l 

# A-9g-3o ; 

# r**Ji~D-t6CJ** Report ofan... ' 

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# - 

# Emission Study

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# .. performed for... 

# I. I. 

# Michigan Division . .. 

# l. 

# U.S. Brick l. 

# Corunna, Michigan 

# L on 

# L

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# Kiln #1 L L March 29, 1995 

# L L 010.07 

# L.

I 

# L 

# Network Environmental, Inc. L 

# Grand Rapids, MI l_ 

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Network Environmental, Inc. p.o. Box·202l Grand Rapids, MJ: 49501 

### SOURCE EMISSION TESTING ' 

### at MICHIGAN OJ:Vl:SION, t1.S. BRICK CORUNNA, MICHIGAN ·

**~-** lULN tl SCRt1BBER--EX1!At1ST

- ·- DATE: -3-129/95



# --

**~'.**

### TABLE OF CONTENTS

L Introduction 

# rr. Presentation ofResults 

### ll.l Sulfur Dioxide (S02) Emission Results 

# m. Discussion ofResults 

### - IV. Source Description 

## v. SamplingandAnalytical ProtoCol



### -
Appenc:li_ces 

# l_ Exhaust Gas Parameters SO2 Analyzer Output & CalibrationData 

# L S02 Analyzer Specifications & Gas Certifications Field Data 

# ! Calculations Raw Data

l .



# L. /-

**~** 

# - _--,c__ **~** -- .1



### - 2 2 

### 3 3



# - A B 

# -. c D

**~** E F

_,

# _______________I. 

### I I. INTRODUCTION NetworkEnvironmental, Inc. 

### was retained by theMichiganDivision ofU.S. Brick in Corunna, Michigan, toperforman emission studyon the exhaust oftheir

### Kiln #1. Thepurpose ofthe study

### was to document the sulfur dioxide (S02) emissions from the 

### Kiln #1 exhaust in order to meet the testingrequirements ofMDNR Air Permit No. 902·91. The study 

### was performed on

### March 29, 1995 by Bertram

### J. Smith and Vincent G. Schultes ofNetwork Environmental, Inc.. The testing

### was performed in accordance with U.S. EPAReference Method 6C for S02• In addition, the exhaust 

### gas parameters (air flow rate, temperature, moisture, and density) were . -, determined in accordancewith U.S. EPAReferenceMethods 1 through4.·Assisting inthestudywas

### Mr.

**~~** Bob Barranti ofthe Michigan Division ofU.S. Brick.

1ll. 

### PRESENTATION OF RESULTS

ll.1 

### TABLE 1 

### SULFUR DIOXIDE (S02) 

### EMISSION RESULTS KILN #1 EXHAUST

. 

### MICillGAN DMSION • U.S. BRICK CORUNNA, MICillGAN MARCH 29, 1995 Air Flow Rate Concentration 

### Mass Emission Rate Sample Time DSCFM PPM 

## - LbS/Hr 1 8:22-9:22 13,681 346.90 46.99 2 9:34-10:34 13,891 351.57 48.36 3 10:47·11:47 13,756 369.29 - 50.30 

### AVERAGE 13,776 

### 355.92 48.55 

# l .


# ,. !

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# [_ 

# l

L. I L. ill. 

### DISCUSSION OF RESULTS The results ofthe sulfur dioxide (SO,) emission sampling are summarized in Table 1 (Section II.l).. ill.1 SO, Emission Concentrations· The SO, concentrations were 346.90 parts 

### permillion on a dry basis 

### (PPM) for sample one, 351.57 PPM for sample two, and 369.29 PPM.for sample three. The average ofthe three samples collected was 355.92 PPM. m.2 SO, Mass Emission Rates •The SO, 

### Mass Emission Rates were 46.99 Lbs/Hr for sample one, 48.36 Lbs!Hr for sample two, and 50.30 Lbs!Hr for sample three. Theaverage ofthe three samples collected was 48.55 Lbs!Hr.

IV. SOURCE DESCRIPTION The source tested was 

### the exhaust of

### Kiln # 

### 1. The 

### kiln is gas 

### fired. The exhaust from the k;ln passes . through an emission control systemconsisting ofa cooler followed by a 

### mixing chamber and

**th~n** through a baghouse priorto exhaustingto atmospherethroughtheexhaust stack. 

### Limeis 

### sprayed intothesystem between the cooler and the mixing 

### chamber. On 3/29/95 CopperBaybricks were fired They weigh onanaverage4.lllbsperbrick, Dry andthere are 11,120 bricks per car (equates to 45,703.2 lbs per car). There were also 

### 2,688, Dry 'real' bricks per car at a weight of0.69 lb per 'real' brick (equates to 1,854.7 lbs per car). The total weight ofe8ch car is 

### approximately

**~7,557.9** 

### lbs per car. The 

### kiln speed during the testing was 

### 12 cars per day. The charge tin2es for 3/29/95 were as follows: 01:40, 03:40, 05:40, 09:40, 11:40, 13:40, 15:40, 17:40, 19:40, 21:40 and 23:40. V. SAMPLING AND ANALYTICAL PROTOCOL V.1 SulfurDioxide The SO,determinations wereperformedinaccordance withU.S. EPAReferenceMethod 6C. APSC· 302 portable stack gas 

### analyzer 

### was used 

### to monitor the 

### Kiln # 

### 1 exhaust. Aheated teflon sample 3 

### -·line was used to transport the exhaust gases from the stack to a gas conditioner to remove moisture and reduce the temperature. From the gas conditioner the stackgases were passed to theanalyzer. The analyzer produces instantaneous readouts ofthe 

### 802 concentrations (PPM). The analyzer was calibrated by direct injection prior to the testing. A span gas of857.3 PPM was used to establish the initial instrument calibration. Calibration gases of244.0 and 392.9 PPMwere used to determine the calibration error ofthe analyzer. The sampling system (from the back ofthe stack probe to the analyzer) was injected using the 392.9 PPM calibration gas to determine the system bias. After each sample, a system zero and system injection of392.9 PPM was performedto establish system drift and system bias during the test period. All calibration gases used were EPA Protocol 1 Certified. The analyzer was calibrated to the output ofthe data acquisition system (DAS) used to collect the data. A strip chart recorder was also used to record the data as a backup to the DAS. Three (3) samples were collected from the 

### Kiln #1 exhaust. Each sample was sixty (60) IIiinutes in duration. The DAS output, strip chart recorder data, and calibration data can be found in APpendix B. The 

### 802 analyzer specifications and calibration gas certifications can be found in Appendix C. V.3 Exhaust Gas Parameters The exhaust gas parameters (air flow rate, temperature, moisture, anddensity) were determined in conjunction with the other sampling by employing U.S. EPA Reference Methods 1 through 4. A velocity traverse was performed during each 

### 802 sample. All the quality assurance and quality control procedures listed in the methods were incorporated in the sampling and analysis.-

This report was prepared by: Thisreportwas reviewedby: 

# f?!::C¥

**~~** David D. Engelhardt Project Manager Vice President

4

## I 

# I i: .



# . L
I 

### L_ 

# I I

- 

### I._ 

# L I l_ 

# L l [, 

# L

I 

## L_ 

## l_. 

# L L L APP.ENDIXA EXHAUST GAS PARAMETERS ·

### ,-

r· I r . I 

# ,-

Network Environmental, Inc. P.O. Box 2021 Grand Rapids, JU 49501 

### SOURCE EMISSION TESTING at MJ:CBIGAN DJ:Vl:SION, U.S. BIUCK CORUNNA, MICHIGAN !ULN tl SCRUBBER EXI!AIJST ( 1) DATE: 3/29/95r- '.



### I Network Environmental, Inc. STJMMARY OF EXIIAUST GAS PARAMETERS
COMPANY NAME: KICBIGAN DIVISION, U.S. BIUCK COMPANY LOCATION: CORUNNA, KICBIGAN SOURCE NAME: KILN #1 SCRUBBER EXHAUST ( 1) SAMPLING STAFF: SMITB\SCBULTES SAMPLE NTJMBER G1. STACK RADIUS, inches G2. AREA OF STACK, sq. ft. G3. BAROMETIUC PRESSURE, in. BG. G4. STATIC PRESSURE IN STACK, in. B20 G5. STACK GAS TEMPERATURE, deq. F G6 • AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: \ OXYGEN \ CARBON DIOXIDE \ CARBON MONOXIDE \ NITROGEN G10. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: Gll. DRY, @ STP, lbs./cu.ft. G12. WET, @ STP, lba./cu.ft. G13. WET, @ STACK CONDITIONS, lbs./cu.ft. G14. MOLECULAR WEIGHT, DRY, @ STP, lba./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. Gl7. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM STANDARD CONDITIONS, DRY SCFM TEST DATE: 3/29/95

1 19.5 8.30 29.00 0.49- 325 0.664

7.53 0.00 15.07

3.40 0.00 81.53

0.0754 0.0732 0.0478

29.16

2729 22,637 14,795 13,681


## IINetwork Environmental, Inc. PITOT TRAVERSE DATA
COMPANY NAME: MICHIGAN DIVISION, 0.S. BRICK TEST DATE: 3/29/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN U SCRUBBER EXBAOST ( 1) SAMPLING STAFF: SMITH\SCBOLTES RON NUMBER: 1 ' CARBON DIOXIDE: STACK RADIOS, in.: 19.5 ' OXYGEN: GAS TEMPERATURE, Deg F: 325 ' CARBON MONOXIDE: STATIC PRESSURE, in. H20: -.49 PITOT FACTOR: .82 BAROMETRIC PRESSURE: 29 ' POINT VELOCITY PRESSURE, INCHES OF WATER P'l.'. LOCATION, PORT

t INCHES 1 2 1 1.71 0.32 0.31 2 5.69 0.47 0.48 3 11.54 0.50 0.50 4 27.45 0.48 0.48 5 3'3.30 0.47 0.45 6 37.28 0.44 0.42



### j)**,~­**

**,~**

**,~** . 

### '

Network Environmental, Inc. P.O. Box 2021 Grand Rapids, HI 49501 

### SOURCE EMISSION TESTING at MICHIGAN DIVJ:SION, U.S. BIUCK CORUNNA, MICHIGAN K:ILN U SCRUBBER EXHAUST (2) DATE: 3/29/95

**~** 

### I-Network Environmental, Inc. SUMMARY OF EXHAUST GAS PARAMETERS

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN t 1 SCRUBBER EXHAUST ( 2 ) SAMPLING STAFF: SMITH\SCBULTES SAMPLE NUMBER G1. STACK RADIUS, inches G2. AREA OF STACK, sq. ft. G3. BAROMETRIC PRESSURE, in. HG. G4. STATIC PRESSURE IN STACK, in. H20 GS. STACK GAS TEMPERATURE, deg. F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: ts OXYGEN ts CARBON DIOXIDE ts CARBON MONOXIDE ts NITROGEN G10. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: G11. DRY, @ STP, lbs./cu.ft. G12. WE'l', @ STP, lbs./cu.ft. G13. WET, @ STACK CONDITIONS, lbs./cu.ft. G14. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. G17. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM STANDARD CONDITIONS, DRY SCFM TEST DATE: 3/29/95

1 19.5 8.30 29.00 0.48- 318 0.671

7.53 

## o.oo 15.07

3.40 

## o.oo 81.53

0.0754 0.0732 0.0483

29.16

2746
22 '778 15,022 13,891

### Network

**Environmenta~,** 

### Inc. PITOT TRAVERSE DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 3/29/95 COMPANY LOCATION: CORUIINA, MICHIGAN SOURCE NAME: 

### JtiL!r U SCRUBBER EXIIAUST (2) SAMPLING

**S~:** SMITB\SCBULTES RUN NUMBER: 1

- CARBON DIOXIDE: STACK RADIUS, in.: 19.5

- OXYGEN: GAS TEMPERATURE, Deg F: 318

- CARBON MONOXIDE: STATIC PRESSURE, in. B20: -.48 PITOT FACTOR: 

### .82 BAROMETRIC PRESSURE: 29 POl:NT VELoCITY PRESSURE, :Z:NCBES OF WATER PT. LOCATION, PORT

I INCHES 1 2 1 l.71 0.35 0.29 2 5.69 0.50 0.47 3 11.54 0.50 0.53 4 27.45 0.50 0.49 5 3!1.30 0.49 0.47 6 37.28 0.44 0.41

i

/)r -

r



### Network Environmental, Inc. P.O. Box 2021 Grand Rapids, HI 49501 

### SOURCE EMISSION TESTING at MICHIGAN DIVJ:SIOH, U.S. BlUCK CORDHNA, MICHIGAN KILN fl SCRUBBER EXBAUST (3) DATE: 3/29/95



### ;br I

I I Network Environmental, Inc. SUMMARY OF EXHAUST GAS PARAMETERS

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN U SCRUBBER EXHAUST (3) SAMPLING STAFF: SMITH\SCBULTES SAMPLE NUMBER G1. STACK RADIUS, inches G2. AREA OF STACK, sq. ft. G3. BAROMETRIC PRESSURE, in. HG. G4. STATIC PRESSURE IN STACK, in. H20 G5 • STACK GAS TEMPERATURE, deg. F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7 • PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: i OXYGEN i CARBON DIOXIDE t CARBON MONOXIDE i NITROGEN G10. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: Gll. DRY, @ STP, lbs./cu.ft. G12. WET, @ STP, lbs./cu.ft. G13. WET, @ STACK CONDITIONS, lbs./cu.ft. G14. MOLECULAR WEIGHT, DRY, @ STP, lba./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. G17. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM STANDARD CONDITIONS, DRY SCF. TEST DATE: 3/29/95

1 19.5 8.30 29.00 0.51- 311 0.662

7.53 

## o.oo 15.07

3.40 0.00 81.53

0.0754 0.0732 0.0487

29.16

2695 22,355 14,876 13,756



### . 7 / /

### Network Environmental, Inc. I 

# r PITOT TRAVERSE DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 3/29/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN tl SCRUBBER EXHAUST (3) SAMPLING STAFF: SMITH\SCBULTES
,- 1 RUN NUMBER: 1

**~** CARBON DIOXIDE: STACK RADIUS, in.: 19.5

**~** OXYGEN: GAS TEMPERATURE, Deg F: 311

**~** CARBON MONOXIDE: STATIC PRESSURE, in. H20: -.51 PITOT FACTOR: .82 BAROMETRIC PRESSURE: 29 POINT VELoCITY PRESSURE, INCHES OF WATER PT. LOCATION, PORT

t INCHES 1 2 1 1.71 0.26 0.31 2 5.69 0.44 0.47 3 11.54 0.51 0.51 4 27.45 0.51 0.49 5 33.30 0.49 0.45 6 37.28 0.43 0.43



# ;fNetwork Environmental, Inc. ORSAT ANALYSIS DATA COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 3/29/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN tl SCRUBBER EXHAUST SAMPLING STAFF: SMITB\SCBOLTES DATE OF ANALYSIS: 3/29/95 METHOD: MULTIPOINT INTEGRATED SAMPLE

PART CARBON DIOXIDE OXYGEN CARBON .MONOXIDE SKPL CONT RON



### t t t FINAL INIT. 

# ' FINAL INIT. 

# ' FINAL INIT. 

# ' 1 1 1 3.4 0.0 3.4 18.4 3.4 15.0 18.4 18.4 

## o.o 2 3.4 0.0 3.4 18.4 3.4 15.0 18.4 18.4 

## o.o 3 3.4 0.0 3.4 18.6 3.4 15.2 18.6 18.6 

## o.o



# ;9

# r

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# t:

' 

# L L

" 

### l_ 

# [_ 

# L I L. 

# l 

# L L· l' APP.ENDIX B . 

### S02

**ANAL~R** 

### OUTPUT & 

### CALIBRATION DATA

-

**-~--** 

## --- -- ····--· 

### --·- ---------. 

### ----·

**·----~------·----·· ------~,------~**  .,, ...i



## ,. ' 

### EMISSIONS TEST SAMPLING DATE: 03-29-1995 COMPANY: US Brick SOURCE: Kiln #1 Scrubber Exh START S02 

### RUN TIME (PPM)

1 08:22 362 2 09:34 370 3 10:47 391**~(**Company: Michigan Division U.S. Brick Location: Corunna, Ml Source: Kiln #1 Exhaust Date: 3129/95 Operator: Smith\Schultes Monitor: Pace 302 Span Value (PPM): 0-1000 Page#: 1 of 1 Calibration Response, PPM Calibration .. Analyzer

Gas Cone. Direct System Injection

Cal. Error, Drift, % of Span

PPM Injection

Pretest Post 1 Post2 Post3 %of Span Gas

7:52 8:07 9:26 10:39 11:51 Test 1 Tesl2 Test 3

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

244.0 247.0 256.0

0.30

392.9 396.0 408.0 412.0 415.0 417.0 0.31 0.40 0.70 0.90

• 857.3 857.0 869.0

-- - -- --· --- --· ---

• AB Defined By EPA Method, This Value Must Be The Same AB The Relevant Direct InJection Value

•• Run Zero and either mid or high calibration gas, whichever one is closer to aclual stack concentration Pretest 0.00 0.9 1.2 3.2

Analyzer cal. error,% of span= (dir. inj. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% System Bias, %of Span Post 1 Post2 0.00 0.00 1.6 1.9

Drift,% of span= (relevant pastiest sys. inj. cal. response, PPM- sys. inj. pretest cal. response, PPM) x 100% I (span value, PPM): Limit= 3%

**~** System bias,% of span= (relevant sys. inj. cal. response, PPM- dir. lnj. cal. response, PPM) x 100% I (span value, PPM): Limit= 5%

,. r:J --- Post3 0.00 2.1

### 'ILENAME: USB5329.DTA**~OMPANY:** 

### usbrick SOURCE: so2scrubber DATA LISTING



# ------------------------------------------------------------------------------ :H&'INEL: PARAMETER: ""NITS:

LOPE: INTERCEPT: 00 S02 PPM 1000 0



# -------------------------------------------------------------------------------

3-29-1995 08:22:20 364 v3-29-1995 08:23:20 358 03-29-1995 08:24:20 358

3-29-1995 08:25:20 360 3-29-1995 08:26:20 353 03-29-1995 08:27:20 356**~3-29-1995** 

### 08:28:20 360

3-29-1995 08:29:20 367 'J3-29-1995 08:30:20 368 03-29-1995 08:31:20 363

3-29-1995 08:32:20 362 .3-29-1995 08:33:20 361 03-29-1995 08:34:20 361

3-29-1995 08:35:20 361 3-29-1995 08:36:20 349 03-29-1995 08:37:20 360 "3-29-1995 08:38:20 361

3-29-1995 08:39:20 358 u3-29-1995 08:40:20 360 03-29-1995 08:41:20 362

•3-29-1995 08:42:20 363 •3-29-1995 08:43:20 365 03-29-1995 08:44:20 361 "3-29-1995 08:45:20 359 •3-29-1995 08:46:20 349 03-29-1995 08:0:20 358 03-29-1995 08:48:20 361

·3-29-1995 08:49:20 356 v3-29-1995 08:50:20 364 03-29-1995 08:51:20 357

13-29-1995 08:52:20 353 •3-29-1995 08:53:20 358 03-29-1995 08:54:20 359 '13-29-1995 08:55:20 359 •3-29-1995 08:56:20 360 U3-29-1995 08:57:20 368 03-29-1995 08:58:20 365

3-29-1995 08:59:20 367 .3-29-1995 09:00:20 367 03-29-1995 09:01:20 366 ·3-29-1995 09:02:20 366

3-29-1995 09:03:20 370 03-29-1995 09:04:20 366 "3-29-1995 09:05:20 369

3-29-1995 09:06:20 363 v3-29-1995 09:07:20 361 03-29-1995 09:08:20 367

3-29-1995 09:09:20 361**~J.-~**

### 03-29-1995 09:10:20 364 "3-29-1995 09:11:20 364

3-29-1995 09:12:20 360 ,3-29-1995 09:13:20 363 03-29-1995 09:14:20 364

3-29-1995 09:15:20 364 .3-29-1995 09:16:20 346 03-29-1995 09:17:20 361 -3-29-1995 09:18:20 371

3-29-1995 09:19:20 366 )3-29-1995 09:20:20 370 113-29-1995 09:21:20 365

3-29-1995 09:34:29 370 ,3-29-1995 09:35:29 372 03-29-1995 09:36:29 358

3-29-1995 09:37:29 369 3-29-1995 09:38:29 373 J3-29-1995 09:39:29 374

**~3-29-1995** 

### 09:40:29 374

3-29-1995 09:41:29 369 !3-29-1995 09:42:29 373 03-29-1995 09:43:29 259

3-29-1995 09:44:29 181 .3-29-1995 09:45:29 224 03-29-1995 09:46:29 460

3-29-1995 09:47:29 427 3-29-1995 09:48:29 396 )3-29-1995 09:49:29 376 "3-29-1995 09:50:29 381

3-29-1995 09:51:29 379 J3-29-1995 09:52:29 376 03-29-1995 09:53:29 375

3-29-1995 09:54:29 373 .3-29-1995 09:55:29 368 03-29-1995 09:56:29 378

. -3-29-1995 09:57:29 378 3-29-1995 09:58:29 374 )3-29-1995 09:59:29 372 113-29-1995 10:00:29 377

3-29-1995 10:01:29 367 ,3-29-1995 10:02:29 374 03-29-1995 10:03:29 373

13-29-1995 10:04:29 370 13-29-1995 10:05:29 374 )3-29-1995 10:06:29 371 '13-29-1995 10:07:29 379 13-29-1995 10:08:29 380 13-29-1995 10:09:29 381 03-29-1995 10:10:29 372

13-29-1995 10:11:29 374 13-29-1995 10:12:29 375 03-29-1995 10:13:29 374

13-29-1995 10:14:29 378 13-29-1995 10:15:29 365 J3-29-1995 10:16:29 370 '13-29-1995 10:17:29 372.

