# P2695 - TEQ **Project ID: P-10124** 

# Sample Summary **Part 1** 

# Method 23

**An alyte**  **0_8210_ MB001** **Plant 5**

**Inlet-R1 Plant 5** 

**Inlet-R2 Plant 5** 

**Inlet-R3 Plant 5** 

**Outlet R1**  **Plant 5 Outlet**  **R2 Plant 5** **Outlet R3**  **Plant 5 Oven-R1** **Plant 5**

**Oven-R2 Plant 5** 

**Oven-R3**
pg pg pg pg pg pg pg pg pg pg 2,3,7,8-TCDD (1.79) 50.1 45.2 34.3 60.2 29.4 [33.8] (1.77) (2.7) (2.03) 1,2,3,7,8-PeCDD (2.12) 75.2 63.9 66.4 92.3 42.6 61.7 (1.76) (2.75) (2.31) 1,2,3,4,7,8-HxCDD (2.09) 32 21.6 23.4 28 16.8 20.6 (1.77) (3.16) (1.87) 1,2,3,6,7,8-HxCDD (2.06) 49.2 32.1 31.3 [36.6] 20.4 29.4 (1.68) (3.25) (1.81) 1,2,3,7,8,9-HxCDD (2.14) 60.6 44.3 38 49.5 29.2 41.3 (1.88) (3.09) (1.99) 1,2,3,4,6,7,8-HpCDD (2.48) 247 162 139 135 91 108 13.4 [8.43] 9.41 OCDD (4.95) 1500 1030 809 563 421 549 37.8 [27.5] [26.2]

2,3,7,8-TCDF (1.3) 14.4 10.7 [5.02] 4.29 5.58 [3.02] [3] [3.49] (2.26) 1,2,3,7,8-PeCDF (1.43) 15.1 17.7 7.81 [2.36] [3.4] [2.68] 3.72 (3.61) (2.46) 2,3,4,7,8-PeCDF (1.32) 9.13 [8.37] 6 5.98 6.89 5.68 5.89 (3.61) (2.08) 1,2,3,4,7,8-HxCDF (1.38) 11.5 12.7 8.14 4.19 [3.98] 3.74 6.01 (2.02) 3.86 1,2,3,6,7,8-HxCDF (1.27) 11.6 14.5 [6.55] 4.37 [5] [2.63] 5.4 (2.06) 3.2 2,3,4,6,7,8-HxCDF (1.26) 9.5 9.99 [4.9] 4.85 5.76 [4.22] [5.4] (2.05) 5.01 1,2,3,7,8,9-HxCDF (1.66) (2.18) (1.85) (1.66) (1.48) (1.82) (2.73) (1.86) (2.63) (2.77) 1,2,3,4,6,7,8-HpCDF (1.5) 27.4 32.8 19.2 11.6 12.2 12 11.4 (2.31) 8.79 1,2,3,4,7,8,9-HpCDF (2.08) 4.56 4.2 (1.99) (1.76) (2.27) (3.31) (2.63) (3.29) (1.9) OCDF (3.57) [10.3] 14.8 (3.07) [6.56] 6.95 [6.83] [3.15] (2.96) [4.26]
**ITEF TEQ (ND=0; EMPC=0) 0.00**  **116 95.6**  **83.4 121**  **63.4 45.0**  **4.56 0.00**  **1.39 ITEF TEQ (ND=0; EMPC=EMPC)**  **0.00 116**  **99.8 85.0**  **125 64.5**  **79.9 5.40**  **0.461 1.42** 
**ITEF TEQ (ND=DL/2; EMPC=0) 2.48**  **116 96.1**  **83.7 121**  **63.7 47.2**  **6.42 4.16**  **4.11 ITEF TEQ (ND=DL/2; EMPC=EMPC)**  **2.48 116**  **99.9 85.1**  **125 64.6**  **80 7.10**  **4.43 4.14** 
**ITEF TEQ (ND=DL; EMPC=EMPC) 4.96**  **116 100**  **85.2 125**  **64.7 80.2**  **8.79 8.41**  **6.85**

