# EMISSION S TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -003

PARTICULATE MATTER, SULFUR DI OXIDE, AND, VISIBLE EMISSIONS EVALUATION Marc h 8, 2006

Prepared For: Tampa Elec tric Compa n y Polk P o wer Station P.O. Box 1 11 Tampa, Florida 33601-0111

Prepared By: Tampa Elec tric Compa n y Environme n tal, Health & Safety Environme n tal Service s Air Services Group

Envi ronme n tal Servi c es Ai r Servi c es Grou p 5010 Cau s e w ay Boul eva r d Tampa, Fl ori da 336 19- 6 1 30

## REPORT CERTIFICATION

I ha ve revi ewed the t e st perfor ma nce, associated quality assura nce activities, the resulta n t calculations, a n d the contents of this repor t , a n d certify that a ll proj ect quality obj ectives have been met. Th is r

e port is approved for submitta l.

Signature:__________________________ Raymond A

. McDarby, Jr. Senior Envi ronmenta l Technician Quality Assurance/Quality Control Specialist Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

The sampling and subseque nt da ta entry/reduction det a iled in this report were cond ucted at m y d i rection

, and I here by certif y

t h at t h is tes t report is authentic and accurate to t h e best of my knowledge.

Signature:__________________________ Jorge A. Varino Technician Test Team Lead Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

I ha ve revi ewed the t e sting deta ils and results subm itt e d in t h is r e port, and hereby certify that this test report is authenti c and accurate to the best of my k n owle dge.

Signature:__________________________ Davi d A

. S m ith Coordi nator – Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

## TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1
2.0 DISCUSSION OF RESULTS 2
3.0 SOURCE DESCRIPTION/TEST PROCEDURES 3
4.0 TEST RESULTS PARTICULATE TEST SUMMARY (SOOT BLOWING) 6 PARTICULATE TEST SUMMARY (NON-SOOT BLOWING) 7
SULFUR DIOXIDE DATA SUMMARY 8
VISIBLE EMISSIONS DATA SU MMARY (SOOT BLOWING) 9
VISIBLE EMISSIONS DATA SU MMARY (NON-SOOT BLOWING) 10
HEAT INPUT AND FUEL CONSUMPTION SUMMARY 11
5.0 FIGURES
SAMPLING LOCATION DIAGRAM 13

APPENDICIES

A PARTICULTE TEST CALCULATIONS
B DAILY SULFUR DIOXIDE DATA SUMMARY
C PARTICULATE LABORATORY ANALYTICAL DATA
D BOILER/PRECIPITATOR OPERATIONAL DATA
E FUEL ANALYSIS
F FIELD DATA SHEETS
G SAMPLING EQUIPMENT CALIBRATIONS
H CHAIN OF CUSTODY
I TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION

On March 8, 2006, the Environmental Se rvices, Air Services Group of Tampa Electric Company, performed source emi ssion tests at the Big Bend Station, Boiler No. 3, emissions unit I.D.# 0570039-003. Testing was conducted according to procedures stipulated by t he Florida Department of Environmental Protection (FDEP) for fossil fuel steam generators, and requir ements in Title V
Permit # 0570039-017-AV.

### 2 

## 2.0 DISCUSSION OF RESULTS
The particulate matter emission rate under sootblowing conditions was derived from three United States Environment al Protection Agency (USEPA) Reference Method 5-B test runs. The average of t he three test runs was 0.02 lb/mmBtu.
The FDEP allowable emission rate under soot blowing conditions is 0.03 lb/MMBtu, as listed in condition A.7.

The particulate matter emission rate under non-sootblowing conditions was derived from three USEPA Refe rence Method 5-B test runs. The average of the
three test runs was 0.02 lb/MMBtu. The FDEP allowable emission rate under non-sootblowing conditions is 0.03 lb/ MMBtu, as listed in condition A.7.

The sulfur dioxide emission rate wa s determined using data provided by the Continuous Emissions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was
determined to be 609 lbs/hr. The FDEP a llowable emission rate is 3374 lbs/hr,
based on scenario 3 as listed in condition A.9.e.

Visible emissions were evaluated usi ng a Teledyne Instruments/Monitor Labs, LightHawk 560 transmissometer syst em (S/N 5600448/5600446), during both sootblowing and non-sootblowing testing. The 1-hour average opacity under sootblowing conditions was 4.2%. The 1-hour average opacity under nonsootblowing conditions was 4.6%. The FD EP allowable emission rate is 20%, as
listed in condition A.6.

During the tests performed on March 8, 2006, Boiler No. 3 was operated at an average heat input rate of 4057 mmB tu/hr and an average load of 392 megawatts. The average quantity of f uel burned was 174.8 tons per hour.

### 3 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The common stack 3 (CS003) source sampling location consists of a circular stack 28.83 feet in diameter with four sample ports located 90 degrees apart on t he stack circumference. Upstream and downstream gas flow disturbances were determined to be 8.51 and 2.99 stack diameters from the test ports, respec tively. Using these criteria, a total of 24 sampling points were chosen for particu late sampling, as stipulated in USEPA Method 1 – “Sample and Velocity Traverse s for Stationary Sour ces”. A diagram of the stack sampling location is incl uded in Figure 1 along with other pertinent
information on the test site.

Boiler No. 3 is serviced by an electrostatic precipitator for the control of flyash emissions and a flue gas desulfurization (FGD) system for control of sulfur
dioxide emissions.

Particulate matter sampling was perfo rmed according to USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources". Particulate matter was collected on a high purity, borosilicate mi crofiber filter measuring 82mm in diameter. This dat a is included as Appendix A, and summarized on pages 6 (soot blowing c onditions), and 7 (non-soot blowing conditions) of this report.

Diluent gas sampling and analysis was performed according to USEPA Method 3 "Gas Analysis for Determination of Emi ssion Rate Correction Factor, or Excess Air”. Gas analysis was performed on-site using an Orsat analyzer.

Sulfur Dioxide (SO 2 

### ) and Carbon Dioxide (CO 2 

### ) data were provided by the Continuous Emissions Monitoring S ystem (CEMS), Data Acquisition and Handling System (DAHS). Averages were derived from the time frame of 11:57 through 20:00 EST, corresponding to the time frame of the particulate matter

### 4 

### test. Data from 16:02 through 16:05 was not included in the averaging due to probe blowback (normal operations to ens ure that the sampling system remains clean). This data is included as Appendi x B, and summarized on page 8 of this report.

Visible emissions were assessed using t he installed Continuous Opacity Monitor (COM) system. This data is summariz ed on pages 9 (soot blowing conditions), and 10 (non-soot blowing conditions).

