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PUBLICATIONS

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Or NBS SPECIAL PUBLICATION 630

U.S. DEPARTMENT OF COMMERCE/National Bureau of Standards

Oxidation of Sulfite Ion by

Oxygen in Aqueous Solution—

A Bibliography

—QC—

100

,U57

no i 630

1982

c. 2
NATIONAL BUREAU OF STANDARDS

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Oxidation of Sulfite Ion by Oxygen

in Aqueous Solution—A Bibliography

HATlONAi. BU8BAU

07 STANDARDS

LIBRARY MAY 14 1982

&Cioo

Francis Westley

Center for Chemical Physics

National Measurement Laboratory

National Bureau of Standards

Washington, DC 20234

Prepared lor: Morgantown Energy Technology Center

U.S. Department of Energy

Morgantown. WV 26505 and

Office of Standard Reference Data

National Bureau of Standards Washington, DC 20234

U.S. Department ot Commerce, Malcolm Baldrige, Secretary

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director

Issued March 1 982
Library of Congress Catalog Card Number: 82-600507

National Bureau of Standards Special Publication 630

Nat. Bur. Stand. (U.S.), Spec. Publ. 630, 34 pages (Mar. 1982) CODEN: XNBSAV

U.S. GOVERNMENT PRINTING OFFICE

WASHINGTON: 1982
OXIDATION OF SULFITE ION BY OXYGEN IN AQUEOUS SOLUTION

- A BIBLIOGRAPHY -

Francis Westley

National Bureau of Standards

Chemical Kinetics Division

Center for Chemical Physics

Washington, DC 20234

A list of references is provided for published papers and reports

containing rate constants or mechanisms for the oxidation of S(IV) by

oxygen in aqueous solution, with or without catalysts. Three hundred

and twenty papers are listed, the period covered extending from 1897

to 1981.

Key words: aqueous solution; bibliography: bisulfite ion; chemical

kinetics; oxidation; oxygen; sulfite ion; sulfur dioxide.

IUlFeDUCT I6N

This t ibl logra phy lists papers and reports on "the aqueous solution

kinetics of sulfite oxidation, with or without catalysts, as well as other closely related papers.

The oxidation of sodium sulfite in solution has wide applications

in various fields such as scrubber chemistry, photography, enzymology,

biology, photochemistry, polar ography, atmospheric chemistry, and the

chemistry of aerosols and fog droplets. The first study on the oxidation

of sodium sulfite in solution was performed by W. P. Jor Issen in 1897

on the basis of an observation stated by Fr iederic h Mohr in 1855 ^hat a solution cf sodium arsenite containing an excess of NaHCC^ Is quickly

oxidized by 6^ if a small amount of sulfite is added to the solution.

Jorissen's study was followed by the works of Eigelow ( 1898), Haber and

Bran (190C), Tfoung ( 1902), Titoff ( 1903), Lumiere, et al . ( 1905), and

Plnow (1912). ^ith the exception of the periods 191* - 1918 ( «orld War I)

and 19.42 - 1944 (World War II), the study of sulfite oxidation in aqueous

solution has continued without interruption from 1912 through today.

The present bibliography includes 320 papers dealing with sulfite oxidation

in solution or closely related papers.

The list is arranged chronologically by year, then within the same

year alphabet ically by author(s). For each paper there is a full reference

including the names of the authors, the title of the paper and the name

of the jour ra I . fln the left side of each reference is the so-called

"short reference, " which includes the last two digits of the publication

year, followed by the first three letters of author's name. If the paper

has more than one author, the first three letters of the second author's

name are also given. A slash separates the first three letters of the first

author from the first three letters of the second author. The full reference

format is demonstrated below;

71 CHE/C6F Cheng, R. T., Corn, M « , and Frohliger, J. D. , "Contribution

to the Reaction Kinetics of Water Soluble Aerosols and S6 2 in Air at PPM Concentrations," Atmos^ Environ^ J, 957 (1971).

1
IIST 6F REFERENCES

1 897

97 J6F Jorlssen, W. P., "Qxjgen Activation by Slow Oxidation of Sodium

Sulfite," ZA Fhvs^ Chen, £ toec h iomA Ve rwgndschaf

t

s l^ 23. 6 67

(1897).

1898

?8 BIG Bigelow, S. L., "Catalytic Effects on Oxidation Rate

of Sodiun Sulfite fcy the Air Oxygen," ZA Fh^s^ Chejj,

J&SSS&iSS* Jeraandscha ftsl. 28, 493 (1898).

1 9 0 0

©0 HAE/ERA Haber, F., and Bran, F., "Qn the Autooxidation. Port II.,"

Chemj, ^Leigzi.gJ 35, 81 ( 1900).

1902

»2 YGV Ifoung, S. W., "6n the Inhibition of Chemical Reactions by Foreigi

Substances, I .," JA AmA ChemA Soc. 24, 297 ( 1902).

19C3

©3 TIT Tltoff„ A. "Contribution to the Knowledge of Negative Catalysis

lr a Homogeneous System," Z&Phy_s «. Che ( le l gz ig j 4 5, 641

( 1903).

19<55

05 LEW/TUN Lumiere, A., Lumiere, L., and Seyewetz, A., "The Ant 1 ox i dat ion

of Sodium Sulfite Solutions and the An t 1 oxi da ti on Medium,"

Bull. Soc. Chlm. Fx. 33, 444 (19C5).

2
1912

12 PIN Plnnow, J., "Effect of Oxygen on Hydroqulnone and Sulfite,

Zm Wiss. Photocr. Photophja. Photochem. 11, 289 (1912).

1913

13 PIN1 Plnnow, J. , "Simultaneous Oxidation of Hydroqulnone and Sulfite

by Air," Zj. Elektrochcn, r9, 262 ( 1913).

13 PIN2 Plnnow, J., "flxidatlon and Preservation of Sulf 1 te-Hy droqui none

Solutions," Z& Photogr^ Fhot

o

ghvs . Pho t ochem^ ^12, 41

( 1913 ).

1920

20 MET? Meyer, J., "Oxidation of Sulfurous Acid by Ferric Salts,

SiSS* J&SS&A SUSS* £ 53, 77 ( 1920).

192 1

21 MIL/PA2 Mllbauer, J., and Pazourek, J., "The Oxidation of Sulfites in

Concentrated Solutions," Ckern^ IjjS 1J5, 34 ( 1921 ).

1922

22 BAI/EAI Baly, E. C. C., and Bailey, K. A., "Equilibrium in Aqueous

Solutions of the Alkali Metal Bi sulfites," JA ChegASec. 121

1 ei3 ( 1 922 ) .

22 MIL/PAZ Mllbauer, I. J., end Pazourek, J., "The Oxidation of Sulfites

in Concentrated Solutions," Bui gocj, C hj^m^ FrA 31 . 676 ( 1922),

3
1923

23 PIN Pinnow, J. , Reaction between Fesric Salt and Sulfurous Acid and

Its Catalysis," ZA Elektrochem^ 29, 547 (2923).

25 REI/UE Relnders, T» . , and Vies, S . I., "Reaction velocity of

0 xygen with Solution of some Inorganic Salts. III. The

Catalytic 6x idat iori oi Sulphites,TM Rec . Trav, mwChin. wwm

£sxjdla§ li» 249 C1925).

26 MAS/MAI Mason, R. B . , and Mathews, J. B . , "The Effect of Cltra- Violet

Light on the Oxidation of Sodium Sulfite by Atmospheric Oxygen,

J. Phys. Chen. 3, 414 (1926).

27 MI Y Miyamoto, S • , "The Effect of Alkali on the Oxidation of Sodium

Sulphite with Air," Bull. Chem. Soc. Japan 2, 74 (1927).

1929

29 ALY/BAE Alyea, E • N • , and Eackstrom, H. L. J., "The Inhibitive

Action of Alcohols on the Oxidation of Sodium Sulfite,"

J m Am. Chem. Soc. 51, 90 ( 1929).

29 F0E/BA1 Foerster, F., and Baufe, B • , " Su If urous Acid and its Salts. VI.

Auto-decomposition of Aqueous Bisulfite Solutions," ZA Ano rg^

AJdiU ChemA HZ. 17 ( 1929).

29 FOB/ E I B Foerster, F . , and Kircheisen, E. , " Sulfuroue Acid and its Salts

VII. The Mutual Action of Bisulfites and Sulfhydrates,"

Z. Anorja. Alls. Chem. 177 , 42 ( 1929).
193 1

31 BAB Haber , F ".Autooxidation," fla tvirw^gseagg&a JJ , 450 ( 1931 )

31 VIVKATi Miyamoto, S., and Kaya, T., "On the Rate of Solution of Oxygen

into Water, Part VI, The Sate of Absorption of Oxygen by Sodium

Sulphite Solution," Eul Chem. SocA Ja^an 6, 264 (1931).

31 RI C Rlchter, D., "The Action of Ferrous Iron in Induced Reactions, n Ber, Dtsch,, Ctjen^ GesA B 64, 1240 ( 1931 ).

1932

32 ALB/GOL Albu, H. W., and Goldflnger, P., " Autooxidation , IV. Absorption

Spectrum of Aqueous Solutions of Sulfurous Acid in Relation to

their Autooxidation," Z. Pljjs. Chem. B 16, 338 ( 1932).

32 ALB/SCB Albu, H. W., and von Scbweinltz, H. D. , "Autooxi d e tions. V.

Formation of Dithicnate by the Oxidation of Aqueous Sulfite

Solutions," Eer. Itsch. Chea. Ges, B 65, 729 (1932).

32 BA11 Baumg&rten, P., "The Oxidation of Aqueous Alkali Sulfite Solutions with Cupric Salts in the Presence of Pyridine,"

Be

r

& Dtschj, Ctieg^ Ges^ B 65, 1637 ( 1932).

32 HAB/^AN Haber, F . , and lansbrough- Jones , 0. H. , "The Effect of

Light on the Oxygen Free\ and Oxygen Containing Sulfite

Solutions," Zj, PhjJa, Ch em^ B 1_8 , 103 ( 1932).

32 V0L/EEL1 Volfkovich, S. I., and Belopolekii , A. P., "Oxidation of Sulfites. I." Zhur. Frikl. Khim. 5, 509 (1932).

32 V0I/BEL2 Volfkovich, S. I., and Belopolsk 11 , A. P., "Oxidation of Sulfites. II." Zhur^ Priklj. Khlg4 5, 529 ( 1932 ).

32 V0I/BEI3 Volfkovich, S. I., and Belopolskll, A. P., "Oxidation of Sulfites. III." Zhur. Prlkl^ Khim. 5, 552 (1932).

1933

33 BRI/EIE Briner, E. , and Bledermann, H. , "The Role of Ozone as Catalyst

oi Oxidation. V. The Ozonization of Sodium Sulfite - Influence of

the Dilution of Ozone and the Concentration of Hydrogen Ion,"

Helv. Chlm. Acta 16, 548 (1933).

