INITI AL REVIEW ENGI NEERI NG REPORT 

PMN : 15- 02 47 

Focus Ready Draft 2/1 9/2015 

ENGI NEER: Jon \ DOH 

PV (kg/yr) : 33 , 000 

SUBMI TTER : H. B. Fu ller Compan y 

MSDS : Yes Label : No 

Gen Eqpt: Wear safety g l asses . II Wear chemically resi stan t g l oves and 

long sleeved shir t . // Use local exhau st ventila tion or oth er 

e ng i neeri ng cont r o l s to minimi ze exposu re . 

Respirator : Use a respirator i f general room ven tila t ion i s not 

avai l abl e o r suffi c i ent to e liminate symptoms . NIOSH approved air 

p u r i fying respirator with o r gani c vapor car tri dge . 

Heal t h Effects : Eyes : Can cause i rri t ati o n . I Ski n : Can cause moderate 

ski n i r r i tat ion, def atting, and dermat iti s . Not l i kely to cause 

perman ent damage . May cause sensiti zat ion . // Inha l a t ion : Can cause 

moderat e respi rat ory irr i tation . May cause a l l e r g i c r espi rat ory 

r eaction . Other possi ble symptoms i n c l ude : wheezing and cough i ng due 

t o pul mon ary edema (flu i d b u ild - u p in l ungs) . If produ ct i s heat ed or 

if a n aer osol/mi s t i s generated, a i rbone concen trations may be reached 

t h at cause i r r i t ati on or o t h er adverse e f f ects . Inhalati on o f h igh 

concen t rati o n s may resu l t in centr a l n ervou s system (CNS) effects such 

as d i zzi ness, weakness, f a t igue , nausea, headach e , a nd l ack o f 

coordinati o n . //Ingestion : Harmf ul i f swallowed . Ingesti on i s n ot an 

a n t i cipated rou te o f exposure . Irri tating t o mouth , t h roat, a nd stomach . 

II Chr oni c Ef f ect s : May cau se t umors based on tests with l aborat ory 

a n i mals . //Target Organs : Lungs, S k in . 

TLV/ PEL: 

Ethyl Acetat e (CASRN 14 1- 78 - 6) 30 wt% 400 ppm TWA ACGI H Exposure Limi ts 

Ethyl Acetat e (CASRN 1 41- 78 - 6) 30 wt% 400 ppm TWA OSHA PEL 

Ethyl Acetat e (CASRN 1 41- 78 - 6) 30 wt% 1400 mg/m3 TWA OSHA PEL 

Methylene Bisphen y l Di isocyanate (MDI ) (CASRN 101- 68 - 8) 5 wt% 0 . 005 ppm 

TWA (listed under Me t hyl ene b i sphenyl isocyanate (MDI )) ACGI H Exposu re 

Limi ts 

Methylene Bi sph enyl Di isocyanate (MDI ) (CASRN 1 01 - 68 - 8) 5 wt% 0 . 02 ppm 

Ceiling OSHA PEL 

Methylene Bisphen y l Di isocyanate (MDI ) (CASRN 101- 68 - 8) 5 wt% 0 . 2 mg/m3 

Ceiling OSHA PEL 
2/ 10/201 5) : 

Re l ated Case c SAT Inf o · 

Simila r Case . Analogs : 

Migration to r : Hyd 

PBT rating : P3B1Tl PMN : Pl Bl Tl ; Hyd Pd t : P3B1Tl 

Heal th : 1- 2 Dermal, I nhal a t ion 

Eco : 1 No releases to water 
OCCUPAT I ONAL EXPOSURE RATI NG : 2B 

NOTES & KEY ASSUMPTIONS : 

EXPOSURE- BASED REVI EW : No 
INITI AL REVIEW ENGI NEERI NG REPORT 

PMN : 15- 024 7 

Manufacturing 

Number o f Sit tion : 2 

H. B. Full er Company Grand Rapi ds MI 49544- 11 98 

H. B. Full er Company Pilot Faci l i t y St. Paul MN 55110 

Days/yr: 3 

ENVI RONMENTAL RELEASES ESTIMATE SUMMARY 

OCCUPAT I ONAL EXPOSURES ESTIMATE SUMMARY 
I nhal a tion : 

n egligibl e (VP < 0 . 00 1 torr ) 

Dermal : 

Expos ure to Li q u id at 66 . 59% concentration 

High End : 

> Po t ent ial Dose Rat e : 1 . 5E+3 mg/day over 3 days/yr 

> Lifetime Ave r age Da ily Dos e : 1 . 0E- 1 mg/day over 3 days/yr 

>Aver age Dail y Dose : 1 . 8E- 1 mg/day over 3 days/yr 

>Acut e Poten t i al Dose : 2 . 1E+ 1 mg/day over 3 days/yr 

Number o f wor ker s (all s i tes) with der ma l exposure : 6 
INITI AL REVIEW ENGI NEERI NG REPORT 

P~ : 

2 

Sonoco Eau Clai re WI 

Plastic Packagi ng Hi ckory NC 

Days/yr: 260 

ENVI RONMENTAL RELEASES ESTIMATE SUMMARY 

OCCUPAT I ONAL EXPOSURES ESTIMATE SUMMARY 
I nhal a tion : 

Exposure to Mi s t (non- vol a t i l e) (Cl ass I ) 

Low End of Range : 

> Potent i a l Dose Rate : 4 . 0E- 1 mg/day over 25 0 days/yr 

> Life time Average Da i ly Dose : 2 . 2E- 3 mg/ kg- day over 25 0 days/yr 

>Aver age Dail y Dose : 3 . 9E- 3 mg/day over 250 days/yr 

>Acut e Potent i al Dose : 5 . 7E- 3 mg/day over 25 0 days/yr 

Hi gh End o f Range : 

> Potent i a l Dose Rate : 2 . 6E+O mg/day over 25 0 days/yr 

> Life time Average Da i ly Dose : 1 .5E- 2 mg/ kg- day over 25 0 days/yr 

>Aver age Dail y Dose : 2 . 5E- 2 mg/day over 250 days/yr 

>Acut e Potent i al Dose : 3 . 7E- 2 mg/day over 25 0 days/yr 

Number o f wor ker s (all s i tes) with i nh a l ation exposur e : 6 

NOTE : The respirator c l ass i s : I . Part icul a t e (inc l uding sol id or l iqui d 

d r opl e t s) . 

INHALAT I ON MONI TORI NG DATA REVIEW 

1) Uncertainty (esti mate based on mode l, 

o r data not speci f i c t o i ndu stry) : 

2)a) Exposur e l evel > 1 mg/day? 

regulatory limit, 

Yes 

OR 

b) Hazard Rating f or healt h o f 2 or great er? 1- 2 

=> I nh a l ati o n Monitoring Dat a Desi red? No 

Dermal : 

Exposure to Li q uid at 66 . 59% concentration 

High End : 

> Po t ent ial Dose Rat e : 1 .5E+3 mg/day over 250 days/yr 

Yes 

No 

> Lifetime Ave r age Da ily Dose : 8 . 4E+O mg/day over 25 0 days/yr 

>Aver age Dail y Dose : 1 . 5E+1 mg/day over 250 days/yr 

>Acut e Potent i al Dose : 2 . 1E+1 mg/day over 25 0 days/yr 

Number o f wo r ker s (all s i tes) with der ma l exposure : 6