... , I CHIEF OIL & GAS LLC February 28, 2011 Pennsylvania Department
of Environmental Resources Southwest Regional Office 400 Waterfront Drive Pittsburgh, PA 15222 Re: Chief Oil & Gas LLC 26R Submittal Somerset and Greene Counties Dear

" Sir or Madame: Enclosed please find Chief's 26R submittal for the above referenced county or counties. Included for each county are the following: • Form26R; • Form 26R Attachments; and • Analysis representing the residual waste. Should you have any questions or require additional information, please do not hesitate to contact me at (724) 933-5511. Sincerely, Senior Water Resource

s Coordinator 6051 Wallace Road Ext., Suite 300
• Wexford, PA 15090

• (724) 933-5511

• (724) 933-5519 fax
• www.chiefog.com

r-.:> = :X ::P<" :;o **~** :1: - - .. **~** C) (./) 0 c:: --1 :c **:~o** r-,; rr, v'"l. -1\J ::0 1"'"1 C) 0 ' '1"" ·-2540-PM·BWM0347 Rev.1/2011 

# f)~'!~~~.!!."' COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT
OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT 

### FORM 26R CH

. EMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR This fonn must be accurately completed. All required infonnation must be **r--=~~~~~~~~--~** typed or legibly prir'lted the spaces provided.

If additional space is necessary, identify each attached sheet as Fonn 26R, reference the item number and identify the date prepared. The date on awlched sheets needs to match the date noted below. General Reference Date Prepared/Revised 2-28-11 **~~~~~~~~~~~~~~~~~~~~~u-**

**~** Mailing Address 

### c. Physical Appearance



### - 1 -

Ext No

# 2540-PM-BWM0347 Rev.1/2011 

# a.
A detailed the waste, as specified
in the Instructions,

is attached. 

# b.
A schematic the
control processes producing the waste, as specified
in the instructions,

is attached. 

# c.
If portions of the information submitted are confidential, the substantiation
for a confidentiality claim, as described
In the instructions,

is 

# attached. Address Line 1 Address l.ine


# 1 Address City State ZIP Municipality c. Facility Contact Name Title Phone Address Line
1 

# Address Line


# 1 Address City State ZIP Municipality c. Facility Contact Name Title

· Phone

year. 

# (check one) 

# 0



# D ton 

# (check one) 

# a. Has the waste If ''Yes", list the general permit number or number

. vu11u•"•"' 

# of waste beneficially used in the previous year. n/a



# D cuyd 

# D gal 

# D lb 

# D ton 

# (check one) 

# -2-

No N/A No

# 2540-PM-BWM0347 Rev.1/2011



# · **S~j;:TION**
**P~** 

# CER11FIC}\ TION I certify, under penalty of law, that

I have personally examined and am familiar with the information submitted
in this Annyal Report and all attached documents and that based upon my inquiry of those individuals immediately **responsibl~** 

# for obtaining the information,

I 

# verify that the submitted information

is 

# true, accurate and complete to the best of iny knowledge.



# I understand that the submission
of false information herein is made subject 

# to the penalties of 

# 18 Pa. C.S. 

# §4904, relating to unsworn falsification



# to authorities, which include fine and imprisonment Check the following,

if applicable: 

# 0

I certify the information required
in Section 

# B-1, General Properties was supplied 

# to the Department for the year __ and has not changed. Form Submitted:



# 0 Form 26R 

# 0 Other (specify) Date Submitted: 

# O

I certify the information required
in Section 

# B-2, Chemical Analysis was supplied to the Department for the year __ and has not changed. Form Submitted:



# 0 Form26R 

# 0 Other (specify) Date Submitted: 

# 0

I certify the information required in Section 

# B-3, Process Description and Schematic, was **su~plied** 

# to the Department for the year __ and has not changed. Form Submitted:



# 0 Form 26R 

# 0 Other (specify) Date Submitted:

Title 

# Senior Water Resources Coordinator Date 

# 2-28-11 

# - 3-

# FORM26RATTACHMENT Chief Oil 

# & Gas LLC- Somerset Co. Preparation date: 2-28-11 

# Section
C (a-d): Processing or Disposal Facilities -Additional a. Permit Number: PA0101508 b. Facility: Pennsylvania Brine 5148 

