# Effluent Quality Assessment


# Progress Energy Florida Crystal River Plant Units 1, 2

and 3

Citrus County

NPDES #FL0000159

Sampled August 10, 2009

January 2010

Biology Section

Bureau of Laboratories

Division of Environmental Assessment and Restoration

Quality Manual No. 870346G

NELAC Certification No. E31780

# 1 CONTENTS

Introduction

Methods

Results and Discussion

Literature Cited

Tables
Table 1 Measured algal growth potential (AGP)

Table 2 Effluent limits, Class III Marine Criteria and chemical data

Appendices
Appendix A Chain of Custody
Appendix B Bioassay Bench Sheets
Appendix C SRT Bench Sheet s and Statistical Analyses
Appendix D Organism Receipt
Appendix E Chemical Analyses of Effluent
Appendix F Facility Summary, Effl uent Limits, and Permit Violations
Recorded on Discharge Monitoring Report
Appendix G EPA End Sheet

# 2 Progress Energy Florida Crystal River Plant Unit s 1, 2 and 3, 15760 West Powerline St., Crystal River, Citrus County, Florida, 34428. NPD ES #FL0000159. Effluent grab samples for bioassay and chemical analyses for this facility were collected on August 10, 2009.



# Introduction
Progress Energy Florida Crystal River Plant Unit s 1, 2 and 3 is an electric power generating plant consisting of two fossil fuel units (Units 1 and 2) a nd a nuclear fuel unit (unit 3). The facility has an industrial wastewater treatment and disposal sy stem which treats cooling water and runoff water. (See Appendix F for detailed facility informati on provided by Jason Co hen of FDEP Southwest District)



# Methods
Samples were collected from the EFF-1C, E FF-7 and EFF-10B NPDES sampling points, respectively, for Outfalls D-013, D-00F and D- 072 and from screen wash-water Outfalls D-092 and D-094 by Jason Cohen, Peter Wenner and Chris Anastasiou (FDEP Southwest District) following DEP-SOP-001/01 FS 2400 Wastewater Sampling. All DEP SOPs are available on the

web at: http://www.floridadep.org/labs/qa/sops.htm

.

See Appendix A for the completed chain of custody form.

The 48-hour acute screening toxicity tests and t he algal growth potential test were performed following internal DEP SOPs TA07_03, TA07_04, and TA08_01 through TA08_09. All internal

DEP SOPs are available on the web at: http://www.floridadep.org/labs/cgi-bin/sop/biosop.asp

.



# Results and Discussion
Toxicity Test Results Tests were performed August 11 - 13, 2009.

Americamysis bahia 48-hour acute screening bioassay – LC 50 

## > 100%, 0%* mortality in 100% sample at 48 hours

Menidia beryllina 48-hour acute screening bioassay – LC 50 

## > 100%, 5%* mortality in 100% sample at 48 hours

The bioassay samples were not acutely toxic to the test organisms.

*NOTE: In a 48-hour acute screening test of 100% effluent, mortality of <20% provides

confidence that the effluent meets the acute to xicity criterion of Florida’s Surface Water Quality Standards (Rule 62-302.500 (1) (a) 4, F.A.C.). Mortality between 20-50% indicates low to moderate levels of toxicity , and further action may be required. Mortality

of >50% indicates that the effluent fails to meet the minimum requirement to discharge to waters of the state (Rule 62-4.244(3) (a), F.A.C.).

See Appendix B for bioassay bench sheets. See Appendix C for results of the last 20 standard reference toxicant (SRT) tests and t he bench sheets and statistical analyses of the SRT tests that correspond to these facilit y tests. See Appendix D for test organism receipts.

Algal Growth Potential The Algal Growth Potential (AGP) in the e ffluent samples from Outfalls D-00F, D-013, and D-072 and in the lab duplicate of D-072 wa s 3.0 U (U - Material was analyzed for but

# 3 not detected; the value reported is the mi nimum detection limit) mg dry wt/L of the saltwater species, Dunaliella tertiolecta. Raschke and Schultz found that AGP values above 10.0 mg dry weight/L represent a “problem” threshold for marine receiving waters, implying nutrient enrichment (personal communi cation, Marshall Faircloth, et. al. FDEP, with Ron Raschke USEPA Region 4 1987). The ratios of total nitrogen to totalphosphorus suggest that the effluent from Outfalls D-00F and Outfall D-013 is nitrogenlimited and that the effluent from Outfall D-072 is co-limited by both nitrogen and phosphorus (Maloney et al. 1978).

See Table 1 for AGP results.

Chemistry Results Total residual chlorine and total ammonia were not detected in the bioassay sample in the laboratory. The total ammonia concentration in the samples collected and preserved for chemical analysis from Outfalls D-013, D-00F and D-072 were, respectively, 0.01 U (U - Material was analyzed for but not detected; the value reported is the minimum det ection limit) mg N/L, 0.011 I (I -The reported value is between the laborator y method detection limit (MDL) and the laboratory practical quantitation limit (PQL ) mg N/L, and 0.028 mg N/L. Based on the pH, salinity, and temperature of the effluents as collected, the calculated unionized ammonia concentration in each of the samples was < 0.02 mg N/L.

OUTFALL D-013 Aluminum, total alpha particles, and radium 226 +228 were detected in the effluent at levels that comply with Class III marine wa ter quality criteria (62-302.530, F.A.C.). Arsenic, chromium, lead and zinc were detected between the laboratory MDL and PQL. Iron (1190 mg/L; limit ≤ 300 μg/L, 62-302.500 (38), F.AC.), and effluent turbidity (36 NTU;

limit ≤ 29 NTU, 62-302.500 (69), F.AC.) exceeded t he Class III criteria for marine water. Zinc and nitrate + nitrite were detected in the equipment blank.

OUTFALL D-00F Aluminum, copper, total alpha particles, and radium 226 +228 were detected in the effluent at levels that comply with Clas s III marine water quality criteria (62-302.530, F.A.C.). Arsenic, chromium, lead and zinc were detected between the laboratory MDL and PQL. Iron (970 mg/L; limit ≤ 300 μg/L, 62-302.500 (38), F.AC.) and effluent turbidity (34 NTU; limit ≤ 29 NTU, 62-302.500 (69) , F.AC.) exceeded the Class III criteria for

marine water.

OUTFALL D-072 Aluminum, arsenic, chromium, iron and zinc were detected in the effluent between the laboratory MDL and PQL. Iron (320 mg/L; limit ≤ 300 μg/L, 62-302.500 (38), F.AC.)

exceeded the Class III criter ia for marine water.

