STATEOFARIZONASTATEIMPLEMENTATIONPLAN(SIP)REVISIONAPPENDIX11990RULE-MAKINGCOMPRISEDOFARTICLES5AND6JULY15,1998STATEOFARIZONASIPREVISION.JULY15,1998ARTICLE5.EXISTINGSTATIONARYt’OINTSOURCEPERFORMANCESTANDARDSR18-2-501.DefinitionsForpurposesofthisArticle:1.“Acidmist”meanssulfuricacidmistasmeasuredintheArizonaTestingManualand40CFR60,ApnendixA.“Architecturalcoating”meansacoatingusedcommerciallyorindustriallyforresidential,commercialorindustrialbuildingsandtheirappurtenances:structuralsteel:andotherfabricationssuchasstoraaetanks,bridges,beamsandgirders.“Asnhaltconcreteplant”meansanyfacilityusedtomanufactureasnhaltconcretebyheatinganddryingagreateandmixingwithasphaltcements.Thisislimitedtofacilities,includingdrumdryerplantsthatintroduceasphaltintothedryer,whichemploytwoormoreofthefollowingprocesses:a.Adryer.b.Systemsforscreening,handling,storing,andweighinghotaggregate.c.Systemsforloading,transferring,andstoringmineralfiller,Systemsformixingasphaltconcrete.e.Theloading,transferring,andstoragesystemsassociatedwithemissioncontrolsystems.4.“Blackljuor”meanswasteliquorfromthebrownstockwasherandspentcookingliquorwhichhavebeenconcentratedinthemultiple-effectevaporatorsystem.1

# “Calcine” means the solid materials oroduced by a. lime plant.

“Concentrate” means enriched copoer ore recovered from the froth

flotation process.

7. “Concentrate dryer” means any facility in which a coooer sulfide

ore concentrate chare is heated in the oresence of air to eliminate a oortipn

of the moisture from the charge, provided less than five oercent of the sulfur

contained in the charge is eliminated in the facility.

“Concentrate roaster” means any facility in which a couper sulfide

ore concentrate is heated in the oresence of air to eliminate five percent or

more of the sulfur contained in the charge.

9. “Condensate strinoer system” means a column, arid associated

condensers, used to strio, with air or steam. TRS comourids from condensate

streams of various orocesses within a kraft pulp mill.

10. “Control device” means the air pollution control ecruioment used to

remove particulate matter or cases generated by p orocess source from the

effluent gas stream. “Converter” means any vessel to which copoer matte is charged and

oxidized to copper.

12. “Facility” means an identifiable piece of stationary process

eo-uiment along with all associated air pollution eauipment.

13. “Fugitive dust” means fugitive emissions of particulate matter.

14. “High sulfur oil” means fuel oil containing 0.90 percent or more

by weight of sulfur. “Lime kiln” .means a unit used to calcinate lime rock or kraft pulp

mill lime mud which consists primarily of calcium carbonate, into cuicklime,

which is calcium oxide. 2“Lowsulfuroil”meansfuelci].containinglessthan0.90percentbyweightofsulfur.“Matte”meansametallicsulfidemadebysmeltingcoppersulfideoreconcentrateortheroastedproductofcoppersulfideores.18.“Miscellaneousmetalpartsandproducts”forpurposesofindustrialcoatingincludeallofthefollowing:a.Largefarmmahirierv,suchasharvesting,fertilizingandplantingmachines.tractors,andcombines.b.Smallfarmmachinery,suchaslawnandgardentractors,lawnmowers,andrototillers.c.Smallaopliances.suchasfans.mixers,blenders,crockpots.dehumidifiers,andvacuumcleaners.jCommercialmachinery,suchasofficeeauipment.computersandauxiliaryeauiwment,typewriters,calculators,andvendingmachines.e.Industrialmachinery,suchaspumps,compressors.conveyorcomponents,fans,blowers,andtransformers.f.Fabricatedmetalproducts,suchasmetalcoverddoorsandframes.gnyotherindustrialcategorywhichcoatsmetalpartsorproductsundertheCodeinthe“StandardIndustrialClassificationManual,1987”ofMalorGroup33(primarymetalindustries),Ma-forGroup34(fabricatedmetalproducts),MaiorGroup35(non-electricmachinery),Ma’iorGroup36(electricalmachinery).MaiorGroup37(transportationequipment).MaiorGroup38(miscellaneousinstruments),andMa-iorGroup39(miscellaneousmanufacturingindustries),exceotallofthefollowing:1.Automobilesandlight-dutytrucks.ii.Metalcans.3

# iii. Flat metal sheets and stris in the form of rolls or coils.

jy Magnet wire for use in electrical machinery.

v. Metal furniture.

vi. Large appliances.

vii. Exterior of airtlaries.

viii. Automobile refinishing.

j. Customized top coating of automobiles and trucks. if production is

less than 35 vehicles erday.



# x. Exterior of marine vessels.

19. “Multiple-effect evaporator system” means the multiple-effect

evaporators and associated condenser and hotwell used to concentrate the spent

cooking liquid that is separated from the pulp.

20. “Neutral sulfite semichemical pulping” means any operation in

which pulp is produced from wood by cooking or digesting wood chips in a

solution of sodium sulfite and sodium bicarbonate, followed by mechanical

defibrating or grinding,

ZL.. “Petroleum liquids” means petroleum, condensate, and any finished

or intermediate products manufactured in a petroleum refinery, but does not

mean Number 2 through Number 6 fuel oils as specified in ASTM D-396-86, gas

turbine fuel oils Numbers 2-GT through 4-GT as specified in ASTM D-2880-87. or

diesel fuel oils Numbers 2-D and 4-D as specified in ASTM D-975-81.

“Process source” means the last operation or process which

produces an air contaminant resulting from either:

a. The separation of the air contaminants from the process material,

or The conversion of constituents of the process materials into air

4

# contaminants which is not an air pollution abatement operation.

2.L “Process weight” means the total weight of all materials

introduced into a process source, including fuels, where these contribute to

pollution generated by the process.

24. “Process weight rate” means a rate established Dursuant to Rl8-2-

502.E. j,. “Recovery furnace” means the unit, including the direct-contact

evaporator for a conventional furnace, used for burning black liquor to

recover chemicals consisting primarily of sodium carbonate and sodium sulfide.

2i.. “Reid vapor pressure”means the absolute vaoor oressure of

volatile crude oil and volatile non-viscous petroleum liquids, exceptV



# liguified tetroleum gases. as determined by ASTM D-323-82.

ZL. “Reverberatory smelting furnace” means any vessel in which the

smelting of copøer sulfide oreconcentrates 

# or calcines is performed and in

which the heat necessary for smelting is trovided Drimarily by combustion of a

fossil fuel. “Rotary lime kiln” means a unit with an included rotary drum which

is used to Droduce p lime iroduct from limestone by calcination.

29. “Slag” means the fused and vitrified matter separated during the

reduction of a metal from its ore.

Q.,.. “Smelt dissolving tank” means a vessel used for dissolving the

smelt collected from the kraft mill recovery furnace.V



# “Smelter feed” means all materials utilized in the operation of a

copper smelter including metals or concentrates. fuels and chemical reagents,

calculated as the aggregate sulfur content of all fuels and other feed

materials whose products of combustion and gaseous by-products are emitted to

5theatmosphere.2“Smelting”meansprocessingtechniquesforthesmeltingofacoppersulfideoreconcentrateorcalcinechargeleadingtotheformationofseparatelayersofmoltenslag.moltencopper.orcoptermatte.3“Smeltingfurnace”meansanyvesselinwhichthesmeltingofcoppersulfideoreconcentratesorcalcinesisperformedandinwhichtheheatnecessaryforsmeltingisprovidedbyanelectriccurrent,rapidoxidationofaportionofthesulfurcontainedintheconcentrateasitpassesthroughanoxidizingatmosphere.orthecombustionofafossilfuel.“Standardconditions”meansatemperatureof293K(68°For20°C)andapressureof101.3kiloascals(29.92indhesHor10l3.25mb).3j..“Supplementarycontrolsystem”(SCS)meansasystembywhichsulfurdioxideemissionsarecurtailedduringperiodswhenmeteorologicalconditionsconducivetoground-levelconcentrationsinexcessofambientairqualitystandardsforsulfurdioxideeitherexistorareanticipated.36.“Vaporpressure”meansthepressureexertedbythegaseousformofasubstanceineciuilibriumwithitsliquidorsolidform.Rl82501R18-2-502.Vioibloomioaiono;generplGeneralprovisionsA.Theprovisionsofthi&Articleshallonlyapplytoexistingsources.Exceptasotherwiseprovidedinthccflulc3thisArticlerelatingtospecifictypesofsources,theopacityofanyplumeoreffluentsoh11Shallnotbegreaterthan40percent.andDShallbedeterminedbyreferenceMethod9inthAri2onTc3tingManuni40CFR60.AppendixA.Wherethepresenceofuncombinedwateristheonlyreasonforthe6

# exceedance of any visible emissions requirement in theac flulca this Article,

such exceedance shall not constitute a violation of thece flulec.

C. Upon written application to the Director, a pcrcon owning or

operating an air pollution cource may requcet that a vicible emiociono

evaluation be conducted by the Dureau during a part3mi]n mi

emon3trating compliance with a particulate emiocion uiuuu.-—- 

# The vioibl...

cmicciono opacity during a particulate emiocion tcn

phall, if greater than the opacity citandard of ubciection, 

# ovc, uiia cr

notice and opportunity for public hearing in accordance with 40 CFR 51.4,

perve aci the viciiblp cmiciciionci otandad for the ciource. Such vieible cmiciciiona

standard cihall be incorporated aci a condition of the operating permit for the -m r

A person owning or operating an air pollution source may ask the

Director for a determination on meeting the reo-uirements of the applicable

opacity standard. The owner or operator shall submit the written reports of the

results of the performance tests, the opacity observation results, and

observer certification.

Z If the Director finds that the facility is in compliance with all

applicable standards for the performance test and still fails to meet the

applicable opacity standard. he shall notify the owner or operator of the

finding. :

3. The owner or operator may petition the Director within ten days of

receipt of notification, asking the Director to make an aropriate

ad-iustment to the oDacity standard for the facility.

4. The Director shall grant the petition after public notice and

7

# oportunitv for public hearing takes place. and upon a demonstration by the

owner or operator that:

a. The affected facility and the associated air Dollution control

equitnnent were operated and maintained in a manner to minimize the oDacity of

emissions during the oerformance test.

The performance tests were performed under the conditions

established by the Director.

c. The affected facility and associated air pollution control

equipment were incapable of being adjusted or ooerated to meet the applicable

opacity rea-uirement.

j The Director shall establish an dpacity standard for the affected

facility based on the determination made in Pararaoh 4. of this Subsection.

The ot,acity standard shall be set at a level indicated by the Derformance and

opacity tests, i,roviding that the source will be able to meet the mass or

concentration standard and the opacity standard at all times. Such oDacity

standard shall be incorporated as a condition of the perating oermit for the

affected facility. The Director shall publish the opacity standard once in one or

more newspaoers of general circulation in the county or counties concerned.

D. Application of A. and D. of this Dcction shall be taycd only with

regard to existing copper smelters until the compliance date specified in fl18

2 515, in a nonfcrroua smelter order, a consent rr or in a delayed

compliance order. The process weight rate utilized in this Article shall be

determined as follows:

1. For continuous or long run, steady-state process sources, the

8

# 11

manure ohall be procescod, stored, uced and tranoported in ouch a manner and

by ouch meano that they will not unreaconably cvaporatc, leak, eccape or be

otherwioe diochargod into the ambient air oo ao to cauoc or contribute to air

pollution; and whcre meanc are available to reduce effectively the

contribution to air pollution from evaporation, leakage or dicaharge, the

inatallation and uce of ouch control methodo, dovicco, or equipment ohall be

mandatory.. 

# Whore a otack, vent or other outlet ic at ouch a level that fumeo,

gao miot, odor, omoko, vapor or any combination thereof conotituting air

pollution arc diocharged to adjoining property, the Director may require the

inotallation of abatement equipment or the alteration of ouch otack, vent or

other outlet by the oar or operator thereof to a degree that will adequately

dilute, reduce or eliminate the diochargc of air pollution to adjoining

property. 1’.. No percon ohall allow hydrogen oulfide to be emitted from any

location in ouch manner and amount that the concentration of ouch emiocions

into the ambient air at any occupied place beyond the prcmiseo on which the

oource ic located encoedo 0.03 parto per million by volume for any averaging

period of 20 minutee of more.

0. No peroon ohall cauce, cuff or, allow or permit diochargo from any

otationary oourcc carbon monocidc cmiooiono without the uce of complete

secondary combuotion of waotc geoco generated by any proccoc cource.

II. No peroon ohall allow hydrogen cyanide to be emitted from any

location in such manner and amount that the concentration of ouch—omirioions

into the ambient air at any occupied place beyond thd prcmioeo on which the

oourcc ic located ewcocdo 0.3 parto per million by volume for any averaging :c’

# EE EEC.AllVOCemissiena£emsolventwashingsshallbeconsideredintheemissionlimitationsinthisubscetion,unlessthesolventisdirectedintocontainerscnatnrrvcntevaporationintocnoatmoopncrc.R18-2-503.Standardsofperformanceforexistingfossil-fuelfiredsteamgeneratorsandgeneralfuelburningequipmentA.ThisSectionappliestothefollowing:installationsInstallationsinwhichfuelisburnedfortheprimarypurposeofproducingpower,steam,hotwater,hotairorotherliquids,gasesorsolidsandinthecourseofdoingsotheproductsofcombustiondonotcomeintodirectcontactwithprocessmaterials.Whenanyproductsorby-productsofamanufacturingprocessareburnedforthesamepurposeorinconjunctionwithanyfuel,thesamemaximumemissionlimitationshallapply,exceptforwoodwasteburnersasregulatedunderCectionRl8-2-504.2.Allfossil-fuelfiredsteamgeneratingunitsorgeneralfuelburningecruiDmentwhicharecrreaterthanorecrualto73megawattscaoacity.B.ForpurposesofthisSection,theheatinputshallbetheaggregateheatcontentofallfuelswhoseproductsofcombustionpassthroughastackorotheroutlet.TheheatcontentofsolidfuelshallbedeterminedinaccordancewithRl8-2-3l0.Compliancetestsshallbeconductedduringoperationatthenominalratedcapacityofeachunit.Thctotalheatinputofallfuelburningunitsonaplantorpremiseshallbeusedfordeterminingthemaicimumamountofgaseousoruarticulatemattcrwhichemitted.—l_,—13

# ccisting sources or for which construction, reconstruction or major alteration

has commenced prior to the affective date of this Cection, which arc greater

1. The standard for particulate matter under this Lection is:

No person shall cause, suffer, allow or permit the emission of

particulate matter, caused by combustion of fuel, from any fuel buruing

operation subject to the provisions on in excess of the amounts

calculated by one of the following equations presented below:

For equipment having a heat input rate of 4200 million Btu per

hour or less, the maximum allowable emissions shall be determined by the

following equation:

where: hour. E= 

# l.02Q° 769

E the maximum allowable particulate emissions rate in pounds-mass per

Q= 

# the heat input in million Btu per hour.

For equipment having a heat input rate greater than 4200

million Btu/hr, the maximum allowable emissions shall be determined by the

following equation: E= 

# 17.OQ° 432

where “E” and “Q” have the same meaning as in

1. of this Subsection. Paragraph

For reference purposes only, the two equations in C.l.a. above

Subsection C. of this Section are plotted in Appendix 11, Figure 1. The

emission values obtained from the graph are approximately correct for the heat

input rates shown. However, the actual values shall be calculated from the

_.c—



# 14

# applicable equations and rounded off to two decimal places.--. 

# Except a provided in C.3. below, the atandard for u1fur dioxide

on ic When low sulfur oil is fired:

Existing fuel burning equipment or steam power generating

installations which commenced construction or a major alteration prior to May

30, 1972 shall not emit more than 1.0 pounds sulfur dioxide maximum three hour

average, per million Btu (430 nanograms per joule) heat input when low culfur

oil ic fired. Existing fuel burning equipment or steam power generating

installations which commenced construction or a major alteration after May 30,

1972 shall not emit more than 0.80 pounds of sulfur dioxide maximum three hour

average per million Btu (340 nanograms per joule) heat input when low oulfur

oil ic fired.

e-- F. When high sulfur oil is fired A j.j existing steam power

generating and general fuel burning installations which are subject to the

provisions of this Section shall not emit more than 2.2 pounds of sulfur

dioxide maximum three-hour average per million Btu (946 nanograms per joule)

heat input when high culfur oil ic fired.

