### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information**

Parent Company

Name:

Address:

City:

Country: USA

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: Atlanta 115 Perimeter Center Place Axiall Corporation

225-685-2677

dave.goldsm ith@axiall.com Plaquem ine

P.O. Box 629

Plaquem ine

Dave Goldsmith

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: GA Zip Code: 30346

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 5848

State: LA Zip Code: 70765-0629

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER**

Process Unit ID: P-1

Process Equipment ID: U-156 Wastewater Feed Rate (lb/hr): 20,648 Feed Temperature (°F): 183 Feed Inlet Pressure (psia): 17 Liquid Loading Rate (liters/m2): 38 SteamFeed Rate (lb/hr): 1040 Steamto Feed Ratio (kg steam/liter of wastewater): 0.049 Operating Temperature (°F): 220 Operating Pressure (psig): 2.2 Total Number of Stages: 1 Overall Calculated Tray Efficiency: Stripping Factor: Flow configuration (countercurrent, cocurrent): countercurrent Number of Actual Trays: 10 Colum n Height (meters): 7.2

Year Equipm ent Installed: 1981 Equipm ent Currently

Regulated Under (cite regulations): 40 CFR 61+63 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions**

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessaryPlease also provide the stripper feed rate in liters per hour, or liters for batch strippers: 9663 liters/hour liters

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

13,627 liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

**PVC Process Unit ID**  **Name of PVC Process Wastewater Stream PVC Process**  **Wastewater Stream ID**  **2 Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System**  **1 2**  **3 4**  **5 6** 

**Min** P-1 U-156 SteamStripping Continuous W-4 28,800

**Table 3. PVC Process Wastewater Destination Codes Table**

Wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System**
**2 3** 

**Min Ma** **x Ty** **pe of Process Wastewater**  **Treatment System**

**Destination Description PVC Process**  **Wastewater Treatment**  **System ID PVC Process**  **Unit ID PVC Process**  **Wastewater Stream ID**  **Is this**
**process wastewater**  **treatment system batch**  **or continuous operation?** 

**1**

**Process Wastewater Stream Flow Rate (gallons per day)**  **Source of Process Wastewater Stream PVC Process Wastewater Stream Flow Rate** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage Operating Days Per**  **Year Flow Rate**  **Determination Me** **thod PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) 7**  **8 9**  **10 11** 

**Ma x**  **Av erage**  86,400 61,265 Measured 350 WWT

**Code**
WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System**
**4 5**  **6 7** 

**Av erage**  **PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **Operating Days Per Year** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**Process Wastewater Stream Flow Rate**

**(gallons per day) Flow Rate**  **Determination Me** **thod PVC Process**  **Wastewater Treatment**  **System ID PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Flow Rate**  **Determination Me** **thod**

**Operating Days Per Year** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

**Originating PVC Process Equipment Description**  **Originating PVC Process Equipment ID** **12 13** 

biosystem Yes

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recycled **As sociated Destination**  **Information**

(Refer to Table 3 below) **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 11**  **12**

**PVC Process Wastewater Stream Destination Code** 

(Refer to Table 3 below) **As sociated Destination Information** **14**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 13** 

**Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? If your response in Column 3 is "Other" then please provide a description of the process wastewaetr** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P** 

107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethylpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethylene) 1330207 Xylenes (isomers and mixtures) 179601231 m,p-xylene 95476 o-xylene

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

Axiall Corporation Plaquem ine U-156

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?** 

SW-846-8015C 0.6 Non-detect SW-846-8015C 156 SW-846-8315A 4.15 SW-846-8315A 17.7 SW-846-8270D 0.0631 Non-detect SW-846-8270D 3.96 SW-846-8270D 0.103 Non-detect SW-846-8270D 1.68 SW-846-8270D 0.0349 Non-detect SW-846-8260B 0.00092 Non-detect SW-846-8260B 0.0024 Non-detect SW-846-8260B 0.0045 Non-detect SW-846-8260B 0.00047 Non-detect SW-846-8260B 0.00046 Non-detect SW-846-8260B 0.00109 Non-detect SW-846-8260B 0.0033 Non-detect SW-846-8260B 0.00205 SW-846-8260B 0.0732 SW-846-8260B 0.00058 Non-detect SW-846-8260B 0.00318 SW-846-8260B 0.00116 Non-detect SW-846-8260B 0.00751 SW-846-8260B 0.00418 Non-detect SW-846-8260B 0.0167 Non-detect **Sample Date -->** suspension

