; 

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r Ji~D-t6CJ Report of an ... 

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. - Emission Study I . 

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.. performed for ... I . 

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.. Michigan Division . l. U.S. Brick 

l. Corunna, Michigan 

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' Kiln #1 L 

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March 29, 1995 

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L 010.07 

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L Network Environmental, Inc. 

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Grand Rapids, MI 

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Network Environmental, Inc. 

p.o. Box·202l 

Grand Rapids, MJ: 49501 

SOURCE EMISSION TESTING 

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at 

MICHIGAN OJ:Vl:SION, t1. S. BRICK 

CORUNNA, MICHIGAN · ~-

lULN tl SCRt1BBER--EX1!At1ST - ·-

DATE: -3-129/95 

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TABLE OF CONTENTS 

L Introduction 

rr. Presentation of Results 

ll.l Sulfur Dioxide (S02 ) Emission Results 

m. Discussion of Results -

IV. Source Description 

v. Sampling and Analytical ProtoCol 

-

A ppenc:li_ces 

l_ Exhaust Gas Parameters 

SO 2 Analyzer Output & Calibration Data 

L S02 Analyzer Specifications & Gas Certifications 

Field Data 

! Calculations 

Raw Data 

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B -. 

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I. INTRODUCTION 

Network Environmental, Inc. was retained by the Michigan Division of U.S. Brick in Corunna, Michigan, 

to perform an emission study on the exhaust of their Kiln #1. The purpose of the study was to document 

the sulfur dioxide (S02) emissions from the Kiln #1 exhaust in order to meet the testing requirements 

of MDNR Air Permit No. 902·91. 

The study was performed on March 29, 1995 by Bertram J. Smith and Vincent G. Schultes of Network 

Environmental, Inc.. The testing was performed in accordance with U.S. EPA Reference Method 6C for 

S02 • In addition, the exhaust gas parameters (air flow rate, temperature, moisture, and density) were . 

determined 

-, 

in accordance with U.S. EPA Reference Methods 1 through 4. · Assisting in the study was Mr. ~~ 

Bob Barranti of the Michigan Division of U.S. Brick. 

1 
ll. PRESENTATION OF RESULTS 

ll.1 TABLE 1 

SULFUR DIOXIDE (S02 ) EMISSION RESULTS 

KILN #1 EXHAUST . MICillGAN DMSION • U.S. BRICK 

CORUNNA, MICillGAN 

MARCH 29, 1995 

Air Flow Rate Concentration Mass Emission Rate 

Sample Time DSCFM PPM - LbS/Hr 

1 8:22-9:22 13,681 346.90 46.99 

2 9:34-10:34 13,891 351.57 48.36 

3 10:47·11:47 13,756 369.29 - 50.30 

AVERAGE 13,776 355.92 48.55 

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ill. DISCUSSION OF RESULTS 

The results of the sulfur dioxide (SO,) emission sampling are summarized in Table 1 (Section II.l) .. 

ill.1 SO, Emission Concentrations· The SO, concentrations were 346.90 parts per million on a dry 

basis (PPM) for sample one, 351.57 PPM for sample two, and 369.29 PPM .for sample three. The 

average of the three samples collected was 355.92 PPM. 

m.2 SO, Mass Emission Rates • The SO, Mass Emission Rates were 46.99 Lbs/Hr for sample one, 

48.36 Lbs!Hr for sample two, and 50.30 Lbs!Hr for sample three. The average of the three samples 

collected was 48.55 Lbs!Hr . 

IV. SOURCE DESCRIPTION 

The source tested was the exhaust of Kiln # 1. The kiln is gas fired. The exhaust from the k;ln passes . 

through an emission control system consisting of a cooler followed by a mixing chamber and th~n through 

a baghouse prior to exhausting to atmosphere through the exhaust stack. Lime is sprayed into the system 

between the cooler and the mixing chamber. 

On 3/29/95 Copper Bay bricks were fired They weigh on an average 4.lllbs per brick, Dry and there are 

11,120 bricks per car (equates to 45,703.2 lbs per car). There were also 2,688, Dry 'real' bricks per car 

at a weight of 0.69 lb per 'real' brick (equates to 1,854. 7 lbs per car). The total weight of e8ch car is 

approximately ~7,557.9 lbs per car. The kiln speed during the testing was 12 cars per day. The charge 

tin2es for 3/29/95 were as follows: 01:40, 03:40, 05:40, 09:40, 11:40, 13:40, 15:40, 17:40, 19:40, 21:40 and 

23:40. 

V. SAMPLING AND ANALYTICAL PROTOCOL 

V.1 Sulfur Dioxide 

The SO, determinations were performed in accordance with U.S. EPA Reference Method 6C. APSC· 

302 portable stack gas analyzer was used to monitor the Kiln # 1 exhaust. A heated teflon sample 

3 -· 
line was used to transport the exhaust gases from the stack to a gas conditioner to remove moisture 

and reduce the temperature. From the gas conditioner the stack gases were passed to the analyzer. 

The analyzer produces instantaneous readouts of the 802 concentrations (PPM). 

The analyzer was calibrated by direct injection prior to the testing. A span gas of 857.3 PPM was 

used to establish the initial instrument calibration. Calibration gases of 244.0 and 392.9 PPM were 

used to determine the calibration error of the analyzer. The sampling system (from the back of the 

stack probe to the analyzer) was injected using the 392.9 PPM calibration gas to determine the 

system bias. After each sample, a system zero and system injection of 392.9 PPM was performed to 

establish system drift and system bias during the test period. All calibration gases used were EPA 

Protocol 1 Certified. 

The analyzer was calibrated to the output of the data acquisition system (DAS) used to collect the 

data. A strip chart recorder was also used to record the data as a backup to the DAS. Three (3) 

samples were collected from the Kiln #1 exhaust. Each sample was sixty (60) IIiinutes in duration. 

The DAS output, strip chart recorder data, and calibration data can be found in APpendix B. The 

802 analyzer specifications and calibration gas certifications can be found in Appendix C. 

V.3 Exhaust Gas Parameters 

The exhaust gas parameters (air flow rate, temperature, moisture, and density) were determined in 

conjunction with the other sampling by employing U.S. EPA Reference Methods 1 through 4. A 

velocity traverse was performed during each 802 sample. All the quality assurance and quality 

control procedures listed in the methods were incorporated in the sampling and analysis.-

This report was prepared by: This report was reviewed by: 

f?!::C¥ ~~ David D. Engelhardt 

Project Manager Vice President 

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APP.ENDIXA 

EXHAUST GAS PARAMETERS · 
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Network Environmental, Inc. 

P.O. Box 2021 

Grand Rapids, JU 49501 

SOURCE EMISSION TESTING 

at 

MJ:CBIGAN DJ:Vl:SION, U.S. BIUCK 

CORUNNA, MICHIGAN 

!ULN tl SCRUBBER EXI!AIJST ( 1) 

DATE: 3/29/95 
r-

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I 

Network Environmental, Inc. 

STJMMARY OF EXIIAUST GAS PARAMETERS 

COMPANY NAME: KICBIGAN DIVISION, U.S. BIUCK 

COMPANY LOCATION: CORUNNA, KICBIGAN 

SOURCE NAME: KILN #1 SCRUBBER EXHAUST ( 1) 

SAMPLING STAFF: SMITB\SCBULTES 

SAMPLE NTJMBER 

G1. STACK RADIUS, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETIUC PRESSURE, in. BG. 

G4. STATIC PRESSURE IN STACK, in. B20 

G5. STACK GAS TEMPERATURE, deq. F 

G6 • AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: \ OXYGEN 

\ CARBON DIOXIDE 

\ CARBON MONOXIDE 

\ NITROGEN 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

Gll. DRY, @ STP, lbs./cu.ft. 

G12. WET, @ STP, lba./cu.ft. 

G13. WET, @ STACK CONDITIONS, lbs./cu.ft. 

G14. MOLECULAR WEIGHT, DRY, @ STP, lba. /mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

Gl7. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STANDARD CONDITIONS, DRY SCFM 

TEST DATE: 3/29/95 

1 

19.5 

8.30 

29.00 

0.49-

325 

0.664 

7.53 

0.00 

15.07 

3.40 

0.00 

81.53 

0.0754 

0.0732 

0.0478 

29.16 

2729 

22,637 

14,795 

13,681 

II 
Network Environmental, Inc. 

PITOT TRAVERSE DATA 

COMPANY NAME: MICHIGAN DIVISION, 0. S. BRICK TEST DATE: 3/29/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN U SCRUBBER EXBAOST ( 1) 

SAMPLING STAFF: SMITH\SCBOLTES 

RON NUMBER: 1 ' CARBON DIOXIDE: 

STACK RADIOS, in.: 19.5 ' OXYGEN: 

GAS TEMPERATURE, Deg F: 325 ' CARBON MONOXIDE: 

STATIC PRESSURE, in. H20: -.49 PITOT FACTOR: .82 

BAROMETRIC PRESSURE: 29 

' POINT VELOCITY PRESSURE, INCHES OF WATER 

P'l.'. LOCATION, PORT 

t INCHES 1 2 

1 1.71 0.32 0.31 

2 5.69 0.47 0.48 

3 11.54 0.50 0.50 

4 27.45 0.48 0.48 

5 3'3. 30 0.47 0.45 

6 37.28 0.44 0.42 

j) 
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Network Environmental, Inc. 

P.O. Box 2021 

Grand Rapids, HI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVJ:SION, U.S. BIUCK 

CORUNNA, MICHIGAN 

K:ILN U SCRUBBER EXHAUST ( 2) 

DATE: 3/29/95 

I-~ 
Network Environmental, Inc. 

SUMMARY OF EXHAUST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN t 1 SCRUBBER EXHAUST ( 2 ) 

SAMPLING STAFF: SMITH\SCBULTES 

SAMPLE NUMBER 

G1. STACK RADIUS, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETRIC PRESSURE, in. HG. 

G4. STATIC PRESSURE IN STACK, in. H20 

GS. STACK GAS TEMPERATURE, deg. F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: ts OXYGEN 

ts CARBON DIOXIDE 

ts CARBON MONOXIDE 

ts NITROGEN 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

G11. DRY, @ STP, lbs./cu.ft. 

G12. WE'l', @ STP, lbs./cu.ft. 

G13. WET, @ STACK CONDITIONS, lbs./cu.ft. 

G14. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

G17. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STANDARD CONDITIONS, DRY SCFM 

TEST DATE: 3/29/95 

1 

19.5 

8.30 

29.00 

0.48-

318 

0.671 

7.53 

o.oo 

15.07 

3.40 

o.oo 

81.53 

0.0754 

0.0732 

0.0483 

29.16 

2746 

22 '778 

15,022 

13,891 
Network Environmenta~, Inc. 

PITOT TRAVERSE DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 3/29/95 

COMPANY LOCATION: CORUIINA, MICHIGAN 

SOURCE NAME: JtiL!r U SCRUBBER EXIIAUST ( 2) 

SAMPLING S~: SMITB\SCBULTES 

RUN NUMBER: 1 - CARBON DIOXIDE: 

STACK RADIUS, in.: 19.5 - OXYGEN: 

GAS TEMPERATURE, Deg F: 318 - CARBON MONOXIDE: 

STATIC PRESSURE, in. B20: -.48 PITOT FACTOR: .82 

BAROMETRIC PRESSURE: 29 

POl: NT VELoCITY PRESSURE, :Z:NCBES OF WATER 

PT. LOCATION, PORT 

I INCHES 1 2 

1 l. 71 0.35 0.29 

2 5.69 0.50 0.47 

3 11.54 0.50 0.53 

4 27.45 0.50 0.49 

5 3!1.30 0.49 0.47 

6 37.28 0.44 0.41 

i 

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Network Environmental, Inc. 

P.O. Box 2021 

Grand Rapids, HI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVJ:SIOH, U.S. BlUCK 

CORDHNA, MICHIGAN 

KILN fl SCRUBBER EXBAUST (3) 

DATE: 3/29/95 

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Network Environmental, Inc. 

SUMMARY OF EXHAUST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN U SCRUBBER EXHAUST (3) 

SAMPLING STAFF: SMITH\SCBULTES 

SAMPLE NUMBER 

G1. STACK RADIUS, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETRIC PRESSURE, in. HG. 

G4. STATIC PRESSURE IN STACK, in. H20 

G5 • STACK GAS TEMPERATURE, deg. F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7 • PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: i OXYGEN 

i CARBON DIOXIDE 

t CARBON MONOXIDE 

i NITROGEN 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

Gll. DRY, @ STP, lbs./cu.ft. 

G12. WET, @ STP, lbs./cu.ft. 

G13. WET, @ STACK CONDITIONS, lbs./cu.ft. 

G14. MOLECULAR WEIGHT, DRY, @ STP, lba. /mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

G17. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STANDARD CONDITIONS, DRY SCF. 

TEST DATE: 3/29/95 

1 

19.5 

8.30 

29.00 

0.51-

311 

0.662 

7.53 

o.oo 

15.07 

3.40 

0.00 

81.53 

0.0754 

0.0732 

0.0487 

29.16 

2695 

22,355 

14,876 

13,756 

. 7 / / 
Network Environmental, Inc. 

I 

r PITOT TRAVERSE DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 3/29/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN tl SCRUBBER EXHAUST ( 3) 

SAMPLING STAFF: SMITH\SCBULTES 

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1 RUN NUMBER: 1 ~ CARBON DIOXIDE: 

STACK RADIUS, in.: 19.5 ~ OXYGEN: 

GAS TEMPERATURE, Deg F: 311 ~ CARBON MONOXIDE: 

STATIC PRESSURE, in. H20: -.51 PITOT FACTOR: .82 

BAROMETRIC PRESSURE: 29 

POINT VELoCITY PRESSURE, INCHES OF WATER 

PT. LOCATION, PORT 

t INCHES 1 2 

1 1.71 0.26 0.31 

2 5.69 0.44 0.47 

3 11.54 0.51 0. 51 

4 27.45 0.51 0.49 

5 33.30 0.49 0.45 

6 37.28 0.43 0.43 

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Network Environmental, Inc. 

ORSAT ANALYSIS DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 3/29/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN tl SCRUBBER EXHAUST 

SAMPLING STAFF: SMITB\SCBOLTES 

DATE OF ANALYSIS: 3/29/95 METHOD: MULTIPOINT INTEGRATED SAMPLE 

PART CARBON DIOXIDE OXYGEN CARBON .MONOXIDE 

SKPL CONT RON 

t t t FINAL INIT. ' FINAL INIT. ' FINAL INIT. ' 

1 1 1 3.4 0.0 3.4 18.4 3.4 15.0 18.4 18.4 o.o 

2 3.4 0.0 3.4 18.4 3.4 15.0 18.4 18.4 o.o 

3 3.4 0.0 3.4 18.6 3.4 15.2 18.6 18.6 o.o 

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APP.ENDIX B . 

S02 ANAL~R OUTPUT & CALIBRATION DATA 

- -~-- --- -- ····--· --·- ---------. ----· ·----~------·----·· ------~,------~ .,, ... 
i 

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' 

EMISSIONS TEST 

SAMPLING DATE: 03-29-1995 

COMPANY: US Brick 

SOURCE: Kiln #1 Scrubber Exh 

START S02 

RUN TIME (PPM) 

1 08:22 362 

2 09:34 370 

3 10:47 391 

~( 
Company: Michigan Division 

U.S. Brick 

Location: Corunna, Ml 

Source: Kiln #1 Exhaust 

Date: 3129/95 

Operator: Smith\Schultes 

Monitor: Pace 302 

Span Value (PPM): 0-1000 

Page#: 1 of 1 

Calibration Response, PPM Calibration 

.. Analyzer Gas Cone. Direct System Injection Cal. Error, Drift, % of Span PPM Injection Pretest Post 1 Post2 Post3 %of 

Span Gas 7:52 8:07 9:26 10:39 11:51 Test 1 Tesl2 Test 3 

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

244.0 247.0 256.0 0.30 

392.9 396.0 408.0 412.0 415.0 417.0 0.31 0.40 0.70 0.90 

• 857.3 857.0 869.0 

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-- --· --- --· ---

• AB Defined By EPA Method, This Value Must Be The Same AB The Relevant Direct InJection Value •• Run Zero and either mid or high calibration gas, whichever one is closer to aclual stack concentration 

Pretest 

0.00 

0.9 

1.2 

3.2 

Analyzer cal. error,% of span= (dir. inj. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% 

Sys

~ 

Drift,% 

System 

of 

bias,% 

span= 

of 

(relevant 

span= 

pastiest sys. inj. cal. response, PPM- sys. inj. pretest cal. response, PPM) x 100% I (span value, PP

(relevant sys. inj. cal. response, PPM- dir. lnj. cal. response, PPM) x 100% I (span value, PPM): Limit

,. r:J 
'ILENAME: USB5329.DTA 

~OMPANY: usbrick 

SOURCE: so2scrubber 

DATA LISTING 

------------------------------------------------------------------------------ :H&'INEL: 

PARAMETER: 

""NITS: 

LOPE: 

INTERCEPT: 

00 

S02 

PPM 

1000 

0 

------------------------------------------------------------------------------- 3-29-1995 08:22:20 364 

v3-29-1995 08:23:20 358 

03-29-1995 08:24:20 358 

3-29-1995 08:25:20 360 

3-29-1995 08:26:20 353 

03-29-1995 08:27:20 356 ~3-29-1995 08:28:20 360 

3-29-1995 08:29:20 367 

'J3-29-1995 08:30:20 368 

03-29-1995 08:31:20 363 

3-29-1995 08:32:20 362 

.3-29-1995 08:33:20 361 

03-29-1995 08:34:20 361 

3-29-1995 08:35:20 361 

3-29-1995 08:36:20 349 

03-29-1995 08:37:20 360 

"3-29-1995 08:38:20 361 

3-29-1995 08:39:20 358 

u3-29-1995 08:40:20 360 

03-29-1995 08:41:20 362 

•3-29-1995 08:42:20 363 

•3-29-1995 08:43:20 365 

03-29-1995 08:44:20 361 

"3-29-1995 08:45:20 359 

•3-29-1995 08:46:20 349 

03-29-1995 08:0:20 358 

03-29-1995 08:48:20 361 

·3-29-1995 08:49:20 356 

v3-29-1995 08:50:20 364 

03-29-1995 08:51:20 357 

13-29-1995 08:52:20 353 

•3-29-1995 08:53:20 358 

03-29-1995 08:54:20 359 

'13-29-1995 08:55:20 359 

•3-29-1995 08:56:20 360 

U3-29-1995 08:57:20 368 

03-29-1995 08:58:20 365 

3-29-1995 08:59:20 367 

.3-29-1995 09:00:20 367 

03-29-1995 09:01:20 366 

·3-29-1995 09:02:20 366 

3-29-1995 09:03:20 37 0 

03-29-1995 09:04:20 366 

"3-29-1995 09:05:20 369 

3-29-1995 09:06:20 363 

v3-29-1995 09:07:20 361 

03-29-1995 09:08:20 367 

3-29-1995 09:09:20 361 ~J.-~ 
03-29-1995 09:10:20 364 

"3-29-1995 09:11:20 364 

3-29-1995 09:12:20 360 

,3-29-1995 09:13:20 363 

03-29-1995 09:14:20 364 

3-29-1995 09:15:20 364 

.3-29-1995 09:16:20 346 

03-29-1995 09:17:20 361 

-3-29-1995 09:18:20 371 

3-29-1995 09:19:20 366 

)3-29-1995 09:20:20 370 

113-29-1995 09:21:20 365 

3-29-1995 09:34:29 370 

,3-29-1995 09:35:29 372 

03-29-1995 09:36:29 358 

3-29-1995 09:37:29 369 

3-29-1995 09:38:29 373 

J3-29-1995 09:39:29 374 

~3-29-1995 09:40:29 374 

3-29-1995 09:41:29 369 

!3-29-1995 09:42:29 373 

03-29-1995 09:43:29 259 

3-29-1995 09:44:29 181 

.3-29-1995 09:45:29 224 

03-29-1995 09:46:29 460 

3-29-1995 09:47:29 427 

3-29-1995 09:48:29 396 

)3-29-1995 09:49:29 376 

"3-29-1995 09:50:29 381 

3-29-1995 09:51:29 379 

J3-29-1995 09:52:29 376 

03-29-1995 09:53:29 37 5 

3-29-1995 09:54:29 37 3 

.3-29-1995 09:55:29 368 

03-29-1995 09:56:29 378 

. -3-29-1995 09:57:29 378 

3-29-1995 09:58:29 374 

)3-29-1995 09:59:29 372 

113-29-1995 10:00:29 377 

3-29-1995 10:01:29 367 

,3-29-1995 10:02:29 374 

03-29-1995 10:03:29 373 

13-29-1995 10:04:29 370 

13-29-1995 10:05:29 374 

)3-29-1995 10:06:29 371 

'13-29-1995 10:07:29 379 

13-29-1995 10:08:29 380 

13-29-1995 10:09:29 381 

03-29-1995 10:10:29 372 

13-29-1995 10:11:29 374 

13-29-1995 10:12:29 375 

03-29-1995 10:13:29 374 

13-29-1995 10:14:29 378 

13-29-1995 10:15:29 365 

J3-29-1995 10:16:29 370 

'13-29-1995 10:17:29 372. 

13-29-1995 10:18:29 382 

J3-29-1995 10:19:29 380 

03-29-1995 10:20:29 378 

13-29-1995 10:21:29 379 ~y 
03-29-1995 10:22:29 376 

"3-29-1995 10:23:29 376 

3-29-1995 10:24:2· 377 

v3-29-1995 10:25:2 369 

03-29-1995 10:26:: 376 

3-29-1995 10:27:2c 387 

3-29-1995 10:28:29 375 

03-29-1995 10:29:29 380 

~3-29-1995 10:30:29 384 

3-29-1995 10:31:29 383 

03-29-1995 10:32:29 37 5 

n3-29-1995 10:33:29 380 

3-29-1995 10:47:55 382 

v3-29-1995 10:48:55 382 

03-29-1995 10:49:55 382 

3-29-1995 10:50:55 382 

3-29-1995 10:51:55 384 

;)3-29-1995 10:52:55 384 

"3-29-1995 10:53:55 381 

3-29-1995 10:54:55 379 

J3-29-1995 10:55:55 395 

03-29-1995 10:56:55 395 

3-29-1995 10:57:55 401 

.3-29-1995 10:58:55 402 

03-29-1995 10:59:55 396 

·3-29-1995 11:00:55 396 

3-29-1995 11:01:55 401 

)3-29-1995 11:02:55 404 

"3-29-1995 11:03:55 398 

3-29-1995 11:04:55 395 

J3-29-1995 11:05:55 388 

03-29-1995 11:06:55 393 

3-29-1995 11:07:55 388 

3-29-1995 11:08:55 390 

)3-29-1995 11:09:55 383 

~3-29-1995 11:10:55 390 

3-29-1995 11:11:55 387 

)3-29-1995 11:12:55 384 

n3-29-1995 11:13:55 388 

3-29-1995 11:14:55 384 

.3-29-1995 11:15:55 376 

03-29-1995 11:16:~5 382 

3-29-1995 11:17:55 386 

3-29-1995 11:18:55 383 

)3-29-1995 11:19:55 384 

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'· · S02 ANAL'YZER SPECIFICATIONS & GAS CERTIFICATIONS . 

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TABLE I 

PSC 302 

SPECIFICATIONS 

_,-

-------------------------------------~---------------------------------------

RESPONSE TIME 

RESPONSE 

ACCUP.ACY * 

DRIFT * 

OUTPUTS 

RANGES 

POWER REQUIREMENTS 

W1PEO,A_TURE 

ENVIRONMENT 

(Operating) 

TYPE OF GAS 

<2 Minutes to 90% of Fu11 Sca1e 

Linear Within± 1% in Each Range 

Overa11 Accuracy ±2% 

Zero and Span t2% of Fu11 Sca1e 

0 - 1 Vo1t, 10,000 ohms minimum 4 - 20 mA, 250 ohms maximum 

XI, X3, X10 (See Appendix A) 

,115 Vac, 50/60Hz, 15 amps maximum 

40°F to 90°F 

CO Up to 50,000 PPM S02, NOx up to 150,000 PPM (See Appendix A) 02 Up to 50% 

. SAMPLE LINE 25Ft. E1ectrica11y Heated, Se1f Regu1ating, 20 ;1~ 

CALI8P.AT.ION FREQUENCY Every 24 Hours of Service 

SENSOR TYPE E1ectrochemica1 

SIZE . PSC 302 Monitor - 16". x 12" x 12" Accessory Case - 20" x 29" x 10" 

WEIGHT PSC 302 Monitor- 45 Lbs. with Ce1ls Accessory Case - 40 Lbs. 

-------------------------------------------------------------------------------

* Over 24 Hour Period' 
1.0 INTRODUCTION 

The Environmental Products' PSC 302 Portable Monitor System is caoable of simultaneously monitoring t'11o gases in concentrations up to 150,000 PPt1 from a 

single sample probe. The gases which can be monitored are NOx, SOz, CO and Oz. 

The system uses electrochemical sensors (cells) that operate on the fuel cell 

principle. In a typical sensor, shown in Figure 2, a gas sample ~iffuses through 

a semipermeable membrane, and comes in contact with a sensing electrode where it 

undergoes an oxidation or reduction reaction. This process generates an electrical current output which is linear and directly proportiona1 to the partial 

pressure of the gas that the sensor is designed to sense. This current is convert!!d to a voltage signal which operates a panel meter or outboard device, such· 

as a chart recorder or data logging system. 

Before att~mpting to operate the PSC 302 Ho~itor, the operator should read and 

und!!rstand this manual in order to obtain accurate results and not dama~e the 

monitor. 

2.0 SYSTE:'l DESCRIPTION AND SPECIFICATIONS 

Th!! PSC 302.Portab1e Monitor is designed to be easily transported by one person. 

It weighs less than 45 pounds, and is 16" L by 12" W by 12" H in size. The 

system will monitor concentrations of SOz, NOx, CO or Oz, depending on the sensors. 

installed 1n t"he system. The sample line, prcbe, filter, and calibration gases 

are contai,ned in the Accessory Case which ~1eighs less than 40 pounds, and measures 

20" W by 29" L by 10" H. The specifications for the monitor which accompanies 

this handbook are listed in Table I. 

The gas sample is drawn into the monitor through a heated line by a sample pump 

end then into the sample conditioner, see Drawing 751750. Within the conditioner, the gas is rapidly cooled below 45°F to remove moisture, which is expelled 

through a drain valve. The sample conditioner uses a solid state, thermostatically controlled thermoelectric device to dry the gas being sampled. The sample 

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2.0 SYSTE~ DESCRIPTION AND SPECIFICATIONS (Continued) 

~~en flows ~1rough the sample/calibrate valve and the monitor flow meter to the 

sensors. If an NOx sensor is used (and the sample contains SOz), the sample 

flows through. an SOz scrubber before the NOx sensor. Each sensor generates 

an electrical current.which is converted into a voltage signal to drive the 

monitor meters and other external devices as required. The monitor also provides a 4-20 mA current signal for this purpo?e. 

The PSC 302 monitor uses a 1 to 3 to 10 relationship for its range switch unless 

en optional analyzer board is installed (see Appendix A). If a 30-4 sensor 

is installed, it will read 1,000 PPM fullscale in low range, 3;000 PPM in midrange, and 10,000 PPM in high range. An Oz sensor will reads: full scale in 

low range, 15: in mid-range, and so: in high range. 

To calibrate the monitor, gases of known precise concentrations are connected 

to the sample/calibrate valve. Using this valve, each monitor channel can be 

set to zero using a zero gas such as air or Nz. After the zeroing process is 

complete, the valve is cycled to introduce a calibration gas which facilitates 

adjustment of each channel's span. 

Calibration gases must be regulated to approximately 5-8 PSIG before applying 

them to the·monitor input. If excessive pressure is applied to the sensors, 

it is possible that the membrane can be ruptured thus ruining the sensor. 

3.0 SYSTEM SETUP 

3.1 INSPE~TION AND PLACEMENT 

When the system is unpacked, check for shipping damage, be sure to check all 

items shipped in the accessory case (such as the sample line, probe and calibration gases). Make certain that the system conforms to the system configuration shown in Appendix A of this manual. Contact the factory if there is 

any damage or nonconformance before using. 
i. 

' 

2.0 Technical Daca 

Maxi:um sample gas flo~ race 

of each gas pach 

Operacicg pressure 

Sample gas ia.le~ ce::~pe:-acu:-e 

Sample gas ic.lec de.., poicc 

Sample gas ouclec e:ecperae:ure 

!".A.'< 2 -1 

- !".A.'< 2 

- accu:-acy 

Rutt::t ir.g- in ti:::e 

Dead space per gas pach 

•.. P:-essu:-e drop per gas paeh ' . 

Alcer~acive volcage 

Pove= consu:pcio~ 

BA·l"-~'< 2/9.87·1-2 

~"-"..:< 

!".A.'< 

250 

0,15 

0,5 

7 

2-1, Type 29 - 1 -

2 Tne 30 - 2 -

1/h ac 1 ba:- attd 20 

SCFM ac 14 psi 

2 ,5 bar 

35 psi 

and 

140 Degr c I 284 Degr F 

65 Degr C I 149 Degr F 

Deg:- c 

68 Degr 

+ 3 Deg:- C I 3?,0 Degr F 

ouclec ce::~peracu:-e gas pach 

No. lis 0,5 Degr C I 0,9 Deg:- F 

higher chan gas pach No. 2. 

F 

+!- 0,3 Degr. C I+!- 0,54 Degr F 

Digical display indica cor fot' 

eooli::.g bri:le ce:peracu:-e vich 

li:::ti c icg valt.:e sig::~al 

+!- 0,5 Deg:- c ac 0 ... 10 Degr c 

+!- 0,9 Degr F ac J2 .. so Degr F 

appro:<. 53 c::i:L 

approx. 8,36 cubic·icch 

a p ~:r:- o x. .. 25 c:ba:- ac 250 1/h 

app~o:c. 0,36 psi ac 0' 15 SCF}! 

115 v + lOi.. - lOi:. (60 +1·2) E: 

Code 01 

220 v + 101.. - 151. (50 +/-2) Ez 

Code OJ 

220 v + 151. ... - 51. (60 +1-2) E.: 

Code 04 

zppt'OX. 450 VA, 3,9 A ac 115 v 60 !!: 

approx. 440 VA, 2,0 A ac 220 v 50 !!: 

ap?t"OX:. 480 VA, 2,1 A ac 220 v 60 Hz 
BA-~JL' 219.87-l-J 

2.1 Envi~or.-ental capabilities 

Clicace g~oup 

Rela:ive h~idicy 

Cons. true ~ioc. 

!::!ouc.cing method 

.Di!:lE!:tSiOllS 

(Width x Depth x Heighc) 

Sample gas conc.eccions 

Cocdensac~ ouclec 

Deg::-ee of housing procection 

Proceccion class 

Ope~acive posicion 

ZZ whe~e Z • + 5 Deg::- C ••• +55 Deg::- c 

dto. Z • +41 Deg::- F ••• +131 Deg::- F 

co~::-esponds co DIM 40 0~0, LVE 

+ 5 Deg:- C 

+4t Deg:- F 

+ 4.5 "Deg::- C max. + 55 Deg~ ( 

+llJ Deg::- F max. +l3t Deg::-

* at+ 55 Degr C I +131 Deg::- F the 

maxi:uc Sai:?h gas flo" of K-1..'< Z 

(2 gas paths)· is 125 llh 1 0,075 sc~. 

-25 Deg~ C 

-13 Deg::- F 

+ 6 5 Deg:- C . 

+149 Degr F 

lo"e= chan 75i. annuaL ave::-ag• inte=:~eque~: 

and light condensation co1e~aced. 

360 X 335 X Z90 ~ 

Pipe 6 x 1 = 

O,ZJ6Z x 0,0394. inch 

Pipe lZ x l = 

0,4.724 x 0,0394. inch 

I? 22 co DIN 40 050 

I in acco~dance with DIN 57 700, pa~: l, 

VDE 0700, pa:-c 116.83 

inclination lo~er 5 Deg::-
• 

' ; ' 

J ' 

;• ' 

2.3 l".acerials 

Material ,of gas leading pares 

Material of housing 

2.4 Electrical connections 

Pover supply 

Poceneial free eoncaee 

2.S lleill:hc 

PVDF (Polyviaylidenfluoridi 

steel place, Color RAL lOlS 

po~er cord vtch shock proof plug 

coaneeeion lead 2 x 0,7S =: 

2 x 0,00l2 sqin 

appro:<. 26 kg. 
AGA Gas, Inc. 

CERTIFICATE OF ANALYSIS 

EPA PROTOCOL t1 

PERFORMED ACCORDING TO SECTION 3.0 •• 

FILE NUMBER: EPA1~85 

CYLINDER NUMBER: CC992~8 

PRESSURE: 2000 PSI 

PRODUCTION NUMBER: 03930967 

CERTIFICATION DATE: April 28, 1993 

EXPIRATION OAT!: October 28, 199~ 

CERTIFICATION PERIOD: 18 Months 

CERTIFIED 

COMPONENT 

Sulfur Dioxide 

CERTIFIED 

CONC. 

2H PPI'I 

BALANCE GAS: Nitrogen 

MfALYZ!R 

MAX!/MOD!L/S!RIALt 

Thermo electron/~0/ 

40-17472-170 

ANALYTICAL PRINCIPLE: Fluorescence 

REFERENCE STANDARD: 

MULTIPOINT 

CALIBRATION 

3/4/93 

SRM NUMBER 

GMIS 

CYLINDER NUMBER CONCENTRATION 

CC712i3 , 513.7 PPM 

ANALYSIS #1 ANALYST: M.R. DATE: ~-13-93 

ZERO REF. TEST DEVIATION 

GAS GAS GAS RESULT FROM THE 

(MV! (MV) (MV! (PPM! MEAN(%! 

o. 70 513.80 242.80 H2. 4 PPM 0.00' 

0.70 513.80 242.80 H2. 4 PPI'I 0.00' 

o. 70 513.80 242.80 H2. 4 PPM 0. 00, 

MEAN: 2-!2.-l PPM 

ANALYSIS #2 

ZERO REF. TEST 

GAS GAS GAS 

(MV! (MV) ( MV! 

-.86 511. ?0 2H. 70 

-.86 511. 90 2H. 70 

-.86 511.90 2H. 70 

MEAN: H6. 0 PPM 

ANALYST: M. R. DATE: 4-27-93 

DEVIATION 

RESULT FROM THE 

(PPM! MEAN (%! 

246.0 PPI'I 0.00' 

H6.0 PPI'I o.oo' 

H6. 0 PPI'I 0.00' 

~__;~---· MICHAEL SICKMILLER 

QUALITY CONTROL SUPERVISOR 

--------------------------------------------------------------------- -~5 r~~o,o~ ~"a• / 

ACA Gn r,c 

15-12' ... O,C\0•• J:lo.)(! 

..... ~ .. -- ,.. ..... ~·~11 
SPE.CIAL TY GAS DIVISION 

11711 S. Alameda St~et 

Los Angeles. CA 90059 

(213)564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: 

Airgas I Michigan Date' 19 December 1994 

P.O.' PG-0621 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC37899 Sulfur Dioxide 

Nitrogen 

Certification Period (months): 24 

Expiration Date: 19 December 1996 

Cylinder Pressure: 2000 psia 

DO NOT USE BELOW 150 PSIG 

400 PPM 

Balance 

392.9 PPM 

Balance 

ACTUAL 
SPECIALTY GAS DIVISION 

11711 S. Alameda Stn3et 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: Michigan Alrgas 

EPA Protocol Procedure IT! 

