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Library, E-Gl *V.

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Thermodynamic Properties of Argon

From the Triple Point to 300 K

At Pressures to 1000 Atmospheres

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UNITED STATES DEPARTMENT OF COMMERCE

Maurice H. Stans, Secretary

NATIONAL BUREAU OF STANDARDS • A. V. Astin, Director

Thermodynamic Properties of Argon

From the Triple Point to 300 K at Pressures

to 1000 Atmospheres

A. L. Gosman,* R. D. McCarty,** and J. G. Hust**

*Wichita State University, Wichita, Kansas, and

Cryogenics Division

Institute for Basic Standards

National Bureau of Standards

Boulder, Colorado 80302

**Cryogenics Division

Institute for Basic Standards

National Bureau of Standards

Boulder, Colorado 80302

NSRDS

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Library of Congress Catalog Card Number: 68-62109
Foreword

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technical community of the United States effective access to tjie quantitative data of physical

science, critically evaluated and compiled for convenience, and readily accessible through a variety

of distribution channels. The System was established in 1963 by action of the President’s Office of

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The responsibility to administer the System was assigned to the National Bureau of Standards

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this Office has developed systematic plans for meeting high-priority needs for reliable reference

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Ill
Contents

Page Foreword Ill List of figures IV

List of tables IV Nomenclature, Conversions, Physical Constants, and Fixed

Points for Argon V

1. Introduction 1 2. Survey of the literature 2

3. Summary of P-V-T data 2

4. Summary of vapor pressure data 3

5. Saturated liquid density 4

6. Vapor pressure 5

7. P-V-T surface 9

8. Analysis of P-V-T data 12

Page

9.

Temperature scale conversions

10. Derived thermodynamic properties 11 11. Equation of State and saturation boundary 20

12. Second virial coefficient and intermolecular potential.. 20

13. The Joule-Thomson inversion curve 23

14. Specific heats 24

15. Conclusions 26

16. Acknowledgements 27

17. References 30

18. Appendix A — Table of thermodynamic properties of argon at saturation 31b

19. Appendix B — Table of thermodynamic properties of argon at selected pressures 32a

List of Figures

Figure Page

1. Deviations between calculated equation (9) saturation

liquid densities and experimental saturated liquid densities 5

2. Latent heat of vaporization as a function of temperature 6

3. Volume of vaporization as a function of temperature...

4. Deviations of vapor pressure data from equation (14)... °

5. Low temperature density deviations of data by

Michels et al. [1] from the equation of state (40) 12

6. High temperature density deviations of data by

Michels et al. [1] from the equation of state (40) 12

7. Density deviations in the region of the critical point... 12

8. Pressure deviations in the region of the critical point... 13

9. Density deviations of data by Michels et al. [6] from

equation of state (40) 13

10.

Density deviations for data points near the saturation boundary 13

11. Density deviations of saturation data from equation of

state (40) * 13

12.

Density deviations of data by Rogovaya et al. [7] from

equation of state (40) 14

Figure Page

13. Density deviations of data by van Itterbeek et al. [8. 9] from equation of state (40) 14

14. Density deviations of data by van Itterbeek et al. [9] from equation of state (40) 14

15. Density deviations of data by van Witzenburg [10|

from equation of state (40) 14

16. Pressure-density diagram showing isothermal characteristics 15

17. Density deviations for data at temperatures and pres- sures extrapolated beyond the fitted data points 16

18. Comparison of second virial coefficients 21

19. Potential function comparison 22

20. Inversion curve comparisons 23

21. Specific heat at constant pressure calculated by nu- merical method 24

22. Specific heat at constant volume calculated by numerical method 25

23. Compressibility factor chart 28

24. Temperature-entropy chart 29

List of Tables

Table Page

1. Summary of P-V-T data 3

2. Summary of vapor pressure data 3

3. Coexistence density data 3

4. Coefficients for saturated liquid densities for eq (9) 5

5. Summary of vapor pressure deviations 9

6. Least squares estimates of coefficients for vapor pres- sure equation (14) 9

7. Estimated uncertainties of the experimental data H

8. Least squares estimates of coefficients for equation of

state (40) 11

Page

9.

Conversion from international to thermodynamic temperatures 17

10. Adjustments for entropy and enthalpy of the saturated

liquid 19

11. Comparison of heat of vaporization at the normal boil- ing point 19

12. Vapor pressure comparison 20

13. Second virial coefficients as calculated from virial equation of state (58) 21

14. Inversion curve from eq (64) 23

IV
Nomenclature, Conversions, Physical Constants, and Fixed Points for Argon

Nomenclature

P — absolute pressure

T — absolute temperature

V — specific volume

p — density = 1/C

R — universal gas constant

Z — compressibility factor = PV/RT

U — specific internal energy

H — specific enthalpy

S — specific entropy

Cp — specific heat capacity at constant pressure

Cv — specific heat capacity at constant volume

p — Joule-Thomson coefficient

B — second virial coefficient

G — Gibbs function

A — Helmholtz function

A — residual work content

E — potential energy

r — distance of molecular separation

cr — molecular separation for E = 0

e — Maximum energy of attraction

k — Boltzmann constant

N — Avogadro constant

r* — reduced distance = r/cr T* — reduced temperature = kT/e

bo — reducing parameter — 2ttN(t3I3

B*— reduced second virial coefficient = B/bo

po — distance between cores for minimum energy

h — Planck constant

a — radius of core m — mass of molecule

A* — de Broglie wave length = h/((r Vme)

Superscripts:

0 — ideal gas property

* — real or ideal gas property at very low pres- sures (P approaching 0) except as noted in

symbols above

1 — saturated liquid property

g — saturated vapor property

Subscripts:

c — critical point

0 — reference state property

sat — property at saturation

t — triple point

expr — experimentally determined property value

calc — calculated property value

melt — melting line property

Subscripts on partial derivatives and integrals

indicate which property is being held constant.

Conversions and Physical Constants

1 thermochemical calorie = 4.184 joules

0° C = 273.15 K (Triple point of water = 273.16 K)

Gas constant, R = 0.0820535 liter-atm/g-mole K

Planck constant, h = 6.6256 X 10-34 joule-sec

Boltzmann constant, k = 1.38054 X 10-23 joule/K

Avogadro constant, N= 6.02252 X 1023 per mole

Molecular weight of argon = 39.948g/g-mole (based on the carbon-12 scale where the isotope C

12 = 12.000. . .).

Fixed Points for Argon

Critical pressure = 48.34* atmospheres

Critical density = 300.4* Amagat = 13.41 g-mole/liter

Critical temperature = 150.86* K

Normal boiling point = 87.280 ±0.015** K

Triple point temperature = 83.80** K

Triple point pressure = 0.68005** atmospheres.

* These fixed points are those listed by Michels et al. [1J. Some recent investigations

indicate the critical temperature and pressure may be in error. However, these values appear to be the best estimate available at this writing. In reference [1] the Amagat

unit of density is given as 4.4647 X 10 -5 moles/cm3

, based on the chemical scale. In

this work the physical scale is used, resulting in an Amagat density unit of 4.4659 X 10 -5 moles/cm3

. ** These fixed points are those listed by Ziegler et al. [2]. The value of the normal

boiling point calculated by the vapor pressure equation developed in this work agrees

with that listed by Ziegler [2]. The value of the triple point temperature calculated by

the vapor pressure equation developed in this work deviates from Ziegler's reported

value by 0.0045 percent.

V
'
Thermodynamic Properties of Argon from the Triple Point to 300 K at Pressures

to 1000 Atmospheres

A. L. Gosman, R. D. McCarty, and J. G. Hust

Tabular values of density, internal energy, enthalpy, and entropy of liquid and gaseous argon are presented for temperatures from 83.8 to 300 K at pressures of 0.01 to 1000 atmospheres. Diagrams of

specific heats, compressibility factor, and entropy are included. The properties presented are calculated from an equation of state which was fitted to experimental P-p-T data from the world literature. Extensive comparisons were made between the equation of state and the experimental data, and deviation

plots are presented. The second virial coefficient and Joule-Thomson inversion curve were also cal- culated and comparisons made with values from other sources. A vapor pressure equation which covers

the range from the triple point to the critical point is also given.

Key Words: Argon; compressibility factor; enthalpy; entropy; equation of state; internal energy;

Joule-Thomson coefficient; P—V—T; specific heat; vapor pressure; virial coefficient.

1. Introduction

In recent years technical interest in pure argon

has greatly accelerated. This accelerated interest

has been evidenced by a demand which has more

than sextupled in 12 years. United States production has continued to increase from less than

200.000.

000 cubic feet per year in 1953 to almost

1.300.000.

000 cubic feet in 1965, with about 80

percent being shipped in liquid form [3].

1 In addition, scientific interest in argon has arisen

because of its characteristically “ideal” structural

makeup. That is, argon is monatomic, with the

relatively uncomplicated interatomic forces being

approximated by spherically symmetric, nonpolar

models. In addition, the quantum effects on argon

are relatively small. Although helium and neon

might be considered to be more “ideal” fluids

from the standpoint of simple models, the quantum

effects are relatively large for these two fluids as compared to argon. For these reasons argon might

be expected to permit a more direct classical in- vestigation and experimental verification of the

theoretical model predictions. In view of the increased activity in cryogenic

engineering and physics, it was apparent that a

set of consistent thermodynamic properties, over

a relatively large region of the thermodynamic

surface, was needed. Although many investigators

had published data for the thermodynamic properties of argon, each tabulation was, in general,

limited to the property range of interest of the

specific investigator, and large gaps in the data

existed. In addition, where the ranges of data did

1 Figures in brackets indicate the literature references (sec. 17).

overlap, there was a substantial degree of inconsistency in some instances. For these reasons, this

laboratory undertook the program of making a

critical analysis of the thermodynamic properties

of argon in the cryogenic temperature range, in- cluding the low temperature — high density region.

In recent years, much of the technical design

and synthesis has been done with the aid of high

speed digital computers. Thus the need for an analytical equation of state has become quite significant when compared with the use of tables and

charts of thermodynamic properties. Many equations of state have been proposed in the literature,

each with its own peculiar strengths and weaknesses. Some of these equations represented the

data in certain regions of the thermodynamic

surface, but were quite inadequate in other regions

of the surface. Therefore, the need was established

for a single equation of state which could accurately

and consistently represent the data for both the

liquid and vapor phases with a consistent transition from the low temperature — high density region

to the low density region. In the case of argon, it is difficult to assess the

general overall adequacy of an equation of state in

terms of deviations from the experimental P-V-T

surface. That is, due to the inconsistency of some

of the overlapping experimental data sources, there

is no single experimental P-V-T surface which can

be used as a reference. Also, the significance of

the deviations is wholly dependent upon the var- iable chosen for the comparison and the specific

region of the thermodynamic surface which is being studied. In certain regions of the surface.

1
large pressure deviations are caused by insignificant

density errors, while in other regions the reverse is true. In general, the equation of state presented in

section 7 represents the different sources of experimental data to within the accuracy of the data,

except at the higher temperatures on the coexist- ence boundary and the critical region where the

deviations are, in a few cases, greater than the

accuracy of the data. Numerous deviation plots are presented (sec. 8) in a manner which permits the

comparison of the equation of state with each of

the experimental data sources over the various

regions of the thermodynamic surface.

2. Survey of

A comprehensive search of the literature re- sulted in a bibliography of about 425 references.

The temperatures which were included in this

search covered the range from 0 to 300 K. In addition to manual-reviewing techniques, the data re- trieval personnel and the computerized search

techniques of the Cryogenic Data Center of the

National Bureau of Standards at Boulder, Colo, were utilized. As a result, a bibliography on the

thermophysical properties of argon [4] was prepared

and published in 1964. The literature search was

continually updated so that current data were

rapidly assimilated.

From this literature search, the most appropriate

P-V-T data, vapor pressure data, coexistence

density data, and fixed point data were selected

for consideration and evaluation. In addition, virial

coefficient data, Joule-Thomson data, specific heat

data, and information on equations of state were

acquired and considered.

Although many equations of state were presented in the literature, none of these equations

appeared to have been developed to adequately

represent the data for argon for temperatures from

below the normal boiling point to twice the critical

temperature for the gaseous, dense gas, and liquid

regions. Hirschfelder et al. [5] developed a generalized equation of state which arbitrarily divided

the P-V-T surface into three regions, namely, gas,

dense gas, and liquid regions. For these three

regions, Hirschfelder et al. [5] developed three

equations in such a manner that discontinuities

at the junction of these regions were avoided.

Appearing in the literature were other techniques for representing the P-V-T data. For some

fluids, where perhaps one source of highly precise

3. Summary

Published experimental P-V-T data were re- viewed and examined. As a result, the P-V-T data

which were considered for use in this compilation were distributed as shown in table 1. Evaluation of the experimental P-V-T data of van Itterbeek, Verbeke, and Staes [9] revealed

As a part of the critical analysis, it was deemed

necessary to develop a vapor pressure equation

which would accurately represent the experimental

vapor pressure data from the triple point to the

critical point. This vapor pressure equation could

then be used, in conjunction with the equation of

state, to calculate some of the derived thermodynamic properties such as enthalpy, entropy, etc. Thus it was concluded that a critical analysis of

thermodynamic properties of argon was to be made

for temperatures to about 300 K and for pressures

to about 1000 atm wherever the experimental data

permitted this pressure range.

the Literature

data were available, the P-V-T data could be represented by polynomials along isotherms or polynomials along isochores. One such isothermal

representation is the virial equation of state. The virial equation of state is based on fundamental grounds in that it can be derived from

fundamental statistical mechanics. Furthermore,

in principle, this equation of state depends upon a very small number of parameters in that once one

characterizes the potential function (by assigning

values to its parameters) all virial coefficients can

be calculated. In practice, however, only the second

virial coefficient has been calculated properly. The

third virial has been calculated in the approximation

where nonadditivity is neglected for a small number

of functions. All higher virials have really not been

calculated except for the fourth and fifth virials for

the hard sphere and (12-6) potentials. Thus, in

actual practice, a virial equation of state is, in

effect, an equation of state with a number of parameters equal to the number of virials times the number of isotherms (perhaps minus the second virials).

Thus, Michels et al. [1, 6] equation of state remains

a 100 parameter representation of his 19 isotherms

until higher virials can be properly calculated from

potential functions.

In addition, where multiple sets of data exist

(as with argon) at odd temperature and density

spacings, a complete correlation at all points of the

P-V-T surface becomes very difficult with these

polynomials. That is, if isothermal polynomials are used, then each set of coefficients is valid only for

the one specific isotherm which was fitted. If a point on the P-V-T surface lies between two of the

fitted isotherms, then other interpolative techniques must be used to obtain the P-V-T coordinates of this point.

of P-V T Data

slight inconsistencies. Private communication

from Verbeke [12] indicated that there were typographical errors in the original paper [9]. The new

values given by Verbeke [12] were then used in this work.

2
TABLE 1. Summary o/P-V-T data Table 1. Summary o/P-V-T data — Continued

Number Temperature Pressure Source

of points or volume range (atm)

8 - 140 °C 6 tP 160 Michels, Levelt, and de Graaff [1] 10 -135 7 to 200 m

13 -130 7 to 240 m

17 -125 7 to 280 m

20 -122.5 7 to 300 HI

24 -120 7 to 320 m

26 -110 8 to 400 m

26 -100 8 to 480 in

26 -85 9 to 600 m

27 -70 6 to 700 m

27 -50 7 to 850 m

28 -25 7 to 1030 m

41 Near coexistence region m

48 0°C 19 to 930 Michels, Wijker, and Wijker [6] 46 25 20 to 870 [6] 15 50 to 150 °C 27 to 750 [61 7 - 183.02 °C 26 to 165 Rogovaya and Kaganer [7] 8 - 150.08 25 to 185 [7] 6 - 135.03 72 to 196 [7] 6 - 120.02 73 to 166 [7] 7 -110.04 47 to 176 [7) 9 -100.01 49 to 192 [7] 7 -90.03 50 to 190 [7] 8 -75.03 26 to 194 [7] 8 -49.93 28 to 197 [7] 8 -24.98 27 to 184 [71

8 86.63 K 17 to 90 van Itterbeek and Verbeke [8| 14 87.91 13 to 147 [81 14 89.13 22 to 150 [81 14 90.55 . 18 to 146 [8]

8 90.15 K 10 to 242 van Itterbeek, Verbeke, and Staes [9] 12 96.99 11 to 280 [9] 12 108.18 19 to 260 [91 8 117.10 16 to 284 [9] 7 127.05 30 to 290 [9] 7 130.85 21 to 266 [9] 11 134.40 30 to 258 [91 16 136.02 40 to 257 [91 14 138.98 33 to 285 [91 11 146.63 58 to 248 [9] 9 148.25 45 to 288 [9]

Number Temperature Pressure Source

of points or volume range (atm)

i 93.15 K 320 van Witzenburg [10) 5 98.15 78 to 350 [10] 7 103.15 76 to 330 [10] 12 123.15 303 to 1042 [10] 12 128.15 302 to 1908 [10] 15 133.15 207 to 1941 [10] 7 108.15 322 to 1210 [10] 3 113.15 74 to 967 [10] 10 118.15 296 to 1590 [10] 13 138.15 315 to 1957 [10] 16 148.15 66 to 1902 [10] 13 153.15 315 to 1925 [10]

14 29.2 cm3/g-mol 21 to 488 Walker [11] 15 29.6 25 to 494 in]

17 29.8 43 to 520 [in

20 31.3 39 to 500 [in

17 33.8 16 to 515 [in

24 35.7 24 to 500 [in

22 37.8 27 to 506 [in

16 39.5 34 to 286 [in

16 41.2 34 to 483 [in

23 42.0 38 to 506 [in

24 43.6 45 to 316 [in

25 45.5 43 to 272 [in

14 50.7 45 to 139 [ii] 22 58.3 61 to 209 [in

13 66.5 45 to 122 [n]

A preliminary comparison of Walker’s [11] ex- perimental data showed an inconsistency in the

published density values. Private communication

from Walker [13] indicated that there were errors

in the density values quoted in the original paper

[11]. A more complete discussion of Walker’s [11]

data will be given later.

4. Summary of Vapor Pressure Data

Some of the vapor pressure data which are

available in the literature were published in the

early part of the century. Wherever possible, these

early data were replaced by more recent data if there appeared to be sufficient evidence that the

recent data were of higher reliability.

Modern experimental instrumentation and techniques generally permit a higher order of accuracy

and precision than did the earlier work. In addition, the temperature scales and basic standards

which were used in much of the older work were

substantially different from those used today. Some

of the earlier work may have been conducted with

variations in the temperature scales of as much as 0.06 deg. Much of the time, the early investigator

did not clearly state which temperature scale was

in current use and the results therefore lead to confusion and uncertainty.

As a result of the above considerations, the vapor

pressure data which were selected for further

analysis are shown in table 2. In addition to the vapor pressure data shown

above, two sources of coexistence or saturation

densities were examined. These are indicated in

table 3.

Table 2. Summary of vapor pressure data

Number

of points Temperature

range —

K

Source

23 90 to 150 van der Waals Laboratory data reported by

Clark, Din, Robb, Michels, Wassenaar, and

Zwietering [14].

17 86 to 150 British Oxygen Co. Ltd. data reported by Clark

et al. [14].

23 117 to 150 Michels, Levelt, and de Graaff [1].

6 84 to 87 Flubacher, Leadbetter, and Morrison [15].

34 85 to 148 van Itterbeek, de Boelpaep, Verbeke, Theeuwes,

and Staes [16].

9 129 to 147 van Itterbeek, Verbeke, and Staes [9].

Table 3. Coexistence density data

Number Temperature

of points range — K

23 117-150 Michels, Levelt. and de Graaff [1].

16 90-148 Mathias, Onnes, and Crommelin [17],

3
5. Saturated Liquid Density

In this analysis, it frequently was found con- venient to have an expression which could be used

to predict approximate values for the density of the

saturated liquid. This type of expression was not

needed for the determination of the equation of

state or the calculation of the thermodynamic properties. However, it would prove useful in the preliminary analysis, where saturation data were

evaluated for consistency. Such an expression also

would be useful for obtaining initial approximations

in iterative solutions of the equation of state. For

these purposes a simple expression, based upon

the principle of corresponding states, was developed.

Using the critical point as the reducing parameter,

the principle of corresponding states assumes a universal function which may be expressed as Pr =f(Tr ,Vr ) ( 1 ) where

Pr = PIPc

Tr = T\TC Vr =VIVc .

Combining eqs (3) and (4) yields an equation for

the saturated liquid density, expressed as

p

lPc = l + a(l — 7V) +C(1 — 7V) 1/3 (5)

where C= 6/2.

In order to represent the data with more accuracy

than eq (5) permits, an expanded form of eq (5) was proposed. Physical requirements demand that

the derivative

d(Tr)

d(pl lpc ) 0 at p

l = pc, and Tr — 1 ( 6)

Thus the possibility of an equation with the satu- rated liquid density as a function of only integer

powers of temperature is ruled out, since such an

equation would not fulfill the requirements of

eq (6). It then appears that a fractional power

term such as the last term in eq (5) is necessary

so that zero slope may exist at the critical point.

An expanded form of eq (5) may then be written as

p'lpc= 2 d,(l-Tr )l>. (7)

71 = 0 , 1 , 2 , 3 ,...

However, in the coexistence region where the

saturated liquid and saturated vapor are in mutual

equilibrium, the pressure and temperature are

not independent properties. Thus if eq (1) were examined in accordance with the thermodynamic

requirements of the coexistence fine, it may be

deduced that there also exists a universal function

for the saturated liquid such that

p

l /pc = F(Tr). (2)

Using a coordinate system of reduced temperature versus reduced density, Guggenheim [18]

plotted experimental data points for a number of

pure substances and verified the universal form of

eq (2). For the data which Guggenheim [18] had

available, he found that the coexistence fine could

be adequately expressed by the relationships

^±^=l + a(l-7V) (3)

and

^-^= 6(l-7V)'«, (4)

Pc

where a and 6 are constants. Equation (3) represents the “law” of the rectilinear diameter which

states that the average of the saturated liquid and

saturated vapor densities appears as a straight fine on the reduced coordinate system of temperature

versus density.

For eq (7) to satisfy critical point behavior, the

coefficient do should be essentially equal to unity.

In addition, if the derivative of eq (7) is written

d(Tr) 1 d(p'lpc)

71 = 0 , 1

it is seen that the requirements of eq (6) are satisfied.

In eq (7), fractional exponents other than multiples

of 1/3 were investigated. The results showed no

apparent advantages, and the 1/3 exponent was

retained.

Equation (7) was fitted to the saturated liquid

data by least square techniques. A series of suc- cessive fits was performed with increasing values

of “ft.” Examination of these fits revealed a con- tinued decrease in the deviations between the

calculated density and experimental density until

the fit with ft = 6. For fits with “ft” greater than

six, the results appeared to be approaching the

precision of the data, and, therefore, the final form

for the equation was selected to be

2 ^dnil-Tr)*'

1

, 2 , 3 , . . .

P'lpc =

n1= ( dnK" (9)

where K=(l — Tr )

113 and Tr is calculated from

temperatures in Kelvin units.

An examination of the saturated liquid density

data demonstrates that the data from Michels et al. [1] and Mathias et al. [17] are consistent with each

other, with Michels’ data showing somewhat more

precision. This may be seen in figure 1, where

4
percent density deviation is plotted as a function

of temperature.

90 100 110 120 130 I AO 150

FIGURE 1. Deviations between calculated ( eq (9)) saturation

liquid densities and experimental saturated liquid densities.

In figure 1, it is seen that both sets of data

exhibit almost the same characteristics with the

Mathias data showing a wider envelope of density

deviations. The maximum deviation of the saturated

liquid density data from that calculated by eq (9)

is 0.32 percent which occurs within 1/2 deg of the

critical point. The mean of the absolute values of

density deviations for Michels’ data is 0.099 percent, and for the data of Mathias, 0.098 percent.

However, the three Michels’ data points which

exhibit the largest density deviations are all within

about a degree and a half of the critical point where

the experimental determination of saturated liquid

densities becomes most difficult. If these three

points are not included, then the mean density

deviation is 0.039 percent. On the other hand, the

single data point of the Mathias data which exhibits

the maximum deviation is within about two and a

half degrees of the critical point. If this point is omitted, the mean density deviation for the Mathias

data is 0.076 percent.

With these comparisons, it can be concluded that

eq (9) adequately represents the data, with precision

approaching the precision of the data. In addition,

the data of Michels et al. [1] display a precision

about twice that of Mathias et al. [17].

The coefficients of eq (9) which resulted from the

fit with n = 6 are shown in table 4.

Table 4. Coefficients for saturated liquid densities for eq (9)

Temperature in K, coefficients are dimensionless

do = 0.99995448 dt = 91.361470

d, = 0.47354891 ck =-93.773992

d2 = 11.238328 <4 = 37.769045

<4 = -43.741090

Use of the coefficients in table 4 produces a root-mean-square deviation in p

llpc of 0.002 for the

data considered.

6. Vapor Pressure

The purpose of developing a vapor pressure

equation was twofold. When used in conjunction

with an independently obtained equation of state,

the vapor pressure equation could be used to define

the coexistence boundary. Also, the vapor pressure

equation could be used in conjunction with the

equation of state to calculate some of the derived

thermodynamic properties.

The coexistence boundary may also be defined

without the use of a vapor pressure equation, as discussed in section 11. However, this method

requires a sufficient number of highly precise

experimental P-V-T data points along the boundary.

Since saturation densities are difficult to measure

with a high degree of precision, and since there was only one source of satisfactory coexistence

data, it was difficult to perform a critical evaluation of this data for the purpose of establishing

the coexistence boundary.

Instead, there was in the literature a relatively

large number of experimental P-T data points along

the coexistence boundary. With these data a vapor

pressure equation could be developed. An examination of the literature indicated the existence of

many vapor pressure equations which have been

used. Some of these have been studied, compared,

and listed by Stewart [19].

For this evaluation of argon, a vapor pressure

equation was developed which would represent

the argon data with sufficient precision and at the

same time permit consistency with the equation

of state at the critical point.

The argon vapor pressure equation was developed

from the application of the Clapeyron equation

to a first order phase transition. The Clapeyron

equation is

( dP\ H9 -W

\ dT ) sat T(V«-Vl y

( 10)

If appropriate expressions for the changes in

enthalpy and volume as functions of temperature

and pressure are substituted in eq (10), the equation can then be integrated to give the desired

vapor pressure equation. Some of the simpler and

more commonly used vapor pressure equations were obtained with the assumptions of

V9 > V1

; H9 — H' = constant. (ID

5
The first assumption of eq (11) is valid only for

coexistence states which are considerably below

the critical point. In addition, figures 2 and 3

illustrate that the second and third assumptions

of eq (11) are in substantial error.

Figure 2. Latent heat of vaporization as a function of

temperature.

Therefore, for this work on argon, the following

two approximations were proposed:

H^-Hl = K1 +K2 T+K3 T

2 (12)

and

The approximations suggested by eqs (12) and (13) are compared with the assumptions of eq (11) and

are shown in figures 2 and 3. Figure 2 illustrates a typical plot of the latent

heat of vaporization as a function of temperature.

It is observed that the third assumption of eq (11),

which approximates the latent heat as a constant,

is unsatisfactory both in magnitude and in characteristic nature. It is thus proposed that eq (12)

represent the latent heat of vaporization. Equation

(12) is shown in figure 2 as the dashed line and is seen to represent more closely the characteristic

nature of the physical behavior. The constants in

eq (12) may be adjusted to change slightly the nature

of the curve. Therefore, it was concluded that the

quadratic nature of eq (12) satisfactorily represented

the physical behavior in figure 2, and no higher degree temperature terms were considered necessary.

Figure 3 illustrates a typical plot of the volume

of vaporization as a function of temperature. It is clear that the perfect gas assumption of eq (11)

FIGURE 3. Volume of vaporization as a function of temperature.

becomes quite unsatisfactory as temperature in- creases. In addition, it is noted that the characteristic curvature of the perfect gas representation

is incorrect. In figure 3, it is seen that the approximation proposed by eq (13) represents the physical

behavior more closely and maintains the proper

curvature for the entire temperature range. In

addition, eq (13) permits the volume of vaporization

to reduce to zero as the pressure approaches critical

pressure. It should be noted that the deviations

between the different models shown in figures 2

and 3 are used only for purposes of illustrating

qualitative trends and are not indicative of the

actual deviations of the calculated vapor pressure

properties.

Substitution of eqs (12) and (13) into eq (10) and

integrating give

In P = A/T+B In T+CT+D + EP. (14)

Equation (14) was then the equation which was

proposed for representing the vapor pressure data,

with five constants to be determined by a leastsquare fit to the data.

In order to fit the vapor pressure eq (14) to the data, considerations were given to the ex- permental errors in the observed data points so that

each of the data points could be appropriately

weighted. The weighting scheme, as described by

Hust and McCarty [20], is outlined below.

Let a function with “()” variables

yn =f(Xuii X‘2 n, • • Xqih • • ••> XQri)

for ft = 1 , 2, . . N (15)

6
4

( 26) represent the set of “TV” experimental data points

X\ n , X‘2tit • • •? Xqn ,

. . ., Aqh (16) —+ C — : r,, r

2 A7! + l~£ AP2n

where Yn is the dependent variable for the nth data

point and Xqn is the qth independent variable for

the nth data point. The weighting factor is most

usually described as the reciprocal of the variance

W

crt (17)

which takes into account the variance of the dependent variable.

Since both the independent and dependent

variables affect the final fit of the function to the

data, the weight function for the nth data point is expressed asWn = -

CTy1 n +

Q

29=1

1(»L

\dXqn

(18)

Since P was chosen as the dependent variable in

eq (14), Y becomes

Y=\nP-EP. (19)

To obtain <xy

n for eq (18) for the nth data point,

dY (1 _A

( 20)

Also from eq (18) and the vapor pressure equation

(14),

and

29=1 dTn T”

df__ B A

c)Tn n

( 21 )

( 22)

If the experimental uncertainty of the nth data

point for the qth variable, “A

A

g„”, corresponds to a 95 percent confidence interval on the observed

Xqn , then the standard deviation is related to AXqn as

0~qn 2AXnn. qn- (23)

The vapor pressure equation (14) is a function of

pressure and temperature. Applying eq (23), gives

2aTn = AT„ (24)

and

2o>„ — APn . (25)

Equation (26) was then used as the weighting

function for all of the vapor pressure data except

the data of Clark et al. [14]. The vapor pressure data

of Clark consisted of several hundred observations.

The method which Clark used was a comparison of

the vapor pressure of argon with that of oxygen as determined by Hoge [21], and using the latter as a measure of the temperature. In this manner, the

temperatures were measured with a mercury-inglass manometer over most of the temperature

range. At higher pressures, the temperature was

measured with a copper-constantan thermocouple.

Clark stated that the measurements were taken with

a reproducibility of about 0.05 percent at low pressures. At higher pressures he found that the temperature control on his apparatus would not maintain

the temperature constant with the same precision

as at the lower temperatures, resulting in an uncertainty of about 0.2 percent in pressure for a given

temperature.

Clark et al. [14] published a plot of deviation (from

a fitted equation) in A log P versus log P. From this

plot it appeared that there were about three to four

times as many data points at low pressures than

at pressures near the critical point. From the description of the experimental techniques used, the

uncertainty limits, and the variable density distri- bution of Clark’s data, an arbitrary modifying function was developed to modify the weighting function

eq (26) for Clark’s data. This function, as described

by Gosman [22], is M= —Lr-0.28. (27)

5

ji

Since Clark’s lower temperature range included

more data points than the high temperature range,

and since the temperature control on Clark’s apparatus was less precise at the higher temperatures,

the modifying function (27) was made to reflect the

lower reliability at the higher temperatures.

Equation (27) was used to modify the variance of

the fit, so that the weighting factor for Clark’s data

resulted in

Wc 1 (a/M) 2

' (28)

Using eq (28), the final weighting expression for

Clark’s data is Wc — WM2

, (29)

where W is the general weighting function eq (26).

The nine vapor pressure data points of van Itter- beek, Verbeke, and Staes [9] were not used in the

final determination of the vapor pressure equation.

These nine points were omitted from the final

Substituting the necessary expressions into (18), a weighting function for the nth data point is obtained:

7
evaluation because, within a year of the vapor pres- sure observations of van Itterbeek et al. [9], a new

set of vapor pressure data was reported by van

Itterbeek, de Boelpaep, Verbeke, Theeuwes, and

Staes [16] which deviated considerably from the

earlier data [9], but appeared to be more consistent

with the vapor pressure observations from other

sources. The uncertainties in the vapor pressure data were estimated from the statements of the investigators, the description of the experimental procedures, the deviations between the different sets of data, and the apparent random deviations of

each set of data.

The resulting uncertainties for all of the vapor

pressure data were estimated to be

AT = 0.00025

~p~~ 0.00025.

(30)

Substituting eqs (30) into (26) and (29),

° FLUBACHER, LEADBETTER , AND MORRISON [ 1 5 ] • CLARK, et al [

I 4 ]( Experiments by Michels)

° CLARK, et al. [ 14] (Experiments by Clark ) MICHELS, LEVELT , AND DE GRAAFF [

I ] a VAN ITTERBEEK , et al [

1 6 ]

r ( ^ „ av

6.25 [B + CT-j

J + (EP)2 + 1

and for Clark’s data,

WC = WM\ (32)

For each data point, the weighting functions

(31) or (32) were substituted into the normal leastsquare equations as shown by Hust and McCarty

[ 20]. In addition, it was considered desirable to make

the vapor pressure equation (14) pass through the

critical pressure and temperature so as to be consistent with the equation of state at the critical

point. This required adding a constraining equation

to the normal least-square equations so that the

coefficients of the vapor pressure equation would

satisfy the least-square criteria, as well as simultaneously constrain the vapor pressure equation to pass through the critical point. The generalized

normal least-square equations with constraints are shown by Hust and McCarty [20] and Gosman [22].

A preliminary weighted-least-square fit with one

constraint indicated that the low temperature data

of van Itterbeek et al. [16] exhibited a scatter of

about three to four times as great as the higher

temperature data. Since low temperature vapor

pressure data from other investigators were available, these low temperature data of van Itterbeek

et al. [16] were omitted from the final fit. The resulting fit of the vapor pressure equation

(14) to the data is illustrated in figure 4, where the

deviation between the temperature predicted by

eq (14) and the experimental temperature is plotted

as a function of pressure.

Figure 4. Deviations of vapor pressure data from eq (14).

In figure 4, it is seen that the characteristic shape

of all five of the deviation curves is the same, except

for the low temperature data of van Itterbeek et al. [16] (which was not included in the fitted data).

From figure 4 it is also noted that the data of van

Itterbeek et al. [161 exhibits a pattern of generally

wider scatter at the higher temperatures when compared with the other data sources. The similarity in the basic shape of the deviation curves of figure 4 may be interpreted to indicate a fundamental consistency between the selected

vapor pressure data. The deviation curves also

indicate the possibility of a disagreement in the

temperature scales between the different data

sources. This disagreement of temperature scales

is inferred from the essentially constant shift or displacement between any one of the deviation curves and any of the others. This displacement of

the deviation curves exists despite the fact that an

effort was made to convert all of the temperature

scales to a common thermodynamic temperature

scale. An additional correction of less than 0.01

deg (see sec. 9) was made to the data of Clark et al. [14], since he stated that his data were based on an

ice-point temperature of 273.16 K, whereas the other

vapor pressure data sources were based on the

ice-point temperature of 273.15 K.

From figure 4 it is seen that the maximum temperature deviation is 0.108 deg. This particular

point is in the Clark et al. [14] set of data and may

be questionable since it contributes a sharp spike

in the deviation curve. For Clark’s data, the mean of

the absolute values of the temperature deviations is 0.0290 deg. If the single questionable data point is omitted, the mean deviation of Clark’s data is 0.0240 deg. For the data of Flubacher et al. [15],

8
the maximum temperature deviation is 0.0174 deg,

while the mean of the absolute values of the temperature deviations is 0.0109 deg. The deviations of

Clark et al. [14] (experiments by Michels) appear to oscillate slightly about the zero axis except at the

lower temperatures where the maximum temperature deviation occurs. For the data of Clark et al. [14], the maximum temperature deviation is 0.0339

deg, while the mean of the absolute values of the

temperature deviations is 0.00925 deg. The data of

Michels et al. [1] also exhibit a small oscillation

with a maximum temperature deviation of 0.0309

deg and a mean of 0.0158 deg. For the data of van

Itterbeek et al. [16], the maximum temperature

deviation is 0.156 deg, while the mean is 0.0484 deg.

The summary of the deviations between the temperature predicted by the vapor pressure equation

(14) and the experimental temperature is given in

table 5.

Table 5. Summary of vapor pressure deviations

Max. temp , deviation Mean abs. temp deviation Source

0.0339 0.00925 Clark et al. [14].

a .108 .0290 Clark et al. [14]. .0309 .0158 Michels et al. [1]. .0174 .0109 Flubacher et al. [15). .156 .0484 van Itterbeek et al. [16].

a Experiments by Michels. By independent means, Ziegler et al. [2] obtained

“best” values for the normal boiling point temperature and triple point temperature. It is important to note the deviations between the temperatures given

by Ziegler et al. [2] and the temperatures predicted

by the vapor pressure equation (14). The normal

boiling point temperature given by Ziegler is 87.280 ±0.015 K, while the normal boiling point

temperature predicted by equation (14) is 87.2838 K.

The triple point temperature recommended by

Ziegler is 83.80 K, while the triple point temperature predicted by eq (14) is 83.8038 K, which

corresponds to a temperature deviation of 0.0045

percent.

Table 6. Least squares estimates of coefficients for vapor

pressure eq {14) a

Coefficient Least squares

estimate Standard deviation

of coefficient Significance

level b

A - 1.062454904 X 10’ 4.993 x 10 1 99.5%+

B -4.271440691 1.056 99.5%+ C 1.524254979 X 10“2 5.670 X lO"3 99 %

D 2.992927939 X 10 1 4.796 99.5%+ E 2.465760638 x 10'3 5.049 x 10

4 99.5%+

a Where P is in atm and T is in K.

b These parameters are significant at the level indicated when applying the standard F test.

Table 6 lists the five coefficients for eq (14). Also

tabulated in table 6 are the standard deviations and a significance level of these parameters. The signifi- cance level indicates these parameters are significant at least to the level indicated when applying

the standard F test.

7. The P-V-T Surface

Many equations of state have been proposed to represent the P-V-T surface. Some of these equations represent the experimental data adequately

in limited regions of the thermodynamic surface

but are quite inadequate in other regions. Other

equations, taking the form of polynomials along

isotherms or isochores, are well suited to represent

a single source of highly precise experimental data.

However, the use of these polynomial expressions

becomes very difficult in a complete correlation of

the P-V-T surface with multiple sets of experimental

data with odd spacings of temperature and density.

In this analysis the P-V-T surface was basically

represented by an equation of state proposed by

Benedict, Webb, and Rubin [23] with modifications

by Bloomer and Rao [24] and further modified and

extended by Strobridge [25].

The Benedict-Webb-Rubin equation was developed by defining and utilizing a quantity A, called

the residual work content. The residual work content

was defined as the difference between the Helmholtz

function for a real substance and the Helmholtz

function for an ideal gas.

The Helmholtz function

A = U-TS (33)

may be combined with the first and second laws of

thermodynamics

,

dU = TdS — PdV. (34)

The resulting relationship is dA— — PdV— SdT. (35)

From eq (35),

(36)

where P is the difference in pressure between the

real and ideal gas. Then

P=pRT+eiS

4)T (37)

where the first term on the right side of eq (37) is the ideal gas pressure and the second term is the

difference between the real and ideal gas pressure.

Benedict et al. [23] proposed an expression for the

residual work content which was actually an extension of the Beattie and Bridgeman equation. The

extension to the Beattie-Bridgeman equation was

9
necessary in order to represent more accurately

the real fluid properties at densities which were

higher than the Beattie-Bridgeman equation could

adequately represent. Beattie noted that isometrics

could be expressed by an equation of the form

(P-pRT)lp*=RTF1 (p)-F2 (p)-F3(p)ir~. (38)

Equations for the functions F2 , and F3 were

then empirically developed to fit experimental data

and, at the same time, remain consistent with the

residual work content. By these means, Benedict

et al. developed an eight adjustable parameter

equation of state for hydrocarbons.

After further modifications, Strobridge [25] ex- tended the Benedict-Webb-Rubin equation to represent more accurately the properties of nitrogen. The Strobridge modifications resulted in an

equation with sixteen adjustable parameters.

The form of the equation expressed by Strobridge was the one adopted for the determination of the

argon P-V-T surface. This form of equation appeared

justified because corresponding states theory in- dicated that there should be reasonable correspond- ence between nitrogen and argon [18]. The equation

of state then used is P = pRT+ p

2 {n x T + n2 + n3 \T + n4 IT2 + n3 /T4

) + p

3 (n€

7’ + n7 ) + p

4 n»T

+ p

3 (n9/T2 + riio/T3 + n n/T4

) exp (— n, 6p

2

) + p

5 (n v2 IT2 + n l3 /T3 + nl4 /T4

) exp (—n,ep

2

) + p

6 n15 . (39)

As a matter of convenience, eq (39) was solved

for Z — 1, and the resulting expression was then

fitted to the data by least squares. This expression is Z - 1 =| (m + UfijT + n3\T2 + n4 /T3 + n-JT>)

2 3 + ^

(^6 + n7 /T) + ^

n8

+ ~ (n9/T3 + riio/T4 + nn/T5

) exp (— ni 6p

2

)

+ ^

(n^/T3 + nl3/T4 + nl4/T5

) exp (— n, 6p

2

)

+ ^

nis/T. ( 40)

procedure essentially doubled the number of significant figures carried by the computer, so that

round-off error due to the large number of arithmetic

operations would be minimized.

In addition, an effort was made to check the

results of the least squares solution to see if roundoff error, due to operating on an ill-conditioned

matrix, was present. The method used to perform

this check is outlined as follows: The set of normal

equations was obtained by standard techniques.

The second normal equation in the set was multiplied by a constant and added to the first normal

equation. This sum then replaced the original second

normal equation. The third normal equation was

then multiplied by a different constant and added to the new second normal equation, and so forth. Each

of the constant multipliers was, in general, different.

The constants were selected so that each of the

diagonal elements of the matrix formed by the re- sulting set of normal equations was larger than the

elements to its right. This criterion was used since

appreciable loss of accuracy may occur if a diagonal

is smaller than elements to its right. The entire

check procedure is then equivalent to the rotation

of each of the normal equations relative to the

others. The solution to the matrix with rotated

vectors could then be obtained. If the solution was

the same as that for the original matrix, then it was

considered likely that a sufficient number of

significant figures was carried in the double precision computer solution to make round-off errors

insignificant. For the preliminary least squares fit mentioned above, the solution to the matrix with

rotated vectors was the same as the original matrix,

to eight significant figures. Although eight significant figures is not indicative of the precision of the

original P-V-T data, the agreement of the two solutions indicated that numerical round-off errors were

probably insignificant.

The preliminary least squares fit showed that the

data of Walker [11] deviated substantially from those

of Michels et al. [1] and Rogovaya et al. [7]. Therefore, the data of Walker were not used in the subsequent fits to eq (40). (Further mention of Walker’s

data will be made later.)

In the subsequent fits it was found desirable to satisfy the standard least squares criteria and, in

addition, to simultaneously constrain eq (40) to exactly satisfy three specific requirements at the

critical point. The specific constraints which were

used are:

1. The critical isotherm of the equation of state

(40) has zero slope at the critical point.

A preliminary least squares fit of eq (40) to the

selected P-V-T data indicated possible round-off

discrepancies due to the very large number of

arithmetic operations involved with the solution of

the normal equations. Therefore, the computer

program for the least squares fitting routine was

written for double precision arithmetic which carried

20 decimal figures throughout the calculations. This

dP

dp = 0 (critical point)

2. The critical isotherm of the equation of state

(40) has a point of inflection at the critical point.

(critical point)

10
3. The equation of state (40) predicts the critical

pressure when the critical density and temperature

are substituted into it. In addition, provisions were made to account for

the different uncertainties in the experimental data

from the different data sources. The weighting

function described by eqs (18) and (23) was used

in conjunction with the equation of state (40), where

Y=Z- 1=-§|-1 (41)

cri /AiY2 = P (AP Ap A7V

V2 ) 4 \P +

p

+

T)

(df\_(d(Z-\) \ (dZ\

\dxi) \ dT )p \dTjp

(df\_(d(Z- 1) \ =

/dZ\

\dx2) \ dp ) T \dp) T

2<tt=AT; 2a-p = Ap

.

(42)

(43)

(44)

(45)

Substituting eqs (42) through (45) into eq (18), and simplifying,

4 W

Z2 AP Ap AT

P p T

' 2 r (dZ\ AT 1

2 + 1 [dT)p T _ + P

(dZ_\ Ap (46)

The uncertainties in the P-V-T data were esti- mated from the statements of the investigators,

from a knowledge of the experimental apparatus,

and from preliminary examinations of the data.

The estimated uncertainties associated with the

various data are given in table 7. The uncertainties from table 7 were substituted

into eq (46) and weights were calculated for each

P-V-T data point. These weights were then substituted into the generalized normal least squares

equations with constraints as shown by Hust and

McCarty [20].

Table 7. Estimated uncertainties of the experimental data

Pl ("rj* (£)„ A (48)

% Density % Pressure % Temperature Source

0.05 0.02 0.02 [ i] .05 .02 .02 [ 6]

.1 .1 .1 [ 7]

.2 .02 .02 [ 8]

.2 .02 .02 [ 9]

.2 .2 .2 [10]

Since the normal equations are linear in the

coefficients, the coefficient the in eq (40) had to be

determined before the remaining 15 coefficients were evaluated. A systematic search for the optimum value of rci6 was performed on the digital

computer so that a minimum in the sum of the

squares of the deviations was obtained. In order

to have a realistic range in the search for ni6 , an approximate value was obtained by corresponding

states with nitrogen. A modified corresponding

states method, proposed by Kamerlingh Onnes, was used. This method suggests that the reduced

density is pr=efr (47)

The difference between eq (47) and eq (1) is discussed by Gosman [22]. In eq (40), Ui 6 appears as the coefficient of a squared density term. From eq

(47), a corresponding states expression for a squared

density term was obtained:

where the subscripts N and A represent nitrogen

and argon, respectively. Equation (48) was substituted into the exponential term in eq (40). From

Strobridge, the rti 6 for nitrogen was also substituted into the exponential term of eq (40). The

resulting approximate value of the coefficient nj6 for argon from corresponding states was calculated

to be 0.0039. The range of the systematic search

for tti 6 was thus determined to be 0.0039 ± 0.0015.

The systematic search was accomplished by in- crementing 0.0039 by small values and performing

a linear least squares fit for each consecutive value

of nie. As the search proceeded, it was found that

the sum of the squares of the deviations were not

much affected by the current value of n 16 . However,

the fit of the equation of state in the region of the

critical point was moderately affected by the dif- ferent trial values of tii 6 • The resulting value of ni6 and the least square estimates of the remaining

15 coefficients for eq (40) are given in table 8.

Table 8. Least squares estimates of coefficients for equation of

state ( 40)a

Coefficient Least squares Standard deviation Significance estimate of coefficient level % b

nx 0.25978374 X 10~2 4.927 X 10-5 99.5 +

n-z - .89735867 3.002 x lO"2 99.5 +

n3 -.67273638 X 102 2.939 x 10 99.5 +

n4 -.26494177 X 104 2.475 X 102 99.5 +

n$ .97631231 x 107 7.133 X 10s 99.5 +

ne .70478556 x 10-4 1.814 x 10“6 99.5 +

n7 -. 46767764 X 10“2 1.323 X 10-4 99.5 +

rin .22640765 X lO"5 6.177 X 10-8 99.5 +

.48141071 X 103 8.442 X 10 99.5 +

n 10 .64565346 X 105 3.152 X 104 95.0

nil -. 1 1485282 X 10s 2.495 X 106 99.5 +

- .64835488 1.942 X 10-' 99.5 +

.46524812 X 103 7.373 X 102 25.0 n u . 10933578 X 105 1.287 x 103 99.5 +

n is .69439530 X 10“ 6 4.064 x 10-" 99.5 +

.48 X 10"2

a Where P is in atm, T is in degrees K, p is in g-mol/1, and R = 0.0820535 atm 1/g- mol K.

6 These parameters are significant at the level indicated when applying the standard F test.

316-977 0 - 69-2

11
8. Analysis of P-V-T Data

Using the coefficients shown in table 8, the

equation of state (40) was used to calculate the

densities which corresponded to each of the experimental P-V-T data points. Percent density deviations

between the points calculated by the equation of

state and the individual experimental data points

which were used in the fit are illustrated in figures 5

through 15. These deviation plots permit the identification of the maximum deviations corresponding

to each region of the P-V-T surface as well as the

specific deviations from each data source. The deviation plots for the data of Michels et al.

[1] and Michels et al. [6] are shown by figures 5

through 11. Inspection of figures 5 and 6 shows that

the largest density deviations occur in the vicinity

of the 153.15 K isotherm. For this isotherm, the

largest deviations occur in the region of the critical

point. The same phenomenon occurs for the 163.15

K and 150.65 K isotherms and, to a lesser extent,

for the 173.15 K and 148.15 K isotherms. This behavior is illustrated in figures 7 and 8. Figure 16 illustrates the characteristics of the

different isotherms as they range over the pressuredensity coordinate system. It is seen that the high

and low temperature isotherms have relatively large

50 100 150 200 250 300

, 1 '

1

' ,

1

1

1

' 1

°J\/ ^

133.15 °K

Z

UJo

cr

50 100 150 200 PRESSURE (atm)

250 300

NOTE Density Deviation Lines are Broken in the Region of Critical Pressure. See Figure 7 for Deviations in this Region

Figure 5. Low temperature density deviations of data by

Michels et al. [I\from the equation of state (40).

0 200 400 600 800 1000

0 200 400 600 800 1000 PRESSURE (atm)

NOTE Density Deviation Lines are Broken in the Region of Critical Pressure. See Figure 7 for Deviations in this Region

FIGURE 6. High temperature density deviations of data by

Michels et al. [l]from the equation of state (40).

0 25 50 75 100 125

PRESSURE (atm)

NOTE! These Density Deviations are in the Region of the

Critical Point as Shown in Figures 5 and 6.

Figure 7. Density deviations in the region of the critical point.

12
8

COz

o

<

Gj

Cr3

CO

(O

LdQ

CLz

LsJ o

(TLd

CL

CL

*L

C

30

2.0

10

0

- 1.0

-20

-30

2

.1

0

- I

- 2

I

0

-.1

60 75

1 1 1

1

1 1

1 1

1

7

1 1

1

1 1

i

151 65 °K

,I58I5°K -

I45 65°K-^,"'' /“

A 146 15°K'^

# j

I49I5°K - ^

I4965°K J— 150 I5°K

J l _l \l

-

i

1 i i

131 65°KX 130 15°K'\\)

1 1

#/l37l5°K

/I40 75° K

-

- /

I35I5°K-^J I36I5°K^

*" 144 65°K

-

1 1 i /I3965°K __lZ 1 J 1 1 1 L i i

-

7 I27I5°K^ /

|

I i

|

i l

1

1 1 Il3.3atm y

- _l i 1 i I

X I28 I5°K

i I 1 i 1 j i i

NOTE These Pressure Deviations are in the Region of the Critical Point as Shown in Figures 5 and 6 Figure 8. Pressure deviations in the region of the critical point.

Figure 10. Density deviations for data points near the saturation boundary.

1000

2 1400

400 600 PRESSURE (atm)

1800 2200

800

2600 —1

1 I1

1 1

1

—i i

o- - 273 I5°K

-

This Deviation Plot is for Pressures Extrapolated Beyond the Fitted Data _J 1 i 1 l 1 l i i

-

This Deviation Plot is for Pressures Extrapolated Beyond the Fitted Data

1400 1800 2200 PRESSURE (atm)

FIGURE 9. Density deviations of data by Michels et al. [6] from

equation of state (40). FIGURE 11. Density deviations of saturation data from equation

of state (40).

13
PRESSURE (atm)

Figure 12. Density deviations of data by Rogovaya et al. [7] from equation of state (40). Figure 14. Density deviations of data by van Itterbeek et al.

[9] from equation of state (40).

Figure 13. Density deviations of data by van Itterbeek et al.

[8, 9] from equation of state (40).

slopes with not much change in curvature. However,

the isotherms between 148 K and 173 K have large

variations in the slopes and curvatures. In addition,

the slopes of the isotherms in the vicinity of the

critical point are small, thus producing large density

FIGURE 15. Density deviations of data by van fVitzenburg [10] from equation of state (40).

deviations for rather small pressure or temperature

deviations. The small cross-hatched area in figure 16

indicates the region where the density has the great14
Figure 16. Pressure-density diagram showing isothermal

characteristics.

est sensitivity to small variations in pressure or temperature. If the data points in this region are not

included, the mean of the absolute values of the

density deviations is 0.08 percent for the data of

Michels et al. [1]. If the data points in this region are included, the mean deviation in density becomes

0.26 percent for the data of Michels.

Figures 7 and 8 are expanded-scale deviation

plots from figures 5 and 6 and correspond to the

region near the critical point. Figure 7 is a density

deviation plot and shows a systematic trend which

can be attributed to the equation of state. The magnitudes of the density deviations in figure 7 are due

to the extreme sensitivity of the density in this

region. Figure 8 is a pressure deviation plot for the

same region. The systematic trend is still present,

but the magnitudes of the pressure deviations are

significantly smaller than the corresponding density

deviations.

Figure 9 illustrates the density deviations for two

isotherms from the data of Michels et al. [6]. A total

of 94 data points for these two isotherms were fitted to pressures of about 1000 atm. The mean of the

absolute values of the density deviations is 0.034

percent for pressures to 1000 atm, and the data

appear to be consistent with the data of Michels

et al. [1]. In addition, figure 9 shows density deviation plots for the same two isotherms for pressures

from 1000 to about 3000 atm. The equation of state was not fitted to any data above 1000 atm, so the

latter deviation plots represent an extrapolation of

the equation of state for pressures beyond the fitted

data. The density deviations are approximately

constant for this pressure range with a mean density

deviation of 0.15 percent.

Figure 10 exhibits the density deviations for 41

experimental data points of Michels et al. [1] which

are close to the saturation boundary. With the exception of the points close to the critical point the mean

density deviation is 0.05 percent. The density deviations for the data close to the critical point are again due to the extreme sensitivity of the density in

this region.

Figure 11 is a deviation plot for the saturation fine,

showing the density deviations between the 23 data

points of Michels et al. [1] and the saturation densities calculated by the equation of state. Both

saturated liquid and saturated vapor data points are

illustrated. With the exception of the saturated

liquid data points within about 1.5 K of the critical

point, the mean density deviation for the saturated

liquid data is 0.03 percent. With the exception of the

saturated vapor data points within about 2.5 K of

the critical point, the mean density deviation for the

saturated vapor data is 0.24 percent.

Figure 12 is the deviation plot for the data of

Rogovaya et al. [7]. The mean density deviation is 0.17 percent except for the 90.13 K isotherm. This

90.13 K isotherm appears to be inconsistent with

the data of van Itterbeek and Verbeke [8], and

van Itterbeek et al. [9], and exhibits a mean density

deviation of 0.4 percent. Generally, the data of

Rogovaya showed a more random distribution of

density deviations than the data from some of the

other sources. Rogovaya’s data, in general, did not

approach the region near the critical point as closely

as did Michels et al. [1] and,' therefore, no direct

comparison of these two data sources is possible in

this region where the data are difficult to fit. Figure 13 illustrates the density deviation plot

for the data of van Itterbeek and Verbeke [8]. The

mean density deviation for these four isotherms is 0.026 percent. However, the 0.026 percent density

deviation of van Itterbeek et al. [8] cannot be

directly compared with the deviations of the other

data sources since van Itterbeek’s data are in the

high density—low pressure region of the P-V-T

surface where the isothermal derivative ( dP/dp)r is large. In this region small displacements in the isotherms result in small density deviations.

Figures 13 and 14 show the deviation plots for the

data of van Itterbeek, Verbeke, and Staes [9]. Comparisons of the deviations for isotherms of

increasing temperature show a trend of increasing

negative density deviations. This trend is not evident

in the deviation plots for Michels et al. [1], figures

5 and 6, or Rogovaya et al. [7], figure 12. The mean

density deviation is 0.16 percent with the larger

deviations occurring at the higher temperatures.

Figure 15 shows the deviation plot for the data of van Witzenburg [10J. The trend here is opposite that

of van Itterbeek, Verbeke, and Staes. The data of van Witzenburg exhibit an increasing negative

density deviation for increasing temperatures.

15
However, the van Witzenburg data extend to higher

pressures than - most of the other data sources for

equivalent isotherms, and direct comparisons of

density deviations are difficult to make at these

higher pressures. The low temperature, low pres- sure isotherms may be compared with the data of van Itterbeek, Verbeke, and Staes, where it is noted that the van Witzenburg data exhibit density

deviations which are about an order of magnitude

greater in the negative direction. The mean density

deviation for the data of van Witzenburg is 0.30

percent.

Walker [11] displayed his data by isochores.

Comparisons with other data sources were difficult to make since most of the other data were obtained

isothermally. Therefore, Walker’s data were smoothed to a function of the form P = q\ + q-zTfi-q^T2 where the q s are constants. (This function was

deemed adequate since the isochoric data of Walker

was in the liquid region and exhibited only small

deviations from straight lines.) These smoothed

isochoric P-T values were plotted and compared

with other data sources. This plot showed that the

slopes from the fitted function \yere consistent with

the slopes from other data, but the values of the

isochores assigned by Walker did not agree with

others. This disagreement became greater as the

critical point was approached. Therefore, the density values of each of the isochores were redetermined by least squaring the experimental data, one

isochore at a time, and extrapolating that isochore

to the saturated liquid line. Upon comparison, the

original data of Walker deviate from the values

predicted by the equation of state by about 2 percent

in density, with the deviations increasing to about

10 percent as the critical point is approached. However, when comparing the density deviations between the recalculated least square densities and

the densities predicted by the equation of state,

the mean deviation was 0.25 percent. This latter

comparison is, perhaps, a more valid comparison

of Walker’s data, since he was not able to actually measure the mass of his sample experimentally.

Instead, the density values quoted by Walker were

estimated by him from an extrapolation of the isochores to the coexistence line. Private communication from Walker [13] indicated that there were

errors in the original values quoted for the densities, especially near the critical point. The new

values given to us by Walker [13] agreed much more

closely with the values predicted by the equation

of state. Figure 17 illustrates the density deviations for

the data of Michels et al. [6]. These data include

temperatures above 300 K for pressures to about

2600 atm. Since the equation of state was not

fitted to the data in this region, these deviation

plots represent an extrapolation of the equation of

state for temperatures and pressures beyond the

fitted data. The mean density deviation for these

data is 0.15 percent for temperatures to 423 K and

pressures to 2600 atm, which includes a total of

247 data points. The mean density deviations for

0 600 1200 1800 2400 3000

NOTE These Deviation Plots are for Temperatures and Pressures

which are Extrapolations Beyond the Fitted Dato Points

Figure 17. Density deviations for data at temperatures and

pressures extrapolated beyond the fitted data points.

temperatures from 323 to 423 K for pressures to 1000 atm is 0.11 percent. The deviation plots of

figures 5 through 17 display varying amounts of

systematic deviations between the equation of

state and the experimental data. Most of the sys- tematic deviations are small except for the region near the critical point where they become quite

marked, as shown in figures 7 and 8. It should be

noted that these systematic deviations, although

quite small in most cases, are magnified in their

contribution to the calculated derivatives.

Although not used for the final fit, the 112 data

points of Onnes and Crommelin [26] were compared

to the density values predicted by the equation of

state. In general, the data of Onnes et al. exhibited

a greater scatter than the other data sources, with

a mean density deviation of 1.05 percent from the

equation of state. Although the Onnes data were

limited to pressures below 60 atm, some of the

experimental isotherm data overlapped portions of

the experimental range investigated by Michels et al.

[1]. Generally, the Onnes data showed the same

characteristics as the Michels data except for lesser

precision. In almost all cases where comparisons

could be made, the magnitude of the density quoted

by Onnes was smaller than the experimental density of Michels. In a few instances, the Onnes data

could be compared with the data of Rogovaya et al. [7]. Again, the densities quoted by Onnes were

16
smaller than those given by Rogovaya. Some of range included temperatures from 100 K to 5000 K

these latter comparisons indicated that the equa- with pressures ranging from 0.01 to 100 atm. Except

tion of state predicted density values between those for one region, this comparison showed a mean

of Onnes and those of Rogovaya. density deviation of 0.08 percent. The one region

A final comparison was made between the com- where the deviations were greatest was at the high

pilation of the National Bureau of Standards Circular pressure—low temperature end of the tables corn- 564 by Hilsenrath et al. [27] and the values predicted piled by Hilsenrath et al. (pressures near 100 atm for

by the equation of state. A total of 338 points was temperatures near 180 K). For this region, the values

used for this comparison. The points were selected of Hilsenrath et al. were obtained essentially by

so as to well represent the entire range of data extrapolation of existing experimental data, which

compiled by Hilsenrath et al. The temperature may account for the larger deviations.

9. Temperature Scale Conversions

Wherever appropriate, corrections were made to convert the temperatures reported by the investigator to a consistent thermodynamic Kelvin temperature scale based on an ice point of 273.15 K.

In some cases the specific temperature scale used

by the experimenter was not clearly specified. In

these cases, the literature was searched for other

papers or information from the same laboratories,

and conversions were made from these determinations. Different methods for correcting temperatures are possible, but the following were deemed

most appropriate.

Conversions for the data of Michels, Levelt, and

de Graaff [1] and Michels, Wijker, and Wijker [6] from the van der Waals Laboratory were made by

first correcting the temperatures from the van der

Waals thermometer to the International Temperature Scale and then correcting to the thermodynamic

temperature scale. The net correction was less than

0.02 °C which is within the precision of the data.

The corrections from the van der Waals thermometer to the International Temperature Scale were made by using the information furnished by J. M. H.

Levelt-Sengers [28].

The data of Onnes and Crommelin [26], based

upon an ice point of 273.09 K, were converted to the

International Temperature Scale by

r= ^ +273- 09

) Hi

where tc is a reported centigrade temperature.

The data of Clark et al. [14], based upon an ice

point of 273.16 K, were converted to the Inter- national Temperature Scale by

T=(tc + 273M) ff]fCorrections from the International Temperature

Scale to the thermodynamic temperature scale were made by using the tabular information furnished by C. R. Barber [29]. The tabular information

by Barber is shown in table 9.

Table 9. Conversion from international to thermodynamic temperatures

Temperature, °C 1 3

-10 0.005 -20 .011 -30 .017 -40 .024 -50 .0295 -60 .034 -70 .0365 -80 .036 -90 .032 -100 .0245 -110 .015 -120 .0025 -130 -.010 -140 - .020 - 150 -.024 -183 0

10. Derived Thermodynamic Properties

The calculation of entropy, enthalpy, and internal

energy was performed by using the equation of

state (40), the zero pressure (ideal gas) and specific

heat (cp), and the vapor pressure equation (14).

The relationships for calculating these derived

properties have been described by Gosman [22],

and Hust and Gosman [30], and are presented below.

The entropy of the gaseous phase, as well as the

saturated vapor, was expressed as

S = S°r0 -R In R

_P

j_ (dP

o

2 \BT

dp

dT

T‘

(49)

For eq (49) the reference entropy, SPo — 3.23367

J/g — K, for the ideal gas at Po = l atm, and the

normal boiling point temperature at To — 87.28 K

was selected from Hilsenrath et al. [27]. The ideal

gas specific heat, c£ =f/? = 0.520320 J/g — K, was

also taken from Hilsenrath et al. The enthalpy of the gaseous phase was ex- pressed as

fp r P T H = Hr0 +

Tj 0 lp- P

2

/ dP

KBT/,, j

dp + -P

-RT+ r c°P dT.

JTo (50)

17
Compilations often do not tabulate //£o

. Many times

these compilations tabulate H°0 —Uo, where Uo is the ground-state energy. For purposes of con- sistency with these compilations, a value of

Ht0 — Uo = 45.4119 J/g (for the ideal gas at 87.28 K) was selected from Hilsenrath [27]. Then, in order

to obtain Hj0 for eq (50), a value of U°0 = 192.5197 J/g

was assigned to the ground-state energy. This

value of Uo was selected so that the enthalpy of

the saturated liquid at 1 atm pressure agrees with

the value given by Din [31].

The equation of state (40) wr as then substituted

into eqs (49) and (50). Upon integration, the resulting

expressions are

S = S°t0 -R In fM ^ dT

To 1

+ P ^1 I rji >4 >5 Un2 9

' rji 3

I rji§ ^6 \ o / ^8

2 rp (t

I 9\ /2;i9 — , 3njo , 4nn\ /n exp (—

n

16p

2

)

I — + /2ni 6

-exp <-">«P

2 )(^+^r)(^

3niQ , 4n14 7M Jh

(51)

and

H=m0 +^-RT+ CpdT+

p ^

, 2 n3 , 3 n4 , 5n3

7^2 rji rji 2

' M!)

1 /3na 4nio , 5nn

2rc 16

2^16 \T2 1 y3 1 J-4

1 )(

3/li2

1 4"13

l 5ni4

2niJ \

1 1 J

1 4

J

exp (— rc 16p

2

)

^ exp (— n l6p

2

)

+ p

5 \ , 1

|

. 4ttio 5nn\

/ +2nJ\T2

1 J"3 h T<)

1 / 3»12 , 4/113 , 5^14 \

2n?6 V r

2 r3 f*)' (52)

The internal energy was obtained from

U = H-P/p• (53)

The method of calculation proceeded as follows:

a. The properties of the gaseous phase and sat- urated vapor were calculated with the use of

eqs (51), (52), and (53). b. The volume of vaporization (V^—V1 ) was

calculated with the use of the equation of state (40)

and the vapor pressure equation (14).

c. The slope of the vapor pressure curve dP/dT

was obtained from eq. (14).

d. The entropy and enthalpy changes due to va- porization were calculated with

dP _ S» -Sl dT~ Vy — V

and

H»-Hl =T(S»-S1 )-

18
e. The saturated liquid properties were obtained

by subtracting the entropy and enthalpy changes

due to vaporization from the saturated vapor value.

f. The saturated liquid line, as calculated in

step e, was then used as the datum point for cal- culating properties below the critical temperature and densities greater than those of the sat- urated liquid. These properties were calculated

by the isothermal integration of the appropriate

portions of eqs (49) and (50). These expressions are

Table 10. Adjustments for entropy and

enthalpy of the saturated liquid

Temperature K

Entropy J/g-K

adjustment ;1

Enthalpy

adjustment d

150 0.009539 1.431 149 .009750 1.453 148 .008768 1.298 147 .007549 1.110 146 .006330 0.924

145 .005189 .752 144 .004160 .599 143 .003249 .465 142 .002460 .349 141 .001789 .252

140 .001239 .173 139 .000811 .113 138 .000490 .068 137 .000260 .036 136 .000100 .014 135 .000010 .001

a These adjustments have been subtracted from the entropy and enthalpy of the saturated liquid.

By progressing through the above procedure, the

derived properties were calculated for the entire

portion of the thermodynamic surface under

consideration. However, the method of calculation outlined above may result in a discontinuity.

This discontinuity exists at temperatures below

the critical temperature for pressures above the

critical pressure. The cause of the discontinuity

arises from the fact that the calculation of the

derived properties was performed by one procedure for temperatures above the critical temperature and a second procedure for temperatures

below the critical. For temperatures below the

critical, the changes of entropy and enthalpy due

to vaporization had to be calculated as outlined

in step d, and the saturated liquid line obtained as outlined in step e. For temperatures above the

critical, steps d and e were not needed for the

calculation of derived properties. The mutual

boundary (at the critical temperature) between

these two regions then exhibited the discontinuity. This discontinuity in the derived properties

is possibly due to slight disagreement between the

isochoric slope of the equation of state (40) at the

critical point and the slope of the independently

obtained vapor pressure equation (14) at the same

point.

When the discontinuities were plotted with a highly expanded scale, it was determined that the

discontinuity was independent of pressure. Adjustments to the derived properties were then determined by smoothing the transition region for

isobars near the critical. These adjustments were

applied to the derived properties by making appropriate corrections to the entropy and enthalpy

of vaporization. The adjustments were added to the

entropy and enthalpy of vaporization, thus decreasing the values for the entropy and enthalpy of the

saturated liquid. Table 10 lists the temperature

dependent adjustments which were made.

All of the data which have been calculated were

restricted to the liquid and gaseous regions by using

the following melting curve relationship:

Pmelt Pt + A (54)

In eq (54), A and C are constants which were

determined by a least squares fit to experimental

data. The form of this melting curve relationship

is discussed by Goodwin and Weber [32].

The experimental data which were considered

for the determination of the constant in eq (54) were taken from Michels and Prins [33], Lahr and

Eversole [34], and Bridgman [35]. The constants of

eq (54) were determined to be

A = 2078.76667

C= 1.59817868,

with a mean of the absolute pressure deviations

of 0.08 percent.

The properties, density, enthalpy, internal

energy, and entropy, are presented as functions of

pressure and temperature in the tables of appendix

A. The number of significant figures given in these

tables is not justified on the basis of the uncertainties of the data, but, rather, is desirable to maintain the internal consistency of the tables.

A comparison of the heat of vaporization was

made at the normal boiling point. The heat of

vaporization of various investigators was compared

with the value obtained by using the equation of

state (40) and vapor pressure equation (14). This

comparison is shown in table 11.

TABLE 11. Comparison of heat of vaporization

at the normal boiling point

Frank and Clusius [36] 1557.5 ±1.5 cal/g-mol Flubacher et al. [15] 1555 .0 + 4.6 cal/g-mol Eucken [37] 1501 cal/g-tnol Ziegler et al. [2] 1543.4 cal/g-mol This work 1546.3 cal/g-mol

19
11. Equation of State and Saturation Boundary

The saturation boundary can be defined by the

equation of state if there is a sufficient number

of highly precise experimental P-V-T data points

along the entire boundary. However, saturation

densities are difficult to measure with high precision. In addition, for argon there was only one

source of satisfactory saturation data, and these

data did not cover the entire two-phase boundary.

Therefore, it was difficult to perform a critical

evaluation of these saturation data for the purpose

of determining the saturation boundary.

Instead, there was available a relatively large

number of P-T data points along the saturation

boundary. For these data, the vapor pressure equation (14) was developed. Therefore, the definition

of the saturation boundary was obtained by the use

of two independent equations — the equation of

state (40) and the vapor pressure equation (14).

The saturation boundary, as defined by the

equation of state alone, was then examined for

internal thermodynamic consistency by using the

conditions of thermodynamic equilibrium:

T

l = T9 pi = pv

Gl = G9 . (55)

The equation of state (40) is a continuous function

with a van der Waals form across the saturation

boundary. Therefore, the equation for thermodynamic equilibrium (55) could be substituted into

the equation of state (40). This was accomplished

for a given saturation temperature by imposing

the equilibrium conditions upon both tbe equation

of state and the equation for the Gibbs function

derived from the equation of state and solving them

iteratively and simultaneously for the corresponding

density. By this means the entire saturation boundary was derived by the use of the equation of state and the conditions of thermodynamic equilibrium,

without using the independently obtained vapor

pressure equation (14).

A comparison of the vapor pressures as derived

from the equation of state and the vapor pressures

as obtained from the vapor pressure equation was

made. The results of this comparison are shown in

table 12 for 5-deg temperature increments.

The agreement shown in table 12 indicates that

the equation of state is internally consistent with

the conditions of thermodynamic equilibrium.

Table 12 also indicates that the equation of state

satisfactorily predicts P-V-T values in the vicinity

of the saturation boundary.

Table 12. Vapor pressure comparison

r, k Pi, Atm P2 , Atm Px-Pt

85 0.77945 0.79737 -0.01792

90 1.32133 1.34210 -.02077

95 2.11103 2.13029 -.01926

100 3.20974 3.22249 -.01275

105 4.68121 4.68277 -.00156

110 6.59102 6.57784 .01318 115 9.00650 8.97649 .03001 120 11.99740 11.94960 .04780

125 15.63733 15.57082 .06651 130 20.00587 19.91829 .08758

135 25.19168 25.07827 .11341 140 31.29662 31.15296 .14366 145 38.44154 38.28020 .16134 150 46.77419 46.71197 .06222

Pi is calculated from vapor pressure equation (14). P2 is calculated from equation of state (40).

12. Second Virial Coefficient and Intermolecular Potential

An equation of state which has been extensively

used isPV

— Z — 1 + Bp + Cp2 + Dp3 + . . . , (56)

where B, C, D, . . . are virial coefficients and represent deviations from ideal gas behavior. The

virial coefficients are functions of temperature and

are related to interactions between molecules. The

second virial coefficient, B , is related to interactions

between two molecules, the third virial, C, to the

interaction between three molecules, etc. When

the gas has negligible molecular interaction as compared to interaction with the walls of the confining vessel, then eq (56) reduces to the perfect

gas where Z= 1. The virial coefficients for the equation of state

(40) were obtained by arranging the equation of

state into virial form as shown in eq (56). In order

to obtain the proper form, the exponential term of

eq (40) was expanded as

exp (- n16p

2

) = 1 — (n 16p

2

)

, (”i6p

2 y

2!

( ft i op

2

) 3

3!

Substituting eq (57) into eq (40),

^=l+p(

+ P

2

+ P

4

ftl

- ^ -4 n3

1 U

4

1 ft5 R ' RT RT2 RT3 RT5

' 4- - ft;,

, nio ftn R RT RT3 RT4 RT5

n12 , ftl3 ft 14 ft 16 ftp RT3 RT4 RT5 RT3

ftieftio ft i6ft i i RT4 RT5

(57)

+ p

:

+ . . (58)

20
,

cm 3/

mole

In eq (58), the coefficient of p is the second virial

coefficient, the coefficient of p

2 is the third virial

coefficient, etc. The second virial coefficient was calculated from

eq (58). These coefficients, as functions of temperature are listed in table 13. A comparison between the second virial coefficient calculated by

using the virial equation of state (58) and other

published data is shown in figure 18. Except for the data of Kerr [39], figure 18 illus- trates that eq (58) represents the second virial coefficients within the uncertainty of the data for

temperatures from about 120 to 300 K. Kerr’s virial

data do not appear to have the precision of the

Table 13. Second virial coefficients as calculated from virial equation of state (58 )

Temp. K

B

Temp. K

B

90 -215.22 200 -47.18

100 - 180.09 210 -42.20 no -152.39 220 -37.79

120 - 130.32 230 -33.86

130 - 112.47 240 -30.33

140 - 97.84 250 -27.15

150 - 85.69 260 -24.27

160 - 75.47 270 -21.65

170 - 66.78 280 - 19.26 180 - 59.31 290 -17.07

190 - 52.83 300 -15.05

B has units of cm3/mol.

0

20

40

60

80

100

120

GG

I 140

160

180

200

220

240

80 100 120 140 160 180 200 220 240 260 280 300 TEMPERATURE , °K

MICHELS , ET AL. [I] MICHELS, ET AL. C63 KERR [391 FENDER AND HALSEY [40] WEIR , ET AL. [49] ONNES AND CROMMELIN [26] HOLBORN, ET AL. [41,50,51,52] HILSENRATH , ET AL [27] VAN ITTERBEEK , ET AL. [53] FROM

SOUND VELOCITY AND HOLBORN SECOND VIRIAL VAN ITTERBEEK, ET AL [53] FROM SOUND VELOCITY AND ONNES

SECOND VIRIAL CALCULATED FROM EQUATION (58) CALCULATED FROM 18-6 POTENTIAL FUNCTION

other data sources. For temperatures below 120 K,

eq (58) appears to predict virial coefficients which

are about 2 percent high. Fender and Halsey [40]

estimate their error to be about 1.5 percent, and it is therefore concluded that eq (58) is a satisfactory

representation of the virial coefficient data.

The second virial coefficient may also be theoretically calculated if a mathematical model for

the intermolecular force potential is selected. A

number of force potentials have been advanced

and some of these are discussed in Hirschfelder,

Curtiss, and Bird [38] and Gosman [22].

The Lennard-Jones 12-6 model for the potential

function is the one most commonly used and was

therefore investigated. The expression for the

energy for the 12-6 potential is

E = 4e (59)

Using eq (59), the expression for the reduced sec- ond virial coefficient is obtained as illustrated by

Gosman [22]:

B* =

oo 2

(60)

With eq (60) and the equations

€

h°o — B*

2

b0 = -TrNa3

, 3 (61)

the two parameters e and cr were obtained by the

method described in Gosman [22].

It was found that the two parameters, e and cr, of the 12-6 potential are not truly constants, but

are somewhat temperature dependent. It was also

found that the higher temperature isotherms (about

300 K) are relatively insensitive to variations in the

parameters. At the lower temperatures, however,

relatively small variations in the parameters result

in large variations in the second virial coefficient.

This effect was demonstrated for argon by Gosman

[22] and shown to be a general property of the re- lationship between second virial coefficients and

potential functions by Hanley and Klein [44].

For the temperature range of 90 to 300 K a set of parameters for the Lennard-Jones 12-6 potential was determined to be

e/k= 112.4 K

6o = 57.7 cm3 Figure 18. Comparison of second virial coefficients. /mol.

21
Using these parameters, the mean deviation in B

from values calculated by eq (58) was 0.78 cm3

/ mol.

It is of interest to compare the values of these

parameters with values determined by other

sources. Holborn and Otto [41] found e/A:=122

and bo = 49.58 for temperatures between 173 and

673 K. Michels, Wijker, and Wijker [6] found

e/k — 119.8 and 60 = 49.8 for temperatures between

273 and 423 K. Since the latter two sets of parameters were obtained for relatively high temperature

data, it is expected that the value of e/k would be

larger than that obtained in this evaluation.

Since the 12—6 potential appears to be satisfactory

for limited temperature ranges only, other forms

of the potential function were investigated. Using

the basic technique developed by Hanley [42] the

family of “ra-6” functions was evaluated along

with the Kihara potential function. The “ra-6”

functions were calculated by using the values of

the reduced second virial coefficients as presented

by Klein [43]. The results of these calculations

are shown in figure 19. Figure 19 shows the deviations between second

virials as calculated by the various potential functions and those calculated by the virial eq (58). The

deviations in second virial for the 12—6, 15—6, 18-6,

and Kihara potential functions are all illustrated

in figure 19. It is noted that the Kihara and the

15-6 functions are almost identical over the whole

temperature range. This similarity between potential functions is discussed by Hanley and Klein

[44]. For the temperature range of 90 to 300 K the

set of parameters for the Kihara potential was

determined to be

e/k = 125 K

p0 = 3.711 A

a — 0.080 A.

Using these values for the Kihara potential, the

mean deviation in B from values calculated by eq

(58) was 0.53 cm3 /mol.

The 18-6 potential shows a negligibly small

deviation in second virial above 120 K. Below 120

K, figure 19 shows that the virials calculated by

the 18-6 function deviate from those calculated

by eq (58). However, this was the temperature

range where eq (58) predicted virials which were

2 percent too large. A comparison of the virials

calculated by the 18-6 function with the original

data shows that the 18-6 function predicts the

virial coefficients to about the uncertainty of the

data. The 18—6 function is also shown in figure 19

to illustrate this point.

The parameters for the 18-6 function were

determined to be

e/k= 157.5 K

cr = 3.28 A.

Using these values for the 18-6 function, and

omitting the deviations below 120 K. the mean

deviation in B is 0.14 cm3 /mol.

A final calculation was made for the second virial

coefficient to determine the corrections due to quantum effects. The relationships which were

used to calculate these second virials with quantal

corrections for both the 12-6 and the Kihara potentials are given by Hirschfelder et al. [38]. The

results indicated that the quantal corrections are a

fraction of one percent, even at the lower temperatures. The magnitude of the quantal correction is within the uncertainty of the published experimental

data.

Figure 19. Potential function comparison.

22
13. The Joule-Thomson Inversion Curve

The Joule-Thomson coefficient, //,, is defined as the slope of an isenthalpic curve on the P-T coordinate system:

(62)

Equation (62) may be rewritten for more convenient

evaluation with the equation of state (39):

CP P

2 (dP W

dP\

dT/ p 1p

(63)

The Joule-Thomson inversion curve is defined as the locus of points where /jl = 0, and may be cal- culated from

T \dT)p 1 P

2 (df) P

\dp/ T

(64)

In eq (64), the partial derivatives were evaluated

from the equation of state (39). Equation (64) was programmed for an iterative solution to find the

values of density and temperature which satisfied

the equation. Pressure values were then calculated

from the equation of state for the appropriate

densities and temperatures.

The Joule-Thomson inversion curve data as cal- culated by eqs (64) and (39), are given in table 14

for 10-deg intervals.

Table 14. Inversion curve from eq (64)

Temp. KPressure Atm

Temp. K

Pressure Atm

130 69.27 220 431.68

140 128.64 230 454.08

150 181.92 240 473.88 160 229.83 250 491.23

170 272.96 260 506.28

180 311.83 270 519.19

190 346.81 280 530.07 200 378.27 290 539.04 210 406.48 300 546.22

Figure 20 illustrates the inversion curve and

shows the comparison with other data sources. The solid line represents the locus of inversion curve points as calculated by eqs (64) and (39).

The solid line is terminated at 300 K, which is the temperature limit of the data fitted by the equation of state (39). The dashed portion of the inversion curve above 300 K represents the locus of

points as calculated by eq (64) with data from the

equation of state which have been extrapolated

beyond the fitted region.

Figure 20 also shows the inversion curve data

obtained by Roebuck and Osterberg [45] in 1934.

In 1940, Roebuck and Osterberg [46] published a

FIGURE 20. Inversion curve comparisons.

paper indicating that a numerical error in the pres- sure data had been made. Therefore, the Roebuck

and Osterberg [45] data shown in figure 20 have

been adjusted by the appropriate correction. The

mean of the absolute values of the deviation in

inversion temperatures between the corrected data

of Roebuck and the values calculated by eq (64)

is 1.1 percent.

Michels, Levelt, and Wolkers [47] published

Joule-Thomson coefficient data for temperatures

from 133 K to 273 K. From these data, the inversion curve pressures and temperatures were obtained

by determining where the Joule-Thomson coefficient was equal to zero. The inversion curve data of

Michels et al. [47] determined in this manner, are shown in figure 20. The mean deviation between

the Michels inversion curve temperatures and the

temperatures calculated by eq (64) is 0.30 percent.

Michels, Lunbeck, and Wolkers [48] published

Joule-Thomson coefficient data for temperatures

from 273 to 423 K. Although the equation of state was not fitted to data above 300 K, a comparison

of the data of Michels and the calculated inversion curve is shown in figure 20. The mean deviation in inversion temperatures between the Michels et al. [48] data and the extrapolated values of eq (64)

is 1.1 percent.

The maximum inversion temperature as cal- culated by eq (64) is about 794 K. Based on the

Lennard-Jones 12—6 potential, Hirschfelder et al. [38] shows that the theoretical maximum reduced

23
inversion temperature is 6.47. With this value of

reduced temperature and a selected value for the

ejk parameter of the 12—6 potential, the theoretical

maximum inversion temperature was calculated.

If the value, e/A:=122, obtained by Holborn and

Otto [41] for temperatures up to 673 K is used, the

theoretical maximum inversion temperature is 789 K. The deviation between the theoretical maximum inversion temperature and the value calculated by eq (64) is about 0.6 percent. If the value,

e/k= 119.8, obtained by Michels et al. [6] for temperatures up to 423 K is used, the theoretical maximum inversion temperature is 775 K, giving a deviation of about 2.5 percent. Based upon the

18—6 potential, with a value of e/

k

=157.5, the

theoretical maximum inversion temperature is 770 K, giving a deviation of about 3 percent from

the value calculated by eq (64).

The significance of the inversion curve as a test for the equation of state (39) may be seen by noting

that the inversion curve eq (64) involves derivatives

of the equation of state. As illustrated in figure 20

and as previously mentioned, the deviations between the calculated inversion curve and the data

from other sources are relatively small. Therefore

it may be concluded that the geometric slope of the

physical thermodynamic surface is adequately

described by the equation of state (39).

The specific heats of a gas at constant pressure

and constant volume are given by

and

c’= r (!l

14. Specific Heats

The Cp and Cv illustrated in figures 21 and 22 were calculated by forming the

(^fj

and

numerically with (AS/AT)V and (AS/A7%, where AT

was 0.005 K and AS was calculated using the equations given in section 10. These numerically ob-

(65)

90 100 150 200 250

TEMPERATURE, °K

Figure 21. Specific heat at constant pressure calculated by numerical method.

300

24
from the equation of state (39). Such comparisons were made in all regions of the P-V-T surface

except the compressed liquid region where the

continuous expressions were not possible. The

differences in the specific heats obtained by the

two methods were on the order of 10~5 of the total

value.

Both the Cv and the Cp diagrams omit the isobars

above 100 atm between 130 and 150 K, i.e., areas enclosed by dashed boxes (figs 21, 22). The specific

heats calculated from the equation of state in this

range of temperature and pressure exhibited erratic

behavior inconsistent with the rest of the surface.

This behavior is probably caused by the adjustments

made to the entropy and enthalpy values for the

saturated liquid (see sec. 10).

Comparisons were made between experimental

specific heat data and values calculated from the

equation of state. With the exception of the low

temperature compressed liquid region and the

critical region the agreement was good. The deviations were usually less than 5 percent and averaged

about 1 percent. Experimental Cv specific heat

data near the critical point such as the data of

90 100 150 200 250 300

TEMPERATURE, °K

Figure 22. Specific heat at constant volume calculated by numerical method.

25

Voronel et al. [54] disagree with the values cal- culated from the equation of state by as much as 53 percent with an average deviation of 40 percent.

The only experimental specific heat data available

for the compressed liquid region below 110 K were

those of van Itterbeek et al. [9]. The agreement

between these data and values calculated from the

equation of state was poor, the average deviation

being about 15 percent, in Cv and 5 percent in Cp

. However, these experimental data appear to have

sojne internal inconsistency, and it is difficult to assess their reliability. Unfortunately no other

experimental data exist in this region, leaving it somewhat in doubt. Good agreement was obtained

between the calculated specific heats and the

experimental data of Lestz [55]. These data were

taken at temperatures of 273.15 and 303.7 K at pressures to 12 atm. The maximum deviation between calculated values and these data for both

Cp and Cv is 0.37 percent. The data of Michels et al. [47] and Michels et al. [48] cover a temperature

range from 133.15 to 423.15 K with pressures to 2423 atm. Excluding the critical region and the

compressed liquid where deviations ranged to 9
percent, the maximum deviation between experimental and calculated CVs was 6.4 percent at 2423

atm and 398.15 K. The maximum Cp deviation for

this group of data was 5.8 percent at 163.15 K and

70 atm. The specific heat data of Walker [11] were

also compared with values calculated from the

equation of state. The agreement between these data

and the calculated values was slightly worse than

the agreement obtained with Michels’ data. However, the reliability of these data is believed to be

less than that of Michels.

Comparison of the specific heats calculated here

and those tabulated by two other correlations re- vealed satisfactory agreement. The Cp s tabulated

by Hilsenrath et al. [27] for temperatures of 240 K

and above agree with the values calculated here to better than one percent. However, the Cp s tabulated by Hilsenrath et al. [27] for temperatures below

240 K do not agree as well, especially at the high

pressures. For example, at 200 K and 100 atm, the

disagreement is about 10 percent in Cp while the

value tabulated by Din [31] for this temperature and

pressure agrees with this report to within 1.5 percent. The average deviation in Cp between this

report and Din [31] is about 1.5 percent, which is much greater than the average deviation between

this report and Hilsenrath et al. [27].

It is difficult to formulate a single equation of

state which predicts valid P-V-T values over the

liquid, vapor and critical point regions, and which

also permits accurate calculation of specific heats.

The specific heat of a fluid is a function of the

second derivative of the equation of state. As

pointed out in section 8, slight systematic deviations between the experimental P-V-T surface and

the equation of state become magnified when derivatives are taken. The effect of these deviations

becomes greater as higher order derivatives are taken and, in the region of the critical point where

the equation of state has the largest systematic

deviations, the second order derivatives contribute

large errors to the specific heats.

15. Conclusions

An equation of state has been developed which

represents the experimental P-V-T data for both the

liquid and vapor phases, with a consistent transition

from the low temperature-high density region to the low density region. Since some of multiple data sources are inconsistent where they overlap, it is difficult to assign an overall “figure of merit” for the

adequacy of the equation of state as compared to an

experimental P-V-T surface. In general, the equation of state represents the different sources of

experimental data to within the accuracy of the

data except in the region of the critical point. Nu- merous deviation plots have been presented so that

direct comparisons between the equation of state and each source of experimental data can be made.

In the region of the critical point, the equation of

state has a mean density deviation of about one percent and shows a systematic trend which can be

attributed to the form of the equation of state. The

critical point region has isotherms which undergo

large changes in their first and second derivatives.

Therefore, it is difficult to represent this critical

point region and, at the same time, represent the

liquid and vapor regions with a single analytic equation of state. The difficulty near the critical point is magnified when considering the apparent divergence of the specific heat at constant volume (which

is related to the second derivative of the equation

of state) which was found experimentally by Voronel

et al. [54] and discussed by Levelt-Sengers and

Vicentini-Missoni [56].

Attempts have been made to include the nonanalytic character of the equation of state, as discussed by Levelt-Sengers and VicentiniMissoni [56]. However, at the present, insufficient

progress has been made in including this nonanalytic behavior in equations of state which are

explicit in pressure or density and cover a large

range of the P-V-T surface.

Recent comments by Heller [57] and Pings and

Teague [58] indicate that the critical temperature

(and hence the critical pressure) stated earlier in

this work may be slightly in error. However, definitive experimental verification of these comments

is not yet available and the values for the critical

temperature and pressure stated in this work appear

to be the best estimate which is available at this

writing.

Since the development of the equation of state,

some new data on the P-V-T measurements of

liquid argon have been published by van Witzenburg and Stryland [59]. These data cover the region

from about 95 to 150 K at pressures from about 100

to 1900 atm. A comparison was made between these

data and the values of density predicted by the equation of state. For the 38 points at 115 K and below,

the mean density deviation was 0.15 percent, with one point having a maximum deviation of 0.5 per- cent. For the 126 points from 120 to 150 K, the mean

density deviation was 0.3 percent with three points

having a maximum deviation of 0.5 percent. Van

Witzenburg and Stryland state that there were two

small regions where their data could be compared

with other investigators. One of these comparisons

shows that the density values of van Itterbeek et al. [9] were consistently higher than van Witzenburg

by about 0.4 to 0.5 percent. Comparison of the same

van Itterbeek data with the values predicted by

the equation of state developed here shows that

the densities of van Itterbeek are consistently

higher by about 0.2 to 0.3 percent. The second comparison which could be made shows that six data

points of Michels et al. [1] had densities which were

about 0.25 percent lower than van Witzenburg.

26
Comparison of the same six points of Michels

with the values predicted by the equation of state developed here shows a mean density deviation of

0.03 percent.

An abundance of thermodynamic data for argon

is available in the literature. However, it is only

quite recent that investigators have begun to appreciate the inherent difficulties associated with

obtaining good data in the region of the critical point.

New techniques are being utilized to investigate

critical point behavior, and older techniques are being updated to include the high precision which

is necessary to describe this region. Theoretical

studies are being made to try to understand the

behavior in this interesting region. But much more

experimental and theoretical work has yet to be

done before a complete and definitive description

of this critical region can be obtained.

16. Acknowledgements

The principal support for this work was furnished

by the National Aeronautics and Space Administration, Office of Advanced Research and Technology, Contract R-06-006-046.

We wish to acknowledge the Mechanical Engineering Department of the University of Iowa,

where this work began as a dissertation. In particular, we would like to acknowledge the guidance

and assistance of J. Merle Trummel, of the University of Iowa, who served as academic advisor

to the first author.

We are also grateful to R. B. Stewart, presently

at Worcester Polytechnic Institute, for his com- ments and valuable suggestions during the initial phases of this work.

The authors also take pleasure in acknowledging

the help of N. A. Olien, L. A. Hall, and the staff of

the Cryogenic Data Center of the National Bureau

of Standards at Boulder, Colo., who offered their

valuable assistance in conducting an exhaustive

literature search.

316-977 0 - 69-3

27
PRESSURE,

psia

200

300

400

600

800

1000

2000

3000

4000

6000

z ‘aoiovd AiniaissaddiAioo m'trOcvj — o <j> op h, <0 m 10 c\i 8

8

8

ro

O

O

CJ

o

o

o

00

8

8

o

o

ro

O

CM

O

00

CD

in

ro

CM

z ‘aoiovd Ainiaissaadwoo

28

PRESSURE,

atmospheres

Figure

23.

Compressibility

factor

chart.
TEMPERATURE,

°K

ENTROPY, BTU/lb°R

6 7 8

i—I—

r

D-61

300

275 -

250

225

200

2.5 30

ENTROPY, Joules /q *K

FIGURE 24. Temperature-entropy chart. 29

540

500

450

400

350

300

250

200

TEMPERATURE,

*R
17. References

[1] Michels, A., Levelt, J. M., and de Graaff, W., Compressibility isotherms of argon at temperatures between — 25 and — 155 degrees C and at densities up to 640 amagat

(pressures up to 1050 atmospheres), Physica 24, 659-671

(1958).

[2] Ziegler, W. T., Mullins, J. C., and Kirk, B. S., Calculation

of the Vapor Pressure and Heats of Vaporization and Sublimation of Liquids and Solids, Especially Below One

Atmosphere Pressure. II. Argon, Georgia Inst. Tech.,

Eng. Exp. Sta., Tech. Rept. No. 2 (June 1962).

[3] Bureau of the Census, U.S. Dept, of Commerce Current

Industrial Reports 1928A(65)— 13 supplement 2 issued

Jan. 20, 1967 for 1965 production of Industrial gases.

[4] Hall, L. A., Hust, J. G., and Gosman, A. L., A Bibliography

of Thermophysical Properties of Argon from 0 to 300 °K,

NBS Tech. Note 217 (June 1964).

[5] Hirschfelder, J. O., Buehler, R. J., McGee, H. A., and

Sutton, J. R., A generalized equation of state for both

gases and liquids. I., Wisconsin, Univ. Naval Research

Lab., Dept, of Chemistry, Tech. Rept., Wis-Oor-15

(Oct. 5, 1956) Ind. Eng. Chem. 50, 375-385, 1958.

