# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\691588769209794514\[EPA-HQ-OAR-2013-0290-DRAFT-0075.xls]TK2EE-D-F Data** Date: 12/1/14

Plant name: Kohler Co. Location: Spartanburg, SC Test date: 8/10-8/11/10 Equipment: Tunnel Kiln 2

POC Stack Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 14.2 134.0 4,141 0.438 5.04E-11 0.115 0.241 8.12E-07 1573.9 5.16E-10

2 14.6 134.5 4,150 0.776 8.91E-11 0.204 0.451 1.44E-06 1573.9 9.13E-10 3 14.1 136.1 4,178 0.267 3.03E-11 0.0692 0.1414.92E-07 1632.9 3.01E-10 Average 14.3 4,157 5.66E-11 0.129 0.2789.14E-071593.567 5.73E-10 TEQ 1 M23 14.2 134.0 4,1410.011837 1.36E-12 0.003118 0.0065082.19E-08 1573.9 1.39E-11

2 14.6 134.5 4,150 0.01201 1.38E-12 0.00315 0.006982.22E-08 1573.9 1.41E-11 3 14.1 136.1 4,178 0.01068 1.21E-12 0.002771 0.005661.97E-08 1632.9 1.20E-11 Average 14.3 4,157 1.32E-12 0.003014 0.006382.13E-081593.567 1.34E-11 Notes:

TK2POC-Emission Calcs 1 of 1 12/1/2014

### DIOXIN-FURAN PARTICLE CATCH **Tunnel Kiln 2 POC Stack** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.005870.00633 0.0032 Total TCDD 5.87 6.33 3.2 Total TCDD 5.87 6.33< 3.2 Total PeCDD 0.0042 0.01240.00635 Total PeCDD 4.2 12.4 6.35 Total PeCDD < 4.2 12.4 6.35 Total HxCDD 0.0032 0.0298 0.0292 Total HxCDD 3.2 29.8 29.2 Total HxCDD < 3.2 29.8 29.2 Total HpCDD 0.0345 0.117 0.0478 Total HpCDD 34.5 117 47.8 Total HpCDD 34.5 117 47.8 Total OCDD 0.349 0.578 0.128 Total OCDD 349 578 128 Total OCDD 349 578 128

Total dioxins0.396770.743530.21455 Total TCDF 0.0339 0.0241 0.0265 Total TCDF 33.9 24.1 26.5 Total TCDF 33.9 24.1 26.5 Total PeCDF 0.0024 0.0026 0.0212 Total PeCDF 2.4 2.6 21.2 Total PeCDF < 2.4< 2.6 21.2 Total HxCDF 0.0015 0.0053 0.0033 Total HxCDF 1.5 5.3 3.3 Total HxCDF < 1.5< 5.3< 3.3 Total HpCDF 0.00140.00095 0.0014 Total HpCDF 1.4 0.95 1.4 Total HpCDF < 1.4< 0.95< 1.4 Total OCDF 0.0021 0 0 Total OCDF 2.1 1.6 2 Total OCDF < U 2.1< U 1.6< U 2

Total furans 0.04130.03295 0.0524 TOTAL CDD/CDF0.438070.776480.26695

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEQ Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.0041 0.0025 0.0032 0.0041 0.0025 0.0032 1.0 2,3,7,8 TCDD 4.1 2.5 3.2 2,3,7,8 TCDD < U 4.1< M, U 2.5< U 3.2 1,2,3,7,8 PeCDD 0.00420.00415 0.003 0.00420.00415 0.003 1.0 1,2,3,7,8 PeCDD 4.2 4.15 3 1,2,3,7,8 PeCDD < U 4.2 M, J 4.15< M, U 3 1,2,3,4,7,8 HxCDD 0.0029 0.0027 0.00240.000290.000270.00024 0.1 1,2,3,4,7,8 HxCDD 2.9 2.7 2.4 1,2,3,4,7,8 HxCDD < U 2.9< M, J, R 2.7< U 2.4 1,2,3,6,7,8 HxCDD 0.0032 0.0027 0.00290.000320.000270.00029 0.1 1,2,3,6,7,8 HxCDD 3.2 2.7 2.9 1,2,3,6,7,8 HxCDD < U 3.2< M, J, R 2.7< J, R 2.9 1,2,3,7,8,9 HxCDD 0.0041 0.01 0.00290.00041 0.001 0.00029 0.1 1,2,3,7,8,9 HxCDD 4.1 10 2.9 1,2,3,7,8,9 HxCDD < M, J, R 4.1 M, J 10< M, J, R 2.9 1,2,3,4,6,7,8 HpCDD 0.0345 0.0553 0.0211 0.000350.000550.00021 0.01 1,2,3,4,6,7,8 HpCDD 34.5 55.3 21.1 1,2,3,4,6,7,8 HpCDD M 34.5 55.3 21.1 Total OCDD 0.349 0.578 0.128 0.0001 0.00017 3.8E-05 0.0003 Total OCDD 349 578 128 OCDD 349 578 M 128 Total0.009770.008920.00727 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0071 0.00320.00781 0.00071 0.000320.00078 0.1 2,3,7,8 TCDF 7.1 3.2 7.81 2,3,7,8 TCDF < U 7.1< J, R 3.2 M 7.81 1,2,3,7,8 PeCDF 0.0024 0.0026 0.0033 7.2E-05 7.8E-05 9.9E-05 0.03 1,2,3,7,8 PeCDF 2.4 2.6 3.3 1,2,3,7,8 PeCDF < M, U 2.4< M, U 2.6< U 3.3 2,3,4,7,8 PeCDF 0.0023 0.00250.004360.000690.000750.00131 0.3 2,3,4,7,8 PeCDF 2.3 2.5 4.36 2,3,4,7,8 PeCDF < U 2.3< M, U 2.5 M, J 4.36 1,2,3,4,7,8 HxCDF 0.0016 0.0049 0.0030.000160.00049 0.0003 0.1 1,2,3,4,7,8 HxCDF 1.6 4.9 3 1,2,3,4,7,8 HxCDF < U 1.6< U 4.9< U 3 1,2,3,6,7,8 HxCDF 0.0013 0.0044 0.00280.000130.000440.00028 0.1 1,2,3,6,7,8 HxCDF 1.3 4.4 2.8 1,2,3,6,7,8 HxCDF < J, R 1.3< U 4.4< U 2.8 2,3,4,6,7,8 HxCDF 0.0013 0.0047 0.00290.000130.000470.00029 0.1 2,3,4,6,7,8 HxCDF 1.3 4.7 2.9 2,3,4,6,7,8 HxCDF < U 1.3< U 4.7< U 2.9 1,2,3,7,8,9 HxCDF 0.0015 0.0053 0.00330.000150.000530.00033 0.1 1,2,3,7,8,9 HxCDF 1.5 5.3 3.3 1,2,3,7,8,9 HxCDF < U 1.5< U 5.3< U 3.3 1,2,3,4,6,7,8 HpCDF 0.0011 0.00083 0.0011 1.1E-05 8.3E-06 1.1E-05 0.01 1,2,3,4,6,7,8 HpCDF 1.1 0.83 1.1 1,2,3,4,6,7,8 HpCDF < U 1.1< M, J, U 0.83< U 1.1 1,2,3,4,7,8,9 HpCDF 0.00140.00095 0.0014 1.4E-05 9.5E-06 1.4E-05 0.01 1,2,3,4,7,8,9 HpCDF 1.4 0.95 1.4 1,2,3,4,7,8,9 HpCDF < U 1.4< U 0.95< U 1.4 Total OCDF 0.0021 0.0016 0.002 6.3E-07 4.8E-07 6E-07 0.0003 Total OCDF 2.1 1.6 2 OCDF < U 2.1< U 1.6< U 2 Total0.00207 0.0031 0.00341 **TOTAL CDD/CDF (TEQ)** 0.011840.01201 0.01068 BDL quantities shown as reported. EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency M Indicates that a peak has been manually integrated. U Indicates that this compound was not detected above the MDL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. J Indicates that a target analyte was detected below the LQL. Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK2POC-D-F Data 12/1/2014

### EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample.

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK2POC-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\691588769209794514\[EPA-HQ-OAR-2013-0290-DRAFT-0075.xls]TK2EE-D-F Data** Date: 12/1/14

Plant name: Kohler Co. Location: Spartanburg, SC Test date: 8/10-8/11/10 Equipment: Tunnel Kiln 2

EE Stack Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 20.5 146.0 151 664 7.02E-08 161 62034.12E-05 1573.9 2.62E-08

2 20.5 147.6 151 55.9 5.85E-09 13.4 4903.44E-06 1573.9 2.19E-09 3 20.5 150.0 155 12.4 1.27E-09 2.9 1047.65E-07 1632.9 4.69E-10 Average 20.5 152 2.58E-08 59.0 2265 1.51E-051593.567 9.49E-09 TEQ 1 M23 20.5 146.0 151 3.64 3.85E-10 0.880 34.02.25E-07 1573.9 1.43E-10

2 20.5 147.6 151 0.396 4.14E-11 0.0947 3.462.43E-08 1573.9 1.55E-11 3 20.5 150.0 155 0.141 1.45E-11 0.0332 1.1828.72E-09 1632.9 5.34E-12 Average 20.5 152 1.47E-10 0.336 12.98.62E-081593.567 5.41E-11 Notes:**Need to look into conditions of run 1 because results are a factor of 10 or more higher than the other two runs.**

TK2EE-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Tunnel Kiln 2 EE Stack** Measured wt, ng Measured wt, pg Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Congener Run 1 Run 2 Run 3 Total TCDD 3.26 0.71 0.125 Total TCDD 3260 710 125 Total TCDD 3260 710 125 Total TCDD 3.26 0.71 0.125 Total PeCDD 16.7 1.91 0.736 Total PeCDD 16700 1910 736 Total PeCDD 16700 1910 736 Total PeCDD 16.7 1.91 0.736 Total HxCDD 53.4 4.61 1.29 Total HxCDD 53400 4610 1290 Total HxCDD 53400 4610 1290 Total HxCDD 53.4 4.61 1.29 Total HpCDD 106 8.73 1.81 Total HpCDD 106000 8730 1810 Total HpCDD 106000 8730 1810 Total HpCDD 106 8.73 1.81 Total OCDD 484 39.9 8.38 Total OCDD 484000 39900 8380 Total OCDD 484000 39900 8380 Total OCDD 484 39.9 8.38

Total dioxins 663.36 55.86 12.341 Total TCDF 0.324 0.0270.00899 Total TCDF 324 27 8.99 Total TCDF 324< 27 8.99 Total TCDF 0.324 0.0270.00899 Total PeCDF 0.222 0.02150.00792 Total PeCDF 222 21.5 7.92 Total PeCDF 222 21.5 7.92 Total PeCDF 0.222 0.02150.00792 Total HxCDF 0.0731 0.0084 0.0029 Total HxCDF 73.1 8.4 2.9 Total HxCDF 73.1< 8.4< 2.9 Total HxCDF 0.0731 0.0084 0.0029 Total HpCDF 0.0496 0.011 0.0041 Total HpCDF 49.6 11 4.1 Total HpCDF 49.6< 11< 4.1 Total HpCDF 0.0496 0.011 0.0041 Total OCDF 0.19 0 0 Total OCDF 190 12 3.1 Total OCDF M 190< M, U 12< M, U 3.1 Total OCDF 0.19 0.012 0.0031

