NSRDS-NBS 66, Part I

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Ion Energetics Measurements

Part I. 1971-1973

H. M. Rosenstock, D. Sims,

S. S. Schroyer, and W. J. Webb

Ion Energetics Data Center

National Measurement Laboratory

National Bureau of Standards

Washington, D.C. 20234

IM»m! Butew oS «n, HI *** P*

FEB 1 6 1981

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U.S. DEPARTMENT OF COMMERCE, Philip M. Klutznick, Secretary

Luther H. Hodges, Jr., Deputy Secretary

Jordan J. Baruch, Assistant Secretary for Productivity, Technology and Innovation

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director

Issued September 1980
Library of Congress Cataloging in Publication Data

Main entry under title: Ion Energetics measurements.

(Nat. stand, ref. data ser. ; NSRDS-NBS 66, pt. 1- ) "Issued February 1980.”

Bibliography: p. Includes indexes. CONTENTS: pt. 1. 1971-1973.

Supt. of Docs, no.: C 13.48:66/pt. 1

1. Ions--Tables. I. Rosenstock, Henry M. II. National Measurement

Laboratory (U.S.). Ion Energetics Data Center. III. Series: United States. National Bureau of Standards. National standard reference data series ; NSRDS-NBS 66, pt. 1 QC100.U573 no. 66, pt. 1, etc. [QD561] 602M8s

[541.372] 80-607942

NSRDS-NBS 66, Part I

Nat. Stand. Ref. Data Ser., Nat. Bur. Stand. (U.S.), 66, Part I, 379 pages (Sept. 1980)

CODEN: NSRDAP

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Foreword

The National Standard Reference Data System provides access to the quantitative data of physical science, critically evaluated and compiled for convenience and readily accessible through a variety of distribution channels. The System was established in 1963 by action of the President’s

Office of Science and Technology and the Federal Council for Science and Technology, and

responsibility to administer it was assigned to the National Bureau of Standards.

NSRDS receives advice and planning assistance from a Review Committee of the National

Research Council of the National Academy of Sciences-National Academy of Engineering. A number of Advisory Panels, each concerned with a single technical area, meet regularly to examine

major portions of the program, assign relative priorities, and identify specific key problems in need of further attention. For selected specific topics, the Advisory Panels sponsor subpanels

which make detailed studies of users’ needs, the present state of knowledge, and existing data re- sources as a basis for recommending one or more data compilation activities. This assembly of advisory services contributes greatly to the guidance of NSRDS activities. The System now includes a complex of data centers and other activities in academic insti- tutions and other laboratories. Components of the NSRDS produce compilations of critically

evaluated data, reviews of the state of quantitative knowledge in specialized areas, and computations of useful functions derived from standard reference data. The centers and projects also establish criteria for evaluation and compilation of data and recommend improvements in ex- perimental techniques. They are normally associated with research in the relevant field. The technical scope of NSRDS is indicated by the categories of projects active or being

planned: nuclear properties, atomic and molecular properties, solid state properties, thermodynamic and transport properties, chemical kinetics, and colloid and surface properties.

Reliable data on the properties of matter and materials are a major foundation of scientific and technical progress. Such important activities as basic scientific research, industrial quality control, development of new materials for building and other technologies, measuring and correcting

environmental pollution depend on quality reference data. In NSRDS, the Bureau’s responsibility

to support American science, industry, and commerce is vitally fulfilled.

Ernest Ambler, Director

III
Contents

1. Introduction

2. Acknowledgements

3. Index of Ions

4. Table of Ion Energetics Measurements

5. Bibliography

6. Author Index

Page

12

3

24

343

363

IV
Ion Energetics Measurements

Part I. 1971-1973

H. M. Rosenstock, D. Sims, S. S. Schroyer, and W. J. Webb

Ion Energetics Data Center, National Measurement Laboratory, National Bureau of Standards, Washington, D. C. 20234

The present publication tabulates measurement information on energetics of gaseous positive ions published in 1972 and 1973 along with some information from 1971. It is intended to supplement the information previously

compiled and evaluated in “Energetics of Gaseous Ions.” Approximately five thousand measurements are

tabulated, drawn from over six hundred published papers.

Key words: Appearance potential; electron impact; electron spectroscopy; gaseous ion; ionization potential; photoionization; spectroscopy.

1. Introduction

The present supplement is the first of a series intended

to update the measurement information which was pre- sented and critically evaluated in the compilation “Energetics of Gaseous Ions’ll]. 1 This supplement includes measurement information on

gaseous positive ions which was published in 1972 and

1973, together with additional information which ap- peared in 1971 but was not included in the ion energetics

compilation.

The format and the ordering of ions is similar to the

previously published compilation. The notation (V) after an ionization potential indicates a vertical ionization

potential which is higher than the adiabatic value [1,2].

The methods, along with their abbreviations, are given in table 1. The methods are discussed in detail in references

1 and 2. In addition, the abstracted measurement infor- mation is occasionally annotated with one or more com- ments which will be useful in evaluating the quality of the

information. A list of the comments is given in table 2. They should be self-explanatory, with the possible exception of the comment on metastable transitions. For complex fragmentation processes the observation of

metatstable transitions provides useful corroborative in- formation on the neutral products of the fragmentation

process. Hence where given in the publication presenting

fragment appearance potentials, this additional information has been noted in a comment. We are aware that there is much additional useful information on metastable

transitions in other publications. However, no attempt was made to incorporate this material at this stage of the

project. Evidently, it will have to be taken into account in the critical evaluations which are planned for the future.

We have inserted two asterisks in the other products

column to indicate that no fragmentation takes places.

Hence, a blank space in that column indicates a fragmentation process in which the neutral fragments are not

specified in the journal article. As before, names are given for all compounds where

chemical structure cannot be adequately represented, by a one-line semistructural formula, i.e., ring compounds. In

a departure from the previously published compilation, we have decided to adopt the systematic nomenclature

used by Chemical Abstracts Services. In some instances

this leads to extremely long and involved names. To ease

the pain, in these instances we also give a short name, if available. Unfortunately this is not so for some complex

organometallic compounds. In all cases, name or no name, we give the Chemical Abstracts Services Registry

Number to facilitate access of other data bases and to retain an identifier for the compound which is more

permanent than the name. We emphasize the interim nature of the present sup- plement. It is probable that additional measurements

published during this period will be identified. They will be given in the next supplement, along with those

measurements published in 1974 and 1975. Further, the

intent of the supplement is to present as accurately as possible the measurement information as given in the

papers themselves. This will, of course lead to occasional

inconsistencies in the tabulated information, reflecting the inconsistencies in the literature itself. They will (hopefully) be removed in the critical evaluation planned

for later. Also, the reader should be cautioned that information given in this supplement is not necessarily more accurate than that presented in the earlier compilation.

1 Figures in brackets indicate literature references.

1
Table 1. Methods for ion energetics measurements in order of sort Table 2. List of comments and coding acronyms

preference

Abbreviation Technique

S Spectroscopic

PI Photoionization TPE Threshold Photoelectron Spectroscopy PE Photoelectron Spectroscopy

AUG Auger Electron Spectroscopy

PEN Penning Ionization EM Electron Monochromator Studies RPD Retarding Potential Difference EDD Energy Distribution Difference NRE N

1*1 Root Extrapolation

SRP Square Root Plot FD First Derivative SD Second Derivative DC Deconvolution SEQ Sequential Ionization El Other Electron Impact

SI Surface Ionization CTS Charge Transfer Spectrum

BH Born-Haber Cycle

D Derived Value OTH Other

References for the Introduction

[1J Rosenstock, H. M., Draxl, K., Steiner, B. W., and Herron, J. T., “Energetics of Caseous Ions,” J. Phys. Chem. Ref. Data 6,

Supplement 1 (1977).

(2) Rosenstock, H. M., “The Measurement of Ionization and Appearance Potentials,” Int. J. Mass Spectrom. Ion Phys. 20, 139

(1976).

RN CAS Registry Number xxxxxx-xx-x RD Radical TV Threshold value approximately corrected to O K

HB Threshold value approximately corrected for hot bands

(implies vibrational hot bands) ZK Threshold value for zero kinetic energy ions (used only where threshold dependence on KE is measured)

ZT Zero average translational energy of decomposition at threshold (used where KE is shown to be approximately

0 but no threshold dependence is measured)

AD eV average translational energy of decomposition at threshold HE High kinetic energy ion CD Metastable transition indicates eV kinetic energy

release UN Metastable transitions indicate eV kinetic energy

release (applies to successive metastables) PC Appearance potential of the corresponding metastable

transition MT Metastable transition(s) observed

(used also if there is possibility of collision contribution) RS Average of Rydberg series limits (use words)

AV Average of values

(use words)

FI Fragment from electron impact induced decomposition

of PA Appearance potential of negative ion NI Negative ion detected PM Position of peak maximum

TR Other product(s) thermochemically reasonable SC Mean value of spin-orbit components JC Mean value of Jahn-Teller components

2. Acknowledgements

This project was supported by the National Institute of

General Medical Sciences, National Institutes of Health

(NIGMS) and by the Office of Standard Reference Data,

National Bureau of Standards (OSRD). We would like to thank Dr. R. S. Melville of NIGMS and Dr. D. R. Lide,

Jr. and Dr. L. H. Gevantman of OSRD for their continued

support and encouragement. We are especially grateful

for the considerable assistance given us by Mr. R. W.

Thompson and Mrs. C. Messina of OSRD in the computer

production of this publication. The participation of Mrs.

C. Schmidt in the early phases of this project is gratefully

acknowledged.

2
3 Index of Ions H+ 24 C5 H4+ D+ 24 C5 H5+ H2+ 24 C5 H+

HD+ 24 C5H7+ H3+ 24 C5H8+ Li+ 24 C5H9+

.... Li2+ 24 C5H+ B+ 24 C5H+...

BH+ 25 C5H+

BH3+ 25 C6H2+ B3H5+ 25 C6H+ B3H6+ 25 C6H5+

.... B4H8+ 25 C6H3D2+ B5H8+ 25 C6H6+

.... B5H^ 25 C6H4D+ C+ 25 C6H+.... C

+2 26 C6H8+

.... C

+3 26 C6H9+

.... C,+ 26 C6H+.... C3+ : 26 QH/j...

CH+ 26 C6H+ .... CH2+ 26 C6D,+2 • CH3+ 26 QH+...

CH4+ 28 C7H6+

.... CjH+ 28 C7H7+

.... C2D+ 28 C7H8+

... C,H2+ 28 C7H9+

.... C,D2+ 29 C7H+.... C,H3+ 29 C7H+.... C,D3+ 29 QH+... C2H4+ 29 C7H+.... C,H5+ 30

QH+ 30 C8H6+

.... C3H+ 30 C8H8+

.... C3H2+ 30 C8H9+

.... C3H3+ 30 QH+o.... C3H4+ 30 C8H+... C3H5+

31 CgH+.... C3H6+ 32 CgH+.... C3H7+ 33 C8H+.... C3H8+ 33 C8H+.... C4H2+ 33 C9H7+

.... C4H3+ 33 C9H8+

.... C4H4+ 34 C9H+.... C4H6+ 34 C9H+2

.... C4H7+ 35 C9H+3

.... C4H8+ 35 C9H,+4

.... C4H+ 36 C9H+.... QH+ 36 C9H+...

36

37

37

38

39

39

40

40

40

41

41

41

43

43

44

44

44

45

45

46

46

47

47

47

47

49

50

50

51

51

52

52

52

52

53

54

55

55

56

56

57

57

58

59

60

61

61

61

62 3
c10h;. C10Hjo* cI0H5..

C.oH.V.

C,oH,+5.. c10h,+6

.. C,oH2+0

.. Cn H9+

.. Cj|H,o . CuHS..

C„HS..

C„HS..

C..H+..

C„HS.. c12 h8+

.. c12 h+.. c12 h,+2

.. c12h+.. Ci2 H+.. c12 h+8

.. cI2 hj.. c12hj.. c13 h9+

.. C,3 Hi..

ChH.V. c13 h^.. Ci3H,+4

.. C,3H+.. c13 h2+6

.. c14 H+2

.. c14 Hr4

.. c14h,+6

.. c14 h2+8

.. c15 h9+

.. QjHS-.

C.sH.V- c15 h,+3

.. c15 h,+4

.. Ci5H,+6

.. C.6H.V. C16H,+

,.. c16 h,+2

.. c16 h,+3

.. c16h,v. c16 h,+6

.. cI6h,+8

.. c17 h,v. c17 h,+5

.. c18 h,+2

.. c18 H,v.

62 C18 H,+6 80

62 C18 H,+g 80

63 C18 H2+0 80

64 C19 H,+6 80

64 C19H2+o 80

64 C19 H2+2 80

65 C20H,+2 80

66 QoHji 81

66 C21 Hj+5 81

66 C22H,+2 81

66 C22H,+4 81

67 C22H,+8 81

67 C23H2+6 82

67 C24H,+2 82

68 C24H2+2 82

68 C25H,+6 82

68 C32H,+4 82

68 C6H5 Be+ 82

68 C12 H10Be+ 82

68 C12 H10B+ 82

68 C18 H15 B+ 82

69N+ 82

69

N

+2 82

69N

+3 83

69 N+ 83

70 N+2 83

70 NH+ 84

70 NH2+ 84

70 NH3+ 84

70 ND3+ 84

70 NH4+ 84

71

N2 H4+ 84

73

N3 H+ 85

74 BH6N+ 85

74 B3 H6N3+

85

74 CHN+ 85

74 CH4N+ 85

75 CH5 N+ 85

75 C2H2 N+ 86

75 C2 H4N+ 86

76 C2H6 N+ 86

76 C2 H7 N+ 86

76 C3 HN+ 86

77 C3 H6N+ 86

77 C3 H7 N+ 86

77 C3 H9N+ 86

77 C4H3 N+ 87

78 C4H5 N+ 87

78 C4 H10

N+ 87

78 C4 Hn N+ 87

78 C5 H4N+ : 87

78 C5 H5 N+ 87

79 C5 H6N+ 88 4
C5 H7N+

88 C5H12 N+

88 C6H5 N+

88 C6H6N+ 89 C6H7 N+ 89 C6Hg N+ 90 C6H9N+ 90 C6H15 N+ 90 C7H4N+ 90

90 C7 Hg N+

91 C7H9 N+

91 C7 H10N+ 92 C7Hn N+ 93 Cg H6N+ 93 Cg H7N+ 93 CgH9 N+ 93

QH10N+ 93 CgHnN+

93 Cg H12N+ 94 Cg H13 N+ 94

QH.N+ 94 C9HnN+ 95 C9H13N+ 95 C9H17N+

95

CjoH.N^ 95 C10H15 N+

95 CnH13N+ 96 CnH17N+ 96 C12HnN+ 96 C12H15N+ 96 C13 H9N~ 96 C13H12N+ 96 C13H13 N+ 96 C14H„N+ 97 C14H15 N+ 97 C15HnN+ 97 C16H13 N+ 97 C17H29N+ 97 ClgH15 N+ 97 C19H13 N+

97 C20H23N+ 97

CH2N2+ 97

CH3 N2+ 98 C2 H6N2+ 98 C2H8 N2+ 98 C3 H2 N2+ 98 C3H3 N2+ 98 C3 H4N2+ 98 C3 H6 N2+ 98 C3 Hg N2+ 98 C4H2N2+ 99 C4H4N2+ 99 C4Hg N2+

101 C4H10N2+

101 C4H12 N2+

101 C5 H4N2+ 102 C5 H6N2+

102 C5 H8 N2+ 102 C5 H10N2+ 102 C5 H12 N2+ 102 C6H4N2+ 102 C6H7 N2+ 102 C6Hg N2+

103 C6H10N2+ 103 C6H12N2+

103 C6H14N2+ 104 C6H16N2+

104 C7H8N2+

104 C7H10N2+ 104 C7H12N2+ 104 C7H14N2+ 104

QH16

N2+ 104 C8H6N2+

104 C8 H14N2+

105 C8 H16N2+ 105 C8 H18N2+ 105 Cg H20N2+ 106

106 C10H8 N2+ 106 C10H16N2+ 106 C10H20N2+

106 ChH8 N2+ 106 C12H20N2+ 106 C13H14N2+ 106 C14H12N2+ 106 C14H16N2+ 106 C17H22N2+ 106 Clg Hlg N2+ 107 C19H20N2+ 107 C19H24N2+ 107

CH3 N3+

107 C2H3 N3+ 107 C3 H3 N3+

107 C12Hn N3+

108

CH2 N4+ 108 C2H2N4+ 108 C4H6 N4+ 109 C10H20N4+ 109 C10H24N; 109 CnH15 N5+ 109 C32Hlg Ng+ 109

CHg BN+ 109 C2 Hg BN" 109 C2H9BN+ 109 C3 H12 BN+ 109 5
c4h12 bn\ c6h12 bn+ . c4h13 bn2+ . c5 h15 bn2\ c3 h12 b3 n3+ c6h14 bn3\ c6h18 bn3+ . c6h18 b3 n3+ c8 h24b2 n; o+ o

+2 o2+ OH+ h2o+ d2o+ h3 o+ LiO + Li2 0+ BO+ bo2+ bho2+ co+ co2+ c3o2+ CHO+ CDO+ ch2o+ ch3 o+ chd2o+

.. ch4o+ c2h2o+ c2 h3 o+ c2 h4o+ c2 h5o+ c2 h3 d2o+ c2 h2 d3o+ c2h6o+ c2 h3 d3 o+ c3 h4o+ c3 H6o+ c3 D6o+ c3 h7o+ c3 h4d3 o+ c3 h8 o+ c3 h5 d3 o+ c4 h4o+ c4 h5 o+ c4H6o+ c4H8o+ C4H10O+

... c5 h4o\...

109 C5 H60+ 121

109 C5HgO+ 121

109 C5 H90+ 122

109 C5 H10O+ 122

109 C6H40+ 122

110 C6Hs O+ 122

110 C6H60+ 122

110 C6HgO+ 122

110 C6H10O+ 123

110 C6H120+ 123

110 C7HsO+ 124

110 C7 H60+ 124

111 C7 H70+ 125

111 QHgC^ 126

111 C7H120+ 127

111 C7H140+ 127

112 C8 H70+ 127

112 CgHgO+ 128

112 C8H90+

128

112 C8 H10O+ 128

112 C8 H120+ 129

112 C8H140+ 129

112 C8H160+ 129

112 C9H90+ 130

113 C9H8DO+ 130

113 C9H10O+ 130

114 C9HI20+ 130

114 C9H180+ 130

114 C10Hn DO+ 130

114 C10H14O+ 130

114 C10H16O+131

114 CnH10O+131

115 Cn H120+131

115 C„H130+

131

119 CnH12DO+

131

119 CuH160+

131

119 C12H10O+ 132

119 C12H15 DO+ 132

119 C12H180+ 132

119 C13 H80+ 132

119 C13 H10O+ 132

119 C13 Hu O+

132

120 C13 H120+ 132

120 C14H10O+ 132

120 C14H140+ 132

120 C14H220+ 132

120 C15 H150+ 133

120 C16H10O+ 133

120 C16H160+ 133

121 CI8 H18 0+ 133

121 C19H20O+ 133

121 C19H220+ 133

121 C23H240+ 133 6
CH202+

133 C2H402+ 134 C3 H402+ 134 C3H602+ 134 C4H202+ 134 C4H402+ 134 C4H602+ 134 C4H802+ 134 C5H402+ 135 C5H602+

135 C5H802+ 135 C5H10O2+ 135 C6H402+ 136 C6H502+ 136 C6H602+ 136 C6H802+ 136 C6H10O2+ 137 C6Hu02+ 137 C6H1202+ 137

137

0^0+ 137 C7H702+

138 C7H802+ 138

C.HjoOJ’ 138 C7H1302+

138 C8H702+

138 C8H802+ 139 C8H10O2+ 139 C8H1202+

139

C^qO* 140 C9H1402+ 140 C10H6O2+ 140 C10H12O2+ 140 C10H14O2+ 140 C10H16O2+

141

C„H1602+

141

CiiH2o02+

141

141 C13H10O2+

141 C14H802+

141

^hHioO^ 142 C15H1202+

142

C2oH2202+

142

C2oH260^ 142

C22H1202+

142 C3H203+ 142 C3H403+

142 C3H603+

142 C4H203+

142 C6H603+ 143

C.IW 143 C8H503+ 143 C8H803+ 143 C9H703+

143 C9H10O3+

143 C10H6O3+ 144 C14H803+ 144 C14H1203+ 144 C2H404+ 144 C4H804+ 144 C5H10O4+ 144 C6H604+ 144 C6H8 04+ 144 C6H1204+ 144 C8H604+ 144 C9H804+ 144 C10H6O4+ 144 C14H804+ 145 C22H10O4+

145 C14H806+ 145 C10H14O4Be+ 145

CH3BO+145 C3H9BO+ 145 C3H9B02+ 145 C3H9B03+ 145

NO+145

N20+ 146

NO+ 146 C3N20+ 146 C6H5N03 146

CHNO+ 147

CH3NO+ 147 C2H3 NO+ 147 C2H5NO+ 147 C2H7NO+

147 C3H7NO+

147 C3H9NO+

147 C4H9NO+ 147 C4HnNO+

147 C5 H3 NO+

147 C5H5 NO+

147 C5H8 NO+ 148 C5H13 NO+

148 C6H5NO+ 148 C6H6NO+ 148 C6H7NO+ 148 C6HnNO+

149 C6H15NO+

149 C7H4NO+ 149 C7H6NO+ 149 C7H7NO+ 150 C7H9NO+ 150 C7H10NO+ 150 C7HnNO+ 150 C7H13NO+ 150 C7H17NO+ 150 7
Cg H4 NO* 150 C8 H7 NO+ 150 Cg Hg NO+ 151 C8 H9 NO+ 151 C8 H12 NO+ 151 C8 H13 NO+ 151 Cg H,gNO + 151 C9H8 NO+ 151 C9Hu NO+ 151 C9H13 NO+ 151 C9 H15 NO+ 152 C9H17 NO+ 152 C9 H18 NO+ 152 C10HI0NO+ 152 C10H,,NO+ 152 Cn H13 NO+ 152 C12 H13 NO+ 152 C12 H15 NO+ 152 C6H4N2 0+ 152 C8 Hl0N2O+ 152 C10H22N2O+ 152 C17H20N2O+ 153

CH3 N02+ 153

CD3 NOz+ 153 C2 H5 N02+ 153 C6 H4N02+ 153 C6 H5 N02+ 153 C6H7N02+ 154 C7 H6 N02+ 154 C7 H7 N02+ 154 C7 H10NO2+ 155 C8 H5 N02+ 155 C8 H9N02+ 155 C8 H13N02+ 155 C9Hn N02+ 155 C9H13 N02+ 155 C9H16 N02+ 156 C9H17 NOz+ 156 C10H13 NO2+ 156 C13 H10NO2+ 156 C13 Hu N02+ 156 C14 H13 N02+ 156 C4H4 N202+ 156 C6H6N202+ 156 C7 H4 N202+ 157 C7H8 N2 02+ 157 C8 H10N2O2+ 157 C9 H12 N2Oz+ 157 C9HI5 N2 02+ 157 C9 H17 N202+ 157

C,,H 12N202+ 157 Cn H21 N2 02+ 158

^12^2&N202 158 C13 H12

N2 0+ 158 C14H14N2 02+ 158 C16 H10N2 O2+ 158 C16H12 N2 02+ 158 C18 H17 N3 02+ 158 C4H3 NO+ 158 C6H5 N03+ 158 C7 H4NO+ 158 C7 H7 N03+ 159 C9Hn N03+ 159 C9 H7 N2 03+ 159 C10H10N2 O3+ 159

C;H5 N04+ 159 C8 H7 N04+ 159 C13 H9N04+ 159 C17H9 N04+ 159 C6H4N2 04+ 159 C13 H10N2O4+ 160 C14H12N2 04+ 160 C18 H30N2O4+ 160 C16Hu N3 04+ 160 F+ 160

F+ 160

HF+ 160

DF+ 160

BF+ 160

BF2+ 160

BF+ 160 B2 F4+ 161

CF+161

CF+ 161

CF+ 161 C2F3+ 162

CF4+ 162 C2F4+ 162 C3 F6+ 162 C4F6+ 162 C6F6+ 162 C4F8+ 163 C10Fg+ 163 C12F+ 163 C6F^ 163

CH2F+ 163 C2 HF+ 163 C2 H2 F+

163 C2 H3 F+ 164 C2 H4F+ 164 C2 H5 F+ 164 C3 HF+ 164 C3 H2 F+ 164 C3 H5 F+ 164 C3 H7F+ 164 C6 H4F+ 164 8
C6H5 F+ 164 C7H6F+

165 C7H7F+

165 C10H13F+

165 C10H15F+

165 C12H9F+ 165

CHF2+ 166 C2HF2+ 166 C2H2F2+ 166 C2H3F2+ 166 C3 HF2+ 166 C3H2F2+ 166 C6H4F2+ 166 C12H8F2+ 167 C2HF3+ 167 C2H3 F3+ 167 C3HF3+ 167 C6H3F3+ 167 C6H2F4+ 167 C6HF5+ 168 Cg H3 F5+ 168

NF+ 168 N2F+ 168

NF2+ 168 N2F2+ 169

NF3+ 169 N2F4+ 170 B3 H3N3 F3+ 170

CN2F2+ 170 C3N3 F3+ 170 C5 NF5+ 170 C2N2F6+ 170 C8N2F6+ 170 C9NF7 +

171

CH2 NF+ 171 C2H3 NF+

171 C3 H6NF+ 171 C6H6NF+ 171

CHNF2+

171

CH2NF2+ 171 C2H6NF2+ 171 C6H5 NF2+ 172 C8 H4N2 F2+ 172 C8 H2N2F4+ 172 C6 H2NF5+ 172 C6H7 NF6+ 172 C4H12 BN2 F+ 172 C2 H6 BNF2+ 172 C3 H9B3 N3 F3+ 172

OF+ 172

OF+ 172

HOF+

173

BOF+ 173

BOF+ 173

COF2+ 173 C2OF3+

174

CF40+ 174 C3 OF5+ 174 C3 F60+ 174 C6H4OF+ 174 C6H5 OF+ 174 C7H4OF+ 174 C7H7OF+

175 C7H5 02F+

175 C8 H7 02F+ 175 C6H4OF2+

175 C8H602F2+ 175 C2H3 OF3+ 175 C2H02F3+ 175 C3 H3 02F3+

175 C4H5 02F3+ 176 C5 H5 02F3+ 176 C6H3 02F3+ 176 C8 Hn02 F3+ 176 C4H5 04F3+ 176 C5 H704F3+ 176 C6H904F3+

176 C3 H3 OF5+ 176 C6HOF5+ 176 C7H3 OF5+ 176 C3 H2OF6+ 176 C5 H202 F6+ 176 C10H2 O4F12 Be+ 176

NOF3+ 176 C2NOF6+ 177 C8 H8NOF+ 177 C6H4N02F+ 177 C8 H7NOF2+ 177 C6H4NOF3+ 177

Ne+ 177

Na+ 177

Na2+ 177

Mg+ 177 C5 H5 Mg+ 178 C10H10Mg+ 178 C12H14Mg+ 178

Al+178

A1+ 178

A1C+ 178

A1C2+ 178

A12 C2+ 178 C18 H15A1 + 178

A10+ 178

A102+ 179

A12 0+ 179

A1202+ 179 9
A1F+ 179

A1F+ 179

A10F+ 179

A10F2+ 179 C15H1206F9A1 +

179 CI5 H306F18Ar 179

Si + 179

SiH + 179

SiH2+ 180

SiH3+ 180

SiH4+ 180

Si2H6Te+ 180

SiC2+ 180

Si2 C+ 180

CH3 Si + 180

CHs Si + 180

C^Si* 180 C2H7Si + 180 C3 H8 Si + 180 C3 H9 Si +

181 C4H9Si +

181 C4HI2Si + 181 C5H10 Si + 181 C5 HI2 Si + 182 C6H8 Si + 182 C6H12 Si + 182 C6H14 Si + 182 C8 H„Si+ 182 C8 H,2 Si + 183 C9H14 Si + 183 C10H10Si + 183 C10H14Si + 183 C10H16Si + 183

C,,H 16 Si + 183 C12H16Si + 183 C12 H18 Si + 184 Cl3 HI3 Si + 184

C,3 H14 Si + 184 C13 H16 Si + 184 C14 H14 Si + 184 Cl4 H18 Si + 184

C,7Hlg Si + 185

C,7H20Si + 185 C18 H15 Si + 185 CI8 H16Si + 185 C22H20Si + 185 C24H16Si + 185 C24 H20Si + 185

^6^18^2 186

CnHaoSi? 186

C)2 H,0Si2 186

C^Si* 186 C13 H22Si2+ 186 C14 H24 Si2+ 186 C15 H22 Si2+ 186 C15 H24Si2+ 186 C16H22 Si2+ 186 C21 H24Si2+ 187 C24H26Si2+ 187 C26H26Si2+ 187

C^HuSy- 187 C8 H24Si3+ 187 C17H28 Si3+ 187 C26H32 Si3+ 187 C6H16Si4+ 187 C10H24Si4+ 187 C10H30Sy 187 C10H30Si5+ 187 C12 H36Si5+ 188 C12H36Si6+ 188 C16H36 Si7+ 188

Si2 N+ 188

SiH3 N3+ 188

Si3 H9N+ 188 C2 H9NSi+ 188 C8 H13 NSi+ 188 C3 H9N3 Si + 188 C8H24N4Si + 188

CH9NSi2+

188 Cu H21 NSi2+ 188

SiO + 188

Si2 H60+ 189

CH6OSi+ 189 C3 H9SiO+ 189 C10H16OSi+ 189 C13 H18 OSi+ 189 C13 H20OSi+ 189 C5 H1202 Si + 189 C8 H20O4Si + 189 C12H22OSi2+ 189

Si2 NO+ 189

CH3 NOSi+ 189 C4H9 NOSi+ 190

SiF4+ 190

Si2 F6+ 190

SiH3 F+ 190

SiH2 F2+ 190

SiHF3+ 191

SiF3 C+

191 C5 H9 SiF +

191

CH3 F3 Si + 191 C7 H10F6Si +

191 C6H12 F4Si4+

191

SiAl + 191

SiA10+ 191 P + 192

10
P2+ 192 P4+ 192

PH+ 192

PH2+ 193

PH3+ 193

BP+ 193

PC+

193 C2P+ 193

CP2+ 193

CHP+ 193

CH5 P+ 193 C3H9 P+

193 C4HnP+ 193 C5 H5 P+ 193 C10H9P+

193 C10H13P+ 194 C12H13 P+

194 C12H17 P+ 194 C15HnP+ 194 C17H29P+ 194 C19H13 P+ 194 C29H25P+ 194 C6H18 N3 P+ 194 C8H18 N3 P+ 194

PO+ 194

PO+ 194 P2 03+

195 P204+ 195 P2Os+ 195 P3 06+ 195 P307+ 195 P407+

195 P4Og+ 195 P409+ 195 P4Or0 195

CH4OP+ 195

CH402 P+ 195

CH5 02 P+

195 C2H602 P+ 196 C19H35 02 P+ 196

CH403 P+ 196 C2 H603 P+ 196 C2 H703 P+ 196 C3 H8 04P+ 196 C3 H904P+ 196

PF3+ 196

PF5+ 197 P2F4+ 197

PHF+ 197

BH3 F3 P+ 197 B3 H5 F3 P+ 197

PH2 NF2+ 197

CNF2 P+ 197 C4H12

N2 PF+ 197 C2H6NPF2+ 197 C6H18 N3 F2P+

197 C4H12N2F3P+ 197 C2H6NF4P+ 197 C2H9BNF2P+ 197 C2Hn B3NF2P+ 197 C2H12 B3 NF2P+ 197 C2H12B4NF2P+ 198

C,H14B4NF2P+ 198

POF+ 198 P2OF4+ 198

CNOF2 P+ 198

NaP02+ 198

PSi+ 198

PSi2+

198 P2 Si + 198

SiH5 P+ 198

Si3H9P+

198

CSiP+ 198 C7H19 SiP+

199 C9H25 Si2P+ 199 S +

199 S2+

199 S8+

199

HS+

199 H2S+

199 H3 S + 200

BHS+ 200

CS+ 200

CS2+ 201

CHS+ 202

CH2 S + 202

CH3 S + 202

CH4S + 202 C2H3 S + 203 C2H4S + 203 C2H5 S + 204 C2H6S + 204 C3 H5 S+ 205 C3 H6S + 205 C3 H7S + 205 C3H8 S + 205 C4H4S+ 205 C4D4S + 205 C4H6S + 205 C4H8 S + 205 C4H9S + 206 C4H10S + 206 C5 H6S + 206 C5 H10S + 206 C6H6 S + 206 C6H8 S + 206

11
C6H10 S + 207 C6HI4 S + 207 C7H8 S + 207 Cg H6S + 207 Cg H10S + 207 C8 H12 S + 207 C8 H18 S + 207 C9H10S + 207 CU H10S + 208 C12 H8 S + 208 C12 H10S+ 208

CH2 S2+ 208 C2 H6S2+ 208 C3 H5 S2+ 208 C3 H6 S2+ 209 C3 H8 S2+ 209 C4 H8 S2+ 209 C4H10S2+ 209 C5 H6S2+ 209 C6H4S2+ 209 C6 H10S2+ 209 C6 H14 S2+ 209 C8 H10S2+ 210 C8 H18 S2+ 210 C3H6S3+ 210 C5 H4S3+ 210 C6H6S3+ 210 C7 H8 S3+ 210 C10H12 S3+ 210 C12 H16 S3+ 210 C14 H20S3+ 210 CI7 H12 S3+ 210 c6h4 s; 210 C10H18 S6+ 211 C3 H9BS+ 211 C3 H9 BS2+ 211 C3 H9 BS3+ 211

CHNS+ 211 C2 H3 NS+ 211 C3 H3 NS+ 211 C4H5 NS+ 211 C5 H3 NS+ 212 C5 H5 NS+ 212 C6H7 NS+ 212 CioH9NS+ 212 C12 H9NS+ 212 C13 Hn NS+ 212 C3 H6 N2 S + 213 C4H2 N2 S + 213 C4 H8 N2 S + 213 C6H4 N2 S + 213 C8 H18 N2 S + 213 C16 H18 N2 S + 213 C17 H20

N2 S + 213 C18 H22 N2 S + 213 C20H25 N3 S + 213

SO+ 213

SO+ 214 S2 0+ 214

COS+ 215

CH2 OS+ 215 C2 H4OS+ 216 C2 H6OS+ 216 C3 H5 OS+ 216 C3 H6OS+ 216 C4H8 OS+ 216 C4H10OS+ 216 C5 H4OS+ 216 C5 H6OS+ 216 C6H6OS+ 216 C6HnOS+ 217 C6H12OS+ 217 C6H14OS+ 217 C7 H13 OS+ 217 C7 H14OS+ 217 C8 H16OS + 217 C8H18 OS+ 217 C12H10OS+ 218 C2H602 S + 218 C3 H6S02+ 218 C4H6S02+ 218 C5 H402 S + 218 C5 H10O2 S + 218 C6H602 S + 218 C14H9 02 S + 218 C15 Hn 02 S + 218 C2 H403 S + 218 C2 H603 S + 218 C4H3 NSO+ 219 C4H9NOS+ 219 C6 H7 NOS+ 219 C6 H„NOS+ 219 C7 H5 NOS+ 219 C7 H9 NOS+ 219 C8 H7 NOS+ 219 C8 H9 NOS+ 219 C8 Hn NOS+ 219 C13 H9 NOS+ 219 C3 H2 N2OS+ 220 C4 HI2 N2 OS + 220 C17 H18 N2OS+ 220 C18 H22N2 OS+ 220 C19H22N2 OS + 220 C20H24N2OS+ 220 C19 H23 N3 OS+ 220 C22H27 N3 OS+ 220

12
C23 H29

N3 OS\... c3 h7 no2 s + c4h3 no2 s + c5 hu no2 s + c7 h5 no2 s + c8 h7no2 s+ c8 h9 no2 s + c13 h9 no2 s + c3 h2 n2 o2 s + c15 hu no3 s +

^-' 22^30^4^2^2 •••' SF+ sf2+ sf3+ sf4+ sf5+ s2 f+ S2 F2+ cf2 s + NSF+ nsf3+ C21 H24N3 F3 S +

.... so3 f+ sof2+ so2f2+ ch3 o2fs+ C6H3 OF3 S + C20H21 N2 OF3 S + . c22h26n3 of3 s + . C20H19N2O2F3 S + C22H24N3 02F3 S + SiH4 S +

Si2H6 S + CH6 SiS + CH3 NSiS+ C4H9 NSiS+ PS+ P4S + p4s2+ p4s3+ p4s4+ p4s5+ p4s6+ p4s7+ P s + r4°8 P s +

jr 4°9 P s +

Jr 4 °10 ch2 ps + C6Hlg N3 PS+ C2 H6OPS+ c2 h6o2 ps+ c2 h7o2 ps + c2 h6o3 ps +

220 C3 H9 03 PS + 228

220 C2 H6OPS2+ 228

220 C2 H7 OPS2+ 228

220 C2H602 PS2+ 228

220 C3 H9 02 PS2+ 228

221 CNF2 PS+ 228

221 Cl + 228

221 Cl +2 229

221 Cl2+ 229

221 BC1+ 229

221 BC12+ 229

221 BC13+ 229

221 B2 C14+ 229

221 CC1+ 230

221 CC12+ 230

222 CC13+ 230

222 C6 C14+ 230

222 C6C16+ 230

222 CH2 C1 + 230

222 CH3 C1+ 230

223 C2 HC1+ 231

223 C2H2 C1 + 231

224 C2H3 C1 + 231

224 C2 H5 Cr 231

225 C3 H5 C1+ 231

226 C3 H7 C1 + 231

226 C4H9 C1 + 231

226 C6H4C1+ 231

226 C6H5 C1 + 231

226 C6Hu C1 + 232

226 C7 H6C1 + 232

226 C7 H7C1 + 232

226 C8 H7 C1 + 232

226 C10H15 C1+ 232

226 C12H9 C1 + 232

227 CHC12+ 232

227 CH2 C12+ 233

227 C2H2 C12+ 233

227 C6H2 C12+ 233

227 C6H4C12+ 234

227 C8 H6C12+ 234

227 CHC13+ 234

227 C6H3 C13+ 234

227 C6H2C14+ 234

227 C6HC15+ 234

227 B3 H3 N3 C13+ 234

227 C6H6NC1+ 234

227 C16HI2 NC1+ 235

227 C6H5 NC12+ 235

227 C4H12 BN2 C1 + 235

227 C2 H6BNC12+ 235

228 C3 H9 B3 N3 C13+ 235

228 C102+ 235

13
ci2 o+ COCl2+ C2 OCl3+ c8o3 cl4+ C3 H5 OCl + c6 h4oci + C6 H5OCl + C7 H5OCl + C7 H7OCl + c2 H3 o2 cr.... c8 H7 o2 cr.... c6h4oci2+ c8 h6o2 ci2+ C8 H7 NOCl +

.. C8 H8 NOCr.. C17 HI4 NOCl + c6h4 no2 ci + c8 h7 noci2+

.. C1F+ C1F3+ BC1F+ BC1F2+ BC12 F+ CFC1 + cf2 ci + C2 F2 C1 + cf3 ci + c2 f3 ci + CFC12+ C2 FC12+ CF2C12+ CF2CC12+ CFC13+ CH2 FC1 + C2 HFC1+ C2 H2 FC1 + CHF2 C1 + C2 HF2 C1 + CHFC12+ cio3 f+ Aiocr

sicr

SiCl4+ SiH3 Cl + SiH2 Cl2+ SiHCl3+ C3 H9 SiCl + C4H9 SiCl + C4Hn SiCl +

... C5 H9 SiCr C2 H6 SiCl2+

.... C3 H6SiCl2+

.... c6 HI2 si4ci; ..

236 C4H12

N2 SiCl2+ 244

236 C2 H6NSiCl3+ 244

237 C6H1503 SiCl + 244

237 C4H10O2 SiCl2+ 244

237 C2 H5 OSiCl3+ 244

237 SiF3 Cl + 244

237 PC1 + 245

237 PC12+ 245

237 PC13+ 245

238 PC15+ 245

238 POC1 + 245

238 POC1+ 246

238 PF2C1 + 247

238 CSC12+ 247

238 C2S2C14+ 247

239 C4H3 SC1 + 248

239 NSC1+ 248

239 C17H19N2 SC1 + 248

239 C20H24N3 SC1 + 248

239 SOC1+ 248

240 S02 C12+ 249

240 SOCl3+ 250

240 CH3 02 SC1 + 250

240 C17H17

N2OSCl+ 250

240 C19H21N2OSCl + 250

240 C21 H26N3OSCl+ 250

240 SF5 C1 + 250

241 CFSC1+ 250

241 S02 FC1+ 250

241 PSC1+ 251

241 C4H12N2 PSC1 + 252

241 C2 H6NPSC12+ 252

241 Ar+ 252

241 Ar+2 252

241 Ar+3 252

241 Ar+4 252

241 Ca+ 252

241 Ca+2 252

241 Ca+3 252

242 Sc + 252

242 Sc +3 253

242 Sc +4 253

242 ScC2+ 253

242 C15 H3 06F18 Sc + 253

242 Ti + 253

243 TiC2+ 253

243 TiO + 253

244 Ti02+ 253

244 C15 H3 06F18Ti + 253

244 TiS + 254

244V+ 254

244 VN+ 254

244 VO+ 254

14
vo2+ V40+ v4o+ c15h3o6f18v+

Cr+ C6H6Cr+ C7H8Cr+ C8 H10Cr+ C9H12 Cr+ C10H,0Cr ... CnHnCr+

.. C12H12Cr+

... C12H18 Cr+

... C14H16Cr+

... C20H44Cr+

... C6H7NCr+

.. CrCO+2 C606Cr+ C7H6OCr+

.. C7H8OCr+

.. C8H8OCr+

.. C9H,0OCr+ . C10H12 OCr+ C13Hi8OCr+ . C8H602 Cr+

.. CgH802Cr .. C9H802Cr+

.. C10H10O2Cr+ CnH1202Cr+ Ci4H18 02Cr C9H603 Cr+

.. C9H803 Cr+ . C10H8O3 Cr+ CnHi0O3 Cr C12H1203 Cr+ C15H18 03 Cr+ C10H8O4Cr+ . CnH805 Cr+ . C8H606Cr+

.. C13 H806Cr+ . Ci4H10O6Cr+ C15 H2 i06Cr+ Ci4H10O7 Cr+ C7H7NOCr+ C8 H7N02Cr+

... C7H5 N03 Cr+

... C9H7N03 Cr+

... Cn HnN03 Cr+ . C13 H706FCr+

.. C]4H706F3 Cr+ . Ci5 H1206F9 Cr+ Ci5H306F18 Cr+ C16H44Si4Cr+

....

... 254 C6H18

N3 PCr+ 261

... 254 C7H18

N3 OPCr+ 261

... 254 C9H18

N3 03 PCr+ 261

... 254 C10H18N3 O4PCr+ 261

... 254 Cn H18N3 05 PCr+ 261

... 255 C15H36N603P2Cr+ 261

... 255 Cj 6H36N604P2Cr+ 261

... 255 CrP6Fj^ 261

... 256 C9H8 05 SCr+ 261

... 256 C7H606 SCr+ 261

... 256 C7H4Og SCr+ 261

... 256 C6H5 ClCr+ 261

... 256 C7H5OClCr+ 261

... 256 C8H5 02ClCr+ 262

... 256 C9H503 ClCr+ 262

... 256 C,3H706ClCr+ 262

... 256 Mn+ 262

... 256 MnH+ 262

... 256 C10H10Mn+ 262

... 257 C11 H11 Mn+ 262

... 257 C32H16N8Mn+ 262

... 257 MnCO+ 262

... 257 MnC202+ 262

... 257 MnC303+ 262

... 257 MnC404+ 262

... 257 CHOMn+ 262

... 258 C2H02Mn+ 263

... 258 C3 H03Mn+ 263

... 258 C8H503Mn+ 263

... 258 C4H04Mn+ 263

.. 258 C5H05Mn+ 263

... 258 C15 H21 06Mn+ 263

... 258 MnF+ 263

.. 259 MnF2+ 263

... 259 MnF+ 263

.. 259 MnF4+ 263

.. 259 C15H306F18Mn+ 263

.. 259 C19H3O10F18Mn+ 264

.... 259 C3H9SiMn+ 264

.. 259 C4H9OSiMn+ 264

.. 259 C5H902 SiMn+ 264

.. 260 C6H903 SiMn+ 264

.. 260 C7H904SiMn+ 264

.. 260 C5H3 05 SiMn+ 264

.. 260 C8 H905 SiMn+ 264

.. 260 C7H904F3SiPMn+ 264

... 260 C6H903 F6SiP2Mn+ 264

.. 260 C5 H902F9SiP3 Mn+ 264

.. 260 C10H15 SMn+ 264

.. 260 C18H17 SMn+ 264

.. 260 C8 H13 OSMn+ 265

.. 260 C10H15 OSMn+ 265

.. 261 C18 H17 OSMn+ 265

15
C12 Hl5 02 SMn + 265 C20H17 O2 SMn+ 265 C8 Hn03 SMir 265 C10H13 O3 SMn+ 265 C12 H 15 03 SMn+ 265 C20Hl7O3 SMn+ 265 C10H,,O5 SMn + 265 C5 05 ClMn + 266

Fe+ 266 C3 H3 Fe + 266 C5 H5 Fe+ 266 C10H10Fe + 266 C12 H12 Fe+ 267 C12 H14 Fe + 267 C32H16 N8 Fe+ 267 C15 H21 06Fe+ 267 C33 H5706Fe+ 267 C15 H12 06F9 Fe+ 267 C15 H3 06F18 Fe+ 267 C13 H,8 SiFe + 268 C6 H, 8 N3 PFe+ 268 C12 H36N6P2Fe+ 268 C7 Hlg N3 OPFe+ 268 C8 H18 N3 02 PFe+ 268 C9 H18 N3 03 PFe+ 268 C10H18 N3 O4PFe+ 268 C13 H36N6OP2 Fe+ 268

C, 4H36

N602 P2 Fe+ 268 C15 H36N603 P2 Fe+ 268

FeP5 F1f5 268 C10H9 ClFe+ 268 C10H8 Cl2 Fe+ 268

Co+ 268 C3 H3 Co+ 269 C5 H5 Co+ 269 C10H10Co+ 269

C,,H 13 BCo + 269 CI2 Hi6 B2 Co+ 269 C16 H15 BCo+ 269 C22H20B2 Co+ 269 C32 H16 N8 Co+ 269

COCo + 269 C2 02 Co + 269 C4H04Co+ 269

C, 5 H21 06Co+ 270 C12 H16 B202Co + 270

C,5 H306F18 Co 270 C4 H3 04SiCo + 270 F3 PCo + 270

ClCo + 270

SiCl2 Co+ 270

SiCl 3 Co+ 270

COSiCl3 Co+ 270 C2 02 SiCl3 Co+ 270 C3 03 SiCl3 Co+ 270 F3 SiPCl3 Co+ 270 C3 03 F3 SiPCl2 Co+ 271

COF3 SiPCl3 Co+ 271 C3 03 F3 SiPCl3 Co+ 271

COF6SiP2Cl3 Co+ 271 C202 F6SiP2 Cl3 Co+ 271

Ni + 271 C3 H3 Ni + 271 C5 H5 Ni + 271 C6H10Ni + 272 C8 H8 Ni + 272 C10H10Ni + 272 C32 H16N8 Ni + 272 C5 H5 NONi+ 272 C12 H18 N2 02 Ni + 272

Cu+ 272

Cu2+ 273

Cu3+ 273 C32H16 N8 Cu+ 273 C12 H18 N202Cu+ 273

CuCl+ 273

Cu2 Cl + 273

Cu2 Cl2+ 273

Cu3 Cl2+ 273

Cu3 Cl3+ 273

Cu4Cl3+ 273

Cu4Cl4+ 273

Cu5 Cl4+ 273

Cu5 Cl5+ 274

Zn+ 274 C32H16N8 Zn+ 274

ZnCl2+ 274

Ga+ 274

CH3 Ga+ 274 C2 H3 Ga+ 274 C2 H4Ga+ 274 C2 H6Ga+ 275 C3 H9Ga+ 275 C4H6Ga+ 275 C6H9 Ga+ 275 C12 HI0Ga+ 275 C18 H15 Ga+ 275

GaF+ 275

GaF2+ 275

Ga2 F5+ 275 C15 H3 06F18 Ga+ 275

GaP+ 275

Ge+ 275

Ge+ 275

GeH4+ 275 C3 H9 Ge+ 276

16
C4H12 Ge+ 276 C7 H18 Ge+ 276 C8 H18Ge+ 276 C8 H20Ge+ 276 C9 H14Ge+ 276 C9H20Ge+ 276 C10H14Ge+ 276 C10H16Ge+ 276 C12 H18 Ge+ 277 C13 H15 Ge+ 277 C14H18 Ge+ 277 C6H18 Ge2+ 277

GeH3N3+ 277

Ge3 H9N+ 277

GeO+ 277

Ge2H60+ 277

CH3 NOGe+ 277

GeF2+ 277

GeF4+ 277

Ge2 F4+ 278

GeH3F+ 278

GeH2F2+ 278

GeOF2+ 278 C6H18 SiGe+ 278

GeH5P+ 278

Ge3 H9P+ 278

GeH4S + 278

Ge2H6S + 278

CH3 NSGe+ 278

Cl3 Ge+ 278

Cl4Ge+ 278

GeH3 Cl+ 278

GeH2 Cl2+ 279 C2H6ClGe+ 279 C3H9 ClGe+ 279

CH3 Cl2Ge+ 279 C2H6Cl2Ge+ 279

CH3 Cl3Ge+ 279 C8 H14CrGe+ 279 C9H14OCrGe+ 279 C10H14O2CrGe+ 279 Cn H1403 CrGe+ 279 C5 H3 05 MnGe+ 279 C4H3 04GeCo+ 279

GeCu+ 280

As+ 280

As2+ 280

As4+ 280

AsH3+ 280 C2H7As+ 280 C5H5 As+ 280 C12H13As+ 280 C19H13As+ 280

AsF3+ 280 C6H7F6As+ 280 C8 H,,F6As+ 280

Si3 H9As+ 280

AsP+281

AsP3+ 281

As2 P2+ 281

As3 P+ 281

AsS+ 281

As2 S2+ 281

As3 S2+ 281

As3 S3+ 281

As4S3+ 281

As4S4+ 281

AsC13+ 281

Se + 281

Se+4 281

SeH+ 281 H2 Se+ 281

CSe+ 282 C2H5 Se + 282 C2H6 Se + 282 C3H7 Se + 282 C4H4Se+ 282 C5 H6Se+ 282 C3 H6NSe+ 282 C4H10NSe+ 282

COSe+ 283 C5H4OSe+ 283 C6H6OSe+ 283 C5H402 Se+ 283 C4H6NOSe+ 283 C5 H9NOSe+ 283 C4H8N02 Se+ 283 C5 HnN02Se+ 283 C6H3OF3 Se+ 283

Si2H6Se+ 283

SeP+ 284

CSSe+ 284

ScSe+ 284

Ge2H6Se+ 284

Br+ 284

Br+4 284

Br+5 284

HBr+ 284

DBr+ 284 C2HBr+ 285 C2 H3 Br+ 285 C2 H5 Br+ 285 C3 H5 Br+ 285 C3H7 Br+ 285 C4H7 Br+ 286 C4H9 Br+ 286

17
C5 H9 Br + C5 Hn Br+ C6H4 Br + C6 H5 Br+ C6Hn Br+ C7 H7 Br+ C7 H9Br+ C10H15 Br+ C12 H9 Br + C2 ~H2 Br2+ C5 H8 Br2+ C6 H4 Br2+ C6H10Br2+ ^12 ^8®r2 C6H3 Br3+ C6H6 NBr+

.... C| 8 H17 N2 Br + . C6 H5 NBr2+

.... C4H12 BN2 Br+ C2 H6 BNBr2\.

COBr2+ C5 H9OBr+ C6 H4OBr+ C6H5 OBr+ C7 H4OBr+ C7 H7OBr+ C2 H3 02 Br+

... C7 H5 02 Br +

... C7 H,,02 Br+

.. C8 H7 02 Br+

... C6H4OBr2+ C8 H602 Br^ ... C8 H7 NOBr+ . CgH8 NOBr+ . C6H4N02 Br + C8 H7 NOBr2+ . BrF+ BrF3+ BrF5+ CF3 Br + C2 F3 Br + C5 H8 FBr+ C6H10FBr+ C12 H8 FBr+ SiBr + SiH3 Br+ SiH2 Br2+ C5 H9SiBr+ SiF3 Br+ PBr+ PBr2+ PBr3+ POBif

286 PF2 Br+ 296

286 C4H3 SBr+ 296

286 SOSBr2+ 296

286 SOBr3+ 297

286 PSBr3+ 297

287 C5 H8 ClBr+ 298

287 C6H10ClBr+ 298

287 PClBr+ 298

287 PCl2 Br+ 298

287 PClBr2+ 298

288 C5 05 BrMn+ 298

288 C6H3 N04MnBr+ 298

288 Cu3 Br3+ 298

289 Cu4Br3+ 298

289 Cu4Br4+ 298

289 ZnBr2+ 298

289 GeH3 Br+ 299

289 GeH2 Br2+ 299

289 Kr+ 299

289 KrF2+ 299

289 Rb+ 300

290 Rb+2 300

290 RbCl + 300

290 RbBr+ 300

290 Rb2 Br+ 300

290 Sr+ 300

291 Sr+2 301

291 Sr+3 301

291 SrCl + 301

291 Y+ 301

291 Y

+6 301

291 YS+ 301

291 YSe+ 301

292 Zr+5 301

292 Zr+6 301

292 ZrCl + 301

292 ZrCl2+ 301

292 ZrCl3+ 301

292 ZrCl4+ 301

292 Nb+6 301

293 Nb+7 302

293 NbF3+ 302

293 NbF4+ 302

293 Nb2 F9+ 302

293 Nb3 F,+4 302

293 NbCl + 302

294 NbCl2+ 302

294 NbCl3+ 302

294 NbCtf 302

294 Mo+ 302

294 Mo+7 302

294 Mo+8 302

295 C606Mo+ 302

18
C6H18

N3PMo+ 302

C,2H36

N6P2Mo+ 303 C7H18N3OPMo+ 303 C8H18N3 02PMo+ 303 C9H18N303 PMo+ 303 C10H18N3O4PMo+ 303 ChH18N3 05 PMo+ 303 C13H36N6OP2Mo+ 303 C14H36N602P2Mo+ 303 C15H36N603 P2Mo+ 303 C16H36N604P2Mo+ 303

MoCl+ 303

MoC12+ 303

MoC13+ 303

MoC14+ 303

MoC15+ 303

Mo02C12+ 303

MoOCl+ 304

MoOC14+ 304

Mo02Br2+ 304

Mo02ClBr+ 304

Ru+ 304 C3H3Ru+ 304 C5H5Ru+ 304 C8H8Ru+ 304 C10H10Ru+ 304 C12H14Ru+ 305

Ru04+ . 305 C15H306F18Ru+ 305

RhC+

305

RhC2+ 305

QH^Rh* 305 C12H904Rh+ 305 C17Hn04Rh+

305 C15H2106Rh+ 305 C15H20NO8Rh+ 305 C15H19N2O10Rh+ 306 C15H18N3 012Rh+ 306 C7H404F3Rh+ 306 C7H04F6Rh+ 306

RhP4F12H+ 306

Pd+ 306 C6H10Pd+ 306 C12H18N202Pd+ 306

Ag+ 306

Ag2+ 306

Ag3+ 307

NaAg+ 307

AgAl+ 307

AgP02+ 307

AgCl+ 307

Ag2Cl+ 307

Ag2Cl2+ 307

Ag3 Cl+ 307

Ag3 Cl2+ 307

Ag3 Cl3+ 307

Ag4Cl3+ 307

Ag4Cl4+ 308

Ag5 Cl4+ 308

AgBr+ 308

Ag2Br+ 308

Ag3 Br^ 308

AgjBr^ 308

Cd+ 308

CdCl2+ 308

CdBr2+ 309

In+ 309

In2+ 309

InO+ 309

ln20+ 309

InCl+ 309

InBr+ 309

Sn+ 309

SnH4+ 310 C3 H9Sn+ 310 C4H12 Sn+ 310 C7H18 Sn+ 310 C9H14Sn+ 310 C10H16Sn+ 310 C12H16Sn+ 310 C12H18 Sn+ 310 C13H16 Sn+

311 C14H18 Sn+

311 C14H30Sn+

311 C15H32Sn+

311 C16H36Sn+

311 C24H20Sn+

311 C6H18Sn+ 311

SnO+311 C6H18SiSn+

311 C16H44Si4Sn+

311 C6H18 GeSn+ 311

SnBrCl+

311

SnBr2Cl+

311

SnBr3 Cl+

311

Sb+

311

Sb2+

311

Sb3+ 312

Sb4+ 312

SbH3+ 312 C5H5 Sb + 312

SbF3+ 312

SbP+ 312

TeH+ 312 H2Te+ 312 C2H6Te+ 313

19
c4 hjv 313 Cu3I^ .... C5 H6Te+ 313 Cu2 I3\... C5 H4OTe+ 313 Cu3 I 3+

... C6 H6 OTe+ 313 Cu4I 3+

... C5 H4 02 Te+ 313 cu4i;... C6 H6 02 Te+ 313 Znl2 TeP+ 313 Znl2+ C5 H6 STe+ 313 GeH3 I + Ge2 H6Te+ 313 GeH2 I 2+ r 314 IBr+ I 2+ 314 Rbl +

I^ 2 314 Rb2 I +

... CH3 I + 314 Agl+

.... c2 hi + 314 Cdl2+ C2 H3 I + 314 Inl + C2 H5 I + 314 Xe+ c3 h5 i + 315 XeOF4+ . c3h7 i + 315 Cs+ c4 h9 i + 315 Cs+3 C5 Hm I + 316 Cs+4 C6 H13 I + 316 Cs+5 C7 H7 I + 316 Cs+6 CI2 H9 I + 316 Cs+7 C2 H2 I 2+ 316 Cs+8 c6h6 ni + 316 Cs+9 C7 cH,cN? I + 317 Cs+1° C29H35 N2 I + 317 Cs2+ c4 h, 2 bn2 i + 317 Cs2N03+ c2 h6 bni2+ 317 CsF+

.... C2 H5OI + 317 CsCl +

... C3 H7 OI + 317 CsBr+

... c6h5 oi + 317 Csl + c2 h3 o2 i + 317 Ba+ c8 h7 o2 i + 317 Ba+2 c6h4oi2+ 317 Ba+3 c8h6o2 i2+ 317 Ba+4 C8 H8 NOr 318 Ba+5 IF5+ 318 Ba+6

Nal + 318 Ba+7 Mgir 318 Ba+8

SiH3 r 318 Ba+9

SiH 7 I,+ 318 Ba+I° .... C5 H9 SiI + 318 BaO+

.... PI?- 318 La+ pf2 i + 319 LaC+

.... c4 h2 si2+ 319 LaC2+

.... icr 319 LaC3\... C5 05 IMn+ 319 LaC^ .... cur 319 LaF+

.... Cu2 I + 319 LaF^ .... Cu3 I + 319 La2F51'... Cul2+ 319 LaSe +

.. Cu2 I 2+ 319 LaRh + .

319

319

319

319

320

320

320

320

320

320

320

321

321

321

321

321

321

322

322

322

322

322

322

322

322

322

322

322

322

322

323

323

323

323

323

323

323

323

323

323

323

323

323

323

324

324

324

324

324

324

324

324

324

20
Ce+ 324

Ce+2 325

Ce+3 325

Ce+4 325

Ce2+ 325 C2 Ce+ 325

CeN+ 325

CeO+ 325

Ce02+ 325

Ce202+ 325

CeF+ 325

CeF2+ 325

CeF3+ 325

Ce2F5+ 326

CSiCe+ 326

CeS+ 326

CeS2+ 326

CePd+ : 326

Cel + 326

Cel+2 326

Cel2+ 326

Cel3+ 326

Pr+ 326

Pr+3.. 326

Pr+4 326

Pr+5 326

Prl + 326

Prl2+ 326

Prl3+ 326

Nd+ 326

Nd+3 327

Nd+4 327

NdCl+ 327

NdCl2+ 327

NdCl3+ 327

NdBr+ 327

Ndl+ 327

Ndl2+ 327

Ndl+ 327

Pm+3 327

Pm+4 327

Sm+ 327

Sm+3 327

Sm+4 327

Sml+ 327

Sml2+ 328

Eu+ 328

Eu+3 328

Eu+4 328

Eu2+ 328

EuC2+ 328

EuCN+ 328

EuAg+ 328

Eul+ 328

EuI2+ . 328

Gd+ 328

Gd+3 328

Gd+4 328

GdCl+ 328

GdCl2+ 328

NaGdCl3+ 329

Gdl+ 329

Gdl2+ 329

Gdl3+ 329

Tb+ 329

Tb+3 329

Tb+4 329

Tbl + 329

Tbl2+ 329

Tbl3+ 329

Dy+ 329

Dy+3 329

Dy+4 329

Dyl+ 329

Dyl+ 329

Dyl3+ 329

Ho+ 329

Ho+3 330

Ho+4 330

Ho2+ 330

HoAg+ 330

HoI+ 330

HoI2+ 330

HoI3+ 330

Er+ 330

Er+3 330

Er+4 330

Erl+ 330

Erl+ 330

Erl+ 330

Tm+ 330

Tm+3 330

Tm+4 331

TmBr2+ 331

TmBr3+ 331

Yb+ 331

Yb+2 331

Yb+3 331

Yb+4 331

Yb+ 331

YbCl+ 331

YbCl2+ 331

YbBr+ 331

YbBr+ 331

Lu+ 331

Lu+4 331

21
LuC2+ 331

LuC4+ 332

Hr4 332

Ta+5 332

TaF3+ 332

TaF4+ 332

Ta2 F9+ 332

Ta3 F,+4 332

TaCl2+ 332

TaCl3+ 332

TaCl4+ 332 C6H18 W+ 332 C606W+ 332 C10H5 NO5 W+ 332 Cn H7 N05 W+ 332 C12 H9N05 W+ 332

C,,H4 N205 W+ 332 C12 H36N6 P2 W+ 333 C14 H36N602 P2 W+ 333 C15 H36N603 P2W+ 333 C16H36N604 P2 W+ 333

WC1+ 333

WC12+ 333

WC13+ 333

WC14+ 333

WC15+ 333

WC16+ 333

WOCl3+ 333

WOC1+ 333

WS2 C1 + 333

WS2 C12+ 333

WSC13+ 333

WSC1+ 333

WOSCl+ 334

WOSCl2+ 334

WBr2+ 334

WBr3+ 334

WOBr+ 334

W02 Br + 334

WOBr2+ 334

W02 Br2+ 334

WOBr3+ 334

WOBr4+ 334

W02 I + 334

W02 I 2+ 334

ReO + 334

Re02+ 334

Re03+ 335

Re2 Os+ 335

Re206+ 335

Re207+ 335 C5 HOs Re+ 335

ReF6+ 335 C5 H3 Os SiRe+ 335

ReCl4+ 335

ReOzCl + 335

ReOCl3+ 335

ReOCl4+ 335 C5 H3 05GeRe+ 335

Re03 I + 335

BaRe04+ 335

C,2 H14Os+ 335

0s04+ 336

OsOCl3+ 336

OsOCl4+ 336 C7H704Ir + 336 C7 H04F6Ir + 336

Au+ 336

Au2+ 336

AuB+ 336

AuBO+ 336

AuAl+ 336

AuA12+ 337

Au2A1+ 337

AuGe+ 337

AuCe+ 337

AuHo+ 337

Hg+ 337 C12H10Hg 337

HgCl2+ 337 C3H5ClHg+ 337

Tl + 337

Tl +3 338

Tl2+ 338

T10+ 338

T120+ 338

TlBO+ 338

T1BO+ 338

T12 B02+ 338

T1F+ 338

T12F+ 338

T12F2+ 338

T1C1 + 338

TlAs+ 339

TlBr+ 339

T1I + 339

Pb+4 339 C3H9Pb+ 339 C4H12 Pb+ 339 C7HI8 Pb+ 339 C6H18 Pb2+ 339 C16H44Si4Pb + 339

PbCl2+ 340

Pbl2+ 340

Bi3+ 340

Bi4+ 340

22
BiF3+ 340

BiF4+ 340

Bi2F9+ 340

GaBi+ 340

BiTT 340

Ac+ 340

Th+ 340

ThO+ 340

Th02+ 340

ThCl4+ 340

ThPt+ 340

Pa+ 340 U+ 341 U

+2 341

UO+ 341

U02+ 341

U03+ 341

US+341

UOS+341

UC13+341

UC14+341

Np+

341

Pu+ 341

Am+ 342

Cm+ 342

Bk+ 342

Cr 342

Es+ 342

Fm+ 342

Md+ 342

No+

342

23
Table of Ion Energetics Measurements

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

H

+ H2t

2 Zg

") H 18.0±0.2

(RN-CAS Registry Number 1333-74-0)

H

+ CH4 24.0±0.5

(RN-CAS Registry Number 74-82-8)

(AD- 1.8-3. 2 eV average translational energy of decomposition at threshold)

H

+ H20 OH(X2 n) 18.7+0.05

(RN-CAS Registry Number 7732-18-5)

(ZK-Threshold value for zero kinetic energy ions)

H

+ HCHO HCO 17.41 ±0.07

(RN-CAS Registry Number 50-00-0)

(TR-Other product(s) thermochemically reasonable)

H

+ HF F 19.444

(RN-CAS Registry Number 7664-39-3)

(TV-Threshold value approximately corrected to 0°K)

El 3799

El 3521

El 3906

PI 3554

PI 3928

D+ D20 OD(X2 n)

(RN-CAS Registry Number 7789-20-0)

(ZK-Threshold value for zero kinetic energy ions)

H+ H2(RN-CAS Registry Number 1333-74-0)

H+ H2(RN-CAS Registry Number 1333-74-0)

(Rotational transitions resolved)

H2+ HCHO CO

(RN-CAS Registry Number 50-00-0)

(TR-Other product(s) thermochemically reasonable)

18.7+0.05 El 3906

15.42589+0.00005 S 3770

15.38186+0.00031 PE 3531

15.42+0.06 PI 3554

HD+ HD ** 15.44477±0.00007 S 3763

(RN-CAS Registry Number 13983-20-5)

H3+ C2H6 32.2+1 El 3904

(RN-CAS Registry Number 74-84-0)

(AD-3.93 eV average translational energy of decomposition at threshold)

H3+ C3 H8 31. 6± 1 El 3904

(RN-CAS Registry Number 74-98-6)

(AD-3.46 eV average translational energy of decomposition at threshold)

H3+ «-C4H!0 30.5+1 El 3904

(RN-CAS Registry Number 106-97-8)

(AD-3.03 eV average translational energy of decomposition at threshold)

Li + LiF

(RN-CAS Registry Number 7789-24-4) ~ 12 El 3464

Li2+Li2 (RN-CAS Registry Number 14452-59-6)

4.96+0.1 S 3768

B* B ** (RN-CAS Registry Number 24389-64-8)

8.6±0.4 El 3468

24
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

bh2+ bh3? h?

(RN-CAS Registry Number 13283-31-3)

11-12 El 3441

bh3+ BH3 ** (RN-CAS Registry Number 13283-31-3)

11-12 El 3441

b3 h+ b3 h7 (RN-CAS Registry Number 12429-70-8)

11.5+0.3 El 3652

b3h6+ b3 h7 h

(RN-CAS Registry Number 12429-70-8)

11.2+0.3 El 3652

b4h8+ B4H8 (RN-CAS Registry Number 12007-71-5)

10.9±0.3 El 3652

b5 h8+ B5 H9 H 11.84+0.01 RPD 3547

(RN-CAS Registry Number 19624-22-7)

B5H8+ 1-B5H8 CH3 CH3 10.45+0.02 RPD 3547

(RN-CAS Registry Number 19495-55-7)

b5h8+ 2-B5H8 CH3 ch3 10.61 ±0.05 RPD 3547

(RN-CAS Registry Number 23753-74-4)

b5 h8+ l-BsHgQHs C2H5 10.33+0.05 RPD 3547

(RN-CAS Registry Number 23753-61-9)

b5h8+ 2-B5 H8 C2H5 C2H5 10.3 1 ±0.01 RPD 3547

(RN-CAS Registry Number 23753-62-0)

b5h8+ 1-B5 H8 C3H7 C3 H7 10.98±0.01 RPD 3547

(RN-CAS Registry Number 34692-67-6)

b5 h8+ 1-B5 H8 C1 Cl 1 1 .75 ±0.05 RPD 3547

(RN-CAS Registry Number 19469-13-7)

B5 H8+ 2-B5 H8 Cl Cl 12.20±0.10 RPD 3547

(RN-CAS Registry Number 19469-14-8)

b5 h8+ l-B5 H8 Br Br 1 1 .38 ±0.05 RPD 3547

(RN-CAS Registry Number 23753-67-5)

b5 h8+ 2-B5 H8 Br Br 1 1 .75 ±0.05 RPD 3547

(RN-CAS Registry Number 23753-64-2)

b5 h8+ 1-B5 H8 I I 10.70±0.05 RPD 3547

(RN-CAS Registry Number 30624-33-0)

B5H8+ 2-B5 H8 I I 10.72±0.05 RPD 3547

(RN-CAS Registry Number 20199-87-5)

b5 h9+ b5 h9 (RN-CAS Registry Number 19624-22-7)

9.90 PE 3869

C

+

C

+

c

+

c

+

c ** (RN-CAS Registry Number 7440-44-0)

C ** (RN-CAS Registry Number 7440-44-0)

C ** (RN-CAS Registry Number 7440-44-0)

CH4 (RN-CAS Registry Number 74-82-8)

10.5 ± 1.0

10.8±0.4

1 1.4± 1.5

<25.2

El

El

El

DC

3597

3902

3978

3813

25
Table of Ion Energetics Measurements—-Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C

+2

(

3 P) c

+ ** (RN-CAS Registry Number 14067-05-1)

31.0 SEQ 3489

C

+2(‘P) c

+ ** (RN-CAS Registry Number 14067-05-1)

37.3 SEQ 3489

C

+3 c

+ ** (RN-CAS Registry Number 14067-05-1)

75 SEQ 3489

C

+3

(

2 P) C+2(

3 p°) ** (RN-CAS Registry Number 16092-61-8)

49.5 SEQ 3489

C

+3

(

2 P) C

+ 2 ** (RN-CAS Registry Number 16092-61-8)

55.5 SEQ 3489

C2(RN-CAS Registry Number 12070-15-4)

1 1.1± 1.0 El 3597

C3+ C3(RN-CAS Registry Number 12075-35-3)

12.1±0.2 El 3601

CH* ch4 h2 +h?

(RN-CAS Registry Number 74-82-8)

22.4 DC 3813

ch2+ ch4 h2 (RN-CAS Registry Number 74-82-8)15.3 DC 3813

ch2+ ch3 oh h2o

(RN-CAS Registry Number 67-56-1)

(TR-Other product(s) thermochemically reasonable)

14.05±0.05 PI 3554

ch2+ ch2 =cf2 cf2 (RN-CAS Registry Number 75-38-7)

16.99±0.02 PI 3930

ch2+ ch2 =cf2 cf2 (RN-CAS Registry Number 75-38-7)

17.2±0.1 El 3539

ch3+ CH3 ** (RN-CAS Registry Number 2229-07-4)

9.81 ±0.02 PE 3717

(RD-Radical)

ch3+ CH3 ** (RN-CAS Registry Number 2229-07-4)

9.837±0.005 PE 3942

(RD-Radical)

ch3+ CH3 ** (RN-CAS Registry Number 2229-07-4)

9.86±0.04 (V) PE 3695

(RD-Radical)

ch3+ CH3 ** (RN-CAS Registry Number 2229-07-4)

9.86±0.04 PE 3700

(RD-Radical)

ch3+ ch4 h

(RN-CAS Registry Number 74-82-8)

14.4 DC 3813

CH3+ CH3 C=CH C2H

(RN-CAS Registry Number 74-99-7)

(TR-Other product(s) thermochemically reasonable)

14.6±0.1 El 3769

CH3 CH3 C=CH C2 H 16.0 (RN-CAS Registry Number 74-99-7)

(AD-0.16 eV average translational energy of decomposition at threshold)

El 3808

26
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method

products potential

(eV)

CH3+ C3 H8 C2 H5+ 30.2±1 El

(RN-CAS Registry Number 74-98-6)

(AD-2.7 eV average translational energy of decomposition at threshold)

CH3+ C2H5 C=CH C3 H3 15.1 El

(RN-CAS Registry Number 107-00-6)

(AD-0.19 eV average translational energy of decomposition at threshold)

CH3+ (CH3)2 C=CH2 C3 H5 16.4 El

(RN-CAS Registry Number 115-11-7)

(AD-0.20 eV average translational energy of decomposition at threshold)

CH3+ l-C4Hg C3H5 14.1 El

(RN-CAS Registry Number 106-98-9)

(AD-0.09 eV average translational energy of decomposition at threshold)

CH3+ (CH3)3 CC=CH C5 H7 14.7 El

(RN-CAS Registry Number 917-92-0)

(AD-0. 1 1 eV average translational energy of decomposition at threshold)

CH3+ (CH3)3 CCH= CH2 C5 H9 15.4 El

(RN-CAS Registry Number 558-37-2)

(AD-0.13 eV average translational energy of decomposition at threshold)

CH3+ CH3 NH2 NH2 14.5 El

(RN-CAS Registry Number 74-89-5)

CH3+ C2H5NH2 CH2NH2 15.6 El

(RN-CAS Registry Number 75-04-7)

(AD-0.19 eV average translational energy of decomposition at threshold)

CH3+ (CH3)2NH CH3 NH 14.8 El

(RN-CAS Registry Number 124-40-3)

(AD-0.13 eV average translational energy of decomposition at threshold)

CH3+ (CH3)3N (CH3)2N 14.9 El

(RN-CAS Registry Number 75-50-3)

(AD-0. 1 1 eV average translational energy of decomposition at threshold)

CH3+ (C2H5)2NH C2H5 NHCH2 15.4 El

(RN-CAS Registry Number 109-89-7)

(AD-0.09 eV average translational energy of decomposition at threshold)

CH3+ (C2H5)3 N (C2H5)2NCH2 16.7 El

(RN-CAS Registry Number 121-44-8)

(AD-0. 1 3 eV average translational energy of decomposition at threshold)

ch3+ ch3 oh oh

(RN-CAS Registry Number 67-56-1)

(TR-Other product(s) thermochemically reasonable)

13.82±0.04 PI

ch3+ (CH3)2CO

(RN-CAS Registry Number 67-64-1)

15.2 El

ch3+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

14.6±0.3 El

ch3+ CH2(NF2)CH(NF2)CH3 (RN-CAS Registry Number 15403-25-5)

16.4±0.4 El

ch3+ (CH3)2C(NF2)2 (RN-CAS Registry Number 19309-63-8)

14.7±0.2 El

ch3+ (CH3 0)3 P0

(RN-CAS Registry Number 512-56-1)

17.90±0.40 El

ch3+ (CH3 0)2P(CH3 S)0

(RN-CAS Registry Number 152-20-5)

15.20±0.30 El

ch3+ (CH30)2P(CH3 S)S

(RN-CAS Registry Number 2953-29-9)

27

14.50±0.40 El

Ref.

3904

3808

3808

3808

3808

3808

3808

.3808

3808

3808

3808

3808

3554

3550

3634

3634

3634

3989

3989

3989
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

CHi CHJ I (RN-CAS Registry Number 74-88-4)

(TR-Other product(s) thermochemically reasonable)

CH3+ CH3 I I (RN-CAS Registry Number 74-88-4)

CH4t

2 BJ

CH4T

2 B2) CH4t

2 B2) CH4t

2A,)

ch4+

ch4 ** (RN-CAS Registry Number 74-82-8)

CH4 ** (RN-CAS Registry Number 74-82-8)

CH4 ** (RN-CAS Registry Number 74-82-8)

CH4 ** (RN-CAS Registry Number 74-82-8)

CH4 ** (RN-CAS Registry Number 74-82-8)

C,H

(RD-Radical)

C,H

(RD-Radical)

C,H

C2H ** (RN-CAS Registry Number 2122-48-7)

C2 H ** (RN-CAS Registry Number 2122-48-7)

C2 H ** (RN-CAS Registry Number 2122-48-7)

(RD-Radical)

C2 H

(TVC2H

+ c2h^

(TRC2 H2 H

(RN-CAS Registry Number 74-86-2)

Threshold value approximately corrected to 0°K)

CH=CCN CN

(RN-CAS Registry Number 1070-71-9)

chf2c=ch chf2 (RN-CAS Registry Number 18371-25-0)

Other product(s) thermochemically reasonable)

D" C2 D2 D

(RN-CAS Registry Number 1070-74-2)

(TV-Threshold value approximately corrected to 0°K)

QHjfnj

c2 h2 (RN-CAS-Registry

C2H2 (RN-CAS Registry

C2H2 (RN-CAS Registry

ch3 c=ch

(RN-CAS Registry

(TR-Other product(s) thermochemically

c2 h2+ c2 h3 f

(RN-CAS Registry

(TR-Other product(s) thermochemically

C2 H2+

c2 h2+

Number 74-86-2)

** Number 74-86-2)

** Number 74-86-2)

CH2 Number 74-99-7)

reasonable)

HF

Number 75-02-5)

reasonable)

Ionization or appearance Method Ref.

potential

(eV)

12.260±0.013 PI 3524

12.07 ±0.07 EDD 3626

12.51 PE 3645 ~ 12.51 PE 3529

12.64 PE 3716

22.39 PE 3716

12.8 DC 3813

1 1.6±0.5 El 3601

1 1.96±0.05 D 3931

1 1.96±0.05 D 3929

17.36±0.01 PI 3931

18.19±0.04 PI 3929

16. 19 ±0.02 El 3769

17.44±0.01 PI 3931

1 1.394±0.005 PI 4069

1 1.398±0.005 PI 3921

11.40 PE 4048

1 5.2 ±0.El 3769

13.51 ±0.02 PI 3930

28
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C2H2+ CH2 =CF2 2F

(RN-CAS Registry Number 75-38-7)

19.08±0.03 PI 3930

C2H2+ C2H3 C1 HC1

(RN-CAS Registry Number 75-01-4)

(TR-Other product(s) thermochemically reasonable)

12.47±0.1 PI 3930

c2D2fnj C2D2 ** (RN-CAS Registry Number 1070-74-2)

11.404±0.005 PI 3921

c2d2+ C2D6 2D2 (RN-CAS Registry Number 1632-99-1)

14.8 TPE 3919

c2h3+

(RD-Radical)

c2h3 (RN-CAS Registry Number 2669-89-8)

8.7 ±0.1 D 3930

C2H3+ c2h3 f f

(RN-CAS Registry Number 75-02-5)

13.84+0.04 PI 3930

c2h3+ c2h3ci Cl

(RN-CAS Registry Number 75-01-4)

(TR-Other product(s) thermochemically reasonable)

12.48+0.04 PI 3930

C2D3+ c2d6 d2 +d

(RN-CAS Registry Number 1632-99-1)

14.8 TPE 3919

C,H4t

2B2u) C2H4 (RN-CAS Registry Number 74-85-1)

10.51 PE 3649

c2h+ C2H4 ** (RN-CAS Registry Number 74-85-1)

10.51 PE 3739

C2H4+ C2H4 (RN-CAS Registry Number 74-85-1)

10.51 PE 3847

c2h+ C2H4 (RN-CAS Registry Number 74-85-1)

10.515±0.003 PE 3957

c2h4+ C2H4 (RN-CAS Registry Number 74-85-1)10.56 PE 3533

c2h4

-* c2h4 (RN-CAS Registry Number 74-85-1)

12.38 PE 3739

C2H4t

2 B2g) C2H4 ** (RN-CAS Registry Number 74-85-1)

12.45 PE 3649

c2H* C2H4 (RN-CAS Registry Number 74-85-1)12.56 PE 3533

C2HJ> C2H4 (RN-CAS Registry Number 74-85-1)14.4 PE 3739

C2H4fAg) C2H4 ** (RN-CAS Registry Number 74-85-1)14.43 PE 3649

c2 h^* C2H4 (RN-CAS Registry Number 74-85-1)

14.46 PE 3533

C2H4t

2 B lu) C2H4 ** (RN-CAS Registry Number 74-85-1)

15.74 PE 3649

w C2H4 ** (RN-CAS Registry Number 74-85-1)

15.96 PE 3533

C2H4fB)u) C2H4 ** (RN-CAS Registry Number 74-85-1) ~ 18.8 PE 3649

29
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other appearance Method Ref. products potential

(eV)

QH* C2 H4 ** 18.91 (RN-CAS Registry Number 74-85-1)

C2 H4fAg

) C2 H4 ** -22.8

(RN-CAS Registry Number 74-85-1)

C2 H4+ C3 H8 CH4 11.55 (RN-CAS Registry Number 74-98-6)

(PC-Appearance potential of the corresponding metastable transition)

C2H4+ C3 H8 CH4 11.9 (RN-CAS Registry Number 74-98-6)

(MT-Metastable transition(s) observed)

C2 H5+ C2 H5 Br Br 10.72±0.08 EDD 3626

(RN-CAS Registry Number 74-96-4)

C2 H6 ** 1 1.76±0.05 DC 3791

(RN-CAS Registry Number 74-84-0)

(CH3)2C(NF2)2 NF3 -(-CNF? 13.1 ±0.2 El 3634

(RN-CAS Registry Number 19309-63-8)

c3 h

+ ch3 c=ch h2 +h

(RN-CAS Registry Number 74-99-7)

14.0±0.1 El 3769

c3 h2+ ch3 c=ch h2 (RN-CAS Registry Number 74-99-7)

13.8±0.1 El 3769

C3 H3+ CH3 C=CH H 1 1.9±0.1

(RN-CAS Registry Number 74-99-7)

(TR-Other product(s) thermochemically reasonable)

C3 H3+ C2H5C=CH CH3 11.7 (RN-CAS Registry Number 107-00-6)

(AD-0.06 eV average translational energy of decomposition at threshold)

C3 H3+ C6H6 C3 H3 13.79 (Benzene)

(RN-CAS-Registry Number 71-43-2)

(Corrected for kinetic shift)

C3 H3+ (CH3)2 NCH = CHC=CH C2 H4 + HCN+ H 15.2 (RN-CAS Registry Number 2206-24-8)

(TR-Other product(s) thermochemically reasonable)

C3 H3+ (C2 H5 )2 NCH = CHC^CH 18.6 (RN-CAS Registry Number 1809-53-6)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): 2C2 H2 + HCN+ 3H2 ) c3 h+ ch3 c=ch ** 10.37 PE 4048

(RN-CAS Registry Number 74-99-7)

c3 h4+ ch3 c=ch ** 10.5 ±0.

El 3769

(RN-CAS Registry Number 74-99-7)

(TR-Other product(s) thermochemically reasonable)

C3 H4+ ch2 =c=ch2 ** 10.017±0.003 S 3774

(RN-CAS Registry Number 463-49-0)

(RS-Average of two Rydberg series limits)

El 3769

El 3808

PI 4075

El 3674

El 3674

c2h6+

c2 h6+

PE 3533

PE 3649

El 3488

El 3488

30
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance

products potential

(eV)

Method Ref.

c3 h4+ CH2 = C=CH2 ** (RN-CAS Registry Number 463-49-0)

10.07 (V) PE 4019

C3H4t

2B2) C3 H4 ** (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

9.67 PE 3727

CjH.fB.) c3 h4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

9.86 (V) PE 3505

C3 H4fBi) C3H4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

10.57 PE 3727

CjH4t

2B2) C3 H4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

11.02 (V) PE 3505

C3H4fA,) C3 H4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

12.38 PE 3727

C3H4fA,) C3H4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

12.7 (V) PE 3505

CjH^Bj) C3H4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

14.5 PE 3727

C3 H4t

2 A,) c3 h4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

16.2 PE 3727

C3 H4t

2B,) c3h4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

17.8 PE 3727

C3H4fA,) C3H4 (Cyclopropene)

(RN-CAS Registry Number 2781-85-3)

19.2 PE 3727

C3 H5+ (CH3)2C=CH2 ch3 (RN-CAS Registry Number 115-11-7)

(AD-0.05 eV average translational energy of decomposition at threshold)

11.8 El 3808

c3 h+ i-c4h8 ch3 (RN-CAS Registry Number 106-98-9)

(AD-0.07 eV average translational energy of decomposition at threshold)

11.8 El 3808

C3H5+ c4h8 ch3 (Cyclopropane, methyl-)

(RN-CAS Registry Number 594-11-6)

10.9 SD 3493

C3H+ CH=C(CH2)3 CH3 (RN-CAS Registry Number 693-02-7)

14.09±0.05 El 3585

c3 h5+ CH3 C=CCH2CH2CH3 (RN-CAS Registry Number 764-35-2)

13.9±0.01 El 3585

c3h5+ c6h10 (Cyclohexene)

(RN-CAS Registry Number 110-83-8)

13.68±0.05 El 3585

c3h+ C5H8 = CH2 (Cyclopentane, methylene-)

(RN-CAS Registry Number 1528-30-9)

31

14.05 ±0.05 El 3585
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C3 H+ c5 h7ch3 (Cyclopentene, 1 -methyl-)

(RN-CAS Registry Number 693-89-0)

14.90±0.1 El 3585

c3 h5+ (C2 H5)2 S ch3 sh + h

(RN-CAS Registry Number 352-93-2)

12.41±0.05 PI 4025

c3 h5+ c3 h6s2 s2 h

(1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

10.8±0.2 El 3598

c3 h5+ CH2 = CHCH2 CH2 Br CH2 Br

(RN-CAS Registry Number 5162-44-7)

12.6 El 3900

c3 h5+ CH2 = CH(CH2)3 Br

(RN-CAS Registry Number 1119-51-3)

12.2 El 3900

c3 h+ C6Hu Br

(Cyclohexane, bromo-)

(RN-CAS Registry Number 108-85-0)

12.52±0.05 PI 4078

C3 H6+ c3 h6 (RN-CAS Registry Number 115-07-1)

9.72 PE 3864

c3 h6+ c3 h6 (RN-CAS Registry Number 115-07-1)

9.74 PE 3533

c3 h+ c3 h6 (RN-CAS Registry Number 115-07-1

9.744±0.003 PE 3957

C3 H6+ c3 h6 (RN-CAS Registry Number 115-07-1)

9.86 (V) PE 3950

c3 h6+ c3 h6 (RN-CAS Registry Number 115-07-1)

9.9 (V) PE 3940

c3 h6+ *-c4h10 ch4 (RN-CAS Registry Number 106-97-8)

(PC-Appearance potential of the corresponding metastable transition)

11.06 El 3538

c3 h6+ «-C4H10 CH4 (RN-CAS Registry Number 106-97-8)

11.56 El 3538

(MT-Metastable transition(s) observed)

C3 H6+ (CH3)2C = CHCH2 C2H4 1 1.70±0.1 1 El 3544

(RN-CAS Registry Number 513-35-9)

(TR-Other product(s) thermochemically reasonable)

c3 h6+ ch3ch2 ch2 ch=ch2 c2 h4 (RN-CAS Registry Number 109-67-1)

(TR-Other product(s) thermochemically reasonable)

C3 H6+ (CH3)2CHCH = CH2 c2h4 (RN-CAS Registry Number 563-45-1)

(TR-Other product(s) thermochemically reasonable)

C3 H6+ C2H5 C(CH3)=CH2 c2 h4 (RN-CAS Registry Number 563-46-2)

(TR-Other product(s) thermochemically reasonable)

C3 H6+ cw-C2 H5 CH= CHCH3 c2 h4 (RN-CAS Registry Number 627-20-3)

(TR-Other product(s) thermochemically reasonable)

C3 H6+ toz«s-C2 H5 CH = CHCH3 C2 H4 (RN-CAS Registry Number 646-04-8)

(TR-Other product(s) thermochemically reasonable)

11.61 ±0.08 El 3544

1 1.54±0.10 El 3544

1 1.66±0.06 El 3544

1 1.54±0.02 El 3544

1 1 .73 ±0. 1 1 El 3544

32
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c3 h6+ c5h10 c2h4 (Cyclopentane)

(RN-CAS Registry Number 287-92-3)

(TR-Other product(s) thermochemically reasonable)

c3H6+ c6h12 c3 h6 (Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

c3h6+ «-c3h7oh h2o

(RN-CAS Registry Number 71-23-8)

c3h6+ «-c3h7oh h2o

(RN-CAS Registry Number 71-23-8)

c3h6+ c4h6o CO

(Cyclobutanone)

(RN-CAS Registry Number 1191-95-3)

(TR-Other product(s) thermochemically reasonable)

C3H6+ ko-C3H7NO HNO

(RN-CAS Registry Number 920-40-1)

C3H6f iso-C3H7NO

(RN-CAS Registry Number 920-40-1)

c3h7+

#i-c4h10 ch3 (RN-CAS Registry Number 106-97-8)

(PC-Appearance potential of the corresponding metastable transition)

c3h7+ «-c4h10 ch3 (RN-CAS Registry Number 106-97-8)

(MT-Metastable transition(s) observed)

C3H7+ c6h12 c3 h5 (Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

C3H7+zso-C3 H7C1 Cl?

(RN-CAS Registry Number 75-29-6)

C3H7+ wo-C3H7Br Br?

(RN-CAS Registry Number 75-26-3)

C3H7+

/50-C3H7I I? (RN-CAS Registry Number 75-30-9)

1 1.74±0.07 El 3544

1 1.23 ±0.04 PI 4078

10.33+0.03 EDD 3626

10.3 El 3916

9.85+0.15 EDD 3794

10.8±0.1 El 3602

10.8 ±0.

1

El 3654

11.09 El 3538

11.53 El 3538

11.49+0.03 PI 4078

11.3+ <0.1 El 3735

10.7+ <0.1 El 3735

10.0±<0.1 El 3735

C3H8+ c3h+

c3h8 ** (RN-CAS Registry Number 74-98-6)

c3h8 (RN-CAS Registry Number 74-98-6)

11.5 (V)

11.27±0.05

PE

DC

3710

3791

c4h2+ HC=CC=CH ** (RN-CAS Registry Number 460-12-8)

10.17 PE 4048

c4h3+ (CH3)2NCH=CHC^CH 14.4 El 3674

(RN-CAS Registry Number 2206-24-8)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): cyc/o-(CH2)2N+ Hj)

33
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c4h3+ c4h8 nch=chc=ch

(Pyrrolidine, 1 -( 1 -buten-3-ynyl)-)

(RN-CAS Registry Number 19352-85-3)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): cyclo-(CH1)1 N+ C2 H4)

15.2 El 3674

C4H3+ (C2 H5)2 NCH= CHC=CH

(RN-CAS Registry Number 1809-53-6)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): CH2 = NH + C2H4 + CH3)

15.0 El 3674

C4H4+ CH2 = CHC=CH ** (RN-CAS Registry Number 689-97-4)

c4h4+ ch2 =chc^ch ** (RN-CAS Registry Number 689-97-4)

c4H4+ c6h6 c2 h2 (Benzene)

(RN-CAS-Registry Number 71-43-2)

(Corrected for kinetic shift)

c4h4+ c6h6 c2h2 (Benzene)

(RN-CAS Registry Number 71-43-2)

(PC-Appearance potential of the corresponding metastable transition)

C4H4+ (CH3)2NCH= CHC=CH ch2 =nh+ch3 (RN-CAS Registry Number 2206-24-8)

(TR-Other product(s) thermochemically reasonable)

c4h4+ c4h8nch=chc=ch

(Pyrrolidine, 1 -( 1 -buten-3-ynyl)-)

(RN-CAS Registry Number 19352-85-3)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): CH2N= CH2 + C2 H2 +H)

c4h6+ ch2 =chch=ch2 ** 9.03 PE 3847

(/rans-conformer)

c4h6+

(RN-CAS Registry Number 106-99-0)

ch3 c=cch3 ** 9.59 PE 4048

c4h6+ (RN-CAS Registry Number 503-17-3)ch2 =c=chch3 ** 9.33 (V) PE 4019

c4h+

(RN-CAS Registry Number 590-19-2)

CH=C(CH2)3 CH3 c2h4

1 1.08±0.05 El 3585

c4h+

(RN-CAS Registry Number 693-02-7)

ch3c=cch2ch2ch3 c2h4

1 1.02±0.05 El 3585

c4h+

(RN-CAS Registry Number 764-35-2)

c6h10 c2h4 11.91 ±0.05 El 3585

c4h+

(Cyclohexene)

(RN-CAS Registry Number 110-83-8)

c5 h8 =ch2 c2h4 12.32±0.05 El 3585

c4h6+

(Cyclopentane, methylene-)

(RN-CAS Registry Number 1528-30-9)

c5 h7ch3 c2 h4 12.33±0.05 El 3585

(Cyclopentene, 1 -methyl-)

(RN-CAS Registry Number 693-89-0)

9.63 PE 3997

9.9 El 3767

13.85 PI 4075

14.1 El 3488

13.4 El 3674

13.7 El 3674

34
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

C4H6+ C6HhC1

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

c4h7+ ch3 ch2ch2ch=ch2 ch3 (RN-CAS Registry Number 109-67-1)

(TR-Other product(s) thermochemically reasonable)

c4h7+ (CH3)2C=CHCH3 ch3 (RN-CAS Registry Number 513-35-9)

(TR-Other product(s) thermochemically reasonable)

c4h7+ (CH3)2CHCH=CH2 ch3 (RN-CAS Registry Number 563-45-1)

(TR-Other product(s) thermochemically reasonable)

C4H7+ C2H5C(CH3) = CH2 ch3 (RN-CAS Registry Number 563-46-2)

(TR-Other product(s) thermochemically reasonable)

C4H7+ m-C2H5CH=CHCH3 CH3 (RN-CAS Registry Number 627-20-3)

(TR-Other product(s) thermochemically reasonable)

C4H7+ tra«5-C2H5CH=CHCH3 CH3 (RN-CAS Registry Number 646-04-8)

(TR-Other product(s) thermochemically reasonable)

c4h7+ c5h10 ch3 (Cyclopentane)

(RN-CAS Registry Number 287- 92-3)

(TR-Other product(s) thermochemically reasonable)

c4H7+ c6h12 c2h5 (Cyclohexane)

(RN-CAS Registry Number 110-82-7)

c4h,+ c6h,,ci

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

C4H7+ CH2 =CHCH2CH2Br Br

(RN-CAS Registry Number 5162-44-7)

C4H7+ C6HnBr

(Cyclohexane, bromo-)

(RN-CAS Registry Number 108-85-0)

Ionization or appearance

potential

(eV)

Method Ref.

11.07±0.03 PI 4078

11.35±0.07 El 3544

11.33±0.12 El 3544

11.15±0.12 El 3544

11.34±0.07 El 3544

11.24±0.02 El 3544

11.35±0.03 El 3544

11.36±0.08 El 3544

11.21 ±0.04 PI 4078

11.52±0.05 PI 4078

10.6 El 3900

11.54+0.02 PI 4078

C4H8+ 1-C4H8 ** 9.72 (V) PE 3950

(RN-CAS Registry Number 106-98-9)

C4H8+ i-c4h8 ** 9.625+0.003 PE 3957

(RN-CAS Registry Number 106-98-9)

c4h8+

zso-C4H8 ** 9.21 PE 3533

(RN-CAS Registry Number 115-11-7)

c4h8+ wo-C4H8 ** 9.239±0.003 PE 3957

(RN-CAS Registry Number 115-11-7)

c4h8+ m-2-C4H8 ** 9.07 PE 3533

(RN-CAS Registry Number 590-18-1)

c4h8+

cis-2-C4H8 ** 9.124+0.005 PE 3957

c4h8+ (RN-CAS Registry Number 590-18-1)

m-2-C4H8 ** 9.29 (V) PE 4084

(RN-CAS Registry Number 590-18-1)

35
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C4H8+ fra/j$-2-C4H8 ** (RN-CAS Registry Number 624-64-6)

9.11 (V) PE 3649

c4h8+

trans-2-C4H8 ** (RN-CAS Registry Number 624-64-6)

9.09 PE 3533

c4 h8+

trans-2-C4H8 ** (RN-CAS Registry Number 624-64-6)

9.122±0.005 PE 3957

c4h8+ trans-2-C4H8 ** (RN-CAS Registry Number 624-64-6)

9.32 (V) PE 4084

c4h8+ c4h8 (Cyclobutane)

(RN-CAS Registry Number 287-23-0)

9.92±0.05 PE 3757

c4h8+ c4h8 (Cyclobutane)

(RN-CAS Registry Number 287-23-0)

10.7±0.1 (V) PE 4037

c4h8+ C4H8 (Cyclopropane, methyl-)

(RN-CAS Registry Number 594-11-6)

9.9±0.2 SD 3493

c4h+ c6hI2 c2h4 (Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

11.08±0.01 PI 4078

c4h8+ c6Hu

ci

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

10.2±0.01 PI 4078

c4h+ tert-C4H9NO NO

(RN-CAS Registry Number 917-95-3)

8.9±0.1 El 3602

c4h9+

tert-C4H9NO

(RN-CAS Registry Number 917-95-3)

8.9±0.1 El 3654

c4h9+ c6Hn

ci

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

10.56±0.02 PI 4078

c4h9+ (CH3 )3 CGe(CH3)3 (CH3)3Ge

(RN-CAS Registry Number 1184-91-4)

10.19±0.27 El 3548

c4h9+ (CH3)3 CSn(CH3)3 (CH3)3 Sn

(RN-CAS Registry Number 3531-47-3)

10.03±0.23 El 3548

c4h9+ (CH3)3 CPb(CH3)3 (CH3)3 Pb

(RN-CAS Registry Number 32997-03-8)

9.45 ±0.1

5

El 3548

C4H,+

o *-C4H10 (RN-CAS Registry Number 106-97-8)

10.87±0.05 DC 3791

C4 H+o «-C4H10 (RN-CAS Registry Number 106-97-8)

10.89 El 3538

C4H,+

o «o-C4H10 ** (RN-CAS Registry Number 75-28-5)

1 1.4 (V) PE 3710

C4Hjo /5O-C4H10 ** (RN-CAS Registry Number 75-28-5)10.74±0.05 DC 3791

c5 h4+ ch3 c=cc=ch ** (RN-CAS Registry Number 4911-55-1)

9.51 PE 4048

36
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c5h+ QH4CICH3 (Benzene, l-chloro-2-methyl-)

(RN-CAS Registry Number 95-49-8)

15.67±0.015 El 3777

c5h+ c^acHi

(Benzene, l-chloro-3-methyl-)

(RN-CAS Registry Number 108-41-8)

15.71±0.15 El 3777

c5h+ C^ClCUj

(Benzene, l-chloro-4-methyl-)

(RN-CAS Registry Number 106-43-4)

15.66±0.15 El 3777

c5h5+ C6H4BrCH3 (Benzene, l-bromo-2-methyl-)

(RN-CAS Registry Number 95-46-5)

15. 19±0. 15 El 3777

c5h5+ QH.BrCHa

(Benzene, l-bromo-3-methyl-)

(RN-CAS Registry Number 591-17-3)

15.20±0.15 El 3777

c5h5+ C6H4BrCH3 (Benzene, 1 -bromo-4—methyl-)

(RN-CAS Registry Number 106-38-7)

15.23±0.15 El 3777

c5h+ QHJCH,

(Benzene, l-iodo-2-methyl-)

(RN-CAS Registry Number 615-37-2)

14.34+0.15 El 3777

c5h5+ QHJCH,

(Benzene, l-iodo-3-methyl-)

(RN-CAS Registry Number 625-95-6)

14.47±0.15 El 3777

c5h5+ C^ICHa

(Benzene, l-iodo-4-methyl-)

(RN-CAS Registry Number 624-31-7)

14.66+0.15 El 3777

c5h6+ CH2 =C(CH3)C=CH ** (RN-CAS Registry Number 78-80-8)

10.1 El 3767

C5H+ CH2 =CHC=CCH3 ** (RN-CAS Registry Number 646-05-9)

9.4 El 3767

C5H6+ CH3CH=CHC=CH ** (RN-CAS Registry Number 2206-23-7)

8.5 El 3767

C5H6+ c5h6 (Cyclopentadiene)

(RN-CAS Registry Number 26912-33-4)

8.56±0.01 EM 3535

C5H6+ c5h6

( 1

, 3-Cyclopentadiene)

(RN-CAS Registry Number 542-92-7)

9.0 El 3476

c5h6+ C3H5C=CH ** (Cyclopropane, ethynyl-)

(RN-CAS Registry Number 6746-94-7)

9.58 (V) PE 3997

C5H6 OjHjq c2h4 (Bicyclo[2.2. l]hept-2-ene)

(RN-CAS Registry Number 498-66-8)

(ON-Other name: 2-Norbomene)

(MT-Metastable transition(s) observed)

9.22±0.01 EM 3535

37
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

9.44±0.01 EM 3535

12.13±0.06 EDD 3784

12.04± <0.1 El 3735

12.45±0.1 El 3817

12.18±0.1 El 3817

10.0 El 3900

10.0 El 3900

10.87±0.05 El 3585

10.63±0.05 El 3585

1 1.22±0.05 El 3585

11.71 ±0.05 El 3585

1 1.59±0.05 El 3585

10.0±0.1

7aa)-) PI 3918

< 10.2 ±0.

PI 3918

C27 HiA4

(MT

' 5h6+

(MT

c5 h6+

' 5 n6

' 5 n6

' 5 n6

c7 H10 (Tricyclo[2.2. 1 .0

2,6 ]heptane

(RN-CAS Registry Number 279-19-6)

(ON-Other name: Nortricyclene)

-Metastable transition(s) observed)

c6h5 nh2 hcn

(Benzenamine)

(RN-CAS Registry Number 62-53-3)

-Metastable transition(s) observed)

c6h5 nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

C6H5OH CO

(Phenol)

(RN-CAS Registry Number 108-95-2)

c6h5 sh cs

(Benzenethiol)

(RN-CAS Registry Number 108-98-5)

C^Br C2 H3 Br

(bicyclo[2.2.1]hept-2-ene, 5-bromo-, exo-)

(RN-CAS Registry Number 5810-82-2)

CyHgBr C2 H3 Br

(Bicyclo[2.2. l]hept-2-ene, 5-bromo-,endo-)

(RN-CAS Registry Number 5810-82-2)

'-'5r*7 c5 h7+

(MTC5 H7+

CH^C^H^CHa CH3 (RN-CAS Registry Number 693-02-7)

ch3 c=cch2ch2ch3 ch3 (RN-CAS Registry Number 764-35-2)

-Metastable transition(s) observed)

C6Hio CH3 (Cyclohexene)

(RN-CAS Registry Number 1 10-83-8)

(MT-Metastable transition(s) observed)

c5 h7+ c5 h8 =ch2 ch3 (Cyclopentane, methylene-)

(RN-CAS Registry Number 1528-30-9)

(MT-Metastable transition(s) observed)

c5 h7+ c5 h7ch3 ch3 (Cyclopentene, 1 -methyl-)

(RN-CAS Registry Number 693-89-0)

(MT-Metastable transition(s) observed)

c5H7+ c10h)6

c5 h7+

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: ex:o-Tricyclo[5.2.1.02 ’ 6]decane)

C,oH 15 CH3 (RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-ex0-tricyclo[5.2.1.O2,6]decane)

38
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

C5H7+

c5h7+

c5h7+

c5h7+

c10h15 ch3 >10.2±0.1 pi

(4,7-Methano-li/-indene, octahydro-2-methyl, (2a,3a/3,4a,7a,7a/3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: as-4-Methyl-£xo-tricyclo[5.2.1.02’ 6]decane)

C10H15 CH3 >10.5±0.1 PI

(4,7-Methano-li/-indene, octahydro-8-methyl-, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: a«r/-10-Methyl-e«fifo-tricyclo[5.2.1.02’ 6]decane)

CjoHjsQHs > 10.2+0.1 PI

(4,7-Methano-li/-indene, 5-ethyloctahydro-, (3aa,4/3,5a,7/3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e«rfo-8-Ethyl-exo-tricyclo[5.2.1.02,6]decane)

C6HnCl 10.67+0.05 PI

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

3918

3918

3918

4078

C5H8+ c5h8+ c5h8+ c5h8+ c5h8+ c5h8+ c5h8+

C5 H,t

2A')

C5 H8t

2A)

C5 H,fA

- )

CH2 =C(CH3)CH=CH2 ** (RN-CAS Registry Number 78-79-5)

CH2 =C(CH3)CH + CH2 ** (RN-CAS Registry Number 78-79-5)

ch2 =chch2ch=ch2 ** (RN-CAS Registry Number 591-93-5)

ch3ch=c=chch3 ** (RN-CAS Registry Number 591-96-8)

(CH3)2C=C=CH2 ** (RN-CAS Registry Number 598-25-4)

trans-CH2 =CHCH=CHCH3 ** (RN-CAS Registry Number 2004-70-8)

C5 H8 (Cyclopropane, ethenyl-)

(RN-CAS Registry Number 693-86-7)

QHsQH,

(Cyclopropane, ethenyl-)

(RN-CAS Registry Number 693-86-7)

c3h5 c2h3 (Cyclopropane, ethenyl-)

(RN-CAS Registry Number 693-86-7)

QHsQH,

(Cyclopropane, ethenyl-)

(RN-CAS Registry Number 693-86-7)

8.89 PE 3847

9.04 (V) PE 3892

9.62±0.02 PE 4010

9.13 (V) PE 4019

8.95 (V) PE 4019

8.61 PE 3847

9.1 (V) PE 4034

9.2 PE 3576

10.7 PE 3576

11.7 PE 3576

c5h9+

C5H+

c5h9+

C6H12 CH3

1 1.07±0.04 PI

(Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

C10H16 10.5 ±0. 1 PI (4,7-Methano-l#-indene, octahydro-, (3aa,4/3,7/3,7aa)-)

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: exo-Tricyclo[5.2.1.02,6]decane)

C6HuC1 11.01+0.02 PI (Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

4078

3918

4078

39
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C5 H9+ CH2 = CH(CH2)3 Br Br

(RN-CAS Registry Number 1119-51-3)

10.2 El 3900

C5 H,+

o (CH3 )2C = CHCH3 ** (RN-CAS Registry Number 513-35-9)

8.682±0.003 PE 3957

C5 H,+

o (CH3)2 C = CHCH3 ** (RN-CAS Registry Number 513-35-9)

8.72 PE 3533

C5 H,+

o (CH3)2 C = CHCH3 ** (RN-CAS Registry Number 513-35-9)

8.83 ±0. 1

El 3544

C5 H,+

o (CH3)2CHCH= CH2 ** (RN-CAS Registry Number 563-45-1)

9.533±0.003 PE 3957

C5 H,+

o (CH3)2 CHCH = CH2 ** (RN-CAS Registry Number 563-45-1)

9.60±0.03 El 3544

QHJq C2 H5 C(CH3)=CH2 ** (RN-CAS Registry Number 563-46-2)

9.148±0.003 PE 3957

CsH.+o C5 H+

c5 Hr0

C2 H5 C(CH3)=CH2 ** (RN-CAS Registry Number 563-46-2)

1-C5 H10 (RN-CAS Registry Number 109-67-1)

1-C5 H10 (RN-CAS Registry Number 109-67-1)

9.35±0.08

9.54±0.02 (V) PE

9.82±0.06 El

El

4010

3544

3544

C5H,+

0 C5 H,+

o

1-C5 H10 (RN-CAS Registry Number 109-67-1)

cis-2-C5 H10 ** (RN-CAS Registry Number 627-20-3)

9.524±0.003

9.23±0.02 El

PE

3544

3957

C5 H,+

o C5 H,+

o

cis-2-CsH10 ** (RN-CAS Registry Number 627-20-3)

rra/js-2-C5 H10 ** (RN-CAS Registry Number 646-04-8)

9.036±0.005

9.32±0.03 El

PE

3544

3957

QHjo trans-2-C5 H10 ** (RN-CAS Registry Number 646-04-8)

9.036±0.005 PE 3957

C5 H,+

0 C5 H10 (Cyclopentane)

(RN-CAS-Registry Number 287-92-3)

10.40 PE 4056

C5 H,+

o C5 H10 (Cyclopentane)

(RN-CAS Registry Number 287-92-3)

10.91 ±0.07 El 3544

c5h+ terr-C5 Hn NO NO

(RN-CAS Registry Number 34946-78-6)

8.7 ±0.1 El 3602

c5h,+

1 terf-C5 Hn NO

(RN-CAS Registry Number 34946-78-6)

8.7±0.1 El 3654

C5 H,+

2 n-C5 H12 ** (RN-CAS-Registry Number 109-66-0)

10.36 PE 4056

c5 h,+

2 n-C5 H12 ** (RN-CAS Registry Number 109-66-0)

10.59±0.05 DC 3791

c5 h,+

2 zso-C5 H12 ** (RN-CAS Registry Number 78-78-4)

10.50±0.05 DC 3791

C5 H,+

2 neo-C5 H12 ** 10.25±0.1 PE 3677

(RN-CAS Registry Number 463-82-1)

40
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

C5 H,+

2 neo-C5 H12 ** 10.21 ±0.04 PE 3880

(RN-CAS Registry Number 463 -82-1)

C5 H,+

2 neo-C5H12 ** 11.3 (V) PE 3710

(RN-CAS Registry Number 463 -82-1)

c5h+ neo-C5 H12 ** ~ 11.3 (V) PE 4050

(RN-CAS Registry Number 463-82-1)

(JC-Mean value of Jahn-Teller components)

C6H2+ HC^CC^CC^CH ** 9.50 PE 4048

(RN-CAS Registry Number 3161-99-7)

c6h4+ c6h4

( 1

, 3-Cyclohexadien-5-yne)

(RN-CAS Registry Number 462-80-6)

c6h4+ c6h6 h2 (Benzene)

(RN-CAS-Registry Number 71-43-2)

(Corrected for kinetic shift) c6h4+ c6h6 h2 (Benzene)

(RN-CAS Registry Number 71-43-2)

(MT-Metastable transition(s) observed)

c6h4+ c6h5 cn hcn

(Benzonitrile)

(RN-CAS Registry Number 100-47-0)

(MT-Metastable transition(s) observed)

c6h+ c6h5 cn

(Benzonitrile)

(RN-CAS Registry Number 100-47-0)

c6h5+ c6h5 (Phenyl)

(RN-CAS Registry Number 2396-01-2)

(RD-Radical)

c6h5+ ch=cch2ch2c=ch h

(RN-CAS Registry Number 628-16-0)

c6H5+ c6h6 h

(Benzene)

(RN-CAS-Registry Number 71-43-2)

(Corrected for kinetic shift) c6H+ c6h6 h

(Benzene)

(RN-CAS Registry Number 71-43-2)

c6H5+ c6h6 h

(Benzene)

(RN-CAS Registry Number 71-43-2)

c6h5+ c6h5 cho co+h

(Benzaldehyde)

(RN-CAS Registry Number 100-52-7)

(TR-Other product(s) thermochemically reasonable)

9.75±0.2 RPD 3583

12.94 PI 4075

14.04 ±0.06 EDD 3784

13.80±0.06 EDD 3784

13.92± <0.1 El 3735

8.1 ±0.1 PI 3752

10.21±0.03 El 3790

12.94 PI 4075

13.97±0.06 EDD 3784

14.05± <0.1 El 3735

14.11 El 3792

41
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other appearance Method

products potential

(eV)

C6H5+ C6H5 COCH3 CO4-CH3 13.28 EDD

(Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

(TR-Other product(s) thermochemically reasonable)

C6H5+ C6H5 COCH3 CO + CH3 13.97 El

(Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

(TR-Other product(s) thermochemically reasonable)

C6H5+ (C6H5)2 CO C6H5 +CO 15.67 El

(Methanone, diphenyl-)

(RN-CAS Registry Number 119-61-9)

(TR-Other product(s) thermochemically reasonable)

C6H5+ C6H5 COOH CO + OH 15.08 ±0.2 El

(Benzoic acid)

(RN-CAS Registry Number 65-85-0)

(MT-Metastable transition(s) observed)

C6H5+ QH5COOH CO+ OH 15.08 El

(Benzoic acid)

(RN-CAS Registry Number 65-85-0)

(TR-Other product(s) thermochemically reasonable)

C6H5+ C6H5 COOCH3 CH3 0 + CO 13.82 EDD

(Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

(TR-Other product(s) thermochemically reasonable)

C6H5+ C6H5 COOCH3 CH3 0+ CO 14.74 El

(Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

(TR-Other product(s) thermochemically reasonable)

C6H5+ C6H5 NO NO 11.0±0.1 El

(Benzene, nitroso-)

(RN-CAS Registry Number 586-96-9)

C6H5+ C6H5 NO 11.0±0.1 El

(Benzene, nitroso-)

(RN-CAS Registry Number 586-96-9)

C6H5+ C6H5 CONH2 NH2 + CO 14.21 El

(Benzamide)

(RN-CAS Registry Number 55-21-0)

(TR-Other product(s) thermochemically reasonable)

qh5+ c6h5 no2 no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

C6H5+ C6 H5C1 Cl

(Benzene, chloro-)

(RN-CAS Registry Number 108-90-7)

C6H5+ C6H5 COCl Cl + CO

(Benzoyl chloride)

(RN-CAS Registry Number 98-88-4)

(TR-Other product(s) thermochemically reasonable)

C6H5+ C6H5 Br Br

(Benzene, bromo-)

(RN-CAS Registry Number 108-86-1)

1 1 .93 ±0. 1 El

12.81 EDD

13.81 El

11.82 EDD

Ref.

3626

3792

3792

3973

3792

3626

3792

3602

3654

3792

3447

3626

3792

3626

42
Table of Ion Energetics Measurements—Continued

Ion

c6Hs+

c6h3 d2+

c„h6+

c6h+

C6H6+

C6H6fEl8)

C6H4+

C„H6t

2Ele)

C«H6t

2Elg)

C6H6+

c6h6+

C6H6fElg)

C6H6fEls)

C6H6fE2g)

C6H6t

2 A2u)

CsH.fE.J

C6H6fB2u)

Reactant Other

products

C6H5 I I (Benzene, iodo-)

(RN-CAS Registry Number 591-50-4)

cd^cch2 ch2c=cd h

(RN-CAS Registry Number XXXXX-XX-X)

ch=cch2ch2c=ch ** (RN-CAS Registry Number 628-16-0)

ch3 c=cc=cch3 ** (RN-CAS Registry Number 2809-69-0)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C H ** (Benzene)

(RN-CAS Registry Number 71-43-2)

c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

C6H6 (Benzene)

(RN-CAS Registry Number 71-43-2)

Ionization or appearance Method Ref.

potential

(eV)

11.34 EDD 3626

10.18±0.03 El 3790

9.87±0.03 El 3790

8.91 PE 4048

9.2 PI 3586

9.2 (V) PE 3528

9.24 PE 3519

9.24

(V) PE 3513

9.24

(V) PE 3673

9.24 (V) PE 3898

9.25±0.03 (V) PE 3713

9.25 PE 3520

9.27 PE 3658

11.7 (V) PE 3673

12.35 (V) PE 3673

13.9 (V) PE 3673

14.7 (V) PE 3673

43
Table of Ion Energetics Measurements-—Continued

Ionization or

Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C6H6fB,„) c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

15.4 (V) PE 3673

C6H6fA,g

) c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

16.84 (V) PE 3673

C„H6t

2 E2g) c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

19.0 (V) PE 3673

C6H6+ c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

9.20±0.1 EDD 3624

C6H6+ c6h6 (Benzene)

(RN-CAS Registry Number 71-43-2)

9.25 CTS 3922

C6H+ C8 H8 (Pentacyclo[4.2.0.02 5 .0

3,8 .0

4,7 ]octane)

(RN-CAS Registry Number 277-10-1)

9.2± <0.1 El 3735

C6H6+ c6h5 och3 ch2 o

(Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

1 1.27±0.1 El 3446

c6h6+ c6h5 och3 hcho

(Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

(CD-Metastable transition indicates 0.32 eV kinetic energy release)

11.50 El 3845

c6h+ C6H5 OCH3 (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

1 1 .55 ±<0.1 El 3735

C6H6+ C6H6Cr(CO)3 (Chromium, (Tj

6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

9.49±0.1 El 3788

c6h4d2+ cd=cch2ch2c=cd ** (RN-CAS Registry Number XXXXX-XX-X)9.97±0.06 El 3790

c6h7+ c7h10 ch3 (Bicyclo[2.2. 1 ]hept-2-ene)

(RN-CAS Registry Number 498-66-8)

(ON-Other name: 2-Norbornene)

(MT-Metastable transition(s) observed)

10.46±0.01 EM 3535

QH+ qh.o ch3 (Tricyclo[2.2.1.02,6]heptane

(RN-CAS Registry Number 279-19-6)

(ON-Other name: Nortricyclene)

(MT-Metastable transition(s) observed)

10.17±0.01 EM 3535

c6h8+ c/5-CH2 =CHCH = CHCH = CH2 ** (RN-CAS Registry Number 2612-46-6)

8.32 PE 3847

c6 h8+ trans-CH2 = CHCH = CHCH = Clf2* 8.29 PE 3847

(RN-CAS Registry Number 821-07-8)

44
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c6h8+ c4h7c=ch ** (Cyclobutane, ethynyl-)

(RN-CAS Registry Number 50786-62-4)

10.02 (V) PE 3997

c6h8+ c5 h5 ch3 ** (1,3-Cyclopentadiene, methyl-)

(RN-CAS Registry Number 26519-91-5)

8.28±0.05 (V) PE 3688

c6h8+ C10H16 9.9±0.1

(4,7-Methano-l/7-indene, octahydro-, (3aa,4y3,7/3,7aa)-)

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: exo-Tricyclo[5.2.1.02,6]decane)

PI 3918

C6H9+ c6h9+

c6h9+

c6h9+

c6h9+

c6h9+

c6h9+

c6h9+

CH=C(CH2)3 CH3 (RN-CAS Registry Number

ch3 c=cch2 ch2ch3 (RN-CAS Registry Number

C6H10 (Cyclohexene)

(RN-CAS Registry Number

c5 h8 =ch2 (Cyclopentane, methylene-)

(RN-CAS Registry Number

c5 h7 ch3 (Cyclopentene, 1 -methyl-)

(RN-CAS Registry Number

c10h15 ch3 (4,7-Methano-l/f-indene, octahydro-8-methyl, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: a«?/-10-Methyl-e«Jo-tricyclo[5.2. 1.0

2,6]decane)

C10H15 C2H5 <10.2±0.1

(4,7-Methano-l//-indene, 5-ethyloctahydro-, (3aa,4/3,5a,7j3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e«c?o-8-Ethyl-ex:o-tricyclo[5.2.1.02’ 6]decane)

C6Hu C1 10.40±0.02

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

H 10.75±0.05 El 3585

693-02-7)

H 10.81±0.05 El 3585

764-35-2)

H 1 1.8±0.05 El 3585

110-83-8)

H 12.13+0.05 El 3585

1528-30-9)

H 1 1.97+0.05 El 3585

693-89-0)

9.5 ±0.

