... , 

I 

Pennsylvania Department of Environmental Resources 

Southwest Regional Office 

400 Waterfront Drive 

Pittsburgh, PA 15222 

Re: Chief Oil & Gas LLC 

26R Submittal 

Somerset and Greene Counties 

Dear"Sir or Madame: 

Enclosed please find Chief's 26R submittal for the above referenced county or counties. 

Included for each county are the following: 

• Form26R; 

• Form 26R Attachments; and 

• Analysis representing the residual waste. 

Should you have any questions or require additional information, please do not hesitate to 

contact me at (724) 933-5511. 

Sincerely, 

Senior Water Resource s Coordinator 

6051 Wallace Road Ext., Suite 300 • Wexford, PA 15090 • (724) 933-5511 • (724) 933-5519 fax • www.chiefog.com 

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prepared. The date on awlched sheets needs to match the date noted below. 

General Reference 

Date Prepared/Revised 2-28-11 

~~~~~~~~~~~~~~~~~~~~~u- ~ Mailing Address 

c. Physical Appearance 

- 1 -

Ext 

No 
Address Line 1 

Address l.ine 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title 

Phone 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title · 

Phone 

year. 

(check one) 

0 D ton (check one) 

a. Has the waste 

If ''Yes", list the general permit number or number. 

vu11u•"•"' of waste beneficially used in the previous year. 

n/a D cuyd D gal D lb D ton (check one) 

-2-

No 
Form Submitted: 

0 Other (specify) 

Date Submitted: 

O I certify the information required in Section B-2, Chemical Analysis was supplied to the Department for the year 

__ and has not changed. 

Form Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required in Section B-3, Process Description and Schematic, was su~plied to the Department 

for the year __ and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

Title Senior Water Resources Coordinator 

Date 2-28-11 

- 3-
c. Facility Contact: John Snedden 

Title: Operations Coordinator 

Phone: 814-437-3593 

d. Volume previous year: 0 

a. Permit Number: PA0095273 

b. Facility: Pennsylvania Brine 

Bells Mills Rd 

Josephine, PA 15750 County: Indiana 

c. Facility Contact: Becky Snyder 

Title: Operations Coordinator 

Phone: 724-248-1000 

d. Volume previous year: 0 

a. Permit Number: PA0091472 

b. Facility: Tunnelton Liquids 

671 Hogue Dr 

Saltsburg, P A 15681 County: Indiana 

c. Facility Contact: Bruce Bufalini 

Title: Plant Manager\ 

Phone: 724-459-6138 

d. Volume previous year: 0 

a. Permit Number: SWIW#34 

b. Facility: Stallion - Groselle Well 

SR 88 N. of Adams Rd 

Garrettsville, OH County: Portage 

c. Facility Contact: Mark Wimsatt 

Title: Operations Manager 

Phone: 330-868-2083 

d. Volume previous year: 0 

a. Permit Number: SWIW#11 

b. Facility: David R. Hill!Devco Unit #1 

221 1/2 S 6th St 

Byesville, OH 43723 County: Guernsey 

c. Facility Contact: David R. Hill 

Title: President 

Phone: 740-685-5168 

