VI J

NBS SPECIAL PUBLICATION 392

U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards

National Bureau of Standards

Library, _ E-01 Admin. Bldg.

OCT 1 1981

191023

/ oO

QC

100

• 1X57

no. 2te

l c!14

| c '- —

Vibrationally Excited

Hydrogen Halides:

A Bibliography on

Chemical Kinetics of Chemiexcitation

and Energy Transfer Processes

(1958 through 1973)
NATIONAL BUREAU OF STANDARDS

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Vibrational^ Excited Hydrogen Halides:

A Bibliography on Chemical Kinetics of Chemiexcitation

and Energy Transfer Processes (1958 through 1973)

Francis Westley

Chemical Kinetics Information Center

Institute for Materials Research

National Bureau of Standards

Washington, D.C. 20234

This work was supported by the NBS Office of Standard Reference Data and

the Air Force Office of Scientific Research

1400 Wilson Blvd., Arlington, Va. 22209

U.S. DEPARTMENT OF COMMERCE, Frederick B. Dent, Secretary

NATIONAL BUREAU OF STANDARDS, Richard W. Roberts, Director

Issued April 1974

Natlprial Bureau of Standards MAY 6 1974
Supt. of Docs. No. C13.10:392

1. Chemical reaction, Kate of—Bibliography. 2. Hydrogen

halides—Bibliography. 3. Energy transfer—Bibliography.

I. United States. National Bureau of Standards. Institute for Materials Research. Chemical Kinetics Information Center.

II. Title. III. Series: United States. National Bureau of Standards. Special Publication 392. QC100.U57 No. 392 [Z5524.R5] 389\08s 74-5358 [016.54U39]

National Bureau of Standards Special Publication 392

Nat. Bur. Stand. (U.S.), Spec. Publ. 392, 81 pages (Apr. 1974) CODEN: XNBSAV

U.S. GOVERNMENT PRINTING OFFICE

WASHINGTON: 1974

For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 (Order by SD Catalog No. C13.10:392). Price $1.30
Foreword

The National Standard Reference Data System was established in 1963 for the purpose of pro- moting the critical evaluation and dissemination of numerical data of the physical sciences. The pro- gram is coordinated by the Office of Standard Reference Data of the National Bureau of Standards

but involves the efforts of many groups in universities, government laboratories, and private industry. The primary aim of the program is to provide compilations of critically evaluated physical and

chemical property data. These tables are published in the Journal of Physical and Chemical Ref- erence Data, in the NSRDS-NBS series of the National Bureau of Standards, and through other appropriate channels.

The task of critical evaluation is carried out in various data centers, each with a well-defined

technical scope. A necessary preliminary step to the critical evaluation process is the retrieval from

the world scientific literature of all papers falling within the scope of the center. Each center, therefore, builds up a comprehensive well-indexed bibliographical file which forms the base for the evaluation

task. Bibliographies derived from these files are published when they appear to be of value to research

workers and others interested in the particular technical area.

Further information on NSRDS and the publications which form the primary output of the program may be obtained by writing to the Office of Standard Reference Data, National Bureau of Standards, Washington, DC 20234.

David R. Lide, Jr., Chief

Office of Standard Reference Data

TABLE OP CONTENTS

Introduction 1 Guidelines for the user 7 Journal and report codes 11

Part I. Hydrogen fluoride (HP, DF ) 15

A. Formation of HF* (DF*) 15

1. Bimolecular reactions (Abstraction lasers) 15 a. Abstraction of H (D) atom by F atom 15

i. F + H

2

+ HF + H 15

ii. F + HX > HF* + X . 16

iii. F + RH * HF* + R . . 17

b. Abstraction of F atom by H (D) atom 17

i. H + Fp HF* + F 17

ii. H + FX > HF* + X . . . 18

iii. H + RF -> HF* + R 18

2. Unimolecular reactions (Elimination lasers) 18 a. R- + R

2 * Cri

R

2

] ^ HF + M (Chemical activation ) .18

b. M., + hv -» HF + M9 (Photochemical elimination) . .19

B. HF (DF ) Energy transfer and quenching 19

1. HF (DF ) Energy transfer 19 a. HF(v. = 0) + M* -* HF*(v. > 0) + M (M ^ HF)

(Energy transferred to HF from M ) 19

b. HF*(v. = m) + M -» HF^(v. < m) + M* (v > 0) 1 J J. J (Energy transferred from HF to M) 19

c . HF(v. ) + HF(v . ) -* HF(v, ) + HF(v. ) (i + j = k + I ) (HF - HF Energy transfer) ... ^0

2. HF* (DF*) Quenching .21 + r ±\

a. HF (v. = m ) + M -> HF ( v . < m ) + M (v. > 0)

(Collisional quenching) .21 b. HF*(v. = m) + HF -> HF^^v. < m) + HF (v. & 0)

(HF - HF self-quenching) .22 £

c. HF (v

1 = m) + M -> prod. (Dissociative quenching ) .22 i. HF*(v

1 = m) + M

2 HF(v^ = 0) + M + M. . . . 22

ii. HF*(v

1

= m) + M > H + F + M 23

C. HF* (DF*) Theoretical papers 23

v
Part II. Hydrogen chloride (HC1, DC1) 24

A. Formation of hCl* (DCl*) 24

1. Bimolecular reactions (Abstraction lasers) 24 a. Abstraction of H (D) atom by CI atom 24

i. CI + H

2 * HC1* + H . 24

ii. CI +• HX -> HC1* + X . . . . 24

iii. CI + RH -> FC1* + R 25

b. Abstraction of CI atom by H (D) atom 25

i. H + Cl

2

-> HCl* + CI 25

ii. H + C1X * HCl* + X 26

iii. H + RC1 HCl* + R 26

iv. H + HC1 -> HCl* + H 27

2. Unimolecular reactions (Elimination lasers) 27 a. R

1 + R2

-* [R^Rp] * HC1* + M(Chemical activation) . 27

b. + hv -* HC1 + (Photochemical elimination). .27

± i

B. HC1 (DC1 ) Energy transfer and quenching 27

1. HCl* (DCl*) Energy transfer 27 a. HC1 (v. = 0) + M* -> HCl^v. > 0) + M (M ? HC1)

(Energy transferred to HC1 from M ) 27

b. HCl*(v. = m) + M -> HCl^(v. < m) + M* (v. > 0)

(Energy transferred from HC1 to M) 27 c. HCl(v.) + hCl(v.) > HCl(v, ) + HCl(v ) 1 J K I (i + j = k + i ) (HC1 - HC1 Energy transfer) . . . 28

2. HCl* (DC1 +

) Quenching 28 a. HCl*(v. = m) + M -> HC1- (v. <m)+M (v. > 0) i J J (Collisional quenching) 28

b. HCl^Cv. = m) + HC1 + HCl (4:) (v. < m) + HC1

i i (v. a 0) (HC1 - HC1 self-quenching) 29 c. HCl*(v. = m) + M 0

-> HCl(v. = 0) + M + M

i 2 J (Dissociative quenching) 29

C. HCl* (DCl*) Theoretical papers 30

vi
Part III. Hydrogen bromide (HBr , DBr) 31

A. Formation of HBr* (DBr*) . 31

i. Bimolecular reactions (Abstraction lasers) ...... 31

a. Abstraction of H (D) atom by Br atom 31

i. Br + H

2

HBr* + H 31

ii. Br + HX -> HBr* + X 31

iii. Br + RH -> HBr* + R . . „ 31

b. Abstraction of Br atom by H (D) atom 31

i. H + Br

2

-> HBr* + Br 31

ii. H + BrX -* HBr* + X 32

B. HBr (DBr ) Energy transfer and quenching 32

1. HBr (DBr ) Energy transfer. . . . c 32 a. HBr (v. = 0) + M* -> HBr*(v, > 0) + M (M r HBr)

(Energy transferred to HBr from M ) 32

b. HBr* (v. = m) + M > HBr^(v. < m) + M* (v. > 0)

(Energy transferred from HBr to M) 32 c. HBr (v.) + HBr (v.) -> HBr ( v, ) + HBr (v.)

(i + j = k + z ) (HBr - HBr Energy transfer) ... 32

2. HBr (DBr ) Quenching 32 a. HBr* (v. = m) + M -> HBr^(v. < m) + M (v. > 0)

i J J (Collisional quenching) 32

b. HBr*(v. = m) + HBr * HBr^^v. < m) + HBr

i J (v.> 0) (HBr - HBr self-quenching) 33

J C. HBr* (DBr*) Theoretical papers 33

vii
i. I + H

2

-» HI* + H 34

ii. I + HX + HI* + X 34

Part IV. Hydrogen iodide (HI, DI) 34

A. Formation of HI* (DI*) . . . 34

I. Bimolecular reactions (Abstraction lasers ) 34

a. Abstraction of H (D) atom by I atom 34

2

-+ h

iii. I + RH + HI* + R ....... . 34

b. Abstraction of I atom by H (D) atom 34

i. H + I„ -* HI* + 1 34

ii. H + IX -> HI* + X ............... 34

4= £ -xi B. HI (Dl ) Energy transfer and quenching J4

1. HI (DI ) Energy transfer 34 a. HI (v. = 0) + M* -+ HI* (v. > 0) + M (M t HI)

(Energy transferred to HI from M ) 34

b. HI* (v. = m) + M > HI^*\'v. <m) + M* (v. a= 0)

1 J ^ J (Energy transferred from HI Lo M) 35

c HI(v

1

) + HI (v.) HI(v

k

) + HI(v

x

) (i + j = k + j> ) (HI - HI Energy transfer) .... 35

2. HI* (DI*) Quenching 35

i c i ') a. HI (v. = m) + M -> HI ( v . < m) + M (v.> 0) i J J (Collisional quenching) 35

b. HI* (v. = m) + HI -» HI (v. < m) + HI (v.'fe 0) i J J (HI - HI self-quenching). 35

4= 4= C. HI (DI ) Theoretical papers 35

Part V. Reviews and Bibliographies . 36

Part VI. References 37

viii
VIBRATIONALLY EXCITED HYDROGEN HALIDES:

A Bibliography on Chemical Kinetics of Ohemi-xcitaticn

and Energy Transfer Processes*

Francis Westley

A bibliography, a reaction oriented list of

references, is provided for published papers and

reports containing rate data for reactions of

halogen atoms with hydrogen-containing compounds,

or of H (D, or T) atoms with halogen-containing

compounds to form vibrat ionally chemiexcited

hydrogen halides. The reactions for vibroexcitat ion

of hydrogen halides through unimolecular or

photochemical elimination, as well as the processes

for vibrational energy transfer between hydrogen

halides and various second bodies are also

included. In addition, four lists of theoretical

papers and a list of critical reviews and

bibliographies are provided. Over 300 papers

covering 50 types of reactions are listed. The

period covered extends from 1958 through 1973.

Key words: Bibliography; chemical kinetics;

chemiexcitat ion; gas phase; halogens; hydrogen;

hydrogen halides; laser; quenching; vibrational

energy transfer.

Introduc t ion

The bibliography lists papers and reports on the gas

phase reaction kinetics of two types of chemical processes:

a) formation of vibrationally excited hydrogen halides

through abstraction or elimination and b) vibrational energy

transfer - including quenching - between hydrogen halides and

various second bodies.

This publication is an activity of the Chemical Kinetics

Information Center, National Bureau of Standards. The work

was supported by the Office of Standard Reference Data, National

Bureau of Standards and the Air Force Office of Scientific

Research as part of a program to provide information and datci

on rates of chemical reactions.

1
The articles have been selected from the files of the

Chemical Kinetics Information Center. The criterion for

inclusion of an article is that it must contain some new

information on the reaction. That is, simple quotations of

the results of others and ad hoc guesses have been excluded.

There are gray areas, such as the statement of a rate

calculated from that of the reverse reaction and the

equilibrium constant, or information such as: suggestion

of a new mechanism, or a theoretical calculation, or a new theoretical approach derived from kinetic experiments.

If the information seemed to be important the reference

was included.

The two above mentioned types of reactions (formation

of vibrationally excited hydrogen halides and transfer of

vibrational energy between hydrogen halides and other bodies)

are essential in a fairly new branch of quantum electronics:

the chemical laser . Light amplification by stimulated

emission of radiation (in short: laser ) is a fairly recent

development In science dealing with the generation of coherent

radiation in the infrared and visible regions of the spectrum.

The chemical lasers are based on the new principle of

obtaining energy - in the form of coherent radiation - from

chemical reactions: the principle of "chemical pumping".