See Table 2 for results of analytes detected in the effluent, and corresponding limits. See Appendix E for a complete list of chemical analyses performed.



# Conclusion
The effluent sample collected from the EFF-7 NPDES sampling point for Outfall D-00F for this facility on August 10, 2009, was not acutely toxic to either test species during the 48-hour acute screening bioassays. The AGP results from each of the three effluent samples were less than the "problem” threshold for marine receiving waters. Effluent water quality samples collected on August 10, 2009, exceeded applicable water quality standards for iron in Outfalls D-013, D-00F and D-072 and effluent turbidity in Outfalls D-013 and D-00F.

# 4 Literature Cited
Maloney, T. E., W. E. Miller, and D. T. Spec ht. 1974. The Marine Algal Assay Procedure:

Bottle Test. National Environmental Resear ch Center Office of Research and Development. U. S. EPA, Corvallis, Oregon. 43 p.

# 5 Inor g anic Total

N:P ratio * N:P ratio

D-013 3.0 U - 7.7

D-00F 3.0 U - 7.8

D-072 3.0 AU - 11.6

* - Ortho-phosphate was not measured in the analytical chemistry sample; therefore, inorganic N:P ratios could not be calculated.

A - Value reported is the mean of two or more determinations U - Material analyzed for but not detected; value reported is the

method detection limit Location Progress Energy Florida Crystal River Plant Units 1, 2 and 3.

NPDES# FL0000159. Table 1. Measured algal growth potential (AGP; mg dry weight/L)
of the saltwater species Dunaliella tertiolecta and ratios of nitrogen to phosphorus for samples collected from the Progress Energy Crystal River Plant Units 1, 2 and 3 facility on August 10,

2009.

AGP (measured)

# 6 Progress Energy Florida Crystal
River Plant Units 1, 2 and 3

NPDES# FL0000159 Class III

Criteria Effluent

Limits

None Detected - -

Aluminum ≤ 1500 - 1200 1040 490 I

Arsenic ≤ 50 - 3 I 3.3 I 2.4 I

Cadmium ≤ 8.8 - 0.12 U 0.12 U 0.12 U Calcium (mg/L) - - 356 348 347

Chromium-III - - 4.5 I 4 I 1.8 I Copper ≤ 3.7 Report 2 U 2.7 2 U

Iron ≤ 300 Report 1190 970 320 I

Lead ≤ 8.5 - 0.96 I 0.83 I 0.8 U Magnesium (mg/L) - - 1100 1110 1110 Mercury ≤ 0.025 - - - -

Nickel ≤ 8.3 - 1.4 U 1.4 U 1.4 U

Selenium ≤ 71 - 0.8 U 0.8 U 0.8 U

Silver ≤ 2.3 - 0.1 U 0.1 U 0.1 U

Zinc ≤ 86 - 21 I 20 I 24 I

Total Phosphorus - - 0.089 0.093 AJ 0.048

Total Ammonia - - 0.01 U 0.011 I 0.028

Un-ionized Ammonia - - ≤ 0.02 c ≤ 0.02 c ≤ 0.02 c

Nitrate and Nitrite - - 0.006 I 0.004 U 0.005 I Total Kjeldahl Nitrogen - - 0.68 J 0.72 0.55 Organic Nitrogen - - 0.675 c 0.709 c 0.522 c Total Nitrogen - - 0.686 c 0.722 c 0.555 c

Dissolved Oxygen (mg/L) ≥ 4.0 - 5.3 5.3 6.6 pH (SU) 6.5 - 8.5 - 8.0 8.1 8.1 Conductivity (μmhos/cm) - - 47868 47800 46443 Temperature (°C) - - 41.8 40.7 31.8 Salinity - - 30.6 30.6 26.1 c Total Residual Chlorine (mg/L) ≤ 0.01 - ≤ 0.03 UQ£ 0 0 Chlorophyll a (μg/L) - Corrected - - 4.5 2.2 1.9 Phaeophytin (μg/L) - - 4.1 1.9 1.8 Total Suspended Solids (mg/L) - - 70 78 40 A Turbidity (NTU) < 29 t - 36 A 34 - CBOD, 5 day (mg/L), N - inhibited - - 0.81 I 1.1 I 0.94 I Oils and Greases (mg/L) ≤ 5.0 ≤ 20.0 - 1.4 U - Alpha, Total (pCi/L) ≤ 15 - 3.1 1.8 - Alpha-Counting Error (pCi/L) - - 1.1 0.9 - Radium 226 (pCi/L) - - 1.8 1.4 - Radium 226-Counting Error (pCi/L) - - 0.2 0.2 - Radium 228 (pCi/L) - - 1 0.8 - Radium 228-Counting Error (pCi/L) - - 0.6 0.5 - Radium 226 + 228 (pCi/L) ≤ 5 - 2.8 c 2.2 c -
Hardness (mg CaCO 3 ) - - 5418.73 c 5439.94 c 5437.44 c
Flow (MGD) - 1898 a 218.98 a

Value exceeds the Class III Water Quality Criteria or permit limits a - Annual average

c - Value is calculated t - Shall not exceed 29 NTUs above background

A

- Value reported is the mean of two or more determinations I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit

J - Estimated value U - Material analyzed for but not detected; value reported is the method detection limit Q - Sample held beyond normal holding time £ - Measurement performed in bioassay laboratory Table 2. Effluent limits, Class III Criteria for predominantly marine waters and chemical data for samples collected from the Progress Energy Florida Crystal River Plant Units 1, 2 and 3 facility on
August 10, 2009.

Nutrients (mg/L)

General Physical and Chemical Parameters D-072

Organic Constituents (μg/L)

Metals (μg/L unless otherwise noted) None Detected D-013 D-00F

# 7 Appendix A. Chain of Custody Form

# 8 Appendix A. (continued)

# 9 Appendix B. Bench Sheets

# 10 Appendix B. (continued)

# 11 Appendix B. (continued)

# 12 Appendix B. (continued)

# 13 Appendix B. (continued)

# 14 Appendix B. (continued)

# 15 Appendix C. SRT Bench Sheet s and Statistical Analysis

Florida Department of Environmental Protection

Bureau of Laboratories

Standard Reference Toxicant (SRT) Test Data - 48-hour Acute Toxicity
Americamysis bahia (mysid shrimp) - Cadmium Chloride (CdCl 2 