13-29-1995 10:18:29 382 J3-29-1995 10:19:29 380 03-29-1995 10:20:29 378

1 3-29-1995 10:21:29 379



### ~y

### 03-29-1995 10:22:29 376 "3-29-1995 10:23:29 376

3-29-1995 10:24:2· 377 v3-29-1995 10:25:2 369 03-29-1995 10:26:: 376

3-29-1995 10:27:2c 387 3-29-1995 10:28:29 375 03-29-1995 10:29:29 380

**~3-29-1995** 

### 10:30:29 384

3-29-1995 10:31:29 383 03-29-1995 10:32:29 375 n3-29-1995 10:33:29 380

3-29-1995 10:47:55 382 v3-29-1995 10:48:55 382 03-29-1995 10:49:55 382

3-29-1995 10:50:55 382 3-29-1995 10:51:55 384 ;)3-29-1995 10:52:55 384 "3-29-1995 10:53:55 381

3-29-1995 10:54:55 379 J3-29-1995 10:55:55 395 03-29-1995 10:56:55 395

3-29-1995 10:57:55 401 .3-29-1995 10:58:55 402 03-29-1995 10:59:55 396 ·3-29-1995 11:00:55 396

3-29-1995 11:01:55 401 )3-29-1995 11:02:55 404 "3-29-1995 11:03:55 398

3-29-1995 11:04:55 395 J3-29-1995 11:05:55 388 03-29-1995 11:06:55 393

3-29-1995 11:07:55 388 3-29-1995 11:08:55 390 )3-29-1995 11:09:55 383

**~3-29-1995** 

### 11:10:55 390

3-29-1995 11:11:55 387 )3-29-1995 11:12:55 384 n3-29-1995 11:13:55 388

3-29-1995 11:14:55 384 .3-29-1995 11:15:55 376 03-29-1995

**11:16:~5** 

### 382

3-29-1995 11:17:55 386 3-29-1995 11:18:55 383 )3-29-1995 11:19:55 384 "3-29-1995 11:20:55 387

3-29-1995 11:21:55 382 J3-29-1995 11:22:55 382 03-29-1995 11:23:55 389

<3-29-1995 11:24:55 386 J3-29-1995 11:25:55 391 J3-29-1995 11:26:55 400 13-29-1995 11:27:55 401 13-29-1995 11:28:55 400 )3-29-1995 11:29:55 402 03-29-1995 11:30:55 400

13-29-1995 11:31:55 402 J3-29-1995 11:32:55 401 03-29-1995 11:33:55 396

13-29-1995 11:34:55 395

**·.~) ~** 

### 03-29-1995 11:35:55 380 n3-29-1995 11:36:55 387

3-29-1995 11:37:55 397 v3-29-1995 11:38:55 397 03-29-1995 11:39:55 401

·3-29-1995 11:40:55 401 ,3-29-1995 11:41:55 394 03-29-1995 11:42:55 395

**-~3-29-1995** 

### 11:43:55 396

1

### 3-29-1995 11:44:55 391 U3-29-1995 11:45:55 373 03-29-1995 11:46:55 385

•

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### '· · S02 

### ANAL'YZER SPECIFICATIONS & 

### GAS CERTIFICATIONS . 

### L 

### I- '**I~** 

### L



### 1.

L L

.. ---· 

# ·-· --· 

## -- --"--**~** 

## ----· ..' I

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## TABLE I PSC 302 SPECIFICATIONS 

## _,-

**-------------------------------------~---------------------------------------** 

## RESPONSE TIME RESPONSE ACCUP.ACY 

## * DRIFT 

## * OUTPUTS RANGES POWER REQUIREMENTS W1PEO,A_TURE ENVIRONMENT (Operating) TYPE OF GAS <2 Minutes to 90% of Fu11 Sca1e Linear Within± 1% in Each Range Overa11 Accuracy ±2% Zero and Span t2% of Fu11 Sca1e 0
- 1 Vo1t, 10,000 ohms minimum 4 - 20 

## mA, 250 ohms maximum XI, X3, X10 (See Appendix A) ,115 Vac, 50/60Hz, 15 amps maximum 40°F to 90°F CO Up to 50,000 PPM S02, 

## NOx up to 150,000 PPM (See Appendix A) 02 Up to 50%

. SAMPLE LINE 25Ft. E1ectrica11y Heated, Se1f Regu1ating, 20

**;1~**



## CALI8P.AT.ION FREQUENCY Every 24 Hours of Service SENSOR TYPE E1ectrochemica1 SIZE . PSC 302 Monitor
- 16". x 12" x 

## 12" Accessory Case
- 20" x 29" x 10" WEIGHT PSC 302 Monitor- 45 Lbs. with Ce1ls Accessory Case
- 40 Lbs. 

# ------------------------------------------------------------------------------- * Over 24 Hour Period'

### 1.0 INTRODUCTION The Environmental Products' PSC 302 Portable Monitor System is caoable of simultaneously monitoring t'11o gases in concentrations up to 

### 150,000 PPt1 

### from a single sample probe. The gases which can be monitored are NOx, SOz, CO and Oz. The system uses electrochemical sensors (cells) that operate on the fuel cell principle. In a typical sensor, shown in Figure 2, a gas sample

**~iffuses** 

### through a semipermeable membrane, and comes in contact with a sensing electrode where it undergoes an oxidation or reduction reaction. This process generates an electrical current output which is linear and directly proportiona1 to the partial pressure of 

### the gas that the sensor is designed to sense. This current is convert!!d to 

### a voltage signal which operates a panel meter or outboard device, such· as a chart recorder or data logging system. Before

**att~mpting** 

### to operate the PSC 302

**Ho~itor,** 

### the operator should read and und!!rstand this manual in order to obtain accurate results and not

**dama~e** 

### the monitor. 2.0 SYSTE:'l DESCRIPTION AND SPECIFICATIONS Th!! PSC 302.Portab1e Monitor is designed to 

### be easily transported by one person. It weighs less than 45 pounds, and is 16" L by 12" Wby 12" Hin size. The system will monitor concentrations of SOz, NOx, CO or Oz, depending on the sensors. installed 1n t"he system. The sample line, prcbe, filter, and calibration gases are contai,ned in the Accessory Case which

**~1eighs** 

### less than 40 pounds, and measures 20" Wby 29" L by 10" H. The specifications for the monitor which accompanies this handbook are listed in Table I. The gas sample is drawn into the monitor through a heated line by a sample pump end then into the sample conditioner, see Drawing 751750. Within the conditioner, the gas is rapidly cooled below 45°F to remove moisture, which is expelled through a drain valve. The sample conditioner uses a solid state, thermostatically controlled thermoelectric device to dry the gas being sampled. The sample

1

## _

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### 2.0

**SYSTE~** 

### DESCRIPTION AND SPECIFICATIONS (Continued)

**~~en** 

### flows

**~1rough** 

### the sample/calibrate valve and the monitor flow meter to the sensors. If an NOx sensor is used (and the sample contains SOz), the sample flows through. an SOz scrubber before the NOx sensor. Each sensor generates an electrical current.which is converted into a voltage signal to drive the monitor meters and other external devices as required. The monitor also provides a 4-20 

## mA current signal for this purpo?e. The PSC 302 monitor uses a 1 to 3 to 10 relationship for its range switch unless en optional analyzer board is installed (see Appendix A). If a 30-4 sensor is installed, it will read 1,000 PPM fullscale in low range, 3;000 PPM in midrange, and 10,000 PPM in high range. An Oz sensor will reads: full scale in low range, 15: in mid-range, and so: in high range. To calibrate the monitor, gases of known precise concentrations are connected to the sample/calibrate valve. Using this valve, each monitor channel can be set to zero using a zero gas such as air or 

## Nz. After the zeroing process is complete, the valve is cycled to introduce a calibration gas which facilitates adjustment of each channel's span. Calibration gases must be regulated to approximately 5-8 PSIG before applying them to the·monitor input. If excessive pressure is applied to the sensors, it is possible that the membrane can be ruptured thus ruining the sensor. 3.0 SYSTEM SETUP 3.1

**INSPE~TION** 

### AND PLACEMENT When the system is unpacked, check for shipping damage, be sure to check all items shipped in the accessory case (such as the sample line, probe and calibration gases). Make certain that the system conforms to the system configuration shown in Appendix A of this manual. Contact the factory if there is any damage or nonconformance before using.i. ' 

### 2.0 Technical Daca
Maxi:um sample gas

**flo~** 

### race of each gas pach Operacicg pressure Sample gas

**ia.le~ ce::~pe:-acu:-e**  

### Sample gas ic.lec 

### de.., poicc Sample gas ouclec e:ecperae:ure !".A.'< 

### 2-1

- !".A.'< 

### 2

- accu:-acy

Rutt::tir.g- in ti:::e 

### Dead space per gas pach •.. P:-essu:-e drop per gas paeh ' 

## .

**Alcer~acive** 

### volcage

Pove=

**consu:pcio~ BA·l"-~'<**  

### 2/9.87·1-2

**~"-"..:<** 

### !".A.'< 250 0,15 0,5 7 

### 2-1, Type 29 

# - 1 - 2 Tne 30 

# - 2 - 1/h ac 1 ba:- 

### attd 20

SCFM ac 14 psi 2,5 

### bar 35 psi and
140 Degr 

## c I 284 Degr F

65 Degr C 

### I 149 Degr F Deg:- 

## c 68 Degr

+ 3 Deg:- C 

### I 3?,0 Degr F ouclec

**ce::~peracu:-e** 

### gas pach No. lis 0,5 Degr C 

### I 0,9 Deg:- F higher chan gas pach No. 2. F



### +!- 0,3 Degr. C 

### I+!- 0,54 Degr F Digical display indicacor fot' eooli::.g bri:le 

### ce:peracu:-e vich li:::ti

### cicg valt.:e

**sig::~al** 

### +!- 0,5 Deg:- 

## c ac 0 

# ... 10 Degr 

## c +!- 0,9 Degr F 

### ac J2 

## .. 

# so Degr F appro:<. 

### 53 c::i:L 

### approx. 8,36 cubic·icch ap

**~:r:-** ox... 

### 25 c:ba:- ac 250 1/h

**app~o:c.** 

### 0,36 psi 

### ac 0' 15 SCF}! 

### 115 

## v + lOi.. 

## - lOi:. 

### (60 

### +1·2) 

### E: Code 01 220 

## v + 101.. 

## - 151. 

### (50 +/-2) Ez Code 

### OJ 220 

## v + 151. 

# ... 

# - 51. 

### (60 

### +1-2) E.: 

### Code 04 zppt'OX. 

### 450 VA, 

### 3,9 A ac 115 

## v 60 !!: 

### approx. 440 VA, 

### 2,0 A 

### ac 220 

## v 50 !!: ap?t"OX:. 

### 480 VA, 

### 2,1 A 

### ac 220 

## v 60 Hz**BA-~JL'** 

### 219.87-l-J 2.1 **Envi~or.-ental** 

### capabilities Clicace

**g~oup**



### Rela:ive

**h~idicy**

Cons.true

**~ioc.** 

### !::!ouc.cing method .Di!:lE!:tSiOllS



### (Width x 

### Depth x 

### Heighc) Sample gas conc.eccions

**Cocdensac~** 

### ouclec Deg::-ee of housing procection Proceccion class

**Ope~acive** 

### posicion 

### ZZ

**whe~e** 

### Z • + 5 

### Deg::- C ••• +55 Deg::- 

## c dto. Z • 

### +41 Deg::- F ••• 

### +131 Deg::- F

**co~::-esponds** 

### co DIM 40

**0~0,** 

### LVE + 

### 5 Deg:- C 

### +4t Deg:- 

### F + 4.5 "Deg::- C max. + 

### 55

**Deg~** 

### ( +llJ Deg::- 

### F max. +l3t Deg::- 

## * at+ 55 Degr C 

### I +131 Deg::- 

### F the maxi:uc Sai:?h 

### gas flo" of K-1..'< 

### Z (2 gas paths)· is 125 llh 

### 1 0,075

**sc~.** 

### -25

**Deg~** 

### C -13 Deg::- 

### F + 6 5 Deg:- C . +149 Degr F 

### lo"e= chan 75i. annuaL ave::-ag• **inte=:~eque~:** 

### and light condensation

**co1e~aced.**



### 360 X 

### 335 X 

### Z90

**~** 

### Pipe 6 x 

### 1 

# = O,ZJ6Z x 

### 0,0394. inch Pipe 

### lZ x l 

# = 0,4.724 x 0,0394. inch I? 22 co DIN 40 050 I in

**acco~dance** 

### with DIN 57 700,

**pa~:** 

### l, VDE 0700, pa:-c 116.83 inclination

**lo~er** 

### 5 

### Deg::-

### • 

# ' ' ;

J '



### ' ;• 

### 2.3 l".acerials Material ,of gas leading pares Material of housing 

### 2.4 Electrical connections Pover supply Poceneial free eoncaee 2.S 

### lleill:hc 

### PVDF (Polyviaylidenfluoridi steel place, Color 

### RAL lOlS**po~er** 

### cord vtch shock proof plug coaneeeion lead 

### 2 x 

### 0,7S =: 2 x 

### 0,00l2 

### sqin appro:<. 26 kg.

# AGA Gas, Inc. CERTIFICATE OF ANALYSIS 

## EPA PROTOCOL t1 PERFORMED ACCORDING TO SECTION 3.0•• FILE NUMBER:

**EPA1~85** 

### CYLINDER NUMBER:

**CC992~8** 

### PRESSURE: 2000 PSI PRODUCTION NUMBER: 03930967 CERTIFICATION DATE: April 28, 1993 EXPIRATION OAT!: October 28,

**199~** 

### CERTIFICATION PERIOD: 18 Months CERTIFIED COMPONENT Sulfur Dioxide CERTIFIED CONC. 2H PPI'I BALANCE GAS: Nitrogen MfALYZ!R MAX!/MOD!L/S!RIALt Thermo

**electron/~0/** 

### 40-17472-170 ANALYTICAL PRINCIPLE: Fluorescence REFERENCE STANDARD: MULTIPOINT CALIBRATION 3/4/93

SRM NUMBER GMIS CYLINDER NUMBER CONCENTRATION CC712i3 , 513.7 PPM ANALYSIS #1 ANALYST: M.R. DATE:

**~-13-93** 

### ZERO REF. TEST DEVIATION GAS GAS GAS RESULT FROM THE (MV! (MV) (MV! (PPM! MEAN(%! o. 70 513.80 242.80 H2. 4 

### PPM 0.00' 0.70 513.80 242.80 H2. 4 

### PPI'I 0.00' 

# o. 70 513.80 242.80 H2. 4 

### PPM 0. 00, MEAN: 2-!2.-l PPM ANALYSIS #2 ZERO REF. TEST GAS GAS GAS (MV! (MV) (MV! -.86 511. ?0 2H.70 -.86 511. 90 2H.70 -.86 511.90 2H.70 MEAN: H6. 0 PPM ANALYST: M. R. DATE: 4-27-93 DEVIATION RESULT FROM THE (PPM! MEAN (%! 246.0 PPI'I 0.00' H6.0 PPI'I 

## o.oo' H6.0 PPI'I 0.00'



# ~__;~---· MICHAEL SICKMILLER QUALITY CONTROL SUPERVISOR

---------------------------------------------------------------------

**-~5**

**r~~o,o~ ~"a•**  / ACA Gn r,c 15-12' ...O,C\0•• J:lo.)(!

.....

**~**..-- ,.. ..... **~·~11**SPE.CIALTY GAS DIVISION 11711 S. Alameda

**St~et** Los Angeles. CA 90059 (213)564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Airgas I Michigan Date' 19 December 1994 P.O.' PG-0621 EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC37899 Sulfur Dioxide Nitrogen

Certification Period (months): 24 Expiration Date: 19 December 1996 Cylinder Pressure: 2000 psia DO NOT USE BELOW 150 PSIG 400 PPM Balance 392.9 PPM Balance ACTUAL

### SPECIALTY GAS DIVISION 11711 S. Alameda Stn3et Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Michigan Alrgas

EPA Protocol Procedure IT! CYLINDER NO. CONSTITUENTS CONCENTRATION: CC·25694 Sul!urDloiide Nitrogen
CertlncatlonPeriod (months): 24 Expiration Date: 18 May 1996 Cylinder Pressure: 2000 psla DO NOT USE BELOW !50 PS!G



## -----·-- 800 PPM Balance Date: 18 May 1994 P.O.: PG 0530

NOMINAL 857.3 PPM Balance ACTUAL

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## .....



# ~ Zero Point ,


## . .. Port Size/Type



## . ._

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# . .... -----'

## " APPENDIXE
. 

## ,·- / 

## . CALCULATIONS



## r .

# ' '

r

I. ' 

### EPAMETHOD 6C AVERAGE GAS CONCENTRATIONFORMULA Eq. 

### 6C-l



# - c C = 

### (C- C) 1M

1"' • 

### (C., -C.)



### Where: Cps = Effluent gas

**concentra~on,** 

### dry basis ppm or%. 

### C =Averagegas concentration indicated by gas analyzer, 

### drybasisppmor%. 

# c.=Average ofinitial 

### andfinal systemcalibrationbiascheckresponsesforthe zero gas ppmor%. C =Averageofinitial 

### andfinal

### systemcalibrationbiascheckresponsesforthe



# . . 

### upscale calibration gas ppm or%. 

## C,.. 

# = Actual concentration ofthe upscale gas, ppmorpercent.r1

f .

I



## ,. - ' I



### i

I 

### 1.

2.



### 3. SULFUR DIOXIDE CALCULATIONS
Concentration \m

**M~**

**)**

**~'** 

### - CPPlt!) 

### CM.WJ24.2l 

### where: M.W.
- molecular weight
- 64 for S02 Air 

### Flow 

### Rate in Dry 

### Standard Cubic Meters PerMinute 

### (DSCMM) DSCMM
- (DSCFM) (0.0283) 

### where: 

### DSCFM
- Dry Standard Cubic Feet Per Minute Emission Rate (in 

### Lbs/Hr) Lbs/Hr
-

**(M~**

**)** CM'!Wnl (60 Min/Hr) (2.205 Lbs/Kg) (XgilOOO g) (gllOOO mg) 

### Lbs/Hr
- (MgiM3) 

### (DSCMM) (1.323 X 

### 10-'J

### ,. ,.:

( Network Environmental, Inc. CALCULATION FORMULAS MOISTURE tRAIN CALCULATIONS: M1. BAROMETRIC PRESSURE, inches of Mercury M2. DURATION OF SAMPLE, minutes M3. METER CALIBRATION FACTOR M4. AVERAGE METER TEMPERATURE, degrees F M5. AVERAGE METER PRESSURE, inches of water M6 • METER VOLUME, ACTUAL, cubic feet M7 • METER VOLUME, STP, cubic feet 530 M1 

### + .07355 

### * M5 M7 = M3 

### * M6 

### * ---------- * ------------------ M4 + 460 29.92 MS. LIQUID VOLUME OF WATER CONDENSED, milliliters M9. VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet M9 = MS 

### * 0.0474 M10. TOTAL GAS SAMPLED, @ STP, cubic feet M10 = M7 +M9 M11. PERCENT MOISTURE M9 M11 = 

### * 100 M10 EXHAUST GAS CALCULATIONS: G1. STACK DIMENSIONS, inches G2. AREA OF STACK, square feet3.14159 

### * (DIA/2)"2 G2 (ROUND) 

# =--------------------- 144 WIDTH 

### * LENGTH G2 (RECT.) 

# =---------------- 144 G3. BAROMETRIC PRESSURE, inches of Mercury G4. STATIC PRESSURE IN STACK, inches of water G5. STACK GAS TEMPERATURE, degrees F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION P13 G7 = ----- 

### * 100 P14

# ,- '

c - I
r



### ,- ! Network Environmental, Inc. CALCULATION FORMULAS CONTINUED GS. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION, %02, %C02, %CO, %N2 G10. PERCENT EXCESS AIR AT TEST LOCATION %02
- 0.5 

### * %CO G10 

# = 100 

### * ----------------------------- .264 

### * %N2
- %02 

### + .5 

### * %CO G11. DENSITY, DRY, @STP, lbs./cu. ft• G11 

# = •0827 

### * %02 + .1137 

### * %C02 + (%CO + %N2) 

### * .0724 

# -------------------------------------------------- G12. DENSITY, WET, @STP, lbs./cu. ft. 100
- G7 100 G7 G12 = G11 

### * ---------- + .0465 

### * ----- 100 100 G13. DENSITY, WET, @ STACK CONDITIONS, lbs./cu. ft. 530 G3 + .07355 

### * G4 G13 = G12 

### * ---------- * ------------------ G5 + 460 29.92 G14. MOLECULAR WEIGHT, DRY, lbs./mole G14 = G11 

### * 386.9 G15. AVERAGE GAS VELOCITY, feet/minute 1096 G15 

## = P5 

### * G6 

### * ----------- G16. STACK GAS FLOW RATE, ACFM G16 = G2 

### * G15 G17. STACK GAS FLOW RATE, SCFM SQRT(G13)

530 G3 + .07355 

### * G4 G17 

# =G16 

### * ---------- * ------------------ G5 + 460 29.92 G18. STACK GAS FLOW RATE, DRY, DSCFM 100
- G7 G18 • G17 

### * ---------- 100

## I ,- ' ,_

I Network Environmental, Inc.
CALCULATION FORMULAS CONTINUED
PARTICULATE TRAIN CALCULATIONS: Pl. NUMBER OF POINTS SAMPLED P2. DURATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, square feet 3ol4l59 

### * (P3/2)•2 P4 = -------------------- 

## r- 144 

### '
. P5. PITOT CALIBRATION FACTOR P6. METER CALIBRATION FACTOR P7. AVERAGE FILTER TEMPERATURE, degrees F PS o AVERAGE METER TEMPERATURE, degrees F P9. AVERAGE METER PRESSURE, inches of- water PlO. METER VOLUME, ACTUAL, cubic feet Pll. METER VOLUME, @ STP, cubic feet 

### ' 530 G3 + .07355 

### * P9 · Pll 

# = PlO 

### * P6 

### * ---------- * ------------------**~--** PS + 460 29.92 Pl2o LIQUID VOLUME OF WATER CONDENSED, milliliters P 13o VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet Pl3 = Pl2 

### * 0.0474 Pl4. TOTAL GAS SAMPLED, @ STP, cubic feet Pl4 = Pll + Pl3 Pl5. WEIGHT OF GAS SAMPLED, DRY, pounds Pl5 = Pll 

### * Gll Pl6 o WEIGHT OF GAS SAMPLED, WET, pounds Pl6 = Pl4 

### * Gl2 Pl7. PERCENT ISOKINETICS 100 

### * 29o92 

### * (G5 + 460) 

### * Pl4 Pl7 = ------------------------------------------ 530 

### * (G3 + o07355 

### * G4) 

### * P2 

### * P4 

### * Gl5

### '. ' Network Environmental, Inc. CALCULATION FORMULAS CONTINUED
CONCENTRATION CONVERSION FACTORS: Pl8. 50 % EXCESS AIR, AFER COLLECTOR Gl4 + 18 

### * G7/(100
- G7) Pl8 = 

# ------------------------------------------------------- .1826 

### * %N2
- 2.0592 

### * %02 + Gl4 + 18 

### * G7/(100
- G7) Pl9. 50 % EXCESS AIR, BEFORE COLLECTOR Gl4 + 18 

### * G7/(100
- G7) Pl9 = ------------------------------------------------------- .1826 

### * %N2
- 2.0592 

### * %02 + Gl4 + 18 

### * GS/(100
- G8) P20. MOISTURE BEFORE COLLECTOR Gl4 + 18 

### * G7/(l00
- G7) P20 

# =-------------------------- Gl4 + 18 

### * G8/(l00
- GS) PARTICULATE EMISSION CALCULATIONS: El. E2.
E3. E4. TOTAL WEIGHT PARTICULATE COLLECTED, grams LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL 1000 E2 = El 

### * 

# ----------- 454 

### * Pl6 LBS. PARTICULATE/lOCO LBS. GAS, DRY E3 = E2 

### * P20 LBS. PARTICULATE/lOCO LBS. GAS, WET, 50% EA E4 = E2 

### * Pl8 ES. LBS. PARTICULATE/lOCO LBS. GAS, DRY, 50% EA ES = E2 

### * Pl9 E6. GRAINS/DRY STANDARD CUBIC FOOT El 

### * 7000 

### * 100 E6 = ------------------------ 454 

### * Pl4 

### * (100
- G7) E7. POUNDS/HOUR Gl7 

### * Gl2 

### * 1000 

### * El 

### * .06 E7 = ----------------------------- 454 

### * Pl6 E8. POUNDS/MILLION BTU E7 E8 = ---------------------

**<~ACITY,** MM BTU/HR

**~?­** ) -**~~** ' 

# ·'

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# r,

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## r - 

# r APPENDIXF RAW DATACompany:US.G[tck.location:CIJi?..\J!GNAINCORPORAIEOSource:Date:Operator:Monitor:::Vz.$--:£_(.)e-..eE;(?.__?JIfq:;OEil<'-lrt-1ce.u}302.SpanValue(PPM):ttY>()Page#:I0+'ICalibrationResponse,PPMCalibration..GasCone.DirectSystemInjectionPPMInjectionPretestPost1Post2'/:'$2J[3:otIa:3 40·op00jCjz..<JiJ9IRt/D8L.\IZt-{15•!351-851I88L!AnalyzerCal.Error,Drift,%ofSpanPost3%ofSpanGas1/.'s1Test1Test2Test300000·3041':/-Cl.3\o·ido.qo•AsDefinedByEPAMethod,ThisValueMustBeTheSameAsTheRelevantDirectInjectionValue••RunZeroandeithermidorhighcalibrationgas,whicheveroneIsclosertoactualslackconcentrationPretest0D·CJl·z3.2,Analyzercal.error,%ofspan=(dir.lnj.cal.response,PPM-cal.gascone.,PPM)x100%I(spanvlaue,PPM):Limit=2%SystemBias,%ofSpanPost1Posl2p0r.&,,qviDrift,%ofspan=(relevantposllestsys.In!.cal.response,PPM-sys.lnj.pretestcal.response,PPM)x100%I(spanvalue,PPM):llmll=3%Systembias,%ofspan=(relevantsys.In].cal.response,PPM-dir.In].cal.response,PPM)x100%I(spanvalue,PPM):Limit=5%@-Post3c2·1.•

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# ... Report ofan... 