Total furans 0.8587 0.06790.02391 TOTAL CDD/CDF664.21955.9279 12.3649

Measured wt, ng TEQ, ng Measured wt, pg Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEQ Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Congener Run 1 Run 2 Run 3 2,3,7,8 TCDD 0.18 0.0439 0.019 0.18 0.0439 0.019 1.0 2,3,7,8 TCDD 180 43.9 19 2,3,7,8 TCDD M 180 M 43.9< R 19 2,3,7,8 TCDD 0.18 0.0439 0.019 1,2,3,7,8 PeCDD 1.54 0.18 0.0751 1.54 0.18 0.0751 1.0 1,2,3,7,8 PeCDD 1540 180 75.1 1,2,3,7,8 PeCDD M 1540 M 180 M 75.1 1,2,3,7,8 PeCDD 1.54 0.18 0.0751 1,2,3,4,7,8 HxCDD 2.5 0.238 0.0578 0.25 0.02380.00578 0.1 1,2,3,4,7,8 HxCDD 2500 238 57.8 1,2,3,4,7,8 HxCDD 2500 M 238 57.8 1,2,3,4,7,8 HxCDD 2.5 0.238 0.0578 1,2,3,6,7,8 HxCDD 3.3 0.261 0.063 0.33 0.0261 0.0063 0.1 1,2,3,6,7,8 HxCDD 3300 261 63 1,2,3,6,7,8 HxCDD 3300 M 261 63 1,2,3,6,7,8 HxCDD 3.3 0.261 0.063 1,2,3,7,8,9 HxCDD 6.35 0.565 0.188 0.635 0.0565 0.0188 0.1 1,2,3,7,8,9 HxCDD 6350 565 188 1,2,3,7,8,9 HxCDD M 6350 M 565 M 188 1,2,3,7,8,9 HxCDD 6.35 0.565 0.188 1,2,3,4,6,7,8 HpCDD 50.7 4.25 0.949 0.507 0.04250.00949 0.01 1,2,3,4,6,7,8 HpCDD 50700 4250 949 1,2,3,4,6,7,8 HpCDD 50700 4250 M 949 1,2,3,4,6,7,8 HpCDD 50.7 4.25 0.949 Total OCDD 484 39.9 8.38 0.14520.011970.00251 0.0003 Total OCDD 484000 39900 8380 OCDD 484000 39900 8380 Total OCDD 484 39.9 8.38 Total 3.58720.384770.13698 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.043 0.027 0.008 0.0043 0.0027 0.0008 0.1 2,3,7,8 TCDF 43 27 8 2,3,7,8 TCDF < M, R 43< U 27< M, U 8 2,3,7,8 TCDF 0.043 0.027 0.008 1,2,3,7,8 PeCDF 0.029 0.0099 0.0060.00087 0.00030.00018 0.03 1,2,3,7,8 PeCDF 29 9.9 6 1,2,3,7,8 PeCDF 29< U 9.9< U 6 1,2,3,7,8 PeCDF 0.029 0.0099 0.006 2,3,4,7,8 PeCDF 0.092 0.0152 0.0058 0.02760.004560.00174 0.3 2,3,4,7,8 PeCDF 92 15.2 5.8 2,3,4,7,8 PeCDF < M, R 92 M, J 15.2< U 5.8 2,3,4,7,8 PeCDF 0.092 0.0152 0.0058 1,2,3,4,7,8 HxCDF 0.046 0.0077 0.0026 0.00460.000770.00026 0.1 1,2,3,4,7,8 HxCDF 46 7.7 2.6 1,2,3,4,7,8 HxCDF < U 46< M, U 7.7< U 2.6 1,2,3,4,7,8 HxCDF 0.046 0.0077 0.0026 1,2,3,6,7,8 HxCDF 0.042 0.007 0.0024 0.0042 0.00070.00024 0.1 1,2,3,6,7,8 HxCDF 42 7 2.4 1,2,3,6,7,8 HxCDF < U 42< M, U 7< U 2.4 1,2,3,6,7,8 HxCDF 0.042 0.007 0.0024 2,3,4,6,7,8 HxCDF 0.044 0.0074 0.0026 0.00440.000740.00026 0.1 2,3,4,6,7,8 HxCDF 44 7.4 2.6 2,3,4,6,7,8 HxCDF < U 44< U 7.4< U 2.6 2,3,4,6,7,8 HxCDF 0.044 0.0074 0.0026 1,2,3,7,8,9 HxCDF 0.05 0.0084 0.0029 0.0050.000840.00029 0.1 1,2,3,7,8,9 HxCDF 50 8.4 2.9 1,2,3,7,8,9 HxCDF < U 50< U 8.4< U 2.9 1,2,3,7,8,9 HxCDF 0.05 0.0084 0.0029 1,2,3,4,6,7,8 HpCDF 0.0496 0.0085 0.0032 0.0005 8.5E-05 3.2E-05 0.01 1,2,3,4,6,7,8 HpCDF 49.6 8.5 3.2 1,2,3,4,6,7,8 HpCDF M 49.6< U 8.5< M, U 3.2 1,2,3,4,6,7,8 HpCDF 0.0496 0.0085 0.0032 1,2,3,4,7,8,9 HpCDF 0.016 0.011 0.0041 0.000160.00011 4.1E-05 0.01 1,2,3,4,7,8,9 HpCDF 16 11 4.1 1,2,3,4,7,8,9 HpCDF < U 16< U 11< U 4.1 1,2,3,4,7,8,9 HpCDF 0.016 0.011 0.0041 Total OCDF 0.19 0.012 0.0031 5.7E-05 3.6E-06 9.3E-07 0.0003 Total OCDF 190 12 3.1 OCDF M 190< M, U 12< M, U 3.1 Total OCDF 0.19 0.012 0.0031 Total 0.051680.01081 0.00384 **TOTAL CDD/CDF (TEQ)** 3.638880.395580.14083 BDL quantities shown as reported. EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency M Indicates that a peak has been manually integrated. U Indicates that this compound was not detected above the MDL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. J Indicates that a target analyte was detected below the LQL. Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK2EE-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\691588769209794514\[EPA-HQ-OAR-2013-0290-DRAFT-0075.xls]TK2EE-D-F Data** Date: 12/1/14

Plant name: Kohler Co. Location: Spartanburg, SC Test date: 8/10-8/11/10 Equipment: Tunnel Kiln 2

FE Stack Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 19.8 151.9 1,084 46.8 4.76E-09 10.9 1332.00E-05 1573.9 1.27E-08

2 19.8 148.3 1,033 73.7 7.67E-09 17.5 2123.08E-05 1573.9 1.96E-08 3 19.6 147.0 1,022 38.1 4.00E-09 9.16 101 1.59E-05 1632.9 9.74E-09 Average 19.7 1,046 5.47E-09 12.5 1492.22E-051593.567 1.40E-08 TEQ 1 M23 19.8 151.9 1,084 0.437 4.44E-11 0.1016 1.2391.87E-07 1573.9 1.19E-10

2 19.8 148.3 1,033 0.551 5.73E-11 0.1312 1.592.30E-07 1573.9 1.46E-10 3 19.6 147.0 1,022 0.390 4.10E-11 0.0937 1.0341.63E-07 1632.9 9.97E-11 Average 19.7 1,046 4.76E-11 0.1088 1.2861.93E-071593.567 1.21E-10 Notes:

TK2FE-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Tunnel Kiln 2 FE Stack** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.618 0.679 0.579 Total TCDD 618 679 579 Total TCDD 618 679 579 Total PeCDD 2.19 2.06 1.69 Total PeCDD 2190 2060 1690 Total PeCDD 2190 2060 1690 Total HxCDD 5 5.99 4.33 Total HxCDD 5000 5990 4330 Total HxCDD 5000 5990 4330 Total HpCDD 7.25 10.8 6.05 Total HpCDD 7250 10800 6050 Total HpCDD 7250 10800 6050 Total OCDD 31.7 54 25.3 Total OCDD 31700 54000 25300 Total OCDD 31700 54000 25300

Total dioxins 46.758 73.529 37.949 Total TCDF 0.021 0.019 0.099 Total TCDF 21 19 99 Total TCDF < 21< 19< 99 Total PeCDF 0.0253 0.0812 0.0541 Total PeCDF 25.3 81.2 54.1 Total PeCDF 25.3 81.2 54.1 Total HxCDF 0.00348 0.02 0.014 Total HxCDF 3.48 20 14 Total HxCDF 3.48< 20< 14 Total HpCDF 0.006 0.0032 0.0071 Total HpCDF 6 3.2 7.1 Total HpCDF < 6< 3.2< 7.1 Total OCDF 0.0086 0 0 Total OCDF 8.6 21.7 7.8 Total OCDF < U 8.6 J 21.7< U 7.8

Total furans 0.06438 0.1234 0.1742 TOTAL CDD/CDF46.8224 73.6524 38.1232

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEQ Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.0552 0.048 0.0415 0.0552 0.048 0.0415 1.0 2,3,7,8 TCDD 55.2 48 41.5 2,3,7,8 TCDD M 55.2< M, R 48 M 41.5 1,2,3,7,8 PeCDD 0.226 0.27 0.197 0.226 0.27 0.197 1.0 1,2,3,7,8 PeCDD 226 270 197 1,2,3,7,8 PeCDD M 226 M 270 M 197 1,2,3,4,7,8 HxCDD 0.199 0.246 0.194 0.0199 0.0246 0.0194 0.1 1,2,3,4,7,8 HxCDD 199 246 194 1,2,3,4,7,8 HxCDD 199 M 246 194 1,2,3,6,7,8 HxCDD 0.262 0.378 0.246 0.0262 0.0378 0.0246 0.1 1,2,3,6,7,8 HxCDD 262 378 246 1,2,3,6,7,8 HxCDD 262 M 378 246 1,2,3,7,8,9 HxCDD 0.574 0.874 0.506 0.0574 0.0874 0.0506 0.1 1,2,3,7,8,9 HxCDD 574 874 506 1,2,3,7,8,9 HxCDD M 574 M 874 M 506 1,2,3,4,6,7,8 HpCDD 3.59 5.48 3.07 0.0359 0.0548 0.0307 0.01 1,2,3,4,6,7,8 HpCDD 3590 5480 3070 1,2,3,4,6,7,8 HpCDD 3590 5480 3070 Total OCDD 31.7 54 25.3 0.00951 0.0162 0.00759 0.0003 Total OCDD 31700 54000 25300 OCDD 31700 54000 25300 Total 0.43011 0.5388 0.37139 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.021 0.019 0.099 0.0021 0.0019 0.0099 0.1 2,3,7,8 TCDF 21 19 99 2,3,7,8 TCDF < M, U 21< U 19< U 99 1,2,3,7,8 PeCDF 0.0055 0.0086 0.011 0.00017 0.00026 0.00033 0.03 1,2,3,7,8 PeCDF 5.5 8.6 11 1,2,3,7,8 PeCDF < U 5.5< U 8.6< U 11 2,3,4,7,8 PeCDF 0.012 0.0083 0.011 0.0036 0.00249 0.0033 0.3 2,3,4,7,8 PeCDF 12 8.3 11 2,3,4,7,8 PeCDF < J, R 12< U 8.3< U 11 1,2,3,4,7,8 HxCDF 0.003 0.018 0.013 0.0003 0.0018 0.0013 0.1 1,2,3,4,7,8 HxCDF 3 18 13 1,2,3,4,7,8 HxCDF < U 3< U 18< U 13 1,2,3,6,7,8 HxCDF 0.0028 0.017 0.012 0.00028 0.0017 0.0012 0.1 1,2,3,6,7,8 HxCDF 2.8 17 12 1,2,3,6,7,8 HxCDF < U 2.8< U 17< U 12 2,3,4,6,7,8 HxCDF 0.0029 0.018 0.012 0.00029 0.0018 0.0012 0.1 2,3,4,6,7,8 HxCDF 2.9 18 12 2,3,4,6,7,8 HxCDF < U 2.9< U 18< U 12 1,2,3,7,8,9 HxCDF 0.0033 0.02 0.014 0.00033 0.002 0.0014 0.1 1,2,3,7,8,9 HxCDF 3.3 20 14 1,2,3,7,8,9 HxCDF < U 3.3< U 20< U 14 1,2,3,4,6,7,8 HpCDF 0.0047 0.0047 0.0056 4.7E-05 4.7E-05 5.6E-05 0.01 1,2,3,4,6,7,8 HpCDF 4.7 4.7 5.6 1,2,3,4,6,7,8 HpCDF < U 4.7< J, R 4.7< U 5.6 1,2,3,4,7,8,9 HpCDF 0.006 0.0032 0.0071 0.00006 3.2E-05 7.1E-05 0.01 1,2,3,4,7,8,9 HpCDF 6 3.2 7.1 1,2,3,4,7,8,9 HpCDF < U 6< U 3.2< U 7.1 Total OCDF 0.0086 0.0217 0.0078 2.6E-06 6.5E-06 2.3E-06 0.0003 Total OCDF 8.6 21.7 7.8 OCDF < U 8.6 J 21.7< U 7.8 Total 0.00717 0.01203 0.01876 **TOTAL CDD/CDF (TEQ)** 0.43728 0.55083 0.39015 BDL quantities shown as reported. EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency M Indicates that a peak has been manually integrated. U Indicates that this compound was not detected above the MDL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. J Indicates that a target analyte was detected below the LQL. Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK2FE-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\691588769209794514\[EPA-HQ-OAR-2013-0290-DRAFT-0075.xls]TK2EE-D-F Data** Date: 12/1/14