d. Volume previous year: 0 
This waste is generated from the process of hydrofracturing, whereby hydraulic pressure is applied to a 

reservoir formation to create fractures through which ga5 may move to the wellbore, in the course of 

Marcellus Shale gas well development. Once used, the water returns to the surface through the 

wellbore. 

Section B (3) b: Process Description & Schematic Attachments -Schematic of Process 

Frac 

TankMixing 

\ Fracing fluids are 

Frac 

TankStorage 

mixed in frac tank: r 

water plus small 1 water returns post-hydrofracturing 

amounts of 

additives, examples 

ofwhich are 

provided at 

www.chiefog.com/fracturing fluids.html hydro:fracturing process 
Ms. Margeret Farrell 

Chief Oil and Gas LLC 

6051 Wallace Road Ext. 

Suite 210 

Wexford, PA 15090 

November 26, 2010 

Dear Ms. Farrell, 

Enclosed are the analytical results for samples received by the laboratory on Tuesday, November 02, 

2010 

ALSI Is a National Environmental Laboratory Accreditation Program (NELAP} accredited laboratory and 

as such, certifies that all applicable test results meet the requirements of NELAP. 

If you have any questions regarding this certificate of analysis, please contact Shannon Butler (Project 

Coordinator} or Anna G Milliken (Laboratory Manager} at (717} 944-5541. 

Please visit us at www.anaJyticallab.com for a listing of ALSI's NELAP accreditations and Scope of Work, 

as well as other links to Water Quality documentation on the internet. 

This laboratory report may not be reproduced, except in full, without the written approval of ALSI. 

NOTE: ALSI has changed the report generation tool and while we have tried to retain the existing 

format, you will notice some changes in the laboratory report. Please feel free to contact ALSI in case 

you have any questions. 

Analytical Laboratory Services, Inc. 

CC: Mr. Matt Kapral 

This page Is included as part of the Analytical Report and 

must be retained as a permanent record thereof. 

ReportiD:9873685 

a___/,2~ 

Anna G Milliken 

Laboratory Manager 

Page 1 of20 
9873685001 Bowers West 1-H Flow Back Water 11/1/10 10:05 11/2/10 09:10 Robert McNair 

Workorder Comments: 

Notes 

- Samples collected by ALSI personnel are done so in with the procedures set forth in the ALSI Field Sampling Plan (20 -

Field Services Sampling Plan). 

- All Waste Water analyses comply with methodology requirements of 40 CFR Part 136. 

- All Drinking Water analyses comply with methodology requirements of 40 CFR Part 141. 

- Unless otherwise noted, all ·quantitative results for soils are reported on a dry weight basis. 

- The Chain of Custody document is included as part of this report. 

Standard Acronyms/Flags 

J, B Indicates an estimated value between the Method Detection Limit (MDL) and the Practical Quantitation Limit (PQL) for the analyte 

U Indicates that the analyte·was Not Detected (NO) 

