00616-12-6 11.66 1.45 16.934

Methylcyclohexane 00108-87-2 1.56 1.36 2.113

2,3-Dimethylpentane 00565-59-3 1.25 1.18 1.475

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.15 5.039

n-Heptane 00142-82-5 0.97 0.97 0.934

ortho-Xylene 00095-47-6 7.58 0.46 3.474

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.42 4.898

2-Methyl-1-butene 00563-46-2 6.38 0.39 2.491

2-Methylhexane 00591-76-4 1.09 0.39 0.420

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.36 0.572

2,3-Dimethylbutane 00079-29-8 0.90 0.04 0.039

Total 101.4 314.8 3.105

Vehicle 213b - Fuel 9 psi E0 - Dynamic - Test 25764

Non Zero Mass Species Sorted By VOC
E-150

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 137.80 148.404

2-Methylbutane (Isopentane) 00078-78-4 1.35 122.64 166.167

Toluene 00108-88-3 3.93 78.85 309.495

Cyclohexane 00110-82-7 1.14 72.52 82.482

Ethanol 00064-17-5 1.45 44.76 64.855

n-Hexane 00110-54-3 1.13 43.02 48.814

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 33.34 46.607

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 26.47 31.744

3-Methylpentane 00096-14-0 1.69 22.16 37.466

Benzene 00071-43-2 0.69 19.39 13.466

n-Pentane 00109-66-0 1.21 18.25 22.172

2-Methyl-2-butene 00513-35-9 14.20 17.16 243.526

2,3-Dimethylbutane 00079-29-8 0.90 16.32 14.665

Methylcyclopentane 00096-37-7 2.05 15.20 31.158

t-2-Pentene 00646-04-8 10.47 14.13 148.012

2,3,4-Trimethylpentane 00565-75-3 0.95 10.22 9.699

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.44 65.490

2,4-Dimethylpentane 00108-08-7 1.46 8.30 12.111

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.88 58.216

2-Methylhexane 00591-76-4 1.09 7.73 8.392

2,2-DiMeHexane 00590-73-8 0.94 7.32 6.894

2-Methyl-1-butene 00563-46-2 6.38 7.03 44.865

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 7.01 22.361

c-2-Pentene 00627-20-3 10.28 6.77 69.601

2,3-Dimethylpentane 00565-59-3 1.25 6.08 7.595

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.80 56.150

2,4-Dimethylhexane 00589-43-5 1.61 4.79 7.698

t-2-Hexene 04050-45-7 8.55 4.70 40.186

3-Methyl-t-2-pentene 00616-12-6 11.66 4.53 52.798

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.41 34.991

3-Methyl-c-2-pentene 00922-62-3 12.52 4.19 52.429

n-Heptane 00142-82-5 0.97 4.12 3.978

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.12 6.610

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.91 20.696

2,2,5-Trimethylhexane 03522-94-9 1.05 3.48 3.664

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.31 17.751

2-Methyl-2-pentene 00625-27-4 11.03 3.30 36.401

Cyclopentene 00142-29-0 6.69 3.26 21.774

1-Methylcyclopentene 00693-89-0 12.45 3.11 38.790

Methylcyclohexane 00108-87-2 1.56 3.10 4.829

c-2-Butene 00590-18-1 14.26 3.02 43.106

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.01 19.864

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.51 2.740

ortho-Xylene 00095-47-6 7.58 2.24 16.957

Vehicle 213b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7516

Non Zero Mass Species Sorted By VOC
E-151

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7516

Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 1.81 5.362

t-1,2-Dimethylcyclopentane 00822-50-4 2.68 1.75 4.696

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.70 7.485

2,3,5-Trimethylhexane 01069-53-0 1.12 1.69 1.888

c-1,3-Dimethylcyclopentane 02532-58-3 2.68 1.62 4.325

2,2-Dimethylbutane 00075-83-2 1.11 1.53 1.698

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.49 8.626

Propane 00074-98-6 0.46 1.42 0.648

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.34 7.434

3-Methylheptane 00589-81-1 1.12 1.33 1.490

2-Methylheptane 00592-27-8 0.97 1.21 1.166

2,2-Dimethylpentane 00590-35-2 1.04 1.18 1.236

c-1,3-Dimethylcyclohexane 00638-04-0 2.68 1.18 3.171

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.17 13.745

n-Octane 00111-65-9 0.80 1.12 0.895

2-Methylpropane 00075-28-5 1.18 1.10 1.292

2,2,3-Trimethylbutane 00464-06-2 1.05 1.03 1.086

3,3-Dimethylpentane 00562-49-2 1.12 0.86 0.961

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.86 6.732

c-2-Heptene 06443-92-1 7.08 0.73 5.139

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.62 7.440

Unknown #5 2.68 0.52 1.400

t-3-Heptene 14686-14-7 6.17 0.52 3.219

4-Methyl-t-2-pentene 00674-76-0 8.04 0.49 3.951

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.43 1.658

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.34 3.568

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.30 2.155

2,4-Dimethylheptane 02213-23-2 1.26 0.28 0.356

Methane 00074-82-8 0.01 0.25 0.003

Total 858.6 2298.5 2.677

No MIR available, use weighted average of 2.6770

continued
E-152

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 4.66 9.129

n-Butane 00106-97-8 1.08 4.48 4.821

Ethanol 00064-17-5 1.45 3.43 4.964

Toluene 00108-88-3 3.93 3.30 12.936

2-Methylbutane (Isopentane) 00078-78-4 1.35 2.46 3.328

Cyclohexane 00110-82-7 1.14 1.90 2.160

n-Hexane 00110-54-3 1.13 1.25 1.414

Benzene 00071-43-2 0.69 1.08 0.751

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.94 1.320

Methylcyclopentane 00096-37-7 2.05 0.90 1.847

2,3-Dimethylbutane 00079-29-8 0.90 0.87 0.780

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.86 6.636

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.76 0.834

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.70 4.642

2-Methyl-2-butene 00513-35-9 14.20 0.55 7.769

t-2-Hexene 04050-45-7 8.55 0.54 4.631

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.48 2.113

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.46 5.429

Indan 00496-11-7 3.23 0.45 1.453

2,4-Dimethylpentane 00108-08-7 1.46 0.45 0.655

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.44 2.354

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.38 0.455

3-Methyl-c-2-pentene 00922-62-3 12.52 0.37 4.633

2,3,5-Trimethylhexane 01069-53-0 1.12 0.36 0.405

2-Methyl-1-butene 00563-46-2 6.38 0.36 2.292

2,3,4-Trimethylpentane 00565-75-3 0.95 0.36 0.338

c-2-Pentene 00627-20-3 10.28 0.31 3.183

c-2-Butene 00590-18-1 14.26 0.27 3.862

n-Pentane 00109-66-0 1.21 0.27 0.325

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.27 0.429

Ethylbenzene 00100-41-4 2.96 0.22 0.656

2-Methylhexane 00591-76-4 1.09 0.22 0.238

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.21 2.505

Cyclopentene 00142-29-0 6.69 0.19 1.293

t-2-Pentene 00646-04-8 10.47 0.19 1.969

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.17 0.542

ortho-Xylene 00095-47-6 7.58 0.10 0.752

2,3-Dimethylpentane 00565-59-3 1.25 0.09 0.109

Total 35.3 104.0 2.947

Vehicle 213b - Fuel 7 psi E0 - 86°F Static - Test 7526

Non Zero Mass Species Sorted By VOC
E-153

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 9.49 37.259

2-Methylbutane (Isopentane) 00078-78-4 1.35 6.08 8.236

Cyclohexane 00110-82-7 1.14 5.90 6.710

n-Butane 00106-97-8 1.08 5.83 6.273

Ethanol 00064-17-5 1.45 4.29 6.213

n-Hexane 00110-54-3 1.13 3.00 3.407

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.47 3.453

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.11 2.533

Benzene 00071-43-2 0.69 2.09 1.454

2-Methyl-2-butene 00513-35-9 14.20 1.84 26.133

Methylcyclopentane 00096-37-7 2.05 1.71 3.507

3-Methyl-c-2-pentene 00922-62-3 12.52 1.63 20.410

2,3-Dimethylbutane 00079-29-8 0.90 1.61 1.446

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.55 12.007

3-Methylpentane 00096-14-0 1.69 1.54 2.599

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.22 6.570

t-2-Pentene 00646-04-8 10.47 1.15 12.044

n-Pentane 00109-66-0 1.21 1.13 1.375

2,3,4-Trimethylpentane 00565-75-3 0.95 1.11 1.057

ortho-Xylene 00095-47-6 7.58 0.98 7.435

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.89 10.685

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.86 10.162

2,4-Dimethylpentane 00108-08-7 1.46 0.84 1.230

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.79 3.451

c-2-Pentene 00627-20-3 10.28 0.78 8.015

Ethylbenzene 00100-41-4 2.96 0.76 2.250

t-2-Hexene 04050-45-7 8.55 0.65 5.594

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.65 3.576

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.64 0.700

3-Methyl-t-2-pentene 00616-12-6 11.66 0.62 7.254

2-Methyl-1-butene 00563-46-2 6.38 0.51 3.280

2-Methylhexane 00591-76-4 1.09 0.51 0.553

2,2-DiMeHexane 00590-73-8 0.94 0.46 0.437

2,3-Dimethylpentane 00565-59-3 1.25 0.43 0.540

2-Methyl-2-pentene 00625-27-4 11.03 0.42 4.675

Cyclopentene 00142-29-0 6.69 0.41 2.729

Methylcyclohexane 00108-87-2 1.56 0.40 0.620

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.39 2.587

n-Heptane 00142-82-5 0.97 0.36 0.352

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.36 4.181

2,3,5-Trimethylhexane 01069-53-0 1.12 0.33 0.367

c-2-Butene 00590-18-1 14.26 0.30 4.335

2-Methylheptane 00592-27-8 0.97 0.27 0.264

2,4-Dimethylhexane 00589-43-5 1.61 0.27 0.437

Vehicle 213b - Fuel 7 psi E0 - 105°F Static - Test 7528

Non Zero Mass Species Sorted By VOC
E-154

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 7 psi E0 - 105°F Static - Test 7528

Non Zero Mass Species Sorted By VOC

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.27 1.421

2,2,5-Trimethylhexane 03522-94-9 1.05 0.26 0.269

n-Propylbenzene 00103-65-1 1.96 0.25 0.489

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.23 0.734

2,2-Dimethylbutane 00075-83-2 1.11 0.16 0.176

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.15 0.240

Total 71.0 251.7 3.546

continued
E-155

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 11.71 22.952

Toluene 00108-88-3 3.93 9.41 36.935

n-Butane 00106-97-8 1.08 7.85 8.449

2-Methylbutane (Isopentane) 00078-78-4 1.35 7.14 9.672

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.94 21.177

n-Hexane 00110-54-3 1.13 3.84 4.352

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.80 20.688

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.76 32.264

n-Pentane 00109-66-0 1.21 2.64 3.209

Methylcyclopentane 00096-37-7 2.05 2.27 4.653

Benzene 00071-43-2 0.69 2.10 1.460

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.96 2.346

t-2-Butene 00624-64-6 15.20 1.84 27.977

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.78 20.918

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.69 2.357

3-Methylpentane 00096-14-0 1.69 1.58 2.665

2,3-Dimethylbutane 00079-29-8 0.90 1.53 1.376

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.52 12.081

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.48 6.521

2-Methyl-2-butene 00513-35-9 14.20 1.46 20.689

Methylcyclohexane 00108-87-2 1.56 1.29 2.005

t-2-Pentene 00646-04-8 10.47 1.19 12.424

2,3,4-Trimethylpentane 00565-75-3 0.95 1.11 1.049

Cyclohexane 00110-82-7 1.14 1.08 1.228

Ethylbenzene 00100-41-4 2.96 1.08 3.194

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.02 7.946

n-Octane 00111-65-9 0.80 1.02 0.813

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.00 3.205

n-Heptane 00142-82-5 0.97 1.00 0.965

2-Methylheptane 00592-27-8 0.97 0.96 0.926

c-2-Pentene 00627-20-3 10.28 0.94 9.631

2-Methyl-1-butene 00563-46-2 6.38 0.89 5.655

2,2-DiMeHexane 00590-73-8 0.94 0.86 0.811

n-Nonane 00111-84-2 0.68 0.82 0.558

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.79 4.358

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.78 5.147

3-Methyl-c-2-pentene 00922-62-3 12.52 0.75 9.435

n-Decane 00124-18-5 0.59 0.74 0.440

3-Methylheptane 00589-81-1 1.12 0.69 0.773

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.65 4.618

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.64 1.023

2,4-Dimethylpentane 00108-08-7 1.46 0.64 0.928

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.63 7.550

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.62 0.675

Vehicle 213b - Fuel 7 psi E0 - Dynamic - Test 25769

Non Zero Mass Species Sorted By VOC
E-156

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 7 psi E0 - Dynamic - Test 25769

Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.61 0.984

2,3,5-Trimethylhexane 01069-53-0 1.12 0.61 0.679

ortho-Xylene 00095-47-6 7.58 0.54 4.120

c-2-Butene 00590-18-1 14.26 0.52 7.407

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.51 5.337

2-Methylhexane 00591-76-4 1.09 0.50 0.541

2,2,5-Trimethylhexane 03522-94-9 1.05 0.49 0.515

3-Methyl-t-2-pentene 00616-12-6 11.66 0.35 4.110

2-Methyl-2-pentene 00625-27-4 11.03 0.29 3.219

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.29 1.528

Cyclopentene 00142-29-0 6.69 0.29 1.924

t-2-Hexene 04050-45-7 8.55 0.23 1.967

2,3-Dimethylpentane 00565-59-3 1.25 0.21 0.262

Indan 00496-11-7 3.23 0.11 0.345

2,2-Dimethylbutane 00075-83-2 1.11 0.08 0.092

Total 98.1 381.1 3.885

continued
E-157

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 127.04 172.118

Toluene 00108-88-3 3.93 123.83 486.039

Cyclohexane 00110-82-7 1.14 79.53 90.453

n-Butane 00106-97-8 1.08 74.55 80.280

n-Hexane 00110-54-3 1.13 43.71 49.595

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 34.55 48.288

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 28.63 34.327

3-Methylpentane 00096-14-0 1.69 23.32 39.423

Ethanol 00064-17-5 1.45 22.08 31.989

Benzene 00071-43-2 0.69 20.03 13.907

n-Pentane 00109-66-0 1.21 18.79 22.825

2-Methyl-2-butene 00513-35-9 14.20 17.74 251.830

2,3-Dimethylbutane 00079-29-8 0.90 17.30 15.547

Methylcyclopentane 00096-37-7 2.05 15.61 31.988

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.87 115.305

t-2-Pentene 00646-04-8 10.47 14.54 152.271

2,3,4-Trimethylpentane 00565-75-3 0.95 11.41 10.825

Ethylbenzene 00100-41-4 2.96 7.97 23.619

2,4-Dimethylpentane 00108-08-7 1.46 7.96 11.622

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.62 56.265

2-Methylhexane 00591-76-4 1.09 7.54 8.184

c-2-Pentene 00627-20-3 10.28 7.23 74.294

2-Methyl-1-butene 00563-46-2 6.38 6.98 44.505

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 6.60 21.056

2,3-Dimethylpentane 00565-59-3 1.25 6.36 7.943

2,2-DiMeHexane 00590-73-8 0.94 6.30 5.930

2,4-Dimethylhexane 00589-43-5 1.61 5.52 8.857

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.43 29.166

t-2-Hexene 04050-45-7 8.55 5.41 46.249

3-Methyl-c-2-pentene 00922-62-3 12.52 5.37 67.261

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.86 56.897

3-Methyl-t-2-pentene 00616-12-6 11.66 4.61 53.718

2,2,5-Trimethylhexane 03522-94-9 1.05 4.57 4.811

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.46 7.153

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 4.42 23.438

ortho-Xylene 00095-47-6 7.58 4.13 31.305

n-Heptane 00142-82-5 0.97 3.89 3.759

1-Methylcyclopentene 00693-89-0 12.45 3.46 43.139

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.37 26.789

c-2-Butene 00590-18-1 14.26 3.33 47.422

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.25 3.554

2-Methyl-2-pentene 00625-27-4 11.03 3.23 35.603

Cyclopentene 00142-29-0 6.69 3.13 20.938

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.08 36.198

Vehicle 213b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7538

Non Zero Mass Species Sorted By VOC
E-158

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 213b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7538

Non Zero Mass Species Sorted By VOC

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.88 18.998

2,2-Dimethylbutane 00075-83-2 1.11 2.55 2.836

Methylcyclohexane 00108-87-2 1.56 2.53 3.936

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.28 10.024

t-1,2-Dimethylcyclopentane 00822-50-4 2.98 2.08 6.186

c-1,3-Dimethylcyclopentane 02532-58-3 2.98 1.73 5.138

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.56 8.648

n-Propylbenzene 00103-65-1 1.96 1.41 2.767

2-Methylheptane 00592-27-8 0.97 1.38 1.339

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.19 14.151

2,2-Dimethylpentane 00590-35-2 1.04 1.14 1.184

3-Methylheptane 00589-81-1 1.12 1.05 1.183

Styrene 00100-42-5 1.66 1.05 1.742

n-Octane 00111-65-9 0.80 0.92 0.729

3,3-Dimethylpentane 00562-49-2 1.12 0.90 1.007

Unknown #16 2.98 0.89 2.662

c-2-Heptene 06443-92-1 7.08 0.88 6.247

2-Methylpropane 00075-28-5 1.18 0.86 1.008

Methane 00074-82-8 0.01 0.75 0.010

1c-2t-3-TriMeCyPentane 15890-40-1 2.98 0.72 2.141

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.71 5.590

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.71 4.094

2,3,5-Trimethylhexane 01069-53-0 1.12 0.70 0.780

Unknown #5 2.98 0.69 2.056

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.64 2.485

2,2,3-Trimethylbutane 00464-06-2 1.05 0.58 0.615

c-1,3-Dimethylcyclohexane 00638-04-0 2.98 0.49 1.466

2,4-Dimethylheptane 02213-23-2 1.26 0.48 0.612

4-Methyl-t-2-pentene 00674-76-0 8.04 0.44 3.544

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.43 3.053

t-3-Heptene 14686-14-7 6.17 0.38 2.375

1-Nonene 00124-11-8 2.49 0.38 0.938

Unknown #1 2.98 0.36 1.062

Unknown #3 2.98 0.27 0.812

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.26 2.754

Isopropylbenzene (Cumene) 00098-82-8 2.98 0.19 0.572

Total 864.0 2571.4 2.976

No MIR available, use weighted average of 2.9760

continued
E-159

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7537 21249.9 91.1 19364.6 45551.4 2.352 87

Static E10 - 7 psi 7564 11657.5 81.0 9442.0 28464.0 3.015 96

E0 - 9 psi 7644 24378.7 96.6 23556.0 50039.7 2.124 93

E0 - 7 psi 7677 14347.6 99.7 14299.8 35390.0 2.475 114

105° F E10 - 10 psi 7541 36851.0 78.1 28779.5 70524.0 2.450 105

Static E10 - 7 psi 7565 24424.1 91.8 22427.0 66555.4 2.968 127

E0 - 9 psi 7647 44422.3 90.3 40098.4 88163.2 2.199 108

E0 - 7 psi 7680 25952.5 105.4 27348.3 68042.1 2.488 120

Dynamic E10 - 10 psi 25774 180.3 74.0 133.5 501.4 3.756 45

E10 - 7 psi 25781 685.5 64.2 440.2 1445.3 3.283 69

E0 - 9 psi 25789 2388.4 99.7 2380.7 6653.4 2.795 55

E0 - 7 psi 25794 3527.7 104.6 3689.9 12792.2 3.467 114

DHB E10 - 10 psi 7546 5251.6 91.5 4805.1 12517.4 2.605 107

Total E10 - 7 psi 7569 4272.9 91.7 3916.7 11477.1 2.930 125

E0 - 9 psi 7657 19668.0 103.4 20327.8 49439.0 2.432 128

E0 - 7 psi 7686 19475.3 103.9 20242.7 51559.2 2.547 134

Vehicle 220b
E-160

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 7504.66 8081.860

2-Methylbutane (Isopentane) 00078-78-4 1.35 3577.47 4847.069

n-Hexane 00110-54-3 1.13 1212.40 1375.686

Ethanol 00064-17-5 1.45 782.86 1134.340

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 696.54 973.617

n-Pentane 00109-66-0 1.21 552.04 670.690

3-Methylpentane 00096-14-0 1.69 486.85 823.208

2-Methyl-2-butene 00513-35-9 14.20 461.55 6551.700

t-2-Pentene 00646-04-8 10.47 380.13 3981.302

Toluene 00108-88-3 3.93 347.37 1363.432

2,3-Dimethylbutane 00079-29-8 0.90 326.18 293.136

2-Methyl-1-butene 00563-46-2 6.38 269.35 1718.089

Methylcyclopentane 00096-37-7 2.05 230.99 473.483

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 229.49 275.190

c-2-Pentene 00627-20-3 10.28 206.83 2126.466

Cyclohexane 00110-82-7 1.14 203.89 231.897

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 160.56 1879.309

c-2-Butene 00590-18-1 14.26 147.02 2096.413

Benzene 00071-43-2 0.69 127.10 88.252

2,4-Dimethylpentane 00108-08-7 1.46 99.66 145.434

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 94.87 753.371

2-Methylhexane 00591-76-4 1.09 81.35 88.280

2-Methylpropane 00075-28-5 1.18 80.49 94.701

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 68.36 362.204

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 68.07 217.192

Methylcyclohexane 00108-87-2 1.56 66.82 103.924

t-2-Hexene 04050-45-7 8.55 64.95 555.280

Cyclopentene 00142-29-0 6.69 59.41 397.197

2,3,4-Trimethylpentane 00565-75-3 0.95 56.98 54.068

3-Methyl-t-2-pentene 00616-12-6 11.66 53.80 627.284

2-Methyl-2-pentene 00625-27-4 11.03 51.40 567.109

2,3-Dimethylpentane 00565-59-3 1.25 49.74 62.087

n-Heptane 00142-82-5 0.97 49.68 47.976

3-Methyl-c-2-pentene 00922-62-3 12.52 45.23 566.173

2,2-Dimethylbutane 00075-83-2 1.11 40.40 44.893

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 39.21 259.025

1-Methylcyclopentene 00693-89-0 12.45 34.02 423.682

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 32.91 190.139

2,4-Dimethylhexane 00589-43-5 1.61 28.80 46.238

2,2-Dimethylpentane 00590-35-2 1.04 25.61 26.714

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.29 157.349

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 19.83 31.830

c-1,3-Dimethylcyclopentane 02532-58-3 2.35 16.89 39.737

t-1,2-Dimethylcyclopentane 00822-50-4 2.35 16.30 38.334

Vehicle 220b - Fuel 10 psi E10 - 86°F Static - Test 7537

Non Zero Mass Species Sorted By VOC
E-161

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 10 psi E10 - 86°F Static - Test 7537

Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.61 107.883

2,2,5-Trimethylhexane 03522-94-9 1.05 13.82 14.551

2,2,3-Trimethylbutane 00464-06-2 1.05 12.76 13.445

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 12.18 13.306

n-Octane 00111-65-9 0.80 12.18 9.697

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 10.86 58.288

3,3-Dimethylpentane 00562-49-2 1.12 10.21 11.425

Propane 00074-98-6 0.46 10.13 4.631

2-Methylheptane 00592-27-8 0.97 9.25 8.945

3-Methylheptane 00589-81-1 1.12 8.21 9.232

ortho-Xylene 00095-47-6 7.58 6.03 45.711

c-1,3-Dimethylcyclohexane 00638-04-0 2.35 5.99 14.085

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.53 24.279

2-Methyl-1,3-butadiene 00078-79-5 10.48 4.75 49.801

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.72 55.535

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.57 35.840

Ethylbenzene 00100-41-4 2.96 3.93 11.646

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.66 20.279

Unknown #5 2.35 3.52 8.281

n-Propylbenzene 00103-65-1 1.96 2.73 5.354

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 2.70 10.414

3,5-Dimethylheptane 00926-82-9 1.42 2.58 3.679

t-1,4-Dimethylcyclohexane 02207-04-7 2.35 2.48 5.843

Cyclopentadiene 00542-92-7 6.89 2.28 15.738

3,3-Dimethylhexane 00563-16-6 1.15 2.28 2.623

2,3,5-Trimethylhexane 01069-53-0 1.12 2.28 2.551

c-2-Heptene 06443-92-1 7.08 2.07 14.615

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.35 1.90 4.463

t-3-Heptene 14686-14-7 6.17 1.84 11.381

4-Methyloctane 02216-34-4 0.85 1.84 1.558

Unknown #3 2.35 1.53 3.602

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.50 1.669

1-Heptene 00592-76-7 4.29 1.41 6.061

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.29 15.436

n-Nonane 00111-84-2 0.68 1.27 0.870

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.16 7.601

Indan 00496-11-7 3.23 1.06 3.434

Unknown #8 2.35 1.11 2.605

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.98 8.232

1,3-Butadiene 00106-99-0 12.45 0.95 11.792

continued
E-162

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 10 psi E10 - 86°F Static - Test 7537

Non Zero Mass Species Sorted By VOC

Isopropylbenzene (Cumene) 00098-82-8 2.35 0.76 1.786

1-Nonene 00124-11-8 2.49 0.73 1.828

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.61 6.001

Total 19364.6 45551.4 2.352

No MIR available, use weighted average of 2.3523

continued
E-163

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 10042.39 10814.781

2-Methylbutane (Isopentane) 00078-78-4 1.35 5140.76 6965.156

Ethanol 00064-17-5 1.45 2480.02 3593.485

n-Hexane 00110-54-3 1.13 1267.24 1437.910

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1087.54 1520.153

n-Pentane 00109-66-0 1.21 817.11 992.732

3-Methylpentane 00096-14-0 1.69 765.94 1295.108

2-Methyl-2-butene 00513-35-9 14.20 693.03 9837.500

Toluene 00108-88-3 3.93 600.67 2357.643

t-2-Pentene 00646-04-8 10.47 566.37 5931.860

Unknown #2 2.45 522.26 1279.801

2-Methyl-1-butene 00563-46-2 6.38 394.85 2518.552

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 392.14 470.220

Methylcyclopentane 00096-37-7 2.05 371.24 760.965

Cyclohexane 00110-82-7 1.14 325.07 369.721

c-2-Pentene 00627-20-3 10.28 307.85 3165.135

Benzene 00071-43-2 0.69 261.49 181.568

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 233.60 2734.151

c-2-Butene 00590-18-1 14.26 201.08 2867.390

2,4-Dimethylpentane 00108-08-7 1.46 162.60 237.280

2-Methylhexane 00591-76-4 1.09 136.61 148.251

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 11.57 124.96 1446.257

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 117.89 742.952

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 116.95 373.180

2-Methylpropane 00075-28-5 1.18 108.99 128.237

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 106.17 562.535

t-2-Hexene 04050-45-7 8.55 104.25 891.181

2,3,3-Trimethylpentane 00560-21-4 0.95 101.38 95.875

Cyclopentene 00142-29-0 6.69 89.79 600.341

3-Methyl-t-2-pentene 00616-12-6 11.66 86.47 1008.195

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 86.47 677.498

2,3-Dimethylpentane 00565-59-3 1.25 83.74 104.538

2-Methyl-2-pentene 00625-27-4 11.03 81.66 900.965

3-Methyl-c-2-pentene 00922-62-3 12.52 72.79 911.149

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 62.18 410.779

2,2-Dimethylbutane 00075-83-2 1.11 60.00 66.675

2,4-Dimethylhexane 00589-43-5 1.61 50.58 81.214

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 50.28 290.496

2,2-Dimethylpentane 00590-35-2 1.04 41.61 43.399

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 37.40 290.019

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 36.11 57.969

t-1,2-Dimethylcyclopentane 00822-50-4 2.45 26.43 64.767

1-Octene 00111-66-0 3.14 25.94 81.498

n-Octane 00111-65-9 0.80 23.96 19.078

Vehicle 220b - Fuel 10 psi E10 - 105°F Static - Test 7541

Non Zero Mass Species Sorted By VOC
E-164

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 10 psi E10 - 105°F Static - Test 7541

