1

CHANG, RANDALL

From: Young, Lisa Y L <lisa.young@doh.hawaii.gov>

Sent: Wednesday, January 13, 2016 4:25 PM

To: CHANG, RANDALL

Subject: RE: HDOH Volcano SO2 EE Demo Package - January 2016

Attachments: 2012-2014 SO2 EE doc_FINAL APP D SK_ 101915_PA hours.pdf

Hi Randy,

Sorry about the missing pages, attached is the missing pages.  I guess we were in a rush to meet the timeline and just

missed these.

Hopefully it’s complete now.

Thanks,

Lisa

From: CHANG, RANDALL [mailto:Chang.Randall@epa.gov]  

Sent: Wednesday, January 13, 2016 11:27 AM

To: Young, Lisa Y L

Subject: HDOH Volcano SO2 EE Demo Package ‐ January 2016

Hi Lisa,

               The Volcano SO2 EE Demonstration package dated January 2016 that was submitted to our office, was missing

some pages from Appendix D. Namely, there are pages showing the hours exceeding the 1 hour SO2 NAAQS for Hilo,

Mountain View, and Ocean View. However, the pages for hours exceeding the 1 hour SO2 NAAQS for Pahala are

missing. If you could send those to us at your earliest convenience, that would be great. Thanks.

Randy

Randall Chang 

U.S. EPA, Pacific Southwest (Region 9) 

Air Quality Analysis Office 

75 Hawthorne Street (AIR-7) 

San Francisco, CA 94105 

phone: 415.947.4180 

email: chang.randall@epa.gov
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

1/1/2012 0:00 131.3 1/2/2012 17:00 3.6 1/5/2012 10:00 97.5 1/7/2012 3:00 231.1 1/8/2012 20:00 4.0

1/1/2012 1:00 367.6 1/2/2012 18:00 3.3 1/5/2012 11:00 15.6 1/7/2012 4:00 580.4 1/8/2012 21:00 4.8

1/1/2012 2:00 273.4 1/2/2012 19:00 3.2 1/5/2012 12:00 5.9 1/7/2012 5:00 557.2 1/8/2012 22:00 16.8

1/1/2012 3:00 187.1 1/2/2012 20:00 3.1 1/5/2012 13:00 4.5 1/7/2012 6:00 599.0 1/8/2012 23:00 93.7

1/1/2012 4:00 154.9 1/2/2012 21:00 3.0 1/5/2012 14:00 3.9 1/7/2012 7:00 442.9 1/9/2012 0:00 128.4

1/1/2012 5:00 169.5 1/2/2012 22:00 2.9 1/5/2012 15:00 4.3 1/7/2012 8:00 538.1 1/9/2012 1:00 163.1

1/1/2012 6:00 166.6 1/2/2012 23:00 2.9 1/5/2012 16:00 5.1 1/7/2012 9:00 1025.6 1/9/2012 2:00 191.3

1/1/2012 7:00 147.1 1/4/2012 0:00 13.5 1/5/2012 17:00 5.9 1/7/2012 10:00 288.5 1/9/2012 3:00 350.4

1/1/2012 8:00 118.3 1/4/2012 1:00 16.4 1/5/2012 18:00 6.7 1/7/2012 11:00 19.8 1/9/2012 4:00 249.7

1/1/2012 9:00 79.9 1/4/2012 2:00 22.5 1/5/2012 19:00 17.6 1/7/2012 12:00 9.7 1/9/2012 5:00 269.2

1/1/2012 10:00 37.7 1/4/2012 3:00 29.4 1/5/2012 20:00 32.8 1/7/2012 13:00 4.6 1/9/2012 6:00 174.0

1/1/2012 11:00 10.7 1/4/2012 4:00 36.0 1/5/2012 21:00 71.9 1/7/2012 14:00 4.0 1/9/2012 7:00 93.4

1/1/2012 12:00 5.7 1/4/2012 5:00 153.5 1/5/2012 22:00 179.3 1/7/2012 15:00 3.8 1/9/2012 8:00 78.0

1/1/2012 13:00 4.0 1/4/2012 6:00 121.9 1/5/2012 23:00 329.7 1/7/2012 16:00 3.7 1/9/2012 9:00 28.7

1/1/2012 14:00 3.8 1/4/2012 7:00 137.9 1/6/2012 0:00 380.4 1/7/2012 17:00 4.5 1/9/2012 10:00 10.6

1/1/2012 15:00 3.5 1/4/2012 8:00 132.9 1/6/2012 1:00 446.7 1/7/2012 18:00 6.6 1/9/2012 11:00 11.5

1/1/2012 16:00 3.5 1/4/2012 9:00 37.9 1/6/2012 2:00 452.3 1/7/2012 19:00 6.5 1/9/2012 12:00 4.6

1/1/2012 17:00 3.7 1/4/2012 10:00 21.4 1/6/2012 3:00 614.8 1/7/2012 20:00 20.1 1/9/2012 13:00 3.5

1/1/2012 18:00 4.7 1/4/2012 11:00 6.0 1/6/2012 4:00 598.1 1/7/2012 21:00 35.4 1/9/2012 14:00 3.3

1/1/2012 19:00 6.2 1/4/2012 12:00 4.4 1/6/2012 5:00 537.5 1/7/2012 22:00 157.9 1/9/2012 15:00

1/1/2012 20:00 8.5 1/4/2012 13:00 3.5 1/6/2012 6:00 340.8 1/7/2012 23:00 310.9 1/9/2012 16:00 3.2

1/1/2012 21:00 17.8 1/4/2012 14:00 3.2 1/6/2012 7:00 417.9 1/8/2012 0:00 270.1 1/9/2012 17:00 3.2

1/1/2012 22:00 37.1 1/4/2012 15:00 3.0 1/6/2012 8:00 384.7 1/8/2012 1:00 269.1 1/9/2012 18:00 3.3

1/1/2012 23:00 60.4 1/4/2012 16:00 2.9 1/6/2012 9:00 446.7 1/8/2012 2:00 246.5 1/9/2012 19:00 3.8

1/2/2012 0:00 214.9 1/4/2012 17:00 3.2 1/6/2012 10:00 19.8 1/8/2012 3:00 157.4 1/9/2012 20:00 5.8

1/2/2012 1:00 397.0 1/4/2012 18:00 5.7 1/6/2012 11:00 8.2 1/8/2012 4:00 126.7 1/9/2012 21:00 7.8

1/2/2012 2:00 343.5 1/4/2012 19:00 10.8 1/6/2012 12:00 5.1 1/8/2012 5:00 117.9 1/9/2012 22:00 12.4

1/2/2012 3:00 255.5 1/4/2012 20:00 16.1 1/6/2012 13:00 3.7 1/8/2012 6:00 56.3 1/9/2012 23:00 24.1

1/2/2012 4:00 703.2 1/4/2012 21:00 14.4 1/6/2012 14:00 3.3 1/8/2012 7:00 64.7 1/10/2012 0:00 49.9

1/2/2012 5:00 632.3 1/4/2012 22:00 89.8 1/6/2012 15:00 3.6 1/8/2012 8:00 55.8 1/10/2012 1:00 102.8

1/2/2012 6:00 318.5 1/4/2012 23:00 39.5 1/6/2012 16:00 3.8 1/8/2012 9:00 45.2 1/10/2012 2:00 139.1

1/2/2012 7:00 252.4 1/5/2012 0:00 17.2 1/6/2012 17:00 3.8 1/8/2012 10:00 16.3 1/10/2012 3:00 73.0

1/2/2012 8:00 124.5 1/5/2012 1:00 131.6 1/6/2012 18:00 5.4 1/8/2012 11:00 6.8 1/10/2012 4:00 50.7

1/2/2012 9:00 20.7 1/5/2012 2:00 201.8 1/6/2012 19:00 6.8 1/8/2012 12:00 4.6 1/10/2012 5:00 150.3

1/2/2012 10:00 8.4 1/5/2012 3:00 224.9 1/6/2012 20:00 7.6 1/8/2012 13:00 3.5 1/10/2012 6:00 141.4

1/2/2012 11:00 4.8 1/5/2012 4:00 288.0 1/6/2012 21:00 8.9 1/8/2012 14:00 3.3 1/10/2012 7:00 77.9

1/2/2012 12:00 4.0 1/5/2012 5:00 190.8 1/6/2012 22:00 17.3 1/8/2012 15:00 3.3 1/10/2012 8:00 66.0

1/2/2012 13:00 3.6 1/5/2012 6:00 201.1 1/6/2012 23:00 85.4 1/8/2012 16:00 3.4 1/10/2012 9:00 67.7

1/2/2012 14:00 3.5 1/5/2012 7:00 255.2 1/7/2012 0:00 251.3 1/8/2012 17:00 3.7 1/10/2012 10:00 13.6

1/2/2012 15:00 1/5/2012 8:00 391.0 1/7/2012 1:00 229.9 1/8/2012 18:00 4.1 1/10/2012 11:00 5.5

1/2/2012 16:00 3.7 1/5/2012 9:00 326.1 1/7/2012 2:00 242.4 1/8/2012 19:00 4.1 1/10/2012 12:00 4.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 22
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

1/10/2012 13:00 3.3 1/19/2012 6:00 25.9 1/20/2012 23:00 45.2 1/22/2012 16:00 3.6 1/25/2012 9:00 6.8

1/10/2012 14:00 1/19/2012 7:00 14.2 1/21/2012 0:00 27.4 1/22/2012 17:00 4.1 1/25/2012 10:00 8.8

1/10/2012 15:00 4.5 1/19/2012 8:00 26.7 1/21/2012 1:00 27.7 1/22/2012 18:00 3.9 1/25/2012 11:00 4.4

1/10/2012 16:00 3.4 1/19/2012 9:00 31.6 1/21/2012 2:00 52.2 1/22/2012 19:00 3.7 1/25/2012 12:00 3.8

1/10/2012 17:00 3.3 1/19/2012 10:00 19.3 1/21/2012 3:00 107.1 1/22/2012 20:00 15.4 1/25/2012 13:00 3.2

1/10/2012 18:00 4.4 1/19/2012 11:00 5.3 1/21/2012 4:00 73 1/22/2012 21:00 99.1 1/25/2012 14:00 3.1

1/10/2012 19:00 5.7 1/19/2012 12:00 3.6 1/21/2012 5:00 71.9 1/22/2012 22:00 341.8 1/25/2012 15:00 3

1/10/2012 20:00 8.6 1/19/2012 13:00 3.2 1/21/2012 6:00 313 1/22/2012 23:00 666 1/25/2012 16:00 3

1/10/2012 21:00 43.1 1/19/2012 14:00 2.9 1/21/2012 7:00 372 1/23/2012 0:00 935.1 1/25/2012 17:00 3

1/10/2012 22:00 78.2 1/19/2012 15:00 3.4 1/21/2012 8:00 423.1 1/23/2012 1:00 752.7 1/25/2012 18:00 2.9

1/10/2012 23:00 149 1/19/2012 16:00 3 1/21/2012 9:00 144.6 1/23/2012 2:00 376.3 1/25/2012 19:00 2.9

1/11/2012 0:00 146.9 1/19/2012 17:00 2.9 1/21/2012 10:00 34.1 1/23/2012 3:00 440.8 1/25/2012 20:00 2.8

1/11/2012 1:00 91.9 1/19/2012 18:00 3 1/21/2012 11:00 8.3 1/23/2012 4:00 905.5 1/25/2012 21:00 2.8

1/11/2012 2:00 71.4 1/19/2012 19:00 2.9 1/21/2012 12:00 4.9 1/23/2012 5:00 1532.2 1/25/2012 22:00 2.9

1/11/2012 3:00 79.4 1/19/2012 20:00 11.9 1/21/2012 13:00 3.6 1/23/2012 6:00 1082.7 1/25/2012 23:00 2.7

1/11/2012 4:00 62.6 1/19/2012 21:00 11.9 1/21/2012 14:00 3.3 1/23/2012 7:00 299.9 1/27/2012 0:00 2.7

1/11/2012 5:00 40.2 1/19/2012 22:00 54.4 1/21/2012 15:00 3.2 1/23/2012 8:00 359.6 1/27/2012 1:00 2.7

1/11/2012 6:00 42.5 1/19/2012 23:00 225.9 1/21/2012 16:00 3.4 1/23/2012 9:00 35.7 1/27/2012 2:00 2.7

1/11/2012 7:00 23.8 1/20/2012 0:00 272.1 1/21/2012 17:00 4.9 1/23/2012 10:00 12 1/27/2012 3:00 3.1

1/11/2012 8:00 56.9 1/20/2012 1:00 247.3 1/21/2012 18:00 10.4 1/23/2012 11:00 6 1/27/2012 4:00 6.4

1/11/2012 9:00 42.4 1/20/2012 2:00 191 1/21/2012 19:00 9.5 1/23/2012 12:00 5.1 1/27/2012 5:00 25.2

1/11/2012 10:00 26.2 1/20/2012 3:00 207.4 1/21/2012 20:00 13.6 1/23/2012 13:00 3.5 1/27/2012 6:00 42.7

1/11/2012 11:00 7.4 1/20/2012 4:00 249.5 1/21/2012 21:00 25.3 1/23/2012 14:00 3.5 1/27/2012 7:00 72.3

1/11/2012 12:00 3.8 1/20/2012 5:00 471.9 1/21/2012 22:00 34.1 1/23/2012 15:00 1/27/2012 8:00 110.5

1/11/2012 13:00 3.3 1/20/2012 6:00 313.2 1/21/2012 23:00 98.6 1/23/2012 16:00 3.7 1/27/2012 9:00 59.4

1/11/2012 14:00 3.2 1/20/2012 7:00 237.7 1/22/2012 0:00 155.2 1/23/2012 17:00 3.8 1/27/2012 10:00 26.1

1/11/2012 15:00 3 1/20/2012 8:00 398.4 1/22/2012 1:00 180.5 1/23/2012 18:00 4.8 1/27/2012 11:00 8.3

1/11/2012 16:00 2.9 1/20/2012 9:00 125.9 1/22/2012 2:00 106.2 1/23/2012 19:00 5 1/27/2012 12:00 7

1/11/2012 17:00 3 1/20/2012 10:00 16.2 1/22/2012 3:00 262 1/23/2012 20:00 4.8 1/27/2012 13:00 10.3

1/11/2012 18:00 3.2 1/20/2012 11:00 8.1 1/22/2012 4:00 592.5 1/23/2012 21:00 4.7 1/27/2012 14:00 6.7

1/11/2012 19:00 3 1/20/2012 12:00 5.4 1/22/2012 5:00 753.5 1/23/2012 22:00 4.9 1/27/2012 15:00 4.3

1/11/2012 20:00 5.6 1/20/2012 13:00 3.9 1/22/2012 6:00 970.7 1/23/2012 23:00 5.6 1/27/2012 16:00 3.6

1/11/2012 21:00 13.8 1/20/2012 14:00 3.5 1/22/2012 7:00 900.6 1/25/2012 0:00 112.3 1/27/2012 17:00

1/11/2012 22:00 14.4 1/20/2012 15:00 3.4 1/22/2012 8:00 416.7 1/25/2012 1:00 165.5 1/27/2012 18:00 5.8

1/11/2012 23:00 14.1 1/20/2012 16:00 3.3 1/22/2012 9:00 10.6 1/25/2012 2:00 261.5 1/27/2012 19:00 4.2

1/19/2012 0:00 63.9 1/20/2012 17:00 3.4 1/22/2012 10:00 10.6 1/25/2012 3:00 190.5 1/27/2012 20:00 10.1

1/19/2012 1:00 47.6 1/20/2012 18:00 3.5 1/22/2012 11:00 5 1/25/2012 4:00 54 1/27/2012 21:00 14.3

1/19/2012 2:00 72.8 1/20/2012 19:00 3.9 1/22/2012 12:00 4.1 1/25/2012 5:00 8.3 1/27/2012 22:00 15.8

1/19/2012 3:00 37.1 1/20/2012 20:00 4.6 1/22/2012 13:00 3.6 1/25/2012 6:00 18.5 1/27/2012 23:00 36.9

1/19/2012 4:00 20.2 1/20/2012 21:00 11.4 1/22/2012 14:00 3.3 1/25/2012 7:00 14 1/28/2012 0:00 41.2

1/19/2012 5:00 32.7 1/20/2012 22:00 45 1/22/2012 15:00 3.5 1/25/2012 8:00 19.1 1/28/2012 1:00 41.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 23
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

1/28/2012 2:00 23.5 1/29/2012 19:00 25.5 1/31/2012 12:00 5.3 2/2/2012 5:00 121.8 2/3/2012 22:00 6.1

1/28/2012 3:00 43.2 1/29/2012 20:00 35.8 1/31/2012 13:00 3.5 2/2/2012 6:00 53.6 2/3/2012 23:00 5.5

1/28/2012 4:00 189.7 1/29/2012 21:00 86.1 1/31/2012 14:00 2/2/2012 7:00 127.3 2/7/2012 0:00 4.3

1/28/2012 5:00 580.6 1/29/2012 22:00 91.8 1/31/2012 15:00 4.7 2/2/2012 8:00 281.2 2/7/2012 1:00 4.5

1/28/2012 6:00 512 1/29/2012 23:00 90 1/31/2012 16:00 3.3 2/2/2012 9:00 183.3 2/7/2012 2:00 5.1

1/28/2012 7:00 423.2 1/30/2012 0:00 34.6 1/31/2012 17:00 3.5 2/2/2012 10:00 10 2/7/2012 3:00 29.7

1/28/2012 8:00 408.4 1/30/2012 1:00 64.6 1/31/2012 18:00 3.6 2/2/2012 11:00 15.6 2/7/2012 4:00 38.5

1/28/2012 9:00 153.2 1/30/2012 2:00 408.3 1/31/2012 19:00 4.1 2/2/2012 12:00 11.4 2/7/2012 5:00 27.7

1/28/2012 10:00 15.8 1/30/2012 3:00 365.1 1/31/2012 20:00 5.7 2/2/2012 13:00 3.8 2/7/2012 6:00 57.6

1/28/2012 11:00 15.4 1/30/2012 4:00 342 1/31/2012 21:00 4.8 2/2/2012 14:00 3.4 2/7/2012 7:00 48.5

1/28/2012 12:00 6 1/30/2012 5:00 286.7 1/31/2012 22:00 6.5 2/2/2012 15:00 3.5 2/7/2012 8:00 32.3

1/28/2012 13:00 6.8 1/30/2012 6:00 342.5 1/31/2012 23:00 15.7 2/2/2012 16:00 3.3 2/7/2012 9:00 36.1

1/28/2012 14:00 5.8 1/30/2012 7:00 345.7 2/1/2012 0:00 8.6 2/2/2012 17:00 3.3 2/7/2012 10:00 44

1/28/2012 15:00 5.9 1/30/2012 8:00 192.5 2/1/2012 1:00 27.3 2/2/2012 18:00 3.6 2/7/2012 11:00 75.6

1/28/2012 16:00 4.1 1/30/2012 9:00 100.1 2/1/2012 2:00 106.4 2/2/2012 19:00 3.7 2/7/2012 12:00 21.5

1/28/2012 17:00 5.8 1/30/2012 10:00 29.9 2/1/2012 3:00 108.4 2/2/2012 20:00 3.7 2/7/2012 13:00 18

1/28/2012 18:00 9.3 1/30/2012 11:00 9.6 2/1/2012 4:00 164.2 2/2/2012 21:00 3.7 2/7/2012 14:00

1/28/2012 19:00 9.9 1/30/2012 12:00 14.3 2/1/2012 5:00 295.4 2/2/2012 22:00 8.2 2/7/2012 15:00 15.8

1/28/2012 20:00 76.1 1/30/2012 13:00 5.3 2/1/2012 6:00 270.8 2/2/2012 23:00 54.4 2/7/2012 16:00 12

1/28/2012 21:00 53.8 1/30/2012 14:00 6.4 2/1/2012 7:00 330.6 2/3/2012 0:00 90.4 2/7/2012 17:00 298.5

1/28/2012 22:00 46.6 1/30/2012 15:00 2/1/2012 8:00 240.7 2/3/2012 1:00 59.5 2/7/2012 18:00 109.5

1/28/2012 23:00 53.5 1/30/2012 16:00 6.5 2/1/2012 9:00 167.2 2/3/2012 2:00 86.5 2/7/2012 19:00 54.1

1/29/2012 0:00 27.4 1/30/2012 17:00 11.6 2/1/2012 10:00 62 2/3/2012 3:00 164.9 2/7/2012 20:00 44.5

1/29/2012 1:00 83.6 1/30/2012 18:00 36.9 2/1/2012 11:00 30.1 2/3/2012 4:00 309.7 2/7/2012 21:00 108.6

1/29/2012 2:00 96.1 1/30/2012 19:00 42.1 2/1/2012 12:00 12.7 2/3/2012 5:00 321.7 2/7/2012 22:00 106.7

1/29/2012 3:00 91.4 1/30/2012 20:00 27.6 2/1/2012 13:00 9.4 2/3/2012 6:00 230 2/7/2012 23:00 70

1/29/2012 4:00 59.8 1/30/2012 21:00 71.5 2/1/2012 14:00 3.6 2/3/2012 7:00 224.1 2/8/2012 0:00 53.3

1/29/2012 5:00 37.6 1/30/2012 22:00 119.5 2/1/2012 15:00 3.4 2/3/2012 8:00 136.8 2/8/2012 1:00 41.7

1/29/2012 6:00 36.3 1/30/2012 23:00 67.3 2/1/2012 16:00 3.3 2/3/2012 9:00 132.1 2/8/2012 2:00 43.2

1/29/2012 7:00 71.3 1/31/2012 0:00 39.4 2/1/2012 17:00 3.8 2/3/2012 10:00 56.9 2/8/2012 3:00 44.6

1/29/2012 8:00 619.5 1/31/2012 1:00 94 2/1/2012 18:00 5.7 2/3/2012 11:00 24 2/8/2012 4:00 31.1

1/29/2012 9:00 383.6 1/31/2012 2:00 84.9 2/1/2012 19:00 12 2/3/2012 12:00 24.3 2/8/2012 5:00 47.4

1/29/2012 10:00 136.8 1/31/2012 3:00 43.2 2/1/2012 20:00 23.2 2/3/2012 13:00 11.8 2/8/2012 6:00 148.6

1/29/2012 11:00 20.3 1/31/2012 4:00 34.4 2/1/2012 21:00 60.3 2/3/2012 14:00 7.1 2/8/2012 7:00 173.4

1/29/2012 12:00 12.7 1/31/2012 5:00 25.3 2/1/2012 22:00 63.9 2/3/2012 15:00 4.5 2/8/2012 8:00 168.1

1/29/2012 13:00 9.5 1/31/2012 6:00 49.3 2/1/2012 23:00 51.4 2/3/2012 16:00 9.2 2/8/2012 9:00 107

1/29/2012 14:00 7.1 1/31/2012 7:00 99.5 2/2/2012 0:00 67.3 2/3/2012 17:00 5.5 2/8/2012 10:00 61.9

1/29/2012 15:00 9 1/31/2012 8:00 91.4 2/2/2012 1:00 174.3 2/3/2012 18:00 3.9 2/8/2012 11:00 41.1

1/29/2012 16:00 8 1/31/2012 9:00 32.7 2/2/2012 2:00 158.8 2/3/2012 19:00 3.4 2/8/2012 12:00 24.3

1/29/2012 17:00 17.9 1/31/2012 10:00 29.4 2/2/2012 3:00 123.3 2/3/2012 20:00 3.4 2/8/2012 13:00 15.4

1/29/2012 18:00 26.7 1/31/2012 11:00 7.3 2/2/2012 4:00 80.6 2/3/2012 21:00 4.3 2/8/2012 14:00 9.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 24
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/8/2012 15:00 6.2 2/10/2012 8:00 129.9 2/14/2012 1:00 43.6 2/15/2012 18:00 3.1 2/17/2012 11:00 107.8

2/8/2012 16:00 5.3 2/10/2012 9:00 232.8 2/14/2012 2:00 36.9 2/15/2012 19:00 3.1 2/17/2012 12:00 15.3

2/8/2012 17:00 4.7 2/10/2012 10:00 34.6 2/14/2012 3:00 34.1 2/15/2012 20:00 5.2 2/17/2012 13:00 8.6

2/8/2012 18:00 4.3 2/10/2012 11:00 18 2/14/2012 4:00 21.9 2/15/2012 21:00 19.2 2/17/2012 14:00 23.4

2/8/2012 19:00 4.2 2/10/2012 12:00 10.5 2/14/2012 5:00 20.2 2/15/2012 22:00 16.2 2/17/2012 15:00 19.2

2/8/2012 20:00 4 2/10/2012 13:00 4.5 2/14/2012 6:00 24.9 2/15/2012 23:00 14.4 2/17/2012 16:00 23

2/8/2012 21:00 3.8 2/10/2012 14:00 3.9 2/14/2012 7:00 228.5 2/16/2012 0:00 15.9 2/17/2012 17:00 9.9

2/8/2012 22:00 3.8 2/10/2012 15:00 3.6 2/14/2012 8:00 98.8 2/16/2012 1:00 16.2 2/17/2012 18:00 603.2

2/8/2012 23:00 3.7 2/10/2012 16:00 3.4 2/14/2012 9:00 20.6 2/16/2012 2:00 34.4 2/17/2012 19:00 96.4

2/9/2012 0:00 4.3 2/10/2012 17:00 3.2 2/14/2012 10:00 6.9 2/16/2012 3:00 67.5 2/17/2012 20:00 320.2

2/9/2012 1:00 4.1 2/10/2012 18:00 3.4 2/14/2012 11:00 3.8 2/16/2012 4:00 59.3 2/17/2012 21:00 166.2

2/9/2012 2:00 4.1 2/10/2012 19:00 4.7 2/14/2012 12:00 3.3 2/16/2012 5:00 57.6 2/17/2012 22:00 113.7

2/9/2012 3:00 7.5 2/10/2012 20:00 33.4 2/14/2012 13:00 3.4 2/16/2012 6:00 65.7 2/17/2012 23:00 92.1

2/9/2012 4:00 34.1 2/10/2012 21:00 80.7 2/14/2012 14:00 2/16/2012 7:00 111.8 2/18/2012 0:00 53.3

2/9/2012 5:00 36.2 2/10/2012 22:00 44.3 2/14/2012 15:00 4.8 2/16/2012 8:00 263.7 2/18/2012 1:00 74.8

2/9/2012 6:00 15.3 2/10/2012 23:00 35.2 2/14/2012 16:00 3.4 2/16/2012 9:00 89.7 2/18/2012 2:00 42.8

2/9/2012 7:00 23.8 2/12/2012 0:00 30 2/14/2012 17:00 3.3 2/16/2012 10:00 6.7 2/18/2012 3:00 10.5

2/9/2012 8:00 50.9 2/12/2012 1:00 26.5 2/14/2012 18:00 3.2 2/16/2012 11:00 8.5 2/18/2012 4:00 82.5

2/9/2012 9:00 290.6 2/12/2012 2:00 24 2/14/2012 19:00 3.2 2/16/2012 12:00 5.9 2/18/2012 5:00 45.6

2/9/2012 10:00 272.8 2/12/2012 3:00 12.4 2/14/2012 20:00 3.6 2/16/2012 13:00 3.6 2/18/2012 6:00 46.6

2/9/2012 11:00 34.9 2/12/2012 4:00 33.5 2/14/2012 21:00 10.7 2/16/2012 14:00 3.5 2/18/2012 7:00 85.2

2/9/2012 12:00 18.1 2/12/2012 5:00 75.6 2/14/2012 22:00 37.2 2/16/2012 15:00 3.7 2/18/2012 8:00 867.5

2/9/2012 13:00 17.1 2/12/2012 6:00 43.4 2/14/2012 23:00 39.8 2/16/2012 16:00 5.1 2/18/2012 9:00 252.4

2/9/2012 14:00 23.1 2/12/2012 7:00 17.3 2/15/2012 0:00 32.1 2/16/2012 17:00 4.9 2/18/2012 10:00 159.5

2/9/2012 15:00 19 2/12/2012 8:00 27.2 2/15/2012 1:00 72.3 2/16/2012 18:00 322.4 2/18/2012 11:00 53.6

2/9/2012 16:00 8.1 2/12/2012 9:00 16.7 2/15/2012 2:00 98.8 2/16/2012 19:00 170.5 2/18/2012 12:00 10.5

2/9/2012 17:00 5.4 2/12/2012 10:00 18.3 2/15/2012 3:00 148.9 2/16/2012 20:00 31.3 2/18/2012 13:00 12.8

2/9/2012 18:00 4.8 2/12/2012 11:00 7.1 2/15/2012 4:00 143.5 2/16/2012 21:00 33.4 2/18/2012 14:00 13.9

2/9/2012 19:00 11.5 2/12/2012 12:00 3.7 2/15/2012 5:00 150.8 2/16/2012 22:00 106.3 2/18/2012 15:00 14.5

2/9/2012 20:00 12.1 2/12/2012 13:00 3.3 2/15/2012 6:00 142.9 2/16/2012 23:00 296.7 2/18/2012 16:00 7.9

2/9/2012 21:00 57 2/12/2012 14:00 3.2 2/15/2012 7:00 210.2 2/17/2012 0:00 84 2/18/2012 17:00 12.6

2/9/2012 22:00 23.9 2/12/2012 15:00 3.2 2/15/2012 8:00 49.3 2/17/2012 1:00 157.3 2/18/2012 18:00 435.3

2/9/2012 23:00 19.2 2/12/2012 16:00 4.4 2/15/2012 9:00 20.6 2/17/2012 2:00 137.2 2/18/2012 19:00 374

2/10/2012 0:00 8.6 2/12/2012 17:00 6.7 2/15/2012 10:00 12.9 2/17/2012 3:00 166.3 2/18/2012 20:00 23.9

2/10/2012 1:00 20 2/12/2012 18:00 4.1 2/15/2012 11:00 6.9 2/17/2012 4:00 62.8 2/18/2012 21:00 52.1

2/10/2012 2:00 19.5 2/12/2012 19:00 10.5 2/15/2012 12:00 5.7 2/17/2012 5:00 190.4 2/18/2012 22:00 78.6

2/10/2012 3:00 11.4 2/12/2012 20:00 17.4 2/15/2012 13:00 4.2 2/17/2012 6:00 317 2/18/2012 23:00 18.7

2/10/2012 4:00 8.3 2/12/2012 21:00 15.7 2/15/2012 14:00 3.3 2/17/2012 7:00 203.3 2/19/2012 0:00 65.7

2/10/2012 5:00 7.8 2/12/2012 22:00 28.5 2/15/2012 15:00 3.1 2/17/2012 8:00 243.7 2/19/2012 1:00 26.2

2/10/2012 6:00 16.6 2/12/2012 23:00 5.1 2/15/2012 16:00 3.1 2/17/2012 9:00 29.9 2/19/2012 2:00 68.1

2/10/2012 7:00 35.9 2/14/2012 0:00 34.2 2/15/2012 17:00 3.2 2/17/2012 10:00 250 2/19/2012 3:00 79.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 25
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/19/2012 4:00 63.9 2/20/2012 21:00 32.4 2/22/2012 14:00 31.6 2/24/2012 7:00 131.1 2/27/2012 0:00 43.9

2/19/2012 5:00 17.3 2/20/2012 22:00 25.6 2/22/2012 15:00 5.5 2/24/2012 8:00 319.2 2/27/2012 1:00 52.9

2/19/2012 6:00 9.8 2/20/2012 23:00 16 2/22/2012 16:00 3.8 2/24/2012 9:00 138.4 2/27/2012 2:00 14

2/19/2012 7:00 58.3 2/21/2012 0:00 13.5 2/22/2012 17:00 3.7 2/24/2012 10:00 24.6 2/27/2012 3:00 13.6

2/19/2012 8:00 35.8 2/21/2012 1:00 7.9 2/22/2012 18:00 3.8 2/24/2012 11:00 6.4 2/27/2012 4:00 22.3

2/19/2012 9:00 85.5 2/21/2012 2:00 5 2/22/2012 19:00 9 2/24/2012 12:00 4.6 2/27/2012 5:00 20.4

2/19/2012 10:00 33.5 2/21/2012 3:00 60.6 2/22/2012 20:00 15.7 2/24/2012 13:00 3.9 2/27/2012 6:00 23.3

2/19/2012 11:00 19.3 2/21/2012 4:00 35 2/22/2012 21:00 26.3 2/24/2012 14:00 3.6 2/27/2012 7:00 22.4

2/19/2012 12:00 12.1 2/21/2012 5:00 11.3 2/22/2012 22:00 31.7 2/24/2012 15:00 3.4 2/27/2012 8:00 299

2/19/2012 13:00 6.9 2/21/2012 6:00 38.3 2/22/2012 23:00 108.2 2/24/2012 16:00 3.4 2/27/2012 9:00 29.8

2/19/2012 14:00 4.1 2/21/2012 7:00 113.8 2/23/2012 0:00 118.9 2/24/2012 17:00 3.3 2/27/2012 10:00 23.7

2/19/2012 15:00 3.4 2/21/2012 8:00 78.5 2/23/2012 1:00 90.6 2/24/2012 18:00 3.2 2/27/2012 11:00 18.4

2/19/2012 16:00 4.6 2/21/2012 9:00 36.3 2/23/2012 2:00 76.5 2/24/2012 19:00 3.1 2/27/2012 12:00 12.4

2/19/2012 17:00 4.8 2/21/2012 10:00 69.7 2/23/2012 3:00 58.2 2/24/2012 20:00 3 2/27/2012 13:00 4.4

2/19/2012 18:00 22.1 2/21/2012 11:00 36.5 2/23/2012 4:00 77.5 2/24/2012 21:00 4 2/27/2012 14:00 3.8

2/19/2012 19:00 9.7 2/21/2012 12:00 28.4 2/23/2012 5:00 97.9 2/24/2012 22:00 23.9 2/27/2012 15:00

2/19/2012 20:00 55.8 2/21/2012 13:00 6.5 2/23/2012 6:00 54.4 2/24/2012 23:00 31.4 2/27/2012 16:00 3.6

2/19/2012 21:00 52.4 2/21/2012 14:00 2/23/2012 7:00 104.2 2/26/2012 0:00 36.5 2/27/2012 17:00 3.6

2/19/2012 22:00 15.3 2/21/2012 15:00 16.1 2/23/2012 8:00 41 2/26/2012 1:00 44.4 2/27/2012 18:00 3.7

2/19/2012 23:00 410.6 2/21/2012 16:00 55.2 2/23/2012 9:00 36.8 2/26/2012 2:00 49.1 2/27/2012 19:00 5

2/20/2012 0:00 42.8 2/21/2012 17:00 20 2/23/2012 10:00 27.5 2/26/2012 3:00 39.8 2/27/2012 20:00 10.4

2/20/2012 1:00 6.2 2/21/2012 18:00 36.4 2/23/2012 11:00 15.6 2/26/2012 4:00 11.6 2/27/2012 21:00 31.7

2/20/2012 2:00 4.9 2/21/2012 19:00 188.9 2/23/2012 12:00 12.7 2/26/2012 5:00 4.6 2/27/2012 22:00 41.2

2/20/2012 3:00 17.1 2/21/2012 20:00 80.4 2/23/2012 13:00 4.4 2/26/2012 6:00 4.3 2/27/2012 23:00 21.4

2/20/2012 4:00 22.2 2/21/2012 21:00 48.6 2/23/2012 14:00 3.7 2/26/2012 7:00 10.7 2/28/2012 0:00 9.5

2/20/2012 5:00 44.1 2/21/2012 22:00 170.7 2/23/2012 15:00 3.9 2/26/2012 8:00 29.1 2/28/2012 1:00 12.9

2/20/2012 6:00 23.1 2/21/2012 23:00 69.6 2/23/2012 16:00 3.4 2/26/2012 9:00 12.5 2/28/2012 2:00 22.9

2/20/2012 7:00 6.8 2/22/2012 0:00 49.7 2/23/2012 17:00 3.3 2/26/2012 10:00 7.1 2/28/2012 3:00 20.6

2/20/2012 8:00 27.7 2/22/2012 1:00 177.6 2/23/2012 18:00 3.2 2/26/2012 11:00 7.3 2/28/2012 4:00 46

2/20/2012 9:00 128.2 2/22/2012 2:00 286.2 2/23/2012 19:00 3.3 2/26/2012 12:00 3.8 2/28/2012 5:00 25.2

2/20/2012 10:00 25.8 2/22/2012 3:00 69.3 2/23/2012 20:00 5.3 2/26/2012 13:00 3.4 2/28/2012 6:00 64.4

2/20/2012 11:00 15.8 2/22/2012 4:00 16.4 2/23/2012 21:00 21 2/26/2012 14:00 3.1 2/28/2012 7:00 186.9

2/20/2012 12:00 15.4 2/22/2012 5:00 7.4 2/23/2012 22:00 63.2 2/26/2012 15:00 3 2/28/2012 8:00 135.6

2/20/2012 13:00 13.3 2/22/2012 6:00 53.4 2/23/2012 23:00 89.7 2/26/2012 16:00 3 2/28/2012 9:00 50.9

2/20/2012 14:00 6.4 2/22/2012 7:00 52.8 2/24/2012 0:00 72.2 2/26/2012 17:00 3.9 2/28/2012 10:00 15.7

2/20/2012 15:00 2/22/2012 8:00 16.8 2/24/2012 1:00 166.7 2/26/2012 18:00 13.8 2/28/2012 11:00 9.6

2/20/2012 16:00 19.6 2/22/2012 9:00 60.2 2/24/2012 2:00 267.2 2/26/2012 19:00 88.4 2/28/2012 12:00 16.3

2/20/2012 17:00 5.4 2/22/2012 10:00 31 2/24/2012 3:00 458 2/26/2012 20:00 66.4 2/28/2012 13:00 9.5

2/20/2012 18:00 18.3 2/22/2012 11:00 14.4 2/24/2012 4:00 257.3 2/26/2012 21:00 176.8 2/28/2012 14:00

2/20/2012 19:00 31 2/22/2012 12:00 11.4 2/24/2012 5:00 201.8 2/26/2012 22:00 140.4 2/28/2012 15:00

2/20/2012 20:00 15.5 2/22/2012 13:00 9.5 2/24/2012 6:00 165.2 2/26/2012 23:00 96.2 2/28/2012 16:00 6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 26
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/28/2012 17:00 5.1 3/1/2012 10:00 21.8 3/3/2012 3:00 177.7 3/5/2012 20:00 3.2 3/8/2012 13:00 7.2

2/28/2012 18:00 4.1 3/1/2012 11:00 5.6 3/3/2012 4:00 154.1 3/5/2012 21:00 3.1 3/8/2012 14:00 6.9

2/28/2012 19:00 5.5 3/1/2012 12:00 4.2 3/3/2012 5:00 143.9 3/5/2012 22:00 3 3/8/2012 15:00 6.6

2/28/2012 20:00 4.8 3/1/2012 13:00 3.6 3/3/2012 6:00 110 3/5/2012 23:00 3 3/8/2012 16:00 6.3

2/28/2012 21:00 3.4 3/1/2012 14:00 3.4 3/3/2012 7:00 33.8 3/7/2012 0:00 3.1 3/8/2012 17:00 8.5

2/28/2012 22:00 3.2 3/1/2012 15:00 3.8 3/3/2012 8:00 24.9 3/7/2012 1:00 6.6 3/8/2012 18:00 16.8

2/28/2012 23:00 3 3/1/2012 16:00 3.4 3/3/2012 9:00 16.7 3/7/2012 2:00 12.5 3/8/2012 19:00 22.5

2/29/2012 0:00 3 3/1/2012 17:00 3.3 3/3/2012 10:00 13.7 3/7/2012 3:00 12.4 3/8/2012 20:00 52.7

2/29/2012 1:00 2.9 3/1/2012 18:00 3.2 3/3/2012 11:00 9 3/7/2012 4:00 13.8 3/8/2012 21:00 55.9

2/29/2012 2:00 2.9 3/1/2012 19:00 3.9 3/3/2012 12:00 5.9 3/7/2012 5:00 16.9 3/8/2012 22:00 29.6

2/29/2012 3:00 2.9 3/1/2012 20:00 8.6 3/3/2012 13:00 4.2 3/7/2012 6:00 36.8 3/8/2012 23:00 50.2

2/29/2012 4:00 3.4 3/1/2012 21:00 18.2 3/3/2012 14:00 3.6 3/7/2012 7:00 25.6 3/9/2012 0:00 65.9

2/29/2012 5:00 50.4 3/1/2012 22:00 72.7 3/3/2012 15:00 3.3 3/7/2012 8:00 58.4 3/9/2012 1:00 49.5

2/29/2012 6:00 24.7 3/1/2012 23:00 76.5 3/3/2012 16:00 3.2 3/7/2012 9:00 47 3/9/2012 2:00 124.8

2/29/2012 7:00 29 3/2/2012 0:00 183.6 3/3/2012 17:00 3.2 3/7/2012 10:00 22.9 3/9/2012 3:00 68.8

2/29/2012 8:00 18.7 3/2/2012 1:00 110.6 3/3/2012 18:00 3 3/7/2012 11:00 5.3 3/9/2012 4:00 30.7

2/29/2012 9:00 4.3 3/2/2012 2:00 123.9 3/3/2012 19:00 3 3/7/2012 12:00 4 3/9/2012 5:00 42.6

2/29/2012 10:00 3.6 3/2/2012 3:00 133.5 3/3/2012 20:00 3.5 3/7/2012 13:00 3.5 3/9/2012 6:00 64.6

2/29/2012 11:00 3.3 3/2/2012 4:00 92.2 3/3/2012 21:00 3.2 3/7/2012 14:00 3.2 3/9/2012 7:00 83.2

2/29/2012 12:00 3.1 3/2/2012 5:00 88.9 3/3/2012 22:00 3.4 3/7/2012 15:00 3.1 3/9/2012 8:00 39.3

2/29/2012 13:00 3 3/2/2012 6:00 78 3/3/2012 23:00 3.4 3/7/2012 16:00 3.1 3/9/2012 9:00 151.5

2/29/2012 14:00 3 3/2/2012 7:00 111.3 3/5/2012 0:00 55.7 3/7/2012 17:00 3 3/9/2012 10:00 134.9

2/29/2012 15:00 3.1 3/2/2012 8:00 36 3/5/2012 1:00 49.7 3/7/2012 18:00 3.1 3/9/2012 11:00 19.1

2/29/2012 16:00 5.2 3/2/2012 9:00 52 3/5/2012 2:00 70.7 3/7/2012 19:00 4.7 3/9/2012 12:00 12.7

2/29/2012 17:00 20.2 3/2/2012 10:00 42 3/5/2012 3:00 61.5 3/7/2012 20:00 8.9 3/9/2012 13:00 4.4

2/29/2012 18:00 16.1 3/2/2012 11:00 35.2 3/5/2012 4:00 83.7 3/7/2012 21:00 137.8 3/9/2012 14:00 4.1

2/29/2012 19:00 17.6 3/2/2012 12:00 21.5 3/5/2012 5:00 107.6 3/7/2012 22:00 70.1 3/9/2012 15:00 4.2

2/29/2012 20:00 33 3/2/2012 13:00 5.2 3/5/2012 6:00 137.7 3/7/2012 23:00 146.9 3/9/2012 16:00 3.8

2/29/2012 21:00 14.3 3/2/2012 14:00 4 3/5/2012 7:00 281.8 3/8/2012 0:00 157.1 3/9/2012 17:00 3.5

2/29/2012 22:00 162.3 3/2/2012 15:00 3.7 3/5/2012 8:00 114.8 3/8/2012 1:00 79.3 3/9/2012 18:00 3.9

2/29/2012 23:00 158.8 3/2/2012 16:00 3.4 3/5/2012 9:00 33.5 3/8/2012 2:00 94.1 3/9/2012 19:00 7.7

3/1/2012 0:00 255.9 3/2/2012 17:00 3.4 3/5/2012 10:00 12.2 3/8/2012 3:00 41.7 3/9/2012 20:00 27

3/1/2012 1:00 171.1 3/2/2012 18:00 3.3 3/5/2012 11:00 4.9 3/8/2012 4:00 44.9 3/9/2012 21:00 44.5

3/1/2012 2:00 43.4 3/2/2012 19:00 3.2 3/5/2012 12:00 3.8 3/8/2012 5:00 65.9 3/9/2012 22:00 99.2

3/1/2012 3:00 59.2 3/2/2012 20:00 3.2 3/5/2012 13:00 3.5 3/8/2012 6:00 258.6 3/9/2012 23:00 55.3

3/1/2012 4:00 152.1 3/2/2012 21:00 3.5 3/5/2012 14:00 3.4 3/8/2012 7:00 171.7 3/10/2012 0:00 90.9

3/1/2012 5:00 50.7 3/2/2012 22:00 7.6 3/5/2012 15:00 3/8/2012 8:00 63.8 3/10/2012 1:00 105

3/1/2012 6:00 48.1 3/2/2012 23:00 18.4 3/5/2012 16:00 3.3 3/8/2012 9:00 36.8 3/10/2012 2:00 55

3/1/2012 7:00 38 3/3/2012 0:00 27.4 3/5/2012 17:00 3.2 3/8/2012 10:00 12.4 3/10/2012 3:00 98.7

3/1/2012 8:00 60.3 3/3/2012 1:00 23.2 3/5/2012 18:00 3.2 3/8/2012 11:00 5.2 3/10/2012 4:00 100.5

3/1/2012 9:00 38.1 3/3/2012 2:00 119.8 3/5/2012 19:00 3.3 3/8/2012 12:00 5.2 3/10/2012 5:00 83.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 27
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

3/10/2012 6:00 185.8 3/11/2012 23:00 155.8 3/13/2012 16:00 5.4 3/15/2012 9:00 8.5 3/17/2012 2:00 160

3/10/2012 7:00 82.1 3/12/2012 0:00 224.2 3/13/2012 17:00 6.1 3/15/2012 10:00 6.2 3/17/2012 3:00 58.1

3/10/2012 8:00 221.8 3/12/2012 1:00 331.9 3/13/2012 18:00 11 3/15/2012 11:00 24.1 3/17/2012 4:00 97

3/10/2012 9:00 46.8 3/12/2012 2:00 314 3/13/2012 19:00 24.3 3/15/2012 12:00 12.9 3/17/2012 5:00 110.6

3/10/2012 10:00 19.1 3/12/2012 3:00 231.2 3/13/2012 20:00 53.5 3/15/2012 13:00 4.8 3/17/2012 6:00 170.2

3/10/2012 11:00 7 3/12/2012 4:00 214.7 3/13/2012 21:00 79.6 3/15/2012 14:00 4 3/17/2012 7:00 96.1

3/10/2012 12:00 4.5 3/12/2012 5:00 213.6 3/13/2012 22:00 66.1 3/15/2012 15:00 4.1 3/17/2012 8:00 140.5

3/10/2012 13:00 4.3 3/12/2012 6:00 166.7 3/13/2012 23:00 73.4 3/15/2012 16:00 5.6 3/17/2012 9:00 13.7

3/10/2012 14:00 4 3/12/2012 7:00 189.7 3/14/2012 0:00 73.8 3/15/2012 17:00 17.5 3/17/2012 10:00 19

3/10/2012 15:00 4.2 3/12/2012 8:00 139.3 3/14/2012 1:00 87.6 3/15/2012 18:00 33.6 3/17/2012 11:00 7.3

3/10/2012 16:00 27.7 3/12/2012 9:00 76.7 3/14/2012 2:00 119.1 3/15/2012 19:00 219.1 3/17/2012 12:00 5.3

3/10/2012 17:00 118.9 3/12/2012 10:00 33 3/14/2012 3:00 150.5 3/15/2012 20:00 97.6 3/17/2012 13:00 4.2

3/10/2012 18:00 250.7 3/12/2012 11:00 19.3 3/14/2012 4:00 110.4 3/15/2012 21:00 72.3 3/17/2012 14:00 3.6

3/10/2012 19:00 100.5 3/12/2012 12:00 13.7 3/14/2012 5:00 89.6 3/15/2012 22:00 66.6 3/17/2012 15:00 3.4

3/10/2012 20:00 56 3/12/2012 13:00 14.4 3/14/2012 6:00 73.6 3/15/2012 23:00 255.2 3/17/2012 16:00 3.5

3/10/2012 21:00 98 3/12/2012 14:00 12 3/14/2012 7:00 77.3 3/16/2012 0:00 200.3 3/17/2012 17:00 4.7

3/10/2012 22:00 47.7 3/12/2012 15:00 3/14/2012 8:00 125.6 3/16/2012 1:00 106.2 3/17/2012 18:00 7.8

3/10/2012 23:00 52.4 3/12/2012 16:00 61.8 3/14/2012 9:00 59.2 3/16/2012 2:00 44.1 3/17/2012 19:00 4.1

3/11/2012 0:00 78 3/12/2012 17:00 26.3 3/14/2012 10:00 20 3/16/2012 3:00 85.8 3/17/2012 20:00 52.1

3/11/2012 1:00 89.4 3/12/2012 18:00 47.6 3/14/2012 11:00 9 3/16/2012 4:00 27.3 3/17/2012 21:00 66

3/11/2012 2:00 153.8 3/12/2012 19:00 84.3 3/14/2012 12:00 7.9 3/16/2012 5:00 15.9 3/17/2012 22:00 63.8

3/11/2012 3:00 190.3 3/12/2012 20:00 76.5 3/14/2012 13:00 4.2 3/16/2012 6:00 97.8 3/17/2012 23:00 70.9

3/11/2012 4:00 159.2 3/12/2012 21:00 44.4 3/14/2012 14:00 3.5 3/16/2012 7:00 116.6 3/18/2012 0:00 185.8

3/11/2012 5:00 147.8 3/12/2012 22:00 85.6 3/14/2012 15:00 3.5 3/16/2012 8:00 61.9 3/18/2012 1:00 83

3/11/2012 6:00 110.4 3/12/2012 23:00 43.1 3/14/2012 16:00 3.6 3/16/2012 9:00 18.1 3/18/2012 2:00 138.5

3/11/2012 7:00 123.3 3/13/2012 0:00 34.3 3/14/2012 17:00 5.3 3/16/2012 10:00 22 3/18/2012 3:00 414

3/11/2012 8:00 115.6 3/13/2012 1:00 28.3 3/14/2012 18:00 16.5 3/16/2012 11:00 7.5 3/18/2012 4:00 133.4

3/11/2012 9:00 151.5 3/13/2012 2:00 28.2 3/14/2012 19:00 9.5 3/16/2012 12:00 4.8 3/18/2012 5:00 42.7

3/11/2012 10:00 63.6 3/13/2012 3:00 23 3/14/2012 20:00 5.8 3/16/2012 13:00 4.8 3/18/2012 6:00 30.6

3/11/2012 11:00 47.4 3/13/2012 4:00 21.7 3/14/2012 21:00 31.3 3/16/2012 14:00 3.6 3/18/2012 7:00 51.5

3/11/2012 12:00 12.1 3/13/2012 5:00 19.5 3/14/2012 22:00 27.5 3/16/2012 15:00 3.6 3/18/2012 8:00 44.8

3/11/2012 13:00 7.4 3/13/2012 6:00 15.9 3/14/2012 23:00 33.5 3/16/2012 16:00 4 3/18/2012 9:00 33.2

3/11/2012 14:00 10.9 3/13/2012 7:00 25.2 3/15/2012 0:00 91.9 3/16/2012 17:00 5.5 3/18/2012 10:00 15.6

3/11/2012 15:00 7.6 3/13/2012 8:00 57.5 3/15/2012 1:00 90.1 3/16/2012 18:00 14.8 3/18/2012 11:00 10.1

3/11/2012 16:00 12.7 3/13/2012 9:00 76.4 3/15/2012 2:00 69 3/16/2012 19:00 16.5 3/18/2012 12:00 4.7

3/11/2012 17:00 19.8 3/13/2012 10:00 40.1 3/15/2012 3:00 47 3/16/2012 20:00 30.5 3/18/2012 13:00 3.9

3/11/2012 18:00 32.6 3/13/2012 11:00 18.4 3/15/2012 4:00 52 3/16/2012 21:00 78.4 3/18/2012 14:00 3.6

3/11/2012 19:00 39.7 3/13/2012 12:00 10.1 3/15/2012 5:00 61.8 3/16/2012 22:00 223.8 3/18/2012 15:00 3.4

3/11/2012 20:00 46.8 3/13/2012 13:00 7.3 3/15/2012 6:00 153.8 3/16/2012 23:00 228.9 3/18/2012 16:00 3.4

3/11/2012 21:00 76.3 3/13/2012 14:00 3/15/2012 7:00 50.9 3/17/2012 0:00 125.8 3/18/2012 17:00 3.3

3/11/2012 22:00 92.8 3/13/2012 15:00 6.3 3/15/2012 8:00 80.8 3/17/2012 1:00 110.1 3/18/2012 18:00 3.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 28
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

3/18/2012 19:00 3.9 3/20/2012 12:00 4.5 3/22/2012 5:00 356 3/23/2012 22:00 153.5 3/25/2012 15:00 14.3

3/18/2012 20:00 9.1 3/20/2012 13:00 4.1 3/22/2012 6:00 370 3/23/2012 23:00 50 3/25/2012 16:00 15.4

3/18/2012 21:00 5.6 3/20/2012 14:00 3/22/2012 7:00 242.5 3/24/2012 0:00 51 3/25/2012 17:00 21.9

3/18/2012 22:00 5.5 3/20/2012 15:00 5.1 3/22/2012 8:00 332.9 3/24/2012 1:00 365.2 3/25/2012 18:00 38.5

3/18/2012 23:00 37.6 3/20/2012 16:00 3.9 3/22/2012 9:00 17.3 3/24/2012 2:00 170.8 3/25/2012 19:00 14.4

3/19/2012 0:00 58.5 3/20/2012 17:00 3.6 3/22/2012 10:00 17.7 3/24/2012 3:00 53.4 3/25/2012 20:00 12.1

3/19/2012 1:00 91.6 3/20/2012 18:00 3.6 3/22/2012 11:00 12.3 3/24/2012 4:00 18.6 3/25/2012 21:00 24.3

3/19/2012 2:00 83.2 3/20/2012 19:00 3.4 3/22/2012 12:00 6.6 3/24/2012 5:00 35.6 3/25/2012 22:00 68.8

3/19/2012 3:00 98.8 3/20/2012 20:00 3.9 3/22/2012 13:00 6.9 3/24/2012 6:00 84.6 3/25/2012 23:00 138.4

3/19/2012 4:00 99.8 3/20/2012 21:00 7.5 3/22/2012 14:00 6.6 3/24/2012 7:00 165.2 3/26/2012 0:00 132.7

3/19/2012 5:00 146 3/20/2012 22:00 15.7 3/22/2012 15:00 8.2 3/24/2012 8:00 194.6 3/26/2012 1:00 106

3/19/2012 6:00 344.4 3/20/2012 23:00 13.2 3/22/2012 16:00 4.5 3/24/2012 9:00 210.8 3/26/2012 2:00 104.6

3/19/2012 7:00 192.1 3/21/2012 0:00 58.9 3/22/2012 17:00 264.9 3/24/2012 10:00 37.1 3/26/2012 3:00 93.9

3/19/2012 8:00 108 3/21/2012 1:00 105.8 3/22/2012 18:00 189.6 3/24/2012 11:00 11.6 3/26/2012 4:00 89.8

3/19/2012 9:00 100.8 3/21/2012 2:00 61.8 3/22/2012 19:00 140.9 3/24/2012 12:00 9.2 3/26/2012 5:00 82

3/19/2012 10:00 11.1 3/21/2012 3:00 36.7 3/22/2012 20:00 151.2 3/24/2012 13:00 12.6 3/26/2012 6:00 122.8

3/19/2012 11:00 5.9 3/21/2012 4:00 21.1 3/22/2012 21:00 71.5 3/24/2012 14:00 5.9 3/26/2012 7:00 100.4

3/19/2012 12:00 4.6 3/21/2012 5:00 9.8 3/22/2012 22:00 9.4 3/24/2012 15:00 6.5 3/26/2012 8:00 73.2

3/19/2012 13:00 4 3/21/2012 6:00 11.9 3/22/2012 23:00 6.3 3/24/2012 16:00 6.4 3/26/2012 9:00 80.1

3/19/2012 14:00 3.6 3/21/2012 7:00 6.8 3/23/2012 0:00 5 3/24/2012 17:00 5.2 3/26/2012 10:00 13.7

3/19/2012 15:00 3/21/2012 8:00 12.5 3/23/2012 1:00 8.2 3/24/2012 18:00 25.7 3/26/2012 11:00 13.5

3/19/2012 16:00 3.4 3/21/2012 9:00 14.3 3/23/2012 2:00 20.5 3/24/2012 19:00 39.1 3/26/2012 12:00

3/19/2012 17:00 3.6 3/21/2012 10:00 12 3/23/2012 3:00 42.6 3/24/2012 20:00 8.9 3/26/2012 13:00 5.2

3/19/2012 18:00 3.6 3/21/2012 11:00 8.5 3/23/2012 4:00 36.2 3/24/2012 21:00 7.8 3/26/2012 14:00 4.1

3/19/2012 19:00 3.5 3/21/2012 12:00 7.4 3/23/2012 5:00 32.9 3/24/2012 22:00 6.6 3/26/2012 15:00

3/19/2012 20:00 3.4 3/21/2012 13:00 6.3 3/23/2012 6:00 55.2 3/24/2012 23:00 24.6 3/26/2012 16:00 7.1

3/19/2012 21:00 4.8 3/21/2012 14:00 5.9 3/23/2012 7:00 121.4 3/25/2012 0:00 13.3 3/26/2012 17:00 5

3/19/2012 22:00 23 3/21/2012 15:00 6.6 3/23/2012 8:00 333.3 3/25/2012 1:00 5 3/26/2012 18:00 8.1

3/19/2012 23:00 34 3/21/2012 16:00 162.1 3/23/2012 9:00 45.1 3/25/2012 2:00 4.3 3/26/2012 19:00 8.2

3/20/2012 0:00 28.1 3/21/2012 17:00 650.3 3/23/2012 10:00 18.1 3/25/2012 3:00 8.3 3/26/2012 20:00 17.8

3/20/2012 1:00 42.1 3/21/2012 18:00 276.9 3/23/2012 11:00 16.2 3/25/2012 4:00 15 3/26/2012 21:00 86.5

3/20/2012 2:00 44.6 3/21/2012 19:00 82.9 3/23/2012 12:00 16 3/25/2012 5:00 72.2 3/26/2012 22:00 153.5

3/20/2012 3:00 144.4 3/21/2012 20:00 56.7 3/23/2012 13:00 8.8 3/25/2012 6:00 30.9 3/26/2012 23:00 164

3/20/2012 4:00 98.5 3/21/2012 21:00 34.8 3/23/2012 14:00 8.3 3/25/2012 7:00 13.8 3/27/2012 0:00 146.7

3/20/2012 5:00 140.9 3/21/2012 22:00 143.1 3/23/2012 15:00 4.6 3/25/2012 8:00 9.7 3/27/2012 1:00 96.2

3/20/2012 6:00 329 3/21/2012 23:00 412.9 3/23/2012 16:00 7.9 3/25/2012 9:00 8.5 3/27/2012 2:00 38.4

3/20/2012 7:00 427.2 3/22/2012 0:00 549.3 3/23/2012 17:00 9.8 3/25/2012 10:00 9.2 3/27/2012 3:00 63.7

3/20/2012 8:00 668.3 3/22/2012 1:00 118.7 3/23/2012 18:00 87.7 3/25/2012 11:00 4.8 3/27/2012 4:00 47.8

3/20/2012 9:00 46.1 3/22/2012 2:00 163.1 3/23/2012 19:00 316.7 3/25/2012 12:00 4.7 3/27/2012 5:00 74.7

3/20/2012 10:00 7.1 3/22/2012 3:00 122.7 3/23/2012 20:00 215.2 3/25/2012 13:00 5 3/27/2012 6:00 44.6

3/20/2012 11:00 5.4 3/22/2012 4:00 85.2 3/23/2012 21:00 381.9 3/25/2012 14:00 4.8 3/27/2012 7:00 36.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 29
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

3/27/2012 8:00 160.3 3/29/2012 1:00 105.6 3/30/2012 18:00 54.9 4/2/2012 11:00 87 4/4/2012 4:00 113.6

3/27/2012 9:00 104.3 3/29/2012 2:00 181.6 3/30/2012 19:00 45.9 4/2/2012 12:00 52.8 4/4/2012 5:00 82.2

3/27/2012 10:00 34.9 3/29/2012 3:00 280.7 3/30/2012 20:00 47.3 4/2/2012 13:00 6.1 4/4/2012 6:00 49.7

3/27/2012 11:00 17.1 3/29/2012 4:00 361.5 3/30/2012 21:00 111.4 4/2/2012 14:00 4.3 4/4/2012 7:00 47.2

3/27/2012 12:00 18.9 3/29/2012 5:00 496.3 3/30/2012 22:00 95.3 4/2/2012 15:00 4/4/2012 8:00 90.7

3/27/2012 13:00 12.9 3/29/2012 6:00 274.5 3/30/2012 23:00 82.5 4/2/2012 16:00 3.8 4/4/2012 9:00 22.9

3/27/2012 14:00 3/29/2012 7:00 402 3/31/2012 0:00 73.4 4/2/2012 17:00 3.6 4/4/2012 10:00 30.8

3/27/2012 15:00 13.9 3/29/2012 8:00 367.2 3/31/2012 1:00 75.2 4/2/2012 18:00 3.6 4/4/2012 11:00 9.4

3/27/2012 16:00 33.2 3/29/2012 9:00 301.5 3/31/2012 2:00 54.4 4/2/2012 19:00 3.5 4/4/2012 12:00 4.8

3/27/2012 17:00 3/29/2012 10:00 27.9 3/31/2012 3:00 36.2 4/2/2012 20:00 3.6 4/4/2012 13:00 4

3/27/2012 18:00 35.8 3/29/2012 11:00 10.8 3/31/2012 4:00 41.1 4/2/2012 21:00 5.1 4/4/2012 14:00 3.7

3/27/2012 19:00 35.5 3/29/2012 12:00 4.8 3/31/2012 5:00 148.4 4/2/2012 22:00 9.2 4/4/2012 15:00 3.6

3/27/2012 20:00 38.1 3/29/2012 13:00 3.9 3/31/2012 6:00 253.6 4/2/2012 23:00 28.3 4/4/2012 16:00 3.4

3/27/2012 21:00 45.9 3/29/2012 14:00 4 3/31/2012 7:00 302.2 4/3/2012 0:00 57.6 4/4/2012 17:00 3.3

3/27/2012 22:00 95.9 3/29/2012 15:00 4.1 3/31/2012 8:00 34.8 4/3/2012 1:00 114.5 4/4/2012 18:00 3.2

3/27/2012 23:00 108.8 3/29/2012 16:00 4.1 3/31/2012 9:00 4.6 4/3/2012 2:00 77.5 4/4/2012 19:00 3.3

3/28/2012 0:00 81.6 3/29/2012 17:00 5.2 3/31/2012 10:00 5 4/3/2012 3:00 54.9 4/4/2012 20:00 3.9

3/28/2012 1:00 78.3 3/29/2012 18:00 9.5 3/31/2012 11:00 15.1 4/3/2012 4:00 130.3 4/4/2012 21:00 11.7

3/28/2012 2:00 70.2 3/29/2012 19:00 14.9 3/31/2012 12:00 15.9 4/3/2012 5:00 317.4 4/4/2012 22:00 47.4

3/28/2012 3:00 51.9 3/29/2012 20:00 12.9 3/31/2012 13:00 16.6 4/3/2012 6:00 179.7 4/4/2012 23:00 37.5

3/28/2012 4:00 76.5 3/29/2012 21:00 7.8 3/31/2012 14:00 14.3 4/3/2012 7:00 130.9 4/6/2012 0:00 15.4

3/28/2012 5:00 312.2 3/29/2012 22:00 174.9 3/31/2012 15:00 12 4/3/2012 8:00 124.6 4/6/2012 1:00 46.6

3/28/2012 6:00 338 3/29/2012 23:00 776.9 3/31/2012 16:00 6.4 4/3/2012 9:00 40.5 4/6/2012 2:00 84.6

3/28/2012 7:00 310.2 3/30/2012 0:00 347.6 3/31/2012 17:00 6 4/3/2012 10:00 14.5 4/6/2012 3:00 66

3/28/2012 8:00 210 3/30/2012 1:00 269.5 3/31/2012 18:00 6.5 4/3/2012 11:00 5.4 4/6/2012 4:00 71.5

3/28/2012 9:00 255.1 3/30/2012 2:00 257.2 3/31/2012 19:00 6.8 4/3/2012 12:00 4.2 4/6/2012 5:00 44.5

3/28/2012 10:00 50.1 3/30/2012 3:00 188.2 3/31/2012 20:00 5.3 4/3/2012 13:00 3.9 4/6/2012 6:00 74.5

3/28/2012 11:00 12.5 3/30/2012 4:00 183.7 3/31/2012 21:00 4.4 4/3/2012 14:00 4/6/2012 7:00 91.2

3/28/2012 12:00 5.7 3/30/2012 5:00 236.4 3/31/2012 22:00 4.4 4/3/2012 15:00 5.3 4/6/2012 8:00 138.5

3/28/2012 13:00 4.4 3/30/2012 6:00 249.5 3/31/2012 23:00 4.3 4/3/2012 16:00 3.9 4/6/2012 9:00 24.3

3/28/2012 14:00 4 3/30/2012 7:00 237.9 4/2/2012 0:00 3.3 4/3/2012 17:00 3.6 4/6/2012 10:00 22.4

3/28/2012 15:00 3.8 3/30/2012 8:00 539 4/2/2012 1:00 3.4 4/3/2012 18:00 3.5 4/6/2012 11:00 10.9

3/28/2012 16:00 4.2 3/30/2012 9:00 128.9 4/2/2012 2:00 3.6 4/3/2012 19:00 3.8 4/6/2012 12:00 4.1

3/28/2012 17:00 4.9 3/30/2012 10:00 26 4/2/2012 3:00 4.1 4/3/2012 20:00 4.9 4/6/2012 13:00 3.8

3/28/2012 18:00 14.1 3/30/2012 11:00 9.9 4/2/2012 4:00 3.8 4/3/2012 21:00 8.2 4/6/2012 14:00 3.7

3/28/2012 19:00 19.8 3/30/2012 12:00 11.4 4/2/2012 5:00 3.7 4/3/2012 22:00 27.4 4/6/2012 15:00 3.8

3/28/2012 20:00 13.3 3/30/2012 13:00 14.9 4/2/2012 6:00 4.2 4/3/2012 23:00 198.2 4/6/2012 16:00 3.5

3/28/2012 21:00 27 3/30/2012 14:00 27.2 4/2/2012 7:00 12.5 4/4/2012 0:00 130.1 4/6/2012 17:00 4.2

3/28/2012 22:00 49 3/30/2012 15:00 205.4 4/2/2012 8:00 152.9 4/4/2012 1:00 148.2 4/6/2012 18:00 33.3

3/28/2012 23:00 63.3 3/30/2012 16:00 70.9 4/2/2012 9:00 76.4 4/4/2012 2:00 130.3 4/6/2012 19:00 81.8

3/29/2012 0:00 72.3 3/30/2012 17:00 18 4/2/2012 10:00 78.8 4/4/2012 3:00 145.5 4/6/2012 20:00 273.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 30
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/6/2012 21:00 175.2 4/8/2012 14:00 6.5 4/10/2012 7:00 149.2 4/12/2012 0:00 40 4/13/2012 17:00 3.2

4/6/2012 22:00 31.7 4/8/2012 15:00 7.8 4/10/2012 8:00 70.1 4/12/2012 1:00 25 4/13/2012 18:00 3.3

4/6/2012 23:00 24.3 4/8/2012 16:00 8.9 4/10/2012 9:00 39.6 4/12/2012 2:00 25.6 4/13/2012 19:00 3.1

4/7/2012 0:00 115.1 4/8/2012 17:00 10.2 4/10/2012 10:00 24.3 4/12/2012 3:00 49.1 4/13/2012 20:00 3.2

4/7/2012 1:00 138.1 4/8/2012 18:00 16.1 4/10/2012 11:00 12.1 4/12/2012 4:00 102.1 4/13/2012 21:00 3.1

4/7/2012 2:00 74 4/8/2012 19:00 16 4/10/2012 12:00 7.1 4/12/2012 5:00 168.2 4/13/2012 22:00 3.1

4/7/2012 3:00 40.7 4/8/2012 20:00 16.3 4/10/2012 13:00 4.6 4/12/2012 6:00 244 4/13/2012 23:00 3.2

4/7/2012 4:00 33.8 4/8/2012 21:00 28.7 4/10/2012 14:00 4/12/2012 7:00 197.5 4/14/2012 0:00 3.1

4/7/2012 5:00 53.8 4/8/2012 22:00 66.7 4/10/2012 15:00 5.3 4/12/2012 8:00 82.8 4/14/2012 1:00 3.1

4/7/2012 6:00 99.5 4/8/2012 23:00 58.6 4/10/2012 16:00 4.2 4/12/2012 9:00 60.6 4/14/2012 2:00 3

4/7/2012 7:00 94.7 4/9/2012 0:00 30.6 4/10/2012 17:00 13.1 4/12/2012 10:00 9.7 4/14/2012 3:00 3.1

4/7/2012 8:00 65.5 4/9/2012 1:00 31.8 4/10/2012 18:00 37.8 4/12/2012 11:00 4.8 4/14/2012 4:00 3

4/7/2012 9:00 20.5 4/9/2012 2:00 36.9 4/10/2012 19:00 74.6 4/12/2012 12:00 3.8 4/14/2012 5:00 3.8

4/7/2012 10:00 29.6 4/9/2012 3:00 40.3 4/10/2012 20:00 246.8 4/12/2012 13:00 3.4 4/14/2012 6:00 15.5

4/7/2012 11:00 12.4 4/9/2012 4:00 37.8 4/10/2012 21:00 107.1 4/12/2012 14:00 3.3 4/14/2012 7:00 40.8

4/7/2012 12:00 27.3 4/9/2012 5:00 107.5 4/10/2012 22:00 108 4/12/2012 15:00 3.7 4/14/2012 8:00 95.2

4/7/2012 13:00 14.6 4/9/2012 6:00 125.4 4/10/2012 23:00 79.9 4/12/2012 16:00 3.5 4/14/2012 9:00 40.9

4/7/2012 14:00 10.7 4/9/2012 7:00 157.5 4/11/2012 0:00 109.7 4/12/2012 17:00 3.5 4/14/2012 10:00 16.1

4/7/2012 15:00 11.8 4/9/2012 8:00 150.8 4/11/2012 1:00 88.8 4/12/2012 18:00 3.5 4/14/2012 11:00 7.2

4/7/2012 16:00 25.1 4/9/2012 9:00 81.4 4/11/2012 2:00 52.7 4/12/2012 19:00 3.4 4/14/2012 12:00 4.4

4/7/2012 17:00 45.8 4/9/2012 10:00 29.4 4/11/2012 3:00 109 4/12/2012 20:00 3.4 4/14/2012 13:00 3.9

4/7/2012 18:00 76 4/9/2012 11:00 17.2 4/11/2012 4:00 166.6 4/12/2012 21:00 3.5 4/14/2012 14:00 3.6

4/7/2012 19:00 64.8 4/9/2012 12:00 15.6 4/11/2012 5:00 31 4/12/2012 22:00 3.3 4/14/2012 15:00 3.3

4/7/2012 20:00 71.5 4/9/2012 13:00 15.8 4/11/2012 6:00 11 4/12/2012 23:00 3.5 4/14/2012 16:00 3.2

4/7/2012 21:00 82.7 4/9/2012 14:00 16.7 4/11/2012 7:00 15.2 4/13/2012 0:00 9.7 4/14/2012 17:00 3.1

4/7/2012 22:00 60.2 4/9/2012 15:00 4/11/2012 8:00 28.4 4/13/2012 1:00 20.2 4/14/2012 18:00 3.1

4/7/2012 23:00 42.2 4/9/2012 16:00 26.8 4/11/2012 9:00 39.4 4/13/2012 2:00 54.5 4/14/2012 19:00 3.2

4/8/2012 0:00 64.2 4/9/2012 17:00 32.6 4/11/2012 10:00 23.6 4/13/2012 3:00 78.3 4/14/2012 20:00 17.8

4/8/2012 1:00 68.8 4/9/2012 18:00 28.3 4/11/2012 11:00 6.4 4/13/2012 4:00 69.3 4/14/2012 21:00 43.7

4/8/2012 2:00 81.4 4/9/2012 19:00 51.6 4/11/2012 12:00 4.1 4/13/2012 5:00 48.4 4/14/2012 22:00 26.8