N 

MDL 

PQL 

RDL 

ND 

Cntr 

RegLmt 

LCS 

MS 

MSD 

DUP 

%Rec 

RPD 

Indicates presumptive evidence of the presence of a compound 

Method Detection Limit 

Practical Quantitatlon Limit Reporting Detection Limit Not Detected - indicates that the analyte was Not Detected at the RDL 

Analysis was performed using this container 

Regulatory Limit 

Laboratory Control Sample 

Matrix Spike 

Matrix Spike Duplicate 

Sample Duplicate 

Percent Recovery Relative Percent Difference 

ReportiD:9873685 Page 2 of20 
Lab ID: 9873685001 

Sample 10: Bowers West 1-H Flow Back 

VOLATILE ORGANICS 

Benzene NO 

Toluene NO 

Surrogate Recoveries Results Flag 

1 ,2-Dichloroethane-d4 (S) 95 

4-Bromofluorobenzene (S) 83.4 

Dibrornofluoromethane (S) 81 .8 

Toluene-d8 (S) 94 

GLYCOLS 

Ethylene Glycol NO 

Surrogate ReCQveries Results Flag 

2-Butanone (S) 141 

WET CHEMISTRY 

Acidity, Total 143 

Alkalinity, Total 190 

Ammon ia-N 71.1 

Biochemical Oxygen 69.8 

Demand 

Bromide 415 

Chemical Oxygen Demand 566 

(COD) 

Chloride 58100 

Hardness 15600 

NitrateiNitrite-N NO 

biVGrease Hexane NO 

Extractable 

pH 6.84 

Phenolics NO 

Specific Conductance 95400 

Sulfate NO 

Surta.ctants (MBAS) NO 

Total Dissolved Solids 81200 

Total Kjeldahl Nitrogen 72.6 

Total Suspended Solids 385 

METALS 

Aluminum, Total NO 

Arsenic, Total NO 

Barium, Total 2400 

Beryllium, Total NO 

Boron, Total 13.2 

Cadmium, Total NO 

Calcium, Total 4290 

Report 10: 9873685 

ug/L 

ug/L 

Units 

o/o 

o/o 

o/o 

o/o 

mg/L 

Units 

% 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

pH_Units 

mg/L 

umhos/cm 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mgll 

mgll 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

Date Collected: 111112010 10:05 

Date Received: 11/2/2010 09:10 

1.0 SW846 8260B 

1.0 SW846 8260B 

Umits Method Prepared 

62-133 SW846 8260B 

79-114 SW846 8260B 

78-116 SW846 8260B 

76-127 SW846 82608 

10.0 SW846 80150 

Umits. Method Prepared 

53-147 SW846 80150 

5 SM20-2310B 

5 SM20-2320 B 

0.500 0 .6919-03 

2.0 SM20-5210 B 

150 EPA300 

300 EPA410.4 

1000 EPA300 

125 SM20-2340C 

50.0 EPA300 

1.9 . EPA 1664A 

SM20-4500-H B 

O.Q1 EPA420.4 11/9110 

SM20-2510 B 

25.0 EPA300 

0.025 SM20-5540 C 

5 SM20-2540C 

By 

By 

KRK 

2.0 SM20-4500-N C 11/18110 NON 

5 SM20-2540 D 

5.5 SW846 6010C 1113110 KMK 

0.45 SW846 6010C 1113110 KMK 

0.55 SW846 6010C 1113110 KMK 

0.22 SW8466010C 1113110 KMK 

5.5 SW846 6010C 1113110 KMK 

0.11 SW846 6010C 1113/10 KMK 

5.5 SW846 6010C 1113110 KMK 

Matrix: Water 

1119110 23:33 DJB 0 

'111911 0 23:33 DJB 0 

Analyzed By Cntr 

1119110 23:33 DJB D 

1119110 23:33 OJB 0 

1119110 23:33 DJB 0 

11/9110 23:33 OJB 0 

11115110 23:31 JJH 

Analyzed By Cntr 

11/15110 23:31 JJH 

11/9110 12:00 NJA B 

11/3110 14:02 SAO B 

1118110 13:44 LMM A 

1113110 02:54 JEP B 

1113110 08:01 J1H B 

11/10110 08:53 LMM A 