# Emission 

# Study performed for... 

# Michigan Division U.S. Brick . . . Corunna,·Michigan .,_



## .. ,• 

## on the 

# Kiln # 

# 1Exhaust
May27, 1994 010.05 

# NetworkEnvironmental, Inc. GrandRapids, MI

# I
I 

# l L 

# l. I



# L Network Environmental, Inc. P.O. Box 2021 Grand Rapids, III 49501 

### SOURCE EMISSION TESTING at MJ:CBIGAII DIVISION
- O.S. BRICK
- COROHHA, MJ:CBIGAII

JaLH tl EXBAOST 

## ,=

DAX!!:: 5/27/94

/'I



### .I



## r• I



# r· I . I. II.


## m. TABLE OF CONTENTS

Introduction Summary Tables ofResults 

### II.l Particulate Emission Results 

### Summary 

### II.2 Sulfur Dioxide (S02) 

### Emission Results 

### Discussion ofResults N. · 

### Source Description V. ·Sempling andAnalytical 

### Protocol
Appendices
ParticulateEmission Results 

### S02 

### Analyzer Output & 

### CalibrationDate
- . S02 

### Analyzer Specificetions & 

## Gas Certifications ParticulateField Data Calculetions Raw Data 

### ..-

' 

### ...

**·~**

,-. **~** 

### ' 1



### 2 2 2 3. 3-4 

### 4-6

:A B 

# c D E F **~.**I 

### I_

I l_ 

# I L. 

# ' 

# l I. INTRODUCTION NetworkEnvironmental, 

### Inc. was retained bythe

### Michigan Division ofU.S. Brickin Corunna, 

### Michigan. to performan emissionstudyonthe exhaustoftheir

### Kiln # 1. Thepurpose ofthe studywas 

### to document the particulate and sulfur dioxide (S02) emissions from the 

### Kiln #1 exhaust.
- The study was performed on May 27, 1994 by David D. Engelhardt and 

### Bertram 

### J. Smitf1 ofNetwo_rk Environmental, 

### Inc.. The testing was performed in accordance with :MDNR Reference Method 5B for particulateandU.S.EPAReferenceMethod 6C for S02• 

### Inaddition,theexhaustgas parameterS(air

### flow rate, temperature, moisture, and density) were determined

**~accordance** with U.S. EPA Reference '--- Methods 1 through 4. 

### Mr. Kenneth

### Terry, P.E. ofthe :MDNR Air Quality Division Shiawassee District
- - Office was present 

### to observe portions ofthe testing.

1

# j 

# I r ll.1 

### TABLE 1 

### PARTICULATE EMISSION RESULTS SUMMARY KILN #1 

### EXHAUST MICIDGAN DMSION • U.S. BRICK CORUNNA, MICIDGAN MAY 27, 1994

.·.·. Air

### F1ow Rate 

### Concentration· 

### · •••·• ·}dassEmi"SiinRate Sample Time SCFM Lbs/1000 Lbs, Dry .·· ·.·.. Lbs/Hr .·......·. 1 07:47.08:59 12,236 0.0063 0.31 2 09:26·10:29 12,174 0.0079 0.40 3 10:50·11:53 12,122 0.0075 0.37 .. 

### AVERAGE 12,177 0.0072 0.38

ll.2 

### TABLE 2 

### SULFURDIOXIDE (S02) 

### EMISSION RESULTS KILN #1 

### EXHAUST MICIDGAN DMSION • U.S. BRICK CORUNNA, MICIDGAN MAY 27, 1994 AirFlow

### Rate Concentration 1 • 

### Mass EmissiiJn Rate Sample : 

### Time DSCFM 

### PPM 

### Lbs/Hr . . 1 07:47·08:57 11,053 564 61.73 2 09:25·10:29 11,010 595 64.87 3 10:49·11:52 10,975 579 62.92 

### AVERAGE 11,013 579 83.17

2 

## (.(

### 1

I 

## L r ' 

# I ill. 

### DISCUSSION OF RESULTS Theresultsoftheparticulate emission samplingareSUIIIIIlarized inTable 1 (SectionIT.1). The

**particulate·~** results and the exhaust gas parameters are presented inmore detail inAppendixA ill.1 Particulate Emission Concentrations • The particulate emission concentrations were 0.0063 pounds ofparticulate per thousandpounds ofgas ona dry basis (Lbs/1000 Lbs, Dry) for sample one, 0.0079 Lbs/1000 Lbs, 

### Dry for sample two, and 0.0075 Lbs/1000 Lbs, 

### Dry for sample 

### three. The average ofthe three samples collected was 0.0072 Lbs/1000 Lbs, 

### Dry. ill.2 Particulate 

### Mass Emission Rates • The particulate mass emission rates were 0.31 pounds of particulateperhour (Lbs/Hr) for sample one, 0.40 Lbs/Hr for sampletwo, and0.37 Lbs/Hrfor sample three. The average ofthe 

### three samples collected was 0.36 Lbs/Hr. The sulfur dioxide (S02) emissionresults are presented inTable 2 (Section ll.2) ill.3 SO, Emission Concentrations • The S02 concentrations were 564 

### parts per million on a dry basis (PPM) for sample one, 595 PPMfor sample two, and 579 PPM for sample three. The average ofthe three samples collected was 579 PPM. ill.4 S02 

### Mass Emission Rates· The S02 

### Mass Emission Rates were 61.73 Lbs/Hr for sample one,-_ 64.87 Lbs/Hr for sample two, and62.92 Lbs/Hr for sample three. The average ofthe three samples collected was 63.17 Lbs/Hr. ill.5 Visible Emission Observations · After the completion ofthe field sampling, visible emission observations (opacity) were recorded for a fifteen (15) minute period from the Kiln # 1 exhaust. These observations were recorded by a certified technician in accordance withU.S. EPAReference Method 9. No visible emissions were observed during 

### this 15 minute period. The observation reporting form can be found inAppendix E.


### IV. SOURCE DESCRIPTION The source tested was the exhaust ofKiln # 1. The kiln i.s gas 

### fired. The exhaust from the kiln passes 3

### ' ' 

### '

.

### '

.. 

### f .-

**~**

I l.



### 1 . throughan emission control systemconsisting ofa cooler followed bya mixingchamberand tbenthrough a baghouseprior to exhaustingto atmosphere throughthe exhaust stack. Limeis sprayedinto tbe system between tbe cooler and tbe mixing chamber. 

### On 5/27/94 king sizebirchwood bricks were fired. Theyweigh on an average 5.lllbsperbrick, and tbere are 9,072 bricks per car (equates to 46,360 lbs per car). There were also 4,032 "real" bricks per carat a weight of 0.661 lb per "real" 

### brick (equates to 2,665 lbs per car). The total weight of each car is approximately 49,025 lbs per car. The kiln speed during tbe testing was 8.421 cars per day. The charge times for 5/27/94 were as follows: 01:12, 04:03, 06:54, 09:45, 12:36, 15:27, 18:18, and 21:09.


### V. SAMPLINGAND ANALYTICAL PROTOCOL V.1 Particulate 

## C <l

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**6(~7** i<> t Theparticulateemission samplingwasconductedinaccordance witbMichiganDepartmentofNatural Resources (MDNR) Reference Metbod 5B. Method 5B is an in-stack filtration metbod. Three (3) samples were collectedfrom the exhaust. Each sample was sixty (60) minutes in duration, and had a minimum sample volume of tbirty (30) dry standard cubic feet. .The samples were collected isokinetically andanalyzedfor totalparticulate by gravimetricanalysis. All tbequalityassuranceand quality control procedures listed in the method were incorporated in tbe sampling and analysis. V.2 Sulfur Dioxide · TheS02 determinationswereperformedinaccordance withU.S.EPAReferenceMetbod6C. APSC302 portable stack gas analyzer was used to monitor tbe Kiln # 1 exhaust. A heated teflon sample line was used to transport tbe exhaustgases from tbe stack to a gas conditioner to removemoisture andreduce.tbe temperature. From tbe gas conditioner tbe stackgases werepassed to tbeanalyzer. The analyzer produces instantaneous readouts oftbe S02 concentrations (PPM). The analyzer wascalibrated by directinjectionpriortotbe testing. A spangas of768 PPMwasused to establish the initialinstrument calibration. Calibration gases of50 PPM and244 PPM were used to determine tbe calibration error oftbe analyzer. The sampling system (from tbe.back oftbe stack probe to the analyzer) was injected usingtbe 244 PPM calibration gas to determine tbe systembias. After each sample, a system zero and gystem injection of 244 PPM were performed to establish gystem drift and system bias during tbe test period. At the end of tbe last sample, all three 4

### '. :



# 1 ' calibration gases were direct injected to show the analyzer drift over the entire testing period. All calibration gases used were EPA Protocol 1 Certified. The analyzer was 

### calibrated to the output ofthe data acquisition system (DAS) used to collectthe data. A strip chart recorder was also used to record the data as a backup to the DAS. Three (3) samples were collected from the 

### Kiln #1 exhaust. Eacilsamplewas sixty (60) minutes in duratioD. The DAS output, strip chart recorder data, and calibration data can be found in AppendixB. The 

# so, analyzer specifications andcalibrationgas certifications can be found inAppendix C. V.3 Exhaust Gas Parameters The exhaust gas parameters (airflow rate, temperature, moisture, and density) were determinedin

**~ co~unction**  withtheother samplingby employingU.S. EPAReferenceMethods 1through4. All the quality assurance and quality control procedures listed in the methods were incorporated in the sampling and analysis.

This report waspreparedby: David D. Engelhardt Vice President ' Thisrepcrtwasreviewedby:

5--- 0> (\- '"\ T cmpcraluro Sonsor kn Fillers -+- Slack Wall

. A **~DO.** 9 S-Type Pilol Tullo l· **~**
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/ L Manomolor, TomperahJro Sensor

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(' .._,amplo Lino to}==c /._ _____ __.
Flask (ML Colleclor) Vacuum Uno Thormomclers · Oy-Pass Valvo

/ r*i 0 **-~~-tr_L**

!:::!---- Mail! Valvo

_... , Dry Gas Mol or Air Tighl Pump --i ---, ' Vacuum Gaugo Figure 1 Particulate Swnpling Train -1!

### i 

# r 

# I I ( 

# I ( 

# f I APPENDIXA 

# f PARTICULATE EMISSION RESULTS
. 

# [ [ 

# t [ [ 

# ll [ 

# L {{ 

# Llletwork Environmental., :Inc. SUHMARY OF PARTJ:CllLAD TRAni PARAMETERS

COMPANY NAME: KICBIGAN D:rv:ISJ:ON
- O.S. BRJ:Clt COMPANY LOCATJ:ON: CORUNNA, KICBJ:GAN TEST DAXE: 5/27/94 

# I I 

# I [
SOORCE NAME: KJ:LH tl EXBAOS'r SAMPLJ:NG STAFP': EHGELBARD'I' / SKITB SAMPLE HtlMBER Pl. HtlMBER OF POINTS SAHl'LED P2 • DU'RATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, sq. ft. P5. PJ:TOT CALIBRATION FACTOR P6 • METER CALIBRATJ:ON FACTOR P7. AVERAGE FILTER TEMPERATllRE, deg. F P8. AVERAGE METER TEMPERATURE, deg. F P9. AVERAGE METER PRESSORE, inches of water PlO. METER VOLUME, ACTTlAL READil'IG, cu.ft. Pll. METER VOLUME, @ STP, cu.ft. Pl2. LIQUID VOLUME OF WATER CONDENSED, m.ls. Pl3. VAPOR VOLUME OF WATER COHDEIIISED, @ ST.P, cu.ft. Pl4. TOTAL GAS SAMPLED, @ STP, cu.ft. PlS. WEJ:GBT OF GAS SAMPLED, DRY, lba. Pl6. WEIGHT OF GAS SAMPLED, WET, lbs. Pl7. PERcENT ISOKINEXJ:CS

**CON~TION** CONVERSJ:ON FACTORS: Pl8. Pl9. P20. 50 'l EXCESS AJ:R, Jll"TER COLLECTOR 50 'l EXCESS AJ:R, BEFORE COLLECTOR HOISTllRE COHDJ:TJ:ONS BEFORE COLLECTOR. 1 12 60.00 0.312 0.00053 0.870 0.991 0 79.6 2.028 44.52 42.51

96.0 4.55 47.06

3.20 3.42 99.9

1.07 2 12 60.00 0.312 0.00053 0.870 0.991 0 85.0 2.027 45.56 43.07

96.0 4.55 47.62

3.24 3.46 101.6

1.07 3 12 60.00 0.312 0.00053 0.870 0.991 0 90.5 1.903 45.07 42.17

93.0 4.41 46.58

3.17 3.38 99.8

1.06 

# I 

# r [ [ 

# r [ 

# l L [ [ 

# L L [ 

# L &:,; 

# LJletwork Envirom.ntal., Inc.

COMPANY NAME: MICHIGAN DIVISION
- U.S. BlUet COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN U EXIIAUST SAMPLING STAFF: ENGELBARDT / SKI'l'l! SAMPLE NUMBER Pl. NUMBER OF POINTS SAMPLED P2. DURATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, sq. ft. P5. PITOT CALIBRATION FACTOR P6. METER CALIBRATION FACTOR P7. AVERAGE FILTER

**~TURE,** <:leg. 1! P8. AVERAGE METER TEMPERATURE, deg. F P9. AVERAGE METER PRESS=, illches Of water P10. METER VOLUME, ACTUAL READING, cu.ft. P1l. METER VOLUME, @ STP, cu.ft. P12. LIQUID VOLUME OF liATER COIIDENSED, lllls. P13. VAPOR VOLUME OF WATER CO!IDJ!:I!ISJ!:I), f! sn>, cu.ft. P14. TOTAL GAS SAMPLED, @ STP, cu.ft. P15. WEIGHT OF GAS SAMPLED, DRY, l.bs. P16. WEIGHT OF GAS SAMPLED, WET, l.bs. P17. PERCENT

**ISOKI~ICS** CONCENTRATION CONVERSION FACTORS: P18. 50 ' EXCESS AIR, AFTER COLLECTOR P19. 50 ' EXCESS A.IR, BEJ!ORE COLLECTOR P20. MOISTURE CONDITIONS BEFORE COLLECTOR TEST DATE: 5/27/94

1 2 3 12 12 12 60.00 60.00 60.00 0.312 0.312 0.312 0.00053 0.00053 0.00053 o. 870 0.870 0.870 0.991 0.991 0.991 0 0 0 79.6 85.0 90.5 2.028 2.027 1.903 44.52 45.56 45.07 42.51 43.07 42.17

96.0 96.0 93.0 4.55 4.55 4.41 47.06 47.62 46.58

3.20 3.24 3.17 3.42 3.46 3.38 99.9 101.6 99.8

1.07 1.07 1.06 

# I 

# I ( 

# I 

# r [ [ 

# r [ 

# L ! L 

# [ [ i 

# l 

# L [ 

# LNetwork Environmental, Inc. SUMMARY OF EXBAO'ST GAS PARAMETERS

COMPANY NAME: MICHIGAN DIVISION
- O'.S. BRICK COMPANY LOCATION: CORO'NNA, MICHIGAN SOO'RCE NAME: !aLN tl EX!!AO'ST SAMPLING STAFF: ENGELHARDT / SMITH SAMPLE NllMBER Gl. STACK RADIO'S, inches G2. AREA OF STACK, sq. ft. G3. BAROMETRIC PRESSO'RE, in. HG. G4. STATIC PRESSO'RE IN STACK, in. H20 G5 • STACK GAS TEMPERATO'RE, deg. F G6. AVG. SQRT VELOCITY PRESSO'RE OF POINTS SAMPLED G7. PERCENT MOISTO'RE AT TEST LOCATION G8. PERCENT MOISTO'RE BEFORE COLLECTOR G9 • DRY GAS COMPOSITION: % OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN G10. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS • Gll. DRY, @ STP, lbs./cu.ft. G12.**~.** @ STP, lbs./cu.ft. G13. WET, @ STACK CONDITIONS, lbs./cu.ft. G14. MOLECO'LAR WEIG!I'l', DRY, @ STP, lbs./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. G17. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFH STANDARD CONDITIONS, DRY SCFM TEST DATE: 5/27/94

1 19.5 8.30 29.20 0.26- 272 0.496

9.67 0.00 15.87

3.27 

## o.oo 80.87

0.0754 0.0726 0.0513

29.17

2088 17,323 12,236 11,053 2 19.5 8.30 29.20 0.26- 272 0.493

9.56 

## o.oo 15.40

3.20 

## o.oo 81.40

0.0753 0.0726 0.0512

29.14

2079 17,245 12,174 ll,010 3 19.5 8.30 29.20 0.26- 274 0.492

9.46 0.00 15.40

3.00 0.00 81.60

0.0752 0.0725 0.0511

29.10

2075 17,210 12' 122 10,975 

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### Network Environmental, Inc. SUMMARY OF PARTICULATE EMISSIONS COMPANY NAME:: HJ:CHIGAN DIVISION
- U.S. BRIClt COMPANY LOCATION: COR!l'NNA, MICHIGAN SOURCE NAME: : 1ULN f l EXHAUST SAMPLING STAFF: ENGELHARDT / SMITH SAMPLE NllMBER SUNDARD ANALYSIS E1. TOTAL WEIGHT COLLECTED, qrams E2. Ll!S. PARTictJLATE/1000 LBS. GAS, ACTt1AL( 1) E3. Ll!S. PARTic:tlLATE/1000 LBS. GAS, DRY(2) E6. GRAINS/DSCF(4) E7. Ll!S •/BOt1R TEST DATE: 5/27/94

l 2 0.009 0.012 0.0059 0.0075 0.0063 0.0079 0. 0033 0.0042 0.31 0.40

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# LNetwork Environmental, Inc. EMISSION SOURCE SUMMARY STANDARD ANALYSIS
COMPANY HAKE: MICHIGAN DIVISION
- U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE HAKE: KILN tl EXHAUST SAMPLING STAZF: ENGELHARDT / SMITH STACK RADIOS, inches AREA OF STACK, sq. ft. STATIC PRESSURE IN STACK, in. H20 STACK GAS TEMPERATURE, deg. F PERCENT MOISTURE AT TEST

**~ION** DRY GAS COMPOSITION: % OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN DENSITY, WET, @STP, lbs./cu.ft. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: ACFM

EMISSIONS: SCFM SCFM, DRY

LBS. PARTICOLATE/1000 LBS. GAS, ACTOAL(1) LBS. PARTICOLATE/1000 LBS. GAS, DRY(2) GRAINS/DSC1"(4) LBS./HOOR TEST DATE: 5/27/94

19.5 8.30 0.26-

273 9.56 15.56

3.16 0.00 81.29 0.0726

29.14

2081 17259 12177 11013
0.0068 0.0072 0.0038 0.36
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### CALIBRATION DATA 

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### EMISSIONS TEST SAMPLING DATE: 05-27-1994 COMPANY: MI Div.
- U.S. Brick SOURCE: Kiln 11 Exhaust START S02 

### RUN TIME (PPM)

1 07:48 564 2 09:26 595 3 

### 10:50 579

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# [Company: Michigan Division U.S. Brick Location: Corunna, Ml Source: Kiln #1 Exhaust
Date: 5/27/94 Operator: DOE -- Monitor: PSC-302 Sulfur Dioxide Span Value (PPM): 1500 Page#: 1 of 1 Calibration Response, PPM Calibration .. Analyzer

Gas Cone. Direct System Injection

Cal. Error, Drift, %of Span

PPM S0

2 Injection

Pretest Post 1 Post 2 Post 3 %of Span Gas

06:55 07:14 09:05 10:35 11:58 Test 1 Test2 Test 3

0 0 0 0 4 4 o,oo 0.26 0.26

50 50 0.00

244 250 237 250 249 248 0.40 0.86 0.80 0.73

• 768 768

• As Defined By EPA Method, This Value Must Be The Same As The Relevant Direct Injection Value

••

Run Zero and either mid or high calibration gas, whichever one Is closer to actual stack concentration Pretest 0.00 -0.87

Analyzer cal. error,% of span= (dir. In]. cal. response, PPM- cal. gas cone., PPM) x 100% I (span vlaue, PPM): Limit= 2% System Bias, % of Span Post 1 Post2 0.00 0.26 0.00 -0.07

Drift,% of span= (relevant posttest sys. lnj. cal. response, PPM- sys. lnj. pretest cal. response, PPM) x 100% I (span value, PPM): Limit= 3%

**~**

Syslem bias,% of span= (relevant sys. lnj. cal. response, PPM- dir. in]. cal. response, PPM) x 100% I (span value, PPM): Limit= 5%

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**-~ ~**  ---, ----, ,..____, --.., ' Post 3 0.26 -0.13

### FILENAME: USB40527.DTA COMPANY: MI Div.
- U.S. Brick SOURCE: Kiln #1 Exhaust DATA LISTING

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### CHANNEL: PARAMETER: UNITS: SLOPE: INTERCEPT: 00 S02 PPM 1500 0 

# --------------------------------------------------------------------------- 05-27-1994 07:48:04 05-27-1994 07:49:04 05-27-1994 07:50:04 05-27-1994 07:51:04 05-27-1994 07:52:04 05-27-1994 07:53:04 05-27-1994 07:54:04 05-27-1994 07:55:04 05-27-1994 07:56:04 05-27-1994 07:57:04 05-27-1994 07:58:04 05-27-1994 07:59:04 05-27-1994 08:00:04 05-27-1994 08:01:04 05-27-1994 08:02:04 05-27-1994 08:03:04 05-27-1994 08:04:04 05-27-1994 08:05:04 05-27-1994 08:06:04 05-27-1994 08:07:04 05-27-1994 08:08:04 05-27-1994 08:09:04 05-27-1994 08:10:04 05-27-1994 08:11:04 05-27-1994 08:12:04 05-27-1994 08:13:04 05-27-1994 08:14:04 05-27-1994 08:15:04 05-27-1994 08:16:04 05-27-1994 08:17:04 05-27-1994 08:28:26 05-27-1994 08:29:26 05-27-1994 08:30:26 05-27-1994 08:31:26 05-27-1994 08:32:26 05-27-1994 08:33:26 05-27-1994 08:34:26 05-27-1994 08:35:26 05-27-1994 08:36:26 05-27-1994 08:37:26 05-27-1994 08:38:26 05-27-1994 08:39:26 05-27-1994 08:40:26 05-27-1994 08:41:26 05-27-1994 08:42:26 05-27-1994 08:43:26 05-27-1994 08:44:26 05-27-1994 08:45:26 510 518 510 520 546 561 567 552 557 543 557 559 567 566 554 565 558 542 540 554 554 564 556 564 550 555 554 562 551 553 557 579 586 585 585 578 588 584 589 579 595 586 588 582 580 587 582 589

### 05-27-1994 08:46:26 595 05-27-1994 08:47:26 586 05-27-1994 08:48:26 572 05-27-1994 08:49:26 563 05-27-1994 08:50:26 564 05-27-1994 08:51:26 566 05-27-1994 08:52:26 556 05-27-1994 08:53:26 570 05-27-1994 08:54:26 561 05-27-1994 08:55:26 568 05-27-1994 08:56:26 560 05-27-1994 08:57:26 561 05-27-1994 09:26:24 581 05-27-1994 09:27:24 569 05-27-1994 09:28:24 577 05-27-1994 09:29:24 576 05-27-1994 09:30:24 555 05-27-1994 09:31:24 562 05-27-1994 09:32:24 600 05-27-1994 09:33:24 601 05-27-1994 09:34:24 620 05-27-1994 09:35:24 614 05-27-1994 09:36:24 615 05-27-1994 09:37:24 609 05-27-1994 09:38:24 604 05-27-1994 09:39:24 608 05-27-1994 09:40:24 602 05-27-1994 09:41:24 609 05-27-1994 09:42:24 612 05-27-1994 09:43:24 604 05-27-1994 09:44:24 600 • 

### 05-27-1994 09:45:24 586 05-27-1994 09:46:24 611 05-27-1994 09:47:24 608 05-27-1994 09:48:24 612 05-27-1994 09:49:24 611 05-27-1994 09:50:24 610 05-27-1994 09:51:24 611 05-27-1994 09:52:24 605 05-27-1994 09:53:24 538 05-27-1994 09:54:24 335 05-27-1994 09:55:24 359 05-27-1994 G9:59:16 490 05-27-1994 10:00:16 640 05-27-1994 10:01:16 651 05-27-1994 10:02:16 641 05-27-1994 10:03:16 648 05-27-1994 10:04:16 636 05-27-1994 10:05:16 637 05-27-1994 10:06:16 624 05-27-1994 10:07:16 626 05-27-1994 10:08:16 628 05-27-1994 10:09:16 627 05-27-1994 10:10:16 625 05-27-1994 10:11:16 618 05-27-1994 10:12:16 630 05-27-1994 10:13:16 624 05-27-1994 10:14:16 597 05-27-1994 10:15:16 601 05-27-1994 10:16:16 594 ?,C: _/1::':7

