# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions** Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information** Parent Company

Name:
Address: City: Country: USA
Size of Company

(approximate number of employees including all subsidiaries, branches, and related establishments owned):
**PVC Production Facility General Information** Facility Name: Facility Address: Facility City: Facility Technical Contact Name: Technical Contact Telephone Number:
Technical Contact Email: Number of employees attached to the PVC production facility: Baton Rouge P.O. Box 271 Formosa Plastics Corporation, USA

225-358-8511 OWolff@flbr.fpcusa.com Formosa Plastics Corporation, LA. P.O. Box 271 Baton Rouge Omer Wolff

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: LA Zip Code: 70821

Size of Company

(approximate number of employees including all subsidiaries, branches, and related establishments owned):

State: LA Zip Code: 70821

# November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew**ater**

**PVC Production Process Wastew ater Treatment System Information Update** 

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**Form C-1-c Supplemental Questions FORM C-1-c**  **PROCESS EQUIPMENT - WA STEWA**  **TER STEA M STRIPPER**  Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 6807.554liters/hour liters Process Unit ID: P-1 If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: Process Equipment ID: PC-302A/B Wastewater Feed Rate (lb/hr): 15000 CBI liters/hour (max design) Feed Temperature (°F): 185 liters (max design) Feed Inlet Pressure (psia): 94.7 Liquid Loading Rate (liters/m2): Steam Feed Rate (lb/hr): 515 Steam to Feed Ratio (kg steam/liter of wastewater): 0.17 Operating Temperature (°F): 212 Operating Pressure (psig): 0 Total Number of Stages: 1 Overall Calculated Tray Efficiency: Stripping Factor: Flow configuration (countercurrent, cocurrent): countercurrent Number of Actual Trays: 0 Column Height (meters): 8.15 Year Equipment Installed: 1989 Equipment Currently Regulated Under (cite regulations): None 1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage** P-1 XDW 200 800 600Estimated 365 P-1 SW 0 800 400Estimated 365 **Operating Days Per Year**  **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream PVC Process**  **Wastewater Stream ID**  **2**

**Flow Rate Determination**  **Me thod** 

Used Deionized Water **PVC Process Wastewater Stream Flow Rate (gallons per day)** 

Stormwater

# Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System **1 2**  **3 4**  **5 6**  **7 8**  **9 10**  **11**

**Min Ma** **x Av** **erage** P-1 PVCWWS SteamStripping Continuous WWSOUT 43200 57600 53280Measured 365WWT

**Table 3. PVC Process Wastewater Destination Codes Table Code**  Wastewater treatment system WWT Provide name of the wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall Discharge to POTW, no treatment POTWRAW Provide name of POTW Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW Zero discharge or alternative disposal method ZEROALT Describe method Recycle to process RECYC Describe where in the process the stream is recycled Other OTHER Describe **PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below) **Operating Days Per Year**  **Ty pe of Process**  **Wastewater Treatment System** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Destination Description**  **PVC Process Wastewater**  **Treatment System ID**  **PVC Process Unit ID**  **PVC Process Wastewater**  **Stream ID Is this**  **process wastewater**  **treatment system batch**  **or continuous operation?**  **PVC Process Wastewater Stream Flow Rate (gallons per day)**  **Flow Rate Determination**  **Me thod** 

# Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System **2 3**  **4 5**  **6 7** 

**Min Ma** **x Av** **erage** 4320 21600 12960Estimated 365PVCWWS **1**

Condensate **Process Wastewater Stream Flow Rate (gallons per day)**  **Source of Process Wastewater Stream Flow Rate**  **Determination Me** **thod PVC Process**  **Wastewater Treatment**  **System ID Operating Days**  **Per Year**

# 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10**  **11 12**  **13**

PS501A-H,PS504A/B,PS507,PS508A/B Centrifuges WWT Biological Treatment Plant Yes N/A WWT Biological Treatment Plant and/or IOWWPlant Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? Originating PVC Process**  **Equipment Description Originating PVC Process**  **Equipment ID PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below) **As sociated Destination Information** 

# 12 **13**

Biological Treatment Plant Yes

Provide name of the wastewater treatment system

Describe where in the process the stream is recycled **14**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system**  **As sociated Destination**  **Information** (Refer to Table 3 below) **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Instructions** 

