## Wastew**ater Ty pe** 

**Flow Diagram Equipment No. Date Sampled**  12/17/2009 12/17/2009 12/12/2009 3/12/2012 3/13/2012 3/14/2012 3/15/2012 3/28/2012 3/29/2012 Hits **Lab Report Number** JA32868 JA32868 JA32858 JB1063 JB1064 JB1065 JB1067 JB-2388 JB-2389 Duplicate **Sample Ty pe**  Composite - indicates lab Composite Composite Composite Grab Grab Grab Grab Grab Grab combination of 3 grabs **Compound CA** **S No. Method of A** **naly sis**  1Ethylene Glycol 107-21-1DAI by GC/MS 8260B SIM ND(120) ND(120) ND(120) ND(100) ND(100) ND(100) ND(100) ND(100) ND(100) 2Benzene 71-43-2SW846 8260 B ND(0.23) ND(2.3) ND(0.23) ND(0.22) ND(0.22) ND(1.1) ND(2.2) ND(0.44) ND(0.55) 31,3 Butadiene 106-99-0SW846 8260 B NA NA NA New ND(0.33) ND(0.33) ND(1.6) ND(3.3) ND(0.66) ND(0.82) 4Chlorobenzene 108-90-7SW846 8260 B NA NA NA New ND(0.22) ND(0.22) ND(1.1) ND(2.2) ND(0.45) ND(0.56) 5Chloroethane 75-00-3SW846 8260 B **14 9.9**  **68 1.8**  **5.9** ND(1.8) **10 11**  ND(0.92) **6** 6Chloroform 67-66-3SW846 8260 B ND(0.23) ND(2.3) **0.25** ND(0.21) **0.4** ND(1.0) ND(2.1) ND(0.41) ND(0.52) **2** 7Chloromethane 74-87-3SW846 8260 B **16 13**  **79 1.6**  **5.4** ND(1.1) **7.7 1**  **1 7**  8Chloroprene 126-99-8SW846 8260 B NA NA NA New ND(0.35) ND(0.35) ND(1.7) ND(3.5) ND(0.69) ND(0.87) 91,1-Dichloroethane 75-34-3SW846 8260 B ND(0.29) ND(2.9) **0.57** ND(0.19) ND(0.19) ND(0.96) ND(1.9) ND(0.38) ND(0.48) 101,2-Dichloroethane 107-06-2SW846 8260 B **39 51**  **132 18**  **37 4.7**  **67 5**  **3 8**  111,1-Dichloroethene 75-35-4SW846 8260 B ND(0.40) ND(4.0) ND(0.4) ND(0.28) ND(0.28) ND(1.4) ND(2.8) ND(0.56) ND(0.70) 12Ethylbenzene 100-41-4SW846 8260 B NA NA NA New ND(0.21) ND(0.21) ND(1.1) ND(2.1) ND(0.42) ND(0.53) 13Hexane 110-54-3SW846 8260 B NA NA NA New ND(1.4) ND(1.4) ND(6.8) ND(14) ND(2.7) ND(3.4) 14Isopropylbenzene (cumene) 98-82-8SW846 8260 B ND(0.57) ND(5.7) ND(0.57) ND(0.19) ND(0.19) ND(0.97) ND(1.9) ND(0.39) ND(0.49) 15Methylene chloride 75-09-2SW846 8260 B NA NA NA New ND(0.20) ND(0.20) ND(1.0) ND(2.0) ND(0.40) ND(0.51) 161,1,2,2-Tetrachloroethane 79-34-5SW846 8260 B NA NA NA New ND(0.20) ND(0.20) ND(1.0) ND(2.0) ND(0.40) ND(0.50) 17Toluene 108-88-3SW846 8260 B ND(0.30) ND(3.0) ND(0.30) ND(0.15) ND(0.15) ND(0.73) ND(1.5) ND(0.29) ND(0.36) 181,1,1-Trichloroethane 71-55-6SW846 8260 B NA NA NA New ND(0.24) ND(0.24) ND(1.2) ND(2.4) ND(0.47) ND(0.59) 191,1,2-Trichloroethane 79-00-5SW846 8260 B NA NA NA New ND(0.23) ND(0.23) ND(1.2) ND(2.3) ND(0.46) ND(0.58) 202,2,4-Trimethylpentane 540-84-1SW846 8260 B ND(0.44) ND(4.4) ND(0.44) ND(0.16) ND(0.16) ND(0.79) ND(1.6) ND(0.32) ND(0.40) 21Vinyl Acetate 108-05-4SW846 8260 B NA NA NA New ND(2.6) ND(2.6) ND(13) ND(26) ND(5.2) ND(6.5) 22Vinyl Bromide 593-60-2SW846 8260 B ND(0.10) ND(1.0) ND(0.10) ND(0.31) ND(0.31) ND(1.5) ND(3.1) ND(0.61) ND(0.77) 23Vinyl Chloride 75-01-4SW846 8260 B **172 116**  **377 12**  **45 10**  **35 163**  **7 8**  24Xylene (Total) 1330-20-7SW846 8260 B ND(0.25) ND(2.5) ND(0.25) ND(0.17) ND(0.17) ND(0.87) NS(1.7) ND(0.35) ND(0.43) 252,4-Dinitrophenol 51-28-5SW846 8270 D NA NA NA New ND(17) ND(17) ND(17) ND(17) ND(33) ND(17) 26Phenol 108-95-2SW846 8270 D ND(0.58) ND(0.58) ND(0.58) ND(1.3) ND(1.3) ND(1.3) **4.3** ND(2.6) ND(1.3) **1** 27Acetophenone 98-86-2SW846 8270 D **1,530 1,470**  **967 17**  **12** ND(0.29) **1,500 3**  ND(0.29) **6** 28bis(2-Ethylhexylphthalate 117-81-7SW846 8270 D NA NA NA New ND(0.59) ND(0.59) ND(0.59) ND(0.59) ND(1.2) ND(0.59) 29Hydroquinone 123-31-9SW846 8270 D ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(10) ND(5.0) 30Methanol 67-56-1 SW846-8015C (DAI) **8,370 17,500**  **12,400 5,090**  **3,370 1,610**  **10,900 3,610**  **6,430 8**  31Formaldehyde 50-00-0SW846 8315A **570 194**  **353 325**  **283 315**  **501 390**  **497 8**  32Acetaldehyde 75-07-0SW846 8315A **6,000 4,860**  **76,900 5,330**  **5,840 4,640**  **6,490 6,360**  **4,770 8**  **16,539 24,097**  **90,900 10,783**  **9,553 6,570**  **19,480 10,380**  **11,701 Total non-VCM HA** **P mg/L (ppm)**  **17 24**  **91 11**  **10 7**  **19 10**  **12** Detected values are reported in bold MDL values are reported in italic font for ND values. Note that Detection Limits (DLs) varied with dilution factors Lab analyst determined need for dilutions based on interferences seen on chromatogram and physical properties of the sample **Concentration (ug/l) Concentration (ug/l)**  **Concentration (ug/l) Deer Park Process Wastew** **ater Deer Park Process Wastew** **ater Deer Park Process Wastew** **ater Wastew** **ater stripper (U-316) and discharge stream W-308 to bioplant collection sump**  **Wastew ater stripper (U-316) and discharge stream**  **W-308 to bioplant collection sump Wastew** **ater stripper (U-316) and discharge stream W-308 to bioplant collection sump** 

OV Deer Park WW Mar 2012

### Resin Sampling Results for Wastewater Stripper **OxyVinyls, LP Pasadena, TX** 
**Wastewater Type Flow Diagram Equipment No.**  **Flow Diagram wastewater Stream number** 

**Date Sampled** 12/22/2009 12/29/2009 1/6/2010 1/12/2010 1/19/2010 1/28/2010 **Lab Report Number** JA35458 JA35466 JA35476 JA35488 JA35502 JA36409 **Sample Type** Composite - indicates lab Composite CompositeCompositeCompositeCompositeComposite combination of 3 grabs **Compound CAS No.**  **Method of Analysis** 1Ethy lene Gly col 107-21-1 DAI by GC/MS 8260 SIM ND(120) ND(120) ND(120) ND(120) ND(120) ND(120) 2Benzene 71-43-2 SW846 8260 B ND(1.2) ND(1.2) ND(4.7) ND(12) ND(1.2) ND(59) 31,3 Butadiene 106-99-0 SW846 8260 B NA NA NA NA NA NA 4Chlorobenzene 108-90-7 SW846 8260 B NA NA NA NA NA NA 5Chloroethane 75-00-3 SW846 8260 B ND(1.9) **2.8** ND(7.4) ND(19) **5.8** ND(93) 6Chloroform 67-66-3 SW846 8260 B ND(1.2) **4.3** ND(4.7) ND(12) ND(1.2) ND(59) 7Chloromethane 74-87-3 SW846 8260 B ND(1.4) ND(1.4) ND(5.8) ND(14) ND(1.4) ND(72) 8Chloroprene 126-99-8 SW846 8260 B NA NA NA NA NA NA 91,1-Dichloroethane 75-34-3 SW846 8260 B ND(1.4) ND(1.4) ND(5.7) ND(14) ND(1.4) ND(72) 101,2-Dichloroethane 107-06-2 SW846 8260 B **2.7 2.8**  ND(6.7) ND(17) **2.6** ND(83) 111,1-Dichloroethene 75-35-4 SW846 8260 B ND(2.0) ND(2.0) ND(7.9) ND(20) ND(2.0) ND(99) 12Ethy lbenzene 100-41-4 SW846 8260 B NA NA NA NA NA NA 13Hexane 110-54-3 SW846 8260 B NA NA NA NA NA NA 14Isopropylbenzene (cumene) 98-82-8 SW846 8260 B ND(2.9) ND(2.9) ND(11) ND(29) ND(2.9) ND(140) 15Methylene chloride 75-09-2 SW846 8260 B NA NA NA NA NA NA 161,1,2,2-Tetrachloroethane 79-34-5 SW846 8260 B NA NA NA NA NA NA 17Toluene 108-88-3 SW846 8260 B ND(1.5) ND(1.5) ND(6) ND(15) ND(1.5) ND(75) 181,1,1-Trichloroethane 71-55-6 SW846 8260 B NA NA NA NA NA NA 191,1,2-Trichloroethane 79-00-5 SW846 8260 B NA NA NA NA NA NA 202,2,4-Trimethy

