9/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

1/1/09 34 0.0148 511 257 0.5 0.13 1/2/09 34 0.0148 510 257 0.5 0.13 1/3/09 35 0.0148 510 264 0.5 0.13 1/4/09 32 0.0148 502 238 0.5 0.12 1/5/09 36 0.0148 497 265 0.5 0.13 1/6/09 36 0.0148 512 273 0.5 0.14 1/7/09 35 0.0148 507 263 0.5 0.13 1/8/09 36 0.0148 511 272 0.5 0.14 1/9/09 34 0.0148 505 254 0.5 0.13 1/10/09 30 0.0148 81 36 0.4 0.02 SHUTDOWN 1/11/09 0.0148 0 0 0.0 0.00 1/12/09 0.0148 0 0 0.0 0.00 1/13/09 0.0148 0 0 0.0 0.00 1/14/09 0.0148 0 0 0.0 0.00 1/15/09 0.0148 0 0 0.0 0.00 1/16/09 0.0148 0 0 0.0 0.00 1/17/09 0.0148 0 0 0.0 0.00 1/18/09 0.0148 0 0 0.0 0.00 1/19/09 0.0148 0 0 0.0 0.00 1/20/09 0.0148 0 0 0.0 0.00 1/21/09 0.0148 0 0 0.0 0.00 1/22/09 0.0148 0 0 0.0 0.00 1/23/09 0.0148 0 0 0.0 0.00 1/24/09 0.0148 0 0 0.0 0.00 1/25/09 0.0148 0 0 0.0 0.00 1/26/09 0.0148 0 0 0.0 0.00 1/27/09 0.0148 0 0 0.0 0.00 1/28/09 0.0148 0 0 0.0 0.00 1/29/09 0.0148 0 0 0.0 0.00 1/30/09 0.0148 0 0 0.0 0.00 1/31/09 0.0148 0 0 0.0 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total **JA N**  **2009 34**  **0.0148 4,645**  **2,378 0.5**  **1.2 0.1**  **1.2** FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 273 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - JANUARY20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

2/1/09 0.0148 0 0 0.0 0.00 2/2/09 0.0148 0 0 0.0 0.00 2/3/09 0.0148 0 0 0.0 0.00 2/4/09 0.0148 0 0 0.0 0.00 2/5/09 0.0148 0 0 0.0 0.00 2/6/09 0.0148 0 0 0.0 0.00 2/7/09 0.0148 0 0 0.0 0.00 2/8/09 0.0148 0 0 0.0 0.00 2/9/09 0.0148 0 0 0.0 0.00 2/10/09 0.0148 0 0 0.0 0.00 2/11/09 75 0.0148 106 118 1.1 0.06 STARTUP 2/12/09 32 0.0148 484 229 0.5 0.11 2/13/09 36 0.0148 484 258 0.5 0.13 2/14/09 35 0.0148 471 244 0.5 0.12 2/15/09 34 0.0148 501 252 0.5 0.13 2/16/09 34 0.0148 492 248 0.5 0.12 2/17/09 34 0.0148 501 252 0.5 0.13 2/18/09 34 0.0148 478 241 0.5 0.12 2/19/09 35 0.0148 480 248 0.5 0.12 2/20/09 34 0.0148 478 241 0.5 0.12 2/21/09 34 0.0148 484 244 0.5 0.12 2/22/09 34 0.0148 490 247 0.5 0.12 2/23/09 34 0.0148 475 239 0.5 0.12 2/24/09 36 0.0148 491 261 0.5 0.13 2/25/09 35 0.0148 494 256 0.5 0.13 2/26/09 33 0.0148 489 239 0.5 0.12 2/27/09 35 0.0148 490 254 0.5 0.13 2/28/09 35 0.0148 497 257 0.5 0.13

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 **FEB 2009** **37 0.0148**  **8,386 4,327**  0.5 **2.2 0.1**  **2.3** MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 261 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - FEBRUARY20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

