# Patent

## Title
Light-emitting device

## Abstract

This application discloses a light-emitting device comprising a light-emitting stack layer, a first transparent conductive layer disposed below the light-emitting stack layer, a transparent dielectric barrier layer disposed below the first transparent conductive layer, a second transparent conductive layer disposed below the transparent dielectric barrier layer and a metal reflective layer disposed below the second transparent conductive layer wherein an omni-directional reflector (ODR) comprises the metal reflective layer and the second transparent conductive layer. Besides, the first transparent conductive layer is ohmically connected with the light-emitting stack layer.

## Background
TECHNICAL FIELD
The present application relates to a light-emitting device, more particularly to a light-emitting device comprising a dielectric barrier layer disposed between a first transparent conductive oxide layer and a second transparent conductive oxide layer.
BACKGROUND
The light-emitting mechanism of the LED is to release energy generated from the energy gap between an n type semiconductor layer and a p type semiconductor layer by emitting photons thereafter. Because the above mechanism is different from the lighting mechanism of the light bulb, the light-emitting device is named cold light source. Moreover, LED also shows significant improvement in liability, lifetime, flexible application and power saving. Therefore, LED is a long-excepted innovation in the light source industry and considered as one of the preferred lighting device for the next generation.
FIG. 1 is a structure diagram of a conventional light-emitting diode. As shown in
FIG. 1, a conventional light-emitting device 100 comprises a conductive substrate 10, a metal adhesive layer 12 disposed on the conductive substrate 10, an omni-directional reflector layer 14 disposed on the metal adhesive layer 12, an ohmic contact layer 15 disposed on the omni-directional reflector layer 14, a light-emitting stack layer 16 disposed on the ohmic contact layer 15, and an electrode 18 disposed on the light-emitting stack layer 16 wherein the ohmic contact layer 15 can be a transparent conductive material such as a transparent conductive oxide layer or a thin metal.
In the conventional light-emitting device 100, the light-emitting stack 16, from top,to bottom, comprises a first conductive semiconductor layer 160, a light-emitting layer 162 and a second conductive semiconductor layer 164. The omni-directional reflector layer 14 further comprises a metal reflective layer 140 and a low refractive index layer 142 having lower refractive index comparing with metal reflective layer 140, wherein the material of the metal reflective layer 14 can be Au and Silver, and the material of the low refractive index layer 142 can be SiO2 and Indium Tin Oxide (ITO). In addition, the omni-directional reflector layer 14 further comprises a plurality of ohmic contact dots 144 penetrating through the low refractive index layer 142, and electrically connecting with the ohmic contact layer 15 and the metal refractive layer 140 respectively to conduct current flow so that the electrical performance of the conventional light-emitting device 100 is improved.
However, during the manufacturing process of the above light-emitting diode 100, high thermal processing would incur reaction between the ohmic contact layer 15 and the low refractive index layer 142 of the omni-directional reflector layer 14, and therefore decrease brightness efficiency of the light emitting diode 100. Moreover, the ohmic metal contact point 144, disposed for increasing electrical conductive characteristic of the light-emitting diode 100, is likely to absorb lights emitted from the light emitting layer 162 so as to decrease the lighting efficiency of the light-emitting diode 100.
Besides, the light-emitting device 100 can be combined with other elements to form a light-emitting apparatus. FIG. 4 is a diagram of a conventional light-emitting apparatus. As shown in FIG. 4, a light-emitting apparatus 600 comprises a sub-mount 60 having at least a circuit 602, one solder 62 and an electrical connecting structure 64. The solder 62 is disposed on the sub-mount 60 so as to bond the light-emitting device 100 to the sub-mount 60 and electrically connect the substrate 10 of the light-emitting device 100 with the circuit 602. The electrical connecting structure 64 electrically connects the electrode 18 of the light emitting diode 100 with the circuit 602 of the sub-mount 60 wherein the sub-mount 60 can be a lead frame or a mounting substrate for the purpose of circuit arrangement and heat dissipation.
SUMMARY
The present application is to provide a light-emitting device comprising a light-emitting stack layer, a first transparent conductive oxide layer disposed under the light-emitting stack layer and forming ohmic contact in between, a transparent dielectric barrier layer disposed under the first transparent conductive oxide layer, a second transparent conductive oxide layer disposed under the transparent dielectric barrier layer and a metal reflective layer, wherein an omni-directional reflector is formed of the metal reflective layer and the second transparent conductive oxide layer. With the ohmic contact between the first transparent conductive oxide layer and the light-emitting stack layer, the lighting efficiency of the light-emitting device is increased.
In accordance with the present application, the transparent dielectric barrier layer is utilized for avoiding light-absorbing or light-shielding issues due to cross reaction between the second transparent conductive oxide layer and the first transparent conductive oxide layer or the metal reflective layer incurred by the following high thermal manufacturing process.
Other features and advantages of the present application and variations thereof will become apparent from the following description, drawing and claims.