5
1934

34 HOA/GOd Hoather, R • C, and Goodeve, C. F . , "The flxldat Ion

of Sulphurous Acid. I. The Dllatomotrlc Technique,TM

Trans. Faracay. So 30, 626 ( 1 934 )

.

34 H0A/GOC2 Hoather, R. C, and Goodeve, C. F. , "The 6xidatlon of Sulphurous

Acid. II. Determination of the Molal Volume of Se^, Og, and S63

ij

Dilute Aqueous Solution," TransA Faraday SocA 30, 630 (1934).

34 H0A/G0e3 Hoather, R . C, and Goodeve, C. F . , "The Oxidation of Sulphurous

Acid. III. Catalysis fay Ma n pan o -us Sulphate," Jrans^ Faraday SocA

30, 1149 ( 1934 ).

34 H0A/G0C4 Hoather, R.C., and Goodeve, C. F •

, " The Oxidation of Sulphurous

Acid. IV. Catalysis by a Glass Powder Containing Manganese and

Iron," Trans. Faraday Soc. 30, 1156 (1934).

34 SEI/DIN Relnders, W., and Dingemans, P., "The Speed of Oxidation of

Hydroquinone by Oxygen. II. Influence of Sodium Sulfite,"

Dec. Trav. Chlm. Pays-Eas 53, 231 (1934).

1935

35 BAS/HEN Bassett, H • , and Henry, A. J., "The Formation of Dithionate by

the Oxidation of Sulphurous Acid and Sulphites," J. Chem. Soc.,

914 ( 1935).

35 GF01 Grodzovskl 1 , M. K . , "l . Mechanism of the Catalytic Oxidation of

Sulfur Dioxide in a Solution of Manganese Salts,TM Zhur ^ FJ. z^, ghlrn. 6, 478 (1935).

35 GR02 Grodzovskl 1, M • K., "il. Action of Ozone on Solutions of Manga»

nous Salts," Zhur. Flz. Khlm. 6, 496 (1935).

35 ^AS/KAS ^assiljew, S. S., Kaschtanow, I . I., and Kastorskaja, T. L.

,

"The Kinetics of the Oxidation of Sulfur Dioxide Solutions,"

Acta Physic ochlm. CRSS 3, 413 ( 1935); (see also 36 VAS/KAS )„

1936

36 BAH Baumgarten , P., "The Au tooxidation of Aqueous Sulfite Solutions

in the Presence of Pyridine. The Reaction Mechanism of Sulfite

Autooxidat Ion. II. The Autooxidati on of Aqueous Sulfite Solution!

in the Presence of Pyridine," Ee r,, DJtscha Chem^ Gee.^ B 69, 229

( 1936 ).

6
36 VAS/KAS Vasllev, S. S., Kashtanov, L . T., and Kastorskaya, T. L., "The

Kinetics of -the 0xlda-tlon of Sulfur Dioxide Solutions,"

ZijUfj FlzA Khlm^ 7, 90 (1936); (see also 35 ^AS/KAS).

1937

37 BAtl/EFE Baumgarten , P., and Erbe, H. , "The Mechanism of Sulfite flxidation of Aqueous Sulfite Solutions," Ber, Dtsch, Chen. Ges. B

70 . 2235 ( 1937 ).

194 1

41 FU1/CKI Fuller, E. C, and Crist, R. H. , "The Bate of Oxidation of

Sulfite Ions by 6xygen," JA Am^ Chem. Socj 63, 1644 ( 1941).

1946

46 KEIf Keyes, H. E., "Autooxldation Process for Sulphuric Acid and

Sulfate Production," Cfcem. Metall. Ene. 53, 126 ( 1946 ).

1947

47 PTtE Pye, D. J., "Chemical Fixation of Iron," JA Amj, Water gort^g

&&&8SA 12» 112 1 (1947).

194 9

49 BT3B/H3C Bur riel -Mar 1 1 , F., and Lucena Conde, F., "Contribution to the

Study of the Seduction of Ferric Salts with Sulphurous Acid,"

Anal. Chim. Acta 3, 547 (1949).

7
195 1

51 ABE 1 Abel, E,, "On the Oxidation Theory of Sulfite to Sulfate

by flxygen, " Monat eh . Chen. 82, 815 (1951).

51 BAS/PAI Bassett s H. s and Parker, W . G. , "The Oxidation of Sulphurous

Acid," J. Ct-em. Sec., 1540 ( 1951 ).

£1 WIK/BSI Winter, E. E. S. s and Briscoe, E • V. A., "Oxygen Atom

Transfer during the Oxidation of Aqueous Sodium Sulfite,"

J . Am. Chen. Sec. 73, 496 ( 1951 ).

195;

£2 HAl/TAt Halperin, J., and Taube, H«, "The Transfer of Oxyaen Atoms

in Oxidati on-Reduct Ion Reactions. IV. The Reaction of Hydrogen

Peroxide with Sulfite and Thiosulfate, and of Oxygen, Manganese

Dioxide and Permanganate with Sulfite," Anu Chen, Socj, 74, 330 (1952).

52 SOF/CBA Sorum, C. H • , Charlton, F„ S., Neptune, J. A., and Edwards,

J. 0. 9 " pH Change as an Index to Reaction Mechanisms,"

J. Am. Chen. Soc. 74, 219 (1952).

£2 TER/ISN Terem, B. N . , and Tsnel , A. H. , "Oxidation and Stabilization

of Alkaline Sulfite Solutions.TM" %n«MV>w« Rev. ^vnviwo Fac . wv%k«s^ Sci. v^M Univ. ^mJ** <^M>M Istanbul A WWMWilMII *#»

J, 7, 138 (1952).

1953

53 D'A/MAl d'ANS, J., and Mattner, J., "inhibition of Catalytic Activity

of Heavy Metals by Magnesium Hydroxide," Angejjj, ChemA 55, 368

( 1953).

53 FOE/MEN Foffani, A., and Menegus-Scarpa , M .

, " Spect ropho tomet ric

and Polarographic Study of the Cuprous Sulfite Complexes,"

Gazz. Chlra. Ttol. 83, 1068 (1953).

53 HEI/FPI Heimberg, M . , Fr idovlch, I., and Handler, P., "The Enzymatic

Oxidation of Sulfite," J. Biol. Chem. 204, 913 (1953).

8
1954

54 ABE1 Abel, E., "The Probable Mechanism of Autooxldat ion in Aqueous

Systems in the Abeence of Light, Remarks on the Mechanism of the

Auto ox Idaticr of i" and Se^ 2 ", " Man aJ^h^ S&IS8L* £5., 722 ( 1954).

54 ABE2 Abel, E., "The Thermal Autooxida tion of Sulfite. Action of

Negative Catalysts," Monatsh. Chem. 85, 1003 (1954).

54 BRE/AIG Bret szna jder , S., and Augustyn, W., "Absorption of Sulfur

Dioxide in an Alkaline Solution of Aluminium Sulfate.

IV. Dependence of Sate of Reaction between Oxygen and Absorbed

Sulfur Dioxide on Temperature and Presence of a Catalyst,"

Przem. Chem. 33, 295 ( 1954).

54 DAE Darykina, M . I., "Action of Phenolic Inhibitors on the Rate of

fi X 1 da tier, of Sodium Bisulfite," Tr udy Moskoy^ iSiSijC^^SSLA X&JLJLaa

Khim. i Ehin. F t c Izvod s tvo , 143 (1954).

54 KAS/KA21 Eashtanov, I. I., and Kazanskaya, N. V., "Mechanism of

Inhibitor Action," Zhur. gbshchj, Khim. 24, 1597 ( 1954 ).

54 KAS/ITK Kashtanov, 1. I., and Lukyanov, A. B., "Mechanism of Inhibiting

Reaction," Trudy Moskov. Inzh. -Ekon. Inst.. Khim. i Khim.

Pr^o^zyodstyo. 135 ( 1954 ).

54 KIK/BCK Kikuchl, S., Honda, K . , and Kim, S., "Removal of Dissolved

6xygen by Sodium Sulfite. Application to the Pol arograph ic

Study, " Bull. Chem. Soc. Japan 27, 65 ( 1954).

1955

55 ABE Abel, E., "The Autooxi dation of Nonirr adiated Homogeneous

Aqueous Solutions. With Special Reference to Inorganic Systems,'

E_lek t ro cheg^ 59, 903 ( 1955).

55 BRE Bretszna jder , S., "Catalytic Oxidation of Sulfur Dioxide

absorbed in a Solution of basic Aluminum Sulfate,"

Rocz. Chem. 29, 227 ( 1955).

55 GER/Jfll Gerhard, E. R . , and Johnstone, B. F . , "Photochemical exidatlon

of Sulfur Dioxide in Air," J.nd A EngA Chem,, 47, 972 ( 1955 ).

55 FA6/ SAC Rao, K . B. , and Rao, G. G., "Ox idi me tr ic Methods for the Volumetric Estlaation of Sulphite," Anal. Chim. Acta 13, 213 (1955)

55 WIN Wlnkelmann, D., "Electrochemical Measurement of the Rate of

6xidation of Sodium Sulfite by dissolved flxygen,"

2, Elektrochem. 59, 89 1 (1955).

9
56 ABE Abel. E . , "Anionic Catalysis of Autooxldatlon,"

Monatgh, Chem. 87, 113 ( 1?56 ).

56 ATE/LOt Aten, A. W. H., Jr., Louwrier, K. P., Copper* s, P., Kok, H. A.,

De Roos, A. M., Kriek, E., Hillege, A., Voll brach 1 , I., and

Hartog, F. , "The Reaction of Sulphite Ions in Solution with

Persulphate and Pyrosulphate," J[A jnorgA NucU Chem. 3, 296

( 1956).

56 BRE/KGT Bretszne Jder , S., Kotowska , W., and Pi skorski , J., "Reaction

Process between Ferric Sulfate and Sulfur Dioxide in Solutions

containing Aluatinutt Sullate." Rocz. S£l££l&a 30, 411 ( 1556 ).

56 COt Coughanowr, D. 6 •

, "flsidatlon of Sulfur Dioxide in Fog Droplets,

Abstr. 16 1 1647 ( 1956).

56 FRI/H AN 1 Fridovich, I., and Handler, P., "Sulfite Oxidation by Xanthine

6xidase," S^j^osiun on Jno rgA Ni, trogen Met abol isgj Funct i on of

Jcjhrjs Ho|klia SSi^d* Conlrlb. No& 1,25, 53 9 ( 1556 ).

£6 FRI/HAK2 Fridovich, I., and Handler, P., "Hypoxan thine, Cof actor for

Cysteine Oxidation by liver Preparations," B^iochig^ B iog hys^

Acta 21,, 173 (1956); see also: Fed. Froc^ Fed. Ab^ SoCj, Ex£A

B^olj. J4, 2 14 ( 1S55 ).

56 FRI/HAK3 Fridovich, I., and Handler, P., "Hypoxan thine as a Cofactor for

the Enzyna tic OsiOatlon of Sulfite," J& JJiolj, Chetjj, 221. 323

( 1556).

