# Bioassays of



# Vero Beach Mu nicipal Power Plant

Indian Ri ver County

NPDES #FL0002984

Sampled November 12, 2003

April 2004

Biology Section

Bureau of Laboratories

Division of Resource Asses sment and Management

Quality Manual No. 870346G

NELAC Certification No. E31780

### Vero Bea c h Munici pal Po wer Pla n t, 100 17 th 

### Street, Vero Bea c h, Indian River County, Florida

, NPDES #FL 0 0029 84. Effluent sampl e s f o r this fa cility were coll ecte d on Novem b er 12, 200 3.



## Introduction

This mu nici p a l power pla n t consi s ts of five (5) po we r-gene rating u n i ts. Units #1, #2, and #3

having nam e p late rating s, respe c tively, of 12.5, 16.5, and 24 me ga watts (M W), use a total of 217

million gallo n s per d a y (M GD) of water from the I ndia n River a s on ce-th r o ugh n on-conta c t co oling

water whic h is disc harged (without treat ment) back to the Indian River, a Class III Marine surfac e

water, via out falls D-011, D-012, an d D-0 13 (for merly outfalls 00 1, 002, and 0 0 3 ) . Coolin g wat e r

for the Unit # 4 (No Nam e p l ate Rating ) cooling to we r i s treate d wa stewater o b tai ned from the City

of Vero Beach Wa stewater Treat me nt Plant (WWTP). Cooli ng towe r blowd o wn from Unit #4 is

discha rge d b a ck to the WWTP. Boiler blowdo wn, from Units # 1 , #2, #3, and # 4 , is also

discha rge d to the WWTP. Unit #5 is a combine d cycl e comb ustio n turbine, with a namepl ate

rating of 38 M W , equip ped with a clo s e d auxiliary co oli ng wate r syst em. Wa stewa t er from Unit #5

is coll ecte d in a stora ge tan k , treated, an d discha rge d to the WWTP

. There is n o discha rge fro m

Unit #5 to wat e rs of the State unless otherwi s e authorized within the permit. The facility has a

fuel-oil contai nment area (D-OB) from which stor m w a t er can be discha rge d to the Indian Rive r.

There are al so roof and ya rd drain s (D-OS1 throu gh D-OS6) fro m whi c h sto r m w ater ca n be

discha rge d to the Indian Ri ver (facility informat io n prov ided by Dr. P h il Kane, Allen Hub bard an d

Michael Eckoff, FDEP, Orlando).



## Methods

Sample s we re colle cted from the NPDE S samplin g p o int (fuel oil containme n t area) by Dr. Phil

Kane and Ste v e Kent (FDE P Central District-O rla ndo ) followin g DE P-SOP-0 01/0 1 FS 2400

Wa stewater Sampling. All DEP SOP’s a r e availabl e o n the web at:

http://www.flo r idad ep.o r g/la bs/qa/ sop s .ht m

The toxicity and algal g r o w th potential tests di sc usse d in this repo rt were pe rform ed followi ng

internal DEP SOP’s TA07_ 01,TA07_ 02, and TA08 _01 through TA0 8_06. All internal DEP SOP’s

are availa ble on the we b at: http://www.fl orida dep.o r g/l abs/ c gi-bin/sop/bio s op.a s p



## Toxicit y Test Results

Test s we re p e rform ed Novembe r 13-17, 2003.

Ceri oda phni a

dubia 96 -h r acute d e finitive bioa ssay – Not Toxic; L C 50 

### > 100%, 0% mortality in

100% sa mple at 96 hours

Pim ephales p r om elas 9 6 -h r acute definitive bioassay – Not Toxic; LC 50 

### > 100%, 0% mortality in

100% sa mple at 96 hours

See Table 1 f o r bioa ssay b ench sh eets.



## Algal Gro w t h Potent ial

The effluent Algal Gro w th Potential (AG P ) wa s 0.110 mg dry wt/L o f Pseudo kirch neriell a

s u bc ap ita t a , formerly k n own as Se le na s t r u m c a p r ic or nu tu m . Rasch ke and Shultz (198 7) fou nd

that AGP values a bove 5. 0 mg dry wei ght/L rep r e s e n t a “pro blem ” thre shol d for fresh re ceivi ng

waters, implyi ng nutrie n t en rich ment. The effluent sam p le value was less tha n this "problem"

threshold. Th e “problem ” thre shol d for marin e re ceiv ing wate rs i s 10 mg dry wt/ L (pe r sonal

comm uni cati on- Raschke, USEPA, 1987). Although an AG P test with a salt wat e r speci e s was not

perfo rmed, th e pre s um ptio n is that the result would h a ve also b e e n less than th e "probl em"

threshold of 1 0 mg dry wei ght/L in marin e waters. Th e sampl e value wa s le ss t han the predi cted



## 2

### AGP values b a se d on the i norg ani c nitro gen an d orth o-ph osphate conte n t of the sample (Tabl e

2). The difference betwee n actual a nd predi cted AG P values that are g r eate r than the "pro bl em"

threshold can sometime s b e use d as evi den ce of inhi bition; however, for value s belo w the

probl em thre shold, this tool shoul d be u s ed with c autio n, as the differen c e may be attributable to

variability in the method ra ther than a c tu al algal growt h inhibition.

See Table 2 f o r AGP re sult s.



## Chemistr y Results

Total re sidu al chlori ne an d total ammoni a were not de tected in the bioa ssay sam p le in the

laboratory. Total ammoni a was al so n o t detecte d in the sampl e pre s erve d sp ecifi c ally for

ammoni a ana lysis. Aluminu m , coppe r, an d zin c we re d e tected in the effluent at levels above th e

method dete c tion limits, but below the p r actical qua ntitation limit.

See Table 3 f o r re sult s of analytes dete c ted in the effluent.

See Appen di x 1 for a com p lete list of ch emical a nalyses pe rform e d

.



## Conclusion

The effluent sample s coll ected from this facility on Nov e mbe r 12, 20 03, did not sh ow a c ute

toxicity to eith er test spe c ie s duri ng the 9 6 -ho u r bi oa ssay tests. The effluent AGP result wa s less

than the "pro blem” thresho l d for fresh re ceiving waters.



## Literature Cited

Malo ne y, T

. E., W

. E. Miller, and D. T. Specht. 1974. T he Marin e Alga l Assa y Pr oced ure: Bottle T e st.

National Env i ronmental Research Center Office of Researc h and Dev e lopm ent. U. S. EPA, Corvallis,

Oregon. 43 p.

Miller, W

. E., T. E. Malone y

, a nd J. C. Greene. 1978. T he Sele nastru m c apric ornutu m Printz algal

assa y bottle te st. EPA-600/9-78-0 18. U. S. EPA, Cincin nat i, Ohio. 126 p.



### Miller et al. 1990. The Acute and Chro nic To xicit y

of Amm onia to Marin e Fish a nd Inve rteb ra tes

, Archive s of Environm ental Cont ami natio n and Toxicol ogy 19:40-48.

Ra schke, R. L. and D. A. Schultz. 198 7. The use of the algal gro w th potential test for data

asse ssm ent. J. Wat. Poll. Cont. Fed. 5 9 (4 ): 222-2 2 7

.

W eber, C. I. 1993. Metho d s for measuri ng the acute to xicit y of efflue nts to fresh w a t er an d marin e

orga nisms. 4th editi on. EPA/600/4-9 0 /02 7

. U. S. EPA, Cincin nati, Ohio. 216 pp.