BRIEF DESCRIPTION OF THE DRAWINGS
The foregoing aspects and many of the attendant advantages of this invention will become more readily appreciated as the same becomes better understood by reference to the following detailed description, when taken in conjunction with the accompanying drawings, wherein:
FIG. 1 is a structure diagram illustrating a conventional light-emitting diode.
FIG. 2 is a structure diagram in accordance with one embodiment of the present application.
FIG. 3 is a structure diagram in accordance with another embodiment of the present application.
FIG. 4 is a diagram illustrating a conventional light-emitting apparatus.



DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The accompanying drawings incorporated herein provide a further understanding of the invention therefore constitute a part of this specification. The drawings illustrating embodiments of the invention, together with the description, serve to explain the principles of the invention.
FIG. 2 is a structure diagram in accordance with one embodiment of the present application. As shown in FIG. 2, a light-emitting device 200 comprises a conductive substrate 20, an adhesive layer 22 disposed on the conductive substrate 20, an omni-directional reflector (ODR) 24 disposed on the adhesive layer 22, a first transparent conductive oxide layer 26 disposed on the omni-directional reflector 24, a light-emitting stack layer 28 disposed on the first transparent conductive oxide layer 26, and an electrode 30 disposed on the light emitting stack layer 28, wherein a transparent dielectric barrier layer 32 is further disposed between the omni-directional reflector 24 and the first transparent conductive oxide layer 26, and the omni-directional reflector layer 24, from top to bottom, further comprises a second transparent conductive oxide layer 240 and a metal reflective layer 242. In addition, the light emitting stack layer 28 comprises a first conductive semiconductor layer 280, a light-emitting layer 282 and a second conductive semiconductor layer 284, wherein the above light-emitting stack layer 28 can be III-V semiconductor materials comprising elements selected from the group consisting of Al, Ga, In, P, As, or N, such as GaN, AlGaInP, or GaAs. The structure of the light emitting layer 282 can be single heterostructure (SH), double heterostructure (DH), double-side double heterostructure (DDH), or multi-quantum well (MQW).
In this embodiment, the material of the conductive substrate 20 can be semiconductor material such as silicon, ceramic material such as ZnO, or metal material such as copper, aluminum or molybdenum, or combinations thereof. Materials of the adhesive layer 22 can be Indium, Tin, Au, Al, Silver and combinations thereof. The materials of the first transparent conductive oxide layer 26 and the second transparent conductive oxide layer 240 can be Indium Tin Oxide (ITO), Aluminum Zinc Oxide (AZO), SnCdO, Antimony Tin Oxide (ATO), ZnO or ZnSnO (ZTO), wherein the grain size and the reflective index of the first transparent conductive oxide layer 26 is different from those of the second transparent conductive oxide layer 240. In this embodiment, the average grain size of the first transparent conductive oxide layer 26 is larger than the average grain size of the second transparent conductive oxide layer 240, and the refractive index of the first transparent conductive oxide layer 26 is smaller than that of the second transparent conductive oxide layer 240. In addition, the material of the metal reflective layer 242 can be high refractive index materials such as In—Sn—Al—Au—Pt—Zn—Ag—Ti—Pb—Ge—Cu—Ni—AuBe—AuGe—AuZn, or PbSn. The material of the transparent dielectric barrier layer 32 can be SiO2—SiNx or Al2O3. The thickness of the transparent dielectric barrier layer 32 is about 5 nm to 300 nm.
Moreover, in this embodiment, for achieving good electrical conduction, the transparent dielectric barrier layer 32 further comprises a through region, comprising one or more than one through holes 320, wherein the first transparent conductive oxide layer 26 fills the through hole 320 and electrically connects with the second transparent conductive oxide layer 240. In this embodiment, the area of the through region is less than 40 percent of the area of the transparent dielectric barrier layer 32, and the area of the through hole 320 less than 5 percent of the area of the transparent dielectric barrier layer 32 is preferred.