In other words, chemical interaction between two gaseous

molecules results in the pumping of electronic, vibrational,

or rotational energy into the newly formed bond of one to the

reaction products. The new bond "stores" for a short time

an amount of energy available for other uses. Such a reaction, which is only the first elementary step in the

more complex lasing process, is called in short

"chemiexc itation" , The first observation of an infrared

emission from the reaction of atomic hydrogen with molecular

1 2 chlorine, was reported in 1958 by Cashion and Folanyi -

' . They attributed this emission to the vibrationally excited

hydrogen chloride, which was one of the products of the reaction:

H + Clp -> HClt( v ^ 6) + CI (1)

In 19^1, Polanyi suggested the construction of a HC1

laser, dependent on vibrational excitation, which would

g operate in the Infrared region . Polanyi and coworkers have

continued their pioneering work in the field of chemical

lasers, by following a double path: experimental [Infrared

3 4 5) spectroscopy '

9 - , energy distribution among reaction

products 6,

3 J 14,17,18,29,21,22,23)] and theoretlcal [energy

T Q 10 12 1 Q ^

^

") distribution 3 3 3 ' , potential energy

surface 11 > 12 > 2 3)

) trajectories 12 » 1 5 9 23)^ chemical kinetics l6) ^

2
However, the first description of an operational HC1

pulsed chemical laser was published in I965 by Kasper and

2k

)

Fimentel . In the following years the research on

chemical lasers has been continually expanding. A list of

the universities and industrial research laboratories, as

well as of their scientists carrying out research in chemical

lasers can be found in the introduction of a bibliography

published in 1972 by the U.S. Atomic Energy Commission

[Chemical Lasers: An Overview of the Literature, (i960 - 197D 25) ].

Since 1965* many chemiexcited molecules have been

found suitable in the operation of chemical lasers. However,

the hydrogen halides are the most used molecules for that

purpose. To date, the highest energy level of a chemiexcited

hydrogen balide molecule Is vibrational. The search of the

literature failed to show the existence of a laser based on

an electronically excited hydrogen halide molecule. For these

reasons, this bibliography Is confined only to two types of

reactions involving hydrogen halides: a) vibrational

chemiexc ita tion and b) vibrational energy transfer. No

attempt was made to cover the literature dealing with the

operation of hydrogen halide lasers. The reader interested

in operation of chemical lasers ..hould consult the

"Comprehensive Literature Survey of Chemical Lasers" by

Arnold and Rojeska or the above mentioned bibliography

2^) of Dobratz , as well as other reviews and bibliographies

listed in part V of this work.

This bibliography is not the result of the effort of a single person, but of the whole staff of Chemical Kinetics

Information Center. My thanks to all of them.

In particular, I wish to thank Dr. David Garvin, Director

of the Center, and Dr. Robert Hampson for their more than

helpful suggestions and constant guidance; Mr. James G. Koch,

Supervisor, for tracking down and obtaining papers and reports,

otherwise very difficult to obtain; Mrs. Ann C. Robertson,

Mrs. Geraldine Zumwalt and Miss Darlene Connelly, for typing

a difficult manuscript with particular care.

3
REFERENCES CITED IN THE INTRODUCTORY MATERIAL

1. Cashion, J. K., and Polanyi, J. C, "Infrared

Chemiluminiscence from the Gaseous Reaction H« + Cl„,"

J. Chem. Phys. 2£, 455 (1958)

2. Cashion, J. K., and Polanyi, J. C., "Resolved Infrared

Emission Spectrum of the Reaction Atomic H» + Cl

?

,"

J. Chem. Phys. 30.> 10 97 (1959)

3. Cashion, J. K., and Polanyi, J. C., "Infra-red

Chemiluminescence I. Infra-red Emission from Hydrogen

Chloride formed in the Systems Atomic Hydrogen plus

Chlorine, Atomic Hydrogen plus Deuterium Chloride,

and Atomic Deuterium plus Hydrogen Chloride," Proc.

Roy. Soc. (London), A 2 58 , 529 (I960).

4. Cashion, J. K., and Polanyi, J. C . , " Infra-red ;: Chemiluminescence II. Spectrosopic Data," Proc. Roy.

Soc. (London), Series A 258 , 564 (i960)

5. Cashion, J. K., and Polanyi, J. C., "Infra-red

Chemiluminiscence III. Infra-red Emission from

Hydrogen Bromide formed in the Systems Atomic Hydrogen

plus Bromine, and Atomic Hydrogen plus Hydrogen

Bromide," Proc. Roy. Soc. (London), Series A 258 , 570 (I960)

6. Charters, P. E., and Polanyi, J. C., "Energy

Distribution among Reaction Products. Part 1. The

Reaction Atomic Hydrogen plus Molecular Chlorine,"

Discussions Faraday Soc. _33 9 107 (1962)

7. Polanyi, J. C., "Energy Distribution Among Reagents

and Products of Atomic Reactions," J. Chem. Phys.

31, 1338 (1959)

8. Polanyi, J. C,, "Proposal for an Infrared Maser

Dependent on Vibrational Excitation," J. Chem. Phys.

34, 347 (1961)

9. Polanyi, J. C., "Infrared Chemiluminescence," J. Quant.

Spectr. Radiat. Trans. 3, 471 (1963)

4
10. Polanyi, J. C., and Rosner, S. D., "Energy Distribution

Among Products of Exothermic Reaction," J. Chem.

Phys. 38, 1028 (1963)

11. Polanyi, J. C., "Vibrat ional-Rotational Population

Inversion," Appl. Optics Suppl. 2, 109 (1965)

12. Kuntz, P. J., Nemeth, E. M . , Polanyi, J. C,

Rosner, S. D., and Young, C. E., "Energy Distribution

Among Products of Exothermic Reactions. II.

Repulsive, Mixed, and Attractive Energy Release,"

J. Chem. Phys. 1168 (1966)

13. Airey, J. R., Getty, R. R., Polanyi, J, C., and

Snelling, D. R., "Absolute Efficiency of Conversion

of Heat of the Reaction H + Cl^ into Vibration,"

J. Chem. Phys. 4d, 3255 (1964)

14. Anlauf, K. G.-, Kuntz, P. J., Maylotte, D. H.,

Pacey, P. D., and Polanyi, J. C., "Energy Distribution

among Reaction Products. Part 2. H + and

X + HY," Discussions Faraday Soc. _44, 183 (1967)

15. Anlauf, K. G e , Polanyi, J. C., Wong, W. H., and

Woodall, K. B., "Distribution of Reaction Products.

III. CI + HI, CI + DI," J. Chem. Phys. 49, 5189

(1968)

16. Anlauf, K. G., Maylotte, D. H., Polanyi, J. C, and

Bernstein, R. B., "Rates of the Endothermic Reactions

HC1 + X(X=I, CI) as a Function of Reagent Vibration,

Rotation, and Translation," J. Chem. Phys. 5_1, 5716

(1969)

17. Polanyi, J. C., and Tardy, D. C., "Energy Distribution

in the Exothermic Reaction F + H^ and Endothermic

Reaction HF + H," J. Chem. Phys. 51_ s 5717 (1969)

18. Anlauf, K. G . , Charters, P. E., Home, D. S.,

MacDonald, R. G., Maylotte, D. H., Polanyi, J. C,

Skrlac, W. J., Tardy, D. C, and Woodall, K. B.,

"Translational Energy-Distribution in the Products

of Some Exothermic Reactions," J. Chem. Phys. 53 » 4091 (1970)

5
19. Polanyi, J. C, and Woodall, K. B., "Mechanism of

Rotational Relaxation," J. Chem. Phys. 5_6, 1563

(1972)

20. Maylotte, J. C, Polanyi, J. C, and Woodall, K. B.,

"Energy Distribution among Reaction Products. IV.

X + HY (X3C1, Br, Y =Br , I), CI + DI," J. Chem.

Phys. 57., 15^7 (1972)

21. Polanyi, J. C, and Woodall, K. B., "Energy Distribution

among Reaction Products. VI. F + H

p , Dp

," J. Chem.

Phys. 57, 1574 (1972)

22. Polanyi, J. C., and Sloan, J. J., "Energy Distribution

among Reaction Products. VII. H + F 0 ," J. Chem.

Phys. 57, 4988 (1972)

23. Parr, C. A., Polanyi, J. C, and Wong, W. H.,

"Distribution of Reaction Products ' (Theory ) . VIII.

CI + HI, CI + DI," J. Chem. Phys. 58, 5 (1973)

24. Kasper, J. V. V., and Pimentel, G. C, "HC1 Chemical

Laser," Phys. Rev. Letters 14, 352 (1965)

25. Dobratz, B. M., "Chemical Lasers: An Overview of the

Literature, i960 - 1971," U.S. Atomic Energy Commission,

UCRL 51285 (Sept. 1972) (National Techn. Information

Service

)

26. Arnold, S. J., and Rojeska, H., "Chemical Lasers: A

Comprehensive Literature Survey," Appl. Opt. 12 , 169

(1973)

6
Guidelines for the user

Arrangement of the report . This bibliography is in six

parts :

Part I . Hydrogen fluoride (HF^ or DF^)

Hydrogen chloride (HCl^, or DCl^)

Hydrogen bromide (HBr^, or DBr^)

Hydrogen iodide (HI^, or DI^)

Reviews and Bibliographies (Critical reviews, or

surveys and general bibliographies dealing with

the reactions listed in parts I to IV)

The combined bibliography for Parts I to V arranged

alphabetically by authors. The complete reference

citation for each article mentioned is given here.

Occasionally explanatory notes are appended. These

establish the "bibliography chain" for closely

related .papers by the same authors.

, IliV , ( yioeuT ; sjoudu"'

Parts I to IV are arranged in the order of their

importance: Hydrogen fluoride (Part I) is the most

intensively studied chemical laser, while hydrogen iodide

(Part IV) is the least studied.

Part II.

r dx U T-L T_L TJ. Part IV.

Part V.

Part VI.

Ordering of chemical reactions . The purpose of this

work is to provide the chemical kineticist with a useful list

of articles and papers dealing with the vibrationally excited

hydrogen halides. For that reason, the arrangement of the

bibliography is reaction oriented: parts I to IV are each

divided into three large sections:

Section A . Formation of HX^ (X = F, CI, Br, I)

Section B . HX^ Energy Transfer and Quenching

Section C . HX^ Theoretical Papers

The titles of Sections A and B define very broad

categories of reactions. Section C Includes only theoretical

papers, very closely related to the kinetics of vibrationally

excited hydrogen halides. Section A does not include

i formation of HX^ by energy transfer. This type of reaction

may be found in Section B, under l.a. Each of the Sections

A and B is divided Into smaller categories of reactions and

so on, as indicated in the table of contents.

7
Display of Chemical Reactions and Formulae . With the

exception of subgroups A.l. a and A.l.b, all the other

subgroups define a type of chemical reaction. Subgroups

A.l. a and A.l.b are each further divided into three types

of reactions. For instance, in part I (Hydrogen fluoride)

these types are:

A . 1 .

. Abstraction of H atom by F atom .

i. F + H

2

-> HF^ + H (2)

ii. F + KX > HP"

8 + X (3)

iii. F + RH * HF^ + R (4)

A . 1 . b . Abstraction of F atom by Pi atom .

i. H + F

2 ^ HF^ + F (5)

iio H + FX * HF^ + X (6)

iii. H + RF - HF^ + R (7)

Throughout the work these different types of reactions

are displayed according to a scheme trying to emphasize the

direction and nature of the chemical process, rather than

to follow a mere alphabetical order. So, the above listed

reactions (2) to (7) are all written according to the

invariable pattern:

Abstracting + Molecule -> Vibrat ionally + Other

atom excited Products

Product

In reactions (4) and (7) 3 the terms RH and RF denote in

general a hydrogen containing - and, respectively, a halogen

containing - organic molecule. However, in some instances,

a reference listed under the headings A.l. a. iii. or A.lob.iii.

(Reactions (4) and (7))> might deal with a hydrogen - or

halogen - containing inorganic molecule.

The general "third body", whether excited or in ground

state, is always last:

B.l.a. HF(v

±

= 0) + -> HF^v^O) + M ( HF ) (8)

8
In general, the first term at the right side of a reaction indicates a vibra t ionally excited product. The only

exception is the reaction type B.2.c (Dissociative quenching).

