Effluent Quality Assessment 

Progress Energy Florida Crystal River Plant Units 1, 2 

and 3 

Citrus County 

NPDES #FL0000159 

Sampled August 10, 2009 

January 2010

Biology Section 

Bureau of Laboratories 

Division of Environmental Assessment and Restoration 

Quality Manual No. 870346G 

NELAC Certification No. E31780
1 

CONTENTS

Introduction 

Methods 

Results and Discussion 

Literature Cited 

Tables 

Table 1 Measured algal growth potential (AGP) 

Table 2 Effluent limits, Class III Marine Criteria and chemical data 

Appendices 

Appendix A Chain of Custody 

Appendix B Bioassay Bench Sheets 

Appendix C SRT Bench Sheets and Statistical Analyses 

Appendix D Organism Receipt 

Appendix E Chemical Analyses of Effluent 

Appendix F Facility Summary, Effluent Limits, and Permit Violations 

Recorded on Discharge Monitoring Report 

Appendix G EPA End Sheet 
2 

Progress Energy Florida Crystal River Plant Units 1, 2 and 3, 15760 West Powerline St., Crystal 

River, Citrus County, Florida, 34428. NPDES #FL0000159. Effluent grab samples for bioassay 

and chemical analyses for this facility were collected on August 10, 2009. 

Introduction

Progress Energy Florida Crystal River Plant Units 1, 2 and 3 is an electric power generating plant 

consisting of two fossil fuel units (Units 1 and 2) and a nuclear fuel unit (unit 3). The facility has an 

industrial wastewater treatment and disposal system which treats cooling water and runoff water. 

(See Appendix F for detailed facility information provided by Jason Cohen of FDEP Southwest 

District) 

Methods 

Samples were collected from the EFF-1C, EFF-7 and EFF-10B NPDES sampling points, 

respectively, for Outfalls D-013, D-00F and D-072 and from screen wash-water Outfalls D-092 

and D-094 by Jason Cohen, Peter Wenner and Chris Anastasiou (FDEP Southwest District) 

following DEP-SOP-001/01 FS 2400 Wastewater Sampling. All DEP SOPs are available on the 

web at: http://www.floridadep.org/labs/qa/sops.htm. 

See Appendix A for the completed chain of custody form. 

The 48-hour acute screening toxicity tests and the algal growth potential test were performed 

following internal DEP SOPs TA07_03, TA07_04, and TA08_01 through TA08_09. All internal 

DEP SOPs are available on the web at: http://www.floridadep.org/labs/cgi-bin/sop/biosop.asp. 

Results and Discussion 

Toxicity Test Results 

Tests were performed August 11 - 13, 2009. 

Americamysis bahia 48-hour acute screening bioassay – LC50 > 100%, 0%* mortality in 

 100% sample at 48 hours 

Menidia beryllina 48-hour acute screening bioassay – LC50 > 100%, 5%* mortality in 

 100% sample at 48 hours 

The bioassay samples were not acutely toxic to the test organisms. 

*NOTE: In a 48-hour acute screening test of 100% effluent, mortality of <20% provides 

confidence that the effluent meets the acute toxicity criterion of Florida’s Surface Water 

Quality Standards (Rule 62-302.500 (1) (a) 4, F.A.C.). Mortality between 20-50% 

indicates low to moderate levels of toxicity, and further action may be required. Mortality 

of >50% indicates that the effluent fails to meet the minimum requirement to discharge to 

waters of the state (Rule 62-4.244(3) (a), F.A.C.). 

See Appendix B for bioassay bench sheets. See Appendix C for results of the last 20 

standard reference toxicant (SRT) tests and the bench sheets and statistical analyses of 

the SRT tests that correspond to these facility tests. See Appendix D for test organism 

receipts. 

Algal Growth Potential 

The Algal Growth Potential (AGP) in the effluent samples from Outfalls D-00F, D-013, 

and D-072 and in the lab duplicate of D-072 was 3.0 U (U - Material was analyzed for but 
3 

not detected; the value reported is the minimum detection limit) mg dry wt/L of the 

saltwater species, Dunaliella tertiolecta. Raschke and Schultz found that AGP values 

above 10.0 mg dry weight/L represent a “problem” threshold for marine receiving waters, 

implying nutrient enrichment (personal communication, Marshall Faircloth, et. al. FDEP, 

with Ron Raschke USEPA Region 4 1987). The ratios of total nitrogen to total 

phosphorus suggest that the effluent from Outfalls D-00F and Outfall D-013 is nitrogenlimited and that the effluent from Outfall D-072 is co-limited by both nitrogen and 

phosphorus (Maloney et al. 1978). 

See Table 1 for AGP results. 

Chemistry Results 

Total residual chlorine and total ammonia were not detected in the bioassay 

sample in the laboratory. The total ammonia concentration in the samples 

collected and preserved for chemical analysis from Outfalls D-013, D-00F and 

D-072 were, respectively, 0.01 U (U - Material was analyzed for but not detected; 

the value reported is the minimum detection limit) mg N/L, 0.011 I (I -The 

reported value is between the laboratory method detection limit (MDL) and the 

laboratory practical quantitation limit (PQL) mg N/L, and 0.028 mg N/L. Based on 

the pH, salinity, and temperature of the effluents as collected, the calculated 

unionized ammonia concentration in each of the samples was < 0.02 mg N/L. 

OUTFALL D-013 

Aluminum, total alpha particles, and radium 226 +228 were detected in the effluent at 

levels that comply with Class III marine water quality criteria (62-302.530, F.A.C.). 

Arsenic, chromium, lead and zinc were detected between the laboratory MDL and PQL. 

Iron (1190 mg/L; limit ≤300 μg/L, 62-302.500 (38), F.AC.), and effluent turbidity (36 NTU; 

limit ≤29 NTU, 62-302.500 (69), F.AC.) exceeded the Class III criteria for marine water. 

Zinc and nitrate + nitrite were detected in the equipment blank. 

OUTFALL D-00F 

Aluminum, copper, total alpha particles, and radium 226 +228 were detected in the 

effluent at levels that comply with Class III marine water quality criteria (62-302.530, 

F.A.C.). Arsenic, chromium, lead and zinc were detected between the laboratory MDL 

and PQL. Iron (970 mg/L; limit ≤300 μg/L, 62-302.500 (38), F.AC.) and effluent turbidity 

(34 NTU; limit ≤29 NTU, 62-302.500 (69), F.AC.) exceeded the Class III criteria for 

marine water. 