1114/10 14:38 J1H B 

1119/10 08:46 LMM E 

11/3/10 08:01 J1H B 

11/15110 04:00 JJS G 

11/2/10 09:32 NJA B 

11110110 13:11 TMG H 

11/3/10 14:02 SAO B 

1113/10 07:48 J1H B 

11/2/10 21:30 SAD F 

11/3110 15:55 KAK B 

11118110 10:30 ARK A4 

11/3110 03:25 LJF B 

11111110 15:33 JWK E1 

11111110 15:33 JWK E1 

11111110 15:33 JWK E1 

11111110 15:33 JWK E1 

11111110 15:33 JWK E1 

11/11110 15:33 JWK E1 

11/11110 15:33 JWK E1 

Page 3of20 
Lab ID: 9873685001 

Sample 10: Bowers West 1·H Flow Back 

NO 

44.6 

Iron, Dissolved 44.0 

Lead, Total NO 

Lithium, Total 61 .2 

Magnesium, Total 463 

Manganese, Total 1.7 

Mercury, Total NO 

Molybdenum, Total NO 

Nickel, Total NO 

Selenium, Total NO 

Silver, Total NO 

Sodi.um, To.tal 20400 

Strontium, Total 951 

Thorium, Total NO 

Uranium, Total NO 

Zinc, Total NO 

FIELD. PARAMETERS 

pH, Field (EPA 150.1) 6.83 

Specific Conductance, Field 89500 

Sub'd-GEL Labs NELAP CERTIFIED 

Gross Alpha See 

Attached 

Gross Beta See 

Attached 

Radium 226 See 

Atb:lched 

Radium228 See 

Attached 

Sample Comments: 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mgll 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L 

pH_Units 

umhos/cm 

Date Collected: 11/1/2010 10:05 

Date Received: 11/2/2010 09:10 

SW846 6010C 

0.55 SW846 6010C 

3.4 SW846 6010C 

6.0 SW8466010C 

0.34 SW8466010C 

5.5 SW8466010C 

5.5 SW8466010C 

0.30 SW846 6010C 

0.00050 SW8467470A 

1.1 SW8466010C 

1.1 SW8466010C 

1.1 SW846 6010C 

0.22 SW846 6010C 

28.0 SW8466010C 

0.30 SW8466010C 

5.5 SW8466010C 

11.0 SW846 6010C 

1.1 SW846 6010C 

SM4500B 

SM20-2510 B 

Subcontract 

Subcontract 

Subcontract 

Subcontract 

KMK 

KMK 

KMK 

JWK 

KMK 

11/3/10 KMK 

11/3/10 KMK 

11/3/10 KMK 

11/5/10 MNP 

11/3/10 KMK 

11/3/10 KMK 

H/3/10 KMK 

11/3/10 KMK 

11/3/10 KMK 

11/3/10 KMK 

11/3/10 KMK 

11/3/10 KMK 

11/3/10 KMK 

MBAS calculated as LAS molecular weight 342 g/mol. 

Matrix: Water 

JWK 

JWK 

11/11/10 15:33 JWK 

11/10/10 17:20 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/5110 11:32 MNP 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/11/10 15:33 JWK 

11/1/10 10:05 JRM 

11/1/10 10:05 JRM 

11/20/10 20:21 CLT 

11/20/10 20:21 CLt 

11/23/10 13:40 CLT 

11/17/10 14:46 CLT 

Due to the strontium content, this sample required a 11100 dilution for the 6010C dissolved iron analysis. The detection limit was raised 

accordingly. 11/11/10 JWK 

Due to the barium and strontium content, this sample required a 1/50 dHution for the 6010C total metals analysis. The detection limits 

were raised accordingly. 11/12/10 JWK 

See attached subcontracted result from GEL Laboratories, LLC for Gross Alpha, Gross Beta, Radium 226, and Radium 228 results. 

SRB 11/26/10. 

Reportl0: 9873685 

E1 

E1 

E1 

J1 

E1 

E1 

E1 

E1 

E2 

E1 

E1 

E1 

E1 

E1 

E1 

E1 

E1 

E1 

K 

K 

L 

L 

N 

M 

Page4of20 
