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Chase, Malcolm W/Thermodynamic propertle QC100 .U5753 N0.1243 1987 V198 C.I NBS-P

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ndards

NBS Technical Note 1243

Thermodynamic Properties of the

Altcaline Earth Metal Hydroxides (MOH)

L Literature Citations

Malcolm W. Chase

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Cic^ioo

NBS Technical Note 1243 c.^

Thermodynamic Properties of the

Alkaline Earth Metal Hydroxides (MOH)

L Literature Citations

Malcolm W. Chase

Chemical Thermodynamics Division

Center for Chemical Physics

National Measm^ement Laboratory

National Bureau of Standards

Gaithersburg, MD 20899

December 1987

fffAU O*

U.S. Department of Commerce

C. William Verity, Secretary

National Bureau of Standards

Ernest Ambler, Director
National Bureau of Standards U.S. Government Printmg Office For sale by the Superintendent

Technical Note 1243 Washington: 1987 of Documents,

Natl. Bur. Stand. (U.S.), U.S. Government Printing Office,

Tech. Note 1243 Washington, DC 20402

42 pages (Dec. 1987)

CODEN: NBTNAE
THERMODYNAMIC PROPERTIES OF THE ALKALINE EARTH METAL HYDROXIDES (MOH)

I. Literature Citations

Table of Contents

ABSTRACT iii

INTRODUCTION 1

NOMENCLATURE 2

LITERATURE COVERAGE 3

DATA SUMMARIES 5 ACKNOWLEDGEMENTS 7

BIBLIOGRAPHIES

BERYLLIUM HYDROXIDE (BeOH, BeOH+) 8 MAGNESIUM HYDROXIDE (MgOH, MgOH+) 13

CALCIUM HYDROXIDE (CaOH, CaOH+) 17

STRONTIUM HYDROXIDE (SrOH, SrOH+) 25

BARIUM HYDROXIDE (BaOH, BaOH+) 32

111
ABSTRACT

A bibliographic collection is provided on data which are necessary for the

calculation of the thermochemical properties of the gaseous alkaline earth metal

(mono)hydroxides (MOH) and their positive ions (MOH''") , where M = Be, Mg, Ca, Sr, and

Ba . This is the first in a series of articles that will document the information

used in the critical evaluation of the thermodynamic properties for the JANAF

Thermochemical Tables.

The collection contains references which have been published through the end of

1985, with a limited number of 1986 references. Five bibliographies are given, one for each of the alkaline earth metals. In each bibliography, the references are listed chronologically; alphabetically by first author within each year. The names

of the ten species are given according to the Chemical Abstracts system of

nomenclature (as of the Tenth Collective Index) . The Chemical Abstracts Registry

Numbers are also given for each of the species. A brief summary of the type of

available information is given.

Keywords: alkaline earth hydroxides, bibliography, electron affinity, electronic

energy levels, equilibrium data, formation properties, ionization potential,

molecular structure, review articles, thermochemistry, thermodynamic properties,

vibrational frequencies

IV
INTRODUCTION

This is the first in a series of articles that will document the information used in

the critical evaluation of the thermodynamic properties of chemical species for the

JANAF Thermochemical Tables. In this particular article, thermochemical tables for

the gaseous alkaline earth metal hydroxides (MOH) and their positive ions (MOH+) are being prepared. For the current project, the alkaline earth metals (M) include Be,

Mg, Ca, Sr, and Ba. There are no data available for the Ra species. The

preparation of these thermochemical tables has been divided into a series of

sequential sections, each section containing documentation. This permits the

technical community not only to have access to all the available pertinent

references early in the investigation but also to view the progress in the critical

evaluation of the thermodynamic properties for the JANAF Thermochemical Tables. It

is hoped that this will stimulate interested scientists to comment on the

documentation so that we can make this documentation as complete as possible. The

goal is to construct a complete bibliographic resource, upon which future studies can be built, and to eliminate the need for another search of the past literature on these species. In the future, one only should have to be concerned with current

updates to this survey. A possible limitation is in the appearance of pertinent

data in journals not accessed by the abstracting services. For example, much of the

work on the beryllium species was done under DOD contracts and was often reported

only in progress reports and military reports; these were often not made available

to the abstracting services.

Since the final recommended thermochemical values for these hydroxides are tied in

with the results of other species (e.g. the five (di)hydroxides and five oxides),

there are other stepwise documentation projects in progress.

In general, the first two steps involve the construction of the bibliographies,

followed by a set of data summaries (i.e., summaries of the reported data in a tabular and graphical format) . Subsequently, there will be published preliminary

thermal functions, preliminary formation properties, and then the final

thermochemical tables. The latter normally would be a fine -adjustment of the

preliminary values. This fine -adjustment would result from the examination of data

consistency as viewed from a larger group of species, i.e. a mathematical solution

of a thermochemical network or consideration of trends in the periodic table. From

a network solution, there is obtained a statistical assessment of the overall

uncertainties in the formation properties and a better understanding of the

interconsistency of all data used in the network.
NOMENCLATURE

The species of interest in this bibliographic section are given below with their names and registry numbers as obtained from Chemical Abstracts On-Line (Registry

File) in December 1986. Historically, these species have often been called

monohydroxides , but this naming convention currently is not used by Chemical

Abstracts

.

formula

BeOH

MgOH

CaOH

SrOH

BaOH

BeOH+

MgOH+

CaOH+

SrOH+

BaOH+

name

beryllium hydroxide

magnesium hydroxide

calcium hydroxide

strontium hydroxide

barium hydroxide

hydroxyberyllium(l+)

hydroxymagne s ium ( 1+

)

hydroxycalcium(l+)

hydroxys tront ium (1+)

hydroxybarium(l+)

registry number

20768-68-7

12141-11-6

12177-67-2

12131-14-9

12009-08-4

12280-09-0

60172-61-4

36812-31-4

36812-32-5

68193-67-9
LITERATURE COVERAGE

All pertinent references have been collected into five bibliographies, one for each

of the five alkaline earth metals [there are no data available for the radium

species] . These references were taken primarily from a search of Chemical Abstracts

up to and including the 1986 volumes (i.e. Volumes 104 and 105). However, a scanning of the retrieved articles, manual scanning of selected journals, and use of

personal contacts has yielded additional publications. Since the number of

references for these hydroxides is not excessive, all published sources could have

been listed. Instead, only those articles are included which have some data

pertinent to the thermochemical calculations. The literature collection maintained

by the National Bureau of Standards Ion Energetics and Kinetics Data Center was searched to include articles pertaining to the ionization potential and appearance

potential of the five alkaline earth (mono-) hydroxides. The collection should be

complete through 1986 with the following constraints:

1. All articles referring to aqueous solutions involving MOH+ are not

included. We are interested only in the gaseous MOH and MOH+ species.

Occasionally, this type of article discusses solution spectra of the

OH group; in this case, the article is included.

2. Many articles published in astrophysical journals are not included

because they are not presenting new spectral information. More often,

existing spectral data is used to identify species in stars.

3. Early studies in flame spectroscopy, in which alkaline earth metalcontaining species were added to flames, may not be extensively

covered in this bibliography. In the early investigation of these

flames, the assignment of spectral lines to a given species was not

always definitive.

4. Analytical chemistry articles which deal with the interferences of

MOH(g) electronic bands with other bands usually are not included.

These articles normally do not give definitive values for the

electronic bands nor do they present data relevant to this particular

the rmodynami c s tudy

.

5. Articles using existing thermochemical values for the hydroxides

in calculations are not included, unless the article includes a discussion of problems in the calculated results.
6. During the 1960 's there was a large effort directed towards the

measurement of properties of beryllium and its species by government

agencies and their contractors. Much of this work was documented in

technical progress reports. A critically reviewed publication did

not necessarily follow. There is a high probability that not all of

these reports have been accessed.

7. At this time, only those critical reviews which deal exclusively with

hydroxides are included.

The inclusion of an article in this collection does not imply that it will be of

high importance in the final selection of data. Since there is not much data, we have probably been rather unselective in our choice of entries in these

bibliographies, and have extracted some articles which will not be useful. With the

possible shortage of information, the hope was that some useful information may be

hidden in these articles. The initial examination of the literature suggests that

sufficient reliable information is available to generate sound thermochemical tables

for the alkaline earth metal hydroxides (MOH) , except for BeOH(g) . In fact, there

are no experimental studies on BeOH since 1969, except for the ESR study in 1976.

The five positive ions lack experimental structural and vibrational frequency

information.

In generating these bibliographic files, the intent is to add information

progressively as the evaluation procedure progresses. Thus, at the start, the prime

effort is to list authors and the journal citation. As the literature searching

progresses and as articles are obtained, additional information is added (e.g.,

article title. Chemical Abstracts reference). Thus, some citations may be

incomplete at this time. In general, the majority of the bibliographic citations

will (should) eventually contain:

authors

title of the article

journal citation

abstract citation (Chemical Abstracts, Physics Abstacts, etc.)

short annotation as to information in the article

At this point for the alkaline earth metal hydroxides (MOH) , we have collected the

majority of the available data, with no statement as to its value. During the data

evaluation process, some citations may well be deleted, as well as additional

citations discussed.
DATA SUMMARIES

The next publication in this series will be a set of tabular information which will

summarize the relevant data, as it was presented in the original publication. These

summaries will help direct attention to the data actually available for use in

generating thermochemical tables. In the case of these hydroxides, data summaries

will be given for the following information:

molecular structure (bond angles and bond distances)

vibrational frequencies

electronic energy levels

dissociation energy, in terms of MOH = M + OH

ionization potential, in terms of MOH = MOH"^ + e'

The same information will be summarized for the positive ions, except for the

ionization potential. In all cases, experimental and theoretical data are included.

At this time, it is interesting to summarize briefly the nature and quantity of data

available. The following table is intended to give a rough sense of the

distribution of data for the hydroxides. A more exact summary of the data will be

available after a thorough examination of all references.
SUBJECT COVERAGE IN REFERENCES ON ALKALINE EARTH HYDROXIDES (MOH)

Be Mg Ca Sr Ba

total references 34 32 71 64 48

structure

estimated/calculated 6 11 11 14 11

experimental 12 3 2 1

vibrational frequencies

estimated/calculated 2 11 11 14 11

experimental - 1 3 2 1

electronic energy levels

bands - 10 15 18 12

precise values - 1 3 2 1

enthalpy of formation

indirect (flame studies) - 2 12 11 12

direct (mass spec) 17 3 3 2 3

ionization potential 7 5 10 10 9

Since some articles may contain information pertaining to more than one category

listed above, the sum does not equal the total. In addition, some articles do not

report any data, but, instead, discuss the interpretation of previously reported

data. As a side note, the large number (17) of references for the enthalpy of

formation of beryllium hydroxide is misleading since many are progress reports in

which the same data are reported repeatedly.
ACKNOWLEDGEMENTS

The support of the U. S. Air Office of Scientific Research, Directorate of

Aerospace Sciences, with program directors Dr. L. H. Caveny and Dr. R. Vondra,

is gratefully acknowledged. This activity began while the JANAF Thermochemical

Tables project (AFOSR Contract No. F49620-85-C-0076) was at The Dow Chemical

Company. Numerous people helped in the initial collecting and typing of these

references. Special thanks go to Ms.' Betty Clark, Rhoda Toth, Barbara Meier, and

Ann Schmidt. When this project was transferred to the U. S. National Bureau of

Standards (AFOSR-ISSA-86-0063) , the conversion of the files from word processor

floppy disks to the local Chemical Thermodynamic Data Centers computer system was expedited by Mr. Ronen Lamden and Dr. David Neumann. The NBS BIB computer system,

written by Dr. David Neumann, Ms. Dorothy Bickham, and Mr. Robert Conyne , was used for the conversion of numerous literature formats into the form used in this

publication. The final processing of the literature citations was aided by Ms.