4/8/2012 3:00 92.7 4/9/2012 20:00 32.7 4/11/2012 13:00 3.8 4/13/2012 6:00 80.5 4/14/2012 23:00 16.9

4/8/2012 4:00 123.9 4/9/2012 21:00 33.7 4/11/2012 14:00 3.4 4/13/2012 7:00 89.1 4/16/2012 0:00 75.4

4/8/2012 5:00 130.8 4/9/2012 22:00 50.1 4/11/2012 15:00 3.4 4/13/2012 8:00 11.7 4/16/2012 1:00 110.1

4/8/2012 6:00 103.7 4/9/2012 23:00 40.3 4/11/2012 16:00 3.5 4/13/2012 9:00 9.9 4/16/2012 2:00 95.8

4/8/2012 7:00 103 4/10/2012 0:00 129.9 4/11/2012 17:00 3.4 4/13/2012 10:00 4.9 4/16/2012 3:00 43.9

4/8/2012 8:00 92.8 4/10/2012 1:00 261.2 4/11/2012 18:00 3.8 4/13/2012 11:00 4.1 4/16/2012 4:00 24

4/8/2012 9:00 115.6 4/10/2012 2:00 192.6 4/11/2012 19:00 4.7 4/13/2012 12:00 3.7 4/16/2012 5:00 20.5

4/8/2012 10:00 20.6 4/10/2012 3:00 132.4 4/11/2012 20:00 45.8 4/13/2012 13:00 3.6 4/16/2012 6:00 27.9

4/8/2012 11:00 8.9 4/10/2012 4:00 80.6 4/11/2012 21:00 85.8 4/13/2012 14:00 3.7 4/16/2012 7:00 49.1

4/8/2012 12:00 7.3 4/10/2012 5:00 53.2 4/11/2012 22:00 37.9 4/13/2012 15:00 3.5 4/16/2012 8:00 29.4

4/8/2012 13:00 5.1 4/10/2012 6:00 74.2 4/11/2012 23:00 36.2 4/13/2012 16:00 3.3 4/16/2012 9:00 8.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 31
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/16/2012 10:00 5.1 4/18/2012 3:00 176.9 4/19/2012 20:00 26.3 4/21/2012 13:00 9 4/23/2012 6:00 65.9

4/16/2012 11:00 5.5 4/18/2012 4:00 162.9 4/19/2012 21:00 21.9 4/21/2012 14:00 11 4/23/2012 7:00 43.9

4/16/2012 12:00 8.2 4/18/2012 5:00 152.5 4/19/2012 22:00 14.8 4/21/2012 15:00 30 4/23/2012 8:00 38.2

4/16/2012 13:00 5.7 4/18/2012 6:00 125.8 4/19/2012 23:00 21 4/21/2012 16:00 30.9 4/23/2012 9:00 21.5

4/16/2012 14:00 4.3 4/18/2012 7:00 175.5 4/20/2012 0:00 27.7 4/21/2012 17:00 50.6 4/23/2012 10:00 26.1

4/16/2012 15:00 4/18/2012 8:00 77.2 4/20/2012 1:00 28.5 4/21/2012 18:00 317.5 4/23/2012 11:00 16.6

4/16/2012 16:00 6 4/18/2012 9:00 13.6 4/20/2012 2:00 23.3 4/21/2012 19:00 67.3 4/23/2012 12:00 17.6

4/16/2012 17:00 10.1 4/18/2012 10:00 20.8 4/20/2012 3:00 15.1 4/21/2012 20:00 88.2 4/23/2012 13:00 24.2

4/16/2012 18:00 11.3 4/18/2012 11:00 11.6 4/20/2012 4:00 16.1 4/21/2012 21:00 108.5 4/23/2012 14:00 15.6

4/16/2012 19:00 11.8 4/18/2012 12:00 6.3 4/20/2012 5:00 15.3 4/21/2012 22:00 89.7 4/23/2012 15:00

4/16/2012 20:00 26.2 4/18/2012 13:00 13.2 4/20/2012 6:00 19.9 4/21/2012 23:00 121.1 4/23/2012 16:00 22.3

4/16/2012 21:00 61.2 4/18/2012 14:00 8.2 4/20/2012 7:00 44.9 4/22/2012 0:00 106.3 4/23/2012 17:00 16.8

4/16/2012 22:00 166.3 4/18/2012 15:00 7.8 4/20/2012 8:00 194.3 4/22/2012 1:00 67.8 4/23/2012 18:00 63.3

4/16/2012 23:00 174.8 4/18/2012 16:00 15.3 4/20/2012 9:00 155.5 4/22/2012 2:00 58.8 4/23/2012 19:00 88.6

4/17/2012 0:00 104.3 4/18/2012 17:00 33.8 4/20/2012 10:00 31.7 4/22/2012 3:00 73.8 4/23/2012 20:00 168.1

4/17/2012 1:00 40.5 4/18/2012 18:00 46.3 4/20/2012 11:00 17.1 4/22/2012 4:00 69.8 4/23/2012 21:00 104.3

4/17/2012 2:00 20.9 4/18/2012 19:00 48.6 4/20/2012 12:00 5.1 4/22/2012 5:00 67.7 4/23/2012 22:00 29.6

4/17/2012 3:00 69.5 4/18/2012 20:00 47.3 4/20/2012 13:00 4.2 4/22/2012 6:00 38.9 4/23/2012 23:00 93.9

4/17/2012 4:00 72.5 4/18/2012 21:00 112.7 4/20/2012 14:00 4.9 4/22/2012 7:00 104 4/24/2012 0:00 108.9

4/17/2012 5:00 50.6 4/18/2012 22:00 100.4 4/20/2012 15:00 7.3 4/22/2012 8:00 92.1 4/24/2012 1:00 96.3

4/17/2012 6:00 23.7 4/18/2012 23:00 42.9 4/20/2012 16:00 12 4/22/2012 9:00 45.6 4/24/2012 2:00 87.7

4/17/2012 7:00 75.3 4/19/2012 0:00 22.5 4/20/2012 17:00 16.1 4/22/2012 10:00 15.2 4/24/2012 3:00 61.9

4/17/2012 8:00 55.2 4/19/2012 1:00 137.9 4/20/2012 18:00 35.1 4/22/2012 11:00 7.6 4/24/2012 4:00 54.9

4/17/2012 9:00 76.7 4/19/2012 2:00 239.6 4/20/2012 19:00 29.2 4/22/2012 12:00 16.9 4/24/2012 5:00 67.6

4/17/2012 10:00 41.5 4/19/2012 3:00 190.6 4/20/2012 20:00 38.8 4/22/2012 13:00 34.3 4/24/2012 6:00 54.1

4/17/2012 11:00 13.6 4/19/2012 4:00 85.4 4/20/2012 21:00 55.8 4/22/2012 14:00 16.8 4/24/2012 7:00 94.2

4/17/2012 12:00 8 4/19/2012 5:00 109.7 4/20/2012 22:00 60.1 4/22/2012 15:00 77.3 4/24/2012 8:00 275.9

4/17/2012 13:00 11.4 4/19/2012 6:00 75.6 4/20/2012 23:00 70.2 4/22/2012 16:00 48 4/24/2012 9:00 88.5

4/17/2012 14:00 10.7 4/19/2012 7:00 179.7 4/21/2012 0:00 76.4 4/22/2012 17:00 35.8 4/24/2012 10:00 29.4

4/17/2012 15:00 11.4 4/19/2012 8:00 153.9 4/21/2012 1:00 43.1 4/22/2012 18:00 36.5 4/24/2012 11:00 13.6

4/17/2012 16:00 17.6 4/19/2012 9:00 13.6 4/21/2012 2:00 45.5 4/22/2012 19:00 35.9 4/24/2012 12:00 12.4

4/17/2012 17:00 4/19/2012 10:00 21.7 4/21/2012 3:00 72.6 4/22/2012 20:00 46.2 4/24/2012 13:00 8

4/17/2012 18:00 37.2 4/19/2012 11:00 15.6 4/21/2012 4:00 57.6 4/22/2012 21:00 48.8 4/24/2012 14:00

4/17/2012 19:00 66.7 4/19/2012 12:00 5.9 4/21/2012 5:00 70.6 4/22/2012 22:00 57.4 4/24/2012 15:00 8.8

4/17/2012 20:00 71.4 4/19/2012 13:00 5.3 4/21/2012 6:00 100.4 4/22/2012 23:00 69.8 4/24/2012 16:00 11.7

4/17/2012 21:00 80.1 4/19/2012 14:00 4.2 4/21/2012 7:00 165.8 4/23/2012 0:00 127 4/24/2012 17:00 21.7

4/17/2012 22:00 103.8 4/19/2012 15:00 4.4 4/21/2012 8:00 171.7 4/23/2012 1:00 88.5 4/24/2012 18:00 24.5

4/17/2012 23:00 131.2 4/19/2012 16:00 5.6 4/21/2012 9:00 168.8 4/23/2012 2:00 81.4 4/24/2012 19:00 28.7

4/18/2012 0:00 242 4/19/2012 17:00 5.9 4/21/2012 10:00 102.7 4/23/2012 3:00 74.9 4/24/2012 20:00 18

4/18/2012 1:00 242.8 4/19/2012 18:00 20.8 4/21/2012 11:00 38.5 4/23/2012 4:00 37.5 4/24/2012 21:00 23.2

4/18/2012 2:00 300 4/19/2012 19:00 32.9 4/21/2012 12:00 12.3 4/23/2012 5:00 42.4 4/24/2012 22:00 44.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 32
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/24/2012 23:00 65.3 4/26/2012 16:00 3.7 4/29/2012 9:00 24.1 5/1/2012 2:00 8.8 5/2/2012 19:00 9.2

4/25/2012 0:00 70.5 4/26/2012 17:00 3.5 4/29/2012 10:00 12.4 5/1/2012 3:00 18.6 5/2/2012 20:00 30.2

4/25/2012 1:00 57.9 4/26/2012 18:00 3.5 4/29/2012 11:00 5.6 5/1/2012 4:00 32.4 5/2/2012 21:00 29.3

4/25/2012 2:00 50.4 4/26/2012 19:00 3.5 4/29/2012 12:00 4.8 5/1/2012 5:00 34.2 5/2/2012 22:00 42.1

4/25/2012 3:00 63.8 4/26/2012 20:00 3.8 4/29/2012 13:00 4.1 5/1/2012 6:00 44.4 5/2/2012 23:00 72.2

4/25/2012 4:00 58 4/26/2012 21:00 9.1 4/29/2012 14:00 4.1 5/1/2012 7:00 26.2 5/3/2012 0:00 75.1

4/25/2012 5:00 90.4 4/26/2012 22:00 12.4 4/29/2012 15:00 3.7 5/1/2012 8:00 14.3 5/3/2012 1:00 76.8

4/25/2012 6:00 79.3 4/26/2012 23:00 16.8 4/29/2012 16:00 3.6 5/1/2012 9:00 13.8 5/3/2012 2:00 47.2

4/25/2012 7:00 86.5 4/28/2012 0:00 32.1 4/29/2012 17:00 3.8 5/1/2012 10:00 8.2 5/3/2012 3:00 25.2

4/25/2012 8:00 39.2 4/28/2012 1:00 53.6 4/29/2012 18:00 5.2 5/1/2012 11:00 6 5/3/2012 4:00 47.7

4/25/2012 9:00 12.2 4/28/2012 2:00 21.4 4/29/2012 19:00 45.8 5/1/2012 12:00 4.3 5/3/2012 5:00 134.9

4/25/2012 10:00 14.3 4/28/2012 3:00 92.7 4/29/2012 20:00 29.2 5/1/2012 13:00 3.8 5/3/2012 6:00 189.2

4/25/2012 11:00 9.7 4/28/2012 4:00 122.1 4/29/2012 21:00 45.3 5/1/2012 14:00 5/3/2012 7:00 167.7

4/25/2012 12:00 12.1 4/28/2012 5:00 57.4 4/29/2012 22:00 38.6 5/1/2012 15:00 5.7 5/3/2012 8:00 179.3

4/25/2012 13:00 4.6 4/28/2012 6:00 66.2 4/29/2012 23:00 54.1 5/1/2012 16:00 4.2 5/3/2012 9:00 64.5

4/25/2012 14:00 3.8 4/28/2012 7:00 44.2 4/30/2012 0:00 170.9 5/1/2012 17:00 5.4 5/3/2012 10:00 10.1

4/25/2012 15:00 3.6 4/28/2012 8:00 34.1 4/30/2012 1:00 117.7 5/1/2012 18:00 7.1 5/3/2012 11:00 6.8

4/25/2012 16:00 3.9 4/28/2012 9:00 17.1 4/30/2012 2:00 148.1 5/1/2012 19:00 19.2 5/3/2012 12:00 5.2

4/25/2012 17:00 4.3 4/28/2012 10:00 7.4 4/30/2012 3:00 65.7 5/1/2012 20:00 13.1 5/3/2012 13:00 4.2

4/25/2012 18:00 4.8 4/28/2012 11:00 5 4/30/2012 4:00 34.9 5/1/2012 21:00 14.3 5/3/2012 14:00 4.2

4/25/2012 19:00 12.2 4/28/2012 12:00 4 4/30/2012 5:00 50.5 5/1/2012 22:00 18.6 5/3/2012 15:00 4.9

4/25/2012 20:00 43.5 4/28/2012 13:00 3.5 4/30/2012 6:00 49.4 5/1/2012 23:00 20.2 5/3/2012 16:00 6.4

4/25/2012 21:00 39.1 4/28/2012 14:00 3.4 4/30/2012 7:00 89.7 5/2/2012 0:00 26.1 5/3/2012 17:00 13.7

4/25/2012 22:00 29 4/28/2012 15:00 3.6 4/30/2012 8:00 41.3 5/2/2012 1:00 27.5 5/3/2012 18:00 209.8

4/25/2012 23:00 28.1 4/28/2012 16:00 3.5 4/30/2012 9:00 11.3 5/2/2012 2:00 44.8 5/3/2012 19:00 487.1

4/26/2012 0:00 29.2 4/28/2012 17:00 3.6 4/30/2012 10:00 7.8 5/2/2012 3:00 103.5 5/3/2012 20:00 289.9

4/26/2012 1:00 26.7 4/28/2012 18:00 3.9 4/30/2012 11:00 6.3 5/2/2012 4:00 180.6 5/3/2012 21:00 129.5

4/26/2012 2:00 43 4/28/2012 19:00 14.8 4/30/2012 12:00 5.2 5/2/2012 5:00 139.2 5/3/2012 22:00 40.5

4/26/2012 3:00 37.4 4/28/2012 20:00 10.5 4/30/2012 13:00 4.5 5/2/2012 6:00 179.3 5/3/2012 23:00 25

4/26/2012 4:00 50.9 4/28/2012 21:00 21.5 4/30/2012 14:00 4.7 5/2/2012 7:00 167.3 5/4/2012 0:00 21.7

4/26/2012 5:00 91.6 4/28/2012 22:00 27.2 4/30/2012 15:00 5/2/2012 8:00 142.7 5/4/2012 1:00 23.7

4/26/2012 6:00 77.2 4/28/2012 23:00 198.5 4/30/2012 16:00 5 5/2/2012 9:00 31 5/4/2012 2:00 31.1

4/26/2012 7:00 55.1 4/29/2012 0:00 71.8 4/30/2012 17:00 4.4 5/2/2012 10:00 10.3 5/4/2012 3:00 95.6

4/26/2012 8:00 45.5 4/29/2012 1:00 41.5 4/30/2012 18:00 6.7 5/2/2012 11:00 7.7 5/4/2012 4:00 139.8

4/26/2012 9:00 22.8 4/29/2012 2:00 67.1 4/30/2012 19:00 14.2 5/2/2012 12:00 8.4 5/4/2012 5:00 11

4/26/2012 10:00 8.5 4/29/2012 3:00 87.9 4/30/2012 20:00 42.4 5/2/2012 13:00 5.8 5/4/2012 6:00 7.5

4/26/2012 11:00 4.3 4/29/2012 4:00 82.9 4/30/2012 21:00 64 5/2/2012 14:00 3.9 5/4/2012 7:00 10.8

4/26/2012 12:00 3.7 4/29/2012 5:00 126.1 4/30/2012 22:00 168.1 5/2/2012 15:00 3.6 5/4/2012 8:00 9.3

4/26/2012 13:00 3.6 4/29/2012 6:00 39.2 4/30/2012 23:00 141 5/2/2012 16:00 3.6 5/4/2012 9:00 6.8

4/26/2012 14:00 3.6 4/29/2012 7:00 23.4 5/1/2012 0:00 135.4 5/2/2012 17:00 4.5 5/4/2012 10:00 11

4/26/2012 15:00 4.1 4/29/2012 8:00 26.1 5/1/2012 1:00 28.9 5/2/2012 18:00 5.2 5/4/2012 11:00 11.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 33
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/4/2012 12:00 10.1 5/6/2012 5:00 87.8 5/7/2012 22:00 52.2 5/9/2012 15:00 3.9 5/11/2012 8:00 33.1

5/4/2012 13:00 6.6 5/6/2012 6:00 86.8 5/7/2012 23:00 29.6 5/9/2012 16:00 15 5/11/2012 9:00 20.6

5/4/2012 14:00 4.8 5/6/2012 7:00 215.4 5/8/2012 0:00 60.4 5/9/2012 17:00 20 5/11/2012 10:00 16.9

5/4/2012 15:00 4.1 5/6/2012 8:00 8.4 5/8/2012 1:00 59.2 5/9/2012 18:00 30.5 5/11/2012 11:00 12.6

5/4/2012 16:00 4.5 5/6/2012 9:00 5 5/8/2012 2:00 29.3 5/9/2012 19:00 35.8 5/11/2012 12:00 5.2

5/4/2012 17:00 5.9 5/6/2012 10:00 5.6 5/8/2012 3:00 22.1 5/9/2012 20:00 17.6 5/11/2012 13:00 4.1

5/4/2012 18:00 10 5/6/2012 11:00 7.2 5/8/2012 4:00 32.3 5/9/2012 21:00 18.4 5/11/2012 14:00 4.1

5/4/2012 19:00 13.2 5/6/2012 12:00 5 5/8/2012 5:00 23.3 5/9/2012 22:00 21 5/11/2012 15:00 7.2

5/4/2012 20:00 13.1 5/6/2012 13:00 4 5/8/2012 6:00 21.5 5/9/2012 23:00 21.7 5/11/2012 16:00 12.8

5/4/2012 21:00 12 5/6/2012 14:00 3.7 5/8/2012 7:00 69.2 5/10/2012 0:00 168.3 5/11/2012 17:00 15.1

5/4/2012 22:00 51.7 5/6/2012 15:00 3.7 5/8/2012 8:00 111.4 5/10/2012 1:00 220.2 5/11/2012 18:00 107.3

5/4/2012 23:00 87.9 5/6/2012 16:00 3.6 5/8/2012 9:00 19.5 5/10/2012 2:00 195.3 5/11/2012 19:00 181.3

5/5/2012 0:00 102.5 5/6/2012 17:00 5 5/8/2012 10:00 10.6 5/10/2012 3:00 165.9 5/11/2012 20:00 129.9

5/5/2012 1:00 64.7 5/6/2012 18:00 8.9 5/8/2012 11:00 6.5 5/10/2012 4:00 161.5 5/11/2012 21:00 189.4

5/5/2012 2:00 51.9 5/6/2012 19:00 27.6 5/8/2012 12:00 4.5 5/10/2012 5:00 97.8 5/11/2012 22:00 214.6

5/5/2012 3:00 63.9 5/6/2012 20:00 21.1 5/8/2012 13:00 4.6 5/10/2012 6:00 123 5/11/2012 23:00 67.6

5/5/2012 4:00 101.6 5/6/2012 21:00 20.1 5/8/2012 14:00 5/10/2012 7:00 195.5 5/12/2012 0:00 69.4

5/5/2012 5:00 60.7 5/6/2012 22:00 21.4 5/8/2012 15:00 8.8 5/10/2012 8:00 137.2 5/12/2012 1:00 105

5/5/2012 6:00 58.6 5/6/2012 23:00 22.6 5/8/2012 16:00 4.9 5/10/2012 9:00 7.5 5/12/2012 2:00 141.6

5/5/2012 7:00 33.7 5/7/2012 0:00 53.8 5/8/2012 17:00 7.4 5/10/2012 10:00 17.8 5/12/2012 3:00 90.5

5/5/2012 8:00 18.8 5/7/2012 1:00 75.4 5/8/2012 18:00 9.7 5/10/2012 11:00 12.6 5/12/2012 4:00 60.2

5/5/2012 9:00 27.4 5/7/2012 2:00 101.7 5/8/2012 19:00 25.6 5/10/2012 12:00 4.7 5/12/2012 5:00 36.1

5/5/2012 10:00 14.6 5/7/2012 3:00 117.9 5/8/2012 20:00 39.6 5/10/2012 13:00 4.3 5/12/2012 6:00 25.7

5/5/2012 11:00 6.2 5/7/2012 4:00 129.6 5/8/2012 21:00 121.7 5/10/2012 14:00 4.4 5/12/2012 7:00 67.5

5/5/2012 12:00 4.9 5/7/2012 5:00 102.7 5/8/2012 22:00 76 5/10/2012 15:00 4.4 5/12/2012 8:00 122.7

5/5/2012 13:00 3.9 5/7/2012 6:00 95.4 5/8/2012 23:00 94.4 5/10/2012 16:00 3.9 5/12/2012 9:00 44.9

5/5/2012 14:00 3.7 5/7/2012 7:00 93.1 5/9/2012 0:00 101.6 5/10/2012 17:00 5 5/12/2012 10:00 7.3

5/5/2012 15:00 3.5 5/7/2012 8:00 249.6 5/9/2012 1:00 88.5 5/10/2012 18:00 5.3 5/12/2012 11:00 6.8

5/5/2012 16:00 3.5 5/7/2012 9:00 101.6 5/9/2012 2:00 52.5 5/10/2012 19:00 12.9 5/12/2012 12:00 10.5

5/5/2012 17:00 3.4 5/7/2012 10:00 13.3 5/9/2012 3:00 99.2 5/10/2012 20:00 22.5 5/12/2012 13:00 6.4

5/5/2012 18:00 3.8 5/7/2012 11:00 8.8 5/9/2012 4:00 49.2 5/10/2012 21:00 32.1 5/12/2012 14:00 6.5

5/5/2012 19:00 6.9 5/7/2012 12:00 9.6 5/9/2012 5:00 31.8 5/10/2012 22:00 36.2 5/12/2012 15:00 5

5/5/2012 20:00 8.6 5/7/2012 13:00 11 5/9/2012 6:00 36.5 5/10/2012 23:00 32.9 5/12/2012 16:00 5.3

5/5/2012 21:00 10.1 5/7/2012 14:00 7.9 5/9/2012 7:00 61.8 5/11/2012 0:00 24.8 5/12/2012 17:00 5.4

5/5/2012 22:00 17.1 5/7/2012 15:00 5/9/2012 8:00 102.5 5/11/2012 1:00 52.3 5/12/2012 18:00 6.9

5/5/2012 23:00 26.5 5/7/2012 16:00 8 5/9/2012 9:00 53.2 5/11/2012 2:00 63.2 5/12/2012 19:00 8.9

5/6/2012 0:00 45.3 5/7/2012 17:00 25.5 5/9/2012 10:00 17.8 5/11/2012 3:00 95.4 5/12/2012 20:00 9.1

5/6/2012 1:00 72.7 5/7/2012 18:00 8.3 5/9/2012 11:00 9.5 5/11/2012 4:00 104.3 5/12/2012 21:00 11.7

5/6/2012 2:00 56.8 5/7/2012 19:00 25.3 5/9/2012 12:00 9.4 5/11/2012 5:00 48.8 5/12/2012 22:00 13.5

5/6/2012 3:00 59.5 5/7/2012 20:00 42.6 5/9/2012 13:00 4.7 5/11/2012 6:00 62.7 5/12/2012 23:00 18.2

5/6/2012 4:00 65.1 5/7/2012 21:00 64.8 5/9/2012 14:00 4.1 5/11/2012 7:00 103.1 5/15/2012 0:00 9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 34
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/15/2012 1:00 10.7 5/16/2012 18:00 4 5/20/2012 11:00 5.4 5/22/2012 4:00 139.3 5/23/2012 21:00 20.7

5/15/2012 2:00 40.1 5/16/2012 19:00 13.6 5/20/2012 12:00 4.4 5/22/2012 5:00 314.2 5/23/2012 22:00 31

5/15/2012 3:00 141.6 5/16/2012 20:00 40.8 5/20/2012 13:00 4 5/22/2012 6:00 333.4 5/23/2012 23:00 37.8

5/15/2012 4:00 206.9 5/16/2012 21:00 27.9 5/20/2012 14:00 3.9 5/22/2012 7:00 283.7 5/24/2012 0:00 83.4

5/15/2012 5:00 193.1 5/16/2012 22:00 21.8 5/20/2012 15:00 3.8 5/22/2012 8:00 42 5/24/2012 1:00 89.7

5/15/2012 6:00 305.6 5/16/2012 23:00 33.3 5/20/2012 16:00 3.6 5/22/2012 9:00 6.6 5/24/2012 2:00 55.5

5/15/2012 7:00 305.7 5/19/2012 0:00 47.6 5/20/2012 17:00 3.6 5/22/2012 10:00 11.5 5/24/2012 3:00 72.8

5/15/2012 8:00 123 5/19/2012 1:00 49.8 5/20/2012 18:00 3.6 5/22/2012 11:00 9.9 5/24/2012 4:00 124

5/15/2012 9:00 39.8 5/19/2012 2:00 108.2 5/20/2012 19:00 3.6 5/22/2012 12:00 10.7 5/24/2012 5:00 90.1

5/15/2012 10:00 24.4 5/19/2012 3:00 136.9 5/20/2012 20:00 6 5/22/2012 13:00 7.9 5/24/2012 6:00 144

5/15/2012 11:00 13 5/19/2012 4:00 93.4 5/20/2012 21:00 26.7 5/22/2012 14:00 5/24/2012 7:00 335.5

5/15/2012 12:00 5.7 5/19/2012 5:00 99.4 5/20/2012 22:00 18.7 5/22/2012 15:00 10.5 5/24/2012 8:00 217

5/15/2012 13:00 3.8 5/19/2012 6:00 53.4 5/20/2012 23:00 26.4 5/22/2012 16:00 26.4 5/24/2012 9:00 10.6

5/15/2012 14:00 5/19/2012 7:00 58.9 5/21/2012 0:00 38.6 5/22/2012 17:00 31.1 5/24/2012 10:00 14.3

5/15/2012 15:00 5.8 5/19/2012 8:00 64.5 5/21/2012 1:00 221.7 5/22/2012 18:00 15.5 5/24/2012 11:00 8.6

5/15/2012 16:00 4.3 5/19/2012 9:00 34.3 5/21/2012 2:00 230.8 5/22/2012 19:00 97.7 5/24/2012 12:00 10.6

5/15/2012 17:00 4.4 5/19/2012 10:00 26.8 5/21/2012 3:00 290.9 5/22/2012 20:00 54.5 5/24/2012 13:00 7.5

5/15/2012 18:00 4.7 5/19/2012 11:00 6.1 5/21/2012 4:00 373.6 5/22/2012 21:00 123.9 5/24/2012 14:00 5.6

5/15/2012 19:00 5.6 5/19/2012 12:00 4.6 5/21/2012 5:00 313.6 5/22/2012 22:00 204.7 5/24/2012 15:00 5.8

5/15/2012 20:00 5.6 5/19/2012 13:00 4.1 5/21/2012 6:00 291.4 5/22/2012 23:00 439 5/24/2012 16:00 10.4

5/15/2012 21:00 6.3 5/19/2012 14:00 3.8 5/21/2012 7:00 171.9 5/23/2012 0:00 181.7 5/24/2012 17:00 6.1

5/15/2012 22:00 9 5/19/2012 15:00 3.7 5/21/2012 8:00 80.5 5/23/2012 1:00 64.3 5/24/2012 18:00 11.7

5/15/2012 23:00 112.9 5/19/2012 16:00 3.8 5/21/2012 9:00 17.5 5/23/2012 2:00 222.6 5/24/2012 19:00 13.3

5/16/2012 0:00 275.4 5/19/2012 17:00 4.4 5/21/2012 10:00 7.3 5/23/2012 3:00 101.9 5/24/2012 20:00 35

5/16/2012 1:00 203.9 5/19/2012 18:00 6.9 5/21/2012 11:00 5.3 5/23/2012 4:00 178.3 5/24/2012 21:00 38.2

5/16/2012 2:00 184.4 5/19/2012 19:00 12.5 5/21/2012 12:00 4.7 5/23/2012 5:00 154 5/24/2012 22:00 34.3

5/16/2012 3:00 228.9 5/19/2012 20:00 18.4 5/21/2012 13:00 4.2 5/23/2012 6:00 126.5 5/24/2012 23:00 40.8

5/16/2012 4:00 126.5 5/19/2012 21:00 20.2 5/21/2012 14:00 4.1 5/23/2012 7:00 35.9 5/25/2012 0:00 59.5

5/16/2012 5:00 48.9 5/19/2012 22:00 47.1 5/21/2012 15:00 5/23/2012 8:00 36.7 5/25/2012 1:00 41.1

5/16/2012 6:00 23 5/19/2012 23:00 51.5 5/21/2012 16:00 4.2 5/23/2012 9:00 23.3 5/25/2012 2:00 23.1

5/16/2012 7:00 24.7 5/20/2012 0:00 83.3 5/21/2012 17:00 4.3 5/23/2012 10:00 11.6 5/25/2012 3:00 65.1

5/16/2012 8:00 12.9 5/20/2012 1:00 32 5/21/2012 18:00 4.6 5/23/2012 11:00 18.4 5/25/2012 4:00 35.4

5/16/2012 9:00 41.9 5/20/2012 2:00 11.5 5/21/2012 19:00 7.5 5/23/2012 12:00 8.4 5/25/2012 5:00 93.7

5/16/2012 10:00 5/20/2012 3:00 24.5 5/21/2012 20:00 12.2 5/23/2012 13:00 5.5 5/25/2012 6:00 63.3

5/16/2012 11:00 5/20/2012 4:00 52.9 5/21/2012 21:00 11.1 5/23/2012 14:00 4.2 5/25/2012 7:00 83.7

5/16/2012 12:00 5/20/2012 5:00 32.1 5/21/2012 22:00 24.3 5/23/2012 15:00 4 5/25/2012 8:00 118.8

5/16/2012 13:00 5.1 5/20/2012 6:00 21.2 5/21/2012 23:00 233.4 5/23/2012 16:00 3.8 5/25/2012 9:00 23.7

5/16/2012 14:00 4.3 5/20/2012 7:00 60.6 5/22/2012 0:00 237.4 5/23/2012 17:00 4.4 5/25/2012 10:00 18.4

5/16/2012 15:00 4 5/20/2012 8:00 121.2 5/22/2012 1:00 267.6 5/23/2012 18:00 4.7 5/25/2012 11:00 8.9

5/16/2012 16:00 3.8 5/20/2012 9:00 17.9 5/22/2012 2:00 352.6 5/23/2012 19:00 5.6 5/25/2012 12:00

5/16/2012 17:00 3.8 5/20/2012 10:00 7.5 5/22/2012 3:00 214.6 5/23/2012 20:00 12.9 5/25/2012 13:00 6.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 35
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/25/2012 14:00 5.1 5/27/2012 7:00 62.9 5/29/2012 0:00 87.9 5/30/2012 17:00 9.2 6/1/2012 10:00 8.2

5/25/2012 15:00 6.1 5/27/2012 8:00 18.7 5/29/2012 1:00 229.1 5/30/2012 18:00 125.8 6/1/2012 11:00 8.4

5/25/2012 16:00 9.6 5/27/2012 9:00 9.2 5/29/2012 2:00 34.7 5/30/2012 19:00 354.7 6/1/2012 12:00 7.1

5/25/2012 17:00 14 5/27/2012 10:00 6.2 5/29/2012 3:00 56.5 5/30/2012 20:00 220.4 6/1/2012 13:00 5.9

5/25/2012 18:00 5.8 5/27/2012 11:00 5.1 5/29/2012 4:00 91.9 5/30/2012 21:00 126.2 6/1/2012 14:00 17.3

5/25/2012 19:00 78 5/27/2012 12:00 4.7 5/29/2012 5:00 267.1 5/30/2012 22:00 47.8 6/1/2012 15:00 8.5

5/25/2012 20:00 45.6 5/27/2012 13:00 4.3 5/29/2012 6:00 215.7 5/30/2012 23:00 44.9 6/1/2012 16:00 16.5

5/25/2012 21:00 52.7 5/27/2012 14:00 4.1 5/29/2012 7:00 191.3 5/31/2012 0:00 24.1 6/1/2012 17:00 27.5

5/25/2012 22:00 37.1 5/27/2012 15:00 4.1 5/29/2012 8:00 253.1 5/31/2012 1:00 69 6/1/2012 18:00 23.2

5/25/2012 23:00 55.2 5/27/2012 16:00 4.3 5/29/2012 9:00 61.3 5/31/2012 2:00 76.3 6/1/2012 19:00 237.4

5/26/2012 0:00 61.6 5/27/2012 17:00 6.4 5/29/2012 10:00 30.8 5/31/2012 3:00 36.5 6/1/2012 20:00 187.9

5/26/2012 1:00 107.6 5/27/2012 18:00 13.4 5/29/2012 11:00 5.3 5/31/2012 4:00 47.3 6/1/2012 21:00 302.8

5/26/2012 2:00 121 5/27/2012 19:00 6.4 5/29/2012 12:00 5.9 5/31/2012 5:00 205.1 6/1/2012 22:00 256.1

5/26/2012 3:00 22 5/27/2012 20:00 25.1 5/29/2012 13:00 6.8 5/31/2012 6:00 114.3 6/1/2012 23:00 181.1

5/26/2012 4:00 92.8 5/27/2012 21:00 30.4 5/29/2012 14:00 5/31/2012 7:00 63.2 6/2/2012 0:00 210.3

5/26/2012 5:00 76 5/27/2012 22:00 29.7 5/29/2012 15:00 8.6 5/31/2012 8:00 20.1 6/2/2012 1:00 232.9

5/26/2012 6:00 140.6 5/27/2012 23:00 28 5/29/2012 16:00 6 5/31/2012 9:00 346.2 6/2/2012 2:00 195

5/26/2012 7:00 251 5/28/2012 0:00 67.1 5/29/2012 17:00 5.4 5/31/2012 10:00 135.8 6/2/2012 3:00 154.9

5/26/2012 8:00 18.2 5/28/2012 1:00 68.5 5/29/2012 18:00 92.3 5/31/2012 11:00 9.9 6/2/2012 4:00 129.4

5/26/2012 9:00 15.3 5/28/2012 2:00 41.1 5/29/2012 19:00 118.2 5/31/2012 12:00 7.9 6/2/2012 5:00 84.6

5/26/2012 10:00 9 5/28/2012 3:00 38.2 5/29/2012 20:00 110.5 5/31/2012 13:00 7.2 6/2/2012 6:00 98.3

5/26/2012 11:00 9.6 5/28/2012 4:00 41.9 5/29/2012 21:00 80.1 5/31/2012 14:00 7.3 6/2/2012 7:00 98.2

5/26/2012 12:00 7.1 5/28/2012 5:00 54.4 5/29/2012 22:00 66.5 5/31/2012 15:00 6 6/2/2012 8:00 149.4

5/26/2012 13:00 6.1 5/28/2012 6:00 68.4 5/29/2012 23:00 152 5/31/2012 16:00 7.7 6/2/2012 9:00 78.8

5/26/2012 14:00 5.9 5/28/2012 7:00 81.8 5/30/2012 0:00 178.9 5/31/2012 17:00 13.1 6/2/2012 10:00 21.6

5/26/2012 15:00 5.6 5/28/2012 8:00 96.7 5/30/2012 1:00 251.5 5/31/2012 18:00 79.2 6/2/2012 11:00 30.3

5/26/2012 16:00 7.8 5/28/2012 9:00 83.7 5/30/2012 2:00 319.6 5/31/2012 19:00 135.7 6/2/2012 12:00 24.5

5/26/2012 17:00 5/28/2012 10:00 21.9 5/30/2012 3:00 250.7 5/31/2012 20:00 85.9 6/2/2012 13:00 19.8

5/26/2012 18:00 12.7 5/28/2012 11:00 8.9 5/30/2012 4:00 281.6 5/31/2012 21:00 145.5 6/2/2012 14:00 20.4

5/26/2012 19:00 10.1 5/28/2012 12:00 6.1 5/30/2012 5:00 300.1 5/31/2012 22:00 118.8 6/2/2012 15:00 34.3

5/26/2012 20:00 516 5/28/2012 13:00 6.1 5/30/2012 6:00 277.2 5/31/2012 23:00 69.5 6/2/2012 16:00 36

5/26/2012 21:00 106.5 5/28/2012 14:00 4.8 5/30/2012 7:00 393.1 6/1/2012 0:00 53.5 6/2/2012 17:00 32

5/26/2012 22:00 35.2 5/28/2012 15:00 5/30/2012 8:00 74.9 6/1/2012 1:00 33.8 6/2/2012 18:00 51.2

5/26/2012 23:00 18.7 5/28/2012 16:00 5.7 5/30/2012 9:00 34.8 6/1/2012 2:00 74.1 6/2/2012 19:00 59.9

5/27/2012 0:00 6.9 5/28/2012 17:00 15.2 5/30/2012 10:00 59.4 6/1/2012 3:00 72.6 6/2/2012 20:00 75.6

5/27/2012 1:00 26.9 5/28/2012 18:00 16.1 5/30/2012 11:00 5.2 6/1/2012 4:00 33 6/2/2012 21:00 92.1

5/27/2012 2:00 99.2 5/28/2012 19:00 27.8 5/30/2012 12:00 9.6 6/1/2012 5:00 78.6 6/2/2012 22:00 92.7

5/27/2012 3:00 87.1 5/28/2012 20:00 33.1 5/30/2012 13:00 7.6 6/1/2012 6:00 114.8 6/2/2012 23:00 75.8

5/27/2012 4:00 20.6 5/28/2012 21:00 105.8 5/30/2012 14:00 9 6/1/2012 7:00 71.4 6/3/2012 0:00 76.3

5/27/2012 5:00 10.2 5/28/2012 22:00 85.5 5/30/2012 15:00 9.4 6/1/2012 8:00 40.2 6/3/2012 1:00 69.9

5/27/2012 6:00 6.9 5/28/2012 23:00 50.4 5/30/2012 16:00 11.3 6/1/2012 9:00 6.3 6/3/2012 2:00 47.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 36
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/3/2012 3:00 49.8 6/4/2012 20:00 45.5 6/6/2012 13:00 13.7 6/9/2012 6:00 230.9 6/10/2012 23:00 25.8

6/3/2012 4:00 71.3 6/4/2012 21:00 55.2 6/6/2012 14:00 7.6 6/9/2012 7:00 61.4 6/13/2012 0:00 17.5

6/3/2012 5:00 66.5 6/4/2012 22:00 38 6/6/2012 15:00 7.7 6/9/2012 8:00 20.4 6/13/2012 1:00 34.2

6/3/2012 6:00 54.3 6/4/2012 23:00 31.5 6/6/2012 16:00 12.1 6/9/2012 9:00 45.4 6/13/2012 2:00 71.5

6/3/2012 7:00 70.9 6/5/2012 0:00 31.2 6/6/2012 17:00 12.7 6/9/2012 10:00 11 6/13/2012 3:00 100.4

6/3/2012 8:00 117.6 6/5/2012 1:00 35.3 6/6/2012 18:00 22.2 6/9/2012 11:00 6 6/13/2012 4:00 86.8

6/3/2012 9:00 144.7 6/5/2012 2:00 47.7 6/6/2012 19:00 42.5 6/9/2012 12:00 4.7 6/13/2012 5:00 60.7

6/3/2012 10:00 71.3 6/5/2012 3:00 96.3 6/6/2012 20:00 31.3 6/9/2012 13:00 4.1 6/13/2012 6:00 19

6/3/2012 11:00 19.8 6/5/2012 4:00 81 6/6/2012 21:00 44.9 6/9/2012 14:00 3.9 6/13/2012 7:00 17.6

6/3/2012 12:00 13.3 6/5/2012 5:00 123.7 6/6/2012 22:00 36.3 6/9/2012 15:00 3.7 6/13/2012 8:00 16.1

6/3/2012 13:00 14.8 6/5/2012 6:00 188.1 6/6/2012 23:00 38.6 6/9/2012 16:00 3.7 6/13/2012 9:00 7

6/3/2012 14:00 16.2 6/5/2012 7:00 158.1 6/7/2012 0:00 45.2 6/9/2012 17:00 3.7 6/13/2012 10:00 5

6/3/2012 15:00 13.9 6/5/2012 8:00 34.7 6/7/2012 1:00 106.8 6/9/2012 18:00 4.1 6/13/2012 11:00 4.2

6/3/2012 16:00 12.2 6/5/2012 9:00 19.9 6/7/2012 2:00 238.1 6/9/2012 19:00 10.8 6/13/2012 12:00 4

6/3/2012 17:00 21.2 6/5/2012 10:00 17.7 6/7/2012 3:00 314.5 6/9/2012 20:00 40 6/13/2012 13:00 3.7

6/3/2012 18:00 89.6 6/5/2012 11:00 16.4 6/7/2012 4:00 300.9 6/9/2012 21:00 29.8 6/13/2012 14:00 3.6

6/3/2012 19:00 134.8 6/5/2012 12:00 6.5 6/7/2012 5:00 424.4 6/9/2012 22:00 95.9 6/13/2012 15:00 3.5

6/3/2012 20:00 84.4 6/5/2012 13:00 5.2 6/7/2012 6:00 340 6/9/2012 23:00 73.6 6/13/2012 16:00 3.5

6/3/2012 21:00 43.3 6/5/2012 14:00 6/7/2012 7:00 508.8 6/10/2012 0:00 50.5 6/13/2012 17:00 3.5

6/3/2012 22:00 14.9 6/5/2012 15:00 6 6/7/2012 8:00 170.4 6/10/2012 1:00 69.6 6/13/2012 18:00 3.5

6/3/2012 23:00 16.8 6/5/2012 16:00 4.4 6/7/2012 9:00 123.6 6/10/2012 2:00 117.1 6/13/2012 19:00 3.6

6/4/2012 0:00 71.7 6/5/2012 17:00 5.1 6/7/2012 10:00 23 6/10/2012 3:00 90.1 6/13/2012 20:00 3.7

6/4/2012 1:00 73.8 6/5/2012 18:00 10.8 6/7/2012 11:00 10.6 6/10/2012 4:00 75.8 6/13/2012 21:00 3.8

6/4/2012 2:00 42.4 6/5/2012 19:00 27.4 6/7/2012 12:00 6 6/10/2012 5:00 57.4 6/13/2012 22:00 7.9

6/4/2012 3:00 63.5 6/5/2012 20:00 46.4 6/7/2012 13:00 4.7 6/10/2012 6:00 30.7 6/13/2012 23:00 18.4

6/4/2012 4:00 132.7 6/5/2012 21:00 95.1 6/7/2012 14:00 4.3 6/10/2012 7:00 40.2 6/14/2012 0:00 62.7

6/4/2012 5:00 246.2 6/5/2012 22:00 68.8 6/7/2012 15:00 5.2 6/10/2012 8:00 169.3 6/14/2012 1:00 244.8

6/4/2012 6:00 368.6 6/5/2012 23:00 81.1 6/7/2012 16:00 5 6/10/2012 9:00 14 6/14/2012 2:00 149.5

6/4/2012 7:00 258.9 6/6/2012 0:00 57.3 6/7/2012 17:00 6.1 6/10/2012 10:00 14 6/14/2012 3:00 131.9

6/4/2012 8:00 81.1 6/6/2012 1:00 44.4 6/7/2012 18:00 9.9 6/10/2012 11:00 12.1 6/14/2012 4:00 82.7

6/4/2012 9:00 22.9 6/6/2012 2:00 36.2 6/7/2012 19:00 14.9 6/10/2012 12:00 6.2 6/14/2012 5:00 70.7

6/4/2012 10:00 16.5 6/6/2012 3:00 44.8 6/7/2012 20:00 13.3 6/10/2012 13:00 4.8 6/14/2012 6:00 112.6

6/4/2012 11:00 8 6/6/2012 4:00 55.8 6/7/2012 21:00 10 6/10/2012 14:00 4 6/14/2012 7:00 283.2

6/4/2012 12:00 6.7 6/6/2012 5:00 50.4 6/7/2012 22:00 8.9 6/10/2012 15:00 3.8 6/14/2012 8:00 41.7

6/4/2012 13:00 5.1 6/6/2012 6:00 69 6/7/2012 23:00 6.8 6/10/2012 16:00 3.9 6/14/2012 9:00 38.8

6/4/2012 14:00 4.7 6/6/2012 7:00 63.3 6/9/2012 0:00 51.4 6/10/2012 17:00 3.9 6/14/2012 10:00 10.9

6/4/2012 15:00 6/6/2012 8:00 147.5 6/9/2012 1:00 72.5 6/10/2012 18:00 4.6 6/14/2012 11:00 5.5

6/4/2012 16:00 4.8 6/6/2012 9:00 82.1 6/9/2012 2:00 43.8 6/10/2012 19:00 9.3 6/14/2012 12:00 4.5

6/4/2012 17:00 4.7 6/6/2012 10:00 11.2 6/9/2012 3:00 28 6/10/2012 20:00 43.7 6/14/2012 13:00 4.1

6/4/2012 18:00 9.7 6/6/2012 11:00 19 6/9/2012 4:00 58 6/10/2012 21:00 45 6/14/2012 14:00 3.9

6/4/2012 19:00 39 6/6/2012 12:00 9 6/9/2012 5:00 130.3 6/10/2012 22:00 35.7 6/14/2012 15:00 4.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 37
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/14/2012 16:00 4 6/16/2012 9:00 8.3 6/18/2012 2:00 3.2 6/19/2012 19:00 5.5 6/24/2012 12:00 11.9

6/14/2012 17:00 3.8 6/16/2012 10:00 20.1 6/18/2012 3:00 3.3 6/19/2012 20:00 6.5 6/24/2012 13:00 11.1

6/14/2012 18:00 3.9 6/16/2012 11:00 16.3 6/18/2012 4:00 3.3 6/19/2012 21:00 8.9 6/24/2012 14:00 8.7

6/14/2012 19:00 3.8 6/16/2012 12:00 7.1 6/18/2012 5:00 3.3 6/19/2012 22:00 25.2 6/24/2012 15:00 6.4

6/14/2012 20:00 3.9 6/16/2012 13:00 13.3 6/18/2012 6:00 3.3 6/19/2012 23:00 43.5 6/24/2012 16:00 5.8

6/14/2012 21:00 19.1 6/16/2012 14:00 9.3 6/18/2012 7:00 3.5 6/23/2012 0:00 24.4 6/24/2012 17:00 6.4

6/14/2012 22:00 30.1 6/16/2012 15:00 7.1 6/18/2012 8:00 3.3 6/23/2012 1:00 16.6 6/24/2012 18:00 6

6/14/2012 23:00 22.1 6/16/2012 16:00 9.6 6/18/2012 9:00 4.6 6/23/2012 2:00 14.8 6/24/2012 19:00 12.7

6/15/2012 0:00 18.4 6/16/2012 17:00 10.2 6/18/2012 10:00 29.4 6/23/2012 3:00 14.3 6/24/2012 20:00 22.5

6/15/2012 1:00 15.4 6/16/2012 18:00 12.6 6/18/2012 11:00 150.9 6/23/2012 4:00 14.6 6/24/2012 21:00 75

6/15/2012 2:00 38.5 6/16/2012 19:00 14.3 6/18/2012 12:00 180.4 6/23/2012 5:00 24.4 6/24/2012 22:00 80.3

6/15/2012 3:00 94.5 6/16/2012 20:00 15.4 6/18/2012 13:00 44.7 6/23/2012 6:00 25.6 6/24/2012 23:00 65.8

6/15/2012 4:00 405.2 6/16/2012 21:00 36.6 6/18/2012 14:00 99.2 6/23/2012 7:00 31.8 6/25/2012 0:00 90.3

6/15/2012 5:00 680.6 6/16/2012 22:00 45.5 6/18/2012 15:00 6/23/2012 8:00 13.4 6/25/2012 1:00 120.6

6/15/2012 6:00 211.4 6/16/2012 23:00 49.3 6/18/2012 16:00 164.3 6/23/2012 9:00 8 6/25/2012 2:00 113.4

6/15/2012 7:00 148 6/17/2012 0:00 39.2 6/18/2012 17:00 38.2 6/23/2012 10:00 6.5 6/25/2012 3:00 45.7

6/15/2012 8:00 67 6/17/2012 1:00 42.9 6/18/2012 18:00 66 6/23/2012 11:00 6.1 6/25/2012 4:00 19.8

6/15/2012 9:00 16.3 6/17/2012 2:00 40.3 6/18/2012 19:00 65.7 6/23/2012 12:00 5.3 6/25/2012 5:00 24.4

6/15/2012 10:00 7.2 6/17/2012 3:00 44.6 6/18/2012 20:00 29 6/23/2012 13:00 5.1 6/25/2012 6:00 46

6/15/2012 11:00 5 6/17/2012 4:00 40.1 6/18/2012 21:00 31.4 6/23/2012 14:00 5 6/25/2012 7:00 125.8

6/15/2012 12:00 4.5 6/17/2012 5:00 65 6/18/2012 22:00 31.7 6/23/2012 15:00 5.1 6/25/2012 8:00 302.4

6/15/2012 13:00 4.2 6/17/2012 6:00 121.9 6/18/2012 23:00 10.6 6/23/2012 16:00 20.4 6/25/2012 9:00 28.6

6/15/2012 14:00 3.9 6/17/2012 7:00 162.7 6/19/2012 0:00 8.8 6/23/2012 17:00 13.6 6/25/2012 10:00 18.2

6/15/2012 15:00 3.8 6/17/2012 8:00 137.6 6/19/2012 1:00 5.6 6/23/2012 18:00 10.9 6/25/2012 11:00 13.1

6/15/2012 16:00 3.9 6/17/2012 9:00 116.6 6/19/2012 2:00 140.5 6/23/2012 19:00 22.9 6/25/2012 12:00 6.8

6/15/2012 17:00 4.6 6/17/2012 10:00 32.6 6/19/2012 3:00 18.8 6/23/2012 20:00 45.1 6/25/2012 13:00 12.7

6/15/2012 18:00 6.6 6/17/2012 11:00 22.8 6/19/2012 4:00 35 6/23/2012 21:00 58.9 6/25/2012 14:00 12

6/15/2012 19:00 4.8 6/17/2012 12:00 9.7 6/19/2012 5:00 69.7 6/23/2012 22:00 84.4 6/25/2012 15:00

6/15/2012 20:00 25.1 6/17/2012 13:00 13.3 6/19/2012 6:00 82.1 6/23/2012 23:00 66 6/25/2012 16:00 6.5

6/15/2012 21:00 292.1 6/17/2012 14:00 13.7 6/19/2012 7:00 100 6/24/2012 0:00 74.9 6/25/2012 17:00 7.5

6/15/2012 22:00 244.4 6/17/2012 15:00 12.2 6/19/2012 8:00 97 6/24/2012 1:00 76 6/25/2012 18:00 19.7

6/15/2012 23:00 239.9 6/17/2012 16:00 13 6/19/2012 9:00 39.9 6/24/2012 2:00 75.9 6/25/2012 19:00 35.6

6/16/2012 0:00 256.3 6/17/2012 17:00 13.9 6/19/2012 10:00 12.7 6/24/2012 3:00 93.4 6/25/2012 20:00 60.7

6/16/2012 1:00 280.9 6/17/2012 18:00 14.3 6/19/2012 11:00 8.6 6/24/2012 4:00 67.1 6/25/2012 21:00 79.9

6/16/2012 2:00 327.4 6/17/2012 19:00 30.2 6/19/2012 12:00 6.7 6/24/2012 5:00 60.4 6/25/2012 22:00 126.6

6/16/2012 3:00 340.1 6/17/2012 20:00 5 6/19/2012 13:00 5.5 6/24/2012 6:00 64.1 6/25/2012 23:00 70.9

6/16/2012 4:00 191.3 6/17/2012 21:00 3.4 6/19/2012 14:00 6/24/2012 7:00 65 6/26/2012 0:00 48.7

6/16/2012 5:00 210.2 6/17/2012 22:00 3.3 6/19/2012 15:00 7.3 6/24/2012 8:00 147.9 6/26/2012 1:00 113.6

6/16/2012 6:00 267.1 6/17/2012 23:00 3.3 6/19/2012 16:00 5.6 6/24/2012 9:00 378 6/26/2012 2:00 106.1

6/16/2012 7:00 125.2 6/18/2012 0:00 3.3 6/19/2012 17:00 4.9 6/24/2012 10:00 27.5 6/26/2012 3:00 112.3

6/16/2012 8:00 443.3 6/18/2012 1:00 3.3 6/19/2012 18:00 4.9 6/24/2012 11:00 17 6/26/2012 4:00 132.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 38
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/26/2012 5:00 107.4 6/27/2012 22:00 90.1 6/29/2012 15:00 4.7 7/1/2012 8:00 36.3 7/3/2012 1:00 89.4

6/26/2012 6:00 97.1 6/27/2012 23:00 52.4 6/29/2012 16:00 4.6 7/1/2012 9:00 12.3 7/3/2012 2:00 63

6/26/2012 7:00 119.8 6/28/2012 0:00 72.1 6/29/2012 17:00 5.7 7/1/2012 10:00 5.6 7/3/2012 3:00 20.7

6/26/2012 8:00 119.8 6/28/2012 1:00 80.8 6/29/2012 18:00 11.1 7/1/2012 11:00 4.3 7/3/2012 4:00 51

6/26/2012 9:00 75.8 6/28/2012 2:00 64.5 6/29/2012 19:00 21.8 7/1/2012 12:00 4 7/3/2012 5:00 49.7

6/26/2012 10:00 33.9 6/28/2012 3:00 56.3 6/29/2012 20:00 54.9 7/1/2012 13:00 3.7 7/3/2012 6:00 37.6

6/26/2012 11:00 14.8 6/28/2012 4:00 77.9 6/29/2012 21:00 135.6 7/1/2012 14:00 3.8 7/3/2012 7:00 47.6

6/26/2012 12:00 11.9 6/28/2012 5:00 56.6 6/29/2012 22:00 143.1 7/1/2012 15:00 3.8 7/3/2012 8:00 38.5

6/26/2012 13:00 6/28/2012 6:00 36.4 6/29/2012 23:00 135.1 7/1/2012 16:00 3.7 7/3/2012 9:00 22.9

6/26/2012 14:00 6/28/2012 7:00 29.4 6/30/2012 0:00 98.4 7/1/2012 17:00 3.7 7/3/2012 10:00 6.6

6/26/2012 15:00 6/28/2012 8:00 32.9 6/30/2012 1:00 64.5 7/1/2012 18:00 3.9 7/3/2012 11:00 4.8

6/26/2012 16:00 6/28/2012 9:00 60 6/30/2012 2:00 81.8 7/1/2012 19:00 5.2 7/3/2012 12:00 4.3

6/26/2012 17:00 29.6 6/28/2012 10:00 18.7 6/30/2012 3:00 87.3 7/1/2012 20:00 6.7 7/3/2012 13:00 4.1

6/26/2012 18:00 25.2 6/28/2012 11:00 8.3 6/30/2012 4:00 121.7 7/1/2012 21:00 21.5 7/3/2012 14:00

6/26/2012 19:00 30.1 6/28/2012 12:00 5.7 6/30/2012 5:00 189 7/1/2012 22:00 45.7 7/3/2012 15:00 7.3

6/26/2012 20:00 60.7 6/28/2012 13:00 5.2 6/30/2012 6:00 96.6 7/1/2012 23:00 24.2 7/3/2012 16:00 5

6/26/2012 21:00 58.1 6/28/2012 14:00 5.5 6/30/2012 7:00 115.7 7/2/2012 0:00 22.2 7/3/2012 17:00 4.5

6/26/2012 22:00 39.1 6/28/2012 15:00 6.1 6/30/2012 8:00 60 7/2/2012 1:00 34.1 7/3/2012 18:00 6.6

6/26/2012 23:00 39.8 6/28/2012 16:00 4.7 6/30/2012 9:00 45.4 7/2/2012 2:00 133.6 7/3/2012 19:00 8

6/27/2012 0:00 53.5 6/28/2012 17:00 4.5 6/30/2012 10:00 22.3 7/2/2012 3:00 53.8 7/3/2012 20:00 13.5

6/27/2012 1:00 58.3 6/28/2012 18:00 4.2 6/30/2012 11:00 12 7/2/2012 4:00 24.4 7/3/2012 21:00 18.6

6/27/2012 2:00 44.3 6/28/2012 19:00 4.2 6/30/2012 12:00 5.6 7/2/2012 5:00 69.9 7/3/2012 22:00 25.6

6/27/2012 3:00 51.5 6/28/2012 20:00 3.9 6/30/2012 13:00 4.8 7/2/2012 6:00 60.6 7/3/2012 23:00 29.3

6/27/2012 4:00 75.7 6/28/2012 21:00 5 6/30/2012 14:00 4.3 7/2/2012 7:00 164.6 7/5/2012 0:00 87

6/27/2012 5:00 80.7 6/28/2012 22:00 16.3 6/30/2012 15:00 4 7/2/2012 8:00 55.2 7/5/2012 1:00 138.8

6/27/2012 6:00 103.1 6/28/2012 23:00 58.8 6/30/2012 16:00 3.9 7/2/2012 9:00 19 7/5/2012 2:00 125.2

6/27/2012 7:00 113.6 6/29/2012 0:00 39.8 6/30/2012 17:00 3.8 7/2/2012 10:00 13.1 7/5/2012 3:00 125.8

6/27/2012 8:00 128 6/29/2012 1:00 16 6/30/2012 18:00 4 7/2/2012 11:00 6.9 7/5/2012 4:00 75.6

6/27/2012 9:00 31.9 6/29/2012 2:00 68.8 6/30/2012 19:00 4.9 7/2/2012 12:00 5 7/5/2012 5:00 36.6

6/27/2012 10:00 17.3 6/29/2012 3:00 140.2 6/30/2012 20:00 6.9 7/2/2012 13:00 4.4 7/5/2012 6:00 93.7

6/27/2012 11:00 19 6/29/2012 4:00 95.6 6/30/2012 21:00 14.1 7/2/2012 14:00 3.9 7/5/2012 7:00 67.5

6/27/2012 12:00 16.2 6/29/2012 5:00 44.4 6/30/2012 22:00 27.1 7/2/2012 15:00 7/5/2012 8:00 28.1

6/27/2012 13:00 13 6/29/2012 6:00 99.4 6/30/2012 23:00 39 7/2/2012 16:00 4 7/5/2012 9:00 41.8

6/27/2012 14:00 12.1 6/29/2012 7:00 338.9 7/1/2012 0:00 28.6 7/2/2012 17:00 3.8 7/5/2012 10:00 18.1

6/27/2012 15:00 14.1 6/29/2012 8:00 155.7 7/1/2012 1:00 20.2 7/2/2012 18:00 3.8 7/5/2012 11:00 12

6/27/2012 16:00 13.6 6/29/2012 9:00 212.8 7/1/2012 2:00 29.6 7/2/2012 19:00 5.2 7/5/2012 12:00 12.6

6/27/2012 17:00 175.5 6/29/2012 10:00 35.4 7/1/2012 3:00 19.1 7/2/2012 20:00 11.2 7/5/2012 13:00 9.5

6/27/2012 18:00 45.2 6/29/2012 11:00 11.5 7/1/2012 4:00 41.4 7/2/2012 21:00 14.1 7/5/2012 14:00 10.8

6/27/2012 19:00 84.3 6/29/2012 12:00 7 7/1/2012 5:00 57.8 7/2/2012 22:00 19.3 7/5/2012 15:00 6.1

6/27/2012 20:00 128.6 6/29/2012 13:00 6.7 7/1/2012 6:00 141 7/2/2012 23:00 23.9 7/5/2012 16:00 5.8

6/27/2012 21:00 96.5 6/29/2012 14:00 5.7 7/1/2012 7:00 196.8 7/3/2012 0:00 84.2 7/5/2012 17:00 9.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 39
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/5/2012 18:00 14.8 7/7/2012 11:00 11.3 7/9/2012 4:00 103.1 7/10/2012 21:00 252.8 7/12/2012 14:00 10

7/5/2012 19:00 21.2 7/7/2012 12:00 10.3 7/9/2012 5:00 134.5 7/10/2012 22:00 143.1 7/12/2012 15:00 9.9

7/5/2012 20:00 22.7 7/7/2012 13:00 12.4 7/9/2012 6:00 129.4 7/10/2012 23:00 156.6 7/12/2012 16:00 12.8

7/5/2012 21:00 30.1 7/7/2012 14:00 12.6 7/9/2012 7:00 183.3 7/11/2012 0:00 129.4 7/12/2012 17:00 13.8

7/5/2012 22:00 41.2 7/7/2012 15:00 10.5 7/9/2012 8:00 189.8 7/11/2012 1:00 88.9 7/12/2012 18:00 9.5

7/5/2012 23:00 42.5 7/7/2012 16:00 12.7 7/9/2012 9:00 46 7/11/2012 2:00 89.5 7/12/2012 19:00 9.7

7/6/2012 0:00 65.7 7/7/2012 17:00 15 7/9/2012 10:00 13 7/11/2012 3:00 73.2 7/12/2012 20:00 28.4

7/6/2012 1:00 44.9 7/7/2012 18:00 75.2 7/9/2012 11:00 17 7/11/2012 4:00 83.4 7/12/2012 21:00 27.3

7/6/2012 2:00 26.7 7/7/2012 19:00 169.3 7/9/2012 12:00 10 7/11/2012 5:00 77.3 7/12/2012 22:00 34.8

7/6/2012 3:00 23.9 7/7/2012 20:00 109.7 7/9/2012 13:00 9.2 7/11/2012 6:00 58 7/12/2012 23:00 54

7/6/2012 4:00 32.8 7/7/2012 21:00 78.4 7/9/2012 14:00 6.1 7/11/2012 7:00 14.9 7/13/2012 0:00 69.5

7/6/2012 5:00 25.2 7/7/2012 22:00 83.5 7/9/2012 15:00 7/11/2012 8:00 132.9 7/13/2012 1:00 91.2

7/6/2012 6:00 29 7/7/2012 23:00 221.7 7/9/2012 16:00 17.7 7/11/2012 9:00 51.1 7/13/2012 2:00 103.9

7/6/2012 7:00 28.6 7/8/2012 0:00 11.9 7/9/2012 17:00 21.3 7/11/2012 10:00 9.8 7/13/2012 3:00 85.6

7/6/2012 8:00 10.8 7/8/2012 1:00 196.7 7/9/2012 18:00 463.1 7/11/2012 11:00 6.2 7/13/2012 4:00 74.1

7/6/2012 9:00 11.6 7/8/2012 2:00 276.3 7/9/2012 19:00 309.3 7/11/2012 12:00 4.6 7/13/2012 5:00 76.1

7/6/2012 10:00 15.6 7/8/2012 3:00 82.1 7/9/2012 20:00 347 7/11/2012 13:00 4.3 7/13/2012 6:00 85.6

7/6/2012 11:00 12.1 7/8/2012 4:00 86.3 7/9/2012 21:00 291.4 7/11/2012 14:00 4 7/13/2012 7:00 57.1

7/6/2012 12:00 6 7/8/2012 5:00 121.7 7/9/2012 22:00 150 7/11/2012 15:00 4 7/13/2012 8:00 35.3

7/6/2012 13:00 5 7/8/2012 6:00 53.6 7/9/2012 23:00 152.5 7/11/2012 16:00 4.1 7/13/2012 9:00 20.2

7/6/2012 14:00 4.6 7/8/2012 7:00 23.3 7/10/2012 0:00 171.3 7/11/2012 17:00 5.1 7/13/2012 10:00 16.2

7/6/2012 15:00 4.2 7/8/2012 8:00 34 7/10/2012 1:00 109.8 7/11/2012 18:00 5.6 7/13/2012 11:00 24.3

7/6/2012 16:00 4.3 7/8/2012 9:00 114.4 7/10/2012 2:00 106.1 7/11/2012 19:00 37.4 7/13/2012 12:00 11.8

7/6/2012 17:00 5.4 7/8/2012 10:00 28.1 7/10/2012 3:00 88.8 7/11/2012 20:00 100.1 7/13/2012 13:00 9.4

7/6/2012 18:00 19 7/8/2012 11:00 10.2 7/10/2012 4:00 63 7/11/2012 21:00 179.7 7/13/2012 14:00 11.9

7/6/2012 19:00 42 7/8/2012 12:00 7.1 7/10/2012 5:00 70.1 7/11/2012 22:00 171.5 7/13/2012 15:00 9.5

7/6/2012 20:00 42.9 7/8/2012 13:00 9.6 7/10/2012 6:00 85.8 7/11/2012 23:00 129.1 7/13/2012 16:00 9.6

7/6/2012 21:00 59.6 7/8/2012 14:00 8 7/10/2012 7:00 57.2 7/12/2012 0:00 116.4 7/13/2012 17:00 12.1

7/6/2012 22:00 54.5 7/8/2012 15:00 5.9 7/10/2012 8:00 49.1 7/12/2012 1:00 134.8 7/13/2012 18:00 22.1

7/6/2012 23:00 87.9 7/8/2012 16:00 5.7 7/10/2012 9:00 12.8 7/12/2012 2:00 123.2 7/13/2012 19:00 23.5

7/7/2012 0:00 114.5 7/8/2012 17:00 8.2 7/10/2012 10:00 9.8 7/12/2012 3:00 125 7/13/2012 20:00 19.9

7/7/2012 1:00 49.4 7/8/2012 18:00 18.4 7/10/2012 11:00 8.6 7/12/2012 4:00 132.9 7/13/2012 21:00 19.4

7/7/2012 2:00 72.6 7/8/2012 19:00 21.4 7/10/2012 12:00 5.7 7/12/2012 5:00 256.4 7/13/2012 22:00 24.4

7/7/2012 3:00 134.4 7/8/2012 20:00 29.2 7/10/2012 13:00 4.7 7/12/2012 6:00 598.8 7/13/2012 23:00 142.7

7/7/2012 4:00 47.7 7/8/2012 21:00 51.9 7/10/2012 14:00 7/12/2012 7:00 664.4 7/14/2012 0:00 132.5

7/7/2012 5:00 86.1 7/8/2012 22:00 79.8 7/10/2012 15:00 11.2 7/12/2012 8:00 358.4 7/14/2012 1:00 78.6

7/7/2012 6:00 76 7/8/2012 23:00 127.3 7/10/2012 16:00 180.1 7/12/2012 9:00 32.7 7/14/2012 2:00 116.3

7/7/2012 7:00 199.4 7/9/2012 0:00 136.7 7/10/2012 17:00 353.3 7/12/2012 10:00 14.6 7/14/2012 3:00 99.8

7/7/2012 8:00 156.6 7/9/2012 1:00 172.5 7/10/2012 18:00 286.6 7/12/2012 11:00 11.6 7/14/2012 4:00 56.9

7/7/2012 9:00 148.5 7/9/2012 2:00 179.4 7/10/2012 19:00 187.4 7/12/2012 12:00 6.2 7/14/2012 5:00 57.1

7/7/2012 10:00 66.7 7/9/2012 3:00 120.8 7/10/2012 20:00 195.3 7/12/2012 13:00 6.7 7/14/2012 6:00 61.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 40
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/14/2012 7:00 67.5 7/16/2012 0:00 233.4 7/17/2012 17:00 7.9 7/20/2012 10:00 13.6 7/23/2012 3:00 55.4

7/14/2012 8:00 60.3 7/16/2012 1:00 71.9 7/17/2012 18:00 6.8 7/20/2012 11:00 9.7 7/23/2012 4:00 31.5

7/14/2012 9:00 21.4 7/16/2012 2:00 108 7/17/2012 19:00 8 7/20/2012 12:00 5 7/23/2012 5:00 19.9

7/14/2012 10:00 14.1 7/16/2012 3:00 116.5 7/17/2012 20:00 13.4 7/20/2012 13:00 4.2 7/23/2012 6:00 18.5

7/14/2012 11:00 11.8 7/16/2012 4:00 26.5 7/17/2012 21:00 13.8 7/20/2012 14:00 4.2 7/23/2012 7:00 30.6

7/14/2012 12:00 5.7 7/16/2012 5:00 62.6 7/17/2012 22:00 20.5 7/20/2012 15:00 4.1 7/23/2012 8:00 48.2

7/14/2012 13:00 4.7 7/16/2012 6:00 48.7 7/17/2012 23:00 14.5 7/20/2012 16:00 4 7/23/2012 9:00 13.3

7/14/2012 14:00 4.6 7/16/2012 7:00 567.8 7/19/2012 0:00 15.4 7/20/2012 17:00 4.1 7/23/2012 10:00 6.8

7/14/2012 15:00 4.7 7/16/2012 8:00 64.9 7/19/2012 1:00 26.5 7/20/2012 18:00 3.9 7/23/2012 11:00 6.6

7/14/2012 16:00 5.4 7/16/2012 9:00 21.8 7/19/2012 2:00 50.8 7/20/2012 19:00 3.9 7/23/2012 12:00 4.4

7/14/2012 17:00 9 7/16/2012 10:00 15.2 7/19/2012 3:00 75 7/20/2012 20:00 4.5 7/23/2012 13:00 3.9

7/14/2012 18:00 48.6 7/16/2012 11:00 8.1 7/19/2012 4:00 77.1 7/20/2012 21:00 6.3 7/23/2012 14:00 3.8

7/14/2012 19:00 90.1 7/16/2012 12:00 7.7 7/19/2012 5:00 62.9 7/20/2012 22:00 7.1 7/23/2012 15:00

7/14/2012 20:00 86.3 7/16/2012 13:00 6 7/19/2012 6:00 54.4 7/20/2012 23:00 11.2 7/23/2012 16:00 4

7/14/2012 21:00 67.4 7/16/2012 14:00 6.5 7/19/2012 7:00 42.5 7/21/2012 0:00 24.6 7/23/2012 17:00 3.8

7/14/2012 22:00 77.5 7/16/2012 15:00 7/19/2012 8:00 48.8 7/21/2012 1:00 112.1 7/23/2012 18:00 4.1

7/14/2012 23:00 90.2 7/16/2012 16:00 8.4 7/19/2012 9:00 50.8 7/21/2012 2:00 126.9 7/23/2012 19:00 5.8

7/15/2012 0:00 68.4 7/16/2012 17:00 11 7/19/2012 10:00 64.6 7/21/2012 3:00 77.6 7/23/2012 20:00 106.9

7/15/2012 1:00 44.6 7/16/2012 18:00 12.3 7/19/2012 11:00 20.9 7/21/2012 4:00 72.3 7/23/2012 21:00 58.4

7/15/2012 2:00 52.6 7/16/2012 19:00 16.4 7/19/2012 12:00 13.3 7/21/2012 5:00 109.9 7/23/2012 22:00 30.2

7/15/2012 3:00 80.3 7/16/2012 20:00 13.5 7/19/2012 13:00 7.8 7/21/2012 6:00 67.8 7/23/2012 23:00 11.6

7/15/2012 4:00 53.1 7/16/2012 21:00 16.1 7/19/2012 14:00 6 7/21/2012 7:00 57.6 7/24/2012 0:00 23.8

7/15/2012 5:00 59.8 7/16/2012 22:00 25 7/19/2012 15:00 5.6 7/21/2012 8:00 108.6 7/24/2012 1:00 20.4

7/15/2012 6:00 135.7 7/16/2012 23:00 163.6 7/19/2012 16:00 4.9 7/21/2012 9:00 81.5 7/24/2012 2:00 20.2

7/15/2012 7:00 289.9 7/17/2012 0:00 113.1 7/19/2012 17:00 4.7 7/21/2012 10:00 22.9 7/24/2012 3:00 9.4

7/15/2012 8:00 78.8 7/17/2012 1:00 58.4 7/19/2012 18:00 4.8 7/21/2012 11:00 6 7/24/2012 4:00 27.7

7/15/2012 9:00 61.6 7/17/2012 2:00 66.8 7/19/2012 19:00 5 7/21/2012 12:00 4.9 7/24/2012 5:00 34.1

7/15/2012 10:00 26.4 7/17/2012 3:00 98.7 7/19/2012 20:00 5.7 7/21/2012 13:00 4.4 7/24/2012 6:00 87.6

7/15/2012 11:00 10.9 7/17/2012 4:00 110.6 7/19/2012 21:00 8.2 7/21/2012 14:00 4.4 7/24/2012 7:00 71.7