[6] Michels, A., Wijker, H., and Wijker, H. K., Isotherms of argon between 0 and 150 degrees C and pressures up to 2900 atmospheres, Physica 15, No. 7, 627-633 (1949).

[7] Rogovaya, I. A., and Kaganer, M. G., Compressibility of argon at low temperatures up to 200 atmospheres, Russ.

J. Phys. Chem. 35, 1049-1050 (1961) (English translation), Zhur. Fiz. Khim. 35, 2135—2136 (1961).

[8] van Itterbeek, A., and Verbeke, O., Density of liquid nitrogen

and argon as a function of pressure and temperature,

Physica 26, No. 11, 931-938 (1960).

[9] van Itterbeek, A., Verbeke, O., and Staes, K., Measurements

on the equation of state of liquid argon and methane up to 300 kg/sq cm at low temperatures, Physica 29, 742—754

(1963).

[10] van Witzenburg, W., The Equation of State of Liquid and

Solid Argon, Toronto Univ., Canada, Ph. D. Thesis (1963).

[11] Walker, P. A., The Equation of State and the Specific Heat

of Liquid Argon, University of London, Ph. D. Thesis

(1956).

[12] Private communication from O. Verbeke, Laboratorium voor Lage temperaturen, Leuven, Belgium (1965).

[13] Private communication from P. A. Walker, Research Laboratories, General Electric Co., Ltd., Wembley, Middlesex,

England (1961).

[14] Clark, A. M., Din, F., Robb, J., Michels, A., Wassenaar, T., and Zwietering, Th., The vapour pressure of argon, Physica 17, No. 10, 876-884 (1951). 116th publication of the van der Waals Fund, Amsterdam, Nederland.

[15] Flubacher, P., Leadbetter, A. J., and Morrison, J. A., Thermodynamic Properties of Argon, Proceedings of the

International Conference on Low Temperature Physics,

7th, Toronto, Canada, 1960, pp. 695-697 (1961).

[16] van Itterbeek, A., de Boelpaep, J., Verbeke, O., Theeuwes,

F., and Staes, K., Vapour pressure of liquid argon, Physics 30, No. 12, 2119-2122 (Dec. 1964).

[17] Mathias, E., Onnes, H. K., and Crommelin, C. A., On the

rectilinear diameter for argon, Communs. Phys. Lab., Univ. Leiden, No. 131A (1912), Proc. Acad. Sci., Amster- dam 15, 667-673 and 960-965 (1912); Verslag Gewone

Vergader Wis- En Natuurk. Afdeel. Kon. Akad. Wetenschap, 700-706 and 893-898 (1912); Ann. Phys. 17,

442-455 (1922).

[18] Guggenheim, E. A., The principle of corresponding states,

J. Chem. Phys. 13, 253-261 (1945).

[19] Stewart, R. B., The Thermodynamic Properties of Oxygen,

State Univ. of Iowa, Iowa City, Ph. D. Thesis (June 1966).

[20] Hust, J. G., and McCarty, R. D., Curve-fitting techniques

and applications to thermodynamics. Cryogenics 7, 4,

200-206 (Aug. 1967).

[21] Hoge, H. J., Vapor Pressure and Fixed Points of Oxygen

and Heat Capacity in the Critical Region. J. Res. NBS 44,

321-345 (1950) RP2081.

[22] Gosman, A. L., Thermodynamic Properties of Argon in the Liquid and Gaseous State for Temperatures From the Triple Point to 300 °K With Pressures to 1000 Atmospheres, State Univ. of Iowa, Iowa City, Ph. D. Thesis

(Aug. 1965).

[23] Benedict, M., Webb, G. B., and Rubin, L. C., An empirical

equation for thermodynamic properties of light hydrocarbons and their mixtures, J. Chem. Phys. 8, 334—345

(Apr. 1940).

[24] Bloomer, O. T., and Rao, X. N., Thermodynamic properties

of nitrogen, Inst. Gas Tech. Res. Bull. 18 (Oct. 1952).

[25] Strobridge, T. R., The Thermodynamic Properties of Nitro- gen from 64 to 300 °K between 0.1 and 200 Atmospheres,

NBS Tech. Note No. 129, PB 161630 (1962).

[26] Onnes, H. K., and Crommelin, C. A., Isotherms of monatomic gases and of their binary mixtures. VII. Isotherms

of argon between 20 degrees and — 150 degrees, Proc. Acad. Sci. Amsterdam 13, 614-625 (1911) reprinted in Communs. Phys. Lab. Univ. Leiden No. 118b (1911).

[27] Hilsenrath, J., Beckett, C. W., Benedict, W. S., Fano,

L., Hoge, H. J. Masi, J. F., Nuttall, R. L., Touloukian,

Y. S., and Woolley, H. W., Tables of Thermal Properties

of J^ases, NBS Circ. No. 564 (1955), reprinted as Tables

of Thermodynamic and Transport Properties of Air, Argon,

Carbon Dioxide, Carbon Monoxide, Hydrogen, Nitrogen,

Oxygen, and Steam (Pergamon Press, Oxford, 1960)

478 pp.

[28] Private communication from J. M. H. Levelt-Sengers, National Bureau of Standards, Gaithersburg, Md (1964).

[29] Private communication from C. R. Barber, National Physical Laboratory, Teddington, Middlesex, England (1967).

[30] Hust, J. G., and Gosman, A. L., Functions for the calculation of entropy, enthalpy, and internal energy for real

fluids using equations of state and specific heats. Advances in Cryogenic Engineering 9, 227-233 (1964).

[31] Din, F., Argon, Thermodynamic Functions of Gases, Vol. 2,

pp. 146—201 (Butterworths Scientific Publications, London, 1956).

[32] Goodwin, R. D., and Weber, L. A., A Comparison of Two

Melting-Pressure Equations Constrained to the Triple

Point Using Data for Eleven Gases and Three Metals,

NBS Tech. Note 183 (Oct. 1963).

[33] Michels, A., and Prins, C., The melting fines of argon, kryp- ton and xenon up to 1500 atm; representation of the

results by a low of corresponding states, Physica 28,

No. 2, 101-116 (Feb. 1962).

[34] Lahr, P. H., and Eversole, W. G., Compression isotherms

of argon, krypton, and xenon through the freezing zone, Chem. Eng. Data 7, No. 1, 42-47 (Jan. 1962).

[35] Bridgman, P. W., The melting curves and compressibilities

of nitrogen and argon, Proc. Am. Acad. Arts Sci. 70, 1 (1935).

[36] Frank, A., and Clusius, K., Prazisionsmessungen der Ver- dampfungswarme Der Case 02 , H2 S, PH3 , A. COS, CH4 , and CHoD (Precision measurements of the heat of vapori- zation of gases oxygen, hydrogen sulphide, phosphene,

argon, carbon oxisulphide, methane and deuteromethane)

[37] Eucken, A., Uber das thermische verhalten einiger komprimierter und kondonsierter gase bei tiefen temperaturen (On the thermal behavior of a compressed and

condensed gas at low temperatures) Verhandl. Deut. Physik. Ges. 18, 4-27 (1916).

[38] Hirschfelder, J. O., Curtiss, C. F., and Bird, R. B., Molecular Theory of Gases and Liquids (John Wiley & Sons,

New York, 1954).

[39] Kerr, E. C., I. Second Virial Coefficient of Argon at Low

Temperature and Low Pressure., II. Heat Capacity of Liquid Nitric Oxide Above its Normal Boiling Point.,

University Microfilms (Ann Arbor, Mich.), Publ. No.

21480, Dissertation Abstracts 17, 1232(1957).

[40] Fender, B. E. F., and Halsey, G. D., Jr., Second virial coeffi- cients of argon, krypton, and argon-krypton mixtures at low temperatures, J. Chem. Phys. 36, 1881-1888 (1962). 30
[41] Holborn, L., and Otto, J., Uber die isothermen einiger gase zwischen 400 und —183 grad. (On the isotherms of various gases between 400 and — 183 degrees C.), Z. Physik 33, 1-11 (1925).

[42] Hanley, H. J. M., Comparison of the Lennard-Jones, Exp:

6 and Kihara potential functions using viscosity data of

dilute argon, J. Chem. Phys. 44, 4219 (1966).

[43] Private communication from M. Klein, National Bureau of Standards, Gaithersburg, Md. (1967).

[44] Hanley, H. J. M., and Klein, M., On the selection of the inter- molecular potential function: application of the statistical mechanical theory to experiment, NBS Tech. Note No. 360 (Nov. 1967). Hanley, H. J. M., and Klein, M. On the selection of the inter- molecular potential function: Part 2, from pair properties, Trans. Faraday Soc. (in press).

[45] Roebuck, J. R., and Osterberg, H., The Joule-Thomson

effect in argon, Phys. Rev. 46, 785-790 (1934).

[46] Roebuck, J. R., and Osterberg, H., The Joule-Thomson

effect in mixtures of helium and argon, J. Chem. Phys.

8, 627-635 (1940).

[47] Michels, A., Levelt, J. M., and Wolkers, G. J., Thermodynamic properties of argon at temperatures between

0 and — 140 degrees C and at densities up to 640 amagat

(pressures up to 1050 atmospheres.), Physica 24, 769-794

(1958).

[48] Michels, A., Lunbeck, R. J., and Wolkers, G. J., Thermodynamical properties of argon as function of density and

and temperature between 0 and 150 degrees C and

densities to 640 amagat, Physica 15, 689—695 (1949).

[49] Weir, R. D., Jones, I. W., Rowlinson, J. S., and Saville, G., Equation of state of gases at low temperatures. Part 1. Second virial coefficients of argon and krypton., Trans. Faraday Soc. 63, No. 534, 1320-1329 (1967).

[50] Holborn, L., and Otto, J., The isotherms of several gases up

to 400 degrees and their importance for the gas thermometer, Z. Phys. 23, 77-94 (1924).

[51] Holborn, L., and Otto., J., Isotherms for helium, nitrogen,

and argon below 0 degrees C, Z. Phys. 30, 320-328 (1924).

[52] Holborn, L., and Schultze, H., Uber die Druckwage und die Isothermen von Luft, Argon und Helium Zwischen

0 und 200 Degrees. (Concerning the pressure scale and

the isotherms of air, argon, and helium between 0 and

200 Degrees), Ann. Phys. 47, 1089-1111 (1915).

[53] van Itterbeek, A., and van Paemel, O., Measurements on

the velocity of sound in gaseous argon and deuterium re- spectively at liquid oxygen and hydrogen temperatures.

Calculation and discussion of the second virial coefficient of argon, Physica 5, 845-853 (1938).

[54] Voronel, A. V., Snigirev, V. G., and Chashkin, Yu. R., Behavior of the specific heat Cv of pure substances near

the critical point, Sov. Phys. JETP 21, No. 3, 653-655

(Sept. 1965); Trans, of Zh. Eksp. Teor. Fiz. 48 , 981—984

(Mar. 1965).

[55] Lestz, S. S., Acoustic isotherms for nitrogen, argon, and

krypton, J. Chem. Phys. 38, 2830-2834 (1963).

[56] Sengers, J. M. H. L., and Vicentini-Missoni, M., Thermodynamic Anomalies near the Gas-liquid Critical Point,

Proceedings of the Fourth Symposium on Thermophysical

Properties, pp. 79-86 (1968).

[57] Heller, P., Experimental investigations of critical phe- nomena, Repts. Progr. Phys. 30, Pt. 2, 731-826 (1967).

[58] Pings, C. J., and Teague, R. K., Experimental study of the shape of the coexistence curve of argon near the critical state, Phys. Letters 26A, No. 10, 496—497 (Apr. 1968).

[59] van Witzenburg, W., and Stryland, J. C., Density measure- ments of compressed solid and liquid argon, Can. J. Phys.

46, 811-816 (1968).

31

18. Appendix A

Table of Thermodynamic Properties

of Argon at Saturation

The number of significant figures given in the table is not

justified on the basis of the uncertainty of the data, but is presented to maintain internal consistency.

31b
18. APPENDIX A - Table of Thermodynamic Propertie s of Argon at Saturation

SATURATI ON DATA

TEMP. PRESSURE DENSITY enthalpy ENTROPY

K atm MOL/LITER j/mol J/MOL -K VAPOR LIQUID VAPOR LIQUID VAPOR LIQUID

TP 03,800 0.67979 0.101354 35.4126 9388.0 2814.2 131.21 52.77

04 • 0 0 0 0.69567 0-103520 35.3834 9391.2 2823.2 131.06 52.87

85.000 0.77945 0-114883 35*2363 9407.1 2868.7 130*33 53.41

86.000 0*87082 0-127166 35*0873 9422.7 2914.3 129.62 53*94

87.000 0*97024 0-140413 34.9366 9437.9 2960.2 128.92 54.47

88.000 1.07816 0 .154674 34.7841 9452.7 3006.3 128.24 54.99

89.000 1.16503 0,169995 34.6300 9467.1 3052.6 1 27.58 55.51

90.000 1.32133 0.186428 34.4742 9481.0 3099,2 126.93 56.02

9 1 .000 1 .45 ^ 54 0-204020 34.3169 9494.6 3145.9 126.30 56.54

92.000 1.60412 0-222826 34.1581 9507.7 3192.8 125.68 57.04

93.000 1 .76157 0-242895 33-9978 9520*3 3240-0 125.08 57.55

94.000 1.93037 0.264283 33-8360 9532.5 3287.3 124.49 58.05

95.000 2.11103 0.287044 33.6727 9544.2 3334.8 123.91 58.55

96.000 2.30404 0.311234 33.5080 9555.4 3382.5 123.34 59.04

97.000 2.50991 0.336911 33.3418 9566.1 3430.4 122.78 59.53

98.000 2.72914 0.364134 33.1741 9576.2 3478.5 122.24 60.02

99.000 2.96224 0,392964 33.0049 9585.8 3526,8 121 .70 60.50

100,000 3.20974 0,423464 32.8342 9594,9 3575.2 121.18 60.98

101.000 3.47213 0.455699 32.6620 9603.4 3623.8 120,66 61.45

102.000 3.74996 0.489735 32.4883 9611.3 3672.5 120.15 61.93

103.000 4.04373 0.525642 32.3129 9618.6 3721.5 IIP. 65 62.39

104.000 4.35397 0-563492 32-1359 9625.3 3770.6 v 119.15 62.86

105.000 4.68121 0-603360 31-9572 9631.4 3819.8 118.67 63.32

106.000 5 • 0?598 0-645324 31 -7768 9636.8 3869.2 118.19 63*78

107.000 5.38880 0-689465 31-5947 9641 -6 3918.8 117.72 64.23

108.000 5-77023 0-735870 31-4107 9645.6 3968.6 117.25 64.68

109.000 6.17079 0.784628 31-2247 9649.0 4018.5 116.79 65.13

110.000 6.59102 0.835832 31.0368 9651.7 4068.7 116.33 65,58

111.000 7.03147 0.889583 30.8469 9653.6 4119.0 115.88 66.02

112.000 7.49269 0.945986 30.6547 9654.7 4169.5 115.44 66.46

113*000 7.97523 1-00515 30 *4604 9655.1 4220*3 114.99 66. 9o

114.000 8.47964 1-06719 30-2637 9654.7 4271.2 114.55 67.33

115.000 9.00^50 1-13225 30-0645 9653.4 4322*4 114.12 67-76

116.000 9.55635 1.20044 29.8628 9651.2 4373.9 113.69 68.19

117.000 10-12979 1 -27 i 92 29-6584 9648.2 4425.7 113-26 68*62

118.000 10.72739 1.34685 29.4511 9644.2 4477.7 112.83 69.05

119.000 11.34972 1 .42538 29.2409 9639.3 4530.1 112.40 69.47

120.000 1 1.99740 1.50769 29.0274 9633.4 4582.8 111.98 66.89

121.000 12.67102 1.59399 28.8107 9626.4 4636 • 0 111.56 70.31

122.000 13.37120 1 .68449 28.5904 9618.3 4689.6 111.13 70.73

123.000 14.09855 1.77941 28 . 3b63 9609.1 4743.6 110.71 71.15

124,000 14.85371 1.87901 2b. 1382 9598.7 4798.2 110.29 71.57

125.000 15.63733 1.98357 27.9059 9587.1 4853.3 109.86 71.99

126.000 16.45007 2.09340 27.6690 9574.1 4909.1 109.44 72.41

127.000 17.29259 2.20884 27.4273 9559.8 4965.6 109.01 72.84

128.000 18.16559 2.33026 27.1803 9544,0 5022.8 108.58 73.26

129.000 19.06978 2.45809 26.9276 9526.6 5080.9 108.15 73.69

130.000 20.00*87 2.59280 2b . b689 9507,6 5139.9 107.71 74.11

131.000 20.97461 2.73495 26.4036 9406.8 5200.0 107.27 74.55

132.000 21.97677 2.83513 26.1312 9464.1 5261.2 106.82 74.98

133.000 23.01312 3,04406 25.8508 9439.4 5323.7 106.37 75.42

134.000 24,08448 3.21255 25.5619 9412.4 5387.7 105.91 75.87

135,000 25.19168 3.39153 25.2635 9383.1 5453.2 105.44 76.33

136.000 26.33558 3.58212 24.9546 9351.1 5520.1 104.95 76.79

137.000 27.51709 3.78563 24.6339 9316.2 5588.7 104.46 77.25

138.000 28.73712 4,0 0 3b5 24,3000 9278.0 5659.2 103.95 77.73

139.000 29.99663 4.23809 23.9510 9236.2 5731.7 103,43 78,21

140.000 31.29662 4.49134 23.5848 9190,4 5806.7 102.88 78.71

141,000 32.63813 4. ?6639 23.1987 9139.8 5884.5 102.31 79.22

142.000 34.02222 5.06709 22.7090 9083.8 5965.6 101.71 79.76

143.000 35*45004 5.39851 22-3511 9021.3 6050 • 8 101-08 80-31

144.000 36.92273 5 . 7 b 7 6 0 21-8787 3951.1 6141.0 100.41 80.89

145*000 38 *44154 6*18418 21-3629 8871.2 6237.7 99.68 81-51

146*000 40-00773 6*66296 20-7905 8778.9 6342.6 98.87 8?- 18 147.000 41.62265 7.22752 20.1401 8669.9 6459.0 97.97 82.93

14H.O00 43.28771 7.91978 19.3746 8536.7 6592.2 96.91 03.77

149.000 45.00437 8.82745 18.4161 8364.0 6753.8 95,61 84.80

150.000 46.77419 10.2023 17.0416 8109.1 6977.6 93.78 86.23

150.860 48.34000 13.4123 13.4123 7557.1 7557.1 90.02 90.02

32
19. Appendix B

Table of Thermodynamic Properties

of Argon at Selected Pressures

The number of significant figures given in the table is not

justified on the basis of the uncertainty of the data, but is presented to maintain internal consistency. The shaded parts of the

tables indicate areas of extrapolation of the equation of state.

32a

19. APPENDIX B - Table of Thermodynamic Properties of Argon at Selected Pressures

0.01 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 0.0014176 9477.7 8762.9 167.16

87 0*0014013 9498*5 8775*4 167*40

88 0.0013853 9519.3 8787.8 167.63

89 0.0013698 9540.1 8800.3 167.87

90 0.001354b 9560.8 8812.8 168.10

TEMP, DENSITY ENTHALPY INTERNAL entropy

K mol/liter J/MOL energy

J/MOL

J/MOL-K

91 0.0013396 9581.6 8825.3 168.33

92 0.0013251 9602.4 8837.7 168.56

93 0.0013108 9623.2 8850.2 168.78

94 0.0012968 9644.0 8862.7 169.01

95 0.0012832 9664.8 8875.2 169.23

96 0*0012698 9685*6 8887*6 169.44

97 0*0012567 9706.4 8900*1 169.66

98 0.0012439 9727.2 8912.6 169.87

99 0.0012313 9748.0 8925,1 170.08

100 0.0012190 9768,8 8937.5 170.29

101 0.0012069 9789.6 8950.0 170.50

102 0.0011951 9810.4 8962,5 170.70

103 0.0011835 9831.2 8975.0 170,91

104 0.0011721 9852.0 8987.4 171.11

105 0.0011609 9872.8 8999.9 171.31

106 0.0011499 9893.5 9012.4 171,50

107 0.0011392 9914.3 9024,9 171.70

108 0*0011286 9935*1 9037*3 171*89

109 0.0011183 9955.9 9049.8 172.08

no 0*0011081 9976.7 9062*3 172*27

111 0.0010981 9997.5 9074,8 172.46

112 0*0010883 10018.3 9087.2 172.65

113 0*0010787 10039.1 9099.7 172.83

114 0*0010692 10059*9 9112*2 173*02

115 0*0010599 10080*7 9124*7 173*20

116 0*0010508 10101*5 9137.1 173.38

117 0.0010418 10122.3 9149.6 173.56

118 0.0010330 10143,0 9162.1 173.73

119 0,0010243 10163.8 9174,6 173.91

120 0,0010157 10184,6 9187,0 174,08

121 0.0010073 10205.4 9199.5 174.26

122 0.0009991 10226.2 9212.0 174.43

123 0.0009909 10247.0 9224.5 174.60

124 0*0009830 10267.8 9236.9 174.76

125 0*0009751 10288.6 9249.4 174.93

126 0*0009673 10309.4 9261*9 175*10

127 0*0009597 10330*2 9274*4 175*26

128 0.0009522 10351.0 9286.8 175.42

129 0.0009448 10371.7 9299,3 175.59

130 0.0009376 10392.5 9311.8 175.75

131 0.0009304 10413.3 9324.3 175.91

132 0.0009234 10434.1 9336,7 176.06

133 0,0009164 10454.9 9349.2 176,22

134 0.0009096 10475,7 9361.7 176.38

135 0.0009028 10496.5 9374.2 176.53

136 0*0008962 10517.3 9386*6 176*69

137 0*0008897 10538.1 9399.1 176.84

138 0*0008832 10558*8 9411*6 176*99

139 0*0008769 10579*6 9424*1 177*14

140 0*0008706 10600*4 9436*5 177*29

141 0.0008644 10621,2 9449.0 177,44

142 0*0008583 10642*6 9461 •

5

177*58

143 0*0008523 10662.8 9473.9 177.73

144 0.0008464 10683.6 9486.4 177.87

145 0.0008406 10704.4 9498.9 178.02

1A6 0.0008348 10725.2 9511.4 178.16

147 0.0008291 10746.0 9523.8 178.30

148 0.0008235 10766.7 9536.3 178.44

149 0.0008180 10787.5 9548.8 178.58

150 0*0008125 10808*3 9561*3 178.72

151 0.0008072 10829.1 9573.7 178.86

152 0.0008018 10849.9 9586.2 179.00

153 0*0007966 10870*7 9598*7 179.13

154 0*0007914 10891.5 9611*2 179.27

155 0*0007863 10912*3 9623*6 179.40

156 0*0007813 10933.0 9636.1 179.54

157 0*0007763 10953*8 9648*6 179*67

158 0.0007714 10974.6 9661.0 179.80

159 0.0007665 10995.4 9673.5 179.93

160 0.0007617 11016.2 9686.0 180.06

33
164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

1 86

187

188

189

190

191

192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

0.01 ATMOSPHERE ISOBAR

DEN'S I TY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

mol/liteR J/MOL energy J/MOL-K K mol/liter J/MOL ENERGY J/MOL-K

J/MOL J/MOL

0.0007570 11037.0 9698.5 180.19 231 0.0005276 12492.1 10571.5 187.70

0.0007523 11057.8 9710.9 180.32 232 0.0005253 12512.9 10584.0 187.79

0.0007477 11078.6 9723.4 180.45 233 0,0005231 12533.7 10596.5 187.88

0.0007432 11099.4 9735.9 180.58 234 0.0005208 12554.5 10608,9 187.97

0,0007387 11120.1 9748.4 180.70 235 0.0005186 12575.2 10621.4 188.05

0.0007342 11140.9 9760.8 180.83 236 0.0005164 12596.0 10633.9 188.14

0.0007298 11161.7 9773.3 180.95 237 0.0005142 12616.8 10646.4 188.23

0.0007255 11182.5 9785.8 181.08 238 0.0005121 12637.6 10658.8 188.32

0.0007212 11203.3 9798.2 181.20 239 0.0005099 12658.4 10671.3 188.41

0.0007169 11224.1 9810.7 181.32 240 0.0005078 12679.2 10683.8 188.49

0.0007127 11244.9 9823.2 181.45 241 0.0005057 12700.6 10696.2 188.58

0.0007086 11265.7 9835.7 181.57 242 0.0005036 12720.8 10708.7 188.66

0.000704$ 11286.4 9848.1 181.69 243 0.0005015 12741.5 10721.2 188.75

0.0007004 11307.2 9860*6 181*81 244 0.0004995 12762*3 10733*7 188.84

0.0006964 11328.0 9873.1 181.93 245 0,0004974 12783.1 10746.1 188.92

0.0006925 11348.8 9885.6 182.05 246 Of 0004954 12803.9 10758.6 189.01

0 • 0006886 11369*6 9898*0 182*16 247 0*0004934 12824.7 10771*1 189.09

0*0006847 11390*4 9910*5 182.28 24B 0*0004914 12845.5 10783*6 189.17

0*0006809 11411*2 9923*0 182*40 249 0*0004895 12866*3 10796*0 189*26

0*0006771 11432*0 9935*4 182*51 250 0*0004875 12887*0 10808.5 189.34

0.0006734 11452.7 9947.9 182.63 251 0.0004856 12907.8 10821.0 189.42

0.0006697 11473.5 9960*4 182.74 252 0*0004836 12928.6 10833*4 189.51

0*0006660 11494*3 9972*9 182*86 253 0*0004817 12949.4 10845*9 189.59

0*0006624 11515*1 9985*3 182*97 254 0*0004798 12970*2 10858*4 189.67

0.0006588 11535.9 9997.8 183.08 255 0.0004779 12991.0 10870.9 189.75

0.0006552 11556.7 10010.3 183.19 256 0.0004761 13011.8 10883.3 189,83

0,0006517 11577.5 10022.8 183.31 257 0.0004742 13032.5 10895.8 189.91

0.0006483 11598.3 10035.2 183.42 258 0.0004724 13053.3 10908,3 190,00

0.0006448 11619.0 10047.7 183.53 259 0,0004706 13074,1 10920.7 190.08

0.0006415 11639.8 10060.2 183.64 260 0.0004687 13094.9 10933.2 190.16

0.0006381 11660.6 10072.6 183.75 261 0.0004669 13115.7 10945.7 190.24

0.0006348 11681.4 10085.1 183.85 262 0.0004652 13136.5 10958.2 190.32

0.0006315 11702*2 10097.6 183.96 263 0*0004634 13157.3 10970.6 190.39

0.0006282 11723.0 10110.1 184.07 264 0.0004616 13178.1 10983.1 190.47

0.0006250 11743.8 10122.5 184.18 265 0*0004599 13198.8 10995.6 190.55

0*0006218 11764.6 10135*0 184.28 266 0*0004582 13219.6 11008.0 190.63

0*0006187 11785.3 10147.5 184.39 267 0*0004565 13240*4 11020*5 190.71

0*0006155 11806.1 10159.9 184.49 268 0.0004547 13261.2 11033.0 190.79

0*0006124 11826*9 10172.4. 184*60 269 0*0004531 13282.0 11045*5 190*86

0*0006094 11847*7 10184*9 184*70 270 0*0004514 13302*8 11057*9 190*94

0.0006063 11868.5 10197.4 184.81 271 0.0004497 13323.6 11070.4 191.02

0*0006033 11889.3 10209.8 184.91 272 0 *0004481 13344.3 11082.9 191*09

0 .0006004 11910*1 10222.3 185.01 273 0*0004464 13365.1 11095.3 191.17

0.0005974 11930.9 10234.8 185.11 274 0.0004448 13385.9 11107.8 191.25

0.0005945 11951.6 10247.3 185.22 275 0.0004432 13406.7 11120.3 191.32

0.0005916 11972.4 10259.7 185.32 276 0.0004416 13427.5 11132.8 191.40

0.0005888 11993.2 10272.2 185.42 277 0.0004400 13448.3 11145.2 191 .47

0.0005859 12014.0 10284.7 185.52 270 0.0004384 13469.1 11157.7 191.55

0.0005831 12034.8 10297.1 185.62 279 0.0004368 13489.8 11170.2 191.62

0.0005804 12055.6 10309.6 185.72 280 0.0004353 13510.6 11182.7 191.70

0.0005776 12076.4 10322.1 185.82 281 0.0004337 13531.4 11195.1 191.77

0.0005749 12097.1 10334.6 185.91 282 0.0004322 13552.2 11207.6 191.84

0.0005722 12117.9 10347.0 186.01 283 0.0004306 13573.0 11220*1 191.92

0.0005695 12138.7 10359.5 186.11 284 0.0004291 13593.8 11232.5 191.99

0*0005669 12159.5 10372*0 186*21 285 0*0004276 13614.6 11245.0 192*06

0*0005642 12180*3 10384.4 186.30 286 0*0004261 13635.4 11257.5 192*14

0*0005616 12201*1 10396.9 186.40 287 0*0004246 13656.

i

11270*0 192.21

0.0005591 12221.9 10409.4 186.49 288 0.0004232 13676.9 11282*4 192.28

0*0005565 12242.7 10421.9 186*59 289 0.0004217 13697.7 11294.9 192.35

0*0005540 12263.4 10434.3 1 86 • 68 290 0*0004203 13718.5 11307.4 192.43

0 .0005515 12284.2 10446,8 186.78 29

1

0.0004188 13739.3 11319.8 192.50

0.0005490 12305.0 10459.3 186.87 292 0.0004174 13760.1 11332.3 192.57

0 .000546$ 12325.8 10471.8 186.97 293 0.0004159 13780.9 11344.8 192.64

0.0005441 12346.6 10484.2 187.06 294 0.0004145 13801.6 11357.3 192.71

0.0005417 12367.4 10496.7 187.15 295 0.0004131 13822.4 11369.7 192.78

0.0005393 12388.2 10509.2 187.24 296 0.0004117 13843.2 11382.2 192.85

0.0005369 12409.0 10521 .6 187.33 297 0.0004103 13864.0 11394.7 192.92

0.0005345 12429.7 10534.1 187.43 298 0.0004090 13884.8 11407.1 192.99

0.0005322 12450.5 10546.6 187.52 299 0.0004076 13905.6 11419.6 193.06

0.0005299 12471.3 10559.1 187.61 300 0.0004062 13926.4 11432.1 193.13

34
0.02 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 0*0028361 9477.1 8762.5 161.39

87 0.0028034 9497.9 8775.0 161.63

88 0,0027715 9518.7 8787.5 161.87

89 0,0027403 9539.5 8799.9 162.10

90 0,0027098 9560.3 8812.4 162.33

TEMP. DENSITY ENTHALPY internal ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 0.0026800 9581.1 8824.9 162.56

92 0.0026508 9601,9 8837,4 162.79

93 0.0026223 9622.7 8849.9 163.02

94 0.0025944 9643.5 8862.3 163.24

95 0.0025670 9664.3 8874.8 163.46

96 0.0025402 9685.1 8887.3 163.68

97 0. 0025140 9705,9 8899.8 163.89

98 0.0024883 9726.7 8912.3 164.11

99 0.0024632 9747*5 8924.7 164.32

100 0*0024385 9768*3 8937*2 164.53

101 0.0024143 9789.1 8949.7 164.73

102 0.0023906 9809.9 8962.2 164.94

103 0*0023674 9830.7 8974*7 165.14

104 0*0023446 9851*5 8987*1 165*34

105 0*0023223 9872*3 8999*6 165*54

106 0*0023003 9893.1 9012.1 165.74

107 0.0022788 9913.9 9024.6 165.93

108 0.0022577 9934.7 9037.1 166.13

109 0*0022370 9955.5 9049.5 166.32

110 0.0022166 9976.3 9062.0 166.51

111 0.0021966 9997.1 9074.5 166.70

112 0.0021770 10017.9 9087*0 166.88

113 0,0021577 10038.7 9099.5 167.07

114 0.0021388 10059.5 9111,9 167.25

115 0*0021201 10080.

3

9124.4 167.43

116 0*0021018 10101*1 9136*9 167.61

117 0*0020839 10121.9 9149*4 167.79

118 0.0020662 10142.7 9161,8 167.97

119 0.0020488 10163.5 9174.3 168.14

120 0.0020317 10184.3 9186.8 168.32

121 0.0020149 10205.1 9199.3 168,49

122 0.0019984 1 0225 .

8

9211.8 168.66

123 0*0019821 10246*6 9224*2 168*83

124 0*0019661 10267*4 9236*7 169*00

125 0*0019504 10288*2 9249*2 169*17

126 0.0019349 10309.0 9261.7 169.33

127 0.0019197 10329.8 9274.1 169.50

128 0.0019047 10350.6 9286.6 169.66

129 0.0018899 10371.4 9299.1 169.82

130 0*0018753 10392.2 9311.6 169.98

131 0.0018610 10413.6 9324.1 170.14

132 0.0018469 10433.8 9336.5 170.30

133 0.0018330 10454.6 9349*0 170.46

134 0.0018193 10475.4 9361*5 170.61

135 0.0018058 10496.2 9374.0 170.77

136 0.0017926 10517.0 9386.4 170.92

137 0.0017795 10537.8 9398*9 171*07

138 0.0017666 10558.6 9411.4 171.22

139 0.0017539 10579.3 9423.9 171.37

140 0.0017413 10600.1 9436.3 171.52

141 0.0017290 10620.9 9448.8 171.67

142 0*0017168 10641*7 9461*3 171*82

143 0*0017048 10662*5 9473*8 171*96

144 0.0016929 10683.3 9486.2 172.11

145 0.0016812 10704.1 9498.7 172.25

146 0.0016697 10724.9 9511.2 172.40

147 0.0016584 10745.7 9523.7 172.54

148 0.0016472 10766.5 9536.1 172.68

149 0.0016361 10787*3 9548*6 172*82

150 0*0016252 10808*1 9561*1 172.96

151 0.0016144 10828.9 9573.6 173.10

152 0.0016038 10849.6 9586.0 173.23

153 0.0015933 10870*4 9598.5 173.37

154 0*0015830 10891.2 9611.0 173*51

155 0*0015727 10912*0 9623.5 173.64

156 0*0015627 10932*8 9635.9 173.77

157 0*0015527 10953.6 9648.4 173.91

158 0.0015429 10974.4 9660.9 174.04

159 0.0015332 10995.2 9673.4 174.17

160 0.0015236 11016.0 9685.8 174.30

35
0.02 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY INTERNAL entropy TEMP, DENSITY enthalpy internal entropy

K mol/liter J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL energy

J/MOL

j/mol-k

161 0.0015141 11036.8 9698.3 174.43 231 0.0010552 12492.0 10571.4 181.93

162 0.0015048 11057.6 9710.8 174.56 232 0.0010507 12512.8 10583.9 182.02

163 0.0014955 11078.3 9723.3 174.69 233 0.0010461 12533.6 10596.4 182.11

164 0.0014864 11099.1 973S-.7 174.81 234 0.0010417 12554.3 10608.9 182.20

165 0.0014774 11119,9 9748.2 174.94 235 0.0010372 12575.1 10621.3 182.29

166 0.0014685 11140.7 9760.7 175.07 236 0,0010328 12595.9 10633.8 182,38

167 0.0014597 11161.5 9773.2 175. 19 237 0.0010285 12616.7 10646.3 182.47

166 0.0014510 11182.3 9785.6 175.31 238 0.0010242 12637.5 10658.8 182.55

169 0.0014424 11203.1 9798.1 175.44 239 0.0010199 12658.3 10671.2 182.64

170 0.0014339 11223.9 9810.6 175.56 240 0.0010156 12679.1 10683.7 182.73

171 0.0014255 11244.7 9823.1 175.68 241 0.0010114 12699.9 10696.2 182.82

172 0.0014172 11265,5 9835.5 175.80 242 0.0010072 12720.6 10708.6 182.90

173 0.0014090 11286.2 9848.0 175.92 243 0.0010031 12741.4 10721.1 182.99

1 74 0.0014009 11307.0 9860.5 176.04 244 0.0009990 12762.2 10733.6 183.07

175 0.0013929 11327.8 9872.9 176.16 245 0,0009949 12783.0 10746.1 183.16

176 0,0013850 11348.6 9885.4 176.28 246 0.0009909 12803.8 10758.5 183.24

1 77 0.0013772 11369.4 9897.9 176.40 247 0.0009868 12824,6 10771.0 183.33

178 0.0013695 11390.2 9910.4 176.52 248 0.0009829 12845.4 10783.5 183.41

179 0.0013618 11411.0 9922.8 176.63 249 0.0009789 12866.2 10795.9 183.49

180 0.0013542 11431,8 9935.3 176*75 250 0.0009750 12886.9 10808*4 183.58

181 0.0013468 11452.6 9947,8 176.86 251 0.0009711 12907.7 10820.9 183.66

182 0.0013394 11473.4 9960.3 176.98 252 0.0009673 12928.5 10833.4 183.74

183 0.0013320 11494.1 9972*7 177*09 253 0*0009634 12949*3 10845*8 183*83

184 0*0013248 11514*9 9985*2 177*21 254 0*0009596 12970*1 10858*3 183*91

185 0.0013176 11535*7 9997.7 177*32 255 0*0009559 12990*9 10870*8 183.99

186 0.0013105 11556*5 10010*2 177*43 256 0*0009521 13011*7 10883*3 184*07

187 0.0013035 11577.3 10022.6 177.54 257 0.0009484 13032.5 10895.7 184.15

188 0.0012968 11598.1 10035.1 177.65 258 0.0009448 13053,2 10908.2 184.23

189 0,0012897 11618.9 10047.6 177.76 259 0.0009411 1307^.0 10920.7 184.31

190 0.0012829 11639.7 10060.1 177.87 260 0,0009375 13094.8 IO 933 .I 184.39

191 0,0012762 11660.5 10072.5 177.98 261 0.0009339 13115.6 10945.6 184.47

192 0.0012696 11681.2 10085.0 178.09 262 0*0009303 13136.4 10958.1 184.55

193 0.0012630 11702.0 10097.5 178.20 263 0.0009268 13157.2 10970.6 184.63

194 0.0012565 11722.8 10109.9 178.31 264 0,0009233 13178.0 10983.0 184.71

195 0.0012500 11743.6 10122.4 178.41 265 0,0009198 13198.7 10995.5 184.79

196 0.0012437 11764.4 10134.9 178.52 266 0.0009163 13219.5 11008.0 184.87

197 0.0012374 11785.2 10147.4 178.62 267 0,0009129 13240.3 11020.4 184,94

198 0.0012311 11606.0 10159.8 178.73 268 0.0009095 13261.1 11032.9 185.02

199 0.0012249 11826.8 10172.3 178.83 269 0*0009061 13281.9 11045.4 185.10

200 0.0012188 11847.6 10184.8 178.94 270 0*0009028 13302.7 11057.9 185.18

201 0.0012127 11868.3 10197.3 179.04 271 0.0008994 13323.5 11070.3 185.25

202 0,0012067 11889.1 10209.7 179.15 272 0.0008961 13344.3 11082.8 185.33

203 0*0012008 11909.9 10222.2 179.25 273 0.0008928 13365.0 11095.3 185.41

204 0.0011949 11930.7 10234.7 179.35 274 0,0008896 13385.8 11107.8 185.48

205 0*0011891 11951.5 10247.2 179*45 275 0*0008864 13406.6 11120*2 185*56

206 0*0011833 11972*3 10259*6 179*55 276 0*0008831 13427*4 11132*7 185*63

207 0*0011776 11993*1 10272*1 179*65 277 0*0008800 13448*2 11145*2 185*71

208 0*0011719 12013*9 10284*6 179*75 278 0*0008768 13469*0 11157*6 185*78

209 0*0011663 12034*6 10297*0 179*85 279 0*0008736 13489*8 11170*1 185*86

210 0*0011607 12055*4 10309*5 179*95 280 0*0008705 13510*6 11182*6 185*93

211 0.0011552 12076.2 10322.0 180.05 281 0.0008674 13531.3 11195.1 186.01

212 0.0011498 12097.0 10334.5 180.15 282 0.0008644 13552.1 11207.5 186.08

213 0.0011444 12117.8 10346.9 180,25 283 0.0008613 13572.9 11220.0 186.15

214 0.0011390 12138.6 10359.4 180.35 284 0.0008583 13593.7 11232.5 186.23

215 0.0011337 12159.4 10371.9 180.44 285 0.0008553 13614.5 11244.9 186.30

216 0.0011285 12180.2 10384.4 180.54 286 0.0008523 13635.3 11257.4 186.37

217 0.0011233 12200.9 10396.8 180.63 287 0,0008493 13656.1 11269.9 186.45

218 0.00U181 12221.7 10409,3 180.73 288 0.0008463 13676.8 11282.4 186.52

219 0.0011130 12242.5 10421.8 180.83 289 0.0008434 13697,6 11294.8 186.59

220 0.0011080 12263.3 10434.2 180.92 290 0.0008405 13718.4 11307.3 186.66

221 0.00H030 12284.1 10446.7 181.01 291 0.0008376 13739.2 11319.8 186.73

222 0.0010980 12304.9 10459.2 181.11 292 0.0008347 13760.0 11332.3 186.81

223 0.0010931 12325.7 10471.7 181.20 293 0.0008319 13780.8 11344.7 186.88

224 0.0010882 12346.5 10484,1 181.29 294 0.0008291 13801.6 11357.2 186.95

225 0.00l0a33 12367.3 10496.6 181.39 295 0.0008263 13822.4 11369.7 187.02

226 0.0010786 12388.0 10509.1 181 .48 296 0.0008235 13843.1 11382.1 187.09

227 0.0010738 12408.8 10521.6 181.57 297 0.0008207 13863,9 11394.6 187.16

228 0.0010691 12429.6 10534.0 181.66 298 0,0008179 13884.7 II 4 O 7 .I 187.23

229 0.0010644 12450,4 10546.5 181.75 299 0.0008152 13905.5 11419.6 187.30

230 0,0010598 12471.2 10559.0 lei .84 300 0.0008125 13926.3 11432.0 187,37

36
o.o4 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 0.0056759 9475.8 8761,7 155

87 0,0056105 9496.6 8774.2 155

88 0.0055465 9517.5 8786.7 156

89 0,0054840 9538.3 8799.2 156

90 0,0054228 9559.1 8811.7 156

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

91 0 0053631 9579.9 8824 2 156 79

92 0 0053046 9600.8 8836 7 157 02

93 0 0052474 9621.6 8849 2 157 25

94 0 0051914 9642.4 8861 7 157 47 95 0 0051366 9663.2 8874 1 157 69

96 0 0050830 9684.0 8886 6 157 91 97 0 0050304 9704.8 8899 1 158 12 98 0 0049790 9725.7 8911 6 158 34

99 0 0049286 9746.5 8924 1 158 55

100 0 0048792 9767.3 8936 6 158 76

101 0 0048307 9788.1 8949 1 158 96

102 0 0047833 9808.9 8961 6 159 17 103 0 0047367 9829.7 8974 1 159 37

104 0 0046911 9850.6 8986 5 159 57

105 0 0046463 9871.4 8999 0 159 77

106 0 0046024 9892.2 9011 5 159 97

107 0 0045593 9913.6 9024 0 160 16 108 0 0045170 9933.8 9036 5 160 36

1 09 0 0044755 9954.6 9049 0 160 55

110 0 0044347 9975.4 9061 5 160 74

111 0 0043947 9996.2 9074 0 160 93

112 0 0043554 10017.0 9086 4 161 12 113 0 0043167 10037.9 9098 9 161 30

114 0 0042788 10058*7 9111 4 161 48

115 0 0042415 10079.5 9123 9 161 67

116 0 0042049 10100*3 9136 4 161 85

117 0 0041689 10121.1 9148 9 162 02

118 0 0041335 10141*9 9161 4 162 20

119 0 0040988 10162*7 9173 8 162 38

120 0 0040645 10183.5 9186 3 162 55

121 0 0040309 10204.3 9198 8 162 72

122 0 0039978 10225.1 9211 3 162 89

123 0 0039653 10245.9 9223 8 163 06

124 0 0039332 10266*7 9236 3 163 23

125 0 0039017 10287.5 9248 7 163 40

126 0 0038707 10308*3 9261 2 163 57

127 0 0038402 10329*1 9273 7 163 73

128 0 0038102 10349*9 9286 2 163 89

129 0 0037806 10370*8 9298 7 164 06

130 0 0037515 10391 *6 9311 2 164 22

131 0 0037228 10412.4 9323 6 164 38

132 0 0036946 10433.2 9336 1 164 53

133 0 0036668 10454.0 9348 6 164 69

134 0 0036394 10474.8 9361 1 164 85

135 0 0036124 10495.6 9373 6 165 00

1 36 0 0035858 10516.4 9386 0 165 15 137 0 0035596 10537.2 9398 5 165 31 138 0 0035338 10558.0 9411 0 165 46

139 0 0035083 10578.8 9423 5 165 61 140 0 0034832 10599.6 9436 0 165 76

141 0 0034585 10620.4 9448 4 165 91 142 0 0034341 10641.2 9460 9 166 05

143 0 0034101 10662.0 9473 4 166 20

144 0 0033864 10682*8 9485 9 166 34

145 0 0033630 10703*6 9498 4 166 49

146 0 0033400 10724.4 9510 8 166 63

147 0 0033172 10745.2 9523 3 166 77 148 0 0032948 10766*0 9535 8 166 91 149 0 0032727 10786.8 9548 3 167 05

150 0 0032508 10807*6 9560 8 167 19

151 0 0032293 10828.3 9573 2 167 33

152 0 0032080 10849.1 9585 7 167 47

153 0 0031870 10869.9 9598 2 167 60

154 0 0031663 10890.7 9610 7 167 74 155 0 0031459 10911.5 9623 1 167 87 156 0 0031257 10932.3 9635 6 168 01 157 0 0031058 10953.1 9648 1 1 68 14 158 0 0030861 10973.9 9660 6 168 27

159 0 0030667 10994,7 9673 1 168 40

160 0 0030475 11015.5 9685 5 168 53

37
K

161 162

1 63

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

0.04 atmosphere ISOBAR

DENSITY

mol/liter

ENTHALPY

J/MOL

INTERNAL ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K density

MOL/L ITER ENTHALPY

J/MOL

INTERNAL energy

J/MOL

entropy

J/MOl-K

0.0030286 11036.3 9698.0 168.66 231 0.0021105 12491.7 10571.3 176.17

0 .0030098 11057.1 9710.5 168.79 232 0.0021014 12512.5 10583.7 176.26

0.0029914 11077.9 9723.0 168.92 233 0.0020924 12533.3 10596.2 176.35

0.0029731 11098.7 9735.4 169.05 234 0.0020834 12554.1 10608.7 176.44

0.0029551 11119.5 9747.9 169.17 235 0.0020745 12574.9 10621.2 176.53

0.0029373 11140*3 9760*4 169*30 236 0*0020658 12595*7 10633*6 176*62

0.0029197 11161*1 9772*9 169*43 237 0*0020570 12616*5 10646*1 176*70

0.0029023 11181*9 9785*3 169*55 238 0*0020484 12637*3 10658*6 176*79

0*0028851 11202*7 9797*8 169*67 239 0*0020398 12658*1 10671*1 176*88

0 . 002868

1

11223.5 9810.3 169.80 240 0.0020313 12678.8 10683.5 176.97

0.0028513 11244.3 9822.8 169.92 241 0.0020229 12699.6 10696.0 177.05

0.0028347 11265.1 9835.3 170.04 24? 0.0020145 12720.4 10708.5 177.14

0.0028184 11285.8 9847.7 170*16 243 0.0020062 12741.2 10721.0 177.22

0*0028021 11306*6 9860*2 170*28 244 0*0019980 12762*0 10733*4 177*31

0*0027861 11327*4 9872*7 170**0 245 0*0019899 12782*8 10745*9 177*39

0*0027703 11348*2 9885*2 170*52 246 0*0019818 12803*6 10758*4 177*48

0 *0027546 11369*0 9897*6 170*63 247 0*0019737 12824*4 10770*8 177*56

0,0027391 11389.8 9910.1 170.75 248 0.0019658 12845.2 10783.3 177.65

0,0027238 11410.6 9922.6 170.87 249 0.0019579 12865.9 10795.8 177.73

0.0027087 11431.4 9935.1 170.98 250 0.0019501 12886.7 10808.3 177.81

0.0026937 11452.2 9947.5 171.10 251 0.0019423 12907.5 10820.7 177.90

0*0026789 11473*0 9960*0 171*21 252 0*0019346 12928*3 10833*2 177*98

0.0026643 11493.8 9972.5 171.33 253 0.0019269 12949.1 10845.7 178.06

0.0026498 11514.6 9985.0 171 .44 254 0.0019193 12969.9 10858.2 178.14

0.0026355 11535.4 9997.4 171.55 255 0.0019118 12990.7 10870.6 178,23

0.0026213 11556.2 100O9.9 171.67 256 0.0019043 13011.5 10883.1 178.31

0.0026073 11576.9 10022.4 171.78 257 0.0018969 13032,3 10895.6 178.39

0.0025934 11597.7 10034.9 171.89 258 0.0018896 13053.0 10908.1 178.47

0.0025797 11618.5 10047.3 172.00 259 0*0018823 13073*8 10920.5 178.55

0*0025661 11639*3 10059*8 172*11 260 0*0018750 13094.6 10933*0 178*63

0.0025526 11660.1 10072.3 172.22 261 0.0018678 13115.4 10945.5 178.71

0.0025393 11680*9 10084.8 172*33 262 0*0018607 13136.2 10957*9 178.79

0*0025262 11701*7 10097*2 172* *3 263 0*0018536 13157*0 10970*4 178*87

0.0025131 11722.5 10109,7 172.54 264 0.0018466 13177.8 10982.9 178.95

0.0025002 11743.3 10122.2 172.65 265 0.0018397 13198.6 10995.4 179.03

0.0024875 11764.1 10134.7 172.75 266 0.0018327 13219.3 11007.8 179.10

0.0024749 11784.9 10147.1 172.86 267 0.0018259 13240.1 11020.3 179.18

0.0024623 11805.7 10159.6 172.97 268 0.0018191 13260.9 11032.8 179.26

0.0024500 11826.4 10172.1 173.07 269 0.0018123 13281.7 11045.3 179.34

0.0024377 11847.2 10184.6 173.17 270 0.0018056 13302.5 11057.7 179.41

0.0024256 11868.0 10197.0 173.28 271 0.0017989 13323.3 11070.2 179.49

0.0O24136 11888.8 10209.5 173.38 272 0.0017923 13344.1 11082.7 179.57

0.0024017 11909.6 10222*0 173.48 273 0*0017857 13364.9 11095*1 179.64

0*0023899 11930*4 10234*5 173*59 274 0*0017792 13385*7 11107*6 179.72

0*0023782 11951*2 10246.9 173*69 275 0*0017727 13406.4 11120*1 179.80

0 . 0023b67 11972.0 10259.4 173.79 276 0.0017663 13427.2 11132.6 179.87

0.0023553 11992.8 10271.9 173.89 277 0.0017599 13448.0 11145.0 179.95

0.0023439 12013.6 10284,4 173.99 278 0.0017536 13468.8 11157.5 180 .02

0.0023327 12034.4 10296.8 174.09 279 0.0017473 13489.6 11170.0 180.10

0.0023216 12055.1 10309.3 174.19 2«0 0.0017411 13510.4 11182.5 180.17

0.0023106 12075.9 10321.8 174.29 281 0.0017349 13531.2 11194.9 180.24

0.0022997 12096.7 10334.3 174.39 282 0.0017287 13552.0 11207.4 180.32

0.0022889 12117*5 10346.7 174.48 283 0*0017226 13572*7 1 1219*9 180*39

0.0022782 12138*3 10359*2 174*58 284 0*0017166 13593*5 11232*3 180*46

0.0022676 12159.1 10371.7 174.68 285 0.0017105 13614.3 11244.8 180.54

0.0022571 12179.9 10384.2 174,77 286 0.0017046 13635.1 11257.3 180.61

0.0022467 12200.7 10396.6 17*. 87 287 0,0016986 13655.9 11269.8 180.68

0.0022364 12221.5 10409.1 174.97 288 0.0016927 13676.7 11282.2 180.76

0.0022262 12242.3 10421.6 175.06 289 0.0016869 13697.5 11294.7 180.83

0.0022160 12263.1 10434.1 175.16 290 0.0016810 13718.3 11307,2 180.90

0.0022060 12283.8 10446.5 175.25 291 0.0016753 13739.0 11319.7 180.97

0.0031961 12304.6 10459.0 175.34 292 0.0016695 13759.8 11332.1 181.04

0.0021862 12325*4 10471.5 175.44 293 0*0016638 13780.6 11344.6 181.11

0*0021765 12346*2 10484*0 175*53 294 0*0016582 13801*4 11357.1 181*18

0.0021668 12367.0 10496.4 175.62 295 0.0016525 13822.2 11369.5 181 .25

0.0021572 12337.8 105C8.9 175.72 296 0.0016470 13843.0 11382.0 181.32

0.0021477 12408.6 10521.4 175.81 297 0.0016414 13863.8 11394.5 1 R 1 .40

0.0021383 12429.4 10533.8 175.90 298 0.0016359 13884.6 11407.0 181.46

0.0021289 12450.2 10546.3 175.99 299 0.0016304 13905.4 11419.4 181.53

0.0021197 12470*9 10558.8 176.08 300 0*0016250 13926.1 11431.9 181.60

38
0.06 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY

K MOL/LITER J/MOL

INTERNAL ENTROPY

ENERGY J/MOL-K

J/MOL

86 0.0085195 9474.6 8761.0 152

87 0.0084211 9495.4 8773.5 152

88 0.0083249 9516.3 8786.0 152

89 0*0082309 9537*1 8798.5 152

90 0.0081390 9557.9 8811.0 153

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

J/MOL-K

91 0 0080492 9578 8 8823 5 153 41 92 0 0079613 9599 6 8836 0 153 64

93 0 0078753 9620 5 8848 5 153 87

94 0 0077912 9641 3 8861 0 154 09

95 0 0077088 9662 1 8873 5 154 31 96 0 0076282 9683 0 8886 0 154 53

97 0 0075493 9703 8 8898 5 154 74

98 0 0074719 9724 6 8911 0 154 96

99 0 0073962 9745 5 8923 5 155 17 100 0 0073220 9766 3 8936 0 155 38

101 0 0072492 9787 1 8948 5 155 59

102 0 0071779 9808 0 8961 0 155 79

103 0 0071080 9828 8 8973 5 155 99

104 0 0070394 9849 6 8986 0 156 20

105 0 0069721 9870 4 8998 4 156 40

106 0 0069062 9891 3 9010 9 156 59

107 0 0068414 9912 1 9023 4 156 79

108 0 0067779 9932 9 9035 9 156 98

109 0 0067155 9953 7 9048 4 157 17 110 0 0066543 9974 6 9060 9 157 36

111 0 0065942 9995 4 9073 4 157 55

112 0 0065351 10016 2 9085 9 157 74

113 0 0064772 10037 0 9098 4 157 92

114 0 0064202 10057 9 9110 9 158 11 115 0 0063642 10078 7 9123 4 158 29

116 0 0063092 10099 5 9135 9 158 47

117 0 0062552 10120 3 9148 4 158 65

118 0 0062020 10141 1 9160 9 158 83

119 0 0061498 10161 9 9173 4 159 00 120 0 0060984 10182 8 9185 8 159 18

121 0 0060479 10203 6 9198 3 159 35

122 0 0059982 10224 4 9210 8 159 52

123 0 0059494 10245 2 9223 3 159 69

124 0 0059013 10266 0 9235 8 159 86

125 0 0058540 10286 8 9248 3 160 03

126 0 0058074 10307 7 9260 8 160 19 127 0 0057616 10328 5 9273 3 160 36

128 0 0057165 10349 3 9285 8 160 52

129 0 0056721 10370 1 9298 2 160 68

130 0 0056284 10390 9 9310 7 160 84

131 0 0055854 10411 7 9323 2 161 00 132 0 0055430 10432 5 9335 7 161 36 133 0 0055012 10453 3 9348 2 161 32

134 0 0054601 10474 1 9360 7 161 47 135 0 0054196 10495 0 9373 2 161 63

136 0 0053797 10515 8 9385 6 161 78

137 0 0053404 10536 6 9398 1 1 6

1

93

138 0 0053016 10557 4 9410 6 162 08 139 0 0052634 10578 2 9423 1 162 23

140 0 0052257 10599 0 9435 6 162 38

141 0 0051886 10619 8 9448 1 162 53

142 0 0051520 10640 6 9460 6 162 68

143 0 0051160 10661 4 9473 0 162 82

144 0 0050804 10682 2 9485 5 162 97

145 0 0050453 10703 0 9498 0 163 11 146 0 0050107 10723 8 9510 5 163 26

147 0 0049766 10744 6 9523 0 163 40 148 0 0049429 10765 4 9535 4 163 54

149 0 0049097 10786 2 9547 9 163 68

150 0 0048769 10807 0 9560 4 163 82

151 0 0048446 10827 8 9572 9 163 96

152 0 0049127 10848 6 9585 4 164 09

153 0 0047812 10869 4 9597 9 164 23

154 0 0047501 10890 2 9610 3 164 37 155 0 0047194 10911 1 9622 8 164 50

156 0 0046891 10931 9 9635 3 164 64

157 0 0046592 10952 7 9647 8 164 77 158 0 0046297 10973 5 9660 3 164 90

159 0 0046005 10994 3 9672 7 165 03 160 0 0045718 11015 1 9685 2 165 16

316-977 0 - 69-4

39
161

162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

1 86

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

2 ] 8 219

220

221

222

223

224

225

226

227

228

229

230

0.06 atmosphere ISOBAR

density

MOL/LITER

ENTHALPY

J/MOL INTERNAL ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

0.0045433 11035.9 9697.7 165.29 231 0.0031658 12491.5 10571.1 172.80

0.0045153 11056.7 9710.2 165.42 232 0.0031522 12512.3 10583.6 172.89

0.0044875 11077.5 9722.7 165.55 233 0.0031386 12533.1 10596.0 172.98

0.0044601 11098.3 9735.1 165.68 234 0,0031252 12553.9 10608.5 173.07

0.0044331 11119.1 9747.6 165.80 235 0.0031119 12574.7 10621.0 173.16

0 • 0044064 11139.9 9760*1 165.93 236 0*0030987 12595.5 10633*5 173.24

0.0043800 11160*7 9772.6 166.05 237 0*0030857 12616.2 10645.9 173.33

0.0043539 11181.5 9785*1 166.18 238 0*0030727 12637*0 10658.4 173.42

0.0043281 11202.3 9797.5 166.30 239 0.0030598 12657.8 10670.9 173.51

0.0043026 11223.1 9810.0 166.42 240 0.0030471 12678.6 10683.4 173.59

0.0042774 11243.8 9822.5 166.54 241 0.0030344 12699.

A

10695.8 173.68

0.0042525 11264.6 9835.0 166.67 242 0*0030219 12720.2 10708.3 173.77

0.0042279 11285.4 9847.5 166.79 243 0.0030094 12741.0 10720.8 173.85

0.0042036 11306.2 9859.9 166.91 244 0.0029971 12761.8 10733.3 173.94

0.0041796 11327.0 9872.4 167.03 245 0-0029849 12782.6 10745.7 174.02

0.0041558 11347.8 9884*9 167.14 246 0*0029727 12803.4 10758.2 174.11

0.0041323 11368.6 9897.4 167.26 247 0.0029607 12824.2 10770.7 174.19

0.0041091 11389.4 9909.9 167.38 24R 0.0029488 12844.9 10783.2 174.28

0 , 00^086

1

11410.2 9922.3 167.50 249 0.0029369 12865.7 10795.6 174.36

0.0040634 11431.0 9934,8 167.61 250 0.0029252 12886.5 10808.1 174.44

0.0040409 11451.8 9947.3 167.73 251 0.0029135 12907.3 10820.6 174.53

0.0040187 11472.6 9959.8 167.84 252 0.0029019 12928.1 10833.1 174.61

0.0039967 11493.4 9972.2 167.96 253 0.0028905 12948.9 10845.5 174.69

0.0039750 11514.2 9984.7 168.07 254 0.0028791 12969.7 10858.0 174.77

0.0039535 11535,0 9997.2 168.18 255 0.0028678 12990.5 10870.5 174.85

0.0039322 11555.8 10009.7 168.29 256 0.0028566 13011.3 10883.0 174.94

0.0039112 11576.6 10022.2 168.40 257 0.0028455 13032.1 10895.4 175.02

0.0038903 11597.4 10034.6 168.52 258 0.0028344 13052.8 10907.9 175.10

0.0038697 11618.2 10047.1 168.63 259 0.0028235 13073.6 10920.4 175.18

0.0038494 11639.

C

10059.6 168.74 260 0.0028126 13094.4 10932.9 175.26

0.0038292 11659.8 10072.1 168.84 261 0.0028018 13115.2 10945.3 175.34

0.0038092 11680.6 10084.5 168.95 262 0.0027911 13136.0 10957.8 175.42

0.0037895 11701.4 10097*0 169.06 263 0*0027 80

5

13156.8 10970*3 175.50

0.0037699 11722.2 10109.5 169.17 264 0.0027700 13177.6 10982.7 175.57

0.0037506 11743.0 10122.0 169.28 265 0.0027595 13198.4 10995.2 175.65

0.0037315 11763.8 10134.5 169.38 266 0.0027492 13219.2 11007.7 175.73

0.0037125 11784.5 10146.9 169.49 267 0.0027389 13240.0 11020.2 175.81

0.0036937 11805.3 10159,4 169.59 268 0.0027286 13260.7 11032.6 175.89

0.0036752 11826.1 10171.9 169.70 269 0.0027185 13281.5 11045,1 175.96

0.0036568 11846.9 10184.4 169.80 270 0.0027084 13302.3 11057.6 176.04

0,0036386 11867.7 10196.8 169.91 271 0.0026984 13323.1 11070.1 176.12

0.0036206 11888.5 10209.3 170.01 272 0.0026885 13343.9 11082.5 176.20

0.0036027 11909.3 10221.8 170.11 273 0.0026786 13364.7 11095.0 176.27

0.0035850 11930.1 10234.3 170.21 274 0.0026689 13385.5 11107.5 176.35

0.0035675 11950.9 10246.7 170.32 275 0.0026592 13406.3 11120.0 176.42

0.0035502 11971.7 10259.2 170.42 276 0.0026495 13427.1 11132.4 176.50

0 . 003533

1

11992.5 10271.7 170.52 277 0.0026400 13447.8 11144.9 176.57

0.0035161 12013.3 10264.2 170.62 278 0.0026305 13468.6 11157.4 176.65

0.0034992 12034.1 10296.6 170.72 279 0.0026210 13489.4 11169.9 176.72

0 • U034826 12054.9 10309*1 170.82 280 0*0026117 13510*2 11182.3 176.80

0.0034660 12075.7 10321.6 170.92 281 0.0026024 13531.0 11194.8 176.87

0.0034497 12096.4 10334.1 171.01 282 0.0025931 13551.8 11207.3 176.95

0.0034335 12117.2 10346.5 171.11 283 0.0025840 13572.6 11219.7 177.02

0.0034174 12138.0 10359.0 171.21 284 0*0025749 13593*4 11232*2 177.09

0.0034015 12158.8 10371 .5 171.31 285 0.0025658 13614.2 11244.7 177.17

0.0033858 12179.6 10384*0 171*40 286 0*0025569 13634.9 11257*2 177*24

0.0033702 12200*4 10396.4 171*50 287 0*0025480 13655.7 11269.6 177.31

0*0033547 12221*2 10408*9 171*59 288 0*0025391 13676*5 11282*1 177*38

0.0033394 12242.0 10421 .4 171.69 289 0.0025303 13697.3 1 1294.6 177.46

0.0033242 12262.8 10433.9 171.78 290 0.0025216 13718.1 11307.1 177.53

0.0033091 12283.6 10446.3 171.88 291 0.0025129 13738.9 11319.5 177.60

0.0032942 12304.4 10458.8 171.97 292 0.0025043 13759.7 11332.0 177.67

0.0032795 12325-2 10471.3 172.07 293 0.0024958 13780.5 11344.5 177.74

0.0032648 12346.0 10483.8 172.16 294 0.0024873 13801.3 11357.0 177.81

0.0032503 12366.7 10496.2 172*25 295 0.0024788 13822.0 11369.4 177.88

0.0032359 12387.5 10508.7 1 72 .34 296 0.0024705 13842.8 11381.9 177.95

0.0032216 12408.3 10521.2 172.44 297 0.0024621 13863.6 11394.4 178.02

0.0032075 12429.1 1 0533 •

7

172.53 298 0.0024539 13884.4 11406*8 178.09

0.0031935 12449.9 10546.1 172.62 299 0.0024457 13905.2 11419.3 178.16

0.0031796 12470.7 10558.6 172.71 300 0.0024375 13926.0 11431.8 178.23

40
0.08 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

86 0*0113669 9473.4^ 8760*2 149.84

87 0.0112353 9494.2 8772*7 150*08

88 0.0111068 9515.1 8785.2 150.32

89 0.0109812 9535.9 8797.7 150.55

90 0 . 0l0a5g4 9556.8 8810.2 150.78

TEMP.

K DENSITY

MOL/LITER

enthalpy

J/MOL

internal

ENERGY

J/MOL

entropy

j/mol-k

91 0.0107384 9577.6 8822.8 151.01

92 0.0106209 9598.5 8835.3 151.24

93 0.0105061 9619.3 8847.8 151.47

94 0.0103937 9640.2 8860.3 151.69

95 0.0102837 9661.1 8872.8 151.91

96 0.0101760 9681.9 8885.3 152.13

97 0.0100705 9702.8 8897.8 152.35

98 0*0099672 9723*6 8910*3 152.56

99 0*0098661 9744*5 8922*8 152*77

100 0,0097669 9765.3 8935.3 152.98

101 0.0096698 9786.1 8947.8 153.19

10? 0*0095745 9807.0 8960*3 153.39

103 0.0094811 9827.8 8972.8 153.60

104 0.0093896 9848.7 8985.4 153.80

105 0.0092998 9869.5 8997.9 154.00

106 0.0092117 9890.4 9010.4 154.20

107 0.0091252 9911.2 9022.9 154,39

108 0.0090404 9932.0 9035.4 154.58

109 0.0089571 9952.9 9047.9 154.78

110 0.0088754 9973.7 9060.4 154.97

111 0.0087951 9994.5 9072.9 155.16

112 0.0087163 10015.4 9085.4 155.34

113 0*0086389 10036.2 9097.9 155.53

114 0*0085629 10057.0 9110*4 155-71

115 0*0084882 10077*9 91?2*9 155*89

116 0*0084148 10098*7 9135*4 156*07

117 0.0083426 10119.5 9147.9 156.25

118 0.0082717 10140.4 9160,4 156.43

1 1 9 0.0082020 10161.2 9172.9 156,61

120 0,0081334 10182.0 9185,4 156.78

121 0.0080660 10202.8 9197.9 156.95

12? 0.0079997 10223.7 9210.4 157.12

123 0.0079345 10244.5 9222.8 157.29

124 0.0078703 10265.3 9235*3 157.46

125 0.0078072 10286.1 9247.8 157.63

126 0*0077450 10307*0 9260*3 157.80

127 0*0076839 10327.8 9272.8 157.96

128 0.0076237 10348,6 9285.3 158.12

129 0.0075645 10369.4 9297.8 158.29

130 0.0075061 10390.2 9310.3 158,45

131 0.0074487 10411.1 9322,8 158.61

132 0*0073921 10431 .9 9335.3 158.76

133 0*0073364 10452*7 9347*8 158*92

134 0*0072816 10473*5 9360*3 159*08

135 0*0072275 10494.3 9372*8 159.23

136 0*0071742 10515*2 9385*2 159.39

137 0.0071218 10536.0 9397.7 159.54

138 0.0070701 10556.8 9410.2 159.69

139 0.0070191 10577.6 9422.7 159.84

140 0,0069688 10598.4 9435.2 159.99

141 0.0069193 10619.2 9447.7 160.14

142 0.0068705 10640,0 9460.2 160.28

143 0.0068224 10660.9 9472.7 160.43

1 44 0.0067749 10681.7 9485.2 160.58

145 0.0067281 10702.5 9497.6 160.72

146 0.0066819 10723.3 9510.1 160.86

147 0.0066364 10744.1 95?2 .

6

161.00

148 0.0065915 10764.9 9535.1 161.15

149 0.0065472 10785.7 9547.6 161.29

150 0.0065034 10806.5 9560.1 161.43

151 0.0064603 10827.3 9572.6 161.56

15? 0.0064177 10R48.

1

9585.0 161.70

153 0.0063757 10869.0 9597.5 161.84

154 0*0063343 10889.8 9610*0 161.97

155 0*0062933 10910*6 96?2 •

5

1 6? • 1

1

156 0*0062529 10931.4 9635*0 162.24

157 0*0062130 10952*? 9647*5 162*37

158 0.0061737 10973.0 9660.0 162.51

159 0.0061348 10993.8 9672.4 162.64

160 0.0060964 11014.6 9684.9 162.77

41
0.08 ATMOSPHERE isobar

temp.

K DENSITY

mol/liter

ENTHALPY

J/MOL INTERNAL

ENERGY

J/MOL

entropy

J/MOL-K

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

161 0 .0060585 11035.4 9697.4 162 90 231 0 0042213 12491.3 10570.9 170.41

162 0.0060210 11056.2 9709.9 163 03 232 0 0042031 12512*1 10583*4 170*50

163 0.0059840 11077*0 9722*4 163 15 233 0 0041850 12532*8 10595*9 170*59

164 0*0059475 11097*8 9734.9 163 28 234 0 0041671 12553*6 10608*4 170*67

165 0.0059114 11118.6 9747.3 163 41 235 0 0041494 12574.4 10620.8 170.76

166 0.0058758 11139.4 9759.8 163 53 236 0 0041318 12595.2 10633.3 170.85

167 0,0058405 11160.2 9772.3 163 66 237 0 0041143 12616.0 10645,8 170.94

168 0.0058057 11181.0 9784.8 163 78 238 0 0040970 12636.8 10658.3 171.03

169 0,0057713 11201.8 9797.3 163 91 239 0 0040799 12657.6 10670.7 l7l.ll

170 0.0057373 11222.6 9809.7 164 03 240 0 0040629 12678.4 10683.2 171.20

171 0.0057037 11243.4 9822.2 164 15 241 0 0040460 12699.2 10695.7 171.29

172 0.0056705 11264*2 9834.7 164 27 242 0 0040293 12720.0 10708*2 171*37

173 0.0056377 11285*0 9847.2 164 39 243 0 0040127 12740.8 10720*6 171.46

174 0.0056053 11305.8 9859.7 164 51 244 0 0039963 12761.6 10733.1 171.54

175 0.0055732 11326.6 9872*2 164 63 245 0 0039799 12782*4 10745.6 171.63

176 0.0055415 11347.4 9884.6 164 75 246 0 0039638 12803.1 10758.1 171.71

177 0.0055102 11368.3 9897.1 164 87 247 0 0039477 12823.9 10770.5 171.80

178 0.0054792 11389.1 9909.6 164 99 248 0 0039318 12844.7 10783.0 171.88

179 0.0054486 11409.9 9922,1 165 10 249 0 0039160 12865.5 10795.5 171.97

180 0.0054183 11430.7 9934.6 165 22 250 0 0039003 12886.3 10808.0 172.05

181 0.0053883 11451.5 9947.0 165 33 251 0 0038848 12907.1 10820.4 172.13

182 0.0053587 11472*3 9959.5 165 45 252 0 0038693 12927.9 10832.9 172.22

183 0.0053294 11493*1 9972.0 165 56 253 0 0038540 12948.7 10845.4 172.30

184 0*0053004 11513*9 9984.5 165 68 254 0 0038389 12969*5 10857*9 172*38

185 0.0052717 11534.7 9997.0 165 79 255 0 0038238 12990.3 10870.3 172.46

186 0.0052433 11555.5 10009.4 165 90 256 0 0038089 13011,1 10882.8 172.54

187 0.0052152 11576.2 10021.9 166 01 257 0 0037940 13031.9 10895.3 172.62

188 0.0051875 11597.0 10034.4 166 12 258 0 0037793 13052.6 10907.8 172.70

189 0*0051600 11617.8 10046.9 166 23 259 0 0037647 13073.4 10920*2 172*78

190 0.0051328 11636.6 10059.4 166 34 260 0 0037502 13094.2 10932.7 172.86

191 0.0051059 11659.4 10071.8 166 45 261 0 0037359 13115.0 10945.2 172.94

192 0.0050793 11680.2 10084.3 166 56 262 0 0037216 13135.8 10957.7 173.02

193 0.0050530 11701.0 10096.8 166 67 263 0 0037074 13156.

>

10970*1 173.10

194 0.0050269 11721*8 10109.3 166 78 264 0 0036934 13177.4 10982.6 173.18

195 0.0050011 11742.6 10121.7 166 88 265 0 0036795 13198.2 10995. 1 173.26

196 0 .0049756 11763.4 10134.2 166 99 266 0 0036656 13219.0 11007.6 173.34

197 0.0049503 11784.2 10146,7 167 10 267 0 0036519 13239.8 11020.0 173.42

198 0.0049253 11805.0 10159.2 167 20 268 0 0036383 13260.6 11032.5 173.50

199 0,0049005 11825.8 10171,7 167 31 269 0 0036247 13281 .3 11045,0 173.57

200 0.0048760 11846.6 10184.1 167 41 270 0 0036113 13302.1 11057.5 173.65

201 0.0048517 11867.4 10196.6 167 51 271 0 0035980 13322.9 11069.9 173.73

202 0.0048277 11388.2 10209.1 167 62 272 0 0035847 13343.7 11082.4 173.80

203 0.0048039 11909.0 10221*6 167 72 273 0 0035716 13364.5 11094.9 173.88

204 0.0047803 11929.8 10234.1 167 82 274 0 0035586 13385.3 11107.4 173.96

205 0.0047570 11950.6 10246.5 167 92 275 0 0035456 13406.1 11119.8 174,03

206 0.0047339 11971.4 10259.0 168 02 276 0 0035328 13426.9 11132.3 174.11

207 0-0047110 11992*2 10271*5 168 12 277 0 0035200 13447.7 11144*8 174.18

208 0*0046883 12013*0 10284*0 168 23 278 0 0035073 13468*5 11157*2 174.26

209 0 . 0046659 12033.8 10296.4 168 32 279 0 0034948 13489.3 11169.7 174.33

210 0.0046436 12054.6 103C8.9 168 42 280 0 0034823 13510.0 11182.2 174.41

211 0.0046216 12075.4 10321.4 168 52 281 0 0034699 13530.8 11194.7 174.48

212 0.0045998 12096.2 10333.9 168 62 282 0 0034576 13551.6 11207.1 174.55

213 0.0045782 12117*0 10346*3 168 72 283 0 0034454 13572.4 11219.6 174.63

214 0.0045568 12137.8 10358*8 168 82 284 0 0034332 13593.2 11232.1 174.70

215 0.0045356 12158.6 10371*3 168 91 285 0 0034212 13614.0 11244.6 174.77

216 0.0045146 12179.3 10383*8 169 01 286 0 0034092 13634.8 11257.0 174.85

217 0.0044936 12200*1 10396.3 169 11 287 0 0033973 13655.6 11269.5 174.92

218 0.0044731 12220*9 10408.7 169 20 288 0 0033855 13676.4 11282.0 174.99

219 0 • 004452 7 12241*7 10421.2 169 30 289 0 0033738 13697.2 11294.5 175.06

220 0.0044324 12262*5 10433.7 169 39 290 0 0033622 13717.9 11306.9 175.14

221 0.0044124 12283.3 10446.2 169 49 291 0 0033506 13738.7 11319.4 175.21

222 0.00*3925 12304.1 10458*6 169 58 292 0 0033391 13759.5 11331.9 175.28

223 0*0043728 12324*9 10471*1 169 67 293 0 0033277 13780*3 11344.4 175.35

224 0*00*3532 12345*7 10483*6 169 77 294 0 0033164 13801*1 11356*8 175*42

225 0*0043339 12366*5 10496*1 169 86 295 0 0033052 13821*9 11369*3 175.49

226 0 * 00*31 4 J 12387*3 10508*5 169 95 296 0 0032940 13842*7 11381*8 175.56

227 0.00*2957 12408.1 10521.0 170 04 297 0 0032829 13863.5 11394.3 175.63

228 0.0042768 12428.9 10533.5 170 13 298 0 0032719 13884.3 11406.7 175.70

229 0.0042581 12449.7 10546.0 170 23 299 0 0032609 13905.1 11419.2 175.77

230 0.0042396 12470.5 10558.5 170 32 300 0 0032501 13925.8 11431.7 175.84

42
0.10 atmosphere isobar

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

J/MOL-K

86 0.0142180 9472.1 8759.4 147

87 0.0140532 9493.0 8772.0 148

88 0.0138922 9513.9 8784.5 148

89 0.0137348 9534.7 8797.0 148

90 0.0135810 9555.6 8809.5 148

TEMP.

K density

MOL/LITER

ENTHALPY

J/MOL INTERNAL ENERGY

J/MOL

ENTROPY

J/MOL-K

91 0 0134306 9576.5 8822.0 149.15

R? 0 0132835 9597.4 8834.6 149.38

93 0 0131397 9618.2 8847*1 149*61

94 0 0129989 9639.1 8859*6 149.83

95 0 0128611 9660*0 8872*1 150*05

96 0 0127262 9680*8 8884*6 150*27

97 0 0125942 9701.7 8897.1 150.48

98 0 0124649 9722.6 8909.7 150.70

99 0 0123382 9743.4 8922.2 150.91

100 0 0122140 9764.3 8934.7 151.12

101 0 0120924 9785.2 8947.2 151*33

102 0 0119732 9806.6 8959*7 151*53

103 0 0118563 9826*9 8972*2 151*74

104 0 0117416 9847*7 8984*8 151*94

105 0 0116292 9868*6 8997*3 152*14

106 0 0115189 9889*4 9009*8 152*33

107 0 0114107 9910*3 9022*3 152*53

108 0 0113045 9931*1 9034*8 152*72

109 0 0112003 9952*0 9047*3 152*92

110 0 0110980 9972.8 9059.8 153.11

111 0 0109976 9993.7 9072.3 153.30

112 0 0108989 10014.5 9084.8 153.48

113 0 0108021 10035.4 9097.3 153.67

114 0 0107069 10056*2 9109.9 153.85

115 0 0106134 10077*1 9122*4 154*03

116 0 0105215 10097*9 9134*9 154.21

117 0 0104312 10118*8 9147*4 154*39

118 0 0103425 10139*6 9159*9 154*57

119 0 0102552 10160*4 9172*4 154*75

120 0 0101695 10181*3 9184*9 154*92

121 0 0100851 10202.1 9197.4 155.09

12? 0 0100021 10222.9 9209.9 155.26

123 0 0099205 10243.8 9222*4 155.44

124 0 0098402 10264.6 9234.9 155.60

125 0 0097613 10285.4 9247.4 155.77

126 0 0096835 10306.3 9259.9 155.94

127 0 OO 96 Q 7 O 10327.1 9272.4 156.10

128 0 0095317 10347.9 9284.9 156.27

129 0 0094576 10368.8 9297.4 156.43

130 0 0093847 10389.6 9309*9 156.59

131 0 0093128 10410.4 9322.4 156,75

132 0 0092420 10431.2 9334.9 156.91

133 0 0091724 10452*1 9347.4 157*06

134 0 0091037 10472*9 9359*9 157*22

135 0 0090361 10493*7 9372*4 157.37

136 0 0089695 10514.5 9384.9 157.53

137 0 0089038 10535.4 9397.3 157.68

138 0 0088391 10556.2 9409.8 157.83

139 0 0087754 10577.0 9422.3 157.98

140 0 00P7125 10597.8 9434.8 158.13

141 0 0086506 10618.7 9447.3 158.28

142 0 0085895 10639*5 9459*8 158*43

143 0 0085293 10660*3 9472*3 158.57

144 0 0084700 10681*1 9484*8 158*72

145 0 00R41 14 10701*9 9497*3 158*86

146 0 0083537 10722.8 9509.8 159.00

147 0 0082967 10743.6 9522.3 159.15

148 0 0082405 10764,4 9534.8 159.29

149 0 0081851 10785.2 9547.2 159.43

150 0 0081304 10806.0 9559.7 159.57

151 0 0080765 10826.8 9572.2 159.71

152 0 0080232 10847.6 9584.7 159.84

153 0 0079707 10868.5 9597*2 159.98

154 0 0079189 10889.3 9609.7 160.12

155 0 0078677 10910.1 9622.2 160.25

156 0 0078171 10930.9 9634.7 160.38

157 0 0077673 10951.7 9647.2 160.52

158 0 0077180 10972.5 9659.6 160.65

159 0 0076694 10993.3 9672.1 160.78

160 0 0076214 11014.1 9684.6 160.91

43
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211 212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

0.10 ATMOSPHERE ISOBAR

DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

internal

ENERGY

J/MOL

entropy

j/mol-k

0.0075739 11035.0 9697.1 161.04 231 0.0052768 12491.0 10570.8 168.55

0.0075271 11055,8 9709.6 161.17 232 0.0052540 12511.8 10583.2 168.64

0.0074809 11076.6 9722.1 161.30 233 0.0052314 12532.6 10595.7 168.73

0.0074352 11097.4 9734.6 161.42 234 0.0052091 12553.4 10608.2 168.82

0.0073900 11118.2 9747.0 161.55 235 0.0051869 12574.2 10620.7 168,91

0.0073455 11139.0 9759.5 161*68 236 0*0051649 12595.0 10633*1 169.00

0.0073014 11159.8 9772.0 161.80 237 0^0051431 12615.8 10645*6 169.08

0.0072579 11180.6 9784.5 161.93 238 0.0051215 12636.6 10658.1 169.17

0.0072149 11201.4 9797.0 162.05 239 0.0051000 12657,4 10670,6 169.26

0.0071724 11222.2 9809.5 162.17 240 0.0050788 12678.2 10683.0 169,34

0.0071304 11243.0 9822.0 162.29 241 0.0050577 12699.0 10695.5 169.43

0.0070888 11263.8 9834.4 162. A2 242 0.0050368 12719.8 10708.0 169.52

0.0070478 11284.6 9846.9 162.54 243 0.0050160 12740.6 10720.5 169.60

0.0070072 113C5.5 9859.4 162*66 244 0.0049955 12761.3 10733.0 169.69

0*0069672 11326*3 9871*9 162*78 245 0*0049751 12782-1 10745*4 169-77

0.0069275 11347.1 9884.4 162*89 246 0*0049548 12802*9 10757*9 169.86

0.0068883 11367*9 9896*9 163*01 247 0*0049348 12823*7 10770*4 169.94

0.0068496 11388.7 9909.3 163*13 248 0.0049149 12844.5 10782*9 170.03

0.0068113 1 1409.5 9921.8 163*25 249 0.0048951 12865.3 10795.3 170.11

0*0067734 11430*3 9934.3 163*36 250 0.0048755 12886*1 10807.8 170*19

0.0067359 11451.1 9946.8 163.48 251 0.0048561 12906.9 10820.3 170.28

0.0066988 11471.9 9959.3 163.59 252 0.0048368 12927.7 10832.8 170.36

0.0066622 11492.7 9971.8 163.71 253 0*0048177 12948.5 10845.2 170.44

0*0066259 11513*5 9984*2 163*82 254 0.0047987 12969.3 10857.7 170.52

0 * 0065901 11534.3 9996*7 163*93 255 0*0047799 12990*1 10870*2 170.61

0 >0065546 11555-1 10009.2 164*04 256 0*0047612 13010*9 10882.7 170.69

0.0065195 11575.9 10021.7 164.16 257 0.0047427 13031.7 10895*1 170.77

0*0064848 11596*7 10034*2 164*27 258 0*0047243 13052*5 10907*6 170*85

0*0064505 11617*5 10046*6 164*38 259 0*0047060 13873*2 10920*1 170*93

0*0064165 11638*3 10059*1 164.49 260 0*0046879 13094.0 10932*6 171.01

0.0063828 11659.1 10071.6 164.60 261 0.0046699 13114.8 10945.0 171.09

0.0063496 11679.9 10084.1 164.70 262 0.0046521 13135.6 10957.5 171.17

0 . 0063166 11700*7 10096.6 164.81 263 0 *0046344 13156.4 10970*0 171.25

0.0062840 11721*5 10109.0 164.92 264 0-0046168 13177.2 10982.5 171.33

0.0062518 11742.3 10121.5 165.03 265 0.0045994 13198.0 10994.9 171.41

0.0062199 11763.1 10134.0 165.13 266 0.0045821 13218.8 11007.4 171.48

0.0061882 11783.9 10146.5 165.24 267 0.0045650 13239.6 11019.9 1 7 1 .56

0.0061570 11804.7 10159,0 165.34 268 0.0045479 13260.4 11032.4 171.64

0.0061260 11825.5 10171.4 165.45 269 0.0045310 13281.2 11044.8 171.72

0.0060953 11846.3 10183.9 165.55 270 0.0045142 13302.6 11057.3 171.79

0.0060650 11867.1 10196.4 165.66 271 0.0044975 13322.8 11069.8 171.87

0.0060349 11887.9 10208.9 165.76 272 0.0044810 13343.5 11082.3 171.95

0.0060052 11908.7 10221.4 165.86 273 0.0044646 13364.3 11094.7 172.02

0.0059757 11929.5 10233-8 165-97 274 0.Q044483 13385.1 11107.2 172.10

0.0059465 11950.3 10246.3 166.07 275 0.0044321 13405.9 11119.7 172.18

0.0059176 11971.1 10258.8 166.17 276 0.0044160 13426.7 11132.2 172.25

0 .0058890 11991.9 10271,3 166.27 277 0.0044001 13447.5 11144.6 172.33

0.0058607 12012.7 10283*8 166.37 278 0*0043843 13468.3 11157.1 172.40

0.00&8326 12033.5 10296.2 166.47 279 0.0043685 13489,1 11169.6 172.48

0.0058048 12054.3 10308*7 166-57 280 0.0043529 13509.9 11182.1 172.55

0.0057773 12075.1 10321.2 166.67 281 0.004337a 13530.7 11194.5 172.62

0.0057500 12095.9 10333.7 166.77 282 0.0043220 13551.5 11207.0 172.70

0.0057230 12116.7 10346.2 166.86 283 0.0043068 13572.3 11219.5 172.77

0.0056962 12137.5 10358.6 166.96 284 0.0042916 13593.0 11232.0 172.84

0 .0056697 12158.3 10371.1 167.06 285 0.0042765 13613.8 11244.4 172.92

0.0056435 12179.1 10383.6 167.15 286 0.0042616 13634.6 11256.9 172.99

0.0056174 12199.9 10396.1 167.25 287 0.0042467 13655.4 11269.4 173.06

0 .005591 7 12220*7 10408*5 167.35 288 0-0042320 13676.2 112B1-9 173.14

0 .0065661 12241.5 10421 .Q 167.44 289 0.0042173 13697.0 11294.3 173.21

0.0055408 12262.3 10433.5 167.54 290 0.0042028 13717.8 11306.8 173.28

0.005515? 12283.1 10446.0 167.63 291 0.0041883 13738.6 11319.3 173.35

0.0054906 12303.9 10458.5 167.72 292 0.0041740 13759.4 11331.8 173.42

0.0054662 12324.7 10470.9 167.82 ?93 0.0041597 13780.2 11344.2 173.49 0.0054418 12345.4 10483.4 167.91 294 0.0041456 13801.0 11356.7 173.56

0.0054176 12366.2 10495.9 168.00 295 0.0041315 13821.7 11369.2 173.64

0.0053936 12387.0 10508.4 168. 09 296 0.0041176 13842.5 11381 .7 173.71

0 , 0053b98 12407.8 10520.8 168. 19 297 0.0041037 13863.3 11394.1 173.78

0 .0053462 12428.6 10533.3 168. ?B 298 0.0040899 13884.1 11406.6 173.85

0.0053229 12449.4 10545.8 168.37 299 0.0040762 13904.9 11419.1 173.92

0.0052997 12470.2 10558.3 1 b8 .46 300 0.0040626 13925.7 11431 .6 173.98

44
0.20 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

86 0.0285311 9465.9 8755.6 142

87 0.0281975 9486,9 8768.2 142

88 0.0278717 9507.8 8780.7 142

89 0.0275534 9528.8 8793.3 142

90 0.0272424 9549.8 8805.9 143

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

91 0.0269384 9570.7 8818.4 143.35

92 0.0266412 9591.7 8831.0 143.58

93 0.0263505 9612.7 8843.6 143.80

94 0.0260662 9633.6 8856.1 144.03

95 0.0257880 9654.6 8868.7 144.25

96 0.0255157 9675.5 8881.3 144.47

97 0.0252492 9696.5 8893.8 144.69

98 0.0249882 9717.4 8906.4 144.90

99 0.0247326 973R.4 8919.0 145.11

100 0.0244823 9759.3 8931.5 145.32

101 0.0242370 9780.2 8944.1 145.53

102 0.0239966 9801.2 8956.6 145.74

103 0*0237610 9822*1 8969*2 145*94

1 04 0.0235300 9843.0 8981.8 146.15

105 0,0233035 9863.9 8994.3 146.35

106 0*0230813 9884.9 9006*9 146.54

107 0*0228634 9905*8 9019*4 146*74

108 0*0226496 9926*7 9032*0 146*94

109 0*0224398 9947*6 9044*5 147*13

110 0*0222338 9968*5 9057*1 147*32

111 0.0220316 9989.4 9069.6 147.51

112 0*0218331 10010.4 9082*2 147.70

113 0*0216382 10031*3 9094*7 147*88

114 0*0214467 10052*2 9107*2 148*07

115 0*0212587 10073*1 9119*8 148*25

116 0.0210739 10094.0 9132.3 148.43

117 0.0208923 10114.9 9144.9 148.61

118 0.0207139 10135.8 9157.4 148.79

119 0.0205384 10156.6 9169.9 148.96

120 0.0203660 10177.5 9182.5 149.14

121 0.0201964 10198.4 9195.0 149.31

122 0.0200297 10219.3 9207.5 149.48

123 0.0198657 10240.2 9220.1 149.65

124 0.0197044 10261.1 9232.6 149.82

125 0.0195457 10282.0 9245.1 149.99

126 0.0193895 10302.8 9257.6 150.16

127 0*0192358 10323*7 9270*2 150*32

128 0*0190846 10344*6 9282*7 150*49

129 0*0189357 10365.5 9295*2 150.65

130 0.0187892 10386.3 9307.7 150.81

131 0.0186449 10407.2 9320.3 150.97

132 0.0185028 10428.1 9332*8 151.13

133 0.0183629 10448.9 9345.3 151.28

134 0.0182251 10469.8 9357.8 151.44

135 0.0180894 10490.7 9370.4 151.60

136 0*0179556 10511.5 9382.9 151.75

137 0*0178239 10532*4 9395*4 151*90

138 0.0176940 10553.2 9407.9 152.05

139 0.0175661 10574.1 9420.4 152.21

140 0*0174400 10595.0 9432.9 152.35

141 0.0173157 10615.8 9445.5 152.50

142 0.0171932 10636.7 9458.0 152.65

143 0*0170724 10657.5 9470*5 152*80

144 0*0169533 10678*4 9483*0 152*94

145 0*0168358 10699.2 9495*5 153*09

146 0*0167200 10720*1 9508*0 153*23

147 0*0166057 10740.9 9520*5 153*37

148 0*0164931 10761*8 9533*0 153*51

149 0.0163819 10782.6 9545.5 153.65

150 0.0162722 10803.5 9558.0 153.79

151 0.0161640 10824.3 9570.6 153.93

152 0.0160573 10845.1 9583.1 154.07

153 0*0159519 10866*0 9595*6 154*21

154 0*0158479 10886*8 9608*1 154*34

155 0*0157453 10907*7 9620*6 154*48

156 0.0156440 10928.5 9633.1 154.61

157 0.0155440 10949.3 9645.6 154.74

158 0*0154453 10970*2 9658*1 154.88

159 0.0153478 10991.0 9670.6 155.01

160 0.0152515 11011.8 9683.1 155.14

45
K

161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211 212

213

214

215

216

217

218

219

220

221 22 ? 223

224

225

226

227

228

229

230

0.20 ATMOSPHERE ISOBAR

DENSITY

mol/liter

ENTHALPY

J/MOL

internal

energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

0.0151565 11032 7 9695.6 155 27 231 0 0105554 12489 8 10569.9

0.0150626 11053 5 9708.1 155 40 232 0 0105098 12510 6 10582*4

0*0149699 11074 4 9720*6 155 53 233 0 0104647 12531 4 10594*9

0.0148783 11C95 2 9733*1 155 65 234 0 0104199 12552 2 10607*3

0*0147878 11116 0 9745*6 155 78 235 0 0103755 12573 0 10619*8

0*0146985 11136 8 9758*1 155 91 236 0 0103315 12593 8 10632*3

0.0146102 11157 7 9770*6 156 03 237 0 0102878 12614 6 10644.8

0.0145230 11178 5 9783.1 156 15 238 0 0102446 12635 4 10657.3

0,0144368 11199 3 9795.6 156 28 239 0 0102017 12656 2 10669.7

0.0143516 11220 2 9808.1 156 40 240 0 0101591 12677 0 10682.2

0.0142674 11241 0 9820.6 156 52 241 0 0101169 12697 9 10694.7

0*0141842 11261 8 9833*1 156 64 242 0 0100751 12718 7 10707.2

0*0141020 11282 6 9845*6 156 77 243 0 0100335 12739 5 10719*7

0.0140208 11303 5 9858.1 156 89 244 0 0099924 12760 3 10732.2

0.0139404 11324 3 9870.6 157 00 245 0 0099516 12781 1 10744.6

0.0138610 11345 1 9883.1 157 12 246 0 0099111 12801 9 10757.1

0.0137825 11365 9 9895.6 157 24 247 0 0098709 12822 7 10769.6

0.0137048 11386 8 9908*1 157 36 248 0 0098310 12843 5 10782*1

0*0136281 11407 6 9920*5 157 48 249 0 0097915 12864 3 10794*6

0*0135522 11428 4 9933*0 157 59 250 0 0097523 12885 1 10807*0

0.0134771 11449 2 9945.5 157 71 251 0 0097134 12905 9 10819.5

0.0134029 11470 1 9958.0 157 82 25? 0 0096748 12926 7 10832.0

0.0133295 11490 9 9970.5 157 94 253 0 0096366 12947 5 10844.5

0*0132569 11511 7 9983*0 158 05 254 0 0095986 12968 3 10«57*0

0*0131850 11532 5 9995*5 158 16 255 0 0095609 12989 1 10869*4

0*0131140 11553 3 10008*0 158 27 256 0 0095235 13009 9 10881.9

0.0130437 11574 2 10020.5 158 39 257 0 0094864 13030 7 10894.4

0,0129742 11595 0 10033.0 158 50 258 0 0094496 13051 5 10906.9

0.0129054 11615 8 10045.5 158 61 259 0 0094131 13072 3 10919.4

0.0128373 11636 6 10058.0 158 72 260 0 0093769 13093 1 10931.8

0.0127700 11657 4 10070.5 158 83 261 0 0093409 13113 9 10944.3

0*0127033 11678 2 10082*9 158 94 262 0 0093052 13134 7 10956*8

0.0126373 11699 1 10095.4 159 04 263 0 0092698 13155 5 10969.3

0.0125721 11719 9 10107.9 159 15 264 0 0092347 13176 3 10981.8

0.0125075 11740 7 10120.4 159 26 265 0 0091998 13197 1 10994.2

0.0124435 11761 5 10132*9 159 36 266 0 0091652 13217 9 11006*7

0*0123802 11782 3 10145.4 159 47 267 0 0091308 13238 7 11019*2

0*0123176 11803 1 10157*9 159 58 268 0 0090967 13259 5 11031*7

0*0122556 11823 9 10170*4 159 68 269 0 0090629 13280 3 11044*2

0*0121942 11844 8 10182*9 159 78 270 0 0090293 13301 1 11056*6

0.0121334 11865 6 10195.3 159 89 271 0 0089960 13321 9 11069.1

0.0120732 1 1 886 4 10207.8 159 99 272 0 0089629 13342 7 11081.6

0.0120136 11907 2 10220,3 160 09 273 0 0089300 13363 5 11094.1

0,01 1954 1 11928 0 10232.8 160 20 274 0 0088974 13384 2 11106.5

0.0118962 11948 8 10245.3 160 30 275 0 0088650 13405 0 11119.0

0.0118384 11969 6 10257.8 160 40 276 0 0088329 13425 8 11131.5

0.0117811 11990 4 10270.3 160 50 277 0 0088009 13446 6 11144.0

0.0117244 12011 3 10282.8 160 60 278 0 0087693 13467 4 11156.5

0*0116682 12032 1 10295.2 160 70 279 0 0087378 13488 2 11168*9

0*0116125 12052 9 10307*7 160 80 280 0 0087066 13509 0 11181*4

0.0115574 12073 7 10320.2 160 9(1 281 0 0086756 1 35?9 8 11193.9

0*01150?8 12094 5 10332*7 161 00 282 0 0086448 13550 6 11206*4

C.ni 14487 12115 3 10345*2 161 10 283 0 0086142 13571 4 11218*9

0*0113951 12136 1 10357*7 161 19 284 0 0085839 13592 2 11231*3

0*0113420 12156 9 10370*2 161 29 285 0 0085537 13613 0 11243*8

0*01 12894 121 77 7 10382*6 161 39 286 0 0085238 13633 8 11256*3

0*0) 12373 12198 5 10395*1 161 48 287 0 0084941 13654 6 11268*8

0*0111857 12219 3 10407*6 161 58 288 0 0084646 13675 4 11281*2

0.0111346 12240 1 10420*1 161 67 289 0 0084353 13696 2 11293.7

0.0U0839 12261 0 10432.6 161 77 290 0 0084062 13717 0 11306.2

0.01 10337 12281 8 10445.1 161 86 291 0 0083772 13737 9 11318.7

0*0109839 12302 6 10457.5 161 96 29? 0 0083485 13758 6 11331.2

0*0109346 12323 4 10470*0 162 05 293 0 0083200 13779 4 11343.6

0*0108857 12344 2 10482*5 162 14 ?94 0 0082917 13800 2 11356.1

0.0108372 12365 0 10495*0 162 24 295 0 0082636 13821 0 11368.6

0.0107892 12385 a 10507.5 162 33 296 0 0082356 13841 8 11381.1

0.0107416 12406 6 10520.0 162 42 287 0 0082079 13862 6 11393.5

0.0106945 12427 4 10532.4 162 51 298 0 00ei803 13883 4 11406.0

0*0106477 12448 2 10544.9 162 60 299 0 0081530 13904 2 11418.5

0*0106013 12469 0 10557.4 162 69 300 0 00H1258 13925 0 11431.0

ENTROPY

J/MOL-K

162.78

162.87

162.96

163.05

163*14

163.23

163.32

163.40

163.49

163.58

163.66

163.75

163*84

163.92

164.01

164.09

164.18

164*26

164*34

164*43

164.51

164.59

164.68

164*76

164.84

164.92

165.00

165.08

165.16

165.24

165.32

165.40

165.48

165.56

165.64

165*72

165*80

165*87

165.95

166*03

166.11

166.18

166.26

166.33

166.41

166.49

166.56

166.64

166*71

166*78

166.86

166*93

167*01

167*08

167*15

167*23

167*30

167*37

167.44

167.51

167.59

167.66

167*73

167.80

167.87

167.94

168.01

168.08

168.15

168.22

46
0.30 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

86 0.0429413 9459*6 8751.7 138

87 0*0424348 9480*7 8764*3 138

88 0.0419403 9501.7 8776.9 139

89 0.0414574 9522.0 8789.6 139

90 0.0409857 9543.9 8802*2 139

TEMP. DENSITY ENTHA4.PY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

91 0 0405247 9564 9 8814.8 139 94

92 0 0400742 9586 0 8827.4 140 17 93 0 0396337 9607 0 8840.0 HO 40

94 0 0392029 9628 1 8852.7 140 62

95 0 0387815 9649 1 8865.3 140 84

96 0 0383693 9670 2 8877.9 141 06 97 0 0379658 9691 2 8890.5 141 28

98 0 0375709 9712 2 8903.1 1 4

1

50

99 0 0371842 9733 2 8915.7 1 4

1

71 100 0 0368055 9754 3 8928.3 1 4

1

92

101 0 0364345 9775 3 8940.9 142 13 102 0 0360710 9796 3 8953.5 142 34

103 0 0357148 9817 3 8966.1 142 54

104 0 0353657 9838 3 6978*7 142 75

105 0 0350234 9859 3 8991.3 142 95

106 0 0346877 9880 3 9003*9 143 15 107 0 0343585 9901 3 9016.5 143 34

108 0 0340356 9922 3 9029.1 143 54

109 0 0337187 9943 2 9041.7 143 73

110 0 0334078 9964 2 9054-3 143 92

111 0 0331026 9985 2 9066.9 144 11 112 0 0328029 10006 2 9079-5 1 44 30

113 0 0325088 10027 1 9092.0 144 49

114 0 0322199 10048 1 9104.6 144 67

115 0 0319361 10069 0 9117.2 144 85

116 0 0316574 10090 0 9129.8 145 04

117 0 0313835 10110 9 9142.3 145 22

118 0 0311143 10131 9 9154.9 145 39

119 0 0308498 10152 8 9167.5 145 57

120 0 0305898 10173 8 9180.0 145 75

121 0 0303342 10194 7 9192.6 145 92

122 0 0300828 10215 7 9205.2 146 09

123 0 0298356 10236 6 9217.7 146 26

124 0 0295925 10257 5 9230.3 146 43

125 0 0293534 10278 5 9242.9 146 60

126 0 0291181 10299 4 9255-4 146 77 127 0 0288865 10320 3 9268*0 146 93

128 0 0286587 10341 2 9280*5 147 10 129 0 0284345 10362 1 9293.1 147 26

130 0 0282137 10383 0 9305.6 147 42

131 0 0279964 10404 0 9318.2 147 58

132 0 0277824 10424 9 9330*7 147 74

133 0 0275710 10445 8 9343*3 147 90

134 0 0273642 10466 7 9355.8 148 05 135 0 0271599 10487 6 9368*3 148 21 136 0 0269585 10508 5 9380.9 148 36

137 0 0267602 10529 4 9393*4 148 52

138 0 0265648 10550 3 9406*0 148 67

139 0 0263722 10571 2 9418*5 148 82

140 0 0261824 10592 1 9431.0 148 97

141 0 0259953 10613 0 9443.6 149 12 142 0 0258110 10633 8 9456.1 149 27 143 0 0256292 10654 7 9468.6 149 41 144 0 0254500 10675 6 948 1 •

2

149 56

145 0 0252732 10696 5 9493*7 149 70

146 0 0250990 10717 4 9506.2 149 85

147 0 0249271 10738 3 9518*8 149 99

148 0 0247576 10759 1 9531*3 150 13 149 0 0245904 10780 0 9543*8 150 27

150 0 0244254 10800 9 9556*4 150 41

151 0 0242627 10821 8 9568.9 150 55 152 0 0241021 10842 6 9581.4 150 69

153 0 0239436 10863 5 9593.9 150 82

154 0 0237873 10884 4 9606.4 150 96

155 0 0236329 10905 2 9619.0 151 10 156 0 0234806 10926 1 9631*5 151 23

157 0 0233302 10947 0 9644.0 151 36

158 0 0231818 10967 8 9656.5 151 50

159 0 0230352 10988 7 9669.0 151 63

160 0 0228905 11009 6 9681*6 151 76

47
0.30 ATMOSPHERE isobar

TEMP.

