## 1 

## APPENDICES

Selection of Industry Sectors, Chemicals and Functions in the Remanufacturing Exclusion: Background Document in Support of the Definition of Solid Waste Rule

## 2



## APPENDIX 1: Sector Characterization: Each Sector an d All 4 Sectors Combined Pharmaceutical Manufacturing Sector Table 1.1 Production Related Waste (PRW) Offsite Reporting Table 1.2 Production Related Waste (PRW) Onsite Reporting & Summary Figure 1.1 US Sector Map 1 

## Paint & Coatings Manufacturing S ector Table 2.1 Production Related Waste (PRW) Offsite Reporting Table 2.2 Production Related Waste (PRW) Onsite Reporting & Summary Figure 2.1 US Sector Map Plastic & Resin Manufacturing Sector Table 3.1 Production Related Waste (PRW) Offsite Reporting Table 3.2 Production Related Waste (PRW) Onsite Reporting & Summary Figure 3.1 US Sector Map Basic Organic Chemical Manufacturing Sector Table 4.1 Production Related Waste (PRW) Offsite Reporting Table 4.2 Production Related Waste (PRW) Onsite Reporting & Summary Figure 4.1 US Sector Map, Toluene Subset Table 4.3 Top Waste Reporters / Top Recyclers

- By % of Total Waste Table 4.4 Top Waste Reporters / Top Recyclers

- By Total Waste Table 4.5 Top Waste Reporters / Top Recyclers

- By Chemical Figure 4.2 Top Waste Reporter of Toluene: Henry Map Figure 4.3 Top Waste Reporter of Methanol: Hopewell Map
All 4 Sectors Combined Table 5.1 All 4 sector summary w/ RTKNET.org and OECA Sector Profile Notebook Links Table 5.2 Production Related Waste (PRW) Offsite Reporting Table 5.3 Production Related Waste (PRW) Onsite Reporting & Summary Figure 5.1 US Sector Map: All 4 sectors combined with cement kilns

1 

### US Sector Maps: Facilities in United States reporting Toluene > 25,000 lbs waste.

## 3



## APPENDIX 2: Regional Maps: 2 

## Transportation and co
- located Potential Remanufacturing Facilities Figure 6.1 Pharmaceutical: Elkton, VA Figure 6.2 Pharmaceutical: Florence, SC Figure 6.3 Pharmaceutical: Albany, OR Figure 6.4 Basic Organic: Willow Island, WV Figu re 6.5 Basic Organic: Elgin SC Figure 6.6 Basic Organic: Georgetown, IL Figure 6.6 Basic Organic Willow Island & Pharmaceutical Elkton Figure 6.7 Basic Organic Elgin & Pharmaceutical Florence Figure 6.8 Basic Organic Georgetown & Pharmace utical Kalamazoo (Sector An a lysis, Map 2)



## APPENDIX 3: New Chemicals Assessment: Release and Exposure from Toluene Fuel Blending 7.1 Premanufacture Notice (PMN) Process Flow Chart 7.2 New Chemical assessment as it relates to the Remanufactu ring Exclusion 7.3 ChemSTEER Worksheet: Manufacture and use (destroyed) as an intermediate Figure 7.1 Puerto Rico Map: Transport of Toluene from Pfizer to disposal 7.5 ChemSTEER worksheet: Fuel Blending (unload, blend, load) Activity 7.6 ChemSTE ER: Fuel Blending: ENVIRONMENTAL RELEASES ESTIMATE SUMMARY 7.7 ChemSTEER: Fuel Blending: OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY 7.7 Figure 7.2 Cement Kiln US Sector Map
APPENDIX 4: Mass Balance Model and Embedded Emissions Modules
8.1 Mass Balance Model 8.2 Modules Embedded in Mass Balance Model

2 

### Regional Maps: Facilities in Region reporting toluene > 25,000 lbs waste. Includes current offsite disposal routes and locations of potential remanufacturing facilities.

## 4 

## Table 1.1: TRI Production Related WASTE Reporting - Offsite
Pharmaceutical M anufacturing Pharma N AICS 325412



### Chemical Number of TRI Submissions Total

Underground Injection Total

Landfill Total Other

Management and Disposal Total Recycling 

### Total Energy Recovery (Cement Kiln) Total Thermal

Treatment (Incinerator) Total Other

Treatment (not POTW or wastewater) 

### 1,2,4-TRIMETHYLBENZENE 1 0 0 0 

### 0 352 1,487 0 

### ACETONITRILE 27 0 188 12,533 

### 3,386,714 2,522,096 2,151,060 49,794 

### CHLOROBENZENE 2 0 0 0 

### 0 49,887 263,287 0 

### CHLOROFORM 6 0 0 453 

### 64,651 266,498 246,513 0 

### CHLOROMETHANE 1 0 0 0 

### 0 0 0 0 

### CYCLOHEXANE 4 0 50 0 

### 0 395,945 18,997 0 

### DICHLOROMETHANE 35 0 276 0 

### 4,235,378 2,020,446 5,739,976 908,140 

### ETHYLBENZENE 2 0 0 0 

### 0 39,100 0 0 

### METHANOL 51 0 1, 085 44,063 

### 1,366,677 20,959,681 1,030,964 1,413,242 

### METHYL ISOBUTYL KETONE 3 0 0 0 

### 170,000 179,618 29,343 500 

### METHYL TERT-BUTYL ETHER 12 0 100 4,862 

### 12,056 1,220,686 302,115 33,033 

### N,N-DIMETHYLFORMAMIDE 15 0 56 0 

### 162 3,747,336 69,504 301,891 

### N-BUTYL ALCOHOL 2 0 0 0 

### 0 510,000 758 0 

### N-HEXANE 8 0 50 0 

### 18,000 180,647 43,184 91,622 

### TOLUENE 31 0 1, 592 31,176 

### 1,187,694 7,732,219 1,578,672 467,040 

### XYLENE (MIXED ISOMERS) 8 0 10 1,258 

### 3,118 105,775 119,979 0


### Totals 208 0 3,407 94,345 10,444,450 39,930,286 11,595,839 3,265,262 Relative to Sum of all Categories (%)

-- 0.00 0.00 0.08 9.2 35.2 10.2 2.9 Total All Four Sectors: 1,075,879,320 1,075,879,320 1,075,879,320 % of Total All Four Sectors: 1.0% 3.7% 1.1%



### Table 1.1 Off Site Waste Category (lb) (2008 TRI)

## 5



## Table 1.2: TRI Production Related WASTE Reporting - Offsite Pharmaceutical Manufacturing Pharma NAICS 325412



### Chemical Total Underground Injection Total

Landfill Energy

Recovery Recycling Treatment Total Relative to Sum of al l Chemicals (%) 

### 1,2,4-TRIMETHYLBENZENE 0 0 0 0 0 1,839 0.0 ACETONITRILE 2,800 0 547 921,646 2,576,581 11,623,959 10.2 CHLOROBENZENE 0 0 0 7,672,183 97,855 8,083,212 7.1 CHLOROFORM 0 0 0 0 107,984 686,099 0.6 CHLOROMETHANE 0 0 0 0 39,870 39,870 0.0 CYCLOHEXANE 0 0 0 2,511,052 250,524 3,176,568 2.8 DICHLOROMETHANE 8,500 0 66,256 6,072,254 2,034,702 21,085,928 18.6 ETHYLBENZENE 0 0 0 0 0 39,100 0.0 METHANOL 13,000 5 19,736 7,704,629 6,265,808 38,818,890 34.2 METHYL ISOBUTYL KETONE 0 0 0 0 3,305 382,766 0.3 METHYL TERT-BUTYL ETHER 0 0 0 0 198,721 1,771,573 1.6 N,N-DIMETHYLFORMAMIDE 330,000 0 2 0 813,006 5,261,957 4.6 N-BUTYL ALCOHOL 0 0 0 4,410,529 1,080,644 6,001,931 5.3 N-HEXANE 0 0 16,988 0 44,180 394,671 0.3 TOLUENE 0 0 0 3,422,137 1,389,984 15,810,514 13.9 XYLENE (MIXED ISOMERS) 0 0 0 0 16,476 246,616 0.2