**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)** 107211 Ethylene glycol SW-846-8015C 2 Non-detect 2 Non-detect 2 Non-detect 2 Non-detect 2 Non-detect 67561 Methanol SW-846-8015C 23 18.4 22.5 14.8 17.6
75070Acetaldehyde SW-846-8315A 1.1 0.18 0.18 0.77 0.5
50000 Formaldehyde SW-846-8315A 0.25 0.02 Non-detect 0.023 0.18 0.15 512852,4-dinitrophenol SW-846-8270D 0.02 Non-detect 0.02 Non-detect 0.02 Non-detect 0.1 Non-detect 0.1 Non-detect 98862Acetophenone SW-846-8270D 3.1 4.3 4 3.3 4.7
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 15 52 62 44 19
123319 Hydroquinone SW-846-8270D 0.023 Analyte also detected in method blank. 0.015 Analyte also detected in method blank. 0.02 Analyte also detected in method blank. 0.019 0.039 108952 Phenol SW-846-8270D 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.025 Non-detect 0.025 Non-detect 79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 106990 1,3-butadiene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 540841 2,2,4-trimethylpentane SW-846-8260B 0.001 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 71432 Benzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 108907Chlorobenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 67663Chloroform SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 126998Chloroprene SW-846-8260B 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect
98828Cumene (Isopropylbenzene) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 75003Ethyl chloride (Chloroethane) SW-846-8260B 0.0047 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 100414 Ethylbenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 74873Methyl chloride (Chloromethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 75092 Methylene chloride SW-846-8260B 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 110543n-Hexane SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect
108883Toluene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 79005 1,1,2-Trichloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 108054Vinyl acetate SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 593602Vinyl bromide SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 75014Vinyl chloride EPA Method 107 0.047 0.028 0.026 0.018 0.028 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
1330207Xylenes (isomers and mixtures) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect Total Organic HAP 42.5247 74.923 88.749 63.087 42.019 TOHAP Limit 110 110 110 110 110 **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**4 5**  **Sample Date -->**01/02/13 01/03/13 01/04/13 01/05/13 01/06/13 **1 2**  **3 Resin Type (suspension, dispersion, bulk, etc.) -->** Suspension Suspension Suspension Suspension Suspension

**Stream Flow Rate (gallons per minute) -->**37.19784927 35.6336937 39.68677521 30.08255386 34.66871643 **Flow Rate Determination Method -->** Estimated Estimated Estimated Estimated Estimated **Stream Temperature (degrees F) -->**63 80 65 90 85

**Analysis Date -->**Refer to Lab Report Refer to Lab Report Refer to Lab Report Refer to Lab Report Refer to Lab Report **Lab Report ID -->**L0024127 L0024312 L0024314 L0024382 L0024383 **Lab Sample ID -->**L0024127-01 L0024312-01 L0024314-01 L0024382-01 L0024383-01 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 6. Enter any notes or additional information relevant to the sampling or analysis. 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  2 Non-detect 2 Non-detect 2 Non-detect 2 Non-detect 14 18.1 17.4 17.4
0.46 0.79 1.8 1.6
0.11 0.29 0.028 0.064 0.1 Non-detect 0.1 Non-detect 1 Non-detect 1 Non-detect 3.6 0.98 0.85 12
12 27 17 4.6
0.02 0.033 0.034 Analyte also detected in method blank. 0.5 Non-detect 0.025 Non-detect 0.025 Non-detect 0.25 Non-detect 0.25 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0033 0.022 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.020 0.026 0.035 0.046 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
30.21 47.219 37.1503 35.732 110 110 110 110 **6 7**  **8 9**  01/07/13 01/08/13 01/09/13 01/10/13 Suspension Suspension Suspension Suspension 36.70422363 29.75096703 39.09373474 39.33853149 Estimated Estimated Estimated Estimated 70 60 69 98 Refer to Lab Report Refer to Lab Report Refer to Lab Report Refer to Lab Report L0024382 L0024432 L0024645 L0024382-01 L0024432-01 L0024645-01

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  2 2 Non-detect 2 Non-detect 2 Non-detect 20.9 24.2 21.7 21.2
0.96 3.9 3.2 1.1
0.02 Non-detect 0.2 Non-detect 0.2 Non-detect 0.025 1 Non-detect 1 Non-detect 1 Non-detect 1 Non-detect 70 5 6.8 3.8
9 3.5 1.4 2.3
0.5 Non-detect 0.1 Non-detect 0.1 Non-detect 0.1 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.25 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.07 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.079 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 1.2 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect
0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.033 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0031 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.5 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.1 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect
0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.1 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.038 0.017 0.101 0.036 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
103.047 36.617 33.201 28.5001 110 110 110 110 **13 10**  **11 12**  01/13/13 01/14/13 01/11/13 01/12/13 Suspension Suspension Suspension Suspension 35.19090652 34.41859818 39.91190338 39.5332756 Estimated Estimated Estimated Estimated 66 68 67 77 Refer to Lab Report Refer to Lab Report Refer to Lab Report L0024646 L0024755 Refer to Lab Report L0024742 L0024756 L0024646-01 L0024755-01 L0024742-01 L0024756-01