K DENSITY

mol/liteh

enthalpy

J/MOL

internal

energy

J/mOL

ENTROPY

J/MCL-K

TEMP.

K DENSITY

mol/liter

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

161 0.0227476 11030.4 9694.1 151.89 231 0.0158359 12488.6 10569.0 159.41

162 0.0226064 11051.3 9706.6 152.02 232 0.01 57675 12509.4 10581.5 159.50

163 0.0224671 11072.1 9719.1 152.14 233 0.0156997 12530.2 10594.0 159.59

164 0.0223294 11093.0 9731.6 152.27 234 0.0156325 12551.1 10606.5 159.68

165 0.0221934 11113.8 9744.1 152.40 235 0.0155659 12571.9 10619.0 159.77

166 0.0220591 11134.7 9756.7 152.53 236 0.0154998 12592.7 10631.5 159.85

167 0.0219264 11155.5 9769.2 152.65 237 0.0154343 12613.5 10644.0 159.94

168 0.0217953 11176.4 9781.7 152.78 238 0*0153693 12634.3 10656.4 160.03

169 0.0216657 11197.2 9794.2 152*90 239 0.0153049 12655.1 10668.9 160.12

170 0.0215377 11218.1 9806.7 153.02 240 0.0152410 12675.9 10681.4 160.20

171 0.0214112 11238.9 9819.2 153.14 241 0.0151777 12696.7 10693.9 160.29

172 0.0212862 11259.8 9831.7 153.27 242 0.0151148 12717.5 10706.4 160.38

173 0.0211627 11280.6 9844.2 153.39 243 0.0150525 12738.4 10718.9 160.46

1 74 0,0210405 11301.

S

9856.7 153.51 244 0.0149907 12759.2 10731.4 160.55

175 0.0209198 11322.3 9869,2 153.63 245 0.0149295 12780.0 10743,8 160.63

176 0. 0208005 11343.2 98«1 .8 153.74 246 0.0148687 12800.8 10756.3 160.72

177 0.0206825 11364.0 9894.3 153.86 247 0.0148084 12821.6 10768.8 160.80

178 0.0205658 11384.9 9906.8 153.98 248 0.0147486 12842.4 10781.3 160.89

179 0. 0204505 11405.7 y919.3 154.10 249 0.0146893 12863.2 10793.8 160.97

180 0.0203365 11426.5 9931.8 154.21 250 0.0146304 12884.0 10806.3 161.05

181 0.0202237 11447.4 9944.3 154.33 251 0.0145720 12904.8 10818.8 161.14

182 0.0201122 11468.2 9956.8 154.44 252 0.0145141 12925.6 10831.2 161.22

183 0.0200019 11489.1 9969.3 154.56 253 0.0144567 12946.4 10843.7 161.30

184 0.0198926 11509.9 9981.8 154.67 254 0.0143997 12967.3 10856.2 161.38

185 0.0197849 11530.7 9994.3 154.78 255 0.0143431 12988.1 10868.7 161.47

1 86 0,0196781 11551.6 10006.8 154.90 ?56 0.0)42870 13008.9 10881.2 lfel.55 187 0.0195725 11572.4 10019.3 155.01 257 0.0142314 13029.7 108Q3.7 161.63

188 0.0194681 11593.2 10031.8 155.12 258 0. 0141761 13050.5 10906.2 161.71

189 0.0193647 11614.1 10044.3 155.23 259 0.0141213 13071.3 10918.6 161.79

190 0.0192625 11634.9 10056.8 155.34 260 0.0140669 13092.1 10931.1 161.87

191 0.0191613 11655.7 100t>9.3 155.45 261 0.0140130 13112.9 10943.6 161.95

192 0.0190612 11676.6 10081 .8 155.56 262 0.0139594 13133.7 10956.1 162.03

193 0.0189621 11697.4 10094*3 155.67 263 0-0139062 13154.5 10968.6 162.11

104 0.01&8641 11718-2 10106.8 155.77 264 0*0 138535 13175.3 10981.1 162.19

195 0.0187671 11739-1 10119.3 155-88 265 0*0138012 13196.1 10993*5 162*27

196 0*0186710 11759*9 10131*8 155*99 266 0*0137492 13216*9 11006*0 162*34

197 0*0185760 11780*7 10144*3 156.09 267 0*0136977 13237*7 11018*

5

162*42

198 0.0184819 11801*

5

10156*8 156*20 268 0*0136465 13258.5 11031*0 162*50

199 0.0183887 11822-4 10169.3 156.30 269 0*0)35957 13279.3 11043-5 162*58

200 0.0182965 11843.2 10181.8 156.41 270 0.0135453 13300*2 11055.9 162.65

201 0.0182053 11664.0 10194.3 156.51 271 0.0134952 13321.0 11068.4 162.73

202 0.0161149 11884.9 10206.8 156.62 272 0.0134456 13341 . ft 11080.9 162.81

203 0.0180254 11905.7 10219.3 156.72 273 0.0133962 13362.6 11093.4 162.98

204 0.0179368 11926-5 10231.8 156-82 274 0*0133473 13383*4 11105*9 162*96

205 0.0178491 11947*3 10244.3 156*92 275 0*0132987 13404.2 11118.4 163*04

206 0.0177622 11968.2 10256.8 157.02 276 0.0132505 13425.0 11130.8 163.11

207 0.0176762 11989.0 10269.2 157.12 277 0.0132026 13445.8 11143.3 163.19

20fl 0.0175910 12009.8 10281.7 157.22 278 0,0131550 13466.6 11155.8 163.26

209 0.0175066 12030.6 10294.2 157.32 279 0.0131078 13487.4 11168.3 163.34

210 0,0174230 12051 .4 10306.7 157. *2 280 0.0130610 13508.2 11180.8 163.41

211 0.0173403 12072.3 10319.2 157.52 281 0.0130144 13529.0 11193.3 163.49

212 0.0172583 12093-1 10331*7 157*62 282 0*0129682 13549.8 11205*7 163.56

213 0.0171771 12113.9 10344.2 157.72 283 0.0129224 13570.6 11218.2 163.63

214 0*0170966 12134.7 10356.7 157*62 284 0*0128768 13591.4 11230*7 163-71

215 0-0170169 12155*5 10369*2 157*91 285 0*0 128316 13612*2 11243*2 163*78

216 0.0169380 12176.4 10381*7 158.01 286 0*0127867 13633*0 11255*7 163*85

217 0.0168597 12197.2 10394.2 158.11 287 0-0127421 13653.8 11268-1 163*92

218 0.0167822 12218.0 10406.7 158.20 288 0.0126978 13674.6 11280.6 164.00

219 0,0167054 12238.8 10419.2 15R.30 289 0.0126538 13695.4 11293.1 164.07

220 0.0166293 12259.6 10431.6 158.39 290 0.0126101 13716.2 11305.6 164.14

221 0.0165539 1 2 2 8 u • 5 10444.1 158.49 291 0.0125668 13737.0 11318.1 164.21

22? 0.0164792 12301.3 10456.6 158.58 292 0.0)25237 13757.8 11330,5 164.28

223 0,0164051 12322.1 10469.1 158.67 293 0.0124809 13778.6 11343.0 164.36

224 0.0163317 12342.9 10481.6 158.77 294 0.0124384 13799.4 11355.5 164.43

225 0.0162590 12363.7 10494.1 158.86 295 0.0123962 13820.2 11368.0 164.50

226 0.0161869 12384.5 10506*6 15R.95 296 0.0123543 13841.0 11380*5 164.57

227 0.0161155 12405.4 10519.1 159.04 297 0.0123126 13861.8 11392.9 164.64

228 0.0160447 12426,2 10531.6 159.14 298 0.0122713 13882.6 11405.4 164.71

229 0-0)59745 12447.0 10544.1 159.23 299 0.0122302 13903.4 11417.9 164.78

230 0.0159049 12467.8 10556.5 159.32 300 0.0121894 13924.2 11430.4 164.85

48
0.40 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER j/mol energy J/MOL-K

J/MOL

86 0.0574500 9453.3 8747.8 136.31

87 0.0567671 9474.5 8760.5 136.55

88 0.0560999 9495.6 8773.1 136.80

89 0.0554465 9516.0 8785.8 137.03

90 0,05*6124 9537.9 8798,5 137.27

TEMP.

K DENSITYMOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

j/mol-k

91 0.0541910 9559.1 8811.2 137.51

92 0.0535838 9580*2 8823*8 137.74

93 0.0529904 9601.4 8836.5 137.96

94 0.0524103 9622.5 8849.2 138.19

95 0*0518430 9643*6 8861*8 138*41

96 0*0512880 9664*8 8874*5 1 38*64

97 0*0507451 9685*9 8887*2 138.85

98 0*0502137 9707*0 8899*8 139*07

99 0*0496936 9728*1 8912*5 139*29

100 0.0491843 9749.2 8925.1 139.50

101 0.0486856 9770.3 8937.8 139.71

102 0*0481970 9791 .4 8950*4 139.91

103 0.0477183 9812.5 8963.1 140.12

104 0.0472492 9833.5 8975.7 140.32

105 0.0467894 9854.6 8988.4 140.33

106 0 , 0463386 9875.7 9001.0 140.73

107 0.0458965 9896.7 9013.6 140.92

108 0.0454629 9917.8 9026.3 141.12

109 0.0450376 9938.8 9038.9 141.31

110 0*0446203 9959.9 9051 *5 141*51

111 0.0442107 9980.9 9064.1 141.70

112 0.0438087 10001.9 9076.8 141.88

113 0.0434141 10023*0 9089*4 142*07

114 0*0430265 10044*0 9102*0 142*26

115 0*0426460 10065*0 9114*6 142*44

116 0.0422722 10086.0 9127.2 142.62

117 0.0419050 10107.0 9139.8 142.80

118 0*0415442 10128*0 9152*4 142*98

119 0*0411896 10149*0 9165*0 143*16

120 0*0408411 10170*0 9177*6 143*33

121 0.0404986 10191.0 9190.2 143.51

122 0.0401618 10212*0 9202*8 143.68

123 0*0398306 10233*0 9215*4 143.85

124 0*0395049 10254*6 9228*0 144.02

125 0*0391845 10274.9 9240*6 144.19

126 0*0388694 10295*9 9253*2 144.36

127 0*0385593 10316*9 9265*7 144*52

128 0*0382542 10337*8 9278*3 144.69

129 0.0379539 10358.8 9290.9 144.85

130 0.0376584 10379.8 9303.5 145.01

131 0.0373674 10400.7 9316.1 145.17

132 0*0370810 10421.7 9328.6 145.33

133 0.0367990 10442.6 9341.2 145.49

134 0.0365213 10463.6 9353.8 145.65

135 0,0362477 10484,5 9366.3 145.80

136 0.0359783 10505.4 9378.9 145.96

137 0*0357129 10526.4 9391.5 146.11

138 0*0354514 10547.3 9404.0 146.26

139 0.0351938 10568.2 9416.6 146.41

140 0.0349398 10589.2 9429.1 146.56

141 0.0346896 10610.1 9441.7 146.71

14? 0.0344430 10631.0 9454.3 146.86

143 0.0341998 10651.9 9466.8 147.01

144 0.0339601 10672.9 9479.4 147.15

145 0.033723s 10693.8 9491.9 147.30

146 0.0334907 10714.7 9504.5 147.44

147 0*0332609 10735.6 9517*0 147.59

148 0*0330342 10756*5 9529*6 147*73

149 0.0328106 10777.4 9542.1 147.87

150 0.0325901 10798.3 9554.7 148.01

151 0.0323725 10819.2 9567.2 148.15

152 0*0321578 10840.1 9579.7 148.28

153 0.0319460 10861.0 9592.3 148.42

154 0.0317369 10881,9 9604.8 148.56

155 0.0315306 10902.8 9617.4 148.69

156 0.0313270 10923.7 9629.9 148.83

157 0.0311260 10944.6 9642.4 140.96

158 0.0309276 10965.5 9655.0 149.09

159 0.0307317 10986.4 9667.5 149,23

160 0.0305383 11007.3 9680.0 149.36

49
0.40 ATMOSPHERE isobar

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

internal

energy

J/MOL

entropy

J/MOL-K

TEMP.

K DENSITY

MOL/L I TER ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

161 0.0303473 11028.1 9692.6 149.49 231 0 0211182 12487.4 10568.2 157.01

162 0.0301587 11049.0 9705*1 149*62 2 72 0 0210270 12508.2 10580*7 157*10

163 0.0299724 11069.9 9717.6 149.74 233 0 0209365 12529.1 10593.2 157.19

164 0.0297885 11090.8 9730.2 149.87 234 0 0208468 12549.9 10605.6 157.28

16S 0.029&Q68 11111.7 9742.7 150.00 275 0 0207579 12570.7 10618.1 157.37

166 0.0294273 11132*5 9755.2 150*12 236 0 0206698 12591 .5 10630*6 157.46

167 0.0292500 11153.4 9767.7 150.25 237 0 0205823 12612.3 10643.1 157.55

168 0.0290749 11174.3 9780.3 150.37 238 0 020^957 12633.2 10655.6 157.63

169 0.0289018 11195.2 9792.8 150.50 239 0 0204097 12654.0 10668.1 157.72

170 0.0287308 11216.0 9805.3 150.62 240 0 C203245 12674.8 10680.6 157.81

171 0.0285618 11236.9 9817.8 150.74 241 0 0202399 12695.6 10693.1 157.90

172 0.0283948 11257.8 9630 •

4

150*87 242 0 0201561 12716.4 10705.6 157.98

173 0.0282297 1 1278.6 9842.9 150.99 243 0 0200730 12737.3 10718.1 158.07

174 0.0280666 11299.5 9855.4 151.11 244 0 0199906 12758.1 10730.6 158.15

175 0.0279053 11320.4 9867.9 151.23 2A5 0 0199088 12778.9 10743.1 158.24

176 0.0277459 11341,2 9880.4 151.35 246 0 0198277 12799.7 10755.5 158.32

177 0.0275884 11362.1 9893.0 151.46 247 0 0197472 12820.5 10768.0 158.41

178 0.0274326 11383.0 9905.5 151.58 248 0 0196675 12841.4 10780.5 158.49

179 0.0272785 11403.8 9918.0 151.70 249 0 0195883 12862.2 10793.0 158.57

1 80 0.0271262 11424.7 9930.5 151.81 250 0 0195098 12883.0 10805.5 158.66

181 0.0269756 11445.5 9943.0 151,93 251 0 0194319 12903.8 10818.0 158.74

182 0.0268267 11466*4 9955*5 152*04 252 0 0193547 12924.6 10830*5 158.82

183 0*0266794 11487*2 9968*0 152*16 253 0 0192780 12945*4 10843*0 158*91

184 0.0265337 11508.1 9980*6 152*27 254 0 0192020 12966.2 10855.5 158.99

185 0*0263896 11529.0 9993*1 152*39 255 0 0191265 12987*1 10868*0 159.07

186 0.0262471 11549.8 10005.6 152.50 256 0 0190517 13007.9 10880.4 159.15

187 0.0261061 1 1570.

7

10018.1 152.61 257 0 0ie9774 13028.7 10892.9 159.23

188 0.0259666 11591.5 10030.6 152.72 258 0 0189037 13049.5 10905.4 159.31

189 0.0258286 11612.4 10043.1 152.83 259 0 0188306 13070.3 10917.9 159,39

190 0.0256921 11633,2 10055.6 152.94 260 0 0187580 13091.1 10930.4 159.47

191 0.0255570 11654.1 10068.1 153.05 261 0 0186860 13111.9 10942.9 159.55

192 0.0254233 11674.9 10080.6 153.16 262 0 0186146 13132.8 10955.4 159.63

193 0.0252910 11695.7 10093.2 153.27 263 0 0185437 13153.6 10967.9 159.71

194 0.0251601 11716.6 10105.7 153.38 264 0 0184733 13174.4 10980.3 159.79

195 0.0250306 11737.4 10118.2 153.48 265 0 0184035 13195.2 10992.8 159.87

196 0 .0249024 11758.3 10130.7 153.59 266 0 0183342 13216.0 11005.3 159.95

197 0.0247755 11779.1 10143.2 153.70 267 0 0182654 13236.8 11017.8 160.03

198 0.0246498 11800*0 10155.7 153.80 268 0 0181971 13257.6 11030.3 160.11

199 0.0245255 11820.8 10168.2 153.91 269 0 0181294 13278.4 11042.8 160.18

200 0 .0244024 11841.7 10180*7 154.01 270 0 0180621 13299.2 11055*3 160.26

201 0.0242806 11862.5 10193.2 154.11 271 0 0179954 13320.1 11067.8 160.34

202 0.0241599 11883.3 10205.7 154.22 272 0 0179291 13340.9 11080.2 160.41

203 0 • 0?40405 11904.2 10218*2 154.32 273 0 0178633 13361.7 11092.7 160.49

204 0*0239222 11925*0 10230*7 154*42 274 0 0177980 13382*5 11105*2 160*57

205 0*0238051 11945.8 10243.2 154.53 275 0 0177332 13403*3 11117.7 160*64

206 0.0236892 11966.7 10255.7 154.63 276 0 0176689 13424.1 11130.2 160.72

207 0.023574

3

11987.5 10268.2 154,73 277 0 0176050 13444,9 11142,7 160.79

208 0.0234606 12008.4 10280.7 154.63 278 0 0175416 13465.7 11155.2 160.87

209 0.0233480 12029*2 10293.2 154.93 279 0 0174786 13486.5 11167.6 160.94

210 0.0232364 12050*0 10305*7 155*03 280 0 0174161 13507*3 11180.1 161*02

211 0.0231259 12070.9 10318.2 155.13 281 0 0173540 13528.2 11192.6 161.09

212 0-0230165 12091.7 10330.7 155.23 282 0 0172924 13549.0 11205.1 161.17

213 0.0229081 12112.5 10343*2 155.32 283 0 0172312 13569.fi 11217.6 161*24

214 0.0228007 12133.4 10355.7 155.42 284 0 0171704 13590.6 11230*1 161.31

215 0.0226944 12154.2 10368.2 155.52 285 0 0171101 13611.4 11242.5 161.39

216 0.0225890 12] 75.0 10380.7 155.61 286 0 0170502 13632.2 11255.0 161.46

217 0.0224846 12195.8 10393.2 155.71 287 0 0169907 13653.0 11267.5 161.53

218 0.0223811 12216.7 10405.7 155.81 288 0 0169316 13673.8 11280.0 161.60

219 0.0222786 12237.5 10418.2 155.90 289 0 0168730 13694.6 11292,5 161.68

220 0.0221771 12258.3 10430.7 156.00 290 0 0163147 13715.4 11305.0 161.75

221 0.0220764 12279.2 10443.2 156.09 291 0 0167569 13736.2 11317.4 161.82

222 0.0219767 12300*0 10455.7 156-19 29? 0 0166994 13757.0 11329.9 161.89

223 0*0218779 12320*8 10468*2 156.28 293 0 0166423 13777.8 11342.4 161*96

224 0*0217799 12341*6 10480*7 156.37 294 0 0165856 13798.6 11354*9 162*03

225 0.0216829 12362.5 10493*2 156.46 295 0 0165294 13819.4 11367.4 162.10

226 0*0215867 12383.3 10505.7 156*56 296 0 0164734 13840*3 11379*9 162*17

227 0.0214913 12404.1 10518.2 156.65 297 0 0164179 13861.1 11392.3 162.24

228 0.0213968 12424.9 10530.7 156.74 298 0 0163627 13881.9 11404.8 162.31

229 0.0213032 12445.8 10543.2 156.83 299 0 0163080 13902.7 11417-3 162.38

230 0.0212103 12466*6 10555*7 156.92 300 0 0162535 13923*5 11429.8 162*45

50
0.50 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

86 0.0720617 9446.9 8743.8 134

87 0.0711964 9468.2 8756.6 134

88 0.0703522 9489.4 8769.3 134

H9 0*0695283 9510.7 8782.0 135

90 0.0687241 9532.0 8794.7 135

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

91 0.0679387 9553.2 8807.5 135.61

92 0.0671716 9574,4 8820.2 135.84

93 0.0664220 9595.7 8832.9 136.07

94 0.0656894 9616.9 8845.6 136.30

95 0.0649733 9638.1 8858.4 136.52

96 0.0642729 9659.3 8871.1 136,74

97 0.0635879 9680.5 8883.8 136.96

98 0*0629176 9701*7 8896*5 137*18

99 0.0622617 9722.9 8909*2 137.40

100 0*0616196 9744.

1

8921*9 137*61

101 0. 0609909 9765.3 8934.6 137.82

102 0*0603752 9786,4 8947*3 138.03

103 0*0597721 9807*6 8960*0 138.24

104 0*0591812 9828*8 8972*7 138*44

105 0*0586021 9849*9 8985*4 138*64

106 0 • 0580344 9871*0 8998*0 138*84

107 0.0574779 9892.2 9010*7 139.04

108 0*0569321 9913*3 9023*4 139*24

109 0*0563968 9934*4 9036*1 139.43

110 0*0558717 9955*5 90A8.7 139*62

111 0.0553564 9976.6 9061,4 139.82

112 0.0548507 9997.7 9074.0 140.00

113 0.0543544 10018.8 9086.7 140.19

114 0.0538671 10039.9 9099.3 140.38

115 0.0533886 10061.0 9112.0 140,56

116 0.0529187 10082.0 9124.6 140.74

117 0.0524571 10103.1 9137.3 I 4 O .93

118 0.0520036 10124.2 9149.9 141.10

119 0.0515581 10145.2 9162.6 141,28

120 0.0511202 10166.3 9175.2 141.46

121 0.0506898 10187.3 9187.8 141.63

122 0,0502667 10208,3 9200,4 141.81

123 0.0498507 10229.4 9213.1 141.98

124 0.0494416 10250.4 9225.7 142.15

125 0.0490393 10271.4 9238.3 142.32

126 0.0486435 10292*4 9250*9 142*48

127 0*0482542 10313*5 9263*5 142*65

128 0*0478712 10334*5 9276*1 142*82

129 0.0474942 10355.5 9288.7 142.98

130 0.0471233 10376.5 9301.3 143.14

131 0.0467581 10397.5 9313.9 143.30

132 0*0463987 10418.5 9326.5 143.46

133 0*0460447 10439*5 9339*1 143.62

134 0*0456962 10460*4 9351*7 143*78

135 0*0453530 10481.4 9364*3 143*93

136 0*0450150 10502*4 9376*9 144*09

137 0.0446821 10523.4 9389.5 144*24

138 0 * 0443540 10544.3 9402*1 144*39

139 0*0440309 10565*3 9414*7 144*55

1 40 0*0437124 10586*3 9427*3 144*70

141 0.0433985 10607.2 9439.8 144.84

142 0*0430892 10628*2 9452*4 144.99

143 0*0427843 10649*2 9465*0 145*14

144 0*0424838 10670*1 9477*6 145*29

145 0*0421874 10691 •

1

9490*1 145*43

146 0*0418952 10712*0 9502*7 145*58

147 0.0416071 10732*9 9515*3 145*72

148 0*0413229 10753*9 9527*8 145*86

1 49 0*0410426 10774*8 9540*4 146*00

150 0*0407662 10795*7 9553*0 146*14

151 0.0404934 10816.7 9565.5 146.28

1 52 0.0402244 10837.6 9578.1 146.42

153 0.0399589 10858*5 9590*6 146.56

154 0*0396969 10879.5 9603*2 148.69

155 0*0394383 10900*4 9615*7 146*83

156 0.0391832 10921*3 9628.3 146*96

157 0*0389313 10942*2 9640*9 147*10

158 0*0386827 10963*1 9653*4 147.23

159 0*0384372 10984.0 9666 •

0

147*36

160 0*0381949 11005.0 9678.5 147.49

51
161 162

163

164

165

166

167

168

169

170

171 172 173

174

175

176

177

178

179

180

181 182

183

184

1P5

186

187

188

1 89

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211 212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

0.50 atmosphere ISOBAR

DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

MOL/LITER

enthalpy

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

J/MOL-K

0.0379556 11025.9 9691.1 147.62 231 0.0264025 12486.2 10567.3 155.15

0.0377194 11046.8 9703.6 147.75 232 0.0262883 12507.0 10579.8 155.24

0.0374860 11067.7 9716.1 147.88 233 0.0261751 12527.9 10592.3 155.33

0.0372556 11088.6 9728.7 148.01 234 0.0260630 12548.7 10604.8 155.42

0.0370280 11109.5 9741 .2 148.13 235 0*0259517 12569.5 10617.3 155.51

0.0368032 11130.4 9753.8 148.26 236 0.0258414 12590.4 10629.8 155.60

0.036581 1 11151.3 9766.3 148.39 237 0.0257321 12611.2 10642.3 155.69

0.036361 7 11172.2 9778.8 148.51 238 0.0256236 12632.0 10654.8 155.78

0.0361449 11193.1 9791.4 148.63 239 0.0255161 12652.9 10667.3 155.86

0.035930 7 11214.0 9803.9 148.76 240 0.0254095 12673.7 10679.8 155.95

0.0367191 11234.9 9816.5 148.88 241 0.0253038 12694.5 10692.3 156.04

0.0355100 11255.7 9829.0 149.00 242 0.0251989 12715.3 10704.8 156.12

0,0353032 11276.6 9841.5 149.12 243 0.0250949 12736.2 10717.3 156.21

0,0350990 11297.5 9854.1 149.24 244 0.0249918 12757.0 10729.8 156.29

0 .0348970 11318.4 9866.6 149.36 245 0.0248895 12777.8 10742.3 156.38

0.0346974 11339.3 9879.1 149.48 246 0.0247881 12798.6 10754.8 156.46

0.0345001 11360*2 9891.7 149*60 247 0*0246875 12819.5 10767.3 156.55

0 . 03^3050 11381*0 9904.2 149.72 248 0 • 0245877 12840.3 10779*8 156.63

0.03*1121 11401*9 9916*7 149*84 249 0.0244887 12861*1 10792*2 156.72

0.0339214 11422.8 9929.2 149.95 250 0.0243905 12881.9 10804.7 156.80

0.0337329 11443.7 9941 .8 150.07 251 0.0242931 12902.8 108)7.2 156.88

0.0335464 11464.6 9954.3 150*18 252 0.0241964 12923.6 10829.7 156.97

0.0333620 11485*4 9966.8 150*30 253 0*0241006 12944.4 10842*2 157.05

0.0331796 11506.3 9979.3 150.41 254 0.0240054 12965.2 10854.7 157.13

0.0329992 11527.2 9991.9 150.52 255 0.0239111 12986.1 10867.2 157.21

0.0328207 11548.0 10004.4 150.64 256 0.0238175 13006.9 10879.7 157.29

0.0326442 1 1568.9 10016.9 150.75 257 0.0237246 13027.7 10092.2 157,38

0.0324696 11589.8 10029.4 150.86 258 0.0236324 13048.5 10904,7 157.46

0.0322969 11610.6 10041.9 150.97 259 0.0235409 13069.3 10 9 17.? 157,54

0.0321260 11631,5 10054.5 151.08 260 0.023450? 13090.2 10929.7 157.62

0.0319569 11652.4 10067.0 151.19 261 0.0233602 13111.0 10942.2 157.70

0.0317896 11673.2 10079.5 151.30 262 0*0232708 13131.8 10954.7 157.78

0.0316240 11694.1 10092.0 151.41 263 0*0231821 13152*6 10967*1 157.86

0*0314602 11715*0 10104*5 151*51 264 0*0230941 13173*4 10979*6 157.93

0*0312980 11735*8 10117*1 151 *62 265 0*0230068 13194.3 10992*1 158.01

0.0311375 11756.7 10129.6 151.73 266 0.0229201 13215.1 11004.6 158.09

0.0309787 11777.5 10142.1 151.84 267 0.0228341 13235.9 11017.1 158.17

0.0308215 11798.4 10154.6 151.94 268 0.0227487 13256.7 11029.6 158.25

0.0706659 11819.2 10167.1 152.05 269 0.0226640 13277.5 11042.1 188.33

0.0305118 11840.1 10179.6 152.15 270 0.0225799 13298.3 11054.6 158.40

0.0303593 1 1860.9 10192.1 152.25 271 0.0224964 13319.2 11067.1 158.48

0.0302083 11681.8 10204.7 152.36 272 0.0224135 13340.0 11079.6 188.56

0.0300588 11902.7 10217.2 152.46 273 0.0223312 13360.8 11092.0 158.63

0.0299108 11923.5 10229.7 152.56 274 0.0222496 13381.6 11104.5 158.71

0. 0297643 11944.4 10242.2 152.67 275 0.0221685 13402.4 11117.0 158.78

0*0796192 11965*2 10254*7 152*77 276 0*0220880 13423*2 11129*5 15e*86

0*0294755 11986*1 10267*2 152*87 277 0*0220082 1 3444.1 11142*0 158.94

0.0-593332 12006.9 10279.7 152.97 278 0.0219288 13464.9 11154.5 159.01

0.0291922 12027.7 10292.2 153.07 279 0.0218501 13485.7 11167.0 159.08

0.0290527 12048.6 10304.7 153.17 280 0.0217719 13506,5 11179.5 159. 16 0.0789144 12069,4 10317.2 153.27 2«1 0.0216943 13527.3 11192.0 159.23

0.0287775 12090*3 10329*7 153*37 282 0*0216172 13548.1 11204.4 159.31

0.0?8641B 12111.1 10342.3 153.46 283 0.0215407 13568.9 11216.9 159.38

0 ,0785075 12132.0 10354.8 153.56 284 0.0214647 13589.8 11229.4 159.45

0.0283744 12152.8 10367.3 153.66 285 0.0213893 136)0.6 11241.9 159.53

0.0282428 121 73.7 10379.8 153*75 286 0.0213144 13631.4 11254.4 159.60

0.0781119 12194.5 10392*3 153*85 287 0*0212400 13652.2 11266*9 189.67

0. 0279824 12215.3 10404*8 153*95 288 0*0211661 1 3673*0 11279.4 159.75

0*0778542 12236*2 10^17*3 154*04 289 0*0210927 13693*8 11291.9 159.82

0.0777271 12257.0 10429.8 154.14 290 0.0210199 13714.6 11304.3 159.89

0.0776012 12277.9 10442.3 154.23 291 0.0209475 13735.4 11316.8 159.96

0.0274765 12298.7 10454.8 154.33 292 0*0208757 13756.3 11329.3 160.03

0.0273528 12319.5 10467.3 154.42 293 0.0208043 13777.1 11341.8 160.10

0.02 72303 12340.4 10479.8 154.51 294 0.0207335 13797.9 11354.3 160.17

0.0?710r9 12361 .2 10492.3 154.61 295 0.0206631 13818.7 11366.8 160.25

0.0269385 12382.0 10504.8 154.70 296 0.0205931 13839.5 11379.3 160.32

0.0768692 12402.9 10517.3 154.79 ?97 0.0205237 13860.3 11391.7 160.39

0.0767510 12423.7 10529.8 154. b8 298 0.0204547 13881.1 11404.2 160.46

0.0766333 12444.5 10542.3 154.97 299 0.0203862 13901 .9 11416.7 160.53

0.0765176 12465.4 10554.8 155.06 300 0.0203182 13922.7 11429.2 160.60

52
0,60 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY j/mol-k

J/MOL

86 0.0867764 9440.4 8739.8 132.84

87 0.0857248 9461.8 8752.6 133.09

88 0.0846992 9483.2 8765.4 133.34

89 0.0836988 9504.6 8778.2 133.58

90 0.0827225 9525.9 8791.0 133.82

temp.

K DENSITY

mol/liter

ENTHALPY

J/MOL

INTERNAL ENERGY

J/MOL

entropy

J/MOL-K

91 0.0817694 9547.3 8803.8 134.05

92 0.0808388 9568.6 8816.5 134.29

93 0.0799298 9589.9 8829.3 134.52

94 0.0790416 9611.3 8842.1 134.74

95 0.0781736 9632.6 8854.9 134.97

96 0-0773250 9653.9 8867.6 135*19

97 0.0764952 9675.2 8880.4 135.41

98 0.0756835 9696.5 8893.2 135-63

99 0.0748893 9717.7 8905.9 135.85

100 0.0741121 9739.0 8918.7 136.06

101 0.0733513 9760.2 8931.4 136.27

102 0.0726064 9781*5 8944*1 136.48

103 0.0718769 9802.7 8956.9 136.69

104 0.0711622 9824.0 8969.6 136.89

105 0.0704620 9845.2 8982.3 137.10

106 0.0697758 9866*4 8995* 1 137*30

107 0.0691031 9887.6 9007-8 137.50

1 08 0.0684436 9908.8 9020.5 137.69

109 0.0677968 9930.0 9033.2 137.89

110 0.0671624 9951.1 9045.9 138.08

111 0.0665401 9972.3 9058.6 138.27

112 0.0659294 9993.5 9071.3 138.46

113 0.0653301 10014.6 9084.0 138.65

114 0.0647418 10035.8 9096.7 138.84

115 0.0641642 10056.9 9109.4 139.02

116 0.0635971 10078.0 9122.1 139.21

117 0.0630401 10099.2 9134.7 139.39

118 0.0624929 10120.3 9147.4 139.57

119 0.0619553 10141 ,4 9160.1 139.75

120 0.0614271 10162.5 9172.7 139.92

121 0.0609080 10183.6 9185.4 140,10

122 0.0603977 10204,7 9198.1 140.27

123 0.0598961 10225.8 9210.7 140.44

124 0.0594028 10246.8 9223.4 140.61

125 0.0589178 10267.9 9236.0 140.78

126 0.0584407 10289.0 9248.7 140,95

127 0.0579715 10310.0 9261.3 141.12

128 0.0575098 10331.1 9273,9 141.28

129 0.0570555 10352.1 9286.6 HI. 45

130 0.0566085 10373.2 9299.2 141.61

131 0.0561685 10394.2 9311.8 141.77

132 0*0557354 10415*3 9324.4 141*93

133 0.0553091 10436.3 9337.1 142.09

134 0.0548893 10457.3 9349.7 142.25

135 0.0544759 10478.3 9362.3 142.40

136 0.0540688 10499.4 9374.9 142.56

137 0.0536678 10520.4 9387.5 142.71

138 0*0532727 10541.4 9400*1 142.86

139 0-0528836 10562.4 9412.7 143.02

140 0.0525001 10583*4 9425.3 143.17

141 0.0521222 10604.4 9437.9 143.32

142 0.0517498 10625.4 9450.5 143.46

143 0.0513828 10646.4 9463.1 143.61

144 0.0510210 10667.3 9475.7 H3.76

145 0*0506643 10688.3 9488*3 143.90

146 0*0503126 10709.3 9500*9 144*05

147 0*0499658 10730.3 9513.5 144.19

148 0*0496238 10751*2 9526*1 144*33

149 0.0492865 10772.2 9538.7 144.47

150 0,0489538 10793.2 9551.3 144.61

151 0.0486256 10814.1 9563.8 144.75

152 0.0483019 10835.1 9576.4 144.89

153 0,0479824 10856.1 9589.0 145.03

154 0.0476672 10877.0 9601.6 U5.17

155 0.0473562 10898.0 9614.1 145.30

156 0,0470492 10918.9 9626.7 145,44

157 0.0467462 10939.8 9639.3 145.57

158 0.0464471 10960.8 9651.8 145.70

159 0*0461519 10981.7 9664.4 145.83

160 0.0458604 11002.7 9677.0 145.97

53
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201 202

203

204

205

206

207

208

209

210

211 212

213

214

2]5

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

0.60 ATMOSPHERE ISOBAR

DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITYmol/liter

ENTHALPY

J/MOL

INTERNAL ENERGY

J/MOL

entropy

J/MOL-K

0.0455727 11023.6 9689.5 146.10 231 0.0316886 12485.0 10566.4 153.63

0.0452885 11044.5 9702.1 146.23 232 0.0315515 12505.9 10578.9 153.72

0.0450079 11065.5 9714.7 146.35 233 0.0314156 12526.7 10591.5 153.81

0.0447308 11086.4 9727.2 146.48 234 0.0312808 12547.5 10604.0 153.90

0.0444571 11107.3 9739.8 146.61 235 0.0311472 12568.4 10616.5 153.99

0.0441867 11128.2 9752.3 146.74 236 0.0310148 12589.2 10629.0 154.08

0.0439197 11149.1 9764.9 146.86 237 0.0308835 12610.0 10641.5 154.17

0.0436558 11170.1 9777.4 146.99 238 0.0307532 12630.9 10654.0 154.26

0.0433952 11191.0 9790.0 147.11 239 0.0306241 12651.7 10666,5 154.34

0.0431377 11211.9 9802.5 147.23 240 0.0304961 12672.6 10679.0 154.43

0.0428832 11232.8 9815.1 147.36 241 0.0303691 12693.4 10691 .5 154.52

0.0426317 11253.7 9827.6 147.48 242 0.0302432 12714.2 10704.0 154.60

0.0423832 11274.6 98*0*2 147.60 243 0.0301184 12735*1 10716*5 154.69

0.0421376 11295.5 9852.7 147.72 244 0.0299945 12755.9 10729.0 154.78

0.0418949 11316.4 9865.3 147.84 245 0.0298717 12776.7 10741.5 154.86

0.0416549 11337.3 9877.8 147.96 246 0.0297499 12797.6 10754.0 154.95

0.0414177 11358.2 9890.3 148.08 247 0.0296291 12818.4 10766.5 155.03

0.0411832 11379.1 9902.9 148.20 248 0.0295092 12839.2 10779.0 155.11

0.0409514 11400.0 9915.4 148.31 249 0.0293904 12860.1 10791.5 155.20

0.0407221 11420.9 9928.0 148.43 250 0.0292724 12880.9 10804.0 155.28

0.0404955 11441.8 9940.5 148.54 251 0.0291555 12901.7 10816.5 155.36

0.0402714 11462.7 9953.0 148.66 252 0.0290394 12922.6 10829.0 155.45

0.0400497 11483.6 9965.6 148.77 253 0.0289243 12943.4 10841.5 155.53

0.0398305 11504.5 9978.1 148.89 254 0.0288101 12964.2 10854.0 155.61

0.0396137 11525.4 9990.6 149.00 255 0.0286968 12985.1 10866.5 155.69

0.0393992 11546.3 10003.2 149.11 256 0.0285844 13005.9 10879.0 155.78

0,03^1871 11567.2 10015.7 149.23 257 0.0284729 13026.7 10891.5 155.86

0.0389773 1)588.0 10028.2 149.34 258 0.0283622 13047.5 10904.0 155,94

0.0387697 11608.9 10040.8 149.45 259 0.0282524 13068,* 10916.5 156.02

0.0385643 11629.8 10053.3 149.56 260 0*0281434 13089.2 10928.9 156.10

0.0383611 11650.7 10065.8 149.67 261 0.0280353 13110.0 10941.4 156.18

0.0381600 11671.6 10078.4 149.78 262 0.0279280 13130.8 10953.9 156.26

0.0379611 11692.4 10090.9 149.89 263 0.0278216 13151.7 10966.4 156.34

0.0377642 11713.3 10103.4 149.99 264 0.0277159 13172.5 10978.9 156.42

0.0375694 11734.2 10115.9 150-10 265 0.0276111 13193.3 10991.* 156.49

0.0373765 11755*1 10128*5 150*21 266 0*0275070 132140 11003*9 156.57

0.0371857 11775.9 10141.0 150*31 267 0*0274037 13235.0 11016*4 156*65

0.0369963 11796.8 10153.5 150*42 268 0*0273012 13255.8 11028.9 156.73

0.0368098 11817.7 10166.0 150.52 269 0.0271995 13276.6 11041.4 156.91

0.0366247 11838.5 10178.6 150.63 270 0.0270985 13297.4 11053.9 156.88

0.0364415 11859.4 10191.1 150.73 271 0.0269982 13318.3 11066.4 156.96

0.0362601 11880.3 10203.6 150.84 272 0.0268988 13339.1 11078.9 157.04

0.0360805 11901.1 10216.1 150*94 273 0-0268000 13359.0 11091 .* 157.11

0.0359027 11922.0 10228.6 151.04 274 0.0267020 13380.7 11103.9 157.19

0.0357267 1 1942.9 10241.2 151.14 275 0.0266046 13401.6 11116.4 157.27

0.0355523 11963.7 10253.7 151.25 276 0.0265080 13422.4 11128.9 157.34

0.0353797 11984.6 10266.2 151.35 277 0.0264121 13443.2 111*1.3 157.42

0.0352087 12005*5 102T8.7 151*45 278 0.0263169 13*64.0 11153.8 157.49

0.0350394 12026.3 10291.2 151.55 279 0.0262224 13484.8 11166.3 157.57

0.0348718 12047.2 10303.7 151.65 280 0.0261285 13505.7 11178.8 157.64

0.0347057 12068.0 10316.2 151.75 281 0 , 026C353 13526.5 11191.3 157.72

0.0345412 12088.9 1032B.8 151.8* 282 0. 02594?p 13547.3 11203.8 157.79

0*0343783 12109*7 103*1*3 151*94 283 0*0258509 135680 11216*3 197*86

0.0342169 12130.6 10353.8 152.04 284 0.0257597 13588.9 11228.8 157.94

0*0340570 12151-4 1 03b6 •

3

152*14 285 0*0256691 13609*8 11241*3 158*01

0.0338986 12172.3 10378.8 152.23 286 0.0255792 13630.6 11253.8 155.08

0.0337417 12193.2 10391.3 152.33 287 0.0254899 13651.4 11266.3 158.16

0.0335862 12214.0 10403.8 152.43 288 0.0254012 13672.2 11278.7 158.23

0.0334322 12234.9 10416.3 152.52 289 0.0253131 13693.0 11291.2 158.30

0.0332795 12255.7 10428.9 152.62 290 0.0252257 13713.8 1 1303.7 158.37

0.0331253 12270.6 10441,4 152,71 291 0.0251388 13734.7 11316.2 158.44

0.0329785 12297.4 10453*9 152.81 29? 0.0250526 13755.

S

11328.7 158.51

0.0328300 12318.3 1 04b6 .4 152.90 293 0.0249669 13776.3 11341.2 158.59

0. 0326828 12339.1 10478.9 152.99 29* 0.0248818 13797.1 1)353.7 158.66

0.0325369 12359.9 10491.4 153.09 295 0.0247973 13817.9 11366.2 158.73

0.0.32392'* 12380.8 10503.9 153.18 ?96 0.0247134 13838.7 11379.7 158.80

0.0322491 12*01 .6 10516.4 153.27 297 0.0246300 1 3859.5 11391.2 158.87

0.0321071 12*22.5 10528.9 153.36 298 0.0245472 13880.4 11403.6 158.94

0.0319664 12443.3 10541.* 153*45 299 0.0244650 13901.2 11416.1 159.01

0.0318269 12464.2 10553.9 153.54 300 0.0243833 139??.

o

11428.6 159.08

54
o.7o atmosphere isobar

TFMP. .DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 0.101597 9433.9 8735.8 131.52

87 0.100354 9455.4 8748.6 131.76

88 0.0991430 9476.9 8761.5 132.01

89 0,0979616 9498.4 8774.3 132.25

90 0.0968092 9519.9 8787.2 132.49

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

intfrnal

ENERGY

J/MOL

entropy

J/MOL-K

91 0.0956847 9541.3 8800.0 132.73

92 0.0945869 9562.7 8812.9 132.96

93 0.0935150 9584.2 8825.7 133.19

94 0.0924681 9605.6 8838.5 133.42

95 0.0914451 9627.0 8851.3 133.65

96 0.0904454 9648.4 8864.2 133.87

97 0.0894680 9669.8 8877.0 134.10

98 0.0885122 9691.1 8889.8 134.32

99 0.0875773 9712.5 8902-6 134.53

100 0.0866627 9733-9 8915-4 134.75

101 0.0857675 9755.2 8928.2 134.96

102 0.0848912 9776-5 8941.0 135.17

103 0.084033? 9797.8 8953.8 135.38

104 0 • 0831929 9819-1 8966-5 135-58

105 0-0823697 9840.4 8979-3 135-79

106 0-0815631 9561-7 8992-1 135-99

107 0-0807726 9883-0 9004-9 136-19

108 0-0799978 9904-3 9017-6 136-39

109 0-0792380 9925-5 9030-4 136-58

110 0-0784929 9946-7 9043-1 136-78

111 0.0777621 9968.0 9055.0 136.97

11? 0-0770451 9989.2 9068.6 137.16

113 0-0763415 10010-4 9081-3 137.35

114 0-0756510 10031-6 9094-0 137-53

115 0-0749732 10052-8 9106.8 137-72

116 0.0743077 10074.0 9119.5 137.90

117 0.0736541 10095.2 9132.2 138.08

118 0.0730122 10116.4 9144.9 138.26

119 0.0723817 10137.5 9157.6 138.44

120 0.0717622 10158.7 9170.3 138.62

121 0.0711534 10179.8 9183.0 138.80

122 0 ,0705551 10201.0 9195.7 138.97

123 0.0699670 10222.1 9208.4 139.14

124 0.0693888 10243.2 9221.0 139.31

125 0.0688203 10264.4 9233.7 139.48

126 0.0682611 10285-5 9246-4 139-65

127 0.0677112 10306.6 9259-1 139.82

128 0.0671702 10327.7 9271.7 139.98

129 0.0666380 10348.8 9284.4 140.15

1 90 0.0661142 10369.9 9297.0 140.31

131 0.0655988 10391.0 9309.7 140.47

132 0.0650915 10412.0 9322.4 140.63

133 0.0645921 10433.1 9335.0 140.79

134 0*0641005 10454-2 9347-6 140-95

135 0-0636164 10475-2 9360-3 141-11

136 0-0631396 10496-3 9372-9 141.26

137 0.0626701 10517.3 9385.6 141.4?

138 0.0622076 10538.4 9398.2 141.57

139 0.0617520 10559.4 9410.8 141.72

140 0. 0613031 10580.5 9423.4 141.87

141 0.0608608 10601.5 9436.1 142.02

14? 0.0604249 10622.5 9448.7 142.17

143 0-0599953 10643.6 9461-3 142-32

1 44 0-0595718 10664.6 9473-9 142-46

145 0.0591544 10685.6 9486.5 142.61

146 0. 0587428 10706.6 9499.1 142.75

147 0.0583370 10727.6 9511.7 142.90

1 48 0.0579369 10748.6 9524.4 143.04

149 0.0575422 10769.6 9537.0 143.18

150 0.0571530 10790.6 9549.6 143.32

151 0.0567691 10811.6 9562.2 143.46

152 0.0563903 10832.6 9574.7 1^3.60

153 0.0560166 10853.6 9587.3 143.74

154 0.0556480 10874,5 9599.9 143.87

155 0.0552841 10895.5 9612.5 144.01

156 0.0549251 10916.5 9625-1 144.14

157 0.0545707 10937.5 9637.7 144.28

158 0.0542210 1 0q58 .

4

9650.3 144,41

159 0.0538757 10979.4 9662.9 U4.54

160 0. 053534g 11000.4 9675.4 144.67

316-977 0 - 69-5

55
0.70 ATMOSPHERE ISOBAR

TEMP.

K densitymol/liter

ENTHALPY

J/MOL INTERNAL energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITYMOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

161 0.0531984 11021.3 9688.0 144.81 231 0.0369765 12483.8 10565.6 152.35

162 0.0528661 11042.3 9700.6 144.93 232 0.0368165 12504.7 10578.1 152.44

163 0.0825380 11063.2 9713.2 145.06 233 0.0366578 12525.5 10590.6 152.53

164 0.0522140 11084.2 9725.7 145.19 234 0.0365005 12546.4 10603.1 152.62

165 0.0518940 11105.1 9738.3 145.32 235 0.0363445 12567.2 10615.6 152.71

166 0.0515779 11126.1 9750.9 145.45 236 0.0361698 12588.1 10628.1 152.80

167 0 • 051265 f 11147.0 9763.4 145.57 237 0.0360365 12608.9 10640.6 152.88

168 0.0509573 11168.0 9776.0 145-70 238 0.0358845 12629.7 10653.1 152-97

169 0.0506526 11188-9 9788.6 145.82 239 0.0357337 12650.6 10665.7 153.06

170 0.0503515 11209.8 9801.1 145.94 240 0.0355843 12671.4 10678.2 153.15

171 0.0500541 11230.8 9813.7 146.07 241 0,0354360 12692.3 10690.7 153.23

172 0.0497602 11251.7 9826.3 146.19 242 0.0352890 12713.1 10703.2 153.32

173 0.0494697 11272.6 9838.8 146.31 243 0.0351433 12734.0 10715.7 153.40

174 0.0491826 11293.5 9851 .4 146.43 244 0.0349987 12754.8 10728.2 153.49

178 0.0488989 11314.5 9863.9 146.55 245 0,0348553 12775.7 10740.7 153.53

176 0.0486185 11335.4 9876.5 146.67 246 0.0347131 12796.5 10753.2 153.66

177 0*0483412 11356*3 9889*0 146*79 247 0*0345720 12817.3 10765-7 153*74

178 0.0480672 11377.2 9901*6 146.91 248 0*0344321 12838.2 10778.2 153.83

179 0.0477962 11398.1 9914.1 147.02 249 0*0342934 12859.0 10790*7 153.91

180 0.0475284 11419.1 9926.7 147.14 250 0.0341557 12879.9 10803.2 154.00

181 0.0472635 11440.0 9939.2 147.26 251 0.0340192 12900.7 10815.7 154.08

182 0,0470016 11460.9 9951.8 147.37 252 0.0338837 12921.5 10828.2 154.16

183 0.0467426 11481.8 9964,3 147.49 253 0.0337493 12942.4 10840.7 154.24

184 0 .0464864 11502.7 9976.9 147.60 254 0 .0336160 12963.2 10853.2 154.33

185 0.0462331 11523.6 9989.4 147.71 255 0.0334837 12984.0 10865.7 154.41

186 0.0459825 11544.5 10002*0 147.83 256 0.0333525 13004.9 10878.2 154.49

187 0.0457347 11565.4 10014.5 147.94 257 0.0332223 13025.7 10890.7 154.57

188 0.0454895 11586.3 10027.1 148.05 258 0.0330931 13046.6 10903*2 154.65

189 0.0452470 11607.2 10039.6 148.16 259 0.0329649 13067.4 10915.7 154.73

190 0.0450070 11628,1 10052.1 143.27 260 0.0328377 13088.2 10928.2 154.81

191 0.0447696 11649.0 10064.7 148.38 261 0.0327115 13109.1 10940.7 154.89

192 0*0445347 11669*9 10077*2 148*49 262 0*0325863 13129.0 10953*2 154.97

193 0.0443023 11690.8 10089.7 148.60 263 0.0324620 13150.7 10965.7 155.05

194 0*0440723 11711.7 10102*3 148.71 264 0*0323387 13171.6 10978.2 155.13

195 0 . 043844 7 11732.6 10114.8 140.81 265 0.0322163 13192.4 10990.7 155.21

196 0.0436194 11753.4 10127.3 148.92 266 0.0320948 13213.2 11003.2 155.29

197 0.0433965 11774.3 10139.9 149.03 267 0.0319743 13234.0 11015.7 155.37

198 0.0431756 11795.2 10152.4 149.13 268 0.0318546 13254.9 110?9.2 155.44

199 0.0429574 11816.1 10164.9 149.24 269 0.0317359 13275.7 11040.7 155.52

200 0.0427412 11837.0 10177.5 149.34 270 0.0316180 13296.5 11053.2 155.60

201 0,0425272 11857,9 10190.0 149.45 271 0.0315010 13317.4 11065.7 155.68

202 0.0423153 11878.7 10202.5 149.55 272 0.0313848 13338.2 11078.2 155.75

203 0.0421055 11899.6 10215.1 149.65 273 0.0312696 13359.0 11090*7 155.83

204 0.0418976 11920*5 10227*6 149.76 274 0.0311551 13379.9 11103.2 155.91

205 0.0416922 11941.4 10240.1 149.86 275 0*0310415 13400.7 11115.7 155.98

206 0.0414886 11962.3 10252.6 149.96 276 0.0309288 13421.5 11128.2 156.06

207 0.0412869 11983.1 10265.2 150.06 277 0.0308168 13442.3 11140.7 156.13

208 0.0410873 12004.0 10277.7 150.16 278 0.0307057 13463.2 11153.2 156.21

209 0.0408895 12024.9 10290.2 150.26 2 79 0.0305953 13484.0 11165.7 156.28

210 0.0406937 12045.7 103C2.7 150.36 280 0.0304858 13504.8 11178.2 156.36

211 0.0404997 12066.6 10315.3 150.46 281 0.0303770 13525.6 11190.7 156.43

212 0.0403076 12087.5 10327.8 150.56 282 0-0302690 13546.5 11203.2 156.51

213 0.0401174 12108.3 10340.3 150.66 283 0.0301618 13567.3 11215.7 156.58

214 0-0399289 12129.2 10352*8 150*75 284 0*0300554 13588-1 11228*1 156*65

215 0.0397422 12150.1 O03o5*3 150*85 285 0.0299496 13608.9 11240*6 156.73

216 0.0395572 12170.9 1>377.9 150.95 286 0.0298447 13629.8 11253.1 156.80

217 0.0393739 12191.8 10390.4 151.04 287 0.0297404 1365C.6 11265.6 156.87

218 0.0391924 12212.7 10402.9 151.14 288 0*0296369 13671.4 11278.1 156.94

219 0«0790125 12233.5 10415*4 151 *24 289 0 • 0295341 13692*2 11290*6 157*02

220 0*0388343 12254.4 10427*9 151.33 290 0*0294321 13713-0 11303*1 157-09

221 0.0386577 12275.3 10440.4 151.43 291 0.0293307 13733.9 11315.6 157.16

222 0.0364827 12296.1 10453.0 151.52 292 0*0292300 13754.7 11328.1 157.23

223 0*0393093 12317*0 10465*5 151.61 293 0*0291300 13775.5 11340.6 157.30

224 0.0381374 12337.8 10478.0 151.71 294 0.0290307 13796.3 11353.1 157.37

225 0.0379671 12358.7 104^0.

5

151.80 295 0.0289321 13817.2 11365.6 157.44

226 0.0377984 12379.5 10503.0 151.89 296 0.0288342 13838.0 11378.1 157.51

227 0.0376311 12400.4 10515.5 151.98 297 0.0287369 13858.8 11390.6 157.58

228 0.0374653 12421.2 10528.0 152.08 298 0.0286402 13879.6 11403.0 157.65

229 0.0373009 12442.1 10540.6 152.17 299 0.0285442 13000.4 11415.5 157.72

230 0. 0V1380 12463.0 10553.1 152.26 300 0.0284489 13021.3 11428.0 157.79

56
0.80 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL energy J/MOL-K

J/MOL

86 0*116526 9427.4 8731*7 130*36

87 0.115087 9449*0 8744*6 130*61

88 0*113685 9470*6 8757*5 130*85

89 0*112318 9492*2 8770*4 131*10

90 0*110986 9513*7 8783*4 131*34

TEMP.

K DENSITYMOL/LITER

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

Entropy

j/mol -k

91 0.109686 9535.3 8796.3 131.58

92 0.108417 9556.8 8809.1 131.81

93 0,107179 9578.4 8822.0 132.04

94 0.105970 9599.9 8834.9 132.27

95 0.104789 9621.4 8847.8 132.50

96 0.103635 9642.9 8860.7 132.73

97 0.102507 9664.3 8873.6 132.95

98 0.101404 9685.8 8886,4 133.17

99 0.100326 9707.3 8899.3 133.39

1 00 0.0992720 9728.7 8912.1 133.60

101 0.0982402 9750.1 8925.0 133.82

102 0.0972303 9771.5 8937.8 134.03

103 0.0962418 9792.9 8950.6 134.24

104 0*0952738 9814.3 8963*5 134.44

105 0.0943258 9835.7 8976.3 134.65

106 0,0933970 9857.0 8989.1 134.85

107 0.0924870 9878.4 9001.9 135.05

108 0.0915951 9899.7 9014.7 135.25

109 0.0907208 9921.0 9027.5 135,44

110 0.0898635 9942.3 9040.3 135.64

111 0.0890228 9963.6 9053.1 135.83

112 0.0881981 9984.9 9065.8 136.02

113 0*0873890 10006.2 9078.6 136.21

114 0.0865950 10027.5 9091.4 136.40

115 0.0858157 10048.7 9104.1 136.59

116 0.0850507 10070.0 9116.9 136.77

117 0.0842996 IOO9I .2 9129.6 136.95

118 0.0835619 10112.5 9142.4 137.13

119 0.0828374 10133.7 9155.1 137.31

120 0,0821256 10154.9 9167.8 137.49

121 0.0814263 10176.1 9180.6 137.67

122 0.0807391 10197.3 9193.3 137.84

123 0.0800636 10218.5 9206,0 138.01

124 0,0793996 10239.7 9218.7 138.18

125 0.0787468 10260.8 9231.4 138.35

126 0.0781049 10282.0 9244.1 138.52

127 0.0774735 10303.1 9256.8 138.69

128 0.0768526 10324.3 9269.5 138.86

129 0.0762416 10345.4 9282.2 139.02

130 0.0756406 10366.6 9294.9 139.18

131 0.0750491 10387.7 9307.6 139.35

132 0.0744670 10408.8 9320.3 139.51

133 0,0738940 10429.9 9332.9 139.67

134 0.0733299 10451.0 9345.6 139.82

135 0.0727745 10472.1 9358.3 139.98

136 0.0722277 10493.2 9370.9 140.14

137 0.0716891 10514.3 9383.6 140.29

138 0*0711587 10535.4 9396*2 140.44

139 0.0706361 10556.5 9408.9 140.60

140 0.0701214 10577.6 9421.5 140.75

141 0.0696142 10598.6 9434.2 U0.90

142 0*0691144 10619.7 9446*8 141*05

143 0*0686218 10640*7 9459*5 141*19

144 0*0681363 10661.8 9472*1 141.34

145 0.0676578 10682.8 9484.7 1 4 1 .49

146 0. 0671860 10703.9 9497.4 141.63

147 0.0667208 10724.9 9510.0 141.77

148 0.0662622 10746.0 9522.6 141.92

149 0.0658099 10767.0 9535.2 142.06

150 0*0653638 10788.0 9547.8 142.20

151 0.0649238 10809.0 9560.5 142.34

152 0.0644898 10830.1 9573.1 142.48

153 0.0640616 10851-1 9585.7 142.62

154 0.0636391 10872*1 9598*3 142-75

155 0*0632223 10893.1 9610*9 142*89

156 0*0628109 10914.1 9623.5 143.02

157 0 • 0684049 10935*1 9636.1 143*16

158 0*0620042 10956*1 9648*7 143*29

159 0*0616087 10R77.1 9661*3 143*42

160 0*0612183 10998*1 9673*9 143.55

57
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

1 79

1

8

0

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

0.80 ATMOSPHERE ISOBAR

DENSITY

MOL/LITER

ENTHALPY

J/MOL

internal

ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

MOL/L ITER ENTHALPYJ/MOL

INTERNAL

ENERGY

J/MOL

entropy

j/mol-k

0.0608326 11019.0 9686.5 143 69 231 0 0422664 12482.6 10564.7 151 23

0.0604522 11040.0 9699.1 143 82 232 0 0420833 12503.5 10577.2 151 32

0.0600764 11061.0 9711.7 143 94 233 0 0419018 12524.3 10589.7 151 41 0.0597053 11082.0 9724.3 144 07 234 0 0417219 12545.2 10602.3 151 50

0.0593388 11102.9 9736,8 144 20 235 0 0415435 12566.0 10614.8 151 59

0.0589768 11123.9 9749.4 144 33 236 0 0413666 12586.9 10627.3 151 68

0.0586192 11144.9 97&2.0 144 45 237 0 0411912 12607.8 10639.8 151 77 0.0582660 11165.8 9774.6 144 58 238 0 0410174 12628.6 10652.3 151 86

0.0579171 11186.8 9787.2 144 70 239 0 0408450 12649.5 10664.8 151 94

0.0575724 11207.8 9799.7 144 83 240 0 0406740 12670.3 10677.3 152 03

0.0572318 11228.7 9812.3 144 95 241 0 0405045 12691.2 10689.9 152 12 0.0568952 11249.7 9824.9 145 07 242 0 0403364 12712.0 10702.4 152 20

0.0565627 11270.6 9837.5 145 19 243 0 0401696 12732.9 10714.9 152 29

0.0562340 11291.6 9850.0 145 31 244 0 0400043 12753.7 10727.4 152 38

0.0559091 11312.5 9862.6 145 43 245 0 0398403 12774.6 10739.9 152 46

0,0555880 11333.4 9875.2 145 55 246 0 0396777 12795.4 10752.4 152 55

0,0552707 11354.4 9887.7 145 67 247 0 0395164 12816.3 10764.9 152 63

0.0549569 11375.3 9900,3 145 79 248 0 0393564 12837.1 10777.4 152 72

0.0546467 11396.2 9912.9 145 91 249 0 0391977 12858.0 10789.9 152 80

0,0543401 11417.2 9925.4 146 02 250 0 0390403 12878.8 10802.4 152 88

0.0540369 11438.1 9938.0 146 14 251 0 0388841 12899.7 10814.9 152 97

0.0537371 11459.0 9950.5 146 25 252 0 0387292 12920.5 10827.5 153 05

0.0534406 11480.0 9963.1 146 37 253 0 0385755 12941*4 10840*0 153 13 0.0531474 11500.9 9975.7 146 48 254 0 0384231 12962*2 10852*5 153 21 0-0528574 11521.8 9988*2 146 60 255 0 0382718 12983.0 10865*0 153 30 0.0525706 11542.7 10000-8 146 71 256 0 0381217 13003.9 10877.5 153 38

0-0522869 11563*7 10013*3 146 82 257 0 0379729 13024.7 10890*0 153 46

0.0520063 11584.6 10025*9 146 93 258 0 0378251 13045.6 10902*5 153 54

0.0517287 11605-5 10038*4 147 04 259 0 0376786 13066.4 1091 5*0 153 62

0.0514541 11626.4 10051.0 147 15 260 0 0375331 13087*3 10927.5 153 70

0.0511824 1 L647.3 10063.5 147 26 261 0 0373888 13108.1 10940.0 153 78

0.0509136 11668.2 10076.1 147 37 262 0 0372456 13128.9 10952.5 153 86

0 .0506476 11689.1 10068-6 147 48 263 0 0371035 13149.8 10965.0 153 94

0.0503844 11710.0 10101.2 147 59 264 0 0369625 13170.6 10977.5 154 02

0.0501239 11730.9 10113.7 147 70 265 0 0368225 13191.5 10990*0 154 10 0.0498661 11751.8 10126.2 147 80 266 0 0366836 13212.3 11002.5 154 18 0.0496110 11772.7 10138.8 147 91 267 0 0365457 13233.1 11015.0 154 25

0.0493585 11793.6 10151.3 148 02 268 0 0364089 13254.0 11027.5 154 33

0.0491086 11814.5 10163.9 148 12 269 0 0362731 13274.8 11040.0 154 41 0.0488612 11835.4 10176.4 148 23 270 0 0361384 13295.6 11052*5 154 49

0.0486163 11856.3 10188.9 148 33 271 0 0360046 13316.5 11065.0 154 56

0.0483738 11877.2 10201.5 148 43 272 0 0358718 13337.3 11077.5 154 64

0.0481338 11898.1 10214.0 148 54 273 0 0357400 13358.1 11090.0 154 72 0*0478962 11919*0 10226.5 148 64 274 0 0356091 13379*0 11102*5 154 79

0.0476609 1 1939.9 10239.1 148 74 275 0 0354793 13399-8 11115*0 154 97

0*0474279 11960*8 10251*6 148 84 276 0 0353503 13420*6 11127*5 154 94

0*0471972 11981.7 10264*1 148 95 277 0 0352223 13441*5 11140*0 155 02

0*0469688 12002*5 10276*7 149 05 278 0 0350952 13462-3 11152*5 155 10 0.0467426 12023.4 10289.2 149 15 279 0 0349691 13483.1 11165.0 155 17 0.0465185 12044.3 10301.7 149 25 280 0 0348438 13504.0 11177.5 155 24

0.0462966 12065.2 10314.3 149 34 281 0 0347195 13524.8 11190.0 155 32

0.0460768 12086.1 10326.8 149 44 282 0 0345960 13545.6 11202*5 155 39

0.0458591 12107.0 10339.3 149 54 283 0 0346-734 13566.5 11215.0 155 47

0.0456435 12127.8 10351.9 149 64 284 0 0343517 13587.3 11227.5 155 54

0.0454299 12148.7 10364.4 149 74 285 0 0342308 13608.1 11240*0 155 61 0.0452183 12169.6 10376.9 149 83 286 0 0341108 13628.9 11252.5 155 69

0.0450087 12190.5 10389.4 149 93 287 0 0339916 13649.8 11265.0 155 76

0.0448010 12211.3 10402.0 150 03 288 0 0338733 13670.6 11277.5 155 83

0.0445952 12232.2 10414.5 150 12 289 0 0337558 13691.4 11290.0 155 90 0.0443913 12253.1 10427*0 150 22 290 0 0336391 13712-3 11302*5 155 98

0.0441893 12274.0 10439.5 150 31 291 0 0335232 13733.1 11315.0 156 05 0.0439892 12294.8 10452.0 150 41 292 0 0334081 13753.9 11327.5 156 12 0.0437908 12315.7 1 0464 .

6

150 50 293 0 0332937 13774.7 11340.0 156 19

0 • 0435942 12336*6 10477. 1 150 59 294 0 0331802 13795*6 11352*5 156 26

0.0433994 12357.4 10469*6 150 69 295 0 0330675 13816.4 11365*0 156 33

0.0432064 12378.3 10502.1 150 78 296 0 0329555 13837.2 11377.5 156 40

0.0430150 12399.2 10514.6 150 87 297 0 0328442 13858.0 11390.0 156 47

0.0428254 12420.0 10527.2 150 96 298 0 0327337 13878.9 11402.5 156 54

0.0426374 12440*9 10539-7 151 05 299 0 0326240 13899.7 11414*9 156 61 0.0424511 12461.7 10552.2 151 14 300 0 0325150 13920.5 11427.4 156 68

58
0.90 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 35,0875 2914.4 2911.8 53.94

86.302 35.0419 2928.2 2925.6 54.10

86.302 0.131066 9427.3 8731.5 129.40

87 0.129926 9442.5 8740.6 129.58

88 0.128328 9464.2 8753.6 129.83

89 0.126772 9485.9 8766.5 130*07

90 0.125254 9507.6 8779.5 130.32

temp. DENSITY ENTHALPY INTERNAL Entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 0.123775 9529.2 8792.5 130.55

92 0.122332 9550.9 8805.4 130.79

93 0.120923 9572.5 8818.4 131.03

94 0.119548 959*.

1

8831.3 131.26

95 0.118206 9615.7 8844.2 131.48

96 0.116895 9637.3 8857.2 131.71

97 0.115614 9658.9 8870.1 131.93

98 0.114362 9680.4 8883.0 132.16

99 0.113138 9702.0 8895.9 132.37

100 0.111941 9723.5 8908.8 132.59

101 0.110770 9745.6 8921.7 132.80

102 0.109624 9766.5 8934.6 133.02

103 0.108503 9788.0 8947.5 133.23

1 04 0.107405 9809.4 8960.4 133.43

105 0.106330 0830.9 8973,2 133.64

106 0.105278 9852,3 8986.1 133.84

107 0.104246 9873.7 8998.9 134.04

108 0.103236 9895.1 9011.8 134.24

109 0.102245 9916.5 9024.6 134.44

no 0.101274 9937.9 9037.4 134.63

111 0.100322 9959.3 9050.3 134.83

112 0.0993888 9980*6 9063.1 135.02

113 0.0984728 10002.0 9075.9 135.21

114 0.0975741 10023.3 9088.7 135.40

115 0.0966922 10044.6 9101.5 135.58

116 0.0958265 10066.0 9114.3 135.77

117 0.0949766 10087.2 9127.1 135.95

118 0.0941422 10108.5 9139.8 136.13

119 0,0933226 10129.8 9152.6 136.31

120 0.0925177 10151.1 9165.4 136.49

121 0.0917268 10172.3 9178.1 136.67

122 0.0909498 10193.6 9190*9 136.84

123 0*0901861 10214*8 9203*6 137.01

124 0*0894355 10236.1 9216*4 137*19

125 0*0886976 10257*3 9229*1 137*36

126 0.0879721 10278.5 9241.9 137.53

127 0.0872586 10299.7 9254.6 137.69

128 0.0865569 10320.9 9267.3 137.86

129 0.0858667 10342.1 9280.0 138.02

130 0.0R51876 10363.3 9292.7 . 138.19

131 0.0845194 10384.4 9305.4 138.35

132 0.0838619 10405.6 9318.1 138.51

133 0.0832147 10426,7 9330.8 138.67

134 0.0825777 10447.9 9343.5 138.83

135 0.0819505 10469.0 9356.2 138.99

136 0,0813330 10490.2 9368.9 139.14

137 0.0807249 10511.3 9381.6 139.30

138 0.0801260 10532.4 9394.3 139.45

139 0.0795361 10553.5 9407,0 139.60

140 0.0789550 10574.6 9419.6 139.75

141 0.0783825 10595.8 9432.3 139.90

142 0.0778184 10616.8 9445.0 140.05

143 0*0772625 10637*9 9457.6 140*20

144 0*0767146 10659.0 9470-3 140.35

145 0.0761745 10680.1 9482.9 140.49

146 0.0756422 10701.2 9495.6 140.64

147 0.0751173 10722.3 9508.2 140.79

148 0.0745998 10743.3 9520.9 140.93

149 0.0740895 10764.4 9533.5 141.07

150 0.0735862 10785.4 95*6.1 141.21

151 0.0730899 10806.5 9558.8 141.35

152 0.0726003 10827.5 9571.4 141.49

153 0.0721173 10848.6 9584.0 141.63

154 0.0716408 10869.6 9596.7 141.76

155 0.0711703 10890.6 9609.3 141.90

156 0.0707067 10911.7 9621.9 142.03

157 0.0702*88 10932.7 9634.5 142.17

158 0.0697969 10953.7 9647.1 142.30

159 0.0693509 10974.7 9659.8 142.43

160 0.0689106 10995.7 9672.4 142.57

PHASE change 59
0.90 ATMOSPHERE ISOBAR

TEMP.

K DENSITY

mol/litfk

ENTHALPY

J/MOL

internal

ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

mol/liter

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

Entropy

J/MOL-K

161 0.0684760 11016.8 9685 .

0

142*70 231 0.0475581 12481 .4 10563.9 150.25

162 0.0680468 11037.8 9697.6 142*83 232 0.0473520 12502.3 10576.4 150.34

163 0.0676231 11058.8 9710.2 142.96 233 0.0471476 12523.1 10588.9 150.43

164 0.0672047 11079.8 9722.8 143.08 234 0.0469450 12544.0 10601.4 150.52

165 0.0667915 11100.8 9735.4 143.21 235 0.0467442 12564.9 10613.9 150.61

166 0.0663834 11121.7 9748.0 143.34 236 0.0465450 12585.7 10626.5 150.70

167 0.0659803 11142.7 97b0 • 6 143.46 237 0.0463476 12606.6 10639.0 150.79

168 0.0655821 11163*7 9773*2 143*59 238 0*0461519 12627.5 10651*5 150*87

169 0*0651888 11184*7 9785*8 143*71 239 0*0459578 12648*3 10664*0 150*96

170 0.0648002 11205.7 9796*4 143*84 240 0*0457653 12669.2 10676*5 151*05

171 0.0644163 11226.7 9610.9 143.96 241 0.0455745 12690.1 10689.0 151.14

172 0.0640370 11247.6 9823.5 144.08 242 0.0453852 12710.9 10701.6 151*22

173 0*0636621 11268*6 9836*1 144*21 243 0*0451975 12731.8 10714*1 151*31

174 0*0632917 11289*6 9848*7 144*33 244 0*0450114 12752*6 10726*6 151*39

175 0*0629256 11310*5 9861*3 144*45 245 0*0448268 12773*5 10739*1 151*48

176 0 . 062563? 11331.5 9873*9 144*57 246 0.0446437 12794.4 10751.6 151*56

177 0*0622060 11352*4 9886*4 144*68 247 0*0444621 12815*2 10764*1 151 *65

178 0.0618524 11373.4 9899.0 144.80 248 0.0442820 12836.1 10776.6 151.73

179 0.0615029 11394.4 9911.6 144.92 249 0.0441033 12856.9 10789.2 151.82

180 0.0611573 11415.3 9924.2 145.04 250 0.0439261 12877.8 10801.7 151.90

181 0.0608157 11436.3 9936.7 145.15 251 0.0437503 12898.6 10814.2 151 .98

182 0*0604778 11457*2 9949.3 145*27 252 0.0435759 12919.5 10826*7 152*07

183 0*0601437 11478*1 9961*9 145*38 253 0*0414029 12940*3 10839*2 152*15

184 0*0598134 11499*1 9974*4 145*50 254 0*0432313 12961*2 10851*7 152*23

185 0.0594866 11520.0 9987.0 145.61 255 0.0430611 12982.0 10864.2 152.31

186 0.0591635 11541.0 9999.6 145,72 256 0,0428921 13002.9 10876.7 152.40

187 0.0588439 11561.9 10012.1 145.84 257 0.0427245 13023.7 10889.3 152.48

1 88 0.0585277 11582.8 10024.7 145.95 258 0.0425583 13044.6 IO 9 OI .8 152.56

189 0.0582150 11603.8 10037.2 146.06 259 0.0423933 13065.4 10914.3 152.64

190 0*0579056 11624*7 10049*8 146*17 260 0*0422296 13086.3 10926*8 152*72

191 0.0575995 11645.6 10062.4 146.28 261 0.0420671 13107.1 10939.3 152.00

192 0.0572966 11666.5 10074.9 146.39 262 0*0419059 131 28.0 10951.8 152.88

193 0.0569970 11687*5 10087*5 146.50 263 0*0417459 13148.8 10964.3 152.96

194 0.0567005 11709*4 10100*0 146*60 264 0*041.5872 13169*7 10976*8 153*04

195 0.0564071 11729.3 10112.6 146.71 265 0.0414297 13190.5 10989.3 153.12

196 0.0561167 11750.2 10125.1 146.82 266 0.0412733 13211.4 11001.8 153.19

197 0.0558293 11771.1 10137.7 146.93 267 0.0411182 13232.2 11014.3 153.27

198 0.0555449 11792.1 10150.2 147.03 268 0.0409642 13253.0 11026.8 153.35

199 0.0552633 11813.0 10162.8 147.14 269 0.0408113 13273.9 11039.3 153.43

200 0.0549847 11833.9 10175.3 147.24 270 0.0406596 13294.7 11051.8 153.51

201 0.0547088 11854.8 10187.9 147.35 271 0.0405090 13315.6 11064.3 153.58

202 0.0544358 11875.7 10200.4 147.45 272 0*0403596 13336.4 11076.9 153*66

203 0.0541654 11896.6 10213.0 147.55 273 0.0402112 13357.3 11089.4 153.74

204 0.0538978 11917.5 10225.5 147.66 274 0.0400640 13378.1 11101.9 153.81

205 0.0536328 11938.4 10238.0 147.76 275 0.0399178 13398.9 11114.4 153.89

206 0*0533704 11959.3 10250*6 147*86 276 0*0397726 13419*8 11126*9 153*96

207 0*0531106 11980*2 10263*1 147*96 277 0*0396286 13440*6 11139*4 154.04

208 0*0528533 12001*1 10275*7 148*06 278 0*0394856 13461*4 11151*9 154*11

209 0*0525985 12022*0 10288*2 148*16 279 0*0393436 13482*3 11164*4 154*19

210 0*0523462 12042*9 10300*7 148*26 280 0*0392026 1.3503*1 11176*9 154.26

211 0 . 0520963 12063.8 10313.3 148.36 281 0.0390626 13524.0 11189.4 154.34

212 0 .0518488 12084.7 10325.8 148.46 282 0.0389237 13544.8 11201.9 154.41

213 0.0516036 12105.6 10338.3 148.56 283 0*0387857 13565.6 11214.4 154.49

214 0*0513608 12126*5 10350*9 14e*66 284 0*0386487 13586.5 11226*9 154.56

215 0*0511203 12147*3 10363*4 148*75 285 0*0385126 13607*3 11239*4 154.63

216 0.0508820 12168.2 10375.9 148.85 286 0.0383776 13628.1 11251.9 154.70

217 0.0506459 12189.1 10388.5 148.95 287 0.0382434 13649.0 11264.4 154.78

218 0.0504120 12210.0 10401.0 149.04 288 0.0381103 13669.8 11276.9 154.85

219 0.0501803 12230*9 10413.5 149.14 289 0.0379780 ] 3690.6 11289.4 154.92

220 0.0499507 12251*8 10426*1 149.23 290 0*0378466 13711 .5 11301*9 154.99

221 0.0497233 12272.6 10438.6 149.33 291 0.0377162 13732.3 11314.4 155.07

222 0*0494979 12293*5 10451 .

1

149.42 292 0*0375867 13753*1 11326*9 155.14

223 0*0492745 12314*4 10463*7 149*52 293 0*0374580 13774-0 11339*4 155*21

224 0.0490532 12335*3 10476*2 149*61 294 0*0373302 13794.8 11351*9 155*28

225 0.0488338 12356.2 104a8.7 149.70 295 0.0372033 13815.6 11164.4 155.35

226 0.0*86165 12377.0 10501.2 149.79 296 0.0370773 13836.5 11376.9 155.42

227 0.0484010 12397*9 10513*8 149*89 297 0*0369521 13857.1 11389*4 155.49

228 0*0481875 12418*8 10526*3 149*98 298 0*0368278 13878*1 11401*9 155*56

229 0.0479758 12439*7 10538*8 150*07 299 0*0367043 13898*9 11414*4 155*63

230 0.0477660 12460.5 10551.3 150.16 300 0,0365816 13919.8 11426.9 155.70

60
1.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 35.0883 2914,6 2911.7 53.94

87 34.9368 2960.3 2957.4 54.47

87.284 34.8934 2973.3 2970.4 54.61

87.284 0.14*358 9442.1 8740.2 128.73

88 0.143075 9457*7 8749.5 128.91

89 0.141324 9479.6 8762.6 129.15

90 0.139617 9501.3 8775.6 129*40

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOl.-K

91 0.137954 9523.1 8788.6 129.64

92 0*136332 9544.9 8801.6 129.87

93 0.134749 9566.6 8814.7 130.11

94 0.133205 9588,3 8827.7 130.34

95 0.131698 9610.0 8840.7 130.57

96 0.130227 9631.7 8853.6 130.80

97 0.128789 9653.4 8866.6 131.02

98 0.127385 9675.0 8879.6 131.24

99 0.126012 9696.7 8892.6 131.46

100 0.124670 9718.3 8905,5 131.68

101 0.123358 9739.9 8918.5 131.90

102 0.122074 9761.4 8931.4 132.11

103 0.120818 9783.0 8944.3 132.32

104 0.119588 9804.5 8957.2 132.53

105 0*118385 9826.1 8970-2 132*73

106 0.117206 9847.6 8983.1 132.94

107 0.116052 9869.1 8996.0 133.14

108 0.114921 9890.6 9008.8 133.34

109 0.113813 9912.0 9021.7 133.54

110 0.112726 9933.5 9034.6 133.73

111 0.111661 9954.9 9047.5 133.93

112 0.110617 9976.3 9060.3 134.12

113 0.109593 9997.7 9073,2 134.31

114 0,108588 10019.1 9086.0 134.50

115 0.107602 10040.5 9098.8 134.68

116 0.106635 10061.9 9111.7 134.87

117 0.105685 10083.3 9124.5 135.05

118 0.104753 10104.6 9137.3 135.23

119 0.103837 10125.9 9150.1 135.41

120 0.102938 10147.3 9162.9 135.59

121 0.102055 10168.6 9175.7 135.77

122 0.101187 10189.9 9188.5 135.94

123 0.100334 10211.2 9201.3 136.12

124 0.0994966 10232*4 9214*0 136-29

125 0.0986729 10253.7 9226.8 136.46

126 0*0978630 10275.0 9239.6 136.63

127 0.0970667 10296.2 9252.3 136.80

128 0.0962835 10317.5 9265.1 136.97

129 0.0955133 10338,7 9277,8 137.13

130 0.0947555 10359.9 9290.6 137.29

131 0.0940100 10381.1 9303.3 137.46

132 0.0932765 10402.4 9316.0 137.62

133 0.0925545 10423.6 9328.8 137.78

134 0.0918439 10444.7 9341.5 137.94

135 0.0911444 10465.9 9354.2 138,09

136 0.0904557 10487.1 9366.9 138.25

137 0.0897776 10508.3 9379.6 138.41

138 0,0891098 10529,4 9392,3 138.56

139 0.088*520 10550.6 9405.0 138.71

140 0.0878042 10571.7 9417.7 138.86

141 0.0871659 10592.9 9430.4 139.01

142 0.0865370 10614.6 9443.1 139.16

143 0.0859173 10635-1 9455.8 139.31

144 0.0853066 10656-2 9468*4 139*46

145 0.0847047 10677.4 9481.1 139.61

146 0.0841114 10698.5 94Q3.8 139.75

147 0.0835265 10719.6 9506.5 139. e9

148 0,0829498 10740.7 9519.1 140.04

149 0.0823811 10761.8 9531.8 140.18

1 50 0.0818204 10782.8 9544.4 140.32

151 0.0812673 10803.9 9557.1 140.46

152 0.0807219 10825.0 9569.7 140.60

153 0*0801838 10846.1 9582*4 140*74

154 0.0796529 10867.1 9595.0 140.88

155 0.0791292 10888.2 9607.7 141.01

156 0.0786124 10909.3 9620.3 141.15

157 0.0781024 10930.3 9632.9 141.28

158 0.0775991 10951.4 9645.6 141.42

159 0*0771023 10972-4 9658.2 141-55

160 0.0766119 10993.4 9670-8 141-68

PHASE CHANGE 61
1.00 ATMOSPHERE ISOBAR

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

INTERNAL

energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

mol/liter

ENTHALPY

J/MOL

internal

ENERGY

J/MOL.

entropy

J/mOI.-K

161 0.0761279 11014.5 9683.4 141.81 231 0.0528517 12480.2 10563.0 149.37

le>? 0.075650C 11035.5 9696.1 141.94 232 0.0526225 12501.1 10575.5 149.46

163 0.0751781 11056.5 9708.7 142.07 233 0.0523952 12522.0 10588.0 149.55

164 0,0747122 11077.5 9721.3 142.20 234 0.0521699 12542.0 10600.6 149.64

165 0.0742521 11098.6 9733.9 142.33 235 0.0519466 12563.7 10613.1 149.73

166 0.0737977 11119.6 9746.5 142.45 236 0-0517252 12584.6 10625.6 149.82

167 0*0733489 11140*6 9759*1 142*58 237 0*0515057 12605*5 10638*1 149.91

168 0 • 072905b 11161.6 9771*7 142*71 238 0*0512880 12626*3 10650*7 150.00

16R 0*0724677 11182.6 9784 • 4 142*63 239 0*0510722 12647*2 10663*2 150*08

170 0.0720351 11203.6 9797*0 142*95 240 0*0508582 12668*1 10675*7 150*17

171 0.0716077 11224.6 9809.6 143.08 241 0.0506460 12688.9 10688.2 150.26

172 0.0711854 11245.6 9822.2 143.20 242 0 . 0504355 12709. fl 10700.8 150.34

173 0*0707o81 1 1266 *6 9834*8 143*32 243 0*0502268 12730*7 10713.3 150*43

174 0 • 0703557 11287*6 9847*3 143*44 244 0*0500199 12751*5 10725*8 150*51

175 0-0699482 11308.6 9859*9 143*56 245 0*0498146 12772*4 10738*3 150*60

176 0*0695454 11329*5 9872*5 143*68 246 0*0496111 12793*3 10750*8 150*69

177 0-0691473 11350*5 9885*1 143*60 247 0*0494092 12814.1 10763*4 150*77

178 0*0687537 11371 *5 9897*7 143*92 248 0*0492089 12835*0 10775*9 150*85

17Q 0 * 0683647 11392*5 9910*3 144*04 249 0*0490103 12855*9 10788*4 150*94

180 0.0679801 11413.4 9922.9 144.15 250 0.0488132 12876.7 10800.9 151.02

181 0.0675998 11434.4 9935.5 144.27 251 0.0486178 12897.6 10813.4 151.10

182 0.0672238 11455.4 9948.0 144.39 25? 0.040*239 l?9ie.5 10825.9 151.19

183 0.0668521 11476.3 9960.6 144.50 253 0,0482316 12939.3 10838.5 151.27

184 0.0664844 11497.3 9973.2 144.61 254 0.0480408 12960.2 10851.0 151.35

185 U. 0661206 11518.2 9985.8 144.73 255 0.0478515 12931.0 10863.5 351.43

186 0.0657612 11539.2 9998.3 144.84 256 0.0476637 13001 .0 10876.0 151.52

187 0.0654056 11560.1 10010.9 144.95 257 0.0474774 13022.7 10888.5 151.60

188 0*0650538 11581-1 10023*5 145*06 258 0*0472925 13043-6 10901-0 1 5 1 *68

189 0.0647058 11602*0 10036*1 145 • 1

8

259 0*0471091 13064.5 10913*5 151*76

190 0.0643615 11623*0 10048*6 145*29 260 0*0469271 13085*3 109?6*1 151*84

191 0.0640209 11643.9 10061.2 145.40 261 0 . 0467465 13106.2 10938.6 151.92

192 0.0636839 11664.9 10073.8 145.51 262 0.0465673 13127.0 10951.1 152.00

193 0. 0633505 11685.8 10086*3 145*61 263 0 • 0463894 13147.9 10963*6 152*08

194 0*0630206 11706*7 10098*9 145*72 264 0*0462130 13168-7 10976*1 152*16

195 0*0626942 11727*7 30111*5 145*83 265 0*0460378 13189.6 10988*6 152*24

196 0*0623711 11748*6 10124.0 145.94 266 0*0458640 13210*4 11001*1 152.32

197 0*0620514 11769.5 10136.6 146*04 267 0*0456915 13231*3 11013*6 152*39

198 0.0617350 11790.5 10149-1 146*15 268 0*0455203 13252*1 11026*1 152*47

199 0. 061421a 11811.4 10161.7 146.26 269 0.0453504 13273.0 11038.6 152.55

200 0.0611116 11832.3 10174.2 146.36 270 0.0451818 13293.8 11051.2 152.63

201 0.0608049 11853.2 10186.8 146.46 271 0.045C144 13314.7 11063.7 152.70

202 0 .060501 1 11874.2 10199.3 146.57 272 0.0448482 1 3335.5 11076.2 152.78

203 0.0602004 11895.1 10211.9 146.67 273 0 . 0446833 13356.4 11088.7 152.86

204 0.0599G26 11916.0 10224.5 146.77 274 0.0445196 13377.2 11101.2 152.93

205 0.0596079 11936.9 10237.0 146.88 275 0.0*43571 13398.1 11113.7 153.01

206 0.0593160 11957.8 10249.6 146.98 276 0.0441958 1 34 1

R

, 9 1 1126.2 153.08

207 0.0590270 11978.7 10262.1 147.08 277 0 • 0440356 13439.7 11138.7 153.16

208 0.0587408 11999.6 10274.6 147.18 278 0.0438766 13*60.6 11151.2 153.24

209 0.0584574 12020.6 10287.2 147.28 279 0.0437188 13481.4 11163.7 153.31

210 0.0561767 12041.5 10299.7 147.38 280 0.0435621 13502.3 11176.2 153.38

211 0.0578988 12062.4 10312.3 147.48 281 0.0434065 13523.1 11188.7 153.46

212 0.0576235 12083.3 10324.8 147.58 282 0*0432520 13544.0 11201.2 153.53

213 0.0573508 12104.2 10337.4 147.68 ?R3 0.0430986 1 3564.