CYLINDER NO. CONSTITUENTS CONCENTRATION: 

CC·25694 Sul!ur Dloiide 

Nitrogen 

Certlncatlon Period (months): 24 

Expiration Date: 18 May 1996 

Cylinder Pressure: 2000 psla 

DO NOT USE BELOW !50 PS!G 

-----·--

800 PPM 

Balance 

Date: 18 May 1994 

P.O.: PG 0530 

NOMINAL 

857.3 PPM 

Balance 

ACTUAL 
-

L 

!: 

I. 

I 

-, 

I ; -

I_ 

I_ 

tL 

I 

I 

I_ 

I 

1. 

APPENDIXD 

FIELD DATA 
r 

NETWORK ENVIRONMENTAL, INC. Date: ~3.._./z,"'---q!.-f-!--'-'95,_,_ __ 

Pitot Traverse Data Form 

Clients: _._( /-.>) S..J-_6t:><ll~c::.K..~,__ __ 

Proj. No.: -------

Plant: -.!~~Lf'!:.!.:Ll ,.;~,J~.'I!__ __ __~\~vjh5~· --li~~~l!2.c~~:::::-'-------:----------­

statt 13...j € J. .J 

3q .. ~ 

Stack Size. Inches _ ___,_..__.__~14!£..._ __ Barometric Pressure. "Hg ~tfiL...L.:'.:::.CJc::Cl:.._ __ _ 

Gas Temperature. °F ~3Z..._f5.,J.-b ___ _ Static Pressure, "H2o _.,...__:0::.., • ...::'/t-:9+-------

Pitot Tube 0 Standard ijJ S-Type %0, ----- %C02 -----

I 0 4• ·8f2-

Point J_ Velocity 

~ Velocity Velocity Velocity 

Location Pressure Pressure ,____ Pressure ~ Pressure 

Inches t:: HH:O "H20 t:: '"HaO t:: "H20 0 0 0 0 

a. a. a. a. 

I.~ I 1 D. 3 ?_ 1 0.31 1 1 

J; .(,., q 2 () t../ :i. 2 D.t./A 2 2 

II . 5LJ 3 ().5o 3 0. 5tJ 3 3 

21. t./6 4 D.t.JB 4 6.49, 4 4 

a~· ~o 5 D. 4't 5 0-45 5 5 

31.z,8 6 0. t.Jt./ 6 0•42.- 6 6 

7 7 7 7 

8 8 8 8 

I 9. 9 9 9 

10 10 10 10 

11 11 11 11 

12 12 12 12 

13 13 13 13 

114 14 14 14 

..--------__,I ~p = .{Q~ L\ 

Wall Thickness 

Zero Point 

Port SizefType 
NETWORK ENVIRONMENTAL, INC. 

Clients: 

Pitot Traverse Data Form 

Proj. No.: -------

Plant: __~.G~Ltot.!.L..I-J~rV~t3:::.._ __ _:J~.'-.::$:::.:....· --t~:;!..!-f.:.:• c=-k.:...::::... ________________ _ 

Source: _S=..:::(J::..<2:...__:Sic;;,c:::J:t~IJ.l2b~Oe~l-.:::::._ ___ _ s:att: 0e:,.q.T S Vt ~,.,)+ I 

Stack Size. Inches -~wL.L--!.-~~;,::_ ?q' ~ __ _ Barometric Pressure, "Hg ~z'-'qC!.':::::CIO::::::._ __ _ 

1:) 1.-.o .., Gas Temperature. oF ---'-3"-'/ J)I:..L----!.. :;;~~::::.,_- Static Pressure. "H -o. ~~s 20 ---"~-:::!.u_oL-__ _ 

Pitot Tube 0 Standard ~ S-Type %0, _____ %C0

2 ____ _ 

'l oF o. fJZPoint I Velocity 2. Velocity Velocity Velocity Location - Pressure ~ Pressure ~ Pressure f--- Pressure Inches t: "HzO "HzO "HzO t: "HzO 0 0 0 0 a. a. a. a. 

{ .1-1 1 (J.35 1 0-2.<1 1 1 

.z;. ~q 2 IJJ.O 2 D·L\r:f- 2 2 

I { . 15"4 3 o.se 3 D.52, 3 3 

) r-j_. L/5 4 ().50 4 o.4q 4 4 

-=?3· 30 5 D.l{q 5 Q ,Lft 5 5 

~tJ.zA 6 (),c../i.) 6 (). y \ 6 6 

• 

7 7 7 7 

8 8 8 8 

9 9 9 9 

10 10 10 10 

11 11 11 11 

12 12 12 12 

13 13 13 13 

'4 14 14 14 

Wall Thickness 

Zero Point 

Port Size/Type 
NETWORK ENVIRONMENTAL, INC. Date:---;-------

Clients: \).~. 612.~ Pitot Traverse Data Form 

J Proj. No.: -------

Plant: ~Co~o'!_v~v~t..~~rJ:.:.=:a~-~~s~._G~;;,it:g~,c~,K.S::.__ ____ --.------.----r------

Source: __,5.,_0=7----'$_""""'cLyU~Ioc..::be:..=.:...-'------­ "2q ,. /7) 

statt: --=8e=:..!J___L_.4~vurJ&ce0~+..___ __ _ 

Stack Size, Inches --~-=~-=---W=------ Barometric Pressure, "Hg ~a"'-q~.CJ~O~---

Gas Temperature, •F ..,,3...,1~\ ___ 1 ... '8'J.':2.=""'-- Static Pressure, "H20 __ -_-_:D::_•:_:S~I __ _ 

P1t0t Tube 0 Standard fXJ S-Type %0, ----- %C02 -----

a o,f t.j • 8( 2-

Point 1 Velocity l.. Velocity Velocity Velocity Location f-.. ' Pressure 7 Pressure 7 Pressure f-.. Pressure 

Inches t:: HH:O "H20 "H20 . t:: 0 0 0 0 "H20 ll. ll. ll. ll. 

I. t-f-1 1 . 2& 1 • 3\ 1 1 

&:,,c,q 2 .Ljy 2 • (.j '+ 2 2 

11 .t; !.). 3 .. 5" T 3 • 51 3 3 

;:;, i. t.J 5 4 • 51 4 • Ll '1 4 4 

~ ~.30 5 .&&tJ9 5 ·45 5 5 

31-zS 6 •• t/3 6 .43 6 6 

7 7 7 7 

8 8 8 8 

9 9 9 9 

10 10 10 10 

11 11 11 11 

12 12 12 12 

13 13 13 13 

14 14 14 14 

Wall Thickness I ..... 

~ Zero Point , 

. .. 

Port Size/Type 

. ._ ~ 

. .... -----' 
APPENDIXE " . 

, ·-

/ . CALCULATIONS 

r . 
' ' 

r 

I. 

' 

EPA METHOD 6C 

AVERAGE GAS CONCENTRATION FORMULA 

Eq. 6C-l 

- c C = (C- C) 1M 

1

"' • (C., -C.) 

Where: 

Cps = Effluent gas concentra~on, dry basis ppm or%. 

C =Average gas concentration indicated by gas analyzer, dry basis ppm or%. 

c.= Average of initial and final system calibration bias check responses for the 

zero gas ppm or%. 

C =Average of initial and final system calibration bias check responses for the . . 

upscale calibration gas ppm or%. 

C,.. = Actual concentration of the upscale gas, ppm or percent. 
r1 

f . 

I 

,. -

' 

I 

i 

I 

1. 

2. 

3. 

SULFUR DIOXIDE CALCULATIONS 

Concentration \m M~ ) 

~' - CPPlt!) CM. W J24.2l 

where: M.W. - molecular weight - 64 for S02 

Air Flow Rate in Dry Standard Cubic Meters Per Minute (DSCMM) 

DSCMM - (DSCFM) (0.0283) 

where: DSCFM - Dry Standard Cubic Feet Per Minute 

Emission Rate (in Lbs/Hr) 

Lbs/Hr - (M~ ) CM'!Wnl (60 Min/Hr) (2.205 Lbs/Kg) (XgilOOO g) (gllOOO mg) 

Lbs/Hr - (MgiM3

) (DSCMM) (1.323 X 10-'J 
,. 

,.: 

( 

Network Environmental, Inc. 

CALCULATION FORMULAS 

MOISTURE tRAIN CALCULATIONS: 

M1. BAROMETRIC PRESSURE, inches of Mercury 

M2. DURATION OF SAMPLE, minutes 

M3. METER CALIBRATION FACTOR 

M4. AVERAGE METER TEMPERATURE, degrees F 

M5. AVERAGE METER PRESSURE, inches of water 

M6 • METER VOLUME, ACTUAL, cubic feet 

M7 • METER VOLUME, STP, cubic feet 

530 M1 + .07355 * M5 

M7 = M3 * M6 * ---------- * ------------------ M4 + 460 29.92 

MS. LIQUID VOLUME OF WATER CONDENSED, milliliters 

M9. VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet 

M9 = MS * 0.0474 

M10. TOTAL GAS SAMPLED, @ STP, cubic feet 

M10 = M7 +M9 

M11. PERCENT MOISTURE 

M9 

M11 = * 100 

M10 

EXHAUST GAS CALCULATIONS: 

G1. STACK DIMENSIONS, inches 

G2. AREA OF STACK, square feet 

3.14159 * (DIA/2)"2 

G2 (ROUND) = --------------------- 144 

WIDTH * LENGTH 

G2 (RECT.) = ---------------- 144 

G3. BAROMETRIC PRESSURE, inches of Mercury 

G4. STATIC PRESSURE IN STACK, inches of water 

G5. STACK GAS TEMPERATURE, degrees F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

P13 

G7 = ----- * 100 

P14 
,-

' 

c -

I 

r 

,-

! 

Network Environmental, Inc. 

CALCULATION FORMULAS CONTINUED 

GS. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION, %02, %C02, %CO, %N2 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

%02 - 0.5 * %CO 

G10 = 100 * ----------------------------- .264 * %N2 - %02 + .5 * %CO 

G11. DENSITY, DRY, @STP, lbs./cu. ft • 

G11 = 

• 0827 * %02 + .1137 * %C02 + (%CO + %N2) * .0724 

--------------------------------------------------

G12. DENSITY, WET, @STP, lbs./cu. ft. 

100 - G7 

100 

G7 

G12 = G11 * ---------- + .0465 * ----- 100 100 

G13. DENSITY, WET, @ STACK CONDITIONS, lbs./cu. ft. 

530 G3 + .07355 * G4 

G13 = G12 * ---------- * ------------------ G5 + 460 29.92 

G14. MOLECULAR WEIGHT, DRY, lbs./mole 

G14 = G11 * 386.9 

G15. AVERAGE GAS VELOCITY, feet/minute 

1096 

G15 = P5 * G6 * -----------

G16. STACK GAS FLOW RATE, ACFM 

G16 = G2 * G15 

G17. STACK GAS FLOW RATE, SCFM 

SQRT(G13) 

530 G3 + .07355 * G4 

G17 = G16 * ---------- * ------------------ G5 + 460 29.92 

G18. STACK GAS FLOW RATE, DRY, DSCFM 

100 - G7 

G18 • G17 * ---------- 100 
I 

,-

' ,_ 

I 

Network Environmental, Inc. 

CALCULATION FORMULAS CONTINUED 

PARTICULATE TRAIN CALCULATIONS: 

Pl. NUMBER OF POINTS SAMPLED 

P2. DURATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, square feet 

3ol4l59 * (P3/2)•2 

P4 = -------------------- r- 144 ' . 

P5. PITOT CALIBRATION FACTOR 

P6. METER CALIBRATION FACTOR 

P7. AVERAGE FILTER TEMPERATURE, degrees F 

PS o AVERAGE METER TEMPERATURE, degrees F 

P9. AVERAGE METER PRESSURE, inches of- water 

PlO. METER VOLUME, ACTUAL, cubic feet 

Pll. METER VOLUME, @ STP, cubic feet 

' 

530 G3 + .07355 * P9 

· Pll = PlO * P6 * ---------- * ------------------ ~-- PS + 460 29.92 

Pl2o LIQUID VOLUME OF WATER CONDENSED, milliliters 

P 13 o VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet 

Pl3 = Pl2 * 0.0474 

Pl4. TOTAL GAS SAMPLED, @ STP, cubic feet 

Pl4 = Pll + Pl3 

Pl5. WEIGHT OF GAS SAMPLED, DRY, pounds 

Pl5 = Pll * Gll 

Pl6 o WEIGHT OF GAS SAMPLED, WET, pounds 

Pl6 = Pl4 * Gl2 

Pl7. PERCENT ISOKINETICS 

100 * 29o92 * (G5 + 460) * Pl4 

Pl7 = ------------------------------------------ 530 * (G3 + o07355 * G4) * P2 * P4 * Gl5 
'. 

' 

Network Environmental, Inc. 

CALCULATION FORMULAS CONTINUED 

CONCENTRATION CONVERSION FACTORS: 

Pl8. 50 % EXCESS AIR, AFER COLLECTOR 

Gl4 + 18 * G7/(100 - G7) Pl8 = ------------------------------------------------------- .1826 * %N2 - 2.0592 * %02 + Gl4 + 18 * G7/(100 - G7) 

Pl9. 50 % EXCESS AIR, BEFORE COLLECTOR 

Gl4 + 18 * G7/(100 - G7) Pl9 = ------------------------------------------------------- .1826 * %N2 - 2.0592 * %02 + Gl4 + 18 * GS/(100 - G8) 

P20. MOISTURE BEFORE COLLECTOR 

Gl4 + 18 * G7/(l00 - G7) 

P20 = -------------------------- Gl4 + 18 * G8/(l00 - GS) 

PARTICULATE EMISSION CALCULATIONS: 

El. 

E2. 

E3. 

E4. 

TOTAL WEIGHT PARTICULATE COLLECTED, grams 

LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL 

1000 

E2 = El * ----------- 454 * Pl6 

LBS. PARTICULATE/lOCO LBS. GAS, DRY 

E3 = E2 * P20 

LBS. PARTICULATE/lOCO LBS. GAS, WET, 50% EA 

E4 = E2 * Pl8 

ES. LBS. PARTICULATE/lOCO LBS. GAS, DRY, 50% EA 

ES = E2 * Pl9 

E6. GRAINS/DRY STANDARD CUBIC FOOT 

El * 7000 * 100 

E6 = ------------------------ 454 * Pl4 * (100 - G7) 

E7. POUNDS/HOUR 

Gl7 * Gl2 * 1000 * El * .06 

E7 = ----------------------------- 454 * Pl6 

E8. POUNDS/MILLION BTU 

E7 

E8 = ---------------------

<~ACITY, MM BTU/HR 

~?­ ) -
~~ 

' 

·' 

j 

r , 

r 

r -

r 

APPENDIXF 

RAW DATA 
Company: 

US. G[tck. 

location: CIJi?..\J!GNA I

Source: 

Date: 

Operator: 

Monitor: 

::Vz. $--: £_(.) e-..e E; (?.__ 

?J I fq:; 

OEil < '-lrt-1 ce.u} 

302. 

Span Value (PPM): ttY>() 

Page#: I 0 +' I 

Calibration Response, PPM 

Calibration .. 

Gas Cone. Direct System Injection 

PPM Injection Pretest Post1 Post2 

'/: '$2J [3:o t Ia: 3 4 

0 ·o p 0 0 

jCj z.. <J iJ9IR t/D8 L.\IZ t-{15 

• !351- 851 I88L! 

Analyzer 

Cal. Error, Drift, % of Span 

Post 3 %of 

Span Gas 

1/.' s 1 Test 1 Test2 Test3 

0 0 0 0 

0·30 

41':/- Cl.3\ o·id o.qo 

• As Defined By EPA Method, This Value Must Be The Same As The Relevant Direct Injection Value 

•• Run Zero and either mid or high calibration gas, whichever one Is closer to actual slack concentration 

Pretest 

0 

D·CJ 

l· z 

3. 2, 

Analyzer cal. error, %of span= (dir. lnj. cal. response, PPM - cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% 

S

vi 

Drift, %of span= (relevant posllest sys. In!. cal. response, PPM- sys. lnj. pretest cal. response, PPM) x 100% I (span value, 

System bias,% of span= (relevant sys. In]. cal. response, PPM- dir. In]. cal. response, PPM) x 100% I (span value, PPM): L
.• 

I 

f . 

.r· . 

I 

Pitot tube calibration data. 

P!TCT iUSE IOE!tTIF!CATlON NUMSEi!: __ '_;.l-/_.......J.j-...!:bL._

1 

C.!. TO· ~/:,£_/.r:J /s C,.I.ISR . .\TEC SY: @Sc:: ~ '7 7- [ . ) 

RUH!IO. 

1 

2 

J 

RU!t 110. 

1 

z 

J 

£l ;~~: 

=HzO 

(in. HzOI 

I D.~l/1.. 

I D. 

Ll~-;::! 

""' HzO 

(in. HzOI 

~ ~{sl 

=HzO 

(i,._ HzOl 

C; (SIC: AI 

c. ::r <~ 

c:.-, HzO 

(in. HzOI 

C~ (SlOE Sl 

J 

CEVIATlO.'I c,r,J C~(sl · C~(Al 

I. lo 5 

I 'i.2.. I 0 -oD 

I. 'i'-J I O.oD 

J.g:LS"\o. OO'j 

OEVI.I TIC !I 

C~(d. C~(~l 

! I C;l<l·Cpl.:. oR all 

AilE RACE 1 CE\IIATlON ~ ''{A OR Sl • ..:._ _______ -MUST SE <;O.OI 

J 

/c., (SlOE Al-c10 {SlOE si/-Musr aE s:o.or 
' ' 

' ·! 

I 

·I 

' 

' :i 

,, 

" ' 

i ' ,f, reSl 6 ~\t.~ I : f'; ,._¢}._ ~ ... s E>.-t'(. k:.. 

y.\\ ~ \\\1.0 : 

• £:,'1 X "-,l.:t ~~ '= 

1\ \1.0 = .;l.b~te> -

(o I~ - 5'30 - 0 oo 1 

5ll -l<.\~- 3-:,~D'-\ 

1.{$'",10 3. 'Z.. 

\ 1 'aS'"\ .11. 

;j 

,: 1~ <"-1'.0 Pu~h ~\c. ~k~.J~ \\.,...,<.S 

" OS'-10 I () qy'O I l I '-\0 I I 340 I IS' 1.\01 II ~0 1 

C\"\0 1 0'3 

\ ~ ~0 l :>.. \ '-\( 

:o..~ a~~o. I! 

!, 

' 

,I 

,, 

'I 

,' 

,, 

:j 

,, 

' \ 

·I 

,, 

I 

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L • 

. rr .. ' ...... 

.. 

' 

I 

~-

1" 

r· 

,. 

f 

I 

rr 

r 

r· 

f'. ; 

.1. ~ ... 

Report of an ... 

Emission Study 

performed for ... 

Michigan Division 

U.S. Brick . . . 

Corunna,· Michigan .,_ 

.. ,• 

on the 

Kiln # 1 Exhaust 

May 27, 1994 

010.05 

Network Environmental, Inc. 

Grand Rapids, MI 
I 

I 

l 

L 

l. 

I 

L 

Network Environmental, Inc. 

P.O. Box 2021 

Grand Rapids, III 49501 

SOURCE EMISSION TESTING 

at 

MJ:CBIGAII DIVISION - O.S. BRICK -

COROHHA, MJ:CBIGAII 

JaLH tl EXBAOST ,= 

DAX!!:: 5/27/94 

/' 
I 

. I 

r • 

I 

r· 

I . 

I. 

II. 

m. 

TABLE OF CONTENTS 

Introduction 

Summary Tables of Results 

II.l Particulate Emission Results Summary 

II.2 Sulfur Dioxide (S02) Emission Results 

Discussion of Results 

N. · Source Description 

V. · Sempling and Analytical Protocol 

Appendices 

Particulate Emission Results 

S02 Analyzer Output & Calibration Date - . 

S02 Analyzer Specificetions & Gas Certifications 

Particulate Field Data 

Calculetions 

Raw Data 

.. -

' ... 

·~ 

,-. 

~ 

' 1 

2 

2 

2 

3. 

3-4 

4-6 

:A 

B 

c 

D 

E 

F 

~. 
I I_ 

I 

l_ 

I 

L. 

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l 

I. INTRODUCTION 

Network Environmental, Inc. was retained by the Michigan Division of U.S. Brick in Corunna, Michigan. 

to perform an emission study on the exhaust of their Kiln # 1. The purpose of the study was to document 

the particulate and sulfur dioxide (S02) emissions from the Kiln #1 exhaust. -

The study was performed on May 27, 1994 by David D. Engelhardt and Bertram J. Smitf1 of Netwo_rk 

Environmental, Inc.. The testing was performed in accordance with :MDNR Reference Method 5B for 

particulate and U.S. EPA Reference Method 6C for S02• In addition, the exhaust gas parameterS (air flow 

rate, temperature, moisture, and density) were determined ~accordance with U.S. EPA Reference '---

Methods 1 through 4. Mr. Kenneth Terry, P .E. of the :MDNR Air Quality Division Shiawassee District - -

Office was present to observe portions of the testing. 

1 
j 

I 

r 

ll.1 TABLE 1 

PARTICULATE EMISSION RESULTS SUMMARY 

KILN #1 EXHAUST 

MICIDGAN DMSION • U.S. BRICK 

CORUNNA, MICIDGAN 

MAY 27, 1994 

.·.·. Air F1ow Rate Concentration· 

Sample Time · •••·• ·}dass Emi"Siin Rate SCFM Lbs/1000 Lbs, Dry . ·· ·.·.. Lbs/Hr .· ...... ·. 

1 07:4 7.08:59 12,236 0.0063 0.31 

2 09:26·10:29 12,174 0.0079 0.40 

3 10:50·11:53 12,122 0.0075 0.37 .. 

AVERAGE 12,177 0.0072 0.38 

ll.2 TABLE 2 

SULFUR DIOXIDE (S02) EMISSION RESULTS 

KILN #1 EXHAUST 

MICIDGAN DMSION • U.S. BRICK 

CORUNNA, MICIDGAN 

MAY 27, 1994 

Air Flow Rate Concentration 1 • Mass EmissiiJn Rate 

Sample : Time DSCFM PPM Lbs/Hr . . 

1 07:4 7·08:57 11,053 564 61.73 

2 09:25·10:29 11,010 595 64.87 

3 10:49·11:52 10,975 579 62.92 

AVERAGE 11,013 579 83.17 

2 

(.( 
1 

I 

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I 

ill. DISCUSSION OF RESULTS 

The results of the particulate emission sampling are SUIIIIIlarized in Table 1 (Section IT.1). The particulate·~ 

results and the exhaust gas parameters are presented in more detail in Appendix A 

ill.1 Particulate Emission Concentrations • The particulate emission concentrations were 0.0063 

pounds of particulate per thousand pounds of gas on a dry basis (Lbs/1000 Lbs, Dry) for sample one, 

0.0079 Lbs/1000 Lbs, Dry for sample two, and 0.0075 Lbs/1000 Lbs, Dry for sample three. The 

average of the three samples collected was 0.0072 Lbs/1000 Lbs, Dry. 

ill.2 Particulate Mass Emission Rates • The particulate mass emission rates were 0.31 pounds of 

particulate per hour (Lbs/Hr) for sample one, 0.40 Lbs/Hr for sample two, and 0.37 Lbs/Hr for sample 

three. The average of the three samples collected was 0.36 Lbs/Hr. 

The sulfur dioxide (S02 ) emission results are presented in Table 2 (Section ll.2) 

ill.3 SO, Emission Concentrations • The S02 concentrations were 564 parts per million on a dry 

basis (PPM) for sample one, 595 PPM for sample two, and 579 PPM for sample three. The average 

of the three samples collected was 579 PPM. 

ill.4 S02 Mass Emission Rates· The S02 Mass Emission Rates were 61.73 Lbs/Hr for sample one,-_ 

64.87 Lbs/Hr for sample two, and 62.92 Lbs/Hr for sample three. The average of the three samples 

collected was 63.17 Lbs/Hr. 

ill.5 Visible Emission Observations · After the completion of the field sampling, visible emission 

observations (opacity) were recorded for a fifteen (15) minute period from the Kiln # 1 exhaust. 

These observations were recorded by a certified technician in accordance with U.S. EPA Reference 

Method 9. No visible emissions were observed during this 15 minute period. The observation 

reporting form can be found in Appendix E. 

IV. SOURCE DESCRIPTION 

The source tested was the exhaust of Kiln # 1. The kiln i.s gas fired. The exhaust from the kiln passes 

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through an emission control system consisting of a cooler followed by a mixing chamber and tben through 

a baghouse prior to exhausting to atmosphere through the exhaust stack. Lime is sprayed into tbe system 

between tbe cooler and tbe mixing chamber. 

On 5/27/94 king size birchwood bricks were fired. They weigh on an average 5.lllbs per brick, and tbere 

are 9,072 bricks per car (equates to 46,360 lbs per car). There were also 4,032 "real" bricks per car at a 

weight of 0.661 lb per "real" brick (equates to 2,665 lbs per car). The total weight of each car is 

approximately 49,025 lbs per car. The kiln speed during tbe testing was 8.421 cars per day. The charge 

times for 5/27/94 were as follows: 01:12, 04:03, 06:54, 09:45, 12:36, 15:27, 18:18, and 21:09. 

V. SAMPLING AND ANALYTICAL PROTOCOL 

V.1 Particulate 

C

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+'!oz~ I~(J,,),_o .• ~'l-75,.: 9.4'1- ;;r 

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The particulate emission sampling was conducted in accordance witb Michigan Department of Natural 

Resources (MDNR) Reference Metbod 5B. Method 5B is an in-stack filtration metbod. Three (3) 

samples were collected from the exhaust. Each sample was sixty (60) minutes in duration, and had 

a minimum sample volume of tbirty (30) dry standard cubic feet. . The samples were collected 

isokinetically and analyzed for total particulate by gravimetric analysis. All tbe quality assurance and 

quality control procedures listed in the method were incorporated in tbe sampling and analysis. 

V.2 Sulfur Dioxide · 

The S02 determinations were performed in accordance with U.S. EPA Reference Metbod 6C. A PSC302 portable stack gas analyzer was used to monitor tbe Kiln # 1 exhaust. A heated teflon sample 

line was used to transport tbe exhaust gases from tbe stack to a gas conditioner to remove moisture 

and reduce. tbe temperature. From tbe gas conditioner tbe stack gases were passed to tbe analyzer. 

The analyzer produces instantaneous readouts of tbe S02 concentrations (PPM). 

The analyzer was calibrated by direct injection prior to tbe testing. A span gas of 768 PPM was used 

to establish the initial instrument calibration. Calibration gases of 50 PPM and 244 PPM were used 

to determine tbe calibration error oftbe analyzer. The sampling system (from tbe.back oftbe stack 

probe to the analyzer) was injected using tbe 244 PPM calibration gas to determine tbe system bias. 

After each sample, a system zero and gystem injection of 244 PPM were performed to establish 

gystem drift and system bias during tbe test period. At the end of tbe last sample, all three 

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calibration gases were direct injected to show the analyzer drift over the entire testing period. All 

calibration gases used were EPA Protocol 1 Certified. 

The analyzer was calibrated to the output of the data acquisition system (DAS) used to collect the 

data. A strip chart recorder was also used to record the data as a backup to the DAS. Three (3) 

samples were collected from the Kiln #1 exhaust. Eacilsample was sixty (60) minutes in duratioD. 

The DAS output, strip chart recorder data, and calibration data can be found in Appendix B. The 

so, analyzer specifications and calibration gas certifications can be found in Appendix C. 

V.3 Exhaust Gas Parameters 

The exhaust gas parameters (air flow rate, temperature, moisture, and density) were determined in ~ 

co~unction with the other sampling by employing U.S. EPA Reference Methods 1 through 4. All the 

quality assurance and quality control procedures listed in the methods were incorporated in the 

sampling and analysis. 

This report was prepared by: 

David D. Engelhardt 

Vice President ' 

This repcrt was reviewed by: 

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APPENDIX A 

PARTICULATE f EMISSION RESULTS . 

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lletwork Environmental., :Inc. 

SUHMARY OF PARTJ:CllLAD TRAni PARAMETERS 

COMPANY NAME: KICBIGAN D:rv:ISJ:ON - O.S. BRJ:Clt 

COMPANY LOCATJ:ON: CORUNNA, KICBJ:GAN 

TEST DAXE: 5/27/94 

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SOORCE NAME: KJ:LH tl EXBAOS'r 

SAMPLJ:NG STAFP' : EHGELBARD'I' / SKITB 

SAMPLE HtlMBER 

Pl. HtlMBER OF POINTS SAHl'LED 

P2 • DU'RATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, sq. ft. 

P5. PJ:TOT CALIBRATION FACTOR 

P6 • METER CALIBRATJ:ON FACTOR 

P7. AVERAGE FILTER TEMPERATllRE, deg. F 

P8. AVERAGE METER TEMPERATURE, deg. F 

P9. AVERAGE METER PRESSORE, inches of water 

PlO. METER VOLUME, ACTTlAL READil'IG, cu.ft. 

Pll. METER VOLUME, @ STP, cu.ft. 

Pl2. LIQUID VOLUME OF WATER CONDENSED, m.ls. 

Pl3. VAPOR VOLUME OF WATER COHDEIIISED, @ ST.P, cu. ft. 

Pl4. TOTAL GAS SAMPLED, @ STP, cu.ft. 

PlS. WEJ:GBT OF GAS SAMPLED, DRY, lba. 

Pl6. WEIGHT OF GAS SAMPLED, WET, lbs. 

Pl7. PERcENT ISOKINEXJ:CS 

CON~TION CONVERSJ:ON FACTORS: 

Pl8. 

Pl9. 

P20. 

50 'l EXCESS AJ:R, Jll"TER COLLECTOR 

50 'l EXCESS AJ:R, BEFORE COLLECTOR 

HOISTllRE COHDJ:TJ:ONS BEFORE COLLECTOR. 

1 

12 

60.00 

0.312 

0.00053 

0.870 

0.991 

0 

79.6 

2.028 

44.52 

42.51 

96.0 

4.55 

47.06 

3.20 

3.42 

99.9 

1.07 

2 

12 

60.00 

0.312 

0.00053 

0.870 

0.991 

0 

85.0 

2.027 

45.56 

43.07 

96.0 

4.55 

47.62 

3.24 

3.46 

101.6 

1.07 

3 

12 

60.00 

0.312 

0.00053 

0.870 

0.991 

0 

90.5 

1.903 

45.07 

42.17 

93.0 

4.41 

46.58 

3.17 

3.38 

99.8 

1.06 

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Jletwork Envirom.ntal., Inc. 

COMPANY NAME: MICHIGAN DIVISION - U.S. BlUet 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN U EXIIAUST 

SAMPLING STAFF: ENGELBARDT / SKI'l'l! 

SAMPLE NUMBER 

Pl. NUMBER OF POINTS SAMPLED 

P2. DURATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, sq. ft. 

P5. PITOT CALIBRATION FACTOR 

P6. METER CALIBRATION FACTOR 

P7. AVERAGE FILTER ~TURE, <:leg. 1! 

P8. AVERAGE METER TEMPERATURE, deg. F 

P9. AVERAGE METER PRESS=, illches Of water 

P10. METER VOLUME, ACTUAL READING, cu.ft. 

P1l. METER VOLUME, @ STP, cu.ft. 

P12. LIQUID VOLUME OF liATER COIIDENSED, lllls. 

P13. VAPOR VOLUME OF WATER CO!IDJ!:I!ISJ!:I), f! sn>, cu.ft. 

P14. TOTAL GAS SAMPLED, @ STP, cu. ft. 

P15. WEIGHT OF GAS SAMPLED, DRY, l.bs. 

P16. WEIGHT OF GAS SAMPLED, WET, l.bs. 

P17. PERCENT ISOKI~ICS 

CONCENTRATION CONVERSION FACTORS: 

P18. 50 ' EXCESS AIR, AFTER COLLECTOR 

P19. 50 ' EXCESS A.IR, BEJ!ORE COLLECTOR 

P20. MOISTURE CONDITIONS BEFORE COLLECTOR 

TEST DATE: 5/27/94 

1 2 3 

12 12 12 

60.00 60.00 60.00 

0.312 0.312 0.312 

0.00053 0.00053 0.00053 

o. 870 0.870 0.870 

0.991 0.991 0.991 

0 0 0 

79.6 85.0 90.5 

2.028 2.027 1.903 

44.52 45.56 45.07 

42.51 43.07 42.17 

96.0 96.0 93.0 

4.55 4.55 4.41 

47.06 47.62 46.58 

3.20 3.24 3.17 

3.42 3.46 3.38 

99.9 101.6 99.8 

1.07 1.07 1.06 

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Network Environmental, Inc. 

SUMMARY OF EXBAO'ST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION - O'.S. BRICK 

COMPANY LOCATION: CORO'NNA, MICHIGAN 

SOO'RCE NAME: !aLN tl EX!!AO'ST 

SAMPLING STAFF: ENGELHARDT / SMITH 

SAMPLE NllMBER 

Gl. STACK RADIO'S, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETRIC PRESSO'RE, in. HG. 

G4. STATIC PRESSO'RE IN STACK, in. H20 

G5 • STACK GAS TEMPERATO'RE, deg. F 

G6. AVG. SQRT VELOCITY PRESSO'RE OF POINTS SAMPLED 

G7. PERCENT MOISTO'RE AT TEST LOCATION 

G8. PERCENT MOISTO'RE BEFORE COLLECTOR 

G9 • DRY GAS COMPOSITION: % OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

G1 0. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS • 

Gll. DRY, @ STP, lbs./cu.ft. 

G12. ~. @ STP, lbs./cu.ft. 

G13. WET, @ STACK CONDITIONS, lbs./cu.ft. 

G14. MOLECO'LAR WEIG!I'l', DRY, @ STP, lbs./mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

G17. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFH 

STANDARD CONDITIONS, DRY SCFM 

TEST DATE: 5/27/94 

1 

19.5 

8.30 

29.20 

0.26-

272 

0.496 

9.67 

0.00 

15.87 

3.27 

o.oo 

80.87 

0.0754 

0.0726 

0. 0513 

29.17 

2088 

17,323 

12,236 

11,053 

2 

19.5 

8.30 

29.20 

0.26-

272 

0.493 

9.56 

o.oo 

15.40 

3.20 

o.oo 

81.40 

0.0753 

0.0726 

0.0512 

29.14 

2079 

17,245 

12,174 

ll, 010 

3 

19.5 

8.30 

29.20 

0.26-

274 

0.492 

9.46 

0.00 

15.40 

3.00 

0.00 

81.60 

0.0752 

0. 0725 

0. 0511 

29.10 

2075 

17,210 

12' 122 

10,975 

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Network Environmental, Inc. 

SUMMARY OF PARTICULATE EMISSIONS 

COMPANY NAME:: HJ:CHIGAN DIVISION - U.S. BRIClt 

COMPANY LOCATION: COR!l'NNA, MICHIGAN 

SOURCE NAME: : 1ULN f l EXHAUST 

SAMPLING STAFF: ENGELHARDT / SMITH 

SAMPLE NllMBER 

SUNDARD ANALYSIS 

E1. TOTAL WEIGHT COLLECTED, qrams 

E2. Ll!S. PARTictJLATE/1000 LBS. GAS, ACTt1AL( 1) 

E3. Ll!S. PARTic:tlLATE/1000 LBS. GAS, DRY(2) 

E6. GRAINS/DSCF(4) 

E7. Ll!S • /BOt1R 

TEST DATE: 5/27/94 

l 2 

0.009 0.012 

0.0059 0.0075 

0.0063 0.0079 

0. 0033 0.0042 

0.31 0.40 

1- ~&c~a~L· ••••• &~ ~•• coaDI~Ioaa raaaD &~ ~•• a&x~Liao Loc&~Ioa. 2. ~oaT• zacLaoaa aaLT ~•• a&raa&L xoza~aaa ~••~ woaLD •• sxz~rao raox ~•• 

3 

0. Oll 

0.0070 

0.0075 

0.0039 

0.37 

•aocasa. aOII~O&S &DD&D 0& aa.~a&C~&D aT Taa COLLSCTO& II aOT IaCLOD&Do 

~- ~war• zacLDoaa , •• •o:a,oaa &I xa&aaaao &T raa a&x»Liwo LOC&Tioa. 4. 'oacr• za oaoaa ror&LLT oar coaDITioaa, &LL xozaraaa asxovso. 