3/1/09 36 0.0148 487 259 0.5 0.13 3/2/09 36 0.0148 504 269 0.5 0.13 3/3/09 34 0.0148 511 257 0.5 0.13 3/4/09 33 0.0148 281 137 0.5 0.07 SHUTDOWN 3/5/09 37 0.0148 83 45 0.5 0.02 STARTUP 3/6/09 34 0.0148 492 247 0.5 0.12 3/7/09 34 0.0148 507 255 0.5 0.13 3/8/09 33 0.0148 499 244 0.5 0.12 3/9/09 35 0.0148 507 262 0.5 0.13 3/10/09 35 0.0148 499 258 0.5 0.13 3/11/09 34 0.0148 495 249 0.5 0.12 3/12/09 33 0.0148 490 239 0.5 0.12 3/13/09 34 0.0148 501 252 0.5 0.13 3/14/09 37 0.0148 517 283 0.5 0.14 3/15/09 36 0.0148 510 272 0.5 0.14 3/16/09 33 0.0148 518 253 0.5 0.13 3/17/09 34 0.0148 513 258 0.5 0.13 3/18/09 36 0.0148 514 274 0.5 0.14 3/19/09 36 0.0148 492 262 0.5 0.13 3/20/09 38 0.0148 505 284 0.6 0.14 3/21/09 34 0.0148 407 205 0.5 0.10 SHUTDOWN 3/22/09 0.0148 0 0 #DIV/0! 0.00 3/23/09 0.0148 0 0 #DIV/0! 0.00 3/24/09 0.0148 0 0 #DIV/0! 0.00 3/25/09 0.0148 0 0 #DIV/0! 0.00 3/26/09 0.0148 0 0 #DIV/0! 0.00 3/27/09 0.0148 0 0 #DIV/0! 0.00 3/28/09 0.0148 0 0 #DIV/0! 0.00 3/29/09 0.0148 0 0 #DIV/0! 0.00 3/30/09 0.0148 0 0 #DIV/0! 0.00 3/31/09 0.0148 0 0 #DIV/0! 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 **MA R**  **2009 35**  **0.0148 9,831**  **5,066 0.5**  **2.5 0.2**  **2.7** APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 284 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - MARCH20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

4/1/09 0 0.0148 0 0 0.0 0.00 4/2/09 0.0148 0 0 0.0 0.00 4/3/09 0.0148 0 0 0.0 0.00 4/4/09 0.0148 0 0 0.0 0.00 4/5/09 0.0148 0 0 0.0 0.00 4/6/09 0.0148 0 0 0.0 0.00 4/7/09 0.0148 0 0 0.0 0.00 4/8/09 0.0148 0 0 0.0 0.00 4/9/09 0.0148 0 0 0.0 0.00 4/10/09 0.0148 0 0 0.0 0.00 4/11/09 0.0148 0 0 0.0 0.00 4/12/09 0.0148 0 0 0.0 0.00 4/13/09 0.0148 0 0 0.0 0.00 4/14/09 0.0148 0 0 0.0 0.00 4/15/09 0.0148 0 0 0.0 0.00 4/16/09 0.0148 0 0 0.0 0.00 4/17/09 0.0148 0 0 0.0 0.00 4/18/09 0.0148 0 0 0.0 0.00 4/19/09 0.0148 0 0 0.0 0.00 4/20/09 0.0148 0 0 0.0 0.00 4/21/09 0.0148 0 0 0.0 0.00 4/22/09 0.0148 0 0 0.0 0.00 4/23/09 0.0148 0 0 0.0 0.00 4/24/09 0.0148 0 0 0.0 0.00 4/25/09 0.0148 0 0 0.0 0.00 4/26/09 0.0148 0 0 0.0 0.00 4/27/09 0.0148 0 0 0.0 0.00 4/28/09 0.0148 0 0 0.0 0.00 4/29/09 0.0148 0 0 0.0 0.00 4/30/09 0.0148 0 0 0.0 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 **AP R**  **2009 0**  **0.0148 0**  **0 0.0**  **0.0 0.0**  **0.0** MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL : 

### 0 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - APRIL20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

