### Name: David M. Fraley, Ph.D.

Title: Director - Environmental Affairs Company: City Utilities of Springfield Sign Date: 9/30/2010 Name: Mike Taylor Title: President Company: Catalyst Air Management Sign Date: 9/30/2010 Permitted Facility Representative / Date Testing Company Representative / Date 

## MO2161 James River 4 Final Test Report for

/ / Based on information and belief formed after reasonable inquiry, I certify that the statements and information in this test report are true, accurate, and complete. I have reviewed all testing details and results in this test report and hereby certify that the test report is authentic and accurate.

Saturday, January 29, 2011 Page 1 of 14

### MO2161 James River 4
9/30/2010 Facility Information:
MO2161 James River 4
5701 South Kissick Rd

Springfield MO 65804 Contact: Daniel Hedrick Phone: 417-831-8916 Fax: Email: daniel.hedrick@cityutilities.net Testing Company: Catalyst Air Management 2505 ByingRdton-Solway

Knoxville TN 37931 Contact: Mike Taylor Phone: 865-531-0075 Fax: 865-531-0750 Email: mike.taylor@catalystair.com

Air Permit Number: 2161 Permitted Source ID/Name: City Utilities of Springfield James River Station 4 Permitted Maximum Process Rate: Max. Normal Operation Process Rate: Target Process Test Rate

Description of the source (including control equipment). Please see the attachments for source or process flow diagram: Industry/SCC/NAIS 221112

Sampling Location Information:

Test Parameter Information: AFS #: FRS #:

SCC / Description 10100222 External Combustion Boilers - Electric Generation - Bituminous/Subbituminous Coal - Pulverized Coal: Dry Bottom (Subbituminous Coal)

The following state and federal regulations that apply to the proposed testing:

Location Round

Duct Diam. Distance from upstream dist. Distance from

downstream dist. Number of

Traverse Ports Equiv. Diam Min.Travers Points Rect. Duct Length /Width MO2161 JR4 144 0 0 4 0 16 0 0

Target Parameter Test Method Number of

Test Runs Test Run

Duration Sample

Points Comments Location Carbon Monoxide Method 10 3 120 0 MO2161 JR4 Total organic compounds

(TOC) as Propane Method 25A 3 120 0 MO2161 JR4

Total PM2.5 OTM - 27/28 3 330 0 MO2161 JR4 Organic Condensible

Particulate OTM - 27/28 3 330 0 MO2161 JR4
Inorganic (Aqueous)

Condensible Part. OTM - 27/28 3 330 0 MO2161 JR4



### Saturday, January 29, 2011 Page 2 of 14

### MO2161 James River 4
9/30/2010

The following describes any modifications and/or deviations to the applicable test methods. If alternative methods were requested, see the attachments for documentation of request AND approval, including dates.

Filterable PM2.5 OTM - 27/28 3 330 0 MO2161 JR4 Filterable Particulate Method 29 3 240 0 MO2161 JR4 Selenium Method 29 3 240 0 MO2161 JR4 Nickel Method 29 3 240 0 MO2161 JR4 Manganese Method 29 3 240 0 MO2161 JR4 Antimony Method 29 3 240 0 MO2161 JR4 Arsenic Method 29 3 240 0 MO2161 JR4 Cobalt Method 29 3 240 0 MO2161 JR4 Chromium Method 29 3 240 0 MO2161 JR4 Beryllium Method 29 3 240 0 MO2161 JR4 Cadmium Method 29 3 240 0 MO2161 JR4 Mercury Method 29 3 240 0 MO2161 JR4 Lead Method 29 3 240 0 MO2161 JR4



### Saturday, January 29, 2011 Page 3 of 14

### MO2161 James River 4
9/30/2010 Sampling / Stack Data Results Summary



### Location MO2161 JR4 - Method 10 Average Run Number
Test Date Run Start Time
Run Finish Time Carbon Dioxide, % Oxygen, % Dry Volumetric Flow Rate, dry scfm F-Factor, dscfm/MMBtu @ %O2 Moisture, % Fuel Type
Fw
Fc