**Lab Sample ID --> Lab Report ID -->**  **An alysis Date -->**  **Stream Temperature (degrees F) --> Stream Flow Rate (gallons per minute) -->**  **Resin Type (suspension, dispersion, bulk, etc.) -->**

54 50.3 01/14/13

Stripper Bottoms W astewater 13-015-0214 01/17/13 **Flow Rate Determination Method -->** MeasuredSW-846-8260B 0.00049 Non-detect

SW-846-8260B 0.00138 Non-detect SW-846-8260B 0.00044 Non-detect SW-846-8260B 0.00067 Non-detect SW-846-8260B 0 EPA Method 107 1.47 SW-846-8260B 0.00071 Non-detect SW-846-8260B 0.0007 Non-detect SW-846-8260B 0.00124 Non-detect SW-846-8260B 0.00072 Non-detect1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 0.2 Non-detect 2.28 14.8 0.0664 Non-detect 3.94 0.109 Non-detect 2.52 0.0367 Non-detect 0.00009 Non-detect 0.00024 Non-detect 0.00045 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.0001 Non-detect 0.00033 Non-detect 0.00068 0.0171 0.00005 Non-detect 0.00111 0.00011 Non-detect 0.00336 0.00041 Non-detect 0.00167 Non-detect 01/22/13

Stripper Bottoms W astewater **1 2** 

58 50.2 01/15/13

13-016-0205 Measured Measured0.00004 Non-detect 0.00013 Non-detect 0.00004 Non-detect 0.00006 Non-detect 0 0.478 0.00007 Non-detect 0 Non-detect 0.00012 Non-detect 0.00007 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 1.3 Non-detect 0.2 Non-detect 135 3.2 0.885 16.5 0.923 0.0678 Non-detect 0.0709 Non-detect 5.73 6.7 0.111 Non-detect 0.116 Non-detect 3.56 2.43 0.0375 Non-detect 0.0392 Non-detect 0.00009 Non-detect 0.00009 Non-detect 0.00024 Non-detect 0.00024 Non-detect 0.00045 Non-detect 0.00045 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.0001 Non-detect 0.0001 Non-detect 0.00033 Non-detect 0.00033 Non-detect 0.00054 0.00206 0.0192 0.047 0.00005 Non-detect 0.00005 Non-detect 0.00154 0.00215 0.00011 Non-detect 0.00011 Non-detect 0.00516 0.00226 0.00041 0.00041 Non-detect 0.00167 Non-detect 0.00167 Non-detect 01/22/13

Stripper Bottoms W astewater Stripper Bottoms W astewater **3**

42 49 49.7 41.6 01/17/13 01/16/13

01/21/13 13-017-0227 13-018-0209 Measured Measured0.00004 Non-detect 0.00004 Non-detect

0.00013 Non-detect 0.00013 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.00006 Non-detect 0.00006 Non-detect 0 0 0.486 0.638 0.00007 Non-detect 0.00007 Non-detect 0 Non-detect 0 Non-detect 0.00012 Non-detect 0.00012 Non-detect 0.00007 Non-detect 0.00007 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 0.2 Non-detect 3.24 17.2 0.0709 Non-detect 5.77 0.116 Non-detect 3.8 0.0392 Non-detect 0.00009 Non-detect 0.00024 Non-detect 0.00045 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.0001 Non-detect 0.00033 Non-detect 0.00346 0.1 0.00005 Non-detect 0.00498 0.00011 Non-detect 0.00618 0.00041 Non-detect 0.00167 Non-detect Stripper Bottoms W astewater **4 5** 

53 42.6 01/18/13

01/21/13 13-021-0233 Measured Measured0.00004 Non-detect 0.00013 Non-detect 0.00004 Non-detect 0.00006 Non-detect 0 1.99 0.00007 Non-detect 0 Non-detect 0.00012 Non-detect 0.00007 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

