***STR EAM D O IV: D ISSO LVED O XYG EN AN D AM M O N IA M O D EL (U SEPA; R egion VIII) 1990 *************** D ischarger(s)/R eceiving W ater: _______________________________________________________________ ~~~EFFLU EN T/TR IBU TAR Y C O N D ITIO N S~~~~~~~~~~~~~~~~~~~~~~ STREAM FLO W TEM P. D .O . CBOD5 O R G -N NH3 N O 2+N O 3 SEGM ENT cfs (C ) m g/l m g/l m g/l-N m g/l-N m g/l-N 1 (TC 02) 0.07 7.500 6.910 212.000 0.150 0.100 0.010 | 2 (TC 03) 0.00 0.000 0.000 0.000 0.000 0.000 0.000 | 3 (TC 04) 0.00 0.000 0.000 0.000 0.000 0.000 0.000 | 4 (TC 06) 0.00 0.000 0.000 0.000 0.000 0.000 0.000 | | A B C D E F G H I*********************************************************************************************************************

______________________________________ ~~~U PSTR EAM C O N D ITIO N S~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ ~~~M IXED C O N D ITIO N S-Beginning of Segm ent~~~~~~~~~ ~~FO R C ED VALU ES~~~~~ TEM PD O addD O add FLO W TEM P. D .O . CBOD5 O R G -N NH3 N O 2+N O 3 FLO W TEM P. D .O . CBOD5O R G -N NH3N O 2+N O 3 add (20C ) (T)

cfs (C ) m g/l m g/l m g/l-N m g/l-N m g/l-N cfs (C ) m g/l m g/l m g/l-Nm g/l-Nm g/l-N (C ) m g/l m g/l 14.68 3.700 11.960 267.000 0.150 0.100 0.360 | 14.75 4.70011.936 266.7410.150 0.100 0.358 | 0.982 0.000 0.000 14.75 4.700 11.109 266.369 0.150 0.100 0.355 | 14.75 4.50011.109 266.3690.150 0.100 0.355 | -0.200 0.000 0.000 14.75 4.500 10.608 266.332 0.150 0.100 0.345 | 14.75 6.80010.608 266.3320.150 0.100 0.345 | 2.300 0.000 0.000 14.75 6.800 9.979 266.272 0.149 0.099 0.325 | 14.75 6.700 9.979 266.2720.149 0.099 0.325 | -0.100 0.000 0.000 | J K L M N O P Q~~~SU M M AR Y IN FO R M ATIO N -End of Segm ent~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ U n-ion. U n-ion. STREAM D ISTAN C ETIM E D .O . NH3 N H 3 StndN H 3 Stnd TO TAL SEGM ENT (cum ul.)(cum ul.) FLO W TEM P.D .O . Stnd. CBOD5 O R G -NNH3 U n-ion.Acute-cw C hron-cw pH N O 2+N O 3 N ITR O G EN m iles hours cfs (C ) m g/l m g/l m g/l m g/l-N m g/l-N m g/l-N m g/l-N m g/l-N s.u. m g/l-Nm g/l-N U pstream Values... 0.000 0.000 14.68 3.70 11.960 5.0 267.000 0.150 0.100 0.000 0.100 0.100 7.16 0.360 0.610 1 (TC 02) 1.000 0.95 14.75 4.70 11.109 5.0 266.369 0.150 0.100 0.000 0.100 0.100 7.33 0.355 0.605 2 (TC 03) 2.000 2.38 14.75 4.50 10.608 5.0 266.332 0.150 0.100 0.001 0.100 0.100 7.63 0.345 0.594 3 (TC 04) 3.000 4.09 14.75 6.80 9.979 5.0 266.272 0.149 0.099 0.000 0.100 0.100 5.30 0.325 0.574 4 (TC 06) 4.000 4.98 14.75 6.70 9.421 5.0 265.732 0.149 0.099 0.000 0.100 0.100 6.18 0.316 0.564~~~O BSER VED VALU ES-End of Segm ent~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ (M in.) (M ax.) (M in.) (M ax.) (M in.) (M ax.) (M in.) (M ax.) N FLO W TEM P. D .O . D .O . D .O . CBOD5CBOD5CBOD5 NH3 NH3 NH3 N O 2+N O 3N O 2+N O 3N O 2+N O 3pH cfs (C ) m g/l m g/l m g/l m g/l m g/l m g/l m g/l-N m g/l-N m g/l-N m g/l-N m g/l-N m g/l-N s.u. U pstream Values 0.00 0.00 0.00 1 (TC 02) 20.1894.700 ###### 433.00 0.10 0.37 7.33 2 (TC 03) 10.1194.500 ###### 422.00 0.10 0.38 7.63 3 (TC 04) 11.557 6.800 ###### 471.00 0.10 0.26 5.30 4 (TC 06) 11.976 6.700 9.000 330.00 0.10 0.11 6.18~~~~~~~~~~~ (M in.) (M ax.) pH pH

