Bioassays of 

Vero Beach Municipal Power Plant 

Indian River County 

NPDES #FL0002984 

Sampled November 12, 2003 

April 2004

Biology Section 

Bureau of Laboratories 

Division of Resource Assessment and Management

Quality Manual No. 870346G 

NELAC Certification No. E31780
Vero Beach Municipal Power Plant, 100 17th Street, Vero Beach, Indian River County, Florida,

NPDES #FL0002984. Effluent samples for this facility were collected on November 12, 2003. 

Introduction 

This municipal power plant consists of five (5) power-generating units. Units #1, #2, and #3 

having nameplate ratings, respectively, of 12.5, 16.5, and 24 megawatts (MW), use a total of 217 

million gallons per day (MGD) of water from the Indian River as once-through non-contact cooling 

water which is discharged (without treatment) back to the Indian River, a Class III Marine surface 

water, via outfalls D-011, D-012, and D-013 (formerly outfalls 001, 002, and 003). Cooling water 

for the Unit #4 (No Nameplate Rating) cooling tower is treated wastewater obtained from the City 

of Vero Beach Wastewater Treatment Plant (WWTP). Cooling tower blowdown from Unit #4 is 

discharged back to the WWTP. Boiler blowdown, from Units #1, #2, #3, and #4, is also 

discharged to the WWTP. Unit #5 is a combined cycle combustion turbine, with a nameplate 

rating of 38 MW, equipped with a closed auxiliary cooling water system. Wastewater from Unit #5 

is collected in a storage tank, treated, and discharged to the WWTP. There is no discharge from

Unit #5 to waters of the State unless otherwise authorized within the permit. The facility has a 

fuel-oil containment area (D-OB) from which stormwater can be discharged to the Indian River. 

There are also roof and yard drains (D-OS1 through D-OS6) from which stormwater can be 

discharged to the Indian River (facility information provided by Dr. Phil Kane, Allen Hubbard and 

Michael Eckoff, FDEP, Orlando). 

Methods 

Samples were collected from the NPDES sampling point (fuel oil containment area) by Dr. Phil 

Kane and Steve Kent (FDEP Central District-Orlando) following DEP-SOP-001/01 FS 2400 

Wastewater Sampling. All DEP SOP’s are available on the web at: 

http://www.floridadep.org/labs/qa/sops.htm

The toxicity and algal growth potential tests discussed in this report were performed following 

internal DEP SOP’s TA07_01,TA07_02, and TA08_01 through TA08_06. All internal DEP SOP’s 

are available on the web at: http://www.floridadep.org/labs/cgi-bin/sop/biosop.asp

Toxicity Test Results 

Tests were performed November 13-17, 2003. 

Ceriodaphnia dubia 96-hr acute definitive bioassay – Not Toxic; LC50 > 100%, 0% mortality in 

100% sample at 96 hours 

Pimephales promelas 96-hr acute definitive bioassay – Not Toxic; LC50 > 100%, 0% mortality in 

100% sample at 96 hours 

See Table 1 for bioassay bench sheets.

Algal Growth Potential 

The effluent Algal Growth Potential (AGP) was 0.110 mg dry wt/L of Pseudokirchneriella 

subcapitata, formerly known as Selenastrum capricornutum. Raschke and Shultz (1987) found 

that AGP values above 5.0 mg dry weight/L represent a “problem” threshold for fresh receiving 

waters, implying nutrient enrichment. The effluent sample value was less than this "problem" 

threshold. The “problem” threshold for marine receiving waters is 10 mg dry wt/L (personal 

communication- Raschke, USEPA, 1987). Although an AGP test with a saltwater species was not 

performed, the presumption is that the result would have also been less than the "problem" 

threshold of 10 mg dry weight/L in marine waters. The sample value was less than the predicted 

2
AGP values based on the inorganic nitrogen and ortho-phosphate content of the sample (Table 

2). The difference between actual and predicted AGP values that are greater than the "problem" 

threshold can sometimes be used as evidence of inhibition; however, for values below the 

problem threshold, this tool should be used with caution, as the difference may be attributable to 

variability in the method rather than actual algal growth inhibition. 

See Table 2 for AGP results. 

Chemistry Results 

Total residual chlorine and total ammonia were not detected in the bioassay sample in the 

laboratory. Total ammonia was also not detected in the sample preserved specifically for 

ammonia analysis. Aluminum, copper, and zinc were detected in the effluent at levels above the 

method detection limits, but below the practical quantitation limit. 

See Table 3 for results of analytes detected in the effluent. 

See Appendix 1 for a complete list of chemical analyses performed.

Conclusion 

The effluent samples collected from this facility on November 12, 2003, did not show acute 

toxicity to either test species during the 96-hour bioassay tests. The effluent AGP result was less 

than the "problem” threshold for fresh receiving waters. 

Literature Cited 

Maloney, T. E., W. E. Miller, and D. T. Specht. 1974. The Marine Algal Assay Procedure: Bottle Test. 

National Environmental Research Center Office of Research and Development. U. S. EPA, Corvallis, 

Oregon. 43 p. 

Miller, W. E., T. E. Maloney, and J. C. Greene. 1978. The Selenastrum capricornutum Printz algal 

assay bottle test. EPA-600/9-78-018. U. S. EPA, Cincinnati, Ohio. 126 p. 

Miller et al. 1990. The Acute and Chronic Toxicity of Ammonia to Marine Fish and Invertebrates, 

Archives of Environmental Contamination and Toxicology 19:40-48.

Raschke, R. L. and D. A. Schultz. 1987. The use of the algal growth potential test for data 

assessment. J. Wat. Poll. Cont. Fed. 59(4): 222-227. 

Weber, C. I. 1993. Methods for measuring the acute toxicity of effluents to freshwater and marine

organisms. 4th edition. EPA/600/4-90/027. U. S. EPA, Cincinnati, Ohio. 216 pp. 

USEPA. 2000. Nutrient Criteria Technical Guidance Manual – River and Streams. EPA-822-B-00-002. 

