Page 1 of 80

Subpart VVVVVV -- National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources

Table of Contents Applicability and Compliance Dates §63.11494 What are the applicability requirements and compliance dates? Standards and Compliance Requirements §63.11495 What are the management practices and other requirements? §63.11496 What are the standards and compliance requirements for process vents? §63.11497 What are the standards and compliance requirements for storage tanks? §63.11498 What are the standards and compliance requirements for wastewater systems? §63.11499 What are the standards and compliance requirements for heat exchange systems? §63.11500 Wha t compliance options do I have if part of my plant is subject to both this subpart and another Federal standard? §63.11501 What are the notification, recordkeeping, and reporting requirements , and how may I assert an affirmative defense for violation of em ission standards during malfunction ? Other Requirements and Information §63.11502 What definitions apply to this subpart? §63.11503 Who implements and enforces this subpart? Tables to Subpart VVVVVV of Part 63 Table 1 to Subpart VVVVVV of Part 63

- Hazar dous Air Pollutants Used to Determine Applicability of Chemical Manufacturing Operations Table 2 to Subpart VVVVVV of Part 63

- Emission Limits and Compliance Requirements for Batch Process Vents Table 3 to Subpart VVVVVV of Part 63

- Emission Limits and Compliance Requirements for Continuous Process Vents Table 4 to Subpart VVVVVV of Part 63

- Emission Limits and Compliance Requirements for Metal HAP Process Vents Table 5 to Subpart VVVVVV of Part 63

- Emission Limits andPage 2 of 80

Compliance Requirements for Storage T anks Table 6 to Subpart VVVVVV of Part 63

- Emission Limits and Compliance Requirements for Wastewater Systems Table 7 to subpart VVVVVV of Part 63

- Partially Soluble HAP Table 8 to Subpart VVVVVV of Part 63

- Emission Limits and Compliance Requirements for Hea t Exchange Systems Table 9 to Subpart VVVVVV of Part 63

- Applicability of General Provisions to Subpart VVVVVV Applicability and Compliance Dates § 63.11494 What are the applicability requirements and compliance

dates? (a) Except as specified in paragra ph (c) of this section, you are subject to this subpart if you own or operate a chemical manufacturing process unit (CMPU) that meets the conditions specified in paragraphs (a)(1) and (2 through (3 ) of this

section. (1) The CMPU is located at an area source of uses as feedstocks, generates as byproducts, or produces as products any

of the hazardous air pollutant s (HAP) emissions. (2) HAP listed in Table 1 to this subpart (Table 1 HAP ) ). (2) The CMPU is located at an area source of HAP emissions. (3) Table 1 HAP are present in the CMPU, as specified feedstocks, or Table 1 HAP are generated or produced in paragraph (a)(2)(i), (ii), (iii), or (iv) of this section. (i) The the CMPU uses as feedstock, any material that contains quinoline, manganese, and /or trivalen t chromium arePage 3 of 80

present in process fluid, at an individual concentration greater than 1.0 percent by weight, or any other Table 1 HAP at an

individual concentration concentrations greater than 0.1 percent by weight for carcinogens, as defined by the Occupatio nal Safety and Health Administration at 29 CFR 1910.1200(d)(4), and greater than 1.0 percent for noncarcinogens . To determine the Table 1 HAP content of feedstocks, you may rely on formulation data provided by the manufacturer or supplier, such as the Mate rial Safety Data Sheet (MSDS) for the material. If the concentration in an MSDS is presented as a range, use the upper bound of the

range. (ii) Quinoline is generated as byproduct and is present in the CMPU in any liquid stream (process or waste) at a

conc entration greater than 1.0 percent by weight. (iii) Hydrazine and/or Table 1 organic HAP other than quinoline are generated as byproduct and are present in the CMPU in any liquid stream (process or waste), continuous process vent, or batch process vent at an individual concentration greater than 0.1 percent by weight. (iv) Hydrazine or any Table 1 HAP is produced as a product

of the CMPU. (b) A CMPU includes all process vessels, equipment, and activities necessary to operate a chemical manufacturing process that produces a material or a family of materials described byPage 4 of 80

North American Industry Classification System (NAICS) code 325. A CMPU consists of one or more unit operations and any associated recovery devices. A CMPU also includes each storage tank, tran sfer operation, surge control vessel, and bottoms receiver associated with the production of such NAICS code 325

materials. (c) This subpart does not apply to the operations specified in paragraphs (c)(1) through (6) of this section. (1) Affected sources u nder the following chemical manufacturing area source categories listed pursuant to Clean Air Act (CAA) section 112(c)(3) and 112(k)(3)(B)(ii) that are subject to area source standards under this part: (i) Manufacture of Paint and Allied Products, subject to subpart CCCCCCC of this part. (ii) Mercury Emissions from Mercury Cell Chlor

- Alkali Plants, subject to subpart IIIII of this part. (iii) Polyvinyl Chloride and Copolymers Production, subject to subpart DDDDDD of this part. (iv) Acrylic and Modacrylic Fibers Production, subject to subpart LLLLLL of this part. (v) Carbon Black Production, subject to subpart MMMMMM of this part. (vi) Chemical Manufacturing Area Sources: Chromium Compounds, subject to subpart NNNNNN of this part.Page 5 of 80

(vii) Lead oxide production at Lead Acid Battery Manufacturing Facilities, subject to subpart PPPPPP of this part. (2) Production of the following chemical manufacturing

materials described in NAICS code 325: (i) Manufacture of radioactive elements or isotopes, radi um chloride, radium luminous compounds, strontium, uranium. (ii) Manufacture of photographic film, paper, and plate

where the material is coated with or contains chemicals. This subpart does apply to the manufacture of photographic chemicals. (iii) Fabrica ting operations (such as spinning or compressing a solid polymer into its end use); compounding operations (in which blending, melting, and resolidification of a solid polymer product occurs for the purpose of incorporating additives, colorants, or stabili zers); and extrusion and drawing operations (converting an already produced solid polymer into a different shape by melting or mixing the polymer and then forcing it or pulling it through an orifice to create an extruded product). An operation is subject i f it involves processing with Table 1 HAP solvent or if an intended purpose of the operation is to remove residual Table 1 HAP monomer. (iv) Manufacture of chemicals classified in NAICS code 325222, 325314, 325413, or 325998. (3) Research and development f acilities, as defined in CAAPage 6 of 80

section 112(c)(7). (4) Quality assurance/quality control laboratories. (5) Ancillary activities, as defined in §63.11502(b). (6) Metal HAP in structures or existing as articles as

defined in 40 CFR 372.3. (d) This subpart appli es to each new or existing affected source. The affected source is the facility

- wide collection of CMPUs and each heat exchange system and wastewater system associated with a CMPU that meets the criteria specified in paragraphs (a) and (b) of this section. A CMPU using only Table 1 organic HAP is required to control only total CAA section 112(b) organic HAP. A CMPU using only Table 1 metal HAP is required to control only total CAA section 112(b) metal HAP in accordance with §63.11495 and, if applicable, §63 .11496(f)

. (1) An affected source is an existing source if you

commenced construction or reconstruction of the affected source before October 6, 2008. (2) An affected source is a new source if you commenced

construction or reconstruction of the affected so urce on or after October 6, 2008. (e) A ny area source that installed a federally

- enforceable control device on an affected CMPU is required to obtain a permit under 40 CFR part 70 or 40 CFR part 71 if the control device on the affected CMPU is necessary to maintain thePage 7 of 80

source’s emissions at area source levels. For new and existing sources subject to this rule on [INSERT DATE OF PUBLICATION OF THE FINAL RULE IN FEDERAL REGISTER] and subject to title V as a result of this rule, a complete title V permit application must be submitted no later than [INSERT DATE 12 MONTHS AFTER PUBLICATION OF THE FINAL RULE IN FEDERAL REGISTER] . New and existing so urces that become subject to this rule after [INSERT DATE OF PUBLICATION OF THE FINAL RULE IN FEDERAL REGISTER] must submit a complete title V permit application no later than 12 months after becoming subject to this rule if the source is subject to title V as a result of this rule. source that was a major source and installed a control device on a CMPU after November 15, 1990, and, as a result, became an area source under 40 CFR part 63 is required to obtain a permit under 40 CFR part 70 or 40 CFR part 71. Otherwise, you are exempt from the obligation to obtain a permit under 40 CFR part 70 or 40 CFR part 71, provided you are not otherwise required by law to obtain a permit under 40 CFR 70.3(a) or 40 CFR 71.3(a). Notwithstanding the previous sentence, you mu st continue to comply with the provisions of this subpart. (f) If you own or operate an existing affected source, you must achieve compliance with the applicable provisions in this subpart no later than January 27, 2013 October 29, 2012

. (g) If you start up a new affected source on or beforePage 8 of 80

October 29, 2009, you must achieve compliance with the applicable provisions of this subpart no later than October 29,

2009. (h) If you start up a new affected source after October 29, 2009, you must achieve compliance w ith the provisions in this subpart upon startup of your affected source. Standards and Compliance Requirements §63.11495 What are the management practices and other requirements? (a) Management practices . If you have a CMPU subject to this subpart, you mus t comply with paragraphs (a)(1) through (5)

of this section. (1) Each process vessel in organic HAP service or metal HAP

service must be equipped with a cover or lid that must be

closed in place at all times when it is in organic HAP service or

metal HAP se rvice the vessel contains HAP , except for manual operations that require access, such as material addition and removal, inspection, sampling and cleaning. This requirement does not apply to process vessels containing only metal HAP that are in a liquid solu tion or other form that will not result in particulate emissions of metal HAP (e.g., metal HAP that is in ingot, paste, slurry, or moist pellet form or other form)

. (2) You must use any of the methods listed in paragraphs (a)(2)(i) through (iv) of this sec tion to control total organicPage 9 of 80

HAP emissions from transfer of liquids containing Table 1 organic HAP to tank trucks or railcars. You are not required to comply with this paragraph (a)(2) if you have notified the Administrator in your initial notification th at a material is reactive or resinous, and you will not be able to comply with any of the methods in paragraphs (a)(2)(i) through (iv) of this

section for the transfer of such material. (i) Use submerged loading or bottom loading. (ii) Route emissions to a fuel gas system or process in accordance with §63.982(d) of subpart SS. (iii) Vapor balance back to the storage tank or another storage tank connected by a common header. (iv) Vent through a closed

- vent system to a control device. (3) You must conduct inspections of process vessels and equipment for each CMPU in organic HAP service or metal HAP

service , as specified in paragraphs (a)(3)(i) through (v) of this section, at least quarterly to demonstrate compliance with paragraph (a)(1) of this section thes e requirements and to determine that the process vessels and equipment are sound and

free of leaks. Alternatively, except when the subject CMPU contains metal HAP as particulate, inspections may be conducted while the subject process vessels and equipment are in VOC service, provided that leaks can be detected when in VOC

service.Page 10 of 80

(i) Inspections must be conducted at least quarterly. (ii) For these inspections, detection methods incorporating sight, sound, or smell are acceptable. The inspection must

includ e direct and proximal (thorough) inspection of all areas of potential leak within the CMPU. Indications of a leak identified using such methods constitute method constitutes a leak unless you demonstrate that the indications of a leak are

due to a condition other than loss of HAP. Alternatively, Method 21 of 40 CFR part 60, appendix A