When solid fuel is fired:

Existing general fuel burning equipment and steam power generating

installations which commenced construction or a major alteration prior to May

30, 1972 shall not emit more than 1.0 pounds of sulfur dioxide maximum three :

hour average, per million Btu (430 nanograms per joule) heat input when solid

fuel ic fired.. 

# Existing general fuel burning equipment and steam power generating

installations which commenced construction or major alteration after May 30,

151972shallnotemitmorethan0.80pounds,maximumthree-houraverage,permillionBtu(340nanogramsperjoule)heatinputwhcnsolidfuilisfircd.--..nypermitissuedfortheoperationofanexistingsource,oranyrenewalormodificationofsucha.permit,shallincludeaconditionprohibitingtheuseofhighsulfuroilbythepermittee,unlesstheapplicantdemonstratestothesatisfactionoftheDirectorthatsufficientquantitiesoflowsulfuroilarenot.availableforusebythesourceTandthatithasadequatefacilitiesandcontingencyplanstoinsurethatthesulfurdioxideambientairqualitystandardssetforthinCcctionRl8-2-202Twillnotbeviolated.Thetermsofthepermitmayauthorizetheuseofhighsulfuroilundersuchconditionsasarejustified.IncaseswherethepermitteeisauthorizedtousehighsulfuroilitshallsubmittotheDepartmentmonthlyreportsdetailingitseffortstoobtainlowsulfuroil.Whentheconditionsjustifyingtheuseofhighsulfuroilnolongerexiste,thepermitshallbemodifiedaccordingly.j..NothinginthisSectionshallbeconstruedasallowingtheuseofasupplementarycontrolsystemorotherformofdispersiontechnology.g.Forpurposesofthisflulelowsulfuroilmoonsfucloilcontaining1osthan0.0pcrccntbyweightofsulfurandhighsulfuroilmoansfueloilcontaining0.00pcrccntormorcbyweightofsulfur.3.IntheeventapersonobtainedaninstallationpermitpriortoMay14,1979fortwoormorefuelburningequipmentorsteampowergeneratinginstallationswhichpermittedsuchpersontocomplywiththesulfurdioidc16

# inotallationo conotitutod one emiooion diocharge point, ouch peroon ohall

comply with the applicable oulfur diodde omicoign otaridardo in the manner

opecified in ito inotallation permit and ouch emiocion otandardo ohall be

rn-rrn-ntrri intr riiirh peroon’o operating permit ao an enforceable permit--------- 

# condition. 4_-. 

# Existing steam power generating installations which commenced

construction or a major alteration after May 30, 1972 shall not emit nitrogen

oxides in excess of the following amounts

0.20 pounds of nitrogen oxides, maximum three-hour average,

calculated as nitrogen dioxide, per million Btu heat input when gaseous fossil

fuel is fired. 0.30 pounds of nitrogen oxides, maximum three-hour average,

calculated as nitrogen dioxide, per million Btu heat input when liquid fossil

fuel is fired. 0.70 pounds of nitrogen oxides, maximum three-hour average,

calculated as nitrogen dioxide, per million Btu heat input when solid fossil

fuel is fired. Emission and fuel monitoring systems.L. where deemed necessary by

the Director for sources subject to the provisions of this Section shall

conform to the requirements of Cection Rl8-2-3].3.. 

# The applicable reference methods given in the Arizona Tcting

Manual Atpendices to 40 CFR 60 shall be used to determine compliance with the

standards as prescribed in C.1., C.2., and C.4. above Subsections C. through

G. and I. of this Section, or ao preocribod in a pcroon’o inotallation pcrmit

an provided in C.3., and not by continuouo monitoring. All tests shall be run

at the heat input calculated under Subsection B. of this Section.

17

# R18-2-504. Standards of performance for incinerators

A. The provisions of this Coction arc anolicabi

which are ng sourccs. Notwithstanding the provisions of Ccction RiO 2 501, no person

shall cause, suffcr, allow or permit to be emitted into the atmosphere, from

any type of incinerator, smoke, fumes, gases, particulate matter or othergasborne material which exceeds 20 percent opacity except during the times

specified in A.4. below Subsection D. of this Section.

No person shall cause, suffer, allow or permit the discharge of

particulate matter into the atmosphere in any one hour from any incinerator,

in excess of the following limits;

j For multiple chamber incinerators, controlled atmosphere

incinerators, fume incinerators, afterburners or other unspecified types of

incinerators, emissions shall not exceed 0.1 grain per cubic foot, based on

dry flue gas at standard conditions, corrected to 12 percent carbon dioxide.. 

# 2. For wood waste burners other than air curtain destructors,

emissions discharged from the stack or burner top opening shall not exceed 0.2

grain per cubic foot, based on dry flue gas at standard conditions, corrected

to 12 percent carbon dioxide.

c. For air curtain deotructors, emissions discharged from the pit

opening shall not exceed 0.5 grain per dry standard cubic foot corrected to 12

percent carbon dioxide.

C. Air curtain destructors shall not be used within 500 feet of the

nearest dwelling.

3. The amount of particulate matter emitted shall be determined by

tcot methods and procedures as stated in Lubsection C. below. Test methods may

18bemodified,adjustedoraddedtobytheDircotortosuitspecificsamplingconditionsorneedaandshallbebasedongoodengineeringprastico,judgmcnandcpcricnce.IncineratorsshallbeexemptfromtheaboveopacityandemissionrequirementsdescribedinSubsectionsA.andB.ofthisSectionasfollows:Formultiplechamberincinerators,controlledatmosphereincinerators,fumeincinerators,afterburnersorotherunspecifiedtypesofincinerators,suchexemptionshallbefornotmorethan30secondsinany60-minuteperiod...Woodwasteburnersandaircurtaindootructorsshallbeexemptefollowaboth:.Foraperiodonceeachdayforthepurposeofbuildinganewfirebutnottoexceed60minutes-.andForanupsetofoperationsnottoexceed-threeminutesinany60-minuteperiod.TheowneroroperatorofanyincineratorsubjecttotheprovisionsofthisSectionshallrecordthedailychargingratesandhoursofoperation.ThetestmethodsaridproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsintheArizonaTcotingManual,40CFRSO.AppendixAshallbeusedtodeterminecompliancewiththestandardprescribedinSubsectionA.ofthisSectionasfollows::a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontént.b.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowrate;and19d.Method3forgasanalysisandcalculationofexcessair,usingtbeintegratedsamplingtechnique.2.ForMethod5,thesamplingtimeforeachrunshallbeatleastSOminutesandtheminimumsamplevolumeshallbe0.85dscm(30.0dscf)exceptthatsmallersamplingtimesorsamplevolumes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.R18-2-505.StandardsofperformanceforexistingportlandcementplantsA.TheprovisionsofthisSectionareapplicabletothefollowingaffectedfacilitiesinportlandcementplants:kiln,clinkercooler,rawmillsystem,finishmillsystem,rawmilldryer,rawmaterialstorage,clinkerstorage,finishedproductstorage,conveyortransferpoints,baggingandbulkloadingandunloadingsystems.B.ThenrmrisionoofthiscctionarcapplicabletoallcementplantsunderDtatcofArizonaJuLuJuL.j0flwhicharccxistingsources..Nopersonshallcause,ouffcr,alloworpermitthedischargeofparticulatematterfromanyidentifiableprocesssourcewithinanyexistingcementplantsubjecttotheprovisionsofthisSectionwhichexceedstheamountsallowableundercalculatedbyoneofthefollowingecniations:e--.Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.l0P067:cwhere:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.20Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=where“E”andHP”aredefinedasindicatedin]3.l.a.aboucParagraph1.ofthisSubsection.Noprocesssourcewithinanycxi3tingportlandcementplantshallexceed20percentopacity.Nopersonshallcause,suffcr,alloworpermitdischargeintotheatmosphereofanamountinexcessofsixpoundsofsulfuroxides,calculatedassulfurdioxide,pertoncementkilnfeedfromcementplantssubjecttotheprovisionsofthisSection.TheowneroroperatorofanyportlandcementplantsubjecttotheprovisionsofthisSectionshallrecordthedailyproductionratesandthekilnfeedrates.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsinthcArizonaTctingManual40CFR60,AppendixA,exceptasprovidedforinCcctionRl8-2-312,..shallbeusedtodeterminecompliancewiththestandardsprescribedinSubsectionB.ofthisSectionasfollows:a.Method5fortheconàentrationofparticulatematterandtheassociatedmoisturecontent.b.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowrate;andd.Method3forgasanalysis.212.ForMethod5,theminimumsamplingtimeandminimumsamplevolumeforeachrunexceptwhenprocessvariablesorotherfactorsjustifyingotherwisetothesatisfactionoftheDirector,shallbeasfollows:a.60minutesand0.85dscm(30.0dscf)forthekilnTb.60minutesand1.15dscm(40.6dscf)fortheclinkercooler.3.Totalkilnfeedrate...-(-exceptfuels-)-,expressedinmetrictonsperhouronadrybasis,shallbeboth:a.dctcrmincdDeterminedduringeachtestingperiodbysuitablemethods;andshallbeconfirmedConfirmedbyamaterialbalanceovertheproductionsystem.4.Foreachrun,particulatematteremissions,expresseding/metrictonofkilnfeed,shallbedeterminedbydividingtheemissionrateing/hrbythekilnfeedrate.Theemissionrateshallbedeterminedbytheequation,g/hr=Qxc,whereQ—volumetricflowrateofthetotaleffluentindscm/hrasdeterminedinaccordancewithD.1.c.aboveParagraph1..Subparagraphc.ofthisSubsection,andC=particulateconcentrationing/dscmasdeterminedinaccordancewithDl.a.abovcParagraph1..Subaragrpha.ofthisSubsection.R18-2-506.StandardsofperformanceforexistingnitricacidplantsA.Thestandardfornitrogenoxidesfornitricacidplantswhicharcexist-inasourcesis::cNopersonshallcause,suffer,alloworpermitdischargefromanyexistingsourcenitricacidplantproducingweaknitricacid,whichiseither:30to70percentinstrengthbyeithertheincreasedpressureoratmosphericpressureprocess,or22

# 2 more More than 1.5 kg of total oxides of nitrogen per metric ton

(3.0 lbs/ton) of acid produced expressed as nitrogen dioxide.--. 

# The opacity of any plume subject to the provisions of this Section

shall not exceed 10 ten percent.

B. EmiIion3 monitoring reguircu cni Dectioni 

# as

A continuous monitoring system for the measurement of nitrogen

oxides shall be installed, calibrated, maintained and operated by the owner or

operator, in accordance with Dection R18-2-313.

The test methods and procedures required by this Section are as

follows: 1. The reference methods in the Arizona Testing Manual 40 CFR 60,

Anoendix A shall be used to determine compliance with the standard prescribed

in Subsection A. above of this Section as follows:

a. Method 7 for tie concentration of NO

b. Method 1 for sample and velocitytraversesc. Method 2 for velocity and volumetric flow rate; and

d. Method 3 for gas analysis.

2. For Method 7, the sample site shall be selected according to

Method 1 and the sampling point shall be the centroid of the stack or duct or

at a point no closer to the walls than 1 m (3.28 ft.). Each run shall consist

of at least four grab samples taken at approximately 15-minute intervals. The

arithmetic mean of the samples shall constitute the run value. A velocity

traverse shall be performed once per r’in.

3. Acid production rate, expressed in metric tons per hour of 100

percent nitric acid, shall be both:

a. determined Determined during each testing period by suitable

23methodsandshallconfirmedConfirmedbyamaterialbalanceovertheproductionsystem.4.Foreachrun,nitrogenoxides,expresseding/metrictonof100percentnitricacid,shallbedeterminedbydividingtheemissionrateing/hrbytheacidproductionrate.Theemissionrateshallbedeterminedbytheequation:g/hr=QxcwhereQ=volumetricflowrateoftheeffluentindscm/hr,asdeterminedinaccordancewithC.l.c.aboveParagraehl,SubDaragrahc.ofthisSubsection,andc=NOconcentrationing/dscm,asdeterminedinaccordancewithC.i.a.abovcParagraph1..SubDararaPha.ofthisSubsection.R18-2-507.StandardsofperformanceforexistingsulfuricacidplantsA.TheprovisionsofthisCectionareapplicabletoallnonmotallurgicalsulfuricacidplantsunderona,ctionwnicnarcexistingsources.B--ANosonshallcause,suffer,alloworpermitdischargeatmospnercozmorethan2kgozsuizurajoxipen-rmetrictonsitonof(calculatedas‘cent112004),fromfacilitiesFacilitiesthatproducesulfuricacidbythecontactprocessbyburningelementalsulfur,alkylationacid,hydrogensulfide,organicsulfideandmercaptansoracidsludgeshallnotdischargeintotheatmosohere:_._..__....c____1,_________._..__..__.__t_______.—-—_1___atmosphereofmorethan0.075kgofsulfuricacidmistpermetricton(0.15lbs/ton)ofsulfuricacidproduced(calculatedas100percent112004),expressedas112001,fromfacilitiesthatproducesulfuricacidbythecontact24r————g1—,——S——,organicoulfideeandmercaptancofacidaludgc.1.Greaterthan2kgofsulfurdioxideermetricton(4lbs/ton)osulfuricacidproduced(calculatedas100oercentH2S04),orGreaterthan0.075kgofsulfuricacidmistermetricton(0.15lbs/ton)ofsulfuricacidproduced(calculatedas100percentH2S04).D-B.ThisRuleSectionshallnotapplytometallurgicalplantsorotherfacilitieswhereconversiontosulfuricacidisutilizedasameansofcontrollingemissionstotheatmosphereofsulfurdioxideorothersulfurcompounds.imiionemunitorinrccjuirQaDvfljjL,cc1iOfl1LWoiiowci:Acontinuousmonitoringsystemforthemeasurementofsulfurdioxideshallbeinstalled,calibrated,maintainedandoperatedbytheowneroroperator,inaccordancewithCectionR18-2--313.--‘Q.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsintheArizonaTe3tingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewithstandardsprescribedinSubsectionci!3.andC.aboveA.ofthisSectionasfollows:a.Method8forconcentrationofSO2andacidmistb.Method1forsampleandvelocitytraversesi-.c.Method2forvelocityandvolumetricflowrate;andd.Method3forgasanalysis.2.Themoisturecontenteemaybeconsideredtobezero.ForMethod8thesamplingtimeforeachrunshallbeatleast60minutesandtheminimumsamplevolumeshallbe1.15dscm(40.6dscf)exceptthatsmallersampling25timesorsamplevolumes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.3.Acidproductionrate,expressedinmetrictonsperhourof100percentH2S041shallbeboth:a.dctcrmincdDeterminedduringeachtestingperiodbysuitablemethods.L.andcconfirmodConfirmedbyamaterialbalanceovertheproductionsystem.4.Acidmistandsulfurdioxideemissions,expresseding/metrictonof100percentH2S04,shallbedeterminedbydividingtheemissionrateing/hrbytheacidproductionrate.Theemissionrateshallbedeterminedbytheequation,g/hr-Qxc,whereQ=volumetricflowrateoftheeffluentindscm/hrasdeterminedinaccordancewithF.1.o.abovoParacrraph1.,Subparagraphp.ofthisSubsection,andc=acidmistandconcentrationsing/dscmasdeterminedinaccordancewithF.1.à.abovcParagraph1.,Subparagrapha.ofthisSubsection.R18-2-508.StandardsofperformanceforexistingasphaltconcreteplantsA.Forthopurpooroftniot.cccionanaopna.itconcrc.ton1nnticompriocdonlyofanycoinationofthcfollowing;Dryor,syotemoforcrocning,handling,otoringandweighinghotaggregate,oyotcmoforloading,tranoforringandotoringmineralfiller;oyotcmoformutingaaphaltconcrete;andtheloading,tranofcrringandotoragecyatemoaceociatedwithemiocioncontroloyotcmo.Drumdryerplantd,whercintheaophalticintroducedintotheB-i-.Fixedasphaltconcreteplantse*andportableasphaltconcrete26

