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Texas Registered Engineering Firm F-2393

Tables 

December 16, 2009 

Project No. 0102974 

Environmental Resources Management Southwest, Inc. 

15810 Park Ten Place, Suite 300 

Houston, Texas 77084-5140 

(281) 600-1000
TABLE 1

Constituents of Concern and Analytical Methods

F039 Waste Delisting

ExxonMobil Baytown Refinery

Baytown, Texas

Metals SW 846 Method

Mercury SW 7471A

Antimony SW 7471A

Arsenic SW 7471A

Barium SW 7471A

Beryllium SW 7471A

Cadmium SW 7471A

Chromium SW 7471A

Lead SW 7471A

Nickel SW 7471A

Selenium SW 7471A

Silver SW 7471A

Thallium SW 7471A

Vanadium SW 7471A

VOCs

1,1,1,2-Tetrachloroethane SW 8260

1,1,1-Trichloroethane SW 8260

1,1,2,2-Tetrachloroethane SW 8260

1,1,2-Trichloroethane SW 8260

1,1-Dichloroethane SW 8260

1,1-Dichloroethylene SW 8260

1,2,3-Trichloropropane SW 8260

1,2-Dibromoethane SW 8260

1,2-Dichloroethane SW 8260

1,2-Dichloropropane SW 8260

1,4-Dioxane SW 8260

Acetone SW 8260

Acetonitrile SW 8260

Acrolein SW 8260

Acrylonitrile SW 8260

Benzene SW 8260

Bromodichloromethane SW 8260

Bromoform SW 8260

Carbon disulfide SW 8260

Carbon tetrachloride SW 8260

Chlorobenzene SW 8260

Chlorodibrmomethane (Dibromochloromethane) SW 8260

Chloroethane SW 8260

Chloroform SW 8260

cis-1,3-Dichloropropene SW 8260

Dibromomethane (Methylene bromide) SW 8260

Dichlorodifluoromethane SW 8260

Ethyl methacrylate SW 8260

Ethylbenzene SW 8260

Iodomethane (Methyl iodide) SW 8260

Isobutyl alcohol SW 8260

Methyl methacrylate SW 8260

Methylene chloride SW 8260

Pentachlorobenzene SW 8260

Tetrachloroethylene SW 8260

trans-1,2-Dichloroethylene SW 8260

trans-1,3-Dichloropropene SW 8260

Trichloroethylene SW 8260

Trichloromonofluoromethane SW 8260

Vinyl chloride SW 8260

Xylene SW 8260

1,2-Dibromo-3-chloropropane SW 8260

Ethylene oxide SW 8260

Page 1 of 4

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TABLE 1 (Cont'd)

Constituents of Concern and Analytical Methods

F039 Waste Delisting

ExxonMobil Baytown Refinery

Baytown, Texas

VOCs continued SW 846 Method

Methacrylonitrile SW 8260

Methanol SW 8260

Methyl bromide SW 8260

Methyl ethyl ketone SW 8260

Methyl isobutyl ketone (4-Methyl-2-pentanone) SW 8260

Toluene SW 8260

2-Chloro-1.3-butadiene (Chloroprene) SW 8260

Cyclohexanone SW 8260

3-Chloropropylene (Allyl chloride) SW 8260

Ethyl acetate SW 8260

Ethyl cyanide (Propanenitrile) SW 8260

Ethyl ether SW 8260

m-Dichlorobenzene SW 8260

o-Dichlorobenzene SW 8260

p-Dichlorobenzene SW 8260

Methyl chloride SW 8260

n-butyl alcohol SW 8260

SVOCs SW 846 Method

1,2,4,5-Tetrachlorobenzene SW 8260

1,2,4-Trichlorobenzene SW 8260

1,2-Diphenylhydrazine SW 8260

2,3,4,6-Tetrachlorophenol SW 8260

2,4,5-Trichlorophenol SW 8260

2,4,6-Trichlorophenol SW 8260

2,4-Dichlorophenol SW 8260

2,4-Dimethylphenol SW 8260

2,4-Dinitrophenol SW 8260

2,4-Dinitrotoluene SW 8260

2,6-Dichlorophenol SW 8260

2,6-Dinitrotoluene SW 8260

2-Acetylaminofluorene SW 8260

2-Chloronaphthalene SW 8260

2-Chlorophenol SW 8260

2-Naphthylamine SW 8260

3-Methylcholanthrene SW 8260

4-Aminobiphenyl SW 8260

4-Bromophenyl phenyl ether SW 8260

5-Nitro-o-toluidine SW 8260

Acenaphthene SW 8260

Acenaphthylene SW 8260

Acetophenone SW 8260

Aniline SW 8260

Anthracene SW 8260

Benzo(a)anthracene SW 8260

Benzo(a)pyrene SW 8260

Benzo(b)fluoranthene SW 8260

Benzo(ghi)perylene SW 8260

Benzo(k)fluoranthene SW 8260

Bis(2-chloroethoxy)methane SW 8260

Bis(2-chloroethyl)ether SW 8260

Bis(2-cloroisopropyl)ether SW 8260

Bis(2-ethylhexyl)phthalate SW 8260

Butyl benzyl phthalate SW 8260

Chlorobenzilate SW 8260

Chrysene SW 8260

Di-n-butyl phthalate SW 8260

Di-n-octyl phthalate SW 8260

Dibenz(a,h)anthracene SW 8260

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TABLE 1 (Cont'd)

Constituents of Concern and Analytical Methods

F039 Waste Delisting

ExxonMobil Baytown Refinery

Baytown, Texas

SVOCs continued SW 846 Method

Diethyl phthalate SW 8260

Dimethyl phthalate SW 8260

Diphenylamine SW 8260

Fluoranthene SW 8260

Fluorene SW 8260

Hexachlorobenzene SW 8260

Hexachlorobutadiene SW 8260

Hexachlorocyclopentadiene SW 8260

Hexachloroethane SW 8260

Hexachloropropene SW 8260

Indeno(1,2,3-cd)pyrene SW 8260

Isodrin SW 8260

Isosafrole SW 8260

Kepone SW 8260

Methapyrilene SW 8260

Methyl methanesulfonate SW 8260

Naphthalene SW 8260

Nitrobenzene SW 8260

N-Nitrosodi-n-butylamine SW 8260

N-Nitrosomethylethalamine SW 8260

N-Nitrosomorpholine SW 8260

N-Nitrosopiperidine SW 8260

N-Nitrosopyrrolidine SW 8260

Pentachloronitrobenzene SW 8260

Pentachlorophenol SW 8260

Phenacetin SW 8260

Phenanthrene SW 8260

Phenol SW 8260

Pronamide SW 8260

Pyrene SW 8260

Pyridine SW 8260

Safrole SW 8260

1,1,2-Trichloro-1,2,2-trifluoroethane SW 8260

1,3-Phenylenediamine SW 8260

1,4-Dinitrobenzene SW 8260

2-sec-Butyl-4,6-dinitrophenol (Dinoseb) SW 8260

4,4-methylene bis (2-chloroaniline) SW 8260

Aramite SW 8260

Chlorobenzilate SW 8260

Dieldrin SW 8260

Disulfoton SW 8260

Famphur SW 8260

m-Cresol SW 8260

methyl parathion SW 8260

o-Anisidine (2-methoxyaniline) SW 8260

o-Cresol SW 8260

Parathion SW 8260

p-cresidine SW 8260

p-Cresol SW 8260

4,6-Dinitro-o-cresol SW 8260

p-Nitroaniline SW 8260

p-Nitrophenol SW 8260

Di-n-propylnitrosamine (N-Nitrosodipropylamine) SW 8260

Diphenylnitrosamine (N-Nitrosodiphenylamine) SW 8260

Dibenz(a,e)pyrene SW 8260

p-Chloroaniline SW 8260

p-Chloro-m-cresol SW 8260

Phorate SW 8260

Page 3 of 4

Texas Registered Engineering Firm F-2393 G:\2010\0102974\15096H(Att2)tb.xls
Constituents of Concern and Analytical Methods

F039 Waste Delisting

ExxonMobil Baytown Refinery

Baytown, Texas

Organochlorine Pesticides SW 846 Method

4,4'-DDD SW 8081

4,4'-DDE SW 8081

4,4'-DDT SW 8081

Aldrin SW 8081

alpha-BHC SW 8081

beta-BHC SW 8081

Chlordane SW 8081

delta-BHC SW 8081

Dieldrin SW 8081

Endosulfan I SW 8081

Endosulfan II SW 8081

Endosulfan sulfate SW 8081

Endrin SW 8081

Endrin aldehyde SW 8081

Organochlorine Pesticides SW 846 Method

gamma-BHC SW 8081

Heptachlor SW 8081

Heptachlor epoxide SW 8081

Methoxychlor SW 8081

Toxaphene SW 8081

o,p'-DDD SW 8081

o,p'-DDE SW 8081

o,p'-DDT SW 8081

Chlorinated Herbicides SW 846 Method

2,4,5-T (Trichlorophenoxyacetic acid) SW 8151

Silvex SW 8151

Dioxins/Furans SW 846 Method

1,2,3,4,6,7,8,9-Octachlorodibenzofuran 8290

1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin 8290

1,2,3,4,6,7,8-Heptachlorodibenzofuran 8290

1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 8290

1,2,3,4,7,8,9-Heptachlorodibenzofuran 8290

Hexachlorodibenzofurans 8290

Hexachlorodibenzo-p-dioxins 8290

Pentachlorodibenzofurans 8290

Pentachlorodibenzo-p-dioxins 8290

Tetrachlorodibenzofurans 8290

Tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) 8290

Polychlorinated dibenzofurans 8290

Polychlorinated dibenzo-p-dioxins 8290

Cyanide SW 846 Method

Cyanide (Total) (Amenable) 335.4C

Fluoride SW 846 Method

Fluoride 4500 FC

Sulfide SW 846 Method

Sulfide 4500 SE

PCB SW 846 Method

Polychlorinated biphenyls 8082

TABLE 1 (Cont'd)

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Texas Registered Engineering Firm F-2393

Figures 

December 16, 2009 

Project No. 0102974 

Environmental Resources Management Southwest, Inc. 

15810 Park Ten Place, Suite 300 

Houston, Texas 77084-5140 

(281) 600-1000
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Texas Registered Engineering Firm F-2393

Analytical Laboratory Quality Assurance Plan 

(ALS Laboratory Group) 

Appendix A 

December 16, 2009 

Project No. 0102974 

Environmental Resources Management Southwest, Inc. 

15810 Park Ten Place, Suite 300 

Houston, Texas 77084-5140 

(281) 600-1000
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HS-QA Plan, Rev 08.0, Appendix A

Effective: 09/01/2009 

Page A1 of 10__________

© 2009 ALS Laboratory Group All rights reserved.

APPENDIX A - DEFINITIONS FOR QUALITY SYSTEMS FROM NELAC 

The following selected definitions are from published texts in the 2003 NELAC Standard, June 5, 2003. 

Acceptance Criteria: specified limits placed on characteristics of an item, process, or service defined in 

requirement documents. (ASQC) 

Accuracy: the degree of agreement between an observed value and an accepted reference value. Accuracy 

includes a combination of random error (precision) and systematic error (bias) components which are due to 

sampling and analytical operations; a data quality indicator. (QAMS) 

Analyst: the designated individual who performs the "hands-on" analytical methods and associated techniques 

and who is the one responsible for applying required laboratory practices and other pertinent quality controls to 

meet the required level of quality. (NELAC) 

Assessment: the evaluation process used to measure or establish the performance, effectiveness, and conformance 

of an organization and/or its systems to defined criteria (to the standards and requirements of NELAC). (NELAC) 

Assessment Criteria: the measures established by NELAC and applied in establishing the extent to which an 

applicant is in conformance with NELAC requirements. (NELAC) 

Assessment Team: the group of people authorized to perform the on-site inspection and proficiency testing data 

evaluation required to establish whether an applicant meets the criteria for NELAP accreditation. (NELAC) 

Assessor: one who performs on-site assessments of accrediting authorities and laboratories’ capability and 

capacity for meeting NELAC requirements by examining the records and other physical evidence for each one of 

the tests for which accreditation has been requested. (NELAC) 

Audit: a systematic evaluation to determine the conformance to quantitative and qualitative specifications of 

some operational function or activity. (EPA-QAD) 

Batch: environmental samples that are prepared and/or analyzed together with the same process and personnel, 

using the same lot(s) of reagents. A preparation batch is composed of one to 20 environmental samples of the 

same NELAC-defined matrix, meeting the above mentioned criteria and with a maximum time between the start 

of processing of the first and last sample in the batch to be 24 hours. An analytical batch is composed of 

prepared environmental samples (extracts, digestates or concentrates) which are analyzed together as a group. An 

analytical batch can include prepared samples originating from various environmental matrices and can exceed 20 

samples. (NELAC Quality Systems Committee) 

Blank: a sample that has not been exposed to the analyzed sample stream in order to monitor contamination 

during sampling, transport, storage or analysis. The blank is subjected to the usual analytical and measurement 

process to establish a zero baseline or background value and is sometimes used to adjust or correct routine 

analytical results. Blanks include: 

• Equipment Blank: a sample of analyte-free media which has been used to rinse common sampling equipment 

to check effectiveness of decontamination procedures. (NELAC) 

• Field Blank: blank prepared in the field by filling a clean container with pure de-ionized water and 

appropriate preservative, if any, for the specific sampling activity being undertaken. (EPA OSWER) 

• Instrument Blank: a clean sample (e.g., distilled water) processed through the instrumental steps of the 

measurement process; used to determine instrument contamination. (EPA-QAD) 

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© 2009 ALS Laboratory Group All rights reserved.

• Method Blank: a sample of a matrix similar to the batch of associated samples (when available) that is free 

from the analytes of interest and is processed simultaneously with and under the same conditions as samples 

through all steps of the analytical procedures, and in which no target analytes or interferences are present at 

concentrations that impact the analytical results for sample analyses. (NELAC) 

• Reagent Blank: (method reagent blank): a sample consisting of reagent(s), without the target analyte or 

sample matrix, introduced into the analytical procedure at the appropriate point and carried through all 

subsequent steps to determine the contribution of the reagents and of the involved analytical steps. (QAMS) 

Blind Sample: a sub-sample for analysis with a composition known to the submitter. The analyst/laboratory may 

know the identity of the sample but not its composition. It is used to test the analyst’s or laboratory’s proficiency 

in the execution of the measurement process. (NELAC) 

Calibration: set of operations that establish, under specified conditions, the relationship between values of 

quantities indicated by a measuring instrument or measuring system, or values represented by a material measure 

or a reference material, and the corresponding values realized by standards (VIM:6.11) 

 In calibration of support equipment, the values realized by standards are established through the use of 

Reference Standards that are traceable to the International System of Units (SI). 

 In calibration according to test methods, the values realized by standards are typically established through the 

use of Reference Materials that are either purchased by the laboratory with a certificate of analysis or purity, 

or prepared by the laboratory using support equipment that has be calibrated or verified to meet specifications. 

Calibration Curve: the graphical relationship between the known values, such as concentrations, of a series of 

calibration standards and their instrument response. (NELAC) 

Calibration Method: a defined technical procedure for performing a calibration. (NELAC) 

Calibration Standard: a substance or reference material used to calibrate an instrument. (QAMS) 

Certified Reference Material (CRM): a reference material one or more of whose property values are certified 

by a technically valid procedure, accompanied by or traceable to a certificate or other documentation which is 

issued by a certifying body. (ISO Guide 30 - 2.2) 

Chain of Custody Form: record that documents the possession of the samples from the time of collection to 

receipt in the laboratory. This record generally includes: the number and types of containers; the mode of 

collection; collector; time of collection; preservation; and requested analyses. 

(NELAC) 

Confidential Business Information (CBI): information that an organization designates as having the potential of 

providing a competitor with inappropriate insight into its management, operation or products. NELAC and its 

representatives agree to safeguard identified CBI and to maintain all information identified as such in full 

confidentiality. 

Confirmation: verification of the identity of a component through the use of an approach with a different 

scientific principle from the original method. These may include, but are not limited to: 

• Second column confirmation, 

• Alternate wavelength, 

• Derivatization, 

• Mass spectral interpretation 

• Alternative detectors or 

• Additional cleanup procedures. (NELAC) 

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© 2009 ALS Laboratory Group All rights reserved.

Conformance: an affirmative indication or judgment that a product or service has met the requirements of the 

relevant specifications, contract, or regulation; also the state of meeting the requirements. (ANSI/ASQC E4-1994) 

Corrective Action: the action taken to eliminate the causes of an existing nonconformity, defect or other 

undesirable situation in order to prevent recurrence. (ISO 8402) 

Critical Finding: a finding or combination of findings that results in a significant negative effect on data quality 

or defensibility, if not corrected. (NELAC) 

Data Audit: a qualitative and quantitative evaluation of the documentation and procedures associated with 

environmental measurements to verify that the resulting data are of acceptable quality (i.e., that they meet 

specified acceptance criteria). (NELAC) 

Data Reduction: the process of transforming raw data by arithmetic or statistical calculations, standard curves, 

concentration factors, etc., and collation into a more useable form. (EPA-QAD) 

Deficiency: See Finding and Critical Finding. 

Delegate: any environmental official of the States or the Federal government not sitting in the House of 

Representatives, who is eligible to vote in the House of Delegates. (NELAC) 

Demonstration of Capability: a procedure to establish the ability of the analyst to generate acceptable accuracy. 

(NELAC) 

Denial: to refuse to accredit in total or in part a laboratory applying for initial accreditation or resubmission of 

initial application. (NELAC) 

 

Detection Limit: the lowest concentration or amount of the target analyte that can be identified, measured, and 

reported with confidence that the analyte concentration is not a false positive value. See Method Detection Limit. 

(NELAC) 

Document Control: the act of ensuring that documents (and revisions thereto) are proposed, reviewed for 

accuracy, approved for release by authorized personnel, distributed properly and controlled to ensure use of the 

correct version at the location where the prescribed activity is performed. (ASQC) 

Federal Water Pollution Control Act (Clean Water Act, CWA): the enabling legislation under 33 U.S.C. 1251 

et seq., Public Law 92-50086 Stat. 816, that empowers EPA to set discharge limitations, write discharge permits, 

monitor, and bring enforcement action for non-compliance. (NELAC) 

Field Measurement: The determination of physical, biological, or radiological properties, or chemical 

constituents; that are measured on-site, close in time and space to the matrices being sampled/measured, following 

accepted test methods. This testing is performed in the field outside of a fixed-laboratory or outside of an 

enclosed structure that meets the requirements of a mobile laboratory 

Field of Accreditation: (previously Field of Testing) NELAC’s approach to accrediting laboratories by matrix, 

technology/method and analyte/analyte group. Laboratories requesting accreditation for a matrixtechnology/method-analyte/analyte group combination or for an updated/improved method are required to submit 

only that portion of the accreditation process not previously addressed (see NELAC, section 1.8 ff). (NELAC) 

Field of Proficiency Testing: NELAC’s approach to offering proficiency testing by matrix, technology, and 

analyte/analyte group. 

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Finding: an assessment conclusion, referenced to a NELAC Standard and supported by objective evidence, that 

identifies a deviation from a NELAC requirement. See Critical Finding. 

Holding Times (Maximum Allowable Holding Times): the maximum times that samples may be held prior to 

analysis and still be considered valid or not compromised. (40 CFR Part 136) 

Inspection: an activity such as measuring, examining, testing, or gauging one or more characteristics of an entity 

and comparing the results with specified requirements in order to establish whether conformance is achieved for 

each characteristic. (ANSI/ASQC E4-1994) 

Interim Accreditation: temporary accreditation status for a laboratory that has met all accreditation criteria 

except for a pending on-site assessment which has been delayed for reasons beyond the control of the laboratory. 

(NELAC) 

Internal Standard: a known amount of standard added to a test portion of a sample as a reference for evaluating 

and controlling the precision and bias of the applied analytical method. (NELAC) 

International System of Units (SI): the coherent system of units adopted and recommended by the General 

Conference on Weights and Measures. (CCGPM) (VIM 1.12) 

Laboratory: a body that calibrates and/or tests. (ISO 25) 

Laboratory Control Sample (however named, such as laboratory fortified blank, spiked blank, or QC 

check sample): a sample matrix, free from the analytes of interest, spiked with verified known amounts of 

analytes or a material containing known and verified amounts of analytes. It is generally used to establish intralaboratory or analyst specific precision and bias or to assess the performance of all or a portion of the 

measurement system. (NELAC) 

Laboratory Duplicate: aliquots of a sample taken from the same container under laboratory conditions and 

processed and analyzed independently. (NELAC) 

Legal Chain of Custody Protocols: procedures employed to record the possession of samples from the time of 

sampling until analysis and are performed at the special request of the client. These protocols include the use of a 

Chain of Custody Form that documents the collection, transport, and receipt of compliance samples by the 

laboratory. In addition, these protocols document all handling of the samples within the laboratory. 

(NELAC) 

Limit of Detection (LOD): an estimate of the minimum amount of a substance that an analytical process can 

reliably detect. An LOD is analyte- and matrix-specific and may be laboratory-dependent. 

Limit of Quantitation (LOQ): The minimum levels, concentrations, or quantities of a target variable (e.g., target 

analyte) that can be reported with a specified degree of confidence 

Manager (however named): the individual designated as being responsible for the overall operation, all 

personnel, and the physical plant of the environmental laboratory. A supervisor may report to the manager. In 

some cases, the supervisor and the manager may be the same individual. (NELAC) 

Matrix: the substrate of a test sample. 

Field of Accreditation Matrix: these matrix definitions shall be used when accrediting a laboratory (see Field of 

Accreditation). 

• Drinking Water: any aqueous sample that has been designated a potable or potential potable water source. 

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• Non-Potable Water: any aqueous sample excluded from the definition of Drinking Water. Includes surface 

water, ground water, effluents, water treatment chemicals, and TCLP or other extracts. 

• Solid and Chemical Materials: includes soils, sediments, sludges, products and by-products of an industrial 

process that results in a matrix not previously defined. 

• Biological Tissue: any sample of a biological origin such as fish tissue, shellfish, or plant material. Such 

samples shall be grouped according to origin. 

• Air and Emissions: whole gas or vapor samples including those contained in flexible or rigid wall containers 

and the extracted concentrated analytes of interest from a gas or vapor that are collected with a sorbent tube, 

impinger solution, filter, or other device. (NELAC) 

Quality System Matrix: These matrix definitions are an expansion of the field of accreditation matrices and shall 

be used for purposes of batch and quality control requirements (see Appendix D of Chapter 5). These matrix 

distinctions shall be used: 

• Aqueous: any aqueous sample excluded from the definition of Drinking Water matrix or Saline/Estuarine 

source. Includes surface water, groundwater, effluents, and TCLP or other extracts. 

• Drinking Water: any aqueous sample that has been designated a potable or potential potable water source. 

• Saline/Estuarine: any aqueous sample from an ocean or estuary, or other salt water source such as the Great 

Salt Lake. 

• Non-aqueous Liquid: any organic liquid with <15% settleable solids. 

• Biological Tissue: any sample of a biological origin such as fish tissue, shellfish, or plant material. Such 

samples shall be grouped according to origin. 

• Solids: includes soils, sediments, sludges and other matrices with >15% settleable solids. 

• Chemical Waste: a product or by-product of an industrial process that results in a matrix not previously 

defined. 

• Air and Emissions: whole gas or vapor samples including those contained in flexible or rigid wall containers 

and the extracted concentrated analytes of interest from a gas or vapor that are collected with a sorbent tube, 

impinger solution, filter, or other device. (NELAC) 

Matrix Spike (spiked sample or fortified sample): a sample prepared by adding a known mass of target analyte 

to a specified amount of matrix sample for which an independent estimate of Target analyte concentration is 

available. Matrix spikes are used, for example, to determine the effect of the matrix on a method's recovery 

efficiency. (QAMS) 

Matrix Spike Duplicate (spiked sample or fortified sample duplicate): a second replicate matrix spike 

prepared in the laboratory and analyzed to obtain a measure of the precision of the recovery for each analyte. 

(QAMS) 

May: denotes permitted action, but not required action. (NELAC) 

Measurement System: a test method, as implemented at a particular laboratory, and which includes the 

equipment used to perform the test and the operator(s). 

Method Detection Limit: the minimum concentration of a substance (an analyte) that can be measured and 

reported with 99% confidence that the analyte concentration is greater than zero and is determined from analysis 

of a sample in a given matrix containing the analyte. (40 CFR Part 136, Appendix B) 

Must: denotes a requirement that must be met. (Random House College Dictionary) 

National Accreditation Database: the publicly accessible database listing the accreditation status of all 

laboratories participating in NELAP. (NELAC) 

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National Institute of Standards and Technology (NIST): an agency of the US Department of Commerce’s 

Technology Administration that is working with EPA, States, NELAC, and other public and commercial entities 

to establish a system under which private sector companies and interested States can be accredited by NIST to 

provide NIST-traceable proficiency testing (PT) to those laboratories testing drinking water and wastewater. 

National Environmental Laboratory Accreditation Conference (NELAC): a voluntary organization of State 

and Federal environmental officials and interest groups purposed primarily to establish mutually acceptable 

standards for accrediting environmental laboratories. A subset of NELAP. (NELAC) 

National Environmental Laboratory Accreditation Program (NELAP): the overall National 

Environmental Laboratory Accreditation Program of which NELAC is a part. (NELAC) 

National Voluntary Laboratory Accreditation Program (NVLAP): a program administered by NIST that is 

used by providers of proficiency testing to gain accreditation for all compounds/matrices for which NVLAP 

accreditation is available, and for which the provider intends to provide NELAP PT samples. (NELAC) 

Negative Control: measures taken to ensure that a test, its components, or the environment do not cause 

undesired effects, or produce incorrect test results. (NELAC) 

NELAC Standards: the plan of procedures for consistently evaluating and documenting the ability of 

laboratories performing environmental measurements to meet nationally defined standards established by the 

National Environmental Laboratory Accreditation Conference. (NELAC) 

NELAP Recognition: the determination by the NELAP Director that an accrediting authority meets the 

requirements of the NELAP and is authorized to grant NELAP accreditation to laboratories. (NELAC) 

Non-governmental Laboratory: any laboratory not meeting the definition of the governmental laboratory. 

(NELAC) 

Performance Audit: the routine comparison of independently obtained qualitative and quantitative measurement 

system data with routinely obtained data in order to evaluate the proficiency of an analyst or laboratory. (NELAC) 

Positive Control: measures taken to ensure that a test and/or its components are working properly and producing 

correct or expected results from positive test subjects. (NELAC) 

Precision: the degree to which a set of observations or measurements of the same property, obtained under 

similar conditions, conform to themselves; a data quality indicator. Precision is usually expressed as standard 

deviation, variance or range, in either absolute or relative terms. (NELAC) 

Preservation: refrigeration and/or reagents added at the time of sample collection (or later) to maintain the 

chemical and/or biological integrity of the sample. (NELAC) 

Primary Accrediting Authority: the agency or department designated at the Territory, State or Federal level as 

the recognized authority with responsibility and accountability for granting NELAC accreditation for a specified 

field of testing. (NELAC) 

Procedure: Specified way to carry out an activity or a process. Procedures can be documented or not. (ISO 9000: 

2000 and Note1) 

Proficiency Testing: a means of evaluating a laboratory’s performance under controlled conditions relative to a 

given set of criteria through analysis of unknown samples provided by an external source. (NELAC) 

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Proficiency Testing Oversight Body/Proficiency Testing Provider Accreditor (PTOB/PTPA): an 

organization with technical expertise, administrative capacity and financial resources sufficient to implement and 

operate a national program of PT provider evaluation and oversight that meets the responsibilities and 

requirements established by NELAC standards. (NELAC) 

Proficiency Testing Program: the aggregate of providing rigorously controlled and standardized environmental 

samples to a laboratory for analysis, reporting of results, statistical evaluation of the results and the collective 

demographics and results summary of all participating laboratories. (NELAC) 

Proficiency Testing Study Provider: any person, private party, or government entity that meets stringent criteria 

to produce and distribute NELAC PT samples, evaluate study results against published performance criteria and 

report the results to the laboratories, primary accrediting authorities, PTOB/PTPA, and NELAP. (NELAC) 

Proficiency Test Sample (PT): a sample, the composition of which is unknown to the analyst and is provided to 

test whether the analyst/laboratory can produce analytical results within specified acceptance criteria. (QAMS) 

Protocol: a detailed written procedure for field and/or laboratory operation (e.g., sampling, analysis) which must 

be strictly followed. (EPA-QAD) 

Quality Assurance: an integrated system of activities involving planning, quality control, quality assessment, 

reporting and quality improvement to ensure that a product or service meets defined standards of quality with a 

stated level of confidence. (QAMS) 

Quality Assurance [Project] Plan (QAPP): a formal document describing the detailed quality control 

procedures by which the quality requirements defined for the data and decisions pertaining to a specific project 

are to be achieved. (EPA-QAD) 

Quality Control: the overall system of technical activities whose purpose is to measure and control the quality of 

a product or service so that it meets the needs of users. (QAMS) 

Quality Control Sample: a sample used to assess the performance of all or a portion of the measurement system. 

QC samples may be Certified Reference Materials, a quality system matrix fortified by spiking, or actual samples 

fortified by spiking. 

Quality Manual: a document stating the management policies, objectives, principles, organizational structure and 

authority, responsibilities, accountability, and implementation of an agency, organization, or laboratory, to ensure 

the quality of its product and the utility of its product to its users. (NELAC) 

Quality System: a structured and documented management system describing the policies, objectives, principles, 

organizational authority, responsibilities, accountability, and implementation plan of an organization for ensuring 

quality in its work processes, products (items), and services. The quality system provides the framework for 

planning, implementing, and assessing work performed by the organization and for carrying out required QA and 

QC. (ANSI/ASQC E-41994) 

Raw Data: any original factual information from a measurement activity or study recorded in a laboratory 

notebook, worksheets, records, memoranda, notes, or exact copies thereof that are necessary for the reconstruction 

and evaluation of the report of the activity or study. Raw data may include photography, microfilm or microfiche 

copies, computer printouts, magnetic media, including dictated observations, and recorded data from automated 

instruments. If exact copies of raw data have been prepared (e.g., tapes which have been transcribed verbatim, 

data and verified accurate by signature), the exact copy or exact transcript may be submitted. (EPA-QAD) 

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Recognition: previously known as reciprocity. The mutual agreement of two or more parties (i.e., States) to 

accept each other’s findings regarding the ability of environmental testing laboratories to meet NELAC standards. 

