November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 40

Houston

2801 Post Oak Blvd

Westlake Chemical Corporation

225-673-0680

abodron@westlake.com

Westlake Vinyls Co. - Geismar Plant

36045 Hwy 30

Geismar

Allen Bodron
ers (PVC) Production Process Wastewater

State: Texas Zip Code: 77056

hes, and related establishments owned): 2000

State: Louisiana Zip Code: 70734
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: P-1

Process Equipment ID: U-34

Wastewater Feed Rate (lb/hr): 17000

Feed Temperature (°F): 205

Feed Inlet Pressure (psia): 33

Liquid Loading Rate (liters/m2): 1.5073

Steam Feed Rate (lb/hr): 800

Steam to Feed Ratio (kg steam/liter of wastewater): 0.04196

Operating Temperature (°F): 250

Operating Pressure (psig): 17.5

Total Number of Stages: 7

Overall Calculated Tray Efficiency: 0.777777778

Stripping Factor: 0.999764706

Flow configuration (countercurrent, cocurrent): Counter

Number of Actual Trays: 9

Column Height (meters): 7.85

Year Equipment Installed: 1981

Equipment Currently Regulated Under (cite regulations): 40 CFR 61 Sub F

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: 8646 liters/hour

 liters

m design rate or capacity, please provide those values:

15892 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1 W-11 132000 396000 341000 Estimated 350 U-12 Dryer Feed Centrifuge PrOTWRAW Bio-Treatment Yes

P-1 Initiator Charge Pot Drain W-25 24 72 60 Estimated 350 U-46 Initiator Charge Pots PrOTWRAW Bio-Treatment Yes

P-1 W-26 5 60 20 Estimated 150 U-3 PVC Reactors PrOTWRAW Bio-Treatment Yes

P-1 W-27 400 2400 1200 Estimated 50 U-3 PVC Reactors PrOTWRAW Bio-Treatment Yes

Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1 U-34 Steam Stripping Continuous W-10 17300 63400 51850 Measured 355 PrOTWRAW Bio-Treatment No

Table 3. PVC Process Wastewater Destination Codes Table

Code

Wastewater treatment system WWT Provide name of the wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall

Discharge to POTW, no treatment POTWRAW Provide name of POTW

Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW

Zero discharge or alternative disposal method ZEROALT Describe method

Recycle to process RECYC Describe where in the process the stream is recycled

Other OTHER Describe

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2 3 4 5 6 7

Min Max Average

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

1

None

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

Flow Rate 

Determination 

Method

Destination Description Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or 

continuous 

operation?

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

2

Originating PVC Process 

Equipment ID

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination 

Information

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 

below)

Associated Destination 

Information

(Refer to Table 3 below)

Operating 

Days Per Year

Type of Process 

Wastewater 

Treatment System

Is this PVC process wastewater 

stream exposed to the 

atmosphere at any point between 

the outlet of the PVC process 

wastewater treatment system and 

its destination?

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

Reactor Coating / Condensate from Open Cycles

PVC Process 

Wastewater 

Stream ID

Air Evacuation Steam Jet Condensate

Centrifuge Effluent Water

14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

Operating Days Per 

Year

Is this PVC process wastewater 

stream exposed to the 

atmosphere at any point between 

the originating PVC process 

equipment and its destination?

Originating PVC Process 

Equipment Description
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)

Note (1): Based on historical data for gases analyzed by SW-846 Method 8260B (SW-5030B Purge an

Note (2): The M107 VCM data result was an extrapolated value that was lower than the lowest calibrat

Note (3): The reported value for "Xylenes (isomers and mixtures)" CAS 1330207 is the higher value of 

Note (4): Hydroquinone sample result rejected due to lack of recovery in the associated LCS.
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