### 5 

## 4.0 TEST RESULTS

## BI G BEND ST AT I O N PART I C ULAT E MATT ER D A T A SUMMARY

Run 1s Run 2s Run 3s V m(std ) 

### , sc f 35 .536 38.847 36.980

B ws 

### , ratio 0.153 03 0.14076 0.14877

O 2 

### , % volume 3.5 4 4

M

d 

### , lb/lb - mole 30 .44 30.48 30.40

M

s 

### , lb/lb - mole 28 .54 28.72 28.56

Q s 

### , ac f/min 1182 226.0 1238858.6 1238071.9

Q s(std ) 

### , dsc f /min 8858 92.3 947649.1 938022.6

I, % 9 7

. 2 99.3 95.5

C, lbs/dscf 1.61E-06 1 .17E -06 1 .20E -06

E r 

### , lb/mmBt u 0.02 0.01 0.01

E m ission ra te (E r )

, lb / m m B t u , ca lcula t e d a s : C x 9780 d s cf/ m m B t u x ( 2 0.9/ ( 20.9-%O 2 )) 

### 97 .33

1.327 7E -06

0.02 30 .441

28 .606

1219 718.83

9238 54.68 

### T est Summa ry 37 .121

0.147519

3.83 

### B o iler # 3 W E T-B O TTOM UTILITY B O ILE R M a r c h 8, 2006 SOOT BLOWING

6

## BI G BEND ST AT I O N PART I C ULAT E MATT ER D A T A SUMMARY

R un 1 Run 2 Run 3 V m(std ) 

### , sc f 36 .278 36.764 35.977

B ws 

### , ratio 0.152 61 0.14802 0.15538

O 2 

### , % volume 3.5 3 .5 4

M

d 

### , lb/lb - mole 30 .44 30.44 30.40

M

s 

### , lb/lb - mole 28 .54 28.60 28.47

Q s 

### , ac f/min 1208 983.6 1221593.8 1203225.6

Q s(std ) 

### , dsc f /min 9067 21.9 925340.0 905368.5

I, % 9 6

. 9 96.2 96.3

C, lbs/dscf 1.26E-06 1 .43E -06 1 .28E -06

E r 

### , lb/mmBt u 0.01 0.02 0.02

E m ission ra te (E r )

, lb / m m B t u , ca lcula t e d a s : C x 9780 d s cf/ m m B t u x ( 2 0.9/ ( 20.9-%O 2 )) 

### 1.322 9E -06

0.02 

### NON - SOOT BLOWING

28 .540

1211 267.64

9124 76.82

96 .47 36 .340

0.152006

3.67

30 .429 

### B o iler # 3 W E T-B O TTOM UTILITY B O ILE R M a r c h 8, 2006

T est Summa ry

7

## BIG BEND ST ATI O N SU LFUR DIOXIDE DATA from CEMs

T est Period Informat ion S t art Ti me 1 1 : 57 :0 0 E as te rn S t an dard Ti m e (ES T ) St o p T i m e 20: 00: 0 0 E a s t e rn St a n d a rd T i me ( E ST ) T otal Time 8 : 03 :0 0 C o rresp o n d i n g to th e ti me frame f o r th e PM tes t

.

Su lfur Dio x i d e Da t a : RM - 19 SO 2 

### CO 2 

### SO 2 

### SO 2 

### ppmvw %

, we t l b/mmBtu l bs /h r 61. 739167 12. 32077 0. 150 608. 73

Ca lcula t ion Det a ils SO 2 

### , lb/mmBt u = SO 2 

### , ppmvw x C f 

### x F c 

### x ( 100 / CO2 %, wet)
where: C

f 

### = 1.6635E

- 0 7 (lb/sc f) /ppm SO 2 

### F c



### = 18 00 scf/mm Btu SO 2 

### , lbs/hr = SO 2 

### , lb/m mBt u x Heat Input, mmBt u /h r where: Heat Input = 4057 mmB tu/hr, from Heat In put Calcu l ation 

### Boiler #3 WET

- BOT T O M UT I L I T Y BOI L ER M a r c h 8, 2006

CEM DATA

8

## BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

R e c o r d # D AT E T IME O PAC IT Y 4 1 R e c o r d # D AT E T IME O PAC IT Y 4 1 1 3 /8/2006 17:38 4.400 31 3/8/2006 18:08 3.900 2 3 /8/2006 17:39 4.600 32 3/8/2006 18:09 4.100 3 3 /8/2006 17:40 4.500 33 3/8/2006 18:10 4.100 4 3 /8/2006 17:41 4.200 34 3/8/2006 18:11 4.200 5 3 /8/2006 17:42 4.400 35 3/8/2006 18:12 4.200 6 3 /8/2006 17:43 4.500 36 3/8/2006 18:13 4.100 7 3 /8/2006 17:44 4.100 37 3/8/2006 18:14 4.200 8 3 /8/2006 17:45 4.400 38 3/8/2006 18:15 4.100 9 3 /8/2006 17:46 4.500 39 3/8/2006 18:16 4.000 10 3/8/2006 17:47 4.300 40 3/8/2006 18:17 4.200 11 3/8/2006 17:48 4.400 41 3/8/2006 18:18 4.200 12 3/8/2006 17:49 4.400 42 3/8/2006 18:19 4.300 13 3/8/2006 17:50 4.500 43 3/8/2006 18:20 4.200 14 3/8/2006 17:51 4.500 44 3/8/2006 18:21 4.200 15 3/8/2006 17:52 4.300 45 3/8/2006 18:22 4.400 16 3/8/2006 17:53 4.300 46 3/8/2006 18:23 4.400 17 3/8/2006 17:54 4.000 47 3/8/2006 18:24 4.200 18 3/8/2006 17:55 4.200 48 3/8/2006 18:25 4.200 19 3/8/2006 17:56 4.100 49 3/8/2006 18:26 4.200 20 3/8/2006 17:57 4.300 50 3/8/2006 18:27 4.400 21 3/8/2006 17:58 4.100 51 3/8/2006 18:28 4.300 22 3/8/2006 17:59 4.200 52 3/8/2006 18:29 4.200 23 3/8/2006 18:00 4.000 53 3/8/2006 18:30 4.300 24 3/8/2006 18:01 4.100 54 3/8/2006 18:31 4.300 25 3/8/2006 18:02 4.100 55 3/8/2006 18:32 4.200 26 3/8/2006 18:03 4.100 56 3/8/2006 18:33 4.300 27 3/8/2006 18:04 4.100 57 3/8/2006 18:34 4.200 28 3/8/2006 18:05 4.200 58 3/8/2006 18:35 4.300 29 3/8/2006 18:06 4.300 59 3/8/2006 18:36 4.400 30 3/8/2006 18:07 4.200 60 3/8/2006 18:37 4.200

T e s t Aver age: 4.247 % Minim u m O ne Minu te Aver age: 3.900 % Max i m u m O ne Minu te Aver age: 4.600 %

Max i m u m Six Minu te Aver age: 4.433 % 

### B o iler #3 W E T B O TTOM UTILITY B O ILE R

SOOTB L OWING CONDITIONS

9

## BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITO R

R e c o r d # D AT E T IME O PAC IT Y 4 1 R e c o r d # D AT E T IME O PAC IT Y 4 1 1 3 /8/2006 13:28 4.800 31 3/8/2006 13:58 4.800 2 3 /8/2006 13:29 4.600 32 3/8/2006 13:59 4.700 3 3 /8/2006 13:30 4.700 33 3/8/2006 14:00 4.400 4 3 /8/2006 13:31 4.900 34 3/8/2006 14:01 4.700 5 3 /8/2006 13:32 4.600 35 3/8/2006 14:02 4.200 6 3 /8/2006 13:33 4.700 36 3/8/2006 14:03 4.200 7 3 /8/2006 13:34 5.000 37 3/8/2006 14:04 4.600 8 3 /8/2006 13:35 4.800 38 3/8/2006 14:05 4.900 9 3 /8/2006 13:36 4.500 39 3/8/2006 14:06 4.900 10 3/8/2006 13:37 4.400 40 3/8/2006 14:07 4.900 11 3/8/2006 13:38 4.700 41 3/8/2006 14:08 4.700 12 3/8/2006 13:39 5.000 42 3/8/2006 14:09 4.600 13 3/8/2006 13:40 4.700 43 3/8/2006 14:10 4.600 14 3/8/2006 13:41 4.600 44 3/8/2006 14:11 4.700 15 3/8/2006 13:42 4.500 45 3/8/2006 14:12 4.700 16 3/8/2006 13:43 4.500 46 3/8/2006 14:13 4.400 17 3/8/2006 13:44 4.700 47 3/8/2006 14:14 4.400 18 3/8/2006 13:45 4.600 48 3/8/2006 14:15 4.500 19 3/8/2006 13:46 4.600 49 3/8/2006 14:16 4.300 20 3/8/2006 13:47 4.900 50 3/8/2006 14:17 4.700 21 3/8/2006 13:48 4.700 51 3/8/2006 14:18 4.400 22 3/8/2006 13:49 4.800 52 3/8/2006 14:19 4.200 23 3/8/2006 13:50 4.700 53 3/8/2006 14:20 4.400 24 3/8/2006 13:51 4.700 54 3/8/2006 14:21 4.400 25 3/8/2006 13:52 5.000 55 3/8/2006 14:22 4.400 26 3/8/2006 13:53 4.700 56 3/8/2006 14:23 4.400 27 3/8/2006 13:54 4.600 57 3/8/2006 14:24 4.300 28 3/8/2006 13:55 4.500 58 3/8/2006 14:25 4.400 29 3/8/2006 13:56 4.600 59 3/8/2006 14:26 4.400 30 3/8/2006 13:57 4.700 60 3/8/2006 14:27 4.600