- 7, with a leak definition of 500 parts per million by volume (ppmv), may be used for

detection of leaks or to determine if the indications of a leak

are due to a condition othe r than loss of HAP. If indications of a leak are determined not to be HAP in one quarterly monitoring period, you must still perform the inspection and demonstration in the next quarterly monitoring period. (iii) As an alternative to conducting inspections , as specified in paragraph (a)(3)(ii) of this section, you may use Method 21 of 40 CFR part 60, appendix A

- 7, with a leak definition of 500 ppmv to detect leaks. You may also use Method 21 with a leak definition of 500 ppmv to determine if

indications of a leak identified during an inspection conducted in accordance with paragraph (a)(3)(ii) of this section are due to a condition other than loss of HAP. The procedures in this paragraph (a)(3)(iii) may not be used as an alternative to thePage 11 of 80

inspection require d by paragraph (a)(3)(ii) of this section for process vessels that contain metal HAP as particulate. (iv) Inspections must be conducted while the subject CMPU is operating. (v) No inspection is required in a calendar quarter during which the subject CMPU d oes not operate for the entire calendar quarter and is not in organic HAP service or metal HAP service. If the CMPU operates at all during a calendar quarter, an inspection is required. (4) You must repair any leak within 15 calendar days after

detection o f the leak, or document the reason for any delay of repair. For the purposes of this paragraph (a)(4), a leak will be considered “repaired” if a condition specified in paragraph (a)(4)(i), (ii), or (iii) of this section is met. (i) The visual, audible, olf actory, or other indications of a leak to the atmosphere have been eliminated, or (ii) No bubbles are observed at potential leak sites during a leak check using soap solution, or (iii) The system will hold a test pressure. (5) You must keep records of the dates and results of each inspection event, the dates of equipment repairs, and, if applicable, the reasons for any delay in repair. (b) Small heat exchange systems . For each heat exchange system subject to this subpart with a cooling water flow ratePage 12 of 80

less than 8,000 gallons per minute (gal/min) and not meeting one or more of the conditions in §63.104(a), you must comply with paragraphs (b)(1) through (3) of this section, or as an alternative, you may comply with any one of the requirements in

Item 1.a or 1. b of Table 8 to this subpart. (1) You must develop and operate in accordance with a heat exchange system inspection plan. The plan must describe the inspections to be performed that will provide evidence of hydrocarbons in the cooling water. Among other th ings, inspections may include checks for visible floating hydrocarbon on the water, hydrocarbon odor, discolored water, and/or chemical addition rates. You must conduct inspections at least once per quarter, even if the previous inspection determined

that the indications of a leak did not constitute a leak as defined by §63.104(b)(6). (2) You must perform repairs to eliminate the leak and any

indications of a leak or demonstrate that the HAP concentration in the cooling water does not constitute a leak, as defined by §63.104(b)(6), within 45 calendar days after indications of the leak are identified, or you must document the reason for any delay of repair in your next semiannual compliance report. (3) You must keep records of the dates and results of each

in spection, documentation of any demonstrations that indications of a leak do not constitute a leak, the dates of leak repairs,Page 13 of 80

and, if applicable, the reasons for any delay in repair. (c) Startup, shutdown, and malfunction

. Startup, shutdown,

and malfunction (SSM) provisions in subparts that are referenced in paragraphs (a) and (b) of this section do not apply. (d) General duty . At all times, you must operate and maintain any affected CMPU, including associated air pollution control equipment and m onitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation and maintenance procedures are being used will be

based on information available to the Admin istrator, which may include, but is not limited to, monitoring results, review of operation and maintenance procedures, review of operation and maintenance records, and inspection of the CMPU. §63.11496 What are the standards and compliance requirements

f or process vents? (a) Organic HAP Emissions from Batch Process Vents . You must comply with the requirements in paragraphs (a)(1) through (4) of this section for organic HAP emissions from your batch process vents for each CMPU using Table 1 organic HAP. If uncontrolled organic HAP emissions from all batch process vents from a CMPU subject to this subpart are equal to or greater than 10,000 pounds per year (lb/yr), you must also comply with the emission limits and other requirements in Table 2 to thisPage 14 of 80

subpar t. (1) You must determine the sum of actual organic HAP emissions from all of your batch process vents within a CMPU subject to this subpart using process knowledge, engineering assessment, or test data. Emissions for a standard batch in a process may be u sed to represent actual emissions from each batch in that process. You must maintain records of the calculations. Calculations of annual emissions are not required if you meet the emission standards for batch process vents in Table 2 to this subpart. (2) A s an alternative to calculating actual emissions for each affected CMPU at your facility, you may elect to estimate

emissions for each CMPU based on the emissions for the worst

case CMPU. The worst

- case CMPU means the CMPU at the affected

source with the h ighest organic HAP emissions per batch. The

worst

- case emissions per batch are used with the number of batches run for other affected CMPU. Process knowledge, engineering assessment, or test data may be used to identify the

worst

- case process. You must kee p records of the information and procedures used to identify the worst

- case process. (3) If your current estimate is that emissions from batch process vents from a CMPU are less than 10,000 pounds per year (lb/yr), then you must keep a record of the number of batches of each process operated per month. Also, you must reevaluate yourPage 15 of 80

total emissions from batch process vents prior to making any process changes that affect emission calculations in paragraphs (a)(1) and (2) of this section. If projected emissio ns increase to 10,000 lb/yr or more, you must be in compliance options for batch process vents in Table 2 to this subpart upon initiating operation under the new operating conditions. You must maintain records documenting the results of all updated emissio ns calculations. (4) As an alternative to determining the HAP emissions, you may elect to demonstrate that the amount of organic HAP used in the process is less than 10,000 lb/yr. You must keep monthly records of the organic HAP usage. (b) Organic HAP Emis sions from Continuous Process Vents

. You must comply with the requirements in paragraphs (b)(1) through (3) of this section for organic HAP emissions from your continuous process vents for each CMPU subject to this subpart using Table 1 organic HAP. If the total resource

- effectiveness (TRE) index value for a continuous process vent is less than or equal to 1.0, you must also comply with the emission limits and other requirements in Table 3 to this subpart. (1) You must determine the TRE index value accordin g to the procedures in §63.115(d), except as specified in paragraphs (b)(1)(i) through (iii) of this section. (i) You are not required to calculate the TRE index valuePage 16 of 80

if you control emissions in accordance with Table 3 to this subpart. (ii) Sections 63.115(d)(1)(i) and (ii) are not applicable for the purposes of this paragraph (b)(1)(ii). (iii) You may assume the TRE for a vent stream is > 1.0 if the amount of organic HAP emitted in the vent stream is less than 0.1 pound per hour. (2) If the current T RE index value is greater than 1, you must recalculate the TRE index value before you make any process or operational change that affects parameters in the calculation. If the recalculated TRE is less than or equal to 1.0, then you must comply with one of the compliance options for continuous process vents in Table 3 to this subpart before operating under the new operating conditions. You must maintain

records of all TRE calculations. (3) If a recovery device as defined in §63.11502 is used to

maintain the TRE index value at a level greater than 1.0 and less than or equal to 4.0, you must comply with §63.982(e) and the requirements specified therein. (c) Combined Streams . If you combine organic HAP emissions from batch process vents and continuous process ve nts, you must comply with the more stringent standard in Table 2 or Table 3 to this subpart that applies to any portion of the combined stream, or you must comply with Table 2 for the batch process vents andPage 17 of 80

Table 3 for the continuous process vents. The TR E index value for continuous process vents and the annual emissions from batch process vents shall be determined for the individual streams before they are combined, and prior to any control (e.g., by subtracting any emission contributions from storage tan ks, continuous process vents or batch process vents, as applicable) , in order to determine the most stringent applicable requirements. (d) Combustion of Halogenated Streams

. You must determine if an emission stream is a halogenated vent stream by

calculati ng the mass emission rate of halogen atoms in accordance with §63.115(d)(2)(v). Alternatively, you may elect to designate the emission stream as halogenated. If you use a combustion device to comply with the emission limits for organic HAP from a halogenat ed batch process vent or a halogenated continuous process vent, you must use a halogen reduction device to meet the emission limit in either paragraph (d)(1) or (d)(2) of this section and in accordance with §63.994 and the requirements referenced therein. (1) Reduce overall emissions of hydrogen halide and halogen HAP after the combustion device by greater than or equal to 95 percent, to less than or equal to 0.45 kilograms per hour (kg/hr), or to a concentration less than or equal to 20 parts per million b y volume (ppmv).Page 18 of 80

(2) Reduce the halogen atom mass emission rate before the combustion device to less than or equal to 0.45 kg/hr or to a concentration less than or equal to 20 ppmv. (e) Alternative Standard for Organic HAP . Exceptions to the requirements f or the alternative standard requirements specified in Tables 2 and 3 to this subpart and §63.2505 are specified in paragraphs (e)(1) through ( 6 5 ) of this section. (1) When §63.2505 of subpart FFFF refers to Tables 1 and 2 to subpart FFFF and §§63.2455 and 63.2460, it means Tables 2 and 3 to this subpart and §63.11496(a) and (b). (2) Sections 63.2505(a)(2) and (b)(9) do not apply. (3) When §63.2505(b) references §63.2445 it means §63.11494(f) through (h). (4) The requirements for hydrogen halide and halogen HAP apply only to hydrogen halide and halogen HAP generated in a combustion device that is used to comply with the alternative

standard. (5) When §63.1258(b)(5)(ii)(B)( 2 ) refers to a “notification of process change” report, it means the semi

- annual complia nce report required by §63.11501(d) for the purposes of this subpart. (6) CEMS requirements and data reduction requirements for CEMS specified in §63.2450(j) apply. (f) Emissions from Metal HAP Process Vents . You must complyPage 19 of 80

with the requirements in paragr aphs (f)(1) and (2) of this section for metal HAP emissions from each CMPU using Table 1

metal HAP. If the collective uncontrolled metal HAP emissions from all metal HAP process vents from a CMPU are equal to or greater than 400 lb/yr, then you must also c omply with the emission limits and other requirements in Table 4 to this subpart and in paragraph (f)(3), (4), or (5) of this section. The requirements of this paragraph (f) do not apply to metal HAP process vents from CMPU containing only metal HAP that a re in a liquid solution or other form that will not result in particulate emissions of metal HAP (e.g., metal HAP that is in ingot, paste, slurry, or moist pellet form or other form). (1) You must determine the sum of metal HAP emissions from

all metal HAP process vents within a CMPU subject to this subpart, except you are not required to determine the annual emissions if you control the metal HAP process vents within a CMPU in accordance with Table 4 to this subpart or if you determine your total metal HAP usage in the process unit is less than 400 lb/yr. To determine the mass emission rate you may use process knowledge, engineering assessment, or test data. You must keep records of the emissions calculations. (2) If your current estimate is that total unco ntrolled metal HAP emissions from a CMPU subject to this subpart are less than 400 lb/yr, then you must keep records of either the numberPage 20 of 80

of batches operated per month (batch vents) or the process operating hours (continuous vents). Also, you must reevalua te your total emissions before you make any process or operational change that affects emissions of metal HAP. If projected emissions increase to 400 lb/yr or more, then you must be in compliance with one of the options for metal HAP process vents

in Table 4 to this subpart upon initiating operation under the new operating conditions. You must keep records of all

recalculated emissions determinations. (3) If you have an existing source subject to the HAP metals emission limits specified in Table 4 to this s ubpart, you must comply with the initial compliance and monitoring requirements in paragraphs (f)(3)(i) through (iii) of this section. You must keep records of monitoring results to demonstrate continuous compliance. (i) You must prepare a monitoring plan containing the information in paragraphs (f)(3)(i)(A) through (E) of this section. The plan must be maintained on