7/15/2012 12:00 10.6 7/17/2012 5:00 107.5 7/19/2012 22:00 9 7/21/2012 15:00 4.2 7/24/2012 8:00 44.1

7/15/2012 13:00 6.6 7/17/2012 6:00 103.3 7/19/2012 23:00 14.2 7/21/2012 16:00 4.2 7/24/2012 9:00 15.8

7/15/2012 14:00 6.8 7/17/2012 7:00 144.7 7/20/2012 0:00 24.6 7/21/2012 17:00 4.2 7/24/2012 10:00 6

7/15/2012 15:00 5.8 7/17/2012 8:00 120.3 7/20/2012 1:00 62.4 7/21/2012 18:00 4 7/24/2012 11:00 10.4

7/15/2012 16:00 5.4 7/17/2012 9:00 88.3 7/20/2012 2:00 84.6 7/21/2012 19:00 4 7/24/2012 12:00

7/15/2012 17:00 8.6 7/17/2012 10:00 15.5 7/20/2012 3:00 82.6 7/21/2012 20:00 16.1 7/24/2012 13:00 6.3

7/15/2012 18:00 18.9 7/17/2012 11:00 16.1 7/20/2012 4:00 106.7 7/21/2012 21:00 250 7/24/2012 14:00

7/15/2012 19:00 21.2 7/17/2012 12:00 12 7/20/2012 5:00 109.3 7/21/2012 22:00 165.8 7/24/2012 15:00 8.2

7/15/2012 20:00 179.8 7/17/2012 13:00 6.5 7/20/2012 6:00 99.4 7/21/2012 23:00 99.3 7/24/2012 16:00 6.8

7/15/2012 21:00 291.5 7/17/2012 14:00 7/20/2012 7:00 132.3 7/23/2012 0:00 16.4 7/24/2012 17:00 6.2

7/15/2012 22:00 614 7/17/2012 15:00 7.8 7/20/2012 8:00 103.9 7/23/2012 1:00 20.7 7/24/2012 18:00 8.3

7/15/2012 23:00 129.3 7/17/2012 16:00 6.7 7/20/2012 9:00 52.4 7/23/2012 2:00 52.4 7/24/2012 19:00 39.1

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 41
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/24/2012 20:00 54.7 7/26/2012 13:00 6 7/28/2012 6:00 103 7/29/2012 23:00 29.5 8/2/2012 16:00 4.1

7/24/2012 21:00 18.9 7/26/2012 14:00 7.9 7/28/2012 7:00 64.3 7/30/2012 0:00 28.3 8/2/2012 17:00 3.9

7/24/2012 22:00 15.8 7/26/2012 15:00 6.1 7/28/2012 8:00 44.1 7/30/2012 1:00 54.4 8/2/2012 18:00 3.9

7/24/2012 23:00 27.3 7/26/2012 16:00 5 7/28/2012 9:00 23.5 7/30/2012 2:00 61.9 8/2/2012 19:00 4.9

7/25/2012 0:00 41.6 7/26/2012 17:00 5.9 7/28/2012 10:00 9.5 7/30/2012 3:00 98.9 8/2/2012 20:00 5.4

7/25/2012 1:00 59.4 7/26/2012 18:00 13.6 7/28/2012 11:00 6.1 7/30/2012 4:00 77.5 8/2/2012 21:00 8.1

7/25/2012 2:00 87.5 7/26/2012 19:00 32.6 7/28/2012 12:00 4.6 7/30/2012 5:00 71.2 8/2/2012 22:00 9

7/25/2012 3:00 33.1 7/26/2012 20:00 163.5 7/28/2012 13:00 4.2 7/30/2012 6:00 59.7 8/2/2012 23:00 9.6

7/25/2012 4:00 17.9 7/26/2012 21:00 56.1 7/28/2012 14:00 4 7/30/2012 7:00 40.9 8/3/2012 0:00 19.5

7/25/2012 5:00 17.6 7/26/2012 22:00 70.1 7/28/2012 15:00 4.1 7/30/2012 8:00 24.9 8/3/2012 1:00 23.1

7/25/2012 6:00 41.4 7/26/2012 23:00 54.9 7/28/2012 16:00 4.1 7/30/2012 9:00 31.4 8/3/2012 2:00 19.8

7/25/2012 7:00 85.8 7/27/2012 0:00 50.2 7/28/2012 17:00 4.1 7/30/2012 10:00 8.3 8/3/2012 3:00 49.1

7/25/2012 8:00 609.1 7/27/2012 1:00 31.3 7/28/2012 18:00 4.8 7/30/2012 11:00 5.7 8/3/2012 4:00 36.4

7/25/2012 9:00 297.1 7/27/2012 2:00 21.8 7/28/2012 19:00 5.2 7/30/2012 12:00 5 8/3/2012 5:00 31

7/25/2012 10:00 14.4 7/27/2012 3:00 16.6 7/28/2012 20:00 11.7 7/30/2012 13:00 4.8 8/3/2012 6:00 78.2

7/25/2012 11:00 11.1 7/27/2012 4:00 11.5 7/28/2012 21:00 92.1 7/30/2012 14:00 4.4 8/3/2012 7:00 65.1

7/25/2012 12:00 6.3 7/27/2012 5:00 19 7/28/2012 22:00 54.8 7/30/2012 15:00 8/3/2012 8:00 26.4

7/25/2012 13:00 5 7/27/2012 6:00 72.7 7/28/2012 23:00 34.6 7/30/2012 16:00 4.3 8/3/2012 9:00 13

7/25/2012 14:00 4.5 7/27/2012 7:00 25.8 7/29/2012 0:00 28.4 7/30/2012 17:00 4.4 8/3/2012 10:00 7.4

7/25/2012 15:00 4.5 7/27/2012 8:00 7.6 7/29/2012 1:00 25.2 7/30/2012 18:00 8.9 8/3/2012 11:00 10.6

7/25/2012 16:00 5.3 7/27/2012 9:00 12.4 7/29/2012 2:00 23.2 7/30/2012 19:00 6.9 8/3/2012 12:00 6.5

7/25/2012 17:00 7/27/2012 10:00 9.4 7/29/2012 3:00 17.9 7/30/2012 20:00 5.9 8/3/2012 13:00 4.8

7/25/2012 18:00 49.8 7/27/2012 11:00 4.8 7/29/2012 4:00 14.3 7/30/2012 21:00 5.4 8/3/2012 14:00 4.7

7/25/2012 19:00 133.1 7/27/2012 12:00 4.3 7/29/2012 5:00 20.5 7/30/2012 22:00 6.8 8/3/2012 15:00 4

7/25/2012 20:00 74.6 7/27/2012 13:00 4.1 7/29/2012 6:00 42.1 7/30/2012 23:00 6.1 8/3/2012 16:00 3.8

7/25/2012 21:00 53.4 7/27/2012 14:00 3.9 7/29/2012 7:00 203.6 8/2/2012 0:00 12.4 8/3/2012 17:00 3.7

7/25/2012 22:00 26.4 7/27/2012 15:00 3.8 7/29/2012 8:00 243.4 8/2/2012 1:00 24.8 8/3/2012 18:00 3.7

7/25/2012 23:00 22.1 7/27/2012 16:00 3.7 7/29/2012 9:00 74.5 8/2/2012 2:00 71.9 8/3/2012 19:00 3.8

7/26/2012 0:00 13.5 7/27/2012 17:00 7.6 7/29/2012 10:00 15.8 8/2/2012 3:00 26.8 8/3/2012 20:00 4.1

7/26/2012 1:00 7.6 7/27/2012 18:00 13.4 7/29/2012 11:00 7.3 8/2/2012 4:00 18.5 8/3/2012 21:00 10.3

7/26/2012 2:00 9.4 7/27/2012 19:00 15 7/29/2012 12:00 5.3 8/2/2012 5:00 50.7 8/3/2012 22:00 11.2

7/26/2012 3:00 7.7 7/27/2012 20:00 45.5 7/29/2012 13:00 4.9 8/2/2012 6:00 103.5 8/3/2012 23:00 32.9

7/26/2012 4:00 8.6 7/27/2012 21:00 89.9 7/29/2012 14:00 4.4 8/2/2012 7:00 95 8/4/2012 0:00 43.5

7/26/2012 5:00 4.5 7/27/2012 22:00 69.2 7/29/2012 15:00 4.2 8/2/2012 8:00 90.4 8/4/2012 1:00 35.5

7/26/2012 6:00 29.6 7/27/2012 23:00 59.2 7/29/2012 16:00 4.3 8/2/2012 9:00 60.6 8/4/2012 2:00 57.3

7/26/2012 7:00 69.9 7/28/2012 0:00 49.3 7/29/2012 17:00 4.7 8/2/2012 10:00 12.6 8/4/2012 3:00 50.4

7/26/2012 8:00 5.6 7/28/2012 1:00 105.3 7/29/2012 18:00 6.5 8/2/2012 11:00 7.5 8/4/2012 4:00 49.8

7/26/2012 9:00 6.9 7/28/2012 2:00 105.6 7/29/2012 19:00 19.2 8/2/2012 12:00 6.1 8/4/2012 5:00 60

7/26/2012 10:00 26 7/28/2012 3:00 87.2 7/29/2012 20:00 36.8 8/2/2012 13:00 4.5 8/4/2012 6:00 35.4

7/26/2012 11:00 12.9 7/28/2012 4:00 67.9 7/29/2012 21:00 23.2 8/2/2012 14:00 4.2 8/4/2012 7:00 37.9

7/26/2012 12:00 13.5 7/28/2012 5:00 110.8 7/29/2012 22:00 26.2 8/2/2012 15:00 4.6 8/4/2012 8:00 127

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 42
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

8/4/2012 9:00 37.3 8/8/2012 2:00 62.6 8/9/2012 19:00 21.9 8/14/2012 12:00 12.2 8/16/2012 5:00 48.5

8/4/2012 10:00 16.3 8/8/2012 3:00 97.5 8/9/2012 20:00 7.4 8/14/2012 13:00 7.6 8/16/2012 6:00 121.3

8/4/2012 11:00 16.2 8/8/2012 4:00 120.7 8/9/2012 21:00 14.2 8/14/2012 14:00 8/16/2012 7:00 67.3

8/4/2012 12:00 8.1 8/8/2012 5:00 32.6 8/9/2012 22:00 29.7 8/14/2012 15:00 9.3 8/16/2012 8:00 80.8

8/4/2012 13:00 4.9 8/8/2012 6:00 42.3 8/9/2012 23:00 23.8 8/14/2012 16:00 8.9 8/16/2012 9:00 133

8/4/2012 14:00 4.4 8/8/2012 7:00 99.5 8/11/2012 0:00 29.9 8/14/2012 17:00 14.2 8/16/2012 10:00 13.9

8/4/2012 15:00 4.1 8/8/2012 8:00 249.7 8/11/2012 1:00 55.1 8/14/2012 18:00 26.6 8/16/2012 11:00 7.3

8/4/2012 16:00 4 8/8/2012 9:00 46.1 8/11/2012 2:00 66.6 8/14/2012 19:00 40.8 8/16/2012 12:00 5.5

8/4/2012 17:00 4 8/8/2012 10:00 21.6 8/11/2012 3:00 61.4 8/14/2012 20:00 45.7 8/16/2012 13:00 4.7

8/4/2012 18:00 3.8 8/8/2012 11:00 13.3 8/11/2012 4:00 72.2 8/14/2012 21:00 54.2 8/16/2012 14:00 4.7

8/4/2012 19:00 3.8 8/8/2012 12:00 7.2 8/11/2012 5:00 61.3 8/14/2012 22:00 63.3 8/16/2012 15:00 5

8/4/2012 20:00 4.2 8/8/2012 13:00 6.2 8/11/2012 6:00 105.9 8/14/2012 23:00 75.6 8/16/2012 16:00 4.7

8/4/2012 21:00 13.3 8/8/2012 14:00 4.9 8/11/2012 7:00 165 8/15/2012 0:00 60.4 8/16/2012 17:00 6.9

8/4/2012 22:00 30.5 8/8/2012 15:00 4.8 8/11/2012 8:00 179.3 8/15/2012 1:00 72.7 8/16/2012 18:00 22.5

8/4/2012 23:00 24.1 8/8/2012 16:00 4.3 8/11/2012 9:00 44.7 8/15/2012 2:00 65.4 8/16/2012 19:00 21

8/5/2012 0:00 62.9 8/8/2012 17:00 8/11/2012 10:00 15.2 8/15/2012 3:00 70.3 8/16/2012 20:00 57.6

8/5/2012 1:00 71.6 8/8/2012 18:00 6.3 8/11/2012 11:00 9.8 8/15/2012 4:00 67.2 8/16/2012 21:00 130.3

8/5/2012 2:00 47.2 8/8/2012 19:00 29.6 8/11/2012 12:00 9.6 8/15/2012 5:00 80.5 8/16/2012 22:00 140.3

8/5/2012 3:00 20.9 8/8/2012 20:00 33.7 8/11/2012 13:00 6.3 8/15/2012 6:00 71.2 8/16/2012 23:00 88.3

8/5/2012 4:00 136 8/8/2012 21:00 17.4 8/11/2012 14:00 4.8 8/15/2012 7:00 102.7 8/17/2012 0:00 27

8/5/2012 5:00 162.3 8/8/2012 22:00 17 8/11/2012 15:00 4.3 8/15/2012 8:00 104.4 8/17/2012 1:00 14.5

8/5/2012 6:00 129.9 8/8/2012 23:00 50.6 8/11/2012 16:00 4 8/15/2012 9:00 55.2 8/17/2012 2:00 26.1

8/5/2012 7:00 125.3 8/9/2012 0:00 126.1 8/11/2012 17:00 4.3 8/15/2012 10:00 7.5 8/17/2012 3:00 45.9

8/5/2012 8:00 76.1 8/9/2012 1:00 107.8 8/11/2012 18:00 4.8 8/15/2012 11:00 8.2 8/17/2012 4:00 92.1

8/5/2012 9:00 15.5 8/9/2012 2:00 336.8 8/11/2012 19:00 4.6 8/15/2012 12:00 5.3 8/17/2012 5:00 228.9

8/5/2012 10:00 8.7 8/9/2012 3:00 367.7 8/11/2012 20:00 5.3 8/15/2012 13:00 4.5 8/17/2012 6:00 314.2

8/5/2012 11:00 5.6 8/9/2012 4:00 216.2 8/11/2012 21:00 9.1 8/15/2012 14:00 4.2 8/17/2012 7:00 359.2

8/5/2012 12:00 4.6 8/9/2012 5:00 220.1 8/11/2012 22:00 87.9 8/15/2012 15:00 4.2 8/17/2012 8:00 171.2

8/5/2012 13:00 4.3 8/9/2012 6:00 235.9 8/11/2012 23:00 112.7 8/15/2012 16:00 4 8/17/2012 9:00 106

8/5/2012 14:00 4.1 8/9/2012 7:00 112.4 8/14/2012 0:00 13.9 8/15/2012 17:00 4.7 8/17/2012 10:00 19.8

8/5/2012 15:00 4 8/9/2012 8:00 57.4 8/14/2012 1:00 10.7 8/15/2012 18:00 11.5 8/17/2012 11:00 8.4

8/5/2012 16:00 4 8/9/2012 9:00 24.3 8/14/2012 2:00 8.7 8/15/2012 19:00 20.8 8/17/2012 12:00 5.7

8/5/2012 17:00 3.9 8/9/2012 10:00 15.8 8/14/2012 3:00 9.2 8/15/2012 20:00 42.7 8/17/2012 13:00 4.9

8/5/2012 18:00 3.8 8/9/2012 11:00 7.8 8/14/2012 4:00 11.5 8/15/2012 21:00 48.2 8/17/2012 14:00 4.3

8/5/2012 19:00 3.9 8/9/2012 12:00 6.1 8/14/2012 5:00 10.2 8/15/2012 22:00 23.5 8/17/2012 15:00 4.2

8/5/2012 20:00 5.2 8/9/2012 13:00 4.6 8/14/2012 6:00 18.4 8/15/2012 23:00 76.4 8/17/2012 16:00 4.3

8/5/2012 21:00 6.6 8/9/2012 14:00 4.4 8/14/2012 7:00 23.5 8/16/2012 0:00 422.5 8/17/2012 17:00 4.7

8/5/2012 22:00 10.3 8/9/2012 15:00 5 8/14/2012 8:00 102.1 8/16/2012 1:00 307.9 8/17/2012 18:00 9.1

8/5/2012 23:00 29.8 8/9/2012 16:00 4.4 8/14/2012 9:00 153.2 8/16/2012 2:00 79.3 8/17/2012 19:00 18.8

8/8/2012 0:00 27.2 8/9/2012 17:00 5.1 8/14/2012 10:00 121.6 8/16/2012 3:00 45.6 8/17/2012 20:00 15.7

8/8/2012 1:00 55.3 8/9/2012 18:00 7.1 8/14/2012 11:00 16.1 8/16/2012 4:00 59.3 8/17/2012 21:00 18.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 43
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

8/17/2012 22:00 27.9 8/23/2012 15:00 4.6 8/25/2012 8:00 14.9 8/27/2012 1:00 28.8 8/29/2012 18:00 5.4

8/17/2012 23:00 26.9 8/23/2012 16:00 4.1 8/25/2012 9:00 59.7 8/27/2012 2:00 22.7 8/29/2012 19:00 12.1

8/18/2012 0:00 24.9 8/23/2012 17:00 4 8/25/2012 10:00 80.9 8/27/2012 3:00 64.6 8/29/2012 20:00 11.3

8/18/2012 1:00 66.4 8/23/2012 18:00 3.9 8/25/2012 11:00 93.5 8/27/2012 4:00 70.8 8/29/2012 21:00 68.1

8/18/2012 2:00 90.9 8/23/2012 19:00 3.8 8/25/2012 12:00 12.5 8/27/2012 5:00 55.6 8/29/2012 22:00 106.9

8/18/2012 3:00 82.9 8/23/2012 20:00 5.8 8/25/2012 13:00 6.4 8/27/2012 6:00 76.4 8/29/2012 23:00 77.6

8/18/2012 4:00 74 8/23/2012 21:00 6.9 8/25/2012 14:00 5.5 8/27/2012 7:00 80.1 8/30/2012 0:00 58.3

8/18/2012 5:00 42.8 8/23/2012 22:00 32.9 8/25/2012 15:00 4.9 8/27/2012 8:00 39.3 8/30/2012 1:00 28.9

8/18/2012 6:00 64.1 8/23/2012 23:00 106 8/25/2012 16:00 15.8 8/27/2012 9:00 22.2 8/30/2012 2:00 24.6

8/18/2012 7:00 60.2 8/24/2012 0:00 269.8 8/25/2012 17:00 58.5 8/27/2012 10:00 10.1 8/30/2012 3:00 54.3

8/18/2012 8:00 72.6 8/24/2012 1:00 422.3 8/25/2012 18:00 83.8 8/27/2012 11:00 6.5 8/30/2012 4:00 42.7

8/18/2012 9:00 30 8/24/2012 2:00 190.8 8/25/2012 19:00 124.3 8/27/2012 12:00 4.7 8/30/2012 5:00 33.6

8/18/2012 10:00 28.6 8/24/2012 3:00 162.6 8/25/2012 20:00 51.3 8/27/2012 13:00 4.2 8/30/2012 6:00 61.6

8/18/2012 11:00 9 8/24/2012 4:00 159.5 8/25/2012 21:00 21.5 8/27/2012 14:00 4.1 8/30/2012 7:00 75.6

8/18/2012 12:00 7.3 8/24/2012 5:00 340.1 8/25/2012 22:00 11 8/27/2012 15:00 8/30/2012 8:00 21.1

8/18/2012 13:00 6.9 8/24/2012 6:00 236.6 8/25/2012 23:00 6.1 8/27/2012 16:00 5.2 8/30/2012 9:00 10

8/18/2012 14:00 5.4 8/24/2012 7:00 87.7 8/26/2012 0:00 6 8/27/2012 17:00 4.9 8/30/2012 10:00 7.7

8/18/2012 15:00 5.7 8/24/2012 8:00 32.4 8/26/2012 1:00 11.7 8/27/2012 18:00 8.3 8/30/2012 11:00 5.8

8/18/2012 16:00 4.8 8/24/2012 9:00 13.3 8/26/2012 2:00 92.1 8/27/2012 19:00 31.4 8/30/2012 12:00 5

8/18/2012 17:00 4.7 8/24/2012 10:00 7.4 8/26/2012 3:00 93.8 8/27/2012 20:00 28.6 8/30/2012 13:00 4.7

8/18/2012 18:00 9.1 8/24/2012 11:00 5.5 8/26/2012 4:00 80.7 8/27/2012 21:00 21.9 8/30/2012 14:00 4.2

8/18/2012 19:00 55.6 8/24/2012 12:00 4.8 8/26/2012 5:00 106 8/27/2012 22:00 20.2 8/30/2012 15:00 5.1

8/18/2012 20:00 91.4 8/24/2012 13:00 4.4 8/26/2012 6:00 52.6 8/27/2012 23:00 50.7 8/30/2012 16:00 4.3

8/18/2012 21:00 63.9 8/24/2012 14:00 4.1 8/26/2012 7:00 248.6 8/29/2012 0:00 13.2 8/30/2012 17:00 9.6

8/18/2012 22:00 37 8/24/2012 15:00 4 8/26/2012 8:00 110.9 8/29/2012 1:00 13.1 8/30/2012 18:00 28.4

8/18/2012 23:00 23.9 8/24/2012 16:00 4.1 8/26/2012 9:00 89.1 8/29/2012 2:00 13.3 8/30/2012 19:00 16.9

8/23/2012 0:00 37 8/24/2012 17:00 4.4 8/26/2012 10:00 6.6 8/29/2012 3:00 13.2 8/30/2012 20:00 185.5

8/23/2012 1:00 23.5 8/24/2012 18:00 5.4 8/26/2012 11:00 7.8 8/29/2012 4:00 17.8 8/30/2012 21:00 143.6

8/23/2012 2:00 43.7 8/24/2012 19:00 6.8 8/26/2012 12:00 13.6 8/29/2012 5:00 16.6 8/30/2012 22:00 42.5

8/23/2012 3:00 37.3 8/24/2012 20:00 8.4 8/26/2012 13:00 7.9 8/29/2012 6:00 17.9 8/30/2012 23:00 24.9

8/23/2012 4:00 37.5 8/24/2012 21:00 36.5 8/26/2012 14:00 4.9 8/29/2012 7:00 29.7 8/31/2012 0:00 19.6

8/23/2012 5:00 61.6 8/24/2012 22:00 138.6 8/26/2012 15:00 4.8 8/29/2012 8:00 15.2 8/31/2012 1:00 18.4

8/23/2012 6:00 38.4 8/24/2012 23:00 175.1 8/26/2012 16:00 5.2 8/29/2012 9:00 6.3 8/31/2012 2:00 32.9

8/23/2012 7:00 81.4 8/25/2012 0:00 60.5 8/26/2012 17:00 8.7 8/29/2012 10:00 5.8 8/31/2012 3:00 33.1

8/23/2012 8:00 43.6 8/25/2012 1:00 19.2 8/26/2012 18:00 108.7 8/29/2012 11:00 5.7 8/31/2012 4:00 70.4

8/23/2012 9:00 17.8 8/25/2012 2:00 10.4 8/26/2012 19:00 63.1 8/29/2012 12:00 4.3 8/31/2012 5:00 21.3

8/23/2012 10:00 6.5 8/25/2012 3:00 8.2 8/26/2012 20:00 32.2 8/29/2012 13:00 4.1 8/31/2012 6:00 19.3

8/23/2012 11:00 4.6 8/25/2012 4:00 52.5 8/26/2012 21:00 28.9 8/29/2012 14:00 3.9 8/31/2012 7:00 17

8/23/2012 12:00 4.1 8/25/2012 5:00 17 8/26/2012 22:00 13.7 8/29/2012 15:00 3.8 8/31/2012 8:00 21.8

8/23/2012 13:00 4.1 8/25/2012 6:00 5.8 8/26/2012 23:00 12.4 8/29/2012 16:00 3.8 8/31/2012 9:00 18.4

8/23/2012 14:00 4 8/25/2012 7:00 13.7 8/27/2012 0:00 27.7 8/29/2012 17:00 3.8 8/31/2012 10:00 12.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 44
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

8/31/2012 11:00 8.5 9/2/2012 4:00 117.1 9/3/2012 21:00 46.1 9/5/2012 14:00 4.6 9/7/2012 7:00 101.7

8/31/2012 12:00 5.9 9/2/2012 5:00 10.9 9/3/2012 22:00 95.7 9/5/2012 15:00 5 9/7/2012 8:00 38.2

8/31/2012 13:00 4.6 9/2/2012 6:00 8.7 9/3/2012 23:00 64.1 9/5/2012 16:00 5.8 9/7/2012 9:00 16.3

8/31/2012 14:00 4.5 9/2/2012 7:00 15.2 9/4/2012 0:00 78.7 9/5/2012 17:00 9.7 9/7/2012 10:00 13.1

8/31/2012 15:00 10.7 9/2/2012 8:00 118.7 9/4/2012 1:00 61 9/5/2012 18:00 8.3 9/7/2012 11:00 7.7

8/31/2012 16:00 6.3 9/2/2012 9:00 159.9 9/4/2012 2:00 16.1 9/5/2012 19:00 6.2 9/7/2012 12:00 5

8/31/2012 17:00 6.7 9/2/2012 10:00 10.6 9/4/2012 3:00 18.2 9/5/2012 20:00 38.8 9/7/2012 13:00 4.5

8/31/2012 18:00 103.9 9/2/2012 11:00 6.9 9/4/2012 4:00 21.1 9/5/2012 21:00 129.9 9/7/2012 14:00 4.2

8/31/2012 19:00 305.2 9/2/2012 12:00 6.3 9/4/2012 5:00 16.6 9/5/2012 22:00 252.1 9/7/2012 15:00 4.3

8/31/2012 20:00 115.4 9/2/2012 13:00 6.4 9/4/2012 6:00 28.5 9/5/2012 23:00 266.1 9/7/2012 16:00 4.2

8/31/2012 21:00 71.9 9/2/2012 14:00 6.8 9/4/2012 7:00 59.8 9/6/2012 0:00 232.8 9/7/2012 17:00 4.2

8/31/2012 22:00 43.3 9/2/2012 15:00 6.3 9/4/2012 8:00 43.1 9/6/2012 1:00 208.2 9/7/2012 18:00 8.9

8/31/2012 23:00 28 9/2/2012 16:00 8.8 9/4/2012 9:00 8.8 9/6/2012 2:00 240.8 9/7/2012 19:00 12.3

9/1/2012 0:00 29.4 9/2/2012 17:00 232 9/4/2012 10:00 11.6 9/6/2012 3:00 176.6 9/7/2012 20:00 20.1

9/1/2012 1:00 59.2 9/2/2012 18:00 352.3 9/4/2012 11:00 10 9/6/2012 4:00 94.8 9/7/2012 21:00 22.8

9/1/2012 2:00 66.2 9/2/2012 19:00 69 9/4/2012 12:00 6.8 9/6/2012 5:00 281.3 9/7/2012 22:00 28

9/1/2012 3:00 63.4 9/2/2012 20:00 225.8 9/4/2012 13:00 5.6 9/6/2012 6:00 263.5 9/7/2012 23:00 12.5

9/1/2012 4:00 40.1 9/2/2012 21:00 147.1 9/4/2012 14:00 9/6/2012 7:00 72.3 9/8/2012 0:00 16.7

9/1/2012 5:00 16.6 9/2/2012 22:00 47 9/4/2012 15:00 7.3 9/6/2012 8:00 182.2 9/8/2012 1:00 23.9

9/1/2012 6:00 9.8 9/2/2012 23:00 16.3 9/4/2012 16:00 4.9 9/6/2012 9:00 38.6 9/8/2012 2:00 30.6

9/1/2012 7:00 20 9/3/2012 0:00 20.2 9/4/2012 17:00 4.6 9/6/2012 10:00 11.5 9/8/2012 3:00 27.4

9/1/2012 8:00 88.8 9/3/2012 1:00 153.5 9/4/2012 18:00 4.6 9/6/2012 11:00 9.7 9/8/2012 4:00 75

9/1/2012 9:00 12.9 9/3/2012 2:00 358.5 9/4/2012 19:00 5.7 9/6/2012 12:00 5.5 9/8/2012 5:00 97

9/1/2012 10:00 8.5 9/3/2012 3:00 33.1 9/4/2012 20:00 21.9 9/6/2012 13:00 5 9/8/2012 6:00 75

9/1/2012 11:00 6.6 9/3/2012 4:00 185.2 9/4/2012 21:00 29.3 9/6/2012 14:00 4.5 9/8/2012 7:00 139

9/1/2012 12:00 11.6 9/3/2012 5:00 67.4 9/4/2012 22:00 39 9/6/2012 15:00 5.2 9/8/2012 8:00 92

9/1/2012 13:00 8 9/3/2012 6:00 289.6 9/4/2012 23:00 44.1 9/6/2012 16:00 4.6 9/8/2012 9:00 30

9/1/2012 14:00 8.8 9/3/2012 7:00 934.9 9/5/2012 0:00 80.2 9/6/2012 17:00 4.4 9/8/2012 10:00 9.9

9/1/2012 15:00 9.6 9/3/2012 8:00 217.9 9/5/2012 1:00 52.3 9/6/2012 18:00 5.3 9/8/2012 11:00 6.7

9/1/2012 16:00 5.2 9/3/2012 9:00 17.2 9/5/2012 2:00 21.2 9/6/2012 19:00 8.9 9/8/2012 12:00 4.9

9/1/2012 17:00 5.9 9/3/2012 10:00 17.2 9/5/2012 3:00 76 9/6/2012 20:00 11.1 9/8/2012 13:00 4.5

9/1/2012 18:00 6.9 9/3/2012 11:00 13.2 9/5/2012 4:00 77.5 9/6/2012 21:00 14.4 9/8/2012 14:00 4.3

9/1/2012 19:00 28.1 9/3/2012 12:00 7.4 9/5/2012 5:00 42.8 9/6/2012 22:00 22.3 9/8/2012 15:00 4.2

9/1/2012 20:00 53.6 9/3/2012 13:00 5.5 9/5/2012 6:00 30.9 9/6/2012 23:00 42.8 9/8/2012 16:00 4.1

9/1/2012 21:00 231.9 9/3/2012 14:00 4.7 9/5/2012 7:00 39.3 9/7/2012 0:00 41.6 9/8/2012 17:00 4.2

9/1/2012 22:00 57.3 9/3/2012 15:00 9/5/2012 8:00 17 9/7/2012 1:00 42.5 9/8/2012 18:00 4.5

9/1/2012 23:00 53.1 9/3/2012 16:00 5.4 9/5/2012 9:00 15.9 9/7/2012 2:00 72.6 9/8/2012 19:00 14

9/2/2012 0:00 16.3 9/3/2012 17:00 6.6 9/5/2012 10:00 12.3 9/7/2012 3:00 208.5 9/8/2012 20:00 31

9/2/2012 1:00 62.5 9/3/2012 18:00 7 9/5/2012 11:00 7.2 9/7/2012 4:00 245.3 9/8/2012 21:00 96.2

9/2/2012 2:00 50.1 9/3/2012 19:00 81 9/5/2012 12:00 4.9 9/7/2012 5:00 121 9/8/2012 22:00 36.9

9/2/2012 3:00 28.6 9/3/2012 20:00 203 9/5/2012 13:00 4.6 9/7/2012 6:00 203.3 9/8/2012 23:00 16.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 45
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

9/9/2012 0:00 26.5 9/10/2012 17:00 17.6 9/12/2012 10:00 9.8 9/14/2012 3:00 19.3 9/15/2012 20:00 20.1

9/9/2012 1:00 160.3 9/10/2012 18:00 25 9/12/2012 11:00 11.2 9/14/2012 4:00 34.3 9/15/2012 21:00 18.2

9/9/2012 2:00 309.4 9/10/2012 19:00 373 9/12/2012 12:00 7.7 9/14/2012 5:00 164.7 9/15/2012 22:00 21.4

9/9/2012 3:00 74.8 9/10/2012 20:00 34 9/12/2012 13:00 4.9 9/14/2012 6:00 185.7 9/15/2012 23:00 62.3

9/9/2012 4:00 49.9 9/10/2012 21:00 624.4 9/12/2012 14:00 4.7 9/14/2012 7:00 167.1 9/17/2012 0:00 63.2

9/9/2012 5:00 36.8 9/10/2012 22:00 256.7 9/12/2012 15:00 5.9 9/14/2012 8:00 77.9 9/17/2012 1:00 53.2

9/9/2012 6:00 40.7 9/10/2012 23:00 32.6 9/12/2012 16:00 9.2 9/14/2012 9:00 7.1 9/17/2012 2:00 74.6

9/9/2012 7:00 51.7 9/11/2012 0:00 132.6 9/12/2012 17:00 16.6 9/14/2012 10:00 9.9 9/17/2012 3:00 72.1

9/9/2012 8:00 153.3 9/11/2012 1:00 31.7 9/12/2012 18:00 237.9 9/14/2012 11:00 10.8 9/17/2012 4:00 33.3

9/9/2012 9:00 69 9/11/2012 2:00 51.9 9/12/2012 19:00 277.4 9/14/2012 12:00 4.9 9/17/2012 5:00 14.1

9/9/2012 10:00 15.5 9/11/2012 3:00 23.2 9/12/2012 20:00 22.6 9/14/2012 13:00 4.6 9/17/2012 6:00 26.8

9/9/2012 11:00 12.4 9/11/2012 4:00 105 9/12/2012 21:00 49 9/14/2012 14:00 4.2 9/17/2012 7:00 13.5

9/9/2012 12:00 9.9 9/11/2012 5:00 165.3 9/12/2012 22:00 171.4 9/14/2012 15:00 4.2 9/17/2012 8:00 14.8

9/9/2012 13:00 5.4 9/11/2012 6:00 47.1 9/12/2012 23:00 104.4 9/14/2012 16:00 4.3 9/17/2012 9:00 21

9/9/2012 14:00 4.8 9/11/2012 7:00 20 9/13/2012 0:00 93 9/14/2012 17:00 5.9 9/17/2012 10:00 11.4

9/9/2012 15:00 4.5 9/11/2012 8:00 264.1 9/13/2012 1:00 54.5 9/14/2012 18:00 4.6 9/17/2012 11:00 11.8

9/9/2012 16:00 37.3 9/11/2012 9:00 70 9/13/2012 2:00 52.3 9/14/2012 19:00 6.7 9/17/2012 12:00 5.7

9/9/2012 17:00 7.1 9/11/2012 10:00 13.2 9/13/2012 3:00 98.8 9/14/2012 20:00 79.5 9/17/2012 13:00 4.5

9/9/2012 18:00 22.2 9/11/2012 11:00 7.6 9/13/2012 4:00 91.1 9/14/2012 21:00 141.2 9/17/2012 14:00 4.2

9/9/2012 19:00 38.4 9/11/2012 12:00 5.6 9/13/2012 5:00 100.1 9/14/2012 22:00 96.4 9/17/2012 15:00

9/9/2012 20:00 11.6 9/11/2012 13:00 4.9 9/13/2012 6:00 213.4 9/14/2012 23:00 35.9 9/17/2012 16:00 6.3

9/9/2012 21:00 10.3 9/11/2012 14:00 9/13/2012 7:00 194 9/15/2012 0:00 29.2 9/17/2012 17:00 7.3

9/9/2012 22:00 12.6 9/11/2012 15:00 10.1 9/13/2012 8:00 555.4 9/15/2012 1:00 112.7 9/17/2012 18:00 15.4

9/9/2012 23:00 13.7 9/11/2012 16:00 8.4 9/13/2012 9:00 28.2 9/15/2012 2:00 226 9/17/2012 19:00 170.6

9/10/2012 0:00 6.3 9/11/2012 17:00 35.2 9/13/2012 10:00 20.5 9/15/2012 3:00 126.5 9/17/2012 20:00 218.2

9/10/2012 1:00 5.8 9/11/2012 18:00 373 9/13/2012 11:00 11.4 9/15/2012 4:00 92.2 9/17/2012 21:00 50.2

9/10/2012 2:00 38.1 9/11/2012 19:00 363.8 9/13/2012 12:00 8.3 9/15/2012 5:00 61.9 9/17/2012 22:00 27.8

9/10/2012 3:00 10.2 9/11/2012 20:00 213.6 9/13/2012 13:00 8 9/15/2012 6:00 90.2 9/17/2012 23:00 42.5

9/10/2012 4:00 22 9/11/2012 21:00 114.3 9/13/2012 14:00 10.6 9/15/2012 7:00 138.7 9/18/2012 0:00 21.9

9/10/2012 5:00 17.5 9/11/2012 22:00 69.6 9/13/2012 15:00 8.3 9/15/2012 8:00 101.8 9/18/2012 1:00 11.7

9/10/2012 6:00 5.6 9/11/2012 23:00 16.6 9/13/2012 16:00 6.3 9/15/2012 9:00 31.8 9/18/2012 2:00 12.4

9/10/2012 7:00 20.2 9/12/2012 0:00 16.2 9/13/2012 17:00 14.6 9/15/2012 10:00 17.7 9/18/2012 3:00 7.2

9/10/2012 8:00 319 9/12/2012 1:00 54.4 9/13/2012 18:00 58.5 9/15/2012 11:00 5.6 9/18/2012 4:00 12

9/10/2012 9:00 139.8 9/12/2012 2:00 47.8 9/13/2012 19:00 427.8 9/15/2012 12:00 5.2 9/18/2012 5:00 32.2

9/10/2012 10:00 11.3 9/12/2012 3:00 22.2 9/13/2012 20:00 61.4 9/15/2012 13:00 4.9 9/18/2012 6:00 31.2

9/10/2012 11:00 7.7 9/12/2012 4:00 157.7 9/13/2012 21:00 42.8 9/15/2012 14:00 4.4 9/18/2012 7:00 17.8

9/10/2012 12:00 13.4 9/12/2012 5:00 17.4 9/13/2012 22:00 68.2 9/15/2012 15:00 4.2 9/18/2012 8:00 21

9/10/2012 13:00 8.3 9/12/2012 6:00 173 9/13/2012 23:00 143.9 9/15/2012 16:00 4.3 9/18/2012 9:00 20

9/10/2012 14:00 13.1 9/12/2012 7:00 216.3 9/14/2012 0:00 87.1 9/15/2012 17:00 4.2 9/18/2012 10:00 7.9

9/10/2012 15:00 9/12/2012 8:00 124.3 9/14/2012 1:00 94.6 9/15/2012 18:00 5.2 9/18/2012 11:00 5.3

9/10/2012 16:00 6.5 9/12/2012 9:00 18.4 9/14/2012 2:00 43.3 9/15/2012 19:00 15.7 9/18/2012 12:00 4.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 46
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

9/18/2012 13:00 4.2 9/22/2012 6:00 44.8 9/23/2012 23:00 641.1 9/25/2012 16:00 5.3 9/28/2012 9:00 22.7

9/18/2012 14:00 9/22/2012 7:00 39.6 9/24/2012 0:00 74.2 9/25/2012 17:00 5.4 9/28/2012 10:00 11.4

9/18/2012 15:00 6.9 9/22/2012 8:00 76.7 9/24/2012 1:00 45.8 9/25/2012 18:00 9.3 9/28/2012 11:00 7.9

9/18/2012 16:00 4.9 9/22/2012 9:00 55 9/24/2012 2:00 148.9 9/25/2012 19:00 25.7 9/28/2012 12:00 5.9

9/18/2012 17:00 4.3 9/22/2012 10:00 16.7 9/24/2012 3:00 144.6 9/25/2012 20:00 21.4 9/28/2012 13:00 7

9/18/2012 18:00 4.4 9/22/2012 11:00 10.7 9/24/2012 4:00 255.8 9/25/2012 21:00 22.7 9/28/2012 14:00 7.4

9/18/2012 19:00 5.5 9/22/2012 12:00 9/24/2012 5:00 75.7 9/25/2012 22:00 39.1 9/28/2012 15:00 7.3

9/18/2012 20:00 7.9 9/22/2012 13:00 6.9 9/24/2012 6:00 21.1 9/25/2012 23:00 61 9/28/2012 16:00 8.1

9/18/2012 21:00 72.1 9/22/2012 14:00 5.3 9/24/2012 7:00 12.5 9/26/2012 0:00 90.4 9/28/2012 17:00 13.7

9/18/2012 22:00 134.4 9/22/2012 15:00 6.9 9/24/2012 8:00 163 9/26/2012 1:00 98.2 9/28/2012 18:00 17.3

9/18/2012 23:00 61.6 9/22/2012 16:00 7 9/24/2012 9:00 100.3 9/26/2012 2:00 63.3 9/28/2012 19:00 84.5

9/20/2012 0:00 11.5 9/22/2012 17:00 6.9 9/24/2012 10:00 15.4 9/26/2012 3:00 87 9/28/2012 20:00 93.7

9/20/2012 1:00 11.7 9/22/2012 18:00 9.3 9/24/2012 11:00 8.6 9/26/2012 4:00 59.2 9/28/2012 21:00 60.7

9/20/2012 2:00 10.9 9/22/2012 19:00 14.9 9/24/2012 12:00 8.7 9/26/2012 5:00 90.1 9/28/2012 22:00 56.1

9/20/2012 3:00 10 9/22/2012 20:00 33 9/24/2012 13:00 5.5 9/26/2012 6:00 117.8 9/28/2012 23:00 38.6

9/20/2012 4:00 8.1 9/22/2012 21:00 75.6 9/24/2012 14:00 5 9/26/2012 7:00 131.7 9/29/2012 0:00 22.7

9/20/2012 5:00 7.3 9/22/2012 22:00 66.7 9/24/2012 15:00 9/26/2012 8:00 112.2 9/29/2012 1:00 66.8

9/20/2012 6:00 8.5 9/22/2012 23:00 81.9 9/24/2012 16:00 7 9/26/2012 9:00 34.9 9/29/2012 2:00 89.7

9/20/2012 7:00 8.5 9/23/2012 0:00 110.7 9/24/2012 17:00 27.8 9/26/2012 10:00 10.8 9/29/2012 3:00 35.3

9/20/2012 8:00 13.3 9/23/2012 1:00 110.7 9/24/2012 18:00 30.5 9/26/2012 11:00 8.5 9/29/2012 4:00 77.5

9/20/2012 9:00 9/23/2012 2:00 109.7 9/24/2012 19:00 33.5 9/26/2012 12:00 6.8 9/29/2012 5:00 138.5

9/20/2012 10:00 9/23/2012 3:00 87.3 9/24/2012 20:00 29.2 9/26/2012 13:00 6.3 9/29/2012 6:00 168.6

9/20/2012 11:00 9/23/2012 4:00 50.1 9/24/2012 21:00 27.8 9/26/2012 14:00 5.7 9/29/2012 7:00 83.6

9/20/2012 12:00 11.1 9/23/2012 5:00 34.5 9/24/2012 22:00 26 9/26/2012 15:00 5.3 9/29/2012 8:00 71.6

9/20/2012 13:00 5.6 9/23/2012 6:00 24.8 9/24/2012 23:00 31.4 9/26/2012 16:00 6 9/29/2012 9:00 13.9

9/20/2012 14:00 4.7 9/23/2012 7:00 58.7 9/25/2012 0:00 32.1 9/26/2012 17:00 6.3 9/29/2012 10:00 14.8

9/20/2012 15:00 5.2 9/23/2012 8:00 51.6 9/25/2012 1:00 31.5 9/26/2012 18:00 8.4 9/29/2012 11:00 5.7

9/20/2012 16:00 4.4 9/23/2012 9:00 14.4 9/25/2012 2:00 49.8 9/26/2012 19:00 12.3 9/29/2012 12:00 5

9/20/2012 17:00 4 9/23/2012 10:00 9.7 9/25/2012 3:00 45.2 9/26/2012 20:00 11.8 9/29/2012 13:00 4.7

9/20/2012 18:00 3.9 9/23/2012 11:00 7 9/25/2012 4:00 54.6 9/26/2012 21:00 24.1 9/29/2012 14:00 4.5

9/20/2012 19:00 4 9/23/2012 12:00 5.7 9/25/2012 5:00 62.7 9/26/2012 22:00 47.9 9/29/2012 15:00 4.4

9/20/2012 20:00 3.9 9/23/2012 13:00 4.8 9/25/2012 6:00 53.6 9/26/2012 23:00 86.1 9/29/2012 16:00 4.3

9/20/2012 21:00 4.6 9/23/2012 14:00 4.5 9/25/2012 7:00 82.1 9/28/2012 0:00 109.2 9/29/2012 17:00 4.3

9/20/2012 22:00 77 9/23/2012 15:00 4.2 9/25/2012 8:00 104.5 9/28/2012 1:00 120.8 9/29/2012 18:00 4.3

9/20/2012 23:00 128.7 9/23/2012 16:00 4.9 9/25/2012 9:00 14 9/28/2012 2:00 68.8 9/29/2012 19:00 4.8

9/22/2012 0:00 42.5 9/23/2012 17:00 9/25/2012 10:00 12.8 9/28/2012 3:00 42.5 9/29/2012 20:00 7.6

9/22/2012 1:00 59.8 9/23/2012 18:00 12.2 9/25/2012 11:00 6.5 9/28/2012 4:00 21.6 9/29/2012 21:00 18.8

9/22/2012 2:00 84.7 9/23/2012 19:00 10.5 9/25/2012 12:00 5.3 9/28/2012 5:00 56.3 9/29/2012 22:00 34.3

9/22/2012 3:00 127.3 9/23/2012 20:00 18.4 9/25/2012 13:00 6.1 9/28/2012 6:00 42.9 9/29/2012 23:00 24.4

9/22/2012 4:00 62.8 9/23/2012 21:00 31.8 9/25/2012 14:00 9/28/2012 7:00 108.2 10/1/2012 0:00 36

9/22/2012 5:00 48.2 9/23/2012 22:00 133 9/25/2012 15:00 7.2 9/28/2012 8:00 99.7 10/1/2012 1:00 39.1

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 47
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

10/1/2012 2:00 85.1 10/3/2012 19:00 4.1 10/7/2012 12:00 43.4 10/11/2012 5:00 182 10/12/2012 22:00 86.4

10/1/2012 3:00 49.3 10/3/2012 20:00 4.1 10/7/2012 13:00 21.1 10/11/2012 6:00 193.8 10/12/2012 23:00 401.1

10/1/2012 4:00 60.4 10/3/2012 21:00 4.5 10/7/2012 14:00 14.2 10/11/2012 7:00 85.1 10/13/2012 0:00 626

10/1/2012 5:00 95.2 10/3/2012 22:00 4.4 10/7/2012 15:00 12.3 10/11/2012 8:00 78.3 10/13/2012 1:00 639.7

10/1/2012 6:00 149.8 10/3/2012 23:00 4.3 10/7/2012 16:00 10.8 10/11/2012 9:00 51.3 10/13/2012 2:00 350.1

10/1/2012 7:00 79.1 10/5/2012 0:00 14.6 10/7/2012 17:00 10.7 10/11/2012 10:00 15.7 10/13/2012 3:00 372.5

10/1/2012 8:00 29.7 10/5/2012 1:00 16.7 10/7/2012 18:00 8.8 10/11/2012 11:00 9.4 10/13/2012 4:00 280.1

10/1/2012 9:00 16.8 10/5/2012 2:00 18.8 10/7/2012 19:00 6.9 10/11/2012 12:00 7.3 10/13/2012 5:00 392.9

10/1/2012 10:00 7 10/5/2012 3:00 34.4 10/7/2012 20:00 6.7 10/11/2012 13:00 6.4 10/13/2012 6:00 494

10/1/2012 11:00 5.4 10/5/2012 4:00 38.6 10/7/2012 21:00 11.2 10/11/2012 14:00 5.6 10/13/2012 7:00 397.3

10/1/2012 12:00 4.7 10/5/2012 5:00 52.9 10/7/2012 22:00 20.5 10/11/2012 15:00 6.7 10/13/2012 8:00 73.5

10/1/2012 13:00 4.5 10/5/2012 6:00 64.2 10/7/2012 23:00 43.5 10/11/2012 16:00 6.4 10/13/2012 9:00 16.7

10/1/2012 14:00 4.4 10/5/2012 7:00 75.6 10/8/2012 0:00 92.9 10/11/2012 17:00 6.5 10/13/2012 10:00 13.3

10/1/2012 15:00 10/5/2012 8:00 54.1 10/8/2012 1:00 105.2 10/11/2012 18:00 9.1 10/13/2012 11:00 13.3

10/1/2012 16:00 4.4 10/5/2012 9:00 65.1 10/8/2012 2:00 95 10/11/2012 19:00 14.2 10/13/2012 12:00 7.2

10/1/2012 17:00 4.2 10/5/2012 10:00 25.6 10/8/2012 3:00 83.7 10/11/2012 20:00 15.7 10/13/2012 13:00 5.7

10/1/2012 18:00 4.1 10/5/2012 11:00 11.5 10/8/2012 4:00 59.1 10/11/2012 21:00 27 10/13/2012 14:00 5

10/1/2012 19:00 4 10/5/2012 12:00 6.8 10/8/2012 5:00 32.5 10/11/2012 22:00 124.4 10/13/2012 15:00 4.6

10/1/2012 20:00 3.9 10/5/2012 13:00 5.5 10/8/2012 6:00 21.4 10/11/2012 23:00 208.4 10/13/2012 16:00 4.6

10/1/2012 21:00 3.9 10/5/2012 14:00 4.8 10/8/2012 7:00 14.4 10/12/2012 0:00 673.4 10/13/2012 17:00 5.1

10/1/2012 22:00 3.8 10/5/2012 15:00 4.7 10/8/2012 8:00 11.6 10/12/2012 1:00 477.9 10/13/2012 18:00 8.5

10/1/2012 23:00 3.8 10/5/2012 16:00 4.4 10/8/2012 9:00 6.3 10/12/2012 2:00 616.4 10/13/2012 19:00 20

10/3/2012 0:00 7.1 10/5/2012 17:00 4.2 10/8/2012 10:00 5.4 10/12/2012 3:00 489.4 10/13/2012 20:00 53.4

10/3/2012 1:00 7.6 10/5/2012 18:00 4.1 10/8/2012 11:00 4.9 10/12/2012 4:00 397.7 10/13/2012 21:00 161.8

10/3/2012 2:00 7.2 10/5/2012 19:00 3.9 10/8/2012 12:00 4.6 10/12/2012 5:00 406.1 10/13/2012 22:00 273.8

10/3/2012 3:00 7 10/5/2012 20:00 4 10/8/2012 13:00 4.3 10/12/2012 6:00 378 10/13/2012 23:00 494.4

10/3/2012 4:00 6.4 10/5/2012 21:00 4.2 10/8/2012 14:00 4.2 10/12/2012 7:00 471.2 10/14/2012 0:00 446.6

10/3/2012 5:00 5.9 10/5/2012 22:00 4.1 10/8/2012 15:00 10/12/2012 8:00 129.8 10/14/2012 1:00 633.3

10/3/2012 6:00 8.6 10/5/2012 23:00 4.5 10/8/2012 16:00 4.3 10/12/2012 9:00 143.4 10/14/2012 2:00 345

10/3/2012 7:00 11.9 10/7/2012 0:00 7.1 10/8/2012 17:00 4.1 10/12/2012 10:00 18.4 10/14/2012 3:00 173.2

10/3/2012 8:00 52.6 10/7/2012 1:00 9.1 10/8/2012 18:00 4.2 10/12/2012 11:00 9.1 10/14/2012 4:00 54.4

10/3/2012 9:00 151.9 10/7/2012 2:00 13.2 10/8/2012 19:00 4.1 10/12/2012 12:00 6.7 10/14/2012 5:00 69.5

10/3/2012 10:00 425.4 10/7/2012 3:00 10.9 10/8/2012 20:00 4.1 10/12/2012 13:00 5.7 10/14/2012 6:00 272.5

10/3/2012 11:00 25.2 10/7/2012 4:00 8 10/8/2012 21:00 4.1 10/12/2012 14:00 5.5 10/14/2012 7:00 282.1

10/3/2012 12:00 9.7 10/7/2012 5:00 11.3 10/8/2012 22:00 4.1 10/12/2012 15:00 5.4 10/14/2012 8:00 237.7

10/3/2012 13:00 7.2 10/7/2012 6:00 17.9 10/8/2012 23:00 4.7 10/12/2012 16:00 5.6 10/14/2012 9:00 70.3

10/3/2012 14:00 5.7 10/7/2012 7:00 25.6 10/11/2012 0:00 25 10/12/2012 17:00 5.8 10/14/2012 10:00 17.7

10/3/2012 15:00 4.9 10/7/2012 8:00 115.3 10/11/2012 1:00 20 10/12/2012 18:00 5.9 10/14/2012 11:00 8.9

10/3/2012 16:00 4.6 10/7/2012 9:00 139.8 10/11/2012 2:00 35.1 10/12/2012 19:00 13.3 10/14/2012 12:00 6.6

10/3/2012 17:00 4.4 10/7/2012 10:00 85.1 10/11/2012 3:00 174.5 10/12/2012 20:00 76.4 10/14/2012 13:00 5.9

10/3/2012 18:00 4.2 10/7/2012 11:00 70.4 10/11/2012 4:00 142.9 10/12/2012 21:00 101.8 10/14/2012 14:00 5.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 48
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

10/14/2012 15:00 5.2 10/17/2012 8:00 39 10/19/2012 1:00 20.8 10/20/2012 18:00 6.8 10/22/2012 11:00 5.5

10/14/2012 16:00 5.3 10/17/2012 9:00 19.8 10/19/2012 2:00 29.3 10/20/2012 19:00 6.8 10/22/2012 12:00 4.5

10/14/2012 17:00 6.5 10/17/2012 10:00 9.6 10/19/2012 3:00 24.6 10/20/2012 20:00 8.6 10/22/2012 13:00 4.3

10/14/2012 18:00 6.8 10/17/2012 11:00 5.6 10/19/2012 4:00 24.9 10/20/2012 21:00 12.9 10/22/2012 14:00 4.4

10/14/2012 19:00 9.9 10/17/2012 12:00 5.1 10/19/2012 5:00 34.5 10/20/2012 22:00 12.7 10/22/2012 15:00

10/14/2012 20:00 26.1 10/17/2012 13:00 4.6 10/19/2012 6:00 43.3 10/20/2012 23:00 19 10/22/2012 16:00 4.4

10/14/2012 21:00 34.4 10/17/2012 14:00 4.3 10/19/2012 7:00 27.5 10/21/2012 0:00 29 10/22/2012 17:00 4.2

10/14/2012 22:00 28.2 10/17/2012 15:00 4.3 10/19/2012 8:00 32.9 10/21/2012 1:00 66.7 10/22/2012 18:00 5.7

10/14/2012 23:00 24.6 10/17/2012 16:00 4.3 10/19/2012 9:00 16.8 10/21/2012 2:00 41.6 10/22/2012 19:00 7.5

10/16/2012 0:00 26.1 10/17/2012 17:00 4.3 10/19/2012 10:00 9.2 10/21/2012 3:00 21.2 10/22/2012 20:00 6.8

10/16/2012 1:00 65.2 10/17/2012 18:00 5.2 10/19/2012 11:00 7.6 10/21/2012 4:00 23.9 10/22/2012 21:00 15.9

10/16/2012 2:00 37.4 10/17/2012 19:00 8.1 10/19/2012 12:00 6.4 10/21/2012 5:00 86.7 10/22/2012 22:00 21.2

10/16/2012 3:00 43.8 10/17/2012 20:00 14.6 10/19/2012 13:00 5.2 10/21/2012 6:00 92.1 10/22/2012 23:00 21.5

10/16/2012 4:00 24 10/17/2012 21:00 67.5 10/19/2012 14:00 4.7 10/21/2012 7:00 133.4 10/25/2012 0:00 8.6

10/16/2012 5:00 31.4 10/17/2012 22:00 91.2 10/19/2012 15:00 4.8 10/21/2012 8:00 47.8 10/25/2012 1:00 9

10/16/2012 6:00 140.6 10/17/2012 23:00 90.6 10/19/2012 16:00 5.2 10/21/2012 9:00 18.9 10/25/2012 2:00 10.1

10/16/2012 7:00 256.4 10/18/2012 0:00 89.6 10/19/2012 17:00 23 10/21/2012 10:00 15.1 10/25/2012 3:00 9.6

10/16/2012 8:00 204.1 10/18/2012 1:00 99 10/19/2012 18:00 22 10/21/2012 11:00 11.2 10/25/2012 4:00 10.7

10/16/2012 9:00 20.6 10/18/2012 2:00 117.7 10/19/2012 19:00 18.3 10/21/2012 12:00 6.2 10/25/2012 5:00 20.2

10/16/2012 10:00 16.5 10/18/2012 3:00 114.7 10/19/2012 20:00 17.3 10/21/2012 13:00 5.2 10/25/2012 6:00 21.4

10/16/2012 11:00 6.9 10/18/2012 4:00 200.3 10/19/2012 21:00 20.7 10/21/2012 14:00 4.7 10/25/2012 7:00 42.3

10/16/2012 12:00 5.3 10/18/2012 5:00 256.7 10/19/2012 22:00 8 10/21/2012 15:00 4.5 10/25/2012 8:00 124.4

10/16/2012 13:00 4.9 10/18/2012 6:00 228.5 10/19/2012 23:00 76.1 10/21/2012 16:00 5.5 10/25/2012 9:00 77.3

10/16/2012 14:00 10/18/2012 7:00 184.9 10/20/2012 0:00 119.8 10/21/2012 17:00 6.5 10/25/2012 10:00 12

10/16/2012 15:00 7.1 10/18/2012 8:00 233.7 10/20/2012 1:00 40.6 10/21/2012 18:00 9.9 10/25/2012 11:00 6.4

10/16/2012 16:00 5.4 10/18/2012 9:00 22.8 10/20/2012 2:00 62 10/21/2012 19:00 19.1 10/25/2012 12:00 5.4

10/16/2012 17:00 5.1 10/18/2012 10:00 13 10/20/2012 3:00 92.2 10/21/2012 20:00 30.4 10/25/2012 13:00 5

10/16/2012 18:00 4.9 10/18/2012 11:00 8.7 10/20/2012 4:00 33.7 10/21/2012 21:00 61.5 10/25/2012 14:00 4.6

10/16/2012 19:00 4.7 10/18/2012 12:00 5.8 10/20/2012 5:00 14.8 10/21/2012 22:00 60.1 10/25/2012 15:00 5.5

10/16/2012 20:00 4.7 10/18/2012 13:00 4.9 10/20/2012 6:00 14.9 10/21/2012 23:00 23.5 10/25/2012 16:00 4.7

10/16/2012 21:00 4.7 10/18/2012 14:00 4.8 10/20/2012 7:00 133.9 10/22/2012 0:00 20.5 10/25/2012 17:00 4.4

10/16/2012 22:00 5.2 10/18/2012 15:00 5.4 10/20/2012 8:00 51.4 10/22/2012 1:00 23.2 10/25/2012 18:00 4.3

10/16/2012 23:00 10.1 10/18/2012 16:00 4.8 10/20/2012 9:00 10.7 10/22/2012 2:00 20.6 10/25/2012 19:00 4.8

10/17/2012 0:00 13.9 10/18/2012 17:00 4.9 10/20/2012 10:00 14.5 10/22/2012 3:00 41.8 10/25/2012 20:00 6.8

10/17/2012 1:00 30.3 10/18/2012 18:00 6.4 10/20/2012 11:00 5.2 10/22/2012 4:00 14.7 10/25/2012 21:00 9.8

10/17/2012 2:00 71.3 10/18/2012 19:00 6.6 10/20/2012 12:00 4.8 10/22/2012 5:00 9.9 10/25/2012 22:00 8.1

10/17/2012 3:00 34.3 10/18/2012 20:00 9.9 10/20/2012 13:00 4.7 10/22/2012 6:00 10.7 10/25/2012 23:00 14

10/17/2012 4:00 41.1 10/18/2012 21:00 13.3 10/20/2012 14:00 4.6 10/22/2012 7:00 24.4 10/28/2012 0:00 7.9

10/17/2012 5:00 74.6 10/18/2012 22:00 20.5 10/20/2012 15:00 4.6 10/22/2012 8:00 96.1 10/28/2012 1:00 10.7

10/17/2012 6:00 59.9 10/18/2012 23:00 17.6 10/20/2012 16:00 7.2 10/22/2012 9:00 20.3 10/28/2012 2:00 9.9

10/17/2012 7:00 41.4 10/19/2012 0:00 15.6 10/20/2012 17:00 9.4 10/22/2012 10:00 11 10/28/2012 3:00 17.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 49
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

10/28/2012 4:00 23.3 10/29/2012 21:00 45.7 10/31/2012 14:00 4.8 11/2/2012 7:00 397.9 11/5/2012 0:00 61

10/28/2012 5:00 98.9 10/29/2012 22:00 43 10/31/2012 15:00 4.6 11/2/2012 8:00 509.3 11/5/2012 1:00 76.5

10/28/2012 6:00 102 10/29/2012 23:00 68.3 10/31/2012 16:00 4.5 11/2/2012 9:00 463.5 11/5/2012 2:00 36.8

10/28/2012 7:00 34.9 10/30/2012 0:00 116.6 10/31/2012 17:00 5.7 11/2/2012 10:00 56 11/5/2012 3:00 49.8

10/28/2012 8:00 41.9 10/30/2012 1:00 39.6 10/31/2012 18:00 6.1 11/2/2012 11:00 15.7 11/5/2012 4:00 146.1

10/28/2012 9:00 21.5 10/30/2012 2:00 55.6 10/31/2012 19:00 19.5 11/2/2012 12:00 5.9 11/5/2012 5:00 361.5

10/28/2012 10:00 9.6 10/30/2012 3:00 110.7 10/31/2012 20:00 20.9 11/2/2012 13:00 6.6 11/5/2012 6:00 817.7

10/28/2012 11:00 5.8 10/30/2012 4:00 220.6 10/31/2012 21:00 39.7 11/2/2012 14:00 6.9 11/5/2012 7:00 549.1

10/28/2012 12:00 5.4 10/30/2012 5:00 154.4 10/31/2012 22:00 35.6 11/2/2012 15:00 5.2 11/5/2012 8:00 163.5

10/28/2012 13:00 5 10/30/2012 6:00 100.9 10/31/2012 23:00 52.8 11/2/2012 16:00 5 11/5/2012 9:00 117.3

10/28/2012 14:00 4.6 10/30/2012 7:00 128 11/1/2012 0:00 58.1 11/2/2012 17:00 5.4 11/5/2012 10:00 34.1

10/28/2012 15:00 4.5 10/30/2012 8:00 223.9 11/1/2012 1:00 70.3 11/2/2012 18:00 5.6 11/5/2012 11:00 14.7

10/28/2012 16:00 4.8 10/30/2012 9:00 31.9 11/1/2012 2:00 76.3 11/2/2012 19:00 5.5 11/5/2012 12:00 9.7

10/28/2012 17:00 5.4 10/30/2012 10:00 9.6 11/1/2012 3:00 92.8 11/2/2012 20:00 5.5 11/5/2012 13:00 7.3

10/28/2012 18:00 6.9 10/30/2012 11:00 7.7 11/1/2012 4:00 145.3 11/2/2012 21:00 5.3 11/5/2012 14:00 6.5

10/28/2012 19:00 9.7 10/30/2012 12:00 5.9 11/1/2012 5:00 304.1 11/2/2012 22:00 5.2 11/5/2012 15:00

10/28/2012 20:00 19.2 10/30/2012 13:00 5.2 11/1/2012 6:00 321.9 11/2/2012 23:00 5.5 11/5/2012 16:00 6.9

10/28/2012 21:00 18.5 10/30/2012 14:00 11/1/2012 7:00 552.7 11/4/2012 0:00 24.1 11/5/2012 17:00 6.6

10/28/2012 22:00 26.6 10/30/2012 15:00 7.2 11/1/2012 8:00 563.8 11/4/2012 1:00 16.9 11/5/2012 18:00 7.3

10/28/2012 23:00 17.6 10/30/2012 16:00 5.5 11/1/2012 9:00 22.4 11/4/2012 2:00 34 11/5/2012 19:00 10.9

10/29/2012 0:00 60.3 10/30/2012 17:00 5.2 11/1/2012 10:00 11/4/2012 3:00 32.8 11/5/2012 20:00 8.7

10/29/2012 1:00 73.4 10/30/2012 18:00 5.5 11/1/2012 11:00 7.5 11/4/2012 4:00 98.4 11/5/2012 21:00 22.9

10/29/2012 2:00 87.7 10/30/2012 19:00 5.4 11/1/2012 12:00 6.4 11/4/2012 5:00 83.6 11/5/2012 22:00 44.8

10/29/2012 3:00 102.9 10/30/2012 20:00 6.1 11/1/2012 13:00 6 11/4/2012 6:00 78.3 11/5/2012 23:00 21.4

10/29/2012 4:00 211.8 10/30/2012 21:00 12.7 11/1/2012 14:00 5.3 11/4/2012 7:00 78.4 11/6/2012 0:00 15.6

10/29/2012 5:00 43.7 10/30/2012 22:00 26 11/1/2012 15:00 5.8 11/4/2012 8:00 71 11/6/2012 1:00 14.1

10/29/2012 6:00 24.2 10/30/2012 23:00 28.8 11/1/2012 16:00 4.9 11/4/2012 9:00 57.9 11/6/2012 2:00 15.7

10/29/2012 7:00 107.5 10/31/2012 0:00 36.3 11/1/2012 17:00 5 11/4/2012 10:00 7.4 11/6/2012 3:00 17.4

10/29/2012 8:00 50.3 10/31/2012 1:00 28.1 11/1/2012 18:00 5.1 11/4/2012 11:00 5.8 11/6/2012 4:00 17.1

10/29/2012 9:00 36.6 10/31/2012 2:00 18.2 11/1/2012 19:00 8.9 11/4/2012 12:00 5.3 11/6/2012 5:00 17.3

10/29/2012 10:00 14.9 10/31/2012 3:00 14.4 11/1/2012 20:00 19 11/4/2012 13:00 5.1 11/6/2012 6:00 25.2

10/29/2012 11:00 12.4 10/31/2012 4:00 47.6 11/1/2012 21:00 15.5 11/4/2012 14:00 4.7 11/6/2012 7:00 44.4

10/29/2012 12:00 14 10/31/2012 5:00 49 11/1/2012 22:00 13.4 11/4/2012 15:00 4.6 11/6/2012 8:00 42.9

10/29/2012 13:00 10.8 10/31/2012 6:00 76.5 11/1/2012 23:00 40 11/4/2012 16:00 4.7 11/6/2012 9:00 26.5

10/29/2012 14:00 6.8 10/31/2012 7:00 173.5 11/2/2012 0:00 241.6 11/4/2012 17:00 4.5 11/6/2012 10:00 39.7

10/29/2012 15:00 10/31/2012 8:00 167 11/2/2012 1:00 337.7 11/4/2012 18:00 4.6 11/6/2012 11:00 10.3

10/29/2012 16:00 9 10/31/2012 9:00 80.3 11/2/2012 2:00 299.3 11/4/2012 19:00 4.7 11/6/2012 12:00 8.8

10/29/2012 17:00 13.9 10/31/2012 10:00 21.3 11/2/2012 3:00 247.1 11/4/2012 20:00 4.7 11/6/2012 13:00 7.2

10/29/2012 18:00 24.4 10/31/2012 11:00 9.8 11/2/2012 4:00 187.7 11/4/2012 21:00 5 11/6/2012 14:00

10/29/2012 19:00 33.1 10/31/2012 12:00 6.7 11/2/2012 5:00 220.8 11/4/2012 22:00 7 11/6/2012 15:00 10.2

10/29/2012 20:00 39 10/31/2012 13:00 5.1 11/2/2012 6:00 185.5 11/4/2012 23:00 19.2 11/6/2012 16:00 11.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 50
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/6/2012 17:00 24 11/8/2012 10:00 19.7 11/10/2012 3:00 4.6 11/11/2012 20:00 13.3 11/13/2012 13:00 8.1

11/6/2012 18:00 54.6 11/8/2012 11:00 8.1 11/10/2012 4:00 4.6 11/11/2012 21:00 11.2 11/13/2012 14:00

11/6/2012 19:00 47 11/8/2012 12:00 6.3 11/10/2012 5:00 4.7 11/11/2012 22:00 48.1 11/13/2012 15:00

11/6/2012 20:00 140.9 11/8/2012 13:00 5.3 11/10/2012 6:00 34 11/11/2012 23:00 65.4 11/13/2012 16:00

11/6/2012 21:00 145.1 11/8/2012 14:00 5.1 11/10/2012 7:00 115.7 11/12/2012 0:00 6.2 11/13/2012 17:00

11/6/2012 22:00 136.4 11/8/2012 15:00 7.5 11/10/2012 8:00 416.3 11/12/2012 1:00 5.8 11/13/2012 18:00

11/6/2012 23:00 67.9 11/8/2012 16:00 10.2 11/10/2012 9:00 186.3 11/12/2012 2:00 5.2 11/13/2012 19:00

11/7/2012 0:00 49.4 11/8/2012 17:00 49.3 11/10/2012 10:00 41.5 11/12/2012 3:00 7.7 11/13/2012 20:00

11/7/2012 1:00 37.8 11/8/2012 18:00 36.1 11/10/2012 11:00 32.8 11/12/2012 4:00 20.9 11/13/2012 21:00

11/7/2012 2:00 26.9 11/8/2012 19:00 52.9 11/10/2012 12:00 8.2 11/12/2012 5:00 6.3 11/13/2012 22:00

11/7/2012 3:00 74.2 11/8/2012 20:00 61.9 11/10/2012 13:00 7.2 11/12/2012 6:00 40.4 11/13/2012 23:00

11/7/2012 4:00 143.7 11/8/2012 21:00 50.1 11/10/2012 14:00 7.2 11/12/2012 7:00 46.1 11/14/2012 0:00

11/7/2012 5:00 185.3 11/8/2012 22:00 61.3 11/10/2012 15:00 6.7 11/12/2012 8:00 205.4 11/14/2012 1:00

11/7/2012 6:00 55.6 11/8/2012 23:00 44.3 11/10/2012 16:00 7.8 11/12/2012 9:00 13.6 11/14/2012 2:00

11/7/2012 7:00 17.7 11/9/2012 0:00 66 11/10/2012 17:00 22.8 11/12/2012 10:00 13.6 11/14/2012 3:00

11/7/2012 8:00 33 11/9/2012 1:00 84.6 11/10/2012 18:00 226.1 11/12/2012 11:00 8.8 11/14/2012 4:00

11/7/2012 9:00 19.3 11/9/2012 2:00 89.6 11/10/2012 19:00 116.3 11/12/2012 12:00 6.1 11/14/2012 5:00

11/7/2012 10:00 11.7 11/9/2012 3:00 81 11/10/2012 20:00 43.7 11/12/2012 13:00 5.4 11/14/2012 6:00

11/7/2012 11:00 12.5 11/9/2012 4:00 77.2 11/10/2012 21:00 25.2 11/12/2012 14:00 5.1 11/14/2012 7:00

11/7/2012 12:00 6.4 11/9/2012 5:00 91.8 11/10/2012 22:00 13.4 11/12/2012 15:00 11/14/2012 8:00

11/7/2012 13:00 5.3 11/9/2012 6:00 79.1 11/10/2012 23:00 31.9 11/12/2012 16:00 6.4 11/14/2012 9:00 55.9

11/7/2012 14:00 4.9 11/9/2012 7:00 104.5 11/11/2012 0:00 72.3 11/12/2012 17:00 36.6 11/14/2012 10:00 46.2

11/7/2012 15:00 4.9 11/9/2012 8:00 129.6 11/11/2012 1:00 7.5 11/12/2012 18:00 24.5 11/14/2012 11:00 76.6

11/7/2012 16:00 5 11/9/2012 9:00 17 11/11/2012 2:00 5.4 11/12/2012 19:00 60.6 11/14/2012 12:00 59.1

11/7/2012 17:00 6.8 11/9/2012 10:00 14.6 11/11/2012 3:00 4.6 11/12/2012 20:00 68.5 11/14/2012 13:00 9.6

11/7/2012 18:00 9.3 11/9/2012 11:00 11.8 11/11/2012 4:00 14.3 11/12/2012 21:00 77.2 11/14/2012 14:00 15.2

11/7/2012 19:00 13.3 11/9/2012 12:00 66.7 11/11/2012 5:00 39.5 11/12/2012 22:00 64 11/14/2012 15:00 12.4

11/7/2012 20:00 14 11/9/2012 13:00 38.4 11/11/2012 6:00 68.6 11/12/2012 23:00 38.3 11/14/2012 16:00 57.9