s.u. s.u.~~~D ISSO LVED O XYG EN IN PU TS~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ C BO D ult/ N O D ult/ D O D O CBOD5 NH3 STREAM SAT.SAT-ELEVELEVc C BO D ultR ATIO N O D ult R ATIOT-20 SEGM ENT m g/l m g/l m g/l m g/l (C ) 1 (TC 02) 12.892 10.494 0.814357.297 1.339 0.457 4.570 -15.300 | 2 (TC 03) 12.961 10.550 0.814427.957 1.607 0.456 4.570 -15.500 | 3 (TC 04) 12.208 9.937 0.814460.285 1.728 0.456 4.570 -13.200 | 4 (TC 06) 12.239 9.962 0.814368.747 1.385 0.454 4.570 -13.300 |~~~R ATE C O EFFIC IEN TS (Base e)~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ CBOD REAER. NH3 O R G -N NH3 N O 2+N O 3 BEN TH IC C O EFF. C O EFF. C O EFF. C O EFF. LO SS LO SS DEM AND (K1)20(K1)T (K2)20 (K2)T (K3)20(K3)T (K4)20(K4)T (K5)20(K5)T (K6)20 (K6)T (S)20 (S)T 1/day 1/day 1/day 1/day 1/day 1/day 1/day 1/day 1/day 1/day 1/day 1/daygm /m 2/daygm /m 2/day 0.300 0.035 15.300 10.644 0.200 0.062 0.069 0.028 0.023 0.011 0.500 0.255 0.100 0.038 0.020 0.002 15.300 10.594 0.200 0.061 0.069 0.028 0.023 0.011 1.000 0.505 0.100 0.038 0.020 0.003 15.300 11.187 0.200 0.072 0.069 0.032 0.023 0.013 1.500 0.839 0.100 0.044 0.350 0.055 15.300 11.161 0.200 0.072 0.069 0.032 0.023 0.012 1.500 0.835 0.100 0.043~~~D O D EFIC IT C O M PO N EN TS~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ ~~~U N -IO N IZED AM M O N IA C ALC U LA U pstream D o Initial-pH IN ITIAL P R TO TAL D .O . 7.160 pH STREAM D EFIC ITD EFo D EFC BO DD EFN O DD EFSO DD ELTAD OPHO TO S.C H LO R aRESP.D EF(P/R )D EFIC IT FIN AL pH Factor pKa SEGM ENT m g/l m g/l m g/l m g/l m g/l m g/l m g/l/day ug/l m g/l/day m g/l m g/l m g/l s.u. s.u./hr 1 (TC 02) -1.442 -0.947 0.407 0.001 0.005 1.250 2.500 1.100 0.026 -0.080 -0.614 11.109 | 7.330 0.179 9.914 2 (TC 03) 0.000 0.000 0.043 0.001 0.008 1.250 2.500 0.050 0.001 -0.110 -0.058 10.608 | 7.630 0.210 9.921 3 (TC 04) 0.000 0.000 0.072 0.002 0.007 1.250 2.500 0.200 0.005 -0.123 -0.042 9.979 | 5.300 -1.360 9.840 4 (TC 06) 0.000 0.000 0.612 0.001 0.004 1.250 2.500 1.200 0.029 -0.075 0.541 9.421 | 6.180 0.985 9.843ATIO N S~~~~~~~~~~~~~~~~~~~~~~~~~~~ U n-ion. U n-ion. NH3 N H 3 StndN H 3 Stnd NH3 U n-ion.Acute-cw C hron-cw

