November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility:

Atlanta

115 Perimeter Center Place

Axiall Corporation

225-685-2677

dave.goldsmith@axiall.com

Plaquemine

P.O. Box 629

Plaquemine

Dave Goldsmith
ers (PVC) Production Process Wastewater

State: GA Zip Code: 30346

hes, and related establishments owned): 5848

State: LA Zip Code: 70765-0629
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: P-1

Process Equipment ID: U-156

Wastewater Feed Rate (lb/hr): 20,648

Feed Temperature (°F): 183

Feed Inlet Pressure (psia): 17

Liquid Loading Rate (liters/m2): 38

Steam Feed Rate (lb/hr): 1040

Steam to Feed Ratio (kg steam/liter of wastewater): 0.049

Operating Temperature (°F): 220

Operating Pressure (psig): 2.2

Total Number of Stages: 1

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent): countercurrent

Number of Actual Trays: 10

Column Height (meters): 7.2

Year Equipment Installed: 1981

Equipment Currently Regulated Under (cite regulations): 40 CFR 61+63

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: 9663 liters/hour

 liters

m design rate or capacity, please provide those values:

13,627 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production fa

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wa

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for e

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

PVC Process 

Wastewater 

Stream ID

2
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6

Min

P-1 U-156 Steam Stripping Continuous W-4 28,800

Table 3. PVC Process Wastewater Destination Codes Table

Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment S

2 3

Min Max

Type of Process 

Wastewater 

Treatment System

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

1

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

PVC Process Wastewate

VC) Production Process Wastewater

hin the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process waste

VC production process wastewater treatment system.

ter treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC prod

tment System

4 5 6 7 8

Min Max Average

Operating Days Per 

Year

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day)
7 8 9 10 11

Max Average

86,400 61,265 Measured 350 WWT

Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

Wastewater Treatment System

4 5 6 7

Average

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Operating Days 

Per Year

Process Wastewater Destination D

water Stream Flow Rate 

ons per day)

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

VC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

eated by a PVC production process wastewater treatment system.

hat does not originate from the PVC production facility.

9 10

Originating PVC Process 

Equipment Description

Originating PVC Process 

Equipment ID
12 13

biosystem Yes

e of the wastewater treatment system

ere in the process the stream is recycled

Associated Destination 

Information

(Refer to Table 3 below)

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

11 12

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

able 1 and Column 11 of Table 2

13

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?
de a description of the process wastewaetr 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)

179601231 m,p-xylene

95476 o-xylene
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

Axiall Corporation

Plaquemine

U-156

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 0.6 Non-detect

SW-846-8015C 156

SW-846-8315A 4.15

SW-846-8315A 17.7

SW-846-8270D 0.0631 Non-detect

SW-846-8270D 3.96

SW-846-8270D 0.103 Non-detect

SW-846-8270D 1.68

SW-846-8270D 0.0349 Non-detect

SW-846-8260B 0.00092 Non-detect

SW-846-8260B 0.0024 Non-detect

SW-846-8260B 0.0045 Non-detect

SW-846-8260B 0.00047 Non-detect

SW-846-8260B 0.00046 Non-detect

SW-846-8260B 0.00109 Non-detect

SW-846-8260B 0.0033 Non-detect

SW-846-8260B 0.00205

SW-846-8260B 0.0732

SW-846-8260B 0.00058 Non-detect

SW-846-8260B 0.00318

SW-846-8260B 0.00116 Non-detect

SW-846-8260B 0.00751

SW-846-8260B 0.00418 Non-detect

SW-846-8260B 0.0167 Non-detect

Sample Date -->

suspension

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

54

50.3

01/14/13

Stripper Bottoms Wastewater

13-015-0214

01/17/13

Flow Rate Determination Method --> Measured
SW-846-8260B 0.00049 Non-detect

SW-846-8260B 0.00138 Non-detect

SW-846-8260B 0.00044 Non-detect

SW-846-8260B 0.00067 Non-detect

SW-846-8260B0

EPA Method 107 1.47

SW-846-8260B 0.00071 Non-detect

SW-846-8260B 0.0007 Non-detect

SW-846-8260B 0.00124 Non-detect

SW-846-8260B 0.00072 Non-detect
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