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### 05-27-1994 05-27-1994 05-27-1994 05-27-1994 05-27-1994 05-27-1994 05-27-1994 05-27-1994 : 

### 05-27-1994 05-27-1994 05-27-1994 05-27-1994

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APPENDIXC S02 

### ANAL'YZER SPECIFICATIONS & 

### GAS CERTIFICATIONS

### BA-MAK 2/9.87-1- 

### 1.0 Field of**~pplic~tion G~s**  

### Sample Conditioners**~re** 

### used in gas**~nalysis** 

### systems and**inat~llations** 

### to cool**moisture-cont~ining** 

### sample gas sufficiently so that nowhere in the subsequent analysis systems or**inst~llations** 

### does it fallw below its dew point. In**cert~in** 

### measurement tasks it is**necess~ry,** 

### to hold the dew point of the sample gas constant in order to**elimin~te** 

### the effect of water vapor on the measurement result. For applications of this type the proportion of water vapor, held**const~nt** 

### by the electrical**s~mple g~s**  

### conditioner MAK 2, is**t~ken** 

### into**~ccount** 

### on calibration. The Gas Sample Conditioner MAK 2**~y** 

### not be used The explosion-proof**G~s** 

### Sample Conditioner Modei for this. hazardous**~re~s.**



### . K 3-Ex is**avail~ble**[ 

### - r . 

### ' 

# r-

i 2.0 Technical Data Number of individual gas paths Maximum sample gas flow rate of each gas path Operating pressure Sample gas inlet temperature 

### Sample gas inlet dew point Sample gas outlet temperature 

### MAK 2-l

- MAK 2

- accuracy 

### Sample gas temperature indicator

- indicator tolerance Running-in time Dead space per gas path Pressure drop per gas path Power supply (mains) Alternative voltage**Po~er** consumption 

### BA-MAK 2/9.87-l-2 

## M&' 2-l, Type 29 - l -**~~** 

### 2 Type 30
- 2 - 250 l/h at l bar and 20 Degr 

## c 0,15 SCFM at 14 psi and 68 Degr F 0,5 7 

### 2,5 bar 35 psi 140 Degr C 

### I 284 Degr F

65 Degr C 

### I 149 Degr F + 3 Degr C 

### I 37,0 Degr F outlet temperature gas path No. l is 0,5 Degr C 

### I 0,9 Degr F higher than gas path No. 2. 

## +1- 0,3 Degr. C 

## I +1- 0,54 Degr F Digital display indicator for cooling brine temperature with limiting value signal 

## +I- 0,5 Degr 

## c at 0 0 0 0 

### 10 Degr 

## c +1- 0,9 Degr F at 32 0 • 

### 50 Degr F approx. 55 min. approx. 8,36 cubic-inch apprOXa 

### 25 mbar at 250 llh approx4 

### 0,36 psi at 0, 15 SCFM 115 

### v + 107. 

# - 107. (60 +/-2) 

### Hz Code Ol 220 

### v + 107. 

# - 157. (50 +l-2) 

### Hz Code 03 220 

### v + 157. 0 0 • 

## - 57. (60 +l-2) Hz 

### Code 04 approx. 450 VA, 3,9 A at 115 

### v 60 

### Hz approx. 440 VA, 2,0 A at 220 

### v 50 Hz 

### approx. 480 VA, 2,1 A at 220 

### v 60 Hz

### •

**BA-~AK** 

### 2/9.87·1·5 2.1 Nace on standards and soecifications 

### The

**indus~rial** 

### standards and regulations (DIN, VDE, VDI 

### etc.) referred to in this Operating Manual are applicable in the Federal Republic of

**Ge~any.** 

### When using this device outside German Federal jurisdiction, the relevant specifications, standards and regulations applicable in the country where the device is used muse be observed. 3.0 Mode of ooeration and consc=uccion 

### With the description of the mode of operation and construction of the electric Gas Sample Conditioner

**~'** 

### 2, see also the schematic diagram No. 3 898 0042. 3.1 Descrict:ion 

### In the electric Gas Sample Conditioner MAK 2 the sample gas is cooled co +2 Degr C in a heat exchanger. The

**conde~sace** 

### precipitated from the sample gas is

**deposi~ed** 

### in the precipitation vessel (precipitator). The cooling medium used is refrigerant R 12. A compressor compresses the gaseous refrigerant to approx. 101,5 psi,

**dependi~g** 

### on the operating ·conditions. The compressor consists of a pressure case containing a piston compressor driven by an electric motor. DoYnstreaD of this is the condenser, a 

### ribbed pipe heat exchanger, where the refrigerant is liquefied. The heat is 

### dissipated by means of a fan which is switched off at low ambient temperature by a switch controlled by the refrigerant pressure - the fan pressure switch. The pressure of the refrigerant is then reduced by a capillary tube from approx. 101,5
- 29 psi. The refrigerant, with its pressure reduced in this way, is then injected into a heat exchanger 

### coil (evaporator) where it absorbs energy from the sample gas directly via the cooling brine and evaporates again. The compressor takes in the evapOrated refrigerant once core. 

### The evaporator is located, together with

**t~e** 

### heat exchanger through which sample gas flows, in a container filled with cooling brine, the so-called,heat exchanger unit. The actual heat exchanger comprises a spirally wound pipe with connected precipitator and

**conde~sate** drain 

### pipe. The sample gas is cooled by heat transfer to the cooling brine and from this to the refrigerant. Alle three systems "sample gasrt, "cooling brine" and "refrigerant" are he:-::tet:ically separated from one another. 

### The sample gas outlet temperature is controlled by a hot gas bypass

**cont~ol** valve. Depending on the refrigerant pressure in the evaporator outlet, this pressure regulator takes a greater or lesser amount of refrigerant from the condenser and passes it to the compressor via 

### a bypass. As the pressure and temperature of the refrigerant are directly proportional, if the evaporator pressure is set a 31,9 psi the hot gas bypass control valve ensures that the sacple gas maintains a constant

**te~pe~at:ure** in the area of interest.

# "
SA-HAK 2/9.87-1-6 A microprocessor controlled monitoring device with digital display is used to monitor the sample gas outlet

**te~perature** (= 

### cooling brine temperature). This temperature is

**dete~ined** 

### With a sensor immersed in the cooling brine. If the limit value set by the manufacturer (generally 

### 46 Degr 

### F) is exceeded, visual indication is provided by the digital display flashing. A floating contact is available for external fault indication (status signal). !his is connected with the .connecting cable provided. A fault may be present for instance if after the power is

**swicc~ed** 

### on and the lead time has expired, the cooling .brine temperature is not lower chan its sec limit value (see also section 5.2). !he electric Gas Sample Conditioner

**~~** 

### 2 is supplied with one sample gas circuit or with cwo sample gas circuits. Upgrading from one to two sample gas circuits ist

**~possible.** 

### !he precipitated condensate is collected in a separate external condensate vessel or pumped out by the automatic condensate drain unit (see also section 

### 4.2.2). 4.0 Installation and

**connectin~** instructions 

### 4.1 Selecting the installation site and mounting the unit When selecting the installation site, note that the electric Gas Sample Conditioner MAK 2 may only be installed in areas where the temperatures are within the permitted ambient temperature range (see section 2.1). !he Gas Sample Conditioner MAK 2 should be mounted on a wall or in an analysis cabinet as near as possible to the gas sampling point. !he fastening rails supplied with the unit are used for this; they are screwed co the rear wall of the unit (see dimensionsl drawing No. 

### 4 8J.j 1281). !his drawing also shows the hole spacing and diameter for the fastening screws. The maximum permitted inclination of the.Gas Sample Conditioner is 

### • ·. 5 Degrees; !he gas sample conditioner must be protected against direct heat radiation (from the

**sun~** furnaces, boilers etc.) and agains: rain and excessive contamination. It must have sufficient ground clearance to allow space 

### to discharge and empty the condensate. The sample gas lines leading away from the Gas Sample Conditioner may be at any gradient provided that the Conditioner represents the coldest point in the entire measuring system, i.e. the

**te~peracure** 

### does not fall below the dew point in modules and lines in the gas analysis system

**do~~stream** 

### of the Conditioner.

### 1.0 INTRODUCTION The Environmental Products' PSC 302 Portable Monitor System is caoable of simultaneously monitoring two gases in concentrations up to 150,000 PPH from a single sample probe. The gases which can be monitored are NOx, S02, CO and 

# o 2• The system uses electrochemical sensors (cells) that operate on the fuel cell pri'nciole. In a typical sensor, shown in Figure 2, a gas sample diffuses through a semipermeable membrane, and comes in contact l>ith a sensing electrode where it undergoes an oxidation or reduction reaction. This process generates an electrical current output which is linear and directly proportional to the partial pressure of the gas that the sensor is designed to sense. This current is converted to a voltage signal which operates a panel meter or outboard device, such as a chart recorder or data logging system. Before attempting to operate the PSC 302 Monitor, the operator should read and understand this manual in order to obtain accurate results and not damage the monitor. 2.0 SYSTEM DESCRIPTION AND SPECIFICATIONS The PSC 302 Portab1 e

## ~1onitor is designed to be easi1

### y transported by one person. It weighs less than 45 pounds, and is 16" L by 12" Wby 12" H in size. The system will monitor concentrations of S02, NOx, CO or 02, depending on the sensors installed in t"he system. The sample line, probe, filter, and calibration gases are contained in the Accessory Case which v1eighs less than 40 pounds, and measures 20" W by 2g" L by 10" H. The specifications for the monitor which accompanies this handbook are listed in Table I. The gas sample is drawn into the monitor through a heated 1 ine by a sample pump and then into the sample conditioner, see Drawing 751750. Within the conditioner, the gas is rapidly cooled below 45°F to remove moisture, which is expelled through a drain valve. The sample conditioner uses a solid state, thermostatically controlled thermoelectric device to dry the gas being sampled. The sample

1

## 2.0 SYSTEM DESCRIPTION AND SPECIFICATIONS (Continued) then flows through the sample/calibrate valve and the monitor flow meter to the sensors. If an NOx sensor is used (and the sample contains 

# so2), the sample flows through an S02 scrubber before the NOx sensor. Each sensor generates an electrical current which is converted into a voltage signal to drive the monitor meters and other external devices as required. The monitor also provides a 4-20 

## mA current signal for this purpo?e. The PSC 302 monitor uses a 1 to 3 to 10 relationship for its range switch unless an optional analyzer board is installed (see Appendix A). If a 30-4 sensor is installed, it 

## will read 1,000 PPM fullscale in low range, 3,000 PPM in midrange, and 10,000 PPM in high range. An 02 sensor will read 5% full scale in low range, 15% in mid-range, and SO% in high range. To calibrate the monitor, gases of known precise concentrations are connected to the sample/calibrate valve. Using this valve, each monitor channel can be set to zero using a zero gas such as air or N2. After the zeroing process is complete, the valve is cycled to introduce a calibration gas which facilitates adjustment of each channel's span. Calibration gases must be regulated to approximately 5-8 PSIG before applying them to the· monitor input. If

**excessi~e** 

## pressure is applied to the sensors, it is possible that the membrane can be ruptured thus ruining the sensor. 3.0 SYSTEM SETUP 3.1 INSPECTION AND PLACEMENT When the system is unpacked, check for shipping damage, be sure to check all items shipped in the accessory case (such as the sample line, probe and calibration gases). Make certain that the system conforms to the system config-



# .

J uration shown in Appendix A of this manual. Contact the factory if 

## there is any damage or nonconformance before using.

4I . 

## TABLE I PSC 302 SPECIFICATIONS RESPONSE TIME 

# -------------------------------------------------------------------------------------**[~** 

# <2 Minutes to 90% of Full Sea1 e RESPONSE ACCURACY 

## * DRIFT 

## * OUTPUTS RANGES POWER REQUIREMENTS TEMPERATURE ENVIRONMENT (Operating) TYPE OF GAS SAMPLE LINE CALIBRATION FREQUENCY SENSOR TYPE SIZE WEIGHT Linear Within ± 1% in Each Range Overall Accuracy ±2% Zero and Span ±2% of Full Scale 0
- 1 Volt, 10,000 ohms minimum 4 - 20 rnA, 

## 250 ohms maximum XI, X3, X10 (See Appendix A) 115 Vac, 50/60 Hz, 15 amps maximum

# ~ 

# r7

CO Up to 50,000 PPM S02, NOx up to 150,000 

# o

2 Up to 50% PPM

# ·~ (S•• App•odi> A)

# ~ . [J 25 Ft. Electrically Heated, Self Regulating, 20 Watts/Ft.**l~** 

# [ Every 24 Hours of Service Electrochemical PSC 302 Monitor
- 16" x 12" X 

### 12" 

## Accessory Case
- 20" x 29" x 10" PSC 302 Monitor- 45 Lbs. with Cells Accessory Case
- 40 Lbs. 

# r 

# [?

------------------------------------------------------------------------------------ 

# r_r; [**~**

# ~ * Over 24 Hour Period

2B

# 5"~/**~-~** L

## ·- • 

# --**-=-~-. ·~** **~·.** 

## ;.... :.

# .

: ·: :,-. 

## • 

# Scott Specialty Gases, Inc. 1290 COMSERMERE STREET, TROY, Ml48083 (313) 589-2950 FAX: (313) SS9-2134 

### CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS Customer MICHIGAN AJR GAS 311 STOKERDR SAGINAW Ml48604 ANALYTICAL INFORMATION**Ass:~.y** Labor.Jtory Scan Specialty Gases, Inc. 1290 Combennere Troy,**~1l** 48083 Purchase Order MAGPG0470 Scott Project# 553559

Certiflc:d to exceed the minimum specifications ofE.PA Protocol I Procedure# Gl. Section Number 3.0.4 Cylinder Number ALM030474 Ccrtific:ttion**D::~tc** 7·26·93 General Exp. Date Cylinder Pressure 1900psig Pre,·ious Certification Dates None: Acid**R::~in** Exp. 7-26-96 7-26-96 A.'IALYZED CYLil'<'DER Components SulfurDioxide**8J.I:~.ncc** Gas: Nitrogen Certified**Cnnccntr~ttion** 7G8.J ppm Date
Analvtical Uncertaintv• ±1•1. NIST Directly**Tr.~ccable**

•**A.n~l)'tlc..:ll unc~l""..:~.inry**  is**md~Uive** ofusual known m-er sources**v.·h~~~** Jt le:ut includes**rd~ce ~dan:!**  error 1&. precision ofthe menurcmo=n.t procwes.**REFERE~CEST~~ARD** Type CR.\! 1662 Expir:Hion**D:~.te** 2-6-94
L"'STRIDfENTATTON Instrumenc/Modci/Seri:ll # S02: Horiba!OPE-135/56037204 Cylinder Number AAL 19619**L:~.st D:~.tc** **C:~.libr~tct.l** 7-2-93 Conccntntion 948.2 ppm

## SOz in N2**Analytic:~.l** Principle Non-Dispersive: Wrarc:d
ANALYZER READINGS (z-Uro G:u**R·R~fer-ence** Gas T•Test G:u r-Correl:!otion Coefficient) Components ·· First TriJ.t.l An:1lysis Second Triad Analysis Sulfur Dioxide 03/.c: 7-19-93 Response**Uni~;** mv O.Jte: 7-26-93**~onsc** Un1ts: mv Zt-<1.00 RJs9S.90 Tl•!i5.00 ZlzO.OO Rl-9&.90 n•ss.oo R1•9S.90 z:z.-o.oo Tl•S5.00 R2•9&.90 z:z..o.oo n•ss.oo Zj•O.OO TI•S5.00 RJ-9&.90 lj•O.OO TI•S5.00 R.3•9S.90 Av;. Cone. ofCurt. Cyl 76S.J ppm Av;. Cone. ofCwt.. Cyl 7611.3 ppm 

# L-------JII'---------' L-------JI

'-----1 _ Calib**r.:~tion** Cun•c: Conco=n.tl'lltion•A**+Bx~1:'+**Dx.l+Ex r-0.99999 Consl.ant.s! 3•6.743455 o-o.ooot :.:5303 CR.'A 1662 A-o.OOOOS0096 C-Q.ot6-43769 

# """'**"~:.:-·-** ._-.; ::-...**:-~.···-**.• : .'.**Spc:ci:~.l** Notes : :;_:,:: .-",_;;:..- Irthis product il; wed fur Acid Ibin R.ule**CompU:~nct-,** theAcidR11in**E.~.:piution** Dou noted above

- '**··:~· :tppU~**  per -10 CFH**P:.~rt** 75,**App~ndli** II. Othenvbe,lheCenera/£;.pir111ion D(JJe applies..

# AGA Gas, Inc. CERTIFICATE OF ANALYSIS EPA PROTOCOL 

### tl. PERFORMED ACCORDING TO SECTION 3.0.4 FILE NUMBER:

**EPA1~85** 

### CYLINDER NUMBER: CC99248 PRESSURE: 2000 PSI PRODUCTION NUMBER: 03930967 CERTIFICATION DATE: April 28, 1993 EXPIRATION DATE: October 28,

**199~** 

### CERTIFICATION PERIOD: 18 Months CERTH'IED COMPONENT Sulfur Dioxide CERTII!'IED CONC. 

### 2H PPM BALANCE GAS: 

### Nitrogen ANALYZER MAXE/MODEL/SERIALt Therno electron/tO/ 40-17472-170 ANALYTICAL PRINCIPLE: rluorescence REFERENCE STANDARD: MULTIPOINT CALIBRATION 3/{/93

SRM NUMBER Gl'!IS CYLINDER NUMBER CONCENTRATION CC71213 513.7 PPM ANALYSIS 

### tl ANALYST: M.R. DATE:

**~-13-93** 

### ZERO REF. TEST DEVIATION GAS GAS GAS RESULT FROM THE 

## I MV) {!'IV) 

## IMV) {PPM) MEAN {') 0. 70 513.80 242.80 242. t 

### PPM 0.00' 0. 70 513.80 242.80 242. t 

### PPM 0.00' 0. 70 513.80 H2.80 242. t 

### PPM 0.00' MEAN: H2.

**~** 

### PPM ANALYSIS f2 ANALYST: M. R. DATE: 4-27-93 ZERO REF. TEST GAS GAS GAS {MV) 

## I MV) 

## I MV 

## l -.86 511.\10 2H.70 -.86 511.90 2H.70 -.86 511. 90 2H.70 MEAN: H6. 0 PPM DEVIATION RESULT rROM THE 

## I PPM! MEAN {') 246.0 PPM 0.00' 246.0 PPM 0.00' 246.0 PPM 0.00'



# '-~~-~_:,~~--- MICHAEL SICKMILLER QUALITY CONTROL SUPERVISOR

**--------------------------------------------------------------------~/'** ) AG"' G•s In<:

**5-I~** T

**"-'O"CKI~OI** i'!loaO
._.,...,...,.._ **·::"~ ~.lSJ~**  

## , 

# .. /--- i419•d9J-I;4T\

# AGA Gas, Inc.

CERTIFICATE OF ANALYSIS "EPA PROTOCOL 11" ORDERt 12920520 CYLINDER NUMBERS: FF-40999 CERTIFIED CONCENTRATION: 49.47 PPM SULFUR DIOXIDE BALANCE GAS: NITROGEN CYLINDER PRESSURE: 2015 PSI DATE OF CERTIFICATION: DECEMBER 21, 1992 CERTIFICATION EXPIRATION: JUNE 21, 1994**SR~I** 

### INFORMATION: SRM NUMBER 1693A CYL. NUMBER FF-28604 CONCENTRATION 47.6 PPM S02/N2 THIS ASSAY/CERTIFICATION WAS**PERFOR~IED** 

### ACCORDING TO SECTION 3.0.4. THE ANALYSIS AND CERTIFICATION WERE PERFORtlED AT: AGA SPECIALTY GAS. INC. 6421 MONCLOVA RD. MAUMEE. OH 43537 BY MICHAEL SICKMILLER, QUALITY CONTROL SUPERVISOR INSTRUMENTS USED: SULFUR DIOXIDE:

EPA1179

AOA G.u II'IC- .,..21 Moroclo'w• Road Maumee. Qtuo 4.3537 

### THERMO ELECTRON CORP. PULSED FLUORESCENCE MODEL 40 SERIAL 

### I 40-17472-170**CALl~RATl** 

### 12-18-92 

### 7
- 

# ..**~~** MICHAEL SICKMILLER "'" QUALITY CONTROL SUPERVISOR

Fu JJOOJS

# r r

.I



# r

,--: 

### APPENDIXD 

### ' PARTICULATE FIELD DATA f -
I. 

## I

f

### 0
-



## '
. I I



### I Network Environmental, Inc. PITOT TRAVERSE DATA
COMPANY NAME: HICBIGAII DIVISION
- U.S. BRICK TEST DATE: 5/27/94 COMPANY LOCATION: CORUNNA, KICBIGAII SOURCE NAME: KILN tl EXBAUST SAMPLING STAFF: ENGELIIARDT / SKITB RUN NUMBER: 1 ts CARBON DIOXIDE: 3 STACK RADIUS, in.: 19.5 ts OXYGEN: 0 GAS TEMPERATURE, Deg F: 288 ts CARBON MONOXIDE: 16 STATIC PRESSURE, in. 820: -.26 PITOT FACTOR: .87 BAROMETRIC PRESSURE: 28.92 POINT VELOCITY PRESSURE, INCHES OF WATER PT. LOCATION, PORT



### t INCHES 1 2 1 1.71 0.18 0.18 2 5.69 0.23 0.22 3 11.54 0.24 0.26 4 27.45 0.30 0.28 5 33.30 0.30 0.25 6 37.28 0.27 0.25

### i



## ,. ' 

### Network Environmental, Inc. SAMPLING TRAIN DATA
COMPANY NAME: KJ:CBIGAN DIVISION
- U.S. BRICK TEST DATE: 5/27/94 COMPANY LOCATION: CORtJliNA, KJ:CHIGAN SOURCE NAME: KILN 

### t 1 EXHAUST SAMPLING STAFF: ENGZL!IARDT / SKJ:TH SAMPLE NUMBER: 1 IHPINGER BOX t: 1 GAS METER START: 660.702 TYPE OF TRAIN: MDNR-5B FILTER SET t: 34 METER CAL. FACTOR: .991 NOZZLE DIA, 

### in: .3124 PRIM. FILTER t: DH-585 CLOCK TIME START: 7:4 7 VENTURI NUMBER: SEC. FILTER t: BH-585 METER TIME START: 0 CONTROL BOX t: 3072 BAROMETRIC PRESS: 29.20 METER TIME STOP: 1 PITOT CAL. FACTOR: .87 VELOCITY RATE MTR GAS METER PUMP GAS METER STACK PRESSURE PRESSURE READING VAC. TEMP. , F TEMP. PORT POINT IN. H20 IN. H20 CU. l"T. IN. HG IN OUT F 1 6 0.28 2.28 664.150 3.00 80 80 273 5 0.30 2.43 669.777 2.00 80 79 275 4 0.28 2.28 673.460 2.00 80 79 275 3 0.24 1.97 677.260 2.00 81 79 273 2 0.22 1.81 680.260 1.50 81 79 272 1 0.17 1.42 682.155 1.00 81 79 270 2 6 0.27 2.20 686.140 2.00 78 76 271 5 0.25 2.05 690.260 2.00 81 76 270 4 0.27 2.21 693.970 3.00 83 76 271 3 0.26 2.13 697.390 3.00 84 76 272 2 0.25 2.05 702.000 2.50 85 75 272 1 0.18 1.51 705.226 2.00 86 76 268Network Environmental, Inc. SAMPLING TRAIN DATA
COMPANY NAME: MICHIGAN DIVISION
- U.s. BR.ICK TEST DATE: 5/27/94 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: lULN tl EXIIAOST SAMPLING STAFF: ENGEL!IARDT / SMITH

