HOOSIER ENERGY 

7398 N. State Road 37 

Bloomington, IN 47402 

BASELINE MERCURY TEST 

CONTINUOUS MERCURY MONITOR 

VALIDATION REPORT 

RATTS GENERATING STATION 

GENERATING UNIT #1 

January 18,2007 

AQS Project #06712-17-002 

425 MAIN STREET. EVANSVILLE, IN 47708
 

OFFICE:(812) 452-4785 • FAX:(812) 452-4786
 
BASELINE MERCURY TEST 

and 

CONTINUOUS MERClTRY MONITOR VALIDATION REPORT 

Conducted at 

Ratts Generating Station
 

Generating Unit #1
 

Performed For: 

HOOSIERENERGY
 

RURAL ELECTRIC COOPERATIVE, INC. 

January 18, 2007 

Prepared by: 

rJI-i7j


Air Ol8lityservices
 

Air Quality Services, LLC 

425 Main Street 

Evansville, Indiana 47708 

Phone: (812) 452-4785 

Fax: (812) 452-4786 , 

AQS Project 06712-17-002 
TABLE OF CONTENTS
 

Page 

SECTION 1	 INTRODUCTION 1-1
 

SECTION 2	 OVERVIEW OF MERCURY TEST PROGRAM 2-1
 

2.1 Source Description	 2-1
 

2.2 Mercury SaIIlpling Plan	 2-2
 

2.3 Labeling Conventions and Reporting Units	 2-2
 

2.4 Executive Sunnnary :	 2-2
 

SECTION 3	 MERCURY STUDY TEST RESULTS 3-1
 

SECTION 4	 FIELD QAJQC 4-1
 

4.1 Field Practices	 4-1
 

4.2 Simultaneous Field Duplicate Results	 4-1
 

4.3 Field Blanks	 4-1
 

SECTION 5	 TEST DATA 5-1
 

5.1' CEMS Data 5-1
 

5.2 Hg Trap Results & Data Summary	 5-1
 

SECTION 6	 CALCULATED VALVES 6-1
 

6.1 Mass Emissions Ca1culations.~	 6-1
 

6.1.1 Run #1 Mass Emissions ,	 6-1
 

6.1.2 Run #3 Mass Emissions	 6-2
 

6.1.3 Run #4 Mass Emissions	 6-2
 

6.1.4 Combined Runs Mass Emissions	 6-2
 

SECTION 7	 TEST SAMPLING PROCEDURES AND ANAL\'TICAL TEST
 

METHODS 7-1
 

7.1 Fluegas Absorbent Mercury Speciation (FAMSI'M) Method 7-1
 

7.2 Flo\J,I Measurements	 7-1
 

7.3 Analytical Test Method	 7-3
 
Table 2.4
 

Table 3.1
 

Table 3.2
 

Table 4.2
 

Table 4.3
 

Table 5.1
 

Table 5.2
 

Figure 3.1
 

Figure 3.2
 

APPENDIX A
 

. APPENDIX B
 

LIST OF TABLES 

Key Results and Statistics 2-3 

Total Hg 3-2 

Speciated Hg 3-3 

Simultaneous Field Duplicate Results .4-1 

Field Blank Results 4-1 

CEMS Data 5-1 

HgTrap Results & Data Summary 5-] 

LIST OF FIGURES 

Total Hg 3-2 

Speciated Hg 3-3 

APPENDICES 

FIELD DATA SHEETS 

LABORATORY SUMMARY 
SECTION 1
 

INTRODUCTION
 

Air Quality Services, LLC (AQS) conducted a baseline mercury (Rg) and continuous 

mercury monitor validation test for Hoosier Energy on the Unit #1 coal-burning boiler prestack duct at the Ratts Generating Station located in Petersburg, Indiana. The pUllJose of this 

test was to quantify baseline total mercury emissions as they pertain to the Clean Air 

Mercury Rule (CAMR), and to compare the speciated mercury results obtained by sorbent 

tube technologies with the results obtained by a temporarily installed Thenno EnvirOlID1entai 

Freedom SystemTM Continuous Mercury Monitor (CMM). 

Fluegas sampling was conducted using sorbent tube technology; namely the Fluegas 

Absorbent Mercury Speciation (FAMSTM) sampling method, that provides speciated mercury 

results. Collected fluegas samples, along with a field blank sample, were submitted to a 

dedicated mercury analytical laboratory for digestion and analysis by cold vapor atomic 

fluorescence spectrophotometry (CVAFS) according to the analytical guidelines contained in 

USEPA Method 1631 Revision E: "Mercury in Water by Oxidation, Purge and Trap, and 

Cold Vapor Atomic FluoJ'escence Spectrometry". 

AQS test personnel included Chris Wehner (Project Manager) and Neal Stewart. Kyle Foley 

of Hoosier Energy provided on-site logistics assistance, and coordinated plant operating 

conditions for the test program. Darrel Bayless of Hoosier Energy coordinated the transfer of 

CEMS and CMM data, along with general project oversight. 

111e contacts for this test program are as follows: 

Hoosier Energy 

Mr. Darrel Bayless 

7398 N. State Road 37 

P.O. Box 908
 

Bloomington, IN 47402-0908
 

Phone: 812-876-0370
 

dbayless@hepn.com
 

Air Duality Services. LLC 

Mr. Dan Todd JSteve Endress 

425 Main Street 

Evansville, IN 47708 

Phone: 812-452-4785 

Fax: 812-452-4786 

dtodd@aqsllc.net Jsendress@aqsllc.net 

1-1
 
SECTION 2 

OVERVIE\V OF MERCURY TEST PROGRAM 

Effective mercury emissions removal from coal-fired boilers requires a basic understanding 

of how mercury acts throughout the flue gas stream. The initial source of the mercury, of 

course, is coal. Mercury typically exists as a trace element in coal on the average order of 

0.1 ppl11W, although this concentration varies considerably between coal types. As coal is 

bumed in large boilers at around 1700oK, the mercury in the coal volatilizes to forn'1 

themlodynamically favored gaseous elemental mercury (Hg\ In the subsequent cooling of 

the combustion gases, interaction with other combustion products results in a portion of the 

elemental mercury being converted into gaseous oxidized fon11s of mercury (Hg+2

). 

Oxidation is beneficial because Hg+2 compounds are generally water-soluble and are, 

therefore, more effectively captured by wet scrubbers and other pollution control systems. 

Conversely, HgO is difficult to control and is likely to enter the global atmospheric cycle 

because of its high vapor pressure and low water solubility. A small portion of HgO and Hg+2 

adsorbs onto flue gas particulates, forming particle-bound mercury (HgP). Thus, mercury 

exists in three different fOlms in coal combustion gas - elemental, oxidized, and particulatebound - with the gaseous (vapor stage) forms being the most prevalent in stack emissions. 

Since HgO is the most difficult fonn of mercury flue gas emissions to remove, the primary 

key to reducing total mercury flue gas emissions lies in forming mercury compounds 

(oxidation) or particle-binding (absorption) elemental mercury in the flue gas stream, and 

removing this oxidized or particulate-bound mercury via existing Air Pollution Control 

Devices (APCD). This mercury oxidation/absorption condition is a function of the 

aforementioned inten"elated factors that are quite complex and only partially understood, 

making predictive total mercury emission concentrations difficult. 

TIle Clean Air Mercury Rule (CAlvfR) makes no distinction regarding the speciation of the 

mercury; rather, it seeks to regulate the total mercury emitted from the stack(s) and into the 

atmosphere. TIlls baseline test was designed to present total atmospheric mercury emissions 

at the time of the sampling, thus giving an indication (assuming representative plant 

operations) of the annual baseline mercury emissions at the sampled pre-stack duct. In 

addition, the test results obtained by the sorbent tube technology were compared to the 

results obtained by the temporarily installed Thermo Environnlental Freedom SystemTM 

Continuous Mercury Monitor (CMM) to assess the accurateness of the CMM at the time of 

the sampling. 

2.1 Source Description 

Ratts #1 is a coal-fired unit utilizing La NOx bumers without overfire air and a coldside electrostatic precipitator (ESP). 

2-1
 
2.2 Mercury Sampling Plan 

Prior to the test date(s), a general mercury sampling plan was developed to assess and 

compare the fate of mercury from the tested emission streams, consisting only of 

fluegas sampling. Materials sampling (coal, ash, etc.), as may be appropliate to 

detelluine the relative mass balance of mercury throughout the fluegas stream, was not 

part of this sorbent tube study as these issues are reportedly addressed in the continuous 

mercw-y monitor evaluation. Fluegas samples were obtained at the pre-stack duct only 

in order to establish baseline speciated and total mercury concentrations being emitted 

to the atmosphere. Fluegas sampling consisted of taking simultaneous duplicate 

samples, in order to demonstrate quality assurance by demonstrating reproducibility of 

results within statistical limits. 

The fluegas mercury sampling was conducted at steady load. Testing at the sampling 

location consisted of three runs of duplicate FAMSTM sorbent tubes. In addition, one 

field blank FAMSTM sorbent tube was obtained over the course of the sampling as a 

quality assurance measure. 

This Hg test was conducted on January 18,2006. Over the course of the fluegas testing 

program conducted by AQS, Continuous Emission Monitoring System (CEMS) data 

(C02 and flow) was collected during the Hg sampling program in order to calculate the 

mass emissions (lbs/trillion Btu) of Hg at the stack, along with the Continuous Mercury 

Monitor data to which the sorbent tube results are to be compared. 

2.3 Labeling Conventions and Reporting Units 

AQS utilizes a sample identifier (number) for each Hg sanlple taken. This identifier 

reflects, in order, the run, location, and Hg trap number (e.g. sanlple number 2-2-1 is 

the sample taken during run 2, at sampling location 2, and is the first Hg trap). The 

only sampling location (location #1) for this test study was the pre-stack duct for Unit 

#1. 

.In order to allow direct comparison of Hg concentration results at the stack, all fluegas 

results are reported in micrograms per cubic meter (Jlg/m3

) at standard conditions 

(temperature = 68°F and barometric pressure = 29.92" Hg [1 atmosphere]). 