USEPA. 2002. Short-term methods for estimating the chronic toxicity of effluents and receiving waters 

to freshwater organisms. 4th Edition. EPA-821-R-02-013 

3
Table 1.

continued

Facility: Vero Beach Municipal Power Plant NPDES #: FL0002984 Analysts: J

Location: 100 17th Street, Vero Beach Contact/District: Phil Kane/Central J

County: Indian River Test type: acute definitive 96 hours renewal M

Sample Collection Date: 11/12/2003 Time: 0930 # tests: 2 Receiving Water: Indian River C

 Test Beginning Date: 11/13/2003 Time: 1430 Chlorination Type: nonchlorinated Class III Marine

Test Ending Date: 11/17/2003 Time: 1330 FDEP SOP#: TA07_01 Page 1 of 4 Reviewer: J

Organism: Ceriodaphnia dubia Life stage: <24 hours AFeeding: YCT/Algae Conductivity

0-48 hours Chamber size: 30mL Food Batch #: 3/20 Uncorrected Job number: T

Sample/Diluent SURVIVAL # Alive pH BTemperature CDO (mg/L) μmhos/cm sample number: 

Concentrations Volume(mL) 0 hr 24 hr 48 hr 0 hour 24 hour 48 hour 0 hour 24 hour 48 hour 0 hour 24 hour 48 hour 0 hour 48 hour

Control A 0/20 5 5 5 8.2 - 8.2 24.0 - 24.0 8.1 - 8.2 170 185Control B 0/20 5 5 5 - - 8.2 - - 24.0 - - 7.9 - 180

Control C 0/20 5 5 5 - - 8.2 - - 24.1 - - 7.9 - 182Control D 0/20 5 5 5 - - 8.2 - - 24.0 - - 8.0 - 190

6.25 % A 1.25/18.75 5 5 5 8.2 - 8.3 24.4 - 24.2 8.0 - 8.4 170 195 Total Residual CL2 6.25 % B 1.25/18.75 5 5 5 - - 8.3 - - 24.0 - - 8.5 - 190 Field (100% sample): 

6.25 % C 1.25/18.75 5 5 5 - - 8.3 - - 24.1 - - 8.4 - 195 Lab (100% sample): 6.25 % D 1.25/18.75 5 5 5 - - 8.3 - - 24.0 - - 8.3 - 207 Control water: 

12.5% A 2.5/17.5 5 5 5 8.2 - 8.3 24.5 - 24.4 7.7 - 8.2 170 19012.5% B 2.5/17.5 5 5 5 - - 8.3 - - 24.3 - - 8.5 - 190 Ammonia 

12.5% C 2.5/17.5 5 3 3 - - 8.3 - - 24.0 - - 8.4 - 198 Control water: 12.5% D 2.5/17.5 5 5 5 - - 8.3 - - 24.2 - - 8.3 - 206 100% Sample: 

25% A 5/15 5 5 5 8.3 - 8.4 24.4 - 24.0 7.8 - 8.2 170 19525% B 5/15 5 5 5 - - 8.4 - - 24.0 - - 8.1 - 192 Alk & Hardness 

25% C 5/15 5 5 5 - - 8.4 - - 23.9 - - 8.1 - 194 Control water: 25% D 5/15 5 5 5 - - 8.4 - - 24.1 - - 8.1 - 208 100% Sample: 

50% A 10/10 5 5 5 8.3 - 8.3 24.3 - 24.0 7.8 - 8.1 170 18050% B 10/10 5 5 5 - - 8.3 - - 24.0 - - 8.1 - 187 DSalinity 

50% C 10/10 5 5 5 - - 8.3 - - 24.2 - - 8.1 - 182 100% sample: 50% D 10/10 5 5 5 - - 8.3 - - 24.1 - - 8.3 - 205 Control: 

100% A 20/0 5 5 5 8.4 - 8.3 24.5 - 24.3 7.9 - 8.3 165 180 DSalinity based on conductiv

100% B 20/0 5 5 5 - - 8.3 - - 24.2 - - 8.3 - 171

100% C 20/0 5 5 5 - - 8.3 - - 24.0 - - 8.1 - 183100% D 20/0 5 5 5 - - 8.3 - - 24.1 - - 8.1 - 179

AOrganisms fed prior to testing and before renewal. Room Temperature range for the test period was 23.0 - 24.5°C.BTemperatures of room and test incubator were continuously recorded on a strip chart. Incubator #3 temperature range for the test period was 23.0 - 24.5 °C.CDO = Dissolved Oxygen Light Intensity during the test was 50-100 foot candles.

Photoperiod during the test was 16 hours of light : 8 hours of dark.

Data recorded during the 96-hour acute definitive bioassays of a sample of effluent from the Vero Beach Municipal Power Plant, 100 17th Street, Vero NPDES# FL0002984, performed from 13 to 17 November 2003.

Data T

by: Jam

Facility Type: Municipal Power Plant

4
Table 1.

continued

Facility: Vero Beach Municipal Power Plant NPDES #: FL0002984 Analysts: J

Location: 100 17th Street, Vero Beach Contact/District: Phil Kane/Central J

County: Indian River Test type: acute definitive 96 hours renewal 

Sample Collection Date: 11/12/2003 Time: 0930 # tests: 2 Receiving Water: Indian River C

 Test Beginning Date: 11/13/2003 Time: 1430 Chlorination Type: nonchlorinated Class III Marine

Test Ending Date: 11/17/2003 Time: 1330 FDEP SOP#: TA07_01 Page 2 of 4 Reviewer: J

Organism: Ceriodaphnia dubia Life stage: <24 hours AFeeding: YCT/Algae Conductivity

48 - 96 hours Chamber size: 30mL Food Batch #: 2 / 19 Uncorrected Job number: T

Sample/Diluent SURVIVAL # Alive pH TemperatureB CDO (mg/L) μmhos/cm sample number: 

Concentrations Volume(mL) 48 hr 72 hr 96 hr 48 hr 72 hr 96 hr 48 hr 72 hr 96 hr 48 hr 72 hr 96 hr 48 hr 96 hr

Control A 0/20 5 5 5 8.3 - 8.0 24.0 - 24.1 7.8 - 7.8 165 185Control B 0/20 5 5 5 - - 8.1 - - 24.1 - - 7.7 - 190

Control C 0/20 5 5 5 - - 8.1 - - 24.0 - - 7.7 - 190Control D 0/20 5 5 5 - - 8.1 - - 24.0 - - 7.6 - 205

6.25 % A 1.25/18.75 5 5 5 8.4 - 8.2 24.1 - 24.0 7.8 - 7.7 165 210 Total Residual CL2 6.25 % B 1.25/18.75 5 5 5 - - 8.2 - - 24.0 - - 7.6 - 200 Field (100% sample): 

6.25 % C 1.25/18.75 5 5 5 - - 8.2 - - 24.0 - - 7.6 - 200 Lab (100% sample): 6.25 % D 1.25/18.75 5 5 5 - - 8.2 - - 24.0 - - 7.6 - 205 Control water: 

12.5% A 2.5/17.5 5 5 5 8.4 - 8.2 24.0 - 24.1 7.9 - 7.8 160 21012.5% B 2.5/17.5 5 5 5 - - 8.2 - - 24.1 - - 7.7 - 200 Ammonia 

12.5% C 2.5/17.5 3 3 3 - - 8.2 - - 24.0 - - 7.6 - 200 Control water 12.5% D 2.5/17.5 5 5 5 - - 8.2 - - 24.0 - - 7.7 - 205 100% Sample: 