## )

Date LC50 Mean LC50 Std Dev Lower Control Limit Upper Control Limit

03/11/08 38.21 47.42 11.38 24.66 70.19

04/01/08 53.27 46.90 10.82 25.26 68.53

05/06/08 35.65 45.82 10.81 24.19 67.45

06/03/08 58.28 46.36 11.17 24.03 68.69

07/08/08 47.67 46.00 10.99 24.02 67.98

08/05/08 44.68 46.32 10.84 24.63 68.01

09/03/08 45.94 45.82 10.60 24.62 67.02

10/07/08 41.43 44.39 8.96 26.47 62.30

11/04/08 46.75 44.58 8.97 26.64 62.51

11/12/09 44.92 44.87 8.87 27.13 62.61

12/02/08 40.59 44.42 8.84 26.73 62.11

01/06/09 37.22 43.80 8.89 26.01 61.59

02/03/09 39.02 43.57 8.96 25.66 61.49

03/03/09 30.58 42.81 9.40 24.02 61.61

03/31/09 38.24 42.65 9.45 23.76 61.55

04/08/09 31.38 42.44 9.66 23.12 61.76

05/05/09 33.86 41.62 9.66 22.31 60.93

06/09/09 41.42 40.46 8.00 24.47 56.45

07/07/09 43.11 41.44 6.94 27.55 55.32

08/04/09 35.91 41.41 6.97 27.47 55.34

Lower Confidence Limit = mean - 2 * Std Dev CV = 16.82 Upper Confidence Limit = mean + 2 * Std Dev EPA reference 75th quartile CV = 26%

20 30 40 50 60 70 8003/11/0804/01/0805/06/0806/03/0807/08/0808/05/0809/03/0810/07/0811/04/0811/12/0912/02/0801/06/0902/03/0903/03/0903/31/0904/08/0905/05/0906/09/0907/07/0908/04/09μg/L CdCl2



### Test Date 

## Standard Reference Toxicant Data Americamysis bahia 48-hour LC 50

LC50 Mean LC50 Lower Control Limit Upper Control Limit

# 16 Appendix C. (continued)
Florida Department of Environmental Protection

Bureau of Laboratories

Standard Reference Toxicant ( SRT ) Test Data - Acute Toxicit y M en idi a b ery lli

na (I n l an d s il vers id e )
- C opper Chl or id e (C u Cl 2 

## )

Date LC50 Mean LC50 Std Dev Lower

Control Limit Upper

Control Limit

03/04/08 295.52 295.31 68.1 159.3 431.9

04/01/08 379.50 304.05 67.5 169.0 439.1

05/06/08 272.50 304.73 67.1 170.5 438.9

06/03/08 373.47 312.52 65.5 181.5 443.5

07/08/08 275.20 316.13 61.0 194.2 438.1

08/12/08 221.17 320.17 50.5 219.2 421.1

09/03/08 167.46 313.48 60.9 191.7 435.3

09/09/08 240.07 311.58 62.6 186.3 436.9

10/07/08 325.55 312.05 62.7 186.6 437.5
11/04/08 249.81 307.63 63.9 179.9 435.4

12/02/08 316.79 310.59 62.8 185.0 436.2

01/06/09 257.04 311.08 62.3 186.5 435.7
02/03/09 245.51 305.47 62.9 179.6 431.4

03/03/09 433.98 309.64 68.6 172.5 446.8
03/31/09 228.94 304.17 70.5 163.1 445.2

05/05/09 310.12 302.74 70.1 162.6 442.9
06/02/09 471.25 305.32 75.4 154.6 456.0

06/09/09 370.27 306.03 75.9 154.2 457.9

07/07/09 407.17 309.94 79.1 151.7 468.2
08/04/09 339.47 309.04 78.7 151.7 466.3

Means are of the last 20 SRT tests. EPA reference 75th quartile CV = 21% CV = 25.45

0 50 100 150 200 250 300 350 400 450 50003/04/0804/01/0805/06/0806/03/0807/08/0808/12/0809/03/0809/09/0810/07/0811/04/0812/02/0801/06/0902/03/0903/03/0903/31/0905/05/0906/02/0906/09/0907/07/0908/04/09μg/L CuCl2



## Test Date 

## Standard Reference Toxicant Data Menidia beryllina 48 hour LC50

Lower Control Limit LC50 Mean LC50 Upper Control Limit

# 17 Appendix C. (continued)

# 18 Appendix C. (continued)

# 19 Appendix C. (continued)

# 20 Appendix C. (continued)

# 21 Appendix C. (continued)

A mericamysis bahia Acute Standard Reference Toxicant Test

DATE: 8-4-09 DURATION: 48 hr TOXICANT : CdCl2

SPECIES: Americamysis bahia

RAW DATA: Concentration Number Mortalities (ug/L) Exposed

.00 20 0

20.00 20 1

30.00 20 4

45.00 20 17

67.00 20 19

100.00 20 20

SPEARMAN-KARBER TRIM: 5.00%

SPEARMAN-KARBER ESTIMATES: LC50: 35.91

95% LOWER CONFIDENCE: 32.11

95% UPPER CONFIDENCE: 40.16

M enidia beryllina Acute Standard Reference Toxicant Test

DATE: 8-4-09 DURATION: 48 h TOXICANT : CuCl2

SPECIES: Menidia beryllina

RAW DATA: Concentration Number Mortalities (ug/L) Exposed

.00 20 0

100.00 20 2

200.00 20 2

300.00 20 12

400.00 20 8

500.00 20 16

SPEARMAN-KARBER TRIM: 20.00%

SPEARMAN-KARBER ESTIMATES: LC50: 339.47

95% LOWER CONFIDENCE: 288.65

95% UPPER CONFIDENCE: 399.24

NOTE: MORTALITY PROPORTIONS WERE NOT MONOTONICALLY INCREASING.

ADJUSTMENTS WERE MADE PRIOR TO SPEARMAN-KARBER ESTIMATION.