lpentane 540-84-1 SW846 8260 B ND(2.2) ND(2.2) ND(8.8) ND(22) ND(2.2) ND(110) 21Viny l Acetate 108-05-4 SW846 8260 B NA NA NA NA NA NA 22Viny l Bromide 593-60-2 SW846 8260 B ND(0.50) ND(0.50) ND(2.0) ND(5.0) ND(0.50) ND(25) 23Viny l Chloride 75-01-4 SW846 8260 B **40 38**  **21 37**  **72** ND(110) 24Xy lene (Total) 1330-20-7 SW846 8260 B ND(1.3) ND(1.3) ND(5.0) ND(13) ND(1.3) ND(63) 252,4-Dinitrophenol 51-28-5 SW846 8270 C NA NA NA NA NA NA 26Phenol 108-95-2 SW846 8270 C ND(0.58) ND(0.58) ND(0.58) ND(0.58) ND(0.64) ND(0.62) 27Acetophenone 98-86-2 SW846 8270 C **5,220 9,110**  **4,790 9,010**  **9,190 9,950**  28bis(2-Ethy

lhexy lphthalate 117-81-7 SW846 8270 C NA NA NA NA NA NA 29Hy droquinone 123-31-9 SW846 8270 C ND(5.0) ND(5.0) ND(5.0) ND(5.0) ND(5.6) ND(5.4) 30Methanol 67-56-1 SW846-8015 (DAI) **656,000 858,000**  **806,000 490,000**  **265,000 620,000**  31Formaldehy

de 50-00-0 SW846 8315A **25** ND(6.3) **162** ND(6.3) ND(6.3) ND(6.3) 32Acetaldehy

de 75-07-0 SW846 8315A **844 10**  **8,370 85**  ND(4.8) **2,110 662,092**  **867,130 819,322**  **499,095 274,198**  **632,060 Total non-VCM HAP**  **mg/L (ppm) 660**  **870 820**  **500 270**  **630**

Detected values are reported in bold font. MDL values are reported in italic font for ND values. Note that Detection Limits (DLs) varied with dilution factors Lab analyst determined need for dilutions based on interferences seen on chromatogram and physical properties of the sample **Process water Wastewater stripper (U-1202)**  **Discharge of the wastewater stripper (Stream W-1221) that flows to biological treatment** 

**Concentration (ug/l)**

The samples were analy

zed by Accutest Laboratories. OV Pasadena WW Dec 2009-10

## An**alytical Sampling Results for Sump, Column, Centrate and Scrubber Wastewater OxyVinyls, LP**  **Pedricktown, NJ Wastewater Type**  **LP Sump LP Sump**  **Stripping Column**  **Flow Diagram Equipment No.**  U-602 U-602 U-203
**Flow Diagram wastewater Stream number**  W-604 W-604 Equipment Opening condensate to W-604


## Suspension Grade Med and High Molecular Wt

. General

Purpose Med and

High Molecular Wt

. **Date Sampled** 11/4/2009 1/17/2009 11/4/2009 **Date Received by Lab** 11/5/2009 1/17/2009 11/5/2009 **Lab Report Number** JA32106 JA37850 JA32106 **Compound CA** **S No. Me** **thod of A nalysis**  Ethylene Glycol 107-21-1 DAI by GC/MS 8260 SIM ND(120) ND(120) ND(120) Benzene 71-43-2 SW846 8260 B ND(0.23) ND(0.23) ND(1.2) Chloroethane 75-00-3 SW846 8260 B ND(0.37) **3.0 59.0**  Chloroform 67-66-3 SW846 8260 B ND(0.23) ND(0.23) ND(1.2) Chloromethane 74-87-3 SW846 8260 B ND(0.29) ND(0.29) **13.4** 1,1-Dichloroethane 75-34-3 SW846 8260 B ND(0.29) ND(0.29) ND(1.4) 1,2-Dichloroethane 107-06-2 SW846 8260 B ND(0.33) ND(0.33) ND(1.7) 1,1-Dichloroethene 75-35-4 SW846 8260 B ND(0.40) ND(0.40) ND(2.0) Isopropylbenzene 98-82-8 SW846 8260 B **2.3** ND(0.57) **17.6** Toluene 108-88-3 SW846 8260 B ND(0.30) ND(0.30) ND(1.5) 2,2,4-Trimethylpentane 540-84-1 SW846 8260 B ND(0.44) ND(0.44) ND(2.2) Vinyl Bromide 593-60-2 SW846 8260 B ND(0.10) ND(0.10) ND(0.50) Vinyl Chloride 75-01-4 SW846 8260 B **2.5 23.4**  **2,960** Xylene (Total) 1330-20-7 SW846 8260 B ND(0.25) ND(0.25) ND(1.3) Phenol 108-95-2 SW846 8270 C SW846 3510C **23.8 1.7 J**  **25.3** Acetophenone 98-86-2 SW846 8270 C SW846 3510C **1,270 255**  **1,310** Hydroquinone 123-31-9 SW846 8270 C SW846 3510C ND(5.0) ND(25) ND(5.0) Methanol 67-56-1 SW846-8015 (DAI) **993 1,630**  **645** Formaldehyde 50-00-0 SW846 8315 SW846 8315 **610 175**  **277 J** Acetaldehyde 75-07-0 SW846 8315 SW846 8315 **1,040 411**  **1,830** Detected values are reported in bold font. Values reported with a "J" indicate an estimated value. **Concentration (ug/l)**

The samples were analyzed by Accutest Laboratories. OV Pedricktow n WW Nov 200910/28/2013

d Pedricktown Henry Plant POP4 POP5 POP6 Plant POH4 POH5 POH6 Client Sample ID: TRIP BLANK P4P WD4 P5P WD5 P6P WD6 TRIP BLANK P4H WD4 P5H WD5 P6H WD6 Lab Sample ID: JB4758-2 JB4758-1 JB4759-1 JB4760-1 JB4755-2 JB4755-1 JB4756-1 JB4757-1 Date Sampled: 5/1/2012 5/1/2012 5/2/2012 5/3/2012 5/1/2012 5/1/2012 5/2/2012 5/3/2012

GC/MS Volatiles By Sim Ethylene Glycol ppm 0.000063 U0.000063U0.000063U0.000063U 0.000063 U0.000063U0.000063U0.000063U
GC/MS Volatiles

Benzene ppm 0.00022 U 0.0011 U 0.00055 U 0.0022 U 0.00022 U 0.00022 U 0.00022 U 0.00022U 1,3-Butadiene ppm 0.00033 U 0.0016 U 0.00082 U 0.0033 U 0.00033 U 0.00033 U 0.00033 U 0.00033 U Chlorobenzene ppm 0.00022 U 0.0011 U 0.00056 U 0.0022 U 0.00022 U 0.00022 U 0.00022 U 0.00022U Chloroethane ppm 0.00037 U 0.144 0.106 0.261 0.00037 U 0.144 0.0176 0.0927 Chloroform ppm 0.00021 U 0.001 U 0.00052 U 0.0021 U 0.00021 U 0.00021 U 0.00021 U 0.00021 U Chloromethane ppm 0.00022 U 0.395 0.253 0.829 0.00022 U 0.145 0.0291 0.0866 Chloroprene ppm 0.00035 U 0.0017 U 0.00087 U 0.0035 U 0.00035 U 0.00035 U 0.00035 U 0.00035U 1,1-Dichloroethane ppm 0.00019 U 0.00096 U 0.00048 U 0.0019 U 0.00019 U 0.00019 U 0.00019 U 0.00019U 1,2-Dichloroethane ppm 0.00018 U 0.0073 0.0074 0.0151 0.00018 U 0.0779 0.0168 0.0768 1,1-Dichloroethene ppm 0.00028 U 0.0014 U 0.0007 U 0.0028 U 0.00028 U 0.00028 U 0.00028 U 0.00028U Ethylbenzene ppm 0.00021 U 0.0011 U 0.00053 U 0.0021 U 0.00021 U 0.00021 U 0.00021 U 0.00021 U Hexane ppm 0.0014 U 0.0068 U 0.0034 U 0.014 U 0.0014 U 0.0014 U 0.0014 U 0.0014 U Isopropylbenzene ppm 0.00019 U 0.00097 U 0.00049 U 0.0019 U 0.00019 U 0.00019 U 0.00019 U 0.00019U Methylene chloride ppm 0.0002 U 0.001 U 0.00051 U 0.002 U 0.0002 U 0.0002 U 0.0002 U 0.0002 U 1,1,2,2-Tetrachloroethane ppm 0.0002 U 0.001 U 0.0005 U 0.002 U 0.0002 U 0.0002 U 0.0002 U 0.0002 U Toluene ppm 0.00015 U 0.00073 U 0.00036 U 0.0015 U 0.00015 U 0.00015 U 0.00015 U 0.00015U 1,1,1-Trichloroethane ppm 0.00024 U 0.0012 U 0.00059 U 0.0024 U 0.00024 U 0.00024 U 0.00024 U 0.00024U 1,1,2-Trichloroethane ppm 0.00023 U 0.0012 U 0.00058 U 0.0023 U 0.00023 U 0.00023 U 0.00023 U 0.00023 U 2,2,4-Trimethylpentane ppm 0.00016 U 0.00079 U 0.0004 U 0.0016 U 0.00016 U 0.00016 U 0.00016 U 0.00016U Vinyl Acetate ppm 0.0026 U 0.013 U 0.0065 U 0.026 U 0.0026 U 0.0026 U 0.0026 U 0.0026 U Vinyl Bromide ppm 0.00031 U 0.0015 U 0.00077 U 0.0031 U 0.00031 U 0.00031 U 0.00031 U 0.00031 U Xylene (total) ppm 0.00017 U 0.00087 U 0.00043 U 0.0017 U 0.00017 U 0.00017 U 0.00017 U 0.00017U
GC/MS Semi-volatiles 2,4-Dinitrophenol ppm NA 0.017 U 0.017 U 0.018 U NA 0.018 U 0.017 U 0.018 U Phenol ppm NA 0.0013 U 0.0013 U 0.0014 U NA 0.0014 U 0.0013 U 0.0029 Acetophenone ppm NA 0.767 0.699 0.554 NA 0.0201 0.162 0.11 bis(2-Ethylhexyl)phthalate ppm NA 0.00059 U 0.00061 U 0.00065 U NA 0.0032 0.00061 U 0.0032 Hydroquinone ppm NA 0.005 U 0.0052 U 0.0056 U NA 0.0054 U 0.0052 U 0.0055 U