Checkcode 943-130181-473154-978861-712399-397126-168589-525634-960876-500591-982 Lab ID MB1_8210_DF_SDSP2695_8210_001P2695_8210_002P2695_8210_003P2695_8210_004P2695_8210_005P2695_8210_006P2695_8210_007P2695_8210_008P2695_8210_009
( ) = DL [ ] = EMPC0 20 40 60 80 100 120 140 160 180

**pg** 

# WHO**- 2005** **- TEQ**  **Project ID: P -** **10124 P2695**  ND=0; EMPC=0 ND=0; EMPC=EMPC ND=DL/2; EMPC=0 ND=DL/2; EMPC=EMPC ND=DL; EMPC=EMPC

# P2695 - WHO-2005-TEQ **Project ID: P-10124** 

# Sample Summary **Part 1** 

# Method 23

**An alyte**  **0_8210_ MB001** **Plant 5**

**Inlet-R1 Plant 5** 

**Inlet-R2 Plant 5** 

**Inlet-R3 Plant 5** 

**Outlet R1**  **Plant 5 Outlet**  **R2 Plant 5** **Outlet R3**  **Plant 5 Oven-R1** **Plant 5**

**Oven-R2 Plant 5** 

**Oven-R3**
pg pg pg pg pg pg pg pg pg pg 2,3,7,8-TCDD (1.79) 50.1 45.2 34.3 60.2 29.4 [33.8] (1.77) (2.7) (2.03) 1,2,3,7,8-PeCDD (2.12) 75.2 63.9 66.4 92.3 42.6 61.7 (1.76) (2.75) (2.31) 1,2,3,4,7,8-HxCDD (2.09) 32 21.6 23.4 28 16.8 20.6 (1.77) (3.16) (1.87) 1,2,3,6,7,8-HxCDD (2.06) 49.2 32.1 31.3 [36.6] 20.4 29.4 (1.68) (3.25) (1.81) 1,2,3,7,8,9-HxCDD (2.14) 60.6 44.3 38 49.5 29.2 41.3 (1.88) (3.09) (1.99) 1,2,3,4,6,7,8-HpCDD (2.48) 247 162 139 135 91 108 13.4 [8.43] 9.41 OCDD (4.95) 1500 1030 809 563 421 549 37.8 [27.5] [26.2]

2,3,7,8-TCDF (1.3) 14.4 10.7 [5.02] 4.29 5.58 [3.02] [3] [3.49] (2.26) 1,2,3,7,8-PeCDF (1.43) 15.1 17.7 7.81 [2.36] [3.4] [2.68] 3.72 (3.61) (2.46) 2,3,4,7,8-PeCDF (1.32) 9.13 [8.37] 6 5.98 6.89 5.68 5.89 (3.61) (2.08) 1,2,3,4,7,8-HxCDF (1.38) 11.5 12.7 8.14 4.19 [3.98] 3.74 6.01 (2.02) 3.86 1,2,3,6,7,8-HxCDF (1.27) 11.6 14.5 [6.55] 4.37 [5] [2.63] 5.4 (2.06) 3.2 2,3,4,6,7,8-HxCDF (1.26) 9.5 9.99 [4.9] 4.85 5.76 [4.22] [5.4] (2.05) 5.01 1,2,3,7,8,9-HxCDF (1.66) (2.18) (1.85) (1.66) (1.48) (1.82) (2.73) (1.86) (2.63) (2.77) 1,2,3,4,6,7,8-HpCDF (1.5) 27.4 32.8 19.2 11.6 12.2 12 11.4 (2.31) 8.79 1,2,3,4,7,8,9-HpCDF (2.08) 4.56 4.2 (1.99) (1.76) (2.27) (3.31) (2.63) (3.29) (1.9) OCDF (3.57) [10.3] 14.8 (3.07) [6.56] 6.95 [6.83] [3.15] (2.96) [4.26]

**WH O-2005 TEQ (ND=0; EMPC=0)**  **0.00 151**  **126 115**  **165 83.0**  **74.3 3.28**  **0.00 1.39**  **WH O-2005 TEQ (ND=0; EMPC=EMPC)**  **0.00 151**  **129 116**  **169 84.0**  **109 4.12**  **0.442 1.40** 

