### FORM A**-1**

**COMPA NY INFORMA**  **TION**

**I. Parent Company / Legal Corporate Owner Information**

1. Legal Parent Company / Legal Corporate Name 2. Mailing Address 3. City 4. State 5. Zip Code 6. County

7. Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):



## Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 1 06/23/2009

### FORM A**-2**

**FA CILITY INFORMA** 

**TION**

**II. Polyvinyl Chloride and Copolymers (PVC) Production Facility Information**

1. Facility

Name Facility Address a. Street b. City c. State d. Zip Code e. County Facility Coordinates (Decimal Degrees to the 5th decimal place) f. Latitude g. Longitude

2. Number of employees attached to the PVC production facility :

**III. Technical Contact**

1. Name 2. Technical Contact Title 3. Telephone 4. Facsimile 5. Em ail

**IV. Other**

1. Is the facility

a major source of HAP?

2. If No, did the facility

take a limit of its potential HAP em issions to avoid classification as a major source?

3. If the facility

took a limit of its potential HAP

em issions to avoid classification as a major source, provide the date on which the limit was taken (MM/DD/YYYY).

4. Does the facility

manufacture other products in addition to PVC resin?

5. If Yes, list the other products manufactured at the facility

. 6. Are there any

HAP em issions associated with any co-located facilities?



## Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 1 06/23/2009**FORM F-1 CONTROL DEVICES - ABSORBER** 

**Instructions**

1. Complete the form for each absorber used as a control device within the PVC production facility, or for any absorber that emits directly to atmosphere. 2. Refer to "Enclosure 1" for additional instructions and details.

**1** Type of Equipment or Device **2** Equipment of Device ID **3 Type of Absorber**  **4** If other, provide a description: **5** Gas inlet flow rate (dscfm): **6** Gas inlet temperature (°F): **7** Pressure drop (in H 2 O): **8** Liquid-to-gas ratio (gal/10 3acfm): **Inlet scrubbing liquor 9**  Liquor used: **10** pH: **11** Percent solids: **12** Type of alkali added, if any: **13** Addition rate (lb/gal): **14** Wa stewater generation rate (gal/min):

**15** Year Equipment Installed: **16** Equipment Currently Regulated Under (cite regulations):

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 1 06/23/2009**FORM F-2 CONTROL DEVICES - THERMAL OR CATALYTIC OXIDIZER** 

**1** Control Device ID: **2** Number of operating hours per year (hours/year): **3** Is this emergency equipment? **4 Type**  (Thermal Oxidizer or Catalytic Oxidizer) **5** Oxidizer Inlet Flow Rate (dscfm): **6** Average percentage of total flow originating from the production facility:

**7** Combustion chamber temperature (°F): (please note if temperature

me asurement is not in chamber) **8** Excess air (%): **9** Nominal residence time (s): **Heat recovery 10**  Recuperative, percent heat recovery **11** Regenerative, percent heat recovery **12** Design Capacity (Heat Input) (MMBtu/hr): **13** Fuel Basis for Design Capacity: **14** Heat Release Rate (Btu/scf): **15** Is the unit subject to NSPS? **16** If yes, indicate the year: **Start-up Fuel/Material 17**  Start-up fuel: **18** Number of start-ups per year: **19** Typical length of time for start-up (hours): **20** Higher heating value (HHV): **Fuels/Materials Combusted During Normal Operations (include solid, liquid, and gas waste streams) 21**  Fuel 1: **22** Hours used per year: **23** Higher heating value (HHV): **24** Fuel 2: **25** Hours used per year: **26** Higher heating value (HHV): **27** Fuel 3: **28** Hours used per year: **29** Higher heating value (HHV): **30** Fuel 4: **31** Hours used per year: **32** Higher heating value (HHV): **33** Fuel 5: **34** Hours used per year: **35** Higher heating value (HHV):

**36** Year Equipment Installed: **37** Equipment Currently Regulated Under (cite regulations):

Page 1 of 1 **DRAFT** PVC Section 114 Surv ey Part 1 06/23/2009**FORM F-3 CONTROL DEVICES - CONDENSERS** 

**Instructions**

1. Complete the form for each condenser used as a control device within the PVC production facility, or for any condenser that emits directly to atmosphere. 2. Refer to "Enclosure 1" for additional instructions and details.

**1** Type of Equipment or Device **2** Equipment of Device ID **3 Type of Condenser**  **4** If other, provide a description: **5** Is the condenser refrigerated?

