Wastewater Type

Flow Diagram Equipment No.

Date Sampled 12/17/2009 12/17/2009 12/12/2009 3/12/2012 3/13/2012 3/14/2012 3/15/2012 3/28/2012 3/29/2012 Hits

Lab Report Number JA32868 JA32868 JA32858 JB1063 JB1064 JB1065 JB1067 JB-2388 JB-2389

Duplicate

Sample Type Composite - indicates lab Composite Composite Composite Grab Grab Grab Grab Grab Grab

combination of 3 grabs

Compound CAS No. Method of Analysis

1 Ethylene Glycol 107-21-1 DAI by GC/MS 8260B SIM ND(120) ND(120) ND(120) ND(100) ND(100) ND(100) ND(100) ND(100) ND(100)

2 Benzene 71-43-2 SW846 8260 B ND(0.23) ND(2.3) ND(0.23) ND(0.22) ND(0.22) ND(1.1) ND(2.2) ND(0.44) ND(0.55)

3 1,3 Butadiene 106-99-0 SW846 8260 B NA NA NA New ND(0.33) ND(0.33) ND(1.6) ND(3.3) ND(0.66) ND(0.82)

4 Chlorobenzene 108-90-7 SW846 8260 B NA NA NA New ND(0.22) ND(0.22) ND(1.1) ND(2.2) ND(0.45) ND(0.56)

5 Chloroethane 75-00-3 SW846 8260 B 14 9.9 68 1.8 5.9 ND(1.8) 10 11 ND(0.92) 6

6 Chloroform 67-66-3 SW846 8260 B ND(0.23) ND(2.3) 0.25 ND(0.21) 0.4 ND(1.0) ND(2.1) ND(0.41) ND(0.52) 2

7 Chloromethane 74-87-3 SW846 8260 B 16 13 79 1.6 5.4 ND(1.1) 7.7 1 1 7

8 Chloroprene 126-99-8 SW846 8260 B NA NA NA New ND(0.35) ND(0.35) ND(1.7) ND(3.5) ND(0.69) ND(0.87)

9 1,1-Dichloroethane 75-34-3 SW846 8260 B ND(0.29) ND(2.9) 0.57 ND(0.19) ND(0.19) ND(0.96) ND(1.9) ND(0.38) ND(0.48)

10 1,2-Dichloroethane 107-06-2 SW846 8260 B 39 51 132 18 37 4.7 67 5 3 8

11 1,1-Dichloroethene 75-35-4 SW846 8260 B ND(0.40) ND(4.0) ND(0.4) ND(0.28) ND(0.28) ND(1.4) ND(2.8) ND(0.56) ND(0.70)

12 Ethylbenzene 100-41-4 SW846 8260 B NA NA NA New ND(0.21) ND(0.21) ND(1.1) ND(2.1) ND(0.42) ND(0.53)

13 Hexane 110-54-3 SW846 8260 B NA NA NA New ND(1.4) ND(1.4) ND(6.8) ND(14) ND(2.7) ND(3.4)

14 Isopropylbenzene (cumene) 98-82-8 SW846 8260 B ND(0.57) ND(5.7) ND(0.57) ND(0.19) ND(0.19) ND(0.97) ND(1.9) ND(0.39) ND(0.49)

15 Methylene chloride 75-09-2 SW846 8260 B NA NA NA New ND(0.20) ND(0.20) ND(1.0) ND(2.0) ND(0.40) ND(0.51)

16 1,1,2,2-Tetrachloroethane 79-34-5 SW846 8260 B NA NA NA New ND(0.20) ND(0.20) ND(1.0) ND(2.0) ND(0.40) ND(0.50)

17 Toluene 108-88-3 SW846 8260 B ND(0.30) ND(3.0) ND(0.30) ND(0.15) ND(0.15) ND(0.73) ND(1.5) ND(0.29) ND(0.36)

18 1,1,1-Trichloroethane 71-55-6 SW846 8260 B NA NA NA New ND(0.24) ND(0.24) ND(1.2) ND(2.4) ND(0.47) ND(0.59)

19 1,1,2-Trichloroethane 79-00-5 SW846 8260 B NA NA NA New ND(0.23) ND(0.23) ND(1.2) ND(2.3) ND(0.46) ND(0.58)

20 2,2,4-Trimethylpentane 540-84-1 SW846 8260 B ND(0.44) ND(4.4) ND(0.44) ND(0.16) ND(0.16) ND(0.79) ND(1.6) ND(0.32) ND(0.40)

21 Vinyl Acetate 108-05-4 SW846 8260 B NA NA NA New ND(2.6) ND(2.6) ND(13) ND(26) ND(5.2) ND(6.5)

22 Vinyl Bromide 593-60-2 SW846 8260 B ND(0.10) ND(1.0) ND(0.10) ND(0.31) ND(0.31) ND(1.5) ND(3.1) ND(0.61) ND(0.77)

23 Vinyl Chloride 75-01-4 SW846 8260 B 172 116 377 12 45 10 35 163 7 8

24 Xylene (Total) 1330-20-7 SW846 8260 B ND(0.25) ND(2.5) ND(0.25) ND(0.17) ND(0.17) ND(0.87) NS(1.7) ND(0.35) ND(0.43)

25 2,4-Dinitrophenol 51-28-5 SW846 8270 D NA NA NA New ND(17) ND(17) ND(17) ND(17) ND(33) ND(17)

26 Phenol 108-95-2 SW846 8270 D ND(0.58) ND(0.58) ND(0.58) ND(1.3) ND(1.3) ND(1.3) 4.3 ND(2.6) ND(1.3) 1

27 Acetophenone 98-86-2 SW846 8270 D 1,530 1,470 967 17 12 ND(0.29) 1,500 3 ND(0.29) 6

28 bis(2-Ethylhexylphthalate 117-81-7 SW846 8270 D NA NA NA New ND(0.59) ND(0.59) ND(0.59) ND(0.59) ND(1.2) ND(0.59)

29 Hydroquinone 123-31-9 SW846 8270 D ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(10) ND(5.0)

30 Methanol 67-56-1 SW846-8015C (DAI) 8,370 17,500 12,400 5,090 3,370 1,610 10,900 3,610 6,430 8

31 Formaldehyde 50-00-0 SW846 8315A 570 194 353 325 283 315 501 390 497 8

32 Acetaldehyde 75-07-0 SW846 8315A 6,000 4,860 76,900 5,330 5,840 4,640 6,490 6,360 4,770 8

16,539 24,097 90,900 10,783 9,553 6,570 19,480 10,380 11,701

Total non-VCM HAP mg/L (ppm) 17 24 91 11 10 7 19 10 12

Detected values are reported in bold

MDL values are reported in italic font for ND values.

Note that Detection Limits (DLs) varied with dilution factors

Lab analyst determined need for dilutions based on interferences seen on chromatogram and physical properties of the sample

Concentration (ug/l) Concentration (ug/l) Concentration (ug/l)

Deer Park Process Wastewater Deer Park Process Wastewater Deer Park Process Wastewater

 Wastewater stripper (U-316) and discharge stream 

W-308 to bioplant collection sump

 Wastewater stripper (U-316) and discharge stream 

W-308 to bioplant collection sump

 Wastewater stripper (U-316) and discharge stream 

W-308 to bioplant collection sump

OV Deer Park WW Mar 2012
Resin Sampling Results for Wastewater Stripper

OxyVinyls, LP

 Pasadena, TX

Wastewater Type

Flow Diagram Equipment No.

Flow Diagram wastewater 

Stream number

Date Sampled 12/22/2009 12/29/2009 1/6/2010 1/12/2010 1/19/2010 1/28/2010

Lab Report Number JA35458 JA35466 JA35476 JA35488 JA35502 JA36409

Sample Type Composite - indicates lab Composite Composite Composite Composite Composite Composite

combination of 3 grabs

Compound CAS No. Method of Analysis

1 Ethylene Glycol 107-21-1 DAI by GC/MS 8260 SIM ND(120) ND(120) ND(120) ND(120) ND(120) ND(120)

2 Benzene 71-43-2 SW846 8260 B ND(1.2) ND(1.2) ND(4.7) ND(12) ND(1.2) ND(59)

3 1,3 Butadiene 106-99-0 SW846 8260 B NA NA NA NA NA NA

4 Chlorobenzene 108-90-7 SW846 8260 B NA NA NA NA NA NA

5 Chloroethane 75-00-3 SW846 8260 B ND(1.9) 2.8 ND(7.4) ND(19) 5.8 ND(93)

6 Chloroform 67-66-3 SW846 8260 B ND(1.2) 4.3 ND(4.7) ND(12) ND(1.2) ND(59)

7 Chloromethane 74-87-3 SW846 8260 B ND(1.4) ND(1.4) ND(5.8) ND(14) ND(1.4) ND(72)

8 Chloroprene 126-99-8 SW846 8260 B NA NA NA NA NA NA

9 1,1-Dichloroethane 75-34-3 SW846 8260 B ND(1.4) ND(1.4) ND(5.7) ND(14) ND(1.4) ND(72)

10 1,2-Dichloroethane 107-06-2 SW846 8260 B 2.7 2.8 ND(6.7) ND(17) 2.6 ND(83)

11 1,1-Dichloroethene 75-35-4 SW846 8260 B ND(2.0) ND(2.0) ND(7.9) ND(20) ND(2.0) ND(99)