2.4 Executive SUD1Dlary 

This baseline mercury (Hg) diagnostic study and continuous mercury monitor 

validation test was conducted for Hoosier Energy on Ratts #1 coal-burning power plant 

stack. The purpose ofthis test was to quantify baseline total mercury emissions as they 

pertain to the Clean Air Mercw-y Rule (CAMR) ), and to compare the speciated 

mercury results obtained by sorbent tube technologies with the results obtained by a 

temporarily installed Thenno Environmental Freedom SystemTM Continuous Mercury 

Monitor (CMM).. 

2-2 
The fluegas mercury sampling was conducted at steady load at each of the units. Key 

results and statistics resulting from this study are presented as follows: 

Table 2.4 

Key Results and Statistics 

Approximate 

CEMS CMM ,PAIlS 

'i-;",.,J TotalHg ,.­ " 

CO2 :1JbIIIIlI1an t :r.f~' Run' ('Yo) Flow (sefh) :(MIl",', .I, :.... ...' Hi' WG/IItlli 

13.36% 15,738,366 4.9858 3.8576 0.1700 1.8850 1.0600 3.1150 2.4101 1.871 1.4475 60.06% 

2 13.37% 15,948,153 4.8807 3.7743 0.0450 1.7400 0.9850 2.7700 2.1421 2.1 II 1.6322 76.20% 

3 13.34% 16,271,920 4.8489 3.7568 0.0400 1.9150 0.9900 2.9450 2.2817 1.904 1.4751 64.65% 

AI'l!ruge /3.36% 15,986,147 4.905/ 3.7962 11.0850 1.11467 1.0117 2.9433 2.2780 1.962 1.5183 66.97% 

Sid. Dc,'. 0.01% 2611,7911 U.0717 0.0539 0.0737 0.0936 0.0419 0.1725 0.1340 0.1300 0.0997 8.32% 

t. td. 

DC\'. 0.10% 1.68% 1.46% 1.42% 86.65% 5.07% 4.14% 5.86% 5.88% 6.63% 6.56% 12.42% 

Continuous mercury monitor (CMM) results are approximated, as only total hourly Hg 

results were provided (not matched up exactly to test run times). As can be seen from 

the data presented in the table, the average CMM results for total mercury obtained 

over the test period are approximately 67% higher than total Hg test results obtained 

during the same period by sorbent tube technology. These results are consistent with 

those for Unit #1, which showed CMM results approxiInately 66% higher than sorbent 

tube Hg results. 

2-3
 
SECTION 3
 

l\1ERCURY STUDY TEST RESULTS
 

Presented in tlus section are data and graphs covering both FAMST-M trap and CMM mercury 

test results over the same sampling peliod. Results of the tests, expressed in micrograms per 

cubic meter, are shown on the aforementioned data tables and graphs. The FAMSTM trap 

results for Hoosier Energy Ratts Station Unit #1 are within statistical limits for valid data 

recovery; 

DUling the sampling period, the temperature of the sampling probe at the location of the 

sorbent trap was maintained at 202°P (± SOP) to ensure volatilization of the flue gas moisture. 

As designed, each sampling run consisted oftwo simultaneous sampling trains. Each sample 

train consisted of a 43" section of quartz tubing that extended approximately W' into the flue 

gas stream followed by the PAMSTM sorbent traps; traps 1 and 2, respectively. Upon 

completion of the each sampling run, the sampling pumps were shut off and the sampling 

trains were removed. 

Results from the Continuous Mercury Monitor (CMM) were inserted into the total mercury 

tables for comparative purposes. 

3-1
 
Table 3.1
 

Total Hg
 

Sample 

Number 

Test Results 

(flglm) 

-Run Trap ,TiUJ;H2 

1 1 3.14 

1 2 3.09 

1 CMM 4.99 

2 1 2.78 

2 2 2.76 

2 CMM 4.88 

3 1 2.81 

3 2 3.08 

3 CMM 4.85 

Figure 3.1
 

Total Hg
 

~._---_.- ._--~- --- . ._---; 6.0 

5.0 

4.0 

"'eCl 3.0 

::1. 

2.0 

1.0 

0.0 

1-1 1-2 1-CMM 2-1 2-2 2-CMM
 

RU.~ - (Trap or CMM)


L--- L---_____________ _ -----' 

3-1 3-2 3-CMM 

3-2
 
Table 3.2
 

Speciated Hg
 

Sample 

Number Test Results blg/rol 

) 

Run TI'8D PHlt Ha+a Hl 

1 1 0.18 1.92 1.04 

1 2 0.16 1.85 1.08 

2 1 0.02 1.80 0.96 

2 2 0.07 1.68 1.01 

3 1 0.06 1.82 0.93 

3 2 0.02 2.01 1.05 

Average: 0.09 1.85 1.01 

Std. Dev.: 0.07 0.11 0.06 

ReI. Std. Dev.: 81.4% 6.1% 5.6% 

Figure 3.2
 

Speciated Hg
 

3.5 --------- --~.----.-----.----.-- _.- --.- ------.-------_. --- -- - -----.-._. ------­

3.0 

2.5 

M 2.0 .e 

OJ 

1.5 

1.0 [] HgO 

0.5 .Hg+2 

.PHg 0.0
 

Run -Trap
 

3-3
 
SECTION 4
 

FIELDQAlQC 

4.1. Field Practices 

Sorbent tube technologies intrinsically allow for minimal potential for field 

contamination. All sorbent tubes were handled with powderless latex gloves and sealed 

in zip lock bags following use. 

4.2 Simultaneous Field Duplicate Results 

The Hg sampling plan was designed to conduct a series of simultaneous field duplicates 

in order to measure precision and accuracy of the FAMSTM method. Analytical results 

for the sampled locations, along with the associated statistical information, are shown 

in table 4.2.1. Particle bound Hg is excluded due to its low contribution to the overall 

total. 

Table 4.2
 

Simultaneous Field Duplicate Results
 

FAMS #2 (ug Hglm3) Avera Standardnevlatton 

Run # Hg02 Hg02 HgOO Total Hg02 . HgoD Total Hg02 HgoD 

1.t2 3."4 1.86 1.08 1.06 3;12 0.81 '0.03 0 

2 1.10 OM UI 1.68 1.01 2.76 1;74 0.99 2.77 0.08 OM 

3 1. o.t3 2JI1 2.01 1.06 3.08 1;92 G.99 O..oa 

4.3 Field Blanks 

One field blank was taken during the sampling. The results of these field blanks show 

very little deviation from the laboratory baseline Hg quantities of .033 ng/trap, as 

follows (note that results are presented in nanograms/gram): 

Table 4.3
 

Field Blank Results
 

Test Res~lts (ng/trap) -­

Hg+z HgU SampleID PHg TotalHg

NNN 4155 0.00 0.49 0.95 1.44 

4-1
 
SECTION 5 

TEST DATA 

5.1	 CEMS Data 

CEMS data (C02 and flow), along with estimated HzO% (derived ii-om psychrometric 

charts), was collected from the plant in order to calculate stack emissions in mass units 

(lbs.ltrillion Btu). In addition, coal usage was obtainedin order to calculate theoretical 

Hg emissions from the fuel source. A summary of the sample times and collected test 

data is presented in figure 5.1.1. 

Table 5.1
 

CEMSData
 

Sample CEMSTime Duration Temp Flow Est. 

Date Run Start End (Minutes) degF C02 (%) (seth) H20 % 

1/1812007 1 10:10 11 :10 60 285 13.36% 15,738,366 8.00 

2 11:49 12:49 60 286 13.37% 15,948,153 8.00 

3 13:16 14:16 60 286 13.34% 16,271,920 8.00 

Average: 13.36% 15,986,147 8.00 

5.2	 Hg Trap Results & Data Summary 

A summary of the Hg sample data is presented in the following table: 

Table 5.2 

Hg Tt"ap Results & Data Summary 

Sample 

Number Trap Results (ng/trap) 

•Sampling 

Duration 

Offset Cor 

Volume 

CEMSRun 

Averages Test Results (~mJ)

Run f Trap PHil HIlH HSo Tow H8 (MinUle5) (Lilel5) 

SlIck 

CO: % 

Flow 

(5Cfm) 

Flow 

(dac:fin) PHa HS+1 I~g"

Tolal 

H~

1 1 44242 47.9190 26.0120 78.3553 60 24.96 13.36% 262.306 241,322 0.18 192 1.04 314 

1 2 39888 475126 27.6940 791954 60 25.66 13.36% 262,306 241,322 0.16 1.85 108 3.09 

2 1 0.5937 459492 24.5658 711088 60 25.52 13.37% 265,803 244,538 0.02 1.80 096 2.78 

2 2 17315 42.2303 25.3587 69.3205 60 25.17 1337% 265,803 244,538 0.07 1.68 1.01 2.76 

3 1 14921 454237 23.1882 70.1040 60 24.98 13.34% 271,199 249,503 0.06 1.82 0.93 2.81 

3 2 05055 52.9463 27.6988 81.1506 60 26.28 13.34% 271,199 249,503 0.02 201 105 308 

Field Blank 00000 0.9467 04933 1.4400 

5-1
 
SECTION 6
 

CALCULATED VALVES
 

6.1 Mass Emissions Calculations 

Mass emissions for each stack were calculated in accordance ,,,,ith USEPA Method 19, 

as follows: 

When Hg concentration is measured on a dry basis (Cd) and CO2 concentration is measured on a wet 

basis (C02w), the CO2-based F Factor is determined by the following equation: 

E = Pollutant emission rate, (Ib/trillion Btu) 

Cd = Pollutant concentration, dry basis, (Ib/set) 

Fe = Volume of combustion components per unit of heat content, (scf/million Btu) 

Note: at standard conditions (68 0 F and 29,92 inches of Hg), Fe is as follows: 

Antracite = 1,970 scf/MMBtu 

Bituminous = 1,800 scf/MMBtu 

Lignite = 1,910 scf/MMBtu 

Bws = Moisture fraction of effluent gas, percent
 

C02w = Concentration of CO2 on a wet basis, percent
 

The following subsections present the calculated Hg mass emission rates for each 

sample run: 

6.1.1 Run #1 Mass Emissions 

Data Input 

Cd 

Fe 

Bws 

C02w 

= 

= 

= 

= 

3.115 Ilg/scm 

% 

scf/MMBtu 

% 

(Avg.) 

(Avg.) 

(Avg.) 