**6** Describe the materials condensed:

**7** Describe the fate of the non-condensed gas stream:

**8** Describe the fate of the condensate outlet stream:

**9** Gas inlet flow rate (dscfm): **10** Gas inlet temperature ( ° F): **11** Gas outlet temperature ( ° F): **12** Liquid outlet for rate (gpm):

**15** Year Equipment Installed: **16** Equipment Currently Regulated Under (cite regulations):

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 1 06/23/2009**FORM H EQUIPMENT LEAKS** 

**Instructions**

1. Submit a copy of the leak detection and repair procedures for the PVC production facility and provide responses to the questions below. 2. Refer to "Enclosure 1" for additional instructions and details.

**Table 1. LDAR Program**

**Table 2. Equipment Counts**

**In Source Category**  **Subtotal of Equipment Associated**

**with Closed Vent System(s)** (Subset of count in source category)

In heavy liquid service In gas, vapor, and light liquid service Connectors

In heavy liquid service In gas, vapor, and light liquid service Agitators

In liquid service

In gas and vapor service Pressure Relief Devices

Open ended valves and lines Sampling connection systems Compressors Instrumentation systems Valves

In heavy liquid service

In light liquid service Pumps 40 CFR Part 61, Subpart V Other Federal LDAR Regulation Specify: State LDAR Regulation Specify: Provide the total cost to your facility for conducting the LDAR program at this process unit in 2013:

**Equipment**

In heavy liquid service In gas, vapor, and light liquid service Is there an equipment leak detection and repair (LDAR) program for all equipment at your facility included in the source category? If "No," how are equipment leaks detected and repaired?

If "Yes," is the equipment subject to the requirements of: 40 CFR Part 63, Subpart UU

Page 1 of 1 **DRAFT** PVC Section 114 Survey Part 1 06/23/2009**FORM K-1**

**TA NKS, VESSELS A** **ND PORTA BLE CONTA** **INERS USED FOR FEEDSTOCK STORA GE, PRODUCT STORA** **GE, VENT GA S STORA** **GE, HOLDING A ND WA**  **STEWA TER** 

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) If Other, please specify, being as descriptive as possible: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.

Select the purpose of the equipment:

If Yes, How Are The Emissions Controlled?

**Concentration (ppmvd @ 3% O2)** How is the HAP Concentration Determined? Are HAP Emissions Controlled?

**Individual HA P Present**  Source Equipment Type:

Number of turnovers: Equipment volume (m 3 ):

**Notes** Storage Temperature (°F)

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 2 06/23/2009**FORM L STARTUP, SHUTDOWN, AND MALFUNCTION** 

**Instructions**

1. Complete this form for 2013 only. 2. Submit with your response to this survey, copies of all records of emissions during periods of process startup, shutdown, and malfunctions for 2013 only. 3. Refer to "Enclosure 1" for additional instructions and details.

For a malfunction:

(select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) **Total Emissions During Startup, Shutdown, or Malfunction Event**  We re all of the emissions control devices operating for the entire duration of the startup, shutdown, or malfunction event? Startup, Shutdown or Malfunction?

If startup or shutdown, what was the duration (hours):

Provide a short description of the malfunction and the circumstances:

If No, which control devices were not operating (Control Equipment ID), for how long, and why:

We re permitted emissions limits exceeded?

Provide a description of the procedures used to alert the owner/operator that the malfunction occurred. If the malfunction resulted in a release of emissions, describe any indicators used to signal and/or measure the release. Is there a written startup, shutdown and/or malfunction plan for the process unit?
Provide a description of the systems and equipment in place that function to notify operators that a malfunction **is occurring**

.

Applicable standard or regulation:

Describe what actions, if any, were taken to minimize emissions to the atmosphere:

Page 1 of 1 **DRAFT** PVC Section 114 Survey Part 1 06/23/2009

### FORM P

**PROCESS VENT EMISSIONS TESTING DA TA** 

**Instructions**
1. Copy this worksheet as necessary for pollutants/compounds sampled on different dates. 2. For multiple control devices, users may copy this worksheet within this workbook.

