# SAFETY DATA SHEET

ARMEEN OL

Version 1 Revision Date 06/09/2014 Print Date 06/23/2015 US / Z8

1 / 13 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : ARMEEN OL

Product Use Description : Surfactant

Company : Akzo Nobel Surface Chemistry AB

Stenunge Alle 3

Stenungsund 444 85

Sweden

Telephone : +4630385000

Fax : +4630384659

E

- mail address : Regulatory.Affairs@akzonobel.com

Emergency telephone : 020 99 60 00 Kemiakuten, SE +31 57 06 79 211 AkzoNobel, NL

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance liquid

Color yellow

Odor ammoniacal

GHS Classification

Acute toxicity (Oral) : Category 4

Skin corrosion : Category 1B

Serious eye damage : Category 1

Specific target organ systemic

toxicity

- single exposure : Category 3 (Respiratory system)

Specific target organ systemic

toxicity

- repeated exposure

(Oral) : Category 2 (Gastrointestinal tract)

Aspiration hazard : Category 1

Acute aquatic toxicity : Category 1

Chronic aquatic toxicity : Category 1

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H302 Harmful if swallowed.

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2 / 13 H304 May be fatal if swallowed and enters airways.

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

H373 May cause damage to organs (Gastrointestinal tract)

through prolonged or repeated exposure if swallowed.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements : Prevention:

P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.

P280 Wear protective gloves/ protective clo thing/ eye

protection/ face protection.

Response:

P301 + P310 IF SWALLOWED: Immediately call a POISON

CENTER or doctor/ physician.

P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off

immediately all contaminated clothing. Rinse skin with water/

show er.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/

physician.

Potential Health Effects

Inhalation : Inhalation of aerosols may cause irritation to mucous

membranes.

Thermal decomposition can lead to release of irritating gases

and vapors.

May cause respiratory irritation.

May be fatal if swallowed and enters airways.

Inhalation may cause central nervous system effects.

Skin : Burns may occur several hours after the removal of the

product.

Symptoms may be delayed.

Causes severe skin burns.

The product may be absorbed through the skin.

Eyes : Vapor in the eyes may cause irritation and pain.

Causes severe eye burns.

Ingestion : Harmful if swallowed.

May cause irritation of the mucous membranes.

Causes burns.

May be fatal if swall owed and enters airways.

Aggravated Medical

Condition : None known.

Symptoms of Overexposure : No information available.

Carcinogenicity:

IARC : No ingredient of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed

human carcinogen by IARC.

OSHA : No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential

carcinogen by OSHA.

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3 / 13 NTP : No component of this product present at levels greater than or

equal to 0.1% is identified as a known or a nticipated

carcinogen by NTP.

ACGIH : No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential

carcinogen by ACGIH.

# ARMEEN OL

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4 / 13 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous ingredients

Chemical Name CAS

- No. Classification Concentration [%]

Oleylamine 112

- 90

- 3 Acute Tox. 4; H302

Skin Corr. 1B; H314

Eye Dam. 1; H318

STOT SE 3; H335

STOT RE 2; H373

Asp. Tox. 1; H304

Aquatic Acute 1; H400

Aquatic Chronic 1; H410

M

- Factor (Acute): 10 90

- 100

For the full text of the H

- Statements mentioned in this Section, see Section 16.

The following substances have multiple CAS

- number

Oleylamine : 1213789

- 63

- 9

4. FIRST AID MEASURES

General advice : Immediate medical attention is required.

Move out of dangerous area.

Show this material safety data sheet to the doctor in

attendance.

Burns may occur several hours after the removal of the

product.

Inhalation : Obtain medical attention immediately.

If breathed in, move person into fresh air.

Skin contact : Take off contaminated clothing and shoes immediately.

Wash skin immediately with 0,5 % acetic acid in water, and

then with soap and water.

Immediate medical treatment is necessary as untreated

wounds from corrosion of the skin heal slowly and with

difficulty.

Skin irritation, if untreated, may be prolonged an d serious

(e.g., necrosis). This may be prevented by early treatment

with medium strenght corticosteroids.

Eye contact : In case of contact with eyes, rinse immediately with 0.5%

acetic acid in water for a few minutes, followed by rinsing with

plenty o f water.

Get medical attention immediately. Continue to rinse during

transport of patient.

Remove contact lenses.

Protect unharmed eye.

Keep eye wide open while rinsing.

Small amounts splashed into eyes can cause irreversible

tissue damage and blindness.

Ingestion : Clean mouth with water and drink afterwards plenty of water.