Off Site Total (lb) 65,333,589 354,300 5 103,529 32,714,430 14,919,640 113,425,493 On Site Total (lb): 48,901.904 0.31 0.00 0.09 28.8 13.2 % of All Four Sectors Onsite to Offsite Ratio: 42% 1,075,879,320 1,075,879,320 3.0% 10.5%



### Table 1.2 On Site Waste Category (lb) (2008 TRI)

## 6

## 7



## Table 2.1: TRI Production Related WASTE Reporting - Offsite Paint & Coating Manufacturing P&C NAICS 325510



### Chemical Number of TRI Submissions Total

Underground Injection Total

Landfill Total Other

Management and Disposal Total Recycling Total Energy Recovery (Cement Kiln) Total Thermal

Treatment (Incinerator) Total Other

Treatment (not POTW or wastewater) 1,2,4-TRIMETHYLBENZENE 115 0 2,823 3,706 70,070 1,333,808 59,538 13,892 ACETONITRILE 0 0 0 0 0 0 0 0 CHLOROBENZENE 0 0 0 0 0 0 0 0 CHLOROFORM 0 0 0 0 0 0 0 0 CHLOROMETHANE 0 0 0 0 0 0 0 0 CYCLOHEXANE 6 0 525 0 4,574 18,454 405 255 DICHLOROMETHANE 16 0 0 2,800 52,581 25,572 36,263 0 ETHYLBENZENE 122 0 1,851 5,846 397,294 1,804,975 194,375 16,003 METHANOL 66 0 248 9,596 310,962 604,357 351,268 13,275 METHYL ISOBUTYL KETONE 97 0 235 22,468 2,607,029 1,397,625 265,145 13,962 METHYL TERT-BUTYL ETHER 1 0 0 0 0 0 0 0 N,N-DIMETHYLFORMAMIDE 4 0 0 0 2,018 5,366 394 0 N-BUTYL ALCOHOL 103 0 244 57,174 514,642 1,004,268 133,104 63,816 N-HEXANE 13 0 0 0 15,865 33,423 0 151 TOLUENE 196 0 2,479 42,089 2,412,244 4,248,576 568,581 35,047 XYLENE (MIXED ISOMERS) 252 0 3,748 22,539 2,424,162 12,057,901 932,332 88,704
Totals 991 0 12,153 166,218 8,811,441 22,534,325 2,541,405 245,105 Relative to Sum of all Categories (%)

-- 0.00 0.01 0.17 9.0 23.1 2.6 0.3 Total All Four Sectors: 1,075,879,320 1,075,879,320 1,075,879,320 % of Total All Four Sectors: 0.8% 2.1% 0.2%



### Table 2.1 Off Site Waste Category (lb) (2008 TRI)

## 8



## Table 2.2: TRI Production Related WASTE Reporting - Offsite Paint & Coating Manufacturing P&C NAICS 325510

Chemical Total Underground Injection Total

Landfill Energy

Recovery Recycling Treatment Total Relative to Sum of all Chemicals (%) 1,2,4-TRIMETHYLBENZENE 0 5 0 2,133,971 38,018 3,655,831 3.7 ACETONITRILE 0 0 0 0 0 0 0.0 CHLOROBENZENE 0 0 0 0 0 0 0.0 CHLOROFORM 0 0 0 0 0 0 0.0 CHLOROMETHANE 0 0 0 0 0 0 0.0 CYCLOHEXANE 0 0 0 3,580 0 27,793 0.0 DICHLOROMETHANE 0 0 0 4,876 0 122,092 0.1 ETHYLBENZENE 0 1 0 4,760,217 63,136 7,243,698 7.4 METHANOL 0 0 682,093 14,164,696 485,502 16,621,997 17.0 METHYL ISOBUTYL KETONE 0 0 0 4,628,118 181,591 9,116,173 9.3 METHYL TERT-BUTYL ETHER 0 0 0 0 0 0 0.0 N,N-DIMETHYLFORMAMIDE 0 0 0 0 0 7,778 0.0 N-BUTYL ALCOHOL 0 0 7,309 1,247,171 167,179 3,194,907 3.3 N-HEXANE 0 0 0 146,346 899 196,684 0.2 TOLUENE 0 0 0 7,386,339 688,212 15,383,567 15.7 XYLENE (MIXED ISOMERS) 0 0 0 25,918,934 714,742 42,163,062 43.1

Off Site Total (lb) 34,310,647 0 6 689,402 60,394,248 2,339,279 97,733,582 On Site Total (lb): 63,422,935 0.00 0.00 0.71 61.8 2.4 % of All Four Sectors Onsite to Offsite Ratio: 65% 1,075,879,320 1,075,879,320 5.6% 9.1%



### Table 2.2 On Site Waste Category (lb) (2008 TRI)

## 9

## 10

Table 3.1: TRI Production Related WASTE Reporting - Offsite Plastic & Resin Manufacturing P & R NAICS 325211



### Chemical Number of TRI Su bmissions Total

Underground Injection Total

Landfill Total Other

Management and Disposal Total

Recycling Total Energy

Recovery (Cement Kiln) Total Thermal

Treatment (Incinerator) Total Other

Treatment (not POTW or wastewater) 1,2,4-TRIMETHYLBENZENE 29 3,700 658 1,020 66,172 80,194 2,856 6,471 ACETONITRILE 0 0 0 0 0 0 0 0 CHLOROBENZENE 4 0 1,778 0 954,563 9,980 125,353 42,299 CHLOROFORM 7 0 1 0 0 0 6,634 0 CHLOROMETHANE 5 0 4 0 0 52 38,800 0 CYCLOHEXANE 12 0 594 0 0 134,697 137,719 2,114 DICHLOROMETHANE 10 0 0 765 0 55,971 27,466 0 ETHYLBENZENE 54 7,227 553 1,461 366,211 1,239,529 261,407 9,430 METHANOL 103 2,766,167 25,698 46,386 6,949,415 5,836,953 1,551,445 43,547 METHYL ISOBUTYL KETONE 20 0 0 0 424,332 384,521 827,116 2,395 METHYL TERT-BUTYL ETHER 2 0 0 0 0 0 0 0 N,N-DIMETHYLFORMAMIDE 7 0 0 0 0 233,042 15,735 0 N-BUTYL ALCOHOL 33 17,200 189 70,156 93,817 375,477 75,907 9,774 N-HEXANE 20 0 1 1,408 2,142,264 2,859,306 355,981 114,414 TOLUENE 73 11,377 14,251 18,364 193,551 4,715,645 839,554 12,225 XYLENE (MIXED ISOMERS) 59 45,082 1,083 2,046 1,719,228 3,218,715 138,334 54,544
Totals 438 2,850,753 44,810 141,606 12,909,553 19,144,082 4,404,307 297,213 Relative to Sum of all Categories (%)

-- 1.56 0.02 0.08 7.1 10.5 2.4 0.2 Total All Four Sectors: 1,075,879,320 1,075,879,320 1,075,879,320 % of Total All Four Sectors: 1.2% 1.8% 0.4%



### Table 3.1 Off Site Waste Category (lb) (2008 TRI)

## 11

Table 3.2: TRI Production Related WASTE Reporting - Offsite Plastic & Resin Manufacturing P & R NAICS 325211



