This document may not be reproduced, except in full with written permission from DAT Labs

. 

# DAT Reports

**®** 

# Data Analysis Technologies, Inc. 7715 Corporate Blvd. Plain City, OH 43064 800

-733

-8644 

# Sample Analysis Certificate

Client: Ormet Aluminum Date: 5/28/2013 Address:State Route 7 DAT Project ID: 0413050

Hannibal, OH43931 Date Received: 4/30/2013

Attn: Brian Ashbrook Client Project:114

-ICR Analysis: Method 29

- 11 metals, Method 315

-Particulate/MCEM The following samples were received on 4/30/2013: **DAT Sample ID Client Sample ID**  **Date Sampled**  **Matrix** 0413050

-01 Line 3 Run 1 Cartridge 1 4/4/2013 Filter 0413050

-02 Line 3 Run 1 Cartridge 2 4/4/2013 Filter 0413050

-03 Line 3 Run 1 Cartridge 3 4/4/2013 Filter 0413050

-04 Line 3 Run 1 Cartridge 4 4/4/2013 Filter 0413050

-05 Line 3 Run 1 Cartridge 5 4/4/2013 Filter 0413050

-06 Line 3 Run 1 Cartridge 6 4/4/2013 Filter 0413050

-07 Line 3 Run 1 Cartridge 7 4/4/2013 Filter 0413050

-08 Line 3 Run 1 Cartridge 8 4/4/2013 Filter 0413050

-09 Line 2 Run 1 Cartridge 9 4/4/2013 Filter 0413050

- 10 Line 2 Run 1 Cartridge 10 4/4/2013 Filter 0413050

- 11 Line 2 Run 1 Cartridge 11 4/4/2013 Filter 0413050

- 12 Line 2 Run 1 Cartridge 12 4/4/2013 Filter 0413050

- 13 Line 2 Run 1 Cartridge 13 4/4/2013 Filter 0413050

- 14 Line 2 Run 1 Cartridge 14 4/4/2013 Filter 0413050

- 15 Line 2 Run 1 Cartridge 15 4/4/2013 Filter 0413050

- 16 Line 2 Run 1 Cartridge 16 4/4/2013 Filter 

## 0413050

- 17 Line 3 Run 2 Cartridge 17 4/10/2013 Filter 0413050

- 18 Line 3 Run 2 Cartridge 18 4/10/2013 Filter 0413050

- 19 Line 3 Run 2 Cartridge 19 4/10/2013 Filter 0413050

-20 Line 3 Run 2 Cartridge 20 4/10/2013 Filter 0413050

-21 Line 3 Run 2 Cartridge 21 4/10/2013 Filter 0413050

-22 Line 3 Run 2 Cartridge 22 4/10/2013 Filter

0413050_ Page 1 of 123.This document may not be reproduced, except in full with written permission from DAT Labs

.



## 0413050

-23 Line 3 Run 2 Cartridge 23 4/10/2013 Filter 0413050

-24 Line 3 Run 2 Cartridge 24 4/10/2013 Filter 0413050

-25 Line 2 Run 2 Cartridge 25 4/10/2013 Filter 0413050

-26 Line 2 Run 2 Cartridge 26 4/10/2013 Filter 0413050

-27 Line 2 Run 2 Cartridge 27 4/10/2013 Filter 0413050

-28 Line 2 Run 2 Cartridge 28 4/10/2013 Filter 0413050

-29 Line 2 Run 2 Cartridge 29 4/10/2013 Filter 0413050

-30 Line 2 Run 2 Cartridge 30 4/10/2013 Filter 0413050

-31 Line 2 Run 2 Cartridge 31 4/10/2013 Filter 0413050

-32 Line 2 Run 2 Cartridge 32 4/10/2013 Filter 0413050

-33 Line 3 Run 3 Cartridge 33 4/24/2013 Filter 0413050

-34 Line 3 Run 3 Cartridge 34 4/24/2013 Filter 0413050

-35 Line 3 Run 3 Cartridge 35 4/24/2013 Filter 0413050

-36 Line 3 Run 3 Cartridge 36 4/24/2013 Filter 0413050

-37 Line 3 Run 3 Cartridge 37 4/24/2013 Filter 0413050

-38 Line 3 Run 3 Cartridge 38 4/24/2013 Filter 0413050

-39 Line 3 Run 3 Cartridge 39 4/24/2013 Filter 0413050

-40 Line 3 Run 3 Cartridge 40 4/24/2013 Filter 0413050

-41 Line 2 Run 3 Cartridge 41 4/24/2013 Filter 0413050

-42 Line 2 Run 3 Cartridge 42 4/24/2013 Filter 0413050

-43 Line 2 Run 3 Cartridge 43 4/24/2013 Filter 0413050

-44 Line 2 Run 3 Cartridge 44 4/24/2013 Filter 0413050

-45 Line 2 Run 3 Cartridge 45 4/24/2013 Filter 0413050

-46 Line 2 Run 3 Cartridge 46 4/24/2013 Filter 0413050

-47 Line 2 Run 3 Cartridge 47 4/24/2013 Filter 0413050

-48 Line 2 Run 3 Cartridge 48 4/24/2013 Filter

**Results:** See attached summary. **QC:** Met the criteria for the method.

Reviewed and approved for release by: 

### Date:5/28/2013 

## Ronald K. Mitchum, Ph.D. President, DAT

0413050_ Page 2 of 123.