B . 2 . c

i. HF^(v.=m) + M + HF ( v . =0 ) + M + M (9)

i 1 d j

B.2.C

ii. HF T (v

1

=m) + M+ H + F + M (10)

Excited states of reactants and products . This

bibliography deals exclusively with vibrat ionally excited

hydrogen halides. The sign used to indicate the vibronic

state of a molecules is the double dagger superscript. If

the double dagger appears inside a bracket, it indicates

that the molecule might be in its ground state (zero

vibrational level):

B.l.b. HFT( v .=m) + M -> HF^(v. < m) + M^Cv, >0) (11)

1 J K

(v. might be 0)

J Only in one instance an asterisk is used to indicate

the formation of an intermediate activated complex, which

subsequently is dissociated into a vibrat ionally excited

hydrogen halide molecule and another product:

A. 2. a. R- + R 9 > [R.Rt* -> HX^ + M (Chemical activation)

1

^ (12)

Reactions of the type B.l.c. are expressed by a generalized chemical equation including all the HX - HX

vibrational energy transfer processes. The multiplicity of

vibrational levels (some authors consider 8 vibrational

levels in the same paper) would have made it very difficult

to arrange this bibliography according to all the possible

HX - HX vibronic interactions. Although, in this type of

process, four different vibronic levels coexist, the double

dagger superscript is entirely omitted and the different

vibronic levels are indicated in a bracket following each

HX molecule. The reason for omitting the dagger symbol is

that onlyJ one of the four vibronic levels (v., v., v, . v„ ) i

5 j9 k

5 I

may be zero, provided that the condition I + j = k + i is

satisfied. (If two, or three of these vibronic levels are

zero, then the process becomes a simple quenching, or

excitation one.). For the case of the HF - HF vibrational

energy transfer, the B.l.c. process is indicated as follows:

HF(v

±

) + HP (v.) -> HF(vk) + HF(v^) (i + j = k + i ) (13)

(only one of four levels v., v., v , v may be zero)

9
Reference Citations.

The references under each reaction list the author (s)

and the sources, in the following form:

Author (s) Source-Year-Volume-Page Number of

Author ( s

)

Airey, J. R.

Airey and Fried

Airey, et al.

IJCKBO-I97O-2-65

CHPLBC-1971-8-23

JCPSA6-1964-41-3255

1

2

3 or more

Variations from this format (which we will call "short

reference") are usually in the direction of more explicit

specification. These variations are never made in the first

two fields, source and year. They are fixed and always

present

The sources are indicated by their ASTM CODEN

* ) abbreviations . A guide to these codes follows. As listed

in this guide, the codes include an additional sixth cipher,

** ) which is a "check character" . A code prefixed with an

asterisk is a code not in the ASTM CODEN set. These are

codes we have assigned for reports from industrial

laboratories, research institutes and universities. When

the CODEN system adopts appropriate codes they will be

replaced. The present, temporary codes usually end with Z or U

^Blumental, J . G., Karaman, M . , Editors, "CODEN FOR PERIODICAL

TITLES" (Including Non-Periodical Titles and Deleted Coden)

,

Vol. I and II, ASTM Data Series DS 2JB, Third Edition, (1970);

Padusis, M., Editor, First Supplement to Third Edition,

DS 23B-S1 (05-023021-42, 1972). (American Society for Testing

and Materials, 1916 Race St., Philadelphia, Pa. 19103)

The final sixth character in the journal code Is a "check

character". This is not shown In the listings in ASTM DS

23B and DS 23B-S1, but the calculation Is explained in the

introductions to them. See also "Subroutine for the Calculation of CODEN Check Characters, D. Garvin, National Bureau of

Standards, Tech. Note 738 (Sept. 1972)

10
JOURNAL AND REPORT CODES

ACHRAY ACCOUNTS OP CHEMICAL RESEARCH (Washington)

ACIEAY ANGEWANDTE CHEMIE (International Edition in English)

ACSRAL AMERICAN CHEMICAL SOCIETY, ABSTRACT OF PAPERS

ADCPAA ADVANCES IN CHEMICAL PHYSICS (New York)

APOPAI APPLIED OPTICS (Washington)

APOSAR APPLIED OPTICS, SUPPLEMENT (Washington)

APPLAB APPLIED PHYSICS LETTERS (New York)

ARPLAP ANNUAL REVIEW OF PHYSICAL CHEMISTRY

*ASTSZU THE AEROSPACE CORPORATION

BBPCAX BERICHTE DER BUNSENGESELLSCHAFT FUER PHYSIKALISCHE

CHEMIE (Germany)

BOOKA7 BOOK

CBFMAO COMBUSTION AND FLAME

CCHKAZ COMPREHENSIVE CHEMICAL KINETICS (Amsterdam)

CHDBAN COMPTES RENDUS HEBDOMADA IRES DES SEANCES DE

L ' ACADEMIE DES SCIENCES, SERIE B. SCIENCES

PHYSIQUES (Paris)

CHMBAY CHEMISTRY IN BRITAIN (London)

CHPLBC CHEMICAL PHYSICS LETTERS (Amsterdam)

CITEAH CHEMIE- INGENIEUR-TECHNIK (Germany)

CJCHAG CANADIAN JOURNAL OF CHEMISTRY

CSSPAD CHEMICAL SOCIETY, SPECIAL PUBLICATION (London)

DABBBA DISSERTATION ABSTRACTS INTERNATIONAL, B.

THE SCIENCES AND ENGINEERING

DABSA9 DISSERTATION ABSTRACTS PART B. SCIENCES AND

ENGINEERING

DAKEAT DANSK KEMI (Copenhagen)

DFSOAW DISCUSSIONS OF FARADAY SOCIETY

DIASA9 DISSERTATION ABSTRACTS

DKPCAG DOKLADY PHYSICAL CHEMISTRY, PROCEEDINGS OF THE

ACADEMY OF SCIENCES OF THE USSR (New York)

HIECAP HIGH ENERGY CHEMISTRY (New York)

IEJQA7 IEEE JOURNAL OF QUANTUM ELECTRONICS (New York)

IJCKBO INTERNATIONAL JOURNAL OF CHEMICAL KINETICS

(New York)

11
JAPIAU JOURNAL OP APPLIED PHYSICS (New York)

JASMAN JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA

J CI TAR J OURJMAL Ox1 CHEMICAL SOC1E1Y, 1ARADAY IRANSAG 1 IONS I

( TiOnd on

J Or TBS J OURIJAL Or CHEMICAL oOClEli, rARAUAY 1RAJMSAC llOJNo 11

( London

)

JCPQAY JOURNAL DE CHIMIE PHYSIQUE

JCPSA6 JOURNAL OF CHEMICAL PHYSICS

JCS0A9 JOURNAL OF THE CHEMICAL SOCIETY (London)

JPCHAX JOURNAL \J \y ul Un XL J 1 OF PHYSICAL CHEMISTRY

JQSRAE JOURNAL OF QUANTITATIVE SPECTROSCOPY AND RADIATIVE

TRANSFER

JTPLA2 JETP LETTERS, SOVIET PHYSICS (New York)

KICAA8 KINETICS AND CATALYSIS

LSRVAN LASER FOCUS

MOPHAM MOLECULAR PHYSICS (London)

NATUAS NATURE (London)

PACHAS PURE AND APPLIED CHEMISTRY (London)

PRKNAZ PROGRESS IN REACTION KINETICS

PRLAAZ PROCEEDINGS OF ROYAL SOCIETY, SERIES A.

MATHEMATICAL AND PHYSICAL SCIENCES (London)

PRLTAO PHYSICAL REVIEW LETTERS (New York)

PYLAAG PHYSICS LETTERS, SECTION A (Amsterdam)

QRCSAL QUARTERLY REVIEW OF THE CHEMICAL SOCIETY (London)

RJPCAR RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY

SCAMAC SCIENTIFIC AMERICAN (New York)

SCIEAS SCIENCE (Washington)

SPHJAR SOVIET PHYSICS JETP (New York)

SPUSBI SOVIET PHYSICS - USPEKHI (New York)

SYMCAQ SYMPOSIUM ON COMBUSTION

TFS0A4 TRANSACTIONS OF THE FARADAY SOCIETY

UCRLAE UNIVERSITY OF CALIFORNIA, LAWRENCE RADIATION

LABORATORY, REPORTS

XADRCH UNITED STATES DEPARTMENT OF COMMERCE, NATIONAL

TECHNICAL INFORMATION SERVICE

XCCIAV UNITED STATES DEPARTMENT OF COMMERCE, CLEARINGHOUSE

FOR SCIENTIFIC AND TECHNICAL INFORMATION

12
XERLAR U.S. ATOMIC ENERGY COMMISSION, UNIVERSITY OP

CALIFORNIA, RADIATION LABORATORY

ZEPCAC ZEITSCHRIFT PUER PHYSIKALISCHE CHEMIE, STOECHIOMETRIE UND VERWANDSCHAFTSLIHRE

ZPCBAL ZEITSCHRIFT FUER PHYSIKALISCHE CHEMIE, ABTEILUNG B:

CHEMIE DER ELEMENTARPROZESSE , AUFBAU DER MATERIE

26BMAD MTP (MEDICAL AND TECHNICAL PUBLISHING COMPANY)

INTERNATIONAL REVIEW OF SCIENCE: PHYSICAL CHEMISTRY,

SERIES ONE 1972-1973

13
Abbreviations

The abbreviations listed below, are used in parts I

through IV of this bibliography 0

(calc.) = (calculation)

(cr. sect.) = (cross section)

(d.r.) = (detailed rates)

(mech.) = (mechanism)

(model.) = (modelling)

(pop. distr.) = (population distribution)

(pot. surf.) = (potential energy surface)

(r.p.) = (related paper)

(rev. ) = (review)

(traj.) = (trajectories)

(trans, prob.) = (transition probability)

They are appended inside brackets at the end of the

short references. In general, a short reference without

appended abbreviations indicates a work including rate

constants while a reference followed by appended abbreviations may or may not include rate constants.

The abbreviation r.p. (related paper) indicates-- a paper

which cannot fit in any of the above listed categories.

For instance, a work dealing with laser operation will be

followed by (r D p.) if it is considered of interesto However,

a number of papers with rate constants are included in the

r.p. category. For instance, under the heading: CI + H~ -> I

1

HC1 1 + H a number of papers giving rate constants for

the overall reaction CI + -> HC1 + H are included. In this

reaction, the product HC1 indicates all molecules of hydrogen

chloride whether in the ground state or in an excited state.

Such a paper is therefore a very closely related paper ,

14
Part I. Hydrogen fluoride (HF, DF)

A. Formation of HF* (DF*)

1. Bimolecular Reactions (Abstraction Lasers)

a

Abstraction of H(D) Atom by F Atom

i. F + W

? -> RF* + H

Airey, J. R.

Anlauf, et al.

Basov, et al.

Beattie, et al.

Ben-Shaul, et al.

Ben-Shaul, et al.

Berry, M. J.

Brokaw, R. S.

Burmasov, et al.

Chang; and Setser

Chester and Hess

Clyne, et al.

Cohen, N.

Cool, et al.

Cool, et al.

Coombe and Pimentel

Coombe and Pimentel

Coombe and Pimentel

Deutsch, T. F.

Deutsch, T. F.

Dodonov, et al.

Dolgov-Savel'ev, et al.

Duewer and Setser

Dol^ov-Savel'ev, et al.

Emanuel, et al.

Fettis and Knox

Green and Lin

Gre^g, et al.

Gross, R. W. F.

Gross, et al.

Gross, et al.

Gross, et al.

Hess, L. D.

Hess, L. D.

Hess, L. D.

Homann, et al.

Jaffe, et al.

Jensen and Rice

Jensen and Rice

Jonathan, et al.

Jonathan, et al.

Kaoralova and Chaikin

Kaoralova, et al.

IJCKBO-1970-2-65

JCPSA6-1970-53-4091 (calc, pop. distr.)

JTPLA2-1969-9-375 (r. p.)

IEJQA7-1973-9-202 (r.p.)

JCPSA6-1972-57-5427 (calc, pop. distr.)

CHPLBC-1972-15-160 (pop. distr.)

ACSRAL-197.^-166-Phys. 98

JPCHAX-1965-69-2808 (r. p.)

JTPLA2-1969-10-28 (r. p.)

JCPSA6-1973-58-2298 (pop. distr.)

IEJQA7-1972-8-1 (rev.)

CJCHAG-1973-51-3596 (r. p.)

XADRCA-1972-AD 763715

APPLAB-1969-1 5-318 (r. p.)

JAPIAU-1970-41-4038

IEJQA7-1973-9-192

JCPSA6-1973-59-251

JCPSA6-1973-59-1535

APPLAB-1967-10-234 (r. p.)

APPLAB-1967-11-18 (r. p.)

DKPC AG-1971-198-440

SPHJAR-1970-31-643

JCPSA6-1973-58-2310 (pop. distr.)

SPHJAR-1972-34-34

XADRCA-1972-AD 746685 (rev.)

PRKNAZ-1964-2-2 (r. p.)

JCPSA6-1971-74-3222 (calc.)

CHPLBC-1971-8-609 (r. p.)

JCPSA6-1969-50-1889 (r. p.)

JCPSA6-1968-48-3821 (r. p.)

JCPSA6-1969-51-1250 (r. p.)

IEJQA7-1970-6-168 (r. p.)

IEJQA7-1973-9-201 (r. p.)

JAP I AU-1 972-43-1 157 (r. p.)

J CP S A6-1971-55-2466

BBPCAX-1970-74-585 (r. p.)

JCPSA6-1973-59-1128 (calc.-.pot. surf.,

traj.)