0.2 Non-detect

2.28

14.8

0.0664 Non-detect

3.94

0.109 Non-detect

2.52

0.0367 Non-detect

0.00009 Non-detect

0.00024 Non-detect

0.00045 Non-detect

0.00004 Non-detect

0.00004 Non-detect

0.0001 Non-detect

0.00033 Non-detect

0.00068

0.0171

0.00005 Non-detect

0.00111

0.00011 Non-detect

0.00336

0.00041 Non-detect

0.00167 Non-detect

01/22/13

Stripper Bottoms Wastewater

1 2

58

50.2

01/15/13

13-016-0205

Measured Measured
0.00004 Non-detect

0.00013 Non-detect

0.00004 Non-detect

0.00006 Non-detect

0

0.478

0.00007 Non-detect

0 Non-detect

0.00012 Non-detect

0.00007 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 1.3 Non-detect

0.2 Non-detect 135

3.2 0.885

16.5 0.923

0.0678 Non-detect 0.0709 Non-detect

5.73 6.7

0.111 Non-detect 0.116 Non-detect

3.56 2.43

0.0375 Non-detect 0.0392 Non-detect

0.00009 Non-detect 0.00009 Non-detect

0.00024 Non-detect 0.00024 Non-detect

0.00045 Non-detect 0.00045 Non-detect

0.00004 Non-detect 0.00004 Non-detect

0.00004 Non-detect 0.00004 Non-detect

0.0001 Non-detect 0.0001 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00054 0.00206

0.0192 0.047

0.00005 Non-detect 0.00005 Non-detect

0.00154 0.00215

0.00011 Non-detect 0.00011 Non-detect

0.00516 0.00226

0.00041 0.00041 Non-detect

0.00167 Non-detect 0.00167 Non-detect

01/22/13

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

3

42 49

49.7 41.6

01/16/13 01/17/13

01/21/13

13-017-0227 13-018-0209

Measured Measured
0.00004 Non-detect 0.00004 Non-detect

0.00013 Non-detect 0.00013 Non-detect

0.00004 Non-detect 0.00004 Non-detect

0.00006 Non-detect 0.00006 Non-detect 0 0

0.486 0.638

0.00007 Non-detect 0.00007 Non-detect 0 Non-detect 0 Non-detect

0.00012 Non-detect 0.00012 Non-detect

0.00007 Non-detect 0.00007 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

0.2 Non-detect

3.24

17.2

0.0709 Non-detect

5.77

0.116 Non-detect

3.8

0.0392 Non-detect

0.00009 Non-detect

0.00024 Non-detect

0.00045 Non-detect

0.00004 Non-detect

0.00004 Non-detect

0.0001 Non-detect

0.00033 Non-detect

0.00346

0.1

0.00005 Non-detect

0.00498

0.00011 Non-detect

0.00618

0.00041 Non-detect

0.00167 Non-detect

Stripper Bottoms Wastewater

4 5

53

42.6

01/18/13

01/21/13

13-021-0233

Measured Measured
0.00004 Non-detect

0.00013 Non-detect

0.00004 Non-detect

0.00006 Non-detect

0

1.99

0.00007 Non-detect

0 Non-detect

0.00012 Non-detect

0.00007 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

3.2 Non-detect 3.2 Non-detect

357 414

12.7 15.4

8.18 4.6

0.0671 Non-detect 0.0644 Non-detect

4.9 6.16

0.11 Non-detect 0.105 Non-detect

7.55 2.39

0.0371 Non-detect 0.0356 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00402 0.00057 Non-detect

0.249 0.0791

0.00058 Non-detect 0.00058 Non-detect

0.0118 0.0078

0.00116 Non-detect 0.00116 Non-detect

0.0295 0.0103

0.0122 0.0126

0.0167 Non-detect 0.0167 Non-detect

51

43.8 41

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

6

01/19/13 01/20/13

51

01/23/13 01/23/13

13-022-0211 13-022-0212

Measured Measured
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect 0 0

6.22 1.54

0.00071 Non-detect 0.00071 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00124 Non-detect 0.00124 Non-detect

0.00072 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

3.2 Non-detect

382

0.472

0.499

0.0631 Non-detect

2.14

0.103 Non-detect

10.6

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.0237

0.00058 Non-detect

0.0028

0.00116 Non-detect

0.013

0.0153

0.0167 Non-detect

46.6

01/21/13

7 8

52

01/24/13

13-022-0213

Stripper Bottoms Wastewater

Measured Measured
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

0.635

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

1.3 Non-detect 1.3 Non-detect

173 184

1.03 0.941

0.758 0.638

0.0644 Non-detect 0.0678 Non-detect

4.63 5.13

0.105 Non-detect 0.111 Non-detect

2.52 1.9

0.0356 Non-detect 0.0375 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00199 0.0019

0.0642 0.0672

0.00058 Non-detect 0.00058 Non-detect

0.00715 0.00732

0.00116 Non-detect 0.00116 Non-detect

0.00359 0.00482

0.00418 Non-detect 0.00418 Non-detect

0.0167 Non-detect 0.0167 Non-detect

Measured Measured

40.3 40.3

01/22/13 01/22/13

9

53 53

01/24/13 01/24/13

13-023-0205 13-023-0205

Stripper Bottoms Wastewater Stripper Bottoms Wastewater
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect 0 0