11/7/2012 21:00 26.7 11/9/2012 14:00 23.7 11/11/2012 7:00 43.9 11/13/2012 0:00 38.4 11/14/2012 17:00 132.8

11/7/2012 22:00 46.4 11/9/2012 15:00 34 11/11/2012 8:00 122.7 11/13/2012 1:00 88.6 11/14/2012 18:00 90.3

11/7/2012 23:00 111.9 11/9/2012 16:00 37.3 11/11/2012 9:00 10 11/13/2012 2:00 65.3 11/14/2012 19:00 81.6

11/8/2012 0:00 187.9 11/9/2012 17:00 56.9 11/11/2012 10:00 9.6 11/13/2012 3:00 20.2 11/14/2012 20:00 141.4

11/8/2012 1:00 157.4 11/9/2012 18:00 66.8 11/11/2012 11:00 8.2 11/13/2012 4:00 7.5 11/14/2012 21:00 108.3

11/8/2012 2:00 140.8 11/9/2012 19:00 46.1 11/11/2012 12:00 7 11/13/2012 5:00 5.5 11/14/2012 22:00 77.6

11/8/2012 3:00 109 11/9/2012 20:00 25.9 11/11/2012 13:00 6.5 11/13/2012 6:00 5 11/14/2012 23:00 81

11/8/2012 4:00 68.1 11/9/2012 21:00 34.7 11/11/2012 14:00 6.3 11/13/2012 7:00 208.1 11/15/2012 0:00 71.2

11/8/2012 5:00 45.9 11/9/2012 22:00 90.7 11/11/2012 15:00 6.6 11/13/2012 8:00 34.8 11/15/2012 1:00 55

11/8/2012 6:00 42.7 11/9/2012 23:00 50.7 11/11/2012 16:00 5.4 11/13/2012 9:00 127.6 11/15/2012 2:00 107.1

11/8/2012 7:00 55.3 11/10/2012 0:00 26.3 11/11/2012 17:00 61.9 11/13/2012 10:00 9.6 11/15/2012 3:00 170.8

11/8/2012 8:00 98 11/10/2012 1:00 6.8 11/11/2012 18:00 203.1 11/13/2012 11:00 10 11/15/2012 4:00 195.2

11/8/2012 9:00 32.4 11/10/2012 2:00 4.9 11/11/2012 19:00 69.5 11/13/2012 12:00 8.5 11/15/2012 5:00 157.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 51
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/15/2012 6:00 27.5 11/16/2012 23:00 343.4 11/18/2012 16:00 6.2 11/23/2012 9:00 37.9 11/25/2012 2:00 177.9

11/15/2012 7:00 41.5 11/17/2012 0:00 241.6 11/18/2012 17:00 6.2 11/23/2012 10:00 9.3 11/25/2012 3:00 281.6

11/15/2012 8:00 35.9 11/17/2012 1:00 220.8 11/18/2012 18:00 16.2 11/23/2012 11:00 6.7 11/25/2012 4:00 286.2

11/15/2012 9:00 339.5 11/17/2012 2:00 270.1 11/18/2012 19:00 26.6 11/23/2012 12:00 5.7 11/25/2012 5:00 158.8

11/15/2012 10:00 24.5 11/17/2012 3:00 124.4 11/18/2012 20:00 29.1 11/23/2012 13:00 5.4 11/25/2012 6:00 105.6

11/15/2012 11:00 15.3 11/17/2012 4:00 79.6 11/18/2012 21:00 48.6 11/23/2012 14:00 5.2 11/25/2012 7:00 81

11/15/2012 12:00 13.3 11/17/2012 5:00 43.1 11/18/2012 22:00 47.9 11/23/2012 15:00 5.6 11/25/2012 8:00 128.5

11/15/2012 13:00 10 11/17/2012 6:00 34.2 11/18/2012 23:00 40.1 11/23/2012 16:00 6.9 11/25/2012 9:00 149.9

11/15/2012 14:00 10.7 11/17/2012 7:00 57.1 11/19/2012 0:00 30 11/23/2012 17:00 5.5 11/25/2012 10:00 90

11/15/2012 15:00 30.9 11/17/2012 8:00 84 11/19/2012 1:00 21.9 11/23/2012 18:00 5.7 11/25/2012 11:00 65

11/15/2012 16:00 36.7 11/17/2012 9:00 155.7 11/19/2012 2:00 24.6 11/23/2012 19:00 9.9 11/25/2012 12:00 27.3

11/15/2012 17:00 75.4 11/17/2012 10:00 199.1 11/19/2012 3:00 50.5 11/23/2012 20:00 8.9 11/25/2012 13:00 20.1

11/15/2012 18:00 41.7 11/17/2012 11:00 11.8 11/19/2012 4:00 89.4 11/23/2012 21:00 11 11/25/2012 14:00 25.4

11/15/2012 19:00 63 11/17/2012 12:00 12.9 11/19/2012 5:00 72.4 11/23/2012 22:00 10.3 11/25/2012 15:00 32.5

11/15/2012 20:00 67.8 11/17/2012 13:00 18.6 11/19/2012 6:00 56.2 11/23/2012 23:00 9.2 11/25/2012 16:00 27

11/15/2012 21:00 65.4 11/17/2012 14:00 13.9 11/19/2012 7:00 27.7 11/24/2012 0:00 16.2 11/25/2012 17:00 22.8

11/15/2012 22:00 59.6 11/17/2012 15:00 8.4 11/19/2012 8:00 23 11/24/2012 1:00 24.6 11/25/2012 18:00 104.5

11/15/2012 23:00 74.1 11/17/2012 16:00 11.9 11/19/2012 9:00 22.1 11/24/2012 2:00 25.4 11/25/2012 19:00 80.9

11/16/2012 0:00 95.7 11/17/2012 17:00 18.7 11/19/2012 10:00 17.8 11/24/2012 3:00 40 11/25/2012 20:00 121.7

11/16/2012 1:00 114.4 11/17/2012 18:00 50.4 11/19/2012 11:00 15.2 11/24/2012 4:00 61.6 11/25/2012 21:00 104.9

11/16/2012 2:00 112.4 11/17/2012 19:00 299 11/19/2012 12:00 9.6 11/24/2012 5:00 159.1 11/25/2012 22:00 63.8

11/16/2012 3:00 93.7 11/17/2012 20:00 40.5 11/19/2012 13:00 6 11/24/2012 6:00 133.1 11/25/2012 23:00 72.6

11/16/2012 4:00 88.8 11/17/2012 21:00 31.3 11/19/2012 14:00 5.3 11/24/2012 7:00 101.5 11/26/2012 0:00 68.7

11/16/2012 5:00 143.3 11/17/2012 22:00 44.5 11/19/2012 15:00 11/24/2012 8:00 81.7 11/26/2012 1:00 78.3

11/16/2012 6:00 145.2 11/17/2012 23:00 41.8 11/19/2012 16:00 5.9 11/24/2012 9:00 57.3 11/26/2012 2:00 62.3

11/16/2012 7:00 109.4 11/18/2012 0:00 73.7 11/19/2012 17:00 6.8 11/24/2012 10:00 31.9 11/26/2012 3:00 64.8

11/16/2012 8:00 70.1 11/18/2012 1:00 82.7 11/19/2012 18:00 13.3 11/24/2012 11:00 19.6 11/26/2012 4:00 57.8

11/16/2012 9:00 30.3 11/18/2012 2:00 94.1 11/19/2012 19:00 13.1 11/24/2012 12:00 9.1 11/26/2012 5:00 64.4

11/16/2012 10:00 18.8 11/18/2012 3:00 122.7 11/19/2012 20:00 18.2 11/24/2012 13:00 7.2 11/26/2012 6:00 75.5

11/16/2012 11:00 10.8 11/18/2012 4:00 95.9 11/19/2012 21:00 27 11/24/2012 14:00 6 11/26/2012 7:00 64.6

11/16/2012 12:00 7.9 11/18/2012 5:00 89.7 11/19/2012 22:00 18.8 11/24/2012 15:00 5.2 11/26/2012 8:00 140.9

11/16/2012 13:00 9.7 11/18/2012 6:00 56.1 11/19/2012 23:00 16.3 11/24/2012 16:00 6.4 11/26/2012 9:00 173.8

11/16/2012 14:00 14.3 11/18/2012 7:00 37.3 11/23/2012 0:00 21.5 11/24/2012 17:00 8.7 11/26/2012 10:00 130.8

11/16/2012 15:00 14.2 11/18/2012 8:00 152.7 11/23/2012 1:00 23.5 11/24/2012 18:00 9.1 11/26/2012 11:00 98.6

11/16/2012 16:00 16.1 11/18/2012 9:00 11.2 11/23/2012 2:00 19 11/24/2012 19:00 14.3 11/26/2012 12:00 51.4

11/16/2012 17:00 12.3 11/18/2012 10:00 6.9 11/23/2012 3:00 22 11/24/2012 20:00 16.6 11/26/2012 13:00 33

11/16/2012 18:00 97.9 11/18/2012 11:00 7 11/23/2012 4:00 28.4 11/24/2012 21:00 23.6 11/26/2012 14:00 24.5

11/16/2012 19:00 170.8 11/18/2012 12:00 7.2 11/23/2012 5:00 36.3 11/24/2012 22:00 64.5 11/26/2012 15:00

11/16/2012 20:00 299.6 11/18/2012 13:00 6.4 11/23/2012 6:00 32.7 11/24/2012 23:00 88.5 11/26/2012 16:00 19.2

11/16/2012 21:00 314.6 11/18/2012 14:00 6.6 11/23/2012 7:00 44.1 11/25/2012 0:00 81.6 11/26/2012 17:00 15.9

11/16/2012 22:00 230.6 11/18/2012 15:00 8.7 11/23/2012 8:00 107.7 11/25/2012 1:00 110 11/26/2012 18:00 16.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 52
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/26/2012 19:00 18.5 11/28/2012 12:00 7 11/30/2012 5:00 133 12/1/2012 22:00 8 12/6/2012 15:00 6

11/26/2012 20:00 19.9 11/28/2012 13:00 5.7 11/30/2012 6:00 241.6 12/1/2012 23:00 7.9 12/6/2012 16:00 5.2

11/26/2012 21:00 18.7 11/28/2012 14:00 5.4 11/30/2012 7:00 310.7 12/5/2012 0:00 180 12/6/2012 17:00 5.4

11/26/2012 22:00 29 11/28/2012 15:00 5.5 11/30/2012 8:00 134.8 12/5/2012 1:00 206.1 12/6/2012 18:00 5.3

11/26/2012 23:00 29.6 11/28/2012 16:00 5.3 11/30/2012 9:00 179.5 12/5/2012 2:00 60 12/6/2012 19:00 6.1

11/27/2012 0:00 36.2 11/28/2012 17:00 5.4 11/30/2012 10:00 43.2 12/5/2012 3:00 46.4 12/6/2012 20:00 20.2

11/27/2012 1:00 50 11/28/2012 18:00 5.4 11/30/2012 11:00 36.5 12/5/2012 4:00 36.8 12/6/2012 21:00 33.2

11/27/2012 2:00 68.2 11/28/2012 19:00 5.1 11/30/2012 12:00 22.5 12/5/2012 5:00 24.6 12/6/2012 22:00 26.7

11/27/2012 3:00 63.3 11/28/2012 20:00 4.8 11/30/2012 13:00 14.4 12/5/2012 6:00 16.5 12/6/2012 23:00 68

11/27/2012 4:00 66 11/28/2012 21:00 4.9 11/30/2012 14:00 10.8 12/5/2012 7:00 12.9 12/7/2012 0:00 178.1

11/27/2012 5:00 66.8 11/28/2012 22:00 6.9 11/30/2012 15:00 7.5 12/5/2012 8:00 11 12/7/2012 1:00 268.7

11/27/2012 6:00 74.7 11/28/2012 23:00 11.4 11/30/2012 16:00 5.6 12/5/2012 9:00 12.2 12/7/2012 2:00 236.1

11/27/2012 7:00 88.9 11/29/2012 0:00 15.2 11/30/2012 17:00 5.1 12/5/2012 10:00 10.1 12/7/2012 3:00 165.9

11/27/2012 8:00 95.7 11/29/2012 1:00 26 11/30/2012 18:00 5.2 12/5/2012 11:00 6.3 12/7/2012 4:00 85.6

11/27/2012 9:00 130.6 11/29/2012 2:00 24.7 11/30/2012 19:00 5.2 12/5/2012 12:00 5.6 12/7/2012 5:00 87.3

11/27/2012 10:00 77.5 11/29/2012 3:00 14.2 11/30/2012 20:00 5.3 12/5/2012 13:00 5.2 12/7/2012 6:00 80.9

11/27/2012 11:00 22.9 11/29/2012 4:00 17.6 11/30/2012 21:00 5.6 12/5/2012 14:00 5.1 12/7/2012 7:00 38.7

11/27/2012 12:00 27.9 11/29/2012 5:00 19.1 11/30/2012 22:00 6.2 12/5/2012 15:00 5.3 12/7/2012 8:00 81.9

11/27/2012 13:00 19.4 11/29/2012 6:00 31.5 11/30/2012 23:00 7.8 12/5/2012 16:00 5.4 12/7/2012 9:00 157.5

11/27/2012 14:00 11/29/2012 7:00 61.9 12/1/2012 0:00 14.7 12/5/2012 17:00 5.6 12/7/2012 10:00 20.4

11/27/2012 15:00 21.8 11/29/2012 8:00 97.5 12/1/2012 1:00 21.8 12/5/2012 18:00 7.9 12/7/2012 11:00 11.5

11/27/2012 16:00 23.6 11/29/2012 9:00 139.6 12/1/2012 2:00 34.8 12/5/2012 19:00 12.4 12/7/2012 12:00 8.2

11/27/2012 17:00 36.7 11/29/2012 10:00 118 12/1/2012 3:00 34.9 12/5/2012 20:00 14.8 12/7/2012 13:00 6.7

11/27/2012 18:00 31.3 11/29/2012 11:00 53.7 12/1/2012 4:00 57.5 12/5/2012 21:00 16.8 12/7/2012 14:00 5.5

11/27/2012 19:00 35.3 11/29/2012 12:00 32.1 12/1/2012 5:00 158.7 12/5/2012 22:00 24.5 12/7/2012 15:00 5.1

11/27/2012 20:00 23.9 11/29/2012 13:00 23.5 12/1/2012 6:00 507.5 12/5/2012 23:00 80.9 12/7/2012 16:00 5

11/27/2012 21:00 33.4 11/29/2012 14:00 18.6 12/1/2012 7:00 191.9 12/6/2012 0:00 193.3 12/7/2012 17:00 5.1

11/27/2012 22:00 41.7 11/29/2012 15:00 12/1/2012 8:00 102.8 12/6/2012 1:00 100.6 12/7/2012 18:00 5.7

11/27/2012 23:00 37.2 11/29/2012 16:00 19.4 12/1/2012 9:00 77.1 12/6/2012 2:00 51.9 12/7/2012 19:00 8.9

11/28/2012 0:00 57.3 11/29/2012 17:00 19.2 12/1/2012 10:00 18.5 12/6/2012 3:00 40.5 12/7/2012 20:00 12.4

11/28/2012 1:00 82 11/29/2012 18:00 15.6 12/1/2012 11:00 12.1 12/6/2012 4:00 39.2 12/7/2012 21:00 14.1

11/28/2012 2:00 100 11/29/2012 19:00 15.6 12/1/2012 12:00 8.4 12/6/2012 5:00 118.3 12/7/2012 22:00 16.5

11/28/2012 3:00 102.9 11/29/2012 20:00 13.9 12/1/2012 13:00 7.6 12/6/2012 6:00 310.3 12/7/2012 23:00 48.9

11/28/2012 4:00 108.8 11/29/2012 21:00 12.5 12/1/2012 14:00 6 12/6/2012 7:00 358.6 12/8/2012 0:00 84.7

11/28/2012 5:00 118.7 11/29/2012 22:00 11.5 12/1/2012 15:00 5.2 12/6/2012 8:00 392.9 12/8/2012 1:00 88.4

11/28/2012 6:00 242.4 11/29/2012 23:00 10 12/1/2012 16:00 5.1 12/6/2012 9:00 99.3 12/8/2012 2:00 107.5

11/28/2012 7:00 295.5 11/30/2012 0:00 11.6 12/1/2012 17:00 5 12/6/2012 10:00 14.4 12/8/2012 3:00 127.7

11/28/2012 8:00 254.2 11/30/2012 1:00 20.7 12/1/2012 18:00 5.3 12/6/2012 11:00 7.6 12/8/2012 4:00 104.9

11/28/2012 9:00 77.2 11/30/2012 2:00 159.7 12/1/2012 19:00 6.7 12/6/2012 12:00 6.3 12/8/2012 5:00 108.3

11/28/2012 10:00 13.7 11/30/2012 3:00 176.6 12/1/2012 20:00 8.5 12/6/2012 13:00 5.7 12/8/2012 6:00 257.6

11/28/2012 11:00 13.1 11/30/2012 4:00 108.6 12/1/2012 21:00 7.7 12/6/2012 14:00 5.1 12/8/2012 7:00 430.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 53
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/8/2012 8:00 433.8 12/11/2012 1:00 20.2 12/12/2012 18:00 501.5 12/14/2012 11:00 216.6 12/16/2012 4:00 58.2

12/8/2012 9:00 59.1 12/11/2012 2:00 18.9 12/12/2012 19:00 64.9 12/14/2012 12:00 109.2 12/16/2012 5:00 138.4

12/8/2012 10:00 39.4 12/11/2012 3:00 20.8 12/12/2012 20:00 47.9 12/14/2012 13:00 20.7 12/16/2012 6:00 228.3

12/8/2012 11:00 15.5 12/11/2012 4:00 72.2 12/12/2012 21:00 370.4 12/14/2012 14:00 10.6 12/16/2012 7:00 121

12/8/2012 12:00 9.7 12/11/2012 5:00 144.1 12/12/2012 22:00 13.8 12/14/2012 15:00 15.1 12/16/2012 8:00 122.2

12/8/2012 13:00 7.4 12/11/2012 6:00 120.4 12/12/2012 23:00 8.1 12/14/2012 16:00 7.2 12/17/2012 8:00 24

12/8/2012 14:00 6.6 12/11/2012 7:00 66.1 12/13/2012 0:00 197.5 12/14/2012 17:00 13 12/17/2012 9:00 129.1

12/8/2012 15:00 5.8 12/11/2012 8:00 31.3 12/13/2012 1:00 24.7 12/14/2012 18:00 39 12/17/2012 10:00 686.7

12/8/2012 16:00 5.7 12/11/2012 9:00 274.6 12/13/2012 2:00 62.1 12/14/2012 19:00 57.3 12/17/2012 11:00 266.7

12/8/2012 17:00 6 12/11/2012 10:00 87 12/13/2012 3:00 31.7 12/14/2012 20:00 141.6 12/17/2012 12:00 473.8

12/8/2012 18:00 7.1 12/11/2012 11:00 202.6 12/13/2012 4:00 10 12/14/2012 21:00 207.2 12/17/2012 13:00 305.2

12/8/2012 19:00 6.5 12/11/2012 12:00 194.5 12/13/2012 5:00 29.5 12/14/2012 22:00 165.3 12/17/2012 14:00 417.4

12/8/2012 20:00 17.1 12/11/2012 13:00 10.5 12/13/2012 6:00 264.6 12/14/2012 23:00 141.9 12/17/2012 15:00 477.9

12/8/2012 21:00 20.3 12/11/2012 14:00 12/13/2012 7:00 188.5 12/15/2012 0:00 97.2 12/17/2012 16:00 369.9

12/8/2012 22:00 11.3 12/11/2012 15:00 23 12/13/2012 8:00 65.2 12/15/2012 1:00 111.5 12/17/2012 17:00 109.6

12/8/2012 23:00 11.1 12/11/2012 16:00 187.4 12/13/2012 9:00 97.5 12/15/2012 2:00 53.4 12/17/2012 18:00 34.4

12/10/2012 0:00 57.5 12/11/2012 17:00 134.5 12/13/2012 10:00 65.4 12/15/2012 3:00 399.2 12/17/2012 19:00 18.6

12/10/2012 1:00 150.8 12/11/2012 18:00 137.5 12/13/2012 11:00 147.1 12/15/2012 4:00 84.1 12/17/2012 20:00 11.1

12/10/2012 2:00 154.4 12/11/2012 19:00 271.8 12/13/2012 12:00 29.9 12/15/2012 5:00 91.5 12/17/2012 21:00 24.2

12/10/2012 3:00 37.8 12/11/2012 20:00 157.3 12/13/2012 13:00 14.2 12/15/2012 6:00 15.4 12/17/2012 22:00 12.7

12/10/2012 4:00 17.5 12/11/2012 21:00 110.7 12/13/2012 14:00 23.7 12/15/2012 7:00 20.7 12/17/2012 23:00 6.6

12/10/2012 5:00 43.8 12/11/2012 22:00 146.4 12/13/2012 15:00 92.4 12/15/2012 8:00 39.5 12/18/2012 0:00 24.6

12/10/2012 6:00 94.1 12/11/2012 23:00 88.3 12/13/2012 16:00 367.2 12/15/2012 9:00 9.5 12/18/2012 1:00 34

12/10/2012 7:00 119.7 12/12/2012 0:00 113.6 12/13/2012 17:00 197.9 12/15/2012 10:00 15.7 12/18/2012 2:00 48.6

12/10/2012 8:00 44 12/12/2012 1:00 96.7 12/13/2012 18:00 13.1 12/15/2012 11:00 14.7 12/18/2012 3:00 147.7

12/10/2012 9:00 20.2 12/12/2012 2:00 127.6 12/13/2012 19:00 46.6 12/15/2012 12:00 9.7 12/18/2012 4:00 206.3

12/10/2012 10:00 10.6 12/12/2012 3:00 140.4 12/13/2012 20:00 14 12/15/2012 13:00 8.3 12/18/2012 5:00 113.8

12/10/2012 11:00 9.2 12/12/2012 4:00 57.8 12/13/2012 21:00 30.7 12/15/2012 14:00 6.6 12/18/2012 6:00 67.5

12/10/2012 12:00 9.6 12/12/2012 5:00 80.4 12/13/2012 22:00 12.2 12/15/2012 15:00 6 12/18/2012 7:00 247.9

12/10/2012 13:00 6.2 12/12/2012 6:00 104 12/13/2012 23:00 8.1 12/15/2012 16:00 15.9 12/18/2012 8:00 208.1

12/10/2012 14:00 5.5 12/12/2012 7:00 167.3 12/14/2012 0:00 60.2 12/15/2012 17:00 129.9 12/18/2012 9:00 52.8

12/10/2012 15:00 12/12/2012 8:00 368.6 12/14/2012 1:00 80.6 12/15/2012 18:00 68.2 12/18/2012 10:00 33.3

12/10/2012 16:00 5.7 12/12/2012 9:00 346.5 12/14/2012 2:00 6.4 12/15/2012 19:00 16.2 12/18/2012 11:00 52.4

12/10/2012 17:00 6.5 12/12/2012 10:00 89.3 12/14/2012 3:00 11.2 12/15/2012 20:00 32.2 12/18/2012 12:00 12.5

12/10/2012 18:00 8.9 12/12/2012 11:00 120.2 12/14/2012 4:00 5.8 12/15/2012 21:00 94.8 12/18/2012 13:00 9

12/10/2012 19:00 10.7 12/12/2012 12:00 92 12/14/2012 5:00 48.9 12/15/2012 22:00 41.6 12/18/2012 14:00

12/10/2012 20:00 21.3 12/12/2012 13:00 14.9 12/14/2012 6:00 225.9 12/15/2012 23:00 72.1 12/18/2012 15:00 16.4

12/10/2012 21:00 28.3 12/12/2012 14:00 10.4 12/14/2012 7:00 252.2 12/16/2012 0:00 43 12/18/2012 16:00 10.6

12/10/2012 22:00 17.1 12/12/2012 15:00 36.8 12/14/2012 8:00 143.2 12/16/2012 1:00 25.7 12/18/2012 17:00 80.4

12/10/2012 23:00 10.9 12/12/2012 16:00 53.1 12/14/2012 9:00 187.8 12/16/2012 2:00 37.1 12/18/2012 18:00 202.8

12/11/2012 0:00 12.7 12/12/2012 17:00 440.6 12/14/2012 10:00 473.7 12/16/2012 3:00 20.1 12/18/2012 19:00 65

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 54
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/18/2012 20:00 6.1 12/20/2012 13:00 8.4 12/22/2012 6:00 125.4 12/23/2012 23:00 14.8 12/27/2012 16:00 5.1

12/18/2012 21:00 5.3 12/20/2012 14:00 12.3 12/22/2012 7:00 112.6 12/26/2012 0:00 8 12/27/2012 17:00 4.9

12/18/2012 22:00 5.9 12/20/2012 15:00 14.8 12/22/2012 8:00 81.1 12/26/2012 1:00 26.7 12/27/2012 18:00 6.7

12/18/2012 23:00 75.2 12/20/2012 16:00 20.5 12/22/2012 9:00 36.9 12/26/2012 2:00 214 12/27/2012 19:00 17.4

12/19/2012 0:00 61.4 12/20/2012 17:00 28.6 12/22/2012 10:00 19.3 12/26/2012 3:00 552.4 12/27/2012 20:00 102.6

12/19/2012 1:00 18 12/20/2012 18:00 186.3 12/22/2012 11:00 15.1 12/26/2012 4:00 391.6 12/27/2012 21:00 60.3

12/19/2012 2:00 10.4 12/20/2012 19:00 69.5 12/22/2012 12:00 12 12/26/2012 5:00 82.9 12/27/2012 22:00 83.2

12/19/2012 3:00 15.3 12/20/2012 20:00 304.3 12/22/2012 13:00 8.5 12/26/2012 6:00 38.8 12/27/2012 23:00 46.6

12/19/2012 4:00 8.5 12/20/2012 21:00 280.2 12/22/2012 14:00 6 12/26/2012 7:00 21.2 12/28/2012 0:00 36.4

12/19/2012 5:00 26.2 12/20/2012 22:00 85.7 12/22/2012 15:00 5.4 12/26/2012 8:00 39.7 12/28/2012 1:00 43.4

12/19/2012 6:00 100.1 12/20/2012 23:00 131.1 12/22/2012 16:00 5.4 12/26/2012 9:00 19.5 12/28/2012 2:00 62.5

12/19/2012 7:00 106.5 12/21/2012 0:00 223.5 12/22/2012 17:00 5.4 12/26/2012 10:00 23.1 12/28/2012 3:00 87.3

12/19/2012 8:00 60.3 12/21/2012 1:00 259 12/22/2012 18:00 6 12/26/2012 11:00 13.2 12/28/2012 4:00 44.2

12/19/2012 9:00 21.6 12/21/2012 2:00 197.2 12/22/2012 19:00 6.8 12/26/2012 12:00 9.2 12/28/2012 5:00 24.1

12/19/2012 10:00 18.8 12/21/2012 3:00 92.1 12/22/2012 20:00 7.3 12/26/2012 13:00 7.2 12/28/2012 6:00 14

12/19/2012 11:00 12.8 12/21/2012 4:00 151.3 12/22/2012 21:00 14.3 12/26/2012 14:00 5.8 12/28/2012 7:00 13

12/19/2012 12:00 9.7 12/21/2012 5:00 84.2 12/22/2012 22:00 27.1 12/26/2012 15:00 5.5 12/28/2012 8:00 20.9

12/19/2012 13:00 13.7 12/21/2012 6:00 49.8 12/22/2012 23:00 32.6 12/26/2012 16:00 5.2 12/28/2012 9:00 29.5

12/19/2012 14:00 10.4 12/21/2012 7:00 98.7 12/23/2012 0:00 78.1 12/26/2012 17:00 5.5 12/28/2012 10:00 11.2

12/19/2012 15:00 13.4 12/21/2012 8:00 55.6 12/23/2012 1:00 41.1 12/26/2012 18:00 9.9 12/28/2012 11:00 16.5

12/19/2012 16:00 266.7 12/21/2012 9:00 105.3 12/23/2012 2:00 33.6 12/26/2012 19:00 14.5 12/28/2012 12:00 7.1

12/19/2012 17:00 22.2 12/21/2012 10:00 367.7 12/23/2012 3:00 30.6 12/26/2012 20:00 12.7 12/28/2012 13:00 5.5

12/19/2012 18:00 37 12/21/2012 11:00 273.6 12/23/2012 4:00 43.1 12/26/2012 21:00 12.9 12/28/2012 14:00 5.1

12/19/2012 19:00 51.7 12/21/2012 12:00 64.6 12/23/2012 5:00 34.4 12/26/2012 22:00 17.6 12/28/2012 15:00 5.1

12/19/2012 20:00 12.6 12/21/2012 13:00 12.1 12/23/2012 6:00 102 12/26/2012 23:00 34.8 12/28/2012 16:00 4.9

12/19/2012 21:00 8.2 12/21/2012 14:00 9 12/23/2012 7:00 133.7 12/27/2012 0:00 48 12/28/2012 17:00 4.9

12/19/2012 22:00 11.1 12/21/2012 15:00 22.6 12/23/2012 8:00 55.1 12/27/2012 1:00 49.7 12/28/2012 18:00 4.8

12/19/2012 23:00 10.8 12/21/2012 16:00 41.1 12/23/2012 9:00 69.6 12/27/2012 2:00 54.3 12/28/2012 19:00 5.5

12/20/2012 0:00 22.7 12/21/2012 17:00 20 12/23/2012 10:00 22.5 12/27/2012 3:00 60.1 12/28/2012 20:00 10.8

12/20/2012 1:00 14.4 12/21/2012 18:00 102.4 12/23/2012 11:00 6.8 12/27/2012 4:00 145.7 12/28/2012 21:00 13.5

12/20/2012 2:00 12.6 12/21/2012 19:00 69.2 12/23/2012 12:00 6.2 12/27/2012 5:00 293 12/28/2012 22:00 22.3

12/20/2012 3:00 21.6 12/21/2012 20:00 42.1 12/23/2012 13:00 5.7 12/27/2012 6:00 128.2 12/28/2012 23:00 14.9

12/20/2012 4:00 68.7 12/21/2012 21:00 70.4 12/23/2012 14:00 5.5 12/27/2012 7:00 143.5 12/29/2012 0:00 18.8

12/20/2012 5:00 34.5 12/21/2012 22:00 88.4 12/23/2012 15:00 5.1 12/27/2012 8:00 220.1 12/29/2012 1:00 27.3

12/20/2012 6:00 109.3 12/21/2012 23:00 95.6 12/23/2012 16:00 4.9 12/27/2012 9:00 76.2 12/29/2012 2:00 42.2

12/20/2012 7:00 96.7 12/22/2012 0:00 240.2 12/23/2012 17:00 5.4 12/27/2012 10:00 16.4 12/29/2012 3:00 95.3

12/20/2012 8:00 43.1 12/22/2012 1:00 196.5 12/23/2012 18:00 5.2 12/27/2012 11:00 11.4 12/29/2012 4:00 57.9

12/20/2012 9:00 20 12/22/2012 2:00 81.2 12/23/2012 19:00 5.3 12/27/2012 12:00 9.5 12/29/2012 5:00 67.1

12/20/2012 10:00 15.5 12/22/2012 3:00 28.5 12/23/2012 20:00 5.6 12/27/2012 13:00 6.2 12/29/2012 6:00 48.2

12/20/2012 11:00 12.9 12/22/2012 4:00 12.4 12/23/2012 21:00 6.2 12/27/2012 14:00 5.7 12/29/2012 7:00 18.9

12/20/2012 12:00 7.8 12/22/2012 5:00 60.4 12/23/2012 22:00 10.7 12/27/2012 15:00 5.8 12/29/2012 8:00 32.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 55
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/29/2012 9:00 29.3 1/2/2013 2:00 26.5 1/3/2013 19:00 56.9 1/5/2013 12:00 96.5 1/7/2013 5:00 55.6

12/29/2012 10:00 29.1 1/2/2013 3:00 30.7 1/3/2013 20:00 40.8 1/5/2013 13:00 285.9 1/7/2013 6:00 38.8

12/29/2012 11:00 10.5 1/2/2013 4:00 36.2 1/3/2013 21:00 37.2 1/5/2013 14:00 84.7 1/7/2013 7:00 149.9

12/29/2012 12:00 7.4 1/2/2013 5:00 27.3 1/3/2013 22:00 47.6 1/5/2013 15:00 74.4 1/7/2013 8:00 247.8

12/29/2012 13:00 5.9 1/2/2013 6:00 20.6 1/3/2013 23:00 50.3 1/5/2013 16:00 244.8 1/7/2013 9:00 709.2

12/29/2012 14:00 5.2 1/2/2013 7:00 31.4 1/4/2013 0:00 78.3 1/5/2013 17:00 7.7 1/7/2013 10:00 18.3

12/29/2012 15:00 4.9 1/2/2013 8:00 13.2 1/4/2013 1:00 56.3 1/5/2013 18:00 63.9 1/7/2013 11:00 12.2

12/29/2012 16:00 4.8 1/2/2013 9:00 17.6 1/4/2013 2:00 58.3 1/5/2013 19:00 161.2 1/7/2013 12:00 11.9

12/29/2012 17:00 5 1/2/2013 10:00 17.3 1/4/2013 3:00 33.7 1/5/2013 20:00 58.7 1/7/2013 13:00 7.5

12/29/2012 18:00 5.6 1/2/2013 11:00 11.9 1/4/2013 4:00 58.9 1/5/2013 21:00 22 1/7/2013 14:00 7.1

12/29/2012 19:00 5.2 1/2/2013 12:00 10.6 1/4/2013 5:00 80.9 1/5/2013 22:00 20.7 1/7/2013 15:00

12/29/2012 20:00 10.6 1/2/2013 13:00 7 1/4/2013 6:00 95.2 1/5/2013 23:00 86.6 1/7/2013 16:00 10.5

12/29/2012 21:00 49.1 1/2/2013 14:00 7 1/4/2013 7:00 54.1 1/6/2013 0:00 24.1 1/7/2013 17:00 5.2

12/29/2012 22:00 61 1/2/2013 15:00 7.2 1/4/2013 8:00 28.7 1/6/2013 1:00 120.9 1/7/2013 18:00 80.9

12/29/2012 23:00 66.2 1/2/2013 16:00 16.9 1/4/2013 9:00 25.9 1/6/2013 2:00 135.6 1/7/2013 19:00 479.5

12/30/2012 0:00 45 1/2/2013 17:00 16.8 1/4/2013 10:00 372.3 1/6/2013 3:00 74.4 1/7/2013 20:00 142.1

12/30/2012 1:00 33.4 1/2/2013 18:00 24.5 1/4/2013 11:00 375.8 1/6/2013 4:00 38.7 1/7/2013 21:00 70.8

12/30/2012 2:00 42.9 1/2/2013 19:00 37.2 1/4/2013 12:00 20.1 1/6/2013 5:00 9.6 1/7/2013 22:00 37.2

12/30/2012 3:00 207.7 1/2/2013 20:00 42.3 1/4/2013 13:00 38.9 1/6/2013 6:00 74.2 1/7/2013 23:00 78.6

12/30/2012 4:00 140 1/2/2013 21:00 51.6 1/4/2013 14:00 15.1 1/6/2013 7:00 9.4 1/8/2013 0:00 196.8

12/30/2012 5:00 106.7 1/2/2013 22:00 30.8 1/4/2013 15:00 18.5 1/6/2013 8:00 53.1 1/8/2013 1:00 105.6

12/30/2012 6:00 85.1 1/2/2013 23:00 13.6 1/4/2013 16:00 288.3 1/6/2013 9:00 55.5 1/8/2013 2:00 38.3

12/30/2012 7:00 36.2 1/3/2013 0:00 14.9 1/4/2013 17:00 66.6 1/6/2013 10:00 116.8 1/8/2013 3:00 88

12/30/2012 8:00 21.6 1/3/2013 1:00 41 1/4/2013 18:00 202.2 1/6/2013 11:00 15.4 1/8/2013 4:00 141.5

12/30/2012 9:00 78.8 1/3/2013 2:00 89.8 1/4/2013 19:00 36.1 1/6/2013 12:00 36.6 1/8/2013 5:00 66.1

12/30/2012 10:00 11.9 1/3/2013 3:00 78.8 1/4/2013 20:00 134.4 1/6/2013 13:00 13.6 1/8/2013 6:00 162.9

12/30/2012 11:00 7.3 1/3/2013 4:00 65.1 1/4/2013 21:00 10.4 1/6/2013 14:00 15.7 1/8/2013 7:00 44.2

12/30/2012 12:00 5.9 1/3/2013 5:00 55.5 1/4/2013 22:00 8.4 1/6/2013 15:00 11.4 1/8/2013 8:00 166.8

12/30/2012 13:00 5.4 1/3/2013 6:00 62.3 1/4/2013 23:00 23.4 1/6/2013 16:00 10.6 1/8/2013 9:00 44.1

12/30/2012 14:00 5.1 1/3/2013 7:00 52.1 1/5/2013 0:00 5.5 1/6/2013 17:00 40.7 1/8/2013 10:00 8.1

12/30/2012 15:00 5 1/3/2013 8:00 93.3 1/5/2013 1:00 5.1 1/6/2013 18:00 224 1/8/2013 11:00 10

12/30/2012 16:00 4.9 1/3/2013 9:00 88.6 1/5/2013 2:00 4.6 1/6/2013 19:00 259.4 1/8/2013 12:00 9.9

12/30/2012 17:00 4.8 1/3/2013 10:00 17.5 1/5/2013 3:00 4.4 1/6/2013 20:00 233.4 1/8/2013 13:00 11.6

12/30/2012 18:00 4.7 1/3/2013 11:00 6.6 1/5/2013 4:00 4.4 1/6/2013 21:00 85.5 1/8/2013 14:00

12/30/2012 19:00 4.6 1/3/2013 12:00 7.4 1/5/2013 5:00 4.8 1/6/2013 22:00 358.6 1/8/2013 15:00 14.8

12/30/2012 20:00 4.5 1/3/2013 13:00 5.6 1/5/2013 6:00 4.4 1/6/2013 23:00 271 1/8/2013 16:00 76

12/30/2012 21:00 4.4 1/3/2013 14:00 5.4 1/5/2013 7:00 20.2 1/7/2013 0:00 372.6 1/8/2013 17:00 50.1

12/30/2012 22:00 4.4 1/3/2013 15:00 6.5 1/5/2013 8:00 9.9 1/7/2013 1:00 390.3 1/8/2013 18:00 106.6

12/30/2012 23:00 4.3 1/3/2013 16:00 9.7 1/5/2013 9:00 22.2 1/7/2013 2:00 179.5 1/8/2013 19:00 69.7

1/2/2013 0:00 75.9 1/3/2013 17:00 14.1 1/5/2013 10:00 9.8 1/7/2013 3:00 101.4 1/8/2013 20:00 55.5

1/2/2013 1:00 44.4 1/3/2013 18:00 62.6 1/5/2013 11:00 169 1/7/2013 4:00 376.4 1/8/2013 21:00 90.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 56
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

1/8/2013 22:00 96.8 1/10/2013 15:00 21.8 1/20/2013 8:00 16.1 1/23/2013 1:00 50 1/24/2013 18:00 4.6

1/8/2013 23:00 47.4 1/10/2013 16:00 7 1/20/2013 9:00 9.7 1/23/2013 2:00 61.9 1/24/2013 19:00 5

1/9/2013 0:00 83.3 1/10/2013 17:00 343.5 1/20/2013 10:00 9.4 1/23/2013 3:00 78.4 1/24/2013 20:00 10.3

1/9/2013 1:00 100.2 1/10/2013 18:00 73.1 1/20/2013 11:00 8.9 1/23/2013 4:00 105.9 1/24/2013 21:00 20.6

1/9/2013 2:00 71.3 1/10/2013 19:00 15.8 1/20/2013 12:00 1/23/2013 5:00 311.1 1/24/2013 22:00 35.5

1/9/2013 3:00 17.7 1/10/2013 20:00 10.4 1/20/2013 13:00 10.9 1/23/2013 6:00 412.2 1/24/2013 23:00 20.1

1/9/2013 4:00 20.1 1/10/2013 21:00 9.1 1/20/2013 14:00 14.2 1/23/2013 7:00 245.5 1/26/2013 0:00 53.4

1/9/2013 5:00 14.4 1/10/2013 22:00 6.8 1/20/2013 15:00 13 1/23/2013 8:00 196.8 1/26/2013 1:00 61.8

1/9/2013 6:00 15 1/10/2013 23:00 5.7 1/20/2013 16:00 12.5 1/23/2013 9:00 147 1/26/2013 2:00 84.8

1/9/2013 7:00 39.3 1/11/2013 0:00 5.5 1/20/2013 17:00 10.7 1/23/2013 10:00 23.7 1/26/2013 3:00 73.1

1/9/2013 8:00 27.6 1/11/2013 1:00 22.4 1/20/2013 18:00 9.3 1/23/2013 11:00 13.4 1/26/2013 4:00 81

1/9/2013 9:00 9.8 1/11/2013 2:00 53.3 1/20/2013 19:00 9 1/23/2013 12:00 11.6 1/26/2013 5:00 73

1/9/2013 10:00 18.1 1/11/2013 3:00 62.5 1/20/2013 20:00 8.8 1/23/2013 13:00 6.3 1/26/2013 6:00 111.2

1/9/2013 11:00 11.2 1/11/2013 4:00 31.3 1/20/2013 21:00 7.9 1/23/2013 14:00 6.2 1/26/2013 7:00 254.8

1/9/2013 12:00 9.9 1/11/2013 5:00 44.9 1/20/2013 22:00 7.1 1/23/2013 15:00 5.7 1/26/2013 8:00 245.5

1/9/2013 13:00 12.8 1/11/2013 6:00 63.3 1/20/2013 23:00 13.4 1/23/2013 16:00 5.5 1/26/2013 9:00 43.3

1/9/2013 14:00 7 1/11/2013 7:00 40.8 1/21/2013 0:00 59.7 1/23/2013 17:00 5.4 1/26/2013 10:00 9.1

1/9/2013 15:00 6.3 1/11/2013 8:00 141.5 1/21/2013 1:00 68.1 1/23/2013 18:00 5.3 1/26/2013 11:00 7.7

1/9/2013 16:00 6 1/11/2013 9:00 251.1 1/21/2013 2:00 86.6 1/23/2013 19:00 6.1 1/26/2013 12:00 5.2

1/9/2013 17:00 6.2 1/11/2013 10:00 169.4 1/21/2013 3:00 125.2 1/23/2013 20:00 9.2 1/26/2013 13:00 4.7

1/9/2013 18:00 13.6 1/11/2013 11:00 90.2 1/21/2013 4:00 133.9 1/23/2013 21:00 10.5 1/26/2013 14:00 4.6

1/9/2013 19:00 17.5 1/11/2013 12:00 52.3 1/21/2013 5:00 102.2 1/23/2013 22:00 21.6 1/26/2013 15:00 5

1/9/2013 20:00 23.2 1/11/2013 13:00 31.2 1/21/2013 6:00 65.7 1/23/2013 23:00 27.3 1/26/2013 16:00 5

1/9/2013 21:00 12 1/11/2013 14:00 22.7 1/21/2013 7:00 55.7 1/24/2013 0:00 42.3 1/26/2013 17:00 5

1/9/2013 22:00 16.8 1/11/2013 15:00 17.9 1/21/2013 8:00 50.9 1/24/2013 1:00 98.9 1/26/2013 18:00 5

1/9/2013 23:00 17.1 1/11/2013 16:00 14.1 1/21/2013 9:00 109.7 1/24/2013 2:00 37.7 1/26/2013 19:00 5

1/10/2013 0:00 17.4 1/11/2013 17:00 20 1/21/2013 10:00 174.2 1/24/2013 3:00 36.2 1/26/2013 20:00 4.8

1/10/2013 1:00 42.7 1/11/2013 18:00 16.3 1/21/2013 11:00 107 1/24/2013 4:00 15.6 1/26/2013 21:00 4.6

1/10/2013 2:00 34.4 1/11/2013 19:00 15.3 1/21/2013 12:00 54.5 1/24/2013 5:00 18.5 1/26/2013 22:00 4.4

1/10/2013 3:00 33.5 1/11/2013 20:00 17.4 1/21/2013 13:00 33.1 1/24/2013 6:00 8.3 1/26/2013 23:00 4.4

1/10/2013 4:00 112.7 1/11/2013 21:00 59.3 1/21/2013 14:00 29.3 1/24/2013 7:00 5.9 2/1/2013 0:00 27.6

1/10/2013 5:00 126.4 1/11/2013 22:00 54.5 1/21/2013 15:00 1/24/2013 8:00 5.7 2/1/2013 1:00 36.7

1/10/2013 6:00 97.9 1/11/2013 23:00 97 1/21/2013 16:00 21.7 1/24/2013 9:00 5.4 2/1/2013 2:00 44.3

1/10/2013 7:00 49.1 1/20/2013 0:00 29.5 1/21/2013 17:00 1/24/2013 10:00 5.1 2/1/2013 3:00 60

1/10/2013 8:00 51.9 1/20/2013 1:00 19.5 1/21/2013 18:00 21.6 1/24/2013 11:00 4.9 2/1/2013 4:00 77.1

1/10/2013 9:00 77.6 1/20/2013 2:00 43.3 1/21/2013 19:00 16.8 1/24/2013 12:00 4.8 2/1/2013 5:00 81.4

1/10/2013 10:00 80.5 1/20/2013 3:00 91.5 1/21/2013 20:00 19.6 1/24/2013 13:00 4.8 2/1/2013 6:00 70.6

1/10/2013 11:00 65.9 1/20/2013 4:00 83.4 1/21/2013 21:00 24.6 1/24/2013 14:00 5 2/1/2013 7:00 52.2

1/10/2013 12:00 11.2 1/20/2013 5:00 52.9 1/21/2013 22:00 15.8 1/24/2013 15:00 5.1 2/1/2013 8:00 50.5

1/10/2013 13:00 9.8 1/20/2013 6:00 18.3 1/21/2013 23:00 30.1 1/24/2013 16:00 4.6 2/1/2013 9:00 49.8

1/10/2013 14:00 9.1 1/20/2013 7:00 20.1 1/23/2013 0:00 20.9 1/24/2013 17:00 4.6 2/1/2013 10:00 53.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 57
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/1/2013 11:00 131.7 2/3/2013 4:00 153.4 2/4/2013 21:00 18 2/6/2013 14:00 11.6 2/9/2013 7:00 185.8

2/1/2013 12:00 39.8 2/3/2013 5:00 106.8 2/4/2013 22:00 62.4 2/6/2013 15:00 7.5 2/9/2013 8:00 117.5

2/1/2013 13:00 14.9 2/3/2013 6:00 80 2/4/2013 23:00 59.5 2/6/2013 16:00 6 2/9/2013 9:00 128

2/1/2013 14:00 9.9 2/3/2013 7:00 62.3 2/5/2013 0:00 36.7 2/6/2013 17:00 5.6 2/9/2013 10:00 67.9

2/1/2013 15:00 6.8 2/3/2013 8:00 68.6 2/5/2013 1:00 39.5 2/6/2013 18:00 5.6 2/9/2013 11:00 30.5

2/1/2013 16:00 9 2/3/2013 9:00 49.3 2/5/2013 2:00 93 2/6/2013 19:00 6.2 2/9/2013 12:00 13.7

2/1/2013 17:00 142.1 2/3/2013 10:00 37.4 2/5/2013 3:00 50.3 2/6/2013 20:00 10.5 2/9/2013 13:00 11

2/1/2013 18:00 56.2 2/3/2013 11:00 33.9 2/5/2013 4:00 40.3 2/6/2013 21:00 20.3 2/9/2013 14:00 13.6

2/1/2013 19:00 41.5 2/3/2013 12:00 44.2 2/5/2013 5:00 32.7 2/6/2013 22:00 52.7 2/9/2013 15:00 8.9

2/1/2013 20:00 41.3 2/3/2013 13:00 38.3 2/5/2013 6:00 54.8 2/6/2013 23:00 70.6 2/9/2013 16:00 7.8

2/1/2013 21:00 24.1 2/3/2013 14:00 14 2/5/2013 7:00 82.8 2/8/2013 0:00 51.9 2/9/2013 17:00 8.2

2/1/2013 22:00 98.7 2/3/2013 15:00 12.3 2/5/2013 8:00 81.8 2/8/2013 1:00 68.4 2/9/2013 18:00 8.9

2/1/2013 23:00 67.8 2/3/2013 16:00 18.7 2/5/2013 9:00 37.4 2/8/2013 2:00 55.4 2/9/2013 19:00 20.1

2/2/2013 0:00 84.1 2/3/2013 17:00 18.8 2/5/2013 10:00 17.7 2/8/2013 3:00 90.8 2/9/2013 20:00 43

2/2/2013 1:00 28.7 2/3/2013 18:00 16.8 2/5/2013 11:00 12.8 2/8/2013 4:00 347.4 2/9/2013 21:00 42.3

2/2/2013 2:00 8.9 2/3/2013 19:00 15.9 2/5/2013 12:00 14 2/8/2013 5:00 222.1 2/9/2013 22:00 17.7

2/2/2013 3:00 7.1 2/3/2013 20:00 27.8 2/5/2013 13:00 10 2/8/2013 6:00 116.4 2/9/2013 23:00 42.8

2/2/2013 4:00 8.1 2/3/2013 21:00 46.1 2/5/2013 14:00 2/8/2013 7:00 80.5 2/10/2013 0:00 148.4

2/2/2013 5:00 12.9 2/3/2013 22:00 52.1 2/5/2013 15:00 12.3 2/8/2013 8:00 83.6 2/10/2013 1:00 82.4

2/2/2013 6:00 23.7 2/3/2013 23:00 45 2/5/2013 16:00 8.4 2/8/2013 9:00 72.8 2/10/2013 2:00 50.8

2/2/2013 7:00 107.3 2/4/2013 0:00 116.2 2/5/2013 17:00 8.4 2/8/2013 10:00 45.1 2/10/2013 3:00 19.9

2/2/2013 8:00 161.7 2/4/2013 1:00 87.8 2/5/2013 18:00 9 2/8/2013 11:00 14.4 2/10/2013 4:00 45.3

2/2/2013 9:00 88.7 2/4/2013 2:00 64.9 2/5/2013 19:00 9.4 2/8/2013 12:00 9.6 2/10/2013 5:00 76.2

2/2/2013 10:00 13.1 2/4/2013 3:00 45.3 2/5/2013 20:00 19.1 2/8/2013 13:00 7.3 2/10/2013 6:00 60.8

2/2/2013 11:00 7.8 2/4/2013 4:00 64.6 2/5/2013 21:00 55.9 2/8/2013 14:00 6.1 2/10/2013 7:00 20.7

2/2/2013 12:00 6.3 2/4/2013 5:00 90.5 2/5/2013 22:00 26.2 2/8/2013 15:00 5.6 2/10/2013 8:00 88.5

2/2/2013 13:00 5.6 2/4/2013 6:00 99.3 2/5/2013 23:00 19.2 2/8/2013 16:00 5.4 2/10/2013 9:00 129.8

2/2/2013 14:00 5.2 2/4/2013 7:00 69.2 2/6/2013 0:00 42 2/8/2013 17:00 5.3 2/10/2013 10:00 28.3

2/2/2013 15:00 5.5 2/4/2013 8:00 159.1 2/6/2013 1:00 112.8 2/8/2013 18:00 5.3 2/10/2013 11:00 9.9

2/2/2013 16:00 5.4 2/4/2013 9:00 176.6 2/6/2013 2:00 81.9 2/8/2013 19:00 6.5 2/10/2013 12:00 10.6

2/2/2013 17:00 8 2/4/2013 10:00 156.2 2/6/2013 3:00 63.6 2/8/2013 20:00 7.3 2/10/2013 13:00 10.5

2/2/2013 18:00 12 2/4/2013 11:00 8.6 2/6/2013 4:00 63 2/8/2013 21:00 9 2/10/2013 14:00 9.3

2/2/2013 19:00 12.2 2/4/2013 12:00 7.1 2/6/2013 5:00 85.6 2/8/2013 22:00 18.5 2/10/2013 15:00 9.6

2/2/2013 20:00 70.8 2/4/2013 13:00 12.4 2/6/2013 6:00 48.8 2/8/2013 23:00 34.7 2/10/2013 16:00 49.2

2/2/2013 21:00 81.5 2/4/2013 14:00 11 2/6/2013 7:00 53.8 2/9/2013 0:00 60.9 2/10/2013 17:00 150.9

2/2/2013 22:00 91 2/4/2013 15:00 2/6/2013 8:00 57.7 2/9/2013 1:00 75.8 2/10/2013 18:00 47.3

2/2/2013 23:00 384.5 2/4/2013 16:00 9.2 2/6/2013 9:00 27.6 2/9/2013 2:00 97.5 2/10/2013 19:00 39.2

2/3/2013 0:00 856.9 2/4/2013 17:00 7.4 2/6/2013 10:00 28.3 2/9/2013 3:00 328.7 2/10/2013 20:00 66.2

2/3/2013 1:00 400.1 2/4/2013 18:00 9 2/6/2013 11:00 2/9/2013 4:00 664 2/10/2013 21:00 81.7

2/3/2013 2:00 253.1 2/4/2013 19:00 11.5 2/6/2013 12:00 2/9/2013 5:00 533.8 2/10/2013 22:00 77.9

2/3/2013 3:00 161.2 2/4/2013 20:00 11.5 2/6/2013 13:00 2/9/2013 6:00 350.4 2/10/2013 23:00 46.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 58
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/11/2013 0:00 11.9 2/12/2013 17:00 14 2/14/2013 10:00 16.4 2/16/2013 3:00 18.5 2/17/2013 20:00 261.6

2/11/2013 1:00 5.7 2/12/2013 18:00 14 2/14/2013 11:00 20.1 2/16/2013 4:00 21.7 2/17/2013 21:00 122.8

2/11/2013 2:00 68.9 2/12/2013 19:00 18.4 2/14/2013 12:00 8.9 2/16/2013 5:00 27.6 2/17/2013 22:00 101.4

2/11/2013 3:00 38.8 2/12/2013 20:00 28.8 2/14/2013 13:00 6.5 2/16/2013 6:00 59.6 2/17/2013 23:00 12.7

2/11/2013 4:00 37 2/12/2013 21:00 38.1 2/14/2013 14:00 6.3 2/16/2013 7:00 53.3 2/18/2013 0:00 6.2

2/11/2013 5:00 92.9 2/12/2013 22:00 37.5 2/14/2013 15:00 9.1 2/16/2013 8:00 35.3 2/18/2013 1:00 11.8

2/11/2013 6:00 23.3 2/12/2013 23:00 48.7 2/14/2013 16:00 13.6 2/16/2013 9:00 18 2/18/2013 2:00 18.1

2/11/2013 7:00 29.9 2/13/2013 0:00 52.2 2/14/2013 17:00 11.6 2/16/2013 10:00 21.4 2/18/2013 3:00 5.9

2/11/2013 8:00 108.8 2/13/2013 1:00 49.9 2/14/2013 18:00 10.5 2/16/2013 11:00 15.7 2/18/2013 4:00 5.3

2/11/2013 9:00 40.7 2/13/2013 2:00 70.4 2/14/2013 19:00 12.2 2/16/2013 12:00 21.5 2/18/2013 5:00 8.7

2/11/2013 10:00 12.7 2/13/2013 3:00 53.1 2/14/2013 20:00 13.4 2/16/2013 13:00 130.1 2/18/2013 6:00 6.2

2/11/2013 11:00 10.3 2/13/2013 4:00 89.6 2/14/2013 21:00 14.4 2/16/2013 14:00 59.8 2/18/2013 7:00 45.6

2/11/2013 12:00 7.4 2/13/2013 5:00 152.2 2/14/2013 22:00 26.3 2/16/2013 15:00 388.6 2/18/2013 8:00 50.9

2/11/2013 13:00 6 2/13/2013 6:00 133.2 2/14/2013 23:00 163.3 2/16/2013 16:00 219.8 2/18/2013 9:00 120.8

2/11/2013 14:00 6.9 2/13/2013 7:00 117.7 2/15/2013 0:00 158.5 2/16/2013 17:00 52 2/18/2013 10:00 56.6

2/11/2013 15:00 2/13/2013 8:00 291.1 2/15/2013 1:00 113.7 2/16/2013 18:00 45.1 2/18/2013 11:00 40.9

2/11/2013 16:00 9.4 2/13/2013 9:00 371.2 2/15/2013 2:00 110.8 2/16/2013 19:00 43.3 2/18/2013 12:00 18

2/11/2013 17:00 8 2/13/2013 10:00 164.3 2/15/2013 3:00 168.7 2/16/2013 20:00 32.1 2/18/2013 13:00 19.6

2/11/2013 18:00 9.9 2/13/2013 11:00 45.1 2/15/2013 4:00 175 2/16/2013 21:00 147.9 2/18/2013 14:00 258.2

2/11/2013 19:00 9.1 2/13/2013 12:00 25.9 2/15/2013 5:00 18.1 2/16/2013 22:00 63.3 2/18/2013 15:00

2/11/2013 20:00 22.4 2/13/2013 13:00 11.1 2/15/2013 6:00 35.2 2/16/2013 23:00 49.8 2/18/2013 16:00 20.9

2/11/2013 21:00 37.6 2/13/2013 14:00 7.6 2/15/2013 7:00 45.3 2/17/2013 0:00 93.8 2/18/2013 17:00 78.3

2/11/2013 22:00 26.2 2/13/2013 15:00 6.4 2/15/2013 8:00 100.6 2/17/2013 1:00 29 2/18/2013 18:00 352.4

2/11/2013 23:00 30.1 2/13/2013 16:00 6.8 2/15/2013 9:00 20.4 2/17/2013 2:00 8.5 2/18/2013 19:00 206.5

2/12/2013 0:00 34.6 2/13/2013 17:00 7.5 2/15/2013 10:00 11 2/17/2013 3:00 6.1 2/18/2013 20:00 252.8

2/12/2013 1:00 21.8 2/13/2013 18:00 9.2 2/15/2013 11:00 15.4 2/17/2013 4:00 5 2/18/2013 21:00 223.7

2/12/2013 2:00 19.5 2/13/2013 19:00 10.5 2/15/2013 12:00 7.7 2/17/2013 5:00 5.1 2/18/2013 22:00 94.2

2/12/2013 3:00 21.3 2/13/2013 20:00 34 2/15/2013 13:00 6.9 2/17/2013 6:00 4.9 2/18/2013 23:00 45.3

2/12/2013 4:00 25.7 2/13/2013 21:00 83 2/15/2013 14:00 57.4 2/17/2013 7:00 4.8 2/19/2013 0:00 22.7

2/12/2013 5:00 28.9 2/13/2013 22:00 86 2/15/2013 15:00 184.6 2/17/2013 8:00 5.2 2/19/2013 1:00 33.7

2/12/2013 6:00 29.2 2/13/2013 23:00 138.3 2/15/2013 16:00 132.7 2/17/2013 9:00 59.7 2/19/2013 2:00 26.1

2/12/2013 7:00 37.7 2/14/2013 0:00 167.9 2/15/2013 17:00 135.9 2/17/2013 10:00 75.2 2/19/2013 3:00 71

2/12/2013 8:00 79.8 2/14/2013 1:00 283.7 2/15/2013 18:00 63.1 2/17/2013 11:00 133.4 2/19/2013 4:00 99.4

2/12/2013 9:00 83.3 2/14/2013 2:00 268.6 2/15/2013 19:00 85.5 2/17/2013 12:00 103.3 2/19/2013 5:00 80.4

2/12/2013 10:00 86.6 2/14/2013 3:00 216.7 2/15/2013 20:00 32.2 2/17/2013 13:00 15.5 2/19/2013 6:00 53.8

2/12/2013 11:00 41.4 2/14/2013 4:00 199.4 2/15/2013 21:00 49.1 2/17/2013 14:00 15 2/19/2013 7:00 57.7

2/12/2013 12:00 29.2 2/14/2013 5:00 168.7 2/15/2013 22:00 356 2/17/2013 15:00 12.9 2/19/2013 8:00 18.5

2/12/2013 13:00 25.3 2/14/2013 6:00 293.7 2/15/2013 23:00 345.4 2/17/2013 16:00 49.2 2/19/2013 9:00 20.7

2/12/2013 14:00 2/14/2013 7:00 237.2 2/16/2013 0:00 193.1 2/17/2013 17:00 188.6 2/19/2013 10:00 68.2

2/12/2013 15:00 22.5 2/14/2013 8:00 175.7 2/16/2013 1:00 131.6 2/17/2013 18:00 23 2/19/2013 11:00 48.1

2/12/2013 16:00 12.4 2/14/2013 9:00 41.9 2/16/2013 2:00 70.7 2/17/2013 19:00 269.1 2/19/2013 12:00 47.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 59
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/19/2013 13:00 9.7 2/21/2013 6:00 60.9 2/22/2013 23:00 44.2 2/24/2013 16:00 9.1 2/26/2013 9:00 9.2

2/19/2013 14:00 2/21/2013 7:00 25.8 2/23/2013 0:00 45.7 2/24/2013 17:00 8.9 2/26/2013 10:00 83.8

2/19/2013 15:00 12.4 2/21/2013 8:00 28.1 2/23/2013 1:00 52.4 2/24/2013 18:00 17 2/26/2013 11:00 127.4

2/19/2013 16:00 16.4 2/21/2013 9:00 23.6 2/23/2013 2:00 141.7 2/24/2013 19:00 18.9 2/26/2013 12:00 304.9

2/19/2013 17:00 96.3 2/21/2013 10:00 24 2/23/2013 3:00 259.7 2/24/2013 20:00 39.5 2/26/2013 13:00 234.5

2/19/2013 18:00 123.2 2/21/2013 11:00 16.8 2/23/2013 4:00 124.8 2/24/2013 21:00 49.2 2/26/2013 14:00

2/19/2013 19:00 35 2/21/2013 12:00 9.7 2/23/2013 5:00 108.7 2/24/2013 22:00 50.8 2/26/2013 15:00 81.8

2/19/2013 20:00 15.6 2/21/2013 13:00 7.5 2/23/2013 6:00 90.1 2/24/2013 23:00 36.2 2/26/2013 16:00 175.9

2/19/2013 21:00 12.5 2/21/2013 14:00 6.2 2/23/2013 7:00 130.6 2/25/2013 0:00 17.4 2/26/2013 17:00 190.2

2/19/2013 22:00 9.4 2/21/2013 15:00 6.5 2/23/2013 8:00 50.8 2/25/2013 1:00 13.2 2/26/2013 18:00 86

2/19/2013 23:00 10.8 2/21/2013 16:00 7.2 2/23/2013 9:00 13.2 2/25/2013 2:00 21.2 2/26/2013 19:00 14.3

2/20/2013 0:00 12 2/21/2013 17:00 5.5 2/23/2013 10:00 13.4 2/25/2013 3:00 37.7 2/26/2013 20:00 28.1

2/20/2013 1:00 15.8 2/21/2013 18:00 5.6 2/23/2013 11:00 12.9 2/25/2013 4:00 31.9 2/26/2013 21:00 73.2

2/20/2013 2:00 36.1 2/21/2013 19:00 5.3 2/23/2013 12:00 10.4 2/25/2013 5:00 26.5 2/26/2013 22:00 63.5

2/20/2013 3:00 90.6 2/21/2013 20:00 6.4 2/23/2013 13:00 8.9 2/25/2013 6:00 33.2 2/26/2013 23:00 104.7

2/20/2013 4:00 135.7 2/21/2013 21:00 22.2 2/23/2013 14:00 11.9 2/25/2013 7:00 29.7 2/27/2013 0:00 30.1

2/20/2013 5:00 74.7 2/21/2013 22:00 19.4 2/23/2013 15:00 9.9 2/25/2013 8:00 43.1 2/27/2013 1:00 256.1

2/20/2013 6:00 100.4 2/21/2013 23:00 17.6 2/23/2013 16:00 15.4 2/25/2013 9:00 108.6 2/27/2013 2:00 161.1

2/20/2013 7:00 113.1 2/22/2013 0:00 39.8 2/23/2013 17:00 14.7 2/25/2013 10:00 59.1 2/27/2013 3:00 66.9

2/20/2013 8:00 87.1 2/22/2013 1:00 31.3 2/23/2013 18:00 21.5 2/25/2013 11:00 9 2/27/2013 4:00 42.5

2/20/2013 9:00 28.7 2/22/2013 2:00 25.3 2/23/2013 19:00 38 2/25/2013 12:00 8 2/27/2013 5:00 185.7

2/20/2013 10:00 19.1 2/22/2013 3:00 18.4 2/23/2013 20:00 23.4 2/25/2013 13:00 11.6 2/27/2013 6:00 156.1

2/20/2013 11:00 234.9 2/22/2013 4:00 35.1 2/23/2013 21:00 43.8 2/25/2013 14:00 14.1 2/27/2013 7:00 139.4

2/20/2013 12:00 271.8 2/22/2013 5:00 16.4 2/23/2013 22:00 109 2/25/2013 15:00 2/27/2013 8:00 93.5

2/20/2013 13:00 26.3 2/22/2013 6:00 8.3 2/23/2013 23:00 44.4 2/25/2013 16:00 26.3 2/27/2013 9:00 13.7

2/20/2013 14:00 19.3 2/22/2013 7:00 6.3 2/24/2013 0:00 103.6 2/25/2013 17:00 11.3 2/27/2013 10:00 7.6

2/20/2013 15:00 22.1 2/22/2013 8:00 18.4 2/24/2013 1:00 49.2 2/25/2013 18:00 11.4 2/27/2013 11:00 6.8

2/20/2013 16:00 38.8 2/22/2013 9:00 18.7 2/24/2013 2:00 39.4 2/25/2013 19:00 11.9 2/27/2013 12:00 11.6

2/20/2013 17:00 35.3 2/22/2013 10:00 38.2 2/24/2013 3:00 56.8 2/25/2013 20:00 20.9 2/27/2013 13:00 15.3

2/20/2013 18:00 48.2 2/22/2013 11:00 55.1 2/24/2013 4:00 45.3 2/25/2013 21:00 32.5 2/27/2013 14:00 14.9

2/20/2013 19:00 53.5 2/22/2013 12:00 35.9 2/24/2013 5:00 22.9 2/25/2013 22:00 89 2/27/2013 15:00 22.4

2/20/2013 20:00 48.7 2/22/2013 13:00 40 2/24/2013 6:00 23.8 2/25/2013 23:00 63.9 2/27/2013 16:00 8.6

2/20/2013 21:00 32.7 2/22/2013 14:00 31.3 2/24/2013 7:00 33.2 2/26/2013 0:00 44.4 2/27/2013 17:00 17

2/20/2013 22:00 44.6 2/22/2013 15:00 24.7 2/24/2013 8:00 107.6 2/26/2013 1:00 42.7 2/27/2013 18:00 26.8

2/20/2013 23:00 51.3 2/22/2013 16:00 45.7 2/24/2013 9:00 240.5 2/26/2013 2:00 51.3 2/27/2013 19:00 85

2/21/2013 0:00 27.1 2/22/2013 17:00 12.2 2/24/2013 10:00 166.8 2/26/2013 3:00 57 2/27/2013 20:00 57.6

2/21/2013 1:00 28.9 2/22/2013 18:00 7.8 2/24/2013 11:00 41.8 2/26/2013 4:00 41.3 2/27/2013 21:00 50.7

2/21/2013 2:00 49.4 2/22/2013 19:00 10.9 2/24/2013 12:00 16 2/26/2013 5:00 46.1 2/27/2013 22:00 38.1

2/21/2013 3:00 79.2 2/22/2013 20:00 84.6 2/24/2013 13:00 13.3 2/26/2013 6:00 41.2 2/27/2013 23:00 92.5

2/21/2013 4:00 63.5 2/22/2013 21:00 69.3 2/24/2013 14:00 13.4 2/26/2013 7:00 29.9 2/28/2013 0:00 193.2

2/21/2013 5:00 58.4 2/22/2013 22:00 50.5 2/24/2013 15:00 10.8 2/26/2013 8:00 55.3 2/28/2013 1:00 190.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 60
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/28/2013 2:00 112.1 3/1/2013 19:00 23.3 3/3/2013 12:00 10.9 3/5/2013 5:00 108.1 3/6/2013 22:00 7.5

2/28/2013 3:00 154 3/1/2013 20:00 18.3 3/3/2013 13:00 6.6 3/5/2013 6:00 106.4 3/6/2013 23:00 8.2

2/28/2013 4:00 212.9 3/1/2013 21:00 25.8 3/3/2013 14:00 7.8 3/5/2013 7:00 130.9 3/8/2013 0:00 187.5

2/28/2013 5:00 181.8 3/1/2013 22:00 15.7 3/3/2013 15:00 9.1 3/5/2013 8:00 113.9 3/8/2013 1:00 222.1

2/28/2013 6:00 198.1 3/1/2013 23:00 14 3/3/2013 16:00 14.9 3/5/2013 9:00 86.6 3/8/2013 2:00 122.6

2/28/2013 7:00 47.2 3/2/2013 0:00 12.1 3/3/2013 17:00 17.1 3/5/2013 10:00 18.6 3/8/2013 3:00 77.8

2/28/2013 8:00 329.9 3/2/2013 1:00 46.7 3/3/2013 18:00 15.1 3/5/2013 11:00 12.8 3/8/2013 4:00 79.2

2/28/2013 9:00 215.7 3/2/2013 2:00 53.1 3/3/2013 19:00 16 3/5/2013 12:00 10.7 3/8/2013 5:00 62.8

2/28/2013 10:00 53.3 3/2/2013 3:00 21.1 3/3/2013 20:00 15.1 3/5/2013 13:00 7.3 3/8/2013 6:00 72

2/28/2013 11:00 73.3 3/2/2013 4:00 18.5 3/3/2013 21:00 20.6 3/5/2013 14:00 3/8/2013 7:00 43.7

2/28/2013 12:00 18.8 3/2/2013 5:00 24.2 3/3/2013 22:00 59.8 3/5/2013 15:00 8.8 3/8/2013 8:00 24.6

2/28/2013 13:00 8.5 3/2/2013 6:00 28.9 3/3/2013 23:00 98.2 3/5/2013 16:00 6.7 3/8/2013 9:00 12.3

2/28/2013 14:00 9.4 3/2/2013 7:00 21.4 3/4/2013 0:00 120.7 3/5/2013 17:00 6 3/8/2013 10:00 7.8

2/28/2013 15:00 8.3 3/2/2013 8:00 7 3/4/2013 1:00 103.3 3/5/2013 18:00 6.1 3/8/2013 11:00 6.7

2/28/2013 16:00 9.4 3/2/2013 9:00 18.8 3/4/2013 2:00 78.6 3/5/2013 19:00 9.6 3/8/2013 12:00 6.1

2/28/2013 17:00 13.4 3/2/2013 10:00 28.2 3/4/2013 3:00 85.7 3/5/2013 20:00 10.2 3/8/2013 13:00 5.5

2/28/2013 18:00 19 3/2/2013 11:00 21.5 3/4/2013 4:00 148 3/5/2013 21:00 11.3 3/8/2013 14:00 5.1

2/28/2013 19:00 19 3/2/2013 12:00 182.6 3/4/2013 5:00 252 3/5/2013 22:00 14.9 3/8/2013 15:00 5.1

2/28/2013 20:00 21.2 3/2/2013 13:00 233.6 3/4/2013 6:00 308.7 3/5/2013 23:00 14 3/8/2013 16:00 5.1

2/28/2013 21:00 23 3/2/2013 14:00 11.4 3/4/2013 7:00 232.2 3/6/2013 0:00 44.1 3/8/2013 17:00 4.9

2/28/2013 22:00 31.4 3/2/2013 15:00 10.6 3/4/2013 8:00 249 3/6/2013 1:00 91.8 3/8/2013 18:00 4.9

2/28/2013 23:00 75.7 3/2/2013 16:00 6.2 3/4/2013 9:00 273 3/6/2013 2:00 65 3/8/2013 19:00 5.1

3/1/2013 0:00 110.2 3/2/2013 17:00 16.9 3/4/2013 10:00 198.6 3/6/2013 3:00 167.2 3/8/2013 20:00 5

3/1/2013 1:00 96.4 3/2/2013 18:00 19.7 3/4/2013 11:00 22.7 3/6/2013 4:00 184.3 3/8/2013 21:00 5

3/1/2013 2:00 66.2 3/2/2013 19:00 17.1 3/4/2013 12:00 10 3/6/2013 5:00 163 3/8/2013 22:00 4.9

3/1/2013 3:00 65.1 3/2/2013 20:00 48.8 3/4/2013 13:00 8.8 3/6/2013 6:00 121.3 3/8/2013 23:00 4.8

3/1/2013 4:00 97.2 3/2/2013 21:00 69.3 3/4/2013 14:00 9.2 3/6/2013 7:00 112.6 3/13/2013 0:00 13.4