Westlake Chemical Corporation

Westlake Vinyls Co. - Geismar Plant

U-34

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 0.6 Non-detect

SW-846-8015C 14.2 N

SW-846-8315A 1.86 N

SW-846-8315A 0.721 N

SW-846-8270D 0.00631 Non-detect

SW-846-8270D 0.00729 Non-detect

SW-846-8270D 0.0103 Non-detect

SW-846-8270D 0.3 Non-detect

SW-846-8270D 0.00349 Non-detect

SW-846-8260B 0.00092 Non-detect

SW-846-8260B 0.00651 N

SW-846-8260B 0.0045 Non-detect

SW-846-8260B 0.00047 Non-detect

SW-846-8260B 0.00046 Non-detect

SW-846-8260B 0.00109 Non-detect

SW-846-8260B 0.0033 Non-detect

SW-846-8260B 0.00057 Non-detect

SW-846-8260B 0.174 N

SW-846-8260B 0.00058 Non-detect

SW-846-8260B 0.37 N

SW-846-8260B 0.00116 Non-detect

SW-846-8260B 0.106 N

SW-846-8260B 0.00418 Non-detect

SW-846-8260B 0.0167 Non-detect

Flow Rate Determination Method --> Measured

ETC 93427 / WVC AC39081

ETC 13-008-0228 / WVC PVC010713

1/7/13-1/14/13

116.6

44

01/07/13

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Suspension
SW-846-8260B 0.00049 Non-detect

SW-846-8260B 0.00138 Non-detect

SW-846-8260B 0.00044 Non-detect

SW-846-8260B 0.00067 Non-detect

SW-846-8260B 0.001 TIC

EPA Method 107 2.4 N

SW-846-8260B 0.00116 N

SW-846-8260B 0.00124 Non-detect

ases analyzed by SW-846 Method 8260B (SW-5030B Purge and Trap), the method quantitation limit (MQL) for Vinyl Bromide is estimated to 

as an extrapolated value that was lower than the lowest calibration standard value as per the Method.

es (isomers and mixtures)" CAS 1330207 is the higher value of the mp-Xylene and o-Xylene results.

ejected due to lack of recovery in the associated LCS.
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

13.9 N

1.28 N

J 0.732 N J

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00083 N J

J 0.0048 Non-detect

0.00045 Non-detect UJ

0.00004 Non-detect UJ

0.00004 Non-detect UJ

0.0001 Non-detect UJ

0.00033 Non-detect UJ

0.00005 Non-detect UJ

J 0.0661 N J

0.00005 Non-detect UJ

0.15 N J

0.00011 Non-detect UJ

J 0.0625 N J

0.00041 Non-detect UJ

0.00167 Non-detect UJ

Measured Measured

VC PVC010713 ETC13-010-0207 / WVC PV010813

01/08/13

1 2

118.4

36

1/8/13-1/15/13

ETC93898 / WVC AC39107

Suspension
0.00004 Non-detect UJ

0.00013 Non-detect UJ

0.00071 N J

UJ 0.00006 Non-detect UJ

Note (1) 0.001 TIC Note (1)

Note (2) 1.1 Note (2)

J 0.00104 N J

Note (3) 0.00012 Non-detect UJ Note (3)

d quantitation limit (MQL) for Vinyl Bromide is estimated to be 1 ug/L. Due to the fact that calibration standards and verification standards w

 as per the Method.

 o-Xylene results.
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

0.2 Non-detect 100.4 N

7.48 N U 2.79 N

3.13 N UJ 0.86 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00062 N J 0.00092 Non-detect

0.00138 N 0.0024 Non-detect

0.00045 Non-detect 0.0045 Non-detect

0.00014 N J 0.00047 Non-detect

0.00004 Non-detect 0.00046 Non-detect

0.0001 Non-detect 0.00109 Non-detect

0.00033 Non-detect 0.0033 Non-detect

0.00005 Non-detect 0.00057 Non-detect

0.0745 N 0.104 N

0.00005 Non-detect 0.00058 Non-detect

0.102 N 0.0927 N

0.00011 Non-detect 0.00116 Non-detect

0.0552 N 0.0696 N

0.00041 Non-detect 0.00418 Non-detect

0.00167 Non-detect 0.0167 Non-detect

Measured Measured

ETC13-010-0208 / WVC PV010913 ETC13-014-0206 / WVC PVC RVCM 101013

1/10/13-1/17/13

01/09/13 01/10/13

3

118.4 118.4

38 40

1/9/13-1/16/13

ETC93899 / WVC AC39252 ETC94534 / WVC AC39363

Suspension Suspension
0.00052 N J 0.00049 Non-detect

0.00013 Non-detect 0.00138 Non-detect

0.00097 N J 0.00044 Non-detect

0.00006 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

1.3 Note (2) 1.4

0.00054 N J 0.00098 N

0.00012 Non-detect Note (3) 0.00124 Non-detect

d verification standards were not readily available, estimated concentrations would be reported for Vinyl Bromide. Estimated concentrations 
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