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Network Environmental, Inc. 

EMISSION SOURCE SUMMARY 

STANDARD ANALYSIS 

COMPANY HAKE: MICHIGAN DIVISION - U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE HAKE: KILN tl EXHAUST 

SAMPLING STAZF: ENGELHARDT / SMITH 

STACK RADIOS, inches 

AREA OF STACK, sq. ft. 

STATIC PRESSURE IN STACK, in. H20 

STACK GAS TEMPERATURE, deg. F 

PERCENT MOISTURE AT TEST ~ION 

DRY GAS COMPOSITION: % OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

DENSITY, WET, @ STP, lbs./cu.ft. 

MOLECULAR WEIGHT, DRY, @ STP, lbs./mole 

AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: ACFM 

EMISSIONS: 

SCFM 

SCFM, DRY 

LBS. PARTICOLATE/1000 LBS. GAS, ACTOAL(1) 

LBS. PARTICOLATE/1000 LBS. GAS, DRY(2) 

GRAINS/DSC1"(4) 

LBS./HOOR 

TEST DATE: 5/27/94 

19.5 

8.30 

0.26-

273 

9.56 

15.56 

3.16 

0.00 

81.29 

0.0726 

29.14 

2081 

17259 

12177 

11013 

0.0068 

0.0072 

0.0038 

0.36 

1. ~•era•~· ••••• &T r•• co•axrxo•• roa•a &T r•• ••••Lt•• Loc&rxo•. 

2. 'DaY• I.CLDDSI o•LT Taa a&TDa&L XOIITUaa Ta&T WOULD aa SXITTSD F&DX Taa 

raoca11. XOIITUaa 4DDSD oa IDara&CTSD aT TXS CDLLSCTO& II aOT IaCLUDSD. 

3. '•ar• IaCLDDal TXS XOIITUaa 41 XS&Iuaao &T Taa l&arLta• LUC4TIOa. 

4. ~oacr• xa uaoaa TOT&LLr oar coaoxrzoaa, &LL aoxaraaa aaxovao. 

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APPENDJXB < 

S02 ANAL'YZEROUTPUT &: CALIBRATION DATA 

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EMISSIONS TEST 

SAMPLING DATE: 05-27-1994 

COMPANY: MI Div. - U.S. Brick 

SOURCE: Kiln 11 Exhaust 

START S02 

RUN TIME (PPM) 

1 07:48 564 

2 09:26 595 

3 10:50 579 

. · 

/} ::> / _-) 

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Company: Michigan Division 

U.S. Brick 

Location: Corunna, Ml 

Source: 

Kiln #1 Exhaust 

Date: 5/27/94 

Operator: DOE 

--

Monitor: PSC-302 

Sulfur Dioxide 

Span Value (PPM): 1500 

Page#: 1 of 1 

Calibration Response, PPM 

Calibration 

.. Analyzer Gas Cone. Direct System Injection Cal. Error, Drift, %of Span PPM S02 Injection Pretest Post 1 Post 2 Post 3 %of 

Span Gas 06:55 07:14 09:05 10:35 11:58 Test 1 Test2 Test 3 

0 0 0 0 4 4 o,oo 0.26 0.26 

50 50 0.00 

244 250 237 250 249 248 0.40 0.86 0.80 0.73 

• 768 768 

• As Defined By EPA Method, This Value Must Be The Same As The Relevant Direct Injection Value 

•• Run Zero and either mid or high calibration gas, whichever one Is closer to actual stack concentration 

Pretest 

0.00 

-0.87 

Analyzer cal. error,% of span= (dir. In]. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% 

Sy

~ 

Drift,% of span= (relevant posttest sys. lnj. cal. response, PPM- sys. lnj. pretest cal. response, PPM) x 100% I (span value, P

Syslem bias,% of span= (relevant sys. lnj. cal. response, PPM- dir. in]. cal. response, PPM) x 100% I (span value, PPM): Lim

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FILENAME: USB40527.DTA 

COMPANY: MI Div. - U.S. Brick 

SOURCE: Kiln #1 Exhaust 

DATA LISTING 

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CHANNEL: 

PARAMETER: 

UNITS: 

SLOPE: 

INTERCEPT: 

00 

S02 

PPM 

1500 

0 

---------------------------------------------------------------------------

05-27-1994 07:48:04 

05-27-1994 07:49:04 

05-27-1994 07:50:04 

05-27-1994 07:51:04 

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05-27-1994 07:54:04 

05-27-1994 07:55:04 

05-27-1994 07:56:04 

05-27-1994 07:57:04 

05-27-1994 07:58:04 

05-27-1994 07:59:04 

05-27-1994 08:00:04 

05-27-1994 08:01:04 

05-27-1994 08:02:04 

05-27-1994 08:03:04 

05-27-1994 08:04:04 

05-27-1994 08:05:04 

05-27-1994 08:06:04 

05-27-1994 08:07:04 

05-27-1994 08:08:04 

05-27-1994 08:09:04 

05-27-1994 08:10:04 

05-27-1994 08:11:04 

05-27-1994 08:12:04 

05-27-1994 08:13:04 

05-27-1994 08:14:04 

05-27-1994 08:15:04 

05-27-1994 08:16:04 

05-27-1994 08:17:04 

05-27-1994 08:28:26 

05-27-1994 08:29:26 

05-27-1994 08:30:26 

05-27-1994 08:31:26 

05-27-1994 08:32:26 

05-27-1994 08:33:26 

05-27-1994 08:34:26 

05-27-1994 08:35:26 

05-27-1994 08:36:26 

05-27-1994 08:37:26 

05-27-1994 08:38:26 

05-27-1994 08:39:26 

05-27-1994 08:40:26 

05-27-1994 08:41:26 

05-27-1994 08:42:26 

05-27-1994 08:43:26 

05-27-1994 08:44:26 

05-27-1994 08:45:26 

510 

518 

510 

520 

546 

561 

567 

552 

557 

543 

557 

559 

567 

566 

554 

565 

558 

542 

540 

554 

554 

564 

556 

564 

550 

555 

554 

562 

551 

553 

557 

579 

586 

585 

585 

578 

588 

584 

589 

579 

595 

586 

588 

582 

580 

587 

582 

589 
05-27-1994 08:46:26 595 

05-27-1994 08:47:26 586 

05-27-1994 08:48:26 572 

05-27-1994 08:49:26 563 

05-27-1994 08:50:26 564 

05-27-1994 08:51:26 566 

05-27-1994 08:52:26 556 

05-27-1994 08:53:26 570 

05-27-1994 08:54:26 561 

05-27-1994 08:55:26 568 

05-27-1994 08:56:26 560 

05-27-1994 08:57:26 561 

05-27-1994 09:26:24 581 

05-27-1994 09:27:24 569 

05-27-1994 09:28:24 577 

05-27-1994 09:29:24 576 

05-27-1994 09:30:24 555 

05-27-1994 09:31:24 562 

05-27-1994 09:32:24 600 

05-27-1994 09:33:24 601 

05-27-1994 09:34:24 620 

05-27-1994 09:35:24 614 

05-27-1994 09:36:24 615 

05-27-1994 09:37:24 609 

05-27-1994 09:38:24 604 

05-27-1994 09:39:24 608 

05-27-1994 09:40:24 602 

05-27-1994 09:41:24 609 

05-27-1994 09:42:24 612 

05-27-1994 09:43:24 604 

05-27-1994 09:44:24 600 • 

05-27-1994 09:45:24 586 

05-27-1994 09:46:24 611 

05-27-1994 09:47:24 608 

05-27-1994 09:48:24 612 

05-27-1994 09:49:24 611 

05-27-1994 09:50:24 610 

05-27-1994 09:51:24 611 

05-27-1994 09:52:24 605 

05-27-1994 09:53:24 538 

05-27-1994 09:54:24 335 

05-27-1994 09:55:24 359 

05-27-1994 G9:59:16 490 

05-27-1994 10:00:16 640 

05-27-1994 10:01:16 651 

05-27-1994 10:02:16 641 

05-27-1994 10:03:16 648 

05-27-1994 10:04:16 636 

05-27-1994 10:05:16 637 

05-27-1994 10:06:16 624 

05-27-1994 10:07:16 626 

05-27-1994 10:08:16 628 

05-27-1994 10:09:16 627 

05-27-1994 10:10:16 625 

05-27-1994 10:11:16 618 

05-27-1994 10:12:16 630 

05-27-1994 10:13:16 624 

05-27-1994 10:14:16 597 

05-27-1994 10:15:16 601 

05-27-1994 10:16:16 594 ?,C: _/1::':7 
05-27-1994 10:17:16 594 

05-27-1994 10:18:16 604 

05-27-1994 10:19:16 609 

05-27-1994 10:20:16 588 

05-27-1994 10:21:16 598 

,- . 05-27-1994 10:22:16 597 ' ' 05-27-1994 10:23:16 602 

05-27-1994 10:24:16 598 

05-27-1994 10:25:16 60'2 

05-27-1994 10:26:16 604 

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APPENDIXC 

S02 ANAL'YZER SPECIFICATIONS & GAS CERTIFICATIONS 
BA-MAK 2/9.87-1-

1.0 Field of ~pplic~tion 

G~s Sample Conditioners ~re used in gas ~nalysis systems and inat~llations 

to cool moisture-cont~ining sample gas sufficiently so that nowhere 

in the subsequent analysis systems or inst~llations does it fallw 

below its dew point. 

In cert~in measurement tasks it is necess~ry, to hold the dew point 

of the sample gas constant in order to elimin~te the effect of 

water vapor on the measurement result. For applications of this 

type the proportion of water vapor, held const~nt by the electrical 

s~mple g~s conditioner MAK 2, is t~ken into ~ccount on calibration. 

The Gas Sample Conditioner MAK 2 ~y not be used 

The explosion-proof G~s Sample Conditioner Modei 

for this. 

hazardous ~re~s. 

. K 3-Ex is avail~ble 
[ -

r . 

' 

r -

i 

2.0 Technical Data 

Number of individual gas paths 

Maximum sample gas flow rate 

of each gas path 

Operating pressure 

Sample gas inlet temperature 

Sample gas inlet dew point 

Sample gas outlet temperature 

MAK 2-l 

- MAK 2 

- accuracy 

Sample gas temperature indicator 

- indicator tolerance 

Running-in time 

Dead space per gas path 

Pressure drop per gas path 

Power supply (mains) 

Alternative voltage 

Po~er consumption 

BA-MAK 2/9.87-l-2 

M&' 2-l, Type 29 - l -

~~ 2 Type 30 - 2 -

250 l/h at l bar and 20 Degr c 

0,15 SCFM at 14 psi and 68 Degr F 

0,5 

7 

2,5 bar 

35 psi 

140 Degr C I 284 Degr F 

65 Degr C I 149 Degr F 

+ 3 Degr C I 37,0 Degr F 

outlet temperature gas path 

No. l is 0,5 Degr C I 0,9 Degr F 

higher than gas path No. 2. 

+1- 0,3 Degr. C I +1- 0,54 Degr F 

Digital display indicator for 

cooling brine temperature with 

limiting value signal 

+I- 0,5 Degr c at 0 0 0 0 10 Degr c 

+1- 0,9 Degr F at 32 0 • 50 Degr F 

approx. 55 min. 

approx. 8,36 cubic-inch 

apprOXa 25 mbar at 250 llh 

approx4 0,36 psi at 0, 15 SCFM 

115 v + 107. - 107. (60 +/-2) Hz 

Code Ol 

220 v + 107. - 157. (50 +l-2) Hz 

Code 03 

220 v + 157. 0 0 • - 57. (60 +l-2) Hz 

Code 04 

approx. 450 VA, 3,9 A at 115 v 60 Hz 

approx. 440 VA, 2,0 A at 220 v 50 Hz 

approx. 480 VA, 2,1 A at 220 v 60 Hz 
• 

BA-~AK 2/9.87·1·5 

2.1 Nace on standards and soecifications 

The indus~rial standards and regulations (DIN, VDE, VDI etc.) referred 

to in this Operating Manual are applicable in the Federal Republic 

of Ge~any. When using this device outside German Federal jurisdiction, 

the relevant specifications, standards and regulations applicable in 

the country where the device is used muse be observed. 

3.0 Mode of ooeration and consc=uccion 

With the description of the mode of operation and construction of the 

electric Gas Sample Conditioner ~' 2, see also the schematic diagram 

No. 3 898 0042. 

3.1 Descrict:ion 

In the electric Gas Sample Conditioner MAK 2 the sample gas is cooled 

co +2 Degr C in a heat exchanger. The conde~sace precipitated from 

the sample gas is deposi~ed in the precipitation vessel (precipitator). 

The cooling medium used is refrigerant R 12. A compressor compresses 

the gaseous refrigerant to approx. 101,5 psi, dependi~g on the operating 

·conditions. 

The compressor consists of a pressure case containing a piston compressor 

driven by an electric motor. DoYnstreaD of this is the condenser, a 

ribbed pipe heat exchanger, where the refrigerant is liquefied. The 

heat is dissipated by means of a fan which is switched off at low ambient 

temperature by a switch controlled by the refrigerant pressure - the 

fan pressure switch. The pressure of the refrigerant is then reduced 

by a capillary tube from approx. 101,5 - 29 psi. The refrigerant, with 

its pressure reduced in this way, is then injected into a heat exchanger 

coil (evaporator) where it absorbs energy from the sample gas directly 

via the cooling brine and evaporates again. The compressor takes in 

the evapOrated refrigerant once core. 

The evaporator is located, together with t~e heat exchanger through 

which sample gas flows, in a container filled with cooling brine, the 

so-called,heat exchanger unit. The actual heat exchanger comprises 

a spirally wound pipe with connected precipitator and conde~sate drain 

pipe. 

The sample gas is cooled by heat transfer to the cooling brine and from 

this to the refrigerant. Alle three systems "sample gasrt, "cooling 

brine" and "refrigerant" are he:-::tet:ically separated from one another. 

The sample gas outlet temperature is controlled by a hot gas bypass 

cont~ol valve. Depending on the refrigerant pressure in the evaporator 

outlet, this pressure regulator takes a greater or lesser amount of 

refrigerant from the condenser and passes it to the compressor via 

a bypass. As the pressure and temperature of the refrigerant are directly 

proportional, if the evaporator pressure is set a 31,9 psi the hot 

gas bypass control valve ensures that the sacple gas maintains a constant 

te~pe~at:ure in the area of interest. 
" 

SA-HAK 2/9.87-1-6 

A microprocessor controlled monitoring device with digital display 

is used to monitor the sample gas outlet te~perature (= cooling brine 

temperature). This temperature is dete~ined With a sensor immersed 

in the cooling brine. If the limit value set by the manufacturer (generally 

46 Degr F) is exceeded, visual indication is provided by the digital 

display flashing. A floating contact is available for external fault 

indication (status signal). !his is connected with the .connecting cable 

provided. A fault may be present for instance if after the power is 

swicc~ed on and the lead time has expired, the cooling .brine temperature 

is not lower chan its sec limit value (see also section 5.2). 

!he electric Gas Sample Conditioner ~~ 2 is supplied with one sample 

gas circuit or with cwo sample gas circuits. Upgrading from one to 

two sample gas circuits ist ~possible. 

!he precipitated condensate is collected in a separate external condensate 

vessel or pumped out by the automatic condensate drain unit (see also 

section 4.2.2). 

4.0 Installation and connectin~ instructions 

4.1 Selecting the installation site and mounting the unit 

When selecting the installation site, note that the electric Gas 

Sample Conditioner MAK 2 may only be installed in areas where the temperatures 

are within the permitted ambient temperature range (see section 2.1). 

!he Gas Sample Conditioner MAK 2 should be mounted on a wall or in 

an analysis cabinet as near as possible to the gas sampling point. 

!he fastening rails supplied with the unit are used for this; they 

are screwed co the rear wall of the unit (see dimensionsl drawing 

No. 4 8J.j 1281). !his drawing also shows the hole spacing and diameter 

for the fastening screws. 

The maximum permitted inclination of the.Gas Sample Conditioner is 

• ·. 5 Degrees; 

!he gas sample conditioner must be protected against direct heat radiation 

(from the sun~ furnaces, boilers etc.) and agains: rain and excessive 

contamination. It must have sufficient ground clearance to allow space 

to discharge and empty the condensate. 

The sample gas lines leading away from the Gas Sample Conditioner may be 

at any gradient provided that the Conditioner represents the coldest point 

in the entire measuring system, i.e. the te~peracure does not fall 

below the dew point in modules and lines in the gas analysis system 

do~~stream of the Conditioner. 
1.0 INTRODUCTION 

The Environmental Products' PSC 302 Portable Monitor System is caoable of simultaneously monitoring two gases in concentrations up to 150,000 PPH from a 

single sample probe. The gases which can be monitored are NOx, S02, CO and o

2

• 

The system uses electrochemical sensors (cells) that operate on the fuel cell 

pri'nciole. In a typical sensor, shown in Figure 2, a gas sample diffuses through 

a semipermeable membrane, and comes in contact l>ith a sensing electrode where it 

undergoes an oxidation or reduction reaction. This process generates an electrical current output which is linear and directly proportional to the partial 

pressure of the gas that the sensor is designed to sense. This current is converted to a voltage signal which operates a panel meter or outboard device, such 

as a chart recorder or data logging system. 

Before attempting to operate the PSC 302 Monitor, the operator should read and 

understand this manual in order to obtain accurate results and not damage the 

monitor. 

2.0 SYSTEM DESCRIPTION AND SPECIFICATIONS 

The PSC 302 Portab 1 e ~1oni tor is designed to be eas i1 y transported by one person. 

It weighs less than 45 pounds, and is 16" L by 12" W by 12" H in size. The 

system will monitor concentrations of S02, NOx, CO or 02, depending on the sensors 

installed in t"he system. The sample line, probe, filter, and calibration gases 

are contained in the Accessory Case which v1eighs less than 40 pounds, and measures 

20" W by 2g" L by 10" H. The specifications for the monitor which accompanies 

this handbook are listed in Table I. 

The gas sample is drawn into the monitor through a he a ted 1 i ne by a sample pump 

and then into the sample conditioner, see Drawing 751750. Within the conditioner, the gas is rapidly cooled below 45°F to remove moisture, which is expelled 

through a drain valve. The sample conditioner uses a solid state, thermostatically controlled thermoelectric device to dry the gas being sampled. The sample 

1 
2.0 SYSTEM DESCRIPTION AND SPECIFICATIONS (Continued) 

then flows through the sample/calibrate valve and the monitor flow meter to the 

sensors. If an NOx sensor is used (and the sample contains so2), the sample 

flows through an S02 scrubber before the NOx sensor. Each sensor generates 

an electrical current which is converted into a voltage signal to drive the 

monitor meters and other external devices as required. The monitor also provides a 4-20 mA current signal for this purpo?e. 

The PSC 302 monitor uses a 1 to 3 to 10 relationship for its range switch unless 

an optional analyzer board is installed (see Appendix A). If a 30-4 sensor 

is installed, it will read 1,000 PPM fullscale in low range, 3,000 PPM in midrange, and 10,000 PPM in high range. An 02 sensor will read 5% full scale in 

low range, 15% in mid-range, and SO% in high range. 

To calibrate the monitor, gases of known precise concentrations are connected 

to the sample/calibrate valve. Using this valve, each monitor channel can be 

set to zero using a zero gas such as air or N2. After the zeroing process is 

complete, the valve is cycled to introduce a calibration gas which facilitates 

adjustment of each channel's span. 

Calibration gases must be regulated to approximately 5-8 PSIG before applying 

them to the· monitor input. If excessi~e pressure is applied to the sensors, 

it is possible that the membrane can be ruptured thus ruining the sensor. 

3.0 SYSTEM SETUP 

3.1 INSPECTION AND PLACEMENT 

When the system is unpacked, check for shipping damage, be sure to check all 

items shipped in the accessory case (such as the sample line, probe and calibration gases). Make certain that the system conforms to the system config-

. J uration shown in Appendix A of this manual. Contact the factory if there is 

any damage or nonconformance before using. 

4 
I . 

TABLE I 

PSC 302 

SPECIFICATIONS 

RESPONSE TIME 

------------------------------------------------------------------------------------- [~ 

< 2 Minutes to 90% of Full Sea 1 e 

RESPONSE 

ACCURACY * 

DRIFT * 

OUTPUTS 

RANGES 

POWER REQUIREMENTS 

TEMPERATURE 

ENVIRONMENT 

(Operating) 

TYPE OF GAS 

SAMPLE LINE 

CALIBRATION FREQUENCY 

SENSOR TYPE 

SIZE 

WEIGHT 

Linear Within ± 1% in Each Range 

Overall Accuracy ±2% 

Zero and Span ±2% of Full Scale 

0 - 1 Volt, 10,000 ohms minimum 

4 - 20 rnA, 250 ohms maximum 

XI, X3, X10 (See Appendix A) 

115 Vac, 50/60 Hz, 15 amps maximum 

~ r7 

CO Up to 50,000 PPM 

S02, NOx up to 150,000 

o2 Up to 50% 

PPM 

·~ 

(S•• App•odi> 

. 

A) [J ~ 25 Ft. Electrically Heated, Self Regulating, 20 Watts/Ft. l~ 

Every 24 Hours of Service [ 

Electrochemical 

PSC 302 Monitor - 16" x 12" X 12" 

Accessory Case - 20" x 29" x 10" 

PSC 302 Monitor- 45 Lbs. with Cells 

Accessory Case - 40 Lbs. 

r [? ------------------------------------------------------------------------------------ r_r; 

[ ~ 

~ 

* Over 24 Hour Period 

2B 5"~/ ~-~ L 
·-

• 

--

-=-~-. ·~ ~·. ; .... : . . : ·: : ,-. 

• 

Scott Specialty Gases, Inc. 

1290 COMSERMERE STREET, TROY, Ml48083 (313) 589-2950 FAX: (313) SS9-2134 

CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Customer 

MICHIGAN AJR GAS 

311 STOKER DR 

SAGINAW Ml48604 

ANALYTICAL INFORMATION 

Ass:~.y Labor.Jtory 

Scan Specialty Gases, Inc. 

1290 Combennere 

Troy, ~1l 48083 

Purchase Order MAG PG0470 

Scott Project# 553559 

Certiflc:d to exceed the minimum specifications ofE.PA Protocol I Procedure# Gl. Section Number 3.0.4 

Cylinder Number ALM030474 Ccrtific:ttion D::~tc 7·26·93 General Exp. Date 

Cylinder Pressure 1900 psig Pre,·ious Certification Dates None: Acid R::~in Exp. 

7-26-96 

7-26-96 

A.'IALYZED CYLil'<'DER 

Components 

Sulfur Dioxide 

8J.I:~.ncc Gas: Nitrogen 

Certified Cnnccntr~ttion 

7G8.J ppm 

Date 

Analvtical Uncertain tv• 

±1•1. NIST Directly Tr.~ccable 

• A.n~l)'tlc..:ll unc~l""..:~.inry is md~Uive of usual known m-er sources v.·h~~~ Jt le:ut includes rd~ce ~dan:! error 1&. precision of the menurcmo=n.t procwes. 

REFERE~CEST~~ARD 

Type 

CR.\! 1662 

Expir:Hion D:~.te 

2-6-94 

L"'STRIDfENTA TTON 

Instrumenc/Modci/Seri:ll # 

S02: Horiba!OPE-135/56037204 

Cylinder Number 

AAL 19619 

L:~.st D:~.tc C:~.libr~tct.l 

7-2-93 

Conccntntion 

948.2 ppm SOz in N2 

Analytic:~.l Principle 

Non-Dispersive: Wrarc:d 

ANALYZER READINGS (z-Uro G:u R·R~fer-ence Gas T•Test G:u r-Correl:!otion Coefficient) 

Components ·· First TriJ.t.l An:1lysis Second Triad Analysis 

Sulfur Dioxide 03/.c: 7-19-93 Response Uni~; mv O.Jte: 7-26-93 ~onsc Un1ts: mv 

Zt-<1.00 RJs9S.90 Tl•!i5.00 ZlzO.OO Rl-9&.90 n•ss.oo 

R1•9S.90 z:z.-o.oo Tl•S5.00 R2•9&.90 z:z .. o.oo n•ss.oo 

Zj•O.OO TI•S5.00 RJ-9&.90 lj•O.OO TI•S5.00 R.3•9S.90 

Av;. Cone. of Curt. Cyl 76S.J ppm Av;. Cone. of Cwt.. Cyl 7611.3 ppm 

L-------JII '---------' 

L-------JI '-----1 _ 

Calib r.:~tion Cun•c: 

Conco=n.tl'lltion• A +Bx~1:'+ Dx.l +Ex 

r-0.99999 

Consl.ant.s! 

3•6.743455 

o-o.ooot :.:5303 

CR.'A 1662 

A -o.OOOOS0096 

C-Q.ot6-43769 

"""' 

"~:.:-·- ._-.; 

::-... :-~.···-.• : .'. Spc:ci:~.l Notes 

: :;_:, :: .-",_;;: .. - Ir this product il; wed fur Acid Ibin R.ule CompU:~nct-, the Acid R11in E.~.:piution Dou noted above 

- ' ··:~· :tppU~ per -10 CFH P:.~rt 75, App~ndli II. Othenvbe,lheCenera/ £;.pir111ion D(JJe applies.. 
AGA Gas, Inc. 

CERTIFICATE OF ANALYSIS 

EPA PROTOCOL tl. 

PERFORMED ACCORDING TO SECTION 3.0.4 

FILE NUMBER: EPA1~85 

CYLINDER NUMBER: CC99248 

PRESSURE: 2000 PSI 

PRODUCTION NUMBER: 03930967 

CERTIFICATION DATE: April 28, 1993 

EXPIRATION DATE: October 28, 199~ 

CERTIFICATION PERIOD: 18 Months 

CERTH'IED 

COMPONENT 

Sulfur Dioxide 

CERTII!'IED 

CONC. 

2H PPM 

BALANCE GAS: Nitrogen 

ANALYZER 

MAXE/MODEL/SERIALt 

Therno electron/tO/ 

40-17472-170 

ANALYTICAL PRINCIPLE: rluorescence 

REFERENCE STANDARD: 

MULTIPOINT 

CALIBRATION 

3/{/93 

SRM NUMBER 

Gl'!IS 

CYLINDER NUMBER CONCENTRATION 

CC71213 513.7 PPM 

ANALYSIS tl ANALYST: M.R. DATE: ~-13-93 

ZERO REF. TEST DEVIATION 

GAS GAS GAS RESULT FROM THE 

I MV) {!'IV) I MV) {PPM) MEAN {') 

0. 70 513.80 242.80 242. t PPM 0.00' 

0. 70 513.80 242.80 242. t PPM 0.00' 

0. 70 513.80 H2.80 242. t PPM 0.00' 

MEAN: H2. ~ PPM 

ANALYSIS f2 ANALYST: M. R. DATE: 4-27-93 

ZERO REF. TEST 

GAS GAS GAS 

{MV) I MV) I MV l 

-.86 511.\10 2H. 70 

-.86 511.90 2H. 70 

-.86 511. 90 2H. 70 

MEAN: H6. 0 PPM 

DEVIATION 

RESULT rROM THE 

I PPM! MEAN {') 

246.0 PPM 0.00' 

246.0 PPM 0.00' 

246.0 PPM 0.00' 

'-~~-~_:,~~---

MICHAEL SICKMILLER 

QUALITY CONTROL SUPERVISOR 

--------------------------------------------------------------------~/' ) 

AG"' G•s In<: 

5-I~ T "-'O"CKI~OI i'!loaO 

._.,...,...,.._ ·::"~ ~.lSJ~ 

, .. /---

i419•d9J-I;4T\ 
AGA Gas, Inc. 

CERTIFICATE OF ANALYSIS 

"EPA PROTOCOL 11" ORDERt 12920520 

CYLINDER NUMBERS: FF-40999 

CERTIFIED CONCENTRATION: 49.47 PPM SULFUR DIOXIDE 

BALANCE GAS: NITROGEN 

CYLINDER PRESSURE: 2015 PSI 

DATE OF CERTIFICATION: DECEMBER 21, 1992 

CERTIFICATION EXPIRATION: JUNE 21, 1994 

SR~I INFORMATION: 

SRM NUMBER 

1693A 

CYL. NUMBER 

FF-28604 

CONCENTRATION 

47.6 PPM S02/N2 

THIS ASSAY/CERTIFICATION WAS PERFOR~IED ACCORDING TO 

SECTION 3.0.4. 

THE ANALYSIS AND CERTIFICATION WERE PERFORtlED AT: 

AGA SPECIALTY GAS. INC. 

6421 MONCLOVA RD. 

MAUMEE. OH 43537 

BY MICHAEL SICKMILLER, QUALITY CONTROL SUPERVISOR 

INSTRUMENTS USED: 

SULFUR DIOXIDE: 

EPA1179 

AOA G.u II'IC-

.,..21 Moroclo'w• Road 

Maumee. Qtuo 4.3537 

THERMO ELECTRON CORP. 

PULSED FLUORESCENCE 

MODEL 40 

SERIAL I 40-17472-170 

CALl~RATl 12-18-92 

7 - .. MICHAEL 

~~ 

SICKMILLER "'" 

QUALITY CONTROL SUPERVISOR 

Fu 

JJOOJS 
r 

r 

.I 

r 

,--: 

APPENDIXD 

' 

PARTICULATE FIELD DATA 

f -

I. 

I 

f 
0 -

' . I 

I 

I 

Network Environmental, Inc. 

PITOT TRAVERSE DATA 

COMPANY NAME: HICBIGAII DIVISION - U.S. BRICK TEST DATE: 5/27/94 

COMPANY LOCATION: CORUNNA, KICBIGAII 

SOURCE NAME: KILN tl EXBAUST 

SAMPLING STAFF: ENGELIIARDT / SKITB 

RUN NUMBER: 1 ts CARBON DIOXIDE: 3 

STACK RADIUS, in.: 19.5 ts OXYGEN: 0 

GAS TEMPERATURE, Deg F: 288 ts CARBON MONOXIDE: 16 

STATIC PRESSURE, in. 820: -.26 PITOT FACTOR: .87 

BAROMETRIC PRESSURE: 28.92 

POINT VELOCITY PRESSURE, INCHES OF WATER 

PT. LOCATION, PORT 

t INCHES 1 2 

1 1.71 0.18 0.18 

2 5.69 0.23 0.22 

3 11.54 0.24 0.26 

4 27.45 0.30 0.28 

5 33.30 0.30 0.25 

6 37.28 0.27 0.25 
i 

,. 

' 

Network Environmental, Inc. 

SAMPLING TRAIN DATA 

COMPANY NAME: KJ:CBIGAN DIVISION - U.S. BRICK TEST DATE: 5/27/94 

COMPANY LOCATION: CORtJliNA, KJ:CHIGAN 

SOURCE NAME: KILN t 1 EXHAUST 

SAMPLING STAFF: ENGZL!IARDT / SKJ:TH 

SAMPLE NUMBER: 1 IHPINGER BOX t: 1 GAS METER START: 660.702 

TYPE OF TRAIN: MDNR-5B FILTER SET t: 34 METER CAL. FACTOR: .991 

NOZZLE DIA, in: .3124 PRIM. FILTER t: DH-585 CLOCK TIME START: 7: 4 7 

VENTURI NUMBER: SEC. FILTER t: BH-585 METER TIME START: 0 

CONTROL BOX t: 3072 BAROMETRIC PRESS: 29.20 METER TIME STOP: 1 

PITOT CAL. FACTOR: .87 

VELOCITY RATE MTR GAS METER PUMP GAS METER STACK 

PRESSURE PRESSURE READING VAC. TEMP. , F TEMP. 

PORT POINT IN. H20 IN. H20 CU. l"T. IN. HG IN OUT F 

1 6 0.28 2.28 664.150 3.00 80 80 273 

5 0.30 2.43 669.777 2.00 80 79 275 

4 0.28 2.28 673.460 2.00 80 79 275 

3 0.24 1.97 677.260 2.00 81 79 273 

2 0.22 1.81 680.260 1.50 81 79 272 

1 0.17 1.42 682.155 1.00 81 79 270 

2 6 0.27 2.20 686.140 2.00 78 76 271 

5 0.25 2.05 690.260 2.00 81 76 270 

4 0.27 2.21 693.970 3.00 83 76 271 

3 0.26 2.13 697.390 3.00 84 76 272 

2 0.25 2.05 702.000 2.50 85 75 272 

1 0.18 1.51 705.226 2.00 86 76 268 
Network Environmental, Inc. 

SAMPLING TRAIN DATA 

COMPANY NAME: MICHIGAN DIVISION - U.s. BR.ICK TEST DATE: 5/27/94 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: lULN tl EXIIAOST 

SAMPLING STAFF: ENGEL!IARDT / SMITH 

.. SAMPLE NTJM!IER: 2 IMP INGER BOX t: 1 GAS METER START: 705.325 i 

TYPE 01!' TRAIN: MDNR-5B FILTER SET t: 27 METER CAL. !!'ACTOR: .991 

NOZZLE DIA, in: .3124 PR.IM. FILTER t: DH-514 CLOCK TIME START: 9:26 

VENTURI NUMBER: SEC. FILTER t: BH-574 METER TIME START: 0 

CONTROL BOX t: 3072 BAROMETRIC PRESS: 29.20 METER TIME STOP: 1 

r 

PITOT CAL. !!'ACTOR: .87 

VELOCITY RATE MTR GAS METER POMP GAS METER STACK 

PRESSURE PRESSURE READING VAC. TEMP.' I!' TEMP. 

PORT POINT IN. H20 IN. H20 co. I!'T. IN. HG IN OUT p 

2 6 0.26 2.12 709.200 3.00 76 76 269 

5 0.26 2.13 713.030 3.00 81 76 270 

4 0.27 2.22 717.030 3.00 87 77 272 

3 0.26 2.15 720.980 3.00 90 78 271 

2 0.25 2.07 724.790 3.00 92 79 271 

1 0.19 1.60 728.165 2.50 93 79 269 

1 6 0.28 2.31 732.310 3.00 90 81 273 

5 0.29 2.39 736.480 3.00 93 81 275 

4 0.27 2.23 740.540 3.00 94 82 276 

3 0.24 1.99 744.300 3.00 95 82 276 

2 0.21 1.75 747.830 2.50 95 83 277 

1 0.16 1.37 750.884 2.00 95 84 268 

q; 
,. 

I 

,-

' 

r· 

Network Environmental, rnc. 