3/1/2013 5:00 133.1 3/2/2013 22:00 77.1 3/4/2013 15:00 3/6/2013 8:00 94.4 3/13/2013 1:00 20.8

3/1/2013 6:00 101.2 3/2/2013 23:00 75.2 3/4/2013 16:00 18.8 3/6/2013 9:00 48.8 3/13/2013 2:00 19.8

3/1/2013 7:00 95.1 3/3/2013 0:00 68.3 3/4/2013 17:00 16.2 3/6/2013 10:00 16.9 3/13/2013 3:00 20.6

3/1/2013 8:00 99.9 3/3/2013 1:00 68.8 3/4/2013 18:00 13.7 3/6/2013 11:00 16.8 3/13/2013 4:00 33.1

3/1/2013 9:00 68.9 3/3/2013 2:00 59.4 3/4/2013 19:00 12.9 3/6/2013 12:00 10.4 3/13/2013 5:00 44.3

3/1/2013 10:00 49.6 3/3/2013 3:00 66.5 3/4/2013 20:00 12 3/6/2013 13:00 7 3/13/2013 6:00 40.4

3/1/2013 11:00 193.8 3/3/2013 4:00 101.7 3/4/2013 21:00 16.9 3/6/2013 14:00 6.4 3/13/2013 7:00 31.8

3/1/2013 12:00 36 3/3/2013 5:00 94.2 3/4/2013 22:00 71.6 3/6/2013 15:00 5.8 3/13/2013 8:00 104.1

3/1/2013 13:00 191.4 3/3/2013 6:00 75 3/4/2013 23:00 40.9 3/6/2013 16:00 5.5 3/13/2013 9:00 138.7

3/1/2013 14:00 190.5 3/3/2013 7:00 53.7 3/5/2013 0:00 38.3 3/6/2013 17:00 5.2 3/13/2013 10:00 33.6

3/1/2013 15:00 84.7 3/3/2013 8:00 94.1 3/5/2013 1:00 40.6 3/6/2013 18:00 5.3 3/13/2013 11:00 20.1

3/1/2013 16:00 84.8 3/3/2013 9:00 37.5 3/5/2013 2:00 75.3 3/6/2013 19:00 5.3 3/13/2013 12:00 11.1

3/1/2013 17:00 8.9 3/3/2013 10:00 18.1 3/5/2013 3:00 47.4 3/6/2013 20:00 5.4 3/13/2013 13:00 7.7

3/1/2013 18:00 25.1 3/3/2013 11:00 15.9 3/5/2013 4:00 49.6 3/6/2013 21:00 6.6 3/13/2013 14:00 6.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 61
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

3/13/2013 15:00 5.9 3/28/2013 8:00 70.7 4/4/2013 1:00 16.4 4/5/2013 18:00 5.4 4/7/2013 11:00 7.5

3/13/2013 16:00 5.6 3/28/2013 9:00 49.8 4/4/2013 2:00 22 4/5/2013 19:00 5.6 4/7/2013 12:00 6.6

3/13/2013 17:00 5.5 3/28/2013 10:00 23.4 4/4/2013 3:00 28.7 4/5/2013 20:00 6.3 4/7/2013 13:00 6

3/13/2013 18:00 5.4 3/28/2013 11:00 15.7 4/4/2013 4:00 31.7 4/5/2013 21:00 27.8 4/7/2013 14:00 6

3/13/2013 19:00 5.4 3/28/2013 12:00 8.9 4/4/2013 5:00 36 4/5/2013 22:00 24.3 4/7/2013 15:00 5.6

3/13/2013 20:00 5.5 3/28/2013 13:00 7 4/4/2013 6:00 47.7 4/5/2013 23:00 55.2 4/7/2013 16:00 5.7

3/13/2013 21:00 6.5 3/28/2013 14:00 6.3 4/4/2013 7:00 66.4 4/6/2013 0:00 62.3 4/7/2013 17:00 5.6

3/13/2013 22:00 8.9 3/28/2013 15:00 12.1 4/4/2013 8:00 156.4 4/6/2013 1:00 75.8 4/7/2013 18:00 5.5

3/13/2013 23:00 11.5 3/28/2013 16:00 32.1 4/4/2013 9:00 143.3 4/6/2013 2:00 99.9 4/7/2013 19:00 5.7

3/19/2013 0:00 17.6 3/28/2013 17:00 31.2 4/4/2013 10:00 35.5 4/6/2013 3:00 70.5 4/7/2013 20:00 8.4

3/19/2013 1:00 20.6 3/28/2013 18:00 194 4/4/2013 11:00 20.9 4/6/2013 4:00 70.4 4/7/2013 21:00 10.5

3/19/2013 2:00 20.4 3/28/2013 19:00 44.9 4/4/2013 12:00 15.3 4/6/2013 5:00 149.9 4/7/2013 22:00 10.3

3/19/2013 3:00 19.9 3/28/2013 20:00 43.8 4/4/2013 13:00 13.5 4/6/2013 6:00 159.3 4/7/2013 23:00 12.8

3/19/2013 4:00 22.8 3/28/2013 21:00 48.8 4/4/2013 14:00 10.4 4/6/2013 7:00 151.8 4/9/2013 0:00 5.8

3/19/2013 5:00 24.5 3/28/2013 22:00 37.6 4/4/2013 15:00 9.9 4/6/2013 8:00 31.3 4/9/2013 1:00 125.8

3/19/2013 6:00 30 3/28/2013 23:00 26.1 4/4/2013 16:00 8.3 4/6/2013 9:00 12 4/9/2013 2:00 119.2

3/19/2013 7:00 41.8 4/3/2013 0:00 12.5 4/4/2013 17:00 6.8 4/6/2013 10:00 8.7 4/9/2013 3:00 103.4

3/19/2013 8:00 84 4/3/2013 1:00 22.5 4/4/2013 18:00 8.4 4/6/2013 11:00 7.1 4/9/2013 4:00 37.2

3/19/2013 9:00 51 4/3/2013 2:00 44.7 4/4/2013 19:00 14.9 4/6/2013 12:00 6 4/9/2013 5:00 66.4

3/19/2013 10:00 33.8 4/3/2013 3:00 64.8 4/4/2013 20:00 224.9 4/6/2013 13:00 5.7 4/9/2013 6:00 22.2

3/19/2013 11:00 21.7 4/3/2013 4:00 102.8 4/4/2013 21:00 235.7 4/6/2013 14:00 5.5 4/9/2013 7:00 18.1

3/19/2013 12:00 12.5 4/3/2013 5:00 86.1 4/4/2013 22:00 74 4/6/2013 15:00 5.4 4/9/2013 8:00 26.2

3/19/2013 13:00 9.5 4/3/2013 6:00 58.4 4/4/2013 23:00 68.3 4/6/2013 16:00 5.3 4/9/2013 9:00 19.9

3/19/2013 14:00 4/3/2013 7:00 53.1 4/5/2013 0:00 50.8 4/6/2013 17:00 5.2 4/9/2013 10:00 11.4

3/19/2013 15:00 9.2 4/3/2013 8:00 38.7 4/5/2013 1:00 47.6 4/6/2013 18:00 5.3 4/9/2013 11:00 7.7

3/19/2013 16:00 6.8 4/3/2013 9:00 25.9 4/5/2013 2:00 27 4/6/2013 19:00 5.6 4/9/2013 12:00 6.3

3/19/2013 17:00 5.8 4/3/2013 10:00 11.9 4/5/2013 3:00 22.7 4/6/2013 20:00 8.4 4/9/2013 13:00 5.6

3/19/2013 18:00 5.5 4/3/2013 11:00 8.6 4/5/2013 4:00 50.4 4/6/2013 21:00 12 4/9/2013 14:00

3/19/2013 19:00 5.4 4/3/2013 12:00 8.7 4/5/2013 5:00 100.5 4/6/2013 22:00 11.1 4/9/2013 15:00 7.6

3/19/2013 20:00 5.3 4/3/2013 13:00 9.4 4/5/2013 6:00 158.4 4/6/2013 23:00 11.8 4/9/2013 16:00 6

3/19/2013 21:00 5.1 4/3/2013 14:00 8.3 4/5/2013 7:00 245 4/7/2013 0:00 18 4/9/2013 17:00 5.5

3/19/2013 22:00 5 4/3/2013 15:00 7.8 4/5/2013 8:00 184.3 4/7/2013 1:00 68.8 4/9/2013 18:00 5.3

3/19/2013 23:00 4.8 4/3/2013 16:00 6.8 4/5/2013 9:00 31.9 4/7/2013 2:00 91.8 4/9/2013 19:00 5.5

3/28/2013 0:00 23.4 4/3/2013 17:00 6.2 4/5/2013 10:00 12.3 4/7/2013 3:00 128.6 4/9/2013 20:00 6.5

3/28/2013 1:00 41.8 4/3/2013 18:00 12.4 4/5/2013 11:00 9.3 4/7/2013 4:00 76.9 4/9/2013 21:00 14

3/28/2013 2:00 108.8 4/3/2013 19:00 16.2 4/5/2013 12:00 7.4 4/7/2013 5:00 103.6 4/9/2013 22:00 32.3

3/28/2013 3:00 70.5 4/3/2013 20:00 12.1 4/5/2013 13:00 6.5 4/7/2013 6:00 186.8 4/9/2013 23:00 27.4

3/28/2013 4:00 54.2 4/3/2013 21:00 11 4/5/2013 14:00 6.1 4/7/2013 7:00 251.8 4/11/2013 0:00 23.9

3/28/2013 5:00 39.4 4/3/2013 22:00 14 4/5/2013 15:00 5.8 4/7/2013 8:00 67.2 4/11/2013 1:00 17.9

3/28/2013 6:00 37.7 4/3/2013 23:00 12.4 4/5/2013 16:00 5.6 4/7/2013 9:00 25.1 4/11/2013 2:00 24.3

3/28/2013 7:00 48.6 4/4/2013 0:00 14.6 4/5/2013 17:00 5.5 4/7/2013 10:00 10.4 4/11/2013 3:00 40

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 62
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/11/2013 4:00 14.9 4/12/2013 21:00 5.1 4/17/2013 14:00 6.1 4/19/2013 7:00 92.9 4/25/2013 0:00 5.7

4/11/2013 5:00 18.2 4/12/2013 22:00 5.2 4/17/2013 15:00 4/19/2013 8:00 27 4/25/2013 1:00 5.3

4/11/2013 6:00 192.3 4/12/2013 23:00 5.5 4/17/2013 16:00 6.4 4/19/2013 9:00 13 4/25/2013 2:00 3

4/11/2013 7:00 606.9 4/16/2013 0:00 4.9 4/17/2013 17:00 4.1 4/19/2013 10:00 12.8 4/25/2013 3:00 22.8

4/11/2013 8:00 124.9 4/16/2013 1:00 5.5 4/17/2013 18:00 4/19/2013 11:00 3.1 4/25/2013 4:00 51.4

4/11/2013 9:00 17.8 4/16/2013 2:00 6.7 4/17/2013 19:00 8.5 4/19/2013 12:00 2.1 4/25/2013 5:00 86.3

4/11/2013 10:00 11.9 4/16/2013 3:00 9 4/17/2013 20:00 77.3 4/19/2013 13:00 1.5 4/25/2013 6:00 57.6

4/11/2013 11:00 9.5 4/16/2013 4:00 10.7 4/17/2013 21:00 58.8 4/19/2013 14:00 1.2 4/25/2013 7:00 85.7

4/11/2013 12:00 7.2 4/16/2013 5:00 17 4/17/2013 22:00 16.8 4/19/2013 15:00 1 4/25/2013 8:00 201.3

4/11/2013 13:00 6.3 4/16/2013 6:00 56.4 4/17/2013 23:00 17.2 4/19/2013 16:00 0.9 4/25/2013 9:00 71.7

4/11/2013 14:00 5.9 4/16/2013 7:00 53.2 4/18/2013 0:00 74.2 4/19/2013 17:00 0.8 4/25/2013 10:00 8.7

4/11/2013 15:00 6.5 4/16/2013 8:00 39.8 4/18/2013 1:00 85.4 4/19/2013 18:00 0.7 4/25/2013 11:00 3.9

4/11/2013 16:00 5.7 4/16/2013 9:00 19.9 4/18/2013 2:00 72.6 4/19/2013 19:00 1 4/25/2013 12:00 2.4

4/11/2013 17:00 5.5 4/16/2013 10:00 23.2 4/18/2013 3:00 39.5 4/19/2013 20:00 3.6 4/25/2013 13:00 1.7

4/11/2013 18:00 5.3 4/16/2013 11:00 12.6 4/18/2013 4:00 11.3 4/19/2013 21:00 9.4 4/25/2013 14:00 1.3

4/11/2013 19:00 5.6 4/16/2013 12:00 8.1 4/18/2013 5:00 12.6 4/19/2013 22:00 5.6 4/25/2013 15:00 2.3

4/11/2013 20:00 6.9 4/16/2013 13:00 6.6 4/18/2013 6:00 22.5 4/19/2013 23:00 4.2 4/25/2013 16:00 1.3

4/11/2013 21:00 40.4 4/16/2013 14:00 4/18/2013 7:00 8.5 4/20/2013 0:00 4.5 4/25/2013 17:00 1.4

4/11/2013 22:00 34.6 4/16/2013 15:00 7.9 4/18/2013 8:00 9.7 4/20/2013 1:00 3 4/25/2013 18:00 1.9

4/11/2013 23:00 15.2 4/16/2013 16:00 6.4 4/18/2013 9:00 6 4/20/2013 2:00 3.1 4/25/2013 19:00 3.2

4/12/2013 0:00 21.9 4/16/2013 17:00 5.7 4/18/2013 10:00 4/20/2013 3:00 6.2 4/25/2013 20:00 4.7

4/12/2013 1:00 34.4 4/16/2013 18:00 5.5 4/18/2013 11:00 4/20/2013 4:00 31.7 4/25/2013 21:00 5.3

4/12/2013 2:00 299.6 4/16/2013 19:00 5.3 4/18/2013 12:00 3.4 4/20/2013 5:00 108.5 4/25/2013 22:00 24.6

4/12/2013 3:00 156.5 4/16/2013 20:00 5.3 4/18/2013 13:00 1.8 4/20/2013 6:00 125.5 4/25/2013 23:00 23

4/12/2013 4:00 78.9 4/16/2013 21:00 7.5 4/18/2013 14:00 1.7 4/20/2013 7:00 260.9 5/1/2013 0:00 32.8

4/12/2013 5:00 122.6 4/16/2013 22:00 9.2 4/18/2013 15:00 2.1 4/20/2013 8:00 252 5/1/2013 1:00 42.1

4/12/2013 6:00 64.5 4/16/2013 23:00 75.7 4/18/2013 16:00 1.6 4/20/2013 9:00 13.4 5/1/2013 2:00 99.4

4/12/2013 7:00 205.5 4/17/2013 0:00 177 4/18/2013 17:00 1.4 4/20/2013 10:00 8.6 5/1/2013 3:00 119.5

4/12/2013 8:00 71.5 4/17/2013 1:00 179.7 4/18/2013 18:00 2.4 4/20/2013 11:00 4.1 5/1/2013 4:00 121.5

4/12/2013 9:00 11.1 4/17/2013 2:00 113.1 4/18/2013 19:00 7.5 4/20/2013 12:00 2 5/1/2013 5:00 41.7

4/12/2013 10:00 8.4 4/17/2013 3:00 60 4/18/2013 20:00 10 4/20/2013 13:00 1.5 5/1/2013 6:00 77

4/12/2013 11:00 6.9 4/17/2013 4:00 40.3 4/18/2013 21:00 28.3 4/20/2013 14:00 1.5 5/1/2013 7:00 71.1

4/12/2013 12:00 6.3 4/17/2013 5:00 33.6 4/18/2013 22:00 28.6 4/20/2013 15:00 1.5 5/1/2013 8:00 29.3

4/12/2013 13:00 5.8 4/17/2013 6:00 29 4/18/2013 23:00 38.3 4/20/2013 16:00 1.6 5/1/2013 9:00 17.4

4/12/2013 14:00 5.7 4/17/2013 7:00 23.7 4/19/2013 0:00 22.2 4/20/2013 17:00 1.2 5/1/2013 10:00 5.8

4/12/2013 15:00 5.5 4/17/2013 8:00 29.3 4/19/2013 1:00 18.8 4/20/2013 18:00 1.2 5/1/2013 11:00 2.7

4/12/2013 16:00 5.3 4/17/2013 9:00 42.3 4/19/2013 2:00 29.9 4/20/2013 19:00 1 5/1/2013 12:00 1.7

4/12/2013 17:00 5.2 4/17/2013 10:00 12.1 4/19/2013 3:00 57.4 4/20/2013 20:00 0.9 5/1/2013 13:00 1.3

4/12/2013 18:00 5.1 4/17/2013 11:00 8.3 4/19/2013 4:00 45.6 4/20/2013 21:00 0.8 5/1/2013 14:00 1.1

4/12/2013 19:00 5.3 4/17/2013 12:00 7.4 4/19/2013 5:00 56.8 4/20/2013 22:00 0.8 5/1/2013 15:00 1

4/12/2013 20:00 5.1 4/17/2013 13:00 6.5 4/19/2013 6:00 88.6 4/20/2013 23:00 0.7 5/1/2013 16:00 1

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 63
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/1/2013 17:00 0.9 5/3/2013 10:00 6.6 5/13/2013 3:00 28.5 5/14/2013 20:00 35.3 5/16/2013 13:00 2.4

5/1/2013 18:00 0.8 5/3/2013 11:00 3 5/13/2013 4:00 24.7 5/14/2013 21:00 50.1 5/16/2013 14:00 1.7

5/1/2013 19:00 1 5/3/2013 12:00 1.6 5/13/2013 5:00 28.6 5/14/2013 22:00 43.8 5/16/2013 15:00 2.7

5/1/2013 20:00 2.3 5/3/2013 13:00 1 5/13/2013 6:00 16.8 5/14/2013 23:00 64 5/16/2013 16:00 2

5/1/2013 21:00 7.9 5/3/2013 14:00 0.9 5/13/2013 7:00 25.5 5/15/2013 0:00 57.9 5/16/2013 17:00 1.7

5/1/2013 22:00 13.8 5/3/2013 15:00 0.9 5/13/2013 8:00 10.8 5/15/2013 1:00 30.2 5/16/2013 18:00 6

5/1/2013 23:00 23.7 5/3/2013 16:00 0.8 5/13/2013 9:00 6.4 5/15/2013 2:00 24.9 5/16/2013 19:00 27.8

5/2/2013 0:00 10.4 5/3/2013 17:00 0.9 5/13/2013 10:00 4.2 5/15/2013 3:00 11.5 5/16/2013 20:00 45.3

5/2/2013 1:00 19.3 5/3/2013 18:00 1.1 5/13/2013 11:00 2.2 5/15/2013 4:00 12.2 5/16/2013 21:00 25.7

5/2/2013 2:00 25.7 5/3/2013 19:00 1.1 5/13/2013 12:00 1.5 5/15/2013 5:00 42.7 5/16/2013 22:00 36.4

5/2/2013 3:00 68.9 5/3/2013 20:00 1.7 5/13/2013 13:00 1.1 5/15/2013 6:00 51.3 5/16/2013 23:00 46.8

5/2/2013 4:00 66 5/3/2013 21:00 1.5 5/13/2013 14:00 1.1 5/15/2013 7:00 215.6 5/17/2013 0:00 72.1

5/2/2013 5:00 65.4 5/3/2013 22:00 4.3 5/13/2013 15:00 5/15/2013 8:00 7.4 5/17/2013 1:00 90.1

5/2/2013 6:00 100.2 5/3/2013 23:00 6.9 5/13/2013 16:00 1.1 5/15/2013 9:00 5.7 5/17/2013 2:00 249.7

5/2/2013 7:00 82.8 5/12/2013 0:00 2.7 5/13/2013 17:00 1 5/15/2013 10:00 3.9 5/17/2013 3:00 63.3

5/2/2013 8:00 87 5/12/2013 1:00 2 5/13/2013 18:00 1.1 5/15/2013 11:00 2.4 5/17/2013 4:00 60.4

5/2/2013 9:00 12.5 5/12/2013 2:00 1.2 5/13/2013 19:00 1.8 5/15/2013 12:00 1.5 5/17/2013 5:00 109.2

5/2/2013 10:00 7 5/12/2013 3:00 5.3 5/13/2013 20:00 3.6 5/15/2013 13:00 1.4 5/17/2013 6:00 48.5

5/2/2013 11:00 3.9 5/12/2013 4:00 5.8 5/13/2013 21:00 61.5 5/15/2013 14:00 1.3 5/17/2013 7:00 60.3

5/2/2013 12:00 2.5 5/12/2013 5:00 5 5/13/2013 22:00 80 5/15/2013 15:00 1.1 5/17/2013 8:00 136.8

5/2/2013 13:00 1.7 5/12/2013 6:00 2.9 5/13/2013 23:00 48.4 5/15/2013 16:00 1.2 5/17/2013 9:00 20.1

5/2/2013 14:00 1.2 5/12/2013 7:00 1.6 5/14/2013 0:00 11.3 5/15/2013 17:00 1 5/17/2013 10:00 7.4

5/2/2013 15:00 2.1 5/12/2013 8:00 1.8 5/14/2013 1:00 4.4 5/15/2013 18:00 1.9 5/17/2013 11:00 3.2

5/2/2013 16:00 1.4 5/12/2013 9:00 5.4 5/14/2013 2:00 3 5/15/2013 19:00 25.6 5/17/2013 12:00 2.1

5/2/2013 17:00 2.1 5/12/2013 10:00 3.8 5/14/2013 3:00 4.8 5/15/2013 20:00 218.9 5/17/2013 13:00 1.8

5/2/2013 18:00 60.3 5/12/2013 11:00 2.3 5/14/2013 4:00 10.5 5/15/2013 21:00 98.3 5/17/2013 14:00 1.5

5/2/2013 19:00 99.3 5/12/2013 12:00 1.8 5/14/2013 5:00 90.4 5/15/2013 22:00 238.9 5/17/2013 15:00 1.3

5/2/2013 20:00 13.2 5/12/2013 13:00 2.7 5/14/2013 6:00 135.1 5/15/2013 23:00 165 5/17/2013 16:00 1.2

5/2/2013 21:00 15.7 5/12/2013 14:00 1.5 5/14/2013 7:00 59.6 5/16/2013 0:00 26.4 5/17/2013 17:00 1

5/2/2013 22:00 50.3 5/12/2013 15:00 1.3 5/14/2013 8:00 11.4 5/16/2013 1:00 29.1 5/17/2013 18:00 1.5

5/2/2013 23:00 65.7 5/12/2013 16:00 1.2 5/14/2013 9:00 8 5/16/2013 2:00 35 5/17/2013 19:00 4.6

5/3/2013 0:00 72.7 5/12/2013 17:00 1.2 5/14/2013 10:00 4.5 5/16/2013 3:00 135 5/17/2013 20:00 35.3

5/3/2013 1:00 95.9 5/12/2013 18:00 1.6 5/14/2013 11:00 2.6 5/16/2013 4:00 82.9 5/17/2013 21:00 29.6

5/3/2013 2:00 91.7 5/12/2013 19:00 5.9 5/14/2013 12:00 2.2 5/16/2013 5:00 41.8 5/17/2013 22:00 22.7

5/3/2013 3:00 50.2 5/12/2013 20:00 4.9 5/14/2013 13:00 1.9 5/16/2013 6:00 53.7 5/17/2013 23:00 23.1

5/3/2013 4:00 59 5/12/2013 21:00 56.2 5/14/2013 14:00 5/16/2013 7:00 193.7 5/18/2013 0:00 73.7

5/3/2013 5:00 78.1 5/12/2013 22:00 90 5/14/2013 15:00 3.4 5/16/2013 8:00 238.9 5/18/2013 1:00 95.8

5/3/2013 6:00 25.5 5/12/2013 23:00 45.3 5/14/2013 16:00 1.7 5/16/2013 9:00 40.8 5/18/2013 2:00 73.6

5/3/2013 7:00 28.2 5/13/2013 0:00 101.2 5/14/2013 17:00 1.5 5/16/2013 10:00 12.5 5/18/2013 3:00 32.3

5/3/2013 8:00 21.8 5/13/2013 1:00 35.2 5/14/2013 18:00 2.8 5/16/2013 11:00 8.1 5/18/2013 4:00 17.3

5/3/2013 9:00 30 5/13/2013 2:00 43.9 5/14/2013 19:00 11.2 5/16/2013 12:00 7.3 5/18/2013 5:00 9.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 64
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/18/2013 6:00 11 5/26/2013 23:00 8.3 5/31/2013 16:00 1.1 6/2/2013 9:00 13.2 6/4/2013 2:00 69.1

5/18/2013 7:00 6.3 5/30/2013 0:00 35 5/31/2013 17:00 1.2 6/2/2013 10:00 8.1 6/4/2013 3:00 165.8

5/18/2013 8:00 6.5 5/30/2013 1:00 19.6 5/31/2013 18:00 1.6 6/2/2013 11:00 5.3 6/4/2013 4:00 131.4

5/18/2013 9:00 3.9 5/30/2013 2:00 34.5 5/31/2013 19:00 3.3 6/2/2013 12:00 4.5 6/4/2013 5:00 161.4

5/18/2013 10:00 2.2 5/30/2013 3:00 46.6 5/31/2013 20:00 4.1 6/2/2013 13:00 3.3 6/4/2013 6:00 252.5

5/18/2013 11:00 4.5 5/30/2013 4:00 34.3 5/31/2013 21:00 8 6/2/2013 14:00 2.8 6/4/2013 7:00 156.6

5/18/2013 12:00 5.7 5/30/2013 5:00 31 5/31/2013 22:00 5.1 6/2/2013 15:00 3.1 6/4/2013 8:00 71

5/18/2013 13:00 2.2 5/30/2013 6:00 26.8 5/31/2013 23:00 4.9 6/2/2013 16:00 3.6 6/4/2013 9:00 33.1

5/18/2013 14:00 1.4 5/30/2013 7:00 19.9 6/1/2013 0:00 5.6 6/2/2013 17:00 3.9 6/4/2013 10:00 14.9

5/18/2013 15:00 1.2 5/30/2013 8:00 30.2 6/1/2013 1:00 9 6/2/2013 18:00 13.4 6/4/2013 11:00 5.3

5/18/2013 16:00 1.1 5/30/2013 9:00 40.6 6/1/2013 2:00 10 6/2/2013 19:00 20.5 6/4/2013 12:00 4.6

5/18/2013 17:00 0.9 5/30/2013 10:00 9.8 6/1/2013 3:00 18.3 6/2/2013 20:00 35.4 6/4/2013 13:00 4.6

5/18/2013 18:00 0.8 5/30/2013 11:00 3.8 6/1/2013 4:00 37.1 6/2/2013 21:00 38.2 6/4/2013 14:00

5/18/2013 19:00 0.8 5/30/2013 12:00 2.5 6/1/2013 5:00 60.2 6/2/2013 22:00 298.2 6/4/2013 15:00 1.5

5/18/2013 20:00 0.8 5/30/2013 13:00 2 6/1/2013 6:00 73.5 6/2/2013 23:00 171 6/4/2013 16:00 1.1

5/18/2013 21:00 0.8 5/30/2013 14:00 1.6 6/1/2013 7:00 85.8 6/3/2013 0:00 104.9 6/4/2013 17:00 6.9

5/18/2013 22:00 0.8 5/30/2013 15:00 3.1 6/1/2013 8:00 17.6 6/3/2013 1:00 49.8 6/4/2013 18:00 10

5/18/2013 23:00 0.8 5/30/2013 16:00 1.7 6/1/2013 9:00 11.6 6/3/2013 2:00 32.8 6/4/2013 19:00 15.9

5/26/2013 0:00 8.8 5/30/2013 17:00 1.3 6/1/2013 10:00 10.5 6/3/2013 3:00 70.2 6/4/2013 20:00 18.4

5/26/2013 1:00 9.6 5/30/2013 18:00 1.1 6/1/2013 11:00 6.3 6/3/2013 4:00 62.4 6/4/2013 21:00 14.9

5/26/2013 2:00 14.6 5/30/2013 19:00 1.3 6/1/2013 12:00 5.5 6/3/2013 5:00 86 6/4/2013 22:00 25.4

5/26/2013 3:00 12 5/30/2013 20:00 1.6 6/1/2013 13:00 3.2 6/3/2013 6:00 33.2 6/4/2013 23:00 24.1

5/26/2013 4:00 14.6 5/30/2013 21:00 3.3 6/1/2013 14:00 2.8 6/3/2013 7:00 55.8 6/5/2013 0:00 30.7

5/26/2013 5:00 16.1 5/30/2013 22:00 26.7 6/1/2013 15:00 8.1 6/3/2013 8:00 54.6 6/5/2013 1:00 32.6

5/26/2013 6:00 13.3 5/30/2013 23:00 121.2 6/1/2013 16:00 9 6/3/2013 9:00 16.9 6/5/2013 2:00 39.5

5/26/2013 7:00 34.4 5/31/2013 0:00 81 6/1/2013 17:00 6.3 6/3/2013 10:00 5.9 6/5/2013 3:00 11.6

5/26/2013 8:00 61.4 5/31/2013 1:00 104.3 6/1/2013 18:00 6.9 6/3/2013 11:00 6.2 6/5/2013 4:00 7.1

5/26/2013 9:00 16.4 5/31/2013 2:00 111.7 6/1/2013 19:00 9.4 6/3/2013 12:00 3.6 6/5/2013 5:00 16.2

5/26/2013 10:00 9.3 5/31/2013 3:00 88.3 6/1/2013 20:00 107.4 6/3/2013 13:00 2.4 6/5/2013 6:00 23.1

5/26/2013 11:00 4.2 5/31/2013 4:00 51.9 6/1/2013 21:00 79.7 6/3/2013 14:00 2.7 6/5/2013 7:00 87.2

5/26/2013 12:00 2.7 5/31/2013 5:00 28 6/1/2013 22:00 112.6 6/3/2013 15:00 6/5/2013 8:00 4.1

5/26/2013 13:00 1.9 5/31/2013 6:00 24.8 6/1/2013 23:00 146.8 6/3/2013 16:00 3.3 6/5/2013 9:00 9.5

5/26/2013 14:00 1.5 5/31/2013 7:00 24.6 6/2/2013 0:00 115 6/3/2013 17:00 5.9 6/5/2013 10:00 5.6

5/26/2013 15:00 1.4 5/31/2013 8:00 7.7 6/2/2013 1:00 91.8 6/3/2013 18:00 8.6 6/5/2013 11:00 3.2

5/26/2013 16:00 1.5 5/31/2013 9:00 3.8 6/2/2013 2:00 131.4 6/3/2013 19:00 27.2 6/5/2013 12:00 2.1

5/26/2013 17:00 1.6 5/31/2013 10:00 2.8 6/2/2013 3:00 155.7 6/3/2013 20:00 31.9 6/5/2013 13:00 2.1

5/26/2013 18:00 4.7 5/31/2013 11:00 2.1 6/2/2013 4:00 218 6/3/2013 21:00 26.5 6/5/2013 14:00 1.8

5/26/2013 19:00 83.4 5/31/2013 12:00 1.7 6/2/2013 5:00 238.7 6/3/2013 22:00 49.4 6/5/2013 15:00 2.6

5/26/2013 20:00 45.7 5/31/2013 13:00 1.4 6/2/2013 6:00 258.1 6/3/2013 23:00 96.6 6/5/2013 16:00 2.6

5/26/2013 21:00 22.7 5/31/2013 14:00 1.3 6/2/2013 7:00 174 6/4/2013 0:00 102.6 6/5/2013 17:00 2.2

5/26/2013 22:00 13.6 5/31/2013 15:00 1.1 6/2/2013 8:00 35.2 6/4/2013 1:00 101.2 6/5/2013 18:00 2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 65
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/5/2013 19:00 4.9 6/7/2013 12:00 5.4 6/10/2013 5:00 72.6 6/11/2013 22:00 15.4 6/13/2013 15:00 3.5

6/5/2013 20:00 11.4 6/7/2013 13:00 2.6 6/10/2013 6:00 84.6 6/11/2013 23:00 38.3 6/13/2013 16:00 2.6

6/5/2013 21:00 13.2 6/7/2013 14:00 3.7 6/10/2013 7:00 88.6 6/12/2013 0:00 56 6/13/2013 17:00 15.4

6/5/2013 22:00 16.6 6/7/2013 15:00 2.2 6/10/2013 8:00 95 6/12/2013 1:00 46.5 6/13/2013 18:00 16

6/5/2013 23:00 29.4 6/7/2013 16:00 4.2 6/10/2013 9:00 71.5 6/12/2013 2:00 34.1 6/13/2013 19:00 54.2

6/6/2013 0:00 25.2 6/7/2013 17:00 3.3 6/10/2013 10:00 25.4 6/12/2013 3:00 36.6 6/13/2013 20:00 53.8

6/6/2013 1:00 32 6/7/2013 18:00 5.5 6/10/2013 11:00 11.3 6/12/2013 4:00 30.1 6/13/2013 21:00 30.7

6/6/2013 2:00 32.4 6/7/2013 19:00 63.1 6/10/2013 12:00 5.9 6/12/2013 5:00 35.2 6/13/2013 22:00 212.9

6/6/2013 3:00 29.2 6/7/2013 20:00 17.9 6/10/2013 13:00 3.4 6/12/2013 6:00 20.2 6/13/2013 23:00 136.2

6/6/2013 4:00 36.1 6/7/2013 21:00 19.6 6/10/2013 14:00 2.6 6/12/2013 7:00 111.8 6/15/2013 0:00 23.3

6/6/2013 5:00 30.3 6/7/2013 22:00 17.6 6/10/2013 15:00 6/12/2013 8:00 246.5 6/15/2013 1:00 49.1

6/6/2013 6:00 21.1 6/7/2013 23:00 13.9 6/10/2013 16:00 2.2 6/12/2013 9:00 17.6 6/15/2013 2:00 107.1

6/6/2013 7:00 29.8 6/9/2013 0:00 18.4 6/10/2013 17:00 2 6/12/2013 10:00 6 6/15/2013 3:00 105.8

6/6/2013 8:00 68.1 6/9/2013 1:00 84.4 6/10/2013 18:00 3.1 6/12/2013 11:00 3.6 6/15/2013 4:00 114.8

6/6/2013 9:00 8.9 6/9/2013 2:00 48.4 6/10/2013 19:00 9 6/12/2013 12:00 4.2 6/15/2013 5:00 75.1

6/6/2013 10:00 5.4 6/9/2013 3:00 24.1 6/10/2013 20:00 19.3 6/12/2013 13:00 8.7 6/15/2013 6:00 30.4

6/6/2013 11:00 13.4 6/9/2013 4:00 20.5 6/10/2013 21:00 29.4 6/12/2013 14:00 9.7 6/15/2013 7:00 133.6

6/6/2013 12:00 11.7 6/9/2013 5:00 21.8 6/10/2013 22:00 27.9 6/12/2013 15:00 9.8 6/15/2013 8:00 163.3

6/6/2013 13:00 4.6 6/9/2013 6:00 183 6/10/2013 23:00 22.7 6/12/2013 16:00 7.3 6/15/2013 9:00 16

6/6/2013 14:00 6.7 6/9/2013 7:00 131.6 6/11/2013 0:00 16.3 6/12/2013 17:00 10.1 6/15/2013 10:00 6.8

6/6/2013 15:00 11.7 6/9/2013 8:00 75.4 6/11/2013 1:00 13.6 6/12/2013 18:00 51.3 6/15/2013 11:00 4.7

6/6/2013 16:00 12.7 6/9/2013 9:00 46.3 6/11/2013 2:00 73.8 6/12/2013 19:00 111.2 6/15/2013 12:00 2.8

6/6/2013 17:00 11.7 6/9/2013 10:00 8.7 6/11/2013 3:00 120.6 6/12/2013 20:00 44.8 6/15/2013 13:00 2.1

6/6/2013 18:00 20.9 6/9/2013 11:00 4.9 6/11/2013 4:00 135.1 6/12/2013 21:00 60.6 6/15/2013 14:00 1.8

6/6/2013 19:00 11.6 6/9/2013 12:00 3.5 6/11/2013 5:00 165 6/12/2013 22:00 197.6 6/15/2013 15:00 1.5

6/6/2013 20:00 5.6 6/9/2013 13:00 2.1 6/11/2013 6:00 183 6/12/2013 23:00 146.6 6/15/2013 16:00 1.4

6/6/2013 21:00 100.2 6/9/2013 14:00 1.7 6/11/2013 7:00 162.6 6/13/2013 0:00 67.6 6/15/2013 17:00 1.5

6/6/2013 22:00 312.3 6/9/2013 15:00 1.6 6/11/2013 8:00 79.1 6/13/2013 1:00 48 6/15/2013 18:00 1.8

6/6/2013 23:00 152.9 6/9/2013 16:00 1.7 6/11/2013 9:00 31.9 6/13/2013 2:00 46.4 6/15/2013 19:00 4.5

6/7/2013 0:00 32.3 6/9/2013 17:00 2.9 6/11/2013 10:00 10.3 6/13/2013 3:00 152.7 6/15/2013 20:00 21

6/7/2013 1:00 46.8 6/9/2013 18:00 3 6/11/2013 11:00 4.7 6/13/2013 4:00 337.2 6/15/2013 21:00 52

6/7/2013 2:00 66.6 6/9/2013 19:00 9.5 6/11/2013 12:00 5.8 6/13/2013 5:00 104.2 6/15/2013 22:00 42.1

6/7/2013 3:00 46 6/9/2013 20:00 21.7 6/11/2013 13:00 3 6/13/2013 6:00 17.7 6/15/2013 23:00 23

6/7/2013 4:00 23.6 6/9/2013 21:00 23.1 6/11/2013 14:00 6/13/2013 7:00 33.8 6/16/2013 0:00 22.3

6/7/2013 5:00 21.6 6/9/2013 22:00 28.6 6/11/2013 15:00 3.2 6/13/2013 8:00 48 6/16/2013 1:00 44.4

6/7/2013 6:00 58.8 6/9/2013 23:00 28.1 6/11/2013 16:00 2.3 6/13/2013 9:00 14.3 6/16/2013 2:00 42.4

6/7/2013 7:00 111.6 6/10/2013 0:00 35.7 6/11/2013 17:00 2 6/13/2013 10:00 6.7 6/16/2013 3:00 20.8

6/7/2013 8:00 28.7 6/10/2013 1:00 36.4 6/11/2013 18:00 3.9 6/13/2013 11:00 15.6 6/16/2013 4:00 45.2

6/7/2013 9:00 8 6/10/2013 2:00 31.9 6/11/2013 19:00 7.6 6/13/2013 12:00 6.9 6/16/2013 5:00 62.3

6/7/2013 10:00 13.2 6/10/2013 3:00 43.4 6/11/2013 20:00 18.3 6/13/2013 13:00 3.4 6/16/2013 6:00 78.3

6/7/2013 11:00 9.3 6/10/2013 4:00 59.2 6/11/2013 21:00 12.6 6/13/2013 14:00 2.8 6/16/2013 7:00 69.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 66
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/16/2013 8:00 171.1 6/19/2013 1:00 57.1 6/20/2013 18:00 1.4 6/22/2013 11:00 7.4 6/24/2013 4:00 39.3

6/16/2013 9:00 6.8 6/19/2013 2:00 38 6/20/2013 19:00 2.5 6/22/2013 12:00 4.6 6/24/2013 5:00 79.5

6/16/2013 10:00 8.1 6/19/2013 3:00 30.8 6/20/2013 20:00 12.2 6/22/2013 13:00 4.4 6/24/2013 6:00 72.8

6/16/2013 11:00 6.8 6/19/2013 4:00 32 6/20/2013 21:00 63.5 6/22/2013 14:00 2.8 6/24/2013 7:00 62.6

6/16/2013 12:00 3.5 6/19/2013 5:00 30.1 6/20/2013 22:00 308.5 6/22/2013 15:00 2.2 6/24/2013 8:00 73

6/16/2013 13:00 2.3 6/19/2013 6:00 66.9 6/20/2013 23:00 226.6 6/22/2013 16:00 6 6/24/2013 9:00 20.3

6/16/2013 14:00 2 6/19/2013 7:00 119.8 6/21/2013 0:00 118.5 6/22/2013 17:00 4.5 6/24/2013 10:00 8.8

6/16/2013 15:00 1.6 6/19/2013 8:00 22.2 6/21/2013 1:00 122.8 6/22/2013 18:00 2.8 6/24/2013 11:00 5.5

6/16/2013 16:00 1.4 6/19/2013 9:00 20.4 6/21/2013 2:00 119.4 6/22/2013 19:00 4 6/24/2013 12:00 3.1

6/16/2013 17:00 1.4 6/19/2013 10:00 18 6/21/2013 3:00 85.9 6/22/2013 20:00 3.8 6/24/2013 13:00 2

6/16/2013 18:00 1.5 6/19/2013 11:00 8.6 6/21/2013 4:00 56.5 6/22/2013 21:00 22.6 6/24/2013 14:00 1.7

6/16/2013 19:00 2.4 6/19/2013 12:00 3.3 6/21/2013 5:00 64.9 6/22/2013 22:00 46.9 6/24/2013 15:00

6/16/2013 20:00 5 6/19/2013 13:00 2.4 6/21/2013 6:00 22.9 6/22/2013 23:00 41.9 6/24/2013 16:00 1.8

6/16/2013 21:00 6.2 6/19/2013 14:00 2.1 6/21/2013 7:00 62.5 6/23/2013 0:00 31.3 6/24/2013 17:00 1.6

6/16/2013 22:00 7.4 6/19/2013 15:00 1.8 6/21/2013 8:00 34.9 6/23/2013 1:00 40.2 6/24/2013 18:00 1.5

6/16/2013 23:00 6.5 6/19/2013 16:00 1.8 6/21/2013 9:00 11.5 6/23/2013 2:00 43.6 6/24/2013 19:00 1.5

6/18/2013 0:00 68.2 6/19/2013 17:00 6.4 6/21/2013 10:00 9.4 6/23/2013 3:00 52.3 6/24/2013 20:00 1.6

6/18/2013 1:00 84 6/19/2013 18:00 9.1 6/21/2013 11:00 6.7 6/23/2013 4:00 72.3 6/24/2013 21:00 1.9

6/18/2013 2:00 83.4 6/19/2013 19:00 8.1 6/21/2013 12:00 3.2 6/23/2013 5:00 78.7 6/24/2013 22:00 2.4

6/18/2013 3:00 35.6 6/19/2013 20:00 10.2 6/21/2013 13:00 2.8 6/23/2013 6:00 85.2 6/24/2013 23:00 4.2

6/18/2013 4:00 21.2 6/19/2013 21:00 16.5 6/21/2013 14:00 2.9 6/23/2013 7:00 73.7 6/25/2013 0:00 7.2

6/18/2013 5:00 78.6 6/19/2013 22:00 17.7 6/21/2013 15:00 2.8 6/23/2013 8:00 33.9 6/25/2013 1:00 20.3

6/18/2013 6:00 189.3 6/19/2013 23:00 32.2 6/21/2013 16:00 2.3 6/23/2013 9:00 20 6/25/2013 2:00 65.5

6/18/2013 7:00 151.9 6/20/2013 0:00 39.6 6/21/2013 17:00 2.1 6/23/2013 10:00 14.5 6/25/2013 3:00 82.9

6/18/2013 8:00 33.7 6/20/2013 1:00 46 6/21/2013 18:00 3 6/23/2013 11:00 7 6/25/2013 4:00 62.4

6/18/2013 9:00 36.2 6/20/2013 2:00 21.3 6/21/2013 19:00 3.7 6/23/2013 12:00 5.2 6/25/2013 5:00 72.9

6/18/2013 10:00 7.6 6/20/2013 3:00 19 6/21/2013 20:00 11 6/23/2013 13:00 2.5 6/25/2013 6:00 63.6

6/18/2013 11:00 4.7 6/20/2013 4:00 51.4 6/21/2013 21:00 18.4 6/23/2013 14:00 1.9 6/25/2013 7:00 59.1

6/18/2013 12:00 6.5 6/20/2013 5:00 49.1 6/21/2013 22:00 62.7 6/23/2013 15:00 1.7 6/25/2013 8:00 31.8

6/18/2013 13:00 2.5 6/20/2013 6:00 43.1 6/21/2013 23:00 22.6 6/23/2013 16:00 1.4 6/25/2013 9:00 8.8

6/18/2013 14:00 6/20/2013 7:00 43.1 6/22/2013 0:00 24.2 6/23/2013 17:00 1.3 6/25/2013 10:00 3.7

6/18/2013 15:00 3.1 6/20/2013 8:00 53.7 6/22/2013 1:00 29.2 6/23/2013 18:00 1.5 6/25/2013 11:00 2.7

6/18/2013 16:00 2.3 6/20/2013 9:00 41.8 6/22/2013 2:00 13.2 6/23/2013 19:00 3 6/25/2013 12:00 2.2

6/18/2013 17:00 1.8 6/20/2013 10:00 7.9 6/22/2013 3:00 18.5 6/23/2013 20:00 10.2 6/25/2013 13:00 1.6

6/18/2013 18:00 1.6 6/20/2013 11:00 3.8 6/22/2013 4:00 21.2 6/23/2013 21:00 13.6 6/25/2013 14:00

6/18/2013 19:00 1.6 6/20/2013 12:00 2.7 6/22/2013 5:00 58.7 6/23/2013 22:00 19.4 6/25/2013 15:00 2.8

6/18/2013 20:00 3.8 6/20/2013 13:00 1.9 6/22/2013 6:00 104 6/23/2013 23:00 14.7 6/25/2013 16:00 1.8

6/18/2013 21:00 21.3 6/20/2013 14:00 1.7 6/22/2013 7:00 125.9 6/24/2013 0:00 17 6/25/2013 17:00 1.5

6/18/2013 22:00 16 6/20/2013 15:00 2.9 6/22/2013 8:00 64.6 6/24/2013 1:00 25.6 6/25/2013 18:00 1.4

6/18/2013 23:00 29.6 6/20/2013 16:00 1.7 6/22/2013 9:00 12.8 6/24/2013 2:00 46.3 6/25/2013 19:00 1.2

6/19/2013 0:00 44 6/20/2013 17:00 1.5 6/22/2013 10:00 9.5 6/24/2013 3:00 44.6 6/25/2013 20:00 1.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 67
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/25/2013 21:00 2.7 6/28/2013 14:00 1.7 7/1/2013 7:00 68.8 7/9/2013 0:00 59.6 7/10/2013 17:00 27.3

6/25/2013 22:00 3.3 6/28/2013 15:00 1.5 7/1/2013 8:00 82.8 7/9/2013 1:00 68.6 7/10/2013 18:00 93.6

6/25/2013 23:00 6.9 6/28/2013 16:00 1.3 7/1/2013 9:00 102 7/9/2013 2:00 44.9 7/10/2013 19:00 111.8

6/26/2013 0:00 11.4 6/28/2013 17:00 1.3 7/1/2013 10:00 147.4 7/9/2013 3:00 73.7 7/10/2013 20:00 81.9

6/26/2013 1:00 19.9 6/28/2013 18:00 1.2 7/1/2013 11:00 17.3 7/9/2013 4:00 23.8 7/10/2013 21:00 85.3

6/26/2013 2:00 19.1 6/28/2013 19:00 2.5 7/1/2013 12:00 18.6 7/9/2013 5:00 18.5 7/10/2013 22:00 56.2

6/26/2013 3:00 27 6/28/2013 20:00 6.7 7/1/2013 13:00 20.3 7/9/2013 6:00 33.5 7/10/2013 23:00 65.5

6/26/2013 4:00 34.2 6/28/2013 21:00 26.8 7/1/2013 14:00 14.4 7/9/2013 7:00 168.8 7/11/2013 0:00 51.9

6/26/2013 5:00 35.1 6/28/2013 22:00 78.4 7/1/2013 15:00 7/9/2013 8:00 32.4 7/11/2013 1:00 45.6

6/26/2013 6:00 55.8 6/28/2013 23:00 48.4 7/1/2013 16:00 4.9 7/9/2013 9:00 11.7 7/11/2013 2:00 55.6

6/26/2013 7:00 90.6 6/30/2013 0:00 17.2 7/1/2013 17:00 3.2 7/9/2013 10:00 9.2 7/11/2013 3:00 42.5

6/26/2013 8:00 93.6 6/30/2013 1:00 17.8 7/1/2013 18:00 2.9 7/9/2013 11:00 7 7/11/2013 4:00 31.9

6/26/2013 9:00 45.3 6/30/2013 2:00 14 7/1/2013 19:00 11 7/9/2013 12:00 4.9 7/11/2013 5:00 80.7

6/26/2013 10:00 14.8 6/30/2013 3:00 13.6 7/1/2013 20:00 13.2 7/9/2013 13:00 4.8 7/11/2013 6:00 11.6

6/26/2013 11:00 10.1 6/30/2013 4:00 16.3 7/1/2013 21:00 6.9 7/9/2013 14:00 7/11/2013 7:00 14.6

6/26/2013 12:00 8.8 6/30/2013 5:00 14.8 7/1/2013 22:00 5.7 7/9/2013 15:00 12.4 7/11/2013 8:00 50.4

6/26/2013 13:00 2.7 6/30/2013 6:00 25.1 7/1/2013 23:00 10.2 7/9/2013 16:00 16.5 7/11/2013 9:00 121.9

6/26/2013 14:00 2.2 6/30/2013 7:00 91.5 7/8/2013 0:00 114.4 7/9/2013 17:00 8.5 7/11/2013 10:00 7.6

6/26/2013 15:00 2.3 6/30/2013 8:00 83.4 7/8/2013 1:00 121.6 7/9/2013 18:00 12.3 7/11/2013 11:00 4.3

6/26/2013 16:00 1.7 6/30/2013 9:00 26.9 7/8/2013 2:00 128.7 7/9/2013 19:00 27.9 7/11/2013 12:00 3.7

6/26/2013 17:00 1.8 6/30/2013 10:00 20.5 7/8/2013 3:00 62.4 7/9/2013 20:00 84.3 7/11/2013 13:00 3.6

6/26/2013 18:00 2.7 6/30/2013 11:00 7.3 7/8/2013 4:00 59.4 7/9/2013 21:00 13.2 7/11/2013 14:00 2.2

6/26/2013 19:00 7.5 6/30/2013 12:00 3.7 7/8/2013 5:00 47.6 7/9/2013 22:00 22.8 7/11/2013 15:00 3.4

6/26/2013 20:00 8.9 6/30/2013 13:00 2.6 7/8/2013 6:00 29.6 7/9/2013 23:00 27.8 7/11/2013 16:00 2.4

6/26/2013 21:00 15.8 6/30/2013 14:00 2.1 7/8/2013 7:00 30.2 7/10/2013 0:00 118.2 7/11/2013 17:00 2.3

6/26/2013 22:00 9.4 6/30/2013 15:00 1.8 7/8/2013 8:00 32.4 7/10/2013 1:00 10 7/11/2013 18:00 2.6

6/26/2013 23:00 7.6 6/30/2013 16:00 1.7 7/8/2013 9:00 14.2 7/10/2013 2:00 7.2 7/11/2013 19:00 8

6/28/2013 0:00 11.7 6/30/2013 17:00 1.5 7/8/2013 10:00 10.7 7/10/2013 3:00 25.1 7/11/2013 20:00 25.6

6/28/2013 1:00 18.2 6/30/2013 18:00 1.4 7/8/2013 11:00 3.3 7/10/2013 4:00 30.2 7/11/2013 21:00 22.3

6/28/2013 2:00 42.3 6/30/2013 19:00 3.9 7/8/2013 12:00 2 7/10/2013 5:00 6.3 7/11/2013 22:00 20.4

6/28/2013 3:00 130.7 6/30/2013 20:00 44 7/8/2013 13:00 1.7 7/10/2013 6:00 31.7 7/11/2013 23:00 20.4

6/28/2013 4:00 98 6/30/2013 21:00 27.2 7/8/2013 14:00 1.6 7/10/2013 7:00 133.6 7/12/2013 0:00 13.8

6/28/2013 5:00 70.2 6/30/2013 22:00 30.2 7/8/2013 15:00 7/10/2013 8:00 55.4 7/12/2013 1:00 15.2

6/28/2013 6:00 47.2 6/30/2013 23:00 31.5 7/8/2013 16:00 1.6 7/10/2013 9:00 41.6 7/12/2013 2:00 29.1

6/28/2013 7:00 79.6 7/1/2013 0:00 38.6 7/8/2013 17:00 1.3 7/10/2013 10:00 21.5 7/12/2013 3:00 24.9

6/28/2013 8:00 61.4 7/1/2013 1:00 38.7 7/8/2013 18:00 1.3 7/10/2013 11:00 7.7 7/12/2013 4:00 18.8

6/28/2013 9:00 18.4 7/1/2013 2:00 49.5 7/8/2013 19:00 1.3 7/10/2013 12:00 28.9 7/12/2013 5:00 17.2

6/28/2013 10:00 6.4 7/1/2013 3:00 55.5 7/8/2013 20:00 2.5 7/10/2013 13:00 9.5 7/12/2013 6:00 32.7

6/28/2013 11:00 2.8 7/1/2013 4:00 67.4 7/8/2013 21:00 3.7 7/10/2013 14:00 6.9 7/12/2013 7:00 65.3

6/28/2013 12:00 2.2 7/1/2013 5:00 52 7/8/2013 22:00 27.1 7/10/2013 15:00 4 7/12/2013 8:00 48.5

6/28/2013 13:00 1.8 7/1/2013 6:00 46.3 7/8/2013 23:00 60.4 7/10/2013 16:00 13.1 7/12/2013 9:00 11.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 68
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/12/2013 10:00 7.7 7/17/2013 3:00 60.6 7/18/2013 20:00 1.5 7/21/2013 13:00 5.6 7/24/2013 6:00 36

7/12/2013 11:00 4.7 7/17/2013 4:00 35.7 7/18/2013 21:00 4.1 7/21/2013 14:00 4.5 7/24/2013 7:00 54.7

7/12/2013 12:00 2.6 7/17/2013 5:00 68.3 7/18/2013 22:00 6.1 7/21/2013 15:00 11.1 7/24/2013 8:00 75.5

7/12/2013 13:00 1.9 7/17/2013 6:00 82.2 7/18/2013 23:00 7.9 7/21/2013 16:00 14.6 7/24/2013 9:00 77.4

7/12/2013 14:00 1.5 7/17/2013 7:00 48.7 7/19/2013 0:00 8.1 7/21/2013 17:00 6.8 7/24/2013 10:00 48.5

7/12/2013 15:00 1.4 7/17/2013 8:00 141.2 7/19/2013 1:00 11.6 7/21/2013 18:00 5.5 7/24/2013 11:00 10.8

7/12/2013 16:00 1.1 7/17/2013 9:00 155.1 7/19/2013 2:00 53.6 7/21/2013 19:00 7 7/24/2013 12:00 5.4

7/12/2013 17:00 1.1 7/17/2013 10:00 13.6 7/19/2013 3:00 19 7/21/2013 20:00 8.8 7/24/2013 13:00 3.3

7/12/2013 18:00 1.8 7/17/2013 11:00 6.7 7/19/2013 4:00 8.7 7/21/2013 21:00 7 7/24/2013 14:00 2.5

7/12/2013 19:00 4.7 7/17/2013 12:00 4.5 7/19/2013 5:00 6.5 7/21/2013 22:00 4 7/24/2013 15:00 2.2

7/12/2013 20:00 5 7/17/2013 13:00 3 7/19/2013 6:00 6.4 7/21/2013 23:00 2.7 7/24/2013 16:00 2.4

7/12/2013 21:00 5.6 7/17/2013 14:00 2 7/19/2013 7:00 13.7 7/23/2013 0:00 8.1 7/24/2013 17:00 2.2

7/12/2013 22:00 58.5 7/17/2013 15:00 1.7 7/19/2013 8:00 25.2 7/23/2013 1:00 128.6 7/24/2013 18:00 2.6

7/12/2013 23:00 81.7 7/17/2013 16:00 1.8 7/19/2013 9:00 185.4 7/23/2013 2:00 318.8 7/24/2013 19:00 3.7

7/13/2013 0:00 55.4 7/17/2013 17:00 1.8 7/19/2013 10:00 10.6 7/23/2013 3:00 182.4 7/24/2013 20:00 3.8

7/13/2013 1:00 47.8 7/17/2013 18:00 3.1 7/19/2013 11:00 4.6 7/23/2013 4:00 104.6 7/24/2013 21:00 9.4

7/13/2013 2:00 47.5 7/17/2013 19:00 4.8 7/19/2013 12:00 7/23/2013 5:00 119.3 7/24/2013 22:00 7.7

7/13/2013 3:00 52.1 7/17/2013 20:00 9.7 7/19/2013 13:00 9.2 7/23/2013 6:00 113 7/24/2013 23:00 4.9

7/13/2013 4:00 55.3 7/17/2013 21:00 15.5 7/19/2013 14:00 3.2 7/23/2013 7:00 123.8 7/25/2013 0:00 45.2

7/13/2013 5:00 65.9 7/17/2013 22:00 18 7/19/2013 15:00 2.3 7/23/2013 8:00 33 7/25/2013 1:00 64.5

7/13/2013 6:00 76.7 7/17/2013 23:00 18 7/19/2013 16:00 1.9 7/23/2013 9:00 9 7/25/2013 2:00 53.3

7/13/2013 7:00 54.3 7/18/2013 0:00 17.8 7/19/2013 17:00 1.7 7/23/2013 10:00 5.7 7/25/2013 3:00 45.1

7/13/2013 8:00 68.8 7/18/2013 1:00 24.1 7/19/2013 18:00 2.1 7/23/2013 11:00 4.3 7/25/2013 4:00 40.5

7/13/2013 9:00 28.2 7/18/2013 2:00 28.9 7/19/2013 19:00 2.5 7/23/2013 12:00 3.2 7/25/2013 5:00 24.2

7/13/2013 10:00 10.8 7/18/2013 3:00 52.6 7/19/2013 20:00 10.2 7/23/2013 13:00 2.5 7/25/2013 6:00 34.2

7/13/2013 11:00 4.4 7/18/2013 4:00 74.1 7/19/2013 21:00 14.8 7/23/2013 14:00 7/25/2013 7:00 76

7/13/2013 12:00 2.7 7/18/2013 5:00 58.3 7/19/2013 22:00 13.4 7/23/2013 15:00 3.3 7/25/2013 8:00 162.3

7/13/2013 13:00 2 7/18/2013 6:00 95.7 7/19/2013 23:00 29.7 7/23/2013 16:00 2.2 7/25/2013 9:00 30.5

7/13/2013 14:00 1.8 7/18/2013 7:00 121.9 7/21/2013 0:00 62.6 7/23/2013 17:00 1.9 7/25/2013 10:00 9.1

7/13/2013 15:00 1.6 7/18/2013 8:00 59.7 7/21/2013 1:00 21.6 7/23/2013 18:00 1.7 7/25/2013 11:00

7/13/2013 16:00 1.4 7/18/2013 9:00 26.6 7/21/2013 2:00 12.8 7/23/2013 19:00 1.4 7/25/2013 12:00

7/13/2013 17:00 1.5 7/18/2013 10:00 14.9 7/21/2013 3:00 20.6 7/23/2013 20:00 1.5 7/25/2013 13:00

7/13/2013 18:00 2.9 7/18/2013 11:00 4.3 7/21/2013 4:00 33.4 7/23/2013 21:00 1.7 7/25/2013 14:00

7/13/2013 19:00 19.5 7/18/2013 12:00 2.6 7/21/2013 5:00 41.6 7/23/2013 22:00 1.9 7/25/2013 15:00

7/13/2013 20:00 30.3 7/18/2013 13:00 2.1 7/21/2013 6:00 103.9 7/23/2013 23:00 2.5 7/25/2013 16:00 5.5

7/13/2013 21:00 23.2 7/18/2013 14:00 1.9 7/21/2013 7:00 98.1 7/24/2013 0:00 27.2 7/25/2013 17:00 2.9

7/13/2013 22:00 28.9 7/18/2013 15:00 3.6 7/21/2013 8:00 192.4 7/24/2013 1:00 44.4 7/25/2013 18:00 2.5

7/13/2013 23:00 26.7 7/18/2013 16:00 2.1 7/21/2013 9:00 178.4 7/24/2013 2:00 35.7 7/25/2013 19:00 2.5

7/17/2013 0:00 20.8 7/18/2013 17:00 1.7 7/21/2013 10:00 86.7 7/24/2013 3:00 40.7 7/25/2013 20:00 3.7

7/17/2013 1:00 15.1 7/18/2013 18:00 1.4 7/21/2013 11:00 29.8 7/24/2013 4:00 55 7/25/2013 21:00 4.7

7/17/2013 2:00 15.2 7/18/2013 19:00 1.3 7/21/2013 12:00 11.3 7/24/2013 5:00 28.7 7/25/2013 22:00 15.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 69
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/25/2013 23:00 20.9 7/28/2013 16:00 2.3 8/2/2013 9:00 13.6 8/4/2013 2:00 73.3 8/9/2013 19:00 1.5

7/27/2013 0:00 16.5 7/28/2013 17:00 1.9 8/2/2013 10:00 8.5 8/4/2013 3:00 58.3 8/9/2013 20:00 1.8

7/27/2013 1:00 18.5 7/28/2013 18:00 2.1 8/2/2013 11:00 4.5 8/4/2013 4:00 135.7 8/9/2013 21:00 2.1

7/27/2013 2:00 17.9 7/28/2013 19:00 2.1 8/2/2013 12:00 2.7 8/4/2013 5:00 128.5 8/9/2013 22:00 1.7

7/27/2013 3:00 14.2 7/28/2013 20:00 2.6 8/2/2013 13:00 2.2 8/4/2013 6:00 33.2 8/9/2013 23:00 1.5

7/27/2013 4:00 16.3 7/28/2013 21:00 7.9 8/2/2013 14:00 2.1 8/4/2013 7:00 26 8/12/2013 0:00 47.9

7/27/2013 5:00 27.6 7/28/2013 22:00 10.6 8/2/2013 15:00 2 8/4/2013 8:00 16.6 8/12/2013 1:00 61.4

7/27/2013 6:00 17.3 7/28/2013 23:00 16.6 8/2/2013 16:00 1.7 8/4/2013 9:00 14.7 8/12/2013 2:00 148.4

7/27/2013 7:00 45.8 7/31/2013 0:00 27 8/2/2013 17:00 1.6 8/4/2013 10:00 7.6 8/12/2013 3:00 224.3

7/27/2013 8:00 99.5 7/31/2013 1:00 19.8 8/2/2013 18:00 1.6 8/4/2013 11:00 7 8/12/2013 4:00 166.3

7/27/2013 9:00 41 7/31/2013 2:00 33.7 8/2/2013 19:00 1.9 8/4/2013 12:00 7.1 8/12/2013 5:00 83

7/27/2013 10:00 6.9 7/31/2013 3:00 78.4 8/2/2013 20:00 4.4 8/4/2013 13:00 3 8/12/2013 6:00 54.3

7/27/2013 11:00 3.9 7/31/2013 4:00 129.7 8/2/2013 21:00 10.3 8/4/2013 14:00 2.1 8/12/2013 7:00 59.2

7/27/2013 12:00 3.1 7/31/2013 5:00 134.7 8/2/2013 22:00 8.9 8/4/2013 15:00 1.8 8/12/2013 8:00 36.9

7/27/2013 13:00 2.4 7/31/2013 6:00 129.6 8/2/2013 23:00 14.9 8/4/2013 16:00 1.6 8/12/2013 9:00 35.6

7/27/2013 14:00 1.8 7/31/2013 7:00 54.1 8/3/2013 0:00 72.4 8/4/2013 17:00 1.8 8/12/2013 10:00 23.8

7/27/2013 15:00 1.6 7/31/2013 8:00 125.1 8/3/2013 1:00 102 8/4/2013 18:00 2.4 8/12/2013 11:00 7.1

7/27/2013 16:00 3.4 7/31/2013 9:00 48 8/3/2013 2:00 83.1 8/4/2013 19:00 3.6 8/12/2013 12:00 9.9

7/27/2013 17:00 4 7/31/2013 10:00 105.3 8/3/2013 3:00 48.3 8/4/2013 20:00 20.2 8/12/2013 13:00 10.1

7/27/2013 18:00 20 7/31/2013 11:00 59.7 8/3/2013 4:00 33.2 8/4/2013 21:00 26 8/12/2013 14:00 6

7/27/2013 19:00 27 7/31/2013 12:00 12.8 8/3/2013 5:00 41.8 8/4/2013 22:00 27.9 8/12/2013 15:00

7/27/2013 20:00 55.6 7/31/2013 13:00 13.3 8/3/2013 6:00 132 8/4/2013 23:00 46.6 8/12/2013 16:00 4.3

7/27/2013 21:00 68.4 7/31/2013 14:00 12.7 8/3/2013 7:00 88.3 8/9/2013 0:00 40.2 8/12/2013 17:00 5.7

7/27/2013 22:00 53 7/31/2013 15:00 6.7 8/3/2013 8:00 22.1 8/9/2013 1:00 39.4 8/12/2013 18:00 6.3

7/27/2013 23:00 35.4 7/31/2013 16:00 12.1 8/3/2013 9:00 17.1 8/9/2013 2:00 59.7 8/12/2013 19:00 10.8

7/28/2013 0:00 41 7/31/2013 17:00 14.3 8/3/2013 10:00 10.5 8/9/2013 3:00 131.4 8/12/2013 20:00 18.4

7/28/2013 1:00 66.5 7/31/2013 18:00 17.8 8/3/2013 11:00 4.3 8/9/2013 4:00 210.2 8/12/2013 21:00 16.5

7/28/2013 2:00 104.6 7/31/2013 19:00 28.5 8/3/2013 12:00 3.1 8/9/2013 5:00 193.6 8/12/2013 22:00 18.1

7/28/2013 3:00 70.2 7/31/2013 20:00 51.1 8/3/2013 13:00 4.5 8/9/2013 6:00 107 8/12/2013 23:00 13

7/28/2013 4:00 51 7/31/2013 21:00 173.1 8/3/2013 14:00 3.2 8/9/2013 7:00 77 8/13/2013 0:00 15.6

7/28/2013 5:00 95.7 7/31/2013 22:00 24.7 8/3/2013 15:00 2.2 8/9/2013 8:00 38.8 8/13/2013 1:00 15.4

7/28/2013 6:00 111.6 7/31/2013 23:00 31.3 8/3/2013 16:00 1.8 8/9/2013 9:00 16.1 8/13/2013 2:00 101.9

7/28/2013 7:00 119.7 8/2/2013 0:00 65.1 8/3/2013 17:00 1.7 8/9/2013 10:00 13.5 8/13/2013 3:00 99.8

7/28/2013 8:00 35.6 8/2/2013 1:00 62.7 8/3/2013 18:00 2.7 8/9/2013 11:00 6.4 8/13/2013 4:00 29.5

7/28/2013 9:00 24.3 8/2/2013 2:00 46.1 8/3/2013 19:00 9.5 8/9/2013 12:00 4.1 8/13/2013 5:00 17.6

7/28/2013 10:00 19.2 8/2/2013 3:00 55.1 8/3/2013 20:00 11.1 8/9/2013 13:00 3.3 8/13/2013 6:00 25

7/28/2013 11:00 8 8/2/2013 4:00 107.4 8/3/2013 21:00 35.9 8/9/2013 14:00 3.3 8/13/2013 7:00 16

7/28/2013 12:00 6.3 8/2/2013 5:00 123.2 8/3/2013 22:00 29 8/9/2013 15:00 2.6 8/13/2013 8:00 176.8

7/28/2013 13:00 5 8/2/2013 6:00 71.1 8/3/2013 23:00 24.7 8/9/2013 16:00 2.1 8/13/2013 9:00 161.3

7/28/2013 14:00 3.9 8/2/2013 7:00 86 8/4/2013 0:00 9.7 8/9/2013 17:00 1.8 8/13/2013 10:00 20.7

7/28/2013 15:00 4.3 8/2/2013 8:00 121.1 8/4/2013 1:00 26.6 8/9/2013 18:00 1.6 8/13/2013 11:00 14

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 70
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

8/13/2013 12:00 13.8 8/16/2013 5:00 24.4 8/18/2013 22:00 32.5 8/21/2013 15:00 2.5 8/25/2013 8:00 36.2

8/13/2013 13:00 21.5 8/16/2013 6:00 21.8 8/18/2013 23:00 29.6 8/21/2013 16:00 2.1 8/25/2013 9:00 13.7

8/13/2013 14:00 8/16/2013 7:00 20.1 8/19/2013 0:00 78.1 8/21/2013 17:00 1.9 8/25/2013 10:00 13.3

8/13/2013 15:00 8.4 8/16/2013 8:00 18.8 8/19/2013 1:00 63.7 8/21/2013 18:00 1.8 8/25/2013 11:00 7.7

8/13/2013 16:00 4.4 8/16/2013 9:00 29.6 8/19/2013 2:00 49.3 8/21/2013 19:00 1.6 8/25/2013 12:00 8.1

8/13/2013 17:00 3.8 8/16/2013 10:00 17 8/19/2013 3:00 127.3 8/21/2013 20:00 1.5 8/25/2013 13:00 4.3

8/13/2013 18:00 3.9 8/16/2013 11:00 7 8/19/2013 4:00 136.2 8/21/2013 21:00 1.7 8/25/2013 14:00 2.6

8/13/2013 19:00 14.1 8/16/2013 12:00 5 8/19/2013 5:00 115.2 8/21/2013 22:00 4.3 8/25/2013 15:00 2.1

8/13/2013 20:00 19.8 8/16/2013 13:00 2.5 8/19/2013 6:00 81.1 8/21/2013 23:00 12.9 8/25/2013 16:00 1.8

8/13/2013 21:00 21.1 8/16/2013 14:00 2.6 8/19/2013 7:00 107.7 8/24/2013 0:00 10.2 8/25/2013 17:00 2

8/13/2013 22:00 13.8 8/16/2013 15:00 4 8/19/2013 8:00 94.6 8/24/2013 1:00 83.3 8/25/2013 18:00 3

8/13/2013 23:00 20.3 8/16/2013 16:00 2.6 8/19/2013 9:00 14.4 8/24/2013 2:00 113.9 8/25/2013 19:00 5.5

8/15/2013 0:00 102 8/16/2013 17:00 3.5 8/19/2013 10:00 6.7 8/24/2013 3:00 163.7 8/25/2013 20:00 6.7

8/15/2013 1:00 90.9 8/16/2013 18:00 4.1 8/19/2013 11:00 3.2 8/24/2013 4:00 124.9 8/25/2013 21:00 6.1

8/15/2013 2:00 112.8 8/16/2013 19:00 3.1 8/19/2013 12:00 1.6 8/24/2013 5:00 125.5 8/25/2013 22:00 7.6

8/15/2013 3:00 85.3 8/16/2013 20:00 2.9 8/19/2013 13:00 1.5 8/24/2013 6:00 92.7 8/25/2013 23:00 7.6

8/15/2013 4:00 50.2 8/16/2013 21:00 5 8/19/2013 14:00 1.7 8/24/2013 7:00 64.1 8/27/2013 0:00 7.5

8/15/2013 5:00 49.4 8/16/2013 22:00 10.9 8/19/2013 15:00 8/24/2013 8:00 77.4 8/27/2013 1:00 5.1

8/15/2013 6:00 43.6 8/16/2013 23:00 9.9 8/19/2013 16:00 2.6 8/24/2013 9:00 13.1 8/27/2013 2:00 5.2

8/15/2013 7:00 33.8 8/18/2013 0:00 23.4 8/19/2013 17:00 2.5 8/24/2013 10:00 7.6 8/27/2013 3:00 12.7

8/15/2013 8:00 24.2 8/18/2013 1:00 15.8 8/19/2013 18:00 2.1 8/24/2013 11:00 4.6 8/27/2013 4:00 31.6

8/15/2013 9:00 14.8 8/18/2013 2:00 18.3 8/19/2013 19:00 1.8 8/24/2013 12:00 3.1 8/27/2013 5:00 23.4

8/15/2013 10:00 11.6 8/18/2013 3:00 18.6 8/19/2013 20:00 2.2 8/24/2013 13:00 2.4 8/27/2013 6:00 18.3

8/15/2013 11:00 5.6 8/18/2013 4:00 27.8 8/19/2013 21:00 2.7 8/24/2013 14:00 2 8/27/2013 7:00 91

8/15/2013 12:00 4.1 8/18/2013 5:00 62.3 8/19/2013 22:00 3.5 8/24/2013 15:00 1.9 8/27/2013 8:00 8.6