USEPA. 200 0. Nutrie nt Criteri a T e chnical Gu ida n ce Man u a l – River a nd Streams. EPA-82 2-B-00- 002.

USEPA. 200 2. Short-term methods for estim a ting the c h ron i c tox i c i t y of effl uents an d rece iving w a ters

to fresh w ater o r gan isms. 4 th 

### E d ition. EPA- 821-R-02- 013



## 3Table1.continuedFacility:VeroBeachMunicipalPowerPlantNPDES#:FL0002984Analysts:JoshuaAyresLocation:10017thStreet, VeroBeachContact/District:PhilKane/CentralJames DanielsCounty:IndianRiverTesttype:acute definitive 96hoursrenewalMarshall FairclothSampleCollectionDate:11/12/2003Time:0930#tests:2ReceivingWater:IndianRiverChristaPieriniTest BeginningDate:11/13/2003Time:1430Chlorination Type:nonchlorinatedClassIII MarineTest EndingDate:11/17/2003Time:1330FDEP SOP#:TA07_01Page1of4Reviewer:Julie EspyOrganism:CeriodaphniadubiaLifestage:<24hoursAFeeding:YCT/AlgaeConductivity0-48 hoursChamber size:30mLFood Batch #:3/20UncorrectedJob number:TLH-2003-11-13-42Sample/DiluentSURVIVAL# AlivepHBTemperatureCDO(mg/L)μmhos/cmsamplenumber:716209ConcentrationsVolume(mL)0 hr24hr48hr0 hour24 hour48 hour0 hour24hour48hour0hour24 hour48 hour0 hour48hourControl A0/205558.2-8.224.0-24.08.1-8.2170185Control B0/20555--8.2--24.0--7.9-180ControlC0/20555--8.2--24.1--7.9-182ControlD0/20555--8.2--24.0--8.0-1906.25%A1.25/18.755558.2-8.324.4-24.28.0-8.4170195Total Residual CL2mg/LMethod6.25%B1.25/18.75555--8.3--24.0--8.5-190Field (100%sample):--6.25%C1.25/18.75555--8.3--24.1--8.4-195Lab (100%sample):<0.03Hach6.25%D1.25/18.75555--8.3--24.0--8.3-207Controlwater:<0.03Hach12.5%A2.5/17.55558.2-8.324.5-24.47.7-8.217019012.5%B2.5/17.5555--8.3--24.3--8.5-190AmmoniaTotal (mg/L)Unionized(mg/L)12.5%C2.5/17.5533--8.3--24.0--8.4-198Controlwater:<0.017<0.01712.5%D2.5/17.5555--8.3--24.2--8.3-206100%Sample:<0.017<0.01725%A5/155558.3-8.424.4-24.07.8-8.217019525%B5/15555--8.4--24.0--8.1-192Alk&HardnessAlkalinity(mg/L)Hardness(mg/L)25%C5/15555--8.4--23.9--8.1-194Controlwater:818825%D5/15555--8.4--24.1--8.1-208100%Sample:616150% A10/105558.3-8.324.3-24.07.8-8.117018050%B10/10555--8.3--24.0--8.1-187DSalinityppt50%C10/10555--8.3--24.2--8.1-182100%sample:<150%D10/10555--8.3--24.1--8.3-205Control:<1100%A20/05558.4-8.324.5-24.37.9-8.3165180DSalinitybased onconductivityand temperature.100%B20/0555--8.3--24.2--8.3-171100%C20/0555--8.3--24.0--8.1-183100%D20/0555--8.3--24.1--8.1-179AOrganismsfedprior totestingand beforerenewal.RoomTemperature range for the testperiod was23.0-24.5°C.BTemperaturesofroomandtestincubator werecontinuouslyrecordedon astripchart.Incubator #3temperature range for the testperiod was23.0- 24.5°C.CDO= Dissolved OxygenLightIntensity duringthe testwas50-100footcandles.Photoperiod duringthe testwas16hoursoflight:8 hoursofdark.Data recordedduring the 96-houracute definitive bioassaysofasampleofeffluentfromtheVero BeachMunicipalPower Plant,100 17th Street, VeroBeach, Indian RiverCounty,Florida,NPDES#FL0002984, performedfrom13 to 17November 2003.Data TranscriptionVerificationLIMSdate: 1/30/04by: James Daniels/JoshAyresFacilityType:Municipal Power Plant4Table 1.continuedFacility:VeroBeachMunicipalPowerPlantNPDES#:FL0002984Analysts:Joshua AyresLocation:10017th Street,Vero BeachContact/District:Phil Kane/CentralJamesDanielsCounty:Indian RiverTesttype:acute definitive96 hoursrenewalMarshall FairclothSample Collection Date:11/12/2003Time:0930#tests:2Receiving Water:Indian RiverChristaPieriniTestBeginning Date:11/13/2003Time:1430Chlorination Type:nonchlorinatedClassIIIMarineTestEnding Date:11/17/2003Time:1330FDEPSOP#:TA07_01Page2of4Reviewer:Julie EspyOrganism:CeriodaphniadubiaLifestage:<24hoursAFeeding:YCT/AlgaeConductivity48 -96 hoursChamber size:30mLFood Batch#:2/19UncorrectedJob number:TLH-2003-11-13-42Sample/DiluentSURVIVAL#AlivepHTemperatureBCDO(mg/L)μmhos/cmsample number:716209ConcentrationsVolume(mL)48hr72hr96hr48hr72 hr96hr48 hr72hr96hr48hr72 hr96 hr48hr96 hrControlA0/205558.3-8.024.0-24.17.8-7.8165185ControlB0/20555--8.1--24.1--7.7-190Control C0/20555--8.1--24.0--7.7-190Control D0/20555--8.1--24.0--7.6-2056.25 %A1.25/18.755558.4-8.224.1-24.07.8-7.7165210TotalResidualCL2mg/LMethod6.25 %B1.25/18.75555--8.2--24.0--7.6-200Field (100%sample):--6.25 %C1.25/18.75555--8.2--24.0--7.6-200Lab (100%sample):<0.03Hach6.25 %D1.25/18.75555--8.2--24.0--7.6-205Controlwater:<0.03Hach12.5%A2.5/17.55558.4-8.224.0-24.17.9-7.816021012.5%B2.5/17.5555--8.2--24.1--7.7-200AmmoniaTotal (mg/L)Unionized (mg/L)12.5%C2.5/17.5333--8.2--24.0--7.6-200Control water<0.017<0.01712.5%D2.5/17.5555--8.2--24.0--7.7-205100%Sample:<0.017<0.01725%A5/155558.4-8.324.2-24.08.0-7.716520025%B5/15555--8.3--24.0--7.7-195Alk &HardnessAlkalinity(mg/L)Hardness (mg/L)25%C5/15555--8.3--24.0--7.7-195Control water818825%D5/15555--8.3--24.0--7.7-205100%Sample:616150%A10/105558.4-8.324.2-24.08.1-7.816020050%B10/10555--8.3--24.1--7.7-190Percent50%C10/10555--8.3--24.0--7.7-1950%50%D10/10555--8.3--24.0--7.8-2100%100%A20/05558.4-8.224.2-24.18.3-7.7165190100%B20/0555--8.2--24.1--7.7-195DSalinityppt100%C20/0555--8.2--24.0--7.7-200100%sample:<1100%D20/0555--8.2--24.0--7.7-220Control:<1DSalinitybased onconductivityandtemperature.AOrganismsfedprior totesting and before renewal.RoomTemperature rangefor the testperiod was23.0- 24.5°C.BTemperaturesofroomand testincubatorwerecontinuouslyrecorded ona stripchart.Incubator #3temperature rangefor the testperiod was23.0- 24.5°C.CDO= Dissolved OxygenLightIntensityduringthe testwas50-100footcandles.Photoperiodduring