5/1/09 0.0148 0 0 0.0 0.00 5/2/09 0.0148 0 0 0.0 0.00 5/3/09 0.0148 0 0 0.0 0.00 5/4/09 0.0148 0 0 0.0 0.00 5/5/09 0.0148 0 0 0.0 0.00 5/6/09 0.0148 0 0 0.0 0.00 5/7/09 0.0148 0 0 0.0 0.00 5/8/09 0.0148 0 0 0.0 0.00 5/9/09 0.0148 0 0 0.0 0.00 5/10/09 59 0.0148 335 293 0.9 0.15 STARTUP 5/11/09 39 0.0148 505 291 0.6 0.15 5/12/09 38 0.0148 507 285 0.6 0.14 5/13/09 35 0.0148 516 267 0.5 0.13 5/14/09 32 0.0148 501 237 0.5 0.12 5/15/09 34 0.0148 487 245 0.5 0.12 5/16/09 36 0.0148 469 250 0.5 0.12 5/17/09 32 0.0148 507 240 0.5 0.12 5/18/09 36 0.0148 491 261 0.5 0.13 5/19/09 34 0.0148 518 260 0.5 0.13 5/20/09 35 0.0148 493 255 0.5 0.13 5/21/09 37 0.0148 481 264 0.5 0.13 5/22/09 35 0.0148 467 242 0.5 0.12 5/23/09 34 0.0148 483 243 0.5 0.12 5/24/09 34 0.0148 498 250 0.5 0.13 5/25/09 34 0.0148 502 252 0.5 0.13 5/26/09 31 0.0148 507 232 0.5 0.12 5/27/09 33 0.0148 500 244 0.5 0.12 5/28/09 33 0.0148 488 238 0.5 0.12 5/29/09 30 0.0148 470 209 0.4 0.10 5/30/09 35 0.0148 237 123 0.5 0.06 SHUTDOWN, STARTUP 5/31/09 36 0.0148 496 264 0.5 0.13

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 **MA Y**  **2009 36**  **0.0148 10,456**  **5,448 0.5**  **2.7 0.1**  **2.8** JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 293 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - MAY20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

6/1/09 38 0.0148 498 280 0.6 0.14 6/2/09 35 0.0148 554 287 0.5 0.14 6/3/09 32 0.0148 603 286 0.5 0.14 6/4/09 35 0.0163 485 277 0.6 0.14 6/5/09 36 0.0163 488 286 0.6 0.14 6/6/09 35 0.0163 499 285 0.6 0.14 6/7/09 35 0.0163 473 270 0.6 0.13 6/8/09 32 0.0163 476 248 0.5 0.12 6/9/09 33 0.0163 458 246 0.5 0.12 6/10/09 38 0.0163 453 280 0.6 0.14 6/11/09 35 0.0163 482 275 0.6 0.14 6/12/09 34 0.0163 469 260 0.6 0.13 6/13/09 31 0.0163 25 13 0.5 0.01 SHUTDOWN 6/14/09 0.0163 0 0 #DIV/0! 0.00 6/15/09 0.0163 0 0 #DIV/0! 0.00 6/16/09 0.0163 0 0 #DIV/0! 0.00 6/17/09 0.0163 0 0 #DIV/0! 0.00 6/18/09 0.0163 0 0 #DIV/0! 0.00 6/19/09 0.0163 0 0 #DIV/0! 0.00 6/20/09 0.0163 0 0 #DIV/0! 0.00 6/21/09 0.0163 0 0 #DIV/0! 0.00 6/22/09 0.0163 0 0 #DIV/0! 0.00 6/23/09 0.0163 0 0 #DIV/0! 0.00 6/24/09 0.0163 0 0 #DIV/0! 0.00 6/25/09 0.0163 0 0 #DIV/0! 0.00 6/26/09 0.0163 0 0 #DIV/0! 0.00 6/27/09 0.0163 0 0 #DIV/0! 0.00 6/28/09 0.0163 0 0 #DIV/0! 0.00 6/29/09 0.0163 0 0 #DIV/0! 0.00 6/30/09 0.0163 0 0 #DIV/0! 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 **JUN 2009** **35 0.0163**  **5,962 3,292**  **0.6 1.6**  **0.1 1.8**  JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 287 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - JUNE20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