# 22 Appendix D. Test Organism Receipts

# 23 Appendix D. (continued)24Appendix E. Chemical Analyses performed on the effluent from the ProgressEnergy Florida Crystal River PlantUnits 1, 2, and 3 Plant Outfalls D-00F, D-013, D-092,D-094 and D-072, sampled on August 10, 2009.Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 11:45 D-013 AGP/LN Algal Growth Potential 3 U mg DryWt/L 3 38/10/2009 11:45 D-013 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 0.81 I mg/L 0.2 28/10/2009 11:45 D-013 Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 4.5 ug/L 1.1 3.48/10/2009 11:45 D-013 Chlorophyll/Grain Size/BOD Phaeophytin-a 4.1 ug/L 0.8 2.48/10/2009 11:45 D-013 Metals Zinc 21 I ug/L 15 608/10/2009 11:45 D-013 Metals Cadmium 0.12 U ug/L 0.12 0.488/10/2009 11:45 D-013 Metals Chromium 4.5 I ug/L 1.2 4.88/10/2009 11:45 D-013 Metals Lead 0.96 I ug/L 0.8 3.28/10/2009 11:45 D-013 Metals Silver 0.1 U ug/L 0.1 0.48/10/2009 11:45 D-013 Metals Calcium 356 mg/L 0.22 0.98/10/2009 11:45 D-013 Metals Nickel 1.4 U ug/L 1.4 5.68/10/2009 11:45 D-013 Metals Iron 1190 ug/L 90 3608/10/2009 11:45 D-013 Metals Magnesium 1100 mg/L 0.8 3.28/10/2009 11:45 D-013 Metals Aluminum 1200 ug/L 180 7208/10/2009 11:45 D-013 Metals Selenium 0.8 U ug/L 0.8 3.28/10/2009 11:45 D-013 Metals Copper 2 U ug/L 2 28/10/2009 11:45 D-013 Metals Arsenic 3 I ug/L 1 48/10/2009 11:45 D-013 Nutrients Turbidity 36 A NTU 0.1 0.18/10/2009 11:45 D-013 Nutrients Kjeldahl Nitrogen 0.68 J mg N/L 0.16 0.48/10/2009 11:45 D-013 Nutrients NO2NO3-N 0.006 I mg N/L 0.004 0.018/10/2009 11:45 D-013 Nutrients Ammonia-N 0.01 U mg N/L 0.01 0.028/10/2009 11:45 D-013 Nutrients TSS 70 mg/L 4 168/10/2009 11:45 D-013 Nutrients Total-P 0.089 mg P/L 0.008 0.028/10/2009 11:45 D-013 Overflow Radium 228 1 pCi/L8/10/2009 11:45 D-013 Overflow Alpha, Total 3.1 pCi/L8/10/2009 11:45 D-013 Overflow Radium 226 1.8 pCi/L8/10/2009 11:45 D-013 Overflow Radium 226-Counting Error 0.2 pCi/L8/10/2009 11:45 D-013 Overflow Alpha-Counting Error 1.1 pCi/L8/10/2009 11:45 D-013 Overflow Radium 228-Counting Error 0.6 pCi/L8/10/2009 11:45 D-013 Pesticides Azinphos Methyl 0.22 UJ ug/L 0.22 0.888/10/2009 11:45 D-013 Pesticides Butylate 0.22 UJ ug/L 0.22 0.888/10/2009 11:45 D-013 Pesticides Chlorpyrifos Methyl 0.11 U ug/L 0.11 0.448/10/2009 11:45 D-013 Pesticides Diazinon 0.056 UJ ug/L 0.056 0.2225Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 11:45 D-013 Pesticides Ethoprop 0.11 U ug/L 0.11 0.448/10/2009 11:45 D-013 Pesticides Fenamiphos 0.22 UJ ug/L 0.22 0.888/10/2009 11:45 D-013 Pesticides Mevinphos 0.22 U ug/L 0.22 0.888/10/2009 11:45 D-013 Pesticides Malathion 0.17 U ug/L 0.17 0.688/10/2009 11:45 D-013 Pesticides Metribuzin 0.11 U ug/L 0.11 0.448/10/2009 11:45 D-013 Pesticides Naled 0.9 U ug/L 0.9 3.68/10/2009 11:45 D-013 Pesticides Beta-BHC 0.011 U ug/L 0.011 0.0448/10/2009 11:45 D-013 Pesticides Metalaxyl 0.28 UJ ug/L 0.28 1.18/10/2009 11:45 D-013 Pesticides Metolachlor 0.56 UJ ug/L 0.56 2.28/10/2009 11:45 D-013 Pesticides Endosulfan II 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Atrazine 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Parathion Ethyl 0.17 U ug/L 0.17 0.688/10/2009 11:45 D-013 Pesticides Parathion Methyl 0.11 U ug/L 0.11 0.448/10/2009 11:45 D-013 Pesticides Endrin 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Heptachlor Epoxide 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Chlorpyrifos Ethyl 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Fonofos 0.11 UJ ug/L 0.11 0.448/10/2009 11:45 D-013 Pesticides DDD-p,p' 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides DDE-p,p' 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Delta-BHC 0.011 U ug/L 0.011 0.0448/10/2009 11:45 D-013 Pesticides Endrin Aldehyde 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Gamma-BHC 0.011 U ug/L 0.011 0.0448/10/2009 11:45 D-013 Pesticides Bromacil 0.22 U ug/L 0.22 0.888/10/2009 11:45 D-013 Pesticides Hexazinone 0.11 UJ ug/L 0.11 0.448/10/2009 11:45 D-013 Pesticides Norflurazon 0.17 UJ ug/L 0.17 0.688/10/2009 11:45 D-013 Pesticides Simazine 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Alpha-BHC 0.011 U ug/L 0.011 0.0448/10/2009 11:45 D-013 Pesticides Phorate 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Chlordane 0.22 U ug/L 0.22 0.888/10/2009 11:45 D-013 Pesticides DDT-p,p' 0.034 U ug/L 0.034 0.148/10/2009 11:45 D-013 Pesticides Endosulfan I 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Endosulfan Sulfate 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Methoxychlor 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Alachlor 0.67 UJ ug/L 0.67 2.726Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 11:45 D-013 Pesticides Ametryn 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Ethion 0.056 U ug/L 0.056 0.228/10/2009 11:45 D-013 Pesticides Prometryn 0.17 U ug/L 0.17 0.688/10/2009 11:45 D-013 Pesticides Aldrin 0.011 U ug/L 0.011 0.0448/10/2009 11:45 D-013 Pesticides Dieldrin 0.022 U ug/L 0.022 0.0888/10/2009 11:45 D-013 Pesticides Heptachlor 0.011 U ug/L 0.011 0.0448/10/2009 11:45 D-013 Pesticides Toxaphene 0.84 U ug/L 0.84 3.48/10/2009 11:45 D-013 Priority Organic Pollutants 4-Nitrophenol 17 U ug/L 17 678/10/2009 11:45 D-013 Priority Organic Pollutants Butyl benzyl phthalate 5.6 U ug/L 5.6 228/10/2009 11:45 D-013 Priority Organic Pollutants Phenanthrene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants4-Chlorophenyl phenyl ether 2.2 U ug/L 2.2 8.98/10/2009 11:45 D-013 Priority Organic Pollutants Acenaphthene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Acenaphthylene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Di-n-butyl phthalate 5.6 U ug/L 5.6 228/10/2009 11:45 D-013 Priority Organic Pollutants Hexachloroethane 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants 2,4,6-Trichlorophenol 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 2,6-Dinitrotoluene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 17 U ug/L 17 678/10/2009 11:45 D-013 Priority Organic Pollutants Chrysene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Diethyl phthalate 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants Pentachlorophenol 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants 1,2,4-Trichlorobenzene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 2-Chloronaphthalene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 2-Chlorophenol 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 2-Nitrophenol 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 3,3'-Dichlorobenzidine 45 UJ ug/L 45 1808/10/2009 11:45 D-013 Priority Organic Pollutants 4-Bromophenyl phenyl ether 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Anthracene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(b)fluoranthene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(k)fluoranthene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Bis(2-chloroisopropyl)ether 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants N-Nitrosodi-n-propylamine 2.2 U ug/L 2.2 8.98/10/2009 11:45 D-013 Priority Organic Pollutants Naphthalene 1.1 U ug/L 1.1 4.527Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 11:45 D-013 Priority Organic Pollutants Phenol 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Pyrene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dimethylphenol 11 UJ ug/L 11 458/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dinitrotoluene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Benzidine 