T e s t Aver age: 4.610 % Minim u m O ne Minu te Aver age: 4.200 % Max i m u m O ne Minu te Aver age: 5.000 %

Max i m u m Six Minu te Aver age: 4.800 % 

### B o iler #3 W E T B O TTOM UTILITY B O ILE R NON-SOO T B L OW ING C O N D ITIONS

10

## BI G BEND GENERATI NG STATI O N HEAT INPUT CALCULATIONS

Gro ss Hea t Ra t e , P r evio us Mo nt h ( F eb rua r y) : 10346 KM Bt u/ MW h 1. 0346E +07 M MBt u / M

W h



## Me g aWatt Ho ur Inte g rato r Info rmatio n Init ia l Int e g rator Readin g : 354993 M W h Final Inte g rator Readin g : 358118 M W h T o t a l : 3125 M W h



## T es t T i m e In f o rm a t ion T est i n g St a r t T i me: 11: 57 T est i n g E n d T i me: 19: 55

T otal Te s t Ti me : 7 .9 7 h ou rs



## Cal c ul ate d He at I n p u t Avera g e Unit Lo a d

, MW = MW h / ho urs: 392. 1 M W Hea t I n p u t
, MMBt u/ h = MMBt u/ MW h x MW : 4056. 7 m mBt u / h r



## Fue l Co nsumptio n Calculatio n

Laboratory Sample ID: A A 82365 Bt u a s rec e ived : 11603 Bt u/ lb T o n s o f F u el Co nsum ed

, T o ns/ h r = ( mmBt u / h / Bt u/ lb ) x 500: 174. 8 T o n s/ho ur 

## Coa l F i re d Bo il er Num b er 3 Mar c h 8
, 2006

11

### 12 

## 5.0 FIGURESFI GURE 1 EX HA US T ST AC K 245 F T

. BIG BE N D S T A T IO N CS 0 0 3

PA RT I C ULA T E T R A VERSE POI N T S

OU T L ET 

# N A

B C D

PORT L O CATI ON

R E V I SE D 1 2

- 31- 96 BO I L ER N O

. 3 T EST LOCA T I ON

S T AC K D I AME T ER S D O W N ST R E A M F R O M D I ST UR BA NC E = 3. 0

S T AC K D I AME T ER S U PST RE AM F R O M D I ST UR BA NC E = 8. 5

ST A C K DI A M ET E R = 28. 8333 F T

. ST A C K AR EA = 652. 948 SQ.

PORT LEN G T H ’ S = 14 I N

. T R AV ER SE PO IN T

1

2

3

4

5

6 % O F S T AC K D I AM E T ER I N . F R O M S T AC K W A L L

2.1%

6.7%

11

. 8 %

17

. 7 %

25

. 0 %

35

. 6 % 7

. 2 7 IN

.

2 3 .1 8 IN

.

4 0 .8 3 IN

.
6 1 .2 4 IN

.
8 6 .5 0 IN

.
123. 18 I N

. 499 F T

.

254 F T

.

168 F T

. 86 F T

.

FGD

PR ES SU RIZ E D AN N U L U S



### 13

## APPENDIX A PARTICULTE TEST CALCULATIONS

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 1s Date: 03/08/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.85 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.78 "Hg Average Orifice Meter, ∆ H: 1.214 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 36.777 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 87.3 o F Gas Analysis: 14.4 % CO 2 Average Stack Temp., T s : 134.0 o F 3.5 % O 2 Average √ ∆ p: 0.503 "H 2 O 0.0 % CO Condensate Volume, V lc : 136.2 ml 82.1 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V lc 6.420 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 35.536 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.153 % FDA = 1.0 - B w s 0.847 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B w s ) 28.54 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 30.18 ft/second Q s = v s x A s x 60 1182226.0 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 885892.3 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 97.2 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.026000 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.011 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.008 grains/acf C = c s / 7000 1.613E-06 lbs/dscf E M = C x Q s(std) x 60 85.7 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 2s Date: 03/08/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.95 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.91 "Hg Average Orifice Meter, ∆ H: 1.333 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 40.250 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 90.0 o F Gas Analysis: 14.5 % CO 2 Average Stack Temp., T s : 133.0 o F 4.0 % O 2 Average √ ∆ p: 0.530 "H 2 O 0.0 % CO Condensate Volume, V lc : 135.0 ml 81.5 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V lc 6.364 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 38.847 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.141 % FDA = 1.0 - B w s 0.859 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.48 lb./lb. mole M s = (M d x FDA) + (18.0 x B w s ) 28.72 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 31.62 ft/second Q s = v s x A s x 60 1238858.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 947649.1 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.020650 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.008 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.172E-06 lbs/dscf E M = C x Q s(std) x 60 66.6 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.01 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 3s Date: 03/08/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.95 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.91 "Hg Average Orifice Meter, ∆ H: 1.323 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 38.366 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 90.0 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 133.1 o F 4.0 % O 2 Average √ ∆ p: 0.528 "H 2 O 0.0 % CO Condensate Volume, V l c : 137.1 ml 82.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.463 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 36.980 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.149 % FDA = 1.0 - B ws 0.851 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.40 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.56 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 31.60 ft/second Q s = v s x A s x 60 1238071.9 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 938022.6 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 95.5 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.020100 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.008 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.198E-06 lbs/dscf E M = C x Q s(std) x 60 67.4 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.01 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 1 Date: 03/08/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.85 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.78 "Hg Average Orifice Meter, ∆ H: 1.275 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 37.676 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 89.3 o F Gas Analysis: 14.4 % CO 2 Average Stack Temp., T s : 133.7 o F 3.5 % O 2 Average √ ∆ p: 0.514 "H 2 O 0.0 % CO Condensate Volume, V l c : 138.6 ml 82.1 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.534 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 36.278 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.153 % FDA = 1.0 - B ws 0.847 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.54 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 30.86 ft/second Q s = v s x A s x 60 1208983.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 906721.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 96.9 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.020700 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.009 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.007 grains/acf C = c s / 7000 1.258E-06 lbs/dscf E M = C x Q s(std) x 60 68.4 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.01 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 2 Date: 03/08/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.95 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.88 "Hg Average Orifice Meter, ∆ H: 1.290 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 38.099 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 90.0 o F Gas Analysis: 14.4 % CO 2 Average Stack Temp., T s : 133.0 o F 3.5 % O 2 Average √ ∆ p: 0.521 "H 2 O 0.0 % CO Condensate Volume, V l c : 135.5 ml 82.1 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.387 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 36.764 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.148 % FDA = 1.0 - B ws 0.852 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.60 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 31.18 ft/second Q s = v s x A s x 60 1221593.8 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 925340.0 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 96.2 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.023850 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.010 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.008 grains/acf C = c s / 7000 1.430E-06 lbs/dscf E M = C x Q s(std) x 60 79.4 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 3 Date: 03/08/06