1

PI 3918

PI

PI

3918

4078

C6H

c6h

c6h

c6h

c6h

c6h

c6h

c6h

+

10+

10+

10+

10+

10+

10+

10+

10

CH2 = C(CH3)C(CH3) = CH2 ** (RN-CAS Registry Number 513-81-5)

8.62 PE 3847

CH2 = C(CH3)C(CH3 ) = CH2 ** (RN-CAS Registry Number 513-81-5)

8.76 (V) PE 3892

ch2 =chch2 ch2ch=ch2 ** (RN-CAS Registry Number 592-42-7)

9. 59 ±0.02 (V) PE 4010

CH=C(CH2)3CH3 ** (RN-CAS Registry Number 693-02-7)

10.52+0.05 El 3585

ch3 c=cch2ch2ch3 ** (RN-CAS Registry Number 764-35-2)

9.97+0.05 El 3585

(CH3)2C= C= CHCH3 ** (RN-CAS Registry Number 3043-33-2)

8.69 (V) PE 4019

trans^rans-Cm^CYi =CHCH=CHCH3 (RN-CAS Registry Number 5194-51-4)

8.09 PE 3847

transJrans-CHiCH = CHCH= CHCH3 (RN-CAS Registry Number 5194-51-4)

8.93 (V) PE 3892

45
Table of Ion Energetics Measurements-—Continued

Ionization or Ion Reactant Other

products

appearance Method

potential

(eV)

Ref.

C6H,+

0 c6h10 (Cyclohexene)

(RN-CAS Registry Number 110-83-8)

9.57±0.05 El 3585

QH+o c5 h8 =ch2 (Cyclopentane, methylene-)

(RN-CAS Registry Number 1528-30-9)

8.55±0.01 PI 3585

C6H,+

o c5 h8 =ch2 (Cyclopentane, methylene-)

(RN-CAS Registry Number 1528-30-9)

9.26±0.05 El 3585

C6H,+

o c5 h7ch3 ** (Cyclopentene, 1 -methyl-)

(RN-CAS Registry Number 693-89-0)

8.55±0.01 PI 3585

QHfo c5 h7ch3 ** (Cyclopentene, 1 -methyl-)

(RN-CAS Registry Number 693-89-0)

9.12±0.05 El 3585

C6H,+

0 C6H10(CH3)2 2CH3 (Cyclohexane, 1,2-dimethyl-, cis-)

(RN-CAS Registry Number 2207-01-4)

10.46±0.1 EDD 3581

C6H,+

o C6H10(CH3)2 2CH3 (Cyclohexane, 1,2-dimethyl-, trans-)

(RN-CAS Registry Number 6876-23-9)

10.63 ±0.

EDD 3581

c6h; CIOH15 CH3 (RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-exo-tricyclo[5.2.1.0'

9.8±0.1

’ ,6]decane)

PI 3918

QH+ C10H15 CH3 10.0±0.1

(4,7-Methano- li/-indene, octahydro-2-methyl-, (2a,3a/3,4a,7a,7a/3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: cw-4-Methyl-e*0-tricyclo[5.2.1.O2 ’ 6]decane)

PI 3918

c6h+ c6hu ci

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

10. 10±0.05 PI 4078

C6HJ\ c6H12 h

(Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

1 1.32±0.05 PI 4078

C6Hn C6HuC1

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

10.20±0.05 PI 4078

C6H/i C6Hu Br

(Cyclohexane, bromo-)

(RN-CAS Registry Number 108-85-0)

9.85±0.05 PI 4078

C6H,+

2 (CH3)3 CCH = CH2 ** (RN-CAS Registry Number 558-37-2)

9.450±0.005 PE 3957

c6h,+

2 (CH3)3 CCH = CH2 ** (RN-CAS Registry Number 558-37-2)

9.7 (V) PE 3940

QH+ (CH3)2CHC(CH3) = CH2 ** (RN-CAS Registry Number 563-78-0)

9.072±0.005 PE 3957

C6Hf2 (CH3)2C = C(CH3)2 (RN-CAS Registry Number 563-79-1)

8.26 PE 3533

QH+ (CH3)2C=C(CH3)2 8.271 ±0.005 PE 3957

(RN-CAS Registry Number 563-79-1)

46
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

c6h+ (CH3)2 CHCH2CH=CH2 ** 9.452±0.003 PE 3957

(RN-CAS Registry Number 691-37-2)

QHfi (C2H5)2 C= CH2 9.061 ±0.005 PE 3957

(RN-CAS Registry Number 760-21-4)

c6Hr2 C2H5 CH2C(CH3) = CH2 ** 9.076±0.005 PE 3957

(RN-CAS Registry Number 763-29-1)

QH+ i-c6h12 (RN-CAS Registry Number 592-41-6)

9.31 PE 4033

c6h+ 1-C6H12 (RN-CAS Registry Number 592-41-6)

9.478±0.003 PE 3957

c6h+ i-c6h12 (RN-CAS Registry Number 592-41-6)

9.33 EDD 4033

C6H+ cMCH3)2CHCH=CHCH3 ** 8.976+0.005 PE 3957

(RN-CAS Registry Number 691-38-3)

c6h+ cw-2-C6H12 ** 8.969±0.005 PE 3957

(RN-CAS Registry Number 7688-21-3)

c6h,+

2 cw-3-C6H12 ** 8.954+0.005 PE 3957

(RN-CAS Registry Number 7642-09-3)

QH+ rra/w-(CH3)2CHCH- CHCH3 * * 8.972+0.005 PE 3957

(RN-CAS Registry Number 674-76-0)

c6at2 trans-2-C6H12 ** (RN-CAS Registry Number 4050-45-7)

8.966+0.005 PE 3957

QH+ trans-3-C6H. n

** 8.965+0.005 PE 3957

(RN-CAS Registry Number 13269-52-8)

c6h+ ru **

'~6rl 12 9.88±0.01 S 3757

(Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

QH+ p TT ** 9.88±0.01 PI 4078

(Cyclohexane)

(RN-CAS Registry Number 110-82-7)

c6h+ c H ** 9.87 PE 4056

(Cyclohexane)

(RN-CAS-Registry Number 110-82-7)

QH+ rL w **

6n12 10.3 (V) PE 3997

(Cyclohexane)

(RN-CAS Registry Number 1 10-82-7)

c6d+ c6d12 9.91+0.01 S 3757

(Cyclohexane-<712) (RN-CAS Registry Number 1735-17-7)

C6H+ n~C6H14 10.22 PE 4056

(RN-CAS-Registry Number 1 10-54-3)

C7H6+ C7 H6 8.82 (V) PE 4063

(Bicyclo[4.1.0]hepta-l,3,5-triene)

(RN-CAS-Registry Number 4646-69-9)

c7h7+ C7H7 ** 6.74±0.05 El 3789

(2,4,6-Cycloheptatrien- 1 -yl)

(RN-CAS Registry Number 3551-27-7)

(RD-Radical)

47
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c7h7+ (C6H5 )2CH2 c6 h5 (Benzene, l,l'-methylenebis-)

(RN-CAS Registry Number 101-81-5)

1 1.5±0.1 El 3807

c7 h7+ C6H3 (CH3)2CHO

(Benzaldehyde, 2,4-dimethyl-)

(RN-CAS Registry Number 15764-16-6)

11.2 El 4051

c7h7+ C6H3 (CH3)2 CHO

(Benzaldehyde, 2,5-dimethyl-)

(RN-CAS Registry Number 5779-94-2)

11.2 El 4051

c7 h7+ C6 H3(CH3)2CHO

(Benzaldehyde, 3,4-dimethyl-)

(RN-CAS Registry Number 5973-71-7)

11.1 El 4051

C7H7+ C6H4(CH3 )COOH cooh

(Benzoic acid, 3-methyl-)

(RN-CAS Registry Number 99-04-7)

(MT-Metastable transition(s) observed)

12.48±0.2 El 3973

C7 H7+ C6H4(CH3 )COOH cooh

(Benzoic acid, 4-methyl-)

(RN-CAS Registry Number 99-94-5)

(MT-Metastable transition(s) observed)

1 2.55 ±0.2 El 3973

QH+ C6H5 CH2CH2 OCOCH3 (Acetic acid, 2-phenylethyl ester)

(RN-CAS Registry Number 103-45-7)

12.50 El 3590

c7h7+ C6H4(N02)CH3 no2 (Benzene, l-methyl-3-nitro-)

(RN-CAS Registry Number 99-08-1)

11.58±0.1 El 3447

QH+ C6H4(N02)CH3 no2 (Benzene, l-methyl-4-nitro-)

(RN-CAS Registry Number 99-99-0)

1 1.80±0.1 El 3447

C7H7+ C6H4C1CH3 (Benzene, l-chloro-2-methyl-)

(RN-CAS Registry Number 95-49-8)

11.21±0.1 El 3777

c7h7+ C6H4C1CH3 (Benzene, l-chloro-3-methyl-)

(RN-CAS Registry Number 108-41-8)

1 1.34±0.

El 3777

c7h+ C6H4C1CH3 (Benzene, l-chloro-4-methyl-)

(RN-CAS Registry Number 106-43-4)

1 1.42±0.

El 3777

c7 h7+ C6H4 BrCH3 (Benzene, l-bromo-2-methyl-)

(RN-CAS Registry Number 95-46-5)

11.14±0.1 El 3777

c7h7+ C6H4 BrCH3 (Benzene, 1 -bromo-3-methyl-)

(RN-CAS Registry Number 591-17-3)

1 1.22±0.1 El 3777

c7 h7+ C6H4 BrCH3 (Benzene, l-bromo-4-methyl-)

(RN-CAS Registry Number 106-38-7)

1 1.22±0.1 El 3777

c,h7+ C6H4ICH3 (Benzene, l-iodo-2-methyl-)

(RN-CAS Registry Number 615-37-2)

1 1.14±0.1 El 3777

48
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C?H7+ c6h4ich3 (Benzene, l-iodo-3-methyl-)

(RN-CAS Registry Number 625-95-6)

11.26±0.1 El 3777

c7h7+ c6h4ich3 (Benzene, l-iodo-4-methyl-)

(RN-CAS Registry Number 624-31-7)

11.15±0.1 El 3777

cw

C7H8+

C7H+

C7H+

QH+

C.H+

C.H+

(AV

QHg+

C7H8+

C.H+

c6h5 ch3 (Benzene, methyl-)

(RN-CAS Registry

c6h5 ch3 (Benzene, methyl-)

(RN-CAS Registry

QH5 CH3 (Benzene, methyl-)

(RN-CAS Registry

c6h5 ch3 (Benzene, methyl-)

(RN-CAS Registry

(Benzene, methyl-)

(RN-CAS Registry

c6h5 ch3 (Benzene, methyl-)

(RN-CAS Registry

c6h5 ch3 (Benzene, methyl-)

(RN-CAS Registry

C6H5CH3 (Benzene, methyl-)

(RN-CAS Registry

c6h5ch3 (Benzene, methyl-)

(RN-CAS Registry

C6H5 CH3 (Benzene, methyl-)

(RN-CAS Registry

C6H5 CH3 (Benzene, methyl-)

(RN-CAS Registry

-Average of two values)

C^Hg

(Bicyclo[2.2. ljhepta-

(RN-CAS Registry

CvH,

(Bicyclo[2.2. l]hepta-

(RN-CAS Registry

QHg

(Bicyclo[2.2. ljhepta-

(RN-CAS Registry

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

**

Number 108-88-3)

-2,5-diene)

Number 121-46-0)

**

-2,5-diene)

Number 121-46-0)

**

-2,5-diene)

Number 121-46-0)

8.82 PI 3753

8.72 PE 3955

8.78±0.02 PE 3854

8.80 PE 3868

8.85±0.015 (V) PE 4107

9.0±0.03 (V) PE 3713

8.89±0.03 EDD 3626

8.67 El 3845

8.80±0.1 El 3788

8.71 CTS 3546

8.91 CTS 4029

8.6 (V) PE 3724

8.69 (V) PE 3687

8.70 (V) PE 3509

49
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C7 H8+ c7 h8 (Bicylco[2.2. l]hepta-2, 5-diene)

(RN-CAS Registry Number 121-46-0)

8.69 (V) PE 3824

C,H,fA2) C7 H8 (Spiro[2.4]hepta-4, 6-diene)

(RN-CAS Registry Number 765-46-8)

8.14 PE 3576

C7H,t

2 B|) c7 h8 (Spiro[2.4]hepta-4, 6-diene)

(RN-CAS Registry Number 765-46-8)

9.46 PE 3576

C7 H,fA,) C7 H8 (Spiro[2.4]hepta-4, 6-diene)

(RN-CAS Registry Number 765-46-8)

10.9 PE 3576

C7H,fB2 ) C7 H8 (Spiro[2.4]hepta-4, 6-diene)

(RN-CAS Registry Number 765-46-8)

11.89 PE 3576

C7H8t

2 B,) C7H8 (Spiro[2.4]hepta-4, 6-diene)

(RN-CAS Registry Number 765-46-8)

12.7 PE 3576

C7 H8+

c7 h+

c7 h+

c7 h8+

CaHcC^Ho •'61A5'^4AA ch2 =chch3 10. 10±0.1 9 (Benzene, butyl-)

(RN-CAS Registry Number 104-51-8)

C6H4(OCH3 )CH3 CH20 1 1.22±0.1

(Benzene, l-methoxy-3-methyl-)

(RN-CAS Registry Number 100-84-5)

C6H4(OCH3)CH3 ch2o 11.11 ±0.1

(Benzene, l-methoxy-4-methyl-)

(RN-CAS Registry Number 104-93-8)

C6H4(OCH3)CH3 HCHO 11.23 (Benzene, 1 -methoxy-4-methyl-)

(RN-CAS Registry Number 104-93-8)

(CD-Metastable transition indicates 0.36 eV kinetic energy release)

C7 H8+ C6 H5 CH3 Cr(CO)3 8.31 ±0.1

(Chromium, tricarbonyl[( 1 ,2,3,4,5,6-i7)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

El

El

El

El

El

3629

3446

3446

3845

3788

C7H9+

c7 h9+

c7 h9+

c7 h+

C7 H10 H

(Bicyclo[2.2. l]hept-2-ene)

(RN-CAS Registry Number 498-66-8)

(ON-Other name: 2-Norbornene)

C7H10 H

(Tricyclo[2.2.1.02,6]heptane

(RN-CAS Registry Number 279-19-6)

(ON-Other name: Nortricyclene)

C7 H9Br Br

(bicyclo[2.2.1]hept-2-ene, 5-bromo-, exo-)

(RN-CAS Registry Number 5810-82-2)

C;H9 Br Br

(Bicyclo[2.2. l]hept-2-ene, 5-bromo-, endo-)

(RN-CAS Registry Number 5810-82-2)

11.0±0.01 El

1 1.3±0.01 EM

10.2 El

10.1 El

3535

3535

3900

3900

C7H^j trans,trans-CH2 = CHCH =CHCH = CHCH3 8.07 PE 3847

(RN-CAS Registry Number 17679-93-5)

50
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C.H+ c7h10 (Bicyclo[2.2. l]hept-2-ene)

(RN-CAS Registry Number 498-66-8)

8.95 (V) PE 3509

QHJ, QHjq

(Bicyclo[2.2. l]hept-2-ene)

(RN-CAS Registry Number 498-66-8)

8.97 (V) PE 3687

C7H,+

0 QH.0

(Bicyclo[2.2. l]hept-2-ene)

(RN-CAS Registry Number 498-66-8)

(ON-Other name: 2-Norbomene)

8.80±0.01 EM 3535

qh,; QH.0

(Bicyclo[4. 1.0]hept-2-ene)

(RN-CAS Registry Number 2566-57-6)

8.69 (V) PE 3849

QHjo

(Tricyclo[2.2. 1 .O^heptane)

(RN-CAS Registry Number 279-19-6)

9.40 (V) PE 3741

CrHft QH.o

(Tricyclo[2.2. l.O^heptane

(RN-CAS Registry Number 279-19-6)

(ON-Other name: Nortricyclene)

8.92±0.01 EM 3535

C.H+ C10H15 CH3 9.5±0.1

(4,7-Methano- l//-indene, octahydro-8-methyl-, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: a/z r/-10-Methyl-en^o-tricyclo[5.2. 1.0

2,6]decane)

PI 3918

C/H/i C10H16 9.9±0.1 PI 3918

(4,7-Methano-l/f-indene, octahydro-, (3aa,4/3,7y3,7aa)-)

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: exo-Tricyclo[5.2. 1 .O^jdecane)

QHi'i C10H15CH3 <10.2±0.1 PI 3918

(RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-exo-tricyclo[5.2.1.02’ 6]decane)

CyH^, C10H15CH3 10.0±0.1 PI 3918

(4,7-Methano- l//-indene, octahydro-2-methyl-, (2a,3ay3,4a,7a,7a/3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: czs-4-Methyl-exo-tricyclo[5.2.1.02,6]decane)

CioH^QHs <10.2±0.1 PI 3918

(4,7-Methano- l//-indene, 5-ethyloctahydro-, (3aa,4y3,5a,7y3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e«z/0-8-Ethyl-ex0-tricyclo[5.2.1.O2,6]decane)

C.H+ (CH3)2C=C=C(CH3)2 8.47 (V) PE 4019

(RN-CAS Registry Number 1000-87-9)

c7h+ (C2H3)2C(CH3)2 9.55 (V) PE 3994

(RN-CAS Registry Number 1112-35-2)

c7h+ CH2 =CH(CH2)3 CH=CH2 ** 9.52±0.02 (V) PE 4010

(RN-CAS Registry Number 3070-53-9)

c7h+ C^H,, 10.15 (V) PE 3509

(Bicyclo[2.2. l]heptane)

(RN-CAS Registry Number 279-23-2)

51
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C7 H+2 c7 h12 (Bicyclo[2.2. 1 ]heptane)

(RN-CAS Registry Number 279-23-2)

10.2 (V) PE 3687

c7 h,+

2 C7 H12 (Bicyclo[4. 1.0]heptane)

(RN-CAS Registry Number 286-08-8)

9.46 (V) PE 3849

C7H,+

3 C6H10(CH3 )2 ch3 (Cyclohexane, 1,2-dimethyl-, cis-)

(RN-CAS Registry Number 2207-01-4)

10.55±0.05 EDD 3581

C7 H,+

3 c6 h,0(ch3)2 ch3 (Cyclohexane, 1,2-dimethyl-, trans-)

(RN-CAS Registry Number 6876-23-9)

10.73±0.05 EDD 3581

C7 H

+ rrarts-(CH3)3CCH=CHCH2 ** (RN-CAS Registry Number 690-08-4)

8.908 ±0.008 PE 3957

C7 H,+

4 (CH3)3 CC(CH3) = CH2 (RN-CAS Registry Number 594-56-9)

9.016±0.007 PE 3957

C7 H,+

4 (CH3)3CCH2CH = CH2 ** (RN-CAS Registry Number 762-62-9)

9.399±0.003 PE 3957

C7 H+ (CH3)3 CCH2 CH= CH2 ** (RN-CAS Registry Number 762-62-9)

9.6 (V) PE 3940

C7H1f

4 (CH3)2CHCH2C(CH3)=CH2 ** (RN-CAS Registry Number 2213-32-3)

9.025±0.005 PE 3957

CM CH3 (CH2)3C(CH3)=CH2 (RN-CAS Registry Number 6094-02-6)

9.039±0.005 PE 3957

CMi C2H5 C(CH3)=C(CH3)2 ** (RN-CAS Registry Number 10574-37-5)

8.213±0.005 PE 3957

C7H,+

4 i-c7 h14 (RN-CAS Registry Number 592-76-7)

9.442 ±0.003 PE 3957

C7H,+

4 c/5-(CH3)3 CCH= CHCH3 ** (RN-CAS Registry Number 762-63-0)

8.922±0.008 PE 3957

C7H,+

4 cz5-(CH3)2 CHCH2 CH=CHCH3 ** (RN-CAS Registry Number 13151-17-2)

8.917±0.005 PE 3957

c7 h+ rra/z5-CH3 CH2C(CH3)HCH=CHCH3 (RN-CAS Registry Number 3683-22-5)

8.912±0.005 PE 3957

C7 H,+

4 /mzz5-(CH3 ) 2CHCH2CH = CHCH3 * * (RN-CAS Registry Number 7385-82-2)

8.919±0.005 PE 3957

c8 h6+ CH3 C=CC=CC=CCH3 ** (RN-CAS Registry Number 1072-20-4)

8.60 PE 4048

c8 h6+ c6h5c=ch ** (Benzene, ethynyl-)

(RN-CAS Registry Number 536-74-3)

8.75 PE 3938

C8 H6+ c6h5 c=ch ** (Benzene, ethynyl-)

(RN-CAS Registry Number 536-74-3)

8. 88 ±0.02 (V) PE 3854

c8 h8+ c6h5ch=ch2 ** (Benzene, ethenyl-)

8. 40 ±0.02 PE 3854

(RN-CAS Registry Number 100-42-5)

52
Table of Ion Energetics Measurements—Continued

c8h8+

c8h8+

c8h8+

c8h8+

c8h8+

c8h8+

c8 h8+

c8h8+

QH8+

c,H,+

c8h8+

c8h8+

c8h,+

C,H,+

c8h,+

c8h,+

Reactant

c6h5ch=ch2 (Benzene, ethenyl-)

(RN-CAS Registry Nun:

c6h5 ch=ch2 (Benzene, ethenyl-)

(RN-CAS Registry Nun

QH5QH3

(Benzene, ethenyl-)

(RN-CAS Registry Nun

c6h5ch=ch2 (Benzene, ethenyl-)

(RN-CAS Registry Nun

c6h5ch=ch2 (Benzene, ethenyl-)

(RN-CAS Registry Nun

C8H8 (Bicyclo[2.2. lJhepta-2, 5-diene, 7-methylene-)

(RN-CAS Registry Number 37846-63-2)

(ON-Other name: 7-Methylene-norbornadiene)

C8H8 (Bicyclo[4.2.0]octa-l,3,5-triene)

(RN-CAS-Registry Number 694-87-1)

C8H8 ( 1 , 3, 5, 7-Cyclooctatetraene)

(RN-CAS Registry Number 629-20-9)

CgH8 **

(Pentacyclo[4.2.0.02,5 .0

3,8 .04,7]octane)

(RN-CAS Registry Number 277-10-1)

c8h8 (Tricyclo[3.2. 1.0

2,8]octa-2,6-diene)

(RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: Tetrahydrobullvalene)

C8H8 (Tricyclo[4.2.0.

0

2,5]octa-3, 7-diene, syn-)

(RN-CAS Registry Number 20380-30-7)

C8 H8 (Tricyclo[4.2.0.02’ 5]octa-3,7-diene, anti-)

(RN-CAS Registry Number 20380-31-8)

Cfrl^CHzCI^OCOCI^

(Acetic acid, 2-phenylethyl ester)

(RN-CAS Registry Number 103-45-7)

Other

products

Ionization or appearance

potential

(eV)

Method Ref.

** 8.42 PE 3938

100-42-5)

** 8.49 (V) PE 3964

100-42-5)

*41 8.55 (V) PE 3781

100-42-5)

** 8.55 (V) PE 3898

100-42-5)

** 8.28±0.04 RPD 4097

100-42-5)

** 8.50 (V) PE 3933

8.66 (V)

8.0

8.4± <0.1

8.5 (V)

9.08 (V)

8.96 (V)

8.90

PE

PE

El

PE

PE

PE

El

4063

3999

3735

4034

4045

4045

3590

11.43 ±0.1 El 3629

(Benzene, l-butyl-3-methyl-)

(RN-CAS Registry Number 1595-04-6)

C6H4(CH3)C4H9

1 1.03±0.1 El 3629

(Benzene, 1-buty1-4-methyl-)

(RN-CAS Registry Number 1595-05-7)

C6H4(CH3)CH2CH2OCOCH3 12.30 El 3590

(Phenethyl alcohol, ra-methyl-, acetate)

(RN-CAS Registry Number 33709-40-9)

53
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8 h+ C6H4(CH3)CH2 CH2 OCOCH3 (Phenethyl alcohol, /7-methyl-, acetate)

(RN-CAS Registry Number 22532-47-4)

11.80 El 3590

C8H+o C6H4(CH3)2 (Benzene, 1,2-dimethyl-)

(RN-CAS Registry Number 95-47-6)

8.45±0.02 PE 3854

C8 H,+

o C6H4(CH3)2 (Benzene, 1,2-dimethyl-)

(RN-CAS-Registry Number 95-47-6)

8.57 (V) PE 4063

CMo C6H4(CH3)2 (Benzene, 1,2-dimethyl-)

(RN-CAS Registry Number 95-47-6)

8.75±0.03 (V) PE 3713

CMo C6H4(CH3)2 (Benzene, 1,2-dimethyl-)

(RN-CAS Registry Number 95-47-6)

8.55±0.1 El 3788

QHjo C6H4(CH3)2 (Benzene, 1,2-dimethyl-)

(RN-CAS Registry Number 95-47-6)

8.61 CTS 3546

c8 h,+

o c6h4(ch3)2 (Benzene, 1,2-dimethyl-)

(RN-CAS Registry Number 95-47-6)

(AV-Average of two values)

8.70 CTS 4029

C8 Hj^ C6H4(CH3)2 (Benzene, 1,3-dimethyl-)

(RN-CAS Registry Number 108-38-3)

8.50±0.02 PE 3854

c8 h+ C6H4(CH3)2 (Benzene, 1,3-dimethyl-)

(RN-CAS Registry Number 108-38-3)

8.71±0.015 (V) PE 4107

C8H+ C6H4(CH3)2 (Benzene, 1,3-dimethyl-)

(RN-CAS Registry Number 108-38-3)

8.75 ±0.03 (V) PE 3713

CMo C6H4(CH3)2 (Benzene, 1,4-dimethyl-)

(RN-CAS Registry Number 106-42-3)

8.37±0.02 PE 3854

CM C6H4(CH3)2 (Benzene, 1,4-dimethyl-)

(RN-CAS Registry Number 106-42-3)

8.6±0.03 (V) PE 3713

cMo r h **

'-'8rl10 (Bicyclo[2.2. l]hept-2-ene, 5-methylene-)

(RN-CAS Registry Number 694-91-7)

8.93 (V) PE 3824

cMo c H **

( 1

, 3, 5-Cyclooctatriene)

(RN-CAS Registry Number 1871-52-9)

7.9 PE 3999

cMo c H **

( 1 ,3,6-Cyclooctatriene)

(RN-CAS Registry Number 3725-30-2)

8.5 PE 3999

cMo C8 H10 ** 9.05 (V)

(Tricyclo[3.2.1.02,4 ]oct-6-ene, (la, 2a,4a, 5a)-)

(RN-CAS Registry Number 3635-94-7)

(ON-Other name: Tricyclo[3.2.1.02,4]oct-6-ene, endo-)

PE 3509

54
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method

products potential

(eV)

c8h+

C.H+

QH+

QH+

QH+o

QH+

C8H,o ** 8.90 (V)

(Tricyclo[3.2. l.O^Joct-b-ene, (la,2/3, 4/3, 5a)-)

(RN-CAS Registry Number 3635-95-8)

(ON-Other name: Tricyclo[3.2.1.02, 4]oct-6-ene, exo-)

CgH10 ** 8.5 (V)

(Tricyclo[3.2. l.O^Joct-b-ene)

(RN-CAS Registry Number XXXXX-XX-X)

C8H10 ** 9.25 (V)

(Tricyclo[4.2.0.02, 5]oct-3-ene, (la,2/3, 5/3, 6a)-)

(RN-CAS Registry Number 39781-76-5)

C6H4(CH3)C4H9 CH2 =CHCH3 10.33 ±0.

1

(Benzene, l-butyl-3-methyl-)

(RN-CAS Registry Number 1595-04-6)

C6H4(CH3)C4H9 CH2 =CHCH3 10.14±0.1

(Benzene, l-butyl-4-methyl-)

(RN-CAS Registry Number 1595-05-7)

C6H4(CH3)2Cr(CO)3 8.51+0.1

(Chromium, tricarbonyl[( 1 ,2,3,4, 5, 6-17)- 1 ,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

PE

PE

PE

El

El

El

Ref.

3509

4034

4045

3629

3629

3788

CgHi1; QoHjjCjHs 9.9+0.1 PI 3918

(4,7-Methano-l/f-indene, 5-ethyloctahydro-, (3aa,4/3,5a,7/3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e«c?o-8-Ethyl-exo-tricyclo[5.2. 1.0

2, 6]decane)

c8h+

2

C8H+

c8h

c8h

c8h

c8h

c8h

c8h

+

12

+

12

+

12

+

12

+

12

+

12

r^ u **

gni2

(Bicyclo[2.2. ljheptane, 2-methylene-)

(RN-CAS Registry Number 497-35-8)

9.02 (V) PE 3824

rL u **

8n12 (Bicyclo[2.2. ljheptane, 7-methylene-)

(RN-CAS Registry Number 31463-35-1)

(ON-Other name: 7-Methylene-norbomane)

9.40 (V) PE 3933

C6HnC=CH ** (Cyclohexane, ethynyl-)

(RN-CAS Registry Number 931-48-6)

9.92 (V) PE 3997

cr u **

8n12 ( 1

, 3-Cyclooctadiene)

(RN-CAS Registry Number 1700-10-3)

8.4 PE 3999

c8h12 ( 1 ,4-Cyclooctadiene)

(RN-CAS Registry Number 1073-07-0)

8.5 PE 3999

c8h12 ( 1 , 5-Cyclooctadiene)

(RN-CAS Registry Number 111-78-4)

8.9 PE 3999

C3H5 CH=CHC3H5 ** (Cyclopropane, l,l'-(l,2-ethenediyl)bis- (£))

(RN-CAS Registry Number 10359-44-1)

7.72 PI 3759

C3H5 CH=CHC3H5 ** (Cyclopropane, l,l'-(l,2-ethenediyl)bis- (Z))

7.70 PI 3759

(RN-CAS Registry Number 23510-65-68)

55
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C8 Hj (C3 H5 ) 2 C = CH2 (Cyclopropane, 1 , 1 '-ethenylidenebis-)

(RN-CAS Registry Number 822-93-5)

8.08 PI 3759

c8 h,+

2 c8 h12 (Tricyclo[3.2.1.02,4 ]octane, (la,2a,4a, 5a)-)

(RN-CAS Registry Number 22389-16-8)

(ON-Other name: Tricyclo[3.2.1.02,4]octane, endo-)

9.40 (V) PE 3509

C8 H+ PH ** v-'8 rl 12 (Tricyclo[3.2. 1 .O^Joctane, ( la, 2a,4a, 5a)-)

(RN-CAS Registry Number 22389-16-8)

(ON-Other name: Tricyclo[3.2.1.02' 4]octane, endo-)

8.8±0.1 El 3492

c8h+2 c8 h12 (Tricyclo[3.2. 1.0

2,4]octane, (la,2/3, 4/3, 5a)-)

(RN-CAS Registry Number 13377-46-3)

(ON-Other name: Tricyclo[3.2.1.02,4]octane, exo-)

9.40 (V) PE 3509

c8 h+ c8 h12 (Tricyclo[3.2.1.02,4]octane, (la,2/3,4/3, 5a)-)

(RN-CAS Registry Number 13377-46-3)

(ON-Other name: Tricyclo[3.2.1.02,4]octane, exo-)

9.1 ±0.1 El 3492

C8H+ c8 h12 (Tricyclo^^.O.O^Joctane, syn-)

(RN-CAS Registry Number 28636-10-4)

9.18 (V) PE 4045

C8 H+ c8 h12 (Tricyclo^^.O.O^Joctane, anti-)

(RN-CAS Registry Number 13027-75-3)

9.23 (V) PE 4045

QH+ PH **

'-8rl 12 (Tricyclo[ 5 . 1 .O.O^octane, ( 1 a,2a,4a,7a)-)

(RN-CAS Registry Number 50695-42-6)

8.95 (V) PE 3849

c8 h+2 PH ** ^8“12 (TricyclofS.l.O.O^joctane, (la,2/3,4/3, 7a)-)

(RN-CAS Registry Number 50895-58-4)

9.39 (V) PE 3849

C8 H+ CI0HI6 10.5±0.1

(4,7-Methano-l/f-indene, octahydro-, (3aa,4/3,7/3,7aa)-)

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: exo-TricycloJS^.l.O^^ecane)

PI 3918

c8 h+ C10H15CH3 10.0±0.1

(RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-ejtt>-tricyclo[5.2.1.02,6]decane)

PI 3918

C8 HJ3 C10H15 CH3 10.1 ±0.1 PI 3918

(4,7-Methano-17/-indene, octahydro-2-methyl, (2a,3a/3,4a,7a,7a/3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: c«-4-Methyl-ex0-tricyclo[5.2.1.O2,6]decane)

CgH^ C10H15 CH3 9.5±0.1 PI 3918

(4,7-Methano-l//-indene, octahydro-8-methyl-, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: an//-lO-Methyl-e/ic/0-tricyclo[5.2.1.O2’ 6]decane)

c8h+ (CH3)2C=CHCH = C(CH3)2 ** (RN-CAS Registry Number 764-13-6)

7.65 PE 3847

c8h+ CH2 = CH(CH2)4CH = CH2 ** (RN-CAS Registry Number 3710-30-3)9.52±0.02 (V) PE 4010

56
Table of Ion Energetics Measurements—Continued

Ion

C8 H

+

14

C8H+

14

CgH

+

14

CgH

CgH

CgH

CgH

CgH

CgH

CgH

CgH

CgH

CgH

CgH

CgH

CgH

+

16+

16+

16+

16+

16+

16+

16+

16+

16+

16+

16+

16+

16

CgH+

CgH+

c9h7+

c9h7+

Reactant Other

products

(Bicyclo[2.2.2]octane)

(RN-CAS Registry Number 280-33-1)

C8 H14 (Bicyclo[2. 2.2]octane)

(RN-CAS Registry Number 280-33-1) ^PH **

8n14 (Cyclooctene)

(RN-CAS Registry Number 931-88-4)

(CH3)3CCH2 C(CH3) = CH2 ** (RN-CAS Registry Number 107-39-1)

(CH3)2CHC(CH3) = C(CH3)2 ** (RN-CAS Registry Number 565-77-5)

C2H5 CH2C(CH3)=C(CH3)2 ** (RN-CAS Registry Number 7145-20-2)

(C2H5)2C = CHC2H5 ** (RN-CAS Registry Number 16789-51-8)

(C2H5)2C=C(CH3)2 (RN-CAS Registry Number 19780-67-7)

m-(CH3)2CHCH= CHCH(CH3)2 ** (RN-CAS Registry Number 10557-44-5)

ck-C2H5 C(CH3) =C(CH3)C2H5 ** (RN-CAS Registry Number 19550-87-9)

cis-3-C8H16 (RN-CAS Registry Number 14850-22-7)

m-4-C8H16 (RN-CAS Registry Number7642-15-1)

rra«s-(CH3)2 CHCH=CHCH(CH3;f2* (RN-CAS Registry Number 692-70-6)

?ra/2 s-C2H5 C(CH3) =C(CH3)C2H5 * * (RN-CAS Registry Number 19550-88-0)

trans-4-C8H16 ** (RN-CAS Registry Number 14850-23-8)

C6H10(CH3)2 (Cyclohexane, 1,2-dimethyl-, cis-)

(RN-CAS Registry Number 2207-01-4)

C6H10(CH3)2 (Cyclohexane, 1,2-dimethyl-, trans-)

(RN-CAS Registry Number 6876-23-9)

CgH16 (Cyclooctane)

(RN-CAS Registry Number 292-64-8)

C6H5 C=CCH3 (Benzene, 1-propynyl-)

(RN-CAS Registry Number 673-32-5)

C9H8 h

(1/f-Indene)

(RN-CAS Registry Number 95-13-6)

Ionization or appearance Method Ref.

potential

(eV)

9.43 S 3757

9.45 ±0.02 PE 3757

8.8 PE 3999

8.909±0.005 PE 3957

8.165±0.005 PE 3957

8.186±0.005 PE 3957

8.480+0.004 PE 3957

8.170+0.003 PE 3957

8.846+0.005 PE 3957

8.172±0.003 PE 3957

8.849+0.005 PE 3957

8.841 ±0.005 PE 3957

8.838±0.005 PE 3957

8.156±0.003 PE 3957

8.830±0.005 PE 3957

9.90±0.07 EDD 3581

10.03±0.05 EDD 3581

9.7 PE 3999

11.42±0.05 El 4044

12.62±0.05 El 4044

57
Table of Ion Energetics Measurements—Continued

C9H7+

c9h7+

c9h7+

c9h7+

c9h7+

c9 h7+

c9h7+

c9h7+

c9h7+

c9h7+

c9h7+

c9 h7+

c9 h+

c9h7+

c9h+

c9 h+

Reactant

Ionization or Other appearance Method

products potential

(eV)

C6H8 (C6H5)2 13.6±0.4

(Benzene, 1 , 1 '-(2-cyclohexen- 1 -ylidene)bis-)

(RN-CAS Registry Number 31158-25-5)

C6H10(C6H5)2 13.3±0.4

(Benzene, 1 , 1 '-cyclohexylidenebis-)

(RN-CAS Registry Number 21113-55-3)

C6H9(CH3)(C6H5)2 13.7±0.4

(Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS Registry Number 32812-65-0)

C10HI3 (CH3 )(C6H5)2 13.2±0.4

(Naphthalene, l,2,3,4,4a,5,6,7-octahydro-4a-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-50-2)

C6H5 C^CCH= CHCH2OH 11.43 ±0.05

(2-Penten-4-yn-l-ol, 5-phenyl-, (£)-)

(RN-CAS Registry Number 40317-08-6)

C6H8 ( = 0)(C6H5)2 14.1 ±0.4

(Cyclohexanone, 2,2-diphenyl-)

(RN-CAS Registry Number 22612-62-0)

C6H8( = 0)(C6H5 )2 13.5±0.4

(Cyclohexanone, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-68-1)

C6H7(=0)(CH3)(C6H5)2 13.5±0.4

(Cyclohexanone, 2-methyl-5, 5-diphenyl-)

(RN-CAS Registry Number 50592-49-9)

C6H7(=0)(CH3)(C6H5)2 13.7±0.4

(Cyclohexanone, 6-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-52-4)

C6H8 (OH)(CH3)(C6H5)2 13.7±0.4

(Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-47-7)

C6H6(=0)(CH3)2(C6H5)2 13.8±0.4

(Cyclohexanone, 2, 2-dimethyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-53-5)

El

El

El

El

El

El

El

El

El

El

El

C10H, j( = 0)(CH3)(C6H5)2 13.0±0.4 El

(2(37/)-Naphthalenone,4,4a,5,6,7,8-hexahydro-4a-methyl-7,7-diphenyl-)

(RN-CAS Registry Number 50786-03-3)

C6H6(=0)(CH3)(C6H5)2CH2CH2 CH0 13.4±0.4 El

(Cyclohexanepropanal, l-methyl-2-oxo-3, 3-diphenyl-)

(RN-CAS Registry Number XXXXX-XX-X)

C6H6(=0)(CH3)(C6 H5)2CH2CH2C0CH3 14.2±0.4 El

(Cyclohexanone, 2-methyl-2-(3-oxobutyl)-6, 6-diphenyl-)

(RN-CAS Registry Number 50592-55-7)

C6H6

( = 0)(C6H5) = CHS(CH2)3 CH3

1 3.7 ±0.4 El

(Cyclohexanone, 6-[(butylthio)methylene]-2,2-diphenyl-)

(RN-CAS Registry Number 50592-51-3)

C6H6

( = 0)CH3(C6H5)2CH2CH =C(CH3 )C1 1 3.7 ±0.4 El

(Cyclohexanone, 2-(3-chloro-2-butenyl)-2-methyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-54-6)

Ref.

4018

4018

4018

4018

4044

4018

4018

4018

4018

4018

4018

4018

4018

4018

4018

4018

C,Hjf C9H8 ** 8.33±0.01 El 3805

(1//-Indene)

(RN-CAS Registry Number 95-13-6)

58
Table of Ion Energetics Measurements—Continued

C9H8+

c9h+

c9h+

c9h+

C9H+o

c9h+

C9H,+

o

c9h+

c9h+o

c9h+

C9H+o

c,h;

QH+o

C9H,+

o

c9h+

C9HJq

C9HJq

Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c9h8 (Spiro[4.4]nona-l,3,6,8-tetraene)

(RN-CAS Registry Number 14867-83-5)

7.99 (V) PE 4049

C6H4(CH3 )CH = ch2 (Benzene, l-ethenyl-2-methyl-)

(RN-CAS Registry Number 611-15-4)

8.20+0.02 PE 3854

C6H4(CH3)CH = CH2 ** (Benzene, l-ethenyl-2-methyl-)

(RN-CAS Registry Number 611-15-4)

8.53 (V) PE 3964

C6H4(CH3)CH = CH2 ** (Benzene, l-ethenyl-3-methyl-)

(RN-CAS Registry Number 100-80-1)

8.15±0.02 PE 3854

C6H4(CH3)CH =CH2 ** (Benzene, l-ethenyl-3-methyl-)

(RN-CAS Registry Number 100-80-1)

8.37 (V) PE 3964

C6H4(CH3)CH = CH2 ** (Benzene, l-ethenyl-4-methyl-)

(RN-CAS Registry Number 622-97-9)

8.20 (V) PE 3964

C6H5 C(CH3) =ch2 (Benzene, (1-methylethenyl)-)

(RN-CAS Registry Number 98-83-9)

8.52 (V) PE 3964

C6H5 C(CH3) = ch2 (Benzene, (1-methylethenyl)-)

(RN-CAS Registry Number 98-83-9)

8.18+0.04 RPD 4097

c6h5ch=chch3 ** (Benzene, 1-propenyl-, (E)-)

(RN-CAS Registry Number 873-66-5)

8.20+0.02 PE 3854

c6h5 ch=chch3 ** (Benzene, 1-propenyl-,(E)-)

(RN-CAS Registry Number 873-66-5)

7.84±0.04 RPD 4097

C6H5C(CH3) = ch2 (Benzene, 2-propenyl-)

(RN-CAS Registry Number 300-57-2)

8.20+0.02 PE 3854

c6h5ch2ch=ch2 ** (Benzene, (2-propenyl)-)

(RN-CAS Registry Number 300-57-2)

8.60 PE 3938

r u ** ^9^10

(Bicyclo[3 . 2.2]nona-2,6, 8-triene)

(RN-CAS Registry Number 16216-91-4)

8.72 (V) PE 3991

r u ** ^9“10 (1/f-Indene, 2,3-dihydro-)

(RN-CAS Registry Number 496-11-7)

8.45 ±0.02 (V) PE 3854

r u ** W^io

(l^f-Indene, 2,3-dihydro-)

(RN-CAS-Registry Number 496-11-7)

8.46 (V) PE 4063

r u ** ^9n10 (1/f-Indene, 2,3-dihydro-)

(RN-CAS Registry Number 496-11-7)

8.60±0.01 El 3805

c H ** ^9“10 (1^-Indene, 2,3-dihydro-)

(RN-CAS Registry Number 496-11-7)

59

8.52 CTS 3546
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C9H,+

0 C9H10 ** 8.73 (V)

(Spiro[bicyclo[2.2. 1 ]hepta-2,5-diene-7, 1 '-cyclopropane])

(RN-CAS Registry Number 7092-57-1)

PE 3780

C9H,+

o PH ** ^9° 10 (Tricyclo[3.3. 1 .028]nona-3, 6-diene)

(RN-CAS Registry Number 14693-11-9)

8.4 (V) PE 4034

C9Hf0 PH **

(Tricyclo[4.2. 1 .0

2,5 ]nona-3,7-diene)

(RN-CAS Registry Number 4932-71-2)

8.7 (V) PE 3853

C9H,+

0 C9H10 ** 8.65±0.05 (V)

(Tricyclo[4.2.1.025]nona-3,7-diene, (la, 2/3, 5)3, 6a)-)

(RN-CAS Registry Number 15564-44-0)

(ON-Other name: Tricyclo[4.2.1.02,5 ]nona-3,7-diene, exo-)

PE 4040

C9H,+

0 C6 H4(CH3 )CH2 CH2OCOCH3 (Phenethyl alcohol, m-methyl-, acetate)

(RN-CAS Registry Number 33709-40-9)

8.75 El 3590

C9H,+

0 C6H4(CH3 )CH2 CH2OCOCH3 (Phenethyl alcohol, /7-methyl-, acetate)

(RN-CAS Registry Number 22532-47-4)

8.50 El 3590

c9h+ (C2 H3)4C

(RN-CAS Registry Number 20685-34-1)

9.52 (V) PE 3994

c9 h+ C6H3 (CH3 )3 (Benzene, 1,2,3-trimethyl-)

(RN-CAS Registry Number 526-73-8)

8.6±0.03 (V) PE 3713

c9h+ C6H3(CH3)3 (Benzene, 1,2,4-trimethyl-)

(RN-CAS Registry Number 95-63-6)

8.5±0.03 (V) PE 3713

c9h,+

2 C6H3 (CH3)3 (Benzene, 1,3,5-trimethyl-)

(RN-CAS Registry Number 108-67-8)

8.65 ±0.03 (V) PE 3713

c9 h+ C6H3 (CH3)3 (Benzene, 1,3,5-trimethyl-)

(RN-CAS Registry Number 108-67-8)

8.21 ±0.1 El 3788

C9Hf2 C6H3 (CH3)3 (Benzene, 1,3,5-trimethyl-)

(RN-CAS Registry Number 108-67-8)

(AV-Average of two values)

8.46 CTS 4029

c9h,+

2 PH ** v-'9rl 12 (Bicyclo[3. 2. 2]nona-2, 6-diene)

RN-CAS Registry Number 14993-07-8)

8.84 (V) PE 3991

c9h+ PH **

'-'9rl 12 (Bicyclo[3. 2. 2]nona-6, 8-diene)

(RN-CAS Registry Number 7164-08-1)

9.00 (V) PE 3991

C9H,+

2 PH ** ^9“ 12 (Tetracyclo[3.3. 1 .0

2,8 .04,6]nonane)

(RN-CAS Registry Number 3105-29-1)

8.67 (V) PE 3741

c9h,+

2 C9H12 (Tricyclo[4.2.1.02,5 ]non-3-ene)

(RN-CAS Registry Number 7078-40-2)

9 (V) PE 3853

60
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

GjHjj C9H12 ** 9.00±0.05 (V) PE 4040

(Tricyclo[4.2.1.02,5 ]non-3-ene, (la,2/3, 5/3, 6a)-)

(RN-CAS Registry Number 16529-76-3)

(ON-Other name: Tricyclo[4.2.1.02,5 ]non-3-ene, exo-)

G,H12+ C9H12 ** 8.7 (V) PE 3853

(Tricyclo[4.2. 1 .0

2,5]non-7-ene)

(RN-CAS Registry Number 6827-30-1)

C,H£ C9H12 ** 8.70±0.05 (V) PE 4040

(Tricyclo[4.2. 1.0

2,5]non-7-ene, exo-)

(RN-CAS Registry Number 16529-82-1)

C6H3(CH3)3 Cr(CO)3 8.61 ±0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,3,5-trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

CoH+

3 C10H16 CH3 9.8±0.1

(4,7-Methano- 17/-indene, octahydro-, (3aa,4/3,7/3,7aa)-)

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: ejco-Tricyclo[5.2.1.02,6]decane)

PI 3918

OH+ C10H15 CH3 <10.2±0.1

(RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-exo-tricyclo[5.2. 1 .0

2,6]decane)

PI 3918

QH+ C10H15CH3 10.1 ±0.1

(4,7-Methano- l//-indene, octahydro-2-methyl-, (2a,3a/3,4a,7a,7a/3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: czs-4-Methyl-exo-tricyclo[5.2.1.02,6]decane)

PI 3918

C9H+ C10H15 CH3 9.5±0.1

(4,7-Methano- 1/f-indene, octahydro-8-methyl-, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: arth-lO-Methyl-e/zJo-tricyclofS^.l.O^ldecane)

PI 3918

C.H+ CkjH^QjHj 9.9±0.1

(4,7-Methano- l//-indene, 5-ethyloctahydro-, (3aa,4/3,5a,7/3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e«z/o-8-Ethyl-exo-tricyclo[5.2. 1 .O^Jdecane)

PI 3918

CoH+4 QHh

(Bicyclo[3 . 2.2]non-2-ene)

(RN-CAS Registry Number 40319-81-1)

8.84 (V) PE 3991

C9H14 c9h14 (Bicyclo[3 .2. 2]non-6-ene)

(RN-CAS Registry Number 7124-86-9)

8.95 (V) PE 3991

C9H14

( 1 ,2-Cyclononadiene)

(RN-CAS Registry Number 1123-11-1)

8.87 (V) PE 4019

C.H+ OH14 (Tricyclo[3.2.2.02,4]nonane)

(RN-CAS Registry Number 278-80-8)

9.50 (V) PE 3849

C9H+ C9H14 (Tricyclo[4.2. 1 .O^lnonane, exo-)

(RN-CAS Registry Number 16526-27-5)

9.5±0.05 (V) PE 4040

OHj^ CH2 =CH(CH2)5 CH=CH2 ** 9.51 ±0.02 (V) PE 4010

(RN-CAS Registry Number 4900-30-5)

61
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c9h16+ C7H10(CH3)2 (Bicyclo[2.2. l]heptane, 7,7-dimethyl-)

(RN-CAS Registry Number 2034-53-9)

8.30 PE 3687

c9h+ c9h16 (Bicyclo[3.2.2]nonane)

(RN-CAS Registry Number 283-19-2)

9.6 (V) PE 3991

C,H,+/E) c9h16 (Bicyclo[6. 1.0]nonane)

(RN-CAS Registry Number 286-60-2)

9.4 (V) PE 3509

C9H,+

6 PH ** '-•9rl 16 (Bicyclo[6.1.0]nonane, trans-)

(RN-CAS Registry Number 39124-79-3)

9.36 (V) PE 3849

C9H+ CH3(CH2)3 C(CH3) = C(CH3)2 ** (RN-CAS Registry Number 3074-64-4)

8.145±0.005 PE 3957

c9h+ C2 H5 CH2C(CH3)=C(CH3)C2H5 ** (RN-CAS Registry Number 3074-67-7)

8.077±0.005 PE 3957

c9h,+

8 (C2H5)2C = C(CH3)C2 H5 ** (RN-CAS Registry Number 50787-13-8)

8.128±0.005 PE 3957

c10h8+ c10h8 (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.1 PI 3586

c10h8+ c10h8 (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.13 PE 3637

c10h8+ CioH8 ** (Naphthalene)

(RN-CAS-Registry Number 91-20-3)

8.15 PE 4066

c10h8+ c10h8 (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.15 PE 3638

CioH8+ c10h8 (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.15 PE 3668

c10h8+ CioH8 ** (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.15 (V) PE 3781

c10h8+ c10h8 (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.15 (V) PE 3898

Cions’ c10h8 (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.25±0.01 RPD 3588

c10h8+ Ck>H8 ** (Naphthalene)

(RN-CAS Registry Number 91-20-3)

8.12 CTS 3922

C,oHf0 c6h5 ch=chch=ch2 ** 7.95 PE 3892

(Benzene, 1,3-butadienyl-, (E)-)

(RN-CAS Registry Number 16939-57-4)

62
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method

products potential

(eV)

C10H

+

10

C10H

+

10

C10H

+

10

CMo

C10HJ

C10H10

CH2 =C(C6H5)CH =CH2 ** 8.57 (Benzene, (l-methylene-2-propenyl)-)

(RN-CAS Registry Number 2288-18-8)

** 8.25 (V)

(Bicyclo[4.2. l]nona-2,4,7-triene, 9-methylene-)

(RN-CAS Registry Number 38898-39-4)

C10H10 ** 9.0 (V)

(Cyclopenta[a/]pentalene, 2a,4a, 6a, 6b-tetrahydro-)

(RN-CAS Registry Number 6053-74—3)

(ON-Other name: Triquinacene)

C9H8(=CH2) ** 8.00+0.02

( 1//-Indene, 2, 3-dihydro- 1 -methylene-)

(RN-CAS Registry Number 1194-56-5)

C10H10 ** 8.50 (V)

(l,2,3-Metheno-li7-dicycloprop[a/,/?z]indene, octahydro-)

(RN-CAS Registry Number 33840-23-2)

(ON-Other name: Diademane)

(C5H5)2Fe Fe 13.8+0.5

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

(PC-Appearance potential of the corresponding metastable transition)

C10HJq (C5H5)2Fe Fe 13.96+0.10

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

(MT-Metastable transition(s) observed)

C10HJo (C5H5)2Ni Ni 13.3+0.5

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

(PC-Appearance potential of the corresponding metastable transition)

PE

PE

PE

PE

PE

El

El

El

Ref.

3892

4094

4004

3854

3849

3628

3628

3628

CMi

CMi

c10hr2 CMi

cMi

CM2

C6H3 (CH3)2CH=CH2 ** 8.22 (V)

(Benzene, l-ethenyl-2,4-dimethyl-)

(RN-CAS Registry Number 2234-20-0)

C6H3 (CH3)2CH=CH2 ** 8.10+0.02

(Benzene, 2-ethenyl-l,3-dimethyl-)

(RN-CAS Registry Number 2039-90-9)

C6H3 (CH3)2CH=CH2 ** 8.48 (V)

(Benzene, 2-ethenyl-l, 3 -dimethyl-)

(RN-CAS Registry Number 2039-90-9)

C6H3 (CH3)2CH=CH2 ** 8.00+0.02

(Benzene, 2-ethenyl- 1,4-dimethyl-)

(RN-CAS Registry Number 2039-89-6)

C6H5 CH= C(CH3)2 ** 7.78±0.04

(Benzene, (2-methyl- 1-propenyl)-)

(RN-CAS Registry Number 768-49-0)

C7H6 =C(CH3)2 ** 7.97

(Bicyclo[2.2. l]hepta-2, 5-diene, 7-(l-methylethylidene)-)

(RN-CAS Registry Number 36456-22-1)

C9H9CH3 ** 8.47

(l^fif-Indene, 2, 3-dihydro- 1 -methyl-)

(RN-CAS Registry Number 767-58-8)

PE

PE

PE

PE

RPD

PE

CTS

3964

3854

3964

3854

4097

3687

3546

63
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C10Hf2 C,oH 12 (Naphthalene, 1 ,2,3,4-tetrahydro-)

(RN-CAS-Registry Number 119-64-2)

8.44 (V) PE 4063

C,aH5 C10H12 (Naphthalene, 1,2,3,4-tetrahydro-)

(RN-CAS Registry Number 119-64-2)

8.45 ±0.02 (V) PE 3854

cMi CM

(Naphthalene, 1,2,3,4-tetrahydro-)

(RN-CAS Registry Number 119-64-2)

8.47 CTS 3546

cMi C10H,2 ** 8.78 (V) PE

(Tricycloprop[a//,/f/]indene, decahydro-, (laa,lba,lc/?,2a/3,2ba,2ca,2da,2ea)-)

(RN-CAS Registry Number 50895-59-5)

(ON-Other name: Pentacyclo[3.3.2.02,9 .0

4’ 10 06’ 8 ]decane)

3849

C.oH^ C6H4(C2 H5)2 (Benzene, 1,2-diethyl-)

(RN-CAS-Registry Number 135-01-3)

8.51 (V) PE 4063

CM, C6H4(C2H5)2 (Benzene, 1,2-diethyl-)

(RN-CAS Registry Number 135-01-3)

8.51 CTS 3546

CM, C6H5 C(CH3)3 (Benzene, (1,1-dimethylethyl-)

(RN-CAS Registry Number 98-06-6)

8.64 CTS 3922

CM, C6H2(CH3 )4 (Benzene, 1,2,3,5-tetramethyl-)

(RN-CAS Registry Number 527-53-7)

8.3±0.03 (V) PE 3713

CM, C6H2(CH3 )4 (Benzene, 1,2,4,5-tetramethyl-)

(RN-CAS Registry Number 95-93-2)

8.2 CTS 3543

CM, C7H8 =C(CH3 )2 (Bicyclo[2.2. 1 ]hept-2-ene, 7-( 1 -methylethylidene)-)

(RN-CAS Registry Number 14995-50-7)

8.27 PE 3687

cMs c10h15 ch3 ch3 9.5±0.1 PI 3918

CI0Hfi

c10Hr5

CioHi+

5

(RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-e;c0-tricyclo[5.2.1.O2’ 6]decane)

C10H15 CH3 CH3 10.1 ±0.1

(4,7-Methano- l//-indene, octahydro-2-methyl-, (2a,3a/3,4a,7a,7a/3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: c/5-4-Methyl-exo-tricyclo[5.2.1.02,6]decane)

C10H15 CH3 CH3 9.6±0.1

(4,7-Methano- l//-indene, octahydro-8-methyl-, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: an//-10-Methyl-e/iGfo-tricyclo[5.2.1.02’ 6]decane)

C10H15 C2H5 9.9±0.1

(4,7-Methano- l//-indene, 5-ethyloctahydro-, (3aa,4/3,5a,7/3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e/it/o-S-Ethyl-exo-tricyclofS^.l.O^decane)

PI

PE

PI

3918

3918

3918

C10H,+

6 G,H 14 =CH2 ** 9.0 (V) PE 4094

(Bicyclo[4.2. ljnonane, 9-methylene-)

(RN-CAS Registry Number 40916-48-1)

64
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method

C10Hf6

c10H+

6

C10Hf6

CmHS

C.oH^

C10Hf6

c10h^6

c10h^6

CmHS

C10Hi

(C3H5)2C= C(CH3)2 ** 7. (Cyclopropane, 1 , 1 '-(2-methyl- 1 -propenylidene)bis-)

(RN-CAS Registry Number 27720-84-9)

C10HI6 ** 9. (4,7-Methano- l//-indene, octahydro-, (3aa,4/3,7y3,7aa)-

(RN-CAS Registry Number 2825-82-3)

(ON-Other name: exo-Tricyclo[5.2.1.02,6]decane)

c10h16 (Tricyclo[3.3. 1 .

1

3,7]decane

(RN-CAS Registry Number 281-23-2)

c10h16 (Tricyclo[3 . 3.1.1

3,7]decane)

(RN-CAS Registry Number 281-23-2)

(ON-Other name: Adamantane)

c10h16 (Tricyclo[3.3. 1. l

3,7]decane)

(RN-CAS Registry Number 281-23-2)

(ON-Other name: Adamantane)

c10h16 (Tricyclo [3.3.1.1

3,7]decane)

(RN-CAS Registry Number 281-23-2)

(ON-Other name: Adamantane)

c10h16 (Tricyclo[3 . 3.1.1

3,7]decane)

(RN-CAS Registry Number 281-23-2)

(ON-Other name: Adamantane)

c10h16 (Tricyclo[3.3. 1. l

3,7]decane

(RN-CAS Registry Number 281-23-2)

c10h16 (Tricyclo[3 .3.1.1

3,7]decane)

(RN-CAS Registry Number 281-23-2)

(ON-Other name: Adamantane)

c10h16 (Tricyclo[3.3. 1. l

3,7]decane

(RN-CAS Registry Number 281-23-2)

(ON-Other name: Adamantane)

82

35±0.05

)

9.30±0.01

9.1±0.05

9.22

9.23

9.28±0.1

9.31+0.01

9.55 (V)

9.75 (V)

PI

PI

PE

PE

PE

PE

PE

PE

PE

Ref.

3759

3918

3757

3855

3907

3886

3851

3757

3990

4000

CioH^)

Q0H20

Q0H20

CioH2+

0

CH3 (CH2)3 C(C2H5) =C(CH3)2 ** (RN-CAS Registry Number 19780-61-1)

CH3(CH2)4C(CH3) =C(CH3)2 ** (RN-CAS Registry Number 19781-18-1)

(CH3)3 CCH2C(CH3) =C(CH3)2 ** (RN-CAS Registry Number 33175-59-6)

(terr-C4H9)2C=CH2 ** (RN-CAS Registry Number 5857-68-1)

cMCH3)3CCH=CHC(CH3)3 ** (RN-CAS Registry Number 692-47-7)

c«-(CH3)3 CCH=CHC(CH3)3 ** (RN-CAS Registry Number 692-47-7)

c/5-5-CioH20 ** (RN-CAS Registry Number 7433-78-5)

65

8.101+0.005 PE 3957

8.132+0.005 PE 3957

8.097+0.005 PE 3957

8.795+0.008 PE 3957

8.695+0.010 PE 3957

8.95 (V) PE 4084

8.766+0.005 PE 3957
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C10H2+

o /ra/is-(CH3)3 CCH = CHC(CH3)3 ** (RN-CAS Registry Number 692-48-8)

8.741 ±0.008 PE 3957

CioH^) /ra/tt-(CH3 ) 3 CCH=CHC(CH3)3 ** (RN-CAS Registry Number 692-48-8)

8.89 (V) PE 4084

C10H2+

0 trans-5-C)0H20 ** (RN-CAS Registry Number 7433-56-9)

8.760±0.005 PE 3957

c„h9+ C6H5 C=CCH=CHCH2 C1

(Benzene, (5-chloro-3-penten-l-ynyl)-, (is)-)

(RN-CAS Registry Number 40316-56-1)

8.95±0.05 El 4044

cu h9+ C10H7 CH2 C1

(Naphthalene, l-(chloromethyl)-)

(RN-CAS Registry Number 86-52-2)

1 1.21±0.05 El 4044

c„h9+ C10H7CH2 C1

(Naphthalene, 2-(chloromethyl)-)

(RN-CAS Registry Number 2506-41-4)

11.1 5 =±=0.05 El 4044

CiiHj^ C H **

(Bicyclo[4.4. 1 ]undeca- 1 ,3,5,7,9-pentaene)

(RN-CAS Registry Number 2443-46-1)

7.90 (V) PE 3953

CnHJo C10H7CH3 (Naphthalene, 1 -methyl-)

(RN-CAS Registry Number 90-12-0)

7.95 (V) PE 3685

C„H+0 C10H7CH3 (Naphthalene, 1 -methyl-)

(RN-CAS Registry Number 90-12-0)

7.80±0.03 RPD 3588

C„HJ C10H7 CH3 (Naphthalene, 1 -methyl-)

(RN-CAS Registry Number 90-12-0)

7.98 CTS 3758

C„Hf0 C10H7CH3 (Naphthalene, 2-methyl-)

(RN-CAS Registry Number 91-57-6)

7.93 (V) PE 3685

C„Hi C10H7CH3 (Naphthalene, 2-methyl-)

(RN-CAS Registry Number 91-57-6)

8.10±0.03 RPD 3588

C„Hf0 (C6H5)2S CS

(Benzene, 1,1 '—thiobis—

)

(RN-CAS Registry Number 139-66-2)

12.57 ±0.

El 3817

CnHfi C10H10(=CH2) (Naphthalene, 1,2,3,4-tetrahydro-l-methylene-)

(RN-CAS Registry Number 25108-63-8)

7.90±0.02 (V) PE 3854

CnHii C6H2(CH3)3 CH= CH2 (Benzene, 2-ethenyl- 1 ,3,5-trimethyl-)

(RN-CAS Registry Number 769-25-5)

8.33 (V) PE 3964

C„HS c„h14 (5i/-Benzocycloheptene, 6,7,8,9-tetrahydro-)

(RN-CAS Registry Number 1075-16-7)

8.40±0.02 (V) PE 3854

c„Hr4 c„h14 (5//-Benzocycloheptene, 6,7,8,9-tetrahydro-)

(RN-CAS-Registry Number 1075-16-7)

8.44 (V) PE 4063

66
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

C„H£ QH^CH^ ** 8.47 CTS 3546

(Indan, 1,1 -dimethyl)

(RN-CAS Registry Number 4912-92-9)

CnHj4 C^CH^ ** 8.47 CTS 3546

( lf/-Indene, 2, 3-dihydro-2,2-dimethyl-)

(RN-CAS Registry Number 20836-11-7)

CnHj4 C8H8 =C(CH3)2 ** 7.9 PE 3687

(Tricyclo[3.2. 1.0

2,4]oct-6-ene, 8-(l-methylethylidene)-, endo-)

(RN-CAS Registry Number XXXXX-XX-X)

CnHS

CnH^

C„H+6

C„H+

CnH^

C6H4(CH3)C4H9 ** 8.42±0.1

(Benzene, l-butyl-3-methyl-)

(RN-CAS Registry Number 1595-04-6)

C6H4(CH3)C4H9 ** 8.35 ±0.1

(Benzene, l-butyl-4-methyl-)

(RN-CAS Registry Number 1595-05-7)

QH(CH^ ** 7.9 (Benzene, pentamethyl-)

(RN-CAS Registry Number 700-12-9)

(C3H5)2C=CHC3H5 ** 7.48 (Cyclopropane, 1 , T, 1 ' -( 1 -ethenyl-2-ylidene)tris-)

(RN-CAS Registry Number 23603-63-6)

C10H14(=CH2) 8.82

(Tricyclo[3.3. 1. l

3,7]decane, 2-methylene-)

(RN-CAS Registry Number 875-72-9)

(ON-Other name: Methyleneadamantane)

C8H10 =C(CH3)2 ** 8.18 (Tricyclo[3.2. l.O^Joctane, 8-(l-methylethylidene)-, endo-)

(RN-CAS Registry Number XXXXX-XX-X)

El

El

CTS

PI

PE

PE

3629

3629

3543

3759

3886

3687

CnHp CjoH^QHs CH3 10.0±0.1 PI (4,7-Methano- li/-indene, 5-ethyloctahydro-, (3aa,4/3,5a,7y3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e/w/o-S-Ethyl-exo-tricyclotS^.l.O^decane)

CnHjg C10H15CH3 ** 9.35 ±0.05 PI (RN-CAS Registry Number XXXXX-XX-X)

(ON-Other name: 2-Methyl-ejco-tricyclo[5.2.1.02,6]decane)

CuH,+

8 C10H15CH3 ** 9.35±0.05 PI (4,7-Methano- liT-indene, octahydro-2-methyl-, (2a,3ay3,4a,7a,7ay3)-)

(RN-CAS Registry Number 50745-90-9)

(ON-Other name: m-4-Methyl-exo-tricyclo[5.2.1.02,6]decane)

CnHjg C10H15CH3 ** 9.35±0.05 PI (4,7-Methano- lif-indene, octahydro-8-methyl-, stereoisomer)

(RN-CAS Registry Number 50745-92-1)

(ON-Other name: antf-lO-Methyl-e/n/o-tricyclotS^.l.O^decane)

CnHjg C10H15CH3 ** 9.17±0.02 PE

(Tricyclo[3.3. 1. l 3,7]decane, 1-methyl-)

(RN-CAS Registry Number 768-91-2)

(ON-Other name: 1-Methyladamantane)

3918

3918

3918

3918

3886

67
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C„H2+

0 (ferf-C4H9)2C = C =CH2 ** (RN-CAS Registry Number 22585-31-5)

8.55 (V) PE 4019

c„h2+

2 C2H5CH2C(C2 H5 )=C(C2 H5 )2 ** (RN-CAS Registry Number 50787-14-9)

8.041 ±0.020 PE 3957

c12 h+ C12 H8 (Biphenylene)

(RN-CAS Registry Number 259-79-0)

7.53±0.05 PE 3684

c12 h8+ PH **

'-'12“8 (Biphenylene)

(RN-CAS Registry Number 259-79-0)

7.60±0.02 (V) PE 3702

C12H,+

o (C6H5)2 (l,l'-Biphenyl)

(RN-CAS Registry Number 92-52-4)

7.95±0.02 PE 3702

c12hj (C6H5)2 (l,l'-Biphenyl)

(RN-CAS Registry Number 92-52-4)

8.35 CTS 3577

C12 Hf0 PH **

'~-'12“l0 (Cyclopent[a/]azulene, 2a, 8b-dihydro-)

(RN-CAS Registry Number 38310-40-6)

7.46 (V) PE 4008

C,2H+o PH **

'-'12“ 10 (4a, 8a-Ethenonaphthalene)

(RN-CAS Registry Number 19539-78-7)

8.1 (V) PE 4006

c12 h+ PH **

'-'12“ 12 (4a, 8a-Ethenonaphthalene, 1,4-dihydro-)

(RN-CAS Registry Number 38310-32-6)

8.0 (V) PE 4006

C12 H+ C„H12(=CH2) ** 8.45±0.02 (V)

(5//-Benzocycloheptene, 6,7,8,9-tetrahydro-5-methylene-)

(RN-CAS Registry Number 40562-09-2)

PE 3854

c12 h+ c12h14 (4a, 8a-Ethenonaphthalene, 1,2,3,4-tetrahydro-)

(RN-CAS Registry Number 24139-33-1)

8.0 (V) PE 4006

c12 h+ PH ** ^1 2“14 (4a, 8a-Ethenonaphthalene, 1,4,5,8-tetrahydro-)

(RN-CAS Registry Number 20295-17-4)

8.7 (V) PE 4006

c,2 h,+

6 C6H5 CH=CHC(CH3)3 ** (Benzene, (3,3-dimethyl- 1-butenyl)-, (E)-)

(RN-CAS Registry Number 3846-66-0)

7.80±0.04 RPD 4097

c12 h,+

6 C6H5CH=CHC(CH3)3 ** (Benzene, (3,3-dimethyl- 1-butenyl)-, (Z)-)

(RN-CAS Registry Number 3740-05-4)

8.29 ±0.04 RPD 4097

^i2HJj C6H5C(C(CH3)3)=CH2 (Benzene, (2,2-dimethyl- 1 -methylenepropyl)-)

(RN-CAS Registry Number 5676-29-9)

8.25 ±0.04 RPD 4097

c12 h,+

6 PH ** ^12“l6

(Benzocyclooctene, 5, 6, 7, 8,9, 10-hexahydro-)

(RN-CAS-Registry Number 1076-69-3)

8.42 (V) PE 4063

68
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c12h+6 ^12H16 ** 8.9 (V) PE 4006

(4a, 8a-Ethenonaphthalene, 1,2,3,4,5,8-hexahydro-)

(RN-CAS Registry Number 24139-32-0)

C12H,+

8 C6(CH3)6 ** 7.8 CTS 3543

(Benzene, hexamethyl-)

(RN-CAS Registry Number 87-85-4)

Ci2H,+

8 C12H18 ** 9.05 (V) PE 4006

(4a, 8a-Ethenonaphthalene, 1,2,3,4,5,6,7,8-octahydro-)

(RN-CAS Registry Number 38992-78-8)

C12H£ C6(CH3)6Cr(CO)3 8.55±0.1 El 3788

(Chromium, tricarbonyl[( 1 ,2,3,4,5,6-i7)-hexamethylbenzene]-)

(RN-CAS Registry Number 12088-11-8)

C12H£ C10H15C2H5 ** 9.35 ±0.05 PI 3918

(4,7-Methano-l//-indene, 5-ethyloctahydro-,(3aa,4y3,5a,7/3,7aa)-)

(RN-CAS Registry Number 32787-97-6)

(ON-Other name: e/iJo-8-Ethyl-exo-tricyclo[5.2. 1 .O^decane)

C12H2+ m-(CH3)3CCH2C(CH3)=CHC(CH3)3 ** (RN-CAS Registry Number 27656-50-4)

8.346+0.005 PE 3957

C,jH,+C,4H,CH3 CjHj

(Phenanthrene, 4-methyl-)

(RN-CAS Registry Number 832-64-4)

(MT-Metastable transition(s) observed)

12.7+0.1 El 3454

c13h+ C14H8(CH3)2 (Phenanthrene, 4,5-dimethyl-)

(RN-CAS Registry Number 3674-69-9)

12.4+0.1 El 3454

Ci3H+

(Benzene, 1 , 1 '-(2-cyclohexen- 1 -ylidene)bis-)

(RN-CAS Registry Number 31158-25-5)

13.0+0.4 El 4018

c13h9+ C6H10(C6H5)2 (Benzene, l,l'-cyclohexylidenebis-)

(RN-CAS Registry Number 21113-55-3)

13.3+0.4 El 4018

c13h9+ C6H7(CH3)(C6Hs)2 (Cyclohexene, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-48-8)

13.4+0.4 El 4018

c13h+ C6H9(CH3)(C6H5)2 (Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS Registry Number 32812-65-0)

13.2+0.4 El 4018

c13h9+ C10H13(CH3)(C6H5)2 (Naphthalene, l,2,3,4,4a,5,6,7-octahydro-4a-methyl-

(RN-CAS Registry Number 50592-50-2)

13.4±0.4

-2,2-diphenyl-)

El 4018

C13H+ C6H6( =0)(C6H5)2 (2-Cyclohexen-l-one, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-64-7)

14.4+0.4 El 4018

Ci3H+ C6H8(=0)(C6H5)2 (Cyclohexanone, 2,2-diphenyl-)

(RN-CAS Registry Number 22612-62-0)

13.8±0.4 El 4018
Table of Ion Energetics Measurements—Continued

Ion

'13-rl9

'13 n9

c13 h9+

'13 n9

c13 h9+

CnH13 1A9

'13 n9

c13 h9+

'13 n9

Reactant

Ionization or Other appearance Method Ref.

products potential

(eV)

C6H8( = 0)(C6H5)2 14.4±0.4

(Cyclohexanone, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-68-1)

C6H7(=0)(CH3)(C6H5)2 14.0±0.4

(Cyclohexanone, 2-methyl-5,5-diphenyl-)

(RN-CAS Registry Number 50592-49-9)

C6H7( =0)(CH3)(C6H5)2 14.1 ±0.4

(Cyclohexanone, 6-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-52-4)

C6H8(OH)(CH3)(C6H5)2 13.9±0.4

(Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-47-7)

C6H6(=0)(CH3)2(C6H5)2 13.4+0.4

(Cyclohexanone, 2, 2-dimethyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-53-5)

C6H6(=0)(CH3 )(C6H5)2CH2 CH2CH0 13.6+0.4

(Cyclohexanepropanal, 1 -methyl-2-oxo-3, 3-diphenyl-)

(RN-CAS Registry Number XXXXX-XX-X)

C6H6

( =0)(CH3)(C6H5)2CH2CH2C0CH3

1 3.6 ±0.4 (Cyclohexanone, 2-methyl-2-(3-oxobutyl)-6,6-diphenyl-)

(RN-CAS Registry Number 50592-55-7)

C6H6

( =0)(C6H5) = CHS(CH2)3CH3

1 3.7 ±0.4 (Cyclohexanone, 6-[(butylthio)methylene]-2,2-diphenyl-)

(RN-CAS Registry Number 50592-51-3)

C6H6

( =0)CH3 (C6H5)2CH2CH= C(CH3)C1 1 3.3 +0.4

(Cyclohexanone, 2-(3-chloro-2-butenyl)-2-methyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-54-6)

El

El

El

El

El

El

El

El

El

4018

4018

4018

4018

4018

4018

4018

4018

4018

C13 H,+

0 C13 H,o ** 7.93±0.02 (V) PE 3702

(Fluorene)

(RN-CAS Registry Number 86-73-7)

C13 H+

n

M3nll

'13 nll

c13 h

+

11

(C6H5)3 CH c6h5 (Benzene, 1 , 1', 1 " -methylidynetris-)

(RN-CAS-Registry Number 519-73-3)

c6h5 ch2c6h4oh oh

(Phenol, 4-(phenylmethyl)-)

(RN-CAS Registry Number 101-53-1)

c6h5 ch2c6h4och3 och3 (Benzene, 1 -methoxy-4-(phenylmethyl)-)

(RN-CAS Registry Number 834-14-0)

c6h5 ch2c6h4no2 no2 (Benzene, 1 -nitro-4-(phenylmethyl)-)

(RN-CAS Registry Number 1817-77-2)

10.9 PI 4055

1 1.0±0.2 El 3807

11.6+0.1 El 3807

10.5 ±0. 1 El 3807

C13 H,+

2 (C6H5 )2CH2 ** 8.80±0.02 (V) PE 3854

(Benzene, l,l'-methylenebis-)

(RN-CAS Registry Number 101-81-5)

C13H£ (C6H5)2CH2 ** 9.00±0.05 El 3806

(Benzene, l,l'-methylenebis-)

(RN-CAS Registry Number 101-81-5)

70
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

C13H£ CeHsQI

I

4CH3 ** 8.10±0.02 PE 3702

(l,l'-Biphenyl, 2-methyl-)

(RN-CAS Registry Number 643-58-3)

C13H£ C6H5 C6H4CH3 ** 7.95 ±0.02 PE 3702

(1,1 '-Biphenyl, 3-methyl-)

(RN-CAS Registry Number 643-93-6)

C13H,+

2 C6H5C6H4CH3 ** 7.80±0.02 PE 3702

(1,1 '-Biphenyl, 4-methyl-)

(RN-CAS Registry Number 644-08-6)

C^H^ C13H14 ** 8.50 PE 4036

( 1 ,2,4-Ethanylylidene- li/-cyclobuta[a/]pentalene, octahydro-5,7-bis (methylene)-)

(RN-CAS Registry Number 42607-62-5)

(ON-Other name: 8,1 l-Dimethylene-pentacyclo[5.4.0.02’ 6.0

3, 10.05, 9]tridecane)

C13H£ C13H16 ** 8.2 (V) PE 3999

(Bicyclo[5.4.2]trideca-7,9, 1 1, 12-tetraene)

(RN-CAS Registry Number XXXXX-XX-X)

C13Hf6 C13H16 ** 9.10 PE 4036

( 1 ,2,4-Ethanylylidene- l/7-cyclobuta[a/]pentalene, octahydro-5-methyl-7-methylene-, (la, layS

,2a,3ay8,4a,5a,5ay3,5b/3)-)

(RN-CAS Registry Number 42607-64—7)

C13H2+

6 ((CH3)3C)2C=CHCH(CH3)2 ** (RN-CAS Registry Number 50787-12-7)

c14h+ c14h10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

(RS-Average of two Rydberg series limits)

c14H+ c14h10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

cI 4h,+

o c14h10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

C14HJ0 C14H10 ** (Anthracene)

(RN-CAS Registry Number 120-12-7)

C14H10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

c14H+ c14h10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

C14Hji C„H10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

C14Hjo C14H10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

8.307±0.008 PE 3957

7.47 S 3857

7.4 PI 3586

7.40 PI 3877

7.40 PE 3668

7.40 (V) PE 3896

7.41 ±0.05 PE 3684

7.47±0.01 PE 3644

7.47±0.01 PE 3657

71
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CmHS PH **

'“'14rl 10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

7.35 CTS 3577

C14Hj PH **

v"14rl 10 (Anthracene)

(RN-CAS Registry Number 120-12-7)

7.4 CTS 3543

C14HS c6h5 c=cc6h5 (Benzene, 1 , l'-( 1 ,2-ethynediyl)bis-)

(RN-CAS Registry Number 501-65-5)

7.90±0.02 PE 3854

c14h+ c6h5c=cc6h5 (Benzene, 1,1'—(1 -2-ethynediyl)bis-)

(RN-CAS Registry Number 501-65-5)

8.0±0.05 PE 3684

C14H+0 PH **

'“'14rl 10 (Phenanthrene)

(RN-CAS Registry Number 85-01-8)

7.86±0.01 PE 3644

C14Hfo PH **

'-'14rl10 (Phenanthrene)

(RN-CAS Registry Number 85-01-8)

7.92±0.02 (V) PE 3702

CmHS PH ** (Phenanthrene)

(RN-CAS Registry Number 85-01-8)

7.92 ±0.05 PE 3684

C14H,+

o PH **

'-'14rl 10 (Phenanthrene)

(RN-CAS Registry Number 85-01-8)

8.03±0.01 RPD 3588

c14hS PH ** '—14rl 10 (Phenanthrene)

(RN-CAS Registry Number 85-01-8)

8.25 CTS 3577

c14h£ C6H8(C6H5)2 (Benzene, 1 , 1 '-(2-cyclohexen- 1 -ylidene)bis-)

(RN-CAS Registry Number 31158-25-5)

10.4±0.4 El 4018

c14h+ C6H10(C6H5)2 (Benzene, 1 , 1 '-cyclohexylidenebis-)

(RN-CAS Registry Number 21113-55-3)

10.8±0.4 El 4018

c14h,+

0 C6H9(CH3)(C6H5)2 (Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS Registry Number 32812-65-0)

10.2±0.4 El 4018

c14Hr0 C10H13(CH3)(C6H5)2 9.3±0.4

(Naphthalene, l,2,3,4,4a,5,6,7-octahydro-4a-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-50-2)

El 4018

C14H,+

0 QH8(=OXC6H5)2 (Cyclohexanone, 2,2-diphenyl-)

(RN-CAS Registry Number 22612-62-0)

10.7±0.4 El 4018

C14H,+

o C6H8(=0)(C6H5)2 (Cyclohexanone, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-68-1)

13.2±0.4 El 4018

c14h+ C6H7(=0)(CH3)(C6H5)2 (Cyclohexanone, 2-methyl-5,5-diphenyl-)

(RN-CAS Registry Number 50592-49-9)

9.6±0.4 El 4018

C14H,+

o C6H7(=0)(CH3)(C6H5)2 (Cyclohexanone, 6-methyl-2,2-diphenyl-)

10.3±0.4 El 4018

(RN-CAS Registry Number 50592-52-4)

72
Table of Ion Energetics Measurements—Continued

Ion

CiaH+

10

c14h+

10

c14h

+

10

c14h+

10

Ionization or Reactant Other appearance Method

products potential

(eV)

C6H8(OH)(CH3)(C6H5)2 10.5±0.4 El

(Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-47-7)

C6H6(=0)(CH3)(C6H5)2CH2CH2CH0 10.2±0.4 El

(Cyclohexanepropanal, 1 -methyl-2-oxo-3,3-diphenyl-)

(RN-CAS Registry Number XXXXX-XX-X)

C6H6(=0)(CH3)(C6H5)2CH2CH2C0CH3 10.0+0.4 El

(Cyclohexanone, 2-methyl-2-(3-oxobutyl)-6,6-diphenyl-)

(RN-CAS Registry Number 50592-55-7)

C6H6(=0)CH3(C6H5)2CH2CH=C(CH3)C1 10.5+0.4 El

(Cyclohexanone, 2-(3-chloro-2-butenyl)-2-methyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-54-6)

Ref.

4018

4018

4018

4018

C14H+2

' 14n12

C,.H 14AA12

C14H+

' 14n12

C14H+

c14h+2

'14n12

- 14n12

' 14n12

' 14n12

' 14n12

' 14n12

c6h5ch=chc6h5 ** (Benzene, l,l'-(l,2-ethenediyl)bis-, (E))

(RN-CAS Registry Number 103-30-0)

c6h5ch=chc6h5 ** (Benzene, l,l'-(l,2-ethenediyl)bis-, (E)-)

(RN-CAS Registry Number 103-30-0)

c6h5ch=chc6h5 ** (Benzene, 1,1'—( 1 ,2-ethenediyl)bis-,(Z))

(RN-CAS Registry Number 645-49-8)

c14h12 (Benzene, 1,1'—(1 ,2-ethenediyl)bis-)

(RN-CAS Registry Number 588-59-0)

c6h5ch=chc6h5 ** (Benzene, 1,1'—(1 ,2-ethenediyl)bis-)

(RN-CAS Registry Number 588-59-0)

7.70+0.02

7.76

7. 80 ±0.02

7.5

7.9

(C6H5)2C=CH2 (Benzene, l,l'-ethenylidenebis-)

(RN-CAS Registry Number 530=48-3)

C u **

14n12 (Phenanthrene, 9,10-dihydro-)

(RN-CAS Registry Number 776-35-2)

C6H8(C6H5)2 (Benzene, 1 , 1 '-(2-cyclohexen- 1 -ylidene)bis-)

(RN-CAS Registry Number 31158-25-5)

C6H10(C6H5)2 (Benzene, 1 , 1 '-cyclohexylidenebis-)

(RN-CAS Registry Number 21113-55-3)

C6H7(CH3)(C6H5)2 (Cyclohexene, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-48-8)

C6H9(CH3)(C6H5)2 (Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS Registry Number 32812-65-0)

C10H13(CH3)(C6H5)2 (Naphthalene, l,2,3,4,4a,5,6,7-octahydro-4a-methyl-

(RN-CAS Registry Number 50592-50-2)

C6H8(=0)(C6H5)2 (Cyclohexanone, 2,2-diphenyl-)

(RN-CAS Registry Number 22612-62-0)

8.00+0.02

7.55+0.02

9.8+0.4

9.8+0.4

9.8+0.4

10.1+0.4

9.5±0.4

2,2-diphenyl-)

9.5+0.4

73

PE

PE

PE

PI

CTS

PE

PE

El

El

El

El

El

El

3854

3657

3854

3586

3577

3854

3702

4018

4018

4018

4018

4018

4018
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

' 14“12

CmH14ll 12

' 14 n12

' 14 n12

' 14** 12

' 14n12

' 14“12

C14H,+

2

c14Hfi

C6H8

( =0)(C6H5)2 10.0±0.4

(Cyclohexanone, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-68-1)

C6H7( = 0)(CH3 )(C6H5)2 10.0±0.4

(Cyclohexanone, 2-methyl-5,5-diphenyl-)

(RN-CAS Registry Number 50592-49-9)

C6H7( =0)(CH3)(C6H5)2 10.4±0.4

(Cyclohexanone, 6-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-52-4)

C6H8 (OH)(CH3)(C6H5)2 10. 1 ±0.4

(Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-47-7)

C6H6

( =0)(CH3)2(C6H5)2 9.9±0.4

(Cyclohexanone, 2, 2-dimethyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-53-5)

C6H6(=0)(CH3)(C6H5)2CH2CH2CH0 10.3 ±0.4

(Cyclohexanepropanal, 1 -methyl-2-oxo-3, 3-diphenyl-)

(RN-CAS Registry Number XXXXX-XX-X)

C6H6

( =0)(CH3)(C6H5)2CH2CH2 C0CH3 10.5 ±0.4

(Cyclohexanone, 2-methyl-2-(3-oxobutyl)-6,6-diphenyl-)

(RN-CAS Registry Number 50592-55-7)

C6H6( =0)(C6H5) =CHS(CH2)3CH3

1 0. 1 ±0.4 (Cyclohexanone, 6-[(butylthio)methylene]-2,2-diphenyl-)

(RN-CAS Registry Number 50592-51-3)

C6H6( = 0)CH3(C6H5)2CH2CH=C(CH3)C1 10.0±0.4

(Cyclohexanone, 2-(3-chloro-2-butenyl)-2-methyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-54-6)

El

El

El

El

El

El

El

El

El

4018

4018

4018

4018

4018

4018

4018

4018

4018

' 14n14

cI 4h,+

4

C14 H

+

14

' 14^14

QHsCH.CH.QHs

(Benzene, 1 , l'-( 1 ,2-ethanediyl)bis-)

(RN-CAS Registry Number 103-29-7)

(C6H4CH3)2 (1,1 '-Biphenyl, 2,2'-dimethyl-)

(RN-CAS Registry Number 605-39-0)

(C6H4CH3)2 (l,l'-Biphenyl, 3,3'-dimethyl-)

(RN-CAS Registry Number 612-75-9)

C6H5 C6H4C2 H5 (1,1 '-Biphenyl, 2-ethyl-)

(RN-CAS Registry Number 1812-51-7)

9.00±0.05 El 3806

8.05±0.02 PE 3702

7.85±0.02 PE 3702

8.55±0.02 (V) PE 3702

c14h+ C10H7(CH2)3CH3 (Naphthalene, 1 -butyl-)

(RN-CAS Registry Number 1634-09-0)

7.76 PE 3960

c14 h+ ((CH3)3C)2C=CHC(CH3)3 ** (RN-CAS Registry Number 28923-90-2)

8.169±0.012 PE 3957

c15 h9" c14h9ch3 h2 ±h

(Phenanthrene, 4-methyl-)

(RN-CAS Registry Number 832-64-4)

(MT-Metastable transition(s) observed)

14.4±0.1 El 3454

74
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c15h9+ C14H8(CH3)2 (Phenanthrene, 2,7-dimethyl-)

(RN-CAS Registry Number 1576-69-8)

c15h9+ c14h8(ch3)2 (Phenanthrene, 4,5-dimethyl-)

(RN-CAS Registry Number 3674-69-9)

C15H9+ C14H6(CH3)4 3CH3 (Phenanthrene, 2,4,5,7-tetramethyl-)

(RN-CAS Registry Number 7396-38-5)

(MT-Metastable transition(s) observed)

C15H9+ C14H6(CH3)4 3CH3 (Phenanthrene, 3,4,5,6-tetramethyl-)

(RN-CAS Registry Number 7343-06-8)

(MT-Metastable transition(s) observed)

17.6±0.1 El 3454

15.1 ±0.1 El 3454

14.5±0.1 El 3454

16.5±0.1 El 3454

CjsHi'i C14H9CH3 H

(Phenanthrene, 4-methyl-)

(RN-CAS Registry Number 832-64-4)

C15H+ C14H8(CH3)2 ch3 (Phenanthrene, 2,7-dimethyl-)

(RN-CAS Registry Number 1576-69-8)

CISHJ| C14H8(CH,)2 CH3 (Phenanthrene, 4,5-dimethyl-)

(RN-CAS Registry Number 3674-69-9)

(MT-Metastable transition(s) observed)

c15 h+ c14h9ch3 (Phenanthrene, 1 -methyl-)

(RN-CAS Registry Number 832-69-9) c,5hs c14h,ch,

(Phenanthrene, 2-methyl-)

(RN-CAS Registry Number 2531-84-2)

c15h+ c14h9ch3 (Phenanthrene, 3-methyl-)

(RN-CAS Registry Number 832-71-3)

c15h+ c14h9ch3 (Phenanthrene, 4-methyl-)

(RN-CAS Registry Number 832-64-4)

c15h+ c14h9ch3 (Phenanthrene, 4-methyl-)

(RN-CAS Registry Number 832-64-4)

c15h+ c14h9ch3 (Phenanthrene, 9-methyl-)

(RN-CAS Registry Number 883-20-5)

12.0±0.1 El 3454

13.5±0.1 El 3454

10.8 ±0.1 El 3454

7.7±0.03 RPD 3588

7.9±0.04 RPD 3588

7.68±0.01 RPD 3588

7.70±0.02 RPD 3588

7.1 ±0.1 El 3454

7.46±0.03 RPD 3588

C15H+ C6H10(C6H5)2 10.3 ±0.4 El 4018

(Benzene, 1 , 1 '-cyclohexylidenebis-)

(RN-CAS Registry Number 21113-55-3)

C15Hf3 C6H9(CH3)(C6H5)2 10.6±0.4 El 4018

(Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS Registry Number 32812-65-0)
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref.

products potential

(eV)

'15“13

M5n13

'15 n13 CM

'15 n13

'15 n13

'15 n13

c15hS

C.5H+3

C15H+3

CwHfi

C.5H.+3

C10H13 (CH3)(C6H5)2 10.3 ±0.4 El

(Naphthalene, l,2,3,4,4a,5,6,7-octahydro-4a-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-50-2)

C6H8( =0)(C6H5)2 9.7±0.4 El

(Cyclohexanone, 2,2-diphenyl-)

(RN-CAS Registry Number 22612-62-0)

C6H8( = 0)(C6H5)2 10.5±0.4 El

(Cyclohexanone, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-68-1)

C6H7(=0)(CH3)(C6H5)2 10.8±0.4 El

(Cyclohexanone, 2-methyl-5, 5-diphenyl-)

(RN-CAS Registry Number 50592-49-9)

C6H7(=0)(CH3)(C6H5)2 10.3±0.4 El

(Cyclohexanone, 6-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-52-4)

C6H8(OH)(CH3)(C6H5)2 10.1 ±0.4 El

(Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-47-7)

C6H6(=0)(CH3)2(C6H5)2 10.3±0.4 El

(Cyclohexanone, 2, 2-dimethyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-53-5)

C10H11 (=O)(CH3)(C6H5)2 9.9±0.4 El

(2(3//)-Naphthalenone,4,4a,5,6,7,8-hexahydro-4a-methyl-7,7-diphenyl-)

(RN-CAS Registry Number 50786-03-3)

C6H6(=0)(CH3)(C6H5)2CH2CH2CH0 10.5±0.4 El

(Cyclohexanepropanal, l-methyl-2-oxo-3,3-diphenyl-)

(RN-CAS Registry Number XXXXX-XX-X)

C6H6(=0)(CH3)(C6H5)2 CH2CH2C0CH3 10.6±0.4 El

(Cyclohexanone, 2-methyl-2-(3-oxobutyl)-6,6-diphenyl-)

(RN-CAS Registry Number 50592-55-7)

C6H6(=0)(C6H5)=CHS(CH2)3CH3 10.8±0.4 El

(Cyclohexanone, 6-[(butylthio)methylene]-2,2-diphenyl-)

(RN-CAS Registry Number 50592-51-3)

C6H6(=0)CH3(C6H5)2CH2CH=C(CH3)C1 10.6±0.4 El

(Cyclohexanone, 2-(3-chloro-2-butenyl)-2-methyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-54-6)

4018

4018

4018

4018

4018

4018

4018

4018

4018

4018

4018

4018

CM C13H8(CH3)2 (9/f-Fluorene, 9,9-dimethyl-)

(RN-CAS Registry Number 4569-45-3)

7.8 (V) PE 4081

cM6 C6H5C6H4CH(CH3)2 (l,l'-Biphenyl, 2-isopropyl-)

(RN-CAS Registry Number 19486-60-3)

8.50±0.02 (V) PE 3702

CMe

(l,l'-Biphenyl, 2-propyl-)

(RN-CAS Registry Number 20282-28-4)

8.50±0.02 (V) PE 3702

cMo r u **

'~16rl 10 7.41 (V) PE 3951

(Pyrene)

(RN-CAS Registry Number 129-00-0)

76
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C16Hf0 c16h10 (Pyrene)

(RN-CAS Registry Number 129-00-0)

7.45±0.01 PE 3657

C16Hto c16h10 (Pyrene)

(RN-CAS Registry Number 129-00-0)

7.45 CTS 3577

c16h+ C14H8(CH3)2 (Phenanthrene, 2,7-dimethyl-)

(RN-CAS Registry Number 1576-69-8)

17.7 ±0.

1

El 3454

c16h+ C14H8(CH3)2 (Phenanthrene, 4,5-dimethyl-)

(RN-CAS Registry Number 3674-69-9)

>16 El 3454

C16H/i C14H6(CH3)4 2CH3 +H

(Phenanthrene, 2,4,5,7-tetramethyl-)

(RN-CAS Registry Number 7396-38-5)

(MT-Metastable transition(s) observed)

15.6±0.1 El 3454

C16H+ C14H6(CH3)4 2CH3 +H

(Phenanthrene, 3,4,5,6-tetramethyl-)

(RN-CAS Registry Number 7343-06-8)

(MT-Metastable transition(s) observed)

14.3±0.1 El 3454

c16h+ c10h7c6h5 (Naphthalene, 2-phenyl-)

(RN-CAS-Registry Number 612-94-2)

C16HS C„H6(CH3)4 2CH3 (Phenanthrene, 2,4,5,7-tetramethyl-)

(RN-CAS Registry Number 7396-38-5)

(MT-Metastable transitions) observed)

C16H+ C14H6(CH3)4 2CH3 (Phenanthrene, 3,4,5,6-tetramethyl-)

(RN-CAS Registry Number 7343-06-8)

(MT-Metastable transitions) observed)

C16H,+

3 C16H14 H 13.5 ±0.1 El 3454

(Phenanthrene, 2,7-dimethyl-)

(RN-CAS Registry Number 1576-69-8)

C16H£ C14H8(CH3)2 H 12.3 ±0.1 El 3454

(Phenanthrene, 4,5-dimethyl-)

(RN-CAS Registry Number 3674-69-9)

7.75 PE 4066

14.0±0.1 El 3454

13.5±0.1 El 3454

C16H£ C14H8(CH3)2 ** 8.0±0.1 El 3454

(Phenanthrene, 2,7-dimethyl-)

(RN-CAS Registry Number 1576-69-8)

C16H& C14H8(CH3)2 ** 7.6±0.1 El 3454

(Phenanthrene, 4,5-dimethyl-)

(RN-CAS Registry Number 3674-69-9)

C16H£ C6H6(=0)(C6H5 )2 9.3±0.4 El 4018

(2-Cyclohexen-l-one, 4,4-diphenyl-)

(RN-CAS Registry Number 4528-64-7)

77
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C16H£ C6H8(=0)(C6H5)2 9.6±0.4

(Cyclohexanone, 2,2-diphenyl-)

(RN-CAS Registry Number 22612-62-0)

El 4018

C16H,+

4 C6H7( =0)(CH3 )(C6H5)2 9.2±0.4

(Cyclohexanone, 6-methyl-2,2-diphenyl-)

(RN-CAS Registry Number 50592-52-4)

El 4018

c16h^ C6H6(=0)(CH3)2(C6H5)2 9.4±0.4

(Cyclohexanone, 2, 2-dimethyl-6, 6-diphenyl-)

(RN-CAS Registry Number 50592-53-5)

El 4018

c16h+ C6H6( =0)(CH3)(C6H5)2 CH2CH2CH0 9.4±0.4

(Cyclohexanepropanal, l-methyl-2-oxo-3, 3-diphenyl-)

(RN-CAS Registry Number XXXXX-XX-X)

El 4018

C16H,+

4 C6H6

( =0)(CH3)(C6H5)2CH2CH2C0CH3 9.3 ±0.4

(Cyclohexanone, 2-methyl-2-(3-oxobutyl)-6,6-diphenyl-)

(RN-CAS Registry Number 50592-55-7)

El 4018

C16H+ C6H6

( = 0)CH3 (C6H5)2CH2CH= C(CH3)C1 9. 1 ±0.4

(Cyclohexanone, 2-(3-chloro-2-butenyl)-2-methyl-6,6-diphenyl-)

(RN-CAS Registry Number 50592-54-6)

El 4018

' 16n16

' 16n16

C16H16 ** 8.08 (V)

(Tricyclo[8 . 2. 2.

4,7]hexadeca-4,6, 1 0, 1 2, 1 3 , 1 5-hexaene)

(RN-CAS Registry Number 1633-22-2)

(ON-Other name: [2.2]Paracyclophane)

C16H16 ** 8.24 (V)

(Tricyclo[9. 3 .1.1

4,8]hexadeca- 1(1 5),4, 6, 8(16), 11,1 3-hexaene)

(RN-CAS Registry Number 2319-97-3)

(ON-Other name: [2.2]Metacyclophane)

PE

PE

(Benz[a]anthracene)

(RN-CAS Registry Number 56-55-3)

78

4088

4088

C16Hjg C6H5 C6H4C4H9 (l,l'-Biphenyl, 2-butyl-)

(RN-CAS Registry Number XXXXX-XX-X)

8.50±0.02 (V) PE 3702

CpHJ^ C17H12 **

(1,1 '-Spirobi[ 1/f-indene])

(RN-CAS Registry Number 165-42-4)

7.80 (V) PE 4083

c17 h+ c14h6(ch3)4 ch3 (Phenanthrene, 2,4,5,7-tetramethyl-)

(RN-CAS Registry Number 7396-38-5)

(MT-Metastable transition(s) observed)

1 1.5±0.1 El 3454

Ci7Hj^ C18 H18 CH3 (Phenanthrene, 3,4,5,6-tetramethyl-)

(RN-CAS Registry Number 7343-06-8)

(MT-Metastable transition(s) observed)

1 1 .5 ±0.El 3454

C18H10 ** (Naphthacene)

(RN-CAS Registry Number 92-24-0)

6.9 PI 3586

C„H£ C„H,2 7.42 (V) PE 4039
Table of Ion Energetics Measurements—Continued

Ion

c18h+

c18h+

C18h£

c18h+

c18h+2

c18h,+

2

C18H£

c18h+

C18H£

c18h+

c18h+

c18 h,+

2

C18H£

ClgH^

Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C H ** (Benz[a]anthracene)

(RN-CAS Registry Number 56-55-3)

7.47±0.01 PE 3644

n u **

'^18rl 12 (Benz[a]anthracene)

(RN-CAS Registry Number 56-55-3)

7.56±0.01 PE 3657

r

1 h **

'~'18n12 (Benz[a]anthracene)

(RN-CAS Registry Number 56-55-3)

7.5 CTS 3577

C^ M **

18rl 12 (Benzo[c]phenanthrene)

(RN-CAS Registry Number 195-19-7)

7.62 (V) PE 4039

r m **

'-'18xl12 (Chrysene)

(RN-CAS Registry Number 218-01-9)

7.60±0.01 PE 3644

PM ** M8n12 (Chrysene)

(RN-CAS Registry Number 218-01-9)

7.61 (V) PE 4039

PMU **

18n12 (Chrysene)

(RN-CAS Registry Number 218-01-9)

7.75 CTS 3577

PM **

'-'18rl12 (Naphthacene)

(RN-CAS Registry Number 92-24-0)

7.01 PE 3668

PM ** ^i8rii2 (Naphthacene)

(RN-CAS Registry Number 92-24-0)

7.01 (V) PE 4039

PM **

<-,18*1.12 8.06 (V) PE 3647

(Tetracyclo[6.6.2.1 3’ 13 .l 6’ 10]octadeca-l,3(17),4,6,8,10(18),ll,13,15-nonaene)

(RN-CAS Registry Number 27313-56-0)

(ON-Other name: [2.2.2](l,3,5)cyclophane-l,9,17-triene) PM **

<^18*112 8.06 (V) PE 4088

(Tetracyclo[6.6.2.1 3’ 13 .l.l

6’ 10]octadeca-1, 3(17),4, 6, 8, 10(18), 11,13, 15-nonane)

(RN-CAS Registry Number 27313-56-0)

(ON-Other name: [2.2.2](l,3,5)Cyclophane-l,9,17-triene) PM **

<-.18*112 (Triphenylene)

(RN-CAS Registry Number 217-59-4)

7.84±0.01 PE 3657

PM **

<^18*li2 (Triphenylene)

(RN-CAS Registry Number 217-59-4)

7.86 (V) PE 4039

PM **

<-18*li2 (Triphenylene)

8.1 CTS 3577

(RN-CAS Registry Number 217-59-4)

C18H£ C18H14 ** 7.99±0.01 PE 3657

(1,1':2',1"-Terpheny1) (RN-CAS Registry Number 84-15-1)

C18H£ C18H14 ** 8.01 ±0.01 PE 3657

( 1 , 1' :3

1

-Terpheny1) (RN-CAS Registry Number 92-06-8)

79
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

cI8 h,+

4 PH **

'-'18n14 (l,r:4',l'-Terphenyl)

(RN-CAS Registry Number 92-94—4)

7.78±0.01 PE 3657

C18 H+6 C16H10(CH3)2 (Pyrene, 10b,10c-dihydro-10b,10c-dimethyl-, trans-)

(RN-CAS Registry Number 956-84-3)

6.7 PE 3948

CM C14H6(CH3)4 (Phenanthrene, 2,4,5,7-tetramethyl-)

(RN-CAS Registry Number 7396-38-5)

7.8±0.1 El 3454

CM, C14H6(CH3)4 (Phenanthrene, 3,4,5,6-tetramethyl-)

(RN-CAS Registry Number 7343-06-8)

7.5±0.1 El 3454

CM, C18H18 ** 7.70 (V)

(Tetracyclo[6.6.2.

3’ 13

. l 610]octadeca-l,3(17),6,8, 10(18),13-hexaene)

(RN-CAS Registry Number 27165-88-4)

(ON-Other name: [2.2.2](l,3,5)Cyclophane)

PE 4088

CM, C18 H18 ** 7.70 (V)

(Tetracyclo[6.6.2.1 3 ’ 13 .l

6’ 10]octadeca-l,3(17),6,8,10(18),13-hexaene)

(RN-CAS Registry Number 27165-88-4)

(ON-Other name: [2.2.2](l,3,5)cyclophane)

PE 3647

CM C6H10(C6H5)2 (Benzene, 1 ,

' -cyclohexylidenebis-)

(RN-CAS-Registry Number 21113-55-3)

8.9±0.2 El 4074

CM* (C6H5)3CH

(Benzene, 1 , 1', 1 " -methylidynetris-)

(RN-CAS-Registry Number 519-73-3)

8.34±0.03 PI 4055

CM QH^CH^CeH^

(Cyclohexene, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592-48-8)

8.7±0.4 El 4018

CM C6H8(OH)(CH3)(C6H5)2 h2o

(Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS Registry Number 50592^17-7)

9.2±0.4 El 4018

cMi C6H9(CH3XC6H5)2 (Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS-Registry Number 32812-65-0)

8.8±0.2 El 4074

CM2 C6H9(CH3XC6H5)2 (Benzene, 1 , 1 '-(4-methylcyclohexylidene)bis-)

(RN-CAS-Registry Number 32812-65-0)

8.8±0.2 El 4074

^20^12 C2oHi2 ** (Benzo[a]pyrene)

(RN-CAS Registry Number 50-32-8)

7.12±0.01 PE 3644

^20^12 C2oH12 7.39±0.01 PE 3657

(Benzo[a]pyrene)

(RN-CAS Registry Number 50-32-8)

80
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

CjqH£ C2oH12 ** 6.90±0.01 PE 3657

(Perylene)

(RN-CAS Registry Number 198-55-0)

CjoH^ QoHn ** 7.00±0.01 PE 3644

(Perylene)

(RN-CAS Registry Number 198-55-0)

CjoH^ C2oH12 ** 7.1 CTS 3577

(Perylene)

(RN-CAS Registry Number 198-55-0)

CjoH^ C14H9C6H5 ** 7.25 (V) PE 3896

(Anthracene, 9-phenyl-)

(RN-CAS Registry Number 602-55-1)

CmHS

<^,11+

C2!H+

C2.H+

C22H+

C22H+

C22H+

C22H+

C10H6(CH3)C10H6CH3 ch3 (l,r-Binaphthyl, 2,2'-dimethyl-)

(RN-CAS Registry Number 32834-84-7)

C1 oH6(CH3)C10H6CH3 ch3 (1,1 '-Binaphthyl, 3,3'-dimethyl-)

(RN-CAS Registry Number 34042-82-5)

C10H6(CH3)C10H6CH3 ch3 (1,1 '-Binaphthyl, 7,7'-dimethyl-)

(RN-CAS Registry Number 34003-80-0)

C10H6(CH3)C10H6CH3 ch3 (ljl'-Binaphthyl, 8,8'-dimethyl-)

(RN-CAS Registry Number 32693-05-3)

C22H12 (Benzo[g/rf]perylene)

(RN-CAS Registry Number 191-24-2)

13.25 El

12.25 El

12.75 El

11.50 El

7.19±0.01 PE

C22H14 ** 7.35 ±0.01 PE

(3,4-Benzotetraphene)

(RN-CAS Registry Number XXXXX-XX-X)

C,2H14 ** 6.64 PE

(Pentacene)

(RN-CAS Registry Number 135-48-8)

C22H14 ** 6.74±0.01 PE

(Pentacene)

(RN-CAS Registry Number 135-48-8)

3477

3477

3477

3477

3644

3657

3668

3644

C^Hjg C10H6(CH3)C10H6CH3 ** 8.20 El 3477

(l,l'-Binaphthyl, 2,2'-dimethyl-)

(RN-CAS Registry Number 32834-84-7)

C^HJg C10H6(CH3)C10H6CH3 ** 8.00 El 3477

(l,l'-Binaphthyl, 3,3 '-dimethyl-)

(RN-CAS Registry Number 34042-82-5)

CbHJ C10H6(CH3)C10H6CH3 ** 8.15 El 3477

(1,1 '-Binaphthyl, 7,7'-dimethyl-)

(RN-CAS Registry Number 34003-80-0)

81
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c22h,+

8 CI 0H6(CH3)C10H6CH3 (l,l'-Binaphthyl, 8, 8'-dimethyl-)

(RN-CAS Registry Number 32693-05-3)

8.00 El 3477

c23 h2+

6 C10H13 (CH3)(C6H5)2 ** 8.9±0.2

(Naphthalene, 1,2, 3,4, 4a,5,6, 7-octahydro-4a-methyl-2,2-diphenyl-)

(RN-CAS-Registry Number 50592-50-2)

El 4074

C24Hf2 C24H12 (Coronene)

(RN-CAS Registry Number 191-07-1)

7.34 (V) PE 3951

c24h12 (Coronene)

(RN-CAS Registry Number 191-07-1)

7.5 CTS 3577

C24H2+

2 C10H7(CH2)4C1 ()H7 (Naphthalene, 1,1'—(1 ,4-butanediyl)bis-)

(RN-CAS Registry Number 29571-17-3)

7.67 PE 3960

C25H

C

25H16 ** 7.7 (V) PE 4081

(9,9'-Spirobi[9//-fluorene])

(RN-CAS Registry Number 159-66-0)

C32H,+

4 C32H14 ** 6.86±0.01 PE 3644

(Ovalene)

(RN-CAS Registry Number 190-26-1)

C6H5 Be + (QHj^Be QHj 13.4±0.2 El 3815

(Beryllium, diphenyl-)

(RN-CAS Registry Number 22300-89-6)

C12 H10Be + (C6H5)2Be ** 9.20±0.10 El 3815

(Beryllium, diphenyl-)

(RN-CAS Registry Number 22300-89-6)

C12 H10B+ (C6H5)3 B QHj 10.2 PI 4055

(Borane, triphenyl-)

(RN-CAS-Registry Number 960-71-4)

C18 H15 B

+ (QH^B ** 8.60±0.03 PI 4055

(Borane, triphenyl-)

(RN-CAS-Registry Number 960-71-4)

N+ n2 N 24.4±0.25 El 3797

(RN-CAS Registry Number 7727-37-9)

N+ nh3 h2 +h <22.5 DC 3811

(RN-CAS Registry Number 7664—41-7)

N

+2 N2 N 60.3 ±2 El 3797

(RN-CAS Registry Number 7727-37-9)

82
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

N

+3 N2 N

(RN-CAS Registry Number 7727-37-9)

(HE-High kinetic energy ion)

-100 El 3452

N2tX2 2£ N2 ** (RN-CAS Registry Number 7727-37-9)

15.5812±0.0002 S 3561

N2t

22g) n2(RN-CAS Registry Number 7727-37-9)

15.60 (V) PE 4022

N2tX22^) N2 ** (RN-CAS-Registry Number 7727-37-9)

15.61 PE 4073

N2tA2ri„) N2 ** (RN-CAS Registry Number 7727-37-9)

16.695+0.002 PE 3935

N2tA2nj N2 ** (RN-CAS-Registry Number 7727-37-9)

16.73 PE 4073

N2t

2nj N2 ** (RN-CAS Registry Number 7727-37-9)

16.98 (V) PE 4022

N2t

22J n2(RN-CAS Registry Number 7727-37-9)

18.78 (V) PE 4022

N2tB225 N2 ** (RN-CAS Registry Number 7727-37-9)

18.87 (V) PE 3714

NjtC’Sj n2(RN-CAS Registry Number 7727-37-9)

24.6 (V) PE 3714

n2* N2 ** (RN-CAS Registry Number 7727-37-9)28.2 PE 3975

N2t

22^) N2 ** (RN-CAS Registry Number 7727-37-9)

35 (V) PE 3714

n2* N2 ** (RN-CAS Registry Number 7727-37-9)

36.5 PE 3975

Nj2^ n2(RN-CAS Registry Number 7727-37-9)

38.7 PE 3975

N2f2,5 n2(RN-CAS Registry Number 7727-37-9)

28-29 (V) PE 3714

N2f2^ N2 ** (RN-CAS Registry Number 7727-37-9)

32-33 (V) PE 3714

N2t

2 2^ n2(RN-CAS Registry Number 7727-37-9)

36-37 (V) PE 3714

W) N2 ** (RN-CAS Registry Number 7727-37-9)

43.3+0.9 AUG 3542

n2 + \a"5:u

+

) N2 ** (RN-CAS Registry Number 7727-37-9)

46.2+1.3 AUG 3542

N2 +2(A3ng) N2 ** (RN-CAS Registry Number 7727-37-9)47.2+1.3 AUG 3542

N2+ Xc1n.) n2(RN-CAS Registry Number 7727-37-9)

49.7+1.2 AUG 3542

N2 + \d^u+

) N2 ** (RN-CAS Registry Number 7727-37-9)

51.2+1.15 AUG 3542

N2 + VV) N2 ** (RN-CAS Registry Number 7727-37-9)

52.8 + 1.15 AUG 3542

N2 + W) N2 ** (RN-CAS Registry Number 7727-37-9)96.3 + 1.9 AUG 3542

83
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

n2 +2 n2 ** 43 El 3452

(RN-CAS Registry Number 7727-37-9)

n2 +2 n2+

28 El 3452

(RN-CAS Registry Number 13966-04-6)

NH+ nh3 h2 17.2 DC 3811

(RN-CAS Registry Number 7664-41-7)

nh2+ nh3 H 15.0 DC 3811

(RN-CAS Registry Number 7664-41-7)

nh2+ CH3 NH2 CH3 15.9 El 3808

(RN-CAS Registry Number 74-89-5)

NH3t

2 A,) NH3 ** (RN-CAS Registry Number 7664-41-7)

(HB-Threshold value approximately corrected for hot bands)

10.15 PE 3719

NH3fE) nh3 ** (RN-CAS Registry Number 7664-41-7)

14.98±0.02 PE 3719

NHjfA,) NH3 ** (RN-CAS Registry Number 7664-41-7)

27.0 (V) PE 3719

nh3+ NH3 ** (RN-CAS Registry Number 7664-41-7)10.2 DC 3811

ND,fA,) ND3 ** 10.21 PE 3719

(RN-CAS Registry Number 13550-49-7)

(HB-Threshold value approximately corrected for hot bands)

ND3t

2 E) ND3 ** (RN-CAS Registry Number 13550-49-7)

15.10±0.03 PE 3719

NH4+ C2H5 NH2 C2 H2 + H 12.72±0.02 RPD 3487

(RN-CAS Registry Number 75-04-7)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

NH4+ (CH3)2 NH C2 H2 + H 14.05 ±0.05 RPD 3487

(RN-CAS Registry Number 124-40-3)

(MT-Metastable transition(s) observed)

N2 H4t

2 A) n2 h4 9.91 (V) PE 3862

(RN-CAS Registry Number 302-01-2)

N2 H4+ n2 h4 10.07 PE 3747

N2 H4t

2 B)

(RN-CAS Registry Number 302-01-2)

N2 H4 10.64 (V) PE 3862

N2H4t

2A)

(RN-CAS Registry Number 302-01-2)

N2 H4 15.61 (V) PE 3862

N2 H4t

2 B,2A)

(RN-CAS Registry Number 302-01-2)

n2 h4 16.66 (V) PE 3862

(RN-CAS Registry Number 302-01-2)

n2h* n2 h4 24.5 PE 3715

(RN-CAS Registry Number 302-01-2)

n2hj* N2 H4 30.0 PE 3715

(RN-CAS Registry Number 302-01-2)

84
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

N3H

+

(

2A') hn3 ** 10.72±0.02 PE 3670

(RN-CAS Registry Number 7782-79-8)

N3H+

(

2A') hn3 ** 12.24±0.02 (V) PE 3670

(RN-CAS Registry Number 7782-79-8)

n3h

+ * hn3 ** 15.37±0.02 PE 3670

(RN-CAS Registry Number 7782-79-8)

n3h+ * hn3 ** 1 6. 8 ±0. 1 (V) PE 3670

(RN-CAS Registry Number 7782-79-8)

bh6n+ (BH3)(NH3) ** 9.44±0.02 PE 3699

(RN-CAS Registry Number xxxx-xx-x)

BjHfN? b3h6n3 ** 9.88 PE 3637

(Borazine)

(RN-CAS Registry Number 6569-51-3)

b3h6n3+ B3H6N3 ** 10.09 (V) PE 3673

(Borazine)

(RN-CAS Registry Number 6569-51-3)

B3H6N3 ** 10.14±0.01 PE 3506

(Borazine)

(RN-CAS Registry Number 6569-51-3)

CHN+(X2n) HCN ** 13.61±0.01 PE 3840

CHN+(A22)

(RN-CAS Registry Number 74-90-8)

HCN ** 14.00±0.01 PE 3840

CHN+(B22)

(RN-CAS Registry Number 74-90-8)

HCN ** 19.06±0.01 PE 3840

(RN-CAS Registry Number 74-90-8)

CHN+ HCN ** 13.71 EDD 3737

(RN-CAS Registry Number 74-90-8)

CH4N+ CjHjNOz 10.27±0.05 El 3571

(RN-CAS Registry Number 56-40-6)

ch5n+ ch3nh2 ** 8.80±0.02 PE 3890

CH5N+

(

2A')

(RN-CAS Registry Number 74-89-5)

ch3nh2 ** 9.64 (V) PE 4068

(RN-CAS-Registry Number 74-89-5)

ch5n+ ch3nh2 ** 9.65 (V) PE 4087

CH5N+

(

2A')

(RN-CAS Registry Number 74-89-5)

ch3nh2 ** 13.22 (V) PE 4068

CH5N+

(

2A')

(RN-CAS-Registry Number 74-89-5)

ch3nh2 ** 14.42 (V) PE 4068

CH5N+

(

2A')

(RN-CAS-Registry Number 74-89-5)

ch3nh2 ** 15.45 (V) PE 4068

CH5N+

(

2A")

(RN-CAS-Registry Number 74-89-5)

ch3nh2 ** 16.85 (V) PE 4068

(RN-CAS-Registry Number 74-89-5)

85
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C2H2 N+ c3 h4n2 hcn

(1 //-Imidazole)

(RN-CAS Registry Number 288-32-4)

13.2 El 3910

C2H4N

+ (CH3)2NCH=CHC^CH

(RN-CAS Registry Number 2206-24-8)

13.1 El 3674

c2 h4n+ (CjHj^NCH = CHC=CH

(RN-CAS Registry Number 1809-53-6)

13.6 El 3674

Q,H6N (CH3)2NCH=CHC=CH ch=chc=ch

(RN-CAS Registry Number 2206-24-8)

12.7 El 3674

C^N*

C2H7N+ c2h7 n

+

C2H7 N

+ c2h7n

+

*

75-04-7)

QHsNHj

(RN-CAS Registry Number

C2H5 NH2 (RN-CAS Registry Number

ch3 ch2nh2 (RN-CAS-Registry Number

(CH3)2NH

(RN-CAS Registry Number 124-40-3)

(CH3)2NH ** (RN-CAS Registry Number 124-40-3)

75-04-7)

** 75-04-7)

**

9.44±0. 18 (V) PE 3987

9.50 (V) PE 4032

9.50 (V) PE 4068

8.07 PE 3589

8.25 ±0.02 PE 3890

CiHN

CH=CCN ** (RN-CAS Registry Number 1070-71-9)

CH=CCN ** (RN-CAS Registry Number 1070-71-9)

11.6

11. 64 ±0.01

S

PI

3755

3929

C3 H6N

+ (C2H5)2NCH=CHC^CH

(RN-CAS Registry Number 1809-53-6)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): CH=CHC=CH+CH3 +H)

12.3 El 3674

c3 h6n+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

15.6±0.4 El 3634

c3 h6n

+ CH2(NF2)CH(NF2)CH3 (RN-CAS Registry Number 15403-25-5)

15.6±0.3 El 3634

c3 h6n

+ (CH3)2C(NF2)2 (RN-CAS Registry Number 19309-63-8)

15.4±0.3 El 3634

c3 h7n

+ ch2 =chch2nh2 ** (RN-CAS Registry Number 107-11-9)

8.76 PE 3864

^3119].^ c3 h9n

+ c3 h9n+

c3 h9n

+ c3h9n

+

N(CH3)3 (RN-CAS Registry Number 75-50-3)

(CH3)3 N

(RN-CAS Registry Number 75-50-3)

(CH3)3 N

(RN-CAS Registry Number 75-50-3)

(CH3)3N

(RN-CAS Registry Number 75-50-3)

/j-C3H7NH2 ** (RN-CAS-Registry Number 107-10-8)

86

7.95±0.10 PI 3729

7.83±0.02 PE 3890

8.45±0.01 (V) PE 3699

8.5±0.1 (V) PE 3661

9.44 (V) PE 4068
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c3h9n+ «o-C3H7NH2 ** (RN-CAS-Registry Number 75-31-0)

9.31 (V) PE 4068

C4H3 N+ (CH3)2NCH=CHC=CH 2CH3 15.1 El 3674

(RN-CAS Registry Number 2206-24-8)

(TR-Other product(s) thermochemically reasonable)

C4H3N+ C4H8NCH=CHC=CH C4H8 15.3 El 3674

(Pyrrolidine, l-(l-buten-3-ynyl)-)

(RN-CAS Registry Number 19352-85-3)

(TR-Other produces) thermochemically reasonable)

C4H3N+ (C2H5)2NCH=CHC=CH 2C2H4 +2H 16.5 El 3674

(RN-CAS Registry Number 1809-53-6)

(TR-Other produces) thermochemically reasonable)

C4H5N+ C4H5N ** 8.20±0.01 PI 4058

(l//-Pyrrole)

(RN-CAS-Registry Number 109-97-7)

C4H5N+ C4H5N ** 8.23 (V) PE 4009

(1 //-Pyrrole)

(RN-CAS Registry Number 109-97-7)

C4H5N+ C4H5N ** 8.40±0.05 El 3482

(1 //-Pyrrole)

(RN-CAS Registry Number 109-97-7)

C4H10N+ (Q>H5)3N C,H5 13.14 El 3674

(RN-CAS Registry Number 121-44-8)

C4HnN+ n-QIl^NII^ ** 9.40 (V) PE 4068

(RN-CAS-Registry Number 109-73-9)

C5H4N+ (CH3)2NCH=CHC=CH CH3 +H2 12.4 El 3674

(RN-CAS Registry Number 2206-24-8)

(TR-Other produces) thermochemically reasonable)

C5H4N+ C4H8NCH=CHC=CH C3H3 +H 15.0 El 3674

(Pyrrohdine, l-(l-buten-3-ynyl)-)

(RN-CAS Registry Number 19352-85-3)

(TR-Other produces) thermochemically reasonable)

c5h5n+ c5h5n **

(Pyridine)

(RN-CAS Registry Number 110-86-1)

c5h5n+ c5h5n **

(Pyridine)

(RN-CAS Registry Number 110-86-1)

(HB-Threshold value approximately corrected for hot bands)

CsHsN+^Aj) C5H5N **

(Pyridine)

(RN-CAS Registry Number 110-86-1)

c5h5n+ c5h5n **

(Pyridine)

(RN-CAS Registry Number 110-86-1)

9.4 PI 3586

9.263 PE 3707

9.59 (V) PE 3513

9.60±0.5 (V) PE 3685

87
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

c5 h5 n

+

(

2 a,?) c5h5 n ** 9.7 (V) PE 3832

Cs H,N+

(

2AJ

(Pyridine)

(RN-CAS Registry Number 110- 86- 1 ) C5 H5 N ** 9.73 (V) PE 3513

cs hs n-(2a2?)

