# Patent

## Title
Internal olefin sulfonate composition

## Abstract

Provided are an internal olefin sulfonate composition which is capable of sufficiently enhancing foamability, light foam quality, and instantaneous foam dissipation property, and a cleansing composition containing the internal olefin sulfonate composition. The internal olefin sulfonate composition comprises (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10, and a total content of the component (A) and the component (B) in the internal olefin sulfonate is from 60 to 100% by mass.

## Background
This application is a Continuation of U.S. patent application Ser. No. 14/766,059 filed on Aug. 5, 2015, which is the National Phase of PCT/JP2014/052258 filed Jan. 31, 2014, which claims priority under 35 U.S.C. § 119(a) to Patent Application No. 2013-025319 filed in Japan on Feb. 13, 2013, all of which are hereby expressly incorporated by reference into the present application.


FIELD OF THE INVENTION
The present invention relates to an internal olefin sulfonate composition useful as a base for a cleansing agent, and to a cleansing composition containing the internal olefin sulfonate.
BACKGROUND OF THE INVENTION
Anionic surfactant, particularly, alkyl sulfate and alkyl polyoxyalkylene sulfate, is excellent in detergency and foaming power, and thus are widely used as cleansing ingredients for domestic or industrial use. An olefin sulfonate, particularly, an internal olefin sulfonate obtained with an internal olefin having a double bond inside an olefin chain, not at its end, as a raw material, has been reported as one of anionic surfactants.
Such an internal olefin sulfonate is generally obtained by sulfonating an internal olefin through reactions with a gaseous sulfur trioxide-containing gas, followed by neutralization and then hydrolysis of the resulting sulfonic acid. For example, Patent Documents 1 to 3 disclose improved production methods thereof.
The internal olefin sulfonate thus obtained is known to have good biodegradability or the like, but is still insufficient in a basic performance as a cleansing agent including foamability and foam quality, compared with general-purpose surfactants such as alkyl polyoxyalkylene sulfuric acid ester salt. Thus, further improvement in such a basic performance has been desired. As more people have concerned the water-saving or consumers' preferences have been diversified in recent years, the additional value of light foam quality and instantaneous foam dissipation property in addition to good foamability has also been required for use as a major activator in laundry detergents, dishwashing detergents, shampoos or the like. Specifically, it has been desired to develop a surfactant composition which allows foam to spread quickly by bringing about light foam quality derived from large bubbles and low bubble density and low foam viscosity during cleansing and also facilitates pleasant cleansing and rinsing in a short time by having instantaneous foam dissipation property quickly during rinsing. Such an additional value is useful for, for example, hair shampoos and body cleansers. As more people have a habit to wash their hair or bodies within a limited time before leaving the house after awakening or before going to bed, it tends to spend a considerable amount of time for spreading foam throughout their hair or thoroughly rinsing their hair. This is largely due to fine foam quality and high foam viscosity. If a surfactant composition having light foam quality and instantaneous foam dissipation property can be formulated in a shampoo, the resulting shampoo permits sufficient cleansing in a short time, and not only achieves pleasant cleansing but can bring about a refreshed feel after drying, leading to the realization of water-saving.
Patent Document 4 discloses a specific internal olefin sulfonic acid which is intended to impart the solubilizing ability, penetrating ability, and interfacial tension reducing ability as a cleansing component. It discloses that when it is used, for example, as a shampoo, it lathers well, and achieves an improved feel without friction. Patent Document 5 also describes a specific internal olefin sulfonate for the purpose of improving detergency, and discloses examples of application to shampoos, liquid soaps, and the like. Meanwhile, Patent Document 6 describes a promoter for recovering an oil using a surfactant containing a plurality of internal olefin sulfonates differing in the number of carbon atoms.
[Patent Document 1] JP-A-01-272564
[Patent Document 2] JP-A-61-134366
[Patent Document 3] JP-A-60-32759
[Patent Document 4] JP-A-2003-81935
[Patent Document 5] U.S. Pat. No. 5,078,916
[Patent Document 6] WO-A 2010/129051
SUMMARY OF THE INVENTION
The present invention relates to an internal olefin sulfonate composition comprising (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10, and a total content of the component (A) and the component (B) is from 60 to 100% by mass.