### Chemical Total Underground Injection Total

Landfill Energy Recovery Recycling Treatment Total Relative to Sum of all Chemicals (%) 1,2,4-TRIMETHYLBENZENE 0 30 1 2,662 127,985 291,749 0.2 ACETONITRILE 0 0 0 0 0 0 0.0 CHLOROBENZENE 0 0 142,870 404,680 22,026 1,703,549 0.9 CHLOROFORM 0 0 568,587 0 2,765,405 3,340,627 1.8 CHLOROMETHANE 0 0 1,396,519 0 2,740,181 4,175,556 2.3 CYCLOHEXANE 8,600 0 0 22,862,498 1,670,915 24,817,137 13.6 DICHLOROMETHANE 0 0 0 0 433,497 517,699 0.3 ETHYLBENZENE 0 32 1,244,570 2,171,612 484,401 5,786,433 3.2 METHANOL 378,818 1,370,036 5,947,159 19,555,731 17,476,402 61,947,757 33.8 METHYL ISOBUTYL KETONE 0 0 872,064 7,589,887 1,067,378 11,167,693 6.1 METHYL TERT-BUTYL ETHER 0 0 0 0 0 0 0.0 N,N-DIMETHYLFORMAMIDE 0 0 3,330,856 1,863,080 50,185 5,492,898 3.0 N-BUTYL ALCOHOL 490,519 0 183,408 16,514 696,724 2,029,685 1.1 N-HEXANE 0 1,060 5,243,892 4,343,100 8,195,184 23,256,610 12.7 TOLUENE 0 23 3,551,694 2,985,022 4,142,420 16,484,126 9.0 XYLENE (MIXED ISOMERS) 0 52 1,065,003 13,599,942 2,187,602 22,031,631 12.0

Off Site Total (lb) 37,792,324 877,937 1,371,233 23,546,623 75,394,728 42,060,305 183,043,150 On Site Total (lb): 143,250,825 0.48 0.75 12.86 41.2 23.0 % of All Four Sectors Onsite to Offsite Ratio: 80% 1,075,879,320 1,075,879,320 7.0% 17.0%



### Table 3.2 On Site Waste Category (lb) (2008 TRI)

## 12

## 13



## Table 4.1: TRI Production Related WASTE Reporting - Offsite Basic Organic Chemical Manufacturing BOM NAICS 325199



### Chemical Number of TRI Submissions Total

Underground Injection Total

Landfill Total Other

Management and Disposal Total Energy

Recovery (Cement Kiln) Total Thermal

Treatment (Incinerator) Total

Incineration Total Other

Tr ea tment (not POTW or wastewater) 1,2,4-TRIMETHYLBENZENE 25 231 839 0 2 23,254 34,730 463 ACETONITRILE 26 0 157 5 10,017 725,207 331,609 3,118 CHLOROBENZENE 20 0 0 16 0 38,417 1,085,928 89 CHLOROFORM 20 0 0 250 10,924 86,129 154,456 0 CHLOROMETHANE 20 0 0 0 340,000 1,402 151,341 0 CYCLOHEXANE 36 60,579 15 83,066 10,503 949,539 485,688 0 DICHLOROMETHANE 24 0 67 29 936,005 337,086 193,868 3,693 ETHYLBENZENE 45 122 12,612 36 121,706 1,537,739 61,909 2,646 METHANOL 203 196,440 29,206 41,237 4,740,094 18,837,345 4,367,696 34,615 METHYL ISOBUTYL KETONE 26 0 165 5 32,940 332,951 30,331 43 METHYL TERT-BUTYL ETHER 17 8, 148 15 15,406 846,850 172,196 18,039 0 N,N-DIMETHYLFORMAMIDE 15 0 658 0 72,650 64,978 6,157 16,065 N-BUTYL ALCOHOL 65 0 153 0 26,990 1,019,569 58,909 46 N-HEXANE 55 266 6 56,575 287,937 2,772,254 828,000 27,210 TOLUENE 99 2, 086 62,966 40,403 1,349,500 9,426,573 4,600,405 21,529 XYLENE (MIXED ISOMERS) 69 139 21,590 187,870 468,908 7,051,002 354,768 5,523
Totals 765 268,011 128,449 424,898 9,255,026 43,375,641 12,763,834 115,040 Relative to Sum of all Categories (%)

-- 0.04 0.02 0.06 1.4 6.4 1.9 0.0 Total All Four Sectors: 1,075,879,320 1,075,879,320 % of Total All Four Sectors: 0.9% 4.0%



### Table 4.1 Off Site Waste Category (lb) (2008 TRI)

## 14



## Table 4.2: TRI Production Related WASTE Reporting - Offsite Basic Organic Chemical Manufacturing BOM NAICS 325199

Chemical Total Underground Injection Total Landfill Energy Recovery Recycling Treatment Total Re lative to Sum of all Chemicals (%) 1,2,4-TRIMETHYLBENZENE 0 2 52,918 14,000 85,126 211,565 0.0 AC ETONITRILE 11,584,152 11 9,163,656 2,319,728 3,345,711 27,483,371 4.0 CHLOROBENZENE 25 12 598,199 1,047,198 1,150,884 3,920,768 0.6 CHLOROFORM 0 250 68,000 350,000 9,786,348 10,456,357 1.5 CHLOROMETHANE 0 0 3,600,851 508,485 3,747,316 8,349,395 1.2 CYCLOHEXANE 24,950 4,873 5,318,388 167,981 11,516,056 18,621,638 2.7 DICHLOROMETHANE 0 2,579 261 1,841,486 2,905,163 6,220,237 0.9 ETHYLBENZENE 0 4,102 2,067,830 2,777,434 1,999,578 8,585,714 1.3 METHANOL 4,840,685 14,899 31,275,885 254,012,698 64,483,532 382,874,332 56.2 METHYL ISOBUTYL KETONE 4,900 0 672 3,882,200 602,330 4,886,537 0.7 METHYL TERT-BUTYL ETHER 0 0 44,067 101,994 245,810 1,452,525 0.2 N,N-DIMETHYLFORMAMIDE 0 11,363 0 436,500 597,173 1,205,544 0.2 N-BUTYL ALCOHOL 0 5,029 1,920,577 4,316,302 12,724,577 20,072,152 2.9 N-HEXANE 0 544 2,669,198 16,251 8,116,571 14,774,812 2.2 TOLUENE 0 25,757 4,997,086 119,123,526 8,942,758 148,592,589 21.8 XYLENE (MIXED ISOMERS) 0 9,981 631,866 14,510,678 727,234 23,969,559 3.5

Off Site Total (lb) 66,330,899 16,454,712 79,402 62,409,454 405,426,461 130,976,167 681,677,095 On Site Total (lb): 615,346,196 2.41 0.01 9.16 59.5 19.2 All Four Sectors: Onsite to Offsite Ratio: 90% 1,075,879,320 1,075,879,320 37.7% 63.4%



### Table 4.2 On Site Waste Category (lb) (2008 TRI)

## 15

## 16

Table 4.4: Top Waste Reporters / Top Recyclers By % of Total Waste Table 4.4
Facility Name 