7/1/09 0 0.0163 0 0 0.0 0.00 7/2/09 0.0163 0 0 0.0 0.00 7/3/09 0.0163 0 0 0.0 0.00 7/4/09 0.0163 0 0 0.0 0.00 7/5/09 0.0163 0 0 0.0 0.00 7/6/09 0.0163 0 0 0.0 0.00 7/7/09 0.0163 0 0 0.0 0.00 7/8/09 0.0163 0 0 0.0 0.00 7/9/09 0.0163 0 0 0.0 0.00 7/10/09 0.0163 0 0 0.0 0.00 7/11/09 0.0163 0 0 0.0 0.00 7/12/09 0.0163 0 0 0.0 0.00 7/13/09 0.0163 0 0 0.0 0.00 7/14/09 0.0163 0 0 0.0 0.00 7/15/09 0.0163 0 0 0.0 0.00 7/16/09 0.0163 0 0 0.0 0.00 7/17/09 0.0163 0 0 0.0 0.00 7/18/09 0.0163 0 0 0.0 0.00 7/19/09 0.0163 0 0 0.0 0.00 7/20/09 0.0163 0 0 0.0 0.00 7/21/09 0.0163 0 0 0.0 0.00 7/22/09 0.0163 0 0 0.0 0.00 7/23/09 0.0163 0 0 0.0 0.00 7/24/09 0.0163 0 0 0.0 0.00 7/25/09 0.0163 0 0 0.0 0.00 7/26/09 0.0163 0 0 0.0 0.00 7/27/09 47 0.0163 59 45 0.8 0.02 STARTUP 7/28/09 33 0.0163 325 175 0.5 0.09 7/29/09 35 0.0163 488 278 0.6 0.14 7/30/09 34 0.0163 498 276 0.6 0.14 7/31/09 33 0.0163 497 267 0.5 0.13

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 **JUL 2009** **30 0.0163**  **1,867 1,042**  **0.6 0.5**  **0.0 0.5**  AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 278 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - JULY 20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

8/1/09 34 0.0163 503 279 0.6 0.14 8/2/09 33 0.0163 509 274 0.5 0.14 8/3/09 38 0.0163 295 183 0.6 0.09 SHUTDOWN /STARTUP 8/4/09 41 0.0163 509 340 0.7 0.17 8/5/09 39 0.0163 539 342 0.6 0.17 8/6/09 40 0.0163 515 336 0.7 0.17 8/7/09 36 0.0163 516 303 0.6 0.15 8/8/09 34 0.0163 517 286 0.6 0.14 8/9/09 33 0.0163 515 277 0.5 0.14 8/10/09 34 0.0163 513 284 0.6 0.14 8/11/09 36 0.0163 499 293 0.6 0.15 8/12/09 33 0.0163 504 271 0.5 0.14 8/13/09 31 0.0163 490 247 0.5 0.12 8/14/09 33 0.0163 524 282 0.5 0.14 8/15/09 34 0.0163 517 287 0.6 0.14 8/16/09 34 0.0163 501 278 0.6 0.14 8/17/09 33 0.0163 501 269 0.5 0.13 8/18/09 34 0.0163 512 284 0.6 0.14 8/19/09 42 0.0163 239 164 0.7 0.08 SHUTDOWN 8/20/09 0.0163 0 0 0.0 0.00 8/21/09 140 0.0163 10 22 2.3 0.01 STARTUP /SHUTDOWN 8/22/09 0.0163 0 0 0.0 0.00 8/23/09 0.0163 0 0 0.0 0.00 8/24/09 0.0163 0 0 0.0 0.00 8/25/09 0.0163 0 0 0.0 0.00 8/26/09 0.0163 0 0 0.0 0.00 8/27/09 0.0163 0 0 0.0 0.00 8/28/09 0.0163 0 0 0.0 0.00 8/29/09 101 0.0163 62 102 1.6 0.05 STARTUP 8/30/09 43 0.0163 523 367 0.7 0.18 8/31/09 35 0.0163 532 303 0.6 0.15