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.95 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.91 "Hg Average Orifice Meter, ∆ H: 1.248 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 37.253 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 89.5 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 132.5 o F 4.0 % O 2 Average √ ∆ p: 0.513 "H 2 O 0.0 % CO Condensate Volume, V l c : 140.4 ml 82.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 6.618 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 35.977 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.155 % FDA = 1.0 - B ws 0.845 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.40 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.47 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 30.71 ft/second Q s = v s x A s x 60 1203225.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 905368.5 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 96.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.020900 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0090 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0067 grains/acf C = c s / 7000 1.281E-06 lbs/dscf E M = C x Q s(std) x 60 69.6 lbs/hr E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

## APPENDIX B DAILY SULFUR DIOXIDE DATA SUMMARY

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 1 3/8/06 11:57 12.35 66.7 2 3/8/06 11:58 12.31 66.8 3 3/8/06 11:59 12.36 69 4 3/8/06 12:00 12.41 67.8 5 3/8/06 12:01 12.36 72.3 6 3/8/06 12:02 12.4 79.9 7 3/8/06 12:03 12.44 85.1 8 3/8/06 12:04 12.5 82.9 9 3/8/06 12:05 12.53 75.5 10 3/8/06 12:06 12.43 67.8 11 3/8/06 12:07 12.36 60.6 12 3/8/06 12:08 12.34 57.7 13 3/8/06 12:09 12.33 59.5 14 3/8/06 12:10 12.33 61.2 15 3/8/06 12:11 12.33 58.9 16 3/8/06 12:12 12.28 58.7 17 3/8/06 12:13 12.43 59.5 18 3/8/06 12:14 12.44 60.1 19 3/8/06 12:15 12.34 60.8 20 3/8/06 12:16 12.44 68.4 21 3/8/06 12:17 12.46 75 22 3/8/06 12:18 12.56 74.6 23 3/8/06 12:19 12.41 68.6 24 3/8/06 12:20 12.38 65 25 3/8/06 12:21 12.4 65.7 26 3/8/06 12:22 12.38 65.4 27 3/8/06 12:23 12.42 66.9 28 3/8/06 12:24 12.36 69.3 29 3/8/06 12:25 12.41 68.8 30 3/8/06 12:26 12.44 67.3 31 3/8/06 12:27 12.47 67.2 32 3/8/06 12:28 12.47 67 33 3/8/06 12:29 12.43 65 34 3/8/06 12:30 12.39 66 35 3/8/06 12:31 12.45 65.7 36 3/8/06 12:32 12.39 65.3 37 3/8/06 12:33 12.42 68 38 3/8/06 12:34 12.4 73.1 39 3/8/06 12:35 12.46 71.2

1 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 40 3/8/06 12:36 12.42 72.1 41 3/8/06 12:37 12.36 71.2 42 3/8/06 12:38 12.35 70.1 43 3/8/06 12:39 12.37 74.1 44 3/8/06 12:40 12.4 70.8 45 3/8/06 12:41 12.35 65.8 46 3/8/06 12:42 12.4 62.8 47 3/8/06 12:43 12.32 65.3 48 3/8/06 12:44 12.33 67.6 49 3/8/06 12:45 12.4 69.7 50 3/8/06 12:46 12.47 68.3 51 3/8/06 12:47 12.46 71.6 52 3/8/06 12:48 12.4 73.5 53 3/8/06 12:49 12.35 71.9 54 3/8/06 12:50 12.33 70.4 55 3/8/06 12:51 12.21 66.8 56 3/8/06 12:52 12.2 67.1 57 3/8/06 12:53 12.27 66.7 58 3/8/06 12:54 12.25 62.5 59 3/8/06 12:55 12.31 59.9 60 3/8/06 12:56 12.36 58.1 61 3/8/06 12:57 12.39 63 62 3/8/06 12:58 12.38 64.3 63 3/8/06 12:59 12.41 63.7 64 3/8/06 13:00 12.35 64.7 65 3/8/06 13:01 12.4 65.9 66 3/8/06 13:02 12.4 67.2 67 3/8/06 13:03 12.37 73.3 68 3/8/06 13:04 12.39 76.2 69 3/8/06 13:05 12.41 76.9 70 3/8/06 13:06 12.37 67.2 71 3/8/06 13:07 12.35 61.5 72 3/8/06 13:08 12.38 59.4 73 3/8/06 13:09 12.26 56.8 74 3/8/06 13:10 12.31 54.2 75 3/8/06 13:11 12.35 56.7 76 3/8/06 13:12 12.31 57.5 77 3/8/06 13:13 12.34 60.3 78 3/8/06 13:14 12.43 63

2 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 79 3/8/06 13:15 12.46 62.7 80 3/8/06 13:16 12.33 60.3 81 3/8/06 13:17 12.34 62.2 82 3/8/06 13:18 12.35 62 83 3/8/06 13:19 12.35 63 84 3/8/06 13:20 12.36 61 85 3/8/06 13:21 12.31 58.3 86 3/8/06 13:22 12.4 59.7 87 3/8/06 13:23 12.38 60.7 88 3/8/06 13:24 12.35 56.4 89 3/8/06 13:25 12.37 56.3 90 3/8/06 13:26 12.34 55.2 91 3/8/06 13:27 12.37 58 92 3/8/06 13:28 12.39 57.2 93 3/8/06 13:29 12.43 56.5 94 3/8/06 13:30 12.38 56.2 95 3/8/06 13:31 12.36 54.6 96 3/8/06 13:32 12.4 56.5 97 3/8/06 13:33 12.33 55.9 98 3/8/06 13:34 12.4 53.2 99 3/8/06 13:35 12.38 50.5 100 3/8/06 13:36 12.43 49.2 101 3/8/06 13:37 12.41 53.8 102 3/8/06 13:38 12.45 58.4 103 3/8/06 13:39 12.43 59.4 104 3/8/06 13:40 12.48 60.5 105 3/8/06 13:41 12.39 61.6 106 3/8/06 13:42 12.4 61.6 107 3/8/06 13:43 12.36 61.8 108 3/8/06 13:44 12.4 57.7 109 3/8/06 13:45 12.47 60 110 3/8/06 13:46 12.37 60.3 111 3/8/06 13:47 12.33 59.9 112 3/8/06 13:48 12.47 63 113 3/8/06 13:49 12.39 65.5 114 3/8/06 13:50 12.41 70.6 115 3/8/06 13:51 12.48 70.3 116 3/8/06 13:52 12.5 59.6 117 3/8/06 13:53 12.46 55.9

3 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 118 3/8/06 13:54 12.47 52.3 119 3/8/06 13:55 12.38 51.5 120 3/8/06 13:56 12.38 50.2 121 3/8/06 13:57 12.39 50.6 122 3/8/06 13:58 12.34 51.7 123 3/8/06 13:59 12.3 52.5 124 3/8/06 14:00 12.39 51.4 125 3/8/06 14:01 12.45 52.9 126 3/8/06 14:02 12.46 54.5 127 3/8/06 14:03 12.5 54.8 128 3/8/06 14:04 12.48 57.6 129 3/8/06 14:05 12.53 58.9 130 3/8/06 14:06 12.45 59.1 131 3/8/06 14:07 12.47 60.7 132 3/8/06 14:08 12.47 60.8 133 3/8/06 14:09 12.42 59.2 134 3/8/06 14:10 12.35 58.4 135 3/8/06 14:11 12.34 59.5 136 3/8/06 14:12 12.38 56.7 137 3/8/06 14:13 12.43 57.1 138 3/8/06 14:14 12.51 59.4 139 3/8/06 14:15 12.45 61.1 140 3/8/06 14:16 12.48 66.5 141 3/8/06 14:17 12.47 67.9 142 3/8/06 14:18 12.48 70.5 143 3/8/06 14:19 12.44 66.7 144 3/8/06 14:20 12.43 61.6 145 3/8/06 14:21 12.46 58.8 146 3/8/06 14:22 12.42 58.9 147 3/8/06 14:23 12.39 56.6 148 3/8/06 14:24 12.42 56.8 153 3/8/06 14:25 12.42 57.9 154 3/8/06 14:26 12.49 62 155 3/8/06 14:27 12.47 62.2 156 3/8/06 14:28 12.41 61.4 157 3/8/06 14:29 12.46 65.5 158 3/8/06 14:30 12.48 64.3 159 3/8/06 14:31 12.47 66.4 160 3/8/06 14:32 12.36 67.5