.. SAMPLE NTJM!IER: 2 IMPINGER BOX t: 1 GAS METER START: 705.325 

### i TYPE 01!' TRAIN: MDNR-5B FILTER SET t: 27 METER CAL. !!'ACTOR: .991 NOZZLE DIA, in: .3124 PR.IM. FILTER t: DH-514 CLOCK TIME START: 9:26 VENTURI NUMBER: SEC. FILTER t: BH-574 METER TIME START: 0 CONTROL BOX t: 3072 BAROMETRIC PRESS: 29.20 METER TIME STOP: 1 r PITOT CAL. !!'ACTOR: .87 VELOCITY RATE MTR GAS METER POMP GAS METER STACK PRESSURE PRESSURE READING VAC. TEMP.' I!' TEMP. PORT POINT IN. H20 IN. H20 

### co. I!'T. IN. HG IN OUT p 2 6 0.26 2.12 709.200 3.00 76 76 269 5 0.26 2.13 713.030 3.00 81 76 270 4 0.27 2.22 717.030 3.00 87 77 272 3 0.26 2.15 720.980 3.00 90 78 271 2 0.25 2.07 724.790 3.00 92 79 271 1 0.19 1.60 728.165 2.50 93 79 269 1 6 0.28 2.31 732.310 3.00 90 81 273 5 0.29 2.39 736.480 3.00 93 81 275 4 0.27 2.23 740.540 3.00 94 82 276 3 0.24 1.99 744.300 3.00 95 82 276 2 0.21 1.75 747.830 2.50 95 83 277 1 0.16 1.37 750.884 2.00 95 84 268 

# q;

## ,. I 

## ,- '

r· Network Environmental, rnc. SAMPLING TRAIN DATA
COMPANY NAME: MICHIGAN DIVISION
- U.S. BRICK TEST DATE: 5/27/94 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: KILN j 1 EXBAUST SAMPLING STAFF: ENGELHARDT / SMITB SAMPLE NUMBER: 3 IMPINGER BOX t : 1 GAS METER START: 750.97 TYPE OF TRAIN: MDNR-5B FILTER SET t: 1 METER CAL. FACTOR: .991 NOZZLE DIA, in: .3124 PRIM. FILTER 

### t: DH-562 CLOCK TIME START: 10:50 VENTURI NUMBER: SEC. FILTER t: BH-562 METER TIME START: 0 CONTROL BOX t: 3072 BAROMETRIC PRESS: 29.20 METER TIME STOP: 1 PITOT CAL. FACTOR: .87 VELOCITY PRESSURE PORT POINT IN. H20 RATE MTR GAS METER PUMP GAS METER STACK
1 6 0.27 5 0.29 4 0.28 3 0.23 2 0.21 1 0.16 2 6 0.26 5 0.26 4 0.27 3 0.26 2 0.24 1 0.19 PRESSURE IN. H20 2.08 2.23 2.16 1.79 1.65 1.29 2.03 2.03 2.11 2.04 1.89 1.53 READING CU. FT. 754.800 758.840 762.910 766.350 769.720 772.626 776.430

78.370 784.430 788.530 792.470 796.044 VAC. TEMP., F TEMP. IN. HG IN OUT F

2.50 84 84 274 2.50 86 83 274 2.50 91 83 275 2.50 94 84 276 2.00 96 85 275 2.00 97 86 268 2.50 93 86 274 2.50 96 86 275 2.50 99 87 276 3.00 101 88 275 2.50 102 89 275 2.00 102 89 269

## I Network Environmental, Inc. ORSAT ANALYSIS DATA
COMPANY HAHE: MICHIGAN DrviSION
- U.S. BlUCK TEST DATE: 5/27/94 COMPANY LOCATION: COROIIHA, MICHIGAN 

### ' I SOURCE HAHE: lULH U EXHAUST SAMPLING STAFF: EHGELIIARDT I SMITH DATE OF ANALYSIS: 5/27/94 METHOD: KOLTIPOIHT INTEGRATED SAMPLE

PART CARBON DIOXIDE OXYGEN CARBON MONOXIDE SMPL COHT RON



# • • • FINAL INIT. 

# " FINAL IHIT. 

# " !'INAL IHIT. 

# " 1 1 1 3.4 

## o.o 3.4 19.2 3.4 15.8 19.2 19.2 

## o.o 2 3.2 

## o.o 3.2 19.2 3.2 16.0 19.2 19.2 

## o.o 3 3.2 0.0 3.2 19.0 3.2 15.8 19.0 19.0 0.0 2 2 1 3.2 0.0 3.2 18.6 3.2 15.4 18.6 18.6 

## o.o 

## I 2 3.2 

## o.o 3.2 18.6 3.2 15.4 18.6 18.6 0.0 3 3.2 0.0 3.2 18.6 3.2 15.4 18.6 18.6 0.0 3 3 1 3.0 0.0 3.0 18.4 3.0 15.4 18.4 18.4 0.0 2 3.0 

## o.o 3.0 18.4 3.0 15.4 18.4 18.4 0.0 3 3.0 

## o.o 3.0 18.4 3.0 15.4 18.4 18.4 0.0Network Environmental,**~nc.** LABORATORY AliDILYS:ts REPORT
COMPANY !fAME:**HICB~GAN D:rvJ:S~ON**  - U.S. .BIIJ:CX TEST DATE: 5/27/94 COMPANY LOCATION: CORUNNA, HICl!J:GAN SOURCE !fAME: KILN tl EXHAUST SAMPLING STAFF: ENGELHARDT / SliJ:TB DATE SUBMITTED TO LAB: 5/27/94 ltECEIVED BY: DDE DATE REPORTED FROM LAB: 6/2/94 CRRHTST(S): RSC PARTICULATE**~N** SAMPLE NUMBER 1**--i'~cm.ATE** WEJ:G!I'r GAD!, JIGS.----- CAPTURED WATER LAB SAMPLE ALT 1 ALT 2 IDENT. IDENT. STD. 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS.**~--** 1 DB-585 6.60 10.0 86.0 

### : BB-585 0.00 NW-1 2.50 TOTALS 9.10 0.00 0.00 10.0 86.0 PARTICULATE**~N** SAMP'Ll!! N1lMBER 2

---**PART~cmJI."l'E** lii!!:IG!I'r GlUlf, I!GS.----- CAPTURED WATER LAB SAMPLE ALT 1**~2** IDENT. IDENT. s-ri). 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS. 2 DB-574 8.40 10.0 86.0 BB-574 0.00 NW-2 3.30 TOTALS**~1.70** ll.OO 0.00 10.0 86.0 PARTICULATE**~N** SAMP'Ll!! l!!TJV!!l!l! 3**--PART~CULA-rE** WBIG!I'r GADI, 

## JIGS.---- CAPTURED WATER LAB SAMPLE ALT 1 ALT2 IDENT. IDENT. STD. 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS. 3 DB-562 6.80 9.0 84.0 BB-562 0.00 NW-3 4.00 TOTALS 

## u.so o.oo o.oo 9.0 84.0

# ~ 

# [ [ 

# r l l l (


# l I. 

# l I 

## I APPENDIXE

. CALCULATIONS

.•



# I· ;lrI 

### ! ' Network Environment4l, rnc. CALCULATrON FORMULAs MorsTURE 

### TRAIN CALCULATrONS: M1. BAROMETRJ:C PRESSURE, inches of Mercury K2. DtlRATrON OF SAMPLE, minutes K3. METER CALrBRATrON FACTOR M4. AVERAGE METER TEMPERATURE, degrees F MS. AVERAGE METER PRESSURE, inches of water M6. METER VOLUME, ACTUAL, cubic feet M7. METER VOLUME, STP, cubic feet 530 M7 = K3 

### * M6 

### * ---------- * M4 + 460 M1 

### + .07355 

## * K5



# ------------------ 29.92 MS. LrQUrD VOLUME OF WATER CONDENSED, milliliters K9 • VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet r·· K9 = MS 

### * 0.0474 

# i M10. TOTAL GAS SAMPLED, @ STP, cubic feet M10 = M7 +K9 Mll. PERCENT MOrSTURE M9 M11 = 

### * 100 M10 EXHAUST GAS CALCULATrONS: G1. STACK DrKENsroNs, inches G2. AREA OF STACK, square feet G2 (ROUND) 

# = 3.14159 

### * (DrA/2)•2



# --------------------- 144 wrDTB 

### * LENGTH G2 (RECT.) = 144 G3. BAROMETRJ:C PRESSURE, inches of Mercury G4. STATrc PRESSURE rN STACK, inches of water GS. STACK GAS TEMPERATURE, degrees F G6. AVG. SQRT VELOCrTY PRESSURE OF POrNTS SAMPLED G7. PERCENT MOrSTURE AT TEST LOCATrON G7 = P13 P14 

### * 100Hetwork Environmental, Inc. 

# r CALCULATION l"ORHULAS CONTINUED GB. PERCENT MOISTURE BEl"ORE COLLECTOR G9. DRY GAS COMPOSITION, t02, tC02, tCO, tN2 G10. PERCENT EXCESS AIR AT TEST LOCATION t02
- 0.5 * tCO G10 = 100 *
----------------------------- .264 * tN2 -.t02 

### + .5 *teo G11. DENSITY, DRY, @STP, lbs./cu. ft• •0827 * t02 

### + .1137 * tC02 

### + (tCO 

### + tN2) * .0724 G11 = -------------------------------------------------- 100 G12. DENSITY, WET, @STP, lbs./cu. ft. 100
- G7 G7 G12 • G11 *
---------- 

### + .0465 * 100 100 G13. DENSITY, WET,.@ STACK CONDITIONS, lbs./cu. ft. 530 G3 

### + .07355 * G4 G13 = G12 

### * ---------- * ------------------ G5 

### + 460 G14. MOLECULAR WEIGHT, DRY, lbs./mcle G14 = G11 * 386.9 G15. AVERAGE GAS VELOCITY, feet/minute 1096 G15 = P5 • G6 • ----------- G16. STACK GAS FLOW RATE, ACl"M G16 

# =G2 

## * G15 G17. STACK GAS FLOW RATE, SCl"M SQRT(G13) 29.92

530 G3 + .07355 

### * G4 G17 = G16 

### * ---------- • ------------------ G5 

### + 460 29.92 G18. STACK GAS FLOW RATE, DRY, DSCl"M 100
- G7 G18 = G17 

## * ---------- 100

/ { -7 

## _

_)

## I

1**~-** Network Environmental, Inc.
CALCULATION I!'ORKIJLAS CONTINUED
PARTICULATE TRAJ:N CALCULATIONS: Pl. NUMBER 01!' POINTS SAMPLED P2. DURATION 01!' SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, square feet

P5. P6. P7. PS. P9. 3.14159 

### * (P3/2)•2 P4 =**---------~----------** 144 PITOT CALIBRATION !!'ACTOR METER CALIBRATION !!'ACTOR AVERAGE FILTER TEMPERATURE, degrees I!' AVERAGE METER TEMPERATURE, degrees I!' AVERAGE METER PRESSURE, inches of water PlO. METER VOLUME, ACTUAL, cubic feet Pll. METER VOLUME, @ STP, cubic feet 530 Pll = PlO 

### * P6 

### * ---------- 

## * PS 

### + 460 G3 + .07355 

### * P9 29.92 Pl2. LIQUID VOLUME 01!' WATER CONDENSED, milliliters Pl3. VAPOR VOLUME 01!' WATER CONDENSED, @ STP, cubic feet Pl3 = Pl2 

### * 0.0474 Pl4. TOTAL GAS SAMPLED, @ STP, cubic feet Pl4 = Pll 

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## \.. .'- 

### - 

# IT-D-Hi9 Report ofan... 

# Emission 

# Study performed for... 

# Michigan Division U.S. Brick Corunna, Michigan

. on 

# Various Sources

June 7 & 

## 8, 1995 010.08 

# NetworkEnvironmental, Inc. Grand Rapids, MI !17

# .J

I 

# • J

' oi E:SULTS

ll.1 TABLE 1 PARTICULATE EMISSION RESULTS SUMMARY KILN #2 EXHAUST MICIDGAN DIVISION· U.S. BRICK CORUNNA, MICIDGAN 

### JUNE 7, 1995 Air FlowRate Concentration 

### Mass Emission Rate Sample Time SCFM Lbs/1000 Lbs, Dry 

### Lbs/Hr . ·. 1 09:42·10:45 15,982 0.0010 0.06 2 11:05·12:09 16,425 0.0011 0.07 AVERAGE 16,204 0.0011 0.07

ll.2 TABLE 2 FLUORIDE EMISSION RESULTS SUMMARY KILN #2 MICIDGAN DIVISION· U.S. BRICK CORUNNA, MICIDGAN 

### JUNE 7,1995

·. ·.· Air Flow Rate Concentration ,.· MassEmission Rate · Sample Time SCFM Mg!M'

. .· . Lbs/Hr ...· ... lnlet Outlet lnlet Outlet lnlet Outlet 1 14:10·15:38 13,204 16,337 111.44 0.23 5.66 0.014 2 16:05·17:10 13,336 16,148 110.89 N.D.<ll 5.54 N.D.<'l AVERAGE< 2l 13,270 16,243 111.17 0.20 5.60 0.012 (1) N.D.
- Non Detected at 0.17 Mg!M' (0.010 Lbs/Hr). (2) Tbe outlet averages were calculated using ilie detection limit value for sample 2.
2ll.3 TABLE 3 

### SULFUR DIOXIDE (S02 ) 

### EMISSION RESULTS MIClllGAN DMSION • U.S. BRICK CORUNNA, MIClllGAN 

### JUNE 7 & 8, 1995

·.

. . 

### Concentration 

### Mass Emission Rate Source Sample Date Time. PPM .· Lbs/Hr ··.·.·. ··· Kiln #2 1 617/95 15:00·16:00 539 73.89 

### Outlet 2 617/95 16:31·17:31 445 61.00 

## l AVERAGE 492 67.45 Kiln #2 1 617/95 15:00·16:00 693 82.76



### Inlet 2 617/95 16:31·17:31 576 68.79


# - AVERAGE 635 75.78 

### Holding Room 1 6/8/95 12:43·13:43 

### N.D. N.D. #2 

### Dryer 1 6/8/95 16:56·17:56 3 1.19 (1) 

### N.D. = 

### Non Detected at 1 

### PPM (0.20 

### Lbs/Hr). (2) 

### The mass emission rates were calculated using 13,845 

### DSCFM for the Kiln #2 

### Outlet, 12,061 

### DSCFM for the Kiln #2 

### Inlet, 20,392 

### DSCFM for the Holding Rocm and 40,131 

### DSCFM for the #2 

### Dryer.

3

# l



# l 

# .,

I I


# ..

•


# • •

I

I

I 

### ill. DISCUSSION OF RESULTS The results ofthe sampling are presented in Tables 1 - 6 (Sections IT.1
- IT.6). 

### m.1 Particulate Emissions (Kiln 

### #2) ill.l.1 Particulate Concentrations- The particulate emissionconcentrations on the Kiln #2 exhaust were 0.0010 pounds ofparticulate per thousandpounds ofgas on a drybasis (Lbs/1000 Lbs, Dry) for sample one and 0.0011 Lbs/1000 Lbs, Dryfor sample two. The average ofthe two samples collected was 0.0011 Lbs/1000 Lbs, Dry. ill.l.2 Particulate Mass Emission Rates • The particulate mass emission rates were 0.06 pounds of particulate per hour (Lbs/Hr) for sample one and 0.07 Lbs/Hr for sample two. The average ofthe two samples collected 

### was 0.07 Lbs/Hr. 

### m.2 Fluoride Emissions (Kiln 

### #2) ill.2.1 fluoride Concentrations
- The fluoride concentrations at the inlet to the pollution control device (PCD) were 111.44 milligrams per cubic meter (Mg'M3) for sample one and 110.89 Mg'M3 for sample two. The average inlet concentration 

### was 111.17 Mg'M3• The fluoride concentrations inthe Kiln #2 exhaust were 0.23 Mg'M3 for sample one and non detected at 0.17 Mg'M3 for sample two: ill.2.2 fluoride Mass Emissions Rates
- The fluoride mass rates at the inlet to the PCD were 5.66 pounds per hour (Lbs/Hr) for sample one and 5.54 Lbs/Hr for sample two. The average ofthe two samples was 5.60 Lbs/Hr. The fluoride mass emission rates at the exhaust were 0.014 Lbs/Hr for sample one and non detected at a detection limit of 0.010 Lbs/Hr for sample two. The fluoride collection efficiency ofthe PCD averaged 99.8%. 

## m.3 so. Emission 

### Results ill.3.1 Kiln #2 S02 Concentrations
- The S02 concentrations at the Kiln #2 PCD inlet were 693 parts per million (PPM) for sample one and 576 PPM for sample two. The average of the two samples was 635 PPM. The S02 concentrations on the Kiln #2 exhaust were 539 PPM for sample one and 445 PPM for sample two. The average ofthe two samples was 492 PPM. ill.3.2 Kiln #2 S02 Mass Rates
- The S02 mass rates 

### at the Kiln #2 PCD inlet were 82.76 Lbs/Hr for sample one and 68.79 Lbs/Hrfor sample two. The average ofthe two samples was 75.78 Lbs/Hr. 

### 7

# ,

• The S02 

### mass emissionrates from the Kiln 

### #2 exhaust were 73.89 Lbs/Hr for sample one and 61.00 

### Lbs/Hr for sample two. The average of the two samples 

### was 67.45 Lbs/Hr. The S02 

### reduction efficiency for the two samples averaged 11.0%. 

### ill.3.3 Holding Room S02 

### Emissions
- S02 was 

### non detected at 

### a detection limit of 1 PPM (0.20 

### Lbs/Hr) for the sample collected from the holding room exhaust. ill.3.4 #2Dryer S02 

### Emissions
-TheS02 

### concentrationfor the#2Dryer exhaustwas 

### 3 PPM (mass 

### emission rate of 1.19 

### Lbs/Hr).



## jJ-f

### I



# J 

# J J
_j ill.6.2 HoldingRoomTotalVOC Emissions- TheTotalVOC emissionswere 12.4PPM (1.77 Lbs/Hr) for the sample collected from the Holding Room exhaust.


### IV. SOURCE DESCRIPTION The source tested on 6/7/95 was the exhaustofKiln#2. The kilnis gas fired. The exhaust from the kiln passes through an emission control systemconsisting ofa cooler followed by a mixing chamber and then through a baghouse prior to exhausting to atmosphere through the exhaust stack. Lime is sprayed into the systembetweenthecoolerandthemixingchamber. Thesourcetestedon6/8/95 was theholding room exhaust associated with the #2 Kiln. Duringthe sampling, modular size hickoryridge bricks were fired. The kiln speedduringthe testingwas 12 cars per day. Charge times, brick weight andlime feed rate information can be found inAppendixD. 

### V. SAMPLING AND ANALYTICAL PROTOCOL V.l Particulate The particulate emission sampling was conductedinaccordance withU.S. EPAReference Method 5. Method 5 is an out ofstack filtration method that employs aheated probe and filter (maintained 

### at 250 

### cF plus or minus 25 

### °F). Two (2) samples werecollectedfromthe Kiln #2 exhaust. Each sample was sixty (60) minutes in duration, and had a minimum sample volume ofthirty (30) dry standard cubicfeet. The samples werecollectedisokineticallyandanalyzedfor totalparticulatebygravimetric analysis. All the quality assurance and quality control procedures listed in the method were incorporated in the sampling and analysis. V.2 Fluoride The fluoride emission samplingwas conductedinaccordance withU.S. EPAReference Method 13B. The samples were collected in deionized distilled water isokinetically as described in the method. Each sample was sixty (60) minutesindurationand hada minimum samplevolume ofthirty (30) dry standard cubic feet. Two (2) samples were collected simultaneouslyfrom the inlet and outlet ofthe Kiln #2 PCD. The samples were analyzed for fluoride by specific ion electrode analysis. All the quality assurance and quality control procedures listed in the method were incorporated in the sampling and analysis. 9V.3 Sulfur Dioxide The S02 determinations were performed in accordance with U.S. EPA Reference Method 6C. A Western ResearchModel721·M portable stack gas analyzer was used to monitor the S02 emissions. A heated teflon sample line was used 

### to transport the exhaust gases from the stack 

### to a gas conditioner to remove moisture and reduce the temperature. From the gas conditioner the stack gases were passed 

### to the analyzer. The analyzer produces instantaneous readouts of the S02 concentrations (PPM). Theanalyzerwas calibratedby direct injectionprior

### to thetesting. A span gasof857PPMwas used to establishthe initialinstrumentcalibration. Calibrationgases of222 PPM and 393PPMwereused to determine the calibration error ofthe analyzer. The sampling system (from the backofthe stack. probe to the analyzer) was injected using the 857 PPMcalibrationgas

### to determine the systembias. After each sample, a system zero and system injection of 857 PPM were performed 

### to establish system drift and systembias during the test period. All calibration gases used were EPAProtocol 1 Certified. The analyzer was calibrated to the output ofthe data acquisition system (DAS) used to collect the data. A strip chart recorder was also used to recordthe data as a backup to the DAS. Each sample was sixty (60) minutes in duration. The DAS output, strip chart recorder data, and calibration data can be found in Appendix B. The S02 analyzer specifications and calibration gas certifications can be found in Appendix C.------ ')_, --(::___ ..... "' **~ --~**  ___) Conclonsor Coil Sample Tomporaluro -c

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### r

APPENDIXA


### · PARTICULATE EMISSIONRESULTS & 

### EXHAUST GAS PARAMETERS 

### •



## ·.Network Environmental, Inc. P.O. Box 2021 Grand Rapids, HI 49501 

### SOURCE EMISSION TESTING 

### at MICHIGAN DIVISION, U.S. BRICK CORUNNA, MICHIGAN

t2 KILN EXHAUST

DATE: 6/7/95



# ;:).7 /-Network Environmental, Inc. EMISSION SOURCE SUMMARY STANDARD ANALYSIS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: f2 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT STACK RADIUS, inches AREA OF STACK, sq. ft. STATIC PRESSURE IN STACK, in. H20 STACK GAS TEMPERATURE, deg. F PERCENT MOISTURE AT TEST LOCATION DRY GAS COMPOSITION: % OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN DENSITY, WET, @ STP, lbs./cu.ft. MOLECULAR WEIGHT, DRY, @ STP, lbs•/mole AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: ACFM SCFM SCFM, DRY EMISSIONS: LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL(l) LBS. PARTICULATE/lOCO LBS. GAS, DRY(2) GRAINS/DSCF(4) LBS. /HOUR TEST DATE: 6/7/95

19.5 8.30 0.32-

296 14.64 15.80

3.10 

## o·.oo 81.10 0.0711

29.14

2916 24188 16204 13831
0.0010 0.0011 0.0006 0.07
1. 'ACTOAL' K&ABS AT TR& COaDITIOBS FOOBD AT TB& SAXPLI.G

**~OCATIOB.** 2. "DRY' IRCLDD&S ORLY TR& RATDRAL XOISTOR& TRAT WODLD R& &XITT&D PROX TR& PROCESS. MOliTOR& ADD&D OR SDRTRACT&D BY TR& COLLECTOR IS ROT IRCLOD&D. l. "W&T• IRCLOD&S TB& XOISTDRB AS X&ASOR&D AT TR& SAXPLIRG

**~OCATIDR.** 4. "DSCP' IS DRD&R TOTALLY DRY CORDITIORS, ALL XOiaTO&& &&M09&D.

### Network Environmental, Inc. SUMMARY OF PARTICULATE EMISSIONS COMPANY NAME: MICHIGAN D:rv:ISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: t2 KILN EXHAUST SAMPLJ:NG STAFF: CARGILL/ENGELHARDT SAMPLE NUMBER STANDARD ANALYSIS E 1 . TOTAL 'HEIGHT COLLECTED, grams E2. LBS. PARTICULATE/lOCO LBS. GAS, ACTUAL(l) EJ. LBS. PARTICULATE/lOCO LBS. GAS, DRY(2) E6. GRAINS/DSCF(4) E7. LBS./HOUR TEST DATE: 6/7/95

1 0.0019 0.0009 0.0010 0.0005

0.06 2 0.0021 0.0010 0. 0011 0.0006

0.07

1.**'AC~D•L'** •••••**·~ ~··**  CO.DIT%0.1 FOD•D AT T•a**I·K~LX•G** LOCATIO., 2. 'Dar• I•CLDD&I o•LT Ta& aATDRAL KOIITORK TaAT •oOLD a& KK%TTKD r&OK Ta&**~aOCSII,** KOIITORK ADDED oa**IO~TRACTKD** aT Taa COLLECTOR II aOT IaCLOD&D,**~.** 'WKT• IaCLDDKI Taa KOIITO&a AI KKAIORKD AT Taa**IAK~LlaG** LOCATIOa. 4. 'DICF' II OaDza TOTALLY DRT COaDITIOal, ALL KOIITORK RKKOV&D,Network Environmental, xnc. SUMMARY OF EXHAUST GAS PARAMETERS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: #2 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT SAMPLE NUMBER Gl. STACK RADIUS, inches G2. AREA OF STACK, sq. ft. G3 • BAROMETRIC PRESSURE, in. HG. G4. STATIC PRESSURE IN STACK, in. H20 G5. STACK GAS TEMPERATURE, deg. F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: % OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN GlO. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: Gll. DRY, @ STP, lbs./cu.ft. Gl2.