# us 322 Franklin,

P A 16323 County: Venango c. Facility Contact: John Snedden Title: Operations Coordinator Phone: 814-437-3593 d. Volume previous year:

0 a. Permit Number: PA0095273 b. Facility: Pennsylvania Brine Bells Mills Rd Josephine, PA 15750 County: Indiana c. Facility Contact: Becky Snyder Title: Operations Coordinator Phone: 724-248-1000 d. Volume previous year:

0 a. Permit Number: PA0091472 b. Facility: Tunnelton Liquids 671 Hogue 

# Dr Saltsburg,

P A 15681 County: Indiana c. Facility Contact: Bruce Bufalini Title:
Plant Manager\ Phone: 724-459-6138 d. Volume previous year:

0 a. Permit Number: SWIW#34 b. Facility: Stallion

- Groselle Well SR 88 N. of Adams Rd Garrettsville, OH County: Portage c. Facility Contact: Mark Wimsatt Title: Operations Manager Phone: 330-868-2083 d. Volume previous year:

0 a. Permit Number: SWIW#11 b. Facility: David R. Hill!Devco Unit #1 221 1/2 S 6th St Byesville, OH 43723 County: Guernsey c. Facility Contact: David R. Hill Title: President Phone: 740-685-5168 d. Volume previous year:

0

## FORM26RATTACHMENT

-FB Chief Oil & Gas LLC Preparation date: 2-28-11 

## Section
B (2) (d): Chemical Analysis Attachments- Hazardous Waste Determination As per 40 CFR 262.11 and incorporated

as per 25 Pa. Code 262a.11, this waste has undergone

a hazardous waste determination. This waste is NOT


### a hazardous waste, as per 40 CFR 261.4(b )( 5). 

## Section
B (3) a: Process Description

& 

## Schematic Attachments- Description of Generating Process This waste is generated from the process of hydrofracturing, whereby hydraulic pressure
is applied to a reservoir formation
to create fractures through which ga5 may move to the wellbore, in the course of Marcellus Shale gas well development. Once used, the water returns to the surface through the wellbore. 

## Section
B (3) b: Process Description

& 

## Schematic Attachments -Schematic of Process Frac

## TankMixing 

# \ Fracing fluids are

Frac

## TankStorage mixed in frac tank:



# r water plus small



# 1 water returns post-hydrofracturing amounts of additives, examples ofwhich are provided
at www.chiefog.com/fracturing fluids.html hydro:fracturing processANAI.Jn'ICAI. I..ABORA7tJRV ••• IIICSS, INC. **......,.~coilell.com** ....... MI:Nfliftlfl **-~~** 2:1-!/IIIS IU PIIOIIJ Certificate
of Analysis Ms. Margeret Farrell Chief Oil and Gas LLC 6051 Wallace Road Ext. Suite 210 Wexford, PA 15090 November 26, 2010 Dear Ms. Farrell, Enclosed are the analytical results for samples received by the laboratory on Tuesday, November 02, 2010 ALSI Is a National Environmental Laboratory Accreditation Program (NELAP} accredited laboratory and as such, certifies that all applicable test results meet the requirements

of NELAP. If you have any questions regarding this certificate of analysis, please contact Shannon Butler (Project Coordinator}
or Anna G Milliken (Laboratory Manager}
at (717} 944-5541. Please visit us at www.anaJyticallab.com

for a listing of ALSI's NELAP accreditations and Scope of Work, as well as other links to Water Quality documentation
on the internet. This laboratory report may not be reproduced, except
in full, without the written approval of ALSI. NOTE: ALSI has changed the report generation tool and while we have tried to retain the existing format, you will notice some changes