Plant name: Kohler Co. Location: Spartanburg, SC Test date: 8/12-8/13/10 Equipment: Tunnel Kiln 8

POC Stack Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 18.0 175.3 12,956 78.0 6.87E-09 15.715 74.33.46E-04 3693.2 9.37E-08

2 17.9 171.9 12,674 84.6 7.59E-09 17.370 80.23.74E-04 3693.2 1.01E-07 3 17.9 169.4 12,871 86.1 7.84E-09 17.944 84.03.92E-04 3695 1.06E-07 Average 17.9 12,834 7.43E-09 17.010 79.53.71E-04 3693.8 1.00E-07 TEQ 1 M23 18.0 175.3 12,956 0.867 7.64E-11 0.174702 0.82603.85E-06 3693.2 1.04E-09

2 17.9 171.9 12,674 0.963 8.64E-11 0.197795 0.91344.26E-06 3693.2 1.15E-09 3 17.9 169.4 12,871 0.963 8.77E-11 0.20072 0.9394.39E-06 3695 1.19E-09 Average 17.9 12,834 8.35E-11 0.19107 0.8934.17E-06 3693.8 1.13E-09 Notes:

TK8POC-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Tunnel Kiln POC Stack** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 1.1 1.27 1.69 Total TCDD 1100 1270 1690 Total TCDD 1100 1270 1690 Total PeCDD 4.72 6.09 4.64 Total PeCDD 4720 6090 4640 Total PeCDD 4720 6090 4640 Total HxCDD 10 13.5 15.3 Total HxCDD 10000 13500 15300 Total HxCDD 10000 13500 15300 Total HpCDD 18 18.3 18.4 Total HpCDD 18000 18300 18400 Total HpCDD 18000 18300 18400 Total OCDD 44 45.3 46 Total OCDD 44000 45300 46000 Total OCDD 44000 45300 46000

Total dioxins 77.82 84.46 86.03 Total TCDF 0.119 0.0511 0.0099 Total TCDF 119 51.1 9.9 Total TCDF 119 51.1< 9.9 Total PeCDF 0.0153 0.0084 0.01 Total PeCDF 15.3 8.4 10 Total PeCDF 15.3< 8.4< 10 Total HxCDF 0.013 0.0044 0.0131 Total HxCDF 13 4.4 13.1 Total HxCDF < 13< 4.4 13.1 Total HpCDF 0.0174 0.012 0.02 Total HpCDF 17.4 12 20 Total HpCDF 17.4< 12< 20 Total OCDF 0.021 0.017 0.022 Total OCDF 21 17 22 Total OCDF < M, J, R 21< U 17< U 22

Total furans 0.1857 0.0929 0.075 TOTAL CDD/CDF 78.0057 84.5529 86.105

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEQ Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.121 0.12 0.112 0.121 0.12 0.112 1.0 2,3,7,8 TCDD 121 120 112 2,3,7,8 TCDD 121< R 120 M 112 1,2,3,7,8 PeCDD 0.494 0.539 0.507 0.494 0.539 0.507 1.0 1,2,3,7,8 PeCDD 494 539 507 1,2,3,7,8 PeCDD M 494 M 539 M 507 1,2,3,4,7,8 HxCDD 0.35 0.438 0.422 0.035 0.0438 0.0422 0.1 1,2,3,4,7,8 HxCDD 350 438 422 1,2,3,4,7,8 HxCDD < M, R 350 M 438 M 422 1,2,3,6,7,8 HxCDD 0.35 0.483 0.566 0.035 0.0483 0.0566 0.1 1,2,3,6,7,8 HxCDD 350 483 566 1,2,3,6,7,8 HxCDD < M, R 350 M 483 M 566 1,2,3,7,8,9 HxCDD 0.933 1.2 1.55 0.0933 0.12 0.155 0.1 1,2,3,7,8,9 HxCDD 933 1200 1550 1,2,3,7,8,9 HxCDD M 933 M 1200 M 1550 1,2,3,4,6,7,8 HpCDD 6.65 7.26 7.07 0.0665 0.0726 0.0707 0.01 1,2,3,4,6,7,8 HpCDD 6650 7260 7070 1,2,3,4,6,7,8 HpCDD 6650 7260 7070 OCDD 44 45.3 46 0.0132 0.01359 0.0138 0.0003 OCDD 44000 45300 46000 OCDD 44000 45300 46000 Total 0.858 0.95729 0.9573 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0091 0.01 0.0099 0.00091 0.001 0.00099 0.1 2,3,7,8 TCDF 9.1 10 9.9 2,3,7,8 TCDF < U 9.1< U 10< U 9.9 1,2,3,7,8 PeCDF 0.0141 0.0095 0.01 0.00042 0.00029 0.0003 0.03 1,2,3,7,8 PeCDF 14.1 9.5 10 1,2,3,7,8 PeCDF J 14.1< M, J, R 9.5< U 10 2,3,4,7,8 PeCDF 0.0096 0.0081 0.0097 0.00288 0.00243 0.00291 0.3 2,3,4,7,8 PeCDF 9.6 8.1 9.7 2,3,4,7,8 PeCDF < U 9.6< U 8.1< U 9.7 1,2,3,4,7,8 HxCDF 0.012 0.004 0.0032 0.0012 0.0004 0.00032 0.1 1,2,3,4,7,8 HxCDF 12 4 3.2 1,2,3,4,7,8 HxCDF < U 12< U 4< U 3.2 1,2,3,6,7,8 HxCDF 0.011 0.0037 0.0029 0.0011 0.00037 0.00029 0.1 1,2,3,6,7,8 HxCDF 11 3.7 2.9 1,2,3,6,7,8 HxCDF < U 11< U 3.7< U 2.9 2,3,4,6,7,8 HxCDF 0.011 0.0039 0.0031 0.0011 0.00039 0.00031 0.1 2,3,4,6,7,8 HxCDF 11 3.9 3.1 2,3,4,6,7,8 HxCDF < U 11< U 3.9< U 3.1 1,2,3,7,8,9 HxCDF 0.013 0.0044 0.0035 0.0013 0.00044 0.00035 0.1 1,2,3,7,8,9 HxCDF 13 4.4 3.5 1,2,3,7,8,9 HxCDF < U 13< U 4.4< U 3.5 1,2,3,4,6,7,8 HpCDF 0.0174 0.0098 0.016 0.00017 9.8E-05 0.00016 0.01 1,2,3,4,6,7,8 HpCDF 17.4 9.8 16 1,2,3,4,6,7,8 HpCDF J 17.4< U 9.8< U 16 1,2,3,4,7,8,9 HpCDF 0.011 0.012 0.02 0.00011 0.00012 0.0002 0.01 1,2,3,4,7,8,9 HpCDF 11 12 20 1,2,3,4,7,8,9 HpCDF < U 11< U 12< U 20 OCDF 0.021 0.017 0.022 6.3E-06 5.1E-06 6.6E-06 0.0003 OCDF 21 17 22 OCDF < M, J, R 21< U 17< U 22 Total 0.0092 0.00554 0.00584 **TOTAL CDD/CDF (TEQ)** 0.8672 0.96283 0.96314 BDL quantities shown as reported. EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency M Indicates that a peak has been manually integrated. U Indicates that this compound was not detected above the MDL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. J Indicates that a target analyte was detected below the LQL. Measured wt, pg Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK8POC-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\691588769209794514\[EPA-HQ-OAR-2013-0290-DRAFT-0075.xls]TK2EE-D-F Data** Date: 12/1/14