SAMPLING TRAIN DATA 

COMPANY NAME: MICHIGAN DIVISION - U.S. BRICK TEST DATE: 5/27/94 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: KILN j 1 EXBAUST 

SAMPLING STAFF: ENGELHARDT / SMITB 

SAMPLE NUMBER: 3 IMPINGER BOX t : 1 GAS METER START: 750.97 

TYPE OF TRAIN: MDNR-5B FILTER SET t: 1 METER CAL. FACTOR: .991 

NOZZLE DIA, in: .3124 PRIM. FILTER t: DH-562 CLOCK TIME START: 10:50 

VENTURI NUMBER: SEC. FILTER t: BH-562 METER TIME START: 0 

CONTROL BOX t: 3072 BAROMETRIC PRESS: 29.20 METER TIME STOP: 1 

PITOT CAL. FACTOR: .87 

VELOCITY 

PRESSURE 

PORT POINT IN. H20 

RATE MTR GAS METER PUMP GAS METER STACK 

1 6 0.27 

5 0.29 

4 0.28 

3 0.23 

2 0.21 

1 0.16 

2 6 0.26 

5 0.26 

4 0.27 

3 0.26 

2 0.24 

1 0.19 

PRESSURE 

IN. H20 

2.08 

2.23 

2.16 

1.79 

1.65 

1.29 

2.03 

2.03 

2.11 

2.04 

1.89 

1.53 

READING 

CU. FT. 

754.800 

758.840 

762.910 

766.350 

769.720 

772.626 

776.430 

78.370 

784.430 

788.530 

792.470 

796.044 

VAC. TEMP., F TEMP. 

IN. HG IN OUT F 

2.50 84 84 274 

2.50 86 83 274 

2.50 91 83 275 

2.50 94 84 276 

2.00 96 85 275 

2.00 97 86 268 

2.50 93 86 274 

2.50 96 86 275 

2.50 99 87 276 

3.00 101 88 275 

2.50 102 89 275 

2.00 102 89 269 
I 

Network Environmental, Inc. 

ORSAT ANALYSIS DATA 

COMPANY HAHE: MICHIGAN DrviSION - U.S. BlUCK TEST DATE: 5/27/94 

COMPANY LOCATION: COROIIHA, MICHIGAN 

I ' 

SOURCE HAHE: lULH U EXHAUST 

SAMPLING STAFF: EHGELIIARDT I SMITH 

DATE OF ANALYSIS: 5/27/94 METHOD: KOLTIPOIHT INTEGRATED SAMPLE 

PART CARBON DIOXIDE OXYGEN CARBON MONOXIDE 

SMPL COHT RON 

• • • FINAL INIT. " FINAL IHIT. " !'INAL IHIT. " 

1 1 1 3.4 o.o 3.4 19.2 3.4 15.8 19.2 19.2 o.o 

2 3.2 o.o 3.2 19.2 3.2 16.0 19.2 19.2 o.o 

3 3.2 0.0 3.2 19.0 3.2 15.8 19.0 19.0 0.0 

2 2 1 3.2 0.0 3.2 18.6 3.2 15.4 18.6 18.6 o.o 

I 2 3.2 o.o 3.2 18.6 3.2 15.4 18.6 18.6 0.0 

3 3.2 0.0 3.2 18.6 3.2 15.4 18.6 18.6 0.0 

3 3 1 3.0 0.0 3.0 18.4 3.0 15.4 18.4 18.4 0.0 

2 3.0 o.o 3.0 18.4 3.0 15.4 18.4 18.4 0.0 

3 3.0 o.o 3.0 18.4 3.0 15.4 18.4 18.4 0.0 
Network Environmental, ~nc. 

LABORATORY AliDILYS:ts REPORT 

COMPANY !fAME: HICB~GAN D:rvJ:S~ON - U.S. .BIIJ:CX TEST DATE: 5/27/94 

COMPANY LOCATION: CORUNNA, HICl!J:GAN 

SOURCE !fAME: KILN tl EXHAUST 

SAMPLING STAFF: ENGELHARDT / SliJ:TB 

DATE SUBMITTED TO LAB: 5/27/94 ltECEIVED BY: DDE 

DATE REPORTED FROM LAB: 6/2/94 CRRHTST(S): RSC 

PARTICULATE ~N SAMPLE NUMBER 1 

--i'~cm.ATE WEJ:G!I'r GAD!, JIGS.----- CAPTURED WATER 

LAB SAMPLE ALT 1 ALT 2 

IDENT. IDENT. STD. s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

~-- 1 DB-585 6.60 10.0 86.0 

: BB-585 0.00 

NW-1 2.50 

TOTALS 9.10 0.00 0.00 10.0 86.0 

PARTICULATE ~N SAMP'Ll!! N1lMBER 2 

---PART~cmJI."l'E lii!!:IG!I'r GlUlf, I!GS.----- CAPTURED WATER 

LAB SAMPLE ALT 1 ~2 

IDENT. IDENT. s-ri). s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

2 DB-574 8.40 10.0 86.0 

BB-574 0.00 

NW-2 3.30 

TOTALS ~1.70 ll.OO 0.00 10.0 86.0 

PARTICULATE ~N SAMP'Ll!! l!!TJV!!l!l! 3 

--PART~CULA-rE WBIG!I'r GADI, JIGS.---- CAPTURED WATER 

LAB SAMPLE ALT 1 ALT2 

IDENT. IDENT. STD. s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

3 DB-562 6.80 9.0 84.0 

BB-562 0.00 

NW-3 4.00 

TOTALS u.so o.oo o.oo 9.0 84.0 
~ 

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APPENDIXE 

. CALCULATIONS 

.• 

I· ;lr 
I ! ' 

Network Environment4l, rnc. 

CALCULATrON FORMULAs 

MorsTURE TRAIN CALCULATrONS: 

M1. BAROMETRJ:C PRESSURE, inches of Mercury 

K2. DtlRATrON OF SAMPLE, minutes 

K3. METER CALrBRATrON FACTOR 

M4. AVERAGE METER TEMPERATURE, degrees F 

MS. AVERAGE METER PRESSURE, inches of water 

M6. METER VOLUME, ACTUAL, cubic feet 

M7. METER VOLUME, STP, cubic feet 

530 

M7 = K3 * M6 * ---------- * M4 + 460 

M1 + .07355 * K5 

------------------ 29.92 

MS. LrQUrD VOLUME OF WATER CONDENSED, milliliters 

K9 • VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet 

r·· K9 = MS * 0.0474 

i 

M10. TOTAL GAS SAMPLED, @ STP, cubic feet 

M10 = M7 +K9 

Mll. PERCENT MOrSTURE 

M9 

M11 = * 100 

M10 

EXHAUST GAS CALCULATrONS: 

G1. STACK DrKENsroNs, inches 

G2. AREA OF STACK, square feet 

G2 (ROUND) = 

3.14159 * (DrA/2)•2 

--------------------- 144 

wrDTB * LENGTH 

G2 (RECT.) = 

144 

G3. BAROMETRJ:C PRESSURE, inches of Mercury 

G4. STATrc PRESSURE rN STACK, inches of water 

GS. STACK GAS TEMPERATURE, degrees F 

G6. AVG. SQRT VELOCrTY PRESSURE OF POrNTS SAMPLED 

G7. PERCENT MOrSTURE AT TEST LOCATrON 

G7 = 

P13 

P14 

* 100 
Hetwork Environmental, Inc. 

r CALCULATION l"ORHULAS CONTINUED 

GB. PERCENT MOISTURE BEl"ORE COLLECTOR 

G9. DRY GAS COMPOSITION, t02, tC02, tCO, tN2 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

t02 - 0. 5 * tCO 

G10 = 100 * ----------------------------- .264 * tN2 -.t02 + .5 *teo 

G11. DENSITY, DRY, @STP, lbs./cu. ft • 

• 0827 * t02 + .1137 * tC02 + (tCO + tN2) * .0724 

G11 = -------------------------------------------------- 100 

G12. DENSITY, WET, @STP, lbs./cu. ft. 

100 - G7 G7 

G12 • G11 * ---------- + .0465 * 

100 100 

G13. DENSITY, WET,.@ STACK CONDITIONS, lbs./cu. ft. 

530 G3 + .07355 * G4 

G13 = G12 * ---------- * ------------------ G5 + 460 

G14. MOLECULAR WEIGHT, DRY, lbs./mcle 

G14 = G11 * 386.9 

G15. AVERAGE GAS VELOCITY, feet/minute 

1096 

G15 = P5 • G6 • -----------

G16. STACK GAS FLOW RATE, ACl"M 

G16 = G2 * G15 

G17. STACK GAS FLOW RATE, SCl"M 

SQRT(G13) 

29.92 

530 G3 + .07355 * G4 

G17 = G16 * ---------- • ------------------ G5 + 46 0 29.92 

G18. STACK GAS FLOW RATE, DRY, DSCl"M 

100 - G7 

G18 = G17 * ---------- 100 

/ { _ -7 _) 
I 

1 

~-

Network Environmental, Inc. 

CALCULATION I!'ORKIJLAS CONTINUED 

PARTICULATE TRAJ:N CALCULATIONS: 

Pl. NUMBER 01!' POINTS SAMPLED 

P2. DURATION 01!' SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, square feet 

P5. 

P6. 

P7. 

PS. 

P9. 

3.14159 * (P3/2)•2 

P4 = ---------~---------- 144 

PITOT CALIBRATION !!'ACTOR 

METER CALIBRATION !!'ACTOR 

AVERAGE FILTER TEMPERATURE, degrees I!' 

AVERAGE METER TEMPERATURE, degrees I!' 

AVERAGE METER PRESSURE, inches of water 

PlO. METER VOLUME, ACTUAL, cubic feet 

Pll. METER VOLUME, @ STP, cubic feet 

530 

Pll = PlO * P6 * ---------- * PS + 460 

G3 + .07355 * P9 

29.92 

Pl2. LIQUID VOLUME 01!' WATER CONDENSED, milliliters 

Pl3. VAPOR VOLUME 01!' WATER CONDENSED, @ STP, cubic feet 

Pl3 = Pl2 * 0.0474 

Pl4. TOTAL GAS SAMPLED, @ STP, cubic feet 

Pl4 = Pll + Pl3 

Pl5. WEIGHT 01!' GAS SAMPLED, DRY, pounds 

Pl5 = Pll * Gll 

Pl6. WEIGHT 01!' GAS SAMPLED, WET, pounds 

Pl6 = Pl4 * Gl2 

Pl 7. PERCENT ISOIUNETICS 

100 * 29.92 * (G5 + 460) * Pl4 

Pl7 = ------------------------------------------ 530 * (G3 + .07355 * G4) * P2 * P4 * Gl5 
I 

f c 

I 

,. 

I 

f 

'. 

I 

! 

Network Environmental, Inc. 

CALCULATION FORMULAS CONTINUED 

CONCENTRATION CONVERSION FACTORS: 

Pl8. 50 - EXCESS AIR, Al!'ER COLLECTOR 

Gl4 + 18 * G7/(l00 - G7) Pl8 a ------------------------------------------------------- .1826 * %N2 - 2.0592 * %02 + Gl4 + 18 * G7/(l00 - G7) 

Pl9. 50 % EXCESS AIR, BEFORE COLLECTOR 

Gl4 + 18 * G7/(l00 - G7) Pl9 = ------------------------------------------------------- .1826 * %N2 - 2.0592 * %02 + Gl4 + 18 * G8/(l00 - G8) 

P20. MOISTURE BEFORE COLLECTOR 

P20 = 

Gl4 + 18 * G7/(l00 - G7) 

Gl4 + 18 * G8/(l00 - G8) 

PARTICULATE EMISSION CALCULATIONS: 

El. TOTAL WEIGIIT PARTICULATE COLLECTED, grams 

E2. LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL 

1000 

E2 = El * -----------

454 * Pl6 

E3. LBS. PARTICULATE/lOCO LBS. GAS, DRY 

E3 = E2 * P20 

E4. LBS. PARTICULATE/lOCO LBS. GAS, WET I so• EA 

E4 = E2 * Pl8 

ES. LBS. PARTICULATE/lOCO LBS. GAS, DRY, 50% EA 

ES • E2 * Pl9 

E6. GRAniS/DRY STANDARD Ct!BIC FOOT 

El * 7000 * 100 

E6 = ------------------------ 454 * Pl4 * (100 - G7) 

E7. POUNDS/HOUR 

Gl7 * Gl2 * 1000 * El * .06 

E7 s ----------------------------- 454 * Pl6 

E8. POUNDS/KILLION BTU 

E7 

E8 • --------------------- CAPACITY, MM BTU/BR 

j{) / 
I 

I ' 

' I 

r -

l 

1. 

2. 

3. 

SULFUR DIOXIDE CALCULATIONS 

Concentration ("m Mg!M3

) 

MgtM' - (PP1'n CM. w ./24.2l 

where: M.W. - molecular weight - 64 for 502 

Air Flow Rate in Dry Standard Cubic Meters Per Minute (DSCMM) 

DSCMM - (DSCFM) (0.0283) 

where: DSCFM - Dry Standard Cubic Feet Per Minute 

Emission Rate (in LbS/Hr) 

LbS/Hr - {Mg!M3

) (M'!Minl (60 Min!Hr) (2.205 Lbs/Kg) CK&'J.OOO g) WlOOO mg) 

Lbs/Hr - (M!YM'l (DSCMM) (1.323 x 10-•) 
I 

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r- APPENDIXF 

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c = ;;v~ CP.:C,...,,.. .,;V"'FP-~ CP.~ = "" c~r -~ 

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Company: 

Location: 

Source: 

Date: 

Operator: 

Monitor: 

,.., ,c.h 1~,-" 1); ~·I S I.D o"\ 

t). s. """Bfol.ic..lc.. 

C o~tv r\t\o, JLI X. I 

K,\" ~ I 'E)< h<~v~ 

s /:J.'=t /o, 'i 

"'DD~ 

?.>c.. 30c;l... 

Sv\-\v~ v•o><•j< 

Span Value (PPM): 1 Soo 

Page#: /1 { 

Calibration Response, PPM 

Calibration Analyzer Gas Cone. Direct System Injection .. 

lnjeclion Cal. Error, Drift, % of Span Sy

PPM Pretest Post 1 Post2 Posl3 %of 

~ oes,: '55" 

ot-:1~ 

ot:J:o5 Jo: 35' t~: <;f{ Span Gas Test 1 Test2 Tesl3 Pretest 

0 0 0 0 1 '1 l!l!!!/1 o. 00 0. ')..(g 0. ;;;l(.. b. DO 

5o 5o 

1//~'/ IIIII 1////; llffi'll b.DO VII/I /II// ill/!/! IIIII/ I

;)_ •·H .;25"0 :1..31- .(5b ~L{Cf 

~Lf£6 

c:L 1-/o 

D.~& 

o.~o D:-=13 -o/i31- 

·~ 'HoB V~Wfi'JII!!_Ilill!_ 1/J/11 ill/Ill V#l/ //l!ii/1111; f'&'!V

~ 

"'') 

• As Defined By EPA Method, This Value Must Be The Same As The Relevant Direct Injection Value " Run Zero and either mid or high calibration gas, whichever one Is closer to actual stack concentration Analyzer cal. error,% of span= (dir. In]. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% Drift, %of span= (relevant posllesl sys. inj. cal. response, PPM- sys. lnj. pretest cal. response, PPM) x 100% I (span value, P

System bias,% of span= (relevant sys. lnj. cal. response, PPM- dir. in]. cal. response, PPM) x 100% I (span value, PPM): Lim
INCORPQQAT!.D 

Clients: U. ~. 'O.;,.c.k 

Pitot Traverse Data Form 

Proj. No.:--------

'I ant: _.LJ1..1J.:,·c.,._'v-:Q~~f~u::::>.__,'J)~; v~·t_;jS~• o;u' oc.....--=-:__.~<V:e:·,S~·:__'i3~~:±'<-!0..\.:.s.. _______ -f--------

Sour~e: ----LK::>...:.,u.\ nL.I....!:Jf:::O-L[ ------- staff: -~:::::.a.::e.l~~~£1 ot?.d~+-'--;f-/_' J::'B::..:.· -'==S~,.,!.!..A.!...:-h:.!._ __ 

:a II ,/., 

Stack Size. Inches -...:2:......!- l...:"'F-'F--....-----

Gas Temperature, •F --'t*~_...!:;.~q,.:;_~-=-1-~-~/:l.=l\ ~ 

Pitct Tube 

1.-=t- I 1 0 . I tri JJ.,Q, 1 n. \'V 

r ?.~Cf 2 ('), d.3 1""~ 2 ().~~ 

J--1J.5L{ 3 D. ;t ~ '1-r 3 n.~f..o 

.:21--'1~ 4 o. 'So 7A~ 4 o.d...'? 

I '3).30 5 o, 30 ~- 51 o.~~ 

31-. ;2. g 6 o. ~'1- }'( 6 D .;)..S 

r 7 7 

I 8 8 

I 

9 9 

I 10 10 

11 In 

r 12 12 

I 13 13 

~ 14 14 

f~t-1.:: .lo!)o 

r Wall Thickness Ac.fM:. 11-,00 Lz 

I Zero Point Sc..rl'\ .,_ 1\ l ~39 

i)~ ...... ::. I 0 S'~ I V I 

Port SizefType 'J.-=- o.a_'\o~ 

~~so ~ ll., J. ~. L\4(,) 

Barometric Pressure, "Hg _:2::::.s,8~,..i.91Z.;;?,5L_ __ _ 

·~ 

Static Pressure, "H20 -o, ;;:(Cs:! 

%O. ______ %C0

2 ______ _ 

I 1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

~1'· 

'1;(1'1 

f--

1: 

0 

c. 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

5Jfl., ~ 

··-Velocity 

.. Pressure 

- ~H20 

' 
· NETWORK ENVIRONMENTAL, INC. 

Sample #--..1.----- Fi~er Set# ___;;;3_,=} ___ _ 

Nozzle # 0 · 3 I~ 4f PrimaJY Fmer It "DH - "i~ ;' 

"Ctl- /:'C'? 

Rate Meter#------- Secondary Filter# ~ 

Control Box # 3D]:2l. Type Train ,Y'DtJR- 55 

Condenser Box # Mls. H2

0 Cond. -"-'-TI.:..(a __ _ 

r(J- 0. '1'f 08 f;\o-\- ~ I .,_ 0 ·~1- - Vel p Pump Meter Temp 

Press Venturi Gas Meter Vac. "F 

Port Point 'H20 'H20 Reading 'Hg In Out 

I &, o.o;?.B .;<.~~ '&&1. I'S"' l")•O 1S't"l ~0 

s 0.30 ~.'{3 ~to9.f.H :<.o S'o "19 

1 o .:J.B .:2·~ CP7-3.L{~ :J.o ~0 14 

9 0 .;;J.tf /.'ll- u 1~~(;, .:?.o <gf 1-1 

;J.. o.a;z. j,tg( u, '8o. 1'-{ /.S' 8{ 'T~ 

I o.lr /. t.f.;;.. t_g"W-. lf5' f,o 'B( tc! 

~ ~ 0·~1 ;2..~0 6 t;c;,, tto ~.o 7-S t~ 

b {) .;;.5 ;( .oS"" {/~(). ;)..~ ~.o ~I -=t(p 

'i t;.~f- ~-~I Lo q .3. '1-:t- ~.o <63 i-Co 

.:3 o.~& .;<.13 u,q-:;..CJr 3.o 8'1 -=t~ 

2 o.:25 ;;J .o S" +o-:2. oo ::l.f( g? ""1~ 

I o .IS /.sr '+oS: J. ;;,~ ~.o I '3G 1-<o 

Stack Box 

Temp 

"F 

Temp 

"F 

iil.~ 

;;2+~ 

::J.-=r-s2-=t3 

.:r:r ;2.. 

·~-:;o 

;:z. -=t-1 

.;2.-:t-o 

~1-1 

;2.--=t-:;l.. 

.;2-:tQ 

.:2~~ 

j/1 

.. 

Gas Bag It J 

Dryer#-~ I 

Notes 

-x;.;t.;.l 

~\<. AA 

"·""o rt ~;,., ~}j'l/~ 

,:-,;....! 

~1::. ~ .s-1-

o.cco r t:%,; ~ 

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It I 

o'6:S«J ~ 1; 

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NETWORK ENVIRONMENTAL, INC. 

Sample # _ __,d..=---- Fmer Set# _..::.~_:1-___ _ ~ u ~~~ Nozzle # 0 · .:>I~-, Primary Fi~er # "'l'll - ~ i 

Rate Meter# - Se«Jndary Filter #"'Bit- 5'--:r"' 

Control Box # 3o} ;l. Type Train t:j'Dr\1~ -~ 5 

-

Condenser Box # Mls. H2

0 Cond. ___..S"""/9.....__ __ 

'r'.l- o. 'l~o8 ?;iat .;;. I =- o. 81-

Date: 

Client: 

Barometric Press _c::2---.:.'f....:· ~::.:0=---­

lnrtial Gas Read -..LXo~S ..... _;;;3~~~s-__ 

Clock Meter Start-~•:......:::.D...J.'..:..;: Gl,'Z:..I.(p'L-_ 

Time Meter Start _ __,0=:=------

Time Meter Stop _---~. ___ _ 

Vel p Pump Meter Temp Stack Box 

Press Venturi Gas Meter Vac. OF Temp Temp 

Port Point "H20 "H 0 Reading "Hg In Out OF OF Gas Bag #..Z 2 

.,;2. ~ 1/).~{o ~.~~ -::to9 . ;<.:o ::;;.o ;I( ~ Dryer# J.{ 

G ':f(3.o3 "::7-(n ' o.;)Jt;, e1. (3 8.o 81 ;z-q.o :;.; Notes 

'-! " 

0· ::2.. t- ~.~~ "'1-1-=t-' 0 3 :3.o '8-=7- -=+-+ ~~ '- J::;·, +: .. 1 . -· 

- k~k. ~~+ 

3 ().~ ;).15"' r~o.'1~ 3.o 9o l-'8 .;;r:t-1 .... 

- 6.=-(('lfr. 

" . Mo> 

d.. 0·~5" ;2.o-:;.. "T :;)."{. T~ 3.o '1~ "::f'=t .z:t-( . e 1 S"'''l/. 

1-'1 

(J 

I n.l ~ 1.~0 7- ;2'8.JC9S ::z. s- Cf3 .;:2(o9 -n·o\ .. 1 

I {9 n.~'Zl :2.3{ T-3:<.3/ 3.o 9o '81 :2 -=73 ).c..!<. I es iO,Odoft~"' ~ 6.~9 ~::>9 =7'3~.L./~ 3."D q?; '81 .;:z'l-5 b&(~ 

.Lf 0. -;)..1- ~.;). "3 7'1'0.54( 3.o 9'1 '6~ :2-=t-4> zr 

3 0. -;). l-{ /.~ ""Hi. o-o :3-o '15\'8~ .:2':1. fo 

.).. o.-;;,{ /.'15" 1'"\1-. '33 ;2.5' Cj5 S3 ;7i-f,. 

/0 

\1 

I o. ~(o /.31- 7-5'o.'Bgl{ ;J.c q5' 8'/ :J..t.i6 'ji:.VD 

~r ~ .4r 

Jo:.;J.9 

.:10"'~ 

'"'''0 

1;J.o?S 

tO, 'j41 

c 

( 
· NETWORK ENVIRONMENTAL, INC. 

Date: 5,~:2.~{J;j Client:.k.~ 

Plant tf•'c.b,~~c-:D!v'rsio"- U.S. :Ekid.-

Source I< 1 \,... # J "'£" hd,!).Sf 

Sample# 3 Finer Set# I Barometric Press .;J. Cf. ;<o 

Nozzle# C).31:lj Primary Finer# "'I'H - 5 &:;,. lnrtial Gas Read JlS"D.'1Jro - "B ~- 51,.,;}._ /O.'S"o Rate Meter# Secondary Filter# · · Clock Meter Start 

Control Box # 30,..;2. Type Train /-iD/1/£2.-5'6 Time Meter Start 0 

Condenser Box # Mls. H2

0 Cond. "l$ ~ Time Meter Stop 

Y-1:::. o. '1'1 Cl '8 A1o-J. # I :: o · 'B 1-

Vel p Pump Meter Temp Stack Box 

Press Venturi Gas Meter Vac. OF Temp Temp 3 

Port Point "H20 "H 0 Reading "Hg In Out OF OF Gas Bag# 1 2 

I & ().:J.?- .;:.! .o1? ":1-5'1. ~0 [f'l;"!> QL.j 'j("'j ~~'"1 Dryer# _s5 C). d-. 'I .;2.~3 -rs'B.S'f ~.s % ~ .=rr'1 Notes 

'{ D.-;).. '8 ;;:;. . I~ 7f(.p~. 9 I 1-;<.s- CJ! ~"3 ;;J.-=t'S" ~ihc.l LaJ:. -r.~-4-

3 0·:<3 f.--=f-9 '16,(.,. 35' ;{.s 'JLJ l6'-( ;:J":fG:; ~.ccc ~~ 

:2. () .';l[ 1.~5" ~q.7~ ~.0 Cj~ 8'5" .::t15 

C! IS"""JJ, 0' 

I o.l(o /.~~ T-"t~.~a{.g ~-0 '17- 2>Co .:2u9 -n t\o, 1 ~.&.. 1c:. 

~ (s; o. ;;:l(o ~.03 -::r~ . .f-{3 ~.5' -~3 ~0;; ;;J."":f'l -rey; 

r; D·d-4 .;;< .o3 '?-~ .3-=t- :2.5 Cfc.r, '3~ d.l-5" O~f"i'), ~ 

t:Zk ''II. 

~ 0-~f .;(.!( 7-Z?'/ ,q3 .7.5 '79 'i?i- ;<-=/-CD ~ 

3 I /'l . 'J..b .2.d-f 7<B~. 53 3.o /o/ I'B'S' .2-::;sd. o. :)."/ /.scr t'l:?. LJ1- :;.s /o"J.. ~~ ;2..~5'" 

I o. 19 '·5:3 7'l~.di1 :2 .c /o;}. ~9 ..2~q "illS) ~ j1rs, 

AT 

//: 5'3 

/!} 
c -

,. 

'-

' 

ORSAT ANALYSIS 

· NETWORK ENVIRONMENTAL, INC. 

I Dale sl~x fqr 

I Prore-ct r. 

Integrated ~ Grab 0 

Sample No. Bag No. Run No. C02 02 

1 3.Lf 19.-:t 

1 

2 3.;2_ /9. ;J. 

I 

3 3.~ /9.o 

Avg. 

1 3.;;2. ;g, ~ 

d- 2 3·~ 18. (.., 

;)._ 3 3.~ ;g.c,; 

Avg. 

1 .,,0 /g ·1 

3 3 2 3.o /s.y 

3 3.o I 8'. 'i 

Avg. 

1 

2 

3 • 

Avg. 

1 . 

2 

3 

Avg. 

1 

2 

3 

Avg. 

IF/ 

co 

/f¥.;2. 

/9. ~ 

/9.o 

IS.~ 

I§ .j,g_ 

18.~ 

18.!-J 

/8.'( 

1'6.~ 
ENVIRONMENTAL 

Pitat tube calibration data. 

pr;cr TUBE IOE?tTil'ICA'ilCH IIU~i!~.~: _...:..:.lf_1.__ ___ cJ.n: /J}; /~? . /~ ;~ 

C~LISR~TEOSY: __ ~~~-------------------

.. 

~ ;:-;:: ~~(:) 

r c,r:~ 1 

=HzO c=HzO C!;VIA iiC~ 

FIUH MO. (in. HzOl (ir~. HzOl C;~(>l • C01 (J.l 

1 I . :J..L/ 0 I .J;r;- I. fb4 I ,flo..:l I 

2 I ,;] l/ D I .3/o j.g7/l .,";?<;' 

:J I .c;_u o I - 3 I "l I j'' cr I "1)1 

I - - ~ ..... , I:_ -~ 

c.~:::.:! c.-(~ 

=HzO ._., HzG a<vt.:.na~ 

RU,>t 110. (in. HzOl (in. HzOl C;(,l C;(:l • C01 CSI 

1 I ·,c)l/61 . v ,_7 c-1. u.? I Dn ( 

.z I } 1./ i) I . ? I 0 I. 771 I Ol::l...L 

:l ,!__ ih I . 1 l~ c;-l . f<iJ I o,-, I 

J 

::: 1 c,r,J. c.,r.:. a Fi e11 

1 P.VEAACE OEVt .. HION • tJ (A OR Bl • -MUSi SE >:;C.Cl 

J 

I C;: (SlOE;::.) -c;: !SlOE sJI--MuS7 se <:a.at 

'07 j/j ·----
Calibration Meter Identification: 1 Yds. _t....:I·:...::D::.:o::!-~--

I•

·

·

~~

•

Date: D 

j;J:a h '-( 

Motor Dox ldontlficalion: Q,o-.r·> Barometric Pressure (Pb): (19. 5/:i. 

··.·. 

... •····· ·.·· .... • Tem[Jeraturo . . · 

•• 

. 

·

. .· Callbrallon Meter nox Calibration Meter nox Calibration Or 

I lice ·. Meter I· Meter Meter Motor Meter Orifice M

. ·. 

1 Time ReadlllO Gas V()lume Gas··votumc Averaoo Average Pressure 

Pressure 

• 

. (i\ H) I (V !Is I ·. ·••··· •.· 1 .. _.··•·• . (V d I . . (td~l (I d) · I (i\p) . .•. ( e Dlllcrenllal . C

In 

u

2o 1 <ft~·-·• < •. > < Cl F. • " In 112 0 I min 

1·_ ........... ·.·· ., tl. .. . . .• ·•····· ... F .•. I (t.ll@) ·. 

. < Stop J.o 3to ~~:3. 

~ 3_l: J/lt-. Stf'f (V::>.o /-(o.D O· "/(o 

Start /. 0 

31oa3.1-o~ '-/I u.... 1- Jl_12 (<;>3.0 7o.o D.'f(., g /.79oo /

Average f.o 5.D:J.d.. S".ot.dv ( ·;~ 9-·}· (_) fl-:.;.o o.'/(o 

Stop ,")_.D 3fo :i•j, {o 3 ;J 't.,·.[;. 'DIP I (9:3. ·" 7-19· 5" Q.(v~ Start Q..o ::Vo 3'-/.d.3f- '/18.3.5'1 (._,-;,,')- 2{.5' 0 ./o'f 7- /.'r;S5Cf o/

Average ;}_.0 S.J']_5' ~. 5"D'[ 6' .i. ~) ,- 7-?/.0 0-(o'/ 

Stop :1.0 'Vo 5o.')lo'3 '13'/, L) Jf.:, (u3·!/ t-'1.0 Q, Cjj-· 

Start .'3.0 ?.(.;,j_O.D?c tt~. CJ.til 6, r:· l:,)_.O o.Cf!} I I I /'JD'/1- o.

3-.J Average ~'). 0 /0.3'13 ){), [pL/9 . ~ ,- [S. 5' (), 'l!J' (u:j .. J Stor 'l· 0 3w!QO~~ ~'1?.55<.. (~3.5' 'Zin . :;- I· ::z5' 

Start '-f.D 1/ v'l(), '[(>• + '135: '181 (o'3. 5' '1'3. 5' J.a~ 

Average cr /.953w 0 

'/.o 9.t.o;Jq /0. otJj /.23. :;- 77.0 1.;1.5"" 

Stop 

Start 

~ I'G 

Average 

1--. :--: Stop 

Start 

Averar~e 

s(Vds)[( ld t 460)J[ Pb J Klso • 27.40 Yd • Yd V d (Ids + 460) (Ph ~( tdf }) /.WJ?S o.

(Kd)2 Averaoe 1 3. 6 

Kd = 

Yds(.Y!!L)~ 8 Tds 6 II Pds =[Pb ~(/' ~J] AH@ = 0.0319 Mt(_!_!!_>t t! 2 ~ Pb Yd Vd Klso
\.. . '- -

IT-D-Hi9 

Report of an ... 

Emission Study 

performed for ... 

Michigan Division 

U.S. Brick 

Corunna, Michigan 

. on 

Various Sources 

June 7 & 8, 1995 

010.08 

Network Environmental, Inc. 

Grand Rapids, MI 

!17 
.J 

I 

• 

J 

' 

oi 

E:SULTS 

ll.1 TABLE 1 

PARTICULATE EMISSION RESULTS SUMMARY 

KILN #2 EXHAUST 

MICIDGAN DIVISION· U.S. BRICK 

CORUNNA, MICIDGAN 

JUNE 7, 1995 

Air Flow Rate Concentration Mass Emission Rate 

Sample Time SCFM Lbs/1000 Lbs, Dry Lbs/Hr . ·. 

1 09:42·10:45 15,982 0.0010 0.06 

2 11:05·12:09 16,425 0.0011 0.07 

AVERAGE 16,204 0.0011 0.07 

ll.2 TABLE 2 

FLUORIDE EMISSION RESULTS SUMMARY 

KILN #2 

MICIDGAN DIVISION· U.S. BRICK 

CORUNNA, MICIDGAN 

JUNE 7,1995 

·. ·.· Air Flow Rate Concentration , .· Mass Emission Rate · 

Sample Time SCFM Mg!M' . .· . Lbs/Hr ... · ... 

lnlet Outlet lnlet Outlet lnlet Outlet 

1 14:10·15:38 13,204 16,337 111.44 0.23 5.66 0.014 

2 16:05·17:10 13,336 16,148 110.89 N.D.<ll 5.54 N.D.<'l 

AVERAGE<2 l 13,270 16,243 111.17 0.20 5.60 0.012 

(1) N.D. - Non Detected at 0.17 Mg!M' (0.010 Lbs/Hr). 

(2) Tbe outlet averages were calculated using ilie detection limit value for sample 2. 

2 
ll.3 TABLE 3 

SULFUR DIOXIDE (S02 ) EMISSION RESULTS 

MIClllGAN DMSION • U.S. BRICK 

CORUNNA, MIClllGAN 

JUNE 7 & 8, 1995 

·. 

. . Concentration Mass Emission Rate 

Source Sample Date Time. PPM .· Lbs/Hr ··.·.·. ··· 

Kiln #2 1 617/95 15:00·16:00 539 73.89 

Outlet 

2 617/95 16:31·17:31 445 61.00 

l AVERAGE 492 67.45 

Kiln #2 1 617/95 15:00·16:00 693 82.76 

Inlet 

2 617/95 16:31·17:31 576 68.79 

- AVERAGE 635 75.78 

Holding Room 1 6/8/95 12:43·13:43 N.D. N.D. 

#2 Dryer 1 6/8/95 16:56·17:56 3 1.19 

(1) N.D. = Non Detected at 1 PPM (0.20 Lbs/Hr). 

(2) The mass emission rates were calculated using 13,845 DSCFM for the Kiln #2 Outlet, 12,061 

DSCFM for the Kiln #2 Inlet, 20,392 DSCFM for the Holding Rocm and 40,131 DSCFM for 

the #2 Dryer. 

3 
l 

l 

., I 

I 

.. 