# Li plants which are cxioting courcee shall meet the standards set forth in this



# LI Section. The owner or operator Dhall oul3mit proof of prior uce to the

Director. No person shall cause, suffcr, allow or permit the discharge of



# D particulate matter into the atmosphere in any one hour from any existing

asphalt concrete plant in total quantities in excess of the amounts calculated



# LI by one of the following equations net forth below:

For process sources having a process weight rate of 60,000 pounds



# lii per hour (30 tons per hour) or less, the maximum allowable emissions shall be



# fl determined by the following equation:



# j E =4.l0P 067

where: E = the maximum allowable particulate emission rate ‘in pounds-mass per

hour. P = the process weight rate in tons-mass per hour.

For process sources having a process weight rate greater than

60,000 pounds per hour (30 tons per hour), the maximum allowable emissions

shall be determined by the following equation:

E =

where “E” and “P” are defined as indicated in B.l.a. above Paragraph 1. of

this Subsection. For reference purposes only, the equations given above are plotted :

in Figure 2, Appendix 11. The emission values obtained from the graph are

approximately correct for the process weight rates shown. However, the actual

values shall be calculated from the applicable equations and rounded off to

two decimal places. 

# 27ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.1.TheotandardforculfurinfuelunderthieCectionip.Liquidfuelcontaininggreaterthan0.9percentsulfurbyweightshallnotbeutilizedforasphaltconcreteplantssubjecttothisSection.--.Solidfuelcontaininggreaterthan0.5percentsulfurbyweightshallnotbeutilizedforasphaltconcreteplantssubjecttothisSection.ThetestmethodsandproceduresrequiredunderthisSectionare:1.ThereferencesmethodsgiveninthcrionaTc3tingManual40CFR60,ArpendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsectionB.a:bovc.a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontentb.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowrate;andd.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast60minutesandthesamplingrateshallbeatleast0.9dscrn/hr(0.53dscf/min).L.exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.3.PercentsulfurinliquidfuelshallbedeterminedbyASTMmethodD-129-64,andthepercentsulfurinsolidfuelshallbedeterminedbyASTMmethodD317773D-3177-84.Rl8-2-509.Standardsofperformanceforexistingpetroleumrefineries28

# A. The provisions of this Section are applicable to the following

affected facilities in petroleum refineries: fluid catalytic cracking unit

catalyst regenerators, fluid catalytic cracking unit incinerator-waste heat

boilers, and fuel gas combustion devices. All petroleum rcfineric which are

cxicting courcec arc ubjcct to the proviiono of A.A.C. Title, 

# Chapter 3,

Article 0.. 

# Except as provided in Subsection G. of this Section, all t’etroleum

refineries sub-ject to this Section are also subiect to the provisions of R18-

2-801.10. B,- The owner or operator of a petroleum refinery complex subject to

this Rule Section shall develop and conduct a leak monitoring program in

accordance with Appendix H of the EPA Petroleum Refinery Enforcement manual

Manual (EPA 340/1-80-008), Appendix II aa amended as of March, 1980 (and no

future editions), 

# which is incorporated herein by reference and on file with

the Office of the Secretary of State.

Upon detection of a leaking component, which has a volatile

organic compound concentration exceeding 10,000 ppm when tested in the manner

described in the Arizona Tecting Manual 40 CFR 60. APpendix A. the owner shall

both: Include the leaking component on a written list of scheduled

repairs within 24 hours; andT

Repair and retest the component within 15 days.

Except for safety pressure relief valves, no owner or operator of

a petroleum refinery shall install a valve at the end of a pipe or line

containing volatile organic compounds unless the pipe or line is sealed with a

second valve, a blind flange, a plug, or a cap. The sealing device may be

29

# Li removed only when the line is in use (i.e., as when a sample is being taken)-.

No owner or operator of a petroleum refinery shall operate a

pipeline valve or pressure relief valve in gaseous volatile organic compound

service unless it is marked in some manner that will be readily obvious to

both refinery pcroonncl performing monitoring c.nu cnc LJlrcctor is clearly

visible. G-. 

# Existing petroleum refineries of a capacity of 7,000 barrels per

day or less shall be exempt from the emissions monitoring requirements of 40

CFR 60.105 provided the owner or operator of such a refinery complies with j

the following:

1. All process gases or fuel gases shall be treated in an

afterburner, flare or other combustion device to insure complete combustion of

carbon monoxide, hydrogen sulfide, and unburned hydrocarbons.

2. Ambient concentrations of SO 2 in the vicinity of the refinery

shall be calculated using a suitable model approved by the Director and shall

not exceed the Class II incremcnto maximum allowable increases given in

Cectign fliD 2 217 R1B-2-218.

3. A continuous SO 2 ambient air monitor approved by the Director

shall be placed in a location selected by the Director and shall be maintained

in accordance with C-ection R].8-2-215, and SO 2 concentrations shall not exceed

Class II incremcnt maximum allowable increases.

R18-2-510. Standards of performance for existing storage vessels for

petroleum liquids veppei unucr Ctate OL iEona juriuiion WflLfl

aioting courcec ohall meet the following tanderdo;

No person shall place, store or hold in any reservoir, stationary

30tankorothercontainerhavingacapacityof40,000(151,400liters)ormoregallonsanypetroleumliquidhavingavaporpressureof1.5poundspersquareinchabsoluteorgreaterunderactualstorageconditions,unlesssuchtank,reservoirorothercontainerisapressuretankmaintainingworkingpressuresufficientatalltimestopreventhydrocarbonvapororgaslosstotheatmosphere.oriseauioDedwithoneofthefollowingvaporlosscontroldevices,properlyinstalled,ingoodworkingorderandinoperation:Afloatingroofconsistingofapontoontypedouble-decktyperoofrestingonthesurfaceoftheliquidcontentsandequippedwithaclosuresealtoclosethespacebetweentheroofeaveandtankwcll,wallandavaporballoonorvapordome,designedinaccordancewithacceptedstandardsofthepetroleumindustry.Thecontrolequipmentshallnotbeusedifthepetroleumliquidhasavaporpressureof12poundspersquareinchabsoluteorgreaterunderactualstorageconditions.a.Alltankgaugingandsamplingdevicesshallbegas-tightexceptwhengaugingorsamplingistakingplace.b.Thereshallbenovisibleholes,tears,orotheropeningsinthesealoranysealfabric.Whereapplicable,allopeningsexceptdrainsshallbeequippedwithacover,seal,orlid.Thecover,seal,orlidshallbeinaclosedpositionatalltimes,exceptwhenthedeviceisinactualuse.cAutomaticbleederventsshallbeclosedatalltimes,exceptwhentheroofisfloatedofforlandedontherooflegsupports.:Rimvents,ifprovided,shallbesettoopenwhentheroofisbeingfloatedofftherooflegsupports,oratthemanufacturer’srecommendedsetting.Otherequipmentproventobeofequalefficiencyforpreventing



# 31dischargeofhydrocarbongasesandvaporstotheatmosphere.Anyotherpetroleumliquidstoragetankshallbeequippedwithasubmergedfillingdevice.oracceptableequivalentforthecontrolofhydrocarbonemissions.Allfacilitiesfordockloadingofpetroleumproducts,havingavaporpressureof1.5poundspersquareinchabsoluteorgreateratloadingpressure,shallprovideforsubmergedfillingoracceptablecquipmcntecmivalentforcontrolofhydrocarbonemissions.Allpumpsandcompressorswhichhandlevolatileorganiccompoundsshallbeequippedwithmechanicalsealsorotherequipmentofequalefficiencytopreventthereleaseoforganiccontaminantsintotheatmosphere.ThemonitoringofoperationsrequiredbythisSectionisasfollows:1.TheowneroroperatorofanypetroleumliquidstoragevesseltowhichthisSectionappliesshallforeachsuchstoragevesselmaintainafileofeachtypeofpetroleumliquidstored,ofthetypicaleidvaporpressureofeachtypeofpetroleumliquidstoredandofdatesofstorage.Datesonwhichthestoragevesselisemptyshallbeshown.2.TheowneroroperatorofanypetroleumliquidstoragevesseltowhichthisSectionappliesshallforsuchstoragevesseldetermineandrecordtheaveragemonthlystoragetemperatureandtruevaporpressureofthepetroleumliquidstoredatsuchtemperatureifeither:a.Thepetroleumliquidhasatruevaporpressure,asstored,greaterthan26mmHg(1.5pia0.5psia)butlessthan78mmHg(1.5psia)andisstoredinastoragevesselotherthanoneequippedwithafloatingroof,avaporrecoverysystemortheirequivalents;or32

# b. The petroleum liquid has a true vapor pressure as stored, greater

than 470 mm Hg (9.1 psia) and is stored in a storage vessel other than one

equipped with a vapor recovery system or its equivalent.

3. The average monthly storage temperature shall be an arithmetic

average calculated for each calendar month, or portion thereof, if storage is

for less than a month, from bulk liquid storage temperatures determined at

least once every seven days.

4. The true vapor pressure shall be determined by the procedures in

American Petroleum Institute Bulletin 2517, amended as of February, 1980 (and

no future editions), which is incoroorated herein by reference and on file

with the Office of the Secretary of State. This procedure is dependent upon

determination of the storage temperature and the Reid vapor pressure, which

requires sampling of the petroleum liquids in the storage vessels. Unless the

Director requires in specific cases that the stored petroleum liquid be

sampled, the true vapor pressure may be determined by using the average

monthly storage temperature and the typical Reid vapor pressure. For those

liquids for which certified specifications limiting the Reid vapor pressure

exist, the Reidpe. vapor pressure may be used. For other liquids, supporting

analytical data must be made available upon request to the Director when

typical Reid vapor pressure is used.

Gaolinc volatility tcting and control program

1. Thio flub atatc3 rrrrnii--ti ni-nns-”rtic of gaiolinc at tha tima

and placc accordancc gnation:;‘.,



# of dclivcry in bulk in ----.4--.------rnI-rrnfr 

# gacolinc. L’or purpoco of thip flule, “in bujir’

mcan ga3ollnc tranotcrrcd or otorod prior to delivery to a retail odor.—s



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VparticulatematterintotheatmosphereinanyonehourfromanyexistingVsecondaryleadsmelterintotalquantitiesinexcessoftheamountscalculatedbyoneofthefollowingequations..sctforthbclow.Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.l0P°67where:E=themaximum,allowableemissionrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P01-40VVwhereTIEIIand“2”aredefinedasindicatedinA.l.a.aboveParagraph1.ofthisSubsection.--.ForreferencepurposesonlytheequationsinA.l.aboveSubsectionA.ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces..ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.TheopacityofemissionssubjecttotheprovisionsofthisSectionshallnotexceed20percent.35

# B. 

# The test methods and procedures required by this Section are as

follows: 1. The reference methods set forth in thc Arizona Testing Manual

CFR 60, Appendix A shall be used to determine compliance with the standards

prescribed in Subsection A. above of this Section as follows:

a. Method 5 for the concentration of particulate matter and the

associated moisture content

b. Method 1 for sample and velocity traversesi-.

c. Method 2 for velocity and volumetric flow rate; and

d. Method 3 for gas analysis.

2. For Method 5, the sampling time for each run shall be at least 60

minutes and the sampling rate shall be at least 0.9 dscm/hr (0.53 dscf/min),

except that shorter sampling times, when necessitated by process variables or

other factors, may be approved by the Director. Particulate sampling shall be

conducted during representative periods of furnace operation including

charging and tapping.

R18-2-512. Standards of performance for existing secondary brass

and bronze ingot production plants

A. The standards oct forth in this Doction arc applicable to all

secondary braon and bronc ingot production plants which arc ..sting sources.. 

# No person shall cause, suf for, allow or permit the discharge of

particulate matter into the atmosphere in any one hour from any secondary.p2,



# brass or bronze ingot production plant in total quantities in excess of the

amount calculated by one of the following equations. set forth below.