**WE~,** @ STP, lbs./cu.ft. Gl3. WET, @ STACK CONDITIONS, lbs./cu.ft. Gl4. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole Gl5. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: Gl6. Gl7. Gl8. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM STANDARD CONDITIONS, DRY SCFM TEST DATE: 6/7/95

l 19.5 8.30 28.60 0.32- 298 0.660 14.16



## o.oo 15.30

3.40 0.00 81.30

0.0754 0.0713 0.0476

29.16

2665 23,932 15,962 13,719 2 19.5 8.30 28.60 0.32- 293 0.674 15.11

0.00 16.30

2.80 

## o.oo 80.90

0.0752 0.0709 0.0476

29.11

2947 24,445 16,425 13,943 

# !3cNetwork Environmental, Inc. SUMMARY OF PARTICULATE TRAIN PARAMETERS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: #2 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT SAMPLE NUMBER Pl. NUMBER OF POINTS SAMPLED P2. DURATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, sq. ft. PS. PITOT CALIBRATION FACTOR P6• METER CALIBRATION FACTOR P7. AVERAGE FILTER TEMPERATURE, deq. F P8. AVERAGE METER TEMPERATURE, deq. F P9. AVERAGE METER PRESSURE, inches of water P10. METER VOLUME, ACTUAL READING, cu.ft. P11. METER VOLUME, @ STP, cu.ft. P12. LIQUID VOLUME OF WATER CONDENSED, mls. P13. VAPOR VOLUME OF WATER CONDENSED, @ STP, P14. TOTAL GAS SAMPLED, @ STP, cu.ft. P15. WEIGHT OF GAS SAMPLED, DRY, lbs. P16. WEIGHT OF GAS SAMPLED, WET, lbs. P17. PERCENT ISOKINETICS CONCENTRATION CONVERSION FACTORS: P18. P19. P20. 50 % EXCESS AIR, AFTER COLLECTOR 50 % EXCESS AIR, BEFORE COLLECTOR MOISTURE CONDITIONS BEFORE COLLECTOR TEST DATE: 6/7/95

1 2 12 12 60.00 60.00 0.313 0.313 0.00053 0.00053 0.870 0.870 1.000 1.000 256 256 93.2 92.7 3.233 3.164 58.81 58.19 54.31 53.78 189.0 202

### .o cu.ft. 8.96 9.57 63.26 63.35

4.09 4.05 4.51 4.49 102.8 100.1

1.10 l.ll



### / j.



## - I,._-_ ...



# .-

Network Environmental, Inc. 

### P.o. Box 2021 Grand Rapids, HI 49501 

### SOURCE EMISSION TESTING at MICHIGAN DIVISION, U.S. BRICK CORUNNA, MICHIGAN t2 KILN EXHAUST (FLUORIDE) DA'l'E: 6/7/95Network Environmental, Inc. StJHMARY OF EXHAUST GAS PARAMETERS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: f2 KILN EXHAUST (FLUORIDE) SAMPLING STAFF: BYRD/ENGELHARDT SAMPLE NUMBER G1. STACK RADIUS, inches G2. AREA OF STACK, sq. ft. G3. BAROMETRIC PRESSURE, in. HG. G4. STATIC PRESSURE IN STACK, in. H20 G5. STACK GAS TEMPERATURE, deg. F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7 • PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: % OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN GlO. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: G11. DRY, @ STP, 1bs./cu.ft. Gl2. WET, @ STP, lbs./cu.ft. Gl3. WET, @ STACK CONDITIONS, lbs./cu.ft. Gl4. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. G17. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM STANDARD CONDITIONS, DRY SCFM TEST DATE: 6/7/95

1 19.5 8.30 28.60 0.32- 299 0.675 14.71

0.00 15.30

3.40 

## o.oo 81.30

0.0754 0.0711 0.0474

29.16

2953 24,499 16,337 13,934 2 19.5 8.30 28.60 0.32- 299 0.666 14.65



## o.oo 16.30

2.80 0.00 80.90

0.0752 0.0710 0.0474

29.11

2917 24,200 16,148 13,783


## J

# 3_3Network Environmental, Inc. SUMMARY OF PARTICULATE TRAIN PARAMETERS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: t2 KILN EXHAUST (FLUORIDE) SAMPLING STAFF: BYRD/ENGELHARDT SAMPLE NUMBER Pl. NUMBER OF POINTS SAMPLED P2. DURATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, sq. ft. PS. PITOT CALIBRATION FACTOR P6. METER CALIBRATION FACTOR P7. AVERAGE FILTER TEMPERATURE, deg. F P8. AVERAGE METER TEMPERATURE, deg. F P9. AVERAGE METER PRESSURE, inches" of water PlO. METER VOLUME, ACTUAL READING, cu.ft. Pll. METER VOLUME, @ STP, cu.ft. Pl2. LIQUID VOLUME OF WATER CONDENSED, mls. Pl3. VAPOR VOLUME OF WATER CONDENSED, @ STP, cu.ft. Pl4. TOTAL GAS SAMPLED, @ STP, cu.ft. PlS. WEIGHT OF GAS SAMPLED, DRY, lbs. Pl6. WEIGHT OF GAS SAMPLED, WET, lbs. Pl7. PERCENT ISOKINETICS CONCENTRATION CONVERSION FACTORS: Pl8. SO % EXCESS AIR, AFTER COLLECTOR Pl9. SO % EXCESS AIR, BEFORE COLLECTOR P20. MOISTURE CONDITIONS BEFORE COLLECTOR TEST DATE: 6/7/9S

1 2 12 12 60.00 60.00 0.313 0.313 O.OOOS3 O.OOOS3 0.870 0.870 1.000 1.000 0 0 92.S 97.1 3.073 3.029 SS.90 S7.26 Sl.66 S2.48 188.0 190.0

8.91 9.01 60.S8 61.49

3.89 3.9S 4.31 4.37 96.2 98.8

0.00 

## o.oo

### Network Environmental, rnc. P.O. Box 2021 Grand Rapids, Mr 49501 

### SOURCE EMISSION TESTING 

### at MrCBrGAN DrvrsroN, U.S. BRICK CORUNNA, MrCBrGAN f2 KrLN rNLET (FLUORIDE) DATE: 6/7/95Network Environmental, Inc. SUMMARY OF EXHAUST GAS PARAMETERS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: #2 KILN INLET (FLUORIDE) SAMPLING STAFF: CARGILL/SCHULTES SAMPLE NUMBER G1. STACK RADIUS, inches G2. AREA OF STACK, sq. ft. G3. BAROMETRIC PRESSURE, in. HG. G4. STATIC PRESSURE IN STACK, in. H20 G5. STACK GAS TEMPERATURE, deg. F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: 'i OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN G10. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: G11. DRY, @ STP, 1bs./cu.ft. G12. WET, @ STP, lbs./cu.ft. G13. WET, @ STACK CONDITIONS, lbs./cu.ft. G14. MOLECULAR WEIGHT, DRY, @ STP, lbs./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. G17. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM STANDARD CONDITIONS, DRY SCFM TEST DATE: 6/7/95

1 21.0 9.62 28.60 2.00- 633 0.570

9.74 0.00 17.00

2.40 

## o.oo 80.60

0.0751 0.0724 0.0334

29.07

2975 28,626 13,204 11,918 2 21.0 9.62 28.60 2.00- 614 0.572

8.50 0.00 16.60

2.50 0.00 

## eo .90

0.0751 0.0727 0.0341

29.07

2954 28,423 13,336 12,203Network Environmental, Inc. SUMMARY OF PARTICULATE TRAIN PARAMETERS

COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: #2 KILN INLET (FLUORIDE) SAMPLING STAFF: CARGILL/SCHULTES SAMPLE NUMBER Pl. NUMBER OF POINTS SAMPLED P2. DURATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, sq. ft. P5. PITOT CALIBRATION FACTOR P6. METER CALIBRATION FACTOR P7. AVERAGE FILTER TEMPERATURE, deg. P8. AVERAGE METER TEMPERATURE, deg. F P9. AVERAGE METER PRESSURE, inches ofF water P10. METER VOLUME, ACTUAL READING, cu.ft. P11. METER VOLUME, @ STP, cu.ft. P12. LIQUID VOLUME OF WATER CONDENSED, mls. P13. VAPOR VOLUME OF WATER CONDENSED, @ STP, cu.ft. P14. TOTAL GAS SAMPLED, @ STP, cu.ft. P15. WEIGHT OF GAS SAMPLED, DRY, lbs. P16. WEIGHT OF GAS SAMPLED, WET, lbs. P17. PERCENT ISOKINETICS CONCENTRATION CONVERSION FACTORS: P18. 50 % EXCESS AIR, AFTER COLLECTOR PH. 50 % EXCESS AIR, BEFORE COLLECTOR P20. MOISTURE CONDITIONS BEFORE COLLECTOR TEST DATE: 6/7/95

1 2 12 12 60.00 60.00 0.250 0.313 0.00034 0.00053 0.870 0.870 1.037 1.037 0 0 97.8 98.5 0.727 1.828 26.99 43.19 25.47 40.82

58.0 80.0 2.75 3.79 28.22 44.61

1.91 3.07 2.04 3.24 100.5 100.7



## o.oo o.ooAPPENDIXB 

### ANALY"ZER OUTPUT#< CALIBRATIONDATA



# 3P /_Network Environmental, Inc. P.O. BOX 2021 Grand Rapids, HI 49501 

### SOURCE EMISSION TESTING 

### at MICHIGAN DIVISION, U.s. BRICK CORUNNA, MICHIGAN DRYER DATE: 6/8/95Network Environmental, Inc. SUMMARY OF EXHAUST GAS PARAMETERS
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: DRYER SAMPLING STAFF: SCHULTES/SMITH SAMPLE NUMBER G1. STACK DIMENSIONS, inches G2. AREA OF STACK, sq. ft. G3. BAROMETRIC PRESSURE, in. HG. G4. STATIC PRESSURE IN STACK, in. H20 G5. STACK GAS TEMPERATURE, deg. F G6. AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION G8. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION: % OXYGEN % CARBON DIOXIDE % CARBON MONOXIDE % NITROGEN G10. PERCENT EXCESS AIR AT TEST LOCATION DENSITY AND MOLECULAR WEIGHT OF STACK GAS: G11. DRY, @ STP, lbs./cu.ft. G12. WET, @ STP, 1bs./cu.ft. G13. WET, @ STACK CONDITIONS, 1bs./cu.ft. G14. MOLECULAR WEIGHT, DRY, @ STP, lbs ./mole G15. AVERAGE GAS VELOCITY, feet/min. STACK GAS FLOW RATE: G16. G17. G18. STACK CONDITIONS, ACFM STANDARD CONDITIONS, SCFM

**STAND~** CONDITIONS, DRY SCFM TEST DATE: 6/8/95

1 57.0 16.63 29.00 0.12- 145 0.766

2.23 0.00 17.70

1.60 

## o.oo 80.70

0.0749 0.0743 0.0630

28.97

2909 48,355 41,045 40,131 X 42.0Fii:.ENAM"': 

### USBT567.DTA

**CC~2~~Y:** 

### US 

### Brick 

### I Corunna SOURCE: 

### kilm #2 

# ----------------------------· CE.'I.NNEL: PA..CL'I.l1E

### TER : 

### UNITS: SLOPE: 

### INTERCEPT: 00 S02 PPM 

### 1000 0 

# ----------------------------· 06-07-1995 14:59:10 .,., 565 06-07-1995 15:00:33 546 06-07-1995 15:01:33 535 06-07-1995 15:02:33 558 06-07-1995 15:03:33

**~** 

### 06-07-1995 15:04:33 -1,\._l( 

### 454 06-07-1995 15:05:33 525 06-07-1995 15:06:33 536 06-07-1995 15:07:33 533 06-07-1995 15:08:33 542 06-07-1995 15:09:33



### ~ 06-07-1995 15:10:33 -515 06-07-1995 15:11:33 456 06-07-1995 15:12:33 464 06-07-1995 15:13:33 465 06-07-1995 15:14:33 o->tiJ-'481 06-07-1995 15:15:33 484 06-07-1995 15:16:33 484 06-07-1995 15:17:33 498 06-07-1995 15:18:33 492 06-07-1995 15:19:33 477 06-07-1995 15:20:33 . 419 06-07-1995 15:21:33 536 06-07-1995 15:22:33 584 06-07-1995 15:23:33 "'-"597 06-07-1995 15:24:33 -Y- 

### 596 06-07-1995 15:25:33 615 06-07-1995 15:26:33 616 06-07-1995· 15:27:33 '¥2..)( 

### 4'30 06-07-1995• 15:28:33-5" 190 06-07-1995 15:29:33



## ~JS'y-.182 06-07-1995 15:30:33 183 06-07-1995 15:31:33 449 06-07-1995 15:32:33



### ~24 06-07-1995 15:33:33 595 06-07-1995 15:34:33 I 

### 646 06-07-1995 15:35:34 0

## ,;+k-r661 06-07-1995 15:36:33 682 06-07-1995 15:37:33 694 06-07-1995 15:38:33 704 06-07-1995 15:39:33 681 06-07-1995 15:40:33 497 06-07-1995 15:41:33 768 06-07-1995 15:42:33 845 06-07-1995 15:43:33 872 06-07-199 5 15 : 4 4 : 3 3



# ~' \2\894 06-07-1995 15:45:33 955 06-07-1995 15:46:33 . 932 DATA LISTING

### 06-07-1995 15:47:33 931 06-07-1995 15:48:33 925 06-07-1995 15:49:33 838 

### 06-07-1995 15:50:33 691 06-07-1995 15:51:33 561 06-07-1995 15:52:33 518 06-07-1995 15:53:33 469 06-07-1995 15:54:33 457 06-07-1995 15:55:33 jj_,-'1440 06-07-1995 15:56:33 0" 

### 421 06-07-1995 15:57:33 414 06-07-1995 15:58:33 397 06-07-1995 15:59:33 407 06-07-1995 16:00:51 456 06-07-1995 16:01:51 

# 'sz6 06-07-1995 16:02:51

**·~54** 

### 06-07-1995 16:03:51

**~\** 

### 545 06-07-1995 16:04:51
**~423** 

### 06-07-1995 16:31:28-ltl- 409 06-07-1995 16:32:28 419 06-07-1995 16:33:28 413 06-07-1995 16:34:28 413 06-07-1995 16:35:28 od<'Jr 410 06-07-1995 16:36:28 413 06-07-1995 16:37:28 402 06-07-1995 16:38:28 412 06-07-1995 16:39:28 407 06-07-1995 16:40:28 4 l 2 06-07-1995 16:41:28 328 06-07-1995 16:42:28 500 06-07-1995 16:43:28 527 06-07-1995 16:44:28 533 

### 06-07-1995 16:45:28 .lc 

### 524 06-07-1995 16:46:28 -fo\o:; 

### 529 06-07-1995 16:47:28 531 06-07-1995 16:48:28 542 06-07-1995 16:49:28 538 06-07-1995 16:50:28 524 06-07-1995 16:51:28 460 06-07-1995 16:52:28 420 06-07-1995 16:53:28 427 06-07-1995 16:54:28 428 06-07-1995 1 6 : 55 : 2 8

**~,._,.,** 

### 4 3 3 06-07-1995 16:56:28 cY 

### 433 06-07-1995 16:57:28 427 06-07-1995 16:58:28 435 06-07-1995 16:59:28 430 06-07-1995 17:00:28 440 06-07-1995 17:01:28 384 06-07-1995 17:02:28 557 06-07-1995 17:03:28 601 06-07-1995 17:04:28 598 06-07-1995 17:05:28 ' 591 06-07-1995 17:06:28 

### -.:;r. \.:f

### 5 8 3 06-07-1995 17:07:28 571 06-07-1995 17:08:28 565 06-07-1995 17:09:28 560 06-07-1995 17:10:28 548 

# ;t/z_, 06-07-1995 li:ll:28 486 06-07-1995 **~7:12:28** 

### 451

### 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 06-07-1995 

# - 17:13:28 458 17:14:28 466 17:15:28

**~458** 

### 17:16:28



### ~ 458 17:17:28 17:18:28 17:19:28 17:20:28 17:21:28 17:22:28 17:23:28 17:24:28 17:25:28 17:26:28 17:27:28 17:28:28 17:29:28 17:30:28 460 458 

# 397"

167 206 449 552 564 581 568

**y.\<-~** 

### 568 557 546 546

/**FI~E~~~:** 

### USB568T.DTA**COM?~~Y:** 

### US 

### Brick Michigan SOURCE: 

### kilm 

# -----------------------------· CHANNEL:**P-~~~TER: u~ITS:**  

### SLOPE: INTERCEPT: 00 502 

### PPM 100G 0 

# -----------------------------· 06-08-1995 12:43:32 06-08-1995 12:44:32 06-08-1995 12:45:32 06-08-1995 12:46:32 06-08-1995 12:47:32 06-08-1995 12:48:32 06-08-1995 12:49:32 06-08-1995 12:50:32 06-08-1995 12:51:32 06-08-1995 12:52:32 06-08-1995 12:53:32 06-08-1995 12:54:32 06-08-1995 12:55:32 06-08-1995 12:56:32 06-08-1995 12:57:32 06-08-1995 12:58:32 06-08-1995 12:59:32 06-08-1995 13:00:32 06-08-1995 13:01:32 06-08-1995 13:02:32 06-08-1995 13:03:32 06-08-1995 13:04:32 06-08-1995 13:05:32 06-08-1995 13:06:32 06-08-1995 13:07:32 06-08-1995 13:08:32 06-08-1995 13:09:32 06-08-1995 13:10:32 06-08-1995 13:11:32 06-03-1995 13:12:32 06-08-1995 13:13:32 06-08-1995 13:14:32 06-08-1995 13:15:32 06-08-1995 13:16:32 06-08-1995 13:17:32 06-08-1995 13:18:33 06-08-1995 13:19:32 06-08-1995 13:20:32 06-08-1995 13:21:32 06-08-1995 13:22:32 06-08-1995 13:23:32 06-08-1995 13:24:32 06-08-1995 13:25:32 06-08-1995 13:26:32 06-08-1995 13:27:32 06-08-1995 13:28:32 06-08-1995 13:29:32 06-08-1995 13:30:32 

### 0 0 0 0 0 0 0 0 0 

### 0 0 0 0 0 1 

### 0 0 0 

### 0 0 0 0 

### 0 0 0 0 0 0 

### 0 0 0 

### 0 0 0 0 1 

### 0 0 0 0 

# ·a 0 0 0 

### 0 0 

### 0 0 DATA LISTING

### 06-08-1995 13:31:32 0 06-08-1995 13:32:32 0 06-08-1995 13:33:32 0 06-08-1995 13:34:32 0 06-08-1995 13:35:32 0 06-08-1995 13:36:32 0 06-08-1995 13:37:32 0 06-08-1995 13:38:32 0 06-08-1995 13:39:32 0 06-08-1995 13:40:32 0 06-08-1995 13:41:32 0 06-08-1995 13:42:32 0 06-08-1995 16:56:14 5 

### 06-08-1995 16:57:14 4 

### 06-08-1995 16:58:14 4 

### 06-08-1995 16:59:14 4 

### 06-08-1995 17:00:14 4 

### 06-08-1995 17:01:14 3 06-08-1995 17:02:14 2 06-08-1995 17:03:14 2 06-08-1995 17:04:14 3 06-08-1995 17:05:14 4 

### 06-08-1995 17:06:14 3 06-08-1995 17:07:14 2 06-08-1995 17:08:14 3 06-08-1995 17:09:14 3 06-08-1995 17:10:14 3 06-08-1995 17:11:14 2 06-08-1995 17:12:14 3 06-08-1995 17:13:15 3 06-08-1995 17:14:14 3 06-08-1995 17:15:14 3 06-08-1995 17:16:14 3 06-08-1995 17:17:14 3 06-08-1995 17:18:14 2 06-08-1995 17:19:14 2 06-08-1995 17:20:14 3 06-08-1995 17:21:14 4 

### 06-08-1995 17:22:14 11 06-08-1995 17:23:14 15 06-08-1995 17:24:14 6 

### 06-08-1995 17:25:14 3 06-08-1995 17:26:14 1 06-08-1995 17:27:14 1 

### 06-08-1995 17:28:14 0 06-08-1995 17:29:14 1 

### 06-08-1995 17:30:14 3 06-08-1995 17:31:14 2 06-08-1.995 17:32:14 2 06-08-1995 17:33:14 

## 2 06-08-1995 17:34:14 2 06-08-1995 17:35:14 3 06-08-1995 17:36:14 4 

### 06-08-1995 17:37:14 3 06-08-1995 17:38:14 3 06-08-1995 17:39:14 4 

### 06-08-1995 17:40:14 3 

### 06-08-1995 17:41:14 2 

# -- 06-08-1995 17:42:14 

# - ;L/.:J-- 06-08-1995 17:43:14 

# -

### 06-08-1995 17:44:14 2 06-08-1995 17:45:14 3 06-08-1995 17:46:14 3 06-08-1995 17:47:14 3 06-08-1995 17:48:14 3 06-08-1995 17:49:14 2 06-08-1995 17:50:14 2 06-08-1995 17:51:14 2 06-08-1995 17:52:14 3 06-08-1995 17:53:14 2 06-08-1995 17:54:14 3 06-08-1995 17:55:14 3Company: Michigan Division U.S. Brick -- Location: Corunna, Ml Source:
Kiln #2 -- Date: 6r7/95 -- Operator: BJS - Monitor: Western Research Model 121-M Span Value (PPM): 1000 Page#:

1 of 1 II Calibration Response, PPM Calibration

.. Analyzer Gas Cone. Direct System Injection
Cal. Error, Drift, % of Span PPM S0 2 Injection Pretest Post 1 Post 2 Posl3 %of Span Gas 12:45 13:33 16:18 18:57

Test 1 Test2 Tesl3 0

0

0

0

0

0.00 0.00 222 219

-0.30 .. 393 390

-0.30 . 857 857 830 826 829
-0.40 -0.10 L__ ______ ---- -- ------- • As Defined By EPA Method, This Value Must Be The Same As The Relevant Direct Injection Value •• Run Zero and either mid or high calibration gas, whichever one is closer to actual stack concentration Pretest 0.00 -1.30 Analyzer cal. error,% of span= (dir. inj. cal. response, PPM- cal. gas cone., PPM) x 100%

I (span vlaue, PPM): Limit= 2% System Bias, %of Span Post1 Post2 0.00 0.00 _, . -3.10 -2.80 Drill,% of span =(relevant posttest sys. inj. cal. response, PPM- sys. inj. pretest cal. response, PPM) x 100%

I (span value, PPM): Limit= 3% System bias,% of span= (relevant sys. inj. cal. response, PPM- dir. inj. cal. response, PPM) x 100%

I (span value, PPM): Limit= 5%

"' **~** " ! Post 3Company: Michigan Division U.S. Brick Location: Corunna, Ml Source: Holding Room & #2 Dryer Date: 618195 Operator: BJS Monilor: Western Research Model 121-M Span Value (PPM): 1000 Page#:

1 of 1 Calibration Response, PPM Calibration

.. Analyzer Gas Cone.