- site and be available on request. You must operate and maintain the control device according to a site

- specific monitoring plan at all times. (A) A description of the device; (B) Results of a performance test or engineering assessment conducted in accordance with paragraph (f)(3)(ii) of this section verifying the performance of the device for reducing HAPPage 21 of 80

metals or particulate matter (PM) to the levels required by this subpart; (C) Operation and maintenance plan for the control device (including a preventative maintenance schedule consistent with the manufacturer's instructions for routine and long

- term maintenance) and continuous monitoring syst em (CMS)

. (D) A list of operating parameters that will be monitored to maintain continuous compliance with the applicable emissions limits; and (E) Operating parameter limits based on either monitoring data collected during the performance test or establis hed in the engineering assessment. (ii) You must conduct a performance test or an engineering assessment for each CMPU subject to a HAP metals emissions limit in Table 4 to this subpart and report the results in your Notification of Compliance Status (NOCS ) report . Each performance test or engineering assessment must be conducted under representative operating conditions, and sampling for each performance test must be conducted at both the inlet and outlet of the control device. Upon request, you shall make available to the Administrator such records as may be necessary to determine the conditions of performance tests. If you own or operate an existing affected source, you are not required to conduct a performance test if a prior performance test was conduct edPage 22 of 80

within the 5 years prior to the effective date using the same methods specified in paragraph (f)(3)(iii) of this section , and , either no process changes have been made since the test, or , if you can demonstrate that the results of the performance test, with or without adjustments, reliably demonstrate compliance despite process changes. For each performance test, sampling must be conducted at both the inlet and outlet of the control device, and the test must be conducted under representative process

opera ting conditions. (iii) If you elect to conduct a performance test, it must be conducted according to requirements in §63.11410(j)(1). As an alternative to conducting a performance test using Method 5 or 5D to determine the concentration of PM, you may use Method 29 in 40 CFR part 60, appendix A

- 8 to determine the concentration of HAP metals. You have demonstrated initial compliance if the overall reduction of either HAP metals or total PM is equal to or greater than 95 percent. (4) If you have a new source using a baghouse as a control device, you must install, operate, and maintain a bag leak detection system on all baghouses used to comply with the HAP metals emissions limit in Table 4 to this subpart. You must comply with the testing, monitoring, and reco rdkeeping requirements in §63.11410(g), (i), and (j)(1), except you are not required to submit the monitoring plan required byPage 23 of 80

§63.11410(g)(2) for approval. (5) If you have a new source using a control device other than a baghouse to comply with the HAP metals emission limits in Table 4 to this subpart, you must comply with the initial compliance and monitoring requirements in paragraphs (f)(3)(i) through (iii) of this section. (g) Exceptions and Alternatives to 40 CFR Part 63, Subpart

SS

. If you are comp lying with the emission limits and other requirements for continuous process vents in Table 3 to this subpart, the provisions in paragraphs (g)(1) through (7) and (9) of this section apply in addition to the provisions in 40 CFR part 63, subpart SS. If you are complying with the emission limits and other requirements for batch process vents in Table 2 to this subpart, the provisions in paragraphs (g)(1) through (8) of this section apply in addition to the provisions in subpart

SS. (1) Requirements for Perfo rmance Tests . (i) The requirements specified in §§63.2450(g)(1) through (4) apply

instead of , or in addition to , the requirements specified in 40 CFR part 63, subpart SS. (ii) Upon request, you shall make available to the Administrator, such records as may be necessary to determine the conditions of performance tests. (2) Design Evaluation

. To determine initial compliance withPage 24 of 80

a percent reduction or outlet concentration emission limit, you may elect to conduct a design evaluation as specified in §63.1257(a) (1) instead of a performance test as specified in subpart SS of this part 63. You must establish the value(s) and basis for the operating limits as part of the design evaluation. For continuous process vents, the design evaluation must be

conducted at maxi mum representative operating conditions for the process, unless the Administrator specifies or approves alternate operating conditions. For batch process vents, the design evaluation must be conducted under worst

- case conditions, as specified in §63.2460(c )(2). (3) Outlet Concentration Correction for Combustion Devices

. When §63.997(e)(2)(iii)(C) requires you to correct the measured concentration at the outlet of a combustion device to 3 percent oxygen if you add supplemental combustion air, the requirement s in either paragraph (g)(3)(i) or (g)(3)(ii) of this section apply for the purposes of this subpart. (i) You must correct the concentration in the gas stream at the outlet of the combustion device to 3 percent oxygen if you add supplemental gases, as defi ned in §63.2550, to the vent stream, or; (ii) You must correct the measured concentration for supplemental gases using Equation 1 of §63.2460; you may use process knowledge and representative operating data to determinePage 25 of 80

the fraction of the total flow due t o supplemental gas. (4) Continuous Parameter Monitoring

. The provisions in §63.2450(k)(1) through (6) apply in addition to the requirements for continuous parameter monitoring systems (CPMS) in subpart SS of this part 63, except as specified in paragraphs (g)(4)(i) and (ii) of this section. (i) You may measure pH or caustic strength of the scrubber

effluent at least once per day for any halogen scrubber within a CMPU subject to this rule. (ii) The requirements in §63.2450(k)(6) to request approval of a proc edure to monitor operating parameters does not apply for the purposes of this subpart. You must provide the required information in your NOCS report required by §63.11501(b). (5) Startup, Shutdown, Malfunction (SSM)

. Section s 63.996(c)(2)(ii) and 63.998(b)(2)(iii), (b)(6)(i)(A), (c)(1)(ii)(E) and (d)(3) do not apply for the purposes of this subpart. (6) Excused Excursions

. Excused excursions, as defined in subpart SS of this part 63, are not allowed. (7) Energetics and Organic Peroxides

. If an emi ssion stream contains energetics or organic peroxides that, for safety reasons, cannot meet an applicable emission limit specified in this subpart, then you must submit an application to the Administrator explaining why an undue safety hazard would bePage 26 of 80

crea ted if the air emission controls were installed, and you must describe the procedures that you will implement to minimize

HAP emissions from these vent streams in lieu of the emission

limitations in this section. (8) Additional Requirements for Batch Proce ss Vents . The provisions specified in §63.2460(c) apply in addition to the provisions in subpart SS of this part 63, except as specified in paragraphs (g)(8)(i) through (iii) of this section. (i) References to emission limits in Table 2 to subpart

FFFF mea n the emission limits in Table 2 to this subpart. (ii) References to MCPU mean CMPU for purposes of this subpart. (iii) Section 63.2460(c)(8) does not apply for the purposes of this subpart. (9) Parameter Monitoring Averaging Periods . Daily averages requir ed in §63.998(b)(3) apply at all times except during startup and shutdown. Separate averages shall be determined for each period of startup and period of shutdown. (h) Surge Control Vessels and Bottoms Receivers . For each surge control vessel and bottoms r eceiver that meets the applicability criteria for storage tanks specified in Table 5 to this subpart, you must meet the emission limits and control requirements specified in Table 5 to this subpart. (i) Startup, shutdown, and malfunction (SSM) . References toPage 27 of 80

SSM provisions in subparts that are referenced in paragraphs (a) through (h) of this section or Tables 2 through 5 to this subpart do not apply. §63.11497 What are the standards and compliance requirements for storage tanks? (a) You must comply with th e emission limits and other requirements in Table 5 to this subpart and in paragraph (b) of this section for organic HAP emissions from each of your storage tanks that meet the applicability criteria in Table 5 to this subpart. (b) Planned Routine Maintena nce for a Control Device

. Operate in accordance with paragraphs (b)(1) through (3) of this section for periods of planned routine maintenance of a control device for storage tanks. (1) Add no material to the storage tank during periods of planned routine m aintenance. (2) Limit periods of planned routine maintenance for each control device (or series of control devices) to no more than 240 hours per year (hr/yr), or submit an application to the Administrator requesting an extension of this time limit to a

to tal of 360 hr/yr. The application must explain why the extension is needed and it must be submitted at least 60 days

before the 240

- hour limit will be exceeded.Page 28 of 80

(3) Keep records of the day and time at which planned routine maintenance periods begin and end, and keep a record of the type of maintenance performed. (c) References to SSM provisions in subparts that are referenced in paragraphs (a) or (b) of this section or Table 5 to this subpart do not apply. (d) Combustion of Halogenated Streams