### Chemical Releases (lbs) Waste (l bs) Waste Divided by Release Recycled

ONSITE (lbs) %of total waste
U.S

. BIOFUELS INC. METHANOL 

### 2,250 6,654,105 2,957 6,653,105 99.98% EMERALD PERFORMANCE MATERIALS LLC TOLUENE 27,775 43,643,511 

### 1,571 43,600,537 99.90% WEYLCHEM US INC METHANOL 

### 120 2,561,945 21,350 2,558,844 99.88% VERTELLUS PERFORMANCE MATERIALS INC N-BUTYL ALCOHOL 

### 539 2,350,563 4,361 2,347,673 99.88% NOVA BIOFUELS SENECA LLC METHANOL 

### 4,485 3,504,760 781 3,500,086 99.87% WEYLCHEM US INC METHYL ISOBUTYL KETONE 

### 11 1,673,973 152,179 1,671,734 99.87% TPC GROUP LLC METHANOL 8,787 25,610,952 

### 2,915 25,511,849 99.61% PRODUCT DEVELOPMENT CENTER METHANOL 109,699 23,032,931 

### 210 22,901,905 99.43% DYNACHEM INC TOLUENE 

### 8,128 1,712,051 211 1,702,034 99.41% ALDRICH CHEMICAL CO INC METHANOL 

### 9,554 1,699,660 178 1,689,356 99.39% HERCULES INC METHANOL 362,314 112,891,979 

### 312 112,191,940 99.38% EMERALD PERFORMANCE MATERIALS LLC DICHLOROMETHANE 

### 14,741 1,633,491 111 1,618,616 99.09% EMERALD PERFORMANCE MATERIALS LLC ACETONITRILE 

### 27,580 2,232,316 81 2,202,853 98.68% CYTEC I NDUSTRI ES INC TOLUENE 

### 28,800 12,726,000 442 12,557,000 98.67% DIXIE CHEMICAL CO INC XYLENE (MIXED ISOMERS) 

### 492 10,868,088 22,090 10,700,000 98.45% SI GROUP INC ETH YLBENZENE 

### 968 1,320,120 1,364 1,290,000 97.72% LUBRIZOL CORP BAYPORT FACILITY METHANOL 

### 4,427 3,250,502 734 3,148,503 96.86% CYTEC I NDUSTRI ES INC METHYL ISOBUTYL KETONE 

### 28,920 2,418,820 84 2,337,000 96.62% DIXIE CHEMICAL CO INC TOLUENE 

### 990 2,268,782 2,292 2,170,000 95.65% CIBA CORP METHANOL 

### 2,244 1,440,177 642 1,376,375 95.57% DOW CORNING CORP MIDLAND PLANT TOLUENE 16,296 28,647,278 

### 1,758 26,915,699 93.96% EMERALD KALAMA CHEMICAL LLC METHANOL 

### 1,076 2,068,875 1,923 1,927,710 93.18% WEYLCHEM US INC XYLENE (MIXED ISOMERS) 

### 141 4,805,335 34,080 4,336,368 90.24% AMFI NE CHEMICAL CORP XYLENE (MIXED ISOMERS) 

### 1,940 1,781,915 919 1,603,915 90.01% CYTEC I NDUSTRI ES INC METHANOL 

### 26,830 10,491,630 391 9,411,000 89.70% WEYLCHEM US INC TOLUENE 

### 5,592 3,079,684 551 2,489,361 80.83% TICONA POLYMERS INC METHANOL 132,872 18,898,366 

### 142 14,822,000 78.43% DIXIE CHEMICAL CO INC METHANOL 

### 8,309 2,103,410 253 1,000,000 47.54% SYMRISE INC METHANOL 

### 13,887 1,770,138 127 467,187 26.39% DOW CHEMICAL CO CHLOROMETHANE 

### 11,800 1,271,800 108 150,000 11.79% CHEM FLUER/FIRMENICH INC METHANOL 

### 2,654 1,889,543 712 65,997 3.49% DOW CORNING CORP MIDLAND PLANT XYLENE (MIXED ISOMERS) 

### 8,565 2,940,605 343 50,724 1.72% BASF CORP Freeport TX METHANOL 12,470 22,738,108 

### 1,823 0 0.00%

TOTALS: 885,256 365,981,413 

### 413 324,969,371 88.79%

## 17

Table 4.5: Top Waste Reporters / Top Recyclers By Total Waste Table 4.5

Facility Name 

### Chemical Releases (l bs) Waste (lbs) Waste Divided by Release Recycled

ONSITE (lbs) %of total waste HERCULES INC, Hopewell METHANOL 362,314 112,891,979 

### 312 112,191,940 99.38% EMERALD PERFORMANCE, Henry TOLUENE 27,775 43,643,511 

### 1,571 43,600,537 99.90% DOW CORNING CORP MIDLAND PLANT TOLUENE 16,296 28,647,278 

### 1,758 26,915,699 93.96% TPC GROUP LLC METHANOL 8,787 25,610,952 

### 2,915 25,511,849 99.61% PRODUCT DEVELOPMENT CENTER METHANOL 109,699 23,032,931 

### 210 22,901,905 99.43% BASF CORP METHANOL 12,470 22,738,108 

### 1,823 0 0.00% TI CONA POLYMERS INC METHANOL 132,872 18,898,366 

### 142 14,822,000 78.43% CYTEC INDUSTRIES INC TOLUENE 

### 28,800 12,726,000 442 12,557,000 98.67% DIXIE CHEMICAL CO INC XYLENE (MIXED ISOMERS) 

### 492 10,868,088 22,090 10,700,000 98.45% CYTEC INDUSTRIES INC METHANOL 

### 26,830 10,491,630 391 9,411,000 89.70% U.S. BIOFUELS INC. METHANOL 

### 2,250 6,654,105 2,957 6,653,105 99.98% WEYLCHEM US INC XYLENE (MIXED ISOMERS) 

### 141 4,805,335 34,080 4,336,368 90.24% NOVA BIOFUELS SENECA LLC METHANOL 

### 4,485 3,504,760 781 3,500,086 99.87% LUBRIZOL CORP BAYPORT FACILITY METHANOL 

### 4,427 3,250,502 734 3,148,503 96.86% WEYLCHEM US INC TOLUENE 

### 5,592 3,079,684 551 2,489,361 80.83% DOW CORNING CORP MIDLAND PLANT XYLENE (MIXED ISOMERS) 

### 8,565 2,940,605 343 50,724 1.72% WEYLCHEM US INC METHANOL 

### 120 2,561,945 21,350 2,558,844 99.88% CYTEC INDUSTRIES INC METHYL ISOBUTYL KETONE 

### 28,920 2,418,820 84 2,337,000 96.62% VERTELLUS PERFORMANCE MATERIALS INC N-BUTYL ALCOHOL 

### 539 2,350,563 4,361 2,347,673 99.88% DIXIE CHEMICAL CO INC TOLUENE 

### 990 2,268,782 2,292 2,170,000 95.65% EMERALD PERFORMANCE MATERIALS LLC ACETONITRILE 

### 27,580 2,232,316 81 2,202,853 98.68% DIXIE CHEMICAL CO INC METHANOL 

### 8,309 2,103,410 253 1,000,000 47.54% EMERALD KALAMA CHEMICAL LLC METHANOL 

### 1,076 2,068,875 1,923 1,927,710 93.18% CHEM FLUER/FIRMENICH INC METHANOL 

### 2,654 1,889,543 712 65,997 3.49% AMFINE CHEMICAL CORP XYLENE (MIXED ISOMERS) 

### 1,940 1,781,915 919 1,603,915 90.01% SYMRISE INC METHANOL 

### 13,887 1,770,138 127 467,187 26.39% DYNACHEM INC TOLUENE 

### 8,128 1,712,051 211 1,702,034 99.41% ALDRICH CHEMICAL CO INC METHANOL 

### 9,554 1,699,660 178 1,689,356 99.39% WEYLCHEM US INC METHYL ISOBUTYL KETONE 

### 11 1,673,973 152,179 1,671,734 99.87% EMERALD PERFORMANCE MATERIALS LLC DICHLOROMETHANE 

### 14,741 1,633,491 111 1,618,616 99.09% CIBA CORP METHANOL 

### 2,244 1,440,177 642 1,376,375 95.57% SI GROUP INC ETHYLBENZENE 

### 968 1,320,120 1,364 1,290,000 97.72% DOW CHEMICAL CO CHLOROMETHANE 

### 11,800 1,271,800 108 150,000 11.79%

TOTALS: 885,256 365,981,413 

### 413 324,969,371 88.79%

## 18

Table 4.6: Top Waste Reporters / Top Recyclers By Chemical Table 4.6

Facility Name 