CHPLBC-1970-7-627 (r. p.)

CHPLBC-1971-8-214 (r. p.)

MOPHAM-1971-20-93

APOPAI-1971-10-182

CBFMA0-1969-13-557 (r. p.)

KICAA8-1970-1 1-669 (r. p.)

15
Kerber, et al.

Kerber and Whittier

Kompa, K. L*

Korapa, K. L.

Kompa, et al.

Kompa, et al.

Kompa and Pimentel

Kompa and Wanner

Kompa, et al.

Krogh and Pimentel

Kwok, et al.

Levine, et al.

Levy and Copeland

Levy and Copeland

Levy and Copeland

Meinzer, R. A.

Mercer and Pritchard

Mirels and Spencer

Pan, et al.

Parker and Pimentel

Pearson, et al.

Persky, A.

Pimentel, G. C.

Pimentel, G. C.

Pimentel, G. C.

Pummer and Kompa

Schafer, et al.

Semenov and Shilov

Soencer, et al.

Soinnler and Kittle

Suchard , S. N.

Suchard, et al.

Suchard, et al.

Suchard, et al.

Vedeneev, et al.

Vedeneev, et al.

Wilkins, R. L.

Wilkins, R. L.

Wilson and Stephenson

Wilson, et al.

ii. F + HX -> FF* + X

Airey and McKay

Berry, M. J.

Cool, et al.

Coombe and Pimentel

Cool, et al.

Green and Lin

Jensen and Rice

Jonathan, et al.

I EJQA7-1973-9-94 (rev.)

*ASTSZx-1970-TOR-0059 (6753-10 )-l

ACIEAY-1970-9-773 (rev.)

CITEAH-1970-42-573 (rev.)

CHPLBC-1969-3-210 (r. p.)

JCPSA6-1968-49-4257

JCPSA6-1967-47-857

CHPLBC-1972-12-550

IEJQA7-1970-6-185 (r. p.)

JCPSA6-1972-55-969

APPLAB-1970-16-386 (r. p.)

CHPLBC-1973-19-1 (pop. distr.)

JPCHAX-1963-67-2156 (r. p.)

JPCHAX-1965-69-408 (r. p.)

JPCHAX-1968-72-3168 (r. p.)

IJCKB0-1970-2-335 (r. p.)

JPCHAX-1959-63-1468 (r. p.)

IEJQA7-1971-7-501 (r. p.)

CHPLBC-1971-10-577 (r. p.)

JCPSA6-1969-51-91

IEJQA7-1973-9-723 (r. p.)

JCPSA6-1973-59-3612 (r. p.)

DAKEAT-1969-50-1 (rev.)

IEJQA7-1970-6-174 (rev.)

PACHAS-1969-18-275 ( rev .

)

APPLAB-1972-20-356 (r 6 p.)

JCPSA6-1970-53-3385

KICAA8-1964-6-1 (mech.)

IJCKB0-1969-1-493 (r. o.)

IEJQA7-1970-6-169 (r. p.)

JCPSA6-1973-58-1269

APPLAB-1971-19-411 (r. p.)

JCPSA6-1972-57-5065

XADRCA-1973-AD 763716

RJPCAR-1969-43-713

KICAA8-1969-10-949 (r. p.)

JCPSA6-1972-57-912 (calc. ,d.r. , pop. distr.,

pot. surf.,traj.)

XADRCA-1971-AD 725031 (calc.)

APPLAB-1972-20-64 (r. r>.)

IEJQA7-1973-9-202 (r. t>. )

APPLAB-1969-15-401 (r. p.)

DABBBA-1971-31-72 10

J AP I AU-1970-4 1-4038

I EJQA7-1973-9-192

APPLAB-1969-15-318 (r. p.)

IEJQA7-1971-7-98 (r. p.)

CHPLBC-1970-7-627 (r. p.)

MOPHAM-1971-22-56

16
Jonathan, et al.

Jonathan, et al.

Kirsch and Polanyi

Kompa and Wanner

iii. F + RH -> HF* + R

Perry, M. J.

Brus and Lin

Chang and Setser

Chan/*, et al.

Chang, et al.

Clyne, et al.

Creighton, et al.

Duewer and Setser

Fettis, et al.

Green and Lin

Gregg, et al.

Jacobson and Kimhell

Jacobson and Kimhell

Johnson, et al.

Jonathan, et al.

Jonathan, et al.

Kapralova, et al.

Kim and Setser

Kim and Setser

KomDa, et al.

Kompa and Wanner

Krogh and Pimentel

Lin and Green

Mercer and Pritchard

Molina and Pimentel

Padrick and Pimentel

Parker and Pimentel

Parker and Pimentel

Parker and Pimentel

Pimentel, G. C.

Pimentel, G. C.

Suchard and Pimentel

Vedeneev, et al.

i. H + F

2 -> HF^ + F

Airey, J. R.

Albright, et al.

Basov, et al.

Burmas ov, et al.

Cohen, N.

Cool, et al.

Cool, et al.

Dodonov, et al.

CHPLBC-1970-7-257

APOPAI-1971-10-182 1 ( calc .

)

JCPSA6-1972-57-4498 ( calc . CHPLBC-1972-12-560

IEJQA7-1973-9-199 (r. p.)

JP CRAX-1971-75-2546

JCPSA6-1973-58-2298 (pop. distr.)

JPCHAX-1971-75-2070

CHPLBC-1971-9-587

CJCHAG-1973-51-3596 (r. p.)

IEJQA7-1973-9-200

JCPSA6-1973-58-2310 (pop. distr.)

JCSOA9-1960-1064 (r. p.)

JCPSA6-1971-54-3222

CHPLBC-1971-8-609

CHPLBC-1971-8-309 (r. p.)

JAPIAU-1971-42-3402 (r. p.)

JPCHAX-1973-77-2499 (calc, pop. distr.,

pot. surf. ,traj.)

MOPHAM-1971-20-93

APOPAI-1971-10-182

KICAA8-1970-11-669 (r. p.)

ACSRAL-1973-166-Phys. 99

JPCHAX-1973-77-2493 (pop. distr.)

CHPLBC-1969-3-210 (r. p.)

CHPLBC-1972-12-560

JCPSA6-1972-56-969

JCPSA6-1970-53-3383

JPCHAX-1959-63-1468 (r. p.)

IEJQA7-1973-9-64

APPLAB-1972-20-167

IEJQA7-1970-6-175

JCPSA6-1968-48-5273 (r. p.)

JCPSA6-1971-55-857

DAKEAT-1969-50-1 (rev.)

IEJQA7-1970-6-174 (rev.)

APPLAB-1971-18-530

KICAA8-1963-4-278 (r. r>.)

h. Abstraction of F Atom by H(D) Atom

IJCKBO-1970-2-65

JCPSA6-1969-50-3632

JTPLA2-1969-9-375 (r. p.)

JTPLA2-1969-10-28 (r. p.)

XADRCA-1972-AD 763715

APPLAB-1969-15-318 (r. p.)

JAPIAU-1970-41-4038

KICAA8-1970-1 1-677

17
Emanuel, et al.

Hess, L. D.

Jonathan, et al.

Jonathan, et al.

Jonathan, et al.

Kaoralova and Chaikin

Kerber, et al.

Kerber and Whittier

Komoa, K. L.

Levy and Copeland

Levy and Copeland

Levy and Copeland

Mayer, et al.

O'Neil, et al.

Polanyi and Sloan

Semenov and Shilov

Slootmaekers and Van

Suchard, et al.

Suchard, et al.

Suchard, et al.

Tal'roze, et al.

Vedeneev, et al.

Vedeneev, et al.

Wilkins, R, L.

Wilkins, R. L.

Wilson and Stephenson

ii. H + FX -> HF± + X

Kroe;h and Pimentel

Mayer, et al.

Pimentel, G. C.

iii. H + RF -> HF+ + R

XADRCA-1972-AD 746685 (rev.)

J CPS A6-1971-55-2466

JCPSA6-1970-53-4396 (r. p.)

APOPAI-1971-10-182 1 ( calc

)

M0PHAM-1972-24-1143 (calc, pot. surf.,

traj.)

CBFMAO-1969-13-557 ( mech .

)

I IEJQA7-1973-9-94 (rev.) * ASTSZX-1970-TOR-0059 ( 6753-10 )-l

CITEAH-1970-42-573 (rev.

)

JPCHAX-1963-67-2156 (mech.)

JPCHAX-1965-69-408 (r. p.)

JPCHAX-1968-72-3168 (r. p.)

SYMCAO-1967-1 1-837 (r. p.)

JCPSA6-1973-58-1126 (calc, pot. surf.)

JCPSA6-1972-57-4988 ( calc .

, d . r .

)

KICAA8-1964-6-1 (mech e ) Ti^elen BSCBAG-1958-67-135 (r. p.)

APPLAB-1971-19-411 (r. p.)

JCPSA6-1972-57-5065

XADRCA-1973-AD 763716

KICAA8-1970-1 1-233

KICAA8-1963-4-278 (r. p.)

RJPCAR-1969-43-713

JCPSA6-1973-58-2326 ( calc .

, d . r . , pot . s urf .

,

traj .

)

XADRCA-1971-AD 725031 (calc)

APPLAB-1972-20-64 (r. p.)

JCPSA6-1972-56-969

SYMCAQ-1967-1 1-837 (r. p.)

JCPSA6-1973-58-1270 (r. p.)

Cross, J. B.

Gensel, et al.

Herbelin and Cohen

Kro^h and Pimentel

Perona, M. J.

Pimentel, G. C.

Rabideau, S. W.

JCPSA6-1973-59-966 (r. p.)

CHPLBC-1970-5-179 (r. p.)

CHPLBC-1973-20-605 (r. p.)

JCPSA6-1972-56-969

JCPSA6-1971-54-4024

JCPSA6-1973-58-1270 (r. p.)

JCPSA6-1973-59-1533

2. Unimolecular Reactions (elimination lasers)

a. R

1 + R

2 -> R^R^]* HF^ + M (chemical activation)

Berry, M. J.

Berry and Pimentel

Berry and Pimentel

DABBBA-1971-31-72 10

IEJ(|A7-1970-6-176

J CPS A6-1968-49-5190

IS
b.

a.

Brus and Lin JPCHAX-1971-75-2546

Clough, et al. CJCHAG-1970-48-2919

Cuellar-Ferreira and Pimentel I EJQAT-1973-9-201

Gordon and Lin

Lin, M. C.

Lin, M. C.

Padrick and Pimentel

Padrick and Pimentel

Pimentel, G. C.

Roebber and Pimentel

Ross and Shaw

ACSRAL-1973-166-Phys . 137

IEJQA7-1973-9-200 (r. p.)

JP CHAX-1971-75-3642

APPLAB-1972-20-167

JCPSA6-1971-54-720

IEJQA7-1970-6-174 (rev.)

IEJQA7-1973-9-201 (r. p.)

JPCHAX-1971-75-1170 (r. p.)

hv -> HF* + M (photochemical elimination)

Berry, M. J.

Berry and Pimentel

Berry and Pimentel

Klimek and Berry

Klimek and Berry

Kompa, K. L,

Pimentel, G. C.

DABBBA-1971-31-72 10

IEJ0A7-1970-6-176

JCPSA6-1969-51-2274 (r. p.)

ACSRAL-1973-166-Phys. 103

CHPLBC-1973-20-141

AC I EAY-1970-9-773 (rev.)

IEJQA7-1970-6-174 (rev.)

B. HF*(DF*) Energy Transfer and Quenching

1. HF^(DF*) Energy Transfer

HF(v. = 0) + M 0) + ! T -> HE

Hancock and Green

Heydtmann, et al.

Suchard, et al.

(M ^ HE) (energy transf(

to HF from M*)

J CPS A6-1972-56-2474

APOPAI-1971-10-1755

XADRCA-1973-AD 763716

rred

b. HF*^ = m ) + M -> HF^(v. < m ) + ( Vj ^ 0)

(energy transferred from HF* to M)

Ahl and Cool

Basov, et al.

Basov, et al.

Basov, et al.

Berend and Thommarson

Berend and Thommarson

Blauer, et al.

Blauer, et al.

Bott and Cohen

Bott and Cohen

Chester, A. N.

Cohen, N.

Cohen, et al.

Cool, et al.

Cool, et al.

JCPSA6-1973-58-5540

APOPAI-1971-10-1814

JTPLA2-1969-9-375 (r. p.)

IEJ0A7-1970-6-183 (r. p.)

IEJQA7-1973-9-195

XADRCA-1973-AD 763817

SYMCAQ-1971-13-109

JCPSA6-1972-57-3277

JCPSA6-1973-58-4539

JCPSA6-1973-59-447

JCPSA6-1970-53-3595 (r. p.)

XADRCA-1972-AL 763715

IEJQA7-1970-6-168 (r. p.)