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU &

SD NOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 **AU G**  **2009 43**  **0.0163 10,343**  **6,072 0.6**  **3.0 0.4**  **3.4** SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 367 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - AUGUST20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

9/1/09 32 0.0163 516 269 0.5 0.13 9/2/09 36 0.0163 547 321 0.6 0.16 9/3/09 39 0.0163 530 337 0.6 0.17 9/4/09 41 0.0163 0 0 0.7 0.00 SHUTDOWN 9/5/09 0.0163 0 0 0.0 0.00 9/6/09 0.0163 0 0 0.0 0.00 9/7/09 0.0163 0 0 0.0 0.00 9/8/09 0.0163 0 0 0.0 0.00 9/9/09 0.0163 0 0 0.0 0.00 9/10/09 0.0163 0 0 0.0 0.00 9/11/09 0.0163 0 0 0.0 0.00 9/12/09 0.0163 0 0 0.0 0.00 9/13/09 0.0163 0 0 0.0 0.00 9/14/09 0.0163 0 0 0.0 0.00 9/15/09 0.0163 0 0 0.0 0.00 9/16/09 0.0163 0 0 0.0 0.00 9/17/09 0.0163 0 0 0.0 0.00 9/18/09 0.0163 0 0 0.0 0.00 9/19/09 0.0163 0 0 0.0 0.00 9/20/09 0.0163 0 0 0.0 0.00 9/21/09 0.0163 0 0 0.0 0.00 9/22/09 0.0163 0 0 0.0 0.00 9/23/09 0.0163 0 0 0.0 0.00 9/24/09 0.0163 0 0 0.0 0.00 9/25/09 0.0163 0 0 0.0 0.00 9/26/09 0.0163 0 0 0.0 0.00 9/27/09 0.0163 0 0 0.0 0.00 9/28/09 0.0163 0 0 0.0 0.00 9/29/09 0.0163 0 0 0.0 0.00 9/30/09 0.0163 0 0 0.0 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 **SEP 2009** **37 0.0163**  **1,593 927**  **0.6 0.5**  **0.0 0.5**  OCT 200944 0.0163 4,099 2,658 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 337 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - SEPTEMBER20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

10/1/09 0.0163 0 0 0.0 0.00 10/2/09 0.0163 0 0 0.0 0.00 10/3/09 0.0163 0 0 0.0 0.00 10/4/09 0.0163 0 0 0.0 0.00 10/5/09 0.0163 0 0 0.0 0.00 10/6/09 0.0163 0 0 0.0 0.00 10/7/09 0.0163 0 0 0.0 0.00 10/8/09 0.0163 0 0 0.0 0.00 10/9/09 0.0163 0 0 0.0 0.00 10/10/09 96 0.0163 124 195 1.6 0.10 **STA RTUP**  10/11/09 47 0.0163 553 **421** 0.8 0.21 10/12/09 41 0.0163 558 373 0.7 0.19 10/13/09 37 0.0163 554 334 0.6 0.17 10/14/09 37 0.0163 557 336 0.6 0.17 10/15/09 36 0.0163 550 322 0.6 0.16 10/16/09 35 0.0163 547 312 0.6 0.16 10/17/09 35 0.0163 547 312 0.6 0.16 10/18/09 30 0.0163 109 53 0.5 0.03 **SHUTDOWN** 10/19/09 0.0163 0 0 0.0 0.00 10/20/09 0.0163 0 0 0.0 0.00 10/21/09 0.0163 0 0 0.0 0.00 10/22/09 0.0163 0 0 0.0 0.00 10/23/09 0.0163 0 0 0.0 0.00 10/24/09 0.0163 0 0 0.0 0.00 10/25/09 0.0163 0 0 0.0 0.00 10/26/09 0.0163 0 0 0.0 0.00 10/27/09 0.0163 0 0 0.0 0.00 10/28/09 0.0163 0 0 0.0 0.00 10/29/09 0.0163 0 0 0.0 0.00 10/30/09 0.0163 0 0 0.0 0.00 10/31/09 0.0163 0 0 0.0 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 **OCT 2009** **44 0.0163**  **4,099 2,658**  **0.6 1.3**  **0.2 1.5**  NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 421 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - OCTOBER20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