### Chemical Releases (l bs) Waste (l bs) Waste Divided byRelease Recycled

ONSITE (lbs) %of total waste EMERALD PERFORMANCE MATERIALS LLC ACETONITRILE 27,580 2,232,316 81 2,202,853 98.68% DOW CHEMICAL CO CHLOROMETHANE 11,800 1,271,800 108 150,000 11.79% EMERALD PERFORMANCE MATERIALS LLC DICHLOROMETHANE 14,741 1,633,491 111 1,618,616 99.09% SI GROUP INC ETHYLBENZENE 968 1,320,120 1,364 1,290,000 97.72% HERCULES INC METHANOL 362,314 112,891,979 312 112,191,940 99.38% TPC GROUP LLC METHANOL 8,787 25,610,952 2,915 25,511,849 99.61% PRODUCT DEVELOPMENT CENTER METHANOL 109,699 23,032,931 210 22,901,905 99.43% BASF CORP Freeport TX METHANOL 12,470 22,738,108 1,823 0 0.00% TICONA POLYMERS INC METHANOL 132,872 18,898,366 142 14,822,000 78.43% CYTEC INDUSTRIES INC METHANOL 26,830 10,491,630 391 9,411,000 89.70% U.S. BIOFUELS INC. METHANOL 2,250 6,654,105 2,957 6,653,105 99.98% NOVA BIOFUELS SENECA LLC METHANOL 4,485 3,504,760 781 3,500,086 99.87% LUBRIZOL CORP BAYPORT FACILITY METHANOL 4,427 3,250,502 734 3,148,503 96.86% WEYLCHEM US INC METHANOL 120 2,561,945 21,350 2,558,844 99.88% DIXIE CHEMICAL CO INC METHANOL 8,309 2,103,410 253 1,000,000 47.54% EMERALD KALAMA CHEMICAL LLC METHANOL 1,076 2,068,875 1,923 1,927,710 93.18% CHEM FLUER/FIRMENICH INC METHANOL 2,654 1,889,543 712 65,997 3.49% SYMRISE INC METHANOL 13,887 1,770,138 127 467,187 26.39% ALDRICH CHEMICAL CO INC METHANOL 9,554 1,699,660 178 1,689,356 99.39% CIBA CORP METHANOL 2,244 1,440,177 642 1,376,375 95.57% CYTEC INDUSTRIES INC METHYL ISOBUTYL KETONE 28,920 2,418,820 84 2,337,000 96.62% WEYLCHEM US INC METHYL ISOBUTYL KETONE 11 1,673,973 152,179 1,671,734 99.87% VERTELLUS PERFORMANCE MATERIALS INC N-BUTYL ALCOHOL 539 2,350,563 4,361 2,347,673 99.88% EMERALD PERFORMANCE MATERIALS LLC TOLUENE 27,775 43,643,511 1,571 43,600,537 99.90% DOW CORNING CORP MIDLAND PLANT TOLUENE 16,296 28,647,278 1,758 26,915,699 93.96% CYTEC INDUSTRIES INC TOLUENE 28,800 12,726,000 442 12,557,000 98.67% WEYLCHEM US INC TOLUENE 5,592 3,079,684 551 2,489,361 80.83% DIXIE CHEMICAL CO INC TOLUENE 990 2,268,782 2,292 2,170,000 95.65% DYNACHEM INC TOLUENE 8,128 1,712,051 211 1,702,034 99.41% DIXIE CHEMICAL CO INC XYLENE (MIXED ISOMERS) 492 10,868,088 22,090 10,700,000 98.45% WEYLCHEM US INC XYLENE (MIXED ISOMERS) 141 4,805,335 34,080 4,336,368 90.24% DOW CORNING CORP MIDLAND PLANT XYLENE (MIXED ISOMERS) 8,565 2,940,605 343 50,724 1.72% AMFINE CHEMICAL CORP XYLENE (MIXED ISOMERS) 1,940 1,781,915 919 1,603,915 90.01%

TOTALS: 885,256 365,981,413 413 324,969,371 88.79%

## 19

## 20

## 21 

## Table 5.1: All Four Sectors Combined

OFF SITE: Hazardous Waste Treatment and Disposal 2009TRI Rank by Release: 6 th Rank by Waste: 14th (430,593,831 lbs) Number of TRI submissions: 1673



### ONSITE: (In order of Rank by Waste): 

## Links below to RTKNet3



## . All Other Basic Organic Chemical Manufacturing 2009 Rank by Release: 7 th Rank by Waste: 1 st (2,507,659,932 lbs) Number of TRI submissions: 3230 Plastics Material and Resin Manufacturing 2009 Rank by Release: 15 th Rank by Waste: 3 rd (1,182,555,225 lbs) Number of TRI Su bmissions: 2472 Pharmaceutical Preparation Manufacturing 2009 Rank by Release: 75 th Rank by Waste: low (127,941,376 lbs) Number of TRI Submissions: 376 Paint and Coating Manufacturing 2009 Rank by Release: 61 st Rank by Waste: low (88,569,586 l bs) Number of TRI Submissions: 2187



### Pharmaceutical Sector Profile Notebook 

### : 4 

### http://www.epa.gov/compliance/resources/publications/assistance/sectors/notebooks/pharma.pdf Plastic & Resin Sector Profile Notebook : http://www.epa.gov/compliance/resources/publications/assistance/sectors/notebooks/resfibsn.pdf Basic Organic Chemical Manufacturing Sector Profile Notebook: http://www.cluin.org/download/toolkit/organic.pdf Paint & Coatings : No sector notebook, but all paints and coatings start with a film

-forming agent, which is a resin.

3 

### The Right

-to

-Know

Network provides free access to numerous databases and resources on the environment and provided facility information not readily available in the TRI database. www.RTKNET.org 4 

### EPA’s OECA Sector Notebook series is a unique set of profiles containing information for specific industries and governments. Unlike other resource materials, which are organized by air, water and land pollutants, the Notebooks provide a holistic approach by integrating processes, applicable regulations and other relevant environment information. http://www.epa.gov/compliance/resources/publications/assistance/sectors/notebooks/index.html

## 22



## Table 5.2: TRI Production Related WASTE Reporting - Offsite
Al l Four Sectors NAICS: 325412(Pharma); 325510(P & C); 325199 (BOM); 325211(P & R)



### Chemical Number of TRI Submissions Total

Underground Injection Total

Landfill Total Other

Management and Disposal 

### Total Recycling Total Energy Recovery (Cement Kiln) Total Thermal

Treatment (Incinerator) Total Other

Treatment (not POTW or wastewater) 

### 1,2,4-TRIMETHYLBENZENE 170 3,931 4,320 4,726 

### 136,244 1,437,608 98,611 20,826 

### ACETONITRILE 53 0 345 12,538 

### 3,396,731 3,247,303 2,482,669 52,912 

### CHLOROBENZENE 26 0 1,778 16 

### 954,563 98,284 1,474,568 42,388 

### CHLOROFORM 33 0 1 703 

### 75,575 352,627 407,603 0 

### CHLOROMETHANE 26 0 4 0 

### 340,000 1,454 190,141 0 

### CYCLOHEXANE 58 60,579 1,184 83,066 

### 15,077 1,498,635 642,809 2,369 

### DICHLOROMETHANE 85 0 343 3,594 

### 5,223,964 2,439,075 5,997,573 911,833 

### ETHYLBENZENE 223 7,349 15,016 7,343 

### 885,211 4,621,343 517,691 28,079 

### METHANOL 423 2,962,607 56,236 141,282 

### 13,367,148 46,238,336 7,301,373 1,504,679 

### METHYL ISOBUTYL KETONE 146 0 400 22,473 

### 3,234,301 2,294,715 1,151,935 16,900 

### METHYL TERT-BUTYL ETHER 32 8,148 115 20,268 

### 858,906 1,392,882 320,154 33,033 

### N,N-DIMETHYLFORMAMIDE 41 0 714 0 

### 74,830 4,050,722 91,790 317,956 

### N-BUTYL ALCOHOL 203 17,200 586 127,330 

### 635,449 2,909,314 268,678 73,636 

### N-HEXANE 96 266 57 57,983 

### 2,464,066 5,845,630 1,227,165 233,397 

### TOLUENE 399 13,463 81,288 132,032 

### 5,142,989 26,123,013 7,587,212 535,841 

### XYLENE (MIXED ISOMERS) 388 45,221 26,431 213,713 

### 4,615,416 22,433,393 1,545,413 148,771


### Totals 2402 3,118,764 188,819 827,067 41,420,470 124,984,334 31,305,385 3,922,620 Relative to Sum of all Categories (%)