3.2 Non-detect 3.2 Non-detect 357 414 12.7 15.4 8.18 4.6 0.0671 Non-detect 0.0644 Non-detect 4.9 6.16 0.11 Non-detect 0.105 Non-detect 7.55 2.39 0.0371 Non-detect 0.0356 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.0033 Non-detect 0.00402 0.00057 Non-detect 0.249 0.0791 0.00058 Non-detect 0.00058 Non-detect 0.0118 0.0078 0.00116 Non-detect 0.00116 Non-detect 0.0295 0.0103 0.0122 0.0126 0.0167 Non-detect 0.0167 Non-detect 51 43.8 41

Stripper Bottoms W astewater Stripper Bottoms W astewater **6** 01/19/13 01/20/13

51 01/23/13 01/23/13 13-022-0211 13-022-0212 Measured Measured0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0.00067 Non-detect 0 0 6.22 1.54 0.00071 Non-detect 0.00071 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00124 Non-detect 0.00072 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

3.2 Non-detect 382 0.472 0.499 0.0631 Non-detect 2.14 0.103 Non-detect 10.6 0.0349 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.0237 0.00058 Non-detect 0.0028 0.00116 Non-detect 0.013 0.0153 0.0167 Non-detect 46.6 01/21/13 **7 8** 

52 01/24/13 13-022-0213 Stripper Bottoms W astewater Measured Measured0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 0.635 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

1.3 Non-detect 1.3 Non-detect 173 184 1.03 0.941 0.758 0.638 0.0644 Non-detect 0.0678 Non-detect 4.63 5.13 0.105 Non-detect 0.111 Non-detect 2.52 1.9 0.0356 Non-detect 0.0375 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.0033 Non-detect 0.00199 0.0019 0.0642 0.0672 0.00058 Non-detect 0.00058 Non-detect 0.00715 0.00732 0.00116 Non-detect 0.00116 Non-detect 0.00359 0.00482 0.00418 Non-detect 0.00418 Non-detect 0.0167 Non-detect 0.0167 Non-detect

Measured Measured 40.3 40.3 01/22/13 01/22/13 **9**

53 53 01/24/13 01/24/13 13-023-0205 13-023-0205 Stripper Bottoms W astewater Stripper Bottoms W astewater0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0.00067 Non-detect 0 0 1.23 1.44 0.00071 Non-detect 0.00071 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00124 Non-detect 0.00072 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**
duplicate 0.6 332 1.04 2.58 0.0644 Non-detect 4.2 0.105 Non-detect 4.33 0.0356 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.0429 0.00058 Non-detect 0.0028 0.00116 Non-detect 0.00236 Non-detect 0.00418 Non-detect 0.0167 Non-detect Measured 39 Measured 01/23/13 **10 11** 

51 01/30/13

Stripper Bottoms W astewater 13-024-02110.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 1.2 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 4.8 780 359 12.4 1.81 1.18 0.718 0.0709 Non-detect 0.0651 Non-detect 4.63 3.78 0.116 Non-detect 0.106 Non-detect 4.35 1.48 0.0392 Non-detect 0.036 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.00057 Non-detect 0.109 0.107 0.00058 Non-detect 0.00058 Non-detect 0.00589 0.00409 0.00116 Non-detect 0.00116 Non-detect 0.0288 0.0122 0.00418 Non-detect 0.0121 0.0167 Non-detect 0.0167 Non-detect 45.9 50.6

51 51 Measured Measured 01/24/13 01/25/13 **12**

01/30/13 01/31/13

Stripper Bottoms W astewater Stripper Bottoms W astewater 13-025-0210 13-028-02030.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0.00067 Non-detect 0 0 2.6 2.31 0.00071 Non-detect 0.00071 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00124 Non-detect 0.00072 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

4.4 460 4.89 2.1 0.0678 Non-detect 3.75 0.111 Non-detect 0.486 0.0375 Non-detect 0.00009 Non-detect 0.00024 Non-detect 0.00045 Non-detect 0.00004 Non-detect 0.00004 Non-detect 0.0001 Non-detect 0.00033 Non-detect 0.00083 0.0802 0.00005 Non-detect 0.00389 0.00011 Non-detect 0.0114 0.00041 Non-detect 0.00167 Non-detect 52.6