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) C5 H5 N ** 9.8 (V) PE 3832

c5 h5 n+

(

2 b,)

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) C5 H5 N ** 10.5 (V) PE 3832

c5 h5 n+

(

2 b,)

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) C5 H5 N ** 10.50 (V) PE 3513

C5 HsN+

(

2B2)

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) C5H5 N ** 12.5 (V) PE 3832

c5 h5 n

+

(

2b,)

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) C5 H5 N ** 12.6 (V) PE 3832

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) c5 h5 n

+ C5H5 N ** 9.66±0.03 EDD 3626

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) c5 h5 n

+ C5 H5 N ** 9.70+0.05 El 3498

(Pyridine)

(RN-CAS Registry Number 110-86- 1 ) c5 h6n

+ (CH3)2NCH=CHC=CH ch3 11.2 El 3674

(RN-CAS Registry Number 2206-24-8)

c5 h6n+ c4h8 nch==CHC=CH ch2 =chch2 11.3 El 3674

(Pyrrolidine, 1 -( 1 -buten-3-yny1)-) (RN-CAS Registry Number 19352-85-3)

(TR-Other product(s) thermochemically reasonable)

C5 H6N

+ (C2H5)2NCH=CHC=CH C2H4 +CH3 13.9 El 3674

(RN-CAS Registry Number 1809-53-6)

(TR-Other product(s) thermochemically reasonable)

c5 h7n

+

c5 h7 n

+

C4H4N(CH3) **

(Pyrrole, 1 -methyl-)

(RN-CAS Registry Number 96-54-8)

c4h4nch3 **

(Pyrrole, 2-methyl-)

(RN-CAS Registry Number 636-41-9)

8.4

8.01 ±0.05

El

El

3580

3482

c5 h12n+ (C2H5) 3N ch3 (RN-CAS Registry Number 121-44-8)11.48 El 3674

c6h5 n

+ c5 h5 cn ** (Cyclopentadienecarbonitrile)

(RN-CAS Registry Number 27659-36-5)

9.7 El 3476

88
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

C6H6N

+ C6H4(NH2)COOH co+oh

(Benzoic acid, 3-amino-)

(RN-CAS Registry Number 99-05-8)

(MT-Metastable transition(s) observed)

C6H6N

+ C6H4(NH2)COOH co +oh

(Benzoic acid, 4-amino-)

(RN-CAS Registry Number 150-13-0)

(MT-Metastable transition(s) observed)

C6H6N+ C6H4(N02)NH2 no2 (Benzenamine, 3-nitro-)

(RN-CAS Registry Number 99-09-2)

c6h6n+ c6h4(no2)nh2 no2 (Benzenamine, 4-nitro-)

(RN-CAS Registry Number 100-01-6)

14.26±0.2 El

14.77+0.2 El

11.23+0.1 El

11.53+0.1 El

3973

3973

3447

3447

c6h,n+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.7 PI 3586

c„h7n+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.70+0.01 PI 4028

c6h7n+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.65+0.02 PE 3890

c6h7n

+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.66 PE 3988

c6h7n+ C6H5NH2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.71 PE 3955

c6h7n+ C6H5NH2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

8.05 (V) PE 4106

c6h7n

+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.89+0.03 EDD 3626

c6h7n

+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.89 EDD 3485

CeHvN

+ QH5NH2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.61+0.1 El 3788

QH7N+ c6h5nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

7.63 El 3845

QH,N+ c6h5 nh2 (Benzenamine)

(RN-CAS Registry Number 62-53-3)

8.09+ <0.1 El 3735

c6h7n

+ c5h4nch3 **

(Pyridine, 2-methyl-)

9.20+0.05 (V) PE 3685

(RN-CAS Registry Number 109-06-8)

89
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c6 h7 n

+ c5 h4nch3 **

(Pyridine, 4-methyl-)

(RN-CAS Registry Number 108-89-4)

c6h7 n

+ c5 h4nch3 **

(Pyridine, 4-methyl)

(RN-CAS Registry Number 108-89-4)

C6 H7 N

+ C6 H4(NH2)OCH3 ch2o

(Benzenamine, 3-methoxy-)

(RN-CAS Registry Number 536-90-3)

C6H7 N

+ C6H4(NH2)OCH3 HCHO

(Benzenamine, 4-methoxy-)

(RN-CAS Registry Number 104-94-9)

C6H7 N

+ c6h5 nhcoch3 ch2 =c=

(Acetamide, iV-phenyl-)

(RN-CAS Registry Number 103-84-4)

C6H7 N+ C6H5 NH2Cr(CO)3 (Chromium, (i7

6-benzenamine)tricarbonyl-)

(RN-CAS Registry Number 12108-11-1)

C6H8 N+ (CH3)2NCH= CHC^CH H 10.1 El 3674

(RN-CAS Registry Number 2206-24-8)

(CH3)2NCH = CHC=CH ** 7.7 El 3674

(RN-CAS Registry Number 2206-24-8)

C4H4NC2 H5 ** 7.97±0.05 El 3482

(Pyrrole, 2-ethyl-)

(RN-CAS Registry Number 1551-06-0)

C6H,jN+ (C2H5)3 N ** 8.19±0.05 (V) PE 3987

(RN-CAS Registry Number 121-44-8)

c6h9n

+ c6h9n

+

9.50±0.05 (V) PE 3685

9.55±0.05 El 3498

10.5 1 ±0.

El 3446

9.58 El 3845

10.45 ±0.03 El 3483

7.96±0.1 El 3788

C7H4N

+ C6H4(CN)COOH CO+OH 15.68 ±0.2 El 3973

(Benzoic acid, 4-cyano-)

(RN-CAS Registry Number 619-65-8)

(MT-Metastable transition(s) observed)

C7H4N

+ C6H4(N02)CN N02 12.25 ±0.1 El 3447

(Benzonitrile, 3-nitro-)

(RN-CAS Registry Number 619-24-9)

C7H4N

+ QH/NO^CN N02 12.42 ±0.1 El 3447

(Benzonitrile, 4-nitro-)

(RN-CAS Registry Number 619-72-7)

C7H5 N

+ C6H5CN ** 9.62 PE 3938

(Benzonitrile)

(RN-CAS Registry Number 100-47-0)

C7H5 N

+ C6H5 CN ** 9.7 El 3916

(Benzonitrile)

(RN-CAS Registry Number 100-47-0)

C7H5 N

+ C6H5CN ** 9.77 El 3845

(Benzonitrile)

(RN-CAS Registry Number 100-47-0)

90
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

c6h5cn **

(Benzonitrile)

(RN-CAS Registry Number 100-47-0)

C6H4(CN)OCH3 ch2o

(Benzonitrile, 3-methoxy-)

(RN-CAS Registry Number 1527-89-5)

C6H4(CN)OCH3 ch2o

(Benzonitrile, 4-methoxy-)

(RN-CAS Registry Number 874-90-8)

C6H4(CN)OCH3 hcho

(Benzonitrile, 4-methoxy-)

(RN-CAS Registry Number 874-90-8)

(CD-Metastable transition indicates 0.36 eV kinetic energy release)

C7H8 N+ C6H4(NH2)CH3 h

(Benzenamine, 2-methyl-)

(RN-CAS Registry Number 95-53-4)

C7H8N+ C6H4(NH2)CH3 h

(Benzenamine, 4-methyl-)

(RN-CAS Registry Number 106-49-0)

C7H8 N

+ C6H4(NH2)C4H9 (Benzenamine, 3-butyl-)

(RN-CAS Registry Number 5369-17-5)

C^N* C6H4(NH2)C4H9 (Benzenamine, 4-butyl-)

(RN-CAS Registry Number 104-13-2)

C^N* C6H5CH2C6H4NH2 c6h5 (Benzenamine, 4-(phenylmethyl)-)

(RN-CAS Registry Number 1135-12-2)

c7h8 n+ (C6H4NH2)2CH2 (Benzenamine, 4,4'-methylenebis-)

(RN-CAS Registry Number 101-77-9)

C7H8 N+ C6H4(CH3)NHCOCH3 ch3co

(Acetamide, iV-(2-methylphenyl)-)

(RN-CAS Registry Number 120-66-1)

C7H8 N

+ C6H4(CH3)NHCOCH3 ch3 co

(Acetamide, 7V-(4-methylphenyl)-)

(RN-CAS Registry Number 103-89-9)

C7H8N

+ C6H4(NH2)CH2CH2OCOCH3 (Benzeneethanol, 4-amino-, acetate(ester))

(RN-CAS Registry Number 33709-38-5)

c7h8n+ C6H4(N02)CH2C6H4NH2 (Benzenamine, 4-[(4-nitrophenyl)methyl]-)

(RN-CAS Registry Number 726-17-0)

C7H5N+

c7h5 n+

c7h5n+

C7H5 N+

C7H9N

+ C6H4(NH2)CH3 ** (Benzenamine, 2-methyl-)

(RN-CAS Registry Number 95-53-4)

C7H9N

+ C6H4(NH2)CH3 ** (Benzenamine, 2-methyl-)

(RN-CAS Registry Number 95-53-4)

Ionization or appearance Method Ref.

potential

(eV)

10.02 ±<0.1 El 3735

12.23±0.1 El 3446

12.30±0.1 El 3446

12.39 El 3845

1 1.25 ±0.05 PI 4028

11. 00 ±0.1 PI 4028

12. 13±0.

1

El 3629

11.10±0.1 El 3629

10.6±0.1 El 3807

10.6±0.1 El 3807

13.97±0.02 El 3631

14.21 ±0.02 El 3631

11.00 El 3590

11.6±0.2 El 3807

7.44 ±0.02 PI 4028

7.45±0.02 PE 3890

91
Table of Ion Energetics Measurements—Continued

C7H9N

+

C7H9N

+

C7H9N

+

c7h9n+

C^N*

C7H9N

+

C1H9N+

C7H9N

+

C7H9N+

C7H9N

+

C7H9N

+

C^N*

c,h9n

+

C^N*

c,h9n+

Reactant

C6H4(NH2)CH3 (Benzenamine, 2-methyl-)

(RN-CAS Registry Numbe

C6H4(NH2)CH3 (Benzenamine, 2-methyl-)

(RN-CAS Registry Numbe

C6H4(NH2)CH3 (Benzenamine, 3-methyl-)

(RN-CAS Registry Numbe

C6H4(NH2)CH3 (Benzenamine, 3-methyl-)

(RN-CAS Registry Numbe

C6H4(NH2)CH3 (Benzenamine, 4-methyl-)

(RN-CAS Registry Numbe

C6H4(NH2)CH3 (Benzenamine, 4-methyl-)

(RN-CAS Registry Numbe

C6H4(NH2)CH3 (Benzenamine, 4-methyl-)

(RN-CAS Registry Numbe

c6h5 nhch3 (Benzenamine, A-methyl-)

(RN-CAS Registry Numbe

c6h5nhch3 (Benzenamine, A-methyl-)

(RN-CAS Registry Numbe

C5 H3 N(CH3)2 (2, 6-Dimethylpyridine)

(RN-CAS Registry Numbe

C5H3 N(CH3)2 (Pyridine, 2,5-dimethyl-)

(RN-CAS Registry Numbe

C5 H3 N(CH3)2 (Pyridine, 2,6-dimethyl-)

(RN-CAS Registry Numbe

C6H4(NH2)C4H9 (Benzenamine, 3-butyl-)

(RN-CAS Registry Numbe

CJUQmjCJU

(Benzenamine, 4-butyl-)

C6H4(CH3)NHCOCH3 (Acetamide, A-(2-methylphenyl)-)

(RN-CAS Registry Number 120-66-1)

C6H4(CH3)NHCOCH3 ch2 =c=o

(Acetamide, A-(4-methylphenyl)-)

(RN-CAS Registry Number 103-89-9)

Other

products

Ionization or appearance

potential

(eV)

Method Ref.

** 7.52 PE 3988

95-53-4)

** 7.83 (V) PE 4106

95-53-4)

** 7.55 PE 3988

©oo 7.66 (V) PE 4106

108-44-1)

** 7.24±0.02 PI 4028

106-49-0)

** 7.37 PE 3988

106-49-0)

** 7.62 (V) PE 4106

106-49-0)

** 7.32 PE 3988

100-61-8)

** 7.35±0.02 PE 3890

100-61-8)

** 9.23 ±0.05 El 3498

108-48-5)

** 8.80±0.05 (V) PE 3685

589-93-5)

** 8.90±0.05 (V) PE 3685

108-48-5)

ch2 =chch3 10.10±0.1 El 3629

5369-17-5)

ch2 =chch3 9.37±0.1 El 3629

104-13-2)

ch2 =c=o 10.05 ±0.02 El 3631

10. 12 ±0.02 El 3631

C7H10N

+ (C2H5)2NCH= CHC=CH CH3 13.1 El 3674

(RN-CAS Registry Number 1809-53-6)

92
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c7h11 n+ C4H2N(CH3)3 (Pyrrole, 1,3,4-trimethyl-)

(RN-CAS Registry Number 30144-12-8)

7.3 El 3580

c8h6n+ C6H4(CN)C4H9 (Benzonitrile, 3-butyl-)

(RN-CAS Registry Number 20651-74-5)

12.90±0.1 El 3629

c8 h6n

+ C6H4(CN)C4H9 (Benzonitrile, 4-butyl-)

(RN-CAS Registry Number 20651-73-4)

12.71±0.1 El 3629

c„h7n

+

c8h,n+

'8n7

i

C6H4(CH3)CN ** 9.31 El

(Benzonitrile, 4-methyl-)

(RN-CAS Registry Number 104-85-8)

C6H4(CN)C4H9 CH2 = CHCH3 1 1.55 ±0. 1 El

(Benzonitrile, 3-butyl-)

(RN-CAS Registry Number 20651-74-5)

C6H4(CN)C4H9 CH2 =CHCH3 11.66±0.1 El

(Benzonitrile, 4-butyl-)

(RN-CAS Registry Number 20651-73-4)

4089

3629

3629

C8H9N+ c8h9n ** 7.15±0.02 PE 3890

(1/7-Indole, 2,3-dihydro-)

(RN-CAS Registry Number 496-15-1)

c8h9n+ C6H4(NH2)CH2CH2OCOCH3 7.80 El 3590

(Benzeneethanol, 4-amino-, acetate(ester))

(RN-CAS Registry Number 33709-38-5)

c8h10n

+ C6H5N(CH3)2 h

(Benzenamine, A,A-dimethyl-)

(RN-CAS Registry Number 121-69-7)

10.56±0.05 PI 4028

c8h10n+ C4H8NCH=CHC=CH H 10.7 El 3674

(Pyrrohdine, l-(l-buten-3-ynyl)-)

(RN-CAS Registry Number 19352-85-3)

c8HnN

+

c8h„n+

c8hhn

+

c8h„n+

c8hun+

C6H3(CH3)2NH2 (Benzenamine, 2,6-dimethyl-)

(RN-CAS Registry Number 87-62-7)

C6H3(CH3)2NH2 (Benzenamine, 2,6-dimethyl-)

(RN-CAS Registry Number 87-62-7)

C6H4(CH3)NHCH3 ** (Benzenamine, N,2-dimethyl-)

(RN-CAS Registry Number 611-21-2)

C6H4(CH3)NHCH3 ** (Benzenamine, A,3 -dimethyl-)

(RN-CAS Registry Number 696-44-6)

C6H4(CH3)NHCH3 ** (Benzenamine, A,4-dimethyl-)

(RN-CAS Registry Number 623-08-5)

7.30±0.02

7.36

7.27

7.26

7.13

PE

PE

PE

PE

PE

3890

3988

3988

3988

3988

93
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8 h„n+ C6H5 N(CH3)2 (Benzenamine, A^V-dimethyl-)

(RN-CAS Registry Number 121-69-7)

7. 13 ±0.04 PI 4028

c8 hu n

+ C6H5 N(CH3)2 (Benzenamine, 7V,A-dimethyl-)

(RN-CAS Registry Number 121-69-7)

7.10±0.02 PE 3890

c8 h„n+ C6H5 N(CH3)2 (Benzenamine, A^A-dimethyl-)

(RN-CAS Registry Number 121-69-7)

7.11 PE 3988

c8 hu n

+ C6H5 N(CH3)2 (Benzenamine, A,7V-dimethyl-)

(RN-CAS Registry Number 121-69-7)

7.37 (V) PE 4106

c8 h„n+ C6H5 N(CH3)2 (Benzenamine, A^,A-dimethyl-)

(RN-CAS Registry Number 121-69-7)

7.2 CTS 3543

c8 hu n

+ C6H5 N(CH3)2 (Benzenamine, 7V,7V-dimethyl-)

(RN-CAS Registry Number 121-69-7)

(AV-Average of two values)

7.42 CTS 4029

C8 Hn N

+ c4h8 nch=chc^ch **

(Pyrrolidine, 1 -( 1 -buten-3-ynyl)-)

(RN-CAS Registry Number 19352-85-3)

7.5 El 3674

c8 h12 n

+ (C2 H5)2NCH= CHC=CH h

(RN-CAS Registry Number 1809-53-6)

9.9 El 3674

c8 h13 n+ (C2 H5)2 NCH = CHC=CH ** (RN-CAS Registry Number 1809-53-6)

8.0 El 3674

c8 h13 n

+ c4h4nc4h9 **

( 1/f-Pyrrole, 2-( 1 , 1 -dimethylethyl)-)

(RN-CAS Registry Number 5398-58-3)

7.95 ±0.05 El 3482

c9h7 n

+ c9h7n **

(Isoquinoline)

(RN-CAS Registry Number 119-65-3)

8.50 PE 3638

c9h7 n

+ c9h7 n **

(Isoquinoline)

(RN-CAS Registry Number 119-65-3)

8.54 (V) PE 3723

c9 h7 n

+ c9h7 n ** (Quinoline)

(RN-CAS Registry Number 91-22-5)

8.3 PI 3586

c9h7 n

+ c9h7 n ** (Quinoline)

(RN-CAS-Registry Number 91-22-5)

8.62 PE 4066

c9h7 n

+ c9h7 n ** (Quinoline)

(RN-CAS Registry Number 91-22-5)

8.62 PE 3638

c9 h7 n

+ c9h7 n ** (Quinoline)

(RN-CAS Registry Number 91-22-5)

8.62 (V) PE 3723

94
Table of Ion Energetics Measurements—Continued

c9h„n+

c9h13 n

+

c9h13 n+

c9h13 n+

c9h13 n+

c9h13n+

c9h13 n+

c9h13n+

c9h13 n+

c9h13n

+

c9h13n+

c9h17n+

Reactant Other

products

C9HnN **

(Quinoline, 1,2,3,4-tetrahydro-)

(RN-CAS Registry Number 635-46-1)

C6H2(CH3)3 NH2 (Benzenamine, 2,4,6-trimethyl-)

(RN-CAS Registry Number 88-05-1)

C6H3 (CH3)2NHCH3 (Benzenamine, TV,2, 6-trimethyl-)

(RN-CAS Registry Number 767-71-5)

C6H4(CH3)N(CH3)2 (Benzenamine, A,TV, 2-trimethyl-)

(RN-CAS Registry Number 609-72-3)

C6H4(CH3)N(CH3)2 (Benzenamine, TV,TV,2-trimethyl-)

(RN-CAS Registry Number 609-72-3)

C6H4(CH3)N(CH3)2 (Benzenamine, TV,TV,2-trimethyl-)

(RN-CAS Registry Number 609-72-3)

C6H4(CH3)N(CH3)2 (Benzenamine, TV,TV, 3-trimethyl-)

(RN-CAS Registry Number 121-72-2)

C6H4(CH3)N(CH3)2 (Benzenamine, TV,TV,3-trimethyl-)

(RN-CAS Registry Number 121-72-2)

C6H4(CH3)N(CH3)2 (Benzenamine, TV,TV,4-trimethyl-)

(RN-CAS Registry Number 99-97-8)

C6H4(CH3)N(CH3)2 (Benzenamine, TV,TV,4-trimethyl-)

(RN-CAS Registry Number 99-97-8)

C5H4NC(CH3)3 (Pyridine, 4-(1 , 1 -dimethylethyl)-)

(RN-CAS Registry Number 3978-81-2)

C6HnN=C(CH3)2 (Cyclohexanamine, TV-( 1 -methylethyhdene)-)

(RN-CAS Registry Number 6407-36-9)

Ionization or appearance

potential

(eV)

Method Ref.

7.00±0.02 PE 3890

7.15 PE 3988

7.34 PE 3988

7.40±0.02 PE 3890

7.44 PE 3988

7.92 (V) PE 4106

7.06 PE 3988

7.24 (V) PE 4106

6.95 PE 3988

7.27 (V) PE 4106

9.30±0.05 (V) PE 3685

8.23 PE 4043

C10H,N+

C10H,N+

C10H7(NH2)

(

1 -Naphthylamine)

(RN-CAS Registry Number 134-32-7)

C10H7(NH2) (2-Naphthylamine)

(RN-CAS Registry Number 91-59-8)

7.3

7.2

PI

PI

3586

3586

C10H15 N

+ Q^NH^QH,,

(Benzenamine, 3-butyl-)

(RN-CAS Registry Number 5369-17-5)

7.5 1 ±0.

1

El 3629

c10h15n+ C6H4(NH2)C4H9 (Benzenamine, 4-butyl-)

(RN-CAS Registry Number 104-13-2)

95

7.61 ±0.

1

El 3629
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref.

products potential

(eV)

c10h15 n

+

C10H15 N

+

C,oH15 N

+

C,oH 15 N+

C6H5 N(C2H5)2 (Benzenamine, 7V,./V-diethyl-)

(RN-CAS Registry Number 91-66-7)

C6H2(CH3)3 NHCH3 (Benzenamine, 7V,2,4,6-tetramethyl-)

(RN-CAS Registry Number 13021-14-2)

C6H3 (CH3)2 N(CH3)2 (Benzenamine, A^./V,2,6-tetramethyl-)

(RN-CAS Registry Number 769-06-2)

C6H3(CH3)2N(CH3)2 (Benzenamine, iV,7V,2,6-tetramethyl-)

(RN-CAS Registry Number 769-06-2)

6.95 ±0.02

7.22

7.30±0.02

7.42

PE

PE

PE

PE

3890

3988

3890

3988

c„h13 n

+ C6H4(CN)C4H9 (Benzonitrile, 3-butyl-)

(RN-CAS Registry Number 20651-74-5)

9.77±0.1 El 3629

cu h13 n

+ C6H4(CN)C4H9 (Benzonitrile, 4-butyl-)

(RN-CAS Registry Number 20651-73-4)

10.08±0.1 El 3629

c„h13 n

+ c„h13 n

(2H- 1 ,4-Ethanoquinoline, 3,4-dihydro-)

(RN-CAS Registry Number 4363-25-1)

(ON-Other name: Benzoquinuclidine)

7.85±0.02 PE 3890

C,,H17 N

+ C6H2 (CH3)3 N(CH3)2 ** 7.24 PE 3988

(Benzenamine, A^A^^^-pentamethyl-)

(RN-CAS Registry Number 13021-15-3)

C12 Hu N

+ (C6H5)2 NH ** 7.14±0.03 PI 4028

(Benzenamine, TV-phenyl-)

(RN-CAS Registry Number 122-39-4)

C, 2 Hn N

+ C6H5C6H4NH2 ** 7.28±0.02 PE 3702

([1,1 '-Biphenyl]-2-amine)

(RN-CAS Registry Number 90-41-5)

C12 H15 N

+ C12H15 N ** 6.65±0.02 PE 3890

(l/f,5/f-Benzo[//]quinolizine, 2,3,6,7-tetrahydro-)

(RN-CAS Registry Number 479-59-4)

(ON-Other name: Julolidine)

C13 H9N

+ C13 H9N **

. 7.8 PI 3586

(Acridine)

(RN-CAS Registry Number 260-94-6)

C13 H12 N

+ (C6H4NH2)2CH2 NH2 10.7±0. 1 El 3807

(Benzenamine, 4,4'-methylenebis-)

(RN-CAS Registry Number 101-77-9)

C, 3 H13 N

+ C6H5 CH2C6H4NH2 ** 7.67±0.05 El 3806

(Benzenamine, 4-(phenylmethyl)-)

(RN-CAS Registry Number 1135-12-2)

96
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

CuHnN+ c6h5ch2c6h4cn **

(Benzonitrile, 4-(phenylmethyl)-)

(RN-CAS Registry Number 23450-31-9)

9.25±0.05 El 3806

c14h15n+ c6h5 ch2ch2c6h4nh2 ** (Benzenamine, 4-(2-phenylethyl)-)

(RN-CAS Registry Number 13024—49-2)

7.55±0.05 El 3806

c15h„n+ C^NC^

(Quinoline, 2-phenyl-)

(RN-CAS-Registry Number 612-96-4)

8.10 PE 4066

c16h13n+ C3H3(CN)(C6H5)2 (Cyclopropanecarbonitrile, 1 ,2-diphenyl-)

(RN-CAS Registry Number 10224-14-3)

8.80±0.08 EDD 3575

C17H29N+ C5H2N(C(CH3)3)3 ** 8.6 (V)

(Pyridine, 2,4,6-tris(l, 1-dimethylethyl)-)

(RN-CAS Registry Number 20336-15-6)

C17H29N+ C5H2N(C(CH3)3)3 ** 8.6 (V)

(Pyridine, 2,4,6-tris( 1 , 1 -dimethylethyl)-)

(RN-CAS Registry Number 20336-15-6)

c18h15n+ (C6H5)3N

(Benzenamine, 7V,7V-diphenyl~)

(RN-CAS Registry Number 603-34-9)

6.80±0.05 PI 4028

c19h13n+ CoHgNC^

(Acridine, 9-phenyl-)

(RN-CAS Registry Number 602-56-2)

7.80 (V) PE 3896

C15H12 =CHCH2CH2N(CH3)2 ** 8.26±0.07 CTS 4079

(1 -Propanamine, 3-(10, 1 l-dihydro-5i/-dibenzo[a,</]cyclohepten-5-ylidene)-iV,A-dimethyl-)

(RN-CAS Registry Number 50-48-6)

(ON-Other name: Amitryptyline)

PE 3934

PE 3685

CH2N2fB,) CH2N2 **

(377-Diazirine)

(RN-CAS Registry Number 157-22-2)

CH2N^(2B2) ch2n2 **

(3i/-Diazirine)

(RN-CAS Registry Number 157-22-2)

CH2N2t

2A,) CH2N2 **

(3/7-Diazirine)

(RN-CAS Registry Number 157-22-2)

CH2N2t

2A,) CH2N2 **

(3/f-Diazirine)

(RN-CAS Registry Number 157-22-2)

CHjN^BJ CH2N2 (3/f-Diazirine)

(RN-CAS Registry Number 157-22-2)

10.3 PE 3727

12.8 PE 3727

14.15 PE 3727

16 PE 3727

17.5 (V) PE 3727

97
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CH2N2fB,) ch2 n2 **

(3//-Diazirine)

(RN-CAS Registry Number 157-22-2)

21 PE 3727

CH2 N2fA,) ch2 n2 ** (3//-Diazirine)

(RN-CAS Registry Number 157-22-2)

22.5 (V) PE 3727

ch3 n+ ch3 n=nch3 ch3 (RN-CAS Registry Number 503-28-6)

9.2 El 3632

QH6n2+ trans-CH3 N= NCH3 ** (RN-CAS Registry Number 4143-41-3)

-8.20 PE 3649

CjH.NjfB,) c3 h6n2 (3/f-Diazirine, 3,3-dimethyl-)

(RN-CAS Registry Number 5161-49-9)

12.11 (V) PE 3505

C2 H6N2t

2A,) c3 h6n2 (3//-Diazirine, 3,3-dimethyl-)

(RN-CAS Registry Number 5161-49-9)

13.31 (V) PE 3505

ch3 nhnhch3 ** (RN-CAS Registry Number 540-73-8)

9.02 (V) PE 4085

c2h,n2+ ch3 nhnhch3 ** (RN-CAS Registry Number 540-73-8)

9.62 PE 3747

c3 h2 n2+ CH2(CN)2 ** (RN-CAS-Registry Number 109-77-3)

12.88 PE 4067

c3 h3 n2+ c3h4n2 h

(1/f-Imidazole)

(RN-CAS Registry Number 288-32-4)

12.8 El 3910

CjH4N2+ c3h4n2 (li/-Imidazole)

(RN-CAS Registry Number 288-32-4)

8.78 (V) PE 4009

c3 h4n2+ c3 h4n2 (17/-Imidazole)

(RN-CAS Registry Number 288-32-4)

9.12 El 3910

c3 h4n2+ c3 h4n2 (1/f-Pyrazole)

(RN-CAS Registry Number 288-13-1)

9.15 (V) PE 4009

c3 h6n2+ (CH3)2C=N= N ** (RN-CAS Registry Number 2684-60-8)

7.88 PE 4047

c3 h6n2 (3/f-Diazirine, 3,3-dimethyl-)

(RN-CAS Registry Number 5161-49-9)

9.76 (V) PE 3505

c3 h8n2+ (CH3)2NN=CH2 ** (RN-CAS Registry Number 2035-89-4)

7.85 PE 3884

c3 h,n2+ ch3 nhn=chch3 ** (RN-CAS Registry Number 17167-73-6)

7.67 PE 3884

98
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

C3H8N2+ CH2N2(CH3)2 (Diaziridine, 1,2-dimethyl-)

(RN-CAS Registry Number 6794-95-2)

C3H8N2+ CH2N2(CH3)2 (Diaziridine, 3,3-dimethyl-)

(RN-CAS Registry Number 4901-76-2)

c3h8n+ c3h8n2 (Pyrazolidine)

(RN-CAS Registry Number 504-70-1)

C4H2N2+ cis-CH(CN) =CH(CN) ** (RN-CAS Registry Number 928-53-0)

C4H2N2+ fra/is-CH(CN) = CH(CN) ** (RN-CAS Registry Number 764-42-1)

c4h4n2

^ c4h4n2 **

(Pyrazine)

(RN-CAS Registry Number 290-37-9)

(RS-Average of two Rydberg series limits)

c4h4n2 ** (Pyrazine)

(RN-CAS Registry Number 290-37-9)

c4h4n2 ** (Pyrazine)

(RN-CAS Registry Number 290-37-9)

c4h4n2 (Pyrazine)

(RN-CAS Registry Number 290-37-9)

c4h4n2 ** (Pyrazine)

(RN-CAS Registry Number 290-37-9)

c4h4n2 ** (Pyrazine)

(RN-CAS Registry Number 290-37-9)

c4h4n2 ** (Pyrazine)

(RN-CAS Registry Number 290-37-9)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

99

c4h4n2+

c4h4n2+

C4H4N2fAlg)

C4H4N2t

2B2g)

C4H4N2fB2n)

C4H4N2fBlg)

.4il4I-« 2

C4H4N2t

2B2)

C4H4N2\

2B2)

C4H4N2t

2A2)

C4H4N2t

2Aj)

Ionization or appearance Method Ref.

potential

(eV)

9.42 (V) PE 3888

9.90 (V) PE 3888

7.90 (V) PE 4085

11.15 PE 3778

11.15 PE 3778

9.28±0.01 S 3773

9.216 PE 3750

9.29 PE 3679

9.63 (V) PE 3513

10.18 (V) PE 3513

11.35 (V) PE 3513

11.77 (V) PE 3513

8.64 PE 3679

8.706±0.001 PE 3639

9.31 (V) PE 3513

10.483±0.001 PE 3639

10.61 (V) PE 3513
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

C,H,N;fB,)

C4H4N2t

2A„2B,)

C4H4N2t

2 A,)

C4H4N2t

2 B,)

C4H4N2t

2A,)

C4H4N2t

2B2)

C4H4 N2t

2 A,)

C.H.N^Bj)

C4H4N2fA,)

C4H4N2t

2 A„2B2)

c4h4n2+

C4H4N2t

2B2)

C4H4N2fB2)

C4H4N2t

2B,)

C4H4N2t

2B,)

C4H4N2fA2)

C4H4N2fA,)

C4H4N2 (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 **

(Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyridazine)

(RN-CAS Registry Number 289-80-5)

c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

c4h4n2 (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

c4h4n2 (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

C4H4N2 (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

Ionization or appearance

potential

(eV)

Method Ref.

~ 10.9 (V) PE 3513

-11.1 PE 3639

11.31 (V) PE 3513

13.504±0.003 PE 3639

-13.8 PE 3639

-14.5 PE 3639

-15.88 PE 3639

-16.5 PE 3639

-17.0 PE 3639

20.0 PE 3639

9.23 PE 3679

9.32±0.01 PE 3651

9.73 (V) PE 3513

10.40 ±0.01 PE 3651

10.41 (V) PE 3513

11.1 PE 3651

11.23 (V) PE 3513

100
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C4H4N2t

2A,) c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

11.3 PE 3651

C4H4N2t

2 AJ c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

11.39 (V) PE 3513

C4H4N2fB,) c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

13.6 PE 3651

CJWj?Au*Bd c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

— 14 PE 3651

C4H4N2t

2A,) c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

15.3 PE 3651

C4H4N2t

2B2) c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

16.6 PE 3651

C4H4N2t

2A,) c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

17.2 PE 3651

C4H4N2T

2A„2B2) c4h4n2 (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

20.0 PE 3651

C4H4N2t

2A,) c4h4n2 ** (Pyrimidine)

(RN-CAS Registry Number 289-95-2)

23.4 PE 3651

C4HsN2+ ch3ch=nn=chch3 ** (RN-CAS Registry Number 592-56-3)

8.56 PE 4043

C4HsN2+ ch3 ch=nn= chch3 ** (RN-CAS Registry Number 592-56-3)

9.11 (V) PE 4085

c4h8n2+ OfltNCjHtN **

(l,r-Biaziridine)

(RN-CAS Registry Number 4388-03-8)

8.65 (V) PE 4085

c4h10n+ c2h5 n=nc2h5 ** (RN-CAS Registry Number 821-14-7)

8.7±0.1 El 4099

c4h10n+ CH3NHN=C(CH3)2 ** (RN-CAS Registry Number 5771-02-8)

7.69 PE 3884

c4h10n2+ (CH3)2NN=CHCH3 ** (RN-CAS Registry Number 7422-90-4)

7.54 PE 3884

c4h10n2+ CHN2(CH3)3 (Diaziridine, l,3»3-trimethyl-)

(RN-CAS Registry Number 40711-15-7)

9.20 (V) PE 3888

C4H10N2+ C4H10N2 (Piperazine)

(RN-CAS Registry Number 110-85-0)

(ON-Other name: Piperidazine)

8.72 (V) PE 4085

C4H12N2+ CjHsNHNHQHs ** 8.88 (V) PE 4085

(RN-CAS Registry Number 1615-80-1)

101
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c4h12 n2+ (CH3)2NN(CH3)2 (RN-CAS Registry Number 6415-12-9)

8.38 (V) PE 4085

c4h12 n2+ (CH3)2NN(CH3)2 (RN-CAS Registry Number 6415-12-9)

8.43 (V) PE 3889

c5 h4n2+ c5 h4 =n=n **

(1, 3-Cyclopentadiene, 5-diazo-)

(RN-CAS Registry Number 1192-27-4)

8.33 (V) PE 4047

c5 h6n2+ CH3 C(CN)2CH3 ** (RN-CAS-Registry Number 7321-55-3)

12.39 (V) PE 4067

c5 h6n2+ c5 h4nnh2 ** (2-Pyridinamine)

(RN-CAS Registry Number 504-29-0)

8.85+0.05 El 3891

c5 h6n2+ c5 nh4nh2 ** (2-Pyridinamine)

(RN-CAS Registry Number 504-29-0)

9.3 CTS 3730

cs h6n2+ c5 h4nnh2 ** (3-Pyridinamine)

(RN-CAS Registry Number 462-08-8)

9.03 ±0.05 El 3891

c5 h6n2+ c5 nh4nh2 ** (3-Pyridinamine)

(RN-CAS Registry Number 462-08-8)

9.0 CTS 3730

c5 h6n2+ c5 h4nnh2 ** (4-Pyridinamine)

(RN-CAS Registry Number 504-24-5)

9.27+0.05 El 3891

c5 h6n2+ c5 nh4nh2 ** (4-Pyridinamine)

(RN-CAS Registry Number 504-24-5)

8.4 CTS 3730

C5 H,Nj+ c5h8 n2 (2,3-Diazabicyclo[2.2. 1 ]hept-2-ene)

(RN-CAS Registry Number 2721-32-6)

8.45+0.04 PE 3828

c5 h10n2+ c4h7 n2ch3 ** (l,5-Diazabicyclo[3. 1.0]hexane, 2-methyl-)

(RN-CAS Registry Number 6794-96-3)

8.78 (V) PE 3888

c5 h12 n2+ (CH3)2NN=C(CH3)2 ** (RN-CAS Registry Number 13483-31-3)7.43 PE 3884

c5 h12n2+ CN2(CH3)4 (Diaziridine, tetramethyl-)

(RN-CAS Registry Number 50695-43-7)

8.94 (V) PE 3888

c6h4n2+ c5h4ncn ** (2-Pyridinecarbonitrile)

(RN-CAS Registry Number 100-70-9)

10.33+0.05 El 3498

C6H7n2+ C6H4(NH2)NHCOCH3 ch3 co

(Acetamide, A^-(2-aminophenyl)-)

(RN-CAS Registry Number 34801-09-7)

13.93 ±0.02 El 3631

102
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

qh,n2+ C6H4(NH2)NHCOCH3 ch3 co

(Acetamide, 7V-(4-aminophenyl)-)

(RN-CAS Registry Number 122-80-5)

13.72±0.02 El 3631

C„H,N+ C6H4(NH2)2

( 1 ,4-Benzenediamine)

(RN-CAS Registry Number 106-50-3)

7.16 El 4089

QH8N2+ C4H2N2(CH3)2 (Pyrazine, 2,6-dimethyl-)

(RN-CAS Registry Number 108-50-9)

8.80 PE 3860

c«,h8n2

> C5NH3(CH3)NH2 (2-Pyridinamine, 6-methyl-)

(RN-CAS Registry Number 1824-81-3)

9.1 CTS 3730

c6h8n/ c5h4nnhch3 ** (2-Pyridinamine, A-methyl-)

(RN-CAS Registry Number 4597-87-9)

8.26+0.05 El 3891

c6h8n+ C5NH3(CH3)NH2 ** (3-Pyridinamine, 4-methyl-)

(RN-CAS Registry Number 3430-27-1)

9.3 CTS 3730

qh,n2+ c5h4nnhch3 ** (3-Pyridinamine, TV-methyl-)

(RN-CAS Registry Number 18364-47-1)

8.53+0.05 El 3891

QH.N/ c5h4nnhch3 ** (4-Pyridinamine, TV-methyl-)

(RN-CAS Registry Number 1121-58-0)

8.75+0.05 El 3891

c6h8n2+ C5H4N(=NH)CH3 **

(2( 17f-Pyridinimine, 1 -methyl-)

(RN-CAS Registry Number 4088-63-5)

7.91+0.05 El 3891

C5H4N(=NH)CH3 **

(4( ljfiO-Pyridinimine, 1 -methyl-)

(RN-CAS Registry Number 16562-40-6)

7.85+0.05 El 3891

c<,h8n2+ C5H4N(NH)CH3 ** 7.45+0.1

(Pyridinium, 3-amino- 1 -methyl-, hydroxides, inner salt) (RN-CAS Registry Number 38879-42-2)

El 3891

C8H8N2f C6H4(NH2)NHCOCH3 ch2 =c=o

(Acetamide, A-(2-aminophenyl)-)

(RN-CAS Registry Number 34801-09-7)

10.49 ±0.02 El 3631

CtH8N2+ C6H4(NH2)NHCOCH3 ch2 =c=o

(Acetamide, A-(4-aminophenyl)-)

(RN-CAS Registry Number 122-80-5)

10.06+0.02 El 3631

C6H10N2+ QH.oN,

(2,3-Diazabicyclo[2.2.2]oct-2-ene)

(RN-CAS Registry Number 3310-62-1)

7.79±0.04 PE 3828

c«h12n2+ (CH3)2C=NN=C(CH3)2 (RN-CAS Registry Number 627-70-3)

7.97 PE 4043

C6H12n2+ C6H12N2 7.52 (V) PE 4038

( 1 ,4-Diazabicyclo[2.2.2]octane)

(RN-CAS Registry Number 280-57-9)

103
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c6h12 n2+ c6h12 n2

(

H, 5/f-Pyrazolo[ 1 ,2-a]pyrazole, tetrahydro-)

(RN-CAS Registry Number 5397-67-1)

(ON-Other name: 1,5-Diazabicyclo[3.3.0]octane)

7.90 (V) PE 4085

c6h12 n2+ c6h12n2 (l//,5//-Pyrazolo[l,2-tf]pyrazole, tetrahydro-)

(RN-CAS Registry Number 5397-67-1)

(ON-Other name: 1,5-Diazabicyclo[3.3.0]octane)

7.91 (V) PE 3889

c6h14 n2+ C4H8 N2(CH3)2 (Pyridazine, hexahydro- 1 ,2-dimethyl-)

(RN-CAS Registry Number 26163-37-1)

7.77 (V) PE 3887

c6h16n2+ (CH3)2CHNHNHCH(CH3)2 ** (RN-CAS Registry Number 3711-34-0)8.34 (V) PE 4085

c^n? C7H8 N2 (3,4-Diazatricyclo[4.2. 1 .0

2,5 ]nona-3,7-diene)

(RN-CAS Registry Number 23979-29-5)

9.05 ±0.05 (V) PE 4040

QH.oN,

(3,4-Diazatricyclo[4.2. 1 .0

2,5]non-3-ene)

(RN-CAS Registry Number 23979-30-8)

8.90±0.05 (V) PE 4040

C7H10n2+ C5 NH4N(CH3)2 (4-Pyridinamine, NJV,-dimethyl-)

(RN-CAS Registry Number 1 122-58-3)

7.7 CTS 3730

CtHI2n2+ C5H6N2(CH3)2 (2,3-Diazabicyclo[2.2. l]hept-5-ene, 2,3-dimethyl-)

(RN-CAS Registry Number 14288-15-4)

7.74 (V) PE 3889

C7H12n2+ C7H12N2 (6,7-Diazabicyclo[3.2.2]non-6-ene)

(RN-CAS Registry Number 43195-77-3)

7.64±0.04 PE 3828

C7H12 n2+ C3 N2 (CH3)4 (4i/-Pyrazole, 3,4,4, 5-tetramethyl-)

(RN-CAS Registry Number 19078-32-1)

10.12 (V) PE 4085

C7H 14n2+ C5 H8 N2(CH3)2 (2,3-Diazabicyclo[2.2. l]heptane, 2,3-dimethyl-)

(RN-CAS Registry Number 14287-89-9)

7.58 (V) PE 3889

c,h16n2+ C4H7 N2(CH3)3 (Pyridazine, hexahydro- 1,2,3-trimethyl-)

(RN-CAS Registry Number 38704-92-6)

7.81 (V) PE 3887

c8 h6n2+ c8 h6n2 (Cinnoline)

(RN-CAS Registry Number 253-66-7)

<8.8 PE 3638

c8 h6n2+ c8 h6n2 (Cinnoline)

(RN-CAS Registry Number 253-66-7)

8.90 (V) PE 3722

104
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8h6n2+ c8h6n2 ( 1 , 5-Naphthyridine)

(RN-CAS Registry Number 254-79-5)

9.20 (V) PE 3722

c8h6n+ c8h6n2

( 1 , 6-Naphthyridine)

(RN-CAS Registry Number 253-72-5)

9.07 (V) PE 3722

c8h6n2+ c8h6n2 (1,7-Naphthyridine)

(RN-CAS Registry Number 253-69-0)

8.99 (V) PE 3722

c8h6n2+ c8h6n2 ( 1

, 8-Naphthyridine)

(RN-CAS Registry Number 254-60-4)

9.20 (V) PE 3722

c8h6n2+ c8h6n2 (2, 6-Naphthyridine)

(RN-CAS Registry Number 253-50-9)

8.87 (V) PE 3722

c8h6n2+ c8h6n2 (2, 7-Naphthyridine)

(RN-CAS Registry Number 253-45-2)

8.98 (V) PE 3722

c8 h6n2+ c8h6n2 (Phthalazine)

(RN-CAS Registry Number 253-52-1)

8.70 (V) PE 3722

c8h6n2+ c8h6n2 (Quinazoline)

(RN-CAS Registry Number 253-82-7)

9.00 PE 3638

c8h6n2+ c8h6n2 (Quinazoline)

(RN-CAS Registry Number 253-82-7)

9.08 (V) PE 3722

c8h6n2+ c8h6n2 (Quinoxaline)

(RN-CAS Registry Number 91-19-0)

9.00 (V) PE 3722

c8h6n+ c8h6n2 (Quinoxaline)

(RN-CAS Registry Number 91-19-0)

9.01 PE 3638

c8h14n2+ C6H8N2(CH3)2 (2, 3-Diazabicyclo[2.2. 2]oct-5-ene, 2, 3-dimethyl-)

(RN-CAS Registry Number 14287-91-3)

7.59 (V) PE 3889

c8 h14n2+ c8h14n2 (7,8-Diazabicylco[4.2.2]dec-7-ene)

(RN-CAS Registry Number 32634-64-3)

7.38 ±0.04 PE 3828

C8H16N2+ C8H16N2 (Pyridazino[ 1 ,2-a]pyridazine, octahydro-)

(RN-CAS Registry Number 3661-15-2)

7.59 (V) PE 3889

c8 h18n+ C4H6N2 (CH3)4 (Pyridazine, hexahydro-l,2,3,6-tetramethyl, cis-)

(RN-CAS Registry Number 26171-64-2)

7.82 (V) PE 3887

c8h18n2+ C4H6N2(CH3)4 (Pyridazine, hexahydro-l,2,3,6-tetramethyl, trans-)

(RN-CAS Registry Number 38704-91-5)

7.78 (V) PE 3887

105
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8 h20n2+ (C2H5)2 NN(C2 H5)2 (RN-CAS Registry Number 4267-00-9)8.10 (V) PE 3889

CoH20N2+ C3 H6N2(C3 H7)2 (Pyrazolidine, 1 ,2-bis( 1 -methylethy1)-) (RN-CAS Registry Number 38704-87-9)

7.89 (V) PE 3889

c10h8 n2+ (C5 H4N)2 (2,2'-Bipyridine)

(RN-CAS Registry Number 366-18-7)

8.35±0.02 PE 3702

c10h8 n2+ (C5H4N)2 (4,4'-Bipyridine)

(RN-CAS Registry Number 553-26-4)

9.10±0.02 PE 3702

c10h16n2+ C6H4(N(CH3)2)2

( 1 ,4-Benzenediamine, A^-tetramethy1-) (RN-CAS Registry Number 100-22-1)

6.20±0.05 PI 3729

c10h16n2+ C6H4(N(CH3 )2)2 (1,4-Benzenediamine, AyV,7V\./V'-tetramethyl-)

(RN-CAS Registry Number 100-22-1)

6.7 CTS 3543

c10h20n2+ c5 h10nc5 h10n

(1,1 '-Bipiperidine)

(RN-CAS Registry Number 6130-94-5)

8.05 (V) PE 4085

c„h8 n2+ C„H8N2 (1//-Perimidine)

(RN-CAS Registry Number 204-02-4)

6.80 CTS 4035

C12H2oN^" C6H10NN(C6H10) (Cyclohexanone, cyclohexylidenehydrazone)

(RN-CAS Registry Number 4278-87-9)

7.84 PE 4043

c13 h14n2+ (C6H4NH2)2CH2 (Benzenamine, 4,4'-methylenebis-)

(RN-CAS Registry Number 101-77-9)

7.75±0.05 El 3806

c14 h12 n+ C13 H9N2(CH3) ** 6.53 (l//-Cyclopenta[g/?]perimidine, 6,7-dihydro-l -methyl-)

(RN-CAS Registry Number 18969-93-2)

(ON-Other name: 1-Methylaceperimidine)

CTS 4035

cI4 h16n2+ C6H4(NH2)CH2CH2C6H4NH2 ** (Benzenamine, 4,4'-( 1 ,2-ethanediyl)bis-)

(RN-CAS Registry Number 621-95-4)

7.45±0.05 El 3806

c17 h22n2+ (C6H4N(CH3)2)2CH2 (Benzenamine, 4,4'-methylenebis(7V,7V-dimethyl)-)

(RN-CAS Registry Number 101-61-1)

7.1 CTS 3543

106
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

Ci8 H18 N2+ C6H5 C3 H3 (CN)C6H4N(CH3)2 ** 6.90±0.10 EDD 3575

(Cyclopropanecarbonitrile, 2-(p-(dimethylamino)pheny1)- 1 -phenyl-)

(RN-CAS Registry Number 6114-58-5)

Ci9H20N2+ C6H4(CH3)C3 H3 (CN)C6H4N(CH3 )2** 6.80±0.07 EDD 3575

(Cyclopropanecarbonitrile, 2-(p-(dimethylamino)phenyl)- 1—/?—tolyl—

)

(RN-CAS Registry Number 32589-51-8)

C19H24N2+ C14H12N(CH2)3N(CH3)2 ** 8.21+0.07 CTS 4079

(5i7-Dibenz[Z>,/]azepine-5-propanamine, 10,1 1 -dihydro-A,7V-dimethyl-)

(RN-CAS Registry Number 50-49-7)

(ON-Other name: Imizine)

CH3N3t

2A") CH3 N3 ** 9.81 ±0.02 PE 3670

(RN-CAS Registry Number 624-90-8)

C,H3 N3+ C2H3 N3 ** 10.06 (V) PE 4009

(ltf-1,2,3-Triazole)

(RN-CAS Registry Number 288-36-8)

C2H3 N3+ C2H3N3 ** 10.0 (V) PE 4009

(Lff-1,2,4-Triazole)

(RN-CAS Registry Number 288-88-0)

c3H,N+

C3 H3N^(2E')

c3h3n3+

C3 H3N3t

2E")

CjH3N3t

2Aj

C3 H3 N3t

2E')

C3H3N3t

2A')

CjHjNjfAO

C3H3 N3fA')

C3 H3N3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3 h3n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3 h3n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3h3 n3 **

(1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3 h3n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3h3 n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3 h3n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3 h3 n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

c3 h3 n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

9.98 PE 3679

10.01+0.01 PE 3720

10.1 PE 3637

11.69±0.01 PE 3720

13.26+0.01 PE 3720

14.56+0.01 PE 3720

15.0+0.01 PE 3720

17.1 ±0.01 PE 3720

18.05 ±0.01 PE 3720

107
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

CjHjNjfE') c3 h3 n3 (1,3,5-Triazine)

(RN-CAS Registry Number 290-87-9)

21.0±0.01 PE 3720

C12 Hn N3+ C11 H6N2(NH2)CH3 (l/f-Perimindin-2-amine, 1 -methyl-)

(RN-CAS Registry Number 20551-10-4)

6.41 CTS 4035

ch2 n,+ ch2n4 ** (1/f-Tetrazole)

(RN-CAS Registry Number 288-94-8)

11.3 (V) PE 4009

c2 h2 n;

C2H2 N4t

2B|)

C2H2 N4t

2A,)

C2H2N4t

2A2)

C,H2N4t

2A,)

QHjN.fB,)

C2 H2N4fA,)

C2H2N4fB2, 2 A,)

CjHjN.fA,)

C2 H2N4t

2B2)

C2H2N4 (1,2,4, 5-Tetrazine)

(RN-CAS Registry

c2h2n4

( 1 ,2,4, 5-Tetrazine)

(RN-CAS Registry

CAN,

( 1 ,2,4, 5-Tetrazine)

(RN-CAS Registry

CAN,

( 1 ,2,4, 5-Tetrazine)

(RN-CAS Registry

C2H2 N4 (1,2, 4, 5-Tetrazine)

(RN-CAS Registry

c2h2n4 (1,2,4, 5-Tetrazine)

(RN-CAS Registry

c2h2 n4

( 1 ,2,4, 5-Tetrazine)

(RN-CAS Registry

C2H2N4

( 1 ,2,4, 5-Tetrazine)

(RN-CAS Registry

CAN,

(1,2,4, 5-Tetrazine)

(RN-CAS Registry

CAN,

(1,2,4, 5-Tetrazine)

(RN-CAS Registry

CAN,

(1,2, 4, 5-Tetrazine)

(RN-CAS Registry

CAN,

(1,2,4, 5-Tetrazine)

(RN-CAS Registry

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

**

Number 290-96-0)

9.14 PE 3679

9.24 PE 3740

11.6 PE 3740

12.1 (V) PE 3740

12.5 PE 3740

13.2 PE 3740

15.51 PE 3740

16.5 PE 3740

~ 17.5 (V) PE 3740

18.9 PE 3740

22.0 PE 3740

~24 PE 3740

108
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance Method Ref. products potential

(eV)

c4h6n4+ C2N4(CH3)2 ** 9.08 (V) PE 3679

( 1 ,2,4, 5-Tetrazine, 3, 6-dimethyl-)

(RN-CAS Registry Number 1558-23-2)

c,„h2„n4+ C10H20N4 ** 6.06 (V) PE 3512

(Imidazolidine, 2-( 1 ,3-dimethyl-2-imidazolidinylidene)- 1 ,3-dimethyl-)

(RN-CAS Registry Number 1911-01-9)

c10h24n4+ ((CH3)2N)2C=C(N(CH3)2)2 ** 5.95 (V) PE 3512

(RN-CAS Registry Number 996-70-3)

c„h15 n5+ C„H13N4NH2 ** 9.1 CTS 3915

(977-Purin-6-amine, 9-cyclohexyl-)

(RN-CAS Registry Number 4235-94-3)

c32h18n8+ C32H18 N8 ** 7.36±0.10 El 3829

(29H,

3

l//-Phthalocyanine)

(RN-CAS Registry Number 574-93-6)

ch8bn+ (CH3NH2)(BH3) ** 9.66±0.01 PE 3699

(RN-CAS Registry Number 1722-33-4)

c2h8 bn+ (CH3)2NBH2 ** 9.51 PE 3584

(RN-CAS Registry Number 1838-13-7)

C,H9BN+ ((CH3)2NH)(BH2) ** 9.39+0.01 PE 3699

(RN-CAS Registry Number 74-94-2)

CjH12BN+ ((CH3)3N)(BH3) ** 9.28+0.2 PE 3699

(RN-CAS Registry Number 75-22-9)

c4h12 bn+ (CH3)2NB(CH3)2 ** 8.92 PE 3584

(RN-CAS Registry Number 1113-30-0)

c6h12bn+ C6H12BN ** 8.06 PE 3584

(

1

H,5H-[ 1 ,2]Azaborolo[ 1 ,2-a][ 1 ,2]azaborole, tetrahydro-)

(RN-CAS Registry Number 16153-13-2)

c4h13 bn2+ ((CH3)2N)2BH ** 7.76 PE 3584

(RN-CAS Registry Number 2386-98-3)

c,h,5 bn2+ ((CH3)2N)2B(CH3) ** 7.63 PE 3584

(RN-CAS Registry Number 6914-63-2)

c3h12 b3n3+ C3 H12 B3 N3 ** 8.99 (V) PE 3944

(Borazine, 1,3,5-trimethyl-)

(RN-CAS Registry Number 1004-35-9)

C3H12B3 N3t

2E') C3H12 B3 N3 ** 9.28+0.02 PE 3506

(Borazine, 1,3, 5 -trimethyl-)

(RN-CAS Registry Number 1004-35-9)

109
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c3 h12 b3 n3+ c3 h12 b3 n3 (Borazine, 2,4,6-trimethyl-)

(RN-CAS Registry Number 5314-85-2)

9.50 (V) PE 3944

C,Hl2B3N3t

2E-) c3 h12 b3 n3 (Borazine, 2,4,6-trimethyl-)

(RN-CAS Registry Number 5314-85-2)

9.64±0.03 PE 3506

c6h14 bn3+ C6H14 BN3 ** 7.90

([ 1 ,3,2]Diazaborino[ 1 ,2-a][ 1 ,3,2]diazaborine, octahydro-)

(RN-CAS Registry Number 1730-15-0)

PE 3584

c6h18 bn3+ B(N(CH3)2)3 (RN-CAS Registry Number 4375-83-1)7.60 (V) PE 3704

c6h18 b3 n3+ c6h18 b3 n3 (Borazine, hexamethyl-)

(RN-CAS Registry Number 877-07-6)

8.53 (V) PE 3944

c8 h24b2 n4+ ((CH3)2 N)2 BB(N(CH3)2)2 (RN-CAS Registry Number 1630-79-1)

7.3 (V) PE 3512

c8 h24 b2 n+ ((CH3)2 N)2 BB(N(CH3)2)2 (RN-CAS Registry Number 1630-79-1)

7.58 PE 3584

0

+

(

2 P) O ** (RN-CAS Registry Number 17778-80-2)

18.63 PE 3701

o

+ h2o h2 (RN-CAS Registry Number 7732-18-5)

19.0 DC 3967

o

+ H2 0 2H

(RN-CAS Registry Number 7732-18-5)

26.8 DC 3967

o

+ NO N

(RN-CAS Registry Number 10102-43-9)

20.1 ±0.3 El 3945

0

+ HOF HF

(RN-CAS Registry Number 14034-79-8)

(TV-Threshold value approximately corrected to 0°K)

14.34 PI 3932

o

+2 0+(2 P) ** (RN-CAS Registry Number 14581-93-2)

30 SEQ 3489

o

+2 0

+

(

2D) ** (RN-CAS Registry Number 14581-93-2)

32 SEQ 3489

0

+2('D) o+ ** (RN-CAS Registry Number 14581-93-2)

38 SEQ 3489

0

+2

(

5 S) o+ ** (RN-CAS Registry Number 14581-93-2)

42 SEQ 3489

o

+2 CO C('D)

(RN-CAS Registry Number 630-08-0)

61 SEQ 3489

o

+2 CO+ C('D)

(RN-CAS Registry Number 12144-04-6)

47 SEQ 3489

o

+3 0

+ 2('s) ** (RN-CAS Registry Number 14127-63-0)

49.3 SEQ 3489

110
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

o

+3 0

+2(‘D) ** 52.6 SEQ 3489

(RN-CAS Registry Number 14127-63-0)

o+6 o

+5 ** >160 SEQ 3489

(RN-CAS Registry Number 14127-66-3)

o2tx2nl/2) Ojfa'A,)

(RN-CAS Registry Number 7782-44—7)

11. 108 ±0.002 S 3878

o,tx2iy o2(RN-CAS Registry Number 7782-44-7)

12.07±0.01 PI 4020

o2tx2 n3/28) o2(RN-CAS Registry Number 7782-44-7)

12.077 PE 3834

o2tx2iy o2 ** (RN-CAS-Registry Number 7782-44-7)

12.08 PE 4073

o2tx2n1/2g) o2(RN-CAS Registry Number 7782-44-7)

12.102 PE 3834

O^aVu) o2 ** (RN-CAS Registry Number 7782-44-7)

16.105 PE 3664

o2t

2 ry 02('A,)

(RN-CAS Registry Number 7782-44-7) ~ 16.5 PE 3698

02t

24>„?) O/Ap

(RN CAS Registry Number 7782 44-7)

-17.45 PE 3534

o2f®„) O/A^

(RN-CAS Registry Number 7782-44-7)

17.5 PE 3698

02t

2Ag?) 02(‘A

g

) (RN-CAS Registry Number 7782-44-7)

18.81 PE 3534

o2fnj o2 ** (RN CAS Registry Number 7782 44 7)

22.8±0.1 PE 3975

02tc

423 o2 ** (RN-CAS Registry Number 7782-44-7)

24.6 PE 3975

o2* o2 ** (RN-CAS Registry Number 7782-44-7)

38.4±0.2 PE 3975

OH+

(RD-Radical)

OH+

(RD-Radical)

OH+ OH+

(TV-Threshold

OH ** (RN-CAS-Registry Number 3352-57-6)

OH ** (RN-CAS Registry Number 3352-57-6)

h2o h

(RN-CAS Registry Number 7732-18-5)

HOF F

(RN-CAS Registry Number 14034-79-8)

value approximately corrected to 0°K)

13.5±1.0 El 4054

12.88 D 3932

18.2 DC 3967

15.07 PI 3932

h2o

+ h2o ** 12.619±0.006 S 3983

h2o

+

(

2b,)

(RN-CAS Registry Number 7732-18-5)

h2o ** 12.619 PE 3941

h2o

+

(

2b,)

(RN-CAS Registry Number 7732-18-5)

h2o ** 12.62 PE 3719

(RN-CAS Registry Number 7732-18-5)
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

h2 o

+

(

2 b,) h2o ** 12.624 PE 3530

(RN-CAS Registry Number 7732-18-5)

(Center of rotational envelope)

h2o

+

(

2a,) h2o ** 13.78 PE 3719

(RN-CAS Registry Number 7732-18-5)

H;0 +

(

! A,) h2o ** 13.930±0.010 PE 3530

(RN-CAS Registry Number 7732-18-5)

(Origin of rotational envelope)

h2o

+

(

2a.) h2o ** 14.8 PE 3941

(RN-CAS Registry Number 7732-18-5)

h2o

+

(

2b2) h2o ** 17.02 PE 3719

(RN-CAS Registry Number 7732-18-5)

h2o

+

(

2 b2) h2o ** 17.390 PE 3530

(RN-CAS Registry Number 7732-18-5)

h2o

+

(

2 b2) h2o ** 18.54 PE 3941

(RN-CAS Registry Number 7732-18-5)

h2o

+

(

2a,) h2o ** 32.2 (V) PE 3719

(RN-CAS Registry Number 7732-18-5)

h2o

+ h2o ** 12.7 DC 3967

(RN-CAS Registry Number 7732-18-5)

DzO

+ DzO ** 12.636±0.006 S 3983

(RN-CAS Registry Number 7789-20-0)

D20

+

(

2B,) D20 ** 12.633 PE 3530

(RN-CAS Registry Number 7789-20-0)

(Center of rotational envelope)

D20

+

(

2A,) D20 ** 13.930±0.010 PE 3530

(RN-CAS Registry Number 7789-20-0)

(Origin of rotational envelope)

H30+ CjHjOH C2H2 + H 14.30±0.02 RPD 3487

(RN-CAS Registry Number 64-17-5)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

LiO + LiO ** (RN-CAS Registry Number 12142-77-7)8.45±0.20 El 3909

Li20

+ Li20 ** (RN-CAS Registry Number 12057-24-8)

6.19±0.20 El 3909

BO+ BO ** (RN-CAS Registry Number 13840-87-4)13.0±0.5 El 3473

bo2+ bo2 ** (RN-CAS-Registry Number 13840-88-5)

14.0± 1.0 El 4054

bho2+ bho2 ** (RN-CAS-Registry Number 13460-50-9)13.5±1.0 El 4054

CO+ (X2 2

+

) CO ** 14.014 S 3760

(RN-CAS Registry Number 630-08-0)

112
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

co+(A2n1/2) co ** (RN-CAS Registry Number 630-08-0)

CO+(B22

+

) CO ** (RN-CAS Registry Number 630-08-0)

(RS-Average of two Rydberg series limits)

CO+ (X22

+

) CO ** (RN-CAS-Registry Number 630-08-0)

CO+

(

222p) CO ** (RN-CAS Registry Number 630-08-0)

co+(A2 n) co ** co+

(

2n)

CO+

(B2^

CO+

(

222s) co+(c2

i: +

) co+ co+

(RN-CAS-Registry Number 630-08-0)

CO ** (RN-CAS Registry Number 630-08-0)

CO ** (RN-CAS Registry Number 630-08-0)

CO ** (RN-CAS Registry Number 630-08-0)

CO ** (RN-CAS Registry Number 630-08-0)

C02 0(

3 S)

(RN-CAS Registry Number 124-38-9)

COS S“? (RN-CAS Registry Number 463-58-1)

co2tx2 n3/2g) co2tx2n3/2e) co^iy

co2tx2ng

) co2tA2 na) C021(B

225

C02tC22g)

co2t

2 ij

C02t

2 £E) C02f2u?) C02t

2 Ig?)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS-Registry Number 124-38-9)

co2 ** (RN-CAS-Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

co2 ** (RN-CAS Registry Number 124-38-9)

Cj02t

2 nj

c3o2t

2 ng

)

c3o2 (RN-CAS Registry Number 504-64-3)

c3o2 (RN-CAS Registry Number 504-64-3)

Ionization or appearance

potential

(eV)

Method Ref.

16.550 S 3760

19.672 S 3760

14.01 PE 4073

14.01 (V) PE 4022

16.55 PE 4073

16.91 (V) PE 4022

19.69 (V) PE 3714

19.72 (V) PE 4022

39.0 PE 3975

29.0 PI 4095

15.6 El 3779

13.773±0.002 PI 3925

13.776±0.008 PI 4069

13.78 PE 4073

13.80±0.01 PE 3965

17.34±0.01 PE 3965

18.08±0.01 PE 3965

19.39±0.01 PE 3965

37 PE 4095

38.4 PE 4095

38.4 (V) PE 3975

40.0 (V) PE 3975

10.605 PE 3728

14.502 PE 3728

113
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C,02f2„) c3o2 (RN-CAS Registry Number 504-64-3)

15.751 PE 3728

Cj02t

2 X8

) c3 o2 (RN-CAS Registry Number 504-64-3)

16.978 PE 3728

CjOjfnj c3o2 (RN-CAS Registry Number 504-64-3)

17.258 PE 3728

CHO+ HCHO H

(RN-CAS Registry Number 50-00-0)

1 1.89±0.03 PI 3554

CHO+ CH3 OH H2 + H

(RN-CAS Registry Number 67-56-1)

(TR-Other product(s) thermochemically reasonable)

13.06±0.10 PI 3554

CHO+ (CH3)2o

(RN-CAS-Registry Number 115-10-6)

13.96+0.2 El 4071

CHO+ CH3OCD3 (RN-CAS-Registry Number 13725-27-4)

13.97±0.2 El 4071

CHO+ C2 H5 OCD3 (RN-CAS-Registry Number 16995-14-5)

13.13+0.2 El 4071

CDO+ CH3 OCD3 (RN-CAS-Registry Number 13725-27-4)

13.87+0.2 El 4071

CDO+ C2H5OCD3 (RN-CAS-Registry Number 16995-14-5)

13.57+0.2 El 4071

ch2 o

+ HCHO ** (RN-CAS Registry Number 50-00-0)

10. 88 ±0.02 PI 3554

ch2o

+ HCHO ** (RN-CAS Registry Number 50-00-0)

10.90±0.03 PI 3765

ch2o

+ ch3 oh h2 (RN-CAS Registry Number 67-56-1)

(TR-Other product(s) thermochemically reasonable)

12.05±0.12 PI 3554

ch3o

+ CH3OH H

(RN-CAS Registry Number 67-56-1)

11.55+0.03 PI 3554

ch3 o

+ (CH3 ) 20 ch3 (RN-CAS-Registry Number 115-10-6)

12.42+0.1 El 4071

ch3 o

+ C2 H5OCH3 (RN-CAS-Registry Number 540-67-0)

12. 86 ±0.1 El 4071

ch3 o

+

/i-C3 H7OH c2h5 (RN-CAS Registry Number 71-23-8)11.16+0.03 EDD 3626

chd2 o

+ C2 H5OCD3 (RN-CAS-Registry Number 16995-14-5)

12.86±0.05 El 4071

ch4o

+ CH40

+

(

2A

w

) ch4o

+ CH40

+

(

2A

w

)

CH3 OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS-Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

114

10.83+0.03 PI 3554

10.94 (V) PE 4068

10.95 PE 4087

10.95 (V) PE 4032
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

CH40

+

(

2A')

CH40

+

(

2A')

CH40

+

(

2A')

CH40

+

(

2A')

CH40

+

(

2A')

CH40

+

(

2A')

ch4o

+

(

2a)

CH40

+

(

2A")

CH40

+

(

2A")

CH40

+

(

2A")

CH40

+

(

2A')

CH40

+

(

2A')

ch4o

+

(

2a>

CH40

+

(

2A')

ch3oh ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS-Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS-Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS-Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS-Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

CH3OH ** (RN-CAS Registry Number 67-56-1)

c,h2o

+ c4h6o c2h4 (Cyclobutanone)

(RN-CAS Registry Number 1191-95-3)

(TR-Other product(s) thermochemically reasonable)

C2H30+ (ch3)2co ch3 (RN-CAS Registry Number 67-64-1)

C2H30

+ (CH3)2CO ch3 (RN-CAS Registry Number 67-64-1)

C2H30

+ C6H5OOCCH3 cyclo-C6H50

(Acetic acid, phenyl ester)

(RN-CAS Registry Number 122-79-2)

C,H30

+ C6H5OOCCH3 cyc/o-C6H50

(Acetic acid, phenyl ester)

(RN-CAS Registry Number 122-79-2)

C2H30

+ C6H4(CH3)OOCCH3 C6H4(CH3)0

(Acetic acid, 3-methylphenyl ester)

(RN-CAS Registry Number 122-46-3)

C2H30

+ C6H4(CH3)OOCCH3

(Acetic acid, 4-methylphenyl ester)

(RN-CAS Registry Number 140-39-6)

(OP-the other product(s) is(are): cyc/o-C6H4(CH3)0)

Ionization or appearance

potential

(eV)

Method Ref.

10.96 (V) PE 3941

12.62 (V) PE 3941

12.66 (V) PE 4032

12.68 (V) PE 4068

15.09 (V) PE 4032

15.19 (V) PE 4068

15.21 (V) PE 3941

15.64 (V) PE 3941

15.66 (V) PE 4068

15.69 (V) PE 4032

17.50 (V) PE 4068

17.53 (V) PE 4032

17.62 (V) PE 3941

22.65 (V) PE 3941

10.53±0.15 EDD 3794

10.28±0.05 EDD 3626

11.3 El 3550

12.78±0.2 El 3484

12.83±0.03 El 3483

13.83±0.2 El 3484

13.97±0.2 El 3484

115
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c2 h3o

+ C6H5 CH2 CH2OCOCH3 (Acetic acid, 2-phenylethyl ester)

(RN-CAS Registry Number 103-45-7)

11.70 El 3590

c2 h3 o

+ C6H4(CH3)CH2CH2 OCOCH3 (Phenethyl alcohol, m-methyl-, acetate)

(RN-CAS Registry Number 33709-40-9)

11.90 El 3590

c2 h3 o

+ C6H4(CH3)CH2CH2OCOCH3 (Phenethyl alcohol, /J-methyl-, acetate)

(RN-CAS Registry Number 22532-47-4)

11.90 El 3590

c2h3o

+ C6H4(OCH3)OOCCH3 C6H4(0CH3)0

(Phenol, 3-methoxy-, acetate)

(RN-CAS Registry Number 5451-83-2)

13.92±0.2 El 3484

C2H3 0

+ C6H4(OCH3)OOCCH3 C6H4(0CH3)0

(Phenol, 4-methoxy-, acetate)

(RN-CAS Registry Number 1200-06-2)

14.57±0.2 El 3484

c2 h3 o

+ C6H4(OCH3)CH2CH2 OCOCH3 (Phenethyl alcohol, ra-methoxy-, acetate)

(RN-CAS Registry Number 33709-39-6)

11.80 El 3590

c2h3 o

+ C6H4(OCH3)CH2CH2OCOCH3 (Phenethyl alcohol, />-methoxy-, acetate)

(RN-CAS Registry Number 22532-51-0)

12.20 El 3590

c2h3 o

+ C6H4(COOH)OOCCH3 C6H4(C00H)0

(Benzoic acid, 4-(acetyloxy)-)

(RN-CAS Registry Number 2345-34-8)

12.46±0.2 El 3484

c2 h3o

+ C5 H8NCOCH3 (Pyridine, 1 -acetyl- 1 ,2, 3,4-tetrahydro-)

(RN-CAS Registry Number 19615-27-1)

13.5 El 4046

c2h3o

+ C5 H10NCOCH3 (Piperidine, 1 -acetyl-)

(RN-CAS Registry Number 618-42-8)

15.1 El 4046

c2h3 o

+ C6H5 NHCOCH3 (Acetamide, A-phenyl-)

(RN-CAS Registry Number 103-84-4)

13.22±0.03 El 3483

c2h3o

+ C6H4(NH2)CH2 CH2OCOCH3 (Benzeneethanol, 4-amino-, acetate(ester))

(RN-CAS Registry Number 33709-38-5)

12.30 El 3590

C2 H3 0

+ C6H4(N02)00CCH3 (Acetic acid, 3-nitrophenyl ester)

(RN-CAS Registry Number 1523-06-4)

(OP-the other product(s) is(are): cyc/o-QH^NOjX))

10.94±0.2 El 3484

c2 h3 o

+ C6H4(N02)00CCH3 (Acetic acid, 4-nitrophenyl ester)

(RN-CAS Registry Number 830-03-5)

(OP-the other product(s) is(are): cyc/o-C6H4(N02)0)

10.85±0.2 El 3484

c2 h3o

+ C6H4FOOCCH3 cyclo-C6H4FO

(Phenol, 2-fluoro-, acetate)

(RN-CAS Registry Number 29650-44-0)

12.23±0.03 El 3483

c2 h3 o

+ C6H4FOOCCH3 cyclo-C6H4FO

(Phenol, 4-fluoro-, acetate)

(RN-CAS Registry Number 405-51-6)

12.72±0.03 El 3483

116
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C2H30

+ c6h3f2oocch3 12.00±0.03 El 3480

(Phenol, 2,4-difluoro-, acetate)

(RN-CAS Registry Number 36914-77-9)

C2H30

+ c6h3f2oocch3 12.24±0.03 El 3480

(Phenol, 2,6-difluoro-, acetate)

(RN-CAS Registry Number 36914-78-0)

C2H30

+ ch3cocf3 11.45 El 3550

(RN-CAS Registry Number 421-50-1)

C2H30

+ c6h4fnhcoch3 13.59±0.03 El 3483

(Acetamide, Ar-(2-fluorophenyl)-)

(RN-CAS Registry Number 399-31-5)

C2H3 0

+ c6h4fnhcoch3 13.42±0.03 El 3483

(Acetamide, 7V-(4-fluorophenyl)-)

(RN-CAS Registry Number 351-83-7)

C2H30

+ c6h3f2nhcoch3 13.18±0.03 El 3480

(Acetamide, A-(2,4-difluorophenyl)-)

(RN-CAS Registry Number 399-36-0)

C2H30

+ c6h3f2nhcoch3 13.80±0.03 El 3480

(Acetamide, 7V-(2,6-difluorophenyl)-)

(RN-CAS Registry Number 3869-29-5)

C2H30

+ c6h4cioocch3 12.55±0.03 El 3483

(Acetic acid, 2-chlorophenyl ester)

(RN-CAS Registry Number 4525-75-1)

(OP-the other product(s) is(are): cyc/o-C6H4C10)

c2h3o

+ c6h4cioocch3 12.36±0.2 El 3484

(Acetic acid, 3-chlorophenyl ester)

(RN-CAS Registry Number 13031-39-5)

(OP-the other product(s) is(are): cyclo-C6H4(C1)0)

c2h3o

+ c6h4cioocch3 12.39±0.03 El 3483

(Acetic acid, 4-chlorophenyl ester)

(RN-CAS Registry Number 876-27-7)

(OP-the other product(s) is(are): cyc/o-C6H4C10)

C2H30

+ c6h4cioocch3 12.73+0.2 El 3484

(Acetic acid, 4-chlorophenyl ester)

(RN-CAS Registry Number 876-27-7)

(OP-the other produces) is(are): cyc/o-C6H4(Cl)0)

c2h3o

+ c6h4cich2ch2ococh3 11.60 El 3590

(Phenethyl alcohol, m-chloro-, acetate)

(RN-CAS Registry Number 33709-41-0)

C2H30

+ C6H3Cl2OOCCH3 12.11+0.03 El 3480

(Phenol, 2,4-dichloro-, acetate)

(RN-CAS Registry Number 6341-97-5)

C2H30

+ c6h3ci2oocch3 12.09±0.03 El 3480

(Phenol, 2,6-dichloro-, acetate)

(RN-CAS Registry Number 28165-71-1)

C2H30

+ c6h4cinhcoch3 13.91+0.03 El 3483

(Acetamide, A-(2-chlorophenyl)-)

(RN-CAS Registry Number 533-17-5)

c2h3o

+ c6h4cinhcoch3 13.00+0.03 El 3483

(Acetamide, A-(4-chlorophenyl)-)

(RN-CAS Registry Number 539-03-7)

117
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c2 h3 o

+ c6h3 ci2 nhcoch3 (Acetamide, ,/V-(2,4-dichlorophenyl)-)

(RN-CAS Registry Number 6975-29-7)

13.08±0.03 El 3480

c2 h3 o

+ c6h3 ci2 nhcoch3 (Acetamide, iV-(2,6-dichlorophenyl)-)

(RN-CAS Registry Number 17700-54-8)

13. 40 ±0.03 El 3480

C2 H3 0

+ C6H4BrCOOCH3 (Phenol, 2-bromo-, acetate)

(RN-CAS Registry Number 1829-37-4)

(OP-the other product(s) is(are): cyc/o-C6H4BrO)

12.24±0.03 El 3483

C2 H3 0

+ C6H4BrOOCCH3 (Phenol, 3-bromo-, acetate)

(RN-CAS Registry Number 35065-86-2)

(OP-the other product(s) is(are): cyc/o-C6H4(Br)0)

12.36+0.2 El 3484

C2 H3 0

+ C6H4BrOOCCH3 (Phenol, 4-bromo-, acetate)

(RN-CAS Registry Number 1927-95-3)

(OP-the other product(s) is(are): cyc/o-C6H4(Br)0)

12.87+0.2 El 3484

C2H30

+ C6 H4BrOOCCH3 (Phenol, 4-bromo-, acetate)

(RN-CAS Registry Number 1927-95-3)

(OP-the other product(s) is(are): cyclo-C6H4BrO)

13.06+0.03 El 3483

C2 H30

+ C6H3 Br2OOCCH3 (Phenol, 2,4-dibromo-, acetate)

(RN-CAS Registry Number 36914-79-1)

12.01+0.03 El 3480

C2H30

+ C6H3 Br2OOCCH3 (Phenol, 2,6-dibromo-, acetate)

(RN-CAS Registry Number 28165-72-2)

12.36+0.03 El 3480

C2 H30

+ C6H4BrNHCOCH3 (Acetamide, A^-(2-bromophenyl)-)

(RN-CAS Registry Number 614-76-6)

14.68±0.03 El 3483

C2H30

+ C6H4BrNHCOCH3 (Acetamide, 7V-(4-bromophenyl)-)

(RN-CAS Registry Number 103-88-8)

13.96+0.03 El 3483

C2H3 0

+ C6H3 Br2 NHCOCH3 (Acetamide, 7V-(2,4-dibromophenyl)-)

(RN-CAS Registry Number 23373-04-8)

13.10±0.03 El 3480

C2H30

+ C6H3 Br2NHCOCH3 (Acetamide, 7V-(2,6-dibromophenyl)-)

(RN-CAS Registry Number 33098-80-5)

13.21+0.03 El 3480

C2H3 0

+ C6H4IOOCCH3 cyclo-C6H4IO

(Phenol, 2-iodo-, acetate)

(RN-CAS Registry Number 32865-61-5)

12.47 ±0.03 El 3483

C2H30

+ C6H4IOOCCH3 cyclo-C6H4IO

(Phenol, 4-iodo-, acetate)

(RN-CAS Registry Number 33527-94-5)

12.74±0.03 El 3483

c2 h3o

+ c6h3 i 2oocch3 (Phenol, 2,4-diiodo-, acetate)

(RN-CAS Registry Number 36914-80-4)

12.15±0.03 El 3480

c2h3o

+ c6h3 i2oocch3 (Phenol, 2,6-diiodo-, acetate)

(RN-CAS Registry Number 28165-73-3)

118

12.02 ±0.03 El 3480
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C2H3 0

+ C6H4INHCOCH3 (Acetamide, A-(2-iodophenyl)-)

(RN-CAS Registry Number 19591-17-4)

13.56+0.03 El 3483

C2H30

+ C^INHCOCHj

(Acetamide, 7V-(4-iodophenyl)-)

(RN-CAS Registry Number 622-50-4)

13.16+0.03 El 3483

CH3CHO ** 10.20±0.03 PI 3765

(RN-CAS Registry Number 75-07-0)

C^O*

C2H50

+

(CH3)20 h

(RN-CAS-Registry Number 115-10-6)

CJIsOCHj CH3 (RN-CAS-Registry Number 540-67-0)

1 1 .55 ±0. 1

5

10.9 1 ±0.1

El

El

4071

4071

C2H3d2o ch3ocd3 d

(RN-CAS-Registry Number 13725-27-4)

1 1.53 ±0.

1

El 4071

c,h2d3o

+ ch3ocd3 H 11.15+0.1 El 4071

(RN-CAS-Registry Number 13725-27^1)

C2H2D30

+ C2H50CD3 ch3 11.01±0.1 El 4071

(RN-CAS-Registry Number 16995-14-5)

CAO+

CjH«0+ C2H60

+

(

2Bl)

cy^o*

CjHsOH ** (RN-CAS Registry Number 64-17-5)

CjHsOH ** (RN-CAS-Registry Number 64-17-5)

(CH3)2o

(RN-CAS Registry Number 115-10-6)

(CH^O

(RN-CAS Registry Number 115-10-6)

(CH3)2o

(RN-CAS-Registry Number 115-10-6)

10.62 (V) PE 3941

10.64 (V) PE 4068

10.04 (V) PE 3656

10.04 (V) PE 3844

10.12+0.2 El 4071

C2H3D30

+ CH3OCD3 ** 10.00±0.1 El 4071

(RN-CAS-Registry Number 13725-27-4)

C3H40

+ CH2 =CHCHO ** 10.13 PE 3864

(RN-CAS Registry Number 107-02-8)

C3H40

+ CH2 =CHCHO ** 11.07 (V) PE 3972

(RN-CAS Registry Number 107-02-8)

CjH6o

+ (CH3)2CO ** 9.71 ±0.03 PI 3765

(RN-CAS Registry Number 67-64-1)

0,^0+ (CH3)2CO ** 9.72 PE 3649

(RN-CAS Registry Number 67-64-1)

cjh6o

+ (CH3)2CO ** 9.75 ±0.025 PE 3626

(RN-CAS Registry Number 67-64-1)

CjH<,0 + (CH^CO ** 9.74 EDD 3485

(RN-CAS Registry Number 67-64-1)

c3H6o

+ CH2 =CHCH2OH ** 9.63 PE 3864

(RN-CAS Registry Number 107-18-6)

119
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c3 h6o

+ CH2 = CHCH2OH ** (RN-CAS Registry Number 107-18-6)

10.22 (V) PE 3863

c3 h6o

+ CH2 = CHOCH3 ** (RN-CAS Registry Number 107-25-5)

8.95 PE 3863

c3 h6o

+ c3 H6o

(Oxetane)

(RN-CAS Registry Number 503-30-0)

9.63 PE 3980

c3 d6o

+

c3 h7o

+

c3 h7o

+

c3 h7o

+

(CD3)2CO

(RN-CAS Registry Number 666-52-4)

QHjOCHj H

(RN-CAS-Registry Number 540-67-0)

«-C3 H7OH H

(RN-CAS Registry Number 71-23-8)

*-c3 h7oh h

(RN-CAS Registry Number 71-23-8)

9.68 PE 3649

10.32±0.1 El 4071

10.48±0.03 EDD 3626

10.2 El 3916

C3 H4D3 0

+ C^HjOCDj H 10.22±0.1 El 4071

(RN-CAS-Registry Number 16995-14-5)

c3 H8 o

+ c3 h8o

+

c3 h8o

+

c3 h8o

+

c3 h8o

+

c3 h8o

+ c3 h8o

+ c3 h8o

+

c,h5 och3 (RN-CAS-Registry

/i-C3HtOH

(RN-CAS Registry

/i-C3 H7OH

(RN-CAS-Registry

n-C3 H7OH

(RN-CAS Registry n-C3 HtOH

(RN-CAS Registry

n-C3 H7OH

(RN-CAS Registry

£h?-C3 H7OH

(RN-CAS-Registry

uo-CjHtOH

(RN-CAS Registry

Number 540-67-0)

** Number 71-23-8)

Number 71-23-8)

** Number 71-23-8)

** Number 71-23-8)

Number 71-23-8)

** Number 67-63-0)

Number 67-63-0)

9.62±0.1 El 4071

10. 15 ±0.025 PE 3626

10.49 (V) PE 4068

10.51 (V) PE 3941

10.16±0.03 EDD 3626

10.0 El 3916

10.36 (V) PE 4068

10.42 (V) PE 3941

c 9.64±0.1 El 4071 3 h5 d3o

+ C2H5OCD3 ** (RN-CAS-Registry Number 16995-14-5)

c4 h4o

+ c4h4o ** (Furan)

(RN-CAS-Registry Number 110-00-9)

8.91 ±0.01 PI 4058

c4 h4o

+ c4h4o ** (Furan)

(RN-CAS Registry Number 1 10-00-9)

8.99±0.05 El 3482

c4 h5 o

+ C5 H8 NCOCH = CHCH3 13.0 El 4046

(Pyridine, l,2,3,4-tetrahydro-l-(l-oxo-2-butenyl)-, (E))

(RN-CAS Registry Number 50838-23-8)

120
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c4h5o

+ C5H10NCOCH=CHCH3 **

(Piperidine, l-(l-oxo-2-butenyl)-, (E))

(RN-CAS Registry Number 50838-22-7)

14.6 El 4046

c4H6o

+ c4h6o

+

',4n6

v

c4H6o

c4h6o

ch2 =chcoch3 ** (RN-CAS Registry Number 78-94-4)

ch3ch=chcho ** (RN-CAS Registry Number 4170-30-3)

c4H6o

(Cyclobutanone)

(RN-CAS Registry Number 1191-95-3)

c4H6o

(Cyclobutanone)

(RN-CAS Registry Number 1191-95-3)

c4H6o

(Furan, 2,5-dihydro-)

(RN-CAS Registry Number 1708-29-8)

10.60 (V) PE 3972

10.28 (V) PE 3972

9.61 ±0.02 (V) PE 3517

9.58±0.1 EDD 3794

9.14±0.02 (V) PE 3843

9.54±0.03 PI 3765

9.41 S 3749

9.57±0.02 (V) PE 3843

10.37 (V) PE 4068

10.25 (V) PE 3941

-4n8

v

'41 l8v

(RS-Average

c4h8o

+

C2H5COCH3 ** (RN-CAS Registry Number 78-93-3)

c4h8o

(Furan, tetrahydro-)

(RN-CAS Registry Number 109-99-9)

of four Rydberg series limits)

c4h8o

(Furan, tetrahydro-)

(RN-CAS Registry Number 109-99-9)

c4H10o

c4h10o

n-C4H9OH ** (RN-CAS-Registry Number 71-36-3)

tert-C4H9OH ** (RN-CAS Registry Number 75-65-0)

c5h4o

+ c6h4o2 CO

(2,5-Cyclohexadiene- 1 ,4-dione)

(RN-CAS Registry Number 106-51-4)

11.10±0.05 PI 3523

c5 h„o+ c4h3och3 (Furan, 2-methyl-)

(RN-CAS Registry Number 534-22-5)

8.47±0.05 El 3482

c5 h8o

+ CH2 = C(OCH3)CH =CH2 ** (RN-CAS Registry Number 3588-30-5)

8.43 PE 3892

c5 h8o

+ trans-CH3OCH=CHCH=CH2 ** (RN-CAS Registry Number 10034-09-0)

8.03 PE 3892

C,H„0+ c5 h8o

(Cyclopentanone)

(RN-CAS Registry Number 120-92-3)

9.42±0.03 PI 3765

CsH„0+ c5H8o 9.25±0.02 (V) PE 3517

(Cyclopentanone)

(RN-CAS Registry Number 120-92-3)

121
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c5 h9o

+ n-C4H9 COCH3 ch3 (RN-CAS Registry Number 591-78-6)

9.4 El 3916

c5 h10o

+ *-C3 H7 COCH3 ** (RN-CAS Registry Number 107-87-9)

9.47+0.03 PI 3765

c5 h10o

+ c5 h10o

(2//-Pyran, tetrahydro-)

(RN-CAS Registry Number 142-68-7)

9.48 (V) PE 4082

c5 h10o

+ c5H10o

(2/7-Pyran, tetrahydro-)

(RN-CAS Registry Number 142-68-7)

9.50 (V) PE 3733

c6h4o

+ c6H4o

(Methanone, 2,4-cyclopentadien- 1 -ylidene-)

(RN-CAS Registry Number 4727-22-4)

8.95+0.1 El 3552

c6h4o

+ C5 H4 =CO ** (Methanone, 2,4-cyclopentadien- 1 -ylidene-)

(RN-CAS Registry Number 4727-22-4)

8.99+0.1 El 3553

c6h5o

+ c6h5och3 ch3 (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

c6h5o

+ c6h5 och3 ch3 (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

C6HsO

+ C6H4(OH)COOH co+oh

(Benzoic acid, 3-hydroxy-)

(RN-CAS Registry Number 99-06-9)

(MT-Metastable transition(s) observed)

C6Hs O

+ C6H4(OH)COOH co+oh

(Benzoic acid, 4-hydroxy-)

(RN-CAS Registry Number 99-96-7)

(MT-Metastable transition(s) observed)

c6h5o

+ c6h5no2 no

(Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

C6HsO

+ C6H4(N02)0H no2 (Phenol, 4-nitro-)

(RN-CAS Registry Number 100-02-7)

11.3 El

11.80+0.1 El

14.42+0.2 El

14.56+0.2 El

10.35+0.1 El

11.91+0.1 El

3916

3446

3973

3973

3447

3447

c6H6o

+ c6h5oh

(Phenol)

(RN-CAS Registry Number

**

108-95-2)

8.37 PE 3955

c6h6o

+ C6H5OH

(Phenol)

(RN-CAS Registry Number

**

108-95-2)

8.47+0.02 PE 3890

c6h6o

+ C6H5OH

(Phenol)

(RN-CAS Registry Number

**

108-95-2)

8.69 EDD 3485

c6h6o

+ QHjOH

(Phenol)

(RN-CAS Registry Number

**

108-95-2)

122

8.50 El 3845
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c6h6o

+ c6h5 oh

(Phenol)

(RN-CAS Registry Number 108-95-2)

c6h6o

+ c6h5 oc2h5 c2h4 (Benzene, ethoxy-)

(RN-CAS Registry Number 103-73-1)

(MT-Metastable transition(s) observed)

c6h6o

+ c7h6o2 CO

(2,4, 6-Cycloheptatrien- 1 -one, 2-hydroxy-)

(RN-CAS Registry Number 533-75-5)

(MT-Metastable transition(s) observed)

C6H60

+ C6H4(OH)OCH3 hcho

(Phenol, 4-methoxy-)

(RN-CAS Registry Number 150-76-5)

c6h6o

+ c6h5oocch3 ch2 =c=o

(Acetic acid, phenyl ester)

(RN-CAS Registry Number 122-79-2)

c6h6o

+ c6h5oocch3 ch2 =c=o

(Acetic acid, phenyl ester)

(RN-CAS Registry Number 122-79-2)

9.09±0.1 El

11.3 El

10.8 El

10.30 El

9.57+0.03 El

9.89+0.2 El

3817

3479

3479

3845

3483

3484

C6HgO

+ C4H3OC2H5 ** 8.45 ±0.05 El 3482

(Furan, 2-ethyl-)

(RN-CAS Registry Number 3208-16-0)

C6H80

+ C6Hg O ** 9.44±0.02 (V) PE 3843

(7-Oxabicyclo[2.2. l]hept-2-ene)

(RN-CAS Registry Number 6705-50-6)

c6h10o

+

c6h10o+

c6h10o

+

c6h10o

+

c6h10o

(Cyclohexanone)

(RN-CAS Registry Number 108-94-1)

c6H10o

(Cyclohexanone)

(RN-CAS Registry Number 108-94-1)

c6h10o

(Cyclohexanone)

(RN-CAS-Registry Number 108-94-1)

c6H10o

(7-Oxabicyclo[2.2. ljheptane)

(RN-CAS Registry Number 279-49-2)

9.14±0.03 PI 3765

9.14±0.02 (V) PE 3517

9.5+0.2 El 4074

9.57+0.02 (V) PE 3843

c6h12o

+ (CH3)3 CCOH3 ** (RN-CAS Registry Number 75-97-8)

8.88+0.04 PE 3851

c6h,2o+ (CH3)3 CCOCH3 ** (RN-CAS Registry Number 75-97-8)

9.18+0.03 PI 3765

c6h12o

+ «-C4H9COCH3 ** (RN-CAS Registry Number 591-78-6)

9.44±0.03 PI 3765

c6h12o

+ n-C4H9 COCH3 ** (RN-CAS Registry Number 591-78-6)

9.2 El 3916

123
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c7h5o

+ c6h5cho h

(Benzaldehyde)

(RN-CAS Registry Number 100-52-7)

C7H50

+ c6h5 coch3 ch3 (Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

C^O* QH5COCH3 CH3 (Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

(TR-Other product(s) thermochemically reasonable)

c7h5o

+ (c6h5)2co c6h5 (Methanone, diphenyl-)

(RN-CAS Registry Number 119-61-9)

(TR-Other product(s) thermochemically reasonable)

C^O4^ C6H5COOH OH

(Benzoic acid)

(RN-CAS Registry Number 65-85-0)

0^0+ C6H5 COOH oh

(Benzoic acid)

(RN-CAS Registry Number 65-85-0)

(TR-Other product(s) thermochemically reasonable)

C^O4 c6h5cooch3 ch3o

(Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

(TR-Other product(s) thermochemically reasonable)

C7H50

+ c6h5 cooc6h5 (Benzoic acid phenyl ester)

(RN-CAS Registry Number 93-99-2)

C7H50

+ QHsCOOC^OC^

(Phenol, 4-methoxy-, benzoate)

(RN-CAS Registry Number 1523-19-9)

C7H50

+ c6h5 conh2 nh2 (Benzamide)

(RN-CAS Registry Number 55-21-0)

(TR-Other product(s) thermochemically reasonable)

C^O4 c5 h8ncoc6h5 (Pyridine, l-benzoyl-l,2,3,4-tetrahydro-)

(RN-CAS Registry Number 50838-24-9)

C^O4 c5 h10ncoc6h5 (Piperidine, 1 -benzoyl-)

(RN-CAS Registry Number 776-75-0)

C7H50

+ c6h5cooc6h4no2 (Benzoic acid 4-nitro phenyl ester)

(RN-CAS Registry Number 959-22-8)

C7HsO

+ CftHsCOCl Cl

(Benzoyl chloride)

(RN-CAS Registry Number 98-88-4)

(TR-Other product(s) thermochemically reasonable)

11.26 El 3792

9.6 El 3916

10.38 El 3792

11.72 El 3792

12. 11 ±0.2 El 3973

12.11 El 3792

11.40 El 3792

10.0 El 3897

10.6 El 3897

11.09 El 3792

12.4 El 4046

14.4 El 4046

10.2 El 3897

10.31 El 3792

C,H60

+ C6H5 CHO ** 9.50±0.02 PI 4057

(Benzaldehyde)

(RN-CAS-Registry Number 100-52-7)

124
Table of Ion Energetics Measurements—Continued

Ion

c7H6o

+

c7 h6o

+

c7h6o

+

c7h6o

+

c7 h6o

+

Reactant

C6H5CHO

(Benzaldehyde)

(RN-CAS Registry Number

c7H6o

(Benzaldehyde)

(RN-CAS Registry Number

C6H5CHO

(Benzaldehyde)

(RN-CAS Registry Number

C6H5CHO

(Benzaldehyde)

(RN-CAS Registry Number

C6H5CH2C6H4OH

Other

products

Ionization or appearance

potential

(eV)

Method Ref.

** 9.50±0.02 PI 4031

100-52-7)

** 9.6 PI 3586

100-52-7)

** 9.40 PE 3938

100-52-7)

** 9.74 El 3792

100-52-7)

C6H5 11.1 ±0.2 El 3807

(Phenol, 4-(phenylmethyl)-)

(RN-CAS Registry Number 101-53-1)

c7h7o

+ C6H4(OCH3)CH3 ch3 (Benzene, l-methoxy-3-methyl-)

(RN-CAS Registry Number 100-84-5)

C7H70

+ C6H4(OCH3)CH3 ch3 (Benzene, l-methoxy-4-methyl-)

(RN-CAS Registry Number 104-93-8)

C7H70

+ C6H4(OH)C4H9 (Phenol, 3-butyl-)

(RN-CAS Registry Number 4074-43-5)

C7H70

+ C6H4(OH)C4H9 (Phenol, 4-butyl-)

(RN-CAS Registry Number 1638-22-8)

C7H70

+ C6H4(CH3)OOCCH3 ch3 co

(Acetic acid, 2-methylphenyl ester)

(RN-CAS Registry Number 533-18-6)

C7H70

+ C6H4(CH3)OOCCH3 ch3co

(Acetic acid, 4-methylphenyl ester)

(RN-CAS Registry Number 140-39-6)

c7h7o

+ C6H4(OCH3)COOH cooh

(Benzoic acid, 3-methoxy-)

(RN-CAS Registry Number 586-38-9)

(MT-Metastable transition(s) observed)

C7H70

f C6H4(OCH3)COOH cooh

(Benzoic acid, 4-methoxy-)

(RN-CAS Registry Number 100-09-4)

(MT-Metastable transition(s) observed)

C7H70

+ C6H4(N02)CH3 no

(Benzene, l-methyl-3-nitro-)

(RN-CAS Registry Number 99-08-1)

C7H70

+ C6H4(N02)CH3 no

(Benzene, 1 -methyl-4-nitro-)

(RN-CAS Registry Number 99-99-0)

C7H70

+ C6H4(N02)0CH3 no2 (Benzene, 1 -methoxy-3-nitro-)

(RN-CAS Registry Number 555-03-3)

11.60±0.1 El 3446

11. 45 ±0.1 El 3446

12.79±0.1 El 3629

11.45 ±0.1 El 3629

13.16±0.02 El 3631

13.47 ±0.02 El 3631

13.07±0.2 El 3973

12.80±0.2 El 3973

9.98±0.1 El 3447

10.34±0.1 El 3447

11. 44 ±0.1 El 3447

125
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C7H70

+ C6H4(N02)0CH3 no2 (Benzene, l-methoxy-4-nitro-)

(RN-CAS Registry Number 100-17-4)

1 1.63±0.1 El 3447

C7H8o

+ C6H5 CH2OH ** (Benzenemethanol)

(RN-CAS Registry Number 100-51-6)

9.00±0.

El 3788

c7h8o

+ C6H5OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.20±0.02 PE 3890

C6H5OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.42 (V) PE 3781

c7 h8o

+ C6H5OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.20 El 3845

c7h8o

+ C6H5 OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.20 El 3845

c7h8o

+ C6H5 OCH3 (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.25±0.1 El 3788

c7h8o

+ C6H5 OCH3 (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.39±0.1 El 3446

CjUtO* C6H5OCH3 (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.6 El 3916

QHgO* C6H5OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.6 El 3479

c7H8o

+ C6H5 OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.76± <0.1 El 3735

c7 h8o+ C6H5 OCH3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

8.18 CTS 3758

C7H80

+ c6h5 och3 ** (Benzene, methoxy-)

(RN-CAS Registry Number 100-66-3)

(AV-Average of two values)

8.37 CTS 4029

c7H8o

+ C6H4(OH)CH3 (Phenol, 2-methyl-)

(RN-CAS Registry Number 95-48-7)

8.24±0.02 PE 3890

c7h8o

+ C6H4(OH)CH3 (Phenol, 4-methyl-)

(RN-CAS Registry Number 106-44-5)

8.34 El 4089

c7h8o

+ C6H4(OH)C4H9 ch2 = chch3 (Phenol, 3-butyl-)

(RN-CAS Registry Number 4074-43-5)

1 1.07±0.El 3629

126
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

C7HgO+ C6H4(OH)C4H9 CH2 = CHCH3 10.32±0.1 El

(Phenol, 4-butyl-)

(RN-CAS Registry Number 1638-22-8)

C7H80

+ C6H4(OCH3)2 CH20 10.98±0.1 El

(Benzene, 1,3-dimethoxy-)

(RN-CAS Registry Number 151-10-0)

C7Hg O

+ C6H4(OCH3)2 HCHO 11.00 El

(Benzene, 1,4-dimethoxy-)

(RN-CAS Registry Number 150-78-7)

C7H8 0

+ C6H4(CH3)OOCCH3 CH2 =C=0 9.44±0.02 El

(Acetic acid, 2-methylphenyl ester)

(RN-CAS Registry Number 533-18-6)

C7H80

+ C6H4(CH3)OOCCH3 CH2 = C = 0 10.03 ±0.2 El

(Acetic acid, 3-methylphenyl ester)

(RN-CAS Registry Number 122-46-3)

0^0+ C6H4(CH3)OOCCH3 CH2 =C=0 9.26±0.02 El

(Acetic acid, 4-methylphenyl ester)

(RN-CAS Registry Number 140-39-6)

C7H80+ C6H4(CH3)OOCCH3 CH2 = C=0 9.75+0.2 El

(Acetic acid, 4-methylphenyl ester)

(RN-CAS Registry Number 140-39-6)

C7H8 0

+ C6H5OOCOCH3 C02 10.3 El

(Carbonic acid, methyl phenyl ester)

(RN-CAS Registry Number 13509-27-8)

(MT-Metastable transition(s) observed)

0^0+ C6H5 CH2OHCr(CO)3 9.40±0.1 El

(Chromium, [( 1 ,2, 3,4, 5

,

6-T))-benzenemethanol]tricarbony1-) (RN-CAS Registry Number 12116-45-9)

C^gO* C6H5OCH3 Cr(CO)3 8.45+0.1 El

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5

,

6-i7)-methoxybenzene]-)

(RN-CAS Registry Number 12116-44-8)

3629

3446

3845

3631

3484

3631

3484

3479

3788

3788

** 9.17±0.02 (V) PE 3517

(Cycloheptanone)

(RN-CAS Registry Number 502-42-1)

C7H120+ C6H9( =0)CH3 ** 9. 5+0.2 El 4074

(Cyclohexanone, 2-methyl-)

(RN-CAS-Registry Number 583-60-8)

C7H140

+ («-C3 H7)2CO ** 9.12+0.03 PI 3765

(RN-CAS Registry Number 123-19-3)

C7H140

+ C6H10(OH)CH3 ** 9.8±0.2 El 4074

(Cyclohexanol, 1 -methyl-)

(RN-CAS-Registry Number 590-67-0)

C8H70

+ C6H4(CH3 )COOH OH 12.38+0.2 El 3973

(Benzoic acid, 3-methyl-)

(RN-CAS Registry Number 99-04-7)

C8 H70

+ C6H4(CH3)COOH OH 12.07+0.2 El 3973

(Benzoic acid, 4-methyl-)

(RN-CAS Registry Number 99-94-5)

127
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8 h7o

+ c6h5 cococ6h4ch3 c6h5 co

(Ethanedione, (4-methylphenyl)phenyl-)

(RN-CAS Registry Number 2431-00-7)

(TR-Other product(s) thermochemically reasonable)

9.84±0.10 SD 3823

c8h8o

+ C6H5 CH2CHO ** (Benzeneacetaldehyde)

(RN-CAS Registry Number 122-78-1)

c8 h8o

+ c6h5coch3 ** (Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

c8 h8o

+ c6h5 coch3 ** (Ethanone, 1 -phenyl-)

(RN-CAS-Registry Number 98-86-2)

c8 h8o

+ c8h8o ** (Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

c8 h8o

+ c6h5 coch3 ** (Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

C8 HgO

+ QHjCOCHj ** (Ethanone, 1 -phenyl-)

(RN-CAS Registry Number 98-86-2)

8.80 PE 3938

9.29±0.2 PI 4031

9.29±0.2 PI 4057

9.6 PI 3586

9.1 El 3916

9.50 El 3792

c8h9o

+ C6H4(OCH3)C4H9 (Benzene, l-butyl-3-methoxy-)

(RN-CAS Registry Number 20893-43-0)

12.04±0.1 El 3629

C8 H90 + C6H4(OCH3)C4H9 (Benzene, l-butyl-4—methoxy-)

(RN-CAS Registry Number 18272-84-9)

10.79±0.1 El 3629

c8 h9o

+ C6H5CH2C6H4OCH3 c6h5 (Benzene, 1 -methoxy-4-(phenylmethyl)-)

(RN-CAS Registry Number 834-14-0)

1 1.9±0.1 El 3807

c8 h9o

+ C6H4(OCH3)CH2CH2OCOCH3 (Phenethyl alcohol, /n-methoxy-, acetate)

(RN-CAS Registry Number 33709-39-6)

12.10 El 3590

c8h9o

+ C6H4(OCH3)CH2CH2OCOCH3 (Phenethyl alcohol, p-methoxy-, acetate)

(RN-CAS Registry Number 22532-51-0)

11.50 El 3590

c8 H10o

+

c8 h10o

+

c8 h10o

+

c8 h10o

+

c6h5oc2h5 (Benzene, ethoxy-)

(RN-CAS Registry Number 103-73-1)

QHjCHjOCI^ ** (Benzene, (methoxymethyl)-)

(RN-CAS Registry Number 538-86-3)

C6H4(OCH3)CH3 ** (Benzene, l-methoxy-2-methyl-)

(RN-CAS Registry Number 578-58-5)

C6H4(OCH3)CH3 ** (Benzene, l-methoxy-3-methyl-)

(RN-CAS Registry Number 100-84-5)

128

8.6 El 3479

9.12 (V) PE 3781

8.03 ±0.02 PE 3890

8.35 ±0. 1 El 3446
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method

products potential

(eV)

CgH10O

+

CgH10O

+

C8 H10O

+

c8h10o

+

CgH10O

+

cgH10o

+

C6H4(OCH3)CH3 ** (Benzene, l-methoxy-4-methyl-)

(RN-CAS Registry Number 104-93-8)

C6H4(OCH3)CH3 ** (Benzene, l-methoxy-4-methyl-)

(RN-CAS Registry Number 104-93-8)

C6H4(OCH3)CH3 ** (Benzene, l-methoxy-4-methyl-)

(RN-CAS Registry Number 104-93-8)

QH^CH^OH

(Phenol, 2,6-dimethyl-)

(RN-CAS Registry Number 576-26-1)

C8H10O

(Tricyclo[3.2. l.O^Joctan-S-one, (la,2a, 4a, 5 a)-)

7.85

8.33±0.1

7.91

8.05 ±0.02

8.8 =1= 0.

1

(RN-CAS Registry Number 14224-86-3)

(ON-Other name: Tricyclo[3.2.1.02,4]octan-8-one, endo-)

CgH10O ** 9.2±0.1

(Tricyclo[3.2.1.02,4]octan-8-one, exo-)

(RN-CAS Registry Number 7076-83-7)

CgH10O

+ C6H4(OCH3)C4H9 CH2 =CHCH3 10.52±0.1

(Benzene, l-butyl-3-methoxy-)

(RN-CAS Registry Number 20893-43-0)

C8H10O

+ C6H4(OCH3)C4H9 CH2 =CHCH3 10.38±0.1

(Benzene, l-butyl-4-methoxy-)

(RN-CAS Registry Number 18272-84-9)

CgHjoO4- CeHjOOCOCjHs C02 10.0 (Carbonic acid, ethyl phenyl ester)

(RN-CAS Registry Number 3878-46-4)

(MT-Metastable transition(s) observed)

El

El

CTS

PE

El

El

El

El

El

Ref.

3845

3446

3758

3890

3492

3492

3629

3629

3479

c8h12o+

CgH120

+

C*Hi20

+

c8h12o

+

c8huoh

(Tricyclo[3.2.1.02,4]octan-8-ol, endo-syn-)

(RN-CAS Registry Number 7076-81-5)

CgHnOH

(Tricyclo[3.2. 1 .O^^octan-S-ol, endo-anti-)

(RN-CAS Registry Number 16384-97-7)

CgHnOH

(Tricyclo[3.2.1.02,4]octan-8-ol, exo-syn-)

(RN-CAS Registry Number 7076-80-4)

CgHnOH

(Tricyclo[3.2.1.02,4]octan-8-ol, exo-anti-)

8. 8 ±0.1 El 3492

9.1 ±0.1 El 3492

9.1 ±0.1 El 3492

9.3 ±0.1 El 3492

C8H140

+ CgH140 ** 9.09±0.02 (V) PE 3517

(Cyclooctanone)

(RN-CAS Registry Number 502-49-8)

C8 H160

+ n-C6H13 COCH3 ** 9.40±0.03 PI 3765

(RN-CAS Registry Number 111-13-7)

C8H160

+ n-C4H9COCH2CH2CH3 ** 9.10±0.05 PI 3765

(RN-CAS Registry Number 589-63-9)

129
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c9h9o^ C6H2(CH3)2(CH2 D)CHO ch2 d

(Benzaldehyde, 2,4-dimethyl-5-(methyl-</-)-)

(RN-CAS Registry Number 38479-87-7)

12.3±0.1 El 4041

c9h9o

+ C6H2 (CH3)2 (CH2 D)CHO ch2 d

(Benzaldehyde, 2, 5-dimethyl-4-(methyl-d)-)

(RN-CAS Registry Number 38479-86-6)

1 1.4±0.1 El 4041

c9h8 do+ C6H2(CH3)2(CH2 D)CHO ch3 (Benzaldehyde, 2,4-dimethyl-5-(methyl-*/-)-)

(RN-CAS Registry Number 38479-87-7)

1 1.5±0.1 El 4041

c9h8 do+ C6H2 (CH3)2(CH2 D)CHO ch3 (Benzaldehyde, 2,5-dimethyl-4-(methyl-£f)-)

(RN-CAS Registry Number 38479-86-6)

11.4±0.1 El 4041

c9h10o+ C6H4(OCH3)CH2 CH2OCOCH3 (Phenethyl alcohol, m-methoxy-, acetate)

(RN-CAS Registry Number 33709-39-6)

8.40 El 3590

c9h10o

+ C6H4(OCH3)CH2CH2OCOCH3 (Phenethyl alcohol, /7-methoxy-, acetate)

(RN-CAS Registry Number 22532-51-0)

8.25 El 3590

"9rM2'

'91 1 12'

C6H3 (CH3)2OCH3 (Benzene, 2-methoxy- 1

, 3-dimethyl-)

(RN-CAS Registry Number 1004-66-6)

CioH 1202 CO

(2,5-Cyclohexadiene-l,4-dione, 2,3,5,6-tetramethyl-)

(RN-CAS Registry Number 527-17-3)

8.10±0.02

10.1 ±0.05

PE

PI

3890

3523

c9h18o

+ c9h18o

+

((CH3)3C)2CO

(RN-CAS Registry Number 815-24-7)

(ko-C4H9)2CO ** (RN-CAS Registry Number 108-83-8)

8.65±0.03

9.04±0.03

PI

PI

3765

3765

C10HU DO+ C6H2(CH3)2(CH2 D)CHO ** (Benzaldehyde, 2,4-dimethyl-5-(methyl-</-)-)

(RN-CAS Registry Number 38479-87-7)

8.7±0.1 El 4041

C10Hn DO+ C6H2(CH3)2(CH2D)CHO ** (Benzaldehyde, 2,5-dimethyl-4-(methyl-</)-)

(RN-CAS Registry Number 38479-86-6)

8.7±0.1 El 4041

c10h14o

+ C6H4(OH)C4H9 (Phenol, 3-butyl-)

(RN-CAS Registry Number 4074-43-5)

8.92±0.1 El 3629

C10H14O

+ C6H4(OH)C4H9 (Phenol, 4-butyl-)

(RN-CAS Registry Number 1638-22-8)

8.67±0.1 El 3629

C{0HhO

+ C6H4(OH)C4H9 8.10±0.02 PE 3890

(Phenol, 2-(l,l-dimethylethyl-)

(RN-CAS Registry Number 88-18-6)

130
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c10h14o

+ c10h14o

(Tricyclo[3.3. 1. l

3,7]decan-2-one)

(RN-CAS Registry Number 700-58-3)

(ON-Other name: Adamantanone)

8.59 PE 3886

C10H16O

+ C10H16O ** 8.76+0.03 PI 3765

(Bicyclo[2,2, 1 Jheptan-2-one, 1,7,7-trimethyl-)

(RN-CAS Registry Number 76-22-2)

C10H16O

+ C10H15OH ** 9.09+0.05 PE 3886

(Tricyclo[3.3. 1. l

3,7]decan-l-ol)

(RN-CAS Registry Number 768-95-6)

(ON-Other name: 1-Adamantanol)

C10H16O

+ C10H15OH ** 9.09+0.07 PE 3886

(Tricyclo[3.3. 1. l

3,7]decan-2-ol)

(RN-CAS Registry Number 700-57-2)

(ON-Other name: 2-Adamantanol)

CuH10O

+ C10H7OCH3 ** 7.72 (V) PE 3781

(Naphthalene, 1-methoxy-)

(RN-CAS Registry Number 2216-69-5)

CnH10O

+ C10H7OCH3 ** 7.87 (V) PE 3781

(Naphthalene, 2-methoxy-)

(RN-CAS Registry Number 93-04—9)

CnH120

+ C2oH2602 11.46+0.05 El 3571

(Z)-Homoestra- 1 , 3, 5( 1 0)-trien- 1 7a-one, 3-methoxy-)

(RN-CAS Registry Number 1232-89-9)

CnH120

+ C2oH2602 11.20+0.05 El 3571

(D-Homoestra- 1 , 3, 5( 1 0)-trien- 1 7a-one, 3-methoxy-, (8a)-)

(RN-CAS Registry Number 1232-88-8)

CnH130

+ C6(CH3)4(CH2D)CHO CH2D 11.2+0.1 El 4041

(Benzaldehyde, 2,3,5, 6-tetramethyl-4-(methy

(RN-CAS Registry Number 43022-36-2)

CuH12DO+ C6(CH3)4(CH2D)CHO CH3 11.2+0.1 El 4041

(Benzaldehyde, 2,3,5, 6-tetramethyl-4—(methy\-d)~)

(RN-CAS Registry Number 43022-36-2)

C„H160

+ C6H4(OCH3)C4H9 ** 8.17+0.1 El 3629

(Benzene, l-butyl-3-methoxy-)

(RN-CAS Registry Number 20893-43-0)

C„H160

+ QH^OCH^QH, ** 8.24±0.1 El 3629

(Benzene, l-butyl-4-methoxy-)

(RN-CAS Registry Number 18272-84-9)

CuH160

+ C10H13(=O)CH3 ** 9.6+0.2 El 4074

(2(3//)-Naphthalenone, 4,4a,5,6,7,8-hexahydro-4a-methyl-)

(RN-CAS-Registry Number 826-56-2)

131
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c12 h10o

+ C6H5C6H4OH

([1,1 '-Biphenyl]-2-ol)

(RN-CAS Registry Number 90-43-7)

7.80±0.02 PE 3702

c12 h15 do+ C6(CH3)4(CH2 D)CHO ** (Benzaldehyde, 2,3,5,6-tetramethyl-4-(methyl-</)-)

(RN-CAS Registry Number 43022-36-2)

8.3 ±0.