GC Volatiles (SW846-8015 (DAI))
Methanol ppm NA 68.4 51.2 29.5 NA 5.16 1.99 9.55 Ethylene Glycol ppm NA 10 U 10 U 10 U NA 10 U 10 U 10 U GC Semi-volatiles (SW846 8315) Formaldehyde ppm NA 0.0543 0.0655 0.0751 NA 0.162 0.851 0.564 Acetaldehyde ppm NA 3 2.49 2.79 NA 0.0481 0.194 0.26 Vinyl Chloride, Method 107 PPM NA 0.61 2.41 1.91 NA 0.123 0.158 0.078

Page 1 PolyOne WW NJ & IL May 2012

### Wastewater (Accutest) **Stripper 1 Stripper 2**  **Stripper 3 Stripper 1**  **Stripper 2 Stripper 3**  **Stripper 1 Stripper 2** **Stripper 3 Stripper 1**  **Stripper 2 Stripper 3**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **5/8/12 5/8/12**  **5/8/12 5/9/12**  **5/9/12 5/9/12**  **5/8/12 5/8/12**  **5/8/12 5/9/12**  **5/9/12 5/9/12**  **Acetaldehyde** 8315A 8315A **ppm** 9.6 6.2 3.8 9.7 6.5 1.7 mg/L 9.6 6.2 3.8 9.7 6.5 1.7 **Bromoethane (Viny l Bromide)**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **1,3-Butadiene** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Benzene** 8260B 8260B **ppb** 0 0 0 0 0 3 mg/L 0 0 0 0 0 0.003 **2-Chloro-1,3-Butadiene (Chloroprene)** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Chloroethane (Ethy l Chloride)**  8260B 8260B **ppb** 0 0 0 2.3 0 9.1 mg/L 0 0 0 0.0023 0 0.0091 **Chloromethane (Methy l chloride)**  8260B 8260B **ppb** 6 17 0 9.4 0 0 mg/L 0.006 0.017 0 0.0094 0 0 **Chloroform** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **1,1-Dichloroethene (Viny lidene chloride)**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **1,1-Dichloroehtane (Ethy lidene dichloride)**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **1,2-Dichloroethane (Ethy lene dichloride)**  8260B 8260B **ppb** 26 21 6.2 44 23 0 mg/L 0.026 0.021 0.0062 0.044 0.023 0 **Methy lene Chloride (Dichloromethane)**  8260B 8260B **ppb** 0 0 15 0 9.8 16 mg/L 0 0 0.015 0 0.0098 0.016 **Viny l Acetate**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Isopropy lbenzene (Cumene)**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Acetophenone** 8270D 8270D **ppb** 3500 1200 1400 4900 1400 1700 μg/L 3.5 1.2 1.4 4.9 1.4 1.7 **Bis(2-Ethy lhexyl)phathalate**  8270D 8270D **ppb** 0 0 0.79 0 0 0 μg/L 0 0 0.00079 0 0 0 **Phenol** 8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Methanol** 8015C 8015C **ppm** 49.7 0 31.8 49.9 0 32.4 μg/L 49700 0 31800 49900 0 32400 **Formaldehy de**  8315A 8315A **ppm** 0.72 0.99 0.6 1.3 1.3 0.38 mg/L 0.72 0.99 0.6 1.3 1.3 0.38 **Viny l Chloride**  8260B 8260B **ppb** 4.3 15 0 6.5 5.4 0 mg/L 0.0043 0.015 0 0.0065 0.0054 0 **Chlorobenzene** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **2,4-Dinitrophenol** 8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Ethy lbenzene**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Ehty lene gly** **col** 8015C 8015C **ppm** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Hexane** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Hy droquinone**  8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **1,1,2,2-Tetrachloroethane** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Toluene** 8260B 8260B **ppb** 0 0.27 0 0 0 11 mg/L 0 0.00027 0 0 0 0.011 **1,1,2-Trichloroethane** 8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **2,2,4-Trimethy lepentane**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Xy lenes**  8260B 8260B **ppb** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Methy l Ethy** **l Ketone (2-Butanone)** 8260B 8260B **ppb** 100 400 7300 130 500 4200 mg/L 0.1 0.4 7.3 0.13 0.5 4.2 **Methy l Isobutyl Ketone (4-Methyl-2-pentanone)**  8260B 8260B **ppb** 220 140 680 330 170 410 mg/L 0.22 0.14 0.68 0.33 0.17 0.41 **Total HAP (VCM by**

**Method 8260B) ppm**  **63.876 8.983**  **45.602 66.322**  **9.908 40.829**  **Analyte Method**  **Required Method Unit** 

Shintech WW TX May 2012 Accutes

### Wastewater (ECI) **Stripper 1 Stripper 2**  **Stripper 3 Stripper 1**  **Stripper 2 Stripper 3**  **Stripper 1 Stripper 2** **Stripper 3 Stripper 1** **Stripper 2 Stripper 3**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **14:00 14:00**  **5/8/12 5/8/12**  **5/8/12 5/9/12**  **5/9/12 5/9/12**  **5/8/12 5/8/12**  **5/8/12 5/9/12**  **5/9/12 5/9/12**  **Acetaldehyde** 8315A 8315A **ppm** 14.64 3.64 2.21 9 0.765 1.42 mg/L 14.64 3.64 2.21 9 0.765 1.42 **Bromoethane (Vinyl Bromide)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **1,3-Butadiene** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Benzene** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **2-Chloro-1,3-Butadiene (Chloroprene)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Chloroethane (Ethyl Chloride)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Chloromethane (Methyl chloride)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Chloroform** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **1,1-Dichloroethene (Vinylidene chloride)** 8260B 8260B **ppb** 0 0 0 0 60 0 μg/L 0 0 0 0 60 0 **1,1-Dichloroehtane (Ethylidene dichloride)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **1,2-Dichloroethane (Ethylene dichloride)** 8260B 8260B **ppb** 27 19 0 37 21 0 μg/L 27 19 0 37 21 0 **Methylene Chloride (Dichloromethane)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Vinyl Acetate** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Isopropylbenzene (Cumene)** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Acetophenone** 8270D 8270D **ppb** 2340 595 557 3730 923 1250 μg/L 2340 595 557 3730 923 1250 **Bis(2-Ethylhexyl)phathalate** 8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Phenol** 8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Methanol NCAS507** 8015C 8015C **ppm** 34 18 76 38 154 85 mg/L 34 18 76 38 154 85 **Formaldehyde** 8315A 8315A **ppm** 0.519 0.68 0.38 0.53 0.12 0.37 mg/L 0.519 0.68 0.38 0.53 0.12 0.37 **Vinyl Chloride** 8260B 8260B **ppb** 4 0 0 0 8 0 μg/L 4 0 0 0 8 0 **Chlorobenzene** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **2,4-Dinitrophenol** 8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Ethylbenzene** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Ehtylene glycol** 8015C 8015C **ppm** 0 0 0 0 0 0 mg/L 0 0 0 0 0 0 **Hexane** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Hydroquinone** 8270D 8270D **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **1,1,2,2-Tetrachloroethane** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Toluene** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **1,1,2-Trichloroethane** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **2,2,4-Trimethylepentane** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Xylenes** 8260B 8260B **ppb** 0 0 0 0 0 0 μg/L 0 0 0 0 0 0 **Methyl Ethyl Ketone (2-Butanone)** 8260B 8260B **ppb** 96 335 5670 105 329 2560 μg/L 96 335 5670 105 329 2560 **Methyl Isobutyl Ketone (4-Methyl-2-pentanone)** 8260B 8260B **ppb** 252 133 605 336 129 366 μg/L 252 133 605 336 129 366 **Total HAP (VCM by Method 8260B) ppm**  **51.878 23.402**  **85.422 51.738**  **156.355 90.966**  **Analyte Method**  **Required Method Unit** 

Shintech WW TX May 2012 ECI

# Shintech

**Wastewater (ECI&A ccutest) at A** **ddis and Plaquemine**

**Ac cutest**  22:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 14:00 6:00 14:00 14:00 **4/10/12 5/8/12**  **5/9/12 4/10/12**  **5/8/12 5/9/12**  **4/10/12 5/8/12**  **5/9/12 4/10/12**  **5/8/12 5/9/12**  **Ac etaldehyde**  8315A 8315A **ppb** 840 850 910 1100 940 760 9790 6720 5980 6700 4900 7300 **Bromoethane (Vinyl Bromide)** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **1,3-Butadiene** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Benzene** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **2-Chloro-1,3-Butadiene (Chloroprene)** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Chloroethane (Ethyl Chloride)** 8260B 8260B **ppb** 14 115 87 30 100 96 25 0 0 28 9.4 0 **Chloromethane (Methyl chloride)** 8260B 8260B **ppb** 15 0 0 3.8 22 0 0 0 0 5.8 0 0 **Chloroform** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **1,1-Dichloroethene (Vinylidene chloride)** 8260B 8260B **ppb** 0 0 0 0 36 21 0 0 0 0 0 0 **1,1-Dichloroehtane (Ethylidene dichloride)** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0.91 0 0 **1,2-Dichloroethane (Ethylene dichloride)** 8260B 8260B **ppb** 63 146 111 53 170 120 29 18 28 31 19 28 **Me thylene Chloride (Dichloromethane)**  8260B 8260B **ppb** 0 0 0 0 11 6.3 0 0 0 0 0 0 **Vinyl A cetate**  8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Isopropylbenzene (Cumene)** 8260B 8260B **ppb** 0 0 0 0 19 3.6 0 0 0 1.1 0.68 0 **Ac etophenone**  8270D 8270D **ppb** 2540 4670 2270 2850 5400 3200 4020 3140 3150 3190 4500 5000 **Bis(2-Ethylhexyl)phathalate** 8270D 8270D **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Phenol** 8270D 8270D **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Me thanol**  8015C 8015C **ppb** 57000 71000 73000 75200 113000 95300 319000 58000 58000 23000 26200 17900 **Formaldehyde** 8315A 8315A **ppb** 540 700 920 660 1300 1100 367 490 360 610 380 420 **Vinyl Chloride** 8260B 8260B **ppb** 60 383 349 130 370 330 111 39 40 120 43 39 **Chlorobenzene** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **2,4-Dinitrophenol** 8270D 8270D **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Ethylbenzene** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Ehtylene glycol** 8015C 8015C **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Hexane** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Hydroquinone** 8270D 8270D **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **1,1,2,2-Tetrachloroethane** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Toluene** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **1,1,2-Trichloroethane** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **2,2,4-Trimethylepentane** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Xylenes** 8260B 8260B **ppb** 0 0 0 0 0 0 0 0 0 0 0 0 **Me thyl Ethyl Ketone (2-Butanone)**  8260B 8260B **ppb** 4790 3460 2370 3900 4300 3200 238 127 171 200 200 240 **Me thyl Isobutyl Ketone (4-Methyl-2-pentanone)**  8260B 8260B **ppb** 1200 1760 695 940 1800 810 508 326 492 440 370 540 **Total HA P (VCM by Method 8260B)**  **ppb 67062**  **83084 80712**  **84867 127468**  **104947 334088**  **68860 68221**  **34327 36622**  **31467** 