(NELAC) 

Reference Material: a material or substance one or more properties of which are sufficiently well established to 

be used for the calibration of an apparatus, the assessment of a measurement method, or for assigning values to 

materials. (ISO Guide 30-2.1) 

Reference Standard: a standard, generally of the highest metrological quality available at a given location, from 

which measurements made at that location are derived. (VIM-6.08) 

Replicate Analyses: the measurements of the variable of interest performed identically on two or more subsamples of the same sample within a short time interval. (NELAC) 

Requirement: denotes a mandatory specification; often designated by the term “shall”. (NELAC) 

Resource Conservation and Recovery Act (RCRA): the enabling legislation under 42 USC 321 et seq. (1976), 

that gives EPA the authority to control hazardous waste from the “cradle-to-grave”, including its generation, 

transportation, treatment, storage, and disposal. (NELAC) 

Revocation: the total or partial withdrawal of a laboratory’s accreditation by the accrediting authority. (NELAC) 

Safe Drinking Water Act (SDWA): the enabling legislation, 42 USC 300f et seq. (1974), (Public Law 93-523), 

that requires the EPA to protect the quality of drinking water in the U.S. by setting maximum allowable 

contaminant levels, monitoring, and enforcing violations. (NELAC) 

Secondary Accrediting Authority: the Territorial, State or federal agency that grants NELAC accreditation to 

laboratories, based upon their accreditation by a NELAP-recognized Primary Accrediting Authority. See also 

Recognition and Primary Accrediting Authority. (NELAC)[1.5.2.3] 

Selectivity: (Analytical chemistry) the capability of a test method or instrument to respond to a target substance 

or constituent in the presence of non-target substances. (EPA-QAD) 

Sensitivity: the capability of a method or instrument to discriminate between measurement responses representing 

different levels (e.g., concentrations) of a variable of interest. (NELAC) 

Shall: denotes a requirement that is mandatory whenever the criterion for conformance with the specification 

requires that there be no deviation. This does not prohibit the use of alternative approaches or methods for 

implementing the specification so long as the requirement is fulfilled. (ANSI) 

Should: denotes a guideline or recommendation whenever noncompliance with the specification is permissible. 

(ANSI) 

Spike: a known mass of target analyte added to a blank sample or sub-sample; used to determine recovery 

efficiency or for other quality control purposes. (NELAC) 

Standard: the document describing the elements of laboratory accreditation that has been developed and 

established within the consensus principles of NELAC and meets the approval requirements of NELAC 

procedures and policies. (ASQC) 

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Standard Operating Procedures (SOPs): a written document which details the method of an operation, analysis 

or action whose techniques and procedures are thoroughly prescribed and which is accepted as the method for 

performing certain routine or repetitive tasks. (QAMS) 

Standard Method: a test method issued by an organization generally recognized as competent to do so. 

Standardized Reference Material (SRM): a certified reference material produced by the U.S. National Institute 

of Standards and Technology or other equivalent organization and characterized for absolute content, independent 

of analytical method. (EPA-QAD) 

Statistical Minimum Significant Difference (SMSD): the minimum difference between the control and a test 

concentration that is statistically significant; a measure of test sensitivity or power. The power of a test depends in 

part on the number of replicates per concentration, the significance level selected, e.g., 0.05, and the type of 

statistical analysis. If the variability remains constant, the sensitivity of the test increases as the number of 

replicates is increased. (NELAC) 

Supervisor (however named): the individual(s) designated as being responsible for a particular area or category 

of scientific analysis. This responsibility includes direct day-to-day supervision of technical employees, supply 

and instrument adequacy and upkeep, quality assurance/quality control duties and ascertaining that technical 

employees have the required balance of education, training and experience to perform the required analyses. 

(NELAC) 

Surrogate: a substance with properties that mimic the analyte of interest. It is unlikely to be found in 

environment samples and is added to them for quality control purposes. (QAMS) 

Suspension: temporary removal of a laboratory’s accreditation for a defined period of time, which shall not 

exceed six months, to allow the laboratory time to correct deficiencies or area of non-compliance with the 

NELAC standards. (NELAC) 

Technical Director: individual(s) who has overall responsibility for the technical operation of the environmental 

testing laboratory. (NELAC) 

Technology: a specific arrangement of analytical instruments, detection systems, and/or preparation techniques. 

Test: a technical operation that consists of the determination of one or more characteristics or performance of a 

given product, material, equipment, organism, physical phenomenon, process or service according to a specified 

procedure. The result of a test is normally recorded in a document sometimes called a test report or a test 

certificate. (ISO/IEC Guide 2-12.1, amended) 

Test Method: an adoption of a scientific technique for a specific measurement problem, as documented in a 

laboratory SOP or published by a recognized authority. (NELAC) 

Test Sensitivity/Power: the minimum significant difference (MSD) between the control and test concentration 

that is statistically significant. It is dependent on the number of replicates per concentration, the selected 

significance level, and the type of statistical analysis (see Chapter 5, Appendix D, section 2.4.a). (NELAC) 

Tolerance Chart: A chart in which the plotted quality control data is assessed via a tolerance level (e.g. ± 10% of 

a mean) based on the precision level judged acceptable to meet overall quality/data use requirements instead of 

statistical acceptance criteria (e.g. ± 3 sigma) (applies to radio bioassay laboratories). (ANSI) 

Traceability: the property of a result of a measurement whereby it can be related to appropriate standards, 

generally international or national standards, through an unbroken chain of comparisons. (VIM-6.12) 

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United States Environmental Protection Agency (EPA): the federal governmental agency with responsibility 

for protecting public health and safeguarding and improving the natural environment (i.e., the air, water, and land) 

upon which human life depends. (US-EPA) 

Validation: the confirmation by examination and provision of objective evidence that the particular requirements 

for a specific intended use are fulfilled. 

Verification: confirmation by examination and provision of evidence that specified requirements have been met. 

(NELAC) 

NOTE: In connection with the management of measuring equipment, verification provides a means for 

checking that the deviations between values indicated by a measuring instrument and corresponding 

known values of a measured quantity are consistently smaller than the maximum allowable error defined 

in a standard, regulation or specification peculiar to the management of the measuring equipment. 

The result of verification leads to a decision either to restore in service, to perform adjustment, to repair, 

to downgrade, or to declare obsolete. In all cases, it is required that a written trace of the verification 

performed shall be kept on the measuring instrument’s individual record. 

Work Cell: a well-defined group of analysts that together perform the method analysis. The members of the 

group and their specific functions within the work cell must be fully documented. 

(NELAC) 

Working Range: the difference between the Limit of Quantitation and the upper limit of measurement system 

calibration. 

Sources: 

40CFR Part 136 

American Society for Quality Control (ASQC), 

Definitions of Environmental Quality Assurance Terms, 1996 American National Standards Institute (ANSI), 

Style Manual for Preparation of Proposed American National Standards, Eighth Edition, March 1991 

ANSI/ASQC E4, 1994 

International Standards Organization (ISO) Guides 2, 30, 8402 

National Institute of Standards and Technology (NIST) 

National Environmental Laboratory Accreditation Conference (NELAC), July 1998 Standards 

Random House College Dictionary 

US EPA Quality Assurance Management Section (QAMS), Glossary of Terms of Quality Assurance 

Terms, 8/31/92 and 12/6/95 

US EPA Quality Assurance Division (QAD) 

Webster’s New World Dictionary of the American Language 

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APPENDIX B – Containers, Preservation and Holding Times 

Parameter Containers 1 Preservative Holding Time 2

Acidity / E305.1 P, G - 250 ml >0 to 6 ° C 14 days 

Alkalinity / SM 2320B – E310.1 P, G - 250 mL >0 to 6 ° C 14 days 

Ammonia as N P, G – 500 mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

Bacterial Tests (Coliform, Total, Fecal 

and E. Coli) 

PA, G – 250-ml Cool <10 ° C; 0.008% 

Na2S2O3 if Cl2 present 

6 hours 

Biological Oxygen Demand (BOD) P, G – 1000 mL >0 to 6 ° C 48 hours 

(Carbonaceous) Biological Oxygen 

Demand (CBOD) 

P, G – 1000 mL >0 to 6 ° C 48 hours 

Bromide P, G – 500 mL None required 28 days 

(Total Organic) Carbon (TOC) / SW 9060 P, G – 250 mL >0 to 6 °C; HNO3 or 

H2SO4 

to pH<2 

28 days 

Chemical Oxygen Demand (COD) P, G – 500 mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

Chloride P, G – 500 mL None required 28 days 

Color P, G – 500 mL >0 to 6 ° C 48 hours 

Conductivity (Spec. Conductance) P, G – 250 mL >0 to 6 ° C 28 days 

(Reactive) Cyanide P, G – 4 oz wm None required 14 days 

Cyanide (Total and Amenable to 

Chlorination) 

P, G - 1000 mL >0 to 6 ° C; NaOH to 

pH>12; 

0.6g ascorbic acid 

14 days 

Cyanide (Total or Reactive) / Soil P, G – 100 g in 250-ml 

wm bottle. 

>0 to 6 ° C 14 days 

Fluoride P – 250 mL None required 28 days 

Hardness P, G – 250 mL HNO3 or H2SO4 to pH<2 6 months 

Nitrate as N P, G – 250 mL >0 to 6 ° C 48 hours 

Nitrate-Nitrite as N P, G – 250 mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

Nitrite as N P, G – 250 mL >0 to 6 °

C 48 hours 

(Total Kjeldahl) Nitrogen P, G – 250 mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

Oil and Grease G – 1000 mL wm >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

pH (hydrogen ion) P, G – 250 mL >0 to 6 ° C analyze immediately 

(Total) Phenols (wet method) G / amber – 1000 mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

(ortho-) Phosphate P, G – 250 mL Filter immediately; 

 >0 to 6 ° C 

48 hours 

(Total) Phosphate P, G – 250 mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

Residue (Total Solids) P, G – 500 mL >0 to 6 ° C 7 days 

Residue (Dissolved Solids) (TDS) P, G – 500 mL >0 to 6 ° C 7 days 

Residue (Suspended Solids) (TSS) P, G – 500 mL >0 to 6 ° C 7 days 

Residue (Settleable) P, G – 1000 mL >0 to 6 ° C 48 hours 

Residue (Total Volatile) (TVS) P, G – 500 mL >0 to 6 ° C 7 days 

Residue (Volatile Suspended) (TVSS) P, G – 500 mL >0 to 6 ° C 7 days 

Silica P – 500 mL >0 to 6 ° C 28 days 

Chromium VI P, G – 250 mL >0 to 6 ° C 24 hours 

Chromium VI (soil) P, G – 4 oz wide mouth >0 to 6 ° C 24 hours 

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Parameter Containers 1 Preservative Holding Time 2

Mercury P, G – 500 mL HNO3 to pH<2 28 days 

Mercury (soil) P, G – 4 oz wm bottle None 28 days 

Metals (except Chromium IV and Hg) P, G – 1000 mL HNO3 to pH<2 6 months 

Metals (except CrVI and Hg)/ (soil) P, G – 50 g in 120 ml 

bottle 

None 6 months 

TCLP Mercury P, G – 1000 mL >0 to 6 ° C 28 days to extract; 28 days 

after extraction to analysis 

TCLP Metals (except Mercury) P, G – 1000 mL >0 to 6 ° C 180 days to extract; 180 days 

after extraction to analysis 

Dioxins (TCDD) G – 2 x 1L amber >0 to 6 ° C; 0.008% 

Na2S2O3 if Cl2 is 

present 

7 days to extract; 40 days after 

extraction to analysis 

Pesticides in Soil (Organochlorine) 8081B G, 4 oz wide mouth >0 to 6 °C 7 days to extract; 40 days 

after extraction to analysis 

Pesticides – water 

(Organochlorine)/8081B 

Amber G, 2 x 1L >0 to 6 °C; adjust pH to 

4-5 

7 days to extract; 40 days 

after extraction to analysis 

PCBs in Soil 

SW 8082A 

G, 4 oz wide mouth >0 to 6 ° C 7 days to extract; 40 days 

after extraction to analysis 

PCBs in water 

SW 8082A / EPA 608 

Amber G; 2 x 1L >0 to 6°C; adjust pH to 

4-5 

7 days to extract; 40 days 

after extraction to analysis 

(Total) Petroleum Hydrocarbons (TPH) 

Water – by TX 1005 

G – 2 x 40 mL 

with no headspace 

>0 to 6 °C; HCl to pH<2 14 days to extract; 14 days 

after extraction to analysis 

Polynuclear Aromatic Hydrocarbons 

(PAHs) / (soil) 

G, 4 oz wide mouth >0 to 6 ° C; store in the 

dark 

14 days to extract; 40 days 

after extraction to analysis 

Polynuclear Aromatic Hydrocarbons 

(PAHs) by 8270 (water) 

Amber G; 2 x 1L >0 to 6 ° C 7 days to extract; 40 days 

after extraction to analysis 

Semi-Volatiles (BNAs) in soil G, 4 oz wide mouth >0 to 6 ° C 7 days to extract; 40 days 

after extraction to analysis 

Semi-Volatiles (BNAs) Amber G, 2 x 1L >0 to 6 ° C 7 days to extract; 40 days 

after extraction to analysis 

Semi-Volatiles (TCLP) G, 4 oz wide mouth >0 to 6 ° C 14 days to TCLP extraction; 7 

days from TCLP extraction to 

BNA extraction; 40 days after 

BNA extraction to analysis 

Total Organic Halogens (TOX) / SW9020 Amber G, 250mL >0 to 6 ° C; H2SO4 to 

pH<2 

28 days 

Volatiles (water) 

SW 8260B 

G – 3 x 40 mL 

with no headspace 

>0 to 6 ° C; HCl to pH<2 14 days 

Volatiles (TCLP) G, 2 x 4 oz wide mouth >0 to 6 ° C 14 days to extract; 14 days 

after extraction to analysis 

Volatiles 

(low level soil by 5035A, where soil 

likely contain VOCs < 200 ppb) 

Collect sample using 

approved coring device 

(EnCore, etc) or field 

preserve 5 gram sample in 

pre-tared 40 ml VOA vial, 

containing 5ml of organic 

free water, 1g sodium 

bisulfate & stir bar 

>0 to 6 ° C; or freeze3

samples to –12 to -20 ° C 

as an alternative to 

preservation with sodium 

bisulfate as a means to 

inhibit biodegradation. 

48 hrs to transfer contents of 

core device to a 40 ml VOA 

vial , containing 5ml of 

organic free water, 1g sodium 

bisulfate & stir bar; analyze 

transferred sample 14 days 

from collection 

 

Volatiles 

(high level soil by 5035A, where soil may 

contain VOCs >200 ppb) 

Collect sample using 

approved coring device 

(EnCore, etc) or field 

preserve samples in pretared 60 ml glass bottles 

>0 to 6 ° C; or freeze3

samples to –12 to –20 °

C as an alternative to 

preservation with 

methanol as a means to 

 48 hrs to transfer contents of 

core device to a 40 ml VOA 

vial , containing 10 ml of 

purge and trap grade 

methanol; analyze methanol 

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Parameter Containers 1 Preservative Holding Time 2

with methanol inhibit biodegradation. preserved sample 14 days 

from collection 

Volatiles (Soil) G, 2 oz wide mouth >0 to 6 ° C 14 days 

Alpha, Beta, and Radium P, G – 1000 mL HNO3 to pH<2 6 months 

1

 (P) polyethylene/plastic; (G) Glass ; (PA) Autoclavable Plastic 

2

 Recommended Holding Times from 40CFR136 and/or USEPA SW-846. 

3 Option to freeze core soil must be approved by regulatory agency or QA Project Plan. 

 

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APPENDIX C – Houston Floor Plan and Laboratory Equipment 

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Table C.1 Calibration And Maintenance Schedule – Houston Facility 

Instrument Activity Frequency Documentation 

pH electrometers Calibration: 

1. pH buffer aliquot are used only 

once 

2. Buffers used for calibration 

will bracket the pH of the 

media, reagent, or sample 

tested. 

Before use Worksheet/log book 

pH probe / ISE probes Maintenance: 

Use manufacturer’s specifications 

As needed Worksheet/log book 

Spectrophotometer. 1. Keep cells clean 

2. Service contract. Check 

wavelength settings with color 

standards 

Annually Post service date on 

Unit 

Refrigerators, 

Freezers, and BOD 

incubators 

1. Thermometers are immersed in 

liquid to the appropriate 

immersion line 

2. The thermometers are graduated 

in increments of 1°C or less 

Temperatures are 

recorded each day in use 

Worksheet/log book 

DO electrometer Calibrate as specified in SOP Before use Worksheet/log book 

DO probe Maintenance as specify by 

manufacturer 

As needed Worksheet/log book 

CETAC Mercury 

Analyzer 

Check tubing for wear 

Fill rinse tank with 10% HCl 

Insert clean drying tube filled with 

Magnesium Perchlorate 

Fill reductant bottle with 10% 

Stannous Chloride 

Daily 

Daily 

Daily 

Daily 

Worksheet/log book 

UV-Vis 

Spectrophotometer 

Clean ambient flow cell 

Precision check/alignment of flow 

cell 

Wavelength verification check 

As required 

As required 

Semi-annually 

Worksheet/log book 

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Table C.1 Calibration And Maintenance Schedule – Houston Facility 

Instrument Activity Frequency Documentation 

ICP/MS Check pump tubing 

Check liquid argon supply 

Check fluid level in waste container 

Check filters 

Clean or replace filters 

Check torch 

Check sample spray chamber for 

debris 

Clean and align nebulizer 

Check entrance slit for debris 

Change printer ribbon 

Replace pump tubing 

Daily 

Daily 

Daily 

Weekly 

As required 

Daily 

Monthly 

Monthly 

Monthly 

As required 

As required 

Worksheet/log book 

GC/MS Systems Ion gauge tube degassing 

Pump oil-level check 

Diffusion Pump oil changing 

Analyzer bake-out 

Analyzer cleaning 

Resolution adjustment – Tune MSD 

Auto sampler maintenance 

Purge and Trap maintenance 

As required 

Monthly 

Annually 

As required 

As required 

As required 

As required 

As required 

Worksheet/log book 

Electron Capture 

Detector (ECD) 

Detector wipe test (Ni-63) 

Detector cleaning 

Semi-annually 

As required 

Worksheet/log book 

Gas Chromatograph Compare standard response to 

previous day or since last initial 

calibration 

Check carrier gas flow rate in 

column 

Check temp. of detector, inlet, 

Daily 

Daily via use of known 

RT 

Daily 

Worksheet/log book 

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Table C.1 Calibration And Maintenance Schedule – Houston Facility 

Instrument Activity Frequency Documentation 

Gas Chromatograph 

continued 

column oven 

Septum replacement 

Glass wool replacement 

Check system for gas leaks with 

SNOOP 

Check for loose/fray wires and 

insulation 

Bake injector/column 

Change/remove sections of guard 

column 

Replace connectors/liners 

Change/replace column(s) 

Autosampler Maintenance 

As required 

As required 

W/cylinder change as 

required 

Monthly 

As required 

As required 

As required 

As required 

As required 

Flame Ionization 

Detector (FID) 

Detector cleaning As required Worksheet/log book 

Photoionization 

Detector (PID) 

Change O-rings 

Clean lamp window 

As required 

As required 

Worksheet/log book 

HPLC / IC units Change guard columns 

Change lamps 

Change pump seals 

Replace tubing 

Change fuses in power supply 

Filter all samples and solvents 

Change autosampler rotor/stator 

As required 

As required 

Semi-annually or as 

required 

As required 

As required 

Daily 

As required 

Worksheet/log book 

TOC Analyzer Check Sample Delivery Tubing 

Check Gas and Reagent supplies 

Replace Catalyst 

Daily 

Daily 

As required 

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Table C.1 Calibration And Maintenance Schedule – Houston Facility 

Instrument Activity Frequency Documentation 

IR Detector cleaning As required 

Balances Class "S" traceable weight check 

Clean pan and check if level 

Field service 

Daily, when used 

Daily 

At least annually 

Conductivity Meter 0.01 M KCl calibration 

Conductivity cell cleaning 

Daily, when used 

As required 

Turbidimeter Check light bulb Daily, when used 

Deionized/ 

Water 

Check resistance 

Check deionizer light 

Monitor for VOA's 

Replace cartridge & large mixed bed 

resins 

Daily 

Daily 

Daily 

As required 

Drying Ovens Temperature monitoring 

Temperature adjustments 

Daily 

As required 

Refrigerators/ 

Freezers 

Temperature monitoring 

Temperature adjustment 

Defrosting/cleaning 

Daily 

As required 

As required 

pH/Specific Ion 

Meter 

Calibration/check slope 

Clean electrode 

Daily 

As required 

BOD Incubator Temperature monitoring 

Coil and incubator cleaning 

Daily 

Monthly 

Table C.3 – Houston Lab 

Item Description 

Manufacturer/Model Condition / Year Installed Approx. 

Age-Years

GC with FID (FID #2) HP 5890A, HP7673 Injector Used / good – 11/1999 9 

GC with FID/FPD (FID #1) HP 5890A, HP7673A Injector Used / good – 11/1999 8 

GC with FID (FID#3) HP 5890A Series II, HP7673A Injector Used / good – 09/2000 8.5 

GC with FID (FID #4) / with 

Headspace Analyzer 

HP 5890A Series II / HTA HT280T 

Headspace Autosampler 

 Used / good – 02/2001 / 

Headspace – new - 2007 

7 / 2 

GC with FID, Dual Thu-put 

(FID#7 / #8) 

Agilent 6890N, Dual Column/FID New / Excellent – 02/2006 2.5 

18 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page C6 of 7 ____________

© 2009 ALS Laboratory Group - All Rights Reserved 

Table C.3 – Houston Lab 

Item Description 

Manufacturer/Model Condition / Year Installed Approx. 

Age-Years

GC with FID, Dual Thu-put 

(FID#10 / #11) 

Agilent 6890N, Dual Column/FID New / Excellent – 02/2006 2.5 

GC with FID (FID#6- GRO) HP 5890 Series II, Used/ good – 09/2000 8.5 

Purge & Trap Conc, for GRO OI 4560 (for FID #6) Used/ good – 09/2000 8.5 

Purge & Trap Concentrator OI 4552 Autosampler (for FID 6 ) Used/ good – 09/2000 8.5 

GC with FID (FID#9- GRO) Agilent 6890 GC Used/ good – 09/2006 2.5 

Purge & Trap Concentrator Tekmar 3100 (for FID #9 – GRO) New / excellent – 04/2004 4 

Closed Loop Multi-sampler OI 4552 Multi-sampler (FID#9) Used/ good – 09/2000 7.5 

GC Dual PID (BTEX 1&2) HP 5890 Series II Used/ good – 09/2000 8.5 

Purge & Trap Concentrator Tekmar 3000 (BTEX 1&2) Used/ good – 09/2000 8.5 

Closed Loop Multi-sampler Varian Archon Sampler (BTEX 1&2) Used/ good – 09/2000 8.5 

GC Dual PID (BTEX 3&4) HP 5890 Series II Used / good – 02/2001 8 

Closed Loop Multi-sampler Varian Archon Sampler (BTEX 3&4) New / excellent – 08/2001 7.5 

Purge & Trap Tekmar 3000 New / excellent – 02/2001 8 

GC Dual ECD (ECD 1&2) HP 5890 Series II, HP7673 Injector Used / good – 02/2000 9 

GC Dual ECD (ECD 3&4) HP 5890 Series II, HP7673 Injector Used / good – 07/2000 8.5 

GC Dual ECD (ECD 5&6) HP 5890 Series II, HP7673 Injector Used / good – 07/2000 8.5 

GC Dual ECD (ECD 7&8) Agilent 6890N, dual micro ECDs, 

Agilent 7683B Injector 

 New / excellent – 05/2005 3.5 

GC Dual ECD (ECD 9&10) HP 5890 Series II, HP7673 Injector Used / good – 05/2007 7 

GC/MSD (VOA1) HP5890 Series II with HP5972A MSD Used / good – 12/1999 9 

Closed Loop Multi-sampler Varian Archon Multi-sampler (VOA1) New / excellent – 02/2001 8 

Purge & Trap Concentrator HP Purge and Trap (VOA 1) Used / good – 12/1999 9 

GC/MSD II (VOA2) Agilent 6890 GC with 5973A MSD New / excellent – 07/2000 9 

Closed Loop Multi-sampler Varian Archon Multi-sampler (VOA2) New / excellent – 07/2000 9 

Purge & Trap Concentrator Tekmar Dohrman Velocity (VOA2) New / excellent – 04/2004 5 

GC/MSD II (VOA3) HP5890 Series II with HP5972A MSD Used / good – 12/1999 9 

Closed Loop Multi-sampler Varian Archon Multi-sampler (VOA3) New / excellent – 06/2002 6.5 

Purge & Trap Concentrator Tekmar Dohrmann 3100 (VOA3) New / excellent – 06/2002 6.5 

GC/MSD II (VOA4) Agilent 6890 GC with 5973 Inert MSD New / excellent – 04/2004 5 

Closed Loop Multi-sampler Varian Archon Multi-sampler (VOA4) New / excellent – 04/2004 5 

Purge & Trap Concentrator Tekmar Dohrmann Velocity (VOA4) New / excellent – 04/2004 5 

GC/MSD II (VOA5) Agilent 6890 GC with 5975 Inert MSD New / excellent – 03/2005 4 

Closed Loop Multi-sampler Tekmar/Dohrmann SOLATek (VOA5) New / excellent – 03/2005 4 

Purge & Trap Concentrator Tekmar Dohrmann Velocity (VOA5) New / excellent – 03/2005 4 

GC/MSD II (VOA5) Agilent 6890 GC with 5975 Inert MSD New / excellent – 02/2009 <1 

Closed Loop Multi-sampler Varian Archom (VOA5) New / excellent – 02/2009 <1 

Purge & Trap Concentrator Tekmar Dohrmann Velocity (VOA5) New / excellent – 02/2009 <1 

GC/MSD II (SV2) Agilent 6890 Plus with 5973 MSD New / excellent – 07/2000 8.5 

GC/MSD III (SV3) Agilent 6890 Plus with 5973 MSD New / excellent – 03/2002 7 

GC/MSD IV (SV4) Agilent 6890 Plus with 5973 MSD New / excellent – 08/2004 4.5 

GC/MSD V (SV5) Agilent 6890 Plus with 5973 MSD New / excellent – 06/2006 5.5 

Soxtec Extraction Unit (1) Model 2055 (Total Ext. Capacity = 6) New / good – 6/2002 6.5 

Soxtec Extraction Unit (2) Model 2055 (Total Ext. Capacity = 6) New / good – 7/2008 <1 

HPLC – with UV and 

Fluorescence detectors 

Agilent 1100 Series HPLC, with 

autosampler 

 New / excellent – 03/ 2002 7 

UV/VIS Shimadzu UV-2450 New / Excellent – 02/2006 3 

Ion Chromatograph Dionex ICS-3000 New / Excellent – 11/2006 3 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page C7 of 7 ____________

© 2009 ALS Laboratory Group - All Rights Reserved 

Table C.3 – Houston Lab 

Item Description 

Manufacturer/Model Condition / Year Installed Approx. 

Age-Years

ICP/MS Agilent 7500 Series ORC New / excellent – 08/2003 5.5 

ICP/MS Agilent 7500 Series ORCE New / excellent – 04/2005 4 

ICP/MS Agilent 7500 Series ORCE New / excellent – 03/2007 3 

Mercury Analyzer CETAC Technologies M-6000A New / excellent – 01/2000 9 

TOC Analyzer (for waters) OI 1010 TOC Analyzer &Autosampler New / excellent – 02/2005 4 

TOC Analyzer (for soils) OI TOC Solids Analyzer New / excellent – 07/2003 5.5 

Cyanide Distillation Environmental Express 10 position New / excellent – 06/2002 6.5 

Ammonia Distillation Environmental Express 10 position New / excellent – 06/2003 5.5 

Vortex Fisher Genie 2 New / excellent – 01/2002 7 

Stirrer Labline Multi Magnestir New / excellent – 01/2000 9 

Centrifuge (4) IES Used/good – 01/2000 9 

Water Bath Precision Used/good – 01/2000 9 

Nitrogen Evaporator Organomation N-Evap Used/good – 01/2001 8 

Turbo Vap II (2 units) Caliper Life Sciences, Turbo Vap II New / excellent – 03/2006 3 

3-D Shaker Glass-col New / excellent – 01/2002 7 

Multi-tube Vortexer VWR VX 2500 New / excellent – 01/2002 7 

GPC OI Analytical Autoprep 2000 New / excellent – 06/2002 6.5 

Furnace Thermodyne New / excellent – 01/2002 7 

Furnace Thermodyne New / excellent – 07/2008 <1 

Sonicator Ultrasonic Heat System XL New / excellent – 01/2001 8 

Ultrasonic Bath (3) Branson 2200 Used / good – 12/1999 9 

Hot Plate (2) Corning PC 104 Used / good – 12/1999 9 

Hot Block Digesters (2) Environmental Express New / excellent – 01/2000 & 

07/2001 

9 & 8 

Hot Block Digesters (2) Environmental Express New / excellent – 04/2007 2 

Analytical balances (6) Mettler AE 200 (2), Mettler AE 163(2), 

Fisher A160, Cahn Micro-balance (1) 

 Used / good – 01/2000 9 

Analytical balance Ohaus ScoutPro 400g New / Excelent – 11/2006 2 

Analytical balance Shimadzu UniBlock AUX220 New / Excellent – 02/2006 2 

Specific Ion/pH Meter (2) Fisher Accumet AR-50 New / excellent – 01/2000 9 

Specific Ion/pH Meter Fisher Accumet AR-50 New / excellent – 04/2008 <1 

PH Meter Mettler Toledo SevenEasy New / Excellent – 11/2006 2 

ZHE Extraction Units (9) Environmental Express New / excellent – 01/2002 6 

Top Loading balance (1) Mettler 4400 Used / good – 01/2000 8 

Top Loading balance (1) Denver Instruments APX-1502 New / excellent – 05/2003 5 

Forced Air Oven VWR FM 1390 Used / good – 12/1999 9 

Drying Oven (2) VWR Model 1326 New / excellent – 12/2005 3 

Full Size Refrigerator/Freezer (3) Labline Explosion Proof Used / good – 12/1999 9 

13' x 40' Walk-in Refrigerator Thermo-Kool New / excellent – 04/2007 2 

8' x 10' Walk-in Refrigerator NorLake Used / good – 12/1999 9 

8' x 10' Walk-in Freezer NorLake Used / good – 6/2002 6 

Refrigerators (5) Various Used / good – 06/2001 8 

Freezer (3) Hussmann/Tappan Used / good – 12/1999, 4/2002 9 & 7 

ELIMS Database e-LIMS New / excellent – 7/2004 4 

Computer Servers (4) HP and Compaq New / excellent – 12/1999 9 

Computer Server (Target) e-Lab Analytical, Inc. New / excellent – 7/2005 4 

SQL Server (eLIMS) e-Lab Analytical, Inc. New / excellent – 7/2005 4 

 

20 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page D1 of 4 

© 2009 ALS Laboratory Group - All Rights Reserved 

APPENDIX D – ALS Laboratory Group Standard Operating Procedures

SOP 

Number 

Rev. 