Direct System Injection
Cal. Error, Drift, % of Span PPM S0 2 Injection Pretest Posl1 Post 2 Post 3 %of 06:30 06:36 11:30 16:40 16:15 Spun Gas Test 1 Test 2 Test 3 0

0

0

0

0

0 0.00 0.00 0.00 222 221

-0.10 393 387

-0.60 • 857 657 637 637 659 650 0.00 2.20 0.90 • As Defined By EPA Method, This Value Must Be The Same As The Relevant Direct Injection Value •• Run Zero and either mid or high calibration gas, whichever one is closer to actual stack concentration Pretest 0.00 -2.00 Analyzer cal. error,% of span= (dir. inj. cal. response, PPM- cal. gas cone., PPM) x 100%

I (span vlaue, PPM): Limit= 2% System Bias, % of Span Post 1 Post2 0.00 0.00 -2.00 0.20 Drift, %of span= (relevant posltest sys. inj. cal. response, PPM- sys. inj. pretest cal. response, PPM) x 100%

I (span value, PPM): Limit= 3% System bias,% of span= (relevant sys. inj. cal. response, PPM- dir. lnj. cal. response, PPM) x 100%

I (span value, PPM): Limit= 5%

0., > " Posl3 0.00 -0.70

### APPENDIXC ANALY:lER SPECIFICATIONS & 

### GAS CERTIFICATIONS 

# . .



# ;</7

### • BA-MA.'< 2/9 .87-l-l. l.O Field of !::application Gas Sample Conditioners are used in gas analysis systems and installations co cool moisture-containing sample gas sufficiently so that nowhere in the subsequent analysis systems or installations does it fallw below its dew point. In certain measurement casks it is necessary, to hold the dew point of the sample gas constant in order Co eliminate the effect of water vapor on the measurement result. For applications of this type the proportion of water vapor, held constant by the electrical sample gas conditioner MAK 2, is taken into account on calibration. The Gas Sample Conditioner MAK 2 may not be used in hazardous areas. The explosion-proof Gas Sample Conditioner Model MAK 3-Ex is available ' for chis.



## /.fZ...... 

### 2.0 Technical Data Number of individual gas paths Maximum sample gas flow**rat~** 

### of each gas path Operating pressure Sample gas inlet temperature Sample gas inlet dew point Sample gas outlet temperature MAK 

### 2-1

- MAK 2

-**accu~acy·** 

### Sample gas temperature indicator

- indicator tolerance Running-in time 

### Dead space per gas path Pressure drop per gas path**Powe~** 

### SUP.ply (mains) Alternative voltage

Power consumption**BA-~~** 

### 219.87-1-2**~~** 

### 2-1, Type 29
- 1
- MAK 

### 2 Type 30
- 2
- 250 llh at 1 bar and 20 Degr C 0,15 SCFM at 14 psi and 68 Degr F 

### 0,5 7 

### 2,5 bar 35 psi 140 Degr C 

### I 2S4 Degr F



### 65 Degr C 

### I 149 Degr 

### F + 3 Degr C 

### I 37,0 Degr F outlet temperature gas path No. 1 is 0,5 Degr C 

### I 0,9 Degr F higher than gas path No. 2. 

## +1- 0,3 Degr. C 

## I +1- 0,54 Degr F Digital display indicator for cooling brine te::Iperature 

### with limiting value signal 

## +I- 0,5 Degr 

## c at 0 

# ... 10 Degr 

## c +1- 0,9 Degr F 

### at 32 

### 50 Degr F 

### approx. 55 min. approx. 8,36 cubic-inch approx. 25 mbar at 250 llh approx. 0,36 psi at 0,15 SCFM 115 

## v + 10% 

## - lO'i:. 

### (60 +l-2) Code 01 220 

## v + 10% 

## - 15% (50 +l-2) 

### Code 03 Hz Hz 220 

## v + 15% 

# ... - 5% (60 +l-2) Hz Code 04 approx. 450 VA, 3,9 A at 115 

## v 60 Hz approx. 440 VA, 2,0 A at 220 

## v 50 Hz approx. 480 VA, 2,1 A at 220 

## v 60 Hz 

## J:;}j ' i

.> 

# L 

# l**BA·~'** 2/9.87·1·5 2.1 Note on

**standa~ds** and

**s~ecifications** The

**i~dusc~ial** scandards and regulations

**(DI~,** VDE, VDI etc.)

**~efe~red** to in this Operating Manual lre applicable in the Federal Republic of

**Ger~any.** wnen using this device outside

**Ge~an** Federal jurisdiction, the relevant specifications, standards and regulations applicable in 

### ' the country where ehe device is used must be observed. 3.0 Mode of oneration and

**const~uction** With the description of the mode of operation and construction of the elec:ric Gas Sample Conditioner

**~JL'** 2, see also the

**sche~atic** diagram No. 3 898 0042. 3.1

**Desc~iotion** In the electric Gas Sample Conditioner 

### M&' 2 the sample gas is cooled to +2 Degr C in a heat exchanger. The condensate precipitated from the sample gas is deposited in the precipitation vessel (precipitator). The cooling medium used is refrigerant R 12. A compressor compresses the gaseous

**ref~igerant** to approx. 101,5 psi, depending en the operating conditions. The compressor consists of a pressure case containing a piston cocpressor

**drive~** by an electric motor. Downstreac of this is the condenser, a ribbed pipe heat exchanger, where the refrigerant is liquefied. The heat is dissipated by

**mea~s** of a fan which is

**•~itched** off at low ambient te=perature by a switch controlled by the refrigerant pressure - the fan pressure

**s~itch.** The pressure of che

**re:=ig~=~~t** is then reduced by a capilla=y tube froc approx. 101,5
- 29 psi. The

**refrig~rant,** with its pressu=e reduced in this

**~ay,** is then injecced inca a heat exchanger coil (evaporator) where it absorbs energy from the sample gas directly via the cooling brine and evaporates again. The cocpressor takes in che evaporated

**refrig~rant** once more. The evaporator is located, together with the hea: exchanger through which

**s~ple** gas flows, in 

### a container filled With cooling brine, the so-called hea: exchanger unit. The actual heac exchanger comprises a spirally wound pipe with connected precipitator and condensate drain pipe. The sample gas is cooled by heat transfer to the cooling brine and from this to the ref::-ige:-ant. Alle three systems "sample gas", "cooling brine" and "re£rige:-ant" are her.necically separated f:-om one another.. The sample gas outlet

**te~perature** is controlled by a hot gas bypass

**cont~ol** valve. Depending en the refrigerant pressure in the evaporator outlet, this pressure regulator takes a greater or lesser amount of refrigeranc

**f~oc** the condenser and passes it eo the cocpressor via a bypass. As the pressure and temperature of the refrigerant are directly proportional, if the evaporator pressure is set a 31,9 psi the hoC gas bypass control valve ensures that the sample gas maintains a constant

**te~pe=acure** in the area of interest. ··• 

# -·

## .•·· '



# .

·. **BA-Mfl~** 

### 2/9.87-1-6 A

**mic~oprocessor** controlled monitoring device with digital display is used to monitor the

**s~~ple** gas outlet teQperature (= cooling brine teQperature). This temperature

**i~ dete~ined**  with a sensor immersed in the cooling brine. If the limit value set by the manufacturer (generally 

### 46 Degr 

### F) is exceeded, visual indication is provided by the digital display flashing. A floating contact is available for external fault indication (status signal). This is connected with the .connecting cable provided. A fault may be present for instance if after the power is svitched on and the lead time has expired, the cooling .brine temperature is not lover than its set limit value (see also section 5.2). The electric Gas Sample Conditioner

**~~~** 2 is supplied vith one sample gas circuit or with tvo

**sa~ple** gas circuits. Upgrading from one to cwo sample gas circuits isc not possible4 The precipitated condensate is collected in a separate external condensate vessel or puffiped out by the automatic condensate drain unit (see also section 

### 4.2.2). 4.0 Installation and

**connectin~ inst~uctions**  4.1 Selecting the installation site and mounting the unit When selecting the installation site, note that the electric Gas Sample Conditioner

**MJL~** 2 may only be installed in areas where the_temperatures are within the

**pe~itted** ambient temperature range (see section 

### 2.1). The Gas Sample

**Conditioner~~** 2 should be mounted on a wall or in an analysis cabinet as near as possible to the gas sampling point. The fastening rails supplied with the unit are used for this; they are screwed to the rear wall of the unit (see dimensionsl _drawing No. 

### 4 8Jj 1281). This drawing also shows the hole spacing and diameter for the fastening screws. 

### The caximum

**pe~itted** inclination of the 

### Gas Sample Conditioner 

### is 5 Deg::-ees':. The gas sample conditioner must be protected against direct heat radiation (from the sun, fu=naces, boile=s etc.) and against rain and excessive contamination. It must have sufficient ground clearance to allow space to discharge

**a~d** empty the condensate. The saQple gas lines leading away from the Gas Sample Conditioner may be at any gradient provided that the Conditioner represents the coldest point in the entire measuring system, i.e. the temperature does not fall below the dew point in modules and lines in the gas analysis system

**do~~stream** of the Conditioner. 

# )s_3 ! 

## ' L 

# LOperating

### Manual Introduction 

# 1 Principle of Operation 1.1 The Basis, 1 

### Themicroprocessor-based Models 72li\1 and 72li\1D photometric analyzersmeasure, at two discrete wavelengths, the absorbances ofultraviolet radiation (light) by a gas sample. The concentrations ofthe components absorbing the light (absorbers) are then determined from relationships developed through application ofthe ideal gas la':' in 

### concert with the laws ofBouguer, Beer and Lambert. Thus, the absorbance, A, 

### due to 

### a single absorber is, 

## A 

# = [x]k,_ZP RT 

## ' where 

### l is the path length ofthe light in the gas sample, [x] 

### is the concentration (mole percent1) 

### of absorber 

### x, k). 

### is the molar absorptivity of absorber 

### x at the measuring wavelength, A, 

## T and 

## P are the temperature and pressure of the gas sample, respectively, and R 

### is the universal gas constant. For any given system at constant temperature and pressure, the equation can be simplified to: A= 

### Ck,_[x], 

### where C = 

### ZPIRT

### is a constant depending only upon the system ofunits employed. If 

### only one absorber is present, the concentration is easily determined from the absorbance measurement at the single wavelength. If more than one absorber is present, the total 

### absorbance, 

## A.., is the sum of the absorbances by the individual absorbers,

where 

# % is the absorbance at wavelength A due to the 

## iu. absorber and 

### N is the number ofabsorbers. Combining with the previous equation yields: N 

### A).= 

### CLka.[x],. i..l 

## Inthis case withmore thanone absorber, themeasurement ofabsorbance atjustone wavelength is not sufficient to 

### determine the concentrations: there is only one
1 For an ideal gas, mole pe:cent is equal to volume percent. At the nor.nal operating conditions of Ute analyzer, be real gas 1:1i.xture de,iates from ideal behaviourby less than OS percent 903.4502 

### Rev. 2 

### 10!)€ratingManual Introduction 

### singlerack-mountenclosure. For theModel72l)!:l'Y,' 

### a..."l additional cabinetis required to acco=odate the opacal 

### bench with 

### a

**long-p~th** 

### measuring cell. Two wavelengths are used-- one which is absorbedby

### SOz is usedfor the measuring waveleng-th (285 nm) and one which is not absorbed by 

### 802 

### or other components normallyin the gas sample streamis used as a reference wavelength (585 nm). The sample flows through the measuring cell while the reference cell contains only nonabsorbing gases. As the chopper wheel rotates, a flash ofradiation passes through the measuring filter to the beam splitter. M..er 

### a briefperiod, a flash ofradiation passes through the reference filter to the beam splitter. These flashes ofmeasuring and reference radiation contim:.e at a nominal frequency of 52 times per second per filter. The beam splitter directs halfthe radiation through the measuring cell and halfthrough the reference cell to the two detectors which develop electrical signals proportional to the amount ofradiationthatimpinged on the detectors. The detector signals are demultiplexedinto two measuringsignals andtwo reference signals. The reference signals are used to automatically control the gain of each detector to independently compensate each pathfor optical contamination. The detector signal developed from the measuring wavelength radiation that paSS!=S through the reference cell is used to control the current to the ultraviolet source. The two detector signals developed from the reference wavelength radiation that pass through the measuring and reference cell are used to produce an analyzer output signal that is proportional to the 

### 802 

### concentrationin the measuring cell. 

# 2 Features • 1\<licroprocessor-based The operation of the analyzer, calculations, data manipulations and user interface are all controlled by two on-board microprocessors. 

### • Two Cell Lengths Two cell lengths are available. For the higher concentrationrange (0 to 5000 p:p!Il 

### 802), 

### the .Model 721M typically uses a (standard) 35.0 em cell mounted wit...1Un 

### the same enclosure as the electronics. For the lower concentration range (0 to 1500 ppm 

### 802) 

### the Model 72LMD uses a (standard) 100.0

# = cell which is mountedin a separate cabinet. 

### • Auto Calibration Automatically adjusts the calibration of the analyzer using calibration gas mi1:tures. The Auto-Calibrationfunction maybe initiated on co=andbythe user, at user-speci£ed time intervals or, by a remote, dry 

### (potential free) contact closure.

903.4502 F.ev. 2 

### 3 1994-01-07

**~·_....** 

## I 7 '7 L

• 

# ••



# •



# ' ,. t;·

1 

## '
.

**-~**

### OperatingManual Introduction 

### equation but

## N unknown concentrations. The solution to this problem is to make absorbance measurements at additional wavelengths to develop a system oflinear equations: N



### A~.



## 1 = 

## C

# L k,._1

### [x]; , i•l N 

### AIC! = 

### C:[k.l.2[x],, i•l N



### A~.m = 

### C

# L kD.m[x], , i•l 

### where 

### m is the number ofdiscrete wavelengths at which the absorbance measurements are made. Provided onlythat

### m is equal to or greaterthan

### N, this system of equations canbe solved using standard methods oflinear algebra. In 

### lieu of determining the concentrations ofadditional absorbers, measurements at additional wavelengths at which itis known that 

## all components in the gas sample 

### do 

## not absorb maybe used 

### to compensate for contamination ofthe optical path and ageing ofthe radiation source. 

# 1.2 The Implementation The Models 721M and 72lMD Analyzers are comprised ofa single ultraviolet line source, a chopper wheel containing two interference filters, a beam splitter, one measuring cell, one reference cell andtwo matched photodetectors, asisindicatedin 

# :::r----- ________**::~~:~:_~~~-------** ! I Measuring Cell 

## !Splitter 

## L •••• 

# .·i______ ------------------------- -· i 

## ~-I Detector 1 M2



# ~---f>---:

**~--{>--1** 

# I

**-~-I** R2

1 

# -1 M1 Detector 1



## -~-I A1 Gain I I I I



# ~--{>---~---- 1 Measunng

**~**

# __{>__1:Signal I I I I

**---~---------------** I I



# -~2*-,' I 

# F=CJ

# r.-

**S:~n:!''l!** t;:o!'tr.oL ___________________ 1

Source Filters 

### the block diagram. For the Model 72li"\1, 

## all components are contained 

### within a
903.4502 

### Rev. 2 

### 2'. 72L"\1/i2l:M:D Operating Manual 

### Introduction 

### • Calibration Gas SolenoidValve Control Up to four solenoid valves 

### can be controlled by the analyzer. One of the outputs is reserved for the zero gas. The length of time that each solenoid valve is On is determined by a user-adjustable timer. There is one timer for each output. Each ofthe outputs for controlling the solenoids may be turned Offby the user if

### it

### will not 

### be used. A timer maybe started manuallybythe user or automatically during the Auto-Calibration sequence. • .Analog Output Channels There are four independent output signal channels. Each channel consists of a voltage output (which can 

### be set to 

### 0.1 V, 

### 1 V or 

### 10 V full-scale) and an· optional isolated 

### 4 to 

### 20 mA current output. Within 

### a channel, either the voltage outputorthe currentoutput,butnotboth,may

### be calibrated. Thefullscale concentration for each output channel may be set by the user to any value within the operating range ofthe analyzer. • True Dual-Range Capability The assignment ofthe concentration signal to two different output channels which have different full-scale ranges provides simultaneous dual-range outputs. 

### • Status Relays There are two independent sets ofSPDT (Form C) dry (potential free) relay contacts. One set ofcontacts indicates when calibration ofthe analyzer is in progress. The second set is configured for fail-safe operation and indicates if 

### the self-diagnostic system ofthe analyzerhas detected a fault. • Dilution Air

### Correction (optional) Adjusts the S02 

### concentration measuredby the analyzerto a reference excess air 

### conditionbased on the concentration ofoxygen (02) 

### in the sample. The 0 2 

### content ofthe samplemaybemeasuredbyanoptional paramagnetic0 2 

### sensor installecj. within the Model 

### 721M analyzer enclosure or by a separate, independent 0 2 

### analyzer. • Mass 

### Flow Calculation (optional) 

# 3 Calculates the volumetric flow rate ofthe process stream and mass flow rate of

# so2 (or sulfur) in the process stream. ·Input signals representative ofthe process stream temperature and velocity are required for the calculation. 

# Technical Data These performance characteristics are based on operation with factory-set filtering time constants, a 

### 35.0 em path length for the Model 

### 721M, a 

### 100.0 em path length
903.4502 

### Rev. 2 

### 4 1994-01-07 

# )5'7 l I L

l



# :.,
...



### l l.::


### ! 

## ·t



# .

-

## (--- Operating Manual Introduction 

### for the Model 72EYID, and the gas sample in the cell at 25°C (77°F) and a pressure of 101.325 kPa (760 =ofHg, 14.696psia). 

### Measuring Range (ppm) 

### 721.!."1 

### 802 0 to 

### 5000 

### Noise Level (ppm SOz) 

### 721M Typical: 

### Maximum: :!:0.25 :!:0.5 

### Constant-Temperature Zero Drift (ppm SO,Iday) 

### 72L.'ID 0 to 

### 1500 72L1\1D :!:0.1 :!:0.2 72Li\l 72L1\1D :!:0.5 :!:0.2 

### Ambient-Temperature Change Drift (ppm SO,ICelsius degree) 

### 721M 72L.'ID T:ypical: :!:0.25 :!:0.1 

### Maximum: :!:0.5 :!:0.2 

### Linearity :!:0.5 percent of any selected full-sr.ale range up to:**72l.J.~** 

### 1000 ppm 

### Sensith,ity (ppm) 

### 721M 0.5 

### Accuracy**72l.J.~** 

### 300 ppm**72L~** 

### 0.2 T;rpically, better than :!:1 percent of full-scale. 

### Analog Outputs Four (4) output channels, each with a voltage output and a current output. Either, butnotboth,may

### be calibrated. Voltage: 0 

## to 0.1 V, 0 to 

### 1 V or 0 to 

### 10 V Uow impedance source, not isolated) Current: 4 to 

### 20 m.A. 

### (0 to 

### 1000 

## n load, isolated)self-poweredorlooppoweredUoop powerbyuser).
9{)3.4502 

### Rev. 2 

### 5 Output 

### Ranges Any full-scale within the measuring range ofthe analyzer. Set by user. 

### Cell Construction Standard 316 stainless steelbodywith quartz windows. Othermaterials available to suit applications. 

### Power Requirements 50 W for analyzer only. 120 VAC (105 to 132 VAC), 50/60 Hz 220 VAC (200 to 264 VAC), 50/60 Hz 

### Ambient Limits 15 to 

### 35°C (59 

## to 95°F) 5 to 

### 95 percent relative humidity, noncondensing. 

### Dimensions 721M Standard 19-inchrack-mount enclosure, 178

# = (7 in) high and 597 = (23.5 in) deep. 72l.MD The above enclosure plus an opticalbench cabinet: 197 = (7.75 in) high by 264 

# = (10.375 in) wide by 1238

# = (48.75 in) long. 

### CommunicationPorts One RS-232 port used for service. Of the two RS-422 ports, one is used for co=unicationsbetweenthemicroprocessors and the other is reserved. 

### Speed ofResponse Determined by digital filtering time constant and sample gas flow rate. Time constant can be changed byuser.

1994-0l-D7



## ;_f6

# I. 

# INTRODUCTION Thermo Environmental Instruments' Inc. Model 42H Chemiluminescence 

### NO-N02

### -NO. Analvzer 

## is a second generation analytical instrument capable of measuring 

## oxides of nicrogen at levels from sub parts per million to 5000 parts per million. The Model 42H generates three continuous signals of

### NO, NOz (NO.-NO), and 

### NO•. 

### J. Compared to other types of source chemiluminescence

## analy;~rs, the Model 42H offers the following significant advantages: 

# I 

# l 1 

# ] ] • Increased sensitivity • Linearity through all r<1Ilges • Microprocessor control and operation • Simplicity ofoperation • Fa.St response·time • Independent 

### NO-N02

### -NO. ranges • Rep!ac,sable converter cartridge • Teflon diaphragm sample pump The microcomputer circuitry upon which the Model 42H is based eliminates many disadvantages inherent in analog systems and provides for increased stability, accuracy, and flexibility. Digital computations are insensitive to drift with time or temperature, therefore sources of instrument drift or error due to the eleccronics are minimized. Thermo Environmental Instruments is pleased to supply this Chemiluminescence 

### NO-N0 2- 

### NO. analyzer. We are committed to the. manufacture of instruments exhibiting high standards ofperformance and worklnanship. However, we are prepared and eager to be of service if any problems are encountered in the use of this analyzer. 

## ) PR.L'.'CIPLE OF**OPER~TION** 

# I 

# I I I 

# I The Model 42H Chemiluminescent Analyzer utilizes the reaction of nitric oxide 

### (NO) with ozone as its basic principle. Specifically: 

### NO+ 

### 0 3 

### -------+ 

### N0 2 + 

### 0 2 + 

### hv
The sample is drawn into the Model 

### 42H by an external pump. After it reaches the reaction chamber, it mixes with ozone which is generated by the internal ozonator. The chemical reaction above then**tak~s** 

### place. This reaction produces a characteristic luminescence with an imensity proportional to the concentration of 

### NO. Specifically, light emission results when electronically excited 

### N02 

### molecules decay to lower energy states. The light emission is detected by a photomultiplier tube, which in turn generates a proportional electronic 

# ;f1 '•
• 

## •



## • •
' :• 

# I 

# I i-------- ---- 

## -- ----·- 

## -- ------------- 

### I. Introduction signal. Tne ekcc-onic signal is processed by the microcomputer into a NO concentration reading. To measure the NO, (NO 

## + NOz) concentration, N02 

### must be transfonned to NO prior to reaching the reaction chamber. Tnis transfonnation takes place in a stainless

**st~l** 

### converter heated to approximately 625 "C. Upon reaching the reaction chamber, the converted molecules along with the original NO molecules react with ozone. The resultina 

## "' signal represents the NO, reading: A so!e:1oid is used to switch the Model 42H between .the NO, mode, where the sample passes through the stainless

**st~l** 

### converter, and the NO mode, where the sample bypasses the stainless

**st~l** 

### converter. The N02 

### conce:1tration is determined by subtracting the signal obtained in the NO mode from the signal obtained in the NO, mode. NO -NO= NO X 2 

### :I:.'<STRlii\fE:".l' 

## OVERVIEW The ins:rument overview (see Figure I) 

### can be conveniently discussed by separating it into the following operational components. Photomultiplier Cooler Tne thermoelectric cooler houses the photomultiplier tube (PMT). The PMTis ofthe multialkali type 

### in order to have the infrared se:Jsitivity required to detect N02 

### luminescence. Tne PMT is cooled to approximately -4 

### "C to reduce dark current and increase instrument sensitivity. Tne control circuitry and power source for the cooler is located on the power supply board. Reaction Chamber Tne reac:.ion chamber subassembly is an integrdpa....--r ofthe photomultipliercooler assembly. It is a two piece 24 carat gold plated assembly which design allows for ease ofcleaning and mainte:1ance. In this reaction chamber, the sample reacts with ozone producing excited 

## NOz which decays giving off a photon ofenergy. The reaction chamber is heated and controlled to approximately 50 acto ensure the greatest instrument stability. A thermistor mounted on the reaction chamber is used as the temperature sensor and the heating mechanism is a resistor with AC current passing through it. Tne temperature control circuitry for the reaction chamber is located on the temperature control board. Also housed in the reaction chamber assembly are the sample capillary (5 mil) and the ozone capillary (10 mil). 