1.23 1.44

0.00071 Non-detect 0.00071 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00124 Non-detect 0.00124 Non-detect

0.00072 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

duplicate 0.6

332

1.04

2.58

0.0644 Non-detect

4.2

0.105 Non-detect

4.33

0.0356 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.0429

0.00058 Non-detect

0.0028

0.00116 Non-detect

0.00236 Non-detect

0.00418 Non-detect

0.0167 Non-detect

Measured

39

Measured

01/23/13

10 11

51

01/30/13

Stripper Bottoms Wastewater

13-024-0211
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

1.2

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 4.8

780 359

12.4 1.81

1.18 0.718

0.0709 Non-detect 0.0651 Non-detect

4.63 3.78

0.116 Non-detect 0.106 Non-detect

4.35 1.48

0.0392 Non-detect 0.036 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.109 0.107

0.00058 Non-detect 0.00058 Non-detect

0.00589 0.00409

0.00116 Non-detect 0.00116 Non-detect

0.0288 0.0122

0.00418 Non-detect 0.0121

0.0167 Non-detect 0.0167 Non-detect

45.9 50.6

51 51

Measured Measured

01/24/13 01/25/13

12

01/30/13 01/31/13

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

13-025-0210 13-028-0203
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect 0 0

2.6 2.31

0.00071 Non-detect 0.00071 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00124 Non-detect 0.00124 Non-detect

0.00072 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

4.4

460

4.89

2.1

0.0678 Non-detect

3.75

0.111 Non-detect

0.486

0.0375 Non-detect

0.00009 Non-detect

0.00024 Non-detect

0.00045 Non-detect

0.00004 Non-detect

0.00004 Non-detect

0.0001 Non-detect

0.00033 Non-detect

0.00083

0.0802

0.00005 Non-detect

0.00389

0.00011 Non-detect

0.0114

0.00041 Non-detect

0.00167 Non-detect

52.6

57

Measured Measured

13 14

01/26/13

02/05/13

Stripper Bottoms Wastewater

13-029-0216
0.00004 Non-detect

0.00013 Non-detect

0.00004 Non-detect

0.00006 Non-detect

0

3.04

0.00007 Non-detect

0 Non-detect

0.00012 Non-detect

0.00007 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

2.1 3.5

477 436

6.14 3.17

2.02 2.96

0.0651 Non-detect 0.0686 Non-detect

4.05 4.28

0.106 Non-detect 0.112 Non-detect

2.04 0.31

0.036 Non-detect 0.0379 Non-detect

0.00009 Non-detect 0.00092 Non-detect

0.00024 Non-detect 0.0024 Non-detect

0.00045 Non-detect 0.0045 Non-detect

0.00004 Non-detect 0.00047 Non-detect

0.00004 Non-detect 0.00046 Non-detect

0.0001 Non-detect 0.00109 Non-detect

0.00033 Non-detect 0.0033 Non-detect

0.00103 0.00057 Non-detect

0.155 0.0427

0.00005 Non-detect 0.00058 Non-detect

0.0751 0.0028 Non-detect

0.00048 Non-detect 0.00116 Non-detect

0.11 0.00502

0.00133 0.022

0.00167 Non-detect 0.0167 Non-detect

52.8

53

Measured

15

01/27/13 01/28/13

49

Measured

02/26/00 02/18/00

Stripper Bottoms Wastewater

13-029-0217 13-029-0218

Stripper Bottoms Wastewater

52.8
0.00004 Non-detect 0.00049 Non-detect

0.00013 Non-detect 0.00138 Non-detect

0.00074 Non-detect 0.00044 Non-detect

0.00006 Non-detect 0.00067 Non-detect 0 0

8.78 0.916

0.00007 Non-detect 0.00071 Non-detect 0 Non-detect 0.0007 Non-detect

0.00012 Non-detect 0.00124 Non-detect

0.00007 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

4.9

319

5.4

1.53

0.0671 Non-detect

4.73

0.11 Non-detect

0.627

0.0371 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.103

0.00058 Non-detect

0.0035

0.00116 Non-detect

0.0175

0.0257

0.0167 Non-detect

16 17

01/29/13

Measured Measured

54

13-031-0208

Stripper Bottoms Wastewater

02/23/00

53.1
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

2.41

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

4.7 0.9

498 47.2

10.7 2.41

2.07 7.24

0.0657 Non-detect 0.0841 Non-detect

3.7 4.72

0.107 Non-detect 0.137 Non-detect

0.202 0.3 Non-detect

0.0364 Non-detect 0.0465 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00782

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.13 0.354

0.00058 Non-detect 0.00058 Non-detect

0.0119 0.0112

0.00116 Non-detect 0.00116 Non-detect

0.022 0.0454

0.0261 0.0361

0.0167 Non-detect 0.0167 Non-detect

18

01/30/13 01/31/13