Number 

SOP Title – Houston Facility 

General 

HS-GEN 001 07 Preparation / Management of Standard Operating Procedures 

HS-GEN 002 07 Laboratory Ethics, Accountability and Responsibility 

HS-GEN 003 06 Glassware Cleaning 

HS-GEN 004 05 Client Confidentiality of Electronic Data Transfers 

HS-GEN 005 05 Departures from Approved Procedures 

HS-GEN 006 03 Resources Review 

HS-GEN 007 04 Subcontract Sample Submittal 

HS-GEN 008 04 QC Criteria Development Where No Regulatory Criteria Exist 

Administrative 

HS-ADM 003 07 Work Order Reporting 

HS-ADM 004 05 Complaint Resolution 

Quality Assurance 

HS-QS 001 06 Chemical Purchase/Receipt; Chemical Prep., Storage & Tracking

HS-QS 002 04 Changing Analytical Results/Report Revision

HS-QS 003 06 Nonconformance Corrective Action Reporting 

HS-QS 004 07 Control Charting 

HS-QS 005 04 Validation of New Instrumentation and New Methods 

HS-QS 006 04 Limit of Detection and Limit of Quantitation 

HS-QS 007 06 Reagent Water 

HS-QS 008 06 Container Sub-sampling - Metals, Inorganics, Semivolatile Organics 

HS-QS 009 06 Data Reduction, Review and Validation 

HS-QS 010 01 Container Sub-sampling-Volatile Organics, SW5035A 

HS-QS 011 05 Records Archival 

HS-QS 012 04 Internal Audits 

HS-QS 013 05 Employee Training 

HS-QS 014 06 Laboratory Records Control Procedures 

HS-QS 015 01 Data Integrity System 

HS-QS 016 05 Manual Integration Policy 

HS-QS 017 02 Quality Assurance Management Review 

HS-QS 018 03 Sporadic Marginal Exceedance 

HS-QS 019 02 Estimation of Measurement Uncertainty 

Client Services - Sample Management- Safety 

HS-SM 001 07 Sample Log-in Procedures 

HS-SM 002 05 Bottle Orders 

HS-SM 003 03 LIMS Login Procedures 

HS-SAF 001 04 Waste Disposal Procedures 

Information Technology 

HS-IT 001 04 LIMS Raw Data and Data Integrity 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page D2 of 4 

© 2009 ALS Laboratory Group - All Rights Reserved 

SOP 

Number 

Rev. 

Number 

SOP Title – Houston Facility 

HS-IT 002 03 Computer Software Installation and Maintenance 

HS-IT 003 03 LIMS System Security 

HS-IT 004 01 Electronic Data Archival and Storage 

HS-IT 005 01 Electronic Time Changes 

Equipment 

HS-EQ 001 07 Balance Calibration and Use 

HS-EQ 002 08 Thermometer Calibration and Temperature Monitoring 

HS-EQ 003 06 Lab Volumetric Ware Calibration 

HS-EQ 004 05 Preventative Maintenance 

Metals Preparation and Analysis 

HS-MET 001 08 Hot Block Metals Digestion - Solids Samples 

HS-MET 002 06 Hot Block Metals Digestion - Aqueous Samples 

HS-MET 003 07 ICP-MS Analysis – SW6020A – EPA 200.8 

HS-MET 004 08 Mercury Analysis for Aqueous Samples – 7470A – EPA 245.2 

HS-MET 005 08 Mercury Analysis for Solid Samples – 7471B 

General Chemistry 

HS-WC 001 06 Alkalinity Forms by SM 2320B / E310.1 

HS-WC 002 06 pH (Aqueous SW9040C – EPA150.1 / soils SW 9045D) 

HS-WC 003 07 Total Suspended Solids, TSS- EPA 160.2 

HS-WC 004 02 Analysis of Fluoride by ISE Method SM 4500 F B & C 

HS-WC 005 03 Free Carbon Dioxide, SM 4500 CO2 D 

HS-WC 006 06 Ortho Phosphorus, SM 4500 P / EPA 365.3

HS-WC 007 05 Analysis of Fluoride by ISE Method SW9214 

HS-WC 008 06 Chrome VI Analysis, SW 7196A & SM3500-Cr B 

HS-WC 009 05 Chrome VI – Preparation of Soils , SW 3060A 

HS-WC 010 03 Ferrous Iron, SM 3500 Fe D 

HS-WC 011 04 Specific Conductivity, EPA120.1 / SW9050A / SM2510 B 

HS-WC 012 07 Total Dissolved Solids, TDS- SM 2540 C 

HS-WC 013 06 Total, Fixed and Volatile Solids, Aqueous Samples- SM 2540 B & E 

HS-WC 014 06 Percent Solids, Percent Moisture, Soils - 

HS-WC 015 04 Total Phosphorus, EPA 365.3 

HS-WC 016 03 Settleable Solids, SM 2540 F 

HS-WC 017 04 Silica (SiO2), SM 4500 Si D 

HS-WC 018 05 Sulfide, Iodometric Method, SM 4500 S-2 F 

HS-WC 019 03 Sulfite, Iodometric Method, SM 4500 SO3

-2 B 

HS-WC 020 05 Cyanide, Total SW9010/SW9014 / E335.3 / SM4500 CN C&E 

HS-WC 021 04 Total Organic Carbon, Aqueous SM5310C / SW9060A 

HS-WC 022 03 Total Organic Carbon, Soils - SW9060 Modified 

HS-WC 023 02 Color, SM 2120B 

HS-WC 025 03 Chemical Oxygen Demand, Hach 8000 

HS-WC 026 03 Ammonia as N, SM 4500-NH3 B / F 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page D3 of 4 

© 2009 ALS Laboratory Group - All Rights Reserved 

SOP 

Number 

Rev. 

Number 

SOP Title – Houston Facility 

HS-WC 027 02 Ammonia as N, by ISE, SM 4500-NH3 B / D 

HS-WC 028 03 Residual Chlorine - SM 4500 Cl F 

HS-WC 029 03 Total Recoverable Phenols, EPA 420.4 – SW9065 

HS-WC 030 01 Turbidity by Nephelometry 

HS-WC 031 Nitrite as N, SM 4500-N02 B / EPA 354.1 

HS-WC 032 02 Cyanide, Weak Acid Dissociable, SM 4500 CN – I 

HS-WC 033 03 Total Kjeldahl Nitrogen, EPA 351.2 / SM 4500-NH3 D 

HS-WC 036 03 Oil and Grease, SPE - EPA 1664 

HS-WC 037 02 Flash Point by D93-02a / SW1010 Ignitability 

HS-WC 040 02 TOC on Solids, Walkley-Black 

HS-WC 041 01 Ignitability of Solids, SW1030 

HS-WC 042 01 Paint Filter Liquids Test, SW9095B 

HS-WS 043 01 Dissolved Qxygen SM4500-O G & EPA360.1 

HS-BIO 003 02 BOD and CBOD (EPA 405.1 & SM5210 B) 

 

HS-IC 001 06 Anions by Ion Chromatography, SW-9056A-EPA 300.0 

HS-IC 002 02 Perchlorate by Ion Chromatography, EPA 314 

Leachate Preparation Methods 

HS-LEACH 001 01 TCEQ 7 Day Leachate Procedure 

HS-TCLP 001 06 Toxic Characteristic Leaching Procedure (TCLP) – ZHE 

HS-TCLP 002 05 Toxic Characteristic Leaching Procedure (TCLP) – SV/ Metals 

HS-SPLP 001 06 Synthetic Characteristic Leaching Procedure (SPLP) – ZHE 

HS-SPLP 002 05 Synthetic Characteristic Leach. Procedure (SPLP) – SV/ Metals 

Organic Preparation Methods 

HS-EXT 001 09 Separatory Funnel Extraction of Aqueous Samples 

HS-EXT 002 09 Automated Soxhlet Extraction of Solids/Soils – SW3541 

HS-EXT 003 05 Sep. Funnel Extraction – Herbicides from Waters, SW 8151A 

HS-EXT 004 05 Sonication Extraction- Herbicides-Soils, SW8151A 

HS-EXT 005 07 Extraction of TPH from Waters and Soil - TX1005 

HS-EXT 006 04 Fractionation of TPH from Waters and Soil - TX1006 

HS-EXT 008 04 LL Sonication Extraction – DRO - Soils - SW3550C 

HS-EXT 009 04 LL Extraction of DRO From Waters - SW3510C 

HS-EXT 011 03 GPC Cleanup - SW3640A 

HS-EXT 013 02 Salting Out Extraction of Explosives from Waters by SW8330A 

HS-EXT 014 03 Extraction of Explosives from Soils by SW8330A 

HS-EXT 015 01 Extraction – Derivatization of Formaldehyde – Soils/Waters - SW8315A 

HS-EXT 017 01 Massachusetts EPH, extraction – fractionation, water & soil 

HS-EXT 020 01 HEM from soils by SW9071B 

GC / HPLC Methods 

HS-BTEX 001 06 BTEX Analysis in Solid and Aqueous Samples – SW8021B 

HS-GRO 001 03 GRO by Purge & Trap – Soils & Waters – GC/FID – SW8015C 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page D4 of 4 

© 2009 ALS Laboratory Group - All Rights Reserved 

SOP 

Number 

Rev. 

Number 

SOP Title – Houston Facility 

HS-GRO 002 01 Massachusetts VPH 

HS-GCFID 001 07 TCEQ 1005 -Total Petroleum Hydrocarbons 

HS-GCFID 003 05 Low Level DRO, ORO by GC/FID SW-8015C 

HS-GCFID 005 03 Nonhalogenated Organics by Dir. Inj GCFID - 8015 Modified 

HS-GCFID 006 03 Fractionation Analysis of TPH by TCEQ 1006 

HS-GCFID 009 01 Massachusetts EPH 

HS-GCFID 010 01 RSK-175, Headspace Analysis, Methane, Ethane, Ethene 

HS-GCECD 001 07 Organochlorine Pesticides by GC/ECD – 8081B – EPA 608 

HS-GCECD 002 08 Polychlorinated Biphenyls (PCBs) by GC/ECD – 8082A – EPA 608 

HS-GCECD 003 06 Herbicides by GC/ECD - 8151A 

HS-GCECD 004 03 EDB and DBCP by GC/ECD - 8011 / EPA 504.1 

HS-HPLC 002 02 Acrylamide by SW 8316 

HS-HPLC 003 03 Analysis of Explosives by SW8330A 

HS-HPLC 004 01 Formaldehyde by SW8315A 

GC/MS Methods 

HS-MSSV 001 09.1 Semivolatile Organic Compounds by GC/MS by 8270D – EPA 625 

HS-MSSV 003 04 Low Level SV Organic Compounds by GC/MS - 8270D Modified 

HS-MSV 001 09.1 Volatile Organics Compounds by GC/MS 8260C – EPA 624 

Miscellaneous SOP for State Specific Programs 

HS-LaDNR 001 03 Sample Preparation 

HS-LaDNR 002 03 Cation Exchange Capacity - Exchangeable Cations - ESP 

HS-LaDNR 003 03 Saturated Paste - Saturation Point of Soils - LA DNR 29B 

HS-LaDNR 004 02 True Total Barium - LA DNR 29B 

HS-LaDNR 005 02 Leachate Test of Soil - LA DNR 29B 

HS-LaDNR 006 02 Oil and Grease from 7 Day Leachate Test of Soil - LA DNR 29B 

HS-LaDNR 007 01 Oil and Grease from Soil - LA DNR 29B 

HS-LaDNR 008 01 LaDNR l:1 Aqueous Extract 

HS-LaDNR 009 01 LaDNR Soil pH 

HS-LaDNR 010 01 LaDNR Electrical Conductivity 

 

24 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page E1 of 18 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.1.1 Calibration Summary & QC Procedures - Colorimetric Methods (SW 7196, etc), Houston Facility 

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Initial multipoint 

calibration (minimum 5 

standards and a blank). 

initial calibration prior 

to sample analysis. 

Correlation coefficient >0.995 

for linear regression. 

Correct problem then repeat 

initial calibration. 

Second-source calibration 

check standard. 

Once per initial 

calibration, prior to 

sample analysis. 

Analyte within +10% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Calibration verification. After every 15 samples 

and at the end of the 

analysis sequence. 

The analyte within +10% of 

expected value. 

Correct problem then repeat 

ICAL or CCV and reanalyze all 

samples since last successful 

CCV. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Table G.1.1 

Recalculate results; locate and fix 

system problem and rerun 

demonstration for analytes that 

did not meet criteria. 

Method blank. One per prep batch. No analyte detected 

Above 1⁄2 LOQ. 

or .> 5% of regulatory limit or 

>5% of target analyte detected 

in a sample. 

Correct problem then reprep and 

analyze method blank and all 

samples in the affected batch. 

LCS for the analyte. One LCS per prep 

batch. 

QC acceptance criteria, 

Table G.1.1 

Correct problem then reprep and 

analyze the LCS and all samples 

in the affected prep batch. 

MS/MSD. One MS/MSD per every 

20 field samples per 

matrix. 

QC acceptance criteria, 

Table G.1.1; RPD < 20% 

Describe in Laboratory Review 

Checklist. 

LOD study. Once per 12 month 

period. 

LODs established shall be < 1/2 

the LOQs in Table F.1 

None. 

Table E.1.2 Calibration Summary and QC Procedures for EPA Method 300.0 / SW9056A – Houston Facility 

QC Check 

Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Minimum five-point 

initial calibration for all 

analytes. 

Initial calibration prior to 

sample analysis. 

Calibration factor or Linear 

least squares regression - r >

0.995 

Correct problem then repeat 

initial calibration. 

Second-source (ICV) 

calibration verification, 

all analytes. 

Once per five-point 

initial calibration. 

All analytes within ± 10% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Retention time window 

verified for each analyte. 

Each initial calibration Verify RT ± 3 times standard 

deviation for each analyte 

average retention time over 8 to 

24 hr period after ICAL. CCVs 

must fall within the RT window 

Correct problem then reanalyze 

all samples analyzed since the 

last retention time check. 

25 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page E2 of 18 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.1.2 Calibration Summary and QC Procedures for EPA Method 300.0 / SW9056A – Houston Facility 

QC Check 

Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Calibration verification 

(CCV and CCB) 

CCV and CCB after 

every 10 injections and 

at the end of the analysis 

sequence. 

All analytes within ± 10% of 

expected value for CCV; no 

analytes in CCB above 2-3 

times the LOD. 

Correct problem, repeat 

calibration verification and 

reanalyze all samples since last 

successful calibration 

verification. 

Demonstration of ability 

to generate acceptable 

accuracy and precision 

using four replicate LCS. 

Annually, Once per 

analyst. 

LCS recovery ± 10% of 

expected value. 

Recalculate results; locate and 

fix problem with system, then 

rerun demonstration for those 

analytes not meeting criteria. 

Method blank. One per analytical batch 

of 10 (E300.0) or 20 

(SW9056A) or less. 

No analytes detected above the 

LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem, and then reanalyze method blank and all 

samples processed with the 

contaminated blank. 

LCS for all analytes. One LCS per analytical 

batch of 10 (E300) or 20 

(SW9056A) field 

samples. 

Recovery ± 10% of expected 

value). 

Correct problem, and then reanalyze the LCS and all samples 

in the affected analytical batch. 

MS One MS per every 10 

(E300) or every 20 

(SW9056A) field 

samples per matrix. 

Advisory acceptance recovery ±

20% of expected value 

Describe in Laboratory Review 

Checklist. 

Duplicate or MSD One duplicate (or MSD) 

per every 10 (E300) or 

every 20 (SW9056A) 

field samples per matrix. 

RPD <20% 

Describe in Laboratory Review 

Checklist. 

LOD Study Once per 12 month 

period 

Detection limits established 

shall be ≤ 1⁄2 the LOQs 

Table E.1.3 Calibration Summary & QC Procedures - Ion Selective Electrode (e. g. SM 4500-NH3 D) Houston Facility

QC Check 

Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Minimum five-point 

initial calibration for the 

ISE analyte. 

Upon initial instrument 

set-up, major 

maintenance (e.g. new 

ISE probe installation) or 

each time a CCV fails to 

meet criteria. 

Slope in range of 55 to 59 mV Correct problem then repeat 

initial calibration. 

Second-source (ICV) 

calibration verification, 

all analytes. 

Once per initial 

calibration curve 

All analytes within ± 10% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Calibration verification 

(CCV and CCB) 

CCV and CCB after 

every 10 injections and 

at the end of the analysis 

sequence. 

All analytes within ± 10% of 

expected value for CCV; no 

analytes in CCB above the 

times the LOQ. 

Correct problem, repeat CCV 

and reanalyze all affected 

samples since last successful 

CCV. 

26 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page E3 of 18 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.1.3 Calibration Summary & QC Procedures - Ion Selective Electrode (e. g. SM 4500-NH3 D) Houston Facility

QC Check 

Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Demonstration of ability 

to generate acceptable 

accuracy and precision 

using four replicate LCS. 

Annually, Once per 

analyst. 

LCS recovery ± 10% of 

expected value. 

Recalculate results; locate and 

fix problem with system, then 

rerun demonstration for those 

analytes not meeting criteria. 

Method blank. One per analytical batch 

of 10 (E300.0) or 20 

(SW9056A) or less. 

No analytes detected above the 

LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem, and then reanalyze method blank and all 

samples processed with the 

contaminated blank. 

LCS for all analytes. One LCS per analytical 

batch of 10 (E300) or 20 

(SW9056A) field 

samples. 

Recovery ± 10% of expected 

value). 

Correct problem, and then reanalyze the LCS and all samples 

in the affected analytical batch. 

MS One MS per every 10 

(E300) or every 20 

(SW9056A) field 

samples per matrix. 

Advisory acceptance recovery ±

20% of expected value 

Describe in Laboratory Review 

Checklist. 

Duplicate or MSD One duplicate (or MSD) 

per every 10 (E300) or 

every 20 (SW9056A) 

field samples per matrix. 

RPD <20% 

Describe in Laboratory Review 

Checklist. 

LOD Study Once per 12 month 

period 

Detection limits established 

shall be ≤ 1⁄2 the LOQs 

Table E.2.1 - Summary of Calibration and QC Procedures for ICP/MS Methods SW6020A and 200.8 Houston Facility 

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action 

MS tuning sample. Prior to initial calibration Tune requirements for both EPA 

200.8 and SW6020A must be 

met (see §11.3 of SOP MET-003, 

current revision) 

Retune instrument then 

reanalyze tuning solution. 

Initial calibration 

(minimum 4 standards 

and a blank). 

Daily initial calibration 

prior to sample analysis. 

r > 0.998. N/A. 

Initial Calibration 

verification (second 

source). 

Daily after initial 

calibration 

All analytes within ±10% of 

expected value. 

Correct problem and repeat 

initial calibration. 

Low Level ICV (LLICV). Daily, after ICV All analytes should within ±30% 

of expected value. 

Rinse system again , and repeat 

LLICV 

Calibration blank (ICB 

and CCB). 

Run the ICB after the 

ICV (Before analyzing 

samples) and run a CCB 

after each CCV, The 

CCV is run every 10 

samples and at end of the 

analysis sequence. 

Assess analytes detected >LOQ 

(or MQL). 

If any >MQL, Correct problem 

then re-analyze the CCB and 

any affected previous samples 

having detections >MQL. 

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Table E.2.1 - Summary of Calibration and QC Procedures for ICP/MS Methods SW6020A and 200.8 Houston Facility 

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action 

Calibration verification 

(Instrument Check 

Standard). 

Before beginning a 

sample run, after every 

10 samples and at the end 

of the analysis sequence. 

All analyte(s) within +10% of 

expected value. 

Correct problem then repeat 

ICAL or CCV and reanalyze all 

samples since last successful 

CCV. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. 6020A: QC acceptance criteria, 

Recovery within 80-120% of 

expected results. 

200.8: QC acceptance criteria, 

Recovery within 85-115% of 

expected results. 

Recalculate results; locate and 

fix system problem and rerun 

demonstration for analytes that 

did not meet criteria. 

Method blank. One per preparation 

batch. 

No analytes detected 

> 1⁄2 LOQ; for common lab 

contaminants (Ca, Na, Mg, Fe, 

Al, Zn) - > LOQ ; or > 5% of 

regulatory limit or >5% of target 

analyte detected in a sample. 

Correct problem reprep and 

analyze method blank and all 

samples processed with the 

contaminated blank. 

Interference check 

solutions (ICS-A and 

ICS-AB). 

At the beginning and end 

of an analytical run or 

twice during a 12-hour 

period, whichever is 

more frequent. 

ICS-A: All non-spiked analytes 

< 1⁄2 LOQ; within +20% of true 

value. 

ICS-AB: Within +20% of true 

value. 

Terminate analysis; locate and 

correct problem; reanalyze ICS; 

reanalyze all affected samples. 

LCS for the analyte. One LCS per prep batch. 6020A: QC acceptance criteria, 

Recovery within 80-120% of 

expected results. 

200.8: QC acceptance criteria, 

Recovery within 85-115% of 

expected results. 

Correct problem, reprep and 

analyze the LCS and all 

samples in affected prep batch. 

Dilution test (6020A 

only). 

Each preparatory batch. 1:4 dilution must agree within 

+10% of the original 

determination for analytes 

present at concentrations > 50x 

concentration of the LOQ. 

Perform post digestion spike 

addition for failed analytes. 

Post digestion spike 

addition (6020A only). 

When dilution test fails. Recovery within 75-125% of 

expected results. 

Dilute the sample; reanalyze 

post digestion spike addition. 

MS/MSD SW6020A:One MS/MSD 

per every 20 field 

samples per matrix; 

200.8: One MS per every 

10 field samples per 

matrix 

SW6020A: QC advisory 

acceptance criteria, 75-1255% of 

expected results ; 

 200.8: QC advisory acceptance 

criteria, recovery within 70-

130% of expected results 

Describe in Laboratory Review 

Checklist. 

Internal Standards (ISs). Every sample. For 6020A: See Table 21.3 – 

Sample IS intensity >70% of 

intensity of IS in the ICAL 

blank. 

For 200.8: Sample IS intensity 

within 60-125% of intensity of IS 

in the ICAL blank. CCBs and 

CCVs must meet 80-120%. 

Perform corrective action as 

described in Method 

SW6020A, Section 8.3. 

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Table E.2.1 - Summary of Calibration and QC Procedures for ICP/MS Methods SW6020A and 200.8 Houston Facility 

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action 

LOD study. MDL Study performed 

annually. Limits are 

checked quarterly 

through Detection Limit 

Check Study (DCS) 

LODs established shall be ≤1/2 

the LOQs in Table F.2.1 

None. 

Table E.2.2 - Calibration & QC Procedures – Mercury SW7470A/EPA 245.1 & SW7471B - Houston Facility 

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Initial multipoint 

calibration (minimum 5 

standards and a blank). 

Daily initial calibration 

prior to sample analysis. 

Correlation coefficient >0.995 

for linear regression. 

Correct problem then repeat 

initial calibration. 

Instrument Performance 

Check (ICP = ICCV, for 

EPA 245.1 only) 

Daily after initial 

calibration prior to sample 

analysis (same source as 

ICAL) 

The analyte within +5% of 

expected value (EPA 245.1 

only). 

Correct problem then repeat 

initial calibration. 

Second-source Initial 

Calibration Verification 

standard. 

Once per initial daily 

multipoint calibration. 

Analyte within +10% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Calibration blank. Once per initial daily 

multipoint calibration. 

No analyte detected 

> 1⁄2 LOQ. 

Correct problem then 

reanalyze calibration blank 

and all samples associated 

with blank. 

Continuing Calibration 

verification (CCV). 

After every 10 samples 

and at the end of the 

analysis sequence. 

The analyte within +10% of 

expected value. 

Correct problem then repeat 

calibration and reanalyze all 

samples since last successful 

calibration. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, within 

+15% of expected value. 

Recalculate results; locate and 

fix system problem and rerun 

demonstration for those 

analytes not meeting criteria. 

Method blank. One per prep batch of 20 

or less. 

No analytes detected 

> 1⁄2 LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem then reprep 

and analyze method blank and 

all samples processed with the 

contaminated blank. 

LCS for the analyte. One LCS per prep batch of 

20 or less. 

QC acceptance criteria, within 

+15% of expected value. 

Correct problem then reprep 

and analyze the LCS and all 

samples in the affected prep 

batch. 

MS/MSD. One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria, within 

+15% of expected (7470A & 

7471B); ,within +30% of 

expected (for EPA 245.1) 

Describe in Laboratory 

Review Checklist. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Initially once per analyst, 

then annually thereafter. 

QC acceptance criteria, within 

+15% of expected value. 

Recalculate results; locate and 

fix system problem and rerun 

demonstration for analytes 

not meeting criteria. 

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LOD (MDL) study. Once per 12 month period. LODs established shall be ≤1/2 

LOQs in Table F.2.2 

None. 

Table E.3.1 - Calibration and QC Procedures for TPH by Method TX 1005 – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Five-point initial 

calibration for all 

analytes. 

Initial calibration prior to 

sample analysis. 

Linear – RSD for all analytes 

≤20% or 

Linear – least squares regression 

R > 0.995; or 

Correct problem then repeat 

initial calibration. 

Second-source calibration 

verification (ICV). 

Once per five-point initial 

calibration. 

All analytes within ≤25% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Calibration verification 

(CCV). 

Daily, before sample 

analysis, after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ≤25% of 

expected value. 

Correct problem, repeat CCV 

or ICAL and reanalyze all 

samples since last successful 

CCV. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Table G.4. 

Recalculate results; locate 

and fix system problem and 

rerun demonstration for 

analytes not meeting criteria. 

Method blank. One per prep batch. No TPH detected 

≥ LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem then reprep 

and analyze method blank 

and all samples processed 

with the contaminated blank. 

LCS One LCS per prep batch, 

LCS includes all analytes. 

QC acceptance criteria, 

Table G.4. 

Correct problem, then reprep and analyze the LCS and 

all samples in the affected 

prep batch. 

Surrogate spike Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, 

Table G.4. 

Method 8000C, Section 9.6 

Requirements. Describe in 

Laboratory Review Checklist. 

MS/MSD One MS/MSD per every 

20 samples per matrix. 

QC acceptance criteria, 

Table G.4. 

Describe in Laboratory 

Review Checklist. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Initially once per analyst, 

then annually thereafter. 

QC acceptance criteria, 

Table G.5. 

Recalculate results; locate 

and fix system problem and 

rerun demonstration for 

analytes not meeting criteria. 

LOD study. Once per 12 month period. LODs established shall be 

≤ 1/2 LOQs in Table F.3. 

None. 

Table E.3.2 - Calibration and QC Procedures for TPH & Misc. Analytes, Method 8015D – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Five-point initial 

calibration for all 

analytes. 

Initial calibration prior to 

sample analysis. 

Linear – RSD for all analytes 

≤20% or 

Linear – least squares regression 

R > 0.995; or 

Correct problem then repeat 

initial calibration. 

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Table E.3.2 - Calibration and QC Procedures for TPH & Misc. Analytes, Method 8015D – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Second-source calibration 

verification (ICV). 

Once per five-point initial 

calibration. 

All analytes within ≤20% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Calibration verification 

(CCV). 

Daily, before sample 

analysis, after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ≤20% of 

expected value. 

Correct problem, repeat CCV 

or ICAL and reanalyze all 

samples since last successful 

CCV. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Table G.4. 

Recalculate results; locate 

and fix system problem and 

rerun demonstration for 

analytes not meeting criteria. 

Method blank. One per prep batch. No analytes detected 

≥ LOQ for TPH or 

≥ 1⁄2 LOQ for Misc. Analytes 

or .> 5% of regulatory limit or 

>5% of target analyte detected 

in a sample. 

Correct problem then reprep 

and analyze method blank 

and all samples processed 

with the contaminated blank. 

LCS One LCS per prep batch, 

LCS includes all analytes. 

QC acceptance criteria, 

Table G.3.2 

Correct problem, then reprep and analyze the LCS and 

all samples in the affected 

prep batch. 

Surrogate spike Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, 

Table G.3.2 

Method 8000C, Section 9.6 

Requirements. Describe in 

Laboratory Review Checklist. 

MS/MSD One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria, 

Table G.3.2 

Describe in Laboratory 

Review Checklist. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Initially once per analyst, 

then annually thereafter. 

QC acceptance criteria, 

Table G.3.2 

Recalculate results; locate 

and fix system problem and 

rerun demonstration for 

analytes not meeting criteria. 

LOD study. Once per 12 month period. LODs established shall be 

≤ 1/2 LOQs in Table F.3. 

None. 

Table E.4 - Calibration and QC Procedures for Method SW 8011 / EPA504.1 – Houston Facility

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Minimum of five-points 

to generate initial 

calibration curve 

Initial calibration prior to 

sample analysis. 