**WH O-2005 TEQ (ND=DL/2; EMPC=0)**  **2.86 151**  **127 115**  **166 83.3**  **76.5 5.58**  **4.45 4.45**  **WH O-2005 TEQ (ND=DL/2; EMPC=EMPC)**  **2.86 151**  **129 116**  **169 84.1**  **109 6.26**  **4.70 4.46** 

**WH O-2005 TEQ (ND=DL; EMPC=EMPC)**  **5.73 151**  **129 117**  **169 84.2**  **109 8.39**  **8.97 7.52** 

Checkcode 943-130181-473154-978861-712399-397126-168589-525634-960876-500591-982 Lab ID MB1_8210_DF_SDSP2695_8210_001P2695_8210_002P2695_8210_003P2695_8210_004P2695_8210_005P2695_8210_006P2695_8210_007P2695_8210_008P2695_8210_009
( ) = DL [ ] = EMPC0 1000 2000 3000 4000 5000 6000 7000

**pg** 

# To**tals Project ID: P** **- 10124**  **P2695** Total PCDD/Fs (ND=0; EMPC=0) Total PCDD/Fs (ND=0; EMPC=EMPC) Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC)

# P2695 - Totals **Project ID: P-10124** 

# Sample Summary **Part 2** 

# Method 23

**An alyte**  **0_8210_ MB001** **Plant 5**

**Inlet-R1 Plant 5** 

**Inlet-R2 Plant 5** 

**Inlet-R3 Plant 5** 

**Outlet R1**  **Plant 5 Outlet**  **R2 Plant 5** **Outlet R3**  **Plant 5 Oven-R1** **Plant 5**

**Oven-R2 Plant 5** 

**Oven-R3**
pg pg pg pg pg pg pg pg pg pg **Totals**

TCDDs 0 2070 2290 1670 2310 1170 1430 28 59 0 PeCDDs 0 1300 1260 1180 1600 820 1040 56.7 62.6 17.2 HxCDDs 0 910 642 664 782 439 545 63 90.3 20.7 HpCDDs 0 578 385 334 336 221 268 40.8 27.8 9.41 OCDD 0 1500 1030 809 563 421 549 37.8 27.5 26.2

TCDFs 0 247 337 158 208 207 94 82.7 36 21.5 PeCDFs 0 90.6 111 50.7 60.5 53.7 42.1 44.7 0 5.73 HxCDFs 0 78.1 88 36.9 31.4 12.8 3.74 26.4 4.43 14.8 HpCDFs 0 38.6 43.3 27.8 14.3 15.7 12 11.4 0 8.79 OCDF 0 10.3 14.8 0 6.56 6.95 6.83 3.15 0 4.26

**Total PCDD/Fs (ND=0; EMPC=0) 0.00**  **6,810 6,200**  **4,930 5,900**  **3,370 3,990**  **391 280**  **98.1 Total PCDD/Fs (ND=0; EMPC=EMPC)**  **0.00 6,910**  **6,240 5,040**  **6,000 3,480**  **4,160 465**  **383 187** 
**Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC) 34.4**  **6,910 6,240**  **5,050 6,010**  **3,490 4,170**  **479 423**  **209**
**Total 2378s (ND=0; EMPC=0) 0.00**  **2,120 1,520**  **1,180 963**  **688 831**  **83.6 0.00**  **30.3 Total 2378s (ND=0.5; EMPC=0)**  **17.2 2,120**  **1,520 1,190**  **968 693**  **843 92.9**  **25.4 43.4**  **Total 2378s (ND=1; EMPC=0) 34.4**  **2,120 1,520**  **1,190 972**  **697 854**  **102 50.9**  **56.6**
**Total 2378s (ND=0; EMPC=1) 0.00**  **2,130 1,530**  **1,200 1,010**  **700 885**  **95.1 39.4**  **60.7 Total 2378s (ND=0.5; EMPC=1)**  **17.2 2,130**  **1,530 1,200**  **1,010 702**  **888 102**  **59.1 71.5**  **Total 2378s (ND=1; EMPC=1) 34.4**  **2,130 1,530**  **1,210 1,010**  **704 891**  **108 78.9**  **82.2**