79.6 N

2.77 N U

J 1.02 N J

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.0932 N

0.00058 Non-detect

0.0766 N

0.00116 Non-detect

0.062 N

0.00418 Non-detect

0.0167 Non-detect

Measured Measured

C PVC RVCM 101013 ETC13-014-0207 / WVC 130111173815

1/11/13-1/17/13

01/11/13

4 5

118.4

38

ETC94535 / WVC AC39449

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

 0.001 TIC Note (1)

 1.5 Note (2)

J 0.00071 Non-detect

Note (3) 0.00124 Non-detect Note (3)

de. Estimated concentrations are calculated based on the closest Internal Standard.
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

1 N U 0.6 Non-detect

130 N 189 N

0.996 N 1.31 N

0.527 N 0.255 N

0.0631 Non-detect 0.0316 Non-detect

0.0729 Non-detect 0.0365 Non-detect

0.103 Non-detect 0.0516 Non-detect

0.3 Non-detect UJ 0.15 Non-detect

0.0349 Non-detect 0.0175 Non-detect

0.00009 Non-detect 0.00009 Non-detect

0.00024 Non-detect 0.00225 N

0.00045 Non-detect 0.00045 Non-detect

0.00004 Non-detect 0.001 N

0.00004 Non-detect 0.00004 Non-detect

0.0001 Non-detect 0.0001 Non-detect

0.00033 Non-detect 0.00033 Non-detect

0.00005 Non-detect 0.00005 Non-detect

0.07 N 0.0509 N

0.00005 Non-detect 0.00005 Non-detect

0.465 N 0.42 N

0.00011 Non-detect 0.00011 Non-detect

0.0623 N 0.037 N

0.00041 Non-detect 0.00041 Non-detect

0.00167 Non-detect 0.00167 Non-detect

Measured Measured

ETC13-025-0211 / WVC 130123134324 ETC13-025-0212 / WVC 130124145508

1/23/13-1/31/13 1/24/13-1/31/13

116.6

6

01/23/13 01/24/13

113

40 37

ETC96990 / WVC AC40667 ETC96992 / WVC AC40777

Suspension Suspension
0.00004 Non-detect 0.00004 Non-detect

0.00013 Non-detect 0.00013 Non-detect

0.00111N 0.00152N

0.00006 Non-detect 0.00006 Non-detect

0.001 TIC Note (1) 0.001 TIC

1.6 Note (2) 1.5

0.001N

U 0.00007 Non-detect

0.000120 Note (3) 0.000120
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

3 N U

143 N

0.998 N

0.227 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

U 0.00047 Non-detect

0.00046 Non-detect

0.01 N U

0.0033 Non-detect

0.00057 Non-detect

0.0968 N

0.00058 Non-detect

0.385 N

0.00116 Non-detect

0.0507 N

0.013 N J

0.0167 Non-detect

Measured Measured

ETC97255 / WVC AC40883

C 130124145508 ETC13-028-0204 / WVC 130125143226

1/25/13-2/01/13

7 8

113

01/25/13

37

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

Note (2) 1.6 Note (2)

0.00071 Non-detect

Note (3) 0.00124

0 Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

2.3 N U 3.5 N

247 N 211 N

2.05 N 1.73 N

0.822 N 0.783 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

NO RESULT R Note (4) NO RESULT

0.0349 Non-detect 0.0349 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.0616 N 0.0404 N

0.00058 Non-detect 0.00058 Non-detect

0.324 N 0.147 N

0.00116 Non-detect 0.00116 Non-detect

0.039 N 0.0339 N

0.0286 N J 0.033 N

0.0167 Non-detect 0.0167 Non-detect

ETC97467 / WVC AC40998 ETC97470 / WVC AC41113

ETC13-029-0224 / WVC 130126164003 ETC13-029-0225 / WVC 130127164504

1/26/13-2/4/13 1/27/13-2/4/13

9

113 113

01/26/13 01/27/13

Suspension Suspension

Measured Measured

34 31
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

1.4 Note (2) 0.8

0.00071 Non-detect 0.00071 Non-detect

0.001240 Note (3) 0.001240
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 3 N U

131 N

1.75 N

0.709 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

R Note (4) NO RESULT R Note (4)

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

J 0.0861 N J

0.00058 Non-detect

J 0.132 N J

0.00116 Non-detect

J 0.0355 N J

J 0.0321 N J

0.0167 Non-detect

ETC97485 / WVC AC41229

C 130127164504 ETC13-029-0226 / WVC 130128133801

1/28/13-2/4/13

10 11

123.8

01/28/13

31

Measured Measured

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

Note (2) 1.6 Note (2)