### Location MO2161 JR4 - Method 25A Average Run Number
Test Date Run Start Time
Run Finish Time Carbon Dioxide, % Oxygen, % Dry Volumetric Flow Rate, dry scfm F-Factor, dscfm/MMBtu @ %O2 Moisture, % Fuel Type
Fw
Fc



### Saturday, January 29, 2011 Page 4 of 14

### MO2161 James River 4
9/30/2010
Location MO2161 JR4 - Method 29 Average Run Number M29-1 M29-2 M29-4
Test Date 6/22/2010 6/23/2010 6/24/2010 Run Start Time 11:15:00 AM 6:00:00 AM 11:43:00 AM

Run Finish Time 3:07:30 PM 9:52:30 AM 3:35:30 PM

Net Run Time, minutes 240 240 240 Dry Gas Meter Volume Sampled, dscf 129.545 128.815 129.206 129.189 Moisture Content of Stack Gas, % 13.62 15.16 13.68 14.153 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Carbon Dioxide, % 12.1 12.3 12.7 12.367 Oxygen, % 7.4 7.2 7 7.200 Average Stack Gas Temperature, °F 329.78 313.44 313.06 318.760 Dry Volumetric Flow Rate, dry scfm 146,751.7 144,006.3 148,982.6 146,580.200 Actual Wet Volumetric Flue Gas Flow Rate, acfm 265,664.9 260,846.9 263,900.5 263,470.767 Percent Isokinetic of Sampling Rate, % 100.9 102.2 99.1 100.733 F-Factor, dscfm/MMBtu @ %O2 9780 9780 9780 9,780.000
Fw 10640 10640 10640 10,640.000
Fc 1800 1800 1800 1,800.000



### Location MO2161 JR4 - OTM - 27/28 Average Run Number
Test Date Run Start Time
Run Finish Time Net Run Time, minutes Dry Gas Meter Volume Sampled, dscf Moisture Content of Stack Gas, % Moisture Saturation at Stack Gas Temperature, % Carbon Dioxide, % Oxygen, % Average Stack Gas Temperature, °F Dry Volumetric Flow Rate, dry scfm Actual Wet Volumetric Flue Gas Flow Rate, acfm Percent Isokinetic of Sampling Rate, % F-Factor, dscfm/MMBtu @ %O2
Fw
Fc



### Saturday, January 29, 2011 Page 5 of 14

### MO2161 James River 4
9/30/2010

Saturday, January 29, 2011 Page 6 of 14

### MO2161 James River 4
9/30/2010 Emissions Summary



### Location: MO2161 JR4 - Method 10 Compound: Carbon Monoxide Average Run M10-1 M10-2 M10-3 lb/mmBtuO2 1.16E-01 1.79E-01 1.50E-01 0.148 ppm 1.07E+02 1.66E+02 1.41E+02 138.000 ppm@7%O2 1.08E+02 1.67E+02 1.40E+02 138.333



### Location: MO2161 JR4 - Method 25A Compound: Total organic compounds (TOC) as Average Run M25A-1 M25A-2 M25A-3 lb/mmBtuO2 5.85E-05 1.76E-04 1.45E-04 0.000 ppm 3.45E-02 1.04E-01 8.69E-02 0.075 ppm@7%O2 3.48E-02 1.05E-01 8.63E-02 0.075



### Location: MO2161 JR4 - Method 29 Compound: Antimony Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.0048 0.0028 0.0028 0.003 lb/mmBtuO2 1.24E-06 7.15E-07 7.03E-07 0.000 

### Compound: Arsenic Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.01115 0.00688 0.00631 0.008 lb/mmBtuO2 2.87E-06 1.76E-06 1.58E-06 0.000 