56 FRI/BAK4 Fridovich, I., and Handler, P., "The Initial Step in Enzymatic

Sulfite Oxidation," JA ElolA Chenu 223 , 321 (1956).

56 SCH/GAE Schultz, J « S . , and Gaden, E. I , Jr., "Sulfite rtxidation

as a Measure of Aeration Effectiveness," J. ncij, Enjr.^ Chea^

43, 2205 ( 1<56 ).

56 SCH/STE Schwab, G. M., and Strohmeyer, N., "The Kinetics of the

Autooxidat ion of Eenzaldehyde and Sodium Sulfite in the Dark,"

Z . Phys, Chen. (Frankfurt am Main) 7, 132 ( 1956).

10
1^57

57 BOT/CUI

57 CHE1

Bot toml ey , G • A., and Cullen, V> u 1 • , "induction E 1 fee Is in the

Oxidation of Bisulphite Ion at pH 4," Chem^ SoCj,, 4592 ( 1957)

Ctertkov, B„ A., "flsldatlon of Ammonium Sulfite -Bisulfite

Solutions," JA Ajajl^ Chjgj USSR 30, 1564 ( 1957); tr. of:

Zhurj, Priklj Khim, 30, 1496 (1957).

57 FP I/HA IS Fridovicb, I., and Handler, P., "Xanthine Oxidase. I. The Oxidation of Sulfite," Elol L

», Chen. 228 , 67 ( 1957),

57 HIG/NAF fllgglnsoi), W • C. £, , and Marshall, J . V . , "Equivalence

Changes in Cxidation-Rf ductlon Reactions in Solution : Some

Aspects of the Oxidation of Sulphurous Acid," J^. ChegA

447 (1957).

57 PIF/CAI Plrt, S. J., Callow, D. S. , and Gillett , W. A. , "Oxygen

Absorption Bates in Sodium Sulphite Solution. Comparison of

Cu 2 * and Co 2 * as Catalysts," £gsg» lag* UaS&&&8l1* 730 (1957).

57 WII/KIK Williamson, F. S. , and King, E. L. , "The Kinetics of the Reaction of Sulfite and Eromate," J*_ Am& Chem. Soc^ 79, 5397 ( 1957).

1958

58 FRI/FAF Fr idovich, I., Parkas, W. , and Eandler , P., "Sulfite Cxidation

in Rat Liver," Eull^ SociChlra. E^iol^ 40, 1795 ( 1958).

58 FRI/BA*2 Fridovich, I., and Handler, P., "Xanthine Oxidase. III. Sulfite

Oxidation as an Ultra Sensitive Assay," JA jiiolA Chegj 233 . 1578

C 1958)

58 FRI/BAK3 Fridovich, I., and Handler, P., "Xanthine Oxidase. IV. Participation of I son in Internal E lectron Transport," Jj, Bi^olj^ C hem^ 233, 1 581 ( 1958 ).

58 JOH/COt Johnstone, H • F . , and Coughanowr , D. R . , "Absorption of

Sulfur Dioxide from Air," Jnd^ Eng. Chemj, 50, 1169 ( 1958).

58 JUN/EYA Junge, C. E . , and Ryan, T. G., "Study of the S0 2 exldati on

in Solution and its role in Atmospheric Chemistry,"

0. J. R. Meteorol. Sec. 84, 46 (1958).

58 MAE Mader, P. M . , "Kinetics of the Hydrogen Peroxide - Sul f ite Reaction in Alkaline Solution," Jj, AmA ChemA SoCj 80, 2634 ( 1958 ).

58 NETf/TA \ Neytzell-de Wilde, F. G . , and Taverner, L . , "Experiments

relating to the passible Production of an Oxidsirg Acid Leach

Liquor by Auto-oxidation for the Extraction of Uraniun,"

Proc^ 2nd UK Internj, Conf. Peaceful Uses At^ Ener^ 3, 303 (1958)

11
1959

59 CHE1 Chertkov, E . A,, "Effects of Temperature and Partial Pressure

of 6xygen in the Gas on the Oxidation Pate of Ammonium SulfiteBisulfite Solutions, " J & Aggl^ Chen. USSR 32, 78 (1959);

tr. oft 2hurd P?i kl^ Khirn^ 32, 78 (1959).

59 CHE2 Chertkov, B. A., "Oxidation of Ammonium Sulf ite-E isul f ite

Solutions in the E j tract ion of £02 from Flue Gases,"

Jj, &£S\» ChemA USSR 32, 983 ( 1959); tr. of: Zhur^ P^ikV. U3i&s,

32, 960 (1959).

59 CHE3 Cr.ertkov, B. A., "Theory of the Sxidatlon of SulfiteBisulfite Solutions," J & Aggl^ Cheg. USSR 32. 1687 ( 1959);

tr. of: Zhurj Prj,klA KhJSj. 32, 260 9 ( 1959).

59 FRI/HAfc Fr idovich, T., and Bandler, P., "Utilization of the Photosensitized Oxidation of Sulfite for Manometric Ac t i none etry ,

B ioc h injji SiSfiJJjA Ac la 35, 546 ( 1959).

59 JOE Jorlssen, W. P., "induced Oxidation," pp.26 - 31 (Elsevier

Publishing Company, Amsterdam , 1959).

a 9 6©

60 CHE

60 DUB/NAI

60 F R I/HAN

60 JOH/Mei

60 OKA/KAN

60 CKA/GVA

60 €KA/ SAh

Chertkov, B, A., "exlda t ion of Magnesiun Sulfite and Bisulfite

during extraction of S6 2 from gases," Jj^ Chettj ^CSSR 33,

2136 (I960 ); tr. of: Zhjjra PriklA Kh|m. 33, 2165 (I960).

Dubovaya, V, K . , and Nabiev, M . N. , "Oxidation of Potassium

Sulfite in the Process of Nitric Acid Treatment of Phosphates,

Using Sulfur Dioxide," Uzbek. Khim. Zhur., 3 (1960).

Fridovich, I., and Bandler, P., "Detection of Free Radicals in

Illuminated Dye Solutions by the Initiation of Sulfite Oxidation," JA Bio\A Chem. 235 . 1835 (1960).

Johnstone, H. F . , and Well, A. J., "Formation of Sulfuric

Acid in Fogs," Ind. Ens. Chem. 52, 861 (1960).

Okabe, T., Kamisawa, K., and Hori, S«, " Autooxida tlon of Sulfites and the Related Salts in Aqueous Solution. III. Autooxidatlon of Zinc Salts," Niton Kagaku Z ass h i 81, 529 (I960).

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Sulfurous Acid," Nipon Kaoaku Zasshi 81, 1818 (1960).

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Autooxidat ion of aluninum Salts," Nipppt] Kagaku Z^jghji &JL B 1814

( 1960 )

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12
1961

6 1 CHE Cfcertkov, B . A . , General Equation for the 6x idat Ion Fate

oi Sulfite -Bisulfite Solutions in the Extraction cf S«

2 from

Gases," J* 2§JS * ?43 (1961); tr. of:

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61 DEV/JAI Dev s B 8js and Jain, B. B . , "inhibitors in the Au too si da t i on of

Sodium Sulfite Solutions," J» Sci. Ind. Pes, Sect.D 2C, 46 1

( 1961 ).

61 EIG/KTJS Eifien, M Evstin, J., and Maass, G. , "Rate of the Hydration

of S62 in Aqueous Solution," Z. Ph^Sj, Chem* ^Frankfurt an MainJ

30, 130 (1 561 ).

61 FR I/HA U Fr ldovlch, I., and Handler, P., "Detection of Free Radicals Generated during Enzynic Oxidations by the Initiation of Sulfite

Oxidation, " J. Biol- Chen. 236 , 1836 (1961).

61 P6X./HAK Pollard, F «, H . , Hanson, P., and Nickless , G . , "Chromatographic

Studies on the Oxidation of Sulphurous Acid by Ferric Ion in Aqueous Acid Solution," JA

C ti r oraat cg^, 5, 68 (196 1).

61 PHI Pri tchett, P. V . , "The Catalyzed Reaction of flxyaen with

Sulf urous Acid and its Effect or the Absorption of Oxygen and

Sulfur Dioxide Into Water," Diss. Abstr. 21, 2652 (1961).

61 ZEL/JAK Zelionkait e, V., Janickis, J., and Likslene, K. , "exidat ion of

Sulfite Solutions with 6xygen In the Presence of Sele not ri t hlonate." Llet. 3JR AukstA Mokjklu Mokslo Darbj, Chen,. Chem. TechA

J. , H2 ( 1961 ).

1962

62 CHE/VAS Cfcertkov, E. A. , Vasilev, E. T . , and Dobromyslova , N. S.

,

"Increasing the Stability of Annon ium Bisulfite Used in the

Production of Caprclact am, " KhigA P romA . 633 (1962).

€2 EAV/SM I Davis, G. G • , Smith, M. , "The Kinetics of the Formation

of the Mono sulpha to Con flex of Iron (III) in Aqueous Solution,

Can. J. Chen- 40, 183C (1562).

13
62 SAF/GLt Sapotn itskl 1 , S. A. a and Glushcbenho, N. V. , "Oxidation of Sulfites with Air in Dilute Acidified Solutions," AgglA Chemj,

H» 2 104 < 1?62 ); 1r. of: Zhur. Prj^kl^ Kbim* 25, 21

62 SHI/HAW Shlrai , T. , Hacrad a , £., Takahashl, H. , <3zavia, T. , Ohnura, T. , and

Kawa&ami, T • , "Photoonldation of SGg in Air," Kog^o Kagaku

Zasshi 65, 1906 (1962).

62 STA/SCE 2 Stauf f , J., and Schnldkunz , H. , " Chemi luroi ne seen ce of Oxidation

Reactions. Ill, 6 xygen - van der ftaals Associates as Possible Substrata of ti-e Che n llunr 1 ne scene e s " ZA PbjjsA Cbem& ^Fr ankjur t am

Main) 35, 2«5 ( 1962 ).

62 YAG/INf Yagl, S., and Inoue , E, s "The Absorption of Oxygen into Sodium

Sulphite Solution," Chen. EngA

ScjU 17, , 411 ( 1962).

1963

63 BAF Barron, C. E . , "Reaction Kinetics of the Oxidation of Sodium

Sulfite by the Sapid-nlxing Flow Method," Diss. Abstr, 24,

2388 ( 1 963 )

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63 KAF Kar raker , D. G . , "The Kinetics of the Reaction between

Sulfurous Acid and Ferric Ion," J. Phys. Chen. 67, 87 1 (1963).

63 SCH1 Schroeter, L. C . , "Kinetics of Air Oxidation of Sulfurous

Acid Salts," JA Phar Sc i» 52, 559 (1963).

63 SCH2 Schroeter, I. C . , "Potentiometric Determination of Sulfite

Oxidation Rates," J^. Pharg. Scl. 52, 56* ( 1963).