APPLAB-1969-15-318 (r. p.)

JAPI AU-1970-41^038

19
Dillon and Stephenson

Falk, T. J.

Green and Hancock

Gross, R. W. F.

Hancock and Green

Hancock and Green

Herbelin and Cohen

Hinchen, J. J.

Kapralova, et al.

Kapralova, et al.

Kerber, et al.

Kerber, et al.

Kerber and Whittier

Sentman, L. H.

Sentman and Solomon

Stephens and Cool

Suchard, et al.

Vasil'ev, et al.

Vedeneev, et al.

Vedeneev, et al.

JCPSA6-1973-58-2056 ( calc, cr. sect.)

XCCIAV-1972-AD 745450

IEJQA7-1973-9-50

JCPSA6-1969-50-1889 (r. p.)

JCPSA6-1972-56-2474

JCPSA6-1972-57-4515

CHPLBC-1973-20-605 (r. p.)

JCPSA6-1973-59-233

DKPCAG-1971-197-281 ( calc.

)

DKPCAG-1971-198-452 (r. p.)

IEJQ/^7-1973-9-94 (rev.)

IEJQA7-1973-9-190 (r. p.)

*ASTSZx-1970-TOR-0059 (6753-10 )-l (calc .

)

CHPLBC-1973-18-493 ( calc .

)

JCPSA6-1973-59-89 (calc.)

JCPSA6-1972-56-5863

JCPSA6-1972-57-5065

SPHJAR-1972-34-51

RJPCAR-1969-43-713

KICAA8-1970-11-26 (rev.)

HF(v.) + HF(v.) -> HF(v

k

) + HF(v

1

) (i + j = k + 1)

(HF - HF energy transfer)

Ahl and Cool

Berend and Thommarson

Bott, J. F.

Bott, J. F.

Bott and Cohen

Cohen, N.

Emanuel, et al.

Green and Hancock

Hinchen, J. J.

Kerber, et al.

Kerber and Whittier

Kerber, et al.

Kompa, et al.

Osgood, et al.

Osgood, et al.

Sentman, L. H.

Suchard, et al.

Suchard, et al.

J CPSA6-1973-58-5540

XADRCA-1973-AD 763817

IEJQA7-1973-9-189

JCPSA6-1972-57-96

JCPS A6-1973-59-447

XADRCA-1972-AD 763715

XABRCA-1972-AD 746685 (rev.)

IEJQA7-1973-9-50

JCPSA6-1973-59-233

IEJQA7-1973-9-190

*ASTSZx-1970-TOR-0059 (6753-10 )-l

IEJQA7-1973-9-94 (rev.)

JCPSA6-1968-49-4257

IEJQA7-1973-9-190

APPLAB-1972-20-469

CHPLBC-1973-18-493 (calc.)

J CPS A6-1972-57-5065

XADRCA-1973-AD 763716

20
2. HF+(DF+) Quenching

a. HF*(v

i = m) + M -> HF±(Vj < m ) + M (v > 0)

(collisional quenching)

Ahl and Cool

Airey, J. R.

Airey and Fried

Airey and Smith

Anlauf, et al.

Be rend and Thommarson

Berend and Thommarson

Blair, et al.

Blauer and Solomon

Blauer and Solomon

Blauer, et al.

Blauer, et al.

Bott and Cohen

Bott and Cohen

Bott and Cohen

Bott and Cohen

Brokav, R. S.

Cohen, N.

Emanuel, et al.

Fried, et al.

Green and Hancock

Hancock and Green

Hancock and Green

Hess, L. D.

Hinchen, J. J.

Hinchen, J. J.

Just and Rimpel

Kapralova and Chaikin

Kapralova, et al.

Kapralova, et al.

Kapralova, et al.

Kerber, et al.

Kerber and Whit tier

Kerber, et al.

Kompa, et al.

Kwok, M. A.

Molina and Pimentel

Parker, J. V.

Sentman, L. H.

Shin, H. K.

Suchard, et al.

Suchard, et al.

Thompson, D. L.

Thompson, D. L.

Wilkins, R. L.

Wilkins, R. L.

JCPSA6-1973-58-5540

IJCKBO-1970-2-65

CHPLBC-1971-8-23

JCPSA6-1972-57-1669

JCPSA6-1973-58-5354

IEJQA7-1973-9-195

JCPSA6-1973-58-3454 (calc. , traj .

)

JCPSA6-1973-59-1582

IJCKB0-1973-5-553

SYMCAQ-1973-14-189

IJCKB0-1972-4-293

XCCIAV-1972-AD 738296

JCPSA6-1971-55-3698

JCPSA6-1971-55-51 4

JCPSA6-1973-58-934

JCPSA6-1973-58-4539

JPCHAX-1965-69-2488

XADRCA-1972-AD 763715

XADRCA-1972-AD 746685 (rev.)

IEJQA7-1973-9-59

IEJQA7-1973-9-50

JCPSA6-1972-56-2474

JCPSA6-1972-57-4515

IEJQA7-1973-9-201 (r. u.)

IEJQA7-1973-9-196

JCPSA6-1973-59-233

IEJQA7-1973-9-196

CBFMAO-1969-13-557

KICAA8-1969-10-23

CHPLBC-1968-2-581 (calc. , trans, prob.

)

KI CAA8-1964-6-884

IEJQA7-1973-9-190 (r. p.)

*ASTSZx-1970-TOR-0059 (6753-10 )-l

IEJQA7-1973-9-94 (rev.)

JCPSA6-1968-49-4257

IEJQA7-1973-9-196

IEJQA7-1973-9-64

IEJQA7-1973-9-189

CHPLBC-1973-18-493 ( calc .

)

CHPLBC-1972-14-64 (calc.)

JC PSA6-1972-57-5065

XADRCA-1973-AD 763715

JCPSA6-1972-57-4164 (calc.,uot surf., traj.)

JCPSA6-1972-57-4170 (calc. , traj .

)

JCPSA6-1973-58-3038 (calc., pop. distr.,

pot. surf., traj .)

JCPSA6-1973-59-698

21
b. HF+(v

i = in) + HF -> HF^fv^ < m ) + HF(vj ? 0)

(HF - HF self-quenching)

Ahl and Cool

Airey and Fried

Airey and Smith

Tier end and Thommarson

Berend and Thommarson

Blair, et al.

Blauer, et al.

Bott, J.

Bott and Cohen

Bott and Cohen

Bott and Cohen

Emanuel, et al.

Falk, T. J.

Fried, et al.

Green and Hancock

Hancock and Green

Hancock and Green

Hinchen, J. J.

Hinchen, J. J.

Just and Rimpel

Komrn, et al.

Mac Lean and Tregay

Molina and Pimentel

Sentman, L. H.

Shin, H. K.

Shin, H. K.

Solomon, et al.

Stephens and Cool

Suchard, et al.

Tal'roze, et al.

Thompson, T). L.

Vasil'ev, et al.

JCPS A6-1973-58-5540

CHPLBC-1971-8-23

JCPSA6-1972-57-1669

IEJQA7-1973-9-195

JCPSA6-1973-58-3203

J CPS A6-1973-59-1582

SYMCAQ-1971-13-109

IEJQA7-1973-9-189

JCPSA6-1971-55-3698

JCPSA6-1973-58-934

JCPSA6-1973-58-4539

XADRCA-1972-AD 746685

XCCIAV-1972-AD 745450

IEJQA7-1973-9-59

IEJQA7-1973-9-50

J CPSA6-1972-56-2474

JCPSA6-1972-57-4515

IEJQA7-1973-9-196

JCPSA6-1973-59-233

IEJQA7-1973-9-196

JCPSA6-1968-49-4257

XADRCA-1971-AD 732927

IEJQA7-1973-9-64

CHPLBC-1973-18-493 (calc.)

CHPLBC-1971-1 0-81 ( calc .

)

JCPSA6-1973-59-879 (calc.)

IJCKBO-1971-3-215

J CPSA6-1972-56-5863

JC PS A6-1972-57-5065

KICAA8-1970-1 1-233

J C PS A6-1972-57-2589

DKPCAG-1970-19 1-296

:. HF^(v^ = m) + M -> nroducts (dissociative quenching)

i. HF^(v

i = m ) + M2 -> HF(v, = 0) + M + M

Airey, J. R.

Basov, et al.

Brokaw, R. S.

Kapralova and Chaikin

Kanralova and Chaikin

Kauralova, et al.

Kawalova, et al.

Kat>ralova, et al.

Kat»ralova, et al.

Kompa, K. L.

Tal'roze, et al.

Vasil'ev, et al.

IJCKBO-1970-2-65

JTPLA2-1969-9-375 (r. p.)

JCPSA6-1965-69-2488

C BFMA0--1969-13-557

KICAA8-1969-1 0-195 (r. p.)

DKPCAG-1971-198-452 (r. p.)

KICAA8-1969-10-23

KICAA8-1963^-567 (r. p.)

KICAA8-1964-6-884

AC I EAY-1970-9-773 (rev.)

KICAA8-1970-11-233

DKPCAG-1970-191-296

22
ii. HF+(v. = td) + M->H + F+ M

Maclean and Tre^ay SYMCAQ-1973-14-157

HF* (DF+) Theoretical papers

Anlauf, et al.

Ben-Shaul, et al.

Ben-Shaul, et al.

Berend and Thommarson

Blais and Truhlar

Billon and Stephenson

Emanuel and Whittier

Jaffe and Anderson

Jaffe, et al.

Jonathan, et al.

Kapralova, et al.

Kerber, et al.

Levine, et al.

Muckerman, J. T.

Muckerman, J. T.

Muckerman, J. T.

Muckerraan and Newton

O'Neil, et al.

Polanyi and Sloan

Polanyi and Tardy

Polanyi and Woodall

Schatz, et al.

Thompson, D. L.

Thompson, "D. L.

Thruhlar, T>. G.

Wilkins, R. I.

Vilkins, R. L.

Wilkins, R. L.

Wilkins, R. L.

JCPSA6-1970-53-4091 (pop. distr.)

J CPSA6-1 972-57-5427 (calc, pop. distr.)

CHPLBC-1972-15-160 (pop. distr.)

JCPSA6-1973-58-3454 (calc, traj.)

JCPSA6-1973-58-1090 (pot. surf., t raj.)

JCPSA6-1973-58-2056 (calc.,cr. sect.)

APOPA1-1972-1 1-2047 (calc.)

JCPSA6-1971-54-2224 (pot. surf., t raj.)

JCPSA6-1973-59-1128 (pot. surf., traj.)

M0PHAM-1972-24-1143 (pop. distr.,

pot. surf.,traj.)

CHPLBC-1968-2-581 (trans, proh.

)

APOPAI-1972-1 1-1112 (pop distr. , model.

)

CHPLBC-1973-19-1 (pop. distr.)

JCPSA6-1971-54-1 155 ( traj .

)

JCPSA6-1972-56-2997 (pot. surf., traj.)

JCPSA6-1972-57-3388 (pop. distr. , traj .

)

JCPSA6-1972-56-3191 (pot. surf.)

JCPSA6-1973-58-1126 (calc, pot. surf.)

JCPSA6-1972-57-4988 (d. r.

)

JCPSA6-1969-51-5717 (pop. distr.)

JCPSA6-1972-57-1574 (d. r.

)

JCPSA6-1973-53-4023 (pop. distr.)

JCPSA6-1972-57-4164 (calc, pot. surf.

traj.

)

JCPSA6-1972-57-4170 (calc. , traj .

)

JCPSAS-1972-56-3189 (pot. surf.)

JCPSA6-1972-57-912 (calc., pop. distr.,

pot. surf. , traj.)

JCPSA6-1973-53-3038 (calc,pop. distr.

pot. surf. , traj.)

JCPSA6-1973-58-2326 (calc, pop. distr.,

pot. surf. , traj.)

J CPSA6-1973-59-698 (calc. ,d.r. , pop. distr.,

pot. surf.,traj.)

23
Part II. Hydrogen chloride (HC1, DC1)

A. Formation of HC1* (DC]*)

1. Bi molecular reactions (abstraction lasers)

a. Abstraction of H(D) atom by CI atom

i. CI + H

2 -> HCl^ + H

Ashmore, P. G.

Ashmore and Chanmu^ara

Benson, et al.

Clyne and Walker

Corneil, P. H.

Corneil and Kasper

Corneil and Pinentel

Davis, et al.

Deutsch, T. F.

Deutsch, T. F.

Deutsch, T. F.

Fettis and Knox

Galante and Gislason

Henry, et al.

Johnson, et al.

Klein, et al.

Kompa, K. L.

Norrish, R. G. W.

Pitientel, G. C.

Raff, et al.

Shiz^al and Xarplus

Snider, N. S«

Stednan, et al.

Truhlar, D. G.

Westenber^, A. A. Westenber^ and cie Haas

Wood, G. 0.