• 

• 

• 

I 

I 

I 

ill. DISCUSSION OF RESULTS 

The results of the sampling are presented in Tables 1 - 6 (Sections IT.1 - IT.6) . 

m.1 Particulate Emissions (Kiln #2) 

ill.l.1 Particulate Concentrations- The particulate emission concentrations on the Kiln #2 exhaust 

were 0.0010 pounds of particulate per thousand pounds of gas on a dry basis (Lbs/1000 Lbs, Dry) for 

sample one and 0.0011 Lbs/1000 Lbs, Dry for sample two. The average of the two samples collected 

was 0.0011 Lbs/1000 Lbs, Dry. 

ill.l.2 Particulate Mass Emission Rates • The particulate mass emission rates were 0.06 pounds of 

particulate per hour (Lbs/Hr) for sample one and 0.07 Lbs/Hr for sample two. The average of the 

two samples collected was 0.07 Lbs/Hr . 

m.2 Fluoride Emissions (Kiln #2) 

ill.2.1 fluoride Concentrations - The fluoride concentrations at the inlet to the pollution control 

device (PCD) were 111.44 milligrams per cubic meter (Mg'M3) for sample one and 110.89 Mg'M3 for 

sample two. The average inlet concentration was 111.17 Mg'M3

• The fluoride concentrations in the 

Kiln #2 exhaust were 0.23 Mg'M3 for sample one and non detected at 0.17 Mg'M3 for sample two: 

ill.2.2 fluoride Mass Emissions Rates - The fluoride mass rates at the inlet to the PCD were 5.66 

pounds per hour (Lbs/Hr) for sample one and 5.54 Lbs/Hr for sample two. The average of the two 

samples was 5.60 Lbs/Hr. The fluoride mass emission rates at the exhaust were 0.014 Lbs/Hr for 

sample one and non detected at a detection limit of 0.010 Lbs/Hr for sample two. The fluoride 

collection efficiency of the PCD averaged 99.8%. 

m.3 so. Emission Results 

ill.3.1 Kiln #2 S02 Concentrations - The S02 concentrations at the Kiln #2 PCD inlet were 693 

parts per million (PPM) for sample one and 576 PPM for sample two. The average of the two 

samples was 635 PPM. The S02 concentrations on the Kiln #2 exhaust were 539 PPM for sample 

one and 445 PPM for sample two. The average of the two samples was 492 PPM. 

ill.3.2 Kiln #2 S02 Mass Rates - The S02 mass rates at the Kiln #2 PCD inlet were 82.76 Lbs/Hr 

for sample one and 68.79 Lbs/Hr for sample two. The average of the two samples was 75.78 Lbs/Hr. 

7 
, 

• 

The S02 mass emission rates from the Kiln #2 exhaust were 73.89 Lbs/Hr for sample one and 61.00 

Lbs/Hr for sample two. The average of the two samples was 67.45 Lbs/Hr. The S02 reduction 

efficiency for the two samples averaged 11.0%. 

ill.3.3 Holding Room S02 Emissions - S02 was non detected at a detection limit of 1 PPM (0.20 

Lbs/Hr) for the sample collected from the holding room exhaust . 

ill.3.4 #2 Dryer S02 Emissions - The S02 concentration for the #2 Dryer exhaust was 3 PPM (mass 

emission rate of 1.19 Lbs/Hr). 

jJ-f 
I 

J 

J 

J 

_j 

ill.6.2 Holding Room Total VOC Emissions- The Total VOC emissions were 12.4 PPM (1.77 Lbs/Hr) 

for the sample collected from the Holding Room exhaust. 

IV. SOURCE DESCRIPTION 

The source tested on 6/7/95 was the exhaust of Kiln #2. The kiln is gas fired. The exhaust from the kiln 

passes through an emission control system consisting of a cooler followed by a mixing chamber and then 

through a baghouse prior to exhausting to atmosphere through the exhaust stack. Lime is sprayed into 

the system between the cooler and the mixing chamber. The source tested on 6/8/95 was the holding room 

exhaust associated with the #2 Kiln. 

During the sampling, modular size hickory ridge bricks were fired. The kiln speed during the testing was 

12 cars per day. Charge times, brick weight and lime feed rate information can be found in Appendix D. 

V. SAMPLING AND ANALYTICAL PROTOCOL 

V.l Particulate 

The particulate emission sampling was conducted in accordance with U.S. EPA Reference Method 5. 

Method 5 is an out of stack filtration method that employs a heated probe and filter (maintained at 

250 cF plus or minus 25 °F). Two (2) samples were collected from the Kiln #2 exhaust. Each sample 

was sixty (60) minutes in duration, and had a minimum sample volume of thirty (30) dry standard 

cubic feet. The samples were collected isokinetically and analyzed for total particulate by gravimetric 

analysis. All the quality assurance and quality control procedures listed in the method were 

incorporated in the sampling and analysis. 

V.2 Fluoride 

The fluoride emission sampling was conducted in accordance with U.S. EPA Reference Method 13B. 

The samples were collected in deionized distilled water isokinetically as described in the method. 

Each sample was sixty (60) minutes in duration and had a minimum sample volume of thirty (30) dry 

standard cubic feet. Two (2) samples were collected simultaneously from the inlet and outlet of the 

Kiln #2 PCD. The samples were analyzed for fluoride by specific ion electrode analysis. All the 

quality assurance and quality control procedures listed in the method were incorporated in the 

sampling and analysis. 

9 
V.3 Sulfur Dioxide 

The S02 determinations were performed in accordance with U.S. EPA Reference Method 6C. A 

Western Research Model721·M portable stack gas analyzer was used to monitor the S02 emissions. 

A heated teflon sample line was used to transport the exhaust gases from the stack to a gas 

conditioner to remove moisture and reduce the temperature. From the gas conditioner the stack 

gases were passed to the analyzer. The analyzer produces instantaneous readouts of the S02 

concentrations (PPM). 

The analyzer was calibrated by direct injection prior to the testing. A span gas of 857 PPM was used 

to establish the initial instrument calibration. Calibration gases of 222 PPM and 393 PPM were used 

to determine the calibration error of the analyzer. The sampling system (from the back of the stack. 

probe to the analyzer) was injected using the 857 PPM calibration gas to determine the system bias. 

After each sample, a system zero and system injection of 857 PPM were performed to establish 

system drift and system bias during the test period. All calibration gases used were EPA Protocol 

1 Certified. 

The analyzer was calibrated to the output of the data acquisition system (DAS) used to collect the 

data. A strip chart recorder was also used to record the data as a backup to the DAS. Each sample 

was sixty (60) minutes in duration. 

The DAS output, strip chart recorder data, and calibration data can be found in Appendix B. The 

S02 analyzer specifications and calibration gas certifications can be found in Appendix C. 
------ ')_, 

--(::___ 

..... 

"' ~ --~ ___) Conclonsor Coil Sample Tomporaluro -c ~ Fillers Tubing "'""' ~ ""'"' Probe ""'W'" I ~_[_~ - :JI ; ''· '751 c;.""""'l / II ~ . Healed leo nalh 1 flllorllox S-Typo Pllol Tube n . Pilot Manometer 

Orifice 

Tomporaluro Sensor ~· , ai~, ~- P•bo L] 

J _I 

Vacuum Uno 

~ Main Valvo 

Vac

Pilot Tubo 

Manometer Air Tlohl Pump 

Dry Gas Moler 

Partlcu
'--. 

~ 

v-

..... 

... 

Pilol/ 

Mnnomolor 

"" 

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leo Dalll 

lmplngors 

. Therrnornelers 

Orilico 

Tempor~o Se:or .....,._'\7101'--

;{- lui'-~- IJ=::;I ~II f 

Primary Secondary 

Pilol Tui'Jo I Filler Filler -I/"" U I Lj. Fillor / 

llolder Mnnomelur Ory Ga~ Mclor 

- • • 

Filler 

I 

Vacuum Uno 

Oy-Pass Valvo 

-r/ _£ tAl ' 

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Main Valve 

Vacuum 

Air Tiohl Pump 

Flu
I· 

r 

APPENDIX A 

· PARTICULATE EMISSION RESULTS & EXHAUST GAS PARAMETERS • 

·. 
Network Environmental, Inc. 

P.O. Box 2021 

Grand Rapids, HI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVISION, U.S. BRICK 

CORUNNA, MICHIGAN 

t2 KILN EXHAUST 

DATE: 6/7/95 

;:).7 /-
Network Environmental, Inc. 

EMISSION SOURCE SUMMARY 

STANDARD ANALYSIS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: f2 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

STACK RADIUS, inches 

AREA OF STACK, sq. ft. 

STATIC PRESSURE IN STACK, in. H20 

STACK GAS TEMPERATURE, deg. F 

PERCENT MOISTURE AT TEST LOCATION 

DRY GAS COMPOSITION: % OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

DENSITY, WET, @ STP, lbs./cu.ft. 

MOLECULAR WEIGHT, DRY, @ STP, lbs • /mole 

AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: ACFM 

SCFM 

SCFM, DRY 

EMISSIONS: 

LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL(l) 

LBS. PARTICULATE/lOCO LBS. GAS, DRY(2) 

GRAINS/DSCF(4) 

LBS. /HOUR 

TEST DATE: 6/7/95 

19.5 

8.30 

0.32-

296 

14.64 

15.80 

3.10 

o·.oo 

81.10 

0. 0711 

29.14 

2916 

24188 

16204 

13831 

0.0010 

0.0011 

0.0006 

0.07 

1. 'ACTOAL' K&ABS AT TR& COaDITIOBS FOOBD AT TB& SAXPLI.G ~OCATIOB. 

2. "DRY' IRCLDD&S ORLY TR& RATDRAL XOISTOR& TRAT WODLD R& &XITT&D PROX TR& PROCESS. MOliTOR& ADD&D OR SDRTRACT&D BY TR& COLLECTOR IS ROT IRCLOD&D. l. "W&T• IRCLOD&S TB& XOISTDRB AS X&ASOR&D AT TR& SAXPLIRG ~OCATIDR. 4. "DSCP' IS DRD&R TOTALLY DRY CORDITIORS, ALL XOiaTO&& &&M09&D. 
Network Environmental, Inc. 

SUMMARY OF PARTICULATE EMISSIONS 

COMPANY NAME: MICHIGAN D:rv:ISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: t2 KILN EXHAUST 

SAMPLJ:NG STAFF: CARGILL/ENGELHARDT 

SAMPLE NUMBER 

STANDARD ANALYSIS 

E 1 . TOTAL 'HEIGHT COLLECTED, grams 

E2. LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL(l) 

EJ. LBS. PARTICULATE/lOCO LBS. GAS, DRY(2) 

E6. GRAINS/DSCF(4) 

E7. LBS./HOUR 

TEST DATE: 6/7/95 

1 

0.0019 

0.0009 

0.0010 

0.0005 

0.06 

2 

0.0021 

0.0010 

0. 0011 

0.0006 

0.07 

1. 'AC~D•L' ••••• ·~ ~·· CO.DIT%0.1 FOD•D AT T•a I·K~LX•G LOCATIO., 2. 'Dar• I•CLDD&I o•LT Ta& aATDRAL KOIITORK TaAT •oOLD a& KK%TTKD r&OK Ta& 

~aOCSII, KOIITORK ADDED oa IO~TRACTKD aT Taa COLLECTOR II aOT IaCLOD&D, 

~. 'WKT• IaCLDDKI Taa KOIITO&a AI KKAIORKD AT Taa IAK~LlaG LOCATIOa. 

4. 'DICF' II OaDza TOTALLY DRT COaDITIOal, ALL KOIITORK RKKOV&D, 
Network Environmental, xnc. 

SUMMARY OF EXHAUST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: #2 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

SAMPLE NUMBER 

Gl. STACK RADIUS, inches 

G2. AREA OF STACK, sq. ft. 

G3 • BAROMETRIC PRESSURE, in. HG. 

G4. STATIC PRESSURE IN STACK, in. H20 

G5. STACK GAS TEMPERATURE, deg. F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: % OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

GlO. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

Gll. DRY, @ STP, lbs./cu.ft. 

Gl2. WE~, @ STP, lbs./cu.ft. 

Gl3. WET, @ STACK CONDITIONS, lbs. /cu. ft. 

Gl4. MOLECULAR WEIGHT, DRY, @ STP, lbs. /mole 

Gl5. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

Gl6. 

Gl7. 

Gl8. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STANDARD CONDITIONS, DRY SCFM 

TEST DATE: 6/7/95 

l 

19.5 

8.30 

28.60 

0.32-

298 

0.660 

14.16 

o.oo 

15.30 

3.40 

0.00 

81.30 

0.0754 

0.0713 

0.0476 

29.16 

2665 

23,932 

15,962 

13,719 

2 

19.5 

8.30 

28.60 

0.32-

293 

0.674 

15.11 

0.00 

16.30 

2.80 

o.oo 

80.90 

0.0752 

0.0709 

0.0476 

29.11 

2947 

24,445 

16,425 

13,943 

!3c 
Network Environmental, Inc. 

SUMMARY OF PARTICULATE TRAIN PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: #2 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

SAMPLE NUMBER 

Pl. NUMBER OF POINTS SAMPLED 

P2. DURATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, sq. ft. 

PS. PITOT CALIBRATION FACTOR 

P6 • METER CALIBRATION FACTOR 

P7. AVERAGE FILTER TEMPERATURE, deq. F 

P8. AVERAGE METER TEMPERATURE, deq. F 

P9. AVERAGE METER PRESSURE, inches of water 

P10. METER VOLUME, ACTUAL READING, cu.ft. 

P11. METER VOLUME, @ STP, cu.ft. 

P12. LIQUID VOLUME OF WATER CONDENSED, mls. 

P13. VAPOR VOLUME OF WATER CONDENSED, @ STP, 

P14. TOTAL GAS SAMPLED, @ STP, cu. ft. 

P15. WEIGHT OF GAS SAMPLED, DRY, lbs. 

P16. WEIGHT OF GAS SAMPLED, WET, lbs. 

P17. PERCENT ISOKINETICS 

CONCENTRATION CONVERSION FACTORS: 

P18. 

P19. 

P20. 

50 % EXCESS AIR, AFTER COLLECTOR 

50 % EXCESS AIR, BEFORE COLLECTOR 

MOISTURE CONDITIONS BEFORE COLLECTOR 

TEST DATE: 6/7/95 

1 2 

12 12 

60.00 60.00 

0.313 0.313 

0.00053 0.00053 

0.870 0.870 

1.000 1.000 

256 256 

93.2 92.7 

3.233 3.164 

58.81 58.19 

54.31 53.78 

189.0 202 .o 

cu.ft. 8.96 9.57 

63.26 63.35 

4.09 4.05 

4.51 4.49 

102.8 100.1 

1.10 l.ll 

/ j. 

- I 
,._-_ ... 

. -

Network Environmental, Inc. 

P.o. Box 2021 

Grand Rapids, HI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVISION, U.S. BRICK 

CORUNNA, MICHIGAN 

t2 KILN EXHAUST (FLUORIDE) 

DA'l'E: 6/7/95 
Network Environmental, Inc. 

StJHMARY OF EXHAUST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: f2 KILN EXHAUST (FLUORIDE) 

SAMPLING STAFF: BYRD/ENGELHARDT 

SAMPLE NUMBER 

G1. STACK RADIUS, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETRIC PRESSURE, in. HG. 

G4. STATIC PRESSURE IN STACK, in. H20 

G5. STACK GAS TEMPERATURE, deg. F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7 • PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: % OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

GlO. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

G11. DRY, @ STP, 1bs./cu.ft. 

Gl2. WET, @ STP, lbs./cu.ft. 

Gl3. WET, @ STACK CONDITIONS, lbs./cu.ft. 

Gl4. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

G17. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STANDARD CONDITIONS, DRY SCFM 

TEST DATE: 6/7/95 

1 

19.5 

8.30 

28.60 

0.32-

299 

0.675 

14.71 

0.00 

15.30 

3.40 

o.oo 

81.30 

0.0754 

0.0711 

0.0474 

29.16 

2953 

24,499 

16,337 

13,934 

2 

19.5 

8.30 

28.60 

0.32-

299 

0.666 

14.65 

o.oo 

16.30 

2.80 

0.00 

80.90 

0.0752 

0.0710 

0.0474 

29.11 

2917 

24,200 

16,148 

13,783 

J 3_3 
Network Environmental, Inc. 

SUMMARY OF PARTICULATE TRAIN PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: t2 KILN EXHAUST (FLUORIDE) 

SAMPLING STAFF: BYRD/ENGELHARDT 

SAMPLE NUMBER 

Pl. NUMBER OF POINTS SAMPLED 

P2. DURATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, sq. ft. 

PS. PITOT CALIBRATION FACTOR 

P6. METER CALIBRATION FACTOR 

P7. AVERAGE FILTER TEMPERATURE, deg. F 

P8. AVERAGE METER TEMPERATURE, deg. F 

P9. AVERAGE METER PRESSURE, inches" of water 

PlO. METER VOLUME, ACTUAL READING, cu.ft. 

Pll. METER VOLUME, @ STP, cu.ft. 

Pl2. LIQUID VOLUME OF WATER CONDENSED, mls. 

Pl3. VAPOR VOLUME OF WATER CONDENSED, @ STP, cu.ft. 

Pl4. TOTAL GAS SAMPLED, @ STP, cu.ft. 

PlS. WEIGHT OF GAS SAMPLED, DRY, lbs. 

Pl6. WEIGHT OF GAS SAMPLED, WET, lbs. 

Pl7. PERCENT ISOKINETICS 

CONCENTRATION CONVERSION FACTORS: 

Pl8. SO % EXCESS AIR, AFTER COLLECTOR 

Pl9. SO % EXCESS AIR, BEFORE COLLECTOR 

P20. MOISTURE CONDITIONS BEFORE COLLECTOR 

TEST DATE: 6/7/9S 

1 2 

12 12 

60.00 60.00 

0.313 0.313 

O.OOOS3 O.OOOS3 

0.870 0.870 

1.000 1.000 

0 0 

92.S 97.1 

3.073 3.029 

SS.90 S7.26 

Sl.66 S2.48 

188.0 190.0 

8.91 9.01 

60.S8 61.49 

3.89 3.9S 

4.31 4.37 

96.2 98.8 

0.00 o.oo 
Network Environmental, rnc. 

P.O. Box 2021 

Grand Rapids, Mr 49501 

SOURCE EMISSION TESTING 

at 

MrCBrGAN DrvrsroN, U.S. BRICK 

CORUNNA, MrCBrGAN 

f2 KrLN rNLET (FLUORIDE) 

DATE: 6/7/95 
Network Environmental, Inc. 

SUMMARY OF EXHAUST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: #2 KILN INLET (FLUORIDE) 

SAMPLING STAFF: CARGILL/SCHULTES 

SAMPLE NUMBER 

G1. STACK RADIUS, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETRIC PRESSURE, in. HG. 

G4. STATIC PRESSURE IN STACK, in. H20 

G5. STACK GAS TEMPERATURE, deg. F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: 'i OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

G11. DRY, @ STP, 1bs./cu.ft. 

G12. WET, @ STP, lbs./cu.ft. 

G13. WET, @ STACK CONDITIONS, lbs./cu.ft. 

G14. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

G17. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STANDARD CONDITIONS, DRY SCFM 

TEST DATE: 6/7/95 

1 

21.0 

9.62 

28.60 

2.00-

633 

0.570 

9.74 

0.00 

17.00 

2.40 

o.oo 

80.60 

0.0751 

0.0724 

0.0334 

29.07 

2975 

28,626 

13,204 

11,918 

2 

21.0 

9.62 

28.60 

2.00-

614 

0.572 

8.50 

0.00 

16.60 

2.50 

0.00 

eo .90 

0.0751 

0.0727 

0.0341 

29.07 

2954 

28,423 

13,336 

12,203 
Network Environmental, Inc. 

SUMMARY OF PARTICULATE TRAIN PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: #2 KILN INLET (FLUORIDE) 

SAMPLING STAFF: CARGILL/SCHULTES 

SAMPLE NUMBER 

Pl. NUMBER OF POINTS SAMPLED 

P2. DURATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, sq. ft. 

P5. PI TOT CALIBRATION FACTOR 

P6. METER CALIBRATION FACTOR 

P7. AVERAGE FILTER TEMPERATURE, deg. 

P8. AVERAGE METER TEMPERATURE, deg. F 

P9. AVERAGE METER PRESSURE, inches of 

F 

water 

P10. METER VOLUME, ACTUAL READING, cu.ft. 

P11. METER VOLUME, @ STP, cu.ft. 

P12. LIQUID VOLUME OF WATER CONDENSED, mls. 

P13. VAPOR VOLUME OF WATER CONDENSED, @ STP, cu.ft. 

P14. TOTAL GAS SAMPLED, @ STP, cu.ft. 

P15. WEIGHT OF GAS SAMPLED, DRY, lbs. 

P16. WEIGHT OF GAS SAMPLED, WET, lbs. 

P17. PERCENT ISOKINETICS 

CONCENTRATION CONVERSION FACTORS: 

P18. 50 % EXCESS AIR, AFTER COLLECTOR 

PH. 50 % EXCESS AIR, BEFORE COLLECTOR 

P20. MOISTURE CONDITIONS BEFORE COLLECTOR 

TEST DATE: 6/7/95 

1 2 

12 12 

60.00 60.00 

0.250 0.313 

0.00034 0.00053 

0.870 0.870 

1.037 1.037 

0 0 

97.8 98.5 

0.727 1.828 

26.99 43.19 

25.47 40.82 

58.0 80.0 

2.75 3.79 

28.22 44.61 

1.91 3.07 

2.04 3.24 

100.5 100.7 

o.oo o.oo 
APPENDIXB 

ANALY"ZER OUTPUT#< CALIBRATION DATA 

/_ 3P 
Network Environmental, Inc. 

P.O. BOX 2021 

Grand Rapids, HI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVISION, U.s. BRICK 

CORUNNA, MICHIGAN 

DRYER 

DATE: 6/8/95 
Network Environmental, Inc. 

SUMMARY OF EXHAUST GAS PARAMETERS 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: DRYER 

SAMPLING STAFF: SCHULTES/SMITH 

SAMPLE NUMBER 

G1. STACK DIMENSIONS, inches 

G2. AREA OF STACK, sq. ft. 

G3. BAROMETRIC PRESSURE, in. HG. 

G4. STATIC PRESSURE IN STACK, in. H20 

G5. STACK GAS TEMPERATURE, deg. F 

G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

G8. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION: % OXYGEN 

% CARBON DIOXIDE 

% CARBON MONOXIDE 

% NITROGEN 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

DENSITY AND MOLECULAR WEIGHT OF STACK GAS: 

G11. DRY, @ STP, lbs./cu.ft. 

G12. WET, @ STP, 1bs./cu.ft. 

G13. WET, @ STACK CONDITIONS, 1bs./cu.ft. 

G14. MOLECULAR WEIGHT, DRY, @ STP, lbs ./mole 

G15. AVERAGE GAS VELOCITY, feet/min. 

STACK GAS FLOW RATE: 

G16. 

G17. 

G18. 

STACK CONDITIONS, ACFM 

STANDARD CONDITIONS, SCFM 

STAND~ CONDITIONS, DRY SCFM 

TEST DATE: 6/8/95 

1 

57.0 

16.63 

29.00 

0.12-

145 

0.766 

2.23 

0.00 

17.70 

1.60 

o.oo 

80.70 

0.0749 

0.0743 

0.0630 

28.97 

2909 

48,355 

41,045 

40,131 

X 42.0 
Fii:.ENAM"': USBT567.DTA CC~2~~Y: US Brick I Corunna 

SOURCE: kilm #2 

----------------------------· 

CE.'I.NNEL: 

P A..CL'I.l1E TE R : 

UNITS: 

SLOPE: 

INTERCEPT: 

00 

S02 

PPM 

1000 

0 

----------------------------· 

06-07-1995 14:59:10 .,., 565 

06-07-1995 15:00:33 546 

06-07-1995 15:01:33 535 

06-07-1995 15:02:33 558 

06-07-1995 15:03:33 ~ 

06-07-1995 15:04:33 -1,\._l( 454 

06-07-1995 15:05:33 525 

06-07-1995 15:06:33 536 

06-07-1995 15:07:33 533 

06-07-1995 15:08:33 542 

06-07-1995 15:09:33 ~ 06-07-1995 15:10:33 -515 

06-07-1995 15:11:33 456 

06-07-1995 15:12:33 464 

06-07-1995 15:13:33 465 

06-07-1995 15:14:33 o->tiJ-'481 

06-07-1995 15:15:33 484 

06-07-1995 15:16:33 484 

06-07-1995 15:17:33 498 

06-07-1995 15:18:33 492 

06-07-1995 15:19:33 477 

06-07-1995 15:20:33 . 419 

06-07-1995 15:21:33 536 

06-07-1995 15:22:33 584 

06-07-1995 15:23:33 "'-"597 

06-07-1995 15:24:33 -Y- 596 

06-07-1995 15:25:33 615 

06-07-1995 15:26:33 616 

06-07-1995· 15:27:33 '¥2..)( 4'30 

06-07-1995• 15:28:33-5" 190 

06-07-1995 15:29:33 ~JS'y-.182 06-07-1995 15:30:33 183 

06-07-1995 15:31:33 449 

06-07-1995 15:32:33 ~24 06-07-1995 15:33:33 595 

06-07-1995 15:34:33 I 646 

06-07-1995 15:35:34 0 ,;+k-r 661 

06-07-1995 15:36:33 682 

06-07-1995 15:37:33 694 

06-07-1995 15:38:33 704 

06-07-1995 15:39:33 681 

06-07-1995 15:40:33 497 

06-07-1995 15:41:33 768 

06-07-1995 15:42:33 845 

06-07-1995 15:43:33 872 

0 6-0 7-19 9 5 15 : 4 4 : 3 3 ~' \2\8 9 4 

06-07-1995 15:45:33 955 

06-07-1995 15:46:33 . 932 

DATA LISTING 
06-07-1995 15:47:33 931 

06-07-1995 15:48:33 925 

06-07-1995 15:49:33 838 

06-07-1995 15:50:33 691 

06-07-1995 15:51:33 561 

06-07-1995 15:52:33 518 

06-07-1995 15:53:33 469 

06-07-1995 15:54:33 457 

06-07-1995 15:55:33 jj_,-'14 4 0 

06-07-1995 15:56:33 0" 421 

06-07-1995 15:57:33 414 

06-07-1995 15:58:33 397 

06-07-1995 15:59:33 407 

06-07-1995 16:00:51 456 

06-07-1995 16:01:51 'sz6 06-07-1995 16:02:51 ·~54 

06-07-1995 16:03:51 ~\ 545 

06-07-1995 16:04:51 ~423 

06-07-1995 16:31:28-ltl- 409 

06-07-1995 16:32:28 419 

06-07-1995 16:33:28 413 

06-07-1995 16:34:28 413 

06-07-1995 16:35:28 od<'Jr 410 

06-07-1995 16:36:28 413 

06-07-1995 16:37:28 402 

06-07-1995 16:38:28 412 

06-07-1995 16:39:28 407 

06-07-1995 16:40:28 4 l 2 

06-07-1995 16:41:28 328 

06-07-1995 16:42:28 500 

06-07-1995 16:43:28 527 

06-07-1995 16:44:28 533 

06-07-1995 16:45:28 .lc 5 24 

06-07-1995 16:46:28 -fo\o:; 52 9 

06-07-1995 16:47:28 531 

06-07-1995 16:48:28 542 

06-07-1995 16:49:28 538 

06-07-1995 16:50:28 524 

06-07-1995 16:51:28 460 

06-07-1995 16:52:28 420 

06-07-1995 16:53:28 427 

06-07-1995 16:54:28 428 

06-07-1995 1 6 : 55 : 2 8 ~,._,., 4 3 3 

06-07-1995 16:56:28 cY 433 

06-07-1995 16:57:28 427 

06-07-1995 16:58:28 435 

06-07-1995 16:59:28 430 

06-07-1995 17:00:28 440 

06-07-1995 17:01:28 384 

06-07-1995 17:02:28 557 

06-07-1995 17:03:28 601 

06-07-1995 17:04:28 598 

06-07-1995 17:05:28 ' 591 

06-07-1995 17:06:28 -.:;r. \.:f 5 8 3 

06-07-1995 17:07:28 571 

06-07-1995 17:08:28 565 

06-07-1995 17:09:28 560 

06-07-1995 17:10:28 548 

;t/z_, 06-07-1995 li:ll:28 486 

06-07-1995 ~7:12:28 451 
06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

06-07-1995 

17:13:28 -458 

17:14:28 466 

17:15:28 ~458 

17:16:28 ~ 458 

17:17:28 

17:18:28 

17:19:28 

17:20:28 

17:21:28 

17:22:28 

17:23:28 

17:24:28 

17:25:28 

17:26:28 

17:27:28 

17:28:28 

17:29:28 

17:30:28 

460 

458 

397" 

167 

206 

449 

552 

564 

581 

568 y.\<-~ 568 

557 

546 

546 

/ 
FI~E~~~: USB568T.DTA 

COM?~~Y: US Brick Michigan 

SOURCE: kilm 

-----------------------------· 

CHANNEL: 

P-~~~TER: 

u~ITS: 

SLOPE: 

INTERCEPT: 

00 

502 

PPM 

100G 

0 

-----------------------------· 

06-08-1995 12:43:32 

06-08-1995 12:44:32 

06-08-1995 12:45:32 

06-08-1995 12:46:32 

06-08-1995 12:47:32 

06-08-1995 12:48:32 

06-08-1995 12:49:32 

06-08-1995 12:50:32 

06-08-1995 12:51:32 

06-08-1995 12:52:32 

06-08-1995 12:53:32 

06-08-1995 12:54:32 

06-08-1995 12:55:32 

06-08-1995 12:56:32 

06-08-1995 12:57:32 

06-08-1995 12:58:32 

06-08-1995 12:59:32 

06-08-1995 13:00:32 

06-08-1995 13:01:32 

06-08-1995 13:02:32 

06-08-1995 13:03:32 

06-08-1995 13:04:32 

06-08-1995 13:05:32 

06-08-1995 13:06:32 

06-08-1995 13:07:32 

06-08-1995 13:08:32 

06-08-1995 13:09:32 

06-08-1995 13:10:32 

06-08-1995 13:11:32 

06-03-1995 13:12:32 

06-08-1995 13:13:32 

06-08-1995 13:14:32 

06-08-1995 13:15:32 

06-08-1995 13:16:32 

06-08-1995 13:17:32 

06-08-1995 13:18:33 

06-08-1995 13:19:32 

06-08-1995 13:20:32 

06-08-1995 13:21:32 

06-08-1995 13:22:32 

06-08-1995 13:23:32 

06-08-1995 13:24:32 

06-08-1995 13:25:32 

06-08-1995 13:26:32 

06-08-1995 13:27:32 

06-08-1995 13:28:32 

06-08-1995 13:29:32 

06-08-1995 13:30:32 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

·a 

0 

0 

0 

0 

0 

0 

0 

DATA LISTING 
06-08-1995 13:31:32 0 

06-08-1995 13:32:32 0 

06-08-1995 13:33:32 0 

06-08-1995 13:34:32 0 

06-08-1995 13:35:32 0 

06-08-1995 13:36:32 0 

06-08-1995 13:37:32 0 

06-08-1995 13:38:32 0 

06-08-1995 13:39:32 0 

06-08-1995 13:40:32 0 

06-08-1995 13:41:32 0 

06-08-1995 13:42:32 0 

06-08-1995 16:56:14 5 

06-08-1995 16:57:14 4 

06-08-1995 16:58:14 4 

06-08-1995 16:59:14 4 

06-08-1995 17:00:14 4 

06-08-1995 17:01:14 3 

06-08-1995 17:02:14 2 

06-08-1995 17:03:14 2 

06-08-1995 17:04:14 3 

06-08-1995 17:05:14 4 

06-08-1995 17:06:14 3 

06-08-1995 17:07:14 2 

06-08-1995 17:08:14 3 

06-08-1995 17:09:14 3 

06-08-1995 17:10:14 3 

06-08-1995 17:11:14 2 

06-08-1995 17:12:14 3 

06-08-1995 17:13:15 3 

06-08-1995 17:14:14 3 

06-08-1995 17:15:14 3 

06-08-1995 17:16:14 3 

06-08-1995 17:17:14 3 

06-08-1995 17:18:14 2 

06-08-1995 17:19:14 2 

06-08-1995 17:20:14 3 

06-08-1995 17:21:14 4 

06-08-1995 17:22:14 11 

06-08-1995 17:23:14 15 

06-08-1995 17:24:14 6 

06-08-1995 17:25:14 3 

06-08-1995 17:26:14 1 

06-08-1995 17:27:14 1 

06-08-1995 17:28:14 0 

06-08-1995 17:29:14 1 

06-08-1995 17:30:14 3 

06-08-1995 17:31:14 2 

06-08-1.995 17:32:14 2 

06-08-1995 17:33:14 2 

06-08-1995 17:34:14 2 

06-08-1995 17:35:14 3 

06-08-1995 17:36:14 4 

06-08-1995 17:37:14 3 

06-08-1995 17:38:14 3 

06-08-1995 17:39:14 4 

06-08-1995 17:40:14 3 

06-08-1995 17:41:14 2 -- 06-08-1995 17:42:14 - ;L/.:J-- 06-08-1995 17:43:14 -
06-08-1995 17:44:14 2 06-08-1995 17:45:14 3 06-08-1995 17:46:14 3 06-08-1995 17:47:14 3 06-08-1995 17:48:14 3 06-08-1995 17:49:14 2 06-08-1995 17:50:14 2 06-08-1995 17:51:14 2 06-08-1995 17:52:14 3 06-08-1995 17:53:14 2 06-08-1995 17:54:14 3 06-08-1995 17:55:14 3 
Division 

Ml 

esearch 

-M 

ration Response, PPM 

.. Analyzer 

System Injection Cal. Error, Drift, % of Span 

st Post 1 Post 2 Posl3 %of 

Span Gas 

3 16:18 18:57 Test 1 Test2 Tesl3 

0 0 0.00 0.00 

.. -0.30 

-0.30 

0 826 829 -0.40 -0.10 

-------

od, This Value Must Be The Same As The Relevant Direct Injection Value 

 high calibration gas, whichever one is closer to actual stack concentration 

Pretest 

0.00 

-1.30 

n= (dir. inj. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% 

System Bias, %of Span 

Post1 Post2 

0.00 0.00 

_, 

. 

-3.10 -2.80 

osttest sys. inj. cal. response, PPM- sys. inj. pretest cal. response, PPM) x 100% I (span value, PPM): Limit= 3% 

evant sys. inj. cal. response, PPM- dir. inj. cal. response, PPM) x 100% I (span value, PPM): Limit= 5% 

"' ~ 

" 

! 

Post 3 
Division 

Ml 

om & 

esearch 

-M 

ration Response, PPM 

.. Analyzer 

System Injection Cal. Error, Drift, % of Span 

st Posl1 Post 2 Post 3 %of 

6 11:30 16:40 16:15 

Spun Gas 

Test 1 Test 2 Test 3 

0 0 0 0.00 0.00 0.00 

-0.10 

-0.60 

7 637 659 650 0.00 2.20 0.90 

d, This Value Must Be The Same As The Relevant Direct Injection Value 

high calibration gas, whichever one is closer to actual stack concentration 

Pretest 

0.00 

-2.00 

n= (dir. inj. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% 

System Bias, % of Span 

Post 1 Post2 

0.00 0.00 

-2.00 0.20 

osltest sys. inj. cal. response, PPM- sys. inj. pretest cal. response, PPM) x 100% I (span value, PPM): Limit= 3% 

evant sys. inj. cal. response, PPM- dir. lnj. cal. response, PPM) x 100% I (span value, PPM): Limit= 5% 

0., 

> 

" 

Posl3 

0.00 

-0.70 
APPENDIXC 

ANALY:lER SPECIFICATIONS . & GAS CERTIFICATIONS . 

;</7 
• 

BA-MA.'< 2/9 .87-l-l. 

l.O Field of !::application 

Gas Sample Conditioners are used in gas analysis systems and installations 

co cool moisture-containing sample gas sufficiently so that nowhere 

in the subsequent analysis systems or installations does it fallw 

below its dew point. 

In certain measurement casks it is necessary, to hold the dew point 

of the sample gas constant in order Co eliminate the effect of 

water vapor on the measurement result. For applications of this 

type the proportion of water vapor, held constant by the electrical 

sample gas conditioner MAK 2, is taken into account on calibration. 

The Gas Sample Conditioner MAK 2 may not be used in hazardous areas. 

The explosion-proof Gas Sample Conditioner Model MAK 3-Ex is available 

' for chis. 