## 0413050_ Page 3 of 123.

# DAT SAMPLE RECEIVING

7715 Corporate Blvd. Plain City,OH 43064.



## Project Number: **0413050**

**Date Received:** 4/30/2013 **Client Name:** Ormet Primary Aluminum **Tracking number:** 799632096529 **Carrier:** Fed-X overnight **Analysis:** M29,M315 **Package Temp:** 21.8°C (Amb-Room) **COC:** check if COC from client

**Sample Information Custody Seals ?:**  Yes



## Client ID: Laboratory ID Date Matrix: Container: Comment: Sample Record number Line 3 Run 1 Cartridge 1 0413050-01 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 1 Cartridge 2 0413050-02 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 1 Cartridge 3 0413050-03 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 1 Cartridge 4 0413050-04 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 1 Cartridge 5 0413050-05 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 1 Cartridge 6 0413050-06 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 1 Cartridge 7 0413050-07 4/4/2013 Filter Metal Cartridge Nozzle fell off 6 E +

0413050 4/30/2013 10:57:42 AM **Laboratory Receiving Initials**



## 0413050_ Page 4 of 123.

# DAT SAMPLE RECEIVING

7715 Corporate Blvd. Plain City,OH 43064.



## Project Number: **0413050**

Client ID: Laboratory ID Date Matrix: Container: Comment: Sample Record number Line 3 Run 1 Cartridge 8 0413050-08 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 9 0413050-09 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 10 0413050-10 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 11 0413050-11 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 12 0413050-12 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 13 0413050-13 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 14 0413050-14 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 15 0413050-15 4/4/2013 Filter Metal Cartridge 6 E + Line 2 Run 1 Cartridge 16 0413050-16 4/4/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 17 0413050-17 4/10/2013 Filter Metal Cartridge 6 E +

0413050 4/30/2013 10:57:42 AM **Laboratory Receiving Initials**



## 0413050_ Page 5 of 123.

# DAT SAMPLE RECEIVING

7715 Corporate Blvd. Plain City,OH 43064.



## Project Number: **0413050**

Client ID: Laboratory ID Date Matrix: Container: Comment: Sample Record number Line 3 Run 2 Cartridge 18 0413050-18 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 19 0413050-19 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 20 0413050-20 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 21 0413050-21 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 22 0413050-22 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 23 0413050-23 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 2 Cartridge 24 0413050-24 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 25 0413050-25 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 26 0413050-26 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 27 0413050-27 4/10/2013 Filter Metal Cartridge 6 E +

0413050 4/30/2013 10:57:42 AM **Laboratory Receiving Initials**



## 0413050_ Page 6 of 123.

# DAT SAMPLE RECEIVING

7715 Corporate Blvd. Plain City,OH 43064.



## Project Number: **0413050**

Client ID: Laboratory ID Date Matrix: Container: Comment: Sample Record number Line 2 Run 2 Cartridge 28 0413050-28 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 29 0413050-29 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 30 0413050-30 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 31 0413050-31 4/10/2013 Filter Metal Cartridge 6 E + Line 2 Run 2 Cartridge 32 0413050-32 4/10/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 33 0413050-33 4/24/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 34 0413050-34 4/24/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 35 0413050-35 4/24/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 36 0413050-36 4/24/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 37 0413050-37 4/24/2013 Filter Metal Cartridge 6 E +

0413050 4/30/2013 10:57:42 AM **Laboratory Receiving Initials**



## 0413050_ Page 7 of 123.

# DAT SAMPLE RECEIVING

7715 Corporate Blvd. Plain City,OH 43064.



## Project Number: **0413050**

Client ID: Laboratory ID Date Matrix: Container: Comment: Sample Record number Line 3 Run 3 Cartridge 38 0413050-38 4/24/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 39 0413050-39 4/24/2013 Filter Metal Cartridge 6 E + Line 3 Run 3 Cartridge 40 0413050-40 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 41 0413050-41 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 42 0413050-42 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 43 0413050-43 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 44 0413050-44 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 45 0413050-45 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 46 0413050-46 4/24/2013 Filter Metal Cartridge 6 E + Line 2 Run 3 Cartridge 47 0413050-47 4/24/2013 Filter Metal Cartridge 6 E +

0413050 4/30/2013 10:57:42 AM **Laboratory Receiving Initials**



## 0413050_ Page 8 of 123.

# DAT SAMPLE RECEIVING

7715 Corporate Blvd. Plain City,OH 43064.



## Project Number: **0413050**

Client ID: Laboratory ID Date Matrix: Container: Comment: Sample Record number Line 2 Run 3 Cartridge 48 0413050-48 4/24/2013 Filter Metal Cartridge 6 E +

0413050 4/30/2013 10:57:42 AM **Laboratory Receiving Initials**



## 0413050_ Page 9 of 123.

# EPA Method **29 :**  **Multi**

**- Metals** 

A stack sample is withdrawn isokinetically from the source, particulate emissions are collected in the probe and on a heated filter, and gaseous emissions are then collected in an aqueous acidic solution of hydrogen peroxide (analyzed for all metals including Hg) and an aqueous acidic solution of potassium permanganate (analyzed only for Hg). The recovered samples are digested, and appropriate fractions are analyzed for Hg by cold vapor atomic absorption spectroscopy (CVAAS) and for Sb, As, Ba, Be, Cd, Cr, Co, Cu, Pb, Mn, Ni, P, Se, Ag, Tl, and Zn by inductively coupled argon plasma emission spectroscopy



## 0413050_ Page 10 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 1
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-01 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 6.17 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.75 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 14.35 Manganese 0.55 1.25 

### 0.91 J Nickel 0.40 1.25 

### 7.35 Selenium 1.50 5.00 

### 5.45 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 11 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 2
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-02 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.91 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.62 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 11.93 Manganese 0.55 1.25 

### 0.86 J Nickel 0.40 1.25 

### 7.56 Selenium 1.50 5.00 

### 3.71 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 12 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 3
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-03 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.95 Arsenic 1.43 5.00 

### 1.47 J Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.71 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 14.08 Manganese 0.55 1.25 

### 0.81 J Nickel 0.40 1.25 

### 6.17 Selenium 1.50 5.00 

### 3.32 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 13 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 4
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-04 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.13 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.58 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 11.48 Manganese 0.55 1.25 