110 U ug/L 110 4508/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(a)pyrene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic PollutantsBis(2-chloroethyl)ether 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Dibenzo(a,h)anthracene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Dimethyl phthalate 11 U ug/L 11 458/10/2009 11:45 D-013 Priority Organic Pollutants Hexachlorobenzene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dichlorophenol 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(a)anthracene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic PollutantsBis(2-chloroethoxy)methane 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Di-n-octyl phthalate 1.1 UJ ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Fluoranthene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Hexachlorocyclopentadiene 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Isophorone 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants N-Nitrosodimethylamine 2.2 U ug/L 2.2 8.98/10/2009 11:45 D-013 Priority Organic Pollutants Nitrobenzene 2.2 U ug/L 2.2 8.98/10/2009 11:45 D-013 Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants Fluorene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Hexachlorobutadiene 3.4 U ug/L 3.4 138/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dinitrophenol 17 U ug/L 17 678/10/2009 11:45 D-013 Priority Organic Pollutants 4-Chloro-3-methylphenol 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(g,h,i)perylene 1.1 U ug/L 1.1 4.58/10/2009 11:45 D-013 Field Parameter pH 8.048/10/2009 11:45 D-013 Field Parameter Sample Depth 0.2 m8/10/2009 11:45 D-013 Field Parameter Specific Conductance 47868 umhos/cm8/10/2009 11:45 D-013 Field Parameter Dissolved Oxygen 5.31 mg/L8/10/2009 11:45 D-013 Field Parameter Temperature 41.83 C8/10/2009 12:05 D-00F AGP/LN Algal Growth Potential 3 U mg DryWt/L 3 328Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 12:05 D-00F Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 1.1 I mg/L 0.2 28/10/2009 12:05 D-00F Chlorophyll/Grain Size/BOD Phaeophytin-a 1.9 ug/L 0.4 1.28/10/2009 12:05 D-00F Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 2.2 ug/L 0.55 1.78/10/2009 12:05 D-00F Toxicology Bioassay-Acute-Screen-SW-Mysid, LC50 100 L LC508/10/2009 12:05 D-00F Toxicology Bioassay-Acute-Screen-SW-Fish, LC50 100 L LC508/10/2009 12:05 D-00F Metals Silver 0.1 U ug/L 0.1 0.48/10/2009 12:05 D-00F Metals Cadmium 0.12 U ug/L 0.12 0.488/10/2009 12:05 D-00F Metals Aluminum 1040 ug/L 180 7208/10/2009 12:05 D-00F Metals Zinc 20 I ug/L 15 608/10/2009 12:05 D-00F Metals Lead 0.83 I ug/L 0.8 3.28/10/2009 12:05 D-00F Metals Iron 970 ug/L 90 3608/10/2009 12:05 D-00F Metals Chromium 4 I ug/L 1.2 4.88/10/2009 12:05 D-00F Metals Arsenic 3.3 I ug/L 1 48/10/2009 12:05 D-00F Metals Nickel 1.4 U ug/L 1.4 5.68/10/2009 12:05 D-00F Metals Copper 2.7 ug/L 2 28/10/2009 12:05 D-00F Metals Magnesium 1110 mg/L 0.8 3.28/10/2009 12:05 D-00F Metals Selenium 0.8 U ug/L 0.8 3.28/10/2009 12:05 D-00F Metals Calcium 348 mg/L 0.22 0.98/10/2009 12:05 D-00F Nutrients Total-P 0.093 AJ mg P/L 0.008 0.028/10/2009 12:05 D-00F Nutrients Turbidity 34 NTU 0.1 0.18/10/2009 12:05 D-00F Nutrients TSS 78 mg/L 4 168/10/2009 12:05 D-00F Nutrients NO2NO3-N 0.004 U mg N/L 0.004 0.018/10/2009 12:05 D-00F Nutrients Ammonia-N 0.011 I mg N/L 0.01 0.028/10/2009 12:05 D-00F Nutrients Kjeldahl Nitrogen 0.72 mg N/L 0.16 0.48/10/2009 12:05 D-00F Overflow Radium 226-Counting Error 0.2 pCi/L8/10/2009 12:05 D-00F Overflow Radium 228-Counting Error 0.5 pCi/L8/10/2009 12:05 D-00F Overflow Alpha, Total 1.8 pCi/L8/10/2009 12:05 D-00F Overflow Oil and Grease 1.4 U mg/L 1.4 58/10/2009 12:05 D-00F Overflow Radium 226 1.4 pCi/L8/10/2009 12:05 D-00F Overflow Alpha-Counting Error 0.9 pCi/L8/10/2009 12:05 D-00F Overflow Radium 228 0.8 pCi/L8/10/2009 12:05 D-00F Pesticides Ametryn 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Atrazine 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Fenamiphos 0.22 UJ ug/L 0.22 0.8829Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 12:05 D-00F Pesticides Parathion Methyl 0.11 U ug/L 0.11 0.448/10/2009 12:05 D-00F Pesticides Simazine 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides DDT-p,p' 0.032 U ug/L 0.032 0.138/10/2009 12:05 D-00F Pesticides Endrin Aldehyde 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Chlorpyrifos Ethyl 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Metalaxyl 0.27 UJ ug/L 0.27 1.18/10/2009 12:05 D-00F Pesticides DDE-p,p' 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Metolachlor 0.54 UJ ug/L 0.54 2.28/10/2009 12:05 D-00F Pesticides Parathion Ethyl 0.16 U ug/L 0.16 0.648/10/2009 12:05 D-00F Pesticides DDD-p,p' 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Endosulfan II 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Endosulfan Sulfate 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Heptachlor Epoxide 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Bromacil 0.22 U ug/L 0.22 0.888/10/2009 12:05 D-00F Pesticides Diazinon 0.054 UJ ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Alpha-BHC 0.011 U ug/L 0.011 0.0448/10/2009 12:05 D-00F Pesticides Delta-BHC 0.011 U ug/L 0.011 0.0448/10/2009 12:05 D-00F Pesticides Heptachlor 0.011 U ug/L 0.011 0.0448/10/2009 12:05 D-00F Pesticides Chlorpyrifos Methyl 0.11 U ug/L 0.11 0.448/10/2009 12:05 D-00F Pesticides Fonofos 0.11 UJ ug/L 0.11 0.448/10/2009 12:05 D-00F Pesticides Hexazinone 0.11 UJ ug/L 0.11 0.448/10/2009 12:05 D-00F Pesticides Naled 0.86 U ug/L 0.86 3.48/10/2009 12:05 D-00F Pesticides Norflurazon 0.16 UJ ug/L 0.16 0.648/10/2009 12:05 D-00F Pesticides Aldrin 0.011 U ug/L 0.011 0.0448/10/2009 12:05 D-00F Pesticides Gamma-BHC 0.011 U ug/L 0.011 0.0448/10/2009 12:05 D-00F Pesticides Azinphos Methyl 0.22 UJ ug/L 0.22 0.888/10/2009 12:05 D-00F Pesticides Metribuzin 0.11 U ug/L 0.11 0.448/10/2009 12:05 D-00F Pesticides Mevinphos 0.22 U ug/L 0.22 0.888/10/2009 12:05 D-00F Pesticides Phorate 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Beta-BHC 0.011 U ug/L 0.011 0.0448/10/2009 12:05 D-00F Pesticides Dieldrin 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Ethion 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Ethoprop 0.11 U ug/L 0.11 0.448/10/2009 12:05 D-00F Pesticides Prometryn 0.16 U ug/L 0.16 0.6430Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 12:05 D-00F Pesticides Chlordane 0.22 U ug/L 0.22 0.888/10/2009 12:05 D-00F Pesticides Methoxychlor 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Pesticides Toxaphene 0.81 U ug/L 0.81 3.28/10/2009 12:05 D-00F Pesticides Alachlor 0.65 UJ ug/L 0.65 2.68/10/2009 12:05 D-00F Pesticides Butylate 0.22 UJ ug/L 0.22 0.888/10/2009 12:05 D-00F Pesticides Malathion 0.16 U ug/L 0.16 0.648/10/2009 12:05 D-00F Pesticides Endosulfan I 0.022 U ug/L 0.022 0.0888/10/2009 12:05 D-00F Pesticides Endrin 0.054 U ug/L 0.054 0.228/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dinitrophenol 16 U ug/L 16 638/10/2009 12:05 D-00F Priority Organic Pollutants4-Chlorophenyl phenyl ether 2.1 U ug/L 2.1 8.48/10/2009 12:05 D-00F Priority Organic Pollutants 2-Nitrophenol 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-chloroethoxy)methane 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dinitrotoluene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2,6-Dinitrotoluene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 