25% A 5/15 5 5 5 8.4 - 8.3 24.2 - 24.0 8.0 - 7.7 165 20025% B 5/15 5 5 5 - - 8.3 - - 24.0 - - 7.7 - 195 Alk & Hardness 

25% C 5/15 5 5 5 - - 8.3 - - 24.0 - - 7.7 - 195 Control water 25% D 5/15 5 5 5 - - 8.3 - - 24.0 - - 7.7 - 205 100% Sample: 

50% A 10/10 5 5 5 8.4 - 8.3 24.2 - 24.0 8.1 - 7.8 160 20050% B 10/10 5 5 5 - - 8.3 - - 24.1 - - 7.7 - 190 

50% C 10/10 5 5 5 - - 8.3 - - 24.0 - - 7.7 - 195 50% D 10/10 5 5 5 - - 8.3 - - 24.0 - - 7.8 - 210 

100% A 20/0 5 5 5 8.4 - 8.2 24.2 - 24.1 8.3 - 7.7 165 190100% B 20/0 5 5 5 - - 8.2 - - 24.1 - - 7.7 - 195 D Salinity 

100% C 20/0 5 5 5 - - 8.2 - - 24.0 - - 7.7 - 200 100% sample: 100% D 20/0 5 5 5 - - 8.2 - - 24.0 - - 7.7 - 220 Control: 

D Salinity based on conduc

AOrganisms fed prior to testing and before renewal. Room Temperature range for the test period was 23.0 - 24.5°C.BTemperatures of room and test incubator were continuously recorded on a strip chart. Incubator #3 temperature range for the test period was 23.0 - 24.5 °C.CDO = Dissolved Oxygen Light Intensity during the test was 50-100 foot candles.

Photoperiod during the test was 16 hours of light : 8 hours of dark.

Mortal

Control water (w

100% (wat

Data recorded during the 96-hour acute definitive bioassays of a sample of effluent from the Vero Beach Municipal Power Plant, 100 17th StrCounty, Florida, NPDES# FL0002984, performed from 13 to 17 November 2003.

Data T

by: Jam

Facility Type: Municipal Power Plant

5
Table 1.

continued

Facility: Vero Beach Municipal Power Plant NPDES #: FL0002984 Analysts

Location: 100 17th Street, Vero Beach Contact/District: Phil Kane/Central 

County: Indian River Test type: acute definitive 96 hours renewal 

Sample Collection Date: 11/12/2003 Time: 0930 # tests: 2 Receiving Water: Indian River 

 Test Beginning Date: 11/13/2003 Time: 1430 Chlorination Type: nonchlorinated Class III Marine

Test Ending Date: 11/17/2003 Time: 1330 FDEP SOP#: TA07_02 Page 3 of 4 Reviewer

Organism: Pimephales promelas Life stage: 3 days AFeeding: Artemia Conductivity

0 - 48 hours Chamber size: 1000 ml Food Batch #: 0194025G Uncorrected Job number

Sample/Diluent SURVIVAL # Alive pH BTemperature CDO (mg/L) μmhos/cm sample number

Concentrations Volume(mL) 0 hr 24 hr 48 hr 0 hour 24 hour 48 hour 0 hour 24 hour 48 hour 0 hour 24 hour 48 hour 0 hour 48 hour

Control A 0/20 10 10 10 8.0 - 8.1 24.0 - 24.4 8.3 - 7.9 274 295Control B 0/20 10 10 10 - 7.9 - - 25.4 - - 7.0 - - -

6.25 % A 1.25/18.75 10 10 10 8.1 - 8.1 24.1 - 24.1 7.9 - 7.8 284 2906.25 % B 1.25/18.75 10 10 10 - 8.0 - - 24.8 - - 7.3 - - -

12.5% A 2.5/17.5 10 10 10 8.1 - 8.1 24.1 - 24.2 8.0 - 7.8 275 282 Total Residual CL2 12.5% B 2.5/17.5 10 10 10 - 8.0 - - 24.5 - - 7.4 - - - Field (100% sample): 

25% A 5/15 10 10 10 8.1 - 8.1 24.2 - 24.0 8.1 - 7.8 256 268 Lab (100% sample): 25% B 5/15 10 10 10 - 8.0 - - 24.1 - - 7.4 - - - Control water: 50% A 10/10 10 10 10 8.1 - 8.1 24.5 - 24.0 8.0 - 7.8 237 23350% B 10/10 10 10 10 - 8.0 - - 24.2 - - 7.6 - - - Ammonia 

100% A 20/0 10 10 10 8.1 - 8.1 24.8 - 24.2 7.9 - 7.7 163 175 Control water100% B 20/0 10 10 10 - 8.0 - - 24.0 - - 7.5 - - - 100% Sample

AOrganisms fed prior to testing and before renewal. Room Temperature range for the test period was 23.0 - 24.5 °C. Alk & Hardness BTemperatures of room and test incubator were continuously recorded Incubator #3 temperature range for the test period was 23.0 - 24.5°C. Control waterCDO = Dissolved Oxygen Light Intensity during the test was 50-100 foot candles. 100% Sample

Photoperiod during the test was 16 hours of light : 8 hours of dark.

D Salinity 

 100% sample

Control

D Salinity based on cond

by: J

Data recorded during the 96-hour acute definitive bioassays of a sample of effluent from the Vero Beach Municipal Power Plant, 100 17th Street, VFlorida, NPDES# FL0002984, performed from 13 to 17 November 2003.

Dat

Facility Type: Municipal Power Plant

6
Table 1.

concluded.

Facility: Vero Beach Municipal Power Plant NPDES #: FL0002984 Analysts: Jos

Location: 100 17th Street, Vero Beach Contact/District: Phil Kane/Central Jam

County: Indian River Test type: acute definitive 96 hours renewal Ma

Sample Collection Date: 11/12/2003 Time: 0930 # tests: 2 Receiving Water: Indian River Ch

 Test Beginning Date: 11/13/2003 Time: 1430 Chlorination Type: nonchlorinated Class III Marine

Test Ending Date: 11/17/2003 Time: 1330 FDEP SOP#: TA07_02 Page 4 of 4 Reviewer: Jul

Organism: Pimephales promelas Life stage: 12 days AFeeding: Artemia Conductivity

48 - 96 hours Chamber size: 1000 ml Food Batch #: 0194025G Uncorrected Job number: TL

Sample/Diluent SURVIVAL # Alive pH TemperatureB DO (mg/L) μmhos/cm sample number: 

Concentrations Volume(mL) 48 hr 72 hr 96 hr 48 hr 72 hr 96 hr 48 hr 72 hr 96 hr 48 hr 72 hr 96 hr 48 hr 96 hr

Control A 0/20 10 10 10 - 8.1 8.1 - 24.2 25.3 - 8.0 7.8 - 325Control B 0/20 10 10 10 8.1 - 8.1 24.5 - 25.9 8.0 - 7.7 290 335