El 4041

c12h18o

+ C10H15 COCH3 ** (Ethanone, l-tricyclo[3.3. 1 .

3,7 ]dec- 1 -yl-)

(RN-CAS Registry Number 1660-04-4)

8.82±0.05 PE 3851

(ON-Other name: 1-Acetyladamantane)

C13 HgO

+ C13 H80 ** 8.36±0.02 PI 3523

(9//-Fluoren-9-one)

(RN-CAS Registry Number 486-25-9)

c13 h10o

+ (C6H5)2CO

(Methanone, diphenyl-)

(RN-CAS-Registry Number 119-61-9)

c13 h10o

+ (c6h5)2 co • (Methanone, diphenyl-)

(RN-CAS Registry Number 119-61-9)

c13 h10o

+ (C6H5)2 CO

(Methanone, diphenyl-)

(RN-CAS Registry Number 119-61-9)

c13 hI0o

+ (c6h5)2co

(Methanone, diphenyl-)

(RN-CAS Registry Number 119-61-9)

9.14±0.03 PI 4057

9.14±0.03 PI 4031

9.4 PI 3586

9.46 El 3792

c13 h„o+ c6h5 ch2c6h4och3 ch3 (Benzene, 1 -methoxy-4-(phenylmethyl)-)

(RN-CAS Registry Number 834-14—0)

11.9±0.1 El 3807

c13 h12o+ c6h5 ch2c6h4oh ** (Phenol, 4-(phenylmethyl)-)

(RN-CAS Registry Number 101-53-1)

8.45 ±0.05 El 3806

c14hI0o+ c14h10o

(9(10//)-Anthracenone)

(RN-CAS Registry Number 90-44-8)

8.83±0.03 PI 3523

c14h14o

+ QHjCHzQIijOCHj ** (Benzene, 1 -methoxy-4-(phenylmethyl)-)

(RN-CAS Registry Number 834-14-0)

8.20±0.05 El 3806

c14h22o

+ C6H3 (C4H9)2OH 7.70±0.02 PE 3890

(Phenol, 2,6-bis( 1 , 1 -dimethylethyl-)

(RN-CAS Registry Number 128-39-2)

132
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

C14H220

+ C6H3(C4H9)2OH ** 7.90±0.02 PE 3890

(Phenol, 3,5—bis(l, 1-dimethylethyl-)

(RN-CAS Registry Number 1138-52-9)

C15H150

+ C20H22O2 11.46±0.05 El 3571

(D-Homoestra- 1 , 3, 5( 1 0),6, 8-pentaen- 1 7a-one, 3-methoxy-)

(RN-CAS Registry Number 1232-90-2)

C15H150

+ C20H22O2 10.84±0.09 El 3571

(£>-Homoestra-l,3,5(10),6,8-pentaen-17a-one, 3-methoxy-, (14y3)-)

(RN-CAS Registry Number 1232-91-3)

C16H10O

+

Cj6H,0O ** 7.95 (V) PE 4088

(4,6-Ethenodibenz[Z>/|oxepine, (Z,Z)-)

(RN-CAS Registry Number 42073-03-0)

(ON-Other name: 8, 16-Oxido-c«[2.2]metacyclophane- 1,9-diene)

c16H16o

+

c16h16o

+

v-^xj.2^2 ch2o2+ ch2o2+ ch2o2+ ch2o?

ch2o?

C20H22O2 10.79±0.07

(Z>-Homoestra-l,3,5(10),6,8-pentaen-17a-one, 3-methoxy-)

(RN-CAS Registry Number 1232-90-2)

C2oH2202 10.44±0.11

(Z)-Homoestra- 1 ,3, 5( 10), 6, 8-pentaen- 1 7a-one, 3-methoxy-, (14/3)—)

(RN-CAS Registry Number 1232-91-3)

El

El

HCOOH ** (RN-CAS Registry Number 64-18-6)

HCOOH ** (RN-CAS Registry Number 64-18-6)

HCOOH ** (RN-CAS Registry Number 64-18-6)

HCOOH ** (RN-CAS Registry Number 64-18-6)

HCOOH ** (RN-CAS Registry Number 64-18-6)

HCOOH ** (RN-CAS Registry Number 64-18-6)

3571

3571

c18h18o

+ C6H8(=0)(C6H5)2 (Cyclohexanone, 4,4-diphenyl-)

(RN-CAS-Registry Number 4528-68-1)

8.8±0.2 El 4074

^19^20^+ C6H7( =0)(CH3)(C6H5)2 (Cyclohexanone, 2-methyl-5,5-diphenyl-)

(RN-CAS-Registry Number 50592-49-9)

8.8±0.2 El 4074

Ci9H220

+ C6H8(OH)(CH3)(C6H5)2 (Cyclohexanol, 1 -methyl-4,4-diphenyl-)

(RN-CAS-Registry Number 50592-47-7)

9.2±0.2 El 4074

c23h24o+ C10H, , ( =0)(CH3)(C6H5)2 ** 8.9±0.2

(2(3/f-Naphthalenone, 4,4a,5,6, 7,8-hexahydro-4a-methyl-7,7-diphenyl-)

(RN-CAS-Registry Number 50786-03-3)

El

1 4074

11. 05 ±0.03 PI 3765

11.3 PE 3883

11.33 PE 3874

11.35+0.03 PE 3734

12.4 PE 3883

16.9 PE 3883

133
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c2 h4o2+ CH3 COOH ** (RN-CAS Registry Number 64-19-7)

10.38±0.03 PI 3765

c2 h4o2+ CH3 COOH ** (RN-CAS Registry Number 64-19-7)

10.65 PE 3874

c2 h4o2+ CH3 COOH ** (RN-CAS Registry Number 64-19-7)

10.69+0.03 PE 3734

c2 h4o2+ CH3 COOH ** (RN-CAS Registry Number 64-19-7)

10.70 PE 3718

c2 h4o2+ HCOOCH3 ** (RN-CAS Registry Number 107-31-3)

10.85 PE 3718

c3 h4o2+ ch2 =chcooh ** (RN-CAS Registry Number 79-10-7)

10.60 PE 3864

c3 h6o2+ C2H5 COOH ** (RN-CAS Registry Number 79-09-4)

10.44+0.03 PE 3734

c3 h6o2+ C2 H5 COOH ** (RN-CAS Registry Number 79-09-4)

10.54 PE 3874

c3 h6o2+ CH3 COOCH3 ** (RN-CAS Registry Number 79-20-9)

10.33 PE 3718

c3 h6o2+ CH3 COOCH3 ** (RN-CAS Registry Number 79-20-9)10.59 (V) PE 3937

c3 h6o2+ HCOOC2H5 ** (RN-CAS Registry Number 109-94-4)

10.62 PE 3718

c3 h6o2+ c3h6o2 (1,3-Dioxolane)

(RN-CAS Registry Number 646-06-0)

10.1 (V) PE 3733

c4h2o2+ c6h4o2 c2h2 (2,5-Cyclohexadiene- 1 ,4-dione)

(RN-CAS Registry Number 106-51-4)

11.2+0.05 PI 3523

c4h4o2+ C4H40(=0) **

(2(3//)-Furanone) (RN-CAS Registry Number 20825-71-2)

10.70 (V) PE 3826

c4h6o2+ CH2 =CHCOOCH3 ** (RN-CAS Registry Number 96-33-3)

10.72 (V) PE 3937

c4h6o2+ CH2 = CHCOOCH3 ** (RN-CAS Registry Number 96-33-3)

10.72 (V) PE 3972

c4h6o2+ CH3 COCOCH3 ** (RN-CAS Registry Number 431-03-8)

9.55 (V) PE 3936

c4h6o2+ c4h6o( = O)

(2(37/)~Furanone, dihydro-)

(RN-CAS Registry Number 96-48-0)

10.26 (V) PE 3826

c4h8o2+ CH3 CH(CH3)COOH ** (RN-CAS Registry Number 79-31-2)

10.30 (V) PE 3937

c4h8o2+ HCOOCH2CH2CH3 ** (RN-CAS Registry Number 110-74-7)

10.62 PE 3718

c4h8o2+ CH3 COOC2 H5 ** 10.24 PE 3718

(RN-CAS Registry Number 141-78-6)

134
Table of Ion Energetics Measurements—Continued

Ion

c4H8o2+ c4h8o2+ c4h8o2+ c4h8o2+ c4h8o2+

c4h8o2+

c4h8o2+

c4h8o2+

Reactant Other

products

h-C3H7COOH ** (RN-CAS Registry Number 107-92-6)

n-C3 H7COOH

(RN-CAS Registry Number 107-92-6)

«o-C3H7COOH ** (RN-CAS Registry Number 79-31-2)

£so-C3H7COOH ** (RN-CAS Registry Number 79-31-2)

c4H8o2 (1,3-Dioxane)

(RN-CAS Registry Number 505-22-6)

c4H8o2 (1,3-Dioxane)

(RN-CAS Registry Number 505-22-6)

c4H8o2 (1,4-Dioxane)

(RN-CAS Registry Number 123-91-1)

c4H8o2 (1,4-Dioxane)

(RN-CAS Registry Number 123-91-1)

Ionization or appearance

potential

(eV)

Method Ref.

10.46 PE 3874

10.22 (V) PE

10.33+0.03 PE 3734

10.33 PE 3874

10.1 (V) PE 3733

10.12 (V) PE 4082

9.41 (V) PE 4082

9.43 (V) PE 3733

c5h4o2+ c5h4o2 ** 10.25 (V) PE 3826

(4-Cyclopentene- 1 ,3-dione)

(RN-CAS Registry Number 930-60-9)

c5h4o2+ C4H3OCHO ** 9.50+0.05 El 3482

(2-Furancarboxaldehyde)

(RN-CAS Registry Number 98-01-1)

C,H602f

CsHjO?

QH^O),

( 1 , 3-Cyclopentanedione)

(RN-CAS Registry Number 3859-41-4)

C5H5(=0)0H ** (2-Cyclopenten-l-one, 3-hydroxy-)

(RN-CAS Registry Number 5870-62-2)

9.46+0.05

9.22+0.05 (V)

PE

PE

3848

3848

c5h8o2+ CH2 =C(CH3)COOCH3 ** (RN-CAS Registry Number 80-62-6)

10.28 (V) PE 3937

C5 HsO+ CH2 =C(CH3)COOCH3 ** (RN-CAS Registry Number 80-62-6)

10.28 (V) PE 3972

c5 h8o2+ CH3COCH2COCH3 ** (RN-CAS Registry Number 123-54-6)

8.85±0.05 PE 3848

cs h8o2+ CH3COCH2COCH3 ** (RN-CAS Registry Number 123-54-6)

9. 18 ±0.07 (V) PE 3682

c5h8o2+ CH3CH=CHCOOCH3 * * (RN-CAS Registry Number 18707-60-3)

10.11 (V) PE 3972

C5H10O2+ c5h10o2+ c5h10o2+

CH3COOCH(CH3)2 ** (RN-CAS Registry Number 108-21-4)

HCOO(CH2)3CH3 ** (RN-CAS Registry Number 592-84-7)

«-C4H9COOH ** (RN-CAS Registry Number 109-52-4)

135

10.08 PE 3718

10.54 PE 3718

10.53 (V) PE 3874
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c5 h10o2+

c5 h10o2+

im-C4H9COOH ** (RN-CAS Registry Number 503-74-2)

C3 H402(CH3)2 (1,3-Dioxolane, 2,2-dimethyl-)

(RN-CAS Registry Number 2916-31-6)

10.51 (V)

9.71 (V)

PE

PE

3874

3733

c6h4o+ c6H4o2 (2, 5-Cyclohexadiene- 1 ,4—dione)

(RN-CAS Registry Number 106-51-4)

9.7 PI 3586

c6h4o2+ c6h4o2 (2, 5-Cyclohexadiene- 1 ,4—dione)

(RN-CAS Registry Number 106-51-4)

9.96+0.01 PI 3523

c6h4o+ c6h4(=o)2 (2,5-Cyclohexadiene- 1 ,4—dione)

(RN-CAS Registry Number 106-51-4)

10.03 (V) PE 3936

c6h5o2+

c6h5o2+

QH5o2+

c6h5o2+

C6H4(OH)OCH3 ch3 (Phenol, 4-methoxy-)

(RN-CAS Registry Number 150-76-5)

C6H4(OH)OOCCH3 ch3co

(Benzeneacetic acid, 2-hydroxy-)

(RN-CAS Registry Number 614-75-5)

C6H4(OH)OOCCH3 ch3co

(Benzeneacetic acid, 4-hydroxy-)

(RN-CAS Registry Number 156-38-7)

C6H4(N02)0H no

(Phenol, 4-nitro-)

(RN-CAS Registry Number 100-02-7)

1 l.lOdbO.l El 3446

12.54±0.02 El 3631

13.83±0.02 El 3631

9.90±0.1 El 3447

c6H6o2+

c6H6o2+

c6h6o2+

c6h6o2 ( 1 ,4-Benzenediol)

(RN-CAS Registry Number 123-31-9)

C4H3 OCOCH3 ** (Ethanone, l-(2-furanyl)-)

(RN-CAS Registry Number 1192-62-7)

C6H4(OH)OOCCH3 ch2 =c=o

(Benzeneacetic acid, 2-hydroxy-)

(RN-CAS Registry Number 614-75-5)

C6H4(OH)OOCCH3 ch2 =c=o

(Benzeneacetic acid, 4-hydroxy-)

(RN-CAS Registry Number 156-38-7)

7.95±0.03 PI

9.27±0.05 El

9.30±0.02 El

9.28±0.02 El

3523

3482

3631

3631

C6H802+ C6H8( =0)2 ** 9.52±0.05 PE 3848

( 1 ,3-Cyclohexanedione)

(RN-CAS Registry Number 504-02-9)

C6H802+ C6H8(=0)2 ** 9.65 (V) PE 3936

( 1 ,4-Cyclohexanedione)

(RN-CAS Registry Number 637-88-7)

C6H802+ C5H5( = 0)2CH3 ** 9.40±0.1 (V) PE 3848

( 1 ,3-Cyclopentanedione, 2-methyl-)

(RN-CAS Registry Number 765-69-5)

136
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c6h,o2+ C5H4(=0)(0H)CH3 (2-Cyclopenten- 1 -one, 3-hydroxy-2-methy1-) (RN-CAS Registry Number 5870-63-3)

8.84±0.05 PE 3848

c6h10o2+ tams-CH3 CH=CHCOOC2H5 * * (RN-CAS Registry Number 623-70-1)

10.11 (V) PE 3937

C6Hn02+

c6huo2+

c6huo2+

c6hho2+

C4H602(CH3)2 H 9.693 ±0.005 El

(1,3-Dioxane, 4,6-dimethyl-, cis-)

(RN-CAS Registry Number 3390-18-9)

C4H602(CH3)2 H 9.540±0.003 El

(1,3-Dioxane, 4,6-dimethyl-, trans-)

(RN-CAS Registry Number 1121-87-5)

C4H502(CH3)3 CH3 9.593 ±0.006 El

(1,3-Dioxane, 2,4,6-trimethyl-, (2a,4a,6a)-)

(RN-CAS Registry Number 19145-91-6)

(ON-Other name: cis-2-r-4—cis-6-Trimethy1- 1 , 3-dioxan)

C4H502(CH3)3 CH3 9.448 ±0.002 El

(1,3-Dioxane, 2,4,6-trimethyl-, (2a,4a,6)8)-)

(RN-CAS Registry Number 36402-73-0)

(ON-Other name: cis-2-r-4-trans-6-Trimethyl- 1 , 3-dioxan)

3481

3481

3481

3481

c6h12o2+ CH3 COO(CH2)3CH3 ** 10.17 PE 3718

(RN-CAS Registry Number 123-86-4)

c6h12o2+te/?-C4H9COOCH3 ** 9.90±0.04 PE 3851

(RN-CAS Registry Number 598-98-1)

C7H5 02+ C6H4(OH)COOH oh

(Benzoic acid, 3-hydroxy-)

(RN-CAS Registry Number 99-06-9)

C^HjO^ C6H4(OH)COOH OH

(Benzoic acid, 4-hydroxy-)

(RN-CAS Registry Number 99-96-7)

C7H502+ C6H4(COOH)2 COOH

(1,3-Benzenedicarboxyhc acid)

(RN-CAS Registry Number 121-91-5)

(MT-Metastable transition(s) observed)

C7H502+ C6H4(COOH)2 COOH

(1,4-Benzenedicarboxylic acid)

(RN-CAS Registry Number 100-21-0)

(MT-Metastable transition(s) observed)

12.51 ±0.2 El 3973

12.00±0.2 El 3973

12.42 ±0.2 El 3973

12.56±0.2 El 3973

C,H60? C6H5 COOH ** 9.75 ±0.2 El 3973

(Benzoic acid)

(RN-CAS Registry Number 65-85-0)

C7H602+ C6H5COOH ** 9.75 El 3792

(Benzoic acid)

(RN-CAS Registry Number 65-85-0)

C7H602+ C7H602 ** 9.78 ±0.02 PI 3523

(2,5-Cyclohexadiene-l,4-dione, 2-methyl-)

(RN-CAS Registry Number 553-97-9)

137
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c7h7 o2+ C6H4(OCH3)2 ch3 (Benzene, 1,3-dimethoxy-)

(RN-CAS Registry Number 151-10-0)

c7 h7o2+ C6H4(OCH3)2 ch3 (Benzene, 1,4-dimethoxy-)

(RN-CAS Registry Number 150-78-7)

c7 h7o2+ C6H4(N02)0CH3 no

(Benzene, l-methoxy-3-nitro-)

(RN-CAS Registry Number 555-03-3)

C7H702+ C6H4(N02)0CH3 no

(Benzene, l-methoxy-4—nitro-)

(RN-CAS Registry Number 100-17-4)

11.17+0.1 El 3446

10.98 ±0.1 El 3446

9.39±0.1 El 3447

10.03 ±0.1 El 3447

C7 H8 02+ C6H4(OH)OCH3 ** 7.50 (Phenol, 4-methoxy-)

(RN-CAS Registry Number 150-76-5)

C7H8 02+ C6H4(OH)OCH3 ** 8.02±0.1

(Phenol, 4-methoxy-)

(RN-CAS Registry Number 150-76-5)

C7H802+ C6H4(OCH3)OOCCH3 CH2 =C= 0 9.56±0.2

(Phenol, 3-methoxy-, acetate)

(RN-CAS Registry Number 5451-83-2)

C7H8 02+ C6H4(OCH3 )OOCCH3 CH2 =C=0 9.48 ±0.2

(Phenol, 4-methoxy-, acetate)

(RN-CAS Registry Number 1200-06-2)

QH.oO^ c6h7(=o)2 ch3 ( 1 ,3-Cyclohexanedione, 2-methyl-)

(RN-CAS Registry Number 1193-55-1)

9.37±0.05 PE 3848

C5 H4(=0)2 (CH3)2 ( 1 ,3-Cyclopentanedione, 2,2-dimethyl-)

(RN-CAS Registry Number 3883-58-7)

9.08±0.05 PE 3848

C7H10O2

' c5 h5 (=o)2c2h5 ( 1

, 3-Cyclopentanedione, 2-ethyl-)

(RN-CAS Registry Number 823-36-9)

9.35 ±0. 1 (V) PE 3848

c7h10o2+ C5 H4

( =0)(0H)C2H5 (2-Cyclopenten- 1 -one, 2-ethyl-3-hydroxy-)

(RN-CAS Registry Number 5857-25-0)

8.79±0.05 PE 3848

El 3845

El 3446

El 3484

El 3484

QHjjO^ C4H402(CH3)4 CH3 9.332±0.006 El 3481

(1,3-Dioxane, 2,2,4,6-tetramethyl-, cis-)

(RN-CAS Registry Number 17227-17-7)

C7H1302+ C4H402(CH3)4 CH3 9. 128 ±0.008 El 3481

(1,3-Dioxane, 2,2,4,6-tetramethyl-, trans-)

(RN-CAS Registry Number 20268-00-2)

C8 H702+ C6H4(OCH3)COOH OH 12.51 ±0.2 El 3973

(Benzoic acid, 3-methoxy-)

(RN-CAS Registry Number 586-38-9)

138
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8 h7o2+ C6H4(OCH3)COOH OH

(Benzoic acid, 4-methoxy-)

(RN-CAS Registry Number 100-09-4)

12.53±0.2 El 3973

c8 h8 o2+ C6H5 OOCCH3 ** (Acetic acid, phenyl ester)

(RN-CAS Registry Number 122-79-2)

8.75±0.03 El 3483

c8 h8o^ C6H5 OOCCH3 ** (Acetic acid, phenyl ester)

(RN-CAS Registry Number 122-79-2)

8.84±0.2 El 3484

c8h8 o2+ C6H4(CH3 )COOH ** (Benzoic acid, 3-methyl-)

(RN-CAS Registry Number 99-04-7)

9.43±0.2 El 3973

c8 h8 o2+ C6H4(CH3)COOH ** (Benzoic acid, 4-methyl-)

(RN-CAS Registry Number 99-94-5)

9.23±0.2 El 3973

c8h8 o2+ C6H5 COOCH3 ** (Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

9.40±0.025 PE 3626

c8 h8 o2+ C6H5 COOCH3 ** (Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

9.35±0.03 EDD 3626

c8h8 o2+ C6H5 COOCH3 ** (Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

9.35±0.1 El 3788

c8h8o2+ C6H5 COOCH3 ** (Benzoic acid methyl ester)

(RN-CAS Registry Number 93-58-3)

9.49 El 3792

c8 h8o2+ C6H5 COOCH3 Cr(CO)3 9.31 ±0.1

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5, 6-i7)-methylbenzoate]-)

(RN-CAS Registry Number 12125-87-0)

El 3788

c8h10o2+ C6H4(OCH3)2 (Benzene, 1,3-dimethoxy-)

(RN-CAS Registry Number 151-10-0)

8.17+0.1 El 3446

c8h10o2+ C6H4(OCH3)2 (Benzene, 1,4-dimethoxy-)

(RN-CAS Registry Number 150-78-7)

7.90 (V) PE 3781

c8 h10o2+ C6H4(OCH3)2 (Benzene, 1,4-dimethoxy-)

(RN-CAS Registry Number 150-78-7)

7.45 El 3845

c8 h10o2+ C6H4(OCH3 )2 (Benzene, 1,4-dimethoxy-)

(RN-CAS Registry Number 150-78-7)

7.88+0.1 El 3446

c8 h12o2+ C4(=0)2(CH3)4

( 1 , 3-Cyclobutanedione, 2,2,4,4-tetramethyl-)

(RN-CAS Registry Number 933-52-8)

8.80 (V) PE 3936

c8 h12o2+ C6H6( = 0)2(CH3)2

( 1 ,3-Cyclohexanedione, 5,5-dimethyl-)

(RN-CAS Registry Number 126-81-8)

9.28±0.05 PE 3848

139
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8h12o2+ C6H7( = 0)0C2 H5 (2-Cyclohexen-l-one, 3-ethoxy-)

(RN-CAS Registry Number 5323-87-5)

8.69±0.05 PE 3848

c9h10o2+ C6H4(CH3 )OOCCH3 *

(Acetic acid, 2-methylphenyl ester)

(RN-CAS Registry Number 533-18-6)

8.38±0.02 El 3631

c9h10o2+ C6H4(CH3 )OOCCH3 ** (Acetic acid, 3-methylphenyl ester)

(RN-CAS Registry Number 122-46-3)

8.98±0.2 El 3484

C<,H 10O2+ C6H4(CH3)OOCCH3 ** (Acetic acid, 4-methylphenyl ester)

(RN-CAS Registry Number 140-39-6)

7.84±0.02 El 3631

C9H10O2+ C6H4(CH3 )OOCCH3 ** (Acetic acid, 4-methylphenyl ester)

(RN-CAS Registry Number 140-39-6)

8.61 ±0.2 El 3484

CoHhO} C6H7( =0)2 CH(CH3)2

( 1 ,3-Cyclohexanedione, 2-( 1-methylethyl)-)

(RN-CAS Registry Number 3401-01-2)

9.09 ±0.05 PE 3848

c9h14o2+ C6H5( =0)2(CH3)3 (1,3-Cyclohexanedione, 2,5,5-trimethyl-)

(RN-CAS Registry Number 1125-11-7)

9.10±0.05 PE 3848

c10h6o2+ c10h6o2

( 1 ,4-Naphthalenedione)

(RN-CAS Registry Number 130-15-4)

9.56±0.01 PI 3523

CioH 120^ C10H12O2 ** 9.16±0.03

(2,5-Cyclohexadiene-l,4-dione, 2,3,5,6-tetramethyl-)

(RN-CAS Registry Number 527-17-3)

PI 3523

c10h12o2+ c10h12o2 (Tricyclo[3.3. 1 . l

3,7 ]decane-2,6-dione)

(RN-CAS Registry Number 39751-07-0)

(ON-Other name: 2,6-Adamantanedione)

9.06 PE 3886

C10H14O2+ C7H5(=0)2(CH3)3 (Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-)

(RN-CAS Registry Number 465-29-2)

8.80 (V) PE 3936

c10h14o2+ C8 HuOOCCH3 ** (TricycloP^.l.O^octan-S-ol, acetate, endo-syn-)

(RN-CAS Registry Number 32426-26-9)

8.6±0.1 El 3492

C10Hi4O2+ C8 H,,OOCCH3 **

(Tricyclo[3.2.1.02,4]octan-8-ol, acetate, endo-anti-)

(RN-CAS Registry Number 32350-51-9)

9.0±0.1 El 3492

CioH 140^ C8H,,OOCCH3 ** (TricyclofS^.l^^Joctan-S-ol, acetate, exo-syn-)

(RN-CAS Registry Number 32350-52-0)

8.9±0.1 El 3492

c10h14o2+ C8 Hn OOCCH3 ** (TricycloP^.l.O^Joctan-S-ol, acetate, exo-anti-)

(RN-CAS Registry Number 32350-50-8)

9.3±0.1 El 3492

140
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CioH140^ C8H8 (OCH3)2 ** 8.6±0.1 El 3492

(Tricyclo[3.2.1.02,4]oct-6-ene, 8,8-dimethoxy-, (la,2a,4a, 5a)-)

(RN-CAS Registry Number 14224-84-1)

(ON-Other name: Tricyclo[3.2.1.02,4]oct-6-ene, 8,8-dimethoxy-, endo-)

CioH160^

QqH160^

C6H7( = 0)2C(CH3)3 ( 1

, 3-Cyclohexanedione, 2-( 1 , 1 -dimethylethyl)-)

(RN-CAS Registry Number XXXXX-XX-X)

C6H4

( =0)2(CH3)4

( 1

, 3-Cyclohexanedione, 2,2,5 , 5-tetramethyl-)

(RN-CAS Registry Number 702-50-1)

9.05±0.1

9.04±0.05

PE

PE

3848

3848

CioH160^

QoH160^

C8H10(OCH3)2 ** 8.7 ±0.1

(Tricyclo[3.2.1.02,4]octane, 8,8-dimethoxy-, (la, 2a,4a, 5a)-)

(RN-CAS Registry Number 14224-85-2)

(ON-Other name: Tricyclo[3.2.1.02’ 4]octane, 8,8-dimethoxy-, endo-)

C8H10(OCH3)2 ** 8.9±0.1

(Tricyclo[3.2.1.02,4]octane, 8,8-dimethoxy-, (la, 2/3, 4/3, 5a)-)

(RN-CAS Registry Number 7076-82-6)

(ON-Other name: Tricyclo[3.2.1.02’ 4]octane, 8,8-dimethoxy-, exo-)

El

El

3492

3492

CnH1602+ c10h15 cooh ** (Tricyclo[3 .3.1.1

3 ' 7]decane- 1 -carboxylic acid)

(RN-CAS Registry Number 828-51-3)

(ON-Other name: 1-Adamantanecarboxylic acid)

9.34 PE 3886

CnH20O^ (CH3)3 CCOCH2 COC(CH3)3 ** (RN-CAS Registry Number 1118-71-4)

8.86±0.07 (V) PE 3682

Ci2H18 02+ C10H15 COOCH3 ** 9.38±0.03

(Tricyclo[3.3.1.1 3,7]decane-l -carboxylic acid methyl ester)

(RN-CAS Registry Number 711-01-3)

(ON-Other name: 1-Carbomethoxyadamantane)

PE 3851

c14h8o+ c14h8o2 (9//-Xanthen-9-one)

(RN-CAS Registry Number 90-47-1)

8.42±0.03 PI 3523

c13 h10o2+ C6H5 COOC6H5 ** (Benzoic acid phenyl ester)

(RN-CAS Registry Number 93-99-2)

9.0 El 3897

c14h8o2+ Ci4H8 02 **

( 1 ,4-Anthracenedione)

(RN-CAS Registry Number 635-12-1)

8.45±0.02 PI 3523

c14h8o2+

Ci4H802 **

(9, 10-Anthracenedione)

(RN-CAS Registry Number 84-65-1)

9.25±0.03 PI 3523

c14h8 o2+ Ci4Hg02 ** 9.3 PI 3586

(9, 10-Anthracenedione)

(RN-CAS Registry Number 84-65-1)

141
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c14 h8 o2+ c14 h8o2 (9, 10-Anthracenedione)

(RN-CAS Registry Number 84-65-1)

(ON-Other name: Anthraquinone)

9.40±0.08 El 3571

c14 h8 o2+ c14h8 o2 (9, 10-Phenanthrenedione)

(RN-CAS Registry Number 84-11-7)

8.64±0.03 PI 3523

c14h10o2+ C6H5 COCOC6H5 ** (Ethanedione, diphenyl-)

(RN-CAS Registry Number 134-81-6)

8.86±0.15 SD 3823

c15 h12o2+ C6H5 COCOC6H4CH3 ** (Ethanedione, (4-methylphenyl)phenyl-)

(RN-CAS Registry Number 2431-00-7)

9.05±0.10 SD 3823

c20h22o2+

C20H22O2 ** 7.56±0.07

(Z)-Homoestra-l,3,5(10),6,8-pentaen-17a-one, 3-methoxy-)

(RN-CAS Registry Number 1232-90-2)

C20H22O2 ** 7. 82 ±0.07

(Z)-Homoestra-l,3,5(10),6,8-pentaen-17a-one, 3-methoxy-, (14/3)-)

(RN-CAS Registry Number 1232-91-3)

El

El

3571

3571

^20^26^2

^20^260^

^-20^26^2

** (Z>-Homoestra- 1 ,3, 5( 1 0)-trien- 1 7a-one,

(RN-CAS Registry Number 1232-89-9)

^20^26^2 ** (£)-Homoestra- 1

, 3 , 5( 1 0)-trien- 1 7a-one, (RN-CAS Registry Number 1232-88-8)

8.22±0.06

3-methoxy-)

8.17±0.08

3-methoxy-, (8a)-)

El

El

3571

3571

c22h12o2+ c22H12o2 (6, 1 3-Pentacenedione)

(RN-CAS Registry Number 3029-32-1)

8.07±0.05 PI 3523

c3 h2o3+ c3 h2o2 (=o)

( 1

, 3-Dioxol-2-one)

(RN-CAS Registry Number 872-36-6)

11.91 (V) PE 3826

c3 h4o3+ C3 H402(=0)

(l,3-Dioxolan-2-one)

(RN-CAS Registry Number 96-49-1)

11.47 (V) PE 3826

c3 h6o3+ c3 h6o3 (1,3,5-Trioxane)

(RN-CAS Registry Number 110-88-3)

-10.8 (V) PE 3733

c4h2o3+ c4h2o( =0)2 (2,5-Furandione)

(RN-CAS Registry Number 108-31-6)

11.45 (V) PE 3826

142
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

C6H603+ C4H3OCOOCH3 ** 9.32+0.05 El 3482

(2-Furancarboxylic acid, methyl ester)

(RN-CAS Registry Number 611-13-2)

C7H603+ C6H4(OH)COOH ** 9.20±0.2 El 3973

(Benzoic acid, 3-hydroxy-)

(RN-CAS Registry Number 99-06-9)

C7H603+ C6H4(OH)COOH ** 9.22 ±0.2 El 3973

(Benzoic acid, 4-hydroxy-)

(RN-CAS Registry Number 99-96-7)

C7H603+ C6H4(COOH)OOCCH3 CH2 =C=0 10.08±0.2 El 3484

(Benzoic acid, 4-(acetyloxy)-)

(RN-CAS Registry Number 2345-34-8)

C8 H503+ C6H4(COOH)2 OH 12.17+0.2 El 3973

( 1

, 3-Benzenedicarboxylic acid)

(RN-CAS Registry Number 121-91-5)

C8H503+ C6H4(COOH)2 OH 12.14±0.2 El 3973

(1,4-Benzenedicarboxylic acid)

(RN-CAS Registry Number 100-21-0)

C8H803+ C6H4(OH)OOCCH3 ** (Benzeneacetic acid, 2-hydroxy-)

(RN-CAS Registry Number 614-75-5)

C8H803+ C6H4(OH)OOCCH3 ** (Benzeneacetic acid, 4-hydroxy-)

(RN-CAS Registry Number 156-38-7)

c8h8o3+ C6H4(OCH3)COOH ** (Benzoic acid, 3-methoxy-)

(RN-CAS Registry Number 586-38-9)

C8H803+ C6H4(OCH3)COOH ** (Benzoic acid, 4-methoxy-)

(RN-CAS Registry Number 100-09-4)

8.16±0.02 El 3631

8.12±0.02 El 3631

9.06±0.2 El 3973

9.04±0.2 El 3973

C9H703+ C6H4(COOCH3)COSC6H4CH3 10.98+0.2 El 4062

(Benzoic acid, 2-[[(4-methylphenyl)thio]carbonyl]- methyl ester)

(RN-CAS-Registry Number 42797-32-0)

(OP-The other product(s) is(are): C6H4(S)CH3) C9H703+ C8H40( =0)(0CH3)SC6H4CH3 10.7+0.2 El 4062

( 1 (3//)-Isobenzofuranone, 3-methoxy-3-[(4-methylphenyl)thio]-)

(RN-CAS-Registry Number 51053-89-5)

(OP-The other product(s) is(are): C6H4(S)CH3) c9H10o3+ C6H4(OCH3)OOCCH3 ** (Phenol, 3-methoxy-, acetate)

(RN-CAS Registry Number 5451-83-2)

8.29+0.2 El 3484

c9h10o3+ C6H4(OCH3)OOCCH3 ** (Phenol, 4-methoxy-, acetate)

(RN-CAS Registry Number 1200-06-2)

7.92+0.2 El 3484

143
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C10H6O3+ C10H5 O2 (OH)

( 1 ,4-Naphthalenedione, 5-hydroxy-)

(RN-CAS Registry Number 481-39-0)

8.70±0.02 PI 3523

c14 h8o3+ c14H7o2 (OH)

(9,10-Anthracenedione, 1-hydroxy-)

(RN-CAS Registry Number 129-43-1)

8.43±0.05 PI 3523

cI4 h8 o3+ c14 H7o2 (OH)

(9, 10-Anthracenedione, 2-hydroxy-)

(RN-CAS Registry Number 605-32-3)

8.70±0.03 PI 3523

c14 h12 o3+ C6H5 COOC6H4OCH3 ** (Phenol, 4-methoxy-, benzoate)

(RN-CAS Registry Number 1523-19-9)

8.6 El 3897

c2 h4o4+ (HCOOH)2 ** (RN-CAS Registry Number 14523-98-9)11.3 (V) PE 3734

c4 h8o4+ (CH3 COOH)2 ** (RN-CAS Registry Number 6993-75-5)10.6 (V) PE 3734

c5 h10o4+

(Z50-C3 H7 COOH)(HCOOH) ** (RN-CAS Registry Number XXXXX-XX-X)

10.5 (V) PE 3734

c6h6o4+ CH3 OOCC=CCOOCH3 ** (RN-CAS Registry Number 762-42-5)10.9 (V) PE 3937

c6 h8 o4+c/5-CH3 OOCCH = CHCOOCH3 ** (RN-CAS Registry Number 624-48-6)

10.47 (V) PE 3937

c6 h8o4+ rra«s-CH3 OOCCH=CHCOOCH3* * (RN-CAS Registry Number 624-49-7)

10.70 (V) PE 3937

c6 h12o+ (CH3 CH2 COOH)2 ** (RN-CAS Registry Number XXXXX-XX-X)

10.4 (V) PE 3734

c8 h6o4+ C6H4(COOH)2 ** (1,3-Benzenedicarboxylic acid)

(RN-CAS Registry Number 121-91-5)

9.98±0.2 El 3973

c8 h6o4+ C6H4(COOH)2 ** (1,4-Benzenedicarboxylic acid)

(RN-CAS Registry Number 100-21-0)

9.86±0.2 El 3973

c9 h8o4+ C6H4(COOH)OOCCH3 ** (Benzoic acid, 4-(acetyloxy)-)

(RN-CAS Registry Number 2345-34-8)

9. 11 ±0.2 El 3484

C10H6O4+ C10H4O2(OH)2 ( 1 ,4-Naphthalenedione, 5,8-dihydroxy-)

(RN-CAS Registry Number 475-38-7)

8.20±0.02 PI 3523

144
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

'14n8w4

c14h8o4+

c14h8o4+

c14h6o2(oh)2 (9, 1 0-Anthracenedione, 1 ,4-dihydroxy-)

(RN-CAS Registry Number 81-64-1)

C14H602(0H)2 (9, 1 0-Anthracenedione, 1,5 -dihydroxy-)

(RN-CAS Registry Number 117-12-4)

c14H6o2(OH)2 (9,1 0-Anthracenedione, 2,6-dihydroxy-)

(RN-CAS Registry Number 84-60-6)

7.94+0.03 PI

8.53+0.03 PI

8.65±0.05 PI

CH3 BO+

(

2E)

CH3BO+

(

2A!)

CH3 BO+

(

2E)

CH3 BO+

(

2A!)

(BH3KCO)

(RN-CAS Registry Number 13205-44-2)

(BH3)(CO)

(RN-CAS Registry Number 13205 - 44-2)

(BH3)(CO)

(RN-CAS Registry Number 13205 -44 - 2)

(BH3)(CO)

(RN-CAS Registry Number 13205-44 2)

NO+

(

3 n) NO ** (RN-CAS Registry Number 10102-43-9)

(RS-Average of two Rydberg series limits)

NO+(X! 2

+

) NO ** (RN-CAS Registry Number 10102-43-9)

NO+(X1 2

+

) NO ** (RN-CAS-Registry Number 10102-43-9)

NO+

(a

3 2

+

) NO ** (RN-CAS Registry Number 10102-43-9)

145

21.721+0.006

9.27

3523

3523

3523

C22H10O4+ C22H10O4 (5,7, 12, 14-Pentacenetetrone)

(RN-CAS Registry Number 23912-79-0)

9.22+0.05 PI 3523

c14H8o6+ c14H4o2(OH)4 (Anthraquinone, 1 ,4, 5, 8-tetrahydroxy-)

(RN-CAS Registry Number 81-60-7)

7.83+0.02 PI 3523

QoHi404Be+ (CH3COCHCOCH3)2Be ** (Beryllium, bis(2,4-pentanedionato-0,0')-, (T-4)-)

(RN-CAS Registry Number 10210-64-7)

8.41+0.07 (V) PE 3682

12.51+0.02 (V) PE 3699

13.73+0.01 PE 3699

16.09+0.02 PE 3699

18.48+0.02 PE 3699

ch3 bo+ (BH3xco)

(RN-CAS Registry Number 13205-44-2)

11.14+0.02 PE 3699

C3H9BO+ (CH3)2BOCH3 ** (RN-CAS-Registry Number 7318-81-2)

10.32 (V) PE 4065

c3 h9bo2+ (CH30)2BCH3 ** (RN-CAS-Registry Number 7318-81-2)

10.40 (V) PE 4065

C^BO^ B(OCH3)3 (RN-CAS-Registry Number 121-43-7)

10.40 (V) PE 4065

S 3761

PE 3516

PE 4073

PE 3516
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other appearance Method Ref.

products potential

(eV)

NO+

(b

3 ri) NO ** 16.562±0.003 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+ (w3 A) NO ** 16.863±0.003 PE 3516

NO+

(b'

3 2')

(RN-CAS Registry Number 10102-43-9)

NO ** 17.586±0.003 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+ (A''2) NO ** 17.8 11 ±0.003 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+ (A’n) NO ** 18.319±0.003 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+ (w'A) NO ** <18.36 PE 3516

(RN-CAS Registry Number 10102-43-9)

No+

(c

3 n) NO ** 21.722±0.010 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+ (B'n) NO ** 21.722±0.010 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+

(B''2 +

) NO ** 22.727±0.010 PE 3516

(RN-CAS Registry Number 10102-43-9)

NO+ ('2 +

) NO ** 9.27±0.05 RPD 3453

(RN-CAS Registry Number 10102-43-9)

NO+ ch3 no2 11.75±0.01 PI 3524

(RN-CAS Registry Number 75-52-5)

NO+ CH3 ONO CH30 10.917±0.008 PI 3524

(RN-CAS Registry Number 624-91-9)

(TR-Other product(s) thermochemically reasonable)

N20

+ (X2 n) N20 ** 12.90 TPE 3998

(RN-CAS Registry Number 10024-97-2)

N2 0

+ (A2 2

+

) N20 ** 16.40 TPE 3998

(RN-CAS Registry Number 10024-97-2)

no2+ no2 ** (RN-CAS Registry Number 10102-44-0)

<9.62±0.01 PI 3927

CjN2 o

+

(

2 b2 ) (CN)2 CO ** (RN-CAS Registry Number 1115-12-4)

12.56 (V) PE 3726

c3 n2o

+ * (CN)2CO ** (RN-CAS Registry Number 1115-12-4)

13.76 (V) PE 3726

c3 n2 o

+ * (CN)2 CO ** (RN-CAS Registry Number 1115-12-4)

14.41 (V) PE 3726

c3 n2o

+ * (CN)2 CO ** (RN-CAS Registry Number 1115-12-4)

14.79 (V) PE 3726

c,n2o

+

(

2b,) (CN)2CO ** (RN-CAS Registry Number 1115-12-4)

16.7 (V) PE 3726

c3 n2o

+ * (CN)2 CO ** (RN-CAS Registry Number 1115-12-4)

17.9 (V) PE 3726

c6h5 no3 C6H4(0H)N02 ** 7.38 (Phenol, 4-nitro-)

(RN-CAS Registry Number 100-02-7)

El 4089

146
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CHNO+

(

2A") HNCO ** 11.62±0.02 PE 3670

(RN-CAS Registry Number 75-13-8)

CHNO+

(

2A) HNCO ** 12. 30 ±0.02 (V) PE 3670

(RN-CAS Registry Number 75-13-8)

CHNO+ * HNCO ** 15. 8 ±0.1 (V) PE 3670

(RN-CAS Registry Number 75-13-8)

CHNO+ * HNCO ** 17.50±0.02 (V) PE 3670

(RN-CAS Registry Number 75-13-8)

CHNO+ * HNCO ** 19.24±0.02 (V) PE 3670

(RN-CAS Registry Number 75-13-8)

CH3NO+ hconh2 ** (RN-CAS Registry Number 75-12-7)

10.16±0.03 PI 3765

C2H3NO+

(

2A

w ) CH3NCO ** (RN-CAS Registry Number 624-83-9)

10.67±0.02 PE 3670

C2H5 NO+ ch3 conh2 ** (RN-CAS Registry Number 60-35-5)

9.65±0.03 PI 3765

C2H5NO+ CH3CONH2 ** (RN-CAS Registry Number 60-35-5)

9.80 PE 3718

C2H5NO+ C2H5NO ** (RN-CAS Registry Number 925-91-7)

10.1 ±0.2 El 4099

C2H7NO+ nh2ch2ch2oh ** (RN-CAS Registry Number 141-43-5)9.87±0.06 (V) PE 3987

c3h7no+ CH3 CONHCH3 ** (RN-CAS Registry Number 79-16-3)

-9.85 (V) PE 3718

C3H9NO+ CH3OCH2CH2NH2 ** (RN-CAS Registry Number 109-85-3)

9.45 ±0.09 (V) PE 3987

c3h9no+ NH2(CH2)3OH ** (RN-CAS Registry Number 156-87-6)

9.77±0.20 (V) PE 3987

CH3 CON(CH3)2 ** (RN-CAS Registry Number 127-19-5)

9.43 (V) PE 3718

C4HnNO+ C4HhNO+

(CH3)2NCH2CH2OH ** (RN-CAS Registry Number 108-01-0)

CH30(CH2)3NH2 ** (RN-CAS Registry Number 5332-73-0)

8.85±0.04 (V)

9.37±0.12 (V)

PE

PE

3987

3987

c5h3no+ C4H3OCN ** (2-Furancarbonitrile)

(RN-CAS Registry Number 617-90-3)

9.77±0.05 El 3482

c5h5no+ C5H4N(OH) ** 9.28±0.02 El 3636

(2-Pyridinol)

(RN-CAS Registry Number 109-10-4)

147
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C5 H5 NO+ C5 H4N(OH) ** (3-Pyridinol)

(RN-CAS Registry Number 109-00-2)

9.55±0.02 El 3636

c5 h5 no+ C5 H4N(OH) ** (3-Pyridinol)

(RN-CAS Registry Number 109-00-2)

9.55±0.05 El 3635

c5 h5 no+ C5 H4N(OH) **

(4-Pyridinol)

(RN-CAS Registry Number 626-64-2)

9.89±0.02 El 3636

c5 h5 no+ C4H4NCHO **

( 1 -i/-Pyrrole-2-carboxaldehyde)

(RN-CAS Registry Number 1003-29-8)

8.93±0.05 El 3482

c5 h8 no+ (CH3)2NCOCH=CHCH3 ch3 (RN-CAS Registry Number 23135-18-4)

11.0±0.1 El 3996

c5 h13 no+ (CH3)2N(CH2)3OH ** (RN-CAS Registry Number 3179-63-3)

8.74±0.04 (V) PE 3987

c6h5 no+ C6H5 NO ** (Benzene, nitroso-)

(RN-CAS Registry Number 586-96-9)

8.09 PE 3938

C6H6 NO+ C6H4(NH2)OCH3 ch3 (Benzenamine, 3-methoxy-)

(RN-CAS Registry Number 536-90-3)

C6H6NO+ C6H4(NH2)OCH3 ch3 (Benzenamine, 4-methoxy-)

(RN-CAS Registry Number 104-94-9)

C6H6NO+ C6H4(OH)NHCOCH3 ch3co

(Acetamide, iV-(2-hydroxyphenyl)-)

(RN-CAS Registry Number 614-80-2)

C6H6NO+ C6H4(OH)NHCOCH3 ch3co

(Acetamide, A-(4-hydroxyphenyl)-)

(RN-CAS Registry Number 103-90-2)

C6H6NO+ C6H4(N02)NH2 no

(Benzenamine, 3-nitro-)

(RN-CAS Registry Number 99-09-2)

C6H6NO+ C6H4(N02)NH2 no

(Benzenamine, 4-nitro-)

(RN-CAS Registry Number 100-01-6)

11.07±0.1 El 3446

10.43 ±0.1 El 3446

13.46±0.02 El 3631

13.52±0.02 El 3631

9. 12 ±0.1 El 3447

9.56±0.1 El 3447

C6H7 NO+ C5 H4N(OCH3) ** 8.96±0.02 El 3636

(Pyridine, 2-methoxy-)

(RN-CAS Registry Number 1628-89-3)

C6H7 NO+ C5 H4N(OCH3) ** 9.34±0.02 El 3636

(Pyridine, 3-methoxy-)

(RN-CAS Registry Number 7295-76-3)

C6H7 NO+ C5 H4N(OCH3) ** 9.34±0.05 El 3635

(Pyridine, 3-methoxy-)

(RN-CAS Registry Number 7295-76-3)

148
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

C6H7NO+

c6h7no+

c6h7no+

c6h7no+

C6H7NO+

c6h7no+

c6h7no+

QH7NO+

c6h7no+

C5 H4N(OCH3) **

(Pyridine, 4-methoxy-)

(RN-CAS Registry Number 620-08-6)

C5 H4N(=0)CH3 (2( l/O-Pyridinone, 1 -methyl-)

(RN-CAS Registry Number 694-85-9)

C5 H4N(=0)CH3 (4( l//)-Pyridinone, 1 -methyl-)

(RN-CAS Registry Number 695-19-2)

C4H4NCOCH3 ** (Ethanone, 1 -( 1 //-pyrrol-2-yl)-)

(RN-CAS Registry Number 1072-83-9)

C5H4N(0)CH3 ** 7.90±0.02

(Pyridinium, 3-hydroxy- 1 -methyl-, hydroxide, inner salt) (RN-CAS Registry Number 25065-00-3)

C5H4N(0)CH3 ** 7.90+0.05

(Pyridinium, 3-hydroxy- 1 -methyl-, hydroxide, inner salt) (RN-CAS Registry Number 25065-00-3)

C5H3N(OH)CH3 ** 9.15+0.05

(3-Pyridinol, 6-methyl-)

(RN-CAS Registry Number 1121-78-4)

C6H4(OH)NHCOCH3 CH2 =C= 0 9.41+0.02

(Acetamide, 7V-(2-hydroxyphenyl)-)

(RN-CAS Registry Number 614-80-2)

C6H4(OH)NHCOCH3 CH2 =C=0 9.82+0.02

(Acetamide, A-(4-hydroxyphenyl)-)

(RN-CAS Registry Number 103-90-2)

9.58+0.02

8.58+0.02

8.48±0.02

> 8.72+0.05

El

El

El

El

El

El

El

El

El

3636

3636

3636

3482

3636

3635

3635

3631

3631

QHnNO* (CH3)2NCOCH=CHCH3 ** (RN-CAS Registry Number 23135-18-4)

9.0+0.

1

El 3996

C6H15NO+ (C2H5)2NCH2CH2OH ** (RN-CAS Registry Number 100-37-8)8.58+0.03 (V) PE 3987

C7H4NO+ C6H4(CN)OCH3 ch3 (Benzonitrile, 3-methoxy-)

(RN-CAS Registry Number 1527-89-5)

C7H4NO+ C6H4(CN)OCH3 ch3 (Benzonitrile, 4-methoxy-)

(RN-CAS Registry Number 874-90-8)

C7H4NCT C6H4(NOz)CN no

(Benzonitrile, 3-nitro-)

(RN-CAS Registry Number 619-24-9)

C7H4NO+ C6H4(N02)CN no

(Benzonitrile, 4—nitro-)

(RN-CAS Registry Number 619-72-7)

12.75+0.1 El 3446

12.65+0.1 El 3446

10.45±0.1 El 3447

10.80+0.1 El 3447

C7H6NO+ C6H4(NH2)COOH OH 12. 18 ±0.2 El 3973

(Benzoic acid, 3-amino-)

(RN-CAS Registry Number 99-05-8)

149
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C7 H6 NO+ C6H4(NH2)COOH OH 12.12±0.2 El 3973

(Benzoic acid, 4-amino-)

(RN-CAS Registry Number 150-13-0)

c7 h7 no+ C6H5 CONH2 *# 9.60 El 3792

(Benzamide)

(RN-CAS Registry Number 55-21-0)

C7 H9NO+

c7 h9 no+

c7 h9no+

C7H9 NO+

C6H4(NH2)OCH3 ** (Benzenamine, 3-methoxy-)

(RN-CAS Registry Number 536-90-3)

C6H4(NH2)OCH3 ** (Benzenamine, 4-methoxy-)

(RN-CAS Registry Number 104-94-9)

C6H4(NH2)OCH3 ** (Benzenamine, 4-methoxy-)

(RN-CAS Registry Number 104-94-9)

C6H4(NH2)OCH3 (Benzenamine, 4-methoxy-)

(RN-CAS Registry Number 104-94-9)

7.76±0.1 El 3446

6.92 El 3845

7.60±0.1 El 3446

9.39 El 4089

c7 h10no+ c4h8 ncoch=chch3 ch3 (Pyrrolidine, 1 -( 1 -oxo-2-butenyl)-)

(RN-CAS Registry Number 51944-65-1)

11.2±0.1 El 3996

CyHjjNO^ C5 H8 NCOCH3 **

(Pyridine, 1 -acetyl- 1 ,2,3,4-tetrahydro-)

(RN-CAS Registry Number 19615-27-1)

8.8 El 4046

C7 H13NO+ C5 H10NCOCH3 **

(Piperidine, 1 -acetyl-)

(RN-CAS Registry Number 618-42-8)

9.1 El 4046

c7h17 no+ (C2 H5)2N(CH2)3OH ** (RN-CAS Registry Number 622-93-5)

8.56±0.05 (V) PE 3987

c8 h4no+ C6H4(CN)COOH oh

(Benzoic acid, 4-cyano-)

(RN-CAS Registry Number 619-65-8)

12.68±0.2 El 3973

C8 H7 NO+ C6H4(CN)OCH3 **

(Benzonitrile, 3-methoxy-)

(RN-CAS Registry Number 1527-89-5)

9. 11 ±0.1 El 3446

c8 h7 no+ C6H4(CN)OCH3 **

(Benzonitrile, 4-methoxy-)

(RN-CAS Registry Number 874-90-8)

8.74 El 3845

c8 h7 no+ C6H4(CN)OCH3 **

(Benzonitrile, 4-methoxy-)

(RN-CAS Registry Number 874-90-8)

8.97±0.1 El 3446

150
Table of Ion Energetics Measurements

Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C8H8NO+ c6h4cinhcoch3 (Acetamide, A-(2-chlorophenyl)-)

(RN-CAS Registry Number 533-17-5)

8.86±0.03 El 3483

c8h8no+ C6H4BrNHCOCH3 (Acetamide, 7V-(2-bromophenyl)-)

(RN-CAS Registry Number 614-76-6)

9.08±0.03 El 3483

c8h8no+ C6H4INHCOCH3 (Acetamide, 7V-(2-iodophenyl)-)

(RN-CAS Registry Number 19591-17-4)

8.57±0.03 El 3483

c8h9no+ QHjNHCOCHj ** (Acetamide, 7V-phenyl-)

(RN-CAS Registry Number 103-84-4)

8.18±0.03 El 3483

c8h12no+ C5H10NCOCH=CHCH3 **

(Piperidine, l-(l-oxo-2-butenyl)-)

(RN-CAS Registry Number 3626-69-5)

11.1+0.1 El 3996

CsH,3 NO+ C4H8NCOCH=CHCH3 **

(Pyrrolidine, l-(l-oxo-2-butenyl)-)

(RN-CAS Registry Number 51944-65-1)

9.0±0.1 El 3996

c8h18no+

(RD-Radical)

(terr-C4H9)2NO ** (RN-CAS Registry Number 2406-25-9)

6.77 PE 3712

C9H8NO+ c6h5nhcoch=chch3 ch3 (2-Butenamide, 7V-phenyl-)

(RN-CAS Registry Number 1733-40-0)

12.1+0.3 El 3996

C9HhNO+ C6H4(CH3)NHCOCH3 ** (Acetamide, A-(2-methylphenyl)-)

(RN-CAS Registry Number 120-66-1)

8.03+0.02 El 3631

C9HuNO+ C6H4(CH3)NHCOCH3 ** (Acetamide, 7V-(4-methylphenyl)-)

(RN-CAS Registry Number 103-89-9)

7.75 ±0.02 El 3631

C9HnNO+ C6H4(CHO)N(CH3)2 ** (Benzaldehyde, 4-(dimethylamino)-)

(RN-CAS Registry Number 100-10-7)

7.36±0.02 PI 4028

C9H13NO+ C6H4(OCH3)N(CH3)2 (Benzenamine, 2-methoxy-A,7V-dimethyl-)

(RN-CAS Registry Number 700-75-4)

7.59±0.02 El 3630

C9H13NO+ C6H4(0)N(CH3)3 ** —6.8

(Benzenaminium, 2-hydroxy-A,Ar,A-trimethyl-, hydroxide, inner salt) (RN-CAS Registry Number 31061-58-2)

El 3630

C9H13NO+ C5H8NCOCH=CHCH3 **

(Pyridine, 1 ,2,3,4-tetrahydro- 1 -( 1 -oxo-2-butenyl)

(RN-CAS Registry Number 50838-23-8)

8.6 (E))El 4046

151
Table of Ion Energetics Measurements-—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C9H15 NO+ C5 H10NCOCH= CHCH3 (Piperidine, l-(l-oxo-2-butenyl)-, (E))

(RN-CAS Registry Number 50838-22-7)

8.9 El 4046

c9h15 no+ c5 h10ncoch=chch3 ch3 (Piperidine, 1 -( 1 -oxo-2-butenyl)-)

(RN-CAS Registry Number 3626-69-5)

8.9±0.1 El 3996

c9h17 no+ C5 H5 N(=0)(CH3)4 (4-Piperidinone, 2,2,6,6-tetramethyl-)

(RN-CAS Registry Number 826-36-8)

8.30±0.05 El 3494

c9h18 no+

(RD-Radical)

c5 H6N(CH3)4o

( 1 -Piperidinyloxy, 2,2,6,6-tetramethyl-)

(RN-CAS Registry Number 2564-83-2)

6.73 PE 3712

C10H10NO+ c6h5 ch2 nhcoch=chch3 ch3 (2-Butenamide, Ar-(phenylmethyl)-)

(RN-CAS Registry Number 51944-67-3)

10.7±0.1 El 3996

C10Hn NO+ C6H5 NHCOCH=CHCH3 ** (2-Butenamide, A^-phenyl-)

(RN-CAS Registry Number 1733-40-0)

8.7±0.1 El 3996

cuh13no+ C6H5 CH2NHCOCH=CHCH3 ** (2-Butenamide, Af-(phenylmethyl)-)

(RN-CAS Registry Number 51944-67-3)

8.6±0.1 El 3996

c12 h13 no+ C5 H8 NCOC6H5 **

(Pyridine, l-benzoyl-l,2,3,4-tetrahyro-)

(RN-CAS Registry Number 50838-24-9)

8.4 El 4046

cI2 h15 no+ C5 H10NCOC6H5 **

(Piperidine, 1 -benzoyl-)

(RN-CAS Registry Number 776-75-0)

8.8 El 4046

c6h4n2o

+ c6h4n2o

(Benzofurazan)

(RN-CAS Registry Number 273-09-6)

9.37 PE 4017

c8 h10n2o

+

c8 h10n2o

+

C6H4(NH2)NHCOCH3 ** (Acetamide, A-(2-aminophenyl)-)

(RN-CAS Registry Number 34801-09-7)

QH/NH^NHCOCHj ** (Acetamide, A-(4-aminophenyl)-)

(RN-CAS Registry Number 122-80-5)

7.39±0.02

7.12±0.02

El

El

3631

3631

c10h22n2 o

+ C2 H4N20(C4H9)2

( 1

, 3,4-Oxadiazolidine, 3,4-bis( 1 , 1 -dimethylethy1)-) (RN-CAS Registry Number 38786-33-3)

8.15 (V) PE 3889

152
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c17 h20n2o

+ (C6H4N(CH3)2)2CO

(Methanone, diphenyl-, bis(dimethylamino)deriv.)

(RN-CAS Registry Number 58211-66-8)

7.25±0.1 PI 4028

ch3 no2+ ch3 no2 ** (RN-CAS Registry Number 75-52-5)

11.040±0.017 PI 3524

ch3 no2 (2a1 ) ch3 no2 ** (RN-CAS Registry Number 75-52-5)

11. 07 ±0.01 PE 3721

ch3 no2+ ch3no2 ** (RN-CAS Registry Number 75-52-5)

11.31 ±0.015 (V) PE 4107

CHjN02t

2A2) ch3 no2 ** (RN-CAS Registry Number 75-52-5)

1 1.73±0.01 PE 3721

CH3 N02t

2 B2) ch3no2 ** (RN-CAS Registry Number 75-52-5)

13.85±0.01 PE 3721

CHjNOJ'B,) ch3no2 ** (RN-CAS Registry Number 75-52-5)

15.75±0.01 (V) PE 3721

CHjNOjfBj) ch3 no2 ** (RN-CAS Registry Number 75-52-5) ~ 16.7 PE 3721

CH3 N02t

2A,) ch3 no2 ** (RN-CAS Registry Number 75-52-5)

19.1 (V) PE 3721

ch3 no2+ ch3ono ** (RN-CAS Registry Number 624-91-9)

10.475+0.007 PI 3524

CD3 N02fA,) cd3 no2 ** (RN-CAS Registry Number 13031-32-8)

1 1.08±0.01 PE 3721

CD3 N02t

2A2) cd3no2 ** (RN-CAS Registry Number 13031-32-8)

1 1 .73 ±0.01 PE 3721

c2h5 no2+ c2h5no2 ** (RN-CAS Registry Number 56-40-6)9.21+0.05 El 3571

c6h4no2+ c6h4(N02)2 no2 (Benzene, 1,3-dinitro-)

(RN-CAS Registry Number 99-65-0)

12.34±0.1 El 3447

c6h4no2+ c6h4(no2)2 no2 (Benzene, 1,4-dinitro-)

(RN-CAS Registry Number 100-25-4)

12.50±0.1 El 3447

c6h5 no2+ c6h5no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.88±0.015 (V) PE 4107

c6h5no2+ c6h5 no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.94±0.025 PE 3626

C6H5N02fB,) c6h5 no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.99+0.01 PE 3721

c6h5 no2+ c6h5no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.99 PE 3856

153
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c6h5 no2+ c6h5 no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.90 EDD 3485

c6 h5 no2+ c6h5 no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.6 El 3916

c6h5 no2+ c6h5 no2 (Benzene, nitro-)

(RN-CAS Registry Number 98-95-3)

9.65±0.1 El 3447

c6h7 no2+ C4H4NCOOCH3 ** (l//-Pyrrole-2-carboxylic acid, methyl ester)

(RN-CAS Registry Number 1193-62-0)

8.65±0.05 El 3482

c7 h6 no2+ C6H4(N02)C4H9 (Benzene, l-butyl-3-nitro-)

(RN-CAS Registry Number 20651-76-7)

13.08±0.1 El 3629

c7h6no2+ C6H4(No2)c4h9 (Benzene, l-butyl-4-nitro-)

(RN-CAS Registry Number 20651-75-6)

12.54+0.1 El 3629

c7 h7 no2+ C6H4(N02)CH3 (Benzene, l-methyl-2-nitro-)

(RN-CAS Registry Number 88-72-2)

9.69±0.015 (V) PE 4107

c7h7 no2+ C6H4(N02)CH3 (Benzene, l-methyl-3-nitro-)

(RN-CAS Registry Number 99-08-1)

9.49+0.015 (V) PE 4107

c7 h7 no2+ C6H4(N02)CH3 (Benzene, l-methyl-3-nitro-)

(RN-CAS Registry Number 99-08-1)

9.48+0.1 El 3447

c7 h7 no2+ C6H4(N02)CH3 (Benzene, l-methyl-4-nitro-)

(RN-CAS Registry Number 99-99-0)

9.54+0.015 (V) PE 4107

c7 h7 no2+ C6H4(N02)CH3 (Benzene, l-methyl-4-nitro-)

(RN-CAS Registry Number 99-99-0)

9.50±0.1 El 3447

c7 h7 no2+ C6H4(N02)CH3 (Benzene, l-methyl-4-nitro-)

(RN-CAS Registry Number 99-99-0)

9.56 El 4089

c7 h7 no2+ C6H4(NH2)COOH ** (Benzoic acid, 3-amino-)

(RN-CAS Registry Number 99-05-8)

8.41+0.2 El 3973

c7 h7 no2+ C6H4(NH2)COOH ** (Benzoic acid, 4-amino-)

(RN-CAS Registry Number 150-13-0)

8.36±0.2 El 3973

c7 h7no2+ C6H4(N02)C4H9 ch2 = chch3 (Benzene, l-butyl-3-nitro-)

(RN-CAS Registry Number 20651-76-7)

11.52+0.1 El 3629

c7 h7 no2+ C6H4(N02)C4H9 ch2 = chch3 (Benzene, l-butyl-4-nitro-)

(RN-CAS Registry Number 20651-75-6)

11. 44 ±0.1 El 3629

154
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c7h10no2+ C4H8NO(COCH= CHCH3) ** (Morpholine, 4-( 1 -oxo-2-butenyl)-)

(RN-CAS Registry Number 51944-66-2)

11.1+0.1 El 3996

c8h5 no2+ C6H4(CN)COOH ** (Benzoic acid, 4-cyano-)

(RN-CAS Registry Number 619-65-8)

10.27±0.2 El 3973

c8h9no2+ C6H4(OH)NHCOCH3 ** (Acetamide, iV-(2-hydroxyphenyl)-)

(RN-CAS Registry Number 614-80-2)

7.01 ±0.02 El 3631

c8h9no2+ C6H4(OH)NHCOCH3 ** (Acetamide, A-(4-hydroxyphenyl)-)

(RN-CAS Registry Number 103-90-2)

7.57+0.02 El 3631

c8h9no2+ c6h3 (ch3)2no2 (Benzene, 1 , 3-dimethyl-2-nitro-)

(RN-CAS Registry Number 81-20-9)

9.17±0.015 PE 4107

c8h9no2+ C6H3(CH3)2N02 (Benzene, 2,4-dimethyl- 1-nitro-)

(RN-CAS Registry Number 89-87-2)

9.38±0.015 (V) PE 4107

c8h9no2+ c5 h4nch2 cooch3 ** (2-Pyridineacetic acid methyl ester)

(RN-CAS Registry Number 1658-42-0)

9.40±0.02 El 3627

c,h»no2+ c5 h4nch2cooch3 ** (3-Pyridineacetic acid methyl ester)

(RN-CAS Registry Number 39998-25-9)

9.52+0.02 El 3627

c,h,no2+ c5 h4nch2 cooch3 ** (4-Pyridineacetic acid methyl ester)

(RN-CAS Registry Number 29800-89-3)

9.62+0.02 El 3627

c,h13 no2+ C4H8NO(COCH=CHCH3) ** (Morpholine, 4-(l-oxo-2-butenyl)-)

(RN-CAS Registry Number 51944-66-2)

8.8 ±0.

1

El 3996

c9huno2+

c9huno2+

C9Hn N02+

C5H4N(CH3) = CHCOOCH3 ** 7.02±0.02 El

(Acetic acid, ( 1 -methyl-2( l//)-pyridinylidene)-, methyl ester)

(RN-CAS Registry Number 39998-21-5)

C5 H4N(CH3) =CHCOOCH3 ** 6.82±0.02 El

(Acetic acid, ( 1 -methyl-4( l//)-pyridinylidene)-, methyl ester)

(RN-CAS Registry Number 39998-22-6)

C6H5CH2CH(NH2)COOH ** <8.4 PI (DL-Phenylalanine)

(RN-CAS Registry Number 150-30-1)

3627

3627

3766

C9H13 N02+ C5H5 N(CH3)CH2COOCH3 ** 6.94±0.02 El 3627

(3-Pyridineacetic acid, 1,4-dihydro- 1 -methyl-, methyl ester)

(RN-CAS Registry Number 39998-23-7)

155
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c9h16no2+

(RD-Radical)

C5 H4N(0)( = 0)(CH3)4 (1-Piperidinyloxy, 2,2,6,6-tetramethyl-4-oxo-)

(RN-CAS Registry Number 2896-70-0)

7.40±0.05 El 3494

QHpNO^ rra^-(C2 H5)2 NCH= CHCOC2 H5 ** (RN-CAS Registry Number 13894-28-5)

7.63 (V) PE 3885

c9h17 no2+ C5 H4N( = 0)(0H)(CH3)4 (4-Piperidinone, 1 -hydroxy-2,2, 6, 6-tetramethyl-)

(RN-CAS Registry Number 3637-11-4)

8.51 ±0.05 El 3494

c10h13 no2+ C6H4(N02)C4H9 (Benzene, l-butyl-3-nitro-)

(RN-CAS Registry Number 20651-76-7)

9.94±0.1 El 3629

c10h13 no2+ C6H4(N02)C4H9 (Benzene, l-butyl-4-nitro-)

(RN-CAS Registry Number 20651-75-6)

10.07±0.1 El 3629

c13h10no2+ (C6H4N02)2CH2 no2 (Benzene, 1 , 1 '-methylenebis[4-nitro-)

(RN-CAS Registry Number 1817-74-9)

11.1 ±0.

El 3807

c13 hu no2+ c6h5 ch2 c6h4no2 ** (Benzene, 1 -nitro-4-(phenylmethyl)-)

(RN-CAS Registry Number 1817-77-2)

9.35±0.05 El 3806

c14 hI3 no2+ c6h5 ch2ch2c6h4no2 ** (Benzene, 1 -nitro-4-(2-phenylethyl-)

(RN-CAS Registry Number 14310-29-3)

9.17±0.05 El 3806

c4h4n2o2+ c4h4n2o2 **

(2,4( 17/,3i/)-Pyrimidinedione)

(RN-CAS Registry Number 66-22-8)

(ON-Other name: Uracil)

9.53±0.02 El 3571

c4h4n2 o2+ c4h4nno2 **

(Pyrrole, 2-nitro-)

(RN-CAS Registry Number 5919-26-6)

9.30±0.05 El 3482

c6h6n2 o2+ C6H4(N02)NH2 (Benzenamine, 2-nitro-)

(RN-CAS Registry Number 88-74-4)

8.43 (V) PE 3856

c6h6n2o2+ C6H4(N02)NH2 (Benzenamine, 3-nitro-)

(RN-CAS Registry Number 99-09-2)

8.60 (V) PE 3856

c6h6n2o2+ C6H4(N02)NH2 (Benzenamine, 3-nitro-)

(RN-CAS Registry Number 99-09-2)

8.73 ±0.

El 3447

c6h6n2 o2+ C6H4(N02)NH2 (Benzenamine, 4-nitro-)

(RN-CAS Registry Number 100-01-6)

8.60 (V) PE 3856

156
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

c6h6n2o2+ QH/NO^NH,

(Benzenamine, 4-nitro-)

(RN-CAS Registry Number 100-01-6)

8.43 El 4089

c6h6n2o2+ C6H4(N02)NH2 (Benzenamine, 4-nitro-)

(RN-CAS Registry Number 100-01-6)

8.62±0.1 El 3447

C7H4N202+ QH^O^CN ** 10.29±0.1 El 3447

(Benzonitrile, 3-nitro-)

(RN-CAS Registry Number 619-24-9)

C7H4N202+ QH^O^CN ** 10.23±0.1 El 3447

(Benzonitrile, 4-nitro-)

(RN-CAS Registry Number 619-72-7)

c7h8 n2o2+

c7h8 n2 o2+

C6H4(N02)NHCH3 ** (Benzenamine, TV-methyl-2-nitro-)

(RN-CAS Registry Number 612-28-2)

C6H4(N02)NHCH3 ** (Benzenamine, A-methyl-4-nitro-)

(RN-CAS Registry Number 100-15-2)

8.02 (V)

8.17 (V)

PE

PE

3856

3856

c8 h10n2o2+ c6h2no2(ch3)2nh2 (Benzenamine, 2,6-dimethyl-4-nitro-)

(RN-CAS Registry Number 16947-63-0)

8.33 (V) PE 3856

c8 h,„n2o2+ C6H2N02 (CH3)2NH2 (Benzenamine, 3,5-dimethyl-4-nitro-)

(RN-CAS Registry Number 34761-82-5)

8.23 (V) PE 3856

c8 h10n2o2+ C6H4(N02)N(CH3)2 (Benzenamine, A,A-dimethyl-4—nitro-)

(RN-CAS Registry Number 100-23-2)

8.0 (V) PE 3856

c9h12n2o2+ C6H3 N02(CH3)N(CH3)2 8.30 (V) PE 3856

(Benzenamine, A^,A^,2-trimethyl-4-nitro-)

(RN-CAS Registry Number 32417-74-6)

C9H15 N202+ C4HN(0)(CH3)4C0NH2 ** 7.40±0.05 El 3494

( 177-Pyrrol- 1 -yloxy, 3-(aminocarbonyl)-2, 5-dihydro-2,2, 5, 5-tetramethyl-)

(RN-CAS Registry Number 3229-73-0)

(RD-Radical)

C9H17N202+ C4H3N(0)(CH3)4C0NH2 ** 7.40±0.05 El 3494

(1-Pyrrolidinyloxy, 3-(aminocarbonyl)-2,2, 5, 5-tetramethyl-)

(RN-CAS Registry Number 4399-80-8)

(RD-Radical)

C„H12N202+ ChH12N202 ** <7.5 El 3766

(DL-Tryptophan)

(RN-CAS Registry Number 54-12-6)

157
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

cu h21 n2 o2+

(RD-Radical)

C5 H5 N(0)(CH3)4NHC0CH3 ** 7.40±0.05

(1-Piperidinyloxy, 4-(acetylamino)-2,2,6,6-tetramethyl-)

(RN-CAS Registry Number 14691-89-5)

El 3494

C12 H20N2 O2+ C12 H20O2 N2 (2-Pentanone, 4,4'-( 1 ,2-ethanediyldinitrilo)bis-)

(RN-CAS Registry Number 6310-76-5)

7.71 (V) PE 3822

c13 h12 n2o2+ C6H4(N02)CH2 C6H4NH2 (Benzenamine, 4-[(4-nitrophenyl)methyl]-)

(RN-CAS Registry Number 726-17-0)

7.87±0.05 El 3806

c14 h14 n2o2+ C6H4(NH2)CH2CH2 C6H4N02 ** (Benzenamine, 4-[2-(4-nitrophenyl)ethyl]-)

(RN-CAS Registry Number 7357-96-2)

7.78±0.05 El 3806

c16h10n2o2+ c16h1?n2o2 ([A

2 ' 2 -Biindoline]-3,3'-dione)

(RN-CAS Registry Number 12626-73-2)

(ON-Other name: Indigo Blue)

7.17 PI 3586

c16h12 n2o2+ C6H4(N02)C3 H3 (CN)C6H5 ** 9.05±0.10

(Cyclopropanecarbonitrile, 1 -(p-nitrophenyl)-2-phenyl-)

(RN-CAS Registry Number 10432-22-1)

EDD 3575

c18h17n3o2+ C6H4(N02)C3 H3 (CN)C6H4N(CH3)2** 8.30±0.07 EDD

(Cyclopropanecarbonitrile, 2-(p-(dimethylamino)phenyl)- 1 -(p-nitrophenyl)-)

(RN-CAS Registry Number 28752-34-3)

3575

c4h3 no3+ c4h3ono2 ** (Furan, 2-nitro-)

(RN-CAS Registry Number 609-39-2)

10.04 ±0.05 El 3482

c6h5 no3+

c6h5 no3+

c6h5 no3+

C6H4(N02)0H ** 8.84±0.1 El 3447

(Phenol, 4-nitro-)

(RN-CAS Registry Number 100-02-7)

C6H4(N02)00CCH3 CH2 =C=0 10.85±0.2 El 3484

(Acetic acid, 3-nitrophenyl ester)

(RN-CAS Registry Number 1523-06-4)

C6H4(N02)00CCH3 CH2 =C=0 10.76 ±0.2 El 3484

(Acetic acid, 4-nitrophenyl ester)

(RN-CAS Registry Number 830-03-5)

C7H4N03+ C6H4(N02)C00H OH 13.00±0.2 El 3973

(Benzoic acid, 3-nitro-)

(RN-CAS Registry Number 121-92-6)

C7H4N03+ C6H4(N02)C00H OH 1 1 .58 ±0.2 El 3973

(Benzoic acid, 4-nitro-)

(RN-CAS Registry Number 62-23-7)

158
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c7h7no3+ C6H4(N02)0CH3 ** (Benzene, l-methoxy-3-nitro-)

(RN-CAS Registry Number 555-03-3)

9.09+0.1 El 3447

c7h7no3+ C6H4(N02)0CH3 ** (Benzene, l-methoxy-4-nitro-)

(RN-CAS Registry Number 100-17-4)

9.04±0.1 El 3447

c9huno3+ C6H4(OH)CH2CH(NH2)COOH ** (DL-Tyrosine)

(RN-CAS Registry Number 556-03-6)

<8.4 El 3766

c9h7n2 o3+ C6H4(N02)NHC0CH=CHCH3 ch3 (2-Butenamide, 7V-(4-nitrophenyl)-)

(RN-CAS Registry Number 51944-68-4)

13.6+0.3 El 3996

CioHiqNjO^ C6H4(N02)NHC0CH=chch3 * * (2-Butenamide, 7V-(4-nitrophenyl)-)

(RN-CAS Registry Number 51944-68-4)

9.1 ±0.1 El 3996

C^HjNO^ C6H4(No^cooh ** (Benzoic acid, 3-nitro-)

(RN-CAS Registry Number 121-92-6)

10.31+0.2 El 3973

c7h5 no4+ C6H4(N02)C00H ** (Benzoic acid, 4-nitro-)

(RN-CAS Registry Number 62-23-7)

10.18+0.2 El 3973

c8 h7no4+ C6H4(N02)00CCH3 ** (Acetic acid, 3-nitrophenyl ester)

(RN-CAS Registry Number 1523-06-4)

9.43+0.2 El 3484

c8h7no4+ C6H4(N02)00CCH3 ** (Acetic acid, 4-nitrophenyl ester)

(RN-CAS Registry Number 830-03-5)

9.48+0.2 El 3484

c13h9 no4+ c6h5 cooc6h4no2 ** (Benzoic acid 4-nitro phenyl ester)

(RN-CAS Registry Number 959-22-8)

9.3 El 3897

c17h9no4+ c17h9no4 ** (Naptho[2,3-/)quinoline-7, 12-dione, 5,6-dihydroxy-)

(RN-CAS Registry Number 568-02-5)

(ON-Other name: Alizarine Blue)

7.35 PI 3586

c6h4n2o4+ C6H4(N02)2 (Benzene, 1,3-dinitro-)

(RN-CAS Registry Number 99-65-0)

10.62+0.1 El 3447

c6h4n2o4+ C6H4(N02)2 (Benzene, 1,4-dinitro-)

(RN-CAS Registry Number 100-25-4)

10.63+0.1 El 3447

159
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c13 h10n2o4+ (QH.NO^CH,

(Benzene, 1 , 1 '-methylenebis[4-nitro-)

(RN-CAS Registry Number 1817-74-9)

9.98±0.05 El 3806

c14 h12 n2o4+ C6H4(N02)CH2 CH2 C6H4N02 ** (Benzene, 1,1'—(1 ,2-ethanediyl)bis[4-nitro-)

(RN-CAS Registry Number 736-30-1)

9.77±0.05 El 3806

C18H3oN204+ C4(N(C2H5)2)2(COOC2 H5)2 ** 7.55 (V)

( 1 ,3-Cyclobutadiene- 1 ,3-dicarboxylic acid, 2,4-bis(diethylamino)-

(RN-CAS Registry Number 20913-35-3)

PE

-, diethyl ester)

3885

C16HnN3 04+ C3 H3(CN)((C6H4)N02)2 (Cyclopropanecarbonitrile, 1 ,2-bis(p-nitrophenyl)~)

(RN-CAS Registry Number 28752-28-5)

9.30±0.05 EDD 3575

F

+ F2 F

(RN-CAS Registry Number 7782-41-4)

(TV-Threshold value approximately corrected to 0°K)

19.008 PI 3928

F2t

!ng) f2(RN-CAS Registry Number 7782-41-4)

(RS-Average of two Rydberg series limits)

15.70±0.02 S 3743

F2fng) f2(RN-CAS Registry Number 7782-41-4)

15.70 PE 3507

F2fnj f2(RN-CAS Registry Number 7782-41-4)18.98 (V) PE 3507

F2t

2 nu) F2 ** (RN-CAS Registry Number 7782-41-4) ~ 18.45 D 3743

HF+ (X2 n) HF ** (RN-CAS Registry Number 7664-39-3)

16.03±0.01 PE 3500

HF+

(

2 2

+

) HF ** (RN-CAS Registry Number 7664-39-3)

19.118 PE 3500

DF+

(

22

+

) DF ** (RN-CAS Registry Number 14333-26-7)

19.172 PE 3500

BF+ BF ** (RN-CAS-Registry Number 13768-60-0)

1 2 ± 1 El 4054

bf2+ BF2 ** (RN-CAS Registry Number 13842-55-2)

8± 1 El 3465

bf2+ BF2 ** (RN-CAS-Registry Number 13842-55-2)

9± 1 El 4054

bf2+ bf3 (RN-CAS-Registry Number 7637-07-2) ~ 16 El 4054

BFjfAJ BF3 ** (RN-CAS Registry Number 7637-07-2)

15.95 (V) PE 3704

BFjt2E') BF3 ** (RN-CAS Registry Number 7637-07-2)

160

16.65 (V) PE 3704
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

BF3t

2E") BF3 ** (RN-CAS Registry Number 7637-07-2)

17.10 (V) PE 3704

BF3fA2) BF3 ** (RN-CAS Registry Number 7637-07-2)

19.15 (V) PE 3704

BF3t

2E') BF3 ** (RN-CAS Registry Number 7637-07-2)

20.10 (V) PE 3704

bf3+ BF3 ** (RN-CAS Registry Number 7637-07-2)

15.71 ±0. 10 RPD 3540

bf3+ BF3 ** (RN-CAS-Registry Number 7637-07-2)

17± 1 El 4054

bf3+ (C2H5)2OBFj (c2h5)2o

(RN-CAS Registry Number 109-63-7)

15.00±0.10 RPD 3540

B2F4fA,) B2F4 (RN-CAS Registry Number 13965-73-6)

<12.23 ±0.06 PE 3709

B2F4fE) B2F4 (RN-CAS Registry Number 13965-73-6)

<15.50±0.03 PE 3709

B2F4t

2 B,) B2F4 (RN-CAS Registry Number 13965-73-6)

16.32±0.01 (V) PE 3709

B,F4t

2 B2) b2f4 (RN-CAS Registry Number 13965-73-6)

17.20+0.01 PE 3709

B2F4t

2E) b2f4 (RN-CAS Registry Number 13965-73-6)

<18.71 ±0.03 PE 3709

B2F4t

2E,2A,) b2f4 (RN-CAS Registry Number 13965-73-6)

20.52±0.01 PE 3709

CF+ CF ** (RN-CAS Registry Number 3889-75-6)9.24 D 3930

(RD-Radical)

CF+ CH2 =CF2 CH2F

(RN-CAS Registry Number 75-38-7)

(TR-Other product(s) thermochemically reasonable)

14.92±0.02 PI 3930

CF+ c,f3ci cf2ci

(RN-CAS-Registry Number 79-38-9)

16.7 ±0.

1

El 4070

CF+ CFC1=CFC1 CFC12 (RN-CAS-Registry Number 598-88-9)

16.5±0.1 El 4070

cf2+ CF2 ** (RN-CAS Registry Number 2154-59-8)

1 1 .54±0. 10 El 3818

(RD-Radical)

cf2+ CF2 ** (RN-CAS Registry Number 2154-59-8)

9.74 D 3930

(RD-Radical)

cf2+ c2f4 cf2 (RN-CAS Registry Number 116-14-3)

15.2±0.1 El 3539

cf3+ ch3cf3 ch3

1 3.94±0.

1

El 3478

(RN-CAS Registry Number 71-55-6)

cf3+ (CF3)2CO 13.8 El 3550

(RN-CAS Registry Number 684-16-2)

161
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

cf3+ CH3 COCF3 (RN-CAS Registry Number 421-50-1)

14.6 El 3550

c2f3+ C2 F3 C1 Cl

(RN-CAS-Registry Number 79-38-9)

15.4±0.1 El 4070

CF4fT,) CF4 ** (RN-CAS Registry Number 75-73-0)

16.25 ±0.04 (V) PE 3880

CF^TJ CF4 ** (RN-CAS Registry Number 75-73-0)

17.46±0.04 (V) PE 3880

CF4t

2 E) CF4 ** (RN-CAS Registry Number 75-73-0)

18.58±0.04 (V) PE 3880

C2F4fB2u) C2F4 (RN-CAS Registry Number 116-14-3)

10.10 PE 3649

C2F4+ C2 F4 (RN-CAS Registry Number 116-14-3)

10.32 PE 3589

c2f4+ C2F4 (RN-CAS Registry Number 116-14-3)

10.52 (V) PE 4084

C2F4t

2 Ag

) C2 F4 ** (RN-CAS Registry Number 116-14-3)

15.6 PE 3649

C2F4t

2B2g) C2F4 (RN-CAS Registry Number 116-14-3)

16.4 (V) PE 3649

C.F.fB.J C2 F4 (RN-CAS Registry Number 116-14-3)

16.6 (V) PE 3649

C2 F4t

2A„) C2F4 ** (RN-CAS Registry Number 116-14-3)

16.9 (V) PE 3649

C2F4t

2 B3g) C2F4 ** (RN-CAS Registry Number 116-14-3)

17.50 PE 3649

QF.fBjJ C2 F4 (RN-CAS Registry Number 116-14-3)

18.0 PE 3649

C2 F4t

2 B ]u) C2F4 ** (RN-CAS Registry Number 116-14-3)

19.19 PE 3649

C2F4t

2 Ag

) C2F4 ** (RN-CAS Registry Number 116-14-3)

-20.6 PE 3649

C2 F4t

2 B,J C2F4 ** (RN-CAS Registry Number 116-14-3)

-22.3 PE 3649

c3 f6+ cf3 cf=cf2 ** (RN-CAS Registry Number 116-15-4)10.62 PE 3589

c4f6+ cf3 c=ccf3 ** (RN-CAS Registry Number 692-50-2)12.31 PE 3589

C6F6+ c6f6 (Benzene, hexafluoro-)

(RN-CAS Registry Number 392-56-3)

9.90±0.01 S 3559

c6f* C F ** ^6r6 (Benzene, hexafluoro-)

(RN-CAS Registry Number 392-56-3)

12.62±0.01 S 3559

162
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

c6f6+ p c **'-6r6 9.90 (V) PE 3873

(Benzene, hexafluoro-)

(RN-CAS Registry Number 392-56-3)

C6F6fE,e

) r f ** 9.93 PE 3637

(Benzene, hexafluoro-)

(RN-CAS Registry Number 392-56-3)

C4F8+

cis-2-C4F8 ** 11.46 (V) PE 4084

(RN-CAS Registry Number 1516-65-0)

C4F8+

trans-2-CA¥% ** 11.55 (V) PE 4084

(RN-CAS Registry Number 1516-64-9)

c4f8+

trans-2-C4F8 ** 11.55 (V) PE 3649

(RN-CAS Registry Number 1516-64-9)

c10f8+ C10F8 (Naphthalene, octafluoro-)

(RN-CAS Registry Number 313-72-4)

8.85 PE 3637

C^Fjo (C6F5)2 (1,T-Biphenyl, decafluoro-)

(RN-CAS Registry Number 434-90-2)

9.40±0.02 PE 3702

QF+ (CF3)2C=C(CF3)2 (RN-CAS Registry Number 360-57-6)

12.61 (V) PE 4084

ch2f

+ ch2f ** (RN-CAS Registry Number 3744-29-4)

(RD-Radical)

ch2f

+ ch2f ** (RN-CAS Registry Number 3744-29-4)

(RD-Radical)

ch2f

+ ch2f2 f

(RN-CAS Registry Number 75-10-5)

(TR-Other product(s) thermochemically reasonable)

ch2f

+ ch2 =cf2 cf

(RN-CAS Registry Number 75-38-7)

(TR-Other product(s) thermochemically reasonable)

8.90 EM 3732

9.16+0.02 D 3930

14.06 EM 3732

14.84+0.02 PI 3930

C,HF+ C2H3 F H2 (RN-CAS Registry Number 75-02-5)

(TR-Other product(s) thermochemically reasonable)

c2hf4 ch2 =cf2 hf

(RN-CAS Registry Number 75-38-7)

C^F* QHjF h

(RN-CAS Registry Number 75-02-5)

C2H2F

+ ch2 =cf2 f

(RN-CAS Registry Number 75-38-7)

(TR-Other product(s) thermochemically reasonable)

C2H2F

+ CH2 = CFC1 Cl

(RN-CAS-Registry Number 2317-91-1)

13.72+0.02 PI 3930

14.18+0.03 PI 3930

13.56+0.04 PI 3930

14.37±0.02 PI 3930

13.7+0.1 El 4070

163
Table of Ion Energetics Measurements—Continued

Ion

-3 n5

J

'3 n5

J

Reactant Other

products

ch2 =chch2f ** (RN-CAS Registry Number 818-92-8)

ch2 =chch2f ** (RN-CAS Registry Number 818-92-8)

Ionization or appearance

potential

(eV)

Method

10.11

10.56 (V)

PE

PE

Ref.

c2 h3 f

+ c2 h3 f 10.35+0.01 PI 3930

(RN-CAS Registry Number 75-02-5)

c2 h4f

+ ch3 chf2 f 14.80±0.1 El 3478

(RN-CAS Registry Number 75-37-6)

C,HsF

+

(

2A') C2H5 F ** 12.43 (V) PE 3984

C2Hs F

+

(

2 A”)

(RN-CAS Registry Number 353-36-6)

QHsF ** 12.87 (V) PE 3984

(RN-CAS Registry Number 353-36-6)

C2Hs F

+

(

2A’) C2 H5 F ** 13.96 (V) PE 3984

C2 H5 F

+

(

2A')

(RN-CAS Registry Number 353-36-6)

C2H5 F ** 14.57 (V) PE 3984

C2 Hs F

+

(

2A')

(RN-CAS Registry Number 3.53-36-6)

C2H5 F

** 16.00 (V) PE 3984

C2H5 F

+

(

2A',2A

w

) (RN-CAS Registry Number 353-36-6)

c2h5 f 17.23 (V) PE 3984

(RN-CAS Registry Number 353-36-6)

C3 HF+ chf2c=ch hf

(RN-CAS Registry Number 18371-25-0)

12.6±0.15 El 3769

c3 h2f

+ CHF2C=CH f

(RN-CAS Registry Number 18371-25-0)

14.2±0.2 El 3769

3863

4091

c3 h7 f «-c3 h7f ** (RN-CAS Registry Number 460-13-9)

11.96 (V) PE 3984

C6H4F

+ C6H4(F)COOH co+oh

(Benzoic acid, 3-fluoro-)

(RN-CAS Registry Number 455-38-9)

(MT-Metastable transition(s) observed)

C6H4F

+ C6H4(F)COOH co+oh

(Benzoic acid, 4-fluoro-)

(RN-CAS Registry Number 456-22-4)

(MT-Metastable transition(s) observed)

c6h4f+ c6h4fno2 no2 (Benzene, l-fluoro-3-nitro-)

(RN-CAS Registry Number 402-67-5)

c6h4f

+ c6h4fno2 no2 (Benzene, l-fluoro-4-nitro-)

(RN-CAS Registry Number 350-46-9)

15.25±0.2 El

15.33±0.2 El

12.22±0.1 El

12.37±0.1 El

3973

3973

3447

3447

C6H5 F

+ C6H5 F ** 9.20 S 3559

(Benzene, fluoro-)

(RN-CAS Registry Number 462-06-6)

164
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

c6h5 f

+ *

c6h5f

+

c6h5f

+

c6h5f

+

c6h5 f+

c6h5f

+

C7H6f

+

C7H7f

+

C7H7f

+

C7H7f

+

c6h5 f

(Benzene, fluoro-)

(RN-CAS Registry Number 462-06-6)

c6h5f

(Benzene, fluoro-)

(RN-CAS Registry Number 462-06-6)

C6H5 F

(Benzene, fluoro-)

(RN-CAS Registry Number 462-06-6)

C6H5F

(Benzene, fluoro-)

(RN-CAS Registry Number 462-06-6)

c6h4foch3 ch2o

(Benzene, l-fluoro-3-methoxy-)

(RN-CAS Registry Number 456-49-5)

c6h4foch3 ch2o

(Benzene, l-fluoro-4-methoxy-)

(RN-CAS Registry Number 459-60-9)

c6h4fc4h9 (Benzene, l-butyl-3-fluoro-)

(RN-CAS Registry Number 20651-66-5)

c6h4fc4h9 (Benzene, l-butyl-4-fluoro-)

(RN-CAS Registry Number 20651-65-4)

c6h5 ch2f ** (Benzene, (fluoromethyl)-)

(RN-CAS Registry Number 350-50-5)

c6h4fc4h9 ch2 =chch3 (Benzene, 1 -butyl-3-fluoro-)

(RN-CAS Registry Number 20651-66-5)

c6h4fc4h9 ch2 =chch3 (Benzene, l-butyl-4-fluoro-)

(RN-CAS Registry Number 20651-65-4)

11.82 S 3559

9.11 PE 3955

9.19 (V) PE 3873

9.35±0.03 (V) PE 3713

11.76+0.1 El 3446

11.55+0.1 El 3446

11.69+0.1 El 3629

11. 25 ±0.1 El 3629

9.55 (V) PE 3992

10.21 ±0.1 El 3629

10.29±0.1 El 3629

c10h13f+

c10h13f

+

c6h4fc4h9 (Benzene, l-butyl-3-fluoro-)

(RN-CAS Registry Number 20651-66-5)

c6h4fc4h9 (Benzene, l-butyl-4-fluoro-)

(RN-CAS Registry Number 20651-65-4)

9.19±0.1

9. 1 5 ±0.

1

El

El

3629

3629

c10h15f

+ c10h15f

(Tricyclo[3 . 3.1.1

3,7]decane, 2-fluoro-)

(RN-CAS Registry Number 16668-83-0)

(ON-Other name: 2-Fluoroadamantane)

9.46 PE 3886

c12h9f

+ c6h5 c6h4f 8.20±0.02 PE 3702

(l,l'-Biphenyl, 2-fluoro-)

(RN-CAS Registry Number 321-60-8)

165
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c12 h9f

+ c6h5 c6h4f

(l,l'-Biphenyl, 4-fluoro-)

(RN-CAS Registry Number 324-74-3)

8.00±0.02 PE 3702

chf2+

(RD-Radical)

chf2 ** (RN-CAS Registry Number 2670-13-5)

<8.90 EM 3732

chf2+ ch2 f2 h

(RN-CAS Registry Number 75-10-5)

13.11 EM 3732

chf2+ chf2c=ch c2h

(RN-CAS Registry Number 18371-25-0)

13.8±0.1 El 3769

QHF2+ ch2 =cf2 h

(RN-CAS Registry Number 75-38-7)

15.80+0.04 PI 3930

C2 H2F2+ CH2 =CF2 ** (RN-CAS Registry Number 75-38-7)

10.29+0.01 PI 3930

c2 h2 f2+ ck-CHF =CHF ** (RN-CAS Registry Number 1630-77-9)

10.43 (V) PE 3649

c2 h2 f2+ trans-CHF =CHF ** (RN-CAS Registry Number 1630-78-0)10.38 (V) PE 3649

c2 h3 f2+ CH3 CF3 f

(RN-CAS Registry Number 71-55-6)

15. 14±0.El 3478

c3 hf2+ CHF2C=CH h

(RN-CAS Registry Number 18371-25-0)

12.9+0.1 El 3769

c3 h2f2+ CHF2C=CH ** (RN-CAS Registry Number 18371-25-0)11.6±0.1 El 3769

c6h4f2+ C6H4F2 (Benzene, 1,2-difluoro-)

(RN-CAS Registry Number 367-11-3)

9.30 (V) PE 3873

c6h4f2+ c6h4f2 (Benzene, 1,2-difluoro-)

(RN-CAS Registry Number 367-11-3)

9.6±0.03 (V) PE 3713

c6h4f2+ C6H4F2 (Benzene, 1,3-difluoro-)

(RN-CAS Registry Number 372-18-9)

9.32 (V) PE 3873

C6H4F2+ C6H4F2 (Benzene, 1,3-difluoro-)

(RN-CAS Registry Number 372-18-9)

9.6±0.03 (V) PE 3713

c6h4f2+ c6h4f2 (Benzene, 1,4-difluoro-)

(RN-CAS Registry Number 540-36-3)

9.15 (V) PE 3873

c6h4f2+ C6H4F2 (Benzene, 1,4-difluoro-)

(RN-CAS Registry Number 540-36-3)

9.4±0.03 (V) PE 3713

166
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c12h8f2+

2

(C6H4F)2 (l,l'-Biphenyl, 2,2'-difluoro-)

(RN-CAS Registry Number 388-82-9)

(C6H4F)2 (1,1 '-Biphenyl, 3,3'-difluoro-)

(RN-CAS Registry Number 396-64-5)

8.35+0.02

8.35+0.02

PE

PE

3702

3702

c12h8f2+ (C6H4F)2 (1,1 '-Biphenyl, 4,4'-difluoro-)

(RN-CAS Registry Number 398-23-2)

8.00+0.02 PE 3702

QHF+ c2hf3 ** (RN-CAS Registry Number 359-11-5)10.53 (V) PE 3649

c2h3 f3+ ch3 cf3 ** (RN-CAS Registry Number 71-55-6)

13.26+0.1 El 3478

c3hf3+ cf3c=ch ** (RN-CAS Registry Number 661-54-1)

11.83 PE 3589

C«H,F,t

2E') C6H3 F,

(Benzene, 1,3,5-trifluoro-)

(RN-CAS Registry Number 372-38-3)

(RS-Average of two Rydberg series limits)

9.64 S 3764

C6H3 F3fA3 C6H3F3 (Benzene, 1,3,5-trifluoro-)

(RN-CAS Registry Number 372-38-3)

12.35 S 3764

C6H3F3+ C6H3F3 (Benzene, 1,3,5-trifluoro-)

(RN-CAS Registry Number 372-38-3)

9.26 (V) PE 3873

C6H3 F3

lf2 E") c6h3f3 (Benzene, 1,3,5-trifluoro-)

(RN-CAS Registry Number 372-38-3)

9.64 PE 3764

C6H3F3t

2AD C6H3F3 (Benzene, 1,3,5-trifluoro-)

(RN-CAS Registry Number 372-38-3)

12.35 PE 3764

c,h3f3-» C6H3 F3 (Benzene, 1,3,5-trifluoro-)

(RN-CAS Registry Number 372-38-3)

13.58 (V) PE 3764

c6h2f4+ C6H2F4 (Benzene, 1,2,3,4-tetrafluoro-)

(RN-CAS Registry Number 551-62-2)

9.56 (V) PE 3873

C6H2F4+ C6H2F4 (Benzene, 1,2,3,5-tetrafluoro-)

(RN-CAS Registry Number 2367-82-0)

9.56 (V) PE 3873

C6H2F4+ C6H2F4 (Benzene, 1,2,4,5-tetrafluoro-)

(RN-CAS Registry Number 327-54-8)

9.36 (V) PE 3873

C6H2F4+ c6h2f4

( 1 ,2,4, 5-Tetrafluorobenzene)

(RN-CAS Registry Number 327-54-8)

8.92 PE 3522

167
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c6hf5+ c6hf5 (Benzene, pentafluoro-)

(RN-CAS Registry Number 363-72-4)

(RS-Average of two Rydberg series limits)

9.82 S 3559

c6hf* c6hf5 (Benzene, pentafluoro-)

(RN-CAS Registry Number 363-72-4)

12.44 S 3559

c6hf5+ c6hf5 (Benzene, pentafluoro-)

(RN-CAS Registry Number 363-72-4)

9.64 (V) PE 3873

c8 h3 f5+ c6f5ch=ch2 (Benzene, ethenylpentafluoro-)

(RN-CAS Registry Number 653-34-9)

NF+ NF2 F"

(RN-CAS Registry Number 3744-07-8)

(TR-Other product(s) thermochemically reasonable)

NF+ NF2 F

(RN-CAS Registry Number 3744-07-8)

(TR-Other product(s) thermochemically reasonable)

NF+ N2F4 NF2 +F

(RN-CAS Registry Number 10036-47-2)

(TR-Other product(s) thermochemically reasonable)

NF+ (CH2 NF2)CH2 (RN-CAS Registry Number 21298-22-6)

NF+ (CH3)2C(NF2)2 (RN-CAS Registry Number 19309-63-8)

n2f+ n2 f4 f2 +f

(RN-CAS Registry Number 10036-47-2)

(TR-Other product(s) thermochemically reasonable)

N2 F

+ N2F4 3F

(RN-CAS Registry Number 10036-47-2)

(TR-Other product(s) thermochemically reasonable)

NFJ'A,) NF2 (RN-CAS Registry Number 3744-07-8)

(RD-Radical)

NFJ'A,) NF2 (RN-CAS Registry Number 3744-07-8)

(RD-Radical)

NF2t

3 B,) NF2 ** (RN-CAS Registry Number 3744-07-8)

(RD-Radical)

NFjt’B,) NF2 (RN-CAS Registry Number 3744-07-8)

(RD-Radical)

NF2t'B„

3 B2 , !A2) NF2 (RN-CAS Registry Number 3744-07-8)

(RD-Radical)

9.18±0.02 PE 3854

11.86±0.2 El 3785

15.46±0.2 El 3785

~ 16.6 El 3785

13.0±0.3 El 3634

13.9+0.3 El 3634

14.2+0.3 El 3785

16.7±0.3 El 3785

12.1 ±0.1 (V) PE 3671

12.1 PE 3693

14.6+0.1 (V) PE 3671

14.6 PE 3693

~ 16.4+0.1 (V) PE 3671

168
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

nf2+ NF2 ** (RN-CAS Registry Number 3744-07-8)

16.4 PE 3693

(RD-Radical)

NF? NF2 ** (RN-CAS Registry Number 3744-07-8)

~17.6±0.1 (V) PE 3671

(RD-Radical)

NF2t'B2) NF2 ** (RN-CAS Registry Number 3744-07-8)

17.6 PE 3693

(RD-Radical)

nf2+ NF2 ** (RN-CAS Registry Number 3744-07-8)

11.76±0.1 El 3785

(RD-Radical)

nf2+ N2F4 F“+NF

(RN-CAS Registry Number 10036-47-2)

12. 40 ±0.1 DC 3785

nf2+ n2f4 nf2 (RN-CAS Registry Number 10036-47-2)

(TR-Other product(s) thermochemically reasonable)

12.70±0.1 DC 3785

nf2+ (CHjNF^CHj

(RN-CAS Registry Number 21298-22-6)

14.8±0.4 El 3634

nf2+ (CH3)2C(NF2)2 (RN-CAS Registry Number 19309-63-8)

13.9±0.4 El 3634

N2F2t

2Ag

) trans-N2F2 ** (RN-CAS Registry Number 13776-62-0)

12.8 PE 3649

N2 F2t

2AJ trans-N2F2 ** (RN-CAS Registry Number 13776-62-0)

13.65 PE 3649

N2F2t

2A„) tra«5-N2F2 ** (RN-CAS Registry Number 13776-62-0)

18.0 PE 3649

N2F^2 Bu) trans-N2F2 ** (RN-CAS Registry Number 13776-62-0)

19.8 (V) PE 3649

N2F2t

2 Ag

) trans-N2F2 ** (RN-CAS Registry Number 13776-62-0)

21.0 (V) PE 3649

N2F2t

2 BJ taz«s-N2F2 ** (RN-CAS Registry Number 13776-62-0)

22.3 PE 3649

N2F2+ N2F4 2F

(RN-CAS Registry Number 10036-47-2)

(TR-Other product(s) thermochemically reasonable)

16.0±0.1 El 3785

NFjfA,) NF3 ** (RN-CAS Registry Number 7783-54-2)12.97±0.04 PE 3641

NF3* NF3 ** (RN-CAS Registry Number 7783-54-2)

15.49 ±0.04 PE 3641

NFj* NF3 ** (RN-CAS Registry Number 7783-54-2)

16.55±0.05 (V) PE 3641

NF3fE) NF3 ** (RN-CAS Registry Number 7783-54-2)

17.16±0.03 PE 3641

NFjfA,) NF3 ** (RN-CAS Registry Number 7783-54-2)

19.24±0.03 PE 3641

NF3fE) NF3 ** (RN-CAS Registry Number 7783-54-2)

21.14±0.07 (V) PE 3641

169
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

nf3+ NF3 ** (RN-CAS Registry Number 7783-54-2)

13.18±0.1 El 3578

n2 f4+ N2F4 (RN-CAS Registry Number 10036-47-2)

12.00±0.El 3785

B3 H3 N3 F3+ B3 H3 N3 F3 (Borazine, 2,4,6-trifluoro-)

(RN-CAS Registry Number 13779-24-3)

10.46 PE 3637

b3 h3 n3 f3+ B3 H3 N3 F3 (Borazine, 2,4,6-trifluoro-)

(RN-CAS Registry Number 13779-24-3)

10.66 (V) PE 3944

b3 h3 n3 f3+ b3 h3 n3 f3 (Borazine, 2,4,6-trifluoro-)

(RN-CAS Registry Number 13779-24-3)

10.66 (V) PE 3673

CN2 F2t

2B,) cf2 n2 **

(3J/-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

11.2 PE 3727

CN2F2t

2B2, 2A,) cf2n2 **

(3//-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

15.00 PE 3727

CN2F2fB2 , 2A,) cf2 n2 **

(3J/-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

16.75 (V) PE 3727

CN2 F2t

2A2) cf2n2 **

(3/f-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

17.8 (V) PE 3727

CN2F2fB,) cf2 n2 **

(3/f-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

19.0 PE 3727

CN2 F2t

2A„2B2) cf2 n2 **

(3/f-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

20.9 (V) PE 3727

CN2F2t

2A„2B,) cf2 n2 **

(3/f-Diazirine, 3,3-difluoro-)

(RN-CAS Registry Number 693-85-6)

23.4 (V) PE 3727

C3 N3 F3+ c3 n3 f3 **

(1,3,5-Triazine, 2,4,6-trifluoro-)

(RN-CAS Registry Number 675-14-9)

11.5 PE 3637

c5 nf+ c5 nf5 **

(Pyridine, pentafluoro-)

(RN-CAS Registry Number 700-16-3)

10.08 PE 3637

C2 N2 F6+ os-CF3N=NCF3 ** (RN-CAS Registry Number XXXXX-XX-X) ~ 10.5 PE 3649

C8 N2 F6+ C8 N2(F)6 (Cinnoline, hexafluoro-)

(RN-CAS Registry Number 28734-86-3)

170

9.66 (V) PE 3959
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8n2f6+ c8n2(F)6 (Phthalazine, hexafluoro-)

(RN-CAS Registry Number 25732-35-8)

9.90 (V) PE 3959

c8 n2f6+ C8 N2(F)6 (Quinazoline, hexafluoro-)

(RN-CAS Registry Number 28734-87-4)

9.43 (V) PE 3959

c8 n2 f6+ c8n2(F)6 (Quinoxaline, hexafluoro-)

(RN-CAS Registry Number 21271-15-8)

9.65 (V) PE 3959

c9nf7 + c9nf7 **

(Isoquinoline, heptafluoro-)

(RN-CAS Registry Number 13180-39-7)

9.29 (V) PE 3723

c9nf7+ c9nf7 **

(Quinoline, heptafluoro-)

(RN-CAS Registry Number 13180-38-6)

9.51 (V) PE 3723

ch2nf+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

11.9±0.2 El 3634

ch2nf+ CH2(NF2)CH(NF2)CH3 CH3 C(NF2)FH?

(RN-CAS Registry Number 15403-25-5)

11.5±0.2 El 3634

c2h3 nf+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

16.8±0.4 El 3634

c3h„nf+ CH2(NF2)CH(NF2)CH3 (RN-CAS Registry Number 15403-25-5)14.6±0.3 El 3634

c6h6nf+ c6h4fnhcoch3 ch2 =c=o

(Acetamide, 7V-(2-fluorophenyl)-)

(RN-CAS Registry Number 399-31-5)

9.80+0.03 El 3483

c6h6nf+ c6h4fnhcoch3 ch2 =c=o

(Acetamide, 7V-(4-fluorophenyl)-)

(RN-CAS Registry Number 351-83-7)

10.12±0.03 El 3483

chnf2+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

13.7+0.3 El 3634

chnf2+ (CH3)2C(NF2)2 (RN-CAS Registry Number 19309-63-8)

13.2+0.3 El 3634

ch2nf2+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

13.6±0.3 El 3634

ch2 nf2+ CH2(NF2)CH(NF2)CH3 (RN-CAS Registry Number 15403-25-5)

13.1+0.2 El 3634

c2h6nf2+ (CH2NF2)CH2 (RN-CAS Registry Number 21298-22-6)

11.8+0.3 El 3634

c2h6nf2+ CH2(NF2)CH(NF2)CH3 (RN-CAS Registry Number 15403-25-5)

10.8±0.2 El 3634

c2h6nf2+ (CH3)2C(NF2)2 (RN-CAS Registry Number 19309-63-8)

11.1+0.3 El 3634

171
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c6h5 nf2+ c6h3 f2 nhcoch3 ch2 =c=o

(Acetamide, iV-(2,4-difluorophenyl)-)

(RN-CAS Registry Number 399-36-0)

9.70±0.03 El 3480

c6h5 nf2+ c6h3 f2 nhcoch3 ch2 =c=o

(Acetamide, V-(2,6-difluorophenyl)-)

(RN-CAS Registry Number 3896-29-5)

9.52±0.03 El 3480

c8h4n2f2+ C8 H4N2(F)2 (Quinoxaline, 2,3-difluoro-)

(RN-CAS Registry Number 7066-36-6)

9.30 (V) PE 3959

c8h2n2f4+ C8 H2N2(F)4 (Quinoxaline, 5,6,7,8-tetrafluoro-)

(RN-CAS Registry Number 33319-19-6)

9.50 (V) PE 3959

c„h2 nf5+ c6f5 nh2 (Benzenamine, 2,3,4,5,6-pentafluoro-)

(RN-CAS Registry Number 771-60-8)

8.40±0.02 PE 3890

c„h2nf5+ c6f5 nh2 (Benzenamine, 2, 3 ,4, 5 , 6-pentafluoro-)

(RN-CAS Registry Number XXXXX-XX-X)

8.60 PE 3955

c6h7 nf+ (CH3)2NC(CF3) =C(CF3)H

(RN-CAS Registry Number 35186-00-6)

8.22 PE 3589

c4h12 bn2f

+ ((CH3)2N)2 BF2 (RN-CAS Registry Number 383-90-4)

8.04 PE 3584

c2h6bnf2+ (CH3)2NBF2 ** (RN-CAS Registry Number 359-18-2)

9.71 PE 3584

C3H9 B3 N3 F3+ c3 h9b3 n3 f3 **

(Borazine, 2,4,6-trifluoro-l,3,5-trimethyl-)

(RN-CAS Registry Number 13722-15-1)

9.48 (V) PE 3944

OF+

(RD-Radical)

OF ** (RN-CAS Registry Number 12061-70-0)12.79±0.1 D 3920

OF+ OF2 F

(RN-CAS Registry Number 7783-41-7)

(TV-Threshold value approximately corrected to 0°K)

<14.438 PI 3920

of2+ OF2 ** (RN-CAS Registry Number 7783-41-7)

13.11 ±0.0PI 3920

OFJ'Bj) OF2 ** (RN-CAS Registry Number 7783-41-7)

13.11 PE 3649

OFjfB,) OF2 ** (RN-CAS Registry Number 7783-41-7)13.26 (V) PE 3694

OF2fA,) OF2 ** (RN-CAS Registry Number 7783-41-7)15.74 PE 3649

OF2t

2 B2) OF2 ** (RN-CAS Registry Number 7783-41-7)

172

16.17 (V) PE 3694
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

OF2t"B|) of2 ** 16.44 (V) PE 3649

(RN-CAS Registry Number 7783-41-7)

OF2fA2) of2 ** 16.47 (V) PE 3694

(RN-CAS Registry Number 7783-41-7)

OF2t

2A2) of2 ** ~ 17.9 PE 3649

(RN-CAS Registry Number 7783-41-7)

OF2

h* of2 ** 18.68 (V) PE 3694

(RN-CAS Registry Number 7783-41-7)

of2* of2 ** 19.50 (V) PE 3694

(RN-CAS Registry Number 7783-41-7)

OF2fB„2A,) of2 ** 19.55 (V) PE 3649

(RN-CAS Registry Number 7783-41-7)

OF2fB2) of2 ** 20.7 (V) PE 3649

(RN-CAS Registry Number 7783-41-7)

OF2** of2 ** 20.9 (V) PE 3694

(RN-CAS Registry Number 7783-41-7)

HOF+ HOF ** 12.7 1 ±0.01 PI 3932

(RN-CAS Registry Number 14034-79-8)

HOF+(2A") HOF ** 12.69+0.03 PE 3831

(RN-CAS Registry Number 14034-79-8)

HOF+

(

2A') HOF ** 14.50+0.03 PE 3831

HOF+

(

2A')

(RN-CAS Registry Number 14034-79-8)

HOF ** 15.9+0.05 PE 3831

(RN-CAS Registry Number 14034-79-8)

BOF+ BOF ** 14± 1 El 4054

(RN-CAS-Registry Number 23361-56-0)

bof2+ bof2 ** 1 7 ± 1 El 4054

(RN-CAS-Registry Number 12006-82-5)

COFjfB,) cf2o ** 13.02 PE 3649

COF2t

2B2) (RN-CAS Registry Number 353-50-4)

cf2o ** 13.04 PE 3726

COF2t

2B2) (RN-CAS Registry Number 353-50-4)

cf2o ** 14.09 PE 3649

(RN-CAS Registry Number 353-50-4)

COF2* cf2o ** <14.26 PE 3726

COF2t

2A„2B„2A2) (RN-CAS Registry Number 353-50-4)

cf2o ** 16.1 PE 3649

(RN-CAS Registry Number 353-50-4)

cof2* cf2o ** 16.6 (V) PE 3726

COF2t

2B,)

(RN-CAS Registry Number 353-50-4)

cf2o ** 16.90 PE 3726

COF2t

2A„2B„2A2) (RN-CAS Registry Number 353-50-4)

cf2o ** 16.91 PE 3649

(RN-CAS Registry Number 353-50-4)

COF^ cf2o ** 19.06 PE 3726

COF2t

2A,)

(RN-CAS Registry Number 353-50-4)

cf2o ** 19.15 PE 3649

(RN-CAS Registry Number 353-50-4)

173
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

COFj* cf2o ** (RN-CAS Registry Number 353-50-4)

19.46 PE 3726

COF2t

2 B2) cf2 o ** (RN-CAS Registry Number 353-50-4)

19.8 (V) PE 3649

COF2fB,) cf2o ** (RN-CAS Registry Number 353-50-4)

21.1 (V) PE 3649

COF2fA,) cf2o ** (RN-CAS Registry Number 353-50-4)

-22.7 PE 3649

C2OF3+ (CF3)2 CO

(RN-CAS Registry Number 684-16-2)

11.65 El 3550

CF40

+

(

2A

w

) cf3 of ** (RN-CAS Registry Number 373-91-1)

13.6 (V) PE 3941

cf4o

+ * CF3 OF ** (RN-CAS Registry Number 373-91-1)

16.6 (V) PE 3941

cf4o

+ * cf3 of ** (RN-CAS Registry Number 373-91-1)

17.5 (V) PE 3941

cf4o

+ * cf3 of ** (RN-CAS Registry Number 373-91-1)

19.0 (V) PE 3941

cf4o

+ * cf3 of ** (RN-CAS Registry Number 373-91-1)

20.40 (V) PE 3941

c3 of5+ (CF3 )2 CO

(RN-CAS Registry Number 684-16-2)

16 El 3550

c3 f6o

+ (CF3)2CO

(RN-CAS Registry Number 684-16-2)

11.44 PE 3649

c6h4of

c6h4of+

c6h4of+

'6n4

v

c6h4foch3 ch3 (Benzene, l-fluoro-3-methoxy-)

(RN-CAS Registry Number 456-49-5)

c6h4foch3 ch3 (Benzene, l-fluoro-4-methoxy-)

(RN-CAS Registry Number 459-60-9)

c6h4fno2 no

(Benzene, l-fluoro-3-nitro-)

(RN-CAS Registry Number 402-67-5)

c6h4fno2 no

(Benzene, l-fluoro-4-nitro-)

(RN-CAS Registry Number 350-46-9)

12.53±0.1

1 1.99±0.1

10.25±0.

10.64±0.