Non Zero Mass Species Sorted By VOC

c-1,3-Dimethylcyclopentane 02532-58-3 2.45 21.80 53.413

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 21.45 23.422

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 20.78 111.546

2,2,3-Trimethylbutane 00464-06-2 1.05 20.40 21.497

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 19.80 146.249

3,3-Dimethylpentane 00562-49-2 1.12 17.86 19.980

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 15.75 60.864

3-Methylheptane 00589-81-1 1.12 13.90 15.632

Propane 00074-98-6 0.46 12.19 5.574

ortho-Xylene 00095-47-6 7.58 10.98 83.193

t-1,4-Dimethylcyclohexane 02207-04-7 2.45 10.73 26.306

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.65 42.401

1,3,5-Trimethylbenzene 00108-67-8 11.75 8.40 98.793

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.15 39.641

2-Methyl-1,3-butadiene 00078-79-5 10.48 6.95 72.810

Ethylbenzene 00100-41-4 2.96 6.94 20.556

3,5-Dimethylheptane 00926-82-9 1.42 6.52 9.276

1-Methylcyclopentene 00693-89-0 12.45 5.20 64.751

n-Propylbenzene 00103-65-1 1.96 5.04 9.868

Unknown #5 2.45 4.36 10.676

3,3-Dimethylhexane 00563-16-6 1.15 4.30 4.953

c-2-Heptene 06443-92-1 7.08 3.54 25.084

2,3,5-Trimethylhexane 01069-53-0 1.12 3.23 3.617

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.00 35.865

t-3-Heptene 14686-14-7 6.17 2.91 17.948

1,1-Dimethylcyclohexane 00590-66-9 1.12 2.75 3.071

4-Methyloctane 02216-34-4 0.85 2.75 2.332

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.45 2.74 6.710

n-Nonane 00111-84-2 0.68 2.67 1.825

Cyclopentadiene 00542-92-7 6.89 2.65 18.246

Unknown #8 2.45 2.58 6.333

2,4-Dimethylheptane 02213-23-2 1.26 2.13 2.699

Unknown #16 2.45 1.95 4.785

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.93 12.615

3-Methyloctane 02216-33-3 0.88 1.93 1.704

Unknown #3 2.45 1.89 4.638

Unknown #13 2.45 1.82 4.448

1-Heptene 00592-76-7 4.29 1.71 7.327

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.66 1.415

t-4-Octene 14850-23-8 4.69 1.62 7.615

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.62 13.589

Isopropylbenzene (Cumene) 00098-82-8 2.45 1.43 3.504

continued
E-165

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 10 psi E10 - 105°F Static - Test 7541