### 0.77 J Nickel 0.40 1.25 

### 3.42 Selenium 1.50 5.00 

### ND 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 14 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 5
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-05 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.61 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.73 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 13.06 Manganese 0.55 1.25 

### 1.04 J Nickel 0.40 1.25 

### 3.98 Selenium 1.50 5.00 

### 4.59 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 15 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 6
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-06 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.61 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.06 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.57 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 9.98 Manganese 0.55 1.25 

### 0.62 J Nickel 0.40 1.25 

### 4.51 Selenium 1.50 5.00 

### 2.91 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 16 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 7
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-07 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.88 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.05 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.62 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 12.42 Manganese 0.55 1.25 

### 0.93 J Nickel 0.40 1.25 

### 2.90 Selenium 1.50 5.00 

### 2.60 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 17 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 8
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-08 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.18 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.64 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 14.51 Manganese 0.55 1.25 

### 0.76 J Nickel 0.40 1.25 

### 3.56 Selenium 1.50 5.00 

### 3.84 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 18 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 9
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-09 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.17 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.61 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 13.46 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.86 Selenium 1.50 5.00 

### 2.61 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 19 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 10
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-10 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.86 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.63 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 14.53 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.03 Selenium 1.50 5.00 

### 4.28 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 20 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 11
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-11 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.75 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.60 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 13.71 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.18 Selenium 1.50 5.00 

### 3.72 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 21 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 12
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-12 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.88 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.61 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 13.34 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.35 Selenium 1.50 5.00 

### 2.28 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 22 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 13
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-13 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.97 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.58 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 13.11 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 1.27 Selenium 1.50 5.00 

### 3.32 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 23 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 14
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-14 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.16 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.58 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 12.40 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 1.33 Selenium 1.50 5.00 

### 2.54 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 24 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 15
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-15 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.47 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.63 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 14.92 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 1.56 Selenium 1.50 5.00 

### 3.70 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 25 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 1 Cartridge 16
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-16 **Sample Date:** 4/4/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.93 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.62 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 14.36 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 1.25 J Selenium 1.50 5.00 

### 1.70 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050R_Page 26 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 17
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-17 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 8.42 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.78 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 22.21 Manganese 0.55 1.25 

### 0.91 J Nickel 0.40 1.25 

### 7.01 Selenium 1.50 5.00 

### 6.18 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 27 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 18
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-18 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 7.68 Arsenic 1.43 5.00 

### 1.61 J Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.71 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 19.12 Manganese 0.55 1.25 

### 0.72 J Nickel 0.40 1.25 

### 8.92 Selenium 1.50 5.00 

### 4.71 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 28 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 19
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-19 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 7.63 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.74 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 21.18 Manganese 0.55 1.25 

### 0.74 J Nickel 0.40 1.25 

### 7.27 Selenium 1.50 5.00 

### 4.78 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 29 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 20
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-20 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 6.03 Arsenic 1.43 5.00 

### 1.43 J Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.61 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 17.95 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.75 Selenium 1.50 5.00 

### 1.88 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 30 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 21
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-21 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.45 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.57 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 15.98 Manganese 0.55 1.25 

### 0.56 J Nickel 0.40 1.25 

### 3.01 Selenium 1.50 5.00 

### 2.83 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 31 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 22
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-22 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.66 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.56 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 17.34 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 4.05 Selenium 1.50 5.00 

### 4.24 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 32 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 23
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-23 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.80 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.05 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.56 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 17.02 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.50 Selenium 1.50 5.00 

### 3.43 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 33 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 24
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-24 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 6.21 Arsenic 1.43 5.00 

### 1.63 J Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.55 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 16.04 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.70 Selenium 1.50 5.00 

### 3.67 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 34 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 25
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-25 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.21 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.62 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 16.39 Manganese 0.55 1.25 

### 0.71 J Nickel 0.40 1.25 

### 4.57 Selenium 1.50 5.00 

### 6.65 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 35 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 26
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-26 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.97 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.71 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 18.46 Manganese 0.55 1.25 

### 0.68 J Nickel 0.40 1.25 

### 3.44 Selenium 1.50 5.00 

### 9.41 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 36 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 27
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-27 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.54 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.65 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 17.92 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.49 Selenium 1.50 5.00 

### 5.24 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 37 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 28
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-28 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 6.24 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.63 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 17.55 Manganese 0.55 1.25 

### 0.61 J Nickel 0.40 1.25 

### 3.94 Selenium 1.50 5.00 

### 8.81 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 38 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 29
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-29 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.90 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.58 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 19.92 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.09 Selenium 1.50 5.00 

### 9.70 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 39 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 30
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-30 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 6.00 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.57 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 16.56 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.95 Selenium 1.50 5.00 

### 1.86 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 40 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 31
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-31 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 6.96 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.65 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 18.50 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.90 Selenium 1.50 5.00 

### 5.29 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 41 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 2 Cartridge 32
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-32 **Sample Date:** 4/10/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 5.66 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.65 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 18.40 Manganese 0.55 1.25 

### 0.89 J Nickel 0.40 1.25 

### 3.36 Selenium 1.50 5.00 

### 4.26 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 42 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 33
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-33 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.81 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.05 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.70 Cobalt 0.73 2.50 

### 2.10 J Lead 1.80 5.00 

### 9.98 Manganese 0.55 1.25 

### 0.79 J Nickel 0.40 1.25 

### 7.89 Selenium 1.50 5.00 

### 2.78 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 43 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 34
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-34 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.16 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.06 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.64 Cobalt 0.73 2.50 

### 1.78 J Lead 1.80 5.00 

### 8.99 Manganese 0.55 1.25 

### 2.08 Nickel 0.40 1.25 

### 7.88 Selenium 1.50 5.00 

### ND 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 44 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 35
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-35 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.25 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.67 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 9.78 Manganese 0.55 1.25 

### 1.21 J Nickel 0.40 1.25 

### 5.58 Selenium 1.50 5.00 

### ND 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 45 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 36
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-36 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.01 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.62 Cobalt 0.73 2.50 