El

El

El

El

3446

3446

3447

3447

C6H5OF+ C6H4FOOCCH3 CH2 = C=0 9. 17 ±0.03 El 3483

(Phenol, 2-fluoro-, acetate)

(RN-CAS Registry Number 29650-44-0)

C6H5OF+ C6H4FOOCCH3 CH2 =C=0 9.55±0.03 El 3483

(Phenol, 4-fluoro-, acetate)

(RN-CAS Registry Number 405-51-6)

C7 H4OF+ C6H4(F)COOH OH 12.50±0.2 El 3973

(Benzoic acid, 3-fluoro-)

(RN-CAS Registry Number 455-38-9)

174
Table of Ion Energetics Measurements—-Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C7H4OF+ C6H4(F)COOH oh

(Benzoic acid, 4-fluoro-)

(RN-CAS Registry Number 456-22-4)

12.33±0.2 El 3973

c7h7of+ C6H4FOCH3 ** (Benzene, l-fluoro-3-methoxy-)

(RN-CAS Registry Number 456-49-5)

8.70±0.1 El 3446

c7h7of+ C6H4FOCH3 ** (Benzene, l-fluoro-4-methoxy-)

(RN-CAS Registry Number 459-60-9)

8.58±0.1 El 3446

C7H502F

+ C6H4(F)COOH ** 9.91 ±0.2 El 3973

(Benzoic acid, 3-fluoro-)

(RN-CAS Registry Number 455-38-9)

C7H5 02F

+ C6H4(F)COOH ** 9.91 ±0.2 El 3973

(Benzoic acid, 4-fluoro-)

(RN-CAS Registry Number 456-22-4)

c,h7o2 f+ c6h4foocch3 ** 8.78±0.03 El 3483

(Phenol, 2-fluoro-, acetate)

(RN-CAS Registry Number 29650-44-0)

c»hvo2f

+ C6H4FOOCCH3 ** 8.27±0.03 El 3483

(Phenol, 4-fluoro-, acetate)

(RN-CAS Registry Number 405-51-6)

C6H4OF2+ C6H3F2OOCCH3 CH2 =C=0 9.63 ±0.03 El 3480

(Phenol, 2,4-difluoro-, acetate)

(RN-CAS Registry Number 36914-77-9)

C6H4OF2+ C6H3F2OOCCH3 CH2 =C = 0 9.69 ±0.03 El 3480

(Phenol, 2,6-difluoro-, acetate)

(RN-CAS Registry Number 36914-78-0)

c8 h6o2f2+ c6h3 f2oocch3 ** 8.60±0.03 El 3480

(Phenol, 2,4-difluoro-, acetate)

(RN-CAS Registry Number 36914-77-9)

c,h6o2f,+ C6H3F2OOCCH3 ** 8.88±0.03 El 3480

(Phenol, 2,6-difluoro-, acetate)

(RN-CAS Registry Number 36914-78-0)

C2H3 OF3+ CF3 CH2OH ** 11.7 (V) PE 3941

(RN-CAS Registry Number 75-89-8)

C2H02F3+ CF3 COOH ** 11.46 PE 3718

(RN-CAS Registry Number 76-05-1)

C2H02F3+ CF3 COOH ** 12.00±0.03 (V) PE 3734

(RN-CAS Registry Number 76-05-1)

C2H02F3+ CF3 COOH ** 12.00 (V) PE 3874

(RN-CAS Registry Number 76-05-1)

C3 H3 02F3+ HCOOCH2 CF3 ** 11.31 PE 3718

(RN-CAS Registry Number 32042-38-9)

175
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c4h5o2 f3+ CF3 COOC2 H5 ** (RN-CAS Registry Number 383-63-1)

-11.6 (V) PE 3718

c4 h5o2 f3+ CH3 COOCH2 CF3 ** (RN-CAS Registry Number 406-95-1)

10.84 PE 3718

c5 h5 o2 f3+ CF3 COCH2 COCH3 ** (RN-CAS Registry Number 367-57-7)

9.92±0.07 (V) PE 3682

c6h3 o2 f3+ C4H3 OCOCF3 ** (Ethanone, 2,2,2-trifluoro-l-(2-furanyl)-)

(RN-CAS Registry Number 18207-47-1)

9.77±0.05 El 3482

c8 h„o2 f3+ (CH3)3 CCOCH2 COCF3 ** (RN-CAS Registry Number 22767-90-4)

9.87±0.07 (V) PE 3682

c4h5 o4f3+ (CF3 COOH)(CH3 COOH) ** (RN-CAS Registry Number XXXXX-XX-X)11.1 (V) PE 3734

c5 h7o4f3+ (C2 H5 COOH)(CF3 COOH) ** (RN-CAS Registry Number XXXXX-XX-X)10.9 (V) PE 3734

c6h9o4f3+

(/so-C3 H7COOH)(CF3 COOH) ** (RN-CAS Registry Number XXXXX-XX-X)

10.7 (V) PE 3734

c3 h3of5+ C2 F5 CH2OH ** (RN-CAS Registry Number 422-05-9)11.68 (V) PE 3941

c6hof5+ C6F5 OH ** (Phenol, pentafluoro-)

(RN-CAS Registry Number 771-61-9)

9.20±0.02 PE 3890

c7 h3 of5+ C6F5 OCH3 ** (Benzene, pentafluoromethoxy-)

(RN-CAS Registry Number 389-40-2)

9.10±0.02 PE 3890

c3 h2of6+ CF3 CH(OH)CF3 ** (RN-CAS Registry Number 920-66-1)

12.23 (V) PE 3941

c5 h2o2 f6+ CF3 COCH2COCF3 ** (RN-CAS Registry Number 1522-22-1)

10.74±0.07 (V) PE 3682

^10^2^4^12®e (CF3 COCHCOCF3)2 Be ** 10.39±0.07 (V) PE

(Beryllium, bis(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (T-4)-)

(RN-CAS Registry Number 19648-82-9)

3682

NOF3t

2 E) NOF3 ** (RN-CAS Registry Number 13847-65-9)

(This value probably corresponds to the first vibrationally excited

state of the ion.)

13.36±0.01 PE 3641

NOF^ NOF3 ** (RN-CAS Registry Number 13847-65-9)

14.83±0.06 PE 3641

176
Table of Ion Energetics Measurements—-Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

NOF3* NOF3 ** (RN-CAS Registry Number 13847-65-9)

16.34±0.03 PE 3641

NOF3t

2E) NOF3 ** (RN-CAS Registry Number 13847-65-9)

19.90±0.02 PE 3641

NOF3fA,) NOF3 ** (RN-CAS Registry Number 13847-65-9)

21.1 ±0.1 (V) PE 3641

C2NOF6+

(RD-Radical)

(CF3)2NO

(RN-CAS Registry Number 2154-71-4)

10,7±0.1 (V) PE 3671

C8H8NOF+ C6H4FNHCOCH3 ** (Acetamide, 7V-(2-fluorophenyl)-)

(RN-CAS Registry Number 399-31-5)

8.27+0.03 El 3483

c8h8nof+ C6H4FNHCOCH3 ** (Acetamide, 7V-(4-fluorophenyl)-)

(RN-CAS Registry Number 351-83-7)

8.20+0.03 El 3483

c6h4no2f

+ c6h4fno2 (Benzene, l-fluoro-3-nitro-)

(RN-CAS Registry Number 402-67-5)

9.93+0.1 El 3447

c6h,no2f+ c6h4fno2 ** (Benzene, l-fluoro-4-nitro-)

(RN-CAS Registry Number 350-46-9)

10.00+0.1 El 3447

c8h7nof2+ C6H3 F2NHCOCH3 ** (Acetamide, Ar-(2,4-difluorophenyl)-)

(RN-CAS Registry Number 399-36-0)

8.21+0.03 El 3480

c8h7nof2+ C6H3F2NHCOCH3 ** (Acetamide, iV-(2, 6-difluorophenyl)-)

(RN-CAS Registry Number 3896-29-5)

8.52+0.03 El 3480

QH4NOF3+ C4H4NCOCF3 ** (Ethanone, 2,2,2-trifluoro- 1 -( lif-pyrrol-2-yl)-)

(RN-CAS Registry Number 2557-70-2)

9.18+0.05 El 3482

Ne+

(

2P,/2) Ne ** (RN-CAS Registry Number 7440-01-9)

2 1.56471 ±0.00001 S 3754

Na+ Na ** (RN-CAS Registry Number 7440-23-5)

5.3±0.2 El 3609

Na+ NaF

(RN-CAS Registry Number 7681-49-4)

~12 El 3464

Na2+ Na2 ** (RN-CAS Registry Number 25681-79-2)

<6±2 El 3609

Mg+ (C5 H5)2Mg

(Magnesium, bis(i7

5 -2,4-cyclopentadien- 1 -yl)-)

(RN-CAS Registry Number 1284-72-6)

(ON-Other name: Magnesocene)

1 3.9 ±0.5 RPD 3793

177
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C5 H5 Mg+ (C5 H5 )2 Mg

(Magnesium, bis(T)

5 -2,4-cyclopentadien- 1 -yl)-)

(RN-CAS Registry Number 1284-72-6)

(ON-Other name: Magnesocene)

1 1.0±0.2 RPD 3793

C10H10Mg+ (C5 H5)2 Mg

(Magnesium, bis(7)

5 -2,4-cyclopentadien-l-yl)-)

(RN-CAS Registry Number 1284-72-6)

(ON-Other name: Magnesocene)

8.11 (V) PE 3688

C10H10Mg+ (C5 H5 )2 Mg

(Magnesium, bis(i7

5 -2,4-cyclopentadien-l-yl)-)

(RN-CAS Registry Number 1284-72-6)

(ON-Other name: Magnesocene)

8.0±0.1 RPD 3793

C12 H 14 Mg+ (C5 H4CH3 )2 Mg

(Magnesocene, 1 , 1 '-dimethyl-)

(RN-CAS Registry Number 40672-08-0)

7.78 (V) PE 3688

Al + A1 ** (RN-CAS Registry Number 7429-90-5)

6.6+0.6 El 3440

Al2+ Al2 ** (RN-CAS Registry Number 32752-94-6)5.4±1.0 El 4005

ai2+ Al2 ** (RN-CAS Registry Number 37361-48-1)5.4±1.0 El 4014

Al2+ ai2o

(RN-CAS Registry Number 12004-36-3)

15.2±0.5 El 4005

A1C+ A1C2? (RN-CAS Registry Number 37297-57-7)14.0±1.0 El 4014

A1C2+ A1C2 ** (RN-CAS Registry Number 37297-57-7)

9.3±1.0 El 4014

ai2 c2+ A12C2 (RN-CAS Registry Number 12122-01-9)

8.0±0.5 El 4014

c18 h15ai + (C6H5)3 A1

(Aluminum, triphenyl-)

(RN-CAS-Registry Number 841-76-9)

8.53±0.03 PI 4055

A10 + AlO ** (RN-CAS Registry Number 14457-64-8)

9.5± 1 El 3617

A10+ AlO ** (RN-CAS Registry Number 14457-64-8)

9.53±0.15 El 3816

A10+ AlO ** (RN-CAS Registry Number 14457-64-8)

9±1 El 3463

A10+ AlO ** (RN-CAS Registry Number 14457-64-8)

10± 1 El 3620

A10 + ai2o

(RN-CAS Registry Number 12004-36-3)

15.1±0.3 El 4005

178
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

aio2+ aio2 ** (RN-CAS Registry Number 1 1092-32-3)

10±1 El 3463

aio2+ aio2 ** (RN-CAS Registry Number 1 1092-32-3)

10±1 El 3617

ALO

A1,0

A10F+

A10F+

ai2o ** (RN-CAS Registry Number 12004-36-3)

ai2o ** (RN-CAS Registry Number 12004-36-3)

ai2o ** (RN-CAS Registry Number 12004-36-3)

ai2o ** (RN-CAS Registry Number 12004-36-3)

ai2o ** (RN-CAS Registry Number 12004-36-3)

AlOF ** (RN-CAS Registry Number 13596-12-8)

AlOF ** (RN-CAS Registry Number 13596-12-8)

7.7±0.2 El 4005

7.7±0.5 El 3985

8.20±0.15 El 3816

8.5 ± 1 El 3617

9± 1 El 3620

ai2o2+ ai2o2 ** (RN-CAS Registry Number 12252-63-0)

10±1 El 3617

A1F+ A1F ** (RN-CAS Registry Number 13595-82-9)

9 El 3606

A1F2+ A1F2 ** (RN-CAS Registry Number 13569-23-8)

10 El 3606

10.5 ± 1 El 3462

11 El 3606

A10F2+ A10F2 ** 13 ±1 El 3606

(RN-CAS Registry Number 38344-66-0)

C15H1206F9A1+ (CF3 COCHCOCH3)3Al ** 9.22±0.07 (V) PE 3682

(Aluminum, tris( 1,1,1 -trifluoro-2,4-pentanedionato-0,O')-)

(RN-CAS Registry Number 14354-59-7)

C15H306F18A1+ (CF3COCHCOCF3)3Al ** 10.33 ±0.07 (V) PE 3682

(Aluminum, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-)

(RN-CAS Registry Number 15306-18-0)

Si +

Si ** 8.1 ±0.5 El 3969

(RN-CAS Registry Number 7440-21-3)

Si +

Si ** 8.5±0.5 El 3610

(RN-CAS Registry Number 7440-21-3)

Si + SiH4 13.3 DC 3813

(RN-CAS Registry Number 7803-62-5)

SiH+(X1 2

+

) SiH ** 7.91 D 3564

(RN-CAS Registry Number 13774-94-2)

179
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SiH + SiH4 (RN-CAS Registry Number 7803-62-5)

14.7 DC 3813

SiH2+ SiH4 H2 (RN-CAS Registry Number 7803-62-5)

11.8 DC 3813

SiH2+ SiH4 2H?

(RN-CAS Registry Number 7803-62-5)

16.2 DC 3813

SiH3+ SiH4 H

(RN-CAS Registry Number 7803-62-5)

12.2 DC 3813

SiH^Bj) SiH4 ** (RN-CAS Registry Number 7803-62-5)

11.60 PE 3716

SiH4fA,) SiH4 ** (RN-CAS Registry Number 7803-62-5)

17.95 PE 3716

Si2 H6Te+ (SiH3)2Te

(RN-CAS Registry Number 19415-73-7)

8.63 (V) PE 3656

SiC2+ SiC2 ** (RN-CAS Registry Number 12071-27-1)

10. 1 db0.5 El 4005

SiC2+SiC, ** (RN-CAS Registry Number 12071-27-1)

10.3±0.5 El 3969

Si2C

+

Si2 C ** (RN-CAS Registry Number XXXXX-XX-X)

9.0+0.5 El 4005

Si2 C

+

Si2 C ** (RN-CAS Registry Number XXXXX-XX-X)

9.5±0.5 El 3969

CH3 Si + CH2 =CHSi(CH3)3 (RN-CAS Registry Number 754-05-2) ~ 15 El 3809

CH5 Si + CH2 = CHSi(CH3)3 (RN-CAS Registry Number 754-05-2) ~ 15 El 3809

C2H6Si + 1-C4H8 (RN-CAS Registry Number 7291-09-0)

10.37 (V) PE 3950

C2 H6 Si + CH2 =CHSiH3 ** (RN-CAS Registry Number 7291-09-0)

10.4 (V) PE 3940

C2 H7 Si + CH2 =CHSi(CH3)3 (RN-CAS Registry Number 754-05-2) ~ 13 El 3809

C3 H8 Si + CH2 =CHCH2 SiH3 ** (RN-CAS Registry Number 18191-59-8)

9.49 (V) PE 3950

C3 H8 Si + C3 H8 Si ** (Silacyclobutane)

(RN-CAS Registry Number 287-29-6)

10.05 (V) PE 4077

C3 H8 Si + CH2 =CHSi(CH3)3 C2 H4 (RN-CAS Registry Number 754-05-2)

~10 El 3809

180
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

C3H9Si + (CH3)4Si CH3 (RN-CAS Registry Number 75-76-3)

C3H9Si + CH2 =CHSi(CH3)3 C2H3 (RN-CAS Registry Number 754-05-2)

C3H9Si + (CH3)3 SiSi(CH3)3 (CH3)3 Si (RN-CAS Registry Number 1450-14-2)

C3 H9Si + C6H5 Si2(CH3)5 C6H5 Si(CH3)2 (Disilane, pentamethylphenyl-)

(RN-CAS Registry Number 1130-17-2)

(TR-Other product(s) thermochemically reasonable)

C3H9Si + (C6H5)2SiCH3 Si(CH3)3 (Disilane, 1,1,1 ,2-tetramethyl-2,2-diphenyl-)

(RN-CAS Registry Number 1450-16-4)

(TR-Other product(s) thermochemically reasonable)

(OP-the other product(s) is(are): (C6H5)2SiCH3) C3H9Si + (C6H5 (CH3)2Si)2 (C6H5)2SiCH3 (Disilane, 1, 1,2, 2-tetramethyl- 1,2-diphenyl-)

(RN-CAS Registry Number 1 145-98-8)

(TR-Other produces) thermochemically reasonable)

C3H9Si + (C6H5)3 SiSi(CH3)3 (C6H5)3 Si

(Disilane, 1, 1, 1 -trimethyl-2,2, 2-triphenyl-)

(RN-CAS Registry Number 1450-18-6)

(TR-Other product(s) thermochemically reasonable)

C3H9Si + (CH3)3 SiOSi(CH3)3 (RN-CAS Registry Number 107-46-0)

C3H9Si+ (CH3)3 SiOSi(CH3)2OSi(CH3)3 (RN-CAS Registry Number 107-51-7)

C3H9Si + (CH3)3 SiOSi(CH3)(C2H3)OSi(CH3)3 (RN-CAS Registry Number 5356-85-4)

C3 H9Si + (CH3)3 SiOSi(CH3)(C2H5)OSi(CH3)3 (RN-CAS Registry Number 17861-60-8)

C3H,Si+ (CH3)3 SiGe(CH3)3 (CH3)3Ge

(RN-CAS Registry Number 31608-80-7)

C3H9Si+ (CH3)3 SiSn(CH3)3 (CH3)3 Sn

(RN-CAS Registry Number 16393-88-7)

Ionization or appearance

potential

(eV)

Method Ref.

10.53±0.20 El 3548

~11 El 3809

10.22±0.18 El 3548

10.08 ±0.09 El 3549

10.59±0.03 El 3549

11.04±0.03 El 3549

10.83+0.09 El 3549

15.4±0.2 El 3444

15.8+0.2 El 3444

15.4+0.2 El 3444

15.3±0.2 El 3444

10.19±0.12 El 3548

10.18±0.26 El 3548

C4H9Si + CH2 =CHSi(CH3)3 CH3 (RN-CAS Registry Number 754-05-2)

C4H12 Si + (CH3)4Si ** (RN-CAS Registry Number 75-76-3)

C4H12 Si + (CH3)4Si ** (RN-CAS Registry Number 75-76-3)

C4H12Si +

(

2Aj) (CH3)4Si ** (RN-CAS Registry Number 75-76-3)

C4H12 Si + (CH3)4Si ** (RN-CAS Registry Number 75-76-3)

C5H10Si + (CH3)3 SiC=CH ** (RN-CAS Registry Number 1066-54-2)

~9 El 3809

9.42+0.1 PE 3677

9.79+0.04 PE 3880

15.62 (V) PE 3503

9.85 ±0. 16 El 3548

9.9±0.1 PE 4002

181
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C5 H12 Si + (CH3)3 SiCH =CH2 ** (RN-CAS Registry Number 754-05-2)

9.8 (V) PE 3940

C5 H12 Si + (CH3)3 SiCH = CH2 ** (RN-CAS Registry Number 754-05-2)

9.8 (V) PE 3908

C5 H12 Si + CH2 =CHSi(CH3)3 ** (RN-CAS Registry Number 754-05-2)

9.2 El 3809

C5 H12 Si + C3 H6Si(CH3)2 (Silacyclobutane, 1,1 -dimethyl-)

(RN-CAS Registry Number 2295-12-7)

9.40 (V) PE 4077

C6H8 Si + C6H5 SiH3 (Silane, phenyl-)

(RN-CAS Registry Number 694-53-1)

9.09 PE 3868

C6H8 Si + C6H5 SiH3 (Silane, phenyl-)

(RN-CAS Registry Number 694-53-1)

9.25 PE 3922

C6H12 Si + (C2H3)2 Si(CH3)2 (RN-CAS Registry Number 10519-87-6)9.8 (V) PE 3994

C6H14 Si + (CH3 )3 SiCH2CH=CH2 ** (RN-CAS Registry Number 762-72-1)9.0 (V) PE 390! C6H14Si + (CH3 )3 SiCH2 CH=CH2 ** (RN-CAS Registry Number 762-72-1)

9.0 (V) PE 3940

C6H14 Si + C3 H5 Si(CH3)3 (Silacyclobutane, 1, 1,2-trimethyl-)

(RN-CAS Registry Number 30681-90-4)

9.20 (V) PE 4077

C6H14Si + C4H8 Si(CH3)2 (Silacyclopentane, 1 , 1 -dimethyl-)

(RN-CAS Registry Number 1072-54-4)

9.75 (V) PE 4077

Cg Hn Si + C6H5 Si(CH3)2H H

(Silane, dimethylphenyl-)

(RN-CAS Registry Number 766-77-8)

(TR-Other product(s) thermochemically reasonable)

C8 Hn Si + C6H5 Si(CH3)3 CH3 (Silane, trimethylphenyl-)

(RN-CAS Registry Number 768-32-1)

(TR-Other product(s) thermochemically reasonable)

C8 H„Si + C6H5 Si2(CH3)5 Si(CH3)3 (Disilane, pentamethylphenyl-)

(RN-CAS Registry Number 1130-17-2)

(TR-Other product(s) thermochemically reasonable)

C8 Hn

Si + (C6H5 ) 2 SiCH3 Si(CH3)3 C6H5 Si(CH3)2 (Disilane, 1,1, 1 ,2-tetramethyl-2,2-diphenyl-)

(RN-CAS Registry Number 1450-16-4)

(TR-Other product(s) thermochemically reasonable)

C8 Hn Si + (C6H5(CH3)2 Si)2 C6H5 Si(CH3)2 (Disilane, 1 , 1 ,2,2-tetramethyl- 1 ,2-diphenyl-)

(RN-CAS Registry Number 1145-98-8)

(TR-Other product(s) thermochemically reasonable)

10.43±0.04

10.26±0.03

9.86±0.06

9.75±0.04

9.87±0.08

El

El

El

El

El

3549

3549

3549

3549

3549

182
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C8H„Si+ (C6H5)3 SiSi(CH3)3 (C6H5)2 SiCH3 (Disilane, 1,1, 1 -trimethyl-2,2, 2-triphenyl-)

(RN-CAS Registry Number 1450-18-6)

(TR-Other product(s) thermochemically reasonable)

10. 13 ±0.03 El 3549

CsHl2 Si + (C2H3)4Si (RN-CAS Registry Number 1112-55-6)

9.7 (V) PE 3994

C8H,2Si + C6H5 Si(CH3)2H

(Silane, dimethylphenyl-)

(RN-CAS Registry Number 766-77-8)

8.92±0.15 El 3549

C9H14Si + C6H5 Si(CH3)3 (Silane, trimethylphenyl-)

(RN-CAS Registry Number 768-32-1)

8.81+0.15 El 3549

C9H14Si+ C6H5 Si(CH3)3 (Silane, trimethylphenyl-)

(RN-CAS Registry Number 768-32-1)

8.79 CTS 3922

CioHioSi + C10H7 SiH3 (Silane, 1-naphthalenyl-)

(RN-CAS Registry Number 38274-75-8)

8.12 CTS 3922

C10H14Si + C8H8 Si(CH3)2 ( 1 -Silaindan, 1 , 1 -dimethyl-)

(RN-CAS Registry Number 17158-48-4)

8.54 CTS 3546

C10H14Si + C8H8 Si(CH3)2

( 1/7-2-Silaindene, 2,3-dihydro-2,2-dimethyl-)

(RN-CAS Registry Number 2764-87-6)

8.41 CTS 3546

CioH16Si + C6H5CH2Si(CH3)3 (Silane, trimethyl(phenylmethyl)-)

(RN-CAS Registry Number 770-09-2)

8.27 CTS 3922

C10H16Si + C6H5CH2 Si(CH3)3 (Silane, trimethyl(phenylmethyl)-)

(RN-CAS Registry Number 770-09-2)

8.37 CTS 3546

C„H16Si + C6H5 CH=CHSi(CH3)3 **

(Silane, trimethyl(2-phenylethenyl)-, (E)-)

(RN-CAS Registry Number 19372-00-0)

7. 89 ±0.04 RPD 4097

C„H16Si + C6H5CH=CHSi(CH3)3 **

(Silane, trimethyl(2-phenylethenyl)-, (Z)-)

(RN-CAS Registry Number 19319-11-0)

8. 19 ±0.04 RPD 4097

C„H16Si + C6H5C(Si(CH3)3) =CH2 (Silane, trimethyl( 1 -phenylethenyl)-)

(RN-CAS Registry Number 1923-01-9)

8.23 ±0.04 RPD 4097

C12H16Si + C9H7Si(CH3)3 (Silane, 1/f-inden-l-yltrimethyl-))

(RN-CAS Registry Number 18053-75-3)

7.65±0.01 El 3805

183
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c12 h18 Si + C9H9 Si(CH3 )3 (Silane, (2,3-dihydro-l//-inden-l-yl)trimethyl-)

(RN-CAS Registry Number 18036-88-9)

7.87±0.01 El 3805

c12 h oo C9H9 Si(CH3)3 (Silane, 1-indanyltrimethyl-)

(RN-CAS Registry Number 18036-88-9)

8.13 CTS 3546

c12 h oo CA C6 H5 CH = CHCH2 Si(CH3)3 **

(Silane, trimethyl(3-phenyl-2-propenyl)-, (E)-)

(RN-CAS Registry Number 40595-34-4)

7.61 ±0.04 RPD 4097

c12 hi 8 Si + C6H5 CH= CHCH2 Si(CH3)3 **

(Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)-)

(RN-CAS Registry Number 40595-35-5)

7.77±0.04 RPD 4097

C13 H13 Si + (C6H5) 2 Si(CH3)H H

(Silane, methyldiphenyl-)

(RN-CAS Registry Number 776-76-1)

C13 H13 Si + (C6H5 )2SiCH3 Si(CH3)3 (CH3)3 Si (Disilane, 1,1,1 ,2-tetramethyl-2,2-diphenyl-)

(RN-CAS Registry Number 1450-16-4)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

C13 H13 Si + (C6H5 (CH3)2Si)2 (CH3)3 Si (Disilane, 1 , 1 ,2,2-tetramethyl- 1 ,2-diphenyl-)

(RN-CAS Registry Number 1145-98-8)

(TR-Other product(s) thermochemically reasonable)

CI3 H13 Si +((C6H5)2CH3 Si)2 (C6H5)2SiCH3 (Disilane, 1 ,2-dimethyl- 1

, 1 ,2,2-tetraphenyl-)

(RN-CAS Registry Number 1172-76-5)

(TR-Other product(s) thermochemically reasonable)

C13 H14Si + (C6H5)2 Si(CH3)H

(Silane, methyldiphenyl-)

(RN-CAS Registry Number 776-76-1)

8.75±0.15 El 3549

C13 H16 Si + C10H7 Si(CH3)3 (Silane, trimethyl- 1 -naphthalenyl-)

(RN-CAS Registry Number 18052-80-7)

8.03 CTS 3758

C14 H14 Si + C12 H8 Si(CH3)2 (5//-Dibenzosilole, 5,5-dimethyl-)

(RN-CAS Registry Number 13688-68-1)

7.9 (V) PE 4081

C14H18 Si + C10H7CH2Si(CH3)3 (Silane, trimethyl( 1 -naphthalenylmethyl)-)

(RN-CAS Registry Number 18410-58-7)

7.83 CTS 3922

C14H18 Si + C10H7 CH2 Si(CH3)3 (Silane, trimethyl( 1 -naphthalenylmethyl)-)

(RN-CAS Registry Number 18410-58-7)

7.83 CTS 3758

10.97±0.12 El 3549

9.63 ±0.02 El 3549

9.60±0.02 El 3549

9.51 ±0.05 El 3549

184
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C17H18Si + C9H7 Si(CH3)2C6H5 (Silane, llT-inden- 1 -yldimethylphenyl-)

(RN-CAS Registry Number 27490-90-0)

7.69±0.04 El 3805

C17H20Si + C9H9 Si(CH3)2C6H5 ** 7.94 ±0.01

(Silane, (2, 3-dihydro- 177-inden- 1 -yl)dimethylphenyl-)

(RN-CAS Registry Number 41273-54-5)

El 3805

C18 H15 Si + (C6H5)3 SiH H

(Silane, triphenyl-)

(RN-CAS Registry Number 789-25-3)

(TR-Other product(s) thermochemically reasonable)

C18H15 Si + (C6H5)4Si C6H5 (Silane, tetraphenyl-)

(RN-CAS-Registry Number 1048-08-4)

CigH15 Si + (C6H5)4Si C6H5 (Silane, tetraphenyl-)

(RN-CAS Registry Number 1048-08-4)

(TR-Other product(s) thermochemically reasonable)

C18H15 Si + (C6H5)3 SiSi(CH3)3 (CH3)3 Si (Disilane, 1, 1, l-trimethyl-2,2, 2-triphenyl-)

(RN-CAS Registry Number 1450-18-6)

(TR-Other product(s) thermochemically reasonable)

C18 H15 Si +((C6H5)2CH3 Si)2 C6H5 Si(CH3)2 (Disilane, 1 ,2-dimethyl- 1

, 1 ,2,2-tetraphenyl-)

(RN-CAS Registry Number 1172-76-5)

(TR-Other product(s) thermochemically reasonable)

C18 H15 Si +

((C6H5)3 Si)2 (C6H5)3 Si (Disilane, hexaphenyl-)

(RN-CAS Registry Number 1450-23-3)

(TR-Other product(s) thermochemically reasonable)

C18H16Si + (C6H5)3 SiH

(Silane, triphenyl-)

(RN-CAS Registry Number 789-25-3)

8.80±0.15 El 3549

C22H-2oSi + C10H7Si(CH3)2C10H7 (Silane, dimethy1—di— 1 -naphthalenyl-)

(RN-CAS Registry Number 18753-19-0)

8.03 CTS 3758

C24H16Si +

^24^16^1 **

(5,5 '-Spirobi[5i/-dibenzosilole])

(RN-CAS Registry Number 159-68-2)

7.85 (V) PE 4081

C24H2oSi + (C6H5)4Si

(Silane, tetraphenyl-)

(RN-CAS-Registry Number 1048-08-4)

8.50±0.03 PI 4055

^24^20^1 + (C6H5)4Si (Silane, tetraphenyl-)

(RN-CAS Registry Number 1048-08-4)

8.65 ±0. 1

5

El 3549

9.58±0.08 El 3549

9.7 PI 4055

9.93±0.08 El 3549

9.35±0.03 El 3549

9.35±0.03 El 3549

9.61 ±0.09 El 3549

185
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C6H18 Si2+ (CH3)3 SiSi(CH3)3 (RN-CAS Registry Number 1450-14-2)8.69 (V) PE 3504

C6H18 Si2+ (CH3 ) 3 SiSi(CH3)3 (RN-CAS Registry Number 1450-14-2)

8.35 ±0. 1

El 3548

C6H18 Si2+ (CH3 )3 SiSi(CH3)3 (RN-CAS Registry Number 1450-14-2)

8.46±0.15 El 3549

CnH20Si^ C6H5 Si2(CH3 )5 (Disilane, pentamethylphenyl-)

(RN-CAS Registry Number 1130-17-2)

8.35 (V) PE 3946

iH20Si^ C6H5 Si2 (CH3)5 (Disilane, pentamethylphenyl-)

(RN-CAS Registry Number 1130-17-2)

8.35±0.15 El 3549

CnH20Si^ C6H5 Si2(CH3 )5 (Disilane, pentamethylphenyl-)

(RN-CAS Registry Number 1130-17-2)

8.37 CTS 3946

C8 H8 Si(CH3)Si(CH3)3 (2-Silaindan, 2-methyl-2-(trimethylsilyl)-)

(RN-CAS Registry Number 27490-20-6)

8.37 CTS 3546

Ci2H22Si^ C6H5 CH2 Si2 (CH3)5 (Disilane, pentamethyl(phenylmethyl)-)

(RN-CAS Registry Number 3098-82-6)

8.27 CTS 3546

Ci 3 H22Si^ C6H5 CH= CHSi2(CH3)5 **

(Disilane, pentamethyl(2-phenylethenyl)-, (E)-)

(RN-CAS Registry Number 40595-36-6)

7.73±0.04 RPD 4097

C14H24Si^ C9H9Si2(CH3)5 (Disilane, 1 -indanylpentamethyl-)

(RN-CAS Registry Number 27490-23-9)

8.07 CTS 3546

C14H24Si2+ C6H5 CH= C(Si(CH3)3)2 (Silane, (phenylethenylidene)bis[trimethyl-)

(RN-CAS Registry Number 18415-23-1)

8.12±0.04 RPD 4097

C15 H22Si^ C10H7 Si2 (CH3)5 (Disilane, pentamethyl- 1-naphthalenyl-)

(RN-CAS Registry Number 38446-40-1)

7.95 CTS 3758

C15 H24Si2+ C9H6(Si(CH3)3)2 (Silane, l//-indene- 1 ,2-diylbis[trimethyl-)

(RN-CAS Registry Number 26205-36-7)

7.54±0.01 El 3805

C16H22Si2+ (C6H5)2 SiCH3 Si(CH3)3 (Disilane, 1,1,1 ,2-tetramethyl-2,2-diphenyl-)

(RN-CAS Registry Number 1450-16-4)

8.38 ±0. 1

5

El 3549

^i6H22Si^ (C6H5 (CH3)2 Si)2 (Disilane, 1 , 1 ,2,2-tetramethyl- 1 ,2-diphenyl-)

(RN-CAS Registry Number 1145-98-8)

8.1 1 ±0. 1

5

El 3549

186
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C2 iH24Si2

1' (C6H5)3 SiSi(CH3)3 (Disilane, 1, 1, 1 -trimethyl-2,2, 2-triphenyl-)

(RN-CAS Registry Number 1450-18-6)

8.30±0.15 El 3549

C10H7(Si(CH3)2)2C10H7 ** 7.91

(Disilane, 1 , 1 ,2,2-tetramethyl- 1 ,2-di- 1 -naphthalenyl-)

(RN-CAS Registry Number 38446-41-2)

CTS 3758

^26^26^2* ((C6H5)2CH3 Si)2 (Disilane, 1 ,2-dimethyl- 1

, 1 ,2,2-tetraphenyl-)

(RN-CAS Registry Number 1172-76-5)

8.05±0.15 El 3549

C36H30Si^ ((C6H5)3 Si)2 (Disilane, hexaphenyl-)

(RN-CAS Registry Number 1450-23-3)

8.16+0.15 El 3549

C8H24Si3

" Si3 (CH3)8 (RN-CAS Registry Number 3704-44-7)

8.19 (V) PE 3504

C17H28Si3+ C10H7 Si3 (CH3)7 ** 7.93 CTS 3758

(Trisilane, 1,1, 1 ,2,2, 3, 3-heptamethyl-3-( 1 -naphthalenyl)-)

(RN-CAS Registry Number 38446-42-3)

C17H28Si3+ C10H7 Si(Si(CH3)3)2CH3 ** 7.85 CTS 3758

(Trisilane, 1, 1, l,2,3,3,3-heptamethyl-2-)(-naphthalenyl)-)

(RN-CAS Registry Number 38446-43-4)

C26H32Si3+ C10H7(Si(CH3)2)3 C10H7 ** 7.92 (Trisilane, 1 , 1

, 2, 2, 3 , 3-hexamthy1- 1 , 3-di- 1 -naphthalenyl-)

(RN-CAS Registry Number 38580-43-7)

CTS 3758

C6H16Si4+ C6H16Si4

( 1 , 3 , 5 ,7-Tetrasilatricyclo[3 .3.1.1

3,7]decane)

(RN-CAS Registry Number 281-44-7)

(ON-Other name: 1,3,5,7-Tetrasilaadamantane)

9.0+0.05 PE 3855

C6H16Si4+ C6H16Si4

( 1 ,3,5,7-Tetrasilatricyclo[3. 3 .1.1

3,7]decane)

(RN-CAS Registry Number 281-44-7)

(ON-Other name: Silamantane)

9.7 (V) PE 4000

CioH^Si^ C6H12 Si4(CH3)4 ** 8.45 ±0.05

(l,3,5,7-Tetrasilatricyclo[3.3.1.1 3 ’ 7]decane, 1,3,5,7-tetramethyl)-)

(RN-CAS Registry Number 17995-33-4)

(ON-Other name: 1 , 3 , 5, 7-Tetramethy1- 1 , 3, 5 , 7-tetrasilaadamantane)

PE 3855

CioH30Si^ «-Si4(CH3) 10 (RN-CAS Registry Number 865-76-9)

7.98 (V) PE 3504

CioH30Si^ Si5(CH3) 10 (Cyclopentasilane, decamethyl-)

(RN-CAS Registry Number 13452-92-1)

7.94 (V) PE 3504

187
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C, 2 H36Si5+ Si(Si(CH3)3)4 (RN-CAS Registry Number 4098-98-0)8.24 (V) PE 3504

C12 H36Si6+

Si6(CH3 ) 12 (Cyclohexasilane, dodecamethyl-)

(RN-CAS Registry Number 4098-30-0)

7.79 (V) PE 3504

Ci6H36Si^ C10H18 Si7(CH3 )6 ** 7.9±0.05 PE

(2H- 1 , 5 : 8, 1 2-Dimethano-3,6a, 1 0-metheno- 1

, 3, 5 , 6a, 8, 1 0, 1 2-heptasilaoctalene, dodecahydro- 1

,

3,5,8, 10, 12-hexamethyl-)

(RN-CAS Registry Number 26393-20-4)

(ON-Other name: Carborundane)

3855

Si2 N

+

Si2N ** (RN-CAS Registry Number XXXXX-XX-X)

9.5±0.5 El 3810

SiH3 N3t

2 A") SiH3 N3 ** (RN-CAS Registry Number 13847-60-4)

10.33 ±0.02 (V) PE 3670

Si3 H9 N

+ (SiH3 )3 N

(RN-CAS Registry Number 13862-16-3)

9.7 ±0.1 (V) PE 3661

C2 H9NSi + (CH3)2 NSiH3 ** (RN-CAS Registry Number 2875-98-1)

8.5 ±0.1 (V) PE 3661

C8 H13 NSi + C5 H4NS(CH3)3 **

(Pyridine, 2-(trimethylsilyl)-)

(RN-CAS Registry Number 13737-04-7)

8. 90 ±0.05 (V) PE 3685

C8 H13 NSi + C5 H4NS(CH3 )3 (Pyridine, 4-(trimethylsilyl)-)

(RN-CAS Registry Number 18301-46-7)

9.30±0.05 (V) PE 3685

C3 H9N3 Si + (CH3 )3 SiN3 (RN-CAS Registry Number 4648-54-8)

9.7±0.1 (V) PE 3670

C8 H24N4Si + ((CH3)2N)4Si (RN-CAS Registry Number 1624-01-7)

8.39 (V) PE 3503

CH9NSi2+ (SiH3 )2 NCH3 ** (RN-CAS Registry Number 4459-06-7)

9.2±0.1 (V) PE 3661

C„H21 NSi2+ C5 H3 N(S(CH3)3)2 (Pyridine, 2,5-bis(trimethylsilyl)-)

(RN-CAS Registry Number 35505-51-2)

8.65 ±0.05 (V) PE 3685

C„H21 NSi2+ C5 H3 N(S(CH3)3)2 (Pyridine, 2,6-bis(trimethylsilyl)-)

(RN-CAS Registry Number 35505-52-3)

8.50±0.05 (V) PE 3685

SiO + SiO ** (RN-CAS Registry Number 10097-28-6)

10.2±0.5 El 3985

SiO + SiO **

1 1 .3 ±0.3 El 4005

(RN-CAS Registry Number 10097-28-6)

188
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

SiO+

SiO +

SiO ** (RN-CAS Registry Number 10097-28-6)

SiO ** (RN-CAS Registry Number 10097-28-6)

11.3±0.5

11.5+0.3

El

El

3810

3610

Si2H60

+

(

2B,) (SiH3)20

(RN-CAS Registry Number 13597-73-4)

11.17 (V) PE 3656

Si2H60

+ (SiH3)zO

(RN-CAS Registry Number 13597-73-4)

11.19 (V) PE 3844

CH6OSi+ CH3OSiH3 ** (RN-CAS Registry Number 2171-96-2)

10.61 (V) PE 3844

C3H9SiO+ (CH3)3 SiOSi(CH3)3 (RN-CAS Registry Number 107-46-0)

21.8+0.2 El 3444

C3H9SiO+ (CH3)3 SiOSi(CH3)2OSi(CH3)3 (RN-CAS Registry Number 107-51-7)

21.8+0.2 El 3444

C3H9SiO+ (CH3)3 SiOSi(CH3)(C2H3)OSi(CH3)3 (RN-CAS Registry Number 5356-85-4)

23.6+0.2 El 3444

C3H9SiO+ (CH3)3 SiOSi(CH3)(C2H5)OSi(CH3)3 (RN-CAS Registry Number 17861-60-8)

21.8+0.2 El 3444

C10Hl6OSi +

r

C6H4(OCH3)Si(CH3)3 (Silane, (4-methoxyphenyl)trimethyl-)

(RN-CAS Registry Number 877-68-9)

8.03 CTS 3758

C13H18OSi+ C9H7Si(CH3)2OC2H5 **

(Silane, ethoxy- 1/7-inden- 1 -yldimethyl-)

(RN-CAS Registry Number 41273-57-8)

7.63+0.01 El 3805

^-'13^20®Si + C9H9Si(CH3)2OC2H5 ** 7.81 ±0.01

(Silane, (2, 3-dihydro- 1/f-inden- 1 -yl)ethoxydimethyl-)

(RN-CAS Registry Number 41273-53-4)

El 3805

C5 H1202 Si + C3 H6Si(OCH3)2 (Silacyclobutane, 1 , 1 -dimethoxy-)

(RN-CAS Registry Number 33446-84-3)

10.15 (V) PE 4077

C8 H20O4Si + (C^O^Si

(RN-CAS Registry Number 78-10-4)

9.77 (V) PE 3503

C,2H220Si2+ C6H4(OCH3)Si2(CH3)5 (Disilane, (4-methoxphenyl)pentametyl-)

(RN-CAS Registry Number 4199-03-5)

7.85 CTS 3758

Si2NO+

Si2NO ** (RN-CAS Registry Number 12033-47-5)10.8+0.5 El 3810

CH3NOSi+ SiH3NCO ** (RN-CAS Registry Number 13730-13-7)

11.10+0.02 (V) PE 3670

189
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref.

products potential

(eV)

C4H9NOSi+ (CH3 ) 3 SiNCO ** 10.3±0.1 (V) PE 3670

(RN-CAS Registry Number 1118-02-1)

SiF4t

2T,) SiF4 ** 16.46 ±0.04 (V) PE 3880

(RN-CAS Registry Number 7783-61-1)

SiF4t

2T2 ) SiF4 ** 1 7.55 ±0.04 (V) PE 3880

(RN-CAS Registry Number 7783-61-1)

SiF4t

2 A,) SiF4 ** 1 8.09 ±0.04 (V) PE 3880

(RN-CAS Registry Number 7783-61-1)

SiF4t

2 E) SiF4 ** 19.51 ±0.04 (V) PE 3880

(RN-CAS Registry Number 7783-61-1)

Si2 F6+Si2 F6 ** 13.20±0.02 (V) PE 4026

(RN-CAS Registry Number 13830-68-7)

SiH3 F

+

(

2 E) SiH3 F ** 12.58 (V) PE 3511

(RN-CAS Registry Number 13537-33-2)

SiH3 F

+

(

2 E) SiH3 F

** 12.6±0.1 (V) PE 3510

SiH3 F

+

(

2A,)

(RN-CAS Registry Number 13537-33-2)

SiH3 F ** ~16(V) PE 3510

(RN-CAS Registry Number 13537-33-2)

SiH3 F

+ SiH3 F ** 16.1 ±0.1 (V) PE 3502

SiH3 F

+

(

2A|)

(RN-CAS Registry Number 13537-33-2)

SiH3 F ** ~ 16.13 (V) PE 3511

SiH3 F

+

(

2E)

(RN-CAS Registry Number 13537-33-2)

SiH3 F ** 16.2±0.1 (V) PE 3510

(RN-CAS Registry Number 13537-33-2)

SiH3 F

+

(

2 E) SiH3 F ** ~ 16.58 (V) PE 3511

SiH3 F

+

(

2 A|)

(RN-CAS Registry Number 13537-33-2)

SiH3 F ** 19.29 (V) PE 3511

(RN-CAS Registry Number 13537-33-2)

SiH2 F2t

2 B,) SiH2 F2 ** 12.85 (V) PE 3511

SiH2 F2t

2B,)

(RN-CAS Registry Number 13824-36-7)

SiH2F2 * 12.85 (V) PE 3694

SiH2 F2t

2 B,)

(RN-CAS Registry Number 13824-36-7)

SiH2F2 ** 12.9±0.1 (V) PE 3510

SiH2 F2fA,)

(RN-CAS Registry Number 13824-36-7)

SiH2F2 ** 15.20 (V) PE 3511

SiH2 F2t

2 A,)

(RN-CAS Registry Number 13824-36-7)

SiH2 F2 ** 15.20 (V) PE 3694

SiH2 F2t

2 B2) (RN-CAS Registry Number 13824-36-7)

SiH2 F2 ** 16.07 (V) PE 3511

SiH2 F2fB2) (RN-CAS Registry Number 13824-36-7)SiH2F2 ** 16.07 (V) PE 3694

SiH2F2t

2Aj)

(RN-CAS Registry Number 13824-36-7)

SiH2F2 ** 16.37 (V) PE 3511

S,H2 F2t

2 A2) (RN-CAS Registry Number 13824-36-7)

SiH2F2 ** 16.37 (V) PE 3694

SiH2 F2t

2B,)

(RN-CAS Registry Number 13824-36-7)

SiH2F2 ** 17.60 (V) PE 3511

(RN-CAS Registry Number 13824-36-7)

190
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SiH2F2t

2Bj) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

17.60 (V) PE 3694

SiH2F2t

2A!) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

17.93 (V) PE 3511

SiH2F2t

2B2) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

17.93 (V) PE 3694

SiH2F2fB,) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

18.30 (V) PE 3511

SiH2F2fA,) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

18.30 (V) PE 3694

SiH2F2fA,) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

20.19 (V) PE 3511

SiH2F2t

2A!) SiH2F2 ** (RN-CAS Registry Number 13824-36-7)

20.19 (V) PE 3694

SiHFjfA,) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

14.48+0.02 (V) PE 4026

SiHF3t

2A2) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

15.94+0.02 (V) PE 4026

SiHF3t

2E) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

16.38±0.02 (V) PE 4026

SiHF3t

2E) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

17.24+0.02 (V) PE 4026

SiHFjfA,) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

18.20±0.02 (V) PE 4026

SiHF3t

2E) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

18.61±0.02 (V) PE 4026

SiHFjfA,) SiHF3 ** (RN-CAS Registry Number 13465-71-9)

20.94+0.02 (V) PE 4026

SiF3C

+

(

2A,) SiF3Cl ** (RN-CAS Registry Number 14049-36-6)

20. 86 ±0.02 (V) PE 4026

C5HgSiF+ (CH3)3 SiC=CF ** (RN-CAS Registry Number 38346-22-4)

9.8±0.1 PE 4002

CH3F3 Si+ CH3 SiF3 ** (RN-CAS Registry Number 373-74-0)

13.24±0.02 (V) PE 4026

C,H10F6Si + c£s-(CH3)3 SiC(CF3) = C(CF3)H * * (RN-CAS Registry Number 35186-03-9)

9.86 PE 3589

C6H12F4Si4+ C6H12Si4F4 ** 9.8±0.05

(l,3,5,7-Tetrasilatricyclo[3.3. 1. l

3,7]decane, 1,3,5,7-tetrafluoro-)

(RN-CAS Registry Number 33664-21-0)

(ON-Other name: l,3,5,7-Tetrafluoro-l,3,5,7-tetrasilaadamantane)

PE 3855

SiAl +

SiAl ** (RN-CAS Registry Number 12042-55-6)

6.5+ 1.0 El 4005

SiA10+ SiAlO ** 6.3±1.0 El 4005

(RN-CAS Registry Number 37361-47-0)

191
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SiA10 + AlSiO ** (RN-CAS Registry Number 37361-47-0)

8.0± 1 El 3985

P

+ P2(RN-CAS Registry Number 12185-09-0)

15.9 El 3472

P

+ PH3 H2 + H

(RN-CAS Registry Number 7803-51-2)

16.3 DC 3811

P

+ PC13 C12 + C1

(RN-CAS Registry Number 7719-12-2)

(TR-Other product(s) thermochemically reasonable)

18.5±0.7 EDD 3556

P

+ PBr3 Br2 + Br

(RN-CAS Registry Number 7789-60-8)

(TR-Other product(s) thermochemically reasonable)

16.7±0.7 EDD 3556

P+ p2 ** (RN-CAS Registry Number 12185-09-0)

(RS-Average of two Rydberg series limits)

10.7±0.1 S 3567

p2fnj P2 ** (RN-CAS Registry Number 12185-09-0)

10.60 PE 3695

P2t

: 2e

) P2(RN-CAS Registry Number 12185-09-0)

10.84 (V) PE 3695

P2+ P2(RN-CAS Registry Number 12185-09-0)

9.7±0.5 El 3458

P2+ P2 ** (RN-CAS Registry Number 12185-09-0)

9.7 El 4001

P2+ P2 ** (RN-CAS Registry Number 12185-09-0)11.2 El 3472

P2+ P2(RN-CAS Registry Number 12185-09-0)11.4±0.5 El 4098

P2+ P2(RN-CAS Registry Number 12185-09-0)

1 1.8+0.5 El 3555

P4+ P4 ** (RN-CAS Registry Number 12185-10-3)

9.10±0.05 PE 3683

P4t

2E) P4 ** (RN-CAS Registry Number 12185-10-3)

9.2 PE 3643

PjfTj) P4(RN-CAS Registry Number 12185-10-3)

10.2 PE 3643

P4t

2 A,) P4 ** (RN-CAS Registry Number 12185-10-3)

11.80+0.07 PE 3643

pJ

2t2) P4(RN-CAS Registry Number 12185-10-3)

-14.2 PE 3643

p4+ P4 ** (RN-CAS Registry Number 12185-10-3)

10.0+0.5 El 4098

p; rP **

4(RN-CAS Registry Number 12185-10-3)

10.8+0.3 El 3555

PH+ ph3 h2 (RN-CAS Registry Number 7803-51-2)

12.9 DC 3811

192
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

PH+ ph3 H 13.4 DC 3811

(RN-CAS Registry Number 7803-51-2)

PHafA,)

PHafA.)

PH3t

2E)

PH3t

2E)

PH3t

2A,)

CHP+(x2n)

CHP+(A22)

ph3 ** (RN-CAS Registry Number 7803-51-2)

ph3 ** (RN-CAS Registry Number 7803-51-2)

PH3 ** (RN-CAS Registry Number 7803-51-2)

PH3 ** (RN-CAS Registry Number 7803-51-2)

PH3 ** (RN-CAS Registry Number 7803-51-2)

PH3 ** (RN-CAS Registry Number 7803-51-2)

9.96±0.01

9.96

12.40±0.02

12.64±0.02

19.0 (V)

10.0

HCP ** (RN-CAS Registry Number 6829-52-3)

HCP ** (RN-CAS Registry Number 6829-52-3)

10.79±0.01

12.86+0.01

PE

PE

PE

PE

PE

DC

PE

PE

3703

3719

3703

3719

3719

3811

BP+ BP ** (RN-CAS Registry Number 20205-91-8)

<13+2 El 3619

PC+ PC ** (RN-CAS Registry Number 12326-85-1)

10.5±0.5 El 3458

C^P* QP ** (RN-CAS Registry Number 12602-39-0)

10.9±0.5 El 3458

CP2+ CP2 ** (RN-CAS Registry Number 12601-93-3)

9.4+0.5 El 3458

3840

3840

ch5p

+ ch3ph2 ** (RN-CAS Registry Number 593-54-4)

9.6±0.1 (V) PE 3661

c3h<>p + (CH3)3P

(RN-CAS Registry Number 594-09-2)

8.6±0.1 (V) PE 3661

C4HuP

+ (C2H5)2PH

(RN-CAS Registry Number 627-49-6)

8.69 PE 3589

c5h5p

+ c5h5p ** (Phosphorin)

(RN-CAS Registry Number 289-68-9)

9.2 (V) PE 3832

C10H,P+ c6h5c4h4p

(li/-Phosphole, 1 -phenyl-)

(RN-CAS Registry Number 20342-00-1)

8.45 (V) PE 4090

193
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c10h13 p

+ c6 h5 c4h8 p

(Phospholane, 1 -phenyl-)

(RN-CAS Registry Number 3302-87-2)

8.35 (V) PE 4090

c12 h13 p+ C6H5 C4H2 P(CH3)2 (l//-Phosphole, 2,5-dimethyl-l-phenyl-)

(RN-CAS Registry Number 13904-58-0)

8.0 (V) PE 4090

c12 hI7 p

+ C6H5 C4H6P(CH3)2 (Phospholane, 2, 5-dimethyl- 1 -phenyl-)

(RN-CAS Registry Number 40358-68-7)

8.35 (V) PE 4090

C, 5 Hn P

+ c9h6pc6h5 (Phosphinoline, 2-phenyl-)

(RN-CAS-Registry Number 39768-04-2)

7.65 PE 4066

c17 h29p

+ C5 H2 P(C(CH3)3)3 (Phosphorin, 2,4,6-tris( 1 , 1 -dimethylethyl)-)

(RN-CAS Registry Number 17420-29-0)

8.0 (V) PE 3934

c19h13 p

+ C13 H8 PC6H5 (Acridophosphine, 10-phenyl-)

(RN-CAS Registry Number 20995-81-7)

7.25 (V) PE 3896

c29h25 p

+ C9H6P(C6H5)(CH2C6H5)2 ** 6.00 (Phosphinoline, 1 , 1 -dihydro-2-phenyl- 1

, 1 -bis(phenylmethyl)-)

(RN-CAS-Registry Number 39767-95-8)

PE 4066

c6h18 n3 p

+ ((CH3)2N)3 P

(RN-CAS Registry Number 1608-26-0)

7.61 (V) PE 3825

c6h18 n3 p

+ (((CH3)2 N)3 P)2Mo(CO)4 (RN-CAS Registry Number 27342-90-1)

10.1 ±0.05 El 3952

c8 h18 n3 p

+ (((CH3)2N)3 P)2 Mo(CO)4 (RN-CAS Registry Number 27342-90-1)

10.1 ±0.05 El 3952

PO+ PO ** (RN-CAS Registry Number 14452-66-5)

8.231 S 3762

PO+ PO ** (RN-CAS Registry Number 14452-66-5)

8.38 S 3560

PO+ PO ** (RN-CAS Registry Number 14452-66-5)

8.5 ± 1 El 3819

PO+ PO ** (RN-CAS Registry Number 14452-66-5)

9.5±0.5 El 4098

PO+ p2o3 (RN-CAS Registry Number 1314-24-5)

1 3.5 ± 1.0 El 4098

PO+ (CH3 0)3 P0 0+ CH30+ 2H

(RN-CAS Registry Number 512-56-1)

18.90±0.50 El 3989

po2+ po2 ** 10.5± 1 El 3819

(RN-CAS Registry Number 12164-97-5)

194
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

po2+

po2+

po2 ** (RN-CAS Registry Number 12164-97-5)

p2o3 (RN-CAS Registry Number 1314-24-5)

11.5±0.5

15.4±1.0

El

El

4098

4098

p2o3+ p2o3 (RN-CAS Registry Number 1314-24-5)

10.4±0.5 El 4098

p2o4+ p2o4 (RN-CAS Registry Number XXXXX-XX-X)

10.8+1.0 El 4098

p2o5+ p2o5 (RN-CAS Registry Number 1314-56-3)

12.0+1.0 El

i 4098

p3o6+ p3o6 (RN-CAS Registry Number XXXXX-XX-X)

12.3+1.0 El 4098

p3o7+ P4o9 (RN-CAS Registry Number XXXXX-XX-X)

15.0+1.0 El 4098

p4o7+ p4o7 (RN-CAS Registry Number 12065-80-4)

11.4+0.5 El 4098

p4o8+ p4o8 (RN-CAS Registry Number 12037-06-8)

11.9±0.5 El 4098

p4o9+ p4o9 (RN-CAS Registry Number XXXXX-XX-X)12.4+0.5 El 4098

P4O,+

0 P4O10 (RN-CAS Registry Number XXXXX-XX-X)

13.0±0.5 El 4098

ch4op+ (CH30)2P(CH3 S)S

(RN-CAS Registry Number 2953-29-9)

13.40+0.30 El 3989

ch4o2p

+ ch4o2p

+

(MT-Metastable

ch4o2p

+

(MT-Metastable

ch4o2p

+

(CH30)3 P0 2HCHO+H

(RN-CAS Registry Number 512-56-1)

(CH30)2P(CH3 S)0 ch3 s +hcho

(RN-CAS Registry Number 152-20-5)

transition(s) observed)

(CH30)2P(CH3 S)S ch3 s +hchs

(RN-CAS Registry Number 2953-29-9)

transition(s) observed)

(CH3 S)2P(CH30)0 CH3 S +HCHS

(RN-CAS Registry Number 22608-53-3)

14.90+0.20

12.25±0.20

12.75±0.20

11.90±0.10

El

El

El

El

3989

3989

3989

3989

CH502P

+ (CH30)3 P0 2HCHO

(RN-CAS Registry Number 512-56-1)

CH502P

+ (CH30)2P(CH3 S)0 hchs +hcho

(RN-CAS Registry Number 152-20-5)

(MT-Metastable transition(s) observed)

12.9 1 ±0. 10

12.35+0.20

El

El

3989

3989

195
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C2H602 P

+ (CH3 0)2 P(CH3 S)S

(RN-CAS Registry Number 2953-29-9)

10.40±0. 10 El 3989

c19h35o2 p

+ C5 H2 P(OCH3)2(C4H9)3 6.7 (V) PE 4053

(Phosphorin, 2,4,6-tris( 1 > 1 -dimethylethyl)- 1, 1 -dihydro- 1, 1 -dimethoxy-)

(RN-CAS-Registry Number 37912-85-9)

ch4o3 p

+ (CH30)3 P0 hcho-i-ch3 (RN-CAS Registry Number 512-56-1)

(MT-Metastable transition(s) observed)

CH403 P

+ (CH3 0)2P(CH3 S)0 hchs+ ch3 (RN-CAS Registry Number 152-20-5)

CjH603 P

+ (CH3 0)3 P0 hcho+ h

(RN-CAS Registry Number 512-56-1)

C2H603 P

+ (CH30)2P(CH3 S)0 ch3 s (RN-CAS Registry Number 152-20-5)

C2H703 P

+ (CH30)3 P0 hcho

(RN-CAS Registry Number 512-56-1)

(MT-Metastable transition(s) observed)

C2H703 P

+ (CH3 0)2 P(CH3 S)0 hchs

(RN-CAS Registry Number 152-20-5)

(MT-Metastable transition(s) observed)

c3 H8o4p

+ (CH3 0)3 P0 h 12.73±0.20 El 3989

(RN-CAS Registry Number 512-56-1)

c3 h9o4p

+ (CH3 0)3 P0 ** 10.70±0.10 El 3989

(RN-CAS Registry Number 512-56-1)

PF,t

2A,) PF3 ** 11.57±0.01 PE 3703

(RN-CAS Registry Number 7783-55-3)

PF3t

2A.) PF3 ** 1 1.66±0.01 PE 3641

(RN-CAS Registry Number 7783-55-3)

pf3+ PF3 ** 12.23±0.02 (V) PE 3662

pf3 +

(

2a2) (RN-CAS Registry Number 7783-55-3)

PF3 ** 15.31 ±0.05 PE 3641

PF3t

2E)

(RN-CAS Registry Number 7783-55-3)

PF3 ** 16.31 ±0.07 (V) PE 3641

PF3t

2E)

(RN-CAS Registry Number 7783-55-3)

PF3 ** 17.08±0.01 PE 3641

PFjt2A,)

(RN-CAS Registry Number 7783-55-3)

PF3 ** 18.26±0.01 PE 3641

PFjt2E)

(RN-CAS Registry Number 7783-55-3)

PF3 ** 19.06±0.01 PE 3641

PF,t

2A,)

(RN-CAS Registry Number 7783-55-3)

PF3 ** (RN-CAS Registry Number 7783-55-3)

22.6 (V) PE 3641

pf3+ PF3 ** 1 1.72±0.1 El 3578

(RN-CAS Registry Number 7783-55-3)

13.90±0.20 El 3989

13.20±0.20 El 3989

14.1 ±0.20 El 3989

1 1.90±0.10 El 3989

1 1.62±0.10 El 3989

11.00±0.10 El 3989

196
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

pf5+ pf5 ** (RN-CAS Registry Number 7647-19-0)

15.54 (V) PE 3872

pf5+ PF5 ** (RN-CAS Registry Number 7647-19-0)

15.6 (V) PE 3669

p2f4+ p2f4 (RN-CAS Registry Number 13824-74-3)

9.64 (V) PE 3662

phf2+ pf2h ** (RN-CAS Registry Number 14984-74-8)

11.0±0.1 (V) PE 3662

bh3f3p

+ (PF3)(BH3) (RN-CAS Registry Number 14931-39-6)

11.02+0.03 PE 3699

b3h5f3p

+ b3h7pf3 (RN-CAS Registry Number 11126-95-7)

10.8+0.3 El 3652

ph2nf2+ pf2nh2 ** (RN-CAS Registry Number 25757-74-8)10.9 (V) PE 3662

cnf2p

+ pf2cn ** (RN-CAS Registry Number 14118-40-2)

11.9+0.1 (V) PE 3662

c4h12n2pf+ ((CH3)2N)2PF

(RN-CAS Registry Number 1735-82-6)

8.18 (V) PE 3825

c,h6npf2+ (CH3)2NPF2 (RN-CAS Registry Number 814-97-1)

9.58 (V) PE 3825

c2h6nf2p

+ (CH3)2NPF2 ** (RN-CAS Registry Number 814-97-1)

9.6 (V) PE 3662

c2h6nf2p

+ (CH3)2NF2P ** (RN-CAS Registry Number 814-97-1)

10.2 ±0.3 El 3652

c6h,„n3f2p

+ ((CH3)2N)3PF2 (RN-CAS Registry Number 7549-83-9)

8.04 (V) PE 3825

C4H,2N2FjP+ ((CH3)2N)2PF3 (RN-CAS Registry Number 1735-83-7)

8.84 (V) PE 3825

c2h6nf4p

+ (CH3)2NPF4 (RN-CAS Registry Number 2353-98-2)

10.35 (V) PE 3825

c2h9bnf2p

+ (CH3)2NF2 PBH3? ** (RN-CAS Registry Number 2851-73-2)

12.2±0.3 El 3652

c2h11 b3nf2p

+ (CH3)2NF2PB3 H7 (RN-CAS Registry Number 11126-93-5)

10.4±0.3 El 3652

c2h12b3 nf2p

+ (CH3)2NF2PB3 H7 h

(RN-CAS Registry Number 11126-93-5)

10.5+0.3 El 3652

197
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C2 H12 B4NF2 P

+ (CH3)2 NF2 PB4H8 (RN-CAS Registry Number 12602-24-3)

10.0±0.3 El 3652

c2 h14 b4nf2 p

+ (CH3 )2 NF2 Pb4h8 (RN-CAS Registry Number 12602-24-3)

9.6±0.3 El 3652

POF3t

2 E) POF3 ** (RN-CAS Registry Number 13478-20-1)

12.77 ±0.04 PE 3641

POF,t2 A,) POF3 ** (RN-CAS Registry Number 13478-20-1)

15.16±0.04 PE 3641

POF,t2 A2) POF3 ** (RN-CAS Registry Number 13478-20-1)

16.69±0.05 PE 3641

POF3t

2 E) POF3 ** (RN-CAS Registry Number 13478-20-1)

17.68 (V) PE 3641

POF3t

2 E) POF3 ** (RN-CAS Registry Number 13478-20-1)

18.45±0.02 PE 3641

POF,t2A,) POF3 ** (RN-CAS Registry Number 13478-20-1)

19.61 (V) PE 3641

POF3t

2 E) POF3 ** (RN-CAS Registry Number 13478-20-1)

20.36±0.02 PE 3641

POF,t!A,) POF3 ** (RN-CAS Registry Number 13478-20-1)

23.4±0.1 (V) PE 3641

P2OF4+ PF2OPF2 ** (RN-CAS Registry Number 13812-07-2)

11.2 (V) PE 3662

cnof2 p

+ pf2 nco ** (RN-CAS Registry Number 461-59-6)

11.05 ±0.02 (V) PE 3662

NaP02+ NaP02 ** (RN-CAS Registry Number XXXXX-XX-X)

8.6 El 4098

PSi + PSi ** (RN-CAS Registry Number 12137-64-3)

9.1 ±0.5 El 4102

PSi2+ PSi2 ** (RN-CAS Registry Number 37347-46-9)

8.4±0.5 El 4102

P2 Si + P2 Si ** (RN-CAS Registry Number 12137-68-7)

9.0±0.5 El 4102

SiH5 P

+ SiH3 PH2 ** (RN-CAS Registry Number 14616-47-8)

9.9±0.1 (V) PE 3661

Si3 H9 P

+ (SiH3)3 P

(RN-CAS Registry Number 15110-33-5)

9.3 ±0. 1 (V) PE 3661

CSiP + CSiP ** (RN-CAS Registry Number 37342-74-8)

8.9±0.5 El 4102

198
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C7H19 SiP+ (CH3)3 P =CHSi(CH3)3 (RN-CAS Registry Number 3272-86-4)

6.80 PE 3782

C9H25 Si2 P

+ (CH3)3 P =CHSi2(CH3)5 ** (RN-CAS Registry Number 29947-67-9)

6.87 PE 3782

S

+ S

** (RN-CAS Registry Number 7704-34-9)

S

+

S

** (RN-CAS Registry Number 7704-34-9)

S

+ S

** (RN-CAS Registry Number 7704-34-9) s

+ h2s h2 (RN-CAS Registry Number 7783-06-4)

S

+ CS2 CS

(RN-CAS Registry Number 75-15-0)

(CD-Metastable transition indicates <0.25 eV kinetic energy release)

(PC-Appearance potential of the corresponding metastable transition)

S

+ CS2 CS

(RN-CAS Registry Number 75-15-0)

(CD-Metastable transition indicates <0.25 eV kinetic energy release)

(PC-Appearance potential of the corresponding metastable transition)

S

+ COS CO

(RN-CAS Registry Number 463-58-1)

10.3+0.3 El 3449

10.5+0.3 El 3616

11+0.5 El 3448

13.5 DC 3967

15+1 El 3812

1 7± 1 El 3812

13.7 El 3779

S2+

(RN-CAS Registry Number 12185-11-4) + c **

2 (RN-CAS Registry Number 12185-11-4)

2+ c3 h6s2 ch2 =chch3 (1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

(TR-Other product(s) thermochemically reasonable) s2 f2 (RN-CAS Registry Number 13709-35-8)

9.42+0.10

9. 8±0.5

10.7±0.1

17.6±0.4

El

El

El

El

3616

3615

3598

3738

S

+ c ** a8(RN-CAS Registry Number 10544-50-0)

9.23 (V) PE 3846

HS+ h2 s h

(RN-CAS Registry Number 7783-06-4)

14.4 DC 3967

h2s

+

(

2b.)

h2s

+

(

2 b,)

h2s

+

(

2a,)

h2 s

** (RN-CAS-Registry Number 7783-06-4)

H2S

** (RN-CAS Registry Number 7783-06-4)

H2S

** (RN-CAS Registry Number 7783-06-4)

H2 S

** (RN-CAS

H2 S

(RN-CAS

Registry Number 7783-06-4)

** Registry Number 7783-06-4)

199

10.43 PE 4073

10.47 PE 3678

10.47 PE 3719

10.48 PE 3697

12.752 PE 3515
Table of Ion Energetics Measurements—Continued

Ion

h2 s

+

(’a,)

H2 S

+ *

H2 S

+

(

2 A,)

h2 s

+

Reactant Other

products

H2 S

** (RN-CAS Registry Number 7783-06-4)

H2 S

** (RN-CAS Registry Number 7783-06-4)

H2 S

** (RN-CAS Registry Number 7783-06-4)

H2 S

** (RN-CAS Registry Number 7783-06-4)

H2 S

** (RN-CAS Registry Number 7783-06-4)

Ionization or appearance

potential

(eV)

Method Ref.

12.78 PE 3719

13.21 (V) PE 3697

14.78 PE 3719

22.2 (V) PE 3719

10.45 DC 3967

h3 s

+ c2h5 sh c2h3 (RN-CAS Registry Number 75-08-1)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

h3 s

+ (ch3)2s c2h2 +h

(RN-CAS Registry Number 75-18-3)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

BHS+ (X2 ri) HBS ** (RN-CAS Registry Number 14457-85-3)

BHS+ HBS ** (RN-CAS Registry Number 14457-85-3)

BHS+(A22

+

) HBS ** (RN-CAS Registry Number 14457-85-3)

BHS+ (B2 2

+

) HBS ** (RN-CAS Registry Number 14457-85-3)

CS + (X2 !^) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS + CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS + (X22) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+ (X22) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS + * CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS + (A2 7r) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS + (A2 7t) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

12.41 ±0.02 RPD 3487

14.14±0.02 RPD 3487

11.11 ±0.03 PE 3982

11.12 PE 3871

13.54±0.03 PE 3982

15.83 ±0.PE 3982

1 1.33±0.01 PE 3691

1 1.33±0.02 PE 3696

1 1.34±0.02 PE 3690

11.34 PE 3689

12.56±0.02 PE 3696

12.78±0.02 PE 3690

12.78 PE 3689

200
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

CS+(A27ru) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+

(B22) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+(B2D) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+

(B22^ CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+(E2 2^ CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+(C22) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS^C2!) CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+ CS ** (RN-CAS Registry Number 2944-05-0)

(RD-Radical)

CS+ CS2 s (RN-CAS Registry Number 75-15-0)

(CD-Metastable transition indicates <0.40 eV kinetic energy release)

(PC-Appearance potential of the corresponding metastable transition)

CS+ COS CT?

(RN-CAS Registry Number 463-58-1)

12.79±0.01

15.83±0.02

15.83

15.84±0.01

18.00±0.01

18.03+0.02

18.03

11.39+0.10

16.3+1

16.7

PE

PE

PE

PE

PE

PE

PE

El

El

El

3691

3690

3689

3691

3691

3690

3689

3616

3812

3779

cs2tA2nl/2u) CS2 ** (RN-CAS Registry Number 75-15-0)

12.586 S 3573

cs2tx2ng

) CS2 ** (RN-CAS Registry Number 75-15-0)

10.06+0.01 PE 3965

cs2tx2 n!/2) CS2 ** (RN-CAS-Registry Number 75-15-0)

10.06 PE 4073

CS2+ CS2 ** (RN-CAS Registry Number 75-15-0)

10.06 PE 3697

cs2tA2 nj CS2 ** (RN-CAS Registry Number 75-15-0)

12.67+0.01 PE 3965

CS2* CS2 ** (RN-CAS Registry Number 75-15-0)

12.83 (V) PE 3697

CSjB2^cs2 (RN-CAS Registry Number 75-15-0)

14.47±0.01 PE 3965

CSJC2!^) CS2 ** (RN-CAS Registry Number 75-15-0)

16.18+0.01 PE 3965

CS^* CS2 ** (RN-CAS Registry Number 75-15-0)

16.70+0.01 PE 3965

CS2+ CS2 ** (RN-CAS Registry Number 75-15-0)10.07±0.10 El 3616

201
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CHS+ c3 h6s2 chs + ch4? (1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

(MT-Metastable transition(s) observed)

13±0.4 El 3598

CHS+ C3 H6OS

(1,3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

12.9±0.2 El 3598

CHjS+^BJ CH2 S

** (RN-CAS Registry Number 865-36-1)

9.338±0.010 PE 3697

CH2 S

+

(

2 B.) CH2 S

** (RN-CAS Registry Number 865-36-1)

1 1.78±0.01 PE 3697

ch2 s

+ ch3 sh h2 (RN-CAS Registry Number 74-93-1)

10.8±0.1 PI 4025

ch2 s

+ (CH3)2S ch4 (RN-CAS Registry Number 75-18-3)

10.46±0.08 PI 4025

ch2 s

+ (C2 H5)2 S c2 h4 +ch4 (RN-CAS Registry Number 352-93-2)

11.75±0.03 PI 4025

ch2 s

+ C3 H6S2 (1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

11 ±0.4 El 3598

ch2 s

+ C3 H6OS

(1,3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

12.5±0.2 El 3598

ch2 s

+ c5 h10o2 s 2HCHO+C2H4 (1,3,6-Dioxathiocane)

(RN-CAS Registry Number 2094-92-0)

(TR-Other product(s) thermochemically reasonable)

12.55±0.1 El 3903

ch3 s

+ CH3 SH h

(RN-CAS Registry Number 74-93-1)

1 1.37±0.05 PI 4025

ch3 s

+ (CH3)2 S ch3 (RN-CAS Registry Number 75-18-3)

10. 79 ±0.04 PI 4025

ch3 s

+ (C2 H5)2 S c2h4 +ch3 (RN-CAS Registry Number 352-93-2)

12. 00 ±0.05 PI 4025

ch3 s

+ C3 H6S2 (1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

1 1.4±0.4 El 3598

ch3 s

+ (CH3 0)2 P(CH3 S)0

(RN-CAS Registry Number 152-20-5)

13.1 ±0.30 El 3989

ch3 s

+ (CH3 S)2 P(CH30)0

(RN-CAS Registry Number 22608-53-3)

12.60±0.20 El 3989

ch4s

+ CH3 SH ** (RN-CAS Registry Number 74-93-1)

9.44±0.01 PI 4025

ch4s

+ CH3 SH ** (RN-CAS Registry Number 74-93-1)

9.415 PE 3697

CH4S

+

(

2 A

w ) CH3 SH ** (RN-CAS Registry Number 74-93-1)

9.42 PE 3678

CH4S

+

(

2 A

w

) CH3 SH ** (RN-CAS Registry Number 74-93-1)

9.44 PE 4032

202
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

ch4s

+ ch3 sh ** 9.44 PE 4087

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A") ch3 sh ** 9.44 (V) PE 3656

(RN-CAS Registry Number 74-93-1)

ch4s

+ ch3 sh ** 9.44 (V) PE 3898

(RN-CAS Registry Number 74-93-1)

ch4s

+ * ch3 sh ** 11.90 (V) PE 3697

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A') ch3 sh ** 12.0 (V) PE 3678

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A) ch3 sh ** 12.08 (V) PE 4032

(RN-CAS Registry Number 74-93-1)

ch4s

+ * ch3 sh ** 13.50 (V) PE 3697

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A') ch3sh ** 13.67 (V) PE 4032

(RN-CAS Registry Number 74-93-1)

C.H4S

+

(

2A') ch3sh ** 13.9 (V) PE 3678

(RN-CAS Registry Number 74-93-1)

ch4s

+ * ch3sh ** 14.90 (V) PE 3697

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A") ch3 sh ** 15.0 (V) PE 3678

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A") ch3 sh ** 15.5 (V) PE 3678

(RN-CAS Registry Number 74-93-1)

ch4s

+ * ch3 sh ** 15.5 (V) PE 3697

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2Aw ) ch3 sh ** 15.63 (V) PE 4032

(RN-CAS Registry Number 74-93-1)

CH4S

+

(

2A') ch3 sh ** -20.0 (V) PE 3678

(RN-CAS Registry Number 74-93-1)

C,HjS+ c3H6s2 ch3 s 10.8±0.4 El 3598

(1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

CjHjS* c3h6os ch2o+h 12.3+0.1 El 3598

( 1

, 3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

C2H4S

+ c2h4s

** (Thiirane)

(RN-CAS Registry Number 420-12-2)

(RS-Average of three Rydberg series limits)

c2h4s

** (Thiirane)

(RN-CAS Registry Number 420-12-2)

c2h4s

** (Thiirane)

(RN-CAS Registry Number 420-12-2)

(C2H5)2 S c2h6 (RN-CAS Registry Number 352-93-2)

203

C2H4S

+

C2H4S

+

c,h4s

+

9.051 ±0.006 S 3882

9.00 PE 3861

9.05 (V) PE 3837

9.89±0.3 PI 4025
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref.

products potential

(eV)

C2 H4S

+ C3 H6S2 CH2 S 1 1.2±0.3

(1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

C2 H4S

+ c3 h6os ch2o 10.5±0.1

(1,3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

(MT-Metastable transition(s) observed)

C2 H4S

+ C5 H10O2 S 10.4+0.02

( 1 ,3,6-Dioxathiocane)

(RN-CAS Registry Number 2094-92-0)

C2H5 S

+ (CH3)2S H 10.93 ±0.1

(RN-CAS Registry Number 75-18-3)

C2 H5 S

+ (C2H5)2S C2H5 10.23 ±0J

(RN-CAS Registry Number 352-93-2)

C2 H5 S

+ C3 H6S2 CHS 11.4+0.3

(1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

(TR-Other product(s) thermochemically reasonable)

C2 H5 S

+ C3 H6OS CHO 10.4±0.1

( 1

, 3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

(TR-Other product(s) thermochemically reasonable)

C2 H5 S

+ C5 H10O2 S CH3CO+HCHO 10.8±0.2

(1,3, 6-Dioxathiocane)

(RN-CAS Registry Number 2094-92-0)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

c2 h6 s

+ c2 h5 sh

(RN-CAS Registry Number

** 75-08-1)

9.29 PE 4032

c2h6s

+ (CH3)2S

(RN-CAS Registry Number

(RS-Average of three Rydberg series limits)

** 75-18-3)

8.706+0.010 S 3970

c2 H6s

+ (CH3)2S

(RN-CAS Registry Number

** 75-18-3)

8.69±0.01 PI 4025

c2h6s

+ (CH3)2S

(RN-CAS Registry Number

** 75-18-3)

8.57+0.04 PE 3842

c2h6s

+ (CH3)2 S

(RN-CAS Registry Number

** 75-18-3)

8.65 (V) PE 3678

c2h6s

+ (CH3)2s (RN-CAS Registry Number

** 75-18-3)

8.67 PE 3867

c2 h6s

+ (CH3)2s (RN-CAS Registry Number

** 75-18-3)

8.67 (V) PE 3898

c2 h6s

+ (CH3)2S

(RN-CAS Registry Number

** 75-18-3)

8.7 PE 4104

c2h6s*(2b,) (CH3)2S

(RN-CAS Registry Number

** 75-18-3)

8.71 (V) PE 3656

c2 h6 s

+ (C2H5)2 S

(RN-CAS Registry Number

C2H4 352-93-2)

9.90+0.03 PI 4025

El 3598

El 3598

El 3903

PI 4025

PI 4025

El 3598

El 3598

El 3903

204
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c3 h5 s

+ c3 h6s2 sh

(1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

10.5 ±0.1 El 3598

c3 h6s+ ch2 =chch2sh ** (RN-CAS Registry Number 870-23-5)

9.25 PE 3864

c3h6s

+ ch2 =chsch3 ** (RN-CAS Registry Number 1822-74-8)

8.45 (V) PE 3898

C3 H6S

+ C5H10O2S 2HCHO

(1,3, 6-Dioxathiocane)

(RN-CAS Registry Number 2094-92-0)

(TR-Other product(s) thermochemically reasonable)

1 1 .35 ±0.01 El 3903

C3H7S

+

CjH8 S

+ C3H,S+

(C,H5 ) 2 S ch,

(RN-CAS Registry Number 352-93-2)

«-c3h7sh ** (RN-CAS Registry Number 107-03-9)

«o-C3H7 SH ** (RN-CAS Registry Number 75-33-2)

10.16±0.05 PI 4025

9.19 PE 4032

9.14 PE 4032

c4h4s

+

c4h4s

+

c4h4s

+

c4h4s

+

c4h4s

+

c4h4s

+

c4h4s

** (Thiophene)

(RN-CAS Registry Number 110-02-1)

c4h4s

** (Thiophene)

(RN-CAS-Registry Number 110-02-1)

c4h4s

** (Thiophene)

(RN-CAS Registry Number 110-02-1)

c4h4s

** (Thiophene)

(RN-CAS Registry Number 110-02-1)

c4h4s

** (Thiophene)

(RN-CAS Registry Number 110-02-1)

c4h4s

** (Thiophene)

(RN-CAS Registry Number 110-02-1)

8.874±0.005 S 3731

8.86±0.01 PI 4058

8.87 (V) PE 3858

8.90 PE 4017

9.12±0.05 El 3482

9.05 CTS 3787

c4d4s

+ c4d4s

** (Thiophene-*/4) (RN-CAS Registry Number 2036-39-7)

8.874±0.005 S 3731

c4h6s

+ c4H6s

(Thiophene, 2,5-dihydro-)

(RN-CAS Registry Number 1708-32-3)

8.54 (V) PE 3995

c4h8 s

+ ch3 sch2ch=ch2 ** 8.6 PE 4104

(RN-CAS Registry Number 10152-76-8)

205
Table of Ion Energetics Measurements—Continued

Ion

c4h8 s

+

c4h8 s

+

Ionization or Reactant Other appearance Method Ref.

products potential

(eV)

C4H8 S ** 8.40 (V) PE 3995

(Thiophene, tetrahydro-)

(RN-CAS Registry Number 110-01-0)

C4H8 S ** 8.62±0.05 El 3498

(Thiophene, tetrahydro-)

(RN-CAS Registry Number 110-01-0)

C4H9S (C2 H5)2S H

(RN-CAS Registry Number 352-93-2)

10.2±0.1 PI 4025

c4h10s

+ (C2 H5)2S

** 8.42±0.01 PI 4025

(RN-CAS Registry Number 352-93-2)

c4h10s

+ (C2 H5)2 S

** 8.44 (V) PE 3898

(RN-CAS Registry Number 352-93-2)

c4h10s

+ n-C4H9SH ** 9.15 PE 4032

(RN-CAS Registry Number 109-79-5)

c4h10s

+ sec-C4H9SH ** 9.10 PE 4032

(RN-CAS Registry Number 513-53-1)

c4h10s

+ iso-C4H9SH ** 9.12 PE 4032

(RN-CAS Registry Number 513-44-0)

c4h10s

+

ter/-C4H9SH ** 9.03 PE 4032

(RN-CAS Registry Number 75-66-1)

c5 h6s

+ c4h3 sch3 ** (Thiophene, 2-methyl-)

(RN-CAS Registry Number 554-14-3)

8.63±0.05 El 3482

c5 h6s

+ c4h3 sch3 ** (Thiophene, 2-methyl-)

(RN-CAS Registry Number 554-14-3)

8.61 CTS 3787

c5 h6s

+ QH3SCH3 ** (Thiophene, 3-methyl-)

(RN-CAS Registry Number 616- 44 4)

8.72 El 3787

c5 h6s

+ c4h3 sch3 ** (Thiophene, 3-methyl-)

(RN-CAS Registry Number 616 -44 4)

8.84 CTS 3787

C5 H10S

+ C5 H10S ** 8.45 (V) PE 3733

(2//-Thiopyran, tetrahydro-)

(RN-CAS Registry Number 1613-51-0)

C6H6S

+ C6H5 SH ** 8.28 PE 3678

(Benzenethiol)

(RN-CAS Registry Number 108-98-5)

C6H6S

+ C6H5 SH ** 8.95±0.1 El 3817

(Benzenethiol)

(RN-CAS Registry Number 108-98-5)

C6H8 S

+ C4H2S(CH3)2 ** 8.10 El 3787

(Thiophene, 2,5-dimethyl-)

(RN-CAS Registry Number 638-02-8)

206
Ion

c6h8 s

+

c6h8 s

+

c6h8 s

+

Table of Ion Energetics Measurements—Continued

Ionization or Reactant Other appearance Method Ref. products potential

(eV)

C4H2 S(CH3)2 ** 8.18 CTS 3787

(Thiophene, 2,5-dimethyl-)

(RN-CAS Registry Number 638-02-8)

C4H3 SC,H5 ** 8.67±0.05 El 3482

(Thiophene, 2-ethyl-)

(RN-CAS Registry Number 872-55-9)

C4H3 SC2H5 ** 8.57 CTS 3787

(Thiophene, 2-ethyl-)

(RN-CAS Registry Number 872-55-9)

C6H10S

+ QH^S ** 8.28 ±0.04 PE 3842

(7-Thiabicyclo[2.2. l]heptane)

(RN-CAS Registry Number 279-59-4)

C6H14S

+ («-C3H7)2S ** 8.34 (V) PE 3898

(RN-CAS Registry Number 111-47-7)

C6H14S

+ («o-C3H7)2S ** 8.26 (V) PE 3898

(RN-CAS Registry Number 625-80-9)

C7HsS

+ c6h5 ch2sh ** (Benzenemethanethiol)

(RN-CAS Registry Number 100-53-8)

8.85 (V) PE 3678

c,h8 s+ QHgSCHj ** (Benzene, (methylthio)-)

(RN-CAS Registry Number 100-68-5)

8.07 (V) PE 3781

C,HgS

+ c6h5 sch3 ** (Benzene, (methylthio)-)

(RN-CAS Registry Number 100-68-5)

8.07 (V) PE 3898

c8h6s

+

c8 h6s+

c8h6s

(Benzo[6]thiophene)

(RN-CAS Registry Number 95-15-8)

c8H6s

(Benzo[c]thiophene)

(RN-CAS Registry Number 270-82-6)

8.20

7.75

PE

PE

4017

4017

c8 h,0s

+ c6h5 ch2sch3 ** (Benzene, [(methylthio)methyl]-)

(RN-CAS Registry Number 766-92-7)

9.01 (V) PE 3781

c8 hI2 s

+ c4h3sc4h9 ** (Thiophene, 2-( 1 , 1 -dimethylethyl)-)

(RN-CAS Registry Number 1689-78-7)

8.54+0.05 El 3482

c8 hI8 s

+

(tert-C4H9)2S

** (RN-CAS Registry Number 107-47-1)

8.07 (V) PE 3898

C,H,„S + c6h5ch=chsch3 ** 7.75 (V) PE 3781

(Benzene, [2-(methylthio)ethenyl]-(Z)-)

(RN-CAS Registry Number 35822-50-5)

207
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c9HI0s

+ c6h5 ch=chsch3 ** (Benzene, [2-(methylthio)ethenyl]-, (Z)-)

(RN-CAS Registry Number 35822-50-5)

8.75 (V) PE 3898

C„H10S

+ c10h7 sch3 ** (Naphthalene, l-(methylthio)-)

(RN-CAS Registry Number 10075-72-6)

7.67 (V) PE 3781

C,|H 10S

+ c10h7 sch3 ** (Naphthalene, 2-(methylthio)-)

(RN-CAS Registry Number 7433-79-6)

7.71 (V) PE 3781

C„H10S

+ c10h7 sch3 ** (Naphthalene, 2-(methylthio)-)

(RN-CAS Registry Number 7433-79-6)

7.71 (V) PE 3898

c12 h8 s

+ c12 h8 s

(Dibenzothiophene)

(RN-CAS Registry Number 132-65-0)

8.01 (V) PE 3852

c12 h8 s

+ c12 H8 s

(Dibenzothiophene)

(RN-CAS Registry Number 132-65-0)

8.34 El 3787

c12h8 s

+ c12h8 s

(Dibenzothiophene)

(RN-CAS Registry Number 132-65-0)

8.23 CTS 3787

cI 2 h10s

+ (C6H5)2 S

(Benzene, l,l'-thiobis-)

(RN-CAS Registry Number 139-66-2)

7.88±0.05 El 3498

c12 h10s

+ (C6H5)2 S

(Benzene, 1,1 thiobis—

)

(RN-CAS Registry Number 139-66-2)

8.45±0.1 El 3817

cI 2 h10s

+ c4h3 sch=chc6h5 ** (Thiophene, 2-(2-phenylethenyl)-)

(RN-CAS Registry Number 3783-65-1)

7.55 El 3787

c12 h10s

+ c4h3 sch=chc6h5 ** (Thiophene, 2-(2-phenylethenyl)-)

(RN-CAS Registry Number 3783-65-1)

7.78 CTS 3787

ch2 s2+ c3 H6s2 c2 h4 (1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

10.8±0.2 El 3598

c2 h6s2+ ch3 ssch ** (RN-CAS Registry Number 624-92-0)

8.97 (V) PE 3898

c2h6s2+ CH3 SSCH3 ** (RN-CAS Registry Number 624-92-0)

8.82 (V) PE 3697

c3 h5 s2+ c3 H6s2 h

(1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

1 1.2±0.2 El 3598

208
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c3h6s2+ c3h6s2 (1,3-Dithiolane)

(RN-CAS Registry Number 4829-04-3)

9.0±0.05 El 3598

c3 h8s2+ (CH3 S)2CH2 ** (RN-CAS Registry Number 1618-26-4)

8.65 (V) PE 3898

c4h8s2+ rra/w-CH3 SCH=CHSCH3 ** (RN-CAS Registry Number 764-45-4)

7.96 (V) PE 3898

c4h8 s2+ c4h8 s2 (1,2-Dithiane)

(RN-CAS Registry Number 505-20-4)

8.36 (V) PE 3898

c4h8s2+ c4H8s2 (1,3-Dithiane)

(RN-CAS Registry Number 505-23-7)

8.33 (V) PE 3898

c4h„s2+ c4H8 s2 (1,3-Dithiane)

(RN-CAS Registry Number 505-23-7)

8.54 (V) PE 3733

c4h8s2+ c4h8 s2 (1,4-Dithiane)

(RN-CAS Registry Number 505-29-3)

8.58 (V) PE 3733

c4h10s2+ CjHjSSCjHs ** (RN-CAS Registry Number 110-81-6)

8.70 (V) PE 3898

c4h10s2+ ch3 sch2ch2sch3 ** (RN-CAS Registry Number 6628-18-8)

8.64 (V) PE 3898

c5 h„s2

* C4H3 SSCH3 ** (Thiophene, 2-(methylthio)-)

(RN-CAS Registry Number 5780-36-9)

8.10+0.05 El 3482

C6H4s2+ c6H4s2 (Thieno[2,3-6]thiophene)

(RN-CAS Registry Number 250-84-0)

8.32 PE 4017

QH4S2+ c6h4s2 (Thieno[3,2-6]thiophene)

(RN-CAS Registry Number 251-41-2)

8.10 PE 4017

Qh4s2+ QH.S,

(Thieno[3,2-6]thiophene)

(RN-CAS Registry Number 251-41-1)

8.14 (V) PE 3852

c6h10s2+

c£s,c£s-CH3 SCH=CHCH=CHSCPf3 (RN-CAS Registry Number 35822-49-2)

7.48 (V) PE 3898

c6h14s2+ (CH3)2CHSSCH(CH3)2 ** (RN-CAS Registry Number 4253-89-8)

8.54 (V) PE 3898

c6h14s2+ (n-C3H7)2S2 ** (RN-CAS Registry Number 629-19-6)

8.62 (V) PE 3898

209
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance

products potential

(eV)

Method Ref.

c8 h10s2+ C6H4(SCH3)2 (Benzene, l,4-bis(methylthio)-)

(RN-CAS Registry Number 699-20-7)

7.93 (V) PE 3781

C8H18 S2+ (CH3)3 CSSC(CH3)3 ** (RN-CAS Registry Number 110-06-5)

8.17 (V) PE 3898

c3 h6s3+ c3 h6s3 (1,3,5-Trithiane)

(RN-CAS Registry Number XXXXX-XX-X)

8.76 (V) PE 3733

c5 h4s3+ C5 H4S3

([ 1 ,2]Dithiolo[ 1 ,5-Z>][ 1 ,2]dithiole- 7-SIV

) (RN-CAS Registry Number 252-09-5)

(ON-Other name: Thiathiophthene)

8.11 (V) PE 3569

C6H6S3+ c5 h3 s3 ch3 **

([ 1 ,2]Dithiolo[ 1 , 5-Z>][ 1 ,2]dithiole- 7-S1

'v

, 2-methyl-)

(RN-CAS Registry Number 20718-55-2)

(ON-Other name: 2-Methylthiathiophthene)

7.83 (V) PE 3569

c7h8 s3+ C5 H2 S3 (CH3)2

([ 1 ,2]Dithiolo[ 1 ,5-6][ 1 ,2]dithiole- 7-STM

,

2,5-dimethyl-)

(RN-CAS Registry Number 2080-35-5)

(ON-Other name: 2,5-Dimethylthiathiophthene)

7.73 (V) PE 3569

c7 h8 s3+ C5 H2 S3 (CH3)2

([ 1 ,2]Dithiolo[ 1 ,5-6][ 1 ,2]dithiole- 7-5IV

, 3,4-dimethyl-)

(RN-CAS Registry Number 29977-00-2)

(ON-Other name: 3,4-Dimethylthiathiophthene)

7.63 (V) PE 3569

CioHi 2 S^ C8 H6 S3(CH3)2 ** 7.34 (V) PE

(3H-[ 1 ,2]Dithiolo[4,5, 1 -hi][ 1 ,2]benzodithiole-5-5IV

, 4, 5-dihydro-2,6-dimethyl-)

(RN-CAS Registry Number 35437-21-9)

3569

c12 h16s3+ C8 H6S3(C2H5 )2 ** 7.33 (V) PE

(3//-[ 1 ,2]Dithiolo[4,5, 1 -hi][ 1 ,2]benzodithiole-5-5IV

, 2, 6-diethyl-4, 5-dihydro-)

(RN-CAS Registry Number 35505-46-5)

3569

c14 h20s3+ C8 H6S3(C3 H7)2 ** 7.19 (V) PE

(3//-[l,2]Dithiolo[4,5,l-/j/][l,2]benzodithiole-5-5IV

, 4,5-dihydro-2,6-bis(l-methylethyl)-)

(RN-CAS Registry Number 35505-47-6)

3569

c17 h 12 s3+ C5 H2 S3(C6H5)2 ** 7.57 (V)

([ l,2]Dithiolo( l,5-6][ l,2]dithiole-7-5IV

, 3,4-diphenyl-)

(RN-CAS Registry Number 25730-47-6)

(ON-Other name: 3,4-Diphenylthiathiophthene)

PE 3569

c6h4s4+ C6H4S4 ** 6.83 (V)

(1,3-Dithiole, 2-(l,3-dithiol-2-ylidene)-)

(RN-CAS Registry Number 31366-25-3)

(ON-Other name: Tetrathiofulvalene)

PE 3981

210
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

CioH18S<r c4h8 s2 (1,4-Dithiane)

(RN-CAS Registry Number 505-29-3)

8.46 (V) PE 3898

C3H9BS+ (CH3)2BSCH3 ** (RN-CAS-Registry Number 19163—05—4)

9.40 (V) PE 4065

C3H.BS+ (CH3 S)2BCH3 ** (RN-CAS-Registry Number 19163-08-7)8.74 (V) PE 4065

C3 H9BS3+ B(SCH3)3 (RN-CAS-Registry Number 997-49-9)8.74 (V) PE 4065

CHNS+

(

2A')

CHNS+

(

2A')

CHNS+ * CHNS+ *

HNCS ** (RN-CAS Registry Number 3129-90-6)

HNCS ** (RN-CAS Registry Number 3129-90-6)

HNCS ** (RN-CAS Registry Number 3129-90-6)

HNCS ** (RN-CAS Registry Number 3129-90-6)

9.94±0.02 (V) PE 3670

10.3+0.1 (V) PE 3670

13.31+0.02 (V) PE 3670

15.12+0.02 (V) PE 3670

C2H3NS CH3NCS ** (RN-CAS Registry Number 556-61-6)

9.37±0.02 (V) PE 3670

C,H,NS

C3H3NS **

(Isothiazole)

(RN-CAS Registry Number 288-16-4)

C3H3NS **

(Isothiazole)

(RN-CAS Registry Number 288-16-4)

C3H3NS **

(Isothiazole)

(RN-CAS Registry Number 288-16-4)

9.55

9.55

9.80

PE

PE

El

3587

3736

3587

c4h5ns+

c4h5 ns+

c4h5 ns+

c4h5 ns+

c4h5 ns+

C3H2NS(CH3) **

(Isothiazole, 3-methyl-)

(RN-CAS Registry Number 693-92-5)

C3H2NS(CH3) (Isothiazole, 4-methyl-)

(RN-CAS Registry Number 693-90-3)

C3H2NS(CH3) **

(Isothiazole, 4-methyl-)

(RN-CAS Registry Number 693-90-3)

C3H2NS(CH3) **

(Isothiazole, 4-methyl-)

(RN-CAS Registry Number 693-90-3)

C3H2NS(CH3) (Isothiazole, 5-methyl-)

(RN-CAS Registry Number 693-97-0)

9.60

9.25

9.25

9.65

9.65

El

PE

PE

El

El

3587

3587

3736

3587

3587

211
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c5 h3 ns + C4H3 SCN * * 9.83±0.05 El 3482

(2-Thiophenecarbonitrile)

(RN-CAS Registry Number 1003-31-2)

C5 H5 NS+ C5 H4N(SH) ** 8.92±0.02 El 3636

(2-Pyridinethiol)

(RN-CAS Registry Number 2637-34-5)

C5 H5 NS+ C5 H4N(SH) ** 9.41 ±0.02 El 3636

(3-Pyridinethiol)

(RN-CAS Registry Number 16133-26-9)

C5 H5 NS+ C5 H4N(SH) ** 9.50±0.02 El 3636

(4-Pyridinethiol)

(RN-CAS Registry Number 4556-23-4)

c6h7 ns+

c6h7 ns+

c6h7 ns +

c6h7 ns +

c6h7 ns +

C5 H4N(SCH3) **

(Pyridine, 2-(methylthio-)

(RN-CAS Registry Number 18438-38-5)

C5 H4N(SCH3) (Pyridine, 3-(methylthio)-)

(RN-CAS Registry Number 18794-33-7)

C5H4N(SCH3) **

(Pyridine, 4-(methylthio)-)

(RN-CAS Registry Number 22581-72-2)

C5 H4N(=S)CH3 **

(2(l//)-Pyridinethione, 1-methyl-)

(RN-CAS Registry Number 2044-27-1)

C5 H4N(=S)CH3 ** (4(l//)-Pyridinethione, 1 -methyl-)

(RN-CAS Registry Number 6887-59-8)

8.47 ±0.02 El 3636

8.93 ±0.02 El 3636

9.00±0.02 El 3636

7.84±0.02 El 3636

7.54±0.02 El 3636

CioH9NS + C6H5CH2(C3 H2 NS) ** 9.05 PE 3587

(Isothiazole, 4-(phenylmethyl)-)

(RN-CAS Registry Number 36412-26-7)

C10H9NS + C6H5CH2(C3 H2 NS) ** 9.35 El 3587

(Isothiazole, 4-(phenylmethyl)-)

(RN-CAS Registry Number 36412-26-7)

C10H9NS + C3 H2 NSCH2C6H5 ** 9.05 PE 3736

(Isothiazole, 4—(phenylmethyl)-)

(RN-CAS Registry Number 36412-26-7)

C12 H9NS + C12 H9NS ** 6.74±0.07 CTS 4079

( 1 0//-Phenothiazine)

(RN-CAS Registry Number 92-84-2)

C12 H9NS+ C12 H9NS ** 6.87 CTS 4035

( 10/f-Phenothiazine)

(RN-CAS Registry Number 92-84-2)

C13 Hu NS+ C12 H8 NSCH3 ** 6.73 ±0.07 CTS 4079

(10/f-Phenothiazine, 10-methyl-)

(RN-CAS Registry Number 1207-72-3)

212
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance Method Ref. products potential

(eV)

CjH6N2S+ C,H3N2SCH3 ** 8.92 (V) PE 4024

( 1 ,2,5-Thia(SIV)diazole, 3,4-dihydro-3-methyl-)

(RN-CAS Registry Number 24692-43-1)

c4h2n2s

+ C3H2NS(CN) ** 10.55 El 3587

(4-Isothiazolecarbonitrile)

(RN-CAS Registry Number 3912-37-6)

c4h8n2s

+ C,H2N2S(CH3)2 ** 9.62 (V) PE 4024

(1,2, 5-Thia(*SIV)diazole, 3,4-dihydro-3,3-dimethyl-)

(RN-CAS Registry Number 24692-45-3)

QH4N2S+ C6H4N2S ** 9.15 (V) PE 3852

( 1 ,2, 3-Benzothiadiazole)

(RN-CAS Registry Number 273-77-8)

C(;H4N2S

+ C6H4N2S ** 8.98 PE 4017

(2, 1

, 3-Benzothiadiazole)

(RN-CAS Registry Number 273-13-2)

QH4N2S

1 QH^S ** 9.00 (V) PE 3852

(2, 1, 3-Benzothiadiazole)

(RN-CAS Registry Number 273-13-2)

c8h,8n2s+ ((CH3)3CN)2S ** 8.65 (V) PE 4024

(RN-CAS Registry Number 2056-74-8)

C16H„N2S

+ C12H8NSCH2CH2N(CH3)2 ** 8.25 ±0.07 CTS 4079

( 1 0/7-Phenothiazine- 1 0-ethanamine, A,7V-dimethyl-)

(RN-CAS Registry Number 522-24-7)

(ON-Other name: Ethizine)

C„H20N2S

+ C12H8NS(CH2)3N(CH3)2 ** 8.22±0.07 CTS 4079

( 1 OH-Phenothiazine- 1 0-propanamine, 7V,7V-dimethyl-)

(RN-CAS Registry Number 58-40-2)

(ON-Other name: Promazine)

c18h22n2s

+ C12H8NSCH2CH2N(C2H5)2 ** 7.85±0.07 CTS 4079

( 1 077-Phenothiazine- 1 0-ethanamine, A^V-diethyl-)

(RN-CAS Registry Number 60-91-3)

(ON-Other name: Dinezine)

C2oH25N3S

+

C,2H8NS(CH2)3C4H8N2CH3 ** 6.87±0.07 CTS 4079

( 1 0/f-Phenothiazine, 1 0-[3-(4—methyl- 1 -piperazinyl)propyl]-)

(RN-CAS Registry Number 84-97-9)

(ON-Other name: Perazine)

so+

(

2n> SO(3 2T) ** 10.32 PE 3701

(RN-CAS Registry Number 13827-32-2)

(RD-Radical)

so+(*n) SO(

3 2T) ** -11.3 PE 3701

(RN-CAS Registry Number 13827-32-2)

(RD-Radical)

213
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SO +

(42~) SO(3 2‘) * 14.96 PE 3701

(RN-CAS Registry Number 13827-32-2)

(RD-Radical)

SO + SO ** 10.28±0.02 El 3816

(RN-CAS Registry Number 13827-32-2)

(RD-Radical)

SO + COS C 19.8 El 3779

(RN-CAS Registry Number 463-58-1)

S02fA.) so2 ** 12.3 PE 3865

(RN-CAS Registry Number 7446-09-5)

S02t

2 A,) so2 ** 12.31 PE 4092

(RN-CAS Registry Number 7446-09-5)

S02t

2 A,) so2 ** 12.50 (V) PE 3879

(RN-CAS Registry Number 7446-09-5)

S02t

2 A,) so2 ** 12.54 (V) PE 4024

(RN-CAS Registry Number 7446-09-5)

S02t

! A2) so2 ** 13.01 (V) PE 4092

(RN-CAS Registry Number 7446-09-5)

S02t

2A2) so2 ** 13.24 (V) PE 3879

(RN-CAS Registry Number 7446-09-5)

S02t

2Aj) so2 ** 13.25 (V) PE 4024

(RN-CAS Registry Number 7446-09-5)

S02fB2) so2 ** 13.30 (V) PE 4092

(RN-CAS Registry Number 7446-09-5)

S02t

2B2) so2 ** 13.47 (V) PE 3879

(RN-CAS Registry Number 7446-09-5)

S02t

2B2) so2 ** 13.56 (V) PE 4024

(RN-CAS Registry Number 7446-09-5)

S02fB,) so2 ** 15.99 PE 3879

SOjfBJ

(RN-CAS Registry Number 7446-09-5)

so2 ** 15.992±0.003 PE 3865

S02t

2 A,)

(RN-CAS Registry Number 7446-09-5)

so2 ** 16.324±0.004 PE 3865

(RN-CAS Registry Number 7446-09-5)

S02fA,) so2 ** 16.33 PE 3879

(RN-CAS Registry Number 7446-09-5)

S02fB,) so2 ** 16.498±0.004 PE 3865

S02fB,)

(RN-CAS Registry Number 7446-09-5)

so2 ** 16.57 (V) PE 4092

S02t

2 B,,2 B2) (RN-CAS Registry Number 7446-09-5)

so2 ** -16.6 (V) PE 4024

(RN-CAS Registry Number 7446-09-5)

S02fB2 , 2A,) so2 ** 16.65 (V) PE 4092

(RN-CAS Registry Number 7446-09-5)

SO^ so2 ** 20.06±0.05 PE 3865

(RN-CAS Registry Number 7446-09-5)

S20

+

(

2 A') s2o ** 10.52 PE 4092

s2 o-(2a’)

(RN-CAS Registry Number 20901-21-7)

s2o ** 10.53±0.02 PE 3841

(RN-CAS Registry Number 20901-21-7)

214
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

s2o+(2A')

S20

+

(

2A')

S20

+

(

2A')

s2o

+

(

2a

w )

S20

+

(

2A')

S20

+

(

2A')

S20

+

(

2A')

S20

+

(

2A')

S20

+

(

2A")

S20

+

(

2A')

SzO

+

(

2A')

S20

+

(

2A')

S20

+

(

2A

r

)

S20

+

(

2A')

S20

+

(

2A')

S20+

(

2A')

s2o

(RN-CAS Registry Number

sso

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

SSO

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

SSO

(RN-CAS Registry Number

SSO

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

s2o

(RN-CAS Registry Number

SSO

(RN-CAS Registry Number

SSO

(RN-CAS Registry Number

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

** 20901-21-7)

cos+(x2n) cos ** (RN-CAS Registry Number 463-58-1)

cos+(x2n3/2) cos ** (RN-CAS-Registry Number 463-58-1)

cos+(A2n) cos ** (RN-CAS Registry Number 463-58-1)

COS+(B22

+

) COS ** (RN-CAS Registry Number 463-58-1)

cos+(c2i: +

) cos ** (RN-CAS Registry Number 463-58-1)

COS+ COS ** (RN-CAS Registry Number 463-58-1)

CH2OS+ C3H6OS C2H4

( 1 , 3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

Ionization or appearance

potential

(eV)

Method Ref.

10.62 PE 3692

11.22 PE 4092

11.25±0.02 PE 3841

11.31 ±0.02 PE 3841

11.32 PE 3692

11.34 PE 4092

11.37 PE 3692

14.3±0.02 PE 3841

14.3 PE 3692

14.62 (V) PE 4092

14.84 (V) PE 4092

14.9±0.02 PE 3841

15.5+0.02 PE 3841

15.5 PE 3692

15.80 (V) PE 4092

18.50 (V) PE 4092

11.18+0.01 PE 3965

11.22 PE 4073

15.09±0.01 PE 3965

16.05+0.01 PE 3965

17.96+0.01 PE 3965

11.3 El 3779

10.4±0.3 El 3598

215
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C2 H4OS + C2 H4SO

* 9.66 (V) PE 3646

(Thiirane, 1 -oxide)

(RN-CAS Registry Number 7117-41-1)

c2 h6os+ (CH3)2 SO ** 9.01 (V) PE 3646

(RN-CAS Registry Number 67-68-5)

c2 h6os+ (CH3)2 SO ** 9.11 (V) PE 3705

(RN-CAS Registry Number 67-68-5)

c2 h6os+ (CH3)2 SO ** 9.20±0.05 El 3498

(Sulfinylbis(methane))

(RN-CAS Registry Number 67-68-5)

C3 H5OS+ c3 h6os h

( 1 , 3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

10.8±0.1 El 3598

c3 h6os+ C3 H6OS **

( 1

, 3-Oxathiolane)

(RN-CAS Registry Number 2094-97-5)

9±0.05 El 3598

C4Hg OS+ C4H8OS ** (1,4-Oxathiane)

(RN-CAS Registry Number 15980-15-1)

c4h8 os+ c4h8 so ** (Thiophene, tetrahydro-1 -oxide)

(RN-CAS Registry Number 1600-44—8)

c4h8os+ c4h8 so ** (Thiophene, tetrahydro-, 1 -oxide)

(RN-CAS Registry Number 1600-44—8)

c4h8os+ c5h10o2s hcho

(1,3,6-Dioxathiocane)

(RN-CAS Registry Number 2094-92-0)

(MT-Metastable transition(s) observed)

(TR-Other product(s) thermochemically reasonable)

8.67 (V) PE 3733

8.77 (V) PE 3646

9.07 ±0.05 El 3498

9.1 ±0.01 El 3903

c4 h10os+ (CH3 CH2)2SO ** (RN-CAS Registry Number 70-29-1)

8.76 (V) PE 3646

c5 h4os+ C4H3 SCHO ** (2-Thiophenecarboxaldehyde)

(RN-CAS Registry Number 98-03-3)

9.55±0.05 El 3482

c5 h6os + C4H3 SOCH3 ** (Thiophene, 2-methoxy-)

(RN-CAS Registry Number 16839-97-7)

8.30±0.05 El 3482

c6h6os+ C4H3 SCOCH3 ** 9.20±0.05 El 3482

(Ethanone, 1 -(2-thienyl)-)

(RN-CAS Registry Number 88-15-3)
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c6h6os+ c4h3 scoch3 ** (Ethanone, 1 -(3-thienyl)-)

(RN-CAS Registry Number 1468-83-3)

9.32±0.05 El 3482

c6huos+ C4H5OS(CH3)3 ch3 (1,3-Oxathiane, 2,4,6-trimethyl-, (2a,4a, 6a)-)

(RN-CAS Registry Number 22521-88-6)

8.54±0.01 El 3803

<^H„OS+ C4H5OS(CH3)3 ch3 (1,3-Oxathiane, 2,4,6-trimethyl-, (2a,4a,6/3)-)

(RN-CAS Registry Number 22425-91-8)

8.67 El 3803

c6h,,os + C4H5OS(CH3)3 ch3 (1,3-Oxathiane, 2,4,6-trimethyl-, (2a,4/3, 6a)-)

(RN-CAS Registry Number 22425-90-7)

8.64 El 3803

c6h,2os+ C4H6OS(CH3)2 (1,3-Oxathiane, 4,6-dimethyl-, cis-)

(RN-CAS Registry Number 22452-25-1)

8.75 El 3803

c6h12os+ C4H6OS(CH3)2 (1,3-Oxathiane, 4,6-dimethyl-, trans-)

(RN-CAS Registry Number 22452-26-2)

8.67±0.01 El 3803

c6H14os ((CH3)2CH)2SO ** (RN-CAS Registry Number 2211-89-4)

8.46 (V) PE 3646

C7H13OS+

C7H13OS+

C4H4OS(CH3)4 ch3 (1,3-Oxathiane, 2,2,4,6-tetramethyl-, cis-)

(RN-CAS Registry Number 34560-79-7)

C4H4OS(CH3)4 ch3 (1,3-Oxathiane, 2,2,4,6-tetramethyl, trans-)

(RN-CAS Registry Number 34560-78-6)

8.63±0.01

8.54±0.01

El

El

3803

3803

C^H^OS* C4H5OS(CH3)3 (1,3-Oxathiane, 2,4,6-trimethyl-, (2a,4a, 6a)-)

(RN-CAS Registry Number 22521-88-6)

8.55 El 3803

c7h14os+ C4H5OS(CH3)3 ** (1,3-Oxathiane, 2,4,6-trimethyl-, (2a,4a, 6/3)-)

(RN-CAS Registry Number 22425-91-8)

8.54 El 3803

c7h14os+ C4H5OS(CH3)3 (1,3-Oxathiane, 2,4,6-trimethyl-, (2a,4/3, 6a)-)

(RN-CAS Registry Number 22425-90-7)

8.58 El 3803

c„h16os+ C4H4OS(CH3)4 ** (1,3-Oxathiane, 2,2,4,6-tetramethyl-, cis-)

(RN-CAS Registry Number 34560-79-7)

8.48±0.02 El 3803

c„hI6os+ C4H4OS(CH3)4 ** (1,3-Oxathiane, 2,2,4,6-tetramethyl, trans-)

(RN-CAS Registry Number 34560-78-6)

8.45±0.01 El 3803

c„h18os+ ((CH3)3 C)2 SO

(RN-CAS Registry Number 2211-92-9)

8.18 (V) PE 3646

217
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

cI2 h10os+ (C6H5 )2 SO

(RN-CAS Registry Number 945-51-7)

9.02±0.05 El 3498

c2 h6o2 s

+ (CH3)2 so2 (RN-CAS Registry Number 67-71-0)

10.80 (V) PE 3993

C2H6o2 s

+ (ch3)2 so2 (RN-CAS Registry Number 67-71-0)

10.97 (V) PE 3705

c3 h6so2+ CH2 =CHS(CH3 )02 ** (RN-CAS Registry Number 3680-02-2)

10.82 (V) PE 3993

c4h6so2+ (c2h3)2so2 (RN-CAS Registry Number 77-77-0)

10.62 (V) PE 3993

c5 h4o2 s

+ C4H3 SCOOH ** (2-Thiophenecarboxylic acid)

(RN-CAS Registry Number 527-72-0)

9.35 El 3804

c5 h10o2 s

+ c5 H10o2s

( 1 ,3,6-Dioxathiocane)

(RN-CAS Registry Number 2094-92-0)

8.67±0.05 El 3903

c6h6o2 s

+ C4H3 SCOOCH3 ** (2-Thiophenecarboxylic acid, methyl ester)

(RN-CAS Registry Number 5380-42-7)

9.22±0.05 El 3482

c14 h9o2 s

+ C6H4(COSC6H5)2 c6h5 s

(1,2-Benzenedicarbothioic acid SyS-diphenyl ester)

(RN-CAS-Registry Number 42797-33-1)

10.3±0.2 El 4062

c14h9o2s

+ C8 H40( =0)(SC6H5)2 c6h5 s

(l(3//)-Isobenzofuranone, 3,3-bis(phenylthio)-)

(RN-CAS-Registry Number 4792-31-8)

10.3±0.2 El 4062

c15 h„o2s

+ C6H4(COSC6H4CH3)2 C6H4(S)CH3 10.1 ±0.2

(1,2-Benzenedicarbothioic acid S^S-bis(4-methylphenyl)ester)

(RN-CAS-Registry Number 42797-34-2)

El 4062

c15 huo2 s

+ C8 H40(=0)(SC6H4CH3)2 C6H4(S)CH3 9.9±0.2 El 4062

( 1 (3//)-Isobenzofuranone, 3,3-bis[(4-methylphenyl)thio]-)

(RN-CAS-Registry Number 42797-36-4)

C2H403 S

+ C2H402 S0 ** 10.93 (V) PE 3646

(1,3,2-Dioxathiolane 2-oxide)

(RN-CAS Registry Number 3741-38-6)

C2H403 S

+ CjH^SO ** 10.30±0.05 El 3498

(1,3,2-Dioxathiolane 2-oxide)

(RN-CAS Registry Number 3741-38-6)

C2H603 S

+ (CH30)2 S0 ** 10.25 (V) PE 3646

(RN-CAS Registry Number 616-42-2)

218
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance Method Ref. products potential

(eV)

C4H3 NSO+ C3H2NS(CHO) ** 10.25 El 3587

(5-Isothiazolecarboxaldehyde)

(RN-CAS Registry Number 5242-57-9)

c4h9nos+ (CH3)3 CNSO ** 10.54 (V) PE 4024

(RN-CAS Registry Number38662-39-4)

c6h7nos+ C5 H2NH(=S)(OH)CH3 ** 8.04±0.05 El 3635

(2( l/7)-Pyridinethione, 3-hydroxy-6-methyl-)

(RN-CAS Registry Number 22989-67-9)

c6h7nos+ C5H3N(OH)SCH3 ** 8.53+0.05 El 3977

(3-Pyridinol, 2-(methylthio)-)

(RN-CAS Registry Number 32637-37-9)

C6HuNOS+ C6HnNSO ** ~10.0(V) PE 4024

(Cyclohexanamine, 7V-sulfinyl-)

(RN-CAS Registry Number 30980-11-1)

C7H5NOS+ C7H5NS(0) ** 6.92+0.05 El 3977

(Thiazolo[3,2-a]pyridinium, 3-hydroxy-, hydroxide, inner salt) (RN-CAS Registry Number 42715-25-3)

C^NOS* C5H2N(OH)(CH3)SCH3 ** 8.24+0.05 El 3635

(3-Pyridinol, 6-methyl-2-(methylthio)-)

(RN-CAS Registry Number 23003-25-0)

C8H7NOS+ C7H4NS(0)CH3 ** 6.82+0.05 El 3977

(Thiazolo[3,2-a]pyridinium, 3-hydroxy-2-methyl-, hydroxide, inner salt) (RN-CAS Registry Number 35143-56-7)

c8h7nos+ C7H4NS(0)CH3 ** 7.03+0.05 El 3635

(Thiazolo[3,2-a]pyridinium, 8-hydroxy-5-methyl-, hydroxide, inner salt) (RN-CAS Registry Number 30277-17-9)

c8h9nos+ C7H6NOS(CH3) ** 8.03+0.05 El 3635

( 1 ,4-Oxathiino[3,2-6]pyridine, 2, 3-dihydro-6-methyl-)

(RN-CAS Registry Number 35688-70-1)

c8h9nos+ C5H2N(=S)(OH)(CH3)C2H3 ** 7.73+0.05 El 3635

(2( l//)-Pyridinethione, 1 -ethenyl-3-hydroxy-6-methyl-)

(RN-CAS Registry Number 35688-69-8)

c8h9nos+ C7H6NS(0)CH3 ** 7.35 ±0.05 El 3635

(Thiazolo[3,2-a]pyridinium, 2,3-dihydro-8-hydroxy-5-methyl-, hydroxide, inner salt) (RN-CAS Registry Number 23003-43-2)

c8h„nos+ C5H2N(=S)(OH)(CH3)C2H5 ** 7.75+0.05 El 3635

(2( l//)-Pyridinethione, 1 -ethyl-3-hydroxy-6-methyl-)

(RN-CAS Registry Number 24207-15-6)

c13h9nos+ CyH^S^CeHs ** 6.70+0.05 El 3977

(Thiazolo[3,2-a]pyridinium, 3-hydroxy-2-phenyl-, hydroxide, inner salt) (RN-CAS Registry Number 32044-03-4)

219
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance Method

potential

(eV)

Ref.