Cynthia Jackson and Dr. David Neumann. The assistance of Ms. Rhoda Levin in the

preparation of this article for publication, both in terms of cross-checking the

references for inclusion in the bibliographies and improving the clarity of the

work, is greatly appreciated.
JANAF THERMOCHEMICAL TABLES - BERYLLIUM BIBLIOGRAPHY

BERYLLIUM HYDROXIDE (BeOH, BeOH+)

59MAD Mader, C. L. , "Ideal gas thermodynamic properties of detonation

products", U.S At. Energy Comm. , AECU-4508 . 206pp (1959), CA 57

5364h, thermochemlcal table

60MAD Mader, C. L. , "Thermodynamic properties of detonation products",

U.S. At. Energy Comm., AECU-4508 (Suppl) . 57 pp (i960), CA 57

15891J , thermochemlcal table

62HIL/THE Hildenbrand, D. L. , Theard, L. P., "Thermodynamic properties of

rocket combustion products". Ford Motor Company, Aeronutronlc

Division, Second Quarterly Technical Progress Report, U-1546

(February 1, 1952), enthalpy of formation

62HIL/THE2 Hildenbrand, D. L. , Theard, L. P., "Thermodynamic properties of

rocket combustion products". Ford Motor Company, Aeronutronlc

Division, Final Technical Report, U-1784 (31 July 1962), enthalpy

of formation

6 3 ALT Altman, R. L. , "Thermochemistry of the beryllla-water reaction", J

Chem. Eng. Data, 8(4), 534-6 (1963), CA 60 61f, enthalpy of

formation

63HIL/THE

64GRE/YAT

64HIL

Hildenbrand, D. L. , Theard, L. P., Ju, F. , "Investigation of

thermodynamic properties of rocket combustion products". Ford Motor

Co., Aeronutronlc Division, Third Quarterly Report, U-2231 (1

Aprll-30 June, 1963), enthalpy of formation

Greenbaum, M. A., Yates, R. E., Blauer, J. A., Arshadl , M. , Ko , H.

C, Wong, M. , Wether, J., Farber, M. , "Study of rocket engine

exhaust products". Research and Development Laboratories RPI , Twelfth Quarterly Report, March 1 May 31, 1964, OR-7414-12

(1964) , enthalpy of formation

Hildenbrand, D. L. , "Survey of thermodynamic data for beryllium

species", Proc . Meeting Interagency Chem. Rocket Propulsion Group

Thermochem. , 1st, New York, 1963, 1, 81-6 (1964), CA 62 72f,

enthalpy of formation
JANAF THERMOCHEMICAL TABLES - BERYLLIUM BIBLIOGRAPHY

BERYLLIUM HYDROXIDE (BeOH, BeOH+)

65GRE/YAT Greenbaum, M. A., Yates, R. E., Frisch, M. A., Ko , H. C, Farber,

M. , "Thermodynamic properties of rocket exhaust products", Maremont

Corp., 1st Quarterly Report 1 August through October 1965 (1965),

enthalpy of formation

65HIL/THE Hildenbrand, D. L. , Theard, L. P., Murad, E., Ju, F.

,

"Investigation of thermodynamic properties of rocket combustion

products". Final Report, AFRPL-TR-65-95 , Philco-Ford Corporation,

Aeronutronic Division, U-3068, 75 pp (1965), CA 66 87205e, this

report is also indexed as AD-466785 and NASA Accession No.

N65-29905

66BLA/GRE Blauer, J., Greenbaum, M. A., Farber, M. , "The thermodynamic and

physical properties of beryllium compounds. IX. The free energy of

formation of beryllium hydroxide (g)", J. Phys . Chem. , 70(4)

.

973-7 (1966) , CA 64 16721g, possibly derive enthalpy of formation

value

66FAR/GRE Farber, M. , Greenbaiim, M. A., Frisch, M. A., Ko , H. C, Marantz , L. B. , Chai , B., Grenier, G., Yates, R. , "Investigation of the

thermodynamic properties of rocket exhaust products". Final Report,

AFRPL-TR-66-220 (1966), enthalpy of formation

66GRE/FRI Greenbaum, M. A., Frisch, M. A., Ko , H. C, Marantz, L. B., Chai,

B. J., Farber, M. , "Thermodynamic properties of rocket exhaust

products", Maremont Corp., 3rd Quarterly Report, 1 February 1966

through 30 April 1966 (1966), enthalpy of formation

66GRE/YAT Greenbaum, M. A., Yates, R. E., Frisch, M. A., Ko, H. C, Marantz,

L. B. , Farber, M. , "Thermodynamic properties of rocket exhaust

products", Maremont Corp., 2nd Quarterly Report, 1 November through

31 January 1966 (1966), enthalpy of formation

67BOY/INA Boyer, M. H. , Inami , Y. H. , Ju, F. , "Investigation of thermodynamic

properties of rocket combustion products", 5th Quarterly Technical

Report, AFRPL-TR-67-108, Philco-Ford Corporation, Aeronutronic

Division, U-4024 (1967), enthalpy of formation

67BOY/INA2 Boyer, M. H. , Inami, Y. H., Potter, N. D., Ju, F. , "Investigation

of thermodynamic properties of rocket combustion products", Final

Technical Report, AFRPL-TR-67-212 , Philco-Ford Corporation,

Aeronutronic Division, U-4109 (1967) , enthalpy of

formation
JANAF THERMOCHEMICAL TABLES - BERYLLIUM BIBLIOGRAPHY

BERYLLIUM HYDROXIDE (BeOH, BeOH+)

67FAR/GRE Farber, M. , Greenbaum, M. A., Frisch, M. A., Ko , H. C, Chai, B.,

"Thermodynamic properties of several high temperature species:

HBO(g), BeOH(g), AlCl2(g), and Al2Cl4(g) " , Interagency

Chemical Rocket Propulsion Group, Thermochemistry Working Group,

Fifth Meeting Bulletin, CPIA Publication, 1(146), 31-58 (1967),

enthalpy of formation

67KO/GRE Ko, H. C., Greenbaum, M. A., Farber, M. , "The thermodynamic and

physical properties of beryllium compounds. XI. The heat of

formation and entropy of beryllium hydroxide", J. Phys . Chem.

71(6), 1875-9 (1967), CA 67 6285b, enthalpy of formation

67MAY/SCH Mayer, S. W. , Schieler, L. , Johnston, H. S., "Computation of

high- temperature constants for bimolecular reactions of combustion

species", 11th Symp . Combust. 1966, 11, 837-44 (1967), CA 69

5606m, rate data

67POT Potter, N. , "Recent thermochemical studies". Interagency Chemical

Rocket Propulsion Group, Thermochemistry Working Group, Fifth

Meeting Bulletin (1967) CPIA Publication, 1(146), 15-30 (1967),

enthalpy of formation

68INA/JU Inami , Y. H., Ju, F. , "Thermodynamic properties of rocket

combustion products", 1st Quarterly Technical Report,

AFRPL-TR-68-39, Philco-Ford Corp., Aeronutronic Division, U-4387

(1968) , enthalpy of formation

68INA/JU2 Inami, Y. H. , Ju, F., "Thermodynamic properties of rocket

combustion products", 2nd Quarterly Technical Report,

AFRPL-TR-68-78, Philco-Ford Corp., Aeronutronic Division, U-4352

(1968) , enthalpy of formation

69POT/INA Potter, N. D., Inami, Y. H., Ju, F. , "Some recent thermochemical

studies at Aeronutronic", Interagency Chemical Rocket Propulsion

Group Thermochemistry Working Group, 7th Meeting Bull. CPIA

Publication, 1(189), 237-45 (1969), enthalpy of formation

71JAC Jackson, D. D., "Thermodynamics of the gaseous hydroxides". Report,

UCRL-51137 . 141 pp (1971), CA 77 93702h, thermochemical table

76BRO/WEL Brom, J. M. , Jr., Weltner, W. , Jr., "ESR spectrum of the beryllium

hydroxide (BeOH) molecule", J. Chem. Phys., 64(9), 3894-5 (1976),

CA 85 12107h, structure and electronic configuration

10
JANAF THERMOCHEMICAL TABLES - BERYLLIUM BIBLIOGRAPHY

BERYLLIUM HYDROXIDE (BeOH, BeOH+)

79CHA/ZYU Charkin, 0. P., Zyubina, T. S., "Some regularities in a change in

the characteristics of potential surfaces for light-weight element

hydroxides based on data from ab initio calculations", Zh. Neorg.

Khim. , 24(11), 2877-81 (1979), CA 92 203832v, Eng. transl., Russ

.

J. Inorg. Chem. 24(11), 1598-1600 (1979), structure and ionization

potential

79ZYU/CHA Zyubina, T. S., Charkin, 0. P., "Calculations of potential surfaces

of AOH-HAO intramolecular rearrangements in lithium, beryllium, and

boron hydroxide", Zh. Neorg. Khim., 24(10), 2595-600 (1979), CA

91 217037f, Eng. transl., Russ. J. Inorg. Chem. 24(10), 1441-4

(1979) , structure and ionization potential

80HIN Hinchliffe, A., "Structure and electronic properties of the

radicals BeOH and MgOH" , J. Mol. Struct., 64, 289-92 (1980), CA

93 32094V, structure

81SLI/S0L Sliznev, V. V., Solomonik, V. G., Krasnov, K. S., "Study of the

applicability of the PPDP/2 method to calculate dipole moments of some inorganic molecules" , Deposited document SPSTL, 334 . khp-D81, 15 pp (1981), CA 97 118997m

82ABA/DEM Abashkin, Yu. G., Dement'ev, A. I., "Calculation of spectroscopic

constants of beryllium hydroxide (BeOH) and magnesium hydroxide

(MgOH) molecules and beryllium hydroxide (1+) and magnesium

hydroxide (l-l-) ions in an SCF approximation", Zh. Strukt. Khim.,

23(1), 179-80 (1982), CA 97 14115f, Eng. transl., J. Struct.