In this embodiment, because the first transparent conductive oxide layer 26 is also an ohmic contact layer forming ohmic contact with light-emitting stack layer 28, and the first transparent conductive oxide layer 26 is electrically connected with the second transparent conductive oxide layer 240, it is not necessary to contain light-absorbing material to improve the electrical performance, and the possibility of the absorption of light emitted from the light emitting layer 282 is also reduced. Moreover, the transparent dielectric barrier layer 32 is disposed between the first transparent conductive oxide layer 26 and the second transparent conductive oxide layer 240 disposed on the omni-directional reflector layer 24 so as to prevent reaction between the first transparent conductive oxide layer 26 and the second transparent conductive oxide layer 240 at the high thermal environment during manufacturing process. Therefore, the brightness of the light emitting device 200 is raised.
FIG. 3 is a structure diagram in accordance with another embodiment of the present application. As shown in FIG. 3, the light-emitting device 300 comprises a substrate 40, an adhesive layer 42 disposed on the substrate 40, an omni-directional reflector (ODR) 44 disposed on the adhesive layer 42, a first transparent conductive oxide layer 46 disposed on the omni-directional reflector (ODR) 44, and a light emitting stack layer 48 disposed on the first transparent conductive oxide layer 46, wherein a transparent dielectric barrier layer 50 is further disposed between the omni-directional reflector 44 and the first transparent conductive oxide layer 46, and the omni-directional reflector 44, from top to bottom, further comprises a second transparent conductive oxide layer 440 and a metal reflective layer 442.
In addition, from top to bottom, the light emitting stack layer 48 comprises a first conductive semiconductor layer 480, a light emitting layer 482 and a second conductive semiconductor layer 484. The light emitting stack layer 48 has a surface exposing the second conductive semiconductor layer 484. A first electrode 52 and a second electrode 54 are disposed on the first conductive semiconductor 480 and the surface exposing the second conductive semiconductor layer 484 respectively. The light emitting stack layer 48 can be elements selected from the group consisting of III-V semiconductor materials comprising Al, Ga, In, P, As, or N, and combination thereof, such as GaN, AlGaInP, or GaAs. The structure of the light emitting layer 282 can be heterostructure (SH), double heterostructure (DH), double-side double heterostructure (DDH), or multi-quantum well (MQW).
In this embodiment, the material of the substrate 40 can be semiconductor material such as silicon or GaAs, ceramic material such as AIN or Al2O3, or metal material such as copper, aluminum or molybdenum, and combination thereof. Materials of the adhesive layer 42 can be Indium, Tin, Au, Al, Silver, alloys thereof, PI, BCB, or PFCB. The material of the first transparent conductive oxide layer 46 and the second transparent conductive oxide layer 440 can be Indium Tin Oxide (ITO), Aluminum Zinc Oxide (AZO), SnCdO, Antimony Tin Oxide (ATO), ZnO or Zn2SnO4 (ZTO), wherein characteristics such as the grain size and reflective index of the first transparent conductive oxide layer 46 are different from the grain size and reflective index of the second transparent conductive oxide layer 440. In this embodiment, the average grain size of the first transparent conductive oxide layer 46 is larger than the average grain size of the second transparent conductive oxide layer 440, and the refractive index of the first transparent conductive oxide layer 46 is smaller than the refractive index of the second transparent conductive oxide layer 440. In addition, the material of the metal reflective layer 442 can be high refractive index materials such as In, Sn, Al, Au, Pt, Zn, Ag, Ti, Pb, Ge, Cu, Ni, AuBe, AuGe, AuZn, or PbSn. The materials of the transparent dielectric barrier layer 50 can be SiO2, SiNx or Al2O3, and the thickness of the transparent dielectric barrier layer 50 is substantially between 5 nm to 300 nm.
In this embodiment, because the transparent dielectric barrier layer 50 is disposed between the first transparent conductive oxide layer 46 and the omni-directional reflector 44, the reaction between the first transparent conductive oxide layer 46 and the second transparent conductive oxide layer 440 at the high thermal environment during manufacturing process is avoided. Therefore, the brightness of the light emitting device 300 is raised.
Other embodiments of the application will be apparent to those having ordinary skills in the art from consideration of the specification and practice of the invention disclosed herein. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the invention being indicated by the following claims.