R

11213.7 153.61

214 0.0570807 12125.1 1 034Q.9 147.78 284 0.0429464 13585.6 11226.2 153.68

215 0. 0508132 12146.0 10362.4 147.87 285 0.0427951 13606.5 11238.7 153.75

216 0.0565482 12166.9 10375.0 147.97 ?R6 0.04?6450 13627.3 11251.2 153.83

217 0.0562856 12187.8 10387.5 148.07 287 0.04?4959 13648.? 11263.8 153.90

218 0.056025b 12208.7 10400.1 148.16 288 0.0423479 13669.0 11276.3 153.97

219 0.0557678 12229.6 10412.6 148.26 289 0.0422008 13689.8 1 1 288.8 154.04

220 0.0555125 12250.5 10425.1 148.35 290 0 .0420548 13710.7 11301.3 154.12

221 0.0552595 12271.3 10437.7 148.45 291 0.0419098 13731 .5 11313.8 154.19

222 0.0550088 12292.2 10450.2 148.54 292 0.0417659 13752.4 11326.3 154.26

223 0.0547604 12313.1 10462.7 148.64 293 0.0416229 13773.2 11338.8 154.33

224 0.0545143 12334.0 10475.3 148.78 294 0.0414808 13794.0 11351.3 154.40

225 0.0542704 12354.9 10487.8 148.82 295 0.0413398 13814.9 11363.8 154.47

226 0.0540286 12375.3 10500*3 148.92 296 0*0411997 13835.7 11376.3 154.54

227 0.0537890 12396.7 10512.9 149.01 297 0.0410605 13856.5 11388.8 154.61

228 0.0535516 12417.6 10525.4 149.10 298 0.0409223 13877.4 11401.3 154.68

229 0.0533162 12438.4 10537.9 149.19 299 0-0407851 13898.2 11413.8 154.75

230 0.0530829 12459.3 10550.5 149.28 300 0.0406487 13019.

0

11426.3 154.82

62
1.50 ATMOSPHERE ISOBAR

TEMP.

K density

mol/litek

ENTHALPY

J/MOL INTERNALENERGY

J/MOL

ENTROPY

J/MOL-K

86 35.0921 2915.5 2911.2 53.93

87 34.9407 2961.2 2956.8 54.46

88 34.7874 3007.1 3002.7 54.98

89 34.6324 3053.2 3048.8 55.50

90 34.4757 3099.5 3095.1 56.02

0

TEMP. DENSITY FNTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.3173 3146.0 3141.5 56.54

91.297 34.2698 3159.0 3155.4 56.69

91.297 0.209481 9498,5 8773.0 126.12

92 0.207674 9514.2 8782.3 126.29

93 0.205161 9536.5 8795.7 126.53

94 0.202714 9558.0 8809.0 126.77

95 0.200328 9581.0 8822.3 127.00

96 0.198003 9603.2 8835.6 127.24

97 0*195736 9625.4 8848.9 127.46

98 0.193524 9647.5 8862.2 127.69

99 0.191365 9669.7 8875.4 127.92

100 0-189257 9691*7 8888*6 128.14

101 0.187199 9713.8 8901.9 128.36

10? 0.185188 9735.8 8915.1 128.57

103 0.183222 9757.8 8928,3 128.79

104 0.181301 9779.0 8941.4 129.00

105 0.179422 9001.7 8954.6 129.21

106 0.177585 9823.6 8967.7 129.42

107 0*175787 9845.5 8980*9 129.62

108 0*174027 9867*4 8994*0 129*83

109 0.172304 9889.2 9007.1 130.03

no 0,170617 9911.0 9020.2 130.23

1 1

1

0.168965 9932.8 9033.3 130.43

112 0.167346 9954.6 9046.3 130.62

113 0*165760 9976.3 9059.4 130.81

114 0.164204 9998.1 9072*4 131*01

115 0*162680 10019.8 9085*5 131.20

116 0.161185 10041.5 9098*5 131.38

117 0.159718 10063.1 9111.5 131.57

118 0*158280 10084.8 9124*5 131.75

119 0.156868 10106.4 9137.5 131.94

120 0*155482 10128*0 9150*5 132*12

121 0.154122 10149.6 9163.4 132.30

122 0.152786 10171,2 9176.4 132,47

123 0.151475 10192.7 9189.3 132.65

124 0.150187 10214.3 9202.3 132.82

125 0.148921 10235.8 9215.2 133.00

126 0.147677 10257*3 9228.1 133*17

127 0.146455 10278.0 9241.0 133.34

128 0*145254 10300.3 9253*9 133*51

] 29 0.144073 10321.8 9266.8 133.67

130 0.142912 10343.2 9279.7 133.84

131 0.141770 10364.7 9292.6 134.00

132 0*140647 10386.1 9305.4 134.17

133 0.139542 10407.5 9318.3 134.33

134 0.138455 10428*9 9331*1 134.49

135 0*137385 10450*3 9344.0 134.65

136 0.136333 10471.7 9356.8 134.81

137 0.135297 10493.0 9369.6 134.96

138 0.134277 10514.4 9382.5 135.12

139 0.133273 10535.7 9395.3 135.27

140 0*132284 10557.1 9408.1 135.42

141 0.131310 10578.4 9420.9 135.58

142 0.130351 10599.7 9433.7 135.73

143 0.129406 10621.0 9446.5 135.88

144 0.128475 10642.3 9459.3 136.02

145 0.127558 10663*6 9472*0 136.17

146 0-126655 10684.9 9484.8 136.32

147 0.125764 10706.1 9497.6 136.46

148 0.124886 10727.4 9510.3 136.61

149 0.124021 10748.6 9523.1 136.75

150 0.123168 10769.9 9535.8 136.89

151 0.122326 10791.1 9548.6 137.03

152 0*121497 10812*

3

95610 137*17

153 0.120679 10833.5 9574.1 137.31

154 0.119872 10854.7 9586.8 137.45

155 0.119076 10875.9 9599.5 137.59

156 0.118291 10897.1 9612.3 137.72

157 0.117517 IO9I8.3 9625.0 137.86

158 0.116752 10939.5 9637,7 137.99

159 0.115998 10960.7 9650.4 138.13

160 0.115254 10981.9 9663.1 138.26

phase change 63
K

161 162

163

164

165

166

167

168

169

170

171 172

173

174 175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

209

209

210

211

212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

1.50 ATMOSPHERE ISOBAR

DENSITY

mol/litek

enthalpy

J/MOL

internal

energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITYmol/liter

ENTHALPY

j/mol

INTERNAL

ENERGY

J/MOL

ENTROPY

J/mOL-K

0,114519 11003.0 9675.8 138.39 231 0.0793477 12474.2 10558.7 145.98

0.1)3794 11024.2 9688.5 138.52 232 0.0790025 12495.1 10571.2 146.07

0.113079 11045.3 9701*2 138*65 233 0*0706603 12516.0 10583.8 146-16

0.112372 11066.5 9713.9 138.78 234 0.0783211 12537.0 10596.3 146.25

0.111674 11087.6 9726.6 138.91 235 0.0779848 12557.

9

10608.9 146,34

0.110986 11108.7 9739.3 139.04 236 0.0776514 12578.8 10621.4 146.43

0.110305 11129.9 9751.9 139.17 237 0.0773209 12599.7 10634.0 146.52

0.109634 11151.0 9764.6 139,29 238 0.0769932 12620,6 10646.5 146.61

0.108970 11172.1 9777.3 139.42 239 0.0766683 12641.5 10659.1 146.69

0.108315 11193.2 9790*0 139.54 240 0.0763461 12662.5 10671.6 146.78

0.107667 11214.3 9802.6 139.67 241 0.0760266 12683.4 10684.2 146.87

0.107028 11235.4 9815.3 139.79 242 0.0757099 12704.3 10696.7 146.96

0.106396 11256.5 9828.0 139.91 243 0*0753958 12725.2 10709.3 147.04

0.105772 11277*6 9840*6 140.03 244 0.0750843 12746.1 10721.8 147*13

0*105155 11298*7 9853*3 140*15 245 0*0747753 12767*0 10734.4 147.21

0*1 04545 11319.8 9865.9 140*27 246 0 * 0744690 12787*9 10746*9 147*30

0.103943 11340*8 9878.6 140*39 247 0.0741651 12808.8 10759.4 147*38

0*103347 11361 .9 9891.2 140*51 248 0*0738637 12829*7 10772*0 147.47

0.102759 11383.0 9903.9 140.63 249 0.0735648 12850.6 10784.5 147.55

0.102177 11404.0 9916.5 140.75 250 0.0732683 12871.5 10797.1 147.64

0.101602 11425.1 9929.1 140.66 251 0.0729742 12892.4 10809.6 147.72

0.101033 11446.1 9941.8 140*98 252 0-0726825 12913.3 10822*1 147.80

0.100471 11467.2 9954.4 141.09 253 0.0723931 12934.2 10834.7 147.88

0.0999156 11488.2 9967.0 141.21 254 0.0721061 12Q55.1 10847.2 147.97

0.0993660 11509.3 9979,7 141.32 255 0.0718213 12976.0 10859.8 148.05

0.0988224 11530-3 9992.3 141.44 256 0-0715387 12996.9 10872.3 148.13

0.0982849 11551.4 10004*9 141.55 257 0*0712584 13017.8 10884.8 148.21

0*0977533 11572*4 10017*5 141*66 258 0*0709803 13038*7 10897*4 148*29

0.0972275 11593.4 10030.2 141.77 259 0.0707044 13059.6 10909.9 148.37

0,0967073 11614.4 10042,8 141.88 260 0.0704306 13080.5 10922.4 148.45

0.0961928 11635.5 10055.4 141.99 261 0.0701590 13101.4 10935.0 148.53

0.0956839 11656.5 10068.0 142.10 262 0*0698894 13122*2 10947.5 148.61

0.0951803 11677.5 10080.6 142.21 263 0.0696219 13143.1 10960.0 148.69

0.09*6821 11698.5 10093.2 142,32 264 0,0693565 13164.0 10972.6 148.77

0.09*1891 11719.5 10105.8 142.43 265 0,0690931 13184.9 10985.1 148,85

0.0937014 11740.5 10118.4 142.54 266 0.0688317 13205.8 10997.6 148.93

0.0932187 11761.5 10131*0 142.64 267 0.0685723 13226.7 11010*1 149.01

0*0927410 11782*5 10143*6 142*75 268 0.0683148 13247*5 11022*7 149.09

0*0922682 11803.5 10156.2 142*86 269 0.0680593 13260.4 11035*2 149.17

0*0918003 11824*5 10168.8 142*96 270 0*0678057 13289*3 11047*7 149.24

0.0913372 11845.5 10181.4 143.07 271 0.0675540 13310.2 11060.3 149.32

0.0908788 11866.5 10194.0 143.17 272 0.0673042 13331.1 11072.8 149.40

0.0904250 11887.5 10206.6 143.27 273 0.0670562 13351.9 11085.3 149.47

0.0899758 11908.5 10219.2 143.38 274 0.0668100 13372.8 11097.8 149.55

0.0895311 11929.4 10231.8 143.48 275 0.0665657 13393.7 11110.4 149.63

0.0890908 11950.4 10244.4 143,58 276 0.0663231 13414.6 11122.9 149.70

0.0886549 11971.4 10257.0 143.68 277 0.0660824 13435.4 11135.4 149.78

0.0882232 11992.4 10269.6 143.79 278 0.0658433 13456.3 11147.9 149.85

0.0877958 12013.3 10282.2 143.89 279 0.0656060 13477.2 11160.5 149.93

0.0873725 12034.3 10294.7 143.99 2«0 0.0653704 13498.1 11173.0 150.00

0.0869534 12055.3 10307.3 144,09 281 0.0651365 13518.9 111R5.5 150.08

0.0865383 12076.2 10319.9 144.18 282 0.0649043 13539.8 11198.0 150.15

0.0861272 12C97.2 10332.5 144.28 283 0*0646738 13560.7 11210.5 150.22

0*0857200 12118*2 10345*0 144*38 284 0.0644448 13581 .5 11223.1 150*30

0.0853167 12139.1 10357.6 144.48 205 0.0642175 13602.4 11235.6 150.37

0.0849172 12160.1 10370,2 144.58 206 0.0639919 13623.3 11248.1 150.44

0.0R45214 12181.0 10382.6 144.67 287 0.0637678 13644.1 11260.6 150.52

0.0841294 12202.0 10395.3 144.77 288 0.0635452 13665.0 11273.1 150.59

0.0837410 12222.9 10407.9 144.87 209 0.0633242 13685.9 11285.7 150.66

0.0833562 12243.9 10420.5 144.96 290 0.0631048 13706.7 11298.2 150.73

0.0829750 12264.8 10433.0 145.06 291 0.0628869 13727.6 11310.7 150.81

0.0825973 12285.8 10445.6 145.15 292 0.0626705 13748.5 11323.2 150.88

0.0822230 12306.7 10458.2 145.24 293 0.0624556 13769.3 11335.7 150.95

0.0fll8522 12327.7 10470.7 145.34 294 0.0622421 13790.2 113*8.2 151.02

0.0814847 12348. to 10483.3 145.43 295 0.0620301 13811.6 11360.8 151.09

0.0811205 12369.5 10495.9 145.52 296 0.0618196 13831.9 11373.3 151.16

0.0807596 12390.5 10508.4 145.62 297 0.0616105 13852.8 11385.8 151.23

0.0804019 12411.4 10521.0 145.71 ?R0 0-0614028 13873.6 11398.3 151.30

0*0800474 12432*3 10533*6 145*80 299 0*0611965 ) 3894-S 11410*8 151*37

0.0796960 12453.3 10546.1 145.89 300 0.0609916 13915.3 11423.3 151.44

64
2.00 ATMOSPHERE isobar

TEMP. DENSITY enthalpy INTERNAL ENTROPY

K mol/liter J/MOL energy

J/MOL

J/MOL-K

86 35.0960 2916.4 2910.6 53,92

87 34.9446 2962.1 2956.3 54,45

88 34.7914 3008.0 3002.1 54.98

89 34.6365 3054.0 3048,2 55.50

90 34.4799 3100.3 3094.5 56.01

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K

91 34.3216 3146.8 3140.9 56.53

92 34.1616 3193.5 3187.6 57.04

93 33.9999 3240.4 3234.4 57.55

94 33.8366 3287.4 3281,4 58.05

94.393 33.7719 3306.0 3300.0 58.25

94.393 0*273070 9537*2 8795*0 124.26

95 0*271039 9551*6 8803*3 124*40

96 0 *267765 9573*8 8816*9 124*64

97 0*264577 9596*5 8830*6 124*88

98 0*261472 9619*2 8844.2 125.11

99 0*258447 9641*9 8857*7 12504

100 0.255498 9664,4 8871.3 125.57

101 0.252622 9687.0 8884.8 125.79

102 0.249817 9709.5 8898.3 126.01

103 0.247079 9732.0 8911.8 126.23

104 0.244406 9754.4 8925,2 126.45

105 0.241795 9776.0 8938.6 126.66

106 0.239245 9799.1 8952.1 126.88

107 0.236752 9821.4 8965.4 127.09

108 0.234315 9843.7 8978.8 127.29

109 0.231932 9865.9 8992.2 127.50

110 0.229601 9888.1 9005.5 127.70

111 0.227319 9910.3 9018.8 127.90

112 0*225086 9932*4 9032*1 128.10

113 0*222900 9954.5 9045*4 128*30

114 0*220759 9976*6 9058*6 128.49

115 0*218661 9998*7 9071*9 128*68

116 0*216606 10020*7 9085*1 128*87

117 0*214592 10042*7 9098*3 129-06

118 0*212617 10064*6 9111*5 129*25

119 0*210681 10086*6 9124*7 129.43

120 0*208782 10108*5 9137*8 129.62

121 0.206919 10130.4 9151.0 129.80

122 0.205091 10152.2 9164.1 129.98

123 0.203296 10174.1 9177.2 130.16

124 0.201535 10195.9 9190.3 130.33

125 0.199806 10217.7 9203.4 130.51

126 0.198108 10239.4 9216.5 130.68

127 0*196440 10261.2 9229*5 130*86

128 0-194801 10282.9 9242.6 131.03

129 0.193191 10304.6 9255.6 131.19

130 0.191609 10326.3 9268.7 131.36

131 0.190054 10348.6 9281.7 131.53

132 0*188525 10369.6 9294.7 131.69

133 0*187022 10391.3 9307-7 131.86

134 0*185543 10412.9 9320*7 132*02

135 0.184089 10434.5 9333.6 132.18

136 0.182659 10456.1 9346.6 132.34

137 0.181251 10477.7 9350.

6

132.50

138 0.179866 10499.2 9372.5 132.65

139 0.178503 10520.fi 9385.4 132.81

140 0.177162 10542.3 9398.4 132.96

141 0.175841 10563.8 9411.3 133.12

142 0.174540 10585.3 9424.2 133.27

143 0.173260 10606*8 9437.1 133.42

144 0.171999 10628.2 9450.0 133.57

145 0.170756 10649.7 9462.9 133.72

146 0.169533 10671.1 9475.8 133.86

147 0.168327 10692.6 9488.6 134.01

148 0.167139 10714.0 9501.5 134.16

14? 0.165968 10735.4 9514.4 134.30

150 0.164814 10756.8 9527.2 134.44

151 0.163677 10778.2 9540.0 134.58

152 0.162555 10799.6 9552.9 134.73

153 0.161450 10820.9 9565.7 134.87

154 0.160360 10842.3 9578.5 135.01

155 0.159285 10063.6 9591.3 135.14

1 56 0.158225 10885.0 9604.2 135.28

157 0.157179 10906.3 9617.0 135.42

158 0.156147 10927.6 9629.8 135.55

159 0.155129 10948.9 9642.6 135.69

160 0.154125 10970.2 9655.3 135.82

phase change 65
2.00 ATMOSPHERE isobar

TEMP.

K density

mol/litek

ENTHALPY

J/MOL

INTERNAL

energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITYmol/liter

ENTHALPY

J/MOL

intfrnal

ENERGY

J/MOL

entropy

j/mol-k

161 0.153134 10991.5 9668.1 135.95 231 0.105890 12468.2 10554.3 143.57

162 0.152157 11012.8 9680.9 136.08 232 0.105428 12489.1 10566.9 143.66

163 0.151191 11034.1 9693,7 136.22 233 0.104970 12510.1 10579.5 143.75

164 0.150239 11055.3 9706.4 136.35 234 0.104516 12531.1 10592.1 143.84

165 0.149299 11076.6 9719.2 136.47 235 0.104066 12552.0 10604.7 143.93

166 0.148370 11097.8 9732.0 136.60 236 0.103620 12573.0 10617.2 144.02

167 0*147454 11119.1 9744.7 136*73 237 0*103177 12594*0 10629*8 144.11

168 0 • 146549 11140-3 9757.5 136.86 238 0-102739 12614.9 10642.4 144.20

169 0.145655 11161.5 9770*2 136.98 239 0*102304 12635.9 10655.0 144.29

170 0.144772 11182.8 9782.9 137.11 240 0.101873 12656.8 10667.5 144.37

171 0.143901 11204.0 9795.7 137.23 241 0.101445 12677.8 10680.1 144.46

172 0*143040 11225*2 9808.4 137.36 242 0*101022 12698.7 10692*7 144.55

173 0*142189 11246.4 9821*1 137*48 243 0*100601 12719.7 10705*3 144.63

174 0-141349 11267*6 9833.8 137.60 244 0*100185 12740*6 10717.0 144.72

175 0*140519 11288.8 9846*6 137.72 245 0 * 0997717 12761*6 10730*4 144.80

176 0 • 159699 11309*9 9859*3 137*84 246 0*0993618 12782*5 10743*0 144.89

177 0.138888 11331.1 9872.0 137.96 247 0.0989553 12803.5 10755.5 144.98

178 0.138088 11352.3 9884.7 138.08 248 0.0985522 12824.4 10760.1 145,06

179 0.137296 11373.4 9897.4 138.20 249 0.0981524 12845.4 10780.7 145.14

180 0.136514 11394.6 9910.1 138.32 250 0.0977558 12866.3 10793.2 145.23

181 0.135741 11415.7 9922.8 138.44 251 0.0973624 12887.2 10805.8 145.31

182 0.13*976 11436.9 9935.5 138.55 252 0.0969723 12908.2 10818.4 145.39

183 0.134221 11458.0 9948.2 138.67 253 0.0965852 12929.1 10830.9 145.48

184 0*133474 11479*2 9960*9 138*78 254 0*0962013 12950*0 10843.5 145*56

185 0.132735 11500.3 9973.5 138.90 255 0.0958204 12971.0 10856.0 145.64

186 0.132005 11521,4 9986.2 139.01 256 0.0954426 12991.9 10868.6 145.72

187 0.131283 11542.5 9998.9 139.13 257 0.0950678 13012.8 10881.1 145.81

188 0*130569 11563.7 10011*6 139.24 258 0.0946959 13033.8 10893*7 145.89

189 0.129862 11584.8 10024.2 139.35 259 0.0943269 13054.7 10906.3 145.97

190 0,129164 11605.9 10036.9 139.46 260 0.0939609 13075.6 10918.8 146.05

191 0.128473 11627.0 10049.6 139,57 261 0.0935976 13096.5 10931.4 146.13

192 0.127790 11648.1 10062.2 139.68 262 0.0932372 13117.5 10943.9 146.21

193 0.127114 11669.2 10074,9 139.79 263 0.0928796 13138.4 10956.5 146.29

194 0.126445 11690.3 10087.5 139.90 264 0.0925248 13159.3 10969.0 146.37

195 0.125783 11711.3 10100,2 140.01 265 0.0921726 13180.2 10981.6 146.45

1 96 0.125128 11732.4 10112.9 140.12 266 0.0918232 13201.1 10994.1 146.53

197 0.124481 11753.5 10125.5 140.22 267 0.0914764 13222.0 11006,7 146.60

198 0.123840 11774.6 10138.1 140.33 268 0.0911323 13243.0 11019.2 146.68

199 0.123205 11795*6 10150-8 140*44 269 0.0907907 13263.9 11031.8 146*76

200 0*122578 11816.7 10163*4 140*54 270 0*0904517 13284*8 11044*3 146*84

201 0.121956 11837.8 10176.1 140.65 271 0.0901153 13305.7 11056.8 146,92

202 0*121342 11858.8 10188.7 140*75 272 0.0897813 13326.6 11069.4 146.99

203 0.120733 11879.9 10201*3 140*66 273 0.0894499 33347.5 11081.9 147.07

204 0*120130 11900*9 10214*0 140*96 274 0*0891209 13368.4 11094.5 147*15

205 0*119534 11922*0 10226*6 141*06 275 0*0887943 13389*3 11107*0 147.22

206 0*118944 11943-0 10239*2 141*17 276 0*0884702 13410.? 11119*6 147*30

207 0.118359 11964.1 10251-9 141*27 277 0*0881484 13431*1 11132.1 1 4^.37

208 0*117780 11985*1 10264*5 141*37 278 0*0878289 13452*0 11144*6 147.45

209 0*117207 12006.1 10277*1 141*47 279 0*0875118 13472*9 11157.2 147.52

210 0.116640 12027.2 10289.7 141.57 280 0.0871970 13493.8 11169.7 147.60

211 0.116078 12048.2 10302.3 141.67 281 0.0868844 13514.7 11182.3 147.67

212 0.115522 12069.2 10315.0 141 .77 282 0.0865741 13535.6 11194.8 147.75

213 0.114971 12090.2 10327.6 141.87 283 0.0862661 13556.5 11207.3 147.82

214 0.114425 12111.3 10340.2 141.97 284 0.0859602 13577.4 11219.9 147.89

215 0.H3885 12132.3 10352.8 142*06 285 0.0856565 13598.3 11232.4 147.97

216 0.113349 12153.3 10365.4 142.16 286 0.0853549 13619.2 11244.9 148.04

217 0.112819 12174.3 10378.0 142*26 2«7 0*0850555 13640*1 11257.5 148.11

218 0.112294 12195.3 10390*6 142*36 288 0*0847582 13661-0 11270*0 148.19

219 0.111774 12216.3 10403.2 142.45 289 0.0844630 13681.9 112«2.5 148.26

220 0.111258 12237.3 10415.8 142.55 290 0.0841698 13702.8 11295.1 148.33

221 0.110747 12258.3 10428.4 142.64 291 0.0838787 13723.7 11307.6 148.40

222 0.110242 12279.3 10441.0 142*74 292 0*0835896 13744.6 1 1 320 •

1

148*48

223 0.109740 12300.3 10453.6 142.83 293 0*0833024 13765.4 11332.7 148.55

224 0 • 10^244 12321*3 10466.2 142*93 294 0*0830173 13786.3 11345.2 148.62

225 0.108751 12342.3 10478.8 143.02 295 0-0827341 13807*2 11357.7 148.69

226 0 . 108264 12363*3 10491*4 143.11 296 0*0824529 13828*1 11370.3 148*76

227 0.107761 12384*2 10504.0 143.21 297 0 • 082 1 736 13849.0 11382*8 148.83

228 0.107302 12405.2 10516.6 143.30 298 0.0818961 13869.9 11395.3 148.90

229 0.106827 12426.2 10529.2 143.39 299 0.0816206 13890.7 11407.9 148.97

230 0.106357 12447*2 10541.8 143*48 300 0*0813469 13911.6 11420.4 149.04

66
3.oo atmosphere: isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITFR J/MOL ENERGY J/MOL-K

J/MOL

86 35.1036 2918.2 2909.6 53.91

87 34.9524 2963.9 2955.2 54.44

88 34.7994 3000.7 3001.0 54.96

89 34.6447 3055.8 3047.0 55.48

90 34.4883 3102.1 3093.2 56.00

TFMP. density ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

91 34.3301 3148.5 3139.7 56.51

02 34.1703 3195.2 3186.3 57.02

93 34.0089 3242.0 3233.1 57.53

94 33.8458 3289.0 3280.1 58.03

95 33.6811 3336.3 3327.2 58.53

96 33.5147 3383.6 3374.6 59.03

97 33.3466 3431.2 3422.1 59.52

98 33.1768 3478.9 3469.8 60.01

99 33.0053 3526.8 3517.6 60.50

# 99.156 32.9783 3534.3 3525.1 60.5?

* 99 . i 56 0.397624 9587.3 8822,8 121.62

100 0.393495 9607.3 8834.8 121.82

101 0.388728 9631.0 8849.0 122.06

102 0*384092 9654.6 8863.2 122.29

103 0*379583 9678*2 8877*3 122*52

104 0*375193 9701*6 8891.4 122*74

105 0-370918 9725*6 8905*5 122.97

106 0.366753 9748.3 8919.5 123.19

107 0.362693 9771*6 8933*4 123.41

108 0.358733 9794.7 8947.4 123.62

109 0.354870 9817.9 8961.2 123,84

110 0.351100 9840.9 8975.1 124.05

111 0.347418 9863.9 8988,9 124.25

112 0.343822 9886.8 9002*7 124.46

113 0*340309 9909.7 9016*5 124.66

114 0*336874 9932.6 9030.2 124.87

115 0*333516 9955.3 9043.9 125.06

116 0.330231 9978.1 9057.5 125.26

117 0.327017 10000.7 9071.2 125.46

118 0.323871 10023.4 9084.8 125.65

119 0*320791 10046.0 9098*4 125*84

120 0*317775 10068.

5

9111.9 126*03

121 0.314821 10091.0 9125.5 126.21

122 0.311926 10113.5 9139.0 126.40

123 0.309089 10135.9 9152.5 126.58

124 0.306307 10158.3 9165.9 126.76

125 0.303580 10180.7 9179.4 126.94

126 0*300904 10203*6 9192*8 127.12

127 0*298280 10225*3 9206.2 127.30

128 0*295704 10247.5 9219.6 127.47

129 0*293176 10269*8 9232*9 127.64

130 0*290695 10292*0 9246*3 127.82

131 0.288258 10314.1 9259.6 127.99

132 0.285865 10336.3 9272.9 128.15

133 0.283514 10358.4 9286.2 128.32

134 0.281205 10380.4 9299,4 128.49

135 0*278935 10402.5 9312.7 128.65

136 0*276704 10424.5 9325.9 128.81

137 0.274511 10446.5 9339.1 128.97

138 0.272355 10468.5 9352.3 129.13

139 0.270234 10490.4 9365.5 129.29

140 0.268149 10512.3 9378.7 129.45

141 0.266097 10534.2 9391.9 129.61

142 0*264079 10556.1 9405.0 129.76

143 0*262093 10578*6 9418.1 129.91

144 0*260138 10599*8 9431.3 130.07

145 0.258214 10621.6 9444.4 130.22

146 0.256320 10643,4 9457,5 130,37

147 0.254454 10665.2 9470.6 130.52

148 0.252618 10687.0 9483.6 130.66

149 0.250809 10708.7 9496.7 130.81

150 0-249027 10730*4 9509.7 130.95

151 0.247272 10752.1 9522.8 131.10

152 0.245542 10773.8 9535.8 131.24

153 0*243838 10795*5 9548.8 131*38

154 0*242158 10817.1 9561 *8 131*52

155 0.240503 10838.8 9574.8 131*66

156 0.238871 10860.4 95«7.8 131.80

157 0.237262 10882.6 9600*8 131*94

158 0*235675 10903.6 9613.8 132.08

159 0*234111 10925.2 9626.7 132.22

160 0.232568 10946.8 9639.7 132.35

PHASE changf 67
3.00 ATMOSPHERE IS08AR

TEMP.

K DENSITY

MOL/LITER

ENTHALPY

J/MOL

internal

energy

J/MOL

entropy

J/MOL-K

temp.

K DENSITYmol/liter

ENTHALPY

J/MOL

INTERNAL

energy

J/MOL

entropy

J/MOL-K

161 0.231046 10968.3 9652.6 132.48 231 0.159118 12456.1 10545.7 140.16

162 0. 2295*5 10989.9 9665.6 132.62 232 0.158419 12477.2 10558.3 140.25

163 0. 228084 11011.4 9678.5 132.75 233 0.157726 12498,? 10570.9 140.34

164 0.226603 11032.9 9691 .4 132.88 234 0.157040 12519.3 10583.6 U0.43

165 0.225162 11054.4 9704.3 133.01 235 0.156360 12540.3 10596.2 140.52

166 0,223739 11075.9 9717.2 133.14 236 0.155685 12561.4 10608,8 U0.61

167 0.222335 11097.4 9730.1 133.27 237 0.155017 12582.4 10621.5 140 ,70

168 0.220949 11118.8 9743.0 133.40 238 0.154354 12603.5 10634.1 140.79

169 0*219581 11140*3 9755*9 133*53 239 0*153697 12624.5 10646*7 140.88

170 0.218230 11161.7 9768*8 133.65 240 0.153046 12645.6 10659.4 140.97

171 0.216896 11183.2 9781.7 133.78 241 0.152400 12666.6 10672.0 141.06

172 0.215580 11204.6 9794.5 133*90 242 0.151760 12687-7 10684.6 141.14

173 0.214279 11226.0 9807*4 134.03 243 0-151125 12708.7 10697.2 141.23

174 0.212995 11247.4 9820.2 134.15 244 0*150495 12729.7 10709.8 141.32

175 0.211727 11268.8 9833*1 134.27 245 0*149871 12750*8 10722*5 141*40

176 0.210474 11290.2 9845.9 134.40 246 0.149252 12771.

A

10735.1 141 .49

177 0.209237 11311.6 9858.8 134.52 247 0.148638 12792.8 10747.7 141.57

178 0.208014 11332.9 9871.6 134.64 248 0.148030 12813.8 10760.3 141.66

179 0.206806 11354.3 98H4.4 134.76 249 0*147426 12834.9 10772.9 141.74

180 0.205613 11375.6 9897.2 134.88 250 0*146827 12855.9 10785*5 141.03

181 0,20*434 11397.0 9910.0 134.99 251 0.146234 12876.9 10798.1 141.91

182 0.203268 11416.3 9922.8 135.11 252 0*1 45645 12897.9 10810.7 1 4 1 .99

183 0*202116 11439*6 9935*6 135*23 253 0*145061 12918*9 10823*4 142*08

184 0*200978 11461.0 9948*4 135.35 254 0.144481 12939.9 10836.0 142.16

185 0.199852 11482.3 9961 .2 135.46 255 0.143907 12960.9 10848.6 142.24

186 0.198740 11503.6 9974,0 135.58 256 0,143336 12981.9 10861.2 142.32

187 0.197640 11524.9 9986.8 135.69 257 0.142771 13002.9 10873.8 142.41

188 0.196553 11546.1 9999.6 135.80 258 0.142210 13023.9 10886.4 142.49

1 89 0.195478 11567.4 10012.3 135.92 259 0.141653 13044.9 10899.0 142.57

190 0.194415 11588.7 10025.1 136.03 260 0.141101 13065.

R

10911.5 142.65

191 0.193364 11610.0 10037.9 136.14 261 0.140553 13086.9 10924,1 142.73

192 0.192324 11631.2 10050.6 136.25 262 0.140010 13107.9 10936.7 142.81

193 0.191296 11652.5 10063.4 136.36 263 0.139470 13128.

Q

10949.3 142.89

194 0.190279 11673.7 10076.1 136.47 264 0.138935 13149.9 10961.9 142.97

195 0.189273 11694.9 10088.9 136.58 265 0.138404 13170.8 10974.5 143.05

1 96 0.188278 11716.2 10101.6 136.69 266 0.137877 13191.9 10987.1 143.13

197 0.187294 11737.4 10114.4 136.80 267 0.137354 13212.8 10999.7 143.21

198 0.186320 11758.6 10127.1 136.90 268 0.136835 13233.8 11012.3 143.29

199 0.185356 11779.8 10139.8 137.01 269 0.136320 1325A.R 11024.9 143.36

200 0.184403 11801.0 10152.6 137.12 270 0.135809 13275.7 11037.4 143.44

201 0.183460 11822.2 10165.3 137.22 271 0.135302 13296.7 11050.0 143.52

202 0.182526 11843.4 10178.0 137.33 272 0.134799 13317.7 11062.6 143.60

203 0.181602 11864.6 10190.7 137.43 273 0.134299 13338.7 11075.2 143.67

204 0.180688 11885.8 10203.4 137.54 274 0*133803 13359.6 11087.8 143.75

205 0*179783 11907*0 10216.2 137*64 275 0*133311 13380*6 11100*3 143.83

206 0.178887 11928.2 10228.9 137.74 276 0.132823 1 340 1.5 11112.9 143.90

207 0.178000 11949.3 10241.6 137.85 277 0.132338 13422.5 11125.5 143.98

208 0*177123 11970*5 10254.3 137.95 278 0.131856 13443.5 11138.1 144.05

209 0 • 176254 11991.7 10267*0 138*05 279 0*131379 13464.4 11150.6 144*13

210 0*175393 12012.8 10279.7 138.15 2R0 0*130904 13485.4 11163.2 144.20

211 0.174542 12034.0 10292.4 138.25 281 0.130433 13506.3 11175.8 144.28

212 0.173698 12055.1 10305.0 138.35 282 0.129966 13527.3 11188.4 144.35

213 0.172863 12076.2 10317.7 138.45 283 0.129502 13548.3 11200.9 144.43

214 0.172036 12097.4 10330.4 138.55 284 0.129041 13569.2 11213.5 144.50

215 0.171217 12118.5 10343.1 138.65 285 0.128583 13590.2 11226.1 144.57

216 0.170406 12139.6 10355.8 138.75 286 0.128129 13611.1 11238.6 144.65

217 0.169603 12160.8 10368.5 138,84 287 0.127678 13632.0 11251,2 144.72

218 0.168808 12181.9 10381,1 138.94 288 0.127230 13653,0 11263,8 144.79

219 0.168020 12203.0 10393.8 139.04 280 0.126786 13673.9 11276.3 144.87

220 0.167240 12224.1 10406.5 139.13 290 0.126344 13694.9 11288.9 144.94

221 0.166466 12245.2 10419.1 139.23 291 0.125906 13715.8 11301.5 145.01

222 0.165701 12266.3 10431.8 139.32 292 0*125470 13736.8 11314.0 145.08

223 0.16*942 12287.4 10444.5 139.42 293 0.125038 13757.7 11326.6 145.15

224 0.164190 12308.5 10457.1 139.51 294 0.124609 13778.6 11339.1 145.23

225 0.163446 12329.6 10469.8 139.61 295 0.124182 13799.6 11351.7 145.30

226 0.162708 12350.7 10462.4 139.70 296 0.123759 13820.5 11364.3 145.37

227 0.161977 12371.8 10495.1 139.79 297 0.123338 13841 .4 11376.8 145.44

226 0.161252 12392.9 10507.7 139.89 298 0.122921 13862.4 11389.4 145.51

229 0.160534 12413.9 10520.4 139.98 299 0.122506 13883.3 11401.9 145.58

230 0.159823 12435,0 10533.0 140.07 300 O.I 22 O 94 13904.? 11414.5 145.65

68
4.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITF.H J/MOL ENERGY J/MOL-K

J/MOL

86 35.1113 2920.0 2908.5 53.90

87 34.9602 2965.7 2954.1 54.43

88 34.8074 3011*5 2999.9 54.95

89 34.6529 3057.6 3045.9 55*47

90 34.4966 3103*8 3092.0 55.99

PHASE change

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENFRGY

J/MOL

J/MOL-K

91 34.3387 3150.2 3138.4 56.50

92 34.1791 3196,9 3185.0 57.01

93 34.0179 3243.7 3231.8 57.52

94 33.8550 3290.7 3278.7 58.02

95 33.6906 3337. <5 3325.8 58.52

96 33.5244 3385.2 3373.1 59.01

97 33.3566 3432.7 3420.6 59.51

98 33.1871 3480.4 3468.2 60.00

99 33.0158 3528.3 3516.0 60.48

100 32.8428 3576.3 3564.0 60.97

101 32.6679 3624.5 3612.1 61.44

102 32,4911 3672.9 3660.4 61.92

102.855 32.3384 3714.3 3701.8 62.33

102*855 0*520302 9617.6 8838*6 119.72

103 0*519345 9621.2 8840*8 119.75

104 0.512883 9645.9 8855.6 119.99

105 0.506612 9670.4 8870.4 120,23

106 0.500522 9694,9 8885.1 120.46

107 0,494603 9719.2 8899.7 120.69

108 0,488849 9743.4 8914.3 120.91

109 0.483250 9767.5 8928.8 121.14

110 0,477800 9791.6 8943.3 121,36

111 0.472493 9815.5 8957.7 121.57

112 0.467321 9839.3 8972.0 121.79

1)3 0.462279 9863.1 8986.3 122.00

114 0.457361 9886.8 9000.6 122.21

115 0.452563 9910.4 9014.8 122.41

116 0.447879 9933.9 9029.0 122.62

117 0.443305 9957.4 9043*1 122.82

118 0.438837 9980.8 9057,2 123.02

119 0.434469 10004.1 9071.2 123.21

120 0.430200 10027,3 9085.2 123.41

121 0.426024 10050.5 9099.2 123.60

122 0.421939 10073,7 9113.1 123.79

123 0.417941 10096.7 9127.0 123,98

124 0.414028 10119.8 9140.8 124.17

125 0.410196 10142,7 9154.6 124.35

126 0.406442 10165.7 9168.4 124.53

127 0.402764 10188.5 9182.2 124.71

128 0.399159 10211,3 9195.9 124,89

129 0.395625 10234.1 9209.6 125.07

130 0,392160 10256.8 9223.3 125.24

131 0.388762 10279.5 9236.9 125.42

132 0.385427 10302.2 9250.6 125,59

133 0.382155 10324,7 9264.2 125.76

134 0.378944 10347,3 9277.7 125.93

135 0.375791 10369.8 9291.3 126,10

136 0*372695 10392.3 9304.8 126.26

137 0.369654 10414.8 9318.3 126.43

138 0*366667 10437,2 9331.8 1?6.59

139 0*363733 10459.5 9345*2 126*75

140 0.360848 10481 .9 9358*7 126.91

141 0.358013 10504.2 9372.1 127.07

142 0*355226 10526.5 9385*5 127.23

143 0*352486 10548.7 9398*9 127.39

144 0.349790 10571.0 9412.2 127.54

145 0.347139 10593.1 9425.6 127.69

146 0,344531 10615,3 9438.9 127.85

147 0.341965 10637.4 9452.2 128.00

148 0.339439 10659.6 9465.5 128.15

149 0.336953 10681.6 9478.8 128.30

150 0.334506 10703.7 9492.0 128.44

151 0.332097 10725.7 9505.3 128.59

152 0.329724 10747.7 9518.5 128.73

153 0*327388 10769*7 9531-7 128*88

154 0*325086 10791.7 9544.9 129.02

155 0.322819 10813.7 9558.1 129.16

156 0.320585 10835.6 9571.3 129.31

157 0.318384 10857.5 9584.5 129.45

158 0.316215 10879.6 9597.6 129. 5R 159 0*314076 10901*2 9610*7 129. 72 160 0*311969 10923*1 9623*9 129.86

69
161

16 ? 163

164

1 65

166

167

168

169

170

171 172

173

174

175

176

177

178

179

1 80

181

1 8?

183

184

185

186

187

188

189

190

191 19?

193

184

195

196

197

198

199

200

201

20?

?03

204

205

206

207

208

209

210

21 1 21 ? 213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

4.00 atmosphere ISOBAR

DENSITY

MOL/LI TEH ENTHALPY

J/MOL

INTERNAL

energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITYmol/liter

ENTHALPY

J/MOL

INTERNAL

energy

J/MOL

entropy

J/MOL-K

0.309891 10944.9 9637.0 130.00 231 0.212534 12444.0 10537.0 137.73

0,307842 10966.7 9650.1 130.13 23? 0.211595 12465.2 10549.7 137.82

0.305821 10938.5 9663.2 130.26 233 0.210664 12486.3 10562.4 137.92

0.303829 11010.3 9676.3 130.40 234 0.209742 12507.5 10575.0 138.01

0-301863 11032.0 9689.3 130.53 235 0.208828 12528.6 10587.7 138.10

0.299924 11053.8 9702.4 130*66 236 0.207922 12549.8 10600*4 138.19

0*298012 11075.5 9715*4 130*79 237 0-207024 12570*9 10613*1 138-28

0.296124 11097*2 9728*5 130*92 238 0*206134 12592.1 10625.8 138.36

0*294262 11118.9 9741*5 131*05 239 0*205251 12613*2 10630*5 138.45

0*292424 11140*6 9754*5 131*18 240 0*204376 12634*3 10651*2 138*54

0.290611 11162.2 9767.5 131.30 241 0.203509 12655.4 10663.8 138.63

0.288820 11183.9 9780.5 131.43 242 0.202649 12676.6 10676.5 138.72

0*287053 11205.5 9793*5 131 .56 248 0 *20 ! 797 12697.7 10609 •

2

138*80

0-285308 11227*1 9806.5 131*68 244 0*200952 12710.8 10701 «R 138.89

0.283585 11248.7 9819.5 131.80 245 0.200114 12739.9 10714.5 138.98

0.28 1884 11270.3 9832.5 131.93 246 0.199283 12761.0 10727.2 139.06

0.280204 11291.9 9845.4 132.05 247 0.198460 12782.1 10739.8 139.15

0.278545 11313.5 9858.4 132.17 248 0.197643 12803.2 10752.5 139.23

0.27&906 11335.0 9871.3 132.29 249 0.196833 12824.3 10765.2 139.32

0.275238 11356.6 9884.3 132.41 250 0.196029 12845.4 10777.8 139.40

0.273688 11378.1 9897.2 132.53 251 0.195233 12866.5 10790.5 139.49

0.272109 11399.6 9910.1 132.65 252 0.194443 1 2a87 ,

6

10803.1 139.57

0.270548 11421.1 9923.0 132.77 253 0.193659 12908.7 10815.8 139.65

0.269005 11442.6 9935.9 132.89 254 0-192882 12929.8 10820.4 139.74

0.267481 11464.1 9948.8 133.00 255 0-192111 12950.8 10841.1 139.8?

0.265974 11485.6 9961.7 133.12 256 0.191346 12971 .9 10853.7 139.90

0.264486 11507.1 9974.6 133.23 257 0.190588 12993.0 10866.4 139.99

0.263014 11528.5 9987.5 133.35 ?5R 0.189835 13014,1 10879.0 140.07

0.261559 11550.0 10000.4 133.46 259 0.189089 13035.1 10891.6 140.15

0.260121 11571.4 10013.3 133.57 260 0.188348 13056.2 10904.3 UO .23

0.258699 11592.8 10026.1 133.69 261 0.187614 13077.3 10916.9 140.31

0.257293 11614.3 10039.0 133*80 262 0-186885 13090.3 10929.5 140.39

0. 255903 11635.7 10051.8 133.91 263 0*186162 13] 19.4 10942.2 140.47

0.254529 11657.1 10064.7 134.02 264 0*185445 13140*4 10954.8 140.55

0.253169 11678.5 10077*5 134.13 265 0*184733 13161*5 10967*4 140.63

0.251825 11699.8 10090*4 134.24 266 0*184027 13182.5 10980.1 140.71

0*250495 11721.2 10103*2 134*35 267 0*183326 13203.6 10992*7 140*79

0*249180 11742.6 10116*0 134.46 26 a 0.182630 13224.6 11005-3 140.87

0-247879 11764*0 10120.8 134.56 260 0*181940 13245.7 11017*9 140.95

0.246591 11785.3 10141.7 134*67 270 0*181255 13266.7 11030.6 141*02

0.245318 11806.6 10154.5 134.78 ?7

1

0.180576 13287.7 11043.2 141.10

0.244058 11«28.0 10167.3 134.88 272 0.179901 13308.0 11055.8 141.18

0.242811 11849.3 10180.1 134.99 273 0.17923? 13329.8 11068.4 141.26

0.241578 11870*6 10192*9 135.09 274 0*178568 13350.0 11081-0 141.33

0.240357 11891.9 10205.7 135.20 275 0*177908 13371.R 11093.6 141.41

0.239149 11913.3 10218.5 135.30 276 0*177254 13392.9 11106.3 141 .49

0.237953 11934.6 10231*2 135.40 277 0*176604 13413.9 11118.9 141.56

0.236770 11955.9 102*4.0 135.51 2 78 0.175960 13434.9 11131.5 141.64

0.235599 11977.1 10256.8 135.61 279 0.175320 13455.9 11144.1 141.71

0.234439 11990.4 10269.6 135.71 280 0.174684 13476.9 11156.7 141 . 79 0.233291 12019.7 10282.3 135.81 281 0.174054 13498.6 11169.3 141.86

0.232155 12041.0 10295.1 135.91 282 0.17342a 13519.0 11181,9 141.04

0.231030 12062.2 10307.9 136.01 283 0.172806 13540.0 11194.5 142.01

0.229916 12083.5 10320.6 136.11 284 0.172189 13561.0 11207.1 142.09

0.228813 12104.7 10333.4 136.21 285 0.171577 13582.0 1 1 ? ] 9 ,

7

’42.16

0.227721 12126.0 10346.1 136.31 ?R6 0.170968 13603.0 11232.3 142.23

0,226640 12147.2 10358.9 136.41 287 0.170365 13624.0 11244.9 142.31

0.225569 12168.4 10371.6 136.51 288 0.169765 13648.0 11257.5 142.38

0.224508 12189.7 10384.3 136.60 289 0.169170 13666.0 11270.1 142.45

0.223458 12210.9 10397.1 136.70 290 0.168579 13687.0 11282.7 142.53

0.222418 12232.1 10409.8 136.80 ?9

1

0.167992 13708.0 11295.3 142.60

0.221387 12253.3 10422.5 136.89 29? 0.167409 13729.0 11307.9 142.67

0.220366 12274.5 10435.3 136.99 293 0.166831 13750.0 11320.5 142.74

0.2)9355 12295.7 10448*0 137.08 294 0-166256 13770.9 11333*1 142.81

0.218353 12316.9 10460*7 137.18 295 0.165685\ 13791.9 11345.7 142.88

0.217361 12338.1 10473.4 137.27 296 0.165119 \ 13812.9 11358.2 142.96

0.216378 12359.3 10486.1 137.36 297 0.1 64556 13833.9 11370.8 143.03

0.215404 12380.5 10498.8 137.46 298 0.163997 1385* .

9

11383.4 143.10

0.214438 12401.7 1051 1.6 137.55 299 0.16344? 13875.9 11396.0 143.17

0.213482 12422.8 10524.3 137.64 300 0.162890 13896.8 11408.6 143.24

70
5.00 atmosphere isobar

TFMP.

K DENSITY ENTHALPY INTtRNAL ENTROPY

MOL/LITFR J/MOL ENERGY J/MOL-K

J/MOL

86 35.1189 2921.9 2907.4 53.89

87 34.9680 2967.5 2953.0 54.41

88 34.81&4 3013.3 2998.7 54.94

89 34.6610 3059.3 3044.7 55.46

90 34.5050 3105.5 3090*8 55.97

6

*

TEMP. DENSITY ENTHALPY internal entropy

K moi. /liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.3472 3151.9 3137.2 56.49

92 34.1879 3198.5 3183*7 57.00

93 34.0269 3245,3 3230.5 57.50

94 33.8642 3292.3 3277.4 58.01

95 33.7000 3339.5 3324.4 58.50

96 33*5341 3386*8 3371.7 59.0 0 97 33.3665 3434.3 3419.1 59.49

98 33.1973 3482.0 3466.7 59.98

99 33.0263 3529,8 3514.5 60.47

100 32.8536 3577.8 3562.4 60.95

101 32.6790 3625.9 3610.4 61.43

102 32.5026 3674.3 3658.7 61.90

103 32.3242 3722.8 3707.1 62,38

104 32.1437 3771.4 3755.6 62.85

105 31.9612 3820.2 3804.4 63.31

105.926 31.7901 3865*6 3849*7 63.74

105.926 0.642163 9636.4 8847.5 118.22

106 0.641553 9638.3 8848.6 118.24

107 0.633*00 9663.9 8864.1 118.48

108 0.625501 9689.4 8879.4 118.72

109 0.617842 9714.7 8894.7 118.95

110 0.610410 9739.8 8909.8 119.18

111 0.603193 9764.9 8924.9 119.41

112 0.596181 9789.7 8939.9 119.63

113 0.589364 9814.5 8954.9 119.85

114 0.582732 9839.1 8969.7 120.07

115 0.576276 9863.7 8984.5 120.28

116 0*569989 9888.1 8999.2 120.49

117 0.563862 9912*4 9013.9 120.70

118 0.557890 9936.6 9028.5 120.91

119 0.552064 9960,8 9043.0 121.11

120 0.546380 9984.8 9057.5 121.31

121 0.540831 10008.7 9072.0 121.51

122 0.535412 10032.6 9086.3 121.71

123 0.530117 10056.4 9100.7 121.90

124 0.524942 10080.1 9115.0 122.10

125 0.519883 10103.7 9129.2 122.29

126 0.514934 10127.3 9143.4 122.47

127 0,510092 10150.8 9157.5 122.66

128 0.505353 1017*.

2

9171.7 122.84

129 0.500714 10197.6 9185.7 123.02

130 0.496170 10220.9 9199.8 123.20

131 0.491718 10244.1 9213.8 123.38

132 0*487357 10267.3 9227*7 123.56

133 0.483081 10290.4 9241.7 123.73

134 0.478889 10313.5 9255.5 123.91

135 0.474778 10336.5 9269.4 124*08

136 0.470745 10359.5 9283.2 124.25

137 0*466788 10382-4 9297*0 124.41

138 0*462904 10405.3 9310*8 124.58

139 0.459092 10428-1 9324.5 124.75

140 0.4553*9 10450.9 9338.3 124.91

141 0.451673 10473.6 9352.0 125.07

142 0.448061 10496.3 9365.6 125.23

143 0.444513 10519.0 9379.3 125.39

144 0.441027 10541.6 9392.9 125.55

145 0.437599 10564.2 9406.5 125.70

146 0.434230 10586.8 9420.0 125.86

147 0.430918 10609.3 9433.6 126.01

148 0.427660 10631.8 9447.1 126.17

149 0*424455 10654.2 9460*6 126.32

150 0.421303 10676.6 9474.1 126.47

151 0.418201 10699.0 9487.5 126.62

152 0.4151*8 10721.4 9501.0 126.76

153 0.412143 10743.7 9514.4 126.91

154 0*409185 10766*0 9527-8 127*05

155 0.406273 10788.2 9541.2 127.20

156 0.403405 10810.5 9554.6 127.34

157 0.400580 10832.7 9567.9 127.48

158 0.397798 10854.8 9581.2 127.62

159 0.395057 10877.6 9594.6 127.76

160 0.392357 10899.1 9607.9 127.90

PHASE CHANGE 71
161

16 ? 163

164

165

166

167

168

169

170

171 17?

173

174

175

176

177

178

179

180

181 18?

183

184

185

186

187

188

189

190

191 19?

193

194

195

196

197

198

199

?00

201

20 ? 203

204

205

206

207

208

209

210

211

21 ? 213

214

215

216

217

2)8

21 9 220

221 222

223

224

225

2?6

227

228

229

230

5.00 ATMOSPHERE ISOBAR

DENSITY

mol/litek

0.389696

0.387073

0.384488

0.381939

0.379427

0.376949

0.374506

0.372096

0.369719

0.367374

0.365061

0.362778

0.360526

0.358302

0.386108

0.353942

0.351804

0.349692

0.347608

0.345549

0.343516

0.341508

0.339524

0.337565

0.335629

0.333717

0.331827

0.329959

0.328113

0.326289

0.324486

0.322704

0.320942

0*319200

0.317477

0 , 3 J 5774

0. 31*090

0.312424

0.310777

0.309148

0.307536

0*305942

0.304365

0.302804

0.301261

0.299733

0.298221

0.296726

0.295245

0.293780

0.292330

0.290894

0.239473

0.288067

0.286674

0.285296

0.283930

0*282579

0.281240

0.279915

0.27860?

0.27730?

0.276015

0.274739

0.273476

0.272225

0.270985

0.269757

0.268541

0.267335

ENTHALPY

J/MOL INTERNAL energy

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

mol/liter

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

J/MOL-K

10921.2 9621.2 128.04 231 0.266141 12431.9 10528.2 135.84

10943.3 9634.4 128.18 232 0.264958 12453.1 10541.0 135.93

10965.4 9647.7 128.31 233 0.263785 12474.4 10553.7 136.02

10987.4 9660.9 128.45 234 0.262623 12495.6 10566.5 136.11

11009.4 9674.2 128.58 235 0.261472 12516,9 10579.2 136.21

11031.4 9687.4 128.71 236 0.260330 12538.1 1 0592.0 136.30

11053.4 9700.6 128.85 237 0.259199 12559.4 10604.7 1.36,39

11075.4 9713.8 128.99 238 0.258078 12580.6 10617.5 136.47

11097.3 9727.0 129.11 239 0.256967 12601.8 1 0630 •

2

136.56

11119.2 9740.1 129.24 240 0.255866 12623.0 10642.9 136.65

11141.1 9753.3 129.37 241 0.254774 12644.2 10655.7 136.74

11163.0 9766.4 129.49 ?42 0.253692 12665.4 10668.4 136.83

11184.8 9779.6 129.62 243 0.252619 12686.7 10681.1 136.9?

11206.7 9792.7 129.75 244 0.251555 12707.9 10693.8 137.00

11228.5 9805.8 129.87 245 0.250501 12729.0 10706.5 137.09

11250.3 9818.9 129.99 246 0.249455 12750.2 10719.3 137.1

8

11272.1 9832.0 130.12 247 0.?4q4ig 12771.4 10732.0 137.26

11293.9 98*5.1 130.24 248 0.247391 12792,6 10744.7 137.35

11315.6 9658.1 130.36 240 0.246372 12813.8 10757.4 137.43

11337.4 9871.2 130.48 250 0.245361 12835.0 10770.1 137.52

11359.1 9884.2 130.60 251 0.244359 12856.1 10782.8 1? 7 .60

11380.8 9897.3 130.72 252 0.243366 12877.3 10795.5 137.69

11402.5 9910.3 130*84 253 0*242380 12898.5 10808.2 137.77

11424.2 9923.3 130.96 254 0.241403 12919.6 10820*9 137.85

11445.9 9936*4 131*08 255 0*240433 129&C.8 10833-6 137.94

11467.5 9949.4 131.20 256 0.239472 12961 .9 10846.3 13«.02

11489.2 9962.4 131.31 257 0.238518 12983.1 1 0858 .

9

138.10

11510.8 9975.4 131.43 258 0.237572 13004.2 10871.6 138.18

11532.4 9988,3 131.54 259 0,236634 13025.3 10884.3 138.27

11554.0 10001.3 131.66 260 0.235703 13046.5 10897.0 138.35

1 1575.6 10014.3 131.77 261 0.234780 13067.8 10909.7 138.43

11597.2 10027.2 131.88 262 0.233864 13088.7 10922.3 138.51

11618.8 10040*2 131*99 263 0*232955 13109.9 10935.0 138.59

11640*4 10053*1 132-11 264 0.232053 13131.0 10947*7 118.67

11661.9 10066.1 132-22 265 0.231159 13152.1 10960.4 138.75

11683.5 10079.0 132.33 266 0.230271 13173.2 10973.0 138. R3

11705.0 10091,9 132.44 267 0.229391 13194,3 10985.7 138.91

11726.5 10104.9 132.54 268 0.228517 13215.4 1099R.4 138,99

11748.0 10117.8 132.85 269 0.227650 13236.5 UOU .0 139.07

11769.5 10130.7 132.76 270 0.226790 13257.6 11023.7 139.14

11791.0 10143.6 132.67 271 0.225936 13278.7 11036.3 139.22

11812.5 10156.5 132.97 27? 0 • 225089 13299.

R

11049.0 139.30

11833.9 10169.4 133.08 273 0.224248 13320.9 11061.6 139.38

1 1855.4 10182.2 133.19 274 0.223414 13342.0 11074.3 139.45

11876.9 10195.1 133.29 275 0.222586 13363.1 11086.9 139.53

11898.3 10208.0 133,40 276 0.221764 13384.2 11099.6 139.61

11919.7 10220.9 133.50 277 0.220948 13405.3 11112.2 139.68

11941.2 10233.7 133.60 278 0.220138 13426.3 11124.9 139.76

11962.6 10246.6 133.71 2 79 0.219335 13447.4 11137.5 139.84

11984.0 10259.4 133.61 280 0.218537 13468.5 11150.2 139.91

12005.4 10272.3 133.91 281 0.217745 13489.6 11162.8 139.99

12026.8 10285.1 134.01 282 0.216959 13510.6 11175.5 140.06

12048.2 10297.9 134.11 283 0.216179 13531.7 11188.1 140.14

12069.5 10310.8 134.21 284 0.215405 13552.R 11200.7 140.21

12090.9 10323.6 134.31 285 0.214636 13573.8 11213.4 140.28

12112*3 10336.4 134-41 ?R6 0.213872 13594.0 11226.0 140.36

12133.6 10349*2 134.51 287 0*213114 13615.9 112.38.6 140.43

12155.0 10362*1 134*61 ?88 0*212362 13637.0 11251*3 140.50

12176-3 10374.9 134.70 ?89 0*211615 1365R.0 11263*9 U0.58

12197.6 10387.7 134.80 290 0.210873 13679.1 11276.5 140.65

12219.0 10400.5 134.90 ?9\ 0.210137 13700.1 1 1 ?R9 .

1

140.7?

12240.3 10413.3 134.99 ?°? 0.209405 13721.2 11301.8 140.79

12261.6 10426.0 135.09 293 0 • ?08679 13742.2 11314.4 140.87

12282.9 10438.8 135.19 294 n. 207958 13763.2 11327.0 140.94

12304.2 1C451 .6 135.28 ?9S 0*207242 13784.3 11339.6 141.01

12325.5 1 0464 .

4

135.37 ?°6 0.206531 1 3R05.3 11352.2 141.08

12346.8 10477.2 135.47 297 0.205825 13826.3 11364.8 141.15

12368.1 10489.9 135.56 29R 0.205124 13847.4 11377.5 141.22

12389.3 10502.7 135.66 299 0.204428 1 386R.4 11300.1 U1.29

12410,6 10515.5 135.75 300 0.203736 13889.4 11402.

7

141.36

72
6.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/litfr J/MOL ENERGY

J/MOL

J/MOL-K

86 35.1265 2923.7 2906.4 53.88

87 34.9758 2969.3 2951.9 54.40

88 34,8233 3015.1 2997.6 54.93

89 34.6692 3061.1 3043.5 55.45

90 34.5133 3107.3 3089.6 55.96

tfmp. DENSITY ENTHALPY INTERNAL Entropy

K mol/liter J/MOL ENERGY

J/MOL

J/mOL-K

91 34.3557 3153.7 3136.0 56.47

92 34.1966 3200.2 3182.5 56.98

93 34.0358 3247.0 3229.1 57.49

94 33.8734 3293.9 3276.0 67.99

95 33.7094 3341.1 3323.0 58.49

96 33.5438 3388.4 3370.3 58.98

97 33.3765 3435 ,

8

3417.6 59.48

98 33.2075 3483.5 3465.2 59.97

99 33*0368 3531*3 3512*9 60.45

100 32*8644 3579*2 3560*7 60*93

101 32.6901 3627.4 3608.8 61 .41 102 32.5140 3675.7 3657.0 61.89

103 32*3360 3724.1 3705.3 62.36

104 32.1559 3772*7 3753.8 62.83

105 31*9738 3821*5 3802*5 63.30

106 31*7894 3870*4 3851*3 63.76

107 31.6028 3919.6 3900.3 64.22

106 31*4138 3968.9 3949.5 64.68

* 108.580 31*3031 3997.5 3978.1 64.94

* 108.580 0*763834 9647*7 8851*7 116.98

109 0*759613 9658*9 8858*5 117*08

110 0*749809 9685*4 8874*5 117*33

111 0.740324 9711.6 8890.4 117.56

112 0.731139 9737.7 8906.2 117.80

113 0*722237 9763*6 8921.8 118.03

114 0*713602 9789.4 8937.4 118.26

115 0.705222 9814.9 8952.8 118.48

116 0*697081 9840*4 8968*2 118.70

117 0*689169 9865*7 8983*5 118*92

118 0.681474 9890.8 8998.7 1 19.13

119 0.673986 9915.8 9013.8 119.34

120 0.666695 9940.7 9028.8 119.55

121 0.659592 9965.5 9043.8 119.76

122 0.652669 9990*2 9058.7 119.96

123 0*645918 10014.7 9073.5 120.16

124 0*639331 10039.2 9088.3 120.36

125 0*632902 10063.6 9103.0 120.55

126 0*626624 10087.8 9117.6 120.75

127 0*620491 10112*0 9132*2 120.94

128 0*614498 10136.1 9146*7 121.13

129 0*608638 10160.1 9161*2 121.31

130 0*602908 10184.6 9175*6 121.50

131 0.597301 10207.8 9190.0 121.68

132 0*591814 10231.6 9204.3 121.86

133 0*586442 10255.3 9218*6 122*04

134 0*581181 10278.9 9232*8 122.22

135 0*576028 10302*5 9247*0 122*39

136 0*570978 10326*0 9261*2 122*56

137 0*566028 10348*4 9275*3 122*74

138 0*561175 10372*8 9289 •

4

122*91

139 0*556416 10396*1 9303*4 123*07

140 0*551747 10419.4 9317*5 123*24

141 0.547166 10442.6 9331.4 123.41

142 0.542670 10465.7 9345.4 123.57

143 0.538257 10488.fi 9359,3 123.73

144 0.533923 10511.8 9373,2 123.89

145 0.529667 10534.8 9387.0 124.05

146 0.525486 10557.8 9400.8 124.21

147 0.521377 10580.7 9414.6 124.37

148 0.517340 10603.6 9428.4 124.52

149 0.513372 10626.4 9442.1 124.68

150 0.509470 10649.2 9455.8 124.83

151 0.505634 10671.9 9469.5 124.98

152 0.501861 10694.6 9483.2 125.13

153 0.498150 10717.3 9496.fi 125.28

154 0.494498 10739.9 9510.4 125.42

155 0.4Q0905 10762.5 9524.0 125.57

156 0.487369 10785.0 9537.6 125.72

157 0.483888 10R07.6 9551.1 125.86

158 0.480461 10fi30.1 9564.7 126.00

159 0.477087 1 0fi52 .

5

9578.2 126.14

160 0.473764 10P74.Q 95P1 .7 126.28

* phase change 73
6.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 0.470491 10897.3 9605.1 126.42 231 0.319939 12419.7 10519.5 134.29

162 0.4f-7267 10919.7 9618.6 126.56 232 0.318508 12441.1 10532,3 134,38

163 0.4*4091 10942.0 9632.0 126.70 233 0.317089 12462.5 10545.1 134.47

16A 0.460961 10964.4 9645.4 126.84 234 0.315684 12483.8 10557.9 134,56

165 0.457876 10986.6 9658.8 126.97 235 0.314291 12505.1 10570.7 134.65

1 66 0.454836 11008.9 9672.2 127.11 236 0.312911 12526.5 10583,5 134.74

167 0.451839 11031.1 9685.6 127.24 237 0.311544 12547.8 10596.3 134.83

168 0.448884 11053.3 9698.9 127.37 238 0.310189 12569.1 10609.1 134,92

169 0.445971 11075.5 9712.3 127.50 239 0.308846 12590.4 10621.9 135.01

170 0.443098 11097.7 9725.6 127.64 240 0,307514 12611.7 10634,7 135.10

171 0.440265 11119.8 9738.9 127.76 241 0.306195 12633.0 10647.5 135.19

172 0.437471 11141.9 9752.2 127.89 242 0.304887 12654.3 10660*3 135.28

173 0.434714 11164.0 9765.5 128.02 243 0.303591 12675.6 10673.0 135.37

174 0 .431994 11186.1 9778.7 128.15 244 0.302306 12696.9 10685.8 135.45

175 0.429310 11208.1 9792.0 128.28 245 0.301032 12718.2 10698.6 135.54

176 0.426662 11230.2 9805.2 128.40 246 0.299769 12739.4 10711.3 135.63

177 0,424049 11252.2 9818.4 128.53 247 0.298517 12760.7 10724.1 135.71

178 0.421469 11274.1 9831.7 128.65 248 0.297275 12782.0 10736.8 135.80

179 0.418923 11296.1 9844.9 128.77 249 0.296044 12803.2 10749.6 135.89

180 0.416409 11318.1 9858.0 128.89 250 0.294824 12824.5 10762.4 135.97

181 0.413927 11340.0 9871.2 129.02 251 0.293614 12845.7 10775.1 136.06

182 0.411477 11361.9 9884,4 129.14 252 0.292414 12867.0 10787.8 136.14

183 0.409057 11383.8 9897.5 129.26 253 0.291224 12888.2 10800.6 136.22

184 0.406667 11405.7 9910.7 129.38 254 0.290044 12909.4 10813.3 136.31

185 0.404307 11427.5 9923.8 129 . 4 9 255 0.288873 12930.7 10826.1 136.39

1 86 0.401975 1 1449,4 9936.9 129.61 256 0.287713 12951.9 10838.8 136.47

187 0.399672 11471.2 9950.0 129,73 257 0.286562 12973.1 10851.5 136.56

1 88 0.397396 11493.0 9963.1 129.85 258 0.285420 12994.3 10864.3 136.64

1 89 0.395148 11514.8 9976.2 129.96 259 0.284288 13015.5 10877.0 136.72

1 90 0.392926 11536.6 9969,3 130.0s 260 0,283164 13036.7 10889.7 136.80

191 0.390731 11558.4 10002.4 130.19 261 0.282050 13057.9 10902.4 136.88

192 0.388561 11580.1 10015.5 130.30 262 0.280945 13079.1 10915.1 136.97

193 0.386417 11601.8 10028.5 130.42 263 0.279848 13100.3 10927.9 137.05

194 0.384297 11623.6 10041.6 130.53 264 0.278761 13121.5 10940.6 137.13

195 0.382202 11645.3 10054.6 130.64 265 0.277682 13142.7 10953.3 137.21

196 0.380131 11667.0 10067.6 130.75 266 0.276611 13163.9 10966.0 137.29

197 0.378083 11688,7 10060.6 130,66 267 0.275549 13185.1 10978.7 137.37

198 0,376058 11710.3 10093.7 130.97 268 0.274495 13206.2 10991.4 137.44

199 0.374056 11732.0 10106,7 131.08 269 0.273449 13227.4 11004.1 137.52

200 0.372076 11753.6 10119.7 131.19 270 0.272412 13248.6 11016.8 137.60

201 0.370118 11775.3 10132.6 131.30 271 0.271382 13269.7 11029.5 137.68

202 0.368181 11796.9 10145.6 131.40 272 0.270361 13290.9 11042.2 137.76

203 0.366266 11818.5 10158.6 131*51 273 0*269347 13312.1 11054.9 137.84

204 0 • 364371 11840*1 10171*6 131*62 274 0*268341 13333*2 11067*6 137*91

205 0.362497 11861.7 10184.5 131*72 275 0*267342 13354.4 11080.2 137.99

206 0.360642 11883.3 10197.5 131.83 276 0.266352 13375.5 11092.9 138.07

207 0.358808 11904.8 10210.4 131.93 277 0,265368 13396.6 11105.6 138,14

208 0.356992 11926.4 10223.4 132.04 278 0.264392 13417.8 11118.3 138.22

209 0.355196 11948.0 10236.3 132.14 279 0.263424 13438.9 11131.0 138.30

210 0.353419 11969.5 10249.2 132.24 2R0 0,262462 13460.0 11143.6 138.37

211 0.351660 11991.0 10262.2 132.35 281 0.261508 13481.2 11156.3 138.45

212 0.349919 12012.5 10275.1 132.45 282 0.260560 13502.3 11169.0 138.52

213 0.348196 12034,0 10288.0 132.55 283 0.259620 13523.4 11181.7 138.60

214 0.349491 12055.5 10300.9 132.65 284 0.258687 13544.5 11194.3 138.67

215 0.344803 12077.0 10313.8 132.75 285 0.257760 13565.6 11207.0 138.75

216 0.343132 12098.5 10326.7 132.85 286 0.256840 13586.8 11219.7 138.82

217 0.341477 12120.0 10339.6 132.95 287 0.255927 13607.9 11232.3 138.89

218 0.339839 12141.4 10352.5 133.05 288 0.255020 13629.0 11245.0 138.97

219 0.338218 12162.9 10365.3 133.14 289 0.254120 13650.1 11257.6 139.04

220 0.339612 12184.3 10378.2 133.24 290 0.253227 13671.2 11270.3 139.11

221 0.335022 12205.8 10391.1 133.34 291 0.252339 13692.3 11283.0 139.18

222 0.333448 12227.2 10403.9 133*44 292 0.251459 13713.4 11295.6 139.26

223 0.331889 122 ^ 8.6 10416*8 133*53 293 0*250584 13734.5 11308.3 139.33

224 0.330345 1227C.1 10429.7 133.63 ?94 0.249715 13755.6 11320.9 139.40

225 0.328816 12291 .5 10442.5 133.72 295 0.248853 13776.6 11333.6 139.47

226 0.327301 12312.9 10455.3 1 33.82 296 0.247996 13797.7 11346,2 139.54

227 0.325801 12334.2 10468.2 133.91 297 0.247146 13818.8 11358.9 139.62

228 0*324315 12355.6 10481.0 134.01 298 0.246302 13839.9 11371.5 139.69

22 ° 0.322842 12377.0 10493.8 134.10 299 0*245463 13861.0 11384.1 139.76

230 0.321384 12398.4 10506*7 134.19 300 0*244630 13882.6 11396.8 139.83

74
7.00 atmosphere isobar

TEMP. DENSITY ENTHALPY internal ENTROPY

K mol/liter J/MOL energy

J/MQL

J/MOL-K

86 35.1341 2925.5 2905.3 53.86

07 34.9836 2971.1 2950.8 54.39

88 34.8313 3016.9 2996.5 54.91

89 34*6773 3062*8 3042*4 55*43

90 34.5216 3109.0 3088.5 55.95

PHASE CHANGE

TEMP. DENSITY ENTHALPY internal entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.3642 3155.4 3134.7 56,46

92 34.2053 3201.9 3181.2 56.97

93 34.0447 3248.7 3227.8 57.47

94 33.8826 3295.6 3274.7 57.98

95 33.7188 3342.7 3321.7 58.47

96 33.5534 3390.0 3368.8 58.97

97 33*3864 3437.4 3416*2 59*46

98 33.2177 3485.0 3463.7 59.95

99 33.0473 3532.8 3511.3 60.43

100 32.8751 3580.7 3559.1 60,92

101 32.7012 3628.8 3607.1 61.39

102 32*5254 3677.0 3655.2 61.87

103 32.3477 3725.4 3703*5 62 » 34

104 32*1680 3774-0 3752*0 62*81

105 31.9863 3822.7 3800.6 63.28

106 31.8024 3871.6 3849.3 63.74

107 31.6162 3920.7 3898.3 64.20

108 31.4276 3970.0 3947.4 64.66

109 31.2366 4019.4 3996.7 65.12

110 31.0428 4069.1 4046.2 65.57

110.930 30.8602 4115.5 4092.5 65.99

110.930 0.885740 9653.5 8852.7 115.91

111 0.884899 9655.4 8853.9 115,93

112 0,873112 9682.9 8870.5 116.18

113 0.861731 9710.1 8887.0 116.42

114 0.850732 9737.2 8903.4 136.66

115 0.840091 9763.9 8919.6 116.89

116 0.829788 9790.5 8935.7 117.12

117 0*819803 9816.9 8951-7 117.35

118 0.810119 9843.1 8967.6 117.57

119 0,000720 9869.2 8983.3 117.79

120 0,791592 9895.0 8999.0 118.01

121 0.782719 9920.7 9014.5 118.22

122 0*774091 9946*3 9030*0 118.43

123 0*765694 9971*7 9045 * 4 118.64

124 0.757518 9997.0 9060.7 118.84

125 0.749553 10022.2 9075.9 119.05

126 0.741790 10047.2 9091.0 119.24

127 0.734219 10072.1 9106.0 119.44

128 0.726832 10096.9 9121.0 119.64

129 0.719622 10121.6 9135.9 119.83

130 0.712581 10146.2 9150.8 120.02

131 0.705702 10170.7 9165.6 120.21

132 0.698979 10195.1 9\«0.3 120.39

133 0.692406 10219.4 9195.0 120.57

134 0.685978 10243.6 9209.6 120.76

135 0.679688 10267.7 9224.2 120.94

136 0.673531 10291 .0 9298.7 121*11

137 0*667504 10315.7 9253-1 121*29

138 0*661601 10339.6 9267.5 121 .46 139 0*655817 10363*5 9281*9 121*63

140 0*650150 10387*2 9296-2 121.80

141 0.644594 10410.9 9310.5 121.97

142 0.639147 10434.5 9324.8 122.14

143 0*633804 10458.1 9339.0 122.31

144 0.628562 10481.6 9353-1 122.47

145 0.623418 10505.0 9367.2 122.63

146 0.618370 10528.4 9381.3 122.79

147 0.613413 10551.7 9395.4 122.95

148 0*608545 10574.9 9409.4 123.11

149 0*603764 10598.2 9423.4 123.27

150 0.599067 10621.3 9437.3 123.42

151 0.594452 10644.4 9451.3 123.57

152 0.589916 10667.5 9465.1 123.73

153 0.585456 10690.8 9478.0 123.88

154 0.581072 10713.5 9492.8 124.03

155 0.576760 10736.4 9506.6 124.18

156 0.572519 10759.3 9520.4 124.32

157 0.568346 10782.2 9534.2 124.47

158 0.564241 10805.0 9547.9 124.61

159 0*560200 10827*8 9561*6 124*76

160 0*556224 10850*5 9575*3 124.90
K

161

16 ? 163

164

1 65

1 66

167

16R

169

170

171 172

173

174

175

176

177

178

179

lflO

181 182

183

184

185

1 86

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

7.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL ENTROPY TEMP, DENSITY ENTHALPY INTERNAL ENTROPY

MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

0.552309 10873.2 9589.0 125.04 231 0.373929 12407.6 10510.7 132.97

0.548454 10895.9 9602.6 125.10 232 0.372246 12429.0 10523.6 133.06

0.544658 10918.5 9616.2 125.32 233 0.370578 12450.5 10536.5 133.15

0.540920 10941 .

1

9629.8 125.46 234 0.368925 12471.9 10549.3 133.24

0.537237 10963.6 9643.4 125.60 235 0.36728ft 12493.4 10562.2 133.33

0.^33609 10986.2 9656.9 125.73 236 0.365666 12514.8 10575.0 133.43

0.530034 11008.7 9670.5 125.87 237 0.36405ft 12536.2 10507.9 133.52

0.526511 11031.1 9684.0 126.00 230 0.362465 12557.6 10600.7 133.61

0.523039 11053.6 9607.5 126.13 239 0.360887 12579.0 1061 3,6 133.70

0.519616 11076.0 9710.9 126.27 240 0.359323 12600.4 10626.4 133.79

0.51624? 11098.3 9724.4 126.40 241 0.357772 12621.8 10639.3 133.87

0.512915 11120.7 9737.8 126.53 242 0.356236 12643.2 10652.1 133.96

0.509634 11143.0 9751.3 126.66 243 0.354713 12664.5 10664.9 134.05

0.506399 11165.3 9764.7 126.79 244 0.353203 12685.9 10677.7 134.14

0.503207 11187.6 9778.1 126.91 245 0.351707 12707.3 10690.6 134.23

0.5O0059 11209.9 97«1 .4 127.04 246 0.350223 12728.6 10703.4 134,31

0.496953 11232.1 9804.8 127.17 247 0.348753 12750.0 10716.2 134.40

0.493888 11254.3 9818.1 127.29 248 0.347295 12771.3 10729.0 134.4Q

0.490864 11276.5 9831.5 127.42 249 0.345850 12792.7 10741.8 134.57

0.437880 11298.6 9844.8 127.54 250 0.344417 12814.0 10754.6 134.66

0.484934 11320.7 9858.1 127.66 251 0.342996 12835.3 10767.4 134.74

0.482026 11342.9 9871.4 127.78 252 0.341587 12856.6 10780.2 134.83

0.479155 11365,0 9884.7 127.90 253 0.340191 12878.0 10793.0 134,91

0.476321 11387.0 9897.9 128,02 254 0.338805 12899.3 10805.8 135.00

0.473522 11409.1 9911.2 128.14 255 0.337*32 12920.6 10818.5 135.08

0.47075g 11431.1 9924.4 128.26 256 0.336070 12941.9 10831.3 135.16

0.468029 11453.1 9937.6 128.38 257 0.334719 12963.2 10844.1 135.25

0*465334 11475*1 9950*8 128.50 258 0*333379 12984.4 10856*9 135.33

0.462671 11497*1 9964*0 128.61 259 0*332051 13005.7 10869*6 135.41

0*460040 11519*0 9977*2 128*73 260 0*330733 13027*0 10882*4 135.49

0.437441 11541.0 9990.4 120.85 261 0.329426 13048.3 10895.2 135.57

0.454873 11562.9 10003.6 128.96 262 0.328129 13069.5 10907*9 135.66

0*452336 11584.8 10016.7 129*07 263 0*326843 13090*8 10920*7 135.74

0.449829 11606.7 10029.9 129.19 264 0*325567 13112*1 10933*4 135.82

0.447350 11628.6 10043.0 129.30 265 0*324301 13133.3 10946.2 135.90

0.444901 11650.4 10056*2 129.41 266 0*323046 13154.6 10958.9 135.98

0.442480 11672.3 10089.3 129.52 267 0*321800 13175.8 10971.7 136.06

0.440086 11694.1 10082.4 129.63 268 0.320564 13197.0 10984.4 136.14

0.437720 11715.9 10095.5 129.74 26R 0.319338 13218.3 10997.1 136.22

0.435381 11737.7 10108.6 129.85 270 0.318122 13239.5 11009,9 136.30

0.433069 11759.5 10121,7 129.96 271 0.316915 13260.7 11022.6 136.37

0.430780 11781.3 10134.7 130*07 272 0.315717 13282.0 11035.3 136.45

0.428518 11803.0 10147.8 130.18 273 0.314529 13303.2 11048.1 136.53

0.426281 11824.8 10160*9 130.28 274 0.313349 13324.4 11060.8 136.61

0.424069 11846*5 10173*9 130*39 275 0*312179 13345.6 11073.5 136*68

0.421880 11868.2 10186.9 130*50 276 0*311018 13366.8 11086.2 136.76

0*419715 11889*9 10200*0 130*60 277 0*309865 13388*6 11099*0 136*84

0.41 7574 11911.6 10213.0 130.71 278 0.308721 13409.2 11111.7 136.91

0.415455 11933.3 10226.0 130.81 279 0.307586 13430,4 11124.4 136.99

0.413358 11955.0 10239.0 130.91 280 0.306459 13451.6 11137.1 137.07

0.411284 11976.6 10252.0 131.02 281 0.305341 13472.8 11149.8 137.14

0.409231 11998.3 10265.0 131.12 282 0.304231 13494,6 11162.5 137.22

0.407200 12019.9 10278.0 131,22 283 0.303129 13515.1 11175.2 137.29

0.405190 12041.5 10291.0 131.32 284 0.302036 13536.3 11187.9 137.37

0.403201 12063.1 10304.0 131.42 285 0.300950 13557.5 11200.6 137.44

0.401231 12084.7 10316.9 131.52 286 0.299872 13578.6 11213.3 137.52

0.399282 12106.3 10329.9 131.62 287 0.298803 13599.0 11226.0 137.59

0.397353 12127.9 10342.8 131 .72 288 0.297741 13621.0 11238.7 137.66

0.395443 12149.5 10355.8 131.82 289 0.296686 13642.1 11251.4 137.74

0.393552 12171.0 10368.7 131.92 290 0.295640 13663.3 11264.1 137.81

0.391679 12192.6 10381.7 132.02 291 0.294600 13684.4 11276.8 137.88

0.389826 12214.1 10394.6 132.11 292 0.293569 13705.6 11289.5 137.95

0.387990 12235.6 10407.5 132.21 293 0.292544 13726.7 11302.1 138.03

0.386173 12257.2 10420.4 132.31 294 0.291527 13747.9 11314.8 138.10

0.384373 12278.7 10433.4 132.40 295 0.290517 13769.0 11327.5 138.17

0.382590 12300.2 10446.3 132.50 296 0.289514 13790.1 11340.2 138.24

0.380825 12321.7 10459.2 132.59 297 0.288518 13811.3 11352.9 138.31

0.379076 12343.2 10472.1 132.69 298 0.287530 13832.4 11365.5 138.38

0.377344 12364.6 10484.9 132.78 299 0.286548 13853.5 11378.2 138.46

0.375629 12386.1 10497.8 132.87 300 0.285573 13874.6 11390.9 138.53

76
8.00 ATMOSPHFRF ISOBAR

TEMP. density ENTHALPY INTERNAL ENTROPY

K mol/liteR J/MOL energy

J/MOL

J/MOL-K

86 35.1417 2927.3 2904.3 53.85

87 34.9913 2972.9 2949.7 54.38

88 34.8392 3018.6 2995*4 54.90

89 34.6854 3064.6 3041.2 55.42

90 34.5299 3110.7 3087.3 55.93

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOl /liter J/MOL ENERGY J/MOL-K

J/MOL

91 34.3727 3157.1 3133.5 56.45

92 34.2140 3203.6 3179.9 56.96

93 34.0536 3250.3 3226.5 57.46

94 33.8917 3297.2 3273.3 57.96

95 33.7282 3344.3 3320.3 58.46

96 33.5630 3391.5 3367.4 58.95

97 33.3962 3439.0 3414.7 59.45

9R 33.2278 3486.5 3462.1 59.93

99 33.0577 3534.3 3509.7 60.42

100 32.8858 3582.2 3557.5 60.90

101 32.7122 3630.2 3605.4 61.38

102 32.5368 3678.4 3653.5 61.85

103 32.3594 3726.8 3701*7 62*33

104 32*1801 3775*3 3750*1 62*79

105 31*9987 3824*0 3798*7 63.26

106 31.8152 3872.9 3847.4 63.72

107 31.6295 3921.9 3896.3 64.18

108 31.4414 3971.1 3945.3 64.64

109 31.2508 4020*5 3994.6 65.10

110 31.0576 4070*1 4044*0 65.55

111 30.8617 4119.9 4093.7 66.00

112 30.6628 4170.0 4143.5 66.45

113 30,4607 4220.3 4193.7 66.90

113.050 30.4505 4222.8 4196.2 66.92

113.050 1.00819 9655.1 8851.1 114.97

114 0.995068 9682.2 8867.5 115.21

115 0.981740 9710.4 8884.7 115.46

116 0.968883 9738.3 8901.6 115.70

117 0.956467 9765.9 8918.4 115.93

118 0,944464 9793.3 8935.0 116.17

119 0.932850 9820.5 8951 ,5 116.40

120 0.921602 9R47.5 8967.9 116.62

121 0.910699 9874.2 8984.1 116.84

122 0*900122 9900*8 9000*2 117*06

123 0.889854 9927.1 9016.2 117.28

124 0.879879 9953.3 9032.1 117 .49

125 0*870183 9979.4 9047*8 117.70

126 0.860750 10005.2 9063.5 117.91

127 0*851569 10031*0 9079*1 118.11

128 0.842629 10056.6 9094.5 118.31

129 0*833917 10082 •

0

9109*9 118*51

130 0.825423 10107.3 9125.3 118.70

131 0.817139 10132.5 9140.5 118.90

132 0.809054 10157.6 9155.7 119.09

133 0.801162 10182.6 9170.7 119.28

134 0.793453 10207.4 9185*8 119.46

135 0.785920 10232.1 9200.7 119.65

136 0.778557 10256.8 9215.6 119.83

137 0.771356 10281.3 9230.4 120.01

138 0.764313 10305.8 9245.2 120.19

139 0.757420 10330.2 9259.9 120.36

140 0.750672 10354.4 9274.6 120.54

141 0.744064 10378.6 9289.2 120.71

142 0.737592 10402.7 9303.7 120.88

143 0.731250 10426.8 9318.2 121.05

144 0.725033 10450.7 9332.7 121.21

145 0.718939 10474. (S 9347.1 121.38

146 0*712962 10498*5 9361.5 121 *54

147 0*707098 10522*2 9375*8 121*70

148 0.701345 10545.9 9390.1 121.87

149 0.695699 10569.5 <5404.3 122.02

150 0.690155 10593.) 9418.5 122.18

151 0.684712 10616.6 9432.7 122.34

152 0.679366 10640.0 9446.8 122.49

183 0.674114 10663.4 <5460.9 122.65

154 0*668954 10686.8 9475*0 122.80

155 0*663883 10710.1 <548<5.

0

122. <55 156 0*658897 10733.3 <5503.0 123.10

157 0.653996 10756.5 9517.0 123.25

158 0*649175 10779.6 9530*9 123*39

159 0*644434 10802.7 9544*8 123.54

160 0.639770 10825.8 9558.7 123.68

PHASE CHANGE 77
K

161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177 178

179

180

181 182

183

184

185

186

187

188

189

190

191

1 92

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

20 ® 210

211 212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

23 0

8.00 atmosphere ISOBAR

DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL Entropy

MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITEP J/MOL ENERGY

J/MOL

j/moi.-k

0.635161 10848.8 9572.6 123.83 231 0.428112 12395.4 10501.9 131.82

0.630665 10871.7 9586.4 123.97 232 0.426173 12417.0 10514.9 131.91

0.626220 10894.7 9600*2 124.11 233 0.424251 12438*5 10527.8 132*00

0 • 631845 10917.6 9614.0 124.25 274 0.422348 12460*0 10540*7 132-10

0*61 7536 10940*4 9627*7 124.39 235 0.420462 12481.6 10553*6 132*19

0*61 3294 1 0963*2 9641*5 124.53 236 0*418594 12503*1 10566.5 132*28

0.609115 10986.0 9655.2 124.66 237 0.416743 12524.6 10579.5 132.37

0.604999 11008.7 9668.8 124.80 238 0.414909 12546.1 10592.4 132.46

0*600944 11031*4 9682*5 124*93 239 0*413092 12567*6 10605*3 132*55

0.596949 11054.1 9696.1 125.07 240 0.411291 12589.1 10618.1 132.64

0.563011 11076.7 9709.7 125.20 241 0.409506 12610.5 10631.0 132.73

0*589130 11099*3 9723*3 125*33 242 0*407738 12632*6 1 0643 •

9

132*82

0.585305 11121.9 9736.9 125*46 243 0*405985 12653*5 10656*8 132*91

0.581533 11144.4 9750.5 125.59 244 0.404248 12674.9 10669.7 133.00

0.577815 11166.9 9764.0 125.72 245 0.402526 12696.4 10682.5 133.08

0.574148 11189.4 9777.5 125.85 246 0.400820 12717.8 10695.4 133.17

0.570531 11211.9 9791.0 125.98 247 0.399128 12739.2 10708.3 133.26

0 .566964 11234.3 9804.5 126.10 248 0*397451 12760*7 10721-1 133.34

0.563445 11256.7 9818.0 126.23 ?49 0.395789 12782.1 10734.0 133.43

0.559973 11279.0 9831.4 126.35 250 0.394140 12R03.5 10746.8 133.52

0.556547 11301.4 9844.9 126.48 251 0.392507 12824.9 10759.7 133.60

0.553166 11323.7 9858.3 126.60 252 0.390887 12846.3 10772.5 133.69

0.549830 11346.0 9871.7 126.72 253 0.389280 12867.7 10785.3 133.77

0.546537 11368.3 9885.1 126.84 254 0.387688 12889.1 10798.2 133.86

0.543286 11390.5 9898.4 126.96 255 0.386109 12910.5 10811.0 133.94

0.540077 11412.7 9911.8 127.08 256 0.384543 12931.8 10823.8 134.02

0.536908 11434.9 9925.1 127.20 257 0.382990 12953.2 10836.6 134.11

0.533780 11457.1 9938.5 127.32 258 0.381450 12974.6 10849.5 134.19

0*530690 11479.3 9951*8 127*44 259 0.379923 12995*9 10862*3 134.27

0. 5?7638 11501*4 9965*1 127.56 260 0*378408 13017.3 10875*1 134.35

0.524624 11523.5 9978.4 127.67 261 0.376906 13038.6 10887.9 134.44

0.521646 11545.6 9991.7 127.79 262 0.375416 13059.9 10900.7 134.52

0.518705 11567.7 10004.9 127.90 263 0*373938 13081.3 10913.5 134.60

0*516799 11589.8 10018*2 128.02 264 0*372472 13102*6 10926.3 134.68

0.512927 11611.8 10031.4 128.13 265 0.371018 13123.9 10939.1 134.76

0.510090 11633.8 10044.6 128.24 266 0.369576 13145.2 10951,9 134.84

0.507286 11655.8 10057.9 128.35 267 0.368145 13166.5 10964.6 134.92

0.504514 11677.8 10071.1 128.47 268 0.366725 13187.9 10977.4 135.00

0.501775 11699.8 10084,3 128.58 269 0.365317 13209.2 10990.2 135.08

0.499067 11721.7 10097.4 128,69 270 0,363919 13230.4 11003.0 135.16

0.466390 11743.7 10110.6 128.80 271 0.362533 13251.7 11015.7 135.24

0 . 493744 11765.6 10123.8 128.90 272 0.361158 13273.0 11028.5 135.32

0.491127 11787.5 10136.9 129.01 273 0.359793 13294.3 11041.3 135.39

0.488539 11809.4 10150.1 129.12 2 74 0.358439 13315.6 11054.0 135.4?