63 SCH3 Schroeter, L . C . , "Oxidation of Sulfurous Acid Salts in Pharmaceutical Systems," J± PhartnA

Sci. 52 . 888 ( 1963).

63 STA/SCE 1 Stauf f , J. , and Schnldkunz , H. , "Chesri lumi nescence of Oxidation

Reactions. IV. Determination of the Radical Concentration by

Cheniluminescence and Electron Spin Resonance," 7 A Pbvju Cji emA

(Frankfurt am Main) 36, 61 (1963).

63 STA/SCE 2 Stauf f, J. , Schnldkunz, H . , and Hartmann, G. , %eek Chemilumi nescence of Cjiication Reactions," Na ture UondonJ ,198.

281 (1963).

63 TEM/FTS Tenple tor,, C. C. , Pushing, S. S. , and Rodgers, J. C. , "Solubility Factors Accompanying Oxygen Scavenging with Sulfite in ""111 Field Brines," Mater. Frot. (8), 42 (1963).

63 VAN/MAS Van den Beuvel, A. F . , and Mason, £• J., "The f oraati on of

Ammonium Sulphate in Water Droplets Exposed to Gaseous Sulphur

Dioxide and Ammonia," Q. R^ Meteorolj, SocA 89, 271 ( 1963 ).

14
.196.4

64 AST/MAE Astarlta, G., Marrucci, G,, and Celetl, L., "Catalytic

Oxidation of Sodium Sulfite: A Method to Measure the Interfacial Area," Chin. Ind. (Milan) 46, 1021 (1964).

64 STE/IIK Stephens, B. G., and Linds-trcm, F., "Spect rophotonetr ic Determi'

ration of Sulfur Eioside Suitable for Atmospheric Analysis,"

Anal. Chem. 36, 1308 ( 1 <=6 4 ).

196 5

65 COt/KEA Coughanour, D. R., and Erause, F. E . , "The Reaction of SO,

and 0g Aqueous Solutions of MnSO^

4, 61 ( 1 96 5 )

.

Ind. Eng. Chem. Fun dam,

65 HAI/PEF Baiaht, G. P., Jr., Perchcnock, E. , Emmenegger, F., and Gordon,

G . , "The Mechanism of the Oxidation of Sulfur(IV) by Chromlum( VI

)

ic Acid Solution," J. Am. Chem. Soc. 87, 3385 (1965).

65 VEP/^AG Veprek-Slskba, J., and lagnerova, D. M . , "One-equ ival en t Oxidations. I. Oxidation of Sulfite by Means of Potassium Bexacyanof er rate( III ) , " Collect. Czech. Chem, Commun. 30, 1390 ( 1965).

1966

66 BAB/O'B Barron, C. 1., and C'Bern, H • A., "Reaction Einetlcs of Sodium

Sulfite Oxidation by the Sapid-mixing Method," Chei, En^^ ScjL^

21, 397 (1966).

66 SCB Schroe t ter , 1. C, "Sulfur Dioxide. Applications in Foods.

Beverages, and Pharmaceuticals," pp. 34-76, ( Pergamon Fress,

Oxford. 1966).

66 SHA/GRE Shaw, J. T., and Green, P. D . , "Oxidation of Sulphur Eioxide in

Air at 950° C. ; Co-operati"ve Influence of Carbon Monoxide and

Nitric Oxide," Nature (.LondonJ 211 . 1171 ( 1966).

66 VEF/S0I Veprek-Siska, J., Solcova, A., and Wagnerova, D. M., "8neequivalent Oxidations. III. Kinetics of Sulfite Oxidation by

Pentacyano f errate( 1 1 1 ) , " Collect^ Czech. CherrA Cogmun^ 31.

3287 ( 1 966 ) .

15
66 VEF/tSE Veprek«Slska, J., en« Urer, L. , "Reduction of Nitric Acid by

Means of Sulfur Dioxide," Collect, Czech. Chen. Ccmtnun. 31.

4 363 ( 1966 ).

66 VEP/WAG Veprek-Siska , J., Wagnerova, D. M. , and Eckschlager, K., "OneEquivalent SxldaUons, II. Oxidation of Sulfites by Means of Complex Ions," Cc.1 le c tj, Czech. ChefflA Commu n^ 31 . 1248 ( 1966 ).

66 WAA/flKE Waal, K. J. D. de , and Ckeson, J„ C, "The oxidation of

sodium sulfite solutions," Chems Eng^ Scj^ 2A 3 555 ( 1566 ).

1967

67 RAN/GAI

67 SC0/H6B

Rand, M . C, and Gale, S. E., "Kinetics of the Oxidation of

Sulfites by Dissolved fxygen," Frj^cjjales Apjalj^ ~S£SS £J2£5L*A

PJ-SSj. SjJ^allS SSSj Corf,^ 4thA Rutgers^ State Univ. 4, 380 ( 1967).

Scott, W. D • , and Hobbs, P. V., "The Forncation of Sulfate in

Hater Droplets," J. ilnos. Sci. 24, 54 (1967).

67 SWI

67 VEP

Swinehart, J. H., "Tfce Kinetics of the Hexacyano f errate( II I )-

Sulphite Reaction," J_. Inorg. Nucl. Chemj, 27, 2312 ( 1567).

Veprek-Slska, J., "Oxidation of the Sulfite Ion with Singleequivalent exidizing Agents," Ann& Genje Chlm . 3, 126 ( 1967).

1968

68 CAV Cavaslno, F . P., m h Temperature- Jump Study of the

Kinetics of the Formation of the Monosulfato Complex of

Iron ( III)," J. Phjs. Chen. 72, 1378 ( 1968).

68 FOM/DTfM Fomlna, T« V., Dymarchuk, N. P., and Mishchenko, K • P., "Chemical and Amperomei ric Study of the Kinetics of the Peaction between

Na gSfl^ and K2^2^8 * n *9 ueous Solution," J^. Ajjgls. Chegj,

t SSR 41., 932 (1568); tr. of: Zhurj. PriklA Khire* 4T

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68 GRI G rigoryan, g. "Mechanism of the Oxidation of Sulfites

to Sulfates by Atsospheric 6xy gen in the Presence of Nitrogen

Oxides," Aro4Khinn^. Zhur. 2_l a 711 ( 1968).

16
68 SRI/MCN Srlvastava, R. D . , McMillan, A. F. , and Harris, I. J., "The

Kinetics of flxldatlon of Sodium Sulphite," Csn^ JA

Chern^ Engj,

4 6, 181 (156 8).

68 VEP/HAS Veprek-S is ka , J., and Basnedl, A., "Specific Effects of Electrolytes on the Oxidation of Sulphite by Hexacyanof errat e (III),"

Cten^ Ccnmj, 1167 (1568).

1965

69 FOS Foster, P. M • , "The Oxidation of Sulphur Dioxide in Power

Station Plumes," Atmos. Environ. 3, 157 (1969).

69 MAT/BAB Matsuura, A., Harada, J., Akehata, T., and Shirai, T e , "Sates cf Antranium Svlfite Oxidation in Aqueous Solutions,"

Jj Chem. Enj. Jajan 2, 155 ( 1965).

69 MAT/ SIC Matteson, M. J., Stoeber, W., and Luther, H • , "Kinetics of

the 6xldatlcn of Sulfur Dioxide by Aerosols of Manganese

Sulfate," Ind,* En^ £hegA Fundam^ 8, 677 ( 1969).

69 MCC/FE 12 McCord, J. M • , and Fridovich, I., "The Utility of Superoxide

Dismutase in Studying Free Radical Reactions," EJ.pl,. Cheni

244, 6056 ( 1565 ) .

1C7C

70 BET/\eS Betts, R. H . , and Voss, K. H. , "The Kinetics of fxyaen

Exchange between the Sulfite Ion and Water," CanA

C hern^, 4J, 2035 ( 1 «70 ).

70 CAB/KIK

70 COD

7 0 C 0 5/F E K

Carlyle, D. w., and King, E. L . , "The Influence of Sulfite Ion

upon the Rale of Aquation of Various Complexes of Chromium( 1 1 1 ) Ion. The Stability of Su I i 1 1 oc h rotn lum( III) Ion," Jnor£. Chem.

9, 2333 ( 197C ).

Code, R. K . , "The Aqueous Phase Catalytic Oxidation of Sulfur

Dioxide," DisSj. Atjtr. Intj. B 30, 4114 ( 1970).

Cox, R. A., and Fenkett, S. A., "The Photo-oxidation of Sulphur

Dioxide in Sunlight," AtmosA Environ^ 4, 425 (1979).

70 GTJN/SAL Gunn, D. J., and Saleem, A., "Absorption and Liquid-Phase Oxidation of Sulphur Dioxide," TrasA InstA Chema En^j, 48, T46

( 1970).

70 HOF/^EI Horn, R. W., We i s s te rg er , E. , and Collman, J. P., "An Oxygen-18

Study of the Reaction between Iridium- and Platinum-Oxygen Complexes and Sulfur Dioxide to form Coordinated Sulfate,"

Inorg^ ChemA 9, 2 367 ( 1570).

17
70 IIN/NA\1 linek, \ ., and Mayr hof er ova , J., "The Kinetics of Oxidation of

Aqueous Sulphite Solutions in the Presence of CofceltC II ) Sulphate," Collect^ Czech, Cheng, Cogmun, 35, 688 ( 1970).

70 I IK/ MA 2 Linek, V.„ and Mayrhof erova, J., "The Kinetics of Aqueous

Sodium Sulphite Solution, " Chen. £2&& , 7e7 ( 1970 ).

70 NAF Nakamura , S «, , "initiation of Sulfite flsidatlon by Spinach

Ferredoxin-NADP Reductase and Ferredoxin System: A Model Experinent on the Superoxide Anion Radical Production by Metallof lavoproteins," Eiochem. E iophys. Res. Comoiun, 41, 177 (1970).

70 flES/ \AN Wesselingh, J. >. . , and Van' t Hoop, A . C. , "Oxidation of Aqueous

Sulphite Solutions; A Model Reaction for Measurements in Gas - Liquid Dispersions," Trans, Inst, Chem. En^, 48, 169 (1970).

70 YAN "Vang, S. F . , "Sulfoxide Formation from Methionine or its Sulfide

Analogs during Aerobic Oxidation of Sulfite." Biochemistry 9,

5 CC 8 ( 1970 ) .

1971

71 BRA/GAL Bracewel I, J « M . , and Gall , D. , "The Catalytic Oxidation of

Sulphur Dioxide in Solution at Concentrations Occuring in Fog

Droplets," Syren. Phys.-Cbem. Transform. Sulphur Coop, in Atmos.

and Fortt, of Ac i_d Smog, Pjr o c . s pp. 17-26 (Mainz, Germany, 1967)

( Pub I. 1971 ).

71 CAE Carlyle , D. 1 . , "A Kinetic Study of the Aquation of

Sulf ltoiron( III i Ion," Inorg, Chem, 10 „ 761 ( 1971 ).