DETAILED DESCRIPTION OF THE INVENTION
Further improvement is still required for any of the compositions described in the above-mentioned documents to exert good foamability together with light foam quality and instantaneous foam dissipation property at high levels as a cleansing agent which is applied to hair, skin, or the like.
Therefore, the present invention relates to an internal olefin sulfonate composition which is capable of sufficiently enhancing good foamability, light foam quality, and instantaneous foam dissipation property, and a cleansing composition containing the internal olefin sulfonate.
The present inventors studied a length of an aliphatic chain in an internal olefin sulfonate, a ratio thereof and other various conditions, and consequently found that an internal olefin sulfonate composition which has good foamability together with light foam quality and instantaneous foam dissipation property can be obtained by setting the ratio between an internal olefin sulfonate having 12 carbon atoms and an internal olefin sulfonate having 14 carbon atoms to a predetermined range while setting the total content thereof to a predetermined range. On the basis of these findings, the present invention has been completed.
According to the present invention, it can provide an internal olefin sulfonate composition which satisfies good foamability, also brings about light foam quality derived from large bubbles and low bubble density and foam viscosity which allow foam to spread quickly during cleansing, also permits pleasant cleansing by bringing about instantaneous foam dissipation property capable of dissipating foam at once during rinsing, and can further adequately bring about a good feel without perceivable residues from the cleansing agent after cleansing and subsequent towel drying, for example, and a cleansing composition containing the internal olefin sulfonate.
Hereinbelow, the present invention will be described in detail.
<Internal Olefin Sulfonate Composition>
The internal olefin sulfonate composition of the present invention includes (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, in which a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10, and a total content of the component (A) and the component (B) is from 60 to 100% by mass.
In the present invention, an internal olefin sulfonate is a sulfonate obtained by sulfonating an internal olefin (an olefin having a double bond inside the olefin chain) as the raw material, followed by neutralization and then hydrolysis, as described above. That is, sulfonation of an internal olefin quantitatively produces β-sultone, some of which are converted into γ-sultone and olefin sulfonic acid, which are further converted into hydroxyalkane sulfonate and olefin sulfonate in the process of neutralization and hydrolysis (for example, J. Am. Oil Chem. Soc. 69, 39 (1992)). It should be noted that the above internal olefin may also has a broad meaning including a trace amount of so-called α-olefin, in which a double bond is present at the C-1 position of the carbon chain. Here, the hydroxyl group of the hydroxyalkane sulfonate thus obtained is present inside the alkane chain, and the double bond of the olefin sulfonate thus obtained is present inside the olefin chain. The product thus obtained is mainly a mixture of the aforementioned substances, some of which may include a trace amount of hydroxyalkane sulfonate having a hydroxyl group at the end of the carbon chain, or olefin sulfonate having a double bond at the end of the carbon chain. In the present specification, each of these products and a mixture thereof are collectively referred to as an internal olefin sulfonate. Hydroxyalkane sulfonate is referred to as a hydroxy form of an internal olefin sulfonate (hereinbelow, may also be referred to as HAS), and olefin sulfonate is referred to as an olefin form of an internal olefin sulfonate (hereinbelow, may also be referred to as IOS).
A content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate composition of the present invention is from 10/90 to 90/10 and is preferably from 25/75 to 90/10, more preferably from 50/50 to 90/10, more preferably from 75/25 to 90/10, and even more preferably from 80/20 to 90/10, from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying. The content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate composition of the present invention is preferably from 10/90 to 80/20, more preferably from 10/90 to 70/30, more preferably from 10/90 to 30/70, and even more preferably from 10/90 to 20/80, from the viewpoint of foamability.
The content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate composition is a numerical value measured by a high-performance liquid chromatograph-mass spectrometer (hereinbelow, abbreviated as HPLC-MS). Specifically, an internal olefin sulfonate having 12 carbon atoms and an internal olefin sulfonate having 14 carbon atoms are separated by HPLC, each of which then is identified by analysis with MS. From the HPLC-MS peak area thereof, the content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate composition is determined.
The total content of the component (A) and the component (B) in the internal olefin sulfonate composition of the present invention is from 60 to 100% by mass. The lower limit of the total content of the component (A) and the component (B) is preferably 70% by mass or more, more preferably 80% by mass or more, more preferably 90% by mass or more, more preferably 95% by mass or more, more preferably 96.5% by mass or more, and even more preferably 97% by mass or more, from the viewpoint of foamability, light foam quality, instantaneous foam dissipation property, and a feel after drying.
As is apparent from the aforementioned production method, the sulfonate group in the internal olefin sulfonate of the present invention is present inside the olefin chain or alkane chain. In the present invention, it is preferable that the content of an internal olefin sulfonate in which the sulfonate group is present at the C-2 position of the olefin chain or alkane chain is low, while the content of an internal olefin sulfonate in which the sulfonate group is present further inside is high, from the viewpoint of foamability, light foam quality, instantaneous foam dissipation property, and a feel after drying. It is more preferable that the content of an internal olefin sulfonate in which the sulfonate group is present at the C-2 position of the olefin chain or alkane chain is low, with respect to both of the above internal olefin sulfonate having 12 carbon atoms and 14 carbon atoms.
A content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the internal olefin sulfonate (component (A) and component (B)) having 12 and 14 carbon atoms of the present invention is, in the total content of the component (A) and the component (B), preferably 28% by mass or less, more preferably less than 25% by mass, more preferably 23% by mass or less, and even more preferably 22% by mass or less, from the viewpoint of light foam quality and instantaneous foam dissipation property. The content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the component (A) and the component (B) is, in the total content of the component (A) and the component (B), preferably 5% by mass or more, more preferably 7% by mass or more, more preferably 15% by mass or more, and even more preferably 19% by mass or more, from the viewpoint of cost and productivity.
Considering these viewpoints together, the content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the component (A) and the component (B) is, in the total content of the component (A) and the component (B), preferably 5% by mass or more and 28% by mass or less, more preferably 7% by mass or more and less than 28% by mass, more preferably 7% by mass or more and less than 25% by mass, more preferably 15% by mass or more and 23% by mass or less, and even more preferably 19% by mass or more and 22% by mass or less.
A content of the α-olefin sulfonate in which the sulfonate group is positioned at the C-1 position of an olefin chain or an alkane chain is, in the total content of the component (A) and the component (B), preferably less than 2.8% by mass and more preferably 2.0% by mass or less, from the viewpoint of light foam quality, and instantaneous foam dissipation property. The content of the α-olefin sulfonate in which the sulfonate group is positioned at the C-1 position of an olefin chain or an alkane chain is, in the total content of the component (A) and the component (B), preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 0.3% by mass or more, from the viewpoint of cost and productivity. Considering these viewpoints together, the content of the α-olefin sulfonate in which the sulfonate group is positioned at the C-1 position of an olefin chain or an alkane chain is, in the total content of the component (A) and the component (B), preferably 0.01% by mass or more and less than 2.8% by mass, more preferably 0.1% by mass or more and less than 2.8% by mass, and even more preferably 0.3% by mass or more and less than 2.8% by mass.
It should be noted that the content of the internal olefin sulfonate in which the sulfonate group is present at the C-2 position in the internal olefin sulfonate having 12 and 14 carbon atoms may be measured by a method such as nuclear magnetic resonance spectroscopy. More specifically, it is a numerical value measured by a method using gas chromatography described later in Example.
A content mass ratio of the hydroxy form to the olefin form, (hydroxy form/olefin form), in the internal olefin sulfonate having 12 and 14 carbon atoms is preferably from 50/50 to 100/0, more preferably from 60/40 to 100/0, more preferably from 70/30 to 100/0, more preferably from 75/25 to 100/0, and even more preferably from 75/25 to 95/5, from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying.
The content mass ratio of the hydroxy form and the olefin form in the internal olefin sulfonate having 12 and 14 carbon atoms of the present invention may be measured by the method described later in Examples.
A content of an internal olefin sulfonate having 18 or more carbon atoms in the internal olefin sulfonate composition of the present invention is preferably 5% by mass or less, more preferably 3% by mass or less, still more preferably 2% by mass or less, and even more preferably 1% by mass or less, from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying. The lower limit of the content of the internal olefin sulfonate having 18 or more carbon atoms is preferably 0% by mass, that is, it is preferable that the internal olefin sulfonate composition of the present invention does not contain the internal olefin sulfonate having 18 or more carbon atoms unless this internal olefin sulfonate is inevitably mixed therein.