### Compound: Beryllium Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.00146 0.00087 0.00078 0.001 lb/mmBtuO2 3.76E-07 2.22E-07 1.96E-07 0.000 

### Compound: Cadmium Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.00506 0.00101 0.00095 0.002 lb/mmBtuO2 1.30E-06 2.58E-07 2.38E-07 0.000 

### Compound: Chromium Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.20539 1.4984 0.12474 0.610 lb/mmBtuO2 5.29E-05 3.83E-04 3.13E-05 0.000 

### Compound: Cobalt Average RunNumber M29-1 M29-2 M29-4



### Saturday, January 29, 2011 Page 7 of 14

### MO2161 James River 4
9/30/2010 Mass_mg 0.01355 0.03877 0.0059 0.019 lb/mmBtuO2 3.49E-06 9.90E-06 1.48E-06 0.000 

### Compound: Filterable Particulate Average RunNumber M29-1 M29-2 M29-4 Mass_mg 62.4 83.4 83.4 76.400 lb/mmBtuO2 1.61E-02 2.13E-02 2.09E-02 0.019 

### Compound: Lead Average RunNumber M29-1 M29-2 M29-4 Mass_mg 32.51279 0.02139 0.19259 10.909 lb/mmBtuO2 8.38E-03 5.46E-06 4.83E-05 0.003 

### Compound: Manganese Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.10225 0.30655 0.04035 0.150 lb/mmBtuO2 2.63E-05 7.83E-05 1.01E-05 0.000 

### Compound: Mercury Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.01074 0.01091 0.01044 0.011 lb/mmBtuO2 2.77E-06 2.79E-06 2.62E-06 0.000 

### Compound: Nickel Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.42278 1.79288 0.18198 0.799 lb/mmBtuO2 1.09E-04 4.58E-04 4.57E-05 0.000 

### Compound: Selenium Average RunNumber M29-1 M29-2 M29-4 Mass_mg 0.0222 0.0385 0.0171 0.026 lb/mmBtuO2 5.72E-06 9.83E-06 4.29E-06 0.000



### Location: MO2161 JR4 - OTM - 27/28 

### Compound: Filterable PM2.5 Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 46.8 64.3 45.6 52.233 lb/mmBtuO2 1.33E-02 1.76E-02 1.25E-02 0.014 

### Compound: Inorganic (Aqueous) Condensible Pa Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 94 97 78 89.667 lb/mmBtuO2 2.66E-02 2.66E-02 2.14E-02 0.025



### Saturday, January 29, 2011 Page 8 of 14

### MO2161 James River 4
9/30/2010

Process Run Data Compound: Organic Condensible Particulate Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 4.9 3.5 4.7 4.367 lb/mmBtuO2 1.39E-03 9.59E-04 1.29E-03 0.001 

### Compound: Total PM2.5 Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 145.7 164.8 128.3 146.267 lb/mmBtuO2 4.13E-02 4.52E-02 3.53E-02 0.041



### Saturday, January 29, 2011 Page 9 of 14

### MO2161 James River 4
9/30/2010 Process Run Data

APCD Run Data

Process Lab Run Data 

### Run Name Value UOM Comments Target Value 1 Heat Input 536.5 Million Btus/million BTU using O2 Daily Average (6- 22-10) 0