71 CBE/CCE Cheng, R. T . , Corn, M . , and Frohliger, J. D. , "Contribution to

tfce Reaction Kinetics of Water Soluble Aerosols and S6-. in Air

z at FPM Concentrations," Atmos. Environ. 5, 987 (1971).

71 LAK/MEF Lancaster, J. M . * and Murray, R • S .

, "The Ferri cyanide- Sulphite

Reaction," J. Chem, Sec, A, 2755 (1971).

71 1 IK Linek , V "The Oxidation of Aqueous Sulphite Solutions,

C&em, Enj, Jci^ 26, 49 1 (1971).

7 1 L IK/T \ F Linek, V ., Tvrdlk , J. , "A Generalization of Kinetic Data on

Sulfite Oxidation Systems," giotechnolj, Ei^oen^ 13 9 353 ( 197 1 ).

71 MCK McKay, H. A. C., "The Atmospheric Oxidation of Sulphur

D ioxlde in later Droplets in Presence of Ammonia ,

Atmos. Environ. 5, 7 ( 1971).

18
71 N6F/STC Norman, B. C. C . , Storey, P. M . , "Electron Spin Besonance

Studies. Part XXXI. Tttie Generation, and Some Reactions of the

Radicals SO3" -2 C 3 and SH. in Aqueous Solution,'

J- Chen. Soc. B, 1009 ( 1971 ).

71 TSt Tsunogai, S . , "Oxidation Bate of Sulfite in Water and its

Bearing on the Origin of Sulfate in Meteoric Precipitation,"

Gjochem^ J A 5, 175 (157 1).

71 VAI/\AI Valentine, J • , Valentine, D. , Jr., and (Tollman, J. P., "The

Formation of Chelated Sulfate by Reactions between Sulfur Dioxide

and Oxygen in the Coordination Sphere of Iridium and Euthenium

Complexes," Irjorj^ Cfcem^ J.©, 2 19 ( 1971 )

.

71 ZAG/SEE Zagorski, Z. P., Sehested, K . , and Nielsen, S. 0., " Pulse

Radiolysis of Aqueous Alkaline Sulfite Solutions,"

J , Phys. Cheat. 75, 3510 ( 1971).

1572

72 CAB Carlyle, D • W . , "Electron Transfer Between Sulfur( IV ) and

Trls( 1 , 10-phenanthrclire ) Ir on{ III) Ion in Aqueous Solution,"

J. Am. *mm**9* m^** Chens. m*r& Soc-w<& mobs 94,* 4525 ( 1972).

72 CHE/BAB Chen, T. I», and Barron, C. H. , "Sone Aspects of the Homogeneous

Kinetics of Sulfite Oxidation, " Ind. Eng. Chen, Functan. 11, 4

( 1972).

72 HA VISE

72 MIL/DEE

7 2 OND/TAX

Hayon, E», Treinin , A., and Wi I f , J., "Electronic Spectra,

Photochemistry, and Autoxidatlon Mechanism of the SulfiteB isulf 1 te- Pyroeulfite Systems. The S< S0- S6, end se 5

" Radicals," JA A3a. £hem5> Joe,, 94, 47 ( 1972).

Miller, J. M«, dePena, R. G. , "Contribution of Scavenged

Sulfur Dioxide to the Sulfate Content of Rain Water,"

J , Geophys. Res. 77, 5905 (1972).

Onda , K . , Takeuchl, B • , Maeda, Y . , "The Absorbtion of

Oxysen into Sodium Sulphite Solutions in a Packed Column,'

SUSS* SSfiA JS.U J2, 449 (1972).

72 PEN Penkett S. A., Oxidation of Sflg and Other Atmospheric Gases by

Ozone in Aqueous Solution," Nature (^LondonJj, Ph^J* MS..ks> 24 0 . 1C5 (1972).

72 SA^ Sewlcki, J. E . , "Reaction Kinetics of the Heterogeneous Oxidation of Sodium Sulfite," Elss. Abstr. Int. B 33, 700 (1972).

19
73 ALP ALper, E "The Kinetics of flxidatlon of Sodium Sulphite

Solution," Irans. Inst. Chem. Ens. 51, 159 (1573).

73 ASA/KIS Asada, K • , and Kisc, K . , "initiation of Aerobic Oxidation of

Sulfite by Illuminated Spinach Chloroplast s , " Eurj JA Bi. oc hern.

33, 253 ( 1 973 ) .

73 BAI/BIS Bailey, P. I., and Bishop, E . , "Reaction of Sulphite Ions with

Cyanogen Chloride," J. Chem. Soc. Dalton Trans., 9 17 (1973).

73 CAR/ZEC Carlyle , D. , and Zeck , F. , Jr., "Electron Transfer between

Sulfur(IV) and He xaaquo i ron( 1 1 1 ) Ion in Aqueous Perchlorate

Solution. Kinetics and Mechanisms of Uncatalyzed and Copper(II)-

Catalyzed Reactions," Inor^ ChemA 12 . 2978 (1973).

Chawla, fl. P., Arthur, N. L., and Fessenden, R. w., "An

Electron Spin Resonance Study of the Photolysis of Aqueous

Sulfite Solutions," Ph^s^. Chen. 77, 772 ( 1973 ).

Hartley, E. M . , and Mat teson, M. J., "Catalytic e nidation Rates

of Sulfur Dioxide in Aqueous Solutions of Manganese and Ammonia at

Various Tenperatures," Am. ChemA Soc^ Annu. Meet. (^Abjjtr^ J

165. INDE1 (1973).

73 REI/BEE Reith, T., and Beek, W . J., "The Oxidation of Aqueous Sodium

Sulphite Sclutons," Chfim. |nc. Sci^. 28 , 1331 ( 1972).

73 SOW/DO Roman, R * , and Dunford, H. E • , "Studies on Horseradish Peroxidase. XII. A Kinetic Study of the Oxidation of Sulfite and

Nitrite by Compounds I and II," Can., JN Chem. 5_^, 588 ( 1973).

"*3 CHA/AR1

73 HAS/NAT

73 SAV/BAF Sawickl , J. E. , and Barron, C. H. , "6n the Kinetics of Sulfite

Oxidation in Heterogeneous Systems," Chem^ Engj, J., 5, 153

( 1973 ).

73 STE Stemmle, J. T. s "Mechanisn & Kinetics of the Oxidation of

Sulfite and Thiosulfate by Fer rate ( V I ) , " Diss,, Abstj, Jnt^ B

34, 1418 (1 973 ).

73 TSI/1RI Tsirlin, A. M. , Trushanov, v. N. , and Khodov, G. Tf ., "Use of

Cobalt Sulfate as a Catalyst of Sodium Sulfite Oxidation in

Aqueous Solutions," Aggl& Chen. USSR 46, 2307 (1973);

tr. of j Zhur . Prikl. Khlm. 46, 2167 (1973).

20
JLJ74

74 ALT/SEE Altwicker, E. R., and Sekullc, T., "inhibition of Sul fur Dioxide

during Absorption," Environ. Lett. 7, 125 (1974).

74 BRI/SPF.1 Brimblecombe , P., and Syedding, E. J., "The Reaction erder

of the Metal Ion Catalysed Oxidation of Sulphur Dioxide in

Aqueous Solution," Chemosphere 3- 29 ( 1974).

74 BRI/SPH2 Brimblecombe, P., and Spedding, D. J., "The Absorption ol Low

Concentrations of Sulphur Dioxide into Aqueous Solutions,"

Tellus 26, 272 (1974).

74 BRI/SPI3 Brimblecombe, P., end Spedding, D. J., "The Catalytic Oxidation

of Micronolar Aqueous Sulphur Dioxide- 1," Atgos^ JSXJt5Sfia 8

,

937 (1974).

74 ERI Erlksen, T. E., "pH Effects on the Pulse Radiolysis of

De oxygenated Aqueous Solutions of Sulphur Dioxide,"

J. Chem. Soc. Faraday Trans. 1 70, 208 (1974).

74 FRE Freiberg, J., "Effects of Relative Humidity and Temperature on Iron-catalyzed Oxidation of S0g in Atmospheric Aerosols,"

Environ. Scl, Techno I. 8, 731 ( 1974).

74 JAC/M0J2 Jacobson, S. E., and Wojcicki, A., "Sulphur Dioxide Insertion.

XS. The Reaction of Sulfur Dioxide with Some Alkyl Complexes of

Chromiun, Manganese, Molybdenum, Rhenium, and Ruthenium. A comparative Study of Reactivity." J. Organomet. Chen. 72, 113

( 1974).

74 M13R Murray, P.. S., "Reinvestigation of the Reaction fcetween Hexacyanoferra te( II I ) and Sulphite Xona s H Chem^ Soc^ Dalton

Transj, 2381 (1974).

74 PEN/GA* Penkett, S. A., and Garland, J. A., "6xidatlon of Sulphur Dioxide in Artificial Fogs by Ozone, " Tellus 26, 284 (1974).

74 F.0D/ZEK Rcdlonov, A, I., Zenkov, V. V., Vladimirov, A. N. , and Strekalov

skaya, L. P., "Rate Constant of Oxidation of Aqueous Sodium

Sulfite Solutions by Cxygen and Area of Phase Contact in SievePlate Columns," J. Aprl . Chem. USSR 47, 2538 (1974); tr. of:

Zhu&* SSi&i,* £iJimA 47, 2468 (1974).

74 SCO Scott, K. L., "Preparation and Characterisation of cis- and

trans-Tetra-amn:lnei:is( sulphito )cobaltate( III ) Anions and the Kinetics of Redox Decomposition In Aqueous Acid Solution,"

J. Chem. Soc. Daltcn Trans., 1486 (1974).

74 STA/CAi Stapp, E. L., and Carlyle, D. Ml., "Reduction of Bexachloroirldate(IV) Ion by Sulfur(IV) In Acidic Aqueous Solution,"

J.S£££* Che no j. JL3, 834 ( 1974 K

21
74 THA/SCC Thacker , M . A. , Scott, K. I., Simpson, M. E. , Murray, B. S . , and

Eigglnsdfij ^. C. E., "Redox Deeorap© s i t ion of tra n g-Te tra-amminea quosulphi tocobal t( III) in Aqueous Solution." J. Chens . Soc.

Dalton Trans., 647 (1974).

74 VEP/LtKl Veprek-Siska, J., and Lunak , S . , "The Sole of Copper Ions in

Copper Catalyzed Aw too a i d© t ion of Sulfite," ****** Z. Na turf orsch . B »WW M% 29, 689 (1574).

74 VEF/11K2 Veprek-Siska , J,, Lunak, S. , and El-Wakil, A., "Catalytic Effect

of Ferric lens cn the Photo ini t iated Autooxidat i on of Sulfite,"

2, Naturlorsch. B 29, £12 (1974).