-- 0.3 0.0 0.1 3.8 11.6 2.9 0.4 Total All Four Sectors: 1,075,879,320 1,075,879,320 1,075,879,320 % of Total All Four Sectors: 3.8% 11.6% 2.9%



### Table 5.2 Off Site Waste Category (lb) (2008 TRI)

## 23



## Table 5.3: TRI Production Related WASTE Reporting - Offsite
Al l Four Sectors NAICS: 325412(Pharma); 325510(P & C); 325199 (BOM); 325211(P & R)



### Chemical Total Underground Injection Total Landfill Energy Recovery Recycling Treatment Total Relative to Sum of all Chemicals (%) 

### 1,2,4-TRIMETHYLBENZENE 0 37 52,919 2,150,633 251,129 4,160,984 0.4 ACETONITRILE 11,586,952 11 9,164,203 3,241,374 5,922,292 39,107,330 3.6 CHLOROBENZENE 25 12 741,069 9,124,061 1,270,765 13,707,529 1.3 CHLOROFORM 0 250 636,587 350,000 12,659,737 14,483,083 1.3 CHLOROMETHANE 0 0 4,997,370 508,485 6,527,367 12,564,821 1.2 CYCLOHEXANE 33,550 4,873 5,318,388 25,545,111 13,437,495 46,643,136 4.3 DICHLOROMETHANE 8,500 2,579 66,517 7,918,616 5,373,362 27,945,956 2.6 ETHYLBENZENE 0 4,135 3,312,400 9,709,263 2,547,115 21,654,945 2.0 METHANOL 5,232,503 1,384,940 37,924,873 295,437,754 88,711,244 500,262,975 46.5 METHYL ISOBUTYL KETONE 4,900 0 872,736 16,100,205 1,854,604 25,553,169 2.4 METHYL TERT-BUTYL ETHER 0 0 44,067 101,994 444,531 3,224,098 0.3 N,N-DIMETHYLFORMAMIDE 330,000 11,363 3,330,858 2,299,580 1,460,364 11,968,177 1.1 N-BUTYL ALCOHOL 490,519 5,029 2,111,294 9,990,516 14,669,124 31,298,675 2.9 N-HEXANE 0 1,604 7,930,078 4,505,697 16,356,834 38,622,777 3.6 TOLUENE 0 25,780 8,548,780 132,917,024 15,163,374 196,270,796 18.2 XYLENE (MIXED ISOMERS) 0 10,033 1,696,869 54,029,554 3,646,054 88,410,868 8.2

Off Site Total (lb) 235,448,248 17,686,949 1,450,646 86,749,008 573,929,867 190,295,391 1,075,879,320 On Site Total (lb): 870,111,861 1.6 0.1 8.1 53.3 17.7 % of All Four Sectors Onsite to Offsite Ratio: 78% 1,075,879,320 1,075,879,320 53.3% 1216.9%



### Table 5.3 On Site Waste Category (lb) (2008 TRI)

## 24

## 25 

## APPENDIX 2: Regional Maps: 5 

## Transportation and co
- located Potential Remanufacturing Facilities Figure 6.1 Pharmaceutical: Merck, Elkton, VA Figure 6.2 Pharmaceutical: Roche, Florence, SC Figure 6.3 Pharmaceutical: Synthetic, Albany, OR Figure 6.4 Basic Organic: Cytec, Willow Island, WV Figure 6.5 Basic Organic: Weylchem, Elgin SC Figure 6.6 Basic Organic: Dynachem, Georgetown, IL Figu re 6.6 Basic Organic Cytec & Pharmaceutical Merck Figure 6.7 Basic Organic Weylchem & Pharmaceutical Roche Figure 6.8 Basic Organic Dynachem & Pharmaceutical Pfizer (Map 2)

5 

### Regional Maps: Facilities in Region reporting toluene > 25,000 lbs waste. Includes current offsite disposal routes and locations of potential remanufacturing facilities.

## 26

## 27

## 28

## 29

## 30

## 31

## 32

## 33

## 34



## APPENDIX 3: New Ch emicals Assessment: Release and Exposure from Toluene Fuel Blending 7.1 Premanufacture Notice (PMN) Process Flow Chart 7.2 New Chemical assessment as it relates to the Remanufacturing Exclusion 7.3 ChemSTEER Worksheet: Manufacture and use (destroyed) as an intermediate Figure 7.1 Puerto Rico Map: Transport of Toluene from Pfizer to disposal 7.5 ChemSTEER worksheet: Fuel Blending (unload, blend, load) Activity 7.6 ChemSTEER: Fuel Blending: ENVIRONMENTAL RELEASES ESTIMATE SUMMARY 7 .7 ChemSTEER: Fuel Blending: OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY Figure 7.2 Cement Kiln US Sector Map

## 35 

## Appendix 3 7.1: New Chemical assessment and Releases & Exposures from Fuel Blending A primary

responsibility in the Office of Pollution Prevention and Toxics, via the Toxic Substance Control Act (TSCA), is the assessment of a new chemical, known as Premanufacture Notice (PMN). The Chemical Engineering Branch 6 

## estimates the worker exposure and releases for the manufacturing, processing and use of a new chemical substance utilizing the ChemSTEER model.

6 

### The Chemical Engineering Branch manages the Green Engineering Program, and the Industrial Chemistry Branch manages the Green Chemistry Program. In

-house risk assessment is inherent in both of these voluntary partnership programs.

## 36

7.2: New Chemical Assessment as it relates to the Remanufacturing Exclusion
Chemical Screening Tool For Exposures & E nvironmental Releases The chemical engineering branch performs worker exposure and environmental release assessments for the manufacture (chemical created), processing (chemical neither created nor destroyed), and use (chemical destroyed or no longer available for release or exposure) of a new chemical substance. Tools and scenarios have been developed to assess further downstream (use operations) in order to fill in blanks of our assessment of nearly 2000 chemicals annually. All that is needed is the amount of material (lbs), basic physical

– chemical properties (vapor pressure), and the operation. In the case of the manufacture of a new chemical, the input mass (production volume) is known. In the case of the Remanufacturing Exclusion, the output mass from processing is known. This is the TRI Production Related Waste reporting

– often referred to as ‘waste’, where a submission reports specific pounds of chemicals to both onsite (chemical industry) and offsite (hazardous waste industry) transfers. Another ‘known’ or can be modeled are the emissions from particular (unit) operations, as a similar operation will have a similar release and exposure. In addition, we know of the manufacturing emissions to create the solvents. So a partial life cycle assessment can be performed using TRI reported measured flows and modeled emissions. (See Appendix 4, Mass Balance Model) As creation and destruction is the largest footprint, any thing to extend the processing life of the solvent has multiple benefits in multiple medias. DSW Remanufacturing Exclusion Ma nufacturing - Beginning of L ife (BOL) (solvent is created) Create: Reactor (never 100% complete) Separate: Evaporate to gas & condense to liquid Site(s) typically controlled by the submitter mi nim al in num ber (1 - 3), lower # of workers larger, single point releases



### Ma nufacturing Aid Solvent @ 85% Processing - Extensionof L ife(EXOL) (solvent neither created or destroyed) Separate: Evaporate to gas & condense to liquid 

### Remanufacture STEAM: Solvent Reprocessing (distillation)

Sites controlled by the submitter and others


### TRI W aste Reporting (mass)
Process Activity: fuel blend before destroy Use - E ndof L ife(EOL) (solvent destroyed or transformed) Destroy: Cement Kiln (ER), Incinerator (I) 

### (no longer available for release or exposure) No longer available: u ndergrou nd inj ection , landfill Sites typically controlled by others Canhave 1000's use sites, large # of workers 

### Reprocess after

use as ma nufacturing aid @ 85%

## 37

7.3: ChemSTEER Worksheet

– Manufactured and used as an intermediate (destroyed) 7

7 

### Austin, S., Chicago Completed CS Worksheet, ChemSTEER Training Materials posted on ChemSTEER website and incor porated in all Sustainable Futures training materials.