Non Zero Mass Species Sorted By VOC

1,3-Butadiene 00106-99-0 12.45 1.42 17.743

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.36 9.664

1-Nonene 00124-11-8 2.49 1.33 3.326

Unknown #9 2.45 1.17 2.861

Indan 00496-11-7 3.23 1.07 3.455

1,4-Diethylbenzene 00105-05-5 4.39 0.99 4.351

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.88 8.637

n-Decane 00124-18-5 0.59 0.82 0.483

2-Methylheptane 00592-27-8 0.97 0.71 0.684

1-Butyne 00107-00-6 6.05 0.70 4.251

2,2-Dimethyloctane 15869-87-1 0.76 0.59 0.444

c-2-Octene 07642-04-8 2.45 0.55 1.352

c- & t-4-Nonene 02198-23-4 4.42 0.52 2.293

Unknown #7 2.45 0.51 1.261

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.49 3.688

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.48 0.571

t-2-Nonene 06434-78-2 2.45 0.48 1.165

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.47 1.798

sec-Butylbenzene 00135-98-8 2.29 0.44 1.019

Total 28779.5 70524.0 2.450

No MIR available, use weighted average of 2.4505

continued
E-166

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 20.69 81.203

n-Hexane 00110-54-3 1.13 15.30 17.365

Ethanol 00064-17-5 1.45 8.67 12.564

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.36 39.529

2,3,3-Trimethylpentane 00560-21-4 0.95 6.54 6.186

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 6.16 7.382

Unknown #2 3.76 5.52 20.733

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.69 20.624

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.34 33.634

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.26 50.132

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.92 30.725

Unknown #23 3.76 3.61 13.563

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.39 21.348

1-Octene 00111-66-0 3.14 2.87 9.017

Benzene 00071-43-2 0.69 2.23 1.546

Cyclohexane 00110-82-7 1.14 2.16 2.459

3-Methylheptane 00589-81-1 1.12 2.01 2.256

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.88 2.048

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.81 21.618

2,4-Dimethylhexane 00589-43-5 1.61 1.76 2.818

ortho-Xylene 00095-47-6 7.58 1.69 12.817

2-Methyl-2-butene 00513-35-9 14.20 1.60 22.727

n-Propylbenzene 00103-65-1 1.96 1.54 3.011

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.50 8.318

3-Methylpentane 00096-14-0 1.69 1.42 2.398

n-Butane 00106-97-8 1.08 1.39 1.496

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.30 2.080

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.29 1.802

2-Methylhexane 00591-76-4 1.09 1.18 1.279

Ethylbenzene 00100-41-4 2.96 1.14 3.363

t-2-Pentene 00646-04-8 10.47 1.13 11.783

Methylcyclopentane 00096-37-7 2.05 1.07 2.194

Methane 00074-82-8 0.01 0.99 0.014

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.94 3.008

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.94 3.622

2,4-Dimethylpentane 00108-08-7 1.46 0.86 1.251

3-Methyl-c-2-pentene 00922-62-3 12.52 0.84 10.510

n-Octane 00111-65-9 0.80 0.81 0.642

2,3-Dimethylpentane 00565-59-3 1.25 0.79 0.990

Cyclopentene 00142-29-0 6.69 0.57 3.794

Indan 00496-11-7 3.23 0.45 1.440

t-2-Hexene 04050-45-7 8.55 0.42 3.589

2-Methyl-1-butene 00563-46-2 6.38 0.32 2.070

n-Pentane 00109-66-0 1.21 0.16 0.189

3-Methyl-t-2-pentene 00616-12-6 11.66 0.02 0.245

Total 133.5 501.4 3.756

No MIR available, use weighted average of 3.7557

Vehicle 220b - Fuel 10 psi E10 - Dynamic - Test 25774

Non Zero Mass Species Sorted By VOC
E-167

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 892.60 961.253

2-Methylbutane (Isopentane) 00078-78-4 1.35 526.18 712.909

Ethanol 00064-17-5 1.45 428.56 620.967

Toluene 00108-88-3 3.93 351.76 1380.656

n-Hexane 00110-54-3 1.13 308.99 350.599

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 202.21 282.648

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 192.65 231.016

3-Methylpentane 00096-14-0 1.69 151.41 256.016

n-Pentane 00109-66-0 1.21 102.33 124.325

2-Methyl-2-butene 00513-35-9 14.20 95.80 1359.818

Cyclohexane 00110-82-7 1.14 95.58 108.714

Methylcyclopentane 00096-37-7 2.05 93.41 191.477

2,3-Dimethylbutane 00079-29-8 0.90 90.28 81.133

t-2-Pentene 00646-04-8 10.47 78.05 817.462

2,3,4-Trimethylpentane 00565-75-3 0.95 71.14 67.498

Benzene 00071-43-2 0.69 64.99 45.126

Methylcyclohexane 00108-87-2 1.56 59.68 92.818

2-Methylhexane 00591-76-4 1.09 57.54 62.439

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 50.18 160.132

2,4-Dimethylpentane 00108-08-7 1.46 49.79 72.657

n-Heptane 00142-82-5 0.97 47.93 46.289

2-Methyl-1-butene 00563-46-2 6.38 47.42 302.473

c-2-Pentene 00627-20-3 10.28 42.18 433.701

2,3-Dimethylpentane 00565-59-3 1.25 33.91 42.337

2,4-Dimethylhexane 00589-43-5 1.61 33.29 53.444

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 33.24 257.829

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 28.63 335.068

t-2-Hexene 04050-45-7 8.55 27.16 232.162

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 24.94 40.040

2,2,5-Trimethylhexane 03522-94-9 1.05 24.23 25.514

n-Octane 00111-65-9 0.80 23.84 18.988

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 23.50 124.511

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 21.98 117.995

3-Methyl-t-2-pentene 00616-12-6 11.66 21.21 247.336

c-2-Butene 00590-18-1 14.26 20.30 289.422

3-Methyl-c-2-pentene 00922-62-3 12.52 19.91 249.228

2-Methyl-2-pentene 00625-27-4 11.03 19.48 214.867

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 18.91 139.677

1-Methylcyclopentene 00693-89-0 12.45 18.81 234.242

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 16.71 18.253

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 16.03 105.888

Cyclopentene 00142-29-0 6.69 14.61 97.703

2-Methylheptane 00592-27-8 0.97 14.02 13.559

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 13.03 103.456

Vehicle 220b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7546

Non Zero Mass Species Sorted By VOC
E-168

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7546

Non Zero Mass Species Sorted By VOC

2,2-Dimethylpentane 00590-35-2 1.04 12.12 12.640

3-Methylheptane 00589-81-1 1.12 11.69 13.140

t-1,2-Dimethylcyclopentane 00822-50-4 2.61 11.53 30.038

ortho-Xylene 00095-47-6 7.58 10.03 75.993

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.47 41.600

c-1,3-Dimethylcyclopentane 02532-58-3 2.61 9.28 24.168

2,2-Dimethylbutane 00075-83-2 1.11 9.21 10.238

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 8.99 51.949

1,3,5-Trimethylbenzene 00108-67-8 11.75 8.94 105.076

Ethylbenzene 00100-41-4 2.96 8.72 25.839

c-1,3-Dimethylcyclohexane 00638-04-0 2.61 8.41 21.910

2-Methylpropane 00075-28-5 1.18 8.36 9.839

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.31 40.486

3,3-Dimethylpentane 00562-49-2 1.12 6.91 7.726

2,2,3-Trimethylbutane 00464-06-2 1.05 6.08 6.412

n-Propylbenzene 00103-65-1 1.96 5.37 10.519

2,2-DiMeHexane 00590-73-8 0.94 5.22 4.918

n-Nonane 00111-84-2 0.68 4.61 3.147

3,5-Dimethylheptane 00926-82-9 1.42 4.34 6.185

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.30 33.725

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 4.07 15.727

2,3,5-Trimethylhexane 01069-53-0 1.12 3.80 4.259

t-1,4-Dimethylcyclohexane 02207-04-7 2.61 3.61 9.404

4-Methyloctane 02216-34-4 0.85 3.60 3.054

Unknown #5 2.61 3.44 8.973

Unknown #8 2.61 3.44 8.973

Unknown #16 2.61 3.30 8.596

n-Decane 00124-18-5 0.59 3.09 1.828

3,3-Dimethylhexane 00563-16-6 1.15 2.78 3.197

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.70 32.264

Unknown #13 2.61 2.42 6.302

1,1-Dimethylcyclohexane 00590-66-9 1.12 2.27 2.531

3-Methyloctane 02216-33-3 0.88 2.17 1.920

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.61 2.17 5.648

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.94 1.660

Indan 00496-11-7 3.23 1.94 6.274

c-2-Heptene 06443-92-1 7.08 1.87 13.219

2,4-Dimethylheptane 02213-23-2 1.26 1.78 2.257

1-Nonene 00124-11-8 2.49 1.78 4.445

Isopropylbenzene (Cumene) 00098-82-8 2.61 1.72 4.477

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.71 12.093

t-3-Heptene 14686-14-7 6.17 1.63 10.042

continued
E-169

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7546

Non Zero Mass Species Sorted By VOC

1,4-Diethylbenzene 00105-05-5 4.39 1.53 6.712

t-4-Octene 14850-23-8 4.69 1.48 6.962

Unknown #9 2.61 1.47 3.839

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.32 8.608

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.17 12.249

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.09 9.131

Unknown #3 2.61 1.09 2.835

Propane 00074-98-6 0.46 1.05 0.479

1-Heptene 00592-76-7 4.29 0.98 4.191

c- & t-4-Nonene 02198-23-4 4.42 0.89 3.942

1,3-Butadiene 00106-99-0 12.45 0.88 10.993

t-2-Nonene 06434-78-2 2.61 0.84 2.181

2,2-Dimethyloctane 15869-87-1 0.76 0.77 0.584

sec-Butylbenzene 00135-98-8 2.29 0.60 1.382

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.60 5.844

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.53 0.633

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.53 2.038

c-2-Octene 07642-04-8 2.61 0.52 1.349

Unknown #7 2.61 0.47 1.224

4-Methyl-t-2-pentene 00674-76-0 8.04 0.43 3.492

1,3-Diethylbenzene 00141-93-5 7.08 0.34 2.410

Total 4805.1 12517.4 2.605

No MIR available, use weighted average of 2.6050

continued
E-170

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 2650.87 3591.628

Ethanol 00064-17-5 1.45 800.67 1160.156

n-Butane 00106-97-8 1.08 756.65 814.851

n-Hexane 00110-54-3 1.13 580.87 659.099

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 514.76 719.528

n-Pentane 00109-66-0 1.21 408.11 495.831

3-Methylpentane 00096-14-0 1.69 360.08 608.854

2-Methyl-2-butene 00513-35-9 14.20 338.74 4808.373

t-2-Pentene 00646-04-8 10.47 280.15 2934.157

2,3-Dimethylbutane 00079-29-8 0.90 254.63 228.837

Toluene 00108-88-3 3.93 242.74 952.747

2-Methyl-1-butene 00563-46-2 6.38 198.81 1268.108

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 171.61 205.776

Methylcyclopentane 00096-37-7 2.05 170.27 349.010

c-2-Pentene 00627-20-3 10.28 152.17 1564.527

Cyclohexane 00110-82-7 1.14 145.36 165.322

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 119.30 1396.394

c-2-Butene 00590-18-1 14.26 108.49 1547.021

Benzene 00071-43-2 0.69 92.64 64.323

2,4-Dimethylpentane 00108-08-7 1.46 73.97 107.943

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 71.61 568.645

2-Methylpropane 00075-28-5 1.18 62.65 73.719

2-Methylhexane 00591-76-4 1.09 60.01 65.118

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 51.06 162.915

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 50.68 268.531

Methylcyclohexane 00108-87-2 1.56 50.21 78.100

t-2-Hexene 04050-45-7 8.55 48.28 412.718

Cyclopentene 00142-29-0 6.69 43.71 292.221

2,3,4-Trimethylpentane 00565-75-3 0.95 42.32 40.158

3-Methyl-t-2-pentene 00616-12-6 11.66 39.85 464.665

2-Methyl-2-pentene 00625-27-4 11.03 37.64 415.293

n-Heptane 00142-82-5 0.97 37.08 35.811

2,3-Dimethylpentane 00565-59-3 1.25 36.74 45.867

3-Methyl-c-2-pentene 00922-62-3 12.52 33.57 420.182

2,2-Dimethylbutane 00075-83-2 1.11 29.63 32.923

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 28.99 191.537

1-Methylcyclopentene 00693-89-0 12.45 25.94 323.019

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 24.21 139.870

2,4-Dimethylhexane 00589-43-5 1.61 21.28 34.162

2,2-Dimethylpentane 00590-35-2 1.04 19.27 20.104

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 15.13 24.292

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.95 115.931

t-1,2-Dimethylcyclopentane 00822-50-4 3.01 11.74 35.401

2,2,5-Trimethylhexane 03522-94-9 1.05 10.44 10.999

Vehicle 220b - Fuel 7 psi E10 - 86°F Static - Test 7564

Non Zero Mass Species Sorted By VOC
E-171

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - 86°F Static - Test 7564

Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.20 75.368

n-Octane 00111-65-9 0.80 9.96 7.934

c-1,3-Dimethylcyclopentane 02532-58-3 3.01 9.87 29.743

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.46 50.792

2,2,3-Trimethylbutane 00464-06-2 1.05 9.37 9.880

Propane 00074-98-6 0.46 9.06 4.142

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.66 9.460

3,3-Dimethylpentane 00562-49-2 1.12 7.99 8.934

2-Methylheptane 00592-27-8 0.97 7.06 6.828

3-Methylheptane 00589-81-1 1.12 5.65 6.356

ortho-Xylene 00095-47-6 7.58 4.53 34.296

c-1,3-Dimethylcyclohexane 00638-04-0 3.01 4.43 13.349

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.81 16.734

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.77 44.336

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.71 29.091

2-Methyl-1,3-butadiene 00078-79-5 10.48 3.58 37.532

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.29 18.230

Ethylbenzene 00100-41-4 2.96 2.87 8.490

3,5-Dimethylheptane 00926-82-9 1.42 2.55 3.634

n-Propylbenzene 00103-65-1 1.96 2.06 4.034

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 2.04 7.897

t-1,4-Dimethylcyclohexane 02207-04-7 3.01 1.85 5.591

3,3-Dimethylhexane 00563-16-6 1.15 1.85 2.132

Unknown #5 3.01 1.84 5.541

Cyclopentadiene 00542-92-7 6.89 1.64 11.270

2,3,5-Trimethylhexane 01069-53-0 1.12 1.56 1.748

c-2-Heptene 06443-92-1 7.08 1.51 10.680

n-Nonane 00111-84-2 0.68 1.47 1.006

t-3-Heptene 14686-14-7 6.17 1.36 8.372

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.34 16.030

Unknown #16 3.01 1.25 3.768

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.17 1.303

4-Methyloctane 02216-34-4 0.85 1.13 0.958

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.01 1.11 3.358

Unknown #8 3.01 1.11 3.341

Unknown #3 3.01 0.87 2.626

1,3-Butadiene 00106-99-0 12.45 0.86 10.721

1-Heptene 00592-76-7 4.29 0.82 3.495

Isopropylbenzene (Cumene) 00098-82-8 3.01 0.80 2.405

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.79 5.197

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.72 5.127

t-4-Octene 14850-23-8 4.69 0.67 3.165

continued
E-172

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - 86°F Static - Test 7564

Non Zero Mass Species Sorted By VOC

1-Nonene 00124-11-8 2.49 0.67 1.671

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.66 5.506

n-Decane 00124-18-5 0.59 0.64 0.380

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.63 0.538

2,4-Dimethylheptane 02213-23-2 1.26 0.42 0.536

3-Methyloctane 02216-33-3 0.88 0.41 0.366

Unknown #9 3.01 0.40 1.208

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.31 3.028

1-Butyne 00107-00-6 6.05 0.18 1.099

n-Undecane 01120-21-4 0.52 0.16 0.086

Total 9442.0 28464.0 3.015

No MIR available, use weighted average of 3.0146

continued
E-173

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 5769.20 7816.612

Ethanol 00064-17-5 1.45 2589.89 3752.691

n-Butane 00106-97-8 1.08 1559.36 1679.295

n-Hexane 00110-54-3 1.13 1414.77 1605.303

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1218.97 1703.867

n-Pentane 00109-66-0 1.21 915.30 1112.033

3-Methylpentane 00096-14-0 1.69 858.34 1451.348

2-Methyl-2-butene 00513-35-9 14.20 773.35 10977.672

Toluene 00108-88-3 3.93 656.57 2577.062

t-2-Pentene 00646-04-8 10.47 633.05 6630.198

2,3-Dimethylbutane 00079-29-8 0.90 593.24 533.142

2-Methyl-1-butene 00563-46-2 6.38 441.57 2816.547

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 440.53 528.245

Methylcyclopentane 00096-37-7 2.05 412.33 845.189

Cyclohexane 00110-82-7 1.14 347.77 395.544

c-2-Pentene 00627-20-3 10.28 344.63 3543.302

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 263.56 3084.817

Benzene 00071-43-2 0.69 227.73 158.124

c-2-Butene 00590-18-1 14.26 226.76 3233.612

2,4-Dimethylpentane 00108-08-7 1.46 182.35 266.113

2-Methylhexane 00591-76-4 1.09 151.57 164.481

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 144.84 1150.181

Methylcyclohexane 00108-87-2 1.56 132.17 205.572

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 131.60 419.935

2-Methylpropane 00075-28-5 1.18 127.58 150.115

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 121.35 642.951

t-2-Hexene 04050-45-7 8.55 117.30 1002.733

2,3,4-Trimethylpentane 00565-75-3 0.95 115.01 109.127

Cyclopentene 00142-29-0 6.69 104.56 699.056

n-Heptane 00142-82-5 0.97 97.85 94.496

3-Methyl-t-2-pentene 00616-12-6 11.66 96.96 1130.464

2,3-Dimethylpentane 00565-59-3 1.25 93.43 116.628

2-Methyl-2-pentene 00625-27-4 11.03 91.72 1011.846

3-Methyl-c-2-pentene 00922-62-3 12.52 82.76 1036.021

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 71.09 469.667

2,2-Dimethylbutane 00075-83-2 1.11 69.23 76.931

1-Methylcyclopentene 00693-89-0 12.45 66.31 825.804

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 58.14 335.930

2,4-Dimethylhexane 00589-43-5 1.61 57.48 92.290

2,2-Dimethylpentane 00590-35-2 1.04 47.87 49.926

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 41.57 66.729

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 40.64 315.148

t-1,2-Dimethylcyclopentane 00822-50-4 2.97 29.75 88.286

2,2,5-Trimethylhexane 03522-94-9 1.05 29.38 30.935

Vehicle 220b - Fuel 7 psi E10 - 105°F Static - Test 7565

Non Zero Mass Species Sorted By VOC
E-174

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - 105°F Static - Test 7565

Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 28.01 22.300

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 26.14 140.342

2,2,3-Trimethylbutane 00464-06-2 1.05 25.38 26.755

c-1,3-Dimethylcyclopentane 02532-58-3 2.97 25.04 74.296

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 24.60 26.870

3,3-Dimethylpentane 00562-49-2 1.12 21.75 24.335

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 21.73 160.471

2-Methylheptane 00592-27-8 0.97 17.82 17.240

Propane 00074-98-6 0.46 16.88 7.715

3-Methylheptane 00589-81-1 1.12 15.97 17.957

c-1,3-Dimethylcyclohexane 00638-04-0 2.97 12.00 35.609

ortho-Xylene 00095-47-6 7.58 11.88 89.997

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.82 47.540

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 10.16 79.609

1,3,5-Trimethylbenzene 00108-67-8 11.75 10.00 117.556

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 8.49 47.032

2-Methyl-1,3-butadiene 00078-79-5 10.48 8.27 86.655

Ethylcyclohexane 01678-91-7 1.35 8.09 10.877

Ethylbenzene 00100-41-4 2.96 7.29 21.601

n-Propylbenzene 00103-65-1 1.96 6.42 12.574

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 5.54 21.384

t-1,4-Dimethylcyclohexane 02207-04-7 2.97 5.50 16.327

Unknown #5 2.97 5.42 16.092

3,3-Dimethylhexane 00563-16-6 1.15 5.35 6.156

Cyclopentadiene 00542-92-7 6.89 5.09 35.060

c-2-Heptene 06443-92-1 7.08 4.75 33.578

n-Nonane 00111-84-2 0.68 4.07 2.777

t-3-Heptene 14686-14-7 6.17 3.84 23.672

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.79 45.212

1,1-Dimethylcyclohexane 00590-66-9 1.12 3.66 4.080

2,3,5-Trimethylhexane 01069-53-0 1.12 3.61 4.049

Unknown #3 2.97 3.19 9.455

Unknown #8 2.97 3.01 8.926

4-Methyloctane 02216-34-4 0.85 2.94 2.494

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.97 2.91 8.627

Unknown #13 2.97 2.75 8.159

1-Heptene 00592-76-7 4.29 2.66 11.402

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 2.65 17.338

Isopropylbenzene (Cumene) 00098-82-8 2.97 2.59 7.693

4-Methyl-t-2-pentene 00674-76-0 8.04 2.56 20.606

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 2.25 18.832

3-Methyloctane 02216-33-3 0.88 2.23 1.971

continued
E-175

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - 105°F Static - Test 7565

Non Zero Mass Species Sorted By VOC

n-Decane 00124-18-5 0.59 2.22 1.312

Unknown #16 2.97 2.08 6.186

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 2.06 1.763

1-Nonene 00124-11-8 2.49 1.81 4.502

1,3-Butadiene 00106-99-0 12.45 1.71 21.247

1,4-Diethylbenzene 00105-05-5 4.39 1.65 7.255

2,4-Dimethylheptane 02213-23-2 1.26 1.65 2.088

t-4-Octene 14850-23-8 4.69 1.55 7.276

Unknown #9 2.97 1.54 4.573

Indan 00496-11-7 3.23 1.54 4.965

3-Ethyl-c-2-Pentene 00816-79-5 9.76 1.48 14.414

Unknown #23 2.97 1.45 4.316

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.40 9.937

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.24 9.372

1-Methyl-2-Propylbenzene 01074-17-5 5.43 1.21 6.580

Unknown #14 2.97 1.15 3.408

2,2-Dimethyloctane 15869-87-1 0.76 0.97 0.733

1,3-Diethylbenzene 00141-93-5 7.08 0.97 6.834

c- & t-4-Nonene 02198-23-4 4.42 0.95 4.195

t-2-Nonene 06434-78-2 2.97 0.89 2.656

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.87 6.526

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.82 0.971

sec-Butylbenzene 00135-98-8 2.29 0.72 1.655

3-Methylnonane 2.97 0.72 2.141

Unknown #7 2.97 0.67 1.996

Unknown #4 2.97 0.65 1.943

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.65 2.498

Isobutylbenzene 00538-93-2 2.97 0.65 1.933

Unknown #6 . 2.97 0.64 1.886

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.62 6.348

Unknown #15 2.97 0.57 1.680

Unknown #10 2.97 0.48 1.430

1-Butyne 00107-00-6 6.05 0.42 2.558

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.39 2.944

t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 0.37 2.164

c-1,2-Dimethylcyclohexane 02207-01-4 2.97 0.34 1.006

n-Undecane 01120-21-4 0.52 0.34 0.176

c-2-Octene 07642-04-8 2.97 0.32 0.959

Unknown #12 2.97 0.32 0.944

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.25 1.123

1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.19 1.748

Total 22427.0 66555.4 2.968

No MIR available, use weighted average of 2.9676

continued
E-176

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 98.83 133.901

Ethanol 00064-17-5 1.45 28.30 41.006

n-Hexane 00110-54-3 1.13 26.58 30.156

Toluene 00108-88-3 3.93 24.49 96.112

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 22.09 30.872

n-Pentane 00109-66-0 1.21 16.18 19.656

3-Methylpentane 00096-14-0 1.69 15.88 26.846

2-Methyl-2-butene 00513-35-9 14.20 12.64 179.359

n-Butane 00106-97-8 1.08 11.94 12.859

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 11.47 13.757

2,3-Dimethylbutane 00079-29-8 0.90 11.39 10.233

t-2-Pentene 00646-04-8 10.47 10.47 109.676

Methylcyclopentane 00096-37-7 2.05 8.17 16.737

2-Methyl-1-butene 00563-46-2 6.38 7.92 50.510

Cyclohexane 00110-82-7 1.14 6.74 7.663

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.19 33.261

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 5.12 16.339

c-2-Pentene 00627-20-3 10.28 5.06 52.052

c-2-Butene 00590-18-1 14.26 4.93 70.326

Benzene 00071-43-2 0.69 4.79 3.324

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.41 51.813

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.36 51.038

2,4-Dimethylpentane 00108-08-7 1.46 3.96 5.784

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.86 20.464

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.79 30.111

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.67 28.441

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.57 15.704

2,3,4-Trimethylpentane 00565-75-3 0.95 3.55 3.372

2-Methylpropane 00075-28-5 1.18 3.43 4.033

2-Methylhexane 00591-76-4 1.09 3.32 3.604

Methylcyclohexane 00108-87-2 1.56 3.12 4.854

n-Heptane 00142-82-5 0.97 2.95 2.854

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.60 17.196

t-2-Hexene 04050-45-7 8.55 2.54 21.712

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.51 17.810

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.43 17.949

2,2-Dimethylpentane 00590-35-2 1.04 2.29 2.391

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.26 12.543

n-Octane 00111-65-9 0.80 2.11 1.684

n-Nonane 00111-84-2 0.68 2.06 1.404

2,3-Dimethylpentane 00565-59-3 1.25 2.01 2.514

Methane 00074-82-8 0.01 1.99 0.028

2-Methyl-2-pentene 00625-27-4 11.03 1.91 21.073

3-Methyl-t-2-pentene 00616-12-6 11.66 1.89 22.026

Vehicle 220b - Fuel 7 psi E10 - Dynamic - Test 25781

Non Zero Mass Species Sorted By VOC
E-177

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - Dynamic - Test 25781

Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 1.87 0.975

2,2,5-Trimethylhexane 03522-94-9 1.05 1.81 1.902

Cyclopentene 00142-29-0 6.69 1.77 11.804

ortho-Xylene 00095-47-6 7.58 1.76 13.337

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.67 19.911

3-Methyl-c-2-pentene 00922-62-3 12.52 1.66 20.757

2,2-Dimethylbutane 00075-83-2 1.11 1.62 1.796

n-Propylbenzene 00103-65-1 1.96 1.60 3.133

3,3-Dimethylpentane 00562-49-2 1.12 1.46 1.630

3-Methylheptane 00589-81-1 1.12 1.40 1.569

t-1,2-Dimethylcyclopentane 00822-50-4 3.28 1.38 4.516

Indan 00496-11-7 3.23 1.34 4.321

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.32 2.113

1-Methylcyclopentene 00693-89-0 12.45 1.25 15.571

c-1,3-Dimethylcyclohexane 00638-04-0 3.28 1.20 3.939

c-1,3-Dimethylcyclopentane 02532-58-3 3.28 1.20 3.928

Ethylbenzene 00100-41-4 2.96 1.07 3.180

n-Decane 00124-18-5 0.59 1.02 0.600

2-Methylheptane 00592-27-8 0.97 0.81 0.780

2,2,3-Trimethylbutane 00464-06-2 1.05 0.73 0.768

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.68 2.611

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.67 3.875

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.63 6.610

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.52 0.571

2,4-Dimethylhexane 00589-43-5 1.61 0.02 0.034

Total 440.2 1445.3 3.283

No MIR available, use weighted average of 3.2833

continued
E-178

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 489.17 662.773

Ethanol 00064-17-5 1.45 400.13 579.776

Toluene 00108-88-3 3.93 359.77 1412.113

n-Hexane 00110-54-3 1.13 300.42 340.878

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 192.23 268.701

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 182.57 218.917

3-Methylpentane 00096-14-0 1.69 145.21 245.525

n-Butane 00106-97-8 1.08 119.26 128.430

n-Pentane 00109-66-0 1.21 95.19 115.644

Cyclohexane 00110-82-7 1.14 93.57 106.425

2-Methyl-2-butene 00513-35-9 14.20 90.18 1280.067

Methylcyclopentane 00096-37-7 2.05 89.98 184.432

2,3-Dimethylbutane 00079-29-8 0.90 84.97 76.362

t-2-Pentene 00646-04-8 10.47 73.23 766.951

2,3,4-Trimethylpentane 00565-75-3 0.95 68.70 65.189

Benzene 00071-43-2 0.69 64.99 45.127

Methylcyclohexane 00108-87-2 1.56 58.40 90.837

2-Methylhexane 00591-76-4 1.09 54.62 59.269

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 48.02 153.243

n-Heptane 00142-82-5 0.97 47.88 46.239

2,4-Dimethylpentane 00108-08-7 1.46 47.48 69.294

2-Methyl-1-butene 00563-46-2 6.38 43.73 278.949

c-2-Pentene 00627-20-3 10.28 39.42 405.244

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 34.71 269.153

2,4-Dimethylhexane 00589-43-5 1.61 32.69 52.491

2,3-Dimethylpentane 00565-59-3 1.25 31.57 39.406

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 28.61 211.289

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 27.35 320.167

t-2-Hexene 04050-45-7 8.55 26.15 223.518

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 25.58 137.339

n-Octane 00111-65-9 0.80 25.39 20.218

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 23.79 38.192

2,2,5-Trimethylhexane 03522-94-9 1.05 23.77 25.033

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 22.90 121.314

3-Methyl-t-2-pentene 00616-12-6 11.66 20.75 241.964

3-Methyl-c-2-pentene 00922-62-3 12.52 19.27 241.268

2-Methyl-2-pentene 00625-27-4 11.03 18.56 204.719

c-2-Butene 00590-18-1 14.26 18.06 257.579

1-Methylcyclopentene 00693-89-0 12.45 18.02 224.391

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 16.64 18.172

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 15.53 102.611

Cyclopentene 00142-29-0 6.69 13.49 90.225

2-Methylheptane 00592-27-8 0.97 13.31 12.877

3-Methylheptane 00589-81-1 1.12 11.96 13.451

Vehicle 220b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7569

Non Zero Mass Species Sorted By VOC
E-179

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7569

Non Zero Mass Species Sorted By VOC

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 11.86 94.172

2,2-Dimethylpentane 00590-35-2 1.04 11.44 11.931

t-1,2-Dimethylcyclopentane 00822-50-4 2.93 11.38 33.352

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 11.25 49.438

1,3,5-Trimethylbenzene 00108-67-8 11.75 10.70 125.754

ortho-Xylene 00095-47-6 7.58 10.23 77.467

2,2-Dimethylbutane 00075-83-2 1.11 9.79 10.883

c-1,3-Dimethylcyclopentane 02532-58-3 2.93 9.07 26.589

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 8.70 48.240

c-1,3-Dimethylcyclohexane 00638-04-0 2.93 8.65 25.348

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 8.21 47.420

Ethylbenzene 00100-41-4 2.96 7.78 23.059

2-Methylpropane 00075-28-5 1.18 7.40 8.705

n-Propylbenzene 00103-65-1 1.96 6.78 13.292

3,3-Dimethylpentane 00562-49-2 1.12 6.66 7.446

2,2,3-Trimethylbutane 00464-06-2 1.05 5.72 6.028

n-Nonane 00111-84-2 0.68 5.18 3.537

2,2-DiMeHexane 00590-73-8 0.94 4.79 4.504

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.32 33.865

4-Methyloctane 02216-34-4 0.85 4.15 3.519

Unknown #16 2.93 4.07 11.939

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 4.07 15.734

2,3,5-Trimethylhexane 01069-53-0 1.12 3.93 4.401

t-1,4-Dimethylcyclohexane 02207-04-7 2.93 3.78 11.067

3,5-Dimethylheptane 00926-82-9 1.42 3.74 5.329

Unknown #8 2.93 3.60 10.550

Unknown #5 2.93 3.53 10.346

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.50 41.768

n-Decane 00124-18-5 0.59 3.19 1.884

3-Methyloctane 02216-33-3 0.88 3.01 2.662

3,3-Dimethylhexane 00563-16-6 1.15 2.96 3.407

Unknown #13 2.93 2.84 8.314

1,1-Dimethylcyclohexane 00590-66-9 1.12 2.48 2.768

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 2.40 2.050

Indan 00496-11-7 3.23 2.34 7.572

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.28 16.138

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.93 2.25 6.584

c-2-Heptene 06443-92-1 7.08 2.11 14.911

1-Nonene 00124-11-8 2.49 1.89 4.711

Isopropylbenzene (Cumene) 00098-82-8 2.93 1.84 5.394

1,4-Diethylbenzene 00105-05-5 4.39 1.78 7.792

t-3-Heptene 14686-14-7 6.17 1.73 10.692

continued
E-180

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7569

Non Zero Mass Species Sorted By VOC

2,4-Dimethylheptane 02213-23-2 1.26 1.61 2.041

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 1.49 1.759

Unknown #9 2.93 1.32 3.856

1-Methyl-2-Propylbenzene 01074-17-5 5.43 1.30 7.076

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.22 7.986

1,3-Butadiene 00106-99-0 12.45 1.16 14.450

1-Heptene 00592-76-7 4.29 1.15 4.924

t-4-Octene 14850-23-8 4.69 1.12 5.244

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.12 9.362

3-Methylnonane 2.93 1.08 3.176

Ethylene 00074-85-1 8.88 1.02 9.052

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.00 10.454

Propane 00074-98-6 0.46 0.99 0.452

Unknown #14 2.93 0.92 2.697

c- & t-4-Nonene 02198-23-4 4.42 0.91 4.022

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.90 6.791

t-2-Nonene 06434-78-2 2.93 0.88 2.585

Unknown #3 2.93 0.88 2.581

Unknown #22 . 2.93 0.86 2.524

1,3-Diethylbenzene 00141-93-5 7.08 0.84 5.930

c-2-Octene 07642-04-8 2.93 0.82 2.398

sec-Butylbenzene 00135-98-8 2.29 0.78 1.795

2,2-Dimethyloctane 15869-87-1 0.76 0.74 0.560

n-Undecane 01120-21-4 0.52 0.72 0.378

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.63 2.409

4-Methyl-t-2-pentene 00674-76-0 8.04 0.62 5.015

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.62 6.279

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.61 5.955

Unknown #7 2.93 0.58 1.693

Isobutylbenzene 00538-93-2 2.93 0.56 1.630

Unknown #6 . 2.93 0.54 1.583

Unknown #12 2.93 0.50 1.468

Unknown #10 2.93 0.45 1.317

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.41 3.123

t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 0.41 2.440

Unknown #17 2.93 0.41 1.190

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.33 2.478

Unknown #15 2.93 0.30 0.878

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.28 1.240

Total 3916.7 11477.1 2.930

No MIR available, use weighted average of 2.9303

continued
E-181

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 9476.55 10205.420

2-Methylbutane (Isopentane) 00078-78-4 1.35 6062.19 8213.588

Cyclohexane 00110-82-7 1.14 1145.93 1303.337

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 749.37 1047.458

n-Hexane 00110-54-3 1.13 595.96 676.225

n-Pentane 00109-66-0 1.21 516.50 627.514

3-Methylpentane 00096-14-0 1.69 480.94 813.205

2,3-Dimethylbutane 00079-29-8 0.90 442.20 397.402

2-Methyl-2-butene 00513-35-9 14.20 413.43 5868.679

Toluene 00108-88-3 3.93 401.99 1577.804

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 341.71 409.745

t-2-Pentene 00646-04-8 10.47 320.70 3358.834

Methylcyclopentane 00096-37-7 2.05 227.84 467.014

2-Methyl-1-butene 00563-46-2 6.38 219.35 1399.150

c-2-Pentene 00627-20-3 10.28 174.52 1794.265

t-2-Butene 00624-64-6 15.20 132.26 2010.005

Benzene 00071-43-2 0.69 130.94 90.916

2,4-Dimethylpentane 00108-08-7 1.46 128.45 187.447

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 127.39 1491.092

c-2-Butene 00590-18-1 14.26 102.93 1467.759

2,3,4-Trimethylpentane 00565-75-3 0.95 87.93 83.431

2,2-Dimethylbutane 00075-83-2 1.11 87.02 96.698

2,3-Dimethylpentane 00565-59-3 1.25 75.65 94.439

2-Methylhexane 00591-76-4 1.09 74.15 80.472

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 67.24 356.267

t-2-Hexene 04050-45-7 8.55 64.62 552.425

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 64.49 205.770

3-Methyl-t-2-pentene 00616-12-6 11.66 62.94 733.843

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 61.13 485.454

Cyclopentene 00142-29-0 6.69 53.21 355.777

2-Methyl-2-pentene 00625-27-4 11.03 50.00 551.639

3-Methyl-c-2-pentene 00922-62-3 12.52 44.98 563.086

1-Methylcyclopentene 00693-89-0 12.45 38.94 484.991

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 37.82 249.884

3-Methyl-1-butene 00563-45-1 6.85 36.81 252.358

2-Methylpropane 00075-28-5 1.18 33.81 39.779

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 31.90 184.292

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 31.78 246.451

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 29.81 47.859

2,4-Dimethylhexane 00589-43-5 1.61 29.62 47.552

2,2,5-Trimethylhexane 03522-94-9 1.05 25.30 26.642

n-Heptane 00142-82-5 0.97 23.59 22.784

2,2-Dimethylpentane 00590-35-2 1.04 18.53 19.325

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 18.52 20.224

Vehicle 220b - Fuel 9 psi E0 - 86°F Static - Test 7644

Non Zero Mass Species Sorted By VOC
E-182

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - 86°F Static - Test 7644

Non Zero Mass Species Sorted By VOC

Methylcyclohexane 00108-87-2 1.56 16.79 26.122

t-1,2-Dimethylcyclopentane 00822-50-4 2.12 16.73 35.534

c-1,3-Dimethylcyclopentane 02532-58-3 2.12 13.43 28.535

2,2,3-Trimethylbutane 00464-06-2 1.05 11.95 12.596

4-Methyl-t-2-pentene 00674-76-0 8.04 11.71 94.130

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.47 61.582

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.49 77.485

ortho-Xylene 00095-47-6 7.58 9.39 71.125

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.78 34.179

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 7.32 57.358

3,3-Dimethylpentane 00562-49-2 1.12 7.03 7.865

3-Methylheptane 00589-81-1 1.12 6.24 7.017

Ethylbenzene 00100-41-4 2.96 6.15 18.224

Unknown #1 2.12 4.83 10.259

2-Methylheptane 00592-27-8 0.97 4.80 4.647

2-Methyl-1,3-butadiene 00078-79-5 10.48 4.62 48.464

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.43 52.038

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.18 23.191

Propane 00074-98-6 0.46 4.17 1.908

n-Propylbenzene 00103-65-1 1.96 3.93 7.710

Unknown #5 2.12 3.68 7.826

n-Octane 00111-65-9 0.80 3.17 2.527

c-2-Heptene 06443-92-1 2.12 2.95 6.277

Unknown #6 . 2.12 2.46 5.236

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.28 27.177

c-1,3-Dimethylcyclohexane 00638-04-0 2.12 2.19 4.662

t-3-Heptene 14686-14-7 6.17 2.10 12.978

Unknown #3 2.12 2.07 4.405

Unknown #16 2.12 1.87 3.977

Unknown #22 . 2.12 1.83 3.890

1-Heptene 00592-76-7 4.29 1.82 7.802

3,3-Dimethylhexane 00563-16-6 1.15 1.66 1.908

2,3,5-Trimethylhexane 01069-53-0 1.12 1.65 1.853

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.64 10.762

Ethylcyclohexane 01678-91-7 1.35 1.64 2.203

n-Nonane 00111-84-2 0.68 1.46 0.995

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.45 1.612

Methane 00074-82-8 0.01 1.33 0.018

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.33 11.117

Styrene 00100-42-5 1.66 1.24 2.052

Unknown #8 2.12 1.10 2.331

Isopropylbenzene (Cumene) 00098-82-8 2.12 1.02 2.170

continued
E-183

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - 86°F Static - Test 7644

Non Zero Mass Species Sorted By VOC

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.97 9.450

1-Nonene 00124-11-8 2.49 0.89 2.210

4-Methyloctane 02216-34-4 0.85 0.84 0.710

2,4-Dimethylheptane 02213-23-2 1.26 0.82 1.041

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.75 4.734

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.12 0.70 1.480

1,3-Butadiene 00106-99-0 12.45 0.64 7.994

Total 23556.0 50039.7 2.124

No MIR available, use weighted average of 2.1243

continued
E-184

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 13505.49 14544.237

2-Methylbutane (Isopentane) 00078-78-4 1.35 9713.77 13161.067

Cyclohexane 00110-82-7 1.14 2674.68 3042.085

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1448.55 2024.768

n-Hexane 00110-54-3 1.13 1252.04 1420.662

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1063.79 1275.612

3-Methylpentane 00096-14-0 1.69 954.60 1614.109

n-Pentane 00109-66-0 1.21 868.43 1055.084

2,3-Dimethylbutane 00079-29-8 0.90 836.00 751.307

2-Methyl-2-butene 00513-35-9 14.20 701.33 9955.338

Toluene 00108-88-3 3.93 683.32 2682.063

t-2-Pentene 00646-04-8 10.47 537.38 5628.248

Methylcyclopentane 00096-37-7 2.05 488.57 1001.463

2,3,4-Trimethylpentane 00565-75-3 0.95 364.02 345.394

2-Methyl-1-butene 00563-46-2 6.38 361.34 2304.852

2,4-Dimethylpentane 00108-08-7 1.46 300.42 438.410

c-2-Pentene 00627-20-3 10.28 294.44 3027.258

Benzene 00071-43-2 0.69 273.07 189.604

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 213.03 2493.441

2-Methylhexane 00591-76-4 1.09 208.43 226.182

2,3-Dimethylpentane 00565-59-3 1.25 203.30 253.786

t-2-Butene 00624-64-6 15.20 190.39 2893.522

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 183.66 586.061

c-2-Butene 00590-18-1 14.26 156.04 2225.116

2,2-Dimethylbutane 00075-83-2 1.11 149.97 166.643

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 138.21 732.285

t-2-Hexene 04050-45-7 8.55 134.27 1147.862

3-Methyl-t-2-pentene 00616-12-6 11.66 131.42 1532.305

2,4-Dimethylhexane 00589-43-5 1.61 117.92 189.323

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 115.00 184.612

2-Methyl-2-pentene 00625-27-4 11.03 102.46 1130.401

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 96.46 748.104

3-Methyl-c-2-pentene 00922-62-3 12.52 95.63 1197.103

Cyclopentene 00142-29-0 6.69 94.31 630.569

1-Methylcyclopentene 00693-89-0 12.45 93.50 1164.488

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 88.56 703.287

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 77.91 418.321

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 74.39 491.440

n-Heptane 00142-82-5 0.97 72.26 69.783

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 64.71 373.877

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 63.26 467.230

2,2,5-Trimethylhexane 03522-94-9 1.05 62.81 66.145

3-Methyl-1-butene 00563-45-1 6.85 59.58 408.389

Methylcyclohexane 00108-87-2 1.56 54.72 85.117

Vehicle 220b - Fuel 9 psi E0 - 105°F Static - Test 7647

Non Zero Mass Species Sorted By VOC
E-185

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - 105°F Static - Test 7647

Non Zero Mass Species Sorted By VOC

t-1,2-Dimethylcyclopentane 00822-50-4 2.20 46.75 102.786

2,2-Dimethylpentane 00590-35-2 1.04 40.75 42.504

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 39.42 173.207

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 36.88 40.280

c-1,3-Dimethylcyclopentane 02532-58-3 2.20 36.59 80.450

ortho-Xylene 00095-47-6 7.58 32.08 243.040

1,3,5-Trimethylbenzene 00108-67-8 11.75 29.47 346.410

4-Methyl-t-2-pentene 00674-76-0 8.04 25.95 208.593

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 25.34 140.416

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 24.99 195.770

2,2,3-Trimethylbutane 00464-06-2 1.05 24.02 25.321

1,2,3-Trimethylbenzene 00526-73-8 11.94 22.49 268.523

3,3-Dimethylpentane 00562-49-2 1.12 19.27 21.557

1-Methyl-3-Propylbenzene 01074-43-7 7.08 19.07 135.059

n-Propylbenzene 00103-65-1 1.96 16.55 32.438

Ethylbenzene 00100-41-4 2.96 15.85 46.961

Indan 00496-11-7 3.23 13.39 43.324

1,4-Diethylbenzene 00105-05-5 4.39 12.70 55.719

Unknown #16 2.20 12.53 27.550

2-Methylpropane 00075-28-5 1.18 10.60 12.475

1-Methyl-2-Propylbenzene 01074-17-5 5.43 9.83 53.430

c-2-Heptene 06443-92-1 7.08 9.35 66.163

Unknown #13 2.20 9.24 20.320

2-Methylheptane 00592-27-8 0.97 8.97 8.676

3-Methylheptane 00589-81-1 1.12 8.84 9.935

3,5-Dimethylheptane 00926-82-9 1.42 8.76 12.468

3,3-Dimethylhexane 00563-16-6 1.15 8.68 9.991

Isopropylbenzene (Cumene) 00098-82-8 2.20 8.01 17.611

2-Methyl-1,3-butadiene 00078-79-5 10.48 8.00 83.901

Unknown #1 2.20 7.25 15.930

1-Nonene 00124-11-8 2.49 6.52 16.256

t-3-Heptene 14686-14-7 6.17 6.48 39.994

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 6.32 41.394

2,3,5-Trimethylhexane 01069-53-0 1.12 6.29 7.051

Unknown #5 2.20 6.27 13.793

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 6.24 63.426

n-Octane 00111-65-9 0.80 5.90 4.700

Unknown #3 2.20 5.86 12.893

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.20 5.86 12.876

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 5.41 40.743

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 5.27 39.690

1-Heptene 00592-76-7 4.29 5.22 22.403

continued
E-186

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - 105°F Static - Test 7647

Non Zero Mass Species Sorted By VOC

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 5.15 19.898

n-Butylbenzene 00104-51-8 2.29 5.10 11.690

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 4.56 38.172

c-1,3-Dimethylcyclohexane 00638-04-0 2.20 4.19 9.209

1,3-Diethylbenzene 00141-93-5 7.08 3.88 27.462

4-Methyloctane 02216-34-4 0.85 3.84 3.258

sec-Butylbenzene 00135-98-8 2.29 3.69 8.447

t-2-Nonene 06434-78-2 2.20 3.69 8.103

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 3.47 26.167

Unknown #8 2.20 3.41 7.501

2,4-Dimethylheptane 02213-23-2 1.26 3.33 4.212

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.22 20.301

Isobutylbenzene 00538-93-2 2.20 3.16 6.942

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.15 12.028

3-Methyloctane 02216-33-3 0.88 3.08 2.722

t-4-Octene 14850-23-8 4.69 3.03 14.222

3-Ethyl-c-2-Pentene 00816-79-5 9.76 2.95 28.756

n-Nonane 00111-84-2 0.68 2.56 1.750

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.78 1.523

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.78 1.987

t-1,4-Dimethylcyclohexane 02207-04-7 2.20 1.36 3.000

Unknown #6 2.20 1.33 2.917

Total 40098.4 88163.2 2.199

No MIR available, use weighted average of 2.1987

continued
E-187

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 269.58 365.257

Cyclohexane 00110-82-7 1.14 260.03 295.753

Toluene 00108-88-3 3.93 257.58 1011.006

n-Butane 00106-97-8 1.08 243.42 262.141

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 149.78 179.600

n-Hexane 00110-54-3 1.13 95.00 107.789

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 88.81 124.131

2,3,4-Trimethylpentane 00565-75-3 0.95 66.17 62.789

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 64.02 343.730

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 63.74 494.302

3-Methylpentane 00096-14-0 1.69 63.57 107.495

2,3-Dimethylbutane 00079-29-8 0.90 47.93 43.072

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 45.43 199.609

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 44.81 330.946

Methylcyclopentane 00096-37-7 2.05 37.42 76.698

n-Pentane 00109-66-0 1.21 36.38 44.193

2,2,5-Trimethylhexane 03522-94-9 1.05 31.69 33.371

2,4-Dimethylpentane 00108-08-7 1.46 30.13 43.974

2-Methyl-2-butene 00513-35-9 14.20 27.27 387.108

Benzene 00071-43-2 0.69 27.23 18.910

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 25.76 82.203

2-Methylhexane 00591-76-4 1.09 25.42 27.584

2,3-Dimethylpentane 00565-59-3 1.25 23.79 29.697

1,3,5-Trimethylbenzene 00108-67-8 11.75 22.93 269.521

t-2-Pentene 00646-04-8 10.47 21.86 228.949

2,4-Dimethylhexane 00589-43-5 1.61 20.69 33.226

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 20.23 32.484

n-Heptane 00142-82-5 0.97 17.15 16.560

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 15.59 86.382

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 15.37 81.438

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 14.53 15.864

2-Methyl-1-butene 00563-46-2 6.38 14.15 90.287

c-2-Pentene 00627-20-3 10.28 13.59 139.745

n-Propylbenzene 00103-65-1 1.96 13.50 26.459

ortho-Xylene 00095-47-6 7.58 13.49 102.226

2,3,5-Trimethylhexane 01069-53-0 1.12 11.40 12.776

Unknown #16 2.79 10.86 30.361

3-Methyl-t-2-pentene 00616-12-6 11.66 10.58 123.391

t-2-Hexene 04050-45-7 8.55 10.58 90.470

t-1,2-Dimethylcyclopentane 00822-50-4 2.79 8.58 23.992

Ethylbenzene 00100-41-4 2.96 8.30 24.591

1,2,3-Trimethylbenzene 00526-73-8 11.94 8.25 98.453

3-Methylheptane 00589-81-1 1.12 8.11 9.123

2,2-Dimethylbutane 00075-83-2 1.11 8.02 8.911

Vehicle 220b - Fuel 9 psi E0 - Dynamic - Test 25789

Non Zero Mass Species Sorted By VOC
E-188

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - Dynamic - Test 25789

Non Zero Mass Species Sorted By VOC

1-Methylcyclopentene 00693-89-0 12.45 7.71 96.014

2-Methyl-2-pentene 00625-27-4 11.03 6.97 76.909

c-1,3-Dimethylcyclopentane 02532-58-3 2.79 6.85 19.131

Methylcyclohexane 00108-87-2 1.56 6.78 10.541

3-Methyl-c-2-pentene 00922-62-3 12.52 6.59 82.532

Cyclopentene 00142-29-0 6.69 6.52 43.578

2,2-Dimethylpentane 00590-35-2 1.04 6.13 6.393

n-Octane 00111-65-9 0.80 5.67 4.516

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 5.34 62.538

2-Methylheptane 00592-27-8 0.97 4.84 4.683

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.54 29.964

Total 2380.7 6653.4 2.795

No MIR available, use weighted average of 2.7947

continued
E-189

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Cyclohexane 00110-82-7 1.14 2643.58 3006.714