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  2 Non-detect 2 Non-detect 2 Non-detect 2 Non-detect 23.9 20.1 23.5 21.7
0.52 0.4 0.19 0.4
0.05 0.057 0.23 0.18 0.1 Non-detect 1 Non-detect 1 Non-detect 1 Non-detect 5.8 2.5 2.7 1.9
3.7 1.6 5.4 9.2
0.99 0.21 0.1 Non-detect 0.1 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.00038 Non-detect 0.0005 Non-detect 0.0025 Non-detect 0.0005 Non-detect 0.00012 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00017 Non-detect 0.005 Non-detect 0.025 Non-detect 0.005 Non-detect 0.00021 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00036 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00036 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00068 Non-detect 0.025 Non-detect 0.12 Non-detect 0.025 Non-detect
0.0003 Estimated value between MDL and PQL 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.0029 0.001 Non-detect 0.005 Non-detect 0.0019 0.0002 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00034 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00029 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00036 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00081 Non-detect 0.01 Non-detect 0.05 Non-detect 0.01 Non-detect 0.00081 Non-detect 0.002 Non-detect 0.01 Non-detect 0.002 Non-detect
0.0003 Estimated value between MDL and PQL 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00025 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00035 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00033 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.00029 Non-detect 0.002 Non-detect 0.01 Non-detect 0.002 Non-detect 0.020 0.020 0.013 0.021 0.00041 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect
0.0002 Non-detect 0.001 Non-detect 0.0075 Estimated value between MDL and PQL 0.001 Non-detect
34.9835 24.887 32.0405 33.4029 110 110 110 110 **14 15**  **16 17**  01/15/13 01/16/13 01/17/13 01/18/13 Suspension Suspension Suspension Suspension 39.47657394 34.97198868 39.15098953 29.60000038 Estimated Estimated Estimated Estimated 80 69 68 58 Refer to Lab Report Refer to Lab Report Refer to Lab Report L0024930 Refer to Lab Report
L0024791-01 L0024929-01 L0024930-01 L0024754-01 L0024754 L0024791 L0024929

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  4.9 5.6 2 Non-detect 2 Non-detect 37.1 24.2 19.8 18.9
1.4 0.76 1.1 1.7
0.065 0.023 0.064 0.16 Analyte also detected in method blank. 1 Non-detect 1 Non-detect 1 Non-detect 0.1 Non-detect 18 14 3 7.7
1.9 3.1 4.2 1.1
0.7 1.9 0.17 1.6 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.003 Non-detect 0.025 Non-detect 0.025 Non-detect 0.0025 Non-detect 0.0038 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0012 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.0017 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0021 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0036 Non-detect 0.5 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0036 Non-detect 1.2 Non-detect 1.2 Non-detect 0.12 Non-detect 0.0068 Non-detect
0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0023 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0066 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.002 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0034 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0029 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0036 Non-detect 0.5 Non-detect 0.5 Non-detect 0.05 Non-detect 0.0081 Non-detect 0.1 Non-detect 0.1 Non-detect 0.01 Non-detect 0.0081 Non-detect
0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0027 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0025 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0035 Non-detect 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0033 Non-detect 0.1 Non-detect 0.1 Non-detect 0.01 Non-detect 0.0029 Non-detect 0.077 0.025 0.039 0.070 0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.0041 Non-detect
0.05 Non-detect 0.05 Non-detect 0.005 Non-detect 0.002 Non-detect
64.142 49.608 28.373 31.2366 110 110 110 110 **19 20**  **21 18**  01/19/13 01/20/13 01/21/13 01/22/13 Suspension Suspension Suspension Suspension 39.9439621 39.87981796 39.67871094 43.60550308 Estimated Estimated Estimated Estimated 58 71 70 58 Refer to Lab Report Refer to Lab Report Refer to Lab Report Refer to Lab Report L0024986 L0024985 L0024984 L0025039 L0025039-01 L0024986-01 L0024985-01 L0024984-01

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  2 Non-detect 2.7 2 Non-detect 2 Non-detect 23 16.7 13.5 10.7
10 1 0.94 1.2 Analyte also detected in method blank. 0.5 Non-detect 0.02 Non-detect 0.062 0.096 1 Non-detect 1 Non-detect 1 Non-detect 1 Non-detect 11 3 1.9 1.4
0.84 0.96 0.41 0.51
0.19 1.6 2.9 1.1 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.0005 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.005 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0038 0.001 Non-detect 0.001 Non-detect 0.0011 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.0011 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.065 0.023 0.011 0.032 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect
45.0999 25.983 19.723 15.0391 110 110 110 110 **22 23**  **24 25**  01/23/13 01/24/13 01/25/13 01/26/13 Suspension Suspension Suspension Suspension 39.79145813 30.1038208 41.38405609 39.5979805 Estimated Estimated Estimated Estimated 72 72 54 75 Refer to Lab Report Refer to Lab Report Refer to Lab Report Refer to Lab Report L0025204 L0025312 L0025077 L0025203 L0025077-01 L0025203-01 L0025204-01 L0025312-01