in the laboratory report. Please feel free to contact ALSI in case you have any questions. Analytical Laboratory Services, Inc. CC: Mr. Matt Kapral This page Is included as part of the Analytical Report and must be retained as a permanent record thereof. ReportiD:9873685 **a___/,2~** Anna G Milliken Laboratory Manager
Page
1 of20ANIII.Jri'ICAI.I.1181J.U.71JRV•••JIICIIS,INC......,IU:a'fllllf8liP.ll22-2115N.lP.IIOIIJSAMPLESUMMARYWorkorder:9873685FORM26RFLOWBACKDiscardDate:12110/20109873685001BowersWest1-HFlowBackWater11/1/1010:0511/2/1009:10RobertMcNairWorkorderComments:Notes-SamplescollectedbyALSIpersonnelaredonesoinwiththeproceduressetforthintheALSIFieldSamplingPlan(20-FieldServicesSamplingPlan).-AllWasteWateranalysescomplywithmethodologyrequirementsof40CFRPart136.-AllDrinkingWateranalysescomplywithmethodologyrequirementsof40CFRPart141.-Unlessotherwisenoted,all·quantitativeresultsforsoilsarereportedonadryweightbasis.-TheChainofCustodydocumentisincludedaspartofthisreport.StandardAcronyms/FlagsJ,BIndicatesanestimatedvaluebetweentheMethodDetectionLimit(MDL)andthePracticalQuantitationLimit(PQL)fortheanalyteUIndicatesthattheanalyte·wasNotDetected(NO)NMDLPQLRDLNDCntrRegLmtLCSMSMSDDUP%RecRPDIndicatespresumptiveevidenceofthepresenceofacompoundMethodDetectionLimitPracticalQuantitatlonLimitReportingDetectionLimitNotDetected-indicatesthattheanalytewasNotDetectedattheRDLAnalysiswasperformedusingthiscontainerRegulatoryLimitLaboratoryControlSampleMatrixSpikeMatrixSpikeDuplicateSampleDuplicatePercentRecoveryRelativePercentDifferenceReportiD:9873685Page2of20ANAI.vriCAJ. I.ASIIIUIY'tll!lV ••• llltiSS, INC. **----~.,.,.com** ....., lfl:f:rflfllffH I'A :lfi-21J!i IU 1'.11111111 Worl<order: 9873685 FORM 26R FLOW BACK Lab ID
: 9873685001 Sample 10
: Bowers West 1-H Flow Back VOLATILE ORGANICS Benzene

NO Toluene

NO Surrogate Recoveries Results Flag 1 ,2 - Dichloroethane-d4

(S) 95 4-Bromofluorobenzene

(S) 83

. 4 Dibrornofluoromethane

(S)
81

. 8 Toluene-d8 (S)

94 GLYCOLS Ethylene Glycol

NO Surrogate ReCQveries Results Flag 2-Butanone (S)

141 WET CHEMISTRY Acidity, Total

143 Alkalinity, Total

190 Ammon ia-N
71.1 Biochemical Oxygen 69.8 Demand Bromide

415 Chemical Oxygen Demand 566 (COD) Chloride
58100 Hardness
15600 NitrateiNitrite-N

NO biVGrease Hexane

NO Extractable pH

6
. 84 Phenolics

NO Specific Conductance 95400 Sulfate

NO Surta

. ctants (MBAS)
NO Total Dissolved Solids 81200 Total Kjeldahl Nitrogen 72.6 Total Suspended Solids 385 METALS Aluminum

, Total

NO Arsenic

, Total

NO Barium

, Total 2400 Beryllium, Total

NO Boron, Total

13

. 2 Cadmium, Total

NO Calcium

, Total 4290 Report 10
: 9873685 ANALYTICAL RESULTS ug/L ug/L Units o/o o/o o/o o/o mg/L Units % mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L pH_Units mg/L umhos/cm mg/L mg/L mg/L mg/L mg/L mgll mgll mg/L mg/L mg/L mg/L mg/L Date Collected: 111112010 10:05 Date Received