### 0.73 J Lead 1.80 5.00 

### 6.79 Manganese 0.55 1.25 

### 1.35 Nickel 0.40 1.25 

### 3.08 Selenium 1.50 5.00 

### 2.00 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 46 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 37
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-37 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.84 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.82 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 10.24 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 4.11 Selenium 1.50 5.00 

### 6.10 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 47 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 38
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-38 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.10 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.05 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.85 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 11.75 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 6.01 Selenium 1.50 5.00 

### 4.87 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 48 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 39
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-39 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.64 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.09 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.83 Cobalt 0.73 2.50 

### 1.07 J Lead 1.80 5.00 

### 10.54 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 13.46 Selenium 1.50 5.00 

### 6.54 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 49 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 40
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-40 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.27 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.05 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.78 Cobalt 0.73 2.50 

### 0.97 J Lead 1.80 5.00 

### 11.33 Manganese 0.55 1.25 

### 0.85 J Nickel 0.40 1.25 

### 6.70 Selenium 1.50 5.00 

### 3.31 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 50 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 41
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-41 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.10 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.72 Cobalt 0.73 2.50 

### 1.02 J Lead 1.80 5.00 

### 9.42 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 4.85 Selenium 1.50 5.00 

### 1.76 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 51 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 42
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-42 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.49 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.72 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 8.36 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.97 Selenium 1.50 5.00 

### 3.20 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 52 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 43
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-43 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 1.50 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.67 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 5.95 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.57 Selenium 1.50 5.00 

### 2.09 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 53 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 44
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-44 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 1.75 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.64 Cobalt 0.73 2.50 

### 1.48 J Lead 1.80 5.00 

### 6.27 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.76 Selenium 1.50 5.00 

### ND 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 54 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 45
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-45 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.44 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.69 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 9.00 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.01 Selenium 1.50 5.00 

### 2.22 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 55 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 46
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-46 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 3.41 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.72 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 10.76 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.82 Selenium 1.50 5.00 

### 2.08 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 56 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 47
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-47 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.43 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.03 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.74 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 11.05 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 3.47 Selenium 1.50 5.00 

### 4.30 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 57 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 2 Run 3 Cartridge 48
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-48 **Sample Date:** 4/24/2013 **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.21 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.75 Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 8.59 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### 2.50 Selenium 1.50 5.00 

### ND 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 58 of 123.

# EPA Method **29 :**  **QC Summary** 

**Summary:** A stack sample is withdrawn isokinetically from the source, particulate emissions are collected in the probe and on a heated filter, and gaseous emissions are then collected in an aqueous acidic solution of hydrogen peroxide (analyzed for all metals including Hg) and an aqueous acidic solution of potassium permanganate (analyzed only for Hg). The recovered samples are digested, and appropriate fractions are analyzed for Hg by cold vapor atomic absorption spectroscopy (CVAAS) and for Sb, As, Ba, Be, Cd, Cr, Co, Cu, Pb, Mn, Ni, P, Se, Ag, Tl, and Zn by inductively coupled argon plasma emission spectroscopy
**QC:** Matrix Blank

-Matrix such as hydrogen peroxide, nitric acid and permanganate

Used to determine if any interferences are present in the associated blank
LCS

-laboratory control spike ( 80

- 120%R) Used to access the digestion and instrument suitability for measurement PDS

- Post digestion Spike(80

- 120%R) Use to determine if any bias is introduced by the sample



## 0413050_ Page 59 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.**
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-MB **Sample Date:** NA **Preparation Date:** 4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.59 J Arsenic 1.43 5.00 

### 1.54 J Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### 0.19 J Cobalt 0.73 2.50 

### ND Iron 1.80 5.00 

### 7.44 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### ND Selenium 1.50 5.00 

### 1.50 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 60 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.**
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-MB2 **Sample Date:** NA **Preparation Date:** 4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 4.94 Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### ND Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### ND Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 5.18 Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### ND Selenium 1.50 5.00 

### 1.90 J 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 61 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.**
**Site:** Ormet Primary Aluminum **Lab Sample ID: Cartridge:**  0413050-MB3 **Sample Date:** NA **Preparation Date:** 4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train



### Analyte: MDL, ug LOQ, ug 

### Total ug **Q**
Antimony 1.30 3.00 

### 2.26 J Arsenic 1.43 5.00 

### ND Beryllium 0.03 0.13 

### 0.04 J Cadmium 0.20 0.50 

### ND Chromium 0.19 0.50 

### ND Cobalt 0.73 2.50 

### ND Lead 1.80 5.00 

### 3.84 J Manganese 0.55 1.25 

### ND Nickel 0.40 1.25 

### ND Selenium 1.50 5.00 

### ND 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 62 of 123.

### Client: Ormet Primary Aluminum

**Sample ID** 0413050 LCS **Analysis Date:** 5/21/2013 **Project #:** 0413050



## Analyte **Amt Found, ug/L**  **Amt Spiked,**

**ug/L % Rec**  **QC Limits** Antimony 1017.99 1000 102 80-120 Arsenic 956.51 1000 96 80-120 Beryllium 48.24 50 96 80-120 Cadmium 437.94 500 88 80-120 Chromium 181.25 200 91 80-120 Cobalt 475.47 500 95 80-120 Iron 1044.90 1000 104 80-120 Manganese 472.84 500 95 80-120 Nickel 470.49 500 94 80-120 Selenium 969.14 1000 97 80-120

*Outside of QC limits 

# Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064


# LCS Summary

0413050_ Page 63 of 123.