/.fZ 
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2.0 Technical Data 

Number of individual gas paths 

Maximum sample gas flow rat~ 

of each gas path 

Operating pressure 

Sample gas inlet temperature 

Sample gas inlet dew point 

Sample gas outlet temperature 

MAK 2-1 

- MAK 2 

- accu~acy· 

Sample gas temperature indicator 

- indicator tolerance 

Running-in time 

Dead space per gas path 

Pressure drop per gas path 

Powe~ SUP.ply (mains) 

Alternative voltage 

Power consumption 

BA-~~ 219.87-1-2 

~~ 2-1, Type 29 - 1 -

MAK 2 Type 30 - 2 -

250 llh at 1 bar and 20 Degr C 

0,15 SCFM at 14 psi and 68 Degr F 

0,5 

7 

2,5 bar 

35 psi 

140 Degr C I 2S4 Degr F 

65 Degr C I 149 Degr F 

+ 3 Degr C I 37,0 Degr F 

outlet temperature gas path 

No. 1 is 0,5 Degr C I 0,9 Degr F 

higher than gas path No. 2. 

+1- 0,3 Degr. C I +1- 0,54 Degr F 

Digital display indicator for 

cooling brine te::Iperature with 

limiting value signal 

+I- 0,5 Degr c at 0 ... 10 Degr c 

+1- 0,9 Degr F at 32 50 Degr F 

approx. 55 min. 

approx. 8,36 cubic-inch 

approx. 25 mbar at 250 llh 

approx. 0,36 psi at 0,15 SCFM 

115 v + 10% - lO'i:. (60 +l-2) 

Code 01 

220 v + 10% - 15% (50 +l-2) 

Code 03 

Hz 

Hz 

220 v + 15% ... - 5% (60 +l-2) Hz 

Code 04 

approx. 450 VA, 3,9 A at 115 v 60 Hz 

approx. 440 VA, 2,0 A at 220 v 50 Hz 

approx. 480 VA, 2,1 A at 220 v 60 Hz 

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2.1 Note on standa~ds and s~ecifications 

The i~dusc~ial scandards and regulations (DI~, VDE, VDI etc.) ~efe~red 

to in this Operating Manual lre applicable in the Federal Republic 

of Ger~any. wnen using this device outside Ge~an Federal jurisdiction, 

the relevant specifications, standards and regulations applicable in 

' the country where ehe device is used must be observed. 

3.0 Mode of oneration and const~uction 

With the description of the mode of operation and construction of the 

elec:ric Gas Sample Conditioner ~JL' 2, see also the sche~atic diagram 

No. 3 898 0042. 

3.1 Desc~iotion 

In the electric Gas Sample Conditioner M&' 2 the sample gas is cooled 

to +2 Degr C in a heat exchanger. The condensate precipitated from 

the sample gas is deposited in the precipitation vessel (precipitator). 

The cooling medium used is refrigerant R 12. A compressor compresses 

the gaseous ref~igerant to approx. 101,5 psi, depending en the operating 

conditions. 

The compressor consists of a pressure case containing a piston cocpressor 

drive~ by an electric motor. Downstreac of this is the condenser, a 

ribbed pipe heat exchanger, where the refrigerant is liquefied. The 

heat is dissipated by mea~s of a fan which is •~itched off at low ambient 

te=perature by a switch controlled by the refrigerant pressure - the 

fan pressure s~itch. The pressure of che re:=ig~=~~t is then reduced 

by a capilla=y tube froc approx. 101,5 - 29 psi. The refrig~rant, with 

its pressu=e reduced in this ~ay, is then injecced inca a heat exchanger 

coil (evaporator) where it absorbs energy from the sample gas directly 

via the cooling brine and evaporates again. The cocpressor takes in 

che evaporated refrig~rant once more. 

The evaporator is located, together with the hea: exchanger through 

which s~ple gas flows, in a container filled With cooling brine, the 

so-called hea: exchanger unit. The actual heac exchanger comprises 

a spirally wound pipe with connected precipitator and condensate drain 

pipe. 

The sample gas is cooled by heat transfer to the cooling brine and from 

this to the ref::-ige:-ant. Alle three systems "sample gas", "cooling 

brine" and "re£rige:-ant" are her.necically separated f:-om one another .. 

The sample gas outlet te~perature is controlled by a hot gas bypass 

cont~ol valve. Depending en the refrigerant pressure in the evaporator 

outlet, this pressure regulator takes a greater or lesser amount of 

refrigeranc f~oc the condenser and passes it eo the cocpressor via 

a bypass. As the pressure and temperature of the refrigerant are directly 

proportional, if the evaporator pressure is set a 31,9 psi the hoC 

gas bypass control valve ensures that the sample gas maintains a constant 

te~pe=acure in the area of interest. 

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BA-Mfl~ 2/9.87-1-6 

A mic~oprocessor controlled monitoring device with digital display 

is used to monitor the s~~ple gas outlet teQperature (= cooling brine 

teQperature). This temperature i~ dete~ined with a sensor immersed 

in the cooling brine. If the limit value set by the manufacturer (generally 

46 Degr F) is exceeded, visual indication is provided by the digital 

display flashing. A floating contact is available for external fault 

indication (status signal). This is connected with the .connecting cable 

provided. A fault may be present for instance if after the power is 

svitched on and the lead time has expired, the cooling .brine temperature 

is not lover than its set limit value (see also section 5.2). 

The electric Gas Sample Conditioner ~~~ 2 is supplied vith one sample 

gas circuit or with tvo sa~ple gas circuits. Upgrading from one to 

cwo sample gas circuits isc not possible4 

The precipitated condensate is collected in a separate external condensate 

vessel or puffiped out by the automatic condensate drain unit (see also 

section 4.2.2). 

4.0 Installation and connectin~ inst~uctions 

4.1 Selecting the installation site and mounting the unit 

When selecting the installation site, note that the electric Gas 

Sample Conditioner MJL~ 2 may only be installed in areas where the_temperatures 

are within the pe~itted ambient temperature range (see section 2.1). 

The Gas Sample Conditioner~~ 2 should be mounted on a wall or in 

an analysis cabinet as near as possible to the gas sampling point. 

The fastening rails supplied with the unit are used for this; they 

are screwed to the rear wall of the unit (see dimensionsl _drawing 

No. 4 8Jj 1281). This drawing also shows the hole spacing and diameter 

for the fastening screws. 

The caximum pe~itted inclination of the Gas Sample Conditioner is 

5 Deg::-ees':. 

The gas sample conditioner must be protected against direct heat radiation 

(from the sun, fu=naces, boile=s etc.) and against rain and excessive 

contamination. It must have sufficient ground clearance to allow space 

to discharge a~d empty the condensate. 

The saQple gas lines leading away from the Gas Sample Conditioner may be 

at any gradient provided that the Conditioner represents the coldest point 

in the entire measuring system, i.e. the temperature does not fall 

below the dew point in modules and lines in the gas analysis system 

do~~stream of the Conditioner. 

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Operating Manual Introduction 

1 Principle of Operation 

1.1 The Basis, 1 

The microprocessor-based Models 72li\1 and 72li\1D photometric analyzers measure, 

at two discrete wavelengths, the absorbances of ultraviolet radiation (light) by a gas 

sample. The concentrations of the components absorbing the light (absorbers) are 

then determined from relationships developed through application of the ideal gas 

la':' in concert with the laws of Bouguer, Beer and Lambert. 

Thus, the absorbance, A, due to a single absorber is, 

A = [x]k,_ZP 

RT ' 

where l is the path length of the light in the gas sample, [x] is the concentration 

(mole percent1

) of absorber x, k). is the molar absorptivity of absorber x at the 

measuring wavelength, A, T and P are the temperature and pressure of the gas 

sample, respectively, and R is the universal gas constant. For any given system at 

constant temperature and pressure, the equation can be simplified to: 

A= Ck,_[x], 

where C = ZP I RT is a constant depending only upon the system of units employed. 

If only one absorber is present, the concentration is easily determined from the 

absorbance measurement at the single wavelength. 

If more than one absorber is present, the total absorbance, A.., is the sum of the 

absorbances by the individual absorbers, 

where % is the absorbance at wavelength A due to the iu. absorber and N is the 

number of absorbers. Combining with the previous equation yields: 

N 

A).= CLka.[x],. 

i .. l 

In this case with more than one absorber, the measurement of absorbance at just one 

wavelength is not sufficient to determine the concentrations: there is only one 

1 For an ideal gas, mole pe:cent is equal to volume percent. At the nor.nal operating conditions of 

Ute analyzer, be real gas 1:1i.xture de,iates from ideal behaviour by less than OS percent 

903.4502 Rev. 2 1 
0!)€rating Manual Introduction 

single rack-mount enclosure. For the Model72l)!:l'Y,' a..."l additional cabinet is required 

to acco=odate the opacal bench with a long-p~th measuring cell. 

Two wavelengths are used-- one which is absorbed by SOz is used for the measuring 

waveleng-th (285 nm) and one which is not absorbed by 802 or other components 

normally in the gas sample stream is used as a reference wavelength (585 nm). The 

sample flows through the measuring cell while the reference cell contains only nonabsorbing gases. As the chopper wheel rotates, a flash of radiation passes through 

the measuring filter to the beam splitter. M..er a brief period, a flash of radiation 

passes through the reference filter to the beam splitter. These flashes of measuring 

and reference radiation contim:.e at a nominal frequency of 52 times per second per 

filter. The beam splitter directs half the radiation through the measuring cell and 

half through the reference cell to the two detectors which develop electrical signals 

proportional to the amount of radiation that impinged on the detectors. The detector 

signals are demultiplexed into two measuring signals and two reference signals. The 

reference signals are used to automatically control the gain of each detector to 

independently compensate each path for optical contamination. The detector signal 

developed from the measuring wavelength radiation that paSS!=S through the reference cell is used to control the current to the ultraviolet source. The two detector 

signals developed from the reference wavelength radiation that pass through the 

measuring and reference cell are used to produce an analyzer output signal that is 

proportional to the 802 concentration in the measuring cell. 

2 Features 

• 1\<licroprocessor-based 

The operation of the analyzer, calculations, data manipulations and user 

interface are all controlled by two on-board microprocessors. 

• Two Cell Lengths 

Two cell lengths are available. For the higher concentration range (0 to 5000 

p:p!Il 802), the .Model 721M typically uses a (standard) 35.0 em cell mounted 

wit...1Un the same enclosure as the electronics. For the lower concentration 

range (0 to 1500 ppm 802) the Model 72LMD uses a (standard) 100.0 = cell 

which is mounted in a separate cabinet. 

• Auto Calibration 

Automatically adjusts the calibration of the analyzer using calibration gas 

mi1:tures. The Auto-Calibration function may be initiated on co=and by the 

user, at user-speci£ed time intervals or, by a remote, dry (potential free) 

contact closure. 

903.4502 F.ev. 2 3 1994-01-07 ~·_.... 

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Operating Manual Introduction 

equation but N unknown concentrations. The solution to this problem is to make 

absorbance measurements at additional wavelengths to develop a system of linear 

equations: 

N 

A~.1 = C L k,._1 [x]; , i•l 

N 

AIC! = C:[k.l.2[x],, 

i•l 

N 

A~.m = C L kD.m[x], , i•l 

where m is the number of discrete wavelengths at which the absorbance measurements are made. Provided only that m is equal to or greater than N, this system of 

equations can be solved using standard methods of linear algebra. 

In lieu of determining the concentrations of additional absorbers, measurements at 

additional wavelengths at which it is known that all components in the gas sample 

do not absorb may be used to compensate for contamination of the optical path and 

ageing of the radiation source. 

1.2 The Implementation 

The Models 721M and 72lMD Analyzers are comprised of a single ultraviolet line 

source, a chopper wheel containing two interference filters, a beam splitter, one 

measuring cell, one reference cell and two matched photodetectors, as is indicated in 

:::r----- ________ ::~~:~:_~~~-------

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Measuring Cell 

! Splitter 

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-· i 

~-I Detector 1 

M2 ~---f>---: 

-~-I R2 ~--{>--1 I 

1

-1 M1 

Detector 1 

-~-I A1 

Gain 

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~--{>---~---- 1 Measunng 

~ __ {> __ 1 : Signal 

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-~2*-,' F=CJ r.- I S:~n:!''l! t;:o!'tr.oL ___________________ 1 

Source 

Filters 

the block diagram. For the Model 72li"\1, all components are contained within a 

903.4502 Rev. 2 2 
'. 

72 L"\1/i2l:M:D Operating Manual Introduction 

• Calibration Gas Solenoid Valve Control 

Up to four solenoid valves can be controlled by the analyzer. One of the 

outputs is reserved for the zero gas. The length of time that each solenoid 

valve is On is determined by a user-adjustable timer. There is one timer for 

each output. Each of the outputs for controlling the solenoids may be turned 

Off by the user if it will not be used. A timer may be started manually by the 

user or automatically during the Auto-Calibration sequence. 

• .Analog Output Channels 

There are four independent output signal channels. Each channel consists of 

a voltage output (which can be set to 0.1 V, 1 V or 10 V full-scale) and an· 

optional isolated 4 to 20 mA current output. Within a channel, either the 

voltage output or the current output, but not both, may be calibrated. The fullscale concentration for each output channel may be set by the user to any 

value within the operating range of the analyzer. 

• True Dual-Range Capability 

The assignment of the concentration signal to two different output channels 

which have different full-scale ranges provides simultaneous dual-range 

outputs. 

• Status Relays 

There are two independent sets of SPDT (Form C) dry (potential free) relay 

contacts. One set of contacts indicates when calibration of the analyzer is in 

progress. The second set is configured for fail-safe operation and indicates if 

the self-diagnostic system of the analyzer has detected a fault. 

• Dilution Air Correction (optional) 

Adjusts the S02 concentration measured by the analyzer to a reference excess 

air condition based on the concentration of oxygen (02) in the sample. The 0 2 

content of the sample maybe measured by an optional paramagnetic 0 2 sensor 

installecj. within the Model 721M analyzer enclosure or by a separate, 

independent 0 2 analyzer. 

• Mass Flow Calculation (optional) 

3 

Calculates the volumetric flow rate of the process stream and mass flow rate 

of so2 (or sulfur) in the process stream. ·Input signals representative of the 

process stream temperature and velocity are required for the calculation. 

Technical Data 

These performance characteristics are based on operation with factory-set filtering 

time constants, a 35.0 em path length for the Model 721M, a 100.0 em path length 

903.4502 Rev. 2 4 1994-01-07 

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Operating Manual Introduction 

for the Model 72EYID, and the gas sample in the cell at 25°C (77°F) and a pressure 

of 101.325 kPa (760 =of Hg, 14.696 psia). 

Measuring Range (ppm) 

721.!."1 

802 0 to 5000 

Noise Level (ppm SOz) 

721M 

Typical: 

Maximum: 

:!:0.25 

:!:0.5 

Constant-Temperature 

Zero Drift (ppm SO,Iday) 

72L.'ID 

0 to 1500 

72L1\1D 

:!:0.1 

:!:0.2 

72Li\l 72L1\1D 

:!:0.5 :!:0.2 

Ambient-Temperature 

Change Drift (ppm SO,ICelsius degree) 

721M 72L.'ID 

T:ypical: :!:0.25 :!:0.1 

Maximum: :!:0.5 :!:0.2 

Linearity 

:!:0.5 percent of any selected full-sr.ale 

range up to: 

72l.J.~ 

1000 ppm 

Sensith,ity (ppm) 

721M 

0.5 

Accuracy 

72l.J.~ 

300 ppm 

72L~ 

0.2 

T;rpically, better than :!:1 percent of 

full-scale. 

Analog Outputs 

Four (4) output channels, each with a 

voltage output and a current output. 

Either, but not both, may be calibrated. 

Voltage: 0 to 0.1 V, 0 to 1 V or 

0 to 10 V Uow impedance 

source, not isolated) 

Current: 4 to 20 m.A. (0 to 1000 n load, 

isolated) self-powered or looppowered Uoop power by user). 

9{)3.4502 Rev. 2 5 

Output Ranges 

Any full-scale within the measuring 

range of the analyzer. Set by user. 

Cell Construction 

Standard 316 stainless steel body with 

quartz windows. Other materials available to suit applications. 

Power Requirements 

50 W for analyzer only. 

120 VAC (105 to 132 VAC), 50/60 Hz 

220 V AC (200 to 264 V AC), 50/60 Hz 

Ambient Limits 

15 to 35°C (59 to 95°F) 

5 to 95 percent relative humidity, noncondensing. 

Dimensions 

721M Standard 19-inch rack-mount 

enclosure, 178 = (7 in) high and 597 

= (23.5 in) deep. 

72l.MD The above enclosure plus an 

optical bench cabinet: 197 = (7. 7 5 in) 

high by 264 = (10.375 in) wide by 

1238 = (48.75 in) long. 

Communication Ports 

One RS-232 port used for service. Of 

the two RS-422 ports, one is used for 

co=unications between the microprocessors and the other is reserved. 

Speed of Response 

Determined by digital filtering time 

constant and sample gas flow rate. 

Time constant can be changed by user. 

1994-0l-D7 

;_f6 
I. INTRODUCTION 

Thermo Environmental Instruments' Inc. Model 42H Chemiluminescence NO-N02-NO. 

Analvzer is a second generation analytical instrument capable of measuring oxides of 

nicrogen at levels from sub parts per million to 5000 parts per million. The Model 42H 

generates three continuous signals of NO, NOz (NO.-NO), and NO •. 

J. Compared to other types of source chemiluminescence analy;~rs, the Model 42H offers the 

following significant advantages: 

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• Increased sensitivity 

• Linearity through all r<1Ilges 

• Microprocessor control and operation 

• Simplicity of operation 

• Fa.St response ·time 

• Independent NO-N02-NO. ranges 

• Rep!ac,sable converter cartridge 

• Teflon diaphragm sample pump 

The microcomputer circuitry upon which the Model 42H is based eliminates many 

disadvantages inherent in analog systems and provides for increased stability, accuracy, and 

flexibility. Digital computations are insensitive to drift with time or temperature, therefore 

sources of instrument drift or error due to the eleccronics are minimized. 

Thermo Environmental Instruments is pleased to supply this Chemiluminescence NO-N02-

NO. analyzer. We are committed to the. manufacture of instruments exhibiting high 

standards of performance and worklnanship. However, we are prepared and eager to be of 

service if any problems are encountered in the use of this analyzer. 

) PR.L'.'CIPLE OF OPER~TION 

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The Model 42H Chemiluminescent Analyzer utilizes the reaction of nitric oxide (NO) with 

ozone as its basic principle. Specifically: 

NO+ 0 3 -------+ N02 + 0 2 + hv 

The sample is drawn into the Model 42H by an external pump. After it reaches the reaction 

chamber, it mixes with ozone which is generated by the internal ozonator. The chemical 

reaction above then tak~s place. This reaction produces a characteristic luminescence with 

an imensity proportional to the concentration of NO. Specifically, light emission results 

when electronically excited N02 molecules decay to lower energy states. The light emission 

is detected by a photomultiplier tube, which in turn generates a proportional electronic 

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I. Introduction 

signal. Tne ekcc-onic signal is processed by the microcomputer into a NO concentration 

reading. To measure the NO, (NO + NOz) concentration, N02 must be transfonned to NO 

prior to reaching the reaction chamber. Tnis transfonnation takes place in a stainless st~l 

converter heated to approximately 625 "C. Upon reaching the reaction chamber, the 

converted molecules along with the original NO molecules react with ozone. The resultina 

"' 

signal represents the NO, reading: 

A so!e:1oid is used to switch the Model 42H between .the NO, mode, where the sample 

passes through the stainless st~l converter, and the NO mode, where the sample bypasses 

the stainless st~l converter. The N02 conce:1tration is determined by subtracting the signal 

obtained in the NO mode from the signal obtained in the NO, mode. 

NO -NO= NO X 2 

:I:.'<STRlii\fE:".l' OVERVIEW 

The ins:rument overview (see Figure I) can be conveniently discussed by separating it into 

the following operational components. 

Photomultiplier Cooler 

Tne thermoelectric cooler houses the photomultiplier tube (PMT). The PMT is of the multialkali type in order to have the infrared se:Jsitivity required to detect N02 luminescence. 

Tne PMT is cooled to approximately -4 "C to reduce dark current and increase instrument 

sensitivity. Tne control circuitry and power source for the cooler is located on the power 

supply board. 

Reaction Chamber 

Tne reac:.ion chamber subassembly is an integrd pa....--r of the photomultiplier cooler assembly. 

It is a two piece 24 carat gold plated assembly which design allows for ease of cleaning and 

mainte:1ance. In this reaction chamber, the sample reacts with ozone producing excited NOz 

which decays giving off a photon of energy. The reaction chamber is heated and controlled 

to approximately 50 acto ensure the greatest instrument stability. A thermistor mounted on 

the reaction chamber is used as the temperature sensor and the heating mechanism is a 

resistor with AC current passing through it. Tne temperature control circuitry for the 

reaction chamber is located on the temperature control board. Also housed in the reaction 

chamber assembly are the sample capillary (5 mil) and the ozone capillary (10 mil). 

1"0, Con;-erter 

The NO, con\·errer consists of a stainless steel cartridge surrounded bv a band heater with 

a type K thermocouple inserted into a clamping rin-g. This cartridge is housed in an 

insulated converter box. The stainless steel convener cartridge is heated to approximately 

6:::5 ac in order to convert NOc to NO. The temperature control circuitry for the convener 

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II. SPECIFICATIONS 

Ranges 

Noise 

Detection Limit 

Zero Drift (24 Hour) 

Span Drift (24 Hour) 

Rise, Fall Times (0-90%) 

Linearity 

Sample Flow Rate . 

Bypass Flow Rate 

Vacuum 

Power Requirement 

Physical Dimensions 

Weight 

Outputs 

0-!0, 20, 50, 100, 200, 500, 

!000, 2000, 5000 PPM 

25 PPB 

50 PPB 

50 PPB 

+I· I% Full Scale 

2.5 seconds NO 

5.0 seconds NO, 

+I- 1% Full Scale 

25 cc/min. 

250 to 1100 cc/min. 

28.5" Hg 

500 Watts 

115+10Volts 

220 ± 20 Volts 

50160 Hz 

17"W X 8 3/4"H X: 23"D 

70 Lbs. (including external pump) 

NO, N~. NO, 

Selectable Voltage 

4-20 rnA, RS-232 

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The Thermo Environmental Inst=umer.ts Inc. Model 48 has been 

designated by the United States Environmental Protection Agency 

(E?A) as a Reference Method.for the measurement of ambient concentrations of carbon Monox~de pursuant ~o~ith the requirements 

defined in 40 CFR Part 53. 

DESIGNATION REFERENCE METHOD NU~3~ RFCA-0981-054 

EPA DESIGNATION DATE Sept. 23, 1981 

The Thermo Electron Hodel 48 co Analyzer meets the EPA 

designation method requirements ~o~hen opera ted ~o;i th the follo;.;ing 

pa!:ameters: 

R~'lGE: 

LINE VOLTAGE R~'lGE: 

TEY.PERATU"RE R~GE: 

TIME CONSTANT 

0 - 50 PPM 

105 - 125 VAC 

20 - 30 DEGREES CELSIUS 

30 SECONDS 

With or ~o~i~~out the following options: 

48-001 

48-002 

48-003 

Particulate Filter 

19" Rack Mountable Configuration 

Remote Activation of Zero and Span 

The analyzer must be operated and maintained according to 

the operation and service Manual to conform to the EPA designation require~ents. 
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The ad~antages of t~e Medel 43 are appreciable ~hen compared 

tc a.t:alog systerls whe=e eac:: co::-rec'ticn made to the .lnstrument 

c~~~u~ requires not c~ly t~e appro~=iate transducer, but also a 

c:::t;:er:sat.icn ci::-cuit w·hic:h may neeC. to ha~:e a particular nonli~ea= ci~cuit which may need to have a particular non-linear 

c~a=ac~eristic (as is the case for the effect of pressure and 

t~~pe=at~re cha~9es en inf=are~ absorpti?n m7asurements). Analog 

d~agncst~c func~.lons also requ~re more c.1rcu~try thereby increasing both complexity and cost while decreasing reliabilitv. Data 

averaging in analog systems is usually done at considerable extra 

ccst wit~ a separate instr~illent connected to the output of the 

basic analyzer. 

In contrast, the Model 48 has been designed to perfor~ a 

large variety of tasks by utilizing appropriate information 

stored in the system's program memory. For example, the microcohlputer is used to process signals from both a pressure and 

temcerature transducer to make corrections to the instrument 

output, resulting in co concentration measurements which are 

unaffected by changes in the temperature or pressure of the gas 

being sampled. Both linear and non-linear corrections are handled with equal ease. In addition, many diagnostic functions can 

be selected through the use of front panel pushbutton s~itches 

(Figure I-1). User selectable program options include: settable ti~e resuonse for data s~oothing; one hour averaged value which 

may be set for continuous output at a standard secondary pair of 

output terninals, or can be set to interrupt the primary output 

briefly every hour, or can be de-activated. These options are sta~dard with every instrument and are selected by setting 

s-.-itches on the front panel of the instrument. 

The~o Enviror.mental Instru~ents Inc. is pleased to have 

supplied you with a Medel 48. We are co~~itted to the manufacture of instruments exhibiting high standards of ~~ality perfo~­

a::ce, a::d w·orkwanship. We are prepared and eaga= to be of service to ycu in the use of this instr~~ent. 

A. F~INCIFLE OF OP~~TION CF ·r~~ GAS FILTER C~~~-LATION 

SPECTROMETER 

The techniaue of Gas Filter correlation (GFC) offers improved s;;ecific{ty and sensitivity over conventional nondisoers:ve infrared (NDIR) techniques. GFC spectroscopy is based uco~ cc~oarison of the detailed structure of the infrared absorption s~eStrun of the measured gas to that of other gases also 

present :n the sam;:>le being analyzed. The technique is implemented tv using a high concentration sample of the measured gas, 

i.e., cc~ as a filter for the infrared radiation transmitted 

throug~ ~he analyzer, hence the te~ GFC. 

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The basic components of the GFC co spect~orneter are shown in 

Figure I-2. Radiation from an IR source is chopped and then 

passed through a gas filter alternating bet~een CO and N2 due tc 

rotation of the filter ~o·heel. The radiation then passes through 

a narrow bandpass interference filter and enters a multiple 

optical pass cell where absorption by the sample gas occurs. The 

IR radiation then exits the sample cell and falls en an IR detector. 

The CO gas filter acts to produce a reference beam which 

cannot be further attenuated by CO in the sample cell. The N2 

side cf the filter wheel is transparent tc the IR radiation and 

therefore produces a measure beam which can be absorbed by co in 

the cell. The chopped detector signal is modulated by the alter-. 

nation between the two aas filters with an amolitude related tc 

the concentration cf CO-in the sample cell. Other gases do net 

cause modulation of the detector signal since they absorb the 

reference and measure beams equally. Thus the GFC system responds specifically tc co. 

With the improved rejection cf interferences afforded by the 

GFC technique, it is possible tc increase the sensitivity cf the 

analyzer. This is achieved by the multiple pass optics (White 

cell) used in the sample cell which leads tc a large path length, 

and thus an improved sensitivity, in a small physical space. This allows full scale sensitivity do~o~ to 1 PPM with a lower 

detectable limit (LDL) of 0.1 PPM tc be achieved. 

B. INSTRUMENT DESCRIPI'ION 

The instrument can be mcst conveniently discussed by separating it into the following operational components (Figure I-3): 

1. Ootical bench 

2. Correlation wheel and chopper motor 

3. Source and source power supply 

~- Detector, preamplifier, and bias supplies 

5. Input signal conditioning board 

6. DC power supply 

7. Microconpute= 

8. Temperature controller 

9. Flew components (pQ~p, valves, flo~oweter, and plumbing) 

10. Temperature and pressure transducers 

I-5 
] 

j 

J 

] 

] 

J 

] 

C. SPE:CIFICATIONS 

Ra.nges 0-1, 2, 5, 10, 

500, 1000 PPM 

20, so, 100, 200 ' 

Noise 0.05 PPM R~S - with time constant 

of J 0 seconds 

Minimum Detectable Limit 0.10 PPM 

Zero Drift, 24 hours +/- 0.2 PPM 

Sp•an Drift, 24 hours +/- 1% Full Scale 

Rise, Fall Times (0-95%) 1 Minutes 

(at 1 lpm flow, 30 second 

response time) 

Precision +/- 0.1 PPM 

Linearity +/- 1% 

Flow Rate 0.5 - 2 lpm 

Rejection Ration Negligible interference from 

water and C02. 

Operating Temperature Performance specifications maintained over the range 

15-J5°C (may be operated safely 

over the range 5-45°C) . 

Power Requirements 105 - 125 VAC, 60 Hz 

220 - 240 VAC, 50 Hz 

100 Watts 

Ph¥sical Dimensions 17''W x 8 3/4"H x 2J''D 

Weight 45 lbs. 

Dua:L outputs (Standard) Individually selectable to 

0-lOmv, o-100mv, o-1v, o-sv, 

0-lOV, digital display, 1 hour 

integrated value. other outputs 

available upon request 

(4-20ma) 

l 

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{ 
, 

~~.· 

'··-~· 

• 

SECTION 3 

SPECIFICATIONS 

Model 51 Total Hydrocarbon Analyzer 

Petector 

Type 

Minimum detectable 

Auto igniter 

Flame out safety 

Noise 

Drift 

Repeatability 

Accuracy 

Range 

Auto Ranging 

Temperature 

Sample 

Sampling Rate 

Detector Flow Rate 

Response Factor 

Response Time 

outputs 

vacuum fluorescent 

Display 

Analog 

Flame Ionization. 

0.1 ppm. (independent of gas). 

electronic, processor controlled. 

solenoid shuts off hydrogen fuel 

on flame out and alarms. 

less than 1% F.S. 

less than 1% in 24 hours. 

2% of reading± 0.1 ppm. 

2% of reading plus span gas accuracy 

± o .1 ppm. 

0.1 ppm to 10,000 ppm.(for propane). 

Covers total instrument operating 

ranges automatically. 

200 degrees c. Controlled by 

microprocessor with readout on 

screen. 

approximately 2.5 L/min. 

approximately 30 mL/min. 

Front panel settable to report same 

as span gas or different compound. 

90% within 5 seconds (on each range) 

Alpha numeric 20 character length 4 

lines. 

0-10 volts (O - 5v & 0 - lv options 

available) with 7 adjustable ranges. 

4-20 rna output available as Option 

5. 

Serial Port RS232 port for sending all reports 

to external printer for archival 

purposes, or to a computer for two 

way communication. 

Reports 

Analysis reports High, low, and average concentration 

3-1 
·----- ·------

Report Frequency 

Alarm 

ca 1 i.bra tion 

for each period scrolled on display 

and made available to RS2J2C port. 

Settable from 1 to 99 minutes. 

Concentration alarm with time 

written to alarm report in UTILITY. 

Notice also appears on the display 

any time there is a concentration 

exceedance. 

External The standard calibration procedure permits the introduction of the zero 

and span gases into the Model 51 

through the sample port. 

Internal (Optional) 

Span Gas 

Frequency 

Standard span value entered via key 

pad. 

Completely automatic zero and span 

on a settable cycle from 1 to 99 

hours. 

The most recent good calibration 

data retained in EEPROM'S not 

overwritten by erroneous calibration. 

sample stream Selection (Optional with Model 440) 

streem sequence settable in any order to 10 digits. 

Time between stream settable in minutes 1 to 99. 

changes (also time 

of analysis reports). 

Manual Front panel controls, through. 

to hold the present· 

advance to the next 

Utility Menu, 

stream or to 

stream. 

Concentration Individually settable over total 

system 

Internal 

External 

Alarm condition 

range for each sample stream. 

Denotes problem with analyzer. 

Audible so db alarm for both alarms. 

Both alarms activate JA AC/DC 

contact closure for external alarms. 

Reported to screen, RS232C, and 

alarm status memory in unit. 

J-2 

!k-7 

i 

t. 

L I 

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J 

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l.. 

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.. ' ! . '. 

, I 
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Gases 

Combustion Air 

Fuel Hydrogen 

Span gas 

Zero Air 

Control 

Phvsical 

Ambient Temperature 

Power Requirements 

Case size 

Weight 

150 mLjmin @ 30 psig required. 

25 mLjmin @ 30 psig 

required. 

40% HydrogenjHelium - 80 mLjmin @ 

70 psig required. 

Generally propane in air. Supplied 

to unit at about 10 psig and 

adjusted for proper flow. About 

1500 mL required per calibration. 

Supplied to unit at about 10 psig 

and adjusted for proper flow. About 

2 L required per calibration. 

All critical flows are controlled by 

temperature controlled restrictors 

adjusted by pressure regulators 

on flow panel of instrument. 

40 Degrees F (5 degrees C) to 115 

degrees F (40 degrees). 

120 /220 VAC, 60/50 Hz, 3.0 A 

Bench Mount HWD 9.2 x 16.9 x 22 in. 

(23.4 x 42.9 x 55.9 em.) . Bench: 55 lbs.(24.9Kg). 

3-3 
SPECIALTY GAS DIVISION 

11711 S. Alameda Street 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: Mlchlg:l.ll A!rgas 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: 

CC·25694 Sulfur D!oxlde 

Nitrogen 

Certification Period (months): 24 

Expiration Date: 18 May 1996 

Cylinder Pressure: 2000 psi a 

DO NOT USE BELOW 150 PSIG 

azue~ ANALYST 

800 PPM 

Balance 

Date: 18 May 1994 

P.O.: PG 0530 

NOMINAL 

857.3 PPM 

Balance 

ACTUAL 
SPECIALTY GAS DIVISION 

11711 S. Alameda Street 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: 

Airgas I Michigan Date: 19 December 1994 

P.O.: PG-0621 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC37899 Sulfur Dioxide 

Ni troger. 

Certification Period (months): 24 

Expiration Date: 19 Decembe= 1996 

Cylinder Pressure: 2000 psia 

DO NOT USE BE~OW 150 PSIG 

400 PPM 

Balance 

392.9 PPM 

Balance 

ACTUAL 
SPECIALTY GAS DIVISION 

11711 S. Alameda Street 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: 

Airgas I Mic:higan Date: 19 December 1994 

P.O.: PG-0621 

EPA Protocol Procedure G-1 

CYLINOER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC37923 Sulfu::- Dioxide 

Nitrogen 

Certification Period (months): 24 

Expiration Date: 19 December 1996 

Cylinde= Pressure: 2000 psia 

DO NOT USE BELOW 150 PSIG 

225 PPM 

Balance 

222.7 PPM 

Balance 

ACTUAL 
SPECIALTY GAS DIVISION 

11711 S. Alameda Street 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: 

Airgas I Michigan Date: 19 December 1994 

P.O.' PG-0621 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC37948 Nitric Oxide 

NOX 

Nitrogen 

Certification Period (months): 24 

Expiration Date: 19 December 1996 

Cylinder Pressure: 2000 psia 

DO NOT USE BELOW 150 PSIG 

ANALYST 

225 PPM 

Balance 

221.4 PPM 

221.6PPM 

Balance 

ACTUAL 
SPECIALTY GAS DIVISION 

11711 S. Alameda Street 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPO.RT- PRODUCT CERTIFICATION 

TO: 

Airgas I Michigan Date' 19 December 1994 

P.O., PG-0621 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC38000 Nitric Oxide 

NOX 

Nitrogen 

Certification Period (months): 24 

Expiration Date: 19 December 1996 

Cylinder Pressure: 2000 psia 

DO NOT USE BELOW 150 PSIG 

ANALYST 

125 PPM 

Balance 

122.5 PPM 

122.9 PPM 

Balance 

ACTUAL 
Scott Specialty Gases, Inc. 

1290 COMBERMERE STREET, TROY, Ml48083 (313) 585>-2950 FAX: (313) SSS-2134 

CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Customer 

MICHIGAN AIR GAS 

311 STOKER DR 

SAGINAW MI 48604 

ANALYTICAL INFORMATION 

Assay Laboratory 

Scott Specialty Gases, Inc. 