For the internal olefin sulfonate having 18 or more carbon atoms, it is also preferable to have a low content of the internal olefin sulfonate in which the sulfonate group is positioned at the C-2 position of an olefin chain or an alkane chain and a high content of the internal olefin sulfonate in which the sulfonate group is positioned more internally, from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying.
As the internal olefin sulfonate composition of the present invention is obtained by sulfonating an internal olefin, followed by neutralization and hydrolysis as described above, an unreacted raw material internal olefin and inorganic compounds may remain in the composition. It is preferred that the contents of these components are much smaller.
A content of the raw material internal olefin in the internal olefin sulfonate composition of the present invention is preferably less than 5.0% by mass, more preferably less than 3.0% by mass, more preferably less than 1.5% by mass, more preferably less than 1.0% by mass and even more preferably less than 0.05% by mass with respect to the amount of the internal olefin sulfonates from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying.
The content of the unreacted internal olefin may be measured by a method described later in Examples.
A content of inorganic compounds in the internal olefin sulfonate composition of the present invention is preferably less than 7.5% by mass, more preferably less than 5.0% by mass, more preferably less than 3.0% by mass, and even more preferably less than 1.0% by mass with respect to the amount of the internal olefin sulfonates from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying.
In this context, the inorganic compound includes sulfate and alkali agent. The content of these inorganic compounds may be measured by a potentiometric titration. Specifically, the content may be measured by a method described later in Examples.
The internal olefin sulfonate composition of the present invention may contain a hydroxy form and an olefin form having any number of carbon atoms which are different from that of the component (A) and the component (B). The number of carbon atoms in the hydroxy form and the olefin form other than the component (A) and the component (B) is preferably from 8 to 24, more preferably from 16 to 20, more preferably from 16 to 18, and even more preferably 16 from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying. These hydroxy forms and olefin forms having various numbers of carbon atoms are derived from the internal olefin used as a raw material.
The internal olefin sulfonate composition of the present invention may contain other components, for example, water as a medium, a pH adjuster, a viscosity reducing agent, an organic solvent, and polyhydric alcohols, in addition to the components described above.
<Method for Producing Internal Olefin Sulfonate Composition>
The internal olefin sulfonate composition may be produced by sulfonating a raw material internal olefin composition containing a raw material internal olefin having 8 to 24 carbon atoms, followed by neutralization and hydrolysis. More specifically, for example, the composition may be produced in accordance with the methods described in U.S. Pat. Nos. 1,633,184 and 2,625,150, and Tenside Surf. Det. 31 (5) 299 (1994), and the like.
As mentioned above, in the present invention, a raw material internal olefin refers to an olefin substantially having a double bond inside the olefin chain. A content of the α-olefin in which a double bond is present at a C-1 position in the raw material internal olefin is, in the total content of the component (A) and the component (B), preferably less than 2.8% by mass and more preferably 2.0% by mass or less, from the viewpoint of light foam quality, instantaneous foam dissipation property, and a feel after drying. The content of the α-olefin in which a double bond is present at a C-1 position in the raw material internal olefin is, in the total content of the component (A) and the component (B), preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 0.3% by mass or more, from the viewpoint of cost and productivity. Considering these viewpoints together, the content of the α-olefin sulfonate in which the sulfonate group is positioned at the C-1 position of an olefin chain or an alkane chain is, in the total content of the component (A) and the component (B), preferably 0.01% by mass or more and less than 2.8% by mass, more preferably 0.1% by mass or more and less than 2.8% by mass, more preferably 0.3% by mass or more and less than 2.8% by mass, even more preferably 0.3% by mass or more and 2.0% by mass or less.
From the viewpoint of light foam quality, instantaneous foam dissipation property of the internal olefin sulfonate composition obtained thus, the number of carbon atoms in the raw material internal olefin is preferably from 8 to 24, more preferably from 12 to 20, more preferably from 12 to 18, more preferably from 12 to 16, more preferably from 12 to 14, and even more preferably 12 and 14. An internal olefin to be used as a raw material may be used singly, or a combination of two or more thereof may be used.
When the internal olefin sulfonate composition is obtained by sulfonating the raw material internal olefin composition, followed by neutralization and hydrolysis, the content of the internal olefin in which a double bond is present at a C-2 position in the raw material internal olefin composition is preferably from 15 to 40% by mass, and more preferably from 15 to 35% by mass.
In the synthesis of the internal olefin sulfonate composition, the content of the raw material internal olefin in which a double bond is present at a C-2 position in the raw material internal olefin composition may be measured by a gas chromatograph (hereinbelow, abbreviated as GC). Specifically, this content may be measured by the method described later in Examples.
The raw material internal olefin composition may contain a paraffin component. A content of the paraffin component is preferably less than 5% by mass, more preferably less than 3% by mass, more preferably 1% by mass or less, and even more preferably 0.1% by mass or less, from the viewpoint of foamability.
The content of the paraffin component may be measured, for example, by GC-MS.
The sulfonation reaction may be carried out by reacting a sulfur trioxide gas with a raw material internal olefin composition at a ratio of from 1 to 1.2 moles of sulfur trioxide per mole of the raw material internal olefin. The reactions may be carried out at a reaction temperature of from 20 to 40° C.
Neutralization is carried out by reacting from 1 to 1.5 times the molar amount of an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, ammonia or 2-aminoethanol with the theoretical value of sulfonate group.
The hydrolysis reaction may be carried out at from 90 to 200° C. for from 30 minutes to three hours in the presence of water. These reactions may be successively carried out. Also, upon completion of the reactions, the products may be purified by extraction, washing, or the like.
In the production of the internal olefin sulfonate composition, the raw material internal olefin in which the number of carbon atoms is distributed in from 8 to 24 may be subjected as a raw material internal olefin composition to sulfonation, neutralization, and hydrolysis to produce the internal olefin sulfonate composition. Alternatively, the raw material internal olefin having a uniform number of carbon atoms may be subjected to sulfonation, neutralization, and hydrolysis to produce internal olefin sulfonic acid, which is then mixed with a plurality of internal olefin sulfonates each having different number of carbon atoms to produce the internal olefin sulfonate composition.
The internal olefin sulfonate composition of the present invention exerts good foamability together with light foam quality, and instantaneous foam dissipation property at high levels, and is thus useful as a cleansing ingredient. Specifically, it can be used in household cleansing agents such as hair shampoos, body cleansers, laundry detergents, and kitchen detergents, and is particularly useful as a base for the hair shampoo.
<Cleansing Composition>
The cleansing composition of the present invention is not particularly limited as long as it contains (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein the content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10, and the total content of the component (A) and the component (B) in the internal olefin sulfonate is from 60 to 100% by mass, as in the internal olefin sulfonate composition of the present invention. The cleansing composition of the present invention may contain other components depending on the intended purpose. Examples of the other components include other surfactant, a foaming increasing agent, and an auxiliary agent or the like. The total content of the internal olefin sulfonate in the cleansing composition is preferably from 0.1 to 80% by mass, more preferably from 1 to 50% by mass, and even more preferably from 2 to 30% by mass.
The other surfactant is preferably, for example, an alkyl sulfate or an alkyl polyoxyalkylene sulfate. Examples of the auxiliary agent include, but not particularly limited to, water, polymer, an oil solution, silicone, a moisturizing agent, a viscosity regulator, a preservative, an anti-inflammatory agent, an antioxidant, an ultraviolet absorber, a sequestering agent, a pearlescent agent, a dye, a fragrance, an enzyme, a bleaching agent, a bleach activator, and a pH adjuster.
The cleansing composition of the present invention may be produced, for example, by formulating the internal olefin sulfonate composition obtained as described above, and may be produced by further mixing the internal olefin sulfonate composition with the components described above.
In relation to the embodiments mentioned above, the present invention further discloses the following internal olefin sulfonate composition and cleansing composition:
<1> An internal olefin sulfonate composition comprising (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10, and a total content of the component (A) and the component (B) is from 60 to 100% by mass.