thetestwas16hoursof light:8 hoursofdark.MortalityControl water (water flea):100%(water flea):Data recordedduring the 96-houracutedefinitivebioassaysofa sample ofeffluent fromthe VeroBeach MunicipalPowerPlant,100 17th Street,VeroBeach, IndianRiverCounty,Florida,NPDES# FL0002984, performed from13 to 17 November2003.Data TranscriptionVerificationLIMSdate:1/30/04by: JamesDaniels/JoshAyresFacilityType: Municipal PowerPlant5Table 1.continuedFacility:VeroBeachMunicipalPowerPlantNPDES#:FL0002984Analysts:JoshuaAyresLocation:10017thStreet, VeroBeachContact/District:Phil Kane/CentralJames DanielsCounty:IndianRiverTesttype:acutedefinitive96hours renewalMarshall FairclothSampleCollection Date:11/12/2003Time:0930#tests:2ReceivingWater:IndianRiverChristaPieriniTestBeginningDate:11/13/2003Time:1430Chlorination Type:nonchlorinatedClassIIIMarineTestEndingDate:11/17/2003Time:1330FDEPSOP#:TA07_02Page3of4Reviewer:Julie EspyOrganism:PimephalespromelasLifestage:3daysAFeeding:ArtemiaConductivity0- 48hoursChambersize:1000mlFoodBatch#:0194025GUncorrectedJob number:TLH-2003-11-13-42Sample/DiluentSURVIVAL#AlivepHBTemperatureCDO(mg/L)μmhos/cmsample number:716209ConcentrationsVolume(mL)0hr24hr48hr0 hour24hour48hour0hour24hour48hour0hour24hour48hour0hour48hourControlA0/201010108.0-8.124.0-24.48.3-7.9274295ControlB0/20101010-7.9--25.4--7.0---6.25 %A1.25/18.751010108.1-8.124.1-24.17.9-7.82842906.25 %B1.25/18.75101010-8.0--24.8--7.3---12.5%A2.5/17.51010108.1-8.124.1-24.28.0-7.8275282TotalResidualCL2mg/LMethod12.5%B2.5/17.5101010-8.0--24.5--7.4---Field (100%sample):--25%A5/151010108.1-8.124.2-24.08.1-7.8256268Lab (100%sample):<0.03Hach25%B5/15101010-8.0--24.1--7.4---Controlwater:<0.03Hach50%A10/101010108.1-8.124.5-24.08.0-7.823723350%B10/10101010-8.0--24.2--7.6---AmmoniaTotal (mg/L)Unionized(mg/L)100%A20/01010108.1-8.124.8-24.27.9-7.7163175Controlwater:<0.017<0.017100%B20/0101010-8.0--24.0--7.5---100%Sample:<0.017<0.017AOrganismsfedprior totestingandbefore renewal.RoomTemperature range forthetestperiodwas23.0-24.5 °C.Alk &HardnessAlkalinity(mg/L)Hardness (mg/L)BTemperaturesofroomandtestincubator were continuouslyrecordedIncubator #3temperature range forthetestperiodwas23.0-24.5°C.Control water:8090CDO= Dissolved OxygenLight Intensityduringthe testwas50-100footcandles.100%Sample:6161Photoperiodduringthe testwas16hoursoflight :8 hoursofdark.DSalinityppt100%sample:<1Control:<1DSalinitybasedonconductivityand temperature.date: 1/30/04by: James Daniels/Josh AyresDatarecordedduringthe 96-houracute definitivebioassaysofa sampleofeffluent fromthe Vero Beach MunicipalPowerPlant,100 17thStreet,VeroBeach,IndianRiverCounty,Florida,NPDES# FL0002984, performed from13 to 17 November2003.DataTranscriptionVerificationLIMSFacilityType: MunicipalPowerPlant6Table1.concluded.Facility:Vero BeachMunicipalPower PlantNPDES#:FL0002984Analysts:Joshua AyresLocation:10017thStreet,VeroBeachContact/District:Phil Kane/CentralJamesDanielsCounty:IndianRiverTesttype:acute definitive 96hoursrenewalMarshallFairclothSampleCollection Date:11/12/2003Time:0930#tests:2ReceivingWater:Indian RiverChristaPieriniTestBeginning Date:11/13/2003Time:1430Chlorination Type:nonchlorinatedClassIIIMarineTestEndingDate:11/17/2003Time:1330FDEPSOP#:TA07_02Page4 of4Reviewer:JulieEspyOrganism:Pimephales promelasLifestage:12daysAFeeding:ArtemiaConductivity48-96hoursChambersize:1000 mlFood Batch #:0194025GUncorrectedJob number:TLH-2003-11-13-42Sample/DiluentSURVIVAL#AlivepHTemperatureBDO (mg/L)μmhos/cmsamplenumber:716209ConcentrationsVolume(mL)48hr72hr96hr48hr72hr96hr48hr72hr96hr48hr72hr96hr48hr96hrControlA0/20101010-8.18.1-24.225.3-8.07.8-325ControlB0/201010108.1-8.124.5-25.98.0-7.72903356.25%A1.25/18.75101010-8.18.0-24.425.2-7.47.3-3106.25%B1.25/18.751010108.1-8.024.5-24.77.7-7.129431012.5%A2.5/17.5101010-8.18.0-24.724.5-7.27.2-295Total ResidualCL2mg/LMethod12.5% B2.5/17.51010108.2-8.024.3-24.97.7-7.1213305Field(100% sample):--25%A5/15101010-8.17.9-24.824.1-7.67.1-280Lab(100%sample):<0.03Hach25%B5/151010108.2-7.924.2-25.97.8-7.1270300Controlwater:<0.03Hach50%A10/10101010-8.18.0-25.125.5-7.77.1-25550%B10/101010108.2-8.024.2-24.77.8-7.1235245AmmoniaTotal(mg/L)Unionized (mg/L)100%A20/0101010-8.17.9-24.924.0-7.37.2-180Controlwater:<0.017<0.017100%B20/01010108.2-7.924.1-24.17.9-7.4170180100%Sample:<0.017<0.017AOrganisms fedpriortotestingandbeforerenewal.RoomTemperaturerange for the testperiodwas23.0- 24.5 °C.Alk&HardnessAlkalinity(mg/L)Hardness(mg/L)BTemperaturesofroomandtestincubatorwerecontinuously recordedIncubator#3temperaturerange forthetestperiodwas23.0-24.5°C.Controlwater:8090CDO =DissolvedOxygenLightIntensity duringthe testwas50-100footcandles.100%Sample:6161Photoperiodduringthetestwas16hoursoflight:8hoursofdark.Percent0%0%DSalinityppt100%sample:<1Control:<1DSalinitybasedonconductivityandtemperature.100%:date:1/30/04by:JamesDaniels/JoshAyresMortalityControlwater:Data recordedduring the 96-houracute definitive bioassaysofasample ofeffluent fromtheVeroBeach Municipal PowerPlant,100 17thStreet, Vero Beach, IndianRiver County,Florida,NPDES#FL0002984, performed from13to 17November2003.DataTranscription VerificationLIMSFacilityType:Municipal PowerPlant7

### T a b l e 2. M eas ured and pr edicted alg a l gr o w th po tential ( A G P ) of P.subc api tata for total soluble

inor ga nic nitrogen (T SIN) a nd or t ho pho s phate ( O P) limitatio n in th e s a m p le of e ffluent

fr

om th e Ver o

Beach M uni c i

pal P o wer P

l ant.