For process sources having a process weight rate of 60,000 pounds

per hour (30 tons per hour) or less, the maximum allowable emissions shall be- 

# 36determinedbythefollowingequation:0.67E=4.].OPwhere:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P0-40where“E”and“P”aredefinedasindicatedinA.1.a.aboveParagraph1.ofthisSubsection.Forreferencepurposesonly,theequationsinA.l.aboveSubsectionA.ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.--ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.pTheopacityofemissionssubjecttotheprovisionsofthisSectionshallnotexceed20percent.B,-ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodssetforthintheArizonaTentingManualCFR60.AppendixAshallbeusedtodeterminecompliancewiththestandards37prescribedinSubsectionA.aboveofthisSectionasfollows:a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontentjb.Method1forsampleandvelocitytraverses-ic.Method2forvelocityandvolumetricflowrate;andd.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast120minutesandthesamplingrateshallbeatleast0.9dscm/hr(0.53dscf/min)exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Particulatemattersamplingshallbeconductedduringrepresentativeperiodsofchargingandrefining,butnotduringpouringoftheheat.R18-2-513.StandardsofperformanceforexistingironandsteelplantsA.ThestanuarussetorcnincnisCoctionarcapp.i.icasiotocasiooxygenprocessfurnacesunderDtatoofiona,onwhicharesources.Nopersonshallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanybasicoxygenprocessfurnaceintotalquantitiesinexcessoftheamountcalculatedbyonethefollowingequations.Lsetforthbelow.Forprocesssourceshavingaprocessweightrateof60,000pounds:‘perhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.l0P067where: 

# 38E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:B=55.0P01-40whereTIEJIand“P”aredefinedasindicatedinA.1..abovcParagraph1.ofthisSubsection.Forreferencepurposesonly,theequationsinA.1.andA.2.a.bovcSubsectionA.ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.ForpurposesofthisP.ulcSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.TheopacityofemissionssubjecttotheprovisionsofthisSectionshallnotexceed20percent.B,-MonitoringofoperationsunderthisSectionisasfollows:1.Theowneroroperatorofanaffectedfacilityshallmaintaindailyrecordsofthetimeanddurationofeachsteelproductioncycle.2.TheowneroroperatorofanyaffectedfacilitythatusesVenturiscrubberemissioncontrolequipmentshallinstall,calibrate,maintainandcontinuouslyoperatethefollowingmonitoringdevices:a.Amonitoringdeviceforthecontinuousmeasurementofthepressure



# 39lossthroughtheVenturiconstructionconstrictionofthecontrolequipment.Themonitoringdeviceistoshallbecertifiedbythemanufacturertobeaccuratewithin±250pascals(±1inchwater)b.Amonitoringdeviceforthecontinuousmeasurementofthewatersupplypressuretothecontrolequipment.Themonitoringdeviceistobecertifiedbythemanufacturertobeaccuratewithin5percentofthedesignwatersupplypressure.Thepressuresensorortapmustshallbelocatedclosetothewaterdischargepoint.TheDirectormaybeconsultedforapprovalofalternativelocationsorthepreurcsensorortap.3.AllmonitoringdevicesrequiredinC.2.belowSubsectionF..Paragraph2,ofthisSectionarctoshallberecalibratedannuallyandatothertimesastheDirectormayrequire,inaccordancewiththeproceduresinAppendix9.ThetestmethodsandproceduresrequiredunderthisSectionareasfollows:1.ThereferencemethodssetforthintheArizonaTootingmanual,4.QCFR60,AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsectioneA.andB.aboveofthisSectionasfollows:a.Method5forconcentrationofparticulatematterandassociatedmoisturecontentib.Method1forsampleandvelocitytraversesc.Method2forvolumetricflowrate;ancLd.Method3forgasanalysis.2.ForMethod5,thesamplingforeachrunshallcontinueforanintegralnumberofcycleswithtotaldurationofatleast60minutes.Thesamplingrateshallbeatleast0.9dscm/hr(0.53dscf/min)exceptthat40shortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Acycleshallstartatthebeginningofeitherthescrappreheatortheoxygenblowandshallterminateimmediatelypriortotapping.R18-2-514.Standardsofperformanceforexistingsewagetreatmentplantsinnrovi1pnLJniOcocionareuppicasietoallmunicipalicwagctreatmentplantoludgeincincratoroofanyoicwhicharcexioting3ourccp..NotwithatandingtheprovitionofDcctionRiO2501,noNpersonshallcause,ouffcr,alloworpermittobeemittedintotheatmosphereTfromanymunicipalsewagetreatmentDlantsludgeincineratoreubjccttotheproviionofthiaCcction,rnno]tcSmoke,fumes,gases,particulatematterorothergas-bornematerialwhichexceeds20percentopacityformorethan30secondsinany60-minuteperiod.2.Nopcronhalicaucc,auffor,allowortcrmittohoemittedintotheatmocphcrofromanyewagceludgeincineratoroübjocttotheprovi3ionoofthiscction,particulateParticulatematterinconcentrationsinexcessof0.1grainpercubicfoot,basedondryfluegasatstandardconditions,correctedto12percentcarbondioxide.B.Monitoringofopcrationrequiredbythiscaticniocofollows;Theowneroroperatorofanysludgeincineratorsubjecttothe:provisionsofthisSectionshallmonitoroierationsbydoingallofthefollowing:Install,calibrate,maintainandoperateaflowmeasuringdevicewhichcanbeusedtodetermineeitherthemassorvolumeofsludgechargedto



# 41

# the incinerator. The flow measuring device shall have an accuracy of .& jJ

five percent over its operating range.

Provide access to the sludge charged so that a well-mixed

representative grab sample of the sludge can be obtained.

Install, calibrate, maintain and operate a weighing device for

determining the mass of any municipal solid waste charged to the incinerator

when sewage sludge and municipal solid wastes are incinerated together. The

weighing device shall have an accuracy of .5. +1- five percent over its

operating range.

C. The test methods and procedures required by this Section are as

follows: 1. The. reference method set forth in theArizonaTcting 

# Manual jQ.

CFR 60, Appendix A shall be used to determine compliance with the standards

prescribed in Subsections. A. andB.above 

# of this Section as follows:

a. Method 5 for concentration of particulate matter and associated

moisture contenti-.

b. Method 1 for sample and velocity traverses-r.

c. Method 2 for volumetric flow rate; and

d. Method 3 for gas analysis.

2. For Method 5, the sampling time for each run shall be at least 60

minutes and the sampling rate shall be at least0.015 

# dscm/min(0.53 dscf/min),

except that shorter sampling times, when necessitated by process variables or

other factors, may be approved by the Director.

Rl8-2-515. Standards of performance for existing primary copper

smelters; Site specific reauirements

A. Tha rovirianri of this Boction arc applicabic to allprimary



# 42——--a--. 

# No owner or operator of an ccioting primary copper smelter, from—



# anu acer tnc compliance date apecified in uacccionL., 

# compi.

.n u nonfcrrouo cmeltcr order, in a concent decree, or in a delayca.

cificd order, shall cause, cuff cr, allow or permit the discharge of

particulate matter into the atmosphere from any process in total quantities in

excess of the amount calculated by one of the qucctiona act forth below

following eauat ions:

For process sources having a process weight rate of 60,000 pounds

per hour (30 tons per hour) or less, the maximum allowable emissions shall be

determined by the following equation:

E= 

# 4.lOP 067

where E= 

# the maximum allowable particulate emissions rate in pounds-mass per

hour. P= 

# the process weight rate in tons-mass per hour.

For process sources having a process weight rate greater than

60,000 pounds per hour (30 tons per hour), the maximum allowable emissions

shall be determined by the following equation:

E= 

# 55.0P 0 -40

where “E” and “P” are defined as indicated in Z.l.a. above Paragraph 1. of

this Subsection. For reference purposes only, the equations in 13.1. above

Subsection A. of this Section are plotted in Figure 2, Appendix 11. The

emission values obtained from the graph are approximately correct for the

43processweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.ForpurposesofthisCuboectionSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematterforthatprocess..1i.Forthe-__-—,____..=ii.Forthecopper•••••‘‘°—4e 

# 44fleyMinesTheopacityofemissionssubjecttotheprovisionofthisCub3cctionSectionshallnotexceed20percent.-‘cDirectorfor4n,a‘-,ca-iftrcviionofits-ripib1cemissionslimitproviuisectS.Interimoperatingrequirements;a.Duringtheperiodpriortothecompliancedate,theowneroroperatorofasmeltersubjecttothisCectionshallcomplywiththefollowingemissionlimitsbyoperatinghisparticulateremovalequipmentatitsmaximumsoppersmelterofMagmaCopperCompy,eulateemosies.iim.tshallbe1830poundsperhour.iv.rortheeoppersmeltereACARCO,me.,hayden,theticulatoniimiconai.be800poundsv.FortheeeppermeiteroLne.1.psDodgermrvratien,DouglasionW,i-ir-i..ssienlimitshallbe1752pounasrrIivi.FortheeeppersmeiterorheipsDodgeCerperaon,P1orenthe“‘-tiemissionlimitshallbe2144poundspernour.vii.ForthesoppersmelterofrheipsDodge•orporation,NewCarneliaBraneh,thepartioulateemissionlimitshallbe!3G0poundsperhour.6--ThereferencemethodssetforthintheArizonaTestingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinthisubscctionSectionasfollows:ExceptadescribedinC.a.i.below,MethodAlorReferenceMethod5forconcentrationofparticulatematterandassociatedmoisturecontent.i.Cemplianeewiththestandardspreseribedin5.a.i.andS.a.iii.shallbedetermineaaeembiRefereneeMethods5and8inwhiehaMethodSfilterismaintainedat2500FahrenheitandaMethod0impingertrainisused.ThepartieulatereportedshallineludetheeatehfromtheMethod5filter,partieulatesfremtheprobewash,andthesulfurieaeid-8-b--.ReferenceMethod1forsampleandvelocitytraverses-7-ReferenceMethod2forvolumetricflowrate,and--jReferencemethod3forgasanalysis.G-sulfurdioxideemissionslimitations:45

# Except as provided in a nonferrouci cimeltcr order, a consent decree

or a delayed compliance order, no owner or operator of any ccicitiRg primary

copper smelter, from and afterci. 

# date (hereinafter cai.i.ea the “compliance

date”) three ycarci acrnc 

# uac on which the Adminiotrator, acting purciua.nt

to Cection 110 of the Act, approvco thici Cu.boection, shall discharge or cause

the discharge of sulfur dioxide into the atmosphere from any stack-(-s-)- required

to be monitored by Paragraph 4. below R18-2-515.Ol.K. in excess of the

following: For the copper smelter of Magma Copper Company, San Manuel

Division:-- 

# nnual average emissions, as calculated pursuant to raragraphci 2.

and 3. below R18-2-515.0l.C. throuh R18-2-515.Ol.J., shall not exceed 18,275

pounds per hour. The number of three-hour average emissions as calculated

pursuant to Paragraphci 2. and 3. below R18-2-515.01C. through R18-2-515.01.J.

shall not exceed n cumulative occurrences in excess of E, the emission level,

shown in the following table in any compliance period:

E. lb/hr.

0 72,000

1 68,000

2 64,000

4 61,000 :

7 57,800

12 54,800

20 52,000

32 49,500

464847,5006845,5009443,50013041,20018039,20024537,200330-35,20043533,77056032,00071030,20089028,700110027,200134025,700161024,500191023,000224021,700ForthecoppersmelterofASARCOInc.,Hayden:a.Annualaverageemissions,ascalculatedpursuanttoParagraph2.and3.bclowR18-2-515.01.C.throuhR18-2-515.01.J.,shallnotexceed9,521poundsperhour.Thenumberofthree-houraverageemissionsascalculatedpursuanttoraragraph2.and3.bolowR].8-2-5l5.Ol.C.throughR1B-2-515.01.J.shallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:E.lb/hr.038,00047136,000234,000432,000730,5001228,8002027,3003226,0004825,0006823,8009422,70013021,50018020,50024519,30033018,50043517,50056016,70071016,00089015,000110014,200134013,500161012,800191012,200224011,5003ForthecoppersmelterofKcnnccottCoppc.rCorporationASARCO,Inc.,RayMinesDivision:a.Annualaverageemissions,ascalculatedpursuanttoParagraphs2.48and3.belowRl8-2-515.01.C.throuahR18-2-5l5.01.J.,shallnotexceed7,790poundsperhour.Thenumberofthree-houraverageemissionsascalculatedpursuanttoraragraph2.and3.belowRl8-2-515.01.C.throughR18-2-515.O1.J.shallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:E,lb/hr.034,000132,000230,000428,500726,8001225,3002024,0003222,8004821,7006820,7009419,70013018,70018017,70024516,70033015,70043515,20056014,40071013,50089012,70049110012,000134011,200161010,500191010,00022409,5004-j.ForthecoppersmelterofIncipirationConoo.CyprusMiamiMiningCorporation,Miami:a.Annualaverageemissions,ascalculatedpursuanttoraragraphci2.and3.bclowRlB-2-515.0l.C.throughRl8-2-515.0l.J,,shallnotexceed3,163poundsperhour.Thenumberofthree-houraverageemissionsascalculatedpursuanttoParagraphz2.and3.bclowR18-2-5l5.01.C.throughRlB-2-515.0l.J.shallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:E.lb/hr.016,900115,800214,750413,900713,1001212,2502011,5003210,8004810,250689,750949,250501308,7001808,2002457,6003307,2004356,7505606,3007105,8008905,50011005,20013404,80016104,50019104,10022403,800jForthecoppersmelterofPhelpsDodgeCorporation,NewCorneliaBranch:a.Annualaverageemissions,ascalculatedpursuanttoraragraphc2.and3.belowR18-2-5l5.01.C.throughRl8-2-515.Ol.J,,shallnotexceed8,900poundsperhour.Thenumberofthree-houraverageemissionsascalculatedpursuanttoFaragrapho2.and3.belowR18-2-515.01.C.throughR18-2-515.01.J.shallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:fl.E,lb/hr.037,000135,000232,50051431,000729,0001227,5002026,0003225,0004823,5006822,5009421,50013020,50018019,50024518,50033017,50043517,00056016,00071015,00089014,250110013,500134012,500161012,000191011,000224010,500theecrncrtnctcrofPhelpoDodgcCooration,.ojavcraaccmiiOfl,ppand3.bclow,cxcccd15,C75011y522.and3.bclowohallnottheemioenlevel,sheiintheLellewingaèleinaycomplianceperiod:——E1b/hr.GCl,0058,30055,000452,2004,50047,00044,70042,5004-840,50030,000.9437,00035,200.84-33,3002A_531,C0030,20043920,000-6427,30026,0008-9424,500110023,200131022,000161020,00053192.019,000-2240-10,000ForthecoppersmelterofPhelpsDodgeCorporation,MorenciBranch:a.nnualaverageemissions,ascalculatedpursuanttoraragrapho2.and3.belowR18-2-5l5.0l.C.throughR18-2-515.0]..J.,shallnotexceed10,505poundsperhour.Thenumberofthree—houraverageemissionsascalculatedpursuanttoParagraphs2.and3.bclowRlB-2-5l5.01.C.throughRl8-2-5l5.0l.7.shallnotexceedncumulativeoccurrencesinexcessofE,theemissionslevel,showninthefollowingtableinanycomplianceperiod:E,lb/hr.043,500141,000238,200436,200734,5001232,5002030,5003229,5004828,0006827,0009426,00013024,50018023,00024522,000



# 5433021,00043519,50056018,50071017,50089016,500110015,500134015,000161014,000191013,000224012,000R18-2-515.0l.Standardsofverformanceforexistingprimarycoppersmelters;ComplianceandmonitoringThecumulativeoccurrenceandemissionlimitsspecifiedinthizParagraphR18-2-515.F.shallapplytothesumtotalofsulfurdioxideemissionsfromthesmelterprocessingunitsandsulfurdioxidecontrolandremovalequipment,butnotincludinguncapturedfugitiveemissionsandthoseemissionsduesolelytotheuseoffuelforspaceheatingorsteamgeneration.Periodsofmalfunction,startup,shutdownand,’orotherupsetconditionsshallnotbeexcludedwhendeterminingcompliancewiththecumulativeoccurrenceand-/orannualaverageemissionlimitsspecifiedinthi3ParagraphR18-2-515.F.2.Compliancowiththcoumulativcoccurrcnccandcmiooionlimits:containcdinParagraph1duringthoinicia3CEdaycompliancepericathooclimitaarceffectivewithrcopc.cpccificomcltcr,ohallbcmedaofollowoa.Compliance55Paragraph1shallbedeterminedenamenthlybasisbyaveragingtheemissiensforallhoursmeasuredfromtheaomplieodatethreughthelastdayofthecalendarmonth.Attheendofthefirstmonth,thesmeltershallbedeemedtobeincompliancewiththeapplicablenumericallimitifitoaveragecmiooionoexceeditoannualaverageomiooionlimitbynomorethan11percentofouchlimit.Attheendofthesecondmonth,thesmeltershallbedeemedtobeincomplianceifitoaverageemiosionoexceeditoannualavoragaemiooionlimitbynomorethan10perccntofouchlimit.Ineachoucceedingmonththepermiooiblcpercentageabovethelimitshallbedecrcaoodbyonepercentoftheannualaverageouchthat,attheendofthetwelfthrnonth,theomcltcrohallbcincompliancewithitoannualaverageemissionlimit.b.CompliancewiththeapplicablecumulativeoccurrencelimitsinParagraph1ohallbedeterminedonthebaoioofallthreehouravcrageocalculatedaodeocribedinParagraph3.Cubparagraphb.belowthathavebeenCompliancewiththecumulativeoccurrenceandemissionlimitscontainedinParagraph1R18-2-515.F.forallcompliancepcricdosubsequenttothcinitial3CdaycomplianceperiodopccificdinParagraph2shallbedeterminedasfollows:Annualaverageemissionsshallbecalculatedattheendofeachdaybyaveragingtheemissionsforallhoursmeasuredduringthecomplianceperiodendingonthatday.Anannualemissionsaverageinexcessoftheallowableannualaverageemissionlimitwillbeconsideredaviolationifeither:a.Theannualaverageislargerthantheannualaveragecomputedfortheprecedingday;or56

# IHannualaveragescomputedforthefiveprecedingdays



# 7allexceedtheallowableannualaverageemissionlimit.Three-houremissionsaveragesshallbecalculatedattheendofeachclockhourbyaveragingthehourlyemissionsfortheprecedingthreeconsecutivehourswhenevereachsuchhourwasmeasuredinaccordancewiththerequirementscontainedinParagraph—4SubsectionK.ofthisSection.