<2> The internal olefin sulfonate composition according to <1>, wherein the content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate composition is preferably from 25/75 to 90/10, more preferably from 50/50 to 90/10, more preferably from 75/25 to 90/10, and even more preferably from 80/20 to 90/10.

<3> The internal olefin sulfonate composition according to <1>, wherein the content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate composition is preferably from 10/90 to 80/20, more preferably from 10/90 to 70/30, more preferably 10/90 to 30/70, and even more preferably from 10/90 to 20/80.

<4> The internal olefin sulfonate composition according to any one of <1> to <3>, wherein a lower limit of a total content of the component (A) and the component (B) in the internal olefin sulfonate composition is preferably 70% by mass or more, more preferably 80% by mass or more, more preferably 90% by mass or more, more preferably 95% by mass or more, more preferably 96.5% by mass or more, and even more preferably 97% by mass or more.

<5> The internal olefin sulfonate composition according to any one of <1> to <4>, wherein a content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the internal olefin sulfonate having 12 and 14 carbon atoms is preferably 28% by mass or less, more preferably less than 25% by mass, more preferably 23% by mass or less, and even more preferably 22% by mass or less, and preferably 5% by mass or more, more preferably 7% by mass or more, more preferably 15% by mass or more, and even more preferably 19% by mass or more.

<6> The internal olefin sulfonate composition according to any one of <1> to <5>, wherein a mass ratio of a content of a hydroxy form to a content of an olefin form, (hydroxy form/olefin form), in the internal olefin sulfonate having 12 and 14 carbon atoms is preferably from 50/50 to 100/0, more preferably from 60/40 to 100/0, more preferably from 70/30 to 100/0, more preferably from 75/25 to 100/0, and even more preferably from 75/25 to 95/5.

<7> The internal olefin sulfonate composition according to any one of <1> to <6>, wherein a content of an internal olefin sulfonate having 18 or more carbon atoms is preferably 3% by mass or less, more preferably 2% by mass or less, and even more preferably 1% by mass or less, with its lower limit being preferably 0% by mass.

<8> The internal olefin sulfonate composition according to any one of <1> to <7>, wherein a content of a raw material internal olefin in the internal olefin sulfonate composition is preferably less than 5.0% by mass, more preferably less than 3.0% by mass, more preferably less than 1.5% by mass, more preferably less than 1.0% by mass, and even more preferably less than 0.05% by mass with respect to the amount of the internal olefin sulfonate.

<9> The internal olefin sulfonate composition according to any one of <1> to <8>, wherein a content of inorganic compound in the internal olefin sulfonate composition is preferably less than 7.5% by mass, more preferably less than 5.0% by mass, more preferably less than 3.0% by mass, and even more preferably less than 1.0% by mass with respect to the amount of the internal olefin sulfonates.

<10> The internal olefin sulfonate composition according to any one of <1> to <9>, wherein the number of carbon atom in the hydroxy form and the olefin form other than the component (A) and the component (B) in the internal olefin sulfonate composition is preferably from 8 to 24, more preferably from 16 to 20, more preferably from 16 to 18, and even more preferably 16.

<11> The internal olefin sulfonate composition according to any one of <1> to <10>, obtained by sulfonating a raw material internal olefin composition containing a raw material internal olefin, followed by neutralization and then hydrolysis, with a content of the raw material internal olefin in which a double bond is present at a C-2 position being preferably from 15 to 40% by mass.

<12> The internal olefin sulfonate composition according to <11>, wherein a content of the raw material internal olefin in which a double bond is present at a C-2 position in the raw material internal olefin composition is preferably from 15 to 35% by mass.

<13> A cleansing composition obtained by formulating the internal olefin sulfonate composition according to any one of <1> to <12>.

<14> A cleansing composition comprising (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10, and a total content of the component (A) and the component (B) is from 60 to 100% by mass.

<15> The cleansing composition according to <13> or <14>, wherein a content of the internal olefin sulfonate is preferably from 0.1 to 80% by mass.

<16> The cleansing composition according to any one of <13> to <15>, further comprising one or more preferably selected from the group consisting of an alkyl sulfate and an alkyl polyoxyalkylene sulfate.

<17> A method for washing hair, comprising applying the cleansing composition according to any one of <13> to <16> to hair, followed by washing and then rinsing.