1290 Combermere 

Troy, MI 48083 

Purchase Order 039 I 1 

Scott Project# 560481 

Certified to exc:::ed the minimum specifications of EPA Protocol 1 Procedure #G 1, Section Number 3.0.4 

Cylinder Number ALM016066 Certification Date 1-19-94 Expiration Date I-19-96 

C:;!ir:c!;:r Pn:::s.:;ur.: 19CO p.!:it;; 

ANALVZED CYLINDER 

Components 

Nitric Oxide 

Total Oxides of Nitrogen 

Balance Gas: Nitrogen 

Certjfied Concentration 

50.40 ppm 

50.50 ppm 

t: ... ~c 

Analvtical Uncertaintv• 

±1 '% NIST Directly Traceable 

Reference Value Only 

• Analytical WlCert;Unty is inclusive of usual kn0'-"11 error sources which at least includes reference standard error & precision of the measurement processes. 

REFERE~CESTANPARD 

Type Expiration Date 

CR..\11684 9-17,94 

INSTRUMENT A T!ON 

Instrument/Model/Serial# 

NO: Horiba/OPE-235/483814 

Cylinder Number 

ALM-024698 

Last Date Calibrated 

1-6-94 

Concentration 

95.6 PPM NO IN Nz 

Analytical Principle 

Chemiluminescence 

ANALYZER READINGS (Z=Zero Gas R=Rererence Gas T=Test Gas ,....Correlation Coefficient) 

Ccmpcne:Jts 

Nitric Oxide 

Special :"iotes 

-r=-s· .. Triad An::: lysis Second Triad An:::'y:is - Dace: J-12-94 Response Units: mv Dace: 1-19-94 Response Umts: mv 

ZI,.O.OO Rl-95.60 T\,.50.50 Z\..(1.00 Rl-95.60 T\•50.30 

Rl""J5.60 Z2=0.oo· n .. 5o.5o R.Z-95.60 Z2..0.00 n .. 5o.3o 

Z3..0.00 TI=-50.50 RJ-95.60 ZJ=O.OO D=-50.30 RJ-95.60 

Avg. Cone. ofCt1SC. Cyl. 50.50 ppm Avg. Cone. ofCllst Cyl. 50.30 ppm 

~IL-----1 _ L____ll '------

Calib:-aticr: Cu!"'Vc 

Concenrratioa .. A+Blt+CX""+D:t}+Ex 4 

r-=0.99999 CRM 1684 

Constants: 

B*\.000\15 

D-0 

A--o.000967384 

c-o 

E-<l 

Concentration"'A+Blt+Cxl+DltJ+Ex4 

ConcentrJ.rion•A+Blt +D){ +Ex 

Analyst Fronk P. Doran 
SPECIALTY GAS DIVISION 

11711 5. Alameda Street 

Los Angeles, CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: 

Airgas I Michigan Date: 19 December 1994 

P.O.: PG-0621 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC37999 Carbon Monoxide 

Nitrogen 

Certification Period (months): 36 

Expiration Date: 19 December 1997 

Cylinder Pressure: 2000 psia 

DO NOT USE BELOW 150 PS:G 

400 PPM 

Balance 

402.3 PPM 

Balance 

ACTUAL 
SPECIALTY GAS DIVISION 

1 1711 S. Alameda Street 

Los Angeles. CA 90059 

(213) 564-5711 

ANALYTICAL REPORT- PRODUCT CERTIFICATION 

TO: 

Airgas I Michigan Date, 19 December 1994 

P.O.' PG-0621 

EPA Protocol Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL 

CC37919 Carbon Monoxide 

Nitrogen 

Certification Period (months}; 36 

Expiration Date: 19 December 1997 

Cylinder Pressure: 2000 psia 

DO NOT USE BELOW 150 PSIG 

225 PPM 

Balance 

224.5 PPM 

Balance 

ACTUAL 
AGA Gas, Inc. 

Cert~f~cate of Ana1ys~s 

EPA Protocol il 

Production Number: 03930968 

Cylinder Number(s): CC92021 

certified concentration: ~7.92 ppm Carbon Monoxide 

Balance Gas: Nitrogen 

Cylinder Pressure: 2015 psi 

Date of Certification: March 30, 1993 

Certification Expiration: September 30, 199~ 

SRM Information: SRM Number 

1678C 

This assay/certification was 

Cyl. Number Concentration 

CAL-6685 ~5.2 ppm CO/N2 

performed according to Section 3.0.i 

The certification was performed at: AGA Specialty Gas, Inc. 

6~21 Monclova Rd. 

Maumee, Ohio ~3537 

Instruments Used: 

EPAlnl 

AGA Gas Inc. 

&42 1 Monclova j:load 

~ .... m_ ~""' <1."'10:,11 

Carbon Monoxide: Horiba OPE-l~~E. CFA-26 

Non-dispersive Infrared 

Serial No. 8501190110 

Calibration: 2-15-93 

... ~~~~-~ 

'" 

Michael Sickmiller 

Quality Control Supervisor 

{ 

; 

f • 

I 

.... 
1""1ICHIG;.N qr~GAS 1 517 755 2100 P.C12 

SP£CIAL TY GAS OIVISION 

11711 S. Alemeda Stlltet 

Los Angol••· CA. 900$9 

(213) 564-5711 

____ __,A~N,_,A=L YTICAl REP9AT :- PRODVCT CERTIFICATION 

TO: 

Airgaa f Michigan 

P.O.: PG0654 

E~A Tr&~•ability PrQtOeol For Aaaay And Certifi~ation 

o: G&8e0ua Calib~ation Stan~r~ P:ocedu~• G-1 

CYUNOER NO. CONSTITUENTS CONCENTRATION-;--· """NOMINAl. 

CC10656 Prop<~n• 

Nitrogen 

Certification !'eriod (men~) : J6 

Expiration Oats • 16 February l9t8 Cyli~de: Pre••u~•: ~000 p•ia 

00 NOT OSZ BELOW 150 PSrG 

425 PPM 

S..lanc:e 

411.7 !'PM 

Balance 

ACTUAL 
Date' 03 March 1995 

p .0.' PGO 654 

~:- ··'.- '; 

EPA T~aceability P~otocol Fer Assay JL~d Certification 

of Gaseous Calibration Standards Procedure G-1 

CYLINDER NO. CONSTITUENTS CONCENTRATION: 

150-299 Propane 

Nitrogen 

Certification Period {months) 

Expiration Date : 16 February 

Cylinder Pressure: 2000 psia 

DO NOT USE BELOW 150 PSIG 

' 3 6 

1998 

250 PPM 

Balance 

NOMINAL 

257.7 PPM 

Balance 

ACTUAL 

l 

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~.·. 

~ 

~ 

tl 

~ 

L[ 

tL 

;F; rL 
APPENDIXD 

FIEL1> DATA 

j/2 
····· ........ 

-·-···---

DIVISION -··-· OF l.iiiii -·-·· -

... ·-

. ·· · --·-·.1 ----·· ... --···-·· 

To: Bertram Smith 

From: Carl Gewirtz 

#2 Kiln- Modular Size Brick 

Blend of Brick: Hickory Ridge 

Charge times with a 12 car per day push rate: 

0120 

0320 

0520 

0720 

0920 

1120 

1320 

1520 

1720 

1920 

2120 

2315 

Lime feed rate of 165 lbs. per hour. 

Dry Face Brick wt. 4.10 x 10680 = 43,788 

Dry 1-1/4" solid slabs wt. 2.03 x 1789 = 3,631 

Total= 47,419 

Fired Face Brick wt. 3.80 x 10680 = 40,584 

Fired 1-1/4" solid slabs wt. 1.9 x 1789 = 3,399 

Total = 43,983 

6-13-95 

i'iii~~~~;'; ~-=-=~ • P.O. BOXes • 3820 SEAR ROAD • CORUNNA. MICHICAN 48117 • 517f7 .. 3·3-4-4 .. • 1001812·8880 • FAX 517f743-3:SG4 

;f.3 
Detroit Regional Office 

22345 Roethel Drive 

P.O. Box 8022 

Nevi, Ml 483 75 

(81 0) 344-1770 

Fax (810) 344-2654 

June 28, 1995 

Mr. David D. Engelhardt 

NETWORK ENVIRONMENTAL 

2629 Remico S.W., Suite B 

Grand Rapids, MI 49509 

Dear Mr. Engelhardt: 

Clayton 

ENVIRONMENTAL 

CONSULTANTS 

Clayton Project No. 27503.00 

Client Reference: 10.08 

Attached is our analytical laboratory report for the samples received on 

June 9, 1995. Also enclosed is a copy of the Chain-of-Custody record 

acknowledging receipt of these samples. 

Please note that any unused portiOn of the samples will be discarded after 

July 28, 1995, unless you have requested otherwise. 

We appreciate the opportunity to assist you. If you haye any questions 

concerning this report, please contact a Client Services Representative at 

(810) 344-2650' 

"";i£7--;f /r 

Robert Lieckfield, Jr., CIH 

Director; Laboratory Services 

Detroit Regional Office 

RL/ke 

Attac:r..ments 

Clayton Environmental Consultants, Inc. Detroit • New Yotk 

Minneapolis • Cleveland • Chicago • Birmingham, U.K. 

• Atlanta • San Francisco • Los Angeles • Honolulu 

london, U.K. • Southampton. U.K. • C.11teshead. U.K. 
Sample Identification: 

Lab Number: 

Sample Type: 

Analyst: 

Analyte 

P'lun:=ida 

#l 

COla 

Analytical Results 

for 

NETWORK ENVIRONMENTAL 

Clayton Project No. 27503.00 

Client Reference: 10.08 

Date 

Date 

Impinger 

sc 

Sampled: 

Received: 

Concentration LOD Analytical 

(,ug) (,ug) Method 

400 300 EPA l3B 

Clayton 

ENVIR:QNMfi'oTAL 

CONSULTANTS 

06/07/SS 

06/0S/SS 

Date 

Analyzed 

06/27 /SS 

------------------------------------------------------------------------------------

Sample Identification: #2 Date Sampled: 06/07 /SS 

Lab Number: 002a Date Received: 06/0S/SS 

Sample Type: Impinger 

Analyst: sc 

Concentration LOD Analytical Date 

Analyte (,ug) (,ug) Method Analyzed 

Fluoride <300 300 EPA l3B 06/27 /SS 
Sample Identification: 

Lab Number: 

Sample Type: 

Analyst: 

Analyte 

Fluoride 

#3 

003a 

Analytical Results 

for 

NETWORK ENVIRONMENTAL 

Clayton Project No. 27503.00 

Client Reference: 10.08 

Date 

Date 

Impinger 

sc 

Sampled: 

Received: 

Concentration LOD Analytical 

(!'g) (!'g) Method 

89,000 300 EPA 13B 

Clayton 

fNVUi.0NM€NTAL 

(QNSULT,t.NTS 

06/07/95 

06/09/95 

Date 

Analyzed 

06/27/95 

------------------------------------------------------------------------------------

Sample Identification: #4 Date Sampled: 06/07/95 

Lab Number: 004a Date Received: 06/09/95 

Sample Type: Impinger 

Analyst: sc 

Concentration LOD Analytical Date 

Analyte (!'g) (!'g) Method Analyzed 

Fluoride 140,000 300 EPA 13B 06/27/95 

;fl-. 
Analytical Results 

for 

NETWORK ENVIRONMENTAL 

Clayton Project No. 27503.00 

Client Reference: 10.08 

Sample Identification: #5 Date Sampled: 

Lab Number: 005a 

Sample Type: 

Analyst: 

Analyte 

Fluoride 

General Notes: 

<: Less than the 

Impinger 

sc 

Concentration 

()lg) 

<300 

indicated limit of 

-- . Information not available or not 

Date Received: 

LOD Analytical 

()lg) Method 

300 EPA l.3B 

detection (LOD) 

applicable 

Clayton 

ENVIRONMENTAL 

CONSULTANTS 

06/07/95 

06/09/95 

Date 

Analyzed 

06/27/95 
"'I ~ ......_~ !' Clayton - -.I For Clayton Us

ENVIRONMENTAL 

CONSULTANTS 

A 

~huh & Md ~nno~n 

Compo~ny 

REQUEST FOR LABORATORY 

ANALYTICAL SERVICES 

Project No. 

Balch No. 

Client No. 

'/· 

( ' [> Name ~.<>-ILod __ t" 

~ 

"- ·, ,\"' 0 f Purchase Order No. C

1-- ~ (:! Company --- ----- Dept. w Name fL S Marling Address 

--~ §'! B f.,..o:-m=p a"'ny-:-----L,=---,Lt--.lh4-~

ll! ~ City, Stale, Zip ~ > 1-- Address 

a: Telophone No.c J(r u. n J ~ City, Stale, Zip Dalo RestJII !Jequirod: 11ush Charges Aui~\Orized? Phone Resulls Samples are: ( ' 5- 0 Yes [2j;No · (check il applicable) 

iSpodal Jnslruclions: (method, limit ol detection, etc.) h D Drinking Water 

"Fillut'-r.l'< r"·Q, EPA - fl/dlw.! - /3 5 D Collected in the 

• Explanation ol PresoJValivo: Stale ol New York 

CLIENT SAMPLE IDENTIFICATION DATE MATRIX/ AIR VOLUME I SAMPLED MEDIA (specify units) 

i" 

m 

c 

'iii 

c 

8 

0 

a; 

.0 

E 

z " !.'' -<. 

f}. 

'I ?I I l l' l l 

I </r/hl ,_,LuI'.,, '·i.e I, X. -, /_/..,_ r7(:.-- -D~.,~.n.-. ,_''II ' ' 

I I I I I r I I X: 

' -l I \lt 1'-Y I ,Jr ,, y -1TX 

lA 

CHAIN flecoived by: _ c;• 

OF Received at Lab by: ~?v: <'ff CUSTODY J:)- Sample Condition Upon Receipt:.-- J;] Accepta

. I 

AuthoriZe Date _ _._'4--"'-/--L.L..... RECEIVE

Please return completed !arm and s;;;;rel'es to one ol the Clayton Environmental Consullants, Inc. Jabs listed below: 

~ 22345 Roethel Drive 

~ Novi, Ml 48375 

\ (313) 344-1770 

Raritan Canter 

160 Fieldcrest Ave. 

Edison, NJ 08837 

(201) 225-6040 

400 Chastai~,J;;enter Blvd., N.W. 

Suite 490 

Kennesaw, GA 30144 

(404) 499-7500 

1252 Quarry Lane 

Pleasanton, CA 945Sir' 

(415) 426-2600 

6/9
·. 

Network Environmental, Inc. 

P.O. Box 202l 

Grand Rapids, MI 4950l 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIV:tSION, U.S. BRJ:CK 

CORUNNA, MICHIGAN 

t2 lULN EXHAUST 

DATE: 6/7/95 
Network Environmental, Znc. 

PZTOT TRAVERSE DATA 

COMPANY NAME: MJ:CBZGAN DZVJ:SZON, U.S. BIUCK TEST DATE: 6/7/95 

COMPANY LOCATZON: CORUNNA, MJ:CBIGAN 

SOURCE NAME: f2 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

RUN NUMBER: 1 % CARBON DIOXIDE: 

STACK RADIUS, in.: 19.5 % OXYGEN: 

GAS TEMPERATURE, Deg F: 295 % CARBON MONOXIDE: 

STATIC PRESSURE, in. H20: -.32 PITOT FACTOR: .87 

BAROMETIUC PRESSURE: 28.6 

POINT VELOCITY PRESSURE, rNCBES OF WATER 

PT. LOCATION, PORT 

• INCHES 1 2 

1 1. 72 0.33 0.30 

2 5.69 0.41 0.40 

3 11.54 0.49 0.47 

4 27.46 0.48 0.51 

5 33.31 0.47 0.51 

6 37.28 0.46 0.51 

C("' ) ';C 
Network Environmental, Inc. 

SAMPLING TRAIN DATA 

COMPANY NAME: MICHIGAN DIVISION, u.s. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: t2 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

SAMPLE NUMBER: 1 IMPINGER BOX #: 1 GAS METER START: 169.274 

TYPE OF TRAIN: EPA-5 FILTER SET #: 29 METER CAL. FACTOR: l.OOO 

NOZZLE DIA, in: .3125 PRIM. FILTER #: DH-756 CLOCK TIME START: 9:42 

VENTURI NUMBER: SEC. FILTER i: BH-756 METER TIME START: 0 

CONTROL BOX i: 1 BAROMETRIC PRESS: 28.6 METER TIME STOP: 1 

PITOT CAL. FACTOR: .87 

VELOCITY RATE MTR GAS METER POMP GAS METER STACK FILTER 

PRESSURE PRESSURE READING VAC. TEMP.' F TEMP. TEMP. 

PORT POINT IN. H20 IN. H20 CU. FT. IN. HG IN OUT F F 

2 6 0.48 3.53 174.320 3.00 90 90 296 254 

5 0.49 3.61 179.490 3.50 90 90 296 256 

4 0.50 3.68 184.710 3.50 92 90 298 256 

3 0.44 3.24 189.630 3.50 94 90 299 256 

2 0.40 2.95 194.350 3.50 95 90 300 256 

1 0.34 2.51 198.727 3.00 96 91 298 255 

1 6 0.45 3.35 203.680 3.50 95 91 292 258 

5 0.46 3.40 208.720 3.50 96 91 298 258 

4 0.48 3.55 213.850 3.50 98 91 299 258 

3 0.45 3.33 218.830 3.50 99 92 300 256 

2 0.43 3.19 223.720 3.50 99 93 300 257 

1 0.33 2.45 228.080 3.00 100 93 300 256 

;LJ/ 
Network Environmental, Inc. 

SAMPLING TRAIN DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: 12 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

SAMPLE NUMBER: 2 IMPINGER BOX f: 1 GAS METER START: 228.268 

TYPE OF TRAIN: EPA-5 FILTER SET f: 34 METER CAL. FACTOR: 1.000 

NOZZLE OrA, in: .3125 PRIM. FILTER f: DH-758 CLOCK TIME START: 11: 05 

VENTURI NUMBER: 

CONTROL BOX f: 1 

VELOCITY 

PRESSURE 

PORT POINT IN. H20 

1 6 0.46 

5 0.47 

4 0.48 

3 0.48 

2 0.43 

1 0.45 

2 6 0.45 

5 0.51 

4 0.51 

3 0.46 

2 0.41 

1 0.36 

SEC. FILTER i: BH-758 METER TIME START: 0 

BAROMETRIC PRESS: 28.6 

PITOT CAL. FACTOR: .87 

RATE MTR GAS METER 

PRESSURE READING 

IN. H20 CO. FT. 

3.19 233.100 

3.26 238.020 

3.33 242.970 

3.33 247.920 

2.98 252.650 

3.15 257.512 

3.13 262.330 

3.55 267.490 

3.54 272.630 

3.18 277.440 

2.84 282.070 

2.49 286.462 

METER TIME STOP: 1 

POMP GAS METER STACK FILTER 

VAC. TEMP. , F TEMP. TEMP. 

IN. HG IN OUT F F 

2.50 93 93 295 254 

3.00 93 92 294 256 

3.00 94 92 293 257 

3.00 96 92 295 256 

3.00 96 92 295 257 

3.00 95 92 290 252 

3.00 92 91 289 257 

3.00 92 90 289 256 

3.00 93 90 292 257 

3.00 95 90 296 257 

3.00 96 90 296 257 

3.00 96 90 296 257 
Network Environmental, Inc. 

LABORATORY ANALYSIS REPORT 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: t2 KILN EXHAUST 

SAMPLING STAFF: CARGILL/ENGELHARDT 

DATE SUBMITTED TO LAB: 6/9/95 RECEIVED BY: DDE 

DATE REPORTED FROM LAB: 6/12/95 CHEMIST ( S) : DDE 

PARTICULATE TRAIN SAMPLE NUMBER 1 

-----PARTICULATE WEIGHT GAIN, MGS.----- CAPTURED WATER 

LAB SAMPLE ALT 1 ALT 2 

!DENT. !DENT. STD. s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

1 DH-756 0.50 9.0 180.0 

BH-756 0.00 

NW-1 1.40 

TOTALS 1.90 o.oo 0.00 9.0 180.0 

PARTICULATE TRAIN SAMPLE NUMBER 2 

-----PARTICOLAXE WEIGHT GAIN, MGS.----- CAPTURED WATER 

LAB SAMPLE ALT 1 ALT2 

!DENT. IDENT. STD. s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

2 DH-758 0.80 8.0 194.0 

BH-758 o.oo 

NW-2 1.30 

TOTALS 2.10 0.00 0.00 8.0 194.0 
Network Environmental, Znc. 

P.O. Box 2021 

Grand Rapids, HZ 49501 

SOURCE EMISSION TESTING 

at 

MZCIUGAN D:rv:tSZON, U.S. BRICK 

CORUNNA, MZCBZGAN 

f2 KILN EXHAUST (FLUORIDE) 

DATE: 6/7/95 
Network Environmental, Inc. 

PITOT TRAVERSE DATA 

COMPANY NAME: KICBIGAN DI:VJ:SION, U.S. B!UCK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, KICBIGAN 

SOURCE NAME: f2 KILN EXHAUST (FLUO!UDE) 

SAMPLING STAFP: BYRD/ENGELHARDT 

RUN NUMBER: 1 % CARBON DIOXIDE: 

STACK RADIUS, in.: 19.5 % OXYGEN: 

GAS TEMPERATURE, Deg F: 295 % CARBON MONOXIDE: 

STATIC PRESSURE, in. B20: -.32 PITOT FACTOR: .87 

BAROMETRIC PRESSURE: 28.6 

POINT VELOCITY PRESSURE, INCHES OF WATER 

PT. LOCATION, PORT 

t INCHES 1 2 

1 1. 72 0.33 0.30 

2 5.69 0.41 0.40 

3 11.54 0.49 0.47 

4 27.46 0.48 0.51 

5 33.31 0.47 0.51 

6 37.28 0.46 0.51 
Network Environmental, Inc. 

SAMPLING TRAIN DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: #2 KILN EXHAUST (FLUORIDE) 

SAMPLING STAFF: BYRD/ENGELHARDT 

SAMPLE NUMBER: 1 IMPINGER BOX t: 1 GAS METER START: 286.595 

TYPE OF TRAIN: FLUORID FILTER SET t: METER CAL. FACTOR: 1.000 

NOZZLE DLA, in: .3125 PRIM. FILTER #: CLOCK TIME START: 14:10 

VENTUIU NUMBER: SEC. FILTER i: METER TIME START: 0 

CONTROL BOX t: 1 BAROMETRIC PRESS: 28.6 METER TIME STOP: 1 

PITOT CAL. FACTOR: .87 

VELOCITY 

PRESSURE 

PORT POINT IN. H20 

RATE MTR GAS METER PUMP GAS METER STACK FILTER 

PRESSURE READING VAC. TEMP. , F TEMP. TEMP. 

IN. H20 CU. FT. IN. HG IN OUT F F 

2 6 0.51 3.43 291.550 2.50 90 90 298 

5 0.52 3.49 296.710 2.50 93 90 301 

4 0.52 3.48 299.500 2.50 90 90 301 

3 0.46 3.08 304.760 2.50 92 90 300 

2 0.40 2.68 309.100 2.50 94 90 298 

1 0.28 1.89 313.369 2.50 93 90 299 

1 6 0.47 3.18 318.100 2.50 92 90 298 

5 0.50 3.16 323.060 2.50 95 90 299 

4 0.48 3.23 328.000 2.50 97 90 300 

3 0.47 3.17 332.900 2.50 98 91 300 

2 0.58 3.92 338.300 3.00 100 92 298 

1 0.32 2.17 342.493 2.00 100 92 297 

;9fc 
Network Environmental, Inc. 

SAMPLING TRAIN DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: #2 KILN EXHAUST (FLUORIDE) 

SAMPLING STAFF: BYRD/ENGELHARDT 

SAMPLE NUMBER: 2 IMP INGER BOX t: 1 GAS METER START: 342.816 

TYPE OF TRAIN: FLUORID FILTER SET #: METER CAL. FACTOR: 1.000 

NOZZLE DIA, in: .3125 PRIM. FILTER #: CLOCK TIME START: 16:05 

VENTURI NUMBER: SEC. FILTER t: METER TIME START: 0 

CONTROL BOX #: 1 BAROMETRIC PRESS: 28.6 METER TIME STOP: 1 

PITOT CAL. FACTOR: .87 

VELOCITY 

PRESSURE 

PORT POINT IN. B20 

RATE MTR GAS METER PUMP GAS METER 

PRESSURE READING VAC. TEMP. , F 

STACK FILTER 

TEMP. TEMP. 

IN. B20 CO. FT. IN. BG IN OUT F F 

1 6 0.48 3.12 347.650 2.50 93 92 296 

5 0.50 3.38 352.640 2.50 97 92 300 

4 0.49 3.31 357.650 2.50 100 93 300 

3 0.48 3.25 362.585 2.50 101 93 300 

2 0.43 2.92 367.350 2.50 101 94 298 

1 0.35 2.38 371.538 2.50 101 94 296 

2 6 0.51 3.47 376.000 2.50 99 94 298 

5 0.48 3.36 381.510 2.50 102 95 301 

4 0.47 3.19 386.470 2.50 102 95 300 

3 0.51 3.47 391.540 3.00 103 95 299 

2 0.38 2.59 396.460 2.50 103 95 298 

1 0.28 1.91 400.081 2.00 102 95 297 

!9} 
Network Environmental, Inc. 

ORSAT ANALYSIS DATA 

COMPANY NAME: MICHIGAN DIVISION, u.s. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: t2 KILN EXHAUST (FLUORIDE) 

SAMPLING STAFF: BYRD/ENGELHARDT 

DATE OF ANALYSIS: 6/7/96 METHOD: MULTIPOINT INTEGRATED SAMPLE 

PART CARBON DIOXIDE OxYGEN CARBON MONOXIDE 

SMPL. CONT RUN 

t t t FINAL INIT. ' FINAL INIT. ' FINAL INIT. ' 

1 1 1 3.4 0.0 3.4 18.7 3.4 15.3 18.7 18.7 0.0 

2 3.4 0.0 3.4 18.7 3.4 15.3 18.7 18.7 0.0 

3 3.4 o.o 3.4 18.7 3.4 15.3 18.7 18.7 0.0 

2 2 1 2.8 o.o 2.S 19.1 2.8 16.3 19.1 19.1 0.0 

2 2.8 0.0 2.8 19.1 2.8 16.3 19.1 19.1 0.0 

3 2.8 0.0 2.8 19.1 2.8 16.3 19.1 19.1 o.o 
Network Environmental, Inc. 

LABORATORY ANALYSIS REPORT 

COMPANY NAME: HJ:CHIGAN D:rvJ:SION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, HJ:CBIGAN 

SOURCE NAME: f2 KILN EXHAUST (FLUORIDE) 

SAMPLING STAFF: BYRD/ENGELHARDT 

DATE SUBHJ:TTED TO LAB: 6/9/95 RECEIVED BY: DOE 

DATE REPORTED FROM LAB: CBEHJ:ST(S): CLAYTON 

PARTICULATE TRAIN SAMPLE NtlMBER 1 

-----PARTICULATE WEIGHT GAIN, MGS.-----

LAB SAMPLE ALT 1 ALT 2 

IDENT. IDENT. STD. 

NO. MARK ANAL. 

F01 

TOTALS 0.00 o.oo 0.00 

PARTICULATE TRAIN SAMPLE NtlMBER 2 

-----PARTICULATE WEIGHT GAIN, MGS.-----

LAB SAMPLE ALT 1 ALT 2 

IDENT. IDENT. STD. 

NO. MARK ANAL. 

F02 

TOTALS 0.00 o.oo 0.00 

CAPTURED WATER 

S. GEL 

GRAMS 

12.0 

12.0 

CAPTURED 

s. GEL 

GRAMS 

12 .o 

12 .o 

CONDSR 

MLS. 

176.0 

176.0 

WATER 

CONDSR 

MLS. 

178.0 

178.0 

/9:7 
: 

Network Environmental, Inc. 

P.O. Box 2021 

Grand Rapids, HI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVJ:SION, 0. S. BRICK 

CORUNNA, MICHIGAN 

t2 lULN INLET (FLUORIDE) 

DATE: 6/7/95 
Network Environmental, Inc. 

PITOT TRAVERSE DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORO'NNA, MICHIGAN 

SOURCE NAME: t2 KILN INLET (FLUORIDE) 

SAMPLING STAFF: CARGILL/SCBO'LTES 

RUN NO'MBER: 1 ' CARBON DIOXIDE: 

STACK RADIO'S, in.: 21 ' OXYGEN: 

GAS TEMPERATO'RE, Deg P: 542 ' CARBON MONOXIDE: 

STATIC PRESSURE, in. H20: -2 PITOT PACTOR: .87 

BAROMETRIC PRESSURE: 28.6 

POINT VELOCITY PRESSURE, INCHES OP WATER 

PT. LOCATION, PORT 

t INCHES 1 2 

1 1.84 0.47 0.43 

2 6.13 0.45 0.42 

3 12.43 0.43 0.39 

4 29.56 0.39 0. 33 

5 35.86 0.31 0.25 

6 40.15 0.36 0.25 
Network Environmental, Inc. 

ORSAT ANALYSIS DATA 

COMPANY NAME: MICHIGAN DIVISION, u.s. BJUCK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

S0t1RCE NAME: t2 KILN INLET ( FLOOJUDE) 

SAMPLING STAFF: CARGILL/SCBOLTES 

DATE OF ANALYSIS: 617/95 METHOD: KIJLTIPOINT INTEGRATED SAMPLE 

PART CARBON DIOXIDE OXYGEN CARBON MONOXIDE 

SMPL CONT RON 

t t t FINAL INIT. '!; FINAL INIT. '!; FINAL INIT. '!; 

1 1 1 2.4 0.0 2.4 19.4 2.4 17.0 19.4 19.4 0.0 

2 2.4 0.0 2.4 19.4 2.4 17.0 19.4 19.4 0.0 

3 2.4 0.0 2.4 19.4 2.4 17.0 19.4 19.4 0.0 

2 2 1 2.5 0.0 2.5 19.1 2.5 16.6 19.1 19.1 o.o 

2 2.5 o.o 2.5 19.1 2.5 16.6 19.1 19.1 0.0 

3 2.5 o.o 2.5 19.1 2.5 16.6 19.1 19.1 o.o 

.• 
Network Environmental, Inc. 

LABORATORY ANALYSIS REPORT 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: f2 KILN INLET (FLUORIDE) 

SAMPLING STAPF: CARGILL/SCHULTES 

DATE SUBMITTED TO LAB: 6/9/95 RECEIVED BY: DDE 

DATE REPORTED FROM LAB: CBEMIST(S): CLAYTON 

PARTICULATE TRAIN SAMPLE NUMBER 1 

-----PARTICULATE WEIGHT GAIN, MGS.----- CAPTURED WATER 

LAB SAMPLE ALT 1 ALT2 

IDENT. IDENT. STD. s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

FI1 8.0 50.0 

TOTALS o.oo o.oo 0.00 8.0 50.0 

PARTICULATE TRAIN SAMPLE NUMBER 2 

-----PARTICULATE WEIGHT GAIN, MGS.----- CAPTURED WATER 

LAB SAMPLE ALT 1 ALT2 

IDENT. IDENT. STD. s. GEL CONDSR 

NO. MARK ANAL. GRAMS MLS. 

FI2 12.0 68.0 

TOTALS 0.00 0.00 o.oo 12.0 68.0 

.· 
Network Environmental, Inc. 

P.O. BoX 2021 

Grand Rap~ds, MI 49501 

SOURCE EMISSION TESTING 

at 

MICHIGAN DIVISION, U.S. BRICK 

CORUNNA, MICHIGAN 

DRYER 

DATE: 6/8/95 
Network Environmental, Inc. 

PITOT TRAVERSE DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BlUCK TEST DATE: 6/8/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: DRYER 

SAMPLING STAPF: SCHULTES/SMITH 

RUN NUMBER: 1 • CARBON DIOXIDE: 

STACK DIMENSIONS, in.: 57 by 42 • OXYGEN: 

GAS TEMPERATURE, Deg F: 145 • CARBON MONOXIDE: 

STATIC PRESSURE, in. H20: -.12 PITOT FACTOR: .87 

BAROMETRIC PRESSURE: 29 

POINT VELOCITY PRESSURE, INCHES OF WATER 

PT. LOCATION, PORT 

t INCHES 1 2 3 

1 7.00 0.68 0.70 0.64 

2 21.00 0.52 0.40 0.57 

3 35.00 0.74 0.50 0.57 

·. 
Network Environmental, Xnc. 

ORSAT ANALYSIS DATA 

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/8/95 

COMPANY LOCATION: CORUNNA, MICHIGAN 

SOURCE NAME: DRYER 

SAMPLING STAFF: SCHULTES/SMITH 

DATE OF ANALYSIS: 6/8/95 METHOD: MULTIPOINT INTEGRATED SAMPLE 

PART CARBON DIOXIDE OXYGEN CARBON MONOXIDE 

SMPL CONT RUN 

t t t FINAL INIT. ' FINAL INIT. ' FINAL INIT. ' 

1 1 1 1.6 0.0 1.6 19.3 1.6 17.7 19.3 19.3 0.0 

2 1.6 0.0 1.6 19.3 1.6 17.7 19.3 19.3 0.0 

3 1.6 0.0 1.6 19.3 1.6 17.7 19.3 19.3 0.0 
APPENDIXE 

• 

CALCULATIONS 
Network Environmental, Xnc. 

CALCULATION FORMULAs 

MOISTURE TRAIN CALCULATIONS: 

Ml. BAROMETRIC PRESSURE, inches of Mercury 

H2 • DURATION OF SAMPLE, minutes 

M3 • METER CALIBRATION FACTOR 

M4. AVERAGE METER TEMPERATURE, degrees F 

MS. AVERAGE METER PRESSURE, inches of water 

M6. METER VOLUME, ACTUAL, cubic feet 

M7. METER VOLUME, STP, cubic feet 

530 Ml + .07355 * H5 

M7 = H3 * M6 * ---------- * ------------------ M4 + 460 29.92 

MS. LIQUID VOLUME OF WATER CONDENSED, milliliters 

H9. VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet 

H9 = MB * 0.0474 

MlO. TOTAL GAS SAMPLED, @ STP, cubic feet 

MlO = M7 +H9 

Mll. PERCENT MOISTURE 

H9 

Mll = * 100 

MlO 

EXHAUST GAS CALCULATIONS: 

Gl. STACK DIMENSIONS, inches 

G2. AREA OF STACK, square feet 

3.14159 * (DIA/2)•2 

G2 (ROUND) = --------------------- 144 

WIDTH * LENGTH 

G2 (RECT.) = ---------------- 144 

G3. BAROMETRIC PRESSURE, inches of Mercury 

G4. STATIC PRESSURE IN STACK, inches of water 

G5. STACK GAS TEMPERATURE, degrees F 

G6 • AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED 

G7. PERCENT MOISTURE AT TEST LOCATION 

Pl3 

G7 = ----- * 100 

Pl4 
Network Environmental, Inc. 

CALCULATION FORMULAS CONTIIIUED 

GS. PERCENT MOISTURE BEFORE COLLECTOR 

G9. DRY GAS COMPOSITION, %02, %C02, %CO, %N2 

G10. PERCENT EXCESS AIR AT TEST LOCATION 

%02 - 0.5 * %CO 

G10 = 100 * -----------------------------

.264 * %N2 - %02 + .5 * %CO 

G11. DENSITY, DRY, @STP, lbs./cu. ft . 