6.25 % A 1.25/18.75 10 10 10 - 8.1 8.0 - 24.4 25.2 - 7.4 7.3 - 3106.25 % B 1.25/18.75 10 10 10 8.1 - 8.0 24.5 - 24.7 7.7 - 7.1 294 310

12.5% A 2.5/17.5 10 10 10 - 8.1 8.0 - 24.7 24.5 - 7.2 7.2 - 295 Total Residual CL2 12.5% B 2.5/17.5 10 10 10 8.2 - 8.0 24.3 - 24.9 7.7 - 7.1 213 305 Field (100% sample): 

25% A 5/15 10 10 10 - 8.1 7.9 - 24.8 24.1 - 7.6 7.1 - 280 Lab (100% sample): 25% B 5/15 10 10 10 8.2 - 7.9 24.2 - 25.9 7.8 - 7.1 270 300 Control water: 50% A 10/10 10 10 10 - 8.1 8.0 - 25.1 25.5 - 7.7 7.1 - 25550% B 10/10 10 10 10 8.2 - 8.0 24.2 - 24.7 7.8 - 7.1 235 245 Ammonia 

100% A 20/0 10 10 10 - 8.1 7.9 - 24.9 24.0 - 7.3 7.2 - 180 Control water: 100% B 20/0 10 10 10 8.2 - 7.9 24.1 - 24.1 7.9 - 7.4 170 180 100% Sample: 

AOrganisms fed prior to testing and before renewal. Room Temperature range for the test period was 23.0 - 24.5 °C. Alk & Hardness AlBTemperatures of room and test incubator were continuously recorded Incubator #3 temperature range for the test period was 23.0 - 24.5°C. Control water: CDO = Dissolved Oxygen Light Intensity during the test was 50-100 foot candles. 100% Sample: 

Photoperiod during the test was 16 hours of light : 8 hours of dark.

D Salinity 

 100% sample: 

Control: 

D Salinity based on conductivit

100%:

by: Jam

Mortality

Control wat

Data recorded during the 96-hour acute definitive bioassays of a sample of effluent from the Vero Beach Municipal Power Plant, 100 17th Stree

Florida, NPDES# FL0002984, performed from 13 to 17 November 2003.

Data Tra

Facility Type: Municipal Power Plant

7
Table 2. Measured and predicted algal growth potential (AGP) of P.subcapitata for total soluble 

inorganic nitrogen (TSIN) and ortho phosphate (OP) limitation in the sample of effluent

from the Vero Beach Municipal Power Plant.

Location AGP (measured) Predicted AGP (TSIN) ± 

20% Predicted AGP (OP) ± 20% Inorganic N:P ratio

Effluent 

Samples 0.110 0.57 ± 0.114 8.6 ± 1.72 0.75

8
Table 3. Effluent limits, Class III Criteria and chemical data from samples collected from the 

 Vero Beach Municipal Power Plant on 12 November, 2003.

Vero Beach Municipal Power Plant Class III Marine 

Stds Effluent

None Detected - -

Aluminum ≤ 1500 17 I

Arsenic ≤ 50 9.8 U

Cadmium ≤ 9.3 0.025 U

Calcium (mg/L) - 21.1

Chromium-III - 3 U

Copper ≤ 3.7 3.6 I

Iron ≤ 300 15 U

Lead ≤ 8.5 0.05 U

Magnesium (mg/L) - 1.6

Nickel ≤ 8.3 3 U

Selenium ≤ 7.1 1 U

Silver - 0.02 U

Zinc ≤ 86 6.5 I

Ortho-phosphate - 0.02

Total Phosphorus - 0.02 U

Ammonia - 0.01 U

Unionized Ammonia - -

Nitrate+Nitrite - 0.015

Total Kjeldahl Nitrogen - 0.19 I

Organic Nitrogen - 0.19 c

Total Nitrogen - 0.2 c

Hardness (mg/L) - 59.3 c

AGP (mg DryWt/L) - 0.11 I

Total Residual Chlorine (Lab) ≤ 0.01 < 0.03 p

Total Residual Chlorine (Field) ≤ 0.01 -

c - calculated value.

I - The reported value is between the laboratory method detection limit and the laboratory

practical quantitation limit.

p - Material analyzed for and not detected. Value reported (0.03) is the laboratory minimum detection value.

U - Material was analyzed for but not detected. The value reported is the minimum detection limit.

General Physical and Chemical Parameters

Organic Constituents (μg/L)

Metals (μg/L unless otherwise noted)

Nutrients (mg/L)

9
Appendix 1. Chemical Analyses performed on the effluent from the Vero Beach Municipal Power Plant

sampled on November 12, 2003.

Date Sampled Field ID Analysis Group Component Result Units Remark MDL PQL

11/12/2003 9:30 VBP BNA-Water 1,2,4,5-Tetrachlorobenzene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 1,2,4-Trichlorobenzene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 1,2-Dichlorobenzene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 1,3,5-Trinitrobenzene 3.8 ug/L U 3.8 15

11/12/2003 9:30 VBP BNA-Water 1,3-Dichlorobenzene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 1,3-Dinitrobenzene 1.9 ug/L U 1.9 7.6

11/12/2003 9:30 VBP BNA-Water 1,4-Dichlorobenzene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 1,4-Naphthoquinone 19 ug/L U 19 76

11/12/2003 9:30 VBP BNA-Water 1-Naphthylamine 9.5 ug/L UJ 9.5 38

11/12/2003 9:30 VBP BNA-Water 2,3,4,6-Tetrachlorophenol 1.9 ug/L UJ 1.9 7.6

11/12/2003 9:30 VBP BNA-Water 2,4,5-Trichlorophenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2,4,6-Trichlorophenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2,4-Dichlorophenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2,4-Dimethylphenol 48 ug/L U 48 190

11/12/2003 9:30 VBP BNA-Water 2,4-Dinitrophenol 14 ug/L U 14 57

11/12/2003 9:30 VBP BNA-Water 2,4-Dinitrotoluene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2,6-Dichlorophenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2,6-Dinitrotoluene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Acetylaminofluorene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Chloronaphthalene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Chlorophenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Methyl-4,6-dinitrophenol 2.9 ug/L U 2.9 11

11/12/2003 9:30 VBP BNA-Water 2-Methylnaphthalene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Naphthylamine 9.5 ug/L U 9.5 38

11/12/2003 9:30 VBP BNA-Water 2-Nitroaniline 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Nitrophenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 2-Picoline 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 3,3'-Dichlorobenzidine 38 ug/L U 38 150

11/12/2003 9:30 VBP BNA-Water 3,3'-Dimethylbenzidine 19 ug/L U 19 76

11/12/2003 9:30 VBP BNA-Water 3-Methylcholanthrene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 3-Nitroaniline 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 4,4'-DDD 1.4 ug/L U 1.4 5.7