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5 / 13 Never give anything by mouth to an unconscious person.

Take victim immediately to hospital.

Do not induce vomiting! May cause chemical burns in mouth

and throat.

Notes to physician

Symptoms : No information available.

Risks : No information available.

Treatment : No information available.

5. FIRE

- FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Unsuitable extinguishin g

media : High volume water jet

Specific hazards during fire

fighting / Specific hazards

arising from the chemical : Treat as oil fire.

Do not use a solid water stream as it may scatter and spread

fire.

Water spray may be ineffective unless used by experienced

firefighters.

Do not allow run

- off from fire fighting to enter drains or water

courses.

Combustion products : Carbon oxides

Nitrogen oxides (NOx)

Special protective equipment

for fire

- fighters : Wear self

- contained breathing apparatus and protective suit.

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must

be disposed of in accordance with local regulations.

See also Section 9. Physical and chemical properties: Safety data

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Use personal protective equipment.

Wear respiratory protection.

Ensure adequate ventilation.

Environmental precautions : Do not flush into surface water or sanitary sewer system.

If the product contaminates rivers and lakes or drains inform

respective authorities.

Methods for cleaning up /

Methods for containment : Soak up with inert absorbent material (e.g. sand, silica gel,

acid binder, universal binder, sawdust).

Keep in suitable, closed containers fo r disposal.

Additional advice : For personal protection see section 8.

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6 / 13 7. HANDLING AND STORAGE

Handling

Advice on safe handling : For personal protection see section 8.

Avoid formation of aerosol.

Do not breathe vapors or spray mist.

Smoking, eating and drinking should be prohibited in the

application area.

Dispose of rinse water in accordance with local and national

regulations.

Advice on protection against

fire and explosion : Normal measures for preventive fire protection.

Storage

Requirements for storage

areas and containers : Prevent unauthorized access.

Keep container tightly closed in a dry and well

- ventilated

place.

Avoid elevated temperatures.

Reacts with copper, aluminum, zinc and their alloys

Other data : No decomposition if stored and applied as directed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Contains no substances with occupational exposure limit values.

Engineering measures

Provide eyewash station and safety shower. Keep solutions of 0.5% acetic acid in water close at

hand.

Effective exhaust ventilation system

Personal protective equipment

Eye/face protection : Tightly fitting safety goggles

Wear face

- shield and protective suit for abnormal processing

problems.

Hand protection : Glove material: Nitrile rubber

: Glove material: butyl

- rubber

Skin and body protection : Protective suit

Respiratory protection : In the case of vapor formation use a respirator with an

approved filter.

Wear full face mask supplied with:

Combination filter: ABEKP.

Hygiene measures : Avoid contact with skin, eyes and clothing.

When using do not eat or drin k.

When using do not smoke.

Dry

- clean contaminated clothing before reuse.

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7 / 13 Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.

If the product contaminates rivers and lakes or drains inform

respective authorities.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form : liquid

Color : yellow

Odor : ammoniacal

Odor Threshold : No data available

Safety data

pH : not determined

Melting point/range : 10

- 20 °C

Boiling point/boiling range : > 300 °C

Flash point : > 150 °C

Method: Pensky

- Martens closed cup

Ignition temperature : > 100 °C

Evaporation rate : not determined

Flammability (solid, gas) : The product is not flammable.

Lower explosion limit : No data available

Upper explosion limit : No data available

Vapor pressure : < 0.1 hPa at 20 °C

Relative vapor density : No data available

Density : 790 kg/m3 at 60 °C

Relative density : 0.795 at 80 °C

Water solubility : insoluble

Solubility in other solvents : Soluble in alcohols and hydrocarbons.

Partition coefficient: n

octanol/water : No data available

Autoignition temperature : 265 °C

Dec omposition temperature : No data available

Viscosity, dynamic : 4.93 mPa.s at 20 °C

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8 / 13 Viscosity, kinematic : not determined

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

This material safety datasheet on ly contains information relating to safety and does not replace any

product information or product specification.

10. STABILITY AND REACTIVITY

Conditions to avoid : Extremes of temperature and direct sunlight.

Materials to avoid : Reacts with copper, aluminum, zinc and their alloys

Oxidizing agents

Hazardous decomposition

products : No hazardous decomposition products are known.

Thermal decomposition : No data available

Reactivity : Stable under normal conditions.

Chemical stability : Stable under recommended storage conditions.

Hazardous reactions : No dangerous reaction known under conditions of normal use.