Linear – mean RSD for all 

analytes(peaks) <20%; or 

Linear – least squares regression, 

r > 0.995; or 

Non-linear – COD >0.99 (6 

points must be used for 2nd

order). 

Correct problem, then repeat 

initial calibration. 

Second-source Calib. 

Verification (ICV) 

Once per initial 

calibration. 

Agree within ± 30 % of expected 

value (same as the LCS). 

Correct problem then repeat 

initial calibration. 

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Table E.4 - Calibration and QC Procedures for Method SW 8011 / EPA504.1 – Houston Facility

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Calibration verification 

(CCV) 

Daily, before sample 

analysis, after every 20 

samples and at the end of 

the analysis sequence. 

All analytes within ±30% of 

expected value. 

Correct problem, then repeat 

CCV. If second CCV fails, 

repeat ICAL. Reanalyze all 

samples since last successful 

calibration verification. 

Retention time window 

set +/- 0.07 minutes from 

the average RT. 

Each initial calibration 

and calibration 

verifications. 

RT windows are set at +/- 0.07 

minutes from the ICAL mean 

RT. 72 hr RT Study after the 

ICAL must be within window. 

Absolute RTs are updated with 

each CCV to compensate for 

minor shifts in absolute RT. 

Correct problem then reanalyze 

all samples analyzed since the 

last retention time check. 

Method blank. One per preparation batch. No analytes detected 

 >1/2 LOQ or .> 5% of 

regulatory limit or >5% of target 

analyte detected in a sample. 

Correct problems then re-prep 

and analyze method blank and 

all samples processed with the 

contaminated blank. 

LCS One LCS per preparation 

batch. 

QC acceptance criteria, 

Table G.4.1 for 8011; 

Table G.4.2 for 504.1 

Correct problem then re-extract 

and analyze the LCS and all 

samples in the affected 

analytical batch. 

MS/MSD One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria, 

Table G.4.1 for 8011; 

Table G.4.3 for 504.1 

Describe in Laboratory Review 

Checklist. 

Second Column 

Confirmation 

Every sample and QC 

sample, 100% for all 

positive results 

Detected results 5X above the 

LOQ should differ no more than 

40%. 

Inspect chromatography for coelutions and narrate as 

necessary when due to sample 

matrix. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Table G.4.1 for 8011; 

Table G.4.2 for 504.1 

Recalculate results; locate and 

fix problem with system, then 

rerun demonstration for those 

analytes not meeting criteria. 

Table E.5 Calibration and QC Procedures for BTEX by Method SW8021B / EPA 602 – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Five-point initial 

calibration for all 

analytes. 

Initial calibration prior to 

sample analysis. 

Linear – RSD for all analytes 

<20% or Linear – least squares 

regression r > 0.995; or 

Non-linear – COD > 0.990 (6 

points shall be used for second 

order). [Note: use of grand mean 

not allowed.] 

Correct problem then repeat 

initial calibration. 

Second-source (ICV) 

calibration verification. 

Once per five-point initial 

calibration. 

All analytes within ±20% of 

expected value. 

Correct problem then repeat 

initial calibration. 

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Table E.5 Calibration and QC Procedures for BTEX by Method SW8021B / EPA 602 – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Calibration verification 

(CCV). 

Daily, before sample 

analysis, after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ±20 of 

expected value 

Correct problem then repeat 

ICAL or CCV and reanalyze 

all samples since last 

successful CCV. 

Method blank. One per prep batch. No analytes detected 

 < 1⁄2 LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem then reprep 

and analyze method blank 

and all samples processed 

with the contaminated blank. 

LCS LCS for all analytes. One LCS per prep batch, 

Table G.5. 

Correct problem then reprep 

and analyze the LCS and all 

samples in the affected prep 

batch. 

Surrogate spike Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, 

Table G.5. 

Method 8000C, Section 9.6 

Requirements. Describe in 

Lab Review Checklist. 

MS/MSD One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria, 

Table G.5. 

Describe in Laboratory 

Review Checklist. 

Second-column 

confirmation. 

100% for all positive 

results. 

Same as for initial or primary 

column analysis. 

Same as for initial or 

primary column analysis. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Initially once per analyst, 

then annually thereafter. 

QC acceptance criteria, 

Table G.5. 

Recalculate results; locate 

and fix system problem and 

rerun demonstration for 

analytes not meeting criteria. 

LOD study. Once per 12 month period. Detection limits established shall 

be ≤1/2 LOQs in Table F.5. 

None. 

Table E.6 Summary of Calibration and QC Procedures for Method SW8081B – Houston Facility

QC Check 

Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Five-point initial 

calibration for all 

analytes. 

Initial calibration prior to 

sample analysis. 

Linear – avg. RSD for all 

analytes <20% RSD or 

Linear – least squares regression; 

r > 0.995; or 

Non-linear – COD >0.990 (6 or 

more points must be used for 

second order). [Note: grand mean 

not allowed.] 

Correct problem then repeat 

initial calibration. 

Second-source (ICV) 

calibration verification 

For all analytes. 

Once per five-point initial 

calibration. 

All analytes within ±15% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Retention time window 

verified for each analyte. 

Each initial calibration Verify ± 3 times standard 

deviation for each analyte 

retention time from 72-hour 

study. 

Correct problem then 

reanalyze all samples 

analyzed since the last 

retention time check. 

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Table E.6 Summary of Calibration and QC Procedures for Method SW8081B – Houston Facility

QC Check 

Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Calibration verification 

(CCV). 

Daily, before sample 

analysis , after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ±15% of 

expected value. 

Correct problem then repeat 

CCV or ICAL and reanalyze 

all samples since last 

successful CCV. 

Breakdown check 

(Endrin and DDT). 

Daily prior to analysis of 

samples. 

Degradation <15%. Take corrective action prior 

to calibration. Repeat 

breakdown check. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Table G.6. 

Recalculate results; locate 

and fix system problem and 

rerun demonstration for 

analytes not meeting criteria. 

Method blank. One per prep batch. No analytes detected 

 >1/2 LOQ or .> 5% of 

regulatory limit or >5% of target 

analyte detected in a sample. 

Correct problem then reprep 

and analyze method blank 

and all samples processed 

with the contaminated blank. 

LCS for all analytes. One LCS per prep batch. QC acceptance criteria, 

Tables G.6, G.14. 

Correct problem then reprep 

and analyze the LCS and all 

samples in the affected prep 

batch. 

Surrogate spike. Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, 

Table G.6. 

Method 8000C, Section 9.6 

Requirements. Describe in 

Laboratory Review 

Checklist. 

MS/MSD. One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria, 

Tables G.6 

Describe in Laboratory 

Review Checklist. 

Second-column 

confirmation (excluding 

Toxaphene & chlordane). 

100% for all positive 

results. 

Same as for initial or primary 

column analysis. 

Same as for initial or primary 

column analysis. 

LOD study. Once per 12 month 

period. 

LODs established shall be ≤ 1/2 

LOQs in Table F.6. 

None 

Table E.7 - Summary of Calibration and QC Procedures – Method SW8082A – Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Minimum five-point 

initial calibration (ICAL) 

for Aroclor 1016/1260 

mix. Single point 

calibration for other 

Aroclors, for pattern 

recognition and 

calibration factor. 

Initial calibration prior to 

sample analysis. 

Calibration Factor – RSD for all 

analytes (peaks) <20% or 

Linear – least squares regression 

 r > 0.995; or 

Non-linear regression – (COD) 

 r2 > 0.99 (6 points must be used 

for 2nd order). [Note: use of grand 

mean not allowed.] 

Correct problem then repeat 

initial calibration. 

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Table E.7 - Summary of Calibration and QC Procedures – Method SW8082A – Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Second-source calibration 

verification (ICV) for 

PCB 1016/1260 mix. 

Once per initial calibration . Mix within ±15% of expected 

value. 

Correct problem then repeat 

initial calibration. 

Absolute RT position 

established for each 

analyte and surrogate 

Set once with each ICAL 

and set at the beginning of 

each (12-hr) shift with 

CCV. 

Position shall be set using the 

ICAL midpoint standard, or set 

with the value of CCV that is run 

at beginning of each (12-hr) shift. 

N/A 

RT window verification 

for each analyte and 

surrogate. RT window set 

+/- 0.07 minutes from the 

absolute RT for Aroclor 

1016/1260 mix. 

Each calibration 

verification (ICV and 

CCVs). 

All analytes and surrogates in 

ICV & CCV must fall within the 

RT windows 

Correct problem then reanalyze 

CCV and all samples analyzed 

since the last acceptable RT 

verification. If CCV fails RT 

verification again, redo ICAL 

& reset RT widow & position. 

Calibration verification 

(CCV) for PCB 

1016/1260 mix. 

Daily, before sample 

analysis, after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ±15% of 

expected value. 

Correct problem, repeat ICAL 

or CCV and reanalyze all 

affected samples since last 

successful CCV. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Table G.7. 

Recalculate results; locate and 

fix system problem and rerun 

demonstration for analytes not 

meeting criteria. 

Method blank. One per prep batch. No analytes detected 

 >1/2 LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem then re-prep 

and analyze method blank and 

all samples processed with the 

contaminated blank. 

LCS (1016/1260 mix). One LCS per prep batch. QC acceptance criteria, 

Tables G.7 

Correct problem then reprep 

and analyze the LCS and all 

samples in affected prep batch. 

Surrogate spike. Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, 

Table G.7. 

Method 8000C, Section 9.6 

Requirements. Describe in 

Laboratory Review Checklist. 

MS/MSD (1016/1260 

mix). 

One MS/MSD per every 20 

samples per matrix. 

QC acceptance criteria, 

Tables G.7 

Describe in Laboratory Review 

Checklist. 

LOD study. Once per 12 month period. Detection limits established shall 

be < 1/2 the LOQs in table F.7. 

None. 

Table E.8 Summary of Calibration and QC Procedures for Method SW8151A – Houston Facility

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Five-point initial 

calibration (ICAL) for all 

analytes. 

Initial calibration prior to 

sample analysis. 

Linear – RSD for all analytes 

>20%D or Linear – least 

squares regression r > 0.995; or 

Non-linear – COD 

 > 0.990 (6 points shall be used 

for second order, 7 points shall be 

used for third order). [Note: use of 

grand mean not allowed.] 

Correct problem then repeat 

initial calibration. 

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Table E.8 Summary of Calibration and QC Procedures for Method SW8151A – Houston Facility

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Second-source 

calibration verification 

(ICV). 

Once per five-point initial 

calibration. 

All analytes within ±20% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Retention time (RT) 

window verified for each 

analyte. 

Each initial calibration Verify ± 3 times standard 

deviation for each analyte 

retention time from 72-hour study. 

Correct problem then reanalyze all samples analyzed 

since the last RT check. 

Calibration verification 

(CCV). 

Daily, before sample 

analysis, after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ±20% of 

expected value. 

Correct problem then repeat 

CCV (or ICAL) and reanalyze 

all samples since last 

successful CCV. 

Method blank. One per prep batch. No analytes detected 

 >1/2 LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem then reprep 

and analyze method blank and 

all samples processed with the 

contaminated blank. 

LCS for all analytes. One LCS per prep batch. QC acceptance criteria, 

Tables G.8 

Correct problem then reprep 

and analyze the LCS and all 

samples in affected prep batch. 

Surrogate spike. Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, Table G.8. Method 8000C, Section 9.6 

Requirements. Describe in 

Laboratory Review Checklist. 

MS/MSD. One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria, 

Tables G.8. 

Describe in Laboratory Review 

Checklist. 

Second-column 

confirmation. 

100% for all positive 

results. 

Same as for initial or primary 

column analysis. 

Same as for initial or primary 

column analysis. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, Table G.8. Recalculate results; locate and 

fix system problem and rerun 

demonstration for analytes not 

meeting criteria. 

LOD study. Once per 12 month period. Detection limits established shall 

be ≤ 1/2 LOQs in Table F.8. 

None. 

Table E.9 Calibration and QC Procedures for Method SW8260C & EPA 624 – Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Minimally use five-point 

initial calibration (ICAL) 

for all analytes, use six 

points if second order 

curve fit to be used . 

Initial calibration prior to 

sample analysis. 

Average RRF : see Table in SOP; 

RSD for Target analytes <20%; 

or option below: 

Option 1 linear – least squares 

regression r > 0.995. 

Option 2 non-linear – r2

 > 0.99 

(must use 6 points at minimum). 

[Note: grand mean not allowed.] 

Correct problem then repeat 

initial calibration. 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.9 Calibration and QC Procedures for Method SW8260C & EPA 624 – Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Second-source (ICV) 

calibration verification. 

Once per five-point initial 

calibration. 

8260C- Analytes within ±30% of 

expected value, poor purging VOCs 

±40%. 

624 – Analytes within ±20% of 

expected value, poor purging VOCs 

±25% (Acrolein, Acrylonitrile, 

ketones) 

Correct problem then repeat 

initial calibration. 

Relative Retention Time 

evaluated for each analyte 

in ICAL. 

Each ICAL standard Relative retention time (RRT) of the 

analyte within ± 0.06 RRT units of 

the RRT of the ICAL midpoint. 

Correct problem then re-run 

ICAL. 

Calibration verification 

(CCV). 

Daily, before sample 

analysis and every 12 

hours of analysis time for 

80260C. 

8260C – CCV min RRF- Table in 

SOP; RSDs : < 20% Diff. (when 

using RFs) or drift (when using 

linear 1st order or non-linear 2nd

order fit). 624 – All analytes within 

±20 % D (or ±20 %Drift). 

Correct problem then repeat 

ICAL 

Calibration verification 

(CCV) Internal Standards. 

 

With every calibration 

verification 

Retention time ±30 seconds from 

retention time of the mid-point std. 

In the ICAL. EICP area within –

50% to +100% of ICAL mid-point 

std. 

Inspect mass spectrometer and 

GC for malfunctions; 

mandatory reanalysis of 

samples analyzed while 

system was malfunctioning. 

Internal Standards – 

samples and QC samples. 

All samples and QC 

samples except the CCV 

Retention time ±30 seconds from 

retention time of the CCV. EICP 

area within –50% to +100% of 

CCV. 

Reanalyze sample to confirm 

IS failure due to matrix, and 

describe in lab review 

checklist. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four LCS analyses. 

Once per analyst. QC acceptance criteria, 

Table G.9. 

Recalculate results; locate and 

fix system problem and rerun 

demonstration for those 

analytes not meeting criteria. 

Method blank. One per preparation batch. No analytes detected >1⁄2 LOQ; no 

common lab contaminants 

detected >LOQ or .> 5% of 

regulatory limit or >5% of target 

analyte detected in a sample. 

Correct problem, then reanalyze method blank and all 

samples processed with 

contaminated blank. 

LCS for all analytes. One LCS per preparation 

batch. 

QC acceptance criteria, Table G.9 

and G.14 

Correct problem, then reanalyze the LCS and all 

samples in the affected batch. 

MS/MSD. One MS/MSD per every 

20 project samples per 

matrix. 

QC acceptance criteria for % 

Recovery - Table G.9; 

20% RPD limit for waters; 30% 

PRD Limit for Soils 

Describe in Laboratory 

Review Checklist. 

Check of mass spectral 

ion intensities using BFB 

Prior to ICAL and each 

12hr CCV 

Refer to criteria listed in the method 

description 

Retune instrument and verify. 

Surrogate spike. Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, Table G.9. Method 8000C, Section 9.6 

Requirements. Describe in 

Lab Review Checklist. 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page E14 of 18 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.9 Calibration and QC Procedures for Method SW8260C & EPA 624 – Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

MDL study. Once per 12 month period. Detection limits established shall be 

< 1/2 the LOQs in Table F.9 

None. 

Table E.10 - Calibration and QC Procedures for Method SW8270D & EPA 625 - Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Check of mass spectral ion 

intensities using DFTPP. 

Prior to Init. Calib. And 

12hr Cont. Calibration 

verification (CCV). 

Refer to criteria listed in the 

method description 

Retune instrument and verify. 

Minimum Five-point initial 

calibration for all analytes; 

use six points if second 

order curve fit is used. 

Initial calibration prior to 

sample analysis. 

Evaluate for best curve fit model, 

Avg Response Factors (avg RF) 

and each level RF should meet 

min RF requirements in SOP and 

%RSDs for each: ≤20% or one 

option below: linear curve fit, r > 

0.995; or when non-linear 

(quadratic) where r2

 > 0.990 and 

6 points shall be used (2nd order). 

[Note: use of grand mean not 

allowed.] 

Correct problem then repeat 

initial calibration. 

Second-source (ICV) 

calibration verification. 

Once per each initial 

calibration curve. 

Analytes within ±30% of 

expected value. 

Correct problem then rerun 

ICV. If ICV fails again, correct 

problem and repeat initial 

calibration. 

Continuing Calibration 

Verification (CCV). 

Daily, before sample 

analysis and every 12 

hours of analysis time. 

CCV RF should meet RF 

requirements in Table in SOP 

All compounds should meet 

≤ 20% difference (if using RFs) 

or ≤ 20% drift (if using linear or 

non-linear calibration). 

Correct problem then rerun 

CCV. If CCV fails again, 

repeat initial calibration. 

CCV Internal Standards. Immediately after or 

during data acquisition of 

calibration check standard 

(CCV). 

Retention time ±30 seconds from 

RT of the mid-point standard in 

the ICAL. EICP area within –

50% to +100% of ICAL midpoint standard. 

Check mass spectrometer and 

GC for malfunctions; 

mandatory reanalysis of 

samples analyzed while system 

malfunctioned. 

Internal Standards – 

samples and QC samples. 

All samples and QC 

samples except the CCV 

Retention time ±30 seconds from 

retention time of the daily CCV 

standard. EICP area within –50% 

to +100% of the daily CCV. 

Reanalyze sample to confirm IS 

failure due to matrix, and 

describe in lab review 

checklist. 

Method blank. One per preparation batch. No analytes detected ≥ 1⁄2 MQL; 

no common lab contaminants 

(e.g. phthalates) detected ≥MQL 

or .> 5% of regulatory limit or 

>5% of target analyte detected in 

a sample. 

Correct problem, then reanalyze method blank and all 

samples processed with the 

contaminated blank. 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.10 - Calibration and QC Procedures for Method SW8270D & EPA 625 - Houston Facility 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

LCS for all analytes. One LCS per preparation 

batch. 

QC acceptance criteria, 

Table G.10 & G.14 for 8270 ; 

Table G.11 & G.14 for 625 

Correct problem, then reanalyze the LCS and all 

samples in the affected 

preparation batch. 

MS/MSD. One MS/MSD per every 

20 project samples per 

matrix. 

QC advisory criteria, 

Table G.10 for 8270D 

Table G.11 for 625 

Describe in Laboratory Review 

Checklist. For matrix 

evaluation. If MS results are 

outside LCS limits, evaluate if 

source of difference is due to 

matrix effect or lab error. 

Surrogate spike. All field samples and QC 

samples. 

QC acceptance criteria, 

Table G.10 for 8270D 

Table G.11 for 625 

Method 8000C, Section 9.6 

Requirements. Describe in 

Laboratory Review Checklist. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS 

analyses. 

Once per analyst. QC acceptance criteria, 

Table G.10 for 8270D and 

Table G.11 for 625 

Recalculate results; locate and 

fix problem with system and 

then rerun demonstration for 

those analytes that did not meet 

criteria. 

MDL/LOD study. MDL once annually. Detection limits established 

should ≤ 1/3 the LOQ in 

Table F.10 for 8270D and 

Table F.11 for EPA 625 

None. 

Table E.11 - Summary of Calibration and QC Procedures for Method EPA 608 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

Five-point initial 

calibrations for pesticides 

and separate PCB 

1016/1260 mix. 

Initial calibration prior to 

sample analysis. 

Calibration Factors – mean RSD 

for all analytes <10% or 

Linear – least squares regression 

R > 0.995. 

Correct problem then repeat 

initial calibration. 

Second-source calibration 

verification for pesticides 

and PCB 1016/1260 mix. 

Once per five-point initial 

calibration. 

Mix within ±15% of expected 

value. 

Correct problem then repeat 

initial calibration. 

Calibration verification 

(CCV) for pesticides and 

PCB 1016/1260 mix. 

After every 20 samples and 

at the end of the analysis 

sequence. 

All analytes within ±15% of 

expected value. 

Correct problem then repeat CCV 

(or ICAL) and reanalyze all 

samples since last successful 

CCV. 

Demonstrate ability to 

generate acceptable 

accuracy and precision 

using four replicate LCS. 

Once per analyst. QC acceptance criteria, 

Tables G.6 & G7. 

Recalculate results; locate and fix 

problem with system and then 

rerun demonstration for those 

analytes that did not meet criteria. 

Method blank. One per prep batch. No analytes detected 

> 1⁄2 LOQ or .> 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem then reprep and 

analyze method blank and all 

samples processed with the 

contaminated blank. 

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HS-QA Plan-Rev08.0 -Appendix C

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 Page E16 of 18 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.11 - Summary of Calibration and QC Procedures for Method EPA 608 

QC Check Minimum 

Frequency

Acceptance 

Criteria

Corrective 

Action

LCS (for pesticides and 

separate 1016/1260 mix). 

One LCS per prep batch. QC acceptance criteria, 

Table G.6 & G 7 

Correct problem then reprep and 

analyze the LCS and all samples 

in the affected prep batch. 

Surrogate spike. Every sample, spiked 

sample, standard, and 

method blank. 

QC acceptance criteria, 

Table G. 6 & G.7 

Confirm failure if necessary. If 

chromatography indicates matrix 

cause, re-analysis may not be 

necessary. Describe in Lab Data 

Review Checklist. 

MS/MSD (1016/1260 

mix). 

One MS/MSD per every 20 

project samples per matrix. 

QC acceptance criteria, 

Table G.6 & G.7 

Describe in Laboratory Review 

Checklist. 

LOD.MDL study. Once per 12 month period. Detection limits established 

shall be ≤ 1/2 LOQs in table F.6 

& F.7. 

None. 

Table E.12- Calibration and QC Procedures for Explosives SW8330A – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Five-point initial 

calibration for all analytes. 

Initial calibration prior to 

sample analysis. 

Linear – mean RSD for all 

analytes <20%; or 

Linear – 1sf order fit, R > 

0.995; or Non-linear – COD 

> 0.99 (6 points required for 

2nd order). 

Correct problem then repeat 

initial calibration. 

Second-source calibration 

verification (ICV) 

Once per five-point initial 

calibration. 

All analytes within ±25% of 

expected value (±30% for 

Tetryl). 

Correct problem then repeat 

initial calibration. 

Continuing Calibration 

verification (CCV). 

After every 20 samples and 

at the end of the analysis 

sequence. 

All analytes within ±20% of 

expected value. 

Correct problem then repeat 

CCV (or ICAL) and reanalyze 

all samples since last 

successful CCV. 

Retention Time (RT) 

Window verification 

At instrument setup and 

after major maintenance 

(e.g. column change) 

Verify RT widow with 72 

hour study (use CCV data 

from three days) 

N/A 

Method blank. One per preparation batch. No analytes detected 

> 1⁄2 MQL or > 5% of 

regulatory limit or >5% of 

target analyte detected in a 

sample. 

Correct problem, then reprepare and analyze method 

blank and all samples 

processed with the 

contaminated blank. 

LCS LCS for all analytes. 

One LCS per preparation 

batch. 

QC acceptance criteria, 

Table G.12. 

LCSD RPD < 30% 

Correct problem, then reprepare and analyze LCS and 

all samples processed with the 

LCS. 

MS/MSD One MS/MSD per 

preparation batch (20 or 

less samples per matrix). 

QC acceptance criteria, 

Table G.12. MS/MSD RPD 

<50% for waters and soils. 

Describe in Laboratory 

Review Checklist. 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table E.12- Calibration and QC Procedures for Explosives SW8330A – Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Detection 2nd Column 

Confirmations 

Each detection Results agree within 40 %. Evaluate any > 40 % for coelutions 

Analyst demonstrate 

ability to generate 

acceptable accuracy / 

precision - four LCS. 

Once per analyst. QC acceptance criteria, 

Table G.12 

Recalculate results; locate and 

fix problem with system and 

then rerun demonstration. 

LOD/MDL study. Once per 12 month period. MDLs established shall be <

1/3 the LOQ in Tables F.12 

None. 

Table E.13.1 Calibration and QC Procedures for SW 8315A & SW8316 - Houston Facility

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Five-point initial 

calibration for all 

analytes. 

Initial calibration prior to 

sample analysis. 

CF – mean RSD for all analytes 

<20%; or 

Linear – 1sf ordert, R > 0.995; or 

Non-linear – COD > 0.99 (6 

points required for 2nd order). 

Correct problem then repeat 

initial calibration. 

Second-source 

calibration verification 

(ICV) 

Once per five-point 

initial calibration. 

All analytes within ±20% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Continuing Calibration 

verification (CCV). 

After every 20 samples 

and at the end of the 

analysis sequence. 

All analytes within ±20% of 

expected value. 

Correct problem then repeat 

CCV (or ICAL) and 

reanalyze all samples since 

last successful CCV. 

Retention Time (RT) 

Window verification 

At instrument setup and 

after major maintenance 

(e.g. column change) 

Verify RT widow with 72 hour 

study (use CCV data from three 

days) 

N/A 

Method blank. One per preparation 

batch. 

No analytes detected 

> 1⁄2 MQL or > 5% of regulatory 

limit or >5% of target analyte 

detected in a sample. 

Correct problem, then reprepare and analyze method 

blank and all samples 

processed with the 

contaminated blank. 

LCS LCS for all analytes. 

One LCS per preparation 

batch. 

QC acceptance criteria, 

Table G.13. 

LCSD RPD < 20% (waters) 

LCSD RPD < 30% (soil) 

Correct problem, then reprepare and analyze LCS 

and all samples processed 

with the LCS. 

MS/MSD One MS/MSD per 

preparation batch (20 or 

less samples per matrix). 

QC acceptance criteria, 

Table G.13. MS/MSD/RPD 

Describe in Laboratory 

Review Checklist. 

Analyst demonstrate 

ability to generate 

acceptable accuracy / 

precision - four LCS. 

Once per analyst. QC acceptance criteria, Table G.13 Recalculate results; locate 

and fix problem with system 

and then rerun 

demonstration. 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page E18 of 18 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table E14 - Summary of Calibration and QC Procedures for RSK – 175

QC Check Minimum 

Frequency 

Acceptance 

Criteria 

Corrective 

Action

Minimum of five-points 

for initial calibration for 

all analytes. 

Initial calibration (ICAL) 

prior to sample analysis. 

Linear – mean RSD for all 

analytes <25%; or 

Linear – least squares 

regression, R > 0.995; or Nonlinear – COD > 0.99 (6 points 

shall be used for second order). 

Correct problem then repeat 

initial calibration. 

Second-source (ICV) 

calibration verification. 

Once per each initial 

calibration curve. 

All analytes within ±25% of 

expected value. 

Correct problem then repeat 

initial calibration. 

Calibration verification. Daily, before sample 

analysis, after every 

20 samples and at the end 

of the analysis sequence. 

All analytes within ±25% of 

expected value. 

Correct problem, then repeat 

ICAL verification and 

reanalyze all samples since last 

successful calibration 

verification. 

Method blank. One per preparation 

batch. 

Any analytes detected must be 

< 1/2 LOQ. 

Correct problem, then reprepare and analyze method 

blank and all affected samples 

processed with the 

contaminated blank. 

LCS/LCSD LCS for all analytes, one 

LCS per preparation 

batch. 

Recovery: ±25% of expected 

value; LCSD RPD <30%. 

Correct problem then reanalyze the LCS and all 

samples in the affected batch. 

MS/MSD One MS/MSD per every 

20 project samples. 

Recovery: ±30% of expected 

value; MSD RPD <30%. 

Describe in Laboratory Review 

Checklist. 

Duplicate (for sample, or 

as MSD, or as LCSD). 

One duplicate per every 

20-project samples. 

Duplicate RPD <30%. Describe in Laboratory Review 

Checklist. 

Analyst demonstrate 

ability to generate 

acceptable accuracy and 

precision using four 

replicate LCS. 

Once per analyst initially 

and annually thereafter. 

QC acceptance criteria for LCS 

Recovery : ±25%, RPD <30%. 