11/12/2003 9:30 VBP BNA-Water 4,4'-DDE 1.4 ug/L U 1.4 5.7

11/12/2003 9:30 VBP BNA-Water 4,4'-DDT 1.4 ug/L U 1.4 5.7

11/12/2003 9:30 VBP BNA-Water 4-Aminobiphenyl 3.8 ug/L UJ 3.8 15

11/12/2003 9:30 VBP BNA-Water 4-Bromophenyl phenyl ether 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 4-Chloro-3-methylphenol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 4-Chloroaniline 0.95 ug/L UJ 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 4-Chlorophenyl phenyl ether 1.9 ug/L U 1.9 7.6

11/12/2003 9:30 VBP BNA-Water 4-Nitroaniline 0.95 ug/L UJ 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 4-Nitrophenol 14 ug/L U 14 57

11/12/2003 9:30 VBP BNA-Water 5-Nitro-o-toluidine 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water 7,12-Dimethylbenz(a)anthracene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Acenaphthene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Acenaphthylene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Acetophenone 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Aldrin 1.4 ug/L UJ 1.4 5.7

11/12/2003 9:30 VBP BNA-Water Aniline 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Anthracene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Azobenzene/1,2-Diphenylhydrazine 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Benzidine 95 ug/L U 95 380

11/12/2003 9:30 VBP BNA-Water Benzo(a)anthracene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Benzo(a)pyrene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Benzo(b)fluoranthene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Benzo(g,h,i)perylene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Benzo(k)fluoranthene 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Benzyl alcohol 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Bis(2-chloroethoxy)methane 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Bis(2-chloroethyl)ether 0.95 ug/L U 0.95 3.8

11/12/2003 9:30 VBP BNA-Water Bis(2-chloroisopropyl)ether 2.9 ug/L U 2.9 11

11/12/2003 9:30 VBP BNA-Water Bis(2-ethylhexyl)phthalate 14 ug/L U 14 57

11/12/2003 9:30 VBP BNA-Water Butyl benzyl phthalate 4.8 ug/L U 4.8 19

10
11/12/2003 9:30

VBPBNA-WaterChrysene 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterDi-n-butylphthalate4.8 ug/LU4.8 19

11/12/2003 9:30VBPBNA-WaterDi-noctyl phthalate0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterDibenzo(a,h)anthracene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterDibenzofuran0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterDieldrin1.4 ug/LU1.4 5.7

11/12/2003 9:30VBPBNA-WaterDiethylphthalate0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterDimethyl phthalate48ug/LU48 190

11/12/2003 9:30VBPBNA-WaterDimethylaminoazobenzene 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterDinoseb3.8ug/LUJ3.8 15

11/12/2003 9:30VBPBNA-WaterDiphenylamine2.9ug/LU 2.911

11/12/2003 9:30VBPBNA-WaterEndosulfanI3.8 ug/LU3.8 15

11/12/2003 9:30VBPBNA-WaterEndosulfan II3.8ug/LU 3.815

11/12/2003 9:30VBPBNA-WaterEndosulfan sulfate1.4 ug/LU1.4 5.7

11/12/2003 9:30VBPBNA-WaterEndrin1.4 ug/L UJ 1.45.7

11/12/2003 9:30VBPBNA-WaterEndrin aldehyde3.8ug/LU 3.815

11/12/2003 9:30VBPBNA-WaterEthyl methanesulfonate 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterFluoranthene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterFluorene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterHeptachlor1.4 ug/LU1.4 5.7

11/12/2003 9:30VBPBNA-WaterHeptachlor epoxide1.4 ug/LU1.4 5.7

11/12/2003 9:30VBPBNA-WaterHexachlorobenzene 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterHexachlorobutadiene2.9ug/LU 2.911

11/12/2003 9:30VBPBNA-WaterHexachlorocyclopentadiene2.9ug/LUJ2.9 11

11/12/2003 9:30VBPBNA-WaterHexachloroethane2.9 ug/LU2.9 11

11/12/2003 9:30VBPBNA-WaterHexachloropropene1.9ug/LUJ1.9 7.6

11/12/2003 9:30VBPBNA-WaterIndeno(1,2,3-cd)pyrene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterIsophorone0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterIsosafrole0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterMethapyrilene3.8ug/LU 3.815

11/12/2003 9:30VBPBNA-WaterMethyl methanesulfonate 0.95 ug/L UJ 0.95 3.8

11/12/2003 9:30VBPBNA-WaterN-Nitrosodi-n-butylamine0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterN-Nitrosodi-n-propylamine1.9ug/LU 1.97.6

11/12/2003 9:30VBPBNA-WaterN-Nitrosodiethylamine 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterN-Nitrosodimethylamine1.9 ug/LU1.9 7.6

11/12/2003 9:30VBPBNA-WaterN-Nitrosodiphenylamine2.9 ug/L UJ 2.911

11/12/2003 9:30VBPBNA-WaterN-Nitrosomethylethylamine1.9ug/LU 1.97.6

11/12/2003 9:30VBPBNA-WaterN-Nitrosomorpholine0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterN-Nitrosopiperidine 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterN-Nitrosopyrrolidine1.9 ug/LU1.9 7.6

11/12/2003 9:30VBPBNA-WaterNaphthalene 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-WaterNitrobenzene1.9 ug/LU1.9 7.6

11/12/2003 9:30VBPBNA-WaterNitroquinoline1-oxide19ug/LUJ1976

11/12/2003 9:30VBPBNA-WaterPentachlorobenzene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterPentachloroethane48 ug/LU48190

11/12/2003 9:30VBPBNA-WaterPentachloronitrobenzene 0.95 ug/L UJ 0.95 3.8

11/12/2003 9:30VBPBNA-WaterPentachlorophenol2.9ug/LUJ2.9 11

11/12/2003 9:30VBPBNA-WaterPhenacetin3.8 ug/LU3.8 11

11/12/2003 9:30VBPBNA-WaterPhenanthrene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterPhenol0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterPyrene0.95ug/LU 0.95 3.8

11/12/2003 9:30VBPBNA-WaterPyridine3.8 ug/LU3.8 15

11/12/2003 9:30VBPBNA-WaterSafrole 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBNA-Wateralpha-BHC1.4ug/LU 1.45.7

11/12/2003 9:30VBPBNA-Waterbeta-BHC1.4 ug/LU1.4 5.7

11/12/2003 9:30VBPBNA-Waterdelta-BHC1.4ug/LU 1.45.7

11/12/2003 9:30VBPBNA-Watergamma-BHC1.4ug/LU 1.45.7

11/12/2003 9:30VBPBNA-Waterm,p-Cresols1.9ug/LU 1.97.6

11/12/2003 9:30VBPBNA-Watero-Cresol1.9 ug/LU1.9 7.6

11/12/2003 9:30VBPBNA-Watero-Toluidine 0.95 ug/LU0.953.8

11/12/2003 9:30VBPBio-AGP/LimNut Algal Growth Potential0.11mg DryWt/LI0.1 0.3

11/12/2003 9:30VBP Bio-Chl-aChlorophyll-A, Monochromatic, Water0.85ug/LU 0.85 2.6