2-Methylbutane (Isopentane) 00078-78-4 1.35 2560.63 3469.363

Toluene 00108-88-3 3.93 1916.57 7522.592

n-Butane 00106-97-8 1.08 1875.86 2020.143

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1562.98 1874.200

n-Hexane 00110-54-3 1.13 980.68 1112.754

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 910.28 1272.376

3-Methylpentane 00096-14-0 1.69 648.42 1096.390

2,3,4-Trimethylpentane 00565-75-3 0.95 639.78 607.049

2,3-Dimethylbutane 00079-29-8 0.90 481.07 432.339

Methylcyclopentane 00096-37-7 2.05 403.11 826.281

2,4-Dimethylpentane 00108-08-7 1.46 307.60 448.886

n-Pentane 00109-66-0 1.21 285.38 346.713

2,2,5-Trimethylhexane 03522-94-9 1.05 264.19 278.202

2-Methyl-2-butene 00513-35-9 14.20 259.61 3685.166

2,4-Dimethylhexane 00589-43-5 1.61 259.46 416.578

2,3-Dimethylpentane 00565-59-3 1.25 250.68 312.927

2-Methylhexane 00591-76-4 1.09 249.85 271.132

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 230.04 1784.097

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 227.46 725.803

Benzene 00071-43-2 0.69 216.35 150.224

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 190.62 306.007

t-2-Pentene 00646-04-8 10.47 186.84 1956.837

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 139.34 152.175

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 134.72 723.366

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 116.89 863.338

2-Methyl-1-butene 00563-46-2 6.38 108.96 695.021

c-2-Pentene 00627-20-3 10.28 102.93 1058.279

n-Heptane 00142-82-5 0.97 102.71 99.194

t-2-Hexene 04050-45-7 8.55 102.09 872.758

3-Methyl-t-2-pentene 00616-12-6 11.66 100.99 1177.529

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 91.64 485.539

3-Methyl-c-2-pentene 00922-62-3 12.52 79.20 991.387

1-Methylcyclopentene 00693-89-0 12.45 78.94 983.143

2-Methyl-2-pentene 00625-27-4 11.03 76.89 848.310

ortho-Xylene 00095-47-6 7.58 71.30 540.145

2,2-Dimethylbutane 00075-83-2 1.11 70.51 78.350

Methylcyclohexane 00108-87-2 1.56 68.87 107.119

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 61.04 714.439

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 59.85 395.408

t-1,2-Dimethylcyclopentane 00822-50-4 2.43 57.32 139.397

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 55.08 242.007

1,3,5-Trimethylbenzene 00108-67-8 11.75 53.20 625.384

Ethylbenzene 00100-41-4 2.96 46.59 138.042

Vehicle 220b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7657

Non Zero Mass Species Sorted By VOC
E-190

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7657

Non Zero Mass Species Sorted By VOC

3-Methylheptane 00589-81-1 1.12 45.74 51.435

c-1,3-Dimethylcyclopentane 02532-58-3 2.43 43.12 104.879

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 42.72 236.717

2,2-Dimethylpentane 00590-35-2 1.04 41.75 43.552

Cyclopentene 00142-29-0 6.69 40.07 267.923

2-Methylheptane 00592-27-8 0.97 37.77 36.528

2,3,5-Trimethylhexane 01069-53-0 1.12 36.96 41.403

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 32.03 185.086

n-Propylbenzene 00103-65-1 1.96 31.02 60.784

Unknown #16 2.43 30.74 74.756

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 27.90 218.631

Unknown #5 2.43 27.82 67.658

2,2,3-Trimethylbutane 00464-06-2 1.05 27.03 28.489

c-2-Butene 00590-18-1 14.26 25.69 366.299

Unknown #13 2.43 25.22 61.328

n-Octane 00111-65-9 0.80 24.50 19.510

3,5-Dimethylheptane 00926-82-9 1.42 21.65 30.814

1-Methyl-3-Propylbenzene 01074-43-7 7.08 21.10 149.450

3,3-Dimethylpentane 00562-49-2 1.12 19.22 21.501

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 19.13 84.333

1-Nonene 00124-11-8 2.49 18.27 45.552

Isopropylbenzene (Cumene) 00098-82-8 2.43 16.68 40.569

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 15.26 58.935

c-1,3-Dimethylcyclohexane 00638-04-0 2.43 13.16 32.011

1-Methyl-2-Propylbenzene 01074-17-5 5.43 12.74 69.217

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 12.63 100.326

4-Methyl-t-2-pentene 00674-76-0 8.04 11.84 95.172

c-2-Heptene 06443-92-1 7.08 11.62 82.195

4-Methyloctane 02216-34-4 0.85 10.95 9.285

3,3-Dimethylhexane 00563-16-6 1.15 10.20 11.750

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 10.07 63.469

1,4-Diethylbenzene 00105-05-5 4.39 10.01 43.930

Unknown #8 2.43 9.65 23.458

t-2-Nonene 06434-78-2 2.43 9.55 23.237

Indan 00496-11-7 3.23 9.50 30.729

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 9.20 7.857

3-Methyloctane 02216-33-3 0.88 8.89 7.868

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.43 8.64 21.015

t-3-Heptene 14686-14-7 6.17 7.93 48.926

1,1-Dimethylcyclohexane 00590-66-9 1.12 7.74 8.626

2,4-Dimethylheptane 02213-23-2 1.26 7.68 9.718

3-Methylnonane 2.43 7.56 18.381

continued
E-191

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7657

Non Zero Mass Species Sorted By VOC

t-4-Octene 14850-23-8 4.69 7.39 34.647

n-Decane 00124-18-5 0.59 7.29 4.307

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 6.96 45.553

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 6.05 45.571

1-Heptene 00592-76-7 4.29 5.78 24.769

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 5.77 58.588

n-Nonane 00111-84-2 0.68 5.71 3.898

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 5.47 6.476

Unknown #3 2.43 5.30 12.892

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 5.12 42.865

Unknown #6 . 2.43 4.96 12.074

t-1,4-Dimethylcyclohexane 02207-04-7 2.43 4.39 10.680

Unknown #9 2.43 4.36 10.594

sec-Butylbenzene 00135-98-8 2.29 4.19 9.596

1,3-Diethylbenzene 00141-93-5 7.08 3.76 26.645

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 3.65 27.512

Unknown #12 2.43 3.45 8.398

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.30 12.617

3-Ethyl-c-2-Pentene 00816-79-5 9.76 3.22 31.463

Unknown #10 2.43 2.87 6.971

Unknown #1 2.43 2.77 6.747

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 2.66 20.040

Isobutylbenzene 00538-93-2 2.43 2.58 6.284

Unknown #14 2.43 2.47 6.000

c-1,2-Dimethylcyclohexane 02207-01-4 2.43 2.40 5.836

2-Methyl-1,3-butadiene 00078-79-5 10.48 2.40 25.140

c-2-Octene 07642-04-8 2.43 2.30 5.606

Unknown #4 2.43 2.18 5.291

1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 2.03 18.779

n-Undecane 01120-21-4 0.52 1.98 1.033

Unknown #15 2.43 1.77 4.294

Unknown #7 2.43 1.60 3.895

2,2-Dimethyloctane 15869-87-1 0.76 1.48 1.119

Unknown #11 2.43 1.41 3.435

c- & t-4-Nonene 02198-23-4 4.42 1.38 6.097

Naphthalene 00091-20-3 3.28 1.26 4.141

1,2-Diethylbenzene 00135-01-3 5.43 1.20 6.530

t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 0.82 4.831

Unknown #18 2.43 0.79 1.918

1-Undecene 00821-95-4 1.77 0.72 1.281

Unknown #17 2.43 0.71 1.726

Unknown #20 2.43 0.49 1.187

1,3-Butadiene 00106-99-0 12.45 0.42 5.224

Total 20327.8 49439.0 2.432

No MIR available, use weighted average of 2.4321

continued
E-192

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 4755.33 6442.941

n-Butane 00106-97-8 1.08 2804.48 3020.183

Cyclohexane 00110-82-7 1.14 947.18 1077.287

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 621.17 868.257

n-Hexane 00110-54-3 1.13 484.59 549.854

n-Pentane 00109-66-0 1.21 410.06 498.199

3-Methylpentane 00096-14-0 1.69 387.85 655.811

Toluene 00108-88-3 3.93 372.27 1461.151

2,3-Dimethylbutane 00079-29-8 0.90 355.33 319.334

2-Methyl-2-butene 00513-35-9 14.20 324.01 4599.304

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 301.05 360.994

t-2-Pentene 00646-04-8 10.47 250.71 2625.789

Methylcyclopentane 00096-37-7 2.05 184.42 378.029

2-Methyl-1-butene 00563-46-2 6.38 171.45 1093.593

c-2-Pentene 00627-20-3 10.28 136.37 1402.106

Benzene 00071-43-2 0.69 106.54 73.980

2,4-Dimethylpentane 00108-08-7 1.46 106.52 155.451

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 100.97 1181.827

t-2-Butene 00624-64-6 15.20 100.03 1520.254

2-Methylpropane 00075-28-5 1.18 85.84 101.004

2,3,4-Trimethylpentane 00565-75-3 0.95 85.48 81.106

c-2-Butene 00590-18-1 14.26 80.09 1142.038

2,2-Dimethylbutane 00075-83-2 1.11 67.79 75.333

2,3-Dimethylpentane 00565-59-3 1.25 64.83 80.930

2-Methylhexane 00591-76-4 1.09 63.09 68.467

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 55.59 177.379

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 55.45 293.784

t-2-Hexene 04050-45-7 8.55 51.07 436.554

3-Methyl-t-2-pentene 00616-12-6 11.66 50.32 586.652

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 48.47 384.874

Cyclopentene 00142-29-0 6.69 41.68 278.641

2-Methyl-2-pentene 00625-27-4 11.03 39.73 438.373

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 38.65 299.777

2,4-Dimethylhexane 00589-43-5 1.61 38.17 61.289

3-Methyl-c-2-pentene 00922-62-3 12.52 35.89 449.291

1-Methylcyclopentene 00693-89-0 12.45 31.28 389.566

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 29.72 196.364

3-Methyl-1-butene 00563-45-1 6.85 29.26 200.602

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 27.02 43.375

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 25.91 149.689

2,2,5-Trimethylhexane 03522-94-9 1.05 25.85 27.217

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 23.67 127.097

n-Heptane 00142-82-5 0.97 20.24 19.545

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 19.56 144.444

Vehicle 220b - Fuel 7 psi E0 - 86°F Static - Test 7677

Non Zero Mass Species Sorted By VOC
E-193

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 86°F Static - Test 7677

Non Zero Mass Species Sorted By VOC

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 18.02 19.684

2,2-Dimethylpentane 00590-35-2 1.04 15.21 15.867

t-1,2-Dimethylcyclopentane 00822-50-4 2.47 14.33 35.462

Methylcyclohexane 00108-87-2 1.56 13.88 21.584

Propane 00074-98-6 0.46 12.18 5.566

ortho-Xylene 00095-47-6 7.58 11.75 89.001

c-1,3-Dimethylcyclopentane 02532-58-3 2.47 11.09 27.448

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.96 48.171

2,2,3-Trimethylbutane 00464-06-2 1.05 9.83 10.358

1,3,5-Trimethylbenzene 00108-67-8 11.75 8.91 104.686

Ethylbenzene 00100-41-4 2.96 7.71 22.846

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 6.71 37.180

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 6.23 48.793

3,3-Dimethylpentane 00562-49-2 1.12 5.94 6.647

n-Propylbenzene 00103-65-1 1.96 5.02 9.845

3-Methylheptane 00589-81-1 1.12 4.75 5.346

2-Methylheptane 00592-27-8 0.97 4.75 4.593

Unknown #1 2.47 3.83 9.486

2,3,5-Trimethylhexane 01069-53-0 1.12 3.78 4.230

Unknown #5 2.47 3.68 9.114

1,2,3-Trimethylbenzene 00526-73-8 11.94 3.44 41.119

2-Methyl-1,3-butadiene 00078-79-5 10.48 3.43 35.917

1-Methyl-3-Propylbenzene 01074-43-7 7.08 3.22 22.771

c-2-Heptene 06443-92-1 7.08 3.08 21.773

1,4-Diethylbenzene 00105-05-5 4.39 2.93 12.842

Unknown #16 2.47 2.84 7.037

1-Methyl-2-Propylbenzene 01074-17-5 5.43 2.74 14.882

n-Octane 00111-65-9 0.80 2.45 1.953

Unknown #13 2.47 2.19 5.412

c-1,3-Dimethylcyclohexane 00638-04-0 2.47 1.97 4.879

3,5-Dimethylheptane 00926-82-9 1.42 1.89 2.696

t-3-Heptene 14686-14-7 6.17 1.77 10.938

Indan 00496-11-7 3.23 1.76 5.679

Isopropylbenzene (Cumene) 00098-82-8 2.47 1.62 4.011

3,3-Dimethylhexane 00563-16-6 1.15 1.60 1.839

1-Nonene 00124-11-8 2.49 1.50 3.745

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.50 9.792

Unknown #3 2.47 1.34 3.307

n-Decane 00124-18-5 0.59 1.33 0.785

1-Heptene 00592-76-7 4.29 1.30 5.592

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 1.26 9.470

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 1.26 12.762

continued
E-194

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 86°F Static - Test 7677

Non Zero Mass Species Sorted By VOC

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.23 9.243

4-Methyloctane 02216-34-4 0.85 1.13 0.955

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.08 6.796

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.05 8.796

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.02 0.872

2,4-Dimethylheptane 02213-23-2 1.26 0.92 1.164

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.92 1.023

3-Methyloctane 02216-33-3 0.88 0.89 0.789

t-2-Nonene 06434-78-2 2.47 0.86 2.129

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.47 0.83 2.066

1,2-Diethylbenzene 00135-01-3 5.43 0.77 4.211

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.76 7.439

sec-Butylbenzene 00135-98-8 2.29 0.75 1.712

t-4-Octene 14850-23-8 4.69 0.75 3.499

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.71 5.387

Isobutylbenzene 00538-93-2 2.47 0.71 1.750

t-1,4-Dimethylcyclohexane 02207-04-7 2.47 0.68 1.685

Unknown #8 2.47 0.67 1.656

3-Methylnonane 2.47 0.61 1.522

Unknown #6 . 2.47 0.60 1.495

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.59 0.698

n-Nonane 00111-84-2 0.68 0.58 0.394

1,3-Butadiene 00106-99-0 12.45 0.48 5.925

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.44 1.689

1,3-Diethylbenzene 00141-93-5 7.08 0.40 2.835

Unknown #4 2.47 0.20 0.503

1-Butyne 00107-00-6 6.05 0.15 0.893

n-Undecane 01120-21-4 0.52 0.01 0.004

Total 14299.8 35390.0 2.475

No MIR available, use weighted average of 2.4749

continued
E-195

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 8764.59 11875.037

n-Butane 00106-97-8 1.08 4859.64 5233.408

Cyclohexane 00110-82-7 1.14 2002.13 2277.155

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1243.11 1737.602

n-Hexane 00110-54-3 1.13 1001.50 1136.376

Toluene 00108-88-3 3.93 856.61 3362.204

3-Methylpentane 00096-14-0 1.69 784.45 1326.408

n-Pentane 00109-66-0 1.21 777.45 944.548

2,3-Dimethylbutane 00079-29-8 0.90 701.05 630.032

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 669.74 803.101

2-Methyl-2-butene 00513-35-9 14.20 622.22 8832.412

t-2-Pentene 00646-04-8 10.47 478.46 5011.111

Methylcyclopentane 00096-37-7 2.05 380.82 780.590

2-Methyl-1-butene 00563-46-2 6.38 321.47 2050.481

c-2-Pentene 00627-20-3 10.28 259.21 2665.056

2,4-Dimethylpentane 00108-08-7 1.46 223.75 326.528

Benzene 00071-43-2 0.69 222.99 154.832

2,3,4-Trimethylpentane 00565-75-3 0.95 197.80 187.675

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 182.54 2136.613

t-2-Butene 00624-64-6 15.20 173.16 2631.622

2-Methylpropane 00075-28-5 1.18 145.88 171.641

c-2-Butene 00590-18-1 14.26 140.52 2003.758

2,3-Dimethylpentane 00565-59-3 1.25 139.41 174.023

2-Methylhexane 00591-76-4 1.09 136.67 148.308

2,2-Dimethylbutane 00075-83-2 1.11 130.26 144.744

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 121.08 386.346

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 111.34 589.945

t-2-Hexene 04050-45-7 8.55 104.95 897.210

3-Methyl-t-2-pentene 00616-12-6 11.66 103.39 1205.434

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 88.68 687.753

2,4-Dimethylhexane 00589-43-5 1.61 87.44 140.389

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 82.16 652.441

2-Methyl-2-pentene 00625-27-4 11.03 81.05 894.128

Cyclopentene 00142-29-0 6.69 80.05 535.205

3-Methyl-c-2-pentene 00922-62-3 12.52 74.65 934.484

1-Methylcyclopentene 00693-89-0 12.45 64.97 809.151

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 62.40 100.167

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 60.71 401.110

2,2,5-Trimethylhexane 03522-94-9 1.05 60.21 63.401

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 53.31 286.254

3-Methyl-1-butene 00563-45-1 6.85 52.13 357.334

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 49.14 283.915

n-Heptane 00142-82-5 0.97 46.07 44.496

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 41.17 44.963

Vehicle 220b - Fuel 7 psi E0 - 105°F Static - Test 7680

Non Zero Mass Species Sorted By VOC
E-196

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 105°F Static - Test 7680

Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 34.81 257.119

2,2-Dimethylpentane 00590-35-2 1.04 31.12 32.463

2,2-DiMeHexane 00590-73-8 0.94 30.50 28.708

t-1,2-Dimethylcyclopentane 00822-50-4 2.49 30.41 75.650

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 25.50 112.051

ortho-Xylene 00095-47-6 7.58 25.49 193.083

c-1,3-Dimethylcyclopentane 02532-58-3 2.49 24.11 59.989

2,2,3-Trimethylbutane 00464-06-2 1.05 19.96 21.034

1,3,5-Trimethylbenzene 00108-67-8 11.75 18.93 222.525

Ethylbenzene 00100-41-4 2.96 18.75 55.552

Propane 00074-98-6 0.46 17.08 7.807

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 15.81 87.588

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 13.54 106.125

3,3-Dimethylpentane 00562-49-2 1.12 12.18 13.631

3-Methylheptane 00589-81-1 1.12 11.62 13.065

n-Propylbenzene 00103-65-1 1.96 11.09 21.728

2-Methylheptane 00592-27-8 0.97 10.73 10.378

2,3,5-Trimethylhexane 01069-53-0 1.12 8.22 9.211

1,2,3-Trimethylbenzene 00526-73-8 11.94 8.12 96.945

Unknown #5 2.49 7.44 18.522

1-Methyl-3-Propylbenzene 01074-43-7 7.08 6.90 48.873

Unknown #16 2.49 6.77 16.834

Unknown #1 2.49 6.51 16.201

c-2-Heptene 06443-92-1 7.08 6.38 45.146

2-Methyl-1,3-butadiene 00078-79-5 10.48 5.97 62.552

n-Octane 00111-65-9 0.80 5.77 4.594

Indan 00496-11-7 3.23 4.77 15.423

3,5-Dimethylheptane 00926-82-9 1.42 4.70 6.691

Unknown #13 2.49 4.20 10.457

Isopropylbenzene (Cumene) 00098-82-8 2.49 4.09 10.165

1,4-Diethylbenzene 00105-05-5 4.39 4.01 17.618

t-3-Heptene 14686-14-7 6.17 3.92 24.203

3,3-Dimethylhexane 00563-16-6 1.15 3.34 3.850

1-Methyl-2-Propylbenzene 01074-17-5 5.43 3.21 17.438

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 3.20 20.966

1-Nonene 00124-11-8 2.49 2.97 7.402

c-1,3-Dimethylcyclohexane 00638-04-0 2.49 2.91 7.235

1-Heptene 00592-76-7 4.29 2.89 12.404

Unknown #3 2.49 2.77 6.884

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 2.54 2.165

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.49 2.47 6.155

Unknown #6 . 2.49 2.46 6.112

continued
E-197

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 105°F Static - Test 7680

Non Zero Mass Species Sorted By VOC

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 2.28 19.076

4-Methyloctane 02216-34-4 0.85 2.02 1.718

3-Methyloctane 02216-33-3 0.88 1.95 1.728

1,1-Dimethylcyclohexane 00590-66-9 1.12 1.91 2.134

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 1.88 19.101

2,4-Dimethylheptane 02213-23-2 1.26 1.79 2.268

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.70 12.806

Unknown #8 2.49 1.67 4.151

n-Decane 00124-18-5 0.59 1.62 0.959

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.60 6.123

sec-Butylbenzene 00135-98-8 2.29 1.54 3.525

3-Methylnonane 2.49 1.53 3.819

3-Ethyl-c-2-Pentene 00816-79-5 9.76 1.52 14.836

t-2-Nonene 06434-78-2 2.49 1.48 3.680

1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 1.35 12.506

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.31 8.240

t-1,4-Dimethylcyclohexane 02207-04-7 2.49 1.25 3.099

Isobutylbenzene 00538-93-2 2.49 1.12 2.787

n-Nonane 00111-84-2 0.68 1.09 0.745

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 1.02 7.716

1,3-Butadiene 00106-99-0 12.45 0.98 12.253

1,3-Diethylbenzene 00141-93-5 7.08 0.84 5.927

c-1,2-Dimethylcyclohexane 02207-01-4 2.49 0.82 2.033

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 0.80 0.947

Unknown #9 2.49 0.80 1.990

1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.67 6.186

c-2-Octene 07642-04-8 2.49 0.66 1.635

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.62 2.753

Unknown #12 2.49 0.49 1.207

Unknown #4 2.49 0.42 1.044

n-Butylbenzene 00104-51-8 2.29 0.36 0.815

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.28 2.080

n-Undecane 01120-21-4 0.52 0.25 0.132

2,2-Dimethyloctane 15869-87-1 0.76 0.20 0.148

Total 27348.3 68042.1 2.488

No MIR available, use weighted average of 2.4880

continued
E-198

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Cyclohexane 00110-82-7 1.14 385.12 438.025

2-Methylbutane (Isopentane) 00078-78-4 1.35 371.97 503.974

Toluene 00108-88-3 3.93 351.94 1381.382

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 199.68 1072.127

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 196.81 235.994

n-Butane 00106-97-8 1.08 143.43 154.461

n-Hexane 00110-54-3 1.13 122.85 139.394

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 114.17 159.587

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 106.45 825.559

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 94.05 694.666

2,3,4-Trimethylpentane 00565-75-3 0.95 88.91 84.360

3-Methylpentane 00096-14-0 1.69 80.49 136.094

1,3,5-Trimethylbenzene 00108-67-8 11.75 68.09 800.358

2,3-Dimethylbutane 00079-29-8 0.90 65.49 58.855

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 58.20 255.720

Methylcyclopentane 00096-37-7 2.05 51.19 104.920

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 44.35 245.761

2,4-Dimethylhexane 00589-43-5 1.61 42.97 68.998

n-Pentane 00109-66-0 1.21 41.09 49.916

2,2,5-Trimethylhexane 03522-94-9 1.05 40.84 43.009

ortho-Xylene 00095-47-6 7.58 38.61 292.515

2,4-Dimethylpentane 00108-08-7 1.46 37.61 54.882

1,2,3-Trimethylbenzene 00526-73-8 11.94 37.49 447.540

2-Methyl-2-butene 00513-35-9 14.20 36.06 511.918

Benzene 00071-43-2 0.69 34.66 24.065

2-Methylhexane 00591-76-4 1.09 33.50 36.352

2,3-Dimethylpentane 00565-59-3 1.25 32.54 40.619

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 32.38 103.320

1-Methyl-3-Propylbenzene 01074-43-7 7.08 32.04 226.874

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 31.29 50.239

n-Propylbenzene 00103-65-1 1.96 29.23 57.280

Ethylbenzene 00100-41-4 2.96 28.70 85.018

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 25.25 27.573

t-2-Pentene 00646-04-8 10.47 23.93 250.683

Unknown #16 3.47 22.78 78.988

Indan 00496-11-7 3.23 22.56 72.974

1-Methyl-2-Propylbenzene 01074-17-5 5.43 22.10 120.098

n-Heptane 00142-82-5 0.97 18.55 17.912

c-2-Pentene 00627-20-3 10.28 18.19 187.043

2-Methyl-1-butene 00563-46-2 6.38 16.70 106.517

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 16.17 121.897

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 16.08 163.373

t-2-Hexene 04050-45-7 8.55 15.50 132.535

3-Methyl-t-2-pentene 00616-12-6 11.66 15.37 179.197

Vehicle 220b - Fuel 7 psi E0 - Dynamic - Test 25794

Non Zero Mass Species Sorted By VOC
E-199

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - Dynamic - Test 25794

Non Zero Mass Species Sorted By VOC

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 14.81 78.469

1,4-Diethylbenzene 00105-05-5 4.39 13.00 57.054

3-Methyl-c-2-pentene 00922-62-3 12.52 12.48 156.261

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 12.47 145.965

n-Decane 00124-18-5 0.59 12.41 7.332

2-Methyl-2-pentene 00625-27-4 11.03 12.19 134.512

2,2-DiMeHexane 00590-73-8 0.94 11.86 11.162

t-2-Butene 00624-64-6 15.20 11.05 167.884

1-Methylcyclopentene 00693-89-0 12.45 10.90 135.760

2,2-Dimethylbutane 00075-83-2 1.11 10.89 12.096

4-Methyl-t-2-pentene 00674-76-0 8.04 9.93 79.853

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 9.87 65.180

t-1,2-Dimethylcyclopentane 00822-50-4 3.47 9.69 33.596

c-2-Butene 00590-18-1 14.26 9.46 134.928

3-Methylheptane 00589-81-1 1.12 8.28 9.305

2,3,5-Trimethylhexane 01069-53-0 1.12 8.00 8.961

n-Octane 00111-65-9 0.80 7.83 6.234

c-1,3-Dimethylcyclopentane 02532-58-3 3.47 7.27 25.206

Cyclopentene 00142-29-0 6.69 7.19 48.040

Isopropylbenzene (Cumene) 00098-82-8 3.47 6.98 24.183

1,3-Diethylbenzene 00141-93-5 7.08 6.82 48.287

3-Methylnonane 3.47 6.78 23.518

2-Methylheptane 00592-27-8 0.97 6.75 6.526

Styrene 00100-42-5 1.66 6.21 10.321

2,2-Dimethylpentane 00590-35-2 1.04 6.03 6.288

n-Nonane 00111-84-2 0.68 5.92 4.042

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 5.74 33.179

2-Methylpropane 00075-28-5 1.18 5.64 6.634

Unknown #18 3.47 5.58 19.333

n-Butylbenzene 00104-51-8 2.29 5.31 12.170

sec-Butylbenzene 00135-98-8 2.29 5.20 11.924

1-Undecene 00821-95-4 1.77 5.03 8.924

Unknown #5 3.47 4.97 17.215

Ethylcyclohexane 01678-91-7 1.35 4.90 6.587

2,2,3-Trimethylbutane 00464-06-2 1.05 4.75 5.006

1-Nonene 00124-11-8 2.49 4.66 11.605

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 4.65 17.766

c-2-Heptene 06443-92-1 7.08 4.63 32.729

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.21 32.961

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.15 32.941

Unknown #24 3.47 4.11 14.244

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 3.96 17.442

continued
E-200

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - Dynamic - Test 25794

Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 3.70 1.930

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 3.58 26.990

4-Methyloctane 02216-34-4 0.85 3.58 3.034

3-Methyl-1-butene 00563-45-1 6.85 3.49 23.934

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 3.43 25.884

Unknown #6 . 3.47 3.30 11.450

Naphthalene 00091-20-3 3.28 3.24 10.638

c-1,3-Dimethylcyclohexane 00638-04-0 3.47 3.12 10.809

3,3-Dimethylpentane 00562-49-2 1.12 3.01 3.372

Isobutylbenzene 00538-93-2 3.47 2.99 10.375

1,1-Dimethylcyclohexane 00590-66-9 1.12 2.47 2.756

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.47 2.47 8.568

3,3-Dimethylhexane 00563-16-6 1.15 2.40 2.762

3-Methyloctane 02216-33-3 0.88 2.35 2.081

1,2-Diethylbenzene 00135-01-3 5.43 2.08 11.324

1-Heptene 00592-76-7 4.29 1.78 7.649

2,4-Dimethylheptane 02213-23-2 1.26 1.78 2.255

Unknown #8 3.47 1.73 6.005

Unknown #20 3.47 1.56 5.393

t-3-Heptene 14686-14-7 6.17 1.52 9.377

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 1.39 1.646

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.30 1.107

2-Methyl-1,3-butadiene 00078-79-5 10.48 1.25 13.100

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.23 8.072

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.01 6.385

t-1,4-Dimethylcyclohexane 02207-04-7 3.47 0.92 3.203

Unknown #1 3.47 0.69 2.389

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.66 5.535

Total 3689.9 12792.2 3.467

No MIR available, use weighted average of 3.4668

continued
E-201

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Cyclohexane 00110-82-7 1.14 2781.83 3163.949

