**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 1 of 13 

# SignaFresh  **10EC**

***** **Ac tive Ingredient:**  Lysophosphatidylethanolamine (LPE)
..................... 10 .00 % **Other Ingredients:**
................................ ................. 90 .00 % **Total**
................................ ................................ .... 100 .00 % Contains 0.751 pounds LPE per gallon **KEEP OUT OF REA CH OF CHILDREN** 



## CA**UTION** See (side) (back) panel for first aid and additional precautionary statements. EPA Reg. No.: (Pending as file symbol 73562 - E ) EPA Est. No.: XXXXX-XX-X Manufactured by : DOOSAN Corporation, Glonet BU Biotech Research Institute 864 B/5F, Aict, 864- 1, Iui -dong, Yeongtong -gu, Suwon -si, G ye onggi -d o, Korea

Net Contents: XX Batch/Lot Number: XX**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 2 of 13 **FIRST A ID**  **If on skin or clothing**  ● Ta ke off contaminated clothing.

● Rinse skin immediately with plenty of water for 15 - 20 minutes. ● Call a poison control center or doctor for treatment advice. **If in eyes**  ● Hold eye open and rinse slowly and gently with water for 15 -20 minutes.

● Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. ● Call a poison control center or doctor for treatment advice. **HOT LINE NUMBER** Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1 - 800 -222 - 1222 for emergency medical treatment information. **(Precautionary Statements for uses covered by the Worker Protection Standard)**  **PRECA UTIONA** **RY STA TEMENTS**  **HA ZA** **RDS TO HUM ANS**  **AND DOMESTIC A NIM**  **AL S** 

**CA UTION**  Causes moderate eye irritation. Avoid contact with eyes , skin or clothing. W ash thoroughly with soap and water after handling and before eating, drinking, chew ing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse. Prolonged or frequently repeated skin contact may

cause allergic reactions in some individuals. **PERSONA L**  **PROTECTIVE EQUIPMENT**  **(PPE)** : Applicators an d other handlers mu st wear coveralls worn over short-sleeved shirt and short pants, chemical resistant (such as nitrile or butyl) gloves, and shoes plus socks. F ollow ma nufacturer’s instructions for cleaning / ma intaining PPE. Keep and wash PPE separatel y from other laundry. **User Safety Recommendations:** Users should remove clothing immediately if pesticide gets inside. T hen wash thoroughly and put on clean clothing. U sers should remove PPE immediately after handling this product. As soon as possible , wash thoroughly and change into clean clothing. **Environmental Hazards:** Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the me an highwater ma rk
. D o not contaminate water when cleaning equipment or disposing of equipment washwaters or rinsate. **Physical or Chemical Hazards: Combustible.** Do not use or store near heat or open flame. **(Precautionary Statements for uses not**  **covered by the Worker Protection Standard) PRECA** **UTIONA RY STA**  **TEMENTS HA**  **ZA RDS**  **TO HUM ANS**  **AND DOMESTIC A NIM**  **AL S** 

**CA UTION**  Causes moderate eye irritation. Avoid contact with eyes , skin or clothing. W ash thoroughly with soap and water after handling and before eating, drinking, chewing gum , using tobacco or using the toilet
. Remove con taminated clothing and wash clothing before reuse. Prolonged or frequently repeated skin contact may

cause allergic reactions in some individuals. **Environmental Hazards:** Do not apply directly to water, or to areas where surface water is present, or to in tertidal areas below the me an highwater ma rk
. D o not contaminate water when cleaning equipment or disposing of equipment washwaters or rinsate. **Physical or Chemical Hazards: Combustible.** Do not use or store near heat or open flame.**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 3 of 13**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 4 of 13 