11/12/2003 9:30VBP Bio-Chl-aPhaeophytin-A, Monochromatic, Water0.85ug/LU 0.85 2.6

11/12/2003 9:30VBP Bio-ToxicologyBioassay-Acute-Def-FW-C.dubia, LC50 100LC50L

11/12/2003 9:30VBP Bio-Toxicology Bioassay-Acute-Def-FW-Fish, LC50 100LC50L

11/12/2003 9:30VBP GC-WaterAlachlor 0.57 ug/LU0.572.28

11
11/12/2003 9:30 VBP GC-Water Ametry

n0.048ug/LU0.0480.192

11/12/2003 9:30 VBP GC-Water Atrazine 0.048ug/LU 0.0480.192

11/12/2003 9:30 VBP GC-Water Azinphos Methyl0.048ug/LUJ0.0480.192

11/12/2003 9:30 VBP GC-WaterBromacil 0.19ug/LU0.190.76

11/12/2003 9:30 VBP GC-Water Butylate 0.19ug/L UJ0.19 0.76

11/12/2003 9:30 VBP GC-Water Chlorpyrifos Ethyl0.048ug/LU0.0480.192

11/12/2003 9:30 VBP GC-Water Chlorpyrifos Methyl0.095ug/LU0.0950.38

11/12/2003 9:30 VBP GC-Water Diazinon0.048ug/LU0.0480.192

11/12/2003 9:30 VBP GC-Water Ethion0.048ug/LU0.0480.192

11/12/2003 9:30 VBP GC-Water Ethoprop0.095ug/LU0.095 0.38

11/12/2003 9:30 VBP GC-Water Fenamiphos 0.19ug/L UJ0.19 0.76

11/12/2003 9:30 VBP GC-Water Fonofos0.095ug/LU0.095 0.38

11/12/2003 9:30 VBP GC-Water Hexazinone0.095ug/LU0.0950.38

11/12/2003 9:30 VBP GC-WaterMalathion0.14ug/LU0.14 0.56

11/12/2003 9:30 VBP GC-Water Metalaxyl0.24ug/LU0.24 0.96

11/12/2003 9:30 VBP GC-Water Metolachlor0.48ug/LU0.48 1.92

11/12/2003 9:30 VBP GC-Water Metribuzin0.095ug/LU0.0950.38

11/12/2003 9:30 VBP GC-Water Mevinphos0.19ug/LUJ0.190.76

11/12/2003 9:30 VBP GC-Water Naled0.76ug/LU0.76 3.04

11/12/2003 9:30 VBP GC-Water Norflurazon0.095ug/LU0.095 0.38

11/12/2003 9:30 VBP GC-Water Parathion Ethyl0.14ug/LU0.14 0.56

11/12/2003 9:30 VBP GC-Water Parathion Methyl0.095ug/LU0.0950.38

11/12/2003 9:30 VBP GC-WaterPhorate0.048ug/L UJ0.0480.192

11/12/2003 9:30 VBP GC-Water Prometryn0.14ug/LU 0.140.56

11/12/2003 9:30 VBP GC-Water Simazine0.048ug/LU0.0480.192

11/12/2003 9:30 VBP Metals-Water Aluminum17ug/LI7 28

11/12/2003 9:30 VBP Metals-WaterArsenic9.8ug/LU9.8 39

11/12/2003 9:30 VBP Metals-Water Cadmium0.025ug/LU0.025 0.1

11/12/2003 9:30 VBP Metals-Water Calcium21.1mg/L0.050.2

11/12/2003 9:30 VBP Metals-Water Chromium3ug/LU312

11/12/2003 9:30 VBP Metals-Water Copper3.6ug/LI14

11/12/2003 9:30 VBP Metals-Water Iron15ug/LU1560

11/12/2003 9:30 VBP Metals-Water Lead 0.05ug/LU0.050.2

11/12/2003 9:30 VBP Metals-Water Magnesium1.6mg/L0.02 0.08

11/12/2003 9:30 VBP Metals-Water Nickel3ug/LU312

11/12/2003 9:30 VBP Metals-Water Selenium1ug/LU14

11/12/2003 9:30 VBP Metals-Water Silver 0.02ug/LU0.020.08

11/12/2003 9:30 VBP Metals-Water Zinc6.5ug/LI416

11/12/2003 9:30 VBP Nutrients-LiquidAmmonia-N0.01mg N/LU0.01 0.02

11/12/2003 9:30 VBP Nutrients-Liquid NO2NO3-N0.015mg N/L0.004 0.01

11/12/2003 9:30 VBP Nutrients-Liquid N_KJEL_TOT 0.19mg N/LI0.06 0.2

11/12/2003 9:30 VBP Nutrients-Liquid O-Phosphate-P0.02mg P/L0.004 0.01

11/12/2003 9:30 VBP Nutrients-LiquidTotal-P0.02mg P/LU0.02 0.06

11/12/2003 9:30 VBP BLANKBNA-Water 1,2,4,5-Tetrachlorobenzene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 1,2,4-Trichlorobenzene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 1,2-Dichlorobenzene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 1,3,5-Trinitrobenzene3.8 ug/LU3.8 15

11/12/2003 9:30 VBP BLANKBNA-Water 1,3-Dichlorobenzene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 1,3-Dinitrobenzene 1.9ug/LU 1.97.7

11/12/2003 9:30 VBP BLANKBNA-Water 1,4-Dichlorobenzene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 1,4-Naphthoquinone 19 ug/LU1977

11/12/2003 9:30 VBP BLANKBNA-Water 1-Naphthylamine9.6 ug/L UJ 9.638

11/12/2003 9:30 VBP BLANKBNA-Water 2,3,4,6-Tetrachlorophenol1.9 ug/L UJ 1.97.7

11/12/2003 9:30 VBP BLANKBNA-Water 2,4,5-Trichlorophenol 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2,4,6-Trichlorophenol 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2,4-Dichlorophenol 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2,4-Dimethylphenol48ug/LU 48 190

11/12/2003 9:30 VBP BLANKBNA-Water 2,4-Dinitrophenol14ug/LU 14 58

11/12/2003 9:30 VBP BLANKBNA-Water 2,4-Dinitrotoluene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2,6-Dichlorophenol 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2,6-Dinitrotoluene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2-Acetylaminofluorene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 2-Chloronaphthalene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 2-Chlorophenol 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 2-Methyl-4,6-dinitrophenol 2.9ug/LU 2.912