8/15/2013 13:00 4.1 8/18/2013 6:00 224.1 8/19/2013 23:00 5.2 8/24/2013 16:00 1.8 8/27/2013 9:00 6.5

8/15/2013 14:00 3.7 8/18/2013 7:00 146.1 8/21/2013 0:00 4.7 8/24/2013 17:00 2.2 8/27/2013 10:00 6

8/15/2013 15:00 3.9 8/18/2013 8:00 40.6 8/21/2013 1:00 6.3 8/24/2013 18:00 2.9 8/27/2013 11:00 3.5

8/15/2013 16:00 2.8 8/18/2013 9:00 9.5 8/21/2013 2:00 8.1 8/24/2013 19:00 4.9 8/27/2013 12:00 3

8/15/2013 17:00 3.6 8/18/2013 10:00 6.6 8/21/2013 3:00 14 8/24/2013 20:00 9.3 8/27/2013 13:00 1.9

8/15/2013 18:00 7.1 8/18/2013 11:00 3.6 8/21/2013 4:00 15.7 8/24/2013 21:00 45.6 8/27/2013 14:00

8/15/2013 19:00 8.4 8/18/2013 12:00 2.6 8/21/2013 5:00 47 8/24/2013 22:00 111.4 8/27/2013 15:00 3.1

8/15/2013 20:00 33.3 8/18/2013 13:00 2.1 8/21/2013 6:00 176.3 8/24/2013 23:00 63.9 8/27/2013 16:00 1.4

8/15/2013 21:00 30.1 8/18/2013 14:00 1.8 8/21/2013 7:00 368.5 8/25/2013 0:00 50.9 8/27/2013 17:00 1.3

8/15/2013 22:00 20.5 8/18/2013 15:00 1.7 8/21/2013 8:00 248.3 8/25/2013 1:00 42.2 8/27/2013 18:00 1.7

8/15/2013 23:00 26.7 8/18/2013 16:00 1.7 8/21/2013 9:00 73.4 8/25/2013 2:00 42.4 8/27/2013 19:00 1.7

8/16/2013 0:00 51.6 8/18/2013 17:00 2.1 8/21/2013 10:00 25.4 8/25/2013 3:00 96.3 8/27/2013 20:00 2

8/16/2013 1:00 87.6 8/18/2013 18:00 1.8 8/21/2013 11:00 8.4 8/25/2013 4:00 184.6 8/27/2013 21:00 17.8

8/16/2013 2:00 92.1 8/18/2013 19:00 2.2 8/21/2013 12:00 4.7 8/25/2013 5:00 96.6 8/27/2013 22:00 155.9

8/16/2013 3:00 35.6 8/18/2013 20:00 7.2 8/21/2013 13:00 3 8/25/2013 6:00 87.5 8/27/2013 23:00 158

8/16/2013 4:00 31.7 8/18/2013 21:00 32.1 8/21/2013 14:00 2.7 8/25/2013 7:00 94.3 8/28/2013 0:00 124.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 71
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

8/28/2013 1:00 123.1 8/30/2013 18:00 1.9 9/1/2013 11:00 5.5 9/3/2013 4:00 90.7 9/5/2013 21:00 27.7

8/28/2013 2:00 57.9 8/30/2013 19:00 1.8 9/1/2013 12:00 4.5 9/3/2013 5:00 128 9/5/2013 22:00 17.2

8/28/2013 3:00 69.1 8/30/2013 20:00 1.6 9/1/2013 13:00 7.8 9/3/2013 6:00 139.1 9/5/2013 23:00 9.8

8/28/2013 4:00 61.4 8/30/2013 21:00 1.9 9/1/2013 14:00 5.1 9/3/2013 7:00 142.4 9/6/2013 0:00 6.8

8/28/2013 5:00 59.6 8/30/2013 22:00 4 9/1/2013 15:00 2.9 9/3/2013 8:00 166.6 9/6/2013 1:00 7.9

8/28/2013 6:00 24.4 8/30/2013 23:00 6.2 9/1/2013 16:00 2.5 9/3/2013 9:00 46 9/6/2013 2:00 9

8/28/2013 7:00 23.8 8/31/2013 0:00 6.8 9/1/2013 17:00 2.7 9/3/2013 10:00 11.5 9/6/2013 3:00 14.1

8/28/2013 8:00 29 8/31/2013 1:00 6.2 9/1/2013 18:00 6 9/3/2013 11:00 6.6 9/6/2013 4:00 26.8

8/28/2013 9:00 27.3 8/31/2013 2:00 5.8 9/1/2013 19:00 6.3 9/3/2013 12:00 3.3 9/6/2013 5:00 20.5

8/28/2013 10:00 26 8/31/2013 3:00 5.6 9/1/2013 20:00 29.6 9/3/2013 13:00 1.8 9/6/2013 6:00 14.3

8/28/2013 11:00 22.2 8/31/2013 4:00 5.7 9/1/2013 21:00 45.5 9/3/2013 14:00 9/6/2013 7:00 28.4

8/28/2013 12:00 15.5 8/31/2013 5:00 25.5 9/1/2013 22:00 55.6 9/3/2013 15:00 3.2 9/6/2013 8:00 113.4

8/28/2013 13:00 14.9 8/31/2013 6:00 83.5 9/1/2013 23:00 31.1 9/3/2013 16:00 1.8 9/6/2013 9:00 75.2

8/28/2013 14:00 11.8 8/31/2013 7:00 103 9/2/2013 0:00 32.2 9/3/2013 17:00 2.7 9/6/2013 10:00 25.8

8/28/2013 15:00 8.1 8/31/2013 8:00 63.8 9/2/2013 1:00 12.6 9/3/2013 18:00 3 9/6/2013 11:00 10.9

8/28/2013 16:00 6.1 8/31/2013 9:00 14.2 9/2/2013 2:00 16.7 9/3/2013 19:00 2.6 9/6/2013 12:00 5.2

8/28/2013 17:00 4.5 8/31/2013 10:00 7.4 9/2/2013 3:00 17.4 9/3/2013 20:00 7.2 9/6/2013 13:00 3.5

8/28/2013 18:00 3.9 8/31/2013 11:00 5 9/2/2013 4:00 21.5 9/3/2013 21:00 12.9 9/6/2013 14:00 2.9

8/28/2013 19:00 3.8 8/31/2013 12:00 3.6 9/2/2013 5:00 64.3 9/3/2013 22:00 57.5 9/6/2013 15:00 2.3

8/28/2013 20:00 3.4 8/31/2013 13:00 2.7 9/2/2013 6:00 73.9 9/3/2013 23:00 52.6 9/6/2013 16:00 2

8/28/2013 21:00 3.1 8/31/2013 14:00 2.6 9/2/2013 7:00 50.7 9/5/2013 0:00 31.2 9/6/2013 17:00 1.8

8/28/2013 22:00 3.1 8/31/2013 15:00 2.1 9/2/2013 8:00 137.6 9/5/2013 1:00 24.4 9/6/2013 18:00 1.7

8/28/2013 23:00 4.5 8/31/2013 16:00 1.8 9/2/2013 9:00 25.4 9/5/2013 2:00 24.5 9/6/2013 19:00 1.6

8/30/2013 0:00 29 8/31/2013 17:00 1.8 9/2/2013 10:00 7.9 9/5/2013 3:00 26.9 9/6/2013 20:00 1.8

8/30/2013 1:00 21.6 8/31/2013 18:00 2.1 9/2/2013 11:00 5.9 9/5/2013 4:00 43.3 9/6/2013 21:00 5.4

8/30/2013 2:00 62 8/31/2013 19:00 6.1 9/2/2013 12:00 4.7 9/5/2013 5:00 77.4 9/6/2013 22:00 32.5

8/30/2013 3:00 29.6 8/31/2013 20:00 18 9/2/2013 13:00 3.6 9/5/2013 6:00 36.7 9/6/2013 23:00 44.8

8/30/2013 4:00 16 8/31/2013 21:00 41 9/2/2013 14:00 2.6 9/5/2013 7:00 37 9/10/2013 0:00 113.8

8/30/2013 5:00 21.5 8/31/2013 22:00 39.5 9/2/2013 15:00 9/5/2013 8:00 22 9/10/2013 1:00 212.5

8/30/2013 6:00 93 8/31/2013 23:00 36.2 9/2/2013 16:00 2 9/5/2013 9:00 12.9 9/10/2013 2:00 325.2

8/30/2013 7:00 105.7 9/1/2013 0:00 46.9 9/2/2013 17:00 1.8 9/5/2013 10:00 7.6 9/10/2013 3:00 252.8

8/30/2013 8:00 29.5 9/1/2013 1:00 77.4 9/2/2013 18:00 2.1 9/5/2013 11:00 8.6 9/10/2013 4:00 379.9

8/30/2013 9:00 20.9 9/1/2013 2:00 68.3 9/2/2013 19:00 3.4 9/5/2013 12:00 8.5 9/10/2013 5:00 259.8

8/30/2013 10:00 21 9/1/2013 3:00 85.6 9/2/2013 20:00 18 9/5/2013 13:00 1.5 9/10/2013 6:00 117.3

8/30/2013 11:00 196.1 9/1/2013 4:00 116.1 9/2/2013 21:00 23 9/5/2013 14:00 1.5 9/10/2013 7:00 141.4

8/30/2013 12:00 10.4 9/1/2013 5:00 22.9 9/2/2013 22:00 17.3 9/5/2013 15:00 2.7 9/10/2013 8:00 181

8/30/2013 13:00 4.9 9/1/2013 6:00 15.4 9/2/2013 23:00 12.1 9/5/2013 16:00 2.4 9/10/2013 9:00 105.1

8/30/2013 14:00 3.2 9/1/2013 7:00 111.8 9/3/2013 0:00 15.4 9/5/2013 17:00 2.3 9/10/2013 10:00 15.2

8/30/2013 15:00 2.4 9/1/2013 8:00 388.2 9/3/2013 1:00 14.4 9/5/2013 18:00 2.1 9/10/2013 11:00 6.7

8/30/2013 16:00 2.2 9/1/2013 9:00 24.1 9/3/2013 2:00 19.7 9/5/2013 19:00 2 9/10/2013 12:00 4

8/30/2013 17:00 2.1 9/1/2013 10:00 10 9/3/2013 3:00 22.7 9/5/2013 20:00 54.5 9/10/2013 13:00 2.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 72
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

9/10/2013 14:00 9/12/2013 7:00 40 9/14/2013 0:00 14.1 9/15/2013 17:00 2.2 9/17/2013 10:00 93.6

9/10/2013 15:00 5.2 9/12/2013 8:00 34.6 9/14/2013 1:00 14.2 9/15/2013 18:00 3.3 9/17/2013 11:00 25.6

9/10/2013 16:00 3 9/12/2013 9:00 19.4 9/14/2013 2:00 20.4 9/15/2013 19:00 48.2 9/17/2013 12:00

9/10/2013 17:00 2.4 9/12/2013 10:00 18.5 9/14/2013 3:00 29.7 9/15/2013 20:00 49.3 9/17/2013 13:00 7.2

9/10/2013 18:00 2.2 9/12/2013 11:00 10.4 9/14/2013 4:00 35.6 9/15/2013 21:00 87.3 9/17/2013 14:00

9/10/2013 19:00 10.6 9/12/2013 12:00 7.6 9/14/2013 5:00 77.4 9/15/2013 22:00 82.7 9/17/2013 15:00 9.6

9/10/2013 20:00 15.5 9/12/2013 13:00 8.7 9/14/2013 6:00 55.8 9/15/2013 23:00 16.1 9/17/2013 16:00 10.2

9/10/2013 21:00 16.7 9/12/2013 14:00 9.7 9/14/2013 7:00 41.3 9/16/2013 0:00 6 9/17/2013 17:00 16.9

9/10/2013 22:00 21.6 9/12/2013 15:00 8.6 9/14/2013 8:00 47.2 9/16/2013 1:00 4.2 9/17/2013 18:00 39.7

9/10/2013 23:00 22.2 9/12/2013 16:00 5.2 9/14/2013 9:00 22.6 9/16/2013 2:00 3 9/17/2013 19:00 77

9/11/2013 0:00 27.5 9/12/2013 17:00 4.1 9/14/2013 10:00 7.2 9/16/2013 3:00 2.4 9/17/2013 20:00 27.1

9/11/2013 1:00 28.5 9/12/2013 18:00 3.9 9/14/2013 11:00 3.8 9/16/2013 4:00 4.2 9/17/2013 21:00 8.4

9/11/2013 2:00 52.2 9/12/2013 19:00 3.3 9/14/2013 12:00 2.8 9/16/2013 5:00 9.5 9/17/2013 22:00 128.5

9/11/2013 3:00 54.1 9/12/2013 20:00 3 9/14/2013 13:00 2.4 9/16/2013 6:00 2.2 9/17/2013 23:00 123.1

9/11/2013 4:00 79.7 9/12/2013 21:00 7.2 9/14/2013 14:00 2.1 9/16/2013 7:00 48.1 9/18/2013 0:00 120.3

9/11/2013 5:00 69.1 9/12/2013 22:00 47.9 9/14/2013 15:00 1.8 9/16/2013 8:00 222.2 9/18/2013 1:00 36.3

9/11/2013 6:00 133.5 9/12/2013 23:00 78 9/14/2013 16:00 1.7 9/16/2013 9:00 118.3 9/18/2013 2:00 50.5

9/11/2013 7:00 144 9/13/2013 0:00 34.9 9/14/2013 17:00 1.7 9/16/2013 10:00 48.9 9/18/2013 3:00 37.7

9/11/2013 8:00 79.8 9/13/2013 1:00 42.2 9/14/2013 18:00 1.6 9/16/2013 11:00 19.7 9/18/2013 4:00 41.6

9/11/2013 9:00 35.8 9/13/2013 2:00 42.9 9/14/2013 19:00 1.5 9/16/2013 12:00 4.4 9/18/2013 5:00 12.5

9/11/2013 10:00 13.5 9/13/2013 3:00 66.3 9/14/2013 20:00 1.4 9/16/2013 13:00 4 9/18/2013 6:00 6.4

9/11/2013 11:00 6.1 9/13/2013 4:00 118.3 9/14/2013 21:00 1.4 9/16/2013 14:00 3.1 9/18/2013 7:00 22

9/11/2013 12:00 3.6 9/13/2013 5:00 99 9/14/2013 22:00 1.7 9/16/2013 15:00 9/18/2013 8:00 25.5

9/11/2013 13:00 2.5 9/13/2013 6:00 53.9 9/14/2013 23:00 2 9/16/2013 16:00 3.6 9/18/2013 9:00 16.7

9/11/2013 14:00 2.3 9/13/2013 7:00 41.5 9/15/2013 0:00 4.1 9/16/2013 17:00 4.4 9/18/2013 10:00 5.5

9/11/2013 15:00 2.3 9/13/2013 8:00 40.4 9/15/2013 1:00 22.6 9/16/2013 18:00 33.2 9/18/2013 11:00 2

9/11/2013 16:00 2.2 9/13/2013 9:00 16.9 9/15/2013 2:00 30.9 9/16/2013 19:00 42.2 9/18/2013 12:00 1.6

9/11/2013 17:00 2.3 9/13/2013 10:00 8.5 9/15/2013 3:00 24.9 9/16/2013 20:00 13.9 9/18/2013 13:00 1.7

9/11/2013 18:00 2.1 9/13/2013 11:00 4.2 9/15/2013 4:00 21.5 9/16/2013 21:00 20.4 9/18/2013 14:00 1.5

9/11/2013 19:00 2.4 9/13/2013 12:00 2.7 9/15/2013 5:00 19.2 9/16/2013 22:00 7.7 9/18/2013 15:00 1.5

9/11/2013 20:00 2.6 9/13/2013 13:00 2.6 9/15/2013 6:00 35.5 9/16/2013 23:00 3.6 9/18/2013 16:00 1.7

9/11/2013 21:00 7.9 9/13/2013 14:00 2.4 9/15/2013 7:00 14.2 9/17/2013 0:00 3.4 9/18/2013 17:00

9/11/2013 22:00 15.2 9/13/2013 15:00 2.3 9/15/2013 8:00 12 9/17/2013 1:00 9.2 9/18/2013 18:00 6.2

9/11/2013 23:00 17.6 9/13/2013 16:00 2.1 9/15/2013 9:00 10.3 9/17/2013 2:00 6.6 9/18/2013 19:00 4

9/12/2013 0:00 16.2 9/13/2013 17:00 2 9/15/2013 10:00 8.3 9/17/2013 3:00 72.6 9/18/2013 20:00 13.6

9/12/2013 1:00 25.4 9/13/2013 18:00 1.8 9/15/2013 11:00 4 9/17/2013 4:00 174.9 9/18/2013 21:00 27.3

9/12/2013 2:00 35.3 9/13/2013 19:00 1.8 9/15/2013 12:00 2.8 9/17/2013 5:00 189.2 9/18/2013 22:00 48.4

9/12/2013 3:00 58.7 9/13/2013 20:00 1.9 9/15/2013 13:00 2.1 9/17/2013 6:00 334.6 9/18/2013 23:00 53.3

9/12/2013 4:00 54.3 9/13/2013 21:00 2.3 9/15/2013 14:00 1.9 9/17/2013 7:00 164.2 9/19/2013 0:00 29.3

9/12/2013 5:00 46.5 9/13/2013 22:00 5.1 9/15/2013 15:00 1.7 9/17/2013 8:00 186.1 9/19/2013 1:00 26.3

9/12/2013 6:00 34.2 9/13/2013 23:00 10.3 9/15/2013 16:00 1.6 9/17/2013 9:00 50.9 9/19/2013 2:00 22.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 73
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

9/19/2013 3:00 20.2 9/20/2013 20:00 40.8 9/25/2013 2:00 124.3 9/26/2013 19:00 2.8 9/28/2013 12:00 3.8

9/19/2013 4:00 20.1 9/20/2013 21:00 22 9/25/2013 3:00 127.8 9/26/2013 20:00 24.4 9/28/2013 13:00 8.4

9/19/2013 5:00 20.4 9/20/2013 22:00 15.9 9/25/2013 4:00 181.1 9/26/2013 21:00 12.4 9/28/2013 14:00 6

9/19/2013 6:00 77.2 9/20/2013 23:00 10.7 9/25/2013 5:00 72.3 9/26/2013 22:00 20.1 9/28/2013 15:00 10.2

9/19/2013 7:00 93.9 9/21/2013 0:00 37.8 9/25/2013 6:00 29 9/26/2013 23:00 14.3 9/28/2013 16:00 6.9

9/19/2013 8:00 72.2 9/21/2013 1:00 26.8 9/25/2013 7:00 30.9 9/27/2013 0:00 14.9 9/28/2013 17:00 89.7

9/19/2013 9:00 15.7 9/21/2013 2:00 5.1 9/25/2013 8:00 21.7 9/27/2013 1:00 59.2 9/28/2013 18:00 204

9/19/2013 10:00 11.2 9/21/2013 3:00 4.9 9/25/2013 9:00 16.4 9/27/2013 2:00 113.1 9/28/2013 19:00 151.5

9/19/2013 11:00 4 9/21/2013 4:00 6.9 9/25/2013 10:00 6 9/27/2013 3:00 250.1 9/28/2013 20:00 33.9

9/19/2013 12:00 2.6 9/21/2013 5:00 34.1 9/25/2013 11:00 6.5 9/27/2013 4:00 80.7 9/28/2013 21:00 12.5

9/19/2013 13:00 2.4 9/21/2013 6:00 48.3 9/25/2013 12:00 4.1 9/27/2013 5:00 151.2 9/28/2013 22:00 14

9/19/2013 14:00 2.2 9/21/2013 7:00 170.2 9/25/2013 13:00 1.9 9/27/2013 6:00 132.2 9/28/2013 23:00 48.7

9/19/2013 15:00 2.9 9/21/2013 8:00 119.7 9/25/2013 14:00 1.8 9/27/2013 7:00 31.7 9/29/2013 0:00 38.5

9/19/2013 16:00 2.2 9/21/2013 9:00 33.1 9/25/2013 15:00 2.5 9/27/2013 8:00 22.1 9/29/2013 1:00 37.7

9/19/2013 17:00 2.3 9/21/2013 10:00 11.4 9/25/2013 16:00 5.4 9/27/2013 9:00 16.4 9/29/2013 2:00 57.2

9/19/2013 18:00 7.3 9/24/2013 0:00 43.5 9/25/2013 17:00 6.1 9/27/2013 10:00 8.3 9/29/2013 3:00 71.3

9/19/2013 19:00 55.6 9/24/2013 1:00 60 9/25/2013 18:00 31.1 9/27/2013 11:00 3.8 9/29/2013 4:00 57.4

9/19/2013 20:00 53.5 9/24/2013 2:00 66 9/25/2013 19:00 129.6 9/27/2013 12:00 2.6 9/29/2013 5:00 47.4

9/19/2013 21:00 82.3 9/24/2013 3:00 34.3 9/25/2013 20:00 63.7 9/27/2013 13:00 2.4 9/29/2013 6:00 119.6

9/19/2013 22:00 53.5 9/24/2013 4:00 22.7 9/25/2013 21:00 19.6 9/27/2013 14:00 2.2 9/29/2013 7:00 121.2

9/19/2013 23:00 36.3 9/24/2013 5:00 21.6 9/25/2013 22:00 69.4 9/27/2013 15:00 2.2 9/29/2013 8:00 83.2

9/20/2013 0:00 23.6 9/24/2013 6:00 56.3 9/25/2013 23:00 167.3 9/27/2013 16:00 2.2 9/29/2013 9:00 166.5

9/20/2013 1:00 37.2 9/24/2013 7:00 104.5 9/26/2013 0:00 104.5 9/27/2013 17:00 2.2 9/29/2013 10:00 11.5

9/20/2013 2:00 113 9/24/2013 8:00 106.7 9/26/2013 1:00 66 9/27/2013 18:00 4.3 9/29/2013 11:00 11.7

9/20/2013 3:00 181.5 9/24/2013 9:00 94.2 9/26/2013 2:00 64.7 9/27/2013 19:00 8.3 9/29/2013 12:00 5.9

9/20/2013 4:00 68.7 9/24/2013 10:00 114.9 9/26/2013 3:00 263.5 9/27/2013 20:00 40.3 9/29/2013 13:00 3.8

9/20/2013 5:00 34.3 9/24/2013 11:00 6 9/26/2013 4:00 274.2 9/27/2013 21:00 63.6 9/29/2013 14:00 3.2

9/20/2013 6:00 24.7 9/24/2013 12:00 4.7 9/26/2013 5:00 188 9/27/2013 22:00 24.3 9/29/2013 15:00 2.5

9/20/2013 7:00 241.2 9/24/2013 13:00 4.2 9/26/2013 6:00 82.1 9/27/2013 23:00 14.9 9/29/2013 16:00 2.3

9/20/2013 8:00 113.8 9/24/2013 14:00 9/26/2013 7:00 147.7 9/28/2013 0:00 34.1 9/29/2013 17:00 2.3

9/20/2013 9:00 31.4 9/24/2013 15:00 7.5 9/26/2013 8:00 90.8 9/28/2013 1:00 21.1 9/29/2013 18:00 2.2

9/20/2013 10:00 10.2 9/24/2013 16:00 3.4 9/26/2013 9:00 410.7 9/28/2013 2:00 19.7 9/29/2013 19:00 9.3

9/20/2013 11:00 9.5 9/24/2013 17:00 2.9 9/26/2013 10:00 124.3 9/28/2013 3:00 38.1 9/29/2013 20:00 26.4

9/20/2013 12:00 6.4 9/24/2013 18:00 2.8 9/26/2013 11:00 16 9/28/2013 4:00 61 9/29/2013 21:00 25.7

9/20/2013 13:00 5.7 9/24/2013 19:00 2.8 9/26/2013 12:00 7.2 9/28/2013 5:00 15.7 9/29/2013 22:00 35.3

9/20/2013 14:00 3.4 9/24/2013 20:00 4.9 9/26/2013 13:00 4.5 9/28/2013 6:00 5.1 9/29/2013 23:00 29.3

9/20/2013 15:00 3 9/24/2013 21:00 9 9/26/2013 14:00 3.5 9/28/2013 7:00 15.1 10/1/2013 0:00 87

9/20/2013 16:00 2.4 9/24/2013 22:00 10.3 9/26/2013 15:00 4 9/28/2013 8:00 112.7 10/1/2013 1:00 67.5

9/20/2013 17:00 3 9/24/2013 23:00 8.4 9/26/2013 16:00 3 9/28/2013 9:00 14 10/1/2013 2:00 45.7

9/20/2013 18:00 14.9 9/25/2013 0:00 5.1 9/26/2013 17:00 2.7 9/28/2013 10:00 39.5 10/1/2013 3:00 27.5

9/20/2013 19:00 83.6 9/25/2013 1:00 4.6 9/26/2013 18:00 2.6 9/28/2013 11:00 3.9 10/1/2013 4:00 18.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 74
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

10/1/2013 5:00 16.4 10/2/2013 22:00 24 10/4/2013 15:00 2.3 10/6/2013 8:00 26.2 10/9/2013 1:00 18.9

10/1/2013 6:00 19.3 10/2/2013 23:00 74.8 10/4/2013 16:00 2.1 10/6/2013 9:00 16.7 10/9/2013 2:00 25.6

10/1/2013 7:00 17.5 10/3/2013 0:00 73.6 10/4/2013 17:00 2.2 10/6/2013 10:00 11.3 10/9/2013 3:00 12.5

10/1/2013 8:00 39.7 10/3/2013 1:00 127.8 10/4/2013 18:00 5.5 10/6/2013 11:00 3.7 10/9/2013 4:00 10.1

10/1/2013 9:00 19.5 10/3/2013 2:00 64.2 10/4/2013 19:00 9.5 10/6/2013 12:00 2.7 10/9/2013 5:00 34.5

10/1/2013 10:00 5.1 10/3/2013 3:00 51.2 10/4/2013 20:00 18.1 10/6/2013 13:00 2.2 10/9/2013 6:00 80.8

10/1/2013 11:00 3.6 10/3/2013 4:00 47.1 10/4/2013 21:00 48.3 10/6/2013 14:00 2.5 10/9/2013 7:00 141.9

10/1/2013 12:00 2.9 10/3/2013 5:00 92.9 10/4/2013 22:00 66.8 10/6/2013 15:00 2.5 10/9/2013 8:00 117.6

10/1/2013 13:00 2.5 10/3/2013 6:00 49.6 10/4/2013 23:00 41.9 10/6/2013 16:00 2.3 10/9/2013 9:00 30.5

10/1/2013 14:00 10/3/2013 7:00 20.2 10/5/2013 0:00 24.5 10/6/2013 17:00 2.2 10/9/2013 10:00 10.5

10/1/2013 15:00 4.5 10/3/2013 8:00 27.3 10/5/2013 1:00 10.8 10/6/2013 18:00 2.6 10/9/2013 11:00 4.7

10/1/2013 16:00 2.6 10/3/2013 9:00 14.3 10/5/2013 2:00 8.4 10/6/2013 19:00 8.4 10/9/2013 12:00 3.4

10/1/2013 17:00 2.2 10/3/2013 10:00 10 10/5/2013 3:00 11.3 10/6/2013 20:00 10.5 10/9/2013 13:00 3.5

10/1/2013 18:00 2.1 10/3/2013 11:00 4.5 10/5/2013 4:00 60.6 10/6/2013 21:00 11.7 10/9/2013 14:00 2.4

10/1/2013 19:00 5.2 10/3/2013 12:00 4.2 10/5/2013 5:00 162.4 10/6/2013 22:00 10.4 10/9/2013 15:00 2.5

10/1/2013 20:00 41.4 10/3/2013 13:00 2.8 10/5/2013 6:00 77.6 10/6/2013 23:00 10.2 10/9/2013 16:00 2.6

10/1/2013 21:00 20.5 10/3/2013 14:00 2.4 10/5/2013 7:00 38.5 10/8/2013 0:00 38.6 10/9/2013 17:00 3.2

10/1/2013 22:00 27.4 10/3/2013 15:00 3.3 10/5/2013 8:00 19.9 10/8/2013 1:00 45.9 10/9/2013 18:00 108.7

10/1/2013 23:00 80.1 10/3/2013 16:00 2.3 10/5/2013 9:00 22.8 10/8/2013 2:00 31.7 10/9/2013 19:00 138.7

10/2/2013 0:00 71.9 10/3/2013 17:00 2.1 10/5/2013 10:00 8.6 10/8/2013 3:00 23.4 10/9/2013 20:00 61.6

10/2/2013 1:00 41.5 10/3/2013 18:00 2 10/5/2013 11:00 6.7 10/8/2013 4:00 31.4 10/9/2013 21:00 44.8

10/2/2013 2:00 49.3 10/3/2013 19:00 2 10/5/2013 12:00 4.8 10/8/2013 5:00 30.9 10/9/2013 22:00 36.7

10/2/2013 3:00 30.6 10/3/2013 20:00 2.5 10/5/2013 13:00 4 10/8/2013 6:00 35.5 10/9/2013 23:00 31.3

10/2/2013 4:00 7.5 10/3/2013 21:00 3.9 10/5/2013 14:00 2.9 10/8/2013 7:00 32.9 10/11/2013 0:00 33.4

10/2/2013 5:00 8.7 10/3/2013 22:00 3.2 10/5/2013 15:00 2.6 10/8/2013 8:00 55.4 10/11/2013 1:00 32.1

10/2/2013 6:00 11.2 10/3/2013 23:00 12.7 10/5/2013 16:00 4.5 10/8/2013 9:00 17.3 10/11/2013 2:00 22

10/2/2013 7:00 12.2 10/4/2013 0:00 41.8 10/5/2013 17:00 6.7 10/8/2013 10:00 13.9 10/11/2013 3:00 6.1

10/2/2013 8:00 16 10/4/2013 1:00 14.9 10/5/2013 18:00 24.6 10/8/2013 11:00 14.9 10/11/2013 4:00 4.1

10/2/2013 9:00 11.4 10/4/2013 2:00 5.6 10/5/2013 19:00 37.9 10/8/2013 12:00 5.1 10/11/2013 5:00 4.2

10/2/2013 10:00 8.8 10/4/2013 3:00 6 10/5/2013 20:00 131.4 10/8/2013 13:00 11.9 10/11/2013 6:00 104.7

10/2/2013 11:00 3.5 10/4/2013 4:00 21.3 10/5/2013 21:00 132.3 10/8/2013 14:00 10/11/2013 7:00 39.1

10/2/2013 12:00 3 10/4/2013 5:00 11.9 10/5/2013 22:00 85.3 10/8/2013 15:00 6.4 10/11/2013 8:00 16.9

10/2/2013 13:00 2.8 10/4/2013 6:00 8.6 10/5/2013 23:00 66.7 10/8/2013 16:00 5.6 10/11/2013 9:00 59.1

10/2/2013 14:00 2.2 10/4/2013 7:00 44.4 10/6/2013 0:00 56.5 10/8/2013 17:00 5.2 10/11/2013 10:00 69.3

10/2/2013 15:00 2 10/4/2013 8:00 123.7 10/6/2013 1:00 65.5 10/8/2013 18:00 4 10/11/2013 11:00 24.8

10/2/2013 16:00 5.2 10/4/2013 9:00 31.5 10/6/2013 2:00 54.1 10/8/2013 19:00 8.7 10/11/2013 12:00 7.4

10/2/2013 17:00 17.2 10/4/2013 10:00 10.5 10/6/2013 3:00 34.3 10/8/2013 20:00 24.3 10/11/2013 13:00 2.8

10/2/2013 18:00 33.4 10/4/2013 11:00 5.3 10/6/2013 4:00 65.8 10/8/2013 21:00 286.7 10/11/2013 14:00 2

10/2/2013 19:00 74.4 10/4/2013 12:00 3.9 10/6/2013 5:00 45.1 10/8/2013 22:00 82 10/11/2013 15:00 2.6

10/2/2013 20:00 84.7 10/4/2013 13:00 2.9 10/6/2013 6:00 167.1 10/8/2013 23:00 66.2 10/11/2013 16:00 2.9

10/2/2013 21:00 40.4 10/4/2013 14:00 2.4 10/6/2013 7:00 79.2 10/9/2013 0:00 80.6 10/11/2013 17:00 3.1

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 75
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

10/11/2013 18:00 3.1 10/16/2013 11:00 7.3 10/24/2013 4:00 50.2 10/25/2013 21:00 2.2 10/30/2013 14:00 4.4

10/11/2013 19:00 2.9 10/16/2013 12:00 4.9 10/24/2013 5:00 45.9 10/25/2013 22:00 3.4 10/30/2013 15:00 3.1

10/11/2013 20:00 2.6 10/16/2013 13:00 2.9 10/24/2013 6:00 61 10/25/2013 23:00 5.8 10/30/2013 16:00 2.6

10/11/2013 21:00 2.4 10/16/2013 14:00 2.4 10/24/2013 7:00 71.2 10/29/2013 0:00 75.4 10/30/2013 17:00 2.3

10/11/2013 22:00 2.2 10/16/2013 15:00 2.4 10/24/2013 8:00 121.8 10/29/2013 1:00 97.1 10/30/2013 18:00 4.5

10/11/2013 23:00 4.8 10/16/2013 16:00 2.2 10/24/2013 9:00 66.8 10/29/2013 2:00 122.6 10/30/2013 19:00 27.2

10/12/2013 0:00 13.7 10/16/2013 17:00 2.2 10/24/2013 10:00 15.1 10/29/2013 3:00 102.5 10/30/2013 20:00 56.2

10/12/2013 1:00 25.3 10/16/2013 18:00 16.3 10/24/2013 11:00 6.7 10/29/2013 4:00 96.4 10/30/2013 21:00 32.3

10/12/2013 2:00 22.2 10/16/2013 19:00 8.5 10/24/2013 12:00 3.5 10/29/2013 5:00 83.2 10/30/2013 22:00 30.4

10/12/2013 3:00 19.2 10/16/2013 20:00 3.9 10/24/2013 13:00 2.9 10/29/2013 6:00 61.9 10/30/2013 23:00 27

10/12/2013 4:00 43.5 10/16/2013 21:00 3 10/24/2013 14:00 2.5 10/29/2013 7:00 46.6 10/31/2013 0:00 16.1

10/12/2013 5:00 65.1 10/16/2013 22:00 2.5 10/24/2013 15:00 3.1 10/29/2013 8:00 66.2 10/31/2013 1:00 9.4

10/12/2013 6:00 50.7 10/16/2013 23:00 2.3 10/24/2013 16:00 2.5 10/29/2013 9:00 69.5 10/31/2013 2:00 39.6

10/12/2013 7:00 47.4 10/23/2013 0:00 93.4 10/24/2013 17:00 2.4 10/29/2013 10:00 11 10/31/2013 3:00 46.8

10/12/2013 8:00 89.3 10/23/2013 1:00 129.5 10/24/2013 18:00 2.2 10/29/2013 11:00 6.3 10/31/2013 4:00 53.8

10/12/2013 9:00 56.9 10/23/2013 2:00 122.1 10/24/2013 19:00 2.1 10/29/2013 12:00 3.6 10/31/2013 5:00 43.9

10/12/2013 10:00 19.9 10/23/2013 3:00 118.5 10/24/2013 20:00 2.6 10/29/2013 13:00 2.8 10/31/2013 6:00 23.8

10/12/2013 11:00 8.7 10/23/2013 4:00 100.8 10/24/2013 21:00 3.9 10/29/2013 14:00 10/31/2013 7:00 24

10/12/2013 12:00 4.4 10/23/2013 5:00 167.2 10/24/2013 22:00 7.2 10/29/2013 15:00 4.2 10/31/2013 8:00 31.7

10/12/2013 13:00 3.1 10/23/2013 6:00 168.1 10/24/2013 23:00 9 10/29/2013 16:00 2.8 10/31/2013 9:00 28.4

10/12/2013 14:00 2.6 10/23/2013 7:00 169.7 10/25/2013 0:00 15 10/29/2013 17:00 2.5 10/31/2013 10:00 11.6

10/12/2013 15:00 2.3 10/23/2013 8:00 100.3 10/25/2013 1:00 45.2 10/29/2013 18:00 2.9 10/31/2013 11:00 3.7

10/12/2013 16:00 2.1 10/23/2013 9:00 42.9 10/25/2013 2:00 52.5 10/29/2013 19:00 6.9 10/31/2013 12:00 2.7

10/12/2013 17:00 2.1 10/23/2013 10:00 34.6 10/25/2013 3:00 59.5 10/29/2013 20:00 12.8 10/31/2013 13:00 2.5

10/12/2013 18:00 1.9 10/23/2013 11:00 14.8 10/25/2013 4:00 84.8 10/29/2013 21:00 97 10/31/2013 14:00 2.3

10/12/2013 19:00 1.8 10/23/2013 12:00 5.6 10/25/2013 5:00 117 10/29/2013 22:00 142.2 10/31/2013 15:00 3.4

10/12/2013 20:00 2 10/23/2013 13:00 4.2 10/25/2013 6:00 128.1 10/29/2013 23:00 63.2 10/31/2013 16:00 2.3

10/12/2013 21:00 1.8 10/23/2013 14:00 3 10/25/2013 7:00 74.7 10/30/2013 0:00 42.9 10/31/2013 17:00 2.2

10/12/2013 22:00 1.8 10/23/2013 15:00 2.7 10/25/2013 8:00 55.9 10/30/2013 1:00 72.5 10/31/2013 18:00 2.7

10/12/2013 23:00 2 10/23/2013 16:00 2.4 10/25/2013 9:00 68.6 10/30/2013 2:00 125.2 10/31/2013 19:00 13.1

10/16/2013 0:00 42.5 10/23/2013 17:00 2.3 10/25/2013 10:00 57.7 10/30/2013 3:00 104 10/31/2013 20:00 53.6

10/16/2013 1:00 40.9 10/23/2013 18:00 2 10/25/2013 11:00 25.2 10/30/2013 4:00 117.1 10/31/2013 21:00 70.4

10/16/2013 2:00 36.1 10/23/2013 19:00 3.8 10/25/2013 12:00 10.2 10/30/2013 5:00 90.7 10/31/2013 22:00 90.2

10/16/2013 3:00 41.7 10/23/2013 20:00 6.9 10/25/2013 13:00 6.7 10/30/2013 6:00 118.1 10/31/2013 23:00 89.9

10/16/2013 4:00 37.2 10/23/2013 21:00 9.1 10/25/2013 14:00 5 10/30/2013 7:00 119.9 11/1/2013 0:00 78.1

10/16/2013 5:00 58.8 10/23/2013 22:00 8.4 10/25/2013 15:00 3.3 10/30/2013 8:00 266.5 11/1/2013 1:00 67

10/16/2013 6:00 122 10/23/2013 23:00 11.3 10/25/2013 16:00 2.8 10/30/2013 9:00 305.2 11/1/2013 2:00 66.5

10/16/2013 7:00 118.6 10/24/2013 0:00 14.6 10/25/2013 17:00 2.7 10/30/2013 10:00 26.5 11/1/2013 3:00 53.4

10/16/2013 8:00 105.8 10/24/2013 1:00 32.1 10/25/2013 18:00 2.5 10/30/2013 11:00 7.8 11/1/2013 4:00 67.9

10/16/2013 9:00 48.7 10/24/2013 2:00 41.8 10/25/2013 19:00 2.3 10/30/2013 12:00 5.7 11/1/2013 5:00 81.5

10/16/2013 10:00 19.9 10/24/2013 3:00 46.8 10/25/2013 20:00 2.1 10/30/2013 13:00 5.3 11/1/2013 6:00 79.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 76
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/1/2013 7:00 61.6 11/3/2013 0:00 22.2 11/9/2013 17:00 1.9 11/12/2013 10:00 142.3 11/15/2013 3:00 2.6

11/1/2013 8:00 101.1 11/3/2013 1:00 4.2 11/9/2013 18:00 5.5 11/12/2013 11:00 59.3 11/15/2013 4:00 47.9

11/1/2013 9:00 100.6 11/3/2013 2:00 3 11/9/2013 19:00 9.2 11/12/2013 12:00 41.9 11/15/2013 5:00 97.6

11/1/2013 10:00 9.3 11/3/2013 3:00 2.8 11/9/2013 20:00 15.9 11/12/2013 13:00 42.5 11/15/2013 6:00 56.9

11/1/2013 11:00 7.7 11/3/2013 4:00 2.7 11/9/2013 21:00 52.2 11/12/2013 14:00 11/15/2013 7:00 74.1

11/1/2013 12:00 7.5 11/3/2013 5:00 2.3 11/9/2013 22:00 76 11/12/2013 15:00 19 11/15/2013 8:00 56.7

11/1/2013 13:00 13.6 11/3/2013 6:00 2.4 11/9/2013 23:00 101 11/12/2013 16:00 16.3 11/15/2013 9:00 10.4

11/1/2013 14:00 7.7 11/3/2013 7:00 4 11/11/2013 0:00 19.1 11/12/2013 17:00 25.5 11/15/2013 10:00 6.6

11/1/2013 15:00 5.1 11/3/2013 8:00 9.7 11/11/2013 1:00 21.8 11/12/2013 18:00 15.4 11/15/2013 11:00 4.8

11/1/2013 16:00 7.9 11/3/2013 9:00 33.7 11/11/2013 2:00 27.6 11/12/2013 19:00 16.2 11/15/2013 12:00 3.1

11/1/2013 17:00 8.4 11/3/2013 10:00 101.9 11/11/2013 3:00 32.4 11/12/2013 20:00 23.9 11/15/2013 13:00 2.5

11/1/2013 18:00 126.3 11/3/2013 11:00 50.4 11/11/2013 4:00 47.1 11/12/2013 21:00 22.2 11/15/2013 14:00 2.2

11/1/2013 19:00 108.3 11/3/2013 12:00 30.2 11/11/2013 5:00 47.6 11/12/2013 22:00 21.7 11/15/2013 15:00 2.1

11/1/2013 20:00 83.6 11/3/2013 13:00 21 11/11/2013 6:00 45.7 11/12/2013 23:00 22.8 11/15/2013 16:00 1.9

11/1/2013 21:00 76.2 11/3/2013 14:00 17 11/11/2013 7:00 47.8 11/13/2013 0:00 30.6 11/15/2013 17:00 2

11/1/2013 22:00 44 11/3/2013 15:00 18.6 11/11/2013 8:00 45.8 11/13/2013 1:00 38.3 11/15/2013 18:00 3.9

11/1/2013 23:00 42.3 11/3/2013 16:00 16.7 11/11/2013 9:00 33.6 11/13/2013 2:00 49 11/15/2013 19:00 19.6

11/2/2013 0:00 40.9 11/3/2013 17:00 36.6 11/11/2013 10:00 24.3 11/13/2013 3:00 65.3 11/15/2013 20:00 32

11/2/2013 1:00 53.5 11/3/2013 18:00 52.9 11/11/2013 11:00 15.3 11/13/2013 4:00 115.6 11/15/2013 21:00 18.5

11/2/2013 2:00 90.3 11/3/2013 19:00 43.6 11/11/2013 12:00 3.8 11/13/2013 5:00 247.9 11/15/2013 22:00 26.5

11/2/2013 3:00 134.4 11/3/2013 20:00 52.5 11/11/2013 13:00 6.2 11/13/2013 6:00 304.3 11/15/2013 23:00 66.6

11/2/2013 4:00 171.4 11/3/2013 21:00 78.3 11/11/2013 14:00 4.3 11/13/2013 7:00 499.1 11/16/2013 0:00 87.1

11/2/2013 5:00 161.1 11/3/2013 22:00 72.4 11/11/2013 15:00 11/13/2013 8:00 756.8 11/16/2013 1:00 151.2

11/2/2013 6:00 28.7 11/3/2013 23:00 89.3 11/11/2013 16:00 4.9 11/13/2013 9:00 332.7 11/16/2013 2:00 93.7

11/2/2013 7:00 13.2 11/9/2013 0:00 29.1 11/11/2013 17:00 8.8 11/13/2013 10:00 47.3 11/16/2013 3:00 103.6

11/2/2013 8:00 61.6 11/9/2013 1:00 44.2 11/11/2013 18:00 75.5 11/13/2013 11:00 20.9 11/16/2013 4:00 93.7

11/2/2013 9:00 10.5 11/9/2013 2:00 37.1 11/11/2013 19:00 65.5 11/13/2013 12:00 11.1 11/16/2013 5:00 92.7

11/2/2013 10:00 7.8 11/9/2013 3:00 40.4 11/11/2013 20:00 89.7 11/13/2013 13:00 5.6 11/16/2013 6:00 90.3

11/2/2013 11:00 14.9 11/9/2013 4:00 60.4 11/11/2013 21:00 81.5 11/13/2013 14:00 4.7 11/16/2013 7:00 78.7

11/2/2013 12:00 20.6 11/9/2013 5:00 48.6 11/11/2013 22:00 58.7 11/13/2013 15:00 6 11/16/2013 8:00 68.4

11/2/2013 13:00 18.5 11/9/2013 6:00 21.2 11/11/2013 23:00 62.7 11/13/2013 16:00 4.8 11/16/2013 9:00 31.4

11/2/2013 14:00 8.8 11/9/2013 7:00 16.6 11/12/2013 0:00 69.1 11/13/2013 17:00 3.7 11/16/2013 10:00 11.6

11/2/2013 15:00 7.8 11/9/2013 8:00 33.9 11/12/2013 1:00 114 11/13/2013 18:00 3.9 11/16/2013 11:00 7.2

11/2/2013 16:00 6.8 11/9/2013 9:00 52.8 11/12/2013 2:00 111.3 11/13/2013 19:00 4.3 11/16/2013 12:00

11/2/2013 17:00 403.9 11/9/2013 10:00 33.5 11/12/2013 3:00 84.8 11/13/2013 20:00 4 11/16/2013 13:00 4.2

11/2/2013 18:00 16.5 11/9/2013 11:00 9.8 11/12/2013 4:00 72.7 11/13/2013 21:00 5.8 11/16/2013 14:00 2.9

11/2/2013 19:00 79.3 11/9/2013 12:00 5.7 11/12/2013 5:00 70 11/13/2013 22:00 11.8 11/16/2013 15:00 2.5

11/2/2013 20:00 171 11/9/2013 13:00 3.1 11/12/2013 6:00 40.4 11/13/2013 23:00 7.1 11/16/2013 16:00 2.4

11/2/2013 21:00 63.3 11/9/2013 14:00 2.6 11/12/2013 7:00 29.7 11/15/2013 0:00 1.5 11/16/2013 17:00 2.9

11/2/2013 22:00 70.2 11/9/2013 15:00 2.3 11/12/2013 8:00 33 11/15/2013 1:00 1.5 11/16/2013 18:00 5.5

11/2/2013 23:00 93.8 11/9/2013 16:00 2.1 11/12/2013 9:00 134.1 11/15/2013 2:00 1.4 11/16/2013 19:00 4.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 77
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/16/2013 20:00 41.7 11/18/2013 13:00 3.1 11/24/2013 6:00 122.1 11/25/2013 23:00 44.7 11/27/2013 16:00 2.9

11/16/2013 21:00 139.8 11/18/2013 14:00 2.9 11/24/2013 7:00 112.7 11/26/2013 0:00 78 11/27/2013 17:00 2.4

11/16/2013 22:00 205.6 11/18/2013 15:00 11/24/2013 8:00 206.4 11/26/2013 1:00 98.1 11/27/2013 18:00 2.5

11/16/2013 23:00 133 11/18/2013 16:00 3.1 11/24/2013 9:00 242.7 11/26/2013 2:00 127.7 11/27/2013 19:00 3.1

11/17/2013 0:00 97.3 11/18/2013 17:00 2.7 11/24/2013 10:00 238.7 11/26/2013 3:00 53.4 11/27/2013 20:00 5.6

11/17/2013 1:00 63.7 11/18/2013 18:00 2.3 11/24/2013 11:00 127.9 11/26/2013 4:00 86.6 11/27/2013 21:00 12.7

11/17/2013 2:00 45.9 11/18/2013 19:00 2.2 11/24/2013 12:00 53.8 11/26/2013 5:00 98 11/27/2013 22:00 35.6

11/17/2013 3:00 46.1 11/18/2013 20:00 2 11/24/2013 13:00 26.9 11/26/2013 6:00 102.5 11/27/2013 23:00 107.9

11/17/2013 4:00 71.5 11/18/2013 21:00 1.9 11/24/2013 14:00 27 11/26/2013 7:00 98 11/28/2013 0:00 247.7

11/17/2013 5:00 222 11/18/2013 22:00 2.1 11/24/2013 15:00 16.5 11/26/2013 8:00 38.3 11/28/2013 1:00 72

11/17/2013 6:00 266.2 11/18/2013 23:00 3.6 11/24/2013 16:00 19.7 11/26/2013 9:00 22 11/28/2013 2:00 75

11/17/2013 7:00 143 11/22/2013 0:00 14 11/24/2013 17:00 28 11/26/2013 10:00 11.6 11/28/2013 3:00 71.2

11/17/2013 8:00 57.9 11/22/2013 1:00 11.5 11/24/2013 18:00 99.5 11/26/2013 11:00 9.6 11/28/2013 4:00 68.9

11/17/2013 9:00 23.9 11/22/2013 2:00 8.2 11/24/2013 19:00 199 11/26/2013 12:00 4.6 11/28/2013 5:00 94.5

11/17/2013 10:00 11 11/22/2013 3:00 8.5 11/24/2013 20:00 33.4 11/26/2013 13:00 7.6 11/28/2013 6:00 95.7

11/17/2013 11:00 10.6 11/22/2013 4:00 12.1 11/24/2013 21:00 18 11/26/2013 14:00 11/28/2013 7:00 46.2

11/17/2013 12:00 3.6 11/22/2013 5:00 12 11/24/2013 22:00 18.1 11/26/2013 15:00 4.4 11/28/2013 8:00 65.8

11/17/2013 13:00 3.1 11/22/2013 6:00 27.8 11/24/2013 23:00 21.6 11/26/2013 16:00 2.9 11/28/2013 9:00 19.1

11/17/2013 14:00 2.5 11/22/2013 7:00 25.9 11/25/2013 0:00 24.7 11/26/2013 17:00 2.4 11/28/2013 10:00 12

11/17/2013 15:00 2.3 11/22/2013 8:00 26.1 11/25/2013 1:00 21.1 11/26/2013 18:00 2.5 11/28/2013 11:00 4.1

11/17/2013 16:00 2.3 11/22/2013 9:00 90.9 11/25/2013 2:00 22.9 11/26/2013 19:00 3 11/28/2013 12:00 2.8

11/17/2013 17:00 11/22/2013 10:00 73.6 11/25/2013 3:00 25.2 11/26/2013 20:00 4 11/28/2013 13:00 2.4

11/17/2013 18:00 6.6 11/22/2013 11:00 47.1 11/25/2013 4:00 17.4 11/26/2013 21:00 22.2 11/28/2013 14:00 2.4

11/17/2013 19:00 3.3 11/22/2013 12:00 18 11/25/2013 5:00 92.5 11/26/2013 22:00 65.5 11/28/2013 15:00 3

11/17/2013 20:00 2.7 11/22/2013 13:00 12 11/25/2013 6:00 96.9 11/26/2013 23:00 87 11/28/2013 16:00 2.6

11/17/2013 21:00 3.7 11/22/2013 14:00 20.3 11/25/2013 7:00 14.1 11/27/2013 0:00 117.5 11/28/2013 17:00 2.5

11/17/2013 22:00 11.7 11/22/2013 15:00 11 11/25/2013 8:00 10.6 11/27/2013 1:00 91.7 11/28/2013 18:00 2.5

11/17/2013 23:00 22.4 11/22/2013 16:00 7.4 11/25/2013 9:00 8.8 11/27/2013 2:00 64.6 11/28/2013 19:00 2.4

11/18/2013 0:00 68.7 11/22/2013 17:00 7 11/25/2013 10:00 23.7 11/27/2013 3:00 55.2 11/28/2013 20:00 8.2

11/18/2013 1:00 776.1 11/22/2013 18:00 27 11/25/2013 11:00 8.6 11/27/2013 4:00 133.5 11/28/2013 21:00 18.5

11/18/2013 2:00 356.5 11/22/2013 19:00 30.4 11/25/2013 12:00 4.1 11/27/2013 5:00 149.6 11/28/2013 22:00 16.6

11/18/2013 3:00 78.2 11/22/2013 20:00 19 11/25/2013 13:00 3.2 11/27/2013 6:00 134.6 11/28/2013 23:00 44.4

11/18/2013 4:00 39.6 11/22/2013 21:00 19.3 11/25/2013 14:00 2.4 11/27/2013 7:00 162.8 11/29/2013 0:00 77.7

11/18/2013 5:00 20.3 11/22/2013 22:00 19.8 11/25/2013 15:00 11/27/2013 8:00 58.3 11/29/2013 1:00 237

11/18/2013 6:00 35 11/22/2013 23:00 14.1 11/25/2013 16:00 2.7 11/27/2013 9:00 70.4 11/29/2013 2:00 98.8

11/18/2013 7:00 31.1 11/24/2013 0:00 50 11/25/2013 17:00 2.7 11/27/2013 10:00 10.1 11/29/2013 3:00 23.1

11/18/2013 8:00 24.6 11/24/2013 1:00 50.7 11/25/2013 18:00 3.5 11/27/2013 11:00 4.4 11/29/2013 4:00 27.5

11/18/2013 9:00 24.7 11/24/2013 2:00 58.3 11/25/2013 19:00 6.3 11/27/2013 12:00 2.8 11/29/2013 5:00 35.7

11/18/2013 10:00 6.3 11/24/2013 3:00 55.6 11/25/2013 20:00 10.5 11/27/2013 13:00 2.7 11/29/2013 6:00 31.5

11/18/2013 11:00 16.3 11/24/2013 4:00 64.6 11/25/2013 21:00 26.7 11/27/2013 14:00 3 11/29/2013 7:00 131.8

11/18/2013 12:00 4.5 11/24/2013 5:00 79.4 11/25/2013 22:00 56.8 11/27/2013 15:00 3 11/29/2013 8:00 34.1

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 78
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/29/2013 9:00 8.2 12/3/2013 2:00 60.9 12/4/2013 19:00 15.8 12/6/2013 12:00 4.2 12/11/2013 5:00 185.8

11/29/2013 10:00 5 12/3/2013 3:00 137.8 12/4/2013 20:00 190.6 12/6/2013 13:00 2.9 12/11/2013 6:00 166.2

11/29/2013 11:00 3.8 12/3/2013 4:00 130.2 12/4/2013 21:00 153.9 12/6/2013 14:00 2.6 12/11/2013 7:00 95.4

11/29/2013 12:00 3.1 12/3/2013 5:00 104.5 12/4/2013 22:00 114.4 12/6/2013 15:00 2.4 12/11/2013 8:00 58

11/29/2013 13:00 2.5 12/3/2013 6:00 101.3 12/4/2013 23:00 60.3 12/6/2013 16:00 2.2 12/11/2013 9:00 69.5

11/29/2013 14:00 2.3 12/3/2013 7:00 75.4 12/5/2013 0:00 56.9 12/6/2013 17:00 2.1 12/11/2013 10:00 24.8

11/29/2013 15:00 2.1 12/3/2013 8:00 27.6 12/5/2013 1:00 48.1 12/6/2013 18:00 1.9 12/11/2013 11:00 5.8

11/29/2013 16:00 2 12/3/2013 9:00 21.3 12/5/2013 2:00 28.9 12/6/2013 19:00 2.5 12/11/2013 12:00 4

11/29/2013 17:00 1.9 12/3/2013 10:00 20.7 12/5/2013 3:00 24.2 12/6/2013 20:00 6.9 12/11/2013 13:00 3.1

11/29/2013 18:00 1.7 12/3/2013 11:00 19.1 12/5/2013 4:00 28.8 12/6/2013 21:00 7.2 12/11/2013 14:00 2.8

11/29/2013 19:00 1.7 12/3/2013 12:00 5.1 12/5/2013 5:00 29.2 12/6/2013 22:00 7.7 12/11/2013 15:00 2.4

11/29/2013 20:00 1.7 12/3/2013 13:00 3.6 12/5/2013 6:00 41.9 12/6/2013 23:00 7.7 12/11/2013 16:00 2.3

11/29/2013 21:00 1.6 12/3/2013 14:00 12/5/2013 7:00 44.3 12/10/2013 0:00 8 12/11/2013 17:00 2.5

11/29/2013 22:00 1.6 12/3/2013 15:00 4.6 12/5/2013 8:00 14.2 12/10/2013 1:00 15.8 12/11/2013 18:00 3.2

11/29/2013 23:00 1.5 12/3/2013 16:00 3 12/5/2013 9:00 6.9 12/10/2013 2:00 33.7 12/11/2013 19:00 6.2

12/2/2013 0:00 1.5 12/3/2013 17:00 2.6 12/5/2013 10:00 4.4 12/10/2013 3:00 32.2 12/11/2013 20:00 5.7

12/2/2013 1:00 1.4 12/3/2013 18:00 2.5 12/5/2013 11:00 3.2 12/10/2013 4:00 31.2 12/11/2013 21:00 59.5

12/2/2013 2:00 1.4 12/3/2013 19:00 3.7 12/5/2013 12:00 2.6 12/10/2013 5:00 30.5 12/11/2013 22:00 156.3

12/2/2013 3:00 1.9 12/3/2013 20:00 14.2 12/5/2013 13:00 2.4 12/10/2013 6:00 76.5 12/11/2013 23:00 416.9

12/2/2013 4:00 3.9 12/3/2013 21:00 29.3 12/5/2013 14:00 2.3 12/10/2013 7:00 137.4 12/12/2013 0:00 274.9

12/2/2013 5:00 6.9 12/3/2013 22:00 16.6 12/5/2013 15:00 4.7 12/10/2013 8:00 141.5 12/12/2013 1:00 83.5

12/2/2013 6:00 7.4 12/3/2013 23:00 13.6 12/5/2013 16:00 2.6 12/10/2013 9:00 149.2 12/12/2013 2:00 235.8

12/2/2013 7:00 13.6 12/4/2013 0:00 16.9 12/5/2013 17:00 2.3 12/10/2013 10:00 119.9 12/12/2013 3:00 119.3

12/2/2013 8:00 27.9 12/4/2013 1:00 19.3 12/5/2013 18:00 2.2 12/10/2013 11:00 12.3 12/12/2013 4:00 59.3

12/2/2013 9:00 34.2 12/4/2013 2:00 49.4 12/5/2013 19:00 3 12/10/2013 12:00 9.9 12/12/2013 5:00 41.3

12/2/2013 10:00 8.1 12/4/2013 3:00 57.1 12/5/2013 20:00 5.4 12/10/2013 13:00 6.7 12/12/2013 6:00 51.3

12/2/2013 11:00 4.4 12/4/2013 4:00 50.2 12/5/2013 21:00 15 12/10/2013 14:00 12/12/2013 7:00 69.5

12/2/2013 12:00 3.3 12/4/2013 5:00 27.7 12/5/2013 22:00 114.1 12/10/2013 15:00 7.3 12/12/2013 8:00 34.6

12/2/2013 13:00 2.6 12/4/2013 6:00 45.7 12/5/2013 23:00 121.1 12/10/2013 16:00 7.3 12/12/2013 9:00 23

12/2/2013 14:00 2.2 12/4/2013 7:00 120.3 12/6/2013 0:00 187.5 12/10/2013 17:00 12.4 12/12/2013 10:00 12.5

12/2/2013 15:00 12/4/2013 8:00 59.1 12/6/2013 1:00 201 12/10/2013 18:00 20.5 12/12/2013 11:00 4.7

12/2/2013 16:00 2.1 12/4/2013 9:00 11.6 12/6/2013 2:00 108.1 12/10/2013 19:00 51 12/12/2013 12:00 3.5

12/2/2013 17:00 1.9 12/4/2013 10:00 11.7 12/6/2013 3:00 71.9 12/10/2013 20:00 34.8 12/12/2013 13:00 2.9

12/2/2013 18:00 10 12/4/2013 11:00 6.4 12/6/2013 4:00 45.8 12/10/2013 21:00 14.1 12/12/2013 14:00 2.6

12/2/2013 19:00 140 12/4/2013 12:00 3.7 12/6/2013 5:00 25.4 12/10/2013 22:00 21.9 12/12/2013 15:00 4.4

12/2/2013 20:00 82.2 12/4/2013 13:00 2.6 12/6/2013 6:00 27.3 12/10/2013 23:00 57 12/12/2013 16:00 2.7

12/2/2013 21:00 29.5 12/4/2013 14:00 2.2 12/6/2013 7:00 45.8 12/11/2013 0:00 70.6 12/12/2013 17:00 2.3

12/2/2013 22:00 13.7 12/4/2013 15:00 2.2 12/6/2013 8:00 45.7 12/11/2013 1:00 354.9 12/12/2013 18:00 2.2

12/2/2013 23:00 14.7 12/4/2013 16:00 2.2 12/6/2013 9:00 24.4 12/11/2013 2:00 103.6 12/12/2013 19:00 2.1

12/3/2013 0:00 13.6 12/4/2013 17:00 2.2 12/6/2013 10:00 12.2 12/11/2013 3:00 70.1 12/12/2013 20:00 16.9

12/3/2013 1:00 17.6 12/4/2013 18:00 2.1 12/6/2013 11:00 5.7 12/11/2013 4:00 105.9 12/12/2013 21:00 35.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 79
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/12/2013 22:00 33.2 12/14/2013 15:00 2.6 12/18/2013 8:00 28.3 12/20/2013 1:00 42.5 12/23/2013 18:00 7.5

12/12/2013 23:00 149.3 12/14/2013 16:00 2.4 12/18/2013 9:00 39.1 12/20/2013 2:00 73.8 12/23/2013 19:00 19.2

12/13/2013 0:00 769 12/14/2013 17:00 2.5 12/18/2013 10:00 33.5 12/20/2013 3:00 105.5 12/23/2013 20:00 124.3

12/13/2013 1:00 304.3 12/14/2013 18:00 2.5 12/18/2013 11:00 27.7 12/20/2013 4:00 47.7 12/23/2013 21:00 86.1

12/13/2013 2:00 246.5 12/14/2013 19:00 9 12/18/2013 12:00 6.5 12/20/2013 5:00 108.7 12/23/2013 22:00 54

12/13/2013 3:00 191.7 12/14/2013 20:00 13.2 12/18/2013 13:00 3.2 12/20/2013 6:00 131.8 12/23/2013 23:00 29

12/13/2013 4:00 221.8 12/14/2013 21:00 9.8 12/18/2013 14:00 2.6 12/20/2013 7:00 85.5 12/24/2013 0:00 21

12/13/2013 5:00 149.2 12/14/2013 22:00 8.2 12/18/2013 15:00 2.4 12/20/2013 8:00 37.2 12/24/2013 1:00 28.8

12/13/2013 6:00 106.9 12/14/2013 23:00 58.5 12/18/2013 16:00 2.2 12/20/2013 9:00 27.8 12/24/2013 2:00 19.7

12/13/2013 7:00 72.5 12/15/2013 0:00 105.2 12/18/2013 17:00 2.3 12/20/2013 10:00 17.4 12/24/2013 3:00 24.2

12/13/2013 8:00 80.2 12/15/2013 1:00 68.2 12/18/2013 18:00 9.1 12/20/2013 11:00 7.1 12/24/2013 4:00 41

12/13/2013 9:00 17.2 12/15/2013 2:00 36.6 12/18/2013 19:00 87.5 12/20/2013 12:00 3.7 12/24/2013 5:00 89

12/13/2013 10:00 6.4 12/15/2013 3:00 89.5 12/18/2013 20:00 54.4 12/20/2013 13:00 3.1 12/24/2013 6:00 89.2

12/13/2013 11:00 12/15/2013 4:00 103.9 12/18/2013 21:00 25 12/20/2013 14:00 2.8 12/24/2013 7:00 88

12/13/2013 12:00 3.5 12/15/2013 5:00 65.9 12/18/2013 22:00 26.8 12/20/2013 15:00 2.6 12/24/2013 8:00 95.9

12/13/2013 13:00 3.1 12/15/2013 6:00 44.9 12/18/2013 23:00 11.4 12/20/2013 16:00 2.5 12/24/2013 9:00 128.7

12/13/2013 14:00 2.8 12/15/2013 7:00 22.4 12/19/2013 0:00 45 12/20/2013 17:00 2.4 12/24/2013 10:00 72.8

12/13/2013 15:00 2.5 12/15/2013 8:00 21.7 12/19/2013 1:00 45.4 12/20/2013 18:00 2.2 12/24/2013 11:00 7.2

12/13/2013 16:00 2.3 12/15/2013 9:00 8.7 12/19/2013 2:00 108.6 12/20/2013 19:00 3.5 12/24/2013 12:00 9.1

12/13/2013 17:00 2.3 12/15/2013 10:00 4 12/19/2013 3:00 357.6 12/20/2013 20:00 9.6 12/24/2013 13:00 15.9

12/13/2013 18:00 2.3 12/15/2013 11:00 3.1 12/19/2013 4:00 192.5 12/20/2013 21:00 17.5 12/24/2013 14:00

12/13/2013 19:00 8.3 12/15/2013 12:00 2.6 12/19/2013 5:00 99.8 12/20/2013 22:00 22.4 12/24/2013 15:00 7.9

12/13/2013 20:00 13 12/15/2013 13:00 2.4 12/19/2013 6:00 185.3 12/20/2013 23:00 32 12/24/2013 16:00 9.1

12/13/2013 21:00 22.6 12/15/2013 14:00 2.3 12/19/2013 7:00 134.2 12/23/2013 0:00 11.4 12/24/2013 17:00 14.9

12/13/2013 22:00 47 12/15/2013 15:00 2.4 12/19/2013 8:00 131.3 12/23/2013 1:00 34.6 12/24/2013 18:00 25.9

12/13/2013 23:00 159.6 12/15/2013 16:00 2.3 12/19/2013 9:00 28.3 12/23/2013 2:00 37.9 12/24/2013 19:00 32.8

12/14/2013 0:00 277.3 12/15/2013 17:00 2.1 12/19/2013 10:00 26.5 12/23/2013 3:00 100.9 12/24/2013 20:00 70.5

12/14/2013 1:00 423 12/15/2013 18:00 2 12/19/2013 11:00 13.9 12/23/2013 4:00 94.5 12/24/2013 21:00 49.2

12/14/2013 2:00 185.6 12/15/2013 19:00 1.9 12/19/2013 12:00 14.8 12/23/2013 5:00 55.3 12/24/2013 22:00 43.1

12/14/2013 3:00 144.5 12/15/2013 20:00 1.9 12/19/2013 13:00 4.1 12/23/2013 6:00 99.3 12/24/2013 23:00 78.3

12/14/2013 4:00 84.4 12/15/2013 21:00 1.9 12/19/2013 14:00 3 12/23/2013 7:00 63.6 12/25/2013 0:00 68.3

12/14/2013 5:00 35 12/15/2013 22:00 1.8 12/19/2013 15:00 3.3 12/23/2013 8:00 57.3 12/25/2013 1:00 47.1

12/14/2013 6:00 22.8 12/15/2013 23:00 1.7 12/19/2013 16:00 3.3 12/23/2013 9:00 24 12/25/2013 2:00 34.2

12/14/2013 7:00 86.5 12/18/2013 0:00 11.7 12/19/2013 17:00 3.3 12/23/2013 10:00 20.6 12/25/2013 3:00 25.4

12/14/2013 8:00 119.2 12/18/2013 1:00 7.3 12/19/2013 18:00 10.3 12/23/2013 11:00 10.1 12/25/2013 4:00 28.4

12/14/2013 9:00 24.5 12/18/2013 2:00 9 12/19/2013 19:00 78.7 12/23/2013 12:00 4.4 12/25/2013 5:00 77.5

12/14/2013 10:00 16.3 12/18/2013 3:00 11.7 12/19/2013 20:00 102.9 12/23/2013 13:00 3 12/25/2013 6:00 74.7

12/14/2013 11:00 7 12/18/2013 4:00 8.5 12/19/2013 21:00 63.8 12/23/2013 14:00 2.6 12/25/2013 7:00 153

12/14/2013 12:00 3.8 12/18/2013 5:00 10.1 12/19/2013 22:00 141.1 12/23/2013 15:00 12/25/2013 8:00 168.2

12/14/2013 13:00 3 12/18/2013 6:00 21.4 12/19/2013 23:00 95.6 12/23/2013 16:00 4.3 12/25/2013 9:00 95.4

12/14/2013 14:00 2.8 12/18/2013 7:00 19.7 12/20/2013 0:00 62.9 12/23/2013 17:00 5.8 12/25/2013 10:00 46.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 80
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/25/2013 11:00 10.5 1/3/2014 4:00 1.6 1/4/2014 21:00 92.1 1/6/2014 14:00 99.8 1/8/2014 7:00 49.5

12/25/2013 12:00 7.5 1/3/2014 5:00 1.7 1/4/2014 22:00 116.5 1/6/2014 15:00 1/8/2014 8:00 93.8

12/25/2013 13:00 4.7 1/3/2014 6:00 10.8 1/4/2014 23:00 89.8 1/6/2014 16:00 31 1/8/2014 9:00 164.6

12/25/2013 14:00 3.4 1/3/2014 7:00 48.6 1/5/2014 0:00 59.7 1/6/2014 17:00 26.4 1/8/2014 10:00 76.5

12/25/2013 15:00 3.4 1/3/2014 8:00 439.1 1/5/2014 1:00 83.8 1/6/2014 18:00 110.1 1/8/2014 11:00 136

12/25/2013 16:00 4.7 1/3/2014 9:00 450.8 1/5/2014 2:00 56.5 1/6/2014 19:00 76.9 1/8/2014 12:00 92.4

12/25/2013 17:00 5.6 1/3/2014 10:00 178.4 1/5/2014 3:00 44.1 1/6/2014 20:00 92.5 1/8/2014 13:00 45

12/25/2013 18:00 5.5 1/3/2014 11:00 152.7 1/5/2014 4:00 44.4 1/6/2014 21:00 94.6 1/8/2014 14:00 14.7

12/25/2013 19:00 9.2 1/3/2014 12:00 115.2 1/5/2014 5:00 44.2 1/6/2014 22:00 124.3 1/8/2014 15:00 5.3

12/25/2013 20:00 16 1/3/2014 13:00 200.4 1/5/2014 6:00 31.6 1/6/2014 23:00 94.9 1/8/2014 16:00 4.3

12/25/2013 21:00 34.1 1/3/2014 14:00 155.7 1/5/2014 7:00 35.2 1/7/2014 0:00 68.5 1/8/2014 17:00 4.1

12/25/2013 22:00 43.1 1/3/2014 15:00 112.5 1/5/2014 8:00 28.1 1/7/2014 1:00 46 1/8/2014 18:00 4

12/25/2013 23:00 45.7 1/3/2014 16:00 52.7 1/5/2014 9:00 30.8 1/7/2014 2:00 28.6 1/8/2014 19:00 4.1

12/26/2013 0:00 36.6 1/3/2014 17:00 21.4 1/5/2014 10:00 137.5 1/7/2014 3:00 46.7 1/8/2014 20:00 3.7

12/26/2013 1:00 26 1/3/2014 18:00 18.4 1/5/2014 11:00 136.7 1/7/2014 4:00 37.2 1/8/2014 21:00 4

12/26/2013 2:00 28.2 1/3/2014 19:00 17.8 1/5/2014 12:00 127.1 1/7/2014 5:00 23.9 1/8/2014 22:00 5.9

12/26/2013 3:00 27.9 1/3/2014 20:00 19.5 1/5/2014 13:00 80.9 1/7/2014 6:00 18.1 1/8/2014 23:00 12.1

12/26/2013 4:00 31.9 1/3/2014 21:00 13.8 1/5/2014 14:00 73.2 1/7/2014 7:00 17.9 1/9/2014 0:00 25.2

12/26/2013 5:00 28.8 1/3/2014 22:00 14.6 1/5/2014 15:00 40.1 1/7/2014 8:00 40.7 1/9/2014 1:00 39

12/26/2013 6:00 23.9 1/3/2014 23:00 12.4 1/5/2014 16:00 28.1 1/7/2014 9:00 70.8 1/9/2014 2:00 42.4

12/26/2013 7:00 22.4 1/4/2014 0:00 11.4 1/5/2014 17:00 23 1/7/2014 10:00 195.2 1/9/2014 3:00 34.2

12/26/2013 8:00 29.3 1/4/2014 1:00 8.8 1/5/2014 18:00 12.4 1/7/2014 11:00 111.7 1/9/2014 4:00 28.7

12/26/2013 9:00 59.8 1/4/2014 2:00 6.3 1/5/2014 19:00 11.3 1/7/2014 12:00 71.5 1/9/2014 5:00 51.5

12/26/2013 10:00 76.1 1/4/2014 3:00 6.1 1/5/2014 20:00 17 1/7/2014 13:00 59.5 1/9/2014 6:00 84.5