Wood and Chan^

Yaakov, et al.

ii. CI + HX -> HC1* + X

Airey, J. P.

Airey, J. R.

Airsy, J. R.

Anlauf, et al.

Anlauf, et al.

Anlauf, et al.

Anlauf, et al.

Ben-Shaul, et al.

Ben-Shaul, et al.

Blauer, et al.

Chester, A. N.

Cool, et al.

TFS0A4-1953-49-251 (r. p.)

TFS0A4-1953-i9-254 (r. r>.)

IJCKBO-1969-1-29 fr. p.)

JCFTAR-1973-59-1547 (r. p.)

DABSA9-1968-28-4524

IEJQA7-1970-6-170

JCPSA6-1968-49-1379

IJCKBO-1970-2-101 (r. p.)

APPLAB-1967-1 0-234 (r. p.)

APPLAB-1967-1 1-13 (r. p.)

ISJQA7-1967-3-419 (r. p.)

PRKMZ-1964-2-2 (r. p.)

CHPLBC-1973-18-231 (r. p.)

CHDBAN-1958-257-616

JCPSA6-1970-52-6372

JCPSA6- 1964-41-1799

CITEAH-1970-42-573 ( rev.

)

PRLAAZ-1967-301-1 (r. p.)

SCAfUC-1956-214-32 (r. p.)

J CPSA6-1970-53-1606

JCPSA6-1971-54-4357 (r. p.)

JCPSA6-1970-53-4116 (r. p.)

CHPLBC-1970-7-173

JCPSA6-1972-56-3189 (r. p.)

JCPSA6-1970-53-4117 (r. p.)

JCPSA6-1968-43-4-i05 (r. p.)

JCPSA6-1972-56-1723 (r. p.)

APPLAB-1972-20-77 (r. p.)

JCPSA6-1973-59-2415 (r. p.)

IEJQA7-19S7-3-203 (r. p.)

IEJQA7-1970-6-175

JCPSA6-1970-52-156

JCPSA6-1970-53-4091

DFS0AW-1967-44-133 (pop. distr.)

PYLAAG-1967-24-203 (pop. distr.)

JCPSA6-1968-49-5139 ( calc .

}

CHPLBC-1972-15-160 (pop. distr.)

JCPSA6-1972-57-5427 ( calc .

)

XADRCA-1972-AD 738296

JCPS A6-1970-53-3595

APPLAB-1969-15-313 (r. p.)

24
Cool, et al.

Cool, et al.

Cowley, et al.

Glaze, et al.

Kompa, K. L.

Levine, et al.

Maylotte, et al.

Moore, C. B.

Moore and Zittel

Naegeli and Ultee

Piraentel, G. C.

Polanyi, J. C.

Polanyi and Woodall

iii. CI + RK -> HCl^ + R

Clyne and Walker

Davis, et al.

Fettis and Knox

Knox and Nelson

IJCKB0-1969-1-495 (r. p.)

JAPIAU-1970-41-4038 (r. p.)

CHPLBC-1971-12-144

APPLAB-1971-18-173 (r. p.)

ACIEAY-1970-9-773 (rev.)

CHPLBC-1973-19-1 (poD. distr.)

JCPSA6-1972-57-1547

ISJQA7-1968-4-52 (r. p.)

SCIEAS-1 973-182-541 (rev.)

CHPLBC-1970-6-121 (r. r>.)

PACHAS-1969-18-275 (rev.)

APOSAR-1965-2-109 (theory)

JCPSA6-1972-55-1563 ( calc .

)

JCFTAR-1973-69-1547 (r. p.)

IJCKBO-1970-2-101 (r. p.)

PRKNAZ-1964-2-2 (r. p.)

TFS0A4-1959-55-937

b. Abstraction of CI Atom by H(D) Atom

i. H + Cl

2 -> HCl^ + CI

Airey, J. R.

Airey, et al.

Airey, et al.

Albright, et al.

Anlauf, K. G.

Anlauf, et al.

Anlauf, et al.

Anlauf, et al.

Anlauf, et al.

Ashmore, P. G.

Basov, et al.

Ben-Shaul, et al.

Bo wen and Overholser

Cabre and Henry

Cabre and Henry

Charters, et al.

Cashion and Polanyi

Cashion and Polanyi

Cashion and Polanyi

Cashion and Polanyi

Cashion and Polanyi

Charters and Polanyi

Chester, A. N.

Cool, et al.

Cool, et al.

Corneil and Kasper

Dodonov, et al.

IJCKBO-1970-2-65

CJCHAG-1964-42-2 193

JCPSA6-1964-41-3255

J CP S A6-1969-50-3632

DABBBA-1970-31-1 195

JCPSA6-1970-53-4091

JCPSA6-1972-57-156

PFS0AW-1967-44-183

PYLAAG-1967-24-208

TFS0A4-1953-49-251

JTPLA2-1969-9-147 ( JCPSA6-1972-57-5427

ASACAW-1969-14-475

JCPQAY-1967-64-119

CHDBAN-1969-269-46

NATUAS-1962-193-367

JCPSA6-1958-29-455

JCPSA6-1959-30-1097

JCPSA6-1961-35-600

PRLAAZ-1960-258-529

PRL AAZ-1960-258-564

DFSOAW-1962-33-107

JCPSA6-1970-53-3595

APPLAB-1969-15-318

JAP I AU-1970-4 1-4038

IEJQA7-1970-6-170

KICM8-1970-1 1-677

(calc, pop. distr.)

(calc, pop. distr.)

(d. r.)

(pop. distr.)

(pop. distr.)

(mech.

)

rev.

)

(calc, pop. distr.)

(pop. distr.)

(pop. distr.)

(pop. distr.)

(r. p.)

(r. p.)

(pop. distr.)

(pop. distr.)

(r. p.)

(pop. distr.)

(calc, pop. distr.)

(r. p.)

(r. p.)

25
Fass, et al.

Henry, et al.

Kasner, J. V. V.

Kasper and Pimentel

Klein and Wolfsber^

Kompa, K. L.

Lev in e, et al.

Mayer, et al.

Menard-Bourcin, et al.

Miller and Li^ht

Moore, C. B.

Norrish, R. G. VI. Pacey and Polanyi

Perona, et al.

Pimentel, G. C.

Pimentel, G. C.

Pimentel, G. C.

Pimentel, G. C.

Polanyi, J. C„

Polanyi, J. C.

Polanyi, J. C.

Polanyi, J. C.

Polanyi, J. C.

Polanyi, J. C,

Polanyi, J. C.

Polanyi and Rosner

Polanyi and Woodall

Rice and Jensen

Russell and Li^ht

Semenov and Shilov

Slootmaekers and Van Ti^elen

Spinnler and Kittle

Stedman, et al.

Wilkins, R. L.

Warner and Wolfrum

JPCHAX-1972-76-2801 (r. p.)

CHDBAN-1968-267-616

DIASA9-1966-26-5062 (r. p.)

PRLT A0-1965-14-352

JCPSA6-1961-34-1494 (r. t). ) CITEAH-1970-42-573 (rev.)

CHPLBC-1973-19-1 (pop. dist.)

SYMCAQ-1967-1 1-837 (r. p.)

CHDBA1I-1972-274-241 (x>op. distr.)

JCPSA6-1971-54-1643 (calc.,pot. surf.)

IEJQA7-1968-4-52 (r. p.)

PRLAAZ-1967-301-1 (r. p.)

APOPAI-1971-10-1725

JCPSA6-1970-52-6384

DAKEAT-1969-50-1 (rev.)

IEJQA7-1970-6-174 ( rev .

)

PACHAS-1969-18-275 (rev.)

SCAMAC-1966-2 14-32 (r. x>.

)

APOSAR-1965-2-109 (calc.,Dop. distr.)

CHMBAY-1966-2-151 (rev.)

DFS0AW-1962-33-279 (r. p.)

I EJQA7-1970-6-168 (r. p.)

JCPSA6-1959-31-1338 ( rev .

)

JCPSA6-196 1-34-347 (calc.,pop. distr.)

JQSRAE-1963-3-471 (rev.)

JCPSA6-1963-38-1028 (r. p.)

JCPSA6-1972-56-1563 (cal ..pop. distr.)

IEJ0A7-1973-9-199

J CPSA6-1969-51-1720 (calc.DOT). distr.,

traj . J KICAA8-1964-6-1 (r. p.)

BSCBAG-1958-G7-135 (r. p.)

IEJQA7-1970-6-169 (r. v.)

CHPLBC-1970-7-173

JCPSA6-1965-42-806 (r. p.)

ACIEAY-1971-10-604 (rev.)

ii. E + C1X -> HCr*- + X

Anlauf, et al.

Krostfi and Pimentel

Mayer, et al.

JCPSA6-1970-53-4091 (calcpot). distr.)

J C PS A6-1972-56-969

SYMCAQ-1967-1 1-837 (r. p.)

iii. H + RC1 -> HC1* + R

Anlauf, K. G.

Charters, et al.

Cabre and Henry

Cashion and Polanyi

Freeman and Phillios

Henry, et al.

Heydtmann and Polanyi

DABBBA-1970-31-1195 (pop. distr.)

HATUAS-1962-193-367 (r. p.)

CHDBAN-1969-269-46 (pop. distr.)

JCPSA6-196 1-35-600

JPCHAX-1968-72-3031 (r. n.

)

CHDBM-1968-267-6 16

APOPAI-1971-10-1738 (dop. distr.)

2 b
Johnson, R. L. DABBBA-1969-30-2632 (nop. distr.)

Johnson, et al. JCPSA6-1970-52-6372 (nop. distr.)

Johnson and Setser CHPLBC-1969-3-207 (nop. distr.)

Lin, M. C. CHPLBC-1970-7-209 (mech.)

Menard-Bourcin, et al. CHDBAN-1972-274-241 (dot), distr.)

Perona, et al. JCPSA6-1970-52-6384

Perona, et al. JPCHAX-1969-73-2091

Rabideau, S. W. JCPSA6-1973-59-1533

Rice and Jensen IEJQA7-1973-9-199

iv. H + HC1 -> HC1* + H

Cashion and Polanyi PRLAAZ-1960-258-529 (nop. distr.)

Wood, G. 0. JCPSA6-1972-56-1723 (r. p.)

2. Unimolecular Reactions (elimination lasers)

a. R

1 + Rp -> [R-jR^l _> HCl^ + M (chemical activation)

Berry and Pimentel IEJQA7-1970-6-176

Chang, et al. JPCHAX-1971-75-2070 (pop. distr.)

Lin, M. C. IEJQA7-1973-9-200 (r. p.)

h. M^ + hv -> HCl^ + M

?

(nhotochemical elimination)

Berry, M. J. DABBBA-1971-3 1-7210

Berry and Pimentel IEJQA7-1970-6-176

Berry and Pimentel J CP S A6-1969-51-2274

Berry and Pimentel JCPSA6-1970-53-3453

Molina and Pimentel IEJQA7-1973-9-64

Molina and Pimentel JCPSA6-1972-56-3988

B. HCl^DCrh Energy Transfer. and Quenching

1. HCl^ (DC1*) Energy transfer

a. HC1 (v

i = 0) + -> HCl+(Vj > 0) + M (M ^ HC1)

(energy transferred to HC1 from M^)

Ahl and Cool JCPSA6-1973-5S-5540

Blauer, et al. JCPSA6-1972-57-3277

Chen, et al. CHPLBC-1968-2-593

Moore and Zittel SCIEAS-1973-182-541 (rev.)

b. HCl^v = m) + M -> HCl ( ^(v. < m ) + (v. > 0)

(energy transferred from IICl* to M)

Ahl and Cool JCPSA6-1973-58-5540

Airey, J. R. IEJQA7-1970-6-175

Airey, J. R. JCPSA6-1970-52-156

Bott and Cohen JCPSA6-1973-58-4539

Bowen and Overholser ASACAW-1969-14-475

Chen and Moore IEJQA7-1970-6-175

27
Chen and Moore

Chen and Moore

Chen, et al.

Cool, et al.

Cool, et al.

Dillon and Stephenson

Hopkins, et al.

Hopkins and Chen

Moore, C. B.

Moore and Zittel

Sentman, L. H.

Stephenson, et al.

Zittel and Moore

JCPSA6-1971-54-4072

J C PS A6~1971-54-4080

CHPLBC-1968-2-593

IJCKB0-1969-1-495 (r. p.)

JAPIAU-1970-41-4038 (r. p.)

JCPSA6-1973-58-2056 (calc.,cr. sect.)

JCPSA6-1973-59-836

JCPSA6-1972-57-3161

ACHRAY-1969-2-103 (rev.)

SCIEAS-1973-182-541 (rev.)

CHPLBC-1973-18-493 (calc. , model.