: 11/2/2010 09:10 1.0 SW846 8260B 1.0 SW846 8260B Umits Method Prepared 62-133 SW846 8260B 79-114 SW846 8260B 78-116 SW846 8260B 76-127 SW846 82608 10

. 0 SW846 80150 Umits. Method Prepared 53-147 SW846 80150 5 SM20-2310B 5 SM20-2320

B 0.500

0

. 6919-03 2
. 0 SM20-5210

B 150 EPA300 300 EPA410.4 1000 EPA300 125 SM20-2340C 50.0 EPA300 1.9

. EPA 1664A SM20-4500-H

B O.Q1 EPA420

. 4 11/9110 SM20-2510

B 25

. 0 EPA300 0.025 SM20-5540

C 5 SM20-2540C

By By KRK 2.0 SM20-4500-N

C 11/18110 NON 5 SM20-2540

D 5
. 5 SW846 6010C 1113110 KMK 0

. 45 SW846 6010C 1113110 KMK 0

. 55 SW846 6010C 1113110 KMK 0

. 22 SW8466010C 1113110 KMK 5
. 5 SW846 6010C 1113110 KMK 0.11 SW846 6010C 1113/10 KMK 5.5 SW846 6010C 1113110 KMK Matrix

: Water 1119110 23:33 DJB
0 ' 111911
0 23:33 DJB
0 Analyzed
By Cntr 1119110 23

: 33 DJB
D 1119110 23

: 33 OJB
0 1119110 23

: 33 DJB
0 11/9110 23

: 33 OJB
0 11115110 23:31 JJH Analyzed
By Cntr 11/15110 23:31 JJH 11/9110 12

: 00 NJA
B 11/3110 14

: 02 SAO
B 1118110 13:44 LMM
A 1113110 02:54 JEP
B 1113110 08:01 J1H
B 11/10110 08:53 LMM
A 1114/10 14:38 J1H
B 1119/10 08:46 LMM

E 11/3/10 08:01 J1H
B 11/15110 04

: 00 JJS G 11/2/10 09:32 NJA
B 11110110 13

: 11 TMG
H 11/3/10 14

: 02 SAO
B 1113/10 07

: 48 J1H
B 11/2/10 21:30 SAD

F 11/3110 15:55 KAK
B 11118110 10:30 ARK A4 11/3110 03:25 LJF
B 11111110 15

: 33 JWK E1 11111110 15

: 33 JWK E1 11111110 15

: 33 JWK E1 11111110 15

: 33 JWK E1 11111110 15

: 33 JWK E1 11/11110 15:33 JWK E1 11/11110 15

: 33 JWK E1 Page 3of20ANAI..,.,ICIU. I.AIIDRA'riiii'V lllsRIIItss, INc. **....,.~.com** ,.., JIIZI8flltllfi Workorder

: 9873685 FORM 26R FLOW BACK Lab ID
: 9873685001 Sample 10
: Bowers West 1·H Flow Back NO 44.6 Iron, Dissolved
44.0 Lead, Total

NO Lithium, Total

61

. 2 Magnesium, Total
463 Manganese, Total

1.7 Mercury, Total

NO Molybdenum, Total

NO Nickel, Total

NO Selenium, Total

NO Silver, Total

NO Sodi

. um, To

. tal 20400 Strontium, Total

951 Thorium, Total

NO Uranium, Total

NO Zinc, Total

NO FIELD

. PARAMETERS pH, Field (EPA 150.1) 6.83 Specific Conductance, Field 89500 Sub'd-GEL Labs NELAP CERTIFIED Gross Alpha

See Attached Gross Beta

See Attached Radium 226
See Atb:lched Radium228

See Attached Sample Comments:

PA :12-21JS IU P.IIOIII ANALYTICAL RESULTS mg/L mg/L mg/L mg/L mg/L mgll mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L pH_Units umhos/cm Date Collected

: 11/1/2010 10:05 Date Received

: 11/2/2010 09:10 SW846 6010C 0.55 SW846 6010C 3.4 SW846 6010C 6.0 SW8466010C 0.34 SW8466010C 5
. 5 SW8466010C 5.5 SW8466010C 0

. 30 SW846 6010C 0.00050 SW8467470A 1.1 SW8466010C 1.1 SW8466010C 1.1 SW846 6010C 0.22 SW846 6010C 28.0 SW8466010C 0.30 SW8466010C 5.5 SW8466010C 11.0 SW846 6010C 1.1 SW846 6010C SM4500B SM20-2510

B Subcontract Subcontract Subcontract Subcontract
KMK KMK KMK JWK KMK 11/3/10 KMK 11/3/10 KMK 11/3/10 KMK 11/5/10 MNP 11/3/10 KMK 11/3/10 KMK H/3/10 KMK 11/3/10 KMK 11/3/10 KMK 11/3/10 KMK 11/3/10 KMK 11/3/10 KMK 11/3/10 KMK MBAS calculated as LAS molecular weight 342 g/mol.

Matrix

: Water JWK JWK 11/11/10 15:33 JWK 11/10/10 17:20 JWK 11/11/10 15

: 33 JWK 11/11/10 15

: 33 JWK 11/11/10 15

: 33 JWK 11/11/10 15:33 JWK 11/5110 11:32 MNP 11/11/10 15:33 JWK 11/11/10 15:33 JWK 11/11/10 15:33 JWK 11/11/10 15:33 JWK 11/11/10 15:33 JWK 11/11/10 15:33 JWK 11/11/10 15:33 JWK 11/11/10 15

: 33 JWK 11/11/10 15

: 33 JWK 11/1/10 10:05 JRM 11/1/10 10:05 JRM 11/20/10 20:21 CLT 11/20/10 20:21 CLt 11/23/10 13

: 40 CLT 11/17/10 14:46 CLT Due to the strontium content, this sample required

a 11100 dilution for the 6010C dissolved iron analysis. The detection limit was raised accordingly. 11/11/10 JWK Due to the barium and strontium content, this sample required

a 1/50 dHution for the 6010C total metals analysis

. The detection limits were raised accordingly. 11/12/10 JWK See attached subcontracted result from GEL Laboratories, LLC for Gross Alpha, Gross Beta, Radium 226, and Radium 228 results

. SRB 11/26/10

. Reportl0

: 9873685

E1 E1 E1 J1 E1 E1 E1 E1 E2 E1 E1 E1 E1 E1 E1 E1 E1 E1 K K L L N M Page4of20AINAI.Jri'ICAI.f.IUIIIRAFIJR'V....,lkaWIIttHIN.l,.IHJI(JANALYTICALRESULTSWorkorder:9873685FORM26RFLOWBACKLabID:9873685001SampleID:BowersWest1-HFlowBackReportID:9873685DateCollected:11/1/201010:05DateReceived:11/2/201009:10Matrix:Watera_,___;;2J,U__AnnaGMillikenLaboratoryManagerPage5of20ANAI.V'I'ICAI. I..IIBORAFOR'V lllisRIIItss, INc. ........ .,_,.,

• .com IISIJIIIItCCrflflltflfi lilA ::l11-2U N.1 PIIHIIIJ ANALYTICAL RESULTS QUALIFIERS\FLAGS Woi'Xorder

: 9873685 FORM 26R FLOW BACK PARAMETER QUALIFIERS\FLAGS (1) Due to sample matrix interferences, this analyte was analyzed
at a dilution and the detection levels adjusted accordingly. Report 10: 9873685