OUTFALL D-072 

Aluminum, arsenic, chromium, iron and zinc were detected in the effluent between the 

laboratory MDL and PQL. Iron (320 mg/L; limit ≤300 μg/L, 62-302.500 (38), F.AC.) 

exceeded the Class III criteria for marine water. 

See Table 2 for results of analytes detected in the effluent, and corresponding limits. See 

Appendix E for a complete list of chemical analyses performed. 

Conclusion 

The effluent sample collected from the EFF-7 NPDES sampling point for Outfall D-00F for this 

facility on August 10, 2009, was not acutely toxic to either test species during the 48-hour acute 

screening bioassays. The AGP results from each of the three effluent samples were less than the 

"problem” threshold for marine receiving waters. Effluent water quality samples collected on 

August 10, 2009, exceeded applicable water quality standards for iron in Outfalls D-013, D-00F 

and D-072 and effluent turbidity in Outfalls D-013 and D-00F. 
4 

Literature Cited 

Maloney, T. E., W. E. Miller, and D. T. Specht. 1974. The Marine Algal Assay Procedure: 

Bottle Test. National Environmental Research Center Office of Research and 

Development. U. S. EPA, Corvallis, Oregon. 43 p. 
5 

Inorganic Total

N:P ratio * N:P ratio

D-013 3.0 U - 7.7

D-00F 3.0 U - 7.8

D-072 3.0 AU - 11.6

* - Ortho-phosphate was not measured in the analytical chemistry 

sample; therefore, inorganic N:P ratios could not be calculated.

A - Value reported is the mean of two or more determinations

U - Material analyzed for but not detected; value reported is the 

method detection limit

Location

Progress Energy Florida Crystal River Plant Units 1, 2 and 3. 

NPDES# FL0000159.

Table 1. Measured algal growth potential (AGP; mg dry weight/L) 

of the saltwater species Dunaliella tertiolecta and ratios of 

nitrogen to phosphorus for samples collected from the Progress 

Energy Crystal River Plant Units 1, 2 and 3 facility on August 10, 

2009.

AGP

(measured)
6 

Progress Energy Florida Crystal 

River Plant Units 1, 2 and 3 

NPDES# FL0000159

Class III 

Criteria

Effluent 

Limits

None Detected - -

Aluminum ≤ 1500 - 1200 1040 490 I

Arsenic ≤ 50 - 3 I 3.3 I 2.4 I

Cadmium ≤ 8.8 - 0.12 U 0.12 U 0.12 U

Calcium (mg/L) - - 356 348 347

Chromium-III - - 4.5 I 4 I 1.8 I

Copper ≤ 3.7 Report 2 U 2.7 2 U

Iron ≤ 300 Report 1190 970 320 I

Lead ≤ 8.5 - 0.96 I 0.83 I 0.8 U

Magnesium (mg/L) - - 1100 1110 1110

Mercury ≤ 0.025 - - - -

Nickel ≤ 8.3 - 1.4 U 1.4 U 1.4 U

Selenium ≤ 71 - 0.8 U 0.8 U 0.8 U

Silver ≤ 2.3 - 0.1 U 0.1 U 0.1 U

Zinc ≤ 86 - 21 I 20 I 24 I

Total Phosphorus - - 0.089 0.093 AJ 0.048

Total Ammonia - - 0.01 U 0.011 I 0.028

Un-ionized Ammonia - - ≤ 0.02 c ≤ 0.02 c ≤ 0.02 c

Nitrate and Nitrite - - 0.006 I 0.004 U 0.005 I

Total Kjeldahl Nitrogen - - 0.68 J 0.72 0.55

Organic Nitrogen - - 0.675 c 0.709 c 0.522 c

Total Nitrogen - - 0.686 c 0.722 c 0.555 c

Dissolved Oxygen (mg/L) ≥ 4.0 - 5.3 5.3 6.6

pH (SU) 6.5 - 8.5 - 8.0 8.1 8.1

Conductivity (μmhos/cm) - - 47868 47800 46443

Temperature (°C) - - 41.8 40.7 31.8

Salinity - - 30.6 30.6 26.1 c

Total Residual Chlorine (mg/L) ≤ 0.01 - ≤ 0.03 UQ£ 0 0

Chlorophyll a (μg/L) - Corrected - - 4.5 2.2 1.9

Phaeophytin (μg/L) - - 4.1 1.9 1.8

Total Suspended Solids (mg/L) - - 70 78 40 A

Turbidity (NTU) < 29 t - 36 A 34 -

CBOD, 5 day (mg/L), N - inhibited - - 0.81 I 1.1 I 0.94 I

Oils and Greases (mg/L) ≤ 5.0 ≤ 20.0 - 1.4 U -

Alpha, Total (pCi/L) ≤ 15 - 3.1 1.8 -

Alpha-Counting Error (pCi/L) - - 1.1 0.9 -

Radium 226 (pCi/L) - - 1.8 1.4 -

Radium 226-Counting Error (pCi/L) - - 0.2 0.2 -

Radium 228 (pCi/L) - - 1 0.8 -

Radium 228-Counting Error (pCi/L) - - 0.6 0.5 -

Radium 226 + 228 (pCi/L) ≤ 5 - 2.8 c 2.2 c -

Hardness (mg CaCO3) - - 5418.73 c 5439.94 c 5437.44 c

Flow (MGD) - 1898 a 218.98 a

Value exceeds the Class III Water Quality Criteria or permit limits

a - Annual average

c - Value is calculated

t - Shall not exceed 29 NTUs above background

A - Value reported is the mean of two or more determinations

I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit

J - Estimated value

U - Material analyzed for but not detected; value reported is the method detection limit

Q - Sample held beyond normal holding time

£ - Measurement performed in bioassay laboratory

Table 2. Effluent limits, Class III Criteria for predominantly marine waters and chemical data for 

samples collected from the Progress Energy Florida Crystal River Plant Units 1, 2 and 3 facility on 

August 10, 2009.