Plant name: Kohler Co. Location: Spartanburg, SC Test date: 8/12-8/13/10 Equipment: Tunnel Kiln 10

POC Stack Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 19.2 128.6 6,860 10.7 1.28E-09 2.940 24.33.43E-05 823.8 4.16E-08

2 19.1 127.1 6,669 8.73 1.06E-09 2.426 18.42.75E-05 823.8 3.34E-08 3 19.0 126.0 6,653 7.44 9.12E-10 2.086 14.92.36E-05 799 2.95E-08 Average 19.1 6,727 1.09E-09 2.484 19.22.84E-05815.5333 3.49E-08 TEQ 1 M23 19.2 128.6 6,860 0.1132 1.36E-11 0.031090 0.25723.62E-07 823.8 4.40E-10

2 19.1 127.1 6,669 0.0877 1.06E-11 0.024358 0.18502.76E-07 823.8 3.35E-10 3 19.0 126.0 6,653 0.0892 1.09E-11 0.02501 0.1792.83E-07 799 3.54E-10 Average 19.1 6,727 1.17E-11 0.02682 0.2073.07E-07815.5333 3.76E-10 Notes:

TK10POC-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Tunnel Kiln 10 POC Stack** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.114 0.117 0.0765 Total TCDD 114 117 76.5 Total TCDD 114 117 76.5 Total PeCDD 0.294 0.312 0.323 Total PeCDD 294 312 323 Total PeCDD 294 312 323 Total HxCDD 0.964 0.819 0.86 Total HxCDD 964 819 860 Total HxCDD 964 819 860 Total HpCDD 1.82 1.45 1.21 Total HpCDD 1820 1450 1210 Total HpCDD 1820 1450 1210 Total OCDD 7.49 6.02 4.96 Total OCDD 7490 6020 4960 Total OCDD 7490 6020 4960

Total dioxins 10.682 8.718 7.4295 Total TCDF 0.011 0.0065 0.0062 Total TCDF 11 6.5 6.2 Total TCDF < 11< 6.5< 6.2 Total PeCDF 0.0042 0.002 0.0017 Total PeCDF 4.2 2 1.7 Total PeCDF < 4.2< 2< 1.7 Total HxCDF 0.0039 0.0024 0.00213 Total HxCDF 3.9 2.4 2.13 Total HxCDF < 3.9< 2.4 2.13 Total HpCDF 0.0029 0.003 0.0013 Total HpCDF 2.9 3 1.3 Total HpCDF < 2.9< 3< 1.3 Total OCDF 0.0018 0.0023 0.0014 Total OCDF 1.8 2.3 1.4 Total OCDF < M, J, R 1.8< U 2.3< M, J, R 1.4