12 Ethylbenzene 100-41-4 SW846 8260 B NA NA NA NA NA NA

13 Hexane 110-54-3 SW846 8260 B NA NA NA NA NA NA

14 Isopropylbenzene (cumene) 98-82-8 SW846 8260 B ND(2.9) ND(2.9) ND(11) ND(29) ND(2.9) ND(140)

15 Methylene chloride 75-09-2 SW846 8260 B NA NA NA NA NA NA

16 1,1,2,2-Tetrachloroethane 79-34-5 SW846 8260 B NA NA NA NA NA NA

17 Toluene 108-88-3 SW846 8260 B ND(1.5) ND(1.5) ND(6) ND(15) ND(1.5) ND(75)

18 1,1,1-Trichloroethane 71-55-6 SW846 8260 B NA NA NA NA NA NA

19 1,1,2-Trichloroethane 79-00-5 SW846 8260 B NA NA NA NA NA NA

20 2,2,4-Trimethylpentane 540-84-1 SW846 8260 B ND(2.2) ND(2.2) ND(8.8) ND(22) ND(2.2) ND(110)

21 Vinyl Acetate 108-05-4 SW846 8260 B NA NA NA NA NA NA

22 Vinyl Bromide 593-60-2 SW846 8260 B ND(0.50) ND(0.50) ND(2.0) ND(5.0) ND(0.50) ND(25)

23 Vinyl Chloride 75-01-4 SW846 8260 B 40 38 21 37 72 ND(110)

24 Xylene (Total) 1330-20-7 SW846 8260 B ND(1.3) ND(1.3) ND(5.0) ND(13) ND(1.3) ND(63)

25 2,4-Dinitrophenol 51-28-5 SW846 8270 C NA NA NA NA NA NA

26 Phenol 108-95-2 SW846 8270 C ND(0.58) ND(0.58) ND(0.58) ND(0.58) ND(0.64) ND(0.62)

27 Acetophenone 98-86-2 SW846 8270 C 5,220 9,110 4,790 9,010 9,190 9,950

28 bis(2-Ethylhexylphthalate 117-81-7 SW846 8270 C NA NA NA NA NA NA

29 Hydroquinone 123-31-9 SW846 8270 C ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.6) ND(5.4)

30 Methanol 67-56-1 SW846-8015 (DAI) 656,000 858,000 806,000 490,000 265,000 620,000

31 Formaldehyde 50-00-0 SW846 8315A 25 ND(6.3) 162 ND(6.3) ND(6.3) ND(6.3)

32 Acetaldehyde 75-07-0 SW846 8315A 844 10 8,370 85 ND(4.8) 2,110

662,092 867,130 819,322 499,095 274,198 632,060

Total non-VCM HAP mg/L (ppm) 660 870 820 500 270 630

Detected values are reported in bold font.

MDL values are reported in italic font for ND values.

Note that Detection Limits (DLs) varied with dilution factors

Lab analyst determined need for dilutions based on interferences seen on chromatogram and physical properties of the sample

Process water

 Wastewater stripper (U-1202)

Discharge of the wastewater stripper (Stream W-1221) that flows to 

biological treatment

Concentration (ug/l)

The samples were analyzed by Accutest Laboratories. OV Pasadena WW Dec 2009-10
Analytical Sampling Results for Sump, Column, Centrate and Scrubber Wastewater

OxyVinyls, LP

 Pedricktown, NJ

Wastewater Type LP Sump LP Sump

Stripping 

Column

Flow Diagram Equipment 

No. U-602 U-602 U-203

Flow Diagram wastewater 

Stream number W-604 W-604

Equipment 

Opening 

condensate to 

W-604

Suspension Grade

Med and 

High 

Molecular 

Wt. 

General 

Purpose 

Med and 

High 

Molecular 

Wt. 

Date Sampled 11/4/2009 1/17/2009 11/4/2009

Date Received by Lab 11/5/2009 1/17/2009 11/5/2009

Lab Report Number JA32106 JA37850 JA32106

Compound CAS No. Method of Analysis

Ethylene Glycol 107-21-1 DAI by GC/MS 8260 SIM ND(120) ND(120) ND(120)

Benzene 71-43-2 SW846 8260 B ND(0.23) ND(0.23) ND(1.2)

Chloroethane 75-00-3 SW846 8260 B ND(0.37) 3.0 59.0

Chloroform 67-66-3 SW846 8260 B ND(0.23) ND(0.23) ND(1.2)

Chloromethane 74-87-3 SW846 8260 B ND(0.29) ND(0.29) 13.4

1,1-Dichloroethane 75-34-3 SW846 8260 B ND(0.29) ND(0.29) ND(1.4)

1,2-Dichloroethane 107-06-2 SW846 8260 B ND(0.33) ND(0.33) ND(1.7)

1,1-Dichloroethene 75-35-4 SW846 8260 B ND(0.40) ND(0.40) ND(2.0)

Isopropylbenzene 98-82-8 SW846 8260 B 2.3 ND(0.57) 17.6

Toluene 108-88-3 SW846 8260 B ND(0.30) ND(0.30) ND(1.5)

2,2,4-Trimethylpentane 540-84-1 SW846 8260 B ND(0.44) ND(0.44) ND(2.2)

Vinyl Bromide 593-60-2 SW846 8260 B ND(0.10) ND(0.10) ND(0.50)

Vinyl Chloride 75-01-4 SW846 8260 B 2.5 23.4 2,960

Xylene (Total) 1330-20-7 SW846 8260 B ND(0.25) ND(0.25) ND(1.3)

Phenol 108-95-2 SW846 8270 C SW846 3510C 23.8 1.7 J 25.3

Acetophenone 98-86-2 SW846 8270 C SW846 3510C 1,270 255 1,310

Hydroquinone 123-31-9 SW846 8270 C SW846 3510C ND(5.0) ND(25) ND(5.0)

Methanol 67-56-1 SW846-8015 (DAI) 993 1,630 645

Formaldehyde 50-00-0 SW846 8315 SW846 8315 610 175 277 J

Acetaldehyde 75-07-0 SW846 8315 SW846 8315 1,040 411 1,830

Detected values are reported in bold font.

Values reported with a "J" indicate an estimated value.

Concentration (ug/l)

The samples were analyzed by Accutest Laboratories. OV Pedricktown WW Nov 2009
10/28/2013

d Pedricktown Henry

Plant POP4 POP5 POP6 Plant POH4 POH5 POH6

Client Sample ID: TRIP BLANK P4P WD4 P5P WD5 P6P WD6 TRIP BLANK P4H WD4 P5H WD5 P6H WD6

Lab Sample ID: JB4758-2 JB4758-1 JB4759-1 JB4760-1 JB4755-2 JB4755-1 JB4756-1 JB4757-1

Date Sampled: 5/1/2012 5/1/2012 5/2/2012 5/3/2012 5/1/2012 5/1/2012 5/2/2012 5/3/2012

 

GC/MS Volatiles By Sim

 

Ethylene Glycol ppm 0.000063 U 0.000063 U 0.000063 U 0.000063 U 0.000063 U 0.000063 U 0.000063 U 0.000063 U

 

GC/MS Volatiles

 

Benzene ppm 0.00022 U 0.0011 U 0.00055 U 0.0022 U 0.00022 U 0.00022 U 0.00022 U 0.00022 U

1,3-Butadiene ppm 0.00033 U 0.0016 U 0.00082 U 0.0033 U 0.00033 U 0.00033 U 0.00033 U 0.00033 U

Chlorobenzene ppm 0.00022 U 0.0011 U 0.00056 U 0.0022 U 0.00022 U 0.00022 U 0.00022 U 0.00022 U

Chloroethane ppm 0.00037 U 0.144 0.106 0.261 0.00037 U 0.144 0.0176 0.0927

Chloroform ppm 0.00021 U 0.001 U 0.00052 U 0.0021 U 0.00021 U 0.00021 U 0.00021 U 0.00021 U

Chloromethane ppm 0.00022 U 0.395 0.253 0.829 0.00022 U 0.145 0.0291 0.0866

Chloroprene ppm 0.00035 U 0.0017 U 0.00087 U 0.0035 U 0.00035 U 0.00035 U 0.00035 U 0.00035 U

1,1-Dichloroethane ppm 0.00019 U 0.00096 U 0.00048 U 0.0019 U 0.00019 U 0.00019 U 0.00019 U 0.00019 U

1,2-Dichloroethane ppm 0.00018 U 0.0073 0.0074 0.0151 0.00018 U 0.0779 0.0168 0.0768

1,1-Dichloroethene ppm 0.00028 U 0.0014 U 0.0007 U 0.0028 U 0.00028 U 0.00028 U 0.00028 U 0.00028 U

Ethylbenzene ppm 0.00021 U 0.0011 U 0.00053 U 0.0021 U 0.00021 U 0.00021 U 0.00021 U 0.00021 U

Hexane ppm 0.0014 U 0.0068 U 0.0034 U 0.014 U 0.0014 U 0.0014 U 0.0014 U 0.0014 U

Isopropylbenzene ppm 0.00019 U 0.00097 U 0.00049 U 0.0019 U 0.00019 U 0.00019 U 0.00019 U 0.00019 U

Methylene chloride ppm 0.0002 U 0.001 U 0.00051 U 0.002 U 0.0002 U 0.0002 U 0.0002 U 0.0002 U

1,1,2,2-Tetrachloroethane ppm 0.0002 U 0.001 U 0.0005 U 0.002 U 0.0002 U 0.0002 U 0.0002 U 0.0002 U

Toluene ppm 0.00015 U 0.00073 U 0.00036 U 0.0015 U 0.00015 U 0.00015 U 0.00015 U 0.00015 U

1,1,1-Trichloroethane ppm 0.00024 U 0.0012 U 0.00059 U 0.0024 U 0.00024 U 0.00024 U 0.00024 U 0.00024 U

1,1,2-Trichloroethane ppm 0.00023 U 0.0012 U 0.00058 U 0.0023 U 0.00023 U 0.00023 U 0.00023 U 0.00023 U

2,2,4-Trimethylpentane ppm 0.00016 U 0.00079 U 0.0004 U 0.0016 U 0.00016 U 0.00016 U 0.00016 U 0.00016 U