Chem. 23(1), 152-4 (1982), structure and vibrational frequencies

84RAM/ABA Rambidi, N. G., Abashkin, Yu. G., Dement'ev, A. I., "Electronic

structure and properties of lithium, sodium, beryllium, and

magnesium hydroxides", Zh. Neorg. Khim., 29(12), 3009-13 (1984),

CA 102 67582J , Eng. transl., Russ. J. Inorg. Chem. 29(12), 1719-22

(1984) , structure (calc) and vibrational frequencies (calc)

85PAL/KIR Palke, W. E., Kirtman, B., "Calculations of the bending potentials

of magnesium hydroxide (MgOH) and beryllium hydroxide (BeOH)",

Chem. Phys. Lett., 117(5), 424-6 (1985), CA 103 93168u

86BAU/LAN Bauschlicher , C.W., Jr., Langhoff, S.R., Partridge, H., "Ab initio

study of the alkali and alkaline-earth monohydroxides" , J. Chem.

Phys., 84(2), 901-9 (1986), CA104(10) : 75442v, structure,

vibrational frequencies, dissociation energy

11
JANAF THERMOCHEMICAL TABLES - BERYLLIUM BIBLIOGRAPHY

BERYLLIUM HYDROXIDE (BeOH, BeOH+)

86PAR/LAN Partridge, H. , Langhoff, S.R., Bauschlicher , C.W., Jr., "Ab initio

calculations on the positive ions of the alkaline earth oxides,

fluorides, and hydroxides" , J. Chem. Phys . , 84(8), 4489-96

(1986), CA105(2) :14349u, ionization potential

12
JANAF THERMOCHEMICAL TABLES - MAGNESIUM HYDROXIDE

MAGNESIUM HYDROXIDE (MgOH, MgOH+)

57GAY Gaydon, A. G. , "Laboratory production and assignment of spectra of

alkaline earth hydroxides and oxides", Mem. soc. roy. sci. Liege,

18, 507-12 (1957), CA 51 16093e, spectra

59BUL/SUG Bulewicz, E. M. , Sugden, T. M. , "Determination of the dissociation

constants and heats of formation of molecules by flame photometry.

V. Stabilities of MgO and MgOH", Trans. Faraday Soc, 55, 720-9

(1959), CA 54 5219b, spectra and dissociation energy

59PES/GAY Pesic, D., Gaydon, A. G., "Band spectra of magnesium oxide between

4000 and 3600 A", Proc. Phys . Soc. (London), 73, 244-9 (1959), CA

57 5471f, spectra

61TRA Trajmar, S., Ph. D. Thesis, Univ. California,

Berkeley, UCRL-9773 (1961)

62BRE/TRA Brewer, L. , Trajmar, S., "Ultraviolet bands of magnesium hydroxide

and oxide", J. Chem. Phys., 36(6), 1585-7 (1962), CA 57 5471f,

spectra

62SUG Sugden, T. M. , "Excited species in flames", Ann. Rev. Phys. Chem.,

13, 369-90 (1962), CA 58 1915e, review of flame spectra

63BUE Buell, B. E., "Limited-area flame spectrometry- chemiluminescence "

,

Anal. Chem., 35, 372-82 (1963), CA 58 10867h, chemiluminescence

63ZHI/LYU Zhitkevich, V. F. , Lyutyi, A. I., Nesterko, N. A., Rossikhin, V.

S., Tsikora, I. L. , "Spectroscopic study of dissociation and

ionization processes in the flame", Optika i Spektroskopiya,

14(1), 35-8 (1963), CA 58 7504c, Eng. transl.. Opt. Spectrosc.

14(1), 17-9 (1963), spectra

69COT/JEN Cotton, D. H. , Jenkins, D. R. , "Bond-dissociation energy of gaseous

magnesium oxide". Trans. Faraday Soc, 65(2), 376-9 (1969), CA 70

82538p, dissociation energy

71JAC Jackson, D. D., "Thermodynamics of the gaseous hydroxides", Report,

UCRL-51137 . 141 pp (1971), CA 77 93702h, thermochemical table

13
JANAF THERMOCHEMICAL TABLES - MAGNESIUM HYDROXIDE

MAGNESIUM HYDROXIDE (MgOH, MgOH+)

73BRO/WEL Brom, J. M. , Jr., Weltner, W. , Jr., "ESR spectrum and structure of

the magnesium hydroxide radical", J. Chem. Phys . , 58.(12), 5322-30

(1973), CA 79 47572J , structure

73ROZ/GUT Rozhdestvenskii, I. B., Gutov, V. N., Zhigul' skaya, N. A.,

"Approximation coefficients of the thermodynamic potential for

substances formed by aluminum, boron, carbon, calcium, chlorine,

copper, fluorine, hydrogen, potassium, lithium, magnesium,

nitrogen, sodium, oxygen, phosphorus, sulfur, silicon, and titanium

atoms in a temperature range up to 6000 K" , Sb . Tr . Glavniiproekt

Energ. Inst., 7, 88-121 (1973), CA 85 83876u

76MIR/KAI Mirodatos, C, Kais , A. A., Vedrine, J. C., Pichat, P., Barthomeuf,

D. , "Correlations of cracking properties of magnesium-yttrium

zeolites with their acidic and basic sites", J. Phys. Chem.,

80(21), 2366-71 (1976), CA 85 195026y, spectra

76MIR/PIC- Mirodatos, C, Pichat, P., Barthomeuf, D., "Generation of

catalytically active acidic OH groups upon CO2 neutralization

of basic sites in Mg- and Ca-Y zeolites", J. Phys. Chem., 80(12)

1335-42 (1976)

77CLE/WYC Clegg, R. , Wyckoff, S., "Calcium chloride in cool stars", Mon. Not.

R. Astron. Soc, 179(2), 417-32 (1977), CA 87 31743v,

dissociative equilibrium in cool stars

78MAE/SAS Maeda, E., Sasamato, T., Sata, T., "Vaporization from magnesia in

oxygen-water atmospheres", Yogyo Kyokai Shi, 86(10), 492-9

(1978), CA 90 142409X, no MgOH data, only calculation

80HIN Hinchliffe, A., "Structure and electronic properties of the

radicals BeOH and MgOH", J. Mol. Struct., 64, 289-92 (1980), CA

93 32094V, structure

80MUR Murad, E. , "Mass spectrometric study of the thermochemical

properties of gaseous MgOH", Chem. Phys. Lett., 72(2), 295-6

(1980), CA 93 189639n, dissociation energy

80ZYU/CHA Zyubina, T. S., Charkin, 0. P., "Calculation of the structure and

relative stability of AOH and HAO isomers of triatomic sodium,

magnesium, and aluminum hydroxides by an ab-initio method", Zh.

Neorg. Khim., 25(3), 609-14 (1980), CA 92 220819p, Eng. transl.,

Russ. J. Inorg. Chem. 25(3), 335-8 (1980), structure and ionization

potential

14
JANAF THERMOCHEMICAL TABLES - MAGNESIUM HYDROXIDE

MAGNESIUM HYDROXIDE (MgOH, MgOH+)

81MUR Murad, E., "Thermochemical properties of the gaseous alkaline earth

monohydroxides" , U. S. Air Force Geophysical Laboratory,

AFGL-TR-81-0284 . 7 pp (1981), dissociation energy, appearance

potential, structure

81MUR2 Murad, E., "Thermochemical properties of the gaseous alkaline earth

monohydroxides", J. Chem. Phys . , 75(8), 4080 (1981), CA 95

176745X, dissociation energy

81R0W/FAH Rowe, B. R. , Fahey, D. W. , Ferguson, E. E., Fehsenfeld, F. C.,

"Flowing afterglow studies of gas phase magnesium ion chemistry",

J. Chem. Phys., 75(7), 3325-8 (1981), CA 95 176477m

82ABA/DEM Abashkin, Yu. G., Dement'ev, A. I., "Calculation of spectroscopic

constants of the molecules beryllium hydroxide (BeOH) and magnesium

hydroxide (MgOH) and the beryllium hydroxide (+) and magnesium

hydroxide (+) ion in the SSP approximation", Zh. Strukt. Khim.

,

23(1), 179-80 (1982), CA 97 14115f, Eng. transl., J. Struct.

Chem. 23(1), 152-4 (1982), structure and frequencies

82SOK Sokalski, W. A., "Improved procedure for analysis of electron

density redistribution in molecular complexes", J. Chem. Phys.,

77(9), 4529-41 (1982), CA 97 203402h, structure (calc) of MgOH+

82UPP/STA Uppal, J. S., Staley, R. H. , "Reactions of aluminum (+) and

magnesium (+) ions with alcohols and organic halides in the gas

phase", J. Amer. Chem. Soc, 104(5), 1229-34 (1982), CA 96

104337p

84RAM/ABA Rambidi, N. G., Abashkin, Yu. G., Dement'ev, A. I., "Electronic

structure and properties of lithium, sodium, beryllium, and

magnesium hydroxides", Zh. Neorg. Khim., 29(12), 3009-13 (1984),

CA 102 67582J , Eng. transl., Russ. J. Inorg. Chem. 29(12), 1719-22

(1984) , structure (calc) and vibrational frequencies (calc)

85HU/CHE Hu, F. , Chen, X., Xiao, B., "Characteristics of 3-dimensional

distribution of lA and IIA element species in air-acetylene flame"

Kexue Tongbao (Foreign Lang. Ed.), 30(6), 851 (1985), CA 103

171043r

85PAL/KIR Palke, W. E., Kirtman, B., "Calculations of the bending potentials

of magnesium hydroxide (MgOH) and beryllium hydroxide (BeOH)",

Chem. Phys. Lett., 117(5), 424-6 (1985), CA 103 93168u

15
JANAF THERMOCHEMICAL TABLES - MAGNESIUM HYDROXIDE

MAGNESIUM HYDROXIDE (MgOH, MgOH+)

86BAU/LAN Bauschlicher , C.W., Jr., Langhoff, S.R., Partridge, H. , "Ab initio

study of the alkali and alkaline -earth monohydroxides" , J. Chem.

Phys., 84(2), 901-9 (1986), CA104(10) : 75442v, structure,

vibrational frequencies, dissociation energy

86PAR/LAN Partridge, H. , Langhoff, S.R., Bauschlicher, C.W. , Jr., "Ab initio

calculations on the positive ions of the alkaline earth oxides,

fluorides, and hydroxides" , J. Chem. Phys., 84(8), 4489-4496

(1986), CA105(2) :14349u, ionization potential

86SCH/GOD Schilling, J. B., Goddard, W.A. , III, Beauchamp , J. L.