2-Methylbutane (Isopentane) 00078-78-4 1.35 2708.35 3669.503

Toluene 00108-88-3 3.93 2047.86 8037.885

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1622.66 1945.756

n-Hexane 00110-54-3 1.13 1029.43 1168.072

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 964.70 1348.439

n-Butane 00106-97-8 1.08 687.61 740.501

3-Methylpentane 00096-14-0 1.69 678.06 1146.507

2,3,4-Trimethylpentane 00565-75-3 0.95 675.28 640.725

2,3-Dimethylbutane 00079-29-8 0.90 502.21 451.336

Methylcyclopentane 00096-37-7 2.05 424.33 869.782

2,4-Dimethylpentane 00108-08-7 1.46 319.31 465.972

n-Pentane 00109-66-0 1.21 308.39 374.676

2,2,5-Trimethylhexane 03522-94-9 1.05 281.46 296.395

2-Methyl-2-butene 00513-35-9 14.20 277.04 3932.600

2,4-Dimethylhexane 00589-43-5 1.61 273.19 438.626

2-Methylhexane 00591-76-4 1.09 262.79 285.175

2,3-Dimethylpentane 00565-59-3 1.25 261.52 326.467

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 251.66 1951.697

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 239.29 763.565

Benzene 00071-43-2 0.69 230.34 159.937

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 200.68 322.163

t-2-Pentene 00646-04-8 10.47 197.73 2070.893

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 147.98 161.607

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 137.12 736.236

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 129.98 960.035

2-Methyl-1-butene 00563-46-2 6.38 115.39 736.039

n-Heptane 00142-82-5 0.97 114.06 110.154

c-2-Pentene 00627-20-3 10.28 108.89 1119.567

t-2-Hexene 04050-45-7 8.55 106.56 910.942

3-Methyl-t-2-pentene 00616-12-6 11.66 105.14 1225.831

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 99.40 526.683

2,2-DiMeHexane 00590-73-8 0.94 87.94 82.771

3-Methyl-c-2-pentene 00922-62-3 12.52 83.41 1044.084

1-Methylcyclopentene 00693-89-0 12.45 83.19 1036.094

2-Methyl-2-pentene 00625-27-4 11.03 80.28 885.656

ortho-Xylene 00095-47-6 7.58 77.18 584.743

2,2-Dimethylbutane 00075-83-2 1.11 73.59 81.769

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 64.94 760.100

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 62.64 413.807

t-1,2-Dimethylcyclopentane 00822-50-4 2.55 60.49 154.069

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 56.51 248.325

1,3,5-Trimethylbenzene 00108-67-8 11.75 55.08 647.405

Ethylbenzene 00100-41-4 2.96 51.55 152.738

Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686

Non Zero Mass Species Sorted By VOC
E-202

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686

Non Zero Mass Species Sorted By VOC

3-Methylheptane 00589-81-1 1.12 48.91 54.991

c-1,3-Dimethylcyclopentane 02532-58-3 2.55 45.86 116.797

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 44.77 248.123

2,2-Dimethylpentane 00590-35-2 1.04 43.43 45.301

Cyclopentene 00142-29-0 6.69 42.07 281.299

2-Methylheptane 00592-27-8 0.97 40.88 39.541

2,3,5-Trimethylhexane 01069-53-0 1.12 40.14 44.962

Unknown #16 2.55 34.81 88.655

n-Propylbenzene 00103-65-1 1.96 33.47 65.583

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 33.27 192.238

t-2-Butene 00624-64-6 15.20 31.11 472.786

Unknown #5 2.55 29.42 74.943

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 29.27 229.309

2,2,3-Trimethylbutane 00464-06-2 1.05 28.28 29.804

Unknown #13 2.55 28.17 71.750

n-Octane 00111-65-9 0.80 28.05 22.333

c-2-Butene 00590-18-1 14.26 27.58 393.341

1-Methyl-3-Propylbenzene 01074-43-7 7.08 24.60 174.232

3,5-Dimethylheptane 00926-82-9 1.42 24.30 34.589

3,3-Dimethylpentane 00562-49-2 1.12 20.27 22.673

1-Nonene 00124-11-8 2.49 20.25 50.466

2-Methylpropane 00075-28-5 1.18 19.01 22.371

1,2,3-Trimethylbenzene 00526-73-8 11.94 18.87 225.237

Isopropylbenzene (Cumene) 00098-82-8 2.55 18.22 46.403

c-1,3-Dimethylcyclohexane 00638-04-0 2.55 14.49 36.919

3-Methyl-1-butene 00563-45-1 6.85 13.74 94.204

Unknown #6 . 2.55 13.55 34.503

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 13.24 105.107

4-Methyloctane 02216-34-4 0.85 12.88 10.923

c-2-Heptene 06443-92-1 7.08 12.32 87.155

1-Methyl-2-Propylbenzene 01074-17-5 5.43 11.92 64.785

Indan 00496-11-7 3.23 11.45 37.045

3-Methyloctane 02216-33-3 0.88 10.81 9.566

t-2-Nonene 06434-78-2 2.55 10.74 27.343

3,3-Dimethylhexane 00563-16-6 1.15 10.69 12.307

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 10.53 8.989

1,4-Diethylbenzene 00105-05-5 4.39 10.45 45.863

Unknown #8 2.55 9.67 24.617

n-Decane 00124-18-5 0.59 9.58 5.660

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.55 9.31 23.719

2,4-Dimethylheptane 02213-23-2 1.26 8.65 10.938

1,1-Dimethylcyclohexane 00590-66-9 1.12 8.60 9.584

continued
E-203

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686

Non Zero Mass Species Sorted By VOC

3-Methylnonane 2.55 8.49 21.618

t-3-Heptene 14686-14-7 6.17 8.37 51.625

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 7.29 47.685

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 7.21 54.349

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 6.82 69.284

2,4-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+ 1.18 6.28 7.432

1-Heptene 00592-76-7 4.29 6.01 25.778

n-Nonane 00111-84-2 0.68 5.67 3.868

Unknown #3 2.55 5.49 13.984

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 5.34 44.723

1,3-Diethylbenzene 00141-93-5 7.08 5.04 35.723

t-1,4-Dimethylcyclohexane 02207-04-7 2.55 4.94 12.581

Unknown #9 2.55 4.74 12.080

sec-Butylbenzene 00135-98-8 2.29 4.69 10.750

Methane 00074-82-8 0.01 4.14 0.057

Unknown #12 2.55 3.66 9.315

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.64 13.897

3-Ethyl-c-2-Pentene 00816-79-5 9.76 3.39 33.053

n-Butylbenzene 00104-51-8 2.29 3.21 7.359

Propane 00074-98-6 0.46 3.18 1.454

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 3.14 23.657

Unknown #10 2.55 2.96 7.543

Isobutylbenzene 00538-93-2 2.55 2.95 7.503

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 2.87 21.607

Unknown #14 2.55 2.75 7.009

Ethylene 00074-85-1 8.88 2.65 23.562

c-1,2-Dimethylcyclohexane 02207-01-4 2.55 2.49 6.350

c-2-Octene 07642-04-8 2.55 2.45 6.232

2-Methyl-1,3-butadiene 00078-79-5 10.48 2.44 25.541

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 2.29 10.116

c- & t-4-Nonene 02198-23-4 4.42 2.21 9.787

n-Undecane 01120-21-4 0.52 1.88 0.983

Unknown #7 2.55 1.82 4.626

t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 1.80 10.689

Unknown #15 2.55 1.73 4.417

1,2-Diethylbenzene 00135-01-3 5.43 1.65 8.947

1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 1.63 15.111

2,2-Dimethyloctane 15869-87-1 0.76 1.48 1.118

Unknown #11 2.55 1.42 3.609

continued
E-204

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686

Non Zero Mass Species Sorted By VOC

Unknown #18 2.55 1.39 3.538

4-Methyl-t-2-pentene 00674-76-0 8.04 1.38 11.125

Naphthalene 00091-20-3 3.28 1.27 4.165

Unknown #4 2.55 1.10 2.810

1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.85 7.896

Unknown #20 2.55 0.60 1.535

Unknown #19 2.55 0.51 1.292

Unknown #17 2.55 0.43 1.093

1,3-Butadiene 00106-99-0 12.45 0.36 4.511

Total 20242.7 51559.2 2.547

No MIR available, use weighted average of 2.5471

continued
E-205

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7557 1592.1 85.9 1367.1 3249.9 2.377 57

Static E10 - 7 psi 7571 951.42 75.9 722.3 2179.9 3.018 65

E0 - 9 psi 7650 1390.71 89.8 1248.3 2750.8 2.204 66

E0 - 7 psi 7691 979.48 114.5 1121.8 2764.8 2.465 72

105° F E10 - 10 psi 7559 2131.5 92.0 1960.1 4768.7 2.433 79

Static E10 - 7 psi 7572 1354.2 93.7 1268.7 3796.8 2.993 76

E0 - 9 psi 7652 1823.3 100.0 1824.1 3993.6 2.189 66

E0 - 7 psi 7692 1351.9 115.3 1558.2 4073.8 2.614 103

Dynamic E10 - 10 psi 25778 158.8 97.8 155.3 519.8 3.347 54

E10 - 7 psi 25783 144.6 118.7 171.6 578.9 3.373 59

E0 - 9 psi 25790 192.8 161.7 311.8 851.8 2.732 55

E0 - 7 psi 25797 230.2 88.6 204.1 877.0 4.298 49

DHB E10 - 10 psi 7562 2254.5 86.6 1952.6 5269.2 2.699 90

Total E10 - 7 psi 7579 2189.4 85.0 1860.2 5643.5 3.034 104

E0 - 9 psi 7667 1788.4 90.9 1625.8 4353.4 2.678 83

E0 - 7 psi 7716 1593.2 103.2 1644.2 4729.0 2.876 92

Vehicle 221b
E-206

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 507.38 546.399

2-Methylbutane (Isopentane) 00078-78-4 1.35 244.45 331.201

Ethanol 00064-17-5 1.45 112.02 162.308

n-Hexane 00110-54-3 1.13 53.33 60.513

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 47.74 66.732

n-Pentane 00109-66-0 1.21 38.87 47.229

3-Methylpentane 00096-14-0 1.69 33.41 56.489

2-Methyl-2-butene 00513-35-9 14.20 32.15 456.361

Toluene 00108-88-3 3.93 28.26 110.903

t-2-Pentene 00646-04-8 10.47 26.46 277.129

2,3-Dimethylbutane 00079-29-8 0.90 24.22 21.766

2-Methyl-1-butene 00563-46-2 6.38 19.05 121.508

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 16.89 20.256

Methylcyclopentane 00096-37-7 2.05 16.25 33.304

Cyclohexane 00110-82-7 1.14 16.17 18.394

c-2-Pentene 00627-20-3 10.28 14.57 149.764

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 13.65 159.727

c-2-Butene 00590-18-1 14.26 10.97 156.379

Benzene 00071-43-2 0.69 10.09 7.005

2,4-Dimethylpentane 00108-08-7 1.46 7.20 10.501

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.88 54.642

2-Methylpropane 00075-28-5 1.18 5.57 6.558

2-Methylhexane 00591-76-4 1.09 5.21 5.656

Methylcyclohexane 00108-87-2 1.56 5.16 8.021

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.10 26.998

t-2-Hexene 04050-45-7 8.55 4.90 41.861

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.87 15.546

Cyclopentene 00142-29-0 6.69 4.31 28.829

2,3,4-Trimethylpentane 00565-75-3 0.95 4.12 3.911

3-Methyl-t-2-pentene 00616-12-6 11.66 4.08 47.578

2,3-Dimethylpentane 00565-59-3 1.25 3.80 4.741

2-Methyl-2-pentene 00625-27-4 11.03 3.76 41.465

3-Methyl-c-2-pentene 00922-62-3 12.52 3.50 43.821

n-Heptane 00142-82-5 0.97 3.42 3.303

2,2-Dimethylbutane 00075-83-2 1.11 3.29 3.657

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.00 19.794

2,4-Dimethylhexane 00589-43-5 1.61 2.63 4.222

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.43 14.038

1-Methylcyclopentene 00693-89-0 12.45 2.40 29.841

2,2-Dimethylpentane 00590-35-2 1.04 1.98 2.069

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.85 2.978

2,2,5-Trimethylhexane 03522-94-9 1.05 1.32 1.389

t-1,2-Dimethylcyclopentane 00822-50-4 2.38 1.26 2.996

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.25 1.370

Vehicle 221b - Fuel 10 psi E10 - 86°F Static - Test 7557

Non Zero Mass Species Sorted By VOC
E-207

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 10 psi E10 - 86°F Static - Test 7557

Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 1.09 0.866

c-1,3-Dimethylcyclopentane 02532-58-3 2.38 1.00 2.387

2-Methylheptane 00592-27-8 0.97 0.86 0.836

2,2,3-Trimethylbutane 00464-06-2 1.05 0.85 0.901

3,3-Dimethylpentane 00562-49-2 1.12 0.83 0.932

c-1,3-Dimethylcyclohexane 00638-04-0 2.38 0.71 1.680

3-Methylheptane 00589-81-1 1.12 0.64 0.715

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.55 5.749

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.46 3.580

Unknown #5 2.38 0.26 0.625

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.25 0.970

t-1,4-Dimethylcyclohexane 02207-04-7 2.38 0.20 0.482

t-3-Heptene 14686-14-7 6.17 0.17 1.037

Total 1367.1 3249.9 2.377

No MIR available, use weighted average of 2.3773

continued
E-208

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 654.61 704.963

2-Methylbutane (Isopentane) 00078-78-4 1.35 330.02 447.133

Ethanol 00064-17-5 1.45 199.28 288.754

n-Hexane 00110-54-3 1.13 80.10 90.882

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 69.35 96.933

n-Pentane 00109-66-0 1.21 53.77 65.332

Toluene 00108-88-3 3.93 49.46 194.113

3-Methylpentane 00096-14-0 1.69 48.75 82.430

2-Methyl-2-butene 00513-35-9 14.20 45.60 647.285

t-2-Pentene 00646-04-8 10.47 37.84 396.335

2,3-Dimethylbutane 00079-29-8 0.90 35.30 31.727

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 27.98 33.546

2-Methyl-1-butene 00563-46-2 6.38 25.93 165.410

Methylcyclopentane 00096-37-7 2.05 25.14 51.537

Cyclohexane 00110-82-7 1.14 24.77 28.177

c-2-Pentene 00627-20-3 10.28 20.58 211.612

Benzene 00071-43-2 0.69 15.99 11.101

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 15.19 177.840

c-2-Butene 00590-18-1 14.26 14.09 200.980

2,4-Dimethylpentane 00108-08-7 1.46 11.42 16.661

2-Methylhexane 00591-76-4 1.09 9.62 10.435

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 8.82 70.036

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.51 65.987

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.38 26.727

Methylcyclohexane 00108-87-2 1.56 7.88 12.255

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 7.69 40.730

2,3,4-Trimethylpentane 00565-75-3 0.95 7.54 7.157

t-2-Hexene 04050-45-7 8.55 7.41 63.364

2-Methylpropane 00075-28-5 1.18 6.78 7.979

2,3-Dimethylpentane 00565-59-3 1.25 6.54 8.161

n-Heptane 00142-82-5 0.97 6.22 6.005

Cyclopentene 00142-29-0 6.69 6.20 41.456

3-Methyl-t-2-pentene 00616-12-6 11.66 6.04 70.384

2-Methyl-2-pentene 00625-27-4 11.03 5.67 62.532

3-Methyl-c-2-pentene 00922-62-3 12.52 5.31 66.467

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.48 24.042

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.47 29.525

2,2-Dimethylbutane 00075-83-2 1.11 4.28 4.759

1-Methylcyclopentene 00693-89-0 12.45 3.91 48.731

2,4-Dimethylhexane 00589-43-5 1.61 3.55 5.700

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.33 19.258

2,2-Dimethylpentane 00590-35-2 1.04 2.78 2.896

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.66 4.272

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.56 11.235

Vehicle 221b - Fuel 10 psi E10 - 105°F Static - Test 7559

Non Zero Mass Species Sorted By VOC
E-209

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 10 psi E10 - 105°F Static - Test 7559

Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 2.41 18.246

2,2,5-Trimethylhexane 03522-94-9 1.05 2.10 2.215

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.99 23.409

t-1,2-Dimethylcyclopentane 00822-50-4 2.43 1.99 4.842

n-Octane 00111-65-9 0.80 1.90 1.511

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.89 2.067

Ethylbenzene 00100-41-4 2.96 1.66 4.914

c-1,3-Dimethylcyclopentane 02532-58-3 2.43 1.64 3.978

2,2,3-Trimethylbutane 00464-06-2 1.05 1.41 1.491

Propane 00074-98-6 0.46 1.41 0.643

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.33 9.834

3,3-Dimethylpentane 00562-49-2 1.12 1.29 1.440

2-Methylheptane 00592-27-8 0.97 1.25 1.205

3-Methylheptane 00589-81-1 1.12 1.20 1.352

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.15 6.399

c-1,3-Dimethylcyclohexane 00638-04-0 2.43 0.92 2.242

n-Propylbenzene 00103-65-1 1.96 0.92 1.801

2,2-DiMeHexane 00590-73-8 0.94 0.80 0.754

n-Decane 00124-18-5 0.59 0.75 0.441

n-Nonane 00111-84-2 0.68 0.62 0.426

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.58 6.893

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.55 4.296

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.49 5.122

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.48 1.854

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.43 0.42 1.031

Unknown #5 2.43 0.41 1.005

t-3-Heptene 14686-14-7 6.17 0.36 2.224

Unknown #16 2.43 0.36 0.873

3,3-Dimethylhexane 00563-16-6 1.15 0.36 0.411

3,5-Dimethylheptane 00926-82-9 1.42 0.33 0.475

4-Methyloctane 02216-34-4 0.85 0.31 0.265

1-Nonene 00124-11-8 2.49 0.27 0.672

t-1,4-Dimethylcyclohexane 02207-04-7 2.43 0.25 0.619

2,3,5-Trimethylhexane 01069-53-0 1.12 0.25 0.283

Unknown #3 2.43 0.25 0.606

Total 1960.1 4768.7 2.433

No MIR available, use weighted average of 2.4329

continued
E-210

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 35.68 69.925

Toluene 00108-88-3 3.93 18.49 72.586

Ethanol 00064-17-5 1.45 15.22 22.056

Methane 00074-82-8 0.01 9.22 0.128

Unknown #22 . 3.35 6.27 20.981

Benzene 00071-43-2 0.69 5.45 3.787

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.89 37.958

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.88 26.179

Propane 00074-98-6 0.46 3.47 1.588

1-Butyne 00107-00-6 6.05 3.03 18.355

ortho-Xylene 00095-47-6 7.58 2.57 19.460

2,3,5-Trimethylhexane 01069-53-0 1.12 2.49 2.787

Cyclohexane 00110-82-7 1.14 2.44 2.778

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.25 9.872

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.11 11.157

Indan 00496-11-7 3.23 2.07 6.692

2,2-DiMeHexane 00590-73-8 0.94 2.03 1.914

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.91 22.476

n-Hexane 00110-54-3 1.13 1.90 2.152

3-Methyl-c-2-pentene 00922-62-3 12.52 1.83 22.931

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.77 21.115

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.66 1.994

n-Decane 00124-18-5 0.59 1.63 0.963

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.60 10.573

1,3-Butadiene 00106-99-0 12.45 1.45 18.033

2,4-Dimethylhexane 00589-43-5 1.61 1.38 2.221

2-Methyl-2-pentene 00625-27-4 11.03 1.37 15.100

2,2-Dimethylpentane 00590-35-2 1.04 1.18 1.233

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.11 7.827

3-Methyl-t-2-pentene 00616-12-6 11.66 1.01 11.784

2-Methylheptane 00592-27-8 0.97 0.94 0.910

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.91 5.033

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.91 9.504

n-Undecane 01120-21-4 0.52 0.89 0.467

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.85 0.932

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.77 5.775

c-1,3-Dimethylcyclopentane 02532-58-3 3.35 0.74 2.467

2,3,4-Trimethylpentane 00565-75-3 0.95 0.72 0.685

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.72 5.686

t-2-Hexene 04050-45-7 8.55 0.72 6.120

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.69 1.111

Methylcyclohexane 00108-87-2 1.56 0.66 1.025

3-Methylnonane 05911-04-6 0.66 0.56 0.367

2,2,5-Trimethylhexane 03522-94-9 1.05 0.52 0.552

Vehicle 221b - Fuel 10 psi E10 - Dynamic - Test 25778

Non Zero Mass Species Sorted By VOC
E-211

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 10 psi E10 - Dynamic - Test 25778

Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 0.52 1.534

2-Methyl-1-butene 00563-46-2 6.38 0.50 3.184

c-2-Butene 00590-18-1 14.26 0.28 4.022

2-Methylhexane 00591-76-4 1.09 0.28 0.303

2,3-Dimethylpentane 00565-59-3 1.25 0.26 0.322

t-2-Pentene 00646-04-8 10.47 0.24 2.500

n-Octane 00111-65-9 0.80 0.15 0.122

n-Pentane 00109-66-0 1.21 0.04 0.054

Cyclopentene 00142-29-0 6.69 0.04 0.282

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.02 0.245

Total 155.3 519.8 3.347

No MIR available, use weighted average of 3.3471

continued
E-212

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 405.47 436.652

Ethanol 00064-17-5 1.45 401.87 582.293

2-Methylbutane (Isopentane) 00078-78-4 1.35 204.81 277.497

Toluene 00108-88-3 3.93 144.31 566.423

n-Hexane 00110-54-3 1.13 94.53 107.256

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 58.08 81.188

n-Pentane 00109-66-0 1.21 46.82 56.882

2-Methyl-2-butene 00513-35-9 14.20 46.22 656.138

Benzene 00071-43-2 0.69 42.13 29.250

t-2-Pentene 00646-04-8 10.47 41.61 435.802

3-Methylpentane 00096-14-0 1.69 39.23 66.329

Cyclohexane 00110-82-7 1.14 36.84 41.905

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 27.82 33.355

2,3-Dimethylbutane 00079-29-8 0.90 26.04 23.406

Methylcyclopentane 00096-37-7 2.05 25.48 52.221

2-Methyl-1-butene 00563-46-2 6.38 24.07 153.548

c-2-Pentene 00627-20-3 10.28 21.57 221.725

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 16.40 127.185

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 14.90 174.354

c-2-Butene 00590-18-1 14.26 11.51 164.182

2-Methylhexane 00591-76-4 1.09 11.04 11.986

2,4-Dimethylpentane 00108-08-7 1.46 10.89 15.891

t-2-Hexene 04050-45-7 8.55 10.44 89.227

2,3,4-Trimethylpentane 00565-75-3 0.95 9.90 9.391

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 9.76 31.155

n-Heptane 00142-82-5 0.97 9.54 9.218

2,3-Dimethylpentane 00565-59-3 1.25 8.41 10.501

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.32 44.086

Methylcyclohexane 00108-87-2 1.56 7.80 12.139

3-Methyl-t-2-pentene 00616-12-6 11.66 7.57 88.256

Cyclopentene 00142-29-0 6.69 7.56 50.570

2,2-DiMeHexane 00590-73-8 0.94 6.78 6.384

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.75 53.635

3-Methyl-c-2-pentene 00922-62-3 12.52 6.24 78.115

2-Methyl-2-pentene 00625-27-4 11.03 5.88 64.848

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.78 38.174

1-Methylcyclopentene 00693-89-0 12.45 5.72 71.292

2,4-Dimethylhexane 00589-43-5 1.61 5.31 8.522

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.12 27.500

ortho-Xylene 00095-47-6 7.58 4.45 33.722

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.12 30.430

2,2-Dimethylbutane 00075-83-2 1.11 3.60 3.997

2-Methylpropane 00075-28-5 1.18 3.37 3.965

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 3.29 5.280

Vehicle 221b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7562

Non Zero Mass Species Sorted By VOC
E-213

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7562

Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 3.19 2.542

2,2,5-Trimethylhexane 03522-94-9 1.05 3.19 3.360

Ethylbenzene 00100-41-4 2.96 3.15 9.335

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.88 3.146

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.85 16.486

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.57 11.292

t-1,2-Dimethylcyclopentane 00822-50-4 2.70 2.44 6.572

2-Methylheptane 00592-27-8 0.97 2.23 2.153

2,2-Dimethylpentane 00590-35-2 1.04 1.99 2.080

c-1,3-Dimethylcyclopentane 02532-58-3 2.70 1.90 5.131

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.84 21.657

3-Methylheptane 00589-81-1 1.12 1.78 2.000

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.57 8.723

n-Propylbenzene 00103-65-1 1.96 1.55 3.035

3,3-Dimethylpentane 00562-49-2 1.12 1.45 1.620

2,3,5-Trimethylhexane 01069-53-0 1.12 1.42 1.586

2,2,3-Trimethylbutane 00464-06-2 1.05 1.35 1.424

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.19 9.299

3,5-Dimethylheptane 00926-82-9 1.42 1.00 1.426

Unknown #1 2.70 0.95 2.557

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.89 9.374

1,3-Butadiene 00106-99-0 12.45 0.89 11.106

Unknown #16 2.70 0.89 2.400

n-Decane 00124-18-5 0.59 0.89 0.525

n-Nonane 00111-84-2 0.68 0.88 0.601

c-1,3-Dimethylcyclohexane 00638-04-0 2.70 0.87 2.358

t-3-Heptene 14686-14-7 6.17 0.81 5.009

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.77 9.183

Propane 00074-98-6 0.46 0.74 0.340

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.70 0.72 1.939

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.65 2.529

Isopropylbenzene (Cumene) 00098-82-8 2.70 0.63 1.711

Indan 00496-11-7 3.23 0.59 1.916

3,3-Dimethylhexane 00563-16-6 1.15 0.51 0.584

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.49 3.481

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.48 4.002

Unknown #5 2.70 0.47 1.259

c-2-Heptene 06443-92-1 7.08 0.42 2.981

4-Methyloctane 02216-34-4 0.85 0.39 0.334

t-1,4-Dimethylcyclohexane 02207-04-7 2.70 0.36 0.969

1-Nonene 00124-11-8 2.49 0.31 0.762

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.30 1.950

continued
E-214

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7562

Non Zero Mass Species Sorted By VOC

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.25 1.554

2,4-Dimethylheptane 02213-23-2 1.26 0.25 0.310

Unknown #8 2.70 0.18 0.492

Unknown #14 2.70 0.08 0.221

Total 1952.6 5269.2 2.699

No MIR available, use weighted average of 2.6986

continued
E-215

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 183.65 248.820

Ethanol 00064-17-5 1.45 85.05 123.234

n-Butane 00106-97-8 1.08 55.98 60.286

n-Hexane 00110-54-3 1.13 42.42 48.137

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 36.76 51.389

n-Pentane 00109-66-0 1.21 29.25 35.538

3-Methylpentane 00096-14-0 1.69 26.06 44.059

2-Methyl-2-butene 00513-35-9 14.20 24.79 351.885

Toluene 00108-88-3 3.93 21.45 84.201

t-2-Pentene 00646-04-8 10.47 20.72 216.997

2,3-Dimethylbutane 00079-29-8 0.90 18.25 16.404

2-Methyl-1-butene 00563-46-2 6.38 14.75 94.109

Methylcyclopentane 00096-37-7 2.05 12.48 25.573

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 12.26 14.700

c-2-Pentene 00627-20-3 10.28 11.25 115.647

Cyclohexane 00110-82-7 1.14 10.96 12.467

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 10.28 120.270

c-2-Butene 00590-18-1 14.26 8.44 120.327

Benzene 00071-43-2 0.69 7.98 5.543

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.61 44.524

2,4-Dimethylpentane 00108-08-7 1.46 5.40 7.883

n-Propylbenzene 00103-65-1 1.96 4.99 9.781

2-Methylhexane 00591-76-4 1.09 4.63 5.023

Methylcyclohexane 00108-87-2 1.56 4.49 6.989

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.19 13.370

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 4.00 21.181

2-Methylpropane 00075-28-5 1.18 3.70 4.351

t-2-Hexene 04050-45-7 8.55 3.61 30.821

Cyclopentene 00142-29-0 6.69 3.29 22.015

2,3,4-Trimethylpentane 00565-75-3 0.95 3.09 2.934

2-Methyl-2-pentene 00625-27-4 11.03 3.06 33.788

3-Methyl-t-2-pentene 00616-12-6 11.66 3.00 34.957

n-Heptane 00142-82-5 0.97 2.89 2.787

2,3-Dimethylpentane 00565-59-3 1.25 2.85 3.560

3-Methyl-c-2-pentene 00922-62-3 12.52 2.80 35.108

2,2-Dimethylbutane 00075-83-2 1.11 2.64 2.935

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.45 16.187

1-Methylcyclopentene 00693-89-0 12.45 1.96 24.373

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.88 10.848

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.84 14.307

2,2-Dimethylpentane 00590-35-2 1.04 1.56 1.630

2,4-Dimethylhexane 00589-43-5 1.61 1.51 2.422

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.28 2.052

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.11 1.213

Vehicle 221b - Fuel 7 psi E10 - 86°F Static - Test 7571

Non Zero Mass Species Sorted By VOC
E-216

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E10 - 86°F Static - Test 7571

Non Zero Mass Species Sorted By VOC

t-1,2-Dimethylcyclopentane 00822-50-4 3.02 1.02 3.093

c-1,3-Dimethylcyclopentane 02532-58-3 3.02 0.99 2.984

n-Octane 00111-65-9 0.80 0.85 0.676

Unknown #22 . 3.02 0.82 2.476

3,3-Dimethylpentane 00562-49-2 1.12 0.81 0.902

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.71 3.799

2,2,3-Trimethylbutane 00464-06-2 1.05 0.70 0.734

2,2,5-Trimethylhexane 03522-94-9 1.05 0.67 0.704

2-Methylheptane 00592-27-8 0.97 0.52 0.502

ortho-Xylene 00095-47-6 7.58 0.51 3.902

3-Methylheptane 00589-81-1 1.12 0.51 0.577

Propane 00074-98-6 0.46 0.51 0.232

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.43 1.903

2,3,5-Trimethylhexane 01069-53-0 1.12 0.42 0.468

c-1,3-Dimethylcyclohexane 00638-04-0 3.02 0.41 1.241

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.41 2.264

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.40 4.174

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.36 1.364

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.28 2.182

Ethylbenzene 00100-41-4 2.96 0.22 0.642

t-1,4-Dimethylcyclohexane 02207-04-7 3.02 0.16 0.480

Total 722.3 2179.9 3.018

No MIR available, use weighted average of 3.0180

continued
E-217

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 300.70 407.411

Ethanol 00064-17-5 1.45 175.93 254.913

n-Butane 00106-97-8 1.08 86.54 93.192

n-Hexane 00110-54-3 1.13 76.52 86.830

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 64.44 90.071

n-Pentane 00109-66-0 1.21 49.08 59.633

Toluene 00108-88-3 3.93 48.57 190.638

3-Methylpentane 00096-14-0 1.69 45.21 76.439

2-Methyl-2-butene 00513-35-9 14.20 42.39 601.709

t-2-Pentene 00646-04-8 10.47 35.06 367.186

2,3-Dimethylbutane 00079-29-8 0.90 31.83 28.603

2-Methyl-1-butene 00563-46-2 6.38 24.29 154.955

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 23.37 28.018

Methylcyclopentane 00096-37-7 2.05 22.39 45.898

Cyclohexane 00110-82-7 1.14 20.15 22.915

c-2-Pentene 00627-20-3 10.28 19.28 198.187

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 16.25 190.254

Benzene 00071-43-2 0.69 14.77 10.255

c-2-Butene 00590-18-1 14.26 13.00 185.313

2,4-Dimethylpentane 00108-08-7 1.46 9.82 14.329

2-Methylhexane 00591-76-4 1.09 8.43 9.146

Methylcyclohexane 00108-87-2 1.56 8.15 12.672

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 7.85 62.371

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 7.20 22.976

t-2-Hexene 04050-45-7 8.55 6.54 55.875

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.52 34.548

2,3,4-Trimethylpentane 00565-75-3 0.95 5.94 5.635

2-Methylpropane 00075-28-5 1.18 5.68 6.687

Cyclopentene 00142-29-0 6.69 5.68 37.998

n-Heptane 00142-82-5 0.97 5.59 5.397

2,3-Dimethylpentane 00565-59-3 1.25 5.31 6.624

3-Methyl-t-2-pentene 00616-12-6 11.66 5.24 61.099

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 5.09 39.451

2-Methyl-2-pentene 00625-27-4 11.03 4.87 53.696

3-Methyl-c-2-pentene 00922-62-3 12.52 4.63 57.940

2,2-Dimethylbutane 00075-83-2 1.11 4.44 4.934

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.07 26.881

1-Methylcyclopentene 00693-89-0 12.45 3.74 46.520

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.22 18.583

2,4-Dimethylhexane 00589-43-5 1.61 3.18 5.103

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.91 15.637

Methane 00074-82-8 0.01 2.70 0.037

2,2-Dimethylpentane 00590-35-2 1.04 2.58 2.693

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.39 3.835

Vehicle 221b - Fuel 7 psi E10 - 105°F Static - Test 7572

Non Zero Mass Species Sorted By VOC
E-218

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E10 - 105°F Static - Test 7572