Measured Measured

60 47

02/16/00

13-031-0209 13-032-0224

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

02/29/00

52.6 50
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect 0 0

2.9 5.71

0.00071 Non-detect 0.00071 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00124 Non-detect 0.00124 Non-detect

0.00072 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.8

61.5

15.4

2.95

0.0809 Non-detect

4.17

0.132 Non-detect

0.361

0.0447 Non-detect

0.00186 Non-detect

0.0048 Non-detect

0.009 Non-detect

0.00095 Non-detect

0.00092 Non-detect

0.00218 Non-detect

0.0066 Non-detect

0.00489

0.218

0.00116 Non-detect

0.0218

0.00232 Non-detect

0.0188

0.00836 Non-detect

0.0334 Non-detect

19 20

02/01/13

49.4

Measured Measured

57

02/12/13

13-035-0217

Stripper Bottoms Wastewater
0.00099 Non-detect

0.00276 Non-detect

0.00089 Non-detect

0.00135 Non-detect

0

3.98

0.00143 Non-detect

0.0014 Non-detect

0.00248 Non-detect

0.00145 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect duplicate 0.9

54.6 39.5

11.2 8.76

3.3 2.39

0.0671 Non-detect 0.0678 Non-detect

3.2 2.21

0.11 Non-detect 0.111 Non-detect

0.452 0.323 Non-detect

0.0371 Non-detect 0.0375 Non-detect

0.00186 Non-detect 0.00186 Non-detect

0.0048 Non-detect 0.0143

0.009 Non-detect 0.009 Non-detect

0.00095 Non-detect 0.00095 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.00218 Non-detect 0.00218 Non-detect

0.0033 Non-detect 0.0066 Non-detect

0.00426 0.0042

0.279 0.461

0.00116 Non-detect 0.00116 Non-detect

0.0288 0.0369

0.00232 Non-detect 0.00232 Non-detect

0.022 0.0408

0.00836 Non-detect 0.00836 Non-detect

0.0334 Non-detect 0.0334 Non-detect

21

02/01/13 02/02/13

50

Measured Measured

57

13-035-0217

02/12/13 02/11/13

49.4 47.4

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

13-036-0228
0.00099 Non-detect 0.00099 Non-detect

0.00276 Non-detect 0.00276 Non-detect

0.00089 Non-detect 0.00089 Non-detect

0.00135 Non-detect 0.00135 Non-detect 0 0

5.99 8.74

0.00143 Non-detect 0.00143 Non-detect

0.0014 Non-detect 0.0014 Non-detect

0.00248 Non-detect 0.00248 Non-detect

0.00145 Non-detect 0.00145 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

35.2

5.75

1.97

0.0686 Non-detect

5.18

0.112 Non-detect

0.833

0.0379 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.0021

0.115

0.00058 Non-detect

0.00647

0.00116 Non-detect

0.00662

0.00418 Non-detect

0.0167 Non-detect

Measured Measured

46

02/15/13

48

Stripper Bottoms Wastewater

13-036-0229

02/03/13

22 23
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

1.73

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

26.1 32.7

6.47 10.3

1.91 2.98

0.0725 Non-detect 0.0651 Non-detect

4.19 4.67

0.119 Non-detect 0.106 Non-detect

0.3 Non-detect 1.12

0.0401 Non-detect 0.036 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00352

0.0496 0.1

0.00058 Non-detect 0.00058 Non-detect

0.00589 0.0182

0.00116 Non-detect 0.00116 Non-detect

0.0055 0.0156

0.00418 Non-detect 0.00418 Non-detect

0.0167 Non-detect 0.0167 Non-detect

61

02/18/13 02/16/13

13-036-0234 13-037-0209

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

48.7 48.4

02/04/13 02/05/13

24

49

Measured Measured
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect 0 0

0.835 2.52

0.00071 Non-detect 0.00071 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00124 Non-detect 0.00124 Non-detect

0.00072 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

42.7

1.89

3.82

0.0631 Non-detect

4.29

0.103 Non-detect

1.42

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00296

0.129

0.00058 Non-detect

0.00741

0.00116 Non-detect

0.0175

0.00418 Non-detect

0.0167 Non-detect

26

02/06/13

25

Measured

54.5

49

Stripper Bottoms Wastewater

02/16/13

13-038-0266

Measured
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

2.68

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

10.8 29.3

0.666 1.29

3.5 3.99

0.0678 Non-detect 0.0701 Non-detect

2.33 4.75

0.111 Non-detect 0.115 Non-detect

0.223 0.333 Non-detect

0.0375 Non-detect 0.0388 Non-detect

0.00009 Non-detect 0.00092 Non-detect