,

"Theoretical studies of transition-metal hydrides. 1. Bond energies

for MH+ with M - Ca, Sc, Ti, V, Cr, Mn, Fe , Co, Ni , Cu, and

Zn", J. Am. Chem. Soc . , 108(4), 582-4 (1986), CA104(12) : 95921d,

dissociation energy

xxNI/HAR Ni, Y. , Harris, D. 0., "The structure of the alkaline earth

monohydroxides, MgOH and MgOD" , J. Mol. Spectrosc. (xxxx) , to be

published

16
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

5 5 GAY Gaydon, A. G. , "Green and orange band spectra of CaOH, CaOD, and

calcium oxide", Proc. Roy. Soc. (London), A231, 437-45 (1955), CA

50 674b, band spectra and geometry

55JAM/SUG James, C. G., Sugden, T. M. , "New identification of the flame

spectra of the alkaline earth metals". Nature, 175 . 333-4 (1955),

CA 49 10055c, flame spectra

55LAG/HUL Lagerqvist, A. , Huldt, L. , "Carriers of flame spectra of alkaline

earth metals" , Naturwissenschaften, 42, 365-6 (1955), CA 50

11109b, flame spectra

55SUG/WHE Sugden, J. M. , Wheeler, R. C, "The ions produced by traces of

alkaline earth metals in hydrogen flames". Disc. Faraday Soc,

19, 76-86 (1955), CA 49 8330h, enthalpy of formation

56CHA/GAY Charton, M. , Gaydon, A. G., "Band spectra emitted by strontium and

barium in arcs and flames", Proc. Phys . Soc. (London), 69A , 520-6

(1956), CA 51 78h, spectra

56HUL/LAG Huldt, L. , Lagerqvist, A., "The origin of the band spectra of

calcium and strontium", Arkiv Fysik, 11, 347-56 (1956), CA 51

7850g, spectra

56SUG Sugden, T. M. , "Determination of the dissociation constants and

heats of formation of molecules by flame photometry. Part I. Equilibrium in flame gases and general kinetic considerations",

Trans. Faraday Soc, 52(11), 1465-75 (1956), enthalpy of

formation, spectra

57GAY Gaydon, A. G., "Laboratory production and assignment of spectra of

alkaline earth hydroxides and oxides", Mem. soc. roy. sci. Liege,

18, 507-12 (1957), CA 51 16093e, spectra

57VEI Veits, I. v., "Determination of energies of dissociation of the

monoxides of rare-earth metals on the basis of measurements of

intensities of resonance lines of atoms of metals in the flame

spectra". Candidates Dissertation, Moscow, (1957), dissociation

energy, structure

17
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

57VEI/GUR Veits, I. V., Gurvlch, L. V., "Bond energy in the molecules of CaOH

and SrOH", Optika i Spektroskoplya, 2(2), 274-6 (1957), CA 52

14323e, bond energy

62REI/SUG Reid, R. W. , Sugden, T. M. , "Electronic excitation of metallic

hydroxides MOH in hydrogen flame gases", Disc. Faraday Soc ., 33 . 213-27 (1962), CA 58 11993a, enthalpy of formation

62SUG Sugden, T. M., "Excited species in flames", Ann. Rev. Phys . Chem.

,

13, 369-90 (1962), CA 58 1915e, review of flame spectra

63BUE Buell, B. E., "Limited-area flame spectrometry- chemiluminescence"

,

Anal. Chem., 35, 372-82 (1963), CA 58 10867h, chemiluminescence

63ZHI/LYU Zhitkevich, V. F. , Lyutyi , A. I., Nesterko, N. A., Rossikhin, V.

S., Tsikora, I. L. , "Spectroscopic study of dissociation and

ionization processes in the flame", Optika i Spektroskoplya,

14(1), 35-8 (1963), CA 58 7504b, Eng. transl., Opt. Spectrosc.

14(1), 17-9 (1963), flame spectra

65RYA/GUR Ryabova, V. G., Gurvich, L. V., "Energy of metal -hydroxyl bond in

molecules Ca-OH, Sr-OH, and Ba-OH" , Teplof iz . Vysokikh Temperatur

Akad. Nauk SSSR, 3(2), 318-21 (1965), CA 63 7664a, Eng. transl..

High Temp. 3(2), 284-7 (1965), enthalpy of dissociation

66HAU Hauge, R. H., Ph. D. Thesis, Univ. California,

Berkeley,, 1966. (1966)

66SUG/SCH Sugden, T. M. , Schofield, K. , "Heats of dissociation of gaseous

alkaline earth dyhydroxides" , Trans. Faraday Soc, 62(3), 566-75

(1966), CA 64 11950b, indirect information

67VEI/GUR Veits, I. V., Gurvich, L. V., "Absorption spectra of the molecules

of substances not readily volatile and of radicals in shock waves",

Dokl. Akad. Nauk SSSR, 173(6), 1325-7 (1967), CA 67 69103m, Eng.

transl., Dokl. Chemistry 173(4-6), 377-80 (1967), absorption

spectra

68BRE/HAU Brewer, L. , Hauge, R. , "Near infrared bands of diatomic CaO and

SrO", J. Mol. Spectrosc, 25(3), 330-9 (1968), CA 68 91361m,

spectra

18
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

68COT/JEN Cotton, D. H., Jenkins, D. R. , "Dissociation energies of gaseous

alkaline earth hydroxides" , Trans. Faraday Soc, 64(11) > 2988-97

(1968), CA 70 7135b, dissociation energy

68JEN2 Jensen, D. E., "Production of electrons from alkaline earths in

flames - equilibrium and kinetic considerations". Combust. Flame,

12(3), 261-8 (1968), CA 69 46378g, enthalpy of formation (CaOH+)

69NES/ROS Nesterko, N. A., Rossikhin, V. S., Tsikora, I. L. , "Effect of a constant electric field on the emission spectra of alkaline earth

metals in a flame", Spektrosk. At. Mol.', Egorov, Yu. P., Ed., Izd.

Naukova Dumka, Kiev, USSR, 9-14 (1969), CA 74 17679d, spectra

69RYA/GUR Ryabova, V. G., Gurvich, L. V., "Energy of a metal -hydroxyl bond in

calcium hydroxide, strontium hydroxide, and barium hydroxide

molecules", Prikl. Spektrosk. Mater. Soveshch., 16th (1965), 1,

258-62 (Pub. 1969), CA 72 70788y, dissociation energy

70PAD/KEL Padley, P. J., Kelly, R. , "Ionization potentials of alkaline earth

monohydroxides", J. Chem. Soc. D, 1970(23), 1606-7 (1970), CA 74

25142p, ionization potential

71JAC Jackson, D. D. , "Thermodynamics of the gaseous hydroxides", U. S At. Energy Comm. , UCRL-51137 . 141 pp (1971), CA 77 93702h,

thermochemical table

71KEL/PAD2 Kelly, R. , Padley, P. J., "Use of a rotating single probe in

studies of ionization of additives to premixed flames. Part 4.

Alkaline earths and uranium", Trans. Faraday Soc, 67.(5), 1384-96

(1971), CA 75 10845s, ionization potential

71NES/R0S Nesterko, N. A., Rossikhin, V. S., Tsikora, I. L. , "Effect of an electrical field on emission spectra of a salt-containing flame

plasma", Khim. Fiz . Nizkotemp. Plasmy, Tr . Mezhvus . Konf., 1st

(1970), 162-5 (1971), CA 76 92441q, emission spectra

72HAY/KIT Hayhurst, A. N., Kittleson, D. B., "Kinetics of gas phase reactions

of calcium and strontium hydroxide ions", J. Chem. Soc., Chem.

Commun.(7), 422-3 (1972), CA 77 25327q, ionization potential

72HAY/KIT2 Hayhurst, A. N. , Kittleson, D. B., "Ionization potentials of

calcium hydroxide and strontium hydroxide", Combust. Flame,

19(2), 306-8 (1972), CA 78 47945n, ionization potential

19
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

72PES Pesch, P., "CaOH, a new triatomic molecule in stellar atmospheres",

Astrophys. J., 174(3), Pt.2, L155-L156 (1972), CA 77 41223h,

spectra

72RYA/KHI Ryabova, V. G., Khltrov, A. N., Gurvich, L. V., " Spec trophotome trie

determination of molecule dissociation energies. III. Calcium

monochloride , calcium dichloride, calcium monohydroxide , calcium

hydroxide chloride, barium monochloride, barium dichloride, barium

monohydroxide, and barium hydroxide chloride", Teplofiz. Vys

.

Temp., 10(4), 744-9 (1972), CA 77 131547w, Eng. transl., High

Temp, 10(4), 669-73 (1972), dissociation energy

73KAL/ALK Kalff, P. J., Alkemade , C. Th. J., "Determination of dissociation

energies for some alkaline earth (hydro-) oxides in carbon

monoxide-nitrous oxide flames", J. Chem. Phys .

, ^(5), 2572-9

(1973), CA 79 150172c, dissociation energy

73ROZ/GUT Rozhdestvenskii, I. B., Gutov, V. N. , Zhigul ' skaya, N. A.,

"Approximation coefficients of the thermodynamic potential for

substances formed by aluminum, boron, carbon, calcium, chlorine,

copper, fluorine, hydrogen, potassium, lithium, magnesium,

nitrogen, sodium, oxygen, phosphorus, sulfur, silicon, and titanium

atoms in a temperature range up to 6000 K" , Sb . Tr . Glavniiproekt

Energ. Inst., 7, 88-121 (1973), CA 85 83876u

73VAN/HOL Van der Hurk, J., Hollander, Tj . , Alkemade, C. Th. J.,

"Identification of the emitters of some visible alkaline -earth

bands in flames", J. Quant. Spectrosc. Radiat. Transfer, 13(3),

273-88 (1973), CA 78 90604n, emission bands , review

74GRI/KIY Gritsyna, V. V., Kiyan, T. S., Logachev, Yu. E., Fogel, M. Ya. , "On

the Iviminescence of molecular particles knocked- out from the

surface of metals by a beam of ions with an energy of 30 keV"

,

Vzaimodeistvie At. Chastits Tverd. Telom. Dokl . Vses. Konf. 3rd,

2, 7-9 (1974) , CA 84 97327g

74KAL/ALK Kalff, P. J., Alkemade, C. Th. J., "Erratum on determination of

dissociation energies for some alkaline earth (hydro-) oxides in

CO/N2O flames", J. Chem. Phys., 60(4), 1698 (1974),

dissociation energy

75HUM/ZEE Human, H. G. C, Zeegers , P. J. Th. , "Molecular fluorescence of

CaOH, SrOH, and BaCl in flames", Spectrochim. Acta Part B,

30B(6-7), 203-9 (1975), CA 83 170229n, spectra

20
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

76MIR/PIC Mirodatos, C, Pichat, P., Barthomeuf, D., "Generation of

catalytically active acidic OH groups upon CO2 neutralization

of basic sites in Mg- and Ca-Y zeolites", J. Phys . Chem. , 80(12)

.

1335-42 (1976)

77BEN/SLA Benard, D. J., Slafer, W. D. , Hecht, J., "Chain reaction

chemiluminescence of alkaline earth catalyzed N2O-CO flames",

J. Chem. Phys., 66(3), 1012-6 (1977), CA 86 113285r

77CLE/WYC Clegg, R. , Wyckoff, S., "Calcium chloride in cool stars", Mon. Not.

