## ATTACHMENT HEADER SHEET
Attachment Number 020 Attachment Name Attachment 20 Chemical #5(PNZT) MVSDS



## Associated PMN Section Number N/A Does notcontain CBI



## Report Number CONSi 10317786855351

### Attachment 20 - 

### Lead Niobium Titanium Zirconium Oxide NSDS REPORT#
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### CONS110317786855351 

## MATERIAL SAFETY DATA SHEET
SECTION 1- PRODUCT INFORMATION Manufacturer's Name: Lockheed Martin Health 3 497Electronics Parkway Flanmmability 0 Syracuse, N.Y. 13088 Reactivity 1 Emergency Telephone (315) 456-3723 8am-5pm -EST (315) 456-2917 24Hours

Information Telephone: (315) 456-3723 Chemical Name: Lead Niobium Titanium Zirconium Oxide TradeName: PZT-5A, LM-5 1 SECTION 11I- HEALTH HAZARD IDENTIFICATION EMERGENCY OVERVIEW Caution may cause eye, skin and respiratory tract irritation. May cause damage to thenervous and immune systems, kidneys, blood andproduce adverse reproductive effects. May cause cancer. ROUTES OFEXPOSURE Inhalation: Inhalation ofdust or fumemay cause respiratory irritation. Ingestion: Ingestion ofdust may result fromhand to mouthcontact or ingestion ofdust SkinContact: Contact with skin may cause irritation. SkinAbsorption: Not expected fromdusts. Eye Contact: Dust or fume contact witheyes may cause irritation. POTENTIALHEALTH EFFECTS Single Acute Overexposure: May produce eye, skinand respiratory tract irritation, effects onthe nervous system and kidneys, gastrointestinal distress and anemia. Common symptoms are a loss of appetite, nausea, vomiting, stomach cramps, constipation, anxiety, difficulty in sleeping, fatigue, moodiness, headache,joint or muscle aches and decreased sexual drive. Extreme overexposure may lead to tremors, convulsions, paralysis, stupor, coma and death. Chronic, Prolonged or Repeated Children have enhanced absorption and retention ofingested lead and are Overexposure particularly sensitive tothe chronic effects oflead, with slowed cognitive development and reduced growth. Mayproduce effects onthe blood, nervous and immune systems, blood pressure, kidneys as well as skinand pulmonary inflammatory tissue masses, rickets-like bone deformities, decreased sperm count and spontaneous abortion. Common symptoms are a loss ofappetite, metallic taste

### Attachment 20 - 

### Lead Niobium Titanium Zirconium Oxide NSDS REPORT#
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### CONS110317786855351
inthe mouth, anxiety, constipation, nausea, pallor, fatigue, weakness, insomnia, headache, nervous irritability, muscle andjoint painor soreness, fine tremors, numbness, dizziness, hyperactivity and abdominal pain. Maternal overexposure may produce lowbirth weight, birth defects and slowed postnatal neurobehavioral development in the offspring. Extreme overexposure maylead to vomiting, drowsiness, stupor, poormemory, restlessness, irritability, tremor, convulsions, coma anddeath. Muscular weakness may develop and progress to paralysis observed as "wrist-drop" and/or "foot-drop". Component Carcinogenicity Lead Compounds Inorganic IARC: Group 2A - Probably Carcinogenic to Humans. NTP: Reasonably anticipatedto be a human carcinogen

EMERGENCY AND FIRST AID PROCEDURES Inhalation: Ifa person breathes large amounts ofthis chemical, move the exposed personto fresh air at once. Ifbreathing has stopped, perform artificial respiration. Keep the affected person warm and at rest. Getmedical attention as soon aspossible. Ingestion: Ifthis chemical has been swallowed, getmedical attention immediately. Skin Ifthis chemical contacts the skin, promptly flush the contaminated skin with soap and water. Ifthis chemical penetrates theclothing, promptly remove the clothing and flush the skin with water. Ifirritation persists after washing, get medical attention. Eye Ifthis chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts ofwater, occasionally lifting the lower and upperlids. Get medical attention immediately.
NOTE TOPHYSICIAN: Damage to the central nervous system in general and thebrain (encephalopathy) in particular is one ofthemost severe forms ofleadpoisoning. The most severe, often fatal, form ofencephalopathy may be preceded by vomiting, a feeling ofdullnessprogressing todrowsiness and stupor, poor memory, restlessness, irritability, tremor, and convulsions. It may arise suddenly with the onset ofseizures, followed by coma, and death. There is a tendency for muscular weakness to develop at the sametime. This weakness may progress to paralysis often observed as a characteristic "wrist drop" or "foot drop" and is a manifestation ofa disease to the nervous system called peripheral neuropathy. Those chronically intoxicated may have gingival lead lines, i.e. blue discoloration. SECTION III-HAZARDOUS INGREDIENTS Material orComponent C.A.S. # Weight % TLV-TWA mglm3 8hr PEL- TW A mg/m3 8hr Lead niobium titanium zirconium oxide 56572-83-9 100 O.05(as Pb) 0.05(asPb)

This product isconsidered a lead compound. Please refer to the Code ofFederal Regulations CFR Title 29 1910.1025 Lead Standard for industrial workers.