C3 H2 N2 OS + C3 H2 NSNO **

(Isothiazole, 4-nitro-)

(RN-CAS Registry Number 931-07-7)

10.45 PE 3736

c4 h12 n2 os+ ((CH3 )2N)2 SO

(RN-CAS Registry Number 3768-60-3)

8.53 (V) PE 3646

c17 h18 n2os + C12 H8 NSCOCH2 CH2 N(CH3 )2 ** 8.26±0.07

(10//-Phenothiazine, 10-[3-(dimethylamino)-l-oxopropyl]-)

(RN-CAS Registry Number 3576-44-1)

CTS 4079

c18 h22n2os+ C12 H7 NS(OCH3 )CH2 CH(CH3 )N(CH3 )2 ** 8.18±0.07

(1077-Phenothiazine-10-ethanamine, 2-methoxy-7V,./V,a-trimethyl-)

(RN-CAS Registry Number 7624-74-0)

(ON-Other name: Thisercine)

CTS 4079

c19 h22n2os+ C12 H8 NSCOCH2CH2 N(C2 H5)2 ** (107/-Phenothiazine, 10-[3-(diethylamino)-

(RN-CAS Registry Number 3576-47-4)

(ON-Other name: Acizine)

7.85±0.07

1-oxopropyl]-)

CTS 4079

c20h24n2os+ C12 H8 NSCO(CH2)3 N(C2 H5)2 **

( 1 0/7-Phenothiazine, 1 0-[4-(diethylamino)-

(RN-CAS Registry Number 51307-45-0)

7.88±0.07

1-oxobutyl]-)

CTS 4079

c19h23 n3os+ C12 H7 NS(CH3 )NHCOCH2 N(C2 H5)

[2* 7. 1 3 ±0.07

(Acetamide, 2-(diethylamino)-7V-(l 0-methyl- 10/f-phenothiazin-3-yl)-)

(RN-CAS Registry Number 1952-62-1)

CTS 4079

C22 h27n3 os+ C22H27N3OS ** 9.05 ±0.07 CTS

(Ethanone, 1 -[ 1 0-[3-(4-methy1- 1 -piperazinyl)propyl]- 1 0//-phenothiazin-2-yl]-)

(RN-CAS Registry Number 1053-74-3)

4079

c23h29n3 os + C23H29N3OS ** 9.08 ±0.07 CTS

( 1 -Propanone, 1 -[ 1 0-[3-(4-methyl- 1 -piperazinyl)propyl]- 1 0//-phenothiazin-2-yl]-)

(RN-CAS Registry Number 20686-45-7)

4079

c3 h7 no2 s

+ SHCH2CH(NH2)COOH ** (RN-CAS Registry Number 3374-22-9)

~9 PI 3766

c4h3 no2 s

+ c4h3 sno2 ** (Thiophene, 2-nitro-)

(RN-CAS Registry Number 609-40-5)

9.77±0.05 El 3482

c5 hu no2 s

+ CH3 SCH2 CH2CH(NH2)COOH ** (RN-CAS Registry Number 59-51-8)

~9 PI 3766

c7 h5 no2 s

+ C7H4NS(0)0H ** (Thiazolo[3,2-fl]pyridinium, 3,8-dihydroxy-

(RN-CAS Registry Number 35143-55-6)

8.70±0.05

-, hydroxide, inner salt) El 3977

220
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c8 h7 no2 s

+ C7H3 NS(0)(0H)CH3 ** 8.60±0.05 El 3977

(Thiazolo[3,2-a]pyridinium, 3,8-dihydroxy-2-methyl-, hydroxide, inner salt) (RN-CAS Registry Number 35191-20-9)

C8H9 N02 S

+ C5 H3 N(SCH3)OCOCH3 ** 7.91+0.05 El 3977

(3-Pyridinol, 2-(methylthio)- acetate (ester)) (RN-CAS Registry Number 42715-30-0)

C13H9N02 S

+ C7H3 NS(0)(0H)C6H5 ** 8.42+0.05 El 3977

(Thiazolo[3,2-a]pyridinium, 3,8-dihydroxy-2-phenyl-, hydroxide, inner salt) (RN-CAS Registry Number 35143-57-8)

C3H2 N202 S

+ C3 H2NS(N02) ** 10.45 PE 3587

(Isothiazole, 4-nitro-)

(RN-CAS Registry Number 931-07-7)

C3 H2N2 02 S

+ C3 H2NS(N02) ** 10.80 El 3587

(Isothiazole, 4-nitro-)

(RN-CAS Registry Number 931-07-7)

C15HnN03 S

+ C7H3 NOS(OCOCH3)C6H5 ** 6.27±0.05 El 3977

(Thiazolo[3,2-a]pyridinium, 8-(acetyloxy)-3-hydroxy-2-phenyl-, hydroxide, inner salt) (RN-CAS Registry Number 32002-92-9)

C22H30N4O2 S2+ C22H30N4O2 S2 ** 6.81 ±0.07 CTS 4079

( 1 0//-Phenothiazine-2-sulfonamide, 7V,vV-dimethyl- 1 0[3-(4-methyl- 1 -piperazinyl)propy1]-) (RN-CAS Registry Number 316-81-4)

(ON-Other name: Majeptil)

SF+

(RD-Radical)

SF+

SF ** (RN-CAS Registry Number 16068-96-5)

SF6 (RN-CAS Registry Number 2551-62-4)

10.09±0.10

30.5+0.5

El

El

3818

3818

sf2+

(RD-Radical)

SF2 ** (RN-CAS Registry Number 13814-25-0)

10.29±0.10 El 3818

sf2+ sf4 (RN-CAS Registry Number 7783-60-0)

17.4±0.5 El 3818

sf2+ sf6 (RN-CAS Registry Number 2551-62-4)

27.5+0.5 El 3818

sf2+

s2f2 (RN-CAS Registry Number 13709-35-8)

16.2+0.4 El 3738

sf3+ sf4 f

(RN-CAS Registry Number 7783-60-0)

12.63+0.10 El 3818

sf3+ sf6 (RN-CAS Registry Number 2551-62-4)

20.0+0.5 El 3818

sf4+ SF4 ** (RN-CAS Registry Number 7783-60-0)

12.03+0.05 El 3578

221
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

sf4+ SF4 ** (RN-CAS Registry Number 7783-60-0)

12.08±0.10 El 3818

sf4+ SF6 2F

(RN-CAS Registry Number 2551-62-4)

18.44±0. 10 El 3818

sf5+ sf6 f

(RN-CAS Registry Number 2551-62-4)

15.50±0.10 El 3818

s2 f

+ S2 F2 (RN-CAS Registry Number 13709-35-8)

14.0±0.4 El 3738

s2 f2+ S2F2 (RN-CAS Registry Number 13709-35-8)

1 1.6±0.4 El 3738

CFjS»(2 B2) CF2 S

+

(

2 B2>

F,CS

(RN-CAS Registry Number 420-32-6)

f2cs ** (RN-CAS Registry Number 420-32-6)

(HB-Threshold value approximately corrected for hot bands)

csf2+ f2cs

cf2 s

+

(

2b,)

(RN-CAS Registry

f2cs

cf2s

+

(

2 b,)

(RN-CAS Registry

f2 cs

cf2s

+

(

2a,)

(RN-CAS Registry

f2cs

cf2 s

+ * (RN-CAS Registry

f2 cs

(RN-CAS Registry

(HB-Threshold value approximately corrected for hot bands)

2 s

+ * f2cs ** (RN-CAS Registry Number 420-32-6)

f2cs ** (RN-CAS Registry Number 420-32-6)

f2cs ** (RN-CAS Registry Number 420-32-6)

f2cs ** (RN-CAS Registry Number 420-32-6)

F2CS ** (RN-CAS Registry Number 420-32-6)

f2 cs ** (RN-CAS Registry Number 420-32-6)

f2cs ** (RN-CAS Registry Number 420-32-6)

cf2s

+ * cf2 s

+ * cf2 s

+

(

2 b,)

cf2 s

+ * cf2 s

+ *

10.45±0.01 PE 3708

10.52 PE 4080

10.64 (V) PE 3746

1 1.34±0.01 PE 3708

11.39 PE 4080

14.87 PE 3708

14.91 PE 4080

15.87 (V) PE 4080

16.48 (V) PE 4080

17.65 PE 3708

17.67 (V) PE 4080

18.76 (V) PE 4080

19.20 (V) PE 4080

10.53±0.10 El 3818

1 1.49±0.02 PE 3665

1 1.54±0.01 PE 3666

11.82 (V) PE 3518

NSF+

(

2 A')

NSF+

(

2 A')

NSF+

(

2A')

NSF ** (RN-CAS Registry Number 18820-63-8)

NSF ** (RN-CAS Registry Number 18820-63-8)

NSF ** (RN-CAS Registry Number 18820-63-8)

222
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

NSF+

(

2A') NSF ** 11.82 (V) PE 3660

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 13.382+0.004 PE 3666

(RN-CAS Registry Number 18820-63-8)

(HB-Threshold value approximately corrected for hot bands)

NSF+

(

2A') NSF ** 13.39±0.02 PE 3665

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 13.50 (V) PE 3518

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 13.50 (V) PE 3660

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A") NSF ** 13.775+0.005 PE 3666

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A") NSF ** 13.78+0.02 PE 3665

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A") NSF ** 13.87 (V) PE 3518

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A

w

) NSF ** 13.87 (V) PE 3660

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 14.93+0.01 PE 3666

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 15.35+0.02 PE 3665

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 15.61 (V) PE 3518

(RN-CAS Registry Number 18820-63-8)

NSF+

(2A') NSF ** 15.61 (V) PE 3660

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A',

2A") NSF ** ~ 16.3 PE 3665

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A') NSF ** 16.47 (V) PE 3518

(RN-CAS Registry Number 18820-63-8)

NSF+

(

2A

w

) NSF ** 16.56+0.03 (V) PE 3666

NSF+

(

2A')

(RN-CAS Registry Number 18820-63-8)

NSF ** 17.24+0.08 (V) PE 3666

NSF+

(

2A')

(RN-CAS Registry Number 18820-63-8)

NSF ** 21.1+0.1 (V) PE 3666

(RN-CAS Registry Number 18820-63-8)

NSF3t

2E) nsf3 ** 12.50 (V) PE 3660

(RN-CAS Registry Number 15930-75-3)

NSFjfA,) nsf3 ** 14.15 (V) PE 3660

(RN-CAS Registry Number 15930-75-3)

NSF3t

2 E) nsf3 ** 16.65 (V) PE 3660

(RN-CAS Registry Number 15930-75-3)

NSF3fA2?) nsf3 ** 18.35 (V) PE 3660

(RN-CAS Registry Number 15930-75-3)

c21 h24n3f3 s

+ C12H7NS(CF3)(CH2)3 C4H8N2CH3 ** 7.10+0.07 CTS 4079

( 1 Oi/-Phenothiazine, 1 0-[3-(4-methy1- 1 -piperazinyl)propyl]-2-(trifluoromethyl)-)

(RN-CAS Registry Number 1 17-89-5)

(ON-Other name: Triphthazine)

223
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

so] f

+

(

2 a2) SOjF ** 12.85±0.1 (V) PE 3671

(RN-CAS Registry Number 21549-02-0)

(RD-Radical)

SOF2t

2 A') sof2 ** 12.19 PE 3705

(RN-CAS Registry Number 7783-42-8)

SOF2t

2 A') sof2 ** 12.25 PE 3879

(RN-CAS Registry Number 7783-42-8)

sof2+ sof2 ** 12.58 (V) PE 3646

(RN-CAS Registry Number 7783-42-8)

SOF2t

2 A') sof2 ** 12.6 (V) PE 3694

(RN-CAS Registry Number 7783-42-8)

SOF2t

2 A") sof2 ** — 1 3.4 PE 3879

(RN-CAS Registry Number 7783-42-8)

SOF2t

2 A

w

) sof2 ** 14.04 (V) PE 3705

(RN-CAS Registry Number 7783-42-8)

SOF2t

2 A") sof2 ** 14.14 (V) PE 3694

(RN-CAS Registry Number 7783-42-8)

SOF2t

2A') sof2 ** 14.54 PE 3705

SOF2t

2A")

(RN-CAS Registry Number 7783-42-8)

sof2 ** 14.55 PE 3879

(RN-CAS Registry Number 7783-42-8)

SOF2t

2 A') sof2 ** 14.8 (V) PE 3694

SOF2t

2 A')

(RN-CAS Registry Number 7783-42-8)

sof2 ** 16.2 (V) PE 3694

(RN-CAS Registry Number 7783-42-8)

SOF^ sof2 ** 16.4 (V) PE 3705

SOF2t

2 A")

(RN-CAS Registry Number 7783-42-8)

sof2 ** 16.6 (V) PE 3879

(RN-CAS Registry Number 7783-42-8)

SOF^ sof2 ** 16.97 (V) PE 3705

SOF2t

2 A")

(RN-CAS Registry Number 7783-42-8)

sof2 ** 17.0 (V) PE 3694

SOF2t

2 A')

(RN-CAS Registry Number 7783-42-8)

sof2 ** 17.0 (V) PE 3879

(RN-CAS Registry Number 7783-42-8)

SOF^ sof2 ** 18.03 PE 3705

(RN-CAS Registry Number 7783-42-8)

sof2+ sof2 ** 12.58±0.10 El 3818

(RN-CAS Registry Number 7783-42-8)

S02 F2t

2B2) so2 f2 ** — 1 3.0 PE 3879

S02F2t

2 B2 ) (RN-CAS Registry Number 2699-79-8)

so2 f2 ** 13.04±0.01 PE 3675

so; f2x

2 a2) (RN-CAS Registry Number 2699-79-8)

so2f2 ** 13.43 (V) PE 3705

so2 f2x

2 a2) (RN-CAS Registry Number 2699-79-8)

so2 f2 ** 13.55 PE 3879

S02 F2t

2 B,)

(RN-CAS Registry Number 2699-79-8)

so2 f2 ** 13.55 (V) PE 3694

(RN-CAS Registry Number 2699-79-8)

224
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

S02F2fA2) so2f2 ** (RN-CAS Registry Number 2699-79-8)

13.57±0.02 PE 3675

S02F2t

2A2) so2f2 ** 13.61 (V) PE 3694

(RN-CAS Registry Number 2699-79-8)

S02F2t

2 B2) so2f2 ** 13.78 (V) PE 3705

(RN-CAS Registry Number 2699-79-8)

S02F2t

2A,) so2f2 ** 14.8 PE 3705

(RN-CAS Registry Number 2699-79-8)

S02 F2fB,) so2f2 ** 14.85±0.01 PE 3675

S02F2t

2B,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 14.89 PE 3879

(RN-CAS Registry Number 2699-79-8)

S02 F2fB2) so2f2 ** 15.18 (V) PE 3694

S02F2t

2A,)

(RN-CAS Registry Number 2699-79-8)

so2f2 15. 181 ±0.006 PE 3675

SO,F2t

2A,)

(RN-CAS Registry Number 2699-79-8)

so2F2 15.23 PE 3879

S02F2t

2B,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 15.30 (V) PE 3705

SOjF.fAJ

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 15.35 (V) PE 3694

S02 F2fB2) (RN-CAS Registry Number 2699-79-8)

so2f2 ** (RN-CAS Registry Number 2699-79-8)

16.676±0.005 PE 3675

(HB-Threshold value approximately corrected for hot bands)

SO.F* so2f2 ** 16.68 PE 3705

S02F2t

2A,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 16.68 PE 3879

S02F2t

2A,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 16.68 (V) PE 3694

S02F2t

2B,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 17.89 PE 3879

S02F2fB,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 18.07±0.03 PE 3675

(RN-CAS Registry Number 2699-79-8)

SO,F,** so2f2 ** 18.29 (V) PE 3705

S02 F2t

2 B2 ) (RN-CAS Registry Number 2699-79-8)

so2f2 ** 18.34 (V) PE 3694

S02 F2t

2B2) (RN-CAS Registry Number 2699-79-8)

so2f2 ** 19.175±0.007 PE 3675

S02F2fA,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 19.699±0.007 PE 3675

S02F2t

2 B2) (RN-CAS Registry Number 2699-79-8)

so2f2 19.70 PE 3879

(RN-CAS Registry Number 2699-79-8)

S()2 F.'* so2F2 19.80 (V) PE 3705

(RN-CAS Registry Number 2699-79-8)

SO,FT* so2f2 ** 19.89 (V) PE 3694

S02F2t

2 A,)

(RN-CAS Registry Number 2699-79-8)

so2f2 ** 20.5 PE 3879

(RN-CAS Registry Number 2699-79-8)

225
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

so2f2* so2 f2 ** (RN-CAS Registry Number 2699-79-8)

~21 (V) PE 3694

S02 F2t

2A,) so2 f2 ** (RN-CAS Registry Number 2699-79-8)

24.2 ±0.1 (V) PE 3675

S02 F2t

2B,) so2 f2 ** (RN-CAS Registry Number 2699-79-8)

27.7 ±0.1 (V) PE 3675

ch3o2 fs+ ch3 so2 f ** (RN-CAS Registry Number 558-25-8)12.61 (V) PE 3705

C6HjOF3 S

+ C4H3 SCOCF3 ** (Ethanone, 2,2,2-trifluoro-l-(2-thienyl)-)

(RN-CAS Registry Number 651-70-7)

9.70±0.05 El 3482

c6h3of3 s

+ C4H3 SCOCF3 ** (Ethanone, 2,2,2-trifluoro- 1 -(3-thienyl)-)

(RN-CAS Registry Number 30933-31-4)

9.63±0.05 El 3482

C2oH2I N20F3 S

+ C12H7 NS(CF3)COCH2CH2N(C2H5^ 7.89±0.07 CTS 4079

(1077-Phenothiazine, 10-[3-(diethylamino)-l-oxopropyl]-2-(trifluoromethyl)-)

(RN-CAS Registry Number 30223-48-4)

(ON-Other name: Fluoracizine)

C22H26N3OF3S + C22H26N3OF3 S ** 8.64+0.07 CTS 4079

( 1 -Piperazineethanol, 4-[3-[2-(trifluoromethyl)- 10//-phenothiazin- 1 0-yl]propyl]-)

(RN-CAS Registry Number 69-23-8)

(ON-Other name: Fluorphenazine)

C20H I9N2O2 F3 S

+ C12H7 NS(CF3)COCH2CH2C4H8NO* 8.54±0.07 CTS 4079

( 1 0/f-Phenothiazine, 1 0-[3-(4-morpholinyl)- 1 -oxopropyl]-2-(trifluoromethyl)-)

(RN-CAS Registry Number 33414-29-8)

C22H24N3 02F3 S

+ C22H24N302F3 S ** 8.71 ±0.07 CTS 4079

( 1 0/f-Phenothiazine, 1 0-[3-[4-(2-hydroxyethyl)- 1 -piperazinyl]- 1 -oxopropyl]-2-(trifluoromet

hyl)-)

(RN-CAS Registry Number 33414-36-7)

SiH4S

+

(

2A") SiH3 SH ** 9.97 (V) PE 3656

(RN-CAS Registry Number 14044-97-4)

(SiH3)2 S ** 9.59 (V) PE 3867

(RN-CAS Registry Number 16544-95-9)

(SiH3)2S ** 9.70 (V) PE 3656

(RN-CAS Registry Number 16544-95-9)

CH6SiS + CH3 SSiH3 ** (RN-CAS Registry Number 16643-15-5)

9.10 (V) PE 3867

CH3 NSiS + SiH3 NCS ** (RN-CAS Registry Number 14311-54-7)

9.54±0.02 (V) PE 3670

Si2H6S

+

Si2H6S

+

(

2 B,)

226
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C4H9NSiS + (CH3)3 SiNCS ** (RN-CAS Registry Number 2290-65-5)

9.3±0.1 (V) PE 3670

PS+ PS ** (RN-CAS Registry Number 12281-36-6)

9.0 El 4001

P4S

+ P4S** (RN-CAS Registry Number XXXXX-XX-X)

10.6+0.5 El 3615

P4S2+ P4S2 (RN-CAS Registry Number 12165-70-7)

10.6+0.5 El 3615

P4S3+ P4S3 (RN-CAS Registry Number 1314-85-8)

9.7+0.5 El 3615

p4s4+ P4S4 (RN-CAS Registry Number XXXXX-XX-X)

10.1+0.5 El 3615

P4S5+ p4s5 (RN-CAS Registry Number 12137-70-1)

10.4+0.5 El 3615

p4s6+ P4S6 (RN-CAS Registry Number XXXXX-XX-X)

10.0+0.5 El 3615

P4S7+ P4S7 (RN-CAS Registry Number 12037-82-0)

10.1+0.5 El 3615

p4s8+ pc ** r4^8 (RN-CAS Registry Number 37295-14-0)9.8+0.5 El 3615

P4S9+ pc ** r4a9 (RN-CAS Registry Number 25070-46-6)

9. 8+0.5 El 3615

P4Sf0 pcr **

4a10 (RN-CAS Registry Number 12066-62-5)

9.6+0.5 El 3615

CH2PS + (CH30)2P(CH3 S)S h+hcho+hs

(RN-CAS Registry Number 2953-29-9)

(MT-Metastable transition(s) observed)

14.05+0.30 El 3989

c6h1!n3 ps + PS(N(CH3)2)3 (RN-CAS Registry Number 3732-82-9)

7.66+0.003 PE 4086

C2H6OPS+ (CH30)2P(CH3 S)S hcho+hs

(RN-CAS Registry Number 2953-29-9)

(MT-Metastable transition(s) observed)

11.70+0.20 El 3989

C2H602PS + (CH30)2P(CH3 S)0 ch3o

(RN-CAS Registry Number 152-20-5)

C2H602PS + (CH30)2P(CH3 S)S ch3 s (RN-CAS Registry Number 2953-29-9)

(MT-Metastable transition(s) observed)

11.82+0.20

10.10±0.10

El

El

3989

3989

227
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

C2 H602 PS + (CH3 S)2 P(CH30)0 CH3 S 10.50±0.10 El 3989

(RN-CAS Registry Number 22608-53-3)

C2 H702 PS + (CH3 0)2 P(CH3 S)0 hcho

(RN-CAS Registry Number 152-20-5)

(MT-Metastable transition(s) observed)

C2 H702 PS + (CH3 0)2 P(CH3 S)S hchs

(RN-CAS Registry Number 2953-29-9)

C2 H702 PS + (CH3 S)2 P(CH30)0 hchs

(RN-CAS Registry Number 22608-53-3)

(MT-Metastable transition(s) observed)

C2 H603 PS + (CH3 0)2 P(CH3 S)0 CH3 10.03 ±0.10 El 3989

(RN-CAS Registry Number 152-20-5)

(MT-Metastable transition(s) observed)

C3 H903 PS + (CH30)2 P(CH3 S)0 ** 9.55+0.10 El 3989

(RN-CAS Registry Number 152-20-5)

(CH3 0)2P(CH3 S)S CH30 10.20±0.30 El 3989

(RN-CAS Registry Number 2953-29-9)

(CH3 S)2 P(CH30)0 CH30 10.15+0.10 El 3989

(RN-CAS Registry Number 22608-53-3)

C2H7OPS2+ (CH30)2P(CH3 S)S hcho

(RN-CAS Registry Number 2953-29-9)

(MT-Metastable transition(s) observed)

C2H7OPS2+ (CH3 S)2 P(CH30)0 hcho

(RN-CAS Registry Number 22608-53-3)

(MT-Metastable transition(s) observed)

C2H602 PS2+ (CH3 0)2P(CH3 S)S ch3 (RN-CAS Registry Number 2953-29-9)

C2 H602 PS2+ (CH3 S)2 P(CH3 0)0 ch3 (RN-CAS Registry Number 22608-53-3)

(MT-Metastable transition(s) observed)

C3 H902 PS2+ (CH30)2 P(CH3 S)S ** (RN-CAS Registry Number 2953-29-9)

C3 H902 PS2+ (CH3 S)2 P(CH30)0 ** (RN-CAS Registry Number 22608-53-3)

CNF2 PS + PF2NCS ** 10.2 ±0.1 (V) PE 3662

(RN-CAS Registry Number 461-60-9)

Cl + CH2C12 CH2C1 17.4 RPD 3490

(RN-CAS Registry Number 75-09-2)

(AD-0.219 eV average translational energy of decomposition at threshold)

(TR-Other product(s) thermochemically reasonable)

9.65±0.20 El 3989

9.47 ±0.10 El 3989

9.0±0.10 El 3989

9.20±0.10 El 3989

10.00±0.10 El 3989

9.90±0.20 El 3989

C2 H6OPS2+ C2 H6OPS2+

10.51±0.10 El 3989

10.35±0.10 El 3989

10.10±0.10 El 3989

228
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

Cl + ch2ci2 ch2ci 17.4±0.1 El 3442

(RN-CAS Registry Number 75-09-2)

(AD-0.22 eV average translational energy of decomposition at threshold)

(TR-Other product(s) thermochemically reasonable)

cr Ag3 Cl3 ~ 15.5 El 3605

(RN-CAS Registry Number 12444-97-2)

Cl +2 Cl + ** 23.8137zh0.0002 S 3756

(RN-CAS Registry Number 14835-24-6)

Cljfllg) Cl2 ** 11.49 PE 3507

(RN-CAS Registry Number 7782-50-5)

ci;t

J nj Cl2 ** 14.43 (V) PE 3507

(RN-CAS Registry Number 7782-50-5)

Cl21(22

+

) Cl2 ** 16.10 (V) PE 3507

(RN-CAS Registry Number 7782-50-5)

BC1 + BC1 ** 12± 1 El 3465

(RN-CAS Registry Number 20583-55-5)

BC12+ BC12 ** 12±1.0 El 3465

(RN-CAS Registry Number 13842-52-9)

BCljfAi) BC13 ** 11.62 (V) PE 3704

BCl3t

2E')

(RN-CAS Registry Number 10294-34-5)

BC13 ** 12.28 (V) PE 3704

BCl3t

2E')

(RN-CAS Registry Number 10294-34-5)

BC13 ** 12.53 (V) PE 3704

BCIjfAJ

(RN-CAS Registry Number 10294-34-5)

BC13 ** 14.35 (V) PE 3704

BCl3t

2E')

(RN-CAS Registry Number 10294-34-5)

BC13 ** 15.49 (V) PE 3704

BCljfAJ)

(RN-CAS Registry Number 10294-34-5)

BC13 ** 17.70 (V) PE 3704

(RN-CAS Registry Number 10294-34-5)

B2 Cl4t

2A,) B2C14 ** <10.42±0.02 PE 3709

B2Cl4t

2E)

(RN-CAS Registry Number 13701-67-2)

B2C14 <11.49±0.01 PE 3709

BjOJ(2AJ

(RN-CAS Registry Number 13701-67-2)

B2C14 12.25±0.01 (V) PE 3709

B2Cl4fBi)

(RN-CAS Registry Number 13701-67-2)

B2C14 12.49±0.01 (V) PE 3709

BjCUt'BJ

(RN-CAS Registry Number 13701-67-2)

B2 C14 13.02±0.02 (V) PE 3709

B2Cl4fE)

(RN-CAS Registry Number 13701-67-2)

B2C14 <13.34±0.02 PE 3709

B2Cl4fE)

(RN-CAS Registry Number 13701-67-2)

B2C14 ** <14.42±0.02 PE 3709

B2Cl4t

!A,)

(RN-CAS Registry Number 13701-67-2)

B2 C14 15.20±0.01 (V) PE 3709

(RN-CAS Registry Number 13701-67-2)

229
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

B,Cl4t

2 B; ) B2 C14 (RN-CAS Registry Number 13701-67-2)

<16.60±0.01 PE 3709

B2 Cl4t

2 A,) B2 C14 (RN-CAS Registry Number 13701-67-2)

<17.90±0.03 PE 3709

CC1 + c2 f3 ci cf3 (RN-CAS-Registry Number 79-38-9)

16.9±0.1 El 4070

ccr CFC1 = CFC1 CF2C1

(RN-CAS-Registry Number 598-88-9)

16.4±0.2 El 4070

CC12+ CFC1 =CFC1 CF2 (RN-CAS-Registry Number 598-88-9)

(TR-Other product(s) thermochemically reasonaable)

13.8±0.1 El 4070

CC13+ CC13 ** (RN-CAS Registry Number 3170-80-7)

8.28 EM 3732

(RD-Radical)

CC13+ CC14 Cl

(RN-CAS Registry Number 56-23-5)

11.37 EM 3732

CC13+ (CCl3)2CO

(RN-CAS Registry Number 116-16-5)

11.75 El 3550

C6C1+ C6C14

( 1

, 3-Cyclohexadien-5-yne, 1 ,2, 3,4-tetrachloro-)

(RN-CAS Registry Number 13280-72-3)

10.66±0.2 RPD 3583

QC1+ C803C14 (1,3-Isobenzofurandione, 4,5,6,7-tetrachloro-)

(RN-CAS Registry Number 117-08-8)

(ON-Other name: Tetrachlorophthalic anhydride)

14.31 ±0.2 RPD 3583

C6C14+ C6C15 I (Benzene, pentachloroiodo-)

(RN-CAS Registry Number 16478-18-5)

14.51 ±0.2 RPD 3583

C6C14+ C6C14I

2 (Tetrachloro-l,2-diiodobenzene)

(RN-CAS Registry Number XXXXX-XX-X)

12.85±0.2 RPD 3583

C6C16+ c6ci6 (Benzene, hexachloro-)

(RN-CAS Registry Number 118-74-1)

9.20 (V) PE 3873

ch2 ci + CH2C1 ** (RN-CAS Registry Number 6806-86-6)

8.80 EM 3732

(RD-Radical)

CH2 C1 + CH3C1 h

(RN-CAS Registry Number 74-87-3)

12.96 EM 3732

ch2ci + ch2ci2 Cl

(RN-CAS Registry Number 75-09-2)

(TR-Other product(s) thermochemically reasonable)

12.15 EM 3732

ch3 ci + CH3 C1

*

(RN-CAS Registry Number 74-87-3)

11.27 EM 3732

230
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C,HC1+ CH=CC1 ** (RN-CAS Registry Number 593-63-5)

11.044+0.004 S 3876

C2H2C1+ ch2 =cfci f

(RN-CAS-Registry Number 2317-91-1)

14.8+0.1 El 4070

C,H3 C1+ QHjCI ** 9.99±0.02 PI 3930

(RN-CAS Registry Number 75-01-4)

Q,H3 C1+

(

2A') C^Cl ** 11.65 PI 3930

(RN-CAS Registry Number 75-01-4)

C,H3 C1+ CH2 =CHC1 ** 10.01 PE 3863

(RN-CAS Registry Number 75-01-4)

C,H5C1+ QHjCI ** 11.01 (V) PE 4076

(RN-CAS Registry Number 75-00-3)

C3H5C1+ CH2 =CHCH2C1 ** 10.05 PE 3863

(RN-CAS Registry Number 107-05-1)

C3H5 C1+ CH2 =CHCH2C1 ** 10.34 (V) PE 4091

(RN-CAS Registry Number 107-05-1)

C3H7C1+ n-C3H7Cl ** 10.88 (V) PE 4076

(RN-CAS Registry Number 540-54—5)

C3H7C1+ «o-C3H7C1 ** 11.0±<0.1 El 3735

(RN-CAS Registry Number 75-29-6)

C4H9C1+ n-C4H9Cl ** (RN-CAS Registry Number 109-69-3)

10.84 (V) PE 4076

C^Cr QI^CINO;, N02 12.00±0.1

(Benzene, 1 -chloro-3-nitro-)

(RN-CAS Registry Number 121-73-3)

C6H4C1+ C6H4C1N02 N02 12.30+0.1

(Benzene, 1 -chloro-4—nitro-)

(RN-CAS Registry Number 100-00-5)

C6H5C\+ C^sCl ** 9.09 (V)

(Benzene, chloro-)

(RN-CAS Registry Number 108-90-7)

C6H5C1+ C^Cl ** 8.99 (Benzene, chloro-)

(RN-CAS Registry Number 108-90-7)

QH5C1+ C6H5 C1 ** 9.12+0.1

(Benzene, chloro-)

(RN-CAS Registry Number 108-90-7)

C6H5 C1 + C6H4C10CH3 CH20 11.68+0.1

(Benzene, l-chloro-3-methoxy-)

(RN-CAS Registry Number 2845-89-8)

QH5C1+ C^ClOCHj HCHO 11.42 (Benzene, l-chloro-4-methoxy-)

(RN-CAS Registry Number 623-12-1)

(CD-Metastable transition indicates 0.35 eV kinetic energy release)

El

El

PE

El

El

El

El

3447

3447

3873

3845

3788

3446

3845

231
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c6 h5ci + c6h4cioch3 ch2o

(Benzene, l-chloro-4-methoxy-)

(RN-CAS Registry Number 623-12-1)

1 1.56±0.1 El 3446

c6h5 ci + C6H5 ClCr(CO)3 (Chromium, tricarbonyl(i7

6-chlorobenzene)-)

(RN-CAS Registry Number 12082-03-0)

9. 1 5 ±0.

El 3788

C6HhC1 + c6huci

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

10.10±0.01 PI 4078

c6hu ci + c6hu ci

(Cyclohexane, chloro-)

(RN-CAS Registry Number 542-18-7)

10.67 (V) PE 4078

c7h6ci + C6H4ClCH2 CH2OCOCH3 (Phenethyl alcohol, m-chloro-, acetate)

(RN-CAS Registry Number 33709-41-0)

12.90 El 3590

c7h7ci + C6H5 CH2C1 ** (Benzene, (chloromethyl)-)

(RN-CAS Registry Number 100-44-7)

9.30 (V) PE 3992

C^Cl* C6H4C1CH3 ** (Benzene, l-chloro-2-methyl-)

(RN-CAS Registry Number 95-49-8)

8.72±0.1 El 3777

C7H7C1 + C6H4C1CH3 ** (Benzene, l-chloro-3-methyl-)

(RN-CAS Registry Number 108-41-8)

8.67±0.1 El 3777

C^Cl* C6H4C1CH3 ** (Benzene, l-chloro-4-methyl-)

(RN-CAS Registry Number 106-43-4)

8.78±0.1 El 3777

C8 H7C1 + C6H4ClCH2CH2OCOCH3 (Phenethyl alcohol, m-chloro-, acetate)

(RN-CAS Registry Number 33709-41-0)

8.90 El 3590

C10H15 C1 + CioH15 C1 ** 9.30 PE 3886

(Tricyclo[ 3 .3.1.1

3,7 ]decane, 1 -chloro-)

(RN-CAS Registry Number 935-56-8)

(ON-Other name: 1-Chloroadamantane)

C12 H9C1 + C6H5 C6H4C1 ** 8.20±0.02 PE 3702

(l,l'-Biphenyl, 2-chloro-)

(RN-CAS Registry Number 2051-60-7)

C12 H9C1 + C6H5 C6H4C1 ** 8.10±0.02 PE 3702

(1,1 '-Biphenyl, 4-chloro-)

(RN-CAS Registry Number 2051-62-9)

CHC12+

(RD-Radical)

CHC12 ** (RN-CAS Registry Number 3474-12-2)

8.45 EM 3732

232
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CHC12+ CHC13 Cl

(RN-CAS Registry Number 67-66-3)

(TR-Other product(s) thermochemically reasonable)

11.52 EM 3732

chci2+ chci2ch2 ci ch2ci

(RN-CAS Registry Number 79-00-5)

(TR-Other product(s) thermochemically reasonable)

11.80 EM 3732

CH2 C12+ ch2ci2 ** (RN-CAS Registry Number 75-09-2)

11.28 EM 3732

c2 h2 ci2+ trans-CRC\ = CHC1 ** (RN-CAS Registry Number 156-60-5)9.72 (V) PE 3648

C2 H2Cl2t

2Ag

) trans-CYiCX = CHC1 ** (RN-CAS Registry Number 156-60-5)

11.92 (V) PE 4022

C2 H2Cl2t

2Be) trans-CHCX =CHC1 ** (RN-CAS Registry Number 156-60-5)

12.11 (V) PE 4022

C2H2 Cl2t

2 B„) trans-CHC1 =CHC1 ** (RN-CAS Registry Number 156-60-5)

12.67 (V) PE 4022

C2H2Cl2t

2Au) trans-CHCX = CHC1 ** (RN-CAS Registry Number 156-60-5)

13.87 (V) PE 4022

C6H2C12+ C6H2C12

( 1 , 3-Cyclohexadien-5-yne, 1 ,2-dichloro-)

(RN-CAS Registry Number 24634-92-2)

9.66+0.2 RPD 3583

c6h2 ci2+ C6H2C12

( 1 ,3-Cyclohexadien-5-yne, 1 ,3-dichloro-)

(RN-CAS Registry Number 24634-94-4)

9.97+0.2 RPD 3583

c6h2 ci2+ C6H2C12

( 1 ,3-Cyclohexadien-5-yne, 1 ,4-dichloro-)

(RN-CAS Registry Number XXXXX-XX-X)

9. 11 ±0.2 RPD 3583

c6h2ci2+ C6H2C12 ( 1 ,3-Cyclohexadien-5-yne, 2,3-dichloro-)

(RN-CAS Registry Number 24634-93-3)

9.58±0.2 RPD 3583

c6h2ci2+ c8 h2o3 ci2 ( 1

, 3-Isobenzofurandione, 4, 7-dichloro-)

(RN-CAS Registry Number 4466-59-5)

(ON-Other name: 3,6-Dichlorophthalic anhydride)

13.60+0.2 RPD 3583

c6h2 ci2+ C8 H203 C12 (1,3 -Isobenzofurandione, 5 , 6-dichloro-)

(RN-CAS Registry Number 942-06-3)

(ON-Other name: 4,5-Dichlorophthalic anhydride)

14.06+0.2 RPD 3583

c6h2ci2+ C6H2C12 I2 (3,4-Dichloro- 1 ,2-diiodobenzene)

(RN-CAS Registry Number XXXXX-XX-X)

14.11±0.2 RPD 3583

c6h2ci2+ c6h2ci2i2 (3,5-Dichloro- 1 ,2-diiodobenzene)

(RN-CAS Registry Number XXXXX-XX-X)

14.43±0.2 RPD 3583

c6h2 ci2+ C6H2 C12 I2 (4, 5-Dichloro- 1 ,2-diiodobenzene)

(RN-CAS Registry Number XXXXX-XX-X)

14. 11 ±0.2 RPD 3583

233
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c6h4ci2+ c6h4ci2 (Benzene, 1,2-dichloro-)

(RN-CAS Registry Number 95-50-1)

9.08 (V) PE 3873

c6h4ci2+ c6h4ci2 (Benzene, 1,3-dichloro-)

(RN-CAS Registry Number 541-73-1)

9.15 (V) PE 3873

c6h4ci2+ c6H4ci2 (Benzene, 1,4-dichloro-)

(RN-CAS Registry Number 106-46-7)

9.00 (V) PE 3873

c8 h6ci2+ C6H3 (C1)2CH=ch2 (Benzene, 1 , 3-dichloro-2-ethenyl-)

(RN-CAS Registry Number 28469-92-3)

8.70±0.02 PE 3854

chci3+ CHC13 ** (RN-CAS Registry Number 67-66-3)

11.41 EM 3732

c6h3 ci3+ C6H3 C13 (Benzene, 1,2,3-trichloro-)

(RN-CAS Registry Number 87-61-6)

9.22 (V) PE 3873

c6h3 ci3+ C6H3 C13 (Benzene, 1,3,5-trichloro-)

(RN-CAS Registry Number 108-70-3)

9.36 (V) PE 3873

c6h2ci+ C6H2C14 (Benzene, 1 , 2, 3 ,4-tetrachloro-)

(RN-CAS Registry Number 634-66-2)

9.11 (V) PE 3873

c6h2ci+ C6H2C14 (Benzene, 1,2,3,5-tetrachloro-)

(RN-CAS Registry Number 634-90-2)

9.16 (V) PE 3873

c6h2ci4+ C6H2 C14 (Benzene, 1,2,4,5-tetrachloro-)

(RN-CAS Registry Number 95-94-3)

9.06 (V) PE 3873

c6hci5+ C6HC15 (Benzene, pentachloro-)

(RN-CAS Registry Number 608-93-5)

9.11 (V) PE 3873

b3 h3 n3 ci3+ B3 H3 N3C13 ** (Borazine, 2,4,6-trichloro-)

(RN-CAS Registry Number 933-18-6)

10.55 (V) PE 3944

b3 h3 n3ci3+ b3 h3 n3 ci3 (Borazine,2,4,6-trichloro-)

(RN-CAS Registry Number 933-18-6)

10.55 (V) PE 3673

c6h6nci + C6H4ClNHCOCH3 ch2 =c=o

(Acetamide, 7V-(2-chlorophenyl)-)

(RN-CAS Registry Number 533-17-5)

10.76±0.03 El 3483

c6h6nci + c6h4cinhcoch3 ch2 =c=o

(Acetamide, 7V-(4-chlorophenyl)-)

(RN-CAS Registry Number 539-03-7)

10. 11 ±0.03 El 3483

234
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C16H12NC1+ C6H4(C1)C3 H3(CN)C6H5 ** 8.18±0.10

(Cyclopropanecarbonitrile, 1 -(p-chlorophenyl)-2-pheny1-) (RN-CAS Registry Number 32589-55-2)

EDD 3575

c6h5 nci2+ C6H3 (C1)2NH2 (Benzenamine, 2,6-dichloro-)

(RN-CAS Registry Number 608-31-1)

7. 60 ±0.02 PE 3890

c6h5nci2+ c6h3 ci2nhcoch3 ch2 =c=o

(Acetamide, A-(2,4—dichlorophenyl)-)

(RN-CAS Registry Number 6975-29-7)

10.09+0.03 El 3480

c6h5 nci2+ c6h3 ci2nhcoch3 ch2 =c=o

(Acetamide, N-(2, 6-dichloropheny1)-) (RN-CAS Registry Number 17700-54-8)

9.93+0.03 El 3480

c4h12 bn2 ci + B(N(CH3)2)2C1 ** (RN-CAS Registry Number 6562-41-0)

8.15 (V) PE 3704

c4h12 bn2ci + ((CH3)2N)2BC12 (RN-CAS Registry Number 6562-41-0)

8.08 PE 3584

c2h6bnci2+ (CH3)2NBC12 ** (RN-CAS Registry Number 1113-31-1)

9.56 PE 3584

c2h6bnci2+ (CH3)2NBC12 ** (RN-CAS Registry Number 1113-31-1)

9.68 (V) PE 3704

CjH^jNjC^ (CH3)3 B3 N3 C13 (Borazine, 2,4, 6-trichloro- 1 , 3, 5-trimethyl-)

(RN-CAS Registry Number 703-86-6)

9.45 (V) PE 3944

cio2+ cio2 (RN-CAS Registry Number 10049-04-4)

10.36+0.02 PE 3499

(RD-Radical)

C102t

2A,) cio2 ** (RN-CAS Registry Number 10049-04-4)

10.5+0.1 (V) PE 3671

(RD-Radical)

ClO^Bj?) cio2 ** (RN-CAS Registry Number 10049-04-4)

12.32+0.02 PE 3499

(RD-Radical)

C102t

3B„1 B„3B2) cio2 ** (RN-CAS Registry Number 10049-04-4)

12.9+0.1 (V) PE 3671

(RD-Radical)

ClO^vB,, Blt 3 B2) cio2 ** (RN-CAS Registry Number 10049-04-4)

13.4+0.1 (V) PE 3671

(RD-Radical)

ClO^Bj?) cio2 ** (RN-CAS Registry Number 10049-04-4)

15.27+0.02 PE 3499

(RD-Radical)

ClOJ'Bj) cio2 ** (RN-CAS Registry Number 10049-04-4)

15.5+0.1 (V) PE 3671

(RD-Radical)

235
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

ClO^’AJ cio2 ** > 17 (V) PE 3671

(RN-CAS Registry Number 10049-04-4)

(RD-Radical)

ci2o

+

(

2 b,) ci2o ** 11.02 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2o

+

(

2 b2 ) ci2o ** 12.37 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2o

+

(

2a,) ci2 o ** 12.65 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2 o

+

(

2a2) ci2o ** 12.79 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2o

+

(

2 b,) ci2o ** 15.90 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2o

+ * ci2o ** 16.65 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2o

+ * ci2o ** 17.68 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

ci2 o

+ * ci2o ** 20.64 (V) PE 3694

(RN-CAS Registry Number 7791-21-1)

COCl2+ cci2o ** ~ 1 1.2 PE 3726

(RN-CAS Registry Number 75 44-5)

COCl^[2 B2) cci2o ** 1 1 .55 ±0.02 PE 3667

(RN-CAS Registry Number 75_44_5)

COCl^ cci2o ** ~ 12.3 (V) PE 3726

(RN-CAS Registry Number 75_44_5)

COCljfB^BO cci2o ** 12.6±0.1 (V) PE 3667

(RN-CAS Registry Number 75-44-5)

COCl2t

2 B2?) cci2 o ** 12.6 (V) PE 3726

(RN-CAS Registry Number 75-44-5)

COCl^ cci2o ** ~ 13.0 (V) PE 3726

(RN-CAS Registry Number 75-44 5) COCl2t

2A,) cci2o ** 13.05±0.05 (V) PE 3667

(RN-CAS Registry Number 75-44-5)

COCl^ cci2o ** 13.31 PE 3726

(RN-CAS Registry Number 75 44 5) COCl2t

2 A2) cci2o ** 13.39±0.02 PE 3667

(RN-CAS Registry Number 75-44-5)

COCl2t

2 A,) cci2o ** 15.80±0.02 PE 3667

(RN-CAS Registry Number 75-44-5)

COCl^ cci2o ** 16.63 PE 3726

(RN-CAS Registry Number 75-44-5)

COCl2t

2 B,) cci2o ** 16.66±0.02 PE 3667

(RN-CAS Registry Number 75-44-5)

COClj** cci2o ** 16.75 PE 3726

(RN-CAS Registry Number 75-44-5)

COCl^ cci2o ** 17.0 (V) PE 3726

(RN-CAS Registry Number 75-44-5)

COCl2t

2 B2) cci2o ** 17. 11 ±0.02 (V) PE 3667

(RN-CAS Registry Number 75-44-5)

236
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

COCl^Aj) cci2o ** 19.29±0.02 PE 3667

(RN-CAS Registry Number 75-44-5)

COCl^ cci2o ** 19.5 (V) PE 3726

(RN-CAS Registry Number 75-44-5)

C2OCl3+ (CCl3)2CO

(RN-CAS Registry Number 116-16-5)

12.0 El 3550

C8 03 C14+ C803 C14 ** 10.77±0.2 RPD 3583

( 1

, 3-Isobenzofurandione, 4, 5 , 6, 7-tetrachloro-)

(RN-CAS Registry Number 117-08-8)

(ON-Other name: Tetrachlorophthalic anhydride)

C3 H5OCl+ CH3 COCH2Cl ** 9.91 ±0.03 PI 3765

(RN-CAS Registry Number 78-95-5)

C6H4OCl+

c6h4oci+

c6h4oci+

c6h4oci+

c6h4cioch3 ch3 (Benzene, l-chloro-3-methoxy-)

(RN-CAS Registry Number 2845-89-8)

c6h4cioch3 ch3 (Benzene, l-chloro-4-methoxy-)

(RN-CAS Registry Number 623-12-1)

c6h4cino2 no

(Benzene, l-chloro-3-nitro-)

(RN-CAS Registry Number 121-73-3)

c6h4cino2 no

(Benzene, l-chloro-4-nitro-)

(RN-CAS Registry Number 100-00-5)

11.89±0.1 El 3446

11.84±0.1 El 3446

10.31 ±0.1 El 3447

10.61 ±0.1 El 3447

C6H5 OCl+

c6h5oci+

c6h5 oci+

c6h5 oci+

c6h4cioocch3 ch2 =c=o

(Acetic acid, 2-chlorophenyl ester)

(RN-CAS Registry Number 4525-75-1)

c6h4cioocch3 ch2 =c=o

(Acetic acid, 3-chlorophenyl ester)

(RN-CAS Registry Number 13031-39-5)

c6h4cioocch3 ch2 =c=o

(Acetic acid, 4-chlorophenyl ester)

(RN-CAS Registry Number 876-27-7)

c6h4cioocch3 ch2 =c=o

(Acetic acid, 4-chlorophenyl ester)

(RN-CAS Registry Number 876-27-7)

9.19±0.03 El

10. 11 ±0.2 El

9.60±0.03 El

10.17±0.2 El

3483

3484

3483

3484

C7H5 OCl+ C6H5 COCl ** 9.85 El 3792

(Benzoyl chloride)

(RN-CAS Registry Number 98-88-4)

C7H7OCl + C6H4C10CH3 ** 8.72±0.1 El 3446

(Benzene, l-chloro-3-methoxy-)

(RN-CAS Registry Number 2845-89-8)

C7H7OCl + C6H4C10CH3 ** 8.18 El 3845

(Benzene, l-chloro-4-methoxy-)

(RN-CAS Registry Number 623-12-1)

237
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C7 H7OCl + c6h4cioch3 ** (Benzene, l-chloro-4-methoxy-)

(RN-CAS Registry Number 623-12-1)

8.52±0.1 El 3446

c2 h3 o2 ci + ch2 cicooh ** (RN-CAS Registry Number 79-11-8)10.99 (V) PE 3874

c8 h7o2ci + c6 h4cioocch3 ** (Acetic acid, 2-chlorophenyl ester)

(RN-CAS Registry Number 4525-75-1)

8.67±0.03 El 3483

c8 h7o2 ci + c6h4cioocch3 ** (Acetic acid, 3-chlorophenyl ester)

(RN-CAS Registry Number 13031-39-5)

8.83±0.2 El 3484

c8 h7o2 ci + c6h4cioocch3 ** (Acetic acid, 4-chlorophenyl ester)

(RN-CAS Registry Number 876-27-7)

8.42±0.03 El 3483

c8 h7o2 ci + c6h4cioocch3 ** (Acetic acid, 4-chlorophenyl ester)

(RN-CAS Registry Number 876-27-7)

8.79±0.2 El 3484

c6h4oci2+ C6H3 (Cl)2 OH

(Phenol, 2,6-dichloro-)

(RN-CAS Registry Number 87-65-0)

8.65±0.02 PE 3890

c6 h4oci2+ c6h3 ci2oocch3 ch2 =c=o

(Phenol, 2,4-dichloro-, acetate)

(RN-CAS Registry Number 6341-97-5)

9.37±0.03 El 3480

c6h4oci+ c6h3 ci2oocch3 ch2 =c=o

(Phenol, 2,6-dichloro-, acetate)

(RN-CAS Registry Number 28165-71-1)

9.88±0.03 El 3480

c8 h6o2 ci2+ C6H3 Cl2 OOCCH3 ** (Phenol, 2,4-dichloro-, acetate)

(RN-CAS Registry Number 6341-97-5)

8.16±0.03 El 3480

c8 h6o2 ci2+ C6 H3 Cl2OOCCH3 ** (Phenol, 2,6-dichloro-, acetate)

(RN-CAS Registry Number 28165-71-1)

8.68±0.03 El 3480

c8 h7 noci + C6H3 Cl2 NHCOCH3 (Acetamide, A^-(2,4-dichlorophenyl)-)

(RN-CAS Registry Number 6975-29-7)

8.81 ±0.03 El 3480

c8 h7 noci + C6H3 Cl2 NHCOCH3 (Acetamide, N-^^-dichlorophenyl)-)

(RN-CAS Registry Number 17700-54-8)

8.79±0.03 El 3480

c8 h8 noci + c6h4cinhcoch3 ** (Acetamide, A^-(2-chlorophenyl)-)

(RN-CAS Registry Number 533-17-5)

8.07±0.03 El 3483

c8 h8 noci + c6 h4cinhcoch3 ** (Acetamide, A-(4-chlorophenyl)-)

(RN-CAS Registry Number 539-03-7)

8.07 ±0.03 El 3483

238
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance Method

potential

(eV)

Ref.

C17 H14NOCl+ C6H4(Cl)C3 H3 (CN)C6H4(OCH3) ** 7.70+0.05

(Cyclopropanecarbonitrile, l-(p-chlorophenyl)-2-(p-methoxyphenyl)-)

(RN-CAS Registry Number 32589-54-1)

EDD 3575

c6H4No2 cr c6h4cino2 ** (Benzene, l-chloro-3-nitro-)

(RN-CAS Registry Number 121-73-3)

9.92+0.1 El 3447

c6h4no2ci + c6h4cino2 ** (Benzene, l-chloro-4-nitro-)

(RN-CAS Registry Number 100-00-5)

9.96+0.1 El 3447

c8 h7noci2+ C6H3 Cl2NHCOCH3 ** (Acetamide, A-(2,4—dichlorophenyl)-)

(RN-CAS Registry Number 6975-29-7)

8.09+0.03 El 3480

c8h7noci2+ C6H3 Cl2NHCOCH3 ** (Acetamide, N-(2, 6-dichlorophenyl)-)

(RN-CAS Registry Number 17700-54-8)

8.25+0.03 El 3480

ciF+

(

2 n3/2g) CIF ** (RN-CAS Registry Number 7790-89-8)

12.66+0.01 PE 3507

ClF+

(2II3/2) C1F ** (RN-CAS Registry Number 7790-89-8)

(HB-Threshold value approximately corrected for hot bands)

12.66+0.01 PE 3680

ciF-(2 n 1/2g) CIF ** (RN-CAS Registry Number 7790-89-8)12.74+0.01 PE 3507

ciF*(2 nl/2) CIF ** (RN-CAS Registry Number 7790-89-8)

12.74+0.01 PE 3680

ciF+

(

2 n3/2, 2n,/2) CIF ** (RN-CAS Registry Number 7790-89-8)

16.25+0.08 PE 3680

CiF (

2 IIJ CIF ** (RN-CAS Registry Number 7790-89-8)

16.39+0.01 PE 3507

cif+

(

25; +

) CIF ** (RN-CAS Registry Number 7790-89-8)

17.80+0.01 PE 3507

ClF+

(

2 2

+

) CIF ** (RN-CAS Registry Number 7790-89-8)

17.81+0.08 PE 3680

ClF3t

2 B2 , 2 A,) C1F3 ** (RN-CAS Registry Number 7790-91-2)

12.65+0.05 PE 3680

ClFjfA,) C1F3 ** (RN-CAS Registry Number 7790-91-2)

13.76+0.06 PE 3680

ClF3t

2 B,) C1F3 ** (RN-CAS Registry Number 7790-91-2)

14.83+0.03 (V) PE 3680

ClF3t

2 A2 ) C1F3 ** (RN-CAS Registry Number 7790-91-2)

15.36+0.03 (V) PE 3680

ClFjfBJ C1F3 ** (RN-CAS Registry Number 7790-91-2)

16.07±0.01 (V) PE 3680

ClF3t

2 B,) C1F3 ** (RN-CAS Registry Number 7790-91-2)

16.82+0.06 PE 3680

CIFJ(

2A1

, 2Bj) C1F3 ** (RN-CAS Registry Number 7790-91-2)

~19(V) PE 3680

239
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

ClFjfB,) C1F3 ** (RN-CAS Registry Number 7790-91-2) ~ 19.5 (V) PE 3680

BC1F + BC1F ** (RN-CAS Registry Number 22395-93-3)

1

± 1 El 3465

BC1F2+ BC1F2 ** (RN-CAS Registry Number 14720-30-0)13 ±1 El 3465

bci2 f

+ BC12 F

** (RN-CAS Registry Number 14720-31-1)

14± 1 El 3465

CFC1 +

CFC1 +

CFC1 +

CFC1 +

C2 F3 C1 CF2 (RN-CAS Registry Number 79-38-9)

CFC1 = CFC1 CFC1

(RN-CAS Registry Number 598-88-9)

CFC1, 2C1

(RN-CAS Registry Number 75-69-4)

ch2 =cfci ch2 (RN-CAS Registry Number 2317-91-1)

15.0+0.1 El 3539

1 5.3 ±0. 1

5

El 3539

17.1 ±0.1 El 3539

16.8+0.1 El 3539

CF2 C1 + C2 F3 C1 CF 14.9 ±0. 1 El 4070

(RN-CAS-Registry Number 79-38-9)

(TR-Other product(s) thermochemically reasonaable)

CF2 C1 + (CF2 Cl)2 CO 11.95 El 3550

(RN-CAS Registry Number 127-21-9)

C2 F2C1 + c2 f3 ci F 15.9±0.2 El 4070

(RN-CAS-Registry Number 79-38-9)

C2 F2 C1 + CFC1 =CFC1 Cl 14.8 ±0.El 4070

(RN-CAS-Registry Number 598-88-9)

CF3 C1 +

(

2 E) CF3 CI ** 13.0 (V) PE 3914

CF3 C1 +

(

2 E)

(RN-CAS Registry Number 75-72-9)

CF3 CI ** 13.08 ±0.02 (V) PE 4026

cf3ci +

(

2 a,)

(RN-CAS Registry Number 75-72-9)

CF3 CI ** 15.0 (V) PE 3914

CFjC1 +

(

2A,)

(RN-CAS Registry Number 75-72-9)

CF3 CI ** 15. 15 ±0.02 (V) PE 4026

CFjC1 +

(

2A2) (RN-CAS Registry Number 75-72-9)

CF3 CI ** 15.55 (V) PE 3914

cf,ci +

(

2a2) (RN-CAS Registry Number 75-72-9)

CF3 CI ** 15.82±0.02 (V) PE 4026

CF3 C1 +

(

2 E)

(RN-CAS Registry Number 75-72-9)

CF3 CI ** 16.5 (V) PE 3914

CF3 C1 +

(

2 E)

(RN-CAS Registry Number 75-72-9)

CF3 CI ** 16.56±0.02 (V) PE 4026

CF3 C1 +

(

2 E)

(RN-CAS Registry Number 75-72-9)

CF3 CI ** 17.4 (V) PE 3914

CF3 C1 +

(

2 E)

(RN-CAS Registry Number 75-72-9)

CFjCl ** 17.53±0.02 (V) PE 4026

(RN-CAS Registry Number 75-72-9)

240
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

CF3 C1 +

(

2A1 ) CF3 C1 ** 20.1 (V)

(RN-CAS Registry Number 75-72-9)

CF3 C1 +

(

2E) CF3 C1 ** -21.0 (V

(RN-CAS Registry Number 75-72-9)

C2F3 C1 + C2F3 C1 ** 9.76 (RN-CAS Registry Number 79-38-9)

C2F3 C1 + C2F3 C1 ** 9.82 (RN-CAS Registry Number 79-38-9)

C2F3 C1+ C2F3 C1 ** 10.6±0.1

(RN-CAS-Registry Number 79-38-9)

CFC12+ CFC1 =CFC1 cf

(RN-CAS-Registry Number 598-88-9)

(TR-Other product(s) thermochemically reasonaable)

14.3 ±0.

1

El 4070

C2FC12+ CFC1 =CFC1 F

(RN-CAS-Registry Number 598-88-9)

15.7±0.1 El 4070

cf2ci2+ CF2C12 ** (RN-CAS Registry Number 75-71-8)

12.3 (V) PE 3914

CF2CC12+ CF2 =CC12 ** 9.62 (RN-CAS Registry Number 79-35-6)

C2F2 C12+ CFC1=CFC1 ** 10.2±0.1

(RN-CAS-Registry Number 598-88-9)

CFC13+ cfci3 ** (RN-CAS Registry Number 75-69-4)

11.9 (V) PE 3914

ch2fci + CH2FC1 ** (RN-CAS Registry Number 593-70-4)

11.74 PE 3914

c2hfci+ ch2 =cfci h

(RN-CAS-Registry Number 2317-91-1)

16.2±0.2 El 4070

CH2 =CFC1 ** 9.97 S 3776

(RN-CAS Registry Number 2317-91-1)

CH2 =CFC1 ** 10.7±0.2 El 4070

(RN-CAS-Registry Number 2317-91-1)

CH2 = CFC1 ** 10.7±0.2 El 3539

(RN-CAS Registry Number 2317-91-1)

CHF2 C1 + chf2ci ** (RN-CAS Registry Number 75-45-6)

12.6 (V) PE 3914

c2hf2ci + CF2 =CHC1 ** (RN-CAS Registry Number 359-10-4)

9.76 S 3776

chfci2+ CHFC12 ** (RN-CAS Registry Number 75-43-4)

12.0 (V) PE 3914

C2H2FC1 + c2h2fci+ c2h2fci+

PE 3589

El 4070

PE 4026

PE 4026

S 3776

PE 3589

El 4070

241
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

C103 F

+

(

2A2) cio3 f ** (RN-CAS Registry Number 7616-94-6)

C103 F

+

(

2 E) cio3 f ** (RN-CAS Registry Number 7616-94-6)

C103 F

+

(

2 A,) cio3 f ** (RN-CAS Registry Number 7616-94-6)

C103 F

+

(

2 E) cio3 f ** (RN-CAS Registry Number 7616-94—6)

C103 F

+

(

2E) cio3 f ** (RN-CAS Registry Number 7616-94—6)

C103 F

+

(

2A,) cio3 f ** (RN-CAS Registry Number 7616-94-6)

C103 F

+

(

2 A,) cio3 f ** (RN-CAS Registry Number 7616-94-6)

Ionization or appearance

potential

(eV)

Method Ref.

12.945 ±0.005 PE 3675

13.68±0.02 PE 3675

14.29±0.02 (V) PE 3675

15.385±0.008 PE 3675

19.70±0.01 PE 3675

21.3±0.1 (V) PE 3675

23. 8 ±0.1 (V) PE 3675

A10C1 + AlOCl ** 12±1 El 3462

(RN-CAS Registry Number 13596-11-7)

SiCl + Cl3 SiCo(Co)2(PF3)2 16.4±0.5 El 3653

(RN-CAS Registry Number 37769-29-2)

SiCl +

Cl3 SiCo(CO)3 PF3 16.2±0.5 El 3653

(RN-CAS Registry Number 37769-28-1)

SiCl4fT,) SiCl4 ** 12.06 (V) PE 3514

SiCUfTj)

(RN-CAS Registry Number 10026-04-7)

SiCl4 ** 12.95 (V) PE 3514

SiCl4t

2 E)

(RN-CAS Registry Number 10026-04-7)

SiCl4 ** 13.44 (V) PE 3514

(RN-CAS Registry Number 10026-04-7)

SiH3 Cl +

(

2 E) SiH3 Cl ** 11.61 ±0.02 (V) PE 3510

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl + SiH3 Cl ** 11.61 ±0.05 (V) PE 3502

SiH3 Cl +

(

2 E)

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl ** 11.65 (V) PE 3511

SiH3 Cl +

(

2A,)

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl ** 13.4±0. 1 (V) PE 3510

SiH3 Cl +

(

2A,?)

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl ** 13.51 (V) PE 3511

SiH3 Cl +

(

2E)

(RN-CAS Registry Number 13465-78-6)

SiH3Cl ** 1 3.7 ±0. 1 (V) PE 3510

SiH3 Cl +

(

2 E?)

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl ** 13.99 (V) PE 3511

SiH3 Cl +

(

2A,)

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl ** 18.04±0.02 (V) PE 3510

SiH3 Cl +

(

2A,)

(RN-CAS Registry Number 13465-78-6)

SiH3 Cl ** 18.13 (V) PE 3511

(RN-CAS Registry Number 13465-78-6)

SiH2 Cl2+ SiH2 Cl2 ** 11. 64 ±0.02 (V) PE 3510

(RN-CAS Registry Number 4109-96-0)

242
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SiHjCl^Bj) SiH2Cl2 ** 11.70 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2

l(

2B2) SiH2Cl2 ** 11.70 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2t

2B,) SiH2Cl2 ** 12.09 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2t

2B1 ) SiH2Cl2 ** 12.09 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH2CI2t

2A1) SiH2Cl2 ** 12.53 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiHjCljfA;) SiH2Cl2 ** 12.53 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH2Cl^(

2A1 ) SiH2Cl2 ** 12.76 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2t

2A,) SiH2Cl2 ** ~ 12.76 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiH,Cl7t

2B7?) SiH2Cl2 ** 14.20 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiHjCl^* SiH2Cl2 J4.20 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2t

2A,?) SiH2Cl2 ** 14.45 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2* SiH2Cl2 14.45 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH,Cl7t

2B,?) SiH2Cl2 ** 14.60 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiHjCl^ SiH2Cl2 14.60 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2t

2A,) SiH2Cl2 ** 18.32 (V) PE 3511

(RN-CAS Registry Number 4109-96-0)

SiH2Cl2

1* SiH2Cl2 ** 18.32 (V) PE 3694

(RN-CAS Registry Number 4109-96-0)

SiHCl3t

2A2) SiHCl3 ** 11.94 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

SiHC^Aj) SiHCl3 ** 12.41 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

SiHCl3t

2E") SiHCl3 ** 12.41 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

SiHCl3t

2E') SiHCl3 ** 13.07 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

SiHCl3t

2E) SiHCl3 ** 14.75 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

SiHCl3t

2Ai) SiHCl3 ** 14.98 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

SiHCl^A,) SiHCl3 ** 18.14 (V) PE 3511

(RN-CAS Registry Number 10025-78-2)

C3H9SiCl + (CH3)3 SiCl ** 10.76 (V) PE 3503

(RN-CAS Registry Number 75-77-4)

243
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C4H9 SiCl + C3 H6Si(Cl)CH3 ** (Silacyclobutane, 1 -chloro- 1 -methyl-)

(RN-CAS Registry Number 2351-34-0)

9.95 (V) PE 4077

C4H,,SiCl + (CH3 ) 3 SiCH2Cl ** (RN-CAS Registry Number 2344-80-1)

10.17±0.1 (V) PE 3830

C5 H9SiCl + (CH3 )3 SiC=CCl ** (RN-CAS Registry Number 7652-06-4)

9.4±0.1 PE 4002

C2 H6SiCl2+ (CH3 )2 SiCl2 (RN-CAS Registry Number 75-78-5)

10.99 (V) PE 3503

C3 H6 SiCl2+ C3 H6SiCl2 (Silacyclobutane, 1 , 1 -dichloro-)

(RN-CAS Registry Number 2351-33-9)

10.50 (V) PE 4077

C6 H12 Si4Cl4+ C6 HI2 Si4Cl4 ** 9.4±0.05

(l,3,5,7-Tetrasilatricyclo[3.3.1.1

3 ’ 7 ]decane, 1,3,5,7-tetrachloro-)

(RN-CAS Registry Number 18222-89-4)

(ON-Other name: l,3,5,7-Tetrachloro-l,3,5,7-tetrasilaadamantane)

PE 3855

C4H12 N2 SiCl2+ ((CH3)2 N)2 SiCl2 (RN-CAS Registry Number 13328-30-8)8.81 (V) PE 3503

C2 H6 NSiCl3+ ((CH3 ) 2N)SiCl3 (RN-CAS Registry Number 13307-04-5)9.30 (V) PE 3503

C6H15 03 SiCl + (C2 H5 0)3 SiCl

(RN-CAS Registry Number 4667-99-6)

10.52 (V) PE 3503

C4 H10O2 SiCl2+ (C2 H5 0)2 SiCl2 ** (RN-CAS Registry Number 4667-38-3)

10.78 (V) PE 3503

C2 H5 OSiCl3+ (C2 H50)SiCl3 ** (RN-CAS Registry Number 1825-82-7)

11.30 (V) PE 3503

SiF3Cl +

(

2 E) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

13. 44 ±0.02 (V) PE 4026

SiF3 Cl +

(

2 A,) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

15.33 ±0.02 (V) PE 4026

SiF3 Cl +

(

2 A2) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

16. 35 ±0.02 (V) PE 4026

SiF3 Cl +

(

2 E) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

16.70±0.02 (V) PE 4026

SiF3 Cl +

(

2 E) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

17.49±0.02 (V) PE 4026

SiF3 Cl +

(

2 A,) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

18.26±0.02 (V) PE 4026

SiF3 Cl +

(

2 E) SiF3 Cl ** (RN-CAS Registry Number 14049-36-6)

18.92±0.02 (V) PE 4026

244
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

PC1 + PC13 16.0±0.2 EDD 3556

(RN-CAS Registry Number 7719-12-2)

PC12+ PC13 Cl 11.9+0.1 EDD 3556

(RN-CAS Registry Number 7719-12-2)

PC12+ PCl2 Br Br 1 1 .3 ±0.

1

EDD 3556

(RN-CAS Registry Number 13536-48-6)

PCljfA,) PC13 ** 10.51 (V) PE 4023

(RN-CAS Registry Number 7719-12-2)

PCljfA,) PC13 ** 10.52±0.03 (V) PE 3669

(RN-CAS Registry Number 7719-12-2)

PCljfA*) PC13 ** 11.69±0.03 (V) PE 3669

(RN-CAS Registry Number 7719-12-2)

PCljfA*) PC13 ** 11.70 (V) PE 4023

(RN-CAS Registry Number 7719-12-2)

PCl3t

2E) PC13 ** 11.97±0.03 (V) PE 3669

PCljfE)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 12.00 (V) PE 4023

(RN-CAS Registry Number 7719-12-2)

PCl3t

2E) PC13 ** 12.94±0.03 (V) PE 3669

PCl3t

2E)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 12.97 (V) PE 4023

PCljfA,)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 14.23 ±0.03 (V) PE 3669

PCljfA,)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 14.23 (V) PE 4023

PCl3t

2E)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 15.19±0.03 (V) PE 3669

PCl3t

2E)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 15.20 (V) PE 4023

PCljfA,)

(RN-CAS Registry Number 7719-12-2)

PC13 ** 18.81 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7719-12-2)

PC13+ PC13 ** 10.5 ±0.

1

EDD 3556

(RN-CAS Registry Number 7719-12-2)

PC15+ PC15 ** 10.88 (V) PE 3669

(RN-CAS Registry Number 10026-13-8)

POCl+

(

2E) POC1 ** 11.85 (V) PE 4023

POCl +

(

2A2)

(RN-CAS Registry Number 21295-50-1)

POC1 ** 12.35 (V) PE 4023

POC1 +

(

2Ej/2) (RN-CAS Registry Number 21295-50-1)

POC1 ** 12.93 (V) PE 4023

POCl +

(

2E,/2) (RN-CAS Registry Number 21295-50-1)

POC1 ** 12.98 (V) PE 4023

POCl+

(

2A!)

(RN-CAS Registry Number 21295-50-1)

POC1 ** 13.48 (V) PE 4023

POCl+

(

2E)

(RN-CAS Registry Number 21295-50-1)

POC1 ** 13.85 (V) PE 4023

(RN-CAS Registry Number 21295-50-1)

245
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref.

products potential

(eV)

POCl +

(

2A!) POC1 ** 15.37 (V) PE 4023

POCl +

(

2E)

(RN-CAS Registry Number 21295-50-1)

POC1 ** 16.53 (V) PE 4023

(RN-CAS Registry Number 21295-50-1)

POCl3t

2 E) POCl3 ** 11.36±0.02 PE 3835

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 11.58+0.05 PE 3641

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 11.89+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCljfAJ POCl3 ** 12.36+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCl3fA2) POCl3 ** 12.38+0.02 (V) PE 3835

(RN-CAS Registry Number 10025-87-3)

POCljfAj) POCl3 ** 12.52+0.04 (V) PE 3641

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 12.97+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCl3t

2E) POCl3 ** 12.98+0.01 (V) PE 3835

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 13.18+0.05 (V) PE 3641

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 13.46+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 13.47+0.01 (V) PE 3835

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 13.63+0.04 (V) PE 3641

(RN-CAS Registry Number 10025-87-3)

POCl3t

2E) POCl3 ** 13.84+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 13.85+0.02 (V) PE 3835

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 13.99+0.05 (V) PE 3641

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 15.10+0.01 PE 3835

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 15.35+0.06 PE 3641

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 15.36+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 16.13+0.02 PE 3835

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 16.34±0.02 PE 3641

(RN-CAS Registry Number 10025-87-3)

POCl3t

2 E) POCl3 ** 16.53+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 19.48+0.03 PE 3641

(RN-CAS Registry Number 10025-87-3)

POCljfA,) POCl3 ** 19.53+0.03 (V) PE 3669

(RN-CAS Registry Number 10025-87-3)

246
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance Method

potential

(eV)

Ref.

POCl3t

2A,) POCl3 ** (RN-CAS Registry Number 10025-87-3)

19.55+0.04 (V) PE 3835

PF2C1 + PF2C1 ** (RN-CAS Registry Number 14335-40-1)

12.8+0.1 (V) PE 3662

CSCl^Bj) CC12S

** 9.61 ±0.02 PE 3667

(RN-CAS Registry Number 463-71-8)

(HB-Threshold value approximately corrected for hot bands)

CSCl2t

2B2) C12CS ** 9.68 PE 4080

(RN-CAS Registry Number 463-71-8)

CSC12+C12CS ** 9.80 (V) PE 3746

(RN-CAS Registry Number 463-71-8)

CSCl2t

2Bj) C12CS ** 10.63 PE 4080

CSCl2t

2Bj)

(RN-CAS Registry Number 463-71-8)

CC12S

** 10.65+0.02 PE 3667

(RN-CAS Registry Number 463-71-8)

CSCl2t

2B2) CC12S

** 11.67+0.02 PE 3667

(RN-CAS Registry Number 463-71-8)

CSCl^ C12CS ** 11.93 (V) PE 4080

(RN-CAS Registry Number 463-71-8)

CSCl^1* C12CS ** 12.36 (V) PE 4080

CSCl^Aj)

(RN-CAS Registry Number 463-71-8)

CC12S

** 12.38+0.02 (V) PE 3667

(RN-CAS Registry Number 463-71-8)

CSCl? C12CS ** 12.68 (V) PE 4080

CSCl2t

2A2)

(RN-CAS Registry Number 463-71-8)

CC12S

** 12.69+0.02 (V) PE 3667

CSCl^Ai)

(RN-CAS Registry Number 463-71-8)

CC12S

** 14.23+0.02 PE 3667

CSCl^Bj)

(RN-CAS Registry Number 463-71-8)

C12CS ** 14.27 PE 4080

CSCl2t

2B,)

(RN-CAS Registry Number 463-71-8)

CC12S ** 14.99+0.02 PE 3667

(RN-CAS Registry Number 463-71-8)

CSClj* C12CS ** 15.11 (V) PE 4080

CSCl^Bj)

(RN-CAS Registry Number 463-71-8)

CC12S ** 15.99+0.02 PE 3667

(RN-CAS Registry Number 463-71-8)

CSClj* C12CS ** 16.22 (V) PE 4080

CSCl^Aj)

(RN-CAS Registry Number 463-71-8)

CC12S ** 18.09+0.02 PE 3667

(RN-CAS Registry Number 463-71-8)

CSC12* C12CS ** 18.32 (V) PE 4080

(RN-CAS Registry Number 463-71-8)

C^Ctf C2S2C14 ** 9.69 (V) PE 3898

(1,3-Dithietane, 2,2,4,4-tetrachloro-)

(RN-CAS Registry Number 20464-23-7)

247
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C4H3 SC1 + c4h3 sci ** (Thiophene, 2-chloro-)

(RN-CAS Registry Number 96-43-5)

9.06±0.05 El 3482

c4 h3 sci + C4H3 SC1 ** (Thiophene, 2-chloro-)

(RN-CAS Registry Number 96-43-5)

8.83 CTS 3787

NSC1 +

(

2A') NSC1 ** 10.96 (V) PE 3660

NSC1 +

(

2A',2A")

(RN-CAS Registry Number 17178-58-4)

NSC1 ** 11.80 (V) PE 3660

NSC1 +

(

2A')

(RN-CAS Registry Number 17178-58-4)

NSC1 ** 13.77 (V) PE 3660

(RN-CAS Registry Number 17178-58-4)

NSC1 +

(

2A') NSC1 ** 14.46 (V) PE 3660

(RN-CAS Registry Number 17178-58-4)

c,7h19n2sci+ C12 H7 NS(C1)(CH2)3 N(CH3)2 ** 8.25±0.07 CTS 4079

( 1 0/7-Phenothiazine- 1 0-propanamine, 2-chloro-A,yV-dimethyl-)

(RN-CAS Registry Number 50-53-3)

(ON-Other name: Aminazine)

C2oH24N3 SC1 + CI2 H7 NS(C1)(CH2)3 C4H8 N2 CH3 ** 7.03±0.07 CTS 4079

( l Oi/-Phenothiazine, 2-chloro- 1 0-[3-(4-methyl- 1 -piperazinyl)propyl]-)

(RN-CAS Registry Number 58-38-8)

(ON-Other name: Metherazine)

SOCl2+ SOCl2 ** 11.12 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOCl2+

socl2 ** 11.13 (V) PE 3646

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2 A') SOCl2 ** 11.3 (V) PE 3694

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A') SOCl2 ** 11.3 (V) PE 3879

(RN-CAS Registry Number 7719-09-7)

SOCl^ SOCl2 ** 11.89 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A") SOCl2 ** 11.9 (V) PE 3694

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2 A") SOCl2 ** 11.9 (V) PE 3879

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2 A') SOCl2 ** 12.15 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2 A') SOCl2 * 12.21 (V) PE 3694

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A') SOCl2 ** 12.21 (V) PE 3879

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2 A") SOCl2 ** 12.55 (V) PE 3694

(RN-CAS Registry Number 7719-09-7)

SOCl^ SOCl2 ** 12.55 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2 A',2 A') SOCl2 ** 12.55 (V) PE 3879

(RN-CAS Registry Number 7719-09-7)

248
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

SOCl2t

2A',2A") SOCl2 ** 13.04 (V) PE 3694

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A") SOCl2 ** 13.04 (V) PE 3879

(RN-CAS Registry Number 7719-09-7)

SOCl^ SOCl2 ** 13.15 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOClj* SOCl2 ** 13.25 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A') SOCl2 ** 15.69 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A') SOCl2 ** 15.8 (V) PE 3694

(RN-CAS Registry Number 7719-09-7)

SOCl2t

2A') SOCl2 ** 16 (V) PE 3879

(RN-CAS Registry Number 7719-09-7)

SOCl^ SOCl2 ** 16.32 (V) PE 3705

(RN-CAS Registry Number 7719-09-7)

so2 ci2+ so2ci2 ** 12.05 PE 3879

(RN-CAS Registry Number 7791-25-5)

S02Cl2t

2A2, 2 B,) so2 ci2 ** 12.4 (V) PE 3694

(RN-CAS Registry Number 7791-25-5)

so2ci2+ so2 ci2 ** 12.42 (V) PE 3705

S02 Cl2t

2A!)

(RN-CAS Registry Number 7791-25-5)

so2ci2 ** 13.0 PE 3879

S02 Cl2t

2B2) (RN-CAS Registry Number 7791-25-5)

so2ci2 ** 13.25 (V) PE 3694

(RN-CAS Registry Number 7791-25-5)

SOjCl^ so2 ci2 ** 13.26 (V) PE 3705

S02 Cl2t

2 A,)

(RN-CAS Registry Number 7791-25-5)

so2 ci2 ** 13.74 (V) PE 3694

(RN-CAS Registry Number 7791-25-5)

so2ci2+ so2 ci2 ** 13.74 (V) PE 3879

S02 Cl2t

2 B2?) (RN-CAS Registry Number 7791-25-5)

so2ci2 ** 13.74 (V) PE 3879

(RN-CAS Registry Number 7791-25-5)

so2ci2^ so2 ci2 ** 13.81 (V) PE 3705

S02 Cl2t

2A2 , 2B,)

(RN-CAS Registry Number 7791-25-5)

so2 ci2 ** 14.1 (V) PE 3694

(RN-CAS Registry Number 7791-25-5)

SOjCl^ so2ci2 ** 14.20 (V) PE 3705

S02 Cl2t

2A,?)

(RN-CAS Registry Number 7791-25-5)

S02C12 ** 16.93 PE 3879

S02Cl2t

2 A,)

(RN-CAS Registry Number 7791-25-5)

so2ci2 ** 16.93 (V) PE 3694

(RN-CAS Registry Number 7791-25-5)

so2ci2* so2ci2 ** 16.98 (V) PE 3705

(RN-CAS Registry Number 7791-25-5)

so2 ci2+ so2 ci2 ** 17.61 (V) PE 3694

S02 Cl2t

2 B,)

(RN-CAS Registry Number 7791-25-5)

so2 ci2 ** 17.61 (V) PE 3879

(RN-CAS Registry Number 7791-25-5)

249
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance Method

potential

(eV)

Ref.

so2 ci2* so2 ci2 ** (RN-CAS Registry Number 7791-25-5)

17.70 (V) PE 3705

so2 ci2+ so2 ci2 ** (RN-CAS Registry Number 7791-25-5)

18.12 (V) PE 3694

so2 c]2i

2 b2) so2 ci2 ** (RN-CAS Registry Number 7791-25-5)

18.12 (V) PE 3879

SOjCI^ so2 ci2 ** (RN-CAS Registry Number 7791-25-5)

18.20 (V) PE 3705

SOCl3t

2 E) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X)

9.63 ±0.02 PE 3835

SOCl3t

2A2) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X)

10.67±0.02 PE 3835

SOCl3t

2A,) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X) ~ 12.4 (V) PE 3835

SOCl3t

2 E) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X)

12.54±0.01 (V) PE 3835

SOCl3t

2 E) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X)

13.39±0.02 (V) PE 3835

SOCl3t

2A,) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X)

14.54±0.01 PE 3835

SOCl3t

2 E) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X)

15.36±0.01 PE 3835

SOCl3t

2A,) SOCl3 ** (RN-CAS Registry Number XXXXX-XX-X) ~ 18.7 (V) PE 3835

ch3 o2 sci + ch3 so2 ci ** (RN-CAS Registry Number 124-63-0)

11.74 (V) PE 3705

c17 hI7 n2osci + C12 H7 NS(Cl)COCH2CH2N(CH3 )2 ** 8.24±0.07

( 1 0/7-Phenothiazine, 2-chloro- 1 0-[3-(dimethylamino)- 1 -oxopropyl]-)

(RN-CAS Registry Number 3576-45-2)

CTS 4079

c19 h21 n2osci + C12 H7 NS(Cl)COCH2CH2N(C2H5)2** (10i/-Phenothiazine, 2-chloro- 10-[3-(diethylamino)

(RN-CAS Registry Number 800-22-6)

(ON-Other name: Chloracizine)

7.87±0.07

-1 -oxopropyl]-)

CTS 4079

c21 h26n3 osci + C21 H26N3 OSCl ** 8.63 ±0.07

(1-Piperazineethanol, 4-[3-(2-chloro-10//-phenothiazin-10-yl)propyl]-)

(RN-CAS Registry Number 58-39-9)

(ON-Other name: Ethaperazine)

CTS 4079

sf5 ci + SFjCl ** (RN-CAS Registry Number 13780-57-9)

12.335±0.005 PE 3655

CFSC1 + FC1CS ** (RN-CAS Registry Number 1495-18-7)

10.20 (V) PE 3746

so2 fci + so2fci ** 12.61 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

250
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

so2fci+ so2fci ** 13.36 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

so2fci + so2fci ** 14.14 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

so2fci+ so2fci ** 14.63 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

so2fci+ so2fci ** 15.04 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

so2fci+ so2fci ** 16.58 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

so2fci + so2fci ** 16.8 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

so2fci + so2fci ** 18.8 (V) PE 3705

(RN-CAS Registry Number 13637-84-8)

PSCl3t

2E) PSC13 ** 9.71 ±0.003 PE 4086

(RN-CAS Registry Number 3982-91-0)

PSCl3t

2E) PSC13 ** 10.11 (V) PE 4023

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 10.13±0.03 (V) PE 3669

(RN-CAS Registry Number 3982-91-0)

PSCl^Aj) PSC13 ** 11.74±0.1 PE 4086

PSCl3t

2A2) (RN-CAS Registry Number 3982-91-0)

PSC13 ** 11.99 (V) PE 4023

PSCl3t

2A2) (RN-CAS Registry Number 3982-91-0)

PSC13 ** 12.01 ±0.03 (V) PE 3669

PSCl3t

2A,)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 12. 15 ±0.1 PE 4086

PSCljfA,)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 12.56±0.03 (V) PE 3669

PSCljfA,)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** ~ 12.65 (V) PE 4023

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** ~ 12.65 (V) PE 4023

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 12.68 ±0. 1 (V) PE 4086

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 13.11 ±0.

1

PE 4086

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 13.39±0.03 (V) PE 3669

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 13.39 (V) PE 4023

PSCljt2A,)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 14.59±0.1 PE 4086

PSCl3t

2A,)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 14.77±0.03 (V) PE 3669

PSCl3t

2 A,)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 14.78 (V) PE 4023

PSCl3t

2E)

(RN-CAS Registry Number 3982-91-0)

PSC13 ** 15.37±0.1 PE 4086

(RN-CAS Registry Number 3982-91-0)

251
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance Method

potential

(eV)

Ref.

PSCl3t

2 E) PSC13 ** (RN-CAS Registry Number 3982-91-0)

15.80±0.03 (V) PE 3669

PSCl3t

2 E) PSC13 ** (RN-CAS Registry Number 3982-91-0)

15.80 (V) PE 4023

PSCljfA,) PSC13 ** (RN-CAS Registry Number 3982-91-0)

18.34±0.1 PE 4086

PSCIjfA,) PSC13 ** (RN-CAS Registry Number 3982-91-0)

18.62±0.03 (V) PE 3669

C4 H12 N2 PSC1 + PSCKMCH^

(RN-CAS Registry Number 3732-81-8)

8.23 ±0.003 PE 4086

c2 h6npsci2+ PSC12 N(CH3 )2 ** (RN-CAS Registry Number 1498-65-3)

8.97 ±0.003 PE 4086

Ar +

(

2 P3/2) Ar ** (RN-CAS Registry Number 7440-37-1)

15.75973 ±0.00001 S 3923

Ar+

(

2P3/2) Ar ** (RN-CAS Registry Number 7440-37-1)

15.753±0.002 TPE 3525

Ar+

(

2P1/2) Ar ** (RN-CAS Registry Number 7440-37-1)

15.930±0.002 TPE 3525

Ar +

(

2 P3/2) Ar ** (RN-CAS Registry Number 7440-37-1)

15.713±0.003 PEN 3541

Ar+2 Ar ** (RN-CAS Registry Number 7440-37-1)

43.7±0.5 SRP 3625

Ar +2 Ar ** (RN-CAS Registry Number 7440-37-1) —43 El 3445

Ar +3 Ar ** (RN-CAS Registry Number 7440-37-1)

-84 El 3445

Ar+4 Ar ** (RN-CAS Registry Number 7440-37-1)

-145 El 3445

Ca+ Ca ** (RN-CAS Registry Number 7440-70-2)

-6.1 El 3486

Ca +2 Ca ** (RN-CAS Registry Number 7440-70-2)

18 El 3486

Ca +3 Ca ** (RN-CAS Registry Number 7440-70-2)-69 El 3486

Ca +3

(

2 P3/2) Ca +2 ** (RN-CAS-Registry Number 14127-61-8)

50.9 1357 ±0.0003 S 4059

Ca* J(

2 P l/2) Ca +2 ** (RN-CAS-Registry Number 14127-61-8)

51.30014±0.0003 S 4059

Sc + Sc ** (RN-CAS Registry Number 7440-20-2)

6.7 El 3600

252
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

Sc +3 Sc +2 ** 24.75700 ±0.00006 S 3905

(RN-CAS Registry Number 14336-96-0)

Sc +3 Sc +2 ** 24. 75 704 ±0.00001 S 4007

(RN-CAS Registry Number 14336-96-0)

Sc +4

(

2P3/2) Sc +3 ** 73.49004±.00037 S 4064

(RN-CAS-Registry Number 22537-29-7)

Sc+4

(

2P1/2) Sc +3 ** 74.02635 ±.00037 S 4064

(RN-CAS-Registry Number 22537-29-7)

ScC2+ ScC2 ** 7.7±0.2 El 3470

(RN-CAS Registry Number 12175-91-6)

Ci5 H306Fi8Sc +

Ti+

Ti+

Ti+

Ti+

Ti +

(CF3 COCHCOCF3)3 Sc ** 10.13±0.07 (V) PE 3682

(Scandium, tris( 1,1, 1 ,5,5,5-hexafluoro-2,4-pentanedionato-0,O')-, (OC-6-1 1)-)

(RN-CAS Registry Number 18990-42-6)

Ti ** (RN-CAS Registry Number 7440-32-6)

Ti ** (RN-CAS Registry Number 7440-32-6)

Ti ** (RN-CAS Registry Number 7440-32-6)

TiO

(RN-CAS Registry Number 12137-20-1)

TiO O

(RN-CAS Registry Number 12137-20-1)

6.6±0.5 El 3449

7.3±0.6 El 3902

7.4±0.5 El 3594

14.5±0.7 El 3594

14.51±0.36 El 4103

TiC^ TiC2 ** 8.2±0.6 El 3902

(RN-CAS Registry Number 12071-32-8)

TiO+ TiO ** 6.8±0.5 El 3449

(RN-CAS Registry Number 12137-20-1)

TiO+ TiO ** 7.22±0.35 El 4103

(RN-CAS Registry Number 12137-20-1)

TiO+ TiO ** 7.3 ±0.5 El 3594

(RN-CAS Registry Number 12137-20-1)

TiOz+ TiOz ** (RN-CAS Registry Number 13463-67-7)

8.5±0.5 El 3594

TiOz+ Ti02 ** (RN-CAS Registry Number 13463-67-7)

1 1.56±0. 14 El 4103

ClsH306F„Ti+ (CF3COCHCOCF3)3Ti ** 7.94±0.07 (V) PE 3682

(Titanium, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,O')“> (OC-6-1 1)-) (RN-CAS Registry Number 22854-59-7)

C15H306F18Ti+ (CF3COCHCOCF3)3Ti ** 7.98 (V) PE 3681

(Titanium, tris( 1,1, 1 ,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-)

(RN-CAS Registry Number 22854-59-7)

253
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

TiS + TiS ** (RN-CAS Registry Number 12039-07-5)

7.1 ±0.3 El 3449

V+ V ** (RN-CAS Registry Number 7440-62-2)

7± 1 El 3801

VN+ VN ** (RN-CAS Registry Number 24646-85-3)8± 1 El 3801

vo+ VO ** (RN-CAS Registry Number 12035-98-2)

8± 1 El 3620

vo2+ vo2 ** (RN-CAS Registry Number 12036-21-4)

10±2 El 3620

v4o8+ v4o8 (RN-CAS Registry Number 12503-87-6)

13± 1 El 3620

v4oa v n ** v 4'“'10 (RN-CAS Registry Number 12503-98-9)

12± 1 El 3620

c15 h3 o6f18 v+ (CF3 COCHCOCF3)3V ** 8.68±0.07 (V) PE 3682

(Vanadium, tris( 1,1, 1 ,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (0C-6- 1 1)-)

(RN-CAS Registry Number 15695-77-9)

C15 H3 06F18V

+ (CF3 COCHCOCF3)3V ** 8.68 (V) PE 3681

(Vanadium, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-)

(RN-CAS Registry Number 15695-77-9)

Cr+ C6H6Cr(CO)3 C6H6 + 3CO 12.2±0.2 El

(Chromium, (i7

6-benzen e)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

Cr + C6H6Cr(CO)3 C6H6 + 3CO 13.50±0.1 El

(Chromium, (T} 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

Cr+ C6H5CH3 Cr(CO)3 C6H5 CH3 + 3CO 13.42±0.1 El

(Chromium, tricarbonyl[( 1 ,2,3,4, 5,6-i7)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

(MT-Metastable transition(s) observed)

Cr + C6H4(CH3)2Cr(CO)3 13.06±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

(MT-Metastable transition(s) observed)

(OP-The other product(s) is(are): C6H4(CH3)2 + 3CO)

Cr + C6H3 (CH3)3 Cr(CO)3 13.90±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,3,5-trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

(OP-The other product(s) is(are): C6H3 (CH3)3 + 3CO)

(MT-Metastable transition(s) observed)

3786

3788

3788

3788

3788

254
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance

products potential

(eV)

Method Ref.

Cr+ C6(CH3)6Cr(CO)3 C6(CH3)6 +3CO 13.00±0.1

(Chromium, tricarbonyl[(l,2,3,4,5,6-T7)-hexamethylbenzene]-)

(RN-CAS Registry Number 12088-11-8)

(MT-Metastable transition(s) observed)

Cr+ C6H5 CH2OHCr(CO)3 14.01 ±0.1

(Chromium, [( 1 ,2, 3 ,4, 5 , 6-T7)-benzenemethanol]tricarbonyl-)

(RN-CAS Registry Number 12116-45-9)

(MT-Metastable transition(s) observed)

(OP-The other product(s) is(are): C6H5 CH2OH+ 3CO)

Cr+ C6H5 OCH3 Cr(CO)3 12.65±0.1

(Chromium, tricarbonyl[(l,2,3,4,5,6-T7)-methoxybenzene]-)

(RN-CAS Registry Number 12116-44-8)

(MT-Metastable transition(s) observed)

(OP-The other product(s) is(are): C6H5 OCH3 +3CO)

Cr+ C6H5 COOCH3 Cr(CO)3 14.00±0.1

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5,6-i7)-methylbenzoate]-)

(RN-CAS Registry Number 12125-87-0)

(OP-The other product(s) is(are): C6H5 COOCH3 +3CO)

(MT-Metastable transition(s) observed)

Cr+ C6H5NH2Cr(CO)3 C6H5NH2 +3CO 13.17+0.1

(Chromium, (i7

6-benzenamine)tricarbonyl-)

(RN-CAS Registry Number 12108-11-1)

(MT-Metastable transition(s) observed)

Cr+ ((CH3)2N)3 PCr(CO)5 (RN-CAS Registry Number XXXXX-XX-X)

Cr+ (((CH3)2N)3 P)2Cr(CO)4 (RN-CAS Registry Number 19976-85-3)

Cr+ C6H5 ClCr(CO)3 C6H5 Cl + 3CO

(Chromium, tricarbonyl(r)6-chlorobenzene)-)

(RN-CAS Registry Number 12082-03-0)

(MT-Metastable transition(s) observed)

El

El

3788

3788

El 3788

El 3788

El 3788

22.3+0.05 El 3952

22.2+0.05 El 3952

14.10+0.1 El 3788

C6H6Cr+ C6H6Cr(CO)3 3CO 9.0±0.2 El 3786

(Chromium, (i7 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

C6H6Cr+ C6H6Cr(CO)3 3CO 10.34+0.1 El 3788

(Chromium, (7) 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

C/HgCr4^ C6H5CH3 Cr(CO)3 3CO 10.04+0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-T7)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

(MT-Metastable transition(s) observed)

Cg H10Cr+ C6H4(CH3)2Cr(CO)3 3CO 9.60+0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

(MT-Metastable transition(s) observed)

255
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other appearance Method Ref. products potential

(eV)

C9H,2 Cr + C6H3(CH3)3 Cr(CO)3 3CO 10.35±0.1

(Chromium, tricarbonyl[(l,2,3,4,5,6-7j)-l,3,5-trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

(MT-Metastable transition(s) observed)

El 3788

C,oHioCr + (C5 H5)2Cr

(Chromocene)

(RN-CAS Registry Number 1271-24-5)

5.50 PE 3725

C„HnCr+ C5 H5 CrC6H6 (Chromium, (7j 6-benzene)(i7 5 -2,4-cyclopentadien-

(RN-CAS Registry Number 12093-16-2)

6.20±0.1 (V)

i-yi)-)

PE 3686

CI2 H12Cr+ (C6H6) 2Cr

(Chromium, bis(benzene)-)

(RN-CAS Registry Number 1271-54-1)

5.4±0. 1 (V) PE 3686

C12 H18 Cr+ C6(CH3)6Cr(CO)3 3CO 9.82±0.1

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-hexamethylbenzene]-)

(RN-CAS Registry Number 12088-11-8)

(MT-Metastable transition(s) observed)

El 3788

C14H16Cr+ (C6H5 CH3)2Cr

(Chromium, bis(i7

6-methyl benzene)-)

(RN-CAS Registry Number 12087-58-0)

5.24±0.1 (V) PE 3686

C20H44Cr+ ((CH3)3 CCH2)4Cr

(RN-CAS Registry Number 37007-84-4)

7.25 ±0.1 (V) PE 3830

C6H7 NCr+ C6H5 NH2 Cr(CO)3 3CO

(Chromium, (7)

6-benzenamine)tricarbonyl-)

(RN-CAS Registry Number 12108-11-1)

(MT-Metastable transition(s) observed)

9.96±0.1 El 3788

CrCO+2 CrCO ** (RN-CAS Registry Number XXXXX-XX-X)

1 7.3 ± 1.0 El 3572

C606Cr+ Cr(CO)6 (RN-CAS Registry Number 13007-92-6)

8.40±0.02 (V) PE 3979

C606Cr+ Cr(CO)6 (RN-CAS Registry Number 13007-92-6)

8. 1 9 ±0.El 3582

C7H6OCr+ C6H6Cr(CO)3 2CO 7.9±0.2 El 3786

(Chromium, (T/

6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

C7 H6OCr + C6H6Cr(CO)3 2CO 8.09 ±0.1 El 3788

(Chromium, (i7 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

256
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method

products potential

(eV)

C7H8OCr+ C6H5 CH2OHCr(CO)3 3CO 10.35 ±0.1 El

(Chromium, [(l,2,3,4,5,6-7])-benzenemethanol]tricarbonyl-)

(RN-CAS Registry Number 12116-45-9)

(MT-Metastable transition(s) observed)

C7H8OCr+ C6H5OCH3 Cr(CO)3 3CO 9.90±0.1 El

(Chromium, tricarbonyl[( 1 ,2, 3 ,4, 5 , 6-i7)-methoxybenzene]-)

(RN-CAS Registry Number 12116-44-8)

(MT-Metastable transition(s) observed)

Ref.

3788

3788

C8H8OCr+ C6H5 CH3 Cr(CO)3 2CO 8. 11 ±0.1 El 3788

(Chromium, tricarbony1[( 1 ,2, 3 ,4, 5 , 6-7j)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

(MT-Metastable transition(s) observed)

C9H10OCr+ C6H4(CH3)2Cr(CO)3 2CO 7.85 ±0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

(MT-Metastable transition(s) observed)

C10H12OCr+ C6H3 (CH3)3 Cr(CO)3 2CO 8.00±0.1 El 3788

(Chromium, tricarbonyl[( 1 ,2, 3 ,4, 5, 6-17)- 1,3, 5-trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

(MT-Metastable transition(s) observed)

C13HlgOCr+ C6(CH3)6Cr(CO)3 2CO 7.70±0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-rj)-hexamethylbenzene]-)

(RN-CAS Registry Number 12088-11-8)

(MT-Metastable transition(s) observed)

C8H602Cr+ C6H6Cr(CO)3 CO 7.25 ±0.1 El 3788

(Chromium, (i7 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

C8H602Cr+ C6H6Cr(CO)3 CO 7.4±0.2 El 3786

(Chromium, (i7

6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(MT-Metastable transition(s) observed)

C8H802Cr+ C6H5CH2OHCr(CO)3 2CO 8.19±0.1 El

(Chromium, [(l,2,3,4,5,6-7j)-benzenemethanol]tricarbonyl-)

(RN-CAS Registry Number 12116-45-9)

(MT-Metastable transition(s) observed)

C8H802Cr+ C6H5OCH3 Cr(CO)3 2CO 7.90±0.1 El

(Chromium, tricarbonyl[( 1 ,2, 3 ,4, 5 , 6-rj)-methoxybenzene]-)

(RN-CAS Registry Number 12116-44-8)

(MT-Metastable transition(s) observed)

C8Hg02Cr+ C6H5 COOCH3 Cr(CO)3 3CO 10.00±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-T7)-methylbenzoate]-)

(RN-CAS Registry Number 12125-87-0)

(MT-Metastable transition(s) observed)

3788

3788

3788

257
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C9H802 Cr+ C6H5 CH3 Cr(CO)3 CO 7.09±0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

(MT-Metastable transition(s) observed)

C10H10O2 Cr + C6 H4(CH3 )2Cr(CO)3 CO 7.00±0.1 El 3788

(Chromium, tricarbonyl[( 1 ,2,3,4,5,6-17)- 1 ,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

(MT-Metastable transition(s) observed)

Cu H12 02 Cr + C6H3 (CH3)3 Cr(CO)3 CO 6.69±0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,3,5-trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

(MT-Metastable transition(s) observed)

C14H1802 Cr+ C6(CH3 )6Cr(CO)3 CO 6.45+0.1 El 3788

(Chromium, tricarbonyl[(l,2,3,4,5,6-Tj)-hexamethylbenzene]-)

(RN-CAS Registry Number 12088-11-8)

(MT-Metastable transition(s) observed)

C9H603 Cr + C6H6Cr(CO)3 (Chromium, (7} 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

C„H6OjCr + C6H6Cr(CO)3 ** (Chromium, (rj

6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

C9H603 Cr+ C6H6Cr(CO)3 (Chromium, (i7 6-benzene)tricarbonyl-)

(RN-CAS Registry Number 12082-08-5)

(AV-Average of two values)

6.74±0.1 El 3788

7.0±0.2 El 3786

7.28 CTS 4029

C9Hg03 Cr+ C6H5CH2OHCr(CO)3 CO 7.32+0.1 El

(Chromium, [(l,2,3,4,5,6-i7)-benzenemethanol]tricarbonyl-)

(RN-CAS Registry Number 12116-45-9)

(MT-Metastable transition(s) observed)

C9H803 Cr + C6H5OCH3 Cr(CO)3 CO 6.95+0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-rj)-methoxybenzene]-)

(RN-CAS Registry Number 12116-44-8)

(MT-Metastable transition(s) observed)

C9Hg 03 Cr + C6H5 COOCH3 Cr(CO)3 2CO 8.27±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-methylbenzoate]-)

(RN-CAS Registry Number 12125-87-0)

(MT-Metastable transition(s) observed)

C10H8 O3 Cr + C6H5CH3Cr(CO)3 ** 6.69+0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

C10H8 O3 Cr+ C6H5 CH3 Cr(CO)3 ** 7.29 CTS

(Chromium, tricarbonyl[( 1 ,2,3,4,5,6-rj)-methylbenzene]-)

(RN-CAS Registry Number 12083-24-8)

(AV-Average of two values)

3788

3788

3788

3788

4029

258
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method

CnH10O3 Cr+ C6H4(CH3)2 Cr(CO)3 ** 6.70±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-i7)-l,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

C„H10O3 Cr+ C6H4(CH3)2Cr(CO)3 ** 7.29 CTS

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5, 6-tj)- 1 ,2-dimethylbenzene]-)

(RN-CAS Registry Number 12129-29-2)

(AV-Average of two values)

Ref.

3788

4029

C12H1203 Cr+ C6H3 (CH3)3 Cr(CO)3 ** 6.60±0.1 El 3788

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5

,

6-tj)- 1 , 3, 5-trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

C12H1203 Cr+ C6H3(CH3)3 Cr(CO)3 ** 7.29 CTS 4029

(Chromium, tricarbony1[( 1 ,2, 3,4, 5

,

6-tj)- 1,3,5 -trimethylbenzene]-)

(RN-CAS Registry Number 12129-67-8)

(AV-Average of two values)

C15 H1803Cr+ C6(CH3)6Cr(CO)3 ** 6.35 ±0.1 El 3788

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5 , 6-Tj)-hexamethylbenzene]-)

(RN-CAS Registry Number 12088-11-8)

C10Hg O4Cr+ C6H5CH2OHCr(CO)3 ** 6.92±0.1 El

(Chromium, [(l,2,3,4,5,6-Tj)-benzenemethanol]tricarbonyl-)

(RN-CAS Registry Number 12116-45-9)

C10H8O4Cr+ C6H5OCH3Cr(CO)3 ** 6.75±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-Tj)-methoxybenzene]-)

(RN-CAS Registry Number 12116-44-8)

C10H8O4Cr+ C6H5OCH3Cr(CO)3 ** 7.32 CTS

(Chromium, tricarbonyl[(l,2,3,4,5,6-Tj)-methoxybenzene]-)

(RN-CAS Registry Number 12 11 6-44-8)

(AV-Average of two values)

C10H8O4Cr+ C6H5 COOCH3 Cr(CO)3 CO 7.60±0.1 El

(Chromium, tricarbonyl[(l,2,3,4,5,6-Tj)-methylbenzoate]-)

(RN-CAS Registry Number 12125-87-0)

(MT-Metastable transition(s) observed)

C„H8 OsCr+ C6H5COOCH3 Cr(CO)3 ** 7.02+0.1

(Chromium, tricarbonyl[( 1 ,2, 3,4, 5 , 6-7j)-methylbenzoate]-)

(RN-CAS Registry Number 12125-87-0)

El 3788

C,H606Cr+ (CO)5CrC(OCH3)CH3 ** 7.46+0.1

(Chromium, pentacarbonyl(l-methoxyethylidene)-, (OC-6-21))

(RN-CAS Registry Number 20540-69-6)

El 3582

C13H806Cr+ C6H5 C(OCH3)Cr(CO)5 ** 7.26±0.1

(Chromium, pentacarbonyl(methoxyphenylmethylene)-, (OC-6-21)-)

(RN-CAS Registry Number 27436-93-7)

El 3582

Ci4H10O6Cr+ C6H4(CH3)C(OCH3)Cr(CO)5 ** 7. 13 ±0.1 El

(Chromium, pentacarbonyl(methoxy(4-methylphenyl)methylene)-, (OC-6-21)-)

(RN-CAS Registry Number 29160-36-9)

3582

3788

3788

4029

3788

259
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance

products potential

(eV)

Method Ref.

C15 H21 06Cr+ (CH3 COCHCOCH3)3 Cr ** 7.46±0.07 (V)

(Chromium, tris(2,4-pentanedionato-0,0')-, (OC-6-11)-)

(RN-CAS Registry Number 21679-31-2)

PE 3682

CuH|o07 Cr + C6H4(OCH3 )C(OCH3)Cr(CO)5 ** 7.05±0.1

(Chromium, pentacarbonyl(o,a-dimethoxybenzylidene)-)

(RN-CAS Registry Number 27436-99-3)

El 3582

C7H7 NOCr+ C6H5 NH2 Cr(CO)3 2CO 7.84±0.1

(Chromium, (Tj

6-benzenamine)tricarbonyl-)

(RN-CAS Registry Number 12108-11-1)

(MT-Metastable transition(s) observed)

El 3788

C8 H7 N02Cr+ C6H5 NH2 Cr(CO)3 CO 6.75 ±0.1

(Chromium, (rj

6-benzenamine)tricarbonyl-)

(RN-CAS Registry Number 12108-11-1)

(MT-Metastable transition(s) observed)

El 3788

C7 H5 N03 Cr+ C5 H5 Cr(NO)(CO)2 ** 7.80 (Chromium, dicarbonyl(i75 -2,4-cyclopentadien- l-yl)nitrosyl-)

(RN-CAS Registry Number 36312-04-6)

El 3579

G,H7N03 Cr+ C6H5 NH2Cr(CO)3 ** 6.52±0.1

(Chromium, (7j 6-benzenamine)tricarbonyl-)

(RN-CAS Registry Number 12108-11-1)

El 3788

Cn Hn N03 Cr+ C6H5 N(CH3)2Cr(CO)3 ** 7.38 (Chromium, tricarbonyl(A^^V-dimethylbenzenamine)-)

(RN-CAS Registry Number 12109-10-3)

CTS 4029

C13 H706FCr+ C6H4FC(OCH3)Cr(CO)5 ** 7.32±0.1 El

(Chromium, pentacarbonyl[(4-fluorophenyl)methoxymethylene]-, (OC-6-2 1 )-)

(RN-CAS Registry Number 27436-94-8)

3582

C14H706F3Cr+ C6H4(CF3)C(OCH3)Cr(CO)5 ** 7.34±0.1 El

(Chromium, pentacarbonyl[a-methoxy-o-(trifluoromethyl)benzylidene]-)

(RN-CAS Registry Number 32011-10-2)

3582

C14H7 06F3Cr+ C6H4(CF3)C(OCH3)Cr(CO)5 ** 7.42±0.1 El 3582

(Chromium, pentacarbonyl[methoxy[4-(trifluoromethyl)phenyl]methylene]-, (OC-6-21)-)

(RN-CAS Registry Number 27637-27-0)

C15 H1206F9Cr+ (CF3 COCHCOCH3)3Cr ** 8. 58 ±0.07 (V) PE 3682

(Chromium, tris( 1,1,1 -trifluoro-2,4-pentanedionato-0,0')

(RN-CAS Registry Number 14592-89-3)

C15 H3 06F18Cr+ (CF3 COCHCOCF3)3Cr ** 9.53 (V) PE 3681

(Chromium, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-)

(RN-CAS Registry Number 14592-80-4)

C15 H3 06F18Cr+ (CF3 COCHCOCF3)3 Cr ** 9.57±0.07 (V) PE 3682

(Chromium, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-)

(RN-CAS Registry Number 14592-80-4)

260
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

C16H44Si4Cr+ ((CH^SiCH^Cr ** 7.26±0.1 (V) PE 3830

(RN-CAS Registry Number 35394-18-4)

((CH3)2N)3 PCr(CO)5 5CO 12.5 ±0.05 El 3952

(RN-CAS Registry Number XXXXX-XX-X)

(((CH3)2N)3 P)2Cr(CO)4 11.0±0.05 El 3952

(RN-CAS Registry Number 19976-85-3)

C7H18N3 OPCr+ ((CH3)2N)3 PCr(CO)5 4CO

(RN-CAS Registry Number XXXXX-XX-X)

9.8±0.05 El 3952

C9H18N303 PCr+ ((CH3)2N)3PCr(CO)5 2CO

(RN-CAS Registry Number XXXXX-XX-X)

8.6±0.05 El 3952

Ci„H,gN304PCr+ ((CH3)2N)3 PCr(CO)5 CO

(RN-CAS Registry Number XXXXX-XX-X)

7.6±0.05 El 3952

CnH18N3 05 PCr+ ((CH3)2N)3PCr(CO)5 (RN-CAS Registry Number XXXXX-XX-X)

6.6±0.05 El 3952

C15H36N603 P2Cr+ (((CH3)2N)3 P)2Cr(CO)4 CO

(RN-CAS Registry Number 19976-85-3)

9.5±0.05 El 3952

C16H36N604P2Cr+ (((CH3)2N)3 P)2Cr(CO)4 (RN-CAS Registry Number 19976-85-3)6.5±0.05 El 3952

CrP6F+ Cr(PF3)6 (RN-CAS Registry Number 26117-61-3)

9.0 PE 4021

C9H805 SCr+ C4H8 SCr(CO)5 ** 7.45 ±0.05

((OC-6-22)-Pentacarbonyl(tetrahydrothiophene)chromium)

(RN-CAS Registry Number 15038-40-1)

El 3498

C7H606SCr+ SO(CH3)2Cr(CO)5 ** 7.64±0.05

((OC-6-22)-Pentacarbonyl(sulfinylbis(methane)-5)chromium)

(RN-CAS Registry Number 36083-80-4)

El 3498

C7H408 SCr+ C2H402 S0Cr(C0)5 ** 7.80±0.05

((OC-6-22)-Pentacarbonyl(l,3,2-dioxathiolane 2-oxide-5)chromium)

(RN-CAS Registry Number 36252-44-5)

El 3498

C6H5 ClCr+ C6H5 ClCr(CO)3 3CO

(Chromium, tricarbonyl(7}6-chlorobenzene)-)

(RN-CAS Registry Number 12082-03-0)

(MT-Metastable transition(s) observed)

10.10±0.1 El 3788

C^OClCr* C6H5 ClCr(CO)3 2CO

(Chromium, tricarbonyl(i7

6-chlorobenzene)-)

(RN-CAS Registry Number 12082-03-0)

(MT-Metastable transition(s) observed)

8. 1 8 ±0.

1

El 3788

C6H18N3 PCr+ C6H18N3 PCr+

261
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref.

products potential

(eV)

C8H5 02 ClCr+ C6H5 ClCr(CO)3 CO 7.45±0.1 El 3788

(Chromium, tricarbonyl(i7

6-chlorobenzene)-)

(RN-CAS Registry Number 12082-03-0)

(MT-Metastable transition(s) observed)

C9H5 03 ClCr+ C6H5 ClCr(CO)3 ** (Chromium, tricarbonyl(rj

6-chlorobenzene)-)

(RN-CAS Registry Number 12082-03-0)

7. 00 ±0.1 El 3788

C13 H7 06ClCr + C6H4ClC(OCH3)Cr(CO)5 ** 7.34±0.1 El

(Chromium, pentacarbonyl[(4-chlorophenyl)methoxymethylene]-, (OC-6-2 1)-)

(RN-CAS Registry Number 29160-37-0)

3582

Mn+ HMn(CO)5 (RN-CAS Registry Number 16972-33-1)

17.3 El 3814

Mn+ (CH3)3 SiMn(CO)5 (RN-CAS Registry Number 26500-16-3)

21.7 El 3814

Mn+ (CH3)3 SiMn(CO)4PF3 (RN-CAS Registry Number 33989-27-4)

21.9 El 3814

MnH+ HMn(CO)5 5CO

(RN-CAS Registry Number 16972-33-1)

13.8 El 3814

C10HioMn + (C5 H5)2Mn

(Manganocene)

(RN-CAS Registry Number 1271-27-8)

6.55 PE 3725

C11 H11 Mn+ C5 H5 MnC6H6 (Manganese, (Tj

6-benzene)(i75 -2,4-cyclopentadien-

(RN-CAS Registry Number 1271-43-8)

6.36±0.1 (V)

—i—yi)—) PE 3686

C32H16N8 Mn+ C32H16N8 Mn ** 7.26±0.10 El

(Manganese, [2977,3 l//-phthalocyaninato(2>A^29,7V

30,7V31 ,7V32]- (SP-4-1)-)

(RN-CAS Registry Number 14325-24-7)

(ON-Other name: Manganese phthalocyanine)

3829

MnCO+ (CH3 ) 3 SiMn(CO)5 (RN-CAS Registry Number 26500-16-3)

17.9 El 3814

MnC202+ HMn(CO)5 (RN-CAS Registry Number 16972-33-1)

13.7 El 3814

MnC3 03+ HMn(CO)5 (RN-CAS Registry Number 16972-33-1)

13.2 El 3814

MnC404+ HMn(CO)5 (RN-CAS Registry Number 16972-33-1)

11.2 El 3814

CHOMn+ HMn(CO)5 4CO

(RN-CAS Registry Number 16972-33-1)

12.7 El 3814

262
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C2H02Mn+ HMn(CO)5 3CO 10.3 El 3814

(RN-CAS Registry Number 16972-33-1)

C3H03 Mn+ HMn(CO)5 2CO 9.9 El 3814

(RN-CAS Registry Number 16972-33-1)

C8H503Mn+ C5H5 Mn(CO)3 ** 8.12±0.1 El 3578

(Manganese, tricarbonyl(i7

5 -2,4-cyclopentadien- 1—yl)—

)

(RN-CAS Registry Number 12079-65-1)

C4H04Mn+ HMn(CO)5 CO 8.7 El 3814

(RN-CAS Registry Number 16972-33-1)

C5H05Mn+ HMn(CO)5 ** 8.5+0.1 El 3814

(RN-CAS Registry Number 16972-33-1)

C15 H21 06Mn+ (CH3COCHCOCH3)3Mn ** 7.32±0.07 (V) PE 3682

(Manganese, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-)

(RN-CAS Registry Number 14284-89-0)

MnF+ MnF ** 8.51 ±0.2 El 3623

(RN-CAS Registry Number 13569-25-0)

(TW-Threshold value approximately corrected to 298°K)

MnF+ MnF2 13.60±0.2 El 3623

(RN-CAS Registry Number 7782-64-1)

(TW-Threshold value approximately corrected to 298°K)

MnF^ MnF2 . ** 11. 38 ±0.2 El 3623

(RN-CAS Registry Number 7782-64-1)

(TW-Threshold value approximately corrected to 298°K)

MnF2+ MnF3 14.79±0.2 El 3623

(RN-CAS Registry Number 7783-53-1)

(TW-Threshold value approximately corrected to 298°K)

MnF3+ MnF3 ** 12.57±0.2 El 3623

(RN-CAS Registry Number 7783-53-1)

(TW-Threshold value approximately corrected to 298°K)

MnF3+ MnF4 15.50±0.2 El 3623

(RN-CAS Registry Number 15195-58-1)

(TW-Threshold value approximately corrected to 298°K)

MnF^ MnF4 ** 13.46±0.2 El

(RN-CAS Registry Number 15195-58-1)

(TW-Threshold value approximately corrected to 298°K)

C15 H3 06F18Mn+ (CF3 COCHCOCF3)3Mn ** 9.2 (V) PE

(Manganese, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (0C-6-1 1)-) (RN-CAS Registry Number 14354-50-8)

3623

3682

263
Table of Ion Energetics Measurements-—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C19 H3 O10Fi 8 Mn (CF3 COCHCOCF3)3 (CO)4Mn ** 8. 11 ±0.07 (V) PE

(Tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato)manganese tetracarbonyl)

(RN-CAS Registry Number XXXXX-XX-X)

3682

C3 H9 SiMn + (CH3 ) 3 SiMn(CO)5 (RN-CAS Registry Number 26500-16-3)

12.8 El 3814

C4H9OSiMn + (CH3)3 SiMn(CO)5 4CO

(RN-CAS Registry Number 26500-16-3)

12.0 El 3814

C4 H9OSiMn + (CH3)3 SiMn(CO)4 PF3 3CO + PF3 (RN-CAS Registry Number 33989-27-4)

12.7 El 3814

C5 H902 SiMn + (CH3 )3 SiMn(CO)5 3CO

(RN-CAS Registry Number 26500-16-3)

10.8 El 3814

C5 H902 SiMn + (CH3)3 SiMn(CO)4 PF3 2CO + PF3 (RN-CAS Registry Number 33989-27-4)

11.1 El 3814

C6 H903 SiMn + (CH3 )3 SiMn(CO)5 2CO

(RN-CAS Registry Number 26500-16-3)

10.2 El 3814

C7 H904 SiMn + (CH3)3 SiMn(CO)5 CO

(RN-CAS Registry Number 26500-16-3)

9.2 El 3814

C7 H904SiMn + (CH3)3 SiMn(CO)4PF3 PF3 (RN-CAS Registry Number 33989-27-4)

9.9 El 3814

C5 H3 Os SiMn + SiH3 Mn(CO)5 ** (RN-CAS Registry Number 15770-61-3)8.99±0.02 (V) PE 3827

C8 H905 SiMn + Si(CH3)3 Mn(CO)5 ** (RN-CAS Registry Number XXXXX-XX-X)

9.0±0.1 (V) PE 3827

Cg H905 SiMn + (CH3)3 SiMn(CO)5 ** (RN-CAS Registry Number 26500-16-3)8.7±0.2 El 3814

C7 H904F3 SiPMn + (CH3)3 SiMn(CO)4PF3 ** (RN-CAS Registry Number 33989-27-4)

8.7±0.2 El 3814

C6 H903 F6SiP2 Mn+ (CH3)3 SiMn(CO)3 (PF3)2 ** (RN-CAS Registry Number 36087-62-4)

8.1 ±0.1 El 3814

C5 H902 F9 SiP3 Mn+ (CH3)3 SiMn(CO)2 (PF3)3 ** (RN-CAS Registry Number 36087-61-3)

9.1 ±0.2 El 3814

C10H15 SMn+ C4H8 SC5 H4CH3 Mn(CO)2 2CO 7.9±0.1 El 3498

(Dicarbonyl(( 1 ,2, 3,4, 5-)- 1 -methyl-2,4-cyclopentadien-

(RN-CAS Registry Number 12153-94-5)

1 -yl)(tetrahydrothiophene)manganese)

C18 H17 SMn + (C6H5)2 SC5 H4 CH3 Mn(CO)2 2CO 8.0±0.