Vinyl Acetate ppm 0.0026 U 0.013 U 0.0065 U 0.026 U 0.0026 U 0.0026 U 0.0026 U 0.0026 U

Vinyl Bromide ppm 0.00031 U 0.0015 U 0.00077 U 0.0031 U 0.00031 U 0.00031 U 0.00031 U 0.00031 U

Xylene (total) ppm 0.00017 U 0.00087 U 0.00043 U 0.0017 U 0.00017 U 0.00017 U 0.00017 U 0.00017 U

 

GC/MS Semi-volatiles

 

2,4-Dinitrophenol ppm NA 0.017 U 0.017 U 0.018 U NA 0.018 U 0.017 U 0.018 U

Phenol ppm NA 0.0013 U 0.0013 U 0.0014 U NA 0.0014 U 0.0013 U 0.0029

Acetophenone ppm NA 0.767 0.699 0.554 NA 0.0201 0.162 0.11

bis(2-Ethylhexyl)phthalate ppm NA 0.00059 U 0.00061 U 0.00065 U NA 0.0032 0.00061 U 0.0032

Hydroquinone ppm NA 0.005 U 0.0052 U 0.0056 U NA 0.0054 U 0.0052 U 0.0055 U

 

GC Volatiles (SW846-8015 (DAI))

 

Methanol ppm NA 68.4 51.2 29.5 NA 5.16 1.99 9.55

Ethylene Glycol ppm NA 10 U 10 U 10 U NA 10 U 10 U 10 U

 

GC Semi-volatiles (SW846 8315)

 

Formaldehyde ppm NA 0.0543 0.0655 0.0751 NA 0.162 0.851 0.564

Acetaldehyde ppm NA 3 2.49 2.79 NA 0.0481 0.194 0.26

Vinyl Chloride, Method 107 PPM NA 0.61 2.41 1.91 NA 0.123 0.158 0.078

Page 1 PolyOne WW NJ & IL May 2012
Wastewater (Accutest)

Stripper 1 Stripper 2 Stripper 3 Stripper 1 Stripper 2 Stripper 3 Stripper 1 Stripper 2 Stripper 3 Stripper 1 Stripper 2 Stripper 3

14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00

5/8/12 5/8/12 5/8/12 5/9/12 5/9/12 5/9/12 5/8/12 5/8/12 5/8/12 5/9/12 5/9/12 5/9/12

Acetaldehyde 8315A 8315A ppm 9.6 6.2 3.8 9.7 6.5 1.7 mg/L 9.6 6.2 3.8 9.7 6.5 1.7

Bromoethane (Vinyl Bromide) 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

1,3-Butadiene 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Benzene 8260B 8260B ppb 0 0 0 0 0 3 mg/L 0 0 0 0 0 0.003

2-Chloro-1,3-Butadiene (Chloroprene) 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Chloroethane (Ethyl Chloride) 8260B 8260B ppb 0 0 0 2.3 0 9.1 mg/L 0 0 0 0.0023 0 0.0091

Chloromethane (Methyl chloride) 8260B 8260B ppb 6 17 0 9.4 0 0 mg/L 0.006 0.017 0 0.0094 0 0

Chloroform 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

1,1-Dichloroethene (Vinylidene chloride) 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

1,1-Dichloroehtane (Ethylidene dichloride) 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

1,2-Dichloroethane (Ethylene dichloride) 8260B 8260B ppb 26 21 6.2 44 23 0 mg/L 0.026 0.021 0.0062 0.044 0.023 0

Methylene Chloride (Dichloromethane) 8260B 8260B ppb 0 0 15 0 9.8 16 mg/L 0 0 0.015 0 0.0098 0.016

Vinyl Acetate 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Isopropylbenzene (Cumene) 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Acetophenone 8270D 8270D ppb 3500 1200 1400 4900 1400 1700 μg/L 3.5 1.2 1.4 4.9 1.4 1.7

Bis(2-Ethylhexyl)phathalate 8270D 8270D ppb 0 0 0.79 0 0 0 μg/L 0 0 0.00079 0 0 0

Phenol 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Methanol 8015C 8015C ppm 49.7 0 31.8 49.9 0 32.4 μg/L 49700 0 31800 49900 0 32400

Formaldehyde 8315A 8315A ppm 0.72 0.99 0.6 1.3 1.3 0.38 mg/L 0.72 0.99 0.6 1.3 1.3 0.38

Vinyl Chloride 8260B 8260B ppb 4.3 15 0 6.5 5.4 0 mg/L 0.0043 0.015 0 0.0065 0.0054 0

Chlorobenzene 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

2,4-Dinitrophenol 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Ethylbenzene 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Ehtylene glycol 8015C 8015C ppm 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Hexane 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Hydroquinone 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

1,1,2,2-Tetrachloroethane 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Toluene 8260B 8260B ppb 0 0.27 0 0 0 11 mg/L 0 0.00027 0 0 0 0.011

1,1,2-Trichloroethane 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

2,2,4-Trimethylepentane 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Xylenes 8260B 8260B ppb 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Methyl Ethyl Ketone (2-Butanone) 8260B 8260B ppb 100 400 7300 130 500 4200 mg/L 0.1 0.4 7.3 0.13 0.5 4.2

Methyl Isobutyl Ketone (4-Methyl-2-pentanone) 8260B 8260B ppb 220 140 680 330 170 410 mg/L 0.22 0.14 0.68 0.33 0.17 0.41

Total HAP (VCM by Method 8260B) ppm 63.876 8.983 45.602 66.322 9.908 40.829

Analyte Method Required Method Unit

Shintech WW TX May 2012 Accutes
Wastewater (ECI)

Stripper 1 Stripper 2 Stripper 3 Stripper 1 Stripper 2 Stripper 3 Stripper 1Stripper 2Stripper 3Stripper 1Stripper 2Stripper 3

14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00

5/8/12 5/8/12 5/8/12 5/9/12 5/9/12 5/9/12 5/8/12 5/8/12 5/8/12 5/9/12 5/9/12 5/9/12

Acetaldehyde 8315A 8315A ppm 14.64 3.64 2.21 9 0.765 1.42 mg/L 14.64 3.64 2.21 9 0.765 1.42

Bromoethane (Vinyl Bromide) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

1,3-Butadiene 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Benzene 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

2-Chloro-1,3-Butadiene (Chloroprene) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Chloroethane (Ethyl Chloride) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Chloromethane (Methyl chloride) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Chloroform 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

1,1-Dichloroethene (Vinylidene chloride) 8260B 8260B ppb 0 0 0 0 60 0 μg/L 0 0 0 0 60 0

1,1-Dichloroehtane (Ethylidene dichloride) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

1,2-Dichloroethane (Ethylene dichloride) 8260B 8260B ppb 27 19 0 37 21 0 μg/L 27 19 0 37 21 0

Methylene Chloride (Dichloromethane) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Vinyl Acetate 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Isopropylbenzene (Cumene) 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Acetophenone 8270D 8270D ppb 2340 595 557 3730 923 1250 μg/L 2340 595 557 3730 923 1250

Bis(2-Ethylhexyl)phathalate 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Phenol 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Methanol NCAS507 8015C 8015C ppm 34 18 76 38 154 85 mg/L 34 18 76 38 154 85

Formaldehyde 8315A 8315A ppm 0.519 0.68 0.38 0.53 0.12 0.37 mg/L 0.519 0.68 0.38 0.53 0.12 0.37

Vinyl Chloride 8260B 8260B ppb 4 0 0 0 8 0 μg/L 4 0 0 0 8 0

Chlorobenzene 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

2,4-Dinitrophenol 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Ethylbenzene 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Ehtylene glycol 8015C 8015C ppm 0 0 0 0 0 0 mg/L 0 0 0 0 0 0

Hexane 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Hydroquinone 8270D 8270D ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

1,1,2,2-Tetrachloroethane 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Toluene 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

1,1,2-Trichloroethane 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

2,2,4-Trimethylepentane 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Xylenes 8260B 8260B ppb 0 0 0 0 0 0 μg/L 0 0 0 0 0 0

Methyl Ethyl Ketone (2-Butanone) 8260B 8260B ppb 96 335 5670 105 329 2560 μg/L 96 335 5670 105 329 2560

Methyl Isobutyl Ketone (4-Methyl-2-pentanone) 8260B 8260B ppb 252 133 605 336 129 366 μg/L 252 133 605 336 129 366

Total HAP (VCM by Method 8260B) ppm 51.878 23.402 85.422 51.738 156.355 90.966

Analyte Method Required Method Unit

Shintech WW TX May 2012 ECI
Shintech 

Wastewater (ECI&Accutest) at Addis and Plaquemine

Accutest

22:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 6:00 14:00 14:00

4/10/12 5/8/12 5/9/12 4/10/12 5/8/12 5/9/12 4/10/12 5/8/12 5/9/12 4/10/12 5/8/12 5/9/12

Acetaldehyde 8315A 8315A ppb 840 850 910 1100 940 760 9790 6720 5980 6700 4900 7300

Bromoethane (Vinyl Bromide) 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

1,3-Butadiene 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Benzene 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

2-Chloro-1,3-Butadiene (Chloroprene) 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Chloroethane (Ethyl Chloride) 8260B 8260B ppb 14 115 87 30 100 96 25 0 0 28 9.4 0

Chloromethane (Methyl chloride) 8260B 8260B ppb 15 0 0 3.8 22 0 0 0 0 5.8 0 0

Chloroform 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

1,1-Dichloroethene (Vinylidene chloride) 8260B 8260B ppb 0 0 0 0 36 21 0 0 0 0 0 0

1,1-Dichloroehtane (Ethylidene dichloride) 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0.91 0 0

1,2-Dichloroethane (Ethylene dichloride) 8260B 8260B ppb 63 146 111 53 170 120 29 18 28 31 19 28