# Total HA**P (VCM by**

**Method 8260B) ppm**  **67.06 83.08**  **80.71 84.87**  **127.47 104.95**  **334.09 68.86**  **68.22 34.33**  **36.62 31.47**  

# Plaquemine **ECI Ac** **cutest ECI** 



# Ad**dis**

ShintechWW Addis&PLQ Apr-May-12

### Sampling Results for Wastewater Stripper **FPC TX PVC Unit: PC 701D Point Comfort, TX** 

6.04.12

mg/l=ppm ug/l =ppb div by 1000 to get ppm

Date of Sample 5/19/2012 5/20/2012 5/21/2012 5/18/20125/21/20125/23/2012 Average TOHAP Date of Testing 5/21/2012 5/21/2012 5/21/2012 5/18/20125/21/20125/23/2012 For FPC TX PVC: Sample No. 600-55332-1600-55332-3600-55332-5 156429 156527 156530 ppm Method of Analysis Concentration (mg/l) Note 1 Note 1 Note 1 1 107211Ethylene glycol. 8015B 13 23 15 

### 17.00 2 67561Methanol. 8015B 98 72 63 

### 77.67
4 50000Formaldehyde. 8315A 0.23 0.28 0.17 

### 0.23 5 512852,4-dinitrophenol. 8270D ND ND ND 6 98862Acetophenone. 8270D 6.54 6.11 5.2 

### 5.95

7 117817Bis(2-ethylhexyl)

phthalate (DEHP). 8270D 0.0447 0.0722 0.033 

### 0.05 8 123319Hydroquinone. 

### 0.00 9 108952Phenol. 0.0524 0.051 0.0478 

### 0.05

10 793451,1,2,2-tetrachloroethane. 8260 0.02 0.02 0.02 

### 0.02 11 1069901,3-butadiene. 8260 0.02 0.02 0.02 

### 0.02

12 5408412,2,4-trimethylpentane. 8260 0.04 0.04 0.04 

### 0.04 13 71432Benzene. 8260 0.02 0.02 0.02 

### 0.02 14 108907Chlorobenzene. 8260 0.02 0.02 0.02 

### 0.02 15 67663Chloroform. 8260 0.04 0.04 0.04 

### 0.04 16 126998Chloroprene. 8260 0.02 0.02 0.02 

### 0.02 17 98828Cumene. 0.04 0.04 0.04 

### 0.04

18 75003Ethyl chloride

(Chloroethane). 8260 0.1 0.1 0.1 

### 0.10 19 100414Ethylbenzene. 8260 0.02 0.02 0.02 

### 0.02

20 107062Ethylene dichloride (1,2-

Dichloroethane). 8260 0.02 0.02 0.02 

### 0.02

21 75343Ethylidene dichloride (1,1-

Dichloroethane). 8260 0.02 0.02 0.02 

### 0.02

22 74873Methyl chloride

(Chloromethane). 8260 0.1 0.1 0.1 

### 0.10 23 75092Methylene chloride. 8260 0.02 0.02 0.02 

### 0.02 24 110543n-Hexane. 8260 0.1 0.1 0.1 

### 0.10 25 108883Toluene. 8260 0.02 0.02 0.02 

### 0.02

2671556/790 05 Trichloroethane. 8260 0.02 0.02 0.02 

### 0.02 27 108054Vinyl acetate. 8260 0.04 0.04 0.04 

### 0.04 28 593602Vinyl bromide. 8260 0.2 0.2 0.2 

### 0.20 29 75014Vinyl chloride.

30 75354Vinylidene chloride (1,1-

Dichloroethylene). 8260 0.02 0.02 0.02 

### 0.02

31 1330207Xylenes (isomers and

mixtures). 8260 0.06 0.06 0.06 

### 0.06

Acetaldehyde 8315A 4.4 6.7 4.7 

### 5.27

Total HAP/Sample 115.63 101.98 82.87 7.5971 7.1932 6.2408 

### 107.17

29 75014Vinyl chloride. 8260 0.1 0.1 0.316 

### 0.17 **FPC TX: Suspension PVC Unit Wastewater stripper (PC 701D)** 

10/28/2013 FPC TX PVC May 2012

### Wastewater Stripper **FPC TX SPVC Unit (MV-327A) Point Comfort, TX** 

6.4.12

mg/l=ppm ug/l =ppb div by 1000 to get ppm

Date of Sample 5/19/2012 5/20/2012 5/21/2012 5/22/20125/23/2012 Average TOHAP Date of Testing 5/21/2012 5/21/2012 5/21/2012 5/22/20125/23/2012 For FPC TX SPVC: Sample No. 600-55332-7600-55332-8600-55332-9 156502 156529 ppm Method of Analysis Concentration (mg/l) Note1 Note1 1 107211Ethylene glycol. 8015B 3.1 3.1 3.1 

### 3.10 2 67561Methanol. 8015B 4.8 25 0.56 

### 10.12 4 50000Formaldehyde. 8315A 0.12 0.028 0.037 

### 0.06 5 512852,4-dinitrophenol. 8270D ND ND 6 98862Acetophenone. 8270D 0.0501 0.123 

### 0.09

7 117817Bis(2-ethylhexyl)

phthalate (DEHP). 8270D 0.00576 0.0254 

### 0.02 8 123319Hydroquinone. 

### 0.00 9 108952Phenol. 0.0105ND 

### 0.01
10 793451,1,2,2-tetrachloroethane. 8260 0.005 0.02 

### 0.01 11 1069901,3-butadiene. 8260 0.005 0.02 

### 0.01

12 5408412,2,4-trimethylpentane. 8260 0.01 0.04 

### 0.03 13 71432Benzene. 8260 0.005 0.02 

### 0.01 14 108907Chlorobenzene. 8260 0.005 0.02 

### 0.01 15 67663Chloroform. 8260 0.01 0.04 

### 0.03 16 126998Chloroprene. 8260 0.005 0.02 

### 0.01 17 98828Cumene. 0.01 0.04 

### 0.03
18 75003Ethyl chloride

(Chloroethane). 8260 0.025 0.342 

### 0.18 19 100414Ethylbenzene. 8260 0.005 0.02 

### 0.01

20 107062Ethylene dichloride (1,2-

Dichloroethane). 8260 0.005 0.02 

### 0.01

21 75343Ethylidene dichloride (1,1-

Dichloroethane). 8260 0.005 0.02 

### 0.01

22 74873Methyl chloride

(Chloromethane). 8260 0.025 0.448 

### 0.24 23 75092Methylene chloride. 8260 0.005 0.02 

### 0.01 24 110543n-Hexane. 8260 0.025 0.1 

### 0.06 25 108883Toluene. 8260 0.005 0.02 

### 0.01
2671556/79 005 Trichloroethane. 8260 0.005 0.02 

### 0.01 27 108054Vinyl acetate. 8260 0.01 0.668 

### 0.34 28 593602Vinyl bromide. 8260 0.05 0.2 

### 0.13 29 75014Vinyl chloride.

30 75354Vinylidene chloride (1,1-

Dichloroethylene). 8260 0.005 0.02 

### 0.01
31 1330207Xylenes (isomers and

mixtures). 8260 0.015 0.06 

### 0.04

Acetaldehyde 8315A 3.5 2.2 0.27 

### 1.99

**Total HAP/Sample 11.52**  **30.328 3.967**  **0.30636 2.3264**  

### 16.59 Final PVC MACT WW TOHAP Limit **110 110**  **110**

29 75014Vinyl chloride. 8260 0.025 77.5 

### 38.76

Note 1= All values in column were reported as "<" the value.**FPC TX: Specialty PVC Unit**

**Wastewater stripper (MV-327A):**Note that the sampling was done on the Unit's Batch WWStripper because its continuous WWstripper was out of service