Nutrients (mg/L)

General Physical and Chemical Parameters

D-072

Organic Constituents (μg/L)

Metals (μg/L unless otherwise noted)

None Detected

D-013 D-00F
7 

Appendix A. Chain of Custody Form 
8 

Appendix A. (continued) 
9 

Appendix B. Bench Sheets 
10 

Appendix B. (continued) 
11 

Appendix B. (continued) 
12 

Appendix B. (continued) 
13 

Appendix B. (continued) 
14 

Appendix B. (continued) 
15 

Appendix C. SRT Bench Sheets and Statistical Analysis 

Florida Department of Environmental Protection

Bureau of Laboratories

Standard Reference Toxicant (SRT) Test Data - 48-hour Acute Toxicity

Americamysis bahia (mysid shrimp) - Cadmium Chloride (CdCl2) 

Date LC50 Mean LC50 Std Dev Lower Control Limit Upper Control Limit

03/11/08 38.21 47.42 11.38 24.66 70.19

04/01/08 53.27 46.90 10.82 25.26 68.53

05/06/08 35.65 45.82 10.81 24.19 67.45

06/03/08 58.28 46.36 11.17 24.03 68.69

07/08/08 47.67 46.00 10.99 24.02 67.98

08/05/08 44.68 46.32 10.84 24.63 68.01

09/03/08 45.94 45.82 10.60 24.62 67.02

10/07/08 41.43 44.39 8.96 26.47 62.30

11/04/08 46.75 44.58 8.97 26.64 62.51

11/12/09 44.92 44.87 8.87 27.13 62.61

12/02/08 40.59 44.42 8.84 26.73 62.11

01/06/09 37.22 43.80 8.89 26.01 61.59

02/03/09 39.02 43.57 8.96 25.66 61.49

03/03/09 30.58 42.81 9.40 24.02 61.61

03/31/09 38.24 42.65 9.45 23.76 61.55

04/08/09 31.38 42.44 9.66 23.12 61.76

05/05/09 33.86 41.62 9.66 22.31 60.93

06/09/09 41.42 40.46 8.00 24.47 56.45

07/07/09 43.11 41.44 6.94 27.55 55.32

08/04/09 35.91 41.41 6.97 27.47 55.34

Lower Confidence Limit = mean - 2 * Std Dev CV = 16.82

Upper Confidence Limit = mean + 2 * Std Dev EPA reference 75th quartile CV = 26%

20

30

40

50

60

70

80

03/11/0804/01/0805/06/0806/03/0807/08/0808/05/0809/03/0810/07/0811/04/0811/12/0912/02/0801/06/0902/03/0903/03/0903/31/0904/08/0905/05/0906/09/0907/07/0908/04/09

μg/L CdCl2

Test Date

Standard Reference Toxicant Data 

Americamysis bahia 48-hour LC50

LC50 Mean LC50 Lower Control Limit Upper Control Limit
16 

Appendix C. (continued) 

Florida Department of Environmental Protection

Bureau of Laboratories

Standard Reference Toxicant (SRT) Test Data - Acute Toxicity

Menidia beryllina (Inland silverside) - Copper Chloride (CuCl2)

Date LC50 Mean LC50 Std Dev

Lower 

Control Limit

Upper 

Control Limit

03/04/08 295.52 295.31 68.1 159.3 431.9

04/01/08 379.50 304.05 67.5 169.0 439.1

05/06/08 272.50 304.73 67.1 170.5 438.9

06/03/08 373.47 312.52 65.5 181.5 443.5

07/08/08 275.20 316.13 61.0 194.2 438.1

08/12/08 221.17 320.17 50.5 219.2 421.1

09/03/08 167.46 313.48 60.9 191.7 435.3

09/09/08 240.07 311.58 62.6 186.3 436.9

10/07/08 325.55 312.05 62.7 186.6 437.5

11/04/08 249.81 307.63 63.9 179.9 435.4

12/02/08 316.79 310.59 62.8 185.0 436.2

01/06/09 257.04 311.08 62.3 186.5 435.7

02/03/09 245.51 305.47 62.9 179.6 431.4

03/03/09 433.98 309.64 68.6 172.5 446.8

03/31/09 228.94 304.17 70.5 163.1 445.2

05/05/09 310.12 302.74 70.1 162.6 442.9

06/02/09 471.25 305.32 75.4 154.6 456.0

06/09/09 370.27 306.03 75.9 154.2 457.9

07/07/09 407.17 309.94 79.1 151.7 468.2

08/04/09 339.47 309.04 78.7 151.7 466.3

Means are of the last 20 SRT tests.

EPA reference 75th quartile CV = 21% CV = 25.45

0

50

100

150

200

250

300

350

400

450

500

03/04/0804/01/0805/06/0806/03/0807/08/0808/12/0809/03/0809/09/0810/07/0811/04/0812/02/0801/06/0902/03/0903/03/0903/31/0905/05/0906/02/0906/09/0907/07/0908/04/09

μg/L CuCl2

Test Date

Standard Reference Toxicant Data 

Menidia beryllina 48 hour LC50

Lower Control Limit LC50 Mean LC50 Upper Control Limit
17 

Appendix C. (continued) 
18 

Appendix C. (continued) 
19 

Appendix C. (continued) 
20 

Appendix C. (continued) 
21 

Appendix C. (continued) 

Americamysis bahia Acute Standard Reference Toxicant Test 

 DATE: 8-4-09 DURATION: 48 hr TOXICANT : CdCl2 

 SPECIES: Americamysis bahia

 RAW DATA: Concentration Number Mortalities 

 (ug/L) Exposed 

 .00 20 0 

 20.00 20 1 

 30.00 20 4 

 45.00 20 17 

 67.00 20 19 

 100.00 20 20 

 SPEARMAN-KARBER TRIM: 5.00% 

 SPEARMAN-KARBER ESTIMATES: LC50: 35.91 

 95% LOWER CONFIDENCE: 32.11 

 95% UPPER CONFIDENCE: 40.16 

Menidia beryllina Acute Standard Reference Toxicant Test 

DATE: 8-4-09 DURATION: 48 h TOXICANT : CuCl2 

 SPECIES: Menidia beryllina

 RAW DATA: Concentration Number Mortalities 

 (ug/L) Exposed 

 .00 20 0 

 100.00 20 2 

 200.00 20 2 

 300.00 20 12 

 400.00 20 8 

 500.00 20 16 

 SPEARMAN-KARBER TRIM: 20.00% 

 SPEARMAN-KARBER ESTIMATES: LC50: 339.47 

 95% LOWER CONFIDENCE: 288.65 

 95% UPPER CONFIDENCE: 399.24 

 NOTE: MORTALITY PROPORTIONS WERE NOT MONOTONICALLY INCREASING. 