11. TOXICOLOGICAL INFORMATION

PRODUCT INFORMATION:

Toxicology Assessment

Further information : May cause damage to organs through prolonged or repeated

exposure.

Carcinogenicity:

IARC : No ingredient of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed

human carcinogen by IARC.

OSHA : No ingredient of this product present at levels grea ter than or

equal to 0.1% is identified as a carcinogen or potential

carcinogen by OSHA.

NTP : No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated

carcinogen by NTP.

ACGIH : No ingredie nt of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential

carcinogen by ACGIH.

TOXICOLOGY DATA FOR THE INGREDIENTS:

Test result

Component: Oleylamine

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9 / 13 Acute oral toxicity : LD50: > 300

- 2,000 mg/kg

Species: rat

Read

- across (Analogy)

Skin irritation : Result: Causes burns.

Target Organ Systemic

Toxicant

- Single exposure : Routes of exposure: Inhalation

Target Organs: Respiratory Tract

May cause respiratory irritation.

Target Organ Systemic

Toxicant

- Repeated

exposure : Routes of exposure: Oral

Target Organs: Gastrointestinal tract

May cause damage to organs through prolonged or repeated

exposure.

Aspiration toxicity : May be fatal if swallowed and enters airways.

12. ECOLOGICAL INFORMATION

PRODUCT INFORMATION:

Ecotoxicology Assessment

Additional ecological

information : An environmental hazard cannot be excluded in the event of

unprofessional handling or disposal.

Very toxic to aquatic life with long lasting effects.

Further information on ecology

Hazardous to the ozone layer

Regulation : 40 CFR Protection of Environment; Part 82 Protection of

Stratospheric Ozone

- CAA Section 602 Class I Substances

Remarks : This product neither contains, nor was manufactured with a

Class I or Class II ODS as defined by the U.S. Clean Air Act

Section 602 (40 CFR 82, Subpt. A, App.A + B).

INGREDIENTS:

Test result

Component: Oleylamine

Ecotoxicity effects

Toxicity to fish : LC50: > 0.01

- 0.1 mg/l

Exposure time: 96 h

Species: Pimephales promelas (fathead minnow)

Method: OECD Test Guideline 203

Read

- across (Analogy)

Toxicity to daphnia and other

aquatic invertebrates : EC50: > 0.01

- 0.1 mg/l

Exposure time: 48 h

Species: Daphnia magna (Water flea)

Method: OECD Test Guideline 202

Read

- across (Analogy)

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10 / 13 Toxicity to algae : EC50: > 0.01

- 0.1 mg/l

Exposure time: 72 h

Species: Desmodesmus subspicatus (green algae)

Method: OECD Test Guideline 201

Read

- across (Analogy)

M

- Factor : 10

Elimination information (persistence and degradability)

Bioaccumulation : Bioconcentration factor (BCF): > 500

Mobility : Can be leached out from soil.

Biodegradability : Result: Readily biodegradable.

Method: OECD Test Guideline 301D

Further information on ecology

Biochemical Oxygen

Demand (BOD) : No data available

13. DISPOSAL CONSIDERATIONS

Product : The product should not be allowed to enter drains, water

courses or the soil.

Do not contaminate ponds, waterways or ditches with

chemical or used container.

Hazardous waste

Dispose of contents/container in accordance with local

regulation.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.

14. TRANSPORT INFORMATION

International regulation

IATA

- DGR

UN/ID No. : UN 2735

Proper shipping name : Amines, liquid, corrosive, n.o.s.

(Alkylamine)

Class : 8

Packing group : II

Labels : 8

Packing instruction (cargo

aircraft) : 855

Packing instruction

(passenger aircraft) : 851

Packing instruction (LQ) : Y840

Environmentally hazardous : yes

IMDG

- Code

UN number : UN 2735

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11 / 13 Proper shipping name : AMINES, LIQUID, CORR OSIVE, N.O.S.

(Alkylamine)

Class : 8

Packing group : II

Labels : 8

EmS Code : F

- A

, S

- B

Marine pollutant : yes

(Alkylamine)

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

Domestic regulation

49 CFR

UN/ID/NA number : UN 2735

Proper shipping name : Amines, liquid, corrosive, n.o.s.

: (Alkylamine )

Class : 8

Packing group : II

Labels : 8

ERG Code : 153

Marine pollutant : yes

(Alkylamine )

Reportable Quantity : This product does not contain an environmentally hazardous

substance per 49 CFR 172.101, Appendix A.