)

J CPS A6-1972-5G-52 14

JCPSA6-1973-58-2004

c. HCl(v.) + HCl(vj) -> HCl(vk

) + HCl(v^) (i + j = k + l)

(HC1 - HC1 energy transfer)

Bo wen and Overholser

Chen and Moore

Chen and Moore

Chen, et al.

Cohen, et al.

Cornell and Kasper

Findlay and Polanyi

Findlay and Polanyi

Gorshkov, et al.

Hookins and Chen

Hopkins and Chen

I^oshin and Oraevskii

Leone and Moore

Moore and Zittel

Polanyi, J. C.

Sentman, L. H.

Sharma, et al.

2. HCl^(DCl^) Quenching

Ahl and Cool

Bott and Cohen

Bo wen and Overholser

Chen and Moore

Chen, et al.

Cohen, et al.

Corneil and Kasper

Craip and Moore

Gorshkov, et al.

Hopkins and Chen

Kapralova, et al.

Letokhov, V. S.

ASACAVM969-14-475

JCPSA6-1971-54-4072

J CPS A6-1971-54-4080

CHPLBC-1968-2-593

IJCKBO-1969-1-551

IEJQA7-1970-6-170 ( calc .

)

CJCHAG-1964-42-2 176

IFS0AW-1962-33-274

APOPAI-1971-10-1781

IEJQA7-1973-9-196

JCPSA6-1972-57-3816

HIECAP-1971-5-357 (calc.)

CHPLPC-1973-19-340

SCIEAS-1973-182-541 (rev.)

JQSRAE-1963-3-471 (rev.)

CHPLBC-1973-13-493 (calc. , model.)

JCPSA6-1973-58-3519 ( calc .

)

a. HCl±(v = m) + M -> HCl (:,:) (v. <

J- %j m) + M (v. s o) (collisional

a^uenchin.f^)

JCPSA6-197.3-58-5540

JCPSA6-1973-58-4539

ASACAW-1969-14-4-75

JCPSA6-1971-54-4072

CHPLBC-1968-2-593

IJCKBO-1969-1-551

IEJQA7-1970-6-170 (calc.)

JPCHAX-1971-75-1622

APOPAI-1971-10-1781

JCPSA6-1972-57-3161

CHPLBC-1968-2-581 (calc. , trans, prob.)

SCIEAS-1973-180-451

28
Moore and Zittel

Ridley and Smith

Ridley and Smith

Seery, D. J.

Sentman, L. H.

Smith and Wood

Zittel and Moore

SCIEAS-1973-182-541 (rev.)

CHPLBC-197 1-9-457

JCFTBS-1972-68-1231

JCPSA6-1973-58-1^9c

CHPLBC-1973-18-49? (calc. , model.

)

M0PHAM-1973-25-441

JCPSA6-1973-58-2004

h. HCl*(v. = m) + HC1 -> HCl ( ^(v. < m) + HC1 (v. * 0)

(KC1 - HC1 self-quenching)

Ahl and Cool

Borrell, P.

Bowen and Overholser

Bowman and Seery

Breazeale and Kneser

Breshears and Bird

Cahre and Henry

Chen, H-L.

Chen and Moore

Chen, et al.

Cohen, et al.

Cornell, P. H.

Corneil and Fasper

Ferguson and Read

Kapralova, et al,

Leto)diov, V. S.

Marmot tin-Maclou, et al.

Molina and Pimentel

Moore, C. B.

Ridley and Smith

Sentman, L. H.

Shin, H. K.

Shin, H. X.

Stephenson, et al.

Thommarson and Berend

Thompson, B. L.

Thompson, D. L.

Zittel and Moore

c. HCl*(v. = m ) + M

2 -> HCKvj

JCPSA6-1973-5S-5540

CSSPAB-1966-20-263

ASACAW-19G9-14-475

JCPSA6-1969-50-1904

JASMA>I-1960-32-885

JCPSA6-1969-50-333

JCPQAY-1967-64-119 Uop. distr.)

JCPSA6-1971-55-5551

JCPSA6-1971-54-4072

CHPLBC-1968-2-593

IJCKBO-1969-1-551

DABSA9-19G8-28-4524 (r. p.)

I EJ0A7-1970-6-170

TFS0A4-1967-63-61 (calc.)

CHPLBC-1968-2-5S1 (calc. , trans. t>rob.

)

SCIEAS-1973-180-451

APOPAI-1971-10-1768

IEJQA7-1973-9-64

JCPSA6-1965-43-297 (calc. , model.

)

JCFTBS-1972-G8-1231

CHPLBC-1973-18-493 (calc. , model.

)

CHPLBC-1970-6-494 ( calc

)

JPCHAX-197 1-75-1 079 (calc.)

JCPSA6-1972-56-52 14

IJCKBC-1973-5-629 (calc, pot. surf.,

traj .)

JCPSA6-1972-56-3570 (calc, pot. surf.,

traj.)

JCPSA6-1972-57-2589

JCPSA6-1973-58-2004

0) + M + M (dissociative

quenching)

Anlauf, et al. JCPSA6-1969-51-5716

Slootmaekers and Van Tiggelen BSCBAG-1958-67-135 (r. p.)

29
hci+ (Dcrh Theoretical papers

Anlauf, et al.

Anlauf, et al.

Anlauf, et al e Ben-Shaul, et al.

Ben-Shaul, et al.

Dillon and Stephenson

Kapralova, et al.

Levine, et al.

Miller and Li^ht

Moore, C. B.

Parr and Truhlar

Parr, et al.

Polanyi, J. C.

Polanyi, J. C.

Polanyi and Rosner

Polanyi and Woodall

Raff, et al.

Rankin and Li^ht

Russell and Li^ht

Sentman, L. H.

Sharina, et al.

Shin, H. K.

Shin, H. K.

Stern, et al.

Wei and Yankv/ich

JCPSA6-1970-53-4091 (calc.,pon. distr.)

JCPSA6-1972-57-1561 (calc, d. r.

)

JCPSA6-1963-49-5189 (nop. distr.)

CHPLBC-1972-15-160 (pon. distr.)

JCPSA6-1972-57-5427 (calc, nop. distr.)

JCPSA6-1973-58-2056 (calc.,cr. sect.)

CHPLBC-1968-2-581 (calc. , trans . nrob.

)

CHPLBC-1973-19-1 (non. distr.)

JCPSA6-1971-54-1643 (calc, not. surf.)

JCPSA6-1965-43-2979 (calc. , model.

)

JPCHAX-1971-75-1844 (calc, not. surf.)

JCPSA6-1973-58-5 (calc, pop. distr.,

pot. surf.,traj.)

APOSAR-1965-2-109 (pot. surf.)

JCPSA6-1959-31-1338 (nop. distr.)

JCPSA6-1963-38-1028 (r. p.)

JCPSA6-1972-56-1563 (calc.non. distr.)

JCPSA6-1970-53-1606 (calc.)

JCPSA6-1969-51-1701 (calc, pop. distr.,

not. surf.)

JCPSA6-1969-51-1270 (calc, pop. distr.,

traj .)

CHPLBC-1973-18-493 (calc. , model.

)

JCPSA6-1973-58-3519 (calc.)

CHPLBC- 1970-6-494 (calc. .model.

)

JPCHAX-1971-75-1079 (calc.)

JCPSA6-1973-5S-5697 (calc. , model.

)

J CP SA6- 1973-58-5552 (calc.)

30
Part III. Hydrogen bromide (HBr, DBr)

A. Formation of HBr*(DBr*)

Bimolecular reactions (abstraction lasers)

Abstraction of H (D) atom by Br atom

Br + H

2 -> HBr* + H

1.

a.

i.

Bodenstein and Jung

Deutsch, T. F.

Deutsch, T. F.

Fettis and Knox

Jost, W.

Raff, et al.

Truhlar, D. G.

Wood and Chang

ii. Br + HX -> HBr* + X

Anlauf, et al.

Blauer, et al.

Maylotte, et al.

iii. Br + RH -> HBr* + R

Fettis and Knox

ZEPCAC-1926-12 1-127 (r. p.)

APPLAB-1967-10-234 (r. t>. ) IEJQA7-1967-3-419 (r. t>.)

PRKNAZ-1964-2-2 (r. p.)

ZPCBAL-1929-3-95 (r. p.)

JCPSA6-1970-53-1606 ( calc .

)

JCPSA6-1972-56-3189 (pot. surf.)

APPLAB-1972-20-77 (r. p.)

DFS0AW-1967-44-183 ( calc .

)

XADRCA-1972-AD 738296

JCPSA6-1972-57-1547 (pop. distr.)

PRKNAZ-1964-2-2 (r. t>.)

b. Abstraction of Br Atom by H(D) Atom

i. H + Br

2 -> HBr* + Br

Airey, et al.

Anlauf, K. G.

Anlauf, et al.

Anlauf, et al.

Anlauf, et al.

Anlauf, et al.

Ben-Shaul, et al.

Bodenstein and Jung

Cashion and Polanyi

Chester, A. N.

Cool and Stephens

Fass, et al.

Jost, W.

Mayer, et al.

Pimentel, G. C.

Polanyi, J. C.

Polanyi, J. C.

Warner and Wolfrum

White, J. M.

SYMCAQ-1967-11-85

DABBBA-1970-31-1 195

JCPSA6-1970-53-4091

JCPSA6-1972-57-1561

DFS0AW-1967-44-183

PYLAAG-1967-24-208

JCPSA6-1972-57-5427

ZEPCAC-1926-12 1-127

PRLAAZ-1960-258-570

JCPSA6-1970-53-3595

JCPSA6-1970-52-3304

JPC HAX-1972-76-280

ZPCBAL-1929-3-95 (r

S YM CAQ-1967-1 1-837

PACHAS-1969-18-275

IEJQA7-1970-6-168 ( JCPSA5-1959-31-1338

ACIEAY-1971-10-604

JCPSA6-1973-58-4482

(calc, pop. distr.)

(calc, d. r.)

(calc, pop. distr.)

(pop. distr.)

(calc, pop. distr.)

(r. p.)

(calc, pop. distr.)

(r. p.)

. p.)

(r. p.)

(rev.

)

r, p.)

(rev.)

(rev.)

(calc, cr. sec,

pop. distr. ,traj .

)

31
ii. H + BrX -> HBr* + X

Ben-Shaul, et al. JCPSA6-1972-57-5427 (calc, pop. distr.)

Mayer, et al. S YMCAQ-1967-1 1-837 (r. p.)

B. HBr* (DBrT

) Energy Transfer and Quenching

1. HBr* (DBr*) Energy Transfer

a. HBr(v. = o) + M* -> HBr+(v. > o) + H (H / HBr)

(energy transferred to HBr from M*)

JCPSA6-1973-58-5540

IEJQA7-197Q-6-175

JCPSA6-1970-52-156

JCPSA6-1973-58-4539

IEJQA7-1970-6-175

JCPSA6-1971-54-4080

JAPI AU-1970-41-4038

TFS0A4-1970-66-2 148

SCIEAS-1973-182-541 (rev.)

h. HBr±(v = m) + M -> HBr ( ^(v < m ) + M* (v. 2 o)

l J J I (energy transferred from HBr* to M)

Ahl and Cool

Airey, J. R.

Airey, J. R.

Bott and Cohen

Chen and Moore

Chen and Moore

Cool, et al.

Donovan, et al.

Moore and Zittel

Ahl and Cool JCPSA6-1973-58-5540

Bott and Cohen JCPSA6-1973-58-4539

Chen, H-L. JCPSA6-1971-55-5551

Chen, H-L. JCPSA6-1971-55-5557

Cool and Stephens JCPSA6-1970-52-3304 (r. p.)

Donovan, et al. TFSOA4-1970-66-2148

Hopkins, et al. JCPSA6-1973-59-836

Hopkins and Chen JCPSA6-1973-59-1495

Sentman, L. H. CHPLBC-1973-18-493 (calc. , model.

)

Stephenson, et al. JCPSA6-1972-56-5214

c. HBr(v.) + HBr (v.) -> HBr(v

k

) + HBr(v^) (i + j = k + i)

(HBr - HBr energy transfer)

Chen, H-L. JCPSA6-1971-55-5551

2. HBr* (DBr*) Quenching

HBr*(v. = m) + M -> HBr (:}:) (v. < m ) + M (v. > 0)

(collisional quenching)

Ahl and Cool JCPSA6-1973-58-5540

Bott and Cohen JCPS A6-1973-58-4539

Chen and Chen JCPSA6-1972-56-3315

Hopkins and Chen JCPSA5-1973-59-1495

Sentman, L. H. CHPLBC-1973-18-493 (calc. , model.

)

32
HBr* (v. - m) + HBr -> HBr^ (v. < m) + HBr (v. > 0)

(HBr - HBr self-quenching)

Ahl and Cool

Borrell, P.

Breshears and Bird

Chen and Chen

Ferguson and Read

Kanralova, et al.

Kiefer, et al.