4 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 161 3/8/06 14:33 12.44 66.7 162 3/8/06 14:34 12.43 61.5 163 3/8/06 14:35 12.47 62.3 164 3/8/06 14:36 12.44 60.4 165 3/8/06 14:37 12.45 58.2 166 3/8/06 14:38 12.4 56.8 167 3/8/06 14:39 12.46 59.3 168 3/8/06 14:40 12.45 60.9 169 3/8/06 14:41 12.45 63.4 170 3/8/06 14:42 12.38 59.6 171 3/8/06 14:43 12.45 65.1 172 3/8/06 14:44 12.48 64.7 173 3/8/06 14:45 12.46 64.4 174 3/8/06 14:46 12.4 64.5 175 3/8/06 14:47 12.4 63.8 176 3/8/06 14:48 12.36 62.7 177 3/8/06 14:49 12.37 61.5 178 3/8/06 14:50 12.45 59.9 179 3/8/06 14:51 12.43 63.6 180 3/8/06 14:52 12.4 67 181 3/8/06 14:53 12.4 66.9 182 3/8/06 14:54 12.45 64.7 183 3/8/06 14:55 12.4 65.1 184 3/8/06 14:56 12.41 64.9 185 3/8/06 14:57 12.4 67.5 186 3/8/06 14:58 12.41 68.5 187 3/8/06 14:59 12.46 71 188 3/8/06 15:00 12.29 68 189 3/8/06 15:01 12.35 68.4 190 3/8/06 15:02 12.34 67.2 191 3/8/06 15:03 12.39 69 192 3/8/06 15:04 12.29 72.4 193 3/8/06 15:05 12.34 75.8 194 3/8/06 15:06 12.38 76.2 195 3/8/06 15:07 12.36 75 196 3/8/06 15:08 12.36 68.2 197 3/8/06 15:09 12.4 64.7 198 3/8/06 15:10 12.44 62 199 3/8/06 15:11 12.45 62.5

5 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 200 3/8/06 15:12 12.4 64.5 201 3/8/06 15:13 12.42 63.8 202 3/8/06 15:14 12.4 61.8 203 3/8/06 15:15 12.47 66.5 204 3/8/06 15:16 12.37 68.4 205 3/8/06 15:17 12.35 67.5 206 3/8/06 15:18 12.38 69 207 3/8/06 15:19 12.38 65.9 208 3/8/06 15:20 12.36 62.9 209 3/8/06 15:21 12.34 61.7 210 3/8/06 15:22 12.35 63 211 3/8/06 15:23 12.41 66 212 3/8/06 15:24 12.38 67.2 213 3/8/06 15:25 12.39 66.4 214 3/8/06 15:26 12.35 65.2 215 3/8/06 15:27 12.41 66.5 216 3/8/06 15:28 12.43 68 217 3/8/06 15:29 12.39 67.9 218 3/8/06 15:30 12.39 64.7 219 3/8/06 15:31 12.39 66.1 220 3/8/06 15:32 12.38 65.2 221 3/8/06 15:33 12.39 63.6 222 3/8/06 15:34 12.38 67.4 223 3/8/06 15:35 12.36 70.2 224 3/8/06 15:36 12.36 67.5 225 3/8/06 15:37 12.28 65.5 226 3/8/06 15:38 12.35 65.4 227 3/8/06 15:39 12.36 61.9 228 3/8/06 15:40 12.3 61.9 229 3/8/06 15:41 12.24 61.2 230 3/8/06 15:42 12.16 54.5 231 3/8/06 15:43 12.22 53.6 232 3/8/06 15:44 12.4 53.1 233 3/8/06 15:45 12.4 56.9 234 3/8/06 15:46 12.32 59 235 3/8/06 15:47 12.28 62.7 236 3/8/06 15:48 12.32 61.9 237 3/8/06 15:49 12.33 61.3 238 3/8/06 15:50 12.29 63.5

6 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 239 3/8/06 15:51 12.23 61.9 240 3/8/06 15:52 12.25 60.3 241 3/8/06 15:53 12.19 60.5 242 3/8/06 15:54 12.15 60.5 243 3/8/06 15:55 12.17 62.3 244 3/8/06 15:56 12.13 60.4 245 3/8/06 15:57 12.15 63.2 246 3/8/06 15:58 12.18 67 247 3/8/06 15:59 12.13 66.7 248 3/8/06 16:00 12.18 61 249 3/8/06 16:01 12.16 55.3 250 1/0/00 0:00 251 1/0/00 0:00 252 1/0/00 0:00 253 1/0/00 0:00 254 3/8/06 16:06 12.12 64.1 255 3/8/06 16:07 12.12 63.5 256 3/8/06 16:08 12.07 61.1 257 3/8/06 16:09 12.1 61.7 258 3/8/06 16:10 12.14 60 259 3/8/06 16:11 12.15 61.2 260 3/8/06 16:12 12.15 57.2 261 3/8/06 16:13 12.13 57.6 262 3/8/06 16:14 12.19 57 263 3/8/06 16:15 12.12 52.9 264 3/8/06 16:16 12.14 52.4 265 3/8/06 16:17 12.19 54.4 266 3/8/06 16:18 12.21 57.9 267 3/8/06 16:19 12.22 58.2 268 3/8/06 16:20 12.24 57.6 269 3/8/06 16:21 12.15 57.6 270 3/8/06 16:22 12.18 54.6 271 3/8/06 16:23 12.19 52.2 272 3/8/06 16:24 12.2 52.2 273 3/8/06 16:25 12.2 55.5 274 3/8/06 16:26 12.24 56.8 275 3/8/06 16:27 12.2 56.7 276 3/8/06 16:28 12.22 54.6 277 3/8/06 16:29 12.2 52.6

7 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 278 3/8/06 16:30 12.28 53.3 279 3/8/06 16:31 12.24 54.3 280 3/8/06 16:32 12.24 52.7 281 3/8/06 16:33 12.24 56.1 282 3/8/06 16:34 12.23 54.1 283 3/8/06 16:35 12.22 57.4 284 3/8/06 16:36 12.22 61.5 285 3/8/06 16:37 12.22 59.7 286 3/8/06 16:38 12.23 58.2 287 3/8/06 16:39 12.16 55.4 288 3/8/06 16:40 12.17 54.1 289 3/8/06 16:41 12.17 54.9 290 3/8/06 16:42 12.21 55.5 291 3/8/06 16:43 12.24 56.1 292 3/8/06 16:44 12.19 56.9 293 3/8/06 16:45 12.26 60.7 294 3/8/06 16:46 12.31 63 295 3/8/06 16:47 12.29 63.6 296 3/8/06 16:48 12.2 64.9 297 3/8/06 16:49 12.21 65.5 298 3/8/06 16:50 12.27 64.5 299 3/8/06 16:51 12.27 62.9 300 3/8/06 16:52 12.31 59.9 301 3/8/06 16:53 12.31 54.8 302 3/8/06 16:54 12.34 54.7 303 3/8/06 16:55 12.27 54.4 304 3/8/06 16:56 12.24 55.4 305 3/8/06 16:57 12.19 53.8 306 3/8/06 16:58 12.25 50.5 307 3/8/06 16:59 12.27 52.7 308 3/8/06 17:00 12.26 55.4 309 3/8/06 17:01 12.28 59.2 310 3/8/06 17:02 12.36 60.5 311 3/8/06 17:03 12.29 60.2 312 3/8/06 17:04 12.31 61.3 313 3/8/06 17:05 12.33 61.5 314 3/8/06 17:06 12.32 61.3 315 3/8/06 17:07 12.35 62.9 316 3/8/06 17:08 12.28 59.7