Checkcode 943-130181-473154-978861-712399-397126-168589-525634-960876-500591-982 Lab ID MB1_8210_DF_SDSP2695_8210_001P2695_8210_002P2695_8210_003P2695_8210_004P2695_8210_005P2695_8210_006P2695_8210_007P2695_8210_008P2695_8210_009

( ) = DL [ ] = EMPC

# P2695 - Others **Project ID: P-10124** 

# Sample Summary **Part 3** 

# Method 23

**An alyte**  **0_8210_ MB001** **Plant 5**

**Inlet-R1 Plant 5** 

**Inlet-R2 Plant 5** 

**Inlet-R3 Plant 5** 

**Outlet R1**  **Plant 5 Outlet**  **R2 Plant 5** **Outlet R3**  **Plant 5 Oven-R1** **Plant 5**

**Oven-R2 Plant 5** 

**Oven-R3**
pg pg pg pg pg pg pg pg pg pg **Other PCDD/Fs (ND=0, EMPC=0)**

Other TCDD 0 2020 2240 1640 2250 1140 1430 28 59 0 Other PeCDD 0 1230 1200 1110 1510 777 983 56.7 62.6 17.2 Other HxCDD 0 768 544 571 705 372 454 63 90.3 20.7 Other HpCDD 0 331 223 195 202 130 161 27.4 27.8 0

Other TCDF 0 232 327 158 204 202 94 82.7 36 21.5 Other PeCDF 0 66.4 93.3 36.9 54.6 46.8 36.4 35.1 0 5.73 Other HxCDF 0 41.6 50.8 26.8 18 7.08 0 15 4.43 2.68 Other HpCDF 0 6.58 6.28 8.61 2.77 3.48 0 0 0 0
**Other PCDD/Fs (ND=0, EMPC=EMPC)**

Other TCDD 0 2020 2240 1660 2250 1140 1450 40.9 72.4 13.6 Other PeCDD 0 1230 1200 1110 1510 777 983 63.1 81.2 17.2 Other HxCDD 0 768 544 571 705 397 477 63 90.3 31.7 Other HpCDD 0 331 223 195 202 130 161 27.4 27.8 12.7

Other TCDF 0 280 332 198 239 227 154 106 67.6 27.8 Other PeCDF 0 89.6 104 61.8 71.5 78.6 46.6 50.8 0 10.4 Other HxCDF 0 48.2 60.2 29.2 18 24.9 12.7 18.8 4.43 13.1 Other HpCDF 0 11.5 11.4 8.61 5.81 5.38 0 0 0 0

Checkcode 943-130181-473154-978861-712399-397126-168589-525634-960876-500591-982 Lab ID MB1_8210_DF_SDSP2695_8210_001P2695_8210_002P2695_8210_003P2695_8210_004P2695_8210_005P2695_8210_006P2695_8210_007P2695_8210_008P2695_8210_009

( ) = DL [ ] = EMPC

### P2695 - TEQ overview **Project ID: P-10124**



### TEQ Summary **Part 4**

( ) = DL [ ] = EMPCMethod Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F = fail) 0 10 20 30 40 50 60 70 80 90 100

**% Rec.**  

### Mean Recoveries of Extraction Standards (N=10) **Project ID: P -** **10124 P2695**  Mean Std. Dev.Method Specification Limits: Tetra-Octa SS: 70-130% (F = fail) 0 20 40 60 80 100 120

**% Rec.**  

### Mean Recoveries of Sampling Standards (N=10) **Project ID: P -** **10124 P2695**  Mean Std. Dev.0_8210_MB001 95.3 95.1 88.6 88 92.5 89.9 83.9 96.3 91.6 92.6 86.1