m g/l-N m g/l-Nm g/l-N m g/l-N

0.100 0.000 0.100 0.100 0.100 0.001 0.100 0.100 0.099 0.000 0.100 0.100 0.099 0.000 0.100 0.100~~~H YD R AU LIC IN PU T~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ D epth C onstants Velocity C onstants (optional) (optional) SEGM ENTTRAVEL STREAM DEPTH alpha beta VELO C ITYa b SLO PELEN G THTIM E SEGM ENT feet ft/sec ft/ft m iles days 1 (TC 02) 0.870 1.547 1.0000 0.0395 2 (TC 03) 0.719 1.027 1.0000 0.0595 3 (TC 04) 0.964 0.856 1.0000 0.0714 4 (TC 06) 1.217 1.641 1.0000 0.0372~~~TEM PER ATU R E AD JU STM EN T C O EFFIC IEN TS~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ The following coefficients are used in conjunction with the rate coefficients. By inputting new values in the m atrix below, the m odel will autom atically adjust. K1 K2 K3 K4 K5 K6 S CBOD R eaer. NH3 O rg-N N H 3 LossN O 2+N O 3Benthic {theta} {theta} {theta} {theta} {theta} {theta} {theta} 1.150 1.024 1.080 1.060 1.047 1.045 1.065 1.150 1.024 1.080 1.060 1.047 1.045 1.065 1.150 1.024 1.080 1.060 1.047 1.045 1.065 1.150 1.024 1.080 1.060 1.047 1.045 1.065~~~IN TER IM C ALC U LATIO N S~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ The following are interim calculations extracted from the m odel. They are displayed to assist in m odel diagnostics and debugging. ~~~(R ate coefficients) x (tim e)~~~~~~~~~~~~~~~~ K1(t) K2(t) K3(t) K4(t) K5(t) K6(t)CBODK1CBODK2NODK3NODK2

0.0014 0.4204 0.0024 0.0011 0.0004 0.0101 1.1891 0.7821 0.0027 0.0017 0.0001 0.6302 0.0036 0.0017 0.0007 0.0301 0.0926 0.0493 0.0026 0.0014 0.0002 0.7985 0.0052 0.0023 0.0009 0.0599 0.1301 0.0585 0.0030 0.0013 0.0020 0.4156 0.0027 0.0012 0.0005 0.0311 1.8074 1.1953 0.0029 0.0019

## 0.000 50.000 100.000 150.000 200.000 250.000 300.000 350.000 400.000 450.000 500.000

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500CBOD5 (mg/l)



## Distance (miles) CBOD5 PROFILE

Predicted Observed (avg.) Observed (min.) Observed (max.)

## 0.000 2.000 4.000 6.000 8.000 10.000 12.000 14.000

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500Dissolved Oxygen (mg/l)



## Distance (miles) DISSOLVED OXYGEN PROFILE

Predicted Observed (avg.) Observed (min.) Observed (max.)

## 0.000 0.000 0.000 0.000 0.000 0.001 0.001

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500Un-ionized Ammonia (mg/l-N)



## Distance (miles) UN-IONIZED AMMONIA PROFILE

Predicted

## 0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500Temperature (oC)



## Distance (miles) TEMPERATURE PROFILE

Observed (avg.) Predicted

## 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500pH (s.u.)



## Distance (miles) pH PROFILE

Predicted Observed (avg.) Observed (min.) Observed (max.)

## 0.000 0.050 0.100 0.150 0.200 0.250 0.300 0.350 0.400

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500NO2 + NO3 (mg/l-N)



## Distance (miles) NITRITE + NITRATE PROFILE

Predicted Observed (avg.) Observed (min.) Observed (max.)

## 0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500Nitrogen (mg/l-N)



## Distance (miles) TOTAL NITROGEN PROFILE

Total N Ammonia Organic N NO2+NO3

## 0.00 5.00 10.00 15.00 20.00 25.00

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500Flow (cfs)



## Distance (miles) FLOW PROFILE

Predicted Observed (avg.)

## 0.000 0.020 0.040 0.060 0.080 0.100 0.120

0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500Total Ammonia (mg/l-N)



## Distance (miles) AMMONIA PROFILE

Predicted Observed (avg.) Observed (min.) Observed (max.)