Lo cation A G P (meas ur ed) Predicted A G P (TS I N) ±

20 % P r edict e d A G P (O P) ± 20% Inor ga nic N: P r a tio



### Ef

f l uent

Sam p les 0.110 0.57 ± 0.114 8.6 ± 1.72 0.75



## 8

### T a b l e 3. E ffluent limits

, Clas s III Cr it

er

ia an d c hem ic al d a ta fr o m s a m p les collec t e d fr

om the

V

e r

o

Be ac h M u nic i pa l Powe r Plan t on 12 Nov e mber , 2 003.

V e r o Be a c h M u nic i pa l P o w e r P l a n t Cl ass III M a rine

St ds E ffl ue nt

Non e Det e cted

- -

Alu m inum ≤ 15 00 1 7 I

Ar senic ≤ 5 0 9. 8 U

Cad m i u m ≤ 9

. 3 0.0 25 U

Cal c ium (m g/L)

- 2 1.1

Chrom i um

- III

- 3 U

Cop per ≤ 3

. 7 3 .6 I

Ir on ≤ 30 0 1 5 U

Lea d ≤ 8

. 5 0.0 5 U

Ma gnes iu m ( m g / L)

- 1 .6

Ni ck el ≤ 8. 3 3 U

Sel enium ≤ 7. 1 1 U

Silv er

- 0 .0 2 U

Zi n c ≤ 86 6. 5 I

O r t ho- pho s phate

- 0

. 02

T o t a l Pho s phor u s

- 0 .0 2 U

Am m onia

- 0.0 1 U

Uni oniz e d Am m o nia

- -

Nitrate+Nitr ite

- 0. 015

T o t a l Kj eld ahl Ni tr ogen

- 0

. 19 I

O r g anic Nitr ogen

- 0 .1 9 c

T o ta l N i t r og e n

- 0 .2 c

Hardnes s ( m g/L )

- 5 9

. 3 c

AGP ( m g Dr y W t / L)

- 0

. 11 I

T o t a l Residual Chlor i ne ( Lab) ≤ 0. 01 < 0

. 03 p

T o t a l Residual Chlor i ne ( F ield ) ≤ 0. 01

-

c - c a lc ula t ed va lue.

I - T he r e p o r t ed value i s betw een th e laborator y m e thod detection lim it and the lab o r a tory

pr a c tic a l q uantita t ion lim it.

p - Mater i al anal y z ed f o r and not det ec ted. Value r epor t ed ( 0 .0 3) is th e labo r a tor y m i nim u m de tec t ion value.

U - Mater i al w a s analy z ed f o r but no t detected. T he valu e r epo r t ed is the m i nim u m detection lim it. Ge n e r a l P h y sic a l an d Ch emical P a ram e t e rs Or g a ni c C ons ti tue n ts (μg/ L )

Me t a l s ( μ g /L u n less ot h e rw ise n o t e d )

Nut r ie nts (mg/L )



## 9

### A ppendi x 1. Che m i c a l A n al y s es p e rfo r med on the efflue nt from the V e r o B e ach M uni ci pal P o w e r P l a n t

sampled on Nov e mber 12 , 20 03

.

Date Sam p led F ield ID Analy s is G r ou p C o m po ne nt Re s u lt Units R em ark M DL PQL

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,2,4 ,5 -T e t rachlo rob e n z en e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,2 ,4-T ric h lorob e n z e n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,2 -Dic h l o r ob en z e ne 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,3,5 -T ri nitro b e n z e n e 3

. 8 u g/L U 3.8 1 5

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,3 -Dic h l o r ob en z e ne 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,3-Din itro be nz en e 1 .9 u g /L U 1 .9 7.6

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,4 -Dic h l o r ob en z e ne 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 ,4 -Na p h t ho qu ino n e 1 9 u g/L U 1 9 76

11 /1 2/20 03 9:30 VBP BNA-W a te r 1 -Nap hthy la m i ne 9

. 5 u g/L U J 9 .5 38

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,3,4 ,6 -T e t rac h lo rop h e n o l 1

. 9 u g/L U J 1 .9 7.6

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,4 ,5 -T ric h lorop hen ol 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,4 ,6 -T ric h lorop hen ol 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,4 -Dic h l orop he no l 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,4-Dim e t h y l phe no l 4 8 u g/L U 4 8 1 9 0

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,4-Din itrop h e n o l 1 4 u g /L U 1 4 5 7

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,4-Din itroto lue n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,6 -Dic h l orop he no l 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 ,6-Din itroto lue n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Ac e ty la m i no f l uo re ne 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Ch l orona ph tha l en e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Ch l orop he nol 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Me t hy l-4

, 6

- di nitro p h e n o l 2 .9 u g /L U 2 .9 11

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Meth y ln ap htha le ne 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Nap hthy la m i ne 9

. 5 u g/L U 9.5 3 8

11/ 1 2/2003 9:30 VBP BN A-W a ter 2

- N itr o aniline 0 .95 u g/L U 0. 95 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Ni t rop h e n o l 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 2 -Pic o lin e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 3 ,3'-Dic h lo rob e n z i d in e 3 8 u g/L U 3 8 1 5 0

11 /1 2/20 03 9:30 VBP BNA-W a te r 3 ,3 '

- Dim e th y l be nz id ine 1 9 u g/L U 1 9 76

11 /1 2/20 03 9:30 VBP BNA-W a te r 3 -Me t hy lc h o la nth r en e 0 .95 u g/L U 0

. 9 5 3.8

11/ 1 2/2003 9:30 VBP BN A-W a ter 3

- N itr o aniline 0 .95 u g/L U 0. 95 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 ,4'-DDD 1 .4 u g /L U 1 .4 5.7

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 ,4 '

- DDE 1 .4 u g /L U 1 .4 5.7

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 ,4'-DDT 1 .4 u g /L U 1 .4 5.7

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 -Am i no bi phe ny l 3 .8 u g /L UJ 3.8 1 5

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 -Bro m o ph en y l p h e n y l ethe r 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 -Chl oro

- 3-m e thy l ph en ol 0.95 u g /L U 0 .9 5 3 .8

11/ 1 2/2003 9:30 VBP BN A-W a ter 4

- C hlor oaniline 0 .95 u g/L U J 0

. 9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 -Chlo r o p h e n y l ph en y l e t h e r 1 .9 u g /L U 1 .9 7.6

11/ 1 2/2003 9:30 VBP BN A-W a ter 4

- N itr o aniline 0 .95 u g/L U J 0

. 9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 4 -Ni t rop h e n o l 1 4 u g /L U 1 4 5 7

11 /1 2/20 03 9:30 VBP BNA-W a te r 5 -Nit ro-o-to l ui din e 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r 7 ,12