R. Astron. Soc, 179(2), 417-32 (1977), CA 87 31743v,

dissociative equilibrium in cool stars

77STA/RYA Starovoitov, E. M. , Ryabova, V. G., Gurvich, L. V., Khitrov, A. N.

,

Nazarenko, I. I., Belyaev, A. V., "Spectrometric determination of

dissociation energies of molecules. V. Alkaline earth metal

hydroxides (CaOH and Ca(0H)2) and calcium oxide", Teplofiz.

Vys. Temp., 15(4), 909-11 (1977), CA 87 157905t, Eng. transl.,

High Temp. 15(4), 770-2 (1977), dissociation energy

78ABD/KAB Abdallah, A. M. , Kabil, M. A., "Analysis of calcium by flame

emission of the calcium hydroxide band - Part I. Interference

effects of some metals", Indian J. Chem. Sect. A, 16A (11) . 949-51

(1978), CA 90 132295t

78ABD/KAB2 Abdallah, A. M. , Kabil, M. , "Effect of acids on the emission of the

calcium hydroxide (CaOH) band", Chem. Anal. (Warsaw), 23(6)

.

1007-11 (1978), CA 90 197059p

78BLA/MER Blackburn, M. B. , Mermet, J. M. , Winefordner, J. D. , "CW-laser

excited molecular fluorescence of species in flames", Spectrochim.

Acta Part A, 34A(9) , 847-52 (1978), CA 90 143696a, spectra

78JEN/J0N Jensen, D. E., Jones, G. A., "Alkaline earth flame chemistry",

Proc. Roy. Soc. (London), *A364(1719) , 509-35 (1978), CA 90

124079k, ionization potential

78WEE/HAR Weeks, S. J., Haraguchi , H., Winefordner, J. D., "Laser-excited

molecular fluorescence of calcium hydroxide (CaOH) in an airacetylene flame", J. Quant. Spectrosc. Radiat. Transfer,

19(6), 633-40 (1978), CA 89 155074p, A-X and B-X system

79DAI Daidoji, H., "Spectral interferences in atomic absorption

spectrometry. IV. Molecular absorption spectra of calcium salts"

Bunko Kenkyu, 28(3), 145-51 (1979), CA 91 184412u

21
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

80DOW/SHA Downey, S. W. , Shabushnig, J. G., Hleftje, G. M. , "Reduction of

spectral interferences in flame emission spectrometry by selective

spectral-line modulation", Anal. Chim. Acta, 121, 165-74 (1980),

CA 94 95132X

80HU/WAN Hu, F. , Wang, S. L. , Liu, C. C, "Application of three-dimensional

tables. Optimization of atomic absorption determination of lithium

and barium and strontium hydroxide (SrOH) and calcium hydroxide

(CaOH) interference in air-acetylene flame", K'o Hsuch Tung Pao,

25(10), 446-9 (1980), CA 93 160578t

80SPI Spitzer-Aronson, M. , "Layers and profiles of SiOH, CaOH, and KOH

polyatomic ion groups found in the glass, as an effect of a special

corrosion", J. Non-Cryst. Solids, 38-39 (2) . 613-17 (1980), CA 93

209015y

81MUR Murad, E. , "Mass spectrometric measurement of thermochemcial

properties of gaseous CaOH and SrOH", 29th Ann. Conf. Mass

Spectrom. Allied Top., Minneapolis, Minn., 24-29 May 1981, 81 pp

(1981), Mass Spectrom. Bull. 16(4), section 7-3511 206 pp (1981),

dissociation energy.

81MUR2 Murad, E., "Thermochemical properties of the gaseous alkaline earth

monohydroxides" , U. S. Air Force Geophysical Laboratory,

AFGL-TR-81-0284 . 7 pp (1981), dissociation energy, appearance

potential, structure

81MUR3 Murad, E. , "Thermochemical properties of the gaseous alkaline earth

monohydroxides", J. Chem. Phys .

, 75(8), 4080 (1981), CA 95

176745x, dissociation energy, appearance potential, structure

82BUR/HAY Burdett, N. A., Hayhurst, A., "Hydration of gas-phase ions and the

measurement of boundary- layer cooling during flame sampling into a mass spectrometer", J. Chem. Soc, Faraday Trans. 1, 78(10) . 2997-3007 (1982), CA 97 205320d, spectra

82SAT/SAS Sata, T., Sasamoto, T., Matsumoto, K. , "High temperature

vaporization of calcium oxide", High Temp. -High Pressures, 14(4)

399-408 (1982), CA 99 26795g

83HIL/QIN Hilborn, R. C, Qingshi , Z., Harris, D. 0., "Laser spectroscopy of

the A-X transitions of calcium hydroxide (CaOH and CaOD)", J. Mol.

Spectrosc, 97(1), 73-91 (1983), CA 98 62579c

22
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

83MUR Murad, E. , "Abstraction reactions of calcium (1+) and strontium

(1+) ions", J. Chem. Phys . , 78(11), 6611-13 (1983), CA 99

129150x, ionization potential

83WOR/TRK Wormsbecher, R. F. , Trkula, M. , Martner, C, Penn, R. E., Harris,

D. 0. , "Chemiluminescent reactions of alkaline -earth metals with

water and hydrazine" , J. Mol. Spectrosc, 97(1), 29-36 (1983), CA

98 80891c, chemiluminescence

84BAU/PAR Bauschlicher, C. W. , Jr., Partridge, H., "On the dissociation

energy of calcium monohydroxide and lithium hydroxide", Chem. Phys.

Lett., 106(1-2), 65-8 (1984), CA 100 198078f, dissociation energy

84BEL/LEB Belyaev, V. N. , Lebedeva, N. L. , Krasnov, K. S., Gurvich, L. V.,

"Determination of radiation parameters and dissociation energies of

molecules on the basis of a spectrophotometric study of reaction

equilibria in flames. The B^S-X^S transition of calcium

hydroxide", Teplofiz. Vys . Temp., 22(5), 1008-11 (1984), CA 102

35795q, no English translation available

84BER/KIN Bernath, P. F. , Kinsey-Nielsen, S., "Dye laser spectroscopy of the

B-X transition of CaOH", Chem. Phys. Lett., 10^(6), 663-7 (1984),

CA 100 182573c, B-X absorption band

84SVY/KUZ Svyatkin, I. A., Kuznetsova, L. A., "Study of the intensities in

spectra of green and orange band systems of calciiom oxide and

calcium hydroxide molecules", VINITI , 1042-84 . 12 pp (1984), CA

102 122337k, transition probabilities and oscillator strengths

85BER/BRA Bernath, P. F. , Brazier, C. R. , "Spectroscopy of calcium hydroxide

(CaOH)", Astrophys. J., 288(1, pt.l), 373-6 (1985), CA 102

103028U

85BRA/BER Brazier, C. R. , Bernath, P. F., Kinsey-Nielson, S., Ellinboe, L. C, "Laser spectroscopy of organometallic free radicals", J. Chem.

Phys., 82(2), 1043-5 (1985), CA 102 140128x, electronic energy

levels

85HU/CHE Hu, F. , Chen, X., Xiao, B., "Characteristics of 3-dimensional

distribution of lA and IIA element species in air-acetylene flame",

Kexue Tongbao (Foreign Lang. Ed.), 30(6), 851 (1985), CA 103

171043r

23
JANAF THERMOCHEMICAL TABLES - CALCIUM HYDROXIDE

CALCIUM HYDROXIDE (CaOH, CaOH+)

85ZHU/LI Zhu, Q. , Li, M. , Wang, C, Zhang, Y. , Gong, J., Liu, J.,

"Laser- induced fluorescence spectroscopy approach of analyzing and

identifying overlapping and perturbing bands- the study of

A^n-X^E perturbing overtones of calcium hydroxide

(CaOH) radical", Kexue Tongbao (Foreign Lang. Ed.), 30(3), 346-50

(1985), CA 103 131599V

86BAU/LAN Bauschlicher , C.W., Jr., Langhoff, S.R., Partridge, H. , "Ab initio

study of the alkali and alkaline -earth monohydroxides" , J. Chem,

Phys., 84(2), 901-9 (1986), CA104(10) : 75442v, structure,

vibrational frequencies, dissociation energy

86BER Bernath, P. F. , "Laser and Fourier transform spectroscopy:

diatomics to organometallics" , AIP Conf. Proc .

, Adv. Laser Sci.

1, 146, 443-6 (1986), CA105(20) : 180779d, fluorescence spectra

86BRA/BER Brazier, C. R. , Bernath, P. F. , Kinsey-Nielsen, S., Ellingboe, L. C, Bopegedera, A. M. R. P., "Laser spectroscopy of organometallic

free radicals", NBS Spec. Publ. (U. S.), 716, 102-17 (1986),

CA105(18) :161330j , electronic energy levels, vibrational

frequencies

86KRU/WIN Krupa, R. J., Winefordner, J. D., "Power dependencies of ICP

absorption, emission, and fluorescence signals for the extended

sleeve torch", Spectrochim. Acta, Part B, 41B(9) , 1015-21 (1986),

CA105(20) : 182883g, absorption and emission spectra

86PAR/LAN Partridge, H. , Langhoff, S.R., Bauschlicher, C.W., Jr., "Ab initio

calculations on the positive ions of the alkaline earth oxides,

fluorides, and hydroxides" , J. Chem. Phys., 84(8), 4489-96

(1986), CA105(2) :14349u, ionization potential

24
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

55JAM/SUG James, C. G., Sugden, T. M. , "New identification of the flame

spectra of the alkaline earth metals", Nature, 175 . 333-4 (1955),

CA 49 10055c, flame spectra

55LAG/HUL Lagerqvist, A., Huldt, L. , "Carriers of flame spectra of alkaline

earth metals", Naturwissenschaften, 42, 365-6 (1955), CA 50

11109b, flame spectra

55SUG/WHE Sugden, T. M. , Wheeler, R. C, "The ions produced by traces of

alkaline earths in hydrogen flames". Disc. Faraday Soc .