### Client: Ormet Primary Aluminum

**Sample ID** 0413050 LCS **Analysis Date:** 5/22/2013 **Project #:** 0413050



## Analyte **Amt Found, ug/L**  **Amt Spiked,**

**ug/L % Rec**  **QC Limits** Antimony 1224.05 1000 122 80-120 Arsenic 1077.61 1000 108 80-120 Beryllium 48.40 50 97 80-120 Cadmium 491.21 500 98 80-120 Chromium 190.29 200 95 80-120 Cobalt 490.40 500 98 80-120 Lead 1195.55 1000 120 80-120 Manganese 509.69 500 102 80-120 Nickel 514.81 500 103 80-120 Selenium 1065.33 1000 107 80-120

*Outside of QC limits 

# Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064


# LCS Summary

0413050_ Page 64 of 123.

### Client: Ormet Primary Aluminum

**Sample ID** 0413050 LCS3 **Analysis Date:** 5/23/2013 **Project #:** 0413050



## Analyte **Amt Found, ug/L**  **Amt Spiked,**

**ug/L % Rec**  **QC Limits** Antimony 1089.50 1000 109 80-120 Arsenic 963.38 1000 96 80-120 Beryllium 50.91 50 102 80-120 Cadmium 437.31 500 87 80-120 Chromium 199.71 200 100 80-120 Cobalt 534.55 500 107 80-120 Lead 1087.94 1000 109 80-120 Manganese 553.34 500 111 80-120 Nickel 543.57 500 109 80-120 Selenium 996.99 1000 100 80-120

*Outside of QC limits 

# Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064


# LCS Summary

0413050_ Page 65 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 1 Cartridge 7
**Site:** Ormet Primary Aluminum **Lab Sample ID: FH1:**  0413050-07 DUP **Sample Date:** 4/4/2013 **FH2: Preparation Date:**  4/30/2013 **Analysis Date:** 5/21/2013 **Matrix:** Train

**Analyte:** MDL, ug LOQ, ug **Front Half Total ug**  **Q**
Antimony 1.30 3.00 **3.23** Arsenic 1.43 5.00 **ND** Beryllium 0.03 0.13 **0.04** J Cadmium 0.20 0.50 **ND** Chromium 0.19 0.50 **0.61** Cobalt 0.73 2.50 **ND** Iron 1.80 5.00 **16.43** Manganese 0.55 1.25 **0.95** J Nickel 0.40 1.25 **2.85** Selenium 1.63 5.00 **2.82** J 

### Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 66 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 2 Cartridge 23
**Site:** Ormet Primary Aluminum **Lab Sample ID: FH1:**  0413050-23 DUP **Sample Date:** 4/10/2013 **FH2: Preparation Date:**  4/30/2013 **Analysis Date:** 5/22/2013 **Matrix:** Train

**Analyte:** MDL, ug LOQ, ug **Front Half Total ug**  **Q**
Antimony 1.30 3.00 **5.76** Arsenic 1.43 5.00 **ND** Beryllium 0.03 0.13 **0.06** J Cadmium 0.20 0.50 **ND** Chromium 0.19 0.50 **0.59** Cobalt 0.73 2.50 **ND** Lead 1.80 5.00 **17.81** Manganese 0.55 1.25 **0.55** J Nickel 0.40 1.25 **3.70** Selenium 1.63 5.00 **3.09** J 

### Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 67 of 123.**Client:** Ormet Primary Aluminum **Project #:** 0413050

**Client Run/Test No.** Line 3 Run 3 Cartridge 38
**Site:** Ormet Primary Aluminum **Lab Sample ID: FH1:**  0413050-38 DUP **Sample Date:** 4/24/2013 **FH2: Preparation Date:**  4/30/2013 **Analysis Date:** 5/23/2013 **Matrix:** Train

**Analyte:** MDL, ug LOQ, ug **Front Half Total ug**  **Q**
Antimony 1.30 3.00 **3.28** Arsenic 1.43 5.00 **ND** Beryllium 0.03 0.13 **0.05** J Cadmium 0.20 0.50 **ND** Chromium 0.19 0.50 **0.80** Cobalt 0.73 2.50 **ND** Lead 1.80 5.00 **10.70** Manganese 0.55 1.25 **ND** Nickel 0.40 1.25 **5.69** Selenium 1.63 5.00 **5.41** 

### Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 

# Sample Analysis Certificate

0413050_ Page 68 of 123.