Lab ID: 9873685001 

Sample ID: Bowers West 1-H Flow Back 

Report ID: 9873685 

Date Collected: 11/1/2010 10:05 

Date Received: 11/2/2010 09:10 

Matrix: Water 

a_,___ ;;2 J,U__ 

Anna G Milliken 

Laboratory Manager 

Page 5 of20 
PARAMETER QUALIFIERS\FLAGS 

(1) Due to sample matrix interferences, this analyte was analyzed at a dilution and the detection levels adjusted accordingly. 

Report 10: 9873685 Page 6 of 20 
Report1D: 9873685 

Page 7 of20 
ReportiD:9873685 

Page 8of20 
I 

i 

ReportiD: 9873685 Page 9of20 
3400GWOODtANE 

MIDDt.ETOWif, !'A 11051 

SHIP TO: {843f55&-el1t Bn.L SEHDEA 

GentraJ Engif!eering Labs 

Genet'l Engineering Labs 

2040 sawg&' Road 

CharlestQ.n, SC 29407 

Ref# 

lrtJOiet~# 

PO# 

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III]IIIIIIMIIIIIIIII 

m 7940 a1oo 6303 'rBU - O.f NOV A1 PRIORITY OvBRNXGBT 

29407 

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A.ftt' prtnilns Ut~ ~1: . _ 

1. U. tl)e ·p,y.r~ on t~ P891t to. print Yfl.llf ~ 'o your laser or lnkiet printer. 

2. fold ~ .. p!Jfi,~ peg111 along the rizc!ntallfna. . , 

3. Place rabel'ln ~in9 poiuc:h and affbt: it l9 ~ .!lltfPment so that ct1e ba~s1)altion af1b• fabel ~., be read and scanned. 

Warili"ft: UU Gf~~Y tlw prinled original !,a~ for ahippirlg, U~ a phoiOCIOPf Of. Utis lab!J fpr's!'I!PP!f19 pu~s .Ia rr.ucl\lletl~ al)jt oollld 

raull 11'1 I '$lUng dlarges. lllong w!lh~e ~._liOt\ of YO\II" FedEli ac;tot;~nt nUmber. 

Usea{Jbf• ~~tesl'OUr 11111~!0 ""~~In l1llt CXIft'lliM FHel ~~ G!A4e, llll!lil*e Oft.ftld"elt.~,Fecle! wll nCit be 

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riot~ ac111a1 docuME~nled.ose..-.8llllrnii!Du llenl• at·~ ~!t ~s s~ e,e• ' p~roua m.~jja,llllliallable _.O!Mr llema listed 111 our SeMI:aGulde ~ •lnia mus~ ~Iliad SaXe....,.. bmlta, -see cam.nl FIKIEI< SCiovlcB ~ 

hups:lfwww.fedex.COmlshippinglhtJnlleniiPrintiFrame.html lll3/40l0 

ReportiD:9873685 Page 10of20 
a memb8f ofThe GEL Group•Nc 

C

a

eston, SC 29417 2040 SaloaQII Ro<ad Ch3rlesiM. SC 29407 

P&t3.558.8t71 F84:U&G.l1'* 

November 24, 2010 

M$. Susan B&cr 

Anal~ LabofatO.f)' $(:rvicea ~4 Posw~ Ltme 

Middl!%1wn, ~nia 1'7037 

Re: M1dd1ciown Nonl)J;P 'Reporting 

Work Order U62tl0 

ne.M~.B~: 

OEL ~ LLC (Ql!L) ap~iafe~ dio oppoi:t\U1jty l() provide-the 1Cnclo$ed analytical resutts tor 1be 

sample(s) we-rcQCiveil on N~r Q4, 2010. Thi~ ori8fnat data n:part has been pref*ed and reviewed in 

aocordaoce wijh GEL·~ &lilndard optratinf proc:cOurC$. 

Our polley is to provide high quality, penOJqtliud analylical services l() enabre you to ll!C:CI your analytical 

needs on time evetY time. We lnllll that you will flad ~e.tylhms In order and lO }'0!11 s&lis!aCtion.. If you bave 

any quostioM, plleue do n~t ltcsi~ to calf me .at (843) 5~171, ext. 4300. 

Si~)l. 

Cli41nt s.rv~ T~ Project Managet 

Page 1 otlO 

prOblem solved 

Report 10: 9873685 

-.get.com 

Page 11 of20 