• 0827 * %02 + .1137 * %C02 + (%CO + %N2) * .0724 

G11 = --------------------------------------------------

G12. DENSITY, WET, @STP, lbs./cu. ft. 

100 - G7 

100 

G12 = G11 * ---------- + .0465 * 100 

G13. DENSITY, WET, @ STACK CONDITIONS, lbs./cu. ft. 

G7 

100 

530 G3 + .07355 * G4 

G13 = G12 * ---------- * ------------------ G5 + 460 29.92 

G14. MOLECULAR WEIGHT, DRY, lbs./mole 

G14 = G11 * 386.9 

G15. AVERAGE GAS VELOCITY, feet/minute 

1096 

G15 = P5 * G6 * -----------

SQRT(G13) 

G16. STACK GAS FLOW RATE, ACFM 

G16 = G2 * Gl5 

Gl7. STACK GAS FLOW RATE, SCFM 

530 G3 + .07355 * G4 •. Gl7 = Gl6 * ---------- * ------------------ G5 + 460 29.92 

Gl8. STACK GAS FLOW RATE, DRY, DSCFM 

100 - G7 

Gl8 = Gl7 * ---------- 100 
Network Environmental, Inc. 

CALCULATION FORMULAs CONTINUED 

PARTICULATE TRAIN CALCULATIONS: 

Pl. NUMBER OF POINTS SAMPLED 

P2. DURATION OF SAMPLE, minutes 

P3. NOZZLE DIAMETER, inches 

P4. NOZZLE AREA, square feet 

3.14159 * (P3/2)"2 

P4 = --------------------

P5. PITOT CALIBRATION FACTOR 

P6. METER CALIBRATION FACTOR 

144 

P7. AVERAGE FILTER TEMPERATURE, degrees F 

PB. AVERAGE METER TEMPERATURE, degrees F 

P9. AVERAGE METER PRESSURE, inches of water 

PlO. METER VOLUME, ACTUAL, cubic feet 

Pll. METER VOLOME, @ STP, cubic feet 

530 G3 + .07355 * P9 

Pll = PlO * P6 * ---------- * ------------------ PB + 460 29.92 

Pl2. LIQUID VOLUME OF WATER CONDENSED, milliliters 

Pl3. VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet 

Pl3 = Pl2 * 0.0474 

Pl4. TOTAL GAS SAMPLED, @ STP, cubic feet 

Pl4 = Pll + Pl3 

Pl5. WEIGHT OF GAS SAMPLED, DRY, pounds 

Pl5 = Pll * Gll 

Pl6. WEIGHT OF GAS SAMPLED, WET, pounds 

Pl6 = Pl4 * Gl2 

Pl7. PERCENT ISOKINETICS 

Pl7 = 100 * 29.92 * (G5 + 460) * Pl4 

530 * (G3 + .07355 * G4) * P2 * P4 * Gl5 
Network Environmental, Inc. 

CALCULATION FORMlJI.AS CONTINUED 

CONCENTRATION CONVERSION FACTORS: 

P18. 50 % EXCESS AIR, AFER COLLECTOR 

G14 + 18 * G7/(100 - G7) 

P18 = ------------------------------------------------------- .1826 * %N2 - 2.0592 * %02 + G14 + 18 * G7/(100 - G7) 

P19. 50 %EXCESS AIR, BEFORE COLLECTOR 

G14 + 18 * G7/(100 - G7) 

P19 = ------------------------------------------------------- .1826 * %N2 - 2.0592 * %02 + G14 + 18 * G8/(100 - G8) 

P20. MOISTURE BEFORE COLLECTOR 

G14 + 18 * G7/(100 - G7) 

P20 = 

G14 + 18 * G8/(100 - G8) 

PARTICULATE EMISSION CALCULATIONS: 

El. 

E2. 

E3. 

E4. 

TOTAL WEIGHT PARTICULATE COLLECTED, grams 

LBS. PARTICULATE/1000 LBS. GAS, ACTUAL 

1000 . 

E2 = E1 * ----------- 454 * P16 

LBS. PARTICULATE/1000 LBS. GAS, DRY 

E3 = E2 * P20 

LBS. PARTICULATE/ 1000 LBS. GAS, WET, 50% EA 

E4 = E2 * P18 

E5. LBS. PARTICULATE/1000 LBS. GAS, DRY, 50% EA 

E5 = E2 * P19 

E6. GRAINS/DRY STANDARD CUBIC FOOT 

E1 * 7000 * 100 

E6 = ------------------------ 454 * P14 * (100 - G7) 

E7. POUNDS/BOOR 

G17 * G12 * 1000 * E1 * .06 

E7 = ----------------------------- 454 * P16 

E8. POUNDS/MILLION BTU 

E7 

E8 = --------------------- CAPACITY, MM BTU/BR 

/}J/ 
EPA METI:IOD 6C 

AVERAGE GAS CONCENTRATION FORMULA 

Eq. 6C-l 

- c C =(C-C) 103 

gas o (C., -Co) 

Where: 

C = Effiuent gas concentration, dry basis ppm or%. 

p.s • 

C =Average gas concentration indicated by gas analyzer, dry basis ppm or%. 

Co= Average of initial and final system calibration bias check responses for the 

zero gas ppm or %. 

C m =Average of initial and final system calibration bias check responses for the . 

upscale calibration gas ppm or%. 

C.,.= Actual concentration of the upscale gas, ppm or percent 
Date: _ __,c,c....----.:.S_-_<1__::.s-___ _ 

INCOQPOQATED 

("\,·"~ ,'5c.."' e r ,·c. t Clients: 

Pitot Traverse Data Form 

Proj. No.:---------

Plant: __ U..:::::.__,S::._.,;,3~,.-!..._·~· <-"--!:k~-=---C,~.:....'~"'-;:._:"'-_"'-_:_:."'-;:._ _________ ~----------

Source: __ __:Wt,~, __,l~~_,_\ c..:"-'-"';J;--.c.R_.."'-o..:::.-..=._ ____ _ 

'7 / (( 

Stack Size, Inches __ ____:<>~"''------- Barometric Pressure, "Hg __ z_c:;_._0

_o ___ _ 

/ 0 2 ., Gas Temperature, "F ___ ....~ _ __:::: ____ _ -. osStatic Pressure, "H20 ----------

Pitot Tube [] Standard (5r S-Type %0z _______ %C02 --------

3 "'/, 1-.- j:t- Cp - '?1- ""-<> i ( .,.. - - 0 

>,.Veloclty ,'_ - Point . 

.I L. ·::·Velocity ., .. ,,• v lo lty .. -, ... :Velocity - : .·- e c . 

·Location ·f-=- ' ..... Presst.~re ·1-:-:- :·:Pressure ~--: --;: ···:::Pressure 7 :Pressure 

Inches . . . 't: .. .,.,H 0 .. ... ·:'t: ···:>·"H 0 :· ~- .·~H20 "H20 .. 0 . ·. ...... 2 :-;. 0 . ...... 2 0 0 . ll. ... ·c .. , _,. ll. ll. . .. . . ll. .· 

I. s-S 1 I .43 1 -~ 1 1 

5.'.2..-.5 2 .f.. I 2 . --::;. ~ 2 2 

I o. (,~ 3 ,(..~ 3 ·~ b 3 3 

2s-. 3t.f 4 t.o b 4 ,g) 4 4 

3D.:f'j 5 \.D 0 5 .4 s;- 5 5 

3<-\.£{ 

' 6 . 8 2._ I 6 .7'5'"' 6 6 

7 I 7 7 7 

8 I 8 8 8 

9 9 9 9 

10 10 10 11) 

11 11 11 11 

12 112 12 12 

13 13 13 13 

14 14 14 14 

Wall Thickness 1\)f\- . 

Zero Point tJ~ 

Port SizerType I' I 14..,~ 
Date: h - 8 - '1.r INCO~PO~ATED 

Clients: (11,·J.ti,(l,..,_ ~rl~ k. 

Pitot Traverse Data Form 

Proj. No.:---------

u._ s '? (' ; Ll - c " ( (A .,_ "'- "'-- Plant: _ __;::..:;:..::::..,__;D~-'-'""'--'~"--"""'...:::v:...:_~----=~---------------------

Source: __ J)'-"'I::...:_r_:i1-e_"'--r __________ _ Staff: ----"'S=c-__,(=.J'-.!.~=e."'-s ___:.+__::Si::..c:Ml.!.;+.!...L....~---- s-=; I{ V '-{ L (( Stack Size, Inches ---=-_..:__,.t;l"-::,_..,;_:;.=----- Barametric Pressure, "Hg _ __::::;;:l:......:.<f_._o_v__ _ 

I '{S'D Gas Temperature, •F ___ .:.._--'------ l'Z... Static Pressure, "H20 ----------

Pita! Tube [] Standard ~ S-Type %02 ---------- %C02 ----------

Foint 

Location 

Inches 

/.oo 

Z.l.oD 

55'. 0 6 

Wall Thickness 

Zero Point 

Port SizerType 

~ I Cp = • '81- . - ._ 

l ·- ,"\VeloCity _ 2_ 

~ 0 

c. 

1 

2 

3 

I 4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

Nit 

!O rt 

" ..... Pressure 1--t:: 

'"H 0 . ·· -. -. - 2 . , __ - 0 

c. 

1 

I 2 

3 

I 4 

I 5 

I 6 

7 

8 

I 9 

10 

11 

13 

' 

31

'Porf-

-:Velocity - _ 3 '-._..·,v'elocttY -· -·Pressure -: · ;-:-:- ·Pressure ., .,.H 0 • -- t:: - :,_ H 0 -··- 2. -- 0 - . 2. - -- c. ---. .- .. 

9-0 

2 

, S'D 3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

-

-~ 0 

c. 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

Velocity 

-Pressure 

"H20 
Pitot tube calibration data. 

P11or 1uas: roel'lnFICATioN NuMaE.~: __ lf'--... 2~--- oAr<: /J}; If? . A?/? ;~ 

CAL!ER~TEOEY: __ ~I~'IL----------------------

RUN NO. I 

t I 

2 I 

3 I 

RU"' NO. 

t 

.2 

-,.··SlOE CAL!!;;AiiO!I 

il F::::! tl. ~ (;) 

r c,rll 

=HzO =HzO 

(in. HzOI (in. HzOI 

. ':J..L/0 I < J;r;- I. f&LJ I 

,;] 'I 0 I .3/D 1-6'7/ I 

.J..vo I ~ 3; ') J.~,cr I -

··a·· SlOE C.!LI~;;:.TIO!'I 

c.;::;::: 

""" HzO 

(in. HzOI 

J 

c.~(~ 

c:.-, HzG 

lin. Hzul . C;:fll 

.. 

CEVIAriO:'! 

C;:(11 • t.,L~I 

I(';?~ 

. Ov c::; 

~ 1:::>2._ 

0€¥1.! 11011 

C;;( 1i · C;:ISI 

0 ( 

I[) 0 ( 

I 

:::I C;:iii·C,I.! OFi Sll 

1 P.VERAGE OEVl-"riOM ''' (;1 p;; Sl • ..:...... _______ -MUST SE <:;a.Qt 

1 c., !SloE ;:.J -c., !s1a: s1/--Musr se <a.at 

.7;7 
Pitot tube calibration data. 

PITOiiU!!E ICE!HlFIC.:.IlON HI.!Mo~iL __ Fl:!.· __ · ___ O~ri:: II h/<?.:1 

Oc/ 1 1 C~lloR~7ECBY:_4f\~,~~,L~----------------------------~-------

RUN HO. 

1 

2 

3 

fl[Jiollo!Q. 

.2 

J 

C,. P,::! 

=HzO 

(in. HzO I 

c9.. s7S I 

5"1 

c..~~= 

""' H zO 

(i". HzOI 

I 

I 

ll.p[,l 

=HzO 

(i.,_ HzOI 

' 

,3o7S"" 

c_ 1s1a: 1.1 

' 

c.~~<.) 

e.-, HzO 

(in. Hzul 

C:;; (SIO E Bl 

3 

OEVl.il. iTO~ 

c:,(,) . C;:IAI 

' DS 

.DD f{ 

CEVI.:. 1!011 

c.r,l. c,<,l 

DD 

VD 

:::I c~l·l·Cpl-"' OR all 

1 P.IIERACEOEIII..lTIOM • <J(AQRBI • -~USTSE<;;O.Ol 

3 

I "57 

•D03 
Pitot tube calibration data. 

P!TOT TUBE !OENT!FICATlON NU'-ISER: _7f- _ _!.../..£::'cJ--_:....::::__ ___ OATE: tt/~hj CAI.lBR-"TEo SY: f,.:(<... I 

RUN .'10. 

2 

J 

RU~j NO. 

z 

J 

-A·· SlOE CALIBiUTIO!.I 

~ P:::! 

c:-:1 HzO 

(in.HzOl 

11,:,::: 

c"' H zO 

(in. HzOI 

ll P(,) 

c"' HzO 

(ire HzOl 

c, (SlOE AI 

ll ::(!.! 

c..,HzO 

(in. HzOl 

Cp (SlOE Bl 

J 

0 EV!ATI 0~ 

C;>(>l · C;~(Al 

OoVIA TIO!I 

c.c.1. c.,r31 

::: j c,hl· cp(A oR all 

AVERAGE OEVIATION 1 • ''(A OR Bl • ..:___ _______ -MUST BE ~0.01 

J 

r C10 (SlOE A)-Cp (SlOE Bl/--MUST BE <::0.01 

r:J,/7 
tNCO;;~CIO..O.TtC 

Pitot Traverse Data Form 

Clients: ---------

Proj. No.:--------

Plant: -~\...)...) _,__ • ....,5~----p.t=....:...;.!....:, ~::::.....=.-----------------

Source: _:_1f..,.;o~iL,..., J:::,k..L-1 IL.Ca~O-LJ.J...u ±...J.....t::l-e.f=::::..L.. __ _ ,, 

Staff: c~ jt=:"f)ef!1~ 

Stack Size, Barometric Pressure, "Hg :J ?. (:, <:::> Inches _::,3L....!'=t _______ _ 

Gas Temperature, •F ,.,J,~q:J.....:5"L-. ___ ---!./....!~"=5=1...J 

Pitot T:Jbe 0 Standard ~ S-Type 

4 I - . t' 7 . . : . . . . : 

Point .. J •. ,'.:-'· Ve loclty · . ~ . ::Velocity 

Location - ·Pressure :·.··Pressure 

Inches 't: ~ .. H20 't: ·.-·, .. H20 0 .. ... 0 

c. c. . .. 

1 . 7l. 1 I .T~ 1 . .?v 

$_bq 2 .'·1 I I 2 y {) ' 

1!. 5 L\ 3 lj(/ 3 . '-/7 l 

.l1.4L 4 L/1 I 4 ~I 

~'3-'l,l 5 . l/ 7 5 5-1 

.lll' •. 

-:;720 6 6 'c;-, T 

7 7 

8 8 

9 9 

10 10 

11 11 .. 

12 12 

13 13 

14 14 

Wall Thickness 

Zero Point 

Port SizefType \ 

.. '· , 

Static Pressure, "H20 __ ___,_ •....!3::::..S~2!....-----

%0, ------ %C02 ------

. 

. "' 

I--

't: 

0 

c. 

1 

2 

3 

41 

5 

6 

I ,7 

8 

9 

10 

11 

1.2 

13 

14 

. :·:·Velocity 

·· :. Pressure 

' 

·< ·~H20 . . "' . 

I 

I 

: 

1 

N 

Velocity 

~ . Pressure 

't: 

0 "H20 

c. 

1 

2 

3 I 

i 

I 

4 

·- 5 

6 

7 

8 

9 

10 

11 

12 

13 

14 
Project 1: 

Plant ~ 5. '5, r .. J-, 

Source '# Jl. f-J: E:) a,u d- Staff~/~~ 

• Sample #---r-=1 ;;...._--:-- Filter Set# " '1 Barometric Press .;:2? £ 0 

Nozzle# S I ~b · '? P { Primary Filter# J:>H- -:;.. 5 & lnftiaJ Gas Read _/6 '1. c2 ?<{ 

· Rate Meter# 

1 

Secondal)' Filter# JSI(--:;:-S'(o Clock Meter Start 9: V..?.. 

Control Box # I Type Train. =:;- Time Meter Start _ _:::0:::;...._ __ _ 

C on denser So X # I Mls . 2 H 0 C.:>nd l-gD Time Met e p r Sto r 

vd= /. oooc- P,M_ ::o .~ 7 #_.1 

Vel I Ve~uri Pump Meter Temp Stack Box Press Gas Meter Vac. "F Temp Temp _1_ Port Poirt "H20 "H20 Reading "Hg In Out •F "F Gas Bag# 

2 (p Lf? ~.53 r; (/, 3 J._ .3_ '/0 '70 ,;l.Jj6 o257 Dl)'er # js,.- ~-

s- .V'tf ).~ ( hc;,c;q 96 3.5" '10 ).qh OZ5'6 Notes 

j 

~ ,~) ?>. b r /tJY. 7 I 7.s; fJ Cfo ,2q~ )._5}7 ::;:;, "r/i ,J!. 

} . v~r ;3.2l( !??. 6 ~ 3.-;- rv CJo c9. 1Cf ?.~ ~c..k \ ( 2.d:> c,,< .. J-

~ 2.._ ,t.f_o Qq~ ;q~_Js- 3.{'" fc; qD SDD 

\ CJ. 00-~ .~L\ 

;, 

J.sL ;qf, 7:2 7 3 ?.I. qr c2<qS' (5""'>" e ;s" 11 ~ 

I':? ?; .; ~1. Joa 3.j q~ q( ;-r;Y . 

l (, . y s- ar,;z 

l/f.? 3.~0 ?0~-72 ~-5""1Lf£ 19 J 24? ' J-;_J) ) :2.5'? t. ... -.lk 

~ .Lll 7., st; ) (3.5"~ }.) 9? fq_j 2_11 29' ,_z j 

) 0 .ooatf!, v .~s ;.33 1

d 18'.c?3 ).j' 9Y 12.., _]c5D :J$1, e .s-1( ~ 1.~3 3.10 ).)._3. "'}___). ?.c; q1 9"2 5au I~E7 ~ 

~I 

' 3 ' 

EAI)- \ .;)) :2_. L/c( 2'2!.8? /a /J 13 joD 2.5b .,.. 'fe.>t 

lo:<.fs -

$ 
Plant -~~{):-"-'-~~-=---'\S_.::.;_....;..r',:_' J.r_------------.,.--r--

Source _il=~;l~k~~ \""~....:C.::...i-)I.::_::A~tr..::::U.S.:::.l.T" _______ Staff C~ ~~~ 

• Sample# FiHer Set# )., L\ Barometric Press d !f. -{ O 

Nozzle# "1\ I IO ,3 I) <"' Primary Filter# PH- 7- 5S lr.itial Gas Read ~c:f'. ::J...b d-' 

· Rate Meter# I Secor:dary Filter# '3 If - -:;... ?'3Clcd< Meter Start II ~0) 

Control Box # / TYJ:<l Train 5' Time Meter Start __ 0=-----

Condenser Box # I Mls. H2

0 Concl. \ ~ Time Meter Stop _ ___._/ __ _ 

V d ;::- ), CJ 6[) c_;-

1

i:?.j,y/ # j_ C • cJ/ , 

Vel f P Pump Meter Temp Stack Box ') 

Press Venturi Gas Meter Vac. • F Temp Temp """-

Port Pcirt "H20 "HzO Reading "Hg In Out •F °F Gas Bag# 

I G ,l_fh ).(t:f d-.5'S.ro :~ 1 '! 3 77 2.'-!'-5 d.t;Lf Dryer#JL/ ~ 

) .~7 } <..<.- J-2 ?-ocr-. 3 C(J 1 )__ ;). q L/ 'Jsl.- Notes L 
lNCORPO~ATED 

U. ,'B.RrCk, 

Pro;ec: 1: 

Plant -~f.::.......-L.~~:....L.!..:; c~k==----~,.:-H.::..::c7~~~~~~~,.:._..1,..2~:;,..._---,-----,--l Source -----'"UJ-~---'~---l.(l""-•!::.u.J..J...' ..:..:.l~;;;;.:....f-_......:(.._F~(g;l..J1.a6..:.'d=-=:.._:....J:--- Staff ~~ILL:.~~~~~q 

1 FO I?: I • 

• Sample# "4- · ~~Iter Set# _.(..:;,();,..:A-~.--- Barometric Press _:2=::-;fz.....;. • ...._6.:..:...0""---

5 1

Nozzle# --=+/"-=Ia.__ 1 ' ___ ' :S I ::J.. ;:;- P . nmary Fill er # ----- Initial' Gas Read ~0' "') 'o, · 5 9. ....:> <-

Rate Meter#---'-( ___ Sea:mdary FiHer # ---- Clccl< Meter Start-..:....I...:.Lf...:..~...:../...:.:__ __ 

Control Box # I Type Train -;t/ou,.. r' rH Time Meter Start ___ 0=----

Condenser Box # I MIS. H2

0 Con<:!. Time Meter Stop I 

\I J~ (oooc:;- Plv:t #j:J- ?/ 

I 

Vel p Pump Meter Temp Stack Box Press Venturi I Gas Meter Vac. •F Tamp Temp Port Pcirl "H20 "H2o Reading "Hg In Out •F "F Gas Bag# 

2 (, ~.f)( 3.'13 2 91. c:;c;- -~·5 91 qr :;;;qg 

"?..<': Dryer# 7- '10 'l'e -;:>q~ 

s 6.C:2. 3/{q ;<,1 (=.. ?-I :;;.s q3 <Jo ~, 

-"7'~~ 

lz.i4A-+l' :~es 

5'2 "3'.{1&. ~-~ "'9" ::r/'1 i f,afl 'f 0.~ <. . .> '7'0 30 ( 

3 {),<(6 ~-~ 3t;L{. ?-(, ~."'!) '12. J..ea ... ) .. ,_ C(6 :3~0 Lhe~ ). .2. (),<;o 2.~'3 "<·S"" Cf<.{ 9o O,o:Joffi 3o cr. to 29g 

~ y-:;~ !.<."" 

I ~- -:2,<( /, ~1 3! 3. 3fo"7 2.5 C{3 '1o ~ ....... e 

2'79 .€=f'~ ~ 

I (, o/-l:::r "3 .IS 31 s. I ~S' 9-z ?o '29$" ;;z; ,.zc.Q l' LL 

s- {).~6 3, /0 323L>~ 2.~ Cf'S"' '.?o 2.'19 c...},z~ 

L.f {) . <{ "§ 'J. 2-:2, 3'23. 0 2.5' C{1- '76 3oCl 

0, oca;; ~ ~/(J d .7t 

3 (). Lf.t- "3.l=f 3 32.. 'to .:z~ 1-Cf<J q, '30~ -

2 6,1fj 3 /h. S3)3,3c, 3.D !6o q'2_ ;<'T% 

I 6J62... :2. I ::t: '342. i"9:3 :2..0 !oo 9:Z jJ...q-::j- ~t7 -

<:5· I;;: ·~ i" 

I f 
I Da1e: 

Pro]'tct 1: 

Plant --~U=:::...:.·-=5~. ~'12:::..!.r...:··...:'-':::::k~-------------:----,----,-­

source _~:._· '-"'d-"::;.....C.k.::::..i:..L/~"' ---.:E:::::..!y,.:..!:h.!:..>~~d-:;:....:._______ Staff 0Ji!

1

1£(}P a£18 ef./-

· Sample # _ __:2:::::-....:...F~O=--- Fitter Sat# NA- 8arometr.c Press c2. J>, 6 0 

Nozzle # • 31 2. S" Primary Filter# Initial Gas Read 3<{ 2 , ~ ( <c 

Rate Meter# I Secondary Filter# Cleek Meter Start I G : Cl S: 

Control Box # I Type Train -;;J/our/ck> Time MeterStart _ __:O;;;;:_ ___ _ 

Condenser Box # ......~-1 ___ Mls. H20 Cond. ----- Time Meter Stop -~~-----

\I A- /. oou-=:;- o/. M .:if /;2 ~ . rP / 

Vel II p Pump Meter Temp Stack Box 2 Press Venturi Gas Meter Vac. •F Temp Temp 

Port Poirt "HzO "H?O Reading "Hg In 1 Out •F OF Gas Bag# 

I c;: CJ .&.('1' :3.1'2 31-R. fo~ l.2.c;- 43 9?-. 2.9<;- . Dryer# 5 

"'-< <::?'7, "'1'2.. -:2..."T~ 

~I o .56 3. 38 :352' C..4 z.~ c;-=t- '12. 3:::>6 Notes 

r lo.'(cr 3..3( 3-s--::r. ~s- '2S (60 qs ~0 :In·,-licJ 

3 I".~R' "3.2S ?/'"?. 5gs R'·:s- /6 ( '13 3~o j_ec.kA_ 

cAe l!. 

2.. () '43 2.'12. 3~ -r 3s- 2.5' lot 9'{ '29~ o,~/7 ~I"\ 

( lo.3s :<.38 3-;ti.53F? 2. . .$ ICJ/ C(<{ 2..9G 

e ~_!;;til b 

:2_ t, 0.5( '3,<..(7- 3":f.(,, 6 ;;:: .~ 1'9'1 Cf'L( ~'?? ';2:-zcn L d. 

c; "~ I ({ 5;' I~ .s(p 3'3<J.s-t 2.-? /C 2._ 9> ..3"01 ~<:u4_ 

O.e.a>j:f ~ q (J. {-r=r- '3.[q I 3Sb.4/~ 2.s- /6'2. ~ 3oo @;6 (/ f 

s ~ 1{9. 57 ~ .'f~ -sq I. S:Lf 3.0 /1)3 '7:) 2qq -

I 6,3'6 2. S7 3q{;, I <-t<-

':2. • :? £"r/) ".2... ~ /6 "'!:, 1~ 2.<7 'ff' 

1~.2"a / 

!q5 ~-r¢ [ f.ct! L/()(J '0~ ( 2,0 /t!:L 29-=1-- ;~:~ I 
........... ----~ ...... ~--~, ~T ~ ·····m l :::::::: :~a. ET JrtrO 

:::::: ..... :::: ENVIRONMENTAL (;: __ .. ~.......... INCO.QPO.QATEO 

~.!!!!•'"' 

Pitot Traverse Data Form 

Date: ? lz /t; s= 

I I 

Clients: f'rll c ~; j CA. .., g,. ,' c K 

Proj. No.:--------

Plant: ___:U::..::...:=.S____!{)L..:...r-!.~..=C.::....k~_L=-o_r_"-~""-""'..:..!c.._=---------------------

Source: _,K~· f'-Ln"'--~--"2=--.......r..:c~...:Yl-'-'=le.-'-'-/- ______ _ 

/l'\/1 '7\,.r+ Stack Size, Inches __ ::!__,__,.,4._____.,.2::w.:::~""-'----

Staff: $c..~ !te.S f 

Barometric Pressure, "Hg -"-~'-'8'--'.-"b"--"'O ___ _ 

rLj"l~ Gas Temperature, °F ---"'L~~r ___ _ Static Pressure, "H20 -----~'--.0_o ___ _ 

Pitot Tube 0 Standard !$) S· Type %0, ------ %C02 ------- * <i c CJ:r , p :;. I 

l . : 

?-.- . .: . 

Point . ;c:•veloclty . ::Velocity : - ·. cveloclty Velocity . . 

Location - ~ : . Pressure ·· f-- ··-·-Pressure ·· · -r . :Pressure 7 . Pressure 

Inches :"H:O ., t: 

c ·. ·-.. ·.· "H 0 ·· ·.c :~H:O "H20 ., ; ~' c ·'. 2 . .. c ' c 

t1. - c.. .. - ·. - c.. . ...• '. c.. 

/. ~if 1 J y 1- 1 'L{3 1 1 

(,. I) 2 'Lf6" 2 I L{ 2- 2 2 

ll,.i{l 3 .ti? 3 .3~ 3 3 

2 q. )lo 4 .~q I 4 ,JJ" 4 4 

)j, 1l 5 .':)\ I 5 1..-s- 5 5 - ·-. - - ~ _.!.- 4 o. 15 r;------:3-b -- . 

6 .E.~ 6 • I '..:· 

I 

7 7 7 ... I . 

8 ( I 8 8 8 

9· 'I 9 9 9 

10 10 10 10 

11 111 11 11 

112 12 12 12 

13 13 13 13 

14 114 14 14 

Wall Thickness N?; ~ 

1 Zero Point 51/ 

Port Size/Type 3 ~It u~ ~l--~3 
I

Ciient: M B ·<-~ /5 "l... ,.;.,_ k 

Projec! t: 

· Sample # ----- Fitter ~t # _ __,_;V-'-,4-'---- Bare metric Press ~2:::::-"8;...;.·-~a&..:::O;..__ __ 

Nozzle # __ '_._H..:........:-'-'- 0 =?S''-- Primarj Fitter# _......;H_It-'--- Initial Gas Read 0 8 ~ -'-f T= 

tV 11- _....=:::...,:u~~-'---

. "Rate Meter #-___;.;,N'~.o;.'--- SeconearJ Filter# Clcd<. Meter Start-~h.>...:.._,_l.;;;..O __ _ 

Contrcl Box # J,q }.N 4 Type Train F/:; v.,. /Je Time Meter Start ----''""0.,__ __ 

Condenser Box # /114- Mls H 0 Cond N'f!r Time Meter Stop \[ . 2 

Y,..) ~ 1.o3 1s;";!? ~CP=. 87- ~ 

Vel p Pump ~eterTemp Stack Box }~ Press Venturi Gas Meter Vac. •F T9f'11' Temp 

Port Point "HzO "H2 o Heading "Hg In Out •F •F Gas Bag# 

I I ~ I , Lf-z._ /12- e g~. 'lo 3 q:;t qcz Ll/3_ iJ ·11 Dryer# }3 J ' /f./ C/ /II I I 

) l.l{) .Cfj t6SS -~2-- ~ 11- 9'6 bs-o Nit Not~ 

~ I I 3~ ,g~ £,t[D ·f..r ~t ~'1 --- 3 05'i ('/If z .... -1-t~ 

3 .S3 ,12! R 9 2 . ~4 > ~:;.- 1f b4Z.. tilt- ~~ 

(..#UI( 

;z .z.c- . s-tf g~L(' ~3 z_ 18 CZb 0 ~I rV~ O,oo~ 

I "'r*J 

I ,1Jt' ~~- B 1? .53 '£..., qB 0<;"" &~I rJJot 

z. ? I . ~C) . tj.) ~1i. oj 5 q{, 1t s-sy N;f 

s- tJ3 ,=tt.J CJD/.lf/ :-; qq i? c.zt- ,V)f- I 

~ I ~1 . :r I Cfo7~rl ~ to1 _?t-1 ~30 ('14 '. 

3 3Y .1- cl 10 h. OLf ; I Dl- 9h ~oc; riA . 

L. I (z_cf ,5~ qog .1 ~ ~ fo) ~l A~ j'1)fT' 

I ~~5 ,.S~ ·q(o.L/0 s IDq ik bSD {'/If E~A~ 

~+ 

l ): :t1 

!"-.... ~ ~ 

I -:--·, \ 

I . 

. ~;1 rj \' 
[C;oont frJtC..W. f?Jt(W {3/!.lt:.~ 

I Project 1: 

Plant ~U~S__;;,G~r_;_i;;:;.v.~...:)<:::..___~-:----------~---- Source _JI:-,..;;___.?::......---..:k.:......:....::i L::....:rJ_;__~r.....::."'-.:..;(~~:....+:_ _____ Staff <;~ (~ { C:...,-1,· I( 

Sample#_. • 2 __ Finer Set# _..~....t1:....:..:4:..._ __ 

Nozzle# -.:8 ~. 'o9 g;s Primary Filter# IV# 

A WJ'f · Rate Meter# _._!..!..,1'/.:..J.--r __ Secondary Finer#--'-~-:--

Control Sox #- /V 11 Type Train F / V"-" '·J<? 

Barometric Press Z.«i.C.o 

Initial Gas Read i.W., 7 l 

Clock Meter Start l'; 0~ I 

Time Meter Start 0 

C ndenser Sox # f'Y If Mls H 0 Cond IV J4- 0 . 2 I I 

VJ=I·. 7~2?- Jtil CP.:. f3 ?-

Time Meter Stop 

Vel p Pump Meter Temp Stack Sox 'Z.. Press Venturi Gas Meter Vac. OF Temp Temp 

Port Poirt "H20 "Hz._O Reading "Hg In 1 Out •F •F Gas Bag# 

1).. (p 17~ 2. o9 'fli.JZ ~ qt_. t;c, f-t'{ NA Dryer# 'i 

• 

~ .31 2.03 qt8.13 :} lq-:J- lS"' t~ /JP,. Notes 

~ ,)& r.q ~ 0l/.{1 f 11 15" tsu tV If ::r-..... , ·r~ ( 

~ .Zj- ! .~ b 12:;-. I lJ i'l rn 1s- (,. ~ 9 NJ f.LA;, {C 

C't-1 ~ t )(. 

1 . ?-5 r. Y~ qlg,z_,~ ~ I a J.... 1~ (,_ ~0 !VA 0. oo~D(£; 

\ { ')._ ~ /. <ft q~).~-!7 5/ /D) t:;(, q1JI Nft- ;sit 

1-1_9 

I. .... _ {, t4L 'l-b~ o; 3 5""". ;1. '1 v: 11 7] <J8~ N/1-

I~ . <1L 2-2~ i) q.ts -r (o I 7~ C'IC( NffI ~ ·~S 2.);} 'rn.tB 1- tO) tt~ &f5 piA5 .) ~ 1J6Y 9 L(-q. • q 7-· 1" /D~ q~ ~41 !'lit 

'& .2§' /. t£ CJs-o .n t--1 ~~ ttl '5~0 rJfr 

I ·1r; !-)~ cts--~. q D ~ JO~ tit- &<-1 ( yJfr 

Sv..d 

I I ~sl---

/7-:;6 
// 1::

...

...

~

\ ,.

..

Calibration Meter ldenlilicallon: 1 Yds. · 6 0 0 ·

Date: S'- f:J'- c;,s- 

Meter Box ldenlilicalion: :1 Barometric Pressure (Pb): P. 9. I!} 

~ ~ ~ • 

i f!{ ! MiJcii ·••···•·······••• .• r.·.·< .. >. ••·21i,6i1t.t6W G·~;~;•••••·~·6~•· 1 • .. Temperature ... · I:_.· >·. iii•'. 

[·········>·· }··········· 

C TL Calibration Meter Box Calibration ortl!ce .•... Mct(!t << r,let or.} >,MI,!ter · Motor . i _Meter I< .· · ..Reatltno 

1 

?.as voturn? 

1

Gar1.votume Averaoe. ~verage Pressur~ I•···········, ' (A II)~ (V du ) .·.• Vd) ····•·•••·. 

··············~ 

~·) •. ·.··· . .~~d):·} 

••. (Ap) I (m ' 

. ..·.· .. ·.•·.·.· 

lnJt

2o .·····</it3 i i . 3 . ·.·. ·. · .. · .. II · In 112 6\ • .. F • .. >··.·· .. ·. . .. 

. ·, ... ,. . .. . 

Stop /.0 l(536.Jl I o 5./ o5 {,(,.<'_;- :J3.0 . -r ro 

9 Start I, o ~I') 33.251- /0).00 &ro .) 7-D, 0 'Lif Average I 0 :;-. oztp '). oz__5 H5 -rt.s- 'L/7) 

Stop 't·() L 15' t)').<oz 1. 113.~0 (,~.'( J-'0.0 .v, 1 Start )_,b tf { .3'13-ST)l /0~.32-l._ (o~ .) "fl. 0 '0!1 Average 2.0 5'1 11 

5.~/5 

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