### Client: Ormet Primary Aluminum

**Sample ID** 0413050-15 PDS **Analysis Date:** 5/21/2013 **Project #:** 0413050



### Analyte **Amt Found, ug/L**  **Amt Spiked,**

**ug/L Sample Amt,** 

**ug/L Q**  **% Rec QC Limits**  Antimony 1116.47 1000 89.336 

### 103 80-120 Arsenic 899.79 1000 -23.204 

### 92 80-120 Beryllium 45.71 50 0.314 

### 91 80-120 Cadmium 471.00 500 -18.193 

### 98 80-120 Chromium 226.62 200 12.566 

### 107 80-120 Cobalt 517.59 500 -15.508 

### 107 80-120 Iron 1214.44 1000 196.648 

### 102 80-120 Manganese 514.88 500 9.215 

### 101 80-120 Nickel 689.42 500 31.245 

### 132 80-120 Selenium 845.10 1000 73.978 

### 77 80-120

*Outside of QC limits 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064


## PDS Summary



## 0413050_ Page 69 of 123.

### Client: Ormet Primary Aluminum

**Sample ID** 0413050-30 PDS **Analysis Date:** 5/22/2013 **Project #:** 0413050



### Analyte **Amt Found, ug/L**  **Amt Spiked,**

**ug/L Sample Amt,** 

**ug/L Q**  **% Rec QC Limits**  Antimony 1084.59 1000 120.087 

### 96 80-120 Arsenic 829.35 1000 -30.486 

### 86 80-120 Beryllium 38.29 50 0.765 

### 75 80-120 Cadmium 455.84 500 -16.703 

### 95 80-120 Chromium 195.44 200 11.306 

### 92 80-120 Cobalt 436.87 500 6.391 

### 86 80-120 Lead 1158.24 1000 331.224 

### 83 80-120 Manganese 417.37 500 9.696 

### 82 80-120 Nickel 610.25 500 59.049 

### 110 80-120 Selenium 786.32 1000 37.126 

### 75 80-120

*Outside of QC limits 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064


## PDS Summary



## 0413050_ Page 70 of 123.

### Client: Ormet Primary Aluminum

**Sample ID** 0413050-45 PDS **Analysis Date:** 5/23/2013 **Project #:** 0413050



### Analyte **Amt Found, ug/L**  **Amt Spiked,**

**ug/L Sample Amt,** 

**ug/L Q**  **% Rec QC Limits**  Antimony 901.19 1000 48.794 

### 85 80-120 Arsenic 696.74 1000 -42.378 

### 74 80-120 Beryllium 37.79 50 0.899 

### 74 80-120 Cadmium 389.22 500 -4.307 

### 79 80-120 Chromium 198.91 200 13.750 

### 93 80-120 Cobalt 412.59 500 11.826 

### 80 80-120 Lead 941.47 1000 180.002 

### 76 80-120 Manganese 432.68 500 6.820 

### 85 80-120 Nickel 614.03 500 60.239 

### 111 80-120 Selenium 714.33 1000 44.360 

### 67 80-120

*Outside of QC limits 

## Method 29 Metals Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064


## PDS Summary



## 0413050_ Page 71 of 123.

# Method **29/ 7470A/**  **7471B Cold Vapor mercury**

This method uses cold

-vapor atomic absorption and is based on the absorption of radiation at the 253.7

- nm wavelength by mercury vapor. The mercury is reduced to the elemental state and aerated from solution in a closed system. The mercury vapor passes through a cell positioned in the light path of an atomic absorption spectrophotometer. Absorbance (peak height) is measured as a function of mercury concentration.



## 0413050_ Page 72 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 1**  Cartridge Filter Filter 0413050-1 0.003 0.0002 0.000354 J

**Total Hg in Entire Train, ug** 0.000354
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 73 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 2**  Cartridge Filter Filter 0413050-2 0.003 0.0002 0.000615 J

**Total Hg in Entire Train, ug** 0.000615
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 74 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 3**  Cartridge Filter Filter 0413050-3 0.003 0.0002 0.000409 J

**Total Hg in Entire Train, ug** 0.000409
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 75 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 4**  Cartridge Filter Filter 0413050-4 0.003 0.0002 0.000399 J

**Total Hg in Entire Train, ug** 0.000399
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 76 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 5**  Cartridge Filter Filter 0413050-5 0.003 0.0002 0.000484 J

**Total Hg in Entire Train, ug** 0.000484
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 77 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 6**  Cartridge Filter Filter 0413050-6 0.003 0.0002 0.000425 J

**Total Hg in Entire Train, ug** 0.000425
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 78 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 7**  Cartridge Filter Filter 0413050-7 0.003 0.0002 0.000507 J

**Total Hg in Entire Train, ug** 0.000507
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 79 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 1 Cartridge 8**  Cartridge Filter Filter 0413050-8 0.003 0.0002 0.000543 J

**Total Hg in Entire Train, ug** 0.000543
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 80 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 9**  Cartridge Filter Filter 0413050-9 0.003 0.0002 0.000263 J

**Total Hg in Entire Train, ug** 0.000263
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 81 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 10**  Cartridge Filter Filter 0413050-10 0.003 0.0002 0.000328 J

**Total Hg in Entire Train, ug** 0.000328
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 82 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 11**  Cartridge Filter Filter 0413050-11 0.003 0.0002 0.000211 J

**Total Hg in Entire Train, ug** 0.000211
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 83 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 12**  Cartridge Filter Filter 0413050-12 0.003 0.0002 0.000375 J

**Total Hg in Entire Train, ug** 0.000375
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 84 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 13**  Cartridge Filter Filter 0413050-13 0.003 0.0002 0.001468 J

**Total Hg in Entire Train, ug** 0.001468
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 85 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 14**  Cartridge Filter Filter 0413050-14 0.003 0.0002 0.000134 J

**Total Hg in Entire Train, ug** 0.000134
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 86 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 15**  Cartridge Filter Filter 0413050-15 0.003 0.0002 0.000325 J

**Total Hg in Entire Train, ug** 0.000325
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 87 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/4/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 1 Cartridge 16**  Cartridge Filter Filter 0413050-16 0.003 0.0002 0.000270 J

**Total Hg in Entire Train, ug** 0.000270
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 88 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 17**  Cartridge Filter Filter 0413050-17 0.003 0.0002 0.000044 J

**Total Hg in Entire Train, ug** 0.000044
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 89 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 18**  Cartridge Filter Filter 0413050-18 0.003 0.0002 0.000429 J

**Total Hg in Entire Train, ug** 0.000429
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 90 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 19**  Cartridge Filter Filter 0413050-19 0.003 0.0002 0.000197 J

**Total Hg in Entire Train, ug** 0.000197
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 91 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 20**  Cartridge Filter Filter 0413050-20 0.003 0.0002 0.000125 J

**Total Hg in Entire Train, ug** 0.000125
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 92 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 21**  Cartridge Filter Filter 0413050-21 0.003 0.0002 0.000159 J

**Total Hg in Entire Train, ug** 0.000159
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 93 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 22**  Cartridge Filter Filter 0413050-22 0.003 0.0002 0.000172 J

**Total Hg in Entire Train, ug** 0.000172
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 94 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 23**  Cartridge Filter Filter 0413050-23 0.003 0.0002 0.000120 J

**Total Hg in Entire Train, ug** 0.000120
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 95 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 2 Cartridge 24**  Cartridge Filter Filter 0413050-24 0.003 0.0002 0.000176 J

**Total Hg in Entire Train, ug** 0.000176
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 96 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 25**  Cartridge Filter Filter 0413050-25 0.003 0.0002 0.000507 J

**Total Hg in Entire Train, ug** 0.000507
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 97 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 26**  Cartridge Filter Filter 0413050-26 0.003 0.0002 0.000131 J