### 2 Heat Input 541.6 Million Btus/million BTU using O2 Daily Average (6- 23-10) 0

3 Heat Input 540 Million Btus/million BTU using O2 Daily Average (6- 24-10) 0



### 1 Unit Load 55.5 MW Daily Average (6- 22-10) 0

2 Unit Load 56.6 MW Daily Average (6- 23-10) 0

3 Unit Load 56.6 MW Daily Average (6- 24-10) 0



### 1 Steam Rate 415.1 1000 lbs/hr Daily Average (6- 22-10) 0

2 Steam Rate 429.9 1000 lbs/hr Daily Average (6- 23-10) 0



### 3 Steam Rate 428.3 1000 lbs/hr Daily Average (6- 24-10) 0

1 Fuel Rate 31.7 tons/hr Daily Average (6- 22-10) 0



### 2 Fuel Rate 32 tons/hr Daily Average (6- 23-10) 0

3 Fuel Rate 32 tons/hr Daily Average (6- 24-10) 0

Run Name Value UOM Comments Target Value 

### 1 OVERFIRE AIR 0 0
1 NSCR (NON-SELECTIVE CATALYTIC REDUCTION) 0 0



### 1 ELECTROSTATIC PRECIPITATOR 0 0

Saturday, January 29, 2011 Page 10 of 14

### MO2161 James River 4
9/30/2010 Sampling / Stack Data Results Detail



### Location MO2161 JR4 - Method 10 Average Run Number Test Date Run Start Time Run Finish Time Carbon Dioxide, % Oxygen, % Fuel Factor Dry Volumetric Flow Rate, dry scfm F-Factor, dscfm/MMBtu @ %O2 Moisture, % Analyzer Make Analyzer Model Analyzer Serial Number Operating Range Operating Units No. Readings/Avg. Calibration Set Calibration Pre Zero Cylinder ID Calibration Pre Zero Cylinder Instrument Response Calibration Pre Zero Cylinder Bias Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID Calibration Pre High Cylinder Instrument Response Calibration Pre High Cylinder Bias Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID Calibration Post Zero Cylinder Instrument Response Calibration Post Zero Cylinder Bias Calibration Post Zero Cylinder Drift Calibration Post High Cylinder ID Calibration Post High Cylinder Instrument Response Calibration Post High Cylinder Bias Calibration Post High Cylinder Drift Cavg Cavg Units Cgas Cgas Units Fuel Type Fw Fc Cgasw Cgasw Units



### Saturday, January 29, 2011 Page 11 of 14

### MO2161 James River 4
9/30/2010
Location MO2161 JR4 - Method 25A Average Run Number Test Date Run Start Time Run Finish Time Carbon Dioxide, % Oxygen, % Fuel Factor Dry Volumetric Flow Rate, dry scfm F-Factor, dscfm/MMBtu @ %O2 Moisture, % Analyzer Make Analyzer Model Analyzer Serial Number Operating Range Operating Units No. Readings/Avg. Calibration Set Calibration Pre Zero Cylinder ID Calibration Pre Zero Cylinder Instrument Response Calibration Pre Zero Cylinder Bias Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID Calibration Pre High Cylinder Instrument Response Calibration Pre High Cylinder Bias Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID Calibration Post Zero Cylinder Instrument Response Calibration Post Zero Cylinder Bias Calibration Post Zero Cylinder Drift Calibration Post High Cylinder ID Calibration Post High Cylinder Instrument Response Calibration Post High Cylinder Bias Calibration Post High Cylinder Drift Cavg Cavg Units Cgas Cgas Units Fuel Type Fw Fc Cgasw Cgasw Units