ADJUSTMENTS WERE MADE PRIOR TO SPEARMAN-KARBER ESTIMATION. 
22 

Appendix D. Test Organism Receipts 
23 

Appendix D. (continued) 
24 

Appendix E. Chemical Analyses performed on the effluent from the Progress Energy Florida Cr

Units 1, 2, and 3 Plant Outfalls D-00F, D-013, D-092, D-094 and D-072, sampled on August 10, 20

Date Field ID Analysis Component Result Remark Units M

8/10/2009 11:45 D-013 AGP/LN Algal Growth Potential 3 U mg DryWt/L 3 8/10/2009 11:45 D-013 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 0.81 I mg/L 08/10/2009 11:45 D-013 Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 4.5 ug/L 18/10/2009 11:45 D-013 Chlorophyll/Grain Size/BOD Phaeophytin-a 4.1 ug/L 08/10/2009 11:45 D-013 Metals Zinc 21 I ug/L 18/10/2009 11:45 D-013 Metals Cadmium 0.12 U ug/L 08/10/2009 11:45 D-013 Metals Chromium 4.5 I ug/L 18/10/2009 11:45 D-013 Metals Lead 0.96 I ug/L 08/10/2009 11:45 D-013 Metals Silver 0.1 U ug/L 08/10/2009 11:45 D-013 Metals Calcium 356 mg/L 08/10/2009 11:45 D-013 Metals Nickel 1.4 U ug/L 18/10/2009 11:45 D-013 Metals Iron 1190 ug/L 98/10/2009 11:45 D-013 Metals Magnesium 1100 mg/L 08/10/2009 11:45 D-013 Metals Aluminum 1200 ug/L 18/10/2009 11:45 D-013 Metals Selenium 0.8 U ug/L 08/10/2009 11:45 D-013 Metals Copper 2 U ug/L 2 8/10/2009 11:45 D-013 Metals Arsenic 3 I ug/L 1 8/10/2009 11:45 D-013 Nutrients Turbidity 36 A NTU 08/10/2009 11:45 D-013 Nutrients Kjeldahl Nitrogen 0.68 J mg N/L 08/10/2009 11:45 D-013 Nutrients NO2NO3-N 0.006 I mg N/L 08/10/2009 11:45 D-013 Nutrients Ammonia-N 0.01 U mg N/L 08/10/2009 11:45 D-013 Nutrients TSS 70 mg/L 4 8/10/2009 11:45 D-013 Nutrients Total-P 0.089 mg P/L 08/10/2009 11:45 D-013 Overflow Radium 228 1 pCi/L 8/10/2009 11:45 D-013 Overflow Alpha, Total 3.1 pCi/L 8/10/2009 11:45 D-013 Overflow Radium 226 1.8 pCi/L 8/10/2009 11:45 D-013 Overflow Radium 226-Counting Error 0.2 pCi/L 8/10/2009 11:45 D-013 Overflow Alpha-Counting Error 1.1 pCi/L 8/10/2009 11:45 D-013 Overflow Radium 228-Counting Error 0.6 pCi/L 8/10/2009 11:45 D-013 Pesticides Azinphos Methyl 0.22 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Butylate 0.22 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Chlorpyrifos Methyl 0.11 U ug/L 08/10/2009 11:45 D-013 Pesticides Diazinon 0.056 UJ ug/L 0
25 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 11:45 D-013 Pesticides Ethoprop 0.11 U ug/L 08/10/2009 11:45 D-013 Pesticides Fenamiphos 0.22 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Mevinphos 0.22 U ug/L 08/10/2009 11:45 D-013 Pesticides Malathion 0.17 U ug/L 08/10/2009 11:45 D-013 Pesticides Metribuzin 0.11 U ug/L 08/10/2009 11:45 D-013 Pesticides Naled 0.9 U ug/L 08/10/2009 11:45 D-013 Pesticides Beta-BHC 0.011 U ug/L 08/10/2009 11:45 D-013 Pesticides Metalaxyl 0.28 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Metolachlor 0.56 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Endosulfan II 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Atrazine 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Parathion Ethyl 0.17 U ug/L 08/10/2009 11:45 D-013 Pesticides Parathion Methyl 0.11 U ug/L 08/10/2009 11:45 D-013 Pesticides Endrin 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Heptachlor Epoxide 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Chlorpyrifos Ethyl 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Fonofos 0.11 UJ ug/L 08/10/2009 11:45 D-013 Pesticides DDD-p,p' 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides DDE-p,p' 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Delta-BHC 0.011 U ug/L 08/10/2009 11:45 D-013 Pesticides Endrin Aldehyde 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Gamma-BHC 0.011 U ug/L 08/10/2009 11:45 D-013 Pesticides Bromacil 0.22 U ug/L 08/10/2009 11:45 D-013 Pesticides Hexazinone 0.11 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Norflurazon 0.17 UJ ug/L 08/10/2009 11:45 D-013 Pesticides Simazine 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Alpha-BHC 0.011 U ug/L 08/10/2009 11:45 D-013 Pesticides Phorate 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Chlordane 0.22 U ug/L 08/10/2009 11:45 D-013 Pesticides DDT-p,p' 0.034 U ug/L 08/10/2009 11:45 D-013 Pesticides Endosulfan I 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Endosulfan Sulfate 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Methoxychlor 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Alachlor 0.67 UJ ug/L 0
26 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 11:45 D-013 Pesticides Ametryn 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Ethion 0.056 U ug/L 08/10/2009 11:45 D-013 Pesticides Prometryn 0.17 U ug/L 08/10/2009 11:45 D-013 Pesticides Aldrin 0.011 U ug/L 08/10/2009 11:45 D-013 Pesticides Dieldrin 0.022 U ug/L 08/10/2009 11:45 D-013 Pesticides Heptachlor 0.011 U ug/L 08/10/2009 11:45 D-013 Pesticides Toxaphene 0.84 U ug/L 08/10/2009 11:45 D-013 Priority Organic Pollutants 4-Nitrophenol 17 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Butyl benzyl phthalate 5.6 U ug/L 58/10/2009 11:45 D-013 Priority Organic Pollutants Phenanthrene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 4-Chlorophenyl phenyl ether 2.2 U ug/L 28/10/2009 11:45 D-013 Priority Organic Pollutants Acenaphthene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Acenaphthylene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Di-n-butyl phthalate 5.6 U ug/L 58/10/2009 11:45 D-013 Priority Organic Pollutants Hexachloroethane 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants 2,4,6-Trichlorophenol 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2,6-Dinitrotoluene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 17 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Chrysene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Diethyl phthalate 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants Pentachlorophenol 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants 1,2,4-Trichlorobenzene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2-Chloronaphthalene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2-Chlorophenol 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2-Nitrophenol 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 3,3'-Dichlorobenzidine 45 UJ ug/L 48/10/2009 11:45 D-013 Priority Organic Pollutants 4-Bromophenyl phenyl ether 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Anthracene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(b)fluoranthene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(k)fluoranthene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Bis(2-chloroisopropyl)ether 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants N-Nitrosodi-n-propylamine 2.2 U ug/L 28/10/2009 11:45 D-013 Priority Organic Pollutants Naphthalene 1.1 U ug/L 1