**Total Hg in Entire Train, ug** 0.000131
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 98 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 27**  Cartridge Filter Filter 0413050-27 0.003 0.0002 0.000096 J

**Total Hg in Entire Train, ug** 0.000096
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 99 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 28**  Cartridge Filter Filter 0413050-28 0.003 0.0002 0.001188 J

**Total Hg in Entire Train, ug** 0.001188
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 100 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 29**  Cartridge Filter Filter 0413050-29 0.003 0.0002 0.000265 J

**Total Hg in Entire Train, ug** 0.000265
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 101 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 30**  Cartridge Filter Filter 0413050-30 0.003 0.0002 0.000277 J

**Total Hg in Entire Train, ug** 0.000277
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 102 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 31**  Cartridge Filter Filter 0413050-31 0.003 0.0002 0.000111 J

**Total Hg in Entire Train, ug** 0.000111
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 103 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/10/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 2 Cartridge 32**  Cartridge Filter Filter 0413050-32 0.003 0.0002 0.000169 J

**Total Hg in Entire Train, ug** 0.000169
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 104 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 33**  Cartridge Filter Filter 0413050-33 0.003 0.0002 0.000161 J

**Total Hg in Entire Train, ug** 0.000161
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 105 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 34**  Cartridge Filter Filter 0413050-34 0.003 0.0002 0.000264 J

**Total Hg in Entire Train, ug** 0.000264
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 106 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 35**  Cartridge Filter Filter 0413050-35 0.003 0.0002 0.000347 J

**Total Hg in Entire Train, ug** 0.000347
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 107 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 36**  Cartridge Filter Filter 0413050-36 0.003 0.0002 0.000246 J

**Total Hg in Entire Train, ug** 0.000246
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 108 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 37**  Cartridge Filter Filter 0413050-37 0.003 0.0002 0.000256 J

**Total Hg in Entire Train, ug** 0.000256
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 109 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 38**  Cartridge Filter Filter 0413050-38 0.003 0.0002 0.000327 J

**Total Hg in Entire Train, ug** 0.000327
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 110 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 39**  Cartridge Filter Filter 0413050-39 0.003 0.0002 0.000266 J

**Total Hg in Entire Train, ug** 0.000266
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 111 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 3 Run 3 Cartridge 40**  Cartridge Filter Filter 0413050-40 0.003 0.0002 0.000325 J

**Total Hg in Entire Train, ug** 0.000325
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 112 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 41**  Cartridge Filter Filter 0413050-41 0.003 0.0002 0.000221 J

**Total Hg in Entire Train, ug** 0.000221
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 113 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 42**  Cartridge Filter Filter 0413050-42 0.003 0.0002 0.000313 J

**Total Hg in Entire Train, ug** 0.000313
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 114 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 43**  Cartridge Filter Filter 0413050-43 0.003 0.0002 0.000270 J

**Total Hg in Entire Train, ug** 0.000270
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 115 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 44**  Cartridge Filter Filter 0413050-44 0.003 0.0002 0.000096 J

**Total Hg in Entire Train, ug** 0.000096
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 116 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 45**  Cartridge Filter Filter 0413050-45 0.003 0.0002 0.000236 J

**Total Hg in Entire Train, ug** 0.000236
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 117 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 46**  Cartridge Filter Filter 0413050-46 0.003 0.0002 0.000314 J

**Total Hg in Entire Train, ug** 0.000314
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 118 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 47**  Cartridge Filter Filter 0413050-47 0.003 0.0002 0.000101 J

**Total Hg in Entire Train, ug** 0.000101
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 119 of 123.**Client:** Ormet Primary Aluminum **Client Project: DAT Project:**  0413050 **Date Sampled:** 4/24/2013 **Date Received:** 4/30/2013 **Date Prepped:** 4/30/2013 **Date Analyzed:** 5/23/2013 **Analyst:** JK

**Client ID: DAT ID:**  **PQL, ug MDL, ug**  **Total Hg in Sample, ug**  **Q Line 2 Run 3 Cartridge 48**  Cartridge Filter Filter 0413050-48 0.003 0.0002 0.000361 J

**Total Hg in Entire Train, ug** 0.000361
ND = Not detected at the Method Detection Limit shown. J = Value below Practical Quantitation Limit shown. D = Value calculated from a dilution. 114-ICR 

### Data Analysis Technologies, Inc.

**Method 29 / Mercury Data Summary Table**  Plain City, OH 43064 7715 Corporate Boulevard



## 0413050_ Page 120 of 123.

# QC Summary

**Method 29/**  **7471B Cold Vapor mercury**



## 0413050_ Page 121 of 123.**Client:** 

### Ormet Primary Aluminum

**Client Project:** 

### 114-ICR **DAT Project:** 

### 0413050 **Date Prepped:** 

### 4/30/2013 **Date Analyzed:** 

### 5/23/2013 **Analyst:** 

### JK

**Measured Hg conc., ug/L**  **Hg**

**Added, ug/L**  **PQL, ug/L** 

### % Rec **%RPD %D**  Method Blank MB1 ND 0.05 

### Method Blank MB2 ND 0.05 

### Method Blank MB3 ND 0.05 

### Laboratory Spike LCS1 10.04 

### 10 100 Laboratory Spike LCS2 10.25 

### 10 103 Laboratory Spike LCS3 10.08 

### 10 101 Matrix Spike 0413050-10 ms 11.45 

### 10 114 Matrix Spike Dup 0413050-10 ms d 11.75 

### 10 117 2.59 Matrix Spike 0413050-30 ms 11.27 

### 10 113 Matrix Spike Dup 0413050-30 ms d 11.74 

### 10 117 4.09 Matrix Spike 0413050-48 ms 11.72 

### 10 117 Matrix Spike Dup 0413050-48 ms d 11.66 

### 10 117 0.51 Duplicate 0413050-1 dup 0.0084 

### * Duplicate 0413050-20 dup 0.002 

### *

ND = Not detected at the Practical Quantitation Limit shown. * RPD is not calculated if sample and/or duplicate results are less than 2 times the PQL. 