### Saturday, January 29, 2011 Page 12 of 14

### MO2161 James River 4
9/30/2010
Location MO2161 JR4 - Method 29 Average Run Number M29-1 M29-2 M29-4 Test Date 6/22/2010 6/23/2010 6/24/2010 Run Start Time 11:15:00 AM 6:00:00 AM 11:43:00 AM Run Finish Time 3:07:30 PM 9:52:30 AM 3:35:30 PM Net Traversing Points 32 32 32 Net Run Time, minutes 240 240 240 Nozzle Diameter, inches 0.275 0.275 0.275 0.275 Pitot Tube Coefficient 0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor 0.99 0.99 1.01 0.997 Barometric Pressure, inches of Mercury 28.65 28.55 28.68 28.627 Average Orifice Meter Differential, inches H2O 0.93 0.91 0.95 0.930 Dry Gas Meter Volume Sampled, cubic feet 144.780 141.944 139.856 142.193 Average Dry Gas Meter Temperature, °F 100.73 90.91 94.66 95.433 Dry Gas Meter Volume Sampled, dscf 129.545 128.815 129.206 129.189 Total Moisture Liquid collected, g 434 489 435 452.667 Volume of Water Vapor, standard cubic feet 20.43 23.02 20.48 21.310 Moisture Content of Stack Gas, % 13.62 15.16 13.68 14.153 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Dry Mole Fraction 0.8638 0.8484 0.8632 0.858 Carbon Dioxide, % 12.1 12.3 12.7 12.367 Oxygen, % 7.4 7.2 7 7.200 Carbon Monoxide & Nitrogen, % 80.5 80.5 80.3 80.433 Fuel Factor 1.12 1.11 1.09 Dry Molecular Weight, lb/lb-Mole 30.23 30.26 30.31 30.267 Wet Molecular weight, lb/lb-Mole 28.56 28.40 28.63 28.530 Flue Gas Static Pressure, inches of H2O -0.35 -0.35 -0.35 -0.350 Absolute Flue Gas Pressure, inches of Mercury 28.62 28.52 28.65 28.597 Average Stack Gas Temperature, °F 329.78 313.44 313.06 318.760 Average Velocity Head, inches of H2O 0.3075404436 33086 0.299997101

221617 0.311239203

777391 0.306
Average Stack Gas Velocity, feet/second 39.15 38.44 38.89 38.827 Stack Cross-Sectional Area, square feet 113.097 113.097 113.097 113.097 Dry Volumetric Flow Rate, dry scfm 146,751.7 144,006.3 148,982.6 146,580.200 Actual Wet Volumetric Flue Gas Flow Rate, acfm 265,664.9 260,846.9 263,900.5 263,470.767 Percent Isokinetic of Sampling Rate, % 100.9 102.2 99.1 100.733 Percent Excess Air, % 53.4 51.2 49.3 51.300 F-Factor, dscfm/MMBtu @ %O2 9780 9780 9780 9,780.000 Round Duct Diameter, inches 144 144 144 Rectangular Duct Width, inches 0 0 0 Rectangular Duct Length, inches 0 0 0 Fw 10640 10640 10640 10,640.000 Fc 1800 1800 1800 1,800.000



### Saturday, January 29, 2011 Page 13 of 14

### MO2161 James River 4
9/30/2010
Location MO2161 JR4 - OTM - 27/28 Average Run Number Test Date Run Start Time Run Finish Time Net Traversing Points Net Run Time, minutes Nozzle Diameter, inches Pitot Tube Coefficient Dry Gas Meter Calibration Factor Barometric Pressure, inches of Mercury Average Orifice Meter Differential, inches H2O Dry Gas Meter Volume Sampled, cubic feet Average Dry Gas Meter Temperature, °F Dry Gas Meter Volume Sampled, dscf Total Moisture Liquid collected, g Volume of Water Vapor, standard cubic feet Moisture Content of Stack Gas, % Moisture Saturation at Stack Gas Temperature, % Dry Mole Fraction Carbon Dioxide, % Oxygen, % Carbon Monoxide & Nitrogen, % Fuel Factor Dry Molecular Weight, lb/lb-Mole Wet Molecular weight, lb/lb-Mole Flue Gas Static Pressure, inches of H2O Absolute Flue Gas Pressure, inches of Mercury Average Stack Gas Temperature, °F Average Velocity Head, inches of H2O Average Stack Gas Velocity, feet/second Stack Cross-Sectional Area, square feet Dry Volumetric Flow Rate, dry scfm Actual Wet Volumetric Flue Gas Flow Rate, acfm Percent Isokinetic of Sampling Rate, % Percent Excess Air, % F-Factor, dscfm/MMBtu @ %O2 Round Duct Diameter, inches Rectangular Duct Width, inches Rectangular Duct Length, inches Fw Fc



### Saturday, January 29, 2011 Page 14 of 14