. If you us e a combustion device to comply with the emission limits for organic HAP from a halogenated vent stream from a storage tank, you must reduce emissions in accordance with §63.11496(d) and the requirements referenced therein. §63.11498 What are the standard s and compliance requirements for wastewater systems? (a) You must comply with the requirements in paragraph (a)(1) and (2) of this section and in Table 6, Item 1 to this subpart for all wastewater streams from a CMPU subject to this subpart. If the partia lly soluble HAP concentration in a wastewater stream is equal to or greater than 10,000 parts per million by weight (ppmw) and the wastewater stream contains a separate organic phase, then you must also comply with Table 6, Item 2 to this subpart for that wastewater stream. Partially soluble HAP are listed in Table 7 to this subpart. (1) Except as specified in paragraph (a)(2) of this section, you must determine the total concentration of partiallyPage 29 of 80

soluble HAP in each wastewater stream using process knowled ge, engineering assessment, or test data. Also, you must reevaluate the concentration of partially soluble HAP if you make any process or operational change that affects the concentration of partially soluble HAP in a wastewater stream. (2) You are not req uired to determine the partially soluble concentration in wastewater that is hard piped to a combustion unit or hazardous waste treatment unit, as specified in Table 6, Item 2.b to this subpart and you are not required to determine the partially soluble HAP concentration in wastewater that is hard piped to a storage tank from which the wastewater is collected and shipped offsite for treatment in a combustion unit

or hazardous waste treatment unit

. (3) Separated organic material that is recycled to a

process is no longer wastewater and no longer subject to the wastewater requirements after it has been recycled. (b) The requirements in Item 2 of Table 6 to this subpart do not apply during periods of startup or shutdown. References to SSM provisions in subparts that are referenced in paragraph (a) of this section or Table 6 to this subpart do not apply. §63.11499 What are the standards and compliance requirements for heat exchange systems? (a) If the cooling water flow rate in your heat exchange system is equal to or greater than 8,000 gal/min and is notPage 30 of 80

meeting one or more of the conditions in §63.104(a), then you must comply with one of the requirements specified in Table 8 to this subpart. (b) For equipment that meets Current Good Manufacturing Practice (CGMP) requirements of 21 CFR part 211, you may use the physical integrity of the reactor as the surrogate indicator of heat exchanger system leaks when complying with Item 1.a in Table 8 to this subpart. (c) Any reference to SSM provisions in other subparts tha t are referenced in paragraphs (a) and (b) of this section or Table 8 to this subpart do not apply. §63.11500 What compliance options do I have if part of my plant is subject to both this subpart and another Federal standard? For any CMPU, heat exchange sy stem, or wastewater system subject to the provisions of both this subpart and another rule, you may elect to comply only with the more stringent provisions as specified in paragraphs (a) through (d) of this section. You must consider all provisions of the rules, including monitoring, recordkeeping, and reporting. You must identify the subject CMPU, heat exchange system, and/or wastewater system, and the provisions with which you will comply in your NOCS report required by §63.11501(b). You also must demonst rate in your NOCS report that each provision with which you will comply is at least as stringent as the otherwise applicable requirement inPage 31 of 80

this subpart VVVVVV. You are responsible for making accurate determinations concerning the more stringent standards and noncompliance with this rule is not excused if it is later determined that your determination was in error and, as a result, you are violating this subpart. Compliance with this rule is your responsibility and the NOCS report does not alter

or affect t hat responsibility. (a) Compliance with Other Subparts of this Part 63

. (1) If any part of a CMPU that is subject to the provisions of this subpart is also subject to the provisions of another subpart of 40 CFR part 63, then compliance with any of the requ irements in the other subpart of this part 63 that are at least as stringent as the corresponding requirements in this subpart VVVVVV constitutes compliance with this subpart VVVVVV. (2) After the compliance dates specified in §63.11494, at

an offsite relo ading or cleaning facility subject to §63.1253(f), as referenced from §63.2470(e) and Table 4 to subpart VVVVVV, compliance with the monitoring, recordkeeping, and reporting provisions of any other subpart of this part 63 constitutes compliance with the mo nitoring, recordkeeping, and reporting provisions of §63.1253(f)(7)(ii) or (iii). You must identify in your notification of compliance status report required by §63.11501(b) the subpart of this part 63 with which the owner or operator of the offsite reload ing or cleaningPage 32 of 80

facility complies. (b) Compliance with Subparts of 40 CFR Part 60

. If any part of a CMPU that is subject to the provisions of this subpart is also subject to the provisions of subpart VV, DDD, III, NNN, RRR, or YYY in 40 CFR part 60, then c ompliance with any of the requirements in 40 CFR part 60, subpart VV, DDD, III, NNN, RRR, or YYY that are at least as stringent as the corresponding requirements in this subpart VVVVVV constitutes compliance with this subpart VVVVVV. (c) Compliance with Su bparts of 40 CFR Part 61 . If any part of a CMPU that is subject to the provisions of this subpart is also subject to the provisions of subpart V, Y, BB, or FF of 40 CFR part 61, then compliance with any of the requirements in 40 CFR part 61, subpart V, Y, BB, or FF that are at least as stringent as the corresponding requirements in this subpart VVVVVV constitutes compliance with this subpart VVVVVV. (d) Compliance with 40 CFR Parts 260 through 272

. If any part of a CMPU that is subject to the provisions of this subpart is also subject to the provisions of 40 CFR parts 260 through 272, then compliance with any of the requirements in 40 CFR part 260 through 272 rule that are at least as stringent as the corresponding requirements in this subpart VVVVVV constit utes compliance with this subpart VVVVVV. §63.11501 What are the notification, recordkeeping, andPage 33 of 80

reporting requirements , and how may I assert an affirmative defense for violation of emission standards during malfunction ? (a) General Provisions . You must meet the requirements of the General Provisions in 40 CFR part 63, subpart A, as shown in Table 9 to this subpart. The General Provisions in other parts do not apply except when a requirement in an overlapping standard, which you determined is a t least as stringent as subpart VVVVVV and with which you have opted to comply, requires compliance with general provisions in another part. (b) Notification of Compliance Status (NOCS) . Your NOCS required by §63.9(h) must include the following additional information as applicable: (1) This certification of compliance, signed by a responsible official: (i) “This facility complies with the management practices in §63.11495.” (ii) “This facility complies with the requirements in §63.11496 for HAP emissions fr om process vents.” (iii) “This facility complies with the requirements in §63.11496 and §63.11497 for surge control vessels, bottoms receivers, and storage tanks.” (iv) “This facility complies with the requirements in §63.11498 to treat wastewater streams.” (v) “This facility complies with the requirements inPage 34 of 80

§63.11499 for heat exchange systems.” (2) If you comply with the alternative standard as specified in Table 2 to this subpart or Table 3 to this subpart, include the information specified in §6 3.1258(b)(5), as applicable. (3) If you establish an operating limit for a parameter that will not be monitored continuously in accordance with §§63.11496(g)(4) and 63.2450(k)(6), provide the information as specified in §§63.11496(g)(4) and 63.2450(k)(6). (4) A list of all transferred liquids that are reactive or resinous materials, as defined in §63.11502(b). (5) If you comply with provisions in an overlapping rule in accordance with §63.11500, identify the affected CMPU, heat exchange system, and/or waste water system; provide a list of the specific provisions with which you will comply; and demonstrate that the provisions with which you will comply are at least as stringent as the otherwise applicable requirements, including monitoring, recordkeeping, and reporting requirements, in this subpart VVVVVV. (c) Recordkeeping . You must maintain files of all information required by this subpart for at least 5 years following the date of each occurrence according to the requirements in §63.10(b)(1). If you are subj ect, you must comply with the recordkeeping and reporting requirements ofPage 35 of 80

§63.10(b)(2) (iii) and (vi) through (xiv), and the applicable requirements specified in paragraphs (c)(1) through ( 8 7 ) of this

section. (1) For each CMPU subject to this subpart , you must keep the records specified in paragraphs (c)(1)(i) through ( viii vi )

of this section , as applicable

. (i) Records of management practice inspections, repairs, and reasons for any delay of repair, as specified in §63.11495(a)(5). (ii) Records of small he at exchange system inspections,

demonstrations of indications of leaks that do not constitute leaks, repairs, and reasons for any delay in repair as specified in §63.11495(b). (iii) If batch process vent emissions are less than 10,000 lb/yr for a CMPU, rec ords of batch process vent emission calculations, as specified in §63.11496(a)(1), the number of batches operated each month, as specified in §63.11496(a)(3), and any updated emissions calculations, as specified in §63.11496(a)(3). Alternatively, keep reco rds of the worst

- case processes or organic HAP usage, as specified in §63.11496(a)(2) and (4), respectively. (iv) Records of all TRE calculations for continuous process vents as specified in §63.11496(b)(2). (v) Records of metal HAP emission calculations a s specifiedPage 36 of 80

in §63.11496(f)(1) and (2). If total uncontrolled metal HAP process vent emissions from a CMPU subject to this subpart are estimated to be less than 400 lb/yr, also keep records of either the number of batches per month or operating hours, as s pecified in §63.11496(f)(2). (vi) Records identifying wastewater streams and the type of treatment they receive, as specified in Table 6 to this subpart. (vii) Records of the date, time, and duration of each malfunction of operation of process equipment, c ontrol devices, recovery devices, or continuous monitoring systems used to comply with this subpart that causes a failure to meet a

standard. The record must include a list of the affected sources or equipment, an estimate of the volume of each regulated

p ollutant emitted over the standard, and a description of the

method used to estimate the emissions. (viii) Records of actions taken during periods of

malfunction to minimize emissions in accordance with §63.11495(d), including corrective actions to restore malfunctioning process and air pollution control and monitoring equipment to its normal or usual manner of operation. (2) For batch process vents subject to Table 2 to this subpart and continuous process vents subject to Table 3 to this subpart, you must keep records specified in paragraphs (c)(2)(i) or (ii) of this section, as applicable.Page 37 of 80

(i) If you route emissions to a control device other than a flare, keep records of performance tests, if applicable, as specified in §63.998(a)(2)(ii) and (4), keep reco rds of the monitoring system and the monitored parameters, as specified in §63.998(b) and (c), and keep records of the closed

- vent system, as specified in §63.998(d)(1). If you use a recovery device to maintain the TRE above 1.0 for a continuous process ve nt, keep records of monitoring parameters during the TRE index value determination, as specified in §63.998(a)(3). (ii) If you route emissions to a flare, keep records of the flare compliance assessment, as specified in §63.998(a)(1)(i), keep records of th e pilot flame monitoring, as specified in §63.998(a)(1)(ii) and (iii), and keep records of the closed

- vent system, as specified in §63.998(d)(1). (3) For metal HAP process vents subject to Table 4 to this subpart, you must keep records specified in paragra phs (c)(3)(i) or (ii) of this section, as applicable. (i) For a new source using a control device other than a baghouse and for any existing source, maintain a monitoring plan, as specified in §63.11496(f)(3)(i), and keep records of monitoring results, as specified in §63.11496(f)(3). (ii) For a new source using a baghouse to control metal HAP emissions, keep a site

- specific monitoring plan, as specified in §§63.11496(f)(4) and 63.11410(g), and keep records of bag leakPage 38 of 80

detection systems, as specified in §§6 3.11496(f)(4) and 63.11410(g)(4). (4) For each storage tank subject to Table 5 to this subpart, you must keep records specified in paragraphs (c)(4)(i) through (vi) of this section, as applicable. (i) Keep records of the vessel dimension s , capacity, and

li quid stored, as specified in §63.1065(a). (ii) Keep records of each inspection of an internal floating roof, as specified in §63.1065(b)(1). (iii) Keep records of each seal gap measurement for external floating roofs, as specified in §63.1065(b)(2), and

ke ep records of inspections of external floating roofs, as specified in §63.1065(b)(1). (iv) If you vent emissions to a control device other than a flare, keep records of the operating plan and measured parameter values, as specified in §§63.985(c) and 63.99 8(d)(2). (v) If you vent emissions to a flare, keep records of all periods of operation during which the flare pilot flame is absent, as specified in §§63.987(c) and 63.998(a)(1), and keep

records of closed

- vent systems, as specified in §63.998(d)(1). (vi) For periods of planned routine maintenance of a control device, keep records of the day and time at which each maintenance period begins and ends, and keep records of the type of maintenance performed, as specified in §63.11497(b)(3).Page 39 of 80