27 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 11:45 D-013 Priority Organic Pollutants Phenol 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Pyrene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dimethylphenol 11 UJ ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dinitrotoluene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Benzidine 110 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(a)pyrene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Bis(2-chloroethyl)ether 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Dibenzo(a,h)anthracene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Dimethyl phthalate 11 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Hexachlorobenzene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dichlorophenol 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(a)anthracene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Bis(2-chloroethoxy)methane 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Di-n-octyl phthalate 1.1 UJ ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Fluoranthene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Hexachlorocyclopentadiene 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Isophorone 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants N-Nitrosodimethylamine 2.2 U ug/L 28/10/2009 11:45 D-013 Priority Organic Pollutants Nitrobenzene 2.2 U ug/L 28/10/2009 11:45 D-013 Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants Fluorene 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Hexachlorobutadiene 3.4 U ug/L 38/10/2009 11:45 D-013 Priority Organic Pollutants 2,4-Dinitrophenol 17 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants 4-Chloro-3-methylphenol 1.1 U ug/L 18/10/2009 11:45 D-013 Priority Organic Pollutants Benzo(g,h,i)perylene 1.1 U ug/L 18/10/2009 11:45 D-013 Field Parameter pH 8.04 8/10/2009 11:45 D-013 Field Parameter Sample Depth 0.2 m 8/10/2009 11:45 D-013 Field Parameter Specific Conductance 47868 umhos/cm 8/10/2009 11:45 D-013 Field Parameter Dissolved Oxygen 5.31 mg/L 8/10/2009 11:45 D-013 Field Parameter Temperature 41.83 C 8/10/2009 12:05 D-00F AGP/LN Algal Growth Potential 3 U mg DryWt/L 3 
28 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 12:05 D-00F Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 1.1 I mg/L 08/10/2009 12:05 D-00F Chlorophyll/Grain Size/BOD Phaeophytin-a 1.9 ug/L 08/10/2009 12:05 D-00F Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 2.2 ug/L 08/10/2009 12:05 D-00F Toxicology Bioassay-Acute-Screen-SW-Mysid, LC50 100 L LC50 8/10/2009 12:05 D-00F Toxicology Bioassay-Acute-Screen-SW-Fish, LC50 100 L LC50 8/10/2009 12:05 D-00F Metals Silver 0.1 U ug/L 08/10/2009 12:05 D-00F Metals Cadmium 0.12 U ug/L 08/10/2009 12:05 D-00F Metals Aluminum 1040 ug/L 18/10/2009 12:05 D-00F Metals Zinc 20 I ug/L 18/10/2009 12:05 D-00F Metals Lead 0.83 I ug/L 08/10/2009 12:05 D-00F Metals Iron 970 ug/L 98/10/2009 12:05 D-00F Metals Chromium 4 I ug/L 18/10/2009 12:05 D-00F Metals Arsenic 3.3 I ug/L 1 8/10/2009 12:05 D-00F Metals Nickel 1.4 U ug/L 18/10/2009 12:05 D-00F Metals Copper 2.7 ug/L 2 8/10/2009 12:05 D-00F Metals Magnesium 1110 mg/L 08/10/2009 12:05 D-00F Metals Selenium 0.8 U ug/L 08/10/2009 12:05 D-00F Metals Calcium 348 mg/L 08/10/2009 12:05 D-00F Nutrients Total-P 0.093 AJ mg P/L 08/10/2009 12:05 D-00F Nutrients Turbidity 34 NTU 08/10/2009 12:05 D-00F Nutrients TSS 78 mg/L 4 8/10/2009 12:05 D-00F Nutrients NO2NO3-N 0.004 U mg N/L 08/10/2009 12:05 D-00F Nutrients Ammonia-N 0.011 I mg N/L 08/10/2009 12:05 D-00F Nutrients Kjeldahl Nitrogen 0.72 mg N/L 08/10/2009 12:05 D-00F Overflow Radium 226-Counting Error 0.2 pCi/L 8/10/2009 12:05 D-00F Overflow Radium 228-Counting Error 0.5 pCi/L 8/10/2009 12:05 D-00F Overflow Alpha, Total 1.8 pCi/L 8/10/2009 12:05 D-00F Overflow Oil and Grease 1.4 U mg/L 18/10/2009 12:05 D-00F Overflow Radium 226 1.4 pCi/L 8/10/2009 12:05 D-00F Overflow Alpha-Counting Error 0.9 pCi/L 8/10/2009 12:05 D-00F Overflow Radium 228 0.8 pCi/L 8/10/2009 12:05 D-00F Pesticides Ametryn 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides Atrazine 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides Fenamiphos 0.22 UJ ug/L 0
29 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 12:05 D-00F Pesticides Parathion Methyl 0.11 U ug/L 08/10/2009 12:05 D-00F Pesticides Simazine 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides DDT-p,p' 0.032 U ug/L 08/10/2009 12:05 D-00F Pesticides Endrin Aldehyde 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Chlorpyrifos Ethyl 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides Metalaxyl 0.27 UJ ug/L 08/10/2009 12:05 D-00F Pesticides DDE-p,p' 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Metolachlor 0.54 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Parathion Ethyl 0.16 U ug/L 08/10/2009 12:05 D-00F Pesticides DDD-p,p' 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Endosulfan II 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Endosulfan Sulfate 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Heptachlor Epoxide 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Bromacil 0.22 U ug/L 08/10/2009 12:05 D-00F Pesticides Diazinon 0.054 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Alpha-BHC 0.011 U ug/L 08/10/2009 12:05 D-00F Pesticides Delta-BHC 0.011 U ug/L 08/10/2009 12:05 D-00F Pesticides Heptachlor 0.011 U ug/L 08/10/2009 12:05 D-00F Pesticides Chlorpyrifos Methyl 0.11 U ug/L 08/10/2009 12:05 D-00F Pesticides Fonofos 0.11 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Hexazinone 0.11 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Naled 0.86 U ug/L 08/10/2009 12:05 D-00F Pesticides Norflurazon 0.16 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Aldrin 0.011 U ug/L 08/10/2009 12:05 D-00F Pesticides Gamma-BHC 0.011 U ug/L 08/10/2009 12:05 D-00F Pesticides Azinphos Methyl 0.22 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Metribuzin 0.11 U ug/L 08/10/2009 12:05 D-00F Pesticides Mevinphos 0.22 U ug/L 08/10/2009 12:05 D-00F Pesticides Phorate 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides Beta-BHC 0.011 U ug/L 08/10/2009 12:05 D-00F Pesticides Dieldrin 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Ethion 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides Ethoprop 0.11 U ug/L 08/10/2009 12:05 D-00F Pesticides Prometryn 0.16 U ug/L 0