11/12/2003 9:30 VBP BLANKBNA-Water 2-Methylnaphthalene0.96ug/LU 0.96 3.8

12
11/

12/2003 9:30 VBP BLANKBNA-Water 2-Naphthylamine9.6 ug/LU9.6 38

11/12/2003 9:30 VBP BLANKBNA-Water 2-Nitroaniline0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 2-Nitrophenol0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 2-Picoline0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 3,3'-Dichlorobenzidine 38 ug/LU38150

11/12/2003 9:30 VBP BLANKBNA-Water 3,3'-Dimethylbenzidine 19 ug/LU1977

11/12/2003 9:30 VBP BLANKBNA-Water 3-Methylcholanthrene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 3-Nitroaniline0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 4,4'-DDD 1.4ug/LU 1.45.8

11/12/2003 9:30 VBP BLANKBNA-Water 4,4'-DDE 1.4ug/LU 1.45.8

11/12/2003 9:30 VBP BLANKBNA-Water 4,4'-DDT 1.4ug/LU 1.45.8

11/12/2003 9:30 VBP BLANKBNA-Water 4-Aminobiphenyl3.8 ug/L UJ 3.815

11/12/2003 9:30 VBP BLANKBNA-Water 4-Bromophenyl phenyl ether0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 4-Chloro-3-methylphenol0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 4-Chloroaniline0.96ug/LUJ0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 4-Chlorophenyl phenyl ether1.9 ug/LU1.9 7.7

11/12/2003 9:30 VBP BLANKBNA-Water 4-Nitroaniline0.96ug/LUJ0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water 4-Nitrophenol14ug/LU 14 58

11/12/2003 9:30 VBP BLANKBNA-Water 5-Nitro-o-toluidine0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water 7,12-Dimethylbenz(a)anthracene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Acenaphthene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-WaterAcenaphthylene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Acetophenone 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Aldrin 1.4ug/LUJ1.4 5.8

11/12/2003 9:30 VBP BLANKBNA-Water Aniline0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water Anthracene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Azobenzene/1,2-Diphenylhydrazine 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Benzidine96ug/LU 96 380

11/12/2003 9:30 VBP BLANKBNA-Water Benzo(a)anthracene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Benzo(a)pyrene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Benzo(b)fluoranthene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water Benzo(g,h,i)perylene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Benzo(k)fluoranthene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Benzyl alcohol0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water Bis(2-chloroethoxy)methane 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Bis(2-chloroethyl)ether0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water Bis(2-chloroisopropyl)ether2.9 ug/LU2.9 12

11/12/2003 9:30 VBP BLANKBNA-Water Bis(2-ethylhexyl)phthalate 14 ug/LU1458

11/12/2003 9:30 VBP BLANKBNA-WaterButyl benzyl phthalate4.8 ug/LU4.8 19

11/12/2003 9:30 VBP BLANKBNA-Water Chrysene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Din-butyl phthalate4.8 ug/LU4.8 19

11/12/2003 9:30 VBP BLANKBNA-WaterDi-n-octyl phthalate0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-WaterDibenzo(a,h)anthracene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-WaterDibenzofuran 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-WaterDieldrin 1.4ug/LU 1.45.8

11/12/2003 9:30 VBP BLANKBNA-Water Diethyl phthalate0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-WaterDimethyl phthalate48ug/LU 48 190

11/12/2003 9:30 VBP BLANKBNA-Water Dimethylaminoazobenzene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water Dinoseb3.8 ug/L UJ 3.815

11/12/2003 9:30 VBP BLANKBNA-WaterDiphenylamine2.9 ug/LU2.9 12

11/12/2003 9:30 VBP BLANKBNA-Water Endosulfan I3.8 ug/LU3.8 15

11/12/2003 9:30 VBP BLANKBNA-Water Endosulfan II 3.8ug/LU 3.815

11/12/2003 9:30 VBP BLANKBNA-Water Endosulfan sulfate1.4 ug/LU1.4 5.8

11/12/2003 9:30 VBP BLANKBNA-Water Endrin 1.4ug/LUJ1.4 5.8

11/12/2003 9:30 VBP BLANKBNA-Water Endrin aldehyde 3.8ug/LU 3.815

11/12/2003 9:30 VBP BLANKBNA-Water Ethyl methanesulfonate 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-WaterFluoranthene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-WaterFluorene 0.96 ug/LU0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water Heptachlor 1.4ug/LU 1.45.8

11/12/2003 9:30 VBP BLANKBNA-Water Heptachlor epoxide 1.4ug/LU 1.45.8

11/12/2003 9:30 VBP BLANKBNA-Water Hexachlorobenzene0.96ug/LU 0.96 3.8

11/12/2003 9:30 VBP BLANKBNA-Water Hexachlorobutadiene2.9 ug/LU2.9 12

11/12/2003 9:30 VBP BLANKBNA-Water Hexachlorocyclopentadiene2.9 ug/L UJ 2.912

11/12/2003 9:30 VBP BLANKBNA-Water Hexachloroethane 2.9ug/LU 2.912

11/12/2003 9:30 VBP BLANKBNA-WaterHexachloropropene 1.9ug/LUJ1.9 7.7

11/12/2003 9:30 VBP BLANKBNA-Water Indeno(1,2,3-cd)pyrene 0.96 ug/LU0.963.8

13
1

1/12/2003 9:30VBP BLANKBNA-Water Isophorone 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-Water Isosafrole 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-Water Methapyrilene3.8 ug/LU3.8 15

11/12/2003 9:30VBP BLANKBNA-WaterMethyl methanesulfonate 0.96 ug/L UJ 0.963.8

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosodi-n-butylamine 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosodi-n-propylamine1.9 ug/LU1.97.7

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosodiethylamine0.96ug/LU 0.963.8

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosodimethylamine 1.9ug/LU1.97.7

11/12/2003 9:30 VBP BLANKBNA-WaterN-Nitrosodiphenylamine2.9ug/LUJ2.912

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosomethylethylamine1.9 ug/LU1.97.7

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosomorpholine0.96ug/LU 0.963.8

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosopiperidine0.96ug/LU 0.963.8

11/12/2003 9:30VBP BLANKBNA-Water N-Nitrosopyrrolidine1.9 ug/LU1.97.7

11/12/2003 9:30VBP BLANKBNA-Water Naphthalene0.96ug/LU 0.963.8

11/12/2003 9:30 VBP BLANKBNA-WaterNitrobenzene1.9ug/LU 1.97.7

11/12/2003 9:30VBP BLANKBNA-Water Nitroquinoline-1-oxide 19 ug/L UJ 19 77

11/12/2003 9:30VBP BLANKBNA-Water Pentachlorobenzene 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-Water Pentachloroethane48ug/LU 48 190