74 ZEC/CAE Zeck, 6. F., and Carlyle, D . W., "Electron Transfer between

Sulfur( IV) and Chloroiron( III ) and Chlorocopper( II) Ions In

Aqueous Chloride Media. Fcrmation of a Sulfur Dioxide Conplex

with Chi cr ocoppe r( I JBSS-Ss, S£SS^. i2 , 34 ( 1974 ).

1975

75 BEI/LAM1 Beilke, S. , and Lamb, E . , "Remarks on the Rate of Formation of

Bisulfite lens in Aqueows Solution," AIChE J. 21, 402 (1975).

75 BE I/LAM 2 Beilke, S. , Iamb, E . , and Mueller, J., "«n the TJncatalyzed

6ssidaticm of Almospheric £6^ toy 6xygen in Aqueous Systems,

A toe os. Ervlton. 9, 1083 ( 1975).

75 BEN/BJS Bengtsscn, S . , and BJerle, I., "Catalytic Oxidat ion oi Sulphite

is Diluted Aoueov s Sclutens, " Chem. Ens. Sc i . 30, 1429 ( 1975).

75 DAV/CHA Davis, A. R., and Chatter Jee, R. M . , "A Vibrational- Spectroscopic Study of the Sflg - Bgd System," JA Solution, ChemA 4, 3

( 1975).

75 FRE Freiberg, J., "The Mechanism of Iron Catalyzed Oxidation of S0 2

in Oxygenated Solutions," ^tgg=A gnv^rojn.5 9, 661 (1975).

75 G6S/KA S Gost lsa-Nl helclc , P., and Kastening, B. , "ESR- Inveeti gat ions

on the Reaction Kinetics of S6 2 ~ with Organic Halides,"

Ph^g^ CI. eg^ ^FrenMui't am MaJ.nj 98, 443 ( 1975).

75 H0F/ED* Hoffmann, M. R . , and Edwards, J . 6., "Kinetics of the Oxidation

oi Sulfite by Hydrogen Peroxide in Acidic Solution,"

S&S&t J.J. 20?C (1975).

75 ISE/IN€ Ishikawa, T., and Inouye, K. , "Role of Chlorine in 0-FeflOH on Its Thermal Change and Reactivity to Sulfur Dioxide,"

Bull. Chem. Soc. Japan 48, 1580 (1975).

22
75 KAF/NCJ Kaplan, D. , McJilten, C . , and luchtel, D., "Bisulfite Induced

Lipid flxidation," Arcfcj Envj^rcrj^ Health 30, 507 ( 1575).

75 Keweki , \*. , and Broi ikowsk i , T., "flxidation of Sulfur Dioxide in

Acid Soluticns Containing Ferric Salts," ChemA Stosowj, _lf , 255

( 1975).

75 Kf«M/SMI Kcniyama, B , , Snith, J. M., "Sulfur Dioxide Gxidallon in Slurries of Activated Carbon," AIChE JA 21 . 664 (1975).

75 NIS/SEI M ishra , G . C«, and Srlvastava, R„ D . , "Kinetics of Oxidation of

Airmen i un Sulfite by Rapid-Mixing Method," Chem. En^. 3SXa

1387 ( 1 575 ) .

75 ¥€IS Boss, A. B. 9 "Selected Specific Rates of Reactions of Transients

from Water in Aqueous Solution. Bydrated Electron, Supplemental

Data," Netj, P tan Rei «_ Data Ser& Nat^ Bur. fjtandj, 43, ( 1975).

75 TRL/TSI Lrushanov, V. N., Tsirl in, A • M . , Nikitenko, A. M., and Khodov,

G. Y . , "Einetlcs of K» 2 S€ 3 6xldation in Aqueous Solution in Presence of Cobalt Ions," J. Aggl^ ChenA USSR 48, 30C (1575); tr. of

Zhur. Prlkl. Khim. 48, 297 (1975).

1976

76 BAN/FES Bansal, K. W., and Fessenden, R. W., " Pulse Radiolysls Studies

of the Oxidation of Fbenols by ' A ~ and Br," in Aqueous Solutions, Hadiat, Res. 67 1 ( 1976 ).

76 BAB/CEC Barrie, L. A., and Georgil, B. W., "An Experimental Investigation of the Absorption of Sulphur Dioxide by Water Drops containing Heavy Metal Ions," Atmos& Enviro n. 10 . 742 (1576).

7 6 FAT Fatora, D. A., "^ash Water Recycling by Catalytic Oxidation of

Thiosulfates and Sulfites," Aggl^ P hotos Enj2j, 2, 227

( 1576 ).

76 FED/SE1 Fedorova, S. K., Skiblda, I. P., and Gladkii, A. V . , "Kinetics of

the Oxidation of Acueous Magnesium Sulfite by 6xygen," Jj, AdjjI,.

Chem. USSR 49, 753 (1576); tr. of: Zhur. Prikl. Khim. 49, 716

( 1976).

76 LAS Larson, T. V., "^he Einetics of Sulfur Dioxide Oxidation by

0 xy gen and Ozone in A tn osghe rl c Hydrometeors , " Dlssj, Abstf^

Int. B 37, 1162 (1976).

76 LUN/vEFl Lunak, S., and Veprek-Sisba , J.„ "Catalytic Effect of Metal Ions

or Photochentlcal Reactions of Molecular Oxygen. III. Photochemical

Autooxidation of Sulfite Catalyzed by Manganese ( 1 1 ) Ions,"

React^ I Cat a

l

A Lett^ 5, 157 (1976).

23
76 LKN/VEF2 Lunak, S., and VeprelfSislsa, J,, "Photochemical Autooxldatlon of

Sulphite Catalyzed by Iron( I II ) Ions," Collec Czech,, Chem^

Ccromun. 41, 3495 ( 1976 ),

76 MIS/SBI Misbra, G„ C, and Srivastava, K • D . , "Homogeneous Kinetics of

Potassium Sulfite Oxidation," Cbem. gcij, 31 , 969 ( 1976),

76 PLA/BFA Plakhotnik, V. N . , and Erabkina, K . , "Kinetics and Mechanism of

Substitution Reactions of Acido-Conplexes of Sulfur Dioxide,"

K inet. Catal. ( TJSSR ) \f s 1177 ( 1976); tr . of: Ki net, Katal

.

1356 ( 1 976 ).

76 SAN/SEI Sander, S, P,, and Seinfeld, J . B« , "Chemical Kinetics of Homogeneous Atmospheric Oxidation of Sulfur Dioxide," Environ, Scl.

Technol, 10, 1114 (1976),

1977

77 ALT

77 AUB

Altwicker, E , R,, "the Sole of Inhibitors in the Einetics of

Sulphite Oxidation," Trans. Inst. Chem. Eng. 55, 281 (1977).

Aubuchon, C, S,, "The Bate of Iron Catalyzed Oxidation of Sulfur

Dioxide by exygen in Water," Diss., Abstr. Int. B 37, 5062 (1977).

77 BAR/BE I Barrie, I., Beilbe, S., and Georgii, W.. S6g Removal by Cloud

and Fog Drops as affected by Ammonia and Heavy Metals,

ERDA S£g£A Serj ±1, 15 1 (1977),

77 BEI/LAW

77 BRI/BEE

Belike, S, , Lamb, E,, and Mueller, J,, "Heterogeneous Oxidation

of S62 in Relation to Atmospheric Scavenging," EKEA Svmg^ SerA

4.1, 137 (1977).

Brisgs, J. P., Budgins, R. R., and S i I vest on , P. I., "Composition Cycling of an se^ 6xidation Reactor," Chem, MS&A 32.

1 C87 ( 1977 ).

77 D6E/RPC Dorfman, Y. A., Rogoza, Z. I., and Kashnikova, L , V,, "Reduction

of Copper(II) by Sulfur Dioxide in Presence of Chloride and

Iodide Ions," J. Acpl. Chem. USSR 50, 1639 ( 1977); tr . oft

Zhur. Prlkl, Khifir. 50, 1709 (1977).

77 EAS/B0E Easter, R. C, and Hobbs, P. V,, "Formation of Sulfates in

Clouds through the Removal of Sulfur Dioxide and Ammonia* a Numerical Study," ERE A Symp, Ser. 41, 95 (1977).

77 ERiySAl Erickson, R. E., Yates, I. M . , Clark, R. L., and McEwen, D.,

"The Reactlcn of Sulfur Dioxide with Ozone in Water and its Possible Atmospheric Significance," Atmosj, Enyjj.ron y 11 . 813 ( 1977).

77 FAB/ EO £ Farhataziz and Ross, A. B . , "Selected Specific Rates of Reactions of Transients front Water in Aqueous Solution. III. Hydrcsxyl

Badical and Perhydroxyl Radical and their Radical Ions,"

Nat. Stand. Ref. Eata Ser. Nat. Bur. Stand. 59 . ( 1977 5*

24
77 FRA/EAI

77 GII/SCT

77 HEF/GRe

77 SFZ

77 HIK/ASA

77 HIK/TBI

77 KEN/E A

1

77 KFA/Sm

Frank, S. N«, and Sard, A. J., "Heterogeneous Pho toca talyt lc

Oxidation of Cyanide and Sulfite in Aqueous Solutions at Semiconductor Pcudera," J A Fhvs Cfcemj, £1, 1484 ( 1977).

Glines, A., and Sutherland, J. W., "Oxidation of Sulfur Dioxide

in Aqueous Acidic Solutions," AmA Chemj SocA Ann u « Meet. LAS^Jj.

SS&si JLls* ENVT7S (1577).

Herce, J. L., Gros, J • E., and Bugarel, R . , "influence of Pressure on the Kinetics of SOg Oxidation over a Vanadium Catalyst,"

Chea, En&s. Sci^ 32, 729 ( 1977).

Heunisch, G. ^ . , " St o ic h lenet ry of the Reaction of Sulfites with

Hydrogen Sulfide Icn," Tnorg^ Chem. 16 . 1411 ( 1977).

Hikita, 9. , Asai, S., and TsuJ 1 , T., "Absorption of Sulfur Dioxide into Aqueous Sodium Hydroxide and Sodium Sulfite Solutions,"

AIChE J. 23, E3€ (1977).

Hine, J., and Thiaearajan, V., "Equilibria and Kates in the

Reaction of o-Methyl Malachite Green with Sulfite Ions,"

id SS3* £he3^ 42, 3978 (1977).

Kent, S. A., Katzer, J. P., and Manogue, W. H. , "infrared Spectroscopic Investigation of the Adsorption and Reactions of S6^

on CuO," Ind. Ena- Chen. Fundaor. 16, 443 ( 1977).

Kramer, J. B., and Snyder, R . , "Precipitation Scavenging of

Sulfur Oxides using Stable Sulfur Isotopes," E RDA Jy,m£. SerA

4 1 . 127 (1S77).

77 LAE/HAS Larson, T. V., and Harrison, H • , "Acidic Sulfate Aerosols:

Formation from Heterogeneous Oxidation by 0

3

in Clouds,"

£3535* Envircn^, _1_1, 113 3 ( 1977 ).