57 Measured Measured **13 14**  01/26/13

02/05/13

Stripper Bottoms W astewater 13-029-02160.00004 Non-detect 0.00013 Non-detect 0.00004 Non-detect 0.00006 Non-detect 0 3.04 0.00007 Non-detect 0 Non-detect 0.00012 Non-detect 0.00007 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

2.1 3.5 477 436 6.14 3.17 2.02 2.96 0.0651 Non-detect 0.0686 Non-detect 4.05 4.28 0.106 Non-detect 0.112 Non-detect 2.04 0.31 0.036 Non-detect 0.0379 Non-detect 0.00009 Non-detect 0.00092 Non-detect 0.00024 Non-detect 0.0024 Non-detect 0.00045 Non-detect 0.0045 Non-detect 0.00004 Non-detect 0.00047 Non-detect 0.00004 Non-detect 0.00046 Non-detect 0.0001 Non-detect 0.00109 Non-detect 0.00033 Non-detect 0.0033 Non-detect 0.00103 0.00057 Non-detect 0.155 0.0427 0.00005 Non-detect 0.00058 Non-detect 0.0751 0.0028 Non-detect 0.00048 Non-detect 0.00116 Non-detect 0.11 0.00502 0.00133 0.022 0.00167 Non-detect 0.0167 Non-detect 52.8

53 Measured **15** 01/27/13 01/28/13

49 Measured

02/26/00 02/18/00

Stripper Bottoms W astewater 13-029-0217 13-029-0218 Stripper Bottoms W astewater 52.80.00004 Non-detect 0.00049 Non-detect

0.00013 Non-detect 0.00138 Non-detect 0.00074 Non-detect 0.00044 Non-detect 0.00006 Non-detect 0.00067 Non-detect 0 0 8.78 0.916 0.00007 Non-detect 0.00071 Non-detect 0 Non-detect 0.0007 Non-detect 0.00012 Non-detect 0.00124 Non-detect 0.00007 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

4.9 319 5.4 1.53 0.0671 Non-detect 4.73 0.11 Non-detect 0.627 0.0371 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.103 0.00058 Non-detect 0.0035 0.00116 Non-detect 0.0175 0.0257 0.0167 Non-detect **17 16**  01/29/13

Measured Measured 54

13-031-0208 Stripper Bottoms W astewater 02/23/00 53.10.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 2.41 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

4.7 0.9 498 47.2 10.7 2.41 2.07 7.24 0.0657 Non-detect 0.0841 Non-detect 3.7 4.72 0.107 Non-detect 0.137 Non-detect 0.202 0.3 Non-detect 0.0364 Non-detect 0.0465 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00782 0.0033 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.00057 Non-detect 0.13 0.354 0.00058 Non-detect 0.00058 Non-detect 0.0119 0.0112 0.00116 Non-detect 0.00116 Non-detect 0.022 0.0454 0.0261 0.0361 0.0167 Non-detect 0.0167 Non-detect **18** 01/31/13 01/30/13

Measured Measured 60 47 02/16/00 13-032-0224 13-031-0209 Stripper Bottoms W astewater Stripper Bottoms W astewater 02/29/00 52.6 500.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0.00067 Non-detect 0 0 2.9 5.71 0.00071 Non-detect 0.00071 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00124 Non-detect 0.00072 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.8 61.5 15.4 2.95 0.0809 Non-detect 4.17 0.132 Non-detect 0.361 0.0447 Non-detect 0.00186 Non-detect 0.0048 Non-detect 0.009 Non-detect 0.00095 Non-detect 0.00092 Non-detect 0.00218 Non-detect 0.0066 Non-detect 0.00489 0.218 0.00116 Non-detect 0.0218 0.00232 Non-detect 0.0188 0.00836 Non-detect 0.0334 Non-detect **19 20**  02/01/13