4-Chloro-3-methylphenol 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Acenaphthene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Anthracene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(a)anthracene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Di-n-butyl phthalate 5.2 U ug/L 5.2 218/10/2009 12:05 D-00F Priority Organic Pollutants Di-n-octyl phthalate 1 UJ ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Dimethyl phthalate 10 U ug/L 10 428/10/2009 12:05 D-00F Priority Organic Pollutants Isophorone 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Pentachlorophenol 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Priority Organic Pollutants Pyrene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2-Chloronaphthalene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(b)fluoranthene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(k)fluoranthene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-chloroethyl)ether 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-chloroisopropyl)ether 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants N-Nitrosodi-n-propylamine 2.1 U ug/L 2.1 8.48/10/2009 12:05 D-00F Priority Organic Pollutants Naphthalene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dimethylphenol 10 UJ ug/L 10 428/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(g,h,i)perylene 1 U ug/L 1 4.231Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 12:05 D-00F Priority Organic Pollutants Butyl benzyl phthalate 5.2 U ug/L 5.2 218/10/2009 12:05 D-00F Priority Organic Pollutants Dibenzo(a,h)anthracene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Hexachlorobenzene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Hexachlorocyclopentadiene 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Priority Organic Pollutants 4-Bromophenyl phenyl ether 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 16 U ug/L 16 638/10/2009 12:05 D-00F Priority Organic Pollutants Phenanthrene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Phenol 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Acenaphthylene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Benzidine 100 U ug/L 100 4208/10/2009 12:05 D-00F Priority Organic Pollutants Chrysene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Fluoranthene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Fluorene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Priority Organic Pollutants Nitrobenzene 2.1 U ug/L 2.1 8.48/10/2009 12:05 D-00F Priority Organic Pollutants 2-Chlorophenol 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 3,3'-Dichlorobenzidine 42 UJ ug/L 42 1708/10/2009 12:05 D-00F Priority Organic Pollutants 4-Nitrophenol 16 U ug/L 16 638/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(a)pyrene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Diethyl phthalate 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants Hexachlorobutadiene 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Priority Organic Pollutants Hexachloroethane 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Priority Organic Pollutants N-Nitrosodimethylamine 2.1 U ug/L 2.1 8.48/10/2009 12:05 D-00F Priority Organic Pollutants 1,2,4-Trichlorobenzene 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2,4,6-Trichlorophenol 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dichlorophenol 1 U ug/L 1 4.28/10/2009 12:05 D-00F Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 3.1 U ug/L 3.1 138/10/2009 12:05 D-00F Field Parameter Sample Depth 0.2 m8/10/2009 12:05 D-00F Field Parameter Temperature 40.67 C8/10/2009 12:05 D-00F Field Parameter Temperature 40.67 C8/10/2009 12:05 D-00F Field Parameter Sample Depth 0.2 m32Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 12:05 D-00F Field Parameter pH 8.068/10/2009 12:05 D-00F Field Parameter Specific Conductance 47800 umhos/cm8/10/2009 12:05 D-00F Field Parameter Dissolved Oxygen 5.33 mg/L8/10/2009 11:40 Equipment Blank Metals Calcium 0.075 U mg/L 0.075 0.38/10/2009 11:40 Equipment Blank Metals Silver 0.025 U ug/L 0.025 0.18/10/2009 11:40 Equipment Blank Metals Nickel 0.25 U ug/L 0.25 18/10/2009 11:40 Equipment Blank Metals Zinc 7.2 I ug/L 5 208/10/2009 11:40 Equipment Blank Metals Selenium 0.2 U ug/L 0.2 0.88/10/2009 11:40 Equipment Blank Metals Lead 0.2 U ug/L 0.2 0.88/10/2009 11:40 Equipment Blank Metals Chromium 0.3 U ug/L 0.3 1.28/10/2009 11:40 Equipment Blank Metals Iron 30 U ug/L 30 1208/10/2009 11:40 Equipment Blank Metals Aluminum 60 U ug/L 60 2408/10/2009 11:40 Equipment Blank Metals Copper 0.5 U ug/L 0.5 0.58/10/2009 11:40 Equipment Blank Metals Arsenic 0.25 U ug/L 0.25 18/10/2009 11:40 Equipment Blank Metals Magnesium 0.04 U mg/L 0.04 0.168/10/2009 11:40 Equipment Blank Metals Cadmium 0.03 U ug/L 0.03 0.128/10/2009 11:40 Equipment Blank Nutrients NO2NO3-N 0.005 I mg N/L 0.004 0.018/10/2009 11:40 Equipment Blank Nutrients Ammonia-N 0.01 U mg N/L 0.01 0.028/10/2009 11:40 Equipment Blank Nutrients Total-P 0.004 U mg P/L 0.004 0.018/10/2009 11:40 Equipment Blank Nutrients Kjeldahl Nitrogen 0.08 U mg N/L 0.08 0.28/10/2009 12:30 D-092 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 1 I mg/L 0.2 28/10/2009 12:30 D-092 Overflow COD 300 mg/L 32 1008/10/2009 12:30 D-092 Field Parameter Temperature 31.31 C8/10/2009 12:30 D-092 Field Parameter Sample Depth 0.2 m8/10/2009 12:30 D-092 Field Parameter pH 8.038/10/2009 12:30 D-092 Field Parameter Specific Conductance 48351 umhos/cm8/10/2009 12:30 D-092 Field Parameter Dissolved Oxygen 6.15 mg/L8/10/2009 12:50 D-094 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 0.79 I mg/L 0.2 28/10/2009 12:50 D-094 Overflow COD 740 mg/L 32 1008/10/2009 12:50 D-094 Field Parameter Temperature 40.21 C8/10/2009 12:50 D-094 Field Parameter Dissolved Oxygen 5.39 mg/L8/10/2009 12:50 D-094 Field Parameter Specific Conductance 47600 umhos/cm8/10/2009 12:50 D-094 Field Parameter Sample Depth 0.2 m8/10/2009 12:50 D-094 Field Parameter pH 8.0333Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 13:05 D-072 AGP/LN Algal Growth Potential 3 AU mg DryWt/L 3 38/10/2009 13:05 D-072 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 0.94 I mg/L 0.2 28/10/2009 13:05 D-072 Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 1.9 ug/L 0.55 1.78/10/2009 13:05 D-072 Chlorophyll/Grain Size/BOD Phaeophytin-a 1.8 ug/L 0.4 1.28/10/2009 13:05 D-072 Metals Copper 2 U ug/L 2 28/10/2009 13:05 D-072 Metals Zinc 24 I ug/L 20 808/10/2009 13:05 D-072 Metals Magnesium 1110 mg/L 0.8 3.28/10/2009 13:05 D-072 Metals Cadmium 0.12 U ug/L 0.12 0.488/10/2009 13:05 D-072 Metals Nickel 1.4 U ug/L 1.4 5.68/10/2009 13:05 D-072 Metals Silver 0.1 U ug/L 0.1 0.48/10/2009 13:05 D-072 Metals Iron 320 I ug/L 90 3608/10/2009 13:05 D-072 Metals Calcium 347 mg/L 0.22 0.98/10/2009 13:05 D-072 Metals Arsenic 2.4 I ug/L 1 48/10/2009 13:05 D-072 Metals Aluminum 490 I ug/L 180 7208/10/2009 13:05 D-072 Metals Selenium 0.8 U ug/L 0.8 3.28/10/2009 13:05 D-072 Metals Lead 0.8 U ug/L 0.8 3.28/10/2009 13:05 D-072 Metals Chromium 1.8 I ug/L 1.2 4.88/10/2009 13:05 D-072 Nutrients Total-P 0.048 mg P/L 0.008 0.028/10/2009 13:05 D-072 Nutrients TSS 40 A mg/L 4 168/10/2009 13:05 D-072 Nutrients Ammonia-N 0.028 mg N/L 0.01 0.028/10/2009 13:05 D-072 Nutrients NO2NO3-N 0.005 I mg N/L 0.004 0.018/10/2009 13:05 D-072 Nutrients Kjeldahl Nitrogen 0.55 mg N/L 