Methylene Chloride (Dichloromethane) 8260B 8260B ppb 0 0 0 0 11 6.3 0 0 0 0 0 0

Vinyl Acetate 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Isopropylbenzene (Cumene) 8260B 8260B ppb 0 0 0 0 19 3.6 0 0 0 1.1 0.68 0

Acetophenone 8270D 8270D ppb 2540 4670 2270 2850 5400 3200 4020 3140 3150 3190 4500 5000

Bis(2-Ethylhexyl)phathalate 8270D 8270D ppb 0 0 0 0 0 0 0 0 0 0 0 0

Phenol 8270D 8270D ppb 0 0 0 0 0 0 0 0 0 0 0 0

Methanol 8015C 8015C ppb 57000 71000 73000 75200 113000 95300 319000 58000 58000 23000 26200 17900

Formaldehyde 8315A 8315A ppb 540 700 920 660 1300 1100 367 490 360 610 380 420

Vinyl Chloride 8260B 8260B ppb 60 383 349 130 370 330 111 39 40 120 43 39

Chlorobenzene 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

2,4-Dinitrophenol 8270D 8270D ppb 0 0 0 0 0 0 0 0 0 0 0 0

Ethylbenzene 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Ehtylene glycol 8015C 8015C ppb 0 0 0 0 0 0 0 0 0 0 0 0

Hexane 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Hydroquinone 8270D 8270D ppb 0 0 0 0 0 0 0 0 0 0 0 0

1,1,2,2-Tetrachloroethane 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Toluene 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

1,1,2-Trichloroethane 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

2,2,4-Trimethylepentane 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Xylenes 8260B 8260B ppb 0 0 0 0 0 0 0 0 0 0 0 0

Methyl Ethyl Ketone (2-Butanone) 8260B 8260B ppb 4790 3460 2370 3900 4300 3200 238 127 171 200 200 240

Methyl Isobutyl Ketone (4-Methyl-2-pentanone) 8260B 8260B ppb 1200 1760 695 940 1800 810 508 326 492 440 370 540

Total HAP (VCM by Method 8260B) ppb 67062 83084 80712 84867 127468 104947 334088 68860 68221 34327 36622 31467

Total HAP (VCM by Method 8260B) ppm 67.06 83.08 80.71 84.87 127.47 104.95 334.09 68.86 68.22 34.33 36.62 31.47

Plaquemine

ECI Accutest ECI

Addis

ShintechWW Addis&PLQ Apr-May-12
Sampling Results for Wastewater Stripper

FPC TX PVC Unit: PC 701D

Point Comfort, TX

6.04.12

mg/l=ppm

ug/l =ppb div by 1000 

to get ppm

Date of Sample 5/19/2012 5/20/2012 5/21/2012 5/18/2012 5/21/2012 5/23/2012 Average TOHAP

Date of Testing 5/21/2012 5/21/2012 5/21/2012 5/18/2012 5/21/2012 5/23/2012 For FPC TX PVC:

Sample No. 600-55332-1 600-55332-3 600-55332-5 156429 156527 156530 ppm

Method of Analysis Concentration (mg/l) Note 1 Note 1 Note 1

1 107211 Ethylene glycol. 8015B 13 23 15 17.00

2 67561 Methanol. 8015B 98 72 63 77.67

4 50000 Formaldehyde. 8315A 0.23 0.28 0.17 0.23

5 51285 2,4-dinitrophenol. 8270D ND ND ND

6 98862 Acetophenone. 8270D 6.54 6.11 5.2 5.95

7 117817 Bis(2-ethylhexyl) 

phthalate (DEHP). 8270D 0.0447 0.0722 0.033 0.05

8 123319 Hydroquinone. 0.00

9 108952 Phenol. 0.0524 0.051 0.0478 0.05

10 79345 1,1,2,2-tetrachloroethane. 8260 0.02 0.02 0.02 0.02

11 106990 1,3-butadiene. 8260 0.02 0.02 0.02 0.02

12 540841 2,2,4-trimethylpentane. 8260 0.04 0.04 0.04 0.04

13 71432 Benzene. 8260 0.02 0.02 0.02 0.02

14 108907 Chlorobenzene. 8260 0.02 0.02 0.02 0.02

15 67663 Chloroform. 8260 0.04 0.04 0.04 0.04

16 126998 Chloroprene. 8260 0.02 0.02 0.02 0.02

17 98828 Cumene. 0.04 0.04 0.04 0.04

18 75003 Ethyl chloride 

(Chloroethane). 8260 0.1 0.1 0.1 0.10

19 100414 Ethylbenzene. 8260 0.02 0.02 0.02 0.02

20 107062 Ethylene dichloride (1,2-

Dichloroethane). 8260 0.02 0.02 0.02

0.02

21 75343 Ethylidene dichloride (1,1-

Dichloroethane). 8260 0.02 0.02 0.02

0.02

22 74873 Methyl chloride 

(Chloromethane). 8260 0.1 0.1 0.1 0.10

23 75092 Methylene chloride. 8260 0.02 0.02 0.02 0.02

24 110543 n-Hexane. 8260 0.1 0.1 0.1 0.10

25 108883 Toluene. 8260 0.02 0.02 0.02 0.02

26 71556/790

05 Trichloroethane. 8260 0.02 0.02 0.02 0.02

27 108054 Vinyl acetate. 8260 0.04 0.04 0.04 0.04

28 593602 Vinyl bromide. 8260 0.2 0.2 0.2 0.20

29 75014 Vinyl chloride. 

30 75354 Vinylidene chloride (1,1-

Dichloroethylene). 8260 0.02 0.02 0.02

0.02

31 1330207 Xylenes (isomers and 

mixtures). 8260 0.06 0.06 0.06 0.06

Acetaldehyde 8315A 4.4 6.7 4.7 5.27

Total HAP/Sample 115.63 101.98 82.87 7.5971 7.1932 6.2408 107.17

29 75014 Vinyl chloride. 8260 0.1 0.1 0.316 0.17

FPC TX: Suspension PVC Unit

 Wastewater stripper (PC 701D)

10/28/2013 FPC TX PVC May 2012
Wastewater Stripper

FPC TX SPVC Unit (MV-327A)

 Point Comfort, TX

6.4.12

mg/l=ppm

ug/l =ppb div by 1000 

to get ppm

Date of Sample 5/19/2012 5/20/2012 5/21/2012 5/22/2012 5/23/2012 Average TOHAP

Date of Testing 5/21/2012 5/21/2012 5/21/2012 5/22/2012 5/23/2012 For FPC TX SPVC:

Sample No. 600-55332-7 600-55332-8 600-55332-9 156502 156529 ppm

Method of Analysis Concentration (mg/l) Note1 Note1

1 107211 Ethylene glycol. 8015B 3.1 3.1 3.1 3.10

2 67561 Methanol. 8015B 4.8 25 0.56 10.12

4 50000 Formaldehyde. 8315A 0.12 0.028 0.037 0.06

5 51285 2,4-dinitrophenol. 8270D ND ND

6 98862 Acetophenone. 8270D 0.0501 0.123 0.09

7 117817 Bis(2-ethylhexyl) 

phthalate (DEHP). 8270D 0.00576 0.0254 0.02

8 123319 Hydroquinone. 0.00

9 108952 Phenol. 0.0105 ND 0.01

10 79345 1,1,2,2-tetrachloroethane. 8260 0.005 0.02 0.01

11 106990 1,3-butadiene. 8260 0.005 0.02 0.01

12 540841 2,2,4-trimethylpentane. 8260 0.01 0.04 0.03

13 71432 Benzene. 8260 0.005 0.02 0.01

14 108907 Chlorobenzene. 8260 0.005 0.02 0.01

15 67663 Chloroform. 8260 0.01 0.04 0.03

16 126998 Chloroprene. 8260 0.005 0.02 0.01

17 98828 Cumene. 0.01 0.04 0.03

18 75003 Ethyl chloride 

(Chloroethane). 8260 0.025 0.342 0.18

19 100414 Ethylbenzene. 8260 0.005 0.02 0.01

20 107062 Ethylene dichloride (1,2-

Dichloroethane). 8260 0.005 0.02

0.01

21 75343 Ethylidene dichloride (1,1-

Dichloroethane). 8260 0.005 0.02

0.01

22 74873 Methyl chloride 

(Chloromethane). 8260 0.025 0.448 0.24

23 75092 Methylene chloride. 8260 0.005 0.02 0.01

24 110543 n-Hexane. 8260 0.025 0.1 0.06

25 108883 Toluene. 8260 0.005 0.02 0.01

26 71556/79

005 Trichloroethane. 8260 0.005 0.02 0.01

27 108054 Vinyl acetate. 8260 0.01 0.668 0.34

28 593602 Vinyl bromide. 8260 0.05 0.2 0.13

29 75014 Vinyl chloride. 

30 75354 Vinylidene chloride (1,1-

Dichloroethylene). 8260 0.005 0.02

0.01

31 1330207 Xylenes (isomers and 

mixtures). 8260 0.015 0.06 0.04

Acetaldehyde 8315A 3.5 2.2 0.27 1.99

Total HAP/Sample 11.52 30.328 3.967 0.30636 2.3264 16.59

Final PVC MACT WW TOHAP 

Limit 110 110 110

29 75014 Vinyl chloride. 8260 0.025 77.5 38.76

Note 1= All values in column were reported as "<" the value.