1,800 

8.00% 

13.36% 

..... Emiaaion Rate 

2.41011 Ibs.ltrillion Btu 

6-1
 
6.1.2 Run #2 Mass Emissions 

Data Input 

Cd 

Fe 

Bws 

C02w 

= 

= 

= 

= 

2.770 Ilg/scm 

% 

scf/MMBtu 

% 

(Avg.) 

(Avg.) 

(Avg.) 

1,800 

8.00% 

13.37% 

MauEmiuiolllRate 

2.14211 Ibs.ltrillion Btu 

6.1.3 Run #3 Mass Emissions 

Data Input 

Cd 

Fe 

Bws 

C02w 

= 

= 

= 

= 

2.945 Ilg/scm 

% 

scf/MMBtu 

% 

(Avg.) 

(Avg.) 

(Avg.) 

1,800 

8.00% 

13.34% 

Mas. Emisslon·Rate 

2.28171 Ibs.Jtrillion Btu 

6.1.4 Combined Runs Mass Emissions 

Data Input 

Cd 

Fe 

Bws 

C02w 

= 

= 

= 

= 

2.943 Ilg/scm 

% 

scf/MMBtu 

% 

(Avg.) 

(Avg.) 

(Avg.) 

1,800 

8.00% 

13.36% 

..... Em..ioniRate 

2.27795 Ibs.ltrillion Btu 

6-2
 
SECTION 7 

TEST SAMPLING PROCEDURES AND ANALYTICAL TEST METHODS 

Fluegas samples were obtained using sOl'bent tube technologies; namely the Fluegas 

Absorbent Mercury Speciation (FAMSTM) Method. FAMSTM has been granted US EPA 

perfollllance based validation. 

7.1 FJuegas Absorbent Mercury Speciation (FAMSTM) Method 

The FAMS ~ethod r~lies on sequen~ial selective c:a~tW"e to s;}?arate and quantify three 

mercury specIes, partIculate Hg (Hg ), gaseous oXIdIZed (Hg ), and gaseous elemental 

(Hgo

). A known, precise volume (±0.1 liter) of gas is pulled through the FAMS sorbent 

train using standard sampling equipment including a quartz probe liner, heatedlcooled 

probe, silica-gel water trap, mass flow meter and pwnp. The temperature of the FAMS 

sorbent train is kept at 95 ± SoC during sampling to avoid water condensation in the 

trap..The sorbed HgO on the chemically impregnated carbon and the PHg on the glass 

wool plug is leached of collected Hg in the clean lab using hot-refluxing HN03IH2S04, 

then further oxidation in BrCI solution. The sorbed Hg+2 on the KCl trap is dissolved in 

(v/v) BrCl solution. Aliquots of all three Hg species digests are analyzed using EPA 

Method 1631. 

7.2 Flow Measurements 

Flow is determined by the use of mass flow meters. Dry fluegas is pulled at a nominal 

flow rate of 0.2 to 0.6 Llmin through Aalborg flow meters. As a quality assurance 

(QA) measure, these flow meters are calibrated at the factory at standard conditions 

(29.92 inches of mercury and 68°F), traceable to National Institute of Standards and 

Iesting (NIST) standards. The mass flow meters, by virtue of essentially counting 

molecules across the transducer, are not affected by temperature andlor barometric 

pressure fluctuations. 

The operating principle of the transducers is based on heat transfer and the first la\v of 

thermodynamics. During operation process gas enters the instruments flow body and 

divides into two flow paths, one through the sensor tube, and the other through the 

laminar flow element bypass. The laminar flow bypass generates a pressure drop, P1­

P2, forcing a small fraction of the total flow to pass through the sensor tube (m1)' 