El 3498

(Dicarbonyl(( 1 ,2, 3, 4, 5-)- 1 -methyl-2,4-cyclopentadienese)

(RN-CAS Registry Number 36154-47-9)

1 -yl)( 1 , 1 '-thiobis(benzene)-5)mangan

264
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance Method Ref. products potential

(eV)

C8 H13 OSMn+ C5 H4CH3 Mn(CO)2 SO(CH3)2 2CO 7.9±0.1 El 3498

(Dicarbonyl(( 1 ,2, 3, 4, 5-)- 1 -methyl-2,4-cyclopentadien- 1 -yl)(sulfinylbis(methane)-5)mangane

se) (RN-CAS Registry Number 12153-02-5)

C10H15 OSMn+ C4H8 SOC5 H4CH3 Mn(CO)2 2CO 7.5 ±0.1 El 3498

(Dicarbony1(( 1 ,2, 3,4, 5-)- 1 -methyl-2,4-cyclopentadiene- 1 -yl)(tetrahydrothiohene 1 -oxide-5)

manganese)

(RN-CAS Registry Number 12153-95-6)

CI8H17OSMn+ (C6H5 )2 SOC5 H4CH3 Mn(CO)2 2CO 7.8±0.1 El 3498

(Dicarbonyl(( 1 ,2, 3,4,5—tj)— 1 -methyl-2,4-cyclopentadien- 1 -yl)( 1 , 1 '-sulfmylbis(benzene)-S)m

anganese)

(RN-CAS Registry Number 36154-49-1)

C12 H1502 SMn+ C4H8 SC5 H4CH3 Mn(CO)2 ** 6.45 ±0.05 El 3498

(Dicarbonyl(( 1 ,2, 3 ,4, 5-7])- 1 -methyl-2,4-cyclopentadien- 1 -yl)(tetrahydrothiophene)manganes

e) (RN-CAS Registry Number 12153-94-5)

C20H17O2 SMn+ (C6H5)2 SC5 H4CH3Mn(CO)2 ** 6.27+0.05 El 3498

(Dicarbonyl(( 1 ,2, 3,4,5-)- 1 -methyl-2,4-cyclopentadien- 1 -yl)( 1 , 1 '-thiobis(benzene)-5)mangan

ese)

(RN-CAS Registry Number 36154-47-9)

Cg Hn03 SMn+ C2H402 S0C5 H4CH3 Mn(C0)2 2CO 7.75 ±0.1 El 3498

(Dicarbonyl( 1 , 3,2-dioxathiolane 2-oxide-5)(( 1 ,2, 3,4, 5-7])- 1 -methyl-2,4-cyclopentadien- 1 -yl

)manganese)

(RN-CAS Registry Number 12152-97-5)

C10H13 O3 SMn* C5 H4CH3 Mn(CO)2 SO(CH3)2 ** 7.19±0.05 El 3498

(Dicarbonyl((l, 2, 3, 4, 5-)-l-methyl-2,4-cyclopentadien- l-yl)(sulfinylbis(methane)-5)mangane

se) (RN-CAS Registry Number 12153-02-5)

C12 H15 03 SMn+ C4H8 SOC5 H4CH3 Mn(CO)2 ** 6.79±0.05 El 3498

(Dicarbonyl(( 1 ,2,3,4,5 -t})- 1 -methyl-2,4-cyclopentadiene- 1 -yl)(tetrahydrothiophene 1 -oxideS)manganese)

(RN-CAS Registry Number 12153-95-6)

C20H17O3 SMn+ (C6H5)2SOC5 H4CH3 Mn(CO)2 ** 6.76±0.05 El 3498

(Dicarbonyl(( 1,2, 3 ,4, 5-7])- 1 -methyl-2,4-cyclopentadien- 1 -yl)( 1 , 1 '-sulfInylbis(benzene)-S)m

anganese)

(RN-CAS Registry Number 36154-49-1)

C10HuO5 SMn+ C2H402 S0C5H4CH3 Mn(C0)2 ** 7.38±0.05 El 3498

(Dicarbonyl( 1 ,3,2-dioxathiolane 2-oxide-5)(( 1 ,2,3,4,5 -t])- 1 -methyl-2,4-cyclopentadien- 1 -yl

)manganese)

(RN-CAS Registry Number 12152-97-5)

265
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C505 ClMn+ Mn(CO)5 Cl ** (RN-CAS Registry Number 14100-30-2)8.94 (V) PE 3866

Fe+ (C5 H5)2 Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

Fe + (C5 H5)2Fe

(Ferrocene)

(RN-CAS-Registry Number 102-54-5)

Fe+ (C5 H5 )2 Fe (C5 H5)2 (Ferrocene)

(RN-CAS Registry Number 102-54-5)

(MT-Metastable transition(s) observed)

Fe + (C5 H5)2 Fe (C5 H5)2 (Ferrocene)

(RN-CAS Registry Number 102-54-5)

(PC-Appearance potential of the corresponding metastable transition)

Fe + (C5 H5 ) 2 Fe 2C5 H5 (Ferrocene)

(RN-CAS Registry Number 102-54-5)

(PC-Appearance potential of the corresponding metastable transition)

Fe + ((CH3)2 N)3 PFe(CO)4 (RN-CAS Registry Number 19372-47-5)

12.0± 1.5

14.10±0.15

14.00±0.25

14.4±0.5

18.9±0.5

17.0±0.05

RPD

EDD

DC

El

El

El

3793

4072

3628

3628

3628

3952

C3 H3 Fe+

C3 H3 Fe +

(C5 H5)2 Fe

(Ferrocene)

(RN-CAS-Registry Number 102-54-5)

(C5 H5)2 Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

17.75±0.2

18.06±0.10

EDD

El

4072

3628

C5 H5 Fe + (C5 H5)2 Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

13.9±0.2 RPD 3793

C5 H5 Fe+ (C5 H5) 2 Fe

(Ferrocene)

(RN-CAS-Registry Number 102-54-5)

12.95 ±0. 1

5

EDD 4072

C5 H5 Fe + (C5 H5 ) 2 Fe C5 H5 (Ferrocene)

(RN-CAS Registry Number 102-54-5)

(MT-Metastable transition(s) observed)

14.25±0.25 DC 3628

C5 H5 Fe + (C5 H5)2 Fe C5 H5 (Ferrocene)

(RN-CAS Registry Number 102-54-5)

(PC-Appearance potential of the corresponding metastable transition)

14.0±0.5 El 3628

C10H10Fe + (C5 H5)2 Fe ** 6.78 ±0.05 PI 3729

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

C10H10Fe + (C5 H5 ) 2 Fe ** 6.72 PE 3725

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

266
Table of Ion Energetics Measurements—Continued

CioH10Fe

C,oH10Fe

CioH10Fe+

C10H10Fe+

CioH10Fe +

Reactant Other

products

(C5 H5)2Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

(C5 H5) 2Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

(C5 H5)2Fe

(Ferrocene)

(RN-CAS-Registry Number 102-54-5)

(C5 H5)2Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

(C5 H5)2Fe

(Ferrocene)

(RN-CAS-Registry Number 102-54-5)

(C5 H5)2Fe

(Ferrocene)

(RN-CAS Registry Number 102-54-5)

Ionization or appearance Method Ref.

potential

(eV)

6.88 (V) PE 3688

~7.0(V) PE 3527

7.10 (V) PE 4072

6.9±0.1 RPD 3793

6.90±0.1 EDD 4072

6.75±0.25 DC 3628

CI2H12Fe+ C5H5 FeC5H4C2H3 ** 6.75+0.05 PI 3729

(Ferrocene, ethenyl-)

(RN-CAS Registry Number 1271-51-8)

C12H14Fe+ (C5 H4CH3)2Fe ** 6.72 (V) PE 3688

(Ferrocene, 1 , 1 '-dimethyl-)

(RN-CAS Registry Number 1291-47-0)

C12H14Fe+ C5 H5 FeC5H4C2H5 ** 6.70+0.05 PI 3729

(Ferrocene, ethyl-)

(RN-CAS Registry Number 1273-89-8)

C32H16Ng Fe+ C32H16N8Fe ** 7.22+0.10

(Iron, [297f,3177-phthalocyaninato(2-)-A29,A30,Ar

31 ,A32]- (5P-4-1)-)

(RN-CAS Registry Number 132-16-1)

(ON-Other name: Iron phthalocyanine)

El 3829

C15 H21 06Fe+ (CH3 COCHCOCH3)3Fe ** 8.10±0.07 (V)

(Iron, tris(2,4-pentanedionato-0,0')-, (OC-6-11)-)

(RN-CAS Registry Number 14024-18-1)

PE 3682

C33H5706Fe+ ((CH3)3 CCOCHCOC(CH3)3)3Fe ** 7.92±0.07 (V)

(Iron, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-0,0')-)

(RN-CAS Registry Number 14876-47-2)

PE 3682

C15 H1206F9Fe+ (CF3 COCHCOCH3)3 Fe ** 9. 18 ±0.07 (V)

(Iron, tris( 1,1,1 -trifluoro-2,4-pentanedionato-0, 0')- (RN-CAS Registry Number 14526-22-8)

PE 3682

C15 H3 Q6F18 Fe+ (CF3 COCHCOCF3)3 Fe ** 10. 13 ±0.07 (V) PE

(Iron, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-) (RN-CAS Registry Number 17786-67-3)

3682

267
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C13 H18 SiFe + C5 H5 FeC5 H4Si(CH3 )3 ** (Ferrocene, (trimethylsilyl)-)

(RN-CAS Registry Number 12215-68-8)

9.5±0.10 PI 3729

C6H18 N3 PFe+ ((CH3)2 N)3 PFe(CO)4 4CO

(RN-CAS Registry Number 19372-47-5)

10.2±0.05 El 3952

C12 H36N6P2 Fe + (((CH3)2 N)3 P)2 Fe(CO)3 3CO

(RN-CAS Registry Number 19372-46-4

11.7 ±0.05 El 3952

C7 H 18 N3 OPFe+ ((CH3 )2 N)3 PFe(CO)4 3CO

(RN-CAS Registry Number 19372-47-5)

10.2±0.05 El 3952

C8 H18 N3 02 PFe + ((CH3)2 N)3 PFe(CO)4 2CO

(RN-CAS Registry Number 19372-47-5)

9.8±0.05 El 3952

C9H18 N303 PFe + ((CH3)2 N)3 PFe(CO)4 CO

(RN-CAS Registry Number 19372-47-5)

9.4±0.05 El 3952

C10HI8 N3 O4PFe + ((CH3)2N)3 PFe(CO)4 (RN-CAS Registry Number 19372-47-5)

9.0+0.05 El 3952

C13 H36N6OP2 Fe + (((CH3)2 N)3 P)2Fe(CO)3 2CO

(RN-CAS Registry Number 19372-46-4)

10.2±0.05 El 3952

C14 H36N602 P2 Fe + (((CH3)2 N)3 P)2Fe(CO)3 CO

(RN-CAS Registry Number 19372-46-4)

9.7±0.05 El 3952

C15 H36N603 P2 Fe + (((CH3 ) 2N)3 P)2Fe(CO)3 (RN-CAS Registry Number 19372-46-4)

7.7+0.05 El 3952

FeP5 F+ Fe(PF3)5 (RN-CAS Registry Number 13815-34-4)

8.9 PE 4021

CI0H9ClFe + C5 H5 FeC5 H4Cl ** (Ferrocene, chloro-)

(RN-CAS Registry Number 1273-74-1)

6.83±0.05 PI 3729

C10H8 Cl2 Fe+ (C5 H4Cl)2 Fe ** (Ferrocene, l,l'-dichloro-)

(RN-CAS Registry Number 1293-67-0)

7.03 (V) PE 3688

oo

+ (C5 H5)2Co

(Cobaltocene)

(RN-CAS-Registry Number 1277-43-6)

14.10±0.15 EDD 4072

Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

18.9±0.5 El 3653

Co+ Cl3 SiCo(CO)2(PF3 )2 (RN-CAS Registry Number 37769-29-2)

18.9±0.4 El 3653

268
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C3 H3 Co + (C5 H5) 2Co

(Cobaltocene)

(RN-CAS-Registry Number 1277-43-6)

17.50±0.2 EDD 4072

C5 H5 Co+ (C5 H5)2 Co

(Cobaltocene)

(RN-CAS Registry Number 1277-43-6)

14.0±0.3 RPD 3793

C5 H5 Co+ (C5 H5) 2Co

(Cobaltocene)

(RN-CAS-Registry Number 1277-43-6)

13.20+0.2 EDD 4072

CioH10Co+ (C5 H5)2Co

(Cobaltocene)

(RN-CAS Registry Number 1277-43-6)

5.7±0.2 RPD 3793

Ck>HioCo + (C5 H5)2 Co

(Cobaltocene)

(RN-CAS-Registry Number 1277-43-6)

5.95+0.1 EDD 4072

CnH13 BCo+ C5H5 CoC5 H5 BCH3 ** 6.56+0.1 El 3545

(Cobalt, (i7

5 -2,4-cyclopentadien- 1 -yl)[( 1 ,2,3,4,5,6-tj)- 1 -methylboratabenzene]-)

(RN-CAS Registry Number 36534-25-5)

C12 H16B2 Co+ (C5 H5 BCH3)2Co ** 7. 15 ±0.1 El 3545

(Cobalt, bis[( 1 , 2, 3 ,4, 5 , 6-17)- 1 -methylboratabenzene]-)

(RN-CAS Registry Number 36534-27-7)

C16H15 BCo+ C5 H5 CoC5H5 BC6H5 ** 6.63+0.1 El 3545

(Cobalt, (rj

5 -2,4-cyclopentadien- 1 -yl)[( 1 ,2,3,4,5,6-17)- 1-phenylboratabenzene]-)

(RN-CAS Registry Number 36682-12-9)

C22H20B2Co+ (C5 H5 BC6H5)2Co ** 7.25+0.1 El 3545

(Cobalt, bis[( 1 ,2,3,4,5,6-17)- 1 -phenylboratabenzene]-)

(RN-CAS Registry Number 36534-31-3)

C32H16N8 Co+ C32H16N8 Co ** 7.46+0.10 El 3829

(Cobalt, [2977,3 l//-phthalocyaninato(2‘)-A29,A30,A31 ,A32]- (SP-4-1)-)

(RN-CAS Registry Number 3317-67-7)

(ON-Other name: Cobalt phthalocyanine)

COCo+ COCo+

Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

Cl3 SiCo(CO)2(PF3) 2 (RN-CAS Registry Number 37769-29-2)

16.7±0.3

16.9+0.4

El

El

3653

3653

C202 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

15.5+0.4 El 3653

C202 Co+

Cl3 SiCo(CO)2(PF3)2 (RN-CAS Registry Number 37769-29-2)

15.5+0.3 El 3653

C4H04Co+ HCo(CO)4 ** (RN-CAS Registry Number 16842-03-8)

8. 90 ±0.02 (V) PE 3827

269
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CisH2 |06Co + (CH3 COCHCOCH3 ) 3 Co ** (Cobalt, tris(2,4-pentanedionato-0,O')-, (OC-6-

(RN-CAS Registry Number 21679-46-9)

7.52±0.07 (V)

11)-)

PE 3682

Ci2H 16 B2 02 Co (C5 H5 BOCH3 )2 Co ** 7.02±0.

(Cobalt, bis[(l,2,3,4,5,6-rj)-l-methoxyboratabenzene]-)

(RN-CAS Registry Number 36534-20-0)

El 3545

Ci5H306F18Co + (CF3 COCHCOCF3) 3 Co ** 9.73 ±0.07 (V)

(Cobalt, tris(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato-0,0')-, (OC-6-

(RN-CAS Registry Number 16702-37-7)

PE

-11)-)

3682

C4H3 04SiCo + SiH3 Co(CO)4 ** (RN-CAS Registry Number 14652-62-1)

8.85±0.02 (V) PE 3827

F3 PCo + Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

16.9±0.4 El 3653

F3 PCo+ Cl3 SiCo(CO)2(PF3 ) 2 (RN-CAS Registry Number 37769-29-2)

16.7±0.3 El 3653

C1Co + Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

18.7±0.4 El 3653

ClCo + Cl3 SiCo(CO)2 (PF3)2 (RN-CAS Registry Number 37769-29-2)

18.9±0.5 El 3653

SiCl2 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

18.4±0.6 El 3653

SiCl2 Co+ Cl3 SiCo(CO)2 (PF3 )2 (RN-CAS Registry Number 37769-29-2)

18.4±0.3 El 3653

SiCl3 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

1 3.5 ±0.4 El 3653

SiCl3 Co+ Cl3 SiCo(CO)2(PF3 ) 2 (RN-CAS Registry Number 37769-29-2)13.6±0.2 El 3653

COSiCl3 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

1 1 .9 ±0.3 El 3653

COSiCl3 Co + Cl3 SiCo(CO)2 (PF3)2 (RN-CAS Registry Number 37769-29-2)1 1 .9 ±0.3 El 3653

C202 SiCl3 Co + Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)10.8±0.4 El 3653

C202 SiCl3 Co+ Cl3 SiCo(CO)2(PF3)2 (RN-CAS Registry Number 37769-29-2)1 1.0±0.2 El 3653

C3 03 SiCl 3 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)9.6±0.3 El 3653

F3 SiPCl3 Co+ Cl3 SiCo(CO)3 PF3 10.2±0.5 El 3653

(RN-CAS Registry Number 37769-28-1)

270
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

F3 SiPCl3 Co+

Cl3 SiCo(CO)2 (PF3)2 (RN-CAS Registry Number 37769-29-2)

10.2±0.4 El 3653

C3 03 F3 SiPCl2 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)

9.8±0.2 El 3653

COF3 SiPCl3 Co+ Cl3 SiCo(CO)3 PF3 (RN-CAS Registry Number 37769-28-1)10.7 ±0.3 El 3653

COF3 SiPCl3 Co+ Cl3 SiCo(CO)2 (PF3)2 (RN-CAS Registry Number 37769-29-2)

10.9±0.2 El 3653

C3 03 F3 SiPCl3 Co+ Cl3 SiCo(CO)3 PF3 ** (RN-CAS Registry Number 37769-28-1)

9.4±0.2 El 3653

COF6SiP2 Cl3 Co+ Cl3 SiClCo(CO)2(PF3 )2 (RN-CAS Registry Number 37769-29-2)

9.7±0.2 El 3653

C202F6SiP2 Cl3 Co+ Cl3 SiCo(CO)2 (PF3)2 ** (RN-CAS Registry Number 37769-29-2)

9.3+0.2 El 3653

Ni+ (C5H5)2Ni

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

13.9±0.4 RPD 3793

Ni+ (C5 H5) 2 Ni (C5 H5)2 (Nickelocene)

(RN-CAS Registry Number 1271-28-9)

(MT-Metastable transition(s) observed)

13.00±0.25 DC 3628

Ni+ (C5 H5)2Ni (C5 H5)2 (Nickelocene)

(RN-CAS Registry Number 1271-28-9)

(PC-Appearance potential of the corresponding metastable transition)

14.3+0.5 El 3628

Ni + (C5 H5)2 Ni 2C5 H5 (Nickelocene)

(RN-CAS Registry Number 1271-28-9)

17.7±0.5 El 3628

Ni + CjHjNiNO

(Nickel, (7

5 -2,4-cyclopentadien- 1 -yl)nitrosyl-)

(RN-CAS Registry Number 12071-73-7)

14.8 El 4015

C3 H3 Ni + (C5 H5) 2Ni

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

16.7+0.1 El 3628

C5 H5 Ni + (C5 H5 ) 2Ni

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

12.6±0.2 RPD 3793

C5 H5 Ni + (C5 H5)2Ni C5 H5 (Nickelocene)

(RN-CAS Registry Number 1271-28-9)

(MT-Metastable transition(s) observed)

13.00+0.25 DC 3628

271
Table of Ion Energetics Measurements—-Continued

Ionization or

Ion Reactant Other

products

appearance Method

potential

(eV)

Ref.

C5 H5 Ni + (C5 H5 )2 Ni C5 H5 (Nickelocene)

(RN-CAS Registry Number 1271-28-9)

(PC-Appearance potential of the corresponding metastable transition)

13.0±0.5 El 3628

C5 H5 Ni + C5 H5 NiNO

(Nickel, ( 77

5 -2 , 4-cyclopentadien- 1 -yl)nitrosyl-)

(RN-CAS Registry Number 12071-73-7)

10.5 El 4015

C6 H10Ni + (C3 H5)2 Ni

(Nickel, bis(i7

3 -2-propenyl)-)

(RN-CAS Registry Number 12077-85-9)

7.33±0.04 PE 3711

C8 Hg Ni + (C5 H5 ) 2 Ni C2 H2 (Nickelocene)

(RN-CAS Registry Number 1271-28-9)

(MT-Metastable transition(s) observed)

12 . 6 ±0.1 El 3628

C10H10Ni + (C5 H5)2 Ni

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

6.2 PE 3725

C10H10Ni + (C5 H5)2 Ni

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

6.8 ±0.

RPD 3793

C10H10Ni + (C5 H5)2 Ni

(Nickelocene)

(RN-CAS Registry Number 1271-28-9)

6.50±0.25 DC 3628

C32 H I 6N8 Ni + C32 H16N8 Ni ** 7.45±0.10

(Nickel, [2977,3 li/-phthalocyaninato(2>7V29,A^

30,7V31 ,7V32]- (5P-4- 1)-)

(RN-CAS Registry Number 14055-02-8)

(ON-Other name: Nickel phthalocyanine)

El 3829

C5 H5 NONi + C5 H5 NiNO **

(Nickel, (?7

5 -2, 4-cyclopentadien- 1 -yl)nitrosyl-)

(RN-CAS Registry Number 12071-73-7)

8.5 El 4015

C12 H18 N2 02 Ni + C12 H1802 N2 Ni ** 6.80 (V)

(Nickel, [[4,4'-( 1 ,2-ethanediyldinitrilo)bis[2-pentanonato]](2~)-Af,7V’,0,0'

(RN-CAS Registry Number 13878-48-3)

PE

I-)

3822

Cu + Cu ** (RN-CAS Registry Number 7440-50-8)7.72634± 0.00002 S 4011

Cu + Cu ** (RN-CAS Registry Number 7440-50-8)

7.71 ±0.05 RPD 3745

Cu + Cu3 Cl3? (RN-CAS Registry Number 11093-65-5)

14.0±0.5 El 3455

Cu + Cu4Cl4? (RN-CAS Registry Number 1 1093-67-7)

14.0±0.5 El 3455

Cu + Cu3 I

3 (RN-CAS Registry Number XXXXX-XX-X)

15.2±0.5 El 3603

272
Table of Ion Energetics Measurements-—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

Cu2+ Cu2 ** (RN-CAS Registry Number 34015-11-7)

7.8 El 3775

Cu2+ Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

15.2±0.5 El 3603

Cu3+ Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

17.0±0.5 El 3603

CJ2H,6NsCu+ C32H16N8Cu ** 7.37±0.10

(Copper, [29H, 3 li/-phthalocyaninato(2~)-./V29

,./V30,./V

3

1

,

A

32]- (SP-4- 1 )-) (RN-CAS Registry Number 147-14-8)

(ON-Other name: Copper phthalocyanine)

El 3829

C]2H18N202Cu+ C12H1802 N2Cu ** 7.00 (V) PE

(Copper, [[4,4'-(l,2-ethanediyldinitrilo)bis[2-pentanonato]](2“)-Ar,A^,0,0']-)

(RN-CAS Registry Number 14263-53-7)

3822

CuC1+ CuCl ** (RN-CAS Registry Number 7758-89-6)

10.7+0.3 El 3901

Cu2Cl + Cu3 Cl3 CuCl2 (RN-CAS Registry Number 11093-65-5)

12.0±0.5 El 3455

Cu2Cl + Cu3Cl3 CuCl? + Cl?

(RN-CAS Registry Number 1 1093-65-5)

14.8+0.5 El 3455

Cu2Cl + Cu4Cl4? CuCl2? + Cl?

(RN-CAS Registry Number 1 1093-67-7)

14.8+0.5 El 3455

Cu2Cl + Cu4Cl4? Cu2Cl2? +Cl?

(RN-CAS Registry Number 11093-67-7)

14.8+0.5 El 3455

Cu2Cl2+ Cu2Cl2 ** (RN-CAS Registry Number 12258-96-7)9.6+0.03 El 3901

Cu2Cl2+ Cu4Cl4 (RN-CAS Registry Number 1 1093-67-7)14.0+0.5 El 3455

Cu3 Cl2+ Cu3Cl3? (RN-CAS Registry Number 11093-65-5)

12.7+0.5 El 3455

Cu3 Cl2+ Cu4Cl4? CuCl2? (RN-CAS Registry Number 11093-67-7)

12.7±0.5 El 3455

Cu3Cl3+ Cu3Cl3 ** (RN-CAS Registry Number 11093-65-5)

9. 9+0.5 El 3455

Cu4Cl3+ Cu4Cl4 (RN-CAS Registry Number 11093-67-7)

12.4±0.5 El 3455

Cu4Cl4+ Cu4Cl4 ** (RN-CAS Registry Number 1 1093-67-7)

9.9±0.5 El 3455

Cu5 Cl4+ Cu5 Cl5 (RN-CAS Registry Number 1 1093-68-8)

10.6±0.5 El 3455

273
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Cu5 Cl5+ Cu5 Cl5 ** (RN-CAS Registry Number 11093-68-8)

9.7±0.5 El 3455

Zn + Zn ** (RN-CAS Registry Number 7440-66-6)

9.57±0.07 RPD 3745

C32 H16 N8Zn + C32 H16N8 Zn

(Zinc, [2972,3 l//-phthalocyaninato(2>7V^7V30

, TV

31 (RN-CAS Registry Number 14320-04-8)

(ON-Other name: Zinc phthalocyanine)

7.37±0.10

,7V

32]- (SP-4-1)-)

El 3829

ZnCl2fns

) ZnCl2 ** (RN-CAS Registry Number 7646-85-7)

11.7 (V) PE 3963

ZnCl2+ ZnCl2 ** (RN-CAS Registry Number 7646-85-7

1 1 .87 ±0.05 (V) PE 3833

ZnCl2t

2 IIJ ZnCl2 ** (RN-CAS Registry Number 7646-85-7)

12.3 (V) PE 3963

ZnCljfnj ZnCl2 ** (RN-CAS Registry Number 7646-85-7

12.39±0.05 (V) PE 3833

ZnCl2t

22u) ZnCl2 ** (RN-CAS Registry Number 7646-85-7)

13.0 (V) PE 3963

ZnCI2t

2 I„) ZnCl2 ** (RN-CAS Registry Number 7646-85-7

13.07 ±0.05 (V) PE 3833

ZnCI2t

2 Ig

) ZnCl2 ** (RN-CAS Registry Number 7646-85-7)

14.0 (V) PE 3963

ZnCI2t

2 Ig

) ZnCl2 ** (RN-CAS Registry Number 7646-85-7

14. 10±0.05 (V) PE 3833

ZnCl^ ZnCl2 ** (RN-CAS Registry Number 7646-85-719.02 ±0.05 (V) PE 3833

Ga+ Ga ** (RN-CAS Registry Number 7440-55-3)

6.1 El 3472

Ga+ (CH3)3 Ga C2H6 +CH3 (RN-CAS Registry Number 1445-79-0)

(MT-Metastable transition(s) observed)

13.24±0.03 El 3474

Ga+ (CH2 =CH)3 Ga C4H6 ±C2H3 (RN-CAS Registry Number 1188-13-2)

(MT-Metastable transition(s) observed)

11.1 7±0.05 El 3474

CH3Ga+ (CH3)3 Ga 2CH3 (RN-CAS Registry Number 1445-79-0)

(MT-Metastable transition(s) observed)

13.65±0.07 El 3474

C2 H3 Ga+ (CH2 = CH)3 Ga C4H6 (RN-CAS Registry Number 1188-13-2)10.95±0.05 El 3474

C2 H4Ga+ (CH2 =CH)3 Ga C2H3 + C2 H2 (RN-CAS Registry Number 1188-13-2)

(MT-Metastable transition(s) observed)

1 1.85±0.05 El 3474

274
Table of Ion Energetics Measurements-—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

C2H6Ga+ (CH3)3 Ga CH3 (RN-CAS Registry Number 1445-79-0)

(MT-Metastable transition(s) observed)

10.16±0.03 El 3474

C3H9 Ga+ (CH3)3 Ga

(RN-CAS Registry Number 1445-79-0)

9.87±0.02 El 3474

C4H6Ga+ (CH2 =CH)3 Ga C2H3 (RN-CAS Registry Number 1188-13-2)

11.04±0.08 El 3474

C6H9Ga+ (CH2 =CH)3 Ga ** (RN-CAS Registry Number 1188-13-2)

10.81±0.1 El 3474

Ci2H10Ga+ (C6H5)3 Ga C6H5 (Gallium, triphenyl-)

(RN-CAS-Registry Number 1088-02-4)

8.63 PI 4055

CigHi5 Ga+ (C6H5)3 Ga

(Gallium, triphenyl-)

(RN-CAS-Registry Number 1088-02-4)

8.46+0.03 PI 4055

GaF+ GaF ** (RN-CAS Registry Number 13966-78-4)

10.7+0.6 El 3613

GaF+ GaF3 (RN-CAS Registry Number 7783-51-9)

15.1+0.5 El 3613

Cia,F+ Ga2F6 (RN-CAS Registry Number 38586-87-7)

15.6+0.5 El 3613

Ci5 H306Flg Ga+ (CF3 COCHCOCF3)3 Ga ** 10. 19 ±0.07 (V) PE

(Gallium, tris(l,l,l,5,5,5-hexafhioro-2,4-pentanedionato-0,0')-, (OC-6-1 1)-) (RN-CAS Registry Number 19648-92-1)

3682

GaP+ GaP ** (RN-CAS Registry Number 12063-98-8)

<9 El 3472

Ge+ Ge ** (RN-CAS Registry Number 7440-56-4)8.0±0.3 El 3610

Ge2+ Ge2 ** (RN-CAS Registry Number 12596-05-3)7.8 El 3775

GeH4fB2) GeH4 ** (RN-CAS Registry Number 7782-65-2)11.34 PE 3716

GeH4fT2) GeH4 ** (RN-CAS Registry Number 7782-65-2)

12.0 (V) PE 3508

GeH4fA,) GeH4 ** (RN-CAS Registry Number 7782-65-2)

18.21 PE 3716

GeH4fA,) GeH4 ** (RN-CAS Registry Number 7782-65-2)

18.65 (V) PE 3508

275
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C3 H9Ge+ (CH3 )4Ge ch3 10.05±0.14 El 3548

(RN-CAS Registry Number 865-52-1)

C3 H9Ge+ (CH3)3 CGe(CH3)3 (CH3)3 C 9.91 ±0.22 El 3548

(RN-CAS Registry Number 1184-91-4)

C3 H9Ge + (CH3 ) 3 GeGe(CH3)3 (CH3)3Ge 9.96±0.16 El 3548

(RN-CAS Registry Number 993-52-2)

C3 H9 Ge+ (CH3 )3 SiGe(CH3)3 (CH3)3 Si 9.99±0.14 El 3548

(RN-CAS Registry Number 31608-80-7)

C3 H9Ge + (CH3 ) 3 GeCl Cl 11. 75 ±0.04 El 3939

(RN-CAS Registry Number 1529-47-1)

C3 H9 Ge+ C5 H5 (CO)3 CrGe(CH3)3 C5 H5(CO)3Cr? 9.06±0.1 El 3495

(Tricarbonyl(T)

5 -2,4-cyclopentadien- 1 -yl)(trimethylgermyl)chromium)

C3 H9 Ge+

C3 H9Ge+

C3 H9 Ge+

(RN-CAS Registry Number 34962-34-0)

C5 H5(CO)3 MoGe(CH3)3 C5 H5 (CO)3 Mo? 9.63±0.14 El

(Tricarbonyl(i7 5 -2,4-cyclopentadien- 1 -yl)(trimethylgermyl)molybdenum)

(RN-CAS Registry Number 33306-91-1)

(CH3)3 GeSn(CH3)3 (CH3)3 Sn 10.01 ±0.1 8 El

(RN-CAS Registry Number 16393-89-8)

C5 H5 (CO)3 WGe(CH3)3 C5 H5 (CO)3W? 9.84±0.1 El

(Tricarbonyl(i7

5 -2,4-cyclopentadien- 1 -yl)(trimethylgermyl)tungsten)

(RN-CAS Registry Number 33306-93-3)

3495

3548

3495

C4H12 Ge+ (CH3)4Ge

(RN-CAS Registry Number 865-52-1)

9.33±0.04 PE 3880

C4H12 Ge+ (CH3)4Ge

(RN-CAS Registry Number 865-52-1)

9.38±0.1 PE 3677

C4H12 Ge+ (CH3 )4Ge

(RN-CAS Registry Number 865-52-1)

9.29±0.14 El 3548

C7 H18 Ge+ (CH3)3 CGe(CH3)3 (RN-CAS Registry Number 1184-91-4)

8.98±0.12 El 3548

CgHjgGe CH2 = CHGe(C2 H5)3 ** (RN-CAS Registry Number 6207-41-6)

9.2 (V) PE 3850

C8 H20Ge+ (C2H5)4Ge

(RN-CAS Registry Number 597-63-7)

9.3 (V) PE 3850

C9 H14 Ge+ C6H5 Ge(CH3)3 (Germane, trimethylphenyl-)

(RN-CAS Registry Number 1626-00-2)

-8.75 CTS 3922

C9 H20Ge^ CH2 = CHCH2 Ge(C2 H5)3 ** (RN-CAS Registry Number 1793-90-4)

8.8 (V) PE 3850

CioH I4 Ge CgH8Ge(CH3)2

( l//-2-Benzogermole, 2, 3-dihydro-2,2-dimethyl-)

(RN-CAS Registry Number 27490-21-7)

8.39 CTS 3546

C1(>H i 6Ge C6H5CH2 Ge(CH3 )3 (Germane, trimethyl(phenylmethyl)-)

(RN-CAS Registry Number 2848-62-6)

276

8.19 CTS 3922
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

CioHi6Cre +

Cl2HlgGe+

C,3H,5Ge+

Ci4Hi8 Ge+

QH^Ge^

GeH3 N3fA")

Ge3H9N

+

GeO+

Ge2H60

+

(

2Bj)

CH3NOGe+

GeF2+

GeF^Tj)

GeFtfTJ

GeFj*

GeF^(2T2) GeF?

GeF4t

2A,)

GeF^

C6H5 CH2Ge(CH3)3 (Germane, trimethyl(phenylmethyl)-)

(RN-CAS Registry Number 2848-62-6)

C9H9Ge(CH3)3 ** (Germane, 1-indanyltrimethyl-)

(RN-CAS Registry Number 27490-24-0)

C10H7Ge(CH3)3 (Germane, trimethyl- 1 -naphthaleny1-) (RN-CAS Registry Number XXXXX-XX-X)

C10H7CH2Ge(CH3)3 ** (Germane, trimethyl( 1 -naphthalenylmethyl)-)

(RN-CAS Registry Number 51220-35-0)

(CH3)3 GeGe(CH3)3 ** (RN-CAS Registry Number 993-52-2)

GeH3N3 ** (RN-CAS Registry Number 21138-22-7)

(GeH3)3N

(RN-CAS Registry Number 22856-27-5)

GeO ** (RN-CAS Registry Number 20619-16-3)

(GeH3)20

(RN-CAS Registry Number 14939-17-4)

GeH3NCO ** (RN-CAS Registry Number 6928-42-3)

GeF2 ** (RN-CAS Registry Number 13940-63-1)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

GeF4 ** (RN-CAS Registry Number 7783-58-6)

Ionization or appearance Method Ref.

potential

(eV)

8.26 CTS 3546

8.02 CTS 3546

8.00 CTS 3922

7.78 CTS 3922

8.18±0.11 El 3548

10.01 ±0.02 (V) PE 3670

9.2±0.1 (V) PE 3661

11.0±0.3 El 3610

10.40 (V) PE 3656

10.76+0.02 (V) PE 3670

12.9±0.3 El 3570

16.06 ±0.04 (V) PE 3880

16.08 (V) PE 3508

16.50 (V) PE 3508

16.55±0.04 (V) PE 3880

17.04 (V) PE 3508

17.06 ±0.04 (V) PE 3880

1 8.55 ±0.04 (V) PE 3880

277
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

GeF* GeF4 ** (RN-CAS Registry Number 7783-58-6)

18.60 (V) PE 3508

GeF4t

2 A,) GeF4 ** (RN-CAS Registry Number 7783-58-6)

21.3 (V) PE 3508

Ge2 F4+ Ge2 F4 (RN-CAS Registry Number 12332-08-0)13.1 ±0.3 El 3570

GeH3 F

+

(

2 E) GeH3 F ** (RN-CAS Registry Number 13537-30-9)

1 2.3 ±0. 1 (V) PE 3510

GeH3 F

+

(

2 A,) GeH3 F ** (RN-CAS Registry Number 13537-30-9) ~ 15 (V) PE 3510

GeH3 F

+ GeH3 F

** (RN-CAS Registry Number 13537-30-9)

15.0±0.1 (V) PE 3502

GeH3 F

+

(

2 E) GeH3 F

** (RN-CAS Registry Number 13537-30-9)

15.0±0.1 (V) PE 3510

GeH2 F2+ GeH2 F2 ** (RN-CAS Registry Number 14986-65-3)13.0±0.1 (V) PE 3510

GeOF2+ GeOF2 ** (RN-CAS Registry Number XXXXX-XX-X)

12.3±0.3 El 3570

C6H18 SiGe^ (CH3)3 SiGe(CH3 )3 ** (RN-CAS Registry Number 31608-80-7)

8.31 ±0. 10 El 3548

GeH5 P

+ GeH3 PH2 ** (RN-CAS Registry Number 13573-06-3)

9.7±0.1 (V) PE 3661

Ge3 H9P

+ (GeH3)3 P

(RN-CAS Registry Number 15587-38-9)

9.0±0.1 (V) PE 3661

GeH4S

+

(

2A") GeH3 SH ** (RN-CAS Registry Number 21847-06-3)

9.69 (V) PE 3656

Ge2 H6S

+

(

2 B|) (GeH3)2S

(RN-CAS Registry Number 18852-54-5)

9.25 (V) PE 3656

CH3 NSGe+ GeH3 NCS ** (RN-CAS Registry Number 16475-45-9)9.14±0.02 (V) PE 3670

Cl3 Ge+ GeCl4 Cl

(RN-CAS Registry Number 10038-98-9)

12. 12±0.04 El 3939

Cl3 Ge+ CH3 GeCl3 CH3 (RN-CAS Registry Number 993-10-2)

12.22±0.05 El 3939

Cl4Ge+ GeCl4 ** (RN-CAS Registry Number 10038-98-9)1 1 .68 ±0.05 El 3939

GeH3 Cr(2 E) GeH3 Cl ** 1 1.30±0.02 (V) PE 3510

(RN-CAS Registry Number 13637-65-5)

278
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

GeH3 Cl + GeH3 Cl ** 11.34±0.05 (V) PE 3502

(RN-CAS Registry Number 13637-65-5)

GeH3 Cl +

(

2a.) GeH3 Cl ** 13.05 ±0.02 (V) PE 3510

(RN-CAS Registry Number 13637-65-5)

GeH3 Cl +

(

2E) GeH3 Cl ** 13.3+0.1 (V) PE 3510

(RN-CAS Registry Number 13637-65-5)

GeH2Cl2+ GeH2Cl2 ** (RN-CAS Registry Number 15230-48-5)

11.42±0.02 (V) PE 3510

C2H6ClGe+ (CH3)3 GeCl CH3 (RN-CAS Registry Number 1529-47-1)

10.44+0.04 El 3939

C2H6ClGe+ (CH3)2 GeCl2 Cl

(RN-CAS Registry Number 1529-48-2)

11.56±0.04 El 3939

C3 H9ClGe+ (CH3)3 GeCl ** (RN-CAS Registry Number 1529-47-1)

9.62+0.04 El 3939

CH3 Cl2Ge+ CH3 Cl2Ge+

(CH3)2GeCl2 CH3 (RN-CAS Registry Number 1529-48-2)

CH3 GeCl3 Cl

(RN-CAS Registry Number 993-10-2)

11.08+0.05

1 1 .78 ±0.05

El

El

3939

3939

C2H6Cl2Ge+ (CH3)2GeCl2 ** (RN-CAS Registry Number 1529-48-2)

10.18±0.05 El 3939

CH3Cl3 Ge+ CH3GeCl3 ** (RN-CAS Registry Number 993-10-2)

11. 11 ±0.04 El 3939

C8H14CrGe+ C5H5 (CO)3 CrGe(CH3)3 3CO 10.57+0.24

(Tricarbonyl(Tj5 -2,4-cyclopentadien- 1 -yl)(trimethylgermyl)chromium)

(RN-CAS Registry Number 34962-34-0)

El 3495

C9H14OCrGe+ C5H5(CO)3 CrGe(CH3)3 2CO 9.53+0.15

(Tricarbonyl(i75 -2,4-cyclopentadien-l-yl)(trimethylgermyl)chromium)

(RN-CAS Registry Number 34962-34-0)

El 3495

CioHi402CrGe+ C5H5 (CO)3 CrGe(CH3)3 CO 9.13+0.1

(Tricarbonyl(i75 -2,4-cyclopentadien- 1 -yl)(trimethylgermyl)chromium)

(RN-CAS Registry Number 34962-34-0)

El 3495

CnH,403 CrGe+ C5 H5 (CO)3 CrGe(CH3)3 ** 7.79±0.1

(Tricarbonyl(i75 -2,4-cyclopentadien- 1 -yl)(trimethylgermyl)chromium)

(RN-CAS Registry Number 34962-34-0)

El 3495

C5H3 05MnGe+ GeH3 Mn(CO)5 ** (RN-CAS Registry Number 25069-08-3)

8.90±0.02 (V) PE 3827

C4H304GeCo+ GeH3 Co(CO)4 ** (RN-CAS Registry Number 28360-37-4)8. 80 ±0.02 (V) PE 3827

279
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

GeCu^ GeCu ** (RN-CAS Registry Number 12394-89-7)7.5 El 3775

As + As ** (RN-CAS Registry Number 7440-38-2)

>10.0 El 3475

As2+ As2 ** (RN-CAS Registry Number 23878-46-8)10.1 ±0.2 S 3567

AS2 As2? ** (RN-CAS Registry Number 23878-46-8)

9.7±0.7 El 3475

As2

f As2 ** (RN-CAS Registry Number 23878-46-8)

1 1.0±0.5 El 3555

As^ As4? ** (RN-CAS Registry Number 12597-17-0)

8.5+0.7 El 3475

As4+ As4 ** (RN-CAS Registry Number 12597-17-0)

9.9±0.2 El 3555

AsHjfA,) AsH3 ** (RN-CAS Registry Number 7784-42-1)

9.89 PE 3719

AsH3t

2 E) AsH3 ** (RN-CAS Registry Number 7784-42-1)

12.12±0.03 PE 3719

C2 H7 As + (CH3)2 AsH ** (RN-CAS Registry Number 593-57-7)

8.58 PE 3589

C5 H5As + C5 H5 As ** (Arsenin)

(RN-CAS Registry Number 289-31-6)

8.8 (V) PE 3832

C12 H13 As + C6H5 C4H2As(CH3)2 (1/f-Arsole, 2,5-dimethyl-l-phenyl-)

(RN-CAS Registry Number 20527-10-0)

8.0 (V) PE 4090

C19 H13As+ C13 H8 AsC6H5 (Acridarsine, 10-phenyl-)

(RN-CAS Registry Number 28660-45-9)

7.05 (V) PE 3896

AsF3+ AsF3 ** (RN-CAS Registry Number 7784-35-2)

12.84±0.05 El 3578

C6 H7 F6As+ c/5-(CH3)2 AsC(CF3) = C(CF3 )H ** (RN-CAS Registry Number 4648-64-0)

8.61 PE 3589

C6H7 F6As + rran5-(CH3)2AsC(CF3) = C(CF3)H ** (RN-CAS Registry Number 4648-63-9)

8.71 PE 3589

CgH n F6^s + (C2 H5)2AsC(CF3 )=C(CF3)H ** (RN-CAS Registry Number XXXXX-XX-X)

8.44 PE 3589

Si 3 H9As+ (SiH3)3 As ** (RN-CAS Registry Number 15110-34-6)

9.3 ±0.1 (V) PE 3661

280
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

AsP+ AsP ** (RN-CAS Registry Number 12255-33-3)

1 1.2±0.5 El 3555

AsP3+ AsP3 ** (RN-CAS Registry Number 12511-95-4)

10.3±0.3 El 3555

As2 P2+ As2 P2 ** (RN-CAS Registry Number 12512-03-7)

10.3±0.3 El 3555

As3 P

+ As3 P

** (RN-CAS Registry Number 12512-11-7)

10.0±0.3 El 3555

AsS + AsS? ** (RN-CAS Registry Number 12044-79-0)

9.0±0.7 El 3475

As2 S^ As2 S2? ** (RN-CAS Registry Number 1303-32-8)

9.0±0.7 El 3475

As3 S2+ As3 S2? ** (RN-CAS Registry Number 39350-11-3) ~ 1 1 .0 ±0.7 El 3475

As3 S^ A.S4S4 (RN-CAS Registry Number 12279-90-2)

9.0±0.7 El 3475

As4S^ As4S3? ** (RN-CAS Registry Number 12512-13-9)8.7±0.7 El 3475

As4S4+ Ac Q ** /a.^404 (RN-CAS Registry Number 12279-90-2)

9.0±0.7 El 3475

AsC13+ AsC13 ** (RN-CAS Registry Number 7784-34-1)

10.55+0.025 PE 3626

AsC13+ AsCl3 ** (RN-CAS Registry Number 7784-34-1)

10.57±0.03 EDD 3626

Se + Se ** (RN-CAS Registry Number 7782-49-2)

9.9±0.5 El 3600

Se + H2 Se

(RN-CAS Registry Number 7783-07-5)

12.6+0.1 El 3633

Se +4 Se +3 ** (RN-CAS Registry Number 14700-98-2)

42.947±0.003 S 3562

SeH + SeH ** (RN-CAS Registry Number 13940-22-2)

9.79 S 3742

SeH + H2 Se H

(RN-CAS Registry Number 7783-07-5)

13.8+0.2 El 3633

H,Se +

(

2 B,) H2 Se ** (RN-CAS Registry Number 7783-07-5)

9.88 PE 3719

H2 Se +

(

2 B,) H2 Se ** (RN-CAS-Registry Number 7783-07-5)

281

9.93 PE 4073
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

H2 Se +

(

2 A,) H2 Se ** (RN-CAS Registry Number 7783-07-5)

12.40 PE 3719

H2Se+

(

!B2) H2 Se ** (RN-CAS Registry Number 7783-07-5)

14.11 PE 3719

H2 Se +

(

2A|) H2 Se ** (RN-CAS Registry Number 7783-07-5)

21.0 (V) PE 3719

CSe2tX2 n 3/2) CSe2 ** (RN-CAS Registry Number 506-80-9)

9.27±0.01 PE 3965

CSe2tX2 n l/2) CSe2 ** (RN-CAS Registry Number 506-80-9)

9.54+0.01 PE 3965

CSe2tA2 n„) CSe2 ** (RN-CAS Registry Number 506-80-9)

1 1.49±0.01 PE 3965

CSe2tB

! 25 CSe2 ** (RN-CAS Registry Number 506-80-9)

1 3.63 ±0.01 PE 3965

CSe2tC2 2g

") CSe2 ** (RN-CAS Registry Number 506-80-9)

15.90±0.01 PE 3965

C2 H5 Se + CH3 SeCH2 CH2 CH(NH2)COOH

(RN-CAS Registry Number 1464-42-2)

12.03±0.06 El 3443

C2 H6Se + (CH3)2 Se ** (RN-CAS Registry Number 593-79-3)

(RS-Average of three Rydberg series limits)

8.400±0.010 S 3970

C2 H6Se +

(

2 B,) (CH3)2 Se

(RN-CAS Registry Number 593-79-3)

8.40 (V) PE 3656

C3 H7 Se + CH3 SeCH2 CH2CH(NH2)COOH C2 H4N02 (RN-CAS Registry Number 1464-42-2)

(MT-Metastable transition(s) observed)

9.34±0.15 El 3443

C4 H4Se + C4H4 Se ** (Selenophene)

(RN-CAS Registry Number 288-05-1)

8.80 (V) PE 3858

C4 H4 Se + C4 H4Se ** (Selenophene)

(RN-CAS Registry Number 288-05-1)

<8.92 (V) PE 3804

C4 H4 Se + C4H4Se ** (Selenophene)

(RN-CAS Registry Number 288-05-1)

9.01 ±0.05 El 3482

C5 H6Se + C4H3 SeCH3 ** (Selenophene, 2-methyl-)

(RN-CAS Registry Number 7559-42-4)

8.38 ±0.El 3804

C3 H6NSe + CH3 SeCH2 CH2 CH(NH2)COOH

(RN-CAS Registry Number 1464-42-2)

10.33±0.07 El 3443

C4 H10NSe + CH3 SeCH2 CH2 CH(NH2)COOH C02 H

(RN-CAS Registry Number 1464-42-2)

(MT-Metastable transition(s) observed)

9.83 ±0. 1

6

El 3443

282
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

COSe+ (X2 n3/2) COSe ** (RN-CAS Registry Number 1603-84-5)

10.36±0.01 PE 3965

(RD-Radical)

COSe+ (X2 II 1/2) COSe ** (RN-CAS Registry Number 1603-84-5)

10.57±0.01 PE 3965

(RD-Radical)

COSe+ (A2 FI) COSe ** (RN-CAS Registry Number 1603-84-5)

14.58 ±0.01 PE 3965

(RD-Radical)

COSe+ (B22

+

) COSe ** (RN-CAS Registry Number 1603-84-5)

15.75+0.01 PE 3965

(RD-Radical)

COSe+ (C2 2

+

) COSe ** (RN-CAS Registry Number 1603-84-5)

17.90±0.01 PE 3965

(RD-Radical)

C5 H4OSe+ C4H3 SeCHO ** (2-Selenophenecarboxaldehyde)

(RN-CAS Registry Number 25109-26-6)

9.47±0.05 El 3482

C6H6OSe+ C4H3 SeCOCH3 ** (Ethanone, l-selenophene-2-yl-)

(RN-CAS Registry Number 15429-03-5)

9.30+0.05 El 3482

C5 H402 Se + C4H3 SeCOOH ** (2-Selenophenecarboxylic acid)

(RN-CAS Registry Number 22968-45-2)

9.25±0.1 El 3804

C4H6NOSe+ CH3 SeCH2CH2CH(NH2)COOH H20+ CH3 (RN-CAS Registry Number 1464-42-2)

(MT-Metastable transition(s) observed)

10.00+0.05 El 3443

C5 H9NOSe+ CH3 SeCH2CH2CH(NH2)COOH H20

(RN-CAS Registry Number 1464-42-2)

(MT-Metastable transition(s) observed)

8.73+0.10 El 3443

C4H8N02 Se+ CH3 SeCH2 CH2 CH(NH2)COOH CH3 (RN-CAS Registry Number 1464-42-2)

(MT-Metastable transition(s) observed)

9.35+0.10 El 3443

C5 HnN02 Se + CH3 SeCH2CH2CH(NH2)COOH ** (RN-CAS Registry Number 1464-42-2)

8.26±0.03 El 3443

C6H3 OF3 Se + C4H3 SeCOCF3 ** (Ethanone, 2,2,2-trifluoro- 1 -(selenophene-2-yl)-)

(RN-CAS Registry Number 26149-08-6)

9.64±0.05 El 3482

Si2H6 Se +

(

2 Bj) (SiH3)2 Se ** (RN-CAS Registry Number 14939-45-8)

9.18 (V) PE 3656

283
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance

products potential

(eV)

Method Ref.

SeP + SeP ** (RN-CAS Registry Number 12509-41-0)

8.2 El 4001

CSSe + (X2 n 3/2) SCSe ** (RN-CAS Registry Number 5951-19-9)

9.58±0.01 PE 3965

(RD-Radical)

CSSe + (X2 Il 1/2) SCSe ** (RN-CAS Registry Number 5951-19-9)

9.77±0.01 PE 3965

(RD-Radical)

CSSe + (A2 n) SCSe ** (RN-CAS Registry Number 5951-19-9)

12.13±0.01 PE 3965

(RD-Radical)

CSSe + (B2 2

+

) SCSe ** (RN-CAS Registry Number 5951-19-9)

14.07±0.01 PE 3965

(RD-Radical)

CSSe + (C2 2

+

) SCSe ** (RN-CAS Registry Number 5951-19-9)

16.06±0.01 PE 3965

(RD-Radical)

ScSe + ScSe ** (RN-CAS Registry Number 12138-19-1)

7.5 El 3600

(RD-Radical)

Ge2H6Se+

(

2 B,) (GeH3)2Se ** (RN-CAS Registry Number 24254-18-0)

8.84 (V) PE 3656

Br+ CH2 Br2 CH2 Br 16.0 (RN-CAS Registry Number 74-95-3)

(AD-0.192 eV average translational energy of decomposition at threshold)

(TR-Other product(s) thermochemically reasonable)

RPD 3490

Br+ CH2 Br2 CH2 Br

(RN-CAS Registry Number 74-95-3)

(AD-0.19 eV average translational energy of decomposition at threshold)

(TR-Other product(s) thermochemically reasonable)

15.5±0.1 El 3442

Br+4

(

2Pl/2°) Br+ 3 ** (RN-CAS Registry Number 22788-29-0)

45.0556 S 3593

Br + 5 Br +4 ** (RN-CAS Registry Number 22541-82-8)

62.35 S 3592

HBr+ (X2 n3/2) HBr ** (RN-CAS Registry Number 10035-10-6)

1 1.645±0.005 PE 3839

HBr+ (X2 n,/2) HBr ** (RN-CAS Registry Number 10035-10-6)

1 1.979±0.005 PE 3839

HBr+ (A2 5) +

) HBr ** (RN-CAS Registry Number 10035-10-6)

15.288±0.005 PE 3839

DBr+ (X2 n3/2) DBr ** (RN-CAS Registry Number 13536-59-9)

1 1.673±0.005 PE 3839

DBr+ (X2n ]/2) DBr ** (RN-CAS Registry Number 13536-59-9)

284

12.002 ±0.005 PE 3839
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

DBr+ (A2 2

+

) DBr ** 15.284±0.005 PE 3839

(RN-CAS Registry Number 13536-59-9)

C2HBr+ CH=CBr ** 10.762±0.004 S 3876

(RN-CAS Registry Number 593-61-3)

(RS-Average of two Rydberg series limits)

C2 H3 Br+

(

!A") CH2 = CHBr ** 9.80+0.02 PE 3659

(RN-CAS Registry Number 593-60-2)

C2 H3 Br+ CH2 =CHBr ** 9.83 PE 3863

C2H3 Br+

(

2A')

(RN-CAS Registry Number 593-60-2)

CH2 = CHBr ** 10.90±0.02 PE 3659

C2H3 Br+(2A”)

(RN-CAS Registry Number 593-60-2)

CH2 = CHBr ** 12.28 ±0.02 (V) PE 3659

C2 H3 Br+(2A')

(RN-CAS Registry Number 593-60-2)

CH2 = CHBr ** 12.94+0.02 (V) PE 3659

(RN-CAS Registry Number 593-60-2)

C2 H3 Br +

(

2A') CH2 = CHBr ** 15. 02 ±0.02 (V) PE 3659

C2H3 Br+

(

2 A')

(RN-CAS Registry Number 593-60-2)

CH2 =CHBr ** 16.21 ±0.02 (V) PE 3659

(RN-CAS Registry Number 593-60-2)

C2H3 Br+ * CH2 = CHBr ** 19.20±0.02 (V) PE 3659

(RN-CAS Registry Number 593-60-2)

C2H5 Br+

(

2E3/2) C2H5 Br ** 10.28 (V) PE 4076

C2 H5 Br+

(

2E1/2) (RN-CAS Registry Number 74-96-4)

C2H5 Br ** 10.60 (V) PE 4076

(RN-CAS Registry Number 74-96-4)

C3 H5 Br+ CH2 =CHCH2Br ** 10.06 PE 3863

(RN-CAS Registry Number 106-95-6)

C3 H5 Br+ CH2 = CHCH2 Br ** 10.18 (V) PE 4091

C3 H5 Br+(2A")

(RN-CAS Registry Number 106-95-6)

CH2 =CBrCH3 ** 9.58±0.02 (V) PE 3659

C3 H5 Br+

(

2A')

(RN-CAS Registry Number 557-93-7)

CH2 = CBrCH3 ** 10.51 ±0.02 PE 3659

C3 H5 Br+

(

2A")

(RN-CAS Registry Number 557-93-7)

CH2 = CBrCH3 ** 11. 62 ±0.02 (V) PE 3659

C3 H,Br+

(

2 A')

(RN-CAS Registry Number 557-93-7)

CH2 =CBrCH3 ** 12.40±0.02 (V) PE 3659

(RN-CAS Registry Number 557-93-7)

C3 H5 Br+ * CH2 =CBrCH3 ** 1 3.53 ±0.01 (V) PE 3659

(RN-CAS Registry Number 557-93-7)

C3 H5 Br + * CH2 =CBrCH3 ** 15. 15 ±0.02 (V) PE 3659

(RN-CAS Registry Number 557-93-7)

C3 H5 Br + * CH2 =CBrCH3 ** 15.84 ±0.02 (V) PE 3659

(RN-CAS Registry Number 557-93-7)

C3 H,Br+

(

2E3/2) fl-C3 H7 Br ** 10.18 PE 4076

C3 H,Br+

(

2 El/2) (RN-CAS Registry Number 106-94-5)

«-C3 H7 Br ** 10.50 PE 4076

(RN-CAS Registry Number 106-94-5)

285
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C3 H7 Br + /JO-C3 H7 Br ** (RN-CAS Registry Number 75-26-3)10.4± <0.1 El 3735

C4H7 Br + CH2 = CHCH2CH2 Br ** (RN-CAS Registry Number 5162-44-7)

9.9 El 3900

C4 H,Br +

(

2 EJ/2) n-C4H9 Br ** (RN-CAS Registry Number 109-65-9)

10.15 PE 4076

C4H,Br+

(

2E|/2) n-C4H9 Br ** (RN-CAS Registry Number 109-65-9)

10.44 PE 4076

C5 H9 Br + CH2 =CH(CH2)3 Br ** (RN-CAS Registry Number 1119-51-3)

9.6 El 3900

C5 H9 Br + C5 H9 Br ** (Cyclopentane, bromo-)

(RN-CAS Registry Number 137-43-9)

9.94+0.02 PE 4003

C5 H„Br+

(

2 Ev2) n-CjHuBr ** (RN-CAS Registry Number 1 10-53-2)

10.09 PE 3532

C5 H„Br+

(

2El/2) fl-C5 Hu Br ** (RN-CAS Registry Number 110-53-2)

10.40 PE 3532

C6 H4Br + C6H4(Br)COOH CO+OH

(Benzoic acid, 3-bromo-)

(RN-CAS Registry Number 585-76-2)

(MT-Metastable transition(s) observed)

14.91+0.2 El 3973

C6 H4 Br + C6H4(Br)COOH CO+OH

(Benzoic acid, 4-bromo-)

(RN-CAS Registry Number 586-76-5)

(MT-Metastable transition(s) observed)

15.13+0.2 El 3973

C6H4Br + C6H4 BrN02 N02 (Benzene, l-bromo-3-nitro-)

(RN-CAS Registry Number 585-79-5)

12.01+0.1 El 3447

C6H4 Br + C6H4 BrN02 N02 (Benzene, l-bromo-4-nitro-)

(RN-CAS Registry Number 586-78-7)

12.19+0.1 El 3447

C6 H5 Br +

C6H5 Br +

C6H5 Br +

C6H5 Br ** (Benzene, bromo-)

(RN-CAS Registry Number 108-86-1)

C6H4BrOCH3 CH20

(Benzene, l-bromo-3-methoxy-)

(RN-CAS Registry Number 2398-37-0)

C6H4 BrOCH3 CH20

(Benzene, l-bromo-4-methoxy-)

(RN-CAS Registry Number 104-92-7)

9.00 (V) PE 3873

1 1.59±0.1 El 3446

1 1.52±0.1 El 3446

C6 H, ,Br + C6Hn Br ** 9.85±0.01 PI 4078

(Cyclohexane, bromo-)

(RN-CAS Registry Number 108-85-0)

286
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C6Hn Br+ C6Hn Br

(Cyclohexane, bromo-)

(RN-CAS Registry Number 108-85-0)

9.90±0.02 PE 4003

C6Hn Br+ C6HnBr

(Cyclohexane, bromo-)

(RN-CAS Registry Number 108-85-0)

10.00 (V) PE 4078

C7H7 Br+ C6H5 CH2Br ** (Benzene, (bromomethyl)-)

(RN-CAS Registry Number 100-39-0)

9.23 (V) PE 3992

C7H7 Br+ C6H4BrCH3 ** (Benzene, l-bromo-2-methyl-)

(RN-CAS Registry Number 95-46-5)

8.58±0.1 El 3777

C7H7Br+ C6H4BrCH3 (Benzene, l-bromo-3-methyl-)

(RN-CAS Registry Number 591-17-3)

8.77 PE 4089

C^Br* C6H4BrCH3 ** (Benzene, l-bromo-3-methyl-)

(RN-CAS Registry Number 591-17-3)

8.60±0.1 El 3777

C7H7Br+ C6H4BrCH3 ** (Benzene, 1 -bromo-4-methyl-)

(RN-CAS Registry Number 106-38-7)

8.67 PE 4089

C7H7Br+ C6H4BrCH3 (Benzene, 1 -bromo-4-methyl-)

(RN-CAS Registry Number 106-38-7)

8.70±0.1 El 3777

C7H9Br+ C;H9Br **

(bicyclo[2.2.1]hept-2-ene, 5-bromo-, exo-)

(RN-CAS Registry Number 5810-82-2)

9.2 El 3900

C7H9Br+ C^Br ** (Bicyclo[2.2.1]hept-2-ene, 5-bromo-, endo-)

(RN-CAS Registry Number 5810-82-2)

9.2 El 3900

C10H15 Br+ C10H15Br

(tricyclo[3.3. 1. l

3,7]decane, 1-bromo-)

(RN-CAS Registry Number 768-90-1)

(ON-Other name: 1-Bromoadamantane)

CioH15Br+ C10H15 Br **

(Tricyclo[3.3. 1. l

3’ 7]decane, 1-bromo-)

(RN-CAS Registry Number 768-90-1)

(ON-Other name: 1-Bromoadamantane)

C10H15 Br+ C10Hls Br

(Tricyclo[3 . 3.1.1

3,7]decane, 2-bromo-)

(RN-CAS Registry Number 7314-85-4)

(ON-Other name: 2-Bromoadamantane)

9.2 PE 3907

9.30±0.06 PE 3886

9.31 ±0.05 PE 3886

C12H9Br+ C6H5 C6H4Br ** 8.05 ±0.02 PE 3702

(l,l'-Biphenyl, 4-bromo-)

(RN-CAS Registry Number 92-66-0)

C2H2Br2t

2B,) m-CHBr= CHBr ** 9.32±0.02 PE 3659

(RN-CAS Registry Number 590-11-4)

287
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C2 H2 Br2fB2) c/s-CHBr = CHBr ** (RN-CAS Registry Number 590-11-4)

10.74±0.02 (V) PE 3659

C2 H2 Br2t

2 A2) m-CHBr = CHBr ** (RN-CAS Registry Number 590-11-4)

1 1.24±0.02 (V) PE 3659

C2 H2 Br2t

2 A,) m-CHBr = CHBr ** (RN-CAS Registry Number 590-11-4)

1 1.56±0.02 (V) PE 3659

C2H2 Br2t

2 B2 ) c/s-CHBr = CHBr ** (RN-CAS Registry Number 590-11-4)

12.85 ±0.02 (V) PE 3659

C2H2 Br2t

2 B,) c/5-CHBr = CHBr ** (RN-CAS Registry Number 590-11-4)

13.27±0.02 (V) PE 3659

C2 H2 Br2t

2 B2) c«-CHBr=CHBr ** (RN-CAS Registry Number 590-11-4)

14.80±0.02 (V) PE 3659

C2 H2 Br2fA,) cis-CHBr = CHBr ** (RN-CAS Registry Number 590-11-4)

16.49 ±0.02 (V) PE 3659

C2 H2 Br2fAll) trans-CHBr = CHBr ** (RN-CAS Registry Number 590-12-5)

9.30±0.02 PE 3659

C2 H2 Br2+ toz«s-CHBr = CHBr ** (RN-CAS Registry Number 590-12-5)

9.56 (V) PE 3648

C2 H2 Br2t

2 Ag

, 2 Bg

) trans-CHBr = CHBr ** (RN-CAS Registry Number 590-12-5)

11. 05 ±0.02 PE 3659

C2 H2 Br2t

2 Bu) trans-CHBr — CHBr ** (RN-CAS Registry Number 590-12-5)

1 1.60±0.02 (V) PE 3659

C2H2 Br2fAg

, 2A„) trans-CHBr = CHBr ** (RN-CAS Registry Number 590-12-5)

13.00±0.02 (V) PE 3659

C2H2 Br2t

2 Ag

, 2 B„) trans-CHBr = CHBr ** (RN-CAS Registry Number 590-12-5)

15.90±0.02 (V) PE 3659

C2 H2 Br2

t* trans-CHBr = CHBr ** (RN-CAS Registry Number 590-12-5)

19.14±0.02 (V) PE 3659

C5 H8 Br2+ C5 Hg Br2 (Cyclopentane, 1,2-dibromo-, cis-)

(RN-CAS Registry Number 33547-17-0)

10.02±0.02 PE 4003

C5 H8 Br2+ C5 H8 Br2 (Cyclopentane, 1,2-dibromo-, trans-)

(RN-CAS Registry Number 10230-26-9)

10.08±0.02 PE 4003

C6 H4 Br2+ C6H4 Br2 (Benzene, 1,2-dibromo-)

(RN-CAS Registry Number 583-53-9)

9.02 (V) PE 3873

C6H4 Br2+ C6H4Br2 (Benzene, 1,3-dibromo-)

(RN-CAS Registry Number 108-36-1)

9.10 (V) PE 3873

C6 H4 Br2+ C6H4 Br2 (Benzene, 1,4-dibromo-)

(RN-CAS Registry Number 106-37-6)

8.91 (V) PE 3873

C6H10 Br2+ C6Hl0 Br2 (Cyclohexane, 1,2-dibromo- cis-)

(RN-CAS Registry Number 19246-38-9)

9.94±0.02 PE 4003

288
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C6H10Br2+ C6H10Br2 (Cyclohexane, 1,2-dibromo-, trans-)

(RN-CAS Registry Number 7429-37-0)

10.02±0.02 PE 4003

C12 H8 Br+ (C6H4Br)2 (1,1 '-Biphenyl, 2,2'-dibromo-)

(RN-CAS Registry Number 13029-09-9)

8.40±0.02 PE 3702

C6H3 Br3+ C6H3 Br3 (Benzene, 1,3,5-tribromo-)

(RN-CAS Registry Number 626-39-1)

8.91 (V) PE 3873

C6H6NBr+ C6H4BrNHCOCH3 CH2 = C=0 11.17±0.03 El 3483

(Acetamide, A7-(2-bromophenyl)-)

(RN-CAS Registry Number 614-76-6)

C6H6NBr+ C6H4BrNHCOCH3 CH2 = C=0 10.56±0.03 El 3483

(Acetamide, iV-(4-bromophenyl)-)

(RN-CAS Registry Number 103-88-8)

C18H17N2Br+ C6H4(Br)C3 H3(CN)C6H4N(CH3)2 ** 7.10±0.05 EDD 3575

(Cyclopropanecarbonitrile, l-(D-bromophenyl)-2-(o-(dimethylamino)phenyl)-)

(RN-CAS Registry Number 32589-49-4)

C6H5 NBr2+ C6H3 Br2NHCOCH3 CH2 =C=0 10.24±0.03 El 3480

(Acetamide, 7V-(2,4-dibromophenyl)-)

(RN-CAS Registry Number 23373-04-8)

C6H5 NBr2+ C6H3 Br2NHCOCH3 CH2 =C=0 10.02±0.03 El 3480

(Acetamide, N-(2,6-dibromophenyl)-)

(RN-CAS Registry Number 33098-80-5)

C4H12BN2Br+ C4H12BN2Br+((CH3)2N)2 BBr ** (RN-CAS Registry Number 6990-27-8)

B(N(CH3)2)2Br ** (RN-CAS Registry Number 6990-27-8)

8.13

8.16 (V)

PE

PE

3584

3704

C2H6BNBr2+ (CH3)2NBBr ** (RN-CAS Registry Number 7360-64-7)

9.55 (V) PE 3704

C2H6BNBr^ (CH3)2NBBr ** (RN-CAS Registry Number 7360-64-7)

9.60 PE 3584

COBr^

COBr^B^

COBr2+

COBr^

COBr2t

2 B,)

CBrzO ** (RN-CAS Registry Number 593-95-3)

CBr20 ** (RN-CAS Registry Number 593-95-3)

CBr20 ** (RN-CAS Registry Number 593-95-3)

CBr20 ** (RN-CAS Registry Number 593-95-3)

CBr20 ** (RN-CAS

CBr20

(RN-CAS

Registry Number 593-95-3)

**

11.0 (V) PE 3726

11.5 (V) PE 3726

1 1.6 (V) PE 3726

12.0 (V) PE 3726

12.4 (V) PE 3726

14.8 PE 3726

Registry Number 593-95-3)

289
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

COBr^ CBrzO ** (RN-CAS Registry Number 593-95-3)

16.2 (V) PE 3726

C5 H9OBr+ C5 H8 (Br)OH ** (Cyclopentanol, 2-bromo-, cis-)

(RN-CAS Registry Number 28435-62-3)

10.19±0.02 PE 4003

C5 H9OBr+ C5 H8 (Br)OH ** (Cyclopentanol, 2-bromo-, trans-)

(RN-CAS Registry Number 20377-79-1)

10. 11 ±0.02 PE 4003

C6H4OBr+

C6H4OBr+

C6H4OBr+

C6H4OBr+

C6H4BrOCH3 CH3 (Benzene, 1 -bromo-3-methoxy-)

(RN-CAS Registry Number 2398-37-0)

C6H4 BrOCH3 CH3 (Benzene, l-bromo-4-methoxy-)

(RN-CAS Registry Number 104-92-7)

C6H4BrN02 NO

(Benzene, l-bromo-3-nitro-)

(RN-CAS Registry Number 585-79-5)

C6H4BrN02 NO

(Benzene, l-bromo-4-nitro-)

(RN-CAS Registry Number 586-78-7)

12.29 ±0.1 El 3446

1 1.89±0.1 El 3446

10.26±0.1 El 3447

10.55±0.1 El 3447

C6H5 OBr+

C6H5OBr+

C6H5OBr+

C6H5 OBr+

C6H5OBr+

C6H4(OH)Br ** (Phenol, 2-bromo-)

(RN-CAS Registry Number 95-56-7)

C6H4BrOOCCH3 CH2 =C=0

(Phenol, 2-bromo-, acetate)

(RN-CAS Registry Number 1829-37-4)

C6H4BrOOCCH3 CH2 =C=0

(Phenol, 3-bromo-, acetate)

(RN-CAS Registry Number 35065-86-2)

C6H4BrOOCCH3 CH2 =C=0

(Phenol, 4-bromo-, acetate)

(RN-CAS Registry Number 1927-95-3)

C6H4BrOOCCH3 CH2 =C=0

(Phenol, 4-bromo-, acetate)

(RN-CAS Registry Number 1927-95-3)

9.09 ±0.1 El

9.62±0.03 El

10.02±0.2 El

9.84±0.03 El

10.08 ±0.2 El

3553

3483

3484

3483

3484

C7H4OBr+ C6H4(Br)COOH OH 12.23 ±0.2 El 3973

(Benzoic acid, 3-bromo-)

(RN-CAS Registry Number 585-76-2)

C7H4OBr+ C6H4(Br)COOH OH 12.34±0.2 El 3973

(Benzoic acid, 4-bromo-)

(RN-CAS Registry Number 586-76-5)

C7H7OBr+ C6H4BrOCH3 ** 8.69±0.1 El 3446

(Benzene, l-bromo-3-methoxy-)

(RN-CAS Registry Number 2398-37-0)

290
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C7H7OBr+ C6H4BrOCH3 ** (Benzene, l-bromo^4—methoxy-)

(RN-CAS Registry Number 104-92-7)

8.39±0.1 El 3446

C2H302Br+ CH2BrCOOH ** (RN-CAS Registry Number 79-08-3)

11.0 (V) PE 3874

C7H502Br+ C6H4(Br)COOH ** (Benzoic acid, 3-bromo-)

(RN-CAS Registry Number 585-76-2)

9.66+0.2 El 3973

C7H502Br+ C6H4(Br)COOH ** (Benzoic acid, 4-bromo-)

(RN-CAS Registry Number 586-76-5)

9.72+0.2 El 3973

C7H11 02Br+ C5H8(Br)OCOCH3 ** (Cyclopentanol, 2-bromo-, acetate, cis-)

(RN-CAS Registry Number 53093-41-7)

10.00+0.02 PE 4003

C7H11 02 Br+ C5H8(Br)OCOCH3 ** (Cyclopentanol, 2-bromo-, acetate, trans-)

(RN-CAS Registry Number 53093-42-8)

10.07+0.02 PE 4003

C8H702Br+ C6H4BrOOCCH3 ** 8.66+0.03 El 3483

(Phenol, 2-bromo-, acetate)

(RN-CAS Registry Number 1829-37-4)

CgH702Br+ C6H4BrOOCCH3 ** 8.79+0.2 El 3484

(Phenol, 3-bromo-, acetate)

(RN-CAS Registry Number 35065-86-2)

C8H702Br+ C6H4BrOOCCH3 ** 8.42+0.03 El 3483

(Phenol, 4-bromo-, acetate)

(RN-CAS Registry Number 1927-95-3)

C8 H702Br+ C6H4BrOOCCH3 ** 8.61+0.2 El 3484

(Phenol, 4-bromo-, acetate)

(RN-CAS Registry Number 1927-95-3)

C6H4OBr2+ C6H3 Br2OOCCH3 ch2 =c=o 9.45+0.03 El 3480

C6H4OBr2+

(Phenol, 2,4-dibromo-, acetate)

(RN-CAS Registry Number 36914-79-1)

C6H3 Br2OOCCH3 CH2 =C= 0

(Phenol, 2,6-dibromo-, acetate)

(RN-CAS Registry Number 28165-72-2)

9.74+0.03 El 3480

C8H602 Br2+ C6H3 Br2OOCCH3 ** (Phenol, 2,4-dibromo-, acetate)

(RN-CAS Registry Number 36914-79-1)

8.21+0.03 El 3480

QH^OaBr^ C6H3 Br2OOCCH3 ** (Phenol, 2,6-dibromo-, acetate)

(RN-CAS Registry Number 28165-72-2)

8.42+0.03 El 3480

C8H7NOBr+ C6H3 Br2NHCOCH3 8.84+0.03 El 3480

(Acetamide, A-(2,4—dibromophenyl)-)

(RN-CAS Registry Number 23373-04-8)

291
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Cg H7 NOBr+ C6H3 Br2 NHCOCH3 (Acetamide, 7V-(2,6-dibromophenyl)-)

(RN-CAS Registry Number 33098-80-5)

8.88±0.03 El 3480

C8 H8 NOBr+ C6H4BrNHCOCH3 ** (Acetamide, 7V-(2-bromophenyl)-)

(RN-CAS Registry Number 614-76-6)

8. 17 ±0.03 El 3483

C8 H8 NOBr+ C6H4BrNHCOCH3 ** (Acetamide, 7V-(4-bromophenyl)-)

(RN-CAS Registry Number 103-88-8)

8.17±0.03 El 3483

C6H4N02 Br + C6H4BrN02 ** (Benzene, l-bromo-3-nitro-)

(RN-CAS Registry Number 585-79-5)

9.82±0.1 El 3447

C6H4N02 Br + C6H4BrN02 ** (Benzene, l-bromo-4-nitro-)

(RN-CAS Registry Number 586-78-7)

9.76±0.

El 3447

C8 H7 NOBr2+ C6H3 Br2 NHCOCH3 ** (Acetamide, 7V-(2,4-dibromophenyl)-)

(RN-CAS Registry Number 23373-04-8)

8.08±0.03 El 3480

C8 H7 NOBr2+ C6H3 Br2 NHCOCH3 ** (Acetamide, 7V-(2,6-dibromophenyl)-)

(RN-CAS Registry Number 33098-80-5)

8.32±0.03 El 3480

BrF+ (X2 n 3/2) BrF ** (RN-CAS Registry Number 13863-59-7)

1 1.78±0.01 PE 3680

BrF + (X2 n l/2) BrF ** (RN-CAS Registry Number 13863-59-7)12.09±0.01 PE 3680

BrF3fB2, 2 A,) BrF3 ** (RN-CAS Registry Number 7787-71-5)

12. 15 ±0.04 PE 3680

BrF3t

2A,) BrF3 ** (RN-CAS Registry Number 7787-71-5)

1 3.58 ±0.01 PE 3680

BrF3t

2 B,) BrF3 ** (RN-CAS Registry Number 7787-71-5)

14.60±0.04 (V) PE 3680

BrF3t

2 A2 ) BrF3 ** (RN-CAS Registry Number 7787-71-5)

15.05 ±0.03 (V) PE 3680

BrF3t

2 B2) BrF3 ** (RN-CAS Registry Number 7787-71-5)

15.61 ±0.03 (V) PE 3680

BrF3t

2 B,) BrF3 ** (RN-CAS Registry Number 7787-71-5)

16.26±0.03 PE 3680

BrF3X

2A„2B2) BrF3 ** (RN-CAS Registry Number 7787-71-5)

17.59±0.02 (V) PE 3680

BrF3t

2 B,) BrF3 ** (RN-CAS Registry Number 7787-71-5)

18.76±0.04 (V) PE 3680

BrF5+ BrF5 ** (RN-CAS Registry Number 7789-30-2)

13.172±0.005 PE 3655

CF3 Br + CF3 Br ** (RN-CAS Registry Number 75-63-8)

292

12.0 (V) PE 3914
Table of Ion Energetics Measurements—Continued

Ion Reactant

Ionization or Other appearance Method Ref. products potential

(eV)

CF3 Br+

(

2E) CF3 Br ** (RN-CAS Registry Number 75-63-8)

CF3 Br+

(

2Aj) CF3 Br ** (RN-CAS Registry Number 75-63-8)

CF3 Br+

(

2A2) CF3 Br ** (RN-CAS Registry Number 75-63-8)

CF3 Br +

(

2E) CF3 Br ** (RN-CAS Registry Number 75-63-8)

CF3 Br+

(

2E) CF3 Br ** (RN-CAS Registry Number 75-63-8)

CF3 Br +

(

2A!) CF3 Br ** (RN-CAS Registry Number 75-63-8)

12.12±0.02 (V) PE 4026

14.26±0.02 (V) PE 4026

15.78 ±0.02 (V) PE 4026

16.51 ±0.02 (V) PE 4026

17.42±0.02 (V) PE 4026

19.8 (V) PE 4026

C2F3 Br+ QF.Br

(RN-CAS Registry Number 598-73-2)

9.67 PE 3589

C5HgFBr+ C5 H8FBr ** 10.10±0.02 PE 4003

(Cyclopentane, l-bromo-2-fluoro-, as-)

(RN-CAS Registry Number 51422-72-1)

C5 H8 FBr+ C5 H8FBr ** 10.25 ±0.02 PE 4003

(Cyclopentane, l-bromo-2-fluoro-, trans-)

(RN-CAS Registry Number 51422-73-2)

C6H10FBr+ C6H10FBr ** 10.04±0.02 PE 4003

(Cyclohexane, l-bromo-2-fluoro-, cis-)

(RN-CAS Registry Number 51422-74-3)

C6H10FBr+ C6H10FBr ** 10. 18 ±0.02 PE 4003

(Cyclohexane, l-bromo-2-fluoro-, trans-)

(Rn 17170-96-6)

C12H8FBr+ C6H4(Br)C6H4F ** 8.10±0.02 PE 3702

(1,1 '-Biphenyl, 4-bromo-4'-fluoro-)

(RN-CAS Registry Number 398-21-0)

SiBr+SiBr ** 7.3 D 3558

(RN-CAS Registry Number 14791-57-2)

SiH3 Br+

(

2E) SiH3 Br ** 10.90 (V) PE 3511

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+

(

2 E3/2) SiH3 Br ** 10.96±0.02 (V) PE 3510

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+ SiH3 Br ** 11. 03 ±0.05 (V) PE 3502

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+

(

2E1/2) SiH3 Br ** 1 1.10±0.02 (V) PE 3510

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+

(

2A,) SiH3 Br ** 12.85±0.02 (V) PE 3510

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+

(

2A,) SiH3 Br ** 12.96 (V) PE 3511

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+

(

2E) SiH3 Br ** 1 3.3 ±0. 1 (V) PE 3510

(RN-CAS Registry Number 13465-73-1)

293
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SiH3 Br +

(

2 E) SiH3 Br * 13.43 (V) PE 3511

(RN-CAS Registry Number 13465-73-1)

SiH3 Br+

(

2 A,) SiH3 Br ** 18.04 (V) PE 3511

(RN-CAS Registry Number 13465-73-1)

SiH 3 Br +

(

2 A,) SiH3 Br ** 18.1 ±0.1 (V) PE 3510

(RN-CAS Registry Number 13465-73-1)

SiH 3 Br +

(

2 A,) SiH3 Br ** 19.5 ±0. 1 (V) PE 3510

(RN-CAS Registry Number 13465-73-1)

SiH2 Br2+ SiH2 Br2 ** 10.92±0.02 (V) PE 3510

(RN-CAS Registry Number 13768-94-0)

C5 H9 SiBr + (CH3 ) 3 SiC==CBr ** 9.4±0.1 PE 4002

(RN-CAS Registry Number 18243-59-9)

SiF3 Br +

(

2 E) SiF3 Br ** 12.46±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br +

(

2A,) SiF3 Br ** 14.55±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br +

(

2A2) SiF3 Br ** 16.10±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br +

(

2 E) SiF3 Br ** 16.63±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br +

(

2 E) SiF3 Br ** 17.36±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br+

(

2A,) SiF3 Br ** 18.10±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br+

(

2E) SiF3 Br ** 18.80±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

SiF3 Br+

(

2 A,) SiF3 Br ** 20.80±0.02 (V) PE 4026

(RN-CAS Registry Number 14049-39-9)

PBr+ PBr3 14.2±0.2 EDD 3556

(RN-CAS Registry Number 7789-60-8)

PBr2+ PBr3 Br 1 1.2±0.1 EDD 3556

(RN-CAS Registry Number 7789-60-8)

PBr,t

2A,) PBr3 ** 9.96 (V) PE 4023

PBr3fA,)

(RN-CAS Registry Number 7789-60-8)

PBr3 ** 10.00+0.03 (V) PE 3669

PBr5t

2 A2) (RN-CAS Registry Number 7789-60-8)

PBr3 ** 10.61 (V) PE 4023

PBr3t

2A2) (RN-CAS Registry Number 7789-60-8)

PBr3 ** 10.67+0.03 (V) PE 3669

PBr3t

2 EJ/2) (RN-CAS Registry Number 7789-60-8)

PBr3 ** 10.83 (V) PE 4023

PBr3fE)

(RN-CAS Registry Number 7789-60-8)

PBr3 ** 10.87±0.03 (V) PE 3669

PBr3t

2 E, /2) (RN-CAS Registry Number 7789-60-8)

PBr3 ** 11.16 (V) PE 4023

(RN-CAS Registry Number 7789-60-8)

294
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

PBr3t

2E) PBr3 ** 11.79 (V) PE 4023

(RN-CAS Registry Number 7789-60-8)

PBr3t

2E) PBr3 ** 11. 85 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-60-8)

PBr3t

2A,) PBr3 ** 13.09 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-60-8)

PBr3t

2Ai) PBr3 ** 13.13 (V) PE 4023

(RN-CAS Registry Number 7789-60-8)

PBr3t

2E) PBr3 ** 14.09±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-60-8)

PBr3t

2E) PBr3 ** 14.12 (V) PE 4023

(RN-CAS Registry Number 7789-60-8)

PBr3+ PBr3 ** 10.1 ±0.1 EDD 3556

(RN-CAS Registry Number 7789-60-8)

POBr3fE3/2) POBr3 ** 10.75 ±0.02 PE 3835

(RN-CAS Registry Number 7789-59-5)

POBr3t

2E3/2) POBr3 ** 10.99 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

POBr3t

2E) POBr3 ** 11. 03 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-59-5)

POBr3t

2E1/2) POBr3 ** 11.1 3 ±0.02 (V) PE 3835

(RN-CAS Registry Number 7789-59-5)

POBr3t

2E1/2) POBr3 ** 11.13 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

POBr^Aj) POBr3 ** 11.36 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

POBr^Aj) POBr3 ** 11. 38 ±0.02 (V) PE 3835

(RN-CAS Registry Number 7789-59-5)

POBr3t

2A2) POBr3 ** 1 1 .38 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-59-5)

POBr3fE3/2) POBr3 ** 11.73 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

POBr31(2E3/2) POBr3 ** 11.74±0.02 (V) PE 3835

(RN-CAS Registry Number 7789-59-5)

POBr31(2E) POBr3 ** 11. 75 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-59-5)

POBr3t

2E1/2) POBr3 ** 11.97 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

POBr3t

2El/2) POBr3 ** 11. 98 ±0.02 (V) PE 3835

(RN-CAS Registry Number 7789-59-5)

POBr3t

2A,) POBr3 ** 12.39 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

POBr3t

2A,) POBr3 ** 12.41 ±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-59-5)

POBr^A,) POBr3 ** 12.43±0.02 (V) PE 3835

(RN-CAS Registry Number 7789-59-5)

POBr31(2E) POBr3 ** 12.60±0.03 (V) PE 3669

(RN-CAS Registry Number 7789-59-5)

POBr3t

2E) POBr3 ** 12.61 (V) PE 4023

(RN-CAS Registry Number 7789-59-5)

295
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

POBr3t

2 E3/2, 2El/2) POBr3 ** (RN-CAS Registry Number 7789-59-5)

12.66±0.03 (V) PE 3835

POBr3t

2A,) POBr3 ** (RN-CAS Registry Number 7789-59-5)

14.37±0.02 PE 3835

POBr3t

2 A,) POBr3 ** (RN-CAS Registry Number 7789-59-5)

14. 57 ±0.03 (V) PE 3669

POBr3t

2 A,) POBr3 ** (RN-CAS Registry Number 7789-59-5)

14.60 (V) PE 4023

POBr3t

2 E) POBr3 ** (RN-CAS Registry Number 7789-59-5)

15.34±0.03 (V) PE 3669

POBr3t

2 E) POBr3 ** (RN-CAS Registry Number 7789-59-5)

15.35 (V) PE 4023

POBr3t

2E3/2>2E,/2) POBr3 ** (RN-CAS Registry Number 7789-59-5)

15.39±0.02 (V) PE 3835

PF2 Br + PF2 Br ** (RN-CAS Registry Number 15597-40-7)11. 08 ±0.1 (V) PE 3662

C4 H3 SBr + C4H3 SBr ** (Thiophene, 2-bromo-)

(RN-CAS Registry Number 1003-09-4)

8.664±0.005 PE 3911

C4 H3 SBr+ C4H3 SBr ** (Thiophene, 2-bromo-)

(RN-CAS Registry Number 1003-09-4)

8.664 PE 3645

C4 H3 SBr + C4H3 SBr ** (Thiophene, 2-bromo-)

(RN-CAS Registry Number 1003-09-4)

8.93±0.05 El 3482

C4 H3 SBr + C4H3 SBr ** (Thiophene, 2-bromo-)

(RN-CAS Registry Number 1003-09-4)

8.80 CTS 3787

C4 H3 SBr + C4H3 SBr ** (Thiophene, 3-bromo-)

(RN-CAS Registry Number 872-31-1)

8.812±0.005 PE 3911

C4H3 SBr+ C4H3 SBr ** (Thiophene, 3-bromo-)

(RN-CAS Registry Number 872-31-1)

8.812 PE 3645

C4H3 SBr+ C4 H3 SBr ** (Thiophene, 3-bromo-)

(RN-CAS Registry Number 872-31-1)

9.02±0.05 El 3482

SOBr2+ SOBr2 ** 10.54 (V) PE 3646

(RN-CAS Registry Number 507-16-4)

SOBr2+ SOBr2 ** 10.63 (V) PE 3705

(RN-CAS Registry Number 507-16-4)

SOBr2* SOBr2 ** 10.92 (V) PE 3705

(RN-CAS Registry Number 507-16-4)

SOBr^ SOBr2 ** 11.24 (V) PE 3705

(RN-CAS Registry Number 507-16-4)

SOBr2* SOBr2 ** 11.68 (V) PE 3705

SOBr2t

2 A')

(RN-CAS Registry Number 507-16-4)

SOBr2 ** 12.13 (V) PE 3705

(RN-CAS Registry Number 507-16-4)

296
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SOBr2t

2A") SOBr2 ** (RN-CAS Registry Number 507-16-4)

12.37 (V) PE 3705

SOBr2t

2 A') SOBr2 ** (RN-CAS Registry Number 507-16-4)

14.70 (V) PE 3705

SOBr^ SOBr2 ** (RN-CAS Registry Number 507-16-4)

15.81 (V) PE 3705

SOBr3t

2E3/2, 2E1/2) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

9.41 ±0.02 PE 3835

SOBr3t

2A2) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

10.92±0.01 (V) PE 3835

SOBr3t

2 E3/2) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

11.20±0.02 (V) PE 3835

SOBr3t

2 E,/2) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

11.42±0.01 (V) PE 3835

SOBr^Aj) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

11.83+0.01 (V) PE 3835

SOBr3fE3/2, 2E1/2) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

12.20+0.01 (V) PE 3835

SOBr3t

2A,) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

13.68+0.02 PE 3835

SOBr3fE3/2, 2E1/2) SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

14.68+0.02 (V) PE 3835

SOBr^ SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

—'18.2 (V) PE 3835

SOBr^* SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X) — 18.9 (V) PE 3835

SOBr^ SOBr3 ** (RN-CAS Registry Number XXXXX-XX-X)

-20.2 (V) PE 3835

PSBr3t

2E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

9.82 (V) PE 4023

PSBr3t

2E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

9.89±0.03 (V) PE 3669

PSBr3fA2) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

10.86 (V) PE 4023

PSBr3t

2 A2) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

10.94+0.03 (V) PE 3669

PSBr3fE3/2) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

11.16 (V) PE 4023

PSBr3t

2E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

11.21 ±0.03 (V) PE 3669

PSBr3fE1/2) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

11.38 (V) PE 4023

PSBr3t

2 A,) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

11.80 (V) PE 4023

PSBrjfA,) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

1 1.87±0.03 (V) PE 3669

PSBr3t

2E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

12.15 (V) PE 4023

PSBr3t

2E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

297

12.23±0.03 (V) PE 3669
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

PSBr3t

2 A,) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

13.91 (V) PE 4023

PSBrjfA,) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

13.97±0.03 (V) PE 3669

PSBr3t

2 E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

14.59 (V) PE 4023

PSBr3t

2E) PSBr3 ** (RN-CAS Registry Number 3931-89-3)

14.63 ±0.03 (V) PE 3669

C5 H8 ClBr + CjHgCIBr ** (Cyclopentane, l-bromo-2-chloro-, cis-)

(RN-CAS Registry Number 37722-39-7)

10.13±0.02 PE 4003

C5 H8 ClBr + C5 H8ClBr ** (Cyclopentane, 1-bromo 2-chloro-, trans-)

(RN-CAS Registry Number 14376-82-0)

10.23±0.02 PE 4003

C6H10ClBr+ C6H|0ClBr

(Cyclohexane, l-bromo-2-chloro-, cis-)

(RN-CAS Registry Number 51422-75-4)

10.03 ±0.02 PE 4003

C6H10ClBr + C6H10ClBr

(Cyclohexane, l-bromo-2-chloro-, trans-)

(RN-CAS Registry Number 13898-96-9)

10. 13 ±0.02 PE 4003

PClBr + PClBr2 Br

(RN-CAS Registry Number 13550-32-8)

(TR-Other product(s) thermochemically reasonable)

1 1.3±0.1 EDD 3556

PCl2 Br+ PCl2 Br ** (RN-CAS Registry Number 13536-48-6)

10.4±0.1 EDD 3556

PClBr2+ PClBr2 ** (RN-CAS Registry Number 13550-32-8)10.2±0.1 EDD 3556

C5 Os BrMn + Mn(CO)5 Br ** (RN-CAS Registry Number 14516-54-2)

8.86 (V) PE 3866

C6H3 N04MnBr+ m-BrMn(CO)4(CCH3) ** (RN-CAS Registry Number 37474-14-9)

8.26 (V) PE 3866

Cu3 Br3+ Cu3 Br3 ** (RN-CAS Registry Number 37190-22-0)9.7 El 3954

Cu4 Br^ Cu4 Br4 (RN-CAS Registry Number XXXXX-XX-X)

10.4 El 3954

Cu4 Br^ Cu4Br4 ** (RN-CAS Registry Number XXXXX-XX-X)9.2 El 3954

ZnBr2t

! nJ/2g) ZnBr2 ** (RN-CAS Registry Number XXXXX-XX-X)

10.89±0.05 (V) PE 3833

ZnBr2fn1/2g) ZnBr2 ** (RN-CAS Registry Number XXXXX-XX-X)

298

1 1.22±0.05 (V) PE 3833
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

ZnBrjtX) ZnBr2 ** 11.40±0.05 (V) PE 3833

(RN-CAS Registry Number XXXXX-XX-X)

ZnBr2t

!2„) ZnBr2 ** 12.28±0.05 (V) PE 3833

(RN-CAS Registry Number XXXXX-XX-X)

ZnBr2f2g

) ZnBr2 ** 13.55±0.05 (V) PE 3833

(RN-CAS Registry Number XXXXX-XX-X)

ZnBr2* ZnBr2 ** 18.69±0.05 (V) PE 3833

(RN-CAS Registry Number XXXXX-XX-X)

ZnBr2t

2nv2g) ZnBr2 ** 10.8 (V) PE 3963

(RN-CAS Registry Number 7699-45-8)

ZnBr2t

2 n3/J ZnBr2 ** 11.1 (V) PE 3963

(RN-CAS Registry Number 7699-45-8)

ZnBr2t

2 n 1/2g) ZnBr2 ** 11.2 (V) PE 3963

(RN-CAS Registry Number 7699-45-8)

ZnBr2t

2nl/2u) ZnBr2 ** 11.4 (V) PE 3963

(RN-CAS Registry Number 7699-45-8)

ZnBr2t

2ZJ ZnBr2 ** 12.3 (V) PE 3963

(RN-CAS Registry Number 7699-45-8)

ZnBr2\

2Zg) ZnBr2 ** 13.0 (V) PE 3963

(RN-CAS Registry Number 7699-45-8)

GeH3 Br+

(

2E3/2) GeH3 Br ** 10.61 ±0.02 (V) PE 3510

(RN-CAS Registry Number 13569-43-2)

GeH3Br+ GeH3 Br ** 10.72+0.05 (V) PE 3502

(RN-CAS Registry Number 13569-43-2)

GeH3 Br+

(

2E,/2) GeH3 Br ** 10.83±0.02 (V) PE 3510

GeH3Br+

(

2A,)

(RN-CAS Registry Number 13569-43-2)

GeH3Br ** 12.51 ±0.02 (V) PE 3510

GeH3 Br+

(

2E)

(RN-CAS Registry Number 13569-43-2)

GeH3 Br ** 12.9±0.1 (V) PE 3510

(RN-CAS Registry Number 13569-43-2)

GeH2 Br2+ GeH2Br2 ** 10.69 ±0.02 (V) PE 3510

(RN-CAS Registry Number 13769-36-3)

Kr+

(

2P3/2) Kr ** 14.0010±0.0012 S 3881

(RN-CAS Registry Number 7439-90-9)

(RS-Average of eight Rydberg series limits)

Kr+

(

2 P3/2) Kr ** 13.992±0.002 TPE 3525

Kr+

(

2P1/2) (RN-CAS Registry Number 7439-90-9)

Kr ** 14.661 ±0.002 TPE 3525

Kr+

(

2 P3/2) (RN-CAS Registry Number 7439-90-9)

Kr ** 13.974±0.004 PEN 3541

(RN-CAS Registry Number 7439-90-9)

KrFjfnj KrF2 ** 13.06-13.16 PE 3642

KrF2t

2 n3/2J

(RN-CAS Registry Number 13773-81-4)

KrF2 ** 13.34 (V) PE 3501

KrF2t

2 n 1/2u) (RN-CAS Registry Number 13773-81-4)

KrF2 ** 13.47 (V) PE 3501

(RN-CAS Registry Number 13773-81-4)

299
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

KrF2t

22g

) KrF2 ** 13.75 PE 3642

(RN-CAS Registry Number 13773-81-4)

KrF2 KrF ** 13.90 (V) PE 3501 2f2g

) (RN-CAS Registry Number 13773-81-4)

KrF2 KrF,fn ** 14.0 PE 3642

g

) (RN-CAS Registry Number 13773-81-4)

KrF2 ** (RN-CAS Registry Number 13773-81-4)

KrF 14.37 (V) PE 3501 2fng

) KrF2fnu) KrF2 ** 16.25 PE 3642

(RN-CAS Registry Number 13773-81-4)

KrF2fnj KrF2 ** (RN-CAS Registry Number 13773-81-4)

16.92 (V) PE 3501

KrF;f2u) KrF2 ** 17.7 (V) PE 3501

(RN-CAS Registry Number 13773-81-4)

KrFjfSJ KrF2 ** 17.7 (V) PE 3642

KrF2t

2 2g?) (RN-CAS Registry Number 13773-81-4)

KrF2 ** 22.0 PE 3642

(RN-CAS Registry Number 13773-81-4)

KrF2 ** (RN-CAS Registry Number 13773-81-4)

KrF 23.0 (V) PE 3501 2t

2 2g

)

Rb+ RbOH OH ~10 El 3461

(RN-CAS Registry Number 1310-82-3)

Rb + RbCl Cl 8.695 ±0.03 PI 3536

(RN-CAS Registry Number 7791-11-9)

(TV-Threshold value approximately corrected to 0°K)

Rb+ RbBr Br 8.12±0.03 PI 3536

(RN-CAS Registry Number 7789-39-1)

(TV-Threshold value approximately corrected to 0°K)

Rb + Rbl I 7.53±0.03 PI 3536

(RN-CAS Registry Number 7790-29-6)

(TV-Threshold value approximately corrected to 0°K)

Rb +2 Rb+ ** 27.285±0.003 S 3924

(RN-CAS Registry Number 22537-38-8)

RbCl + RbCl ** 8.50±0.03 PI 3536

(RN-CAS Registry Number 7791-11-9)

(HB-Threshold value approximately corrected for hot bands)

RbBr +

(HB-Threshold

RbBr ** (RN-CAS Registry Number 7789-39-1)

value approximately corrected for hot bands)

7.935±0.03 PI 3536

Rb2 Br + Rb2 Br2 Br

(RN-CAS Registry Number 12409-58-4)

(TV-Threshold value approximately corrected to 0°K)

8.485±0.05 PI 3536

Sr Sr ** (RN-CAS Registry Number 7440-24-6)

5.7 El 3486

300
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Sr +2 Sr ** (RN-CAS Registry Number 7440-24-6)

16 El 3486

Sr+3 Sr ** (RN-CAS Registry Number 7440-24-6) — 60 El 3486

Sr+3

(

2 P3/2) Sr+ 2 ** (RN-CAS Registry Number 22537-39-9)

42. 88388 ±0.000 19 S 3926

Sr+3

(

2 P,/2) Sr+2 ** (RN-CAS Registry Number 22537-39-9)

44.08999 ±0.000 19 D 3926

SrCl + SrCl ** (RN-CAS Registry Number 14989-33-4)

5.10±0.06 SI 3526

Y

+ Y ** (RN-CAS Registry Number 7440-65-5)

6.7±0.5 El 3600

y

+6

(

4s3/2) Y+5 ** (RN-CAS Registry Number 39956-79-1)

89.26±0.25 S 3917

Y

+6

(

2 D5/2) Y

+5 ** (RN-CAS Registry Number 39956-79-1)

(RS-Average of two Rydberg series limits)

92.57±0.20 S 3917

YS + YS ** (RN-CAS Registry Number 12210-79-6)6.0 El 4001

YSe+ YSe ** (RN-CAS Registry Number 12067-44-6)

7.9±0.5 El 3600

Zr+5

(

2 P3/2) Zr+YSo) ** (RN-CAS Registry Number 15543-40-5)

78.95±0.01 S 3591

Zr+5

(

2 P 1/2) Zr+4

(‘S0) ** (RN-CAS Registry Number 15543-40-5)

80.89±0.01 s 3591

Zr+6 Zr+

5

** (RN-CAS Registry Number 20679-76-9)

95.8±0.6 s 3895

Zr+6 Zr+5 ** (RN-CAS Registry Number 20679-76-9)

95.8±0.6 s 3912

ZrCl + ZrCl4 (RN-CAS Registry Number 10026-11-6)

21.9 El 3783

ZrCl2+ ZrCl4 (RN-CAS Registry Number 10026-11-6)

16.8 El 3783

ZrCl3+ ZrCl4 (RN-CAS Registry Number 10026-11-6)

12.3 El 3783

ZrCl4+ ZrCl4 ** (RN-CAS Registry Number 10026-11-6)

10.6 El 3783

Nb+6

(

2 P3/2 ) Nb+5

(’S0) ** 102.73±0.01 S 3591

(RN-CAS Registry Number 22537-41-3)

301
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Nb+ ‘(2 P|/2> Nb+s

(

, S0) (RN-CAS Registry Number 22537-41-3)

105.1 1 ±0.01 S 3591

Nb+7 Nb +6 ** (RN-CAS Registry Number 23844-85-1)

1 18.9±0.07 PE 3894

NbF3+ NbF4? F?

(RN-CAS Registry Number 13842-88-1)

21.0 El 3783

NbF4+ NbF4? ** (RN-CAS Registry Number 13842-88-1)

14.0 El 3783

Nb2 F9+ Nb2 F9? ** (RN-CAS Registry Number XXXXX-XX-X)

14.2 El 3783

Nb3F,+

4 Nb3 F14? (RN-CAS Registry Number XXXXX-XX-X)

13.0 El 3783

NbCl + NbCl5 (RN-CAS Registry Number 10026-12-7)

24.2 El 3783

NbCl2+ NbCl5 (RN-CAS Registry Number 10026-12-7)

19.5 El 3783

NbCl3+ NbCl5 (RN-CAS Registry Number 10026-12-7)14.6 El 3783

NbCl4+ NbClj

(RN-CAS Registry Number 10026-12-7)

10.7 El 3783

Mo+ ((CH3 )2 N)3 PMo(CO)5 (RN-CAS Registry Number 14971-43-8

18.4±0.05 El 3952

Mo+ (((CH3)2N)3 P)2 Mo(CO)4 (RN-CAS Registry Number 27342-90-1)

15.3±0.05 El 3952

Mo+ MoCl5 (RN-CAS Registry Number 10241-05-1)

23.1 El 3783

Mo+7

(

2P3/2) Mo+6

(

, S0) ** (RN-CAS Registry Number 16065-87-5)

126.81 ±0.01 S 3591

Mo+7

(

2P1/2) Mo+6

('S„)

(RN-CAS Registry Number 16065-87-5)

129.70±0.01 S 3591

Mo + 8 Mo+7 ** (RN-CAS Registry NumBer 20908-14-9)

144.0 ±1.0 PE 3893

C606Mo+ Mo(CO)6 ** (RN-CAS Registry Number 13939-06-5)

8.50±0.02 (V) PE 3979

C6H18 N3 PMo+ ((CH3)2 N)3 PMo(CO)5 5CO

(RN-CAS Registry Number 14971-43-8

10.3±0.05 El 3952

302
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C6H18 N3 PMo+ (((CH3)2N)3 P)2Mo(CO)4 (RN-CAS Registry Number 27342-90-1)

16.1 ±0.05 El 3952

C,2H36N6P2 Mo+ (((CH3)2N)3 P)2Mo(CO)4 4CO

(RN-CAS Registry Number 27342-90-1)

14.8±0.05 El 3952

C7H18 N3OPMo+ ((CH3)2N)3 PMo(CO)5 4CO

(RN-CAS Registry Number 14971-43-8

12.1+0.05 El 3952

CsH„N302 PMo+ ((CH3)2N)3 PMo(CO)5 3CO

(RN-CAS Registry Number 14971-43-8

9.9+0.05 El 3952

C9HJ8 N303PMO+ ((CH3)2N)3 PMo(CO)5 2CO

(RN-CAS Registry Number 14971-43-8)

9.6+0.05 El 3952

c,„h I8 n3o4pmo+ ((CH3)2N)3 PMo(CO)5 CO

(RN-CAS Registry Number 14971-43-8)

7.8+0.05 El 3952

CuH18 N305 PMo+ ((CH3)2N)3 PMo(CO)5 (RN-CAS Registry Number 14971-43-8)

5.7+0.05 El 3952

C13H36N6OP2Mo+ (((CH3)2N)3P)2Mo(CO)4 3CO

(RN-CAS Registry Number 27342-90-1)

14.0+0.05 El 3952

C14H36N602 P2Mo+ (((CH3)2N)3P)2Mo(CO)4 2CO

(RN-CAS Registry Number 27342-90-1)

11.2+0.05 El 3952

cI5 h36n6o3p2Mo+ (((CH3)2N)3P)2Mo(CO)4 CO

(RN-CAS Registry Number 27342-90-1)

11.1+0.05 El 3952

C16H36N604P2Mo+ (((CH3)2N)3P)2Mo(CO)4 (RN-CAS Registry Number 27342-90-1)

6.8+0.05 El 3952

MoC1+ MoC15 (RN-CAS Registry Number 10241-05-1)

20.3 El 3783

MoC12+ MoC15 (RN-CAS Registry Number 10241-05-1)

17.1 El 3783

MoC13+ MoCl5 (RN-CAS Registry Number 10241-05-1)

12.9 El 3783

MoC14+ MoCl5 (RN-CAS Registry Number 10241-05-1)

10.1 El 3783

MoC15+ MoCl5 ** (RN-CAS Registry Number 10241-05-1)

9.2 El 3783

Mo02C12+ Mo02Cl2 ** (RN-CAS Registry Number 13637-68-8)

12.2±~0.5 El 3604

303
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

MoOC13+ MoOC14 (RN-CAS Registry Number 13814-75-0)

10.9±0.5 El 3604

MoOC14+ MoOC14 ** (RN-CAS Registry Number 13814-75-0)

10.6± 1 El 3604

Mo02 Br2+ Mo02 Br2 ** (RN-CAS Registry Number 13595-98-7)

10.9± ~0.5 El 3604

Mo02 ClBr + Mo02 ClBr ** (RN-CAS Registry Number XXXXX-XX-X)1 1. 1 ± —0.5 El 3604

Ru + (C5 H5 ) 2 Ru (C5 H5)2 (Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

(MT-Metastable transition(s) observed)

16.50±0.25 DC 3628

C3 H3 Ru + (C5 H5) 2 Ru 19.6±0.2 El 3628

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

C5 H5 Ru+ (C5 H5)2 Ru C5 H5 14.75 ±0.25 DC 3628

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

(MT-Metastable transition(s) observed)

C5 H5 Ru + (C5 H5 )2 Ru C5 H5 14.2± 1 El 3628

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

(PC-Appearance potential of the corresponding metastable transition)

C5 H5 Ru+ (C5 H5 ) 2 Ru C3 H3 + C2H2 16.5± 1 El 3628

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

C8 H8 Ru + (C5 H5 ) 2 Ru C2H2 14. 1 ± 1 El 3628

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

(PC-Appearance potential of the corresponding metastable transition)

C8 H8 Ru+ (C5 H5 ) 2 Ru C2 H2 14.6±0.2 El 3628

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

(MT-Metastable transition(s) observed)

C,0HioRu + (C5 H5)2 Ru

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

7.45 (V) PE 3688

C.oH.qRu" (C5 H5)2 Ru

(Ruthenocene)

(RN-CAS Registry Number 1287-13-4)

7.50±0.25 DC 3628

304
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

Ci2H14Ru+ (C5 H4CH3)2Ru

(Ruthenocene, l,l'-dimethyl-)

(RN-CAS Registry Number 33292-37-4)

7.25 (V) PE 3688

Ru04fT2) Ru04 ** (RN-CAS Registry Number 20427-56-9)

12.09 PE 3836

Ru04+ Ru04 ** (RN-CAS Registry Number 20427-56-9)

12.16 PE 3838

Ru04t

2T,) Ru04 ** (RN-CAS Registry Number 20427-56-9)

12.91 PE 3836

Ru04fA,) Ru04 ** (RN-CAS Registry Number 20427-56-9)

13.78 PE 3836

Ru04t

2 E) Ru04 ** (RN-CAS Registry Number 20427-56-9)

13.88 PE 3836

Ru04t

2T2) Ru04 ** (RN-CAS Registry Number 20427-56-9)

16.03 (V) PE 3836

Ci 5H306F18Ru+ (CF3 COCHCOCF3)3 Ru ** 8.85±0.07 (V)

(Ruthenium, tris( 1 , 1 , 1 , 5, 5 , 5-hexafluoropentanedionato-O,O')-, (OC-6- (RN-CAS Registry Number 16827-63-7)

PE

11)-)

3682

RhC+ RhC ** (RN-CAS Registry Number 12127-42-3)

8.1 ±0.6 El 3978

RhC+ RhC ** (RN-CAS Registry Number 12127-42-3)

8.6±0.04 El 3902

RhC2 RhC, ** (RN-CAS Registry Number 37306-47-1)

8.1 ±0.04 El 3902

C7H704Rh+ (CH3 COCHCOCH3)Rh(CO)2 ** (Dicarbonyl(2,4-pentanedionato)rhodium)

(RN-CAS Registry Number 14874-82-9)

8.6±0.1 El 3497

C12H904Rh+ (CH3 COCHCOC6H5)Rh(CO)2 ** (Dicarbonyl(l-phenyl-l,3-butanedionato)rhodium)

(RN-CAS Registry Number 24151-55-1)

8.4±0.1 El 3497

C17Hu04Rh+ (C6H5 COCHCOC6H5 )Rh(CO)2 ** 8.4±0.1

(Dicarbonyl( 1 ,3-diphenyl- 1 ,3-propanedionato)rhodium)

(RN-CAS Registry Number 24151-56-2)

El 3497

C15 H21 06Rh+ (CH3 COCHCOCH3) 3 Rh ** (Tris(2, 4-pentanedionato)rhodium)

(RN-CAS Registry Number 14284-92-5)

7.34±0.01 El 3496

Ci5 H21 06Rh + (CH3 COCHCOCH3)3Rh ** (Tris(2,4-pentanedionato)rhodium)

(RN-CAS Registry Number 14284-92-5)

7.75±0.05 El 3497

C, 5 H20NO8Rh+ ((CH3 C0)2CH)2 Rh(N02C(0CCH3)2) ** 7.65 ±0.02 El

(OC-6-22-(3-Nitro-2,4-pentanedionato-02,0

4)bis(2,4-pentanedionato-O,O')rhodium)

3496

(RN-CAS Registry Number 36530-11-7)

305
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

Ionization or appearance Method Ref.

products potential

(eV)

C15 H19 N2O10Rh + ((CH3 C0)2CN02)2 Rh(CH(0CCH3)2) ** 7.97+0.03 El 3496

(6>C-6-21-Bis(3-nitro-2,4-pentanedionato-02 ,0

4)(2,4-pentanedionato-0,0')rhodium)

(RN-CAS Registry Number 36530-12-8)

C15 H 18 N3 012 Rh+ (CH3 C0C(N02)C0CH3)3 Rh ** 8.39+0.04 El 3496

(OC-6- 1 1 -Tris(3-nitro-2,4-pentanedionato-02 ,0

4)rhodium)

(RN-CAS Registry Number 36530-13-9)

C7 H404F3 Rh + (CH3 COCHCOCF3)Rh(CO)2 ** 8.85+0.05

(Dicarbonyl( 1,1, l-trifluoro-2,4-pentanedionato)rhodium)

(RN-CAS Registry Number 18517-13-0)

El 3497

C7H04F6Rh + (CF3 COCHCOCF3)Rh(CO)2 ** 9.2±0.1

(Dicarbonyl( 1,1, 1 ,5,5,5-hexafluoro-2,4-pentanedionato)rhodium)

(RN-CAS Registry Number 18517-12-9)

El 3497

RhP4F12 H

+ HRh(PF3)4 ** (RN-CAS Registry Number 16949^18-7)

9.7 PE 4021

Pd + Pd ** (RN-CAS Registry Number 7440-05-3)

8.0+0.4 El 3597

C6 H10Pd + (C3 H5)2Pd 7.24+0.03 PE 3711

(Palladium, bis(i7

3-2-propenyl)-)

(RN-CAS Registry Number 12240-87-8)

, 12«lg^2w2 * u C12 H18 02N2 Pd ** 6.88 (V) PE 3822

(Palladium, [[4,4'—( 1 ,2-ethanediyldinitrilo)bis[2-pentanonato]](2')-A,Ar,6>,6>']- (SP-A-2)-)

(RN-CAS Registry Number 38337-62-1)

Ag+ Ag ** 7.51+0.07 RPD 3574

(RN-CAS Registry Number 7440-22-4)

Ag + Ag ** 7.6 El 3472

(RN-CAS Registry Number 7440-22-4)

Ag+ Ag ** 7.8+0.2 El 3609

(RN-CAS Registry Number 7440-22-4)

Ag + AgCl 1 1.1 ±0.3 El 3622

(RN-CAS Registry Number 7783-90-6)

Ag+ Ag3 Cl3 14.5 El 3622

(RN-CAS Registry Number 12444-97-2)

Ag + Ag3 Br2? 1 1.2±0.4 El 3467

(RN-CAS Registry Number 1 1078-32-3)

Ag+ Ag3 Br3? 1 1.2+0.4 El 3467

(RN-CAS Registry Number 11078-33-4)

Ag2+

Ag2+

Ag2+

Ag2 (RN-CAS Registry Number 12187-06-3)

Ag2 (RN-CAS Registry Number 12187-06-3)

Ag2 (RN-CAS Registry Number 12187-06-3)

7.35+0.05 RPD 3574

6.4+0.7 El 3440

7.4+0.8 El 3597

306
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Ag2+ Ag2 (RN-CAS Registry Number 12187-06-3)

8.0+ 1.0 El 3609

Ag2+ Ag3 Cl3 (RN-CAS Registry Number 12444-97-2)

18.0±0.5 El 3622

Ag2+ Ag3 Br2? (RN-CAS Registry Number 11078-32-3)

12.5 ± 1.0 El 3467

Ag2+ Ag3 Br3? (RN-CAS Registry Number 11078-33^1)

12.5±1.0 El 3467

Ag3+ Ag3 Cl3 (RN-CAS Registry Number 12444 97-2)

18.4+0.5 El 3605

NaAg+ NaAg ** (RN-CAS Registry Number 38782-42-2)

<9+2 El 3609

AgAl+ AgAl ** (RN-CAS Registry Number 12379-67-8)

7.8+0.5 El 3796

AgP02+ AgPOz ** (RN-CAS Registry Number XXXXX-XX-X)

9.3 El 4098

AgCl + AgCl ** (RN-CAS Registry Number 7783-90-6)

10.8+0.4 El 3622

AgCl + AgCl ** (RN-CAS Registry Number 7783-90-6)

11.3+0.5 El 3605

AgCl + Ag3Cl3 (RN-CAS Registry Number 12444-97-2)14.2 El 3622

Ag2Cl+ Ag2Cl2? (RN-CAS Registry Number XXXXX-XX-X)

10.8±0.5 El 3622

Ag2Cl + Ag3Cl3 (RN-CAS Registry Number 12444 97-2)

12.9 El 3622

Ag2Cl2+ Ag2Cl2 (RN-CAS Registry Number XXXXX-XX-X)

10.3+0.5 El 3605

Ag3Cl + Ag3Cl3 (RN-CAS Registry Number 12444-97-2)

14.9+0.5 El 3605

Ag3Cl2+ Ag3Cl3 (RN-CAS Registry Number 12444 97-2)

11.1+0.3 El 3622

Ag3Cl2+ Ag3Cl3 (RN-CAS Registry Number 12444 97-2)

11.1+0.5 El 3605

Ag3 Cl3+ Ag3Cl3 (RN-CAS Registry Number 12444-97-2)

10.0+0.5 El 3605

Ag3Cl3+ Ag3Cl3 (RN-CAS Registry Number 12444-97-2)

10.4+0.3 El 3622

Ag4Cl3+ Ag4Cl4 (RN-CAS Registry Number XXXXX-XX-X)

10.9±0.5 El 3605

307
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

Ag4Cl4+ Ag4Cl4 (RN-CAS Registry Number XXXXX-XX-X)

9.6± 1.0 El 3605

Ag5 Cl4+ Ag5 Cl5? (RN-CAS Registry Number XXXXX-XX-X)10.0± 1.5 El 3605

AgBr+ AgBr ** (RN-CAS Registry Number 7785-23-1)9.5±0.3 El 3467

Ag2 Br + Ag3 Br2? (RN-CAS Registry Number 11078-32-3)

1 1.4±0.7 El 3467

Ag2 Br + Ag3 Br3? (RN-CAS Registry Number 1 1078-33-4)

1 1.4±0.7 El 3467

Ag3 Br2+ Ag3 Br2 ** (RN-CAS Registry Number 11078-32-3)

10.0±0.2 El 3467

Ag3 Br3+ Ag3 Br3 ** (RN-CAS Registry Number 11078-33-4)

9.8±0.2 El 3467

Cd +

(

2S1/Z) Cd +

(

2 Pl/2) Cd +

(

2 PV2) Cd+

(

2 Ds/2) Cd+

(

2 DJ/2) Cd +

(

2 DM) Cd+

Cd ** (RN-CAS Registry Number 7440-43-9)

Cd ** (RN-CAS Registry Number 7440-43-9)

Cd ** (RN-CAS Registry Number 7440-43-9)

Cd ** (RN-CAS Registry Number 7440-43-9)

Cd ** (RN-CAS Registry Number 7440-43-9)

Cd ** (RN-CAS Registry Number 7440-43-9)

Cd ** (RN-CAS Registry Number 7440-43-9)

cdci^ry cdci2 ** (RN-CAS Registry Number 10108-64-2)

CdCl2+ CdCl2 ** (RN-CAS Registry Number 10108-64-2)

CdCl^IIJ CdCl2 ** (RN-CAS Registry Number 10108-64-2)

CdCl2t

2 Hu) CdCl2 ** (RN-CAS Registry Number 10108-64-2)

CdCl^SJ CdCl2 ** (RN-CAS Registry Number 10108-64-2)

CdCl2t

2 2u) CdCl2 ** (RN-CAS Registry Number 10108-64-2)

CdCl2t

2 2g

) CdCl2 ** (RN-CAS Registry Number 10108-64-2)

CdCl2t

2 2g

) CdCl2 ** (RN-CAS Registry Number 10108-64-2)

8.99 PEN 3537

14.5 PEN 3537

14.9 PEN 3537

17.6 PEN 3537

18.4 PEN 3537

20.2 PEN 3537

9.07±0.07 RPD 3745

11.3 (V) PE 3963

1 1.44±0.05 (V) PE 3833

11.8 (V) PE 3963

11. 93 ±0.05 (V) PE 3833

12.4 (V) PE 3963

12.53 ±0.05 (V) PE 3833

13.1 (V) PE 3963

13.12±0.05 (V) PE 3833

308
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CdBr^2n3/2g) CdBr2 ** 10.3 (V) PE 3963

(RN-CAS Registry Number 7789-42-6)

CdBr2 CdBr ** 10. 58 ±0.05 (V) PE 3833 2fnMe) (RN-CAS Registry Number 7789-42-6)

CdBr2t

2 nv2u) CdBr2 ** 10.6 (V) PE 3963

CdBr2fn1/2g) (RN-CAS Registry Number 7789-42-6)

CdBr2 ** 10.7 (V) PE 3963

(RN-CAS Registry Number 7789-42-6)

CdBr2t

2 n 1/2u) CdBr2 ** 10.8 (V) PE 3963

CdBr2t

2 n1/2g) (RN-CAS Registry Number 7789-42-6)

CdBr2 ** 10.94±0.05 (V) PE 3833

(RN-CAS Registry Number 7789-42-6)

CdBr2fnj CdBr2 ** 11.1 5 ±0.05 (V) PE 3833

(RN-CAS Registry Number 7789-42-6)

CdBr2fSJ CdBr2 ** 11.7 (V) PE 3963

(RN-CAS Registry Number 7789-42-6)

CdBr2t

2 l„) CdBr2 ** 1 1 .85 ±0.05 (V) PE 3833

CdBr2t

22g) (RN-CAS Registry Number 7789-42-6)

CdBr2 ** 12.4 (V) PE 3963

(RN-CAS Registry Number 7789-42-6)

CdBr2 CdBr ** 12.78±0.05 (V) PE 3833 2t

!2g

) (RN-CAS Registry Number 7789-42-6)

In +In ** 5.85±0.07 RPD 3745

(RN-CAS Registry Number 7440-74-6)

In2+ln20? 12.9±0.5 El 3491

(RN-CAS Registry Number 12030-22-7)

InO+

ln20? In? 14.8±0.5 El 3491

(RN-CAS Registry Number 12030-22-7)

ln20

+

ln20? ** 8.3±0.3 El 3491

(RN-CAS Registry Number 12030-22-7)

InCl + (X22)

InCl +

(

2n>

InCl +

(

22)

InCl ** (RN-CAS Registry Number 13465-10-6)

InCl ** (RN-CAS Registry Number 13465-10-6)

InCl ** (RN-CAS Registry Number 13465-10-6)

9.51 PE 3640

10.17 PE 3640

12.82 PE 3640

6.62 PE 3640

9.09 PE 3640

12.38 PE 3640

7.28±0.07 RPD 3745

InBr +

(

2 II)

InBr+ (X22)

InBr +

(

22)

InBr ** (RN-CAS Registry Number 14280-53-6) InBr ** (RN-CAS Registry Number 14280-53-6) InBr ** (RN-CAS Registry Number 14280-53-6)

Sn' Sn ** (RN-CAS Registry Number 7440-31-5)

309
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

SnH4t

2 B2 ) SnH4 ** (RN-CAS Registry Number 2406-52-2)

10.75 PE 3716

SnH4fA,) SnH4 ** (RN-CAS Registry Number 2406-52-2)16.68 PE 3716

C3 H9 Sn +

C3 H9 Sn +

C3 H9Sn +

C3 H9 Sn +

C3 H9 Sn +

C3 H9Sn +

C3 H9Sn +

C3 H9Sn +

(CH3 )4Sn CH3 9.58±0.19 El

(RN-CAS Registry Number 594-27-4)

(CH3)3 CSn(CH3)3 (CH3)3 C 9.32±0.16 El

(RN-CAS Registry Number 3531-47-3)

(CH3 )3 SnSn(CH3)3 (CH3)3 Sn 9.51 ±0.22 El

(RN-CAS Registry Number 661-69-8)

(CH3)3 SiSn(CH3)3 (CH3)3 Si 9.80±0.24 El

(RN-CAS Registry Number 16393-88-7)

C5 H5 (CO)3 CrSn(CH3)3 C5 H5(CO)3 Cr? 9.09 ±0.1 El

(Tricarbonyl(i75 -2,4-cyclopentadien- 1 -yl)(trimethylstannyl)chromium)

(RN-CAS Registry Number 31854-87-2)

(CH3)3 GeSn(CH3)3 (CH3)3Ge 9.85±0.22 El

(RN-CAS Registry Number 16393-89-8)

C5 H5 (CO)3 MoSn(CH3)3 C5 H5(CO)3 Mo? 9.85 ±0.1 El

(Tricarbonyl(i7

5 -2,4-cyclopentadien- 1 -yl)(trimethylstannyl)molybdenum)

(RN-CAS Registry Number 12214-92-5)

C5 H5 (CO)3 WSn(CH3)3 C5 H5(CO)3W? 10.05 ±0.1 5 El

(Tricarbony1 (t)

5-2,4—cyclopentadien- 1 -yl)(trimethylstannyl)tungsten)

(RN-CAS Registry Number 12093-29-7)

3548

3548

3548

3548

3495

3548

3495

3495

C4H12 Sn +

C4 H12 Sn +

C4 H 12 Sn +

(CH3)4Sn

(RN-CAS Registry Number 594-27-4)

(CH3)4Sn

(RN-CAS Registry Number 594-27-4)

(CH3)4Sn

(RN-CAS Registry Number 594-27-4)

8.85±0.1

8.93 ±0.04

8.76±0.12

PE

PE

El

3677

3880

3548

C7 Hlg Sn + (CH3)3 CSn(CH3)3 (RN-CAS Registry Number 3531-47-3)

8.34±0.1El 3548

C9 HI4 Sn + C6H5 Sn(CH3)3 (Stannane, trimethylphenyl-)

(RN-CAS Registry Number 934—56-5)

-8.75 CTS 3922

^-'10^16^n C6H5 CH2 Sn(CH3)3 (Stannane, trimethyl(phenylmethyl)-)

(RN-CAS Registry Number 4314-94-7)

7.91 CTS 3922

C12 H 16 Sn + C9H7 Sn(CH3)3 ** (Stannane, 1 //-inden- 1 -yltrimethyl-)

(RN-CAS Registry Number 23022-40-4)

7.29±0.01 El 3805

C12 Hjg Sn C9H9Sn(CH3)3 ** (Stannane, (2,3-dihydro- 17/-inden- 1 -yl)trimethyl-)

(RN-CAS Registry Number 41273-55-6)

7.29±0.01 El 3805

310
Table of Ion Energetics Measurements—Continued

Ion

Ionization or Reactant Other appearance Method Ref. products potential

(eV)

Ci3H16Sn+ C10H7Sn(CH3)3 ** 7.99 CTS 3922

(Stannane, trimethyl- 1 -naphthalenyl-)

(RN-CAS Registry Number 944-85-4)

Ci4H18 Sn + C10H7CH2 Sn(CH3)3 ** ~7.6 CTS 3922

(Stannane, trimethyl( 1 -naphthalenylmethyl)-)

(RN-CAS Registry Number 51220-36-1)

Ci4H30Sn+ CH2 =CHSn(«-C4H9)3 ** 8.6 (V) PE 3850

(RN-CAS Registry Number 7486-35-3)

C15H32Sn+ CH2 =CHCH2Sn(»-C4H9)3 ** 8.4 (V) PE 3850

(RN-CAS Registry Number 24850-33-7)

C16H36Sn+ («-C4H9)4Sn ** 8.7 (V) PE 3850

(RN-CAS Registry Number 1461-25-2)

^24^20^0 + (C6H5)4Sn ** 8.34+0.03 PI 4055

(Stannane, tetraphenyl-)

(RN-CAS-Registry Number 595-90-4)

C^H^Sn^- (CH3)3 SnSn(CH3)3 ** 8.02+0.15 El 3548

(RN-CAS Registry Number 661-69-8)

SnO+ SnO ** 9.5 + 1 El 3819

(RN-CAS Registry Number 21651-19-4)

C6H18SiSn+ (CH3)3 SiSn(CH3)3 ** 8.18+0.14 El 3548

(RN-CAS Registry Number 16393-88-7)

Ci6H44Si4Sn+ ((CH3)3SiCH2)4Sn ** 8.71 ±0.1 (V) PE 3830

(RN-CAS Registry Number 18547-12-1)

CfrHjgGeSn 4

^ (CH3)3 GeSn(CH3)3 ** 8.20±0.10 El 3548

(RN-CAS Registry Number 16393-89-8)

SnBrCl+ SnBrCl ** 10.3+0.3 El 3800

(RN-CAS Registry Number 13595-90-9)

SnBr2Cl + SnBr2Cl2? 12.0 El 3800

(RN-CAS Registry Number 13550-35-1)

SnBr2Cl + SnBr3Cl? 12.0 El 3800

(RN-CAS Registry Number 14779-73-8)

SnBr3Cl + SnBr3Cl ** 11.1 ±0.3 El 3800

(RN-CAS Registry Number 14779-73-8)

Sb+ Sb ** 8.68±0.06 El 3956

(RN-CAS Registry Number 7440-36-0)

Sb2+ Sb2 ** 9.3±0.2 S 3567

(RN-CAS Registry Number 32679-33-7)

311
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Sb2+ Sb2 ** (RN-CAS Registry Number 32679-33-7)

8.4±0.3 RPD 3599

Sb2+ Sb2 ** (RN-CAS Registry Number 32679-33-7)

8.64±0.06 El 3956

Sb2+ Sb2 ** (RN-CAS Registry Number 32679-33-7)

8.9±0.3 El 3961

Sb2+ Sb2 ** (RN-CAS Registry Number 32679-33-7)

9.5±0.5 El 3555

Sb2+ Sb4 (RN-CAS Registry Number 12597-17-0)

11.4±0.4 RPD 3599

Sb3+ Sb3 ** (RN-CAS Registry Number 37267-70-2)

8.5±0.3 RPD 3599

Sb3+ Sb3 ** (RN-CAS Registry Number 37267-70-2)

7.50+0.13 El 3956

Sb3+ Sb3 ** (RN-CAS Registry Number 37267-70-2)

9.0+0.2 El 3961

Sb3+ Sb4 (RN-CAS Registry Number 12597-17-0)

10.8+0.5 RPD 3599

Sb3+ Sb4 Sb

(RN-CAS Registry Number 12597-17-0)

10.8+0.3 El 3961

Sb4+ Sb4 ** (RN-CAS Registry Number 12597-17-0)

7.70+0.06 El 3956

Sb4+ Sb4 ** (RN-CAS Registry Number 12597-17-0)

8.4+0.3 El 3961

Sb4+ Sb4 ** (RN-CAS Registry Number 12597-17-0)

9.1 ±0.3 El 3555

SbHjfA,) SbH3 ** (RN-CAS Registry Number 7803-52-3)

9.51 PE 3719

SbH3t

2 E) SbH3 ** (RN-CAS Registry Number 7803-52-3)

1 1.39±0.02 PE 3719

C5 H5 Sb + C5 H5 Sb ** (Antimonin)

(RN-CAS Registry Number 289-75-8)

8.3 (V) PE 3832

SbF3+ SbF3 ** (RN-CAS Registry Number 7783-56-4)

12.61 ±0.El 3578

SbP + SbP ** (RN-CAS Registry Number 25889-81-0)

9.9±0.3 El 3596

TeH + TeH ** (RN-CAS Registry Number 13940-36-8)

9.09 S 3742

H2Te +

(

2 B|) H2Te ** (RN-CAS Registry Number 7783-09-7)

9.14 PE 3719

H2Te +

(

2 A1 ) H2Te ** (RN-CAS Registry Number 7783-09-7)

11.63 PE 3719

312
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

H2Te +

(

2 B2) H2 Te ** (RN-CAS Registry Number 7783-09-7)

13.04 PE 3719

H2Te+(2A,) H2Te ** (RN-CAS Registry Number 7783-09-7)

18.6 (V) PE 3719

C2H6Te+ (CH3)2Te

(RN-CAS Registry Number 593-80-6)

(RS-Average of three Rydberg series limits)

7.926±0.010 S 3970

C2 H6Te +

(

2 B,) (CH3 )2Te

(RN-CAS Registry Number 593-80-6)

7.89 (V) PE 3656

C4H4Te+ C4H4Te ** (Tellurophene)

(RN-CAS Registry Number 288-08-4)

8.27 PE 3858

C4H4Te+ C4H4Te ** (Tellurophene)

(RN-CAS Registry Number 288-08-4)

8.40±0.03 PE 3804

C4H4Te+ C4H4Te ** (Tellurophene)

(RN-CAS Registry Number 288-08-4)

8.60±0.1 El 3804

Cs H6Te+ C4H3TeCH3 ** (Tellurophene, 2-methyl-)

(RN-CAS Registry Number 35246-25-4)

8.25 ±0.