11/1/09 0.0163 0 0 0.0 0.00 11/2/09 0.0163 0 0 0.0 0.00 11/3/09 0.0163 0 0 0.0 0.00 11/4/09 0.0163 0 0 0.0 0.00 11/5/09 0.0163 0 0 0.0 0.00 11/6/09 0.0163 0 0 0.0 0.00 11/7/09 0.0163 0 0 0.0 0.00 11/8/09 0.0163 0 0 0.0 0.00 11/9/09 0.0163 0 0 0.0 0.00 11/10/09 0.0163 0 0 0.0 0.00 11/11/09 0.0163 0 0 0.0 0.00 11/12/09 44 0.0163 140 100 0.7 0.05 **STA RTUP**  11/13/09 36 0.0163 558 327 0.6 0.16 11/14/09 37 0.0163 547 330 0.6 0.16 11/15/09 38 0.0163 565 350 0.6 0.17 11/16/09 38 0.0163 557 345 0.6 0.17 11/17/09 37 0.0163 560 337 0.6 0.17 11/18/09 39 0.0163 572 363 0.6 0.18 11/19/09 36 0.0163 573 336 0.6 0.17 11/20/09 36 0.0163 560 328 0.6 0.16 11/21/09 37 0.0163 556 335 0.6 0.17 11/22/09 37 0.0163 561 338 0.6 0.17 11/23/09 35 0.0163 476 271 0.6 0.14 **SHUTDOWN** 11/24/09 0.0163 0 0 0.0 0.00 11/25/09 0.0163 0 0 0.0 0.00 11/26/09 0.0163 0 0 0.0 0.00 11/27/09 0.0163 0 0 0.0 0.00 11/28/09 0.0163 0 0 0.0 0.00 11/29/09 0.0163 0 0 0.0 0.00 11/30/09 0.0163 0 0 0.0 0.00

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 **NOV 2006** **38 0.0163**  **6,221 3,761**  **0.6 1.9**  **0.0 1.9**  DEC 200937 0.0163 2,773 1,668 0.6 0.8 0.0 0.9

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 363 **0.55 20** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - NOVEMBER20099/26/2011 PLANT 9 Monthly NOx Report Page 1

DAY PPM

NOxFACTORProduction Tons LBS NOx

/DAY LBS

/TONNOx TONS

12/1/09 0.0163 0 0 0.0 0.00 12/2/09 0.0163 0 0 0.0 0.00 12/3/09 0.0163 0 0 0.0 0.00 12/4/09 0.0163 0 0 0.0 0.00 12/5/09 0.0163 0 0 0.0 0.00 12/6/09 0.0163 0 0 0.0 0.00 12/7/09 0.0163 0 0 0.0 0.00 12/8/09 0.0163 0 0 0.0 0.00 12/9/09 0.0163 0 0 0.0 0.00 12/10/09 0.0163 0 0 0.0 0.00 12/11/09 0.0163 0 0 0.0 0.00 12/12/09 0.0163 0 0 0.0 0.00 12/13/09 0.0163 0 0 0.0 0.00 12/14/09 0.0163 0 0 0.0 0.00 12/15/09 0.0163 0 0 0.0 0.00 12/16/09 0.0163 0 0 0.0 0.00 12/17/09 0.0163 0 0 0.0 0.00 12/18/09 0.0163 0 0 0.0 0.00 12/19/09 0.0163 0 0 0.0 0.00 12/20/09 0.0163 0 0 0.0 0.00 12/21/09 0.0163 0 0 0.0 0.00 12/22/09 0.0163 0 0 0.0 0.00 12/23/09 0.0163 0 0 0.0 0.00 12/24/09 0.0163 0 0 0.0 0.00 12/25/09 0.0163 0 0 0.0 0.00 12/26/09 0.0163 37 0 0.0 0.00 STARTUP 12/27/09 39 0.0163 541 344 0.6 0.17 12/28/09 37 0.0163 544 328 0.6 0.16 12/29/09 37 0.0163 545 329 0.6 0.16 12/30/09 37 0.0163 562 339 0.6 0.17 12/31/09 37 0.0163 545 328 0.6 0.16