0.485981 11831.2 10163.2 129.23 275 0.357095 13336.8 11066.8 135.55

0.483450 11853.1 10176.3 129.33 276 0.355761 13358.1 11079.6 135.63

0.480947 11874.9 10169.5 129.44 277 0.354438 13379.4 11092.3 135.70

0.47847

2

11896.3 10202.6 129.54 278 0.353125 13400.6 11105.1 135.78

0.476024 11918.6 10215.7 129.65 279 0.351822 13421.9 11117.8 135.86

0.473601 11940.4 10228.8 129.75 280 0,350528 13443.1 11130.6 135.93

0.471205 11962.2 10241.8 129.86 281 0.349245 13464.4 11143.3 136.01

0.468834 11983.9 10254.9 129.96 282 0.347971 13485.6 11156.0 136.08

0.466488 12005-7 10260.0 130*06 283 0.346706 13506.8 11168.8 136.16

0-464167 12027-4 10281.0 130*16 284 0045451 13528*1 11181.5 136.23

0.461870 12049.2 10294.1 130.27 285 0.344205 13549.3 11194.2 136.31

0.459597 12070.9 10307.1 130.37 286 0.342968 13570.5 11207.0 176.38

0.457347 12092.6 10320.2 130.47 287 0.341741 13591.7 11219.7 136.46

0.455120 12114.3 10333.2 130.57 288 0.340522 13613.0 11232.4 136,53

0.452916 12136.0 10346.2 130.67 289 0.339312 13634.2 11245.2 136.60

0.450735 12157.7 10359.2 130.76 290 0.338111 13655.4 11257.9 136.68

0.448575 12179.3 10372.2 130.86 291 0.336919 13676.6 11270.6 136.75

0.446437 12201.0 10385.2 130.96 292 0.335735 13697.8 11283.3 136.82

0 « 444320 12222.6 10398.2 131*06 293 0*334560 13719.0 11296.0 136.90

0.442224 12244.3 10411.2 131.15 294 0.333393 13740.2 11308.7 136.97

0.440149 12265.9 10424*2 131-25 295 0.332235 13761.4 11321.4 137.04

0.438094 12287.5 10437.2 131.35 296 0.331084 13782.5 11334.2 137.11

0.436056 12309.1 10450.1 131.44 297 0.329942 13803.7 11346.9 137.18

0.434043 12330.7 10463.1 131.54 298 0.328808 13824.9 11359.6 137.25

0.432047 12352.3 10476*0 131.63 299 0.327682 13846.1 11372.3 137.33

0.430070 12373.8 10489.0 131.73 300 0.326563 13867.2 11385.0 137.40

78
9.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITFR j/mol energy j/mol-k

J/MOL

86 35. 1492 2929.2 2903.2 53.84

87 34,9990 2974.7 2948.6 54.36

88 34.8471 3020.4 2994.3 54.89

89 34.6934 3066.4 3040.1 55.41

90 34.5381 3112.5 3086.1 55.92

TEMP. DENSITY ENTHALPY internal ENTROPY

K mol/liter J/MOL energy J/MOL-K

J/MOL

91 34.3812 3158.8 3132.3 56.43

92 34.2227 3205.3 3178.7 56.94

93 34*0625 3252*0 3225*2 57.45

94 33.9008 3298.9 3272.0 57.95

95 33*7375 3345.9 3318.9 58.45

96 33.5726 3393.1 3366.0 58.94

97 33.4061 3440*5 3413.2 59.43

98 33.2379 3488.1 3460.6 59.92

99 33.0681 3535.8 3508.2 60.40

100 32*8965 3583-6 3555.9 60.88

101 32.7232 3631.7 3603.8 61.36

102 32.5481 3679.8 3651.8 61.84

103 32.3711 3728.2 3700.0 62.31

104 32.1921 3776.6 3748.3 62.78

105 32.0112 3825.3 3796.8 63.24

106 31.8281 3874.1 3845,4 63.70

107 31.6427 3923.1 3894.3 64.16

108 31*4551 3972.

2

3943*2 64.62

109 31.2650 4021.6 3992.4 65.00

110 31.0723 4071.1 4041.8 65.53

111 30.8769 4120.9 4091.3 65.98

112 30.6786 4170.9 4141.1 66.43

113 30.4772 4221.1 4191.2 66,87

114 30.2726 4271.6 4241.5 67.32

114.988 30.0669 4321 .8 4291.5 67.76

114.988 1.13144 9653.4 8847.4 11*. 12 115 1.13125 9653.8 8847,6 11*. 13 116 1.11533 9683.2 8865.6 114.38

117 1.10003 9712.3 R8B3.3 114.63

118 1.08529 9741.1 8900.8 114.88

119 1.07108 9769.6 8918.2 115.12

120 1.05736 9797.8 8935.3 115.35

121 1.04411 9825,7 8952.3 115.59

122 1.03129 9853.4 8969.1 115.81

123 1.01888 9880.9 8985.8 116.04

124 1.00685 9908.1 9002.3 116.26

125 0.995195 9935.1 9018,7 116.47

126 0.983877 9961.9 9035.0 116.69

127 0.972885 9988.5 9051.2 116.90

128 0*962201 10015.0 9067.2 117.11

129 0.951812 10041.2 9083.1 117.31

130 0.941701 10067.3 9098.9 117.51

131 0.931857 10093.3 9114.7 117.71

1.32 0.922267 10119.1 9130-3 117.91

133 0.912919 10144.8 9145.8 118.10

134 0.903802 10170.3 9161.3 118.29

135 0.894906 10195.7 9176.7 118,48

136 0.886223 10221.0 9192.0 118.67

137 0.877743 10246.2 9207.2 118.85

138 0.869458 10271.2 9222.3 119.03

139 0.861359 10296.2 9237.4 119.21

140 0.853441 10321.0 9252.4 119.39

141 0.845696 10345.7 9267.4 119.57

142 0.838117 10370.4 9282.3 119.74

143 0.830698 10394.9 9297.1 119.91

144 0.823434 10419.4 9311.9 120.09

145 0.816318 10443.7 9326.6 120.25

146 0.809346 10468.0 9341.3 120.42

147 0.802513 10492.2 9355.9 120.59

148 0.795814 10516.4 9370.4 120,75

149 0.789245 10540.4 9385.0 120.91

150 0.782801 10564.4 9399.4 121.07

151 0.776477 10588.3 9413.9 121.23

152 0*770272 10612*2 9428*2 121*39

153 0.764180 10636.0 9442.6 121.54

154 0*758198 10659*7 9456.9 121*70

155 0.752323 10683.3 9471.2 121.85

156 0.746551 10706.9 9485.4 122.00

157 0.740880 10730.5 9409.6 122.15

158 0.735306 10754.0 9513.7 122.30

159 0.729828 10777.4 9527.9 122.45

160 0.724441 10800.8 9541.9 122.60

PHASE CHANGF
9.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LI TEH J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENFRGY

J/MOL

j/mol-k

161 0.719144 10324.1 9556.0 122.74 231 0.482489 12383.2 10493.1 130.80

162 0.713934 10847.4 9570.0 122.89 232 0.480289 12404.8 10506.1 130.89

163 0.708808 10870.6 9584.0 123.03 233 0.478111 12426.5 10519.1 130.99

1 6 A 0.703765 10893.8 9598.0 123.17 234 0.475952 12448.1 10532.1 131.08

165 0.698801 10916.9 9611.9 123.31 235 0.473815 12469.7 10545.0 131.17

166 0.693916 10940.0 9625.8 123.45 236 0.471697 12491.4 10558.0 131.26

167 0.689107 10963.1 9639.7 123.59 237 0.469599 12513.6 10571.0 131.36

168 0.684372 10986.1 9653.6 123.73 238 0.467520 12534.6 10583.9 131.45

169 0.679709 11009.1 9667.4 123.86 239 0.465461 12556.1 10596.9 131.54

170 0.675116 11032.0 9681.2 124.00 240 0.463420 12577.7 10609.8 131.63

171 0.670592 11054.9 9695.0 124.13 241 0.461398 12599.3 10622.8 131.72

172 0.666135 11077.7 9708.7 124.27 242 0.459394 12620.8 10635.7 131.81

173 0.661743 11100.6 9722.5 124.40 243 0*457409 12642*4 10648.7 131.90

174 0.657415 11123.3 9736.2 124.53 244 0.455441 12663.9 10661.6 131.98

175 0.653149 11146.1 9749.8 124.66 245 0.453491 12685.5 10674.5 132.07

176 0.648943 11168.8 9763.5 124.79 246 0.451558 12707.0 10687.4 132.16

177 0.644797 11191.5 9777.2 124.92 247 0.449642 12728.5 10700.3 132,25

178 0.640709 11214,1 9790.8 125,05 248 0.447743 12750.0 10713.2 132.33

179 0.636677 11236.7 9804.4 125.17 249 0.445861 12771.5 10726.1 132.42

180 0.632701 11259.3 9818.0 125.30 250 0.443995 12793.6 10739.0 132.51

181 0.626779 11281 .9 9831.5 125.42 251 0.442145 12814.5 10751.9 132.59

182 0.624910 11304.4 9845.1 125.55 252 0,440312 12836.0 10764.8 132.68

183 0.621092 11326.9 9858.6 125.67 253 0.438493 12857,4 10777.7 132,76

184 0.617325 11349.4 9872.1 125.79 254 0.436691 12878.9 10790.6 132.85

185 0.613608 11371.8 9885.6 125.92 255 0.434904 12900.3 10803.4 132.93

186 0.609939 11394.3 9899.1 126.04 256 0.433132 12921,8 10816.3 133.02

187 0 .606317 11416,6 9912.6 126.16 257 0.431375 12943,2 10829.2 133.10

188 0.602742 11439.0 9926.0 126.28 258 0.429632 12964.7 10842;0 133.18

189 0.599213 11461 .4 9939.4 126.39 259 0.427904 12986*1 10854.9 133.26

190 0.595727 11483*7 9952 •

9

126*51 260 0*426191 13007.5 10867*7 133*35

191 0.592236 11506.0 9966.3 126.63 261 0.424491 13028.9 10880.6 133.43

192 0.588887 11528.2 9979.7 126.75 262 0.422806 13050.3 10893.4 133.51

193 0.585531 11550.5 9993.0 126.86 263 0.421134 13071,7 10906.3 133.59

1 94 0.582215 11572.7 10006.4 126.98 264 0,419476 13093.1 10919.1 133.67

195 0.578939 11594.9 10019.7 127.09 265 0.417832 13114.5 10931 .9 133.76

196 0.575703 11617.1 10033.1 127.20 266 0.416200 13135.9 10944.8 133.84

197 0.572506 11639.3 10046.4 127.32 267 0.414582 13157.3 10957.6 133.92

198 0.569347 11661.4 10059.7 127.43 268 0.412977 13178,6 10970.4 134,00

1 99 0.566225 11683.6 10073.0 127.54 269 0.411385 13200,0 10983,2 134.08

200 0.563139 11705.7 10086,3 127.65 270 0.409805 13221.4 10996.0 134.15

201 0.560089 11727.7 10099.5 127.76 271 0.408238 13242.7 11008.9 134.23

202 0.557075 11749.8 10112.8 127.87 272 0.406683 13264.1 11021.7 134.31

203 0.554095 11771.9 10126.0 127.98 273 0.405140 13285.4 11034.5 134.39

204 0.551149 11793.9 10139.3 128.09 274 0.403609 13306.8 11047.3 134.47

205 0.548236 11815.9 10152.5 128.20 275 0.402090 13328.1 11060.1 134.55

206 0.545356 11837.9 10165.7 128.30 276 0.400583 13349.4 11072.9 134.62

207 0.542508 11659,9 10178.9 128.41 277 0.399088 13370.7 11085.7 134,70

208 0.539691 11881.9 10192.1 128.51 278 0.397604 13392.1 11098.4 134.78

209 0.536906 11903.8 10205.3 128.62 279 0.396131 13413.4 11111.2 134.85

210 0.534151 11925.7 10218.5 128,72 280 0.394669 13434.7 11124.0 134.93

211 0.531425 11947.7 10231.6 128.83 281 0.393219 13456.0 11136.8 135.01

212 0.528730 11969.6 10244.8 128.93 282 0,391779 13477.3 11149.6 135.08

213 0.526063 11991.5 10257.9 129.04 283 0.390351 13498.6 11162.3 135.16

214 0.523424 12013.3 10271.0 129.14 284 0.3R8933 13519.8 11175.1 135.23

215 0.520814 12035.2 1 02h4 ,

2

129.2a 285 0.387525 13541.1 11187.9 135.31

216 0,518230 12057.0 10297.3 129.34 286 0,386128 13562.4 11200.6 135.38

217 0.515674 12078.9 10310.4 129.44 287 0.384741 13583.7 11213.4 135,46

218 0.513145 12100.7 10323.5 129.54 288 0.383365 13605.0 11226.1 135.53

219 0.510641 12122,5 10336.6 129.64 289 0.381998 13626.2 11238.9 135.60

220 0.508163 12144.3 10349.7 129.74 290 0.380642 13647.5 11251.7 135.68

221 0.505711 12166.1 10362.8 129.84 291 0.379295 13668.7 11264.4 135.75

222 0.503283 12187.8 10375.8 129.94 29? 0*377959 13690*0 11277.2 135.82

223 0*500880 12209.6 10388.9 130*04 293 0*376631 13711*2 11289.9 135.90

224 0.498500 12231.3 10401.9 130.13 294 0.375314 13732.5 11302.6 135.97

225 0.496145 12253.0 10415.0 130.23 295 0.374005 13753.7 11315.4 136.04

226 0.493813 12274,8 10428.0 130.33 296 0.372706 13774.9 11328.1 136.11

227 0.491503 12296.5 1 0441 •

0

130.42 297 0*371417 13796.2 11340*9 136.18

228 0*489217 12318*2 10454*1 130*52 298 0.370136 13817.4 11353*6 136.26

229 0.486952 12339.9 10467.1 130.61 299 0.368865 13838.6 11366.3 136.33

230 0*484710 12361.5 10480-1 130-71 300 0-367602 13859.9 11379.0 136.40

80
10.00 ATMOSPHERE isobar

TEMP. DENSITY enthalpy internal entropy

K MOL/LITER j/mol energy j/mol-k

J/MOL

86 35.1568 2931.0 2902.2 53*83

87 35.0068 2976*5 2947*6 54*35

88 34*8550 3022*2 2993*1 54*87

89 34*7015 3068 •

1

3038*9 55*39

90 34*5464 3114*2 3084*9 55*91

PHASE CHANGE

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.3896 3160.5 3131*1 56.42

92 34.2313 3207*0 3177*4 56.93

93 34*0714 3253*7 3223*9 57.43

94 33*9099 3300*5 3270*6 57*93

95 33*7468 3347*5 3317*5 58.43

96 33*5821 3394*7 3364*5 58*93

97 33*4159 3442*1 3411*8 59*42

98 33*2480 3489*6 3459*1 59*90

99 33.0784 3537.3 3506.6 60.39

100 32.9072 3585.1 3554.3 60.87

101 32.7342 3633.1 3602.1 61.35

102 32.5594 3681.2 3650.1 61.82

103 32.3827 3729.5 3698.2 62.29

104 32.2041 3778.0 3746.5 62.76

105 32.0235 3826.6 3794.9 63.22

106 31.8408 3875,3 3843.5 63.69

107 31.6560 3924.3 3892.3 64,15

108 31 .4688 3973.4 3941.2 64.60

109 31.2791 4022.7 3990.3 65.06

no 31*0870 4072.1 4039.5 65.51

111 30.8921 4121.8 4089.0 65.96

112 30.6944 4171*8 4138.7 66.41

113 30*4936 4221*9 4188*7 66.85

114 30*2896 4272*4 4238*9 67*30

115 30*0821 4323.1 4289.4 67.74

116 29.8710 4374.2 4340.2 68.18

116.777 29.7041 4414,1 4380.0 68.52

116.777 l.?557x 9649.0 8842.0 113.35

117 1.25160 9655.8 8846*2 113*41

118 1.23359 9686.2 8864.8 113.67

119 1.21630 9716.2 8883.1 113.92

120 1.19967 9745.8 8901.2 114.17

121 1.18367 9775.1 8919.0 114.41

122 1.16824 9804.0 8936.7 114.65

123 1.15335 9832.7 8954.1 114.89

124 1.13897 9861.0 8971.4 115.12

125 1.12506 9889.1 8988.5 115.34

126 1*11160 9917-0 9005.4 115.56

127 1.09856 9944.6 9022.2 115.78

128 1.08591 9972.0 9038.9 116.00

129 1.07364 9999.2 9055.4 116.21

1 3 0 1.06172 10026.2 9071.8 116.42

131 1.05013 10052.9 9088.0 116.62

132 1.03887 10079.5 9104.2 116.8?

133 1.02791 10106.0 9120.2 117.02

134 1.01724 10132.3 9136.2 117.22

135 1.00685 10158.4 9152.0 117.41

136 0.996718 10184.3 9167*7 117.61

137 0*986837 10210*2 9183*4 117*79

138 0,977197 10235.9 9198.9 117.98

139 0.967787 10261.4 9214.4 118.17

140 0*958597 10286*8 9229*8 118*35

141 0. <349618 10312.2 9245.1 118.53

142 0.940843 10337.4 9260.4 118.71

143 0*932262 10362*4 9275*5 118.88

144 0*923869 10387*4 9290*7 119.06

145 0*915656 10412.3 9305*7 119.23

146 0.907617 10437.1 9320.7 119.40

147 0.899745 10461.8 0335.6 119.57

148 0.892034 10486.4 0350.5 119.73

149 0.884479 10510.9 9365.3 119.90

150 0.877074 10535.3 9380.0 120.06

151 0.869814 10559.7 9394.7 120.22

152 0.862695 10583.9 9409.4 120.30

153 0.855711 10608.1 9424.0 120.54

154 0.848858 10632.2 9438.5 120.70

155 0 .84? 1 32 10656.3 9453.0 120.86

156 0.835529 10680.2 9467.5 121.01

157 0*829045 10704*2 9481 .9 121*16

158 0*822677 10728*0 9496*3 121*31

159 0*816421 10751*8 9510*7 121*46

160 0*810274 10775*5 9525*0 121*61
161 162

1 63

164

165

166

167

168

169

170

171 172 173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

1«0

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221 222

223

224

2?5

226

227

228

229

230

10.00 ATMOSPHERE ISOBAR

DENSITY enthalpy internal ENTROPY TEMP. DENSITY enthalpy internal ENTROPY

MOL/LITER J/MOL energy

J/MOL

J/MOL-K K mol/liter J/MOL enfrgy

J/MOL

J/MOL-K

0.80*232 10799.2 9539.2 121.76 231 0.537061 12371.6 10484.3 129.89

0.796293 10822.8 9553.4 121 .91 232 0.534597 12392.7 10497.3 129.98

0.792453 10846.3 9567.6 122.05 233 0.532157 12414.6 10510,4 130.07

0.786710 10869.8 9581.8 122.20 234 0.529740 12436.2 10523.4 130.17

0.781061 10893.2 9595.9 122.34 235 0.527346 12457.9 10536.4 130.26

0.775504 10916.6 9610.0 122. 4 8 236 0.524975 12479.6 10549.5 130.35

0.770036 10940.0 9624.1 122.62 237 0.522626 12501.3 10562.5 130.44

0.764654 10963.3 9638.1 122.76 238 0.520299 12523.6 10575.5 130.54

0.759357 10986.5 9652.1 122.90 239 0.517994 12544.7 10588.5 130.63

0.754141 11009.7 9666.1 123.03 240 0.515710 12566.3 10601.5 130.72

0.749006 11032.9 9680.0 123.17 241 0.513448 12588.0 10614.5 130.81

0.743949 11056.0 9694.0 123.30 242 0.511206 12609.6 10627.5 130.90

0.738968 11079.1 9707.9 123.44 243 0 .500984 12631*3 10640.5 130.99

0.734061 11102.1 9721.7 123*57 244 0*506783 12652*9 10653.5 131.07

0.729226 11125.1 9735*6 123.70 245 0*504601 12674.5 10666.4 131*16

0.724462 11148*0 9749*4 123*83 246 0*502439 12696.1 10679*4 131*25

0.719767 11171.0 9763-2 123.96 247 0*500296 12717.7 10692.4 131-34

0.715138 11193*8 9776.9 124.09 248 0*498172 12739.3 10705.3 131.43

0.710576 11216.7 9790.7 124.22 249 0.496067 12760.9 10718.3 131.51

0*706078 11239*5 9804*4 124*35 250 0*493981 12782*5 10731*2 131*60

0.701642 11262.3 r—

1

•

O' CO 00 124.47 251 0,491913 12804.6 10744.2 131.69

0.697267 11285.0 9831.8 124.60 252 0.489862 12825.6 10757.1 131.77

0.692952 11307.7 9845.5 124.72 253 0.487830 12847.1 10770.0 131.86

0.688696 11330.4 9859.1 124.85 254 0,485815 12868.7 10783.0 131.94

0.6R4497 11353.0 9872,7 124.97 255 0.483817 12890.2 10795.9 132.03

0 , 680354 11375.7 9886.3 125.09 256 0.481837 12911.7 10800.8 132.11

0.676265 11398.3 9899.9 125.21 257 0.479873 12933.3 10821.7 132.19

0.672230 11420.8 9913.5 125.33 258 0.477926 12954.8 10834.6 132.28

0.668248 11443.3 9927.0 125.45 259 0.475995 12976,3 10847.5 132.36

0.66*316 11465.9 99*0 *6 125.57 260 0.474080 12997.8 10860.4 132.44

0.660435 11488.3 9954.1 125.69 261 0.472181 13019.2 10873.3 132.53

0*656603 11510.0 9967*6 125*81 262 0*470298 13040*7 10886.2 132.61

0*652819 11533*2 9981 • 1 125-92 263 0*468431 13062.2 10899*1 132.69

0.649083 11555.6 9994.5 126.04 264 0.466579 13083.7 10911.9 132.77

0.645392 11578.0 10008.0 126.15 265 0.4647*2 13105.1 10924,8 132,85

0.641747 11600.3 10021 .4 126.27 266 0.462920 13126,6 10937.7 132.93

0.638146 11622.7 10034.8 126.38 267 0.461113 13148.0 10950.5 133.01

0.634589 11645.0 10048.2 126.49 268 0.459320 13169.4 10963.4 133.09

0.631074 11667.3 10061.6 126.61 269 0.457542 13190.9 10976.3 133.17

0.627602 11689.5 10075.0 126.72 270 0.455778 13212.3 10989.1 133.25

0.62*170 11711.8 10088.4 126.83 271 0.454028 13233.7 11002.0 133.33

0.620778 11734.0 10101.7 126.94 272 0.452292 13255.1 11014.8 133.41

0.617426 11756.2 10115.1 127.05 273 0.450569 13276.5 11027,7 133.49

0.614113 11778.4 10128.4 127.16 274 0.448860 13297.9 11040.5 133.57

0.610838 11800.5 10141.7 127.27 275 0.447165 13319.3 11053.3 133.65

0.607600 1 1822*7 10155.0 127.37 276 0*445482 13340.7 11066.2 133.72

0*604399 11844.8 10168*3 127.48 277 0.443813 13362*1 11079.0 133.80

0.601234 11866.9 10181.6 127*59 278 0-442157 13383.5 11091.8 133.88

0.598104 11889.0 10194.8 127.69 279 0.440513 13404.8 11104.6 133.95

0.595009 11911.1 10208.1 127.80 280 0-438882 13426.2 11117.4 134.03

0.591948 11933.1 10221.4 127.90 281 0.437263 13447.6 11130.3 134.11

0.588920 11955.2 10234.6 128.01 282 0.435657 13468.9 11143.1 134.18

0.585926 11977.2 10247.8 128.11 283 0.434063 13490.3 11155.9 134.26

0.582964 11999.2 10261.0 128.21 284 0*432480 13511.6 11168.7 134.33

0.580033 12021.2 10274.2 128.32 285 0.430910 13533.6 11181.5 134.41

0.577134 12043.1 10287.4 128.42 286 0.429351 13554.3 11194.3 134.48

0.57*265 12065.1 10300.6 128.52 287 0.427804 13575.6 11207.1 134.56

0.571427 12087.0 10313.8 128.62 288 0.426269 13596.9 11219.9 134.63

0.568618 12108.9 10326.9 128.72 289 0.4247*4 13618.3 11232.6 134.71

0.565839 12130.9 10340.1 128.82 290 0.423231 13639.6 11245.4 134.78

0.563088 12152.7 10353.2 128.92 291 0.421729 13660.9 11258.2 134.85

0.560365 12174.6 10366.4 129.02 292 0.420238 13682.2 11271.0 134.93

0.557671 12196.5 10379.5 129.12 293 0.418758 13703.5 11283.8 135.00

0.555003 12218.3 10392.6 129.22 294 0*417288 13724.8 11296*5 135.07

0.552363 12240-2 10405.7 129.31 295 0.415829 13746.1 11309.3 135.14

0.549748 12262*0 10418.8 129.41 296 0.414380 13767.4 11322.1 135.22

0.547160 12283.8 10431.9 129.51 297 0.412942 13788.6 11334.8 135.29

0.544598 12305.6 10445.0 129.60 298 0.411514 13809.9 11347.6 135.36

0.542061 12327.4 10458.1 129.70 299 0.410096 13831.2 11360.4 135.43

0.539548 12349.2 10471.2 129.79 300 0.408688 13852.5 11373.1 135.50

82
15.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 35.19*3 2940.2 2897.0 53.77

87 35.0451 2985.6 2942.2 54,29

88 34.8942 3031.2 2987.6 54.81

89 34.7416 3077.0 3033.2 55.33

90 34.5874 3122*9 3079*0 55.84

TEMP. DENSITY ENTHALPY INTERNAL entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.4316 3169.1 3125.0 56.35

92 34.2742 3215.5 3171.1 56.86

93 34*1154 3262*0 3217.5 57.36

94 33.9550 3308.8 3264.0 57.86

95 33*7930 3355*6 3310*7 58*36

96 33.6296 3402.7 3357.5 58.85

97 33,4646 3449.9 3404.5 59.34

98 33.2980 3497.3 3451.6 59.83

99 33.1298 3544.8 3498.9 60.31

100 32.9600 3592*5 3546*4 60*79

101 32.7885 3640.3 3593.9 61.26

102 32.6153 3688.3 3641.7 61.74

103 32*4403 3736*4 3689*5 62*21

104 32.2635 3784.6 3737.5 62.67

105 32.0848 3833.0 3785.6 63.13

106 31.9040 3881.6 3833.9 63.60

107 31.7212 3930.3 3882.4 64.05

108 31 .5362 3979.1 3930*9 64.51

109 31.3490 4028.2 3979.7 64.96

110 31.1593 4077.4 4028.6 65.41

111 30.9670 4126.8 4077.7 65.86

112 30*7721 4176.4 4127.0 66.30

113 30.5743 4226.2 4176.5 66.74

114 30*3736 4276.3 4226*2 67.18

115 30*1695 4326*6 4276.2 67.62

116 29.9621 4377.2 4326.5 68.06

117 29.7510 4428.2 4377.1 68.50

118 29.5359 4479.5 4428.1 68.94

119 29.3165 4531.3 4479.4 68.37

120 29-0826 4583*5 4531.2 69.81

121 28.8636 4636.2 4583.5 70.25

122 28*6292 4689*5 4636*4 70*69

123 28.3889 4743*4 4689.9 71*13

124 28.1420 4798.1 4744.1 71 .57

* 124,189 28.0945 4808.6 4754.5 71.65

* 124,189 1.89844 9596.6 8796.0 110.21

125 1.87228 96^6

.

1 88j4.3 110.44

126 1.84154 9661.6 8836.3 110.73

127 1.81234 9696.5 8857.8 111.00

128 1.78453 9730.7 8879.0 111.27

129 1.75799 9764.2 8899.7 111.53

130 1.73260 9797.2 8920.0 111.79

131 1.70829 9829.7 8940.0 112.04

132 1*68495 9861*7 8959.6 112.28

133 1.66252 9893.2 8979.0 112.52

134 1.64094 9924.4 8998.1 112.75

135 1.62014 9955.1 9017.0 112.98

136 1.60007 9985.5 9035.6 113.20

137 1.58068 10015.5 9054.0 113,42

138 1.56194 10045.2 9072.2 113.64

139 1.54380 10074.7 9OQ0.1 113.85

140 1.52623 10103.8 9107.9 114.06

141 1.50919 10132.7 9125.6 114.27

142 1.49266 10161.3 9143.0 114.47

143 1.47661 10189.7 9160*3 114.67

144 1.46101 10217.8 9177.5 114.86

145 1.44584 10245.7 9194.5 115.06

146 1.43108 10273.5 9211.4 115.25

147 1.41671 10301.0 9228.1 115.44

148 1.40271 10328.3 9244.8 115.62

149 1.38906 10355.5 9261.3 115.80

150 1.37576 10382.5 9277.7 115.98

151 1.36277 10409.3 9294.0 116.16

152 1.35009 10436.0 9310.2 116.34

153 1.33771 10462.5 9326.3 116.51

154 1.32561 10488.9 9342.3 1\6.68

155 1.31379 10515.1 9358.2 116.85

156 1.30222 10541.2 9374.1 117.02

157 1 .29091 10567.2 9389.8 117.19

158 1.27984 10593.1 9405.5 117.35

159 1.26900 10618.8 9421.1 117.51

160 1*25838 10644.4 9436*6 117*68

PHASE change
15.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP, DENSITY ENTHALPY internal entropy

K mol/liteR J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 1.24798 10669.9 9452.1 117.83 231 0.812870 12309.5 10439.6 126.32

162 1.23779 10695.4 9467.4 117.99 232 0.809022 12331.7 10453.0 126.42

163 1.22780 10720.7 9482.8 118.15 233 0.805213 12354.0 10466.4 126.51

164 1.21801 10745.9 9498.0 118.30 234 0.801443 12376.2 10479.7 126.61

165 1.26840 10771*0 9513*2 118*45 235 0.797711 12398-4 10493*1 126.70

166 1*19897 10796*0 9528*3 118*61 236 0*794015 12420*6 10506.4 126.80

167 1.18972 10821*0 9543*4 118*76 237 0.790357 12442*8 10519.7 126.89

168 1.18064 10845.8 9558*4 118.90 238 0.786734 12465.0 10533*0 126.99

169 1*17172 10870*6 9573*4 119*05 239 0*783147 12487*1 10546*3 127.08

170 1.16296 10895*3 9588*3 119.20 240 0*779595 12509*2 10559.6 127.17

171 1.15436 10919.9 9603.2 119.34 241 0.776078 12531.4 10572.9 127.26

172 1.14690 10944.4 9618.0 119.48 242 0.772594 12553.5 10586.2 127.35

173 1.13759 10968.9 9632.8 119-63 243 0.769144 12575.5 10599.4 127.45

174 1.12942 10993.2 9647.5 119.77 244 0.765726 12597.8 10612.7 127.54

175 1*12139 11017.6 9662*2 119.91 ?45 0.762341 12619.7 10625.9 127.63

176 1.11349 11041.8 9676.8 120.04 246 0.758987 12641.7 10639.1 127.72

177 1.10573 11066*0 9691.4 120-18 247 0.755665 12663.7 10652*4 127.81

178 1.09808 11090.1 9706*0 120.32 248 0.752374 12685.7 10665.6 127.89

179 1.09056 11114.2 9720.5 120.45 249 0.749114 12707.7 10678.8 127.98

180 1.08316 11138.2 9735-0 120.59 250 0.745883 12729.7 10692.0 128*07

181 1.07587 11162.1 9749.4 120.72 251 0.742682 12751.7 10705.2 128.16

182 1.06870 11186.0 9763.8 120.85 252 0.73Q510 12773.6 10718.3 128.25

183 1.06163 11209.9 9778.2 120*98 253 0.736367 12795.6 10731.5 128.33

184 1.05468 11233.6 9792.5 121.11 254 0*733252 12817.5 10744.7 128.42

185 1.04782 11257.4 9806.8 121.24 255 0.730164 12839.4 10757.8 128.51

186 1.04107 11281.1 9821.1 121.37 256 0.727105 12861,4 10771.0 128.59

187 1.03*42 11304.7 9835.3 121. *9 257 0.724072 12883.2 10784,1 128,68

188 1,02786 11328,3 9849,6 121.62 258 0.721066 12905.1 10797.3 128,76

189 1.02140 11351.8 9863.7 121.74 259 0.718087 12927.0 10810.4 128.85

190 1.01503 11375.3 9877.9 121.87 260 0.715133 12948.9 10823.5 128,93

191 1.00875 11398.7 9892.0 121.99 261 0.712206 12970.7 10836.6 129.01

192 1 .00256 11422*1 9906.1 122.11 262 0.709303 12992.6 10849.7 129.10

193 0.996454 11445.5 9920.2 122.23 263 0.706425 1301**4 10862.8 129.18

194 0.960430 11468.8 9934.2 122.35 264 0.703572 13036.2 10875.9 129.26

195 0.984488 11492.1 99*8.2 122.47 265 0.700743 13058.0 10889,0 129.35

196 0.978626 11515.3 9962.2 122.59 266 0.697938 13079.8 10902.1 129.43

197 0.972842 11538.5 9976.2 122.71 267 0.695157 13101.6 10915.1 129.51

198 0.967135 11561.7 9990.1 122.83 268 0.692399 13123.4 10928.2 129,59

199 0.961502 11584.8 10004.0 122.94 269 0,689664 13145.1 10941.3 129.67

200 0.955942 11607.9 10017.9 123.06 270 0.686952 13166.9 10954.3 129.75

201 0.950453 11630.9 10031.8 123.18 271 0.684262 13188.6 10967.4 129.83

202 0.945035 11654,0 10045.6 123.29 272 0.681594 13210,4 10980.4 129.91

203 0.939685 11676.9 10059.5 123.40 273 0.678948 13232.1 10993.4 129.99

204 0.934402 11699.9 10073.3 123*52 274 0.676323 13253*8 11006.5 130.07

205 0.929185 11722*8 1 0087 * 1 123*63 275 0.673720 13275.5 11019.5 130*15

206 0.92*032 11745.7 10100.8 123.74 276 0.671137 13297.2 11032.5 130.23

207 0.9189*2 11768.6 10114.

6

123.85 277 0.668576 13318.9 11045.5 130.31

208 0.913914 11791.4 10128.3 123.96 278 0.666035 13340.6 11058.5 130.39

209 0.908947 11814.2 10142*0 124*07 279 0.663514 13362*2 11071*5 130*47

210 0*90*038 11837*0 10155.7 124*18 280 0*661013 13383*9 11084.5 130.54

211 0.899188 11859.7 10169.4 124.29 281 0.658531 13405.6 11097.5 130.62

212 0.89*396 11882.4 10183.0 124.39 282 0.656070 13427.2 'll 110.5 130.70

213 0.889659 11905.1 10196.7 124.50 283 0.653627 13448.8 11123.5 130.77

214 0.88*976 11927.8 10210.3 124.61 284 0.651203 13470.5 11136.5 130.85

215 0.880348 11950.4 10223.9 124.71 285 0.648798 13492.1 11149.4 130.93

216 0.875773 11973.0 10237.5 124.82 286 0.646412 13513.7 11162.4 131.00

217 0.871249 11995.6 10251.1 124.92 287 0.644044 13535.3 11175.4 131.08

218 0.866777 12018.2 10264.6 125.02 288 0.641694 13556.9 11188.3 131.15

219 0.862354 12040.7 10278.2 125.13 289 0.639362 13578.5 11201.3 131.23

220 0.857980 12063.2 10291.7 125.23 290 0*637047 13600*

l' 11214.2 131.30

221 0.853655 12085.7 10305.2 125.33 291 0.634750 13621.7 11227.2 131.38

222 0.849377 12108.2 10318.7 125.43 292 0.632470 13643.P 11240.1 131.45

223 0.845145 12130.6 10332.2 125.53 293 0.630207 13664.8 11253.0 131.52

224 0.840959 12153.1 10345.7 125.64 294 0.627961 13686.3 11266.0 131.60

225 0.836818 12175.5 10359.1 125.74 295 0,625732 13707.9 11278.9 131.67

226 0,832721 12197.8 10372.6 125.83 296 0.623519 13729.4 11291.8 131.74

227 0.828667 12220.2 103b6.0 125.93 297 0,621323 13751.0 11304.7 131,82

228 0.824656 12242.5 10399.5 126.03 298 0.619142 13772.5 11317.6 131.89

229 0.820686 12264.9 10412.9 126,13 299 0.616977 13794.6 11330.5 131.96

230 0.816758 12287.2 10426.3 126.23 300 0.61*828 13815.5 11343.4 132.03

84
20.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter j/mol energy j/mol-k

J/MOL

86 35.2315 2949.4 2891.8 53.70

87 35.0830 2994.6 2936.9 54.23

88 34.9329 3040.1 2982.1 54.75

89 34.7812 3085.8 3027.6 55.26

90 34.6279 3131.7 3073.2 55.78

PHASE CHANGF

temp. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91 34.4730 3177.8 3119.0 56.29

92 34.3167 3224.0 3165.0 56.79

93 34.1588 3270.4 3211.1 57.29

94 33.9995 3317.0 3257.4 57.79

95 33.8387 3363.8 3303.9 58.29

96 33.6764 3410.7 3350.5 58.78

97 33.5126 3457.8 3397.3 59.27

98 33.3473 3505.0 3444.3 59.75

99 33.1805 3552,4 3491.3 60.23

100 33.0121 3599.9 3538.5 60.71

101 32.8420 3647 .

6

3585.9 61.18

102 32.6704 3695.4 3633.3 61.65

103 32.4970 3743.3 3680.9 62.12

104 32.3219 3791.4 3728.7 62.59

105 32*1449 3839.6 3776*5 63.05

106 31 .9661 3887.9 3824.5 63.51

107 31.7853 3936.4 3872.6 63,96

108 31.6024 3985.0 3920.9 64.41

109 31.4173 4033.8 3969.3 64.86

110 31.2300 4082.7 4017.8 65.31

111 31.0403 4131.9 4066.6 65.75

112 30.8480 4181.2 4115.5 66.20

113 30.6531 4230.7 4164.5 66.64

114 30.4554 4280.4 4213.8 67.07

115 30.2546 4330.3 4263.4 67.51

116 30.0507 4380.6 4313.1 67.95

117 29.8433 4431.1 4363.2 68.38

118 29.6322 4482.6 4413.6 68.81

119 29.4173 4533.2 4464.3 69.24

120 29.1981 4584.8 4515.4 69.68

121 28.9743 4636.9 4567.0 70,11

122 28.7457 4689.5 4619.0 70.54

123 28.5116 4742,7 4671.7 70.98

124 28.2716 4796.6 4724.9 71.41

125 28.0252 4851 .2 4778.9 71.85

126 27.7717 4906.7 4833.7 72.29

127 27.5104 4963.2 4889.5 7?. 74

128 27.2402 5020.7 4946.3 73.19

129 26.9600 5079.6 5004.4 73.65

129.994 26.6705 5139.5 5063.6 74.11

129.994 2*59195 9507*7 8725*9 107*71

130 2.59162 9508.0 8726.0 107.72

131 2.53921 9551.6 8753.5 108.05

132 2.49036 9593.7 8780.0 108.37

133 2.44461 9634.6 8805.6 108.68

134 2.40159 9674.2 8830.4 108.98

135 2*36099 9712.9 8854.5 109.26

136 2*32255 9750*6 8878*0 109.54

137 2*28606 9787.5 8901*0 109.81

138 2*25134 9823*6 8923*4 110.08

139 2.21822 9859.0 8945.4 110.33

140 2*18656 9893.8 8966.9 110-58

141 2.15625 9927.9 8988.1 110.82

142 2.12717 9961.6 9008.9 111.06

143 2*09923 9994.7 9029.3 111.29

144 2-07236 10027.4 9049.5 111*52

145 2.04647 10059.6 9069.3 111.74

146 2*02150 10091*4 9088*9 111*96

147 1.99739 10122.8 9108*2 112*18

148 1 *97408 10153*9 9127*3 112*39

149 1.95153 10184.6 9146.1 112.59

150 1.92969 10215.0 9164.8 112.80

151 1 .90852 10245.1 9183.2 113.00

152 1.88798 10274.9 9201.5 113.19

153 1.86803 10304.4 9219*5 113.39

154 1 .84866 10333.7 9237.5 113.58

155 1.82982 10362*7 9255.2 113*77

156 1.81149 10391 .5 9272.8 113.95

157 1.79364 10420.1 9290.2 114.13

158 1 .77626 10448,4 9307.5 114.31

159 1.75931 10476.6 9324.7 114.49

160 1.74279 10504.6 9341.8 114.67
20.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL entropy TEMP. density ENTHALPY INTERNAL entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/mOL-K

161 1.72667 10532.4 9358.7 114.84 231 1.09367 12247.4 10394.4 123.74

162 1.71093 10560.0 9375.5 115.01 232 1 .08833 12270.2 10408.1 123.83

163 1 .69556 10587.4 9392.2 115.18 233 1.08304 12293.0 10421.8 123.93

164 1.68055 10614.7 9408.8 115.35 234 1.07781 12315.7 10435.5 124,03

165 1.66587 10641.8 9425.3 115,51 235 1.07264 12338.5 10449.2 124.13

166 1.65151 10668.7 9441.6 115.68 236 1.06752 12361.2 10462.8 124.22

167 1.63747 10695.6 9457.9 115.84 237 1.06246 12383.8 10476,4 124.32

168 1.62373 10722.2 9474*2 116.00 238 1.05744 12406.5 10490*0 124.41

169 1.61027 10748.8 9490*3 116.15 239 1.05248 12429.1 10503.6 124.51

170 1.59710 10775*2 9506*3 116.31 240 1*04757 12451 .7 10517.2 124.60

171 1.58419 10801.5 9522.3 116.46 241 1.04271 12474.3 10530.8 124.70

172 1 .57154 10827.7 9538*1 116.62 242 1*03790 12496.9 10544*4 124.79

173 1 .55914 10853*7 9553*9 116*77 243 1-03313 12519.4 10557*9 1 ?4 « 88

174 1 .54698 10879*7 9569*7 116.92 244 1*02842 1254?*

0

10571*4 124.98

175 1.53505 10905*5 9585*3 117*06 245 1.02375 12564*5 10584*9 125*07

176 1*52334 10931*2 9600*9 117*21 246 1*01913 12587*6 10598.5 125.16

177 1.5] 186 10956.9 9616.4 117.36 247 1.01455 12609.4 10611.9 125.25

178 1.50058 10982.4 9631.9 117.50 248 1.01002 12631.9 10625.4 125.34

179 1.48951 11007.8 9647.3 117.64 249 1.00553 12654.3 10638.9 125.43

180 1.47663 11033.2 9662.6 117.78 250 1.00108 12676.7 10652.3 125,52

181 1.46794 11058.4 9677.9 117.92 251 0.996681 12699.1 10665.8 125.61

182 1.45744 11083*6 9693.1 118.06 252 0*992319 12721.5 10679.2 125.70

183 1.44712 11108.7 9708.3 118.20 253 0.987999 12743.8 10692.7 125.79

184 1.43698 11133.7 9723.4 118.34 254 0-983719 12766.2 10706*1 125.88

185 1 *42700 11158.6 9738*5 118.47 255 0*979479 12788*5 10719*5 125.96

186 1.41719 11183.5 9753.5 118.61 256 0*975278 12810.8 10732.9 126.05

187 1.40754 11208.3 9768.5 118.74 257 0.971116 12833.1 10746.2 126.14

188 1.39804 11233.0 9783.4 118.87 258 0.966992 12855.3 10759.6 126,23

189 1.38869 11257.6 9798.3 119.00 259 0.962906 12877,6 10773.0 126.31

190 1.37949 11282.2 9813.1 119.13 260 0.958857 12899.8 10786.3 126.40

191 1.37044 11306.7 9827.9 119.26 261 0.954845 12922.0 10799.7 126.48

192 1.36152 11331.1 9842.7 119.39 262 0.950868 12944.2 10813.0 126.57

193 1.35274 11355.5 9857.4 119.51 263 0*946927 12966.4 10826.3 126.65

194 1.34409 11379.8 9872.0 119.64 264 0.943021 12988.6 10839.6 126.74

195 1.33557 11404.1 9866.7 119.76 265 0.939150 13010.8 10852.9 126.82

1 96 1.32717 11428.2 9901.3 119.89 266 0.935312 13032.9 10066.2 126.90

197 1 . 3] 890 11452.4 9915.8 120.01 267 0.931508 13055.1 10879.5 126.99

198 1.31074 11476.5 9930.4 120.13 268 0.927737 13077.2 10892.8 127.07

199 1.30271 11500.5 9944.9 120*25 269 0.923998 13099.3 10906.0 127.15

200 1.29478 11524.5 9959.3 120.37 270 0.920292 13121.4 10919.3 127.23

201 1.28697 11548.4 9973.7 120.49 271 0.916617 13143.4 10932.5 127.31

202 1-27926 11572*3 9988 •

1

120*61 272 0*912974 13165.5 10945.8 127.40

203 1.27166 11596.1 10002.5 120.73 273 0.909361 13187.6 10959.0 127.48

204 1.26416 11619.9 10016.8 120.85 274 0.905779 13209.6 10972.2 127.56

205 1.25677 11643.6 10031.1 120.96 275 0.902227 13231.6 10985.5 127.64

206 1.24947 11667.3 10045.4 121.08 276 0.898705 13253.6 10998.7 127.72

207 1.24227 11691.0 10059*6 121*19 277 0*895211 13275.6 11011-9 127*80

208 1 .23516 11714.6 10073.8 121.31 278 0.891747 13297.6 11025.1 127.88

209 1.22815 11738.1 10088.0 121.42 279 0.888311 13319.6 11038.3 127.96

210 1.22123 11761.6 10102.2 121.53 280 0,884903 13341 .6 11051.4 128.03

211 1.21439 11785.1 10116.3 121.64 281 0.881523 13363.5 11064.6 128.11

212 1 *20764 11808.5 10130*4 121*75 282 0*878170 13385.5 11077.8 128.19

213 1 .20097 11831.9 10144.5 121.86 283 0.874844 13407.4 11000.9 128.27

214 1 .19439 11855.3 10158.6 121.97 284 0.871545 13429.3 11104.1 128.34

215 1.18789 11878.6 10172.6 122.08 285 0.868272 13451.2 11117.2 128.42

216 1.18147 11901.9 10186.6 122.19 286 0.865025 13473.1 11130.4 128.50

217 1.17512 11925.2 10200.6 122.30 287 0.861804 13495.0 11143.5 128.58

218 1.16886 11948.4 10214.6 122.40 288 0.85860a 13516.9 11156.6 128.65

219 1.16266 1 1971.6 10228.6 122.51 289 0.855437 13538.8 11169.7 128.73

220 1.15654 11994.7 10242.5 122.61 290 0.852291 13560.6 11182.9 128.80

221 1.15049 12017.8 10256.4 122.72 291 0.849169 13582.5 11196.0 128.88

222 1 .14452 12040.9 10270.3 122.82 292 0.846071 13604.3 11209.1 128.95

223 1.13861 12064.0 10284.1 122.93 293 0.842997 13626.1 11222.2 129.03

224 1.13277 12087.0 10298.0 123.03 294 0.839947 13648.0 11235.2 129.10

225 1.12699 12110.0 10311.8 123.13 295 0.836920 13669.8 11248.3 129.18

226 1.12128 12133.0 10325.6 123.23 296 0.833916 13691.6 11261.4 129.25

227 1.11564 12155.9 10339.4 123.34 297 0.830034 13713.4 11274.5 129.32

228 1.11005 12178.8 10353.2 123.44 298 0.827975 13735.1 11287.5 129.40

229 1 .10453 12201.7 10367.0 123.54 299 0.825038 13756.9 11300.6 1?9.47

230 1.09907 12224.6 10380.7 123.64 300 0.822123 13778.7 11313.6 1?9.54

86
25.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 35.2683 2958.6 2886.7 53*64

87 35.1206 3003*8 2931*6 54.17

88 34.9713 3049.1 2976*7 54*69

89 34.8204 3094.7 3022*0 55.20

90 34.6680 3140.5 3067.4 55.71

PHASE CHANGF

TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOI. /liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.5141 3186.4 3113.0 56.22

92 34.3587 3232*6 3158*9 56*72

93 34.2018 3278.9 3204.8 57.22

94 34.0435 3325.4 3251.0 57.72

95 33.8838 3372.0 3297.2 58.22

96 33.7226 3418.8 3343.7 58.71

97 33.5600 3465.7 3390,3 59.19

98 33.3960 3512.8 3437.0 59.67

99 33.2304 3560.1 3483.8 60.15

100 33.0634 3607.4 3530.8 60.63

101 32.8948 3654.9 3577.9 61.10

102 32.7246 3702.6 3625.2 61.57

103 32.5528 3750.3 3672.5 62.04

104 32*3793 3798.2 3720.0 62.50

105 32*2041 3846.? 3767.6 62.96

106 32*0271 3894.4 3815.3 63.42

107 31.8482 3942.6 3863.1 63.87

108 31.6673 3991.0 3911.0 64.32

109 31.4844 4039.6 3959.1 64*77

no 31*2993 4088.3 4007*3 65*21

111 31.1120 4137.1 4055.7 65.65

112 30.9223 4186.1 4104.2 66.09

113 30.7301 4235.3 4152.9 66.53

114 30.5352 4284,7 4201.8 66.97

115 30.3375 4334.3 4250.8 67.40

116 30.1368 4384.? 4300.1 67.83

117 29.9330 4434.3 4349.7 68.26

118 29.7257 4484.7 4399.5 68.69

119 29.5149 4535.5 4449.6 69.1?

120 29.3001 4586.6 4500.1 69.55

121 29.0811 4638.1 4551.0 69.97

122 28.8577 4690.1 4602.3 70.40

123 28.6293 4742.6 4654.1 70.83

124 28.3957 4795.7 4706.5 71.26

125 28.1562 4849.5 4759.5 71.69

126 27.9104 4904.1 4813*3 72*13

127 27.6576 4959.5 4867.9 72.57

128 27.3971 5015.8 4923*4 73.01

129 27.1280 5073.3 4980.0 73.46

130 26.8492 5132.1 5037.8 73.91

131 26.5594 5192.4 5097.0 74.37

132 26.2572 5254.4 5157.9 74.84

133 25.9405 5318.4 5220.7 75.33

134 25.6069 5384.8 5285*8 75.82

134.829 25.3151 5441.9 5341.9 76.25

134.829 3*36017 9388*3 8634*4 105*52

135 3.34525 9397.7 8640.4 105.59

136 3*26288 9451*0 8674*6 105*98

137 3.18785 9501.6 8707.0 106.35

138 3.11895 9549.9 8737.7 106.70

139 3.05522 9596.3 8767.2 107.04

140 2.99593 9641.0 8795.5 107.36

141 2.94050 9684,3 8822.8 107.67

142 2.88846 9726.2 8849.2 107.96

143 2.83941 9767.0 8874.8 108.25

144 2.79304 9806.7 8899.8 108.53

145 2.74906 9845.5 8924.0 108.79

146 2.707?5 9883.5 8947.7 109.05

147 2.66740 9920.6 8970.9 109.31

148 2.62935 9957.1 8993.6 109.56

149 2.59294 9992.8 9015.9 109.80

150 2 • 55804 10028.0 9037*7 110*03

151 2.52454 10062.6 9059.2 110.26

152 2.49232 10096.7 9080.3 110.49

153 2.46131 10130.3 9101.1 110.71

154 2.43141 10163.4 9121.6 110.92

155 2.40255 10196.1 9141.8 111.13

156 2 • 3 7 4 b 7 10228.4 9161*7 111.34

157 2*34770 10260.4 9181.4 111.55

158 2.32159 10291.9 9200.8 111.75

159 2*29629 10323.2 9220*0 111*94

160 2.27176 10354.1 9239.0 1 1 2 . 1 4

316-977 0 - 69-7
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181

182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

25.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

mol/liteh J/MOL energy

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

2.24794 10384.7 9257.8 112.33 231 1.37957 12184.8 10348.6 121.68

2.22481 10415.0 9276.4 112.52 232 1.37261 12208.1 10362.6 121.78

2.20233 10445.0 9294.8 112.70 233 1.36573 12231.5 10376.7 121.88

2.18046 10474.8 9313.] 112*88 234 1.35894 12254.8 10390.7 121.98

2.15917 10504.4 9331.1 113.06 235 1.35221 12278.0 10404.7 122.08

2.10844 10533.7 9349.1 113.24 236 1.34556 12301.3 10418.6 122.18

2.11824 1G562.8 9366.9 113.41 237 1.33899 12324.5 10432.6 122.28

2.09855 10591.6 9384.5 113.59 238 1.33248 12347.6 10446.5 122.38

2.07933 10620.3 9402.0 113.76 239 1.32605 12370.8 10460.4 122.47

2.08053 10648.7 9419.4 113.92 240 1.31969 12393.9 10474.3 122.57

2.04227 10677.0 9436.6 114.09 241 1.31339 12416.9 10488.2 122.67

2.02438 10705.1 9453.8 114.25 242 1.30716 12440.0 10502.1 122.76

2.00690 10733.0 9470.6 114.42 243 1.30100 12463.0 10515.9 122.86

1 .9=>981 10760*8 9487.7 114.58 244 1.29490 12486.6 10529.7 122.95

1.97309 10788*4 9504*5 114*73 245 1*28886 12509.0 10543*5 123*05

1.95672 10815.8 9521.2 114.89 246 1.28288 12531.9 10557.3 123.14

1.94071 10843.1 9537.8 115.04 247 1.27697 12554.9 10571.1 123.23

1.92502 10870.2 9554.3 115.20 248 1.27112 12577.7 10584.9 123.32

1.90966 10897.2 9570.7 115.35 249 1.26533 12600.6 10598.6 123.42

1.89460 10924.1 9587.0 115.50 250 1.25959 12623.5 10612.3 123.51

1.87985 10950.8 9603.3 115.65 251 1.25391 12646.3 10626.1 123.60

1.86538 10977.5 9619.5 115.79 252 1.24829 12669.1 10639.8 123.69

1.85118 11004.0 9635.5 115.94 253 1 .24272 12691 .9 10653.4 123.78

1.83726 11030.3 9651 .5 116.08 254 1*23721 12714.6 10667.1 123.87

1.82359 11056.6 9667.5 116.22 255 1.23175 12737.3 10680.8 123.96

1.81018 11082.8 9683.3 116.37 256 1.22635 12760.0 10694.4 124.05

1.79700 11108.8 9699.1 116.51 257 1.22099 12782.7 10708.0 124.14

1.78407 11134.8 9714.9 116.64 258 1.21569 12805.4 10721.6 124.22

1.77136 11160.6 9730.5 116.78 259 1.21044 12828.0 10735.2 124.31

1.75887 11186.4 9746.1 116.92 260 1.20523 12850.6 10748.8 124.40

1.74659 11212.0 9761.7 117.05 261 1.20008 12873.3 10762.4 124.49

1*73453 11237-6 9777*2 117.19 262 1*19497 12895*8 10776*0 124*57

1.72266 11263*1 9792.6 117.32 263 1*18991 12918.4 10789.5 124.66

1.7] 099 11288.5 9808.0 117.45 264 1.18490 12940.9 10803*1 124.74

1.69951 11313.8 9823.3 117*58 265 1.17994 12963.5 10816*6 124.83

1.68821 11339.1 9838*5 117.71 266 1.17501 12986.0 10830.1 124.91

1.67710 11364.2 9653*8 117.84 267 1*17014 13008.5 10843.6 125*00

1.66616 11389.3 9868.9 117.96 268 1.16531 13030.9 10857.1 125.08

1.65539 11414.3 9884.0 118.09 269 1.16052 13053.4 10870.6 125.17

1.64478 11439.3 9899.1 118.21 270 1,15577 13075.8 10884,0 125.25

1.63434 11464.1 9914.1 118.34 271 1.15106 13098.2 10897.5 125.33

1.62405 11488.9 9929,1 118.46 272 1.14640 13120.6 10910.9 125.41

1.61392 11513.7 9944.1 118.58 273 1.14178 13143.0 10924,4 125.50

1.60393 11538.3 9959.0 118.70 274 1.13720 13165.4 10937.8 125.58

1.59409 11562.9 9973.8 118.62 275 1.13265 13187.7 10951.2 125.66

1.58439 11587.5 9988,6 118.94 276 1.12815 13210.1 10964.6 125.74

1.57483 11612.0 10003.4 119.06 277 1.12368 13232.4 10978.0 125.82

1.56541 11636.4 10018.1 119.18 278 1.11926 13254.7 10991.4 125.90

1.55611 11660.7 10032.9 119.30 279 1.11487 13277.0 11004.8 125.98

1.54694 11685.1 10047.5 119.41 280 1.11052 13299.2 11018.2 126.06

1.53790 11709.3 10062.2 119.53 281 1.10620 13321.5 11031.5 126.14

1.52899 11733.5 10076.7 119.64 282 1.10192 13343.8 11044.9 126.22

1 .52019 11757.7 10091.3 119.76 283 1.09768 13366.0 11058.2 126.30

1.51151 11781.8 10105.8 119.87 284 1.09347 13388.2 11071.5 126.38

1.50294 11605.8 10120.3 119.98 285 1.08929 13410.4 11084.9 126.45

1,49448 11829.8 10134.8 120.09 286 1.08515 13432.6 11098.2 126.53

1.48614 11853.8 10149.3 120.20 287 1.08104 13454.8 11111.5 126.61

1.47790 11877.7 10163.7 120*31 288 1.07697 13476.9 11124.8 126.69

1*46977 11901*6 10178*0 120*42 289 1 • 07293 13499*1 11138.1 126*76

1.46173 11925*4 10192.4 120*53 290 1.06892 13521.2 11151.4 126.84

1.45380 11949.2 10206.7 120.64 291 1.06495 13543.3 11164.6 126.92

1.44597 11972.9 10221.0 120.75 292 1.06100 13565.4 11177.9 126.99

1 .43823 11996.6 10235.3 120.85 293 1.05709 13587.5 11191.2 127.07

1.43059 12020.3 10249.5 120.96 294 1.05320 13609.6 11204.4 127.14

1 .42304 12043.9 10263.8 121.06 295 1.04935 13631.7 U217.7 127.22

1.41558 12067.5 10277.9 121.17 296 1.04553 13653.8 11230.9 127.29

1.40820 12091.0 10292.1 121.27 297 1.04174 13675.8 11244.1 127.37

1.40092 12114.5 10306.3 121.38 298 1.03797 13697.8 11257.3 127.44

1.39372 12138.0 10320.4 121.48 299 1.03424 13719.9 11270.6 127.51

1.38660 12161.4 10334.5 121.58 300 1.03053 13741.9 11283.8 127.59

88
30.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY internal ENTROPY

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K

86 35.3048 2967.8 2881.7 53.59

87 35.1579 3012*9 2926*4 54*11

88 35 .0094 3058*2 2971*3 54*62

89 34.8593 3103*6 3016*4 55.14

90 34.7077 3149.3 3061.7 55.65

PHASE CHANGE

TFMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENFRGY

J/MOL

J/MOL -K

91 34.5547 3195.2 3107.2 56.15

92 34.4002 3241.2 3152.8 56 .66 93 34*2443 3287.4 3198*6 57*16

94 34*0871 3333*7 3244.6 57.65

95 33.9284 3380.3 3290.7 58.14

96 33.7683 3426.9 3336.9 58.63

97 33.6069 3473.7 3383.3 59.12

98 33.4440 3520.7 3429.8 59.60

99 33.2797 3567.8 3476.4 60,08

100 33.1140 3615.0 3523.2 60.55

101 32.9468 3662.4 3570.1 61.02

102 32.7780 3709.8 3617.1 61.49

103 32.6078 3757.4 3664.2 61.96

104 32.4359 3805.1 3711.4 62.42

105 32.2623 3853.0 3758.7 62.87

106 32.0870 3900.9 3806.2 63.33

107 31.9100 3949.0 3853.7 63.78

108 31.7310 3997.2 3901.4 64.23

109 31 .5502 4045.5 3949.1 64.67

110 31 .3672 4093*9 3997*0 65.12

111 31.1822 4142.5 4045.0 65,56

112 30.9949 4191.3 4093.2 65.99

113 30.8053 4240.2 4141 .5 66.43

114 30.6131 4289.2 4190*0 66*86

115 30.4183 4338.5 4238*6 67.29

116 30.2208 4388.6 4287.4 67.72

117 30,0202 4437.8 4336.5 68.15

118 29.8165 4487.8 4385.8 68.57

119 29.6095 4538.1 4435.4 69.00

120 29.3988 4588.7 4485.3 69.42

121 29.1844 4639.7 4535.5 69.84

122 28,9657 4691.1 4586.2 70,27

123 28.7426 4743.0 4637.2 70.69

124 28.5147 4795.4 4688.8 71,11

125 28.2815 4848.4 4741.0 71,54

126 28.0427 4902.1 4793.7 71.97

127 27.7976 4956.6 4847.3 72.40

128 27.5457 5011.9 4901.6 72.83

129 27.2861 5068.2 4956.8 73.27

130 27,0182 5125.7 5013.2 73.71

131 26.7409 5184-4 5070.7 74.16

132 26.4530 5244. 5129.7 74.62

133 26*1530 5306*5 5190*3 75*09

134 25.8391 5370.4 5252.8 75.57

135 25.5091 5436.6 5317.4 76.06

136 25.1601 5505.1 5384 ,

3

76.57

137 24.7880 5576.6 5454.0 77.09

138 24.3876 5651.8 5527.2 77.64

139 23.9512 5731.7 5604.8 78.21

139.003 23.9500 5731.9 5605.0 78.22

139.003 4.23873 9236.1 8519.0 103.43

140 4.10309 9305.1 8564.2 103*92

141 3.98419 9368.7 8605.8 104.37

142 3.87842 9428.0 8644.2 104.79

143 3.78310 9483.8 8680*3 105.18

144 3*69628 9536.8 8714.4 105.55

145 3*61655 9587*3 8746*8 105*90

146 3.54283 9635.8 8777.8 106.24

147 3.47426 9682.4 8807.5 106.55

148 3.41016 9727.5 8836.1 106.86

140 3.35000 9771.2 8863.8 107.15

150 3.29331 9813.7 8890.6 107.44

151 3.23973 9855.0 8916.7 107.71

152 3.18893 9895.3 8942.1 107.98

153 3.14064 9934.7 8966.8 108.24

154 3.09464 9973.3 8991.0 108.49

155 3.05072 10011.1 9014.6 108.73

156 3.00870 10048.2 9037.8 108.97

157 2*96843 10084.6 9060*5 109-20

158 2*92978 10120*4 9082*9 109.43

159 2*89263 10155*7 9104*8 109-65

160 2.85686 10190.4 9126.4 109.87
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

ISO

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211 212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

30.00 atmosphere ISOBAR

density enthalpy INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL Entropy

MOL/LITEK J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOl.-K

2.82239 10224.7 9147.6 110*08 231 1.67063 12121.6 10302.1 119.97

2.78913 10258.4 9168.5 110.29 232 1.66194 12145.6 10316.5 120.07

2,75699 10291,8 9lb9.2 110.50 233 1.65335 12169.5 10330.9 120.17

2.72692 10324.7 9209.5 110.70 234 1 .644B7 12193.3 10345.3 120.27

2.69684 10357.3 9229.7 110.90 235 1.63648 12217.1 10359.6 120.38

2.66669 10389.4 9249.5 111*09 236 1.62819 12240.9 10373.9 120.48

2*63843 10421*3 9269*1 111*28 237 1*62000 12264*7 10388*2 120*58

2 . 6 1 1 0 0 10452.8 9288.6 111*47 238 1.61190 12288.4 10402.5 120.68

2.58437 10484.0 9307.8 111.66 239 1.60389 12312.0 10416.7 120.78

2.55848 10514.9 9326.8 111*64 240 1.59597 12335.6 10431.0 120.87

2.53330 10545.5 9345.6 112.02 241 1 .58814 12359.2 10445.1 120.97

2.50879 10575.9 9364.2 112.20 242 1.58040 12382.8 10459.3 121.07

2.48493 10606.0 9382.7 112.37 243 1.57274 12406.3 10473.5 121.17

2.46168 10635.9 9401.0 112.54 244 1.56517 12429.8 10487.6 121.26

2.43901 10665.5 9419.2 112.71 245 1.55768 12453.2 10501.7 121.36

2.41690 10694.9 9437.2 112.88 246 1.55027 12476.6 10515.8 121.46

2.39532 10724.1 9455.1 113.05 247 1 .54294 12500.6 10529.9 121.55

2.3742b 10753*1 9472*8 113*21 248 1 *53568 12523*4 10543*9 121*64

2.35367 10781.9 9490.4 113,37 249 1.52851 12546.7 10558.0 121.74

2.33355 10810.5 9507,9 113.53 250 1,52140 12570,0 10572.0 121,83

2.31389 10839.0 9525.2 113.69 251 1.51438 12593.3 10586.0 121 .92

2*29465 10867*2 9542*5 113*84 252 1*50742 12616*5 10599*9 122*02

2.27583 10895*3 9559.6 114.00 253 1*50054 . 12639.7 10613.9 122*11

2.25741 1C923.2 9576.6 114.15 254 1.49372 12662.9 10627.8 122.20

2,23936 10951.0 9593.6 114.30 255 1.48698 12686.0 10641 ,7 122.29

2.22169 1C978.6 9610.4 114.45 256 1 .48030 12709.1 10655.6 122.38

2.20436 11006.1 9627.1 114.60 257 1.47369 12732.2 10669.5 122.47

2.18740 11033,4 9643.7 114.74 258 1.46715 12755.3 10683.4 122.56

2.17076 11060.7 9660.3 114.89 259 1.46067 12778.3 10697.2 122.65

2.15443 11087.7 9676.8 115.03 260 1.45425 12801.4 10711.1 122.74

2.13842 11114.7 9693.1 115.17 261 1.44790 12824.4 10724.9 122.83

2.12270 11141.5 9709.4 115.31 262 1.44160 12847.3 10738.7 122.92

2.10727 11168.2 9725.7 115.45 263 1.43537 12870.3 10752.5 123.00

2.09213 11194.8 9741.8 115.59 264 1.42920 12893.2 10766.2 123,09

2.07725 11221.3 9757.9 115.72 265 1.42308 12916.1 10780.0 123.18

2.06263 11247.7 9773.9 115.86 266 1.41703 12939.0 10793.7 123.26

2.04827 11273*9 9789.

8

115*99 267 1*41103 12961 *R 10807.5 123.35

2*03415 11300*1 9805*7 116*12 268 1*40508 12984*6 10821*2 123*43

2*02027 11326.2 9821.5 116.26 269 1*39919 13007.4 10834.9 123.52

2.00663 11352.2 9837.3 116.39 270 1.39336 13030.2 10848.6 123.60

1.99321 11378.0 9852.9 116.51 271 1.38758 13053.0 10862.2 123.69

1.98000 11403.8 9868.6 116.64 272 1.38185 13075.7 10875.9 123.77

1 .96701 11429.5 9884.1 116.77 273 1 .37617 13098.4 10889.5 123.85

1.95*23 11455.2 9899.7 116,90 274 1.37055 13121,1 10903.2 123.94

1 .94165 11480.7 9915.1 117.02 275 1.36497 13143.8 10916,8 124.02

1.92926 11506.2 9930.5 117.14 276 1.35945 13166.5 10930.4 124.10

1.91706 11531.5 9945.9 117.27 277 1.35397 13189.1 10944.0 124.10

1.90505 11556.8 9961.2 117.39 278 1.34854 13211.8 10957.6 124.27

1.89322 11562.1 9976.4 117.51 279 1.34316 13234.4 10971.2 124.35

1.88156 11607.2 9991.7 117.63 280 1.33782 13256.9 10984.7 124.43

1.87008 11632.3 10006.8 117.75 281 1.33254 13279.5 10998.3 124.51

1.85876 11657*3 10021*9 117.87 282 1*32729 13302*1 11011.8 124.59

1.84760 11682*3 10037.0 117.99 283 1.32209 13324*6 11025.3 124.67

1.83660 11707*2 10052*1 118*10 284 1*31694 13347*1 11038.9 124.75

1.82576 11732.0 10067.0 118.22 285 1.31183 13369.6 11052.4 124.83

1 .81507 11756.8 10082.0 118.33 286 1.30676 13392.1 11065.9 124.90

1.80452 11781.5 10096.9 118.45 287 1.30174 13414.6 11079.3 124.98

1.79412 11806.1 10111.

6

118.56 288 1.29675 13437.6 11092.8 125.06

1.78386 11830*7 10126.6 118.67 289 1*29181 13459.4 11106*3 125.14

1.77374 11855*2 10141.4 118.78 290 1*28691 13481.9 11119.7 125.22

1.76375 11879.7 10156.2 118.90 291 1.28205 13504.3 11133.2 125.29

1.75390 11904.1 10170.9 119.01 292 1.27723 13526.6 11146.6 125.37

1*74417 11928*5 10185*6 119*11 293 1*27245 13549*6 11160*1 125*45

1*73456 11952*8 10200*3 119*22 294 1*26770 13571*4 11173*5 125*52

1 *72508 11977*1 10214*9 119*33 295 1 *26300 13593*7 11186*9 125*60

1*71572 12001*3 10229*5 119*44 296 1*25833 13616*0 11200*3 125*67

1.70648 12025.4 10244*1 119.55 297 1*25370 13638*3 11213*7 125.75

1*69735 12049*6 10258*6 119.65 298 1*24911 13660*6 11227*0 125.82

1*68834 12073*6 10273*1 119*76 299 1*24455 13682*9 11240*4 125*90

1*67943 12097*7 10287*6 119*86 300 1*24003 13705*2 11253*8 125*97

90
35.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY

K mol/liter J/MOL energy

J/MOL

J/MOL-K

86 35.3409 2977.1 2876.7 53-53

87 35.1948 3022.0 2921.3 54.05

88 35.0470 3067.2 2966.0 54,56

89 34.8977 3112.6 3011.0 55.07

90 34.7470 3158.2 3056.1 55.58

PHASE CHANGE

TEMP. DENSITY ENTHALPY intfrnal ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 34.5949 3203.9 3101.4 56.09

9? 34.4413 3249.8 3146.8 56.59

93 34.2864 3295.9 3192.5 57.09

94 34.1301 3342.1 3238.2 57.58

95 33.972A 3388.5 3284.2 58.08

96 33.8135 3435.1 3330.2 58.56

97 33.6531 3481.8 3376.4 59.05

98 33.4914 3528.6 3422.7 59.53

99 33.3284 3575.6 3469.2 60.00

100 33.1639 3622.7 3515*7 60.48

101 32.9980 3669.9 3562.4 60.95

102 32.8307 3717*2 3609.2 61*41

103 32*6619 3764.6 3656*0 61*88

104 32*4915 3812*1 3703*0 62*33

105 32*3196 3859*8 3750*1 62*79

106 32*1460 3907*6 3797*2 63*24

107 31*9707 3955*4 3844*5 63*69

108 31.7936 4003.4 3891.9 64.14

109 31.6147 4051.5 3939.3 64.58

110 31.4339 4099.7 3986.9 65.02

111 31.2510 4148.1 4034.6 65.46

112 31*0660 4196.6 4082*4 65.90

113 30.8788 4245.2 4130.3 66.33

114 30.6893 4294.0 4178.4 66.76

115 30.4972 4342.9 4226.6 67.18

116 30.3026 4392.1 4275.1 67.61

117 30.1052 4441 .5 4323.7 68.03

118 29.9049 4491.1 4372.5 68.46

119 29.7014 4541.6 4421.6 68.88

120 29 . 4946 4591.1 4470.9 69.30

121 29.2842 4641.6 4520.5 69.72

122 29.0701 4692.5 4570.5 70.14

123 28.8518 4743.9 4620.9 70*55

124 28.6292 4795.6 4671.8 70.97

125 28.4018 4848.0 4723.1 71.39

126 28.1692 4900.9 4775.0 71.82

127 27*9311 4954.5 4827.5 72.24

128 27*6868 5ooe*9 4880*8 72*67

129 27.4359 5064.2 4934.9 73.10

130 27*1775 5120*4 4989*9 73*53

131 26.9110 5177.8 5046.0 73.97

132 26.6353 5236.4 5103.3 74.42

133 26.3494 5296.6 5162.0 74.87

134 26*0519 5358.4 5222*3 75.33

135 25.7411 5422.2 5284.4 75.81

136 25.4149 5487.8 5348.2 76.29

137 25.0707 5555.7 5414.2 76.79

138 24.7051 5626.5 5482.9 77.30

139 24.3133 5700.6 5554.8 77.84

140 23.8889 5779.0 5630.6 78.40

141 23.4222 5862.9 5711.5 79.00

142 22*8981 5954*5 5799*6 79*65

142*688 22*4910 6023*6 5866*0 80.13

142.688 5.29148 9041.6 8371.3 101.28

143 5.21281 9072.9 8392.6 101.50

144 4.99499 9163.6 8453.6 102.13

145 4.81481 9243.4 8506.8 102*69

146 4.66066 9315.5 8554.5 103.18

147 4.52569 9381*8 8598*2 103.64

148 4 .40553 9443.6 8638.6 104.05

149 4*29718 9501*8 8676*5 104*45

150 4.19849 9557.0 8712.3 104.82

151 4.10785 9609.6 8746.2 105.17

152 4.02404 9660.0 8778.7 105.50

153 3.94611 9708.5 8809.8 105.82

154 3.87328 9755.3 8839.7 106.12

155 3.80493 9800.7 8868.6 106.41

156 3.74055 9844.7 8896*6 106.70

157 3.67971 9887.6 8923.8 106.97

158 3.62204 9929.4 8950.2 107.24

159 3.56724 9970.1 8976.0 1 07.49

160 3.51504 10010.1 9001.1 107.74
35.00 ATMOSPHERE ISOBAR

TEMP. oensity ENTHALPY INTERNAL ENTROPY TEMP. DENSITY enthalpy INTERNAL entropy

K MOL/LITE* J/MOL ENERGY

J/MOL

j/mol-k K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

161 3.48522 10049.1 9025.7 107.99 231 1.96694 12058.0 10255.0 118.48

162 3.41757 10087.5 9049.7 108.23 232 1.95638 12082.5 10269.8 118.59

163 3.37192 10125.1 9073.3 108. *6 233 1.94595 12107.6 10284.5 118.69

164 3.32812 10162,1 9096.5 108.68 234 1.93566 12131.5 10299.3 118.80

165 3.28601 10198.4 9119.2 108.90 235 1,92548 12155.8 10314.0 118.90

166 3.24550 10234.3 9141.5 109.12 236 1.91544 12180.2 10328.7 119.00

167 3.20645 10269.5 9163.5 109.33 237 1.90551 12204.5 10343.3 119.11

168 3.16878 10304.3 9185.1 109.54 238 1.89571 12228.7 10357.9 119.21

169 3.12240 1C338.7 9206.5 109.74 239 1.88602 12252.9 10372.5 119,31

170 3.09722 10372.6 9227.5 109.94 240 1.87644 12277.1 10387.1 119.41

171 3.06317 10406.0 9248.3 110.14 241 1.86698 12301.2 10401.6 119.51

172 3.03019 10439.1 9268.8 110.33 242 1,85762 12325.3 10416.1 119.61

173 2.99822 10471.9 9289.0 110*52 243 1*84838 12349.3 10430*6 119.71

174 2.96719 10504.2 9309.0 110*71 244 1 .83924 12373*3 10445*0 119.81

175 2*92706 10536*3 9328*8 110*89 245 1*83020 12397*2 10459*5 119*91

176 2.90779 1C568.0 9348.4 111.07 246 1.82127 12421.1 10473.9 120.00

177 2.87931 1C599.4 9367.7 111,25 247 1,81243 12445.0 10488.2 120.10

178 2.85161 10630.6 9386.9 111. *3 248 1.80370 12468.8 10502.6 120.20

179 2.82463 10661.4 9405.9 111.60 249 1.79506 12492.6 10516.9 120.29

180 2.79835 10692.1 9424.7 111*77 250 1.78651 12516.4 10531*2 120.39

181 2.77274 10722.4 9443.4 111.94 251 1.77806 12540.1 10545.5 120.48

182 2.74775 10752*5 9461*9 112*11 252 1*76969 12563*7 10559*7 120.58

183 2.72337 10782*4 9480*2 112*27 253 1 *76142 12587*4 10574*0 120*67

184 2.69956 10812*1 9498*4 112*43 254 1*75323 12611*0 10588*2 120*76

185 2*67631 10841*6 9516*5 112*59 255 1*74513 12634*6 10602*4 120*86

186 2*66359 10870*9 9534*4 112*75 256 1*73712 12658*1 10616*6 120*95

187 2*63138 10899*9 9552*2 112*90 257 1*72918 12681*6 10630*7 121*04

188 2.60966 10928.8 9569.8 113.06 258 1.72133 12705.1 10644.8 121.13

189 2.58840 10957.5 9587.4 113.21 259 1.71356 12728.6 10658.9 121.22

190 2.56760 10986.0 9604.8 113.36 260 1.70587 12752.6 10673.0 121.31

191 2.54723 11014.4 9622.1 113.51 261 1.69826 12775.4 10687.1 121.40

192 2.52727 11042.6 9639.3 113.66 262 1.69072 12798.7 10701.1 121.49

193 2.50772 11070.7 9656 .

5

113.80 263 1.68326 12822.1 10715.2 121.58

194 2.48856 11098.6 9673.5 113.95 264 1.67587 12845.4 10729.2 121*67

195 2.46978 11126.3 9690.4 114.09 265 1.66855 12868.6 10743*2 121*76

196 2.45135 11154.0 9707*2 114*23 266 1*66131 12891*9 10757*2 121*85

197 2.43328 11181.4 9724.0 114.37 267 1.65413 12915.1 10771.1 121.93

198 2.41554 11208.8 9740.6 114.51 268 1.64703 12938.3 10785.1 122.02

199 2.39813 11236.0 9757.2 114.65 269 1.63999 12961.5 10799.0 122.11

200 2.38103 11263,1 9773.7 114.78 270 1.63302 12984.6 10812.9 122.19

201 2.36*24 11290.1 9790.1 114.92 271 1.62611 13007.7 10826.8 122.28

202 2.34775 11317.0 9806.4 115.05 272 1.61928 13030,8 10840.7 122,36

203 2.33154 11343.7 9822,6 115.18 273 1.61250 13053.9 10854.5 122.45

204 2.31561 11370.4 9838.8 115.31 274 1.60579 13076.9 10868.4 122.53

205 2.29995 11396.9 9854.9 115.44 275 1 .59914- 13099.9 10882.2 122,61

206 2.28455 11*23.4 9871.0 115.57 276 1.59255 13122.9 10896.0 122.70

207 2.26941 11449.7 9887.0 115.70 277 1.58602 13145.9 10909.8 122.78

208 2.25*52 11475.9 9902.9 115.83 278 1.57954 13168.8 10923*6 122*86

209 2.23986 11502*1 9918.8 115.95 279 1*57313 13191.8 10937*4 122*95

210 2 • 2?544 11528*2 9934*6 116*08 280 1*56678 13214*7 10951*1 123*03

211 2.21124 11554.1 9950.3 116.20 281 1.56048 13237.6 10964.9 123.11

212 2.1R727 11580.0 9966.0 116.32 282 1.55424 13260.4 10978.6 123.19

213 2.18351 11605.8 9981.6 116.44 283 1 .54805 13283.3 10992*3 123*27

214 2*16996 11631*5 9997*2 116*56 284 1*54191 13306*1 11006*0 123*35

215 2.15661 11657*2 10012*7 116*68 285 1 *53583 13328.9 11019*7 123.43

216 2.14346 11682*7 10028*2 116*80 286 1*52981 13351 *7 11033*4 123*51

217 2.13050 11708*2 100*3*6 116*92 287 1*52383 13374.4 11047*1 123*59

218 2*11773 11733*6 10059*0 117*04 288 1*51791 13397*2 11060*7 123*67

219 2*10515 11759*0 10074*3 117*15 289 1*51203 13419*9 11074*4 123*75

220 2.09274 11784.2 10089.6 117.27 290 1.50621 13442.6 11088.0 123.83

221 2.08051 11809.4 10104.8 117.38 291 1.50043 13465.3 11101.6 123.91

222 2.06845 11834.6 10120.0 117.50 292 1.49471 13487.9 11115.2 123.98

223 2.05656 11859.6 10135.2 117.61 293 1.48903 13510.6 11128.8 124.06

224 2,04402 11884.6 10150.3 117.72 294 1.48340 13533.2 11142,4 124.14

225 2.03325 11909.6 10165.3 117.83 295 1.47781 13555.8 11156.0 124.21

226 2.02183 11934.5 10160.4 117.94 296 1.47227 13578.4 11169.6 124.29

227 2.01056 11959.3 10195.4 118.05 297 1.46678 13601.6 11183.1 124.37

228 1 .99944 11984.0 10210.3 118.16 298 1.46133 13623.5 11196.7 124.44

229 1.98847 12008.

7

10225*2 118*27 299 1*45592 13646*1 11210*2 124.52

230 1.97764 12033.4 10240.1 118.37 300 1.45056 13668.6 11223.7 124.59

92
40.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86 35*3767 2986.3 2871*8 53*47

87 35.2313 3031.2 2916.2 53.99

88 35.0843 3076.3 2960,8 54.50

89 34.9358 3121.6 3005.6 55.01

90 34.7059 3167.0 3050.5 55.52

PHASE CHANGE

TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91 34.6346 3212.7 3095.6 56.02

92 34.4819 3258.5 3140.9 56.53

93 34.3279 3304.5 3186.4 57.02

94 34.1726 3350.6 3232.0 57.52

95 34.0160 3396.9 3277.7 58.01

96 33.8581 3443.3 3323.6 58.49

97 33.6988 3489.9 3369.6 58.97

98 33.5383 3536.6 3415.7 59.45

99 33.3764 3583.4 3462.0 59.93

100 33.2132 3630.4 3508.3 60.40

101 33.0486 3677.4 3554.8 60.87

102 32.8826 3724.6 3601.3 61.33

103 32.7152 3771.9 3648.0 61.80

104 32.5463 3819.2 3694.7 6?. 25

105 32,3759 3866.7 3741.5 62.71

106 32.2040 3914.3 3788.4 63.16

107 32.0304 3962.0 3835.4 63.61

108 31.8551 4009.8 3882.5 64.05

109 31.6781 4057.7 3929.7 64.49

110 31.4992 4105.7 3977.0 64.93

111 31.3185 4153.8 4024.3 65.37

112 31.1357 4202.6 4071.8 65.80

113 30.9508 4250.4 4119.4 66.23

114 30.7637 4298.9 4167.1 66.66

115 30.5743 4347.5 4215.0 67.08

116 30.3825 4396.4 4263.0 67.50

117 30.1880 4445,4 4311.1 67.92

118 29.9908 4494.6 4359.5 68.34

119 29.7907 4544.1 4408.1 68.76

120 29.5876 4593.9 4456.9 69.18

121 29.3011 4643.9 4506.0 69.59

122 29.1711 4694 o 3 4555.4 70.01

123 20.9573 4745.1 4605.1 70.42

124 28.7395 4796.3 4655.3 70.84

125 28.5174 4848.0 4705.9 71.25

126 28.2906 4900.2 4757.0 71,67

127 28.0588 4953.1 4008.6 72.09

128 27.8214 5006.6 4860.9 72.51

129 27.5781 5060,9 4914.0 72,93

130 27.3283 5116.1 4967.8 73.35

131 27.0712 5172.3 5022.6 73.79

132 26.8062 5229.7 5078.5 74.22

133 26.5323 5288.3 5135.5 74.66

134 26.2486 5348.4 5194.0 75.11

135 25,9537 5410.1 5254,0 75.57

136 25.6462 5473.4 5315.3 76.04

137 25.3241 5538.5 5378.4 76.52

138 24,9850 5605.8 5443.6 77.01

139 24.6260 5675.7 5511.1 77.51

140 24.2429 5748.8 5581.6 78.04

141 23.8302 5825.7 5655.6 78.58

142 23.3802 5907.5 5734.2 79.16

143 22.8810 5996.1 5818.9 79.78

144 22*3133 6093.9 5912*3 80.47

145 21*6419 6205.9 6018*7 81.24

145.995 20.7934 6342.1 6147.1 82.18

145.995 6.66045 8779.4 8170.9 98.88

146 6.65771 8780.3 8171.5 98,88

147 6.20612 8927.8 8274.8 99.89

148 5.88603 9042.0 8353.4 100.66

149 5.63506 9138.2 8418.9 101.31

150 5.42759 9222.6 0475.9 101.88

151 5.25032 9298.8 8526.9 102.38

152 5.09535 9368.8 8573.4 102.84

153 4.95759 9433.9 8616*4 103.27

154 4.83356 9495.1 8656 •

5

103*67

155 4.72074 9553.6 8694.4 104.04

156 4.61727 9608.1 8730*3 104.40

157 4.52172 9660.8 8764.5 104.74

158 4.43296 9711.5 8797.2 105.06

159 4.35011 9760.4 8828.7 105.37

160 4.27243 9807.7 8859.0 105.66
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

176

179

180

181 162

183

184

185

186

187

188

189

1 9 0

191

192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

40.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

MOL/LITER J/MOL energy

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

4.19933 9853.5 8888.4 105.95 231 2.26854 11993.9 10207.2 117.17

4.13031 9898.1 8916*8 106.22 232 2*25597 12019.0 10222*4 117.28

4.06495 9941*5 8944*4 106.49 233 2*24357 12044.1 10237*6 117.38

4.00289 9983.9 8971.3 106.75 234 2.23133 12069.2 10252.7 117.49

3.94381 10025.3 8997.5 107.00 235 2.21925 12094.2 10267.8 117,60

3.88747 1C065.8 9023.2 107.25 236 2.20732 12119.1 10282.9 117.70

3.83362 10105.5 9048.2 107,48 237 2.19555 12144.0 10297.9 117.81

3.78205 10144.4 9072.7 107.72 238 2.18392 12168.8 10312.9 117.91

3.73260 10182.6 9096.6 107.94 239 2.17244 12193.5 10327.8 118.02

3.68510 10220.2 9120.4 108.17 240 2.16110 12218.2 10342.7 118.12

3.63941 10257.2 9143.5 108.38 241 2.14990 12242.9 10357.6 118.22

3*5^541 10293*6 9166*3 108*59 242 2*13883 12267*5 10372*5 118*32

3.55297 10329.5 9188.7 108*80 243 2*12790 12292*0 10387*3 118.42

3*5] 200 10364*9 9210*8 109*01 244 2*11710 12316*5 10402*1 118*53

3*47241 10399*8 9232*6 109*21 245 2*10642 12341*0 10416*8 118*63

3*43411 10434*3 9254*0 109*40 246 2*09587 12365*4 10431*5 118*72

3*39702 10468*3 9275*2 109*60 247 2*08545 12389*7 10446*2 118.82

3*36107 10502*0 9296*1 109*79 248 2*07514 12414.1 10460*9 118.92

3*32620 10535*3 9316*7 109*97 249 2*06495 12438*3 10475*5 119*02

3.29236 10568*2 9337*1 110*16 250 2*05488 12462*5 10490*1 119*12

3.26948 10600.8 9357.3 110.34 251 2.04492 12486.7 10504.7 119.21

3.22751 10633*0 9377.2 110*51 252 2.03507 12510.9 10519.2 119.31

3.19642 10665.0 9397.0 110.69 253 2.02533 12535.0 10533.8 119.40

3.16615 10696.7 9416.5 110*86 254 2.01570 12559.0 10548.3 119.50

3.13667 10728*0 9435*9 111*03 255 2*00617 12583.0 10562*7 119.59

3.10794 10759.2 9455.1 111*20 256 1.99675 12607.0 10577.2 119.69

3.07993 10790*0 9474*1 111*37 257 1 .98743 12631*0 10591.6 119.78

3.05260 10820*6 9492*9 111*53 258 1*97821 12654*9 10606*0 119.87

3.02592 10851.0 9511.6 111.69 259 1.96908 12678.7 10620.4 119.97

2.99987 10881.2 9530.1 111.85 260 1.96005 12702.6 10634,7 120.06

2.97442 10911.1 9548.5 112.01 261 1.95112 12726.4 10649.0 120.15

2.94955 10940.9 9566.7 112.16 262 1.94228 12750.1 10663.3 120.24

2.92522 10970.4 9584.8 112.31 263 1 .93353 12773.8 10677,6 120.33

2.90143 10999.7 9602.8 112.47 264 1,92487 12797.5 10691.9 120.42

2.87815 11028.9 9620.7 112.62 265 1.91629 12821.2 10706.1 120,51

2.85535 11057.9 9638.4 112.76 266 1.90781 12844.8 10720.3 120.60

2.83303 11086.7 9656.0 112.91 267 1.89941 12868.4 10734.5 120.69

2.81116 11115.3 9673.5 113.06 268 1.89109 12892.0 10748.7 120.78

2.78972 11143.8 9690,9 113.20 269 1.88285 12915.5 10762.9 120.86

2.76871 11172.1 9708.2 113.34 270 1.87470 12939.0 10777.0 120.95

2,74811 11200.3 9725.4 113.48 271 1.86662 12962.5 10791.1 121.04

2*72790 11228*3 9742.5 113*62 272 1.85863 12985*9 10805*2 121*12

2.70^07 11256.2 9759.5 113.76 273 1.85071 13009.3 10819.3 121.21

2.68861 11284.0 9776.4 113.90 274 1.84286 13032.7 10833.4 121.30

2.66951 11311.6 9793.3 114.03 275 1.83509 13056.1 10847.4 121*38

2.65074 11339*1 9810*0 114.16 276 1*82740 13079.4 10861*5 121*46

2*63232 11366*4 9826*7 114*30 277 1*81978 13102*7 10875*5 121*55

2.61421 11393.7 9843.3 114.43 278 1.81222 13126.0 10889.5 121.63

2.5Q642 11420.8 9859.8 114.56 279 1.80474 13149.2 10903.4 121.72

2.57893 11447.8 9876.2 114.69 280 1.79733 13172.5 10917.4 121.80

2.56173 11474.7 9892.6 114.81 281 1.78998 13195.7 10931.3 121.88

2.54482 11501.5 9908.8 114.94 282 1.78270 13218.8 10945.3 121.96

2.52819 11528.2 9925.1 115.07 283 1.77549 13242.0 10959,2 122.05

2.51182 11554.8 9941.2 115.19 284 1 .76834 13265.1 10973,1 122.13

2.40572 11581,3 9957.3 115.32 285 1.76126 13288.2 10987.0 122.21

2.47988 11607.7 9973.3 115.44 286 1.75424 13311.3 11000.8 122.29

2.46428 11634.0 9989.3 115.56 287 1 .74728 13334.4 11014.7 122.37

2.44892 11660.3 10005.2 115.68 288 1.74038 13357.4 11028.5 122.45

2.43379 11686.4 10021.0 115.80 289 1.73354 13380.4 11042.4 122,53

2.41890 11712.4 10036.8 115.92 290 1.72677 13403.4 11056.2 122.61

2.40422 11738.4 10052.6 116.04 291 1.72005 13426.4 11070.0 122.69

2.38977 11764.3 10068.3 116.15 292 1 .71338 13449.3 11083.7 122.77

2.37552 11790.1 10063.9 116.27 293 1.70678 13472.2 11097.5 122.85

2.36148 11815.8 10099.5 116.38 29A 1.70023 13495.1 11111.3 122.92

2.34764 11841.5 10115.0 116.50 295 1.69374 13518.0 11125.0 123.00

2.33399 11867.0 10130.5 116.61 296 1.68730 13540.9 11138.8 123.08

2.32054 11892,5 10145.9 116.72 297 1.68091 13563.7 11152.5 123.16

2.30727 11918.0 10161.3 116.84 298 1.67458 13586.5 11166.2 123.23

2.29418 11943.3 10176.6 116.95 299 1.66830 13609.3 11179.9 123,31

2.28127 11968.6 10191.9 117.06 300 1.66208 13632.1 11193.6 123.39

94
45.00 ATMOSPHERE ISOBAR

temp. density enthalpy internal entropy

K MOL/LITER j/mol energy j/mol-k

J/MOL

86 35.4122 2995.6 2866.9 53.41

87 35.2675 3040.4 2911.1 53.93

88 35.1213 3085.4 2955.6 54.44

89 34.9736 3130.6 3000.2 54.95

90 34.8244 3175.9 3045.0 55.46

TEMP. DENSITY ENTHALPY internal ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/mOI -K

91 34.6740 3221.5 3090.0 55.96

92 34.5222 3267.2 3135.1 56.46

03 34.8691 3313.0 3180.4 56.96

94 34.2147 3359.1 3225.8 57,45

95 34.0501 3405.2 3271.4 57.94

96 33.9022 3*51.6 3317.1 58.42

97 33.7440 3498.0 3362.9 58.90

98 33.5845 3544.6 3408.8 59.38

99 33.4238 3591 .3 3454.9 59.86

100 33.2618 3638.1 3501.0 60.33

101 33.0985 3685.0 3547.3 60.79

102 32.9338 3732. 1 3593.6 61.26

103 32.7678 3779.2 3640*0 61.72

104 32*6003 3826.4 3686*5 62*17

105 32.4314 3873.7 3733*1 62.63

106 32.2610 3921.1 3779.8 63.07

107 32.0891 3968.6 3826.5 63.52

108 31.9156 4016.2 3873.4 63.96

109 31.7403 4063.9 3920.3 64.40

110 31.5634 4111.7 3967.2 64.84

111 31.3846 4159.6 4014.3 65.27

112 31.2040 4207.6 4061.4 65.70

113 31.0213 4255.7 4108.7 66.13

114 30.8366 4303.9 4156.1 66.56

115 30.6497 4352.3 4203.5 66.98

116 30.4605 4400.8 4251.2 67.40

117 30.2688 4449.6 4298.9 67.82

118 30.0746 4498.5 4346 f 8 68.23

119 29.8777 4547 .

6

4395.0 68.65

120 29.6779 4596,9 4443.3 69.06

121 29.4751 4646 .

6

4491.9 69.47

122 29.2690 4696.5 4540.7 69.88

123 29.0594 4746,8 4589.9 70.29

124 28.8461 4797.4 4639.4 70.70

125 28.6289 4848.5 4689.3 71*11

126 28.4074 4900.1 4739.6 71 .53 127 28.1813 4952.3 4790.5 71.94

128 27.9502 5005.0 4841.9 72.35

129 27.7138 5058.5 4894.0 72.77

130 27.4715 5112.8 4946.8 73.19

131 27.2229 5167.9 5000.4 73.61

132 26.9672 5224.1 5055.0 74.04

133 26.7039 5281.4 5110.6 74.47

134 26.4320 5340.0 5167.5 74.91

135 26.1506 5400.