# 7ForpurDosesofthisSection,thecompliancedate,unlessotherwiseprovidedinaconsentdecreeoradelayedcomnlianceorder,shallbeJanuary14,1986.€--.ForpurposesofthisParagraphSubsectionC.ofthisSection,athree-houremissionsaverageinexcessofanemissionlevel(E)willbeconsideredtoviolatetheassociatedcumulativeoccurrencelimit(n)listedinParagraph1Rl8-2-515.F.ifboth:Thenumberofallthree-houremissionsaveragesmeasuredduringthecomplianceperiodinexcessofthatemissionlevelexceedsthecumulativeoccurrencelimitassociatedwiththeemissionlevel;andTheaveragewasmeasuredduringthe,lastoperatingdayofthecomplianceperiodbeingreported.Athree-houremissionsaveragecanonlyviolatethecumulativeoccurrencelimit(n)ofanemissionlevelCE)inthedaycontainingthelasthourintheaverage.MultipleviolationsofacumulativeoccurrencelimitinthesamedayandviolationsofdifferentcumulativelimitsinthesamedayshallconstituteasingleviolationoftherequirementsofthicCectionR18-2-515.Theviolationofanycumulativeoccurrencelimitandanannualaverageemissionlimitinthesamedayshallconstituteonlyasingle



# 57

# violation of the requirements of thic Ccction R18—2-515.

Multiple violations of a cumulative occurrence limit by different

three-hour emissions averages containing any common hour shall constitute a

single violation of the requirements of this Ccction R18-2-515.

For purposes of determining compliance with thio Paragraph

Subsections C. through I. of this Section, the compliance period shall consist

of the 365 calendar days immediately preceding the end of each day of the

month being reported unless that period includes less than 300 operating days.

In such case the number of days preceding the last day of the compliance

period shall be increased until the compliance period contains 300 operating

days. Any day in which sulfur containing feed is introduced into the smelting

process constitutes an operating day.

For purposes of determining compliance with the cumulative

occurrence and emission limits contained in Paragraph 1 R18-2-515.F., the

owner or operator of any smelter subject to such limits shall install,

calibrate, maintain, and operate a measurement system for continuously

monitoring sulfur dioxide concentrations and stack gas volumetric flow rates

in each stack which could emit five percent or more of the allowable annual

average sulfur dioxide emissions from the smelter, and for

Such measurement system shall also continuously monitor4i sulfur

dioxide concentrations and stack gas volumetric flow rates in the ou1et of

each piece of sulfur dioxide control equipment.

Captured fugitive emissions shall be continuously monitored for

sulfur dioxide concentrations and stack gas volumetric flow rates, and these

emissions shall be included as part of total plant emissions when determining

compliance with the cumulative occurrence and emission limits contained in

58

# LiLi____



# Paragraph 1 R18-2-515.F.

If the owner or operator can demonstrate to the Director that

measurement of stack gas volumetrió flow in the outlet of any particular piece

of sulfur dioxide control equipment would yield inaccurate results or would be



# Li technologically infeasible, then the Director may allow measurement of the

flow rate at an alternative sampling point.



# U j. For purposes of this Paragraph Subsection, continuous monitoring

means the taking and recording of at least one measurement of sulfur dioxide



# U concentration and stack gas flow rate reading from the effluent of each

affected stack, outlet or other approved measurement location in each 15-

minute period. n hour of smelter emissions will shall be considered to have



# J been continuously monitored if the emissions from all monitored stacks,

outlets or other approved measurement locations are measured for at least 45



# j minutes of any hour in accordance with the requirements of this Paragraph

Subsection.

j The continuous monitoring system described in this Paragraph

Subsection shall meet all of the following requirements:

a. No later than 18 months prior to the compliance date and at such

other times as the Director may specify, the stack gas volumetric flow rate



# ! measurement system-(-&)- installed and operated pursuant to this Section shall be

demonstrated to meet the performance specifications prescribed in 40 CFR 52,



# ] Appendix E.

b. No later than 18 months prior to the compliance date and at such

other times as the Director may specify, the sulfur dioxide concentration

measurement system-4e1- installed and operated pursuant to this Section shall be

demonstrated to meet the measurement system performance specifications

59prescribedin40CFR52,AppendixD,exceptthat“maximumanticipatedconcentration”shallbesubstitutedfor“emissionstandard”in“TableI--PerformanceSpecifications.”assontainedinParagraph4.ooaidAppendiiD.c.ThedemonstrationsofmeasurementsystemsperformancerequiredbySubparagraphsa.andb.abovcofthisParacrrahshallbeconductedinaccordancewiththefieldtestproceduresprescribedby40CFR52,AppendicesDandEtoPart52,Titic40,ofthoCodcofFc.dcralflcgulationi.TheDirectorshallbenotifiedatleast30daysinadvanceofthestartofthefieldtests.d.LocationofallsamplingpointsformonitoringsulfurdioxideconcentrationsandstackgasvolumetricflowratesshallbeapprovedinwritingbytheDirectorpriortoinstallationandoperationofmeasurementinstruments.e.Themeasurementsystem-(-e-)-installedandusedpursuanttothisParagraphSubsectionshallbesubjecttothemanufacturer’srecommendedzeroadjustmentandcalibrationproceduresatleastonceper24-houroperatingperiodunlessthemanufacturerspecifiesorrecommendscalibrationatshorterintervals,inwhichcasespecificationsorrecommendationsshallbefollowed.Recordsoftheseproceduresshallbemadewhichclearlyshowinstrumentreadingsbeforeandafterzeroadjustmentandcalibration.FailureoftheowneroroperatorofasmeltersubjecttothisSectiontomeasureatleast95percentofthehoursduringwhichemissionsoccurredinanymonthshallconstituteaviolationofthisSection.FailureoftheowneroroperatorofasmeltersubjecttothisSectiontomeasureany12consecutivehoursofemissionsinaccordancewiththerequirementsofthisParagraphSubsectionK.ofthisSectionshallconstituteaviolationofthisSection.601’--j1.TheowneroroperatorofanysmeltersubjecttothisSectionshallmaintainonhandandreadyforimmediateinstallationsufficientsparepartsorduplicatesystemsforthecontinuousmonitoringequipmentrequiredbythisSectiontoallowforthereplacementwithinsixhoursofanymonitoringequipmentpartwhichfailsormalfunctionsduringoperation.Asameansofdeterminingtotaloverallemissions,theowneroroperatorofanysmeltersubjecttothisSectionshallperformmaterialbalancesforsulfurinaccordancewiththeproceduresprescribedbyAppendix8.--.TheowneroroperatorofanysmeltersubjecttothisSectionshallmaintainarecordofallaveragehourlyemissionsmeasurementsrequiredtobemeasuredbythisSection.Therecordofsuchemissionsshallberetainedforatleasttwoyearsfollowingthedateofmeasurement.Meaourcmcntrcault3ofthefollowingmeasurementresultsshallbeexpressedaspoundsperhourofsulfurdioxide.ThefollowingmearnirementoshallbesummarizedmonthlyandsubmittedtotheDirectorwithin-&daysaftertheendofeachmonth:a.Duringtheinitial3C5dayperioddescribedinparagraph2the...vcaverageonsasofthelastdayofthemonth.Foralloubocquentperiodsdescribedinraragraph3SubsectionC,ofthisSection,theannualaverageemissions(expressedinpoundsperhour)ascalculatedattheendofeachdayofthemonth;2Thetotalnumberofhourlyperiodsduringthemonthinwhichmeasurementswerenottakenandethereasonforlossofmeasurementforeachperiod;iThenumberofthree-houremissionsaverageswhichexceededeachoftheapplicableemissionslevelslistedinParagraph1R18-2-515.F.forthe61complianceperiodsendingoneachdayofthemonthbeingreported;--j.Thedate-fe-)-onwhichacumulativeoccurrencelimit-fe-)-listedinParagraph1R18-2-515.F.wasexceededifsuchexceedanceoccurredduringthemonthbeingreported.ComplianceQanca.1.LLCtJ:Q.TheowneroroperatorofasmeltersubjecttothisSectionshall,within0dayifromthcdateonwhichtheAdministratorapprovcthiaCub3cction,submitaproposedcompliancescheduletotheDirector.Thcochcdulch1lwhichdemonstrate.thattheemissionlimitsofParagraph1R18-2-515.F.willbeachievedatthesmelterasexpeditiouslyaspracticable,butnolaterthanthecompliancedate.TheschedulesubmittedpursuanttothisParagraphSubsection0.ofthisSectionshallincludeincrementsofprogressandthedateforachievementofsuchincrements.Theincrementsofprogressshallincludeallofthefollowing:Nolaterthan30monthspriortothecompliancedate,submissiontotheDirectorofafinalcontrolplanformeetingtheemissionlimitsinParagraph1R18-2-515.F.;Nolaterthan28monthspriortothecompliancedate,lettingofcontractsorissuanceofpurchaseordersforanyprocessand,’orcontrolequipmentnecessarytoaccomplishtherequiredemissioncontrol;iii.Nolaterthan24monthspriortothecompliancedate,initiationofanynecessaryon-siteconstructionorinitiationofanynecessaryinstallationofemissioncontrolequipmentand/orprocessmodification;Nolaterthan24monthspriortothecompliancedate,62submissionofthefugitiveemissionsevaluationprescribedinparagraph0.ofthioCcctionR18-2-515.02.B.throughR18-2-515.02.D.,includingacomplianceplanforinstallationofanyadditionalfugitiveemissioncontrolequipmentnecessarytoassureattainmentaridmaintenanceoftheapplicableambientairqualitystandardsinthevicinityofthesmelter;Nolaterthan18monthspriortothecompliancedate,theinitiationofthedemonstrationsofstackgasvolumetricflowrateandsulfurdioxideconcentrationmeasurementsystemsrequiredbyParagraph4.Subparagraphsa.andb.ofSubsectionK.Nolaterthanthreemonthspriortothecompliancedate,completionofanynecessaryon-siteconstruction,orinstallationofemissioncontrolequipmentand,’orprocessmodification;andvii.Nolaterthanthecompliancedate,achievementofcompliancewiththeemissionlimitsinParagraph1R18-2-515.F.TheowneroroperatorshallcertifytotheDirector,within15daysafterthedeadlineforcompletionofeachincrement,whethertherequiredincrementofprogresshasbeenmet.•.—---.-—--a.Duringtheperiodpriortothecompliancedate(hereaftercalled_____________________________________—..14-..-....-.-.4—4—1—1...-:comp;‘ihr‘,,nrrr,m--‘1•CectiQnJIJiJ..L..Lzfl1rnoperatorJwCnL1L1owingemiocionlimitobyoperatinghi_4-__44-4ForthecopperomelterofInopiration4..,-4-._________.163CopperCooration,flayMincocalendarmonth.,.!a—s——-—-—.-..-‘—--‘—‘.-•_•r.1

# 9



# \0



# C fl fl’. 

# rm n c-nmaterialcinproococ.Removedculfurchallincludebutnotbelimitedtooulfurcontainedinclag,blictercopper,ciulfuricacid,liquifiedoulfurdioxide,elementalculfur,flueduct,precipitatorduct,acidplantaludge,ocrubbereffluentandabcorptionplantpurge.Allunremovedculfur,includingfugitivesulfuremiccionc,ohallbeconoideredacomiocionctotheaicntair.ii.MaterialbalancecforoulfurdeocribedinDubdivicioni.aboveshallbeobtainedinaccordancewithprocodurecliotedinAppendix0.iii.Compliancewiththeaveragedailyemiocionlimitoectabliohedby8ubparagrapha.ictobedeterminedbydividingthetotalmonthlyemiccionacalculatedunderCubdivicioni.abovebythenumberofoperatingdayriintheofacopperomelteroubjcattoan.....-.I—4-.t.limitunderthicparagraphahallreporttotheDirectorthefifteenthdayofeachmonth,theomeltermaterialbalanceormeacuredoulfurdioxideotackemiccioncandambientoulfurdioxidedatafortheprecedingcalendarmonthaorequiredbytheoperatingpermitfortheomelter.Ateachpointinthesmelterfacilitywhereameansexiststobypassthesulfurremovalequipment,suchbypassshallbeinstrumentedandmonitoredtodetectandrecordallperiodsthatthebypassisinoperation.EachowneroroperatorofacoppersmeltershallreporttotheDirector,notlaterthanthefifteenthdayofeachmonth,theinformationrequiredtoberecordedbythisParagraphSection.Suchreportshallincludeanexplanationforthenecessityoftheuseofthebypass.R18-2-515.02.Standardsofperformanceforexistingprimarycopper