MONTHYEARPPM

NOxFACTORProduction Tons LBS NOx

/MONTH LBS

/TONNOx TONS Normal RunTONS SU

& SDNOx TONS

Total JAN 200934 0.0148 4,645 2,378 0.5 1.2 0.1 1.2 FEB 200937 0.0148 8,386 4,327 0.5 2.2 0.1 2.3 MAR 200935 0.0148 9,831 5,066 0.5 2.5 0.2 2.7 APR 2009 0 0.0148 0 0 0.0 0.0 0.0 0.0 MAY 200936 0.0148 10,456 5,448 0.5 2.7 0.1 2.8 JUN 200935 0.0163 5,962 3,292 0.6 1.6 0.1 1.8 JUL 200930 0.0163 1,867 1,042 0.6 0.5 0.0 0.5 AUG 200943 0.0163 10,343 6,072 0.6 3.0 0.4 3.4 SEP 200937 0.0163 1,593 927 0.6 0.5 0.0 0.5 OCT 200944 0.0163 4,099 2,658 0.6 1.3 0.2 1.5 NOV 200638 0.0163 6,221 3,761 0.6 1.9 0.0 1.9 **DEC 2009** **37 0.0163**  **2,773 1,668**  **0.6 0.8**  **0.0 0.9** 

DAILY, UNIT, AND 12-MONTH LIMIT :

### 400 **0.6 47** 
ACTUAL :

### 344 **0.55 19.5** 

lbs /daylbs /ton tons /12-mo 

## KENNEWICK FERTILIZER OPERATIONS Plant 9 NOx Emissions Summary - DECEMBER20099/26/2011 PLANT 9 Monthly NOx Report Page 1

12 COUNT DATE TIME SU or SDPLANT 9

1/10/2009 04:05 SD Inventory control 1 2/11/2009 18:13 SU

3/4/2009 14:07 SD minor NOx leak 1 3/5/2009 19:41 SU

3/21/2009 19:30 SD Inventory control 1 5/10/2009 23:00 SU

5/30/2009 10:00 SD Trip 1 5/30/2009 22:00 SU

6/13/2009 01:00 SD Inventory control 1 7/27/2009 21:25 SU

8/3/2009 13:02 SD Trip 1 8/3/2009 23:05 SU

8/19/2009 10:10 SD Expander crash 1 8/19/2009 21:10 SU

8/19/2009 23:00 SD NO GO 1 8/21/2009 21:15 SU

8/21/2009 22:00 SD NO GO 1 8/29/2009 20:40 SU Expander Replacement

9/4/2009 03:00 SD 1 10/10/2009 19:35 SU 10/18/2009 04:08 SD 1 11/12/2009 17:25 SU 11/23/2009 20:42 SD 1 12/26/2009 22:15 SU9/26/2011 PLANT 9 Monthly NOx Report Page 1

NOTES:

Go to

"**S:\ A dmin\ A** **-A ir\ Plant 9 NOx REPORTS** " and open the current month file, i.e. "**2004-01 Jun - lb-day NOx Plant 9.xls** This is the report form that is submitted to BCAA each month before the 10th.

Go to

"**R:\ Stacks\ Plant9\ Reports\ 2004 1st Half Year**" and open the current month CEMS data summary, i.e. "**TJK 2004 -06 June CEMS datalog - Plant 9 xls** This is the data management file used to summarize CEMS data from the datalogc files, to do hourly and daily

averages, and to identify calibrations and down time.

Go to

"**P:\Citect\User\P9_reprt**" and copy the"**datalogc.dbf**"file (current date and time to the minute) and copy it to "**R:\ Stacks\ Plant9\ Reports** This is the raw data file from the Plant 9 CEMS data recorder. Don't open the original for fear of causing it to stop recording.

Open the "**datalogc.dbf**" file copy and copy

the first 3 columns (date, time, ppm NOx) to

"**R:\ Stacks\ Plant9\ Reports\ 2004 1st Half Year\ TJK 2004 -06 June CEMS datalog - Plant 9.xls**" Do a save on the CEMS data file with new data and close the datalogc file.