- Di m e thy l be nz (a )an t hra c e n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r A c e nap hth e n e 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r A c e n a p h thy l e n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r A c e to ph en on e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r A l d rin 1 .4 u g /L UJ 1.4 5 .7

11 /1 2/20 03 9:30 VBP BNA-W a te r A ni lin e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r A nth r acen e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r A z o b e n z ene /1,2-Dip he ny lh y d raz i n e 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r B e n z i d i ne 9 5 u g /L U 9 5 3 80

11 /1 2/20 03 9:30 VBP BNA-W a te r B e n z o (a )a nthrac e n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B e n z o (a )p y r e n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B e n z o (b)f l u o r an then e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B en z o (g ,h ,i )pe r y l en e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B en z o (k )f lu oran th en e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B en z y l alcoh o l 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B i s (2 -c hl oro e th ox y ) m e tha n e 0 .95 u g/L U 0

. 9 5 3.8

11 /1 2/20 03 9:30 VBP BNA-W a te r B is(2-c hl oro e thy l )e the r 0.95 u g /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 VBP BNA-W a te r B i s (2 -c hl oro i s o prop y l )e the r 2

. 9 u g/L U 2.9 1 1

11 /1 2/20 03 9:30 VBP BNA-W a te r B is(2-ethy l he x y l)p h tha l a t e 1 4 u g/L U 1 4 57

11 /1 2/20 03 9:30 VBP BNA-W a te r B uty l b e n z y l ph th al ate 4 .8 u g /L U 4 .8 19



## 1011 /1 2/20 03 9:30 V B P B N A

- W a te r C h r y s ene 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i

- n-bu ty l p h th al a t e 4 .8 ug /L U 4 .8 19

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i

- no c ty l ph tha l ate 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i b en z o ( a ,h ) a nthrac e n e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i b e n z o f u r a n 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i e l d r i n 1 .4 ug /L U 1 .4 5.7

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i e thy l p h th al a t e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i m e t hy l p h tha l ate 4 8 u g / L U 4 8 19 0

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i m eth y l a m i n o a z o b e n z e n e 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i n oseb 3

. 8 u g / L U J 3 .8 15

11 /1 2/20 03 9:30 V B P B N A

- W a te r D i p h e n y l a m i n e 2

. 9 u g / L U 2.9 1 1

11 /1 2/20 03 9:30 V B P B N A

- W a te r E n d o s u l f a n I 3 .8 ug /L U 3 .8 15

11 /1 2/20 03 9:30 V B P B N A

- W a te r E n d o s u l f a n II 3

. 8 u g / L U 3.8 1 5

11 /1 2/20 03 9:30 V B P B N A

- W a te r E n d o s ul f a n s u l f ate 1 .4 ug /L U 1 .4 5.7

11 /1 2/20 03 9:30 V B P B N A

- W a te r E nd r i n 1 .4 ug /L UJ 1.4 5 .7

11 /1 2/20 03 9:30 V B P B N A

- W a te r E nd r i n al d e h y de 3

. 8 u g / L U 3.8 1 5

11 /1 2/20 03 9:30 V B P B N A

- W a te r E th y l m e tha n e s ul fona te 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r F l u oran the n e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r F l u o r e n e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r H e p tachl o r 1 .4 ug /L U 1 .4 5.7

11 /1 2/20 03 9:30 V B P B N A

- W a te r H e p ta c h l o r ep oxi d e 1 .4 ug /L U 1 .4 5.7

11 /1 2/20 03 9:30 V B P B N A

- W a te r H ex a c hl or o b e n z e n e 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r H exac h l orob utad i e n e 2

. 9 u g / L U 2.9 1 1

11 /1 2/20 03 9:30 V B P B N A

- W a te r H e x a c hl o r o c y c l o pe ntad i e n e 2

. 9 u g / L U J 2 .9 11

11 /1 2/20 03 9:30 V B P B N A

- W a te r H e x a c hl o r o e tha n e 2 .9 ug /L U 2 .9 11

11 /1 2/20 03 9:30 V B P B N A

- W a te r H ex a c hl or o p rop e n e 1

. 9 u g / L U J 1 .9 7.6

11 /1 2/20 03 9:30 V B P B N A

- W a te r I n d e n o ( 1

, 2

, 3-c d )py r en e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r I sop h o r on e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r I s o s a f r o l e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r M etha py r i l e ne 3

. 8 u g / L U 3.8 1 5

11 /1 2/20 03 9:30 V B P B N A

- W a te r M e t h y l m e tha n e s ul f o n a te 0.95 ug /L UJ 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r N -Ni t r o s o d i

- n

- b uty l a m i n e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r N

- N i t ros o di -n-prop y l a m i n e 1

. 9 u g / L U 1.9 7 .6

11 /1 2/20 03 9:30 V B P B N A

- W a te r N

- N i t r o s o di e t h y l a m i ne 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r N

- N i t ros o di m e th y l a m i n e 1 .9 ug /L U 1 .9 7.6

11 /1 2/20 03 9:30 V B P B N A

- W a te r N

- N i t rosod i ph en y l am i n e 2 .9 ug /L UJ 2.9 1 1

11 /1 2/20 03 9:30 V B P B N A

- W a te r N

- N i t r o s o m e thy l e t hy l a m i ne 1

. 9 u g / L U 1.9 7 .6

11 /1 2/20 03 9:30 V B P B N A

- W a te r N -Ni t r o s o m o r p ho l i n e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r N -Ni t r o s o p i pe r i d i ne 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r N

- N i t ros o py rr o l i d i n e 1 .9 ug /L U 1 .9 7.6

11 /1 2/20 03 9:30 V B P B N A

- W a te r N ap hth a l e ne 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r N i t r o be nz en e 1 .9 ug /L U 1 .9 7.6

11 /1 2/20 03 9:30 V B P B N A

- W a te r N i t r o qu i n o l i n e1

- o x i d e 1 9 u g / L U J 1 9 7 6

11 /1 2/20 03 9:30 V B P B N A

- W a te r P e n tachl o r o be nz en e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r P e n tac h l o roe t ha ne 4 8 ug /L U 4 8 1 9 0

11 /1 2/20 03 9:30 V B P B N A

- W a te r P e n ta c h l o r o ni tr o b e n z e n e 0.95 ug /L UJ 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r P en ta c h l o rop h e n o l 2

. 9 u g / L U J 2 .9 11

11 /1 2/20 03 9:30 V B P B N A

- W a te r P h e n a c e ti n 3 .8 ug /L U 3 .8 11

11 /1 2/20 03 9:30 V B P B N A

- W a te r P h e n a n t hr e n e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r P he no l 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r P y r en e 0 .95 u g / L U 0.9 5 3.8

11 /1 2/20 03 9:30 V B P B N A

- W a te r P y r i d i n e 3 .8 ug /L U 3 .8 15

11 /1 2/20 03 9:30 V B P B N A

- W a te r S af rol e 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B N A

- W a te r a l p h a -BH C 1

. 4 u g / L U 1.4 5 .7

11 /1 2/20 03 9:30 V B P B N A

- W a te r b eta-BHC 1 .4 ug /L U 1 .4 5.7

11 /1 2/20 03 9:30 V B P B N A

- W a te r d el ta-BHC 1

. 4 u g / L U 1.4 5 .7

11 /1 2/20 03 9:30 V B P B N A

- W a te r g am m a

- B H C 1

. 4 u g / L U 1.4 5 .7

11 /1 2/20 03 9:30 V B P B N A

- W a te r m ,p

- C res o l s 1

. 9 u g / L U 1.9 7 .6

11 /1 2/20 03 9:30 V B P B N A

- W a te r o

- C r e s o l 1 .9 ug /L U 1 .9 7.6

11 /1 2/20 03 9:30 V B P B N A

- W a te r o

- T ol u i di n e 0.95 ug /L U 0 .9 5 3 .8

11 /1 2/20 03 9:30 V B P B i o

- A G P / Li m N u t Al ga l Grow th P o ten t i a l 0 .11 m g Dr y W t/L I 0 .1 0.3