Moore, C. B.

Sharma, et al.

Shin, H. K.

Shin, H. K.

Stephenson, et al.

HBr* (DEr*) Theoretical papers

Anlauf, et al.

Ben-Shaul, et al.

Chester, A. N.

Kapralova, et al.

Moore, C. B.

Parr and Truhlar

Pirkle and McG-ee

Polanyi, J. C.

Raff, et al.

Sentman, L. H.

Sharma, et al.

Shin, H. K.

Shin, H. K.

White, J. M.

JCPSA6-1973-58-5540

CSSPAIM966-20-263

JCPSA6-1970-52-999

J CPS A6-1972-56-331

TFS0A4-1967-63-61

CHPLBC-1968-2-581 (calc. , trans, oroh.)

JCPSA6-1969-50-3641

JCPSA6-1965-43-2979 (calc. , model.

)

JCPS A6-1973-58-3519 ( calc .

)

JPCHAX-1971-75-1079 (calc.)

JCPSA6-1968-49-3964 (r. p.)

JCPSA6-1972-56-5214

JCPSA6-1972-57-1561

JCPSA6-1972-57-5427

JCPSA6-1970-53-3595

CHPLBC-1968-2-581 (c

J CP S A6-1965-^3-2979

JPcHAX-1971-75-1844

J CPS A6-1968-^9-3532

J CPS A6-1959-31-1 338

JCPSA6-1970-53-1606

CHPLBC-1973-18-493 ( J CPS A6-1973-58-3519

JPCHAX-1971-75-1079

J CPS A6-1968-49-3964

J CPS A6-1973-58-4482

(d. r.)

(calc, pop. distr.)

(calc.

)

ale, trans, proo.)

(calc, model.)

calc, pot. sun.;

(calc.,cr. sect.,

pot. _urf.)

(rev.

)

(calc

)

calc. , model.

)

(calc)

(calc

)

(r. p.)

(calc, cr. sec,

nop. distr. , traj .

)

33
Part IV. Hydrogen iodide (HI, DI)

A. Formation of HI*(DI±)

1. Bimolecular Reactions (abstraction lasers)

a. Abstraction of H(D) Atom by I Atom

i. I + H

2 -> HI* + H

Fettis and Knox

Henry, et al.

Parr and Truhlar

Raff, et al.

Truhlar, D. G.

PRKNAZ-1964-2-2 (r. o.

)

CHPLBC-1973-20-138 (r.p.,traj.)

JPCHAX-1971-75-1844 (calc.pot. surf.)

JCPS A6-1970-53-1606 ( calc .

)

JCPSA6-1972-56-3189 (not. surf.)

ii. I + HX -> HI* + X

Anlauf, et al.

iii. I + RH -> HI* + R

Warmer and Wolfrum

b. Abstraction of I Atom by h(D) Atom

i. H + I 0 -> HI* + I

JCPSA6-1969-51-5716

ACIEAY-1971-10-604 (rev.)

Anderson and Kung

Ben-Shaul, et al.

Mayer, et al.

Penzhorn and Darwent

Sullivan, J. H.

ii. H + IX -> HI* +

Ben-Shaul, et al.

Johnson, et al.

JCPSA6-1973-58-2477 (pop. distr. ,traj .

)

JCPSA6-1972-57-5427

SYMCAQ-1967-1 1-837 (r. n.

)

JPCHAX-1968-72-1539 (r. p.)

JCPSA6-1963-39-3001 (r. n.

)

JCPSA6-1972-57-5427 (calc.,non. distr.)

JPCHAX-1973-77-2499 (calc, pot. surf.,

traj.

)

Mayer, et al. SYMCAQ-1967-1 1-837 (r. n.)

B. HI*(DI*) Energy Transfer and Quenching

1. HI*(DI*) Energy Transfer

a. HI(v = 0 ) + M* -> HI*(v > 0) + M ( M ^ HI)

(energy transferred to HI from M*)

Ahl and Cool

Chen, H-L.

Chen and Moore

Chen, et al.

JCPS A6-1973-58-5540

JCPSA6-1971-55-5551

JCPSA6-1971-54-4080

CHPLBC-1968-2-593

34
b. Hlfyv. = m) + M -> HI ( ^(v. < m) + (v. > 0)

l j j i (energy transferred from HI* to M)

Ahl and Cool JCPSA6-1973-58-5540

Breshears and Bird JCPSA6-1971-54-2968

Chen, H-L. J CPS A6-197 1-55-5551

Steohenson, et al. JCPSA6-1972-56-5214

c. HI (v.) + HKvJ -> HI (v.) + HI(v,)(i + j = k + l)

l J & * (HI - HI energy transfer)

Chow and Greene JCPSA6-1965-43-324

Sentman, L. H. CHPLBC-1973-18-493 (calc. , model.

)

2. HI^(DI^) Quenching

a. HI*(v. = m) + M -> KI ( ^(v. < m) + M (v- > 0)

(collisional quenching)

Ahl and Cool

Breshears and Bird

Chen, H-L.

Chow and Greene

Kapralova, et al.

Kiefer, et al.

JCPSA6-1973-58-5540

JCPSA6-1971-54-2968

JCPSA6-1971-55-5551

JCPSA6-1965-43-324

CHPLBC-1968-2-591 (calc. , trans, probj

JCPS A6-1969-50-3641

b. HI*(v. = ) + HI -> HI ( ^(v. < m ) + HI (v, > 0)

(HI - HI self-quenching)

Ahl and Cool

Breshears and Bird

Chen, H-L.

Chow and Greene

Kapralova, et al.

Moore, C. B.

Sentman, L. H.

Shin, H. K,

C. HI^Dfb Theoretical papers

Anderson and Kung

Ben-Shaul, et al.

Henry, et al.

KaBralova, et al.

Moore, C. B.

Sentman, L. H.

Shin, H. K.

JCPSA6-1973-58-5540

JCPSA6-1971-54-2968

JCPSA6-1971-55-5551

JC PS A6-1965-43-324

CHPLBC-1968-2-581 (calc. , trans . Drob.)

J CPSA6-1965-43-2 979

CHPLBC-1973-13-493 (calc. .model.

)

JPCHAX-1971-75-1079

JCPS A6-1 973-58-2477 (pop. distr. , traj .

)

JCPSA6-1972-57-5427 (calc, pop. distr.)

CHPLBC-1973-20-138 (r.p. ,traj .

)

CHPLBC-1968-2-581 (calc. , trans, prob.)

JCPSA6-1965-43-2979

CHPLBC-1973-13-493 (calc. , model.

)

JPCHAX-1971-75-1079

35
r AKT V. KiliVlH-WS Al\iD bJ.hJLlUUrKAl'hlJit)

Arnold and Rojeska

Borrell, P.

Carrington and Garvin

Carrington and Polanyi

Chester, A. N.

Chester and Hess

Cohen, N

Cool, T. A.

Cool, T, A.

Dobratz, B. M.

Dzhidzhoev, M. S.

Emanuel, et al.

Fettis and Knox

Kerber , et al

Komprj , K. L.

Kompa, K. L.

Moore, C. B.

Moore, C. B.

Moore, C. B.

Moore, C. E.

Pimentel, G. C,

Plmentel, G. C.

Rabinovjtch and Flowers

Shuler, et al

,

Wagner and Wolfrum

AFOPAI-I973-I.2-I69

BOOKA7-1969-2-180

CCHKAZ-I969-3-I74

26BMAD-1972-9-135

LSRVAN-1971-7-25.

IEJQA7-1972-8-1

XADRCA-1972-AD 763715

BOOKA7-1971-197

IEJQA7-1973-9-72

XERLAR-1972-UCRL 51285

SPUSBI-1970-13-237

XADRCA-1972-AD 7 4668

PRKNAZ-1964-2-2

IEJQA7-1973-9-94

ACIEAY-1970-9-773

CITEAH-1970-^2-573

ADCPAA-1973-23-41

ARPLAP-1971-22-387

ACHRAY- 19 69-2-10

BOOKA7-1967-133

DAKEAT-1969-50-1

PACHAS-1969-18-275

QRCSAL-1964-18-122

APOSAR-1965-2-8.1

ACIEAY-1971-10-604

36
PART VI. REFERENCES

Ahl, J. L., and Cool, T. A., "Vibrational Relaxation in the

HF-HC1, HF-HBr, HP-HI, and HF-DF Systems," J. Chen.

Phys. 58, 55^0 (1973)

Airey, J . R., "A New Pulsed I-R Chemical Laser," IEEE J.

Quant. Electr. QE-3, 208 (1967)

Airey, J. R., "Report on the International Symposium on

Chemical Lasers, Moscow, September 2-4, 1969," Int.

J. Chem. Kinet. 2, 65 (1970)

Airey, J. R., "CI + HBr Pulsed Chemical Laser: A Theoretical

and Experimental Study," J. Chem. Phys. 52, 156 (1970);

also, see Airey, J. R., "CI + HBr Pulsed Chemical Laser:

A Theoretical and Experimental Study," IEEE J. Quant.

Electr. QE-6, 175 (1970)

Airey, J. R . , Findlay, F. D., and Polanyi, J. C, "The

Hydrogen-Chlorine System in the MM Pressure Range. II.

The Vibrational Ground State Studied by Self-Absorption,"

Can. J. Chem. 4_2, 2193 (1964)

Airey, J. R., and Fried, S. F., "Vibrational Relaxation of

Hydrogen Fluoride," Chem. Phys. Ltrs. 8_, 23 (197D

Airey, J. R., Getty, R. R., Polanyi, J. C, and Snelling, D. R.,

"Absolute Efficiency of Conversion of Heat of the Reaction

H + Cl

2

into Vibration," J. Chem. Phys. 4l, 3255 (1964)

Airey, J. R., and McKay, S. F., "A Supersonic Mixing

Chemical Laser," Appl. Phys. Ltrs. 15, 401 (IO69)

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Muckerman, J. T. , "Classical Dynamics of the Reaction of

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Phys. 56, 3191 (1972)

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2

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," Appl. Opt. 10, 1725 (1971)

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H

2

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68
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69
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?

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71
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, " J. Chem. Phys. 42, 806 (M65)

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2

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2

-* HF + F and D + F

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2326 (1973)

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(1973)

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72
"XBS-I 14A (REV. 7-73)

U.S. DEPT. OF COMM. BIBLIOGRAPHIC DATA

SHEET

1. PUBLICATION OR REPORT NO. NBS SP-3922. Gov't Accession

No.

3. Recipient's Accession No.

4. TITLE AND SUBTITLE

Vibrationally Excited Hydrogen Halides; A Bibliography

on Chemical Kinetics of Chemiexcitation and Energy

Transfer Processes (1958 through 1973)

5. Publication Date April 1974

6. Performing Organization Code

7. AUTHOR(S)

Francis Westley

8. Performing Organ. Report No.

9. PERFORMING ORGANIZATION NAME AND ADDRESS

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

10. Projeet/Task/Work Unit No.

11. Contract /Grant No. AFOSR-ISSA-74-0001-1

12. Sponsoring Organization Name and Complete Address (Street, City, State, ZIP)

NBS Office of Standard Reference Data,

Air Force Office of Scientific Research

1400 Wilson Blvd., Arlington, Va. 22209

13. Type of Report & Period Covered Interim

14. Sponsoring Agency Code

15. SUPPLEMENTARY NOTES

Library of Congress Catalog Card No.: 74-5358

16. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bibliography or literature survey, mention it here.) A bibliography, a reaction oriented list of references, is provided

for published papers and reports containing rate data for reactions of

halogen atoms with hydrogen-containing compounds, or of H (D, or T) atoms

with halogen-containing compounds to form vibrationally chemiexcited

hydrogen halides. The reactions for vibroexcitation of hydrogen halides

through unimolecular or photochemical elimination, as well as the

processes for vibrational energy transfer between hydrogen halides and

various second bodies are also included. In addition, four lists of

theoretical papers and a list of critical reviews and bibliographies are provided. Over 300 papers covering 50 types of reactions are listed.

The period covered extends from 1958 through 1973.

• h io j

17. KEY WORDS (six to twelve entries; alphabetical order; capitalize only the first letter of the first key word unless a proper name; separated by semicolons

)

Bibliography; chemical kinetics; chemiexcitation; gas phase; halogens; hydrogen;

hydrogen halides; laser; quenching; vibrational energy transfer.

18. AVAILABILITY [2^ Unlimited

F °r Off icial Distribution. Do Not Release to NTIS

I

1 Order From Sup. of Doc, U.S. Government Ptip.titvgjO.ffice Washington, D.C. 20402, SD Cat. No. CI 3 • iu • ] Order F rom National Technical Information Service (NTIS)

Springfield, Virginia 22151

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(THIS REPORT)

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21. NO. OF PAGES

81

22. Price $1.30

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scientific and technical activities. National Standard Reference Data Series.

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