77 NET/MAI Neta, P., Madhavan, V., Zemel, B .

, and Fessenden, R. "Rate

Constants and Mechanism of Reaction of S0 A _ 4

pounds, J A Am^ ChemA Scca 99, 163 (1977).

with Aromatic Com77 NIK/AII Nikolov, T . , Allpieva, K • , Petkov, I., and Paunova, R .

, "Sulfur

Dioxide Absorption in Iron Sulfate Solution," God. Khim^

ZS^maU I3J<** Sofia 22, 225 ( 1977).

77 ROC/KIli Rochelle, G. T • , and King C. J., "The Effect of Additives on Mass Transfer in CaCO^ or CaO Slurry Scrubbing of SOg from Waste

Gases," lag* S£SS.S Fund amj, ±6, 67 ( 1977 ).

77 SAD/KT!V Sada, E. , Kumazawa, B • , Eutt, M. A., and Sumi, T., "Removal of

dilute Sulfur Dioxide by Aqueous Slurries of Magnesiun Hydroxide

Particles," Chen. Eng. Scij, 32, 972 ( 1977).

25
77 SAD/NA? Sadek, S. E . , Naiiockl, D. A., Sterbls, E. E. , and Vivian, J. E. , "Absorption with Reaction of Sulfur Dioxide and Chlorine,"

Ind. WVVV Ens. Ckem. Fundam. MDi 16- 36 ( 1977),

77 SAl/OKA Sato, T. e and Okabe, T 9 , "The Formation of Dithionate by the

Reaction of Cxygen and Sulfites in Aqueous Solution," Ni Pgon

Kaaaku. Kaishi, 1124 (1977).

77 STE/e'K Steenken , S f'Neill , F • 0. , and Schul te-Frohl i n de, D. , " Formation cf Radical Zwitterions from Me t ho xy lat ed_ E enzo ic Acids. 1 Pre Electron Ox lc at ion by Tl'

ja PlTys . Chem. 81, 26 (197^).

2* and Sfl 4 -,

77 THO Thorn, G. C . , "The Characterization of the Metal Sulfice Sulfur

Dioxide Reaction in Aqueous Media," Diss. Abs t r Int . B 3_8 s 1239 ( 1977 ).

77 YAS1 "Yasunishl , A., "Reaction Kinetics of Oxidation of Sodium Sulfite

in Aqueous Solution by Rapid-Mixing Flow Method," Mem. F a c. EnjAJ> Kyoto Univ. 39, 122 ( 1977 ).

77 YAS2 Yasunishi, A., "Soire Aspects on Sodium Sulfite Oxidation in

Aqueous Solution," Mem., FacA En^&4> K^oto Uniy^. 39, 13 4 ( 1977).

77 YAS3 Tfasunishi, A . , "Reaction Kinetics of Sodium Sulfite Oxidation

Catalyzed by Cupric Ion," Kajzaku Kogaku R ombun s h u 3 t 62 (1977).

77 YA1/EFA1 "Yatsimirskii, K . I. , Eratushko , Y. I., and Zatsny, I. L. , "Homogeneous Catalysis by Cobalt(II) L-Hlst idinat e of the

Oxidation of Sulfite end Man eanese ( 1 1 ) Histidinate by Molecular

Gxygen in Aqueous Solution," Dokl^ CheanA 232 .38 ( 1977 ); tr. of:

Dcki^ Akad^ Nauk SSSR 232, 346 (1977).

77 YAT/EKA2 T at s i mi r sk 1 i , K. £ • , Eratushko, Y. I., and Zatsny, I. L.

,

"Kinetics and Mechanism of the Reduction of Molecular Oxygen,

Coordinated in the Complex Co_ ( L-Histidi ne ) 4 ^

2

» by Sodium

Sulphite in Aqueous Solution, RussA JA Jnorjj, Cfcen^, 22 , 875

(1977); tr. of* Zhur. Veers. Khim. 22, 1611 (1977).

1978

78 BAR/ANG Barreteau, E. , and Aneelino, H. , "Elimination of Sulfur Dioxide

fcy Reaction with Cupric Oxide in a Fluldized Bed,"

Can. jr. Chen. Eng^ 56, 57C ( 1978).

78 BAE/CeK Barbaray, E., Contour, J.P., and Mouvler, G., "Effects cf Nitrogen

Dioxide and Viater Va y or on Oxidation of Sulfur Dioxide over v

2 ^5

Particles," Environ^ Sclj Technol^ J_2, 1294 ( 1978 ).

26
78 BEI/GRA Belike, S. , and Gravenhoret, G., Heterogenous Se

2 »6x idation

in the Droplet Phase," Atmos. Environ, 12, 231 (1578).

78 Bflt/MAE Boulaud, D., Madeleine, G., Perrln, N* L., "Study of Aerosol

Evcluticr f ten Photooxldation of Sulfur Dioxide," Stud^ En v i ron^

Scl. 1 , 225 ( 1578 ).

78 CAI/CAF Cains, P. W., and Carabine, M. £ . , "6xidation of Sulphur Dioxide

in Aerosol Droplets, Catalysed by Manganous Sulphate," JA

ChemA

Sec- Faraday Trans. 1 74, 2689 (1978).

78 D6F/FeG Dorfman, Y. A., Rogoza, Z. I., and Eashnikova, L. \. , "Reduction

of CopperCII) by Sulfur Dioxide in Presence of Brcnlde and Iodide

lens," Af Chern^ PSSg 51 . 1388 ( 1978); tr. of: ZhUTj,

PrTklA Khlg. 51 . 1457 (1978).

78 DRA/DBA Draganlc, I. G., Dragenic, Z. £., and Sehested, K . , "A Pulse

Eadiclyeis Study of Aqueous Cyanamide Solutions," Phys^ Chemj

82, 757 (1978 ).

78 EAT/MA J Eatough, D. J., Major, T. , Ryder, J., Hill, M • , Mangelson, N. F.,

Eatough, N. L., Hansen, L , D • , Meisenheimer , R. G«, and Fischer,

J. W., "The Fornation and Stability of Sulfite Species in

Aerosols," Atmcj^ Enjlron. \Z 9 263 (1978).

78 EIE/STI Eifcenberger, H., Steenken, S., O'Neill, P., and Schulte-Frohllnde,

D., "Pulse Sadiolysis and Electron Spin Resonance Studies Concerning the Reaction of S€ with Alcohols and Ethers in Aqueous

78 FUZ

Solution, J. Phjs. Chem. 82, 749 (1978).

Fuzzi, S., "Study of Iron(III) Catalysed Sulphur Dioxide Oxidation in Aqueous Solution over a wide range of pH," AtnosA

Environ. 12, 1439 (1978).

78 GLA/FF.E Gladkil, A. "V., Fedorova, S. K • , and Sklbida, I. P., "Oxidation of

Aamonium Sulphite and Hydrogen Sulphite in Solution," Russ . Jj^

Inorg^ Chens 23, 918 ( 1978); tr. of: Zhurj, Neorg. Ujin^ 23, 1665

t 1578).

78 GOT/SMI Goto, S., and Smith, J. M . , "Performance of Slurry and TrickleBed Reactors: Application to Sulfur Dioxide Removal,"

AIChE J. 24, 286 (ic.78).

78 HAt'/JOl Haury, G., Jordan, S., and Hofmann, C. Experimental Investigation of the Ae roscl-Catalyzed Gxidation of S0 2 under Atmospheric

Conditions," Atmos. Environ. 12, 281 (1978).

78 HEG/BOI Hegg, D. A., and Bobbs, P. V., "Oxidation of Sulfur Dioxide in

Aqueous Systems vlth Particular Reference to the Atmosphere,"

Atmos. Environ, 12, 24 1 (1578).

76 HIF/ASA Hikita, B • , Asal, S., and Nose, H., "Absorption of Sulfur

Dioxide intc Water," AIChE J. 24, 147 (1978).

27
78 H01/CO Holt, B • D., Cunningham, P. T. , and Engelkemelr, A . G., "Application of 6 >y ge n - 1 8 Analysis to the Study of Atmospheric Sulfate

Formation," NA

Z. LeS . Sci. Ind. Res. Bull,. 220, 105 (1978 ).

78 IDE/EA* Idemura, H . , Kanai, T., and Yanagioka, H • , "Jet Bubbling Flue

Gas Desulf ur izat ion , " Chcg. _En^Jl Prog. a 46 ( 1978).

78 IN0/IKE I rouye , E.» Ikeda, M. , Ishida, T., 6gata, M., Akiyama, J., and

Utsuml, 1., "Participation of Superoxide Free Padical and Mn

in Sulfite Oxidation," Toxicol . AgglA Pharmacol^ 46, 29 (1978).

78 IT0/TEF Ho, Y. , Terada, A. , and Kawaguchi, S. , B Tri me thy I en e diamine

Complexes. VI. Kinetic and Equilibrium Studies oi 11 g and Substitu*

tion Reactions of 1he 1 rans- Aquab is( diamine )sulf i -to- end trans*

B is( diam ine )-hy dr cxosul ± itocoba lt( 1 1 1 ) Complexes," Bullj, C hem,

SccA Jajsn 51 . 2898 (1978).

78 JTJJ3/STI Judelkis, H. S., Stewart, T. B., and Wren, A. G. , "Laboratory

78 LAP/H0F

78 LEZ/LIK

Studies of Heterogeneous Reactions of S< ±2, 1633 ( 1 C78 ).

Environ^

larson, 1 . V., Ecr ike , N. R., and Harrison, H., "Cxldation of

Sulfur Dioxide by €x>gen and 6zone in Aqueous Solution: A Kinetic

Study with Significance to Atmospheric Rate Processes,"

AJmosA Environ^ 1 2 . 1597 (1978).

Lezina, G. G., Lunenck-Eurmakina, V. A., Emel'yanov, \. B. , and

Rubanik, S. K., "Reaction of Potassium Peroxodlsulpha te with

Sodium Sulphite and the Thermal Decomposition of Potassium Peroxo>

disulphate in Aqueous Solution," Russ^ JA

Inorg. Chen. 23, 457

( 1978 ); 1r. of: Zhur4 Neorg^ Khina^ 23, 826 ( 1978).

78 LCN/ELV Lunak, S., El-Wahll, A. M.„ and Ve prek-Si ska , J., "Au too xidat ion

of Sulfite Catalised by 3d Transition Metals and Inhibited by

2-Propanol. Mecharisnc of Inhibited and Induced Reactions,"

C c I l_ec Czech. C h enu Cogtcun. 43, 3306 ( 1978 ).

78 MAD/LEV

78 PEN

78 RAS

Madhavan, V., levanon, B., and Ne ta , P., "Decarboxylation

b> S04 ** Radicals," B&^l&Sa. BSS* LS. 15 ( 1978).

Penkett, S «, A., "Qxidation of Sulfur Dioxide in "the Liquid Phase,

IH^SSJIi UL5,* 41 ( 197 e )

.