1

El 3804

C5 H4OTe+ C4H3TeCHO ** (2-Tellurophenecarboxaldehyde)

(RN-CAS Registry Number 35273-64-4)

8.88+0.1 El 3804

C6H6OTe+ C4H3 TeCOCH3 ** (Ethanone, l-tellurophene-2-yl-)

(RN-CAS Registry Number 35273-65-5)

8.60±0.1 El 3804

C5 H402Te+ C4H3TeCOOH ** (2-Tellurophenecarboxylic acid)

(RN-CAS Registry Number 35246-22-1)

8.80±0.1 El 3804

C6H602Te + C4H3 TeCOOCH3 ** (2-Tellurophenecarboxylic acid methyl ester)

(RN-CAS Registry Number 35246-23-2)

8.64+0.1 El 3804

TeP+ TeP ** (RN-CAS Registry Number 51890-39-2)

7.8 ± 1.0 El 4001

C5 H6 STe+ C4H3TeSCH3 ** (Tellurophene, 2-(methylthio)-)

(RN-CAS Registry Number 51299-95-7)

8.15+0.1 El 3804

Ge2 H6Te +

(

2 B,) (GeH3)2Te ** (RN-CAS Registry Number 24312-07-0)

8.34 (V) PE 3656

313
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

I + CH2*2 7 I CH,I 13.8 (RN-CAS Registry Number 75-11-6)

(AD-0.131 eV average translational energy of decomposition at threshold)

(TR-Other product(s) thermochemically reasonable)

I + CH2 I2 CH2 I 13.2±0.1

(RN-CAS Registry Number 75-11-6)

(AD-0.13 eV average translational energy of decomposition at threshold)

(TR-Other product(s) thermochemically reasonable)

RPD

El

tfnMg)

i2(RN-CAS Registry Number 7553-56-2)

(HB-Threshold value approximately corrected for hot bands)

i2t n 1/2g) h

(RN-CAS Registry Number 7553-56-2)

(HB-Threshold value approximately corrected for hot bands)

9.3 11 ±0.002

9.953±0.002

PE

PE

3490

3442

3870

3870

I2+ wo2 i2 (RN-CAS Registry Number 14447-89-3)

15.0±0.8 El 3451

I? I2(RN-CAS Registry Number 7553-56-2)

25.5+0.4 El 4052

ch3i +

(

2e3/2) (RS-Average

ch3i +

(

2e,/2)

(RS-Average

ch3 i +

(

2e3/2) CH3 I +

(

2Ei/2) ch3 i +

ch3 i (RN-CAS

of three Rydberg

ch3 i (RN-CAS

of three Rydberg

ch3i (RN-CAS

CH3I (RN-CAS

CH3I (RN-CAS

Registry Number

series limits)

Registry Number

series limits)

Registry Number

Registry Number

Registry Number

** 9.538 S 3748

74-88-4)

** 10.17 S 3748

74-88-4)

** 9.52 PE 3532

74-88-4)

** 10.14 PE 3532

74-88-4)

** 9.48±0.03 EDD 3626

74-88-4)

c2hi +

(

2e3/2) CjHI +

(

2E1/2)

CH=CI ** (RN-CAS Registry Number 14545-08-5)

CH=CI ** (RN-CAS Registry Number 14545-08-5)

9.7397

10.143

3751

3751

CH2 =CHI ** (RN-CAS Registry Number 593-66-8)

9.33 PE 3863

(RS-Average

CjHjI+^E,^

(RS-Average

C2HsI +

(

2E3/2)

CiH5 I (RN-CAS Registry Number 75-03-6)

of three Rydberg series limits)

C2H5I

(RN-CAS Registry Number 75-03-6)

of three Rydberg series limits)

cw

(RN-CAS Registry Number 75-03-6)

9.346 S 3748

9.929 S 3748

9.34 (V) PE 4076

314
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c2h5 i +

(

2e3/2) c2 h5 i ** 9.35 PE 3532

(RN-CAS Registry Number 75-03-6)

c2h5 i + c2 h5 i ** 9.45 ±0.02 (V) PE 3987

(RN-CAS Registry Number 75-03-6)

C2 H5 I +

(

2 Ei/2) c2h5 i ** 9.93 PE 3532

(RN-CAS Registry Number 75-03-6)

C2 H5

I +

(

2 Ei/2) c2h5i ** 9.93 (V) PE 4076

(RN-CAS Registry Number 75-03-6)

'3 n5

J

„3xa5

J

ch2 =chch2i ** (RN-CAS Registry Number 556-56-9)

ch2 =chch2i ** (RN-CAS Registry Number 556-56-9)

9.30

9.30 (V)

PE

PE

4091

3863

C3H7I +

(

2E3/2) «-c3h7i ** 9.269 S 3748

(RN-CAS Registry Number 107-08-4)

(RS-Average of three Rydberg series limits)

C3H7I +

(

2E1/2) «-c3h7i ** 9Ml S 3748

(RN-CAS Registry Number 107-08-4)

(RS-Average of three Rydberg series limits)

C3H7I +

(

2E3/2) «-c3h7i ** 9.25 PE 3532

(RN-CAS Registry Number 107-08-4)

C3H7 I +

(

2E3/2) n-C3H7I ** 9.27 PE 4076

C3H7I +

(

2E1/2) (RN-CAS Registry Number 107-08-4)

«-C3H7I ** 9.82 PE 4076

c3h7 i +

(

2e1/2) (RN-CAS Registry Number 107-08-4)

h-C3H7I ** 9.83 PE 3532

C3 H7I +

(

2E3/2) (RN-CAS Registry Number 107-08-4)

£so-C3H7I ** 9.19 PE 3532

c3h,i+

(

2e1/2) (RN-CAS Registry Number 75-30-9)

/5o-C3H7 I ** 9.75 PE 3532

(RN-CAS Registry Number 75-30-9)

c3h7i +/so-C3H7I ** 9.2± <0.1 El 3735

(RN-CAS Registry Number 75-30-9)

c4h9i+(2e3/2) h-C4H9I ** 9.229 S 3748

(RN-CAS Registry Number 542-69-8)

(RS-Average of four Rydberg series limits)

C4H9I +

(

2E1/2) «-C4H9I ** 9.791 S 3748

(RN-CAS Registry Number 542-69-8)

(RS-Average of three Rydberg series limits)

C4H9I +

(

zE3/2) n-CAH9I ** 9.23 PE 3532

(RN-CAS Registry Number 542-69-8)

C4h9I + n-C4H9I ** 9.24 PE 4076

C4H9I +

(2Ei/2) (RN-CAS Registry Number 542-69-8) «-c4h9i ** 9.79 PE 4076

C4H9I +

(

2 E|/2) (RN-CAS Registry Number 542-69-8) «-c4h9i ** 9.81 PE 3532

c4h,i +

(

2e3/2) (RN-CAS Registry Number 542-69-8)

tert-CAH9I ** 9.08 PE 3532

(RN-CAS Registry Number 558-17-8)

315
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

C4H9

I +

(

2 E1/2) tert-C*H9

I ** (RN-CAS Registry Number 558-17-8)

9.64 PE 3532

CsH„I+

(

2E3/2) n-Cs H„I

(RN-CAS Registry Number 628-17-1)

(RS-Average of three Rydberg series limits)

9.201 S 3748

QHnI^E,^ n-Cs H„I

(RN-CAS Registry Number 628-17-1)

(RS-Average of two Rydberg series limits)

9.760 S 3748

Cs H„I +

(

2 E3/2) n-C5 H„I

(RN-CAS Registry Number 628-17-1)

9.22 PE 3532

C5 H„I +

(

2El/2) n-CsH„I

(RN-CAS Registry Number 628-17-1)

9.78 PE 3532

C6H,jI +

(

2E3/2) «-c6h, 3 i (RN-CAS Registry Number 638-45-9)

(RS-Average of three Rydberg series limits)

9.179 S 3748

c6h13 i +

(

2 e1/2) «-c„h,,i

(RN-CAS Registry Number 638-45-9)

(RS-Average of three Rydberg series limits)

9.742 S 3748

c7 h7 i + c6h5 ch2 i ** (Benzene, (iodomethyl)-)

(RN-CAS Registry Number 620-05-3)

8.91 (V) PE 3992

c7 h7 i + c6h4ich3 ** (Benzene, l-iodo-2-methyl-)

(RN-CAS Registry Number 615-37-2)

8.53 ±0.

El 3777

c7h7 i + c6h4ich3 ** (Benzene, l-iodo-3-methyl-)

(RN-CAS Registry Number 625-95-6)

8.55±0.1 El 3777

c7 h7 i + c6h4ich3 ** (Benzene, l-iodo-4-methyl-)

(RN-CAS Registry Number 624-31-7)

8.60±0.El 3777

c12 h9

i + c6h5 c6h4

i (l,l'-Biphenyl, 2-iodo-)

(RN-CAS Registry Number 2113-51-1)

8.20±0.02 PE 3702

C2 H2 I

2+ trans-CW\ = Cm ** (RN-CAS Registry Number 590-27-2)

8.92 (V) PE 3648

C6H6NI + C6H4 INHCOCH3 CH2 = C= 0 10.48±0.03 El 3483

(Acetamide, Ar-(2-iodophenyl)-)

(RN-CAS Registry Number 19591-17-4)

C6H6NI + C6H4INHCOCH3 CH2 = C = 0 9.72±0.03 El 3483

(Acetamide, A-(4-iodophenyl)-)

(RN-CAS Registry Number 622-50-4)

316
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c25 h25n2 i + c25h25n2 i ** 7.25 PI 3586

(Quinolinium, 1 -ethyl-2-[3-( 1 -ethyl-2( l//)-quinolinylidene)- 1 -propenyl]-, iodide)

(RN-CAS Registry Number 605-91-4)

(ON-Other name: Pinacyanol)

C29H35 N2 I + C29H35 N2 I ** 7.35 PI 3586

(Quinolinium, 1 -(3-methylbutyl)-4-[[ 1 -(3-methylbutyl)-4( 1 i/)-quinolinylidene]methyl]-, iod

ide)

(RN-CAS Registry Number 523-42-2)

(ON-Other name: Quinoline Blue)

c4h12 bn2 i + ((CH3)2N)2 BI

(RN-CAS Registry Number 7318-71-0)

8.11 (V) PE 3704

c2h6bni2+ (CH3)2 NBI2 ** (RN-CAS Registry Number 7318-72-1)

8.95 (V) PE 3704

c2 h5 oi + ch2 ich2oh ** (RN-CAS Registry Number 624-76-0)

9.66+0.07 (V) PE 3987

c3 h7oi + ch3och2 ch2i ** (RN-CAS Registry Number 4296-15-5)

9.43+0.04 (V) PE 3987

C6H5 OI+ C6H4IOOCCH3 CH2 = C= 0 9.72±0.03 El 3483

(Phenol, 2-iodo-, acetate)

(RN-CAS Registry Number 32865-61-5)

C6H5OI + C6H4IOOCCH3 CH2 = C=0 9.38+0.03 El 3483

(Phenol, 4-iodo-, acetate)

(RN-CAS Registry Number 33527-94-5)

C2H3 02 I + CH2 ICOOH ** 11.03 (V) PE 3874

(RN-CAS Registry Number 64-69-7)

C8H702 I + C6H4IOOCCH3 ** 8.25+0.03 El 3483

(Phenol, 2-iodo-, acetate)

(RN-CAS Registry Number 32865-61-5)

C8 H702 I + C6H4IOOCCH3 ** 8.20+0.03 El 3483

(Phenol, 4-iodo-, acetate)

(RN-CAS Registry Number 33527-94-5)

C6H4OI2+ C6H3 I2 OOCCH3 CH2 =C=0 8.94±0.03 El 3480

(Phenol, 2,4-diiodo-, acetate)

(RN-CAS Registry Number 36914-80-4)

C6H4OI2+ C6H3 I2OOCCH3 CH2 = C =0 9. 18 ±0.03 El 3480

(Phenol, 2,6-diiodo-, acetate)

(RN-CAS Registry Number 28165-73-3)

C8 H602 I 2+ C6H3 I2OOCCH3 ** 7.90±0.03 El 3480

(Phenol, 2,4-diiodo-, acetate)

(RN-CAS Registry Number 36914-80-4)

317
Table of Ion Energetics Measurements—Continued

Ionization or

Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

c8 H6o2 i2+ C6H3 I

2OOCCH3 ** (Phenol, 2,6-diiodo-, acetate)

(RN-CAS Registry Number 28165-73-3)

8.07±0.03 El 3480

c8 h8 noi + C6H4 INHCOCH3 ** (Acetamide, Af-(2-iodophenyl)-)

(RN-CAS Registry Number 19591-17-4)

7.98±0.03 El 3483

c8 h8 noi + C6H4 INHCOCH3 ** (Acetamide, 7V-(4-iodophenyl)-)

(RN-CAS Registry Number 622-50-4)

7.87±0.03 El 3483

IF+ IF5 ** (RN-CAS Registry Number 7783-66-6)

12.943±0.005 PE 3655

Nal + Nal ** (RN-CAS Registry Number 7681-82-5)

(HB-Threshold value approximately corrected for hot bands)

7.64±0.02 PI 3536

Mgl2+ Mgl2 (RN-CAS Registry Number 10377-58-9)

9.57±0.03 PI 3536

SiH3 I +

(

2E3/2) SiH3 I ** (RN-CAS Registry Number 13598-42-0)

9.78±0.02 (V) PE 3510

SiH3 I + SiH3 I ** (RN-CAS Registry Number 13598-42-0)

10.05 ±0.05 (V) PE 3502

SiH3 I +

(

2El/2) SiH3 I ** (RN-CAS Registry Number 13598-42-0)

10.33±0.02 (V) PE 3510

SiH3I +

(

2A,) SiH3 I ** (RN-CAS Registry Number 13598-42-0)

12.04±0.02 (V) PE 3510

SiH3 I +

(

2 E) SiH3 I ** (RN-CAS Registry Number 13598-42-0)

12.8±0.1 (V) PE 3510

SiH2 I2+ SiH2 I2 ** (RN-CAS Registry Number 13760-02-6)

9.69 ±0.02 (V) PE 3510

C5 H9SiI + (CH3)3 SiC=CI ** (RN-CAS Registry Number 18163-47-8)

9.1 ±0.1 PE 4002

PI3t

2A,) PI3 ** (RN-CAS Registry Number 13455-01-1)

9.15 (V) PE 4023

PI,t

2Aj) PI3 ** (RN-CAS Registry Number 13455-01-1)

9.42 (V) PE 4023

PIjt

2E3/2) PI3 ** (RN-CAS Registry Number 13455-01-1)

9.57 (V) PE 4023

PI)t

2 E1/2) PI3 ** (RN-CAS Registry Number 13455-01-1)

10.24 (V) PE 4023

pi3K

2e1/2) PI3 ** (RN-CAS Registry Number 13455-01-1)

10.53 (V) PE 4023

pi3X

2e3/2) PI3 ** (RN-CAS Registry Number 13455-01-1)

10.68 (V) PE 4023

PI3t

2A,) PI3 ** 11.80 (V) PE 4023

(RN-CAS Registry Number 13455-01-1)

318
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

PI3t

2 E) PI3 ** (RN-CAS Registry Number 13455-01-1)

12.70 (V) PE 4023

pf2 i + pf2i ** (RN-CAS Registry Number 13819-11-9)

10.1 ±0.1 (V) PE 3662

c4h2 si2+ C4H2 S(I)2 (Thiophene, 2,5-diiodo-)

(RN-CAS Registry Number 625-88-7)

8.32 El 3787

c4h2si2+ C4H2 S(I)2 (Thiophene, 2,5-diiodo-)

(RN-CAS Registry Number 625-88-7)

8.35 CTS 3787

ici +

(

2 n3/2) IC1 ** (RN-CAS Registry Number 7790-99-0)

10.088±0.01 S 4027

ici+

(

2n,/2> IC1 ** (RN-CAS Registry Number 7790-99-0)

10.662±0.01 s 4027

C5 05 IMn+ Mn(CO)5 I ** (RN-CAS Registry Number 14879-42-6)

8.44-8.74 (V) PE 3866

Cul + Cul ** (RN-CAS Registry Number 7681-65-4)

8.7+0.5 El 3603

Cul + Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

14.4+0.5 El 3603

Cu2I + Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

13.4+0.5 El 3603

Cu3 I + Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

15.2±0.5 El 3603

Cul2+ Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)16.1+0.5 El 3603

Cu2I2+ Cu2I2 ** (RN-CAS Registry Number XXXXX-XX-X)

9.3±0.5 El 3603

Cu2I^ Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

14.8±0.5 El 3603

Cu3 I2+ C113 I3 (RN-CAS Registry Number XXXXX-XX-X)

10.8+0.5 El 3603

Cu2 I3+ Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

13.6+0.5 El 3603

Cu3 I3+ Cu3 I3 (RN-CAS Registry Number XXXXX-XX-X)

9.1+0.5 El 3603

Cu4I 3+ Cu4

I4 (RN-CAS Registry Number XXXXX-XX-X)

9.5±0.5 El 3603

319
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Cu4

I 4+ Cu4

I 4 (RN-CAS Registry Number XXXXX-XX-X)

8.7±0.5 El 3603

ZnI2 (

2 nJ/2g) Znl2 ** 9.73±0.05 (V) PE

(RN-CAS Registry Number 10139-47-6)

3!

ZnI2t

2nJ/2g) Znl2 ** (RN-CAS Registry Number 10139-47-6)

9.7 (V) PE 3963

ZnI2t

2 n J/2u) Znl2 ** (RN-CAS Registry Number 10139-47-6)

10.2 (V) PE 3963

zni2t

2 n l/2g, 2 nu) Znl2 ** (RN-CAS Registry Number 10139-47-6)

10.32±0.05 (V) PE 3833

zm2fnl/2g) Znl2 ** (RN-CAS Registry Number 10139-47-6)

10.35 (V) PE 3963

zm2t

2 n,/2u) Znl2 ** (RN-CAS Registry Number 10139-47-6)

10.5 (V) PE 3963

ZnI2t

2 X„) Znl2 ** (RN-CAS Registry Number 10139-47-6)

11.4 (V) PE 3963

ZnI2t

2Xu) Znl2 ** (RN-CAS Registry Number 10139-47-6)

11. 45 ±0.05 (V) PE 3833

ZnI2fXg

) Znl2 ** (RN-CAS Registry Number 10139-47-6)

12.4 (V) PE 3963

Znl2f2g

) Znl2 ** (RN-CAS Registry Number 10139-47-6)

12.74±0.05 (V) PE 3833

Znl? Znl2 ** (RN-CAS Registry Number 10139-47-6)18.39±0.05 (V) PE 3833

GeH3I +

(

2E3/2) GeH3 I ** (RN-CAS Registry Number 13573-02-9)

9.59±0.02 (V) PE 3510

GeH3 I + GeH3 I ** (RN-CAS Registry Number 13573-02-9)

9.84±0.05 (V) PE 3502

GeH3I +

(

2E|/2) GeH3 I ** (RN-CAS Registry Number 13573-02-9)

10. 14±0.02 (V) PE 3510

GeH3 I +

(

2 A,) GeH3 I ** (RN-CAS Registry Number 13573-02-9)

11. 71 ±0.02 (V) PE 3510

GeH3 I +

(

2 E) GeH3 I ** (RN-CAS Registry Number 13573-02-9)

12.6±0.1 (V) PE 3510

GeH2 I

2+ GeH2 I2 ** (RN-CAS Registry Number 14694-31-6)

9.56±0.02 (V) PE 3510

IBr +

(

2 II 3/2) IBr ** (RN-CAS Registry Number 7789-33-5)

(HB-Threshold value approximately corrected for hot bands)

9.790±0.004 PE 3870

IBr +

(

2 II 1/2) IBr ** (RN-CAS Registry Number 7789-33-5)

(HB-Threshold value approximately corrected for hot bands)

10.386±0.004 PE 3870

Rbr Rbl ** (RN-CAS Registry Number 7790-29-6)

(HB-Threshold value approximately corrected for hot bands)

7.308 ±0.03 PI 3536

320
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other appearance Method Ref. products potential

(eV)

Rb2 I + Rb2 I2 I 7.674 PI 3536

(RN-CAS Registry Number 12532-37-5)

(TV-Threshold value approximately corrected to 0°K)

Agl + Agl ** ~8.4 PI 3536

(RN-CAS Registry Number 7783-96-2)

cdi2fn3/2g) Cdl2 ** 9.5 (V) PE 3963

(RN-CAS Registry Number 7790-80-9)

cdi2t

2 n3/2g) Cdl2 ** 9.57±0.05 (V) PE 3833

(RN-CAS Registry Number 7790-80-9)

cdi2t

2 n3/2ll) Cdl2 ** 10.0 (V) PE 3963

(RN-CAS Registry Number 7790-80-9)

cdi2t

2 ni/ig/rijj) Cdl2 ** 10. 11 ±0.05 (V) PE 3833

(RN-CAS Registry Number 7790-80-9)

cdi2t

2 n 1/2g) Cdl2 ** 10.2 (V) PE 3963

(RN-CAS Registry Number 7790-80-9)

cdi2t

2 n 1/2o) Cdl2 ** 10.4 (V) PE 3963

(RN-CAS Registry Number 7790-80-9)

Cdl2t

2 2„) Cdl2 ** 1 1 . 1 5 =±0.05 (V) PE 3833

(RN-CAS Registry Number 7790-80-9)

CdI2t

2 2J Cdl2 ** 11.2 (V) PE 3963

Cdl2f2g

) (RN-CAS Registry Number 7790-80-9)

Cdl2 ** 12.10±0.05 (V) PE 3833

Cdl2f2g

) (RN-CAS Registry Number 7790-80-9)

Cdl2 ** 12.3 (V) PE 3963

(RN-CAS Registry Number 7790-80-9)

InI+(X22) Ini ** 8.50 PE 3640

InI +

(

2 n3/2) (RN-CAS Registry Number 13966-94-4)

Ini ** 8.78 PE 3640

InI +

(

2 n,/2) (RN-CAS Registry Number 13966-94-4)

Ini ** 9.46 PE 3640

InI +

(

2 2)

(RN-CAS Registry Number 13966-94-4)

Ini ** 11.89 PE 3640

(RN-CAS Registry Number 13966-94-4)

12.127+0.002 TPE 3525

13.434+0.002 TPE 3525

12.125+0.004 PEN 3541

12.09+0.03 EDD 3626

>12.0 PE 3943 ~ 14.6 PE 3943

<15.3 PE 3943

Xe+

(

2 P3/2) Xe+

(

2 P 1/2) Xe +

(

2P3/2) Xe +

Xe ** (RN-CAS Registry Number 7440-63-3)

Xe ** (RN-CAS Registry Number 7440-63-3)

Xe ** (RN-CAS Registry Number 7440-63-3)

Xe ** (RN-CAS Registry Number 7440-63-3)

XeOF4+ XeOF^

XeOF^

XeOF4 ** (RN-CAS Registry Number 13774-85-1)

XeOF4 ** (RN-CAS Registry Number 13774-85-1)

XeOF4 ** (RN-CAS Registry Number 13774-85-1)

321
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance Method Ref.

potential

(eV)

XeOF^ XeOF4 ** <16.2 PE 3943

(RN-CAS Registry Number 13774-85-1)

XeOF* XeOF4 ** (RN-CAS Registry Number 13774-85-1)16.90 (V) PE 3943

XeOF* XeOF4 ** (RN-CAS Registry Number 13774-85-1)

18.10 PE 3943

XeOF* XeOF4 ** (RN-CAS Registry Number 13774-85-1) ~ 19.3 PE 3943

XeOF* XeOF4 ** (RN-CAS Registry Number 13774-85-1)<20.3 PE 3943

Cs + CsOH OH ~10 El 3461

(RN-CAS Registry Number 21351-79-1)

Cs + CsN03 (RN-CAS Registry Number XXXXX-XX-X)

10.50±0.5 El 4100

Cs +3 Cs+2 ** (RN-CAS Registry Number 18933-37-4)

37.3±~2 SEQ 3568

Cs +4 Cs+3 ** (RN-CAS Registry Number 18933-38-5)

50± ~2 SEQ 3568

Cs+5 Cs+4 ** (RN-CAS Registry Number XXXXX-XX-X)

62±~2 SEQ 3568

Cs+6 Cs+5 ** (RN-CAS Registry Number XXXXX-XX-X)

74± ~2 SEQ 3568

Cs +7 Cs+6 ** (RN-CAS Registry Number XXXXX-XX-X)86± ~2 SEQ 3568

Cs+8 Cs+7 ** (RN-CAS Registry Number XXXXX-XX-X)

1 14± — 2 SEQ 3568

Cs +9 Cs+8 ** (RN-CAS Registry Number XXXXX-XX-X)

130±~2 SEQ 3568

Cs +I° Cs+9 ** (RN-CAS Registry Number XXXXX-XX-X)

-250 SEQ 3568

Cs2+ Cs2 ** (RN-CAS Registry Number 12184-83-7)3.60-3.71 PI 3772

Cs2N03+ (CsN03)2 (RN-CAS Registry Number XXXXX-XX-X)

14.1± 1.0 El 4100

CsF + CsF ** (RN-CAS Registry Number 13400-13-0)

8.80±0.10 PE 3958

CsCl + CsCl ** (RN-CAS Registry Number 7647-17-8)7.84+0.05 PE 3958

322
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

CsBr+ CsBr ** 7.46+0.05 PE 3958

(RN-CAS Registry Number 7787-69-1)

Csi+

(

2n3/2) Csl ** 7.10+0.05 PE 3958

(RN-CAS Registry Number 7789-17-5)

csi +

(

2 n l/2) Csl ** 8.00+0.10 PE 3958

(RN-CAS Registry Number 7789-17-5)

Ba+ Ba ** ~5.2 El 3486

(RN-CAS Registry Number 7440-39-3)

Ba+ BaO O 10.95±0.18 El 3821

(RN-CAS Registry Number 1304-28-5)

(HB-Threshold value approximately corrected for hot bands)

Ba+2 Ba ** 12 El 3486

(RN-CAS Registry Number 7440-39-3)

Ba+3

Ba+3

Ba ** (RN-CAS Registry Number 7440-39-3)

Ba+2 ** (RN-CAS Registry Number 22541-12-4)

53 El 3486

36.3 +3 SEQ 3568

Ba+4 Ba+3 ** 55±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

Ba+5 Ba+4 ** 67±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

Ba+6 Ba+5 ** 80±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

Ba+7 Ba+6 ** 94±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

Ba+8 Ba+7 ** 105 ±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

Ba+9 Ba+8 ** 141 ±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

Ba+1° Ba+9 ** 167±3 SEQ 3568

(RN-CAS Registry Number XXXXX-XX-X)

BaO+

La+

La+

La+

BaO ** (RN-CAS Registry Number 1304-28-5)

La ** (RN-CAS Registry Number 7439-91-0)

La ** (RN-CAS Registry Number 7439-91-0)

LaF3 (RN-CAS Registry Number 13709-38-1)

323

6.97+0.12 El 3821

5.0±0.5 El 3600

6.9+1.

2

El 3978

26 El 3456
Table of Ion Energetics Measurements—Continued

Ionization or Ion Reactant Other

products

appearance

potential

(eV)

Method Ref.

La" LaF3 (RN-CAS Registry Number 13709-38-1)

26.9 El 3466

LaC + LaC2 C?

(RN-CAS Registry Number 12071-15-7)

14.9±0.5 El 3457

LaC2+ LaC2 ** (RN-CAS Registry Number 12071-15-7)5.4±0.3 El 3457

LaC3+ LaC3 ** (RN-CAS Registry Number 12602-63-0)6.8±0.5 El 3457

LaC4+ LaC4 ** (RN-CAS Registry Number 12603-31-5)

4.7±0.5 El 3457

LaF + LaF3 (RN-CAS Registry Number 13709-38-1)

16 El 3456

LaF+ LaF3 (RN-CAS Registry Number 13709-38-1)18.5 El 3466

LaF2+ LaF3 (RN-CAS Registry Number 13709-38-1)9 El 3456

LaF2+ LaF3 (RN-CAS Registry Number 13709-38-1)

11.8 El 3466

La2 F^ (LaF3)2 (RN-CAS Registry Number 12592-31-3)12.4 El 3466

LaSe + LaSe ** (RN-CAS Registry Number 12031-31-1)

6.0±0.5 El 3600

LaRh + LaRh ** (RN-CAS Registry Number 12142-68-6)

7.7± 1.0 El 3978

Ce + Ce ** (RN-CAS Registry Number 7440-45-1)

5.6±0.5 El 3969

Ce + Ce ** (RN-CAS Registry Number 7440-45-1)

5.7±0.3 El 3597

Ce + Ce? ** (RN-CAS Registry Number 7440-45-1)

5.9±0.4 El 3471

Ce + Ce ** (RN-CAS Registry Number 7440-45-1)

5.9±0.4 El 3468

Ce + Ce ** (RN-CAS Registry Number 7440-45-1)

5.9±0.6 El 3621

Ce + Ce ** (RN-CAS Registry Number 7440-45-1)

6.0±0.5 El 3986

Ce + Ce ** (RN-CAS Registry Number 7440-45-1)

6.0±0.5 El 3473

Ce + CeO

(RN-CAS-Registry Number 12014-74-3)

-13.5 El 4061

Ce + CeF3 (RN-CAS Registry Number 7758-88-5)

324

25.2 El 3607
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Ce + Cel3 31 (RN-CAS Registry Number 7790-87-6)

17.7±0.5 El 3820

Ce+2 Ce? ** (RN-CAS Registry Number 7440-45-1)

22.7±0.8 El 3471

Ce +3 Ce+2 ** (RN-CAS Registry Number 16679-11-1)

20.197±0.003 S 3744

Ce+4 Ce+ 3 ** (RN-CAS Registry Number 18923-26-7)

36.758±0.005 S 3744

Ce2+ Ce2 ** (RN-CAS Registry Number 12595-88-9)

5.9+0.4 El 3471

C2Ce + C2 Ce ** (RN-CAS Registry Number 12012-32-7)

5.6±0.4 El 3597

CeC2+ CeC2 ** (RN-CAS Registry Number 12012-32-7)

6.2±0.5 El 3969

CeN+ CeN ** (RN-CAS Registry Number 25764-08-3)

5.8+0.6 El 3469

CeO+ CeO ** (RN-CAS-Registry Number 12014-74-3)

5.2±0.2 El 4061

CeO+ CeO ** (RN-CAS Registry Number 12014-74-3)

5.3+0.5 El 3986

CeO+ CeO ** (RN-CAS Registry Number 12014-74-3)6.0±0.5 El 3473

CeO+ Ce02 (RN-CAS-Registry Number 1306-38-3)

~11 El 4061

CeO+ Ce02? ** (RN-CAS Registry Number 1306-38-3)

13± 1 El 3986

Ce02+ Ce02 ** (RN-CAS Registry Number 1306-38-3)

9.7±0.5 El 3986

Ce02+ Ce02 ** (RN-CAS-Registry Number 1306-38-3)

10.3±0.2 El 4061

Ce202+ (CeO)2 ** (RN-CAS Registry Number 12258-89-8)

8± 1 El 3986

CeF + CeF3 (RN-CAS Registry Number 7758-88-5)

17.2 El 3607

CeF2+ CeF3 (RN-CAS Registry Number 7758-88-5)

13.5 El 3607

CeF+ CeF3 ** (RN-CAS Registry Number 7758-88-5)

11.4 El 3607

325
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Ce2 F5+ Ce2 F6

(RN-CAS Registry Number 37346-47-7)

13.1 El 3607

CSiCe + CSiCe ** ~9

(RN-CAS Registry Number 51257-45-5)

El 3969

CeS + CeS ** 6.0±0.6 El 3621

(RN-CAS Registry Number 12014-82-3)

CeS2+ CeS2 ** 1 3.5 ± 1 El 3621

(RN-CAS Registry Number 12133-58-3)

CePd + CePd ** 6.2±0.5 El 3597

(RN-CAS Registry Number 12292-14-7)

Cel + Cel3 21 13.6±0.5 El 3820

(RN-CAS Registry Number 7790-87-6)

Cel +2 Cel3 28 ±1 El 3820

(RN-CAS Registry Number 7790-87-6)

Cel2+ Cel3 I 9.7±0.5 El 3820

(RN-CAS Registry Number 7790-87-6)

Cel3+ Cel3 ** 9.6±0.5 El 3820

(RN-CAS Registry Number 7790-87-6)

Pr +Prl3 31 17.0±0.2 El 3820

(RN-CAS Registry Number 13813-23-5)

Pr +3 Pr +2 ** 21.624±0.003 S 3744

(RN-CAS Registry Number 14700-75-5)

Pr +4 Pr +3 ** 38.981 ±0.025 S 3744

(RN-CAS Registry Number 22541-14-6)

Pr + 5 Pr

+4 ** 57.45±0.05 S 3563

(RN-CAS Registry Number 20334-17-2)

Prl + Prl3 21 12.9±0.2 El 3820

(RN-CAS Registry Number 13813-23-5)

Prl2+

Prl3 I 10.0±0.2 El 3820

(RN-CAS Registry Number 13813-23-5)

Prl3+ Prl3 ** 9.2±0.2 El 3820

(RN-CAS Registry Number 13813-23-5)

Nd + Nd ** 6.5 El 4030

(RN-CAS Registry Number 7440-00-8)

Nd + NdCl3 3C1? 20.9 ± 1.0 El 3802

(RN-CAS Registry Number 10024-93-8)

326
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Nd+ NdBr3 (RN-CAS Registry Number 13536-80-6)

16.9+0.7 El 3976

Nd+ Ndl3 31 (RN-CAS Registry Number 13813-24—6)

15.9+0.2 El 3820

Nd+3 Nd+2 ** (RN-CAS Registry Number 16727-26-7)

22.14+0.30 S 3744

Nd+4 Nd+3 ** 40.42 ±0.30 S 3744

(RN-CAS Registry Number 14913-52-1)

NdCl+ NdCl3 2C1?

(RN-CAS Registry Number 10024-93-8)

17.3 + 1.0 El 3802

NdCl^ NdCl3 Cl?

(RN-CAS Registry Number 10024-93-8)

11.9+0.3 El 3802

NdCl3+ NdCl3 ** (RN-CAS Registry Number 10024-93-8)

<11.4 El 3802

NdBr2+ NdBr3 (RN-CAS Registry Number 13536-80-6)

10.5+0.7 El 3976

Ndl+ Ndl3 21 (RN-CAS Registry Number 13813-24-6)

13.6+0.5 El 3820

Ndl2+ Ndl3 I (RN-CAS Registry Number 13813-24-6)9. 3+0.5 El 3820

Ndl3+ Ndl3 ** 9.2±0.5 El 3820

(RN-CAS Registry Number 13813-24—6)

Pm+3 Pm+2 ** 22.42+0.41 S 3744

(RN-CAS Registry Number 24151-74-4)

Pm+4 Pm+3 ** (RN-CAS Registry Number 22541-16-8)

41.09+0.32 S 3744

Sm“ Sml2 (RN-CAS Registry Number 32248-43-4)

12.5 El 3820

Sm+3 Sm+2 ** (RN-CAS Registry Number 16396-66-0)

23.45+0.30 S 3744

Sm+4 Sm+3 ** 41.47+0.43 S 3744

(RN-CAS Registry Number 22541-17-9)

Sml + Sml2 9.2 El 3820

(RN-CAS Registry Number 32248-43-4)

327
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Smlf Sml2 ** (RN-CAS Registry Number 32248-43-4)

8.7 El 3820

Eu + Eu ** (RN-CAS Registry Number 7440-53-1)

' 5.6±0.5 El 3611

Eu + Eu ** (RN-CAS Registry Number 7440-53-1)

5.9±0.2 El 3459

Eu + EuI2 (RN-CAS Registry Number 22015-35-6)

12.45±0.2 El 3612

Eu +3 Eu + 2 ** (RN-CAS Registry Number 16910-54-6)

24.71 ±0.32 S 3744

Eu+4 Eu +3 ** (RN-CAS Registry Number 22541-18-0)

42.65±0.32 S 3744

Eu2+ Eu2 ** (RN-CAS Registry Number 12596-00-8)

6.3 ± 1 .0 El 4012

EuC2+ EuC2 ** (RN-CAS Registry Number 12127-44-5)

6.6±0.7 El 3611

EuCN+ EuCN ** (RN-CAS Registry Number 50647-38-6)

5.5 ± 1.5 El 3798

EuAg + EuAg ** (RN-CAS Registry Number 12249-50-2)

6.1 ±0.5 El 4012

Eul + EuI2 (RN-CAS Registry Number 22015-35-6)9.90±0.2 El 3612

EuI2+ EuI2 ** (RN-CAS Registry Number 22015-35-6)8.85±0.2 El 3612

Gd+ GdCl3 3C1?

(RN-CAS Registry Number 10138-52-0)

20.9 ± 1.0 El 3802

Gd+ Gdl3 31 (RN-CAS Registry Number 13572-98-0)

17.0±0.2 El 3820

Gd +3 Gd +2 ** (RN-CAS Registry Number 18195-96-5)

20.38±0.21 S 3744

Gd +4 Gd +3 ** (RN-CAS Registry Number 22541-19-1)

44.03±0.35 S 3744

GdCl + GdCl3 2C1?

(RN-CAS Registry Number 10138-52-0)

1 6.5 ± 1.0 El 3802

GdCl2+ GdCl3 Cl?

(RN-CAS Registry Number 10138-52-0)

1 1.9±0.3 El 3802

328
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

NaGdCl3+ NaGdCl3 (RN-CAS Registry Number XXXXX-XX-X)

10.1 ±0.5 El 3802

Gdl + Gdl3 21 13.5±0.2 El 3820

(RN-CAS Registry Number 13572-98-0)

Gdl2+ Gdl3 I 10.1 ±0.2 El 3820

(RN-CAS Registry Number 13572-98-0)

Gdl3+ Gdl3 ** 9.2±0.2 El 3820

(RN-CAS Registry Number 13572-98-0)

Tb+ Tbl3 31 17.6±0.2 El 3820

(RN-CAS Registry Number 13813-40-6)

Tb +3 Tb+2 ** 21.98±0.21 S 3744

(RN-CAS Registry Number 18195-97-6)

Tb+4 Tb +3 ** 39.84±0.35 S 3744

(RN-CAS Registry Number 22541-20-4)

Tbl + Tbl3 21 13.7±0.2 El 3820

(RN-CAS Registry Number 13813-40-6)

Tbl2+ Tbl3 I 10.5±0.2 El 3820

(RN-CAS Registry Number 13813-40-6)

Tbl3+ Tbl3 ** (RN-CAS Registry Number 13813-40-6)

9.5±0.2 El 3820

Dy+ Dyl3 31 (RN-CAS Registry Number 15474-63-2)

16.4±0.2 El 3820

Dy+3 Dy

+ 2 ** (RN-CAS Registry Number 14701-44-1)

22.83+0.32 S 3744

Dy+4 Dy+3 ** 41.56+0.35 S 3744

(RN-CAS Registry Number 22541-21-5)

Dyl + Dyl3 21 (RN-CAS Registry Number 15474-63-2)

13.1 ±0.2 El 3820

Dyl2+ Dyl3 I (RN-CAS Registry Number 15474-63-2)

10.5±0.2 El 3820

Dyl3+ Dyl3 ** (RN-CAS Registry Number 15474-63-2)

9.6±0.2 El 3820

Ho+ Ho ** 5.8±0.2 El 3440

(RN-CAS Registry Number 7440-60-0)

329
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Ho + HoI3 31 (RN-CAS Registry Number 13813-41-7)

16.7±0.2 El 3820

Ho+3 Ho +2 ** 22.84±0.10 S 3744

(RN-CAS Registry Number 16468-44-3)

Ho+4 Ho+3 ** 42.51 ±0.35 S 3744

(RN-CAS Registry Number 22541-22-6)

Ho2+ Ho2 ** 6.0± 1.0 El 3440

(RN-CAS Registry Number 12596-28-0)

HoAg+ HoAg ** 5.7±0.6 El 3440

(RN-CAS Registry Number 12002-74-3)

HoI + HoI3 21 13.2±0.2 El 3820

(RN-CAS Registry Number 13813-41-7)

HoI2+ HoI3 I 10.4±0.2 El 3820

(RN-CAS Registry Number 13813-41-7)

HoI3+ HoI3 ** 9.2±0.2 El 3820

(RN-CAS Registry Number 13813-41-7)

Er+ Erl3 31 16.2±0.2 El 3820

(RN-CAS Registry Number 13813-42-8)

Er +3 Er+2 ** 22.74±0.10 S 3744

(RN-CAS Registry Number 18195-92-1)

Er +4 Er +3 ** 42.66±0.20 S 3744

(RN-CAS Registry Number 18472-30-5)

Erl + Erl3 21 (RN-CAS Registry Number 13813-42-8)

1 3.3 ±0.2 El 3820

Erl2+ Erl3 I (RN-CAS Registry Number 13813-42-8)

10.2±0.2 El 3820

Erl3+ Erl3 ** (RN-CAS Registry Number 13813-42-8)

9.0±0.2 El 3820

Tm+ Tm ** (RN-CAS Registry Number 7440-30-4)

5.7 El 3460

Tm+ TmBr3 (RN-CAS Registry Number 14456-51-0)

17.5±0.7 El 3976

Tm+3 Tm +2 ** (RN-CAS Registry Number 16910-52-4)

23.68±0.10 S 3744

330
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Tm+4 Tm+3 ** (RN-CAS Registry Number 22541-23-7)

42.69±0.30 S 3744

TmBr^ TmBr3 (RN-CAS Registry Number 14456-51-0)

11.1 ±0.7 El 3976

TmBr^ TmBr3 ** (RN-CAS Registry Number 14456-51-0)

9.6±0.7 El 3976

Yb+ Yb ** (RN-CAS Registry Number 7440-64-4)

6.3+0.3 El 4105

Yb+ YbCl2 (RN-CAS Registry Number 13874-77-6)

15.05±0.26 El 3614

Yb+ YbBr3? (RN-CAS Registry Number 13759-89-2)

14.7+0.7 El 3976

Yb+2 Yb+ ** (RN-CAS Registry Number 20205-78-1)

12.184+0.006 S 3974

Yb+3 Yb+2 ** (RN-CAS Registry Number 22541-96-4)

25.03 ±0.02 S 3744

Yb+4 Yb+3 ** (RN-CAS Registry Number 18923-27-8)

43.74+0.30 s 3744

Yb2+ Yb2 ** (RN-CAS Registry Number 12771-79-8)

4-5 El 4105

YbCl+ YbCl2 (RN-CAS Registry Number 13874-77-6)

10.70+0.21 El 3614

YbCl2+ YbCl2 ** (RN-CAS Registry Number 13874-77-6)

9.73+0.21 El 3614

YbBr+ YbBr2? (RN-CAS Registry Number 25502-05-0)

10.0+0.7 El 3976

YbBr2+ YbBr3? (RN-CAS Registry Number 13759-89-2)

10.0+0.7 El 3976

Lu+ Lu ** (RN-CAS-Registry Number 7439-94-3)

5.425889+0.00001 S 4060

Lu+ Lu ** (RN-CAS Registry Number 7439-94-3)

5. 3+0.3 El 3618

Lu+4 Lu+3 ** (RN-CAS Registry Number 22541-24-8)

45.20+0.025 PE 3899

LuC2+ LuC2 ** (RN-CAS Registry Number 12175-89-2)

7.8+1 El 3618

331
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

LuC4+ LuC4 ** (RN-CAS Registry Number 37215-84-2)

1 1.1 ± 1 El 3618

Hr4 Hf+3 ** (RN-CAS Registry Number 36756-51-1)

33.319±0.025 S 3744

Ta +5 Ta +4 ** (RN-CAS Registry Number 16044-71-6)

48.4±0.

S 4101

TaF3+ TaF4? F?

(RN-CAS Registry Number 15192-46-8)

22.0 El 3783

TaF4+ TaF4? ** (RN-CAS Registry Number 15192-46-8)

14.6 El 3783

Ta2 F9+ Ta2 F9? ** (RN-CAS Registry Number XXXXX-XX-X)

14.9 El 3783

Ta3 F,+

4 Ta3 F14? ** (RN-CAS Registry Number XXXXX-XX-X)

14.0 El 3783

TaCl2+ TaCl5 (RN-CAS Registry Number 7721-01-9)

20.3 El 3783

TaCl3+ TaCl5 (RN-CAS Registry Number 7721-01-9)

15.2 El 3783

TaCl4+ TaCl5 (RN-CAS Registry Number 7721-01-9)

10.9 El 3783

c6H18 w+ (CH3 )6W

(RN-CAS Registry Number 36133-73-0)

9.8 PE 3663

c6o6w+ W(CO)6 ** (RN-CAS Registry Number 14040-11-0)

8.30±0.02 (V) PE 3979

C10H5 NO5 W+ C5 H5 NW(CO)5 ** (OC-6-22)-Pentacarbonyl(pyridine)tungsten)

(RN-CAS Registry Number 14586-49-3)

7.53±0.05 El 3498

c,,h7 no5 w+ C5 H4N(CH3 )W(CO)5 ** (Pentacarbonyl(4-methylpyridine)tungsten)

(RN-CAS Registry Number 17000-14-5)

7.46±0.05 El 3498

c12 h9 no5 w+ C5 H3 N(CH3)2 W(CO)5 ** 7.43±0.05

((OC-6-22)-Pentacarbonyl(2,6-dimethylpyridine)tungsten)

(RN-CAS Registry Number 36252-39-8)

El 3498

c,,h4n2o5 w+ C5 H4N(CN)W(CO)5 ** 7.65 ±0.05

((OC-6-22)-Pentacarbonyl(2-pyridinecarbonitrile-7V1 )tungsten)

(RN-CAS Registry Number 36252-42-3)

El 3498

332
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

c12h36n6p2 w+ (((CH3)2 N)3 P)2W(CO)4 4CO

(RN-CAS Registry Number 19976-86-4)

10.7±0.05 El 3952

c14h36n6o2 p2 w+ (((CH3)2 N)3 P)2 W(CO)4 2CO

(RN-CAS Registry Number 19976-86-4)

12.2±0.05 El 3952

c15 h36n6o3 p2 w+ (((CH3 ) 2N)3 P)2W(CO)4 CO

(RN-CAS Registry Number 19976-86-4)

10.3 ±0.05 El 3952

c16h36n6o4p2w+ (((CH3) 2 N)3 P)2 W(CO)4 (RN-CAS Registry Number 19976-86-4)

5.5±0.05 El 3952

WC1+ WC16 (RN-CAS Registry Number 13283-01-7)

22.9 El 3783

WC12+ wci6 (RN-CAS Registry Number 13283-01-7)

19.4 El 3783

WC13+ wci6 (RN-CAS Registry Number 13283-01-7)

15.4 El 3783

WC14+ wci6 (RN-CAS Registry Number 13283-01-7)11.4 El 3783

WC14+ WOCl4 (RN-CAS Registry Number 13520-78-0)

16.0+1 El 3604

WC15+ wci6 (RN-CAS Registry Number 13283-01-7)

10.9 El 3783

WC16+ WC16 ** (RN-CAS Registry Number 13283-01-7)

9.5 El 3783

WOCl3+ WOCl4 (RN-CAS Registry Number 13520-78-0)

10.0+0.5 El 3604

WOCl4+ WOCl4 ** (RN-CAS Registry Number 13520-78-0)

10.8+0.5 El 3604

WS2C1 + WS2C12 (RN-CAS Registry Number 24664-20-8)

12.6+0.5 El 3604

WS2 C12+ WS2C12 ** (RN-CAS Registry Number 24664-20-8)

10.5+0.5 El 3604

WSC13+ WSC14 (RN-CAS Registry Number 25127-53-1)

9.5±0.5 El 3604

WSC14+ WSC14 ** (RN-CAS Registry Number 25127-53-1)

10.4± 1 El 3604

333
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

woscr WOSCl2 (RN-CAS Registry Number XXXXX-XX-X)1 3.8 ±0.5 El 3604

WOSCl2+ WOSCl2 ** (RN-CAS Registry Number XXXXX-XX-X)

10.6±0.5 El 3604

WBr2+ WOBr4 (RN-CAS Registry Number 13520-77-9)21.4±0.5 El 3450

WBr3+ WOBr4 (RN-CAS Registry Number 13520-77-9)

18.1 ±0.5 El 3450

WOBr+ W02 Br2 (RN-CAS Registry Number 13520-75-7)20.0 ±0.8 El 3450

WOBr+ WOBr4 (RN-CAS Registry Number 13520-77-9)

18.1 ±0.8 El 3450

W02 Br + W02 Br2 (RN-CAS Registry Number 13520-75-7)

13.0±0.4 El 3450

WOBr2+ WOBr4 (RN-CAS Registry Number 13520-77-9)14.4±0.5 El 3450

W02 Br2+ W02 Br2 ** (RN-CAS Registry Number 13520-75-7)

1 1.4±0.2 El 3450

WOBr3+ WOBr4 (RN-CAS Registry Number 13520-77-9)10.3±0.2 El 3450

WOBr3+ WOBr4 (RN-CAS Registry Number 13520-77-9)

10.5±0.5 El 3604

WOBr4+ WOBr4 ** (RN-CAS Registry Number 13520-77-9)

10.3±0.3 El 3450

WOBr4+ WOBr4 ** (RN-CAS Registry Number 13520-77-9)

1 1 .5 ±0.5 El 3604

wo2 i + wo2 i 2 (RN-CAS Registry Number 14447-89-3)

12.5±0.5 El 3451

wo2 i 2+ wo2

i 2 ** (RN-CAS Registry Number 14447-89-3)10.4±0.4 El 3451

ReO ' Re03 (RN-CAS Registry Number 1314-28-9)

(TR-Other product(s) thermochemically reasonable)

~ 18 El 4016

ReOz+ ReOs (RN-CAS Registry Number 1314-28-9)

(TR-Other product(s) thermochemically reasonable)

14.4± 1.0 El 4016

ReOz+ Re207 (RN-CAS Registry Number 1314-68-7)

21.9± 1.0 El 4016

334
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Re03+ Re03 ** (RN-CAS Registry Number 1314-28-9)

(TR-Other product(s) thermochemically reasonable)

12.5±0.4 El 4016

Re03+ Re207 (RN-CAS Registry Number 1314-68-7)

16.2±0.5 El 4016

Re03+ Re03 Cl

(RN-CAS Registry Number 7791-09-5)

15.6+0.5 El 3604

Re2Os+ Re207 (RN-CAS Registry Number 1314—68-7)

17.5+0.2 El 4016

Re206+ Re207 (RN-CAS Registry Number 1314-68-7)

16.2+0.5 El 4016

Re207+ Re207 ** (RN-CAS Registry Number 1314-68-7)

12.7+0.2 El 4016

C5 H05 Re+ HRe(CO)5 ** (RN-CAS Registry Number 16457-30-0)

8.86+0.02 (V) PE 3827

ReF6+ ReF6 ** (RN-CAS Registry Number 10049-17-9)

7.99 S 3565

C5H3 05 SiRe + SiH3 Re(CO)5 ** (RN-CAS Registry Number 40628-33-9)

8.9 ±0. 1 (V) PE 3827

ReCl4+ ReOCl4 (RN-CAS Registry Number 13814-76-1)16.5+0.5 El 3604

ReOzCl + Re03 Cl

(RN-CAS Registry Number 7791-09-5)

12.3+0.5 El 3604

ReOCl3+ ReOCl4 (RN-CAS Registry Number 13814-76-1)

12.3±0.5 El 3604

ReOCl4+ ReOCl4 ** (RN-CAS Registry Number 13814-76-1)

10.7+0.5 El 3604

C5H3 05 GeRe+ GeH3 Re(CO)5 ** (RN-CAS Registry Number 30012-26-1)

8.9+0. 1 (V) PE 3827

Re03 I + Re03 I ** (RN-CAS Registry Number 39327-80-5)

10.9+0.5 El 4013

BaReO^ Ba(Re04)2? (RN-CAS Registry Number XXXXX-XX-X)

13.4+0.5 El 4108

C12H14Os+ (C5 H4CH3)2Os

(Osmocene, 1 , 1 '-dimethyl-)

(RN-CAS Registry Number 40672-07-9)

6.93 (V) PE 3688

335
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Os04fT2 ) 0s04 ** (RN-CAS Registry Number 20816-12-0)

12.320 PE 3836

0s04+ 0s04 ** (RN-CAS Registry Number 20816-12-0)

12.39 PE 3838

Os04t

! T,) 0s04 ** (RN-CAS Registry Number 20816-12-0)

13.138 PE 3836

0s04t

2 E) Os04 ** (RN-CAS Registry Number 20816-12-0)

13.502 PE 3836

Os04t

2A,) Os04 ** (RN-CAS Registry Number 20816-12-0)

14.543 PE 3836

Os04fT2) Os04 ** (RN-CAS Registry Number 20816-12-0)

16.31 (V) PE 3836

OsOCl3+ OsOCl4 (RN-CAS Registry Number 14998-32-4)

12.4±0.5 El 3604

OsOCl4+ OsOCl4 ** (RN-CAS Registry Number 14998-32-4)

1 1 .3 ±0.5 El 3604

C7 H704 Ir + (CH3 COCHCOCH3 )Ir(CO)2 ** (Dicarbonyl(2,4-pentanedionato)iridium)

(RN-CAS Registry Number 14023-80-4)

8.6±0.1 El 3497

C7 H04F6Ir + (CF3 COCHCOCF3)Ir(CO)2 ** 8.85+0.05

(Dicarbonyl(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato)iridium)

(RN-CAS Registry Number 14049-69-5)

El 3497

Au 4" Au ** (RN-CAS Registry Number 7440-57-5)

9.21 ±0.05 RPD 3745

Au + Au ** (RN-CAS Registry Number 7440-57-5)

8.5±0.8 El 3978

Au + Au ** (RN-CAS Registry Number 7440-57-5)

9.0±0.5 El 3473

>cNJ+ Au2 ** (RN-CAS Registry Number XXXXX-XX-X)

9.5+0.3 El 4014

Au2+ Au2 ** (RN-CAS Registry Number 12187-09-6)

9.5±0.3 El 4005

Au^ Au2 ** (RN-CAS Registry Number 12187-09-6)

9.7±0.4 El 3468

AuB + AuB ** (RN-CAS Registry Number 12408-81-0)

8.7±0.5 El 3468

AuB + AuBO?

(RN-CAS Registry Number 12588-90-8)

14.5±0.5 El 3473

AuBO 4" AuBO ** (RN-CAS Registry Number 12588-90-8)9.7+0.2 El 3473

AuAl + AuAl ** (RN-CAS Registry Number XXXXX-XX-X)

7.6+0.3 El 4014

336
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

AuAl+ AuAl ** (RN-CAS Registry Number 12250-38-3)

7.6±0.3 El 4005

AuAl + AuAl ** (RN-CAS Registry Number 12250-38-3)

7.8±0.3 El 3440

AuAl + AuAl ** (RN-CAS Registry Number 12250-38-3)

9.0± 1.0 El 3796

AuAl^ AuA1 2 ** 6.2± 1.0 El 3966

(RN-CAS Registry Number 12004-03-4)

Au2A1 + Au2A1 ** 7.7±1.0 El 3966

(RN-CAS Registry Number 12250-39-4)

AuGe+ AuGe ** 7.7 El 3775

(RN-CAS Registry Number 12256-41-6)

AuCe+ AuCe ** 6.0±0.3 El 3468

(RN-CAS Registry Number 12408-82-1)

AuHo+ AuHo ** 6.2 ±0.5 El 3440

(RN-CAS Registry Number 12044-80-3)

Hg+

(

2 S 1/2) Hg ** 10.4 PE 3672

(RN-CAS Registry Number 7439-97-6)

Hg+

(

2 D5/2) Hg ** 14.8 PE 3672

Hg+

(

2 S 1/2) (RN-CAS Registry Number 7439-97-6)

Hg ** 10.487±0.005 PEN 3541

Hg+

(

2 D5/2) (RN-CAS Registry Number 7439-97-6)

Hg ** 14.907±0.015 PEN 3541

Hg+

(

2 D3/2) (RN-CAS Registry Number 7439-97-6)

Hg ** 16.787±0.015 PEN 3541

Hg+

(

2 P3/2) (RN-CAS Registry Number 7439-97-6)

Hg ** 18.050±0.050 PEN 3541

(RN-CAS Registry Number 7439-97-6)

Hg+ Hg 10.47±0.05 RPD 3745

(RN-CAS Registry Number 7439-97-6)

Ci 2H10Hg (C6H5)2Hg ** 8.30±0.03

(Mercury, diphenyl-)

(RN-CAS-Registry Number 587-85-9)

PI 4055

HgCl+ HgCl2 ** (RN-CAS Registry Number 7487-94-7)

11.5 (V) PE 3963

C3 H5 ClHg + CH2 = CHCH2HgCl ** (RN-CAS Registry Number 14155-77-2)

9.35 (V) PE 3859

Ti+ tibo2 bo2 (RN-CAS Registry Number XXXXX-XX-X)

10.43±0.07 El 4096

337
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Ti+3 'pj +2 ** (RN-CAS Registry Number 14877-28-2)

29.8523 ±0.0006 S 4093

ti2+ ti2o

(RN-CAS Registry Number 1314-12-1)

1 1 .97 =±0.09 El 4096

T10 + tibo2 (RN-CAS Registry Number XXXXX-XX-X)

1 0.68 ±0. 1El 4096

ti2 o

+ ti2o ** (RN-CAS Registry Number 1314-12-1)

8.02±0.10 El 4096

TlBO + T1BO? ** (RN-CAS Registry Number XXXXX-XX-X)

1 1 .8 ±0.6 El 4096

TlBO + tibo2? ** (RN-CAS Registry Number XXXXX-XX-X)

15.02±0.23 El 4096

tibo2+ tibo2 ** (RN-CAS Registry Number XXXXX-XX-X)

9.92±0.1

El 4096

ti2 bo2+ (RN-CAS Registry Number XXXXX-XX-X)

9.17±0.10 El 4096

TlF+

(

2 2) Tjp ** (RN-CAS Registry Number 7789-27-7)

10.52 PE 3971

TiF+

(

2 n) Tip ** (RN-CAS Registry Number 7789-27-7)

11.15 PE 3971

tif +

(

2 2:) Tip ** (RN-CAS Registry Number 7789-27-7) ~ 14.05 PE 3971

ti2 f

+ (T1F)2 (RN-CAS Registry Number 31970-97-5)

9.97±0.02 PI 3971

ti2 f2+ (T1F)2 ** (RN-CAS Registry Number 31970-97-5)

9.71 ±0.02 PI 3971

Ti2 F2t

2 n a) (T1F)2 ** (RN-CAS Registry Number 31970-97-5)

9.62 PE 3971

(T1F)2 ** (RN-CAS Registry Number 31970-97-5)

13.63 PE 3971

TI2 F2t

2 IJ (T1F)2 ** (RN-CAS Registry Number 31970-97-5)

17.07 PE 3971

(T1F)2 ** (RN-CAS Registry Number 31970-97-5) ~ 17.80 PE 3971

tici +

(

2 2) T1C1 ** 13.79 PE 3913

T1C1 + (X2 2) T1C1 ** (RN-CAS Registry Number 7791-12-0)

9.894 (V) PE 3913

T1C1 +

(

2 II) T1C1 ** (RN-CAS Registry Number 7791-12-0)

9.925 (V) PE 3536

Tici +

(

2 n) T1C1 ** (RN-CAS Registry Number 7791-12-0)

10.384 (V) PE 3913

338
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

TlAs+ TIAs ** (RN-CAS Registry Number 12006-09-6)

TlBr+

(

2 II) TIBr ** (RN-CAS Registry Number 7789-40-4)

TlBr+

(

22) TIBr ** (RN-CAS Registry Number 7789-40-4)

Ionization or appearance Method Ref.

potential

(eV)

9± 1 El 3947

9.832 (V) PE 3913

13.57 PE 3913

Tn+ Til ** (RN-CAS Registry Number 7790-30-9)

(HB-Threshold value approximately corrected for hot bands)

•ni +

(

2z 1 /2, 2 n3/2) tii

(RN-CAS Registry Number 7790-30-9)

Tii+ TII ** (RN-CAS Registry Number 7790-30-9)

ni+

(

2 n) tii ** (RN-CAS Registry Number 7790-30-9)

TH+* TII ** (RN-CAS Registry Number 7790-30-9)

T1I +

(

2:S) TII ** (RN-CAS Registry Number 7790-30-9)

TH+* TII ** (RN-CAS Registry Number 7790-30-9)

Pb+4 Pb+3 ** (RN-CAS Registry Number 18466-73-4)

8.47+0.02 PI 3536

8.47+0.02 PE 3913

8.93 (V) PE 3676

9.39 PE 3913

9.71 (V) PE 3676

13.0 PE 3913

13.52 (V) PE 3676

42.3333 ±0.0006 S 4093

C3 H9Pb+ (CH3)4Pb CH3 8.77±0.16 El 3548

(RN-CAS Registry Number 75-74-1)

C3H9Pb+ (CH3)3 CPb(CH3)3 (CH3)3 C 8.67±0.21 El 3548

(RN-CAS Registry Number 32997-03-8)

C3 H9Pb+ (CH3)3 PbPb(CH3)3 (CH3)3 Pb 9.02±0.14 El 3548

(RN-CAS Registry Number 6713-83-3)

C4H12Pb + (CH3)4Pb ** 8.50±0.04 PE 3880

(RN-CAS Registry Number 75-74-1)

C4H12Pb+ (CH3)4Pb ** 8.83+0.1 PE 3677

(RN-CAS Registry Number 75-74-1)

C4H12Pb+ (CH3 )4Pb ** 8.26±0.17 El 3548

(RN-CAS Registry Number 75-74-1)

C7H18 Pb+ (CH3)3 CPb(CH3)3 (RN-CAS Registry Number 32997-03-8)7.99+0.13 El 3548

C6H18 Pb2+ (CH3)3 PbPb(CH3)3 (RN-CAS Registry Number 6713-83-3)

7.41+0.10 El 3548

C16H44Si4Pb+ ((CH3)3SiCH2)4Pb

(RN-CAS Registry Number 18547-13-2)

8.14+0.1 (V) PE 3830

339
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

PbCl2+ PbCl2 ** (RN-CAS Registry Number 7758-95-4)

10.11 (V) PE 3650

Pbl2+ Pbl2 ** (RN-CAS Registry Number 10101-63-0)

8.86±0.03 PI 3536

Bi3+

Bi3? ** (RN-CAS Registry Number 12595-63-0)

7.6±0.3 El 3599

Bi4+ Bi4 ** (RN-CAS Registry Number XXXXX-XX-X)

7.7±0.3 El 3599

BiF3+ BiF3 ** (RN-CAS Registry Number 7787-62-4) ~ 12 El 3551

BiF4+ BiF5 (RN-CAS Registry Number 7787-62-4)

14.5-15 El 3551

Bi2 F9+ (BiF5)2? (RN-CAS Registry Number XXXXX-XX-X)

14.5-15 El 3551

GaBi + GaBi ** (RN-CAS Registry Number 12010-43-4)

7± 1 El 3608

BiTl + BiTl ** (RN-CAS Registry Number 26257-16-9)7.5±0.4 El 3949

Ac + Ac ** (RN-CAS Registry Number 7440-34-8)5. 17±0. 12 D 3875

Th + Th ** (RN-CAS Registry Number 7440-29-1)5.9±0.15 El 3962

Th + Th ** (RN-CAS Registry Number 7440-29-1)7.83±0.25 SI 4042

Th + Th ** (RN-CAS Registry Number 7440-29-1)6.08±0.12 D 3875

ThO+ ThO ** (RN-CAS Registry Number 12035-93-7)

6.1±0.15 El 3962

Th02+ ThOz ** (Rn 1314-20-1)

8.7 ±0. 1

5

El 3962

ThCl4+ ThCl4 ** (RN-CAS Registry Number 10026-08-1)

12.7 ±0.3 El 3795

ThPt + ThPt ** (RN-CAS Registry Number 12038-30-1)

8±2 El 3968

Pa + Pa ** (RN-CAS Registry Number 7440-13-3)

5.89±0.12 D 3875

340
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

U

+ U

** (RN-CAS Registry Number 7440-61-1)

6.22±0.5 S 3566

U

+ U ** (RN-CAS Registry Number 7440-61-1)

6.1 ±0.3 RPD 3557

u

+ U ** (RN-CAS Registry Number 7440-61-1)

6.8 + 1.5 El 3595

u

+ U ** (RN-CAS Registry Number 7440-61-1)

~6±0.5 El 3448

u

+ U ** (RN-CAS Registry Number 7440-61-1)

6.05±0.07 D 3875

u

+2 u+ ** (RN-CAS Registry Number 15721-70-7)

10.6±1 S 3566

uo+ UO ** (RN-CAS Registry Number 12035-97-1)

5.7+0.4 RPD 3557

uo+ UO ** (RN-CAS Registry Number 12035-97-1)

4.3± 1.5 El 3595

uo+ UO ** (RN-CAS Registry Number 12035-97-1)

~6±0.5 El 3448

uo2+ uo2 ** (RN-CAS Registry Number 1344-57-6)

5.5±0.4 RPD 3557

uo2+ uo2 ** (RN-CAS Registry Number 1344-57-6)

4.5 ± 1.5 El 3595

uo2+ uo2? ** (RN-CAS Registry Number 1344-57-6)

~6±0.5 El 3448

uo3+ uo3 ** (RN-CAS Registry Number 1344-58-7)

11.1 ±0.4 RPD 3557

uo3+ uo3 ** (RN-CAS Registry Number 1344-58-7)

9.5± 1.5 El 3595

us+ US? ** (RN-CAS Registry Number 12039-11-1)

~6±0.5 El 3448

uos+ uos ** (RN-CAS Registry Number 22201-28-1)~8±0.5 El 3448

UC13+ UC13? ** (RN-CAS Registry Number 10025-93-1) ~ 10.0±0.5 El 3795

UC14+ UC14 ** (RN-CAS Registry Number 10026-10-5)

1 1.0±0.3 El 3795

Np+ Np ** (RN-CAS Registry Number 7439-99-8)

6.32±0.12 SI 4042

Np+ Np ** (RN-CAS Registry Number 7439-99-8)

6.20±0.12 D 3875

Pu+ Pu ** 4.99±0.15 SI 4042

(RN-CAS Registry Number 7440-07-5)

341
Table of Ion Energetics Measurements—Continued

Ion Reactant Other

products

Ionization or appearance

potential

(eV)

Method Ref.

Pu + Pu ** (RN-CAS Registry Number 7440-07-5)6.06±0.02 D 3875

Am + Am ** (RN-CAS Registry Number 7440-35-9)

5.993±0.010 D 3875

Cm + Cm ** (RN-CAS Registry Number 7440-51-9)

6.09±0.02 D 3875

Bk + Bk ** (RN-CAS Registry Number 7440-40-6)

6.30±0.09 D 3875

cf+ Cf ** (RN-CAS Registry Number 7440-71-3)

6.41 ±0.10 D 3875

Es + Es ** (RN-CAS Registry Number 7429-92-7)

6.52±0.10 D 3875

Fm f Fm ** (RN-CAS Registry Number 7440-72-4)

6.64±0.1D 3875

Md+ Md ** (RN-CAS Registry Number 7440-11-1)

6.74+0.12 D 3875

No+ No ** (RN-CAS Registry Number 10028-14-5)

6.84+0.12 D 3875
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362
5 Author Index

Abbe, J.-C., 4052

Achiba, Y., 4076 Ackermann, F., 3762 Ackermann, R. J., 3795, 3962, 4061 Adamchuk, V. K., 3729 Adams, G. P., 3570

Aerni, R. J., 3790

Aihara, J., 3877 Akopyan, M. E., 3752, 3766, 4025, 4078, 4086

Ali, Z., 3591, 3917

Allen, J. D„ Jr., 3963

Aloisi, G. G., 3787 Ames, L. L., 4100

Anderson, C. P., 3507, 3528 Andrews, M. N., 3805 Antonova, N. L., 4030

Appell, J., 3521, 3906 Appelman, E. H., 3831, 3932 Armstrong, D. R., 3680 Artemov, A. N., 3786

Asbrink, L„ 3516, 3530, 3531, 3639, 3651, 3720, 3740, 3750

Ashe, A. J., 3832

Askani, R., 4034

Audier, H. E., 3590

Bach, R. D., 4084

Bafus, D. A., 3442

Bagarat'yan, N. V., 4096

Bain, A. D., 3826, 3843

Baker, A. D., 3520

Balducci, G., 3455, 3594, 361 1, 3618, 3901, 4105

Bardi, G., 3986

Barz, P„ 3747

Basch, H., 3643, 3649

Basco, N., 3882

Basset, P. J., 3641

Batich, C., 3832, 3999, 4049

Baumgartel, H., 3930

Baylis, A. B., 3441 Bazhenov, B. A., 4058 Beauchamp, J. L., 3632, 3633

Becker, G., 3844, 3867, 3950

Beez, M., 3847 Begun, G. M., 3793

Bel'ferman, A. L., 3539, 3769, 4070

Benezra, S. A., 3480, 3483, 3631

Benito, I., 4097

Benoit, F., 3792, 3973

Bente, P. F., III., 3916

Bentley, T. W., 3443, 3784

Berger, J. G., 3994 Bergmark, T., 3529, 3645, 3725, 3728, 3911 Berkosky, J. L., 4023

Berkowitz, J., 3500, 3525, 3536, 3640, 3650, 3831, 3913, 3920,

3927, 3928, 3932, 3958, 3960, 3971

Berry, A. D., 3814

Bertorello, H. E., 3454

Bertrand, M., 3845

Bethke, H., 3580 Beynon, J. H., 3845

Bickelhaupt, F., 3896

Bidinasti, D. R., 3572

Bieri, G., 3847, 4002

Bischof, P., 3509, 3999, 4037

Bizot, M., 3945

Blackburn, P. E„ 3595

Blake, A. J., 3672 Bock, H., 3504, 3584, 3646, 3648, 3673, 3746, 3778, 3781, 3844,

3847, 3867, 3898, 3944, 3946, 3950, 4067, 4092, 4097

Boekelheide, V., 3647, 3948

Boggess, G. W., 3963 Bogolyubov, G. M., 3674 Bohlmann, F„ 3996, 4041, 4044, 4046, 4051

Bonati, F., 3497

Bonnier, J. -M., 3588 Borgstrom, A., 4059

Borossay, J., 3444

Boschi, R., 3644, 3846, 3951, 3953, 3990, 4088

Boschi, R. A., 3748, 3751

Botter, R., 4003 Bouchoux, G., 3590 Boyd, R. J., 3828

Branton, G. R., 3794

Breeze, A., 3666, 3680

Briegleb, G., 3577

Briggs, P. R., 3549

Brion, C. E., 3492

Brogli, F., 3532, 3638, 3668, 3780, 4002, 4019, 4039, 4040,

4048, 4063 Brown, P., 3446, 3447 Bruckmann, P., 3997

Brundle, C. R., 3501, 3520, 3637, 3642, 3643, 3649, 3727, 3943

Buchler, A., 3613

Budhiraja, C. J., 3592, 3593

Bull, W. E„ 3507

Biinzli, J. C., 3828, 3835, 3842, 3843, 4004, 4010

Burak, A. J., 4010

Burroughs, P., 3979

Bursey, M. M„ 3480, 3483, 3496, 3631, 3805 Buschek, J. M., 3887, 3889

But, P. G., 4079 Cabaud, B., 3574, 3745, 3956 Cameron, A. E., 4042

Campbell, B. E., 3621 Camus, P., 4060

Cantone, B., 3453

Cardin, D. J., 3495

Carey, R. N„ 3758

Carlson, K. D., 3491, 3599

Carlson, T. A., 3507, 3528, 3880

Carmichael, P. J., 3602, 3654

Carver, J. C., 3507

Castle, P. M., 3820

Cater, E. D., 3448

Causley, G. C., 3970

Ceasar, G. P., 3873, 4008

Centineo, G., 3822 Cermak, V., 3537

Cetinkaya, B., 3512 Chadwick, D., 3517, 3659, 3667, 3694, 3879

Chaghtai, M. S. Z., 3591, 3881, 3917 Chang, C.-A., 3966

Chibrikin, V. M., 4079

Chizhov, Yu. V., 3658, 4078

Chondromatidis, G., 3580

Christian, S. D., 3915 Chupka, W. A., 3525, 3920, 3927, 3932

Ciach, S., 3800, 3802

363
Clark, D. T„ 3832

Clark, I. D., 3522

Clark, P. A., 3668, 4017

ClefT, B., 3542

Cobley, U. T., 3832 Cocke, D. L., 3440, 3597, 3798, 3902, 3966, 3978 Cocksey, B. G., 3833

Collin, J. E„ 3598, 3664, 3839, 3903

Collins, G. A. D., 3666

Collins, R. J„ 3878

Colton, R. J., 3938, 4022 Comes, J., 3519 Compton, R. N., 3793 Conde-Caprace, G., 3598, 3903

Condorelli, G., 3822 Conway, J. G., 4007

Cooks, R. G., 3479, 3845 Cornford, A. B„ 3499, 3671, 3694

Costa, M. L., 3779 Cowan, D. O., 3518, 3660, 3936, 3981 Cowan, R. D., 3566 Cowley, A. H., 3825, 3872 Cowling, S. A., 3824, 3988 Cox, P. A., 3669 Cradock, S., 3502, 3508, 3510, 3656, 3661, 3662, 3663, 3670,

3827, 4009, 4026

Crandall, J. K., 4019

Crooker, A. M., 4093 Crowe, A., 3625, 3797, 3799

Cruickshank, D. W. J., 3666, 3680

Csakvari, B., 3444

Cullen, W. R„ 3589

Cullison, D. A., 4083 Cundy, C. S„ 4077

Cusachs, L. C„ 3836, 3971

Cuthill, A. M„ 3796

Czekalla, J., 3577

Czira, G.f 3939

Daisey, J. M., 3730

Daly, N. R„ 3445, 3452 Danby, C. J., 3833

Danielson, P. M., 3595

Davis, L. P., 3848

Davis, S. P., 4007 Dean, J. A., 4042

Debies, T. P„ 3955, 4022 DeCorpo, J. J., 3442, 3814, 3952 Dehmer, J. L., 3640, 3831, 3958, 3960, 3971 Dehmer, P. M., 3920 DeKock, R. L., 3655, 3666, 3675, 3680 Delwiche, J., 3664, 3839 De Maria, G., 3594, 361 1, 3618, 3949 de Meijere, A., 3576

Denisov, Yu. V., 3918

Depiere, D., 4102

Desideri, A., 3608, 3986 Dewar, M. J. R., 3872 Dewar, M. J. S., 3657, 3825

Dibeler, V. H., 3921, 3929, 3931 Diemann, E., 3838 DiLonardo, G., 3731 Dimroth, K., 4053

Distefano, G., 3497, 3498, 3804, 3806

Dixit, M. N., 3560

Dixon, D. A., 3633 Dixon, R. N., 3665

Dmitriev, A. B., 3729 Donovan, R. J., 3567, 3742, 3878 Doong, P., 3945 Doucet, J., 3749, 3914 Dougherty, R. C., 3454 Drake, J. E., 351 1, 3514

Dromey, R. G., 3834 Drowart, J., 3458, 3557, 3819, 4001, 4098, 4102

Duke, Jr., R. E., 3848 Durup, J., 3906 Duxbury, G,, 3665 Eberbach, W., 3853, 4040

Ebsworth, E. A. V., 3502, 3661, 3670, 3827, 4026

Edqvist, O., 3516 Edwards, J. G., 3449

Ehlert, T. C„ 3623

Eick, H. A., 3459, 3460, 3612, 3614, 3976

Ekberg, J. O., 3893, 3894, 3895, 3912

Eland, J. H. D„ 3684, 3833, 3998

Eley, D. D., 3829

Ellison, F. O., 4023

Ellison, G. B., 3727

El'man, M. S., 3884, 4043 Emma, V., 3453 Emmel, R. H., 3823

Enrione, R. E., 3540, 3547

Ensslin, W., 3504

Epstein, G., 3924

Evans, K., 3876

Evans, S., 3527, 3669, 3676, 3677, 3681, 3682, 3683, 3686, 3688, 3830

Fabian, D. J., 3796

Farber, M., 3462, 3463, 3465, 3606, 3617, 3620, 3801, 4054

Farmer, J. S. H., 3492

Feather, D. H., 3613 Fedorova, M. S., 3918

Fehlner, T. P„ 3871

Felps, S., 3836

Fenderl, K., 3578, 3579

Fenske, R. F., 3866

Ferraris, J. P., 3981

Ferre, Y., 3587

Ferreira, M. A. A., 3779, 3812

Fetizon, M., 3590

Findlay, R. H., 3724, 4009

Finkbeiner, H. C., 3471, 3966

Fischer, E. O., 3582

Fischer, R. D., 3582

Fishel, N. A., 3614

Fjeldstad, P. E., 3977

Fleming, G. R., 3665

Flesch, G. D., 3628, 3791

Florida, D., 3773

Foffani, A., 3498

Foner, S. N., 3785

Forest, M., 4074

Fort, R. C., Jr., 3886

Fortin, C. J., 4018, 4074

Foster, M. S., 3632

Foster, R., 3543

Foster, S., 3836

Fragala, I., 3822

364
Franklin, J. L., 3442, 3487, 3490, 3808, 3987

Franzen, H. F., 3449

Fridh, C., 3639, 3651, 3720, 3740, 3750

Fringuelli, F., 3804

Fritz, G., 3844, 3855, 3867, 3950

Fritz, H. P., 3747

Frost, D. C., 3499, 3511, 3514, 3515, 3517, 3522, 3533, 3589,

3659, 3671, 3678, 3690, 3694, 3826, 3835, 3837,

3840, 3841, 3842, 3843, 3879, 3965, 4004, 4010

Fuchs, R., 3904

Fuss, W., 3584, 3673, 3944

Gaidis, J. M., 3549

Gaivoronskii, P. E., 3786

Galloni, G., 3731 Gamble, A. A., 3484

Gardner, J. L., 3975, 4095

Gelus, M., 3588 George, S., 3562

Gfeller, J.-C., 3953

Gibson, D. M., 3979

Giessner, B. G., 3493

Gigli, G„ 3455, 3901, 3969

Gilbert, J. R., 3484, 3788

Gilbert, R., 3764

Gil'burd, M. M„ 3539, 3769, 4070

Gilles, P. W„ 3449

Gingerich, K. A., 3440, 3468, 3469, 3471, 3472, 3473, 3596,

3597, 3609, 3619, 3621, 3798, 3902, 3961, 3966,

3968, 3978, 4012

Giovannini, E., 4063

Gleiter, R., 3513, 3518, 3569, 3576, 3660, 3679, 3849, 3936,

3981, 4006, 4017, 4034, 4045

Glemser, O., 3660, 3518 Glenn, K. G., 3695, 3700

Glockling, F„ 3474, 3815

Goldstein, M. J., 3991 Gole, J. L., 3743

Goll, W„ 4015 Golob, L., 3942 Gompper, R., 3885 Goodman, D. W., 3657, 3825, 3872 Gopalaraman, C. P., 3568 Gorman, A. A., 3824 Gorokhov, L. N„ 3821 Gounelle, Y„ 4003 Gowenlock, B. G., 3602, 3654

Graber, P., 3622 Grahn, W., 3994

Grasso, F., 3453

Gravel, D., 4074

Green, J., 4008

Green, J. C., 3677, 3686, 3830

Green, M. C., 3503 Green, M. L. H., 3688 Gregory, N. W., 3954

Greiss, G., 3545 Grimley, R. T., 3605 Grimm, F. A., 3507, 3880 Gronneberg, T., 3635, 3636, 3891 Gronowitz, S., 3858

Grosjean, D., 3957

Gross, M. L., 3544, 3735, 3790

Griitzmacher, H. F., 3552, 3553, 3583

Guest, M. F„ 3709

Guido, M., 3455, 3594, 3611, 3618, 3901, 3969, 4105 Gunkel, E.„ 3972 Gupta, S. K„ 3450, 3451 Gusarov, A. V., 3821

Gutbier, H., 3555 Gutmann, F., 4093 Guyon, P. M., 3525

Gyorosi, P., 3789

Hall, M. B., 3709 Hamnett, A., 3681, 3682 Haney, M. A., 3487, 3490 Hansen, J. E., 3893, 3894, 3895, 3912 Hanson, A., 4072

Hariharan, A. V., 3459, 3612, 3614

Harris, M. M., 3477 Hartmann, H., 3738

Haselbach, E., 3505, 3741, 3853, 3860, 4037, 4040

Haselback, E., 3888 Hashmall, J. A., 3936

Hass, A., 3746

Hassan, V., 3881 Hauptmann, H., 4090

Hayakawa, T., 3538

Hazeldine, D. J., 3829 Hedaya, E., 3476

Heier, K.-H., 4066

Heil, H. F., 3545

Heilbronner, E., 3505, 3509, 3513, 3518, 3532, 3576, 3638, 3660,

3668, 3679, 3685, 3687, 3741, 3780, 3832, 3847,

3849, 3936, 3991, 3999, 4002, 4006, 4017, 4019,

4034, 4037, 4038, 4039, 4040, 4045, 4047, 4048,

4049, 4063 Hekman, M., 4045

Heller, D., 3876

Hellwinkel, D., 4081 Henion, J. D., 3817

Herberich, G. E., 3545

Herring, F. G., 3499, 3511, 3514, 3671, 3678, 3693, 3694, 3837, 3879

Hertzberg, M., 3634

Herzberg, G., 3770 Heyman, M. L., 3828

Hickling, R. D„ 3488

Higginson, B. R., 3655, 3680, 3870, 3979

Highsmith, R. E., 3653

Hildenbrand, D. L., 3610, 3616, 3816, 3818, 3909

Hill, R. K., 4083

Hillier, I. H., 3675, 3709

Hillig, H., 3542

Hintz, P. J., 3887 Hirayama, C., 3820 Hoareau, A., 3745, 3956 Hoffman, M. K., 3805 Hoffmann, R. W„ 3933, 4094

Hogberg, S., 3569

Holls, P. J., 4035 Holmes, J. L., 3535 Holmstrom, J.-E., 3905

Holsboer, F., 3885, 4024

Holtz, D., 3633 Homung, V., 3513, 3569, 3679, 3685, 3832, 3936, 3991, 4034,

4040, 4048

Hoshi, T., 3849 Hoshino, H., 4033

365
Hotop, H., 3541 Houk, K. N., 3848

Houte, J. J. v., 3910

Howe, I., 3479, 3916

Hsia, M., 3623 Huber, R., 3855

Hiibner, J., 3552, 3553, 3583 Hudson, R. L., 3785 Huffman, R. E., 3983 Hugo, J. M. V., 3665

Husain, D., 3878

Hussain, M., 3725, 3728

Hvistendahl, G„ 3494, 3627, 3630, 3789

Ikeda, S., 3874, 3883, 4056

Ikuta, S., 4056

Il'in, M. K., 4096

Innorta, G., 3497, 3498, 3804, 3806, 3807

Inokuchi, H., 3877

Ipaktschi, J., 3780

Iskakov, L. I., 4028, 4031, 4057

Iverson, A. A., 3774

Ivko, A. A., 4071

Iwai, T„ 4068

Jackson, S. E., 3686, 3830

Jalonen, J., 3481, 3803

Jenkins, F. A., 3561

Jennings, K. R., 3488

Jewitt, B., 3688

Jinno, M., 4056

Joachim, P. J., 3677, 3683

Johnson, C. A. F„ 3602, 3654

Johnstone, R. A. W„ 3443, 3485, 3626, 3784, 3824, 3852, 3988,

4089

Jois, S. S., 3560

Jonas, A. E., 3880

Jonathan, N., 3534, 3691, 3701, 3717, 3942

Jones, G. R., 3501, 3642, 3943

Jones, R. W., 3869

Jonsson, B. 6., 3639, 3651, 3720, 3740, 3750

Joshi, Y. N., 3562, 3592, 3593

Joyce, T. E., 3603

Judge, D. L„ 3573

Jungen, Ch., 3770

Junk, G. A., 3628

Kaizu, Y., 4029

Kamada, H., 4032, 4087

Karlsson, L., 3529, 3645, 3725, 3728, 3911 Kashparov, I. S., 4035 Katayama, D. H., 3983

Katrib, A., 3511, 3514, 3515, 3659, 3678, 3694, 3837, 3864,

3879, 4022

Katsumata, S., 3862, 3984, 4068, 4076

Kaufman, V., 3563, 3754, 3756, 3899, 3974

Kent, M. E., 3476

Keppie, S. A., 3495

Khalil, O. S., 3856 Khatoon, S., 3917

Khmel'nitskii, R. A., 3767

Kilcast, D., 3832

Killgoar, P. C., Jr., 3927 Kimura, K., 3862, 3984, 4068, 4076

King, G. H„ 3512, 3696, 3704, 3707

Kingston, D. G. I., 3817

Kinneberg, K. F., 3823

Kitaev, Yu. P., 3884, 4043

Klebe, K. J., 3910

Kleimenov, V. I., 3658

Klessinger, M., 3713, 3997

Klinkenberg, P. F. A., 4101

Kloster-Jensen, E., 4002, 4019, 4048

Knowles, D. J., 3800

Kobayashi, H., 4029

Kobayashi, M., 4029

Kobayashi, T., 3638, 3964, 4082, 4106, 4107

Koch, E. E„ 3857 Koch. V. R., 3851 Koenig, T., 3851 Kohl, F. J., 3457, 3470, 4005, 4014

Kollmeier, H. J., 3582

Konstantatos, J., 3742

Kordis, J., 3596, 3798, 3961, 3978, 4012

Komfeld, R., 3916

Kosbahn, W., 4024

Koski, W. S., 3869

Kraessig, R., 3930

Krapp, W., 4081

Kreiter, C. G., 3582 Krenmayr, P., 3556

Krishnamurthy, S. S., 3512, 3704

Kroner, J., 3781, 3944, 4024, 4065

Kroto, H. W., 3696, 3697, 3708, 3982 Kubach, C., 3521 Kuebler, N. A., 3637, 3643, 3649, 3727, 3941, 4036, 4084

Kuppermann, A., 3739

Kutsev, V. S., 3456, 4030

Kuzmenko, N. E., 3558 Kuznetsova, L. A., 3558 Kuzyakov, Yu. Ya., 3558

Lageot, C., 3575, 3581, 3737 Lakshman, S. V. J., 3564

Lampe, F. W., 4099

Lanyiova, Z., 3860

Lappert, M. F., 3495, 3503, 3512, 3548, 3704, 4077

Larin, N. V., 3786

Larkins, J. T., 4075

Lawless, E. W., 3551 Leach, W. P., 3788

Leavell, S., 3987

Lebert, K.-H., 3738

Lee, S. T., 3690, 3840, 3841, 3965

Lee, T. H., 4022, 4023

Leeder, W. R., 3589

Lefebvre-Brion, H., 3762 Lemal, D. M., 4040

Lempka, H. J., 3666, 3990

Leroi, G. E., 3927

Lichtenberger, D. L., 3866

Lightner, D. A., 3629

Lin, L.-N., 3915

Linda, P., 3482

Lindberg, B., 3569 Lindholm, E., 3516, 3639, 3651, 3720, 3740, 3750

Little, D. J., 3742

Litzow, M. R., 3495

Lloyd, D. R., 3506, 3641, 3655, 3666, 3675, 3680, 3682, 3699,

3709, 3711, 3865, 3870, 3935, 3979 Loginov, M. V., 3526 Loginov, Yu. V., 3766

366
Lopatin, S. N., 4086

Lossing, F. P„ 3476, 3732 Loudon, A. G., 3477

Lozac'h, N., 3569 Lynaugh, N„ 3506, 3699, 3709, 3711 Lynch, D. A., 3491 MacDiarmid, A. G., 3653, 3814

Maier, J. P., 3677, 3702, 3703, 3854, 3890

Majer, J. R., 3550

Majeti, S., 3629 Makowiecki, D. M., 3491

Malaspina, L., 3947, 3949, 3986

Maltsev, A. K., 3939 Mamantov, G., 3507

Mancini, V., 3806, 3807 Mannschreck, A., 3505, 3888 Manuel, G., 3850, 3859 Marek, B. C., 3467

Maretina, I. A., 3674 Margrave, J. L„ 3570, 3615, 3743, 4100

Marino, G., 3482, 3804

Markl, G., 4066, 4090

Marr, G. V., 3772

Martens, J., 4062

Martin, H. D., 3509, 3687

Martin, H.-D., 4045, 4047

Martinez de Bertorello, M., 3454

Masclet, P., 3957 Mason, D. C., 3739

Mateescu, G. D., 3886, 3907 Mathar, W„ 3996 Mathey, F., 4090

Mathieu, G., 3812 Matsumoto, A., 3538 Matsumoto, H., 3712, 4076 Mazengo, R. Z., 3477

McAllister, T., 3476 McConkey, J. W„ 3625, 3797, 3799 McCulloh, K. E., 3925, 3931 McDiarmid, R., 3565 McDowell, C. A., 3499, 3515, 3659, 3671, 3678, 3689, 3690,

3692, 3694, 3835, 3837, 3840, 3841, 3879, 3965 McDowell, M. V., 3653, 3814, 3952 McFarland, C. W., 3886

McGillivray, D., 3535 McGlynn, S. P., 3836, 3856

McIntyre, N. S., 3572

McLafferty, F. W„ 3916 McLean, R. A. N., 3511, 3514, 3515, 3659, 3678, 3694, 3868, 3879 McMaster, B. N., 3784 McNeil, D. W„ 3476

Medynskii, G. S., 3658 Meeks, J. L., 3856 Mehlhom, W., 3542

Meijer, F. G., 4101

Meijere, A., 3849

Meisels, G. G., 3493, 3823

Mellon, F. A., 3443, 3485, 3626, 3852, 4089 Menes, F., 4003 Merimson, V. G., 3571

Miller, J. R„ 3788

Miller, L. L., 3851 Mines, G. W., 3705, 3863, 4080

Minghetti, G., 3497 Minnhagen, L„ 3754, 3923

Mintz, D. M., 3739 Mitchum, R. K., 3823

Mittsev, M. A., 3526 Moin, F. B., 3539, 3769

Mollere, P., 3844, 3867, 3950

Mollere, P. D., 3980 Momigny, J., 3812, 3839 Morishima, I., 3712

Moritani, I., 3759

Morris, A., 3534, 3691, 3698, 3701, 3942

Morrison, J. D., 3811, 3813, 3834, 3967

Morrison, R. J., 3815 Morse, R. D., 3882 Mouvier, G., 3957 Muenow, D. W„ 3615, 3810

Muller, A., 3838

Muller, C., 3993

Muller, J., 3545, 3578, 3579, 3582, 4015

Munir, Z. A., 3475 Murdoch, J. D., 3670 Murphy, C. B., 3547 Murphy, Jr., C. B., 3540

Murrell, J. N., 3644, 3707, 3710, 3948 Musso, H., 3741, 4034

Muszkat, K. A., 4038 Myers, C. E., 3458, 3819, 4001 Nagakura, S., 3964, 4076, 4082, 4106, 4107

Nagaraj, S., 3560

Narayan, B., 3755 Narayana, B., 3761

Natalis, P., 3664, 3839, 4073 Natowsky, S., 3991 Nauman, R. V., 3848

Neckel, A., 3775 Nefedov, O. M., 3939

Nelsen, S. F., 3887, 3889 Newkome, G. R., 3848

Ni, R. Y., 3600

Nicholson, A. J. C., 3524, 3800, 3802

Nicoletti, R., 3629

Niehaus, A., 3541

Nihei, Y„ 4032, 4087

Nikitin, O. T., 4096

Nikolaev, E. N., 4108

Nishida, S., 3759

Nixon, J. F., 4021

Nolle, D., 4065

Noth, H., 4065 Nounou, P„ 3574, 3588, 3745, 3956 O'Bryan, C. L., 3983

Oehling, H., 3934

Ogata, H„ 4032, 4087

Ogawa, M., 3573, 3760 Ogawa, S., 3760 Okabe, H., 3929 Okuda, M„ 3691, 3701, 3714, 3942

Okudaira, S., 3486

Olavesen, C., 3550

Olfky, R. S., 3634

Onizuka, H., 4032, 4087 Opendak, I. G., 4108

Orchard, A. F., 3527, 3669, 3677, 3681, 3682, 3683, 3688, 3979

367
Osafune, K., 3862

Otto, A., 3857

Paine, R. T., 3652

Palmer, M. H„ 3724, 4009

Palmer, T. F., 3829 Panchenkov, I. G., 3821

Paquette, L. A., 4006, 4008

Parr, G. R., 4069

Pasanen, P., 3803

Pattoret, A., 3557

Paulus, J.-M., 4052

Pechine, J. M., 4003

Pedley, J. B„ 3503, 3512, 3548, 3704, 4077

Peel, J. B., 3834

Persson, W., 3926

Petrov, A. A., 3674, 3767

Pettsold, R., 4086

Piacente, V., 3472, 3594, 3608, 3609, 3947, 3949, 3986

Pignataro, S„ 3482, 3497, 3498, 3787, 3804, 3806, 3807

Pihlaja, K., 3481, 3803

Pincock, R. E., 3492

Pinkerton, F. H., 3685

Pirnazarova, F. N., 4079

Piruzyan, L. A., 4079

Pitt, C. G., 3546, 3758, 3922, 3946

Plotnikov, V. F., 3674

Poltorakov, A. P., 4079

Polyakova, A. A., 3767

Porter, R. F., 3461, 3464

Potapov, V. K., 3523, 3918, 4028, 4031, 4055, 4057, 4058

Potts, A. W., 3695, 3700, 3715, 3716, 3719

Powell, R. E., 3452

Pozharskii, A. F., 4035

Praefcke, K., 4062

Praet, M. -Th., 3585

Preiss, H., 3783

Pressley, G. A., Jr., 3441

Preston, J. A., 3625

Price, W. C., 3695, 3700, 3715, 3716, 3719, 3761

Prinzbach, H., 3509

Proch, D., 3944

Prudnikova, G. V., 3729

Prusaczyk, J. E., 3599

Pua, C. K. N., 3794

Pupp, C., 3473, 3621 Puttemans, J.-P., 4072

Pygall, C. F., 3688

Rabalais, J. W., 3529, 3530, 3645, 3721, 3725, 3728, 3864, 3911,

3938, 3955, 4022, 4023 Rabeneck, H., 4013 Rademacher, P., 4085

Radler, K., 3857

Radziemski, L. J., 3756, Jr., 3566

Rakita, P. E., 3805

Rankin, D. W. H., 3662 Rao, T. V. R„ 3564 Rauh, E. G., 3448, 3795, 3962, 4061 Raymonda, J. W., 3559, 3757

Reader, J., 3744, 3893, 3894, 3895, 3912, 3924 Redhead, P. A., 3489, 3568

Reetz, M. T., 4094

Reinke, D., 3930 Rennekamp, M. E., 3845

Reuss, G., 3577

Rice, S. A., 3773, 3876

Richardson, N. V., 3669

Ridyard, J. N. A., 3990

Rinke, K., 4013 Robb, J. C., 3550

Roberts, J. A., Jr., 3607

Roberts, P. J., 3669, 3865, 3870

Robertson, A., 3827

Robin, M. B., 3637, 3643, 3649, 3727, 3941, 4084

Roche, A. L., 3762 Rodionov, A. N., 4055

Rogerson, P. F., 3496 Rogozhin, K. L., 4055

Rolinski, E. J., 3603

Rosenstock, H. M., 4075 Rosmus, P., 4092

Ross, K. J., 3534, 3691, 3942

Rossi, M., 3860

Rousseau, Y., 4018, 4074

Russ, B., 4041

Russell, B. R., 3774, 3776, 3970

Saalfeld, F. E„ 3634, 3653, 3814, 3952 Sadovskaya, V. L., 3571

Salahub, D. R., 3748, 3751 Salmona, G., 3587 Salmona, Y. F., 3736

Samson, J. A. R., 3975, 4095 Sandhu, J. S., 3533

Sandorfy, C., 3749, 3764, 3914

Santoro, E., 3989

Sarapu, A. C., 3866

Saunders, V. R., 3675 Sauvageau, P., 3749, 3764, 3914

Savage, W., 3663

Savage, W. J., 3661

Scanlan, I., 3832

Schaaf, D. W., 3954

Schafer, H„ 4013

Schafer, W., 3858, 3896, 3933, 3934, 4053, 4066, 4090, 4094,

4104

Schaublin, J., 3518

Scheppele, S. E., 3823

Scheps, R., 3773, 3876

Schmelzer, A., 3741 Schmidbaur, H., 3782

Schmidt, E., 3981 Schmidt, H., 3859, 3992, 3995, 4091 Schmidt, W„ 3503, 3644, 3647, 3710, 3846, 3855, 3885, 3948,

3951, 3953, 3990, 4000, 4050, 4077, 4088 Schoonmaker, R. C., 3461, 3464

Schubert, R., 3892

Schurter, R., 4063

Schuttler, R., 3933 Schwarz, H., 3996, 4041, 4044, 4046, 4051, 4062 Schweig, A., 3850, 3858, 3859, 3861, 3896, 3908, 3933, 3934,

3940, 3992, 3993, 3994, 3995, 4053, 4066, 4081,

4083, 4090, 4091, 4094, 4104

Schweiger, J. R., 3825, 3872

Schweitzer, G. K„ 3880, 3963

Scott, J. D., 3776, 3970

Searcy, A. W., 3466, 3607, 3613, 4016

Seidl, H„ 4097

Seitz, W., 3505, 3888

Seiver, R. L., 3460

368
Semenov, G. A., 4108 Semmelhack, M. F., 4049 Sen Sharma, D. K., 3808

Sergeev, Yu. L., 3752, 4025, 4078

Setser, D. W., 3845

Seybold, G., 3885 Shannon, T. W., 3549

Shapiro, R. H., 3897, 3900

Sheley, C. F„ 3886

Shen, K.-W., 4036 Shevchuk, V. U., 3769 Shimada, K., 3960

Shimizu, Y., 3624 Shiokawa, T., 4056 Shu-Shou-Shen, S., 3796 Shushunov, N. V., 3786

Siegbahn, K„ 3911, 3529, 3645, 3725, 3728 Simmie, J. M., 3478 Simpson, J., 3548

Singhal. S. R., 3560

Singleton, D. L., 3604

Sirotkin, N. I., 3786

Sizoy, V. F., 3571

Skinner, H. B., 3466, 4016

Smagina, E. I., 3456

Smith, D. H„ 4042

Smith, D. J., 3534, 3691, 3701

Smith, D. R., 3559

Smith, P. G., 3824

Smitt, R., 4064

Smoes, S„ 3458, 3557, 4098, 4102

Smolinsky, G., 3809

Snyder, J. P., 3828

Sodeck, G., 3652, 3775

Sojka, S. A., 4019

Solgadi, D., 4003

Solouki, B., 3646, 4092

Sonnessa, A. J., 3730

Sorokin, L. S., 3729

Sorokin, V. V., 3523

Spalding, T. R., 3495, 3548

Spohr, R., 3525

Spoliti, M., 3455

Srivastava, R. D., 3462, 3463, 3465, 3606, 3617, 3620, 3801, 4054

Stafast, H., 3778, 4067

Stafford, F. E„ 3441, 3601, 3604, 3652

Stalherm, D., 3542

Stearns, C. A., 3457, 3470, 4005, 4014

Stebbings, W. L., 3753

Steichen, J., 3987

Steiger, R. P., 3570

Steinhaus, D. W., 3566

Steudel, R., 4092

Stewart, W. B., 3492

Stockbauer, R., 3919

Strachan, P., 3567

Strack, W., 4024

Strafford, R. G., 3474

Street, G. B., 3475

Streets, D. G., 3873 Sucrow, W., 3580

Suffolk, R. J., 3696, 3697, 3707, 3708, 3982, 3990

Sugar, J., 3563, 3744, 3875, 3899, 3974

Sullivan, C. L., 3599 Sustmann, R., 3892, 3937

Svec, H. J., 3628, 3791 Sweigart, D. A., 3718, 3733

Swingler, D. L., 3800, 3802

Syrvatka, B. G„ 3539, 3769, 4070

Szepes, L., 3444 Szwarc, M., 3960 Szwarc, R., 3819, 4001 Tajima, S., 3777, 3624, 4033 Takezawa, S., 3763 Tamas, J., 3939 Tan, H.-S., 4099

Tanaka, I., 4020

Tanaka, K., 4020

Tanaka, Y„ 3763

Taniguchi, S., 3538

Taticchi, A., 3804

Taylor, G. N., 4084

Taylor, J. W., 3753, 4069

Teraji, T., 3759

Terenin, A., 3586 Thames, S. F., 3685

Thiel, W„ 3861

Thistlethwaite, P. J., 3802 Thomas, R. K., 3705, 3726, 3734, 4080

Thommen, E., 3629 Thompson, G. L., 4006 Thompson, H„ 3705, 3726, 4080 Thompson, H. W., 3863 Thompson, K. R., 3985 Thorn, R. J., 3448

Thuijl, J. v., 3910

Tillett, J. G., 3484 Tomer, K. B., 3900 Tomkins, F. S., 4060

Tondello, E., 3822

Tondello, G., 4011 Toren, E. C., 3758

Torroni, S., 3807

Traeger, J. C., 3811, 3813, 3967

Trill, H., 3937

Trombetti, A., 3731

Tsai, S.-C., 3916 Tschuikow-Roux, E., 3478

Tsuchiya, T., 3624, 3777, 4033

Turk, J., 3897, 3900

Turner, D. W., 3520, 3527, 3677, 3683, 3702, 3703, 3718, 3733, 3854, 3871, 3890

Tuttle, M., 3851 Ul'yanova, O. V., 4079 Undheim, K„ 3494, 3627, 3630, 3635, 3636, 3789, 3891, 3977 Uy, O. M., 3463, 3606, 3617, 3620, 3819, 4001, 4054

Uzan, R., 3574, 3745, 3956

Valind, S., 3926 Van Den Ham, D. M. W., 3722, 3723, 3959 Vander Auwera-Mahieu, A., 3819, 4001 Van Der Helm, D„ 3915 Van Der Meer, D., 3722, 3723, 3959 Van Deurzen, C. H. H., 4007 Varmuza, K., 3556

Vasile, M. J., 3809

Vaziri, C., 4074

Velasco, R., 3768

369
Venkateswarlu, P., 4027 Verma, R. D., 3560 Vermeer, H., 3896

Vikhlyaev, Yu. I., 4079

Vilesov, F. I., 3658, 3752, 3765, 3884, 4025, 4043, 4078, 4086

Vincent, E. J., 3587

Vincent, E.-J., 3736

Visnapuu, A., 3467

Vorlaender, W„ 4051 Vornberger, W., 3782 Vovna, V. I., 3884, 4043, 4086

Wagner, G., 3781 Wagner, L. C., 3605 Wahl, A. C., 3928 Wahlbeck, P. G., 3600, 4103

Walker, J. A., 3921, 3931, 4075

Walker, T. E. H., 3958 Wanczek, K.-P., 3738 Wang, J. L.-F., 4100

Wanger, G„ 3898 Wankenne, H„ 3812 Ward, S. D„ 3485 Warneck, P„ 3554 Watanabe, I., 3874, 3883 Weidner, U„ 3850, 3908, 3940, 3994, 4081, 4083

Weil, K. G„ 3622

Weiler, L., 3517, 3842, 3843, 4004

Weissler, G. L., 3573 Werme, L. O., 3529, 3645, 3725, 3728, 391

Westwood, N. P. C., 3511, 3514, 3982

Wherrett, S. R., 3772

White, G., 3634

Whiteford, R. A., 3510, 3656, 3661, 4026

Wiberg, K. B., 3727

Wilkins, B. T„ 3503, 3855, 3990, 4050, 4077

Wilkins, C. L., 3544

Williams, D. H., 3479

Williams, T. A., 3715

Wilson, J. W., 3815

Wilson, P. W., 3570 Wingard, R. E., Jr., 4006, Jr., 4008

Winters, H. F., 3475

Wittel, K„ 3648, 3746 Work, D. E„ 3976 Worley, R. E., 3561 Worley, S. D., 3886,3907

Wu, H. Y., 4103

Wulfson, N. S., 3571 Wyatt, J. R., 3601 Yamazaki, T., 3984

Yokota, K., 3964 Yokoyama, Y„ 3874, 3883, 4056

Yonezawa, T., 3712

Yoshihara, K., 4056

Yoshikawa, K., 3712

Zaletov, V. G., 4035

Zaretskii, V. I., 3571

Zauli, C., 3731 Zimina, K. I., 3767

370
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1. PUBLICATION OR REPORT NO. NSRDS-NBS 63, Part I

2. Gov't Accession No. 3. ftecifltertt' s Accession No.

4. TITLE AND SUBTITLE

Ion Energetics Measurements

Parti. 1971- 1973

5. Publication Date Sept. 1980

6. Performing Organization Code

7. AUTHOR(S) H. M. Rosenstock, D. Sims, S. S. Schroyer, W. J. Webb

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Appearance potential; electron impact; electron spectroscopy;

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