, 19 . 76-86 (1955), CA 49 8330h, enthalpy of formation

56CHA/GAY Charton, M. , Gaydon, A. G., "Band spectra emitted by strontium and

barium in arcs and flames", Proc. Phys . Soc. (London), 69A . 520-6

(1956), CA 51 78h, spectra

56HUL/LAG Huldt, L. , Lagerqvist, A., "The origin of the band spectra of

calcium and strontium", Arkiv Fysik, 11, 347-56 (1956), CA 51

7850g, spectra

56SUG Sugden, T. M. , "Determination of the dissociation constants and

heats of formation of molecules by flame photometry. Part I. Equilibrium in flame gases and general kinetic considerations",

Trans. Faraday Soc, 52, 1465-75 (1956), enthalpy of formation,

spectra

57GAY Gaydon, A. G. , "Laboratory production and assignment of spectra of

alkaline earth hydroxides and oxides", Mem. soc. roy. sci. Liege,

18, 507-12 (1957), CA 51 16093a, spectra

57GUN/ZEI Gunther, P., Zeil, W. , Grisar, U. , Heim, E., "Experiments on sono luminescence of aqueous solutions", Z. Elektrochem. , 61,

188-201 (1957), CA 52 2561a, spectra

57VEI Veits, I. v., "Determination of energies of dissociation of the

monoxides of rare-earth metals on the basis of measurements of

intensities of resonance lines of atoms of metals in the flame

spectra", Candidates' Dissertation, Mosocw (1957), dissociation

energy, structure

25
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

57VEI/GUR Veits, I. V., Gurvich, L. V., "Bond energy in the molecules of CaOH

and SrOH", Optika i Spektroskopiya, 2(2), 274-6 (1957), CA 52

14323e, bond energy

58KNE/SUG Knewstubb, P. F. , Sugden, T. M. , "Mass spectrometric observations

of ions in flames", Nature, 181 . 474-5 (1958), spectra

62REI/SUG Reid, R. W. , Sugden, T. M. , "Electronic excitation of metallic

hydroxides MOH in hydrogen flame gases". Disc. Faraday Soc, 33 . 213-27 (1962), CA 58 11993a, enthalpy of formation

62SUG Sugden, T. M. , "Excited species in flames", Ann. Rev. Phys . Chem.

,

13, 369-90 (1962), CA 58 1915e, review of flame spectra

63BUE Buell, B. E. , "Limited-area flame spectrometry- chemiluminescence "

,

Anal. Chem., 35, 372-82 (1963), CA 58 10867h, chemiliominescence

63ZHI/LYU Zhitkevich, V. F. , Lyutyi , A. I., Nesterko, N. A., Rossikhin, V.

S., Tsikora, I. L. , "Spectroscopic study of dissociation and

ionization processes in the flame", Optika i Spektroskopiya,

14(1), 35-8 (1963), CA 58 7504b, Eng. transl.. Opt. Spectrosc.

14(1), 17-9 (1963), flame spectra

65RYA/GUR Ryabova, V. G., Gurvich, L. V., "Energy of metal- hydroxy1 bond in

molecules Ca-OH, Sr-OH, and Ba-OH" , Teplofiz. Vysokikh Temperatur,

Akad. Nauk SSSR, 3(2), 318-21 (1965), CA 63 7664a, Eng. transl.,

High Temp. 3(2), 284-7 (1965), dissociation energy

66SUG/SCH Sugden, T. M. , Schofield, K. , "Heats of dissociation of gaseous

alkaline earth dihydroxides" , Trans. Faraday Soc, ^(3), 566-75

(1966), CA 64 11950c, enthalpy of formation

68COT/JEN Cotton, D. H. , Jenkins, D. R. , "Dissociation energies of gaseous

alkaline earth hydroxides" , Trans. Faraday Soc, 64(11). 2988-97

(1968), CA 70 7135b, dissociation energy

68JEN3 Jensen, D. E., "Production of electrons from alkaline earths in

flames - equilibrium and kinetic considerations". Combust. Flame,

12(3), 261-8 (1968), CA 69 46378g, ionization potential

69RYA/GUR Ryabova, V. G. , Gurvich, L. V. , "Energy of a metal -hydroxyl bond in

calcium hydroxide, strontium hydroxide, and barium hydroxide

molecules", Prikl. Spektrosk. , Mater. Soveshch. , 16th (1965), 1,

258-62 (Pub. 1969), CA 72 70788y, dissociation energy

26
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

70KEL/PAD Kelly, R. , Padley, P. J., "Ionization potentials of alkaline earth

monohydroxides", J. Chem. Soc. D, 1970 (23). 1606-7 (1970), CA 74

25142p, ionization potential

71GUR/RYA Gurvich, L. V., Ryabova, V. G., Khitrov, A. N., Starovoitov, E. "Spectrophotometric determination of dissociation energy of

molecules. I. Strontium chloride and strontium monohydroxide"

Teplofiz. Vys. Temp., 9(2), 290-4 (1971), CA 75 54201h,

Eng.transl., High Temp. 9(2), 261-4 (1971), dissociation energy

M,

71JAC Jackson, D. D. , "Thermodynamics of the gaseous hydroxides", U. S. At. Energy Comm. , UCRL-51137 . 141 pp (1971), CA 77 93702h,

thermochemical table

71KAL

71KEL/PAD3

Kalff, P. J Dissertation, Rotterdam (1971)

Kelly, R. , Padley, P. J., "Use of a rotating single probe in

studies of ionization of additives to premixed flames. Part 4.

Alkaline earths and uranium", Trans. Faraday Soc, 67.(5), 1384-96

(1971), CA 75 10845s, ionization potential

71NES/R0S Nesterko, N. A., Rossikhin, V. S., Tsikora, I. L. , "Effect of an electrical field on emission spectra of a salt-containing flame

plasma", Khim. Fiz . Nizkotemp. Plazmy. Tr . Mezhvus . Konf., 1st

(1970), 162-5 (1971), CA 76 92441q, emission spectra

71RYA/GUR Ryabova, V. G., Gurvich, L. V., Khitrov, A. N., "Spectrophotometric

determination of molecular dissociation energies. II. SrC12 and

SrOHCl", Teplofiz. Vys. Temp., 9(4), 755-9 (1971), Eng. transl..

High Temp. 9(4), 686-9 (1971), dissociation energy

72HAY/KIT Hayhurst, A. N. , Kittelson, D. B., "Kinetics of gas phase reactions

of calcium and strontium hydroxide ions", J. Chem. Soc, Chem.

Commun.(7), 422-3 (1972), CA 77 25327q, ionization potential

72HAY/KIT2 Hayhurst, A. N., Kittelson, D. B., "Ionization potentials of

calcium hydroxide and strontium hydroxide", Combust. Flame,

19(2), 306-8 (1972), CA 78 47945n, ionization potential

73KAL/ALK Kalff, P. J., Alkemade , C. T. J., "Determination of dissociation

energies for some alkaline earth (hydro-) oxides in carbon

monoxide -nitrous oxide flames", J. Chem. Phys .

, 5£(5) , 2572-9

(1973), CA 79 150172c, dissociation energy

27
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

73VAN/HOL Van der Hurk, J., Hollander, Tj .

, Alkemade , C. Th. J.,

"Identification of the emitters of some visible alkaline earth

bands in flames", J. Quant. Spectrosc . Radiat. Transfer, 13(3),

273-88 (1973), CA 78 90604n, emission bands , review

74KAL/ALK Kalff, P. J., Alkemade, C. Th. J., "Erratum on determination of

dissociation energies for some alkaline earth (hydro-) oxides in

CO/N2O flames", J. Chem. Phys . , 60(^) , 1698 (1974),

dissociation energy

7 4VAN Van der Hurk, J. H., "Origin and excitation energy of visible

alkaline earth bands in flames". University of Utrecht, Utrecht,

The Netherlands, Ph. D. Thesis (1974), electronic energy levels

74VAN/H0L Van Der Hurk, J., Hollander, Tj ., Alkemade, C. Th. J., "Excitation

energies of strontium monohydroxide bands measured in flames", J.

Quant. Spectrosc. Radiat. Transfer, 14(11), 1167-68 (1974), CA 81

172478a, electronic energy levels

75HUM/ZEE Human, H. G. C., Zeegers , P. J. Th. , "Molecular fluorescence of

CaOH, SrOH, and BaCl in flames", Spectrochim. Acta Part B,

30B(6-7), 203-9 (1975), CA 83 170229n, spectra

77BEN/SLA Benard, D. J., Slafer, W. D., Hecht, J., "Chain reaction

chemiluminescence of alkaline earth catalyzed N2O-CO flames",

J. Chem. Phys., 66(3), 1012-6 (1977), CA 86 113285r

78BLA/MER Blackburn, M. B., Mermet, J. M. , Winefordner, J. D., "CW-laser

excited molecular fluorescence of species in flames", Spectrochim.

Acta Part A, 34A(9) , 847-52 (1978), CA 90 143696a, spectra

78JEN/JON Jensen, D. E., Jones, G. A., "Alkaline earth flame chemistry",

Proc. Roy. Soc . (London), A364 . 509-35 (1978), CA 90 124079k,

ionization potential

78WEE/HAR Weeks, S. J., Haraguchi , H. , Winefordner, J. D., "Laser-excited

molecular fluorescence of calcium hydroxide (CaOH) in an air-acetylene flame", J. Quant. Spectrosc. Radiat. Transfer,

19(6), 633-40 (1978), CA 89 155074p, preliminary examination of

absorption bands

7 9 DAI Daidoj i , H., "Spectral interferences in atomic absorption

spectrometry. V. Molecular absorption spectra of strontium and

barium salts", Bunko Kenkyu, 28(3), 152-8 (1979), CA 91 184413v,

spectra

28
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

79WOR Wormsbecher , R. F. , "Spectroscopy of small metal -containing

polyatomlcs - alkllne earth monohydroxides and monoamides" , Univ.

California, Santa Barbara, Ph. D. Thesis,, 187 pp (1979), CA 93

176510a, avail. Univ. Microfilms Int., Order No. 8019852, Diss.

Abstr. B 41(3), 980 (1980)

80ABD/MOS Abdallah, A. M. , Mostafa, M. A. , "Cationic interference in the

molecular emission of strontium", Indian J. Chem. Sect. A,

19A(11), 1112-15 (1980), CA 94 149526z, spectra

80HU/WAN Hu, F. , Wang, S. L. , Liu, C. C, "Application of three-dimensional

tables. Optimization of atomic absorption determination of lithium

and barium and strontium hydroxide (SrOH) and calcium hydroxide

(CaOH) interference in air-acetylene flame", K'o Hsueh Tung Pao

,

25(10), 446-9 (1980), CA 93 160578t

81H0U/SVE Houk, R. S., Svec , H. J., Fassel, V. A., "Mass spectroraetric

evidence for suprathermal ionization in an inductively coupled

argon plasma" , Appl. Spectrosc, 15(4), 380-4 (1981), CA 95

90524r, spectra

81MUR Murad, E. , "Mass spectrometric measurement of thermochemical

properties of gaseous CaOH and SrOH", 29th Ann. Conf. Mass

Spectrom. Allied Top., Minneapolis, Minn., 24-29 May 1981, 81 pp

(1981), Mass Spectrom. Bull. 16(4), section 7-3511, 206 pp (1981),

dissociation energy

81MUR2 Murad, E. , "Thermochemical proerties of the gaseous alkaline earth

monohydroxides", U. S. Air Force Geophysical Laboratory,

AFGL-TR-81-0284 . 7 pp (1981), dissociation energy, appearance

potential, structure

81MUR3 Murad, E., "Thermochemical properties of the gaseous alkaline earth

monohydroxides", J. Chem. Phys . , 75(8), 4080 (1981), CA 95

176745x, dissociation energy, appearance potential, structure

82BEL/LEB Belyaev, V. N. , Lebedeva, N. L. , Krasnov, K. S., Gurvich, L. V.,

"Determination of optical transitions B-X probability and strontium

hydroxide (SrOH) dissociation energy by flame spectrophotometry",

Izv. Vyssh. Uchebn. Zaved. , Khim. Khim. Tekhnol ., 25(7), 834-7

(1982), CA 97 136048g, dissociation energy

29
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

82BUR/HAY Burdett, N. A., Hayhurst, A., "Hydration of gas-phase ions and the

measurement of boundary- layer cooling during flame sampling into a mass spectrometer", J. Chem. Soc . , Faraday Trans. 1, 78(10),

2997-3007 (1982), CA 97 205320d, spectra

83MUR Murad, E., "Abstraction reactions of calcium (1+) and strontium

(1+) ions", J. Chem. Phys . , 78(11), 6611-13 (1983), CA 99

129150x, ionization potential

83NAK/WOR Nakagawa, J., Wormsbecher, R. F., Harris, D. 0., "High-resolution

laser excitation spectra of linear triatomic molecules - analysis

of the B-X system of strontium hydroxide (SrOH and SrOD)", J. Mol.