<18> A method for washing skin, comprising applying the cleansing composition according to any one of <13> to <16> to skin, followed by rinsing.

<19> Use of the cleansing composition according to any one of <13> to <16> for washing hair.

<20> Use of the cleansing composition according to any one of <13> to <16> for washing skin.

EXAMPLES
Hereinbelow, the present invention will be specifically described with reference to Examples. It should be noted that unless otherwise specifically noted, the content of each of the components is expressed by % by mass in the following Tables. Also, the methods for measuring various physical properties are as follows.
(1) Conditions of Measurement
(i) Method for Measuring the Position of a Double Bond in the Internal Olefin
The position of a double bond in an internal olefin was measured by gas chromatography (hereinbelow, abbreviated as GC). Specifically, an internal olefin was converted to a dithiated derivative by reaction with dimethyl disulfide, and then each component was separated by GC. The position of a double bond in an internal olefin was determined by the peak area of each component.
The apparatus and analytical conditions used for the measurement are as follows. GC apparatus “HP6890” (the product of Hewlett-Packard Company); Column “Ultra-Alloy-1HT capillary column” (30 m×250 μm×0.15 μm, the product of Frontier Laboratories Ltd.); Detector (hydrogen flame ionization detector (FID)); Injection temperature of 300° C.; Detector temperature of 350° C.; and He flow rate of 4.6 mL/min.
(ii) Method for Measuring the Content of Internal Olefin Sulfonate in Which a Sulfonate Group is Present at a C-2 Position
The linkage position of the sulfonate group was measured by GC. Specifically, the internal olefin sulfonate was reacted with trimethylsilyldiazomethane to form a methyl-esterified derivative. Then, each component was separated by GC. Each of a peak area was regarded as a mass ratio, and the content of internal olefin sulfonate in which a sulfonate group is present at a C-2 position was quantitated.
The apparatus and analytical conditions used for the measurement are as follows. GC apparatus “Agilent technology 6850” (the product of Agilent Technologies, Inc.); Column “HP-1 capillary column” (30 m×320 μm×0.25 μm, the product of Agilent Technologies, Inc.); Detector (hydrogen flame ionization detector (FID)); Injection temperature of 300° C.; Detector temperature of 300° C.; He flow rate of 1.0 mL/min.; and Oven (60° C. (0 min.)→10° C./min.→300° C. (10 min.)).
(iii) Method for Measuring the Mass Ratio of Hydroxy Form/Olefin Form
The mass ratio of hydroxy form/olefin form was measured by HPLC-MS. Specifically, the hydroxy form and the olefin form were separated by HPLC and each form was identified by separately analyzing with MS. From the resulting GC-MS peak area, the fraction of each form was determined.
The apparatus and analytical conditions used for the measurement are as follows. HPLC apparatus “Agilent technology 1100” (the product of Agilent Technologies, Inc.); Column “L-column ODS 4.6×150 mm” (the product of Chemicals Evaluation and Research Institute, Japan); Sample preparation (diluted 1000-fold with methanol); Eluent A (10 mM ammonium acetate in water); Eluent B (10 mM ammonium acetate in methanol), Gradient (0 min (A/B=30/70%)→10 min (30/70%)→55 min (0/100%)→65 min (0/100%)→66 min (30/70%)→75 min (30/70%)); MS apparatus “Agilent technology 1100 MS SL (G1946D)” (the product of Agilent Technologies, Inc.); and MS detection (anion detection m/z 60-1600, UV 240 nm).
(iv) Method for Measuring the Content of the Raw Material Internal Olefin
The content of the raw material internal olefin was measured by GC. Specifically, ethanol and petroleum ether were added to an aqueous solution of internal olefin sulfonate, followed by extraction to give olefin in the petroleum ether phase. From the GC peak area of the olefin, the amount thereof was quantitated.
The apparatus and analytical conditions used for the measurement are as follows. GC apparatus “Agilent technology 6850” (the product of Agilent Technologies, Inc.); Column “Ultra-Alloy-1HT capillary column, 15 m×250 μm×0.15 μm” (the product of Frontier Laboratories, Ltd.); Detector (hydrogen flame ionization detector (FID)); Injection temperature of 300° C.; Detector temperature of 350° C.; and He flow rate of 3.8 mL/min.
(v) Method for Measuring the Content of Inorganic Compound
The content of inorganic compound was measured by potentiometric titration and neutralization titration. Specifically, the content of Na2SO4 was quantitated by measuring sulfate ion (SO42−) by potentiometric titration. Also, the content of NaOH was quantitated by neutralization titration with diluted hydrochloric acid.
(vi) Method for Measuring the Content of the Paraffin Component
The content of the paraffin component was measured by GC. Specifically, ethanol and petroleum ether were added to an aqueous solution of internal olefin sulfonate, followed by extraction to give paraffin in the petroleum ether phase. From the GC peak area of the paraffin, the amount thereof was quantitated.
It should be noted that the apparatus and analytical conditions used are the same as those used for the measurement of the content of the raw material internal olefin.
(2) Production of an Internal Olefin
[Production Example A] Synthesis of C12 Internal Olefin in which 33.1% by Mass of Double Bond was Present at C-2 Position
Into a flask with a stirrer, (6000 g (35.6 moles) of 1-dodecene “LINEALENE 12, manufactured by Idemitsu Kosan Co., Ltd.”, and as a solid acid catalyst, 180 g (3% by mass relative to the raw material α-olefin) of protic β-zeolite (CP-814E, Zeolyst International, Inc.) were placed, and the reaction was allowed to proceed for 20 hours at 120° C. while stirring. Subsequently, the crude internal olefin was transferred to a distillation flask and distilled at from 124 to 136° C./7.5 mmHg, whereby 100% pure internal olefin having 12 carbon atoms was obtained. The double bond distribution in the resulting internal olefin was 0.5% by mass at C-1 position, 33.1% by mass at C-2 position, 23.7% by mass at C-3 position, 21.2% by mass at C-4 position, 15.0% by mass at C-5 position, and 6.6% by mass at C-6 position.