0.16 0.48/10/2009 13:05 D-072 Pesticides Endosulfan Sulfate 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Endrin Aldehyde 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Azinphos Methyl 0.21 UJ ug/L 0.21 0.848/10/2009 13:05 D-072 Pesticides Chlorpyrifos Methyl 0.11 U ug/L 0.11 0.448/10/2009 13:05 D-072 Pesticides Fenamiphos 0.21 UJ ug/L 0.21 0.848/10/2009 13:05 D-072 Pesticides Fonofos 0.11 UJ ug/L 0.11 0.448/10/2009 13:05 D-072 Pesticides Heptachlor 0.011 U ug/L 0.011 0.0448/10/2009 13:05 D-072 Pesticides Heptachlor Epoxide 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Methoxychlor 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Ametryn 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Metolachlor 0.53 UJ ug/L 0.53 2.18/10/2009 13:05 D-072 Pesticides Simazine 0.053 U ug/L 0.053 0.2134Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 13:05 D-072 Pesticides Delta-BHC 0.011 U ug/L 0.011 0.0448/10/2009 13:05 D-072 Pesticides Beta-BHC 0.011 U ug/L 0.011 0.0448/10/2009 13:05 D-072 Pesticides DDE-p,p' 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides DDT-p,p' 0.032 U ug/L 0.032 0.138/10/2009 13:05 D-072 Pesticides Toxaphene 0.79 U ug/L 0.79 3.28/10/2009 13:05 D-072 Pesticides Atrazine 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Malathion 0.16 U ug/L 0.16 0.648/10/2009 13:05 D-072 Pesticides Metalaxyl 0.26 UJ ug/L 0.26 18/10/2009 13:05 D-072 Pesticides Alachlor 0.63 UJ ug/L 0.63 2.58/10/2009 13:05 D-072 Pesticides Chlorpyrifos Ethyl 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Naled 0.84 U ug/L 0.84 3.48/10/2009 13:05 D-072 Pesticides Alpha-BHC 0.011 U ug/L 0.011 0.0448/10/2009 13:05 D-072 Pesticides Dieldrin 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Endosulfan II 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Aldrin 0.011 U ug/L 0.011 0.0448/10/2009 13:05 D-072 Pesticides Prometryn 0.16 U ug/L 0.16 0.648/10/2009 13:05 D-072 Pesticides Parathion Ethyl 0.16 U ug/L 0.16 0.648/10/2009 13:05 D-072 Pesticides Metribuzin 0.11 U ug/L 0.11 0.448/10/2009 13:05 D-072 Pesticides Endosulfan I 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Phorate 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Hexazinone 0.11 UJ ug/L 0.11 0.448/10/2009 13:05 D-072 Pesticides Diazinon 0.053 UJ ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Butylate 0.21 UJ ug/L 0.21 0.848/10/2009 13:05 D-072 Pesticides Gamma-BHC 0.011 U ug/L 0.011 0.0448/10/2009 13:05 D-072 Pesticides DDD-p,p' 0.021 U ug/L 0.021 0.0848/10/2009 13:05 D-072 Pesticides Chlordane 0.21 U ug/L 0.21 0.848/10/2009 13:05 D-072 Pesticides Parathion Methyl 0.11 U ug/L 0.11 0.448/10/2009 13:05 D-072 Pesticides Norflurazon 0.16 UJ ug/L 0.16 0.648/10/2009 13:05 D-072 Pesticides Mevinphos 0.21 U ug/L 0.21 0.848/10/2009 13:05 D-072 Pesticides Ethoprop 0.11 U ug/L 0.11 0.448/10/2009 13:05 D-072 Pesticides Ethion 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Endrin 0.053 U ug/L 0.053 0.218/10/2009 13:05 D-072 Pesticides Bromacil 0.21 U ug/L 0.21 0.8435Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 13:05 D-072 Priority Organic Pollutants 2-Chloronaphthalene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2-Nitrophenol 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Acenaphthene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Di-n-octyl phthalate 1.1 UJ ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Dibenzo(a,h)anthracene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Nitrobenzene 2.2 U ug/L 2.2 8.78/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dinitrophenol 16 U ug/L 16 668/10/2009 13:05 D-072 Priority Organic Pollutants Naphthalene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Pyrene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 4-Chloro-3-methylphenol 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(b)fluoranthene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(g,h,i)perylene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic PollutantsBis(2-chloroethyl)ether 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 16 U ug/L 16 668/10/2009 13:05 D-072 Priority Organic Pollutants Dimethyl phthalate 11 U ug/L 11 448/10/2009 13:05 D-072 Priority Organic Pollutants N-Nitrosodi-n-propylamine 2.2 U ug/L 2.2 8.78/10/2009 13:05 D-072 Priority Organic Pollutants N-Nitrosodimethylamine 2.2 U ug/L 2.2 8.78/10/2009 13:05 D-072 Priority Organic Pollutants4-Chlorophenyl phenyl ether 2.2 U ug/L 2.2 8.78/10/2009 13:05 D-072 Priority Organic Pollutants Di-n-butyl phthalate 5.5 U ug/L 5.5 228/10/2009 13:05 D-072 Priority Organic Pollutants Diethyl phthalate 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Isophorone 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dichlorophenol 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2-Chlorophenol 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 4-Bromophenyl phenyl ether 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 4-Nitrophenol 16 U ug/L 16 668/10/2009 13:05 D-072 Priority Organic Pollutants Anthracene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(a)anthracene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(k)fluoranthene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Bis(2-chloroisopropyl)ether 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Priority Organic Pollutants Fluoranthene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Hexachlorobenzene 1.1 U ug/L 1.1 4.436Appendix E. (continued)Date Field ID Analysis Component Result Remark Units MDL PQL8/10/2009 13:05 D-072 Priority Organic Pollutants Hexachlorobutadiene 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Priority Organic Pollutants Hexachlorocyclopentadiene 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Priority Organic Pollutants Pentachlorophenol 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dimethylphenol 11 UJ ug/L 11 448/10/2009 13:05 D-072 Priority Organic Pollutants 3,3'-Dichlorobenzidine 44 UJ ug/L 44 1708/10/2009 13:05 D-072 Priority Organic Pollutants Phenol 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 1,2,4-Trichlorobenzene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2,4,6-Trichlorophenol 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Acenaphthylene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Butyl benzyl phthalate 5.5 U ug/L 5.5 228/10/2009 13:05 D-072 Priority Organic Pollutants Hexachloroethane 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Phenanthrene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dinitrotoluene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2,6-Dinitrotoluene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Priority Organic Pollutants Benzidine 110 U ug/L 110 4408/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(a)pyrene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic PollutantsBis(2-chloroethoxy)methane 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Chrysene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants Fluorene 1.1 U ug/L 1.1 4.48/10/2009 13:05 D-072 Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 3.3 U ug/L 3.3 138/10/2009 13:05 D-072 Field Parameter Dissolved Oxygen 6.55 mg/L8/10/2009 13:05 D-072 Field Parameter Specific Conductance 46443 umhos/cm8/10/2009 13:05 D-072 Field Parameter Sample Depth 0.2 m8/10/2009 13:05 D-072 Field Parameter Temperature 31.83 C8/10/2009 13:05 D-072 Field Parameter pH 8.07