Spectrosc, 97(1), 37-64 (1983), CA 98 80892d, rotational

analysis

83WOR/TRK Wormsbecher, R. F. , Trkula, M. , Martner, C, Penn, R. E., Harris,

D. 0., "Chemiluminescent reactions of alkaline -earth metals with

water and hydrazine" , J. Mol. Spectrosc, 97(1), 29-36 (1983), CA

98 80891c, chemiluminescence

84CUB/SEH Cubicciotti, D., Sehgal, B. R. , "Vapor transport of fission

products in postulated severe light water reactor accidents", Nucl,

Technol., 65(2), 26-91 (1984), CA 100 199274d

84KAU/HAU Kauffman, J. W., Hauge , R. H. , Margrave, J. L. , "Infrared matrix

isolation studies of the interactions of magnesium, calcium,

strontium, and barium atoms and small clusters with water". High

Temp. Sci., 18(2), 97-118 (1984), CA 102 71718a, spectra,

vibrational frequencies

84K0H Kohli, R. , "Thermochemical interactions of fission products in an LWR accident", Kernforschungszent . Karlsruhe, [Ber.] KfK, Int.

Meet. Therm. Nucl. React. Saf .

, 5th, 3, 1405-14 (1984), CA 103

222747h, calculations

85BRA/BER Brazier, C. R. , Bernath, P. F. , Kinsey-Nielsen, S., Ellingboe, L. C, "Laser spectroscopy of organometallic free radicals", J. Chem.

Phys., 82(2), 1043-5 (1985), CA 102 140128x, electronic energy

levels

85BRA/BER2 Brazier, C. R. , Bernath, P. F. , "Laser and Fourier transform

spectroscopy of the A^H-X^S"'" transition of

strontium hydroxide (SrOH)", J. Mol. Spectrosc, 114(1), 163-73

(1985), CA 103 203154W, structure

30
JANAF THERMOCHEMICAL TABLES - STRONTIUM BIBLIOGRAPHY

STRONTIUM HYDROXIDE (SrOH, SrOH+)

8 5 CUB Cubicciotti, D. , "Thermodynamics of vaporization of fission

products and materials under severe reactor conditions", Pure Appl

Chem., 57(1), 1-13 (1985), CA 102 121652x

85HU/CHE Hu, F. , Chen, X., Xiao, B., "Characteristics of 3-dimensional

distribution of lA and IIA element species in air-acetylene flame"

Kexue Tongbao (Foreign Lang. Ed.), 30(6), 851 (1985), CA 103

171043r

86BAU/LAN Bauschlicher , C. W. , Jr., Langhoff, S. R. , Partridge, H., "Ab

initio study of the alkali and alkaline-earth monohydroxides" , J.

Chem. Phys., 84(2), 901-9 (1986), CA104(10) : 75442v, structure,

vibrational frequencies, dissociation energy

86BER Bernath, P. F. , "Laser and Fourier transform spectroscopy:

diatomics to organometallics" , AIP Conf. Proc, Adv. Laser Sci

1, 146, 443-6 (1986), CA105(20) : 180779d, fluorescence spectra

86BRA/BER Brazier, C. R. , Bernath, P. F. , Kinsey-Nielsen, S., Ellingboe, L. C, Bopegedera, A. M. R. P., "Laser spectroscopy of organometallic

free radicals", NBS Spec. Publ. (U. S.), 716, 102-17 (1986),

CA105(18) : 161330J , electronic energy levels, vibrational

frequencies

86BRA/ELL Brazier, C. R. , Ellingboe, L. C, Bernath, P. F. , "Fourier

transform detection of laser induced fluorescence from

cyanomethylidyne and strontium monohydroxide" , NBS Spec. Publ. (U.

S.), 716, 118-26 (1986), CA105(14) : 123416J , electronic energy

levels

86PAR/LAN Partridge, H. , Langhoff, S.R., Bauschlicher, C. W. , Jr., "Ab initio

calculations on the positive ions of the alkaline earth oxides,

fluorides, and hydroxides" , J. Chem. Phys., 84(8), 4489-96

(1986), CA105(2) :14349u, ionization potential

31
JANAF THERMOCHEMICAL TABLES - BARIUM BIBLIOGRAPHY

BARIUM HYDROXIDE (BaOH, BaOH+)

55JAM/SUG James, C. G., Sugden, T. M. , "New identification of the flame

spectra of the alkaline earth metals", Nature, 175 . 333-4 (1955),

CA 49 10055c, flame spectra

55LAG/HUL Lagerqvist, A. , Huldt, L. , "Carriers of flame spectra of alkaline

earth metals", Naturwissenschaften, 42, 365-6 (1955), CA 50

11109b, flame spectra

55SUG/WHE Sugden, T. M. , Wheeler, R. C, "The ions produced by traces of

alkaline earths in hydrogen flames". Disc. Faraday Soc, 19,

76-86 (1955), CA 49 8330h, enthalpy of formation

56BUL Bulewicz , E. M. , "Flame spectrum of barium - red and infrared

bands". Nature, 177, 670-1 (1956), CA 50 lllOSi, flame spectra

56CHA/GAY Charton, M. , Gaydon, A. G. , "Band spectra emitted by strontium and

barium in arcs and flames", Proc . Phys . Soc. (London), 69A . 520-6

(1956), CA 51 78i, spectra

56SUG Sugden, T. M. , "Determination of the dissociation constants and

heats of formation of molecules by flame photometry. Part I. Equilibrium in flame gases and general kinetic considerations",

Trans. Faraday Soc, 52(11), 1465-75 (1956), enthalpy of

formation, spectra

57GAY Gaydon, A. G., "Laboratory production and assignment of spectra of

alkaline earth hydroxides and oxides", Mem. soc. roy. sci. Liege,

18, 507-12 (1957), CA 51 16093e, spectra

58KNE/SUG Knewstubb, P. F. , Sugden, T. M. , "Mass spectrometric observations

of ions in flames". Nature, 181 . 474-5 (1958), ions in flames

62REI/SUG Reid, R. W. , Sugden, T. M. , "Electronic excitation of metallic

hydroxides MOH in hydrogen flame gases", Disc. Faraday Soc, 33,

213-27 (1962), CA 58 11993a, enthalpy of formation

62SUG Sugden, T. M. , "Excited species in flames", Ann. Rev. Phys. Chem.

,

13, 369-90 (1962), CA 58 1915e, review of flame spectra

63BUE Buell, B. E., "Limited-area flame spectrometry-chemiluminescence"

Anal. Chem., 35, 372-82 (1963), CA 58 10867h, chemiluminescence

63ZHI/LYU Zhitkevich, V. F. , Lyutyi , A. I., Nesterko, N. A., Rossikhin, V.

32
JANAF THERMOCHEMICAL TABLES - BARIUM BIBLIOGRAPHY

BARIUM HYDROXIDE (BaOH, BaOH+)

S., Tsikora, I. L. , "Spectroscopic study of dissociation and

ionization processes in the flame", Optika i Spektroskopiya,

14(1), 35-8 (1963), CA 58 7504b, Eng. transl., Opt. Spectrosc.

14(1), 17-9 (1963), flame spectra

64STA/BER Stafford, F. E. , Berkowitz, J., "Mass-spectrometric study of the

reaction of water vapor with solid barium oxide", J. Cham. Phys .

,

40(10), 2963-9 (1964), CA 60 15424c, structure, dissociation

energy

65GUR/RYA Gurvich, L. V., Ryabova, V. G., "Dissociation energies of BaO and

BaOH", Optika i Spektroskopiya, 18(1), 143-5 (1965), CA 62

15602h, Eng. transl.. Opt. Spectrosc. 18(1), 76-7 (1965),

dissociation energy

65NEW Newbury, R. S., "Vapor species of the Ba-O-H system", U.S. At.

Energy Comm. , UCRL-12225-T . 70 pp (1965), CA 63 2410f, enthalpy

of formation

65NEW2 Newbury, R. S., "Vapor species of the barium- oxygen-hydrogen

system". University of California, Berkeley, Ph. D. Thesis, 73 pp

(1965), CA 64 8951e, Dissertation Abstr. 26(6), 3189 (1965), Univ.

Microfilms, Order No. 65-8223, enthalpy of formation

65RYA/GUR Ryabova, V. G. , Gurvich, L. V. , "Energy of metal -hydroxyl bond in

molecules CA-OH, Sr-OH, and Ba-OH" , Teplofiz. Vysokikh Temperatur,

Akad. Nauk SSSR, 3(2), 318-21 (1965), CA 63 7664a, Eng. transl..

High Temp. 3(2), 284 (1965), dissociation energy

66SUG/SCH Sugden, T. M. , Schofield, K. , "Heats of dissociation of gaseous

alkaline earth dihydroxides" , Trans. Faraday Soc, 62(3), 566-75

(1966), CA 64 11950b, enthalpy of formation

68COT/JEN Cotton, D. H. , Jenkins, D. R. , "Dissociation energies of gaseous

alkaline earth hydroxides" , Trans. Faraday Soc, 64(11), 2988-97

(1968), CA 70 7135b, dissociation energy

68JEN Jensen, D. E., "Production of electrons from alkaline earths in

flames - equilibrium and kinetic considerations". Combust. Flame,

12(3), 261-8 (1968), CA 69 46378g, enthalpy of formation (BaOH+)

33
JANAF THERMOCHEMICAL TABLES - BARIUM BIBLIOGRAPHY

BARIUM HYDROXIDE (BaOH, BaOH+)

69RYA/GUR Ryabova, V. G., Gurvich, L. V., "Energy of metal -hydroxyl bond in

calcium hydroxide, strontium hydroxide, and barium hydroxide

molecules", Prikl. Spektrosk. , Mater. Soveshch. 16th, (1965), 1,

258-62 (Pub. 1969), CA 72 70788y, dissociation energy

70PAD/KEL Padley, P. J., Kelly, R. , "Ionization potentials of alkaline earth

monohydroxides", J. Chem. Soc. D(23) , 1606-7 (1970), CA 74 25142p,

ionization potential

71JAC Jackson, D. D. , "Thermodynamics of the gaseous hydroxides", U. S. At. Energy Comm. , UCRL-51137 . 141 pp (1971), CA 77 93702h,

thermochemical table

71KEL/PAD Kelly, R. , Padley, P. J., "Use of a rotating single probe in

studies of ionization of additives to premixed flames. Part 4.