## Claims

1. A light emitting device, comprising:
a light-emitting stack layer;
a first transparent conductive oxide layer connecting with the light-emitting stack layer and forming ohmic contact in between;
a transparent dielectric barrier layer connecting with the first transparent conductive oxide layer;
a second transparent conductive oxide layer connecting with the transparent dielectric barrier layer; and
a metal reflective layer connecting with the second transparent conductive oxide layer, wherein an omni-directional reflector comprises the second transparent conductive oxide layer and the metal reflective layer,
wherein the first transparent conductive oxide layer has a first refractive index, the second transparent conductive oxide layer has a second refractive index, and the first refractive index is different from the second refractive index.

2. The light-emitting device according to the claim 1, further comprising a substrate connecting with the omni-directional reflector layer.

3. The light-emitting device according to the claim 2, further comprising an adhesive layer, disposed between the substrate and the omni-directional reflector layer.

4. The light-emitting device according to the claim 3, wherein the material of the adhesive layer comprises In, Sn, Au, Al, Ag, alloys thereof, PI, BCB and PFCB.

5. The light-emitting device according to the claim 2, wherein the material of the substrate comprises semiconductor, ceramic, or metal.

6. The light-emitting device according to the claim 5, wherein the semiconductor is selected from the group consisting of Si and GaAs.

7. The light-emitting device according to the claim 5, wherein the ceramic is selected from the group consisting of ZnO, AlN, SiC and AlO.

8. The light-emitting device according to the claim 5, wherein the metal is selected from the group consisting of copper, aluminum, molybdenum, and combination thereof.

9. The light-emitting device according to the claim 1, wherein the transparent dielectric barrier layer has a through region comprising one or more than one through holes, and wherein the first transparent conductive oxide layer fills into the one or more than one through holes and electrically connects with the second transparent conductive oxide layer.

10. The light-emitting device according to the claim 9, the area of the through region is less than 40 percent of the area of the transparent dielectric barrier layer.

11. The light-emitting device according to the claim 1, wherein the first transparent conductive oxide layer has a first average grain size, the second transparent conductive oxide layer has a second average grain size, and the first average grain size is different from the second average grain size.

12. The light-emitting device according to the claim 1, wherein the material of first transparent conductive oxide layer and the material of the second transparent conductive oxide layer comprise one or more than one material selected from the group consisting of ITO, AZO, SnCdO, ATO, ZnO, ZTO and combination thereof.

13. The light-emitting device according to the claim 1, wherein the material of the transparent dielectric barrier layer comprises SiO2, SiNx, Al2O3 or combination thereof.

14. The light-emitting device according to the claim 1, wherein the thickness of the transparent dielectric barrier layer is between 5 nm to 300 nm.

15. The light-emitting device according to the claim 1, wherein the material of the metal reflective layer is high reflective material or alloy thereof.

16. The light-emitting device according to the claim 15, wherein the material of the metal reflective layer is selected from the group consisting of In, Sn, Al, Au, Pt, Zn, Ag, Ti, Pb, Ge, Cu, and Ni, and the material of the alloy is selected from the group consisting of AuBe, AuGe, AuZn, and PbSn.

17. The light-emitting device according to the claim 1, wherein the light-emitting stack layer is semiconductor material comprising elements selected from the group consisting of Al, Ga, In, P, As, and N.