ReportiD:9873685 

GEL LABORATORIES LLC 

204() Savage Road Chaltestan SC :29407 - (843) ®8.-a171 - www.gel.com 

Certificate of Analysis Report 

for 

ALSVOOJ Analytical Laboratory Semces,Inc(STND) 

Client SOO: 266280 GEL Work Order: 266280 

The QaaUft•n fD tiiJs report are defined ils tonows: 

• A quality connot analyte t"eCOv~ Is outsi4C ofllpedfied ac:cep~am:~ critcria •• ~.isasurroaate ~ · 

U AaetYto was anal~ for, bul not delec:ted above the MDL, MI)A, or·LOl). 

Where 1he analytical metbocl bll$ been perf'onncd 1111dcr ~AP ~tiOn, lb~ analysis has met allot die 

requltemltllfs of die NELAC sllindard ainle!is qWI.Iifled on the O:mficate of Analysis. 

Th11 dcsi&DaJion NJ), if~ a.ppcars .in lhe cesutt col.umn «Jien tfl:c analyte <:oncencradon is not dee~ above 

l!)e detection Urllit. 

This datlt repol;t has becn.prepaml and ""iowetl in ac:cordanc~: With GBL Labomtories Lt.C standaid opCI'atir,a procediJI'e$, Please direct any questions 10 your ,PrOject Man~gcf'. CJient Services Team. 

Rcvicwedby _ ~ ~ 

Page2 otto 

Page 12 of20 
Certificate of Analysis 

Company: Rcpon Date: November 24. 201 0 

Addless : 

M~wn, PenmylYllllia 170S7 

~onlaCt: M, .. $u$ail Baer 

P.mj"': ~tow.n Non DEP Reporting 

- · ¢UcntSampleTD:. -9813W,ooi • · -----· ·· -- - -

s-.npre m: 2~lSOMJ 

Pro~·- -~ALsVOOl03 

Client ri>: AL$VOOI 

Matrix: Wasc6 W.er 

fJOI!ec:t Date: OJ .• i\(O:V-10 10:05 

Jtccdve Date: ~liiOV•lO 

eonector: cnena 

-----

______ __.... .. 

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Page3 oflO 

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Page 13 of20 
2040 Savage Road Chllffeston, sc 29407- (843) 558-81

71 - www.geLoam 

QCSummao: ~tll!lrt Date: November %4, 2010 ,_.,~ l.o!bontery Servkes 

34 Dogwood'l.a111t 

Mlddltfown,PCIIII)I)'Ivanfa 

Paat I of 3 

Contact: MI. Susan Slier 

Workol'\tert U6l80 

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\hl!cer1alnly +1-7.74 +1-~.J 8CUI 996 ]~;i, 1180 pCVl.. HS (7~125%) U~inl.)' +1-MS -+1~ (7c12lm64m 265956001 MSD "'p ... 254 u 2.07 204 pCill. l4.3 80-2 {0%-10%) 11120110 f\);()1 Unc:ertaimy +1-2..14 +1-~9.4 a. 996 3U lifO pCiiL 6.26 107 ((1%--20%) 

Unoer111in1y +/-US +1-39.3 

.R.aut ·RII-lU ~ 1~4 ~2CIZ2.6M3 21162SCJIIOl DUP 

RWiu-226 3l30 );a,o pCiiL 9.<468 (0%·20%) KSDI ll/2llt~ J4:$0 

U...mainty +f·:Z0.2 -+1·20.3 

Page 4 of JC) 

Reportl0: 9873685 Page 14 of20 
2040 Savage Road Charleston, SC 29407- (843) 556-8171 - www.gel.corn 

Workorcf•r: 

b.re ... 

, a.iLRA-Za5 

a..cl\ 1050$34 

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2.4c.7 

Unccrtaimy. 

l14 

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is kss tban value 

value...,.ed 

'Jbe TlC is• suopacted aldoklonc!CII!Ialkm 

QCSwnmaty 

pCill. 

of./-1,&5 

0.642 JICIIL 

+1-0.35.6 

3230 3100 f(:iiL 

+f-20.2 -+i-43J) 

> 

A 

B JIO!' lbe • blanlt. 

BD ate eltherlJe!ow W. MDC ot ttacet ,_,_,is low 