7-1
 
Figure 1-2. Flow Paths through the Transducer 

CTWOCOilS 

~~~m¥~:tt-Sensor tube 

Laminar flow bypass 

rh =ril, + rt12
 

rh =ril, (1 + 11l 2 /rtl1) =k rtl,
 

Figure 1-2. Flow Paths through the Transducer 

Two resistance temperature detector (RTD) coils around the sensor tube direct a 

constant amount of heat (H) into the gas stream. In actual operation, the gas mass flow 

carries heat from the upstream coil to the downstream coil. The resulting temperature 

difference (DT) is detected by the RTD coils and gives the output signal. Since the 

molecules of the gas carry away the heat, the output signal is linearly proportional to 

gas mass flow. 

Figure 1-3. Flow Measuring Principle 

RTDSenSOr Sensor Tube 

m 

L Constant Heat H ---.J 

FilS Law of Thermodynamic:a
 

(Heel IN = Heal OUT)
 

H. 1ft, C. IT, - T,I+ He 

lm=~ I 

Figure 1-3. Flow Measuring Principle 

7-2
 
7.3 Analytical Test Method 

AQS uses the technical and analytical support of Frontier GeoSciences, Inc. (co-author 

of the FSTM Test Method, USEPA Method J631 and author ofthe FAMSTM Method). 

Accordingly, both fluegas and material samples are analyzed at the Frontier 

GeoSciences, Inc. dedicated trace metals laboratory following the guidelines set fOl1h in 

USEPA Method 1631, revision E. In this method, aliquots of digested Hg samples are 

oxidized with bromine monochloride and sparged with nitrogen onto a gold trap. The 

mercury is thermally desorbed from the gold trap into a cold vapor atomic fluorescence 

spectrometer (CVAFS). The CVAFS analytical test methodology, when used in 

conjunction with FAMSTM sampling protocol, has a demonstrated method detection 

limit (MDL) of 0.006 Ilg/m3 for particulate bound Hg (PHg), 0.026 J..lg/m3for elemental 

Hg (HgO), 0.018 Jlg/m3 for oxidized Hg (Hg+2), and 0.035 Jlg/m3 for total Hg (THg). 

Under standard conditions (l atmosphere at 68°F), the MDL's are 0.73 ppt for 

particulate bound Hg (PHg), 3.17 ppt for elemental Hg (Hgo), 2.20 ppt for oxidized Hg 

(Hg+2), and 4.27 ppt for total Hg (THg). 

7-3
 
1" ',:-",'.' 

,~,\,'~::,j}'-; ',.,">, 

, ;: ~'-'

··APPENDIXA 

! 

--, 

. . 

Field Data Sheets 

:.~_~. ~~~.-r--~~ .. __••_. • e_ - • ~-~-----4-~ _
Mr. Steve Endress ProJe<1: "_ler ERe'1ll' 

Air Quality Services Page I of5 

Results: Mercury Specladon In Flue Gas Via Flue Gas Adsorbent Mercury Speciation (FAMS) Methed 

Gerard Van der Jaxt - Fronder Geosciences Inc:. 1-31-07 

Schematic orFlue Gas Adsorbent Merc 

Hg(O)-8 Hg(O}-A 

! I I ~~ Z '.' , Hg(II)08 H9(1I)-~" c;",... . ~.=~"=~~

... _______n __..__....... _ ............
 

---- -- ---- -- --- ---- -._­

I Vol..... rHg Hg(Oj 8g(Uj TmlHg

Sample ID (LIteR) (OIBlim"3) (... HlllmA (oa HIII"'"3) ("ll Hlllm"3) 3)

NNN4141 24.72 0.18 1.05 1.94 3.17 

NNN4144 25.30 0.16 1.09 1.88 3.13 

NNN3968 24.93 0.02 0.99 1.84 2.85

NNN4127 25.22 0.Q7 1.01 1.67 2.75 

NNN 3958 24.80 0.06 0.94 1.83 2.83 

NNN3960 26.13 0.02 1.06 2.03 3.11 

NNN4155 NA NA NA NA NA

.-~

-.... 

\. '.) \'­

Incident Particulate Trap Or 

Quartz Fiber Filter \?_.... . .~ ,.,. ~",,,.,,.,.;(: ..,. .",,1. 3,:" 

RPD 

1.25 

3.68 

9.37 

< JileIdBluk 

• ________ 9 ____ 

••__'O­

----- -- - -------- .. J 

I SandeID . 

NNN4141 

NNN4144 

NNN3968 

NNN4127 

NNN3958 

NNN3960 

NNN4155 

Avenge> 

l'Ra As % 

OfTOClll1It: 

5.6% 33.2% 61.2% 

5.0% 35.0% 60.0% 

0.8% 34.5% 64.6% 

2.5% 36.6% 60.9% 

2.1% 

0.6% 

NA 

z.rlo 

HI(0)AI%
 

OrTolalHe
 

33.1% 

34.1% 

NA -- ..... 34.4% 

Hg(ll) As '/0
 

OrTOll1 H.
 

64.8% 

65:2% 

NA < I'1eId Blank

6z.rl. .­

TABLE 3: F AMS & FSTM Tral Per Section or Tra' 

Hg(OI
 

S........ ID IIn IIeI1nDII lOll HIIIlrlD)
 

NNN 4141
 

nil 

I I 4.42 26.01
 

NNN 4144
 I 3.99 I 27.69
 

NNN 3968
 0.59 24.57
 

NNN 4127
 I 1.73 I 25.36
 

NNN 3958
 1.49 23.19
 

NNN 3960
 0.51 27.70 

NNN 4155 I 0.00 I 0.49 I 0.95 I 1.44 1< Jilek! 8Iank 

R-.. AOS_1 2407... 
Mr. Steve Endress Project: U_rE••'1!Y 

Air Quality Services Page 2 DfS 

Results: Mercury Speciation In Flue Gas Via Flue Gas Adsorbent Mer~ury Spedallon (Ji'AMS) Method 

Gerard Vlln de, Jagt - F,ontie, GetlSdences Inc. /-3/-07 

... -.. -- .......-.. .. ....... .... __...._­ 8laDk Cor 

Lob Oat. Sot ID 

THGI6-070129-1 

R... # _10 II1!/mtor .00mt.r 

1710 NNN4141pHg 4.549 ng 4.424 og 

TIlGI6-070129-1 1714 NNN 4144 pHg 4.114 ng 3.989 ng 

TUGI6-070129-1 1711 NNN 3968 pHg 0.719 ng 0.594 ng 

TIlG16-070129-1 1715 NNN4127pUa L857 ng 1.731 ng 

TIlGI6-070129-1 1713 NNN 3958pHg \.617 ng 1.492 Dg 

TIlGl6-070129-1 1716 NNN 3960pHg 0.631 ng 0.505 ng 

TIlGl6-070129-1 1717 NNN4155pHg O.ooong 0.000 ng 

. -~." .. ... -.,. ...- && .............._ - ..- ............., u ............... 

lIIo"kC.... 

LobOa.. SolID 

lHG17-Q70129-] 

LobRn. 

6170 

Settqlle ID 

NNN4141 FSTMA 

1la(0.-A 

(IIII1rap) 

25.988 ng 

Hg(O.-A 

1ll1!/lnp) 

25.93 

tHG17-070\29-1 6172 NNN4144 FSTMA 27.457 ng 27.40 

tHOI7-Q70129-1 

TU017-070129-\ 

6171 

6173 

NNN 3968 FSTM A 

NNN 4127 FstM A 

24,326 ng 

15.2S9ng 

24.26 

25.20 

tHGI7-070129-1 6169 NNN 3958 FSTM A 22.968 ng 22.9\ 

tH017-070129-1 6174 NNN 3960FSTMA 27.761 ng 27.70 

TIlO! 7.070129-1 6179 NNN 4155 FSTM A 0.255 ng 0.19 

_. ..__.... .. - - - ...- -_... - -.......
 

Lob Do.. Sot ID 

THG17-070129-1 

TH017-Q70129-1 

lHGI1-010129-\ 

TU017-Q70129-1 

TIlGl 7.070129- 1 

TIlGl7-Q70129-1 

THG17-Q70129-1 

BbIlkCor 

0&<0'-8 0&<0'-8 

R... Som.... 10 Int!ltr'D) (•• /lnP) 

6189 NNN 4141 FSTM B 0.148ng 0,09 

6183 NNN 4144 PSTM B 0.361 ng 0.30 

6181 NNN 3968PSTMB 0.364118 0.30 

6184 NNN 4127 PS'IMB 0.224 ng 0,16 

6182 NNN 3958 FSTM B 0.344ng 0.28 

6185 NNN3960PSTMB 0.157ng 0.00 

6186 NNN 4155 FSTMB 0.363 ng 0.30 

TABLE .. -..... _._...... __.... - ....- PH'

Lob Data set ID 

THGI6-010129-1 

THGl6-070129-1 

...................._.... 

R••• SemplelD lIE 

I 1680 REAGENT BLANK 0.ooo n8 1709 REAGENT BLANK 0.251ng 

Anrage> 0.13 

S..-...J. Devla_ (SD) > NA 

Relative S...dud Devla_ (RSD) > NA 

. ................
 ., ... 411' _ ....._ - .. -......... l ....IIIP ....VU


"BTnp" 

Lob Dota Set 10 Rout. SamDleID ngJlnp 

THGI7-070129-1 6160 FSTM-BUCI 0.122 ng 

THGI7-070129-1 6161 FstM·BUCl 0.043 ng 

TH0l7-070129-1 6162 PSTM·BLK3 0.083 ng 

TH0l7-070129-1 6163 FstM-BUC4 O.ooong 

Aven:ae > 0.06 

StaDdanl De.lotlo. (SO) > 0.05 

Re...... S......n1 Devtatloe (RSD) > 84.7% 

Rnull-AQS_12401ld1 
---- -

Mr. Steve Endress Prvlect: 8_l<r \!AeflJ' 

Air Quality Services Page 3 of 5 

Resullll: Mercury SpeciatIon In Flue Gas Via Flue Gas Adsorbent Mercury Spedalion (FAMS) Method 

Gerard VI/II der Jagt - Frtllltier Geo:M:ienctlS fnc. 1-31-07 

.. ..... _- ......_-_....... .... _. ......-_.
 Blallk Cor 

ng(II)-A Hg(II)-A 

Lab Dola Sol m TIlGl6-070129-1 LabR..# s....... m (IIllUC/Inp) (DC/Inpl 

1690 NNN4141 KClA 47.252 ng 47.11 

THGl6-070129-1 1693 NNN 4144 KCI A 46.284 ng 46.14 

TIlG16-070129-1 1691 NNN3968KClA 45.572 ng 45.43 

TIlGI6-070129-1 1688 NNN 4127 KCIA 41.839 ng 41.70 

TIlGl6-070129·1 1692 NNN 3958 KClA 45004 ng 44.86 

TIlGl6-070129-1 

TIlGI6-070129·1 

1694 NNN3960KClA 51.896 ng 51.75 

1695 NNN4155KClA 1.089 08 0.95 