Now manage the CEMS data by reviewing for missing 2-minute interval readings, shutdown periods, questionable readings. Copy the hourly

average and 3-hour average formula cells down to each xx:00:xx hour. Copy the dailly

average NOx formula down to the last cell of each day

. **Enter a 1, 2, 3, or 4 in column "J" for (1) invalid readings, (2) excess emissions, (3) plant down, or (4) daily auto calilbration.** When finished and all calibrations and daily averages have been calculated, save the document.

Now open the "**S:\ A dmin\ A** **-A ir\ Plant 9 NOx REPORTS** ", "**2004-01 Jun - lb-day NOx Plant 9.xls**" andenter the daily average NOx ppm readings

The daily

nitric acid production summary is located at "S:\ OPER\ EXCEL\ ops\ daily reports\ Daily

2004" Go to

"**S:\ OPER\ EXCEL\ ops\ daily reports\ Daily 2004**" and record or copy the daily nitric acid production for Plant 9. Enter the daily

production numbers into the tons/day column on the monthly report.

When the monthly

NOx report is finished save a copy to for use the next month. Update the first day and month summary

to 2004. You are done with the Monthly NOx report.

Now, go back to "**R:\ Stacks\ Plant9\ Reports\ 2004 1st Half Year\ TJK 2004 -06 June CEMS datalog - Plant 9.xls** Transfer the total plant operating hours, CEMS operating hours, and excess emission hours to the AOP semi-annual monitoring report at

"**S:\ A dmin\ Environmental\ A** **ir\ BCA A** **Title V Semi-annual Monitoring Reports\ 2004 Jan to Jun semi-annual monnitoring report\ \ 2004 1st CEMS EXCESS EMISSIONS and MONITORING REPORT.xls"** 9/26/2011 PLANT 9 Monthly NOx Report Page 2

**2004-01 Jun - lb-day NOx Plant 9.xls**"

**TJK 2004 -06 June CEMS datalog - Plant 9 xls**" This is the data management file used to summarize CEMS data from the datalogc files, to do hourly and daily

averages, and to identify calibrations and down time.

**R:\ Stacks\ Plant9\ Reports**" This is the raw data file from the Plant 9 CEMS data recorder. Don't open the original for fear of causing it to stop recording.

Now manage the CEMS data by reviewing for missing 2-minute interval readings, shutdown periods, questionable readings.

**Enter a 1, 2, 3, or 4 in column "J" for (1) invalid readings, (2) excess emissions, (3) plant down, or (4) daily auto calilbration.**

enter the daily

average NOx ppm readings

.

When the monthly

NOx report is finished save a copy to for use the next month. Update the first day and month summary

to 2004.

**R:\ Stacks\ Plant9\ Reports\ 2004 1st Half Year\ TJK 2004 -06 June CEMS datalog - Plant 9.xls**". Transfer the total plant operating hours, CEMS operating hours, and excess emission hours to the AOP semi-annual monitoring report at **S:\ A dmin\ Environmental\ A** **ir\ BCA A** **Title V Semi-annual Monitoring Reports\ 2004 Jan to Jun semi-annual monnitoring report\**9/26/2011 PLANT 9 Monthly NOx Report Page 1

YEAR MONTHAVG N2O per MONTH (ppm) RUN HRSWEIGHT CALCAVG N2O

per YEAR (ppm)
Aveage 139 Std Dev 31

2009 JAN

FEB MAR APR MAY JUN **113.6** 315.6 35852 FTIR CEMS calibrated JUL **193.6** 98.5 19070 AUG **158.4** 492.7 78044 SEP **156.8** 75.4 11823 OCT **117.1** 178.8 20937 NOV **109.7** 267.4 29334 DEC **126.7** 120.9 15318 2009 **136**Weighted average 2010 JAN

FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC 2010 JAN

FEB MAR APR MAY JUN JUL SEP OCT NOV DEC 2011 JAN

FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC 2012 JAN

FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC 2013