(5) For each wastewa ter stream subject to Item 2 in Table 6 to this subpart, keep records of the wastewater stream identification and the disposition of the organic phase(s), as specified in Item 2 to Table 6 to this subpart. (6) For each large heat exchange system subject to Table 8 to this subpart, you must keep records of detected leaks; the date the leak was detected; if demonstrated not to be a leak, the basis for that determination; the date of efforts to repair the leak; and the date the leak is repaired, as specified i n Table 8 to this subpart. (7) You must keep a record of all transferred liquids that are reactive or resinous materials, as defined in §63.11502(b),

and not included in the NOCS. (8) For continuous process vents subject to Table 3 to this subpart, keep re cords of the occurrence and duration of each startup and shutdown of operation of process equipment, or of air pollution control and monitoring equipment. (d) Semiannual Compliance Reports . You must submit semiannual compliance reports that contain the inf ormation specified in paragraphs (d)(1) through (7) of this section, as applicable. Reports are required only for semiannual periods during which you experienced any of the events described in paragraphs (d)(1) through ( 8 7 ) of this section. (1) Deviations

. You must clearly identify any deviationPage 40 of 80

from the requirements of this subpart. (2) Delay of Repair for a Large Heat Exchange System . You must include the information specified in §63.104(f)(2) each time you invoke the delay of repair provisions for a heat exchange system with a cooling water flow rate equal to or greater than 8,000 gal/min. (3) Delay of Leak Repair . You must provide the following information for each delay of leak repair beyond 15 days for any process equipment, storage tank, surge control vessel, bottoms receiver, and each delay of leak repair beyond 45 days for any heat exchange system with a cooling water flow rate less than 8,000 gal/min: information on the date the leak was identified, the reason for the delay in repair, and the date t he leak was repaired. (4) Process Change . You must report each process change that affects a compliance determination and submit a new certification of compliance with the applicable requirements in accordance with the procedures specified in paragraph (b) of this section. (5) Data for the Alternative Standard . If you comply with the alternative standard, as specified in Table 2 to this subpart or Table 3 to this subpart, report the information required in §63.1258(b)(5). (6) Overlapping Rule Requirements

. Report any changes inPage 41 of 80

the overlapping provisions with which you comply. (7) Reactive and resinous materials . Report any transfer of liquids that are reactive or resinous materials, as defined in §63.11502(b), and not included in the NOCS. (8) Malfunctions

. If a malfunction occurred during the reporting period, the report must include the number of instances of malfunctions that caused emissions in excess of a

standard. For each malfunction that caused emissions in excess of a standard, the report must inclu de a list of the affected sources or equipment, an estimate of the volume of each regulated pollutant emitted over the standard, and a description of the method used to estimate the emissions. The report must also include a description of actions you took during a

malfunction of an affected source to minimize emissions in accordance with §63.11495(d), including actions taken to correct

a malfunction. (e) Affirmative defense for violation of emission standards during malfunction . In response to an action to enforce the standards set forth in §§63.11495 through 63.11499, you may assert an affirmative defense to a claim for civil penalties for violations of such standards that are caused by malfunction, as defined at 40 CFR 63.2. Appropriate penalties may be as sessed if you fail to meet your burden of proving all of the requirements

in the affirmative defense. The affirmative defense shall notPage 42 of 80

available for claims for injunctive relief. (1) To establish the affirmative defense in any action to

enforce such a sta ndard, you must timely meet the notification requirements in paragraph (e)(2) of this section, and must prove by a preponderance of evidence that: (i) The violation: (A) Was caused by a sudden, infrequent, and unavoidable failure of air pollution control e quipment, process equipment, or a process to operate in a normal or usual manner; and (B) Could not have been prevented through careful planning, proper design, or better operation and maintenance practices;

and (C) Did not stem from any activity or event that could have been foreseen and avoided, or planned for; and (D) Was not part of a recurring pattern indicative of inadequate design, operation, or maintenance; and (ii) Repairs were made as expeditiously as possible when a

violation occurred. Off

- shift and overtime labor were used, to the extent practicable to make these repairs; and (iii) The frequency, amount, and duration of the violation (including any bypass) were minimized to the maximum extent practicable; and (iv) If the violation resulted from a bypass of control equipment or a process, then the bypass was unavoidable toPage 43 of 80

prevent loss of life, personal injury, or severe property damage; and (v) All possible steps were taken to minimize the impact of the violation on ambient air quality, the enviro nment and human health; and (vi) All emissions monitoring and control systems were kept in operation if at all possible, consistent with safety and good air pollution control practices; and (vii) All of the actions in response to the violation were

documen ted by properly signed, contemporaneous operating logs;

and (viii) At all times, the affected CMPU was operated in a manner consistent with good practices for minimizing emissions;

and (ix) A written root cause analysis has been prepared, the purpose of which is to determine, correct, and eliminate the primary causes of the malfunction and the violation resulting from the malfunction event at issue. The analysis must also specify, using best monitoring methods and engineering judgment, the amount of any e missions that were the result of the

malfunction. (2) Report . If you seek to assert an affirmative defense, you must submit a written report to the Administrator, with all necessary supporting documentation, that you have met thePage 44 of 80

requirements set forth in paragraph (e)(1) of this section. This affirmative defense report must be included in the first periodic compliance report, deviation report, or excess emission report otherwise required after the initial occurrence of the

violation of the relevant standar d (which may be the end of any applicable averaging period). If such compliance report, deviation report, or excess emission report is due less than 45 days after the initial occurrence of the violation, the affirmative defense report may be included in th e second compliance report, deviation report, or excess emission report

due after the initial occurrence of the violation of the

relevant standard. Other Requirements and Information §63.11502 What definitions apply to this subpart? (a) The following terms used in this subpart have the meaning given them in the CAA, §63.2, subpart SS (§63.981), subpart WW (§63.1061), 40 CFR 60.111b, subpart F (§63.101), subpart G (§63.111), subpart FFFF (§63.2550), as specified after

each term: CAA (§63.2) Article (40 CFR 3 72.3) Administrator (§63.2) Batch operation (§63.2550) Boiler (§63.111)Page 45 of 80

Bottoms receiver (§63.2550)

Closed

- vent system (§63.981) Combustion device (§63.111) Commenced (§63.2) Compliance date (§63.2) Container (§63.111) Continuous monitoring system (§63.2) Continuous operation (§63.2550)

Control device (§63.111) Distillation unit (§63.111) Emission standard (§63.2) EPA (§63.2) Family of materials (§63.2550) Fill or filling (§63.111) Floating roof (§63.1061) Fuel gas system (§63.981) Halogen atoms (§63.2550) Halogenated vent stream (§63.2550) Halogens and hydrogen halides (§63.2550) Hazardous air pollutant (§63.2) Heat exchange system (§63.101) Incinerator (§63.111) Isolated intermediate (§63.2550) Maintenance wastewater (§63.2550)Page 46 of 80

Major source (§63.2)

Maximu m true vapor pressure (§63.111)

Oil

- water separator or organic

- water separator (§63.111) Operating permit (§63.101) Owner or operator (§63.2) Performance test (§63.2) Permitting authority (§63.2) Process condenser (§63.2550) Process heater (§63.111)

Proces s tank (§63.2550) Process wastewater (§63.101) Reactor (§63.111) Responsible official (§63.2) State (§63.2) Surge control vessel (§63.2550) Supplemental gases (§63.2550) Test method (§63.2) Unit operation (§63.101) (b) All other terms used in this subpart shall have the meaning given them in this section. If a term is defined in the CAA, §63.2, subpart SS (§63.981), subpart WW (§63.1061), 40 CFR 60.111b, subpart F (§63.101), subpart G (§63.111), or subpart FFFF (§63.2550), and in this section, it shall have the meaning given in this section for purposes of this subpart.Page 47 of 80

Affirmative defense means, in the context of an enforcement proceeding, a response or defense put forward by a defendant, regarding which the defendant has the burden of proof, and the merits of which are independently and objectively evaluated in a judicial or administrativ e proceeding. Ancillary activities means boilers, incinerators, and process heaters not used to comply with the emission standards in §§63.11495 through 63.11500, chillers and other refrigeration systems, and other equipment and activities that are not

dir ectly involved (i.e., they operate within a closed system and materials are not combined with process fluids) in the processing of raw materials or the manufacturing of a product or intermediates used in the production of the product. Batch process vent me ans a vent from a CMPU or vents from multiple CMPUs within a process that are manifolded together into a common header, through which a HAP

- containing gas stream is, or has the potential to be, released to the atmosphere. Batch process vents include vents from batch operations and vents with intermittent flow from continuous operations that are not combined with any stream that originated as a continuous gas stream from the same continuous process. Examples of batch process vents include, but are not limite d to, vents on condensers used for product recovery, reactors, filters, centrifuges, and process tanks. The following are not batchPage 48 of 80

process vents for the purposes of this subpart: (1) Continuous process vents; (2) Bottoms receivers; (3) Surge control vesse ls; (4) Gaseous streams routed to a fuel gas system(s); (5) A gas stream routed to other processes for reaction or other use in another process (i.e., for chemical value as a product, isolated intermediate, byproduct, or coproduct, or for heat value). (6) Vents on storage tanks or wastewater systems; (7) Drums, pails, and totes; and (8) Emission streams from emission episodes that are undiluted and uncontrolled containing less than 50 ppmv HAP are not part of any batch process vent. The HAP concentration ma y be determined using any of the following: process knowledge, an engineering assessment, or test data. Byproduct means a chemical (liquid, gas, or solid) that is produced coincidentally during the production of the product. Chemical manufacturing process means all equipment which collectively functions to produce a product or isolated intermediate. A process includes, but is not limited to any, all, or a combination of reaction, recovery, separation, purification, or other activity, operation, manufacture, or treatment which are used to produce a product or isolatedPage 49 of 80

intermediate. A process is also defined by the following: (1) All Routine cleaning operations conducted as part of batch operations are considered part of the process ; (2) Each nondedicated solve nt recovery operation is considered a single process; (3) Each nondedicated formulation operation is considered a single process; (4) Quality assurance/quality control laboratories are not considered part of any process; (5) Ancillary activities are not co nsidered a process or part of any process; and (6) The end of a process that produces a solid material is either up to and including the dryer or extruder, or for a polymer production process without a dryer or extruder, it is up to and including the die p late or solid

- state reactor, except in two cases. If the dryer, extruder, die plate, or solid

- state reactor is followed by an operation that is designed and operated to remove HAP solvent or residual monomer from the solid, then the solvent removal operati on is the last step in the process. If the dried solid is diluted or mixed with a HAP

based solvent, then the solvent removal operation is the last step in the process. Continuous process vent means a “process vent” as defined in §63.101 in subpart F of th is part, except:Page 50 of 80

(1) The reference in §63.107(e) to a chemical manufacturing process unit that meets the criteria of §63.100(b) means a CMPU that meets the criteria of §63.11494(a) and (b); (2) The reference in §63.107(h)(2) to subpart H means §63.11495(a) for the purposes of this subpart; (3) The reference in §63.107(h)(4) to §63.113 means Tables 2 and 3 to this subpart; (4) The reference in §63.107(h)(7) to §63.119 means Table 5 to this subpart, and the reference to §63.126 does not apply for the purposes of this subpart; (5) The second sentence in the definition of “process vent” in §63.101 does not apply for the purposes of this subpart; (6) The references to an “air oxidation reactor, distillation unit, or reactor” in §63.107 means any continuous operat ion for the purposes of this subpart; (7) Section §63.107(h)(8) does not apply for the purposes of this subpart; and (8) A separate determination is required for the emissions from each CMPU, even if emission streams from two or more CMPU

are combined prior to discharge to the atmosphere or to a

control device.