11 /1 2/20 03 9:30 V B P Bi o

- C h l

- a C h l orop hy l l

- A, Mo no c h rom a ti c, W a te r 0 .85 u g / L U 0.8 5 2.6

11 /1 2/20 03 9:30 V B P Bi o

- C h l

- a P ha eo ph y t i n -A, Mon o chr o m a ti c

, W a ter 0 .85 u g / L U 0.8 5 2.6

11 /1 2/20 03 9:30 V B P Bi o

- T o x i c o l o g y B i oa s s a y

- A c ute

- De f

- FW -C.du b i a , L C 50 10 0 L C5 0 L

11 /1 2/20 03 9:30 V B P Bi o

- T o x i c o l o g y Bi o a s s ay -Ac u te-Def -FW

- Fi s h , LC5 0 10 0 L C5 0 L

11 /1 2/20 03 9:30 V B P GC-W ater A l ac h l or 0.57 ug /L U 0 .5 7 2 .28



## 11

### 11 /1 2/20 03 9:30 VBP GC-W ater Am etry n 0 .0 48 u g /L U 0 .04 8 0

. 1 9 2

11 /1 2/20 03 9:30 VBP GC-W ater At r a z i ne 0. 04 8 u g / L U 0.0 4 8 0

. 1 9 2

11 /1 2/20 03 9:30 VBP GC-W ater Az inp h o s Meth y l 0

. 0 4 8 u g/L U J 0 .04 8 0

. 1 9 2

11 /1 2/20 03 9:30 VBP GC-W ater B r om acil 0.19 u g /L U 0 .1 9 0 .7 6

11 /1 2/20 03 9:30 VBP GC-W ater Buty l a te 0.19 u g /L UJ 0

. 1 9 0.7 6

11 /1 2/20 03 9:30 VBP GC-W ater Ch lorpy r if os Eth y l 0 .0 48 u g /L U 0 .04 8 0

. 1 9 2

11 /1 2/20 03 9:30 VBP GC-W ater Ch lo rpy r if o s Meth y l 0

. 0 9 5 u g/L U 0

. 09 5 0 .3 8

11 /1 2/20 03 9:30 VBP GC-W ater Di az in on 0

. 0 4 8 u g/L U 0

. 04 8 0 .1 92

11 /1 2/20 03 9:30 VBP GC-W ater Eth i o n 0

. 0 4 8 u g/L U 0

. 04 8 0 .1 92

11 /1 2/20 03 9:30 VBP GC-W ater Ethop ro p 0 .0 95 u g /L U 0 .09 5 0.3 8

11 /1 2/20 03 9:30 VBP GC-W ater Fen a m i p h o s 0.19 u g /L UJ 0

. 1 9 0.7 6

11 /1 2/20 03 9:30 VBP GC-W ater Fon o f o s 0 .0 95 u g /L U 0 .09 5 0.3 8

11 /1 2/20 03 9:30 VBP GC-W ater Hex a z i no ne 0

. 0 9 5 u g/L U 0

. 09 5 0 .3 8

11 /1 2/20 03 9:30 VBP GC-W ater M a la thio n 0 .14 u g/L U 0

. 1 4 0.5 6

11 /1 2/20 03 9:30 VBP GC-W ater Me tala x y l 0 .24 u g/L U 0

. 2 4 0.9 6

11 /1 2/20 03 9:30 VBP GC-W ater Me tola c h lor 0 .48 u g/L U 0

. 4 8 1.9 2

11 /1 2/20 03 9:30 VBP GC-W ater Me trib uz in 0

. 0 9 5 u g/L U 0

. 09 5 0 .3 8

11 /1 2/20 03 9:30 VBP GC-W ater Me v i n p h o s 0 .19 u g/L U J 0 .1 9 0 .7 6

11 /1 2/20 03 9:30 VBP GC-W ater Nal e d 0 .76 u g/L U 0

. 7 6 3.0 4

11 /1 2/20 03 9:30 VBP GC-W ater Norflura z o n 0 .0 95 u g /L U 0 .09 5 0.3 8

11 /1 2/20 03 9:30 VBP GC-W ater Pa rath ion Eth y l 0 .14 u g/L U 0

. 1 4 0.5 6

11 /1 2/20 03 9:30 VBP GC-W ater Pa ra th io n Meth y l 0

. 0 9 5 u g/L U 0

. 09 5 0 .3 8

11 /1 2/20 03 9:30 VBP GC-W ater P horate 0 .0 48 u g /L UJ 0

. 04 8 0 .1 92

11 /1 2/20 03 9:30 VBP GC-W ater Pr om e t r y n 0 .1 4 u g / L U 0. 14 0

. 56

11 /1 2/20 03 9:30 VBP GC-W ater Si m a z i ne 0

. 0 4 8 u g/L U 0

. 04 8 0 .1 92

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Alu m i n u m 1 7 u g /L I 7 28

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r A r s e nic 9 .8 u g /L U 9 .8 39

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Ca dm iu m 0 .0 25 u g /L U 0 .02 5 0.1

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Calcium 2 1

. 1 m g/L 0 .0 5 0 .2

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Chrom i u m 3 u g/L U 3 1 2

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Cop p e r 3

. 6 u g/L I 1 4

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Iro n 1 5 u g /L U 1 5 6 0

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Le ad 0.05 u g /L U 0 .0 5 0 .2

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Ma gn es i u m 1 .6 m g /L 0

. 0 2 0.0 8

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Ni c k el 3 u g/L U 3 1 2

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Se le niu m 1 u g/L U 1 4

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Silv e r 0.02 u g /L U 0 .0 2 0 .0 8

11 /1 2/20 03 9:30 VBP Me ta ls -W ate r Zin c 6

. 5 u g/L I 4 1 6

11 /1 2/20 03 9:30 VBP Nu trie nts

- L i q u id A m m o nia

- N 0 .01 m g N/L U 0

. 0 1 0.0 2

11 /1 2/20 03 9:30 VBP Nu trie nts

- L i q u id NO2NO3-N 0

. 0 1 5 m g N/L 0 .00 4 0.0 1

11 /1 2/20 03 9:30 VBP Nu trie nts

- L i q u id N_KJ E L

_ T OT 0.19 m g N/L I 0

. 0 6 0.2

11 /1 2/20 03 9:30 VBP Nu trie nts

- L i q u id O-Ph osph ate-P 0 .02 m g P/L 0 .00 4 0.0 1

11 /1 2/20 03 9:30 VBP Nu trie nts

- L i q u id T o ta l-P 0 .02 m g P/L U 0

. 0 2 0.0 6

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1,2,4, 5- T e tr achlor obenz e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1, 2, 4- T r ic hlorobenz e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1, 2- Dic h lor o benz ene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1, 3,5- T r i n itr o benz ene 3 .8 ug/L U 3 .8 15