0

5225.6 75.35

136 25.8586 5461.2 52b4 .

9

75.81

137 25.5545 5524.0 5345.6 76.27

138 25.2366 5588.7 5408.0 76.74

139 24.9028 5655.3 5472.2 77.22

140 24.5505 5724.4 5538.7 77.71

141 24.1760 5796.3 5607.7 78.22

142 23.7749 5871.8 5680.0 78.76

143 23.3407 5951.7 5756.4 79.32

144 22.8642 6037.5 5838.1 79.92

145 22.3312 6131.1 5927.0 80.57

146 21.7184 6235.8 6025.9 81.29

147 20.9816 6357.7 6140.4 82.12

148 20.0171 6511.3 6283.5 83.17

148.997 18.4189 6753.4 6505.8 84.80

148.997 8.8?476 8364.5 7847.8 o5.6i

149 8.81932 8365.8 7848.8 95.62

150 7.65533 8664.5 8068.8 97.62

151 7.08152 8833.6 8189.7 98.74

152 6*68477 8961*7 8279.6 99.59

153 6.37862 9068.0 8353.2 100.29

154 6.12843 9160.6 8416.6 100.89

155 5.91653 9243.5 8472.8 101.43

156 5.73262 9319.1 8523.7 101*91

157 5.57010 9389.1 8570.5 102.36

158 5.42449 9454.6 8614.0 102.78

159 5.29261 9516.4 8654.8 103.17

160 5.17212 9575.0 8693.4 103.53

PHASE CHANGE 95
45.00 4TMOSPHERE ISOBAR

TEMP. density ENTHALPY internal entropy temp. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 5.06121 9630.9 8730.0 103.88 231 2.57545 11929.3 10158.8 115.98

162 4.95849 9684.5 8764.9 104.21 232 2.56073 11955.1 10174.5 116.09

163 4.86285 9736.1 8798.4 104.53 233 2.54622 11980.8 10190.1 116.20

164 4.77341 9785.9 8830.7 104.84 234 2.53190 12006.5 10205.6 116.31

165 4.68942 9834.1 8861.7 105.13 235 2.51778 12032.1 10221.1 116.42

166 4.61027 9880.9 8891.8 105.41 236 2.50385 12057.6 10236.6 116.53

167 4 .53^45 9926.3 8921.0 105.68 237 2.49010 12083.1 10252.0 116.64

168 4.46453 9970.6 8949.3 105.95 238 2.47654 12108.5 10267.3 116.74

169 4.39713 10013.9 8976.9 106.20 239 2.46315 12133.8 10282.6 116.85

170 4.33294 1 0056.1 9003.8 106.45 240 2.44993 12159.1 10297.9 116.96

171 4.27166 10097.5 9030.0 106.70 241 2.43688 12184.3 10313.2 117.06

172 4.21307 10138.0 9055*7 106*93 242 2.42400 12209.5 10328*4 117.16

173 4.15694 10177*7 9080«8 107*16 243 2*41128 12234.5 10343*5 117.27

174 4.10309 10216*8 9105*5 107*39 244 2*39871 12259.6 10358*7 117.37

175 4.05134 10255*2 9129*7 107.61 245 2*38630 12284*5 10373*8 117.47

176 4*00155 10292*9 9153*4 107*82 246 2*37405 12309.5 10388*8 117.57

177 3*95358 10330*1 9176.7 108.03 247 2*36194 12334.3 10403*8 117.68

178 3.90730 10366*7 9199.7 108.24 248 2.34997 12359.1 10418*8 117.78

179 3.86262 10402*8 9222*3 108.44 249 2.33815 12383.9 10433*8 117.88

180 3.81943 10438.4 9244.6 108*64 250 2*32647 12408*6 10448*7 117*97

181 3.77764 10473.6 9266.5 108.84 251 2.31493 12433.3 10463.6 118.07

182 3.73716 1C508.3 9288.2 109.03 252 2.30351 12457.9 10478.4 118.17

183 3.69792 10542*6 9309.6 109.22 253 2.29223 12482*4 10493.2 118.27

184 3.65986 10576.6 9330.7 109.40 254 2.281 08 12507*0 10508.0 118.36

185 3.62291 10610.1 9351.5 109.58 255 2.27006 12531.4 10522.8 118.46

186 3.58701 10643.3 9372.2 109.76 256 2.25916 12555.8 10537.5 118.56

187 3.55211 10676,2 9392.5 109.94 257 2.24838 12580.2 10552.2 118,65

188 3.51815 10708.8 9412.7 110.11 258 2.23772 12604.6 10566.9 118,75

189 3.48509 10741.0 9432.7 110.28 259 2.22718 12628.8 10581.5 118.84

190 3.45289 10773*0 9452*4 110.45 260 2-21675 12653.1 10596*1 118*93

191 3.42151 10804.7 9472.0 110.62 261 2.20643 12677.3 10610.7 119.03

19? 3.39090 10836.1 9491.4 110.78 262 2.19623 12701.5 10625.3 119.12

193 3.36105 10867.3 9510.6 110*94 263 2.18613 12725.6 10639.8 119.21

194 3.33190 10898.2 9529*7 111*10 264 2.17614 12749.7 10654.4 119.30

195 3.30344 10928.9 9548*6 111*26 265 2.16626 12773.7 10668*8 119.39

196 3.27563 10959.3 9567*3 111*42 266 2*15648 12797*8 10683.3 119.48

197 3*24845 10989*6 9565*9 111*57 267 2*14680 12821*7 10697*8 119*57

198 3*22186 11019*6 9604*4 111*72 268 2*13721 12845*7 10712*2 119*66

199 3.19586 11049.5 9622.7 111.87 269 2.12773 12869.6 10726.6 119.75

200 3.17041 11079.1 9640.9 112.02 270 2.11834 12893.4 10740.9 119.84

201 3.14550 11108.6 9659.0 112.17 271 2.10905 12917.3 10755.3 119.93

202 3.12110 11137.8 9676.9 112.31 272 2.09985 12941.1 10769.6 120.02

203 3.09720 11166.9 9694.7 112.46 273 2*09074 12964.9 10783*9 120.10

204 3.07377 11195.9 9712*4 112*60 274 2.08172 12988*6 10798*2 120.19

205 3.05080 11224.7 9730.0 112.74 275 2.07279 13012.3 10812.5 120.28

206 3.02828 11253.3 9747.5 112.88 276 2.06395 13036.0 10826.7 120.36

207 3*00619 11281.7 9764.9 113*02 277 2*05519 13059*6 10841*0 120.45

208 2.98451 11310.0 9782*2 113.15 278 2*04652 13083.2 10855*2 120.53

209 2.96324 11338.2 9799.4 113.29 279 2.03793 13106.8 10869.4 120.62

210 2.94235 11366.3 9816.6 113.42 280 2.02942 13130.3 10883.5 120.70

211 2.92184 11394.2 9833.6 113.56 281 2.02099 13153.9 10897.7 120.79

212 2.90169 11421.9 9850.5 113.69 282 2.01264 13177.4 10911.8 120.87

213 2.88189 11449.6 9867.4 113.82 283 2.00436 13200.8 10925.9 120.95

214 2.86244 11477*1 9884.

1

113*95 284 1*99617 13224.3 10940*0 121*04

215 2.84331 11504.5 9900*8 114.07 285 1.98804 13247.7 10954.1 121.12

216 2.82451 11531.8 9917.5 114.20 286 1.98000 13271.6 10968.1 121.20

217 2.80602 11559.0 9934.0 114.33 287 1.97202 13294.4 10982.2 121.28

218 2.78783 11586,1 9950.5 114.45 288 1.96412 13317.7 10996.2 121.36

219 2.76994 11613.0 9966.9 114,57 289 1,95629 13341.0 11010.2 121,44

220 2.75233 11639.9 9983.2 114.70 290 1 .94853 13364.3 11024.2 121.52

221 2.73500 11666.6 9999.5 114.82 291 1.94083 13387.6 11038.2 121.60

222 2.71794 11693.3 10015.7 114.94 292 1.93321 13410.8 11052.2 121.68

223 2.70115 11719,9 10031.8 115.06 293 1 .92565 13434.0 11066.1 121,76

224 2.68461 11746.4 10047.9 115.18 294 1.91816 13457.2 11080.0 121.84

225 2.66832 11772.7 10063.9 115.29 295 1.91073 13480.3 11094.0 121.92

226 2,65227 11799.0 10079.9 115.41 296 1.90337 13503.5 11107.9 122.00

227 2.63646 11825.3 10095.8 115.53 297 1.89607 13526.6 11121.8 122.08

228 2.62087 11851 ,4 10111.6 115.64 298 1.88883 13549.7 11135.6 122.15

229 2.60552 11877.4 10127.4 115.75 299 1.88165 13572.8 11149.5 122.23

230 2.59038 11903.4 10143.1 115.87 300 1.87453 13595.8 11163.3 122.31

96
50.00 ATMOSPHERF isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITEH J/MOL ENEPGY J/MOL-K

J/MOL

85.042 35.5839 2962*3 2820*0 52.85

86 35.4474 3004.9 2862*0 53.35

87 35.3034 3049.6 2906.1 53.87

88 35.1579 3094.5 2950.4 54.38

89 35.0109 3139.6 2994.9 54.89

90 34.6626 3184.9 3039.5 55.40

phase CHANGE

TEMP. DENSITY ENTHA-LPY internal ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91 34.7129 3230.3 3084.3 55.90

92 34.5620 3275.9 3129.3 56.40

93 34.4098 3321.7 3174.4 56.89

94 34.2563 3367.6 3219.7 57.38

95 34.1017 3413.7 3265*1 57.87

96 33*9457 3459*9 3310*6 58*35

97 33*7886 3506.2 3356.3 58*83

98 33.6302 3552*7 3402*0 59*31

99 33*4707 3599*2 3447*9 59*78

100 33*3098 3645*9 3493 .

8

60.25

101 33.1477 3692.7 3539.9 60.72

102 32.9843 3739.6 3586.0 61*18

103 32*8196 3786.6 3632*2 61*64

104 32.6535 3833.6 3678.5 62.09

105 32.4861 3880.8 3724.8 6? ,54

106 32.3172 3928.0 3771.3 62.99

107 32.1469 3975.4 3817.8 63.44

108 31.9750 4022.8 3864.3 63.88

109 31.8015 4070.3 3911.0 64.31

110 31.6264 4117.9 3957.7 64.75

111 31 .4496 4165.5 4004.4 65,18

112 31.2710 4213.3 4051.3 65.61

113 31.0904 4261.2 4098.2 66.03

114 30*9080 4309.2 4145.2 66.46

115 30*7234 4357.3 4192.4 66 * 88

116 30.5367 4405.5 4239.6 67.30

117 30.3478 4453,9 4287.0 67.71

118 30.1564 4502.5 4334.5 68.12

119 29.9625 4551.3 4382*2 68.54

120 29*7659 4600*2 4430*0 68.95

121 29.5664 4649.5 4478*1 69.35

122 29.3640 4699,0 4526.4 69.76

123 29.1583 4748.8 4575.0 70.17

124 28.9492 4798.9 4623.9 70.57

125 28.7365 4849.5 4673.2 70.98

126 28.5199 4900.5 4722*9 71.39

127 28.2990 4952.0 4773*0 71.79

128 28.0737 5004.1 4823.6 72.20

129 27.8436 5056.8 4874.8 72.61

130 27.6081 5110.2 4926.7 73.02

131 27.3670 5164.4 4979.3 73.44

132 27.1197 5219.5 5032.7 73.86

133 26.8656 5275*6 5087.1 74.28

134 26*6041 5332*9 5142.5 74.71

135 26.3343 5391.5 5199.1 75.15

136 26.0555 5451.0 5256,6 75.59

137 25.7664 5511.9 5315.3 76.03

138 25,4659 5574,3 5375.3 76.49

139 25.1524 5638.3 5436.9 76.95

140 24.8240 5704,3 5500.2 77.42

141 24.4784 5772.4 5565.4 77.91

142 24.1126 5843,3 5633.1 78.41

143 23.7226 5917.4 5703.8 78.93

144 23.3034 5995.6 5778.2 79. 4S

145 22.8477 6078.9 5857.2 80.05

146 22.3450 6168.9 5942.1 80.67

147 21.7793 6267.7 6035.1 81.35

148 21.1238 6379.2 6139.3 82.11

149 20.3278 6510.4 6261.1 82,99

150 19.2741 6678.1 6415.3 84.12

151 17.5415 6944.2 6655.4 85.89

152 11.2264 7980.6 7529.3 92.72

153 9.13533 8431,9 7877.3 95.68

154 8.27788 8651.4 8039.4 97,12

155 7.72594 8808.1 8152.4 98.13

156 7.31726 8933*9 8241.5 98.94

157 6.99241 9040*9 8316.4 99.62

158 6.72280 9135.2 8381.6 100.22

159 6.49240 9220.1 8439.8 100.76

160 6,29132 9297.9 8492.6 101,24
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

50.00 atmosphere ISOBAR

DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

MOL/LITEH J/MOL energy

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

6.11301 9370.1 8541.4 101.69 231 2.88768 11864.3 10109.8 114.89

5.95289 9437*8 8586.7 102*11 232 2*87066 11890.8 10125.9 115.01

5 « 80765 9501*6 8629*2 102*51 233 2*85389 11917*2 10142*0 115*12

5.67482 9562.2 8669.4 102.88 234 2.83736 11943.5 10157.9 115.24

5.55248 9620.0 8707.5 103.23 235 2.82106 11969.8 10173,8 115.35

5.43914 9675.4 8743.9 103.56 236 2.80499 11995.9 10189.7 115,46

5.33360 9728.7 8778.8 103.88 237 2.78915 12022.0 10205.5 115.57

5.23408 9780.1 8812.3 104.19 238 2.77352 12048.0 10221.3 115.68

5*14219 9829.8 8844 • 6 104*49 239 2*75810 12073.9 10237.0 115.79

5.05486 9878*1 8875*8 104*77 240 2.74289 12099*8 10252.7 115.89

4.97232 9925.0 8906.1 105.05 241 2.72789 12125.5 10268.3 116.00

4.89409 9970.7 8935.5 105.31 242 2.71308 12151.2 10283.9 116.11

4.81977 10015.2 8964*1 105.57 243 2.69846 12176.9 10299.4 116.21

4.74899 10058.7 8991.9 105.82 244 2.68404 12202.5 10314.9 116.32

4,68146 10101.3 9019,1 106.06 245 2.66980 12228.0 10330.3 116,42

4.61690 10143.0 9045.6 106.30 246 2.65574 12253.4 10345.7 116.53

4.55507 10183.9 9071.6 106.53 247 2.64185 12278.8 10361.1 116.63

4.49576 10224.0 9097-1 106*76 248 2*62814 12304.1 10376.4 116.73

4.43879 10263*4 9122*1 106.98 249 2*61460 12329.4 10391.7 116.83

4.38396 10302.2 9146.6 107.20 250 2.60123 12354.6 10406.9 116. 94

4.33120 10340.4 9170.6 107.41 251 2.58802 12379.7 10422.1 117.04

4.28030 10377.9 9194.3 107.62 252 2.57496 12404.8 10437.3 117.14

4.23116 10415.0 9217.6 107.82 253 2,56206 12429.8 10452.4 117.23

4.18367 10451.5 9240.5 108.02 254 2.54932 12454.8 10467.5 117,33

4*13773 10487*5 9263 •

1

108.21 255 2*53672 12479*8 10482*5 117.43

4 • 09325 10523*1 9285*4 108*40 256 2*52427 12504*6 10497*6 117*53

4.05014 10558.3 9307.4 108.59 257 2.51197 12529.5 10512.6 117.62

4.00833 10593.0 9329.1 108.78 258 2.49980 12554.2 10527.5 117,72

3.96775 10627.4 9350.5 108.96 259 2.48778 12579.0 10542,4 117.82

3.92834 10661.3 9371.6 109.14 260 2.47589 12603.6 10557.3 117.91

3.89002 10695.0 9392.6 109.32 261 2.46413 12628.3 10572.2 118.01

3.85276 10728.3 9413.3 109.49 262 2.45250 12652.8 10587.0 118.10

3.81648 10761.2 9433.7 109.66 263 2.44100 12677.4 10601,8 118.19

3.78116 10793.9 9454.0 109.83 264 2.42963 12701.9 10616.6 118.29

3.74674 10826.3 9474.0 110.00 265 2.41837 12726.3 10631.4 118.38

3.71318 10858.3 9493.9 110.16 266 2.40724 12750.7 10646.1 118.47

3.68045 10890.2 9513.6 110.32 267 2.39623 12775.1 10660.8 118.56

3*64850 10921*7 9533*1 110*48 268 2*38534 12799*4 10675*4 118.65

3.61730 10953.0 9552*4 110*64 269 2.37456 12823*7 10690.1 118.74

3 • 5R683 10984-1 9571*6 110*80 270 2*36389 12847*9 10704.7 118.83

3.55704 11014.9 9590.6 110.95 271 2.35333 12872.1 10719.3 118.92

3.52793 11045.6 9609.5 111.10 272 2.34288 12896.3 10733.9 119.01

3.49944 11076.0 9628.2 111.25 273 2.33254 12920.4 10748.4 119.10

3.47158 11106*2 9646.8 111*40 274 2.32230 12944.5 10762*9 119.19

3.44430 11136.2 9665.2 111.55 275 2.31217 12968.6 10777.4 119.28

3.41758 11166.0 9683.6 111.69 276 2.30213 12992.6 10791 .9 119.36

3.39141 11195.6 9701.7 111.84 277 2.29220 13016.6 10806.3 119. 45

3.36577 11225.1 9719.8 111.98 278 2.28237 13040.5 10820.7 119.54

3.34064 11254.4 9737.8 112.12 279 2*27263 13064.4 10835*1 119.62

3.31599 11283.5 9755.6 112.26 280 2.26298 13088.3 10849.5 119.71

3.29182 11312.4 9773.4 112.39 281 2.25343 13112.2 10863.9 1 19.79

3.26811 11341.2 9791.0 112.53 282 2.24397 13136.0 10878.2 119.88

3.24464 11369.9 9808.5 112.67 283 2.23461 13159.8 10892.5 119.96

3.22199 11398.4 9826.0 112.80 284 2.22533 13183.5 10906.8 120.05

3.19956 11426.8 9843.3 112.93 285 2.21613 13207.2 10921.1 120.13

3.17752 11455.0 9860.5 113.06 286 2.20703 13230.9 10935.3 120.21

3.15586 11483.1 9877.7 113.19 287 2.19801 13254.6 10949.6 120.29

3.13461 11511.0 9894.8 113.32 288 2.18907 13278.2 10963.8 120.38

3.11370 11538.9 9911.8 113.45 289 2.18021 13301.8 10978.0 120.46

3.09315 11566.6 9928.7 113.57 290 2.17144 13325.4 10992.2 120.54

3.07294 11594.2 9945.5 113.70 291 2.16274 13348.9 11006.3 120.62

3.05306 11621.7 9962.2 113.82 292 2.15412 13372.4 11020.5 120.70

3.03351 11649.0 9978.9 113.95 293 2.14558 13395.9 11034.6 120.78

3.01427 11676*3 9995*5 114*07 294 2*13712 13419.4 11048.7 120*86

2.99533 11703.5 10012.0 114.19 295 2*12873 13442.8 11062.8 120.94

2.97669 11730-5 10028.5 114*31 296 2*12042 13466.2 11076.9 121.02

2.95834 11757.5 10044.9 114.43 297 2.11218 13489.6 11091.0 121.10

2.94028 11784.3 10061*2 114*55 298 2*10401 13513.0 11105*0 121*18

2*92248 11811.1 10077*5 114*66 299 2*09591 13536*3 11119.0 121*26

2.90495 11837.7 10093*7 114.78 300 2.08788 13559.6 11133.0 121*33

98
60.00 atmosphere isobar

TEMP. DENSITY ENTHALPY internal entropy

K mol/liter J/MOL energy

J/MOL

J/MOL-K

S5.29 2 35.6169 2992.3 2821.6 52*87

86 35.5169 3023.6 2852.5 53.24

87 35.3742 3068.1 2896.3 53.75

88 35.2301 3112.8 2940.3 54.26

89 35.0846 3)57.7 2984.4 54.77

90 34.9378 3202.8 3028.8 55.27

TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

j/mol-k

91 34.7898 3248.6 3073.3 55.77

92 34.6405 3293.4 3117.9 56.27

93 34.4900 3339.0 3162.7 56.76

94 34.3383 3384.7 3207.7 57.25

95 34.1855 3430.6 3252.7 57.74

96 34.0315 3476.6 3297.9 58.22

97 33*8763 3522*7 3343-2 58.69

98 33*7201 356B.9 3388.6 59-17

99 33*5626 3615*3 3434*1 59*64

100 33*4040 3661-7 3479*7 60.11

101 33.2443 3708.2 3525.3 60.57

102 33.0833 3754.8 3571.1 61.03

103 32*9212 3801*6 3616.9 61*48

104 32.7578 3048.3 3662.7 61.94

105 32.5931 3895.2 3708.7 62.38

106 32.4271 3942.1 3754.6 62.83

107 32.2598 3989.1 3800.7 63,27

108 32.0911 4036.2 3846.7 63.71

109 31.9209 4083.3 3892.8 64.14

110 31.7492 4130.5 3939.0 64.57

1 1

1

31.5760 4177.8 3985.2 65.00

112 31.4012 4225.1 4031.5 65.43

113 31.2247 4272 .

5

4077.9 65.85

114 31.0465 4320.0 4124.2 66.27

115 30.8664 4367,6 4170.7 66,68

116 30.6844 4415.4 4217.2 67.09

117 30,5003 4463.2 4263.9 67.51

118 30.3142 4511.2 4310.6 67,91

119 30.1258 4559.3 4357.5 68.32

120 29.9351 460^.6 4404.5 68.72

121 29.7419 4656 .

1

4451.7 69.13

122 29.5461 4704,8 4499.0 69,53

123 29.3475 4753.8 4546,6 69.93

124 29.1460 4803.0 4594.4 70.33

125 28.9414 4852.6 4642.5 70.72

126 28.7335 4902.5 4691.0 71.12

127 29.5221 4952*9 4739.7 71*52

128 28*3069 5003*7 4789.0 71*92

129 28.0877 5055*1 4838.6 72*32

130 27.8642 5107.0 4888.8 72.72

131 27,6360 5159.6 4939.6 73.12

132 27.4029 5213.0 4991.1 73.53

133 27.1645 5267.1 5043.3 73.94

134 26.9202 5322.2 5096.4 74.35

135 26.6695 5378.4 5150.4 74.77

136 26.4120 5435.2 5205.0 75.19

137 26,1468 5493.0 5260.5 75.61

138 25.8734 5551.9 5316.9 76.04

139 25.5907 5611.9 5374.4 76.47

140 25.2978 5673.3 5432.9 76.91

141 24.9934 5736.0 5492.8 77.36

142 24.6760 5800*5 5554.1 77.82

143 24.3439 5867.0 5617.2 78.28

144 23.9950 5935.9 5682.5 78.76

145 23.6264 6007.6 5750,2 79,26

146 23.2349 6082.6 5020.9 79,78

147 22.8159 6161.6 5895.1 80.32

14g 22.3636 6245.5 5973,6 80.89

149 21 .8699 6335,2 6057.2 81.50

150 21.3237 6432.6 6147.5 82.15

151 20.7081 6540.4 6246.8 82.87

152 19.9974 6662.5 6358.5 83.68

153 19.1499 6804.9 6487.4 04.61

154 18.0952 6978.7 6642.7 05.74

155 16.7257 7202.3 6838.8 87.19

156 14.9897 7491.1 7085.5 89.05

157 13.1911 7810.2 7349.3 91.08

158 11.7452 8092.7 7575.1 92.88

159 10.6917 8320.1 7751.5 94.31

160 9.91469 8503.4 7890*2 95.46

PHASE CHANGE 99
60.00 ATMOSPHERE ISOBAR

TEMP. density ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/L ITER J/MOL ENERGY

J/MOL

j/mol-k

161 9.31762 8655.7 8003.2 96.41 231 3.52793 11733.4 10010.1 112.96

162 8.84052 8785.9 8098.2 97.22 232 3.50585 11761.3 10027.1 113.08

163 8.44686 8900*2 8180*4 97*92 233 3.48411 11789.1 10044*1 113*20

164 8. ] 1372 9002*4 8253*1 98*55 234 3*46271 11816.

7

10061*0 113*31

165 7.82611 9095-2 8318.4 99.11 235 3*44165 11844.3 10077*8 113*43

166 7*57378 9180*6 8377.8 99.63 236 3.42090 11871*8 10094*5 113.55

167 7.34950 9259.9 8432.6 100*10 237 3*40047 11899*1 10111*2 113.66

168 7.14799 9334.1 8483.5 100.55 238 3.38034 11926.4 10127.8 113.78

169 6.96529 9404.1 8531.2 100.96 239 3.36050 11953.5 10144.4 113.89

170 6.79838 9470*4 8576*1 101*35 240 3.34096 11980.6 10160.8 114.01

171 6.64489 9533.6 8618.7 101.72 241 3.32170 12007.5 10177.2 114.12

172 6.50293 9594.0 8659.1 102.08 242 3.30271 12034.4 10193.6 114.23

173 6.37099 9652.1 8697.8 102.41 243 3.28399 12061.2 10209.9 114.34

174 6.24782 9707.9 8734*9 102*73 244 3*26553 12087.9 10226.1 114.45

175 6.13239 9761.9 8770.5 103.04 245 3.24733 12114.5 10242.3 114.56

176 6.02384 9814.1 8804.9 103.34 246 3.22937 12141,1 10258.4 1 1 * • 67

177 5.92144 9864.8 8838.1 103.63 247 3.21166 12167.5 10274.5 114.77

178 5.82458 9914.0 8870.3 103.91 248 3.19419 12193.9 10290.5 114.88

179 5.73271 9962.0 8901.5 104.17 249 3.17695 12220,2 10306,5 114.99

180 5.64538 10008.8 8931.8 104.43 250 3.15993 12246.4 10322.4 115.09

181 5.56219 10054.4 8961.4 104.69 251 3.14314 12272.5 10338.3 115.19

182 5.48279 10099.1 8990.2 104.93 252 3.12656 12298.6 10354.1 115.30

183 5.40687 10142.8 9018*4 105.17 253 3*11019 12324.6 10369.9 115.40

184 5*33416 10185*7 9045*9 105.41 254 3*09403 12350.6 10385*6 115.50

185 5*26441 10227*7 9072*8 105*63 255 3*07808 12376*4 10401*3 115*61

186 5*19740 10269*0 9099*2 105*86 256 3*06232 12402*2 10416*9 115*71

187 5.13295 10309*6 9125*1 106*07 257 3*04675 12428*6 10432*5 115*81

188 5*07088 10349*5 9150*5 106*29 258 3*03138 12453*6 10448*1 115*91

189 5.01104 10388.8 9175.5 106.50 259 3.01619 12479.3 10463.6 116,01

190 4.95327 10427.5 9200.1 106.70 260 3.00118 12504.8 10479.1 116.10

191 4.89745 10465.6 9224.2 106.90 261 2.98636 12530.3 10494.5 116.20

192 4.84347 10503.2 9248.0 107.10 262 2.97170 12555.7 10509.9 116.30

193 4.79121 10540*3 9271*4 107*29 263 2-95722 12581*1 10525.2 116.40

194 4.74057 10577.0 9294.5 107.48 264 2.94291 12606.4 10540.6 116.49

195 4,69147 10613.2 9317.3 107.66 265 2.92876 12631.7 10555.8 116.59

196 4.64383 10649.0 9339.8 107.85 266 2.91477 12656.9 10571.1 116.68

197 4.59755 10684,3 9362.0 108.03 267 2.90094 12682,1 10586.3 116.78

198 4.55259 10719.3 93b3 ,

9

108.21 268 2.88726 12707.2 10601.5 116.87

199 4.50886 10754.0 9405.6 108.38 269 2.87374 12732.2 10616.6 116.96

200 4.46631 10788.2 9427.0 108.55 270 2.86037 12757.2 10631.7 117.06

201 4,42488 10822.2 9448.2 108.72 271 2.84714 12782.2 10646.8 117.15

202 4.38452 10855.8 9469.2 108.89 272 2.83406 12807.1 10661.9 117.24

203 4.34517 10889.1 9489.9 109.05 273 2*82112 12831.9 10676.9 117.33

204 4.30681 10922.1 9510.4 109.21 274 2*80831 12856.7 10691.9 117.42

205 4.26937 10954.8 9530.8 109.37 275 2.79564 12881.5 10706.8 117.51

206 4.23282 10987.3 9551.0 109.53 276 2.78311 12906.2 10721.7 117.60

207 4.19713 11019-5 9570*9 109*69 277 2*77071 12930*9 10736*6 117*69

208 4*16225 11051*4 9590*7 109*84 278 2*75843 12955*5 10751*5 117*78

209 4*12816 11083*1 9610*4 109*99 279 2*74629 12980*1 10766*3 117*87

210 4.09482 11114.6 9629.9 110.14 280 2.73426 13004.7 10781.2 117.96

211 4.06220 11145.8 9649.2 110.29 281 2.72236 13029.2 10795.9 118.04

212 4.03028 11176.9 9668.4 110.44 282 2.71058 13053.6 10810.7 lie. 13 213 3.99903 11207*7 9687.4 110*58 283 2.69892 13078.1 10825.4 118.22

214 3.96842 11238*3 9706*3 110*73 284 2*68738 13102*4 10840*1 118.30

215 3.93844 11268.7 9725.0 110.87 285 2.67594 13126.8 10854.8 118.39

216 3.90905 11298.9 9743.7 111.01 286 2.66462 13151.1 10869.5 118.47

217 3.88024 11329.0 9762.2 111.15 287 2.65341 13175.4 10884.1 118.56

218 3.85199 11358.9 9780.5 111.29 288 2.64231 13199.6 10898.7 118.64

219 3.82*28 11388.6 9798.8 111.42 289 2*63132 13223.8 10913*3 118.73

220 3.79709 11418.1 9817-0 111*56 290 2*62043 13248.0 10927*9 118.81

221 3.77040 11447.5 9835.0 111.69 291 2.60965 13272.1 10942.4 118.89

222 3.74420 11476.7 9852.9 111.82 292 2.59896 13296.2 10956.9 118.98

223 3.71846 11505.8 9870.8 111.95 293 2.58838 13320.3 10971.4 119.06

224 3.69319 11534.7 9888.5 112*08 294 2*57790 13344.3 10985.9 119.14

225 3.66836 11563.5 9906.2 112.21 295 2.56751 13368.3 11000.4 119.22

226 3.64395 11592.1 9923.7 112.34 296 2.55722 13392.2 11014.8 119.30

227 3.61997 11620.6 9941.1 112.46 297 2.54702 13416.2 11029.2 119.38

228 3.59638 11649.0 9958.5 112.59 298 2.53692 13440.1 11043.6 119.46

229 3.57319 11677.3 9975.8 112.71 299 2.52690 13463.9 11058.0 119.54

230 3.55038 11705.4 9993.0 112.83 300 2*51698 13487.8 11072.3 119.62

100
70.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liteR j/mol ENERGY J/MOL-K

J/MOL

85.542 35.6494 3022.1 2823.2 52.89

86 35.5851 3042.4 2843.1 53.12

87 35.4438 3086.7 2886*6 53.64

88 35.3010 3131*2 2930*3 54.14

89 35.1570 3175*9 2974.2 54*65

90 35.0117 3220*8 3018*2 55*15

PHASE CHANGE

TEMP. density ENTHALPY INTERNAL entropy

K mol/liter J/MOL ENERGY

J/MOL

J/mOL-K

91 34,8651 3265.9 3062.5 55.65

92 34.7174 3311.1 3106.8 56.14

93 34.5686 3356.5 3151.3 56.63

94 34.4186 3402.0 3195.9 57.12

95 34.2675 3447.7 3240.7 57.60

96 34.1154 3493.4 3285.5 58.08

97 33.9621 3539.3 3330.5 58.56

98 33.8078 3585.4 3375.6 59.03

99 33.6525 3631.5 3420.7 59.50

100 33*4960 3677.7 3465.9 59.96

101 33.3385 3724.6 3511.2 60.42

102 33.1798 3770*3 3556*6 60.88

103 33*0201 3816*8 3602*0 61*33

104 32*8592 3863*3 3647*4 61*78

105 32*6971 3909*9 3692*9 62*23

106 32*5338 3956.5 3738-5 62*67

107 32.3693 4003.2 3784.0 63.11

108 32.2036 4049.9 3829.7 63.54

1 Op 32.0365 4096.7 3875.3 63.97

no 31.8681 4143.5 3921.0 64.40

in 31.6982 4190.4 3966.7 64.83

112 31.5269 4237.4 4012.4 65.25

113 31*3541 4284.4 4058.2 65.67

114 31.1798 4331.5 4104.0 66.08

115 31*0038 4378.6 4149.8 66.49

116 30.8260 4425.8 4195.7 66.90

117 30.6465 4473.2 4241.7 67.31

118 30.4651 4520.6 4287.8 67.71

119 30.2817 4568.1 4333.9 68.11

120 30.0963 4615.8 4380.1 68.51

121 29.9087 4663.6 4426.5 68.91

122 29.7188 4711.7 4473.0 69.30

123 29.5265 4759.9 4519.7 69.70

124 29*3317 4808.4 4566.5 70.09

125 29.1342 4857.1 4613.6 70.48

126 28.9339 4906.1 4661.0 70.87

127 28.7306 4955.5 4708.6 71.26

128 28.5241 5005.2 4756.6 71.65

129 28.3142 5055.4 4804.9 72.04

130 28.1007 5106.1 4853.7 72.43

131 27.8835 5157.4 4903.0 72.83

132 27.6621 5209.3 4952.9 73.22

133 27.4364 5261.8 5003.3 73.62

134 27.2059 5315.2 5054.5 74.02

135 26.9705 5369.4 5106.4 74.42

136 26.7296 5424.1 5158.8 7A.82

137 26.4828 5479.6 5211.7 75.23

138 26.2297 5535.8 5265.4 75.64

139 25.9696 5593.6 5319.8 76.05

140 25.7021 5651.0 5375.0 76.47

141 25.4262 5710.0 5431.0 76.89

142 25.1412 5770.2 5488.1 77.32

143 24.8462 5831.8 5546.3 77.75

144 24.5400 5895.0 5605.9 78.19

145 24.2214 5960.6 5667.2 78.64

146 23.8886 6027.1 5730.2 79.10

147 23.5400 6096.6 5795.3 79.58

148 23.1733 6168.8 5862.8 80*07

149 22.7856 6244.1 5932.8 80.58

150 22,3738 6322.9 6005.9 81.11

151 21 .9334 6406.3 6082.9 81.67

152 21 .4593 6495.2 6164.7 82.25

153 20*9446 6590*2 6251.5 82.88

154 20.3808 6692.6 6344.5 83.54

155 19.7570 6804.1 6445.1 84.27

156 19.0601 6927.1 6554.9 85.06

157 18.2761 7064.0 6675.9 85.93

158 17*3953 7217.2 6809.5 86.90

159 16*4234 7387.4 6955*5 87.98

160 15*3952 7571.6 7110*3 89.13
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

1 97

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

70.00 atmosphere ISOBAR

DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

MOL/LI TEH J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

14.3725 7760.2 7266.6 90.31 231 4.18861 11601.6 9908.2 111.24

13.4174 7945.3 7416.7 91.45 232 4.16082 11631.0 9926.3 111.37

12.5661 8119.7 7555.2 92.53 233 4.13351 11660.2 9944.2 111.50

11.8273 8280.0 7680.3 93.51 234 4.10665 11689.3 9962.1 111.62

11.1926 8425.8 7792.1 94.39 235 4.08025 11718.2 9979.9 111.75

10.6475 8558.2 7892.1 95.19 236 4.05428 11747.1 9997.6 111.87

10.1767 8678.8 7981.8 95.92 237 4.02873 11775.7 10015.2 111. 99

9.76684 8769.2 8062.9 96.58 238 4.00359 11804.3 10032.7 112.11

9.40667 8890.8 8136.8 97.18 239 3.97885 11832.7 10050.1 112.23

9.08737 8985.1 8204.6 97.74 240 3.95450 11861.1 10067.4 112.35

8.eol89 9073.0 8267.2 98.25 241 3.93053 11889.3 10084.7 112.46

8 . 54466 9155.5 8325.4 98.73 242 3.90692 11917.4 10101.9 112.58

8.31125 9233.3 8379.9 99.18 243 3.88367 11945.4 10119.0 112.70

8*09809 9307*0 8431*1 99*61 244 3*86077 11973*2 10136.0 112*81

7.90233 9377.1 8479.5 100.01 245 3.83820 12001.0 10153.0 112.92

7.72161 9444.1 8525.5 100.39 246 3.81597 12028.7 10169.9 113.04

7.55401 9508.2 8569*2 100*76 247 3.79406 12056.2 10186*7 113*15

7.39794 9569.8 8611.0 101.10 248 3.77246 12083.7 10203*5 113.26

7.25204 9629.1 8651*1 101.44 249 3.75117 12111*1 10220.2 113.37

7.11519 9686.5 8689.6 101*75 250 3.73018 12138*3 10236*8 113.48

6.98643 9741.9 8726.7 102.06 251 3.70947 12165.5 10253.4 113.59

6.86494 9795.7 8762.5 102.36 252 3.68906 12192.6 10269.9 113.69

6.75002 9848.0 8797.2 102.65 253 3.66892 12219.6 10286.4 113.80

6 . 64 104 9898.9 8830.8 102.92 254 3.64905 12246,5 10302,8 113.91

6.53747 9948,4 8863.5 103.19 255 3.62944 12273.4 10319.1 114.01

6,43885 9996.8 8895.2 103.45 256 3.61010 12300.1 10335.4 114.12

6.34477 10044.1 8926.2 103.71 257 3.59100 12326.8 10351.6 114.22

6.25486 10090-3 8956*3 103*95 258 3*57216 12353*4 10367*8 114.33

6.16879 10135.6 8985*8 104.19 259 3*55355 12379*9 10383.9 114.43

6.08628 10180.0 9014.6 104.43 260 3.53518 12406.4 10400.0 114.53

6.00707 10223.5 9042.8 104.65 261 3.51705 12432.8 10416.0 114.63

5.93093 10266.3 9070.4 104.88 262 3,49913 12459.1 10432.0 114.73

5.85764 10308.3 9097.5 105,10 263 3,48145 12485.3 10447.9 114.83

5.78703 10349.7 9124.0 105.31 264 3,46397 12511.5 10463.8 114.93

5.71892 10390.4 9150.1 105.52 265 3.44671 12537.6 10479.7 115,03

5.65314 10430.5 9175.8 105.72 266 3.42966 12563.6 10495.5 115.13

5.58957 10470.0 9201.0 105.93 267 3.41281 12589.5 10511.2 115.23

5.52807 10508.9 9225.8 106.12 268 3.39616 12615.4 10526.9 115.32

5.46852 10547.3 9250.3 106.32 269 3.37970 12641.3 10542.6 115.42

5.41081 10585.2 9274.4 106.51 270 3.36344 12667.1 10558.2 115.51

5.35485 10622.7 9298.1 106.69 271 3.34736 12692.8 10573.8 115.61

5.30053 10659.7 9321*5 106*88 272 3.33147 12718.4 10589.4 115.70

5.24778 10696*3 9344-7 107.06 273 3*31576 12744*0 10604.9 115.80

5*19650 10732*4 9367*5 107*24 274 3*30022 12769.6 10620*3 115*89

5 . 14 664 10768.2 9390*1 107.41 275 3.28486 12795.1 10635.8 115.98

5.09812 10803.6 9412*3 107.58 276 3.26966 12820.5 10651.2 1 16.08

5.05088 10838.7 9434.4 107.75 277 3.25464 12845.9 10666.5 116.17

5.00485 10873.4 9456.2 107.92 278 3.23978 12871.2 10681.9 116.26

4.95999 10907.8 9477.7 108.08 279 3.22508 12896.5 10697.2 116.35

4.91624 109*1.8 9499.1 108.25 280 3.21053 12921.7 10712.4 116.44

4.87355 10975.6 9520.2 108.41 281 3.19614 12946.9 10727.7 116.53

4.83188 11009.0 9541.1 108.57 282 3.18191 12972-6 10742.9 116.62

4.79118 11042.2 9561.8 108.72 283 3*16782 12997*1 10758*0 116.71

4.75141 11075*2 9582.4 108.88 284 3.15388 13022.1 10773*2 116.80

4.71255 11107.8 9602*7 109*03 285 3*14009 13047-1 10788*3 116*88

4.67454 11140.2 9622*9 109*18 286 3*12643 13072-0 10803.3 116.97

4.63736 11172.4 9642.9 109.33 287 3.11292 13096.9 10818.4 117.06

4.60097 11204.3 9662*7 109.47 288 3*09954 13121*8 10833.4 117*14

4.56535 11236.1 9682.4 109.62 289 3.08629 13146.6 10848.4 117.23

4.53046 11267.6 9701.9 109.76 290 3.07318 13171.3 10863.3 117.32

4.49629 11298.8 9721.3 109.90 291 3.06020 13196.1 10878.3 117.40

4.46280 11329.9 9740*6 110.04 292 3.04735 13220*7 10893.2 117.49

4.42^97 11360*8 9759.7 110.18 293 3.03462 13245.4 10908.0 117.57

4.39778 11391.5 9778.7 110*32 294 3.02201 13270.0 10922.9 117.65

4.36621 11422*0 9797*5 110.46 295 3.00953 13294.5 10937.7 117.74

4.33523 11452*4 9816.3 110*59 296 2*99717 13319*0 10952*5 117.82

4.30483 11482.5 9834.9 110.72 297 2.98492 13343.5 10967.3 117.90

4.27498 11512.5 9853.4 110.86 298 2.97279 13368.0 10982.0 117.98

4.2456/ 1 1542.4 9871.8 110.99 299 2*96078 13392.4 10996.7 118.07

4.21689 11572.1 9890.0 111.12 300 2.94887 13416.8 11011.4 118.15

102
80.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY internal ENTROPY

K mol/liter J/M0L ENERGY

J/MOL

J/MOL-K

85.79j 35.6815 3052.0 2824.8 52. 9o

86 35.6523 3061.2 2833.9 53.01

87 35.5122 3105.4 2877.1 53.52

88 35.3708 3149.7 2920.5 54.03

89 35.2281 3194.3 2964 « 1 54.53

90 35.0842 3239.0 3007.9 55.03

TEMP. DENSITY ENTHALPY internal ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91 34.9391 3283.8 3051,8 55.53

92 34*7929 3328.9 3095*9 56*02

93 34*6456 3374.1 3140«1 56*51

94 34*4973 3419*4 3 1 8 A • 4 56.99

95 340479 3464.9 3228*9 57.47

96 34.1975 3510.5 3273*4 57.95

97 34-0461 3556*2 3318*1 58.42

98 33.8937 3602.0 3362.8 58.89

99 33.7403 3647.9 3407.6 59.36

100 33.5858 3693.8 3452.5 59.82

101 33.4304 3739.9 3497.4 60.28

102 33.2740 3786.0 3542.4 60.74

103 33.1165 3832.2 3587.4 61.19

104 32.9579 3878.5 3632.5 61.63

105 32.7983 3924,8 3677.6 62.08

106 32.6376 3971,1 3722.8 62.52

107 32.4758 4017.5 3767.9 62.95

108 32.3128 4064.0 3813.1 63.38

109 32.1486 4110.4 3858.3 63.81

110 31.9832 4157*0 3903.5 64.24

111 31.8165 4203.5 3948.7 64.66

112 31.6485 4250.1 3994.0 65.08

113 31.4791 4296.7 4039.2 65.49

114 31*3083 4343*4 4084*5 65*90

115 31*1360 4390*1 4129*8 66.31

116 30*9623 4436*9 4175*1 66*71

117 30*7869 4483.7 4220.4 67.12

118 30*6098 4530.7 4265.8 67.52

119 30.4310 4577.7 4311.3 67.91

120 30.2503 4624.0 4356.8 68.31

121 30.0678 4672.1 4402.5 68.70

122 29.8832 4719.5 4448.2 69.09

123 29.6966 4767.0 4494.1 69.48

124 29.5077 4814.8 4540.1 69.86

125 29.3165 4862.7 4586.2 70.25

126 29.1229 4911.6 4632*6 70.63

127 28.9267 4959.5 4679.3 71*02

128 28.7277 5008.3 4726.2 71*40

129 28*5259 5057.5 4773.4 71*78

130 28.3211 5107.2 4821.0 72.17

131 28.1131 5157.3 4868.9 72.55

132 27*9016 5207*9 4917*4 72-94

133 27.6865 5259.2 4966.4 73.32

134 27.4676 5311,1 5016.0 73.71

135 27.2446 5363.7 5066.2 74.10

136 27.0171 5416.7 5116.7 74,49

137 26.7850 5470.3 5167.6 74.89

138 26.5479 5524.5 5219.1 75.28

139 26*3054 5579.3 5271*2 75.68

140 26.0571 5634.8 5323.7 76.07

141 25.8025 5691.1 5376.9 76.47

142 25.5411 5748.2 5430.8 76.88

143 25*2724 5806.3 5485*5 77.29

144 24.9956 5865.5 5541.2 77.70

145 24.7101 5926.1 5598.1 78.12

146 24.4150 5988.2 5656.2 78.55

147 24.1094 6051.9 5715.7 78.99

148 23.7922 6117.4 5776.7 79.43

149 23.4620 6184.7 5839.2 79,89

150 23.1175 6254.3 5903.6 80.36

151 22.7570 6326.6 5970.4 GO CD O 152 22*3784 6402*1 6039*9 81 .34

153 21.9796 6480.7 6111.9 81.85

154 21.5578 6562.9 6186.8 82.39

155 21.1100 6649.0 6265.0 82.95

156 20.6329 6739.8 6346.9 83.53

157 20.1227 6835.8 6432.9 84.14

158 19.5757 6937.7 6523.6 84.79

159 18.9887 7046.2 6619.4 85.47

lt.0 18*3601 7162*0 6720*5 86.20

« PHASE CHANGE 103

316-977 0 - 69-8
80.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. OENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 17.6914 7285.0 6826.8 86,97 231 4.86833 11469.5 9804.4 109.70

162 16.9886 7415.0 6937.9 87.77 232 4.83422 11500.4 9823.6 109.84

163 16.2639 7550.7 7052.3 88.61 233 4.80072 11531.2 9842.6 109.97

164 15.5344 7689.8 7168.0 89.46 234 4.76784 11561.7 9861.5 110.10

165 14.8190 7829.8 7282.8 90.31 235 4.73554 11592.1 9880.3 110.23

166 14.1345 7968.0 7394.5 91,14 236 4.70381 11622.4 9899.0 110.36

167 13.4928 8102.4 7501.6 91.95 237 4.67264 11652.4 9917.6 110,48

168 12.9003 8231,3 7603.0 92.72 238 4.64199 11682.4 9936.1 110.61

169 12.3585 8354.1 7698.2 93 .45 239 4.61187 11712.1 9954.4 110.73

170 11.8661 8470.4 7787.2 94.14 240 4.58225 11741.8 9972*7 110.86

171 11.4196 8580.2 7870.3 94.78 241 4.55312 11771.2 9990.9 110,98

172 11.0147 8683.8 7947.9 95.38 242 4.52447 11800.6 10008.9 111*10

173 10.6472 8781.7 8020*3 95*95 243 4*49628 11829.8 10026.9 111*22

174 10.3126 8874.2 8088.2 96.48 244 4.46854 11858.9 10044.8 111.34

175 10.0070 8961.9 8151.9 96.99 245 4.44123 11887.8 10062.6 111,46

176 9.72711 9045.3 8211.9 97.46 246 4.41435 11916.6 10080.3 111.59

177 9.46962 9124.6 8268.5 97.91 247 4,38788 1 1 945 ,

4

10097.9 111.69

178 9.23196 9200.3 6322.2 98.34 248 4.36181 11973.9 10115.5 111.81

179 9.01180 9272.7 8373.2 98.74 249 4.33614 12002*4 10133*0 111*92

180 8.80718 9342.3 8421*8 99*13 250 4*31085 12030*8 10150*3 112*04

181 8.61639 9409.1 8468.3 99.50 251 4.28592 12059.0 10167.7 112.15

182 8.43793 9473.4 8512.8 99.86 252 4.26136 12087.1 10184.9 112*26

183 8.27054 9535.6 8555*5 100*20 253 4.23716 12115*2 10202*1 112.37

184 8.11310 9595.7 8596.6 100.52 254 4.21330 12143.1 10219.2 112.48

185 7.96465 9654.0 8636.2 100.84 255 4.18977 12170.9 10236.2 112.59

186 7,82434 9710.5 8674.5 101.14 256 4, 16657 12198.7 10253.1 112.70

187 7.69144 9765.4 8711.5 101,44 257 4.14369 12226.3 10270.0 112.81

1 88 7,56530 9818.9 8747.4 101.72 258 4.12113 12253.8 10286.9 112.92

189 7.44534 9871.0 8782.2 102.00 259 4.09886 12281.3 10303.6 113.02

190 7.33105 9921.9 8816.1 102.27 260 4.07690 12308.7 10320.3 113.13

191 7.22198 9971.6 8849.1 102.53 261 4.05523 12335.9 10337.0 113.23

192 7.11772 10020.1 8881.3 102*78 262 4.03384 12363.1 10353.6 113*34

193 7.01791 10067.7 8912.6 103*03 263 4.01273 12390.2 10370.1 113*44

194 6.92224 10114.3 8943*3 103*27 264 3*99189 12417*2 10386.6 113*54

195 6.83040 10160*0 8973*3 103*51 265 3*97132 12444*2 10403.0 113*64

196 6*74214 10204*9 9002*6 103*74 266 3*95100 12471*6 10419*4 113*75

197 6*65721 10249*0 9031*3 103*96 267 3*93094 12497*8 10435*7 113*85

198 6.57539 10292*3 9059.5 104*18 268 3*91113 12524*5 10451*9 113*95

199 6*49650 10335*0 9087*2 104*39 269 3*89157 12551*2 10468*1 114*05

200 6.42035 10376*9 9114.3 104.61 270 3*87224 12577.7 10484.3 114.14

201 6.34677 10418.2 9141.0 104.81 271 3.85315 12604.2 10500.4 114.24

202 6.27562 10459.0 9167.3 105.01 272 3.83428 12630.6 10516.5 114.34

203 6.20675 10499*1 9193.1 105*21 273 3*81564 12657.0 10532*5 114.44

204 6*14004 10538*7 9218*5 105*41 274 3*79721 12683*3 10548*5 114*53

205 6.07538 10577.8 9243.6 105.60 275 3.77901 12709.5 10564.4 114.63

206 6.01264 10616.4 9268.2 105.79 276 3.76101 12735,6 10580.3 114.72

207 5.95174 10654.6 9292.6 105.97 277 3,74322 12761.7 10596.2 114.82

208 5.89258 10692.3 9316.6 106.15 278 3,72563 12787.8 10612,0 114.91

209 5.83506 10729.5 9340.3 106.33 279 3.70824 12813.7 10627.7 115.00

210 5.77912 10766.4 9363.7 106.51 280 3.69105 12839.6 10643.5 115.10

211 5.72468 10802.9 9386.8 106.68 281 3.67404 12865.5 10659.1 115.19

212 5.67166 10838.9 9409.7 106.85 282 3.65723 12891.3 10674.8 115.28

213 5.62001 10874,7 9432,3 107.02 283 3.64060 12917.6 10690.4 115.37

214 5.56965 10910.1 9454.6 107.18 284 3.62414 12942.7 10706,0 115.46

215 5.52054 10945.1 9476.7 107*35 285 3.60787 12968.3 10721*5 115.55

216 5*47262 10979*8 9498*6 107*51 286 3*59177 12993*9 10737*0 115*64

217 5.42584 11014.3 9520.3 107.67 287 3.57584 13019.4 10752.4 115.73

218 5.38015 11048.4 9541.7 107.82 288 3.56008 13044.9 10767.9 115.82

219 5.33551 11082,2 9562.9 107.98 289 3.54448 13070.3 10783.3 115.91

220 5.29187 11115.8 9584.0 100.13 290 3.52904 13095.6 10798.6 115.99

221 5.24920 11149.1 9604.9 108.28 291 3.51377 13120.9 10814.0 116.08

222 5.20746 11182.2 9625.5 108.43 292 3.49865 13146.? 10829.2 116.17

223 5.16661 11215.0 9646.0 108.58 293 3.48368 13171.4 10844.5 116.25

224 5,12663 11247.6 9666 ,

4

108.73 29** 3.46886 13196.6 10859.7 116.34

225 5.08747 11279.9 9686.5 108.87 295 3.45419 13221.7 10874.9 116.43

226 5.04911 11312,0 9706.5 109.01 296 3.43967 13246.8 10890.1 116,51

227 5.01152 11343.9 9726.4 109.15 297 3.42529 13271.8 10905.3 116.60

228 4.97467 11375.6 9746.1 109.29 298 3.41106 13296.0 10920.4 116,68

229 4.93854 11407.1 9765.7 109.43 299 3.39696 13321.8 10935.5 116.76

230 4.90310 11438.4 9785.1 109.57 300 3.38299 13346.7 10950.5 116.85

104
90.00 atmosphere isobar

temp. DENSITY enthalpy internal ENTROPY

K MOL/LI TER J/MOL ENERGY

J/MOL

J/MOL-K

86.039 35.7x30 3001 .8 2826.5 52.92

87 35.5795 3124.1 2867.8 53*41

88 35*4393 3168*3 2911*0 53*91

89 35*2980 3212*6 2954*3 54*42

90 35*1554 3257*2 2997*8 54*91

PHASE CHANGE

temp. density ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91 35.0117 3301.9 3041.4 55.41

92 34.8670 3346.8 3085*2 55.90

93 34*7212 3391*8 3129*1 56*38

94 34*5745 3436*9 3173*2 56*87

95 34.4267 3482.2 3217.3 57.35

96 34*2780 3527.6 3261*6 57*82

<57 34*1283 3573*1 3305*9 58*29

98 33.9777 3618.7 3350,3 58.76

99 33.8262 3664.4 3394.8 59.22

100 33.6737 3710.2 3439.4 59.68

101 33.5203 3756.0 3484.0 60.14

102 33.3659 3801.9 3528.6 60.59

103 33.2105 3847.9 3573.3 61.04

104 33.0542 3893,9 3618.0 61.49

105 32.8970 3940.0 3662.7 61 .93

106 32.7387 3986.1 3707.5 62.36

107 32.5793 4032.2 3752.3 62,80

108 32.4189 4078.3 3797.0 63.23

109 32.2574 4124.5 3841.8 63.65

110 32*0948 4170.7 3886*6 64.07

111 31.9311 4216.9 3931.3 64,49

112 31.7661 4263.2 3976.1 64,91

113 31.6000 4309.5 4020.9 65.32

114 31.4325 4355.8 4065.6 65.73

115 31.2637 4402.1 4110.4 66.13

116 31.0936 4448.5 4155*2 66.53

117 30*9220 4494*9 4200*0 66*93

118 30*7489 4541*4 4244*8 67*33

119 30*5742 4587*9 4289*6 67*72

120 30*3979 4634*5 4334*5 68*11

121 30.2200 4681.2 4379.5 68.50

122 30.0402 4728.1 4424.5 68.88

123 29.8587 4775.0 4469.6 69.27

124 29.6751 4822.2 4514.8 69.65

125 29.4896 4869.5 4560.2 70.03

126 29*3019 4917.6 4605*7 70.41

127 29*1120 496A .

7

4651*5 70*78

128 28*9197 5012*8 4697*4 71*16

129 28*7250 5061*1 4743*6 71*54

130 28.5277 5109.8 4790.1 71.91

131 28.3277 5158.9 4837.0 72.29

132 28.1247 5208.5 4884.3 72.67

133 27.9187 5258.6 4932.0 73.04

134 27.7095 5309.3 4980.2 73.42

135 27.4969 5360.6 5029.0 73.80

136 27.2807 5412.2 5077.9 74.19

137 27.0607 5464.2 5127.2 74.57

138 26.8366 5516.7 5176.9 74.95

139 26.6081 5569.8 5227.0 75.33

140 26.3751 5623.3 5277.5 75.72

141 26.1371 5677.4 5328,4 76.10

142 25*8938 5732*1 5379.9 76.49

143 25*6450 5787*6 5431*9 76*88

144 25.3900 5843.9 5484.

7

77.27

145 25.1286 5901.3 5538.4 77.67

146 24.8602 5959.8 5592.9 78.07

147 24.5842 6019.4 5648.5 78.48

148 24.3000 6080.4 5705*1 78.90

149 24.0070 6142.7 5762.8 79.32

150 23.7044 6206.5 5821.8 79.75

151 23.3913 6272.2 5882.3 80.19

152 23.0668 6340.2 5944.8 80.64

153 22*7299 6410*1 6008.9 81*10

154 22*3793 6482*1 6074*6 81*56

155 22.0140 6556.5 6142.2 82.05

156 21.6324 6633.4 6211.9 82.54

157 21.2333 6713.2 6283.7 83.05

158 20.8151 6796.0 6357.9 83.58

159 20*3765 6882*2 6434*7 84*12

160 19*9164 6972*0 6514*2 84*68
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211 212

213

214

215

216

217

218

219

220

221 222

223

224

225

226

227

228

229

230

90.00 atmosphere ISOBAR

DENSITY ENTHALPY internal entropy TEMP. DENSITY ENTHALPY internal entropy

MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

19.4340 7065.7 6596.4 85.27 231 5.56492 11337.9 9699.1 108.29

18.9292 7163.3 6681.6 85.87 232 5.52390 11370.4 9719.5 108.43

18.4031 7265.0 6769.4 86.50 233 5,48368 11402.7 9739.6 108.57

17.8582 7370.5 6859.8 87.14 234 5.44423 11434.7 9759.7 108.71

17.2987 7479.4 6952.2 87.80 235 5.40553 11466,6 9779.6 168.84

16.7304 7591.0 7045.9 88.48 236 5.36755 11498.3 9799.3 108.98

16.1604 7704.5 7140.2 89.16 237 5-33027 11529.8 9818.9 109.11

15.5964 7818.7 7234.0 89.84 238 5.29368 11561.1 9838.4 109.24

15.0456 7932.7 7326.6 90*52 239 5.25773 11592.2 9857.7 109.37

14.5143 8045*3 7417.0 91*18 240 5.22243 11623*2 9877*0 109.50

14.0071 3155.8 7504.8 91.83 241 5.18774 11654.0 9896.1 109.63

13.5271 8263.5 7589.3 92.46 242 5.15365 11684.6 9915.1 109.76

13.0756 8367.9 7670.5 93.06 243 5.12014 11715.6 9933.9 109.88

12.6530 8468.7 7748.0 93.65 244 5.08720 11745.4 9952.7 110.01

12.2587 8565.9 7821.9 94.20 245 5.05480 11775.5 9971.4 110.13

11.8914 3659*3 7892*4 94*73 246 5*02293 11805*5 9989*9 110*25

11.5495 8749*1 7959*5 95*24 247 4*99158 11835*4 10008*4 110*37

11*2312 8835*3 8023*3 95*73 248 4.96073 11865*1 10026*8 110*49

10.9347 8918*2 8084*2 96*19 249 4*93037 11894*7 10045*0 110*61

10*6582 8998*3 8142*3 96*64 250 4*90048 11924.1 10063*2 110*73

10.4000 9074.7 8197.8 97.06 251 4.87106 11953.4 10081.3 110.85

10.1584 9148.6 8250.9 97.47 252 4.84208 11982.6 10099.3 110.96

9.93206 9219.9 8301*7 97.86 253 4.81355 12011*7 10117.2 111.08

9* 71950 9288*8 8350*6 98*24 254 4*78544 12040*7 10135*0 111*19

9.51955 9355.4 8397.5 98.60 255 4.75774 12069.5 10152.7 111.31

9.33109 9420.0 8442.6 98.95 256 4,730*5 12098.2 10170.4 111.42

9.15313 9482.5 8486.2 99.28 257 4.70355 12126.8 10188.0 111.53

8*98473 9543*2 8528*2 99*60 258 4.67704 12155*3 10205*5 111*64

8.82524 9602.3 8568.9 99.92 259 4.65091 12183.7 10222.9 111.75

8.67378 9659.7 8608.3 100.22 260 4.62514 12212.6 10240.2 111.86

8.52976 9715.7 8646.5 100.51 261 4.59972 12240.1 10257.5 111.97

8.39260 9770.2 8663.6 100.80 262 4.57466 12268.2 10274.7 112.07

8.26177 9823.5 8719.7 101*08 263 4.54994 12296.2 10291.9 112*18

8.I368O 9875.6 8754.8 101*35 264 4*52555 12324.1 10309*0 1 i 2 * 29

8.01726 9926.5 8769*0 101*61 265 4*50148 12351*9 10326.0 112*39

7.90276 9976.4 8822.4 101.86 266 4.47773 12379.6 10342.9 112*50

7.79297 10025.2 8855*0 102*11 267 4.45429 12407.2 10359.8 112*60

7 • 68754 10073*1 8886*8 102*35 268 4*43116 12434.7 10376*7 112*70

7.58621 10120.1 8918.0 102.59 269 4.40832 12462.1 10393.4 112.81

7.48870 10166.3 8948.5 102.82 270 4.38578 12489.5 10410.1 112.91

7.39477 10211.6 8978.4 103.05 271 4.36351 12516.7 10426.8 113.01

7*30*21 10256*2 9007*7 103*27 272 4*34153 12543.9 10443.4 113*11

7.21680 10300*1 9036.5 103*49 273 4.31981 12571.6 10459*9 113*21

7.13237 10343.3 9064.7 103.70 274 4.29836 12598.1 10476.4 113.31

7.05074 10385.9 9092.5 103.91 275 4.27718 12625.0 10492,9 113.40

6.97175 10427.8 9119.8 104.11 276 4.25624 12651.9 10509.3 113.50

6.89527 10469.2 9146.6 104.31 277 4.23556 12678,7 10525.6 113.60

6.82115 10510.0 9173.1 104.51 278 4.21512 12705.4 10541 .9 113.69

6,74926 10550.3 9199.1 104.70 279 4.19493 12732,1 10558,1 113.79

6.67951 10590.0 9224.7 104.89 280 4.17496 12758.7 10574.3 113.89

6.61177 10629.3 9250.0 105.08 281 4.15523 12785.2 10590.5 113.98

6.54594 10668.1 9275.0 105.26 282 4.13572 12811.6 10606.6 114.07

6.48195 10706.5 9299.6 105.44 283 4.11644 12838.6 10622*6 114.17

6.41969 10744.4 9323.9 105*62 284 4.09737 12864.4 10638.7 114.26

6*35903 10781.9 9347.9 105*79 285 4*07852 12890*6 10654.6 114*35

6 » 3 0 0 0 5 10819.1 9371*6 105*97 286 4*05987 12916*8 10670*6 114.44

6.24255 10855.8 9395.0 106*14 287 4.04143 12943.6 10686.5 114.54

6*18648 10692*2 9418*1 106*30 288 4*02319 12969.6 10702*3 114.63

6.13179 10928.3 9441 .0 106.47 289 4.00514 12995.1 10718.1 114.72

6.07842 10964,0 9463.7 106.63 290 3.98730 13021.0 10733.9 114.81

6.02632 10999.4 9486.1 106.79 291 3.96964 13046.9 10749.6 114.90

5.97544 11034.5 9508.3 106.95 292 3*95217 13072*8 10765-3 114.98

5.92572 11069*3 9530*3 107.11 293 3.93488 13098*6 10781*0 115*07

5.87712 11103.8 9552.1 107.26 294 3.91777 13124.3 10796.6 115.16

5.82960 11138.0 9573.6 107.41 295 3.90084 13150.0 10812*2 115.25

5.78312 11171.9 9595.0 107.56 296 3.88408 13175.6 10827.7 115.33

5.73763 11205.6 9616.2 107.71 297 3.86749 13201.2 10843.2 115.42

5.69310 11239.0 9637.2 107.86 298 3.85108 13226.9 10858.7 115.51

5.64949 11272.2 9658.0 108.00 299 3.83482 13252.2 10874.2 115.59

5 ,60673 11305.2 9678.6 108.15 300 3.81873 13277.7 10889.6 115.68

106
100.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

86.287 35.7440 3111.6 2828.2 52.94

87 35.6457 3142.9 2858.6 53.30

88 35.5068 3186.9 2901.5 53.80

89 35*3667 3231*1 2944.6 54.30

90 35.2254 3275.5 2987.8 54.80

PHASE CHANGE

TEMP. DENSITY ENTHALPY internal ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91 35.0831 3320.0 3031.2 55.29

92 34.9398 3364.7 3074.7 55.78

93 34.7955 3409.6 3118.4 56.26

94 34.6502 3454.5 3162.1 56.74

95 34.5040 3499.7 3206.0 57.22

96 34-3569 3544.9 3249*9 57.69

97 34.2089 3590*2 3294.0 58.16

98 34*0600 3635*6 3338*1 58*63

99 33.9103 3681.1 3382.3 59.09

100 33.7596 3726.7 3426.5 59.55

101 33.6081 3772.3 3470,8 60.00

102 33*4557 3818.6 3515*1 60.45

103 33*3024 3863*8 3559-5 60.90

104 33*1482 3909.5 3603*9 61*34

105 32.9931 3955.4 3648.2 61.78

106 32.8371 4001.2 3692.6 62.21

107 32.6802 4047.1 3737.0 62.65

100 32.5222 4093.0 3781.4 63.07

109 32.3633 4138.9 3825.8 63.50

110 32.2033 4184.8 3870.1 63.91

111 32.0423 4230.7 3914.5 64.33

112 31.8803 4276.6 3958.8 64,74

113 31.7171 4322.6 4003.1 65.15

114 31.5527 4368.5 4047.4 65.56

115 31.3871 4414.5 4091,7 65.96

116 31.2203 4460.5 4136.0 66.36

117 31.0523 4506.5 4180.2 66.75

118 30.8828 4552.6 4224.5 67.14

119 30*7120 4598*7 4268*8 67.53

120 30.5398 4644.9 4313*1 67.92

121 30.3660 4691.1 4357.4 68.30

122 30.1907 4737.4 4401*8 68.68

123 30.0137 4783.8 4446 «

2

69.06

124 29.8350 4830.4 4490*8 69.44

125 29.6545 4877.1 4535.4 69.81

126 29.4722 4924,0 4580.1 70,19

127 29.2879 4971.6 4625.1 70,56

128 29.1016 5018,3 4670.2 70,93

129 28.9132 5065,9 4715.5 71,30

130 28.7225 5113.8 4761.1 71.67

131 28,5294 5162.1 4806.9 72.04

132 28.3339 5210.8 4853.1 72.41

133 28.1358 5259.9 4899.7 72.78

134 27.9350 5309.5 4946.8 73.15

135 27.7313 5359.7 4994.3 73.53

136 27.5246 5410.1 5041.9 73.90

137 27.3147 5460,8 5089,8 74.27

138 27.1014 5511.9 5138.0 74.64

139 26.8846 5563,5 5186.6 75,01

140 26.6641 5615.4 5235.3 75.39

141 26.4395 5667,7 5284.4 75.76

142 26*2108 5720*5 5333*9 76.13

143 25.9776 5773.9 5383*8 76.51

144 25.7397 5828.6 5434.3 76.89

145 25*4967 5882-9 5485*5 77.27

146 25*2484 5938.7 5537*3 77.65

147 24.9944 5995.4 5590.0 78.04

148 24.7343 6053. f 5643.4 78.43

149 24.4677 6111.7 5697.6 78.83

150 24.1942 6171*5 5752*7 79.23

151 23.9132 6232.8 5809.1 79,64

152 23.6243 6295.8 5866.9 80.06

153 23.3269 6360.2 5925.8 aO , 48

154 23.0205 6426.0 5985.8 80.91

155 22.7043 6493.3 6047.1 81.35

156 22.3777 6562.4 6109.6 81,79

157 22.0401 6633.2 6173.5 82.24

158 21.6908 6706.0 6238.8 82.71

159 21.3291 6780.8 6305.7 83.18

160 20*9544 6857.8 6374.2 83*66
100.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP. density enthalpy internal entropy

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL energy

J/MOL

J/MOL-K

161 20.5663 6937.1 6444.4 84.15 231 6.27532 11207.6 9592.9 106.98

162 20.164a 7018.8 6516.3 84,66 232 6.22691 11241.7 9614.4 107.13

163 19.7487 7103,0 6589.9 85.18 233 6.17949 11275.5 9635.8 107.28

164 19,3197 7189.7 6665.2 85.71 234 6.13304 11309.1 9657.0 107.42

165 18.8780 7278.8 6742.1 86.25 235 6.08751 11342.5 9678.0 107.56

166 18.4252 7370.4 6820.4 86.80 236 6.04288 11375.6 9698.8 107.70

167 17.9632 7464.0 6899.9 87.37 237 5.99911 11408.5 9719.5 107.84

168 17.4948 7559.6 6980*4 87.94 238 5.95617 11441.2 9740.0 107.98

169 17.0233 7656.5 7061*3 88.51 239 5.91405 11473.7 9760.4 108.12

170 16.5522 7754.5 7142*3 89.09 240 5*87270 11506.0 9780*6 108.25

171 16.0854 7852.8 7222.9 89.67 241 5.83212 11538.1 9800,7 108.38

172 15.6265 7951.1 7302.7 90.24 242 5.79226 11570.0 9820.6 108.52

173 15.1788 8048*8 7381*3 90*81 243 5.75312 11601*7 9840*4 108.65

174 14.7451 8145.4 7458.2 91.36 244 5.71467 11633.2 9860*1 108.78

175 14.3273 8240.5 7533.3 91.91 245 5.67688 11664.6 9879.7 108,91

176 13.9271 8333.8 7606.2 92.44 246 5.63975 11695.8 9899.1 109.03

177 13.5452 8425.0 7676.9 92.96 247 5.60324 11726.8 9918.4 109,16

178 13.1820 8514.0 7745.3 93.46 248 5.56734 11757.6 9937.6 109.28

179 12.8374 8600.6 7811.3 93.94 249 5.53204 11788.3 9956.7 109.41

180 12.5111 8684.8 7874.9 94.41 250 5.49731 11818.9 9975.6 109.53

181 12.2024 8766.6 7936.2 94.86 251 5.46314 11849.3 9994.5 109.65

182 11.9106 8846.0 7995*3 95.30 252 5.42952 11879.5 10013.3 109.77

183 11.6347 8923.1 8052.2 95.72 253 5.39643 11909.6 10031.9 109.89

184 11.3739 8997.9 8107.0 96.13 254 5.36385 11939.6 10050.5 110.01

185 11.1273 9070.5 8159.8 96.53 255 5.33178 11969.4 10069.0 110.12

186 10.8939 9141.0 8210.8 96.91 256 5.30019 11999.1 10087.3 110.24

187 10.6728 9209.4 8260*0 97.27 257 5.26908 12028.7 10105.6 110.36

188 10*4632 9276*0 8307*6 97*63 258 5*23843 12058*1 10123*8 110.47

189 10.2643 9340*8 8353*6 97*97 259 5*20824 12087*4 10141.9 110.58

190 10.0753 9403.8 8398.1 98.30 260 5.17848 12116.6 10159.9 110.70

191 9,89564 9465.2 8441.2 98.63 261 5.14916 12145.7 10177.9 110.81

192 9 • 7?448 9525.1 8483*1 98.94 262 5.12025 12174.7 10195.7 110.92

193 9,56130 9583.5 8523.7 99.24 263 5.09175 12203.5 10213.5 111.03

194 9.40555 9640.5 8563.2 99.54 264 5.06365 12232.3 10231.2 111.14

195 9.25672 9696.2 8601*6 99.82 265 5.03594 12260.9 10248.8 111.25

196 9.11434 9750.7 8639.0 100.10 266 5*00861 12289.4 10266.4 111.35

197 8.97799 9804.1 8675.4 100*37 267 4.98165 12317.9 10283.9 111.46

198 8.8472(3 9856.3 8711.0 100.64 268 4.95505 12346.2 10301.3 111.57

199 8.72180 9907.5 8745.7 100.90 269 4.92880 12374.4 10318.6 111.67

200 8,60127 9957.7 8779.6 101.15 270 4.90291 12402.6 10335.9 111.78

201 8 . 48536 10006,9 8812.8 101.39 271 4.87735 12430.6 10353.1 111.88

202 8.37379 10055.3 8845.2 101.63 272 4.85212 12458.5 10370.2 111.98

203 8.26630 10102.8 8877.0 101.87 273 4-82721 12486.4 10387-3 112.08

204 8.16265 10149.5 8908.2 102.10 274 4.80262 12514.2 10404.3 112.19

205 8.06261 10195.5 8938.7 102.32 275 4.77834 12541.8 10421.3 112.29

206 7.96597 10240,7 8968.7 102.54 276 4.75436 12569.4 10438.2 112.39

207 7.87256 10285.3 8998.2 102.76 277 4.73068 12597,6 10455.0 112.49

208 7.78219 10329.1 9027.1 102.97 278 4,70728 12624.4 10471,8 112.59

209 7.69470 10372.4 9055.5 103,18 279 4.68418 12651.7 10488.5 112.68

210 7.60993 10415.0 9083,5 103.38 280 4.66135 12679.0 10505.2 112.78

211 7.52776 10457.1 9111.0 103.58 281 4.63879 12706.2 10521.8 112.88

212 7.44803 10498.6 9138.1 103.78 282 4.61650 12733,3 10538.4 112.97

213 7.37064 10539.6 9164.8 103.97 283 4.59447 12760.4 10554.9 113.07

214 7.29547 10580.1 9191.2 104.16 284 4.57269 12787.3 10571,4 113.17

215 7.22241 10620.1 9217.1 104.35 285 4.55117 12814.2 10587.8 113.26

216 7.15136 10659.6 9242.7 104.53 286 4.52990 12841.6 10604.2 113.35

217 7.08223 10698.7 9268.0 104.71 287 4.50886 12867.8 10620.5 113.45

218 7.01493 10737.4 9292.* 9 104.89 288 4.48806 12894.5 10636.8 113.54

219 6.94938 10775.6 9317.6 105.06 289 4.46750 12921.1 10653.0 113.63

220 6.88551 10813.5 9341.9 105.24 290 4.44716 12947.7 10669.2 113.72

221 6.82323 10851.0 9365.9 105.41 291 4.42705 12974.2 10685.3 113.82

222 6.76249 10888.1 9389.7 105.57 292 4.40715 13000.6 10701.4 113.91

223 6.70322 10924.8 9413.2 105.74 293 4.38747 13027,0 10717.5 114.00

224 6.64535 10961.3 9436.5 105.90 294 4.36801 13053.3 10733.5 114.09

225 6.58884 10997.4 9459.5 106.06 295 4.34875 13079.5 10749.5 114.18

226 6.53362 11033.1 9482.3 106.22 296 4.32969 13105,7 10765.4 114.26

227 6.47965 11068.6 9504.8 106.38 297 4.31083 13131.8 10781.3 114.35

228 6.42688 11103.8 9527.1 106.53 298 4.29217 13157.9 10797.2 114.44

229 6.37526 11138.7 9549.3 106.68 299 4.27371 13183.9 10813.0 114.53

230 6.32475 11173.3 9571.2 106.83 300 4.25543 13209.9 10828.8 114.61

108
120.00 ATMOSPHERE isobar

TEMP. density enthalpy INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

\

86.782 35.8048 3171.2 2831 .6 52.97

87 35.7751 3180.7 2840.8 53.08

88 35.6385 3224.4 2883.2 53.58

89 35,5008 3268.3 2925.8 54.08

90 35.3621 3312.3 2968.5 54.57

PHASE CHANGE

TEMP. density ENTHALPY INTERNAL entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 35.2223 3356.6 3011.3 55.06

92 35.0817 3400.9 3054.3 55.54

93 34.9401 3445.5 3097.5 56.02

94 34.7977 3490.1 3140.7 56.50

95 34.6544 3534.9 3184.0 56.97

96 34.5103 3579.8 3227.4 57.44

97 34.3655 3624.7 3270.9 57,91

98 34.2198 3669.8 3314.5 58.37

99 34.0734 3714.9 3358.1 58.83

100 33.9262 3760*1 3401.7 59.28

101 33.7782 3805.4 3445.4 59.74

102 33.6295 3850.7 3489.1 60.18

103 33.4800 3896.0 3532.9 60.62

1 04 33.3298 3941.4 3576.6 61.06

105 33.1788 3986.8 3620.3 61.50

106 33.0270 4032*2 3664.0 61*93

107 32.8744 4077.6 3707.7 62*35

108 32.7210 4123.0 3751.4 62.78

109 32.5667 4168.4 3795.0 63. 19 110 32.4116 4213.8 3838.6 63.61

111 32.2556 4259.2 3882.2 64.02

112 32.0988 4304.5 3925*7 64,43

113 31.9410 4349.9 3969.2 64.83

114 31.7822 4395.2 4012.6 65.23

115 31.6225 4440.5 4056.0 65.62

116 31.4618 4485.9 4099.4 66.02

117 31.3000 4531.2 4142.7 66,41

118 31.1372 4576.5 4186.0 66.79

119 30.9732 4621.8 4229.2 67.17

120 30.8080 4667.2 4272.5 67.55

121 30.6417 4712.5 4315.7 67.93

122 30.4741 4758.6 4359.0 68.30

123 30.3052 4803.5 4402.2 68 • 68

124 30*1350 4849.0 4445*5 69*04

125 29.9634 4894.7 4488*9 69.41

126 29*7903 4940*5 4532*3 69*78

127 29.6157 4986.4 4575.8 70.14

128 29.4395 5032.5 4619.5 70.50

129 29.2617 5078.8 4663,2 70.86

130 29.0822 5125.3 4707.2 71.22

131 28.9009 5172.1 4751.4 71.58

132 28.7178 5219.3 4795*9 71.94

133 28.5328 5266.8 4840.6 72*30

134 28.3457 5314.7 4885.7 72.65

135 28*1565 5363.0 4931*2 73*01

136 27*9652 5411.5 4976*7 73-37

137 27*7715 5460*2 5022*3 73*73

138 27.5755 5509.1 5068.1 74.08

139 27.3770 5558.3 5114,1 74.44

140 27.1758 5607.7 5160.2 74.79

141 26.9720 5657.3 5206.4 75.15

142 26.7653 5707.2 5252.9 75.50

143 26.5556 5757.5 5299.6 75.85

144 26*3427 5808.3 5346*7 76.21

145 26.1266 5859.6 5394.2 76.57

146 25.9071 5911*5 5442.2 76.92

147 25*6840 5964.1 5490*6 77.28

148 25*4571 6017*3 5539*6 77.65

149 25*2263 6071*0 5589*0 78-01

150 24.9914 6125.5 5639.0 78.38

151 24.7521 6181.0 5689.8 78.75

152 24.5084 6237.8 5741.7 79.12

153 24.2599 6295.3 5794.1 79.50

154 24.0064 6353.6 5847.1 79.88

155 23.7479 6412.8 5900.8 80.26

156 23*4839 6472*9 5955*2 80*65

157 23.2143 6534.0 6010.2 81.04

158 22.9389 6596.0 6065.9 81.44

159 22.6575 6659.1 6122.4 91.83

160 22.3699 6723.2 6179.7 82.24
120.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 22.0759 6788.5 6237.7 82.64 231 7.72113 10954.9 9380.1 104.63

162 21.7755 6854.9 6296.5 83.05 232 7.65716 10992.0 9404.1 104.79

163 21.4685 6922.4 6356.0 83.47 233 7.59458 11028.9 9427.8 104.95

164 21.1549 6991.2 6416.4 83.89 234 7.53335 11065.3 9451.3 105.11

165 20.8347 7061.2 6477.6 84.31 235 7.47343 11101.5 9474.5 105.26

166 20.5082 7132.4 6539.5 84.75 236 7.41476 11137.5 9497.6 105.41

167 20.1756 7204.9 6602*2 85.18 237 7.35729 11173.1 9520.4 105.56

168 19.8372 7278.6 6665 • 6 85.62 238 7.30100 11208.5 9543-0 105.71

169 19.4936 7353.4 6729.6 86.06 239 7.24584 11243.6 9565.5 105.86

170 19.1455 7429.2 6794.1 86.51 240 7.19177 11278.4 9587.7 106.01

171 18.7936 7506.1 6859.1 86.96 241 7.13875 11313.0 9609.7 106.15

172 18.4390 7583.9 6924.5 87*42 242 7*08676 11347.4 9631.6 106.29

173 18.0827 7662.4 6990.0 87.87 243 7.03575 11381.5 9653*3 106.43

174 17.7260 7741.5 7055.6 88.33 244 6.98570 11415.4 9674.8 106.57

175 17.3702 7821.1 7121.0 88.78 245 6.93658 11449.1 9696.2 106.71

176 17.0165 7900.8 7186.3 89.24 246 6,88836 11482.6 9717.4 106.85

177 16.6662 7980.6 7251.0 89.69 247 6.84100 11515.8 9738.4 106.98

178 16.3206 8060.3 7315.3 90.14 248 6.79449 11548.9 9759.3 107. 11 179 15.9809 8139.6 7378.8 90.58 249 6.74880 11581.8 9780.1 107.25

180 15.6479 8218.5 7441.4 91.02 250 6.70390 11614.

A

9800.7 107.38

181 15.3227 8296.7 7503.1 91.46 251 6.65978 11646.9 9821.1 107.51

182 15.0059 8374.0 7563.7 91.88 252 6.61640 11679.2 9841 .4 107.64

183 14.6981 8450.5 7623.2 92.30 253 6.57375 11711.3 9861.6 107.76

184 14.3997 8525.9 7681.5 92.71 254 6.53181 11743.3 9881.7 107.89

185 14.1109 8600.2 7738,5 93.11 255 6.49056 11775.0 9901.6 108.01

186 13.8319 8673.4 7794.3 93.51 256 6,44997 11806.6 9921.5 108.14

187 13.5627 8745.3 7848.8 93.89 257 6.41003 11838.1 9941.2 108.26

188 13,3033 8816.0 7902.0 94.27 258 6.37073 11869.4 9960.8 108.38

189 13.0536 8885.4 7953.9 94.64 259 6.33204 11900.5 9980.2 108.50

190 12.8132 8953.5 8004.5 95.00 260 6.29395 11931.5 9999.6 108.62

191 12.5820 9020.3 8053.9 95.35 261 6.25644 11962.4 10018.9 108.74

192 12.3597 9085.8 8102.0 95.69 262 6.21950 11993.1 10038.0 108.86

193 12*1459 9150*1 8149*0 96*03 263 6*18312 12023.6 10057 •

1

108.97

194 11.9404 9213*1 8194*8 96*35 264 6*14727 12054.0 10076*0 109.09

195 11.7428 9275.0 8239.5 96.67 265 6.11195 12084,3 10094.9 109.20

196 11.5527 9335.6 8283.1 96.98 266 6.07715 12114.5 10113.6 109.32

197 11,3699 9395.1 8325.7 97.28 267 6.04284 12144.5 10132.3 109.43

198 11.1940 9453.5 8367.3 97.58 268 6.00903 12174.4 10150.9 109.54

199 11.0246 9510.8 8407.9 97.87 269 5.97569 12204.2 10169.4 109.65

200 10.8615 9567.1 8447.6 98.15 270 5,94281 12233.9 10187,8 109.76

201 10.70*3 9622.3 8486.4 98.42 271 5.91039 12263.4 10206.1 109.87

202 10.5529 9676.6 8524*3 98*69 272 5*87841 12292.8 10224*4 109.98

203 10.4067 9729.9 8561.5 98.96 273 5.84687 12322.2 10242.5 110.09

204 10.2657 9782.3 8597.9 99.21 274 5.81575 12351.4 10260*6 110.19

205 10.1296 9833.9 6633.5 99.47 275 5.78504 12380.5 10278.6 110.30

206 9.99811 9884.6 8668.5 99.71 276 5.75474 12409.5 10296.5 110.41

207 9.87097 9934.5 8702.7 99.96 277 5.72483 12438.4 10314.4 110.51

208 9.74802 9983.7 8736.3 100.19 278 5.69531 12467.1 10332.2 110.61

209 9.62904 10032.1 8769.3 100.42 279 5.66617 12495.8 10349.9 110.72

210 9.51384 10079.8 8801.7 100.65 280 5.63739 12524.4 10367.5 110.82

21 1 9.40224 10126.7 8833.5 100.88 281 5.60898 12552.9 10385.1 110.92

212 9.29406 10173.1 8864.8 101.09 282 5.58093 12581.3 10402.6 111.02

213 9.18916 10218.8 8895*5 101.31 283 5.55322 12609.7 10420.1 111.12

214 9.08737 10263.8 6925.8 101.52 284 5.52585 12637.9 10437.4 111.22

215 8.98856 10308.3 8955.6 101.73 285 5.49881 12666.0 10454.8 111.32

216 8,89258 10352.2 8984.9 101.93 286 5.47210 12694.1 10472.0 111.42

217 8.79931 10395.6 9013.7 102.13 287 5.44571 12722.6 10489.2 111.52

218 8.70862 10438.4 9042.2 102.33 288 5.41963 12749.9 10506.3 111.61

219 8.62042 10480.8 9070.2 102.52 289 5.39385 12777.7 10523.4 111.71

220 8.53458 10522.6 9097.9 102.71 200 5.36838 12805.4 10540.5 111.81

221 8.45100 1 0564 ,

0

9125.2 102.90 291 5.34320 12833.1 10557.4 111.90

222 8.36960 10604.9 9152.1 103.09 29? 5.31831 12860.7 10574.3 112.00

223 8.29027 10645.3 9178.6 103.27 293 5.29370 12888.1 10591.2 112.09

224 8.21294 10685.4 9204.9 103.45 294 5.26937 12915.6 10608.0 112.18

225 8.13752 10725.0 9230.8 103.62 295 5.24531 12942.9 10624.8 112.28

226 8.06393 10764.3 9256.4 103.80 296 5.22152 12970.2 10641.5 112.37

227 7.99211 10803-1 9281.7 103*97 297 5.19799 12997.4 10658.1 112.46

228 7.92198 10841.6 9306.7 104.14 298 5.17472 13024.5 10674.7 112.55

229 7.85349 10879.7 9331.4 104.30 299 5*15170 13051*6 10691.3 112.64

230 7.78655 10917*5 9355*9 104.47 300 5.12893 13078.5 10707*8 112.73

110
140.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

87.275 35.8638

88 35.7663

89 35.6308

90 35.4944

3230*6

3262.1

3305.7

3349.5

2835*1

2865.5

2907.6

2949.8

53*00

53.36

53.86

54.34

TEMP. DENSITY ENTHALPY INTERNAL entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

91 35.3571 3393.4 2992.2 54.83

92 35,2189 3437.5 3034.7 55.31

93 35.0799 3481.7 3077,3 55.79

94 34.9401 3526.1 3120.1 56.26

95 34.7995 3570.5 3162.9 56.73

96 34.6583 3615.1 3205.8 57.20

97 34.5163 3659.8 3248.8 57.66

98 340736 3704*5 3291.8 58.12

99 34.2303 3749,3 3334.9 58.58

100 34.0862 3794.2 3378,0 59.03

101 33.9416 3839.1 3421.1 59.48

102 33.7962 3884.0 3464.3 59.92

103 33.6502 3929.0 3507.4 60.36

104 33.5036 3974.0 3550.5 60.79

105 33,3563 4019.0 3593.7 61.22

106 33.2083 4063.9 3636.8 61.65

107 33.0596 4108.9 3679.8 62.07

108 32.9103 4153.9 3722.9 62.49

109 32.7602 4198.9 3765.8 62.90

110 32.6095 4243.8 3808.8 63.31

111 32.4580 4288.7 3851.6 63.72

112 32.3058 4333.5 3894.4 64.12

113 32.1528 4378.4 3937.2 64.52

114 31*9990 4423.2 3979*8 64*92

115 31*8444 4467*9 4022*5 65.31

116 31.6890 4512,7 4065.0 65.69

117 31.5328 4557.4 4107*5 66.08

118 31*3756 4602*1 4149.9 66*46

119 31*2176 4646 * 7 4192.3 66 * 84

120 31.0586 4691.4 4234.6 67.21

121 30.8986 4736.0 4276.9 67.58

122 30.7377 4780.7 4319.2 67.95

123 30.5757 4825.4 4361.4 68,31

124 30.4126 4870.1 4403.7 68.67

125 30.2484 4914.9 4445,9 69.03

126 30.0831 4959.8 4488.2 69.39

127 29.9166 5004.8 4530.6 69.75

128 29.7489 5049.8 4573.0 70.10

129 29.5798 5095.1 4615.5 70.45

130 29.4095 5140.5 4658,2 70.80

131 29.2378 5186.2 4701.0 71.15

132 29.0646 5232.1 4744.0 71.50

133 28.8900 5278.3 4787,3 71.85

134 28.7139 5324.9 4830.9 72.20

135 28.5362 5371.8 4874.7 72.55

136 28.3568 5418.8 4918.5 72.90

137 28.1757 5465.8 4962.4 73.24

138 27.9929 5513.1 5006.3 73.58

139 27.8082 5560.5 5050.4 73.93

140 27.6216 5608.0 5094.5 74.27

141 27.4331 5655.7 5138.6 74.61

142 27.2425 5703.5 5182.8 74.95

143 27.0408 5751*6 5227.1 75.28

144 26.8549 5800.0 5271.8 75.62

145 26.6577 5848.8 5316.7 75.96

146 26.4581 5898.1 5361.9 76.30

147 26.2561 5947.8 5407.5 76.64

148 26*0516 5998.0 5453*4 76.99

149 25.8444 6048.5 5499.6 77.33

150 25.6345 6099.6 5546.2 77.67

151 25.4218 6151.5 5593.5 78.02

152 25.2062 6204.3 5641.5 78.37

153 24*9876 6257.7 5690*0 78.72

154 24.7658 6311.6 5738.8 79.07

155 24.5409 6366.0 5788.0 79.42

156 24.3127 6421.1 5837.6 79.78

157 24.081

1

6476.7 5887.6 80.13

158 23*8460 6532*9 5938*0 80.49

159 23*6074 6589.8 5988.9 80.85

160 23.3652 6647.3 6040.2 81.21

111 PHASE CHANGE
uo.oo atmosphere isobar

TEMP. DENSITY ENTHALPY internal entropy temp. density ENTHALPY INTERNAL entropy

K mol/liteh J/MOL ENERGY

J/MOL

j/mol-k K MOL/LITER J/MOL ENERGY

J/MOL

j/mol-k

161 23.1192 6705.5 6091.9 81.57 231 9.16717 10719,0 9171.5 102.57

162 22.8696 6764.3 6144.0 81 .93 232 9.08794 10758.7 9197.8 102.74

163 22.6162 6823.9 6196.6 82.30 233 9.01046 10798.1 9223.7 102.91

164 22.3590 6884.1 6249.7 82.67 234 8.93466 10837.1 9249,3 103.08

165 22.0981 6945.1 6303.1 83.04 235 8.86050 10875.7 9274.7 103.24

166 21.8334 7006.8 6357.0 83.41 236 8.78792 10914.1 9299.8 103.40

167 21.5651 7069.2 6411.4 83.79 237 8.71686 10952.1 9324.7 103.57

168 21.2932 7132.3 6466 •

1

84.16 238 8.64727 10989.8 9349.3 103.72

169 21.0179 7196.2 6521*2 84 *54 239 8.57911 11027*2 9373.7 103.88

170 20.7394 7260.7 6576.7 84.92 240 8.51232 11064.4 9397.9 104.04

171 20.4580 7326.0 6632.6 85.31 241 8.44687 11101.2 9421.8 104.19

172 20 .1738 7391.9 6688.7 85.69 242 8*38271 11137.8 9445.5 104.34

173 19.9873 7458.3 6745.0 86.08 243 8*31980 11174.1 9469.0 104.49

174 19.5989 7525.4 6801*6 86.46 244 8.25809 11210.1 9492.3 104.64

175 19.3089 7593*0 6858*3 86.85 245 8*1 9757 11245.9 9515.4 104.78

176 19.0180 7661.1 6915.1 87.24 246 8*13817 11281*4 9538*3 104.93

177 18.7265 7729.5 6972.0 87.63 247 8.07988 11316.7 9561.0 105.07

178 18.4350 7798.3 7028.8 88.01 248 8.02266 11351.8 9583.5 105,21

179 18.1443 7867.3 7085.4 88.40 249 7.96648 11386.6 9605.9 105.35

1 80 17.8547 7936.4 7141.9 88.79 250 7.91130 11421.2 9628.1 105.49

181 17.5670 8005.7 7198.1 89.17 251 7.85710 11455.6 9650.1 105.63

182 17.2817 8074.9 7254.0 89.55 252 7.80385 11489.7 9671 .9 105.77

183 16.9994 8144.0 7309.5 89.93 253 7.75152 11523.7 9693.6 105.90

184 16.7206 8212.9 7364.5 90*30 254 7.70008 11557.5 9715.2 106.03

185 16. 4459 8231.5 7418.9 90*68 255 7.64952 11591.6 9736.5 106.17

186 16.1756 8349.8 7472.8 91.04 256 7.59980 11624.4 9757.8 106.30

187 15.9101 8417.6 7526.0 91.41 257 7.55090 11657.6 9778.9 106.43

188 15.6499 8485.0 7578.5 91.77 258 7.50280 11690.6 9799.8 106,55

189 15.3951 8551.8 7630.3 92.12 259 7.45548 11723.4 9820.6 106,68

190 15.1461 8617.9 7681.3 92.47 260 7.40892 11756.0 9841.3 106.81

191 14.9029 8683.4 7731.6 92.81 261 7.36310 11788.5 9861 .9 106.93

192 14.6657 8748*3 7781.0 93.15 262 7*31800 11820*8 9882*3 1Q7.05

193 14.4347 8812.3 7829.6 93.49 263 7.27359 11852.9 9902.6 107.18

194 14.2098 8875.7 7877.3 93.81 264 7.22987 11884.9 9922.8 107.30

195 13-9910 8938.2 7924*3 94.13 265 7*18681 11916.7 9942.9 107.42

196 13.7783 8999.9 7970.4 94.45 266 7.14440 11948.4 9962*8 107.54

197 13*5717 9060*9 8015*6 94*76 267 7*10262 11979*9 9982*7 107*66

198 13.3710 9121*0 8060*0 95.06 268 7*06145 12011*3 10002*4 107*77

199 13*1762 9180*3 8103*7 95*36 269 7*02089 12042*6 10022*0 107*89

200 12.9871 9238.8 8146*5 95*66 270 6*98091 12073.6 10041.6 108.01

201 12.8036 9296.4 8188.5 95.94 271 6.94150 12104.6 10061,0 108.12

202 12.6255 9353.3 8229.7 96.23 272 6.90266 12135.4 10080.3 108*23

203 12.4527 9409.4 8270*2 96.50 273 6*86435 12166.1 10099.5 108*35

204 12.2851 9464.7 8310*0 96.78 274 6.82658 12196.7 10118.6 108.46

205 12.1225 9519.2 8349.0 97.04 275 6.78933 12227.1 10137.7 108.57

206 11.9646 9573.0 8387.3 97.30 276 6.75259 12257.4 10156.6 108.68

207 11.8115 9626.0 8425.0 97.56 277 6.71635 12287.6 10175.5 108.79

208 11.6628 9678.3 8461.9 97.81 278 6.68059 12317.7 10194.3 108.90

209 11.5184 9729.9 8498.3 98.06 279 6.64530 12347.7 10212,9 109.00

210 11.3783 9780.8 8534.0 98.30 280 6.61048 12377.5 10231.5 109.11

211 11.2421 9831.0 8569.1 98,54 281 6.57611 12407.2 10250.1 109.22

212 11.1099 9880*5 8603.7 98.78 282 6.54219 12436.9 10268.5 109.32

213 10.9813 9929.5 8637.6 99.01 283 6.50870 12466.4 10286.9 109.43

214 10.8564 9977.8 8671.1 99.23 284 6.47563 12495.8 10305.1 109.53

215 10.7348 10025.5 8704.0 99.45 285 6.44298 12525.1 10323.3 109.63

216 10.6167 10072,6 8736.4 99.67 286 6.41074 12554.3 10341.5 109.74

217 10.5017 10119.1 8768.3 99.89 287 6.37890 12583.4 10359.5 109.84

218 10.3898 10165.1 8799.7 100.10 288 6.34745 12612.4 10377.5 109.94

219 10.2808 10210.5 8830.7 100.31 289 6.31638 12641.3 10395.5 110.04

220 10,1747 10255.4 8861.2 100.51 290 6.28568 12670.2 10413.3 110.14

221 10.0713 10299.8 8891.3 100.71 291 6.25535 12698,9 10431.1 110.24

222 9.97057 10343.7 8921*0 100*91 292 6.22538 12727*5 10448.8 110.33

223 9.87234 10387*2 8950.2 101*11 293 6*19577 12756.1 10466*5 110.43

224 9*77656 10430*1 8979*1 101*30 294 6.16650 12784.5 10484.1 110.53

225 9,68312 10472.7 9007.6 101.49 295 6.13756 12812.9 10501.6 110.63

226 9.59194 10514.7 9035.8 101,67 296 6.10896 12841.2 10519.1 110.72

227 9,50294 10556,4 9063,6 101.86 297 6.08069 12869,4 10536.5 110.82

228 9.41603 10597.6 9091.1 102.04 298 6.05274 12897.6 10553,8 110.91

229 9.33115 10638.5 9118,2 102.22 299 6.02509 12925.6 10571.1 111.01

230 9.24822 10678.9 9145.0 102.40 300 5.99776 12953.6 10588.4 111*10

112
160.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. density ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL energy J/MOL-K K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL J/MOL

91 35.4877 3430.5 2973.7 54.61

92 35.3519 3474.3 3015.7 55.09

93 35.2152 3518.3 3057.9 55.56

94 35.0779 3562.4 3100.2 56.03

95 34.9399 3606.5 3142.5 56.50

96 34.8012 3650.8 3185*0 56.97

97 34.6619 3695*2 3227.5 57.43

98 34.5220 3739.6 3270.0 57,88

99 34.3815 3784.1 3312.6 58.33

100 34.2404 3828,7 3355.2 58.78

101 34.0987 3873.3 3397.8 59.22

102 33.9565 3917.9 3440.4 59.66

103 33.8137 3962.5 3483.1 60.10

104 33.6703 4007.2 3525.6 60.53

105 33.5264 4051.8 3568.2 60,96

106 33.3819 4096.4 3610.8 61.38

107 33.2368 4141.0 3653.2 61.80

108 33,0912 4185.6 3695.7 62.21

109 32.9449 4230.2 3738.1 62,63

HO 32.7981 4274.7 3780.4 63.03

111 32.6507 4319.1 3822.6 63.43

112 32.5026 4363.6 3864.8 63.83

113 32*3539 4407*9 3906*8 64.23

114 32*2046 4452.2 3948.8 64.62

115 32*0546 4496.5 3990*7 65.00

116 31*9039 4540*7 4032*6 65.39

117 31 *7525 4584*9 4074.3 65-77

118 31.6004 4629.0 4116.0 66.14

119 31.4476 4673.1 4157.6 66.51

120 31.2940 4717.2 4199.