12/26/2013 11:00 80.1 1/4/2014 4:00 7.1 1/5/2014 21:00 57.4 1/7/2014 14:00 1/9/2014 7:00 174.7

12/26/2013 12:00 56.2 1/4/2014 5:00 10.5 1/5/2014 22:00 111.2 1/7/2014 15:00 40.1 1/9/2014 8:00 220.5

12/26/2013 13:00 32.7 1/4/2014 6:00 9.2 1/5/2014 23:00 140.5 1/7/2014 16:00 21.6 1/9/2014 9:00 77.5

12/26/2013 14:00 99.6 1/4/2014 7:00 5.9 1/6/2014 0:00 175.7 1/7/2014 17:00 13.2 1/9/2014 10:00 19.4

12/26/2013 15:00 13.5 1/4/2014 8:00 7.6 1/6/2014 1:00 90.2 1/7/2014 18:00 15.3 1/9/2014 11:00 10.3

12/26/2013 16:00 17.5 1/4/2014 9:00 76.1 1/6/2014 2:00 72.3 1/7/2014 19:00 13.7 1/9/2014 12:00 3.6

12/26/2013 17:00 10.2 1/4/2014 10:00 90.9 1/6/2014 3:00 48.4 1/7/2014 20:00 15 1/9/2014 13:00 3

12/26/2013 18:00 14.5 1/4/2014 11:00 79 1/6/2014 4:00 30.2 1/7/2014 21:00 19.9 1/9/2014 14:00 2.7

12/26/2013 19:00 17.1 1/4/2014 12:00 33.9 1/6/2014 5:00 38.8 1/7/2014 22:00 26 1/9/2014 15:00 3.1

12/26/2013 20:00 18.8 1/4/2014 13:00 42 1/6/2014 6:00 50.2 1/7/2014 23:00 45.1 1/9/2014 16:00 2.5

12/26/2013 21:00 25.4 1/4/2014 14:00 38.9 1/6/2014 7:00 49.2 1/8/2014 0:00 97.4 1/9/2014 17:00 2.5

12/26/2013 22:00 2.9 1/4/2014 15:00 55.3 1/6/2014 8:00 81.5 1/8/2014 1:00 78.4 1/9/2014 18:00 2.8

12/26/2013 23:00 1.9 1/4/2014 16:00 157.9 1/6/2014 9:00 102.6 1/8/2014 2:00 90.1 1/9/2014 19:00 2.8

1/3/2014 0:00 1.6 1/4/2014 17:00 82.8 1/6/2014 10:00 98.4 1/8/2014 3:00 86.7 1/9/2014 20:00 2.6

1/3/2014 1:00 1.6 1/4/2014 18:00 40.8 1/6/2014 11:00 107.9 1/8/2014 4:00 106.9 1/9/2014 21:00 2.8

1/3/2014 2:00 1.6 1/4/2014 19:00 45 1/6/2014 12:00 100.3 1/8/2014 5:00 91.3 1/9/2014 22:00 2.8

1/3/2014 3:00 1.6 1/4/2014 20:00 92.8 1/6/2014 13:00 103.2 1/8/2014 6:00 66.5 1/9/2014 23:00 4.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 81
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

1/10/2014 0:00 55.2 1/11/2014 17:00 2.1 1/16/2014 10:00 30.7 1/22/2014 3:00 1.7 1/25/2014 20:00 1.8

1/10/2014 1:00 97.9 1/11/2014 18:00 2 1/16/2014 11:00 31.2 1/22/2014 4:00 1.8 1/25/2014 21:00 25.3

1/10/2014 2:00 117.4 1/11/2014 19:00 2 1/16/2014 12:00 25 1/22/2014 5:00 1.7 1/25/2014 22:00 81.1

1/10/2014 3:00 126.3 1/11/2014 20:00 2 1/16/2014 13:00 15.3 1/22/2014 6:00 1.7 1/25/2014 23:00 39.5

1/10/2014 4:00 209.5 1/11/2014 21:00 1.9 1/16/2014 14:00 15.6 1/22/2014 7:00 1.7 1/26/2014 0:00 19.3

1/10/2014 5:00 191.7 1/11/2014 22:00 1.9 1/16/2014 15:00 13 1/22/2014 8:00 1.7 1/26/2014 1:00 26.7

1/10/2014 6:00 233.4 1/11/2014 23:00 1.8 1/16/2014 16:00 13.2 1/22/2014 9:00 1.9 1/26/2014 2:00 159

1/10/2014 7:00 107.1 1/13/2014 0:00 3.5 1/16/2014 17:00 1/22/2014 10:00 2.4 1/26/2014 3:00 210.1

1/10/2014 8:00 110.7 1/13/2014 1:00 21.2 1/16/2014 18:00 11.9 1/22/2014 11:00 2 1/26/2014 4:00 299.9

1/10/2014 9:00 80.7 1/13/2014 2:00 30.1 1/16/2014 19:00 9.7 1/22/2014 12:00 1.8 1/26/2014 5:00 293

1/10/2014 10:00 61.6 1/13/2014 3:00 61.6 1/16/2014 20:00 8.2 1/22/2014 13:00 2.3 1/26/2014 6:00 234.3

1/10/2014 11:00 35 1/13/2014 4:00 47.5 1/16/2014 21:00 7.3 1/22/2014 14:00 27 1/26/2014 7:00 202.3

1/10/2014 12:00 28.1 1/13/2014 5:00 78.9 1/16/2014 22:00 7.8 1/22/2014 15:00 91.1 1/26/2014 8:00 242

1/10/2014 13:00 11.4 1/13/2014 6:00 66.4 1/16/2014 23:00 8.4 1/22/2014 16:00 16.4 1/26/2014 9:00 212.7

1/10/2014 14:00 8 1/13/2014 7:00 57.6 1/18/2014 0:00 5.8 1/22/2014 17:00 13 1/26/2014 10:00 124.9

1/10/2014 15:00 5.3 1/13/2014 8:00 118.5 1/18/2014 1:00 13 1/22/2014 18:00 12.8 1/26/2014 11:00 94.6

1/10/2014 16:00 4 1/13/2014 9:00 59.5 1/18/2014 2:00 22.3 1/22/2014 19:00 11.5 1/26/2014 12:00 71.4

1/10/2014 17:00 3.6 1/13/2014 10:00 10.7 1/18/2014 3:00 22.6 1/22/2014 20:00 11.5 1/26/2014 13:00 46.3

1/10/2014 18:00 3.2 1/13/2014 11:00 5.8 1/18/2014 4:00 36.3 1/22/2014 21:00 7.3 1/26/2014 14:00 24.4

1/10/2014 19:00 3.5 1/13/2014 12:00 4.5 1/18/2014 5:00 64.5 1/22/2014 22:00 5 1/26/2014 15:00 20.4

1/10/2014 20:00 5.6 1/13/2014 13:00 3.5 1/18/2014 6:00 169.3 1/22/2014 23:00 3.7 1/26/2014 16:00 18.9

1/10/2014 21:00 17.9 1/13/2014 14:00 3 1/18/2014 7:00 169.6 1/25/2014 0:00 3.1 1/26/2014 17:00 17.8

1/10/2014 22:00 52.4 1/13/2014 15:00 1/18/2014 8:00 67.6 1/25/2014 1:00 2.9 1/26/2014 18:00 14.5

1/10/2014 23:00 98.2 1/13/2014 16:00 2.8 1/18/2014 9:00 67.5 1/25/2014 2:00 2.9 1/26/2014 19:00 12.6

1/11/2014 0:00 131.7 1/13/2014 17:00 2.4 1/18/2014 10:00 31.6 1/25/2014 3:00 2.7 1/26/2014 20:00 16.9

1/11/2014 1:00 169.6 1/13/2014 18:00 2.3 1/18/2014 11:00 17.6 1/25/2014 4:00 2.5 1/26/2014 21:00 22.3

1/11/2014 2:00 121.7 1/13/2014 19:00 2.2 1/18/2014 12:00 12.9 1/25/2014 5:00 2.5 1/26/2014 22:00 31.1

1/11/2014 3:00 82.6 1/13/2014 20:00 2.1 1/18/2014 13:00 7.1 1/25/2014 6:00 2.5 1/26/2014 23:00 28.9

1/11/2014 4:00 68.6 1/13/2014 21:00 2.1 1/18/2014 14:00 4.4 1/25/2014 7:00 2.2 1/29/2014 0:00 7.7

1/11/2014 5:00 81 1/13/2014 22:00 2.1 1/18/2014 15:00 3.3 1/25/2014 8:00 2.2 1/29/2014 1:00 7

1/11/2014 6:00 35.3 1/13/2014 23:00 2 1/18/2014 16:00 3 1/25/2014 9:00 2.2 1/29/2014 2:00 7.1

1/11/2014 7:00 43.2 1/16/2014 0:00 1.9 1/18/2014 17:00 2.8 1/25/2014 10:00 2.6 1/29/2014 3:00 3.2

1/11/2014 8:00 22.6 1/16/2014 1:00 2 1/18/2014 18:00 2.7 1/25/2014 11:00 2.5 1/29/2014 4:00 5.3

1/11/2014 9:00 9 1/16/2014 2:00 9.8 1/18/2014 19:00 2.6 1/25/2014 12:00 2.3 1/29/2014 5:00 7.2

1/11/2014 10:00 4.8 1/16/2014 3:00 91.2 1/18/2014 20:00 2.4 1/25/2014 13:00 2.2 1/29/2014 6:00 18.7

1/11/2014 11:00 3.9 1/16/2014 4:00 99.6 1/18/2014 21:00 2.3 1/25/2014 14:00 2.2 1/29/2014 7:00 138.1

1/11/2014 12:00 3.1 1/16/2014 5:00 64.2 1/18/2014 22:00 3.9 1/25/2014 15:00 2.1 1/29/2014 8:00 136.4

1/11/2014 13:00 2.7 1/16/2014 6:00 101.7 1/18/2014 23:00 6.5 1/25/2014 16:00 1.9 1/29/2014 9:00 214.6

1/11/2014 14:00 2.4 1/16/2014 7:00 120.6 1/22/2014 0:00 1.8 1/25/2014 17:00 1.9 1/29/2014 10:00 96.4

1/11/2014 15:00 2.3 1/16/2014 8:00 97.1 1/22/2014 1:00 1.7 1/25/2014 18:00 1.9 1/29/2014 11:00 22.5

1/11/2014 16:00 2.2 1/16/2014 9:00 45.7 1/22/2014 2:00 1.7 1/25/2014 19:00 1.8 1/29/2014 12:00 15.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 82
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

1/29/2014 13:00 8.2 2/8/2014 6:00 61.4 2/9/2014 23:00 5 2/12/2014 16:00 3 2/19/2014 9:00 53.9

1/29/2014 14:00 4 2/8/2014 7:00 50.2 2/11/2014 0:00 110.1 2/12/2014 17:00 2.8 2/19/2014 10:00 20.7

1/29/2014 15:00 3.2 2/8/2014 8:00 30.6 2/11/2014 1:00 97.3 2/12/2014 18:00 2.7 2/19/2014 11:00 8

1/29/2014 16:00 3.5 2/8/2014 9:00 79 2/11/2014 2:00 118.3 2/12/2014 19:00 2.7 2/19/2014 12:00 5.5

1/29/2014 17:00 7.7 2/8/2014 10:00 67.9 2/11/2014 3:00 398.5 2/12/2014 20:00 2.5 2/19/2014 13:00 4.1

1/29/2014 18:00 7.4 2/8/2014 11:00 34.6 2/11/2014 4:00 241.3 2/12/2014 21:00 2.7 2/19/2014 14:00 3.2

1/29/2014 19:00 12 2/8/2014 12:00 11.9 2/11/2014 5:00 114.7 2/12/2014 22:00 3.7 2/19/2014 15:00 2.8

1/29/2014 20:00 26.7 2/8/2014 13:00 5.3 2/11/2014 6:00 50.8 2/12/2014 23:00 9 2/19/2014 16:00 2.6

1/29/2014 21:00 24.2 2/8/2014 14:00 3.9 2/11/2014 7:00 114.1 2/14/2014 0:00 5 2/19/2014 17:00 2.4

1/29/2014 22:00 29.5 2/8/2014 15:00 3.1 2/11/2014 8:00 126.3 2/14/2014 1:00 42.9 2/19/2014 18:00 2.4

1/29/2014 23:00 41 2/8/2014 16:00 2.9 2/11/2014 9:00 38.7 2/14/2014 2:00 62.8 2/19/2014 19:00 2.3

1/30/2014 0:00 30.8 2/8/2014 17:00 2.7 2/11/2014 10:00 19.5 2/14/2014 3:00 66.2 2/19/2014 20:00 2.4

1/30/2014 1:00 29.9 2/8/2014 18:00 2.7 2/11/2014 11:00 15.4 2/14/2014 4:00 66 2/19/2014 21:00 2.4

1/30/2014 2:00 35.8 2/8/2014 19:00 2.6 2/11/2014 12:00 6.4 2/14/2014 5:00 49.6 2/19/2014 22:00 2.4

1/30/2014 3:00 106.4 2/8/2014 20:00 2.4 2/11/2014 13:00 4.1 2/14/2014 6:00 119.9 2/19/2014 23:00 11.9

1/30/2014 4:00 268.4 2/8/2014 21:00 2.3 2/11/2014 14:00 2/14/2014 7:00 192.9 2/20/2014 0:00 17.7

1/30/2014 5:00 123 2/8/2014 22:00 3.4 2/11/2014 15:00 4.6 2/14/2014 8:00 133.6 2/20/2014 1:00 14.5

1/30/2014 6:00 137 2/8/2014 23:00 8.8 2/11/2014 16:00 3.6 2/14/2014 9:00 164.3 2/20/2014 2:00 22.6

1/30/2014 7:00 124.1 2/9/2014 0:00 15.9 2/11/2014 17:00 3 2/14/2014 10:00 67.3 2/20/2014 3:00 26.4

1/30/2014 8:00 83.2 2/9/2014 1:00 43.9 2/11/2014 18:00 2.8 2/14/2014 11:00 31.4 2/20/2014 4:00 19.3

1/30/2014 9:00 45.6 2/9/2014 2:00 22.6 2/11/2014 19:00 2.8 2/14/2014 12:00 21.5 2/20/2014 5:00 41.8

1/30/2014 10:00 12.1 2/9/2014 3:00 28.1 2/11/2014 20:00 3 2/14/2014 13:00 7.1 2/20/2014 6:00 30.9

1/30/2014 11:00 8.6 2/9/2014 4:00 88.9 2/11/2014 21:00 2.9 2/14/2014 14:00 4.8 2/20/2014 7:00 24.4

1/30/2014 12:00 5 2/9/2014 5:00 66.8 2/11/2014 22:00 3.9 2/14/2014 15:00 3.7 2/20/2014 8:00 42.4

1/30/2014 13:00 3.5 2/9/2014 6:00 73.6 2/11/2014 23:00 6.2 2/14/2014 16:00 2.9 2/20/2014 9:00 99.3

1/30/2014 14:00 3.1 2/9/2014 7:00 53.9 2/12/2014 0:00 28.6 2/14/2014 17:00 2.7 2/20/2014 10:00 23.1

1/30/2014 15:00 3.9 2/9/2014 8:00 30.8 2/12/2014 1:00 27.4 2/14/2014 18:00 2.5 2/20/2014 11:00 11.8

1/30/2014 16:00 2.8 2/9/2014 9:00 22.5 2/12/2014 2:00 39.7 2/14/2014 19:00 2.3 2/20/2014 12:00 4.9

1/30/2014 17:00 2.8 2/9/2014 10:00 12.4 2/12/2014 3:00 70.3 2/14/2014 20:00 2.2 2/20/2014 13:00 3.6

1/30/2014 18:00 4.6 2/9/2014 11:00 5.4 2/12/2014 4:00 72.7 2/14/2014 21:00 2.9 2/20/2014 14:00 3.1

1/30/2014 19:00 6 2/9/2014 12:00 3.7 2/12/2014 5:00 95.3 2/14/2014 22:00 8.4 2/20/2014 15:00 5

1/30/2014 20:00 9.1 2/9/2014 13:00 2.9 2/12/2014 6:00 104.8 2/14/2014 23:00 14.2 2/20/2014 16:00 3

1/30/2014 21:00 13.4 2/9/2014 14:00 2.7 2/12/2014 7:00 110.5 2/19/2014 0:00 7.4 2/20/2014 17:00 2.6

1/30/2014 22:00 14.7 2/9/2014 15:00 2.5 2/12/2014 8:00 130.5 2/19/2014 1:00 19.4 2/20/2014 18:00 2.4

1/30/2014 23:00 12.4 2/9/2014 16:00 2.7 2/12/2014 9:00 29.9 2/19/2014 2:00 42.8 2/20/2014 19:00 2.3

2/8/2014 0:00 11.1 2/9/2014 17:00 2.6 2/12/2014 10:00 17.1 2/19/2014 3:00 41.9 2/20/2014 20:00 2.2

2/8/2014 1:00 21.9 2/9/2014 18:00 2.5 2/12/2014 11:00 6.1 2/19/2014 4:00 38.8 2/20/2014 21:00 2.2

2/8/2014 2:00 46.9 2/9/2014 19:00 2.4 2/12/2014 12:00 4.8 2/19/2014 5:00 48.1 2/20/2014 22:00 2.6

2/8/2014 3:00 61.2 2/9/2014 20:00 2.3 2/12/2014 13:00 2.9 2/19/2014 6:00 87.8 2/20/2014 23:00 3.5

2/8/2014 4:00 53.7 2/9/2014 21:00 2.2 2/12/2014 14:00 2.9 2/19/2014 7:00 89.9 2/24/2014 0:00 24.4

2/8/2014 5:00 48.3 2/9/2014 22:00 2.2 2/12/2014 15:00 3.3 2/19/2014 8:00 65.6 2/24/2014 1:00 41.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 83
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

2/24/2014 2:00 76.8 2/27/2014 19:00 2.8 3/12/2014 12:00 36.4 3/17/2014 5:00 30.8 3/18/2014 22:00 29.2

2/24/2014 3:00 49.4 2/27/2014 20:00 3 3/12/2014 13:00 18.7 3/17/2014 6:00 26.9 3/18/2014 23:00 23.5

2/24/2014 4:00 53.6 2/27/2014 21:00 3.1 3/12/2014 14:00 12.4 3/17/2014 7:00 44.1 3/19/2014 0:00 24.5

2/24/2014 5:00 54.2 2/27/2014 22:00 6.1 3/12/2014 15:00 10.6 3/17/2014 8:00 70.2 3/19/2014 1:00 19.8

2/24/2014 6:00 50.9 2/27/2014 23:00 14.5 3/12/2014 16:00 10.9 3/17/2014 9:00 58 3/19/2014 2:00 16

2/24/2014 7:00 36.9 3/11/2014 0:00 3 3/12/2014 17:00 9.9 3/17/2014 10:00 70.4 3/19/2014 3:00 9.7

2/24/2014 8:00 18.5 3/11/2014 1:00 5.4 3/12/2014 18:00 12.2 3/17/2014 11:00 59.6 3/19/2014 4:00 11.3

2/24/2014 9:00 16.4 3/11/2014 2:00 7.6 3/12/2014 19:00 15.2 3/17/2014 12:00 39.7 3/19/2014 5:00 13.7

2/24/2014 10:00 18 3/11/2014 3:00 14.5 3/12/2014 20:00 28.2 3/17/2014 13:00 46.6 3/19/2014 6:00 18.1

2/24/2014 11:00 21.4 3/11/2014 4:00 14.5 3/12/2014 21:00 22.4 3/17/2014 14:00 24.2 3/19/2014 7:00 31.6

2/24/2014 12:00 27.7 3/11/2014 5:00 10.7 3/12/2014 22:00 26.7 3/17/2014 15:00 3/19/2014 8:00 114.9

2/24/2014 13:00 18.5 3/11/2014 6:00 7.2 3/12/2014 23:00 27.2 3/17/2014 16:00 9.7 3/19/2014 9:00 89.4

2/24/2014 14:00 8.8 3/11/2014 7:00 7.8 3/15/2014 0:00 10.5 3/17/2014 17:00 3/19/2014 10:00 62.1

2/24/2014 15:00 3/11/2014 8:00 29.5 3/15/2014 1:00 10.4 3/17/2014 18:00 11.4 3/19/2014 11:00 40

2/24/2014 16:00 4.7 3/11/2014 9:00 28.1 3/15/2014 2:00 11.9 3/17/2014 19:00 9.9 3/19/2014 12:00 24.3

2/24/2014 17:00 4 3/11/2014 10:00 29.9 3/15/2014 3:00 16.9 3/17/2014 20:00 9.7 3/19/2014 13:00 16.6

2/24/2014 18:00 4.1 3/11/2014 11:00 32 3/15/2014 4:00 33.6 3/17/2014 21:00 8.7 3/19/2014 14:00 10.6

2/24/2014 19:00 7.7 3/11/2014 12:00 24.7 3/15/2014 5:00 43.6 3/17/2014 22:00 13.9 3/19/2014 15:00 12

2/24/2014 20:00 22.8 3/11/2014 13:00 21.3 3/15/2014 6:00 34.4 3/17/2014 23:00 21.2 3/19/2014 16:00 13.8

2/24/2014 21:00 17.2 3/11/2014 14:00 3/15/2014 7:00 23.1 3/18/2014 0:00 29.5 3/19/2014 17:00 16.7

2/24/2014 22:00 8.9 3/11/2014 15:00 16.3 3/15/2014 8:00 38.8 3/18/2014 1:00 49.5 3/19/2014 18:00 15

2/24/2014 23:00 6.3 3/11/2014 16:00 15.2 3/15/2014 9:00 36.1 3/18/2014 2:00 56.2 3/19/2014 19:00 13.9

2/27/2014 0:00 41.3 3/11/2014 17:00 12.5 3/15/2014 10:00 20.6 3/18/2014 3:00 67.3 3/19/2014 20:00 14.3

2/27/2014 1:00 56.1 3/11/2014 18:00 8.8 3/15/2014 11:00 8.6 3/18/2014 4:00 75.2 3/19/2014 21:00 14.9

2/27/2014 2:00 80.4 3/11/2014 19:00 5.1 3/15/2014 12:00 4.8 3/18/2014 5:00 59.3 3/19/2014 22:00 14

2/27/2014 3:00 128.2 3/11/2014 20:00 4.8 3/15/2014 13:00 3.6 3/18/2014 6:00 100.1 3/19/2014 23:00 8.8

2/27/2014 4:00 114.2 3/11/2014 21:00 8.5 3/15/2014 14:00 3.1 3/18/2014 7:00 104.6 3/21/2014 0:00 29.5

2/27/2014 5:00 107.8 3/11/2014 22:00 50.4 3/15/2014 15:00 4.3 3/18/2014 8:00 369.3 3/21/2014 1:00 32.3

2/27/2014 6:00 83.2 3/11/2014 23:00 94.8 3/15/2014 16:00 14.3 3/18/2014 9:00 645 3/21/2014 2:00 11

2/27/2014 7:00 62.8 3/12/2014 0:00 70 3/15/2014 17:00 17 3/18/2014 10:00 405.1 3/21/2014 3:00 5.8

2/27/2014 8:00 93.7 3/12/2014 1:00 72.2 3/15/2014 18:00 62.9 3/18/2014 11:00 324.7 3/21/2014 4:00 5.7

2/27/2014 9:00 32.7 3/12/2014 2:00 51 3/15/2014 19:00 99.5 3/18/2014 12:00 192.5 3/21/2014 5:00 37.3

2/27/2014 10:00 17 3/12/2014 3:00 61.5 3/15/2014 20:00 87.4 3/18/2014 13:00 95.6 3/21/2014 6:00 119.7

2/27/2014 11:00 8.1 3/12/2014 4:00 52.9 3/15/2014 21:00 60.1 3/18/2014 14:00 3/21/2014 7:00 92.1

2/27/2014 12:00 4.2 3/12/2014 5:00 46.4 3/15/2014 22:00 42.6 3/18/2014 15:00 52.9 3/21/2014 8:00 102.1

2/27/2014 13:00 3.5 3/12/2014 6:00 44.3 3/15/2014 23:00 28.6 3/18/2014 16:00 48.1 3/21/2014 9:00 55.9

2/27/2014 14:00 3.6 3/12/2014 7:00 43.9 3/17/2014 0:00 41.8 3/18/2014 17:00 45.8 3/21/2014 10:00 18

2/27/2014 15:00 4.3 3/12/2014 8:00 90.6 3/17/2014 1:00 35.9 3/18/2014 18:00 33.1 3/21/2014 11:00 6.8

2/27/2014 16:00 3.6 3/12/2014 9:00 87.8 3/17/2014 2:00 35.9 3/18/2014 19:00 34 3/21/2014 12:00 4.6

2/27/2014 17:00 3.3 3/12/2014 10:00 70.2 3/17/2014 3:00 77.3 3/18/2014 20:00 33.6 3/21/2014 13:00 3.7

2/27/2014 18:00 2.9 3/12/2014 11:00 47.7 3/17/2014 4:00 56.5 3/18/2014 21:00 28.8 3/21/2014 14:00 3.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 84
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

3/21/2014 15:00 3.2 3/23/2014 8:00 5.7 3/25/2014 1:00 33.6 3/26/2014 18:00 2.5 3/30/2014 11:00 5.6

3/21/2014 16:00 32.8 3/23/2014 9:00 40.8 3/25/2014 2:00 39.1 3/26/2014 19:00 2.5 3/30/2014 12:00 3.7

3/21/2014 17:00 16 3/23/2014 10:00 27.8 3/25/2014 3:00 58.5 3/26/2014 20:00 3.1 3/30/2014 13:00 2.9

3/21/2014 18:00 11 3/23/2014 11:00 35.1 3/25/2014 4:00 26.6 3/26/2014 21:00 5.3 3/30/2014 14:00 2.8

3/21/2014 19:00 19.9 3/23/2014 12:00 10.5 3/25/2014 5:00 15.5 3/26/2014 22:00 8 3/30/2014 15:00 2.7

3/21/2014 20:00 35.8 3/23/2014 13:00 10.1 3/25/2014 6:00 20.9 3/26/2014 23:00 8.8 3/30/2014 16:00 3.8

3/21/2014 21:00 47.9 3/23/2014 14:00 9.2 3/25/2014 7:00 25.9 3/29/2014 0:00 95.9 3/30/2014 17:00 6.6

3/21/2014 22:00 51.5 3/23/2014 15:00 5.2 3/25/2014 8:00 76.1 3/29/2014 1:00 13.4 3/30/2014 18:00 5.8

3/21/2014 23:00 46.5 3/23/2014 16:00 10.1 3/25/2014 9:00 44.5 3/29/2014 2:00 25.7 3/30/2014 19:00 5.4

3/22/2014 0:00 33.5 3/23/2014 17:00 61.3 3/25/2014 10:00 4.8 3/29/2014 3:00 58.4 3/30/2014 20:00 4.8

3/22/2014 1:00 23.6 3/23/2014 18:00 75.2 3/25/2014 11:00 8.3 3/29/2014 4:00 75.5 3/30/2014 21:00 5.5

3/22/2014 2:00 26.4 3/23/2014 19:00 418.8 3/25/2014 12:00 6.7 3/29/2014 5:00 46.6 3/30/2014 22:00 4.9

3/22/2014 3:00 61.9 3/23/2014 20:00 49.3 3/25/2014 13:00 5.8 3/29/2014 6:00 32.7 3/30/2014 23:00 12.3

3/22/2014 4:00 93.4 3/23/2014 21:00 15 3/25/2014 14:00 3/29/2014 7:00 26.4 4/2/2014 0:00 210.8

3/22/2014 5:00 43.4 3/23/2014 22:00 6.8 3/25/2014 15:00 6.5 3/29/2014 8:00 21.6 4/2/2014 1:00 106.4

3/22/2014 6:00 47.4 3/23/2014 23:00 5.8 3/25/2014 16:00 4.4 3/29/2014 9:00 9.6 4/2/2014 2:00 39.9

3/22/2014 7:00 60.9 3/24/2014 0:00 8.6 3/25/2014 17:00 3.4 3/29/2014 10:00 4.8 4/2/2014 3:00 19.1

3/22/2014 8:00 41.5 3/24/2014 1:00 34.4 3/25/2014 18:00 3.2 3/29/2014 11:00 3.5 4/2/2014 4:00 8.8

3/22/2014 9:00 57.4 3/24/2014 2:00 79.4 3/25/2014 19:00 6.9 3/29/2014 12:00 3.1 4/2/2014 5:00 22.6

3/22/2014 10:00 9.4 3/24/2014 3:00 67 3/25/2014 20:00 8 3/29/2014 13:00 2.9 4/2/2014 6:00 34.1

3/22/2014 11:00 6.4 3/24/2014 4:00 50 3/25/2014 21:00 8.7 3/29/2014 14:00 3 4/2/2014 7:00 45.4

3/22/2014 12:00 5.1 3/24/2014 5:00 50.1 3/25/2014 22:00 11.5 3/29/2014 15:00 3.6 4/2/2014 8:00 13.5

3/22/2014 13:00 3.5 3/24/2014 6:00 33.2 3/25/2014 23:00 7.1 3/29/2014 16:00 2.8 4/2/2014 9:00 18.3

3/22/2014 14:00 3.1 3/24/2014 7:00 66.6 3/26/2014 0:00 6 3/29/2014 17:00 2.6 4/2/2014 10:00 8.2

3/22/2014 15:00 2.9 3/24/2014 8:00 77.6 3/26/2014 1:00 9.1 3/29/2014 18:00 2.5 4/2/2014 11:00 5.8

3/22/2014 16:00 2.8 3/24/2014 9:00 334.3 3/26/2014 2:00 13.8 3/29/2014 19:00 2.4 4/2/2014 12:00 4.9

3/22/2014 17:00 5.3 3/24/2014 10:00 244.7 3/26/2014 3:00 35.7 3/29/2014 20:00 3.5 4/2/2014 13:00 4.9

3/22/2014 18:00 4.3 3/24/2014 11:00 18.6 3/26/2014 4:00 57.8 3/29/2014 21:00 15 4/2/2014 14:00

3/22/2014 19:00 6.7 3/24/2014 12:00 7.7 3/26/2014 5:00 62.7 3/29/2014 22:00 15.9 4/2/2014 15:00 4.7

3/22/2014 20:00 41.2 3/24/2014 13:00 5.7 3/26/2014 6:00 75.5 3/29/2014 23:00 18.5 4/2/2014 16:00 3.6

3/22/2014 21:00 84.8 3/24/2014 14:00 5.3 3/26/2014 7:00 50 3/30/2014 0:00 21.8 4/2/2014 17:00 37.5

3/22/2014 22:00 67.7 3/24/2014 15:00 3/26/2014 8:00 36.3 3/30/2014 1:00 16.1 4/2/2014 18:00 44.5

3/22/2014 23:00 55.9 3/24/2014 16:00 29.4 3/26/2014 9:00 29.6 3/30/2014 2:00 8 4/2/2014 19:00 37.3

3/23/2014 0:00 39.5 3/24/2014 17:00 50.8 3/26/2014 10:00 15.4 3/30/2014 3:00 13.4 4/2/2014 20:00 37.5

3/23/2014 1:00 27.7 3/24/2014 18:00 44.5 3/26/2014 11:00 6.5 3/30/2014 4:00 16.5 4/2/2014 21:00 43.6

3/23/2014 2:00 32.5 3/24/2014 19:00 79.9 3/26/2014 12:00 4.2 3/30/2014 5:00 36.9 4/2/2014 22:00 21.8

3/23/2014 3:00 26.5 3/24/2014 20:00 64.9 3/26/2014 13:00 3.4 3/30/2014 6:00 40.1 4/2/2014 23:00 16

3/23/2014 4:00 35.1 3/24/2014 21:00 45.4 3/26/2014 14:00 3 3/30/2014 7:00 35.1 4/3/2014 0:00 41.5

3/23/2014 5:00 27.2 3/24/2014 22:00 30 3/26/2014 15:00 2.8 3/30/2014 8:00 80.1 4/3/2014 1:00 23.9

3/23/2014 6:00 13.2 3/24/2014 23:00 23 3/26/2014 16:00 2.6 3/30/2014 9:00 46.4 4/3/2014 2:00 22.1

3/23/2014 7:00 8.1 3/25/2014 0:00 38.4 3/26/2014 17:00 2.5 3/30/2014 10:00 11.4 4/3/2014 3:00 13.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 85
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/3/2014 4:00 7 4/4/2014 21:00 12 4/6/2014 14:00 4.1 4/9/2014 7:00 65.6 4/11/2014 0:00 54.8

4/3/2014 5:00 26.4 4/4/2014 22:00 10.3 4/6/2014 15:00 3.4 4/9/2014 8:00 120.4 4/11/2014 1:00 84.2

4/3/2014 6:00 94.6 4/4/2014 23:00 5 4/6/2014 16:00 2.9 4/9/2014 9:00 87.4 4/11/2014 2:00 23.4

4/3/2014 7:00 78.1 4/5/2014 0:00 75 4/6/2014 17:00 18.8 4/9/2014 10:00 25.1 4/11/2014 3:00 38.3

4/3/2014 8:00 172.1 4/5/2014 1:00 96.7 4/6/2014 18:00 54.6 4/9/2014 11:00 7.1 4/11/2014 4:00 81.8

4/3/2014 9:00 50.1 4/5/2014 2:00 42.2 4/6/2014 19:00 82.1 4/9/2014 12:00 5.9 4/11/2014 5:00 144.7

4/3/2014 10:00 25.2 4/5/2014 3:00 31.9 4/6/2014 20:00 58.3 4/9/2014 13:00 3.8 4/11/2014 6:00 443.6

4/3/2014 11:00 13.2 4/5/2014 4:00 25.3 4/6/2014 21:00 24.3 4/9/2014 14:00 3.1 4/11/2014 7:00 351.4

4/3/2014 12:00 7.1 4/5/2014 5:00 25.2 4/6/2014 22:00 19.4 4/9/2014 15:00 3.3 4/11/2014 8:00 36.5

4/3/2014 13:00 5.4 4/5/2014 6:00 27.8 4/6/2014 23:00 43.8 4/9/2014 16:00 3.9 4/11/2014 9:00 26.5

4/3/2014 14:00 4.7 4/5/2014 7:00 55.8 4/8/2014 0:00 33.9 4/9/2014 17:00 4.6 4/11/2014 10:00 9.7

4/3/2014 15:00 4.4 4/5/2014 8:00 63.5 4/8/2014 1:00 51.8 4/9/2014 18:00 5.7 4/11/2014 11:00 6.6

4/3/2014 16:00 3.8 4/5/2014 9:00 50 4/8/2014 2:00 63.5 4/9/2014 19:00 9.8 4/11/2014 12:00 4.8

4/3/2014 17:00 3.4 4/5/2014 10:00 34 4/8/2014 3:00 46.1 4/9/2014 20:00 10.5 4/11/2014 13:00 3.6

4/3/2014 18:00 69.8 4/5/2014 11:00 5.2 4/8/2014 4:00 37 4/9/2014 21:00 8.8 4/11/2014 14:00 3.1

4/3/2014 19:00 239.6 4/5/2014 12:00 3.9 4/8/2014 5:00 32.5 4/9/2014 22:00 7.9 4/11/2014 15:00 3.1

4/3/2014 20:00 7.4 4/5/2014 13:00 3.2 4/8/2014 6:00 27.4 4/9/2014 23:00 9.4 4/11/2014 16:00 3

4/3/2014 21:00 11.7 4/5/2014 14:00 2.9 4/8/2014 7:00 31.9 4/10/2014 0:00 35.6 4/11/2014 17:00 2.9

4/3/2014 22:00 113.9 4/5/2014 15:00 2.8 4/8/2014 8:00 95.4 4/10/2014 1:00 22.5 4/11/2014 18:00 3.1

4/3/2014 23:00 228.5 4/5/2014 16:00 2.6 4/8/2014 9:00 88.2 4/10/2014 2:00 28.5 4/11/2014 19:00 5

4/4/2014 0:00 160.2 4/5/2014 17:00 2.6 4/8/2014 10:00 55.2 4/10/2014 3:00 52.9 4/11/2014 20:00 8.2

4/4/2014 1:00 59.4 4/5/2014 18:00 2.6 4/8/2014 11:00 26.9 4/10/2014 4:00 32.4 4/11/2014 21:00 5.8

4/4/2014 2:00 40.9 4/5/2014 19:00 2.6 4/8/2014 12:00 24.5 4/10/2014 5:00 40.6 4/11/2014 22:00 5.1

4/4/2014 3:00 26.5 4/5/2014 20:00 2.4 4/8/2014 13:00 31 4/10/2014 6:00 116.8 4/11/2014 23:00 5.1

4/4/2014 4:00 12.2 4/5/2014 21:00 2.4 4/8/2014 14:00 4/10/2014 7:00 121 4/12/2014 0:00 5.2

4/4/2014 5:00 52.1 4/5/2014 22:00 2.4 4/8/2014 15:00 48.3 4/10/2014 8:00 125.4 4/12/2014 1:00 7

4/4/2014 6:00 6.3 4/5/2014 23:00 2.3 4/8/2014 16:00 12.1 4/10/2014 9:00 48.5 4/12/2014 2:00 12.2

4/4/2014 7:00 43.6 4/6/2014 0:00 2.3 4/8/2014 17:00 28 4/10/2014 10:00 13.7 4/12/2014 3:00 22.8

4/4/2014 8:00 23.8 4/6/2014 1:00 2.3 4/8/2014 18:00 63.6 4/10/2014 11:00 9.8 4/12/2014 4:00 16.4

4/4/2014 9:00 12.3 4/6/2014 2:00 2.2 4/8/2014 19:00 40.9 4/10/2014 12:00 4.4 4/12/2014 5:00 13.4

4/4/2014 10:00 8.2 4/6/2014 3:00 2.2 4/8/2014 20:00 35.7 4/10/2014 13:00 3.4 4/12/2014 6:00 17.2

4/4/2014 11:00 10.4 4/6/2014 4:00 2.2 4/8/2014 21:00 42.4 4/10/2014 14:00 3 4/12/2014 7:00 21.6

4/4/2014 12:00 5 4/6/2014 5:00 2.2 4/8/2014 22:00 41.8 4/10/2014 15:00 3 4/12/2014 8:00 43.2

4/4/2014 13:00 3.3 4/6/2014 6:00 2.5 4/8/2014 23:00 36.7 4/10/2014 16:00 2.8 4/12/2014 9:00 88.1

4/4/2014 14:00 2.9 4/6/2014 7:00 6.9 4/9/2014 0:00 34.7 4/10/2014 17:00 2.8 4/12/2014 10:00 24.2

4/4/2014 15:00 3.1 4/6/2014 8:00 11 4/9/2014 1:00 29.9 4/10/2014 18:00 2.8 4/12/2014 11:00 12.4

4/4/2014 16:00 2.8 4/6/2014 9:00 9.1 4/9/2014 2:00 30.5 4/10/2014 19:00 3.3 4/12/2014 12:00 6.2

4/4/2014 17:00 2.8 4/6/2014 10:00 7.9 4/9/2014 3:00 26.7 4/10/2014 20:00 4.9 4/12/2014 13:00 7.7

4/4/2014 18:00 2.6 4/6/2014 11:00 30.3 4/9/2014 4:00 24.8 4/10/2014 21:00 6.3 4/12/2014 14:00 6

4/4/2014 19:00 2.9 4/6/2014 12:00 15.4 4/9/2014 5:00 26.2 4/10/2014 22:00 10.5 4/12/2014 15:00 7.5

4/4/2014 20:00 12.4 4/6/2014 13:00 6.9 4/9/2014 6:00 40.6 4/10/2014 23:00 14.9 4/12/2014 16:00 6.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 86
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/12/2014 17:00 4.5 4/14/2014 10:00 3 4/17/2014 3:00 9 4/18/2014 20:00 52.9 4/20/2014 13:00 7.6

4/12/2014 18:00 4.1 4/14/2014 11:00 31.8 4/17/2014 4:00 17.7 4/18/2014 21:00 48.2 4/20/2014 14:00 9.8

4/12/2014 19:00 4 4/14/2014 12:00 119.5 4/17/2014 5:00 52 4/18/2014 22:00 44 4/20/2014 15:00 10

4/12/2014 20:00 6.6 4/14/2014 13:00 52.3 4/17/2014 6:00 51.9 4/18/2014 23:00 52 4/20/2014 16:00 18.5

4/12/2014 21:00 16 4/14/2014 14:00 28.4 4/17/2014 7:00 140.7 4/19/2014 0:00 56.9 4/20/2014 17:00 60

4/12/2014 22:00 43 4/14/2014 15:00 4/17/2014 8:00 91.3 4/19/2014 1:00 62.3 4/20/2014 18:00 91.8

4/12/2014 23:00 54.4 4/14/2014 16:00 87.9 4/17/2014 9:00 10.5 4/19/2014 2:00 44.9 4/20/2014 19:00 156.4

4/13/2014 0:00 35.7 4/14/2014 17:00 72.9 4/17/2014 10:00 10.9 4/19/2014 3:00 19 4/20/2014 20:00 115.5

4/13/2014 1:00 28.3 4/14/2014 18:00 38.8 4/17/2014 11:00 8.1 4/19/2014 4:00 16.7 4/20/2014 21:00 93.3

4/13/2014 2:00 54.6 4/14/2014 19:00 36.2 4/17/2014 12:00 5.4 4/19/2014 5:00 71.1 4/20/2014 22:00 86.9

4/13/2014 3:00 39.5 4/14/2014 20:00 45.7 4/17/2014 13:00 5.3 4/19/2014 6:00 160.4 4/20/2014 23:00 239.9

4/13/2014 4:00 31 4/14/2014 21:00 34 4/17/2014 14:00 4 4/19/2014 7:00 59.8 4/21/2014 0:00 116.5

4/13/2014 5:00 18 4/14/2014 22:00 31.7 4/17/2014 15:00 4.8 4/19/2014 8:00 12.8 4/21/2014 1:00 97.8

4/13/2014 6:00 39.9 4/14/2014 23:00 30.8 4/17/2014 16:00 3.3 4/19/2014 9:00 12.7 4/21/2014 2:00 96.4

4/13/2014 7:00 168.1 4/16/2014 0:00 5.2 4/17/2014 17:00 3 4/19/2014 10:00 9.7 4/21/2014 3:00 98.1

4/13/2014 8:00 107 4/16/2014 1:00 15 4/17/2014 18:00 2.8 4/19/2014 11:00 6.9 4/21/2014 4:00 82.2

4/13/2014 9:00 21.1 4/16/2014 2:00 43 4/17/2014 19:00 3.2 4/19/2014 12:00 4.6 4/21/2014 5:00 72.5

4/13/2014 10:00 60.9 4/16/2014 3:00 54.3 4/17/2014 20:00 14.5 4/19/2014 13:00 3.7 4/21/2014 6:00 55.1

4/13/2014 11:00 98.6 4/16/2014 4:00 72.7 4/17/2014 21:00 24.7 4/19/2014 14:00 3.6 4/21/2014 7:00 75.9

4/13/2014 12:00 24.6 4/16/2014 5:00 52 4/17/2014 22:00 26 4/19/2014 15:00 5 4/21/2014 8:00 61.7

4/13/2014 13:00 7.7 4/16/2014 6:00 37.2 4/17/2014 23:00 14.4 4/19/2014 16:00 5.5 4/21/2014 9:00 19.1

4/13/2014 14:00 12.5 4/16/2014 7:00 64.5 4/18/2014 0:00 14.8 4/19/2014 17:00 5.3 4/21/2014 10:00 19.5

4/13/2014 15:00 21.4 4/16/2014 8:00 92.7 4/18/2014 1:00 32.9 4/19/2014 18:00 4/21/2014 11:00 11.9

4/13/2014 16:00 101.5 4/16/2014 9:00 44.6 4/18/2014 2:00 70.1 4/19/2014 19:00 25.2 4/21/2014 12:00 13.7

4/13/2014 17:00 141.6 4/16/2014 10:00 8.5 4/18/2014 3:00 43.9 4/19/2014 20:00 32.5 4/21/2014 13:00 19.3

4/13/2014 18:00 124.5 4/16/2014 11:00 5.1 4/18/2014 4:00 27.8 4/19/2014 21:00 36.7 4/21/2014 14:00 9.9

4/13/2014 19:00 101.5 4/16/2014 12:00 5.1 4/18/2014 5:00 41.9 4/19/2014 22:00 41.4 4/21/2014 15:00

4/13/2014 20:00 100.2 4/16/2014 13:00 4.2 4/18/2014 6:00 45.8 4/19/2014 23:00 73.7 4/21/2014 16:00 16.6

4/13/2014 21:00 12.3 4/16/2014 14:00 3.8 4/18/2014 7:00 95.5 4/20/2014 0:00 179.7 4/21/2014 17:00 16

4/13/2014 22:00 23.6 4/16/2014 15:00 4.4 4/18/2014 8:00 64.7 4/20/2014 1:00 166.7 4/21/2014 18:00 128.3

4/13/2014 23:00 20.1 4/16/2014 16:00 4.1 4/18/2014 9:00 13.6 4/20/2014 2:00 134.3 4/21/2014 19:00 40.4

4/14/2014 0:00 43.5 4/16/2014 17:00 4.1 4/18/2014 10:00 7.3 4/20/2014 3:00 304.2 4/21/2014 20:00 15

4/14/2014 1:00 48.6 4/16/2014 18:00 8.6 4/18/2014 11:00 5.6 4/20/2014 4:00 246 4/21/2014 21:00 60.9

4/14/2014 2:00 44 4/16/2014 19:00 11.7 4/18/2014 12:00 4.4 4/20/2014 5:00 28.3 4/21/2014 22:00 34.7

4/14/2014 3:00 27.6 4/16/2014 20:00 13.4 4/18/2014 13:00 3.7 4/20/2014 6:00 52.1 4/21/2014 23:00 16.6

4/14/2014 4:00 31.6 4/16/2014 21:00 13.3 4/18/2014 14:00 3.3 4/20/2014 7:00 72.3 4/22/2014 0:00 14.8

4/14/2014 5:00 4.2 4/16/2014 22:00 33.9 4/18/2014 15:00 3 4/20/2014 8:00 59.2 4/22/2014 1:00 47.4

4/14/2014 6:00 4.6 4/16/2014 23:00 13 4/18/2014 16:00 2.9 4/20/2014 9:00 49.5 4/22/2014 2:00 53.3

4/14/2014 7:00 14 4/17/2014 0:00 7 4/18/2014 17:00 3.2 4/20/2014 10:00 25.9 4/22/2014 3:00 84.4

4/14/2014 8:00 65.1 4/17/2014 1:00 9.6 4/18/2014 18:00 5.5 4/20/2014 11:00 17.1 4/22/2014 4:00 5.5

4/14/2014 9:00 44.8 4/17/2014 2:00 20.6 4/18/2014 19:00 18.5 4/20/2014 12:00 17.4 4/22/2014 5:00 31.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 87
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

4/22/2014 6:00 30.9 4/23/2014 23:00 40.3 4/25/2014 16:00 4.2 4/27/2014 9:00 23.7 5/3/2014 2:00 157.4

4/22/2014 7:00 140.6 4/24/2014 0:00 7.6 4/25/2014 17:00 10 4/27/2014 10:00 8.7 5/3/2014 3:00 126.8

4/22/2014 8:00 171.7 4/24/2014 1:00 9.2 4/25/2014 18:00 7 4/27/2014 11:00 5 5/3/2014 4:00 83.1

4/22/2014 9:00 26.1 4/24/2014 2:00 34.8 4/25/2014 19:00 4.7 4/27/2014 12:00 4 5/3/2014 5:00 86.4

4/22/2014 10:00 23.2 4/24/2014 3:00 49.9 4/25/2014 20:00 22.4 4/27/2014 13:00 3.4 5/3/2014 6:00 247.3

4/22/2014 11:00 25 4/24/2014 4:00 34.1 4/25/2014 21:00 73.4 4/27/2014 14:00 3.2 5/3/2014 7:00 270

4/22/2014 12:00 78.9 4/24/2014 5:00 44.3 4/25/2014 22:00 43 4/27/2014 15:00 3 5/3/2014 8:00 32.3

4/22/2014 13:00 10.3 4/24/2014 6:00 42.6 4/25/2014 23:00 73.8 4/27/2014 16:00 2.9 5/3/2014 9:00 17.1

4/22/2014 14:00 4/24/2014 7:00 79.9 4/26/2014 0:00 71.3 4/27/2014 17:00 2.8 5/3/2014 10:00 9.4

4/22/2014 15:00 7.5 4/24/2014 8:00 245 4/26/2014 1:00 50.1 4/27/2014 18:00 2.7 5/3/2014 11:00 5.9

4/22/2014 16:00 5.6 4/24/2014 9:00 61.7 4/26/2014 2:00 34.4 4/27/2014 19:00 2.6 5/3/2014 12:00 4.5

4/22/2014 17:00 6.3 4/24/2014 10:00 193 4/26/2014 3:00 41.1 4/27/2014 20:00 2.7 5/3/2014 13:00 3.9

4/22/2014 18:00 8.3 4/24/2014 11:00 20.9 4/26/2014 4:00 54.2 4/27/2014 21:00 2.9 5/3/2014 14:00 3.5

4/22/2014 19:00 15.7 4/24/2014 12:00 7.6 4/26/2014 5:00 50.4 4/27/2014 22:00 3.5 5/3/2014 15:00 3.2

4/22/2014 20:00 22.4 4/24/2014 13:00 8.7 4/26/2014 6:00 44.4 4/27/2014 23:00 6.3 5/3/2014 16:00 3.1

4/22/2014 21:00 18.5 4/24/2014 14:00 6.8 4/26/2014 7:00 83.7 4/30/2014 0:00 104.4 5/3/2014 17:00 3

4/22/2014 22:00 25.2 4/24/2014 15:00 7.2 4/26/2014 8:00 312.8 4/30/2014 1:00 157.9 5/3/2014 18:00 2.8

4/22/2014 23:00 25.8 4/24/2014 16:00 5.2 4/26/2014 9:00 26.1 4/30/2014 2:00 180.9 5/3/2014 19:00 2.7

4/23/2014 0:00 23.8 4/24/2014 17:00 6.6 4/26/2014 10:00 9.1 4/30/2014 3:00 93.6 5/3/2014 20:00 3.1

4/23/2014 1:00 28 4/24/2014 18:00 21.1 4/26/2014 11:00 8.7 4/30/2014 4:00 97.8 5/3/2014 21:00 4

4/23/2014 2:00 19.9 4/24/2014 19:00 59.8 4/26/2014 12:00 7.9 4/30/2014 5:00 90.2 5/3/2014 22:00 5.4

4/23/2014 3:00 24 4/24/2014 20:00 268.9 4/26/2014 13:00 4.6 4/30/2014 6:00 86.6 5/3/2014 23:00 12.9

4/23/2014 4:00 28.9 4/24/2014 21:00 249.3 4/26/2014 14:00 6.7 4/30/2014 7:00 136.8 5/5/2014 0:00 21.2

4/23/2014 5:00 19.3 4/24/2014 22:00 123.4 4/26/2014 15:00 4.1 4/30/2014 8:00 144.8 5/5/2014 1:00 29.9

4/23/2014 6:00 18 4/24/2014 23:00 51.8 4/26/2014 16:00 4.3 4/30/2014 9:00 84.1 5/5/2014 2:00 50

4/23/2014 7:00 19 4/25/2014 0:00 57.1 4/26/2014 17:00 11.8 4/30/2014 10:00 100.3 5/5/2014 3:00 49.2

4/23/2014 8:00 43 4/25/2014 1:00 25.5 4/26/2014 18:00 9.7 4/30/2014 11:00 48.2 5/5/2014 4:00 72.5

4/23/2014 9:00 17.7 4/25/2014 2:00 29.4 4/26/2014 19:00 14.3 4/30/2014 12:00 20.6 5/5/2014 5:00 45.4

4/23/2014 10:00 8.8 4/25/2014 3:00 45.5 4/26/2014 20:00 19.4 4/30/2014 13:00 12.8 5/5/2014 6:00 169.5

4/23/2014 11:00 5.6 4/25/2014 4:00 258.1 4/26/2014 21:00 71.3 4/30/2014 14:00 8.4 5/5/2014 7:00 196.8

4/23/2014 12:00 4.3 4/25/2014 5:00 66 4/26/2014 22:00 72.8 4/30/2014 15:00 6.9 5/5/2014 8:00 130.1

4/23/2014 13:00 3.5 4/25/2014 6:00 82.1 4/26/2014 23:00 45.8 4/30/2014 16:00 6.4 5/5/2014 9:00 15.1

4/23/2014 14:00 3.1 4/25/2014 7:00 99.2 4/27/2014 0:00 20 4/30/2014 17:00 9.1 5/5/2014 10:00 7.1

4/23/2014 15:00 3 4/25/2014 8:00 156.9 4/27/2014 1:00 21.3 4/30/2014 18:00 10.4 5/5/2014 11:00 5.5

4/23/2014 16:00 3 4/25/2014 9:00 109.9 4/27/2014 2:00 86.2 4/30/2014 19:00 8.7 5/5/2014 12:00 4.4

4/23/2014 17:00 3.3 4/25/2014 10:00 40 4/27/2014 3:00 145.5 4/30/2014 20:00 8.1 5/5/2014 13:00 3.7

4/23/2014 18:00 92.7 4/25/2014 11:00 14.8 4/27/2014 4:00 88.4 4/30/2014 21:00 8.3 5/5/2014 14:00 3.4

4/23/2014 19:00 153.2 4/25/2014 12:00 8.6 4/27/2014 5:00 41 4/30/2014 22:00 8.8 5/5/2014 15:00

4/23/2014 20:00 142.5 4/25/2014 13:00 7.5 4/27/2014 6:00 25.8 4/30/2014 23:00 9.3 5/5/2014 16:00 3.3

4/23/2014 21:00 190.5 4/25/2014 14:00 5.2 4/27/2014 7:00 17.8 5/3/2014 0:00 81.7 5/5/2014 17:00 3.2

4/23/2014 22:00 53.6 4/25/2014 15:00 4.4 4/27/2014 8:00 19.3 5/3/2014 1:00 158 5/5/2014 18:00 2.9

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 88
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/5/2014 19:00 2.8 5/8/2014 12:00 3.3 5/18/2014 5:00 65.7 5/19/2014 22:00 2.5 5/25/2014 15:00 2.5

5/5/2014 20:00 2.8 5/8/2014 13:00 3.1 5/18/2014 6:00 270.6 5/19/2014 23:00 4.4 5/25/2014 16:00 2.5

5/5/2014 21:00 3.1 5/8/2014 14:00 2.9 5/18/2014 7:00 165.9 5/20/2014 0:00 19.7 5/25/2014 17:00 2.4

5/5/2014 22:00 4 5/8/2014 15:00 4 5/18/2014 8:00 43.6 5/20/2014 1:00 43.5 5/25/2014 18:00 2.4

5/5/2014 23:00 21.8 5/8/2014 16:00 3 5/18/2014 9:00 9.6 5/20/2014 2:00 63.2 5/25/2014 19:00 2.4

5/6/2014 0:00 35 5/8/2014 17:00 2.8 5/18/2014 10:00 6.1 5/20/2014 3:00 89 5/25/2014 20:00 2.6

5/6/2014 1:00 38.5 5/8/2014 18:00 2.7 5/18/2014 11:00 4.3 5/20/2014 4:00 121.4 5/25/2014 21:00 17.4

5/6/2014 2:00 43.2 5/8/2014 19:00 2.6 5/18/2014 12:00 3.8 5/20/2014 5:00 204.6 5/25/2014 22:00 131.9

5/6/2014 3:00 21.8 5/8/2014 20:00 2.6 5/18/2014 13:00 3.2 5/20/2014 6:00 206.7 5/25/2014 23:00 35.7

5/6/2014 4:00 15.1 5/8/2014 21:00 2.4 5/18/2014 14:00 3.3 5/20/2014 7:00 220 5/26/2014 0:00 15.2

5/6/2014 5:00 15.1 5/8/2014 22:00 2.5 5/18/2014 15:00 3.1 5/20/2014 8:00 71.2 5/26/2014 1:00 22.6

5/6/2014 6:00 19.8 5/8/2014 23:00 2.5 5/18/2014 16:00 3.1 5/20/2014 9:00 18.8 5/26/2014 2:00 25.2

5/6/2014 7:00 67.8 5/10/2014 0:00 3 5/18/2014 17:00 3 5/20/2014 10:00 9.5 5/26/2014 3:00 13.4

5/6/2014 8:00 52 5/10/2014 1:00 5 5/18/2014 18:00 3 5/20/2014 11:00 5.8 5/26/2014 4:00 8.7

5/6/2014 9:00 9.7 5/10/2014 2:00 21.8 5/18/2014 19:00 2.9 5/20/2014 12:00 4.2 5/26/2014 5:00 9.4

5/6/2014 10:00 5/10/2014 3:00 39.7 5/18/2014 20:00 2.7 5/20/2014 13:00 3.6 5/26/2014 6:00 34.4

5/6/2014 11:00 5/10/2014 4:00 61.7 5/18/2014 21:00 2.7 5/20/2014 14:00 5/26/2014 7:00 50.4

5/6/2014 12:00 5/10/2014 5:00 50.9 5/18/2014 22:00 3.7 5/20/2014 15:00 4.8 5/26/2014 8:00 56.8

5/6/2014 13:00 5/10/2014 6:00 77 5/18/2014 23:00 9.9 5/20/2014 16:00 3.7 5/26/2014 9:00 14.1

5/6/2014 14:00 5/10/2014 7:00 151.2 5/19/2014 0:00 14.2 5/20/2014 17:00 3.4 5/26/2014 10:00 10.3

5/6/2014 15:00 3.1 5/10/2014 8:00 70.5 5/19/2014 1:00 43.5 5/20/2014 18:00 3.3 5/26/2014 11:00 9

5/6/2014 16:00 2.8 5/10/2014 9:00 9.3 5/19/2014 2:00 92.5 5/20/2014 19:00 3.1 5/26/2014 12:00 8.5

5/6/2014 17:00 5/10/2014 10:00 6.7 5/19/2014 3:00 99.2 5/20/2014 20:00 3.1 5/26/2014 13:00 4.6

5/6/2014 18:00 5/10/2014 11:00 6.8 5/19/2014 4:00 49.4 5/20/2014 21:00 2.9 5/26/2014 14:00 3.6

5/6/2014 19:00 8.3 5/10/2014 12:00 3.8 5/19/2014 5:00 39 5/20/2014 22:00 5.1 5/26/2014 15:00

5/6/2014 20:00 16 5/10/2014 13:00 3.4 5/19/2014 6:00 35.7 5/20/2014 23:00 18.6 5/26/2014 16:00 3.4

5/6/2014 21:00 50.3 5/10/2014 14:00 3.1 5/19/2014 7:00 30 5/25/2014 0:00 8 5/26/2014 17:00 3.4

5/6/2014 22:00 62.8 5/10/2014 15:00 2.9 5/19/2014 8:00 7.5 5/25/2014 1:00 5.1 5/26/2014 18:00 8.9

5/6/2014 23:00 93.8 5/10/2014 16:00 2.8 5/19/2014 9:00 4.7 5/25/2014 2:00 4.2 5/26/2014 19:00 11.3

5/8/2014 0:00 20.3 5/10/2014 17:00 2.8 5/19/2014 10:00 4.1 5/25/2014 3:00 3.5 5/26/2014 20:00 37.3

5/8/2014 1:00 18 5/10/2014 18:00 2.6 5/19/2014 11:00 3.6 5/25/2014 4:00 3.1 5/26/2014 21:00 82.6

5/8/2014 2:00 30.8 5/10/2014 19:00 2.6 5/19/2014 12:00 3 5/25/2014 5:00 3.2 5/26/2014 22:00 65.4

5/8/2014 3:00 161.7 5/10/2014 20:00 2.5 5/19/2014 13:00 2.9 5/25/2014 6:00 3.4 5/26/2014 23:00 51.8

5/8/2014 4:00 80.8 5/10/2014 21:00 2.6 5/19/2014 14:00 2.8 5/25/2014 7:00 3.6 5/28/2014 0:00 49.2

5/8/2014 5:00 63.7 5/10/2014 22:00 2.5 5/19/2014 15:00 5/25/2014 8:00 4.3 5/28/2014 1:00 34.5

5/8/2014 6:00 46.1 5/10/2014 23:00 2.5 5/19/2014 16:00 2.8 5/25/2014 9:00 5.5 5/28/2014 2:00 17.8

5/8/2014 7:00 43.9 5/18/2014 0:00 18.2 5/19/2014 17:00 2.7 5/25/2014 10:00 3.2 5/28/2014 3:00 56.1

5/8/2014 8:00 16.5 5/18/2014 1:00 49.9 5/19/2014 18:00 2.6 5/25/2014 11:00 2.9 5/28/2014 4:00 87.4

5/8/2014 9:00 6.6 5/18/2014 2:00 81.8 5/19/2014 19:00 2.5 5/25/2014 12:00 2.8 5/28/2014 5:00 31.9

5/8/2014 10:00 5.2 5/18/2014 3:00 83.5 5/19/2014 20:00 2.6 5/25/2014 13:00 2.7 5/28/2014 6:00 14.9

5/8/2014 11:00 3.8 5/18/2014 4:00 95.8 5/19/2014 21:00 2.5 5/25/2014 14:00 2.6 5/28/2014 7:00 31.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 89
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

5/28/2014 8:00 22.7 5/31/2014 1:00 39.7 6/2/2014 18:00 2.7 6/4/2014 11:00 9.8 6/6/2014 4:00 80.9

5/28/2014 9:00 15.6 5/31/2014 2:00 93.7 6/2/2014 19:00 8.2 6/4/2014 12:00 7.3 6/6/2014 5:00 62.3

5/28/2014 10:00 8 5/31/2014 3:00 39.9 6/2/2014 20:00 57.8 6/4/2014 13:00 7.5 6/6/2014 6:00 66.1

5/28/2014 11:00 9 5/31/2014 4:00 53.1 6/2/2014 21:00 77.9 6/4/2014 14:00 9.8 6/6/2014 7:00 28

5/28/2014 12:00 4.7 5/31/2014 5:00 68.6 6/2/2014 22:00 44.4 6/4/2014 15:00 5.4 6/6/2014 8:00 15

5/28/2014 13:00 3.8 5/31/2014 6:00 56.3 6/2/2014 23:00 59.8 6/4/2014 16:00 7.4 6/6/2014 9:00 12.2

5/28/2014 14:00 3.8 5/31/2014 7:00 60.9 6/3/2014 0:00 23.4 6/4/2014 17:00 4.6 6/6/2014 10:00 11.8

5/28/2014 15:00 3.3 5/31/2014 8:00 18.3 6/3/2014 1:00 41.8 6/4/2014 18:00 11.2 6/6/2014 11:00 7.6

5/28/2014 16:00 3.7 5/31/2014 9:00 12.9 6/3/2014 2:00 94.7 6/4/2014 19:00 10.3 6/6/2014 12:00 6.4

5/28/2014 17:00 4.4 5/31/2014 10:00 7.8 6/3/2014 3:00 86.8 6/4/2014 20:00 10 6/6/2014 13:00 6.6

5/28/2014 18:00 4.1 5/31/2014 11:00 4.7 6/3/2014 4:00 53.3 6/4/2014 21:00 10.8 6/6/2014 14:00 5.9

5/28/2014 19:00 4 5/31/2014 12:00 4 6/3/2014 5:00 23 6/4/2014 22:00 32.6 6/6/2014 15:00 7.5

5/28/2014 20:00 15.7 5/31/2014 13:00 3.5 6/3/2014 6:00 20.2 6/4/2014 23:00 46.1 6/6/2014 16:00 6.4

5/28/2014 21:00 51.1 5/31/2014 14:00 3.2 6/3/2014 7:00 23.2 6/5/2014 0:00 43.5 6/6/2014 17:00 304.9

5/28/2014 22:00 37.4 5/31/2014 15:00 3 6/3/2014 8:00 26 6/5/2014 1:00 57.1 6/6/2014 18:00 236.5

5/28/2014 23:00 16 5/31/2014 16:00 2.8 6/3/2014 9:00 24.5 6/5/2014 2:00 57.5 6/6/2014 19:00 63.1

5/30/2014 0:00 23.9 5/31/2014 17:00 2.8 6/3/2014 10:00 19.2 6/5/2014 3:00 50.2 6/6/2014 20:00 67.6

5/30/2014 1:00 23.2 5/31/2014 18:00 2.7 6/3/2014 11:00 8.7 6/5/2014 4:00 35.9 6/6/2014 21:00 54.5

5/30/2014 2:00 31.8 5/31/2014 19:00 3.5 6/3/2014 12:00 5.1 6/5/2014 5:00 16.2 6/6/2014 22:00 72.8

5/30/2014 3:00 48.3 5/31/2014 20:00 9.4 6/3/2014 13:00 4.1 6/5/2014 6:00 15.7 6/6/2014 23:00 23.6

5/30/2014 4:00 114.7 5/31/2014 21:00 16.1 6/3/2014 14:00 6/5/2014 7:00 204 6/7/2014 0:00 45.3

5/30/2014 5:00 151.1 5/31/2014 22:00 19 6/3/2014 15:00 4.6 6/5/2014 8:00 52.3 6/7/2014 1:00 26.4

5/30/2014 6:00 53.6 5/31/2014 23:00 30 6/3/2014 16:00 3.6 6/5/2014 9:00 18.4 6/7/2014 2:00 9

5/30/2014 7:00 54.5 6/2/2014 0:00 7.8 6/3/2014 17:00 3.3 6/5/2014 10:00 7.7 6/7/2014 3:00 53.4

5/30/2014 8:00 22.6 6/2/2014 1:00 7.9 6/3/2014 18:00 3.2 6/5/2014 11:00 6.2 6/7/2014 4:00 101.3

5/30/2014 9:00 13.6 6/2/2014 2:00 5 6/3/2014 19:00 5.4 6/5/2014 12:00 6.2 6/7/2014 5:00 37.9

5/30/2014 10:00 10.7 6/2/2014 3:00 3.7 6/3/2014 20:00 23.3 6/5/2014 13:00 5 6/7/2014 6:00 16.5

5/30/2014 11:00 11.2 6/2/2014 4:00 3.4 6/3/2014 21:00 18.2 6/5/2014 14:00 4.3 6/7/2014 7:00 200.1

5/30/2014 12:00 7.9 6/2/2014 5:00 3.5 6/3/2014 22:00 16.3 6/5/2014 15:00 5.7 6/7/2014 8:00 75.4

5/30/2014 13:00 4.7 6/2/2014 6:00 4.4 6/3/2014 23:00 23.9 6/5/2014 16:00 4.6 6/7/2014 9:00 14.5

5/30/2014 14:00 4 6/2/2014 7:00 6.7 6/4/2014 0:00 23.1 6/5/2014 17:00 5.5 6/7/2014 10:00 9.4

5/30/2014 15:00 3.9 6/2/2014 8:00 7.6 6/4/2014 1:00 27 6/5/2014 18:00 33.2 6/7/2014 11:00 8.3

5/30/2014 16:00 4.2 6/2/2014 9:00 6.5 6/4/2014 2:00 35.4 6/5/2014 19:00 14.9 6/7/2014 12:00 5.1

5/30/2014 17:00 4.5 6/2/2014 10:00 4.2 6/4/2014 3:00 65.6 6/5/2014 20:00 42 6/7/2014 13:00 3.8

5/30/2014 18:00 3.6 6/2/2014 11:00 3.5 6/4/2014 4:00 116.1 6/5/2014 21:00 40 6/7/2014 14:00 3.5

5/30/2014 19:00 6.6 6/2/2014 12:00 3.2 6/4/2014 5:00 110.2 6/5/2014 22:00 84.5 6/7/2014 15:00 3.3

5/30/2014 20:00 9.2 6/2/2014 13:00 2.9 6/4/2014 6:00 70.2 6/5/2014 23:00 71.8 6/7/2014 16:00 3.1

5/30/2014 21:00 12.5 6/2/2014 14:00 2.7 6/4/2014 7:00 82 6/6/2014 0:00 93.7 6/7/2014 17:00 3.2

5/30/2014 22:00 31.8 6/2/2014 15:00 6/4/2014 8:00 88.2 6/6/2014 1:00 61.2 6/7/2014 18:00 3.2

5/30/2014 23:00 52.2 6/2/2014 16:00 2.7 6/4/2014 9:00 32.4 6/6/2014 2:00 77.5 6/7/2014 19:00 3.6

5/31/2014 0:00 54 6/2/2014 17:00 2.7 6/4/2014 10:00 12.7 6/6/2014 3:00 37.4 6/7/2014 20:00 6.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 90
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/7/2014 21:00 5.6 6/14/2014 14:00 4.4 6/17/2014 7:00 90.2 6/20/2014 0:00 24.1 6/23/2014 17:00 3.4

6/7/2014 22:00 9.6 6/14/2014 15:00 3.6 6/17/2014 8:00 45.7 6/20/2014 1:00 27.6 6/23/2014 18:00 4

6/7/2014 23:00 8.7 6/14/2014 16:00 3.4 6/17/2014 9:00 14.5 6/20/2014 2:00 48 6/23/2014 19:00 3.9

6/8/2014 0:00 20.5 6/14/2014 17:00 4.9 6/17/2014 10:00 9.6 6/20/2014 3:00 89.2 6/23/2014 20:00 4.5

6/8/2014 1:00 17.1 6/14/2014 18:00 11.4 6/17/2014 11:00 6 6/20/2014 4:00 79.7 6/23/2014 21:00 5.2

6/8/2014 2:00 13 6/14/2014 19:00 22.8 6/17/2014 12:00 4.3 6/20/2014 5:00 79.4 6/23/2014 22:00 7.6

6/8/2014 3:00 11.2 6/14/2014 20:00 18.8 6/17/2014 13:00 3.9 6/20/2014 6:00 80.3 6/23/2014 23:00 13.3

6/8/2014 4:00 12.7 6/14/2014 21:00 14.8 6/17/2014 14:00 6/20/2014 7:00 71 6/24/2014 0:00 75.2

6/8/2014 5:00 21.2 6/14/2014 22:00 7.7 6/17/2014 15:00 4.7 6/20/2014 8:00 56.3 6/24/2014 1:00 120.3

6/8/2014 6:00 84.6 6/14/2014 23:00 4.1 6/17/2014 16:00 3.7 6/20/2014 9:00 44.7 6/24/2014 2:00 61.7

6/8/2014 7:00 101.5 6/16/2014 0:00 33 6/17/2014 17:00 3.3 6/20/2014 10:00 30.2 6/24/2014 3:00 21.3

6/8/2014 8:00 100.5 6/16/2014 1:00 39.7 6/17/2014 18:00 4 6/20/2014 11:00 20.8 6/24/2014 4:00 34.9

6/8/2014 9:00 17 6/16/2014 2:00 60.2 6/17/2014 19:00 5 6/20/2014 12:00 12.6 6/24/2014 5:00 66.1

6/8/2014 10:00 10.9 6/16/2014 3:00 57.7 6/17/2014 20:00 14.7 6/20/2014 13:00 10.1 6/24/2014 6:00 54.9

6/8/2014 11:00 6.2 6/16/2014 4:00 71.4 6/17/2014 21:00 11.6 6/20/2014 14:00 7.7 6/24/2014 7:00 47

6/8/2014 12:00 7.2 6/16/2014 5:00 137.3 6/17/2014 22:00 14.8 6/20/2014 15:00 7.6 6/24/2014 8:00 44.8

6/8/2014 13:00 6.5 6/16/2014 6:00 105.1 6/17/2014 23:00 23.8 6/20/2014 16:00 8.5 6/24/2014 9:00 36.2

6/8/2014 14:00 5.2 6/16/2014 7:00 62.4 6/19/2014 0:00 112.6 6/20/2014 17:00 10.3 6/24/2014 10:00 17.4

6/8/2014 15:00 3.7 6/16/2014 8:00 45.1 6/19/2014 1:00 125.2 6/20/2014 18:00 10 6/24/2014 11:00 7.7

6/8/2014 16:00 3.2 6/16/2014 9:00 51.9 6/19/2014 2:00 88.1 6/20/2014 19:00 10.3 6/24/2014 12:00 4.9

6/8/2014 17:00 3 6/16/2014 10:00 12.8 6/19/2014 3:00 88.1 6/20/2014 20:00 18.2 6/24/2014 13:00 4.1

6/8/2014 18:00 2.9 6/16/2014 11:00 6.2 6/19/2014 4:00 64.6 6/20/2014 21:00 28 6/24/2014 14:00

6/8/2014 19:00 3.9 6/16/2014 12:00 4.6 6/19/2014 5:00 54.1 6/20/2014 22:00 35.9 6/24/2014 15:00 4.7