OPERA TI ON(S): Media of Release Exposure Routes Workplace / workplaces with same/similar operations Water Inhalation such that estimates of releases and exposures Air Dermal can be assumed to be the same. Landfill Drinking water Incineration Manufacturing VP 1 (PMN chemical is created or formed) Exampl e Release(s) MW 150 sem i volatile liquid * equipment cleaning *l g vessel Density 0.815 Production Volum e? 100,000 kg * sam pling x Sol # of sites? 1 *rinsed w/ water every 5 batches Batchsize? 1000 Batches/Year? Exposure Activities(s) Wt fraction? 80% * loading into transport SAT/Model # of workers? 4 containers * ECO (EpiSuite) * sam pling x Health (SARs) Site(s) typically controlled by the submitter *l oaded into 40 gallon drums mi nim al in num ber (1 - 3), lower # of workers larger, single point releases SUBSEQUENTOPERATION: transport of product / chem ical: % and type of container: Processing (PMN chemical neither created or destroyed0 raw materials Exampl e Release(s) (product/chem ical) * equipment cleaning OR # of sites? * container residue im port PMN batches per year or operating days? Volum e Imported? Wt fraction chemical in product? # of workers? Exposure Activities(s) * unloading & loading containers * vapor release fromunloading Sites controlled by the submitter and others & loading operations SUBSEQUENTOPERATION: transport of product / chem ical: % and type of container: Use (PMN is transform ed or destroyed) Exampl e Release(s) *equipment cleaning raw materials *container residue incinerated Use Rate? 10 kg formu lation / site/ day * End use releases destroyed %PMN in Product # of sites? 80% in form ulation, Operating days/year? 250 Exposure Activities(s) 40 gallon drums # of workers 3 per site unloading transport containers x end use activities: Sites typically controlled by others * coating applications Can have 1000's use sites, large # of workers * unit operations and processing smaller releases over a number of sites * Mi scellaneous activities

## 38

The High energy

value toluene (red line) and low energy value methanol (blue line) arrive at port in Houston or Elizabeth and transported to a holding station such as Port Arthur and Flanders. RCRA regulations limit holding tim e to 10 days, so some of the HSMi s moved around until enough is accumulated for fuel blending (RCRA code HO61

- purple line ) in the correct ratios. Fuel blending can occur at permitted recyclers, such as in M iddlesex but is regularly

d one by

cement kilns such as Fredonia and Pauling. Fuel blended materials go to incinerators and cement kilns in Greencastle, Logansport, Bath, East Liverpool, and Fredonia.

The Trip from Puerto Rico

– Basic Building Block Chemicals (T oluene & Methanol) Mile s T raveled: Houston TX to Fredonia KS: 607 Elizabeth NJ to Pauling OH : 621 Elizabeth NJ to Fredonia KS: 1418

Port Blend & Dispo se

Ho lding Sta

tion Transport



# MANIFEST:

Building Block Chemicals 

# Toluene & Methanol

## 39

7.5: ChemSTEER Worksheet

– Fuel Blending (unload, blend, load) Activity

OPERA TI ON(S): 

### Media of Release Exposure Routes Workplace / workplaces with same/similar operations 

### Water Inhalation such that estimates of releases and exposures 

### Air Dermal can be assumed to be the same. Landfi ll Drinking water Inci nerati on
Tolu ene Manufacturing VP 22 Torr (PMN chemical is created or formed) 

### Exam ple Release(s) MW * equi pment cleaning Density Production Volu me? 

### * sampli ng Sol # of sites? Batch size? Batches/Year? 

### Exposure Activi ti es(s) Wt fraction? 

### * l oading into transport SA T/Model # of workers? 

### containers ECO (EpiSuite) 

### * sampli ng Health (SARs) Site(s) typically controlled by the subm itter mi nim al in num ber (1 - 3), lower # of workers larger, single point releases



### Processing BARGE to Houston (Solvent neither created or destroyed0 

### 3804 tons Exam ple Release(s) 

### Pfizer, Puerto Rico Source/Activity: Fuel Blending * equi pment cleaning 

### OR 1 - Unloading (truck) * contai ner residue im port PMN 2 - Blending (tank) Trucks 3 - Reloading (truck) Exposure Activi ti es(s) # of sites? 

### 390 * unl oading & loading containers batches per year or operating days? 

### * vapor release fromunloading Wt fraction chemical in product? 

### 80% & loading operations # of workers? assumes 1 per activity 

### SUBSEQUENTOPERA TI ON: transport of product / chem ical: % and type of container: 

### Use (olvent is destroyed inCement Kiln ) 

### Exam ple Release(s) Blended Toluene 15 Cement Kilns *equipment cleaning 

### 3804 tons Source/Activity: Unloading *container residue * End use releases Use Rate? 

### TRI Reporting # of sites? 

### 15 Exposure Activi ti es(s) Operating days/year? 

### 350 unloading transport containers # of workers 

### end use activities: * coating applications Can have 1000's use sites, large # of workers 

### * uni t operations and processing
sm aller releases over a nu mber of sites 

### * Miscel laneous activities

## 40

7.6: ENVIRONMENTAL RELEASES ESTIMATE SUMMARY: Toluene Fuel Blending

Water or Incineration High End: 2.6E+1 kg/site

-day over 1 day

/y r from 130 sites or 3.4E+3 kg/y r from: Cleaning Liquid Residuals from Tank Trucks Used to Transport the Raw Material basis: EPA/OPPT Bulk Transport Residual Model, CEB standard 0.2% residual.
Water or Incineration or Landfill Conservative: 1.1E+0 kg/site

-day over 1 day

/y r from 130 sites or 1.4E+2 kg/yr from: Equipment Cleaning Losses of Liquids from a Single, Large Vessel basis: EPA/OPPT Single Vessel Residual Model, CEB standard 1% residual. annual tank cleanout. media of release is uncertain.

Air Output 2: 3.6E

-3 kg/site

-day over 250 days/yrfrom 130 sites from: Equipment Cleaning Losses of Liquids from a Single, Large Vessel basis: EPA/OPPT Mass Transfer Coefficient Model.
Air Ty pical: 8.5E

-3 kg/site

-day

over 250 days/yrfrom 1 30 sites Worst Case: 8.5E

-3 kg/site

-day over 250 days/yr from 130 sites from: Loading Liquid Product into Tank Trucks basis: EPA/OAQPS AP

-42 Loading Model.
Air Ty pical: 8.5E

-3 kg/site

-day

over 250 days/yrfrom 130 sites Worst Case: 8.5E

-3 kg/site

-day over 250 days/yr from 130 sites from: Unloading Liquid Raw Material from Tank Trucks basis: EPA/OAQPS AP

-42 Loading Model.
Air Output 2: 3.3E

- 5 kg/site

-day over 250 days/yrfrom 130 sites from: Cleaning Liquid Residuals from Tank Trucks Used to Transport the Raw Material basis: EPA/OPPT Mass Transfer Coefficient Model.

Incineration High End: 3.4E+3 kg/yr from: Cleaning Liquid Residuals from Tank Trucks Used to Transport the Raw Material basis: EPA/OPPT Bulk Transport Residual Model, CEB standard 0.2% residual.