[Production Example B] Synthesis of C14 Internal Olefin in which 31.8% by Mass of Double Bond was Present at C-2 Position
Into a flask with a stirrer, 6000 g (30.6 moles) of 1-tetradecene “LINEALENE 14, manufactured by Idemitsu Kosan Co., Ltd.”, and as a solid acid catalyst, 180 g (3% by mass relative to the raw material α-olefin) of protic β-zeolite (CP-814E, Zeolyst International, Inc.) were placed, and the reaction was allowed to proceed for 20 hours at 120° C. while stirring. Subsequently, the crude internal olefin was transferred to a distillation flask and distilled at from 124 to 136° C./7.5 mmHg, whereby 100% pure internal olefin having 14 carbon atoms was obtained. The double bond distribution in the resulting internal olefin was 1.3% by mass at C-1 position, 31.8% by mass at C-2 position, 23.8% by mass at C-3 position, 21.0% by mass at C-4 position, 8.6% by mass at C-5 position, and 13.6% by mass at sum of C-6 and C-7 positions.
(3) Production of an Internal Olefin Sulfonate
[Production Example 1] Synthesis of C12 Internal Olefin Sulfonate
Into a thin film sulfonation reactor having an outer jacket, the internal olefin having 12 carbon atoms (the content of an internal olefin in which a double bond is present at a C-2 position is 33.1% by mass) obtained in Production Example A was placed, and the sulfonation reaction was carried out by using sulfur trioxide gas under conditions of passing cooling water at 20° C. through the outer jacket of the reactor. The molar ratio of SO3/internal olefin for the sulfonation reaction was set at 1.09. The resulting sulfonation product was added to an alkaline aqueous solution prepared with 1.5 times the molar amount of sodium hydroxide relative to the theoretical acid value, followed by neutralization at 30° C. for one hour while stirring. The resulting neutralized product was hydrolyzed by heating at 160° C. for one hour in an autoclave, whereby a crude product of sodium C12 internal olefin sulfonate was obtained. Then, 300 g of the crude product was transferred to a separatory funnel, to which 300 mL of ethanol was added and then 300 mL of petroleum ether was added per operation, whereby oil-soluble impurities were removed by extraction. At this time, inorganic compounds (mainly composed of sodium sulfate) which were precipitated at the oil-water interface by the addition of ethanol were also separated and removed from the aqueous phase by the oil-water separation operation. The above removal/extraction operation was repeated three times. Then, the aqueous phase side was evaporated to dryness, whereby sodium C12 internal olefin sulfonate was obtained. The mass ratio of hydroxy form (sodium hydroxyalkane sulfonate)/olefin form (sodium olefin sulfonate) in the obtained sodium internal olefin sulfonate was 92/8. Also, the content of the raw material internal olefin contained in the obtained sodium internal olefin sulfonate was less than 100 ppm (below the GC detection limit), and that of inorganic compounds was 0.2% by mass. Also, the content of an internal olefin sulfonate in which a sulfonate group is present at a C-2 position was 21.0% by mass.
[Production Example 2] Synthesis of C14 Internal Olefin Sulfonate
A sodium C14 internal olefin sulfonate was obtained under the same conditions as those used in Production Example 1 from the internal olefin having 14 carbon atoms (the content of an internal olefin in which a double bond is present at a C-2 position is 31.8% by mass) obtained in Production Example B.
The mass ratio of hydroxy form/olefin form in the obtained sodium internal olefin sulfonate was 93/7. Also, the content of the raw material internal olefin contained in the obtained sodium internal olefin sulfonate was less than 100 ppm (below the GC detection limit) and that of inorganic compounds was 0% by mass. The content of an internal olefin sulfonate in which a sulfonate group is present at C-2 position was 21.7% by mass.
Production Example 3
The composition obtained in Production Example 1 and the composition obtained in Production Example 2 were formulated and mixed at a mass ratio of 10:90 to obtain internal olefin sulfonate composition 1.
Production Example 4
The composition obtained in Production Example 1 and the composition obtained in Production Example 2 were formulated and mixed at a mass ratio of 25:75 to obtain internal olefin sulfonate composition 2.
Production Example 5
The composition obtained in Production Example 1 and the composition obtained in Production Example 2 were formulated and mixed at a mass ratio of 50:50 to obtain internal olefin sulfonate composition 3.
Production Example 6
The composition obtained in Production Example 1 and the composition obtained in Production Example 2 were formulated and mixed at a mass ratio of 75:25 to obtain internal olefin sulfonate composition 4.
Production Example 7
The composition obtained in Production Example 1 and the composition obtained in Production Example 2 were formulated and mixed at a mass ratio of 90:10 to obtain internal olefin sulfonate composition 5.
<Hair Evaluation>
A hair bundle (hair of a Japanese person free from treatment such as bleach or hair color; approximately 20 cm, 15 g) was cleansed with a plain shampoo shown in Table 1. Then, after application of a plain rinse shown in Table 2, the hair bundle was rinsed off with tap water to obtain a tress for evaluation.
Each of the internal olefin sulfonate compositions 1 to 5 obtained in Production Examples 3 to 7 was dissolved in ion-exchange water to prepare an aqueous solution (13% by mass) of the internal olefin sulfonate composition. Using these aqueous solutions, five expert panelists evaluated their foamability, light foam quality, foam dissipation property during rinsing, and feel after cleansing and subsequent towel drying (without perceivable residues) in accordance with evaluation criteria and evaluation methods shown below. (Specifically, 1.0 g of each cleansing composition shown in Table 3 was applied to the tress for evaluation and subjected to lathering, cleansing, and then rinsing.) The results are shown in Table 3.
Table 3 also shows the evaluation results with reference to alkyl polyoxyethylene sulfate (AES), α-olefin sulfonate (AOS), and secondary alkyl sulfonate (SAS). The concentrations of these surfactants in the cleansing compositions were adjusted to 13% by mass.