6/8/2014 20:00 11 6/16/2014 13:00 3.9 6/19/2014 6:00 56.8 6/20/2014 23:00 33.7 6/24/2014 16:00 3.9

6/8/2014 21:00 17.7 6/16/2014 14:00 3.4 6/19/2014 7:00 94.9 6/23/2014 0:00 27.6 6/24/2014 17:00 3.5

6/8/2014 22:00 30.1 6/16/2014 15:00 6/19/2014 8:00 132.4 6/23/2014 1:00 34.7 6/24/2014 18:00 3.3

6/8/2014 23:00 21.2 6/16/2014 16:00 3.2 6/19/2014 9:00 56.6 6/23/2014 2:00 71.8 6/24/2014 19:00 3.2

6/14/2014 0:00 47.7 6/16/2014 17:00 3.1 6/19/2014 10:00 19.7 6/23/2014 3:00 46.3 6/24/2014 20:00 5

6/14/2014 1:00 36.5 6/16/2014 18:00 3 6/19/2014 11:00 7.8 6/23/2014 4:00 47.5 6/24/2014 21:00 11.7

6/14/2014 2:00 51.6 6/16/2014 19:00 3 6/19/2014 12:00 5.6 6/23/2014 5:00 83.4 6/24/2014 22:00 27.4

6/14/2014 3:00 36.7 6/16/2014 20:00 5.4 6/19/2014 13:00 5.4 6/23/2014 6:00 144.5 6/24/2014 23:00 41.1

6/14/2014 4:00 94.2 6/16/2014 21:00 7.9 6/19/2014 14:00 5.9 6/23/2014 7:00 107.9 6/28/2014 0:00 25.5

6/14/2014 5:00 99 6/16/2014 22:00 11.3 6/19/2014 15:00 6.6 6/23/2014 8:00 128.1 6/28/2014 1:00 60.4

6/14/2014 6:00 97.2 6/16/2014 23:00 11.4 6/19/2014 16:00 5.5 6/23/2014 9:00 72.6 6/28/2014 2:00 86.5

6/14/2014 7:00 75.4 6/17/2014 0:00 10.5 6/19/2014 17:00 5.3 6/23/2014 10:00 21.9 6/28/2014 3:00 99.6

6/14/2014 8:00 81.7 6/17/2014 1:00 13.6 6/19/2014 18:00 8.1 6/23/2014 11:00 8.5 6/28/2014 4:00 116

6/14/2014 9:00 7.5 6/17/2014 2:00 24.2 6/19/2014 19:00 10.1 6/23/2014 12:00 6.1 6/28/2014 5:00 156.5

6/14/2014 10:00 7.3 6/17/2014 3:00 39.3 6/19/2014 20:00 9.2 6/23/2014 13:00 4.7 6/28/2014 6:00 127.7

6/14/2014 11:00 6.9 6/17/2014 4:00 31.9 6/19/2014 21:00 28 6/23/2014 14:00 4 6/28/2014 7:00 78.4

6/14/2014 12:00 5.4 6/17/2014 5:00 18.3 6/19/2014 22:00 31.5 6/23/2014 15:00 6/28/2014 8:00 24.9

6/14/2014 13:00 5.2 6/17/2014 6:00 14.8 6/19/2014 23:00 33.2 6/23/2014 16:00 3.6 6/28/2014 9:00 13.2

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 91
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

6/28/2014 10:00 9.7 7/3/2014 3:00 46.3 7/4/2014 20:00 9.7 7/6/2014 13:00 3.5 7/11/2014 6:00 50.4

6/28/2014 11:00 6.4 7/3/2014 4:00 36.5 7/4/2014 21:00 14.8 7/6/2014 14:00 3.2 7/11/2014 7:00 88.8

6/28/2014 12:00 4.8 7/3/2014 5:00 87.4 7/4/2014 22:00 29.2 7/6/2014 15:00 3.1 7/11/2014 8:00 63.1

6/28/2014 13:00 4.1 7/3/2014 6:00 91.2 7/4/2014 23:00 44.5 7/6/2014 16:00 3.2 7/11/2014 9:00

6/28/2014 14:00 3.5 7/3/2014 7:00 22.4 7/5/2014 0:00 36.9 7/6/2014 17:00 3.2 7/11/2014 10:00 10.2

6/28/2014 15:00 3.2 7/3/2014 8:00 10.7 7/5/2014 1:00 42 7/6/2014 18:00 3.1 7/11/2014 11:00 6.5

6/28/2014 16:00 3.1 7/3/2014 9:00 10.7 7/5/2014 2:00 39.9 7/6/2014 19:00 4 7/11/2014 12:00 5.3

6/28/2014 17:00 2.9 7/3/2014 10:00 7 7/5/2014 3:00 45.6 7/6/2014 20:00 10.3 7/11/2014 13:00 4.7

6/28/2014 18:00 2.8 7/3/2014 11:00 5.9 7/5/2014 4:00 43.3 7/6/2014 21:00 31.8 7/11/2014 14:00 3.3

6/28/2014 19:00 2.8 7/3/2014 12:00 4.7 7/5/2014 5:00 40.5 7/6/2014 22:00 28 7/11/2014 15:00 3.2

6/28/2014 20:00 2.7 7/3/2014 13:00 3.9 7/5/2014 6:00 181 7/6/2014 23:00 28.5 7/11/2014 16:00 3

6/28/2014 21:00 2.6 7/3/2014 14:00 3.4 7/5/2014 7:00 334.6 7/9/2014 0:00 20.6 7/11/2014 17:00 4.3

6/28/2014 22:00 2.6 7/3/2014 15:00 4.3 7/5/2014 8:00 293.5 7/9/2014 1:00 16.6 7/11/2014 18:00 9.5

6/28/2014 23:00 2.7 7/3/2014 16:00 3.3 7/5/2014 9:00 81.1 7/9/2014 2:00 20.6 7/11/2014 19:00 9.9

6/29/2014 0:00 3.2 7/3/2014 17:00 3.1 7/5/2014 10:00 16.5 7/9/2014 3:00 40.9 7/11/2014 20:00 8.5

6/29/2014 1:00 8.4 7/3/2014 18:00 2.9 7/5/2014 11:00 9.3 7/9/2014 4:00 15.9 7/11/2014 21:00 10.3

6/29/2014 2:00 18.2 7/3/2014 19:00 3.1 7/5/2014 12:00 6.2 7/9/2014 5:00 17.4 7/11/2014 22:00 12.6

6/29/2014 3:00 43.7 7/3/2014 20:00 3.6 7/5/2014 13:00 4.9 7/9/2014 6:00 20.9 7/11/2014 23:00 25.8

6/29/2014 4:00 69.1 7/3/2014 21:00 4 7/5/2014 14:00 3.7 7/9/2014 7:00 13.2 7/12/2014 0:00 28.4

6/29/2014 5:00 130.8 7/3/2014 22:00 4.6 7/5/2014 15:00 3.5 7/9/2014 8:00 88.5 7/12/2014 1:00 26.7

6/29/2014 6:00 186.9 7/3/2014 23:00 6.9 7/5/2014 16:00 3.4 7/9/2014 9:00 34.5 7/12/2014 2:00 35.7

6/29/2014 7:00 253.1 7/4/2014 0:00 24.7 7/5/2014 17:00 3.3 7/9/2014 10:00 19.1 7/12/2014 3:00 35.9

6/29/2014 8:00 329.7 7/4/2014 1:00 61.8 7/5/2014 18:00 3.4 7/9/2014 11:00 9.3 7/12/2014 4:00 39.1

6/29/2014 9:00 130.6 7/4/2014 2:00 103.5 7/5/2014 19:00 3.4 7/9/2014 12:00 5.1 7/12/2014 5:00 34.8

6/29/2014 10:00 18.8 7/4/2014 3:00 105.4 7/5/2014 20:00 3.9 7/9/2014 13:00 4.3 7/12/2014 6:00 49.1

6/29/2014 11:00 10.8 7/4/2014 4:00 65.4 7/5/2014 21:00 3.4 7/9/2014 14:00 3.5 7/12/2014 7:00 39.9

6/29/2014 12:00 8.7 7/4/2014 5:00 77 7/5/2014 22:00 3.6 7/9/2014 15:00 3.2 7/12/2014 8:00 37.7

6/29/2014 13:00 5.9 7/4/2014 6:00 138 7/5/2014 23:00 4.3 7/9/2014 16:00 3 7/12/2014 9:00 13.5

6/29/2014 14:00 4.5 7/4/2014 7:00 326.9 7/6/2014 0:00 6.1 7/9/2014 17:00 2.9 7/12/2014 10:00 10.2

6/29/2014 15:00 4 7/4/2014 8:00 343.3 7/6/2014 1:00 5.3 7/9/2014 18:00 2.8 7/12/2014 11:00 5.2

6/29/2014 16:00 3.6 7/4/2014 9:00 344.9 7/6/2014 2:00 5.7 7/9/2014 19:00 3 7/12/2014 12:00 4

6/29/2014 17:00 3.5 7/4/2014 10:00 131.4 7/6/2014 3:00 9.3 7/9/2014 20:00 3.7 7/12/2014 13:00 3.7

6/29/2014 18:00 3.3 7/4/2014 11:00 58.3 7/6/2014 4:00 138.7 7/9/2014 21:00 3.7 7/12/2014 14:00 3.5

6/29/2014 19:00 4 7/4/2014 12:00 16.7 7/6/2014 5:00 41.4 7/9/2014 22:00 3.4 7/12/2014 15:00 3.3

6/29/2014 20:00 4.7 7/4/2014 13:00 9.3 7/6/2014 6:00 39.7 7/9/2014 23:00 3.3 7/12/2014 16:00 3.2

6/29/2014 21:00 4.1 7/4/2014 14:00 7.1 7/6/2014 7:00 84.3 7/11/2014 0:00 8.8 7/12/2014 17:00 2.9

6/29/2014 22:00 4.3 7/4/2014 15:00 6.1 7/6/2014 8:00 69.6 7/11/2014 1:00 8.2 7/12/2014 18:00 2.9

6/29/2014 23:00 10.6 7/4/2014 16:00 5.6 7/6/2014 9:00 11 7/11/2014 2:00 10.9 7/12/2014 19:00 2.8

7/3/2014 0:00 80.7 7/4/2014 17:00 5 7/6/2014 10:00 6.2 7/11/2014 3:00 11.5 7/12/2014 20:00 2.9

7/3/2014 1:00 35 7/4/2014 18:00 6.3 7/6/2014 11:00 5 7/11/2014 4:00 15.2 7/12/2014 21:00 4.9

7/3/2014 2:00 65.3 7/4/2014 19:00 9 7/6/2014 12:00 4 7/11/2014 5:00 27.3 7/12/2014 22:00 41.4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 92
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/12/2014 23:00 107.4 7/14/2014 16:00 5.2 7/18/2014 9:00 22 7/22/2014 2:00 6 7/25/2014 19:00 4.5

7/13/2014 0:00 128.4 7/14/2014 17:00 3.8 7/18/2014 10:00 11.7 7/22/2014 3:00 27.8 7/25/2014 20:00 19.3

7/13/2014 1:00 141.2 7/14/2014 18:00 3.4 7/18/2014 11:00 7.8 7/22/2014 4:00 36.1 7/25/2014 21:00 32.1

7/13/2014 2:00 116.5 7/14/2014 19:00 3.1 7/18/2014 12:00 5.1 7/22/2014 5:00 89.7 7/25/2014 22:00 97.4

7/13/2014 3:00 243.7 7/14/2014 20:00 4.8 7/18/2014 13:00 5 7/22/2014 6:00 99 7/25/2014 23:00 26.8

7/13/2014 4:00 204.6 7/14/2014 21:00 7.2 7/18/2014 14:00 4.2 7/22/2014 7:00 93.2 7/27/2014 0:00 31.9

7/13/2014 5:00 101.7 7/14/2014 22:00 7.4 7/18/2014 15:00 3.8 7/22/2014 8:00 52.6 7/27/2014 1:00 42.5

7/13/2014 6:00 79.7 7/14/2014 23:00 8 7/18/2014 16:00 3.4 7/22/2014 9:00 10.8 7/27/2014 2:00 68.1

7/13/2014 7:00 41.7 7/15/2014 0:00 10 7/18/2014 17:00 3.1 7/22/2014 10:00 7.3 7/27/2014 3:00 55.9

7/13/2014 8:00 36.7 7/15/2014 1:00 16.4 7/18/2014 18:00 3.1 7/22/2014 11:00 5.7 7/27/2014 4:00 67.1

7/13/2014 9:00 24 7/15/2014 2:00 12.7 7/18/2014 19:00 3.5 7/22/2014 12:00 5.3 7/27/2014 5:00 166.6

7/13/2014 10:00 16.3 7/15/2014 3:00 17.7 7/18/2014 20:00 6.1 7/22/2014 13:00 4.1 7/27/2014 6:00 173.9

7/13/2014 11:00 7.3 7/15/2014 4:00 51.7 7/18/2014 21:00 9.9 7/22/2014 14:00 7/27/2014 7:00 99.4

7/13/2014 12:00 5.3 7/15/2014 5:00 70.4 7/18/2014 22:00 10.2 7/22/2014 15:00 6 7/27/2014 8:00 46.8

7/13/2014 13:00 4.4 7/15/2014 6:00 107.9 7/18/2014 23:00 26.8 7/22/2014 16:00 3.8 7/27/2014 9:00 15.8

7/13/2014 14:00 3.7 7/15/2014 7:00 88.7 7/19/2014 0:00 30.2 7/22/2014 17:00 3.4 7/27/2014 10:00 17.6

7/13/2014 15:00 3.3 7/15/2014 8:00 70.4 7/19/2014 1:00 39.2 7/22/2014 18:00 3.4 7/27/2014 11:00 6.2

7/13/2014 16:00 3 7/15/2014 9:00 44.4 7/19/2014 2:00 35.7 7/22/2014 19:00 3.9 7/27/2014 12:00 4.6

7/13/2014 17:00 2.9 7/15/2014 10:00 27.3 7/19/2014 3:00 55 7/22/2014 20:00 3.9 7/27/2014 13:00 3.7

7/13/2014 18:00 3.3 7/15/2014 11:00 12.1 7/19/2014 4:00 205.2 7/22/2014 21:00 4.6 7/27/2014 14:00 3.6

7/13/2014 19:00 3.3 7/15/2014 12:00 9 7/19/2014 5:00 195.3 7/22/2014 22:00 4.9 7/27/2014 15:00 3.2

7/13/2014 20:00 7 7/15/2014 13:00 6.2 7/19/2014 6:00 163.9 7/22/2014 23:00 6.5 7/27/2014 16:00 3.2

7/13/2014 21:00 16.2 7/15/2014 14:00 7/19/2014 7:00 131.4 7/25/2014 0:00 29.3 7/27/2014 17:00 3.1

7/13/2014 22:00 94.5 7/15/2014 15:00 11.9 7/19/2014 8:00 122.6 7/25/2014 1:00 36.7 7/27/2014 18:00 3.1

7/13/2014 23:00 145.7 7/15/2014 16:00 6.4 7/19/2014 9:00 112.1 7/25/2014 2:00 44.8 7/27/2014 19:00 3.1

7/14/2014 0:00 166.3 7/15/2014 17:00 5.2 7/19/2014 10:00 53.5 7/25/2014 3:00 35.4 7/27/2014 20:00 3.8

7/14/2014 1:00 80.8 7/15/2014 18:00 4.4 7/19/2014 11:00 16.9 7/25/2014 4:00 37 7/27/2014 21:00 3.8

7/14/2014 2:00 23.4 7/15/2014 19:00 3.9 7/19/2014 12:00 11.5 7/25/2014 5:00 37.4 7/27/2014 22:00 4.8

7/14/2014 3:00 10.6 7/15/2014 20:00 3.6 7/19/2014 13:00 7.6 7/25/2014 6:00 26.2 7/27/2014 23:00 10.4

7/14/2014 4:00 7.2 7/15/2014 21:00 3.8 7/19/2014 14:00 5.7 7/25/2014 7:00 44.5 7/28/2014 0:00 10.9

7/14/2014 5:00 6 7/15/2014 22:00 4.1 7/19/2014 15:00 4.7 7/25/2014 8:00 21.5 7/28/2014 1:00 30

7/14/2014 6:00 5 7/15/2014 23:00 5.1 7/19/2014 16:00 4 7/25/2014 9:00 25.2 7/28/2014 2:00 107.6

7/14/2014 7:00 4.3 7/18/2014 0:00 11 7/19/2014 17:00 3.7 7/25/2014 10:00 20.7 7/28/2014 3:00 102.7

7/14/2014 8:00 3.9 7/18/2014 1:00 62.1 7/19/2014 18:00 3.4 7/25/2014 11:00 8.5 7/28/2014 4:00 152.2

7/14/2014 9:00 3.6 7/18/2014 2:00 128.1 7/19/2014 19:00 3.2 7/25/2014 12:00 4.3 7/28/2014 5:00 171.8

7/14/2014 10:00 3.4 7/18/2014 3:00 86.8 7/19/2014 20:00 3.7 7/25/2014 13:00 3.9 7/28/2014 6:00 182.2

7/14/2014 11:00 3.3 7/18/2014 4:00 21.5 7/19/2014 21:00 7.5 7/25/2014 14:00 3.5 7/28/2014 7:00 112.9

7/14/2014 12:00 3.1 7/18/2014 5:00 15 7/19/2014 22:00 5.8 7/25/2014 15:00 3.2 7/28/2014 8:00 25.5

7/14/2014 13:00 3 7/18/2014 6:00 33.7 7/19/2014 23:00 5.3 7/25/2014 16:00 3 7/28/2014 9:00 22.3

7/14/2014 14:00 2.9 7/18/2014 7:00 41.6 7/22/2014 0:00 3 7/25/2014 17:00 3 7/28/2014 10:00 23

7/14/2014 15:00 7/18/2014 8:00 60.4 7/22/2014 1:00 4.3 7/25/2014 18:00 3.2 7/28/2014 11:00 7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 93
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

7/28/2014 12:00 5.1 7/30/2014 5:00 52.1 8/1/2014 22:00 4.4 8/16/2014 2:00 84.4 8/17/2014 19:00 5

7/28/2014 13:00 4.1 7/30/2014 6:00 50.4 8/1/2014 23:00 4.5 8/16/2014 3:00 43.5 8/17/2014 20:00 5.8

7/28/2014 14:00 3.7 7/30/2014 7:00 60.8 8/3/2014 0:00 26.9 8/16/2014 4:00 53.6 8/17/2014 21:00 7.8

7/28/2014 15:00 7/30/2014 8:00 104.7 8/3/2014 1:00 35.1 8/16/2014 5:00 39.5 8/17/2014 22:00 4.9

7/28/2014 16:00 3.5 7/30/2014 9:00 61.8 8/3/2014 2:00 65.9 8/16/2014 6:00 26.8 8/17/2014 23:00 5.9

7/28/2014 17:00 3.3 7/30/2014 10:00 17.3 8/3/2014 3:00 157.6 8/16/2014 7:00 12.4 8/20/2014 0:00 30.9

7/28/2014 18:00 3.2 7/30/2014 11:00 7.8 8/3/2014 4:00 169.7 8/16/2014 8:00 16.8 8/20/2014 1:00 40.1

7/28/2014 19:00 3.2 7/30/2014 12:00 5.1 8/3/2014 5:00 188.3 8/16/2014 9:00 22.1 8/20/2014 2:00 58.5

7/28/2014 20:00 3.2 7/30/2014 13:00 4.5 8/3/2014 6:00 76.3 8/16/2014 10:00 11.1 8/20/2014 3:00 103.5

7/28/2014 21:00 3.6 7/30/2014 14:00 3.8 8/3/2014 7:00 51.2 8/16/2014 11:00 6.2 8/20/2014 4:00 81.9

7/28/2014 22:00 8.8 7/30/2014 15:00 3.6 8/3/2014 8:00 55.2 8/16/2014 12:00 5.9 8/20/2014 5:00 39.4

7/28/2014 23:00 75.4 7/30/2014 16:00 3.9 8/3/2014 9:00 57.5 8/16/2014 13:00 2.6 8/20/2014 6:00 30.6

7/29/2014 0:00 103 7/30/2014 17:00 4.6 8/3/2014 10:00 16.7 8/16/2014 14:00 1.6 8/20/2014 7:00 29

7/29/2014 1:00 37.9 7/30/2014 18:00 8.1 8/3/2014 11:00 9.1 8/16/2014 15:00 2.1 8/20/2014 8:00 16.8

7/29/2014 2:00 28.5 7/30/2014 19:00 16.8 8/3/2014 12:00 6.2 8/16/2014 16:00 4.5 8/20/2014 9:00 12.8

7/29/2014 3:00 23.2 7/30/2014 20:00 16.8 8/3/2014 13:00 4.7 8/16/2014 17:00 4.6 8/20/2014 10:00 13.7

7/29/2014 4:00 34.7 7/30/2014 21:00 15.4 8/3/2014 14:00 3.9 8/16/2014 18:00 5.5 8/20/2014 11:00 5.5

7/29/2014 5:00 67.2 7/30/2014 22:00 19 8/3/2014 15:00 3.7 8/16/2014 19:00 5.8 8/20/2014 12:00 2.8

7/29/2014 6:00 125.2 7/30/2014 23:00 32.7 8/3/2014 16:00 3.4 8/16/2014 20:00 8.9 8/20/2014 13:00 1.8

7/29/2014 7:00 119.6 8/1/2014 0:00 11 8/3/2014 17:00 3.3 8/16/2014 21:00 13.7 8/20/2014 14:00

7/29/2014 8:00 96.5 8/1/2014 1:00 13.9 8/3/2014 18:00 3.4 8/16/2014 22:00 14.9 8/20/2014 15:00

7/29/2014 9:00 31.4 8/1/2014 2:00 15.1 8/3/2014 19:00 4.1 8/16/2014 23:00 45.3 8/20/2014 16:00

7/29/2014 10:00 11.6 8/1/2014 3:00 12.5 8/3/2014 20:00 5.4 8/17/2014 0:00 58.3 8/20/2014 17:00 2

7/29/2014 11:00 6.6 8/1/2014 4:00 14.7 8/3/2014 21:00 5.7 8/17/2014 1:00 46 8/20/2014 18:00 1.4

7/29/2014 12:00 5.1 8/1/2014 5:00 22.3 8/3/2014 22:00 5 8/17/2014 2:00 41.2 8/20/2014 19:00 1.4

7/29/2014 13:00 4.3 8/1/2014 6:00 141.7 8/3/2014 23:00 6.5 8/17/2014 3:00 47.9 8/20/2014 20:00 1.8

7/29/2014 14:00 8/1/2014 7:00 174.7 8/5/2014 0:00 16.6 8/17/2014 4:00 68.4 8/20/2014 21:00 5.8

7/29/2014 15:00 5.6 8/1/2014 8:00 116 8/5/2014 1:00 13.5 8/17/2014 5:00 60.9 8/20/2014 22:00 10.6

7/29/2014 16:00 4.7 8/1/2014 9:00 71.5 8/5/2014 2:00 13.5 8/17/2014 6:00 53.9 8/20/2014 23:00 11.7

7/29/2014 17:00 4.7 8/1/2014 10:00 51.5 8/5/2014 3:00 32.3 8/17/2014 7:00 57.1 8/22/2014 0:00 21.4

7/29/2014 18:00 4.4 8/1/2014 11:00 21.9 8/5/2014 4:00 36.7 8/17/2014 8:00 62.3 8/22/2014 1:00 28.3

7/29/2014 19:00 4.4 8/1/2014 12:00 8.6 8/5/2014 5:00 47.9 8/17/2014 9:00 77.8 8/22/2014 2:00 40.8

7/29/2014 20:00 5.7 8/1/2014 13:00 5.3 8/5/2014 6:00 42.9 8/17/2014 10:00 7.4 8/22/2014 3:00 76.7

7/29/2014 21:00 7 8/1/2014 14:00 4 8/5/2014 7:00 69.8 8/17/2014 11:00 8.4 8/22/2014 4:00 81.6

7/29/2014 22:00 4.3 8/1/2014 15:00 3.6 8/5/2014 8:00 77.1 8/17/2014 12:00 9.5 8/22/2014 5:00 87.9

7/29/2014 23:00 6.9 8/1/2014 16:00 3.4 8/5/2014 9:00 25.6 8/17/2014 13:00 3.8 8/22/2014 6:00 66

7/30/2014 0:00 8.9 8/1/2014 17:00 3.2 8/5/2014 10:00 11.3 8/17/2014 14:00 2.8 8/22/2014 7:00 157.8

7/30/2014 1:00 13.5 8/1/2014 18:00 3 8/5/2014 11:00 6.9 8/17/2014 15:00 2.4 8/22/2014 8:00 223.7

7/30/2014 2:00 37.2 8/1/2014 19:00 3.1 8/5/2014 12:00 4.8 8/17/2014 16:00 2.2 8/22/2014 9:00 127.3

7/30/2014 3:00 52.9 8/1/2014 20:00 4.1 8/16/2014 0:00 29.7 8/17/2014 17:00 2.8 8/22/2014 10:00 190.8

7/30/2014 4:00 56.4 8/1/2014 21:00 5.5 8/16/2014 1:00 57.4 8/17/2014 18:00 4.7 8/22/2014 11:00 122.3

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 94
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

8/22/2014 12:00 32.9 9/3/2014 5:00 12.8 9/4/2014 22:00 30.9 9/7/2014 15:00 1.3 9/9/2014 8:00 19.3

8/22/2014 13:00 35.8 9/3/2014 6:00 11.5 9/4/2014 23:00 28.8 9/7/2014 16:00 1.2 9/9/2014 9:00 21.4

8/22/2014 14:00 24.8 9/3/2014 7:00 19.8 9/5/2014 0:00 29 9/7/2014 17:00 1.1 9/9/2014 10:00 14.2

8/22/2014 15:00 12.6 9/3/2014 8:00 23.6 9/5/2014 1:00 43.2 9/7/2014 18:00 1 9/9/2014 11:00 7

8/22/2014 16:00 10 9/3/2014 9:00 83.2 9/5/2014 2:00 109.4 9/7/2014 19:00 1 9/9/2014 12:00 2.7

8/22/2014 17:00 14.9 9/3/2014 10:00 47.1 9/5/2014 3:00 163.7 9/7/2014 20:00 2.1 9/9/2014 13:00 2

8/22/2014 18:00 19.8 9/3/2014 11:00 7 9/5/2014 4:00 118.5 9/7/2014 21:00 1.4 9/9/2014 14:00

8/22/2014 19:00 16.1 9/3/2014 12:00 3.9 9/5/2014 5:00 111.6 9/7/2014 22:00 2.7 9/9/2014 15:00 3.1

8/22/2014 20:00 17.6 9/3/2014 13:00 2.6 9/5/2014 6:00 190.7 9/7/2014 23:00 5.3 9/9/2014 16:00 1.8

8/22/2014 21:00 18.9 9/3/2014 14:00 2 9/5/2014 7:00 144.1 9/8/2014 0:00 5.5 9/9/2014 17:00 1.4

8/22/2014 22:00 28.4 9/3/2014 15:00 1.7 9/5/2014 8:00 82 9/8/2014 1:00 6 9/9/2014 18:00 8.5

8/22/2014 23:00 30.5 9/3/2014 16:00 1.4 9/5/2014 9:00 28.7 9/8/2014 2:00 12.4 9/9/2014 19:00 26.2

8/23/2014 0:00 26 9/3/2014 17:00 1.2 9/5/2014 10:00 10.6 9/8/2014 3:00 16.4 9/9/2014 20:00 103.9

8/23/2014 1:00 32.9 9/3/2014 18:00 1.1 9/5/2014 11:00 4 9/8/2014 4:00 13.6 9/9/2014 21:00 39.4

8/23/2014 2:00 20.4 9/3/2014 19:00 2 9/5/2014 12:00 2.8 9/8/2014 5:00 9.9 9/9/2014 22:00 24.5

8/23/2014 3:00 13.8 9/3/2014 20:00 6 9/5/2014 13:00 2.3 9/8/2014 6:00 10.4 9/9/2014 23:00 26.5

8/23/2014 4:00 9.7 9/3/2014 21:00 11.8 9/5/2014 14:00 2.1 9/8/2014 7:00 14.5 9/22/2014 0:00 3

8/23/2014 5:00 11.7 9/3/2014 22:00 23.2 9/5/2014 15:00 1.7 9/8/2014 8:00 22 9/22/2014 1:00 5

8/23/2014 6:00 12.4 9/3/2014 23:00 16.7 9/5/2014 16:00 1.3 9/8/2014 9:00 12.5 9/22/2014 2:00 6.8

8/23/2014 7:00 23.4 9/4/2014 0:00 18.5 9/5/2014 17:00 1.2 9/8/2014 10:00 19.1 9/22/2014 3:00 10.7

8/23/2014 8:00 80.6 9/4/2014 1:00 13.4 9/5/2014 18:00 1.2 9/8/2014 11:00 5.5 9/22/2014 4:00 37.6

8/23/2014 9:00 116.4 9/4/2014 2:00 21.8 9/5/2014 19:00 0.9 9/8/2014 12:00 2.7 9/22/2014 5:00 37.1

8/23/2014 10:00 43.1 9/4/2014 3:00 32.3 9/5/2014 20:00 1.4 9/8/2014 13:00 1.9 9/22/2014 6:00 28.7

8/23/2014 11:00 25.4 9/4/2014 4:00 93.9 9/5/2014 21:00 4.1 9/8/2014 14:00 1.5 9/22/2014 7:00 44.6

8/23/2014 12:00 28.7 9/4/2014 5:00 92.6 9/5/2014 22:00 5.8 9/8/2014 15:00 9/22/2014 8:00 93.8

8/23/2014 13:00 4.7 9/4/2014 6:00 77.7 9/5/2014 23:00 6.3 9/8/2014 16:00 1.3 9/22/2014 9:00 53.4

8/23/2014 14:00 2.7 9/4/2014 7:00 56.3 9/7/2014 0:00 93.8 9/8/2014 17:00 1.1 9/22/2014 10:00 15.7

8/23/2014 15:00 2.2 9/4/2014 8:00 34.5 9/7/2014 1:00 109.7 9/8/2014 18:00 0.9 9/22/2014 11:00 5.2

8/23/2014 16:00 2.2 9/4/2014 9:00 19.9 9/7/2014 2:00 24.9 9/8/2014 19:00 1.9 9/22/2014 12:00 3.3

8/23/2014 17:00 2.2 9/4/2014 10:00 17.5 9/7/2014 3:00 47.4 9/8/2014 20:00 9.5 9/22/2014 13:00 2.4

8/23/2014 18:00 2.3 9/4/2014 11:00 6.7 9/7/2014 4:00 76 9/8/2014 21:00 78.3 9/22/2014 14:00 2

8/23/2014 19:00 5.3 9/4/2014 12:00 3 9/7/2014 5:00 72.9 9/8/2014 22:00 21.5 9/22/2014 15:00

8/23/2014 20:00 21.8 9/4/2014 13:00 2.1 9/7/2014 6:00 33.7 9/8/2014 23:00 26.9 9/22/2014 16:00 2.5

8/23/2014 21:00 28.2 9/4/2014 14:00 1.7 9/7/2014 7:00 39.4 9/9/2014 0:00 22.7 9/22/2014 17:00 3.2

8/23/2014 22:00 27.2 9/4/2014 15:00 2.7 9/7/2014 8:00 37.3 9/9/2014 1:00 15.4 9/22/2014 18:00 15.5

8/23/2014 23:00 31.2 9/4/2014 16:00 1.6 9/7/2014 9:00 12.1 9/9/2014 2:00 11.1 9/22/2014 19:00 14

9/3/2014 0:00 9.5 9/4/2014 17:00 1.2 9/7/2014 10:00 4.9 9/9/2014 3:00 13.8 9/22/2014 20:00 16.9

9/3/2014 1:00 12 9/4/2014 18:00 1.3 9/7/2014 11:00 2.6 9/9/2014 4:00 17.5 9/22/2014 21:00 12.3

9/3/2014 2:00 9.8 9/4/2014 19:00 3.1 9/7/2014 12:00 2.1 9/9/2014 5:00 17.5 9/22/2014 22:00 21

9/3/2014 3:00 8.9 9/4/2014 20:00 32.3 9/7/2014 13:00 1.7 9/9/2014 6:00 14.5 9/22/2014 23:00 19.3

9/3/2014 4:00 10 9/4/2014 21:00 40.3 9/7/2014 14:00 1.5 9/9/2014 7:00 11.2 9/23/2014 0:00 6.5

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 95
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

9/23/2014 1:00 3.7 9/24/2014 18:00 6 9/26/2014 11:00 7.5 10/3/2014 4:00 100.9 10/10/2014 21:00 16.1

9/23/2014 2:00 6.5 9/24/2014 19:00 5.5 9/26/2014 12:00 1.5 10/3/2014 5:00 74 10/10/2014 22:00 15.7

9/23/2014 3:00 30.2 9/24/2014 20:00 7.7 9/26/2014 13:00 1.2 10/3/2014 6:00 59.4 10/10/2014 23:00 15.1

9/23/2014 4:00 68.3 9/24/2014 21:00 12.5 9/26/2014 14:00 1.1 10/3/2014 7:00 50.8 10/11/2014 0:00 3.2

9/23/2014 5:00 100.6 9/24/2014 22:00 14.7 9/26/2014 15:00 1.4 10/3/2014 8:00 16.4 10/11/2014 1:00 28.2

9/23/2014 6:00 32.2 9/24/2014 23:00 15.1 9/26/2014 16:00 1.7 10/3/2014 9:00 15.4 10/11/2014 2:00 40.5

9/23/2014 7:00 40.4 9/25/2014 0:00 17.7 9/26/2014 17:00 1.9 10/3/2014 10:00 15.7 10/11/2014 3:00 12.1

9/23/2014 8:00 71.7 9/25/2014 1:00 23.7 9/26/2014 18:00 1.9 10/3/2014 11:00 3.9 10/11/2014 4:00 3.5

9/23/2014 9:00 10.6 9/25/2014 2:00 24.9 9/26/2014 19:00 1.7 10/3/2014 12:00 2.5 10/11/2014 5:00 1.7

9/23/2014 10:00 9.9 9/25/2014 3:00 19.1 9/26/2014 20:00 1.6 10/3/2014 13:00 2.1 10/11/2014 6:00 36.3

9/23/2014 11:00 3.7 9/25/2014 4:00 20.3 9/26/2014 21:00 1.4 10/3/2014 14:00 1.7 10/11/2014 7:00 249.5

9/23/2014 12:00 2 9/25/2014 5:00 44.1 9/26/2014 22:00 1.8 10/3/2014 15:00 1.5 10/11/2014 8:00 88.9

9/23/2014 13:00 1.9 9/25/2014 6:00 34.7 9/26/2014 23:00 3.1 10/3/2014 16:00 1.3 10/11/2014 9:00 38.2

9/23/2014 14:00 9/25/2014 7:00 34 9/30/2014 0:00 0.9 10/3/2014 17:00 1.2 10/11/2014 10:00 5.3

9/23/2014 15:00 3.3 9/25/2014 8:00 35.6 9/30/2014 1:00 1.3 10/3/2014 18:00 1.1 10/11/2014 11:00 4.9

9/23/2014 16:00 2.2 9/25/2014 9:00 23.1 9/30/2014 2:00 4.4 10/3/2014 19:00 1.1 10/11/2014 12:00 5.5

9/23/2014 17:00 2.6 9/25/2014 10:00 8.1 9/30/2014 3:00 52.3 10/3/2014 20:00 1.8 10/11/2014 13:00 5.2

9/23/2014 18:00 2.1 9/25/2014 11:00 4 9/30/2014 4:00 82 10/3/2014 21:00 3.7 10/11/2014 14:00 3.8

9/23/2014 19:00 7.8 9/25/2014 12:00 2.8 9/30/2014 5:00 82.2 10/3/2014 22:00 21.6 10/11/2014 15:00 3.5

9/23/2014 20:00 63.8 9/25/2014 13:00 1.9 9/30/2014 6:00 34.8 10/3/2014 23:00 20.5 10/11/2014 16:00 3.1

9/23/2014 21:00 122.1 9/25/2014 14:00 1.6 9/30/2014 7:00 53.2 10/10/2014 0:00 35.4 10/11/2014 17:00 3

9/23/2014 22:00 85.2 9/25/2014 15:00 2.6 9/30/2014 8:00 62.3 10/10/2014 1:00 31.4 10/11/2014 18:00 5.1

9/23/2014 23:00 60.7 9/25/2014 16:00 1.5 9/30/2014 9:00 54.3 10/10/2014 2:00 26.2 10/11/2014 19:00 12.3

9/24/2014 0:00 91.6 9/25/2014 17:00 1.3 9/30/2014 10:00 31.9 10/10/2014 3:00 24.6 10/11/2014 20:00 15.6

9/24/2014 1:00 116.2 9/25/2014 18:00 1.2 9/30/2014 11:00 10.1 10/10/2014 4:00 42.7 10/11/2014 21:00 19.1

9/24/2014 2:00 86.1 9/25/2014 19:00 3.2 9/30/2014 12:00 4.2 10/10/2014 5:00 68.6 10/11/2014 22:00 22.6

9/24/2014 3:00 113.5 9/25/2014 20:00 55.9 9/30/2014 13:00 2.8 10/10/2014 6:00 80 10/11/2014 23:00 27.5

9/24/2014 4:00 58.9 9/25/2014 21:00 203.8 9/30/2014 14:00 10/10/2014 7:00 92 10/12/2014 0:00 32.8

9/24/2014 5:00 71.1 9/25/2014 22:00 127.1 9/30/2014 15:00 5.9 10/10/2014 8:00 81.1 10/12/2014 1:00 25.8

9/24/2014 6:00 61.2 9/25/2014 23:00 75.2 9/30/2014 16:00 2.6 10/10/2014 9:00 18.7 10/12/2014 2:00 17.9

9/24/2014 7:00 30.7 9/26/2014 0:00 81.1 9/30/2014 17:00 2 10/10/2014 10:00 9.5 10/12/2014 3:00 23.3

9/24/2014 8:00 30.7 9/26/2014 1:00 56.6 9/30/2014 18:00 1.6 10/10/2014 11:00 6.4 10/12/2014 4:00 26.2

9/24/2014 9:00 29.4 9/26/2014 2:00 83.3 9/30/2014 19:00 1.3 10/10/2014 12:00 17.6 10/12/2014 5:00 24.4

9/24/2014 10:00 12.3 9/26/2014 3:00 75 9/30/2014 20:00 1.3 10/10/2014 13:00 14.1 10/12/2014 6:00 35.4

9/24/2014 11:00 7.5 9/26/2014 4:00 17.6 9/30/2014 21:00 1.2 10/10/2014 14:00 61.8 10/12/2014 7:00 46.8

9/24/2014 12:00 5.9 9/26/2014 5:00 29.7 9/30/2014 22:00 2.4 10/10/2014 15:00 49.3 10/12/2014 8:00 50.6

9/24/2014 13:00 3.2 9/26/2014 6:00 43.2 9/30/2014 23:00 7.3 10/10/2014 16:00 113.5 10/12/2014 9:00 42.7

9/24/2014 14:00 9/26/2014 7:00 57 10/3/2014 0:00 18.9 10/10/2014 17:00 109.9 10/12/2014 10:00 28.1

9/24/2014 15:00 9/26/2014 8:00 21 10/3/2014 1:00 31.4 10/10/2014 18:00 140 10/12/2014 11:00 20.2

9/24/2014 16:00 3.8 9/26/2014 9:00 16.2 10/3/2014 2:00 25.2 10/10/2014 19:00 120.9 10/12/2014 12:00 10.3

9/24/2014 17:00 2.7 9/26/2014 10:00 17.2 10/3/2014 3:00 70.1 10/10/2014 20:00 40.1 10/12/2014 13:00 4

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 96
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

10/12/2014 14:00 2.9 10/14/2014 7:00 67.2 10/25/2014 0:00 226.3 10/26/2014 17:00 5.1 10/30/2014 10:00 35

10/12/2014 15:00 2.3 10/14/2014 8:00 252.2 10/25/2014 1:00 115 10/26/2014 18:00 27.1 10/30/2014 11:00 7.3

10/12/2014 16:00 3 10/14/2014 9:00 24.5 10/25/2014 2:00 55.8 10/26/2014 19:00 93.8 10/30/2014 12:00 10.8

10/12/2014 17:00 9.8 10/14/2014 10:00 19.3 10/25/2014 3:00 63.1 10/26/2014 20:00 36.6 10/30/2014 13:00 5.8

10/12/2014 18:00 14 10/14/2014 11:00 7.9 10/25/2014 4:00 77.7 10/26/2014 21:00 72.6 10/30/2014 14:00 5.4

10/12/2014 19:00 93.6 10/14/2014 12:00 3.9 10/25/2014 5:00 46.4 10/26/2014 22:00 84 10/30/2014 15:00 9.1

10/12/2014 20:00 30.1 10/14/2014 13:00 2.9 10/25/2014 6:00 55.8 10/26/2014 23:00 103.6 10/30/2014 16:00 17.4

10/12/2014 21:00 10.7 10/14/2014 14:00 10/25/2014 7:00 49.9 10/29/2014 0:00 28 10/30/2014 17:00 70.2

10/12/2014 22:00 105.2 10/14/2014 15:00 3.4 10/25/2014 8:00 48.9 10/29/2014 1:00 208 10/30/2014 18:00 57.8

10/12/2014 23:00 165.2 10/14/2014 16:00 2.2 10/25/2014 9:00 26.8 10/29/2014 2:00 139.4 10/30/2014 19:00 126.9

10/13/2014 0:00 96.3 10/14/2014 17:00 1.9 10/25/2014 10:00 18.8 10/29/2014 3:00 62.2 10/30/2014 20:00 32.8

10/13/2014 1:00 54.5 10/14/2014 18:00 2.3 10/25/2014 11:00 9.8 10/29/2014 4:00 36.7 10/30/2014 21:00 41.7

10/13/2014 2:00 34.9 10/14/2014 19:00 5 10/25/2014 12:00 7.7 10/29/2014 5:00 50.1 10/30/2014 22:00 13.9

10/13/2014 3:00 34 10/14/2014 20:00 38.9 10/25/2014 13:00 6.4 10/29/2014 6:00 38.8 10/30/2014 23:00 41.7

10/13/2014 4:00 31.2 10/14/2014 21:00 14.1 10/25/2014 14:00 3.5 10/29/2014 7:00 19.2 11/5/2014 0:00 6.6

10/13/2014 5:00 12.4 10/14/2014 22:00 9.5 10/25/2014 15:00 3.4 10/29/2014 8:00 22.1 11/5/2014 1:00 8.9

10/13/2014 6:00 11.9 10/14/2014 23:00 9.5 10/25/2014 16:00 3.2 10/29/2014 9:00 15.9 11/5/2014 2:00 9.3

10/13/2014 7:00 27 10/24/2014 0:00 60.9 10/25/2014 17:00 3 10/29/2014 10:00 11.2 11/5/2014 3:00 13.5

10/13/2014 8:00 18.8 10/24/2014 1:00 64.3 10/25/2014 18:00 3.4 10/29/2014 11:00 11 11/5/2014 4:00 30.4

10/13/2014 9:00 21 10/24/2014 2:00 27.1 10/25/2014 19:00 4.9 10/29/2014 12:00 15.4 11/5/2014 5:00 39.9

10/13/2014 10:00 14.5 10/24/2014 3:00 25 10/25/2014 20:00 10.2 10/29/2014 13:00 14.6 11/5/2014 6:00 149.1

10/13/2014 11:00 6.8 10/24/2014 4:00 22.9 10/25/2014 21:00 21.7 10/29/2014 14:00 9.3 11/5/2014 7:00 92.4

10/13/2014 12:00 3.4 10/24/2014 5:00 12.7 10/25/2014 22:00 41.5 10/29/2014 15:00 5.5 11/5/2014 8:00 47.8

10/13/2014 13:00 2.1 10/24/2014 6:00 14.8 10/25/2014 23:00 39.7 10/29/2014 16:00 111.6 11/5/2014 9:00 18.7

10/13/2014 14:00 2.8 10/24/2014 7:00 42.2 10/26/2014 0:00 25.1 10/29/2014 17:00 380.8 11/5/2014 10:00 22.2

10/13/2014 15:00 10/24/2014 8:00 25.1 10/26/2014 1:00 20 10/29/2014 18:00 207.2 11/5/2014 11:00 12.6

10/13/2014 16:00 52.9 10/24/2014 9:00 20.4 10/26/2014 2:00 24.7 10/29/2014 19:00 98.4 11/5/2014 12:00 19.1

10/13/2014 17:00 179.8 10/24/2014 10:00 12 10/26/2014 3:00 41.1 10/29/2014 20:00 82.5 11/5/2014 13:00 4.6

10/13/2014 18:00 3.7 10/24/2014 11:00 5.2 10/26/2014 4:00 67.6 10/29/2014 21:00 46.1 11/5/2014 14:00 3.3

10/13/2014 19:00 2.4 10/24/2014 12:00 2 10/26/2014 5:00 42.3 10/29/2014 22:00 22.9 11/5/2014 15:00 2.6

10/13/2014 20:00 46.1 10/24/2014 13:00 2.4 10/26/2014 6:00 34.9 10/29/2014 23:00 17.5 11/5/2014 16:00 2.1

10/13/2014 21:00 76.1 10/24/2014 14:00 2.4 10/26/2014 7:00 53.6 10/30/2014 0:00 20.3 11/5/2014 17:00 2

10/13/2014 22:00 92.9 10/24/2014 15:00 2.2 10/26/2014 8:00 46.3 10/30/2014 1:00 35.4 11/5/2014 18:00 1.8

10/13/2014 23:00 148.2 10/24/2014 16:00 2.1 10/26/2014 9:00 25.5 10/30/2014 2:00 31.1 11/5/2014 19:00 2

10/14/2014 0:00 143.1 10/24/2014 17:00 1.9 10/26/2014 10:00 21 10/30/2014 3:00 31.2 11/5/2014 20:00 6.3

10/14/2014 1:00 142 10/24/2014 18:00 1.8 10/26/2014 11:00 11.4 10/30/2014 4:00 37.8 11/5/2014 21:00 7.2

10/14/2014 2:00 106.5 10/24/2014 19:00 3.8 10/26/2014 12:00 12.1 10/30/2014 5:00 26.6 11/5/2014 22:00 7.6

10/14/2014 3:00 89.2 10/24/2014 20:00 6.1 10/26/2014 13:00 10.6 10/30/2014 6:00 22.1 11/5/2014 23:00 9.2

10/14/2014 4:00 69.9 10/24/2014 21:00 9.1 10/26/2014 14:00 8.8 10/30/2014 7:00 33.5 11/11/2014 0:00 15.8

10/14/2014 5:00 38.3 10/24/2014 22:00 132.4 10/26/2014 15:00 7.4 10/30/2014 8:00 79.9 11/11/2014 1:00 26

10/14/2014 6:00 49.3 10/24/2014 23:00 234 10/26/2014 16:00 4 10/30/2014 9:00 65.5 11/11/2014 2:00 22

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 97
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/11/2014 3:00 16.2 11/15/2014 20:00 9.7 11/17/2014 13:00 12.7 11/20/2014 6:00 78.7 11/24/2014 23:00 177.8

11/11/2014 4:00 13.8 11/15/2014 21:00 12.6 11/17/2014 14:00 16.2 11/20/2014 7:00 79.7 11/25/2014 0:00 182.9

11/11/2014 5:00 11.5 11/15/2014 22:00 12.5 11/17/2014 15:00 11/20/2014 8:00 50.9 11/25/2014 1:00 119.8

11/11/2014 6:00 12 11/15/2014 23:00 11.1 11/17/2014 16:00 8.8 11/20/2014 9:00 12.1 11/25/2014 2:00 151.1

11/11/2014 7:00 13.2 11/16/2014 0:00 11.8 11/17/2014 17:00 7.2 11/20/2014 10:00 7.7 11/25/2014 3:00 182.9

11/11/2014 8:00 20.9 11/16/2014 1:00 18 11/17/2014 18:00 7.8 11/20/2014 11:00 21.2 11/25/2014 4:00 145.1

11/11/2014 9:00 55.8 11/16/2014 2:00 21.6 11/17/2014 19:00 7.7 11/20/2014 12:00 8.2 11/25/2014 5:00 147.1

11/11/2014 10:00 78.7 11/16/2014 3:00 49.2 11/17/2014 20:00 10.3 11/20/2014 13:00 5.7 11/25/2014 6:00 225.6

11/11/2014 11:00 76.2 11/16/2014 4:00 70.4 11/17/2014 21:00 23.3 11/20/2014 14:00 4.4 11/25/2014 7:00 197.8

11/11/2014 12:00 11/16/2014 5:00 72.3 11/17/2014 22:00 20.7 11/20/2014 15:00 23.2 11/25/2014 8:00 256.4

11/11/2014 13:00 17.8 11/16/2014 6:00 79.4 11/17/2014 23:00 15.6 11/20/2014 16:00 8.7 11/25/2014 9:00 239.5

11/11/2014 14:00 11/16/2014 7:00 78.9 11/19/2014 0:00 34.6 11/20/2014 17:00 6.7 11/25/2014 10:00 134.4

11/11/2014 15:00 9.4 11/16/2014 8:00 137.9 11/19/2014 1:00 42.5 11/20/2014 18:00 6.8 11/25/2014 11:00 48.3

11/11/2014 16:00 5.5 11/16/2014 9:00 26.4 11/19/2014 2:00 39.2 11/20/2014 19:00 17.9 11/25/2014 12:00 26.4

11/11/2014 17:00 4 11/16/2014 10:00 15.7 11/19/2014 3:00 50.8 11/20/2014 20:00 31.2 11/25/2014 13:00 27.9

11/11/2014 18:00 3.3 11/16/2014 11:00 13.4 11/19/2014 4:00 35.5 11/20/2014 21:00 20.8 11/25/2014 14:00

11/11/2014 19:00 2.9 11/16/2014 12:00 8.4 11/19/2014 5:00 42.7 11/20/2014 22:00 39.2 11/25/2014 15:00 27.2

11/11/2014 20:00 2.7 11/16/2014 13:00 6.5 11/19/2014 6:00 90.6 11/20/2014 23:00 50 11/25/2014 16:00 21.4

11/11/2014 21:00 2.8 11/16/2014 14:00 4.8 11/19/2014 7:00 128.9 11/24/2014 0:00 6.8 11/25/2014 17:00 12.5

11/11/2014 22:00 4.1 11/16/2014 15:00 3.8 11/19/2014 8:00 65.2 11/24/2014 1:00 14.1 11/25/2014 18:00 13.4

11/11/2014 23:00 7 11/16/2014 16:00 2.9 11/19/2014 9:00 11.5 11/24/2014 2:00 12.3 11/25/2014 19:00 14.8

11/15/2014 0:00 16.8 11/16/2014 17:00 2.4 11/19/2014 10:00 11/24/2014 3:00 7.7 11/25/2014 20:00 17.3

11/15/2014 1:00 20.8 11/16/2014 18:00 2.2 11/19/2014 11:00 11/24/2014 4:00 5.4 11/25/2014 21:00 17.3

11/15/2014 2:00 26.7 11/16/2014 19:00 2.1 11/19/2014 12:00 11/24/2014 5:00 5.1 11/25/2014 22:00 16.2

11/15/2014 3:00 20.8 11/16/2014 20:00 2.4 11/19/2014 13:00 11/24/2014 6:00 5.8 11/25/2014 23:00 24.7

11/15/2014 4:00 16.4 11/16/2014 21:00 2.3 11/19/2014 14:00 18.8 11/24/2014 7:00 5.5 11/26/2014 0:00 20

11/15/2014 5:00 13.7 11/16/2014 22:00 2.2 11/19/2014 15:00 18.1 11/24/2014 8:00 5.1 11/26/2014 1:00 33.8

11/15/2014 6:00 14.7 11/16/2014 23:00 2.6 11/19/2014 16:00 7.4 11/24/2014 9:00 4.2 11/26/2014 2:00 31

11/15/2014 7:00 38.2 11/17/2014 0:00 3.8 11/19/2014 17:00 11 11/24/2014 10:00 4.3 11/26/2014 3:00 23

11/15/2014 8:00 50.7 11/17/2014 1:00 5.6 11/19/2014 18:00 23.7 11/24/2014 11:00 4.3 11/26/2014 4:00 48.5

11/15/2014 9:00 29.5 11/17/2014 2:00 6.9 11/19/2014 19:00 21.7 11/24/2014 12:00 3.6 11/26/2014 5:00 39.3

11/15/2014 10:00 23.3 11/17/2014 3:00 9 11/19/2014 20:00 46.5 11/24/2014 13:00 2.5 11/26/2014 6:00 38.3

11/15/2014 11:00 19.2 11/17/2014 4:00 13.8 11/19/2014 21:00 211.7 11/24/2014 14:00 2.4 11/26/2014 7:00 54.1

11/15/2014 12:00 14.6 11/17/2014 5:00 23.9 11/19/2014 22:00 194.5 11/24/2014 15:00 11/26/2014 8:00 84.4

11/15/2014 13:00 16.3 11/17/2014 6:00 18.9 11/19/2014 23:00 104.1 11/24/2014 16:00 3.2 11/26/2014 9:00 59.2

11/15/2014 14:00 21.8 11/17/2014 7:00 11.5 11/20/2014 0:00 26.2 11/24/2014 17:00 2.9 11/26/2014 10:00 32.6

11/15/2014 15:00 7.3 11/17/2014 8:00 33.6 11/20/2014 1:00 9.5 11/24/2014 18:00 2.4 11/26/2014 11:00 30.9

11/15/2014 16:00 111.5 11/17/2014 9:00 55.5 11/20/2014 2:00 36 11/24/2014 19:00 2 11/26/2014 12:00 24.9

11/15/2014 17:00 12.5 11/17/2014 10:00 123.2 11/20/2014 3:00 65.1 11/24/2014 20:00 2.5 11/26/2014 13:00 15.7

11/15/2014 18:00 12 11/17/2014 11:00 73 11/20/2014 4:00 58.5 11/24/2014 21:00 26.5 11/26/2014 14:00 25.5

11/15/2014 19:00 8.3 11/17/2014 12:00 7.6 11/20/2014 5:00 74.8 11/24/2014 22:00 120.3 11/26/2014 15:00 20.8

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 98
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

11/26/2014 16:00 16.6 11/28/2014 9:00 104.5 12/2/2014 2:00 51.7 12/5/2014 19:00 2.3 12/7/2014 12:00 5.8

11/26/2014 17:00 16.1 11/28/2014 10:00 42.3 12/2/2014 3:00 24.5 12/5/2014 20:00 2.4 12/7/2014 13:00 4.5

11/26/2014 18:00 16.8 11/28/2014 11:00 96.4 12/2/2014 4:00 15 12/5/2014 21:00 3.2 12/7/2014 14:00 3.5

11/26/2014 19:00 21.1 11/28/2014 12:00 74.4 12/2/2014 5:00 14.6 12/5/2014 22:00 3.5 12/7/2014 15:00 3

11/26/2014 20:00 17.7 11/28/2014 13:00 15.2 12/2/2014 6:00 14.8 12/5/2014 23:00 4.4 12/7/2014 16:00 2.7

11/26/2014 21:00 13.1 11/28/2014 14:00 15.4 12/2/2014 7:00 14.9 12/6/2014 0:00 4.6 12/7/2014 17:00 2.8

11/26/2014 22:00 5 11/28/2014 15:00 20.6 12/2/2014 8:00 32.3 12/6/2014 1:00 11.4 12/7/2014 18:00 2.7

11/26/2014 23:00 5.2 11/28/2014 16:00 28.6 12/2/2014 9:00 69.5 12/6/2014 2:00 36.7 12/7/2014 19:00 3

11/27/2014 0:00 10.9 11/28/2014 17:00 25 12/2/2014 10:00 105.9 12/6/2014 3:00 43.7 12/7/2014 20:00 6.5

11/27/2014 1:00 13.9 11/28/2014 18:00 37.7 12/2/2014 11:00 36.3 12/6/2014 4:00 85.1 12/7/2014 21:00 176.5

11/27/2014 2:00 22 11/28/2014 19:00 37.8 12/2/2014 12:00 12.4 12/6/2014 5:00 99.9 12/7/2014 22:00 391.8

11/27/2014 3:00 29.3 11/28/2014 20:00 14.4 12/2/2014 13:00 8.1 12/6/2014 6:00 79.1 12/7/2014 23:00 252.5

11/27/2014 4:00 39.1 11/28/2014 21:00 20.1 12/2/2014 14:00 12/6/2014 7:00 48.7 12/8/2014 0:00 98.9

11/27/2014 5:00 40 11/28/2014 22:00 72.6 12/2/2014 15:00 11.9 12/6/2014 8:00 28.5 12/8/2014 1:00 58.5

11/27/2014 6:00 49.9 11/28/2014 23:00 56.9 12/2/2014 16:00 9.4 12/6/2014 9:00 50.1 12/8/2014 2:00 44.9

11/27/2014 7:00 48.3 12/1/2014 0:00 30.5 12/2/2014 17:00 5.9 12/6/2014 10:00 24.5 12/8/2014 3:00 55.8

11/27/2014 8:00 47.4 12/1/2014 1:00 38.8 12/2/2014 18:00 9 12/6/2014 11:00 11.8 12/8/2014 4:00 42.2

11/27/2014 9:00 52.3 12/1/2014 2:00 33.2 12/2/2014 19:00 13.2 12/6/2014 12:00 10.4 12/8/2014 5:00 25

11/27/2014 10:00 16.2 12/1/2014 3:00 30.9 12/2/2014 20:00 30.9 12/6/2014 13:00 5.5 12/8/2014 6:00 13.1

11/27/2014 11:00 3.1 12/1/2014 4:00 38.9 12/2/2014 21:00 105.5 12/6/2014 14:00 3.8 12/8/2014 7:00 15.9

11/27/2014 12:00 2.4 12/1/2014 5:00 30.6 12/2/2014 22:00 99.2 12/6/2014 15:00 3.3 12/8/2014 8:00 8.1

11/27/2014 13:00 2.9 12/1/2014 6:00 32.5 12/2/2014 23:00 66 12/6/2014 16:00 2.9 12/8/2014 9:00 24.9

11/27/2014 14:00 7.8 12/1/2014 7:00 29.9 12/5/2014 0:00 27.2 12/6/2014 17:00 2.9 12/8/2014 10:00 31.2

11/27/2014 15:00 537.7 12/1/2014 8:00 44.4 12/5/2014 1:00 30.8 12/6/2014 18:00 6 12/8/2014 11:00 5.4

11/27/2014 16:00 128.1 12/1/2014 9:00 53.2 12/5/2014 2:00 42.1 12/6/2014 19:00 5.3 12/8/2014 12:00 3.6

11/27/2014 17:00 5 12/1/2014 10:00 58.4 12/5/2014 3:00 29.6 12/6/2014 20:00 8.9 12/8/2014 13:00 3.2

11/27/2014 18:00 4.5 12/1/2014 11:00 28.4 12/5/2014 4:00 51.8 12/6/2014 21:00 12.8 12/8/2014 14:00 3.1

11/27/2014 19:00 8.4 12/1/2014 12:00 18.4 12/5/2014 5:00 72.6 12/6/2014 22:00 11.3 12/8/2014 15:00

11/27/2014 20:00 8.5 12/1/2014 13:00 17.3 12/5/2014 6:00 69.3 12/6/2014 23:00 10.4 12/8/2014 16:00 2.2

11/27/2014 21:00 5.7 12/1/2014 14:00 18.5 12/5/2014 7:00 82.5 12/7/2014 0:00 8.5 12/8/2014 17:00 2.5

11/27/2014 22:00 5.3 12/1/2014 15:00 12/5/2014 8:00 65.8 12/7/2014 1:00 9.1 12/8/2014 18:00 2.7

11/27/2014 23:00 3 12/1/2014 16:00 14.8 12/5/2014 9:00 48.6 12/7/2014 2:00 8.1 12/8/2014 19:00 2.5

11/28/2014 0:00 2.3 12/1/2014 17:00 14 12/5/2014 10:00 19.5 12/7/2014 3:00 6.2 12/8/2014 20:00 2.4

11/28/2014 1:00 2.3 12/1/2014 18:00 16 12/5/2014 11:00 8.5 12/7/2014 4:00 14.8 12/8/2014 21:00 2.3

11/28/2014 2:00 2.2 12/1/2014 19:00 13.7 12/5/2014 12:00 5.6 12/7/2014 5:00 64.2 12/8/2014 22:00 2.7

11/28/2014 3:00 2.1 12/1/2014 20:00 23.3 12/5/2014 13:00 4.2 12/7/2014 6:00 162.4 12/8/2014 23:00 2.9

11/28/2014 4:00 2 12/1/2014 21:00 47 12/5/2014 14:00 3.6 12/7/2014 7:00 214.3 12/10/2014 0:00 25

11/28/2014 5:00 4.7 12/1/2014 22:00 77.4 12/5/2014 15:00 2.9 12/7/2014 8:00 149.3 12/10/2014 1:00 40.6

11/28/2014 6:00 4 12/1/2014 23:00 47 12/5/2014 16:00 2.8 12/7/2014 9:00 79.6 12/10/2014 2:00 29

11/28/2014 7:00 2.8 12/2/2014 0:00 41.4 12/5/2014 17:00 2.5 12/7/2014 10:00 47.9 12/10/2014 3:00 19.4

11/28/2014 8:00 108 12/2/2014 1:00 37 12/5/2014 18:00 2.3 12/7/2014 11:00 15.5 12/10/2014 4:00 22.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 99
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/10/2014 5:00 33.7 12/11/2014 22:00 14.7 12/17/2014 15:00 3.1 12/19/2014 8:00 33.8 12/21/2014 1:00 41.1

12/10/2014 6:00 72.2 12/11/2014 23:00 17 12/17/2014 16:00 3.1 12/19/2014 9:00 84.3 12/21/2014 2:00 127.2

12/10/2014 7:00 80.6 12/14/2014 0:00 108.3 12/17/2014 17:00 4.7 12/19/2014 10:00 21.2 12/21/2014 3:00 239.1

12/10/2014 8:00 66.4 12/14/2014 1:00 133.1 12/17/2014 18:00 14.3 12/19/2014 11:00 11.1 12/21/2014 4:00 170.5

12/10/2014 9:00 48.8 12/14/2014 2:00 102.2 12/17/2014 19:00 26.6 12/19/2014 12:00 8.6 12/21/2014 5:00 106.4

12/10/2014 10:00 56.6 12/14/2014 3:00 96.9 12/17/2014 20:00 18.4 12/19/2014 13:00 4.9 12/21/2014 6:00 46.7

12/10/2014 11:00 35.5 12/14/2014 4:00 84 12/17/2014 21:00 12 12/19/2014 14:00 3.8 12/21/2014 7:00 15.2

12/10/2014 12:00 17.4 12/14/2014 5:00 60.9 12/17/2014 22:00 11.5 12/19/2014 15:00 3.5 12/21/2014 8:00 69.1

12/10/2014 13:00 8.2 12/14/2014 6:00 43 12/17/2014 23:00 8.5 12/19/2014 16:00 3.4 12/21/2014 9:00 50.2

12/10/2014 14:00 7.5 12/14/2014 7:00 49.1 12/18/2014 0:00 13.4 12/19/2014 17:00 2.8 12/21/2014 10:00 41.4

12/10/2014 15:00 6.1 12/14/2014 8:00 101.1 12/18/2014 1:00 16.1 12/19/2014 18:00 2.7 12/21/2014 11:00 9.9

12/10/2014 16:00 6.1 12/14/2014 9:00 255.9 12/18/2014 2:00 14.4 12/19/2014 19:00 3.5 12/21/2014 12:00 5.5

12/10/2014 17:00 5.3 12/14/2014 10:00 203.5 12/18/2014 3:00 29.1 12/19/2014 20:00 3.8 12/21/2014 13:00 4.3

12/10/2014 18:00 5.7 12/14/2014 11:00 195.9 12/18/2014 4:00 81.1 12/19/2014 21:00 8.6 12/21/2014 14:00 3.3

12/10/2014 19:00 6.4 12/14/2014 12:00 25.9 12/18/2014 5:00 76.7 12/19/2014 22:00 22.2 12/21/2014 15:00 2.9

12/10/2014 20:00 5.7 12/14/2014 13:00 22.4 12/18/2014 6:00 147.3 12/19/2014 23:00 48.7 12/21/2014 16:00 2.8

12/10/2014 21:00 7.3 12/14/2014 14:00 33.4 12/18/2014 7:00 126.7 12/20/2014 0:00 154.5 12/21/2014 17:00 2.5

12/10/2014 22:00 11.3 12/14/2014 15:00 33 12/18/2014 8:00 61 12/20/2014 1:00 290.9 12/21/2014 18:00 2.5

12/10/2014 23:00 44.8 12/14/2014 16:00 85.9 12/18/2014 9:00 22.6 12/20/2014 2:00 317.8 12/21/2014 19:00 2.6

12/11/2014 0:00 154.3 12/14/2014 17:00 180.5 12/18/2014 10:00 6.7 12/20/2014 3:00 113.7 12/21/2014 20:00 2.6

12/11/2014 1:00 212.9 12/14/2014 18:00 41 12/18/2014 11:00 6.3 12/20/2014 4:00 88.9 12/21/2014 21:00 3.1

12/11/2014 2:00 208.5 12/14/2014 19:00 36.4 12/18/2014 12:00 9.7 12/20/2014 5:00 107.4 12/21/2014 22:00 7

12/11/2014 3:00 168.1 12/14/2014 20:00 31.9 12/18/2014 13:00 10.8 12/20/2014 6:00 73.9 12/21/2014 23:00 16.7

12/11/2014 4:00 125.6 12/14/2014 21:00 39.5 12/18/2014 14:00 8.6 12/20/2014 7:00 62.9 12/22/2014 0:00 27.6

12/11/2014 5:00 122 12/14/2014 22:00 100.7 12/18/2014 15:00 12.6 12/20/2014 8:00 23.5 12/22/2014 1:00 32.6

12/11/2014 6:00 131.3 12/14/2014 23:00 62.8 12/18/2014 16:00 10.2 12/20/2014 9:00 10.2 12/22/2014 2:00 23.5

12/11/2014 7:00 94.6 12/17/2014 0:00 19.8 12/18/2014 17:00 6.6 12/20/2014 10:00 10.9 12/22/2014 3:00 16.4

12/11/2014 8:00 88.3 12/17/2014 1:00 58.8 12/18/2014 18:00 17.2 12/20/2014 11:00 10.9 12/22/2014 4:00 15.2

12/11/2014 9:00 33.6 12/17/2014 2:00 121.6 12/18/2014 19:00 16.3 12/20/2014 12:00 5.7 12/22/2014 5:00 12.7

12/11/2014 10:00 17.8 12/17/2014 3:00 116.7 12/18/2014 20:00 11.8 12/20/2014 13:00 5.4 12/22/2014 6:00 25.8

12/11/2014 11:00 8.8 12/17/2014 4:00 57.3 12/18/2014 21:00 16.5 12/20/2014 14:00 3.8 12/22/2014 7:00 16.8

12/11/2014 12:00 5.1 12/17/2014 5:00 39.6 12/18/2014 22:00 22.8 12/20/2014 15:00 2.7 12/22/2014 8:00 27.5

12/11/2014 13:00 3.9 12/17/2014 6:00 122.8 12/18/2014 23:00 39.5 12/20/2014 16:00 2.3 12/22/2014 9:00 89.3

12/11/2014 14:00 3.5 12/17/2014 7:00 82.4 12/19/2014 0:00 47.1 12/20/2014 17:00 2.4 12/22/2014 10:00 36.9

12/11/2014 15:00 4.8 12/17/2014 8:00 32 12/19/2014 1:00 56 12/20/2014 18:00 2.5 12/22/2014 11:00 11.7

12/11/2014 16:00 4 12/17/2014 9:00 20.4 12/19/2014 2:00 35.8 12/20/2014 19:00 11.7 12/22/2014 12:00 11.8

12/11/2014 17:00 13.8 12/17/2014 10:00 10.6 12/19/2014 3:00 60.2 12/20/2014 20:00 63.6 12/22/2014 13:00 5.6

12/11/2014 18:00 16.4 12/17/2014 11:00 11.8 12/19/2014 4:00 57 12/20/2014 21:00 39.6 12/22/2014 14:00 3.4

12/11/2014 19:00 11.9 12/17/2014 12:00 8.4 12/19/2014 5:00 30 12/20/2014 22:00 45.5 12/22/2014 15:00

12/11/2014 20:00 10.4 12/17/2014 13:00 5.2 12/19/2014 6:00 22.6 12/20/2014 23:00 79.5 12/22/2014 16:00 2.9

12/11/2014 21:00 13.3 12/17/2014 14:00 3.6 12/19/2014 7:00 40.6 12/21/2014 0:00 46.7 12/22/2014 17:00 2.7

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 100
Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb Day Start Hr ppb

12/22/2014 18:00 2.4 12/27/2014 11:00 20.8 12/31/2014 4:00 13.3

12/22/2014 19:00 2.3 12/27/2014 12:00 16.5 12/31/2014 5:00 24.1

12/22/2014 20:00 2.4 12/27/2014 13:00 14.4 12/31/2014 6:00 143.1

12/22/2014 21:00 6.7 12/27/2014 14:00 10.6 12/31/2014 7:00 168.6

12/22/2014 22:00 14.1 12/27/2014 15:00 8.3 12/31/2014 8:00 93.7

12/22/2014 23:00 13 12/27/2014 16:00 4.5 12/31/2014 9:00 17.2

12/26/2014 0:00 74.7 12/27/2014 17:00 4 12/31/2014 10:00 12.3

12/26/2014 1:00 124.8 12/27/2014 18:00 3.6 12/31/2014 11:00 7.4

12/26/2014 2:00 241 12/27/2014 19:00 4 12/31/2014 12:00 5.3

12/26/2014 3:00 225.1 12/27/2014 20:00 6.3 12/31/2014 13:00 3.9

12/26/2014 4:00 138.1 12/27/2014 21:00 8.7 12/31/2014 14:00 3.5

12/26/2014 5:00 90.1 12/27/2014 22:00 11.8 12/31/2014 15:00 3

12/26/2014 6:00 114.7 12/27/2014 23:00 12.2 12/31/2014 16:00 2.8

12/26/2014 7:00 114.8 12/29/2014 0:00 9.3 12/31/2014 17:00 2.5

12/26/2014 8:00 80.4 12/29/2014 1:00 11.5 12/31/2014 18:00 2.4

12/26/2014 9:00 36 12/29/2014 2:00 11.8 12/31/2014 19:00 2.3

12/26/2014 10:00 33.8 12/29/2014 3:00 15.6 12/31/2014 20:00 2.3

12/26/2014 11:00 31 12/29/2014 4:00 19.5 12/31/2014 21:00 2.1

12/26/2014 12:00 18.7 12/29/2014 5:00 21.5 12/31/2014 22:00 2

12/26/2014 13:00 11.5 12/29/2014 6:00 27.9 12/31/2014 23:00 2

12/26/2014 14:00 7.3 12/29/2014 7:00 30.5

12/26/2014 15:00 4.9 12/29/2014 8:00 27.2

12/26/2014 16:00 4.4 12/29/2014 9:00 76.3

12/26/2014 17:00 4.5 12/29/2014 10:00 125.4

12/26/2014 18:00 4.9 12/29/2014 11:00 149.5

12/26/2014 19:00 4.7 12/29/2014 12:00 11.4

12/26/2014 20:00 6.6 12/29/2014 13:00 5.5

12/26/2014 21:00 11.9 12/29/2014 14:00 4

12/26/2014 22:00 13.8 12/29/2014 15:00

12/26/2014 23:00 14.5 12/29/2014 16:00 3.3

12/27/2014 0:00 49.7 12/29/2014 17:00 3.2

12/27/2014 1:00 73.3 12/29/2014 18:00 3

12/27/2014 2:00 58.7 12/29/2014 19:00 2.7

12/27/2014 3:00 78.2 12/29/2014 20:00 2.4

12/27/2014 4:00 64.5 12/29/2014 21:00 2.3

12/27/2014 5:00 36.1 12/29/2014 22:00 7.7

12/27/2014 6:00 31.1 12/29/2014 23:00 12.5

12/27/2014 7:00 27.6 12/31/2014 0:00 1.8

12/27/2014 8:00 25.6 12/31/2014 1:00 1.7

12/27/2014 9:00 35 12/31/2014 2:00 1.7

12/27/2014 10:00 29.3 12/31/2014 3:00 1.6

Hours Exceeding the 1-hour SO2 NAAQS for EPA Concurrence

(Hours ≥ 75.5 ppb)

Station: Pahala AQS ID: 150012016

Appendix D 101