Plant 5 Inlet-R1 85.1 84.3 84.1 83.5 90.8 83.9 82.3 82.9 81 80 84.1 Plant 5 Inlet-R2 91.5 88.7 86.7 87.5 93.1 94.5 89.6 87.1 84.9 85 91.8 Plant 5 Inlet-R3 76.7 80.9 78.6 77.7 79.5 79.1 72.2 75.8 77.9 76.5 77.6 Plant 5 Outlet-R1 98.1 95.9 96 93.3 97.6 100 94 96.2 94.3 91.7 97.8 Plant 5 Outlet-R2 96.2 95.8 94.2 93.7 96.8 93.5 88 93.7 91.9 91.5 92.4 Plant 5 Outlet-R3 82.3 86.7 88.6 90.3 91.6 91.7 85.9 80.8 82.8 83.5 88.5 Plant 5 Oven-R1 90.1 89.8 86.5 89.2 92.5 91.6 87.3 86.4 85.2 84.1 87.8 Plant 5 Oven-R2 98.8 94.8 89.6 91.1 95.6 93.4 87.5 96.1 92.8 92.7 94.9 Plant 5 Oven-R3 104 102 95 95 101 95.5 94.3 101 96.6 96.8 95.5

Average 92 91 89 89 93 91 87 90 88 87 90 SD 8 6 5 5 6 6 6 8 6 7 6 Min 76.7 80.9 78.6 77.7 79.5 79.1 72.2 75.8 77.9 76.5 77.6 Max 104 102 96 95 101 100 94.3 101 96.6 96.8 97.8 Within M23 QC TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE TRUE 13COCDD 13CTCDF 13CHxCDF 13CHxCDD 13CHxCDD 13CHpCDD Sample Number 13CTCDD 13CPeCDD 13CHxCDD Extraction Standard Percent Recoveries, % 13CPeCDF 13CPeCDF88.3 88.2 87.4 89.4 84.1 80.8 0_8210_MB001 98.3 97.8 101 99.9 96.9

84.2 81.4 85.5 83.8 82.9 79.2 Plant 5 Inlet-R1 96.1 98.5 97.8 98.8 96.5 90.4 92.2 91.9 90.7 91.3 84.6 Plant 5 Inlet-R2 99.1 98.8 101 102 101 79.1 75.4 77.9 78.6 73.8 71.2 Plant 5 Inlet-R3 98.3 99.5 98.9 101 97.6 97.7 93.2 97 97.7 97.3 92.1 Plant 5 Outlet-R1 96.6 98.9 96.7 99.1 96.6 92.5 92.3 94.7 92.4 90.4 87 Plant 5 Outlet-R2 98 97.8 99.1 101 98.4 86.6 85.2 89.1 89.2 87.7 85.2 Plant 5 Outlet-R3 99.8 98.3 98 102 101 86.5 88.8 88.8 89.4 89.6 84.4 Plant 5 Oven-R1 98.1 101 98.2 103 98.5 92.2 88.6 94.1 94.2 91.2 83.4 Plant 5 Oven-R2 97.1 97.4 99.2 100 98.8 96.1 93.3 96 99.4 97 90.7 Plant 5 Oven-R3 98.7 95.5 102 98.8 97.5

89 88 90 90 89 84 Average 98 98 99 101 98 6 6 6 6 7 6 SD 1 1 2 1 2 79.1 75.4 77.9 78.6 73.8 71.2 Min 96.1 95.5 96.7 98.8 96.5 97.7 93.3 97 99.4 97.3 92.1 Max 99.8 101 102 103 101 TRUE TRUE TRUE TRUE TRUE TRUE Min within M23 QC TRUE TRUE TRUE TRUE TRUE Sample Number CS/SS Percent Recoveries, % 37ClTCDD 13CPeCDD 13CHxCDF 13CHpCDF 13CPeCDF 13CHpCDF 13COCDF 13CHxCDF 13CHxCDF 13CHxCDF 13CHpCDFP2695 Page 1 of 5P2695 Page 2 of 5P2695 Page 3 of 5P2695 Page 4 of 5P2695 Page 5 of 5