Recalculate results; locate and 

fix problem with system and 

then rerun demonstration and 

meet criteria. 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F1 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.1 - Wet Chemistry LODs and LOQs – Houston Facility 

Analyte / method- water matrix 

* NELAC accredited 

LOD 

mg/L 

LOQ 

mg/L 

Analyte / method– solid/soil matrix 

* NELAC accredited 

LOD 

mg/Kg

LOQ 

mg/Kg

 pH / E150.1*/ SW9040C * (standard units) - ± 0.05 pH / SW9045D * (standard units) - ± 0.05

 pH SM4500H+ B * (standard units) - ± 0.05 

Specific Conductance (umhos/cm) / EPA 120.0 / 

SW 9050A* 

1.0 1.0 Specific Conductance / 120.0 / 9050* 0.5 1.0 

Total Dissolved Solids EPA160.2* /SM2540C* 5 10 

Total Suspended Solids - EPA 160.1*/ SM 

2540D* 

2 2 

Total Solids – EPA 160.3* / SM2540B* 5 10 

Volatile Solids - SM 2540 G 5 10 

Percent Moisture (as % weight) - 0.01 Percent Moisture (as % Weight) - 0.01 

Total Alkalinity / SM 2320B / EPA 310.1* 2 5 

Ammonia as N – SM4500 NH3-B-F* 0.008 0.025 

Ammonia as N – SM4500 NH3-D */ E350.3* 0.2 0.2 Ammonia as N – SM4500 NH3-D 10 10 

Fluoride – SM4500 F B & C / EPA 340.2 0.1 0.1 

Fluoride – SW 9214 * 0.1 0.1 

Chrome VI by SW 7196* / SM3500 Cr B 0.004 0.01 Chrome VI by SW 7196* / SW3060A (prep) 0.7 2 

Ferrous Iron by SM 3500-Fe D 0.02 0.05 

Chloride by EPA 300 */ SW9056A* 0.01 0.5 Chloride by EPA 300* / SW9056A* 0.1 5 

Fluoride by EPA 300* / SW9056A* 0.01 0.1 Fluoride by EPA 300 */ SW9056A* 0.1 1 

Sulfate by EPA 300* / SW9056A* 0.01 0.5 Sulfate by EPA 300* / SW9056A* 0.1 5 

o-Phosphorous (P) by EPA 300* / SW9056A* 0.03 0.1 o-Phosphorous (P) - EPA300*/SW9056A* 0.3 1 

Nitrate as N - E300 */ SW9056A* 0.03 0.1 Nitrate as N - E300* / SW9056A* 0.3 1 

Nitrite as N – E300* / SW9056A* 0.03 0.1 Nitrite as N – E300* / SW9056A* 0.3 1 

Bromide – E300* / SW9056A* 0.03 0.1 Bromide – E300* / SW9056A* 0.3 1 

Nitrite as N - SM4500-NO2 B * / E354.1* 0.003 0.01 

Total Kjeldahl Nitrogen, E351.2 / SM4500 

NH3 D 

1.0 1.0 

o-Phosphorous (as P) E365.3* / SM4500 P * 0.006 0.025 

Total Phosphorous (as P) E365.3* / SM4500 P* 0.02 0.05 

Total Cyanide – SW 9010C / 9014 * / E335.3* 0.004 0.02 Total Cyanide - SW9010C / 9014* 0.6 2.0 

Total Cyanide – SM 4500 CN C* & E * 0.004 0.02 

Cyanide, Weak Acid Dissociable– SM4500CN I 0.005 0.02 

Sulfide by SM4500-S2- F * / EPA 376.1* 0.5 1 

Sulfite by SM4500-S03

2- B * (Iodometric) 1.2 5 

Total Organic Carbon – SM5310C / E415.1* / 

SW 9060A* 

0.1 0.5 Total Organic Carbon – 9060A Mod * 

(as %Wt - dry) 

0.02 % 0.06 %

 Total Organic Carbon –Walkley-Black * 

(as %Wt - dry) 

0.02 % 0.02 %

Chemical Oxygen Demand – Hach 8000 * 4 15 

BOD, 5-day – SM 5210 B* / E405.1 * 2 2 

Carbonaceous BOD – SM 5210 B * / E405.1 2 2 

Phenolics, Total Recoverable – E420.1* / 

SW9065* 

0.02 0.05 Phenolics, Total Recoverable – SW9065* 1 2.5 

Oil and Grease, 1664 * 0.6 2 O & G (HEM), SW9071B 33 33 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F2 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.1 - Wet Chemistry LODs and LOQs – Houston Facility 

Analyte / method- water matrix 

* NELAC accredited 

LOD 

mg/L 

LOQ 

mg/L 

Analyte / method– solid/soil matrix 

* NELAC accredited 

LOD 

mg/Kg

LOQ 

mg/Kg

Chlorine, Total Residual - SSM4500CL F * 0.1 0.1 

Hardness (As CaCO3) SM2340 B * 2 2 True Total Barium (LaDNR) 50 50 

Silica, Dissolved (as SiO2) - SM4500-SiD * 0.02 0.1 

Color, Pt-Co units - SM2120B / EPA 110.2 5 5 

Turbidity – EPA 180.1 0.1 0.1 

Table F.2.1 - Metals by ICP/MS – SW 6020A – EPA 200.8 - Houston Facility 

LODs and LOQs - Houston Facility 

Analyte – Water Matrix 

* NELAC accredited 

Isotope LOD 

μg/L 

LOQ 

μg/L 

Analyte - Soil Matrix 

* NELAC accredited 

Isotope LOD 

mg/Kg 

MQL 

mg/Kg 

Aluminum* 27 3.7 10 Aluminum* 27 0.2 1 

Antimony* 121 0.5 5 Antimony* 121 0.25 0.5 

Arsenic* 75 0.9 5 Arsenic* 75 0.06 0.5 

Barium* 135 0.7 5 Barium* 135 0.08 0.5 

Beryllium* 9 0.3 2 Beryllium* 9 0.05 0.5 

Boron* 11 15 20 Boron* 11 1.5 2.5 

Cadmium* 111 0.6 2 Cadmium* 111 0.04 0.5 

Calcium* 44 50 500 Calcium* 44 10 50 

Chromium* 53 0.6 5 Chromium* 53 0.05 0.5 

Cobalt* 59 0.5 5 Cobalt* 59 0.17 0.5 

Copper* 65 0.5 5 Copper* 65 0.14 0.5 

Iron* 56 36 200 Iron* 56 4 50 

Potassium* 39 100 500 Potassium* 39 3.6 50 

Lead* 207 0.4 5 Lead* 207 0.05 0.5 

Magnesium* 24 39 500 Magnesium* 24 3.3 50 

Manganese* 55 0.8 5 Manganese* 55 0.07 0.5 

Molybdenum* 95 0.6 5 Molybdenum* 95 0.05 0.5 

Sodium* 23 100 200 Sodium* 23 4 50 

Nickel* 60 1.4 5 Nickel* 60 0.06 0.5 

Selenium* 82 2.5 5 Selenium* 82 0.25 0.5 

Tin* 118 0.6 5 Tin* 118 0.14 1.0 

Strontium* 88 0.5 5 Strontium* 88 0.06 0.5 

Silver* 109 0.7 5 Silver* 109 0.04 0.5 

Titanium* 47 1.2 5 Titanium* 47 0.13 1.0 

Thallium* 203 0.8 2 Thallium* 203 0.07 0.5 

Vanadium* 51 0.7 5 Vanadium* 51 0.07 0.5 

Zinc* 66 2.5 5 Zinc* 66 0.25 0.5 

Table F.2.2 - Mercury by Cold Vapor - LODs and LOQs - Houston Facility 

Analyte / method- water matrix 

* NELAC accredited 

EPA 254.1 – SW7470A 

LOD 

μg/L 

LOQ 

μg/L 

Analyte / method– solid/soil matrix 

* NELAC accredited 

SW7471B 

LOD 

μg/Kg 

LOQ 

μg/Kg 

Mercury, Total* 0.042 0.2 Mercury, Total* 1.4 13.3 

44 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F3 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.3.1 - TPH Methods - Current LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited 

LOD 

mg/L 

LOQ 

mg/L 

Analyte - solid/soil matrix 

* NELAC accredited 

LOD 

mg/Kg 

LOQ 

mg/Kg 

Total Petroleum Hydrocarbon / TX 1005 * 0.2 0.5 Total Petroleum Hydrocarbon / TX 1005* 16 50 

nC6-nC12 / TX 1005 * 0.2 0.5 nC6-nC12 / TX 1005 * 16 50 

>nC12 to nC28 / TX 1005* 0.2 0.5 >nC12 to nC28 / TX 1005* 16 50 

>nC28 to nC35 / TX 1005* 0.2 0.5 >nC28 to nC35 / TX 1005* 16 50 

TX 1006 – Fractionated Hydrocarbons - - TX 1006 - Fractionated Hydrocarbons - - 

Aliphatics nC6 / TX 1006 - 1 Aliphatics nC6 - 10 

Aliphatics >nC6 to nC8 - 1 Aliphatics >nC6 to nC8 - 10 

Aliphatics >nC8 to nC10 - 1 Aliphatics >nC8 to nC10 - 10 

Aliphatics >nC10 to nC12 - 1 Aliphatics >nC10 to nC12 - 10 

Aliphatics >nC12 to nC16 - 1 Aliphatics >nC12 to nC16 - 10 

Aliphatics >nC16 to nC21 - 1 Aliphatics >nC16 to nC21 - 10 

Aliphatics >nC21 to nC35 - 1 Aliphatics >nC21 to nC35 - 10 

Total Aliphatic Fraction - 5 Total Aliphatic Fraction - 50 

Aromatics >nC7 to nC8 - 1 Aromatics >nC7 to nC8 - 10 

Aromatics >nC8 to nC10 - 1 Aromatics >nC8 to nC10 - 10 

Aromatics >nC10 to nC12 - 1 Aromatics >nC10 to nC12 - 10 

Aromatics >nC12 to nC16 - 1 Aromatics >nC12 to nC16 - 10 

Aromatics >nC16 to nC21 - 1 Aromatics >nC16 to nC21 - 10 

Aromatics >nC21 to nC35 - 1 Aromatics >nC21 to nC35 - 10 

Total Aromatic Fraction - 5 Total Aromatic Fraction - 50 

8015C– Gasoline Range (P&T - C6-C10)* 0.02 0.05 8015C Gasoline Range (P &T C6-C10)* 0.02 0.05 

8015C_ Diesel Range (>C10-C28)* 0.02 0.05 8015C - Diesel Range (>C10-C28)* 0.5 1.7 

8015C – Oil Range (>C28) 0.02 0.1 8015C - Oil Range (>C28) 0.5 3.4 

Table F.3.2 - Non-halogenated Organics by 8015D - LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited 

LOD 

mg/L 

LOQ 

mg/L 

Analyte - solid/soil matrix 

* NELAC accredited 

LOD 

mg/Kg 

LOQ 

mg/Kg 

Ethylene Glycol* 1 1 Ethylene Glycol* 1 1 

1-Propanol * 1 1 1-Propanol * 1 1 

2-Propanol * 1 1 2-Propanol * 1 1 

Isobutanol * 1 1 Isobutanol * 1 1 

Propylene glycol * 10 10 Propylene glycol * 10 10 

Ethanol * 1 1 Ethanol * 1 1 

Methanol* 1 1 Methanol* 1 1 

Table F.3.3 - Dissolved Gases by RSK-175 * - LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Ethane * 0.2 1 Ethene * 0.2 1 

Methane * 0.1 0.5 Isobutane* 1 1 

Propane* 1 1 n-Butane* 1 1 

Table F.4 - SW8011* – EPA 504.1 LODs and LOQs – Houston Facility 

Analyte – water matrix LOD LOQ Analyte – water matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/L μg/L 

1,2-Dibromoethane (EDB)* 0.01 0.02 1,2,3-Trichloropropane (1,2,3-TCP)* 0.01 0.02 

45 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F4 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.4 - SW8011* – EPA 504.1 LODs and LOQs – Houston Facility 

Analyte – water matrix LOD LOQ Analyte – water matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/L μg/L 

1,2-Dibromo-3-chloropropane (DBCP)* 0.01 0.02 

Table F.5 - BTEX by 8021 - LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

Benzene* 0.2 1 Benzene* 0.2 1 

Ethylbenzene * 0.3 1 Ethylbenzene* 0.3 1 

Toluene* 0.4 1 Toluene* 0.4 1 

m,p-Xylene* 0.5 2 m,p-Xylene* 0.7 2 

p-Xylene* 0.5 1 o-Xylene* 0.7 1 

Xylenes, Total* 0.5 3 Xylenes, Total* 0.7 3 

Methyl tert-butyl ether* 1.3 5 Methyl tert-butyl ether* 1.3 5 

Table F.6 - SW 8081B LODs and LOQs – Houston Facility 

Analyte – water matrix 

* NELAC accredited

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited

LOD 

μg/Kg 

LOQ 

μg/Kg 

4,4'-DDD* 0.01 0.1 4,4'-DDD* 0.5 3.3 

4,4'-DDE* 0.01 0.1 4,4'-DDE* 0.5 3.3 

4,4'-DDT* 0.01 0.1 4,4'-DDT* 0.5 3.3 

Aldrin* 0.01 0.05 Aldrin * 0.3 1.7 

Alpha-BHC* 0.01 0.05 Alpha-BHC* 0.3 1.7 

Beta-BHC* 0.01 0.05 Beta-BHC* 0.3 1.7 

Delta-BHC* 0.01 0.05 Delta-BHC* 0.2 1.7 

Chlordane, Technical* 0.12 0.5 Chlordane, Technical* 1.2 17 

Alpha-Chlordane * 0.01 0.05 Alpha-Chlordane* 0.2 1.7 

Gamma-Chlordane* 0.01 0.05 Gamma-Chlordane* 0.2 1.7 

Dieldrin* 0.01 0.1 Dieldrin* 0.5 3.3 

Endosulfan I* 0.01 0.05 Endosulfan I* 0.3 1.7 

Endosulfan II* 0.01 0.1 Endosulfan II* 0.6 3.3 

Endosulfan sulfate* 0.01 0.1 Endosulfan sulfate* 0.6 3.3 

Endrin* 0.01 0.1 Endrin* 0.6 3.3 

Endrin aldehyde* 0.01 0.1 Endrin aldehyde* 0.6 3.3 

Endrin ketone* 0.01 0.1 Endrin ketone* 0.6 3.3 

Gamma-BHC (Lindane)* 0.01 0.05 gamma-BHC (Lindane)* 0.2 1.7 

Heptachlor* 0.01 0.05 Heptachlor * 0.3 1.7 

Heptachlor epoxide* 0.01 0.05 Heptachlor epoxide* 0.3 1.7 

Methoxychlor* 0.09 0.5 Methoxychlor* 3.4 17 

Toxaphene* 0.13 0.5 Toxaphene* 3.8 17 

Hexachlorobenzene * 0.01 0.05 Hexachlorobenzene 0.2 1.7 

Mirex * 0.012 0.05 Mirex * 0.2 1.7 

Table F.7 - SW 8082A - PCBs - LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited

LOD 

μg/Kg 

LOQ 

μg/Kg 

46 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F5 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.7 - SW 8082A - PCBs - LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited

LOD 

μg/Kg 

LOQ 

μg/Kg 

Aroclor 1016* 0.2 0.5 Aroclor 1016* 2.4 17 

Aroclor 1221* 0.2 0.5 Aroclor 1221* 2.4 17 

Aroclor 1232* 0.2 0.5 Aroclor 1232* 2.4 17 

Aroclor 1242* 0.2 0.5 Aroclor 1242* 2.4 17 

Aroclor 1248* 0.2 0.5 Aroclor 1248* 2.4 17 

Aroclor 1254* 0.2 0.5 Aroclor 1254* 2.4 17 

Aroclor 1260* 0.2 0.5 Aroclor 1260* 1.8 17 

Table F.8 - SW 8151A LODs and LOQs - Houston Facility 

Analyte – water matrix 

* NELAC accredited

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited

LOD 

μg/Kg 

LOQ 

μg/Kg 

2,4,5-T* 0.05 0.1 2,4,5-T* 0.6 3.3 

2,4,5-TP (Silvex)* 0.02 0.1 2,4,5-TP (Silvex)* 0.5 3.3 

2,4-D* 0.08 0.2 2,4-D* 1.0 6.6 

2,4-DB* 0.07 0.2 2,4-DB* 1.7 6.6 

Dalapon* 0.05 0.1 Dalapon* 1.6 3.3 

Dicamba* 0.05 0.1 Dicamba* 1.5 3.3 

Dichlorprop* 0.07 0.2 Dichlorprop* 3.0 6.6 

Dinoseb* 0.03 0.1 Dinoseb* 0.5 3.3 

MCPA* 3 20 MCPA* 150 333 

MCPP* 7 20 MCPP* 140 333 

Table F.9.1 – SW8260C – Current LODs and LOQs, 5 ml purge – Houston Facility

Analyte – water matrix 

5 ml purge volume 

* NELAC Accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

based on 5 g dry weight sample 

* NELAC Accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

1,1,1,2-Tetrachloroethane * 0.5 5 1,1,1,2-Tetrachloroethane * 0.5 5 

1,1,1-Trichloroethane * 0.5 5 1,1,1-Trichloroethane * 0.5 5 

1,1,2,2-Tetrachloroethane * 0.5 5 1,1,2,2-Tetrachloroethane * 0.5 5 

1,1,2-Trichlor-1,2,2-trifluoroethane * 0.6 5 1,1,2-Trichlor-1,2,2-trifluoroethane * 0.5 5 

1,1,2-Trichloroethane * 0.5 5 1,1,2-Trichloroethane * 0.5 5 

1,1-Dichloroethane * 0.5 5 1,1-Dichloroethane * 0.5 5 

1,1-Dichloroethene * 0.5 5 1,1-Dichloroethene * 0.5 5 

1,1-Dichloropropene * 0.5 5 1,1-Dichloropropene * 0.5 5 

1,2,3-Trichlorobenzene * 0.5 5 1,2,3-Trichlorobenzene * 0.5 5 

1,2,3-Trichloropropane * 0.7 5 1,2,3-Trichloropropane * 0.5 5 

1,2,3-Trimethylbenzene 0.5 5 1,2,3-Trimethylbenzene 0.5 5 

1,2,4-Trichlorobenzene * 0.5 5 1,2,4-Trichlorobenzene * 0.6 5 

1,2,4-Trimethylbenzene * 0.5 5 1,2,4-Trimethylbenzene * 0.5 5 

1,2-Dibromo-3-chloropropane * 1 5 1,2-Dibromo-3-chloropropane * 0.9 5 

1,2-Dibromoethane * 0.5 5 1,2-Dibromoethane * 0.5 5 

1,2-Dichlorobenzene * 0.5 5 1,2-Dichlorobenzene * 0.5 5 

1,2-Dichloroethane * 0.5 5 1,2-Dichloroethane * 0.5 5 

1,2-Dichloropropane * 0.5 5 1,2-Dichloropropane * 0.5 5 

1,3,5-Trimethylbenzene * 0.5 5 1,3,5-Trimethylbenzene * 0.5 5 

1,3-Butadiene 0.5 5 1,3-Butadiene 5 5 

47 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F6 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.9.1 – SW8260C – Current LODs and LOQs, 5 ml purge – Houston Facility

Analyte – water matrix 

5 ml purge volume 

* NELAC Accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

based on 5 g dry weight sample 

* NELAC Accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

1,3-Dichlorobenzene * 0.5 5 1,3-Dichlorobenzene * 0.5 5 

1,3-Dichloropropane * 0.5 5 1,3-Dichloropropane * 0.5 5 

1,4-Dichlorobenzene * 0.5 5 1,4-Dichlorobenzene * 0.5 5 

1,4-Dioxane * 50 100 1,4-Dioxane * 20 100 

1-Chlorohexane * 0.8 5 1-Chlorohexane * 0.6 5 

1-Propanol * 100 100 1-Propanol * 20 100 

2,2-Dichloropropane * 0.5 5 2,2-Dichloropropane * 0.5 5 

2-Butanone * 1 10 2-Butanone * 1.4 10 

2-Chloro-1,3-butadiene * 1.1 5 2-Chloro-1,3-butadiene * 5 5 

2-Chloroethyl vinyl ether * 1 10 2-Chloroethyl vinyl ether * 1 5 

2-Chlorotoluene * 0.5 5 2-Chlorotoluene * 0.5 5 

2-Hexanone * 1 10 2-Hexanone * 1 10 

2-Methylnaphthalene * 5 5 2-Methylnaphthalene * 0.7 5 

2-Pentanone * 1 10 2-Pentanone * 10 10 

4-Chlorotoluene * 0.5 5 4-Chlorotoluene * 0.5 5 

4-Isopropyltoluene * 0.5 5 4-Isopropyltoluene * 0.5 5 

4-Methyl-2-pentanone * 1 10 4-Methyl-2-pentanone * 1 10 

Acetaldehyde 3.2 10 Acetaldehyde 7 10 

Acetone * 1 10 Acetone * 2 20 

Acetonitrile * 7 50 Acetonitrile * 10 50 

Acrolein * 2 20 Acrolein * 2 20 

Acrylonitrile * 1 10 Acrylonitrile * 1 20 

Allyl alcohol * 100 100 Allyl alcohol 100 100 

Allyl Chloride * 1 10 Allyl Chloride * 1 10 

Amyl Alcohol 10 100 Amyl Alcohol 10 100 

Benzene * 0.5 5 Benzene * 0.5 5 

Benzyl Chloride * 0.5 5 Benzyl Chloride * 0.5 5 

Bromobenzene * 0.5 5 Bromobenzene * 0.5 5 

Bromochloromethane * 0.5 5 Bromochloromethane * 0.5 5 

Bromodichloromethane * 0.5 5 Bromodichloromethane * 0.5 5 

Bromoform * 0.5 5 Bromoform * 0.5 5 

Bromomethane * 0.9 5 Bromomethane * 1 10 

Butyl methacrylate 5 5 Butyl methacrylate 0.5 5 

Carbon disulfide * 1 10 Carbon disulfide * 1 10 

Carbon tetrachloride * 0.5 5 Carbon tetrachloride * 0.5 5 

Chlorobenzene * 0.5 5 Chlorobenzene * 0.5 5 

Chloroethane * 0.5 5 Chloroethane * 1 10 

Chloroform * 0.5 5 Chloroform * 0.5 5 

Chloromethane * 0.5 5 Chloromethane * 1 10 

cis-1,2-Dichloroethene * 0.5 5 cis-1,2-Dichloroethene * 0.5 5 

cis-1,3-Dichloropropene * 0.5 5 cis-1,3-Dichloropropene * 0.5 5 

Cyclohexane 0.6 5 Cyclohexane 5 5 

Dibromochloromethane * 0.5 5 Dibromochloromethane * 0.5 5 

Dibromomethane * 0.5 5 Dibromomethane * 0.5 5 

Dichlorodifluoromethane * 0.5 5 Dichlorodifluoromethane * 0.5 5 

Diethyl Ether * 1.2 5 Diethyl Ether * 0.5 5 

48 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F7 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.9.1 – SW8260C – Current LODs and LOQs, 5 ml purge – Houston Facility

Analyte – water matrix 

5 ml purge volume 

* NELAC Accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

based on 5 g dry weight sample 

* NELAC Accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

Diisopropyl ether * 0.5 5 Diisopropyl ether 0.5 10 

Epichlorohydrin * 2.5 20 Epichlorohydrin * 1 20 

Ethanol * 100 100 Ethanol * 2.4 100 

Ethyl acetate * 0.5 5 Ethyl acetate * 100 10 

Ethyl acrylate 0.5 5 Ethyl acrylate 10 5 

Ethyl Methacrylate * 1.3 5 Ethyl Methacrylate * 0.6 5 

Ethyl tert-Butyl Ether (ETBE) * 5 5 Ethyl tert-Butyl Ether (ETBE) 0.5 5 

Ethylbenzene * 0.5 5 Ethylbenzene * 0.5 5 

Ethylene oxide 2.3 10 Ethylene oxide * 3.5 10 

Hexachlorobutadiene * 0.8 5 Hexachlorobutadiene * 1 5 

Iodomethane * 1.1 10 Iodomethane * 1 10 

Isobutyl alcohol * 26 100 Isobutyl alcohol * 20 100 

Isopropyl alcohol * 21 100 Isopropyl alcohol * 14 100 

Isopropylbenzene * 0.5 5 Isopropylbenzene * 0.5 5 

M,p-Xylene * 1 10 m,p-Xylene * 1 10 

Methacrylonitrile * 0.5 5 Methacrylonitrile * 1.7 5 

Methyl acetate * 0.5 5 Methyl acetate * 0.5 5 

Methyl acrylate * 5 5 Methyl acrylate * 0.5 5 

Methyl methacrylate 0.5 5 Methyl methacrylate 0.5 5 

Methyl tert-butyl ether * 0.5 5 Methyl tert-butyl ether 0.5 5 

Methylcyclohexane * 0.8 5 Methylcyclohexane * 0.5 5 

Methylene chloride * 0.5 10 Methylene chloride * 1 10 

Naphthalene * 0.5 5 Naphthalene * 5 5 

n-Butyl acetate 0.7 5 n-Butyl acetate 0.5 5 

n-Butyl acrylate 0.5 5 n-Butyl acrylate 14 5 

n-Butyl alcohol * 100 100 n-Butyl alcohol 0.5 100 

n-Butylbenzene * 0.6 5 n-Butylbenzene * 0.5 5 

n-Hexane 0.8 5 n-Hexane 0.5 5 

n-Propylbenzene * 0.5 5 n-Propylbenzene * 5 5 

o-Xylene * 0.5 5 o-Xylene * 5 5 

Pentachloroethane * 5 5 Pentachloroethane * 3.5 5 

Propionitrile * 9 50 Propionitrile * 0.5 50 

Propylene oxide 1 10 Propylene oxide 0.5 10 

sec-Butylbenzene * 0.5 5 Sec-Butylbenzene * 0.5 5 

Styrene * 0.5 5 Styrene * 10 5 

Tert-Amyl Methyl Ether * 5 5 Tert-Amyl Methyl Ether 0.5 5 

Tert-Butyl Alcohol * 13 100 Tert-Butyl Alcohol * 0.5 100 

tert-Butylbenzene * 0.6 5 Tert-Butylbenzene * 0.6 5 

Tetrachloroethene * 0.6 5 Tetrachloroethene * 0.7 5 

Tetrahydrofuran 0.6 5 Tetrahydrofuran 0.5 5 

Toluene * 0.5 5 Toluene * 0.5 5 

trans-1,2-Dichloroethene * 0.5 5 Trans-1,2-Dichloroethene * 0.5 5 

trans-1,3-Dichloropropene * 0.5 5 Trans-1,3-Dichloropropene * 5 5 

trans-1,4-Dichloro-2-butene * 0.8 5 Trans-1,4-Dichloro-2-butene * 0.5 5 

Trichloroethene * 0.5 5 Trichloroethene * 0.5 5 

Trichlorofluoromethane * 0.5 5 Trichlorofluoromethane * 1 5 

49 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F8 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.9.1 – SW8260C – Current LODs and LOQs, 5 ml purge – Houston Facility

Analyte – water matrix 

5 ml purge volume 

* NELAC Accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

based on 5 g dry weight sample 

* NELAC Accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

Vinyl acetate * 1 10 Vinyl acetate * 0.5 10 

Vinyl chloride * 0.5 2 Vinyl chloride * 1 2 

Xylenes, Total * 1 15 Xylenes, Total * 1.5 15 

Table F.9.2 - SW8260C Low Level Waters - Houston Facility

Analyte - water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

1,1,1,2-Tetrachloroethane* 0.2 1 Carbon tetrachloride* 0.2 1 

1,1,1-Trichloroethane* 0.1 1 Chlorobenzene* 0.1 1 

1,1,2,2-Tetrachloroethane* 0.2 1 Chloroethane* 0.3 1 

1,1,2-Trichlor-1,2,2-trifluoroethane * 0.1 1 Chloroform* 0.1 1 

1,1,2-Trichloroethane* 0.1 1 Chloromethane* 0.2 1 

1,1-Dichloroethane* 0.2 1 cis-1,2-Dichloroethene 0.2 1 

1,1-Dichloroethene* 0.2 1 cis-1,3-Dichloropropene* 0.1 1 

1,1-Dichloropropene* 0.2 1 Cyclohexane 0.1 1 

1,2,3-Trichlorobenzene* 0.2 1 Dibromochloromethane* 0.1 1 

1,2,3-Trichloropropane 0.1 1 Dibromomethane* 0.2 1 

1,2,4-Trichlorobenzene* 0.1 1 Dichlorodifluoromethane* 0.5 1 

1,2,4-Trimethylbenzene* 0.1 1 Dicyclopentadiene 0.1 1 

1,2-Dibromo-3-chloropropane * 0.1 1 Ethyl acrylate 0.1 1 

1,2-Dibromoethane* 0.1 1 Ethylbenzene* 0.2 1 

1,2-Dichlorobenzene* 0.1 1 Ethyl methacrylate * 0.1 1 

1,2-Dichloroethane* 0.1 1 Hexachlorobutadiene* 0.4 1 

1,2-Dichloropropane* 0.1 1 Iodomethane* 0.4 2 

1,3,5-Trimethylbenzene* 0.1 1 Isopropylbenzene* 0.1 1 

1,3-Dichlorobenzene* 0.1 1 m,p-Xylene* 0.2 2 

1,3-Dichloropropane * 0.1 1 Methacrylonitrile * 0.2 2 

1,4-Dichlorobenzene* 0.1 1 Methyl acetate * 0.1 1 

1,4-Dioxane* 20 20 Methyl acrylate * 0.1 1 

1-Chlorohexane* 0.2 1 Methyl methacrylate * 0.1 1 

2,2-Dichloropropane* 0.1 1 Methyl tert-butyl ether* 0.2 1 

2-Butanone* 0.4 2 Methylcyclohexane * 0.2 1 

2-Chloro-1,3-butadiene 0.1 2 Methylene chloride* 0.1 2 

2-Chloroethyl vinyl ether* 0.2 2 n-Butylbenzene* 0.1 1 

2-Chlorotoluene* 0.2 1 n-Hexane 0.2 1 

2-Hexanone* 0.2 2 n-Propylbenzene* 0.1 1 

2-Methylnaphthalene 0.2 1 Naphthalene* 0.1 1 

4-Chlorotoluene* 0.1 1 o-Xylene* 0.1 1 

4-Isopropyltoluene* 0.1 1 Propylene oxide 0.9 2 

4-Methyl-2-pentanone* 0.2 2 sec-Butylbenzene* 0.1 1 

4-Vinyl-1-cyclohexene 0.1 1 Styrene* 0.1 1 

Acetone* 1 2 tert-Butylbenzene* 0.1 1 

Acetonitrile* 3.7 10 Tetrachloroethene* 0.3 1 

Acrolein* 0.5 2 Toluene* 0.1 1 

50 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F9 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.9.2 - SW8260C Low Level Waters - Houston Facility

Analyte - water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Acrylonitrile* 0.7 2 trans-1,2-Dichloroethene* 0.3 1 