11/12/2003 9:30 VBP BLANKBNA-Water Pentachloronitrobenzene0.96ug/LUJ0.963.8

11/12/2003 9:30VBP BLANKBNA-WaterPentachlorophenol2.9 ug/L UJ2.912

11/12/2003 9:30VBP BLANKBNA-Water Phenacetin 3.8ug/LU3.812

11/12/2003 9:30VBP BLANKBNA-Water Phenanthrene 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-Water Phenol 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-Water Pyrene 0.96 ug/LU0.963.8

11/12/2003 9:30VBP BLANKBNA-WaterPyridine 3.8ug/LU3.815

11/12/2003 9:30VBP BLANKBNA-Water Safrole0.96ug/LU 0.963.8

11/12/2003 9:30 VBP BLANKBNA-Water alpha-BHC1.4ug/LU1.4 5.8

11/12/2003 9:30VBP BLANKBNA-Water beta-BHC 1.4ug/LU1.45.8

11/12/2003 9:30VBP BLANKBNA-Water delta-BHC1.4 ug/LU1.45.8

11/12/2003 9:30VBP BLANKBNA-Water gamma-BHC1.4 ug/LU1.45.8

11/12/2003 9:30VBP BLANKBNA-Waterm,p-Cresols1.9 ug/LU1.97.7

11/12/2003 9:30 VBP BLANKBNA-Water oCresol1.9ug/LU 1.97.7

11/12/2003 9:30VBP BLANKBNA-Watero-Toluidine0.96ug/LU 0.963.8

11/12/2003 9:30VBP BLANKGC-WaterAlachlor0.57ug/LU 0.572.28

11/12/2003 9:30 VBP BLANKGC-WaterAmetryn 0.048ug/LU0.0480.192

11/12/2003 9:30VBP BLANKGC-WaterAtrazine0.048 ug/LU0.048 0.192

11/12/2003 9:30VBP BLANKGC-WaterAzinphosMethyl0.048ug/LUJ0.048 0.192

11/12/2003 9:30VBP BLANKGC-WaterBromacil0.19ug/LU 0.190.76

11/12/2003 9:30VBP BLANKGC-WaterButylate0.19ug/LUJ0.190.76

11/12/2003 9:30VBP BLANKGC-WaterChlorpyrifos Ethyl0.048 ug/LU0.048 0.192

11/12/2003 9:30 VBP BLANKGC-WaterChlorpyrifos Methyl 0.095ug/LU0.0950.38

11/12/2003 9:30VBP BLANKGC-WaterDiazinon0.048 ug/LU0.048 0.192

11/12/2003 9:30VBP BLANKGC-WaterEthion0.048 ug/LU0.048 0.192

11/12/2003 9:30VBP BLANKGC-WaterEthoprop0.095 ug/LU0.0950.38

11/12/2003 9:30VBP BLANKGC-WaterFenamiphos0.19ug/LUJ0.190.76

11/12/2003 9:30VBP BLANKGC-WaterFonofos0.095ug/LU 0.0950.38

11/12/2003 9:30VBP BLANKGC-WaterHexazinone0.095 ug/LU0.0950.38

11/12/2003 9:30 VBP BLANKGC-WaterMalathion0.14ug/LU0.140.56

11/12/2003 9:30VBP BLANKGC-WaterMetalaxyl 0.24 ug/LU0.240.96

11/12/2003 9:30VBP BLANKGC-WaterMetolachlor 0.48 ug/LU0.481.92

11/12/2003 9:30VBP BLANKGC-WaterMetribuzin0.095 ug/LU0.0950.38

11/12/2003 9:30VBP BLANKGC-WaterMevinphos 0.19 ug/L UJ 0.190.76

11/12/2003 9:30VBP BLANKGC-WaterNaled 0.76 ug/LU0.763.04

11/12/2003 9:30 VBP BLANKGC-WaterNorflurazon 0.095ug/LU0.0950.38

11/12/2003 9:30VBP BLANKGC-WaterParathion Ethyl0.14ug/LU 0.140.56

11/12/2003 9:30 VBP BLANKGC-WaterParathion Methyl 0.095ug/LU0.0950.38

11/12/2003 9:30VBP BLANKGC-WaterPhorate0.048ug/LUJ0.048 0.192

11/12/2003 9:30VBP BLANKGC-WaterPrometryn 0.14 ug/LU0.140.56

11/12/2003 9:30VBP BLANKGC-WaterSimazine0.048 ug/LU0.048 0.192

11/12/2003 9:30VBP BLANKMetals-WaterAluminum7 ug/LU7 28

11/12/2003 9:30VBP BLANKMetals-WaterArsenic 9.8ug/LU9.839

11/12/2003 9:30 VBP BLANKMetals-WaterCadmium 0.025ug/LU0.0250.1

11/12/2003 9:30VBP BLANKMetals-WaterCalcium 0.05mg/LU0.050.2

11/12/2003 9:30VBP BLANKMetals-WaterChromium3 ug/LU3 12

11/12/2003 9:30VBP BLANKMetals-WaterCopper1 ug/LU14

11/12/2003 9:30VBP BLANKMetals-WaterIron15ug/LU 15 60

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11/12/2003 9:30 VBP BLANK Metals-Water Lead 0.05 ug/L U 0.05 0.2

11/12/2003 9:30 VBP BLANK Metals-Water Magnesium 0.02 mg/L U 0.02 0.08

11/12/2003 9:30 VBP BLANK Metals-Water Nickel 3 ug/L U 3 12

11/12/2003 9:30 VBP BLANK Metals-Water Selenium 1 ug/L U 1 4

11/12/2003 9:30 VBP BLANK Metals-Water Silver 0.02 ug/L U 0.02 0.08

11/12/2003 9:30 VBP BLANK Metals-Water Zinc 4 ug/L U 4 16

11/12/2003 9:30 VBP BLANK Nutrients-Liquid Ammonia-N 0.01 mg N/L U 0.01 0.02

11/12/2003 9:30 VBP BLANK Nutrients-Liquid NO2NO3-N 0.01 mg N/L I 0.004 0.01

11/12/2003 9:30 VBP BLANK Nutrients-Liquid N_KJEL_TOT 0.06 mg N/L U 0.06 0.2

11/12/2003 9:30 VBP BLANK Nutrients-Liquid O-Phosphate-P 0.004 mg P/L U 0.004 0.01

11/12/2003 9:30 VBP BLANK Nutrients-Liquid Total-P 0.02 mg P/L U 0.02 0.06

15
Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 000 2 9 8 4 11 1203 1 1 1 2 18 B 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 000 2 9 8 4 11 1203 1 1 1 2 18 X 19 S 20 2

66

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks

Remarks

The Bioassay of Vero Beach Municipal Power Plant 

effluent sampled on November 12, 2003, NPDES 

#FL0002984. 

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

The Priority Pollutants Analysis for Bioassay of Vero 

Beach Municipal Power Plant effluent sampled on 

November 12, 2003, NPDES #FL0002984. 

16