Total furans 0.0238 0.0162 0.01273 TOTAL CDD/CDF 10.7058 8.7342 7.44223

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEQ Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.016 0.0027 0.015 0.016 0.0027 0.015 1.0 2,3,7,8 TCDD 16 2.7 15 2,3,7,8 TCDD < M, R 16< M, U 2.7< R 15 1,2,3,7,8 PeCDD 0.0595 0.0531 0.0473 0.0595 0.0531 0.0473 1.0 1,2,3,7,8 PeCDD 59.5 53.1 47.3 1,2,3,7,8 PeCDD M 59.5 M, U 53.1 M 47.3 1,2,3,4,7,8 HxCDD 0.0436 0.042 0.0315 0.00436 0.0042 0.00315 0.1 1,2,3,4,7,8 HxCDD 43.6 42 31.5 1,2,3,4,7,8 HxCDD M 43.6< M, R 42 31.5 1,2,3,6,7,8 HxCDD 0.049 0.042 0.0501 0.0049 0.0042 0.00501 0.1 1,2,3,6,7,8 HxCDD 49 42 50.1 1,2,3,6,7,8 HxCDD < M, R 49< M, R 42 50.1 1,2,3,7,8,9 HxCDD 0.138 0.128 0.0954 0.0138 0.0128 0.00954 0.1 1,2,3,7,8,9 HxCDD 138 128 95.4 1,2,3,7,8,9 HxCDD M 138 M 128 M 95.4 1,2,3,4,6,7,8 HpCDD 0.85 0.666 0.6 0.0085 0.00666 0.006 0.01 1,2,3,4,6,7,8 HpCDD 850 666 600 1,2,3,4,6,7,8 HpCDD M 850 M 666 600 OCDD 7.49 6.02 4.96 0.00225 0.00181 0.00149 0.0003 OCDD 7490 6020 4960 OCDD 7490 6020 4960 Total 0.10931 0.08547 0.08749 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.011 0.0065 0.0062 0.0011 0.00065 0.00062 0.1 2,3,7,8 TCDF 11 6.5 6.2 2,3,7,8 TCDF < U 11< U 6.5< U 6.2 1,2,3,7,8 PeCDF 0.0042 0.002 0.0017 0.00013 0.00006 5.1E-05 0.03 1,2,3,7,8 PeCDF 4.2 2 1.7 1,2,3,7,8 PeCDF < U 4.2< U 2< U 1.7 2,3,4,7,8 PeCDF 0.0041 0.002 0.0021 0.00123 0.0006 0.00063 0.3 2,3,4,7,8 PeCDF 4.1 2 2.1 2,3,4,7,8 PeCDF < U 4.1< J, R 2< M, J, R 2.1 1,2,3,4,7,8 HxCDF 0.0035 0.0022 0.0008 0.00035 0.00022 0.00008 0.1 1,2,3,4,7,8 HxCDF 3.5 2.2 0.8 1,2,3,4,7,8 HxCDF < U 3.5< U 2.2< U 0.8 1,2,3,6,7,8 HxCDF 0.0032 0.002 0.00158 0.00032 0.0002 0.00016 0.1 1,2,3,6,7,8 HxCDF 3.2 2 1.58 1,2,3,6,7,8 HxCDF < U 3.2< U 2 J 1.58 2,3,4,6,7,8 HxCDF 0.0034 0.0021 0.00077 0.00034 0.00021 7.7E-05 0.1 2,3,4,6,7,8 HxCDF 3.4 2.1 0.77 2,3,4,6,7,8 HxCDF < U 3.4< U 2.1< U 0.77 1,2,3,7,8,9 HxCDF 0.0039 0.0024 0.00087 0.00039 0.00024 8.7E-05 0.1 1,2,3,7,8,9 HxCDF 3.9 2.4 0.87 1,2,3,7,8,9 HxCDF < U 3.9< U 2.4< U 0.87 1,2,3,4,6,7,8 HpCDF 0.0022 0.0023 0.002 2.2E-05 2.3E-05 0.00002 0.01 1,2,3,4,6,7,8 HpCDF 2.2 2.3 2 1,2,3,4,6,7,8 HpCDF < U 2.2< U 2.3< M, J, R 2 1,2,3,4,7,8,9 HpCDF 0.0029 0.003 0.0013 2.9E-05 0.00003 1.3E-05 0.01 1,2,3,4,7,8,9 HpCDF 2.9 3 1.3 1,2,3,4,7,8,9 HpCDF < U 2.9< U 3< U 1.3 OCDF 0.0018 0.0023 0.0014 5.4E-07 6.9E-07 4.2E-07 0.0003 OCDF 1.8 2.3 1.4 OCDF < M, J, R 1.8< U 2.3< M, J, R 1.4 Total 0.00391 0.00223 0.00174 **TOTAL CDD/CDF (TEQ)** 0.11321 0.0877 0.08922 BDL quantities shown as reported. EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency M Indicates that a peak has been manually integrated. U Indicates that this compound was not detected above the MDL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. J Indicates that a target analyte was detected below the LQL. Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK10POC-D-F Data 12/1/2014

# Filename: **C:\PROGRA~2\Documentum\CTS\docbases\ProDocbase\config\temp_sessions\691588769209794514\[EPA-HQ-OAR-2013-0290-DRAFT-0075.xls]TK2EE-D-F Data** Date: 12/1/14

Plant name: Kohler Co. Location: Spartanburg, SC Test date: 8/12-8/13/10 Equipment: Tunnel Kiln 10

RCE Stack Control device: None Gas Volum. Emission Process Run Test O2

# conc.,volume, flow rate, Mass, Concentration, rate, rate, Emission factor, Pollutant No. Method % DSCF DSCFM ng BDL MW gr/dscf ng/dscm @7%O2 

# g/hr ton/hr g/ton g/lb CDD/CDF 1 M23 20.0 139.0 5,455 0.693 7.70E-11 0.176 2.721.63E-06 823.8 1.98E-09

2 20.0 144.1 5,651 0.276 2.96E-11 0.0677 1.086.50E-07 823.8 7.89E-10 3 20.0 149.0 5,818 0.160 1.66E-11 0.03794 0.61323.75E-07 799 4.69E-10 Average 20.0 5,641 4.10E-11 0.0939 1.478.86E-07815.5333 1.09E-09 TEQ 1 M23 20.0 139.0 5,455 0.00756 8.39E-13 0.001920 0.029661.78E-08 823.8 2.16E-11

2 20.0 144.1 5,651 0.008623 9.23E-13 0.002113 0.033752.03E-08 823.8 2.46E-11 3 20.0 149.0 5,818 0.005118 5.30E-13 0.001213 0.0196101.20E-08 799 1.50E-11 Average 20.0 5,641 7.64E-13 0.001749 0.02767 1.67E-08815.5333 2.05E-11 Notes:

TK10RCE-Emission Calcs 1 of 1 12/1/2014DIOXIN-FURAN PARTICLE CATCH **Tunnel Kiln 10 RCE Stack** Measured wt, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 Total TCDD 0.0017 0.0028 0.00185 Total TCDD 1.7 2.8 1.85 Total TCDD < 1.7< 2.8 1.85 Total PeCDD 0.00271 0.0021 0.0025 Total PeCDD 2.71 2.1 2.5 Total PeCDD 2.71< 2.1< 2.5 Total HxCDD 0.00246 0.0022 0.0015 Total HxCDD 2.46 2.2 1.5 Total HxCDD 2.46< 2.2< 1.5 Total HpCDD 0.126 0.0468 0.0183 Total HpCDD 126 46.8 18.3 Total HpCDD 126 46.8 18.3 Total OCDD 0.548 0.209 0.13 Total OCDD 548 209 130 Total OCDD 548 209< R 130

Total dioxins 0.68087 0.2629 0.15415 Total TCDF 0.0041 0.0028 0.0021 Total TCDF 4.1 2.8 2.1 Total TCDF < 4.1< 2.8 2.1 Total PeCDF 0.0012 0.0035 0.0013 Total PeCDF 1.2 3.5 1.3 Total PeCDF < 1.2< 3.5< 1.3 Total HxCDF 0.0043 0.0038 0.00067 Total HxCDF 4.3 3.8 0.67 Total HxCDF < 4.3< 3.8< 0.67 Total HpCDF 0.0013 0.0011 0.00096 Total HpCDF 1.3 1.1 0.96 Total HpCDF < 1.3< 1.1< 0.96 Total OCDF 0.0016 0.0022 0.00088 Total OCDF 1.6 2.2 0.88 Total OCDF < U 1.6< U 2.2< U 0.88