RELEASE TOTAL 8.1E+3 kg/yr
- all sites

## 41

7.7: OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

– Toluene Fuel Blending Total # of workers: 390 Days/y r: 250
Inhalation: Exposure to Vapor (Class II) Ty pical: 1.6E+2 mg/day

over 250 days/yr Worst Case: 4.7E+3 mg/day over 250 days/yr Number of workers (all sites) with inhalation exposure: 130 Loading Liquid Product into Tank Trucks; Basis: EPA/OPPT Mass Balance Model
. NOTE: The respirator class is: II. Gas/vapor (all substances in the gas form). Exposure to Vapor (Class II) Ty pical: 1.9E+2 mg/day

over 250 days/yr Worst Case: 5.7E+3 mg/day over 250 days/yr Number of workers (all sites) with inhalation exposure: 130 Unloading Liquid Raw Material from Tank Trucks; Basis: EPA/OPPT Mass Balance Model. NOTE: The respirator class is: II. Gas/vapor (all substances in the gas form). Exposure to Vapor (Class II) Ty pical: 9.2E

-3 mg/day

over 250 days/yr Worst Case: 8.3E

-2 mg/day over 250 days/yr Number of workers (all sites) with inhalation exposure: 130 Cleaning Liquid Residuals from Tank Trucks Used to Transport the Raw Material; Basis: EPA/OPPT Mass Balance Model. NOTE: The respirator class is: II. Gas/vapor (all substances in the gas form).
Dermal: Exposure to Liquid at 82.50% concentration High End: 1.5E+3 mg/day over 250 days/yr Number of workers (all sites) with dermal exposure: 390 Loading Liquid Product into Tank Trucks, Unloading Liquid Raw Material from Tank Trucks, and Cleaning Liquid Residuals from Tank Trucks Used to Transport the Raw Material ; Basis: EPA/OPPT 2

-Hand Dermal Contact with Liquids Model.
Health Effects 8 

## of Toluene : Recognized: Developmental Toxicant Suspected: Cardiovascular or Blood toxicant, Gastrointestinal of Liver toxicant, Immunotoxicant, Kidney Toxicant, Neurotoxicant, Reproductive Toxicant, Respiratory Toxicant, Skin or Sense Organ Toxicant.

8 

### Scorecard is the web's most popular resource for information about pollution problems and toxic chemicals. www.Scorecard.org

## 42

## 43

APPENDIX 4 8.1: Mass Balance Model



## Left side incorporates all current TRI reporting in the four sectors, in which cement and incinerator operations are off

- site. The Right side shifts current off

- site disposal to on

- site recycling, in which portions are sent to cement and incinerator operations. Cement Kiln (ER) Incinerator (I)

ER EOL I EOL NEW ER EOL INEW EOL

U L Offsite ER EOL (end of life) Offsite I EOL (end of life) 

### Cement kiln Incinerator 2008 Solvent Mass (tonne) MASS 9,436 744 56,682 14,111 260,055 239,251 480,450 30,831 7,605 442,014 442,014 Air emission (tonne) CO2

-- -- 267,961 86,555 58,553 464,619 104,657 130,431 47,577

-- 954,213 CH4

-- -- 725 284 107 2,716 191 369 162

-- 5,368 N2O

-- -- 2 0.8 0 5 0 1 0

-- 11 CO

-- -- 316 71 41 793 73 148 39

-- 1,642 NMVOC

-- -- 476 117 298 2,208 532 286 61

-- 3,953 NOx

-- -- 251 88 193 972 344 129 44

-- 1,884 SOx

-- -- 944 426 256 3,145 458 440 241

-- 6,582 Water emission (tonne) TOC

-- -- 450 120 2 2,287 3 299 66

-- 4,170 BOD

-- -- 30 14 14 99 26 14 8

-- 206 COD

-- -- 1,802 480 5 9,190 8 1,201 261

-- 16,750 TDS

-- -- 6,393 3,056 266 20,131 476 2,863 1,771

-- 43,173 Solid waste (tonne) Solid waste

-- -- 1,684 735 126 5,788 225 786 391

-- 11,835 Energy / Carbon MMBTU

-- -- 3,197,671 757,633 701,940 5,998,413 1,254,640 1,558,942 424,185

-- 12,372,487 MT CO2e

-- -- 283,707 92,757 60,802 523,253 108,676 138,399 51,114

-- 1,070,380 Emission Type a, b Underground

Injection (U) and Landfill (L) Recovered Solvent (92% jof Distilled Ma ss) NEW BOL

Mnfctring Emissions (ME) 

### NewRecycling (Bottoms - 92% recovery, double steam) NEW RECYCLING Mnfctring Emissions (ME)

ST EAM New Solvent Mass going to Steam f Current Recycling (75% reported in haz waste)

ST EAM Onsite Reported Recycling Mass f Baseline BOL

Mnfctring Emissions (ME)

## 44

APPENDIX 4 8.2: Modules Embedded in Mass Balance Model One can enter a mass into the mass balance model, which has emission modules embedded into it. Following is the representative module, acronym, and color code that is utilized in the mass balance model. 

## End of Life (EOL)

 The GlaxoSmithKline (GSK) Life Cycle Assessment Waste Treatment Modules9

### , o GSK Incinerator (I) models emissions from mass sent to incinerator:

 the combustion of solvents put in the incinerator ‘oven’,

 the manufacturing emissions of the solvents destroyed in the oven,

 and the Natural Gas used as fuel to heat the oven.

o Energy Recovery (ER) (GSK Adapted) models emissions from mass sent to Cement kiln:

 solvents burned as fuels to heat the cement kiln,

 and the manufacturing emissions from the solvents destroyed.



## Extension of Life (EXOL)

o GSK Solvent Recovery models emissions from steam needed to evaporate the solvent



## Beginning of Life (BOL)

 GSK (embedded) and Zurich Institute 10 

### (adapted) Manufacturing Emissions o The GSK solvent recovery model derived manufacturing emissions to all media for 7 of our solvents: dichloromethane, dimethylformamide, hexane, methanol, THF, toluene (& ethanol) o The Zurich Institute derived Solvent Production energy numbers. These numbers were derived by ERG 11 

### to incorporate emissions to all media for Acetonitrile, butanol, cyclohexane, and methyl ethyl ketone. o The remaining solvents were derived by ERG 12 

### using structural properties.

 ERG 13 

### Natural Gas LCI was used to model emissions from natural gas used as Fuel (EOL & BOL) o Incorporated N20 [not in GSK] o Incorporated LCI [GSK was LCI but did not have N20]

9 

### Gonzalez, Overcash and Curzons, Waste Treatment Modules

– a Partial Life Cycle Inventory, Journal of Chemical Technology and Biotechnology, 76: 707

-706, 2001 10 

### Hungerbuhler, et al,, ETH Zurich Institute for Chemical and Bioengineering , What is a green Solvent? A comprehensive framework for the environmental assessment of solvents, Table 2; Results of the life

-cycle assssment of 26 organic solvents, Green Chemistry Jounal, pg 927

-934, 2007. 11 

### The ETH Zurich paper (Capello et al.) only provides the cumulative energy demand (CED) for the production of each solvent. To estimate emissions, it was assumed that the CED is supplied entirely by natural gas. Cradle

-to

-gate (combustion) life cycle inventory (LCI) data for natural gas were used to estimate the emissions associated with the manufacture of a solvent. 12

### These solvents were assumed to have manufacturing emissions equal to a similar chemical included in the GSK model or a CED equal to a similar chemical included in Capello et al. Chloroform was assumed equal to dichloromethane and methyl tert

-butyl ether was assumed equal to those of ethyl ether (GSK). Chlorobenzene was assumed equal to ethylbenzene; methyl isobutyl ketone was assumed equal to methyl ethyl ketone; and 1,2,4

-trimethylbenzene was assumed equal to xylenes (Capello et al). 13 

### Calculated by ERG, based on updates to LCI data available in the U.S.LCI Database. 

### I (EOL)

ER (EOL)

ST EAM

ME (BOL)

Natural Gas