30 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 12:05 D-00F Pesticides Chlordane 0.22 U ug/L 08/10/2009 12:05 D-00F Pesticides Methoxychlor 0.054 U ug/L 08/10/2009 12:05 D-00F Pesticides Toxaphene 0.81 U ug/L 08/10/2009 12:05 D-00F Pesticides Alachlor 0.65 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Butylate 0.22 UJ ug/L 08/10/2009 12:05 D-00F Pesticides Malathion 0.16 U ug/L 08/10/2009 12:05 D-00F Pesticides Endosulfan I 0.022 U ug/L 08/10/2009 12:05 D-00F Pesticides Endrin 0.054 U ug/L 08/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dinitrophenol 16 U ug/L 18/10/2009 12:05 D-00F Priority Organic Pollutants 4-Chlorophenyl phenyl ether 2.1 U ug/L 28/10/2009 12:05 D-00F Priority Organic Pollutants 2-Nitrophenol 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-chloroethoxy)methane 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dinitrotoluene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2,6-Dinitrotoluene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 4-Chloro-3-methylphenol 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Acenaphthene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Anthracene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(a)anthracene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Di-n-butyl phthalate 5.2 U ug/L 58/10/2009 12:05 D-00F Priority Organic Pollutants Di-n-octyl phthalate 1 UJ ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Dimethyl phthalate 10 U ug/L 18/10/2009 12:05 D-00F Priority Organic Pollutants Isophorone 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Pentachlorophenol 3.1 U ug/L 38/10/2009 12:05 D-00F Priority Organic Pollutants Pyrene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2-Chloronaphthalene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(b)fluoranthene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(k)fluoranthene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-chloroethyl)ether 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-chloroisopropyl)ether 3.1 U ug/L 38/10/2009 12:05 D-00F Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants N-Nitrosodi-n-propylamine 2.1 U ug/L 28/10/2009 12:05 D-00F Priority Organic Pollutants Naphthalene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dimethylphenol 10 UJ ug/L 18/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(g,h,i)perylene 1 U ug/L 1 
31 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 12:05 D-00F Priority Organic Pollutants Butyl benzyl phthalate 5.2 U ug/L 58/10/2009 12:05 D-00F Priority Organic Pollutants Dibenzo(a,h)anthracene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Hexachlorobenzene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Hexachlorocyclopentadiene 3.1 U ug/L 38/10/2009 12:05 D-00F Priority Organic Pollutants 4-Bromophenyl phenyl ether 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 16 U ug/L 18/10/2009 12:05 D-00F Priority Organic Pollutants Phenanthrene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Phenol 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Acenaphthylene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Benzidine 100 U ug/L 18/10/2009 12:05 D-00F Priority Organic Pollutants Chrysene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Fluoranthene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Fluorene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 3.1 U ug/L 38/10/2009 12:05 D-00F Priority Organic Pollutants Nitrobenzene 2.1 U ug/L 28/10/2009 12:05 D-00F Priority Organic Pollutants 2-Chlorophenol 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 3,3'-Dichlorobenzidine 42 UJ ug/L 48/10/2009 12:05 D-00F Priority Organic Pollutants 4-Nitrophenol 16 U ug/L 18/10/2009 12:05 D-00F Priority Organic Pollutants Benzo(a)pyrene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Diethyl phthalate 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants Hexachlorobutadiene 3.1 U ug/L 38/10/2009 12:05 D-00F Priority Organic Pollutants Hexachloroethane 3.1 U ug/L 38/10/2009 12:05 D-00F Priority Organic Pollutants N-Nitrosodimethylamine 2.1 U ug/L 28/10/2009 12:05 D-00F Priority Organic Pollutants 1,2,4-Trichlorobenzene 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2,4,6-Trichlorophenol 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2,4-Dichlorophenol 1 U ug/L 1 8/10/2009 12:05 D-00F Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 3.1 U ug/L 38/10/2009 12:05 D-00F Field Parameter Sample Depth 0.2 m 8/10/2009 12:05 D-00F Field Parameter Temperature 40.67 C 8/10/2009 12:05 D-00F Field Parameter Temperature 40.67 C 8/10/2009 12:05 D-00F Field Parameter Sample Depth 0.2 m 
32 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 12:05 D-00F Field Parameter pH 8.06 8/10/2009 12:05 D-00F Field Parameter Specific Conductance 47800 umhos/cm 8/10/2009 12:05 D-00F Field Parameter Dissolved Oxygen 5.33 mg/L 8/10/2009 11:40 Equipment Blank Metals Calcium 0.075 U mg/L 08/10/2009 11:40 Equipment Blank Metals Silver 0.025 U ug/L 08/10/2009 11:40 Equipment Blank Metals Nickel 0.25 U ug/L 08/10/2009 11:40 Equipment Blank Metals Zinc 7.2 I ug/L 5 8/10/2009 11:40 Equipment Blank Metals Selenium 0.2 U ug/L 08/10/2009 11:40 Equipment Blank Metals Lead 0.2 U ug/L 08/10/2009 11:40 Equipment Blank Metals Chromium 0.3 U ug/L 08/10/2009 11:40 Equipment Blank Metals Iron 30 U ug/L 38/10/2009 11:40 Equipment Blank Metals Aluminum 60 U ug/L 68/10/2009 11:40 Equipment Blank Metals Copper 0.5 U ug/L 08/10/2009 11:40 Equipment Blank Metals Arsenic 0.25 U ug/L 08/10/2009 11:40 Equipment Blank Metals Magnesium 0.04 U mg/L 08/10/2009 11:40 Equipment Blank Metals Cadmium 0.03 U ug/L 08/10/2009 11:40 Equipment Blank Nutrients NO2NO3-N 0.005 I mg N/L 08/10/2009 11:40 Equipment Blank Nutrients Ammonia-N 0.01 U mg N/L 08/10/2009 11:40 Equipment Blank Nutrients Total-P 0.004 U mg P/L 08/10/2009 11:40 Equipment Blank Nutrients Kjeldahl Nitrogen 0.08 U mg N/L 08/10/2009 12:30 D-092 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 1 I mg/L 08/10/2009 12:30 D-092 Overflow COD 300 mg/L 38/10/2009 12:30 D-092 Field Parameter Temperature 31.31 C 8/10/2009 12:30 D-092 Field Parameter Sample Depth 0.2 m 8/10/2009 12:30 D-092 Field Parameter pH 8.03 8/10/2009 12:30 D-092 Field Parameter Specific Conductance 48351 umhos/cm 8/10/2009 12:30 D-092 Field Parameter Dissolved Oxygen 6.15 mg/L 8/10/2009 12:50 D-094 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 0.79 I mg/L 08/10/2009 12:50 D-094 Overflow COD 740 mg/L 38/10/2009 12:50 D-094 Field Parameter Temperature 40.21 C 8/10/2009 12:50 D-094 Field Parameter Dissolved Oxygen 5.39 mg/L 8/10/2009 12:50 D-094 Field Parameter Specific Conductance 47600 umhos/cm 8/10/2009 12:50 D-094 Field Parameter Sample Depth 0.2 m 8/10/2009 12:50 D-094 Field Parameter pH 8.03 
33 