49.4 Measured Measured 57 02/12/13 13-035-0217 Stripper Bottoms W astewater0.00099 Non-detect 0.00276 Non-detect 0.00089 Non-detect 0.00135 Non-detect 0 3.98 0.00143 Non-detect 0.0014 Non-detect 0.00248 Non-detect 0.00145 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect duplicate 0.9 54.6 39.5 11.2 8.76 3.3 2.39 0.0671 Non-detect 0.0678 Non-detect 3.2 2.21 0.11 Non-detect 0.111 Non-detect 0.452 0.323 Non-detect 0.0371 Non-detect 0.0375 Non-detect 0.00186 Non-detect 0.00186 Non-detect 0.0048 Non-detect 0.0143 0.009 Non-detect 0.009 Non-detect 0.00095 Non-detect 0.00095 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.00218 Non-detect 0.00218 Non-detect 0.0033 Non-detect 0.0066 Non-detect 0.00426 0.0042 0.279 0.461 0.00116 Non-detect 0.00116 Non-detect 0.0288 0.0369 0.00232 Non-detect 0.00232 Non-detect 0.022 0.0408 0.00836 Non-detect 0.00836 Non-detect 0.0334 Non-detect 0.0334 Non-detect **21** 02/01/13 02/02/13

50 Measured Measured 57

13-035-0217 02/11/13 02/12/13 49.4 47.4

Stripper Bottoms W astewater Stripper Bottoms W astewater 13-036-02280.00099 Non-detect 0.00099 Non-detect

0.00276 Non-detect 0.00276 Non-detect 0.00089 Non-detect 0.00089 Non-detect 0.00135 Non-detect 0.00135 Non-detect 0 0 5.99 8.74 0.00143 Non-detect 0.00143 Non-detect 0.0014 Non-detect 0.0014 Non-detect 0.00248 Non-detect 0.00248 Non-detect 0.00145 Non-detect 0.00145 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 35.2 5.75 1.97 0.0686 Non-detect 5.18 0.112 Non-detect 0.833 0.0379 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.0021 0.115 0.00058 Non-detect 0.00647 0.00116 Non-detect 0.00662 0.00418 Non-detect 0.0167 Non-detect Measured Measured 46 02/15/13 48

Stripper Bottoms W astewater 13-036-0229 02/03/13 **22 23** 0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 1.73 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 26.1 32.7 6.47 10.3 1.91 2.98 0.0725 Non-detect 0.0651 Non-detect 4.19 4.67 0.119 Non-detect 0.106 Non-detect 0.3 Non-detect 1.12 0.0401 Non-detect 0.036 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.00352 0.0496 0.1 0.00058 Non-detect 0.00058 Non-detect 0.00589 0.0182 0.00116 Non-detect 0.00116 Non-detect 0.0055 0.0156 0.00418 Non-detect 0.00418 Non-detect 0.0167 Non-detect 0.0167 Non-detect 61 02/18/13 02/16/13 13-036-0234 13-037-0209 Stripper Bottoms W astewater Stripper Bottoms W astewater 48.7 48.4 02/04/13 02/05/13 **24**

49 Measured Measured0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0.00067 Non-detect 0 0 0.835 2.52 0.00071 Non-detect 0.00071 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00124 Non-detect 0.00072 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 42.7 1.89 3.82 0.0631 Non-detect 4.29 0.103 Non-detect 1.42 0.0349 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00296 0.129 0.00058 Non-detect 0.00741 0.00116 Non-detect 0.0175 0.00418 Non-detect 0.0167 Non-detect **26** 02/06/13 **25**

Measured 54.5

49

Stripper Bottoms W astewater 02/16/13 13-038-0266 Measured0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 2.68 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 10.8 29.3 0.666 1.29 3.5 3.99 0.0678 Non-detect 0.0701 Non-detect 2.33 4.75 0.111 Non-detect 0.115 Non-detect 0.223 0.333 Non-detect 0.0375 Non-detect 0.0388 Non-detect 0.00009 Non-detect 0.00092 Non-detect 0.00024 Non-detect 0.00024 Non-detect 0.00045 Non-detect 0.00045 Non-detect 0.00004 Non-detect 0.00047 Non-detect 0.00004 Non-detect 0.00046 Non-detect 0.0001 Non-detect 0.00109 Non-detect 0.00033 Non-detect 0.0033 Non-detect 0.00083 0.00409 0.0488 0.148 0.0004 0.00267 0.00242 0.00796 0.00011 Non-detect 0.00116 Non-detect 0.00321 0.00671 0.00041 Non-detect 0.00418 Non-detect 0.00167 Non-detect 0.0167 Non-detect **27** 02/07/13 02/08/13