Co

- Product means a chemical that is produced during the production of another chemical, both for their intended production.Page 51 of 80

Deviation means any instance in which an affected source subject to thi s subpart, or an owner or operator of such a source fails to meet any requirement or obligation established by this subpart, including, but not limited to any emissions limitation or management practice; or fails to meet any term or condition that is adopt ed to implement an applicable requirement in this subpart and that is included in the operating permit for any affected source required to obtain such a permit. Engineering assessment means, but is not limited to, the following: (1) Previous test results p rovided the tests are representative of current operating practices at the process

unit. (2) Bench

- scale or pilot

- scale test data representative of the process under representative operating conditions. (3) Maximum flow rate, TOC emission rate, organic HAP emission rate, metal HAP emission rate, or net heating value limit specified or implied within a permit limit applicable to the process vent. (4) Design analysis based on accepted chemical engineering principles, measurable process parameters, or physical or chemical laws or properties. Examples of analytical methods include, but are not limited to: (i) Use of material balances based on process stoichiometryPage 52 of 80

to estimate maximum organic HAP or metal HAP concentrations; (ii) Estimation of maximum flow rate b ased on physical equipment design such as pump or blower capacities; (iii) Estimation of TOC, organic HAP, or metal HAP concentrations based on saturation conditions; or (iv) Estimation of maximum expected net heating value based

on the vent stream concent ration of each organic compound or, alternatively, as if all TOC in the vent stream were the compound with the highest heating value. (5) All data, assumptions, and procedures used in the engineering assessment shall be documented. Equipment means each pum p, compressor, agitator, pressure relief device, sampling connection system, open

- ended valve or line, valve, connector, and instrumentation system in or

associated with a CMPU. Family of materials means a grouping of materials that have

the same basic com position or the same basic end use or functionality; are produced using the same basic feedstocks, the same manufacturing equipment configuration and in the same sequence of steps; and whose production results in emissions of the same Table 1 HAP at approx imately the same rate per pound of product produced. Examples of families of materials include multiple grades of same product or different variations of a product (e.g., blue, black and red resins).Page 53 of 80

Feedstock means any raw material, reactant, solvent,

add itive, or other material introduced to a CMPU.

Hazardous waste treatment , as used in the wastewater requirements, means treatment in any of the following units: (1) A hazardous waste incinerator for which you have been issued a final permit under 40 CFR pa rt 270 and comply with the requirements of 40 CFR part 264, subpart O, for which you have certified compliance with the interim status requirements of 40 CFR part 265, subpart O, or for which you have submitted a Notification of Compliance under 40 CFR 63. 1207(j) and comply with the requirements of 40 CFR part 63, subpart EEE at all times (including times when non

- hazardous waste is being burned); (2) A process heater or boiler for which you have been issued a final permit under 40 CFR part 270 and comply w ith the requirements of 40 CFR part 266, subpart H, for which you have certified compliance with the interim status requirements of 40 CFR part 266, subpart H, or for which you have submitted a Notification of Compliance under 40 CFR 63.1207(j) and comply with the requirements of 40 CFR part 63, subpart EEE at all times (including times when non

- hazardous waste is being burned); or (3) An underground injection well for which you have been issued a final permit under 40 CFR part 270 or 40 CFR part 144Page 54 of 80

and co mply with the requirements of 40 CFR part 122.

In metal HAP service means that a process vessel or piece of equipment either contains or contacts a feedstock, byproduct, or product that contains metal HAP. A process vessel is no longer in metal HAP service after the vessel has been emptied to the extent practicable (i.e., a vessel with liquid left on process vessel walls or as bottom clingage, but not in pools, due to floor irregularity, is considered completely empty) and any cleaning has been completed.

I n organic HAP service means that a process vessel or piece of equipment either contains or contacts a feedstock, byproduct, or product that contains an organic HAP , excluding any organic HAP used in manual cleaning activities. A process vessel is no longer in organic HAP service after the vessel has been emptied to the extent practicable (i.e., a vessel with liquid left on process vessel walls or as bottom clingage, but not in pools, due to floor irregularity, is considered completely empty) and any cleanin g has been completed

. In VOC service means that a process vessel or piece of equipment either contains or contacts a fluid that contains VOC.

Metal HAP means the compounds containing metals listed as HAP in section 112(b) of the CAA. Metal HAP process vent means the point of discharge to the atmosphere (or inlet to a control device, if any) of a metalPage 55 of 80

HAP

- containing gas stream from any CMPU at an affected source containing at least 50 ppmv metal HAP. The metal HAP concentration may be determined using any o f the following: process knowledge, an engineering assessment, or test data

. Organic HAP means any organic HAP listed in section 112(b) of the CAA. For the purposes of requirements in this subpart VVVVVV, hydrazine is to be considered an organic HAP.

Proce ss vessel means each vessel, except hand

- held containers, used in the processing of raw materials to chemical products. Examples include, but are not limited to reactors, distillation units, centrifuges, mixing vessels, and process

tanks.

Point of determin ation means “point of determination” as defined in §63.111 in subpart G of this part, except: (1) The reference to Table 8 or Table 9 compounds means Table 9 (subpart G) or Table 7 (subpart VVVVVV) compounds; (2) The reference to “as determined in §63.144 of this subpart” does not apply for the purposes of this subpart; and (3) The point of determination is made at the point where the stream exits the CMPU. If a recovery device is used, the point of determination is after the last recovery device.

Product means a compound or chemical which is manufactured as the intended product of the CMPU. Products include co

products. By

- products , isolated intermediates , impurities,Page 56 of 80

wastes, and trace contaminants are not considered products.

Reactive material means energ etics, organic peroxides, and unstable chemicals such as chemicals that react violently with water and chemicals that vigorously polymerize, decompose, or

become self

- reactive under conditions of pressure or temperature. Recovery device means an individual unit of equipment capable of and normally used for the purpose of recovering organic chemicals or metal

- containing chemicals for fuel value (i.e., net positive heating value), use, reuse, or for sale for fuel value, use, or reuse. Examples of equipment th at may be recovery devices include absorbers, carbon adsorbers, condensers, oil

- water separators or organic

- water separators, or organic removal devices such as decanters, strippers, or thin

film evaporation units.

Resinous material means a viscous, high

- b oiling point material resembling pitch or tar, such as plastic resin, that sticks to or hardens in the fill pipe under normal transfer

conditions.

Shutdown , for a unit operation with a continuous process vent, means the cessation of the unit operation for any purpose. Shutdown begins with the initiation of steps as described in a written standard operating procedures (SOP) or shutdown plan to cease normal/stable operation (e.g., reducing or immediatelyPage 57 of 80

stopping feed). Startup , for a unit operation with a co ntinuous process vent, means the setting in operation of the unit for any purpose. The period of startup ends upon completion of the transient, non

- equilibrium step at the time operating conditions reach steady state for operating parameters such as temper ature, pressure, composition, feed rate, and production rate. Periods of startup described by SOP manuals at the affected source may be used to determine the period of startup. Storage tank means a tank or other vessel that is used to store liquids that co ntain organic HAP and that are part of a CMPU subject to this subpart VVVVVV. The following are not considered storage tanks for the purposes of this subpart: (1) Vessels permanently attached to motor vehicles such as trucks, railcars, barges, or ships; (2) Pressu re vessels designed to operate in excess of 204.9 kilopascals (kPa) and without emissions to the atmosphere; (3) Process tanks; (4) Tanks storing organic liquids containing HAP only as impurities; (5) Surge control vessels; (6) Bottoms receivers; and (7) Wastewater storage tanks. Transfer operations means all product loading into tankPage 58 of 80

trucks and rail cars of liquid containing organic HAP from a transfer rack. Transfer operations do not include the loading to other types of containers such as cans, drums, and totes.

Transfer rack means the system used to load organic liquids into tank trucks and railcars at a single geographic site. It includes all loading arms, pumps, meters, shutoff valves, relief valves, and other piping and equipment necessary for the transfer operation. T ransfer equipment that are physically separate (i.e., do not share common piping, valves, and other equipment) are considered to be separate transfer racks.

Uncontrolled emissions means organic HAP process vent emissions or metal HAP process vent emissions , as applicable, at the outlet of the last recovery device, if any, and prior to any control device. In the absence of both recovery devices and control devices, uncontrolled emissions are the emissions discharged to the atmosphere.

Wastewater means water that is discarded from a CMPU or control device and that contains at least 5 ppmw of any HAP listed in Table 9 to 40 CFR part 63, subpart G and has an annual average flow rate of 0.02 liters per minute. Wastewater means both process wastewater and maintena nce wastewater that is discarded from a CMPU or control device. The following are not considered wastewater for the purposes of this subpart: (1) Stormwater from segregated sewers;Page 59 of 80

(2) Water from fire

- fighting and deluge systems, including testing of such systems; (3) Spills; (4) Water from safety showers; (5) Samples of a size not greater than reasonably necessary for the method of analysis that is used; (6) Equipment leaks; (7) Wastewater drips from procedures such as disconnecting hoses after cleaning lines; and (8) Noncontact cooling water.

Wastewater stream means a single point discharge of

wastewater from a CMPU or control device.

Wastewater treatment means chemical, biological, and mechanical procedures applied to wastewater to remove or reduce

HAP or other chemical constituents. § 63.11503 Who implements and enforces this subpart? (a) This subpart can be implemented and enforced by the U.S. EPA or a delegated authority such as a State, local, or tribal agency. If the U.S. EPA Administrator has delegated authority to a State, local, or tribal agency pursuant to 40 CFR part 63, subpart E, then that Agency has the authority to implement and enforce this subpart. You should contact your U.S. EPA Regional Office to find out if this subpart is delegated to a State, local, or tribal agency within your State.Page 60 of 80

(b) In delegating implementation and enforcement authority of this subpart to a State, local, or tribal agency under 40 CFR part 63, subpart E, the approval authorities contained in paragraphs (b)(1) through (4) of this section are retai ned by the Administrator of the U.S. EPA and are not transferred to the State, local, or tribal agency. (1) Approval of an alternative non

- opacity emissions standard under §63.6(g). (2) Approval of a major change to a test method. A “major change to test m ethod” is defined in §63.90. (3) Approval of a major change to monitoring under §63.8(f). A “major change to monitoring” is defined in §63.90. (4) Approval of a major change to recordkeeping/reporting under §63.10(f). A “major change to recordkeeping/repor ting” is defined in §63.90.Page 61 of 80

Tables to Subpart VVVVVV of Part 63 Table 1 to Subpart VVVVVV of Part 63 - Hazardous Air Pollutants Used to Determine Applicability of Chemical Manufacturing Operations As required in §63.11494(a), chemical manufacturing opera tions that process, use, or produce the HAP shown in the following table are subject to subpart VVVVVV. Type of HAP Chemical name CAS No. 1. Organic compounds a. 1,3

- butadiene 106990

b. 1,3

- dichloropropene 542756 c. Acetaldehyde 75070 d. Chloroform 67663 e. Ethylene dichloride 107062 f. Hexachlorobenzene 118741 g. Methylene chloride 75092 h. Quinoline 91225 2. Metal compounds a. Arsenic compounds

b. Cadmium compounds c. Chromium compounds d. Lead compounds e. Manganese compounds f. Nickel compounds 3. Others a. Hydrazine 302012

Table 2 to Subpart VVVVVV of Part 63 — Emission Limits and Compliance Requirements for Batch Process Vents As required in §63.11496, you must comply with the requirements for batch process vents as shown in the following table.