# P2695 - DLs **Project ID: P-10124** 

# Sample Summary **Part 5 (DLs)** 

# Method 23

**An alyte**  **0_8210_ MB001** **Plant 5**

**Inlet-R1 Plant 5** 

**Inlet-R2 Plant 5** 

**Inlet-R3 Plant 5** 

**Outlet R1**  **Plant 5 Outlet**  **R2 Plant 5** **Outlet R3**  **Plant 5 Oven-R1** **Plant 5**

**Oven-R2 Plant 5** 

**Oven-R3**
pg pg pg pg pg pg pg pg pg pg 2,3,7,8-TCDD 1.79 2.19 1.95 2.02 1.63 2.46 3.33 1.77 2.7 2.03 1,2,3,7,8-PeCDD 2.12 3.48 4.48 4.43 3.76 3.34 5.11 1.76 2.75 2.31 1,2,3,4,7,8-HxCDD 2.09 2.31 1.89 1.62 1.68 2.39 2.61 1.77 3.16 1.87 1,2,3,6,7,8-HxCDD 2.06 2.34 1.77 1.72 1.71 2.16 2.66 1.68 3.25 1.81 1,2,3,7,8,9-HxCDD 2.14 2.42 2.09 1.76 1.96 2.5 2.78 1.88 3.09 1.99 1,2,3,4,6,7,8-HpCDD 2.48 4.14 4.28 3.68 2.81 3.85 4.7 2.05 2.71 2.22 OCDD 4.95 4.04 3.2 4.05 3.17 3.74 5.76 3.02 5.28 2.84
2,3,7,8-TCDF 1.3 1.74 1.53 1.56 1.21 1.46 2.59 1.83 3.39 2.26 1,2,3,7,8-PeCDF 1.43 1.69 1.41 1.35 1.34 2.9 2.78 1.86 3.61 2.46 2,3,4,7,8-PeCDF 1.32 1.51 1.38 1.37 1.25 2.67 2.4 1.74 3.61 2.08 1,2,3,4,7,8-HxCDF 1.38 1.63 1.41 1.21 1.09 1.42 2.23 1.34 2.02 2.26 1,2,3,6,7,8-HxCDF 1.27 1.58 1.41 1.1 1.03 1.35 2.08 1.37 2.06 2.17 2,3,4,6,7,8-HxCDF 1.26 1.81 1.38 1.28 1.19 1.45 2.28 1.42 2.05 2.19 1,2,3,7,8,9-HxCDF 1.66 2.18 1.85 1.66 1.48 1.82 2.73 1.86 2.63 2.77 1,2,3,4,6,7,8-HpCDF 1.5 1.83 1.95 1.4 1.21 1.53 2.14 1.88 2.31 1.35 1,2,3,4,7,8,9-HpCDF 2.08 2.41 2.4 1.99 1.76 2.27 3.31 2.63 3.29 1.9 OCDF 3.57 3.39 3.14 3.07 2.56 3.09 3.91 2.14 2.96 2.04

Total TCDD 1.79 2.19 1.95 2.02 1.63 2.46 3.33 1.77 2.7 2.03 Total PeCDD 2.12 3.48 4.48 4.43 3.76 3.34 5.11 1.76 2.75 2.31 Total HxCDD 2.09 2.35 1.91 1.69 1.78 2.34 2.67 1.77 3.15 1.88 Total HpCDD 2.48 4.14 4.28 3.68 2.81 3.85 4.7 2.05 2.71 2.22

Total TCDF 1.3 1.74 1.53 1.56 1.21 1.46 2.59 1.83 3.39 2.26 Total PeCDF 1.37 1.6 1.39 1.36 1.29 2.78 2.59 1.8 3.61 2.27 Total HxCDF 1.38 1.78 1.5 1.3 1.18 1.5 2.31 1.48 2.17 2.33 Total HpCDF 1.76 2.09 2.15 1.66 1.45 1.86 2.66 2.22 2.74 1.59
Checkcode 943-130181-473154-978861-712399-397126-168589-525634-960876-500591-982 Lab ID MB1_8210_DF_SDSP2695_8210_001P2695_8210_002P2695_8210_003P2695_8210_004P2695_8210_005P2695_8210_006P2695_8210_007P2695_8210_008P2695_8210_009