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  2 Non-detect 2 Non-detect 2 Non-detect 2.1 19 12.2 19.3 20.1
2.2 Analyte also detected in method

blank. 1.1 Analyte also detected in method blank. 8.3 35
0.5 Non-detect 0.1 Non-detect 0.15 Estimated value between MDL and PQL 0.5 Non-detect 1 Non-detect 1 Non-detect 0.1 Non-detect 1 Non-detect 4.8 1.2 4.2 4.6
0.25 Non-detect 0.42 0.19 Estimated value between MDL and PQL 0.25 Non-detect
2 0.1 Non-detect 1.3 2 0.25 Non-detect 0.25 Non-detect 0.003 Non-detect 0.25 Non-detect 0.025 Non-detect 0.0005 Non-detect 0.0038 Non-detect 0.025 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0012 Non-detect 0.05 Non-detect 0.25 Non-detect 0.005 Non-detect 0.0017 Non-detect 0.25 0.05 Non-detect 0.001 Non-detect 0.0021 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0036 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0036 Non-detect 0.05 Non-detect 1.2 Non-detect 0.025 Non-detect 0.0068 Non-detect 1.2 Non-detect
0.05 Non-detect 0.001 Non-detect 0.0023 Non-detect 0.05 Non-detect 0.05 Non-detect 0.0014 0.14 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.002 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0034 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0029 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.01 0.05 Non-detect 0.5 Non-detect 0.01 Non-detect 0.0081 Non-detect 0.5 Non-detect 0.1 Non-detect 0.002 Non-detect 0.0081 Non-detect 0.1 Non-detect
0.05 Non-detect 0.001 Non-detect 0.0027 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0025 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0035 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.0033 Non-detect 0.05 Non-detect 0.1 Non-detect 0.002 Non-detect 0.0029 Non-detect 0.1 Non-detect 0.021 0.019 0.204 0.107 0.05 Non-detect 0.001 Non-detect 0.0041 Non-detect 0.05 Non-detect
0.05 Non-detect 0.001 Non-detect 0.002 Non-detect 0.05 Non-detect
28.021 14.9404 33.794 64.157 110 110 110 110 **28 29**  **26 27**  01/27/13 01/28/13 01/29/13 01/30/13 Suspension Suspension Suspension Suspension 40.34253311 39.46036148 40.11184311 39.66257858 Estimated Estimated Estimated Estimated 67 66 74 78 Refer to Lab Report Refer to Lab Report Refer to Lab Report Refer to Lab Report L0025313 L0025311 L0025338 L0025373 L0025338-01 L0025373-01 L0025313-01 L0025311-01

EPA-HQ-OAR-2002-0037-0580**PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method** 107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C
75070Acetaldehyde SW-846-8315A
50000 Formaldehyde SW-846-8315A 512852,4-dinitrophenol SW-846-8270D 98862Acetophenone SW-846-8270D
117817Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D
123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907Chlorobenzene SW-846-8260B 67663Chloroform SW-846-8260B 126998Chloroprene SW-846-8260B
98828Cumene (Isopropylbenzene) SW-846-8260B 75003Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543n-Hexane SW-846-8260B
108883Toluene SW-846-8260B 71556Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054Vinyl acetate SW-846-8260B 593602Vinyl bromide SW-846-8260B 75014Vinyl chloride EPA Method 107 75354Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B
1330207Xylenes (isomers and mixtures) SW-846-8260B Total Organic HAP TOHAP Limit **COMPANY:**Formosa Platics Corporation, USA **FACILITY:**Formas Plartics Corporation, LA

**Sample Date -->**

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->**  **Stream Temperature (degrees F) -->**

**Analysis Date --> Lab Report ID -->**  **Lab Sample ID -->** 

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers **(PVC) Production Process Wastewater**
**PVC Production Process Wastewater Sampling and Analysis Data**

**Concentration (ppmw)**  **Non-Detect? Note(s)** 

2 Non-detect 15.2
0.88
0.064 1 Non-detect 4.9
0.25 Non-detect
0.25 0.25 Non-detect 0.0005 Non-detect 0.001 Non-detect 0.005 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.025 Non-detect
0.001 Non-detect 0.0072 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.01 Non-detect 0.002 Non-detect
0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.015 0.001 Non-detect
0.001 Non-detect
21.3162 110 **30** 01/31/13 Suspension 40.23133087 Estimated 55 Refer to Lab Report L0025447 L0025447-01

EPA-HQ-OAR-2002-0037-0580