Non Zero Mass Species Sorted By VOC

2,2,5-Trimethylhexane 03522-94-9 1.05 1.87 1.969

t-1,2-Dimethylcyclopentane 00822-50-4 2.99 1.66 4.961

n-Octane 00111-65-9 0.80 1.55 1.230

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.54 11.385

ortho-Xylene 00095-47-6 7.58 1.41 10.693

2-Methylheptane 00592-27-8 0.97 1.41 1.359

c-1,3-Dimethylcyclopentane 02532-58-3 2.99 1.37 4.095

2,2,3-Trimethylbutane 00464-06-2 1.05 1.31 1.383

3,3-Dimethylpentane 00562-49-2 1.12 1.28 1.432

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.21 5.325

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.21 1.323

3-Methylheptane 00589-81-1 1.12 1.04 1.174

2,3,5-Trimethylhexane 01069-53-0 1.12 0.98 1.101

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.91 10.720

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.86 6.753

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.77 8.107

n-Propylbenzene 00103-65-1 1.96 0.73 1.427

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.72 4.010

Ethylbenzene 00100-41-4 2.96 0.72 2.129

c-1,3-Dimethylcyclohexane 00638-04-0 2.99 0.71 2.137

Propane 00074-98-6 0.46 0.67 0.307

3,5-Dimethylheptane 00926-82-9 1.42 0.47 0.665

n-Nonane 00111-84-2 0.68 0.44 0.302

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.44 1.706

Unknown #5 2.99 0.39 1.171

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.27 3.231

t-1,4-Dimethylcyclohexane 02207-04-7 2.99 0.26 0.776

t-3-Heptene 14686-14-7 6.17 0.24 1.501

n-Decane 00124-18-5 0.59 0.23 0.133

3,3-Dimethylhexane 00563-16-6 1.15 0.22 0.250

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.14 0.896

n-Undecane 01120-21-4 0.52 0.13 0.068

Total 1268.7 3796.8 2.993

No MIR available, use weighted average of 2.9927

continued
E-219

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 40.59 58.808

Toluene 00108-88-3 3.93 17.21 67.543

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.33 76.277

n-Hexane 00110-54-3 1.13 6.67 7.565

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.32 6.382

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.63 24.844

Benzene 00071-43-2 0.69 4.58 3.177

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.22 49.624

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.77 29.213

2-Methylbutane (Isopentane) 00078-78-4 1.35 3.54 4.799

Methylcyclohexane 00108-87-2 1.56 3.12 4.859

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.01 13.205

3-Methylpentane 00096-14-0 1.69 2.99 5.055

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.99 4.179

2-Methylhexane 00591-76-4 1.09 2.92 3.165

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.90 9.239

c-1,3-Dimethylcyclopentane 02532-58-3 3.37 2.88 9.709

t-1,2-Dimethylcyclopentane 00822-50-4 3.37 2.71 9.150

Unknown #16 3.37 2.66 8.955

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.60 14.407

Unknown #22 . 3.37 2.48 8.357

n-Pentane 00109-66-0 1.21 2.32 2.815

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.28 16.130

2,3,4-Trimethylpentane 00565-75-3 0.95 1.99 1.885

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.96 15.603

n-Nonane 00111-84-2 0.68 1.90 1.300

t-2-Pentene 00646-04-8 10.47 1.58 16.559

n-Octane 00111-65-9 0.80 1.53 1.217

2-Methyl-1-butene 00563-46-2 6.38 1.52 9.671

2,2-Dimethylpentane 00590-35-2 1.04 1.46 1.521

3-Methylheptane 00589-81-1 1.12 1.42 1.595

n-Decane 00124-18-5 0.59 1.40 0.826

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.37 7.237

2-Methyl-2-butene 00513-35-9 14.20 1.36 19.369

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.27 1.382

n-Heptane 00142-82-5 0.97 1.26 1.216

1,4-Diethylbenzene 00105-05-5 4.39 1.21 5.321

2,3,5-Trimethylhexane 01069-53-0 1.12 1.20 1.342

n-Butane 00106-97-8 1.08 1.14 1.232

2,2,5-Trimethylhexane 03522-94-9 1.05 1.13 1.193

2,3-Dimethylpentane 00565-59-3 1.25 1.03 1.285

n-Undecane 01120-21-4 0.52 1.00 0.524

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.00 11.734

2,4-Dimethylpentane 00108-08-7 1.46 0.92 1.346

Vehicle 221b - Fuel 7 psi E10 - Dynamic - Test 25783

Non Zero Mass Species Sorted By VOC
E-220

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E10 - Dynamic - Test 25783

Non Zero Mass Species Sorted By VOC

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.84 1.343

n-Propylbenzene 00103-65-1 1.96 0.81 1.589

c-2-Butene 00590-18-1 14.26 0.69 9.881

c-2-Pentene 00627-20-3 10.28 0.63 6.458

Ethylbenzene 00100-41-4 2.96 0.60 1.775

2,3-Dimethylbutane 00079-29-8 0.90 0.52 0.464

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.50 5.980

3-Methyl-t-2-pentene 00616-12-6 11.66 0.42 4.900

t-2-Hexene 04050-45-7 8.55 0.27 2.335

Methane 00074-82-8 0.01 0.25 0.003

Indan 00496-11-7 3.23 0.23 0.759

2,4-Dimethylhexane 00589-43-5 1.61 0.17 0.269

2,2-Dimethylbutane 00075-83-2 1.11 0.16 0.172

2-Methyl-2-pentene 00625-27-4 11.03 0.15 1.623

ortho-Xylene 00095-47-6 7.58 0.07 0.520

Total 171.6 578.9 3.373

No MIR available, use weighted average of 3.3727

continued
E-221

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 462.69 670.422

Toluene 00108-88-3 3.93 201.13 789.442

2-Methylbutane (Isopentane) 00078-78-4 1.35 182.81 247.689

n-Hexane 00110-54-3 1.13 108.39 122.983

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 61.21 85.555

n-Butane 00106-97-8 1.08 58.34 62.826

Benzene 00071-43-2 0.69 49.41 34.308

2-Methyl-2-butene 00513-35-9 14.20 47.01 667.349

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 44.60 53.484

3-Methylpentane 00096-14-0 1.69 44.17 74.687

n-Pentane 00109-66-0 1.21 43.09 52.348

t-2-Pentene 00646-04-8 10.47 41.06 430.020

Cyclohexane 00110-82-7 1.14 33.85 38.501

Methylcyclopentane 00096-37-7 2.05 29.78 61.051

2,3-Dimethylbutane 00079-29-8 0.90 26.14 23.492

2-Methyl-1-butene 00563-46-2 6.38 23.36 149.005

c-2-Pentene 00627-20-3 10.28 21.21 218.100

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.26 157.099

2,3,4-Trimethylpentane 00565-75-3 0.95 19.46 18.463

Methylcyclohexane 00108-87-2 1.56 16.07 25.002

2-Methylhexane 00591-76-4 1.09 15.30 16.606

n-Heptane 00142-82-5 0.97 14.61 14.110

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 14.09 164.892

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 13.58 43.342

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 13.45 72.212

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 13.39 98.893

2,4-Dimethylpentane 00108-08-7 1.46 13.08 19.095

t-2-Hexene 04050-45-7 8.55 11.58 99.003

c-2-Butene 00590-18-1 14.26 10.58 150.824

2,3-Dimethylpentane 00565-59-3 1.25 9.39 11.720

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 9.20 48.766

2,4-Dimethylhexane 00589-43-5 1.61 8.64 13.864

3-Methyl-t-2-pentene 00616-12-6 11.66 8.30 96.729

n-Octane 00111-65-9 0.80 7.84 6.241

3-Methyl-c-2-pentene 00922-62-3 12.52 7.80 97.607

Cyclopentene 00142-29-0 6.69 7.68 51.325

2,2,5-Trimethylhexane 03522-94-9 1.05 7.03 7.406

2-Methyl-2-pentene 00625-27-4 11.03 6.84 75.490

1-Methylcyclopentene 00693-89-0 12.45 6.76 84.235

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.53 10.483

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.49 51.542

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.37 42.086

ortho-Xylene 00095-47-6 7.58 6.09 46.157

2,2-DiMeHexane 00590-73-8 0.94 5.99 5.635

Vehicle 221b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7579

Non Zero Mass Species Sorted By VOC
E-222

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7579

Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.88 25.857

1,3,5-Trimethylbenzene 00108-67-8 11.75 5.07 59.652

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.96 5.417

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.38 24.261

Ethylbenzene 00100-41-4 2.96 4.29 12.719

2-Methylheptane 00592-27-8 0.97 4.29 4.149

2,2-Dimethylbutane 00075-83-2 1.11 3.52 3.913

t-1,2-Dimethylcyclopentane 00822-50-4 3.03 3.46 10.510

3-Methylheptane 00589-81-1 1.12 3.44 3.874

n-Propylbenzene 00103-65-1 1.96 3.19 6.256

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.19 18.438

2,2-Dimethylpentane 00590-35-2 1.04 2.87 2.994

c-1,3-Dimethylcyclopentane 02532-58-3 3.03 2.77 8.389

2-Methylpropane 00075-28-5 1.18 2.63 3.097

Unknown #16 3.03 2.46 7.477

n-Nonane 00111-84-2 0.68 2.32 1.582

c-1,3-Dimethylcyclohexane 00638-04-0 3.03 2.11 6.401

3,3-Dimethylpentane 00562-49-2 1.12 2.05 2.289

2,2,3-Trimethylbutane 00464-06-2 1.05 1.71 1.806

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.52 11.903

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.52 18.133

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.41 5.433

3,5-Dimethylheptane 00926-82-9 1.42 1.38 1.959

4-Methyloctane 02216-34-4 0.85 1.36 1.156

2,3,5-Trimethylhexane 01069-53-0 1.12 1.30 1.456

Unknown #5 3.03 1.17 3.542

n-Decane 00124-18-5 0.59 1.15 0.682

t-1,4-Dimethylcyclohexane 02207-04-7 3.03 1.15 3.493

1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.01 7.124

Unknown #8 3.03 1.00 3.022

3,3-Dimethylhexane 00563-16-6 1.15 0.93 1.071

Unknown #13 3.03 0.92 2.795

Indan 00496-11-7 3.23 0.90 2.899

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.03 0.89 2.697

3-Methyloctane 02216-33-3 0.88 0.84 0.740

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.82 8.593

1-Nonene 00124-11-8 2.49 0.77 1.930

Isopropylbenzene (Cumene) 00098-82-8 3.03 0.74 2.236

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.72 0.800

2,4-Dimethylheptane 02213-23-2 1.26 0.70 0.881

c-2-Heptene 06443-92-1 7.08 0.69 4.903

1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.66 3.577

continued
E-223

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7579

Non Zero Mass Species Sorted By VOC

3-Methylnonane 3.03 0.64 1.944

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.63 4.764

1,4-Diethylbenzene 00105-05-5 4.39 0.61 2.658

t-3-Heptene 14686-14-7 6.17 0.59 3.610

t-2-Nonene 06434-78-2 3.03 0.51 1.538

Unknown #9 3.03 0.49 1.478

4-Methyl-t-2-pentene 00674-76-0 8.04 0.46 3.712

sec-Butylbenzene 00135-98-8 2.29 0.45 1.029

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.41 3.396

Unknown #3 3.03 0.37 1.130

c- & t-4-Nonene 02198-23-4 4.42 0.36 1.591

1-Heptene 00592-76-7 4.29 0.34 1.452

1,3-Diethylbenzene 00141-93-5 7.08 0.31 2.205

Propane 00074-98-6 0.46 0.31 0.141

Isobutylbenzene 00538-93-2 3.03 0.29 0.890

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.27 0.227

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.23 1.478

n-Undecane 01120-21-4 0.52 0.19 0.098

Total 1860.2 5643.5 3.034

No MIR available, use weighted average of 3.0338

continued
E-224

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 460.36 495.765

2-Methylbutane (Isopentane) 00078-78-4 1.35 319.27 432.580

Cyclohexane 00110-82-7 1.14 60.88 69.245

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 39.91 55.782

n-Hexane 00110-54-3 1.13 33.30 37.790

Toluene 00108-88-3 3.93 30.43 119.456

n-Pentane 00109-66-0 1.21 27.36 33.236

3-Methylpentane 00096-14-0 1.69 25.94 43.858

2,3-Dimethylbutane 00079-29-8 0.90 23.51 21.131

2-Methyl-2-butene 00513-35-9 14.20 22.33 316.947

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 18.56 22.251

t-2-Pentene 00646-04-8 10.47 17.69 185.320

Methylcyclopentane 00096-37-7 2.05 12.61 25.840

2-Methyl-1-butene 00563-46-2 6.38 12.29 78.397

c-2-Pentene 00627-20-3 10.28 10.04 103.198

Benzene 00071-43-2 0.69 8.78 6.097

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.86 92.045

2,4-Dimethylpentane 00108-08-7 1.46 6.98 10.185

c-2-Butene 00590-18-1 14.26 6.30 89.898

2,3,4-Trimethylpentane 00565-75-3 0.95 5.19 4.929

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.90 38.034

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.87 26.155

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.83 21.244

2,2-Dimethylbutane 00075-83-2 1.11 4.65 5.170

2-Methylhexane 00591-76-4 1.09 4.48 4.867

2,3-Dimethylpentane 00565-59-3 1.25 4.20 5.242

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.16 13.278

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.86 20.462

t-2-Hexene 04050-45-7 8.55 3.77 32.188

Ethanol 00064-17-5 1.45 3.71 5.373

3-Methyl-t-2-pentene 00616-12-6 11.66 3.67 42.836

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.56 28.237

Cyclopentene 00142-29-0 6.69 3.29 22.007

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.00 22.154

3-Methyl-c-2-pentene 00922-62-3 12.52 2.99 37.449

2-Methyl-2-pentene 00625-27-4 11.03 2.90 31.999

2-Methylpropane 00075-28-5 1.18 2.63 3.096

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.58 17.033

1-Methylcyclopentene 00693-89-0 12.45 2.29 28.479

2,4-Dimethylhexane 00589-43-5 1.61 2.17 3.477

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.07 3.322

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.97 11.388

2,2,5-Trimethylhexane 03522-94-9 1.05 1.93 2.034

n-Heptane 00142-82-5 0.97 1.82 1.761

Vehicle 221b - Fuel 9 psi E0 - 86°F Static - Test 7650

Non Zero Mass Species Sorted By VOC
E-225

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 9 psi E0 - 86°F Static - Test 7650

Non Zero Mass Species Sorted By VOC

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.74 9.663

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.61 1.755

n-Propylbenzene 00103-65-1 1.96 1.35 2.645

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.32 15.795

ortho-Xylene 00095-47-6 7.58 1.27 9.618

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.19 14.047

2,2-Dimethylpentane 00590-35-2 1.04 1.19 1.241

t-1,2-Dimethylcyclopentane 00822-50-4 2.20 1.17 2.582

c-1,3-Dimethylcyclopentane 02532-58-3 2.20 0.93 2.059

Ethylbenzene 00100-41-4 2.96 0.80 2.363

Methylcyclohexane 00108-87-2 1.56 0.78 1.217

2,2,3-Trimethylbutane 00464-06-2 1.05 0.69 0.728

4-Methyl-t-2-pentene 00674-76-0 8.04 0.66 5.311

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.61 3.874

n-Octane 00111-65-9 0.80 0.61 0.484

3,3-Dimethylpentane 00562-49-2 1.12 0.57 0.638

2-Methylheptane 00592-27-8 0.97 0.54 0.523

3-Methylheptane 00589-81-1 1.12 0.49 0.546

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.35 3.665

Unknown #1 2.20 0.29 0.634

n-Decane 00124-18-5 0.59 0.16 0.096

2,3,5-Trimethylhexane 01069-53-0 1.12 0.08 0.087

Total 1248.3 2750.8 2.204

No MIR available, use weighted average of 2.2036

continued
E-226

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 636.36 685.309

2-Methylbutane (Isopentane) 00078-78-4 1.35 469.23 635.754

Cyclohexane 00110-82-7 1.14 100.16 113.921

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 62.96 88.010

n-Hexane 00110-54-3 1.13 53.73 60.962

Toluene 00108-88-3 3.93 51.80 203.304

n-Pentane 00109-66-0 1.21 41.21 50.068

3-Methylpentane 00096-14-0 1.69 41.07 69.450

2,3-Dimethylbutane 00079-29-8 0.90 36.44 32.750

2-Methyl-2-butene 00513-35-9 14.20 33.67 477.972

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 31.65 37.952

t-2-Pentene 00646-04-8 10.47 26.30 275.421

Methylcyclopentane 00096-37-7 2.05 20.33 41.665

2-Methyl-1-butene 00563-46-2 6.38 18.05 115.161

c-2-Pentene 00627-20-3 10.28 14.23 146.307

Benzene 00071-43-2 0.69 13.97 9.701

2,4-Dimethylpentane 00108-08-7 1.46 11.64 16.988

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 10.46 122.473

2,3,4-Trimethylpentane 00565-75-3 0.95 8.67 8.225

c-2-Butene 00590-18-1 14.26 7.62 108.727

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 7.07 54.853

2-Methylhexane 00591-76-4 1.09 6.98 7.574

2,2-Dimethylbutane 00075-83-2 1.11 6.79 7.541

2,3-Dimethylpentane 00565-59-3 1.25 6.71 8.375

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.41 33.972

t-2-Hexene 04050-45-7 8.55 5.98 51.126

3-Methyl-t-2-pentene 00616-12-6 11.66 5.34 62.218

Ethanol 00064-17-5 1.45 5.20 7.530

2-Methyl-2-pentene 00625-27-4 11.03 4.72 52.108

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.65 36.962

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.65 14.842

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.64 24.922

Cyclopentene 00142-29-0 6.69 4.64 31.029

3-Methyl-c-2-pentene 00922-62-3 12.52 4.35 54.439

2-Methylpropane 00075-28-5 1.18 4.18 4.921

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.77 24.888

1-Methylcyclopentene 00693-89-0 12.45 3.66 45.560

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.42 25.265

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 3.04 4.874

2,4-Dimethylhexane 00589-43-5 1.61 2.97 4.775

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.92 16.865

2,2,5-Trimethylhexane 03522-94-9 1.05 2.46 2.586

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.39 2.605

n-Heptane 00142-82-5 0.97 2.27 2.189

Vehicle 221b - Fuel 9 psi E0 - 105°F Static - Test 7652

Non Zero Mass Species Sorted By VOC
E-227

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 9 psi E0 - 105°F Static - Test 7652

Non Zero Mass Species Sorted By VOC

Methylcyclohexane 00108-87-2 1.56 2.27 3.525

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.24 9.822

ortho-Xylene 00095-47-6 7.58 2.18 16.550

2,2-Dimethylpentane 00590-35-2 1.04 1.89 1.969

t-1,2-Dimethylcyclopentane 00822-50-4 2.19 1.88 4.117

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.67 19.620

c-1,3-Dimethylcyclopentane 02532-58-3 2.19 1.55 3.401

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.20 6.668

2,2,3-Trimethylbutane 00464-06-2 1.05 1.18 1.241

Ethylbenzene 00100-41-4 2.96 1.17 3.466

4-Methyl-t-2-pentene 00674-76-0 8.04 1.15 9.273

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.86 5.413

2-Methylheptane 00592-27-8 0.97 0.84 0.809

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.81 9.717

3-Methylheptane 00589-81-1 1.12 0.80 0.904

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.71 5.575

3,3-Dimethylpentane 00562-49-2 1.12 0.69 0.777

n-Propylbenzene 00103-65-1 1.96 0.67 1.309

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.56 5.836

Unknown #1 2.19 0.49 1.079

n-Octane 00111-65-9 0.80 0.40 0.322

2,3,5-Trimethylhexane 01069-53-0 1.12 0.09 0.097

Total 1824.1 3993.6 2.189

No MIR available, use weighted average of 2.1894

continued
E-228

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Cyclohexane 00110-82-7 1.14 34.45 39.177

n-Butane 00106-97-8 1.08 32.29 34.777

2-Methylbutane (Isopentane) 00078-78-4 1.35 30.81 41.741

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 28.39 39.678

Toluene 00108-88-3 3.93 26.61 104.454

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 15.77 18.914

2,3-Dimethylbutane 00079-29-8 0.90 15.66 14.071

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.73 62.966

n-Pentane 00109-66-0 1.21 10.89 13.226

n-Hexane 00110-54-3 1.13 9.50 10.777

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 8.50 37.361

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.33 49.088

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 6.09 44.983

3-Methylpentane 00096-14-0 1.69 5.66 9.578

Benzene 00071-43-2 0.69 5.02 3.483

2,3,4-Trimethylpentane 00565-75-3 0.95 4.83 4.583

2,3-Dimethylpentane 00565-59-3 1.25 4.27 5.335

Methylcyclopentane 00096-37-7 2.05 3.70 7.591

2-Methyl-2-butene 00513-35-9 14.20 3.01 42.795

2-Methyl-1-butene 00563-46-2 6.38 2.95 18.815

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.89 33.783

2-Methylhexane 00591-76-4 1.09 2.88 3.123

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.65 31.164

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.58 14.295

2,4-Dimethylhexane 00589-43-5 1.61 2.56 4.103

2,4-Dimethylpentane 00108-08-7 1.46 2.30 3.354

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.15 14.180

t-2-Pentene 00646-04-8 10.47 1.82 19.081

Ethylbenzene 00100-41-4 2.96 1.78 5.272

3-Methylheptane 00589-81-1 1.12 1.75 1.966

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.70 5.414

2-Methylheptane 00592-27-8 0.97 1.66 1.607

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.53 18.249

n-Propylbenzene 00103-65-1 1.96 1.52 2.978

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.47 2.354

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.28 8.041

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.22 1.337

ortho-Xylene 00095-47-6 7.58 1.15 8.681

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.10 8.700

n-Heptane 00142-82-5 0.97 0.99 0.954

3-Methyl-c-2-pentene 00922-62-3 12.52 0.93 11.589

2,2,5-Trimethylhexane 03522-94-9 1.05 0.89 0.942

2-Methyl-2-pentene 00625-27-4 11.03 0.84 9.286

3-Methyl-t-2-pentene 00616-12-6 11.66 0.72 8.341

Vehicle 221b - Fuel 9 psi E0 - Dynamic - Test 25790

Non Zero Mass Species Sorted By VOC
E-229

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 9 psi E0 - Dynamic - Test 25790

Non Zero Mass Species Sorted By VOC

2,2-Dimethylpentane 00590-35-2 1.04 0.71 0.739

2,2-Dimethylbutane 00075-83-2 1.11 0.69 0.765

t-2-Hexene 04050-45-7 8.55 0.67 5.756

2,2-DiMeHexane 00590-73-8 0.94 0.65 0.611

1,3-Butadiene 00106-99-0 12.45 0.59 7.321

1-Methylcyclopentene 00693-89-0 12.45 0.43 5.374

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.42 4.417

Cyclopentene 00142-29-0 6.69 0.34 2.254

2,3,5-Trimethylhexane 01069-53-0 1.12 0.20 0.220

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.19 1.003

c-2-Pentene 00627-20-3 10.28 0.11 1.115

Total 311.8 851.8 2.732

continued
E-230

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 391.77 421.903

2-Methylbutane (Isopentane) 00078-78-4 1.35 291.96 395.579

Toluene 00108-88-3 3.93 149.99 588.714

Cyclohexane 00110-82-7 1.14 111.22 126.496

n-Hexane 00110-54-3 1.13 66.44 75.387

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 53.20 74.363

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 41.21 49.420

3-Methylpentane 00096-14-0 1.69 36.07 60.983

Benzene 00071-43-2 0.69 34.30 23.814

n-Pentane 00109-66-0 1.21 33.28 40.434

2-Methyl-2-butene 00513-35-9 14.20 32.16 456.446

t-2-Pentene 00646-04-8 10.47 28.33 296.746

2,3-Dimethylbutane 00079-29-8 0.90 26.75 24.037

Methylcyclopentane 00096-37-7 2.05 22.50 46.117

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 22.02 170.745

2,3,4-Trimethylpentane 00565-75-3 0.95 15.69 14.886

2-Methyl-1-butene 00563-46-2 6.38 14.69 93.703

c-2-Pentene 00627-20-3 10.28 13.83 142.219

2,4-Dimethylpentane 00108-08-7 1.46 11.90 17.361

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.74 52.287

2-Methylhexane 00591-76-4 1.09 9.69 10.513

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 9.48 110.908

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.14 67.516

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.54 27.262

2,3,5-Trimethylhexane 01069-53-0 1.12 8.51 9.529

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.43 44.676

2,3-Dimethylpentane 00565-59-3 1.25 8.42 10.515

c-2-Butene 00590-18-1 14.26 8.36 119.250

t-2-Hexene 04050-45-7 8.55 8.22 70.309

3-Methyl-t-2-pentene 00616-12-6 11.66 7.14 83.278

2,4-Dimethylhexane 00589-43-5 1.61 7.13 11.455

Ethylbenzene 00100-41-4 2.96 6.65 19.712

1-Methylcyclopentene 00693-89-0 12.45 5.80 72.203

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 5.74 36.175

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 5.53 8.883

3-Methyl-c-2-pentene 00922-62-3 12.52 5.49 68.775

2,2,5-Trimethylhexane 03522-94-9 1.05 5.33 5.609

Cyclopentene 00142-29-0 6.69 5.23 34.958

2-Methylpropane 00075-28-5 1.18 5.09 5.985

2-Methyl-2-pentene 00625-27-4 11.03 5.05 55.729

n-Heptane 00142-82-5 0.97 5.01 4.837

ortho-Xylene 00095-47-6 7.58 4.99 37.775

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.88 32.261

4-Methyl-t-2-pentene 00674-76-0 8.04 4.19 33.668

Vehicle 221b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7667

Non Zero Mass Species Sorted By VOC
E-231

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7667

Non Zero Mass Species Sorted By VOC

2,2-Dimethylbutane 00075-83-2 1.11 4.18 4.642

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.96 4.324

Methylcyclohexane 00108-87-2 1.56 3.59 5.580

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.43 40.267

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.23 25.667

Ethanol 00064-17-5 1.45 2.91 4.215

Propane 00074-98-6 0.46 2.77 1.265

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.42 13.969

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.30 12.728

t-1,2-Dimethylcyclopentane 00822-50-4 2.68 2.12 5.690

n-Propylbenzene 00103-65-1 1.96 2.07 4.056

c-2-Heptene 06443-92-1 7.08 1.79 12.655

2,2-Dimethylpentane 00590-35-2 1.04 1.74 1.814

c-1,3-Dimethylcyclopentane 02532-58-3 2.68 1.72 4.609

2-Methylheptane 00592-27-8 0.97 1.70 1.647

3-Methylheptane 00589-81-1 1.12 1.53 1.716

Indan 00496-11-7 3.23 1.44 4.665

n-Octane 00111-65-9 0.80 1.38 1.098

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.21 9.514

Unknown #16 2.68 0.98 2.627

n-Decane 00124-18-5 0.59 0.93 0.551

2,2,3-Trimethylbutane 00464-06-2 1.05 0.88 0.929

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.85 10.147

Unknown #5 2.68 0.84 2.247

3,3-Dimethylpentane 00562-49-2 1.12 0.81 0.903

Isopropylbenzene (Cumene) 00098-82-8 2.68 0.81 2.159

Unknown #1 2.68 0.71 1.896

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.66 2.549

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.62 6.448

3,5-Dimethylheptane 00926-82-9 1.42 0.53 0.762

c-1,3-Dimethylcyclohexane 00638-04-0 2.68 0.49 1.302

1-Nonene 00124-11-8 2.49 0.47 1.166

2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.30 0.257

t-3-Heptene 14686-14-7 6.17 0.29 1.805

Unknown #9 2.68 0.28 0.744

1,4-Diethylbenzene 00105-05-5 4.39 0.26 1.162

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.22 1.849

3,3-Dimethylhexane 00563-16-6 1.15 0.20 0.226

n-Nonane 00111-84-2 0.68 0.14 0.098

Total 1625.8 4353.4 2.678

No MIR available, use weighted average of 2.6776

continued
E-232

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 353.11 478.423

n-Butane 00106-97-8 1.08 239.03 257.412

Cyclohexane 00110-82-7 1.14 69.24 78.747

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 50.17 70.124

n-Hexane 00110-54-3 1.13 36.39 41.296

n-Pentane 00109-66-0 1.21 31.28 38.004

Toluene 00108-88-3 3.93 29.62 116.252

2,3-Dimethylbutane 00079-29-8 0.90 29.50 26.514

3-Methylpentane 00096-14-0 1.69 28.09 47.498

2-Methyl-2-butene 00513-35-9 14.20 25.04 355.396

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 21.13 25.335

t-2-Pentene 00646-04-8 10.47 19.17 200.764

Methylcyclopentane 00096-37-7 2.05 13.81 28.309

2-Methyl-1-butene 00563-46-2 6.38 13.42 85.617

c-2-Pentene 00627-20-3 10.28 10.68 109.799

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.33 68.913

Benzene 00071-43-2 0.69 8.77 6.091

2,4-Dimethylpentane 00108-08-7 1.46 7.87 11.484

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.55 88.328

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.77 52.471

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.25 33.583

c-2-Butene 00590-18-1 14.26 5.84 83.339

2,2-Dimethylbutane 00075-83-2 1.11 5.77 6.410

2,3,4-Trimethylpentane 00565-75-3 0.95 5.63 5.341

2-Methylpropane 00075-28-5 1.18 5.19 6.112

2-Methylhexane 00591-76-4 1.09 4.79 5.194

2,3-Dimethylpentane 00565-59-3 1.25 4.64 5.797

2,4-Dimethylheptane 02213-23-2 1.26 4.19 5.297

t-2-Hexene 04050-45-7 8.55 4.12 35.227

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 4.09 21.663

3-Methyl-t-2-pentene 00616-12-6 11.66 4.07 47.420

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.64 28.886

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.39 10.817

2-Methyl-2-pentene 00625-27-4 11.03 3.26 35.990

Cyclopentene 00142-29-0 6.69 3.17 21.193

3-Methyl-c-2-pentene 00922-62-3 12.52 3.06 38.350

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.81 18.539

2,4-Dimethylhexane 00589-43-5 1.61 2.61 4.194

1,3,5-Trimethylbenzene 00108-67-8 11.75 2.37 27.849

1-Methylcyclopentene 00693-89-0 12.45 2.37 29.494

2,2,5-Trimethylhexane 03522-94-9 1.05 2.29 2.413

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.20 9.687

3-Methyl-1-butene 00563-45-1 6.85 2.16 14.823

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.15 12.430

Vehicle 221b - Fuel 7 psi E0 - 86°F Static - Test 7691

Non Zero Mass Species Sorted By VOC
E-233

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E0 - 86°F Static - Test 7691