For... You must... Except... 1. Batch process vents in a CMPU at an existing source for which the total organic HAP emissions are equal to or greater than 10,000 lb/yr a. Reduce collective uncontrolled total organic HAP emissions from the sum of all batch process vents by ≥85 percent by weight or to ≤20 ppmv by routing emissions from a sufficient number of the batch process i. Compliance maybe based on either total organic HAP or total organic carbon (TOC); and ii. As specified in §63.11496 (g).Page 62 of 80 vents through a closed vent system to any combi nation of control devices (except a flare) in accordance with the requirements of §63.982(c) and the requirements referenced therein; or b. Route emissions from batch process vents containing at least 85 percent of the uncontrolled total organic HAP through a closed

- vent system to a flare (except that a flare may not be used to control halogenated vent streams) in accordance with the requirements of 63.982(b) and the requirements referenced therein; or i. Not applicable.

c. Comply with the alternative standard specified in §63.2505 and the requirements referenced therein; or i. As specified in §63.11496(e) of this subpart.

d. C omply with combinations of the requirements in Items a., b., and c. of this Table for different groups of batch process vents. i. The information specified above for Items a., b., and c., as applicable.

2. Batch process vents in a CMPU at a new source for which the total organic HAP emissions are equal to or greater than 10,000 lb/yr a. Comply with any of the emission limits in Items 1.a through 1.d of this Table, except 90

- percent reduction applies instead of 85 percent reduction in Item 1.a, and 90 perce nt of the emissions must be i. The information specified above for Items 1.a., 1.b., 1.c. and 1.d, as applicable.Page 63 of 80 routed to a flare instead of 85 percent in Item 1.b. 3. Halogenated batch process vent stream at a new or existing source that is controlled through combustion a. Comply with the requirements for halogen scrubbers in §63.11496(d).

Table 3 to Subpart VVVVVV of Part 63 — Emission Limits and Compliance Re quirements for Continuous Process Vents As required in §63.11496, you must comply with the requirements for continuous process vents as shown in the following table.

For... You must... Except... 1. Each continuous process vent with a TRE ≤1.0 a. Reduce emissions of total organic HAP by ≥95 percent by weight (≥85 percent by weight for periods of startup or shutdown) or to ≤20 ppmv by routing emissions through a closed vent system to any combination of control devices (except a flare) in accordance with th e requirements of §63.982(c )(2 ) and the requirements referenced therein; or i. Compliance may be based on either total organic HAP or TOC; and ii. As specified in §63.11496(g).

b. Reduce emissions of total organic by HAP by routing all emissions through a closed

- vent system to a flare (except that a flare may not be used to control halogenated i. Not applicable.Page 64 of 80 vent streams) in accordance with the requirements of §63.982(b) and the requirements re ferenced therein, or c. Comply with the alternative standard specified in §63.2505 and the requirements referenced therein. i. As specified in §63.11496(e).

2. Halogenated vent stream that is controlled through combustion a. Comply with the requirements for halogen scrubbers in §63.11496(d).

3. Each continuous process vent with a TRE >1.0 but ≤4.0 a. Comply with the requirements of §63.982(e) and the requirements specified therein if a recovery device, as defined in §63.11502, is used to maintain a TRE >1.0 but ≤4.0.

Table 4 to Subpart VVVVVV of Part 63 — Emission Limits and Compliance Requirements for Metal HAP Process Vents As required in §63.11496(f), you must comply with the requirements for metal HAP process vents as shown in the following table.

For... You must... Except... Each CMPU with total metal HAP emissions ≥400 lb/yr Reduce collective

uncontrolled emissions of total metal HAP emissions by ≥95 percent by weight by routing emissions from a sufficient number of the metal process vents through a closed

- vent system to any combination of control devices, according to the Not Applicable.Page 65 of 80 req uirements of §63.11496(f)(3), (4), or (5).

Table 5 to Subpart VVVVVV of part 63 — Emission Limits and Compliance Requirements for Storage Tanks As required in §63.11497, you must comply with the requirements for storage tanks as shown in the following table.

For each... You must... Except... 1. Storage tank with a design capacity ≥40,000 gallons, storing liquid that contains organic HAP listed in Table 1 to this subpart, and for which the maximum true vapor pressure (MTVP) of total organic HAP at the storage temperature is ≥5.2 kPa and <76.6 k Pa. a. Comply with the

requirements of subpart WW of this part; i. All required seals must be installed by the compliance date in §63.11494.

b. Reduce total organic HAP emissions by ≥95 percent by weight by operating and maintaining a closed

- vent system and control device (other than a flare) in accordance with §63.982(c )(1 ); or i. Compliance may be based on either total organic HAP or TOC; ii. Comply with the management practice inspection requirements in §63.11495 for the closed

- vent system; iii. When the term storage vessel is used in subpart SS of this part, the term storage tank, surge control vessel, orPage 66 of 80 bottoms receiver, as defined in §63.11502 of this subpart, applies; and iii iv . The requirements do not apply during periods of planned routine maint enance of the control device, as specified in §63.11497(b). c. Reduce total HAP emissions by operating and maintaining a closed

- vent system and a flare in accordance with §63.982(b); or i. The requirements do not apply during periods of planned routine m aintenance of the flare, as specified in §63.11497(b); and ii. When the term storage vessel is used in subpart SS of this part, it means storage tank, surge control vessel, or bottoms receiver, as defined in §63.11502 of this subpart. d. Vapor balance in accordance with §63.2470(e); or i. To comply with §63.1253(f)(6)(i), the owner or operator of an offsite cleaning or reloading facility must comply with §63.11494 and §63.11502 instead of complying with §63.1253(f)(7)(ii), except as specified in item 1.d. ii and 1.2.iii of this table Not applicable

. ii. The reporting requirements in §63.11501 do not apply to the owner or operator of thePage 67 of 80 offsite cleaning or reloading facility. iii. As an alternative to complying with the monitoring, recordkeeping, and reporti ng provisions in §§63.11494 through 63.11502, the owner or operator of an offsite cleaning or reloading facility may comply as specified in §63.11500 with any other subpart of this part 63 which has monitoring, recordkeeping, and reporting provisions as sp ecified in §63.11500. e. Route emissions to a fuel gas system or process in accordance with the requirements in §63.982(d) and the requirements referenced therein. i. When the term storage vessel is used in subpart SS of this part, it means storage tank, surge control vessel, or bottoms receiver, as defined in §63.11502. 2. Storage tank with a design capacity ≥20,000 gallons and <40,000 gallons, storing liquid that contains organic HAP listed in Table 1 to this subpart, and for which the MTVP of total or ganic HAP at the storage a. Comply with one

of the options in Item 1 of this table. i. The information specified above for Items 1.a., 1.b., 1.c., 1.d, and 1.e, as applicable.Page 68 of 80

temperature is ≥27.6 kPa and <76.6 kPa. 3. Storage tank with a design capacity ≥20,000 gallons, storing liquid that contains organic HAP listed in Table 1 to this subpart, and for which the MTVP of total organic HAP at the storage temperature is ≥76.6 kPa. a. Comply with

option b, c, d, or e in Item 1 of this table. i. The informati on specified above for Items 1.b., 1.c., 1.d, and 1.e, as applicable.

4. Storage tank described by Item 1, 2, or 3 in this table and emitting a halogenated vent stream that is controlled with a combustion device. a. Reduce emissions

of hydrogen halide and halogen HAP by ≥95 percent by weight, or to ≤0.45 kg/hr, or to ≤20 ppmv by using a halogen reduction device after the combustion device according to the requirements in §63.11496(d); or b. Reduce the halogen atom mass emission rate to ≤0.45 kg/hr or to ≤20 ppmv by using a halogen reduction device before the combustion device according to the requirements in §63.11496(d).

Table 6 to Subpart VVVVVV of part 63 — Emission Limits andPage 69 of 80 Compliance Requirements for Wastewater Systems As required in §63.11498, you must comply with the requirements for wastewater systems as shown in the following table.

For each... You must... And you must... 1. Wastewater stream a. Discharge to

onsite or offsite wastewater treatment or hazardous waste treatment. i. Maintain records identifying each wastewater stream and documenting the type of treatment that it receives. Multiple wastewater streams with similar characteristics and from the same type of activity in a CMPU may be grouped together for recordkeeping purp oses. 2. Wastewater stream containing partially soluble HAP at a concentration ≥10,000 ppmw and separate organic and water phases a. Use a decanter,

steam stripper, thin film evaporator, or distillation unit to separate the water phase from the organic p hase(s); or i. For the water phase, comply with the requirements in Item 1 of this table, and ii. For the organic phase(s), recycle to a process, use as fuel, or dispose as hazardous waste either onsite or offsite, and iii. Keep records of the wastewater s treams subject to this requirement and the disposition of the organic phase(s). b. Hard pipe the entire wastewater stream to onsite treatment as a hazardous waste, or hard pipe the entire wastewater stream to i. Keep records of the wastewater streams subject to this requirement and the disposition of the wastewater streams.Page 70 of 80 a point of transfer to onsite or for offsite t reatment as a hazardous waste treatment . Table 7 to Subpart VVVVVV of Part 63 — Partially Soluble HAP As required in §63.11498(a), you must comply with emission limits for wastewater streams that contain the partially soluble HAP listed in the following table.