FPC TX: Specialty PVC Unit

 Wastewater stripper (MV-327A): Note that the sampling was done on the Unit's Batch WW Stripper because 

its continuous WW stripper was out of service 

10/28/2013 FPC TX SPVC May 2012
Analyte Prep Method 3-Apr 3-Apr 30-Apr 1-May 2-May 3-May Average 15-Mar 20-Mar 22-Mar 30-Apr 2-May 3-May Average

Acetaldehyde 8015B 3.180 1.850 5.610 4.250 1.180 6.500 3.762 3.400 1.090 4.370 2.560 4.920 6.920 3.877

Ethylene glycol 8015B 0.330 0.330 0.330 0.330 0.330 0.330 0.330 0.580 0.330 0.330 0.330 0.330 0.330 0.372

Methanol 8015B 701.000 194.000 484.000 531.000 113.000 1,630.000 608.833 471.000 178.000 1,070.000 880.000 1,180.000 1,240.000 836.500

Benzene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

Chlorobenzene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

Ethyl chloride 8260B 0.043 0.029 0.107 0.078 0.048 0.083 0.065 0.010 0.003 0.024 0.020 0.020 0.049 0.021

Chloroform 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.002 0.001 0.001 0.020 0.020 0.020 0.011

Methyl chloride 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.011 0.004 0.087 0.020 0.038 0.101 0.043

Chloroproprene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

1,1-Dichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

Ethylene Dichloride 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.005 0.034 0.020 0.020 0.054 0.024

1,1 - Dichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

Ethylbenzene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

Hexane 8260B 0.050 0.050 0.100 0.100 0.050 0.100 0.075 0.050 0.005 0.005 0.100 0.100 0.100 0.060

Cumene 8260B 0.004 0.015 0.020 0.020 0.010 0.020 0.015 0.010 0.000 0.000 0.020 0.020 0.020 0.012

Methylene chloride 8260B 0.023 0.023 0.100 0.100 0.050 0.100 0.066 0.108 0.005 0.005 0.100 0.100 0.100 0.070

1,1,2,2-Tetrachloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.010 0.001 0.001 0.020 0.020 0.020 0.012

Toluene 8260B 0.050 0.050 0.100 0.100 0.050 0.193 0.091 0.050 0.005 0.005 0.100 0.100 0.100 0.060

1,1,1 - Trichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.050 0.001 0.001 0.020 0.020 0.020 0.019

1,1,2 - Trichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 0.015 0.050 0.001 0.001 0.020 0.020 0.020 0.019

Vinyl Acetate 8260B 0.100 0.100 0.200 0.200 0.100 0.200 0.150 0.100 0.010 0.010 0.200 0.200 0.200 0.120

Vinyl chloride 8260B 0.991 0.604 2.360 1.550 0.603 2.300 1.401 0.393 0.110 1.970 0.207 0.353 0.910 0.657

Xylenes 8260B 0.010 0.010 0.020 0.020 0.010 0.055 0.021 0.010 0.001 0.001 0.020 0.020 0.020 0.012

1,3 - Butadiene 5030B 0.080 0.081 0.100 0.100 0.100 0.100 0.094 0.100 0.100 0.100 0.100 0.100 0.100 0.100

2,2,4-Trimethylpentane 5030B 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.012 0.007

Formaldehyde 8315A 0.619 1.080 1.900 1.250 1.260 1.020 1.188 0.695 0.623 0.519 0.486 0.499 0.229 0.509

Bis(2-ethylhexyl)phthalate 3510C 1.000 1.000 1.050 1.320 1.000 1.000 1.062 0.010 0.100 0.100 0.100 0.100 0.100 0.085

2,4 - Dinitrophenol 3510C 1.000 1.000 1.050 1.320 1.000 1.000 1.062 0.010 0.100 0.100 0.100 0.100 0.100 0.085

Phenol 3510C 0.500 0.500 0.526 0.658 0.500 0.500 0.531 0.005 0.050 0.050 0.050 0.050 0.050 0.043

Acetophenone 3510C 3.870 3.470 2.510 2.300 3.010 3.650 3.135 17.200 19.400 14.200 33.800 24.200 29.700 23.083

Hydroquinone 3510C 1.000 1.000 1.270 1.000 1.040 1.020 1.055 1.000 0.100 1.000 1.060 1.000 1.040 0.867

Daily Total 713.971 205.312 501.598 545.941 123.466 1,648.416 623.119 494.924 200.052 1,092.920 919.598 1,212.475 1,280.435 866.738

Red = J Value

Bold = Measured Value

* 2,2,4-Trimethylpentane was not analyzed during the first round of sampling

Plaquemine Aberdeen

Georgia Gulf LA & MS Mar-May-12
8015B_FID 

Prep Method

Compound DF B

Acetaldehyde 1.00 1 05/14/12 13:10

Ethylene glycol 1.00 1 05/17/12 20:42

Methanol 1.00 1 05/14/12 13:10

Analytical Method

Qualifiers/

Definitions

05/29/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Lab ID 1205024-001A Received 05/08/12

Field ID

Water Column

Matrix Aqueous

Sampled

05/07/12 8:30

Analytical Method 8260B 

Prep Method

5030B

Prep Batch

36262

Date/Time Prepped 05/08/12 9:41

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

1 05/08/12 14:45 52199

Limits: 1 05/08/12 14:45 52199

Limits: 1 05/08/12 14:45 52199

Limits: 1 05/08/12 14:45 52199

Limits: 1 05/08/12 14:45 52199

Analytical Method 8015CM1 

Prep Method

5030B

Prep Batch

36295

Date/Time Prepped 05/16/12 8:30

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/15/12 18:41 52240

1 05/15/12 18:41 52240

1 05/15/12 18:41 52240

1 05/15/12 18:41 52240

Analytical Method 8315A 

Prep Method 8315A

05/14/12 9:30

Analytical

8015B_FID Prep Batch

Default Vol/Wt

36326

1 Ml Sample Vol/Wt 1 Ml

2.22 mg/L 0.330 ALS

Units MDL MQL Analyzed

Date/Time Prepped

Date/Time

< 0.330 mg/L 0.330 ALS 52261

17.0

Result

52261

Batch

mg/L 0.330

NFP

Chlorobenzene < 0.00100 mg/L 0.00100 NFP

Benzene < 0.00100

ALS 52261

mg/L 0.00100

NFP

Chloroform < 0.00100 mg/L 0.00100 NFP

Chloroethane < 0.00100 mg/L 0.00100

NFP

Chloropropene < 0.00100 mg/L 0.00100 NFP

Chloromethane < 0.00100 mg/L 0.00100

NFP

1,2-Dichloroethane 0.00355 mg/L 0.00100 NFP

1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP

Ethylbenzene < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP

Isopropylbenzene < 0.00100 mg/L 0.00100 NFP

Hexane < 0.00500 mg/L 0.00500

NFP

1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP

Methylene chloride < 0.00500 mg/L 0.00500

NFP

1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP

Toluene < 0.00500 mg/L 0.00500

NFP

Vinyl acetate < 0.0100 mg/L 0.0100 NFP

1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

NFP

Xylenes, Total < 0.00100 mg/L 0.00100 NFP

Vinyl chloride 0.0296 mg/L 0.00100

NFP

Surrogate: Toluene-d8 95 % 70-130 NFP

Surrogate: Dibromofluoromethane 78 % 70-128

NFP

Surrogate: 1,2-Dichloroethane-d4 85 % 67-136 NFP

Surrogate: 4-Bromofluorobenzene 88 % 71-131

SB

2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB

1,3-Butadiene < 0.100 mg/L 0.100

SB

Surrogate: 4-Bromochlorobenzene 112 % Limits: 50-150 SB

Surrogate: 4-Bromofluorobenzene 103 % Limits: 50-150

Prep Batch 36278 Date/Time Prepped 10/01/12 10:45

WL KY Water Col 5-7-12
Compound B

y

Formaldehyde

0.185

mg/L

0.0250 5

05/11/12 15:19 VC

52238

Analytical Method 8270C 

Prep Method 3510C

Compound B

10 05/27/12 19:18

10 05/27/12 19:18

10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

8270CM30 

Prep Method 3510C

Compound B

Acetophenone 10 05/27/12 19:18

Hydroquinone 10 05/16/12 23:27

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Surrogate: % 10 05/27/12 19:18

Analytical Method

Qualifiers/

Definitions

05/29/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Westlake PVC Corporation

P.O. Box 1027

Calvert City, KY 42029

Project

Description

PVC MACT Site

Calvert City, KY

Lab ID 1205024-001C Received 05/08/12

Field ID

Water Column

Matrix Aqueous

Sampled

05/07/12 8:30

Lab Order Number

12-129-0215

Report of Analysis

Default Vol/Wt

Result

100 mL

Units

Sample Vol/Wt 100 mL

MQL DF

Date/Time

Analyzed

Analytical

Batch

05/14/12 14:00

Analytical

Result Units MQL DF Analyzed Batch

Prep Batch

Default Vol/Wt

36291

1000 mL Sample Vol/Wt 1050 mL

Date/Time Prepped

Date/Time

MJ 52248

Bis(2-ethylhexyl)phthalate < 0.100 mg/L 0.100 MJ 52248

2,4-Dinitrophenol < 0.100 mg/L 0.100

MJ 52248

Phenol < 0.0500 mg/L 0.0500

2-Fluorobiphenyl 81 Limits: 38-107 MJ 52248

4-Terphenyl-d14 92

MJ 52248

Nitrobenzene-d5 67 Limits: 29-110

Limits: 33-122

MJ 52248

Phenol-d6 32 Limits: 10-115 MJ 52248

MJ 52248

2,4,6-Tribromophenol 72 Limits: 40-125

Analyzed Batch

2-Fluorophenol 47 Limits: 20-110

52291

< 0.100 mg/L 0.100 MJ 52291

0.229

MJ 52248

MJ 52291

Prep Batch

Default Vol/Wt

36290

1000 mL Sample Vol/Wt 1020 mL

Date/Time Prepped

Date/Time

05/14/12 10:20

Analytical

Result

mg/L 0.100

Phenol-d6 25 Limits: 10-115

Units MQL DF

MJ

Limits: 20-110 MJ 52291

2,4,6-Tribromophenol 72 Limits: 40-125 MJ 52291

2-Fluorophenol 47

WL KY Water Col 5-7-12
8015B_FID 

DF B

1.00 1 05/14/12 12:27

1.00 1 05/17/12 19:22

1.00 1 05/14/12 12:27

Analytical Method

Qualifiers/

Definitions

06/01/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Analytical Method 8260B 