10/28/2013 FPC TX SPVC May 2012

### Analyte Prep Method 3-Apr 3-Apr 30-Apr 1-May 2-May 3-MayAverage 15-Mar 20-Mar 22-Mar 30-Apr 2-May 3-MayAverage

Acetaldehyde 8015B **3.180 1.850**  **5.610 4.250**  **1.180 6.500**  **3.762 3.400**  **1.090 4.370**  **2.560 4.920**  **6.920 3.877**  Ethylene glycol 8015B 0.330 0.330 0.330 0.330 0.330 0.330 **0.330 0.580**  0.330 0.330 0.330 0.330 0.330 **0.372** Methanol 8015B **701.000 194.000**  **484.000 531.000**  **113.000 1,630.000**  **608.833 471.000**  **178.000 1,070.000**  **880.000 1,180.000** **1,240.000 836.500**  Benzene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** Chlorobenzene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** Ethyl chloride 8260B **0.043 0.029**  **0.107 0.078**  **0.048 0.083**  **0.065** 0.010 **0.003 0.024**  0.020 0.020 **0.049 0.021**  Chloroform 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.002 0.001 0.001 0.020 0.020 0.020 **0.011** Methyl chloride 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015 0.011**  **0.004 0.087**  0.020 **0.038 0.101**  **0.043** Chloroproprene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** 1,1-Dichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** Ethylene Dichloride 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 **0.005 0.034**  0.020 0.020 **0.054 0.024**  1,1 - Dichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** Ethylbenzene 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** Hexane 8260B 0.050 0.050 0.100 0.100 0.050 0.100 **0.075** 0.050 0.005 0.005 0.100 0.100 0.100 **0.060** Cumene 8260B 0.004 **0.015** 0.020 0.020 0.010 0.020 **0.015** 0.010 0.000 0.000 0.020 0.020 0.020 **0.012** Methylene chloride 8260B 0.023 0.023 0.100 0.100 0.050 0.100 **0.066 0.108**  0.005 0.005 0.100 0.100 0.100 **0.070** 1,1,2,2-Tetrachloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.010 0.001 0.001 0.020 0.020 0.020 **0.012** Toluene 8260B 0.050 0.050 0.100 0.100 0.050 **0.193 0.091**  0.050 0.005 0.005 0.100 0.100 0.100 **0.060** 1,1,1 - Trichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.050 0.001 0.001 0.020 0.020 0.020 **0.019** 1,1,2 - Trichloroethane 8260B 0.010 0.010 0.020 0.020 0.010 0.020 **0.015** 0.050 0.001 0.001 0.020 0.020 0.020 **0.019** Vinyl Acetate 8260B 0.100 0.100 0.200 0.200 0.100 0.200 **0.150** 0.100 0.010 0.010 0.200 0.200 0.200 **0.120** Vinyl chloride 8260B **0.991 0.604**  **2.360 1.550**  **0.603 2.300**  **1.401 0.393**  **0.110 1.970**  **0.207 0.353**  **0.910 0.657**  Xylenes 8260B 0.010 0.010 0.020 0.020 0.010 **0.055 0.021**  0.010 0.001 0.001 0.020 0.020 0.020 **0.012** 1,3 - Butadiene 5030B 0.080 0.081 0.100 0.100 0.100 0.100 **0.094** 0.100 0.100 0.100 0.100 0.100 0.100 **0.100** 2,2,4-Trimethylpentane 5030B 0.005 0.005 0.005 0.005 **0.005** 0.005 0.005 0.012 **0.007** Formaldehyde 8315A **0.619 1.080**  **1.900 1.250**  **1.260 1.020**  **1.188 0.695**  **0.623 0.519**  **0.486 0.499**  **0.229 0.509**  Bis(2-ethylhexyl)phthalate 3510C 1.000 1.000 1.050 1.320 1.000 1.000 **1.062** 0.010 0.100 0.100 0.100 0.100 0.100 **0.085** 2,4 - Dinitrophenol 3510C 1.000 1.000 1.050 1.320 1.000 1.000 **1.062** 0.010 0.100 0.100 0.100 0.100 0.100 **0.085** Phenol 3510C 0.500 0.500 0.526 0.658 0.500 0.500 **0.531** 0.005 0.050 0.050 0.050 0.050 0.050 **0.043** Acetophenone 3510C **3.870 3.470**  **2.510 2.300**  **3.010 3.650**  **3.135 17.200**  **19.400 14.200**  **33.800 24.200**  **29.700 23.083**  Hydroquinone 3510C 1.000 1.000 **1.270** 1.000 1.040 1.020 **1.055** 1.000 0.100 1.000 1.060 1.000 1.040 **0.867** Daily Total 713.971 205.312 501.598 545.941 123.4661,648.416 623.119 494.924 200.0521,092.920 919.5981,212.4751,280.435 866.738

Red = J Value Bold = Measured Value * 2,2,4-Trimethylpentane was not analyzed during the first round of sampling Plaquemine Aberdeen

Georgia Gulf LA & MS Mar-May-128015B_FID **Prep Method**

**Compound DF**  **B Ac** **etaldehyde 1.00**  **1 05/14/12 13:10**  Ethylene glycol 1.00 1 05/17/12 20:42 **Methanol 1.00**  **1 05/14/12 13:10**  Analy tical Method Qualifiers/ Definitions 05/29/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) Lab ID 1205024-001A Received 05/08/12 Field ID Water Column Matrix Aqueous Sampled 05/07/12 8:30 Analy tical Method 8260B **Prep Method** 5030B **Prep Batch** 36262 **Date/Time Prepped**05/08/12 9:41 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 **1 05/08/12 14:45**  **52199** 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 1 05/08/12 14:45 52199 **1 05/08/12 14:45**  **52199** 1 05/08/12 14:45 52199 Limits: 1 05/08/12 14:45 52199 Limits: 1 05/08/12 14:45 52199 Limits: 1 05/08/12 14:45 52199 Limits: 1 05/08/12 14:45 52199 Analy tical Method 8015CM1 **Prep Method** 5030B **Prep Batch** 36295 **Date/Time Prepped**05/16/12 8:30 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/15/12 18:41 52240 1 05/15/12 18:41 52240 1 05/15/12 18:41 52240 1 05/15/12 18:41 52240 Analy tical Method 8315A **Prep Method** 8315A 05/14/12 9:30 **An alytical**  8015B_FID **Prep Batch**

**Default Vol/Wt** 36326 1 Ml **Sample Vol/Wt**1 Ml

**2.22 mg/L**  **0.330 AL** **S Units**  **MDL MQL An** **alyzed Date/Time Prepped**  **Date/Time**

< 0.330 mg/L 0.330 ALS 52261

**17.0 Result**  **52261 Batch** 

**mg/L 0.330** 

NFP Chlorobenzene < 0.00100 mg/L 0.00100 NFP Benzene < 0.00100 **AL S**  **52261**

mg/L 0.00100

NFP Chloroform < 0.00100 mg/L 0.00100 NFP Chloroethane < 0.00100 mg/L 0.00100

NFP Chloropropene < 0.00100 mg/L 0.00100 NFP Chloromethane < 0.00100 mg/L 0.00100

NFP **1,2-Dichloroethane 0.00355**  **mg/L 0.00100**  **NFP** 1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP Ethylbenzene < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP Isopropylbenzene < 0.00100 mg/L 0.00100 NFP Hex ane < 0.00500 mg/L 0.00500

NFP 1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP Methylene chloride < 0.00500 mg/L 0.00500

NFP 1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP Toluene < 0.00500 mg/L 0.00500

NFP Vinyl acetate < 0.0100 mg/L 0.0100 NFP 1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

**NFP** Xylenes, Total < 0.00100 mg/L 0.00100 NFP **Vinyl chloride 0.0296**  **mg/L 0.00100** 

NFP Surrogate: Toluene-d8 95 % 70-130 NFP Surrogate: Dibromofluoromethane 78 % 70-128

NFP Surrogate: 1,2-Dichloroethane-d4 85 % 67-136 NFP Surrogate: 4-Bromofluorobenzene 88 % 71-131

SB 2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB 1,3-Butadiene < 0.100 mg/L 0.100

SB Surrogate: 4-Bromochlorobenzene 112 % Limits: 50-150 SB Surrogate: 4-Bromofluorobenzene 103 % Limits: 50-150

10/01/12 10:45 **Prep Batch** 36278 **Date/Time Prepped**

WL KY Water Col 5-7-12**Compound B**  **y Formaldehyde**  **0.185 mg/L**  **0.0250 5 05/11/12 15:19 VC**  **52238** Analy tical Method 8270C **Prep Method** 3510C

**Compound B**  10 05/27/12 19:18 10 05/27/12 19:18 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 8270CM30 **Prep Method** 3510C

**Compound B**  Acetophenone 10 05/27/12 19:18 **Hydroquinone 10**  **05/16/12 23:27** Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Surrogate: % 10 05/27/12 19:18 Analy tical Method Qualifiers/ Definitions 05/29/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)


### Westlake PVC Corporation **P.O. Box 1027 Calvert City, KY 42029**  Project Description PVC MACT Site Calvert City, KY Lab ID 1205024-001C Received 05/08/12 Field ID Water Column Matrix Aqueous Sampled 05/07/12 8:30 Lab Order Number 12-129-0215 Report of Analy

sis **Default Vol/Wt Result**  100 mL

**Units Sample Vol/Wt** 100 mL

**MQL DF Date/Time**  **An alyzed**  **An alytical**  **Batch**

05/14/12 14:00 **An alytical** 
**Result Units**  **MQL DF An** **alyzed Batch**  **Prep Batch Default Vol/Wt**  36291 1000 mL **Sample Vol/Wt**1050 mL **Date/Time Prepped Date/Time** 

MJ 52248 Bis(2-ethylhex

yl)phthalate < 0.100 mg/L 0.100 MJ 52248 2,4-Dinitrophenol < 0.100 mg/L 0.100

MJ 52248 Phenol < 0.0500 mg/L 0.0500

2-Fluorobiphenyl 81 Limits: 38-107 MJ 52248 4-Terphenyl-d14 92 MJ 52248 Nitrobenzene-d5 67 Limits: 29-110

Limits: 33-122

MJ 52248 Phenol-d6 32 Limits: 10-115 MJ 52248 MJ 52248
2,4,6-Tribromophenol 72 Limits: 40-125

**An alyzed**  **Batch** 2-Fluorophenol 47 Limits: 20-110

52291

< 0.100 mg/L 0.100 MJ 52291

**0.229** MJ 52248

**MJ 52291**  **Prep Batch Default Vol/Wt**  36290 1000 mL **Sample Vol/Wt**1020 mL **Date/Time Prepped Date/Time**  05/14/12 10:20 **An alytical** 
**Result**

**mg/L 0.100**  Phenol-d6 25 Limits: 10-115 **Units MQL DF** 

MJ

Limits: 20-110 MJ 52291 2,4,6-Tribromophenol 72 Limits: 40-125 MJ 52291 2-Fluorophenol 47

WL KY Water Col 5-7-128015B_FID

**DF B**  **1.00 1**  **05/14/12 12:27 1.00**  **1 05/17/12 19:22**  **1.00 1**  **05/14/12 12:27** Analy tical Method Qualifiers/ Definitions 06/01/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) Analy tical Method 8260B **Prep Method** 5030B **Prep Batch** 36275 **Date/Time Prepped**05/09/12 10:15 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 **1 05/09/12 17:11**  **52213** 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 **1 05/09/12 17:11**  **52213** 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 1 05/09/12 17:11 52213 **1 05/09/12 17:11**  **52213** 1 05/09/12 17:11 52213 Limits: 1 05/09/12 17:11 52213 Limits: 1 05/09/12 17:11 52213 Limits: 1 05/09/12 17:11 52213 Limits: 1 05/09/12 17:11 52213 Analy tical Method 8015CM1 **Prep Method** 5030B **Prep Batch** 36295 **Date/Time Prepped**05/16/12 8:30 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/15/12 19:08 52240 1 05/15/12 19:08 52240 1 05/15/12 19:08 52240 1 05/15/12 19:08 52240 Analy tical Method 8315A **Prep Method Compound**  **B y**  **Formaldehyde 0.0844**  **mg/L 0.00500 1**  **05/11/12 12:25 VC 52238**  Analy tical Method 8270C 05/14/12 9:30 **An alytical**  **Compound Result**  **Units MDL MQL**  **An alyzed**  **Batch Prep Method**  8015B_FID **Prep Batch Default Vol/Wt**  36326 1 Ml