0.0321 Non-detect

Note (3) 0.00124 Non-detect Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

4.6 N U 5.2 N

126 N 184 N

2.06 N 3.07 N

0.713 N 0.68 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0143 N J 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.129 N J 0.0841 N

0.00058 Non-detect 0.00058 Non-detect

0.178 N J 0.105 N

0.00116 Non-detect 0.00116 Non-detect

0.0542 N J 0.027 N

0.00418 Non-detect 0.0167 N

0.0167 Non-detect 0.0167 Non-detect

ETC97881 / WVC AC41349 ETC97884 / WVC AC41468

ETC13-031-0225 / WVC 130129164027 ETC13-031-0226 / WVC 130130165937

1/29/13-2/11/13 1/30/13-2/7/13

12

01/29/13 01/30/13

31 30

116.6 118.4

Measured Measured

Suspension Suspension
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00241N

J 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

1.7 Note (2) 2.5

0.00071 Non-detect 0.00071 Non-detect

0.00124 Non-detect Note (3) 0.001240
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

U 0.6 Non-detect UJ

27 N J

2.83 N

0.815 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.0549 N J

0.00058 Non-detect

0.121 N J

0.00116 Non-detect

0.0301 N J

J 0.00418 Non-detect

0.0167 Non-detect

ETC98367 / WVC AC41590

C 130130165937 ETC13-035-0215 / WVC 130131193237

1/31/13-2/16/13

01/31/13

13 14

30

120.2

Measured Measured

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

Note (2)

1 Note (2)

0.00071 Non-detect

Note (3) 0.00124

0 Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

1 N U 0.6 N

29.4 N J 31 N

2.13 N 2.59 N

0.813 N 0.922 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0105 N J 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.0465 N J 0.0371 N

0.00058 Non-detect 0.00058 Non-detect

0.119 N J 0.0938 N

0.00116 Non-detect 0.00116 Non-detect

0.0348 N J 0.0296 N

0.00418 Non-detect 0.00418 Non-detect

0.0167 Non-detect 0.0167 Non-detect

ETC98768 / WVC AC41843

31

ETC98369 / WVC AC41711

ETC13-035-0216 / WVC 130201163526 ETC13-036-0241 / WVC 130202154946

2/1/13-2/13/13 2/2/13-2/15/13

02/01/13 02/02/13

111.2

Measured

15

30

107.6

Measured

Suspension Suspension
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

0.67 Note (2) 0.71

0.00071 Non-detect 0.00071 Non-detect

0.001240 Note (3) 0.001240
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

J 0.6 Non-detect

J 32.3 N J

2.4 N

0.92 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

J 0.053 N J

0.00058 Non-detect

J 0.102 N J

0.00116 Non-detect

J 0.0273 N J

0.00418 Non-detect

0.0167 Non-detect

ETC98770 / WVC AC41958

2/3/13-2/15/13

32

C 130202154946 ETC13-036-0242 / WVC 130203132624

114.8

02/03/13

Measured Measured

16 17

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

Note (2) 0.9 Note (2)