Prep Method

5030B

Prep Batch

36275

Date/Time Prepped 05/09/12 10:15

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

1 05/09/12 17:11 52213

Limits: 1 05/09/12 17:11 52213

Limits: 1 05/09/12 17:11 52213

Limits: 1 05/09/12 17:11 52213

Limits: 1 05/09/12 17:11 52213

Analytical Method 8015CM1 

Prep Method

5030B

Prep Batch

36295

Date/Time Prepped 05/16/12 8:30

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/15/12 19:08 52240

1 05/15/12 19:08 52240

1 05/15/12 19:08 52240

1 05/15/12 19:08 52240

Analytical Method 8315A 

Prep Method

Compound B

y

Formaldehyde

0.0844

mg/L

0.00500 1

05/11/12 12:25 VC

52238

Analytical Method 8270C 

05/14/12 9:30

Analytical

Compound Result Units MDL MQL Analyzed Batch

Prep Method 8015B_FID Prep Batch

Default Vol/Wt

36326

1 Ml

3.49 mg/L 0.330 ALS

Sample Vol/Wt 1 Ml

Date/Time Prepped

Date/Time

52261

Ethylene glycol 0.460 J mg/L 0.330 ALS 52261

Acetaldehyde

22.6 mg/L

NFP

Chloroethane < 0.00100 mg/L 0.00100 NFP

Chlorobenzene < 0.00100

0.330 ALS 52261

Benzene < 0.00100 mg/L 0.00100 NFP

Methanol

mg/L 0.00100

NFP

Chloromethane < 0.00100 mg/L 0.00100 NFP

Chloroform < 0.00100 mg/L 0.00100

NFP

1,1-Dichloroethane < 0.00100 mg/L 0.00100 NFP

Chloropropene < 0.00100 mg/L 0.00100

NFP

1,1-Dichloroethene < 0.00100 mg/L 0.00100 NFP

1,2-Dichloroethane 0.00231 mg/L 0.00100

NFP

Hexane < 0.00500 mg/L 0.00500 NFP

Ethylbenzene < 0.00100 mg/L 0.00100

NFP

Methylene chloride < 0.00500 mg/L 0.00500 NFP

Isopropylbenzene < 0.00100 mg/L 0.00100

NFP

Toluene 0.00653 mg/L 0.00500 NFP

1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100

NFP

1,1,2-Trichloroethane < 0.00100 mg/L 0.00100 NFP

1,1,1-Trichloroethane < 0.00100 mg/L 0.00100

NFP

Vinyl chloride 0.0306 mg/L 0.00100 NFP

Vinyl acetate < 0.0100 mg/L 0.0100

NFP

Surrogate: Dibromofluoromethane 80 % 70-128 NFP

Xylenes, Total < 0.00100 mg/L 0.00100

NFP

Surrogate: 4-Bromofluorobenzene 95 % 71-131 NFP

Surrogate: Toluene-d8 93 % 70-130

NFP

1,3-Butadiene < 0.100 mg/L 0.100 SB

Surrogate: 1,2-Dichloroethane-d4 82 % 67-136

SB

Surrogate: 4-Bromofluorobenzene 99 % Limits: 50-150 SB

2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500

SB

8315A Prep Batch 36278 Date/Time Prepped 10/01/12 10:45

Surrogate: 4-Bromochlorobenzene 120 % Limits: 50-150

Date/Time

Analyzed

Analytical

Batch

Default Vol/Wt

Result

100 mL

Units

Sample Vol/Wt 100 mL

MQL DF

WL KY Water Col 5-8-12
Prep Method

Compound B

10 05/27/12 19:53

10 05/27/12 19:53

10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

8270CM30 

Prep Method

Compound B

Acetophenone 10 05/27/12 19:53

Hydroquinone 10 05/17/12 0:02

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Surrogate: Limits: 10 05/27/12 19:53

Analytical Method

Qualifiers/

Definitions

06/01/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Westlake PVC Corporation

P.O. Box 1027

Calvert City, KY 42029

Project

Description

WESTLAKE_PVC_PVC_

MACT

Site

Calvert City, KY

Lab ID 1205027-002B Received 05/09/12

Field ID

Water Column

Matrix Aqueous

Sampled

05/08/12 13:10

Lab Order Number

12-130-0211

Report of Analysis

3510C Prep Batch

Default Vol/Wt

36291

1000 mL Sample Vol/Wt 1040 mL

Date/Time Prepped

Date/Time

05/14/12 14:00

Analytical

Result Units MQL DF Analyzed Batch

MJ 52248

Phenol < 0.0500 mg/L 0.0500 MJ 52248

2,4-Dinitrophenol

Bis(2-ethylhexyl)phthalate < 0.100 mg/L 0.100 MJ 52248

< 0.100 mg/L 0.100

MJ 52248

2-Fluorobiphenyl 71 % 38-107 MJ 52248

Nitrobenzene-d5 57 % 29-110

4-Terphenyl-d14 83 % 33-122 MJ 52248

MJ 52248

2-Fluorophenol 4 % * 20-110 MJ 52248

2,4,6-Tribromophenol

Phenol-d6 29 % 10-115 MJ 52248

68 % 40-125

Date/Time Prepped

Date/Time

05/14/12 10:20

Analytical

Result Units MQL DF Analyzed

0.488 mg/L 0.100 MJ 52291

Batch

3510C Prep Batch

Default Vol/Wt

36290

1000 mL Sample Vol/Wt 1030 mL

< 0.100 mg/L MJ 52291

MJ 52291

0.100

% 40-125 MJ 52291

MJ 52291

2,4,6-Tribromophenol 68

2-Fluorophenol 4 % * 20-110

Phenol-d6 28 % 10-115

WL KY Water Col 5-8-12
8015B_FID 

Prep Method

Compound DF B

Acetaldehyde 1.00 1 05/14/12 13:38

Ethylene glycol 1.00 1 05/17/12 20:22

Methanol 1.00 1 05/14/12 13:38

Analytical Method

Qualifiers/

Definitions

05/29/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Lab ID 1205029-001A Received 05/10/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93060

Sampled

05/09/12 13:30

Analytical Method 8260B 

Prep Method

5030B

Prep Batch

36283

Date/Time Prepped 05/10/12 10:27

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

1 05/10/12 13:06 52221

Limits: 1 05/10/12 13:06 52221

Limits: 1 05/10/12 13:06 52221

Limits: 1 05/10/12 13:06 52221

Limits: 1 05/10/12 13:06 52221

Analytical Method 8015CM1 

Prep Method

5030B

Prep Batch

36295

Date/Time Prepped 05/16/12 8:30

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/15/12 19:35 52240

1 05/15/12 19:35 52240

1 05/15/12 19:35 52240

1 05/15/12 19:35 52240

Analytical Method 8315A 

05/14/12 9:30

Analytical

8015B_FID Prep Batch

Default Vol/Wt

36326

1 Ml Sample Vol/Wt 1 Ml

6.96 mg/L 0.330 ALS

Units MDL MQL Analyzed

Date/Time Prepped

Date/Time

< 0.330 mg/L 0.330 ALS 52261

21.9

Result

52261

Batch

mg/L 0.330

NFP

Chlorobenzene < 0.00100 mg/L 0.00100 NFP

Benzene < 0.00100

ALS 52261

mg/L 0.00100

NFP

Chloroform < 0.00100 mg/L 0.00100 NFP

Chloroethane < 0.00100 mg/L 0.00100

NFP

Chloropropene < 0.00100 mg/L 0.00100 NFP

Chloromethane < 0.00100 mg/L 0.00100

NFP

1,2-Dichloroethane < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP

Ethylbenzene < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP

Isopropylbenzene < 0.00100 mg/L 0.00100 NFP

Hexane < 0.00500 mg/L 0.00500

NFP

1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP

Methylene chloride < 0.00500 mg/L 0.00500

NFP

1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP

Toluene < 0.00500 mg/L 0.00500

NFP

Vinyl acetate < 0.0100 mg/L 0.0100 NFP

1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

NFP

Xylenes, Total < 0.00100 mg/L 0.00100 NFP

Vinyl chloride 0.0114 mg/L 0.00100

NFP

Surrogate: Toluene-d8 96 % 70-130 NFP

Surrogate: Dibromofluoromethane 77 % 70-128

NFP

Surrogate: 1,2-Dichloroethane-d4 83 % 67-136 NFP

Surrogate: 4-Bromofluorobenzene 78 % 71-131

SB

2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB

1,3-Butadiene < 0.100 mg/L 0.100

SB

Surrogate: 4-Bromochlorobenzene 97 % Limits: 50-150 SB

Surrogate: 4-Bromofluorobenzene 101 % Limits: 50-150

WL KY Water Col 5-9-12
Prep Method 8315A

Compound B

y

Formaldehyde

0.110

mg/L

0.0250 5

05/11/12 15:30 VC

52238

Analytical Method 8270C 

Prep Method 3510C

Compound B

10 05/27/12 20:28

10 05/27/12 20:28

10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

8270CM30 

Prep Method 3510C

Compound B

Acetophenone 10 05/27/12 20:28

Hydroquinone 10 05/17/12 0:37

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Surrogate: % 10 05/27/12 20:28

Analytical Method

Qualifiers/

Definitions

05/29/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Westlake PVC Corporation

P.O. Box 1027

Calvert City, KY 42029

Project

Description

WESTLAKE_PVC_PVC_

MACT

Site

Calvert City, KY

Lab ID 1205029-001C Received 05/10/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93060