### (Directions for **Use for uses covered by the Worker Protection Standard) DIRECTIONS FOR USE**  It is a violation of

F ederal law to use this product in a manner inconsistent with its labeling. F or any requirements specific to your State or Tribe, consult the State or Tribal agency responsible for pesticide regulation. D o not apply this product in a way that will contact workers or other persons, either directly or thorough drif t. O nly protected handlers may be in the area during application. **Ag ricultural Use Requirements**  U se this product only in accordance with its labeling and with the Wo rker Protection Standard, 40 CFR Part 170. This standard contains requirements for the protection of agricultural workers on farms, forests, nurseries and greenhouses, and handlers of agricultural pesticides. I t contains requirements for training, decontamination, notification, and emergency assistance. I t also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PP E), and restricted entry intervals (REI). T he requirements in this box only apply to uses of this product that are covered by the Wo rker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval of 4 hours. PPE requirement for early entry to treated areas that is permitted under the Wo rker Protection Standard and that involves contact with anything that has been treated, such as plants, soil or water, is coveralls, waterproof gloves and shoes plus so cks.
**(Directions for Use for uses not**  **covered by the Worker Protection Standard) DIRECTIONS FOR USE**  It is a violation of Federal law to apply this product in a manner inconsistent with its labeling. **Non -** **Ag ricultural Use Requirements**  The requirements in this box apply to uses of t his product that are **not** within the scope of the Wo rker Protection Standard fo r agricultural pesticides (40 CFR Part 170). T he WP S applies when this product is used to produce agricultural plants on fa rms, forests, nurseries or greenhouses. Keep unprotected persons out of treated areas until sprays have dried or dusts have settled. For post- harvest treated commodities, unprotected persons should not handle until dip has dried.**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 5 of 13 

### General: SignaFresh  10EC is a growth regulator that enhances fruit quality, ripening and shelf life of select fruits, flowers and vegetables. SignaFresh  10EC application does not enhance respiration, like other ripening agents. SignaFresh  10EC is also known to reduce senescence by inhibiting so me of enzymes involved in membrane breakdown. F or these reasons, SignaFresh  10EC enhances and promotes shelf life. Wh en applied to physiologically mature fruit (at breaker stage, i.e. early stage of ripening), it stimulates and promotes ripening. READ ENTIRE LABEL BEFORE USING THIS PRODUCT. **DIRECTIONS FOR USE: SPECIFIED TREA TMENTS**  **Mixing Instructions:** Shake well (1 - 3 minutes) before mixing. S ee Pre Harvest Application table below for the application rate (amount of SignaFresh  10EC fl. oz./acre) spec ific to your crop. Dilute product with the amount of

water necessary to treat the intended area. Add half t he water to tank, then add SignaFresh  10EC. Add remaining water and mix thoroughly. **Pre -**  **Harvest A pplication Directions:**  Apply SignaFresh  10E C in water to wet fruit uniformly, using conventional ground or aerial application equipment. F or better coverage, use a sticker deposition agent. Contact your Nutra - Park Representative for guidance on surfactant or adjuvant selection and use. Do not u se with organo-silicone surfactants and use antifoam agents sparingly. Apply SignaFresh  10EC approximately two weeks prior to harvest, unless noted otherwise under “Special Instructions” on the following table. Follow directions for specific crop listed below:**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 6 of 13 

### PRE HA**RVEST AP**  **PLICATION Crop**  **Rate in oz/acre Use**  **Special Instructions Fruiting Vegetables**  **Eggplants** 8 - 30  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality **Tomatoes** Vine Ripe Field

**Tomatoes** Vine Ripe Greenhouse

**Tomatoes** Processing 8 - 30

2 - 4

15 - 45  Increased early

ma rketable yield  Uniform color development  Improved fruit firmness  Apply 10 to 14 days prior to desired use response.  Reapply at 14 -day intervals until final harvest.

 Apply 7 to 10 days prior to desired use response.  Reapply at 7 to 14 day intervals until final harvest.

 Apply approximately two weeks prior to harvest. **Pep pers** 

Red Peppers Hot Peppers

Green Peppers 27

27  Accelerated fruit

ripening  Increased early ma rketable yield  Uniform color development*  Improved fruit quality  Apply at 10 to 20% color break.

 Apply two to three weeks before harvest.

**Pimentos** 8
– 30  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 7 of 13 **Cucurbits Me**  **lons Squash**  **Pu mpkins**  15 - 45  Increased early ma rketable yield  Accelerated fruit ripening  Improved fruit quality **Berries/Small Fruits Raspberries**  **Boysenberries Blackberries**  **Blueberries** 8
– 30  Increased early ma rketable yield  Accelerated fruit ripening  Uniform co lor development  Improved fruit quality **Cranberries**

For tank- mixing with chlorothalonil fungicides 8
– 30

8
– 30  Increased early

ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality

 Decrease t he phytotoxic effect of chlorothalonil containing fungicides  Can be applied through irrigation systems. Consult yo ur Nutra - Park representative for use guidance.

 Apply in tank mixture with the chlorothalonil fungicide. Consult the fungicide label for a ppropriate rate and tim ing of application. **Currants** 8
– 30  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality **Strawberries** 6 - 25  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality  Apply 7 to 10 days prior to desired use response.  Reapply at 7 to 14 day intervals until final harvest.**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 8 of 13 **Tree Fruits Av** **ocados** 8
– 30  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality **Citrus** Grapefruits, Mineolas, Lemons, Limes, Mandarins, Oranges, Pummelos, Tangelos and Tangerines 27  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality

 Improved fruit and rind quality  Apply two to three weeks before to harvest.