0.00071 Non-detect

Note (3) 0.00124 Non-detect Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

76 N 26.5 N

2.76 N 1.91 N

0.89 N 0.765 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.099 N J 0.17 N

0.00058 Non-detect 0.00058 Non-detect

0.153 N J 0.139 N

0.00116 Non-detect 0.00116 Non-detect

0.0759 N J 0.0594 N

0.00418 Non-detect 0.00418 Non-detect

0.0167 Non-detect 0.0167 Non-detect

ETC98764 / WVC AC42087 ETC99441 / WVC AC42257

2/4/13-2/15/13

40 32

ETC13-036-0240 / WVC 130204194456 ETC13-038-0262 / WVC 130205201934

118.4 116.6

2/5/13-2/27/13

02/04/13

Measured Measured

02/05/13

18

Suspension Suspension
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

1.8 Note (2) 3.6

0.00071 Non-detect 0.00071 Non-detect

0.00124 Non-detect Note (3) 0.00124 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

J 24.1 N

1.24 N U

0.721 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.0501 N

0.00058 Non-detect

0.0765 N

0.00116 Non-detect

0.0426 N

0.00418 Non-detect

0.0167 Non-detect

ETC13-038-0263 / WVC 130206144957

ETC99443 / WVC AC42381

C 130205201934

118.4

2/6/13-2/17/13

02/06/13

30

Measured Measured

19 20

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

0.5 Note (2)

0.00071 Non-detect

Note (3) 0.00124 Non-detect Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

50.7 N 38.1 N

0.696 N 2.51 N

0.586 N 0.599 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00092 Non-detect 0.00092 Non-detect

0.0024 Non-detect 0.0024 Non-detect

0.0045 Non-detect 0.0045 Non-detect

0.00047 Non-detect 0.00047 Non-detect

0.00046 Non-detect 0.00046 Non-detect

0.00109 Non-detect 0.00109 Non-detect

0.0033 Non-detect 0.0033 Non-detect

0.00057 Non-detect 0.00057 Non-detect

0.0521 N 0.0528 N

0.01 N U 0.00058 Non-detect

0.0772 N 0.0729 N

0.00116 Non-detect 0.00116 Non-detect

0.0365 N 0.0458 N

0.00418 Non-detect 0.00418 Non-detect

0.0167 Non-detect 0.0167 Non-detect

ETC89389 / WVC AC42495 ETC89392 / WVC AC42588

ETC13-042-0201 / WVC 130207160810 ETC13-042-0202 / WVC 130208183253

2/7/13-2/21/13 2/8/13-2/21/13

32 32

120.2

02/07/13 02/08/13

118.4

Measured Measured

21

Suspension Suspension
0.00049 Non-detect 0.00049 Non-detect

0.00138 Non-detect 0.00138 Non-detect

0.00044 Non-detect 0.00044 Non-detect

0.00067 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

0.7 Note (2) 1.1

0.00071 Non-detect 0.00071 Non-detect

0.00124 Non-detect Note (3) 0.00124 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

30.7 N

1.4 N

0.703 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.049 N

0.00058 Non-detect

0.063 N

0.00116 Non-detect

0.036 N

0.05 N U

0.0167 Non-detect

ETC89819 / WVC AC42698

C 130208183253 ETC13-043-0237 / WVC 130209132522

02/09/13

22 23

2/9/13-2/21/13

34

Measured

118.4

Measured

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

Note (2) 0.76 Note (2)

0.00071 Non-detect

Note (3) 0.00124 Non-detect Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

27.5 N 20.3 N

0.024 N U 0.642 N

0.03 Non-detect 0.737 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00092 Non-detect 0.00009 Non-detect

0.0024 Non-detect 0.00179 N

0.0045 Non-detect 0.00045 Non-detect

0.00047 Non-detect 0.00044 N

0.00046 Non-detect 0.00004 Non-detect

0.00109 Non-detect 0.0001 Non-detect

0.0033 Non-detect 0.00033 Non-detect

0.00057 Non-detect 0.00005 Non-detect

0.0456 N 0.0223 N

0.00058 Non-detect 0.00005 Non-detect

0.058 N 0.0284 N

0.00116 Non-detect 0.00011 Non-detect

0.0327 N 0.0132 N

0.05 N U 0.00041 Non-detect

0.0167 Non-detect 0.00167 Non-detect

ETC89821 / WVC AC42824 ETC89823 / WVC AC42935

34 20

02/10/13 02/11/13

24

118.4

Measured Measured

2/10/13-2/21/13 2/11/13-2/22/13

ETC13-043-0238 / WVC 130210155611 ETC13-043-0239 / WVC 130211145245

118.4

Suspension Suspension
0.00049 Non-detect 0.00004 Non-detect

0.00138 Non-detect 0.00013 Non-detect

0.00044 Non-detect 0.00004 Non-detect

0.00067 Non-detect 0.00006 Non-detect

0.001 TIC Note (1) 0.001 TIC

0.73 Note (2) 0.41

0.00071 Non-detect 0.00007 Non-detect

0.00124 Non-detect Note (3) 0.00012 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

12.6 N

0.291 N B

0.625 N

0.00631 Non-detect

0.00729 Non-detect

0.0103 Non-detect

UJ 0.03 Non-detect UJ

0.00349 Non-detect

0.00009 Non-detect UJ

0.00197 N J

0.00045 Non-detect UJ

J 0.00057 N J

0.00004 Non-detect UJ

0.0001 Non-detect UJ

0.00033 Non-detect UJ

0.00005 Non-detect UJ

0.014 N J

0.00005 Non-detect UJ

0.0123 N J

0.00011 Non-detect UJ

0.00852 N J

0.00041 Non-detect UJ

0.00167 Non-detect UJ

ETC90299 / WVC AC43051

2/12/13-2/22/13

ETC13-045-0216 / WVC 130212150559

Measured

15

118.4

02/12/13

25

Measured

26

C 130211145245

Suspension
0.00004 Non-detect UJ

0.00013 Non-detect UJ

0.00004 Non-detect UJ

0.00006 Non-detect UJ

Note (1) 0.001 TIC Note (1)