Non Zero Mass Species Sorted By VOC

3,3-Dimethylhexane 00563-16-6 1.15 2.07 2.386

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.75 2.813

ortho-Xylene 00095-47-6 7.58 1.60 12.131

n-Heptane 00142-82-5 0.97 1.57 1.516

Ethylbenzene 00100-41-4 2.96 1.45 4.299

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.30 7.189

t-1,2-Dimethylcyclopentane 00822-50-4 2.46 1.15 2.832

2,2-Dimethylpentane 00590-35-2 1.04 1.08 1.131

2-Methylheptane 00592-27-8 0.97 1.08 1.040

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.07 12.797

Propane 00074-98-6 0.46 1.01 0.462

c-1,3-Dimethylcyclopentane 02532-58-3 2.46 0.95 2.341

n-Propylbenzene 00103-65-1 1.96 0.88 1.727

2,2,3-Trimethylbutane 00464-06-2 1.05 0.79 0.837

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.70 0.767

Methylcyclohexane 00108-87-2 1.56 0.58 0.898

3,3-Dimethylpentane 00562-49-2 1.12 0.50 0.564

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.45 3.536

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.40 4.224

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.35 2.183

3-Methylheptane 00589-81-1 1.12 0.33 0.370

2,3,5-Trimethylhexane 01069-53-0 1.12 0.32 0.361

n-Octane 00111-65-9 0.80 0.24 0.191

4-Methyl-t-2-pentene 00674-76-0 8.04 0.17 1.380

Total 1121.8 2764.8 2.465

No MIR available, use weighted average of 2.4645

continued
E-234

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 424.48 575.119

n-Butane 00106-97-8 1.08 264.00 284.303

Cyclohexane 00110-82-7 1.14 120.32 136.846

Toluene 00108-88-3 3.93 69.41 272.440

Unknown #2 2.61 63.63 166.355

n-Hexane 00110-54-3 1.13 57.55 65.305

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 47.69 57.184

3-Methylpentane 00096-14-0 1.69 43.68 73.864

n-Pentane 00109-66-0 1.21 39.63 48.144

2,3-Dimethylbutane 00079-29-8 0.90 39.00 35.047

2-Methyl-2-butene 00513-35-9 14.20 31.47 446.654

t-2-Pentene 00646-04-8 10.47 24.83 260.030

Methylcyclopentane 00096-37-7 2.05 22.35 45.814

2-Methyl-1-butene 00563-46-2 6.38 16.53 105.461

2,3,4-Trimethylpentane 00565-75-3 0.95 16.31 15.471

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.33 76.946

Benzene 00071-43-2 0.69 14.31 9.935

2,4-Dimethylpentane 00108-08-7 1.46 13.68 19.967

c-2-Pentene 00627-20-3 10.28 13.19 135.562

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 10.76 83.472

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 10.04 117.496

2,3-Dimethylpentane 00565-59-3 1.25 9.39 11.716

2-Methylhexane 00591-76-4 1.09 9.39 10.185

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 8.53 63.011

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.44 26.917

2,2-Dimethylbutane 00075-83-2 1.11 7.24 8.050

2,4-Dimethylhexane 00589-43-5 1.61 6.89 11.066

c-2-Butene 00590-18-1 14.26 6.52 93.031

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.46 34.232

2,2,5-Trimethylhexane 03522-94-9 1.05 6.42 6.757

t-2-Hexene 04050-45-7 8.55 6.30 53.899

3-Methyl-t-2-pentene 00616-12-6 11.66 6.10 71.088

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.90 25.924

3-Methyl-c-2-pentene 00922-62-3 12.52 4.96 62.136

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.91 7.883

2-Methylpropane 00075-28-5 1.18 4.79 5.636

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.70 55.274

Cyclopentene 00142-29-0 6.69 4.46 29.822

2-Methyl-2-pentene 00625-27-4 11.03 4.38 48.341

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.37 34.694

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.17 23.083

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.98 26.304

1-Methylcyclopentene 00693-89-0 12.45 3.98 49.558

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.85 4.204

Vehicle 221b - Fuel 7 psi E0 - 105°F Static - Test 7692

Non Zero Mass Species Sorted By VOC
E-235

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E0 - 105°F Static - Test 7692

Non Zero Mass Species Sorted By VOC

n-Heptane 00142-82-5 0.97 3.71 3.583

ortho-Xylene 00095-47-6 7.58 3.15 23.847

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.90 16.778

1,2,3-Trimethylbenzene 00526-73-8 11.94 2.75 32.824

3-Methyl-1-butene 00563-45-1 6.85 2.69 18.437

1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.64 18.691

Methylcyclohexane 00108-87-2 1.56 2.58 4.017

Indan 00496-11-7 3.23 2.50 8.071

1,4-Diethylbenzene 00105-05-5 4.39 2.36 10.359

n-Propylbenzene 00103-65-1 1.96 2.31 4.534

t-1,2-Dimethylcyclopentane 00822-50-4 2.61 2.19 5.728

Unknown #16 2.61 2.03 5.297

2,2-Dimethylpentane 00590-35-2 1.04 1.98 2.070

c-1,3-Dimethylcyclopentane 02532-58-3 2.61 1.80 4.702

Ethylbenzene 00100-41-4 2.96 1.62 4.800

3-Methylheptane 00589-81-1 1.12 1.52 1.712

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.37 10.715

2,2,3-Trimethylbutane 00464-06-2 1.05 1.34 1.409

4-Methyl-t-2-pentene 00674-76-0 8.04 1.21 9.694

2-Methylheptane 00592-27-8 0.97 1.18 1.138

2,3,5-Trimethylhexane 01069-53-0 1.12 1.06 1.189

3,5-Dimethylheptane 00926-82-9 1.42 0.97 1.381

1,3-Diethylbenzene 00141-93-5 7.08 0.94 6.636

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.94 5.895

1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.90 4.890

n-Octane 00111-65-9 0.80 0.86 0.688

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.86 8.744

3,3-Dimethylpentane 00562-49-2 1.12 0.86 0.962

Unknown #5 2.61 0.85 2.219

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.80 5.997

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.79 5.948

Isopropylbenzene (Cumene) 00098-82-8 2.61 0.74 1.922

3-Methyloctane 02216-33-3 0.88 0.73 0.650

1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.67 5.063

c-2-Heptene 06443-92-1 7.08 0.63 4.425

1-Nonene 00124-11-8 2.49 0.58 1.440

2,4-Dimethylheptane 02213-23-2 1.26 0.55 0.702

1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 0.55 5.073

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.55 2.107

1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.52 2.002

c-1,3-Dimethylcyclohexane 00638-04-0 2.61 0.50 1.304

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.47 3.094

continued
E-236

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E0 - 105°F Static - Test 7692

Non Zero Mass Species Sorted By VOC

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.44 4.638

sec-Butylbenzene 00135-98-8 2.29 0.44 1.005

3-Methylnonane 2.61 0.42 1.101

Isobutylbenzene 00538-93-2 2.61 0.41 1.070

Unknown #3 2.61 0.36 0.951

1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.29 2.718

t-3-Heptene 14686-14-7 6.17 0.28 1.725

3,3-Dimethylhexane 00563-16-6 1.15 0.27 0.316

t-2-Nonene 06434-78-2 2.61 0.27 0.706

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.27 2.630

n-Nonane 00111-84-2 0.68 0.24 0.165

Unknown #8 2.61 0.23 0.610

n-Undecane 01120-21-4 0.52 0.22 0.115

Unknown #13 2.61 0.18 0.466

n-Decane 00124-18-5 0.59 0.18 0.104

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.15 0.172

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.61 0.13 0.333

Total 1558.2 4073.8 2.614

No MIR available, use weighted average of 2.6144

continued
E-237

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 25.19 98.866

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 21.01 155.169

2-Methylbutane (Isopentane) 00078-78-4 1.35 20.87 28.280

n-Butane 00106-97-8 1.08 13.42 14.448

Cyclohexane 00110-82-7 1.14 12.89 14.657

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.57 62.112

Unknown #2 4.30 10.80 46.422

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.41 65.248

1,3,5-Trimethylbenzene 00108-67-8 11.75 7.39 86.814

n-Hexane 00110-54-3 1.13 6.01 6.823

Cyclopentane 00287-92-3 2.24 5.80 12.966

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.29 6.344

Benzene 00071-43-2 0.69 3.83 2.662

n-Pentane 00109-66-0 1.21 3.24 3.933

ortho-Xylene 00095-47-6 7.58 2.91 22.066

Ethylbenzene 00100-41-4 2.96 2.80 8.281

3-Methylpentane 00096-14-0 1.69 2.65 4.482

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.51 13.908

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.51 11.027

4-Methyl-t-2-pentene 00674-76-0 8.04 2.42 19.467

n-Propylbenzene 00103-65-1 1.96 2.40 4.694

2-Methyl-2-butene 00513-35-9 14.20 2.30 32.658

n-Heptane 00142-82-5 0.97 2.27 2.193

Methylcyclopentane 00096-37-7 2.05 2.25 4.618

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.83 14.570

Methylcyclohexane 00108-87-2 1.56 1.73 2.691

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.66 10.990

2,3,4-Trimethylpentane 00565-75-3 0.95 1.57 1.494

2,4-Dimethylpentane 00108-08-7 1.46 1.42 2.070

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.36 16.265

2-Methyl-2-pentene 00625-27-4 11.03 1.33 14.635

3-Methyl-t-2-pentene 00616-12-6 11.66 1.28 14.976

c-2-Butene 00590-18-1 14.26 1.24 17.637

2-Methylhexane 00591-76-4 1.09 1.18 1.283

1-Methylcyclopentene 00693-89-0 12.45 1.07 13.316

2-Methyl-1-butene 00563-46-2 6.38 1.06 6.784

t-2-Hexene 04050-45-7 8.55 1.05 9.000

2,3-Dimethylpentane 00565-59-3 1.25 0.99 1.234

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.99 1.582

2,3,5-Trimethylhexane 01069-53-0 1.12 0.79 0.880

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.74 7.736

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.60 1.920

c-2-Pentene 00627-20-3 10.28 0.39 4.017

t-2-Pentene 00646-04-8 10.47 0.37 3.864

Vehicle 221b - Fuel 7 psi E0 - Dynamic - Test 25797

Non Zero Mass Species Sorted By VOC
E-238

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E0 - Dynamic - Test 25797

Non Zero Mass Species Sorted By VOC

2,2,5-Trimethylhexane 03522-94-9 1.05 0.35 0.368

2,2-Dimethylbutane 00075-83-2 1.11 0.09 0.099

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.09 0.096

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.08 0.980

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.06 0.335

Total 204.1 877.0 4.298

No MIR available, use weighted average of 4.2975

continued
E-239

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 331.35 448.947

n-Butane 00106-97-8 1.08 196.09 211.173

Toluene 00108-88-3 3.93 163.70 642.521

Cyclohexane 00110-82-7 1.14 150.06 170.677

n-Hexane 00110-54-3 1.13 81.40 92.365

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 67.99 95.037

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 46.75 56.065

3-Methylpentane 00096-14-0 1.69 44.37 75.032

n-Pentane 00109-66-0 1.21 40.94 49.745

2-Methyl-2-butene 00513-35-9 14.20 39.67 563.085

Benzene 00071-43-2 0.69 38.43 26.682

t-2-Pentene 00646-04-8 10.47 35.41 370.822

2,3-Dimethylbutane 00079-29-8 0.90 33.20 29.835

Methylcyclopentane 00096-37-7 2.05 28.54 58.502

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 19.67 152.524

2-Methyl-1-butene 00563-46-2 6.38 18.63 118.852

2,3,4-Trimethylpentane 00565-75-3 0.95 18.39 17.444

c-2-Pentene 00627-20-3 10.28 16.98 174.558

2,4-Dimethylpentane 00108-08-7 1.46 14.71 21.471

2-Methylhexane 00591-76-4 1.09 12.51 13.577

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.33 132.658

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 11.07 35.326

t-2-Hexene 04050-45-7 8.55 10.95 93.620

2,3-Dimethylpentane 00565-59-3 1.25 10.18 12.710

2,3,5-Trimethylhexane 01069-53-0 1.12 9.69 10.858

3-Methyl-t-2-pentene 00616-12-6 11.66 9.57 111.535

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 9.08 48.126

c-2-Butene 00590-18-1 14.26 8.88 126.689

Methylcyclohexane 00108-87-2 1.56 8.47 13.172

2,4-Dimethylhexane 00589-43-5 1.61 8.25 13.252

1-Methylcyclopentene 00693-89-0 12.45 8.00 99.614

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.16 38.440

3-Methyl-c-2-pentene 00922-62-3 12.52 7.15 89.462

2,2,5-Trimethylhexane 03522-94-9 1.05 6.83 7.194

Cyclopentene 00142-29-0 6.69 6.79 45.423

2-Methyl-2-pentene 00625-27-4 11.03 6.69 73.811

n-Heptane 00142-82-5 0.97 6.30 6.086

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.28 10.088

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.94 39.243

2,2-Dimethylbutane 00075-83-2 1.11 5.57 6.195

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.34 23.450

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.32 39.329

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.55 4.964

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.53 35.955

Vehicle 221b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7716

Non Zero Mass Species Sorted By VOC
E-240

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7716

Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 4.42 33.470

Ethanol 00064-17-5 1.45 4.18 6.063

Ethylbenzene 00100-41-4 2.96 3.64 10.793

t-1,2-Dimethylcyclopentane 00822-50-4 2.88 3.01 8.650

2-Methylpropane 00075-28-5 1.18 2.94 3.457

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.89 16.719

c-1,3-Dimethylcyclopentane 02532-58-3 2.88 2.38 6.852

3-Methylheptane 00589-81-1 1.12 2.31 2.599

n-Propylbenzene 00103-65-1 1.96 2.00 3.927

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.99 11.025

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.99 23.385

2,2-Dimethylpentane 00590-35-2 1.04 1.94 2.028

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.86 14.558

Propane 00074-98-6 0.46 1.73 0.792

n-Octane 00111-65-9 0.80 1.50 1.198

2-Methylheptane 00592-27-8 0.97 1.49 1.445

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.31 15.644

2,2,3-Trimethylbutane 00464-06-2 1.05 1.17 1.236

Unknown #5 2.88 1.17 3.358

Unknown #16 2.88 1.03 2.969

3,3-Dimethylpentane 00562-49-2 1.12 1.03 1.151

c-1,3-Dimethylcyclohexane 00638-04-0 2.88 0.99 2.849

Isopropylbenzene (Cumene) 00098-82-8 2.88 0.99 2.837

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.86 3.327

n-Decane 00124-18-5 0.59 0.82 0.487

c-2-Heptene 06443-92-1 7.08 0.82 5.775

Unknown #1 2.88 0.80 2.302

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.78 6.535

Indan 00496-11-7 3.23 0.77 2.482

3,5-Dimethylheptane 00926-82-9 1.42 0.75 1.061

1,4-Diethylbenzene 00105-05-5 4.39 0.70 3.062

4-Methyloctane 02216-34-4 0.85 0.70 0.592

3-Methyloctane 02216-33-3 0.88 0.68 0.603

Styrene 00100-42-5 1.66 0.67 1.111

Unknown #8 2.88 0.63 1.802

1-Nonene 00124-11-8 2.49 0.56 1.386

t-3-Heptene 14686-14-7 6.17 0.54 3.357

3,3-Dimethylhexane 00563-16-6 1.15 0.49 0.565

1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.48 4.882

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.40 2.620

n-Nonane 00111-84-2 0.68 0.38 0.260

2,4-Dimethylheptane 02213-23-2 1.26 0.35 0.447

continued

continued
E-241

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 221b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7716

Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 0.34 0.178

1-Heptene 00592-76-7 4.29 0.28 1.188

Unknown #3 2.88 0.22 0.619

1,1-Dimethylcyclohexane 00590-66-9 1.12 0.17 0.185

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.88 0.16 0.462

t-4-Octene 14850-23-8 4.69 0.12 0.553

Total 1644.2 4729.0 2.876

No MIR available, use weighted average of 2.8762
E-242

Test Fuel Test No.

Bag

THC

 mg

GC as

% of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86° F E10 - 10 psi 7552 12.2 212.7 26.0 76.7 2.953 21

Static E10 - 7 psi 7576 28.2 95.7 27.0 73.7 2.729 29

E0 - 9 psi 7655 6.4 79.8 5.1 28.5 5.617 10

E0 - 7 psi 7712 7.0 215.7 15.1 59.6 3.957 24

105° F E10 - 10 psi 7554 20.6 163.4 33.7 119.6 3.545 32

Static E10 - 7 psi 7578 28.9 111.3 32.1 134.5 4.189 41

E0 - 9 psi 7659 11.7 180.8 21.2 100.3 4.734 46

E0 - 7 psi 7715 14.0 228.9 32.1 165.4 5.146 43

Dynamic E10 - 10 psi 25779 73.3 30.1 22.1 54.9 2.488 22

E10 - 7 psi 25785 51.6 66.8 34.5 81.1 2.351 21

E0 - 9 psi 25791 33.5 145.1 48.6 231.3 4.759 19

E0 - 7 psi 25808 97.2 72.7 70.6 220.5 3.122 39

DHB E10 - 10 psi 7558 257.2 70.4 181.0 525.8 2.905 68

Total E10 - 7 psi 7580 287.6 93.6 269.1 853.3 3.171 66

E0 - 9 psi 7696 177.2 95.4 169.1 728.2 4.307 64

E0 - 7 psi 7742 136.4 67.5 92.1 286.4 3.111 47

Vehicle 222b
E-243

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 3.93 11.33 44.477

n-Hexane 00110-54-3 1.13 1.49 1.687

n-Pentane 00109-66-0 1.21 1.32 1.607

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.30 1.557

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.25 1.750

Benzene 00071-43-2 0.69 1.19 0.823

Cyclohexane 00110-82-7 1.14 1.07 1.216

2,3,3-Trimethylpentane 00560-21-4 0.95 0.71 0.673

3-Methylpentane 00096-14-0 1.69 0.70 1.187

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.69 2.217

2-Methylhexane 00591-76-4 1.09 0.66 0.713

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.60 4.685

Methylcyclopentane 00096-37-7 2.05 0.59 1.210

2-Methylbutane (Isopentane) 00078-78-4 1.35 0.57 0.770

2,3-Dimethylpentane 00565-59-3 1.25 0.48 0.596

2,4-Dimethylpentane 00108-08-7 1.46 0.42 0.610

2,3-Dimethylbutane 00079-29-8 0.90 0.41 0.372

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.38 2.425

2-Methyl-1-butene 00563-46-2 6.38 0.30 1.885

t-2-Pentene 00646-04-8 10.47 0.27 2.866

2-Methyl-2-butene 00513-35-9 14.20 0.24 3.340

Total 26.0 76.7 2.953

Vehicle 222b - Fuel 10 psi E10 - 86°F Static - Test 7552

Non Zero Mass Species Sorted By VOC
E-244

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 1.45 4.92 7.125

n-Butane 00106-97-8 1.08 3.90 4.200

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.99 13.133

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.83 15.207

Toluene 00108-88-3 3.93 2.21 8.674

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.91 14.814

n-Hexane 00110-54-3 1.13 1.28 1.449

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.12 1.339

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.10 12.894

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.93 1.300

n-Pentane 00109-66-0 1.21 0.90 1.096

ortho-Xylene 00095-47-6 7.58 0.83 6.310

Benzene 00071-43-2 0.69 0.72 0.500

3-Methylpentane 00096-14-0 1.69 0.69 1.173

Cyclohexane 00110-82-7 1.14 0.65 0.736

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.60 3.313

4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.58 2.573

2,2-DiMeHexane 00590-73-8 0.94 0.55 0.519

Ethylbenzene 00100-41-4 2.96 0.54 1.595

2,3,3-Trimethylpentane 00560-21-4 0.95 0.52 0.487

n-Propylbenzene 00103-65-1 1.96 0.49 0.960

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.44 1.405

Methylcyclopentane 00096-37-7 2.05 0.43 0.884

2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.42 3.265

t-2-Pentene 00646-04-8 10.47 0.39 4.041

2-Methyl-2-butene 00513-35-9 14.20 0.35 4.951

2,3-Dimethylbutane 00079-29-8 0.90 0.34 0.302

2,4-Dimethylpentane 00108-08-7 1.46 0.31 0.459

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.31 1.930

c-2-Pentene 00627-20-3 10.28 0.26 2.662

2-Methylhexane 00591-76-4 1.09 0.20 0.222

2-Methylbutane (Isopentane) 00078-78-4 1.35 0.03 0.044

Total 33.7 119.6 3.545

Vehicle 222b - Fuel 10 psi E10 - 105°F Static - Test 7554

Non Zero Mass Species Sorted By VOC
E-245

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2,4-Dimethylhexane 00589-43-5 1.61 2.97 4.776

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.81 3.364

2,3,5-Trimethylhexane 01069-53-0 1.12 2.16 2.419

c-2-Pentene 00627-20-3 10.28 2.00 20.515

2,2,5-Trimethylhexane 03522-94-9 1.05 1.70 1.792

2,3-Dimethylbutane 00079-29-8 0.90 1.55 1.394

2-Methylbutane (Isopentane) 00078-78-4 1.35 1.52 2.055

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.13 1.816

2,3,4-Trimethylpentane 00565-75-3 0.95 0.92 0.871

n-Pentane 00109-66-0 1.21 0.65 0.786

2-Methylhexane 00591-76-4 1.09 0.62 0.676

Ethanol 00064-17-5 1.45 0.56 0.816

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.56 1.782

Benzene 00071-43-2 0.69 0.55 0.384

ortho-Xylene 00095-47-6 7.58 0.44 3.299

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.37 0.512

t-2-Pentene 00646-04-8 10.47 0.35 3.635

2,3-Dimethylpentane 00565-59-3 1.25 0.34 0.429

2-Methyl-1-butene 00563-46-2 6.38 0.33 2.075

Toluene 00108-88-3 3.93 0.24 0.929

3-Methylpentane 00096-14-0 1.69 0.22 0.364

Methylcyclopentane 00096-37-7 2.05 0.08 0.173

Total 22.1 54.9 2.488

Vehicle 222b - Fuel 10 psi E10 - Dynamic - Test 25779

Non Zero Mass Species Sorted By VOC
E-246

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 40.78 55.250

Ethanol 00064-17-5 1.45 23.27 33.720

n-Butane 00106-97-8 1.08 21.95 23.642

Toluene 00108-88-3 3.93 11.56 45.359

n-Pentane 00109-66-0 1.21 5.85 7.110

n-Hexane 00110-54-3 1.13 5.15 5.844

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.39 39.620

Cyclohexane 00110-82-7 1.14 3.32 3.772

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.28 3.929

Benzene 00071-43-2 0.69 3.25 2.257

2,2-DiMeHexane 00590-73-8 0.94 3.21 3.019

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.13 4.377

t-2-Pentene 00646-04-8 10.47 2.77 29.061

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.70 19.972

2-Methyl-2-butene 00513-35-9 14.20 2.54 36.085

3-Methylpentane 00096-14-0 1.69 2.36 3.987

2-Methyl-1-butene 00563-46-2 6.38 2.32 14.800

1-Butyne 00107-00-6 6.05 2.25 13.628

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.20 17.064

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.78 9.562

Methylcyclopentane 00096-37-7 2.05 1.74 3.560

2,3-Dimethylbutane 00079-29-8 0.90 1.63 1.467

c-2-Pentene 00627-20-3 10.28 1.56 16.016

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.29 15.193

2,3,4-Trimethylpentane 00565-75-3 0.95 1.29 1.226

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.24 3.948

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.17 6.503

Methylcyclohexane 00108-87-2 1.56 1.17 1.812

2,4-Dimethylpentane 00108-08-7 1.46 1.15 1.680

2,3-Dimethylpentane 00565-59-3 1.25 1.11 1.384

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.01 8.015

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.95 4.161

2-Methylhexane 00591-76-4 1.09 0.93 1.011

c-2-Butene 00590-18-1 14.26 0.90 12.800

n-Heptane 00142-82-5 0.97 0.90 0.865

n-Decane 00124-18-5 0.59 0.87 0.514

ortho-Xylene 00095-47-6 7.58 0.82 6.192

2,3,5-Trimethylhexane 01069-53-0 1.12 0.77 0.865

2,2,5-Trimethylhexane 03522-94-9 1.05 0.77 0.808

2,4-Dimethylhexane 00589-43-5 1.61 0.75 1.208

3-Methyl-c-2-pentene 00922-62-3 12.52 0.75 9.327

t-2-Hexene 04050-45-7 8.55 0.70 6.011

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.64 0.702

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.63 3.364

Vehicle 222b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7558

Non Zero Mass Species Sorted By VOC
E-247

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 222b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7558