Sampled

05/09/12 13:30

Lab Order Number

12-131-0207

Report of Analysis

10/01/12 10:45

Default Vol/Wt

Result

100 mL

Units

Sample Vol/Wt 100 mL

MQL DF

Date/Time

Analyzed

Analytical

Batch

Prep Batch 36278 Date/Time Prepped

05/14/12 14:00

Analytical

Result Units MQL DF Analyzed Batch

Prep Batch

Default Vol/Wt

36291

1000 mL Sample Vol/Wt 1060 mL

Date/Time Prepped

Date/Time

MJ 52248

Bis(2-ethylhexyl)phthalate < 0.100 mg/L 0.100 MJ 52248

2,4-Dinitrophenol < 0.100 mg/L 0.100

MJ 52248

Phenol < 0.0500 mg/L 0.0500

2-Fluorobiphenyl 63 Limits: 38-107 MJ 52248

4-Terphenyl-d14 71

MJ 52248

Nitrobenzene-d5 46 Limits: 29-110

Limits: 33-122

MJ 52248

Phenol-d6 23 Limits: 10-115 MJ 52248

MJ 52248

2,4,6-Tribromophenol 60 Limits: 40-125

Analyzed Batch

2-Fluorophenol 30 Limits: 20-110

52291

< 0.100 mg/L 0.100 MJ 52291

0.542

MJ 52248

MJ 52291

Prep Batch

Default Vol/Wt

36290

1000 mL Sample Vol/Wt 1040 mL

Date/Time Prepped

Date/Time

05/14/12 10:20

Analytical

Result

mg/L 0.100

Phenol-d6 23 Limits: 10-115

Units MQL DF

MJ

Limits: 20-110 MJ 52291

2,4,6-Tribromophenol 60 Limits: 40-125 MJ 52291

2-Fluorophenol 30

WL KY Water Col 5-9-12
8015B_FID 

Prep Method

Compound DF B

Acetaldehyde 1.00 1 05/14/12 13:24

Ethylene glycol 1.00 1 05/17/12 21:02

Methanol 1.00 1 05/14/12 13:24

Analytical Method

Qualifiers/

Definitions

05/29/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Lab ID 1205032-001A Received 05/11/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93336

Sampled

05/10/12 13:00

Analytical Method 8260B 

Prep Method

5030B

Prep Batch

36300

Date/Time Prepped 05/16/12 9:33

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

1 05/16/12 19:15 52244

Limits: 1 05/16/12 19:15 52244

Limits: 1 05/16/12 19:15 52244

Limits: 1 05/16/12 19:15 52244

Limits: 1 05/16/12 19:15 52244

Analytical Method 8015CM1 

Prep Method

5030B

Prep Batch

36295

Date/Time Prepped 05/16/12 8:30

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/15/12 20:02 52240

1 05/15/12 20:02 52240

1 05/15/12 20:02 52240

1 05/15/12 20:02 52240

Analytical Method 8315A 

05/14/12 9:30

Analytical

8015B_FID Prep Batch

Default Vol/Wt

36326

1 Ml Sample Vol/Wt 1 Ml

< 0.330 mg/L 0.330 ALS

Units MDL MQL Analyzed

Date/Time Prepped

Date/Time

< 0.330 mg/L 0.330 ALS 52261

25.4

Result

52261

Batch

mg/L 0.330

NFP

Chlorobenzene < 0.00100 mg/L 0.00100 NFP

Benzene < 0.00100

ALS 52261

mg/L 0.00100

NFP

Chloroform < 0.00100 mg/L 0.00100 NFP

Chloroethane < 0.00100 mg/L 0.00100

NFP

Chloropropene < 0.00100 mg/L 0.00100 NFP

Chloromethane < 0.00100 mg/L 0.00100

NFP

1,2-Dichloroethane < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP

Ethylbenzene < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP

Isopropylbenzene < 0.00100 mg/L 0.00100 NFP

Hexane < 0.00500 mg/L 0.00500

NFP

1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP

Methylene chloride < 0.00500 mg/L 0.00500

NFP

1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP

Toluene < 0.00500 mg/L 0.00500

NFP

Vinyl acetate < 0.0100 mg/L 0.0100 NFP

1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

NFP

Xylenes, Total < 0.00100 mg/L 0.00100 NFP

Vinyl chloride < 0.00100 mg/L 0.00100

NFP

Surrogate: Toluene-d8 114 % 70-130 NFP

Surrogate: Dibromofluoromethane 103 % 70-128

NFP

Surrogate: 1,2-Dichloroethane-d4 107 % 67-136 NFP

Surrogate: 4-Bromofluorobenzene 95 % 71-131

SB

2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB

1,3-Butadiene < 0.100 mg/L 0.100

SB

Surrogate: 4-Bromochlorobenzene 81 % Limits: 50-150 SB

Surrogate: 4-Bromofluorobenzene 85 % Limits: 50-150

WL KY Water Col 5-10-12
Prep Method 8315A

Compound B

y

Formaldehyde

0.252

mg/L

0.0250 5

05/11/12 16:57 VC

52239

Analytical Method 8270C 

Prep Method 3510C

Compound B

10 05/27/12 21:37

10 05/27/12 21:37

10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

8270CM30 

Prep Method 3510C

Compound B

Acetophenone 10 05/27/12 21:37

Hydroquinone 10 05/17/12 1:12

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Surrogate: % 10 05/27/12 21:37

Analytical Method

Qualifiers/

Definitions

05/29/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Westlake PVC Corporation

P.O. Box 1027

Calvert City, KY 42029

Project

Description

WESTLAKE_PVC_PVC_

MACT

Site

Calvert City, KY

Lab ID 1205032-001C Received 05/11/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93336

Sampled

05/10/12 13:00

Lab Order Number

12-132-0209

Report of Analysis

05/11/12 15:19

Default Vol/Wt

Result

100 mL

Units

Sample Vol/Wt 100 mL

MQL DF

Date/Time

Analyzed

Analytical

Batch

Prep Batch 36285 Date/Time Prepped

05/14/12 14:00

Analytical

Result Units MQL DF Analyzed Batch

Prep Batch

Default Vol/Wt

36291

1000 mL Sample Vol/Wt 1060 mL

Date/Time Prepped

Date/Time

MJ 52248

Bis(2-ethylhexyl)phthalate < 0.100 mg/L 0.100 MJ 52248

2,4-Dinitrophenol < 0.100 mg/L 0.100

MJ 52248

Phenol < 0.0500 mg/L 0.0500

2-Fluorobiphenyl 58 Limits: 38-107 MJ 52248

4-Terphenyl-d14 65

MJ 52248

Nitrobenzene-d5 47 Limits: 29-110

Limits: 33-122

MJ 52248

Phenol-d6 19 Limits: 10-115 MJ 52248

MJ 52248

2,4,6-Tribromophenol 53 Limits: 40-125

Analyzed Batch

2-Fluorophenol 27 Limits: 20-110

52291

< 0.100 mg/L 0.100 MJ 52291

0.550

MJ 52248

MJ 52291

Prep Batch

Default Vol/Wt

36290

1000 mL Sample Vol/Wt 1040 mL

Date/Time Prepped

Date/Time

05/14/12 10:20

Analytical

Result

mg/L 0.100

Phenol-d6 19 Limits: 10-115

Units MQL DF

MJ

Limits: 20-110 MJ 52291

2,4,6-Tribromophenol 53 Limits: 40-125 MJ 52291

2-Fluorophenol 27

WL KY Water Col 5-10-12
8015B_FID 

DF B

1.00 1 05/30/12 12:45

1.00 1 05/30/12 3:28

1.00 1 05/30/12 12:45

Analytical Method

Qualifiers/

Definitions

05/31/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Lab ID 1205035-001A Received 05/15/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93854

Sampled

05/14/12 0:00

Analytical Method 8260B 

Prep Method

5030B

Prep Batch

36300

Date/Time Prepped 05/16/12 9:33

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

1 05/16/12 19:35 52244

Limits: 1 05/16/12 19:35 52244

Limits: 1 05/16/12 19:35 52244

Limits: 1 05/16/12 19:35 52244

Limits: 1 05/16/12 19:35 52244

Analytical Method 8015CM1 

Prep Method

5030B

Prep Batch

36338

Date/Time Prepped 05/22/12 8:31

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/22/12 12:48 52277

1 05/22/12 12:48 52277

1 05/22/12 12:48 52277

1 05/22/12 12:48 52277

Analytical Method 8315A 

05/29/12 10:00

Analytical

Compound Result Units MDL MQL Analyzed Batch

Sample Vol/Wt 1 Ml

Date/Time Prepped

Date/Time

Prep Method 8015B_FID Prep Batch

Default Vol/Wt

36368

1 Ml

52307

Ethylene glycol 0.605 J mg/L 0.330 EV 52307

Acetaldehyde 0.878 J mg/L 0.330 EV

52307

Benzene < 0.00100 mg/L 0.00100 NFP

Methanol 24.4 mg/L 0.330 EV

NFP

Chloroethane < 0.00100 mg/L 0.00100 NFP

Chlorobenzene < 0.00100 mg/L 0.00100

NFP

Chloromethane < 0.00100 mg/L 0.00100 NFP

Chloroform < 0.00100 mg/L 0.00100

NFP

1,1-Dichloroethane < 0.00100 mg/L 0.00100 NFP

Chloropropene < 0.00100 mg/L 0.00100

NFP

1,1-Dichloroethene < 0.00100 mg/L 0.00100 NFP

1,2-Dichloroethane < 0.00100 mg/L 0.00100

NFP

Hexane < 0.00500 mg/L 0.00500 NFP

Ethylbenzene < 0.00100 mg/L 0.00100

NFP

Methylene chloride < 0.00500 mg/L 0.00500 NFP

Isopropylbenzene < 0.00100 mg/L 0.00100

NFP

Toluene < 0.00500 mg/L 0.00500 NFP

1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100

NFP

1,1,2-Trichloroethane < 0.00100 mg/L 0.00100 NFP

1,1,1-Trichloroethane < 0.00100 mg/L 0.00100

NFP

Vinyl chloride < 0.00100 mg/L 0.00100 NFP

Vinyl acetate < 0.0100 mg/L 0.0100

NFP

Surrogate: Dibromofluoromethane 93 % 70-128 NFP

Xylenes, Total < 0.00100 mg/L 0.00100

NFP

Surrogate: 4-Bromofluorobenzene 88 % 71-131 NFP

Surrogate: Toluene-d8 98 % 70-130

NFP

1,3-Butadiene < 0.100 mg/L 0.100 SB

Surrogate: 1,2-Dichloroethane-d4 96 % 67-136

SB

Surrogate: 4-Bromofluorobenzene 83 % Limits: 50-150 SB

2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500

Surrogate: 4-Bromochlorobenzene 82 % Limits: 50-150 SB

WL KY Water Col 5-14-12
Prep Method

Compound B

y

Formaldehyde

0.228

mg/L

0.0250 5

05/18/12 11:31 VC

52269

Analytical Method 8270C 

Prep Method

Compound B

1 05/22/12 23:42

1 05/22/12 23:42

1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

8270CM30 

Prep Method

Compound B

Acetophenone 1 05/22/12 23:42

Hydroquinone 1 05/27/12 23:56

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Surrogate: % 1 05/22/12 23:42