1

66.88

121 31.1396 4761.2 4240,6 67.25

122 30.9844 4805.2 4282.0 67.61

123 30.8284 4849.2 4323.3 67.97

124 30.6715 4893.3 4364.7 68,33

125 30.5138 4937.3 4406.0 68.68

126 30.3551 4981.4 4447.3 69.03

127 30.1954 5025,6 4488.7 69.38

128 30.0348 5069.8 4530.1 69.73

129 29.8732 5114.? 4571.5 70.07

130 29.7105 5158,7 4613.1 70.42

131 29.5468 5203.4 4654.7 70,76

132 29.3819 5248.4 4696.6 71.10

133 29*2159 5293.5 4738*6 71.44

134 29.0488 5339.0 4780.9 71.78

135 28.8803 5384.8 4823.4 72.12

136 28.7107 5430.5 4865.8 72.46

137 28.5397 5476.3 4908.3 72.80

138 28.3674 5522.3 4950.8 73.13

139 28.1937 5568.3 4993.2 73.46

140 28.0186 5614.3 5035.7 73.79

141 27.8420 5660.4 5078.1 74.12

142 27.6639 5706.7 5120-6 74.45

143 27.4842 5753.1 5163.2 74.78

144 27*3029 5799.7 5205*9 75*10

145 27*1200 5846*7 5248*9 75*43

146 26.9353 5893*9 5292*0 75.75

147 26.7489 5941*6 5335*5 76.08

148 26.5606 5989.6 5379.2 76,41

149 26.3705 6037.8 5423.0 76.74

150 26.1785 6086.5 5467.2 77.06

151 25.9846 6135.8 5511.9 77.39

152 25,7886 6185.9 5557.3 77.72

153 25.5905 6236.5 5602.9 78.06

154 25.3904 6287.4 5648.8 78.39

155 25.1881 6338.7 5695.0 78.72

156 2*. 9835 6390.3 5741.4 79.05

157 24.7768 6442.4 5788.1 79.38

87.767 35.9213 3290.0 2838*7 53*04 158 24.5677 6495.0 5835*1 79.72

88 35.8904 3300*1 2848*3 53*15 159 24 • 3564 6547*9 5882*3 80.05

89 35*7570 3343.4 2890*0 53.64 160 24*1427 6601*3 5929*8 80.39

90 35*6228 3386*9 2931 •

8

54*13

PHASE CHANGF 113
160.00 ATMOSPHERE IS08AR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY internal entropy

K MOL/LITEK J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 23.9266 6655.1 5977.5 80.72 231 10.5720 10506.6 8972.4 100.76

162 23,7081 6709.4 6025.6 81.06 232 10.4794 10547.6 9000.5 100.94

163 23.4872 6764.1 6073.9 81.40 233 10.3889 10588.9 9028.3 101.11

164 23.2639 6819.3 6122.4 81.73 234 10.3002 10629.8 9055.8 101.29

165 23 . 03*^2 6875.0 6171.3 82.07 235 10.2133 10670.4 9083.0 101.46

166 22.8102 6931.1 6220.4 82.41 236 10.1283 10710.6 9109,9 101.63

167 22.5798 6987.8 6269.8 82.75 237 10.0450 10750.5 9136.6 101.80

168 22.3471 7044.9 6319.4 83.09 238 9.96346 10790.1 9162.9 101.97

169 22.1122 7102.4 6369.2 83.43 239 9.88348 10829.4 9189.0 102.13

170 21.8751 7160.5 6419.3 83.78 240 9.80510 10868.3 9214.8 102.30

171 21.6360 7218.9 6469.6 84.12 241 9.72825 10907.0 9240.4 102.46

172 21.3949 7277.9 6520.1 84.46 242 9.65289 10945.3 9265.8 102.62

173 21.1521 7337,3 6570.8 84.81 243 9.57898 10983.4 9290.9 102.77

174 20.9077 7397.1 6621.6 85.15 244 9.50648 11021.2 9315.8 102.93

175 20.6618 7457.3 6672.6 85.50 245 9.43535 11058.7 9340.4 103.08

176 20.4146 7517.8 6723*7 85*84 246 9.36553 11095-9 9364.9 103.23

177 20-1665 7578.8 6774.8 86*19 247 9.29701 11132*9 9389.1 103*38

178 19.9177 7640*0 6826*0 86 *83 248 9-22974 11169.6 9413*1 103.53

179 19.6683 7701.5 6877-3 86.88 249 9.16368 11206.1 9436.9 103.68

180 19.4188 7763.3 6928.4 87.22 250 9*09880 11242.4 9460*5 103.82

181 19.1693 7825.3 6979.6 87.56 251 9.03507 11278.4 9484.0 103.97

182 18.9203 7887.5 7030.6 87.91 252 8.97245 11314.1 9507.2 104.11

183 18.6720 7949.7 7081.5 88.25 253 8.91092 11349.7 9530.3 104.25

184 18.4247 8012.1 7132.2 88.59 254 8.85044 11385.6 9553.2 104.39

185 18.1789 8074.5 7182*7 88*93 255 8*79099 11420-1 9575.9 104.53

186 17.9347 8136*8 7232*9 89*26 256 8*73254 11455*0 9598*4 104*66

187 17*6925 8199.1 7282*8 89*60 257 8*67506 11489*7 9620*8 104.80

188 17*4526 8261*3 7332*4 89*93 258 8*61853 11524.2 9643*0 1 04.93

189 17.2154 8323.3 7381.6 90.26 259 8.56292 11558.4 9665.1 105.07

190 16.9909 8385.1 7430*4 90*88 260 8-50820 11592.5 9687*0 105.20

191 16.7496 8446.6 7478.7 90.91 261 8.45436 11626,4 9708.8 105.33

192 16.5215 8507.9 7526.6 91.22 262 8.40137 11660.2 9730.4 105.46

193 16.2970 8568.8 7574.0 91.54 263 8.34922 11693.7 9751.9 105.58

194 16.0762 8629.4 7620.9 91.85 264 8.29787 11727,1 9773.3 105.71

195 15.8592 3689.5 7667.2 92.16 265 8.24731 11760.3 9794.5 105.84

196 15.6461 8749.2 7713.0 92.47 266 8.19752 11793.3 9815,5 1 05 ,96

197 15.4371 8808.4 7758.2 92.77 267 8.14847 11826.1 9836.5 106.08

198 15.2323 8867*2 7802*9 93.07 268 8*10017 11858.8 9857*3 106-21

199 15.0317 8925.5 7846.9 93.36 269 8.05257 11891.3 9878.0 106.33

200 14.8352 3983.2 7890.4 93*65 270 8*00567 11923.7 9898*6 106.45

201 14.6431 9040.4 7933.2 93.94 271 7.95946 11955.9 9919.1 106.57

202 14.4552 9097.1 7975.5 94.22 272 7.91391 11988.0 9939.4 106.68

203 14.2715 9153.2 8017.2 94.49 273 7.86900 12019.9 9959.6 106.80

2f)4 14.0920 9208.7 8o58.2 94.77 274 7,82473 12051.7 9979.8 106.92

205 13.9168 9263.6 8098-7 95.04 275 7.78108 12083.4 9999.8 107.03

206 13.7456 9318.0 8138.6 95*30 276 7.73804 12114.9 10019.7 107-15

207 13*5785 9371*8 8177*9 95*56 277 7*69558 12146*2 10039*5 107.26

208 13*4154 9425*1 8216*6 95.82 278 7*65371 12177*5 10059.2 107.37

209 13-2562 9477*7 8254*7 96*07 279 7*61240 12208*6 10078*8 107.49

210 13.1009 9529.8 8292.3 96.32 280 7.57164 12239.6 10098.4 107.60

211 12.9493 9581.4 8329.4 96.56 281 7.53142 12270.4 10117.8 107.71

212 12.8014 9632*3 8365.9 96.80 282 7.49173 12301*2 10137.1 107.82

213 12.6571 9682*8 8401*9 97*04 283 7-45256 12331.8 10156.4 107.92

214 12.5163 9732.7 8437.3 97.28 284 7.41390 12362.3 10175*5 108.03

215 12.3789 9782*0 8472*3 97*51 285 7*37573 12392.6 10194.6 108.14

216 12.2448 9830*8 8506.8 97.73 286 7.33804 12422*9 10213.5 108.24

217 12.1139 9879.1 8540.8 97.96 287 7.30083 12453.1 10232.4 108.35

218 11.9862 9926*9 8574*3 98*18 288 7.26408 12483.1 10251-3 108.45

219 11.8615 9974.2 8607*3 98.39 289 7*22779 12513*1 10270*0 108.56

220 11.7398 10020.9 8640*0 98-60 290 7*19195 12542.9 10288.6 108.66

221 11.6209 10067.3 8672.1 98.81 291 7.15654 12572.6 10307.2 108.76

222 11.5048 10113.1 8703.9 99.02 292 7.12156 12602.2 10325.7 108.86

223 11.3914 10158.5 8735.2 99.23 293 7,08700 12631.8 10344.1 1 08.97

224 11.2806 10203.4 8766.2 99.43 294 7.05286 12661.2 10362.5 109.07

225 11.1724 10247.8 8796.7 99.62 295 7,01911 12690,5 10380.8 109.17

226 11.0666 10291.9 8826.9 99.82 296 6.98576 12719.8 10399.0 109,26

227 10.9632 10335.5 8656.7 100.01 297 6.95280 12748.9 10417.1 109.36

228 10.8621 10378.7 8886,2 100.20 298 6.92022 12778.0 10435.2 109.46

229 10.7633 10421.5 8915.3 100.39 299 6.88801 12806.9 10453.2 109.56

230 10.6666 10463.9 8944.0 100*57 300 6.85616 12835.8 10471.2 109.65

114
180.00 atmosphere isobar

TEMP. density ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

K mol/liteh J/MOL ENERGY J/MOL-K K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL J/MOL

<31 35.6146 3467.9 2955.8 54.39

92 35.4809 3511.5 2997.4 54.87

93 35.3465 3555.2 3039.2 55.34

94 35-2115 3599.6 3081.0 55.81

95 35*0758 3642*9 3122*9 56.28

96 34*9396 3686.9 3164*9 56*74

97 34*8028 3731*0 3206*9 57*19

98 34.6654 3775.2 3249.0 57.65

99 34.5276 3819.4 3291.1 58,10

100 34.3892 3863.6 3333.3 58.54

101 34.2503 3907.9 3375.4 58.98

102 34.1109 3952.3 3417.6 59.42

103 33*9711 3996.6 3459.7 59.85

104 33*8307 4040*9 3501*8 60*28

105 33.6899 4085.2 3543.8 60.70

106 33,5486 4129.5 3585.9 61.12

107 33.4068 4173.8 3627.8 61,54

108 33.2645 4218.0 3669.7 61.95

109 33.1217 4262.2 3711.5 62.36

110 32.9785 4306.3 3753.3 62.76

111 32.8347 4350.4 3794.9 63.16

112 32.6904 4394.4 3836.5 63.55

113 32.5456 4438.4 3878.0 63.94

114 32.4003 4482.3 3919.4 64.33

115 32*2544 4526.1 3960.7 64.71

116 32.1080 4569.9 4001.8 65.09

117 31*9610 4613.6 4042*9 65.47

118 31.8134 4657.2 4083.9 65,84

119 31.6652 4700.8 4124.8 66.21

120 31.5164 4744.3 4165.6 66.57

121 31.3669 4787.8 4206.4 66.93

122 31.2168 4831.3 4247.0 67.29

123 31,0660 4874.7 A287.6 67.64

124 30.9145 4918.1 4328.1 68.00

125 30.7623 4961.5 4368.6 68.34

126 30.6094 5005.0 4409.1 68.69

127 30,4557 5048.5 4449.6 69.03

128 30.30*3 5092.0 4490 .

1

69.38

129 30.1460 5135.6 4530-6 69.72

130 29*9899 5179.4 4571 • 2 70.05

131 29.8329 5223.3 4611.9 70.39

132 29.6751 5267.4 4652.7 70.72

133 29.5164 5311-7 4693.7 71*06

134 29.3567 5356.2 4734.9 71.39

135 29.1961 5401.1 4776.3 71.73

136 29.0345 5445.8 4817.6 72.06

137 28.8719 5490.6 4858.9 72.38

138 28.7083 5535.4 4900,1 72.71

139 28.5436 5580.3 4941,3 73.04

140 28.3778 5625.2 4982.5 73.36

141 28.2108 5670.1 5023.6 73.68

142 28.0427 5715*0 5064* 6 74.00

143 27.8735 5760.1 5105.7 74.31

144 27*7030 5805.3 5147.0 74.63

145 27*5313 5850*8 5188*3 74*94

146 27.3582 5896.6 5229.9 75.26

147 27.1839 5942.6 5271.7 75,58

148 27.0083 5988.9 5313,6 75.89

149 26.8313 6035.5 5355.7 76.21

150 26*6528 6082*3 5398.0 76.52

151 26.4730 6129.7 5440.7 76.84

152 26.2917 6177.8 5484.1 77.16

153 26.1089 6226.2 5527.7 77.48

154 25.9246 6275.0 5571 .4 77.79

155 25.7388 6324,0 5615,3 78.11

156 25,5514 6373.3 5659,4 78.43

157 25.3625 6422.8 5703.7 78.75

158 25.1719 6472.7 5748.2 79.06

88.257 35,9774 3349.3 2842.3 53.07 159 24.9797 6523.0 5792.8 79.38

89 35.8797 3381.3 2873.0 53. A3 160 24.7860 6573.5 5837.6 79.70

90 35.7475 3424.5 2914.3 53.91

115 * PHASE CHANGE
180.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY internal entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/L ITER J/MOL ENERGY

J/MOL

j/mol-k

161 24.5905 6624.3 5882.6 80.01 231 11.9011 10319.2 8786.7 99.17

162 24.3935 6675.5 5927.8 80*33 232 11.7982 10362.1 8816.2 99.35

163 24.1948 6727*0 5973*1 80*65 233 11*6974 10404.7 8845.4 99.54

164 23*9944 6778.8 6018*7 80*96 234 11*5985 1 0446 *8 8874*3 99.72

165 23*7925 6830*9 6064*4 81*28 235 11*5016 10488.7 8902.9 99.89

166 23.5889 6883.4 6110*2 81.60 236 11.4065 10530.2 8931.2 100.07

167 23.3837 6936*2 6156*3 81*91 237 11*3133 10571*4 8959*3 100*25

168 23.1770 6989.4 6202.5 82.23 238 11.2218 10612.3 8987.0 100.42

169 22.9687 7042.9 6248.8 82.55 239 11.1321 10652.9 9014.5 100.59

170 22.7590 7096*7 6295*3 82*87 240 11.0441 10693*1 9041*7 100*76

171 22.5478 7150.8 6341.9 83.18 241 10.9577 10733.1 9068.6 100.92

172 22.3353 7205.3 6388.7 83.50 242 10.8729 10772.8 9095.3 101.09

173 22.1215 7260*1 6435.6 83*82 243 10.7896 10812.1 9121.7 101.25

174 21.9065 7315.1 6482.5 84.14 244 10.7079 10851.2 9147.9 101.41

175 21.6904 7370.5 6529.6 84.45 245 10*6277 10890.6 9173.9 101.57

176 21.4733 7426.2 6576.8 84.77 246 10.5489 10928.6 9199.6 101.72

177 21.2553 7482.1 6624.0 85.09 247 10.4715 10966.9 9225.1 101.88

178 21.0366 7538.3 6671.3 85.40 248 10.3954 11004.9 9250.4 102.03

179 20.8173 7594.7 6718.6 85.72 249 10.3207 11042.7 9275.5 102.19

180 20.5975 7651 .4 6765.9 86.04 250 10.2473 11080.2 9300.3 102.34

181 20.3774 7708.2 6813.2 86.35 251 10.1751 11117.5 9325.0 102.48

182 20.1571 7765.2 6860,4 86.67 252 10.1042 11154.5 9349.4 102.63

183 19.9370 7822.4 6907.6 86.98 253 10.0345 11191.3 9373.7 102.78

184 19.7170 7879,7 6954.7 87,29 254 9.96598 11227.9 9397.8 102.92

185 19.4975 7937.2 7001.7 87.60 255 9.89856 11264.2 9421.6 103.06

186 19.2785 7994.7 7048.6 87.91 256 9.83225 11300.4 9445,4 103.21

187 19.0604 8052.2 7095.3 88.22 257 9.76702 11336.3 9468.9 103.35

188 18.8433 8109.8 7141.9 88.53 258 9.70284 11372.6 9492-2 1 q3 « 48

189 18.6273 8167.4 7188.2 88.83 259 9.63970 11407.5 9515.4 103*62

190 18.4127 8224.9 7234*3 89«14 260 9.57755 11442-8 9538.4 103.76

191 18.1997 8282.3 7280.2 89.44 261 9.51639 11477.9 9561.3 103.89

192 17.9884 8339.7 7325.8 89.74 262 9.45618 11512.8 9584.0 104.03

193 17.7791 8396.9 7371.1 90*04 263 9.39690 11547.5 9606.5 104.16

194 17.5718 8454.0 7416.1 90.33 264 9.33853 11582.0 9628.9 104.29

195 17.3668 8510.9 7460.7 90.62 265 9.28105 11616.3 9651.1 104.42

196 17.1641 8567.6 7505.0 90.91 266 9.22444 11650.5 9673.2 104.55

197 16.9639 8624.1 7548.9 91.20 267 9.16867 11684.5 9695.2 104.68

198 16.7664 8680.3 7592.4 91.48 268 9.11373 11718.3 9717.0 104.80

199 16.5716 8736.2 7635.6 91 .77 269 9.05959 11751.9 9738.7 104.93

200 16.3796 8791.8 7678.3 92.05 270 9.00625 11785.4 9760.2 105.05

201 16.1905 8847.1 7720.6 92.32 271 8.95367 11818.7 9781.7 105.17

202 16.0044 8902.1 7762.4 92.59 272 8.90185 11851.8 9802.9 105.30

203 15.8214 8956.7 7803.9 92*86 273 8.85076 11884.8 9824.1 105.42

204 15.6414 9010*9 7844.8 93.13 274 8.80039 11917.7 9845.2 105.54

205 15*4645 9064*8 7865*4 93*39 275 8-75072 11950.4 9866*1 105*66

206 15.2908 9118.2 7925.4 93.65 276 8.70175 11982.9 9886.9 105.78

207 15.1202 9171.3 7965.0 93.91 277 8.65344 12015.3 9907.6 105.89

208 14.9528 9224.0 8004.2 94.16 278 8.60579 12047*6 9928.2 106.01

209 14.7885 9276*2 8042*9 94*41 279 8*55879 12079.7 9948*6 106*12

210 14.6273 9328*0 8081.1 94«66 280 8*51241 12111*6 9969*0 106*24

211 14.4693 9379.4 8118.9 94.91 281 8.46665 12143.5 9989.3 106.35

212 14.3144 9430.4 8156.2 95.15 282 8.42149 12175.2 10009.4 1 Q& * 46

213 14.1626 9481.0 8193.1 95.39 283 8.37692 12206.8 10029.5 106.58

214 14.0138 9531.1 8229.6 95.62 284 8.33293 12238.2 10049.5 106.69

215 13.8680 9580*7 8265.6 95.85 285 8.28951 12269.6 10069.3 106.80

216 13*7251 9630*0 8301*1 96*08 286 8.24664 12300*8 10089*1 106.91

217 13.5852 9678.8 8336.2 96.31 287 8.20431 12331.9 10108.8 107.02

218 13.4481 9727.2 8370.9 96.53 288 8.16251 12362.8 10128.3 107.12

219 13.3138 9775.2 8405.2 96.75 289 8.12123 12393.7 10147.8 107.23

220 13.1822 9822.7 6439.1 96.96 290 8.08047 12424.4 10167.2 107.34

221 13.0534 9869.8 8472.6 97.18 291 8.04020 12455.0 10186.6 107.44

222 12.9272 9916.5 8505.7 97.39 292 8*00042 12485.5 10205*8 107*55

223 12.8036 9962*8 8538.3 97.60 293 7*96112 12515.9 10224.9 107.65

224 12.6826 10008.8 8570*6 97.80 294 7*92229 12546.2 10244*0 107.75

225 12.5640 10054.3 8602*6 98.00 295 7*88393 12576.4 10263*0 107.86

226 12 *4478 10099.4 8634*1 98*20 296 7*84601 12606.5 10281*9 107.96

227 12.3339 10144.1 8665.3 98.40 297 7.80855 12636.5 10300.7 108.06

228 12.2224 10188.4 8696.2 98.60 298 7.77151 12666.4 10319.5 108.16

229 12.1131 10232*4 8726.7 98*79 299 7*73490 12696.2 10338*2 108.26

230 12*0061 10276*0 8756.9 98.98 300 7*69872 12725*9 10356*8 108.36

116
200.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. density ENTHALPY INTERNAL ENTROPY

K MOL/UTER J/MOL ENERGY J/MOL-K K MOL/LITER J/MOL ENERGY J/mOL-K

J/MOL J/MOL

91 35.7379 3505.6 2938.5 54.18

92 35.6062 3548.9 2979,7 54.66

93 35.4739 3592.3 3021.0 55.13

94 35.3411 3635.9 3062.4 55.59

95 35.2076 3679,5 3103,9 56.05

96 35.0737 3723.3 3145.5 56.51

97 34.9392 3767.1 3187.1 56.97

98 34.8043 3811.0 3228.8 57.42

99 34.6689 3855.6 3270.5 57.86

100 34.5330 3899.6 3312.2 58.31

101 34.3967 3943.6 3353,9 58.74

102 34.2600 3987,1 3395.6 59.18

103 34.1229 4031.1 3437.2 59.61

1 0 A 33.9853 4075,2 3478.9 60.03

105 33*8474 4119.2 3520.5 60.45

106 33.7090 4163.2 3562*0 60.87

107 33*5702 4207*1 3603*5 61*28

108 33.4311 4251*1 3644*9 61*69

109 33.2915 4294.9 3686.2 62.10

110 33.1515 4338.7 3727.4 62.50

111 33.0111 4382.4 3768.5 62.89

112 32.8702 4426,1 3809.6 63.28

113 32.7290 4469.7 3850.5 63.67

114 32.5873 4513.2 3891.3 64.06

115 32.4451 4556*7 3932*0 64.43

116 32.3025 4600.0 3972.6 64.81

117 32.159A 4643.3 4013.1 65.18

118 32.0159 4686.5 4053.5 65,55

119 31.8718 4729.6 4093.8 65.91

120 31.7273 4772.7 4134.0 66.27

121 31.5822 4815.7 4174.0 66.63

122 31.4366 4858.7 4214.0 66.98

123 31 .2905 4901.6 4253.9 67.33

124 31.1438 4944.5 4293.7 67.68

125 30.9965 4987.3 4333.5 68.03

126 30.8487 5030.2 4373.3 68.37

127 30.7002 5073.1 4413.0 68.71

128 30*5511 5116*0 4452*7 69.04

129 30*4014 5159*0 4492*4 69*38

130 30.2510 5202.1 4532.2 69.71

131 30.0999 5245.3 4572.0 70.04

132 29.9481 5288.6 4612.0 70.37

133 29.7957 5332*2 4652*1 70.70

134 29*6425 5376*0 4692*3 71*03

135 29.4885 5420*6 4732.8 71*36

136 29.3337 5463.9 4773.1 71.68

137 29.1782 5507.9 4813.3 72.00

138 29.0219 5551.8 4853.5 72.32

139 28.8647 5595.8 4893.7 72.64

140 28.7067 5639.7 4933.7 72.95

141 28.5478 5683.6 4973.7 73.27

142 28.3880 5727.4 5013.6 73.58

143 28.2273 5771.4 5053.5 73.89

144 28.0656 5815.5 5093.5 74.19

145 27.9030 5859.8 5133.5 74.50

146 27.7395 5904.4 5173.8 74.81

147 27.5749 5949.1 5214,2 75.12

148 27.4093 5994.1 5254.8 75.42

149 27.2428 6039.3 5295.4 75*73

150 27-0751 6084.6 5336*1 76.04

151 26.9064 6130.5 5377.4 76.34

152 26.7366 6177.1 5419.2 76.65

153 26.5657 6224.0 5461.1 76.96

154 26.3937 6271.0 5503.2 77.27

155 26.2206 6318.2 5545.4 77.57

156 26*0463 6365.7 5587.7 77.88

157 25.8709 6413.4 5630.1 78.18

158 25.6944 6461*4 5672*6 78.49

88.745 36*0321 3408*5 2846*1 53*10 159 25*5166 6509*5 5715*3 78.79

89 35*9991 3419*4 2856*5 53*23 160 25*3377 6557*9 5758*1 79.09

90 35.8688 3462.4 2897.4 53.71

* PHASE CHANGE 117
K

161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

1 89

1 90

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211 212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

200.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY internal entropy

MOL/LITEK J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

25.1577 6606.6 5801.0 79.40 231 13.1325 10159.5 8616.3 97.77

24.9764 6655.5 5844.1 79.70 232 13.0226 10203.0 8646.8 97.96

24.7940 6704.6 5887*3 80.00 233 12.9147 10246.2 8677*0 98.15

24.6104 6754.0 5930*5 80*30 234 12.8087 10289.0 8706.9 98.33

24.4257 b803 • 6 5973*9 80*60 235 12*7045 10331*6 8736.4 98.51

24.2398 6853*5 6017*4 80*91 236 12*6022 10373.8 8765*7 98.69

24.0528 6903.6 6061.0 81.21 237 12.5017 10415.8 8794.8 98.87

23.8647 6953.9 6104.8 81.51 238 12.4030 10457.4 8823.5 99.05

23.6755 7004.5 6148.6 81.81 239 12.3059 10498.8 8852.0 99.22

23.4853 7055.4 6192.5 82.11 240 12.2106 10539.9 8880.2 99.39

23.2941 7106.5 6236.5 82.41 241 12.1169 10580.7 8908.2 99.56

23.1018 7157.8 6280.6 82*71 242 12*0248 10621.2 8935.9 99.73

22.9087 7209.3 6324.7 83.01 243 11.9343 10661.4 8963.3 99.89

22.7147 7261.1 6368.9 83*30 244 1 1.8453 10701.4 8990.5 100.06

22*5199 7313*1 6413*2 83.60 245 11*7578 10741-1 9017*5 100.22

22.3243 7365.3 6457.6 83*90 246 11*6719 10780*5 9044.3 100*38

22.1280 7417.8 6501.9 84.20 247 11.5873 10819.7 9070.8 100.54

21.9311 7470.4 6546.3 84.49 248 11.5042 10858.6 9097,1 100.70

21.7337 7523.2 6590.8 84.79 249 11.4224 10897.3 9123.1 100.85

21.5359 7576.2 6635.2 85.08 250 11.3420 10935.8 9149.0 101.01

21.3377 7629.4 6679.6 85.38 251 11.2628 10974.6 9174.7 101.16

21*1393 7682.7 6724.0 85.67 252 11*1850 11011*9 9200*1 101.31

20.9408 7736.1 6768.4 85.97 253 11.1084 11049.7 9225.3 101.46

20,7422 7789.7 6812.7 86.26 254 11.0331 11087.2 9250.4 101.61

20.5437 7843.4 6857.0 86.55 255 10.9589 11124.5 9275.3 101.75

20.3454 7897.2 6901.1 86.84 256 10.8860 11161.5 9299.9 101.90

20.1474 7951,1 6945.2 87.13 257 10.8141 11198.4 9324.4 102.04

19.9499 8005.0 6989.2 87.42 258 10.7434 11235.0 9348.7 102.19

19.7530 8059.0 7033.1 87.70 259 10.6738 11271.4 9372.8 102.33

19.5567 8113.0 7076.8 87.99 260 10.6052 11307.7 9396.8 102,47

19.3613 8167.0 7120.3 88.27 261 10.5377 11343.7 9420.5 102.60

19.1669 8221.0 7163.7 88.55 262 10*4712 11379.5 9444*2 102.74

18.9735 8275.0 7206.9 88.83 263 10*4057 11415.1 9467*6 102*88

18.7813 8328.9 7249.9 89.11 264 10.3412 11450.6 9490*9 103.01

18.5904 8382*7 7292.6 89.39 265 10.2776 11485.8 9514.0 103.14

18.4010 8436*5 7335*1 89*66 266 10*2150 11520*9 9537*0 103*28

18.2131 8490*1 7377*4 89.94 267 10*1532 11555*8 9559*8 103*41

18.0269 8543.6 7419.4 90.21 268 10.0924 11590.5 9582.5 103.54

17.8424 8597.0 7461.2 90.48 269 10.0325 11625.1 9605.1 103.67

17.6598 8650.1 7502.6 90.74 270 9.97339 11659.4 9627.5 103.79

17.4791 8703.2 7543.7 91.01 271 9.91512 11693.6 9649.7 103.92

17.3004 8756.0 7584.6 91.27 272 9.85767 11727.7 9671.9 104.05

17.1238 8808.6 7625.1 91.53 273 9.80102 11761.5 9693.9 104.17

16.9494 8860*9 7665*3 91.79 274 9.74515 11795.3 9715*7 104.29

16.7772 8913.0 7705*1 92*04 275 9.69004 11828.8 9737*4 104.42

1 6 • 60 73 8964*9 7744*6 92*29 276 9*63569 11862*2 9759*1 104.54

16.4396 9016.5 7783*8 92*54 277 9*58207 11895*5 9780*5 104.66

16.2743 9067*9 7822*6 92*79 278 9.52917 11928.6 9801*9 104.78

16.1115 9118.9 7861.1 93.03 279 9.47697 11961.6 9823.2 104.89

15.9510 9169.6 7899.1 93.28 280 9.42546 11994.4 9844.3 105.01

15.7929 9220.1 7936.9 93.52 281 9,37463 12027,1 9865.3 105.13

15.6374 9270.2 7974.2 93.75 282 9.32446 12059.6 9886.2 105.24

I5.4e42 9320.0 8011.2 93.99 283 9.27493 12092.0 9907.0 105.36

15.3335 9369.5 8047.9 94.22 284 9.22604 12124.3 9927.7 105.47

15.1853 9418.7 8084.1 94.45 285 9.17777 12156.4 9948.3 105.59

15.0395 9467.5 8120*0 94.68 286 9.13012 12188.4 9968.8 105.70

14.8962 9516*0 8155*5 94.90 287 9.08305 12220*3 9989-2 105.81

14.7553 9564*1 8190*7 95*12 288 9.03658 12252*1 10009*5 105*92

14*6168 9612*0 8225*5 95*34 289 8*99068 12283*7 10029.7 106.03

14.4806 9659.4 8260.0 95.56 290 8.94534 12315.2 10049.8 106.14

14.3469 9706.6 8294.1 95.77 291 8.90055 12346.6 10069.8 106.25

14.2155 9753.4 8327.8 95.98 292 8.85631 12377.9 10089.7 106.35

14.0863 9799.8 8361*2 96.19 293 8.81259 12409.1 10109.5 106.46

13.9595 9846*0 8394*2 96.40 294 8.76940 12440*2 10129.2 106.57

13.8349 9891.8 8426.9 96*60 295 8.72672 12471.1 10148.9 106.67

13.7125 9937.2 8459.3 96.80 296 8.68453 12501.9 10168.4 106.78

13.5923 9982.3 8491 .

4

97.00 297 8*64284 12532.7 10187.9 106.88

13.4743 10027.1 8523*1 97.20 298 8.60164 12563.3 10207.3 106.98

13.3583 10071*6 8554.5 97.39 299 8*56090 12593.8 10226.6 107.08

13.2444 10115.7 8585.6 97.58 300 8.52063 12624.2 10245.8 107.19

118
220.00 ATMOSPHERE ISOBAR

TEMP.

K

89.232

90

DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

MOL/LITER J/MOL ENERGY J/MOL-K K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL J/MOL

91 35.8579 3543.4 2921.7 53.98

92 35.7281 3586.5 2962.6 54.45

93 35*5978 3629*7 3003*5 54.92

<54 35.4670 3673.0 3044.5 55.38

95 35.3357 3716.5 3085.6 55.84

96 35.2039 3760.0 3126.8 56.29

97 35.0716 3803.6 3168.0 56.75

98 34.9389 3847.3 3209.2 57.19

99 34.8058 3891.0 3250.5 57.64

100 34.6723 3934,7 3291.8 58.08

101 34.5384 3978.5 3333.1 58.51

102 34.4042 4022.3 3374.4 58.94

103 34.2696 4066.1 3415-6 59.37

104 34.1346 4109.9 3456.8 59.79

105 33.9993 4153.6 3498.0 60.21

106 33.8637 4197.3 3539.1 60.63

107 33.7277 4241.0 3580*1 61.04

108 33.5914 4284.6 3621.0 61.44

109 33.4548 4328.2 3661.9 61.85

110 33*3178 4371*7 3702*6 62*24

111 33.1805 4415.1 3743.3 62.64

112 33.0428 4458.5 3783*8 63.02

113 32.9047 4501 .7 3824.3 63.41

114 32.7664 4544.9 3864.6 63.79

115 32.6276 4588.0 3904.8 64.17

116 32*4885 4631*0 3944*8 64.54

117 32.3490 4673.9 3984.8 64.91

118 32.2091 4716.7 4024,6 65.27

119 32.0688 4759.4 4064.3 65.63

120 31.9281 4802.1 4103.9 65,99

121 31.7870 4844.7 4143.4 66.34

122 31.6455 4887.2 4182.7 66.69

123 31.5035 4929.6 4222.0 67.04

124 31.3611 4972.6 4261.2 67.38

125 31*2182 5014.4 4300.4 67.72

126 31*0749 5056*8 4339*4 68 *06

127 30*9310 5099.2 4378.5 68.39

128 30.7867 5141*5 4417*5 68.73

129 30.6418 5184.0 4456.5 69.06

130 30*4965 5226*5 4495*5 69*38

131 30.3505 5269.1 4534.6 69.71

132 30.2041 5311.9 4573.8 70.04

133 30.0570 5354,e 4613.1 70.36

134 29,9094 5397.9 4652.6 70.68

135 29.7612 5441.2 4692.2 71.01

136 29*6124 5484*4 4731*7 71*32

137 29.4629 5527.6 4771.0 71.64

138 29,3128 5570.8 4810.3 71.96

139 29.1621 5614.0 4849.6 72.27

140 29.0107 5657.1 4888.7 72.58

141 28.8586 5700,1 4927.7 72.88

142 28.7058 5743,1 4966.6 73.19

143 28.5523 5786.2 5005.5 73.49

144 28.3981 5829.4 5044.4 73.79

145 28.2432 5872.7 5083.4 74.09

146 28.0875 5916.2 5122-5 74.39

147 27.9310 5959.9 5161.8 74.69

148 27.7738 6003.9 5201.2 74.99

149 27.6157 6047.9 5240.6 75.29

150 27.4569 6092.1 5280.2 75.59

151 27.2973 6136.8 5320.1 75.89

152 27.1368 6182.1 5360.7 76.19

153 26.9755 6227.7 5401*3 76.49

154 26.8134 6273.4 5442*0 76.79

155 26*6505 6319.2 5482*8 77.08

156 26.4867 6365.3 5523.6 77.38

157 26.3220 6411.5 5564.6 77.67

158 26.1565 6457.9 5605.6 77.97

159 25.9901 6504.5 5646.8 78.26

.0856 3467 ,

6

2849.9 53.14 1 6o 25.8228 6551.3 5688.0 78.56

.9869 3500.5 2881.0 53.50

PHASE CHANGE
K

161 162

163

164

165

166

167

168

169

170

171 172

173

1 74 175

176

177

178

179

180

181

182

183

184

185

186

187

188

189

190

191

192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

220.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

25.6547 6598.2 5729.3 78.85 231 14.2574 10025.2 8461.7 96.55

25.4857 6045.4 5770.7 79.14 232 14.1434 10068.9 8492.7 96.74

25.3159 6692.7 5812.1 79.43 233 14.0313 10112.2 8523.5 96.93

25.1452 6740.2 5853*7 79.72 234 13.9209 10155*3 8553.9 97.11

24.9737 6787.9 5895.3 80.01 235 13.8123 10198.1 8584.1 97.29

24.8013 6835*8 5937*0 80*30 236 13.7054 10240-6 8614.1 97.48

24.6282 6883.9 5978.7 80.59 237 13.6001 10282.8 8643.7 97.65

24.4542 6932.1 6020.5 80.88 238 13.4965 10324.8 8673.2 97.83

24.2795 6980.6 6062.4 81.17 239 13.3946 10366,6 8702.3 98.01

24.1040 7029.2 6104.4 81.45 240 13.2942 10408.1 8731.2 98.18

23.9277 7078,0 6146.4 81.74 241 13.1955 10449.3 8759.9 98.35

23.7508 7127.0 6188.4 82.03 242 13.0982 10490.2 8788.3 98.52

23.5731 7176.2 6230.5 82.31 243 13.0025 10530.9 8816.5 98,69

23,3949 7225.5 6272.6 82.59 244 12.9083 10571 .4 8844.5 98.85

23.2160 7275.0 6314.8 82.88 245 12.8156 10611.6 8872.2 99.02

23.0366 7324.7 6357.0 83.16 246 12.7243 10651.6 8899.7 99.18

22.8567 7374.5 6399.2 83.44 247 12,6344 10691.3 8926.9 99.34

22.6763 7424.5 6441.5 83.73 248 12.5459 10730.8 8954.0 99.50

22,4955 7474.7 6483.7 84,01 249 12.4588 10770.1 8980.8 99.66

22.3143 7525.0 6526,0 84.29 250 12,3730 10809.1 9007.5 99.82

22.1329 7575.4 6568.2 84.57 251 12.2885 10847.9 9033.9 99.97

21.9512 7625.9 6610*4 84.84 252 12.2053 10886.5 9060.1 100.12

21.7694 7676.6 6652*6 85.12 253 12-1234 10924.9 9086*1 100.28

21.5874 7727.4 6694.7 85.40 254 12.0426 10963.6 9111.9 100.43

21.4055 7778.2 6736.8 85.67 255 11.9631 11000*9 9137.5 100.58

21.2236 7829.2 6778.9 85*95 256 1 1.8848 11038.7 9163*0 100.72

21.0419 7880.2 6820.8 86.22 257 11.8076 11076.2 9188.2 100.87

20.8604 7931.4 6862.7 86.50 258 11.7316 11113.5 9213.3 101.02

20.6792 7982.5 6904.5 86.77 259 11,6567 11150.6 9238.2 101.16

20.4984 8033.7 6946.2 87.04 260 11.5829 11187.5 9262,9 101.30

20.3180 8085.0 6987.8 87.31 261 11.5101 11224.2 9287.4 101.44

20.1383 8136.2 7029.3 87.57 262 11.4384 11260.7 9311.8 101.58

19.9591 8187.5 7070*6 87*84 263 11*3677 11297*6 9336.0 101*72

19.7808 8238.7 7111.8 88*10 264 11.2981 11333.1 9360.0 101*86

19.6032 8290*0 7152*8 88.37 265 11.2294 11369.1 9383.9 101*99

19.4266 8341.2 7193.7 88.63 266 11.1617 11404.8 9407.6 102.13

19.2509 8392.3 7234.3 88.89 267 11.0949 11440.4 9431.2 102.26

19.0764 8443.4 7274.8 89.15 268 11.0291 11475.8 9454,6 102.39

18.9030 8494.4 7315.1 89.41 269 10.9641 11511.1 9477.9 102.52

18.7308 8545.3 7355.2 89.66 270 10*9001 11546.1 9501.0 102.65

18.5600 8596.1 7395.0 89.91 271 10.8369 11581.6 9524.0 102.78

18.3905 8646.8 7434.7 90.17 272 10.7746 11615.8 9546.8 102.91

18.2225 8697.4 7474*0 90 .42 273 10*7131 11650.4 9569.5 103*04

18.0560 8747.8 7513.2 90.66 274 10.6525 11684.8 9592.1 103.16

17.8911 8798.1 7552.1 90.91 275 10.5926 11719.0 9614.5 103.29

17.7278 8848.2 7590.7 91.15 276 10.5336 11753.1 9636.9 103.41

17.5662 8898.1 7629.1 91.39 277 10.4753 11787.1 9659.0 103.54

17.4063 8947.8 7667.1 91.63 278 10.4178 11820.9 9681.1 103.66

17.2482 8997.4 7704.9 91.87 279 10.3610 11854.5 9703.0 103.78

17.0919 9046.7 7742.5 92.11 280 10.3050 11888.0 9724.8 103.90

16.9375 9095.8 7779.7 92.34 281 10.2497 11921.4 9746.5 104.02

16.7850 9144.8 7816.7 92.57 282 10*1950 11954.6 9768.1 104.14

16.6343 9193.4 7853.3 92*80 283 10.1411 11987*7 9789.5 104.25

16.4856 9241.9 7889.7 93.03 284 10.0878 12020.7 9810.9 1Q4.37

16.3388 9290.1 7925.7 93.25 285 10.0352 12053.5 9832.1 104,48

16.1940 9338.0 7961.5 93.48 286 9.98334 12086.2 9853.2 104.60

16.0512 9365.7 7996.9 93.70 287 9.93203 12118.7 9874.3 104.71

15.9104 9433.2 8032.1 93.91 288 9.88135 12151.2 9895.2 104.82

15.7715 9480.3 8066.9 94.13 289 9.83128 12183.5 9916.0 1Q4.94

15.6346 9527.3 8101.4 94.34 290 9.78181 12215.6 9936.7 105.05

15.4997 9573.9 8135.7 94.56 291 9.73294 12247.7 9957.3 105.16

15.3668 9620.3 8169.6 94.76 292 9.68465 12279.6 9977*8 105.27

15.2358 9666 .4 8203.2 94.97 293 9.63692 12311.5 9998.3 105.38

15.1068 9712.2 8236.6 95.18 294 9.58976 12343.2 10018.6 105.48

14.9798 9757.8 8269.6 95.38 295 9.54314 12374.7 10038.8 105.59

14.8546 9803.0 8302.4 95.58 296 9.49707 12406.2 10059.0 105.70

14*7314 9848-0 8334.8 95*78 297 9*45152 12437*6 10079*0 105*80

14.6101 9892 .

7

8367.0 95.98 298 9.40650 12468.8 10099.0 105.91

14.4907 9937*2 8398.8 96*17 299 9.36199 12500*0 10118.

9

106.01

14.3731 9981.4 8430.4 96.36 300 9.31797 12531*6 10138.6 106*12

120
240.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

* 89.717 36.1380 3526.7 2853.8 53.17

90 36.1021 3538.8 2865*2 53.30

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/L ITER J/MOL ENERGY

J/MOL

J/MOL-K

91 35.9748 3581.5 2905.5 53.78

92 35.8469 3624.3 2945.9 54.24

93 35,7185 3667.3 2986.5 54.71

94 35.5896 3710.4 3027,1 55.17

95 35,4602 3753.7 3067.9 55.63

96 35.3304 3797.0 3108.6 56.08

97 35.2002 3840.4 3149,5 56.53

98 35.0696 3883.8 3190.4 56.98

99 34.9387 3927.3 3231*3 57*42

100 34.8074 3970.8 3272.2 57.85

101 34.6758 4014.4 3313.1 58.29

102 34.5438 4057.9 3353.9 58.72

103 34.4116 4101*5 3394.8 59.14

104 34*2791 4145*0 3435*6 59.56

105 34.1463 4188.5 3476*3 59.98

106 34.0132 4232.0 3517.0 60.39

107 33.8798 4275.4 3557.6 60,80

108 33,7461 4318.7 3598.1 61.20

109 33.6122 4362.0 3638.5 61.60

110 33*4780 4405.3 3678.8 62.00

111 33.3435 4448.4 3719.1 62.39

112 33.2087 4491 .4 3759.1 62.77

113 33.0737 4534.4 3799.1 63.15

114 32.9383 4577.3 3839.0 63.53

115 32.8027 4620.6 3878.7 63.91

116 32*6668 4662*7 3918*2 64*27

117 32*5306 4705*3 3957-7 64*64

118 32*3940 4747*7 3997*0 65*00

119 32*2571 4790*1 4036*2 65*36

120 32*1200 4832*4 4075*3 65*71

121 31.9824 4874.6 4114.2 66.06

122 31.8446 4916.7 4153.0 66.41

123 31.7064 4958.8 4181.8 66.75

124 31 .5678 5000.7 4230.4 67.09

125 31 .4289 5042.7 4268.9 67.43

126 31 .2896 5084.6 4307.4 67.76

127 31.1499 5126.5 4345.8 68.10

128 31.0098 5168.4 4384*2 68.42

129 30*8693 5210.4 4422.6 68.75

130 30.7284 5252.4 4461.0 69.07

131 30.5870 5294.5 4499.4 69.40

132 30.4452 5336.7 4537.9 69.72

133 30*3030 5379.1 4576.5 70.04

134 30*1603 5421.6 4615.3 70.36

135 30.0171 5464.4 4654.2 70.67

136 29.8735 5507.0 4692.9 70.99

137 29.7294 5549.5 4731.5 71.30

138 29.5847 5592.0 4770,0 71.61

139 29.4396 5634.5 4808.5 71.92

140 29.2939 5676.9 4846.8 72.22

141 29.1477 5719.2 4884.9 72.52

142 29.0009 5761.5 4923.0 72.82

143 28*8536 5803.8 4961*0 73*12

144 28*7058 5846*2 4999*0 73*42

145 28.5573 5888.7 5037.1 73.71

146 28.4083 5931-4 5075.3 74.01

147 28-2587 5974*2 5113*6 74.30

148 28-1085 6017-2 5152*1 74.59

149 27.9577 6060.3 5190.5 74.89

150 27.8062 6103.6 5229.0 75.18

151 27.6542 6147.3 5267.9 75.47

152 27.5015 6191.6 5307 .3 75.76

153 27*3482 6236*1 5346.8 76.06

154 27*1942 6280*7 5386*4 76*35

155 27*0396 6325.4 5426* 0 76*64

156 26.8844 6370.3 5465.7 76.92

157 26.7285 6415.3 5505.5 77.21

158 26.5720 6460.5 5545.3 77.50

159 26.4148 6505.8 5585.1 77.78

160 26.2570 6551.2 56?5 .

1

78.07

* PHASE CHANGE

121
240.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL Entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

j/mol-k

161 26.0985 6596.9 5665.1 78.35 231 15.2768 9913.9 8322.0 95.48

162 25.9394 6642.6 5705.1 78.64 232 15.1611 9957.3 8353.3 95.66

163 25.7797 6688.5 5745.2 78.92 233 15.0471 10000.5 8384.3 95.85

164 25.6193 6734,5 5785.3 79.20 234 14.9346 10043.4 8415.1 96,03

165 25,4583 6780.7 5825.5 79.48 235 14.8237 10086.1 8445.6 96.22

166 25.2967 6827.1 5865.7 79.76 236 14.7144 10120,6 8475.9 96.40

167 25.1345 6873.5 5906.0 80.04 237 14.6065 10170.8 8505.9 96.58

168 24.9717 6920-2 5946.3 80*32 238 14.5002 10212.9 8535.7 96.75

169 24.8083 6966.9 5986.7 80.60 239 14.3954 10254.6 8565.3 96.93

170 24.6444 7013.9 6027.1 80.87 240 14.2921 10296.2 8594.7 97.10

171 24.4799 7060.9 6067.5 81.15 241 14.1902 10337.5 8623.8 97.27

172 24.3149 7108.1 6107.9 81 .43 242 14.0897 10378.6 8652.6 97.44

173 24.1495 7155.4 6148.4 81.70 243 13.9907 10419.5 8681.3 97.61

174 23.9835 7202.9 6188.9 81.97 244 13.8931 10460,2 8709.7 97.78

175 23.8171 7250.5 6229.4 82.25 245 13.7969 10500.6 8738,0 97.94

176 23.6503 7298.2 6269.9 82.52 246 13.7020 10540.8 8766.0 98.11

177 23.4832 7346.1 6310.5 82.79 247 13.6085 10580.8 8793.8 98.27

178 23.3156 7394.0 6351.0 83.06 248 13.5163 10620.6 8821.4 98.43

179 23.1478 7442.1 6391.5 83.33 249 13.4254 10660.1 8848.7 98.59

1 80 22.9797 7490.3 6432.1 83.60 250 13.3358 10699.5 8875.9 98.75

181 22.8114 7538.6 6472.6 83.66 251 13.2474 10738.6 8902.9 98.90

182 22.6429 7587.0 6513.0 84.13 252 13.1603 10777.5 8929.7 99.06

183 22.4743 7635.5 6553*5 84.40 253 13*0744 10816.3 8956.2 99.21

184 22.3056 7684.1 6593.9 84.66 254 12.9897 10854.8 8982.6 99.36

185 22,1369 7732.8 6634.3 84.93 255 12.9062 10893.1 9008,8 99.51

186 21.9681 7781.6 6674.6 85.19 256 12.8238 10931.2 9034.9 99.66

187 21.7995 7830.4 6714.8 85.45 257 12.7426 10969.1 9060.7 99.81

188 21.6310 7879.3 6755.0 85.71 258 12.6625 11006.9 9086.4 99.96

189 21.4626 7928.2 6795.2 85.97 259 12*5835 11044.4 9111*8 100.10

190 21.2945 7977.2 6835.2 86.23 260 12*5056 11081.8 9137.1 100.25

191 21.1268 8026.2 6875.2 86.49 261 12.4287 11118.9 9162.3 100.39

192 20.9594 8075.3 6915.0 86.74 262 12.3529 11155.9 9187.2 100.53

193 20.7924 8124.3 6954.8 87.00 263 12.2781 11192.7 9212.1 100.67

194 20.6259 8173.4 6994.4 87.25 264 12.2043 11229.3 9236.7 100.81

195 20.4600 8222.5 7033.9 87.50 265 12.1315 11265.8 9261.2 100.95

196 20.2947 8271.6 7073.3 87.75 266 12.0597 11302.0 9285.5 101.08

197 20.1301 8320.6 7112.5 88.00 267 11.9888 11338.1 9309.7 101,22

198 19.9662 8369.6 7151.6 88.25 268 11.9189 11374.0 9333.7 161.35

199 19.8032 8418.6 7190.6 88.50 269 11.8499 11409.8 9357.6 101.49

200 19.6410 8467.5 7229.4 88.74 270 11.7818 11445.4 9381.3 101.62

201 19.4797 8516.4 7268.0 88.99 271 11.7146 11480.8 9404.9 101.75

202 19*3195 8565*2 7306*4 89*23 272 11*6482 11516.6 9420-3 101-88

203 19.1602 8613*9 7344.7 89*47 273 11-5827 11551-1 9451-6 102-01

204 19.0021 8662.5 7382.7 89.71 274 11-5181 11586.1 9474.7 102-14

205 18.8451 8711.0 7420.6 89.95 275 11.4543 11620.9 9497.8 102.26

206 18.6893 8759.4 7458.2 90.18 276 11.3913 11655.5 9520.7 102.39

207 18.5348 8807.7 7495.7 90.42 277 11.3290 11690.0 9543.4 102.51

208 18.3815 8855,9 7532.9 90.65 278 11.2676 11724.3 9566.0 102.64

209 18.2296 8904.0 7569.9 90.88 279 11.2069 11758.5 9588.6 102,76

210 18.0791 8951.8 7606.7 91.11 280 11.1470 11792.6 9610.9 102.08

211 17.9299 8999.6 7643.3 91.33 281 11.0878 11826.5 9633.2 103.00

212 17,7823 9047.2 7679.6 91.56 282 11.0294 11860.2 9655.3 103.12

213 17.6361 9094.6 7715.7 91.78 283 10.9716 11893.9 9677.4 103.24

214 17.4914 9141.8 7751.5 92.00 284 10.9146 11927.4 9699.3 103,36

215 17.3482 9188.9 7787.1 92.22 285 10.8582 11960.7 9721.1 103.48

216 17.2066 9235.8 7822.5 92.44 286 10.8025 11993.9 9742.8 103.59

217 17.0665 9282.5 7857.6 92.66 287 10.7475 12027.0 9764.3 103.71

218 16.9281 9329.0 7892.4 92.87 288 10.6932 12060.0 9785.8 103.82

219 16.7913 9375.3 7927.0 93.09 289 10.6394 12092.9 9807.2 103.94

220 16.6561 9421.4 7961.3 93.29 290 10.5863 12125.6 9828.4 104.05

221 16.5225 9467.2 7995.4 93.50 291 10.5339 12158.2 9849.6 104.16

222 16.3905 9512.9 8029.2 93.71 292 10*4820 12190.6 9870.6 104.27

223 16.2602 9558.4 8062.8 93.91 293 10*4307 12223.0 9891 .6 104.39

224 16-1315 9603-6 8096-1 94-11 294 10*3800 12255-2 9912-4 104-50

225 16.0045 9648.6 8129.1 94.31 295 10.3299 12287.4 9933.2 104.60

226 15.8791 9693.4 8161.9 94.51 296 10.2804 12319.4 9953.8 104.71

227 15.7554 9738.0 8194.4 94.71 297 10.2314 12351.3 9974.4 104.82

228 15.6333 9782.3 8226.7 94.90 298 10.1830 12383.6 9994,9 104.93

229 15.5129 9826.4 8258.7 95.10 299 10.1351 12414.7 10015.3 105.03

230 15.3940 9870.3 8290.5 95.29 300 10.0877 12446.3 10035.6 105.14

122
260.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K

temp. DENSITY ENTHALPY INTFRNAL ENTROPY

K MOL/LITER J/MOL ENFRGY

J/MOL

J/MOL-K

90.201 36.1892 3585.7 2857.7 53.20

91 36.0888 3619.7 2889.7 53.58

92 35.9626 3662.4 2929.8 54.0*

93 35.8360 3705.2 2970.0 54.51

94 35*7089 3748.1 3010*3 54.97

95 35.5814 3791*1 3050*7 55.42

96 35.4535 3834.2 3091.1 55.87

97 350252 3877.4 3131*6 56.32

98 35.1966 3920.6 3172*1 56.76

99 35*0677 3963*9 3212*6 57.20

100 34.9385 4007.? 3253.2 57.64

101 34.8090 4050.5 3293.7 58.07

102 34.6793 4093.9 3334.2 58.50

103 34.5493 4137*2 3374.7 58.92

104 34.4190 4180*5 3415*1 59.34

105 34.2885 4223.8 3455*5 59.75

106 34.1578 4267.0 3495.7 60.16

107 34.0269 4310.2 3535*9 60.57

108 33-8957 4353.3 3576*1 60.97

109 33.7643 4396*4 3616*1 61*36

110 33-6326 4439.3 3656*0 61.76

111 33.5008 4482.2 3695.8 62.14

112 33.3687 4525.6 3735*4 62*53

113 33.2364 4567.6 3775.0 62*91

114 33*1039 4610*2 3814.4 63*28

115 32*9711 4652*7 3853.7 63*65

116 32*8381 4695*1 3892*8 64*02

117 32*7049 4737*3 3931*8 64*38

118 32*5714 4779*5 3970*6 64.74

119 32*4377 4821*5 4009*4 65*10

120 32*3037 4863*5 4047*9 65*45

121 32.1695 4905.3 4086.4 65,80

122 32.0350 4947.1 4124.7 66.14

123 31.9002 4988.8 4162*9 66.48

124 31*7651 5030*4 4201*0 66.82

125 31*6298 5072*0 4239*1 67-15

126 31*4941 5113*5 4277*0 67*48

127 31.3582 5155*0 4314.9 67*81

128 31.2219 5196.5 4352.7 68.13

129 31.0853 5238.0 4390.5 68.46

130 30.9484 5279.6 4428.3 68.78

131 30.8111 5321.2 4466.2 69.10

132 30*6735 5362*9 4504*

1

69*41

133 30*5356 5404.8 4542.1 69.73

134 30*3973 5446.9 4580.2 70.05

135 30*2586 5489.1 4618.4 70.36

136 30.1195 5531.2 4656.5 70.67

137 29.9801 5573.2 4694.4 70.98

138 29.8403 5615.1 4732.3 71.28

139 29.7000 5657.0 4770,0 71.59

140 29.5594 5698.8 4807.6 71.89

141 29.4183 5740.5 4845.0 72.18

142 29*2768 5782*1 4882*3 72*48

143 29*1349 5823*8 4919.5 72.77

144 28*9925 5865*5 4956*8 73*06

145 28.8497 5907.3 4994.1 73.35

146 28.7065 5949.2 5031.5 73.64

147 28.5628 5991.3 5069.0 73.93

148 28.4186 6033.6 5106.5 74.22

149 28.2739 6075.9 5144.1 74.51

150 28*1288 6118.3 5181*7 74.79

151 27.9832 6161.2 5219.7 75.08

152 27.8371 6204.6 5258.2 75.37

153 27.6906 6248.2 5296.8 75.65

154 27.5435 6291.9 5335.4 75.94

155 27.3960 6335.7 5374.1 76.22

156 27.2480 6379.6 5412.8 76.50

157 27.0994 6423.7 5451.5 76.79

158 26.9504 6467.8 5490.3 77.07

159 26.8009 6512.1 5529.1 77.35

160 26.6509 6556.5 5567.9 77.62

* PHASE CHANGE 123
260.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP,. DENSITY FNTHALPY INTERNAL ENTROPY

K mol/liteR J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 26.5005 6601.0 5606.8 77.90 231 16.1978 9822.5 81Q6.0 94.52

162 26.3495 6645.6 5645.7 78.18 232 16.0822 9865.4 8227.3 94.71

163 26.1981 6690.3 5684.7 78.45 233 15.9679 9908.2 8258.4 94.89

164 26*0462 6735*2 5723*7 78*73 234 15*8550 9950*8 8289*2 95*08

165 25.8938 6780*1 5762*7 79.00 235 15-7435 9993*3 8319*9 95.26

166 25.7410 6825.2 5801.7 79.27 236 15.6334 10035.5 8350.3 95.44

1 67 25.5877 6870.4 5840,8 79.54 237 15.5246 10077.5 8380.5 95.61

168 25.43*0 6915.7 5879.9 79.81 238 15.4172 10119.3 8410.5 95.79

169 25.2799 6961-1 5919.0 80.08 239 15.3111 10160.9 8440.2 95.96

170 25.1254 7006.7 5958.1 80*35 240 15.2064 10202.3 8469.8 96.14

171 24.9704 7052.3 5997.2 80.62 241 15.1030 10243.5 8499.1 96.31

172 24.8151 7098.0 6036.4 80.89 242 15.0009 10284.5 8528*3 96.48

173 24.6595 7143.9 6075*6 81*15 243 14.9001 10325.3 8557*2 96.65

174 24.5035 7189.9 6114.7 81.42 244 14.8006 10366.0 8586.0 96.81

175 24.3471 7235.9 6153.9 81.68 245 14.7023 10406.4 8614.5 96.98

176 24.1905 7282.1 6193.0 81.94 246 14.6053 10446.6 8642.8 97.14

177 24.0336 7328.4 6232.2 82.21 247 14.5096 10486.6 8670.9 97.31

178 23.8765 7374.8 6271.4 82.47 248 14.4151 10526.5 8698.9 97.47

179 23.7191 7421.2 6310.5 82.73 249 14.3218 10566.1 8726.6 97.63

180 23.5615 7467,8 6349.6 82,99 250 14.2297 10605.6 8754.1 97.78

181 23.4038 7514.4 6388.7 83.25 251 14.1388 10644.8 8781.5 97.94

182 23.2460 7561.1 6427.8 83.50 252 14.0490 10683.9 8808.7 98.10

183 23.0880 7607,9 6466.8 83.76 253 13.9605 10722.8 8835.6 98.25

1 84 22.9300 7654.8 6505.8 84.02 254 13.8730 10761.5 8862,4 98,40

1 85 22.7720 7701.7 6544.8 84.27 255 13.7867 10800,0 8889.1 98.55

186 22.6140 7748.7 6583.7 84.52 256 13.7015 10838.3 8915,5 98.70

187 22.4560 7795.7 6622.6 84.78 257 13.6174 10876.4 8941.8 98.85

1 88 22.2981 7842.9 666 1.4 85.03 258 13.5343 10914.4 8967.9 99.00

189 22.1404 7890.0 6700.1 85.28 259 13.4523 10952.2 8993.8 99.15

190 21.9829 7937.2 6738.8 85.53 260 13.3714 10989.8 9019.5 99.29

191 21.8256 7984.4 6777.4 85.77 261 13.2915 11027.2 9045.1 99.43

192 21.6685 8031.7 6815.9 86.02 262 13.2126 11064.5 9070.6 99.58

193 21.5118 8079.0 6854.3 86.27 263 13.1347 11101.6 9095.8 99.72

194 21.3554 8126.3 6892.6 86.51 264 13.0578 11138.5 9120.9 99.86

195 21.1995 8173.6 6930.8 86.75 265 12.9819 11175.3 9145.9 100.00

196 21.0440 8220.8 6968.9 87.00 266 12.9069 11211.8 9170.7 100.14

197 20.8890 8268.1 7006.9 87.24 267 12.8328 11248.3 9195.3 100.27

198 20.7345 8315.4 7044.8 87.48 268 12.7597 11284.5 9219.8 100.41

199 20.5806 8362,7 7082.6 87.71 269 12.6875 11320.6 9244.2 100.54

200 20.4?74 8409.9 7120.2 87.95 270 12.6162 11356.6 9268.4 100.68

201 20.2749 3457.1 7157.7 88.19 271 12.5457 11392.3 9292.4 100.81

202 20.1231 8504.2 7195.0 88.42 272 12.4762 11428.0 9316.3 100.94

203 19.9721 8551.3 7232.2 88.65 273 12.4074 11463*4 9340*1 101*07

204 19.8219 8598.4 7269.3 88.88 274 12*3395 11498.8 9363.7 101.20

205 19.6726 8645-3 7306*2 89*11 275 12*2725 11533*9 9387*2 101*33

206 19.52*2 8692.2 7342*9 89.34 276 12.2062 11569.0 9410*6 101*45

207 19.3767 8739.0 7379-4 89.57 277 12*1408 11603.8 9433*9 101*58

208 19*2303 8785*8 7415*8 89*79 278 12*0761 11638*6 9457*0 101*70

209 19.0848 8832.4 7452-0 90*02 279 12.0122 11673.2 9480*0 101*83

210 18*9404 8878*9 7488*0 90*24 280 11*9491 11707*6 9502*8 101*95

211 18.7972 8925.3 7523.8 90.46 281 11.8867 11741.9 9525.6 102.07

212 18.6550 8971.6 7559.4 90.68 282 11.8250 11776.1 9548.2 102.20

213 18.5140 9017.8 7594.8 90.90 283 11.7641 11810.2 9570.7 102.32

214 18.3742 9063.9 7630.0 91.11 284 11.7038 11844.1 9593.1 102.44

215 18.2356 9109.8 7665.1 91.33 285 11.6443 11877.8 9615.4 102.55

216 18.0982 9155.6 7699.9 91.54 286 11.5855 11911.5 9637.5 102.67

217 17.9621 9201.2 7734.5 91.75 287 11.5273 11945.6 9659.6 162.79

218 17.8273 9246.7 7768.9 91.96 288 11.4698 11978.4 9681.5 102.91

219 17.6938 9292.0 7803.1 92.17 289 11.4129 12011.7 9703.3 103.02

220 17.5616 9337.2 7837.0 92.37 290 11.3567 12044.8 9725.0 103.14

221 17.4308 9382.2 7870.8 92.58 291 11.3012 12077.8 9746.7 103.25

222 17.3013 9427.0 7904.3 92.78 292 11.2462 12110.7 9768.2 103.36

223 17.1731 9471.7 7937.6 92.98 293 11.1919 12143.5 9789.6 103.47

224 17.0464 9516.2 7970.7 93.18 294 11.1381 12176.2 9810.9 103.59

225 16.9210 9560.5 8003.5 93.37 295 11.0850 12208.7 9832.1 103.70

226 16.7970 9604.6 8036.2 93.57 296 11.0324 12241.2 9853.2 103.81

227 16.6743 9648.6 8068.6 93.76 297 10.9805 12273.5 9874.2 103.91

228 16.5531 9692.3 8100.8 93.96 298 10.9290 12305.7 9895.2 104.02

229 16.4333 9735.9 8132.7 94.15 299 10.8782 12337.8 9916.0 104,13

230 16.3149 9779.3 8164.5 94.34 300 10.8278 12369.8 9936.7 104.24

124
280.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/iiteh J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

90,683 36.2395 3644.7 2861.8 53.24

91 36.2001 3658.1 2874.4 53.38

92 36.0756 3700.6 2914.1 53.85

93 35.9506 3743.2 2954.0 54.31

94 35.8252 3785.9 2994.0 54.76

95 35.6995 3828.7 3034.0 55.22

96 35.5734 3871.6 3074.1 55.67

97 35.4470 3914.6 3114.2 56.11

98 35.3203 3957.7 3154.4 56.55

99 35.1933 4000.8 3194.6 56.99

100 35.0661 4043.9 3234.8 57.43

101 34.9386 4087.0 3275.0 57.85

102 34.8109 4130.1 3315.1 58.28

103 34.6829 4173.3 3355.2 58.70

104 34.5548 4216.4 3395.3 59.12

105 34,4265 4259.4 3435.3 59,53

106 34.2980 4302.4 3475.2 59.94

107 34.1693 4345.4 3515.1 60.34

108 34*0404 4388*3 3554*8 60*74

109 33.9114 4431.1 3594.5 61.13

110 33*7822 4473.8 3634.0 61.52

111 33.6528 4516.5 3673.4 61.91

112 33.5232 4559.0 3712.7 62.29

113 33.3935 4601.4 3751.8 62.67

114 33.2635 4643 .

7

3790.8 63.04

11S 33.1334 4686.0 3829.7 63.41

116 33.0032 4728.1 3868.4 63.77

117 32.8727 4770.6 3907.0 64.13

118 32.7420 4811*9 3945.4 64.49

119 32*6112 4853.7 3983*7 64.84

120 32*4802 4895.3 4021*8 65.19

121 32.3489 4936.9 4059.8 65.54

122 32.2175 4978.3 4097.7 65.88

123 32.0858 5019.7 4135.4 66.22

124 31.9540 5061.0 4173.1 66.55

125 31.8219 5102,2 4210.6 66.88

126 31.6896 5143.4 4248.1 67.21

127 31.5570 5184.5 4285.4 67.53

128 31.4242 5225.6 4322.7 67.86

129 31.2912 5266.7 4360.0 68.18

130 31.1579 5307.9 4397.3 68.49

131 31.0243 5349.1 4434.6 68.81

132 30.8905 5390.4 4472.0 69.12

133 30.7564 5431.9 4509.4 69.44

134 30.6220 5473.5 4547.0 69.75

135 30.4873 5515.3 4584.6 70.06

136 30.3524 5556.8 4622*1 70.37

137 30*2171 5598.4 4659.4 70.67

138 30.0816 5639.8 4696.7 70.97

139 29.9457 5681.2 4733.8 71.27

140 29*8095 5722.5 4770.7 71.57

141 29.6730 5763.6 4807.5 71.86

142 29.5361 5804.7 4844*1 72.15

143 29.3990 5845.-8 4880.7 72.44

144 29*2614 5886*9 4917*3 72*73

145 29.1236 5928.1 4953.9 73*01

146 28*9854 5969.4 4990*6 73*30

147 28.8468 6010*8 5027*3 73*58

148 28*7079 6052*4 5064*2 73*87

149 28.5686 6094.1 5100.9 74.15

150 28.4290 6135,8 5137.8 74,43

151 28.2890 6178.0 5175.0 74.72

152 28.1486 6220.7 5212.8 75.00

153 28.0078 6263.5 5250*5 75.28

154 27.8667 6306.4 5288.3 75.56

155 27.7252 6349.4 5326.1 75.84

156 27.5834 6392.5 5363.9 76.11

157 27.4411 6435.7 5401.8 76.39

158 27.2985 6479.0 5439.7 76.66

159 27.1555 6522.4 5477.6 76.94

160 27.0122 6565.9 5515.5 77.21

* PHASE CHANGE 125
K

161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

18 ] 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

280.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

26.8685 6609.4 5553.5 77.48 231 17.0304 9748.0 8082.1 93.67

26.7244 6653.1 5591.5 77.75 232 16.9158 9790-5 8113.3 93.86

26.5800 6696.9 5629.5 78.02 233 16*8025 9832.8 8144.2 Q4 .04

26.4352 6740*7 5667.5 78.29 234 16*6904 9874.9 8175.0 94.22

26.2901 6784.7 5705*5 78.56 235 16-5794 9916*9 8205*6 94*40

26.1446 6828.7 5743.5 78.82 236 16.4697 9958.7 8236.0 94.58

25.9988 6872.8 5781.6 79.09 237 16.3612 10000.3 8266.2 9*. 75 25.8527 6917.1 5819.6 79.35 238 16.2538 10041.8 8296.3 9A.93

25.7063 6961.4 5857.7 79.62 239 16.1477 10083.1 8326.1 95.10

25*5596 7005.8 5895*8 79.88 240 16*0427 10124.2 8355.7 95.27

25.4126 7050.3 5933.8 80.14 241 15.9390 10165.2 8385.1 95,44

25.2653 7094.8 5971.9 80.40 242 15.8364 10205.9 8414.4 95.61

25.1177 7139.5 6010*0 80*66 243 15*7350 10246*5 8443*4 95.78

24.9699 7184.3 6048.0 80.91 244 15.6347 10237.0 8472.3 95.94

24.8219 7229*1 6086.

1

81*17 245 15*5356 10327*2 8501*0 96.11

24.6737 7274.0 6124.1 81.43 246 15.4376 10367.3 8529.5 96.27

24.52^3 7319.0 6162.1 81.68 247 15.3408 10407.2 8557.8 96.43

24.3767 7364.0 6200*1 81*94 248 15*2451 10447.6 8585.9 96.59

24.2279 7409.2 6238*1 82*19 249 15.1505 10486.5 8613.9 96.75

24.0791 7454*4 6276*1 82-44 250 15*0571 10525.9 8641*6 96.91

23.9301 7499.6 6314.0 82.69 251 14.9647 10565.1 8669.2 97.07

23.7810 7545.0 6351.9 82.94 252 14-8734 10604.2 8696.6 97.22

23.6319 7590.4 6389.8 83.19 253 14.7832 10643.1 8723.9 97.38

23.4827 7635.8 6427.6 83.44 254 14.6941 10681.8 8750.9 97.53

23.3336 7681.3 6465.4 83,68 255 14.6060 10720.3 8777.8 97.68

23.1845 7726.9 6503.2 83.93 256 14.5189 10758.7 8804.6 97.83

23.0354 7772.5 6540*9 84.17 257 14.4329 10796*9 8831.1 97.98

22.8864 7818*2 6578.5 84.42 258 14*3479 10834.9 8857.5 98.13

22.7375 7863*9 6616.1 84.66 259 14.2639 10872.8 8883.8 98.28

22*5888 7909*6 6653*6 84.90 260 14.1809 10910*5 8909.8 98*42

22.4403 7955.3 6691.0 85.14 261 14.0989 10948.1 8935.8 98.56

22.2920 8001.1 6728.4 85.38 262 14.0178 10985.5 8961.5 98.71

22.1439 8046.9 6765.7 85.62 263 13.9377 11022.7 8987.1 98.85

21.9961 8092.7 6802.9 85.86 264 13.8586 11059.8 9012.6 98.99

21.8487 8138.5 6840.0 86.09 265 13.7803 11096.7 9037.9 99.13

21.7016 8184.4 6877.0 86.33 266 13.7030 11133.5 9063.0 99.27

21.5549 8230.2 6913.9 86.56 267 13.6266 11170.1 9088.0 99.41

21.4086 8276.0 6950.8 86.79 268 13.5511 11206.6 9112.9 99.54

21.2628 8321.8 6987.5 87.02 269 13.4765 11242.9 9137,6 99.68

21.1175 8367,6 7024.1 87.25 270 13.4027 11279.6 9162.2 99.81

20.9727 8413.4 7060.6 87.48 271 13.3298 11315.0 9186.6 99.94

20.8285 8459.1 7097.0 87.71 272 13.2577 11350*9 9210.9 100.08

20.6849 8504.8 7133.2 87.93 273 13.1865 11386.6 9235.0 100.21

20.5420 8550.5 7169.3 88.16 274 13.1161 11422.2 9259.1 100.34

20.3997 8596.1 7205.3 88.38 275 13.0465 11457.6 9283.0 100.47

20.2582 8641.6 7241.1 88.60 276 12.9777 11492.9 9306.7 100.50

20.1174 8687.1 7276.8 88.82 277 12.9097 11528.1 9330.4 100.72

19.9774 8732.6 7312.4 89.04 278 12.8424 11563.1 9353.9 100.85

19.8382 8777.9 7347.8 89.26 279 12.7760 11597.9 9377.2 100.97

19.6998 8823.2 7383.0 89.47 280 12*7102 11632.7 9400*5 101.10

19.5623 8868.4 7418.1 89.69 281 12.6452 11667.3 9423.6 101.22

19.4257 8913.5 7453.0 89.90 282 12.5810 11701.8 9446.6 101.34

19.2900 8958.5 7487.7 90.11 283 12-5174 11736.1 9469.5 101*46

19.1553 9003.5 7522*3 90.32 284 12*4546 11770*3 9492.3 101*59

19.0216 9048-3 7556*7 90*53 285 12*3925 11804.4 9515*0 101*71

18.8889 9093.0 7591.0 90*74 286 12.3310 11838.4 9537*5 101.82

18.7572 9137.6 7625.0 90.95 287 12.2702 11872.2 9560.0 101.94

18,6265 9182.1 7658.9 91.15 288 12.2101 11905.9 9582.3 102.06

18.4969 9226.5 7692.6 91.35 289 12.1507 11939.5 9604.5 102.18

18.3684 9270.7 7726.1 91.56 290 12.0918 11973.0 9626.7 102.29

18.2410 9314.8 7759.4 91.76 291 12.0337 12006.4 9648.7 102.41

18.1147 9358.8 7792.6 91.95 292 11.9761 12039.6 9670.6 102.52

17.9896 9402.6 7825.5 92.15 293 11.9192 12072.7 9692.4 102.63

17.8656 9446.3 7858.3 92.35 294 11.8629 12105.7 9714.1 102.75

17.7427 9489.9 7890.8 92.54 295 11.8072 12138.6 9735.7 102.86

17.6210 9533.3 7923.2 92.73 296 11.7520 12171.4 9757.2 102.97

17.5005 9576.5 7955.3 92.92 297 11.6975 12204.1 9778.6 103.08

17.3812 9619.6 7987.3 93.11 298 11.6435 12236.6 9799.9 103.19

17.2631 9662.6 8019.1 93.30 299 11.5901 12269.1 9821.1 103.30

17.1461 9705.4 8050.7 93.49 300 11.5372 12301.4 9842.3 103.41

126
300.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

91.163 36.2888 3703.6 2865*9 53.27

92 36.1859 3739.0 2898.9 53.66

93 36.0625 3781.4 2938.5 54.11

94 35.9388 3823.9 2978.1 54.57

95 35.8147 3866.6 3017.8 55.02

96 35.6903 3909.3 3057.6 55.47

97 35.5657 3952.

i

3097.4 55.91

98 35.4407 3995.0 3137.2 56.35

99 35.3156 4037.9 3177.1 56.79

100 35.1902 4080,8 3217.0 57.22

101 35.0646 4123.8 3256.8 57.64

102 34.9388 4166.7 3296.7 58.07

103 34.8129 4209.6 3336.4 58.49

104 34.6867 4252*5 3376*2 58.90

105 34.5605 4295.4 3415.8 59.31

106 34*4340 4338*2 3455*4 59.72

107 34.3075 4381.0 3494.9 60.12

108 34.1808 4423.6 3534.3 60.52

109 34.0539 4466.2 3573.6 60.91

110 33.9270 4508.8 3612,8 61,30

111 33.7999 4551.2 3651.8 61.68

112 33,6726 4593.5 3690.7 62.06

113 33.5453 4635.7 3729.5 62.44

114 33.4178 4677.8 3768.1 62.81

115 33.2902 4719.7 3806.6 63.17

116 33.1624 4761.6 3844.9 63.53

117 33,0345 4803.3 3883.1 63.89

118 32.9065 4844.9 3921.2 64.25

119 32.7783 4886.4 3959.0 64.60

120 32.6500 4927.8 3996.8 64.94

121 32.5215 4969.1 4034.4 65.29

122 32.3929 5010.

2

4071.8 65.62

123 32.2641 5051.3 4109.1 65.96

124 32.1352 5092.3 4146.3 66.29

125 32.0061 5133.2 4183.4 66,62

126 31.8768 5174.6 4220.4 66.95

127 31.7474 5214.8 4257.3 . 67.27

128 31.6178 5255.6 4294.2 67.59

129 31.4880 5296,4 4331,0 67,91

130 31.3580 5337.2 4367.8 68,22

131 31.2277 5378.1 4404.6 68.53

132 31.0973 5419.0 4441.5 68.85

133 30.9667 5460.1 4478.4 69.16

134 30,8359 5501,3 4515,5 69.46

135 30.7049 5542.6 4552.6 69.77

136 30.5736 5583.8 4589.5 70.08

137 30.4421 5624.9 4626.3 70.38

138 30.3104 5665.9 4663.0 70.67

139 30.1784 5706.9 4699,6 70.97

140 30.0462 5747.7 4736.0 71.26

141 29.9138 5788.3 4772.1 71.55

142 29.7811 5828.9 4808.2 71.84

143 29.6481 5869.5 4844.2 72.13

144 29.5149 5910.1 4880.1 72.41

145 29.3814 5950.7 4916.1 72.69

146 29.2477 5991.5 4952.2 72.97

147 29.1137 6032.4 4988.3 73.26

148 28.9794 6073.4 5024.5 73,54

149 28.8449 6114.4 5060.6 73.81

150 28.7100 6155.6 5096.8 74.09

151 28.5749 6197.1 5133.3 74.37

152 28*4395 6239.2 5170*3 74.65

153 28*3039 6281.4 5207*4 74.92

154 28.1679 6323.6 5244.4 75.20

155 28.0317 6365.9 5281 .5 75.47

156 27.8952 6408.3 5318.6 75.75

157 27.7584 6450.fi 5355.7 76.02

158 27.6213 6493.4 5392.8 76.29

159 27.4840 6536,0 5430.0 76.56

160 27.3463 6578.7 5467.1 76.82

* PHASE change 127
300.00 atmosphere isobar

TEMP. DENSITY ENTHALPY internal ENTROPY temp. DENSITY ENTHALPY INTERNAL entropy

K mol/liteR J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 27.2084 6621.5 5504.3 77.09 231 17.7850 9687.9 7978.7 92.91

162 27.0703 6664 .

4

5541.4 77.36 232 17.6723 9729.8 8009.7 93.09

163 26.9319 6707.3 5578.6 77.62 233 17.5606 9771.6 8040.5 93.27

1 64 26.7932 6750.3 5615.8 77.88 234 17.4499 9813.2 8071.2 93.45

165 26.6542 6793.4 5653,0 78.15 235 17.3403 9854.7 8101.6 93.63

166 26.5150 6836.6 5690.1 78.41 236 17.2318 9896.0 8131.9 93.80

167 26.3756 b879 • 8 5727.3 78.67 237 17.1243 9937.2 8162.0 93.97

168 26.2360 6923.1 5764.5 78.93 238 17.0179 9978.2 8192.0 94.15

169 26.0961 6966.5 5801.7 79.18 239 16.9125 10019.1 8221 .7 94.32

170 25.9560 7010.0 5838.8 79.44 240 16.8081 10059.8 8251.3 94.49

171 25.8157 7053.5 5876.0 79.69 241 16.7048 10100.4 8280.7 94.66

172 25.6752 7097.1 5913.1 79.95 242 16.6026 10140,9 8310.0 94,83

173 25.5345 7140.7 5950.3 80,20 243 16.5014 10181.2 8339.0 94.99 m 2S.3q37 7184.5 5987.4 80.45 244 16.4013 10221.3 8367.9 95.16

175 25.2=;26 7228.3 6024.5 80.70 245 16.3022 10261.3 8396.6 95.32

176 25.111b 7272.1 6061.6 80.95 246 16.2041 10301.1 8425.2 95.48

177 2^.9702 7316.0 6098.7 81.20 2*7 16.1071 103*0.8 8453.6 95,64

178 24.8288 7360.0 6135.7 81.45 248 16.0110 10380.4 8481.8 95.80

179 24.6873 7404*0 6172*7 81*70 249 15*9160 10419*7 8509*8 95*96

180 24.5458 7448.1 6209*7 81*94 250 15*8221 10459.0 8537*7 96.12

181 24.4041 7492.3 6246.7 82.19 251 15.7291 10498.6 8565.4 96.27

182 24.2624 7536.5 6283.6 82.43 252 15.6371 10536.9 8593.0 96.43

183 24.1207 7580*7 6320*5 82*67 253 15*5461 10575*7 8620*3 96*58

184 23.9790 7625*0 6357.3 82*92 254 15.4561 10614.3 8647.6 96.74

185 23*8374 7669*3 6394*1 83*16 255 15*3671 10652*8 8674*6 96.89

186 23.6957 7713.7 6430.8 83.39 256 15.2790 10691.1 8701.5 97.04

187 23.5542 7758.1 6467.5 e3.63 257 15.1919 10729.3 8728.3 97.19

188 23.4127 7802*6 6504.2 83*87 258 15.1057 10767.3 8754.9 97.33

189 23.2713 7847.0 6540.8 84.11 259 15.0205 10805.1 8781.3 97.48

1 90 23.1301 7891.5 6577.3 84.34 260 14.9362 10842.

e

8807.6 97.62

191 22.9890 7936.1 6613.8 84.57 261 14.8528 10880.4 8833.8 97.77

192 22.8481 7980.6 6650.2 84.81 262 14.7704 10917.8 8859.8 97.91

193 22.7074 8025.2 6686.5 85.04 263 14.6888 10955.1 8885.6 98.05

194 22.5670 8069.7 6722.7 85.27 264 14.6081 10992,2 8911.3 98.19

195 22.4269 8114.3 6758.9 85.50 265 14.5283 11029.2 8936.8 98.33

196 22.2870 8158.9 6795.0 85.73 266 14. 4494 11066.0 8962.2 98.47

197 22.1475 8203.5 6831.0 85.95 267 14.3714 11102.7 8987.5 98,61

198 22.0083 8248.1 6866.9 86.18 268 14.2942 11139.3 9012.6 98.75

1 99 21.8695 8292.7 6902.7 86.40 269 14.2178 11175.7 9037.6 98.88

200 21.7311 8337.2 6938.4 86.63 270 14.1423 11211.9 9062.5 99.02

201 21.5932 8381.8 6974.0 86.85 271 14.0676 11248.1 9087.2 99.15

202 21.4557 8426.3 7009.5 87.07 272 13.9937 11284.0 9111.8 99.28

203 21.3188 8470.8 7044.9 87.29 273 13.9206 11319.9 9136.2 99.42

204 21.1823 8515.2 7080.2 87.51 274 13.8483 11355.6 9160.5 99.55

205 21.0464 8559.7 7115.3 87.73 275 13.7768 11391.2 9184.7 99.68

206 20.9111 8604.1 7150.4 87.94 276 13.7061 11426.7 9208.8 99.80

207 20.7764 8648.4 7185.3 88.16 277 13.6361 11462.0 9232.7 99.93

208 20.6423 8692.7 7220.1 88.37 278 13.5669 11497.2 9256.5 100*06

209 20.5089 8736.9 7254.7 88.58 279 13.4984 11532.2 9280.2 100.18

210 20.3762 8781.1 7289.3 88.79 280 13*4307 11567.1 9303.8 100*31

211 20.2442 8825.2 7323.6 89.00 281 13.3637 11601.9 9327.3 100.43

212 20.1129 8869.3 7357.9 89*21 282 13*2973 11636.6 9350.6 100.56

213 19,9824 8913.2 7392.0 89.42 283 13.2317 11671.2 9373.8 100.68

214 19.8527 8957,1 7426.0 89.62 284 13,1668 11705.6 9396.9 100.80

215 19.7237 9001.0 7459.8 89.83 285 13.1026 11739.9 9419.9 100.92

216 19.5956 9044.7 7493,4 90.03 286 13.0391 11774.1 9442.8 101.04

217 19.4684 9088.3 7526.9 90.23 287 12.9762 11808.2 9465.5 101.16

218 19.3420 9131.9 7560.3 90.43 288 12.9140 11842.1 9488.2 101.28

219 19.2165 9175.3 7593.5 90.63 289 12.8524 11875.9 9510.7 101.40

220 19.0919 9218.7 7626.5 90.83 290 12.7914 1 1909.

6

9533.2 101.51

221 18.9682 9261.9 7659.3 91.02 291 12.7311 11943.2 9555.5 101*63

222 18.8455 9305,1 7692.0 91.22 292 12.6714 11976.7 9577.8 101.74

223 16.7237 9348.1 7724.6 91.41 293 12.6124 12010.1 9599.9 101.86

224 18.6029 9391.0 7757.0 91.60 294 12.5539 12043.3 9621 .9 101*97

225 18.4830 9433*8 7789*1 91*80 295 12*4960 12076.5 9643.9 102*08

226 18.36*2 9476.5 7821.2 91.98 296 12.4388 12109.5 9665.7 102.19

227 18.2463 9519.0 7853.0 92.17 297 12.3821 12142.5 9687.4 102.31

228 18.1295 9561.5 7884.7 92.36 298 12.3259 12175.3 9709.1 102.42

229 18.0136 9603.7 7916.2 92.54 299 12.2704 12208.0 9730.6 102.53

230 17.8988 9645.9 7947.6 92.73 300 12.2154 12240.6 9752.1 102.63

128
350.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL energy

J/MOL

J/MOL-K K mol/liter J/MOL energy

J/MOL

J/MOL-K

92.358 36.4082 3850.6 2876.5 53.35

93 36.3313 3877.6 2901.5 53.64

94 36.2113 3919.7 2940.3 54.09

95 36.0911 3962.0 2979.3 54.54

96 35.9707 4004.3 3018.3 54.98

97 35.8500 4046.7 3057.4 55.42

98 35.7291 4089.1 3096.5 55.86

99 35.6081 4131.6 3135.7 56.29

100 35.4870 4174.1 3174.8 56.72

101 35.3657 4216.7 3213.9 57.14

102 35.2443 4259.2 3252.9 57.56

103 35.1228 4301.7 3292.0 57.97

104 35.0013 4344.2 3330.9 58.38

105 34.8796 4386.6 3369.8 58.79

106 34.7579 4429.0 3408.7 59.19

107 34.6361 44,1.3 3447.4 59.59

108 34.5143 4513.5 3486.0 59.98

109 34.3924 4555,7 3524.5 60.37

110 34.2705 4597.7 3562.8 60.75

111 34,1485 4639.6 3601.1 61.13

112 34.0265 4681.4 3639.2 61.51

113 33*9045 4723*1 3677.1 61*88

114 33*7824 4764.7 3714.9 62*25

115 33*6603 4806*2 3752*6 62*61

116 33.5381 4847*5 3790.0 62*97

117 33,4159 4888.7 3827.4 63.32

118 33.2937 4929.7 3864.5 63.67

119 33.1714 4970.6 3901.5 64,01

120 33.0491 5011.4 3938.3 64.36

121 32.9267 5052.1 3975.0 64.69

122 32.8043 5092.7 4011.6 65.03

123 32.6818 5133.1 4047.9 65.36

124 32.5593 5173.4 4084.2 65.68

125 32.4368 5213.7 4120.3 66.01

126 32.3141 5253.9 4156.4 66.33

127 32.1914 5294.6 4192.3 66.64

128 32.0687 5334.6 4228.1 66.96

129 31.9458 5374.1 4263.9 67.27

130 31,8229 5414.2 4299.7 67.58

131 31.6999 5454.2 4335.5 67.89

132 31*5769 5494*4 4371.3 68*19

133 31.4537 5534.7 4407.1 68.50

134 31.3305 5575*0 4443.1 68. 80

135 31*2072 5615.6 4479.1 69.10

136 31.0838 5655.9 4514.9 69.40

137 30.9603 5696.1 4550.6 69.69

138 30*8367 5736.2 4586*1 69.98

139 30.7130 5776.2 4621*5 70.27

140 30*5892 5816.1 4656.7 70.56

141 30.4653 5855.7 4691.6 70.84

142 30.3413 5895.3 4726.4 71.12

143 30.2171 5934.8 4761.2 71.40

144 30.0929 5974.4 4795.9 71.68

145 29.9685 6014.0 4830.6 71.95

146 29.8440 6053.6 4865.3 72.23

147 29.7194 6093.4 4900.1 72.50

148 29.5947 6133.3 4934.9 72.77

149 29.4699 6173.1 4969.7 73.04

150 29.3449 6213.1 5004.5 73.31

151 29.2198 6253.3 5039.6 73.58

152 29.0946 6294.2 5075.2 73.85

153 28.9693 6335.0 5110.8 74.12

154 28.8438 6376.0 5146.4 74*39

155 28.7182 6416.9 5182.0 74.65

156 28.5925 6458.0 5217,6 74.91

157 28.4667 6499.0 5253.2 75.18

158 28.3408 6540.