TABLE 1







(Composition of plain shampoo)








(Component)
(%)











Sodium polyoxyethylene lauryl ether sulfate
11.3


(42.0% in terms of EMAL E-27C (manufactured by Kao Corp.;


27% by weight of active component))


Coconut oil fatty acid N-methylethanolamide
3.0


(AMINON C-11S (manufactured by Kao Corp.))


Citric acid
0.2


Methylparaben
0.3


Purified water
Balance


Total
100.0









(Production of Plain Shampoo)

The components were placed in a beaker, heated to 80° C., and then mixed. After confirmation of uniform dissolution, the mixture was cooled to obtain a plain shampoo.







TABLE 2







(Composition of plain rinse)








(Component)
(%)











Octadecyloxypropyl trimethyl ammonium chloride
3.0


(6.7% in terms of QUARTAMIN E-80K (manufactured by Kao


Corp.; 45% by weight of active component))


Stearyl alcohol
6.0


(KALCOL 8098 (manufactured by Kao Corp.))


Methylparaben
0.3


Purified water
Balance


Total
100.0









(Production of Plain Rinse)

Octadecyloxypropyl trimethyl ammonium chloride and stearyl alcohol were placed in a beaker (A) and melted by heating to 80° C. Purified water and methylparaben were placed in another beaker (B) and heated to 80° C. while stirring. After confirmation of uniform dissolution, the mixed solution in the beaker (A) was added to the beaker (B) while stirring at 80° C., and an emulsification was carried out for 30 minutes. The heating was terminated, and it was cooled to room temperature to obtain a plain rinse.
<Evaluation Criteria and Evaluation Methods>
Foamability
5: Foaming properties were very good
4: Foaming properties were good
3: Ordinary foamability (equivalent to Reference Comparative Example 3: SAS)
2: Foaming properties were poor
1: Foaming properties were too poor to cleanse hair
Light Foam Quality
5: Foam quality was very light and promoted cleansing with large bubbles
4: Foam quality was slightly light and good
3: Foam quality was ordinary (equivalent to Reference Comparative Example 1: AES)
2: Foam quality was slightly heavy and poor
1: Foam quality was very heavy and hindered cleansing
Foam Dissipation Property During Rinsing
5: Foam was dissipated in the moment of rinsing and easily rinsed
4: Foam was quickly dissipated
3: Ordinary (equivalent to Reference Comparative Example 2: AOS)
2: Foam was slowly dissipated
1: Foam was very slowly dissipated and was difficult to rinse
Feel After Cleansing and Subsequent Towel Drying
5: Cleansing finish was very refreshing without perceivable residues from the cleansing agent
4: Cleansing finish was slightly refreshing
3: Ordinary (equivalent to Reference Comparative Example 1: AES)
2: Cleansing finish was hardly refreshing with slightly perceivable residues from the cleansing agent
1: Cleansing finish was not refreshing with strongly perceivable residues from the cleansing agent
<Hand Wash Evaluation>
Each of the internal olefin sulfonate compositions 1 to 5 obtained in Production Examples 3 to 7 was dissolved in ion-exchange water to prepare an aqueous solution (13% by mass) of the internal olefin sulfonate composition. Using these aqueous solutions, five panelists washed their hands, and evaluated foamability, foam dissipation property during rinsing, and feel after cleansing and subsequent towel drying (without perceivable residues) in accordance with the following evaluation criteria and evaluation method. Specifically, 1.0 g of aqueous solution (13% by mass) prepared by using the internal olefin sulfonate compositions shown in Table 3 was applied to the hands and subjected to lathering, cleansing, and then rinsing, and subsequent towel drying. The results are shown in Table 3.
Foamability
5: Foaming properties were very good
4: Foaming properties were good
3: Ordinary foamability (equivalent to Reference Comparative Example 3: SAS)
2: Foaming properties were poor
1: Foaming properties were too poor to cleanse hand
Foam Dissipation Property During Rinsing
5: Foam was dissipated in the moment of rinsing and easily rinsed
4: Foam was quickly dissipated
3: Ordinary (equivalent to Reference Comparative Example 2: AOS)
2: Foam was slowly dissipated
1: Foam was very slowly dissipated and was difficult to rinse
Feel After Cleansing and Subsequent Towel Drying
5: Cleansing finish was very refreshing without perceivable residues from the cleansing agent
4: Cleansing finish was slightly refreshing
3: Ordinary (equivalent to Reference Comparative Example 2: AOS)
2: Cleansing finish was hardly refreshing with slightly perceivable residues from the cleansing agent
1: Cleansing finish was not refreshing with strongly perceivable residues from the cleansing agent










TABLE 3










Reference



Internal olefin sulfonate composition
Comparative Examples
















1
2
3
4
5
1
2
3




















Internal
The number of carbon atoms in internal olefin
12/14
12/14
12/14
12/14
12/14
AES*1
AOS*2
SAS*3


olefin
sulfonate (mass ratio within parentheses)
(10/90)
(25/75)
(50/50)
(75/25)
(90/10)


sulfonate
Total content of C12/14 (%)
100
100
100
100
100


composition
Amount of raw material internal olefin relative
<100 ppm
<100 ppm
<100 ppm
<100 ppm
<100 ppm



to amount of C12/14 internal olefin sulfonate



Hydroxy form/olefin form in C12/14 internal
93/7 
93/7 
92/8 
92/8 
92/8 



olefin sulfonate



Ratio of sulfonate group present at C-2 position
21.6
21.5
21.4
21.2
21.1



in C12/14 internal olefin sulfonate (%)



Ratio of double bond present at C-2 position in
31.9
32.1
32.4
32.7
32.9



raw material internal olefin (%)



Amount of inorganic compound (%)
0.0
0.1
0.1
0.2
0.2

















Evaluation
Hair
Foamability
5.0
4.6
4.2
4.0
3.8
2.0
2.4
3.0


results
evaluation
Foam quality (lightness)
4.2
4.4
4.6
4.8
5.0
3.0
3.6
3.4




Foam dissipation property
4.4
4.6
4.6
4.8
5.0
2.4
3.0
2.0




Feel after drying
4.2
4.4
4.6
5.0
5.0
3.0
3.4
2.4




(without perceivable residues)



Hand wash
Foamability
5.0
4.8
4.4
4.2
3.8
2.0
2.0
3.0



evaluation
Foam dissipation property
4.6
4.8
4.8
5.0
5.0
2.0
3.0
1.4




Feel after drying
4.2
4.4
4.6
4.8
5.0
2.6
3.0
1.8




(without perceivable residues)





*1Sodium alkyl polyoxyethylene sulfate (AES), manufactured by Kao Corp., EMAL 270S (active component: 70%)


*2Sodium α-olefin sulfonate (AOS), manufactured by Lion Corp., LIPOLAN LB-440 (active component: 36%)


*3Secondary sodium alkyl sulfonate (SAS), manufactured by LANXESS K.K., Mersolat H95 (active component: 95%)






INDUSTRIAL APPLICABILITY
The internal olefin sulfonate composition of the present invention can exert good foamability together with light foam quality, and instantaneous foam dissipation property at high levels. Thus, the internal olefin sulfonate composition of the present invention can be used suitably in the fields of household cleansing agents such as hair shampoos, body cleansers, laundry detergents, kitchen detergents, and residential detergents, and is also suitable for cosmetic emulsifiers, industrial emulsifiers, industrial cleansing agents or the like.