Alkaline earths and uranium". Trans. Faraday Soc, 62(5), 1384-96

(1971), CA 75 10845s, ionization potential

72RYA/KHI - Ryabova, V. G., Khitrov, A. N. , Gurvich, L. V., "Spectrophotometric

determination of molecule dissociation energies. III. Calcium

monochloride , calcium dichloride, calcium monohydroxide , calcium

hydroxide chloride, barium mono - chloride , barium dichloride, barium

monohydroxide, and barium hydroxide chloride", Teplofiz. Vys

Temp., 10(4), 744-9 (1972), CA 77 131547w, Eng. transl., High

Temp. 10(4), 669-73 (1972), dissociation energy

73KAL/ALK Kalff, P. J., Alkemade , C. Th. J., "Determination of dissociation

energies for some alkaline earth (hydro) oxides in carbon

monoxide-nitrous oxide flames", J. Chem. Phys . , 59.(5), 2572-9

(1973), CA 79 150172c, dissociation energy

73VAN/H0L Van der Hurk, J., Hollander, Tj .

, Alkemade, C. Th. J.,

"Identification of the emitters of some visible alkaline earth

bands in flames", J. Quant. Spectrosc. Radiat. Transfer, 13(3)

273-88 (1973), CA 78 90604n, emission bands, review

75HUM/ZEE Human, H. G. C, Zeegers , P. J. Th., "Molecular fluorescence of

calcium hydroxide, strontium hydroxide, and barium chloride",

Spectrochim. Acta Part B, 30B(6-7) , 203-9 (1975), CA 83 170229n,

spectra

77CLE/WYC Clegg, R. , Wyckoff, S., "Calcium chloride in cool stars", Mon. Not.

R. Astron. Soc, 179(2), 417-32 (1977), CA 89 31743v,

dissociative equilibrium in cool stars

34
JANAF THERMOCHEMICAL TABLES - BARIUM BIBLIOGRAPHY

BARIUM HYDROXIDE (BaOH, BaOH+)

78WEB Webster, H. A., Ill, "Improved green flares", Proc . Int. Pyrotech.

Semin. 6th, 668-76 (1978), CA 93 49722w, emission spectra

79DAO Daodoji, H. , "Spectral interference in atomic absorption

spectrometry. V. Molecular absorption spectra of strontium and

barium salts". Bunko Kenkyu, 28(3), 152-8 (1979), CA 91 184413v,

spectra

79HAR/WEE Haraguchi, H. , Weeks, S. J., Winefordner, J. D., "Selective

excitation of molecular species in flames by laser excited

molecular fluorescence", Spectrochim. Acta, Part A, 35A (5) . 391-9

(1979), CA 91 219551t, spectra

80MUR

81MUR

Murad, E., "Mass spectrometric study of the thermochemical

properties of gaseous MgOH" , Chem. Phys . Lett., 72(2), 295-6

(1980), CA 93 139693n, dissociation energy

81FAR/SRI Farber, M. , Srivastava, R. D. , "Electron impact ionization of

Ba(0H)2(g)", J. Chem. Phys., 74(4), 2160-62 (1981), CA 94

165251m, dissociation energy, ionization potential

Murad, E. , "Thermochemical properties of the gaseous alkaline earth

monohydroxides" , U. S. Air Force Geophysical Laboratory,

AFGL-TR- 81-0284 . 7 pp (1981), dissociation energy, appearance

potential, structure

81MUR2

82MUR

Murad, E. , "Thermochemical properties of the gaseous alkaline earth

monohydroxides", J. Chem. Phys., 75(8), 4080-5 (1981), CA 95

176745x, dissociation energy, appearance potential, structure

Murad, E., "The reaction of Ba+ ions with O2 and H2O" , J.

Chem. Phys., 77(4), 2057-60 (1982), CA 97 151458J , ionization

potential

83WOR/TRK Wormsbecher, R. F. , Trkula, M. , Martner, C, Penn, R. E. , Harris,

D. 0. , "Chemiluminescent reactions of alkaline -earth metals with

water and hydrazine" , J. Mol. Spectrosc, iZ(l) , 29-36 (1983), CA

98 80891c, chemiluminescence

84KAU/HAU Kauffman, J. W., Hauge , R. H. , Margrave, J. L. , "Infrared matrix

isolation studies of the interactions of magnesium, calcium,

strontium, and barium atoms and small clusters with water", High

Temp. Sci., 18(2), 97-118 (1984), CA 102 71718a, spectra

35
JANAF THERMOCHEMICAL TABLES - BARIUM BIBLIOGRAPHY

BARIUM HYDROXIDE (BaOH, BaOH+)

84K0H Kohli, R. , "Thermochemical interactions of fission products in an LWR accident", Kernforschungszent . Karlsruhe, [Ber.] KfK, Int.

Meet. Therm. Nucl . React. Saf., 5th, 3, 1405-14 (1984), CA 103

222747h, calculations

84SMI/BEL Smirnov, V. I., Belov, P. V., Latyshev, V. N., "Thermodynamic

analysis of metal -containing compounds in flames by mass spectrometry of supersonic molecular beams". Deposited Doc. VINITI

,

5035-84 . 48 pp (1984), CA 103 73415u, enthalpy of formation

85BEL/LEB Belyaev, V. N., Lebedeva, N. L. , Krasnov, K. S., Gurvich, L. V.,

"Spectrophotometric study of equilibrium of chemical reactions in

flames as a method to determine thermochemical and radiation

constants of molecules. Ionic-molecular equilibrium with

participation of barium compounds and ionization potential of

barium(I) hydroxide", Mat. Zadachi Khim. Termodin. , Edited by:

Kokovin, G. A. Nauka, Sib. Otd. : Novosibirsk, USSR, 222-36 (1985),

CA104(12) :96802c, dissociation energy

85BEL/LEB2 Belyaev, V. N., Lebedeva, N. L. , Krasnov, K. S., Gurvich, L. V.,

"Determination of molecular adiabatic ionization potentials from

spectrophotometric studies of equilibria of ion-molecular reactions

in bariiom monohydroxide flames", Zh. Fiz . Khim., 59(5), 1271-3

(1985), CA 103 59630d, Eng. transl., Russ. J. Phys . Chem. 59(5),

744-5 (1985), ionization potential

85HU/CHE Hu, F. , Chen, X., Xiao, B., "Characteristics of 3-dimensional

distribution of lA and IIA element species in air-acetylene flame",

Kexue Tongbao (Foreign Lang. Ed.), 30(6), 851 (1985), CA 103

171043r

86BAU/LAN Bauschlicher , C. W. , Jr., Langhoff, S. R. , Partridge, H., "Ab

initio study of the alkali and alkaline -earth monohydroxides" , J.

Chem. Phys., 84(2), 901-9 (1986), CA104(10) : 75442v, structure,

vibrational frequencies, dissociation energy

86BRA/BER Brazier, C. R. , Bernath, P. F. , Kinsey-Nielsen, S., Ellingboe, L.

C. , Bopegedera, A. M. R. P. , "Laser spectroscopy of organometallic

free radicals", NBS Spec. Publ. (U. S.), 716, 102-17 (1986),

CA105(18) : 161330J , electronic energy levels, vibrational

frequencies

36
JANAF THERMOCHEMICAL TABLES - BARIUM BIBLIOGRAPHY

BARIUM HYDROXIDE (BaOH, BaOH+)

86KIN/BRA Kinsey-Nielson, S., Brazier, C. R. , Bernath, P. F. , "Rotational

analysis of the B ^S"*" - X ^2+ transition of

BaOH and BaOD" , J. Chem. Phys ., 84(2), 698-708 (1986),

CA104(16) :138600t, rotational analysis

86PAR/LAN Partridge, H. , Langhoff, S. R. , Bauschlicher , C. W. , Jr., "Ab

initio calculations on the positive ions of the alkaline earth

oxides, fluorides, and hydroxides", J. Chem. Phys., 84(8),

4489-96 (1986), CA105(2) : 14349u, ionization potential

37

AU.S. GOVERNMENT PRINTING OFFICE: 1987 — 201-490/60188

NBS-114A (REV. 2-8C) U.S. DEPT. OF COMM.

BIBLIOGRAPHIC DATA

SHEET (See instructions)

1. PUBLICATION OR

REPORT NO,

NBS/TN-IZAS

2. Performing Organ. Report No. 3. Publication Date

December 1987

4. TITLE AND SUBTITLE

Thermodynamic Properties of the Alkaline Earth Metal Hydroxides (MOH)

I. Literature Citations

5. AUTHOR(S)

Malcolm W. Chase

6. PERFORMING ORGANIZATION f/ryo/nt or other thon N6S. see /n struct/on s) NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

Gaithersburg, MD 20899

7. Contract/Grant No.

8. Type of Report & Period Covered

Final

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State. ZIP)

Same as item #6 above.

10. SUPPLEMENTARY NOTES

I I Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bibliography or literature survey, mention it here)

A bibliographic collection is provided on data which are necessary for the

calculation of the thermochemical properties of the gaseous alkaline earth

metal (mono) hydroxides (MOH) and their positive ions (MOH ), where M = Be,

Mg, Ca, Sr, and Ba. This is the first in a series of articles that will

document the information used in the critical evaluation of the thermodynamic

properties for the JANAF Thermochemcial Tables. The collection contains

references which have been published through the end of 1985, with a limited

number of 1986 references. Five bibliographies are given, one for each of

the alkaline earth metals. In each bibliography, the references are listed

chronologically; alphabetically by first author within each year. The names

of the ten species are given according to the Chemical Abstracts system of

nomenclature (as of the Tenth Collective Index) . The Chemical Abstracts

Registry Numbers are also given for each of the species. A brief summary

of the type of available information is given.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by semicolons)

alkaline earth hydroxides; bibliography; electron affinity; electronic energy levels:

equilibrium data; formation properties; ionization potential; molecular structure;

review articles: thermochemistry: thermodynamic properties; vibrational treauencies

13. AVAILABILITY

[3 Unlimited

I I For Official Distribution. Do Not Release to NTIS

r I Order From Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. f^ Order From National Technical Information Service (NTIS), Springfield, VA. 22161

14. NO. OF

PRINTED PAGES

15. Price

USCOMM-DC 6043-PeO

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