Benzene* 0.1 1 trans-1,3-Dichloropropene* 0.1 1 

Bromobenzene* 0.1 1 Trans-1,4-Dichloro-2-butene 0.3 1 

Bromochloromethane* 0.2 1 Trichloroethene* 0.1 1 

Bromodichloromethane* 0.2 1 Trichlorofluoromethane* 0.2 1 

Bromoform* 0.3 2 Vinyl acetate* 0.7 1 

Bromomethane* 0.3 2 Vinyl chloride* 0.4 1 

Carbon disulfide* 0.2 1 Xylenes, Total * 0.3 3 

Table F.9.3 - EPA 624 - Houston Facility

Analyte - water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

1,1,1-Trichloroethane* 0.5 5 Chlorobenzene* 0.5 5 

1,1,2,2-Tetrachloroethane* 0.5 5 Chloroethane* 1 5 

1,1,2-Trichloroethane* 0.8 5 Chloroform* 0.5 5 

1,1-Dichloroethane* 0.5 5 Chloromethane* 1 5 

1,1-Dichloroethene* 0.8 5 cis-1,2-Dichloroethene * 0.6 5 

1,2-Dichlorobenzene* 0.5 5 cis-1,3-Dichloropropene* 0.5 5 

1,2-Dichloroethane* 0.5 5 Dibromochloromethane* 0.6 5 

1,2-Dichloropropane* 0.7 5 Ethylbenzene* 0.5 5 

1,3-Dichlorobenzene* 0.5 5 m,p-Xylene* 1 5 

1,4-Dichlorobenzene* 0.5 5 Methylene chloride* 1.4 5 

2-Butanone* 1 10 Methyl tert-butyl ether* 

2-Chloroethyl vinyl ether* 0.8 10 o-Xylene* 0.6 5 

Acetone* 1 10 Tetrachloroethene* 0.6 5 

Acrolein* 2 20 Toluene* 0.5 5 

Acrylonitrile* 3 20 trans-1,2-Dichloroethene* 0.5 5 

Benzene* 0.5 5 trans-1,3-Dichloropropene* 0.5 5 

Bromodichloromethane* 0.5 5 Trichloroethene* 0.7 5 

Bromoform* 0.8 5 Trichlorofluoromethane* 0.5 5 

Bromomethane* 1 5 Vinyl chloride* 1 5 

Carbon tetrachloride* 0.5 5 Xylenes, Total * 1.5 15 

Table F.10.1 - SW8270D - LODs and LOQs – Houston Facility 

Analyte – water matrix LOD LOQ Analyte - solid/soil matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

1,1’-Biphenyl * 0.50 10 1,1’-Biphenyl * 30 167 

1,2,4,5-Tetrachlorobenzene* 1.20 5 1,2,4,5-Tetrachlorobenzene* 30 167 

1,2,4-Trichlorobenzene* 0.80 5 1,2,4-Trichlorobenzene* 30 167 

1,2-Dichlorobenzene* 0.90 5 1,2-Dichlorobenzene* 30 167 

1,2-Dinitrobenzene * 1.90 5 1,2-Dinitrobenzene * 68 167 

1,2-Diphenylhydrazine* 0.80 5 1,2-Diphenylhydrazine* 40 167 

1,3-Dichlorobenzene* 1.10 5 1,3-Dichlorobenzene* 30 167 

1,3-Dinitrobenzene 1.60 5 1,3-Dinitrobenzene* 46 167 

1,4-Dichlorobenzene* 1.10 5 1,4-Dichlorobenzene* 32 167 

51 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F10 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.10.1 - SW8270D - LODs and LOQs – Houston Facility 

Analyte – water matrix LOD LOQ Analyte - solid/soil matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

1,4-Dinitrobenzene * 1.50 5 1,4-Dinitrobenzene * 48 167 

1,4-Dioxane 2.70 5 1,4-Dioxane 47 167 

1,4-Naphthoquinone * 0.90 5 1,4-Naphthoquinone * 37 167 

1- Chloronaphthalene* 0.50 5 1-Chloronaphthalene* 170 167 

1-Methylnaphthalene 0.70 5 1-Methylnaphthalene 30 167 

2,3,4,6-Tetrachlorophenol* 1.60 5 2,3,4,6-Tetrachlorophenol* 47 167 

2,4,5-Trichlorophenol* 0.90 5 2,4,5-Trichlorophenol* 56 167 

2,4,6-Trichlorophenol* 1.40 5 2,4,6-Trichlorophenol* 31 167 

2,4-Dichlorophenol* 1.50 5 2,4-Dichlorophenol* 36 167 

2,4-Dimethylphenol* 1.90 5 2,4-Dimethylphenol* 37 167 

2,4-Dinitrophenol* 1.40 5 2,4-Dinitrophenol* 64 167 

2,4-Dinitrotoluene* 1.00 5 2,4-Dinitrotoluene* 61 167 

2,6-Dichlorophenol* 1.30 5 2,6-Dichlorophenol* 54 167 

2,6-Dimethylphenol 0.70 5 2,6-Dimethylphenol 41 167 

2,6-Dinitrotoluene* 1.10 5 2,6-Dinitrotoluene* 31 167 

2-Chloronaphthalene* 1.10 5 2-Chloronaphthalene* 35 167 

2-Chlorophenol* 1.10 5 2-Chlorophenol* 58 167 

2-Methylnaphthalene* 0.90 5 2-Methylnaphthalene* 30 167 

2-Methylphenol* 1.00 5 2-Methylphenol* 36 167 

2-Nitroaniline* 1.40 5 2-Nitroaniline* 38 167 

2-Nitrophenol* 1.20 5 2-Nitrophenol* 61 167 

3 & 4-Methylphenol* 1.00 5 3 & 4-Methylphenol* 64 167 

3,3 ́-Dichlorobenzidine* 0.90 5 3,3 ́-Dichlorobenzidine* 30 167 

3-Methylcholanthrene * 1.20 5 3-Methylcholanthrene * 30 167 

3-Nitroaniline* 1.40 5 3-Nitroaniline* 30 167 

4,6-Dinitro-2-methylphenol * 0.90 5 4,6-Dinitro-2-methylphenol * 68 167 

4-Bromophenyl phenyl ether* 1.20 5 4-Bromophenyl phenyl ether* 42 167 

4-Bromopyrazole 2.10 5 4-Bromopyrazole 76 167 

4-Chloro-3-methylphenol* 0.80 5 4-Chloro-3-methylphenol* 60 167 

4-Chloroaniline* 0.80 5 4-Chloroaniline* 31 167 

4-Chlorophenyl phenyl ether* 1.00 5 4-Chlorophenyl phenyl ether* 30 167 

4-Nitroaniline* 1.60 5 4-Nitroaniline* 41 167 

4-Nitrophenol* 1.90 5 4-Nitrophenol* 61 167 

4-Nitroquinoline-1-oxide 2.00 5 4-Nitroquinoline-1-oxide 88 167 

7,12-Dimethylbenz(a)anthracene* 0.90 5 7,12-Dimethylbenz(a)anthracene* 37 167 

Acenaphthene* 0.90 5 Acenaphthene* 30 167 

Acenaphthylene* 0.50 5 Acenaphthylene* 30 167 

Acetophenone * 0.90 5 Acetophenone* 30 167 

Aniline* 0.70 5 Aniline* 30 167 

Anthracene* 0.60 5 Anthracene* 30 167 

Aramite* 1.60 5 Aramite* 61 167 

Atrazine* 1.00 5 Atrazine* 46 167 

Azobenzene* 1.00 5 Azobenzene* 30 167 

Benz(a)anthracene* 0.50 5 Benz(a)anthracene* 30 167 

Benzaldehyde 1.30 5 Benzaldehyde 43 167 

Benzidine* 5.00 5 Benzidine* 167 167 

52 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F11 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.10.1 - SW8270D - LODs and LOQs – Houston Facility 

Analyte – water matrix LOD LOQ Analyte - solid/soil matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

Benzo(a)pyrene* 0.60 5 Benzo(a)pyrene* 30 167 

Benzo(b)fluoranthene* 0.70 5 Benzo(b)fluoranthene* 30 167 

Benzo(g,h,i)perylene* 0.50 5 Benzo(g,h,i)perylene* 30 167 

Benzo(k)fluoranthene* 0.90 5 Benzo(k)fluoranthene* 30 167 

Benzoic acid* 5.00 5 Benzoic acid* 33 167 

Benzyl alcohol* 0.60 5 Benzyl alcohol* 36 167 

Bis(2-chloroethoxy)methane* 0.50 5 Bis(2-chloroethoxy)methane* 30 167 

Bis(2-chloroethyl)ether* 1.00 5 Bis(2-chloroethyl)ether* 34 167 

Bis(2-chloroisopropyl)ether* 0.60 5 Bis(2-chloroisopropyl)ether* 30 167 

Bis(2-ethylhexyl)phthalate* 3.30 5 Bis(2-ethylhexyl)phthalate* 30 167 

Butyl benzyl phthalate * 0.70 5 Butyl benzyl phthalate * 30 167 

Caprolactam* 5.00 5 Caprolactam* 51 167 

Carbazole * 0.50 5 Carbazole * 30 167 

Chlorobenzilate* 1.20 5 Chlorobenzilate* 32 167 

Chlorothalonil 0.90 5 Chlorothalonil 55 167 

Chrysene* 0.80 5 Chrysene* 30 167 

Dacthal 0.90 5 Dacthal 36 167 

Di-n-butyl phthalate* 0.50 5 Di-n-butyl phthalate* 30 167 

Di-n-octyl phthalate* 0.60 5 Di-n-octyl phthalate* 30 167 

Dibenz(a,h)anthracene * 0.80 5 Dibenz(a,h)anthracene* 30 167 

Dibenz(a,j)acridine * 1.10 5 Dibenz(a,j)acridine * 30 167 

Dibenzofuran * 0.70 5 Dibenzofuran* 30 167 

Diethyl phthalate* 0.50 5 Diethyl phthalate* 30 167 

Dimethyl phthalate* 0.50 5 Dimethyl phthalate* 30 167 

Diphenylamine* 0.70 5 Diphenylamine* 30 167 

Ethyl methacrylate 1.00 5 Ethyl methacrylate 30 167 

Ethyl methanesulfonate* 0.80 5 Ethyl methanesulfonate* 32 167 

Fluoranthene* 0.50 5 Fluoranthene* 30 167 

Fluorene* 0.60 5 Fluorene* 30 167 

Hexachlorobenzene* 1.10 5 Hexachlorobenzene* 32 167 

Hexachlorobutadiene* 1.10 5 Hexachlorobutadiene* 34 167 

Hexachlorocyclopentadiene* 2.30 5 Hexachlorocyclopentadiene* 41 167 

Hexachloroethane* 1.00 5 Hexachloroethane* 39 167 

Hexachloropropene * 2.50 5 Hexachloropropene * 30 167 

Indeno(1,2,3-cd)pyrene* 1.30 5 Indeno(1,2,3-cd)pyrene* 30 167 

Isodrin* 1.30 5 Isodrin* 50 167 

Isophorone* 0.60 5 Isophorone* 30 167 

Isophthalonitrile 0.50 5 Isophthalonitrile 30 167 

Isosafrole * 0.80 5 Isosafrole* 35 167 

Kepone * 5.00 5 Kepone * 167 167 

Methapyrilene * 1.40 5 Methapyrilene * 30 167 

Methyl methanesulfonate* 1.20 5 Methyl methanesulfonate* 37 167 

N-Nitrosodiethylamine * 0.80 5 N-Nitrosodiethylamine * 47 167 

N-Nitroso-di-n-butylamine * 0.90 5 N-Nitroso-di-n-butylamine * 44 167 

N-Nitrosodi-n-propylamine* 0.90 5 N-Nitrosodi-n-propylamine* 30 167 

N-Nitrosodimethylamine* 0.80 5 N-Nitrosodimethylamine* 46 167 

53 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F12 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.10.1 - SW8270D - LODs and LOQs – Houston Facility 

Analyte – water matrix LOD LOQ Analyte - solid/soil matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

N-Nitrosomethylethylamine * 0.80 5 N-Nitrosomethylethylamine * 56 167 

N-Nitrosodiphenylamine* 0.70 5 N-Nitrosodiphenylamine* 30 167 

N-Nitrosomorpholine * 1.10 5 N-Nitrosomorpholine * 84 167 

N-Nitrosopiperidine * 1.10 5 N-Nitrosopiperidine * 38 167 

N-Nitrosopyrrolidine * 1.10 5 N-Nitrosopyrrolidine * 41 167 

Naphthalene* 0.60 5 Naphthalene* 30 167 

Nitrobenzene* 0.80 5 Nitrobenzene* 33 167 

Pentachlorobenzene* 1.40 5 Pentachlorobenzene* 36 167 

Pentachloroethane 2.20 5 Pentachloroethane 53 167 

Pentachloronitrobenzene* 3.10 5 Pentachloronitrobenzene* 59 167 

Pentachlorophenol* 1.60 5 Pentachlorophenol* 70 167 

Phenacetin* 0.50 5 Phenacetin* 30 167 

Phenanthrene* 0.50 5 Phenanthrene* 30 167 

Phenol* 0.50 5 Phenol* 30 167 

Pronamide* 1.20 5 Pronamide* 30 167 

Pyrazole 1.30 5 Pyrazole 61 167 

Pyrene* 0.50 5 Pyrene* 30 167 

Pyridine* 2.00 5 Pyridine* 30 167 

Quinazoline 0.80 5 Quinazoline 30 167 

Quinoline * 0.60 5 Quinoline * 30 167 

Safrole* 1.20 5 Safrole * 36 167 

Sym-Trinitrobenzene * 1.70 5 Sym-Trinitrobenzene * 167 167 

Table F.10.2 - SW8270D – Low Level Method – Houston Facility 

Analyte – water matrix MDL MQL Analyte - solid/soil matrix MDL MQL 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

1,1 ́-Biphenyl * 0.10 0.2 1,1’-Biphenyl * 2.9 6.6 

1,2,4-Trichlorobenzene * 0.12 0.2 1,2,4-Trichlorobenzene * 3.9 6.6 

1,2-Dichlorobenzene * 0.13 0.2 1,2-Dichlorobenzene * 3.3 6.6 

1,2-Diphenylhydrazine * 0.10 0.2 1,2-Diphenylhydrazine * 2.2 6.6 

1,3-Dichlorobenzene * 0.14 0.2 1,3-Dichlorobenzene * 3.7 6.6 

1,4-Dichlorobenzene * 0.12 0.2 1,4-Dichlorobenzene * 3.6 6.6 

1-Methylnaphthalene 0.09 0.2 1-Methylnaphthalene 2.3 6.6 

2,4,5-Trichlorophenol * 0.09 0.2 2,4,5-Trichlorophenol * 2.8 6.6 

2,4,6-Trichlorophenol * 0.07 0.2 2,4,6-Trichlorophenol* 3.3 6.6 

2,4-Dichlorophenol * 0.08 0.2 2,4-Dichlorophenol * 2.2 6.6 

2,4-Dimethylphenol * 0.08 0.2 2,4-Dimethylphenol * 3.3 6.6 

2,4-Dinitrophenol * 0.08 1.0 2,4-Dinitrophenol * 3.3 33 

2,4-Dinitrotoluene * 0.09 0.2 2,4-Dinitrotoluene * 3.3 6.6 

2,6-Dinitrotoluene * 0.07 0.2 2,6-Dinitrotoluene * 3.2 6.6 

2-Chloronaphthalene * 0.10 0.2 2-Chloronaphthalene * 4.1 6.6 

2-Chlorophenol * 0.08 0.2 2-Chlorophenol * 3.2 6.6 

2-Methylnaphthalene * 0.07 0.2 2-Methylnaphthalene * 2.7 6.6 

2-Methylphenol * 0.08 0.2 2-Methylphenol * 2.9 6.6 

2-Nitroaniline * 0.10 0.2 2-Nitroaniline * 3.3 6.6 

54 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F13 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.10.2 - SW8270D – Low Level Method – Houston Facility 

Analyte – water matrix MDL MQL Analyte - solid/soil matrix MDL MQL 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

2-Nitrophenol * 0.07 0.2 2-Nitrophenol * 4.6 6.6 

3&4-Methylphenol * 0.10 0.2 3 & 4-Methylphenol * 2.8 6.6 

3,3'-Dichlorobenzidine * 0.07 0.2 3,3 ́-Dichlorobenzidine * 3.1 6.6 

3-Nitroaniline * 0.08 0.2 3-Nitroaniline * 2.6 6.6 

4,6-Dinitro-2-methylphenol * 0.08 0.2 4,6-Dinitro-2-methylphenol * 3.3 6.6 

4-Bromophenyl phenyl ether * 0.09 0.2 4-Bromophenyl phenyl ether * 3.3 6.6 

4-Chloro-3-methylphenol * 0.10 0.2 4-Chloro-3-methylphenol * 3.3 6.6 

4-Chloroaniline * 0.07 0.2 4-Chloroaniline * 2.2 6.6 

4-Chlorophenyl phenyl ether * 0.08 0.2 4-Chlorophenyl phenyl ether * 2.2 6.6 

4-Nitroaniline * 0.07 0.2 4-Nitroaniline * 3.3 6.6 

4-Nitrophenol * 0.07 1.0 4-Nitrophenol * 3.8 33 

Acenaphthene* 0.09 0.2 Acenaphthene* 2.2 6.6 

Acenaphthylene* 0.07 0.2 Acenaphthylene* 2.2 6.6 

Acetophenone * 0.10 0.2 Acetophenone * 2.4 6.6 

Aniline * 0.10 0.2 Aniline - 2.2 6.6 

Anthracene* 0.07 0.2 Anthracene* 2.2 6.6 

Atrazine * 0.08 0.2 Atrazine * 3.3 6.6 

Benz(a)anthracene* 0.07 0.2 Benz(a)anthracene* 2.8 6.6 

Benzaldehyde 0.12 0.2 Benzaldehyde 4.6 6.6 

Benzidine * 0.10 0.2 Benzidine * 6.6 6.6 

Benzo(a)pyrene* 0.08 0.2 Benzo(a)pyrene* 2.3 6.6 

Benzo(b)fluoranthene* 0.09 0.2 Benzo(b)fluoranthene* 3.3 6.6 

Benzo(g,h,i)perylene* 0.09 0.2 Benzo(g,h,i)perylene* 2.9 6.6 

Benzo(k)fluoranthene* 0.10 0.2 Benzo(k)fluoranthene* 3.3 6.6 

Benzoic acid * 0.14 0.2 Benzoic acid * 6.6 6.6 

Benzyl alcohol * 0.09 0.2 Benzyl alcohol * 3.1 6.6 

Bis(2-chloroethoxy) methane * 0.09 0.2 Bis(2-chloroethoxy)methane * 2.4 6.6 

Bis(2-chloroethyl) ether * 0.07 0.2 Bis(2-chloroethyl)ether * 2.8 6.6 

Bis(2-chloroisopropyl) ether * 0.07 0.2 Bis(2-chloroisopropyl)ether * 2.7 6.6 

Bis(2-ethylhexyl)phthalate * 0.20 0.2 Bis(2-ethylhexyl)phthalate * 6.6 6.6 

Butyl benzyl phthalate * 0.10 0.2 Butyl benzyl phthalate * 2.5 6.6 

Caprolactam * 0.08 0.2 Caprolactam * 2.4 6.6 

Carbazole * 0.07 0.2 Carbazole * 2.2 6.6 

Chrysene* 0.07 0.2 Chrysene* 2.9 6.6 

Di-n-butylphthalate * 0.07 0.2 Di-n-butyl phthalate * 2.5 6.6 

Di-n-octylphthalate * 0.09 0.2 Di-n-octyl phthalate * 2.9 6.6 

Dibenz(a,h)anthracene* 0.08 0.2 Dibenz(a,h)anthracene* 2.2 6.6 

Dibenzofuran * 0.08 0.2 Dibenzofuran * 2.2 6.6 

Diethylphthalate * 0.07 0.2 Diethyl phthalate * 3.3 6.6 

Dimethylphthalate * 0.10 0.2 Dimethyl phthalate* 2.4 6.6 

Diphenylamine * 0.09 0.2 Diphenylamine * 2.2 6.6 

Fluoranthene* 0.07 0.2 Fluoranthene* 2.2 6.6 

Fluorene* 0.07 0.2 Fluorene* 2.2 6.6 

Hexachlorobenzene * 0.10 0.2 Hexachlorobenzene * 2.6 6.6 

Hexachlorobutadiene * 0.15 0.2 Hexachlorobutadiene * 4.4 6.6 

55 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F14 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.10.2 - SW8270D – Low Level Method – Houston Facility 

Analyte – water matrix MDL MQL Analyte - solid/soil matrix MDL MQL 

* NELAC accredited μg/L μg/L * NELAC accredited μg/Kg μg/Kg 

Hexachlorocyclopentadiene * 0.08 0.2 Hexachlorocyclopentadiene * 3.6 6.6 

Hexachloroethane * 0.17 0.2 Hexachloroethane * 3.9 6.6 

Indeno(1,2,3-cd)pyrene* 0.10 0.2 Indeno(1,2,3-cd)pyrene* 3.5 6.6 

Isophorone * 0.07 0.2 Isophorone * 3.0 6.6 

Naphthalene* 0.10 0.2 Naphthalene* 3.3 6.6 

Nitrobenzene * 0.09 0.2 Nitrobenzene * 3.3 6.6 

N-Nitrosodi-n-propylamine * 0.10 0.2 N-Nitrosodi-n-propylamine * 4.0 6.6 

N-Nitrosodimethylamine * 0.10 0.2 N-Nitrosodimethylamine * 4.1 6.6 

N-Nitrosodiphenylamine * 0.09 0.2 N-Nitrosodiphenylamine * 2.2 6.6 

Pentachlorophenol * 0.08 0.2 Pentachlorophenol * 2.8 6.6 

Phenanthrene* 0.07 0.2 Phenanthrene* 3.0 6.6 

Phenol * 0.07 0.2 Phenol * 3.3 6.6 

Pyrene* 0.07 0.2 Pyrene* 2.2 6.6 

Pyridine * 0.08 1 Pyridine * 3.3 6.6 

Quinoline * 0.08 0.2 Quinoline * 2.2 6.6 

Table F.11 - EPA 625 - LODs and LOQs - Houston Facility 

Analyte – water matrix LOD LOQ Analyte – water matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/L μg/L 

1,2,4-Trichlorobenzene* 0.9 5 Bis(2-chloroethoxy)methane* 0.8 5 

1,2-Dichlorobenzene* 0.7 5 Bis(2-chloroethyl)ether* 0.8 5 

1,2-Diphenylhydrazine 1.0 5 Bis(2-chloroisopropyl)ether* 0.8 5 

1,3-Dichlorobenzene* 0.8 5 Bis(2-ethylhexyl)phthalate* 1.2 5 

1,4-Dichlorobenzene* 0.7 5 Butyl benzyl phthalate* 0.8 5 

2,4,5-Trichlorophenol* 1.3 9 Chrysene* 1.0 5 

2,4,6-Trichlorophenol* 1.6 5 Di-n-butyl phthalate* 0.7 5 

2,4-Dichlorophenol* 1.6 5 Di-n-octyl phthalate* 0.6 5 

2,4-Dimethylphenol* 1.5 5 Dibenz(a,h)anthracene* 0.6 5 

2,4-Dinitrophenol* 1.6 5 Diethyl phthalate* 0.8 5 

2,4-Dinitrotoluene* 0.9 5 Dimethyl phthalate* 0.9 5 

2,6-Dinitrotoluene* 1.0 5 Fluoranthene* 0.6 5 

2-Chloronaphthalene* 0.9 5 Fluorene* 0.8 5 

2-Chlorophenol* 1.8 5 Hexachlorobenzene* 0.6 5 

2-Nitrophenol* 1.3 5 Hexachlorobutadiene* 0.9 5 

3,3 ́-Dichlorobenzidine* 0.7 5 Hexachlorocyclopentadiene* 0.6 5 

4,6-Dinitro-2-methylphenol 1.0 5 Hexachloroethane* 1.4 5 

4-Bromophenyl phenyl ether* 0.9 5 Indeno(1,2,3-cd)pyrene* 0.6 5 

4-Chloro-3-methylphenol* 1.1 5 Isophorone* 0.9 5 

4-Chlorophenyl phenyl ether* 0.9 5 N-Nitrosodi-n-propylamine* 1.0 5 

4-Nitrophenol* 1.0 5 N-Nitrosodimethylamine* 0.9 5 

Acenaphthene* 0.8 5 N-Nitrosodiphenylamine* 0.7 5 

Acenaphthylene* 0.7 5 Naphthalene* 0.8 5 

Anthracene* 0.7 5 Nitrobenzene* 0.8 5 

Benzidine* 5.0 5 Pentachlorobenzene* 0.8 5 

Benz(a)anthracene* 0.6 5 Pentachlorophenol* 1.5 5 

56 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page F15 of 14 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table F.11 - EPA 625 - LODs and LOQs - Houston Facility 

Analyte – water matrix LOD LOQ Analyte – water matrix LOD LOQ 

* NELAC accredited μg/L μg/L * NELAC accredited μg/L μg/L 

Benzo(a)pyrene* 0.7 5 Phenanthrene* 0.7 5 

Benzo(b)fluoranthene* 0.8 5 Phenol* 1.5 5 

Benzo(g,h,i)perylene* 0.9 5 Pyrene* 0.9 5 

Benzo(k)fluoranthene* 0.6 5 

Table F.12 - SW 8330A LODs and LOQs - Houston Facility

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

HMX* 0.10 0.45 HMX* 40 250 

RDX* 0.10 0.45 RDX* 40 250 

1,3,5-Trinitrobenzene* 0.10 0.45 1,3,5-Trinitrobenzene* 80 250 

1,3-Dinitrobenzene* 0.10 0.45 1,3-Dinitrobenzene* 40 250 

Tetryl* 0.10 0.45 Tetryl* 74 500 

Nitrobenzene* 0.10 0.45 Nitrobenzene* 40 250 

2,4,6-Trinitrotoluene* 0.10 0.45 2,4,6-Trinitrotoluene* 40 250 

4-Amino-2,6-dinitrotoluene* 0.10 0.45 4-Amino-2,6-dinitrotoluene* 40 250 

2-Amino-4, 6-dinitrotoluene* 0.10 0.45 2-Amino-4, 6-dinitrotoluene* 40 250 

2,4-Dinitrotoluene* 0.10 0.45 2,4-Dinitrotoluene* 40 250 

2,6-Dinitrotoluene* 0.10 0.45 2,6-Dinitrotoluene* 40 250 

2-Nitrotoluene* 0.10 0.45 2-Nitrotoluene* 40 250 

3-Nitrotoluene* 0.10 0.45 3-Nitrotoluene* 40 250 

4-Nitrotoluene* 0.10 0.45 4-Nitrotoluene* 40 250 

Table F.13.1 - Formaldehyde by SW 8315A - LOD and LOQ - Houston Facility 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

Formaldehyde * 1 5 Formaldehyde * 100 100 

Table F.13.2 - Formaldehyde by SW 8316 - LOD and LOQ - Houston Facility 

Analyte – water matrix 

* NELAC accredited 

LOD 

μg/L 

LOQ 

μg/L 

Analyte - solid/soil matrix 

* NELAC accredited 

LOD 

μg/Kg 

LOQ 

μg/Kg 

Acrylamide * 0.24 1.0 Acrylamide * 0.24 1.0 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Appendix G – Method Acceptance Criteria for LCS 

Table G.1 - Wet Chemistry - LCS Recovery Limits – Houston Facility 

Analyte - Water Matrix SPK 

mg/L 

Low High RPD Analyte - Soil Matrix SPK 

mg/Kg 

Low High RPD 

PH / E150.2/SW9040 

(standard units) 

- 90 110 20 pH / E150.2/SW9045 

(standard units) 

50 78 122 30 

Specific Conductance / E120.0 

SW9050 (umhos/cm) 

- 85 115 20 

Total Dissolved Solids / 

 EPA160.2/ SM 2540C 

1000 85 115 20 

Total Suspended Solids / 

EPA 160.1 / SM 2540D 

100 72 115 20 

Total Solids / EPA 160.3 1000 80 120 20 

Total Alkalinity / SM2320B/E 310.1 1000 85 115 20 

Chrome VI - SW 7196A – SM3500 0.25 86 117 15 Chrome VI by SW 7196 25 81 115 25 

Ferrous Iron by SM 3500-Fe D 0.25 85 115 20 

Ammonia as N - SM4500 NH3-D 10 80 120 20 

Ammonia as N - SM4500 NH3-B-F 0.2 80 120 20 

T. Kjeldahl Nitrogen – SM4500 10 80 120 20 

Fluoride by SM 4500 F BC (ISE) 4 80 120 20 

Fluoride by SW 9214 (ISE) 4 80 120 20 

Bromide by EPA 300 / SW9056A 4 90 110 20 Bromide by EPA 300 / SW9056A 40 90 110 20 

Chloride by EPA 300 / SW9056A 20 90 110 20 Chloride by EPA 300 / SW9056A 200 90 110 20 

Fluoride by EPA 300 / SW9056A 4 90 110 20 Fluoride by EPA 300 / SW9056A 40 90 110 20 

Sulfate by EPA 300 / SW9056A 20 90 110 20 Sulfate by EPA 300 / SW9056A 200 90 110 20 

Nitrate as N - E300 / SW9056A 4 90 110 20 Nitrate as N - E300 / SW9056A 40 90 110 20 

Nitrite as N – E300 / SW9056A 4 90 110 20 Nitrite as N – E300 / SW9056A 40 90 110 20 

O-Phosphorous (P) E300/SW9056A 4 90 110 20 O-Phosphorous (P) E300/SW9056A 40 90 110 20 

Ortho Phosphorous (P) E365.3 0.25 85 115 20 

Total Phosphorous (P) E365.3 0.25 85 115 20 

Total Organic Carbon - E415.1/ 

SW9060A / SM5310C 

10 80 120 20 Total Organic Carbon – 

SW 9060A M for soil 

0.6 

%wt 

80 120 20 

Chemical Oxygen Demand – Hach 100 80 120 20 

Biochemical Oxygen Demand -

E405.1 / SM5210B 

198 85 115 20 

Phenolics, Tot Recoverable – 

SW9065 - E420.1 

0.5 80 120 20 Phenolics, Tot Recoverable 

SW9065 

25 80 120 20 

Perchlorate - E314.0 (unit = μg/L ) 25 85 115 20 

Total Cyanide - SW9010/9014 0.10 80 120 20 Total Cyanide - SW9010/9014 5.0 80 120 30 

Total Cyanide – SM 4500CN E 0.10 80 120 20 

Oil &Grease, EPA 1664A 40 80 120 20 Oil &Grease, EPA1664A/SW9071B 2670 80 120 20 

Table G.3.1 - TPH LCS Recovery Limits - Houston

Analyte – Water Matrix SPK 

mg/L 

Low High RPD Analyte – Soil Matrix SPK 

mg/Kg 

Low High RPD 

NC6-nC12 / TX1005 25 75 125 20 NC6-nC12 / TX1005 250 75 125 30 

>nC12 to nC28 / TX1005 25 75 125 20 >nC12 to nC28 / TX1005 250 75 125 30 

Total Petroleum Hydrocarbons 50 75 125 20 Total Petroleum Hydrocarbons 500 75 125 30 

2-Fluorobiphenyl (Surr) TX1005 5 70 130 20 2-Fluorobiphenyl (Surr) TX1005 50 70 130 30 

Trifluorotoluene (Surr) TX1005 5 70 130 20 Trifluorotoluene (Surr) TX1005 50 70 130 30 

TPH (TX1006) 50 60 140 20 TPH (TX1006) 500 60 140 30 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G2 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.3.1 - TPH LCS Recovery Limits - Houston

Analyte – Water Matrix SPK 

mg/L 

Low High RPD Analyte – Soil Matrix SPK 

mg/Kg 

Low High RPD 

Gasoline Range (Purgeable) by 

SW8015C 

1.0 70 130 20 Gasoline Range (Purgeable) by 

SW8015C 

1.0 70 130 30 

Diesel Range by SW8015C 1.0 70 130 20 Diesel Range by SW8015C 33 70 130 30 

Oil Range by SW8015C 1.0 70 130 20 Oil Range by SW8015C 33 70 130 30 

Table G.3.2 - Nonhalogenated Organics by 8015C - LCS Recovery Limits – Houston Facility

Analyte – Water Matrix SPK 

mg/L 

Low High RPD Analyte – Soil Matrix SPK 

mg/Kg 

Low High RPD 

Ethylene Glycol 100 70 130 20 Ethylene Glycol 100 70 130 30 

1-Propanol 10 70 130 20 1-Propanol 10 70 130 30 

2-Propanol 10 70 130 20 2-Propanol 10 70 130 30 

Isobutanol 10 70 130 20 Isobutanol 10 70 130 30 

Propylene glycol 100 70 130 20 Propylene glycol 100 70 130 30 

Ethanol 10 70 130 20 Ethanol 10 70 130 30 

Methanol 10 70 130 20 Methanol 10 70 130 30 

Table G.3.3 - - Dissolved Gases by Headspace Analysis of waters, RSK-175. 