**0.330 AL** **S 3.49** **mg/L Sample Vol/Wt** 1 Ml **Date/Time Prepped Date/Time** 

**52261 Ethylene glycol**  **0.460 J mg/L**  **0.330 AL** **S 52261**  **Ac etaldehyde** 

**22.6 mg/L** 

NFP Chloroethane < 0.00100 mg/L 0.00100 NFP Chlorobenzene < 0.00100 **0.330 AL** **S 52261** 

Benzene < 0.00100 mg/L 0.00100 NFP **Methanol**

mg/L 0.00100

NFP Chloromethane < 0.00100 mg/L 0.00100 NFP Chloroform < 0.00100 mg/L 0.00100

NFP 1,1-Dichloroethane < 0.00100 mg/L 0.00100 NFP Chloropropene < 0.00100 mg/L 0.00100

**NFP** 1,1-Dichloroethene < 0.00100 mg/L 0.00100 NFP **1,2-Dichloroethane 0.00231**  **mg/L 0.00100** 

NFP Hex ane < 0.00500 mg/L 0.00500 NFP Ethylbenzene < 0.00100 mg/L 0.00100

NFP Methylene chloride < 0.00500 mg/L 0.00500 NFP Isopropylbenzene < 0.00100 mg/L 0.00100

NFP **Toluene 0.00653**  **mg/L 0.00500**  **NFP** 1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100

NFP 1,1,2-Trichloroethane < 0.00100 mg/L 0.00100 NFP 1,1,1-Trichloroethane < 0.00100 mg/L 0.00100

NFP **Vinyl chloride 0.0306**  **mg/L 0.00100**  **NFP** Vinyl acetate < 0.0100 mg/L 0.0100

NFP Surrogate: Dibromofluoromethane 80 % 70-128 NFP Xylenes, Total < 0.00100 mg/L 0.00100

NFP Surrogate: 4-Bromofluorobenzene 95 % 71-131 NFP Surrogate: Toluene-d8 93 % 70-130

NFP

1,3-Butadiene < 0.100 mg/L 0.100 SB Surrogate: 1,2-Dichloroethane-d4 82 % 67-136

SB Surrogate: 4-Bromofluorobenzene 99 % Limits: 50-150 SB 2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500

SB

8315A **Prep Batch** 36278 **Date/Time Prepped** 10/01/12 10:45 Surrogate: 4-Bromochlorobenzene 120 % Limits: 50-150

**Date/Time An** **alyzed An** **alytical Batch**  **Default Vol/Wt Result**  100 mL

**Units Sample Vol/Wt** 100 mL

**MQL DF**

WL KY Water Col 5-8-12**Prep Method**

**Compound B**  10 05/27/12 19:53 10 05/27/12 19:53 10 05/27/12 19:53 Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: **10 05/27/12 19:53**  8270CM30 **Prep Method**

**Compound B**  Acetophenone 10 05/27/12 19:53 **Hydroquinone 10**  **05/17/12 0:02** Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: 10 05/27/12 19:53 Surrogate: Limits: **10 05/27/12 19:53**  Analy tical Method Qualifiers/ Definitions 06/01/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL)



### Westlake PVC Corporation **P.O. Box 1027 Calvert City, KY 42029**  Project Description WESTLAKE_PVC_PVC_ MACT Site Calvert City, KY Lab ID 1205027-002B Received 05/09/12 Field ID Water Column Matrix Aqueous Sampled 05/08/12 13:10 Lab Order Number 12-130-0211 Report of Analy

sis 3510C **Prep Batch**

**Default Vol/Wt** 36291 1000 mL **Sample Vol/Wt**1040 mL **Date/Time Prepped Date/Time**  05/14/12 14:00 **An alytical** 
**An alyzed**  **Batch Result**  **Units MQL DF** 

MJ 52248 Phenol < 0.0500 mg/L 0.0500 MJ 52248 2,4-Dinitrophenol Bis(2-ethylhex

yl)phthalate < 0.100 mg/L 0.100 MJ 52248 < 0.100 mg/L 0.100

MJ 52248 2-Fluorobiphenyl 71% 38-107 MJ 52248 Nitrobenzene-d5 57% 29-110

MJ 52248 4-Terphenyl-d14 83% 33-122

MJ 52248 **2-Fluorophenol 4** **%*** **20-110 MJ**  **52248** 2,4,6-Tribromophenol Phenol-d6 29% 10-115 MJ 52248 68% 40-125

**Date/Time Prepped Date/Time**  05/14/12 10:20 **An alytical** 
**Result Units**  **MQL DF An** **alyzed**

**0.488 mg/L**  **0.100 MJ**  **52291 Batch**  3510C **Prep Batch**

**Default Vol/Wt** 36290 1000 mL **Sample Vol/Wt**1030 mL

MJ 52291 < 0.100 mg/L

MJ 52291 0.100

% 40-125 MJ 52291 **MJ 52291**  2,4,6-Tribromophenol 68 **2-Fluorophenol 4** **%*** **20-110** Phenol-d6 28% 10-115

WL KY Water Col 5-8-128015B_FID **Prep Method**

**Compound DF**  **B Ac** **etaldehyde 1.00**  **1 05/14/12 13:38**  Ethylene glycol 1.00 1 05/17/12 20:22 **Methanol 1.00**  **1 05/14/12 13:38**  Analy tical Method Qualifiers/ Definitions 05/29/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) Lab ID 1205029-001A Received 05/10/12 Field ID Water Column Matrix Aqueous Sample Number 93060 Sampled 05/09/12 13:30 Analy tical Method 8260B **Prep Method** 5030B **Prep Batch** 36283 **Date/Time Prepped**05/10/12 10:27 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 1 05/10/12 13:06 52221 **1 05/10/12 13:06**  **52221** 1 05/10/12 13:06 52221 Limits: 1 05/10/12 13:06 52221 Limits: 1 05/10/12 13:06 52221 Limits: 1 05/10/12 13:06 52221 Limits: 1 05/10/12 13:06 52221 Analy tical Method 8015CM1 **Prep Method** 5030B **Prep Batch** 36295 **Date/Time Prepped**05/16/12 8:30 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/15/12 19:35 52240 1 05/15/12 19:35 52240 1 05/15/12 19:35 52240 1 05/15/12 19:35 52240 Analy tical Method 8315A 05/14/12 9:30 **An alytical**  8015B_FID **Prep Batch**

**Default Vol/Wt** 36326 1 Ml **Sample Vol/Wt**1 Ml

**6.96 mg/L**  **0.330 AL** **S Units**  **MDL MQL An** **alyzed Date/Time Prepped**  **Date/Time**

< 0.330 mg/L 0.330 ALS 52261

**21.9 Result**  **52261 Batch** 

**mg/L 0.330** 

NFP Chlorobenzene < 0.00100 mg/L 0.00100 NFP Benzene < 0.00100 **AL S**  **52261**

mg/L 0.00100

NFP Chloroform < 0.00100 mg/L 0.00100 NFP Chloroethane < 0.00100 mg/L 0.00100

NFP Chloropropene < 0.00100 mg/L 0.00100 NFP Chloromethane < 0.00100 mg/L 0.00100

NFP 1,2-Dichloroethane < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP Ethylbenzene < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP Isopropylbenzene < 0.00100 mg/L 0.00100 NFP Hex ane < 0.00500 mg/L 0.00500

NFP 1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP Methylene chloride < 0.00500 mg/L 0.00500

NFP 1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP Toluene < 0.00500 mg/L 0.00500

NFP Vinyl acetate < 0.0100 mg/L 0.0100 NFP 1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

**NFP** Xylenes, Total < 0.00100 mg/L 0.00100 NFP **Vinyl chloride 0.0114**  **mg/L 0.00100** 

NFP Surrogate: Toluene-d8 96 % 70-130 NFP Surrogate: Dibromofluoromethane 77 % 70-128

NFP Surrogate: 1,2-Dichloroethane-d4 83 % 67-136 NFP Surrogate: 4-Bromofluorobenzene 78 % 71-131

SB 2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB 1,3-Butadiene < 0.100 mg/L 0.100

SB Surrogate: 4-Bromochlorobenzene 97 % Limits: 50-150 SB Surrogate: 4-Bromofluorobenzene 101 % Limits: 50-150

WL KY Water Col 5-9-12**Prep Method** 8315A **Compound B**  **y Formaldehyde**  **0.110 mg/L**  **0.0250 5 05/11/12 15:30 VC**  **52238** Analy tical Method 8270C **Prep Method** 3510C

**Compound B**  10 05/27/12 20:28 10 05/27/12 20:28 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 8270CM30 **Prep Method** 3510C

**Compound B**  Acetophenone 10 05/27/12 20:28 **Hydroquinone 10**  **05/17/12 0:37** Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Surrogate: % 10 05/27/12 20:28 Analy tical Method Qualifiers/ Definitions 05/29/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) 

### Westlake PVC Corporation **P.O. Box 1027 Calvert City, KY 42029**  Project Description WESTLAKE_PVC_PVC_ MACT Site Calvert City, KY Lab ID 1205029-001C Received 05/10/12 Field ID Water Column Matrix Aqueous Sample Number 93060 Sampled 05/09/12 13:30 Lab Order Number 12-131-0207 Report of Analy

sis 10/01/12 10:45 **Default Vol/Wt Result**  100 mL

**Units Sample Vol/Wt** 100 mL

**MQL DF Date/Time**  **An alyzed**  **An alytical**  **Batch Prep Batch**  36278 **Date/Time Prepped**

05/14/12 14:00 **An alytical** 
**Result Units**  **MQL DF An** **alyzed Batch**  **Prep Batch Default Vol/Wt**  36291 1000 mL **Sample Vol/Wt**1060 mL **Date/Time Prepped Date/Time** 