8 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 317 3/8/06 17:09 12.28 61.7 318 3/8/06 17:10 12.37 64 319 3/8/06 17:11 12.36 67.9 320 3/8/06 17:12 12.37 70.7 321 3/8/06 17:13 12.33 64.4 322 3/8/06 17:14 12.27 62.5 323 3/8/06 17:15 12.23 62.8 324 3/8/06 17:16 12.24 59 325 3/8/06 17:17 12.33 54.1 326 3/8/06 17:18 12.36 49.7 327 3/8/06 17:19 12.41 56.3 328 3/8/06 17:20 12.27 60 329 3/8/06 17:21 12.38 62 330 3/8/06 17:22 12.44 62 331 3/8/06 17:23 12.35 58.6 332 3/8/06 17:24 12.27 55.5 333 3/8/06 17:25 12.27 52.9 334 3/8/06 17:26 12.25 53.2 335 3/8/06 17:27 12.23 54.5 336 3/8/06 17:28 12.31 57.4 337 3/8/06 17:29 12.33 63.8 338 3/8/06 17:30 12.42 68.9 339 3/8/06 17:31 12.44 71.8 340 3/8/06 17:32 12.47 71.2 341 3/8/06 17:33 12.4 71.8 342 3/8/06 17:34 12.39 67.9 343 3/8/06 17:35 12.38 67.4 344 3/8/06 17:36 12.33 65.5 345 3/8/06 17:37 12.32 66.5 346 3/8/06 17:38 12.34 65.8 347 3/8/06 17:39 12.22 68.9 348 3/8/06 17:40 12.29 72.7 349 3/8/06 17:41 12.32 71.1 350 3/8/06 17:42 12.25 67.4 351 3/8/06 17:43 12.27 66.4 352 3/8/06 17:44 12.25 63.5 353 3/8/06 17:45 12.32 69.3 354 3/8/06 17:46 12.3 74.9 355 3/8/06 17:47 12.33 81.4

9 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 356 3/8/06 17:48 12.35 79.1 357 3/8/06 17:49 12.3 80.1 358 3/8/06 17:50 12.29 75 359 3/8/06 17:51 12.21 74.1 360 3/8/06 17:52 12.23 72.1 361 3/8/06 17:53 12.22 68.9 362 3/8/06 17:54 12.19 63.5 363 3/8/06 17:55 12.08 56.3 364 3/8/06 17:56 12.15 51.8 365 3/8/06 17:57 12.26 52 366 3/8/06 17:58 12.32 54.6 367 3/8/06 17:59 12.35 60.4 368 3/8/06 18:00 12.33 62.9 369 3/8/06 18:01 12.39 67.6 370 3/8/06 18:02 12.28 62.8 371 3/8/06 18:03 12.23 57 372 3/8/06 18:04 12.14 54.8 373 3/8/06 18:05 12.11 57 374 3/8/06 18:06 12.14 58.4 375 3/8/06 18:07 12.08 55 376 3/8/06 18:08 12.05 54.4 377 3/8/06 18:09 12.28 59.6 378 3/8/06 18:10 12.3 60.4 379 3/8/06 18:11 12.28 63.6 380 3/8/06 18:12 12.33 65.7 381 3/8/06 18:13 12.33 69.3 382 3/8/06 18:14 12.26 67.4 383 3/8/06 18:15 12.27 63.6 384 3/8/06 18:16 12.23 59.6 385 3/8/06 18:17 12.21 59.8 386 3/8/06 18:18 12.21 58 387 3/8/06 18:19 12.23 61.6 388 3/8/06 18:20 12.31 60.6 389 3/8/06 18:21 12.33 62.5 390 3/8/06 18:22 12.27 64.6 391 3/8/06 18:23 12.23 64.1 392 3/8/06 18:24 12.23 66 393 3/8/06 18:25 12.28 70.6 394 3/8/06 18:26 12.28 69.5

10 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 395 3/8/06 18:27 12.3 68.8 396 3/8/06 18:28 12.24 63.9 397 3/8/06 18:29 12.23 61.7 398 3/8/06 18:30 12.22 60.7 399 3/8/06 18:31 12.2 57.5 400 3/8/06 18:32 12.17 56.4 401 3/8/06 18:33 12.27 59.8 402 3/8/06 18:34 12.26 57.1 403 3/8/06 18:35 12.27 54.6 404 3/8/06 18:36 12.32 53.4 405 3/8/06 18:37 12.36 53.1 406 3/8/06 18:38 12.38 55.1 407 3/8/06 18:39 12.38 61.9 408 3/8/06 18:40 12.35 64.4 409 3/8/06 18:41 12.34 64.5 410 3/8/06 18:42 12.29 62.2 411 3/8/06 18:43 12.29 62 412 3/8/06 18:44 12.35 62.4 413 3/8/06 18:45 12.31 61.8 414 3/8/06 18:46 12.27 62.5 415 3/8/06 18:47 12.29 67.4 416 3/8/06 18:48 12.31 70.4 417 3/8/06 18:49 12.26 71.9 418 3/8/06 18:50 12.27 70.6 419 3/8/06 18:51 12.28 71 420 3/8/06 18:52 12.26 69.8 421 3/8/06 18:53 12.24 65.3 422 3/8/06 18:54 12.3 62.3 423 3/8/06 18:55 12.27 61.9 424 3/8/06 18:56 12.26 60.1 425 3/8/06 18:57 12.32 52.7 426 3/8/06 18:58 12.25 43.9 427 3/8/06 18:59 12.35 44.8 428 3/8/06 19:00 12.28 44.8 429 3/8/06 19:01 12.21 41.9 430 3/8/06 19:02 12.16 42.7 431 3/8/06 19:03 12.16 44.3 432 3/8/06 19:04 12.32 47.3 433 3/8/06 19:05 12.31 48.9

11 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 434 3/8/06 19:06 12.32 49.4 435 3/8/06 19:07 12.24 48.8 436 3/8/06 19:08 12.2 49.8 437 3/8/06 19:09 12.33 50.6 438 3/8/06 19:10 12.24 51.7 439 3/8/06 19:11 12.41 56.2 440 3/8/06 19:12 12.4 59.6 441 3/8/06 19:13 12.36 59.2 442 3/8/06 19:14 12.36 60.7 443 3/8/06 19:15 12.36 64.7 444 3/8/06 19:16 12.28 65.9 445 3/8/06 19:17 12.25 59.9 446 3/8/06 19:18 12.26 54.5 447 3/8/06 19:19 12.27 53.4 448 3/8/06 19:20 12.28 54.8 449 3/8/06 19:21 12.28 53.4 450 3/8/06 19:22 12.25 47.5 451 3/8/06 19:23 12.35 45.7 452 3/8/06 19:24 12.32 46.4 453 3/8/06 19:25 12.12 45.2 454 3/8/06 19:26 12.12 49 455 3/8/06 19:27 12.19 49.8 456 3/8/06 19:28 12.25 51.8 457 3/8/06 19:29 12.27 57.7 458 3/8/06 19:30 12.37 60.5 459 3/8/06 19:31 12.34 60.8 460 3/8/06 19:32 12.34 61.3 461 3/8/06 19:33 12.29 60 462 3/8/06 19:34 12.19 60.3 463 3/8/06 19:35 12.24 59.1 464 3/8/06 19:36 12.15 56.1 465 3/8/06 19:37 12.2 61 466 3/8/06 19:38 12.22 58.5 467 3/8/06 19:39 12.13 58 468 3/8/06 19:40 12.23 58.5 469 3/8/06 19:41 12.25 59.7 470 3/8/06 19:42 12.2 63.9 471 3/8/06 19:43 12.23 64.9 472 3/8/06 19:44 12.16 65