C Ami)yie hll!i;becn®llflnilcd 

p from a 41Nicd •-ple 

H lime Will i:llbeedeil 

J ValUe 

K Rl)tortoct wllle Actual value bt loWIIt. 

L (lie$CIIt.ltepoJtell v.ruc may low. Actilal va!uo·l$ oxpmcd to be tripcr. 

llil 

M Mttrix F-'.lute 

"WA 

ND dc1coted llmh 

NJ Oa,la 

Q 011111 11101'!:1 "'aley COISitO.I ¢tena have mn "-"mer;. Refer tr:. the n.IY'IIivnt DER. 

... 

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·PasoSofiO 

ReportiD:9873685 

k$01 11/23/10 1-4:50 

11123/10 14:50 11/21110 14:.50 

Page 15 of20 
2040 Savage Road Ch.arl&s,ton, SC 29407 

 (843) 556

8171 

 www.get.com 

QCSummaq 

Wedtontm U6Z80 Page 3 or 3 

far-. NOM }lPD% ji"te%- - Rlln.t!.. =- P!fi 

Y s.taptc:s spiked """" !his oompoomd 

A. RPPofsa:rnple and duplfcata usint-+1-RL. ConcentJa(tons &11'0 <SX lhe JU •. Qualifier Not far R!lcfiochemistl)'. 

h or prescMIIion"*"'lnj wa. eJCCeCdcd 

t1IM limits do IIOlWb' wben sample spike by a f•ctor o_t 

Per<:eM Oiffllmll'e tbe sam9le du'plicaie (D,UP} evailaated 11gains1 the accClJiAf!ce when the sample ill arwer lhsn 

($l() 1M _r:onlrlltt niq!rifed.;!llioe&ioll timil (JU.). ln c:asee sample or d11pliQIIC is ll!$llh•n .SX 1he RL. -a conlfOl limit of+l·1bc 

die DUP l'e$Ul.t 

For PS, 1!$p,II,I:IC! SOil. T raulls1 lie vi1ua liJtcd are the lllaSUred amolihU, concentrations.. 

w1.ete !be anaty1ic::al tnelboO bas beeJ1. p111rfpl'll1e4 UDder N£LAP -die analysis tlas met all of lbt 

orthl.l N£LAC 'lll&lilied on the QC 

Page6of10 

Report 10:9873685 Page 16 of20 
DATA EXCEPTION REPORT 

~D..y'tt, 

Division: Q!lan&Y Citllt'la: 

lnalnlfntnt 

22-t«<V-10 

yYpfJ: 

Redlo!=hemteay 

~tl~ 

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GFPC EP-' i!JO.ti/Sw846 9319 UqUicl 

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P~•"**"WOdtonhor(a)(SD0}:2~858,~1~.2$6398,2f8527,~.~1,2GeU2.~88702 

Applloallon ....... , 

Fllilled Rec:Qverylor ~ F:elllld RPD forDUP 

INnltiJ'Ita D~ IJIIIPtMltlc;m: 

~DMa~n: 

1. Thlf ~~~andlhll Cluplll:llte 1~378doft0t l!ll'ei the 1. Reporting .. sullll 

bali l'lllliluw·!JeA!etJt ---~ btl'or rello ~t due1o Ill& riiii!II1X of lh8 ~ $ell'iples ,..,. a lllgtt l'IOIM!I•fiatlon o1 dlesotvect 2. Reporting results 

$011da. 

2 . The

_

rM!Itll .... ~377~110tmeei.,. ... ,..~ 

a~cai 

ulnllrillflt. Tht~--~ .:2%. 1M relatM;I ~~ 1~7trttilita~ ~" ... ~ tnallllt ' _.,.,.._ .... ~ie Is,.- 0~·~1!1 Data v.,,~ l.udltr. 

f<enah11 .. 011011 22-NOV-10 N_ul.ang ~OV-10 

Page 7 of 1() 

Report ID: 9873685 

~lalol\ No.: 2 

'!)tJII: ~ CI~ICode: 

ALSV, M!Y'. URSC 

Page 17 of20 
~~ li ~ :z ~ ~ 1 : IS r ·arr .. u 11 

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Report 10: 9873685 Page 18 of20 
mD J Laboratories uc SA

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Page 19 of20 
Reportl0:9873685 

.Page 10 of 10 

Ltfi of i: .. GEL CeJ'tiftmions 8$ of:W 2DlG 

Stare 

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Page 20 of20