Rasch, R., "The Reactions Between Iron 0xide and Sulfur Dioxide," GIT Fachz. Lab. 22, 667 (1978).

78 RAY/SLI Raymond, W. J., Sliger, A. G., "Flue Gas Desulfur Izat ion. The

Kellogg/Weir Scrubbing System," Chenu EngA

P rogj, . 75 ( 1978).

78 R6C/KIK Rcchelle, G. T., and King, C. J., "Alternatives for Stack Gas

Desulfur izatlon by Throwaway Scrubbing," Chem^ En £S£M±»

65 (1978).

78 SIN/SPA Singh, D. K . , Sharma, 6 • N., and Srivastava, R. D., "Kinetics of

Oxidation of Sodlun Dlthlonite by Flow Thermal Method."

AIChE J. 24, 232 (1978).

28
78 SUB/RAT

78 ST32/GCF

78 THC/HAT

^8 URA/NAK

76 VEE/KGE

78 YAN/70N

79 ADA

79 ALT

79 C«E

79 DAS/M 1

79 FIE/BtE

79 HEG/BfJE

Subhanl, M. S., and Kauser, Z. , "Flash Photolysis Decomposition

of Sulphate and Sulphite Anions In Aqueous Solution," Pev_j, Soum^

Chin,, 23, 1129 (197 8).

Suzuki a K. , and Gordon, G., " Sto lch 1 one t ry and Kinetics of the

Reaction Between Chlorine Dioxide and Sulfur( IV ) in Basic Solutions," Inorg^ StSSj. H» 3115 ( 1978).

Thorn, G. C., Waters, P« F., and Hadermann, A. F., "Formation and

Decomposition of Thlosulfate in the Ferrous Sulf ide-Sulf ur Dioxide

Reaction," Inor£ACfcen^ 11, 1693 (1978).

Drano, K . , and Nakanichl, Y . , "flxldatlon of Sulfite Solution by

flxygen in the Presence of Copper," N i^go n Kanaka Ka l shi, 53

( 1S78 ).

Verhoef, J • C«, Kck, W. T., and Barendrecht, E. , "Mechanism and

Reaction Rate of the Karl-Fischer Titration Reaction. Part III.

Rotating Ring-Disk Electrode Measurements - Comparison with the

Aqueous System," 3& HectroanaU Che m. 86, 407 ( 1^78 )

Yandell, J. K . , and Ton X Irs, L« A., "The Trans Effect in Cobalt

(III) Ccnplexes. Kinetics and Mechanism of Substitution of Cobalt

(III) Sulphlto Complexes," Aust. Jj, Ch em . 31 , 561 (1978).

Adamowicz, P. F . , "A Model for the Reversible Washout of Sulfur

Dioxide, Ammonia and Carbon Dioxide from a Polluted Atmosphere and

the Production of Sulfates in Raindrops," AtmosA Envj^^ron^ 13 . 1 C5 ( 1979 )

Altwicker, E. R., "fixidat ion/Inhlbi tion of Sulfite Ion in Aqueous

Solution," AIChE Sjnj, SerA 75 (188), 145 (1979).

Cox, R. A., "Photcchen ic al 6xidation of Atmospheric Sulphur

Dioxide," Ph 1 lo Trans. R, Soc. Lond on^ Serj A 290, E43 ( 1579).

Dasgupta, P. K., Mitchell, P. A., and West, P. W., "Study of

Transition Metal Ion-S( IV ) Systems," Atcos. Env r c n. 13 . 7"*5

( 1979 ).

Fieldes, R. E., Burdett, V, A., and Davidson, J. F • , "Reaction

of Sulphur Dioxide with Limestone Particles: The Influence of

Sulphur Trlexide," Jrans. Instj, ChemA Eng. 57 . 27e ( 1?79).

Hegg, D. A., and Bobbs, P. V., "The Homogeneous e jldatlon of

Sulfur Dioxide in Cloud Droplets," Atmos. E nvi ro n^ 13 , 981

( 1979 ).

29
79 HTS Huss, A., Studies of tfce Catalysis and Inhibition of the Oxidation of Aqueous Sulf ur( TV ) Solutions; Effects on Flue Gas Desulfu

rlzation Processes, " Diss. Abstr. Int. B 39, 602 1 (1979).

79 CIS/7AK Otsuka, K. , Tanaka, K., and Morlkava, K., "The Reaction between

S<9 2 and MnCg ancl "* ne Bole of the Sulfato Complex in the SO^-

Induced Isotrer ization of c ls-2 -Butene, " Bull,. Chea^ SocA J a patn 52, 2069 ( 1«79 ).

79 OVF/ANI Overton, J. B., Aneja, V. P., and Durham, J. L., "Production

of Sulfate in Rain and Raindrops in Polluted Atmospheres,"

MSZlSSSs. JL2» 355 ( 1979).

79 PEN/Jf M Penkett, S . A., Jcnes, £• M . R . , Brice, K. A., and Eggleton, E

J., "The I nrfcr tarice of Atmospheric Ozone and Hydrogen Peroxide

in Oxidising Sulphur Dioxide in Cloud and Rainwater,"

Atgcg. ijvitcnj J3, 122 (1979).

79 PEV/JCU2 Penkett, S. A., Jones, B. M. R., and Eggleton, A. E. J.,

Study of S0g Oxidation in Stored Rainwater Samples,'

AtmosA Env^ion4 12, 129 (1979).

79 R0S/NE1 Ross, A. B . , and Neta, P., "Rate Constants for Reactions of

Inorganic Radicals in Aqueous Solution," Nat. Stand. Fef. Data

Ser. Natj Bir4 S^and^, 65 (1979).

80 BFO/CB

A

80 ELD/HA

I

80 NEE/GEE

80 PE1/SEI

Brodzlnsky, S • , Chang, S. G. , Warkowitz, S. S., and Novakov, T.,

"Kinetics and Mechanism for the Catalytic Oxidation of Sulfur

Dioxide on Carbon in Aqueous Suspensions," Jj_ Ph^j^ Cfjegj, 84 . 3254 ( lego ).

Eldlk, F. V., and Harris, G. M • , "Kinetics and Mechanism of the

Formation, Ac id -Catalyzed Decomposition, and Intramolecular Redox

Reaction of f xygen-Bonded ( Sulf lto )pentaamminecobalt( III ) Ions in

Aqueous Solution," Inorj. Chern^ 19 . 880 (1980).

Neelakantan, K . , and Gehlawat, J. K., "Kinetics of Absorption

of Oxygen in Aqueous Solutions of Ammonium Sulfite,"

Ind. En*. Chen. Fundan. 19, 36 (1980).

Peterson, T. v., and Seinfeld, J. B • , "Heterogeneous Condensation and Chemical Reaction in Droplets - Application to the

Heterogeneous Atmospheric Oxidation of S0_," Adv^ Environ^ Scl A

Technolj, ±0 , 125 (I960).

30
80 WET/fl\E Weisnlcht, W. L • , Overman, J., Wang, C. C, Wang, B. J. , Erwin,

J., and Hudson, J. L . , "Calcium Sulfite Oxidation in a Slurry

Reactor," Chem. Eng., Eel. 35, 463 (1980).

81 CLA CLARKE , A. G . , "Elecfrol jte Solution Theory and the Oxidation

Rate of Sulphur Dioxide in Water," AtmosA Envi ron^ JL J5 , 1591

( 1991 ).

81 FRE/SCE Freiberg, J. E • , and Schwartz, S. E., "Oxidation of Se 2 In

Aqueous Droplets; Mass-Transport Limitation in lefcof atory Studies

and the Anblert A tnoeph ere , " AtnosA Environ. _15, 1145 (1981).

81 HOl/Ktlf Hclt, B . D . , Kumar, R., and Cunningham, P. T., "0xyger-18 Study

of the Aqueous-Phase Oxidation of Sulfur Dioxide," Atmos.

Ervlron. 15, 557 (1981).

ei KAF/FI* Kaplan, D. J., Binnelblau, D. M . , and Kanaoka, C., "Oxidation of

Sulfur Dioxide In Aqueous Airmonium Sulfate Aerosols Containing

Manganese as a Catalyst," Atmos. Environ. 15, 763 (1961).

81 MAR/DAN 1 Martin, L. £ • , Damschen, E. E. , and Judeikis, H. £., The Reactions of Nitrogen Oxides with SO^ in Aqueous Aerosols,"

Atnos. Ervi ton. 15, 191 (1981).

ei MAF/EAK2 Martin, L. E . , and Danschen, D. E., "Aqueous fxldatl on of Sulfur

Dioxide ty Hydrogen Per oxide at Tow pfl," Atmos^ Environ^ 1^5,

1615 ( 1961 ).

81 SCF/FEE Schwartz, S. E., and Freiberg, J. E., "Mass-Transport Limitation

to the Eate of Reaction of Gases in Liquid Droplets; Application

to Oxidation of Sfl_J in Aqueous * Solutions,"* Atmos. - - * — — - - - - - i Environ. imin--" — ii mi m meob 15.' 1 129 ( 1961 ).

31
NBS-T14A (rev. 2-8C) U.S. DEPT. OF COMM. BIBLIOGRAPHIC DATA

SHEET (See instructions)

1. PUBLICATION OR

REPORT NO. NBS SP 630

2. Performing Organ. Report No 3. Publication Date

March 1982

4. TITLE AND SUBTITLE

Oxidation of Sulfite Ion by Oxygen in Aqueous Solution

A Bibliography

5. AUTHOR(S)

Francis Westley

6. PERFORMING ORGANIZATION (If joint or other than NBS. see instructions) 7. Contract/Grant No. NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE 8. Type of Report & Period Covered WASHINGTON, D.C. 20234 Final

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State. ZIP)

Morgantown Energy Technology Center Office of Standard Reference Data

U.S. Department of Energy National Bureau of Standards

Morgantown WV 26505 Washington, DC 20234

10. SUPPLEMENTARY NOTES

Library of Congress Catalog Card Number: 82-600507

J Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bibliography or literature survey, mention it here)

A list of references is provided for published papers and reports containing

rate constants or mechanisms for the oxidation of S(IV) by oxygen in aqueous solution, with or without catalysts. Three hundred and twenty papers are listed, the

period covered extending from 1897 to 1981.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by semicolons)

aqueous solution; bibliography; bisulfite ion; chemical kinetics; oxidation;

oxygen; sulfite ion; sulfur dioxide.

13. AVAILABILITY

[~Xl Unlimited

r~J For Official Distribution. Do Not Release to NTIS

_] Order From Superintendent of Documents, U.S. Government Printing Office, Washington, D.C.

20402.

fj|fl Order From National Technical Information Service (NTIS), Springfield, VA. 22161

14. NO. OF

PRINTED PAGES

34

15. Price

USCOMM-DC B043-P80

<tU.S. GOVERNMENT PRINTING OFFICE: 1 9 8 2 - 3 6 0

" 9 9 7 / 2 0 7 7
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