 Apply four to six weeks before harvest

**Pome Fruits** Apples

Crabapples and Pears 27

27  Increased early

ma rketable yield  Accelerated fruit ripening  Uniform color development*  Improved fruit quality  Apply five to six weeks before harvest.

 Apply two weeks before harvest.**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 9 of 13 **Stone Fruits** Apricots and Plums

Peaches and Nectarines

Red Cherries Bi - color Cherries 27

14

27 27  Increased early

ma rketable yield  Accelerated fruit ripening  Uniform color development*  Improved fruit quality  Apply three weeks before to harvest.

 Apply at pit hardening, approximately three weeks before harvest

 Apply three weeks before harvest

 Apply seven to 10 days before harvest **Tree Nuts** Pistachios, W alnuts, Pecans 8
– 30  Accelerated fruit ripening  Improved fruit quality **Vine Fruits Grapes**  Raisin, W ine and Juice, and Table Grapes (such as Flame Seedless, Crimson, Thompson Seedl ess and Red Globe) 30  Increased early ma rketable yield  Accelerated fruit ripening  Uniform color development*  Improved fruit quality **Kiwi Fruit** 8
– 30  Increased early ma rketable yield  Accelerated fruit ripening  Improved fruit quality**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 10 of 13 **Oth er**  **s Crops**  **Coffee Ma**  **ngos Pomegranates**  **Pineapples**

**Mushrooms**
**Cotton** 8
– 30

8
– 30
15 - 45  Increased early

ma rketable yield  Accelerated fruit ripening  Uniform color development  Improved fruit quality

 Improved fruit quality  Extended shel f life

 Acceleration of boll opening.  Apply when there are sufficient unopened mature bolls to produce desired yi elds. 

### * Not intended for uniform color development use on green peppers, pears, apricots or raisin grapes. **Post -**  **Harvest A pplic** **ation Directions:** Apply SignaFresh  10EC as a washwater dip or as a spray. Prior to sorting and packaging, dip fruit in well -agitated water containing SignaFresh  10EC for up to 3 minutes or uniformly spray fruit with SignaFresh  10EC to achieve full coverage. See Post- Harvest Application Table fo r the application rate (parts per million) specific to the commodity to be treated and the Dilution Table to determine the amount of S ignaFresh  10EC needed to make solution. F or dip applications add SignaFresh  10EC to washwater, maintain water agitation and submerge fruit in washwater for up to 3 minutes. For use as a spray, dilute SignaFresh  10EC in water and apply uniformly to cover fruit prior to packing. Maintain chlorine levels and water pH at levels recommended for post- harvest treatments. Allow fruit to dry before packaging. Follow standard handling procedures after treatment. **Dilution Table Parts Per Million (PPM)**  **Am ount of SignaFresh**   **10EC to make 100 gallons of**  **spray solution**  25 3.5 fl. oz
. 50 7 fl. oz. 100 14 fl. oz. 200 28 fl. oz. 1000 1405 fl. oz. Follow directions below for crop specific post harvest applications directions for use.**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 11 of 13 

### POST HA**RVEST AP**  **PLICA TION**  **Crop/Commodity Rate**  **(ppm) for**  **dip and/or spray Use**  **Fruiting Vegetables Eggplants**  25- 100 dip 500 - 1000 spray  Improved fruit quality

 Extended shelf life **Tomatoes** Fresh Market 50 -200 dip 500 - 1000 spray  Improved fruit quality

 Accelerated natural ripening
**Peppers** 50 -200 dip 500 - 1000 spray  Improved fruit quality

 Extended shelf life **Berries/Small Fruits Blueberries**  **Boysenberries Cranberries**  **Currants** 25- 100 dip 500 - 1000 spray  Improved fruit quality

 Extended shelf life

**Tree Fruits A**  **vocados** 50 -200 dip 500 - 1000 spray  Improved fruit quality

 Accelerated natural ripening **Citrus** Grapefruits, Mineolas, Lemons, Limes, Mandarins, Oranges, Pummelos, Tangelos and Tangerines 50 -200 dip 500 - 1000 spray  Improved fruit quality

 Accelerated natural ripening **Pome Fruits** Apple, Crabapple and Pear 50 -200 dip 500 - 1000 spray  Improved fruit quality