50 45

54 64

Stripper Bottoms W astewater Stripper Bottoms W astewater 02/19/13 02/19/13 13-039-0234 13-043-0236 Measured Measured0.00004 Non-detect 0.00049 Non-detect

0.00013 Non-detect 0.00138 Non-detect 0.00004 Non-detect 0.00044 Non-detect 0.00006 Non-detect 0.00067 Non-detect 0 0 0.728 2.24 0.00007 Non-detect 0.00071 Non-detect 0 Non-detect 0.0007 Non-detect 0.00012 Non-detect 0.00124 Non-detect 0.00007 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect 38 5.24 7.81 0.0671 Non-detect 3.76 0.11 Non-detect 0.373 0.0371 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00496 0.208 0.00058 Non-detect 0.0348 0.00116 Non-detect 0.0148 0.0149 0.0167 Non-detect **28**

13-043-0233 Stripper Bottoms W astewater **29** 02/09/13

45.2

66 02/21/13 Measured Measured0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 3.69 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 0.6 Non-detect 47.1 42.7 3.31 2.54 1.98 2.2 0.0671 Non-detect 0.0657 Non-detect 5.66 3.79 0.11 Non-detect 0.107 Non-detect 0.28 0.133 0.0371 Non-detect 0.0364 Non-detect 0.00092 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.0033 Non-detect 0.00416 0.00374 0.113 0.122 0.00058 Non-detect 0.00058 Non-detect 0.00788 0.00694 0.00116 Non-detect 0.00116 Non-detect 0.00754 0.00828 0.0175 0.0185 0.0167 Non-detect 0.0167 Non-detect 02/24/13 13-043-0234 Measured

Stripper Bottoms W astewater **30** 02/10/13

50.8

48 02/11/13

51.7 Measured 46 02/22/13 13-043-0235 Stripper Bottoms W astewater0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0.00067 Non-detect 0 0 3.47 2.56 0.00071 Non-detect 0.00071 Non-detect 0.0007 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00124 Non-detect 0.00072 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

0.6 Non-detect duplicate 49 2.85 2.08 0.0678 Non-detect 4.52 0.111 Non-detect 0.134 0.0375 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00321 0.112 0.00058 Non-detect 0.00722 0.00116 Non-detect 0.00602 0.0219 0.0167 Non-detect **31**

Measured **32** 02/11/13

51.7 Measured 46 02/22/13 13-043-0235 Stripper Bottoms W astewater0.00049 Non-detect 0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 2.38 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

0.6 Non-detect 23.5 1.5 2.05 0.0637 Non-detect 1.52 0.104 Non-detect 0.175 0.0353 Non-detect 0.00092 Non-detect 0.0024 Non-detect 0.0045 Non-detect 0.00047 Non-detect 0.00046 Non-detect 0.00109 Non-detect 0.0033 Non-detect 0.00057 Non-detect 0.00125 Non-detect 0.00058 Non-detect 0.0028 Non-detect 0.00116 Non-detect 0.00236 Non-detect 0.0162 0.0167 Non-detect **33** 02/12/13

48.9 Measured 46 02/24/13 13-044-0235 Stripper Bottoms W astewater0.00049 Non-detect

0.00138 Non-detect 0.00044 Non-detect 0.00067 Non-detect 0 0.141 0.00071 Non-detect 0.0007 Non-detect 0.00124 Non-detect 0.00072 Non-detect**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 34**  **35 Concentration** 

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **36 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **37 38** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **39 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **40 41** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **42 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **43 44** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **45 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **46 47** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **48 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **49 50** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **51 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **52 53** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **54 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **55 56** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **57 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **58 59** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) 60**