.. ....... , . ... -........ ~&_.._._- ..
 ..." .... Blank Cor 

Uc(U)-B Ug(II)-B 

Lab Dola Sol m Raa* Sa...... ID (agHg/lnp) (III Hg/lnp)

TIlO16-070129·1 1700 NNN4141 KCIB 0.952ng 0.81 

lHGl6-070 129-1 1703 NNN4144KClB 1.513 ng 1.37 

rnG' 6-070129·1 1701 NNN 3968 KCI B 0.662 n, 0.52 

rnGl6-Q70129-1 1704 NNN4.127 KCIB 0.676 ng 0.53 

0705 THGl6·070 129-1 1702 NNN 3958 Kct B 08 0.56 

rnG16-070129-1 1705 NNN 3960 KClB 1.335 ng 1.19 

TIlGI6-070129~1 1718 NNN4155KClB 0.18508 0.00 

.~-_........ ...
 .. .. _ ____........~G'_....... - .-"'I....... ......._._
 

Lab Oata Sot ID R•• * Sam.... m Uc(II)-A8<B 

(ngHg/lnp) 

rnGl6-070129-1 1681 KCI-BLKl 0.00008 

lH016-Q70129-1 1682 KCI·BLK2 0.252 ng 

lH0I6-Q70129-1 1683 KCl-BUO 0.000 Dg 

THOI6-070129·1 1684 KC~BlK4 0.31708 

Aftn" > 0.142 

Slaadanl Davlall..(SDI > 0.17 

Relative Slaadanl Ile.lalloll (MD) > NA 

R..... "Q9_1 2407.• 
Mr. Steve Endress Proj«t: Uooslo. Ea.rgy 

Air Quality Services Page 4 of 5 

Resultll: Mercury Speciation In Flue Gas Via Flue Gas Adsorbent Mercury Spe4:iatlon (FAMS) Method 

Gerard v,." der Jagt - Frontier Ge"sciences Inc. 1-31-07 

TABLE 1I: ESTIMATED MINIMUM DETECTION LIMIT 

TABLE 11: ANALYSIS QAlQC PERFORMANCE SUMMARY - SRM Results 

LobDoco SoliD 

TIlG16-070129-1 

TIlG17-070129·j 

R.. _ 

1673 

6154 

QC Parameler 

lCVINISI' 164ld 

lCV/NIST 1641d 

Observed Vtl.e 

1460786.866 ngiL 

1515311.688ng/L 

TABLE 13: FRONTIER GEOSCIENCES LAB CONTROL SPIKE RECOVERY 

Lob Do," Sot W LobR•• _ LobS........ 10 M.....od (.cttrop' 

B1a... c t 

M..n .... 

('RfTnp) 

E'p<etod 

(nglTnp) 

THGl6-070129·1 1685 KO·SPIKE1+30.. 27.664 ng 27.52 30.00 

TIlGI6-070129-1 1686 KQ.SPIKE2+3Ong 27.817 ng 27.67 30.00 

mG11-o70129-1 6164 fSTM-SPIKEI+30ng 27.884 .. 27.74 30.00 

THGI7-070129-1 6165 fSTM·SPIKE2+3Ona 26.547 .. 26.40 30.00 

TABLE 14: FRONTIER GEOSCIENCES ANALYfICAL SPIKE RECOVERY 

Lob Dol. SoUp LlbR•• _ Lob Simple OJ M.......... (ngltnpJI 

THGl6-070129-1 1699 NNN 4127 KCI A AS+144"ll 1 179.613 ng 

TH0I7-070129-1 6178 NNN 4141 fSTMA AS+80"ll 100.885 ng 

TABLE 15: LAB REPLICATE RESULTS R__ RepIkolelll R........,,1 

Lob DolO SolID _ID (.glTnpJ (qfl'npJ 

mOl~129-1 1698 NNN 4117 KCI A AD 41.839 ng R665"ll 

mOI7-o70129-1 6177 NNN4141fSTMAAD 25.988 .. 24.3731lf1 

R-*·AQS_12"'07.• 
IMr. SIeve Endress .....j.tt: Hoosle' E••l'1ll' 

Air Quality Services Page50f5 

Results: Mereury Speciation In Flue Gal' Via Flue Gas Adsorbent Mercury Speciation (FMIS) Method 

Germ V"" tkr JIIgt. Frontier Ge08aences Inc. 1-31-07 

TABLE 16: Continued Calibration Blanks (CCBs 

Lob Doh Set m R.n# CC81D 

1HGl6-070129-1 1678
 ICBlllB 0.144 "gIL <0.15 

mGl6-070129-1 1675
 CCBl 0.097 ngIL <0.15 

mOI6-070129-1 1676
 CCB2 O.I~OoWL <.0.25 

THG16-070129-1 1677
 CCB3 0.161 "gIL <0.15 

mo16-070129-1 1697
 CCB4 0.094 ngIL <0.15 

mOI6-070129-1 1708
 CCB~ 0.239 ngIL <0.15 

n10l6-070 129-1
 1720
 CCB6 0.1~6 oWL <0.15 

mOI7-070129-1 615~ ICBlBB 0.024 ngIL <0.15 

m017-070129-1 6156
 CCBl 0.060 ngIL < 0.15 

mOl 7-070129-1 61~7 CCB2 0.031 oWL <0.15 

mOl 7-070129-1 6158
 CCB3 0.040 ugIL < 0.15 

nIOI 7-070129· I
 6176
 CCB4 0.094 oWL <;0.15 

1HOI7-070129.' 6188
 CCB~ 0.089 ngIL <0.15 

n10I7-070129-1 6191
 CCB6 0.106 ngIL <0.25 

TABLE 17: Continued Calibration Verlneadon 

Lab Doh Set ID R CCVID Mea..red TncV."c •• ' 111016-070119-1
 

THGl6-070129-1
 

mOl6-070129-1
 

mOl 7-070 129-1
 

mOl 7-070129-1
 

lHGl7-070129·1
 

1696
 

1707
 

1719
 

6175
 

6187
 

6190
 

CCVI 

CCV2 

CCV3 

CCVl 

CCV2 

CCV3 

19.562 nglL 

18813 ngIL 

19534 ngIL 

19.644 ngIL 

19.651 ngIL 

19.559 ngIL 

20.00
 

20.00
 

2000
 

20.00
 

20.00
 

20.00
 

97.r~

'-4.1-;' 

97~7-1,

98.2-;' 

98.3-;, 

".!I-;' 

80% -110"~

80%-110% 

80% -110% 

8O%-110"~

SO-I,· 110-1_ 

8O'~-110%

RMutI,·AQS_'2"Or-'df; 
~-- --~,

•APPENDIXB 

Laboratory Summary
 

, _"J 
Average 

:'Run#2 

TIme I COl I Flow' TTC)fli'ti9, ,. (1Cfh) (lWe-r 

11:50 13.3% 16.081.739.0 

11:51 13.4% 16.126.054.0 

11:52 13.3% 16,040,283.0 

11:53 13.2% 15.669,687.0 

11:54 13.2% 15,403,172.0 

11:55 13.3% 15.756,215.0 

11:56 13.3% 15,917.294.0 

11:57 13.2% 16,108,410.0 

11:58 13.1% 16,064.353.0 

11:59 13.2% 15.878,223.0 

12:00 13.3% 15,858,773.0 

12:01 13.4% 16.002,352.0 

12:02 13.5% 16,278.866.0 

12:03 13.5% 16.273,542.0 

12:04 13.4% 16,327,892.0 

12:05 13.4% 16.306.540.0 

12:06 13.4% 16.265,023.0 

12:07 13.4% 16,404.509.0 

12:08 13.4% 16,463,575.0 

12:09 13.4% 16.394.501.0 

12:10 13.4% 16,162,589.0 

12:11 13.4% 16.184.057.0 

12:12 13.5% 16.195.499.0 

12:13 13.5% 16,119.621.0 

12:14 13.5% 16.105,794.0 

12:15 13.5% 16.168.645.0 

12:16 13.5% 16,131.962.0 

12:17 13.5% 16,183,563.0 

12:18 13.5% 16.144.637.0 

12:19 13.5% 16,457,360.0 

12:20 13.5% 16.516.690.0 

12:21 13.5% 16,456,490.0 

12:22 13.5% 16.396,898.0 

12:23 13.5% 16.062,929.0 

12:24 13.5% 16.029.938.0 

12:25 13.5% 16.054.637.0 

12:26 13.5% 15,921.114.0 

12:27 13.5% 15,609.078.0 

12:28 13.4% 15,605.111.0 

12:29 13.4% 15,482,638.0 

12:30 13.3% 15,525,812.0 

12:31 13.3% 15,658.685.0 

12:32 13.3% 15,827.638.0 

12:33 13.3% 15,433,280.0 

12:34 13.3% 14,853.703.0 

12:35 13.2% 14,633,259.0 

12:36 13.2% 14,781,489.0 

12:37­ 13.1% 14,818,841.0 

12:38 13.1% 15.104.205.0 

12:39 13.2% 15,570,387.0 

12:40 13.2% 15,597,245.0 

12:41 13.3% 15.563,070.0 

12:42 13.3% 16.034.410.0 

12:43 13.4% 16,092.945.0 

12:44 13.4% 16,535.724.0 

12:45 13.4% 16,433,724.0 

12:46 13.4% 16.253.671.0 

12:47 13.4% 16,100,014.0 

12:48 13.4% 16.228.941.0 

12:49 13.4% 16.231.910.0 

13.37% 15,841,153.4 4.881 

.':.<:..••:.... 

;E~U~;;::(I"

13:17 

13:18 

13:19 

13:20 

13:21 

13:22 

13:23 

13:24 

13:25 

13:26 

13:27 

13:28 

13:29 

13:30 

13:31 

13:32 

13:33 

13:34 

13:35 

13:36 

13:37 

13:38 

13:39 

13:40 

13:41 

13:42 

13:43 

13:44 

13:45 

13:46 

13:47 

13:48 

13:49 

'···1Iun1Wl:',. .;i:~

;C02i;;![V;~"iF_."~ 81~T0t8t~ '","': ;',;~f "\WeMMIf 

13.1% 16.104,288.0 

13.2% 16.239.138.0 

13.2% 16.297.255.0 

13.2% 16.247,369.0 

13.2% 16.147,512.0 

13.2% 15.988,081.0 

13.2% 15,952.006.0 

13.2% 16.250,482.0 

13.2% 16,210.157.0 

13.3% 16.247.747.0 

13.4% 16,183.110.0 

13.4% 16.246,452.0 

13.4% 16.402,197.0 

13.4% 16.518,335.0 

13.3% 16,476.976.0 

13.3% 16,326,960.0 

13.3% 16,338.197.0 

13.3% 16,170.797.0 

13.3% 16,209,559.0 

13.3% 16,250.592.0 

13.4% 16,232,434.0 

13.4% 16,324.116.0 

13.4% 16,155.674.0 

13.4% 16,397,497.0 

13.4% 16,589.166.0 

13.4% 16,634,958.0 

13.4% 16.363.735.0 

13.4% 16,258.645.0 

13.4% 16.209.551.0 

13.4% 16,283,894.0 

13.4% 16.185,839.0 

13.4% 16,220,610.0 

13.4% 16,177,027.0 

13:50 13.4% 16.236,904.0 

13:51 13.4% 16,325,519.0 

13:52 13.4% 16,552.293.0 

13:53 

13:54 

13.4% 

13.4% 

16.546,591.0 

16,409.679.0 

13:55 13.3% 16.169.002.0 

13:56 13.3% 16.231,499.0 

13:57 13.3% 16.121.841.0 

13:58 13.3% 16.194,570.0 

13:59 13.4% 16,222.380.0 

14:00 13.4% 16.202.821.0 

14:01 

14:02 

13.4% 

13.4% 

16.153,126.0 

16,180,975.0 

14:03 13.4% 16.426,435.0 

14:04 13.4% 16,547.814.0 

14:05 13.3% 16,445.964.0 

14:06 13.3% 16.282,807.0 

14:07 13.4% 16.131.319.0 

14:08 13.4% 16,089,075.0 