Analytical Method

Qualifiers/

Definitions

05/31/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Westlake PVC Corporation

P.O. Box 1027

Calvert City, KY 42029

Project

Description

WESTLAKE_PVC_PVC_

MACT

Site

Calvert City, KY

Lab ID 1205035-001C Received 05/15/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93854

Sampled

05/14/12 0:00

Lab Order Number

12-136-0208

Report of Analysis

8315A Prep Batch 36299 Date/Time Prepped

3510C Prep Batch

Default Vol/Wt

36316

1000 mL Sample Vol/Wt 1040 mL

Date/Time Prepped

Date/Time

05/21/12 12:00

Analytical

Result

05/17/12 9:00

Default Vol/Wt

Result

100 mL

Units

Sample Vol/Wt 100 mL

MQL DF

Date/Time

Analyzed

Analytical

Batch

Units MQL DF

MJ 52278

Bis(2-ethylhexyl)phthalate < 0.0100 mg/L 0.0100 MJ 52278

Analyzed Batch

2,4-Dinitrophenol < 0.0100 mg/L 0.0100

MJ 52278

Phenol < 0.00500 mg/L 0.00500

2-Fluorobiphenyl 78 Limits: 38-107 MJ 52278

4-Terphenyl-d14 94

MJ 52278

Nitrobenzene-d5 80 Limits: 29-110

Limits: 33-122

MJ 52278

Phenol-d6 25 Limits: 10-115 MJ 52278

MJ 52278

2,4,6-Tribromophenol 66 Limits: 40-125

Date/Time Prepped

Date/Time

05/21/12 16:00

Analytical

2-Fluorophenol 35 Limits: 20-110

Result Units MQL DF Analyzed Batch

< 0.0100

MJ 52278

3510C Prep Batch

Default Vol/Wt

36317

1000 mL Sample Vol/Wt 1040 mL

mg/L 0.0100

MJ 52280

< 0.0100 mg/L 0.0100 MJ 52280

MJ 52280

MJ 52280

2-Fluorophenol 35 Limits: 20-110

Phenol-d6 25 Limits: 10-115

MJ 52280

2,4,6-Tribromophenol 66 Limits: 40-125

WL KY Water Col 5-14-12
8015B_FID 

Prep Method

Compound DF B

Acetaldehyde 1.00 1 05/30/12 13:00

Ethylene glycol 1.00 1 05/30/12 3:39

Methanol 1.00 1 05/30/12 13:00

Analytical Method

Qualifiers/

Definitions

05/31/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Lab ID 1205038-001A Received 05/16/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93991

Sampled

05/15/12 12:10

Analytical Method 8260B 

Prep Method

5030B

Prep Batch

36300

Date/Time Prepped 05/16/12 9:33

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

1 05/16/12 19:55 52244

Limits: 1 05/16/12 19:55 52244

Limits: 1 05/16/12 19:55 52244

Limits: 1 05/16/12 19:55 52244

Limits: 1 05/16/12 19:55 52244

Analytical Method 8015CM1 

Prep Method

5030B

Prep Batch

36338

Date/Time Prepped 05/22/12 8:31

Compound

Default Vol/Wt

Result

10 mL

Units

Sample Vol/Wt 10 mL

MQL DF

Date/Time

Analyzed

Analytical

By Batch

1 05/22/12 11:55 52277

1 05/22/12 11:55 52277

1 05/22/12 11:55 52277

1 05/22/12 11:55 52277

Analytical Method 8315A 

05/29/12 10:00

Analytical

8015B_FID Prep Batch

Default Vol/Wt

36368

1 Ml Sample Vol/Wt 1 Ml

1.10 mg/L 0.330 EV

Units MDL MQL Analyzed

Date/Time Prepped

Date/Time

< 0.330 mg/L 0.330 EV 52307

26.8

Result

52307

Batch

mg/L 0.330

NFP

Chlorobenzene < 0.00100 mg/L 0.00100 NFP

Benzene < 0.00100

EV 52307

mg/L 0.00100

NFP

Chloroform < 0.00100 mg/L 0.00100 NFP

Chloroethane < 0.00100 mg/L 0.00100

NFP

Chloropropene < 0.00100 mg/L 0.00100 NFP

Chloromethane < 0.00100 mg/L 0.00100

NFP

1,2-Dichloroethane < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP

Ethylbenzene < 0.00100 mg/L 0.00100 NFP

1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP

Isopropylbenzene < 0.00100 mg/L 0.00100 NFP

Hexane < 0.00500 mg/L 0.00500

NFP

1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP

Methylene chloride < 0.00500 mg/L 0.00500

NFP

1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP

Toluene < 0.00500 mg/L 0.00500

NFP

Vinyl acetate < 0.0100 mg/L 0.0100 NFP

1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

NFP

Xylenes, Total < 0.00100 mg/L 0.00100 NFP

Vinyl chloride < 0.00100 mg/L 0.00100

NFP

Surrogate: Toluene-d8 105 % 70-130 NFP

Surrogate: Dibromofluoromethane 93 % 70-128

NFP

Surrogate: 1,2-Dichloroethane-d4 100 % 67-136 NFP

Surrogate: 4-Bromofluorobenzene 90 % 71-131

SB

2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB

1,3-Butadiene < 0.100 mg/L 0.100

SB

Surrogate: 4-Bromochlorobenzene 82 % Limits: 50-150 SB

Surrogate: 4-Bromofluorobenzene 84 % Limits: 50-150

WL KY Water Col 5-15-12
Prep Method 8315A

Compound B

y

Formaldehyde

0.358

mg/L

0.0250 5

05/18/12 12:04 VC

52269

Analytical Method 8270C 

Prep Method 3510C

Compound B

1 05/23/12 0:16

1 05/23/12 0:16

1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

8270CM30 

Prep Method 3510C

Compound B

Acetophenone 1 05/23/12 0:16

Hydroquinone 1 05/28/12 0:30

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Surrogate: % 1 05/23/12 0:16

Analytical Method

Qualifiers/

Definitions

05/31/12

2414

WESTLAKE_PVC_AL

* Surrogate Recovery outside accepted limits * I Recoveries affected by interferences or high background

B Analyte detected in the associated Method Blank DF Dilution Factor

E Value exceeds method calibration range H Prepped / Analyzed out of holding time. J Estimated Value Analyte below reported detection limit M Minimum value

MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report

Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)

Westlake PVC Corporation

P.O. Box 1027

Calvert City, KY 42029

Project

Description

WESTLAKE_PVC_PVC_

MACT

Site

Calvert City, KY

Lab ID 1205038-001C Received 05/16/12

Field ID

Water Column

Matrix Aqueous

Sample Number 93991

Sampled

05/15/12 12:10

Lab Order Number

12-137-0205

Report of Analysis

05/17/12 9:00

Default Vol/Wt

Result

100 mL

Units

Sample Vol/Wt 100 mL

MQL DF

Date/Time

Analyzed

Analytical

Batch

Prep Batch 36299 Date/Time Prepped

05/21/12 12:00

Analytical

Result Units MQL DF Analyzed Batch

Prep Batch

Default Vol/Wt

36316

1000 mL Sample Vol/Wt 1030 mL

Date/Time Prepped

Date/Time

MJ 52278

Bis(2-ethylhexyl)phthalate < 0.0100 mg/L 0.0100 MJ 52278

2,4-Dinitrophenol < 0.0100 mg/L 0.0100

MJ 52278

Phenol < 0.00500 mg/L 0.00500

2-Fluorobiphenyl 85 Limits: 38-107 MJ 52278

4-Terphenyl-d14 98

MJ 52278

Nitrobenzene-d5 97 Limits: 29-110

Limits: 33-122

MJ 52278

Phenol-d6 21 Limits: 10-115 MJ 52278

MJ 52278

2,4,6-Tribromophenol 58 Limits: 40-125

Analyzed Batch

2-Fluorophenol 26 Limits: 20-110

52280

< 0.0100 mg/L 0.0100 MJ 52280

< 0.0100

MJ 52278

MJ 52280

Prep Batch

Default Vol/Wt

36317

1000 mL Sample Vol/Wt 1030 mL

Date/Time Prepped

Date/Time

05/21/12 16:00

Analytical

Result

mg/L 0.0100

Phenol-d6 21 Limits: 10-115

Units MQL DF

MJ

Limits: 20-110 MJ 52280

2,4,6-Tribromophenol 58 Limits: 40-125 MJ 52280

2-Fluorophenol 26

WL KY Water Col 5-15-12