Total furans 0.0125 0.0134 0.00591 TOTAL CDD/CDF 0.69337 0.2763 0.16006

Measured wt, ng TEQ, ng Measured wt, pg Congener Run 1 Run 2 Run 3 Run 1 Run 2 Run 3 TEQ Congener Run 1 Run 2 Run 3 Congener Flag Run 1 Flag Run 2 Flag Run 3 2,3,7,8 TCDD 0.0017 0.0028 0.0012 0.0017 0.0028 0.0012 1.0 2,3,7,8 TCDD 1.7 2.8 1.2 2,3,7,8 TCDD < U 1.7< U 2.8< U 1.2 1,2,3,7,8 PeCDD 0.0015 0.0021 0.0025 0.0015 0.0021 0.0025 1.0 1,2,3,7,8 PeCDD 1.5 2.1 2.5 1,2,3,7,8 PeCDD < M, U 1.5< U 2.1< U 2.5 1,2,3,4,7,8 HxCDD 0.0022 0.002 0.0014 0.00022 0.0002 0.00014 0.1 1,2,3,4,7,8 HxCDD 2.2 2 1.4 1,2,3,4,7,8 HxCDD < M, J, R 2.2< U 2< M, U 1.4 1,2,3,6,7,8 HxCDD 0.00246 0.0022 0.0015 0.00025 0.00022 0.00015 0.1 1,2,3,6,7,8 HxCDD 2.46 2.2 1.5 1,2,3,6,7,8 HxCDD M, J 2.46< U 2.2< M, U 1.5 1,2,3,7,8,9 HxCDD 0.0073 0.002 0.0016 0.00073 0.0002 0.00016 0.1 1,2,3,7,8,9 HxCDD 7.3 2 1.6 1,2,3,7,8,9 HxCDD < M, J, R 7.3< U 2< M, J, R 1.6 1,2,3,4,6,7,8 HpCDD 0.0611 0.0225 0.013 0.00061 0.00023 0.00013 0.01 1,2,3,4,6,7,8 HpCDD 61.1 22.5 13 1,2,3,4,6,7,8 HpCDD M 61.1 M 22.5< M, J, R 13 OCDD 0.548 0.209 0.13 0.00016 6.3E-05 3.9E-05 0.0003 OCDD 548 209 130 OCDD 548 209< R 130 Total 0.00517 0.00581 0.00432 Measured wt, ng TEQ, ng 2,3,7,8 TCDF 0.0041 0.0028 0.0011 0.00041 0.00028 0.00011 0.1 2,3,7,8 TCDF 4.1 2.8 1.1 2,3,7,8 TCDF < U 4.1< U 2.8< M, U 1.1 1,2,3,7,8 PeCDF 0.0012 0.0035 0.0013 3.6E-05 0.00011 3.9E-05 0.03 1,2,3,7,8 PeCDF 1.2 3.5 1.3 1,2,3,7,8 PeCDF < U 1.2< U 3.5< U 1.3 2,3,4,7,8 PeCDF 0.0012 0.0034 0.0013 0.00036 0.00102 0.00039 0.3 2,3,4,7,8 PeCDF 1.2 3.4 1.3 2,3,4,7,8 PeCDF < M, U 1.2< U 3.4< U 1.3 1,2,3,4,7,8 HxCDF 0.0039 0.0035 0.00061 0.00039 0.00035 6.1E-05 0.1 1,2,3,4,7,8 HxCDF 3.9 3.5 0.61 1,2,3,4,7,8 HxCDF < U 3.9< U 3.5< U 0.61 1,2,3,6,7,8 HxCDF 0.0036 0.0032 0.00056 0.00036 0.00032 5.6E-05 0.1 1,2,3,6,7,8 HxCDF 3.6 3.2 0.56 1,2,3,6,7,8 HxCDF < U 3.6< U 3.2< U 0.56 2,3,4,6,7,8 HxCDF 0.0038 0.0034 0.00059 0.00038 0.00034 5.9E-05 0.1 2,3,4,6,7,8 HxCDF 3.8 3.4 0.59 2,3,4,6,7,8 HxCDF < U 3.8< U 3.4< U 0.59 1,2,3,7,8,9 HxCDF 0.0043 0.0038 0.00067 0.00043 0.00038 6.7E-05 0.1 1,2,3,7,8,9 HxCDF 4.3 3.8 0.67 1,2,3,7,8,9 HxCDF < U 4.3< U 3.8< U 0.67 1,2,3,4,6,7,8 HpCDF 0.00098 0.0009 0.00075 9.8E-06 9E-06 7.5E-06 0.01 1,2,3,4,6,7,8 HpCDF 0.98 0.9 0.75 1,2,3,4,6,7,8 HpCDF < U 0.98< M, U 0.9< U 0.75 1,2,3,4,7,8,9 HpCDF 0.0013 0.0011 0.00096 1.3E-05 1.1E-05 9.6E-06 0.01 1,2,3,4,7,8,9 HpCDF 1.3 1.1 0.96 1,2,3,4,7,8,9 HpCDF < M, U 1.3< U 1.1< U 0.96 OCDF 0.0016 0.0022 0.00088 4.8E-07 6.6E-07 2.6E-07 0.0003 OCDF 1.6 2.2 0.88 OCDF < U 1.6< U 2.2< U 0.88 Total 0.00239 0.00282 0.0008 **TOTAL CDD/CDF (TEQ)** 0.00756 0.00862 0.00512 BDL quantities shown as reported. EDL Indicates the Estimated Detection Limit, based on the measured background noise for this target in this sample. TEF Indicates the Toxic Equivalency Factor TEQ Indicates the Toxic Equivalency M Indicates that a peak has been manually integrated. U Indicates that this compound was not detected above the MDL R Indicates that the ion abundance ratio for this compound did not meet the acceptance criterion. J Indicates that a target analyte was detected below the LQL. Measured wt, pg

Measured wt, pg

EPA-HQ-OAR-2013-0290-DRAFT-0075 TK10RCE-D-F Data 12/1/2014