Non Zero Mass Species Sorted By VOC

1,3-Butadiene 00106-99-0 12.45 0.58 7.233

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.57 0.922

Indan 00496-11-7 3.23 0.56 1.819

3-Methyl-t-2-pentene 00616-12-6 11.66 0.55 6.363

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.53 3.501

n-Octane 00111-65-9 0.80 0.51 0.404

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.50 5.973

n-Propylbenzene 00103-65-1 1.96 0.50 0.977

2-Methylheptane 00592-27-8 0.97 0.47 0.459

Ethylbenzene 00100-41-4 2.96 0.45 1.330

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.41 3.126

2,2-Dimethylbutane 00075-83-2 1.11 0.38 0.424

2-Methyl-2-pentene 00625-27-4 11.03 0.37 4.110

c-1,3-Dimethylcyclopentane 02532-58-3 2.90 0.37 1.082

2,2-Dimethylpentane 00590-35-2 1.04 0.36 0.374

3,3-Dimethylpentane 00562-49-2 1.12 0.33 0.366

Cyclopentene 00142-29-0 6.69 0.32 2.143

t-1,2-Dimethylcyclopentane 00822-50-4 2.90 0.26 0.760

3-Methylheptane 00589-81-1 1.12 0.24 0.270

2,2,3-Trimethylbutane 00464-06-2 1.05 0.21 0.226

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.21 1.484

4-Methyl-t-2-pentene 00674-76-0 8.04 0.17 1.392

1-Dodecene 00112-41-4 1.56 0.17 0.265

n-Undecane 01120-21-4 0.52 0.17 0.087

Total 181.0 525.8 2.905

No MIR available, use weighted average of 2.9048

continued
E-248

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 9.028 12.231

n-Butane 00106-97-8 1.08 4.627 4.983

Ethanol 00064-17-5 1.45 2.319 3.360

Unknown #2 2.73 1.701 4.641

3-Methylnonane 05911-04-6 0.66 1.336 0.876

n-Pentane 00109-66-0 1.21 1.297 1.576

Toluene 00108-88-3 3.93 0.916 3.596

2-Methyl-2-butene 00513-35-9 14.20 0.758 10.755

2-Methyl-1-butene 00563-46-2 6.38 0.691 4.410

t-2-Pentene 00646-04-8 10.47 0.636 6.661

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.464 5.431

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.448 3.477

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.408 4.797

ortho-Xylene 00095-47-6 7.58 0.281 2.125

2,3-Dimethylpentane 00565-59-3 1.25 0.274 0.342

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.268 1.485

2,4-Dimethylpentane 00108-08-7 1.46 0.230 0.336

2-Methylhexane 00591-76-4 1.09 0.225 0.244

2,2-Dimethylbutane 00075-83-2 1.11 0.204 0.226

Methylcyclopentane 00096-37-7 2.05 0.193 0.396

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.159 0.507

Benzene 00071-43-2 0.69 0.116 0.080

n-Hexane 00110-54-3 1.13 0.104 0.118

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.094 0.112

c-2-Pentene 00627-20-3 10.28 0.072 0.739

n-Undecane 01120-21-4 0.52 0.071 0.037

Cyclohexane 00110-82-7 1.14 0.054 0.061

Ethylbenzene 00100-41-4 2.96 0.026 0.078

3-Methylpentane 00096-14-0 1.69 0.005 0.009

Total 27.0 73.7 2.729

No MIR available, use weighted average of 2.7288

Vehicle 222b - Fuel 7 psi E10 - 86°F Static - Test 7576

Non Zero Mass Species Sorted By VOC
E-249

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 7.67 10.390

Ethanol 00064-17-5 1.45 4.52 6.543

n-Butane 00106-97-8 1.08 2.20 2.375

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.75 12.892

n-Pentane 00109-66-0 1.21 1.63 1.981

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.48 17.289

Toluene 00108-88-3 3.93 1.24 4.862

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.03 12.159

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.01 4.442

t-2-Pentene 00646-04-8 10.47 0.94 9.838

2-Methyl-2-butene 00513-35-9 14.20 0.92 13.031

2-Methyl-1-butene 00563-46-2 6.38 0.82 5.243

1-Butyne 00107-00-6 6.05 0.69 4.202

Unknown #22 . 4.19 0.61 2.557

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.59 7.017

c-2-Butene 00590-18-1 14.26 0.53 7.609

n-Hexane 00110-54-3 1.13 0.45 0.505

c-2-Pentene 00627-20-3 10.28 0.39 4.061

2,3,5-Trimethylhexane 01069-53-0 1.12 0.39 0.433

2,2-DiMeHexane 00590-73-8 0.94 0.38 0.354

n-Undecane 01120-21-4 0.52 0.36 0.190

n-Propylbenzene 00103-65-1 1.96 0.33 0.652

Methylcyclohexane 00108-87-2 1.56 0.23 0.354

ortho-Xylene 00095-47-6 7.58 0.20 1.538

1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.19 1.469

2,2-Dimethylbutane 00075-83-2 1.11 0.19 0.206

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.16 0.265

2,3-Dimethylbutane 00079-29-8 0.90 0.15 0.138

Methylcyclopentane 00096-37-7 2.05 0.14 0.297

n-Heptane 00142-82-5 0.97 0.14 0.140

Benzene 00071-43-2 0.69 0.14 0.098

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.14 0.193

Ethylbenzene 00100-41-4 2.96 0.13 0.392

Cyclohexane 00110-82-7 1.14 0.10 0.118

3-Methylpentane 00096-14-0 1.69 0.07 0.116

2,3-Dimethylpentane 00565-59-3 1.25 0.07 0.086

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.04 0.305

2,3,4-Trimethylpentane 00565-75-3 0.95 0.04 0.036

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.03 0.158

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.01 0.006

2,4-Dimethylpentane 00108-08-7 1.46 0.01 0.008

Total 32.1 134.5 4.189

No MIR available, use weighted average of 4.1888

Vehicle 222b - Fuel 7 psi E10 - 105°F Static - Test 7578

Non Zero Mass Species Sorted By VOC
E-250

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Propylbenzene 00103-65-1 1.96 10.83 21.219

Ethanol 00064-17-5 1.45 5.29 7.670

Unknown #22 . 2.35 2.68 6.291

Toluene 00108-88-3 3.93 2.66 10.434

2,3,5-Trimethylhexane 01069-53-0 1.12 2.26 2.532

n-Decane 00124-18-5 0.59 1.42 0.839

n-Octane 00111-65-9 0.80 1.15 0.919

2-Methylheptane 00592-27-8 0.97 1.09 1.053

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.05 5.803

Indan 00496-11-7 3.23 0.96 3.105

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.93 4.984

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.85 0.928

n-Heptane 00142-82-5 0.97 0.77 0.748

Benzene 00071-43-2 0.69 0.69 0.478

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.64 7.554

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.60 4.395

Ethylbenzene 00100-41-4 2.96 0.31 0.916

ortho-Xylene 00095-47-6 7.58 0.14 1.038

2,2,5-Trimethylhexane 03522-94-9 1.05 0.13 0.137

2,3-Dimethylbutane 00079-29-8 0.90 0.02 0.019

2-Methylhexane 00591-76-4 1.09 0.02 0.023

Total 34.5 81.1 2.351

No MIR available, use weighted average of 2.3514

Vehicle 222b - Fuel 7 psi E10 - Dynamic - Test 25785

Non Zero Mass Species Sorted By VOC
E-251

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 92.55 125.393

Ethanol 00064-17-5 1.45 37.91 54.925

n-Pentane 00109-66-0 1.21 21.15 25.692

2-Methyl-2-butene 00513-35-9 14.20 10.63 150.891

t-2-Pentene 00646-04-8 10.47 10.13 106.146

Toluene 00108-88-3 3.93 9.02 35.392

n-Butane 00106-97-8 1.08 8.38 9.026

2-Methyl-1-butene 00563-46-2 6.38 7.59 48.406

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 5.40 63.239

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.40 7.545

n-Hexane 00110-54-3 1.13 5.15 5.840

c-2-Pentene 00627-20-3 10.28 5.02 51.574

Benzene 00071-43-2 0.69 3.58 2.484

2,2-DiMeHexane 00590-73-8 0.94 3.53 3.322

2,3-Dimethylbutane 00079-29-8 0.90 3.29 2.954

Methylcyclopentane 00096-37-7 2.05 2.78 5.694

3-Methylpentane 00096-14-0 1.69 2.68 4.528

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.45 18.079

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.29 2.748

Cyclohexane 00110-82-7 1.14 1.73 1.972

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.39 10.766

3-Methyl-c-2-pentene 00922-62-3 12.52 1.28 16.079

2,3,5-Trimethylhexane 01069-53-0 1.12 1.26 1.413

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.14 9.033

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.10 3.503

2-Methylhexane 00591-76-4 1.09 1.08 1.174

2,3,4-Trimethylpentane 00565-75-3 0.95 1.01 0.957

2,4-Dimethylpentane 00108-08-7 1.46 0.99 1.447

Methylcyclohexane 00108-87-2 1.56 0.94 1.470

c-2-Butene 00590-18-1 14.26 0.93 13.274

2,2-Dimethylbutane 00075-83-2 1.11 0.90 0.998

2-Methylheptane 00592-27-8 0.97 0.86 0.834

Cyclopentene 00142-29-0 6.69 0.86 5.733

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.81 4.328

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.80 4.634

n-Heptane 00142-82-5 0.97 0.75 0.725

2,2,3-Trimethylbutane 00464-06-2 1.05 0.75 0.786

t-2-Hexene 04050-45-7 8.55 0.74 6.294

n-Decane 00124-18-5 0.59 0.72 0.425

2,3-Dimethylpentane 00565-59-3 1.25 0.69 0.858

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.65 4.312

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.60 3.182

c-1,3-Dimethylcyclopentane 02532-58-3 3.17 0.60 1.904

3-Methyl-t-2-pentene 00616-12-6 11.66 0.57 6.636

Vehicle 222b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7580

Non Zero Mass Species Sorted By VOC
E-252

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 222b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7580

Non Zero Mass Species Sorted By VOC

2-Methyl-2-pentene 00625-27-4 11.03 0.56 6.222

Ethylbenzene 00100-41-4 2.96 0.52 1.552

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.50 0.551

n-Octane 00111-65-9 0.80 0.50 0.397

2,4-Dimethylhexane 00589-43-5 1.61 0.48 0.776

2,2,5-Trimethylhexane 03522-94-9 1.05 0.40 0.416

3,3-Dimethylpentane 00562-49-2 1.12 0.38 0.429

t-1,2-Dimethylcyclopentane 00822-50-4 3.17 0.38 1.198

1c-2t-3-TriMeCyPentane 15890-40-1 3.17 0.35 1.101

4-Methyl-t-2-pentene 00674-76-0 8.04 0.34 2.771

n-Propylbenzene 00103-65-1 1.96 0.34 0.658

3-Methylheptane 00589-81-1 1.12 0.33 0.366

ortho-Xylene 00095-47-6 7.58 0.27 2.025

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.25 0.401

Indan 00496-11-7 3.23 0.24 0.792

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.24 1.042

c-1,3-Dimethylcyclohexane 00638-04-0 3.17 0.20 0.642

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.20 2.083

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.17 0.953

n-Nonane 00111-84-2 0.68 0.14 0.094

1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.13 0.886

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.11 1.344

Total 269.1 853.3 3.171

No MIR available, use weighted average of 3.1711

continued
E-253

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Toluene 00108-88-3 1.46 0.92 1.336

2-Methyl-2-butene 00513-35-9 14.20 0.69 9.865

t-2-Pentene 00646-04-8 10.47 0.67 6.987

2,2-Dimethylbutane 00075-83-2 1.11 0.62 0.689

c-2-Pentene 00627-20-3 10.28 0.61 6.288

n-Pentane 00109-66-0 1.21 0.60 0.729

n-Heptane 00142-82-5 0.97 0.56 0.541

Cyclopentene 00142-29-0 6.69 0.29 1.914

2-Methylbutane (Isopentane) 00078-78-4 1.35 0.10 0.132

n-Hexane 00110-54-3 1.13 0.02 0.025

Total 5.1 28.5 5.617

Vehicle 222b - Fuel 9 psi E0 - 86°F Static - Test 7655

Non Zero Mass Species Sorted By VOC
E-254

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 1.54 2.081

Toluene 00108-88-3 3.93 1.41 5.543

c-2-Butene 00590-18-1 14.26 1.13 16.161

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.11 4.861

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.06 12.518

2,3-Dimethylbutane 00079-29-8 0.90 0.95 0.853

2,3,4-Trimethylpentane 00565-75-3 0.95 0.87 0.822

Ethylbenzene 00100-41-4 2.96 0.84 2.475

n-Pentane 00109-66-0 1.21 0.80 0.967

ortho-Xylene 00095-47-6 7.58 0.60 4.559

2-Methyl-2-butene 00513-35-9 14.20 0.60 8.542

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.54 3.406

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.53 1.698

n-Heptane 00142-82-5 0.97 0.53 0.513

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.53 6.286

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.52 2.885

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.51 2.732

2,3-Dimethylpentane 00565-59-3 1.25 0.46 0.578

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.43 3.190

2,4-Dimethylpentane 00108-08-7 1.46 0.42 0.613

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.40 0.481

Methylcyclohexane 00108-87-2 1.56 0.40 0.619

t-2-Pentene 00646-04-8 10.47 0.38 3.995

2,3,5-Trimethylhexane 01069-53-0 1.12 0.38 0.424

2,4-Dimethylhexane 00589-43-5 1.61 0.34 0.542

2-Methylhexane 00591-76-4 1.09 0.32 0.352

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.31 0.440

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.30 0.325

t-2-Hexene 04050-45-7 8.55 0.30 2.540

n-Propylbenzene 00103-65-1 1.96 0.29 0.566

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.26 2.027

n-Butane 00106-97-8 1.08 0.26 0.276

2-Methyl-1-butene 00563-46-2 6.38 0.25 1.611

3-Methylpentane 00096-14-0 1.69 0.24 0.406

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.24 0.383

2,2-Dimethylbutane 00075-83-2 1.11 0.23 0.251

Cyclopentene 00142-29-0 6.69 0.21 1.396

Cyclohexane 00110-82-7 1.14 0.20 0.231

c-2-Pentene 00627-20-3 10.28 0.18 1.878

Benzene 00071-43-2 0.69 0.14 0.095

2,2,5-Trimethylhexane 03522-94-9 1.05 0.12 0.131

n-Hexane 00110-54-3 1.13 0.06 0.073

Total 21.2 100.3 4.734

Vehicle 222b - Fuel 9 psi E0 - 105°F Static - Test 7659

Non Zero Mass Species Sorted By VOC
E-255

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.78 109.195

3-Methylnonane 05911-04-6 0.66 7.99 5.238

1,3,5-Trimethylbenzene 00108-67-8 11.75 4.20 49.413

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.15 3.778

Toluene 00108-88-3 3.93 2.95 11.569

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.35 3.766

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.79 14.205

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.76 13.636

2,3,5-Trimethylhexane 01069-53-0 1.12 1.70 1.906

n-Propylbenzene 00103-65-1 1.96 1.62 3.182

t-1,4-Dimethylcyclohexane 02207-04-7 4.76 1.35 6.439

2,3,4-Trimethylpentane 00565-75-3 0.95 1.22 1.161

n-Undecane 01120-21-4 0.52 0.89 0.467

n-Octane 00111-65-9 0.80 0.74 0.592

2,2-DiMeHexane 00590-73-8 0.94 0.63 0.592

t-3-Heptene 14686-14-7 6.17 0.51 3.175

Ethylbenzene 00100-41-4 2.96 0.39 1.165

2-Methylhexane 00591-76-4 1.09 0.37 0.396

ortho-Xylene 00095-47-6 7.58 0.18 1.389

Total 48.6 231.3 4.759

No MIR available, use weighted average of 4.7594

Vehicle 222b - Fuel 9 psi E0 - Dynamic - Test 25791

Non Zero Mass Species Sorted By VOC
E-256

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-Methylbutane (Isopentane) 00078-78-4 1.35 29.66 40.180

1,3-Butadiene 00106-99-0 12.45 17.21 214.335

Toluene 00108-88-3 3.93 12.92 50.712

Ethanol 00064-17-5 1.45 12.91 18.706

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 7.64 10.680

Cyclohexane 00110-82-7 1.14 6.43 7.310

n-Hexane 00110-54-3 1.13 5.51 6.253

n-Pentane 00109-66-0 1.21 5.34 6.491

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.71 34.801

3-Methylpentane 00096-14-0 1.69 4.18 7.076

Methylcyclohexane 00108-87-2 1.56 4.04 6.278

2,3-Dimethylbutane 00079-29-8 0.90 3.62 3.250

2-Methyl-1-butene 00563-46-2 6.38 3.40 21.671

t-2-Pentene 00646-04-8 10.47 3.33 34.860

2-Methyl-2-butene 00513-35-9 14.20 3.29 46.756

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.28 3.928

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.02 23.403

1-Butyne 00107-00-6 6.05 2.86 17.332

Benzene 00071-43-2 0.69 2.53 1.757

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.27 12.196

Methylcyclopentane 00096-37-7 2.05 1.97 4.035

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.90 8.327

c-2-Pentene 00627-20-3 10.28 1.70 17.465

3,3-Dimethylpentane 00562-49-2 1.12 1.59 1.780

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.55 18.134

2,3,4-Trimethylpentane 00565-75-3 0.95 1.51 1.437

c-2-Butene 00590-18-1 14.26 1.28 18.226

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.21 9.587

2,2-Dimethylbutane 00075-83-2 1.11 1.09 1.212

Ethylbenzene 00100-41-4 2.96 1.00 2.974

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.98 5.200

2,3,5-Trimethylhexane 01069-53-0 1.12 0.98 1.094

2,4-Dimethylpentane 00108-08-7 1.46 0.77 1.119

2,2,5-Trimethylhexane 03522-94-9 1.05 0.74 0.780

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.69 3.848

t-2-Hexene 04050-45-7 8.55 0.66 5.657

2-Methylhexane 00591-76-4 1.09 0.65 0.708

ortho-Xylene 00095-47-6 7.58 0.65 4.921

2,3-Dimethylpentane 00565-59-3 1.25 0.65 0.807

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.58 0.938

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.56 0.611

3-Methyl-t-2-pentene 00616-12-6 11.66 0.53 6.212

3-Methyl-c-2-pentene 00922-62-3 12.52 0.50 6.248

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.50 2.861

Vehicle 222b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7696

Non Zero Mass Species Sorted By VOC
E-257

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 222b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7696

Non Zero Mass Species Sorted By VOC

1-Methylcyclopentene 00693-89-0 12.45 0.46 5.729

c-1,3-Dimethylcyclohexane 00638-04-0 4.31 0.46 1.970

4-Methyl-t-2-pentene 00674-76-0 8.04 0.45 3.652

2-Methyl-2-pentene 00625-27-4 11.03 0.44 4.888

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.42 4.959

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.42 2.779

n-Heptane 00142-82-5 0.97 0.41 0.392

2,4-Dimethylhexane 00589-43-5 1.61 0.39 0.632

2,2-Dimethylpentane 00590-35-2 1.04 0.37 0.382

n-Octane 00111-65-9 0.80 0.32 0.253

n-Undecane 01120-21-4 0.52 0.31 0.163

n-Propylbenzene 00103-65-1 1.96 0.31 0.608

Cyclopentene 00142-29-0 6.69 0.30 2.020

t-1,2-Dimethylcyclopentane 00822-50-4 4.31 0.28 1.189

3-Methylheptane 00589-81-1 1.12 0.27 0.305

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.24 2.867

c-2-Heptene 06443-92-1 7.08 0.23 1.602

2-Methylheptane 00592-27-8 0.97 0.21 0.205

c-1,3-Dimethylcyclopentane 02532-58-3 4.31 0.20 0.845

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.18 0.585

Total 169.1 728.2 4.307

No MIR available, use weighted average of 4.3074

continued
E-258

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 1.08 4.26 4.585

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.34 17.308

2-Methylbutane (Isopentane) 00078-78-4 1.35 1.49 2.014

Toluene 00108-88-3 3.93 1.04 4.064

c-2-Butene 00590-18-1 14.26 0.83 11.892

Cyclohexane 00110-82-7 1.14 0.70 0.794

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.59 4.567

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.50 2.637

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.43 0.518

2,4-Dimethylhexane 00589-43-5 1.61 0.41 0.663

3-Methylpentane 00096-14-0 1.69 0.39 0.653

n-Pentane 00109-66-0 1.21 0.27 0.323

2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.358

1,3,5-Trimethylbenzene 00108-67-8 11.75 0.24 2.801

Methylcyclopentane 00096-37-7 2.05 0.21 0.434

2-Methyl-2-butene 00513-35-9 14.20 0.21 2.918

t-2-Hexene 04050-45-7 8.55 0.20 1.712

n-Hexane 00110-54-3 1.13 0.18 0.199

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.12 0.660

2,3,4-Trimethylpentane 00565-75-3 0.95 0.11 0.103

2,3-Dimethylbutane 00079-29-8 0.90 0.11 0.095

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.11 0.147

Benzene 00071-43-2 0.69 0.08 0.053

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.03 0.093

Total 15.1 59.6 3.957

Vehicle 222b - Fuel 7 psi E0 - 86°F Static - Test 7712

Non Zero Mass Species Sorted By VOC
E-259

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Benzene 00071-43-2 0.69 0.20 0.142

2-Methylpropane 00075-28-5 1.18 0.97 1.141

2,2-Dimethylbutane 00075-83-2 1.11 0.13 0.140

2-Methylbutane (Isopentane) 00078-78-4 1.35 2.90 3.932

2,3-Dimethylbutane 00079-29-8 0.90 0.26 0.234

ortho-Xylene 00095-47-6 7.58 0.57 4.329

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.71 19.912

3-Methylpentane 00096-14-0 1.69 0.20 0.333

Ethylbenzene 00100-41-4 2.96 0.51 1.513

n-Propylbenzene 00103-65-1 1.96 0.35 0.695

n-Butane 00106-97-8 1.08 0.96 1.039

2,4-Dimethylpentane 00108-08-7 1.46 0.19 0.271

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.35 18.237

1,3,5-Trimethylbenzene 00108-67-8 11.75 1.40 16.495

Methylcyclohexane 00108-87-2 1.56 0.35 0.537

Toluene 00108-88-3 3.93 1.10 4.315

n-Pentane 00109-66-0 1.21 0.70 0.850

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.22 2.538

n-Hexane 00110-54-3 1.13 0.76 0.863

Cyclohexane 00110-82-7 1.14 0.53 0.603

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.27 0.863

n-Octane 00111-65-9 0.80 0.02 0.013

Cyclopentene 00142-29-0 6.69 0.13 0.869

n-Heptane 00142-82-5 0.97 0.22 0.210

Indan 00496-11-7 3.23 0.67 2.176

2-Methyl-2-butene 00513-35-9 14.20 0.09 1.216

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.63 7.531

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.32 0.390

2-Methyl-1-butene 00563-46-2 6.38 0.17 1.093

2,3-Dimethylpentane 00565-59-3 1.25 0.17 0.218

2,3,4-Trimethylpentane 00565-75-3 0.95 0.18 0.169

2,4-Dimethylhexane 00589-43-5 1.61 0.03 0.050

3-Methylheptane 00589-81-1 1.12 0.23 0.261

c-2-Butene 00590-18-1 14.26 0.56 7.938

2-Methylhexane 00591-76-4 1.09 0.04 0.040

2-Methylheptane 00592-27-8 0.97 0.38 0.371

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.04 0.193

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.72 3.986

3-Methyl-t-2-pentene 00616-12-6 11.66 0.36 4.179

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 6.49 47.900

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.54 6.787

t-2-Pentene 00646-04-8 10.47 0.01 0.112

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.51 0.713

Total 32.1 165.4 5.146

Vehicle 222b - Fuel 7 psi E0 - 105°F Static - Test 7715

Non Zero Mass Species Sorted By VOC
E-260

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 9.93 13.882

Toluene 00108-88-3 3.93 8.56 33.605

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.80 6.951

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.33 32.008

Cyclohexane 00110-82-7 1.14 3.63 4.126

2-Methylbutane (Isopentane) 00078-78-4 1.35 3.11 4.212

1-Butyne 00107-00-6 6.05 3.06 18.514

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.60 20.131

2,3,5-Trimethylhexane 01069-53-0 1.12 2.41 2.694

n-Hexane 00110-54-3 1.13 2.31 2.621

2,3,4-Trimethylpentane 00565-75-3 0.95 1.47 1.393

2,4-Dimethylpentane 00108-08-7 1.46 1.40 2.042

3-Methylpentane 00096-14-0 1.69 1.36 2.300

t-2-Pentene 00646-04-8 10.47 1.35 14.118

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.34 10.680

n-Undecane 01120-21-4 0.52 1.29 0.673

t-2-Hexene 04050-45-7 8.55 1.29 11.000

Methylcyclopentane 00096-37-7 2.05 1.29 2.637

n-Octane 00111-65-9 0.80 1.12 0.890

n-Butane 00106-97-8 1.08 1.01 1.091

2-Methylhexane 00591-76-4 1.09 0.95 1.028

2,2-Dimethylpentane 00590-35-2 1.04 0.93 0.966

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.85 0.933

2,4-Dimethylhexane 00589-43-5 1.61 0.82 1.315

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.80 1.281

n-Heptane 00142-82-5 0.97 0.76 0.732

2,3-Dimethylbutane 00079-29-8 0.90 0.76 0.679

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.75 2.405

2,2,5-Trimethylhexane 03522-94-9 1.05 0.74 0.783

2-Methyl-1-butene 00563-46-2 6.38 0.70 4.438

Benzene 00071-43-2 0.69 0.69 0.481

2-Methyl-2-butene 00513-35-9 14.20 0.63 8.950

Methylcyclohexane 00108-87-2 1.56 0.60 0.931

c-2-Pentene 00627-20-3 10.28 0.59 6.036

2,3-Dimethylpentane 00565-59-3 1.25 0.58 0.726

Ethylbenzene 00100-41-4 2.96 0.52 1.536

Unknown #22 . 3.12 0.12 0.382

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.10 1.227

n-Pentane 00109-66-0 1.21 0.09 0.109

Total 70.6 220.5 3.122

No MIR available, use weighted average of 3.1224

Vehicle 222b - Fuel 7 psi E0 - Dynamic - Test 25808

Non Zero Mass Species Sorted By VOC
E-261

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Benzene 00071-43-2 0.69 1.57 1.088

2,2-Dimethylbutane 00075-83-2 1.11 0.44 0.493

2-Methylbutane (Isopentane) 00078-78-4 1.35 12.03 16.295

2,3-Dimethylbutane 00079-29-8 0.90 3.59 3.228

ortho-Xylene 00095-47-6 7.58 2.09 15.860

1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.46 7.829

3-Methylpentane 00096-14-0 1.69 5.15 8.704

Methylcyclopentane 00096-37-7 2.05 1.42 2.904

n-Butane 00106-97-8 1.08 7.14 7.694

2,4-Dimethylpentane 00108-08-7 1.46 0.64 0.930

meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.62 35.806

Methylcyclohexane 00108-87-2 1.56 2.36 3.667

Toluene 00108-88-3 3.93 5.87 23.052

n-Pentane 00109-66-0 1.21 2.14 2.598

1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.24 2.782

n-Hexane 00110-54-3 1.13 6.58 7.464

Cyclohexane 00110-82-7 1.14 5.00 5.691

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.49 1.552

n-Octane 00111-65-9 0.80 0.45 0.362

n-Nonane 00111-84-2 0.68 0.76 0.518

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.94 7.476

n-Decane 00124-18-5 0.59 0.70 0.414

Cyclopentene 00142-29-0 6.69 0.35 2.337

n-Heptane 00142-82-5 0.97 0.04 0.037

2-Methyl-2-butene 00513-35-9 14.20 1.57 22.225

2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.94 2.329

2-Methyl-1-butene 00563-46-2 6.38 0.63 4.037

2,3-Dimethylpentane 00565-59-3 1.25 0.22 0.279

2,3,4-Trimethylpentane 00565-75-3 0.95 0.64 0.611

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.37 0.400

2,4-Dimethylhexane 00589-43-5 1.61 0.30 0.487

c-2-Butene 00590-18-1 14.26 1.14 16.253

2-Methylhexane 00591-76-4 1.09 0.34 0.364

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.02 0.031

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.56 2.968

3-Methyl-t-2-pentene 00616-12-6 11.66 0.59 6.832

t-2-Butene 00624-64-6 15.20 1.18 17.923

2-Methyl-2-pentene 00625-27-4 11.03 0.40 4.405

c-2-Pentene 00627-20-3 10.28 0.48 4.932

t-2-Pentene 00646-04-8 10.47 1.09 11.444

3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.69 4.003

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 8.95 12.511

3-Methyl-c-2-pentene 00922-62-3 12.52 0.48 6.045

2,3,5-Trimethylhexane 01069-53-0 1.12 0.73 0.818

Vehicle 222b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7742

Non Zero Mass Species Sorted By VOC
E-262

Species CAS No. MIR

Composite

VOC

mg

Ozone

mg

Vehicle 222b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7742

Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 2.40 1.255

2,2,5-Trimethylhexane 03522-94-9 1.05 0.45 0.470

t-2-Hexene 04050-45-7 8.55 0.82 6.991

Total 92.1 286.4 3.111

continued