LCS Recovery Limits – Houston Facility

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte – Water Matrix SPK 

μg/L 

Low High RPD 

Ethane 18.0 75 125 20 Methane 9.62 75 125 20 

Ethene 16.8 75 125 20 

Table G.4.1 - SW 8011 LCS Recovery Limits – Houston Facility 

Analyte - Water Matrix SPK 

μg/L 

Low High RPD Analyte - Water Matrix SPK 

μg/L 

Low High RPD 

1,2-Dibromoethane 0.25 60 140 20 1,2-Dibromo-3-chloropropane 0.25 60 140 20 

1,2,3-Trichloropropane 0.25 60 140 20 

Table G.4.2 - EPA 504.1 LCS Recovery Limits – Houston Facility 

Analyte - Water Matrix SPK 

μg/L 

Low High RPD Analyte - Water Matrix SPK 

μg/L 

Low High RPD 

1,2-Dibromoethane 0.25 70 130 20 1,2-Dibromo-3-chloropropane 0.25 70 130 20 

1,2,3-Trichloropropane 0.25 70 130 20 

Table G.4.3 - EPA 504.1 MS Recovery Limits – Houston Facility 

Analyte - Water Matrix SPK 

μg/L 

Low High RPD Analyte - Water Matrix SPK 

μg/L 

Low High RPD 

1,2-Dibromoethane 0.25 65 135 20 1,2-Dibromo-3-chloropropane 0.25 65 135 20 

1,2,3-Trichloropropane 0.25 65 135 20 

Table G.5 - BTEX by SW 8021B LCS Recovery Limits – Houston Facility

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte - Soil Matrix SPK 

μg/Kg 

Low High RPD 

Benzene 20 77 126 20 Benzene 20 74 129 30 

Ethylbenzene 20 76 125 20 Ethylbenzene 20 73 127 30 

Toluene 20 80 124 20 Toluene 20 75 128 30 

M,p-Xylene 40 79 124 20 m,p-Xylene 40 74 127 30 

o-Xylene 20 79 124 20 p-Xylene 20 74 127 30 

Xylenes, Total 60 79 124 20 Xylenes, Total 60 74 127 30 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.5 - BTEX by SW 8021B LCS Recovery Limits – Houston Facility

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte - Soil Matrix SPK 

μg/Kg 

Low High RPD 

Methyl tert-butyl ether 100 75 128 20 Methyl tert-butyl ether 100 73 128 30 

4-BFB (Surr) 30 77 129 20 4-BFB (Surr) 30 75 131 30 

Trifluorotoluene (Surr) 30 75 130 20 Trifluorotoluene (Surr) 30 73 130 30 

Table G.6 - SW 8081B LCS Recovery Limits – Houston Facility 

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte - Soil Matrix SPK 

μg/Kg 

Low High RPD 

4,4'-DDD 0.5 53 144 30 4,4'-DDD 16.7 53 138 30 

4,4'-DDE 0.5 55 144 30 4,4'-DDE 16.7 57 136 30 

4,4'-DDT 0.5 53 149 30 4,4'-DDT 16.7 53 139 30 

Aldrin 0.25 47 141 30 Aldrin 8.33 52 130 30 

Alpha-BHC 0.25 51 141 30 Alpha-BHC 8.33 52 130 30 

Beta-BHC 0.25 58 144 30 Beta-BHC 8.33 62 130 30 

Delta-BHC 0.25 48 146 30 Delta-BHC 8.33 41 137 30 

Dieldrin 0.5 56 144 30 Dieldrin 16.7 54 138 30 

Endosulfan I 0.25 55 141 30 Endosulfan I 8.33 55 132 30 

Endosulfan II 0.5 57 144 30 Endosulfan II 16.7 59 134 30 

Endosulfan sulfate 0.5 58 145 30 Endosulfan sulfate 16.7 54 141 30 

Endrin 0.5 60 163 30 Endrin 16.7 60 157 30 

Endrin aldehyde 0.5 59 158 30 Endrin aldehyde 16.7 56 146 30 

Endrin ketone 0.5 59 154 30 Endrin ketone 16.7 56 153 30 

Gamma-BHC (Lindane) 0.25 53 142 30 Gamma-BHC (Lindane) 8.33 52 133 30 

Heptachlor 0.25 51 144 30 Heptachlor 8.33 54 134 30 

Heptachlor epoxide 0.25 55 142 30 Heptachlor epoxide 8.33 58 130 30 

Methoxychlor 0.25 59 150 30 Methoxychlor 16.7 60 140 30 

Alpha-Chlordane 0.25 55 141 30 Alpha-Chlordane 8.33 55 132 30 

Gamma-Chlordane 0.25 55 137 30 Gamma-Chlordane 8.33 60 129 30 

Mirex 0.5 50 150 30 Mirex 16.7 50 150 30 

Hexachlorobenzene 0.5 50 150 30 Hexachlorobenzene 16.7 50 150 30 

Decachlorobiphenyl (Surr) 0.2 61 154 30 Decachlorobiphenyl (Surr) 6.67 66 150 30 

Tetrachloro-m-xylene (Surr) 0.2 60 144 30 Tetrachloro-m-xylene (Surr) 6.67 63 135 30 

Table G.7 - SW 8082A LCS Recovery Limits - Houston Facility 

Analyte - Water Matrix SPK 

μg/L 

Low High RPD Analyte - Soil Matrix SPK 

μg/Kg 

Low High RPD

Aroclor 1016 5 54 138 30 Aroclor 1016 167 53 135 30 

Aroclor 1260 5 57 136 30 Aroclor 1260 167 54 137 30 

Decachlorobiphenyl (Surr) 0.2 54 140 30 Decachlorobiphenyl (Surr) 6.67 54 143 30 

Tetrachloro-m-xylene (Surr) 0.2 53 137 30 Tetrachloro-m-xylene (Surr) 6.67 55 137 30 

Table G.8 - SW 8151A LCS Recovery Limits,- Houston Facility 

Analyte - Water Matrix SPK 

μg/L 

Low High RPD Analyte - Soil Matrix SPK Low High RPD 

2,4,5-T 0.25 46 127 20 2,4,5-T 0.5 41 149 30 

2,4,5-TP (Silvex) 0.25 54 145 20 2,4,5-TP (Silvex) 0.5 54 142 30 

2,4-D 0.25 31 120 20 2,4-D 0.5 31 120 30 

2,4-DB 0.25 43 147 20 2,4-DB 0.5 55 147 30 

Dalapon 0.25 28 153 20 Dalapon 0.5 49 144 30 

Dicamba 0.25 39 122 20 Dicamba 0.5 41 132 30 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.8 - SW 8151A LCS Recovery Limits,- Houston Facility 

Analyte - Water Matrix SPK 

μg/L 

Low High RPD Analyte - Soil Matrix SPK Low High RPD 

Dichlorprop 0.25 53 128 20 Dichlorprop 0.5 53 124 30 

Dinoseb 0.25 41 128 20 Dinoseb 0.5 41 135 30 

MCPA 25 43 126 20 MCPA 50 37 131 30 

MCPP 25 43 128 20 MCPP 50 39 131 30 

DCAA (Surr) 0.50 43 130 20 DCAA (Surr) 0.5 47 135 30 

Table G.9.1 - SW8260C LCS Recovery Limits - Houston Facility 

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte – Soil Matrix SPK 

μg/Kg 

Low High RPD 

1,1,1,2-Tetrachloroethane 50 78 120 20 1,1,1,2-Tetrachloroethane 50 80 120 30 

1,1,1-Trichloroethane 50 80 122 20 1,1,1-Trichloroethane 50 80 127 30 

1,1,2,2-Tetrachloroethane 50 75 120 20 1,1,2,2-Tetrachloroethane 50 72 124 30 

1,1,2-Trichlor-1,2,2-

trifluoroethane 

50 75 125 20 1,1,2-Trichlor-1,2,2-

trifluoroethane 

50 79 129 30 

1,1,2-Trichloroethane 50 80 120 20 1,1,2-Trichloroethane 50 77 120 30 

1,1-Dichloroethane 50 76 120 20 1,1-Dichloroethane 50 78 124 30 

1,1-Dichloroethene 50 76 120 20 1,1-Dichloroethene 50 80 124 30 

1,1-Dichloropropene 50 75 120 20 1,1-Dichloropropene 50 77 122 30 

1,2,3-Trichlorobenzene 50 76 120 20 1,2,3-Trichlorobenzene 50 74 126 30 

1,2,3-Trichloropropane 50 76 120 20 1,2,3-Trichloropropane 50 72 123 30 

1,2,3-Trimethylbenzene 50 80 120 20 1,2,3-Trimethylbenzene 50 80 120 30 

1,2,4-Trichlorobenzene 50 80 120 20 1,2,4-Trichlorobenzene 50 75 127 30 

1,2,4-Trimethylbenzene 50 75 120 20 1,2,4-Trimethylbenzene 50 80 121 30 

1,2-Dibromo-3-chloropropane 50 75 124 20 1,2-Dibromo-3-chloropropane 50 68 131 30 

1,2-Dibromoethane 50 80 120 20 1,2-Dibromoethane 50 80 120 30 

1,2-Dichlorobenzene 50 80 120 20 1,2-Dichlorobenzene 50 78 120 30 

1,2-Dichloroethane 50 78 120 20 1,2-Dichloroethane 50 75 121 30 

1,2-Dichloropropane 50 80 120 20 1,2-Dichloropropane 50 79 121 30 

1,3,5-Trimethylbenzene 50 80 120 20 1,3,5-Trimethylbenzene 50 80 123 30 

1,3-Butadiene 50 71 127 20 1,3-Butadiene 50 75 127 30 

1,3-Dichlorobenzene 50 80 120 20 1,3-Dichlorobenzene 50 79 120 30 

1,3-Dichloropropane 50 80 120 20 1,3-Dichloropropane 50 78 120 30 

1,4-Dichlorobenzene 50 80 120 20 1,4-Dichlorobenzene 50 78 120 30 

1,4-Dioxane 1000 45 160 20 1,4-Dioxane 1000 61 137 30 

1-Chlorohexane 50 73 120 20 1-Chlorohexane 50 80 125 30 

1-Propanol 1000 54 151 20 1-Propanol 50 60 140 30 

2,2-Dichloropropane 50 80 125 20 2,2-Dichloropropane 50 79 128 30 

2-Butanone 100 70 130 20 2-Butanone 100 68 127 30 

2-Chloro-1,3-butadiene 50 74 122 20 2-Chloro-1,3-butadiene 50 63 136 30 

2-Chloroethyl vinyl ether 100 75 121 20 2-Chloroethyl vinyl ether 100 74 128 30 

2-Chlorotoluene 50 80 120 20 2-Chlorotoluene 50 80 120 30 

2-Hexanone 100 74 132 20 2-Hexanone 100 70 131 30 

2-Methylnaphthalene 50 60 140 20 2-Methylnaphthalene 50 60 140 30 

4-Chlorotoluene 50 80 120 20 4-Chlorotoluene 50 79 120 30 

4-Isopropyltoluene 50 80 120 20 4-Isopropyltoluene 50 80 123 30 

4-Methyl-2-pentanone 100 72 130 20 4-Methyl-2-pentanone 100 71 130 30 

Acetaldehyde 200 60 130 20 Acetaldehyde 200 58 137 30 

Acetone 100 65 138 20 Acetone 100 63 138 30 

Acetonitrile 100 64 133 20 Acetonitrile 500 62 131 30 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.9.1 - SW8260C LCS Recovery Limits - Houston Facility 

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte – Soil Matrix SPK 

μg/Kg 

Low High RPD 

Acrolein 100 64 145 20 Acrolein 100 56 143 30 

Acrylonitrile 100 70 130 20 Acrylonitrile 100 67 130 30 

Allyl Chloride 50 50 149 20 Allyl Chloride 50 71 131 30 

Benzene 50 80 120 20 Benzene 50 79 121 30 

Benzyl Chloride 50 69 120 20 Benzyl Chloride 50 63 133 30 

Bromobenzene 50 80 120 20 Bromobenzene 50 80 120 30 

Bromochloromethane 50 80 120 20 Bromochloromethane 50 80 120 30 

Bromodichloromethane 50 80 120 20 Bromodichloromethane 50 80 121 30 

Bromoform 50 79 120 20 Bromoform 50 74 126 30 

Bromomethane 50 70 133 20 Bromomethane 50 69 125 30 

Butyl methcrylate 50 70 130 20 Butyl methacrylate 50 70 130 30 

Carbon disulfide 100 77 123 20 Carbon disulfide 100 75 128 30 

Carbon tetrachloride 50 76 122 20 Carbon tetrachloride 50 76 130 30 

Chlorobenzene 50 80 120 20 Chlorobenzene 50 80 120 30 

Chloroethane 50 69 129 20 Chloroethane 50 73 128 30 

Chloroform 50 80 120 20 Chloroform 50 77 122 30 

Chloromethane 50 67 125 20 Chloromethane 50 64 129 30 

Cis-1,2-Dichloroethene 50 80 120 20 cis-1,2-Dichloroethene 50 78 122 30 

Cis-1,3-Dichloropropene 50 80 120 20 cis-1,3-Dichloropropene 50 80 123 30 

Cyclohexane 50 70 126 20 Cyclohexane 50 75 129 30 

Dibromochloromethane 50 80 120 20 Dibromochloromethane 50 80 122 30 

Dibromomethane 50 80 120 20 Dibromomethane 50 74 120 30 

Dichlorodifluoromethane 50 62 123 20 Dichlorodifluoromethane 50 57 133 30 

Diethyl Ether 50 75 129 20 Diethyl Ether 50 78 121 30 

Diisopropyl ether 50 75 121 20 Diisopropyl ether 50 74 124 30 

Epichlorohydrin 200 68 131 20 Epichlorohydrin 200 55 132 30 

Ethyl acrylate 50 70 128 20 Ethyl acrylate 50 76 125 30 

Ethyl methacrylate 50 78 123 20 Ethyl methacrylate 50 62 137 30 

Ethylbenzene 50 80 120 20 Ethylbenzene 50 80 120 30 

Hexachlorobutadiene 50 72 123 20 Hexachlorobutadiene 50 74 132 30 

Iodomethane 100 70 126 20 Iodomethane 100 70 130 30 

Isobutyl alcohol 1000 49 150 20 Isobutyl alcohol 1000 57 144 30 

Isoprene 50 71 126 20 Isoprene 50 79 128 30 

Isopropyl alcohol 1000 51 150 20 Isopropyl alcohol 1000 51 145 30 

Isopropylbenzene 50 80 120 20 Isopropylbenzene 50 80 123 30 

M,p-Xylene 100 80 120 20 m,p-Xylene 100 80 120 30 

Methacrylonitrile 50 71 129 20 Methacrylonitrile 50 57 137 30 

Methyl acetate 50 68 132 20 Methyl acetate 50 64 129 30 

Methyl methacrylate 50 75 124 20 Methyl methacrylate 50 73 123 30 

Methyl tert-butyl ether 50 80 122 20 Methyl tert-butyl ether 50 75 124 30 

Methylcyclohexane 50 75 122 20 Methylcyclohexane 50 76 129 30 

Methylene chloride 50 78 120 20 Methylene chloride 50 68 127 30 

n-Butyl acetate 50 57 150 20 n-Butyl acetate 50 59 142 30 

n-Butyl acrylate 50 73 125 20 n-Butyl acrylate 50 69 130 30 

n-Butylbenzene 50 77 120 20 n-Butylbenzene 50 78 128 30 

n-Heptane 50 67 127 20 n-Heptane 50 76 122 30 

n-Hexane 50 68 129 20 n-Hexane 50 76 132 30 

n-Propylbenzene 50 80 120 20 n-Propylbenzene 50 79 124 30 

Naphthalene 50 74 127 20 Naphthalene 50 71 132 30 

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HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.9.1 - SW8260C LCS Recovery Limits - Houston Facility 

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte – Soil Matrix SPK 

μg/Kg 

Low High RPD 

o-Xylene 50 80 120 20 o-Xylene 50 80 121 30 

Propylene oxide 100 60 131 20 Propylene oxide 100 56 142 30 

Sec-Butylbenzene 50 79 120 20 sec-Butylbenzene 50 80 125 30 

Styrene 50 80 120 20 Styrene 50 80 123 30 

Tert-butyl alcohol 1000 57 146 20 Tert-butyl alcohol 1000 58 139 30 

Tert-Butylbenzene 50 80 120 20 tert-Butylbenzene 50 80 122 30 

Tetrachloroethene 50 80 120 20 Tetrachloroethene 50 80 123 30 

Toluene 50 80 120 20 Toluene 50 79 120 30 

Trans-1,2-Dichloroethene 50 80 122 20 Trans-1,2-Dichloroethene 50 78 124 30 

Trans-1,3-Dichloropropene 50 80 120 20 Trans-1,3-Dichloropropene 50 80 122 30 

Trans-1,4-Dichloro-2-butene 50 75 120 20 Trans-1,4-Dichloro-2-butene 50 64 130 30 

Trichloroethene 50 80 120 20 Trichloroethene 50 80 120 30 

Trichlorofluoromethane 50 70 129 20 Trichlorofluoromethane 50 77 132 30 

Vinyl acetate 100 71 129 20 Vinyl acetate 100 61 140 30 

Vinyl chloride 50 67 129 20 Vinyl chloride 50 71 129 30 

Xylenes, Total 150 80 120 20 Xylenes, Total 150 80 120 30 

1,2-Dichloroethane-d4 50 70 125 20 1,2-Dichloroethane-d4 50 70 128 30 

4-Bromofluorobenzene 50 72 125 20 4-Bromofluorobenzene 50 73 126 30 

Dibromofluoromethane 50 71 125 20 Dibromofluoromethane 50 71 128 30 

Toluene-d8 50 75 125 20 Toluene-d8 50 73 127 30 

Table G.9.2 - SW8260C Low Level Water - LCS Recovery - Limits Houston Facility 

Analyte – Low Water Matrix SPK 

μg/L 

Low High RPD Analyte – Low Water Matrix SPK 

μg/L 

Low High RPD 

1,1,1,2-Tetrachloroethane 10 80 120 20 Chlorobenzene 10 80 120 20 

1,1,1-Trichloroethane 10 80 120 20 Chloroethane 10 80 120 20 

1,1,2,2-Tetrachloroethane 10 74 123 20 Chloroform 10 80 120 20 

1,1,2-Trichlor-1,2,2-trifluoroethane 10 76 120 20 Chloromethane 10 72 127 20 

1,1,2-Trichloroethane 10 80 120 20 Cis-1,2-Dichloroethene 10 80 120 20 

1,1-Dichloroethane 10 80 120 20 Cis-1,3-Dichloropropene 10 79 120 20 

1,1-Dichloroethene 10 80 120 20 Cyclohexane 10 75 125 20 

1,1-Dichloropropene 10 80 120 20 Dibromochloromethane 10 74 120 20 

1,2,3-Trichlorobenzene 10 79 120 20 Dibromomethane 10 80 120 20 

1,2,3-Trichloropropane 10 70 126 20 Dichlorodifluoromethane 10 72 125 20 

1,2,3-Trimethylbenzene 10 80 120 20 Dicyclopentadiene 10 80 120 20 

1,2,4-Trichlorobenzene 10 77 120 20 Ethyl acrylate 10 75 125 20 

1,2,4-Trimethylbenzene 10 80 120 20 Ethylbenzene 10 80 120 20 

1,2-Dibromo-3-chloropropane 10 68 120 20 Ethyl methacrylate 10 59 139 20 

1,2-Dibromoethane 10 80 120 20 Hexachlorobutadiene 10 77 122 20 

1,2-Dichlorobenzene 10 80 120 20 Iodomethane 20 58 130 20 

1,2-Dichloroethene, Total 10 80 120 20 Isopropylbenzene 10 80 120 20 

1,2-Dichloroethane 10 79 120 20 m,p-Xylene 20 80 123 20 

1,2-Dichloropropane 10 80 120 20 Methacrylonitrile 10 75 126 20 

1,3,5-Trimethylbenzene 10 80 120 20 Methyl acetate 10 76 122 20 

1,3-Dichlorobenzene 10 80 120 20 Methyl methacrylate 10 73 139 20 

1,3-Dichloropropane 10 80 120 20 Methyl tert-butyl ether 10 79 120 20 

1,4-Dichlorobenzene 10 80 120 20 Methylcyclohexane 10 79 123 20 

1,4-Dioxane 200 60 154 20 Methylene chloride 10 75 125 20 

1-Chlorohexane 10 77 120 20 n-Butylbenzene 10 80 120 20 

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Effective: 09/01/2009 

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© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.9.2 - SW8260C Low Level Water - LCS Recovery - Limits Houston Facility 

Analyte – Low Water Matrix SPK 

μg/L 

Low High RPD Analyte – Low Water Matrix SPK 

μg/L 

Low High RPD 

2,2-Dichloropropane 10 77 121 20 n-Hexane 10 75 125 20 

2-Butanone 20 70 130 20 n-Propylbenzene 10 80 120 20 

2-Chloroethyl vinyl ether 20 75 120 20 Naphthalene 10 74 125 20 

2-Chlorotoluene 10 80 120 20 o-Xylene 10 80 120 20 

2-Hexanone 20 66 131 20 Sec-Butylbenzene 10 80 120 20 

4-Chlorotoluene 10 80 120 20 Styrene 10 78 122 20 

4-Isopropyltoluene 10 80 120 20 Tert-Butylbenzene 10 80 120 20 

4-Methyl-2-pentanone 20 67 132 20 Tetrachloroethene 10 80 120 20 

Acetone 20 65 135 20 Toluene 10 80 121 20 

Acetonitrile 20 70 135 20 Trans-1,2-Dichloroethene 10 80 120 20 

Acrolein 20 70 130 20 Trans-1,3-Dichloropropene 10 76 120 20 

Acrylonitrile 20 70 130 20 Trichloroethene 10 80 120 20 

Benzene 10 80 120 20 Trichlorofluoromethane 10 79 120 20 

Bromobenzene 10 80 120 20 Vinyl acetate 20 63 139 20 

Bromochloromethane 10 80 120 20 Vinyl chloride 10 75 125 20 

Bromodichloromethane 10 80 120 20 Xylenes, Total 30 80 124 20 

Bromoform 10 70 120 20 1,2-Dichloroethane-d4 10 71 125 20 

Bromomethane 10 63 139 20 4-Bromofluorobenzene 10 70 125 20 

Butyl acrylate 10 68 130 20 Dibromofluoromethane 10 74 125 20 

Carbon disulfide 20 80 120 20 Toluene-d8 10 78 123 20 

Carbon tetrachloride 10 79 120 20 

Table G.9.3 - EPA 624 LCS Recovery Limits - Houston Facility 

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte - Water Matrix SPK 

μg/L 

Low High RPD 

1,1,1-Trichloroethane 20 80 133 20 Chloroethane 20 78 125 20 

1,1,2,2-Tetrachloroethane 20 73 133 20 Chloroform 20 79 127 20 

1,1,2-Trichloroethane 20 80 132 20 Chloromethane 20 70 133 20 

1,1-Dichloroethane 20 76 131 20 cis-1,2-Dichloroethene 20 74 129 20 

1,1-Dichloroethene 20 77 124 20 cis-1,3-Dichloropropene 20 74 129 20 

1,2-Dichlorobenzene 20 79 131 20 Dibromochloromethane 20 75 133 20 

1,2-Dichloroethane 20 79 126 20 Ethylbenzene 20 75 137 20 

1,2-Dichloropropane 20 77 132 20 m,p-Xylene 20 70 130 20 

1,3-Dichlorobenzene 20 77 130 20 Methyl tert-butyl ether 20 70 130 20 

1,4-Dichlorobenzene 20 74 125 20 Methylene chloride 20 80 126 20 

2-Butanone 40 70 130 20 o-Xylene 20 70 130 20 

2-Chloroethyl vinyl ether 40 57 120 20 Tetrachloroethene 20 80 132 20 

Acetone 40 65 140 20 Toluene 20 77 134 20 

Acrolein 40 60 120 20 Trans-1,2-Dichloroethene 20 80 130 20 

Acrylonitrile 100 60 120 20 Trans-1,3-Dichloropropene 20 76 128 20 

Benzene 20 75 134 20 Trichloroethene 20 80 132 20 

Bromodichloromethane 20 80 131 20 Trichlorofluoromethane 20 80 120 20 

Bromoform 20 65 135 20 Vinyl chloride 20 70 125 20 

Bromomethane 20 65 135 20 1,2-Dichloroethane-d4 (Surr) 20 65 138 20 

Carbon tetrachloride 20 78 129 20 4-BFB (Surr) 20 77 121 20 

Chlorobenzene 20 80 126 20 Toluene-d8 (Surr) 20 80 123 20 

64 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G8 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.10.1 - Method 8270D LCS Recovery Limits - Houston Facility 

Analyte - 8270 Water SPK 

μg/L 

Low High RPD Analyte - 8270 Soil SPK 

μg/Kg 

Low High RPD 

1,1 ́-Biphenyl 50 50 120 20 1,1 ́-Biphenyl 1667 55 120 30 

1,2,4,5-Tetrachlorobenzene 50 50 120 20 1,2,4,5-Tetrachlorobenzene 1667 55 120 30 

1,2,4-Trichlorobenzene 50 50 120 20 1,2,4-Trichlorobenzene 1667 55 120 30 

1,2-Dichlorobenzene 50 50 120 20 1,2-Dichlorobenzene 1667 55 120 30 

1,2-Dinitrobenzene 50 50 120 20 1,2-Dinitrobenzene 1667 40 130 30 

1,2-Diphenylhydrazine 50 55 120 20 1,2-Diphenylhydrazine 1667 55 120 30 

1,3-Dichlorobenzene 50 50 120 20 1,3-Dichlorobenzene 1667 55 120 30 

1,3-Dinitrobenzene 50 55 120 22 1,3-Dinitrobenzene 1667 55 120 30 

1,4-Dichlorobenzene 50 55 120 20 1,4-Dichlorobenzene 1667 55 120 30 

1,4-Dinitrobenzene 50 55 120 20 1,4-Dinitrobenzene 1667 40 130 30 

1,4-Dioxane 50 10 120 20 1,4-Dioxane 1667 15 120 30 

1,4-Naphthoquinone 50 55 120 20 1,4-Naphthoquinone 1667 55 120 30 

1-Chloronaphthalene 50 40 130 20 1-Chloronaphthalene 1667 50 125 30 

1-Methylnaphthalene 50 55 120 20 1-Methylnaphthalene 1667 55 120 30 

2,3,4,6-Tetrachlorophenol 50 55 120 20 2,3,4,6-Tetrachlorophenol 1667 55 120 30 

2,4,5-Trichlorophenol 100 50 120 20 2,4,5-Trichlorophenol 3333 55 120 30 

2,4,6-Trichlorophenol 100 50 120 20 2,4,6-Trichlorophenol 3333 55 120 30 

2,4-Dichlorophenol 100 50 120 20 2,4-Dichlorophenol 3333 55 120 30 

2,4-Dimethylphenol 100 50 120 20 2,4-Dimethylphenol 3333 55 125 30 

2,4-Dinitrophenol 100 40 120 20 2,4-Dinitrophenol 3333 40 125 30 

2,4-Dinitrotoluene 50 50 120 20 2,4-Dinitrotoluene 1667 55 125 30 

2,6-Dichlorophenol 100 50 120 20 2,6-Dichlorophenol 1667 55 120 30 

2,6-Dimethylphenol 50 50 120 20 2,6-Dimethylphenol 1667 55 120 30 

2,6-Dinitrotoluene 50 55 120 20 2,6-Dinitrotoluene 1667 55 120 30 

2-Chloronaphthalene 50 55 135 20 2-Chloronaphthalene 1667 55 145 30 

2-Chlorophenol 100 50 120 20 2-Chlorophenol 3333 55 120 30 

2-Chloroquinoxaline 50 55 120 20 2-Chloroquinoxaline 1667 55 120 30 

2-Methylnaphthalene 50 55 120 20 2-Methylnaphthalene 1667 55 120 30 

2-Methylphenol 100 50 120 20 2-Methylphenol 3333 55 120 30 

2-Nitroaniline 50 55 120 20 2-Nitroaniline 1667 55 130 30 

2-Nitrophenol 100 55 120 20 2-Nitrophenol 3333 55 120 30 

3&4-Methylphenol 150 55 120 20 3&4-Methylphenol 5000 55 120 30 

3,3 ́-Dichlorobenzidine 50 30 120 20 3,3 ́-Dichlorobenzidine 1667 32 125 30 

3-Methylcholanthrene 50 50 120 20 3-Methylcholanthrene 1667 55 125 30 

3-Nitroaniline 50 40 120 20 3-Nitroaniline 1667 43 120 30 

4,6-Dinitro-2-methylphenol 100 50 120 20 4,6-Dinitro-2-methylphenol 3333 50 130 30 