 Extended shelf life **Stone Fruits** Peaches, Plums, Cherries, Apricots 50 -200 dip 500 - 1000 spray  Improved fruit quality

 Extended shelf life**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 12 of 13 **Other Crops Banan**  **as**

**Ma ngos**  **Pomegranates Pineapples**  50 -200 dip 500 - 1000 spray

50 -200 dip 500 - 1000 spray  Accelerated natural ripening  Improved fruit quality  Extended shelf life

 Improved fruit quality  Extended shelf life



### Use **on Cut**  **Flow ers:**  Use SignaFresh  10EC on freshly cut flowers to extend shelf life, im prove blossom life and enhance uniform bud opening. Dilute SignaFresh  10EC in water at a rate of 1 -25 ppm and submerge stems of freshly c ut fl owers in solution. Renew SignaFresh  10EC solution if water becomes cloudy. Contact your Nutra - Park representative for use guidance for specific flower varieties. **Chemigation Directions for Use General Requirements:**  1) Apply this product only through a sprinkler including a center pivot, lateral move, end tow, side (wheel) roll, traveler, big gun, solid set of hand move irrigation and systems. Do not apply this product through any other type of irrigation system. 2) Crop injury or lack of effectiveness can result from non - uniform distribution of treated water. 3) If you have questions about calibration, you should contact State Extension Service specialists, equipment manufacturers or other experts.**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 13 of 13 4) Do not connect an irrigation system (including green house systems) used for pesticide application to a public water system unless the pesticide label - prescribed safety devices for public water systems are in place. 5) A person knowledgeable of the chemigation system and responsible for its operation, or u nder the supervision of the responsible person, shall shut the system down and ma kea ny n ecessary adjustments should the need arise. **Specific Requirements for Sprinkler Chemigation**  **:** 1) The system must contain a functional check valve, vacuum relief valve a nd low- pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from back flow. 2) The pesticide injection pipeline mu st contain a functional, automatic, quick-closing check valve to prevent the flow of liquid b ack towards the injection pump. 3) The pesticide injection pipeline mu st contain a functional, normally dosed, solenoid -operated valve located on the intake side of the injection pum p and connected to the system interlock to prevent fluid from being withd rawn from the supply tank when the irrigation system is either automatically or manually shut down. 4) The system mu st contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops. 5) The i rrigation line or water pum p mu st include a functional pressure switch which will stop the water pum p motor when the water pressure decreases to the point where pesticide distribution is adversely affected. 6) Systems mu st use a metering pum p, such as a positive displacement injection pum p (e.g. diaphragm pum p) effectively designed and constructed of materials that are com patible with pesticides and capable of being filled with a system interlock. 7) Do not apply when wind speed favors drift beyond the area intended for treatment. **Ap plication Instructions:**  1) Remove scale, pesticide residues, and other foreign matter from the chem ical supply tank and entire injector system. Flush with clean water. Failure to provide a clean tank, void of scale or residues may cause product to loose effectiveness or strength. 2) Determine the treatment rates as indicated in the directions for use and make proper dilutions. 3) Prepare a solution in the chemical tank by filling the tank with the required water and then adding product as required. The product will immediately go into suspension without any required agitation. 4) The product is to be applied continuously for the duration of the water application. 

### STORA**GE AND DISPOSA** **L** Do not contaminate water, food or feed by storage or disposal. **Storage** - Store container in cool place until used. Optimum storage is at refrigerated temperatures (i.e. 33  F to 50  F). **Pesticide Disposal**  - Wastes resulting fro m use of this product may be disposed of at an approved waste disposal fac ility. **Container Disposal -**  Non - refillable container. Do not reuse or refill this container. Triple rinse (or equivalent) promptly after emptying. T riple rinse as follows: E mpty the remaining contents into application equipment or a mix tank and drai n for 10 seconds after the flow begins to drip. Fill the container 1⁄4 full with water and recap. S hake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds af ter the flow b egins to drip. Repeat this procedure two more times. Then offer for recycling if available or puncture and dispose of in a sanitary landfill, or by incineration. D o not burn, unless allowed by state and local ordinances. (Limited Wa rranty)**SignaFresh**  **10EC (pending as File Sy mbol 73562**  **- E)**  MASTER LABEL - Label Version (2) dated March 17, 2011 Page 14 of 13 

### OPTIONA**L LA BEL CLAIMS** 

- SignaFresh  10EC is a growth regulator that enhances fruit quality, ripening and shelf life of select fruits, flowers and vegetables.

- With SignaFresh  Technology.

- Quality Enhancer

- Fresh Focus 

- MasterFresh 