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1, 3- Dic h lor o benz ene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1,3-D i nitr obenz e ne 1.9 u g/L U 1.9 7 .7

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1, 4- Dic h lor o benz ene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1, 4- N a phthoquinone 19 ug/L U 1 9 7 7

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 1- Naphthy l am i n e 9 .6 ug/L UJ 9.6 3 8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2,3, 4, 6- T e t r ac hlor ophenol 1 .9 ug/L UJ 1.9 7 .7

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2, 4, 5- T r ic hlorophenol 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2, 4, 6- T r ic hlorophenol 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2, 4- Dic h lorophenol 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2,4- Dim e t h y l phenol 4 8 u g/L U 48 190

11/ 1 2/2003 9:30 VBP BLANK B N A -W at er 2,4- Dinitr ophenol 1 4 u g/L U 14 58

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2, 4- Dinitr otoluene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2, 6- Dic h lorophenol 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2, 6- Dinitr otoluene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- Ac ety l am i n of luor ene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- C h loronaphthalene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2-C h lorophenol 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- Me thy l

- 4

, 6

- d i n itr o phenol 2.9 u g/L U 2.9 1 2

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- Methy l naphthalene 0 .96 u g/L U 0. 96 3.8



## 12

### 11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- Naphthy l am i n e 9 .6 ug/L U 9 .6 38

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- Nitr oaniline 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2- N i t r ophenol 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 2-Pic o line 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 3, 3'- D ic hlor obenz i dine 38 ug/L U 3 8 1 50

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 3, 3' -D im et hy l b enz i dine 19 ug/L U 1 9 7 7

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 3- Methy l c h olanthr e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 3- Nitr oaniline 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4,4'- D D D 1.4 u g/L U 1.4 5 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4,4' -D DE 1.4 u g/L U 1.4 5 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4,4'- D D T 1.4 u g/L U 1.4 5 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4-Am inobi pheny l 3 .8 ug/L UJ 3.8 1 5

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4- Br om opheny l pheny l ether 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4- Chl o r o

- 3 -m ethy lphenol 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4- Chlor o aniline 0 .96 u g/L U J 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4- Chlo r o pheny l pheny l et her 1 .9 ug/L U 1 .9 7.7

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4- Nitr oaniline 0 .96 u g/L U J 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 4- N i t r ophenol 1 4 u g/L U 14 58

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 5- Nitr o-o- tolui d ine 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater 7,12- D i m ethy lbenz ( a) anthr a c e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W at er Ac enaphthene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater A c enaphthy lene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Ac et ophenone 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Al dr in 1.4 u g/L U J 1 .4 5.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Ani line 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Anthr a cene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Az obenz ene/1,2-D ipheny lhy d raz i ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Benz idine 9 6 u g/L U 96 380

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Be nz o( a) anthrac e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Benz o( a) py r e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Be nz o( b) f l uor a nthene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Benz o( g, h, i ) per y lene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Be nz o( k ) f l uorant hene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Benz y l alcohol 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Bi s ( 2- c h l o r o ethox y ) m ethane 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Bis( 2-c h l o r o ethy l) ether 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Bi s ( 2- c h l o r o is opropy l) ether 2 .9 ug/L U 2 .9 12

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Bis( 2-ethy lhex y l ) p hthalat e 14 ug/L U 1 4 5 8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater B u ty l benz y l pht h al ate 4 .8 ug/L U 4 .8 19

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Chry s e ne 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Din

- b uty l phthalat e 4 .8 ug/L U 4 .8 19

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater D i

- n -oc t y l pht h alate 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater D i be nz o(a,h) anthr a cene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W at er D i benz of ur an 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater D i el dr in 1.4 u g/L U 1.4 5 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Diet hy l phthalat e 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater D i m e thy l phthalate 4 8 u g/L U 48 190

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Dim e thy l am i n oaz o benz en e 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Dinos e b 3 .8 ug/L UJ 3.8 1 5

11/ 1 2/2003 9:30 VBP BLANK B N A -W at er D i pheny l am ine 2 .9 ug/L U 2 .9 12

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Endos u lf an I 3 .8 ug/L U 3 .8 15

11/ 1 2/2003 9:30 VBP BLANK B N A -W at er Endos u l f an II 3.8 u g/L U 3.8 1 5

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater En dos u l f an sulf ate 1 .4 ug/L U 1 .4 5.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Endr i n 1.4 u g/L U J 1 .4 5.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Endr in aldehy de 3.8 u g/L U 3.8 1 5

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Ethy l m e thanes ulf o nat e 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater F l uor a nt hene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater F l uorene 0.96 ug/L U 0

. 9 6 3 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Heptac hlor 1.4 u g/L U 1.4 5 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Heptac hlor epox i de 1.4 u g/L U 1.4 5 .8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater He x a c h lorobenz ene 0 .96 u g/L U 0. 96 3.8

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Hexac h lor o butadiene 2 .9 ug/L U 2 .9 12

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Hex a c h loroc y c l opentadiene 2 .9 ug/L UJ 2.9 1 2

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Hex a chlor o ethane 2.9 u g/L U 2.9 1 2

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater H e x a c h l o r o propene 1.9 u g/L U J 1 .9 7.7

11/ 1 2/2003 9:30 VBP BLANK B N A -W ater Indeno( 1

, 2 ,3- c d) py r e ne 0.96 ug/L U 0

. 9 6 3 .8



## 131 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Is o p h o ron e 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Isos a f ro le 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Me th ap y r il e n e 3

. 8 ug /L U 3 .8 15

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r M e thy l m e t h a n e s ul f o n a te 0.9 6 ug /L UJ 0. 96 3

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N- Ni trosod i-n

- b u t y l a m i n e 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N- Ni tro s od i-n

- prop y l am in e 1

. 9 ug /L U 1 .9 7

. 7

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N- Ni tro s od ie th y l am i n e 0 .9 6 u g / L U 0. 96 3

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N- Ni tro s od im et hy l a m i n e 1. 9 u g / L U 1

. 9 7 .7

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K B N A

- W a t er N

- N i tr os od ip he ny la m i ne 2

. 9 u g/ L U J 2

. 9 1 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N- Ni trosom eth y l e th y l am in e 1

. 9 ug /L U 1 .9 7

. 7

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N-Nitro s om orp h o l i n e 0 .9 6 u g / L U 0. 96 3

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N-Ni tros o p i p eri d i n e 0 .9 6 u g / L U 0. 96 3

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r N-Nitro s o p y rrol i d i n e 1

. 9 ug /L U 1 .9 7

. 7

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Na ph tha l e n e 0 .9 6 u g / L U 0. 96 3

. 8

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K B N A

- W a t er N i tr ob en z e ne 1

. 9 u g/ L U 1. 9 7

. 7

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Ni troq ui n o l i n e -1

- o x i de 19 ug /L UJ 19 77

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Pen t a c hl oro b e n z e n e 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Pen t a c hl oro e t h a n e 4 8 u g / L U 48 19 0

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K B N A

- W a t er Pe nt a c h l o r on it r o be nz en e 0

. 9 6 u g/ L U J 0 .9 6 3

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r P e n t ac h l orop he no l 2

. 9 ug /L UJ 2

. 9 1 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Ph en ac e t i n 3. 8 u g / L U 3

. 8 1 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Ph en an th r e ne 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Phe n o l 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Py r e ne 0.9 6 ug /L U 0