Appendix E. (continued) 

Date Field ID Analysis Component Result Remark Units M

8/10/2009 13:05 D-072 AGP/LN Algal Growth Potential 3 AU mg DryWt/L 3 8/10/2009 13:05 D-072 Chlorophyll/Grain Size/BOD Biochemical Oxygen Demand-5 Day,N-Inhib 0.94 I mg/L 08/10/2009 13:05 D-072 Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 1.9 ug/L 08/10/2009 13:05 D-072 Chlorophyll/Grain Size/BOD Phaeophytin-a 1.8 ug/L 08/10/2009 13:05 D-072 Metals Copper 2 U ug/L 2 8/10/2009 13:05 D-072 Metals Zinc 24 I ug/L 28/10/2009 13:05 D-072 Metals Magnesium 1110 mg/L 08/10/2009 13:05 D-072 Metals Cadmium 0.12 U ug/L 08/10/2009 13:05 D-072 Metals Nickel 1.4 U ug/L 18/10/2009 13:05 D-072 Metals Silver 0.1 U ug/L 08/10/2009 13:05 D-072 Metals Iron 320 I ug/L 98/10/2009 13:05 D-072 Metals Calcium 347 mg/L 08/10/2009 13:05 D-072 Metals Arsenic 2.4 I ug/L 1 8/10/2009 13:05 D-072 Metals Aluminum 490 I ug/L 18/10/2009 13:05 D-072 Metals Selenium 0.8 U ug/L 08/10/2009 13:05 D-072 Metals Lead 0.8 U ug/L 08/10/2009 13:05 D-072 Metals Chromium 1.8 I ug/L 18/10/2009 13:05 D-072 Nutrients Total-P 0.048 mg P/L 08/10/2009 13:05 D-072 Nutrients TSS 40 A mg/L 4 8/10/2009 13:05 D-072 Nutrients Ammonia-N 0.028 mg N/L 08/10/2009 13:05 D-072 Nutrients NO2NO3-N 0.005 I mg N/L 08/10/2009 13:05 D-072 Nutrients Kjeldahl Nitrogen 0.55 mg N/L 08/10/2009 13:05 D-072 Pesticides Endosulfan Sulfate 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Endrin Aldehyde 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Azinphos Methyl 0.21 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Chlorpyrifos Methyl 0.11 U ug/L 08/10/2009 13:05 D-072 Pesticides Fenamiphos 0.21 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Fonofos 0.11 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Heptachlor 0.011 U ug/L 08/10/2009 13:05 D-072 Pesticides Heptachlor Epoxide 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Methoxychlor 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Ametryn 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Metolachlor 0.53 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Simazine 0.053 U ug/L 0
34 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 13:05 D-072 Pesticides Delta-BHC 0.011 U ug/L 08/10/2009 13:05 D-072 Pesticides Beta-BHC 0.011 U ug/L 08/10/2009 13:05 D-072 Pesticides DDE-p,p' 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides DDT-p,p' 0.032 U ug/L 08/10/2009 13:05 D-072 Pesticides Toxaphene 0.79 U ug/L 08/10/2009 13:05 D-072 Pesticides Atrazine 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Malathion 0.16 U ug/L 08/10/2009 13:05 D-072 Pesticides Metalaxyl 0.26 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Alachlor 0.63 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Chlorpyrifos Ethyl 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Naled 0.84 U ug/L 08/10/2009 13:05 D-072 Pesticides Alpha-BHC 0.011 U ug/L 08/10/2009 13:05 D-072 Pesticides Dieldrin 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Endosulfan II 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Aldrin 0.011 U ug/L 08/10/2009 13:05 D-072 Pesticides Prometryn 0.16 U ug/L 08/10/2009 13:05 D-072 Pesticides Parathion Ethyl 0.16 U ug/L 08/10/2009 13:05 D-072 Pesticides Metribuzin 0.11 U ug/L 08/10/2009 13:05 D-072 Pesticides Endosulfan I 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Phorate 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Hexazinone 0.11 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Diazinon 0.053 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Butylate 0.21 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Gamma-BHC 0.011 U ug/L 08/10/2009 13:05 D-072 Pesticides DDD-p,p' 0.021 U ug/L 08/10/2009 13:05 D-072 Pesticides Chlordane 0.21 U ug/L 08/10/2009 13:05 D-072 Pesticides Parathion Methyl 0.11 U ug/L 08/10/2009 13:05 D-072 Pesticides Norflurazon 0.16 UJ ug/L 08/10/2009 13:05 D-072 Pesticides Mevinphos 0.21 U ug/L 08/10/2009 13:05 D-072 Pesticides Ethoprop 0.11 U ug/L 08/10/2009 13:05 D-072 Pesticides Ethion 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Endrin 0.053 U ug/L 08/10/2009 13:05 D-072 Pesticides Bromacil 0.21 U ug/L 0
35 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 13:05 D-072 Priority Organic Pollutants 2-Chloronaphthalene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2-Nitrophenol 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Acenaphthene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Di-n-octyl phthalate 1.1 UJ ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Dibenzo(a,h)anthracene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Nitrobenzene 2.2 U ug/L 28/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dinitrophenol 16 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Naphthalene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Pyrene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 4-Chloro-3-methylphenol 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(b)fluoranthene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(g,h,i)perylene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Bis(2-chloroethyl)ether 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 16 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Dimethyl phthalate 11 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants N-Nitrosodi-n-propylamine 2.2 U ug/L 28/10/2009 13:05 D-072 Priority Organic Pollutants N-Nitrosodimethylamine 2.2 U ug/L 28/10/2009 13:05 D-072 Priority Organic Pollutants 4-Chlorophenyl phenyl ether 2.2 U ug/L 28/10/2009 13:05 D-072 Priority Organic Pollutants Di-n-butyl phthalate 5.5 U ug/L 58/10/2009 13:05 D-072 Priority Organic Pollutants Diethyl phthalate 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Isophorone 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dichlorophenol 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2-Chlorophenol 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 4-Bromophenyl phenyl ether 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 4-Nitrophenol 16 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Anthracene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(a)anthracene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(k)fluoranthene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Bis(2-chloroisopropyl)ether 3.3 U ug/L 38/10/2009 13:05 D-072 Priority Organic Pollutants Fluoranthene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Hexachlorobenzene 1.1 U ug/L 1
36 