12 of 13

### SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 473 3/8/06 19:45 12.15 63 474 3/8/06 19:46 12.17 64.8 475 3/8/06 19:47 12.25 63.6 476 3/8/06 19:48 12.24 59.8 477 3/8/06 19:49 12.21 58 478 3/8/06 19:50 12.16 59.9 479 3/8/06 19:51 12.13 62 480 3/8/06 19:52 12.13 61.8 481 3/8/06 19:53 12.07 60.4 482 3/8/06 19:54 12.13 63.7 483 3/8/06 19:55 12.11 64.6 484 3/8/06 19:56 12.18 65.2 485 3/8/06 19:57 12.23 68.7 486 3/8/06 19:58 12.2 72 487 3/8/06 19:59 12.17 69.8 488 3/8/06 20:00 12.23 62.6

13 of 13

## APPENDIX C PARTICULATE LABORATORY ANALYTICAL DATACustomerAIR SERVICESPlantBIG BENDUnit3Method5-BStack Test Completion Date3/8/2006AnalystSSSample NumberAA82365ACETONE BEAKER1st weighingDate3/13/2006Time9:10% RH41.0%2nd weighingDate3/13/2006Time16:00% RH41.0%3rd weighingDateTime% RH4th weighingDateTime% RH***Blank***Run 1Run 2Run 3Run 1SRun 2SRun 3SAcetone Container IDAIR 41AIR 107AIR 40AIR 47AIR 14AIR 80AIR 101Acetone Rinse Vol.(Va), mls200.00002002002002002002001st Gross Wt., grams109.5121106.1002112.4230104.2867107.5494100.4501108.65312nd Gross Wt., grams109.5117106.1002112.4229104.2864107.5492100.4499108.65273rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams109.51190106.10020112.42295104.28655107.54930100.45000108.65290Tare Wt., grams109.51105106.09485112.41320104.28115107.53900100.44455108.64790Acetone Blank Wt.,mg0.850.850.850.850.850.850.85Acetone Particulate Wt.,mg4.508.904.559.454.604.15Acetone Residue, mg/g0.0054Acetone Blank CriteriaOK to subtract acetone blankFILTER1st weighingDate3/13/2006Time9:40% RH41.0%Date3/13/2006Time16:05% RH41.0%3rd weighingDateTime% RH4th weighingDateTime% RHFilter/Thimble ID2022222030212030262030282030312030272030321st Gross Wt., grams0.26960.28320.28180.28210.28380.28420.28622nd Gross Wt., grams0.26960.28310.28180.28220.28370.28410.28603rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams0.269600.283150.281800.282150.283750.284150.28610Tare Wt., grams0.269350.266950.266850.265800.267200.268100.27015Filter Particulate Wt.,mg16.2014.9516.3516.5516.0515.95Difference, milligrams0.25Total Sample Particulate Wt.,mg20.7023.8520.9026.0020.6520.10Start Here

## APPENDIX D BOILER/PRECIPITATOR OPERATIONAL DATA

## APPENDIX E FUEL ANALYSIS

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272
Report For: 

## Laboratory ID: AA82365

Date and Time Collected: Sampled By: 

### Sample Information
ASG Description: 

### Location Code: 3/29/2006 Report Date:

Big Bend 3 Compliance 

### TE_BB_3_COMP_COAL

Project Account Code: 3/10/2006 Date of Sample Receipt: Sample Collection Method:


### Laboratory Results 3/8/2006 5:06:00 PM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
Ash, as Received % 0.01 ASTM D-3174 PJ 7.53 3/13/2006 2:20:00 PM Ash, Dry Basis % 0.01 ASTM D-3174 PJ 8.65 3/13/2006 2:20:00 PM BTU, as Received BTU/Lb 100 ASTM D-5865 PJ 11603 3/14/2006 1:54:00 PM BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 PJ 13321 3/14/2006 1:54:00 PM BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 PJ 14582 3/14/2006 1:54:00 PM Calculated Heat Inpu t, mmBtu/hr mmBtu/hr RAM 4057 3/29/2006 2:27:00 PM Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 E PA Method 5B/1 7 RAM 4.50 3/29/2006 2:27:00 PM Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 E PA Method 5B/1 7 RAM 8.90 3/29/2006 2:27:00 PM Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 E PA Method 5B/1 7 RAM 4.55 3/29/2006 2:27:00 PM Particulate Wt., Acetone Beaker, Run 4 mg 0.0001 E PA Method 5B/1 7 RAM 9.45 3/29/2006 2:27:00 PM Particulate Wt., Acetone Beaker, Run 5 mg 0.0001 E PA Method 5B/1 7 RAM 4.60 3/29/2006 2:27:00 PM Particulate Wt., Acetone Beaker, Run 6 mg 0.0001 E PA Method 5B/1 7 RAM 4.15 3/29/2006 2:27:00 PM Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 E PA Method 5B/1 7 RAM 16.20 3/29/2006 2:27:00 PM Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 E PA Method 5B/1 7 RAM 14.95 3/29/2006 2:27:00 PM Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 E PA Method 5B/1 7 RAM 16.35 3/29/2006 2:27:00 PM Particulate Wt., Filter/Thimble, Run 4 mg 0.0001 E PA Method 5B/1 7 RAM 16.55 3/29/2006 2:27:00 PM Particulate Wt., Filter/Thimble, Run 5 mg 0.0001 E PA Method 5B/1 7 RAM 16.05 3/29/2006 2:27:00 PM Particulate Wt., Filter/Thimble, Run 6 mg 0.0001 E PA Method 5B/1 7 RAM 15.95 3/29/2006 2:27:00 PM Particulate Wt., Total Sample, Run 1 mg 0.0001 E PA Method 5B/1 7 RAM 20.70 3/29/2006 2:27:00 PM Particulate Wt., Total Sample, Run 2 mg 0.0001 E PA Method 5B/1 7 RAM 23.85 3/29/2006 2:27:00 PM Particulate Wt., Total Sample, Run 3 mg 0.0001 E PA Method 5B/1 7 RAM 20.90 3/29/2006 2:27:00 PM Particulate Wt., Total Sample, Run 4 mg 0.0001 E PA Method 5B/1 7 RAM 26.00 3/29/2006 2:27:00 PM Particulate Wt., Total Sample, Run 5 mg 0.0001 E PA Method 5B/1 7 RAM 20.65 3/29/2006 2:27:00 PM Particulate Wt., Total Sample, Run 6 mg 0.0001 E PA Method 5B/1 7 RAM 20.10 3/29/2006 2:27:00 PM PM non-sootblowing, lbs/ mmBtu lb/mmBtu EPA RM-5/17 RAM 0.02 3/29/2006 2:27:00 PM PM sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 RAM 0.02 3/29/2006 2:27:00 PM
Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated PJ 4.59 3/14/2006 1:54:00 PM

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C RAM 609 3/29/2006 2:27:00 PM
Sulfur, as Received % 0.02 ASTM D-4239 PJ 2.80 3/13/2006 2:19:00 PM Sulfur, Dry Basis % 0.08 ASTM D-4239 PJ 3.22 3/13/2006 2:19:00 PM

Report Number: -032906- 14 AA82365 Page 1 of 2 Laboratory Services certifies that the te st results in this report meet all require ments of the NELAC standards, unless indicat ed otherwise in the body of the report.