**Control Equipment ID:** Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the PVC process and another process unit (non-PVC) ("combined"):

**Parameter**

Test Date (mm/dd/y

y) **Required Operating Parameters During Test** Total Heat Input (MMBtu/hr) Fuel 1 Feed Rate HHV Fuel 2 Feed Rate HHV Fuel 3 Feed Rate HHV Flow Rate Temperature Moisture O2 CO2 Number of PVC resin grades being produced during sampling Number of PVC resin grades being produced (as percentage of all resin grades produced by facility) **Testing Data** Compound Benzene Chloroethane Chloroform Chloroprene 1,1-Dichloroethane 1,2-Dichloroethane n-Hexane Methy lene chloride Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane

### Viny lidene chloride

Acetophenone Bis(2-ethy lhexy l) phthalate (DEHP) 1,4-Dichlorobenzene 2,4-Dinitrophenol Hexachlorobutadiene Hydroquinone Naphthalene Phenol 1,2,4-Trichlorobenzene Acetaldehyde 1,3-Butadiene Chlorobenzene Chloromethane Cumene Ethy lbenzene Ethy lene glycol Formaldehyde Methanol 1,1,2,2-Tetrachloroethane 2,2,4-Trimethy lpentane Viny l acetate Viny l bromide Xy lenes (isomers and mixtures) Viny l chloride Total hydrocarbon (THC) Methane (CH4)

### CA**S Number Run #1**  **Run #2 Run #3**  **Units**

Enter the CAS number for each pollutant/compound. Do not include dashes. Select appropriate unit from list.



### MMBTU/hr

MMBTU/hr BTU/scf

MMBTU/hr BTU/scf

MMBTU/hr BTU/scf dscfm deg F % % %

%

CAS Number 71432 ppm vd @ 3% O2 75003 ppm vd @ 3% O2 67663 ppm vd @ 3% O2 126998 ppm vd @ 3% O2 75343 ppm vd @ 3% O2 107062 ppm vd @ 3% O2 110543 ppm vd @ 3% O2 75092 ppm vd @ 3% O2 108883 ppm vd @ 3% O2 71556 ppm vd @ 3% O2 79005 ppm vd @ 3% O2 Enter numerical value only.



### Enter numerical value only

.

### 75354 ppm vd @ 3% O2

98862 ppm vd @ 3% O2 117817 ppm vd @ 3% O2 106467 ppm vd @ 3% O2 51285 ppm vd @ 3% O2 87683 ppm vd @ 3% O2 123319 ppm vd @ 3% O2 91203 ppm vd @ 3% O2 108952 ppm vd @ 3% O2 120821 ppm vd @ 3% O2 75070 ppm vd @ 3% O2 106990 ppm vd @ 3% O2 108907 ppm vd @ 3% O2 74873 ppm vd @ 3% O2 98828 ppm vd @ 3% O2 100414 ppm vd @ 3% O2 107211 ppm vd @ 3% O2 50000 ppm vd @ 3% O2 67561 ppm vd @ 3% O2 79345 ppm vd @ 3% O2 540841 ppm vd @ 3% O2 108054 ppm vd @ 3% O2 593602 ppm vd @ 3% O2 1330207 ppm vd @ 3% O2 75014 ppbvd @ 3% O2 N/A ppm vd as propane @ 3% O2 74828 ppm vd @ 3% O2

### Run # 1 Detection **Run # 2 Detection Run # 3 Detection** 

Identify the status of measured values relative to the detection

levels Identify the status of measured

values relative to the detection

levels Identify the status of measured

values relative to the detection

levels

### An **alysis M ethod Used**  **Note(s)**

Wh ere applicable, select the analysis method

used. For all pollutants/compounds, provide any other information supporting information you think is necessary about this test report.



### SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B SW -846 Method 8260B

### SW -846 Method 8260B

SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D SW -846 Method 8270D

US EPA Method 18 US EPA Method 25A

### FORM Q

**TOTA L HYDROCA** **RBON 30-DA Y MONITORING** 

**Instructions**
1. For multiple control devices, users may copy this worksheet within this workbook. 2. Add additional rows as necessary to provide 30 days of monitoring data.

**Control Equipment ID:**

**Date and Time THC Reading**  **CH4 Reading O2 level in exhaust gas** 

MM/DD/YYYY HH:MM (ppmvd as propane @ 3% O2) (ppmvd @ 3% O2) (% by volume, dry) 

### Indicate whether the inlet to the control device is from the PVC process only ("dedicated") or from the PVC process and another process unit (non-PVC) ("combined"):

### Moisture in exhaust **gas PVC Type**  **PVC Grade Control Device**  **Temperature**

(% by volume) (e.g., suspension, dispersion/emulsion, bulk, etc.) (e.g., GP, HMW , LMW , etc.) (degF)

### Control Device

**Operations Indicator THC Monitoring**  **Operations Indicator** (note periods of start-up, Shutdown, malfunctions, or normal operation) (note periods of abnormal operations)