. 9 6 3 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r P y rid i ne 3. 8 u g / L U 3

. 8 1 5

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r Saf r ol e 0 .9 6 u g / L U 0. 96 3

. 8

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K B N A

- W a t er al ph a- BH C 1 .4 u g / L U 1

. 4 5. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r be ta-BHC 1. 4 u g / L U 1

. 4 5 .8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r de lt a-BHC 1

. 4 ug /L U 1 .4 5

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r ga m m a-BHC 1

. 4 ug /L U 1 .4 5

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r m

, p-Cres o l s 1

. 9 ug /L U 1 .9 7

. 7

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K B N A

- W a t er oC r es ol 1

. 9 u g/ L U 1. 9 7

. 7

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K B NA -W ate r o

- T o lu id in e 0 .9 6 u g / L U 0. 96 3

. 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r A l a chl o r 0 .5 7 u g / L U 0. 57 2

. 28

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K G C

- W a t e r A m e t r y n 0. 04 8 u g/ L U 0

. 04 8 0 .1 92

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r A traz in e 0 .0 48 ug /L U 0 .0 48 0. 19 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r A z i np ho s M e t h y l 0

. 0 4 8 u g / L U J 0 .0 48 0. 19 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r B ro m a cil 0 .1 9 u g / L U 0. 19 0

. 76

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r B uty l a t e 0 .1 9 u g / L U J 0

. 1 9 0 .76

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r C h l orpy r i f o s Eth y l 0 .0 48 ug /L U 0 .0 48 0. 19 2

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K G C

- W a t e r C h l or py r i f o s Me th y l 0. 09 5 u g/ L U 0

. 09 5 0

. 3 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r D i a z i no n 0 .0 48 ug /L U 0 .0 48 0. 19 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r E t h i o n 0 .0 48 ug /L U 0 .0 48 0. 19 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r E t h o p rop 0 .0 95 ug /L U 0 .0 95 0

. 38

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r F en am ip ho s 0 .1 9 u g / L U J 0

. 1 9 0 .76

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r F on of os 0

. 0 9 5 u g / L U 0.0 9 5 0 .38

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r H e x az i n o n e 0 .0 95 ug /L U 0 .0 95 0

. 38

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K G C

- W a t e r M al at hi on 0

. 14 u g / L U 0 .1 4 0

. 5 6

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r M e t al a x y l 0.2 4 ug /L U 0

. 2 4 0 .96

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r M e t ol a c hl or 0.4 8 ug /L U 0

. 4 8 1 .92

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r M etri bu z i n 0 .0 95 ug /L U 0 .0 95 0

. 38

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r M ev i n p h o s 0.1 9 ug /L UJ 0. 19 0

. 76

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r N al ed 0.7 6 ug /L U 0

. 7 6 3 .04

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K G C

- W a t e r N or f l u r az on 0. 09 5 u g/ L U 0

. 09 5 0

. 3 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r P a r ath i on Eth y l 0 .1 4 u g / L U 0. 14 0

. 56

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K G C

- W a t e r P a r at h i on Met h y l 0. 09 5 u g/ L U 0

. 09 5 0

. 3 8

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r P ho r a te 0

. 0 4 8 u g / L U J 0 .0 48 0. 19 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r P rom e try n 0.1 4 ug /L U 0

. 1 4 0 .56

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K G C-W a te r S im az in e 0 .0 48 ug /L U 0 .0 48 0. 19 2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K M e t al s

- W a te r A l u m i n u m 7 ug /L U 7 28

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K M e t al s

- W a te r A rs en ic 9. 8 u g / L U 9

. 8 3 9

11 / 1 2 / 2 0 0 3 9 : 30 VBP BL AN K M et a l s

- W a t e r C ad m i um 0. 02 5 u g/ L U 0

. 02 5 0

. 1

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K M e t al s

- W a te r C al c i um 0.0 5 m g /L U 0

. 0 5 0 .2

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K M e t al s

- W a te r C hro m i u m 3 ug /L U 3 12

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K M e t al s

- W a te r C op pe r 1 ug /L U 1 4

1 1 /1 2/ 20 03 9:3 0 V BP BLA N K M e t al s

- W a te r I ron 1 5 u g / L U 15 60



## 141 1 /12 / 200 3 9: 30 VBP BLAN K M e t als

- W a t e r Lead 0.0 5 ug/ L U 0. 05 0. 2

1 1 /12 / 200 3 9: 30 VBP BLAN K M e t als

- W a t e r M a gnes i u m 0 .0 2 m g/ L U 0. 02 0.0 8

1 1 /12 / 200 3 9: 30 VBP BLAN K M e t als

- W a t e r N ic k e l 3 ug/ L U 3 1 2

1 1 /12 / 200 3 9: 30 VBP BLAN K M e t als

- W a t e r S el enium 1 ug/ L U 1 4

1 1 /12 / 200 3 9: 30 VBP BLAN K M e t als

- W a t e r S ilver 0.0 2 ug/ L U 0. 02 0.0 8

1 1 /12 / 200 3 9: 30 VBP BLAN K M e t als

- W a t e r Z inc 4 ug/ L U 4 1 6

1 1 /12 / 200 3 9: 30 VBP BLAN K N u t r i en ts

- L iquid A m m onia- N 0 .0 1 m g N / L U 0. 01 0.0 2

1 1 /12 / 200 3 9: 30 VBP BLAN K N u t r i en ts

- L iquid N O 2 N O 3- N 0 .0 1 m g N / L I 0.00 4 0 .0 1

1 1 /12 / 200 3 9: 30 VBP BLAN K N u t r i en ts

- L iquid N

_ K J E L_T O T 0.0 6 m g N / L U 0. 06 0. 2

1 1 /12 / 200 3 9: 30 VBP BLAN K N u t r i en ts

- L iquid O -P hos p hate

- P 0

. 004 m g P / L U 0.00 4 0 .0 1

1 1 /12 / 200 3 9: 30 VBP BLAN K N u t r i en ts

- L iquid T ota l

- P 0.0 2 m g P / L U 0. 02 0.0 6



## 15T r an sacti on C o de N P D E S NU M B E R Y R /M O/D A I n sp T y p e I n spector F ac T y pe

1 N 2 5 3 F L 000 2 9 8 4 1 1 1 203 1 1 1 2 1 8 B 19 S 20 2

66

T r an sacti on C o de N P D E S NU M B E R Y R /M O/D A I n sp T y p e I n spector F ac T y pe

1 N 2 5 3 F L 000 2 9 8 4 1 1 1 203 1 1 1 2 1 8 X 19 S 20 2

66 Fill O u t This S e c t ion For A ll Surf ac e W a t e r Disc harger I n s pec t i o n s ( CE I

, CS I

, CBI

, P A I

, X S I

- RI Op t i onal)

Rem a rk s Rem a rk s 

# Th e Bioassay o f Vero Be ach M unicipal Pow e r Plant

effl uent sampl ed on Nov ember 12, 2003, NPDES

#F L0002984.

Fill O u t This S e c t ion For A ll Surf ac e W a t e r Disc harger I n s pec t i o n s ( CE I

, CS I

, CBI

, P A I

, X S I

- RI Op t i onal)



# Th e Priority Pollutan ts A n aly s is fo r Bio assay of Vero

Beach M u n i cipal Po w e r Pl ant efflu e nt sampled on

No v e mber 12, 2003, NP D ES #FL0002984.

16