Note (2) 2.7U

0.00007 Non-detect UJ

Note (3) 0.00012 Non-detect UJ Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect 0.6 Non-detect

12.1 N 16.3 N

0.349 N B 0.928 N

0.702 N 0.796 N

0.0631 Non-detect 0.0631 Non-detect

0.0729 Non-detect 0.0729 Non-detect

0.103 Non-detect 0.103 Non-detect

0.3 Non-detect UJ 0.3 Non-detect

0.0349 Non-detect 0.0349 Non-detect

0.00009 Non-detect 0.00092 Non-detect

0.00192 N 0.0024 Non-detect

0.00045 Non-detect 0.0045 Non-detect

0.00068 N J 0.00047 Non-detect

0.00004 Non-detect 0.00046 Non-detect

0.0001 Non-detect 0.00109 Non-detect

0.00033 Non-detect 0.0033 Non-detect

0.00005 Non-detect 0.00057 Non-detect

0.0247 N 0.0635 N

0.00005 Non-detect 0.00058 Non-detect

0.0237 N 0.0586 N

0.00017 N J 0.00116 Non-detect

0.0161 N 0.0383 N

0.00041 Non-detect 0.00418 Non-detect

0.00167 Non-detect 0.0167 Non-detect

ETC90301 / WVC AC43188 ETC90771 / WVC AC43303

2/13/13-2/24/13 2/14/13-2/24/13

ETC13-045-0242 / WVC 130213145344 ETC13-049-0210 / WVC 130214171512

Measured Measured

15 30

118.4 116.6

27

02/13/13 02/14/13

Suspension Suspension
0.00004 Non-detect 0.00049 Non-detect

0.00013 Non-detect 0.00138 Non-detect

0.0006N

J 0.00044 Non-detect

0.00006 Non-detect 0.00067 Non-detect

0.001 TIC Note (1) 0.001 TIC

0.31 Note (2) 1.1

0.00007 Non-detect 0.00071 Non-detect

0.00012 Non-detect Note (3) 0.00124 Non-detect
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

0.6 Non-detect

16.6 N

1.27 N

0.645 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

UJ 0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.0024 Non-detect

0.0045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.076 N

0.00058 Non-detect

0.205 N

0.00116 Non-detect

0.0526 N

0.00418 Non-detect

0.0167 Non-detect

ETC90773 / WVC AC43414

29

02/15/13

36

118.4

2/15/13-2/25/13

C 130214171512

Measured Measured

ETC13-049-0211 / WVC 130215151528

28

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

Note (1) 0.001 TIC Note (1)

Note (2) 0.97 Note (2)

0.00071 Non-detect

Note (3) 0.00124 Non-detect Note (3)
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

0.6 Non-detect

21.5 N

1.53 N

0.824 N

0.0631 Non-detect

0.0729 Non-detect

0.103 Non-detect

0.3 Non-detect UJ

0.0349 Non-detect

0.00092 Non-detect

0.00024 Non-detect

0.00045 Non-detect

0.00047 Non-detect

0.00046 Non-detect

0.00109 Non-detect

0.0033 Non-detect

0.00057 Non-detect

0.0886 N

0.00058 Non-detect

0.239 N

0.00116 Non-detect

0.0447 N

0.0128 N J

0.0167 Non-detect

ETC91004 / WVC AC43530

30

02/16/13

34

116.6

2/16/13-2/27/13

ETC13-050-0204 / WVC 130216172444

Measured

Suspension
0.00049 Non-detect

0.00138 Non-detect

0.00044 Non-detect

0.00067 Non-detect

0.001 TIC Note (1)

0.91 Note (2)

0.00071 Non-detect

0.00528 Non-detect Note (3), J
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

31 32

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

33

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

34 35

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

36

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

37 38

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

39

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

40 41

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

42

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

43 44

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

45

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

46 47

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

48

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

49 50

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

51

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

52 53

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

54

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

55 56

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

57

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

58 59

Concentration 

(ppmw) Non-Detect? Note(s)

60