# 65a.ForuroosesofthisSection.theconmliancedate,unlessotherwiseprovidedinaconsentdecreeoradelayedcomolianceorder,shallbeJanuary14.1986.0.Fugitivccmicoioncvaluation;e--.Nolaterthan24monthsbeforethecompliancedatetheowneroroperatorofasmeltersubjecttothisCcctionR18-2-.515,shallsubmittotheDirectortheresultsofanevaluationofthefugitiveemissionsfromthesmelter.Theevaluationresultsshallcontainallofthefollowinginformation:,Ameasurementoraccurateestimateoftotalfugitiveemissionsfromthesmelterduringtypicaloperations,includingplannedstart-upandshutdown.Themeasurementorestimateshallcontaintheamountofbothaverageshort-term(24hours)andaveragelong-term(monthly)fugitiveemissionsfromthesmelter.TheevaluationplanshallbeapprovedinadvancebytheEurcauDepartmentandshallspecifythemethodusedtodeterminethefugitiveemissionamounts,includingtheconditionsdeterminedtobe“typicaloperations”forthesmelter.Ameasurementoraccurateestimateoftherelativeproportion-(expressedasapercentage4-oftotalfugitiveemissionsduringtypicaloperations,includingplannedstart-upandshutdown,producedbythefollowingsmelterprocesses:a.Roasterordryeroperation;,Calcineordriedconcentratetransfer;C.Reverberatoryfurnaceoperations4includingfeeding,slagreturn,matteandslagtapping4-;jMattetransfer;and66e.Converteroperations.ThemeasurementtechniqueormethodofestimationusedtofulfillthiotherequirementinPararah2.ofthisSubsectionshallbeapprovedinadvancebythe]JurcauDeoartment.iii.j..Theresultsofatleasta6-monthfugitiveemissionimpactanalysisconductedduringthatpartoftheyearwhenfugitiveemissionsareexpectedtohavethegreatest.ambientairqualityimpact.Thestudyshallutilizesufficientmeasurementsoffugitiveemissions,meteorologicalconditionsandambientsulfurdioxideconcentrationstoassociatefugitiveemissionswithspecificmeasuredambientconcentrationsofsulfurdioxide.Thestudyshalldescribeindetailthetechniquesusedtomaketherequireddeterminations.ThedesignofthestudyshallbeapprovedinadvancebytheDurcauDepartment.OnthebasisoftheresultsoftheevaluationaswellasotherdataandinformationcontainedintherecordsoftheBurcauDepartment,theDirectorshalldeterminewhetherfugitiveemissionsfromaparticularsmelterhavethepotentialtocauseorsignificantlycontributetoviolationsoftheambientsulfurdioxidestandardsinthevicinityofthesmelter.IftheDirectorfindsthatfugitiveemissionsfromaparticularsmelterhavethepotentialtocauseorsignificantlycontributetoviolationsofambientsulfurdioxidestandardsinthevicinityofasmelter,thentheDirectorshall,nolotcrthan10monthobcforothccompliancodate,adoptflegulationorulesspecifyingtheemissionlimitseandundertakeotherappropriatemeasuresnecessarytomaintainambientsulfurdioxidestandards.TherequirementsofthicraragraphSubsectionB.ofthisSectionshallnotapplytoasmeltersubjecttothisSectioniftheowneroroperator67ofthatsmeltercandemonstratetotheDirectorboththat:CompliancewiththeapplicablecumulativeoccurrenceandemissionlimitslistedinParagraph1R18-2-515.F.willrequirethesmeltertoundergomajormodificationstoitsphysicalconfigurationand/orworkpracticespriortothecompliancedate,andThatthemodification-fe.)-willreducefugitiveemissionstosuchanextentthatsuchemissionswillnotcauseorsignificantlycontributetoviolationsofambientsulfurdioxidestandardsinthevicinityofthesmelter.L..InordertoassessthesufficiencyofthecumulativeoccurrenceandemissionlimitscontainedinParagraph1.ofthisCubcctionR18-2-515.F.tomaintaintheambientairqualitystandardsforsulfurdioxidesetforthinR18-2-202,anowneroroperatorofasmeltersubjecttothisSectionshallcontinuetocalibrate,maintainandoperateanyambientsulfurdioxidemonitoringequipmentownedbythesmelterowneroroperatorandinoperationwithinthedeo-ignatcdliabilityareaofthesmelterenclosedbyacirclewithten-mileradiusascalculatedfromacenterpointwhichshallbethepointofthesmelter’sgreatestsulfurdioxideemissions,onthceffectivedatcofthiscctioninterimperiodandforaperiodofatleastthreeyearsafterthecompliancedate.SuchmonitorsshallbeoperatedandmaintainedinaccordancewithParto40CFR50arid58,Title40oftheCodeofFcderalRcgulaticnoandsuchotherconditionsastheDirectordeemsnecessary.2.ThelocationofambientsulfurdioxidemonitorsandlengthoftimesuchmonitorsremainatalocationshallbedeterminedbytheDirector.R18-2-516.Standardsofperformanceforexistingcoalpreparation68plantsA.TheprovisionsofthisSectionareapplicabletoanyofthefollowingaffectedfacilitiesincoalpreparationplants:Thcrmalthermaldryers,pneumaticcoal-cleaningequipment(airtablcz),coalprocessingandconveyingequipment4includingbreakersandcrushers.)-,coalstoragesystems,andcoaltransferandloadingsystems.Thiscctionicapplicabletoallcoalprcparationplaritowhicharcc3tiotingoourcco.ForpurposesofthisSection,thedefinitionscontainedin40CFR60.251areadoptedbyreferenceandincorporatedherein.Nopersonshallcause,ouffcr,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanyexistingcoalpreparationplantlocatedintotalquantitiesinexcessoftheamountscalculatedbyoneofthefollowincequationsoctforthbelow:Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.10P067where:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P°1-40where“E”and“p”aredefinedasindicatedinA.1.a.abovePararaoh1.of69thisSubsection.Forreferencepurposesonly,theequationsinA.l.aboveSubsectionB.ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.ForpurposesofthisfluicSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.4.TheopacityofanyomiccionoubjecttotheproYieionofthiaCectiunsnailnotexceed4upercent.FugitiveemissionsfromcoalpreparationplantsshallbecontrolledinaccordancewithR18-2-404throughR18-2-407.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsintheArizonaTc3tingManual40CFR60.ApiendixAareusedtodeterminecompliancewithstandardsprescribedinSubsectionA.aboveB.ofthisSectionasfollows:a.Method5fortheconcentrationofparticulatematterandassociatedmoisturecontent.b.Method1forsampleandvelocitytraverses-7-c.Method2forvelocityandvolumetricflowrate,andd.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrun&shallbeatleast60minutesandtheminimumsamplevolumeis0.85dscm(30dscf).L.exceptthatshortsamplingtimesorsmallervolumes,whennecessitatedbyprocess70variablesorotherfactorsmaybeapprovedbytheDirector.Samplingeshallnotebestarteduntil30minutesafterstart-upandictoshallbeterminatedbeforeshutdownprocedurescommence.TheowneroroperatoroftheaffectedfacilityshalleliminatecyclonicflowduringperformancetestsinamanneracceptabletotheDirector.3.Theowneroroperatorshallconstructthefacilitysothatparticulateemissionsfromthermaldryersorpneumaticcoalcleaningequipmentcanbeaccuratelydeterminedbyapplicabletestmethodsandproceduresunder13.1.abovcPararaph1.ofthisSubsection.R18-2-517.Standardsofperformanceforsteelplants:existingelectricarcfurnaces(EAF)A.Thepro-.-icioncofthicDcctionarcapplicabletothefollowingaffectedfailiticinctcclplantowhicharcoxiotingcouraGe:Electricarcurnacccuiiuaucnanuiingcquipmcnt.Nopersonshallcause,cuffcr,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromelectricarcfurnacesordust-handlingeauipmentwhichareaffectedfacilitiesinanysteelplantlocatedintotalquantitiesinexcessoftheamountcalculatedbyoneofthefollowingequationscotforthbelow:Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.l0P067where:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.71P=theprocessweightrateintons-massperhour.--.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P01-40where“E”andlip”aredefinedasindicatedinA.l.a.abcvc?ararah1.ofthisSubsection.--.Forreferencepurposesonly,theequationsgivenaboveareplottedinAppendix11,Figure2.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.ForpurposesofthisflulcSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.4,-nopacitystandardofforty.Qpercentshallnotbeexceededbyexistingsteelplantelectricarcfurnacesandtheirappurtenancesformorethananaggregateofthreeminutesinanyfortyfivcminuteperiod.B,-.EmiccionmonitoringrcquircdbythicCcctionicfollows;Acontinuousmonitoringsystemforthemeasurementoftheopacityofemissionsdischargedintotheatmospherefromthecontroldevice-(-s-)-shallbeinstalled,calibrated,maintained,andoperatedbytheowneroroperatorsubjecttotheprovisionsofthisSection.L.ThetestmethodsandproceduresrequiredunderthisSectionareasfollows:1.ReferencemethodsinthcAr4-—-‘--—maxu.l40CFR60.72ADvendixAshallbeusedtodeterminecompliancewiththestandardsprescribedunderSubsectionA.aboveofthisSectionasfollows:a.Method5forconcentrationofparticulatematterandassociatedmoisturecontent.b.Method].forsampleandvelocityandvolumetricflowrate;andc.Method2forvelocityandvolumetricflowrate;andd.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrunshallbeatleastfourhours.Whenasingle.EAFissampled,thesamplingtimeforeachrunshallalsoincludeanintegralnumberofheats.Shortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Theminimumsamplevolumeshallbe4.5dscm(160dscf).R18-2-518.StandardsofperformanceforexistingkraftpulpmillsA.TheprovisionsofthisSectionareapplicabletothefollowingaffectedfacilitiesindraftkraftpulpmills:digestersystembrownstockwashersystem,multiple-effectevaporatorsystem,blackliquoroxidationsystem,recoveryfurnace,smeltdissolvingtank,limekiln,andcondensatestrippersystem.Inpulpmillsinwhichkraftpulpingiscombinedwithneutralsulfitesemichemicalpulping,theprovisionsofthisSectionareapplicablewhenanyportionofthematerialchargedtoanaffectedfacilityisproducedbythekraftpulpingoperation.Theproviion3ofthioCcctionarcapplicableonlytokraftpulpmillowhicharcctiatingoourcco.Nopersonshallcause,cuffcr,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanykraftpulpmillprocesssourcelocatedintotalquantitiesinexcessoftheamountscalculatedbyoneofthefollowingequationsoctforthbelow:73Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.lOP067where:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P°-40where“E”and“p”aredefinedasindicatedinA.l.a.abovePararaph1.ofthisSubsection..Forreferencepurposesonly,theequationssetforthaboveSubsectionB.ofthisSectionareplottedinAppendix11,Figure2.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.ForpurposesofthisflulcSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.Nooronahallcauc,cuffor,alloworpermittobeomittedto:mocphcreyaffectedfacilityunderthicDection,cmokcor.onwnicncccceu40ncrccntc1r3acitv.S.Theetandardofortotalreducedmoacuredachydrogen74ulfidc(II2)uti1iingMethodIIintheArioncTctingmanualarc:Nopersonshallcause,ouffcr,alloworpermitthedischargeof&totalreducedsulfurmeasuredashydrogensulfide75±Linexcessofthefollowingamounts:Fromanyrecoveryfurnace..anygaseswhichcontainH25inexcessof20ppmbyvolumecorrectedto%eightpercentoxygen.4--2.Fromanylimekilmkiln,anygaseswhichcontainH2Sinexcessof40ppmbyvolumecorrectedto4.t.npercentoxygen.B.Menierineemissionsaiepefa.ionsequi.edèythisGeei.enisazfollows:--.AnyowneroroperatorsubjecttotheprovisionsofthisSectionshallinstall,calibrate,maintain,andoperatethefollowingcontinuousmonitoringsystems:e-Acontinuousmonitoringsystemtomonitorandrecordtheopacityofthegasesdischargedintotheatmospherefromanyrecoveryfurnace,Thespanofthissystemshallbesetat70percentopacity.2..Acontinuousmonitoringsystem,tomonitorandrecordtheconcentrationofH2Semissionsdischargedintotheatmospherefromanyrecoveryfurnaceorlimekiln.ThespanshallbesetatH2Sconcentrationof50ppm.e-j.Acontinuousmonitoringsystemtomonitorandrecordthepercentofoxygenbyvolumeinthegasesdischargedfromanyrecoveryfurnaceorlimekiln.Thecontinuousmonitoringsystemshallbelocateddownstreamofthecontroldevice-(-e.)-fortherecoveryfurnaceorlimekiln,andallmeasurementsshallbemadeonadrybasis.Thespanofthissystemshallbesetat20percentoxygen.j,Foranylimekilnorsmelterdissolvingtankusingascrubberemissioncontroldevice:a.Amonitoringdeviceforthecontinuousmeasurementofthepressurelossofthegasstreamthroughthecontrolequipment.Themonitoringdevice4e.eshallbecertifiedtothemanufacturertobeaccuratewithinagage76pressureof±500pascals(ca.±2inchesofwatergagepressure).Amonitoringdeviceforthecontinuousmeasurementofthescrubbingliquidsupplypressuretothecontrolequipment.Themonitoringdeviceiotoshallbecertifiedbythemanufacturertobeaccuratewithin±15percentofdesignscrubbingliquidsupplypressure.Thepressuresensorortapiotoshallbelocatedclosetothescrubberliquiddischargepoint..ThcalthoughtheDirectormaybeconsultedforapprovalofalternativelocations.Gr.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ReferencemethodsinthoAriEonaTctingManual40CFR60,ADendixAexceptasprovidedunderCcctionR18-2-312,-shallbeusedtodeterminecompliancewithCubocotionA.and13.abovethisSectionasfollows:a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontent.b.Method1forsampleandvelocitytraverses.c.Method3forgasanalysis,andd.Method9forvisibleemissions.e.Method11fortotalreducedsulfurashydrogensulfide.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast60minutesandthesamplingrateshallbeatleast0.85dscm/hr(0.53dscf/min).,exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Watershallbeusedasthe:cleanupsolventinsteadofacetoneinthesamplerecoveryprocedureoutlinedinMethod5.FordeterminationofcompliancewiththisSection,particulatemeasurementsshallatleastbemadeontherecoveryfurnace-fe-)-,smeltdissolvingtank-fe-)-,andlimekiln-fe)-.aJJ,.concentrationsofparticulatematterfromthelimekilnandrecoveryfurnaceshallbecorrectedtoGvolumepercentoxygenandeightvolumepercentoxygen,respectively,when77theoxygenconcentrationsexceedthesevalues.R18-2-519.StandardsofperformanceforexistingstationaryrotatingmachineryA.TheprovisionsofthisSectionareapplicabletothefollowingaffectedfacilities:allstationarygasturbines,oil-firedturbines,orinternalcombustionengineswhicharccxictingcourcc.ThisSectionalsoappliestoaninstallationoperatedfortheurooseofproducingelectricormechanicalpowerwitharesultingdischargeofsulfurdioxideintheinsta].latioiVseffluentgases.ForpurposesofthisSection,theheatinputshallbetheaggregateheatcontentofallfuelswhoseproductsofcombustionpassthroughastackorotheroutlet.Compliancetestsshallbeconctructcdconductedduringoperationatthenormalratedcapacityofeachunit.Thetotalheatinputofalloperatingfuel-burningunitsonaplantorpremisesshallbeusedfordeterminingthemaximumallowableamountofparticulatematterwhichmaybeemitted.2.Thcctandardc—-‘-ticulatcmattcrundcrthicDcctionarc:Nopersonshallcause,cuffcr,alloworpermittheemissionofparticulatematter,causedbycombustionoffuel,fromanystationaryrotatingmachineryinexcessoftheamountscalculatedbyoneofthefollowingequationsprcccntcdbclow.jForequipmenthavingaheatinputrateof4200millionBtuperhourorless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=l.02Q0769where:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.78VQ=theheatinputinmillionBtuperhour.--2.Forequipmenthavingaheatinputrategreaterthan4200millionBtu/hr.,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=l7.OQ°432where“E”and“Q”havethesamemeaningasinA.2.o.i.aboveParagraoh1.ofthisSubsection.--p.Forreferencepurposesonly,thetwoequationsinA.2.a.aboveSubsectionC.ofthisSectionareplottedinAppendix11,Figure1.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheheatinputratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.Notwithstandingtheprovisionsof1UO2501,nopersonshallcause,suffer,alloworpermittobeemittedintotheatmospherefromanystationaryrotatingmachinery,smokeforanyperiodgreaterthantenconsecutivesecondswhichexceeds40percentopacity.Visibleemissionswhenstartingcoldequipmentshallbeexemptfromthisrequirementforthefirsttenminutes.3.incstandardforsulfurdioxideunderthisLeotionis.VThisDcationappliestoaninstallationoperatedforthepurposeuurpuusjriciectricormechanicalnnumwitharrii1innichn,rofsulfurdioxideintheinstallation’seLLiu..uI..Whenlowsulfuroilisfired,&.tationaryrotatingmachineryinstallationswhicharccxistingsourcesshallburnfuelwhichlimitstheemissionofsulfurdioxideto1.0poundpermillionBtuheatinputwhcnlowsulfuroilisfired.Whenhighsulfuroilisfired,tationaryrotatingmachineryinstallationswhichareexistingsourcesshallnotemitmorethan2.2pounds79ofsulfurdioxidepermillionBtuheatinputwhenhighsulfuroilisfired.4--nypermitissuedfortheoperationofanexistingsource,oranyrenewalormodificationofsuchapermit,shallincludeaconditionprohibitingtheuseofhighsulfuroilbythepermittee.,unlcssThisconditionmaynotbeincludedinthepermitiftheapplicantdemonstratestothesatisfactionoftheDirectorboththatsufficientquantitiesoflowsulfuroilarenotavailableforusebythesourceTandthatithasadequatefacilitiesandcontingencyplanstoinsurethatthesulfurdioxideambientairqualitystandardssetforthinR].8-2-202willnotbeviolated.Thetermsofthepermitmayauthorizetheuseofhighsulfuroilundersuchconditionsasarejustified.IncaseswherethepermitteeisauthorizedtousehighsulfuroilitshallsubmittotheDepartmentmonthlyreportsdetailingitseffortstoobtainlowsulfuroil.-Whentheconditionsjustifyingtheuseofhighsulfuroilnolongerexist,thepermitshallbemodifiedaccordingly.NothinginthisSectionshallbeconstruedasallowingtheuseofasupplementarycontrolsystemorotherformofdispersiontechnology.e.FornurposesofthisRule,lowsulfuroilmeansfueloilassthan0.90crccntweightofsulfurandhighsulfuroiliucipi.i.containing0.90nercentormoreDweightofsulfur.B.MonitoringofoperationsrequiredbythisOcotionisasfollows;.TheowneroroperatorofanystationaryrotatingmachinerysubjecttotheprovisionsofthisSectionshallrecorddailythesulfurcontentandlowerheatingvalueofthefuelbeingfiredinthemachine.L..TheowneroroperatorofanystationaryrotatingmachinerysubjecttotheprovisionsofthisSectionshallreporttotheDirectoranydailyperiodduringwhichthesulfurcontentofthefuelbeingfiredinthemachine80exceeds0.8percent.GrLThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.Thereference.onaToot.,IanualshallbeuseddeterminecompliancewiththestandardsprescribedinA.2.andA.3.aboveasfollowsSubsectionsC.throughII.ofthisSection.thefollowingreferencemethodsshallbeused:a.ReferenceMethod20in40CFRGO.AuoendixAfortheconcentrationofsulfurdioxideandoxygen.b.ASTMMethodD200071D-2880-87forthesulfurcontentofliquidfuelse±4.ASTMMethodD-1072-70ethesulfurcontentofgaseousfuels.ThosemethodsshallalsobeusedtocomplywithZ.2.above.TodeterminecomiliancewiththestandardsprescribedinSubsectionJ.ofthisSection.thefollowingreferencemethodsintheArizonaTestingManualshallbeused:a.ASTMMethodD-2880-87forthesulfurcontentoflicruidfuels.ASTMMethodD-1072-70forthesulfurcontentofcraseousfuels.R18-2-520.StandardsofperformanceforexistinglimemanufacturingplantsA.TheprovisionsofthisSectionareapplicabletothefollowingaffectedfacilitiesusedinthemanufactureoflime:rotarylimekilns,verticallimekilns,limehydrators,andlimestonecrushingfacilitieswhicharecicistingsources.ThisSectionisalsoapplicabletolimestonecrushingequipmentwhichexistsapartfromotherlimemanufacturingfacilities.Nopersonshallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanylimemanufacturinge.g.orlimestonecrushingfacilityintotalquantitiesinexcess81oftheamountscalculatedbyoneofthefollowingequationsoctforthbelow:Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:B=4.l0P067where:•E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P01-40where“E”and“P”aredefinedasindicatedin1..l.a.abovePararaDh1.ofthisSubsection.Forreferencepurposesonly,theequationsinA.l.aboveSubsectionB.ofthisSectionareplottedinAppendix11,Figure2.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.4.NotwithitandingtheprovicionoofRiO2501,noporoonohallcauoe,oüffcr,alloworpermittobeemittedintotheatmoopherefromanylimemuzacturingorlimeotonccruohingraciiityomokeorduotwhichexceedo4percentopacity..Fugitiveemissionsfromlimemanufacturingplantsshallbe82controlledinaccordancewithR18-2-404throughRl8-2-407.B.Monitoringofemi...onaofollowo;--.TheowneroroperatorsubjecttotheprovisionsofthisSectionshallinstall,calibrate,maintain,andoperateacontinuousmonitoringsystem,exceptasprovidedinB.2.bclowSubsectionG.ofthisSection,tomonitorandrecordtheopacityofthegasesdischargedintotheatmospherefromanyrotarylimekiln.Thespanofthissystemshallbesetat70percentopacity.TheowneroroperatorofanyrotarylimekilnusingawetscrubbingemissioncontroldevicesubjecttotheprovisionsofthisSectionshallnotberequiredtomonitortheopacityofthegasesdischargedasrequiredinfl.l.abovoSubsectionF.ofthisSection.GThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsintheArizonaTootingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewithCuboectionoA.andB.abovethisSectionasfollows:a.Method5fOrthemeasurementofparticulatematterT.b.Method1forsampleandvelocitytraversesT...c.Method2forvelocityandvolumetricflowrateT...d.Method3forgasanalysisT:e.Method4forstackgasmoisture,and.f.Method9forvisibleemissions.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast60minutesandthesamplingrateshallbeatleast0.85dscm/hr(0.53dscf/min),exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.833.Becauseofthehighmoisturecontent(40to05pcrccntbyvolume)oftheexhaustgasesfromthehydrators,intherangeof40to85percentbyvolume,theMethod5sampletrainmaybemodifiedtoincludeacalibratedorificeimmediatelyfollowingthesamplenozzlewhentestinglimehydrators.Inthisconfiguration,thesamplingratenecessaryformaintainingisokineticconditionscanbedirectlyrelatedtoexhaustgasvelocitywithoutacorrectionformoisturecontent.Eictracareohou..exerciciedwhencleaningtheciampletrainwiththeorificeinthicipociitionfollowingthetecitrunci.R18-2-521.StandardsofperformanceforexistingnonferrousmetalsindustrysourcesA.TheprovisionsofthisSectionareapplicabletothefollowingaffectedfacilities:mines,mills,concentrators,cruhers,screens,materialhandlingfacilities,fineorestorage,dryers,roasters,andloaderswhicharccxiotinaciourceci.Nopersonshallcause,ouffar,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanyprodesssourcesubjecttotheprovisionsofthisSectionintotalquantitiesinexcessoftheamountscalculatedbyoneofthefollowingequationscictforthbelow:Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:where:E=4.1OP0.67E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightgreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbe



# Li Li El IFj 

# El I Ij,-‘—.—84determinedbythefollowingequation:E=where“E”andaredefinedasindicatedinA.l.a.o.bovcPararath1.ofthisSubsection..Forreferencepurposesonly,theequationsinA.i.aboveSubsectionB.ofthisSectionareplottedinAppendix11,Figure2.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedoff.totwodecimalplaces.ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.theaichargeof.2ubjcctto.cmiooionofromanyminingpropertyproceocornonpointthprovioionofthicCection,ductoremokethatcxcccdcuperrmrrrnr,T-—s-———.1Nopersonshallcause,cuffcr,alloworpermittobedischargedintotheatmospherefromanydryerorroastertheoperatingtemperatureofwhichexceeds7000F.,reducedsulfur,whichincludocculfurequivalentfromalloulfuromiccioncincludingbutnotlimitedtooulfurdianidc,culfurtriotideandculfuricacid,inexcessoftenpercentofthesulfurenteringtheprocessasfeed.Reducedsulfurincludessulfureauivalentfromallsulfuremissionsincludingsulfurdioxide,sulfurtrioxide.andsulfuricacid.C.MonitoringofoperationcrequiredbythicCcctionarc;TheowneroroperatorofanyminingpropertysubjecttotheprovisionsofthisSectionshallrecordthedailyprocessratesandhoursofoperationofallmaterialhandlingfacilities.Acontinuousmonitoringsystemformeasuringsulfurdioxideemissionsshallbeinstalled,calibrated,maintainedandoperatedbytheowner85

# suitable methods and shall be confirmed by a material balance over thefossilfuel fired system. R18-2-525. Standards of performance for existing dry cleaning

plants Deetion is applicable e all dry elean..n slants wuien aEc

sources.

B,- Dry cleaning plants utilizing chlorinated---



# person shall conduct any dry cleaning operation using

solvents without minimizing organic solvent emissions

including but not limited to the use of an adequately

maintained activated carbon absorber or other equally

device. G-. 

# Dry cleaning plants utilizing petroleum solvents; No person shall

operate any dry cleaning establishment using petroleum solvents other than

&tcddard, l0 (safety solution) or other non-photochemicaljy reactive solvents

without reducing solvent emissions by at least 90 percent. For purposes of

this Subsection, a photochemically reactive solvent shall be any solvent with

an aggreate of more than twenty oercent of its total volume conmosed of the

chemical comDounds classified in Paragraphs 1. through 3. of this Subsection,

or which exceeds any of the following percentage composition limitations,

referred to the total volume of solvent:

A combination of the following types of compounds having an

olefinic or cyclo-olefinic tyoe of unsaturation-- 

# hydrocarbons, alcohols.

aldehydes, esters, ethers. or ketones: five vercent.

A combination of aromatic compounds with eight or more carbon

atoms to the molecule exceDt ethylbenzene: eight percent.

A combination of ethylbenzene. )cetones having branched hydrocarbon No

chlorinated synthetic

by good modern practices

sized and properly

effective control

structures, trichiorethylene or toluene: 20 iercent.

94Whereastack,ventorotheroutletisatsuchalevelthatfumes,gasmist,odor,smoke,vapororanycombinationthereofconstitutingairpollutichargedpollutionisdischargedtoadjoiningproperty,theDirectormayrequiretheinstallationofabatementequipmentorthealterationofsuchstack,vent,orotheroutletbytheowneroroperatorthereoftoadegreethatwilladequatelydilute,reduceoreliminatethedischargeofairpollutiontotheadjoiningproperty.R18-2-526.StandardsofperformanceforandblastingoperationsNopersonshallcauseorpermitsandblastingorotherabrasiveblastingwithoutminimizingdustemissionstotheatmosphereythroughtheuseofgoodmodernpractices.,puchaciExamplesofgoodmodernpracticesincludewetblastingandtheuseofeffectiveenclosureswithnecessarydustcollectingequipment,oroncracccptablcmco.nci.R18-2-527.StandardsofperformanceforpraypaintingoperationsA.Nopersonshallconductanyspraypaintoperationwithoutminimizingorganicsolventemissionsbygoodmodcrnpracticca.Suchoperations.otherthanarchitecturalcoatingandspotpainting...shallbeconductedinanenclosedareaequippedwithcontrolscontainingnolessthan96percentoftheoverspray.B.Nopersonshalleither:cmployEmploy,apply,evaporateordryanyarchitecturalcoatingcontainingphotochemicallyreactivesolventsforindustrialorcommercialpurposes,matarialcontainingphotochamicallyrcactivaciolvcntciorcihallthinThinordiluteanyarchitecturalcoatingwithaphotochemicallyreactivesolvent.C.Noperooncihall,duringanyoncday,dicipoocofatotalofmarcmdonchalfgallonciofanytopormittheevaporationofti95

# purooses of Subsection B. of this Section, a photochemicallv reactive solvent

shall be any solvent with an aregate of more than twenty percent of its

total volume composed of the chemical compounds classified in ParagraDhs 1.

through 3. of this Subsection. or which exceeds any of the following

Dercentage composition limitations, referred to the total volume of solvent:

A combination of the following types of compounds having an

plefinic or cvclo-olefinic type of unsaturation-- 

# hydrocarbons, alcohols,

aldehydes, esters, ethers, or ketones: five percent.

L.. A combination of aromatic compounds with eight or more carbon

atoms to the molecule except ethylbenzene: eight tercent.

A combination of ethvlbenzene. ketones having branched hydrocarbon

structures, trichlorethylene or toluene: 20 rercent.

p. Whenever any organic solvent or any constituent of an organic

solvent may be classified from its chemical structure into more than one of

the groucs or organic comDounds described in Subsection C.. Paragraphs 1.

through 3. of this Section, it shall be considered to be a member of the group

having the least allowable percent of the total volume of solvents.

R18-2.-528. Standards of performance for existing aimxionium sulfide

manufacturing plants

k. The provisions of this Section are applicable to the following

affected facilities in ammonium sulfide manufacturing plants: Culfide sulfide

unloading facilities, reactor-absorber, bubble cap scrubbers, and fume :4V

incinerator. Thio i applica.blc to all ammonium ulfidc manufacturing plants

undcr Ctata of Arizona -luriodiction which arc cxioting aourcco.

B. inc otanaara icr trticuiatc mattcr arc ac to.LLow;

Notwithotanding thc proviciona of Ccction RiO 2 0l, no person

shall cause, cuf fcr, allow or permit to be emitted into the atmosphere, from

any type of incinerator or other outlet smoke, fumes, gases, particulate

96

# matter or other gas-borne material, the opacity of which exceeds 20 percent.--. 

# No person shall cause, cuffcr, allow or permit to be emitted into

the atmosphere from any emission point from any incinerator, or to pass a

convenient measuring point near such emission point, particulate matter of

concentrations in excess of 0.1 grain per cubic foot, based on dry flue gas at

standard conditions, corrected to 12 percent carbon dioxide.

Tho otandard for hydrocn oulfido ic a followo- No person shall

allow hydrogen sulfide to be emitted from any location in such mariner and

amount that the concentration of such emissions into the ambient air at any

occupied place beyond the premises on which the source is located exceeds 0.03

parts per million by volume for any averaging period of 30 minutes or more.