Page 6 of 20Report1D

: 9873685 ANAI.VFICAI. I.ASIIIUJ'rtJIIr ••• ,,c ••. INC. **www.~flll.com** IIBJIIIII«<fHHIt88l lilA 22-:tiiS N.llfiAIIIO

Page 7 of20IINAI.WICAI.I.ASOfllj7'0R'VINC.ReportiD:9873685www•...,.,aCIIIII.,..comPA:Bl-:llls1UPAOIIJPage8of20

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# lll3/40l0 ReportiD:9873685

Page 10of20IINAI.V"''ICAI. I.ASIIIIArtiRV s •• .,,e.s, INc. (€1 #Ill laboratories
LLC IVIVW •• **,~callllb.com** ....., **~llltllli** PA 211-2115 IU **PA~Jft:l** a memb8f ofThe GEL Group•Nc

PO Bolc'J0712 Charleston, SC 29417 2040 SaloaQII Ro<ad Ch3rlesiM. SC 29407 P&t3.558.8t71 F84:U&G

. l1'* November 24, 2010 M$. Susan B&cr **Anal~** LabofatO.f)' $(:rvicea **~4 Posw~**  Ltme Middl!%1wn, **~nia** 1'7037 Re: M1dd1ciown Nonl)J;P 'Reporting Work **Order** U62tl0 **ne.M~.B~:** OEL **~** LLC (Ql!L) **ap~iafe~** dio oppoi:t\U1jty
l() provide- the 1Cnclo$ed analytical resutts tor 1be sample(s) we- rcQCiveil on **N~r** Q4, 2010. **Thi~** ori8fnat data n:part has been pref*ed and reviewed
in aocordaoce wijh **GEL·~** &lilndard optratinf proc:cOurC$

. Our polley is to provide high quality, penOJqtliud analylical services l() enabre you to ll!C:CI your analytical needs on time evetY time. We lnllll that you will flad **~e.tylhms**
In order and lO }'0!11 s&lis!aCtion..
If you bave any quostioM, plleue do **n~t ltcsi~**  to calf me

. at (843) **5~171,** ext. 4300. **Si~)l.** Cli41nt **s.rv~ T~**  Project Managet Page
1 otlO prOblem solved Report 10: 9873685

-.get.com Page 11 of20ReportiD:9873685 

## ANAI.,.,ICAI. 

# I.ABORA71JR'V

**....,.,.~collflb.com** IIAJUI 

### JtcatiHIIUJII 

# •••.,•css,

l•c. /IIIII 

### :l:l-:lfis lU 1/11110111 

### GEL LABORATORIES LLC 204() Savage Road Chaltestan SC :29407

- (843) ®8.-a171

- www.gel.com 

### Certificate
of Analysis Report for ALSVOOJ Analytical Laboratory Semces,Inc(STND) Client SOO: 266280 GEL Work 

### Order: 266280 The QaaUft•n
fD tiiJs report are defined ils tonows: • A quality connot analyte **t"eCOv~**

Is outsi4C ofllpedfied **ac:cep~am:~ critcria**  •• **~.isasurroaate ~** 

· U 

## AaetYto was **anal~** for, bul not delec:ted above the MDL, MI)A, or

· LOl). Where 1he analytical metbocl bll$ been perf'onncd 1111dcr **~AP ~tiOn,**  **lb~** analysis has met allot die requltemltllfs
of die NELAC sllindard ainle!is qWI.Iifled on the O:mficate of Analysis. Th11 dcsi&DaJion NJ), **if~** a.ppcars .in lhe cesutt col

. umn «Jien tfl:c analyte <:oncencradon

is not **dee~** above l!)e detection Urllit. This datlt repol;t has becn.prepaml and ""iowetl in **ac:cordanc~:** With GBL Labomtories Lt.C standaid opCI'atir,a procediJI'e$, Please direct any questions
10 your ,PrOject **Man~gcf'.** CJient Services Team. Rcvicwedby

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