1

5288.8 75.44

159 28.2147 6581.3 5324.4 75.70

160 28.0885 6622.5 5359.9 75.96

* PHASE CHANGE 129
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

1 9 0

191 192

193

1 94

195

196

1 97

1 98

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

350.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL entropy TEMP. DENSITY ENTHALPY INTERNAL mol/liteR J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

27.9622 6663.8 5395.5 76.21 231 19.3941 9586.7 7758.1

27.8358 6705,1 5431.0 76.47 232 19.2872 9627.1 7788.4

27.7093 6746.4 5466.5 76.72 233 19.1810 9667.5 7818.5

27.5827 6787.8 5502*0 76.98 234 19.0756 9707.7 7848.6

27.4560 6829.2 5537.5 77*23 235 18.9709 9747.9 7878-5

27*3292 6870*7 5573*0 77*48 236 18.8670 9788.0 7908.2

27.2023 6912.2 5608.5 77.73 237 18.7639 9827.9 7937.9

27.0753 6953.8 5643 * 9 77.98 238 18.6615 9867.8 7967.4

26.9482 6995.4 5679.3 78.22 239 18*5600 9907.5 7996.7

26.8211 7037.0 5714.7 78.47 240 18.4592 9947.2 8025.9

26.6939 7078.7 5750.1 78.71 241 18.3592 9986.7 8055.0

26.5666 7120.4 5785.5 78.96 242 18.2599 10026.2 8083.9

26.4393 7162.2 5820*8 79.20 243 18.1615 10065.5 8112.7

26.3119 7203*9 5856.1 79.44 244 18.0639 10104.7 8141.4

26.1845 7245.8 5891.4 79.68 245 17.9670 10143.8 8169.9

26*0571 7287.6 5926*6 79.92 246 17*8710 10182*8 8198*3

25.9296 7329.5 5961*8 80*16 247 17.7757 10221*7 8226*6

25*8021 7371*4 5997*0 80*39 248 17*6812 10260*5 8254-7

25.6747 7413.4 6032.1 80*63 240 17*5876 10299*1 8282*6

25.5472 7455.4 6067*2 80*86 250 17.4947 10337*6 8310*5

25.4198 7497.4 6102.2 81.09 251 17.4026 10376.1 8338.2

25.2924 7539.4 6137.2 81.32 252 17.3113 10414.4 8365.7

25.1650 7581.5 6172.2 81.56 253 17.2208 10452.6 8393.2

25.0377 7623.6 6207.1 81.78 254 17.1311 10490,7 8420,5

24.9104 7665.7 6242.0 82.01 255 17.0421 10528.6 8447.6

24.7833 7707.8 6276.8 82.24 256 16.9540 10566.5 8474.6

24.6562 7750.0 6311.6 82.47 257 16.8666 10604.2 8501.5

24.5292 7792.1 63^6.3 82.69 258 16.7800 10641.8 8528.3

24.4024 7834.3 6381.0 82.91 259 16,6942 10679.3 8554.9

24.2757 7876.5 6415.6 83.14 260 16.6091 10716.7 8581.4

24.U91 7918.7 6450 .

1

83.36 261 16.5248 10753.9 8607.8

24.0227 7960.9 6484.6 83.58 262 16.4413 10791.1 8634.0

23,8965 8003.1 b5 1 9 .

0

83.80 263 16.3585 10828.1 8660.1

23.7705 8045.4 6553.4 84.02 264 16.2765 10865.0 8686.1

23.6447 8087.6 6587.7 84.23 265 16.1952 10901.8 8712.0

23.5191 8129,8 6621.9 84,45 266 16.1147 10938.5 8737.7

23.3938 8172.0 6656.0 84.66 267 16.0349 10975.0 8763.3

23.2687 8214.2 6690.1 84.88 268 15.9558 11011.4 8788.8

23.1439 8256.4 6724.1 85.09 269 15.8775 11047.8 8814.1

23.0194 8298.6 6758.0 85.30 270 1 5 .7999 11084.0 8839.4

22.8952 8340.8 6791.8 85.51 271 15.7230 11120.1 8864.5

22.7714 8383.0 6825.6 85.72 272 15.6468 11156.0 8889.5

22.6479 8425.1 6859*2 85.93 273 15.5713 11191.9 8914.3

22*5247 8467*3 6892*8 86*14 274 15*4965 11227*7 8939*1

22*4019 8509*4 6926 • 3 86*34 275 15*4224 11263*3 8963*7

22*2796 8551 .4 6959.6 86*55 276 15.3490 11298.8 8988.3

22*1576 8593*5 6992*9 86*75 277 15*2763 11334*2 9012*7

22.0361 8635*5 7026*1 86*95 278 15*2042 11369.5 9037.0

21.9150 8677*5 7059.2 87.16 279 15*1328 11404.7 9061*2

21*7943 8719.4 7092*2 87.36 280 15*0621 11439*8 9085-2

21.6742 8761.3 7125.1 87.55 281 14.9920 11474.0 9109.2

21.5545 8803.2 7157.8 87.75 282 14.9226 11509.6 9133.0

21.4354 8845.0 7190.5 87.95 283 14.8538 11544.4 9156.8

21.3168 8886.7 7223.0 88.14 284 14.7857 11579.0 9180.4

21.1987 8928.5 7255.5 88.34 285 14.7182 11613.5 9204.0

21.0812 8970.1 7287.8 88.53 286 14.6513 11648.0 9227.4

20.9642 9011.7 7320.0 88.72 287 14.5850 11682.3 9250.7

20.8479 9053,2 7352.1 88.92 288 14.5193 11716.5 9273.9

20.7321 9094.7 7384.1 89.11 289 14.4543 11750.6 9297.1

20.6169 9136*1 7416.0 89.29 290 14.3898 11784.6 9320.1

20.5024 9177.5 7447.7 89.48 291 14.3259 11818.5 9343.0

20.3885 9218.8 7479.3 89.67 292 14.2626 11852.3 9365.8

20.2753 9260.0 7510.8 89.85 293 14.1999 11886.1 9388.5

20.1627 9301.1 7542.2 90.04 294 14.1378 11919.7 9411.2

20.0508 9342.1 7573.4 90.22 295 14.0762 11953.2 9433.7

19.9396 9383.1 7604.5 90.40 296 14.0152 ] 1986.6 9456.1

19.8290 9424.0 7635.5 90.58 297 13.9547 12019.9 9478.5

19.7192 9464.8 7666 * 3 90*76 298 13.8948 12053.1 9500*7

19.6101 9505.5 7697.0 90.94 299 13.8355 12086.2 9522.9

19.5017 9546.1 7727.6 91.12 300 13.7766 12119.2 9545.0

ENTROPY

J/MOL-K

91.29

91.47

91.64

91*81

91*98

92*15

92.32

92.49

92.66

92.82

92.99

93.15

93.31

93.47

93.63

93*79

93*95

94*11

94.26

94.42

94.57

94.72

94.87

95.03

95.17

95.32

95.47

95.62

95.76

95.90

96.05

96.19

96.33

96.47

96.61

96.75

96.89

97.02

97.16

97.29

97.42

97.56

97.69

97*82

97*95

98.08

98*21

98.33

98.46

98.59

98.71

98.83

98.96

99.08

99.20

99.32

99.44

99.56

99.68

99.80

99.91

100.03

100.14

100.26

100.37

100.48

100.60

100.71

100.82

100.93

130
400.00 ATMOSPHERE ISOBAR

TFMP. density ENTHALPY INTERNAL entropy TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

93.543 36.5228 3997.4 2887*6 53*44

94 36.4695 4016.5 2905*1 53*64

95 36.3527 4058.3 2943.4 54.08

96 36.2357 4100*3 2981.7 54.52

97 36.1186 4142.3 3020.2 54.96

98 36.0014 4184.4 3058.6 55.39

99 35.8841 4226.6 3097*1 55*82

100 35*7667 4268*7 3135*5 56.24

101 35.6492 4310.9 3174.0 56.66

102 35.5317 4353*1 3212.4 57.08

103 35.4141 4395.2 3250.7 57*49

104 35.2965 4437.3 3289.0 57.89

105 35*1789 4479.4 3327.3 58*30

106 35.0613 4521 .4 3365.4 58.70

107 34.9438 4563.3 3403.4 59.09

108 34.8262 4605.2 3441.4 59.48

109 34.7086 4646.9 3479.2 59.86

no 34.5911 4688.6 3516.9 60.24

111 34.4736 4730.1 3554.4 60.62

112 34.3561 4771.5 3591.8 60.99

113 34.2386 4812.8 3629.0 61.36

114 34.1212 4854.0 3666.1 61*72

115 34.0038 4895.6 3703.0 62*08

116 33.8864 4935.9 3739.8 62.43

117 33*7691 4976*6 3776*4 62*78

118 33.6518 5017.2 3812.8 63.13

119 33.5345 5057.7 3849.0 63.47

120 33.4172 5098.0 3885.1 63.81

121 33.3000 5138.2 3921.0 64.14

122 33.1829 5178.2 3956.8 64.47

123 33.0657 5218.2 3992.4 64,80

124 32.9486 5258.0 4027.8 65.12

125 32.8314 5297,7 4063.2 65.44

126 32.7144 5337.3 4098.4 65.75

127 32,5973 5376.9 4133.5 66.07

128 32.4802 5416.4 4168.5 66.38

129 32.3632 5455.9 4203.5 66 .68

130 32.2461 5495.3 4238.4 66.99

131 32.1291 5534.8 4273.3 67.29

132 32.0121 5574.4 4308.3 67.59

133 31.8951 5614.0 4343*2 67.89

134 31.7780 5653.7 4378.3 68.19

135 31.6610 5693.6 4413.4 68.48

136 31.5440 5733.2 4448.3 68.78

137 31.4270 5772*7 4483*0 69.07

138 31.3099 5812.2 4517.6 69.35

139 31*1929 5851*4 4552*1 69*64

140 31.0758 5890.6 4586.3 69.92

141 30.9588 5929.5 4620.3 70.19

142 30.8417 5968.3 4654*1 70.47

143 30.7246 6007*0 4687*9 70*74

144 30.6074 6045.8 4721.6 71*01

145 30*4903 6084.6 4755*2 71*28

146 30*3731 6123*4 4788*9 71*55

147 30*2559 6162*3 4822*7 71*82

148 30.1387 6201.3 4856.5 72.09

149 30.0215 6240.2 4890.2 72.35

150 29,9042 6279.3 4923.9 72.61

151 29.7869 6318.6 4957.9 72.88

152 29.6696 6358.5 4992.4 73.14

153 29.5523 6398.4 5026.9 73.40

154 29.4349 6438.4 5061.4 73,66

155 29.3175 6478.3 5095.9 73.92

156 29.2001 6518.3 5130.3 74.18

157 29.0826 6558.4 5164.7 74,43

158 28.9652 6598,4 5199.1 74.69

159 28.8477 6638.5 5233.5 74.94

160 28*7302 6678*6 5267*9 75*19

PHASE CHANGE 131
<00.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP. DENSITY ENTHA4PY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

161 28.6127 6718.7 5302.2 75.4* 231 20.7031 9536.6 7578.3 89.98

162 28.4951 6758.9 5336.5 75.69 232 20.6022 9575.2 7607.8 90.15

163 28.3776 6799.1 5370.8 75.94 233 20.5019 9614.3 7637.3 90.32

164 28.2600 6839.3 54C5.1 76.18 234 20.4022 9653.3 7666.7 90. 43

165 28.1424 6879.5 5439.3 76.43 235 20.3031 9692.2 7695.9 90.65

166 28.0249 6919.8 5473.5 76.67 236 20.2045 9731.1 7725.1 90.82

167 27.9073 6960.0 5507.7 76.91 237 20.1065 9769.9 7754.1 90.98

168 27.7897 7000.3 5541.8 77.15 238 20.0091 9808.7 7783.0 91.14

169 27.6721 7040.7 5576.0 77.39 239 19.9123 9847,3 7811.8 91.31

170 27.5546 7081.0 5610.1 77.63 240 19.8161 9885.9 7840.5 91 .47

171 27.4370 7121.4 5644.1 77.87 241 19.7205 9924.4 7869.1 91.63

172 27.3195 7161.7 5678.1 78.10 242 19.6255 9962.8 7897.6 91.79

173 27.2020 7202.1 5712*1 78.34 243 19.5311 10001.1 7925.9 91.94

174 27.0845 7242*5 5746.1 78.57 244 19.4373 10039.4 7954*2 92.10

175 26.9671 7283*0 5780-0 78.80 245 19.3441 10077.5 7982.3 02.26

176 26.8496 7323.4 5813.9 79.03 246 19.2516 10115.6 8010.3 92.41

177 26.7323 7363.9 5847.7 79*26 247 19.1597 10153.6 8038.2 92.57

178 26.6150 7404.4 5881.5 79.49 248 19.0684 10191.5 8066.0 92.72

179 26.4977 7444.9 5915.2 79.72 249 18.9777 10229.3 8093.6 92.87

180 26.3805 7485.4 5949.0 79.94 250 18.8876 10267.1 8121.2 93.02

181 26.2634 7525.9 5982.6 80.17 251 18.7982 10304.7 8148.6 93.17

182 26.1463 7566.4 6016.2 80.39 252 18.7094 10342.3 8175.9 93.32

183 26.0294 7606.9 6049,8 80.61 253 18.6213 10379.7 8203.1 93.47

184 25.9125 7647.5 6083.3 80.83 254 18.5337 10417.1 8230.2 93.62

185 25,7958 7688.0 6116,8 81.05 255 18.4468 10454,4 8257.2 93.76

186 25.6791 7728.6 6150,2 81.27 256 18.3606 10491.6 8284.1 93.91

187 25.5626 7769.1 6183.6 81 .*9 257 18.2749 10528.7 8310.8 94.05

188 25.4461 7809.7 6216.9 81.71 258 18.1899 10565.7 8337.5 94.20

189 25.3299 7850.3 6250.1 81.92 259 18.1055 10602.6 8364.0 94.34

190 25.2137 7890*8 6283*3 82*14 260 18.0218 10639.4 8390*4 94 • 48

191 25.0978 7931.4 6316.5 82.35 261 17.9387 10676.2 8416.7 94.62

192 24.9819 7972.0 6349.6 82.56 262 17.8562 10712.8 8442.9 94.76

193 24.8663 8012-5 6382*6 82.77 263 17*7743 10749.3 8469.0 94.90

194 24.7508 8053.1 6415.5 82.98 264 17.6931 10785.8 8495.0 95.04

195 24.6356 8093*7 6448*4 83*19 265 17*6124 10822*1 8520*9 95.18

196 24.5205 8134.2 6481.3 83*40 266 17.5324 10858.4 8546.6 95.32

197 24.4057 8174.7 6514.0 83.60 267 17.4530 10894.6 8572.3 95.45

198 24.2910 8215.3 6546.7 83.81 268 17.3743 10930,6 8597.8 95.59

199 24.1766 8255.8 6579.3 84.01 269 17.2961 10966.6 8623.2 95.72

200 24.0625 8296.3 6611.9 84.22 270 17.2186 11002.5 8648.6 95.85

201 23.9486 8336.8 6644 .

4

84.42 271 17.1416 11038.2 8673.8 95.99

202 23.8350 8377.3 6676.8 84.62 272 17.0653 11073.9 8698.9 96.12

203 23*7216 8417-7 6709*1 84*82 273 16*9895 11109.5 8723*9 96.25

204 23.608b 8458.2 6741.4 85*02 274 16.9144 11145.0 8748.8 96.38

205 23*4958 8498*6 6773*5 85*21 275 16*8399 11180.4 8773*6 96*51

206 23*3833 8539*0 6805*6 85*41 276 16*7659 11215*7 8798*3 96.63

207 23*2712 8579*3 6837*7 85*61 277 16*6925 11251*0 8822*9 96*76

208 23.1594 8619.7 6869.6 85.80 278 16.6198 11286.1 8847.4 96.89

209 23.0479 8660,0 6901.4 85.99 279 16.5476 11321.1 8871.7 97.01

210 22.9368 8700.3 6933.2 86.19 280 16.4760 11356.6 8896.0 97.14

211 22.8261 8740.5 6964.9 86.38 281 16.4049 11390.9 8920.2 97.26

212 22.7157 8780.7 6996.5 86.57 282 16.3344 11425.6 8944.3 97.39

213 22.6057 8820.9 7028.0 86.76 283 16.2645 11460,3 8968.3 97.51

214 22,4961 8861.1 7059.4 86.94 284 16.1952 11494,8 8992.2 97.63

215 22.3869 8901.2 7090.7 87.13 285 16.1264 11529,3 9016.0 97.75

216 22.2782 8941.2 7121.9 87.32 286 16.0582 11563.7 9039.7 97.87

217 22.1698 8981.2 7153*0 87.50 287 15.9905 11598.0 9063.3 97.99

218 22.0619 9021.2 7184.1 87.69 288 15.9234 11632.2 9086*8 98.11

219 21.9545 9061.1 7215.0 87.87 289 15.8568 11666.3 9110*2 98.23

220 21.8475 9101.0 7245.8 88.05 290 15.7907 11700.3 9133.5 98.35

221 21.7409 9140.8 7276.6 88.23 291 15.7252 11734.2 9156.8 98.46

222 21*6349 9180*6 7307.2 88.41 292 15.6602 11768.1 9179*9 98.58

223 21.5293 9220*3 7337.7 88.59 293 15.5958 11801.8 9203.0 98.70

224 21.4242 9260.0 7368.2 88.77 294 15.5318 11835.5 9225.9 98.81

225 21.3196 9299.6 7398.5 88.94 295 15,4684 11869.0 9248.8 08.92

226 21.2155 9339.2 7428.7 89.12 296 15.4055 11902.5 9271.6 99.04

227 21*1120 9378.7 7458.8 89.29 297 15.3431 11935.9 9294.3 99.15

228 21.0089 9418.1 7488.9 89.47 298 15.2811 11969.2 9316.9 99.26

229 20.9065 9457.5 7518.8 89.64 299 15.2197 12002.5 9339.4 99.37

230 20.8045 9496.8 7548.6 89.81 300 15.1588 12035.6 9361.9 99.48

132
450.00 ATMOSPHERE ISOBAR

TEMP. density ENTHALPY internal ENTROPY TEMP. DENSITY enthalpy INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

* 94.720 36.6332 4143.9 2899.2 53.52

95 36.6013 4155.5 2909.7 53.64

96 36.4875 4197.2 2947.5 54.08

97 36.3736 4238.9 2985.3 54.51

98 36.2596 4280.7 3023.1 54.94

99 36.1455 4322.5 3061.0 55.37

100 36.0315 4364.4 3098,9 55.79

101 35.9174 4406.2 3136.7 56.20

102 35.8033 4448.1 3174.5 56.62

103 35*6893 4489.9 3212.3 57.02

104 35.5752 4531.7 3250.0 57.43

105 35,4612 4573.5 3287.6 57.83

106 35.3473 4615.2 3325.2 58.22

107 35.2334 4656.8 3362.6 58.61

108 35.1196 4698.3 3399.9 59.00

109 35.0058 4739.7 3437.2 59.38

110 34.8921 4781.6 3474.2 59.76

111 34.7785 4822.2 3511.2 60.13

112 34.6649 4863.3 3547.9 60.50

113 34.5515 4904.3 3584.6 60.86

114 34.4381 4945*1 3621*0 61*22

115 34.3248 4985.7 3657.3 61 .58

116 34.2116 5026.3 3693*4 61*93

117 34.0985 5066.6 3729.4 62.28

118 33.9855 5106.8 3765.2 62.62

119 33.8725 5146.9 3800.8 62.96

120 33.7597 5186.9 3836.2 63.29

121 33.6469 5226.6 3871.5 63.62

122 33.5342 5266.3 3906.6 63.95

123 33.4216 5305.8 3941.5 64.27

124 33.3091 5345.2 3976.3 64.59

125 33.1966 5384,5 4010.9 64.90

126 33.0843 5423,7 4045.5 65.22

127 32.9720 5462,8 4079.9 65,53

128 32,8598 5501.9 4114.2 65.83

129 32.7476 5540.9 4148.5 66.14

130 32.6355 5579.9 4182.7 66.44

131 32.5235 5618.9 4216.9 66.74

132 32.4116 5657.9 4251.1 67.03

133 32.2997 5697.0 4285*3 67.33

134 32*1879 5736.3 4319.7 67.62

135 32.0761 5775.6 4354.1 67.91

136 31.9644 5814.7 4388.2 68.20

137 31.8528 5853.6 4422.1 68.49

138 31.7412 5892.5 4456.0 68.77

139 31.6297 5931.2 4489.6 69.05

140 31.5182 5969.8 4523.1 69.33

141 31.4068 6008.1 4556.2 69.60

142 31.2954 6046.3 4589.3 69.87

143 31.1841 6084.4 4622.2 70.14

144 31.0728 6122.5 4655.1 70.41

145 30.9616 6160.6 4687.9 70.67

146 30.8504 6198.8 4720.8 70.93

147 30.7392 6237.1 4753.7 71.20

148 30.6281 6275.4 4786.6 71.46

149 30*5170 6313*6 4819*5 71*72

150 30.4060 6352.0 4852*3 71*98

151 30.2950 6390.6 4885.5 72,24

152 30.1840 6429.8 4919.1 72.50

153 30.0731 6468.9 4952.7 72.75

154 29.9622 6508.1 4986.3 73.01

155 29.8514 6547.3 5019.8 73*26

156 29.7406 6586.5 5053*3 73.51

157 29.6299 6625.7 5086*8 73.76

158 29.5191 6665.0 5120*3 74.01

159 29.4085 6704.2 5153.7 74.26

160 29.2978 6743.5 5187.1 7*. 51

PHASE CHANGE 133
161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191 192

193

194

195

196

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

450.00 ATMOSPHERE ISOBAR

DENSITY ENTHALPY INTERNAL entropy TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

mol/liteR J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

29,1873 6782.8 5220.5 74,75 231 21.7986 9519.7 7427.9 88.88

29.0767 6822.1 5253.9 74.99 232 21.7033 9557.7 7456.8 89.04

28.9662 6861*4 5287.2 75.24 233 21.6084 9595.8 7485*6 89.21

28.8558 6900«7 5320.5 75.48 234 21.5139 9633*0 7514.3 89.37

28.7454 6940,0 5353.7 75.72 235 21.4200 9671.7 7543.0 89.53

28,6350 6979.3 5387.0 75.95 236 21.3265 9709.6 7571,5 89.69

28,5248 7018.7 5420.1 76,19 237 21.2334 9747.4 7599.9 89.85

28.4145 7058.0 5453.3 76.43 238 21.1408 9785.1 7628.3 90.01

28.3043 7097.4 5486.4 76.66 239 21.0487 9822.8 7656.5 90.17

28.1942 7136.7 5519.5 76.89 240 20*9571 9860 •

4

7684.7 90*33

28.0842 7176.1 5552.5 77.12 241 20.8659 9898.6 7712.7 90.48

27.9742 7215.5 5585.5 77.35 242 20.7753 9935.5 7740.7 90.64

27.8643 7254,8 5618.4 77.58 243 20.6851 9972.9 7768.5 90.79

27.7545 7294.2 5651.3 77.81 244 20.5954 10010.3 7796.3 90.94

27.6447 7333.6 5684.2 78.03 245 20.5062 10047.6 7824.0 91.10

27.5350 7373.0 5717.0 78.26 246 20.4175 10084.8 7851.6 91.25

27.4254 7412.4 5749*8 78.48 247 20.3293 10122.0 7879.0 91.40

27.3160 7451.8 5782.5 78.70 248 20.2416 10159.1 7906.4 91.55

27.2066 7491*2 5815.2 78.92 249 20.1544 10196.1 7933.7 91.70

27.0972 7530.6 5847.9 79.14 250 20.0678 10233.0 7960.9 91.85

26.9880 7570.0 5880.5 79.36 251 19.9816 10269.9 7987.9 91.99

26.8790 7609.4 5913*0 79.58 252 19*8959 10306*7 8014.9 92*14

26.7700 7648.8 5945.5 79.79 253 19.8108 10343.5 8041.8 92.29

26.6611 7688.2 5977.9 80.01 254 19.7262 10380.1 8068.6 92.43

26.5524 7727.6 6010.3 80*22 255 19.6420 10416.7 8095.3 92.57

26.4438 7767.0 6042.7 80*43 256 19.5584 10453.2 8121.9 92.72

26*3353 7806*4 6075*0 80*65 257 19*4753 10489.7 8148.4 92.86

26.2270 7845*8 6107*2 80*86 258 19*3928 10526*6 8174*8 93*00

26.1188 7885.1 6139.4 81.06 259 19.3107 10562.3 8201.1 93.14

26.0108 7924.5 6171.5 81.27 260 19.2292 10598.5 8227.3 93.28

25.9029 7963.9 6203.5 81.48 261 19.1482 10634.7 8253.4 93.42

25.7952 8003.

2

6235.5 81.68 262 19.0677 10670.7 8279.4 93.56

25.6R77 8042*6 6267*5 81*89 263 18*9877 10706*7 8305*3 93*69

25.5R03 8081*9 6299*4 82*09 264 18.9083 10742*6 8331*1 93*83

25.4731 8121*2 6331*2 82.29 265 18.8294 10778.5 8356.9 93.97

25.3662 8160.5 6362*9 82*49 266 18.7510 10814.2 8382.5 94.10

25.2594 8199.8 6394.6 82.69 267 18.6731 10849.9 8408.0 04.23

25.1528 8239.1 6426.3 02.89 268 1 8 .5957 10805.5 8433.4 04.37

25.0464 8278.3 6457.8 83.09 269 18.5188 10921.0 8458.8 04.50

24.9403 8317.6 6489.3 83.29 270 18.4425 10956.4 8484.0 94.63

24.8344 8356.8 6520.8 83.48 271 18.3667 10991.8 8509.2 94.76

24.7287 8396.0 6552.1 83.68 272 18.2914 11027.1 8534.2 04.89

24.6233 8435.2 6583.4 83.87 273 18.2166 11062.3 8559.2 95.02

24.5181 8474.4 6614.6 84.06 274 18.1423 11097.4 8584.1 95.15

24.4131 8513.5 6645.8 84.26 275 18.0685 11132.4 8608.9 95.28

24.3085 8552.7 6676.9 84.45 276 17.9952 11167.4 8633.5 95.40

24.2041 8591.8 6707.9 84.64 277 17.9225 11202.3 8658.1 95.53

24.0999 8630.8 6738.8 84.82 278 17.8502 11237.1 8682 .

6

95.66

23.9961 8669.9 6769.7 85.01 279 17.7784 11271.8 8707.1 95.78

23.8926 8708.9 6800.5 85.20 280 17.7072 11306.5 8731.4 05,90

23.7893 8747.9 6831 .2 85.38 281 17.6364 11341.0 8755.6 96.03

23.6864 8786.9 6861.8 05.57 282 17*5662 11375.5 8779.8 96.15

23*5838 8825*8 6892.4 85*75 283 17.4964 11409*9 8803*8 96*27

23.4815 8864.7 6922.8 85.93 284 17.4271 11444.3 8827.8 96.39

23.3795 8903.5 6953.2 86.11 285 17.3583 11478.5 8851.7 96.51

23.2779 6942.4 6983.5 86.29 286 17.2900 11512.7 8875.5 96.63

23.1766 8981 .

1

7013.8 86.47 287 17*2222 11546*8 8899.2 96.75

23.0757 9019.9 7043.9 86.65 288 17.1549 11580.8 8922.8 96.87

22*9751 9058*6 7074*0 86*83 289 17*0880 11614.7 8946*3 96.99

22.8749 9097.3 7103.9 87.00 290 17.0216 11648.6 8969.8 97.10

22.7750 9135.9 7133.8 87.18 291 16.9557 11682.4 8993.2 97.22

22.6756 9174.5 7163.6 87.35 292 16.8903 11716.1 9016.4 97.34

22.5765 9213.0 7193.4 87.53 293 16.8253 11749.7 9039.6 97.45

22.4778 9251.5 7223.0 87.70 294 16.7608 11783.2 9062.8 97.57

22.3796 9290.

C

7252.5 87.87 295 16.6968 11816.7 9085.8 97.68

22.2817 9328.4 7282.0 88*04 296 16.6332 11850.1 9108.8 97.79

22.1842 9366.7 7311.3 88.21 297 16.5701 11883.4 9131.6 97.90

22.0872 9405.0 7340.6 88.38 298 16.5074 11916.7 9154.4 98.02

21.9905 9443.3 7369.8 88.55 299 16,4452 11949.8 9177.1 98.13

21.8943 9481.5 7398.9 88.71 300 16.3834 11982.9 9199.8 98.24

134
500.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP, DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

95.886 36.7399 4290.1 2911.1 53.61

96 36.7274 4294.8 2915.3 53.65

97 36.6164 4336.2 2952.6 54.08

98 36.5053 4377.7 2989.9 54,51

99 36.3943 4419.3 3027.2 54,93

100 36.2832 4460.9 3064.5 55.35

101 36.1722 4502.5 3101.8 55.76

102 36.0612 4544.1 3139.1 56,17

103 35*9503 4585*6 3176*4 56.58

104 35.8394 4627.2 3213.5 56.98

105 35.7287 4668.6 3250*6 57.38

106 35.6180 4710.1 3287.6 57.77

107 35*5074 4751.4 3324.5 58.16

108 35*3969 4792*7 3361*3 58*54

109 35*2865 4833*8 3398*0 58.92

110 35.1762 4874.8 3434.6 59.30

111 35.0661 4915.8 3471.0 19.67

112 34.9561 4956.6 3507.2 60.03

113 34.8461 4997.2 3543.3 60.39

114 34,7364 5037.7 3579.2 60.75

115 34.6267 5078.1 3614,9 61.10

116 34.5172 5118.3 3650.5 61.45

117 34.4078 5158.4 3685,9 61.80

118 34.2985 5198.3 3721.1 62.14

119 34.1893 5238.6 3756.2 62.47

120 34.0803 5277.6 3791.0 62.80

121 33.9714 5317.1 3825.7 63.13

122 33.8627 5356.4 3860.3 63.45

123 33.7540 5395.6 3894.6 63.77

124 33.6455 5434.6 3928.8 64,09

125 33.5371 5473,6 3962,9 64,40

126 33.4288 5512.4 3996,8 64,71

127 33.3207 5551.2 4030.7 65.02

128 33.2126 5589,8 4064.4 65.32

129 33*1047 5628.5 4098.1 65.62

130 32*9969 5667.1 4131.7 65.92

131 32.8892 5705.7 4165.2 66.22

132 32*7816 5744.3 4198*8 66*51

133 32.6742 5783.6 4232.4 66.80

134 32.5668 5821,8 4266.1 67,09

135 32.4596 5860.7 4299.9 67.38

136 32.3524 5899.4 4333.4 67.67

137 32.2454 5937.9 4366.7 67.95

138 32.1384 5976.3 4399.9 68.23

139 32.0316 6014.6 4432,9 68.50

140 31.9248 6052.6 4465.6 68.78

141 31.8182 6090.5 4498.2 69.05

142 31.7116 6128.2 4530.5 69.31

143 31.6051 6165.8 4562.8 69.58

144 31.4987 6203.4 4595.0 69.84

145 31.3925 6241.6 4627.1 70.10

146 31.2863 6278.7 4659.3 70.36

147 31.1802 6316-4 4691.5 70*62

148 31.0741 6354.1 4723.7 70.88

149 30.9682 6391.8 4755.9 71.14

150 30.8624 6429.6 4788.0 71.39

151 30.7566 6467.7 4820.4 71.65

152 30.6509 6506.2 4853.3 71 *90

153 30.5453 6544.8 4886.2 72.16

154 30.4398 6583.4 4919.0 72.41

155 30.3344 6622.0 4951*8 72*66

156 30.2290 6660.6 4984.6 72.91

157 30.1238 6699.2 5017.3 73.15

158 30.0186 6737.7 5050.0 73.40

159 29.9135 6776.3 5082.7 73.64

160 29.8085 6815.6 5115.3 73.88

* PHASE CHANGE 135
500.00 ATMOSPHERE isobar

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP, DENSITY ENTHAL.PY INTERNAL entropy

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL energy

J/MOL

j/mol-k

161 29,7036 6853.6 5147.9 74.12 231 22.7376 9527.5 7299.4 87.93

162 29.5988 6892.2 5180.5 74.36 232 22*6472 9564.8 7327.7 88.09

163 29.4940 6930*8 5213.0 74.60 233 22*5571 9601*9 7355.9 88.25

1 64 29.3894 6969.4 5245.5 74.84 234 22.4674 9639.0 7384.0 88.41

165 29.2848 7008.0 5278.0 75.07 235 22.3780 9676.1 7412.1 88.56

166 29.1803 7046.6 5310.4 75.30 236 22.2890 9713.1 7440.1 88.72

167 29.0759 7085.2 5342.7 75.54 237 22.2005 9750.1 7468.0 88.88

168 28.9717 7123.8 5375.1 75.77 238 22.1123 9787.6 7495.8 89.03

169 28.8675 7162.4 5407.4 75.99 239 22.0244 9823.8 7523.5 89.19

170 28.7634 7201.0 5439.6 76.22 240 21*9370 9860.6 7551.1 89.34

171 28,6594 7239.6 5471.8 76.45 241 21.8500 9897.4 7578.7 89.49

172 28.5555 7278.2 5504.0 76.67 242 21*7634 9934.1 7606*2 89.65

173 28.4517 7316.8 5536.1 76*90 243 21*6772 9970.7 7633*5 89.80

174 28.3480 7355.4 5568.2 77.12 244 21*5914 10007*3 7660*9 89.95

175 28.2444 7394.0 5600.2 77.34 245 21.5060 10043.9 7688.1 90.10

176 28.1409 7432.5 5632.2 77.56 246 21.4210 10080.3 7715.2 90.25

177 28.0376 7471.1 5664.1 77,78 247 21.3365 10116,8 7742.3 90.39

178 27.9343 7509.7 5696.0 78.00 248 21.2523 10153.1 7769.2 90.54

179 27.8312 7548.2 5727.8 78.21 249 21.1686 10189.4 7796.1 90.69

180 27.7282 7586.8 5759.6 78.43 250 21*0853 10225.7 7822*9 90*83

181 27.6253 7625.3 5791.4 78.64 251 21.0024 10261.9 7849.6 90.98

182 27.5226 7663.9 5823.1 78.85 252 20.9200 10298.0 7876.2 91.12

183 27.4200 7702.4 5854.7 79.06 253 20*8379 10334.1 7902.7 91.26

184 27.3175 7740.9 5886.3 79.27 254 20*7563 10370.1 7929.2 9 1 .41 185 27.2152 7779.4 5917.8 79.48 255 20.6752 10406.6 7955.5 91.55

186 27.1130 7817,9 5949.3 79.69 256 20.5944 10441,9 7981.8 91.69

187 27.0109 7856.4 5980.7 79.90 257 20.5141 10477.7 8008.0 91.83

188 26.9090 7894.8 6012.1 80*10 258 20.4343 10513.5 8034.1 91.97

189 26.8073 7933*3 6043*4 80*31 259 20.3549 10549.2 8060.1 92*10

190 26.7057 7971.7 6074.6 80.51 260 20.2759 10584,8 8086.1 92.24

191 26.6043 8010.2 6105.8 80.71 261 20.1973 10620.4 8111.9 92.38

192 26.5030 8048*6 6137*0 80*91 262 20*1192 10655.9 8137*7 92*51

193 26*4020 8087*0 6168*0 81*11 263 20*0415 10691*3 8163*4 92*65

194 26.3011 8125*4 6199.

1

81*31 264 19*9643 10726*7 8188*9 92*78

195 26.2003 8163*7 6230*0 81*51 265 19*8875 10762.6 8214.5 92*92

196 26*0998 8202*1 6260*9 81*70 266 19*8111 10797*2 8239*9 93*05

197 25.9995 8240*4 6291.8 81.90 267 19.7352 10832.4 8265*2 93.18

198 25*8993 8278*7 6322*6 82*09 268 19.6597 10867*5 8290*5 93.31

199 25*7994 8317*0 6353*3 82*28 269 19*5847 10902*5 8315*6 93*44

200 25*6996 8355*3 6383*9 82.48 270 19*5101 10937*5 8340*7 93*57

201 25.6001 8393.6 6414.5 82.67 271 19.4359 10972.4 8365.7 93.70

202 25.5008 8431.8 6445*0 82.86 272 19.3622 11007.3 8390.6 93.83

203 25.4017 8470*0 6475.5 83*05 273 19.2890 11042.0 8415.5 93*96

204 25.3028 8508.2 6505*9 83.23 274 19*2161 11076.7 8440.2 94.08

205 25*2042 8546*4 6536*2 83*42 275 19*1437 11111*4 8464*9 94.21

206 25*1058 8584*5 6566*5 83*61 276 19*0718 11146.0 8489*5 94.34

207 25.0076 8622.6 6596.7 83.79 277 19.0003 11180.5 8514.0 94,46

208 24.9097 8660.7 6626.8 83.97 278 18.9292 11214.9 8538.4 94.58

209 24.8120 8698.8 6656.9 84.16 279 18.8585 11249.3 8562.7 94.71

210 24.7146 8736.8 6686.8 64.34 280 18.7883 11283.6 8587.0 94.83

211 24.6175 8774.8 6716.7 84.52 281 18.7185 11317.8 8611.2 94.95

212 24.5206 8812.8 6746.6 84.70 282 18.6492 11351.9 8635.3 95.07

213 24 .4240 8850,7 6776.4 84.88 283 18.5803 11386.0 8659.3 95.19

214 24.3277 8888.6 6806.1 85.05 284 18.5118 11420,1 8683.2 95.31

215 24.2316 8926.5 6835.7 85.23 285 18.4437 11454.6 8707.1 95.43

216 24.1359 8964.4 6865.2 85.41 286 18.3761 11487.9 8730.9 95.55

217 24.0404 9002.2 6894.7 85.58 287 18.3089 11521.7 8754,6 95.67

218 23.9453 9039.9 6924.1 85.75 288 18.2421 11555.5 8778.2 95.79

219 23.8504 9077.7 6953.5 85.93 289 18.1757 11589.2 8801.7 95.90

220 23.7559 9115.4 6982.7 86.10 290 18.1098 11622.8 8825.2 96.02

221 23.6616 9153.1 7011.9 86.27 291 18.0443 11656.3 8848.6 96.14

222 23.5677 9190.7 7041.0 86.44 292 17.9792 11689.8 8871 .9 96.25

223 23.4741 9228.3 7070*0 86.61 293 17*9145 11723*2 8895*

1

96.37

224 23*3809 9265.8 7099*0 86*78 294 17*8502 11756*6 8918*3 96.48

225 23*2880 9303*4 7127*8 86.94 295 17*7863 11789.9 8941.4 96.59

226 23*1954 9340*8 7156*6 87.11 296 17*7229 11823*1 8964*4 06.70

227 23*1031 9378*3 7185*3 87*28 297 17*6598 11856*2 8987*3 96*82

228 23*0112 9415*6 7213*9 87.44 298 17*5972 11889*3 9010*2 96.93

229 22*9197 9453*0 7242*5 87.60 299 17.5350 11922*3 9033*0 97.04

230 22.8285 9490.3 7271.0 87.77 300 17.4731 11955.2 9055.7 97.15

136
600.00 ATMOSPHERE isobar

TEMP.

K DENSITY enthalpy internal entropy

MOL/LITER J/MOL ENERGY J/MOL-K

J/MOL

TEMP. DENSITY ENTHALPY INTERNAL entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

« 98 . 198 36.9438 4581,9 2936.3 53.78

99 36.8589 4614.9 2965.4 54.11

100 36.7531 4656.0 3001.8 54.53

101 36.6474 4697.2 3038.2 54.94

102 36.5418 4738.3 3074.6 55.34

103 36*4363 4779.5 3110*9 55.74

104 36.3310 4820.6 3147.2 56.14

105 36.2257 4861,6 3183.3 56.53

106 36.1207 4902.6 3219.4 56.92

107 36.0158 4943.5 3255.4 57.31

108 35.9110 4984,3 3291.3 57.69

109 35.8064 5025.0 3327.1 58.06

no 35.7020 5065.6 3362,7 58,43

111 35.5978 5106.1 3398.2 58.80

112 35.4937 5146.4 3433*6 59.16

113 35*3898 5186.6 3468*7 59*52

114 35.2861 5226.7 3503.7 59.87

115 35.1826 5266,6 3538.6 60.22

116 35.0793 5306.3 3573.2 60,56

117 34.9761 5345.9 3607.7 60.90

118 34.8732 5385.3 3642.0 61.24

119 34.7704 5424.6 3676.1 61.57

120 34*6678 5463*7 3710*0 61*90

121 34.5654 5502.7 3743,8 62.22

122 34.4632 5541.5 3777.4 62.54

123 34.3612 5580.1 3810.8 62.85

124 34.2594 5618.6 3844.0 63.17

125 34.1577 5657.0 3877.1 63.47

126 34.0562 5695.3 3910.1 63.78

127 33*9549 5733.5 3943.0 64.08

128 33.8538 5771.6 3975.7 64.38

129 33.7529 5809.6 4008,4 64.68

130 33,6521 5847,7 4041.0 64.97

131 33.5515 5885.7 4073.6 65.26

132 33.4511 5923.7 4106.2 65.55

133 33.3508 5961.8 4138.8 65.84

134 33.2507 5999.9 4171.5 66.12

135 33.1508 6038.2 4204.2 66.41

136 33.0511 6076.2 4236.7 66,69

137 32.9515 6114.6 4269.0 66.97

138 32.8520 6151.7 4301.1 67.24

139 32*7527 6189.3 4333.1 67.51

140 32.6536 6226.6 4364.8 67.78

141 32.5547 6263.8 4396.2 68.04

142 32.4558 6300.7 4427.5 68.31

143 32.3572 6337.6 4458.7 68.57

144 32.2587 6374.5 4489.8 68.82

145 32.1603 6411.3 4520*9 69.08

146 32.0621 6448.2 4552.0 69.33

147 31.9640 6485.1 4583.1 69.59

148 31.8661 6522.0 4614.2 69.84

149 31.7683 6558.9 4645.2 70.09

150 31.6707 6595.8 4676.2 70.34

151 31.5732 6633.1 4707.5 70,59

152 31*4759 6670*8 4739.2 70*84

153 31.3786 6708,4 4770.9 71.09

154 31.2816 6746.1 4802.6 71.33

155 31.1846 6783.8 4834.2 71*58

156 31*0878 6821*5 4865*8 71*82

157 30*9912 6859*1 4897*4 72*06

158 30*8947 6896*8 4928*9 72.30

159 30*7983 6934*4 4960.4 72.54

160 30*7020 6972*

i

4991*9 72*77

PHASE CHANGE 137
600.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY internal ENTROPY TEMP, DENSITY ENTHALPY INTERNAL Entropy

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

j/mol-k

161 30.6059 7009.7 5023.3 73.01 231 24.2874 9592.1 7088.9 86.34

162 30.5099 7047.3 5054.6 73.24 232 24.2049 9627.9 7116.2 86.50

163 30.4141 7084.9 5085.9 73,47 233 24.1226 9663.7 7143.4 86.65

164 30.3184 7122.5 5117.2 73.70 234 24.0406 9699.5 7170.6 86.80

165 30.2220 7160.0 5148.4 73,93 235 23.9589 9735.2 7197.7 86.96

166 30.1274 7197.6 5179.6 74.16 236 23.8774 9770,9 7224.7 87.11

167 30.0321 7235.1 5210.7 74.38 237 23.7963 9806.6 7251.7 87,26

168 29.9370 7272.7 5241.8 74.60 238 23.7154 9842.2 7278.6 87.41

169 29.8419 7310.2 5272.9 74.83 239 23.6348 9877.8 7305.4 87.56

170 29.7471 7347.7 5303.9 75.05 240 23.5546 9913.3 7332.2 87.71

171 29.6523 7385.1 5334.8 75.27 241 23.4746 9948.8 7358.9 87.85

172 29.5577 7422*6 5365.7 75.49 242 23*3949 9984.2 7385*5 88.00

173 29.4633 7460*1 5396.6 75*70 243 23*3156 10019*6 7412*0 88.15

174 29.3689 7497*5 5427*4 75*92 244 23*2365 10055*0 7438*5 88*29

175 29.2748 7534.9 5458.1 76.13 245 23.1577 10090.3 7464.9 88.44

176 29,1807 7572,3 5488.9 76.35 246 23.0793 10125.5 7491.3 88.58

177 29.0868 7609.7 5519.5 76.56 247 23.0011 10160.8 7517.6 88.72

178 28.9931 7647.0 5550.1 76.77 248 22.9233 10195.9 7543.8 88.87

179 28.8995 7684.4 5580.7 76.98 249 22.8458 10231.1 7569.9 89.01

180 28.8060 7721.7 5611.2 77.19 250 22.7686 10266.1 7596*0 89.15

181 28.7128 7759.0 5641.6 77.39 251 22.6917 10301.2 7621.9 89.29

182 28.6196 7796.3 5672.0 77.60 252 22.6151 10336.2 7647.9 89.43

183 28.5266 7833*6 5702.3 77.80 253 22*5389 10371*1 7673.7 89.57

184 28.4338 7870*8 5732.6 78*01 254 22*4629 10406*0 7699.5 89.70

185 28.3411 7908*0 5762*8 78*21 255 22*3873 10440*9 7725*2 89*84

186 28.2486 7945*2 5793*0 78*41 256 22*3120 10475*7 7750*9 89.98

187 28.1562 7982*4 5823*1 78*61 257 22*2371 10510*4 7776*4 90*11

188 28.0640 8019.6 5853*2 78.81 258 22*1624 10545*1 7801*9 90.25

189 27.9720 8056*7 5883*2 79*00 259 22*0881 10579*8 7827*4 90*38

190 27.8801 8093*8 5913*2 79.20 260 22*0142 10614.4 7852*7 90.51

191 27.7884 8130.9 5943.1 79.39 261 21.9405 10649.0 7878.0 90.65

192 27.6969 8168.0 5972.9 79.59 262 21.8672 10683.5 7903.2 90.78

193 27.6055 8205.0 6002*7 79.78 263 21*7942 10718.6 7928.4 90.91

194 27.5143 8242.1 6032.4 79.97 264 21.7215 10752.4 7953.5 91.04

195 27.4233 8279.1 6062.1 80.16 265 21.6492 10786.7 7978.5 91.17

196 27.3325 6316*0 6091.7 80*35 266 21*5772 10821*6 8003*4 91*30

197 27.2419 8353*0 6121*3 80*54 267 21*5055 10855*3 8028*3 91 *43

198 27*1514 8389*9 6150*7 80*73 268 21*4342 10889*5 8053*1 91*56

199 27.0611 8426.8 6180.2 80.91 269 21.3632 10923.7 8077.8 91.68

200 26.9711 8463.7 6209.5 81.10 270 21.2925 10957.8 8102.5 91.81

201 26.8812 8500.5 6238.9 81.28 271 21.2222 10991.8 8127.1 91.94

202 26.7815 8537*4 6268*1 81*46 272 21*1522 11025.8 8151*6 92*06

203 26.7020 8574.2 6297.3 81.64 273 21.0826 11059.8 8176.1 92.19

204 26*6127 8610*9 6326*4 81*82 274 21*0133 11093*7 8200*5 92*31

205 26.5236 6647.7 6355.5 82.00 275 20.9443 11127.5 8224.8 92.43

206 26.4347 8684,4 6384.5 82.18 276 20.8756 11161.3 8249.0 92.56

20? 26.3460 8721.1 6413.5 82.36 277 20.8073 11195.1 8273.2 92.68

208 26.2576 8757.7 6442.3 82.54 278 20.7393 11228.8 8297.3 92.80

209 26.1693 8794.4 6471.2 82.71 279 20.6717 11262.4 8321.4 92.92

210 26.0813 e831 .0 6499.9 82*89 280 20*6044 11296.6 8345.4 93*04

211 25.9834 8867.5 6528.6 83.06 281 20.5374 11329.5 8369.3 93.16

212 25.9058 8904.1 6557.2 83.23 282 20.4708 11363.6 8393.1 93.28

213 25.8185 8940*6 6585.8 83*41 283 20*4045 11396.5 8416.9 93.40

214 25.7313 8977*1 6614.3 83*58 284 20*3386 11429.8 8440*6 93.51

215 25.6444 9013*5 6642*8 83*75 285 20*2730 11463*2 8464*3 93.63

216 25.5577 9049.9 6671*1 83.92 286 20*2077 11496*4 8487*8 Q3.75

217 25.4713 9086*3 6699*4 84*08 287 20*1427 11529*6 8511*4 93.86

218 25.3851 9122.7 6727.7 84.25 288 20.0781 11562.8 8534.8 93.98

219 25.2991 9159.0 6755.9 84.42 289 20.0138 11595.9 8558.2 94.09

220 25.2134 9195.3 6784.0 84.58 290 19.9499 11629.0 8581.5 94.21

221 25.1279 9231.5 6812.0 84.75 291 19.8862 11662.0 8604.8 94.32

222 25.0427 9267*7 6840*0 84.91 292 19.8229 11694.9 8627*9 94.43

223 24.9577 9303*9 6867*9 85*07 293 19.7600 11727.8 8651*1 94.55

224 24*8730 9340*1 6895*8 85*24 294 19*6974 11760*7 8674*1 94.66

225 24.7886 9376.2 6923*6 85.40 295 19.6351 11793.4 8697.1 94.77

226 24*7044 5412*2 6951*3 85*56 296 19*5731 11826*2 8720*1 94.08

227 24*6205 9448*3 6978*9 85*72 297 19*5114 11858.9 8742*9 94.99

228 24.5368 9484.3 7006.5 85.87 298 19.4501 11891.5 8765.7 95.10

229 24.4534 9520.3 7034.0 86.03 209 19.3891 11924.1 8788.5 95.21

230 24.3703 9556.2 70bl .5 86.19 300 19.3285 11956.6 8811.1 95.32

138
700.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

100.477 37.1372 4872.8 2962.9 53,95

101 37,0843 4894,2 2981.5 54.17

102 36.9832 4935.6 3017.1 54.57

103 36.8823 4975.8 3052.7 54.97

104 36.7815 5016.6 3088.2 55.36

105 36.6810 5057.3 3123.6 55.75

106 36*5806 5098.0 3159*0 56.14

107 36.4804 5138.5 3194.2 56.52

108 36.3804 5179.6 3229.4 56.89

109 36.2807 5219.4 3264.4 57.27

110 36.1811 5259.7 3299,3 57.63

111 36.0817 5299,8 3334.0 58.00

112 35.9826 5339.8 3368.6 58.36

113 35,8837 5379.7 3403.0 58.71

114 35.7850 5419.4 3437.3 59.06

115 35.6866 5459.6 3471.4 59.40

116 35.5883 5498.4 3505.3 59.75

117 35.4903 5537.6 3539.1 60 .08

118 35*3925 5576*7 3572*6 60.42

119 35.2949 5615.6 3606*0 60.74

120 35*1976 5654.3 3639*2 61*07

121 35.1005 5692.9 3672.2 61.39

122 35*0036 5731*4 3705*0 61*70

123 34*9069 5769.6 3737*7 62*02

124 34.8105 5807.8 3770*2 62.33

125 34.7142 5845.8 3802.5 62.63

126 34.6182 5883.7 3834.8 62.93

127 34.5224 5921.4 3866.9 63.23

128 34*4268 5959.1 3898*8 63*53

129 34.3315 5996.8 3930*8 63*82

130 34.2363 6034.4 3962.6 64.11

131 34.1413 6071.9 3994.4 64.40

132 34.0466 6109.5 4026.2 64.68

133 33.9521 6147.1 4058.0 64.97

134 33.8577 6184,9 4089.9 65.25

135 33.7636 6222.7 4121.9 65,53

136 33.6696 6260.2 4153.6 65.81

137 33.5759 6297.6 4185.0 66.08

138 33.4824 6334.8 4216.4 66.35

139 33*3890 6371.9 4247*5 66.62

140 33*2959 6408.7 4278*4 66.89

141 33.2029 6445.3 4309.1 67.15

142 33.1101 6481.8 4339.6 67.41

143 33.0175 6518.2 4369.9 67 *66

144 32*9251 6554.5 4400*2 67.92

145 32.8329 6590.8 4430.5 68.17

146 32.7408 6627.1 4460*7 68*42

147 32.6489 6663*4 4491.0 68.67

148 32.5572 6699.8 4521*2 68.92

149 32.4657 6736.1 4551.4 69.16

150 32.3744 6772.5 4581 .6 69.41

151 32.2832 6809.1 4612.0 69.66

152 32.1922 6846.2 4642.9 69.90

153 32.1014 6883.3 4673.7 70.14

154 32.0107 6920.3 4704.5 70.39

155 31.9203 6957.4 4735.3 70.62

156 31.8299 6994.4 4766.0 70.86

157 31.7398 7031.4 4796.7 71.10

158 31,6498 7068.4 4827.4 71.33

159 31.5600 7105.4 4858.0 71.57

160 31.4703 7142.4 4888.5 71.80

* PHASE CHANGE 139
K

161 162

1(33 164

165

166

167

168

169

170

171 172

173

174

175

176

177

178

179

180

181 182

183

184

185

186

187

188

189

190

191

192

193

194

195

1 96

197

198

199

200

201

202

203

204

205

206

207

208

209

210

211

212

213

214

215

216

217

218

219

220

221

222

223

224

225

226

227

228

229

230

700.00 ATMOSPHERE ISOBAR

DENSITY enthalpy INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL entropy

MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

31.3808 7179.3 4919.0 72.03 231 25.5393 9698.7 6921 .4 85.04

31.2915 7216.2 4949.5 72.26 232 25*4628 9733.6 6948.0 85.20

31.2023 7253.1 4979.9 72.49 233 25.3865 9768.4 6974.4 85.35

31.1133 7290.0 5010,3 72.71 234 25.3105 9803.2 7000.9 85.49

31.02*5 7326.9 5040.6 72.93 235 25.2347 9838.0 7027.2 85.64

30.9358 7363,7 5070.9 73.16 236 25.1591 9872.7 7053.5 85.79

30.8473 7400.5 5101.1 73.38 237 25.0838 9907.4 7079.7 85.94

30.7589 7437.3 5131.3 73.60 238 25.0086 9942.1 7105.9 86.08

30.6707 7474.1 5161.4 73.82 239 24.9338 9976.7 7132.0 86.23

30.5826 7510.8 5191.5 74.03 240 24.8592 10011.3 7158.1 86.37

30.4947 7547.5 5221.6 74.25 241 24.7848 10045.9 7184.0 86.52

30,4070 7584.2 5251.5 74.46 242 24.7106 10080.4 7210.0 86.66

30.3194 7620.9 5281.5 74.67 243 24.6367 10114.8 7235.8 86.80

30.2320 7657.5 5311.3 74.89 244 24.5631 10149.3 7261.6 86.94

30.1448 7694.1 5341-2 75.10 245 24.4897 10183.7 7287*4 87*08

30.0577 7730.7 5370.9 75.30 246 24.4165 10218.0 7313.1 87.22

29.9707 7767.3 5400.7 75.51 247 24.3436 10252*4 7338.7 87.36

29.8840 7803.8 5430.3 75.72 248 24.2709 10286.6 7364*2 87.50

29.7974 7840*3 5459.9 75.92 249 24*1985 10320.9 7389.7 87.64

29.7109 7876.8 5439,5 76.13 250 24.1264 10355.1 7415.2 87.78

29.6246 7913.3 5519.0 76.33 251 24.0545 10389.2 7440.6 87.91

29.5385 7949.7 5548.5 76.53 252 23.9828 10423.4 7465.9 88.05

29.4525 7986.1 5577.9 76.73 253 23.9114 10457.5 7491.1 88.18

29.3667 8022.5 5607.2 76.93 254 23.8403 10491.5 7516.3 88.32

29.2811 8058.8 5636.5 77.12 255 23.7694 10525.5 7541.5 88.45

29.1956 8095.2 5665.7 77.32 256 23.6988 10559.5 7566.5 88.58

29.1103 8131.5 5694.9 77.51 257 23.6285 10593.4 7591.5 88.72

29.0252 8167.7 5724,0 77.71 258 23.558A 10627.3 7616.5 88.85

28.9402 8204.0 5753.1 77,90 259 23.4886 10661.1 7641.4 88.98

28.8554 8240.2 5782.1 78.09 260 23.4190 10694.9 7666.2 89.11

28.7708 8276.4 5811.1 78.28 261 23.3497 10728.7 7691.0 89,24

28.6863 8312.5 5839.9 78.47 262 23.2806 10762.4 7715.7 89.37

28.6020 8348.7 5868.8 78,66 263 23.2119 10796.1 7740.3 89.50

28.5179 8384,8 5897.6 78,84 264 23.1433 10829.7 7764.9 89.62

28.4340 8420.8 5926.3 79.03 265 23.0751 10863.3 7789.5 89.75

28.3502 8456.9 5955.0 79.21 266 23.0071 10896.9 7813.9 89.88

28.2666 8492.9 5983.6 79.40 267 22.9394 10930.4 7838.3 90.00

28.1832 8528.9 6012.1 79.58 268 22.8720 10963.8 7862.7 90.13

28.1000 8564.8 6040.6 79.76 269 22.8048 10997.3 7887.0 90.25

28.0169 8600*7 6069.1 79.94 270 22.7379 11030.6 7911*2 90.38

27.9340 8636.6 6097.5 80.12 271 22.6712 11064.0 7935.4 90.50

27.8513 8672.5 6125.8 80.30 272 22.6049 11097.3 7959.5 90.62

27.7688 8708.3 6154*0 80*47 273 22*5388 11130.5 7983.5 90.74

27.6865 8744.1 6182.3 80*65 274 22.4729 11163.8 8007.5 90.87

27.6^44 8779.9 6210.4 80.82 275 22.4074 11196.9 8031.5 90.99

27.5224 8815.6 6238.5 81.00 276 22.3421 11230.0 8055.4 9l.ll

27.4406 8851 .4 6266.5 81.17 277 22.2771 11263.1 8079.2 91.23

27.3591 8887.0 6294.5 81.34 278 22.2123 11296.2 8102.9 01,35

27.2777 8922.7 6322*4 81.51 279 22*1479 11329.2 8126.6 91.46

27 . 1965 8958.3 6350-3 81.68 280 22.0837 11362.1 8150.3 01.58

27.1155 8993.9 6378.1 81.85 281 22.0197 11395.6 8173.9 01.70

27*0347 9029*4 6405*8 82*02 282 21*9561 11427*9 8197*4 91*82

26.9542 9065*0 6433*5 82*19 283 21*8927 11460.7 8220*8 91*93

26.8738 9100.5 6461 • 1 82*35 284 21 .8296 11493.5 8244.3 92.05

26.7636 9135.9 6488.7 82.52 285 21.7667 11526.2 8267.6 92.16

26.7136 9171.3 6516.2 82.68 286 21.7041 11558.9 8290.9 02.28

26.6338 9206.7 6543.6 82.85 287 21.6418 11591.6 8314.1 02.39

26.55*2 9242.1 6571.0 83.01 288 21.5798 11624.? 8337.3 92.50

26.4749 9277.4 6598.3 83.17 289 21.5181 11656.7 8360.4 02.62

26.3957 9312.7 6625.6 83.33 290 21.4566 11689.2 8383.5 92.73

26.3168 9348.0 6652.8 83.49 291 21.3954 11721.7 8406.5 92.84

26.2380 9383.2 6679,9 83.65 292 21.3344 11754.1 B4?9 • 5 92.95

26.1595 9418.4 6707.0 83*81 293 21*2737 11786.5 8452.4 93.06

26.0812 9453-5 6734*0 83-97 294 21*2133 11818*8 8475.2 03.17

26.0032 9488*7 6761 • 0 84*12 295 21*1532 11851.1 8498*0 03.28

25*9253 9523 •

8

6787*9 84.28 296 21*0933 11883*4 8520*7 93*39

25.8477 9558.8 6814.7 84.43 297 21.0337 11915.6 8543.4 93.50

25.7702 9593.8 6841.5 84.59 298 20.9744 11947.7 8566.0 93.61

25.6630 9628.8 68b8.2 84.74 299 20.9154 11979.9 8588.6 93.72

25.6161 9663.8 6894.8 84.89 300 20.8566 12011.9 8611.1 93.82

140
800.00 ATMOSPHERE isobar

TEMP. density ENTHALPY internal ENTROPY TEMP. DENSITY ENTHALPY INTERNAL ENTROPY

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K

102.725 37.3220 5162,9 2990,9 54,13

103 37.2953 5174.

o

3000.5 54.24

104 37.1985 5214.5 3035.4 54.63

105 37*1019 5255*0 3070*2 55*02

106 37.0056 5295.4 3104.9 55.40

107 36.9094 5335,7 3139.5 55.78

108 36.8135 5376.0 3174.0 56.15

109 36.7178 5416.1 3208.4 56.52

no 36.6224 5456,1 3242.7 56.89

111 36.5272 5496.0 3276.8 57.25

112 36.4323 5535.8 3310,8 57.61

113 36.3375 5575.4 3344.6 57.96

114 36.2431 5614.9 3378.3 58.31

115 36.1489 5654.2 3411.8 58.65

116 36.0549 5693.4 3445*1 58.99

117 35.9612 5732.3 3478.2 59.32

118 35.8677 5771.2 3511.1 59.65

119 35*7745 5809.8 3543*9 59.98

120 35.6816 5848.3 3576*5 60.30

121 35.5889 5886.6 3608,9 60.62

122 35.4964 5924.8 3641,1 60.93

123 35.4042 5962.8 3673.2 61.24

124 35.3122 6000.6 3705.0 61.55

125 35.2205 6038.4 3736.8 61.85

126 35.1290 6076.0 3768.4 62.15

127 35.0377 6113*5 3799*9 62.45

128 34.9467 6150*9 3831.3 62*74

129 34.8559 6188.2 3862.6 63.03

130 34.7654 6225.5 3893.8 63.32

131 34.6751 6262.7 3925.0 63,61

132 34.5850 6300.0 3956.2 63.89

133 34.4951 6337.3 3987.4 64.17

134 34.4055 6374.7 4018.6 64.45

135 34.3161 6412.2 4050.0 64.73

136 34.2269 6449.4 4081.0 65.01

137 34.1379 6486.4 4111.8 65.28

138 34.0492 6523-3 4142.6 65-54

139 33.9606 6560.0 4173.1 65.81

140 33.8723 6596.5 4203.3 66.07

141 33.7842 6632.8 4233.3 66.33

142 33*6963 6668.8 4263.2 66.59

143 33.6086 6704.8 4292*9 66* 84

144 33.5211 6740.8 4322.5 67.09

145 33.4338 6776.7 4352.1 67,34

146 33.3467 6812.6 4381.7 67.59

147 33.2598 6848.5 4411.3 67.84

148 33.1731 6884.5 4440.9 68.08

149 33,0866 6920.4 4470.4 68.33

150 33.0003 6956.3 4499.9 68.57

151 32.9142 6992.5 4529.7 68.81

152 32.8283 7029.2 4559.9 69.05

153 32.7425 7065.8 4590.1 69.29

154 32.6570 7102.5 4620.2 69.53

155 32.5716 7139.1 4650.3 69.77

156 32.4864 7175.6 4680.4 70.01

157 32.4014 7212.2 4710.4 70.24

158 32.3166 7248.7 4740.3 70.47

159 32.2320 7285.2 4770.3 70.70

160 32.1475 7321.7 4800.1 70.93

phase change 141
800.00 ATMOSPHERE isobar

TEMP. density ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL Entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

j/mol-k

161 32.0633 7358.1 4829.9 71.16 231 26.5914 9831.9 6783.5 83.94

162 31.9792 7394.6 4859.7 71.38 232 26.5197 9866.1 6809.4 84.09

163 31.8952 7431.0 4889.4 71.61 233 26.4481 9900.2 6835.3 84.23

164 31*8115 7467.3 4919.1 71*83 234 26.3768 9934.3 6861 • 1 84.38

165 31.7279 7503.7 4948.7 72.05 235 26.3057 9968.3 6886.8 84.52

166 31.6445 7540.0 4978.3 72.27 236 26.2348 10002.4 6912.5 84.67

167 31.5613 7576.3 5007.8 72.49 237 26.1640 10036.4 693e . 1 84.81

168 31.4782 7612.5 5037.3 72.70 238 26.0935 10070.3 6963.7 84.96

169 31.3953 7648.7 5066.8 72*92 239 26-0232 10104.2 6989*2 85.10

170 31.3126 7684.9 5096.1 73.13 240 25.9531 10138.1 7014.7 85.24

171 31.2301 7721.1 5125.4 73.34 241 25.8832 10171.9 7040.1 85.38

172 31.1477 7757.2 5154.7 73.55 242 25.8135 10205.8 7065.5 e5.52

173 31.0655 7793.3 5183.9 73.76 243 25,7440 10239.5 7090,8 85.66

174 30.9834 7829.4 5213.1 73.97 244 25.6748 10273.3 7116.0 85.80

175 30.9016 7865.4 5242.2 74.18 245 25.6057 10307.0 7141.2 85.94

176 30.8199 7901.5 5271.3 74.38 246 25.5368 10340.6 7166*3 86*07

177 30.7383 7937.4 5300*3 74.59 247 25.4682 10374.3 7191.4 86.21

178 30.6570 7973.4 5329.2 74.79 248 25.3998 10407.9 7216.4 86.35

179 30.5758 8009.3 5358.1 74.99 249 25.3316 10441.4 7241.4 86.48

180 30.4947 8045.2 5387.0 75.19 250 25.2636 10475*0 7266*3 86.61

181 30.4139 8081.0 5415.7 75.39 251 25.1958 10508.5 7291.2 86.75

182 30.3332 8116.9 5444.5 75.59 252 25.1282 10541.9 7316.0 86.88

183 30.2526 8152.7 5473.2 75.78 253 25.0609 10575.3 7340.7 87.01

184 30.1723 8188.4 5501.8 75.98 254 24.9937 10608.7 7365.4 87.15

185 30.0921 8224.1 5530.3 76.17 255 24.9268 10642.1 7390.0 87.28

186 30.0120 8259.8 5558.9 76.36 256 24.8601 10675.4 7414.6 87.41

187 29.9322 8295.5 5587.3 76.56 257 24.7936 10708.6 7439.2 87.54

188 29.8525 8331*1 5615.7 76.75 258 24*7274 10741 .9 7463*6 87.67

189 29.7729 8366*7 5644 * 0 76*93 259 24*6613 10775-1 7488*1 87.79

190 29.6936 8402.3 5672.3 77.12 260 24.5955 10808.2 7512.4 87.92

191 29.6144 8437.8 5700.6 77.31 261 24.5299 10841.4 7536.7 88.05

192 29.5353 8473*3 5728.7 77.49 262 24.4645 10874.4 7561-0 88*18

193 29*4565 8508*8 5756*9 77*68 263 24*3993 10907.5 7585*2 88*30

194 29.3778 8544-2 5784.9 77.86 264 24*3344 10940*5 7609.3 88.43

195 29,2993 8579.6 5812.9 78.04 265 24.2697 10973,5 7633.4 88.55

196 29.2209 8615.0 5840.9 78.22 266 24.2052 11006.4 7657.5 88.68

197 29.1428 8650.3 5868.8 78.40 267 24.1409 11039.3 7681.5 88.80

198 29.0648 8685*6 5896*6 78.58 268 24.0769 11072*2 7705*4 88.92

199 28.9869 8720*9 5924*4 78.76 269 24*0131 11105*0 7729*3 89*04

200 28.9093 8756.1 5952.1 78.94 270 23.9495 11137.8 7753.1 89.17

201 28.8318 8791.3 5979.8 79.11 271 23.8861 11170.6 7776.9 89.29

202 28 . 75^5 8826.5 6007.4 79.29 272 23.8230 11203.3 7800.6 89.41

203 28.6773 8861.7 6035.0 79.46 273 23.7601 11236.6 7824.3 89.53

204 28.6004 8896.8 6062.5 79.63 274 23.6974 11268.6 7847.9 89.65

205 28.5236 8931.8 6089.9 79.80 275 23.6349 11301*2 7871.5 89.77

206 28.4470 8966.9 6117.3 79.98 276 23.5727 11333.8 7895.0 89.88

207 28.3705 9001.9 6144.6 80.14 277 23.5107 11366.3 7918.4 90.00

208 28.2943 9036.8 6171.9 80.31 278 23.4489 11398.8 7941.8 90.12

209 28.2182 9071.8 6199.1 80*48 279 23.3874 11431.3 7965*2 90.24

210 28.1423 9106.7 6226.3 80.65 280 23*3260 11463.7 7988.5 90*35

211 28.0666 9141.6 6253,4 80.81 281 23.2649 11496.1 8011.8 90.47

212 27.9910 9176.4 6280.4 80.98 282 23.2041 11528.4 8035.0 90.58

213 27.9157 9211.2 6307.4 81*14 283 23*1434 11560.7 8058*1 90*70

214 27.8405 9246.0 6334.3 81*30 284 23*0830 11593.6 8081*2 90*81

215 27.7655 9280*7 6361*2 81.47 285 23*0228 11625*2 8104.2 90.92

216 27.6907 9315.4 6388 * 0 81*63 286 22*9629 11657.4 8127*2 9l *04

217 27.6161 9350.1 6414.8 81.79 287 22.9032 11689.5 8150.2 91.15

218 27.5417 9384.7 6441.5 81.95 288 22.8437 11721.6 8173,1 91.26

219 27.4674 9419.3 6468.1 82,11 289 22.7844 11753.7 8195.9 01.37

220 27.3934 9453.9 6494,7 82.26 290 22.7254 11785.7 8218.7 91.48

221 27.3195 9488.4 6521.2 82.42 291 22.6666 11817.7 8241.5 91.59

222 27.2458 9522.9 6547.7 82.57 292 22.6080 11849.7 8264.2 91 .70

223 27.1723 9557 •

4

6574.1 82.73 293 22.5496 11881.6 8286.8 91.81

224 27.0990 9591.8 6600.5 82.88 294 22.4915 11913.5 8309.4 91.92

225 27 . n?59 9626.2 6626.8 83.04 295 22.4336 11945.4 8331.9 92.03

226 26.9530 9660.6 6653.1 83.19 296 22.3759 11977.2 8354.4 92.13

227 26.8803 9694.9 6679.3 83.34 297 22.3185 12008.9 8376.9 92.24

228 26.8078 9729.2 6705.4 83.49 298 22.2613 12040.7 8399.3 02.35

229 26.7355 9763.5 6731.5 83.64 299 22.2043 12072.3 8421 .6 92.45

230 26 . 6633 9797.7 6757.5 83.79 300 22.1475 12104.0 8443.9 92.56

142
<300.00 atmosphere isobar

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY ENTHALPY INTERNAL Entropy

K MOL/LITER J/MOL ENERGY

J/MOL

J/MOL-K K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K

1 0^ 1 944 37.4995 5452.0 3020*1 54.31

105 37.4943 5454.2 3022.0 54.33

106 37*4014 5494.5 3056.2 54.71

107 37.3088 5534.6 3090.3 55.09

108 37*2164 5574.6 3124*3 55.46

109 37.1243 5614.6 3158.1 55.83

no 37.0324 5654.4 3191.9 56.19

111 36.9408 5694.2 3225.5 56.55

112 36.8494 5733.7 3258.9 56.90

113 36*7583 5773*2 3292.2 57.26

114 36.6675 5812*5 3325*4 57.60

115 36*5769 5851*6 3358*4 57*94

116 36.4866 5890.6 3391.1 58.28

117 36.3966 5929.4 3423,8 58.61

118 36.3069 5968.0 3456.2 58.94

119 36.2174 6006.4 3488.5 59.27

120 36.1282 6044.7 3520.5 59.59

121 36.0392 6082.9 3552.4 59.90

122 35.9505 6120.8 3584.1 60.22

123 35.8621 6158.6 3615.7 60.52

124 35.7739 6196.3 3647.1 60.83

125 35.6860 6233.8 3678.3 61.13

126 35.5983 6271.2 3709.4 61.43

127 35-5109 6308.5 3740.4 61.72

128 35.4238 6345.7 3771*3 62*02

129 35.3369 6382.8 3802.1 62.30

130 35.2502 6419.9 3832.8 62.59

131 35.1638 6456.9 3863.5 62.87

132 35.0776 6493.9 3894.1 63.16

133 34.9917 6531.0 3924.8 63.44

134 34.9060 6568,2 3955.6 63.71

135 34.8206 6605.4 3986.4 63.99

136 34.7354 6642.3 4016.9 64.26

137 34.6504 6679.1 4047.3 64.53

138 34.5657 6715.8 4077.4 64,80

13R 34.4811 6752.2 4107.4 65.06

140 34.3969 6788.4 4137.2 65.32

141 34.3128 6824.4 4166.7 65.58

142 34.2289 6860.2 4196.0 65.83

143 34.1453 6896.0 4225.2 66.08

144 34.0619 6931.6 4254.3 66.33

145 33.9787 6967.2 4283.3 66.58

146 33.8957 7002.9 4312.4 66.83

147 33.8129 7038.5 4341*5 67.07

148 33.7304 7074.2 4370.6 67.32

149 33*6480 7109.8 4399.5 67.56

150 33.5658 7145.4 4428.5 67.80

151 33.4839 7181.3 4457.7 68.04

152 33*4021 7217.6 4487.4 68.28

153 33.3206 7253.9 4517.0 68.52

154 33.2392 7290.2 4546.6 68.76

155 33.1581 7326.5 4576.2 68.99

156 33.0771 7362.7 4605.7 69.22

157 32.9963 7398.9 4635.2 69.45

158 32.9157 7435.1 4664.6 69.68

159 32.8353 7471.3 4693.9 69.91

160 32.7551 7507.4 4723.3 70.14

* PHASE CHANGE

143
900.00 ATMOSPHERE ISOBAR

TEMP. DENSITY enthalpy INTERNAL ENTROPY TEMP. DENSITY ENTHA4.PY INTERNAL entropy

K mol/liter J/MOL ENERGY

J/MOL

J/MOL-K K MOL/LITER J/MOL ENFRGY

J/MOL

j/mol-k

161 32.6751 7543.5 4752.5 70.36 231 27.5006 9983.1 6667.0 82.97

162 32.5953 7579.5 4781.7 70.59 232 27.4327 10016.7 6692.4 83.12

163 32.5156 7615.6 4810.9 70.81 233 27.3650 10050.3 6717.7 83.26

164 32.4362 7651.5 4840.0 71.03 234 27.2975 10083.8 6743.0 83.41

165 32.3569 7687.5 4869.1 71.25 235 27.2302 10117.3 6768.3 83.55

166 32.2778 7723.4 4898,1 71.46 236 27.1631 10150.8 6793.5 83.69

167 32.1988 7759.3 4927.1 71.68 237 27.0962 10184.2 6818.6 83.83

168 32.1201 7795.2 4956.0 71.89 238 27.0294 10217.6 6843.7 83.97

169 32.0415 7831.0 4984.9 72.11 239 26.9628 10251.6 6868.7 84.11

170 31.9631 7866.8 5013.7 72,32 240 26.8964 10284.3 6893.7 84.25

171 31.8849 7902.6 5042.4 72.53 241 26.8302 10317.6 6918.7 84,39

172 31.8069 7938.3 5071.1 72.74 242 26.7641 10350,9 6943.5 84.53

173 31.7290 7974.0 5099.8 72.94 243 26.6983 10384.1 6968.4 84,66

174 31.6513 8009.6 5128.4 73.15 244 26,6326 10417.3 6993.1 84.80

175 31.5738 8045*2 5156.9 73.35 245 26*5671 10450*5 7017.9 84.94

176 31.4964 8080.8 5185.4 73.56 246 26.5018 10483.6 7042.5 85.07

177 31.4192 8116.4 5213.8 73.76 247 26,4367 10516,7 7067.2 85.21

178 31.3422 8151.9 5242.2 73.96 248 26,3718 10549.8 7091.7 85.34

179 31.2654 8187.4 5270.5 74.16 249 26.3071 10582.8 7116.2 85,47

180 31.1887 8222.8 5298.8 74.35 250 26.2425 10615.8 7140.7 85.60

181 31.1122 8258.2 5327.0 74.55 251 26.1782 10648.7 7165.1 85.74

182 31.0358 8293.6 5355.2 74.74 252 26.1140 10681.7 7189.5 85.87

183 30.9597 8328.9 5383.3 74.94 253 26.0500 10714.6 7213.8 86.00

184 30.8837 8364.2 5411.3 75.13 254 25.9862 10747.4 7238.1 86.13

185 30.8078 8399.5 5439.3 75.32 255 25.9226 10780.2 7262.3 86.26

186 30.7321 8434.7 5467.3 75,51 256 25.8592 10813.6 7286.4 86.38

187 30.6566 8469.9 5495.1 75.70 2*7 25.7960 10845.8 7310.6 86.51

188 30.5813 8505.0 5523*0 75.89 258 25.7330 10878.5 7334.6 86.64

189 30.5061 8540.1 5550.7 76.07 259 25.6701 10911.2 7358.6 86.77

190 30.4311 8575.2 5578.5 76.26 260 25.6075 10943.9 7382.6 86.89

191 30.3563 8610,3 5606.1 76.44 261 25.5450 10976.5 7A06.5 87.02

192 30.2816 8645,3 5633.7 76.63 262 25.4828 11009.1 7430.4 87.14

193 30.2071 8680.2 5661.3 76.81 263 25.4207 11041.6 7454.2 87.27

194 30,1328 8715.2 5688.8 76.99 264 25.3588 11074.1 7477.9 87.39

195 30.0586 8750.1 5716.2 77.17 265 25.2971 11106.6 7501.7 87.51

196 29.9846 8785.0 5743.6 77.35 266 25*2356 11139.1 7525*3 87.63

197 29.9107 8819.8 5770.9 77.52 267 25.1743 11171.5 7548.9 87.76

198 29.8371 8854,6 5798.1 77.70 268 25.1132 11203.8 7572.5 87.88

199 29.7636 8889.3 5825.4 77.87 269 25.0523 11236.2 7596.0 88.00

200 29.6902 8924.1 5852.5 78.05 270 24,9916 11268.5 7619.5 88.12

201 29.6170 8958.7 5879.6 78.22 271 24.9311 11300.8 7642.9 88.24

202 29.5440 8993.4 5906.7 78.39 272 24.8708 11333.0 7666.3 88.35

203 29.4712 9028.0 5933.6 78.56 273 24.8107 11365.2 7689.6 88.47

204 29.3985 9062.6 5960.6 78.73 274 24.7507 11397.4 7712.9 88.59

205 29.3260 9097.1 5987.4 78.90 275 24.6910 11429.5 7736.1 88.71

206 29.2536 9131.7 6014.3 79.07 276 24.6315 11461*7 7759.3 88.82

207 29.1815 9166.1 6041.0 79*24 277 24.5721 11493*7 7782.4 88.94

208 29.1095 9200.6 6067.7 79.40 27R 24.5130 11525.8 7805.5 89.06

209 29.0376 9235.0 6094.4 79.57 279 24.4540 11557.8 7828.5 89.17

210 28,9660 9269.3 6121.0 79.73 280 24.3953 11589.7 7851.5 89.29

211 28.8945 9303.7 6147.5 79.90 281 24.3367 11621.7 7874.5 89.40

212 28.8231 9338.0 6174.0 80.06 282 24.2784 11653.6 7897.4- 89.51

213 28.7520 9372.2 6200.5 80.22 283 24.2202 11685.4 7920.2 89.63

214 28.6810 9406.5 6226.8 80.38 2«4 24.1622 11717.3 7943.0 89.74

215 28.6101 9440.7 6253.2 80.54 285 24.1045 11749.1 7965.8 89.85

216 28.5395 9474.8 6279.4 80.70 286 24.0469 11780.8 7988.5 89.96

217 28.4690 9S09.0 6305.7 80.85 287 23.9895 11812.6 8011.1 90.07

218 28.3987 9543.0 6331.8 81.01 288 23.9324 11844.3 8033.7 90.18

219 28.3286 9577.1 6357.9 81.17 289 23.8754 11875.9 8056.3 90.29

220 28.2586 9611.1 6384.0 81.32 290 23.8186 11907.5 8078.8 90.40

221 28.1888 9645.1 6410.0 81.48 291 23.7620 11939.1 8101.3 90,51

222 28.1192 9679.1 6435.9 81.63 292 23.7057 11970.7 8123.7 90.62

223 28,0498 9713.0 6461.8 81.78 293 23.6495 12002.2 8146.1 90.73

224 27.9805 9746.9 6487.6 81.93 294 23.5935 12033.7 8168.5 90.83

225 27.9114 9780.7 6513.4 82.08 295 23.5377 12065.2 8190.8 90.94

226 27.8425 9814.5 6539*1 82*23 296 23.4821 12096.6 8213*0 91*05

227 27.7737 9848.3 6564.8 82.38 297 23.4267 12128.6 8235.2 91.15

228 27.7052 9882.0 6590.4 82.53 298 23.3715 12159.3 8257.4 91.26

229 27.6368 9915.8 6616.0 82.68 299 23.3165 12190.7 8279.5 91.36

230 27.5686 9949.4 6641.5 82.83 300 23.2617 12221.9 8301.6 91.47

144
1000.00 ATMOSPHERE ISOBAR

TEMP. DENSITY ENTHALPY INTERNAL ENTROPY TEMP. DENSITY enthalpy INTERNAL ENTROPY

K MOL/LITER J/MOL energy

J/MOL

J/MOL-K K MOL/LITER J/MOL ENERGY

J/MOL

j/mol-k

107.135 37.6708 5740.1 3050.3 54.48

108 37.5936 5774.6 3079.3 54.80

109 37.5046 5814.4 3112.7 55.17

110 37.4158 5854.1 3146»0 55.53

111 37.3274 5893.7 3179.1 55.89

112 37.2392 5933.1 3212.2 56.24

113 37.1512 5972.5 3245.0 56.59

114 37.0636 6011.6 3277.7 56.94

115 36.9762 6050.6 3310.3 57.28

116 36.8891 6089.4 3342.6 57.61

117 36.8023 6128.1 3374,8 57.95

118 36.7158 6166.6 3406.8 58.27

119 36.6295 6204.9 3438.6 58.60

120 36.5435 6243.1 3470.3 58,92

121 36.4578 6281.1 3501.7 59.23

122 36.3724 6318.9 3533.0 59.54

123 36.2873 6356.5 3564.2 59.85

124 36.2024 6394.1 3595.1 60.15

125 36.1178 6431.4 3625.9 60.45

126 36.0334 6468.7 3656.6 60.75

127 35.9493 6505.8 3687.2 61.04

128 35.8655 6542.8 3717.6 61.34

129 35.7819 6579.8 3748.0 61.62

130 35.6986 6616.7 3778.3 61.91

131 35.6156 6653.6 3808.5 62.19

132 35.5328 6690.4 3838.8 62.47

133 35.4502 6727.4 3869.1 62.75

134 35.3679 6764.3 3899.4 63.03

135 35.2859 6801,4 3929.8 63.30

136 35.2041 6838.2 3959,9 63,57

137 35.1225 6874.7 3989.8 63.84

138 35.0412 6911.2 4019.5 64.11

139 34.9601 6947.5 4049.1 64,37

140 34.8792 6983.5 4078.4 64.63

141 34.7986 7019.3 4107.5 64.88

142 34.7182 7054.9 4136.3 65.13

143 34.6380 7090.4 4165.1 65.38

144 34.5581 7125.9 4193.8 65.63

145 34.4783 7161.3 4222.4 65.88

146 34.3988 7196.7 4251.0 66.12

147 34.3195 7232.1 4279.7 66.37

148 34.2405 7267.6 4308.3 66.61

149 34.1616 7302.9 4336.8 66.85

150 34.0830 7338,3 4365.3 67.09

151 34.0045 7374.6 4394.1 67.33

152 33.9263 7410.1 4423.4 67.57

153 33.8482 7446.2 4452.6 67.80

154 33.7704 7482.2 4481.7 68.04

155 33.6928 7518.2 4510.8 68.27

156 33.6154 7554.2 4539.9 68.50

157 33.5381 7590.2 4568.9 68.73

158 33.4611 7626,

f

4597.9 68.96

159 33.3843 7662.0 4626.8 69.19

160 33.3076 7697.8 4655.6 69.41

PHASE CHANGE 145
1000.00 ATMOSPHERE isobar

TEMP.

K DENSITY

mol/liteR

enthalpy

J/MOL

internal

ENERGY

J/MOL

ENTROPY

J/MOL-K

TEMP.

K DENSITY

mol/liter

ENTHALPY

J/MOL

INTERNAL

ENERGY

J/MOL

ENTROPY

J/MOL-K

161 33.2312 7733.6 4684.4 69.64 231 28.3025 10146.9 6566.7 82.11

162 33.1549 7769,4 4713.2 69.86 232 28.2379 10180.1 6591.7 82.25

163 33.0788 7805.1 4741.9 70.08 233 28.1734 10213.2 6616.7 82.40

164 33.0029 7840,9 4770.6 70.29 234 28.1091 10246.3 6641.5 82,54

165 32.9272 7876.5 4799.2 70,51 235 28.0450 10279.4 6666.4 82.68

166 32.8517 7912.2 4827.8 70.73 236 27.9810 10312.4 6691.1 82.82

167 32.7764 7947.8 4856,3 70.94 237 27.9172 10345.4 6715,9 82.96

168 32.7012 7983.3 4884.7 71.15 238 27.8536 10378.4 6740.5 83.10

169 32.6262 8018.8 4913.1 71.36 239 27.7901 10411,3 6765.2 83.24

170 32.5514 8054.3 4941.5 71.57 240 27.7268 10444.3 6789.7 83.37

171 32.4768 8089.8 4969.8 71.78 241 27.6637 10477.1 6814.3 83.51

172 32.4024 8125.2 4998.0 71.99 242 27.6007 10510.6 6838.8 83.65

173 32.3281 8160.5 5026.2 72.19 243 27.5379 10542.8 6863.2 83.78

174 32.2540 8195.9 5054.3 72.4o 244 27.4752 10575.5 6887.6 83.91

175 32.1801 8231 .2 5082.4 72.60 245 27.4127 10608.3 6911.9 84.05

176 32.1063 8266.4 5110.4 72.80 246 27.3504 10641.6 6936.2 84.18

177 32,0327 8301.6 5138,4 73.00 247 27,2883 10673.6 6960.4 84,31

178 31.9593 8336.8 5166,3 73.20 248 27.2263 10706.3 6984.6 84.45

179 31.8861 8372.0 5194.2 73.39 240 27.1645 10738.9 7008.7 84.58

100 31.8130 8407.1 5222,0 73.59 250 27.1029 10771.4 7032.8 84.71

181 31.7401 8442.1 5249.7 73.78 251 27.0414 10804.0 7056.8 84.84

182 31.6674 8477.1 5277.4 73.98 252 26.9801 10836,5 7080.8 84.97

183 31.5948 8512.1 5305.0 74.17 253 26.9190 10868.9 7104.8 85.10

184 31.5224 8547.1 5332.6 74.36 254 26.8580 10901.4 7128.7 85.22

185 31.4502 8582.0 5360.1 74.55 255 26.7972 10933.8 7152.5 85.35

186 31.3782 8616.8 5387.6 74.74 256 26.7366 10966.1 7176.3 85.48

187 31.3063 8651.7 5415.0 74.92 257 26.6762 10998.5 7200.1 85.60

188 31.2345 8686.5 5442.4 75.11 258 26.6159 11030.8 7223.8 85.73

189 31.1629 8721.2 5469.7 75.29 259 26.5558 11063.1 7247.4 85.85

1 90 31.0915 8755.9 5496.9 75.48 260 26.4959 11095.3 7271.0 85.98

191 31.0203 8790.6 5524.1 75.66 261 26.4361 11127.5 7294.6 86.10

192 30.9492 8825.2 5551.2 75.84 262 26.3765 11159.7 7318.1 86.23

193 30.8783 8859.8 5578.3 76.02 263 26,3171 11191,8 7341.6 86.35

194 30,8075 8894.4 5605.3 76.20 264 26.2578 11223.9 7365.0 86.47

195 30.7369 8928.9 5632,3 76.37 265 26.1988 11256.0 7388.4 86.59

196 30.6665 8963.4 5659.2 76.55 266 26.1399 11288.1 7411.7 86.71

197 30.5962 8997.8 5686*0 76.73 267 26.0811 11320.1 7435.0 86.83

198 30*5261 9032*2 5712*8 76*90 268 26*0226 11352*1 7458*2 86*95

199 30,4562 9066.6 5739.6 77.07 269 25.9642 11384.0 7481.4 87.07

200 30.3864 9100.9 5766,3 77.25 270 25.9060 11415.9 7504.6 87.19

201 30.3167 9135.2 5792,9 77.42 271 25,8479 11447.8 7527.7 87.31

202 30.2473 9169.5 5819,5 77.59 272 25.7901 11479.7 7550.7 87.42

203 30.1780 9203.7 5846.0 77.76 273 25.7324 11511.5 7573.7 87.54

204 30.1088 9237*8 5872*5 77.92 274 25.6748 11543.3 7596*7 87.66

205 30.0398 9272.0 5898.9 78.09 275 25.6175 11575.0 7619.6 87.77

206 29.9710 9306.1 5925.2 78.26 276 25,5603 11606.7 7642.5 87.89

207 29.9023 9340.2 5951.5 78.42 277 25.5033 11638.4 7665.3 88.00

208 29.8338 9374.2 5977.8 78,59 278 25.4465 11670.1 7688.1 88.12

209 29.7655 9408.2 6004.0 78.75 279 25.3899 11701.7 7710.9 88.23

210 29.6973 9442.1 6030.1 78.91 280 25.3334 11733.3 7733.6 88.34

211 29.6293 9476.1 6056.2 79.07 281 25.2771 11764.9 7756.2 88.46

212 29.5614 9509.9 6082.2 79.23 282 25.2210 11796.4 7778.8 88.57

213 29.4937 9543,8 6108.2 79.39 283 25.1650 11827.9 7801.4 88.68

214 29.4261 9577.6 6134.1 79.55 284 25.1092 11859.4 7823.9 88,79

215 29.3587 9611.4 6160.0 79.71 285 25.0536 11890.8 7846.4 88.90

216 29,2915 9645.1 6185.8 79.86 286 24.9982 11022.2 7868.8 89.01

217 29.2245 9678.8 6211.6 80.02 287 24.9429 11953.6 7891.2 89.12

218 29,1576 9712.5 6237.3 80.17 288 24.8878 11985.0 7913.6 89.23

219 29.0908 9746.1 6262.9 80.33 289 24.8329 12016.3 7935.9 89.34

220 29.0242 9779.7 6288.6 80.48 290 24.7782 12047.6 7958.2 89.45

221 28.9578 9813.3 6314.1 80.63 291 24,7237 12078.8 7980.4 89,55

222 28.8916 9846.8 6339.6 80.78 292 24.6693 12110.0 8002.6 89.66

223 28.8255 9880.3 6365.0 80.93 293 24.6151 12141.2 8024.7 89.77

224 28.7595 9913.7 6390.4 81.08 294 24.5610 12172.4 8046.8 89,87

225 28.6938 9947.1 6415.8 81.23 295 24.5072 12203.5 8068.9 89.98

226 28.6281 9980.5 6441.1 81.38 296 24.4535 12234.6 8090.9 90.08

227 28.5627 10013.9 6466.3 81,53 297 24.4000 12265.6 8112.9 90.19

228 28.4974 10047,2 6491,5 81.68 298 24.3466 12296.7 8134.8 90.29

229 28.4323 10080.5 6516.6 81.82 299 24.2935 12327.7 8156.7 90.40

230 28.3673 10113.7 6541.7 81.97 300 24.2405 12358.6 8178.5 90.50

146
Announcement of New Publications on

Standard Reference Data

Superintendent of Documents,

Government Printing Office,

Washington, D.C. 20402

Dear Sir:

Please add my name to the announcement list of new publications to be

issued in the series: National Standard Reference Data Series — National Bureau

of Standards.

Name

Company

Address

City State Zip Code

(Notification Key N337)

U. S. GOVERNMENT PRINTING OFFICE : 1969 O -



NATIONAL BUREAU OF STANDARDS

The National Bureau of Standards1 was established by an act of Congress March 3,

1901. Today, in addition to serving as the Nation’s central measurement laboratory,

the Bureau is a principal focal point in the Federal Government for assuring maximum application of the physical and engineering sciences to the advancement of technology in industry and commerce. To this end the Bureau conducts research and

provides central national services in three broad program areas and provides central national services in a fourth. These are: (1) basic measurements and standards,

(2) materials measurements and standards, (3) technological measurements and

standards, and (4) transfer of technology.

The Bureau comprises the Institute for Basic Standards, the Institute for Materials

Research, the Institute for Applied Technology, and the Center for Radiation Research.

THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the

United States of a complete and consistent system of physical measurement, coor- dinates that system with the measurement systems of other nations, and furnishes

essential services leading to accurate and uniform physical measurements throughout

the Nation’s scientific community, industry, and commerce. The Institute consists

of an Office of Standard Reference Data and a group of divisions organized by the

following areas of science and engineering

:

Applied Mathematics—Electricity—Metrology—Mechanics—Heat—Atomic Physics—Cryogenics2—Radio Physics2—Radio Engineering2—Astrophysics2—Time

and Frequency.2 THE INSTITUTE FOR MATERIALS RESEARCH conducts materials research leading to methods, standards of measurement, and data needed by industry, commerce,

educational institutions, and government. The Institute also provides advisory and

research services to other government agencies. The Institute consists of an Office of

Standard Reference Materials and a group of divisions organized by the following areas of materials research:

Analytical Chemistry—Polymers—Metallurgy — Inorganic Materials — Physical

Chemistry.

THE INSTITUTE FOR APPLIED TECHNOLOGY provides for the creation of appropriate opportunities for the use and application of technology within the Federal Government and within the civilian sector of American industry. The primary functions

of the Institute may be broadly classified as programs relating to technological measurements and standards and techniques for the transfer of technology. The Institute

consists of a Clearinghouse for Scientific and Technical Information,3 a Center for

Computer Sciences and Technology, and a group of technical divisions and offices

organized by the following fields of technology:

Building Research—Electronic Instrumentation — Technical Analysis — Product

Evaluation—Invention and Innovation— Weights and Measures —Engineering

Standards—Vehicle Systems Research.

THE CENTER FOR RADIATION RESEARCH engages in research, measurement,

and application of radiation to the solution of Bureau mission problems and the

problems of other agencies and institutions. The Center for Radiation Research consists of the following divisions:

Reactor Radiation—Linac Radiation—Applied Radiation—Nuclear Radiation.

1 Headquarters and Laboratories at Gaithersburg, Maryland, unless otherwise noted ; mailing address Washington, D. C. 20234.

2 Located at Boulder, Colorado 80302.

3 Located at 6285 Port Royal Road, Springfield, Virginia 22161.
U.S. DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20230

OFFICIAL BUSINESS