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
Total Moisture % 0.1 ASTM D-3173 PJ 12.9 3/13/2006 2:19:00 PM 

### Comments

Data Qualifier Codes Explanation:



### Robert Dorey, Manager, Laboratory Services Subcontracted Laboratories:

A ll results calculated on a wet to wet basis

, unless otherwise indicated.

Report Number: -032906- 14 AA82365 Page 2 of 2 Laboratory Services certifies that the te st results in this report meet all require ments of the NELAC standards, unless indicat ed otherwise in the body of the report.

## APPENDIX F FIELD DATA SHEETS

## APPENDIX G SAMPLING EQUIPMENT CALIBRATIONS

### Environmental Service s A ir Services Grou p



## SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS
CONSOLE (MB 06) USEPA RM 5 INITIA L 01/04/2006 (ORIFICE) 1.006 POST TEST 03/21/2006 1.016
NOZZLE (SN 19) INITIA L 01/04/2006 CALIPER 0.280 POST TEST 03/22/2006 MEASUREMENTS 0.280

PYROMETER (PY 10 ) 01/04/2006 ASTM THERMOMETER + 2 o 

### F
PITOT TUBE (PT 09) 02/22/2006 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 06) 02/27/2006 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Red Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30 "Hg Instrument Code Number: ^MB06 Theoretical Critical Vacuum: 14.15 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.64 15 46.100 52.925 6.825 77 77 77 77 1.15 15 52.925 62.029 9.104 78 77 77 78 1.95 15 62.029 73.770 11.741 77 78 83 78 3.70 15 73.770 89.845 16.075 83 78 89 79

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3483 22.5 75 75 75.0 55 0.4660 20.0 75 75 75.0 63 0.5971 19.0 75 75 75.0 73 0.8177 16.0 75 75 75.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.736 6.776 6.851 1.006 0.000 1.739 -0.032 8.989 9.066 9.165 1.009 0.003 1.744 -0.027 11.583 11.617 11.744 1.003 -0.003 1.796 0.025 15.830 15.909 16.083 1.005 -0.001 1.806 0.035 Averages: 1.006 1.771

Review/Approval: Date: 18-Jan-06 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

1/4/2006

JAV

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice

### Environmental Services Air Services Group

Manufacturer: ThermoAnderson Calibration Date: Model Number:MST Barometric Pressure: 29.92 "Hg Instrument Code Number: MB06 Theoretical Critical Vacuum: 14.11 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: RED

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 1.15 10 34.701 40.734 6.033 76 79 77 81 1.15 10 40.734 46.776 6.042 77 81 77 81 1.15 10 46.776 52.828 6.052 77 81 77 82

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4660 20.5 75 75 75.0 55 0.4660 20.5 75 75 75.0 55 0.4660 20.5 75 75 75.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

5.932 6.028 6.110 1.016 0.000 1.746 0.002 5.933 6.028 6.110 1.016 0.000 1.744 -0.001 5.940 6.028 6.110 1.015 -0.001 1.743 -0.001 Averages: 1.016 1.744 Prior Y: 1.006 % Difference: -0.96%

Review/Approval: Date: Big Bend Unit 3 IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

CRD 3/21/2006 

### POST - TEST CALIBRATION CHECK

3/27/2006 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Services A ir Services Group

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET

Calibration Date: 1/4/2005 Responsible Party: R.A. Barthelette Jr.

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.300 0.300 0.300 0.000 0.118 ^SN04 0.320 0.320 0.320 0.000 0.126 ^SN05 0.380 0.380 0.375 0.002 0.149 ^SN06 0.500 0.500 0.500 0.000 0.197 ^SN09 0.700 0.700 0.700 0.000 0.276 ^SN10 0.755 0.755 0.750 0.002 0.297 ^SN12 0.985 0.990 0.990 0.002 0.389 ^SN15 0.420 0.420 0.415 0.002 0.165 ^SN16 0.500 0.500 0.500 0.000 0.197 ^SN19 0.715 0.710 0.710 0.002 0.280 ^SN22 0.930 0.935 0.935 0.002 0.367 ^SN30 0.795 0.800 0.795 0.002 0.314 ^SN36 0.480 0.480 0.480 0.000 0.189 ^SN37 0.520 0.525 0.525 0.002 0.206 ^SN38 0.640 0.640 0.635 0.002 0.251 ^SN46 0.480 0.480 0.480 0.000 0.189 ^SN47 0.515 0.515 0.515 0.000 0.203 ^SN48 0.640 0.640 0.635 0.002 0.251 ^SN50 0.795 0.795 0.790 0.002 0.312 ^SN58 0.615 0.615 0.620 0.002 0.243 ^SN68 0.630 0.630 0.625 0.002 0.247 ^SN69 0.950 0.950 0.955 0.002 0.375 ^SN70 1.560 1.560 1.560 0.000 0.614 ^SN71 1.560 1.560 1.560 0.000 0.614 ^SN72 0.955 0.955 0.955 0.000 0.376 ^SN73 1.280 1.285 1.280 0.002 0.505 ^SN74 1.245 1.245 1.245 0.000 0.490 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".


### QA/QC Review by: Date: 18-Jan-06

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 3/22/2006 

### Calibration Personnel: CRD 

### Test Designation: Big Bend 3



### Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN19 0.715 0.710 0.710 0.002 0.280

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN19 was 0.280

Difference (Pre-test/Post-test) is: 0.000

QA/QC Review by: 27-Mar-06

### Environmental Services A ir Services Group Pyrometer Calibration Red Team Pyrometer Under Tes t Pyrometer Number: ^PY10 Labworks Sample # N/ A Calibration Date: 1/4/2006

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 10/6/2005 Calibration Personnel (Typed and Signature): Jorge A Varino

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 400 0 2 

### 212 211 1 3 

### 32 32 0

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: Date: 

### 18-Jan-06Environmental Services Air Services Group

_ _

s PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT10 Calibration Date 2/22/2006 Operating Quarter/Year: 1/06 Shared Resource Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.9 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 1.2 degrees Pass α < 10 degrees β 1 0 degrees Pass ( α 1 measured across top impact openings) β 2 0.1 degrees Pass ( α 2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α
, Ζ
, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.2 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.44 cm W < 0.08 cm (Asin ο )
Ζ 0.009 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 1.2 degrees ψ angle between tips W 0.051 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by: Charles Dufeny

Q uality Assurance Review / Approval: 24-Feb-06

### Environmental Services A ir Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR05 Calibration Date: 2/27/2006 Calibration Personnel: RAB Labworks #: A A82064 Barometer Reading Reference Reading Difference Time Inches Mercury Inches Mercury "Hg 14:05 30.20 30.24 -0.04 15:05 30.19 30.24 -0.05 0:00 0:00 0:00 A verage Difference: -0.045 Note: Barometric readings must agree within ± 0.1 "Hg. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport

HYGROMETER CALIBRATION
Hygrometer Reading Psychrometer Actual Time Outside % RH Tw Td % RH 0:00 41.0 55.0 68.0 43.0 0:00 0:00 0:00 0:00 A verage Difference % RH: 2 Note: Hygromerer readings must agree within ± 5% RH. Comments (Note any adjustments):

QA/QC Review by: Date: 7-Mar-06

## APPENDIX H CHAIN OF CUSTODY

## APPENDIX I TEST PARTICIPANTS

## TEST PARTICIPANTS

AIR SERVICES GROUP ENVIRONMENTAL SERVICES
Charles Dufeny Environmental Technician
Juan Ramirez Environmental Technician Jorge Varino Technician
BIG BEND STATION

Karen Zwolak Senior Environmental Consultant