## Claims

1. A cleansing composition comprising an internal olefin sulfonate mixture comprising (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10,
wherein the foamability of the cleansing composition comprising the mixture of internal olefin sulfonates is better than if the mixture of internal olefin sulfonates was replaced with secondary sodium alkyl sulfonate, and
wherein the foam dissipation property of the cleansing composition comprising the mixture of internal olefin sulfonates is better than if the mixture of internal olefin sulfonates was replaced with sodium α-sulfonate.

2. The cleansing composition according to claim 1, wherein a content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the internal olefin sulfonate having 12 and 14 carbon atoms is 28% by mass or less.

3. The cleansing composition according to claim 1, wherein a mass ratio of a content of a hydroxy form in the internal olefin sulfonate having 12 and 14 carbon atoms to a content of an olefin form in the internal olefin sulfonate having 12 and 14 carbon atoms, (hydroxy form/olefin form), is from 50/50 to 100/0.

4. The cleansing composition according to claim 1, wherein, in the internal olefin mixture, a content of a raw material internal olefin in the internal olefin sulfonate mixture is less than 5.0% by mass with respect to the amount of the internal olefin sulfonate.

5. The cleansing composition according to claim 1, wherein a the content of an inorganic compound in the internal olefin sulfonate mixture is less than 7.5% by mass with respect to the amount of the internal olefin sulfonate.

6. The cleansing composition according to claim 1, wherein the internal olefin sulfonate mixture is obtained by sulfonating a raw material containing a raw material internal olefin, followed by neutralization and then hydrolysis, with a content of the raw material internal olefin in which a double bond is present at a C-2 position being from 15 to 40% by mass.

7. The cleansing composition according to claim 1, wherein a content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate mixture is from 75/25 to 90/10.

8. The cleansing composition according to claim 1, wherein a content mass ratio of the component (A) to the component (B), (A/B), in the internal olefin sulfonate mixture is from 10/90 to 30/70.

9. The cleansing composition according to claim 1, wherein a total content of (A) the internal olefin sulfonate having 12 carbon atoms and (B) the internal olefin sulfonate having 14 carbon atoms is from 0.1 to 80% by mass.

10. The cleansing composition according to claim 1, comprising one or more selected form the group consisting of an alkyl sulfate and an alkyl polyoxyalkylene sulfate.

11. A method for enhancing foamability and foam dissipation property of a cleansing composition comprising:
mixing with the cleansing composition an internal olefin sulfonate composition comprising (A) an internal olefin sulfonate having 12 carbon atoms and (B) an internal olefin sulfonate having 14 carbon atoms, wherein a content mass ratio of the component (A) to the component (B), (A/B), is from 10/90 to 90/10,
wherein the foamability of the cleaning composition is better than if the mixture of internal olefin sulfonates was replaced with secondary sodium alkyl sulfonate, and
wherein the foam dissipation property of the cleansing composition is better than if the mixture of internal olefin sulfonates was replaced with sodium α-olefin sulfonate.

12. The method according to claim 11, wherein the cleansing composition comprises an alkyl sulfate or an alkyl polyoxyalkylene sulfonate.

13. The method according to claim 11, wherein the cleansing composition comprises water.

14. The method according to claim 11, wherein the content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the internal olefin sulfonate having 12 and 14 carbon atoms is less than 25% by mass.

15. The method according to claim 11, wherein a mass ratio of the content of a hydroxy form to the content of an olefin form, (hydroxyl form/olefin form), in the internal olefin sulfonate having 12 and 14 carbon atoms is from 50/50 to 100/0.

16. A method for enhancing foamability and foam dissipation property of a cleansing composition comprising:
mixing with the cleansing composition (A) an internal olefin sulfonate having 12 carbon atoms; and
mixing with the cleansing composition (B) an internal olefin sulfonate having 14 carbon atoms,
wherein, after the mixing of component (A) and component (B) with the cleansing composition, a content mass ratio of the component (A) to the component (B), (A/B), in the cleansing composition is from 10/90 to 90/10,
wherein the foamability of the cleaning composition is better than if the mixture of internal olefin sulfonates was replaced with secondary sodium alkyl sulfonate, and
wherein the foam dissipation property of the cleansing composition is better than if the mixture of internal olefin sulfonates was replaced with sodium α-olefin sulfonate.

17. The method according to claim 16, wherein the cleansing composition comprises an alkyl sulfate or an alkyl polyoxyalkylene sulfonate.

18. The method according to claim 16, wherein the cleansing composition comprises water.

19. The method according to claim 16, wherein the content of the internal olefin sulfonate in which a sulfonate group is present at a C-2 position in the internal olefin sulfonate having 12 and 14 carbon atoms is less than 25% by mass.

20. The method according to claim 16, wherein a mass ratio of the content of a hydroxy form to the content of an olefin form, (hydroxyl form/olefin form), in the internal olefin sulfonate having 12 and 14 carbon atoms is from 50/50 to 100/0.

21. A method for washing hair, comprising applying the cleansing composition according to claim 1 to hair, followed by washing and then rinsing.

22. A method for washing skin, comprising applying the cleansing composition according to claim 1 to the skin, followed by washing and then rinsing.

23. The cleaning composition according to claim 1 for washing hair.

24. The cleaning composition according to claim 1 for washing skin.

25. The cleansing composition according to claim 1 for dishwashing.

26. The cleansing composition according to claim 1 for laundry detergent.

27. A method of washing dishes, comprising:
applying the cleansing composition of claim 1 to dishes.

28. A method of washing laundry, comprising:
applying the cleansing composition of claim 1 to laundry.