## Method 29 / Mercury **Data Analysis Technologies, Inc.** 7715 Corporate Boulevard Plain City, OH 43064 

## QC Summary Table



## 0413050_ Page 122 of 123.**DAT Reports ®** 

**Client:** Ormet **Client Project:** 114-ICR **DAT Project:** 0513004

**Date Received:** 4/30/2013 **Date Analyzed:** 5/2-16/2013 **Analyst:** JK

**Client ID DAT ID**  **Date Sampled Filter**  **Particulate, mg MCEM, mg**  **PQL, mg** Line 3 Run 1 Cartridge 1 0413050-01 4/4/13 3.1 0.5 0.1 Line 3 Run 1 Cartridge 2 0413050-02 4/4/13 3.7 1.5 0.1 Line 3 Run 1 Cartridge 3 0413050-03 4/4/13 3.3 1.6 0.1 Line 3 Run 1 Cartridge 4 0413050-04 4/4/13 1.6 1.9 0.1 Line 3 Run 1 Cartridge 5 0413050-05 4/4/13 2.7 1.4 0.1 Line 3 Run 1 Cartridge 6 0413050-06 4/4/13 2.0 1.2 0.1 Line 3 Run 1 Cartridge 7 0413050-07 4/4/13 1.7 1.1 0.1 Line 3 Run 1 Cartridge 8 0413050-08 4/4/13 2.4 1.8 0.1 Line 2 Run 1 Cartridge 9 0413050-09 4/4/13 2.0 1.3 0.1 Line 2 Run 1 Cartridge 10 0413050-10 4/4/13 1.7 2.3 0.1 Line 2 Run 1 Cartridge 11 0413050-11 4/4/13 0.6 2.2 0.1 Line 2 Run 1 Cartridge 12 0413050-12 4/4/13 0.3 2.3 0.1 Line 2 Run 1 Cartridge 13 0413050-13 4/4/13 0.5 2.2 0.1 Line 2 Run 1 Cartridge 14 0413050-14 4/4/13 0.2 1.8 0.1 Line 2 Run 1 Cartridge 15 0413050-15 4/4/13 0.3 2.3 0.1 Line 2 Run 1 Cartridge 16 0413050-16 4/4/13 0.5 1.1 0.1 Line 3 Run 2 Cartridge 17 0413050-17 4/10/13 3.9 1.90 0.1 Line 3 Run 2 Cartridge 18 0413050-18 4/10/13 2.9 2.2 0.1 Line 3 Run 2 Cartridge 19 0413050-19 4/10/13 0.9 2.1 0.1 Line 3 Run 2 Cartridge 20 0413050-20 4/10/13 0.8 2 0.1 Line 3 Run 2 Cartridge 21 0413050-21 4/10/13 1.4 6.4 0.1 Line 3 Run 2 Cartridge 22 0413050-22 4/10/13 0.5 5.9 0.1 Line 3 Run 2 Cartridge 23 0413050-23 4/10/13 0.6 1.4 0.1 Line 3 Run 2 Cartridge 24 0413050-24 4/10/13 0.4 1.2 0.1 Line 2 Run 2 Cartridge 25 0413050-25 4/10/13 0.7 1 0.1 Line 2 Run 2 Cartridge 26 0413050-26 4/10/13 0.4 0.5 0.1 Line 2 Run 2 Cartridge 27 0413050-27 4/10/13 0.4 0.7 0.1 Line 2 Run 2 Cartridge 28 0413050-28 4/10/13 0.4 0.8 0.1 Line 2 Run 2 Cartridge 29 0413050-29 4/10/13 0.6 0.6 0.1 Line 2 Run 2 Cartridge 30 0413050-30 4/10/13 0.5 0.6 0.1 Line 2 Run 2 Cartridge 31 0413050-31 4/10/13 0.3 0.4 0.1 Line 2 Run 2 Cartridge 32 0413050-32 4/10/13 0.5 0.5 0.1 Line 3 Run 3 Cartridge 33 0413050-33 4/24/13 1.3 3.3 0.1 Line 3 Run 3 Cartridge 34 0413050-34 4/24/13 2.3 0.9 0.1 Line 3 Run 3 Cartridge 35 0413050-35 4/24/13 0.2 2.6 0.1 Line 3 Run 3 Cartridge 36 0413050-36 4/24/13 0.4 3.8 0.1 Line 3 Run 3 Cartridge 37 0413050-37 4/24/13 0.8 1.1 0.1 Line 3 Run 3 Cartridge 38 0413050-38 4/24/13 2.1 1.7 0.1 Line 3 Run 3 Cartridge 39 0413050-39 4/24/13 7.1 1.9 0.1 Line 3 Run 3 Cartridge 40 0413050-40 4/24/13 2.3 1.6 0.1 Line 2 Run 3 Cartridge 41 0413050-41 4/24/13 1.1 1 0.1 Line 2 Run 3 Cartridge 42 0413050-42 4/24/13 1.2 1.6 0.1 Line 2 Run 3 Cartridge 43 0413050-43 4/24/13 2.7 1.7 0.1 Line 2 Run 3 Cartridge 44 0413050-44 4/24/13 2.6 1.3 0.1 Line 2 Run 3 Cartridge 45 0413050-45 4/24/13 0.3 1.6 0.1 Line 2 Run 3 Cartridge 46 0413050-46 4/24/13 0.4 0.7 0.1 Line 2 Run 3 Cartridge 47 0413050-47 4/24/13 0.4 1.6 0.1 Line 2 Run 3 Cartridge 48 0413050-48 4/24/13 0.4 1.3 0.1 **Method 315** Data Analysis Technologies, Inc. 7715 Corporate Boulevard Plain City, OH 43064 **Data Summary**



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