14:09 13.4% 16.079.225.0 

14:10 13.4% 16,122,427.0 

14:11 13.3% 16,104.110.0 

14:12 13.3% 16,201,814.0 

14:13 13.4% 16,176,998.0 

14:14 13.4% 16,304.205.0 

14:15 13.4% 16,478,446.0 

14:16 13.4% 16,537.013.0 

13.34% 16,271;920.1 4.849 

CEMS Data Summary 

Run #1 

Time I CO2 Flow ITotal Hg (by 

% (Iclh) CMMj I 

10:11 13.5% 16,345,747.0 

10:12 13.5% 16,465,482.0 

10:13 13.4% 16,446,968.0 

10:14 13.4% 16,463,192.0 

10:15 13.3% 16,392,487.0 

10:16 13.2% 16,289,936.0 

10:17 13.2% 16,210,814.0 

10:18 13.3% 16.534,522.0 

10:19 13.4% 16.579,264.0 

10:20 13.4% 16,608,446.0 

10:21 13.4% 16,347,312.0 

10:22 13.4% 16,120.603.0 

10:23 13.3% 16.163.275.0 

10:24 13.3% 16.234.268.0 

10:25 13.3% 16.248,513.0 

10:26 13.4% 16,306.955.0 

10:27 13.4% 16,247,194.0 

10:28 13.4% 16,256,684.0 

10:29 13.4% 16.167,195.0 

10:30 13.4% 16,162,154.0 

10:31 13.4% 16.216,326.0 

10:32 13.3% 16,158.584.0 

10:33 13.2% 16.103.662.0 

10:34 13.2% 15,968,968.0 

10:35 13.3% 15,951.403.0 

10:36 13.4% 15,909,340.0 

10:37 13.4% 15,833.292.0 

10:38 13.4% 15,769,225.0 

10:39 13.4% 15.751,745.0 

10:40 13.4% 15,650,428.0 

10:41 13.4% 15,640.522.0 

10:42 13.3% 15,789,788.0 

10:43 13.3% 16,110,930.0 

10:44 13.4% 16,151,788.0 

10:45 13.4% 15.939,636.0 

10:46 13.4% 15.852,222.0 

10:47 13.4% 15,727,503.0 

10:48 13.4% 15,800,838.0 

10:49 13.5% 15,851,102.0 

10:50 13.5% 15.874,463.0 

10:51 13.5% 15,838.504.0 

10:52 13.4% 15.904,418.0 

10:53 13.4% 16,165,874.0 

10:54 13.4% 14.858,741.0 

10:55 12.9% 4.345.785.0 

10:56 13.6% 3,335,969.0 

10:57 12.7% 11,511.314.0 

10:58 13.2% 19,151,670.0 

10:59 13.2% 16.511,643.0 

11:00 13.3% 16,321,864.0 

11:01 13.5% 16.325.022.0 

11:02 13.5% 16,374,877.0 

11:03 13.5% 16,375,995.0 

11:04 13.4% 16,422,487.0 

11:05 13.5% 16,509,612.0 

11:06 13.5% 16,600,732.0 

11:07 13.5% 16,825,538.0 

11:08 13.4% 16,858,152.0 

11:09 13.3% 16,798,192.0 

11:10 13.3% 16,674.426.0 

13.36% 15.738.366.2 4.986 
Average Data 

Plant: RATT
 

Source: UNIT#1
 

Parameter: Multiole Parameters
 

Report Period: 01/18/2007 10:00 Through 01/18/2007 14:30 Time Online Criteria: 1 

Interval: 1 Minute UNIT#1
 

Type: Roll
 NOX#lMM S02#1~M C02C PERCENTI FLOWSCFH SCFH I LOADMW MW I 1OPAC- -PERCENTI I TEMPF DEGF #/MMBTU #/MMBTU 

01/18/2007 10:00 13.4 16.214.797.0 126.8 -·:T7iR~q.~~: 22.18 275.2 I 

01/1812007 10:01 13.5 16,302,423.0 127.3 20.97 275.2 

01/18/2007 10:02 13.4 16,332,064.0 127.5 19.95 275.2 

01/1812007 10:03 13.4 16,442,098.0 128.0 

.,

.\ 21.00 275.3 

01/1812007 10:04 13.4 16,637,742.0 128.4 23.49 275.3 

01/18/2007 10:05 13.5 16,595.229.0 128.8 22.34 275.5 

01/18/2007 10:06 13.5 16.663,808.0 128.8 23.11 275.8 

01/18/2007 10:07 13.5 16,779,180.0 128.8 22.30 276.0 

01/18/2007 10:08 13.5 16,773,830.0 128.8 21.67 276.2 

01/18/2007 10:09 13.5 16,434,871.0 128.1 21.85 276.1 

01/18/2007 10:10 13.5 16,363,295.0 128.0 r 21.47 276.1 

0111812007 10:11 13.5 16,345,747.0 128.1 , 21.37 276.1 

01/18/2007 10:12 13.5 16,465,482.0 128.1 21.18 276.0 

01/18/2007 10:13 13.4 16.446.968.0 128.0 22.17 276.0 

0111812007 10:14 13.4 16,463,192.0 127.9 25.46 276.1 

01/18/2007 10:15 13.3 16,392,487.0 127.8 26.54 276.1 

01/18/2007 10:16 13.2 16,289,936.0 127.6 26.12 276.3 

01/18/2007 10:17 13.2 16,210,814.0 127.5 24.60 276.4 

01/1812007 10:18 13.3 16,534,522.0 127.4 24.01 276.7 

01/18/2007 10:19 13.4 16,579,264.0 127.4 23.90 277.0 

01/18/2007 10:20 13.4 16,608.446.0 127.4 22.42 277.1 

01/18/2007 10:21 13.4 16,347,312.0 127.2 22.82 277.1 

01/18/2007 10:22 13.4 16,120.603.0 127.0 22.28 276.9 

01/18/2007 10:23 13.3 16,163,275.0 127.1 23.81 276.8 

01/1812007 10:24 13.3 16.234,268.0 127.0 26.92 276.8 

01/18/2007 10:25 13.3 16,248,513.0 127.1 27.13 276.8 

01/18/2007 10:26 13.4 16,306,955.0 127.1 27.12 276.8 

01/18/2007 10:27 13.4 16,247.194.0 126.9 24.34 276.9
 

0111812007 10:28 13.4 16,256.684.0 126.9 24.74
 276.9 

01/18/2007 10:29 13.4 16,167,195.0 126.7 21.60 276.9 

F =Unit Offline E =Exceedance 

I =Invalid M =Maintenance C =Calibration 

Report Generated: 01/19/07 08:28 Report Version 1.2.0829 RATTS-CEMS\\escsupport 1 of 9 
Average Data 

Plant: RAn
 

Source: UNIT#1
 

Parameter: Multiple Parameters
 

Report Period: 01/18/2007 10:00 Through 01/18/2007 14:30 Time Online Criteria: 1 

01/18/2007 10:30 13.4 16.162,154.0 126.2 22.26 277.0 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

10:31 

10:32 

10:33 

10:34 

10:35 

13.4 

13.3 

13.2 

13.2 

13.3 

16,216,326.0 

16,158,584.0 

16,103,662.0 

15,968.968.0 

15,951,403.0 

125.3 

124.6 

124.7 

124.8 

124.6 ~lli 21.53 

21.48 

22.40 

22.11 

22.81 

277.1 

277.1 

276.9 

276,7 

276.5 

01/18/2007 

01/18/2007 

10:36 

10:37 

13.4 

13.4 

15,909,340.0 

15,833.292.0 

124.5 

124.3 

. ··>i;; :O'..lIS4 I ~1~;~,i';'~~~;ri~m~.~~~ I 

21.63 

22,73 

276,3 

276.2 

01/18/2007 10:38 13.4 15,769,225.0 124.1 20.05 276.1 

01/18/2007 10:39 13.4 15,751,745.0 123.6 20.73 276.0 

01/18/2007 10:40 13.4 15.650.428.0 123.4 22,01 275,8 

01/18/2007 10:41 13,4 15.640,522.0 . 123.3 20.22 275.7 

01/18/2007 10:42 13.3 15,789,788.0 123.0 19.24 275.7 

01/18/2007 10:43 13.3 16,110.930.0 122.9 20.37 275.7 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

10:44 

10:45 

10:46 

10:47 

10:48 

10:49 

10:50 

10:51 

10:52 

13,4 

13.4 

13.4 

13.4 

13.4 

13.5 

13.5 

13.5 

13.4 

16.151,788.0 

15,939,636.0 

15.852.222.0 

15.727,503.0 

15,800.838.0 

15.851.102.0 

15,874,463.0 

15,838,504.0 

15.904.418.0 

123.1 

123.2 

123.1 

123.2 

123.3 

123.4 

123.3 

123.3 

123.3 

20.48 

20.93 

19.05 

20.48 

20.95 

20.35 

19,38 

19.51 

20,05 

"~iI'~ ":,'". ~~

~t:~," "H;;';1' ~'Jji!ij~1(i'*1'!§! .~" ~'!1I

II:

h !i!i~li'~~U ;;",j''''''bf,'IJt ::':·f{:G~t ~-, ':''!t. ;I 4r~~~~1 ~;~i-~:: ,., :~fi'"' ~~: \'

t*:_.~i,

275.7 

275.4 

275.2 

275.0 

274.9 

274.8 

274.8 

274.7 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

10:53 

10:54 

10:55 

10:56 

10:57 

10:58 

10:59 

11:00 

11:01 

11:02 

13.4 

I'

li':~ •.,,~j;;'i' :~:;II'

II_!~13.5 

13.5 

16.165,874.0 

.

~-~ :inig{1~31l'l& IC ,·;':':.~i!i~:'lt'7'{< :." ~'l.1iJJ;ro.~ IC ~'~[fgi5.~1~t4~lIi IC .'\·i;~t.:f~~~~'i~,i~~t [.:.~L

'J18;ai1'~,Q'IC . .':.:,",.:.:", i ;'~~"~:'.I"':":-'

16,325.022.0 

16.374.877.0 

124.0 

125.3 

125.4 

124.4 

123.3 

124.7 

126.1 

126.2 

126.8 

126.6 ,";::::,·!;t::: 

20.30 

21.22 

22.00 

21.23 

21.16 

22.29 

21.35 

23.60 

25.74 

22.47 

II~ t''''"'t:r;w'':'·r$~ Ie 

~(~{~~11~ii;'C ",:;;i,j~'''I,g'IC

:i,t)'~~~~~f~~t : 273.2 

274.6 

F = Unit Offline E = Exceedance 

I =Invalid M =Maintenance C =Calibration 

Report Generated: 01/19/07 08:28 Report Version 1.2.0829 RAnS-CEMS\\escsupport 20f9 
Average Data 

. Plant: RAn 

Source: UNIT#1 

Parameter: Multiole Parameters 

Report Period: 01/18/2007 10:00 Through 01/18/2007 14:30 Time Online Criteria: 1 

01/18/2007 11:03 13.5 

01/18/2007 11:04 13.4 

01/18/2007 11:05 13.5 

01/18/2007 11:06 13.5 

01/18/2007 11:07 13.5 

01/18/2007 11:08 13.4 

01/18/2007 11:09 13.3 

01/18/2007 11 :10 13.3 

01/18/2007 11 :11 13.4 

01/18/2007 11:12 13.4 

01/18/2007 11:13 13.4 