# 37 Appendix F. Facility Summary, Efflue nt Limits, and Permit Violations Recorded on Discharge Monitoring Report

# 38 Appendix F. (continued)

# 39 Appendix F. (continued)

# 40 Appendix F. (continued)

# 41 Appendix F. (continued)

# 42 Appendix F. (continued)

# 43 Appendix F. (continued)

# 44 Appendix F. (continued)

# 45 Appendix F. (continued)

# 46 Appendix F. (continued)

# 47 Appendix F. (continued)

# 48 Appendix F. (continued)

# 49 Appendix F. (continued)

# 50 Appendix G. EPA End Sheet

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 0 1 5 9 11 12 0 9 0 8 1 0 18 B 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 0 1 5 9 11 12 0 9 0 8 1 0 18 X 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 0 1 5 9 11 12 0 9 0 8 1 0 18 S 19 S 20 2

66 Remarks Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks 

# The Bioassay of Progress Energy Crystal River Plant units 1, 2, and 3 effluent sampled on August 10, 2009. NPDES #FL0000159.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks



# The Priority Pollutants Analysis of Progress Energy Crystal River
Plant units 1, 2, and 3 efflue nt sampled on August 10, 2009.

NPDES #FL0000159.

Biological Analyses of Progress Energy Crystal River Plant units 1, 2, and 3 effluent sampled on August 10, 2009. NPDES #

FL0000159.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)