MJ 52248 Bis(2-ethylhex

yl)phthalate < 0.100 mg/L 0.100 MJ 52248 2,4-Dinitrophenol < 0.100 mg/L 0.100

MJ 52248 Phenol < 0.0500 mg/L 0.0500

2-Fluorobiphenyl 63 Limits: 38-107 MJ 52248 4-Terphenyl-d14 71 MJ 52248 Nitrobenzene-d5 46 Limits: 29-110

Limits: 33-122

MJ 52248 Phenol-d6 23 Limits: 10-115 MJ 52248 MJ 52248
2,4,6-Tribromophenol 60 Limits: 40-125

**An alyzed**  **Batch** 2-Fluorophenol 30 Limits: 20-110

52291

< 0.100 mg/L 0.100 MJ 52291

**0.542** MJ 52248

**MJ 52291**  **Prep Batch Default Vol/Wt**  36290 1000 mL **Sample Vol/Wt**1040 mL **Date/Time Prepped Date/Time**  05/14/12 10:20 **An alytical** 
**Result**

**mg/L 0.100**  Phenol-d6 23 Limits: 10-115 **Units MQL DF** 

MJ

Limits: 20-110 MJ 52291 2,4,6-Tribromophenol 60 Limits: 40-125 MJ 52291 2-Fluorophenol 30

WL KY Water Col 5-9-128015B_FID **Prep Method**

**Compound DF**  **B** Acetaldehyde 1.00 1 05/14/12 13:24 Ethylene glycol 1.00 1 05/17/12 21:02 **Methanol 1.00**  **1 05/14/12 13:24**  Analy tical Method Qualifiers/ Definitions 05/29/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) Lab ID 1205032-001A Received 05/11/12 Field ID Water Column Matrix Aqueous Sample Number 93336 Sampled 05/10/12 13:00 Analy tical Method 8260B **Prep Method** 5030B **Prep Batch** 36300 **Date/Time Prepped**05/16/12 9:33 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 1 05/16/12 19:15 52244 Limits: 1 05/16/12 19:15 52244 Limits: 1 05/16/12 19:15 52244 Limits: 1 05/16/12 19:15 52244 Limits: 1 05/16/12 19:15 52244 Analy tical Method 8015CM1 **Prep Method** 5030B **Prep Batch** 36295 **Date/Time Prepped**05/16/12 8:30 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/15/12 20:02 52240 1 05/15/12 20:02 52240 1 05/15/12 20:02 52240 1 05/15/12 20:02 52240 Analy tical Method 8315A 05/14/12 9:30 **An alytical**  8015B_FID **Prep Batch**

**Default Vol/Wt** 36326 1 Ml **Sample Vol/Wt**1 Ml

< 0.330 mg/L 0.330 ALS **Units MDL MQL**  **An alyzed**  **Date/Time Prepped Date/Time** 

< 0.330 mg/L 0.330 ALS 52261

**25.4 Result**  52261 **Batch**

**mg/L 0.330** 

NFP Chlorobenzene < 0.00100 mg/L 0.00100 NFP Benzene < 0.00100 **AL S**  **52261**

mg/L 0.00100

NFP Chloroform < 0.00100 mg/L 0.00100 NFP Chloroethane < 0.00100 mg/L 0.00100

NFP Chloropropene < 0.00100 mg/L 0.00100 NFP Chloromethane < 0.00100 mg/L 0.00100

NFP 1,2-Dichloroethane < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP Ethylbenzene < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP Isopropylbenzene < 0.00100 mg/L 0.00100 NFP Hex ane < 0.00500 mg/L 0.00500

NFP 1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP Methylene chloride < 0.00500 mg/L 0.00500

NFP 1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP Toluene < 0.00500 mg/L 0.00500

NFP Vinyl acetate < 0.0100 mg/L 0.0100 NFP 1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

NFP Xylenes, Total < 0.00100 mg/L 0.00100 NFP Vinyl chloride < 0.00100 mg/L 0.00100

NFP Surrogate: Toluene-d8 114 % 70-130 NFP Surrogate: Dibromofluoromethane 103 % 70-128

NFP Surrogate: 1,2-Dichloroethane-d4 107 % 67-136 NFP Surrogate: 4-Bromofluorobenzene 95 % 71-131

SB 2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB 1,3-Butadiene < 0.100 mg/L 0.100

SB Surrogate: 4-Bromochlorobenzene 81 % Limits: 50-150 SB Surrogate: 4-Bromofluorobenzene 85 % Limits: 50-150

WL KY Water Col 5-10-12**Prep Method** 8315A **Compound B**  **y Formaldehyde**  **0.252 mg/L**  **0.0250 5 05/11/12 16:57 VC**  **52239** Analy tical Method 8270C **Prep Method** 3510C

**Compound B**  10 05/27/12 21:37 10 05/27/12 21:37 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 8270CM30 **Prep Method** 3510C

**Compound B**  Acetophenone 10 05/27/12 21:37 **Hydroquinone 10**  **05/17/12 1:12** Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Surrogate: % 10 05/27/12 21:37 Analy tical Method Qualifiers/ Definitions 05/29/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) 

### Westlake PVC Corporation **P.O. Box 1027 Calvert City, KY 42029**  Project Description WESTLAKE_PVC_PVC_ MACT Site Calvert City, KY Lab ID 1205032-001C Received 05/11/12 Field ID Water Column Matrix Aqueous Sample Number 93336 Sampled 05/10/12 13:00 Lab Order Number 12-132-0209 Report of Analy

sis 05/11/12 15:19 **Default Vol/Wt Result**  100 mL

**Units Sample Vol/Wt** 100 mL

**MQL DF Date/Time**  **An alyzed**  **An alytical**  **Batch Prep Batch**  36285 **Date/Time Prepped**

05/14/12 14:00 **An alytical** 
**Result Units**  **MQL DF An** **alyzed Batch**  **Prep Batch Default Vol/Wt**  36291 1000 mL **Sample Vol/Wt**1060 mL **Date/Time Prepped Date/Time** 

MJ 52248 Bis(2-ethylhex

yl)phthalate < 0.100 mg/L 0.100 MJ 52248 2,4-Dinitrophenol < 0.100 mg/L 0.100

MJ 52248 Phenol < 0.0500 mg/L 0.0500

2-Fluorobiphenyl 58 Limits: 38-107 MJ 52248 4-Terphenyl-d14 65 MJ 52248 Nitrobenzene-d5 47 Limits: 29-110

Limits: 33-122

MJ 52248 Phenol-d6 19 Limits: 10-115 MJ 52248 MJ 52248
2,4,6-Tribromophenol 53 Limits: 40-125

**An alyzed**  **Batch** 2-Fluorophenol 27 Limits: 20-110

52291

< 0.100 mg/L 0.100 MJ 52291

**0.550** MJ 52248

**MJ 52291**  **Prep Batch Default Vol/Wt**  36290 1000 mL **Sample Vol/Wt**1040 mL **Date/Time Prepped Date/Time**  05/14/12 10:20 **An alytical** 
**Result**

**mg/L 0.100**  Phenol-d6 19 Limits: 10-115 **Units MQL DF** 

MJ

Limits: 20-110 MJ 52291 2,4,6-Tribromophenol 53 Limits: 40-125 MJ 52291 2-Fluorophenol 27

WL KY Water Col 5-10-128015B_FID

**DF B**  **1.00 1**  **05/30/12 12:45 1.00**  **1 05/30/12 3:28**  **1.00 1**  **05/30/12 12:45** Analy tical Method Qualifiers/ Definitions 05/31/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) Lab ID 1205035-001A Received 05/15/12 Field ID Water Column Matrix Aqueous Sample Number 93854 Sampled 05/14/12 0:00 Analy tical Method 8260B **Prep Method** 5030B **Prep Batch** 36300 **Date/Time Prepped**05/16/12 9:33 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 1 05/16/12 19:35 52244 Limits: 1 05/16/12 19:35 52244 Limits: 1 05/16/12 19:35 52244 Limits: 1 05/16/12 19:35 52244 Limits: 1 05/16/12 19:35 52244 Analy tical Method 8015CM1 **Prep Method** 5030B **Prep Batch** 36338 **Date/Time Prepped**05/22/12 8:31 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/22/12 12:48 52277 1 05/22/12 12:48 52277 1 05/22/12 12:48 52277 1 05/22/12 12:48 52277 Analy tical Method 8315A 05/29/12 10:00 **An alytical**  **Compound Result**  **Units MDL MQL**  **An alyzed**  **Batch Sample Vol/Wt** 1 Ml **Date/Time Prepped Date/Time**  **Prep Method** 8015B_FID **Prep Batch Default Vol/Wt**  36368 1 Ml

**52307 Ethylene glycol**  **0.605 J mg/L**  **0.330 EV**  **52307 Ac** **etaldehyde 0.878 J** **mg/L 0.330**  **EV**

**52307**

Benzene < 0.00100 mg/L 0.00100 NFP **Methanol 24.4** **mg/L 0.330**  **EV**

NFP Chloroethane < 0.00100 mg/L 0.00100 NFP Chlorobenzene < 0.00100 mg/L 0.00100

NFP Chloromethane < 0.00100 mg/L 0.00100 NFP Chloroform < 0.00100 mg/L 0.00100

NFP 1,1-Dichloroethane < 0.00100 mg/L 0.00100 NFP Chloropropene < 0.00100 mg/L 0.00100

NFP 1,1-Dichloroethene < 0.00100 mg/L 0.00100 NFP 1,2-Dichloroethane < 0.00100 mg/L 0.00100

NFP Hex ane < 0.00500 mg/L 0.00500 NFP Ethylbenzene < 0.00100 mg/L 0.00100

NFP Methylene chloride < 0.00500 mg/L 0.00500 NFP Isopropylbenzene < 0.00100 mg/L 0.00100

NFP Toluene < 0.00500 mg/L 0.00500 NFP 1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100

NFP 1,1,2-Trichloroethane < 0.00100 mg/L 0.00100 NFP 1,1,1-Trichloroethane < 0.00100 mg/L 0.00100

NFP Vinyl chloride < 0.00100 mg/L 0.00100 NFP Vinyl acetate < 0.0100 mg/L 0.0100

NFP Surrogate: Dibromofluoromethane 93 % 70-128 NFP Xylenes, Total < 0.00100 mg/L 0.00100

NFP Surrogate: 4-Bromofluorobenzene 88 % 71-131 NFP Surrogate: Toluene-d8 98 % 70-130