01/18/2007 11 :14 13.4 

01/18/2007 11:15 13.3 

01/18/2007 11:16 13.2 

01/18/2007 11:17 13.2 

01/18/2007 11:18 13.2 

01/18/2007 11:19 13.3 

01/18/2007 11:20 13.2 

01/18/2007 11:21 13.1 

01/18/2007 11:22 13.1 

01/18/2007 11:23 13.2 

01/18/2007 11:24 13.2 

01/18/2007 11:25 13.3 

01/18/2007 11:26 13.3 

01/18/2007 11:27 13.2 

01/18/2007 11 :28 13.2 

01/1812007 11:29 13.2 

01/18/2007 11:30 13.3 

01/18/2007 11:31 13.3 

01/18/2007 11:32 13.3 

01/18/2007 11 :33 13.2 

01/18/2007 11:34 13.3 

01/18/2007 11:35 13.3 

F =Unit Offline E =Exceedance 

I =Invalid M =Maintenance 

16,375,995.0 

16,422,487.0 

16,509.612.0 

16.600,732.0 

16,825,538.0 

16.858,152.0 

16,798,192.0 

16,674,426.0 

16.580,366.0 

16.551,174.0 

16.606,579.0 

16.673,441.0 

16,604,883.0 

16.653,577.0 

16,580,546.0 

16,605,157.0 

16,720.385.0 

16.856.736.0 

16.869,598.0 

16.624.093.0 

16,525,594.0 

16,497.548.0 

16.373.086.0 

16,365.091.0 

16,237,410.0 

16,327,854.0 

16.332,809.0 

16,389.834.0 

16,608,388.0 

16.788.768.0 

16,674,536.0 

16,533,322.0 

16.431,932.0 

126.9 r.~";';'""';]1460 I 

127.2 

127.5 J>;i:<;j}i~~=~: 

127.6 

127.8 

128.5 

128.2 :~Jt'.i: 128.7 

128.7 

128.6 

128.6 

128.4 

128.2 

128.1 

128.1 

128.0 

128.0 

128.2 

128.3 

128.4 

128.4 

128.2 

127.9 

127.7 

127.4 

127.4 

127.6 

127.7 

127.7 

127.8 

127.8 

127.8 

127.9 

C =Calibration 

21.88 

22.16 

21.62 

20.72 

21.36 

21.79 

21.96 

20.98 

20.49 

21.54 

22.56 

23.72 

24.49 

24.17 

21.45 

22.54 

_E22.68 

22.52 

24.90 

31.19 

32.57 

29.28 

24.46 

22.73 

23.84 

22.77 

21.45 

21.13 

23.33 

21.72 

21.31 

22.23 

275.4 

275.9 

276.2 

276.4 

276.6 

276.8 

276.9 

276.8 

276.8 

276.7 

276.6 

276.6 

276.7 

276.8 

276.9 

277.0 

277.2 

277.3 

277.4 

277.3 

277.3 

277.2 

277.2 

277.0 

276.9 

276.7 

276.6 

276.5 

276.6 

276.8 

276.7 

276.6 

276.5 

Report Generated: 01/19/0708:28 Report Version 1.2.0829 RAnS-CEMS\\eSC5upport 30f9 
Average Data 

Plant: RATT
 

Source: UNIT#1
 

Parameter: Multiole Parameters
 

Report Period: 01/18/2007 10:00 Through 01/18/200714:30 Time Online Criteria: 1 

01/18/2007 11:36 13.3 16,310,378.0 127.9 21.58 276.4 

01118/2007 11:37 13.3 16.362.244.0 128.0 21.29 276.3 

01118/2007 11:38 13.4 16.385.397.0 128.0 24.00 276.2 

01/18/2007 11:39 13.4 16,495.333.0 128.1 24.58 276.2 

01/18/2007 11:40 13.4 16.449.503.0 128.0 27.41 276.3 

01/18/2007 11:41 13.3 16.381,929.0 128.0 25.95 276.5 

01118/2007 11:42 13.2 16,369.136.0 128.1 24.87 276.6 

01/18/2007 11:43 13.2 16,574,720.0 127.9 23.67 276.8 

01/18/2007 11:44 13.2 16,770,214.0 127.8 21.75 277.0 

01/18/2007 11:45 13.2 16.691.070.0 127.7 21.55 277.0 

01/18/2007 11:46 13.1 16,491.851.0 127.7 .'. :,..0. 3; I 23.66 276.8 

01/18/2007 11:47 13.1 16,421,474.0 127.9 26.21 276.7 

01/18/2007 11:48 13.1 16.309,400.0 128.0 26.71 276.6 

01/18/2007 11:49 13.3 16,179,632.0 127.1 22.56 276.4 

01/18/2007 11:50 13.3 16.081.739.0 126.4 22.60 276.3 

01/18/2007 11:51 13.4 16,126,054.0 126.2 21.12 276.2 

01/18/2007 11:52 ". 13.3 16.040.283.0 126.2 21.05 ~.'~-:d"~'~~,a,I 276.1 

01/18/2007 

01/18/2007 

11:53 

11:54 

13.2 

13.2 

15.669,687.0 

15.403.172.0 

124.8 

123.3 

19.22 

18.83 ';tt~1111~~: 276.0 

275.7 

01/1812007 

01/18/2007 

01/18/2007 

11:55 

11:56 

11:57 

13.3 

13.3 

13.2 

15.756.215.0 

15,917,294.0 

16.108,410.0 

123.3 

123.3 

123.5 

'.;':"i'I",!I!~t~ r 

'i" ',l:;,.'I'Wi~;;;· d .f""','" I" lQ' I ~'~,!,; ~J:/[~ m~t'i~i~r~'t·, i,' ",J:"'i'~';O'41:2; I 

19.14 

18.40 

20.62 "":'11' ;·,~.t~-~~{~'·l;' >'~i: l1f'.r" Jltr !.;;.,~~, _', ,'_ ..'f,r:" 

(}"'.~;- .:. ';'''''1f~ I 

275.6 

275.5 

275.3 

01/18/2007 11:58 13.1 16,064.353.0 124.8 20.14 275.1 

01/18/2007 11:59 13.2 15.878.223.0 125.0 19.96 275.0 

01/18/2007 12:00 13.3 15.858,773.0 125.0 20.08 274.8 

01118/2007 12:01 13.4 16,002.352.0 125.0 19.78 274.7 

01/18/2007 12:02 13.5 16.278,866.0 126.2 22.95 274.7 

01/18/2007 12:03 13.5 16.273,542.0 126.3 25.49 274.8 

01/18/2007 12:04 13.4 16.327,892.0 126.3 22.70 275.1 

01/18/2007 12:05 13.4 16.306,540.0 126.4 21.02 275.3 

01/18/2007 12:06 13.4 16,265.023.0 126.3 25.12 275.5 

01/18/2007 12:07 13.4 16,404.509.0 126.2 23.67 275.9 

01/18/2007 12:08 13.4 16,463.575.0 126.1 ,0: / •. n,a13 I 22.20 276.1 

F ::: Unit Offline E ::: Exceedance 

I ::: Invalid M ::: Maintenance C ::: Calibration 

Report Generated: 01/19/0708:28 Report Version 1.2.0829 RATTS-CEMS\\escsupport 40f9 
Average Data 

Plant: RATI
 

Source: UNIT#1
 

Parameter: Multiple Parameters
 

Repqrt Period: 01/1812007 10:00 Through 01/18/2007 14:30 Time Online Criteria: 1 

01/18/2007 12:09 13.4 16.394.501.0 126.4:{:]I~:,~!'~~I 21.11 276.2 

01/18/2007 12:10 13.4 16.162,589.0 126.3 ,;;.. \.:i/i,O~4'tU 20.37 276.0 

01/18/2007 12:11 13.4 16,184,057.0 126.2·r;·';:!d{t~Y.!~:'1 20.29 275.7 

01/18/2007 12:12 13.5 16,195,499.0 126.3 ':::'(:q~ I 20.12 275.5 

01/18/2007 12:13 13.5 16,119,621.0 126.1 ':)Aii~~ji;el~'1 20.96 275.3 

01/18/2007 12:14 n5 16.105,794.0 126.3P':;;,.;JliO~4$!fjI 26.35 275.1 

01/18/2007 12:15 24.27 275.1 

01/18/2007 12:16 25.04 275.0 

01/18/2007 12:17 21.34 275.0 

01/18/2007 12:18 ~1~ ~~:m:~1~ jf:~ ?ffil! 22.93 275.0 

01/18/2007 12:.19 13.5 16,457,360.0 126.5 "F;:";:iir!itj;'41~'1 21.65 ' 275.2 .;:I~' ': :i'"t;4:iY/:.; ;z.; ,', 01/18/2007 12:20 13.5 16.516.690.0 126.5" ','i;,:;::I~Q;':47:~ I 19.81 275.3 .'i~"~,Y:~l~~~-,,(r-~-l; 01/18/2007 12:21 13.5 16.456,490.0 126.8 """/':';l'iIf1&:1 24.04 275.4 

01/18/2007 12:22 13.5 16,396.898.0 126.9 :::';};,SJi~rPf~~~ 1 20.81 275.3 

01/18/2007 12:23 13.5 16,062.929.0 126,0 ;':·."'1l475': I 19.80 275.1 .",.~;: -'., ~l',.::i:':: ::; '1!.': 01/18/2007 12:24 13.5 16,029,938.0 125.7,' :,r;kP;~:7~1 19.91 275.0 ;\,; ',<,,;,:.~,,:!~ !Hr::' 01/18/2007 12:25 13.5 16,054.637.0 125.7 .,..•.. ,.,·'~idl):~g~1 19.94 274.8 

01/18/2007 12:26 13.5 15.921.114.0 125.0~.·::.<'ii?8~liiBi, 20.87 274.7 

01/18/2007 12:27 19.59 274.6 

0111812007 12:28 :~: ;:::::::: :::~ ~~;f,i~l: 18.62 274.4 

01/18/2007 12:29 13.4 15.482.638.0 122,5~i:i:Ji*i;ql~B.1 19.33 274.2 

01/18/2007 12:30 18.56 1 274.1 

01/18/2007 12:31 ~::: ~::::::::::~ ~~~:: ;:~/·!.·'f;n~~~: 18.51 'I 274.1 

01/18/2007 12:32 13.3 15.827,638.0 122.1:",~';:<;;froi4781 18.32 ,,1 274.1 ;~»;;; ;n~:;~;.r~~·:, :"; : 01/18/2007 12:33 13.3 15.433,280.0 120.4i,;·,·;'lf~:~~~41 19.06 274.0 

01/18/2007 12:34 13.3 14.853.703.0 116.7 /;::;i'S;iY~~f:g}~~" 17.71 J 273.7 

0111812007 12:35 13.2 14,633.259.0 115.3 '",:",::;;,-,r;i!OA75,\ 18.76 I 273.3 <'":.-;;~~ i;',;!;.'.iJi}{F:Jff ;','.: 01/18/2007 12:36 13.2 14,781,489.0 115.9 cli;t~:'il>!;::i~~~7~ I 17.86 ;t:f:1 273.0 ;....'::::;;.;. :'~~;'>.:~'>IJ'; • 01/18/2007 12:37 13.1 14,818.841.0 116.7 '/.>,.}~.j~r,~1 16.96 @, 272.7 

01/18/2007 12:38 13.1 15,104.205.0 117.1 ,':;.'f};'if;::i:k47ZI 17.67 272.5 _'~ i;;/;;'[:jJ)"r:.:iJ;:,}.:<.. [.;~:' 01/18/2007 12:39 13.2 15,570.387.0 118.9;':·"iJ,;!,<OJI8S'1 18.26 ;91 272.4 

01/18/2007 12:40 13.2 15.597.245.0 120.0 ::~)i"l;~5&,~~,1 19.89 :~··'::t{~~j:r:'\Q~,::. 272.4 : 01/18/2007 12:41 13.3 15.563,070.0 119.9 """;::,0:459, I 19.57 272.4 