4-Bromophenyl phenyl ether 50 55 120 20 4-Bromophenyl phenyl ether 1667 55 120 30 

4-Bromopyrazole 100 40 120 20 4-Bromopyrazole 3333 50 125 30 

4-Chloro-3-methylphenol 100 50 120 20 4-Chloro-3-methylphenol 3333 55 120 30 

4-Chloroaniline 50 30 120 20 4-Chloroaniline 1667 30 120 30 

4-Chlorophenyl phenyl ether 50 55 120 20 4-Chlorophenyl phenyl ether 1667 55 120 30 

4-Nitroaniline 50 50 120 20 4-Nitroaniline 1667 55 120 30 

4-Nitrophenol 100 45 120 20 4-Nitrophenol 3333 50 130 30 

4-Nitroquinoline-1-oxide 50 50 130 20 4-Nitroquinoline-1-oxide 1667 50 150 30 

7,12-Dimethylbenz(a)anthracene 50 45 120 20 7,12-Dimethylbenz(a)anthracene 1667 55 120 30 

Acenaphthene 50 55 120 20 Acenaphthene 1667 55 120 30 

Acenaphthylene 50 55 120 20 Acenaphthylene 1667 55 120 30 

Acetophenone 50 40 120 20 Acetophenone 1667 54 120 30 

Aniline 50 30 120 20 Aniline 1667 25 120 30 

65 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G9 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.10.1 - Method 8270D LCS Recovery Limits - Houston Facility 

Analyte - 8270 Water SPK 

μg/L 

Low High RPD Analyte - 8270 Soil SPK 

μg/Kg 

Low High RPD 

Anthracene 50 55 120 20 Anthracene 1667 55 120 30 

Aramite 50 50 120 20 Aramite 1667 55 142 30 

Atrazine 50 50 120 20 Atrazine 1667 55 127 30 

Azobenzene 50 50 130 20 Azobenzene 1667 55 120 30 

Benz(a)anthracene 50 55 120 20 Benz(a)anthracene 1667 55 125 30 

Benzaldehyde 50 45 120 20 Benzaldehyde 1667 20 132 30 

Benzidine 50 10 120 20 Benzidine 1667 10 120 30 

Benzo(a)pyrene 50 55 120 20 Benzo(a)pyrene 1667 55 120 30 

Benzo(b)fluoranthene 50 55 120 20 Benzo(b)fluoranthene 1667 55 125 30 

Benzo(g,h,i)perylene 50 55 120 20 Benzo(g,h,i)perylene 1667 55 120 30 

Benzo(k)fluoranthene 50 55 120 20 Benzo(k)fluoranthene 1667 55 130 30 

Benzoic acid 50 20 120 20 Benzoic acid 1667 15 130 30 

Benzyl alcohol 50 50 120 20 Benzyl alcohol 1667 55 120 30 

Bis(2-chloroethoxy) methane 50 55 120 20 Bis(2-chloroethoxy) methane 1667 55 120 30 

Bis(2-chloroethyl)ether 50 50 120 20 Bis(2-chloroethyl)ether 1667 55 120 30 

Bis(2-chloroisopropyl)ether 50 50 120 20 Bis(2-chloroisopropyl)ether 1667 55 120 30 

Bis(2-ethylhexyl)phthalate 50 50 120 20 Bis(2-ethylhexyl)phthalate 1667 55 125 30 

Butyl benzyl phthalate 50 50 120 20 Butyl benzyl phthalate 1667 55 125 30 

Caprolactam 50 30 120 20 Caprolactam 1667 55 140 30 

Carbazole 50 55 120 20 Carbazole 1667 55 120 30 

Chlorobenzilate 50 55 120 20 Chlorobenzilate 1667 55 120 30 

Chlorothalonil 50 55 120 20 Chlorothalonil 1667 55 140 30 

Chrysene 50 55 120 20 Chrysene 1667 55 125 30 

Dacthal 50 55 120 20 Dacthal 1667 55 125 30 

Di-n-butyl phthalate 50 55 120 20 Di-n-butyl phthalate 1667 55 125 30 

Di-n-octyl phthalate 50 50 120 20 Di-n-octyl phthalate 1667 55 130 30 

Diallate 50 55 120 20 Diallate 1667 50 140 30 

Dibenz(a,h)anthracene 50 55 120 20 Dibenz(a,h)anthracene 1667 55 120 30 

Dibenz(a,j)acridine 50 55 120 20 Dibenz(a,j)acridine 1667 40 130 30 

Dibenzofuran 50 55 120 20 Dibenzofuran 1667 55 120 30 

Diethyl phthalate 50 55 120 20 Diethyl phthalate 1667 55 120 30 

Dimethyl phthalate 50 55 120 20 Dimethyl phthalate 1667 55 120 30 

Diphenyl ether 50 55 120 20 Diphenyl ether 1667 55 120 30 

Diphenylamine 50 55 120 20 Diphenylamine 1667 55 120 30 

Ethyl methacrylate 50 45 120 20 Ethyl methacrylate 1667 35 120 30 

Ethyl methanesulfonate 50 50 120 20 Ethyl methanesulfonate 1667 55 120 30 

Fluoranthene 50 55 120 20 Fluoranthene 1667 55 125 30 

Fluorene 50 55 120 20 Fluorene 1667 55 120 30 

Hexachlorobenzene 50 55 120 20 Hexachlorobenzene 1667 55 120 30 

Hexachlorobutadiene 50 55 120 20 Hexachlorobutadiene 1667 55 120 30 

Hexachlorocyclopentadiene 50 50 120 20 Hexachlorocyclopentadiene 1667 50 120 30 

Hexachloroethane 50 55 120 20 Hexachloroethane 1667 55 120 30 

Hexachloropropene 50 55 120 20 Hexachloropropene 1337 55 120 30 

Indeno(1,2,3-cd)pyrene 50 55 120 20 Indeno(1,2,3-cd)pyrene 1667 55 125 30 

Isodrin 50 55 120 20 Isodrin 1667 55 120 30 

Isophorone 50 55 120 20 Isophorone 1667 55 120 30 

Isophthalonitrile 50 55 120 20 Isophthalonitrile 1667 50 120 30 

Isosafrole 50 55 120 20 Isosafrole 1667 45 140 30 

Kepone 50 15 140 20 Kepone 1667 20 120 30 

66 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G10 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.10.1 - Method 8270D LCS Recovery Limits - Houston Facility 

Analyte - 8270 Water SPK 

μg/L 

Low High RPD Analyte - 8270 Soil SPK 

μg/Kg 

Low High RPD 

Methapyrilene 50 40 130 20 Methapyrilene 1667 40 130 30 

Methyl methanesulfonate 50 50 120 20 Methyl methanesulfonate 1667 55 120 30 

N-Nitrosodiethylamine 50 40 130 20 N-Nitrosodiethylamine 1667 40 130 30 

N-Nitroso-di-n-butylamine 50 40 130 20 N-Nitroso-di-n-butylamine 1667 40 130 30 

N-Nitrosodi-n-propylamine 50 50 120 20 N-Nitrosodi-n-propylamine 1667 55 120 30 

N-Nitrosodimethylamine 50 45 120 20 N-Nitrosodimethylamine 1667 45 120 30 

N-Nitrosomethylethylamine 50 40 130 20 N-Nitrosomethylethylamine 1667 40 130 30 

N-Nitrosodiphenylamine 50 55 120 20 N-Nitrosodiphenylamine 1667 55 120 30 

N-Nitrosomorpholine 50 40 130 20 N-Nitrosomorpholine 1667 40 130 30 

N-Nitrosopiperidine 50 40 130 20 N-Nitrosopiperidine 1667 40 130 30 

N-Nitrosopyrrolidine 50 40 130 20 N-Nitrosopyrrolidine 1667 40 130 30 

Naphthalene 50 55 120 20 Naphthalene 1667 55 120 30 

Nitrobenzene 50 55 120 20 Nitrobenzene 1667 55 120 30 

Pentachlorobenzene 50 55 120 20 Pentachlorobenzene 1667 55 120 30 

Pentachloroethane 50 50 120 20 Pentachloroethane 1667 55 120 30 

Pentachloronitrobenzene 50 50 120 20 Pentachloronitrobenzene 1667 55 140 30 

Pentachlorophenol 100 55 120 20 Pentachlorophenol 3333 50 135 30 

Phenacetin 50 55 120 20 Phenacetin 1667 55 125 30 

Phenanthrene 50 55 120 20 Phenanthrene 1667 55 120 30 

Phenol 100 50 120 20 Phenol 3333 50 120 30 

Pronamide 50 55 120 20 Pronamide 1667 55 122 30 

Pyrazole 100 35 120 20 Pyrazole 1667 40 125 30 

Pyrene 50 55 120 20 Pyrene 1667 55 125 30 

Pyridine 50 35 120 20 Pyridine 1667 30 120 30 

Quinazoline 50 55 120 20 Quinazoline 1667 55 135 30 

Quinoline 50 55 120 20 Quinoline 1667 55 130 30 

Safrole 50 55 120 20 Safrole 1667 55 120 30 

Sym-Trinitrobenzene 58 55 120 20 Sym-Trinitrobenzene 1667 60 160 30 

2,4,6-Tribromophenol 100 42 124 20 2,4,6-Tribromophenol 3333 36 126 30 

2-Fluorobiphenyl 100 48 120 20 2-Fluorobiphenyl 3333 43 125 30 

2-Fluorophenol 100 20 120 20 2-Fluorophenol 3333 37 125 30 

4-Terphenyl-d14 100 51 135 20 4-Terphenyl-d14 3333 32 125 30 

Nitrobenzene-d5 100 41 120 20 Nitrobenzene-d5 3333 37 125 30 

Phenol-d6 100 20 120 20 Phenol-d6 3333 40 125 30 

Table G.10.2 - Method 8270D Low Level LCS Recovery Limits – Houston Facility 

Analyte - 8270 Water SPK 

μg/L 

Low High RPD Analyte - 8270 Soil SPK 

μg/Kg 

Low High RPD 

1,1 ́-Biphenyl 5 45 125 20 1,1 ́-Biphenyl 166.7 50 120 30 

1,2,4-Trichlorobenzene 5 45 120 20 1,2,4-Trichlorobenzene 166.7 50 120 30 

1,2-Dichlorobenzene 5 45 120 20 1,2-Dichlorobenzene 166.7 50 120 30 

1,2-Diphenylhydrazine 5 39 127 20 1,2-Diphenylhydrazine 166.7 50 135 30 

1,3-Dichlorobenzene 5 45 120 20 1,3-Dichlorobenzene 166.7 50 120 30 

1,4-Dichlorobenzene 5 40 120 20 1,4-Dichlorobenzene 166.7 50 120 30 

1-Methylnaphthalene 5 45 120 20 1-Methylnaphthalene 166.7 50 120 30 

2,4,5-Trichlorophenol 5 46 120 20 2,4,5-Trichlorophenol 166.7 45 127 30 

2,4,6-Trichlorophenol 5 42 120 20 2,4,6-Trichlorophenol 166.7 45 130 30 

2,4-Dichlorophenol 5 49 120 20 2,4-Dichlorophenol 166.7 45 125 30 

2,4-Dimethylphenol 5 35 120 20 2,4-Dimethylphenol 166.7 45 120 30 

67 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G11 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.10.2 - Method 8270D Low Level LCS Recovery Limits – Houston Facility 

Analyte - 8270 Water SPK 

μg/L 

Low High RPD Analyte - 8270 Soil SPK 

μg/Kg 

Low High RPD 

2,4-Dinitrophenol 5 15 120 20 2,4-Dinitrophenol 166.7 10 126 30 

2,4-Dinitrotoluene 5 50 122 20 2,4-Dinitrotoluene 166.7 50 130 30 

2,6-Dinitrotoluene 5 50 120 20 2,6-Dinitrotoluene 166.7 50 125 30 

2-Chloronaphthalene 5 50 120 20 2-Chloronaphthalene 166.7 50 145 30 

2-Chlorophenol 5 50 120 20 2-Chlorophenol 166.7 45 120 30 

2-Methylnaphthalene 5 50 120 20 2-Methylnaphthalene 166.7 50 120 30 

2-Methylphenol 5 45 120 20 2-Methylphenol 166.7 45 120 30 

2-Nitroaniline 5 28 139 20 2-Nitroaniline 166.7 45 138 30 

2-Nitrophenol 5 40 120 20 2-Nitrophenol 166.7 45 125 30 

3&4-Methylphenol 5 35 120 20 3&4-Methylphenol 166.7 45 120 30 

3,3 ́-Dichlorobenzidine 5 15 120 20 3,3 ́-Dichlorobenzidine 166.7 15 120 30 

3-Nitroaniline 5 30 120 20 3-Nitroaniline 166.7 40 120 30 

4,6-Dinitro-2-methylphenol 5 25 121 20 4,6-Dinitro-2-methylphenol 166.7 15 135 30 

4-Bromophenyl phenyl ether 5 45 120 20 4-Bromophenyl phenyl ether 166.7 50 125 30 

4-Chloro-3-methylphenol 5 47 120 20 4-Chloro-3-methylphenol 166.7 45 130 30 

4-Chloroaniline 5 20 120 20 4-Chloroaniline 166.7 20 120 30 

4-Chlorophenyl phenyl ether 5 50 120 20 4-Chlorophenyl phenyl ether 166.7 50 120 30 

4-Nitroaniline 5 30 133 20 4-Nitroaniline 166.7 50 127 30 

4-Nitrophenol 5 30 130 20 4-Nitrophenol 166.7 40 147 30 

Acenaphthene 5 45 120 20 Acenaphthene 166.7 50 120 30 

Acenaphthylene 5 47 120 20 Acenaphthylene 166.7 50 120 30 

Acetophenone 5 40 120 20 Acetophenone 166.7 50 120 30 

Aniline 5 10 120 20 Aniline 166.7 10 135 30 

Anthracene 5 45 120 20 Anthracene 166.7 50 123 30 

Atrazine 5 40 130 20 Atrazine 166.7 29 148 30 

Benz(a)anthracene 5 40 120 20 Benz(a)anthracene 166.7 50 131 30 

Benzaldehyde 5 35 130 20 Benzaldehyde 166.7 45 120 30 

Benzidine 5 10 120 20 Benzidine 166.7 10 120 30 

Benzo(a)pyrene 5 45 120 20 Benzo(a)pyrene 166.7 50 130 30 

Benzo(b)fluoranthene 5 50 120 20 Benzo(b)fluoranthene 166.7 50 137 30 

Benzo(g,h,i)perylene 5 42 127 20 Benzo(g,h,i)perylene 166.7 50 130 30 

Benzo(k)fluoranthene 5 45 127 20 Benzo(k)fluoranthene 166.7 50 143 30 

Benzoic acid 5 10 110 20 Benzoic acid 166.7 10 120 30 

Benzyl alcohol 5 35 122 20 Benzyl alcohol 166.7 40 143 30 

Bis(2-chloroethoxy) methane 5 45 120 20 Bis(2-chloroethoxy) methane 166.7 50 120 30 

Bis(2-chloroethyl)ether 5 37 121 20 Bis(2-chloroethyl)ether 166.7 45 127 30 

Bis(2-chloroisopropyl)ether 5 40 120 20 Bis(2-chloroisopropyl)ether 166.7 50 120 30 

Bis(2-ethylhexyl)phthalate 5 40 139 20 Bis(2-ethylhexyl)phthalate 166.7 21 148 30 

Butyl benzyl phthalate 5 47 123 20 Butyl benzyl phthalate 166.7 50 136 30 

Caprolactam 5 35 134 20 Caprolactam 166.7 50 135 30 

Carbazole 5 42 128 20 Carbazole 166.7 50 143 30 

Chrysene 5 43 120 20 Chrysene 166.7 50 130 30 

Di-n-butyl phthalate 5 45 123 20 Di-n-butyl phthalate 166.7 50 140 30 

Di-n-octyl phthalate 5 45 129 20 Di-n-octyl phthalate 166.7 50 140 30 

Dibenz(a,h)anthracene 5 45 120 20 Dibenz(a,h)anthracene 166.7 50 130 30 

Dibenzofuran 5 50 120 20 Dibenzofuran 166.7 50 125 30 

Diethyl phthalate 5 41 120 20 Diethyl phthalate 166.7 50 125 30 

Dimethyl phthalate 5 40 122 20 Dimethyl phthalate 166.7 50 125 30 

Diphenylamine 5 45 120 20 Diphenylamine 166.7 45 132 30 

68 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G12 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.10.2 - Method 8270D Low Level LCS Recovery Limits – Houston Facility 

Analyte - 8270 Water SPK 

μg/L 

Low High RPD Analyte - 8270 Soil SPK 

μg/Kg 

Low High RPD 

Fluoranthene 5 45 125 20 Fluoranthene 166.7 50 131 30 

Fluorene 5 49 120 20 Fluorene 166.7 50 125 30 

Hexachlorobenzene 5 48 120 20 Hexachlorobenzene 166.7 50 124 30 

Hexachlorobutadiene 5 40 120 20 Hexachlorobutadiene 166.7 50 125 30 

Hexachlorocyclopentadiene 5 34 136 20 Hexachlorocyclopentadiene 166.7 45 135 30 

Hexachloroethane 5 40 120 20 Hexachloroethane 166.7 45 125 30 

Indeno(1,2,3-cd)pyrene 5 41 128 20 Indeno(1,2,3-cd)pyrene 166.7 45 139 30 

Isophorone 5 40 121 20 Isophorone 166.7 45 130 30 

N-Nitrosodi-n-propylamine 5 30 140 20 N-Nitrosodi-n-propylamine 166.7 45 120 30 

N-Nitrosodimethylamine 5 40 120 20 N-Nitrosodimethylamine 166.7 20 140 30 

N-Nitrosodiphenylamine 5 40 125 20 N-Nitrosodiphenylamine 166.7 50 130 30 

Naphthalene 5 45 120 20 Naphthalene 166.7 50 125 30 

Nitrobenzene 5 44 120 20 Nitrobenzene 166.7 50 125 30 

Pentachlorophenol 5 19 121 20 Pentachlorophenol 166.7 23 136 30 

Phenanthrene 5 45 121 20 Phenanthrene 166.7 50 125 30 

Phenol 5 20 124 20 Phenol 166.7 45 130 30 

Pyrene 5 40 130 20 Pyrene 166.7 45 130 30 

Pyridine 5 15 130 20 Pyridine 166.7 15 120 30 

Quinoline 5 45 120 20 Quinoline 166.7 45 130 30 

2,4,6-Tribromophenol 5 34 129 20 2,4,6-Tribromophenol 166.7 36 126 30 

2-Fluorobiphenyl 5 40 125 20 2-Fluorobiphenyl 166.7 43 125 30 

2-Fluorophenol 5 20 120 20 2-Fluorophenol 166.7 37 125 30 

4-Terphenyl-d14 5 40 135 20 4-Terphenyl-d14 166.7 32 125 30 

Nitrobenzene-d5 5 41 120 20 Nitrobenzene-d5 166.7 37 125 30 

Phenol-d6 5 20 120 20 Phenol-d6 166.7 40 125 30 

Table G.11 - Method 625 LCS Recovery Limits, Houston Facility 

Analyte - 625 Water SPK 

μg/L 

Low High RPD Analyte - 625 Water SPK 

μg/L 

Low High RPD 

1,2,4-Trichlorobenzene 100 54 120 20 Benzyl alcohol 100 49 120 20 

1,2-Dichlorobenzene 100 49 120 20 Bis(2-chloroethoxy) methane 100 54 120 20 

1,2-Diphenylhydrazine 100 55 134 20 Bis(2-chloroethyl)ether 100 55 120 20 

1,3-Dichlorobenzene 100 55 120 20 Bis(2-chloroisopropyl)ether 100 48 120 20 

1,4-Dichlorobenzene 100 55 120 20 Bis(2-ethylhexyl)phthalate 100 50 120 20 

2,4,5-Trichlorophenol 100 52 120 20 Butyl benzyl phthalate 100 51 120 20 

2,4,6-Trichlorophenol 100 55 120 20 Carbazole 100 55 120 20 

2,4-Dichlorophenol 100 53 120 20 Chrysene 100 52 120 20 

2,4-Dimethylphenol 100 53 120 20 Di-n-butyl phthalate 100 54 120 20 

2,4-Dinitrophenol 100 47 120 20 Di-n-octyl phthalate 100 49 120 20 

2,4-Dinitrotoluene 100 55 120 20 Dibenz(a,h)anthracene 100 55 120 20 

2,6-Dinitrotoluene 100 55 120 20 Dibenzofuran 100 55 120 20 

2-Chloronaphthalene 100 55 125 20 Diethyl phthalate 100 55 120 20 

2-Chlorophenol 100 54 120 20 Dimethyl phthalate 100 55 120 20 

2-Methylnaphthalene 100 46 120 20 Diphenylamine 100 52 120 20 

2-Methylphenol 100 53 120 20 Fluoranthene 100 55 120 20 

2-Nitroaniline 100 53 123 20 Fluorene 100 55 120 20 

2-Nitrophenol 100 53 120 20 Hexachlorobenzene 100 54 120 20 

3&4-Methylphenol 100 48 120 20 Hexachlorobutadiene 100 51 120 20 

3,3 ́-Dichlorobenzidine 100 25 120 20 Hexachlorocyclopentadiene 100 48 120 20 

69 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G13 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

Table G.11 - Method 625 LCS Recovery Limits, Houston Facility 

Analyte - 625 Water SPK 

μg/L 

Low High RPD Analyte - 625 Water SPK 

μg/L 

Low High RPD 

3-Nitroaniline 100 26 120 20 Hexachloroethane 100 54 120 20 

4,6-Dinitro-2-methylphenol 100 51 121 20 Indeno(1,2,3-cd)pyrene 100 51 120 20 

4-Bromophenyl phenyl ether 100 49 120 20 Isophorone 100 55 120 20 

4-Chloro-3-methylphenol 100 51 120 20 N-Nitrosodi-n-propylamine 100 55 120 20 

4-Chloroaniline 100 21 120 20 N-Nitrosodimethylamine 100 42 120 20 

4-Chlorophenyl phenyl ether 100 56 120 20 N-Nitrosodiphenylamine 100 52 120 20 

4-Nitroaniline 100 47 120 20 Naphthalene 100 55 120 20 

4-Nitrophenol 100 26 133 20 Nitrobenzene 100 40 124 20 

Acenaphthene 100 55 120 20 Pentachlorophenol 100 45 125 20 

Acenaphthylene 100 55 120 20 Phenanthrene 100 55 120 20 

Anthracene 100 55 120 20 Phenol 100 38 120 20 

Benz(a)anthracene 100 53 120 20 Pyrene 50 54 120 20 

Benzidine 100 10 120 20 2,4,6-Tribromophenol 100 42 124 20 

Benzo(a)pyrene 100 55 120 20 2-Fluorobiphenyl 100 48 120 20 

Benzo(b)fluoranthene 100 54 120 20 2-Fluorophenol 100 20 120 20 

Benzo(g,h,i)perylene 100 55 120 20 4-Terphenyl-d14 100 51 135 20 

Benzo(k)fluoranthene 100 50 120 20 Nitrobenzene-d5 100 41 120 20 

Benzoic acid 100 24 131 20 Phenol-d6 100 20 120 20 

Table G.12 - SW 8330B LCS Recovery Limits – Houston Facility 

Analyte – Water Matrix SPK 

μg/L 

Low High RPD Analyte – Soil Matrix SPK 

μg/Kg 

Low High RPD 

HMX 3.25 60 120 20 HMX 2500 60 125 30 

RDX 3.25 50 120 20 RDX 2500 60 130 30 

1,3,5-Trinitrobenzene 3.25 60 125 20 1,3,5-Trinitrobenzene 2500 60 125 30 

1,3-Dinitrobenzene 3.25 55 120 20 1,3-Dinitrobenzene 2500 60 125 30 

Tetryl 3.25 45 140 20 Tetryl 2500 45 140 30 

Nitrobenzene 3.25 55 120 20 Nitrobenzene 2500 60 120 30 

2,4,6-Trinitrotoluene 3.25 60 130 20 2,4,6-Trinitrotoluene 2500 60 130 30 

4-Amino-2,6-dinitrotoluene 3.25 55 120 20 4-Amino-2,6-dinitrotoluene 2500 60 125 30 

2-Amino-4, 6-dinitrotoluene 3.25 55 120 20 2-Amino-4, 6-dinitrotoluene 2500 60 125 30 

2,4-Dinitrotoluene 3.25 60 120 20 2,4-Dinitrotoluene 2500 60 125 30 

2,6-Dinitrotoluene 3.25 60 125 20 2,6-Dinitrotoluene 2500 60 120 30 

2-Nitrotoluene 3.25 55 125 20 2-Nitrotoluene 2500 60 125 30 

3-Nitrotoluene 3.25 55 120 20 3-Nitrotoluene 2500 60 120 30 

4-Nitrotoluene 3.25 55 120 20 4-Nitrotoluene 2500 60 125 30 

1,2-DNB (Surr) 3.25 55 140 20 1,2-DNB (Surr) 2500 50 150 30 

Table G.13.1 - SW 8315A LCS Recovery Limits - Houston Facility

Analyte – Water Matrix SPK 

μg/L

Low High RPD Analyte – Soil Matrix SPK 

μg/Kg

Low High RPD 

Formaldehyde 50 60 120 20 Formaldehyde 1000 70 130 30 

Table G.13.2 - SW 8316 LCS Recovery Limits – Houston Facility 

Analyte – Water Matrix SPK 

μg/L

Low High RPD Analyte – Soil Matrix SPK 

μg/Kg

Low High RPD 

Acrylamide 25 60 120 20 Acrylamide 25 60 120 30 

70 g:\2010\0102974\15096H(Att2-AppA2).pdf
HS-QA Plan-Rev08.0 -Appendix C

Effective: 09/01/2009 

 Page G14 of 13 

© 2009 ALS Laboratory Group - All Rights Reserved 

TABLE G. 14 - NUMBER OF ALLOWABLE SPORADIC MARGINAL EXCEEDANCES

Number of analytes Sporadic Marginal Exceedances Allowed 

0-11 0 

11-30 1 

31-50 2 

51-70 3 

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ALS Laboratory Group Company Profile 

Attachment 3 

August 12, 2010 

Project No. 0102974 

Environmental Resources Management Southwest, Inc. 

15810 Park Ten Place, Suite 300 

Houston, Texas 77084-5140 

(281) 600-1000 
Corporate Profile

ALS is a diversified international analytical laboratory group which first 

established its operations in Queensland, Australia in 1975. With 160 

locations and in excess of 6,000 staff operating in 40 countries throughout Australia, North America, South America, Africa, Europe and Asia, the 

company is now one of the largest analytical laboratory groups in the 

world.

ALS provides a broad range of sophisticated, state of the art services to 

four main market segments; mining and mineral exploration, environmental monitoring, equipment maintenance through used lubricant analysis, 

and commodity analysis & certification. 

With a long term commitment to: 

•	 Quality 

•	 Service 

•	 Innovation 

•	 ALS has remained at the forefront of analytical chemistry and built an 

enviable reputation in its target markets. 

ALS embraces a consistent global approach to:

•	 Quality Assurance 

•	 Human Resources 

•	 Occupational Health and Safety 

•	 Environmental Best Practices 

•	 All ALS laboratories operate in compliance with ISO17025, with dedicated Quality Control Chemists in each major laboratory, a dedicated 

Quality 

Control Group in each region of the world, and a Global Technical 

Manager for each service area in which the company operates. As a 

professional services organisation, ALS is committed to the ongoing 

professional development of all staff through peer interaction as well 

as in-house and external training Programs. ALS operates a proactive 

global OHS&E program that ensures consistent compliance that is in 

excess of local regulatory requirements, throughout the world.

ALS is a wholly owned subsidiary of Campbell Brothers Ltd, an Australian 

based public company that began operations in 1863.

www.alsglobal.com

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www.alsglobal.com

Environmental Division Overview

ALS Laboratory Group’s (ALS) Environmental Division is one of the largest, most geographically diverse 

environmental testing companies in the world. Currently we have over 40 laboratories strategically 

located throughout Asia, Australia, Europe, North America and South America to provide our clients 

with analytical and technical support for local and international projects.

ALS’s Environmental Division provides reliable analytical testing data to assist consulting and 

engineering firms, industry, and governments around the world in making informed decisions about 

their environmental projects. Our comprehensive range of environmental testing and technical support 

services is complemented by a solid commitment to quality and customer service.

Benefits of Using ALS 

The depth of technical and management expertise at ALS allows us to deliver a consistently high level 

of service to our clients. Our commitment to good science and personal service is backed by a sound 

quality program. Each laboratory within the ALS network has evolved to meet the needs of local clientele, and is involved in accreditation or other recognition programs pertinent to its own specialized 

testing services. Accreditations are held for specific tests as related on each lab’s Scope of Accreditation. To obtain copies of any of our Scopes of Accreditation follow the location links on this website, 

refer to the websites of our accrediting bodies, or contact your ALS client service representative.

Additional benefits include:

•	 Rapid turnaround times to keep projects on schedule 

•	 Project mobilization assistance to ensure we provide the information you require 

•	 Extensive technical resources to help solve your environmental problems 

•	 Assistance with data interpretation to help you draw informed conclusions 

•	 Extensive experience with a wide range of clients and environmental programs 

•	 Direct electronic data transfer of analytical results to your database 

•	 Ease of communication with all personnel, including senior management, for rapid issue resolution 

www.alsenviro.com

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