NFP

1,3-Butadiene < 0.100 mg/L 0.100 SB Surrogate: 1,2-Dichloroethane-d4 96 % 67-136

SB Surrogate: 4-Bromofluorobenzene 83 % Limits: 50-150 SB 2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500

SB Surrogate: 4-Bromochlorobenzene 82 % Limits: 50-150

WL KY Water Col 5-14-12**Prep Method Compound**  **B y**  **Formaldehyde 0.228**  **mg/L 0.0250 5**  **05/18/12 11:31 VC 52269**  Analy tical Method 8270C **Prep Method**

**Compound B**  1 05/22/12 23:42 1 05/22/12 23:42 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 8270CM30 **Prep Method**

**Compound B**  Acetophenone 1 05/22/12 23:42 Hydroquinone 1 05/27/12 23:56 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Surrogate: % 1 05/22/12 23:42 Analy tical Method Qualifiers/ Definitions 05/31/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) 

### Westlake PVC Corporation **P.O. Box 1027 Calvert City, KY 42029**  Project Description WESTLAKE_PVC_PVC_ MACT Site Calvert City, KY Lab ID 1205035-001C Received 05/15/12 Field ID Water Column Matrix Aqueous Sample Number 93854 Sampled 05/14/12 0:00 Lab Order Number 12-136-0208 Report of Analy

sis 8315A **Prep Batch** 36299 **Date/Time Prepped**

3510C **Prep Batch**

**Default Vol/Wt** 36316 1000 mL **Sample Vol/Wt**1040 mL **Date/Time Prepped Date/Time**  05/21/12 12:00 **An alytical** 
**Result** 05/17/12 9:00 **Default Vol/Wt Result**  100 mL

**Units Sample Vol/Wt** 100 mL

**MQL DF Date/Time**  **An alyzed**  **An alytical**  **Batch**

**Units MQL DF** 

MJ 52278 Bis(2-ethylhex

yl)phthalate < 0.0100 mg/L 0.0100 MJ 52278 **An alyzed**  **Batch**

2,4-Dinitrophenol < 0.0100 mg/L 0.0100

MJ 52278 Phenol < 0.00500 mg/L 0.00500

2-Fluorobiphenyl 78 Limits: 38-107 MJ 52278 4-Terphenyl-d14 94 MJ 52278 Nitrobenzene-d5 80 Limits: 29-110

Limits: 33-122

MJ 52278 Phenol-d6 25 Limits: 10-115 MJ 52278 MJ 52278
2,4,6-Tribromophenol 66 Limits: 40-125

**Date/Time Prepped Date/Time**  05/21/12 16:00 **An alytical**  2-Fluorophenol 35 Limits: 20-110

**Result Units**  **MQL DF An** **alyzed Batch**  < 0.0100 MJ 52278

3510C **Prep Batch**

**Default Vol/Wt** 36317 1000 mL **Sample Vol/Wt**1040 mL

mg/L 0.0100

MJ 52280 < 0.0100 mg/L 0.0100 MJ 52280 MJ 52280

MJ 52280 2-Fluorophenol 35 Limits: 20-110 Phenol-d6 25 Limits: 10-115

MJ 52280 2,4,6-Tribromophenol 66 Limits: 40-125

WL KY Water Col 5-14-128015B_FID **Prep Method**

**Compound DF**  **B Ac** **etaldehyde 1.00**  **1 05/30/12 13:00**  Ethylene glycol 1.00 1 05/30/12 3:39 **Methanol 1.00**  **1 05/30/12 13:00**  Analy tical Method Qualifiers/ Definitions 05/31/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) Lab ID 1205038-001A Received 05/16/12 Field ID Water Column Matrix Aqueous Sample Number 93991 Sampled 05/15/12 12:10 Analy tical Method 8260B **Prep Method** 5030B **Prep Batch** 36300 **Date/Time Prepped**05/16/12 9:33 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 1 05/16/12 19:55 52244 Limits: 1 05/16/12 19:55 52244 Limits: 1 05/16/12 19:55 52244 Limits: 1 05/16/12 19:55 52244 Limits: 1 05/16/12 19:55 52244 Analy tical Method 8015CM1 **Prep Method** 5030B **Prep Batch** 36338 **Date/Time Prepped**05/22/12 8:31 **Compound Default Vol/Wt**  **Result** 10 mL **Units Sample Vol/Wt** 10 mL **MQL DF Date/Time**  **An alyzed**  **An alytical**  **By Batch** 1 05/22/12 11:55 52277 1 05/22/12 11:55 52277 1 05/22/12 11:55 52277 1 05/22/12 11:55 52277 Analy tical Method 8315A 05/29/12 10:00 **An alytical**  8015B_FID **Prep Batch**

**Default Vol/Wt** 36368 1 Ml **Sample Vol/Wt**1 Ml

**1.10 mg/L**  **0.330 EV**  **Units MDL MQL**  **An alyzed**  **Date/Time Prepped Date/Time** 

< 0.330 mg/L 0.330 EV 52307

**26.8 Result**  **52307 Batch** 

**mg/L 0.330** 

NFP Chlorobenzene < 0.00100 mg/L 0.00100 NFP Benzene < 0.00100 **EV 52307** 

mg/L 0.00100

NFP Chloroform < 0.00100 mg/L 0.00100 NFP Chloroethane < 0.00100 mg/L 0.00100

NFP Chloropropene < 0.00100 mg/L 0.00100 NFP Chloromethane < 0.00100 mg/L 0.00100

NFP 1,2-Dichloroethane < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethane < 0.00100 mg/L 0.00100

NFP Ethylbenzene < 0.00100 mg/L 0.00100 NFP 1,1-Dichloroethene < 0.00100 mg/L 0.00100

NFP Isopropylbenzene < 0.00100 mg/L 0.00100 NFP Hex ane < 0.00500 mg/L 0.00500

NFP 1,1,2,2-Tetrachloroethane < 0.00100 mg/L 0.00100 NFP Methylene chloride < 0.00500 mg/L 0.00500

NFP 1,1,1-Trichloroethane < 0.00100 mg/L 0.00100 NFP Toluene < 0.00500 mg/L 0.00500

NFP Vinyl acetate < 0.0100 mg/L 0.0100 NFP 1,1,2-Trichloroethane < 0.00100 mg/L 0.00100

NFP Xylenes, Total < 0.00100 mg/L 0.00100 NFP Vinyl chloride < 0.00100 mg/L 0.00100

NFP Surrogate: Toluene-d8 105 % 70-130 NFP Surrogate: Dibromofluoromethane 93 % 70-128

NFP Surrogate: 1,2-Dichloroethane-d4 100 % 67-136 NFP Surrogate: 4-Bromofluorobenzene 90 % 71-131

SB 2,2,4-Trimethylpentane < 0.00500 mg/L 0.00500 SB 1,3-Butadiene < 0.100 mg/L 0.100

SB Surrogate: 4-Bromochlorobenzene 82 % Limits: 50-150 SB Surrogate: 4-Bromofluorobenzene 84 % Limits: 50-150

WL KY Water Col 5-15-12**Prep Method** 8315A **Compound B**  **y Formaldehyde**  **0.358 mg/L**  **0.0250 5 05/18/12 12:04 VC**  **52269** Analy tical Method 8270C **Prep Method** 3510C

**Compound B**  1 05/23/12 0:16 1 05/23/12 0:16 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 8270CM30 **Prep Method** 3510C

**Compound B**  Acetophenone 1 05/23/12 0:16 Hydroquinone 1 05/28/12 0:30 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Surrogate: % 1 05/23/12 0:16 Analy tical Method Qualifiers/ Definitions 05/31/12 2414 WESTLAKE_PVC_AL * Surrogate Recovery

outside accepted limits * I Recoveries affected by interferences or high background B Analy

te detected in the associated Method Blank DF Dilution Factor E Value exceeds method calibration range H Prepped / Analy zed out of holding time. J Estimated Value Analy te below reported detection limit M Minimum value MDL Method Dection Limit (adjusted) MQL Method Quantitation Limit (adjusted) MRL Method Reporting Limit N Refer to attached Non-Compliance Report Q RPD >40% between primary and confirmation columns SQL Sample Quantitation Limit (adjusted MDL) 

### Westlake PVC Corporation **P.O. Box 1027 Calvert City, KY 42029**  Project Description WESTLAKE_PVC_PVC_ MACT Site Calvert City, KY Lab ID 1205038-001C Received 05/16/12 Field ID Water Column Matrix Aqueous Sample Number 93991 Sampled 05/15/12 12:10 Lab Order Number 12-137-0205 Report of Analy

sis 05/17/12 9:00 **Default Vol/Wt Result**  100 mL

**Units Sample Vol/Wt** 100 mL

**MQL DF Date/Time**  **An alyzed**  **An alytical**  **Batch Prep Batch**  36299 **Date/Time Prepped**

05/21/12 12:00 **An alytical** 
**Result Units**  **MQL DF An** **alyzed Batch**  **Prep Batch Default Vol/Wt**  36316 1000 mL **Sample Vol/Wt**1030 mL **Date/Time Prepped Date/Time** 

MJ 52278 Bis(2-ethylhex

yl)phthalate < 0.0100 mg/L 0.0100 MJ 52278 2,4-Dinitrophenol < 0.0100 mg/L 0.0100

MJ 52278 Phenol < 0.00500 mg/L 0.00500

2-Fluorobiphenyl 85 Limits: 38-107 MJ 52278 4-Terphenyl-d14 98 MJ 52278 Nitrobenzene-d5 97 Limits: 29-110

Limits: 33-122

MJ 52278 Phenol-d6 21 Limits: 10-115 MJ 52278 MJ 52278
2,4,6-Tribromophenol 58 Limits: 40-125

**An alyzed**  **Batch** 2-Fluorophenol 26 Limits: 20-110

52280

< 0.0100 mg/L 0.0100 MJ 52280 < 0.0100 MJ 52278

MJ 52280 **Prep Batch Default Vol/Wt**  36317 1000 mL **Sample Vol/Wt**1030 mL **Date/Time Prepped Date/Time**  05/21/12 16:00 **An alytical** 
**Result**

mg/L 0.0100 Phenol-d6 21 Limits: 10-115 **Units MQL DF** 

MJ

Limits: 20-110 MJ 52280 2,4,6-Tribromophenol 58 Limits: 40-125 MJ 52280 2-Fluorophenol 26

WL KY Water Col 5-15-12