F =Unit Offline E =Exceedance 

I 

=Invalid M =Maintenance C 

=Calibration 

Report Generated: 01/19/0708:28 Report Version 1.2.0829 RATIS-CEMS\\escsupport 50f9 
Average Data 

Plant: RAn
 

Source: UNIT#1
 

Parameter: MultiDle Parameters
 

Report Period: 01(1812007 10:00 Through 01(18(2007 14:30 Time Online Criteria: 1 

01/18/2007 12:42 13.3 16,034,410.0 121.3 19.47 272.6 

01/18/2007 12:43 13.4 16,092,945.0 122.0 19.24 272.9 

01/18/2007 12:44 13.4 16,535,724.0 122.9 ~~[iJ: 20.66 273.2 

01/18/2007 12:45 13.4 16,433,724.0 123.4 ,-, ,/; () 443' I 20.69 273.5 

01/18/2007 12:46 13.4 16,253,671.0 123.6 20.37 273.6 

01/18/2007 12:47 13.4 16,100,014.0 123.7 Jf~~~il: 20.70 273.7 

01/18/2007 12:48 13.4 16,226,941.0 123.6 ,ft'!4t'\, I 20.42 273.6 

01/18/2007 12:49 13.4 16,231,910.0 123.6 !4i4il 16.66 273.9 

01/18/2007 12:50 13.3 16.124.956.0 123.7 16.77 274.0 

01/18/2007 12:51 13.3 16,232.459.0 124.0 k.,,:·tj:J:;iy,·:~fln' : 20.04 274.1 

01/18/2007 12:52 13.3 16,307,932.0 124.3 .::!: "i~:;;;~~'6f~4i I 21.26 274.3 

01/18/2007 12:53 13.3 16,339,493.0 124.4 ',', 21.83 274.4 

01/18/2007 12:54 ,~;~:IC T:l;t'~!~~() IC 124.5 21.60 .• '~',. ," h:" r})-li ~,;~! _~L;~,t?f ("tL

01/18/2007 12:55 !IIC ",(;'3:~z;~'M;lS:IC 124.6 22.34 

01/18/2007 12:56 :IC :,~,;~i~~W~,C 124.5 19.77 

0111812007 12:57 IC it~r"lW)~'lii:thc 124.4 .,f.: t~'I·t':"" 20.61 )!f1!"I,."p.I.IU;'Itl!!, d'ir"lc: 01/18/2007 12:58 IC j"'H.ili!J~~,\lIC 124.7 19.76 !!Ui'l-ii'ilUI!il'@!;:, 01/18/2007 12:59 IC i'li18~MJ;i~'IO, IC 124.7 21.06 

01/18/2007 13:00 i)6;o IC 124.6 ~!g~1!~I~~ IC ;;;.' '. 21.96 ·'J":"~'F.9fj". .i~ 'C 

01/18/2007 13:01 13.3 16.356.246.0 125.0 20.90 ~1~~~~i';frt;'~~ I 272.7 

0111812007 13:02 13.3 16,325,662.0 125.0 .\ 20.15 

~"~~ 274.0

01/18/2007 13:03 13.3 16,333,149.0 125.1 I 20.70 ;~rJ'1 274.6 

0111812007 13:04 13.3 16,336,455.0 124.6 19.97 275.3 

01/18/2007 13:05 13.3 16,399,924.0 124.6 20.53 275.6 

01/18/2007 13:06 13.3 16,462.665.0 125.0 20.56 275.9 

01/18/2007 13:07 13.3 16.577.096.0 125.0 20.31 276.3 

01/18/2007 13:08 13.3 16,565,736.0 125.2 22.09 276.5 

01/18/2007 13:09 13.2 16.020,627.0 123.3 19.36 276.4 

01/18/2007 13:10 13.2 15.766,967.0 121.7 16.60 276.1 

01/18/2007 13:11 13.2 15,651.765.0 122.0 19.73 275.6 

01/18/2007 13:12 13.1 16.117,490.0 123.0 19.60 275.5 

01/18/2007 13:13 13.1 15.966.965.0 123.7 19.22 275.3 

01/18/2007 13:14 13.2 15.606,696.0 122.9 16.69 275.1 

F =Unit Offline E =Exceedance
 

I 

=Invalid M =Maintenance
 C 

=Calibration 

:'i~~~~
 

" 

Report Generated: 01/19/07 08:28 Report Version 1.2.0829 RAnS-CEMS\\escsupport 6of9 
Average Data 

Plant: RATT
 

Source: UNIT#1
 

Parameter: Multiole Parameters
 

Report Period: 01/1812007 10:00 Through 01/18/2007 14:30 Time Online Criteria: 1 

01/18/2007 13:15 13.2 15,782,162.0 122.2 19.40 274.9 

01/18/2007 13:16 13.2 15.938,351.0 122.3 19.31 274.6 

01/18/2007 13:17 13.1 16,104,288.0 123.3 19.22 274.4 

01/18/2007 13:18 13.2 16,239,138.0 123.4 19.91 274.5 

01/18/2007 13:19 13.2 16,297,255.0 123.4 19.48 274.4 

01/18/2007 13:20 13.2 16,247,369.0 123.4 18.37 274.3 

01/18/2007 13:21 13.2 16,147,512.0 123.2 19.09 274.0 

01/18/2007 13:22 13.2 15,988.081.0 123.3 17.95 273.8 

01/18/2007 13:23 13.2 15,952,006.0 123.1 ·;;:.·'·;:~;ip;.41911 18.65 273.7 

01/18/2007 13:24 13.2 16,250,482.0 124.2 .(:,!.~~£g~9h4¥~'1 19.99 273.6 

01/18/2007 13:25 13.2 16,210,157.0 124.6 18.67 273.7 

01118/2007 13:26 13.3 16,247,747.0 124.5 19.73 273.7 

01/18/2007 13:27 13.4 16,183,110.0 124.6 19.68 273.8 

01/18/2007 13:28 13.4 16,246,452.0 124.8 19.07 273.9 

01/18/2007 13:29 13.4 16,402,197.0 124.9 19.08 274.2 

01118/2007 13:30 13.4 16,518,335.0 124.8 19.66 274.4 

01/18/2007 13:31 , 13.3 16,476,976.0 124.8 19.85 274.6 

01/18/2007 13:32 13.3 16,326,960.0 124.6 18.92 274.6 

01/18/2007 13:33 13.3 16,338,197.0 124.8 20.67 274.6 

01/18/2007 13:34 13.3 16,170,797.0 124.8 18.64 274,5 

01/18/2007 13:35 13.3 16,209,559.0 124.8 19.75 274.6 

01/18/2007 13:36 13.3 16,250,592.0 125.0 20.02 274.6 

01/18/2007 13:37 13.4 16,232,434.0 125.2 18.84 274.7 

01/18/2007 13:38 13.4 16,324,116.0 125.2 19.48 274.9 

01/18/2007 13:39 13.4 16,155,674.0 125.3 20.21 274.9 

01/18/2007 13:40 13.4 16,397,497.0 125.5 19.57 275.2 

01/18/2007 13:41 13.4 16,589,166.0 125.5 19.23 275.4 

01/18/2007 13:42 13.4 16,634,958.0 125.5 19.97 275.5 '.' 01/18/2007 13:43 13.4 16,363,735.0 125.6 19.56 275.5 

01/18/2007 13:44 13.4 16,258,645.0 125.5 19.21 275,4 

01/18/2007 13:45 13.4 16,209,551.0 125.3 19.86 275.3 

01/18/2007 13:46 13.4 16,283,894.0 125.3 19.62 275,2 .:: :' 

01/18/2007 13:47 13.4 16,185,839.0 125.3 21.08 275.2 

F =Unit Offline E =Exceedance
 

I =Invalid M =Maintenance
 C =Calibration 

··;;;j!~jhV~~~tll :';-'i!rL''''LiiS'J~Si I ,v;t:'.;~~:;;;~~t~;L"'n' . 

Report Generated: 01/19/07 08:28 Report Version 1.2.0829 RATTS-CEMS\\escsupport 7 af9 
Average Data 

Plant: RAn
 

Source: UNIT#1
 

Parameter: Multiole Parameters
 

Report Period: 0111812007 10:00 Through 0111812007 14:30 Time Online Criteria: 1 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

01/18/2007 

13:48 

13:49 

13:50 

13:51 

13:52 

13:53 

13:54 

13:55 

13:56 

13:57 

13:58 

13:59 

14:00 

14:01 

14:02 

14:03 

14:04 

14:05 

14:06 

14:07 

14:08 

14:09 

14:10 

14:11 

14:12 

14:13 

14:14 

14:15 

14:16 

14:17 

14:18 

14:19 

14:20 

~~: ::::::~ :::: '~Ii:
 13.4 16.325.519.0 125.5 .""';'::;iO~~91

13.4 16.180.975.0 124.9··>::'::Jh;~oI 

13.4 16,426.435.0 124.8 "::(';':"H" "". " 

13.4 16.547.814.0 124.9 

13.3 16.445.964.0 124.9 

13.3 16.282.807.0 125.2 

13.4 16.131.319.0 125.1 , 

13.4 16.089.075.0 125.0 

13.4 16.079.225.0 124.8 

13.4 16.122.427.0 124.9 

13.3 16.104.110.0 124.9 

13.3 16.201.814.0 124.9 

13.4 16.176.998.0 124.9 

13.4 16.304.205.0 125.0 

13.4 16.478,446.0 125.0 

13.4 16.537.013.0 124.9 

13.4 16.346.795.0 124.8 

13.3 16.262.360.0 124.6 

13.3 15.999.293.0 124.6 

13.3 16.024.168.0 124.5 

iill:

19.21 

19.59 

19,56 

20.51 

18.70 

19.08 

21.11 

23.20 

19.90 

20.39 

18.86 

19.99 

20.08 

20.51 

18.58 

20.09 

18.35 

18.97 

19.64 

19.79 

18.30 

19.65 

19.44 

19.40 

19.70 

18.66 

19.12 

19.87 

18.26 

18.88 

19.46 

19.63 

19.80 

275.2 

275.1 

275.1 

275.3 

275.4 

275.6 

275.4 

275.2 

275.1 

I 274.9 

I 274.8 

I 274.8 

I 274.7 

274.7 

274.7 

I 274.9 

275.0 

275.0 

275.0 

274.9 

274.9 

:1 274.8 

I 274.7 

I 274.7 

, 274.7 

I 274.7 

274.8 

275.0 

275.1 

275.1 

274.9 

274.8 

274.7 

• F =Unit Offline E 

=Exceedance 

I 

=Invalid M = Maintenance C 

=Calibration 

Report Generated: 01/19/07 08:28 Report Version 1.2.0829 RAnS-CEMS\\escsupport 8 of 9 
Plant Name: Hooiser
 

General Average Report
 

Reporting Period: 12/15/2006 to 01/23/2007
 

Site Name: HG_TEST
 

Data Average: 1 hr
 

HG_T 

Date Time (uglm3 ) 

1/18/2007 0:00 4.8 

1:00 4.5 

2:00 4.5 

3:00 4.4 

4:00 4.8 

5:00 4.8 

6:00 5.0 

7:00 5.0 

8:00 4.8 

9:00 4.6 

Status Flag 

Sorbent Tube Sam lin Period 

< 

10:00 

11:00 

12:00 

13:00 

14:00 

15:00 

4.8 

5.0 

5.0 

4.9 

4.8 

4.7 

16:00 4.9 

17:00 4.7 

18:00 4.8 

19:00 4.6 

20:00 4.5 

21:00 

22:00 4.1 

23:00 4.2