### Attachment 20 - 

### Lead Niobium Titanium Zirconium Oxide NSDS REPORT#
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### CONS110317786855351

SECTION IV -PHYSICAL DATA Boiling Point at760mm Hg: NA Specific Gravity (H20 =1): 7.6 -8.1 Melting Point: 1350C Solubility in H20 (g/l): 0.05 Vapor Pressure (mm Hg): % NA Evaporation Rate: NA Volatiles byVolume: NA Molecular Weight 321 to 347 Appearance and Odor: Yellow or Tan or Reddish Tan Powder, Odorless SECTION V -FIRE AND EXPLOSION HAZARD DATA LEL: NA UEL: NA Flash PointFlammable NA Auto ignition Temperature NA Limits: Extinguishing NA Media Water, C02 and Dry Chemical Special Fire Fighting Procedures: Wear full body protective clothing, full face piece andNIOSH/MSHA approved Positive pressure self-contained breathing apparatus. Unusual Fire and Explosion Hazards: Fume, vapor and/or dust may occur and are considered toxic andrespiratory irritants. Mayreact with strong oxidizing agents. SECTION VI- REACTIVITY DATA Stability Stable to 800 C Incompatibilities: Strong Acids, Conditions to Avoid: Donot heat in thepresence ofstrong acids as dissolutionoflead may occur. Hazardous Decomposition Products: Elevated temperatures (above 800C) or fire may produce lead oxide fume, vapor or dust. Hazardous Polymerization: Will notoccur. SECTION VII- SPECIAL PROTECTION Respiratory Protection: A NIOSHJ approved respirator with P100 filters shall be worn when airborne exposures may exceed OSHA/ACGIH permissible air concentrations. Protective Gloves: Latex or nitrile gloves required. Eye Protection: Safety glasses are recommended for protection against exposures to dusts. Protective Clothing: Full body clothing should be worn to prevent potential exposure to skin. IfleadPEL or TLV is exceeded, protective clothing shall be provided in accordance with OSHA Standard 29 CFR 1910.1025. Ventilation: Sufficient mechanical ventilation (general and/or local exhaust) shall be provided to maintain exposures below permissible airconcentrations. SECTION VIII- SPILL OR LEAKPROCEDURES Steps to Take in theEvent ofa Spill or Release

### Attachment 20 - 

### Lead Niobium Titanium Zirconium Oxide NSDS REPORT#
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### CONS110317786855351
In theevent ofa spill or leak, avoid inhalation ofdust or fume. Gloves, goggles and respirators should be worn during clean-up. Small spills shouldbe vacuumed using a high efficiency filter vacuum. Donot use dry sweeping or compressed air. Waste Disposal Method: Waste shall be collected and disposed ofin accordance with all local, state and federal regulations. Waste may also be recycled in accordance with local, state and federal regulations.. Neutralizing Materials: NotApplicable SECTION IX - SPECIAL PRECAUTIONS Food and drink shall notbe consumed in areas ofuse. Tobacco products and cosmetics shall notbe used in areas ofuse. Always wash thoroughly after handling. Dirty shoes and clothing should notleave the workplace. Store thisproduct away from all foods and feeds. Do notreuse containers. Containers may retain product residues. All labeled precautions mustbe observed. This product is intended for industrial use only. Keep away from children. Store in dry area. Avoid contact with acids andbases. SECTION X - TRANSPORTATION INFORMATION UN Number - UN2291I Proper Shipping Name - Lead Compound, soluble, n.o.s. Hazard Class - 6.1 Packing Group - PG III SECTION XI- DEFINITIONS TLV/TWA Threshold LimitValue - Time Weighted Average (American Conference of Governmental Industrial Hygienists) PEL Permissible Exposure Limit (Occupational Safety &Health Administration LEL Lower Explosive Limit UEL Upper Explosive Limit NA Not Applicable NE NotEstablished PREPARED BY: Lockheed Martin 

### 497 Electronics Parkway Syracuse, New York 13088 MSDS Revision Date: 1/2011 The information accumulated and setforth herein is believed to be accurate as ofthedate hereof. Lockheed Martin makes no warranty with respect thereto and disclaims all liability from reliance thereon. Recipients are advised to confirm in advance that the information iscurrent, applicable, and suitable for theirparticular circumstances.RECIPIENT: PEEL HERE

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