0.00024 Non-detect 0.00024 Non-detect

0.00045 Non-detect 0.00045 Non-detect

0.00004 Non-detect 0.00047 Non-detect

0.00004 Non-detect 0.00046 Non-detect

0.0001 Non-detect 0.00109 Non-detect

0.00033 Non-detect 0.0033 Non-detect

0.00083 0.00409

0.0488 0.148

0.0004 0.00267

0.00242 0.00796

0.00011 Non-detect 0.00116 Non-detect

0.00321 0.00671

0.00041 Non-detect 0.00418 Non-detect

0.00167 Non-detect 0.0167 Non-detect

27

02/07/13 02/08/13

50 45

54 64

Stripper Bottoms Wastewater Stripper Bottoms Wastewater

02/19/13 02/19/13

13-039-0234 13-043-0236

Measured Measured
0.00004 Non-detect 0.00049 Non-detect

0.00013 Non-detect 0.00138 Non-detect

0.00004 Non-detect 0.00044 Non-detect

0.00006 Non-detect 0.00067 Non-detect 0 0

0.728 2.24

0.00007 Non-detect 0.00071 Non-detect 0 Non-detect 0.0007 Non-detect

0.00012 Non-detect 0.00124 Non-detect

0.00007 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

38

5.24

7.81

0.0671 Non-detect

3.76

0.11 Non-detect

0.373

0.0371 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00496

0.208

0.00058 Non-detect

0.0348

0.00116 Non-detect

0.0148

0.0149

0.0167 Non-detect

28

13-043-0233

Stripper Bottoms Wastewater

29

02/09/13

45.2

66

02/21/13

Measured Measured
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

3.69

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

47.1 42.7

3.31 2.54

1.98 2.2

0.0671 Non-detect 0.0657 Non-detect

5.66 3.79

0.11 Non-detect 0.107 Non-detect

0.28 0.133

0.0371 Non-detect 0.0364 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00416 0.00374

0.113 0.122

0.00058 Non-detect 0.00058 Non-detect

0.00788 0.00694

0.00116 Non-detect 0.00116 Non-detect

0.00754 0.00828

0.0175 0.0185

0.0167 Non-detect 0.0167 Non-detect

02/24/13

13-043-0234

Measured

Stripper Bottoms Wastewater

30

02/10/13

50.8

48

02/11/13

51.7

Measured

46

02/22/13

13-043-0235

Stripper Bottoms Wastewater
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect 0 0

3.47 2.56

0.00071 Non-detect 0.00071 Non-detect

0.0007 Non-detect 0.0007 Non-detect

0.00124 Non-detect 0.00124 Non-detect

0.00072 Non-detect 0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect duplicate

49

2.85

2.08

0.0678 Non-detect

4.52

0.111 Non-detect

0.134

0.0375 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00321

0.112

0.00058 Non-detect

0.00722

0.00116 Non-detect

0.00602

0.0219

0.0167 Non-detect

31

Measured

32

02/11/13

51.7

Measured

46

02/22/13

13-043-0235

Stripper Bottoms Wastewater
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

2.38

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect

23.5

1.5

2.05

0.0637 Non-detect

1.52

0.104 Non-detect

0.175

0.0353 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.00125 Non-detect

0.00058 Non-detect

0.0028 Non-detect

0.00116 Non-detect

0.00236 Non-detect

0.0162

0.0167 Non-detect

33

02/12/13

48.9

Measured

46

02/24/13

13-044-0235

Stripper Bottoms Wastewater
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0

0.141

0.00071 Non-detect

0.0007 Non-detect

0.00124 Non-detect

0.00072 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

34 35

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

36

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

37 38

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

39

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

40 41

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

42

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

43 44

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

45

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

46 47

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

48

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

49 50

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

51

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

52 53

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

54

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

55 56

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

57

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

58 59

Concentration 

(ppmw) Non-Detect? Note(s)

60