15. REGULATORY INFORMATION

Notification status

CH INV : YES

. On the inventory, or in compliance with the inventory

TSCA : YES

. All chemical substances in this product are either listed on the

TSCA Inventory or in compliance with a TSCA Inventory exemption.

DSL : YES

. All components of this product are on the Canadian DSL.

AICS : YES

. On the inven tory, or in compliance with the inventory

NZIoC : YES

. On the inventory, or in compliance with the inventory

ENCS : YES

. On the inventory, or in compliance wi th the inventory

ISHL : YES

. On the inventory, or in compliance with the inventory

KECI : YES

. On the inven tory, or in compliance with the inventory

PICCS : YES

. On the inventory, or in compliance with the inventory

IECSC : YES

. On the inventory, or in compliance with the inventory

For explanation of abbreviations, see section 16.

OSHA Hazards : Toxic by ingestion, Corrosive to skin, Corrosive to eyes,

Corrosive to respiratory system

EPCRA

- Emergency Planning and Community Right

- to

- Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 E HS RQ.

SARA 311/312 Hazards : Acute Health Hazard

SARA 302 : SARA 302: No chemicals in this material are subject to the

reporting requirements of SARA Title III, Section 302.

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12 / 13 SARA 313 : SARA 313: This material does not contain any chemical

components with known CAS numbers that exceed the

threshold (De Minimis) reporting levels established by SARA

Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air

Act Section 12 (40 CFR 61).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for

Accidental Release Pre vention (40 CFR 68.130, Subpart F).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI

Intermediate or Final VOC's (40 CFR 60.489).

Clean Water Act

This product does not contain any H azardous Substances listed under the U.S. CleanWater Act,

Section 311, Table 116.4A.

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,

Section 311, Table 117.3.

This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307

.

California Prop. 65

This product does not contain any chemicals known to the State of California to cause cancer, birth,

or any other reproductive defects.

16. OTHER INFORMATION

Full text of H

- Statements

H302 : Harmful if swallowed.

H304 : May be fatal if swallowed and enters airways.

H314 : Causes severe skin burns and eye damage.

H318 : Causes serious eye damage.

H335 : May cause respiratory irritation.

H373 : May cause damage to organs through prolonged or repeated

exposure if swallowed.

H400 : Very toxic to aquatic life.

H410 : Very toxic to aquatic life with long lasting effects.

Further information

HMIS Classification : Health Hazard: 3

Flammability: 1

Reactivity: 0

NFPA Classification : Health Hazard: 3

Fire Hazard: 1

Reactivity Hazard: 0



# 0 1

3

# ARMEEN OL

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13 / 13 Notification status explanation

REACH 1907/2006 (EU)

CH INV Switzerland. New notified substances and declared preparations

TSCA United States TSCA Inventory

DSL Canadian Domestic Substances List (DSL)

AICS Australia Inventory of Chemical Substances (AICS)

NZIoC New Zealand. Inventory of Chemical Substances

ENCS Japan. ENCS

- Existing and New Chemical Substances Inventory

ISHL Japan. ISHL

- Inventory of Chemical Substances (METI)

KECI Korea. Korean Existing Chemicals Inventory (KECI)

PICCS Philippines Inventory of Chemicals and Chemical Substances

(PICCS)

IECSC China. Inventory of Existing Chemical Substances in China (IECSC)

Further information

Revision Date 06/09/2014

AkzoNobel, Tomorrow's Answers Today are trademarks of the AkzoNobel N.V. For more

information on our brands and products please visit: www.akzonobel.com/brands_products

The information in this material safety data sheet should be provided to all who will use, handle,

store, transport or otherwise be exposed to this product. The user must determine the

appropriate measures that need to be implemented for the use and handling of this product in

the c ontext of the user's operations and use of this product. The information contained herein

supersedes all previously issued bulletins on the subject matter covered. If the date on this

document is more than three years old,call to make certain that this sheet is current. No warranty

is made as to the product’s me rchantability or fitness for any particular purpose, or that any

suggested use will not infringe any patent. User must determine for himself, by preliminary tests

or otherwise, the suitability of this product for his purposes, including mixing with other p roducts.

Nothing contained herein shall be construed as granting or extending any license under any

patent.

The information provided in this Material Safety Data Sheet is correct to the best of our

knowledge, information and belief at the date of its publication. The information given is designed

only as a guidance for safe handling, use, processing, storage, tr ansportation, disposal and

release and is not to be considered a warranty or quality specification. The information relates

only to the specific material designated and may not be valid for such material used in

combination with any other materials or in a ny process, unless specified in the text.