Appendix E. (continued)

Date Field ID Analysis Component Result Remark Units M

8/10/2009 13:05 D-072 Priority Organic Pollutants Hexachlorobutadiene 3.3 U ug/L 38/10/2009 13:05 D-072 Priority Organic Pollutants Hexachlorocyclopentadiene 3.3 U ug/L 38/10/2009 13:05 D-072 Priority Organic Pollutants Pentachlorophenol 3.3 U ug/L 38/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dimethylphenol 11 UJ ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 3,3'-Dichlorobenzidine 44 UJ ug/L 48/10/2009 13:05 D-072 Priority Organic Pollutants Phenol 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 1,2,4-Trichlorobenzene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2,4,6-Trichlorophenol 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Acenaphthylene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Butyl benzyl phthalate 5.5 U ug/L 58/10/2009 13:05 D-072 Priority Organic Pollutants Hexachloroethane 3.3 U ug/L 38/10/2009 13:05 D-072 Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Phenanthrene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2,4-Dinitrotoluene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2,6-Dinitrotoluene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 3.3 U ug/L 38/10/2009 13:05 D-072 Priority Organic Pollutants Benzidine 110 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Benzo(a)pyrene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Bis(2-chloroethoxy)methane 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Chrysene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants Fluorene 1.1 U ug/L 18/10/2009 13:05 D-072 Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 3.3 U ug/L 38/10/2009 13:05 D-072 Field Parameter Dissolved Oxygen 6.55 mg/L 8/10/2009 13:05 D-072 Field Parameter Specific Conductance 46443 umhos/cm 8/10/2009 13:05 D-072 Field Parameter Sample Depth 0.2 m 8/10/2009 13:05 D-072 Field Parameter Temperature 31.83 C 8/10/2009 13:05 D-072 Field Parameter pH 8.07
37 

Appendix F. Facility Summary, Effluent Limits, and Permit Violations 

Recorded on Discharge Monitoring Report 
38 

Appendix F. (continued) 
39 

Appendix F. (continued) 
40 

Appendix F. (continued) 
41 

Appendix F. (continued) 
42 

Appendix F. (continued) 
43 

Appendix F. (continued) 
44 

Appendix F. (continued) 
45 

Appendix F. (continued) 
46 

Appendix F. (continued) 
47 

Appendix F. (continued) 
48 

Appendix F. (continued) 
49 

Appendix F. (continued) 
50 

Appendix G. EPA End Sheet 

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 0 1 5 9 11 12 0 9 0 8 1 0 18 B 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 0 1 5 9 11 12 0 9 0 8 1 0 18 X 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 0 1 5 9 11 12 0 9 0 8 1 0 18 S 19 S 20 2

66

Remarks

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks

The Bioassay of Progress Energy Crystal River Plant units 1, 2, 

and 3 effluent sampled on August 10, 2009. NPDES #FL0000159.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks

The Priority Pollutants Analysis of Progress Energy Crystal River 

Plant units 1, 2, and 3 effluent sampled on August 10, 2009. 

NPDES #FL0000159.

Biological Analyses of Progress Energy Crystal River Plant units 

1, 2, and 3 effluent sampled on August 10, 2009. NPDES # 

FL0000159. 

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)