Partially Soluble HAP Name CAS No. 1. 1,1,1

- Trichloroethane (methyl chloroform) 71556 2. 1,1,2,2

- Tetrachloroethane 79345 3. 1,1,2

- Trichloroethane 79005 4. 1,1

- Dichloroethylene (vinylidene chloride) 75354 5. 1,2

- Dibromoethane 106934 6. 1,2

- Dichloroethane (ethylene dichloride) 107062 7. 1,2

- Dichloropropane 78875 8. 1,3

- Dichloropropene 542756 9. 2,4,5

- Trichlorophenol 95954 10. 1,4

- Dichlorobenzene 106467 11. 2

- Nitropropane 79469 12. 4

- Methyl

- 2

- pentanone (MIBK) 108101 13. Acetaldehyde 75070 14. Acrolein 107028 15. Acrylonitrile 107131 16. Allyl chloride 107051 17. Benzene 71432 18. Benzyl chloride 100447 19. Biphenyl 92524 20. Bromoform (tribromomethane) 75252 21. Bromomethane 74839 22. Butadiene 106990 23. Carbon disulfide 75150 24. Chlorobenzene 108907 25. Chloroethane (ethyl chloride) 75003 26. Chloroform 67663 27. Chloromethane 74873 28. Chloroprene 126998 29. Cumene 98828 30. Dichloroethyl ether 111444 31. Dinitrophenol 51285 32. Epichlorohydrin 106898Page 71 of 80

33. Ethyl acrylate 140885 34. Ethylbenzene 100414 35. Ethylene oxide 75218 36. Ethylidene dichloride 75343 37. Hexachlorobenzene 118741 38. Hexachlorobutadiene 87683 39. Hexachloroethane 67721 40. Methyl methacrylate 80626 41. Methyl

- t

- butyl ether 1634044 42. Methylene chloride 75092 43. N

- hexane 110543 44. N,N

- dimethylaniline 121697 45. Naphthalene 91203 46. Phosgene 75445 47. Propionaldehyde 123386 48. Propylene oxide 75569 49. Styrene 100425 50. Tetrachloroethylene (perchloroethylene) 127184 51. Tetrachloromethane (carbon tetrachloride) 56235 52. Toluene 108883 53. Trichlorobenzene (1,2,4

- ) 120821 54. Trichloroethylene 79016 55. Trimethylpentane 540841 56. Vinyl acetate 108054 57. Vinyl chloride 75014 58. Xylene (m) 108383 59. Xylene (o) 95476 60. Xylene (p) 106423

Table 8 to Subpart VVVVVV of Part 63 - Emission Limits and Compliance Requirements for Heat Exchange Systems As required in §63.11499, you must comply with the requirements for heat exchange systems as shown in the following table.

For... You must... Except... 1. Each heat exchange system with a cooling water flow rate ≥8,000 gal/min and not meeting one or a. Comply with the

monitoring requirements in §63.104(c), the leak repair requirements in §63.104(d) and (e), and the recordkeeping and i. The reference to monthly monitoring for the first 6 months in §63.104 (b)(1) and (c)(1)(iii) does not apply. Monitoring shall be no less frequent than quarterly;Page 72 of 80

more of the conditions in §63.104(a) reporting

requirements in §63.104(f); or ii. The reference in §63.104(f)(1) to record retention requirements in §63.103(c)(1) does not apply. Records must be retained as speci fied in §§63.10(b)(1) and 63.11501(c); and iii. The reference in §63.104(f)(2) to “the next semi

- annual periodic report required by §63.152(c)” means the next semi

- annual compliance report required by §63.11501(f). b. Comply with the heat exchange system requirements in §63.104(b) and the requirements referenced therein. i. Not applicable.

Table 9 to Subpart VVVVVV of Part 63 — Applicability of General Provisions to Subpart VVVVVV As required in §63.11501(a), you must comply with the requirements of the NESHAP General Provisions (40 CFR part 63, subpart A) as shown in the following table.

Citation Subject Applies to Subpart VVVVVV? Explanation

63.1(a)(1), (a)(2), (a)(3), (a)(4), (a)(6), (a)(10)

- (a)(12) (b)(1), (b)(3), (c)(1), (c)(2), (c)(5), (e) Applicability Yes

63.1(a)(5), (a)(7)

- (a)(9), (b)(2), (c)(3), (c)(4), (d) Reserved NoPage 73 of 80

63.2 Definitions Yes 63.3 Units and Abbreviations Yes

63.4 Prohibited Activities and Circumvention Yes

63.5 Preconstruction Review and Notification Requirements Yes

63.6(a), (b)(1)

- (b)(5), (b)(7), (c)(1), (c)(2), (c)(5), (e)(1)(iii), (g), (i), (j) Compliance with Standards and Maintenance Requirements Yes

63.6(b)(6), (c)(3), (c)(4), (d), (h)(3), (h)(5)(iv) Reserved No

63.6 (e)(1)(i) and (ii), (e)(3), and (f)(1) SSM Requirements No See §63.11495(d) for general duty requirement. 63.6(h)(1)

- (h)(4), (h)(5)(i)

- (h)(5)(iii), (h)(6)

- (h)(9) No Subpart VVVVVV does not include opacity or visible emissions (VE) standards or require a continuous opacity monitoring sy stem (COMS). 63.7(a)(1), (a)(3), (a)(4), (c), (e)(4), and (f)

- (h) Performance Testing Requirements Yes

63.7(a)(2), (b), (d), (e)( 2)

— (e)( 1)

– ( 3) Performance Testing Schedule, Notification of Performance Test, Performance Yes/No Requirements apply if conducting test for metal HAP control; requirements in §§63.997(c)(1),Page 74 of 80 Testing Facilities, and Conduct of Performance Tests (d), (e), and 63.999(a)(1) apply, as referenced in §63.11496(g), if conducting test for organic HAP or hydrogen halide and halogen HAP co ntrol device. 63.7(e)(1) Performance Testing No See §63.11496(f)(3) (ii) if conducting a test for metal HAP emissions. See §§63.11496(g) and 63.997(e)(1) if conducting a test for continuous process vents or for hydrogen halide and halogen emissions. See §§ 63.11496(g) and 63.2460(c) if conducting a test for batch process vents. 63.8(a)(1), (a)(4), (b), (c)(1 )(ii), (c)(2 )

- (c)(3), (f)(1)

- (5) Monitoring Requirements Yes References to SSM in §63.8(c) do not apply.

63.8(c)(1)(i) General Duty to Minimize Emissions and CMS Operation No

63.8(c)(1)(iii) Requirement to Develop SSM Plan for CMS No

63.8(a)(2) Monitoring NoPage 75 of 80 Requirements 63.8(a)(3) Reserved No 63.8(c)(4) Yes No Only for CEMS. Continuous parameter monitoring system ( CPMS ) requirements in 40 CFR part 63, subpart s SS and FFFF are referenced from §63.11496. Requirements for COMS do not apply because subpart VVVVVV does not require COMS. 63.8(c)(5) No Subpart VVVVVV does not require COMS. 63.8(c)(6)

- (c)(8), (d )(1)

- (d)(2 ), ( e), (f)(6) Yes Requirements apply only if you use a continuous emission monitoring system (CEMS) to demonstrate compliance with the alternative standard in §63.11496(e). References to SSM in §63.8(d) do not apply. 63.8(d)(3) Written Procedures for CMS Yes Requirement applies except for last sentence, which refers to an SSM plan. SSM plans are not required. 63.8(g)(1)

- (g)(4) Yes Data reduction requirementsPage 76 of 80 apply only if you use CEMS to demonstrate compliance with alternative standard in §63.11496(e). C OMS requirements do not apply. Requirement in §63.8(g)(2) does not apply because data reduction for CEMS are specified in 40 CFR part 63, subpart FFFF. 63.8(g)(5) No Data reduction requirements for CEMS are specified in §63.2450(j)(4), 40 CFR part 63, subpart FFFF, as referenced from §63.11496. CPMS requirements are specified in 40 CFR part 63, subpart s SS and FFFF , as referenced from §63.11496. 63.9(a), (b)(1), (b)(2), (b)(4), (b)(5), (c), (d), (e), (i) Notification Requirements Yes

63.9(b)(3), (h)( 4) Reserved No 63.9(f) No Subpart VVVVVV does not contain opacity or VE limits. 63.9(g) Yes AdditionalPage 77 of 80 notification requirement applies only if you use CEMS to demonstrate compliance with alternative standard in §63.11496(e). 63.9(h)(1)

- (h)(3), (h)(5)

- (h)(6) Yes Except subpart VVVVVV does not contain opacity or VE limits. 63.9(i) Yes 63.9(j) Change in Information Already Provided No Notification of process changes that affect a compliance determination are required in §63.11501(d)(4)

. 63.10(a) Recordkeeping Requirements Yes 63.10(b)(1) Yes 63.10(b)(2)(i )

- (b)(2)(v ) Recordkeeping of Occurrence and Duration of Startups and Shutdowns No Yes See §63.11501(c)(8) for recordkeeping of occurrence and duration of each startup and shutdown for continuous process vents that are subpart to Table 3 to this subpart. Any references to SSM do not apply. 63.10(b)(2)(ii) Recordkeeping of Malfunctions No See §63.11501(c)(1) (vii) and (viii) for recordkeepingPage 78 of 80 of (1) date, time, duration, and volume of exc ess emissions and (2) actions taken during malfunction. 63.10(b)(2)(iii) Maintenance Records Yes 63.10(b)(2)(iv) and (v) Actions Taken to Minimize Emissions During SSM No

63.10(b)(2)(vi), (x), (xi), (xiii) Yes Apply only if you use CEMS to demonstrate compliance with alternative standard in §63.11496(e). 63.10(b)(2)(vii)

- (b)(2)(ix), (b)(2)(xii), (b)(2)(xiv) Yes

63.10(b)(3) Yes 63.10(c)(1), (c)(5)

- (c)(6), (c)(13)

- (c)(14) Yes Apply only if you use CEMS to demonstrate compliance with alternative standard in §63.11496(e). 63.10(c)(7)

- (8) Additional Recordkeeping Requirements for CMS

– Identifying Exceedances and Excess Emissions Yes

63.10(c)( 7)

- (c)(8), (c)( 10 )

- (c)(12), (c)(15 ) Recordkeeping Nature and Cause of Malfunctions No Yes See §63.11501(c)(1) (vii) and (viii) for malfunctions recordkeepingPage 79 of 80 requirements. An y reference to SSM does not apply. 63.10(c)(11) Recording Corrective Actions No See §63.11501(c)(1) (vii) and (viii) for malfunctions recordkeeping requirements. 63.10(c)(12) Yes 63.10(c)(15) Use of SSM Plan No 63.10(c)(2)

- (c)(4), (c)(9) Reserved No 63.10(d)(1), (d)(2), (d)(4), (e)(1), (e)(2), (f) Reporting Requirements Yes

63.10(d)(3) No Subpart VVVVVV does not include opacity or VE limits. 63.10(d)(5) SSM Reports No See §63.11501(d)(8) for reporting requirements for malfunctions. 63.10(e)(1)

- (e)(2) Yes Apply only if you use CEMS to demonstrate compliance with alternative standard in §63.11496(e). 63.10(e)(3) Yes 63.10(e)(4) No Subpart VVVVVV does not include opacity or VE limits. 63.11 Control Device Requirements Yes

63.12 State Authorities and Delegations Yes

63.13 Addresses YesPage 80 of 80

63.14 Incorporations by Reference Yes

63.15 Availability of Information and Confidentiality Yes

63.16 Performance Track Provisions Yes