Where a stack, vent or other outlet is at such a level that fumes,

gas mist, odor, smoke, vapor or any combination thereof constituting air

pollution are discharged to adjoining property, the Director may require the

installation of abatement equipment or the alteration of such stack, vent, or

other outlet by the owner or operator thereof to a degree that will adequately

dilute, reduce or eliminate the discharge of air pollution to adjoining

property. E. Monitoring of opcrntions rcquircd by thio Ocation io go followo;. 

# The owner or operator of any ammonium sulfide tailgas incinerator

subject to the provisions of this Section shall do both of the following:

e-.- 1. Install, calibrate, maintain, and operate a flow measuring device

which can be used to determine either the mass or volume of tailgas charged to

the incinerator. The flow measuring device shall have an accuracy of ± & five

percent over its operating range.

2.. Provide access to the tailgas charged so that a well-mixed

representative grab sample can be obtained.

The test methods and procedures required by this Section are as

97

# LI follows:



# fl 1. The reference methods in tho Arizona Tooting anual 40 CFR 60.

Li ADoendix A shall be used to determine compliance with the standard.2 prescribed

in Eulxicctionc B. and C. above this Section as follows:

a. Method 5 for the concentration of particulate matter and the

associated moisture contenti-..

b. Method 1 for sample and velocitytraversec. Method 2 for velocity and volumetric flowrated. Method 3 for gas analysis and calculation of excess air, using the

integrated sample technique; .ncL

e. Method 11 shall be used to determine the concentration of H 2 S and



# El Method 6 shall be used to determine the concentration of

2. For Method 5, the sampling time for each run shall be at least 60



# j minutes and the minimum sample volume shall be 0.85 dsctn (30.0 dscf) except

that shorter sampling times and smaller sample volumes, when necessitated by

process variables or other factors, may be approved by the Director.



# ] 3. Particulate matter emissions, expressed in g/dscm, shall be

corrected to 12 percent CO 2 by using the following formula:

C 12 = 12c %C0 2

where: C 12

= the concentration of particulate matter corrected to 12 percent

Cc 2

, 98

# c = the concentration of particulate matter as measured by Method 5,

and %C0 2

= the percentage of CO 2 as measured by Method 3, or when

applicable, the adjusted outlet CO 2 percentage.

4. If Method 11 is used, the gases sampled shall be introduced into

the sampling train at approximately atmospheric pressure. Where fuel gas lines

are operating at pressures substantially above atmosphere, this may be

accomplished with a flow control valve. If the line pressure is high enough to

operate the sampling train without a vacuum pump, the pump may be eliminated

from the sampling train. The sample shall be drawn from a point near the

centroid of the fuel gas line. The minimum sampling time shall be 10 minutes

and the minimum sampling volume 0.01 dscm (0.35 dscf) for each sample. The

arithmetic average of two samples of equal sampling time shall constitute one

run. Samples shall be taken at approximately 1-hour intervals. For most fuel

gases, sample times exceeding 20 minutes may result in depletion of the

collecting solution, although fuel gases containing low concentrations of

hydrogen sulfide may necessitate sampling for longer periods of time.

5. If Method 5 is used, Method 1 shall be used for velocity traverses

and Method 2 for determining velocity and volumetric flow rate. The sampling

site for determining CO 2 concentration by Method 3 shall be the same as for

determining volumet±ic flow rate by Method 2. The sampling point in the duct

for determining SO 2 concentration by Method 3 shall be at the centroid of the

cross section if the cross sectional area is less than 5 m 2 (54 ft2) or at a

point no closer to the walls than 1 m (3.28 feet> if the cross sectional area

is 5 m 2 or more and the centroid is more than one meter from the wall. The

sample shall be extracted at a rate proportional to the gas velocity at the

sampling point. The minimum sampling time shall be 10 minutes and the minimum

sampling volume 0.01 dscm (0.36 dscf) for each sample. The arithmetic average

99

# of two samples of equal sampling time shall constitute one run. Samples shall

be taken at approximately one-hour intervals.

R18-2-529. Standards of performance for cotton gins

A. Thc provisions of this Dcotion arc applicable to all now or

existing cotton gins in the Dtate of Arizona.- 

# Fugitive dust, lint, balls, cotton seed or other material emitted

from e a cotton gin or lying loose in 1±e, 

# yard shall be collected and

disposed of in an efficient manner or shall

be treated in accordance with Ccctions Rl8-2-404 through Rl8-2-407.--. 

# Cotton gins shall conform to Ceotion 1U8 2 501, Visibic emiSSions;

general, at all times. n opacity of 40 percent or less shall exempt the

source from mass emissions testing. In the event that the cotton gin does not

comply with the 40 percent opacity standard, the owner or operator may request

the permission of the Director to perform a mass emissions test observed by a

representative of the Bureau of Air Quality Control Department. Successful

completion of this test will result in an adjustment to the simultaneous

opacity standard in accordance with Ceotion fllO 2 501.C R18-2-502.D.

No person shall cause, suffer, allow, or permit the discharge of

particulate matter into the atmosphere in any one hour from any cotton gin in

total quantities in excess of the amounts calculated by one of the following

equations. set forth below.

j For process sources having a process weight rate of 60,000 pounds

per hour (30 tons per hour) or less, the maximum allowable emissions shall be

determined by the following equation:

E= 

# 4.10P 067

where: E= 

# the maximum allowable particulate emissions rate in pounds-mass

per hour. 100

# P= 

# the process weight rate in tons-mass per hour.

For process sources having a process weight rate greater than

60,000 pounds per hour (30 tons per hour), the maximum allowable emissions

shall be determined by the following equation:

E= 

# 55.0P 0 ’-40

where EU and “P” are defined as indicated in A.3.a. aovc Paragraph 1. of

this Subsection. The test methods and procedures required by this Section are as

follows: 1. The reference methods in the Arizona Testing Manual and 40 CFR 60,

Aptendix A shall be used to determine compliance with Cuboction A. abovc this

Section as follows:

a. Method A-2 for the measurement of particulate matter

b. Method 1 for sample and velocity traverses 7 -

c. Method 2 for velocity and volumetric flowrated. Method 3 for gas analysis

e. Method 9 for visible emissions.

2. For Method A-2, the sampling time for each run shall be at least

60 minutes and the sampling rate shall be at least 0.85 dry standard cubic

meters per hour (0.53 dry standard cubic feet per minute), except that shorter

sampling times, when necessitated by progress variables or other factors, may

be approved by the Director. :

R18-2-530. Standards of performance for un1assified sources

No existing source which is not otherwise subiect to standards of

performance under this Article or Article 8 or 9 shall cause or permit the

emission of pollutants at rates greater than the following:

For particulate matter discharged into the atmosphere in any one

hour from any unclassified process source in total quantities in excess of the

101

# amounts calculated by one of the following equations:

a. For process sources having a orocess weight rate of 60.000 pounds

er hour (30 tons per hour) or less, the maximum allowable emissions shall be

determined by the following equation:

= 4.lOP°’ 67

where: E = the maximum allowable particulate emissions rate in rounds-mass er

hour. P = the process weight in tons-mass per hour.

k For process weight rate reater than 60.000 rounds er hour (30

tons er hour), the maximum allowable emissions shall be determined by the

following equation: = 55.OPO.h’-40

where “E” and “P” are defined as indicated in Subparagraph a. of this

Paragraph.. 

# Sulfur dioxide-- 

# 600 parts per million.

3. Nitrogen oxides exrssed as N02-- 

# 500 parts er million.

For ourooses of this Section. the total process weight from all

similar units employing a similar tvoe process shall be used in determining

the maximum allowable emission of particulate matter.

C. For reference only the ecuations in Subsection A.. Paragraoh 1. of

this Section are olotted in Aooendix 11. Figure 2. The emission values

obtained from the graph are aooroximately correct for the orocess weight rates

shown. However, the actual values shall be calculated from the apolicable

ecuations and rounded off to two decimal olaces.

0. No oerson shall emit gaseous or odorous materials from equioment.

ooerations or premises under his control in such cuantities or concentrations

as to cause air pollution. 102

# No person shall ooerate or use any machine, ecmioment or other

contrivance for the treatment or processing of animal or vegetable matter,

separately or in combination, unless all gaseous vapors and gas entrained

effluents from such operations, equiPment or contrivance have been either:

incinerated to destruction. as indicated by a temperature

measuring device, at not less than 1,200 degrees Fahrenheit if constructed or

reconstructed prior to January 1, 1989, or 1600 degrees Fahrenheit with a

minimum residence time of 0.5 seconds if constructed or reconstructed

thereafter; or Passed through such other device which is designed, installed and

maintained to prevent the emission of odors or other air contaminants and

which is aroved by the Director.

P. Materials including solvents or other volatile compounds paints,

acids, alkalies, pesticides. fertilizers and manure shall be processed,

stored. used and transported in such a manner and by such means that they will

not evaporate, leak, escape or be otherwise discharged into the ambient air so

as to cause or contribute to air pollution. Where means are available to

reduce effectively the contribution to air pollution from evaporation, leakage

or discharge. the installation and use of such control methods devices, or

eauipment shall be mandatory.

G. Where a stack, vent or other outlet is at such a level that fumes,

gas mist, odor, smoke. vapor or any combination thereof constituting air :

pollution are discharged to adpininq property, the Director may require the

installation of abatement equipment or the alteration of such stack. vent or

other outlet by the owner or operator thereof to a decree that will adecuately

dilute, reduce or eliminate the discharge of air pollution to adjoining

property. H. No person shall allow hydrogen sulfide to be emitted from any

103

# L location in such manner and amount that the concentration of such emissions

into the ambient air at any occupied olace beyond the premises on which the

source is located exceeds 0.03 Darts per million by volume for any averaing

period of 30 minutes or more.



# U L. No person shall cause. allow or permit discharge from any

stationary source carbon monoxide emissions without the use of comn].ete

secondary combustion of waste gases generated by any process source.

No person shall allow hydroen cyanide to be emitted from any

location in such manner and amount that the concentration of such emissions

into the ambient air at any occupied place beyond the premises on which the

source is located exceeds 0.3 parts per million by volume for any averaging

neriod of eight hours.

No person shall allow sodium cyanide dust or dust from any other



# j solid cyanide to be emitted from any location in such manner and amount that

the concentration of such emissions into the ambient air at any occupied vlace

beyond the premises on which the source is located exceeds 140 micrograms er

cubic meter for any averaging period of eight hours.

ks.. No owner or operator of a facility enaged in the surface coating

of miscellaneous metal Darts and products may operate a coating application

system subiect to this Section that emits volatile organic comiounds in excess

of any of the following:. 

# 4.3 pounds per gallon (0.5 kilograms per liter) of coating.

excluding water, delivered to a coating anplicator that aplies clear

coatings. 3.5 pounds per gallon (0.42 kilograms per liter) of coating.

excluding water delivered to a coating applicator in a coating application

system that is air dried or forced warm air dried at temoeratures uo to 194°F

(90°c) . 

# 104. 

# 3.5 pounds per gallon (0.42 kilograms er liter) of coating,

excluding water, delivered to a coating applicator that applies extreme

performance coatings.

j 3.0 pounds er gallon (0.36 kilograms oer liter) of coating,

excluding water. delivered to a coating applicator for all other coatings and

coating application systems.

K If more than one emission limitation in Subsection L. of this

Section aDDlies to a svecific coating, then the least stringent emission

limitation shall be poplied.

All VOC emissions from solvent washings shall be considered in the

emission limitations in Subsection I. of this Section, unless the solvent is

directed into containers that prevent evaooration into the atmosohere.

105

# ARTICLE 6. EMISSIONS FROM MOBILE POINT SOURCES

(NEW AND EXISTING)

Rl8-2-601. Conoral Classification of mobile sources. 

# This Article is applicable to mobile sources which either move

while emitting air contaminants or are frequently moved during the course of

their utilization, but are not classified as motor vehicles, agricultural

vehicles, or agricultural equipment used in normal farm operations.

L. Unless otherwise specified, no mobile source shall emit smoke or

dust the opacity of which exceeds 40 percent.

R18-2-602. Off-road machinery

A. Of f road machincry chall include trucka (cuch aa mining trucka),

rrrnrr1 rollera, and other conotruction and minin machinery not

norally driven on a completed public roadway.

B-. 

# Notwithctanding the provicionc of RiO 2 Cd, no person shall

cause, cuff cr, allow or permit to be emitted into the atmosphere from any of f

road machinery, smoke for any period greater than ten consecutive seconds, the

opacity which exceeds 40 percent. Visible emissions when tarting cold

equipment shall be exempt from this requirement for the first ten minutes.

B. Off-road machinery shall include trucks, graders, scrapers,

rollers, locomotives and other construction and mining machinery not normally

driven on a comoleted public roadway.:‘



# R18-2-603. Heater-planer units

No person shall cause, cuf far, allow or permit to be emitted into the

atmosphereT from any heater-planer operated for the purpose of reconstructing

asphalt pavements, smoke the opacity of which exceeds 20 percent. However 1

three minutes’ upset time in any one hour will shall not constitute a

violation of this Rule Section. 106

# Rl8-2-604. Roadway and site cleaning machineryfl 

# •1——, 

# ——————..—s‘——___—4



# icul..

be kept-— 

# becoming airborne. Duct and othcr particulo.tec chall

by employing duct ouppreccanto, wetting down, vacuum

devicec or by other rcaoonablc meanc. Darth or other material may be removed

from paved ctrect onto which earth or other material hac been trancportcd by

trucking or earth moving equipment, crocion by water, or by other meanc.

B-r. 

# Notwithotanding. the proviciono of RiO 2 C0l, no person shall

cause, cuffcr, allow or permit to be emitted into the atmosphere from any

roadway and site cleaning machinery, smoke or dust for any period greater than

ten consecutive seconds, the opacity of which exceeds 40 percent. Visible

omokc. emissions when starting cold equipment shall be exempt from this

requirement for the first ten minutes.. 

# In addition to complying with Subsection A. of this Section, no

person shall cause. allow or permit the cleaning of any site. roadway, or

alley without taking reasonable precautions to prevent iDarticulate matter from

becoming airborne. Reasonable precautions may include applyin dust

suppressants. Earth or other material shall be removed from paved streets onto

which earth or other material has been transported by trucking or earth moving

ecmiment, erosion by water, or by other means.

R18-2-605. Asphalt or tar kettles. 

# No person shall cause, allow or permit to be emitted into the

atmosphere from any asohalt or tar kettle, smoke for any period greater than

ten consecutive seconds. the opacity of which exceeds 40 percent.

B. In addition to complying with Subsection A. of this Section, Ne no

person shall cause, allow or permit the operation of an asphalt or tar kettle

without minimizing air contaminant emissions by utilizing all rcaoonably

107

# availabic of the following control measures

. 

# including thc The control of temperature recommended by the

asphalt or tar manufacturer,-

The, operation of the kettle with lid closed except when

charging..

I,.. the The pumping of asphalt from the kettle or the drawing of

asphalt through cocks with no dippingT..

j. 

# the The dipping of tar in an approved

manner



# the The maintaining of the kettle in clean, properly adjusted, and

good operating conditionT

the Ib firing of the kettle with liquid petroleum gas or other

fuels acceptable to the Director. :‘



# 108