### 1"0, Con;-erter The NO, con\·errer consists of a stainless steel cartridge surrounded bv a band heater with a type 

# K thermocouple inserted into a clamping rin-g. This cartridge is housed in an insulated converter box. The stainless steel convener cartridge is heated to approximately 6:::5 ac in order to convert NOc to NO. The temperature control circuitry for the convener 

### /

**{-c~,**

# ] 

# ] 

# J J J J l 

# - J l 

# - J lI 

# - l


# - l 1
. 1 • 

# ]
J 

# II. SPECIFICATIONS

Ranges Noise Detection Limit Zero Drift (24 Hour) Span Drift (24 Hour) Rise, Fall Times (0-90%) Linearity Sample Flow Rate . Bypass Flow Rate Vacuum Power Requirement
Physical Dimensions Weight Outputs 0-!0, 20, 50, 100, 200, 500, !000, 2000, 5000 PPM 25 PPB 50 PPB 50 PPB 

## +I· I% Full Scale 2.5 seconds NO 5.0 seconds NO, 

## +I- 1% Full Scale 25 cc/min. 250 to 1100 cc/min. 28.5" Hg 500 Watts 115+10Volts 220 

## ± 20 Volts 

### 50160 Hz 

### 17"W X 

### 8 3/4"H X: 

### 23"D 70 Lbs. (including external pump) NO,**N~.** 

### NO, Selectable Voltage 4-20 rnA, RS-232



### II-I 

## )b/

# J



# i , 

# J 

# l • 

# J

I 

### ' -,

I ;;J 

# J J The Thermo Environmental Inst=umer.ts Inc. Model 48 has been designated by 

### the United States Environmental Protection Agency (E?A) as a Reference Method.for the measurement of ambient concentrations of carbon

### Monox~de pursuant

### ~o~ith the requirements defined in 40 CFR Part 53. DESIGNATION REFERENCE METHOD**NU~3~** 

### RFCA-0981-054 EPA DESIGNATION DATE Sept. 23, 1981 The Thermo Electron Hodel 48 co Analyzer meets the EPA designation method requirements

## ~o~hen operated

## ~o;ith the follo;.;ing pa!:ameters:**R~'lGE:** 

### LINE VOLTAGE**R~'lGE:** 

### TEY.PERATU"RE**R~GE:** 

### TIME CONSTANT 0
- 50 PPM 105
- 125 VAC 20
- 30 DEGREES CELSIUS 30 SECONDS With or**~o~i~~out** 

### the following options: 48-001 48-002 48-003 Particulate Filter 19" Rack Mountable Configuration Remote Activation of Zero and Span The analyzer must be operated and maintained according to the operation and service Manual to conform to the EPA designa

### tion**require~ents.**

# j 

# J j j j 

# J ] 

# J J 

# J J J J J ] ] J The

**ad~antages** 

### of

**t~e** 

### Medel 43 are appreciable

**~hen** 

### compared tc a.t:alog systerls whe=e eac:: co::-rec'ticn made to the .lnstrument

**c~~~u~** 

### requires not

**c~ly t~e**  **appro~=iate** 

### transducer, but also a 

### c:::t;:er:sat.icn ci::-cuit w·hic:h 

### may neeC. to

**ha~:e** 

### a particular non**li~ea= ci~cuit**  

### which may need to have a particular non-linear

**c~a=ac~eristic** 

### (as is the case for the effect of pressure and

**t~~pe=at~re cha~9es**  

### en
**inf=are~** 

### absorpti?n m7asurements). Analog

**d~agncst~c func~.lons**  

### also

**requ~re** 

### more **c.1rcu~try** 

### thereby increas

### ing both complexity and cost while decreasing reliabilitv. Data averaging in analog systems is usually done at considerable extra ccst

**wit~** 

### a separate
**instr~illent** 

### connected to the output of the 

### basic analyzer. In contrast, the Model 48 has been designed to

**perfor~** 

### a large variety of tasks by utilizing appropriate information stored in the system's program memory. For example, the microcohlputer is used to process signals from both a pressure and temcerature transducer to make corrections to the instrument output, resulting in co concentration measurements which are unaffected by changes in the temperature or pressure of the gas being sampled. Both linear and non-linear corrections are handled with equal ease. In addition, many diagnostic functions can be selected through the use of front panel pushbutton

**s~itches** 

### (Figure I-1). User selectable program options include: settable

**ti~e** 

### resuonse for data

**s~oothing;** 

### one hour averaged value which may be set for continuous output at a standard secondary pair of output terninals, or can be set to interrupt the primary output 

### briefly every hour, or can be de-activated. These options are

**sta~dard** 

### with every instrument and are selected by setting s-.-itches on the front panel of the instrument.

**The~o** 

### Enviror.mental
**Instru~ents** 

### Inc. is pleased to have 

### supplied you with a Medel 48. We are **co~~itted** 

### to the manufacture of instruments exhibiting high standards of

**~~ality perfo~­**  

### a::ce, a::d w·orkwanship. We are prepared and eaga= to be of serv

### ice to ycu in the use of this
**instr~~ent.** 

### A.
**F~INCIFLE** 

### OF

**OP~~TION** 

### CF

**·r~~** 

### GAS 

### FILTER
**C~~~-LATION** 

### SPECTROMETER The techniaue of Gas Filter correlation (GFC) offers improved s;;ecific{ty and sensitivity over conventional non

### disoers:ve infrared (NDIR) techniques. GFC spectroscopy is based

**uco~ cc~oarison**  

### of the detailed structure of the infrared absorption

**s~eStrun** 

### of the measured gas to that of other gases also 

### present :n the sam;:>le being analyzed. The technique is implemented tv using a high concentration sample of the measured gas, i.e.,

**cc~** 

### as a filter for the infrared radiation transmitted

**throug~ ~he**  

### analyzer, hence the

**te~** 

### GFC. I-4 j
I
't.



# r L 

# I[l

# rl L 

# 1k_

# 3 

# rl •

# J

J J 

# J J J

I j

# ! j 

# J 

# j J I The 

### basic components of the GFC 

## co

**spect~orneter** 

### are shown 

### in Figure I-2. Radiation from an IR source is chopped and then passed through a gas filter alternating

**bet~een** 

### CO and N2 due tc rotation of the filter

**~o·heel.** 

### The radiation then passes through a narrow bandpass interference filter and enters a multiple optical pass cell where absorption by the sample gas occurs. The IR radiation then exits the sample cell and falls en an IR detector. The CO gas filter acts to produce a reference beam which cannot be further attenuated by CO in the sample cell. The N2 side cf the filter wheel is transparent tc the IR radiation and therefore produces a measure beam which can be absorbed by co in the cell. The chopped detector signal 

### is modulated by the alter-. nation between the two aas filters with an amolitude related tc the concentration cf CO-in the sample cell. Other gases do net cause modulation of the detector signal since they absorb the reference and measure beams equally. Thus the GFC system responds specifically tc co. With the improved rejection cf interferences afforded by the GFC technique, it is possible tc increase the sensitivity cf the analyzer. This is achieved by the multiple pass optics (White cell) used in the sample cell which leads tc a large path length, and thus an improved sensitivity, in a small physical space. This allows full scale sensitivity

**do~o~** 

### to 1 PPM with a lower detectable limit (LDL) of 0.1 PPM tc be achieved. B. INSTRUMENT DESCRIPI'ION The instrument can be mcst conveniently discussed by separating it into the following operational components (Figure I-3): 1. Ootical bench 2. Correlation wheel and chopper motor 3. Source and source power supply

**~-** 

### Detector, preamplifier, and bias supplies 5. Input signal conditioning board 6. DC power supply 7. Microconpute= 8. Temperature controller 

### 9. Flew components

**(pQ~p,** 

### valves,

**flo~oweter,** 

### and plumbing) 10. Temperature and pressure transducers



### I-5

# ] j 

# J ] 

# ] 

# J ] C. SPE:CIFICATIONS Ra.nges 0-1, 2, 5, 10, 500, 1000 PPM 20, so, 100, 200

## ' Noise 0.05 PPM**R~S** 

### - with time constant of J0 seconds Minimum Detectable Limit 0.10 PPM Zero Drift, 24 hours +/- 

### 0.2 PPM Sp•an Drift, 24 hours 

### +/- 1% Full Scale Rise, Fall Times (0-95%) 1 Minutes (at 1 lpm flow, 30 second response time) Precision +/- 

### 0.1 PPM Linearity +/- 

### 1% Flow Rate 0.5 - 2 lpm Rejection Ration Negligible interference from water and C02. Operating Temperature Performance specifications maintained over the range 15-J5°C (may be operated safely over the range 5-45°C) . Power Requirements 105
- 125 VAC, 60 Hz 220
- 240 VAC, 50 Hz 100 Watts Ph¥sical Dimensions 17''W x 8 3/4"H x 2J''D Weight 45 lbs. Dua:L outputs (Standard) Individually selectable to 0-lOmv, o-100mv, o-1v, o-sv, 0-lOV, digital display, 1 hour integrated value. other outputs available upon request (4-20ma) l 

# ' ' r. 

### L ; 

# L 

# L

f L 

# I ( 

# LL {

# ,**~~.·**

# '··-~·



# • SECTION 3 SPECIFICATIONS Model 51 Total Hydrocarbon Analyzer Petector Type Minimum detectable Auto igniter Flame out safety Noise Drift Repeatability Accuracy Range Auto Ranging Temperature Sample Sampling Rate Detector Flow Rate Response Factor Response Time outputs vacuum fluorescent

Display Analog Flame Ionization. 0.1 ppm. (independent of gas). electronic, processor controlled. solenoid shuts off hydrogen fuel on flame out and alarms. less than 1% F.S. less than 1% in 24 hours. 2% of reading± 0.1 ppm. 2% of reading plus span gas accuracy ± o .1 ppm. 0.1 ppm to 10,000 ppm.(for propane). Covers total instrument operating ranges automatically. 200 degrees 

## c. Controlled by microprocessor with readout on screen. approximately 2.5 L/min. approximately 30 mL/min. Front panel settable to report same as span gas or different compound. 90% within 5 seconds (on each range) Alpha numeric 20 character length 4 lines. 0-10 volts (O
- 

### 5v 

### & 0
- lv options available) with 7 

### adjustable ranges. 4-20 rna output available as Option 5. 

### Serial Port RS232 port for sending all reports to external printer for archival purposes, or to a computer for two way communication. Reports Analysis reports High, low, and average concentration 3-1·----- ·------


### Report Frequency Alarm

ca1

### i.bration for each period scrolled on display and made available to RS2J2C port. Settable from 1 to 99 minutes. Concentration alarm with time written to alarm report in UTILITY. Notice also appears on the display any time there is a concentration exceedance. External The standard calibration procedure permits the introduction of the zero and span gases into the Model 51 

### through the sample port. Internal (Optional) Span Gas Frequency Standard span value entered via key pad. Completely automatic zero and span on a settable cycle from 1 

### to 99 hours. The most recent good calibration data retained in EEPROM'S not overwritten by erroneous calibration. sample stream Selection (Optional with Model 440) 

### streem sequence settable in any order to 10 

### digits. Time between stream settable in minutes 1 

### to 99.

changes (also time of analysis reports). Manual Front panel controls, through. to hold the present· advance to the next Utility Menu, stream or to stream. Concentration Individually settable over total system Internal External Alarm condition range for each sample stream. Denotes problem with analyzer. Audible 

## so db alarm for both alarms. Both alarms activate JA AC/DC contact closure for external alarms. Reported to screen, RS232C, and alarm status memory in unit. J-2 

# !k-7 i

t.

L I

! 

# J

.**~** '



### l.. ·l."'



# I 

# l**~I** 

# .'I

# ~ \f L1

' 

# .. ! . 

# '.



# ,I

# ..;t GasesCombustion Air Fuel Hydrogen Span gas Zero Air Control

Phvsical Ambient Temperature Power Requirements Case size Weight 150 mLjmin @ 

### 30 psig required. 25 mLjmin @ 

### 30 psig required. 40% HydrogenjHelium
- 80 mLjmin 

### @ 70 psig required. Generally propane in air. Supplied to unit at about 10 psig and adjusted for proper flow. About 1500 mL 

### required per calibration.

Supplied to unit at about 10 psig and adjusted for proper flow. About 2 L required per calibration. All critical flows are controlled by temperature controlled restrictors adjusted by pressure regulators on flow panel of instrument.

40 Degrees F (5 degrees C) to 115 degrees F (40 degrees). 120 /220 VAC, 60/50 Hz, 3.0 A Bench Mount HWD 9.2 x 16.9 x 22 in. (23.4 

### x 42.9 

### x 55.9 em.) . Bench: 55 lbs.(24.9Kg).

3-3

### SPECIALTY GAS DIVISION 11711 S. Alameda Street Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Mlchlg:l.ll A!rgas

EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: CC·25694 SulfurD!oxlde Nitrogen

Certification Period (months): 24 Expiration Date: 18 May 1996 CylinderPressure: 2000 psia DO NOT USE BELOW 150 PSIG

# azue~ ANALYST 800 PPM Balance Date: 18 May 1994 P.O.: PG 0530

NOMINAL 857.3 PPM Balance ACTUAL

### SPECIALTY GAS DIVISION 11711 S. Alameda Street Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Airgas I Michigan Date: 19 December 1994 P.O.: PG-0621 EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC37899 Sulfur Dioxide Nitroger.

Certification Period (months): 24 Expiration Date: 19 Decembe= 1996 Cylinder Pressure: 2000 psia DO NOT USE**BE~OW** 150 PSIG 400 PPM Balance 392.9 PPM Balance ACTUAL

### SPECIALTY GAS DIVISION 11711 S. Alameda Street Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Airgas I Mic:higan Date: 19 December 1994 P.O.: PG-0621 EPA Protocol Procedure G-1 CYLINOER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC37923 Sulfu::- Dioxide Nitrogen

Certification Period (months): 24 Expiration Date: 19 December 1996 Cylinde= Pressure: 2000 psia DO NOT USE BELOW 150 PSIG 225 PPM Balance 222.7 PPM Balance ACTUAL

### SPECIALTY GAS DIVISION 11711 S. Alameda Street Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Airgas I Michigan Date: 19 December 1994 P.O.' PG-0621
EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC37948 Nitric Oxide NOX Nitrogen

Certification Period (months): 24 Expiration Date: 19 December 1996 Cylinder Pressure: 2000 psia DO NOT USE BELOW 150 PSIG

ANALYST 225 PPM Balance 221.4 PPM 221.6PPM Balance ACTUAL

### SPECIALTY GAS DIVISION 11711 S. Alameda Street Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPO.RT- PRODUCT CERTIFICATION TO: Airgas I Michigan Date' 19 December 1994 P.O., PG-0621 EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC38000 Nitric Oxide NOX Nitrogen

Certification Period (months): 24 Expiration Date: 19 December 1996 Cylinder Pressure: 2000 psia DO NOT USE BELOW 150 PSIG

ANALYST 125 PPM Balance 122.5 PPM 122.9 PPM Balance ACTUAL

# Scott Specialty Gases, Inc. 1290 COMBERMERE STREET, TROY, Ml48083 (313) 585>-2950 FAX: (313) SSS-2134 

### CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS Customer MICHIGAN AIRGAS 311 STOKER DR SAGINAW MI 48604 ANALYTICAL INFORMATION Assay Laboratory Scott Specialty Gases, Inc. 1290 Combermere Troy, MI 48083 Purchase Order 039I1 Scott Project# 560481

Certified to exc:::ed the minimum specifications ofEPA Protocol 1 Procedure#G 1, Section Number 3.0.4 Cylinder Number ALM016066 Certification Date 1-19-94 Expiration Date I-19-96 C:;!ir:c!;:r Pn:::s.:;ur.: 19CO p.!:it;; ANALVZED CYLINDER Components Nitric Oxide Total Oxides ofNitrogen Balance Gas: Nitrogen Certjfied Concentration 50.40 ppm 50.50 ppm 

### t:...

**~c** Analvtical Uncertaintv• ±1 '% NIST Directly Traceable Reference Value Only
•Analytical WlCert;Unty is inclusive ofusual kn0'-"11 error sources which at least includes reference standard error & precision ofthe measurement processes.

**REFERE~CESTANPARD** Type Expiration Date CR..\11684 9-17,94
INSTRUMENTAT!ON Instrument/Model/Serial# NO: Horiba/OPE-235/483814 Cylinder Number ALM-024698

LastDate Calibrated 1-6-94 Concentration 95.6 PPM NO IN 

### Nz
Analytical Principle Chemiluminescence ANALYZER READINGS (Z=Zero Gas R=Rererence Gas T=Test Gas ,....Correlation Coefficient) Ccmpcne:Jts Nitric Oxide

Special :"iotes r=-s· Triad An:::lysis 

## -

# .. Second Triad An:::'y:is 

# - Dace: J-12-94 Response Units: mv Dace: 1-19-94 Response Umts: mv ZI,.O.OO Rl-95.60 T\,.50.50 Z\..(1.00 Rl-95.60 T\•50.30 Rl""J5.60 Z2=0.oo· n ..5o.5o R.Z-95.60 Z2..0.00 n ..5o.3o Z3..0.00 TI=-50.50 RJ-95.60 ZJ=O.OO D=-50.30 RJ-95.60 Avg. Cone. ofCt1SC. Cyl. 50.50 ppm Avg. Cone. ofCllst Cyl. 50.30 ppm



# ~IL-----1

# _ L____ll'------ Calib:-aticr: Cu!"'Vc Concenrratioa.. A+Blt+CX""+D:t}+Ex4 r-=0.99999 CRM 1684 Constants: B*\.000\15 D-0 A--o.000967384 c-o E-<l Concentration"'A+Blt+Cxl+DltJ+Ex4

ConcentrJ.rion•A+Blt +D){ +Ex

Analyst Fronk P. Doran

### SPECIALTY GAS DIVISION 11711 5. Alameda Street Los Angeles, CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Airgas I Michigan Date: 19 December 1994 P.O.: PG-0621 EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC37999 Carbon Monoxide Nitrogen

Certification Period (months): 36 Expiration Date: 19 December 1997 Cylinder Pressure: 2000 psia DO NOT USE BELOW 150 PS:G 400 PPM Balance 402.3 PPM Balance ACTUALSPECIALTY GAS DIVISION 11711 S. Alameda Street Los Angeles. CA 90059 (213) 564-5711 

## ANALYTICAL REPORT- PRODUCT CERTIFICATION TO: Airgas I Michigan Date, 19 December 1994 P.O.' PG-0621
EPA Protocol Procedure G-1 CYLINDER NO. CONSTITUENTS CONCENTRATION: NOMINAL CC37919 Carbon Monoxide Nitrogen

Certification Period (months}; 36 Expiration Date: 19 December 1997 Cylinder Pressure: 2000 psia DO NOT USE BELOW 150 PSIG 225 PPM Balance 224.5 PPM Balance ACTUAL

# AGA Gas, Inc.**Cert~f~cate** 

### of**Ana1ys~s** 

### EPA Protocol il Production Number: 03930968 Cylinder Number(s): CC92021 certified concentration:**~7.92** 

### ppm Carbon Monoxide Balance Gas: Nitrogen Cylinder Pressure: 2015 psi Date of Certification: March 30, 1993 Certification Expiration: September 30,**199~** 

### SRM Information: SRM Number 1678C This assay/certification was Cyl. Number Concentration CAL-6685**~5.2** 

### ppm CO/N2 performed according to Section 3.0.i The certification was performed at: AGA Specialty Gas, Inc.**6~21** 

### Monclova Rd. Maumee, Ohio**~3537** 

### Instruments Used:

EPAlnl

AGA Gas Inc. &42 1 Monclova j:load**~**....m_**~""'** <1."'10:,11 

### Carbon Monoxide: Horiba**OPE-l~~E.** 

### CFA-26 Non-dispersive Infrared Serial No. 8501190110 Calibration: 2-15-93



# ...

# ~~~~-~

'" Michael Sickmiller Quality Control Supervisor 

# { ; f 

# •
I


## ....1""1ICHIG;.N**qr~GAS** 1 517 755 2100 P.C12



### SP£CIALTY GAS 

### OIVISION 11711 S. Alemeda Stlltet Los Angol••· CA. 900$9 (213) 564-5711



## ____**__,A~N,_,A=L**

## YTICAl REP9AT :- PRODVCT CERTIFICATION TO: Airgaa f Michigan P.O.: PG0654**E~A Tr&~•ability**  PrQtOeol For Aaaay And**Certifi~ation** o: G&8e0ua**Calib~ation Stan~r~** **P:ocedu~•** G-1

CYUNOER NO. CONSTITUENTS CONCENTRATION-;--·"""NOMINAl.
CC10656**Prop<~n•** Nitrogen

Certification !'eriod**(men~)** : J6 Expiration Oats • 16 February l9t8**Cyli~de: Pre••u~•:** **~000** p•ia 00 NOT OSZ BELOW 150 PSrG 425 PPM S..lanc:e 411.7 !'PM Balance ACTUALDate' 03 March 1995 p .0.' PGO 654

**~:-** ··'.- '; EPA **T~aceability P~otocol**  Fer Assay

**JL~d** Certification of Gaseous Calibration Standards Procedure G-1

CYLINDER NO. CONSTITUENTS CONCENTRATION:
150-299 Propane Nitrogen

Certification Period {months) Expiration Date : 16 February Cylinder Pressure: 2000 psia DO NOT USE BELOW 150 PSIG ' 3 6 1998 250 PPM Balance NOMINAL
257.7 PPM Balance ACTUALl



### ' \ L



# . I 

# "·'

,. 

# I L



# ~

**~.·.**



# ~

**~** 

# tl

**~** L[ 

# tL ;F; 

# rL

### APPENDIXD FIEL1> DATA



# j/2

# -·-···--- ····· -··-·-··

# . ........

# -·

# ... DIVISION OF l.iiiii - ·- ·· · 

# --·-·.1 

# ----·· ... 

# --···-·· To: Bertram Smith From: Carl Gewirtz 

## #2 Kiln- Modular Size Brick Blend of Brick: Hickory Ridge Charge times with a 12 car per day push rate: 0120 0320 0520 0720 0920 1120 1320 1520 1720 1920 

## 2120 2315 Lime feed rate of 165 lbs. per hour. Dry Face Brick 

# wt. 4.10 x 10680 

# = 43,788 Dry 1-1/4" solid slabs 

# wt. 2.03 x 1789 

# = 3,631 Total=47,419 Fired Face Brick 

## wt. 3.80 x 10680 

# =40,584 Fired 1-1/4" solid slabs 

## wt. 1.9 x 1789 

# = 3,399 Total 

## =43,983 6-13-95**i'iii~~~~;'; ~-=-=~**  

# • P.O. BOXes • 3820 SEAR ROAD • CORUNNA. MICHICAN 48117 • 517f7..3·3-4-4.. • 1001812·8880 • FAX 517f743-3:SG4 

# ;f.3Detroit Regional Office 22345 Roethel Drive P.O. Box 8022 Nevi, Ml 483 75 (81 0) 344-1770 Fax (810) 344-2654

June 28, 1995
Mr. David D. Engelhardt NETWORK ENVIRONMENTAL 2629 Remico S.W., Suite B Grand Rapids, MI 49509

Dear Mr. Engelhardt: 

# Clayton ENVIRONMENTAL CONSULTANTS

Clayton Project No. 27503.00 Client Reference: 10.08
Attached is our analytical laboratory report for the samples received on June 9, 1995. Also enclosed is a copy of the Chain-of-Custody record acknowledging receipt of these samples. Please note that any unused portiOn of the samples will be discarded after July 28, 1995, unless you have requested otherwise. We appreciate the opportunity to assist you. If you haye any questions concerning this report, please contact a Client Services Representative at (810) 344-2650' 

# "";i£7--;f /r Robert Lieckfield, Jr., CIH Director; Laboratory Services Detroit Regional Office RL/ke Attac:r..ments

Clayton Environmental Consultants, Inc. Detroit • New Yotk Minneapolis • Cleveland • Chicago • Birmingham, U.K. • Atlanta • San Francisco • Los Angeles • Honolulu london, U.K. • Southampton. U.K. • C.11teshead. U.K.Sample Identification: Lab Number: Sample Type: Analyst: Analyte P'lun:=ida #l COla Analytical Results for NETWORK ENVIRONMENTAL Clayton Project No. 27503.00 Client Reference: 10.08
Date Date Impinger 

### sc Sampled: Received:
Concentration LOD Analytical (,ug) (,ug) Method 400 300 EPA l3B 

## Clayton ENVIR:QNMfi'oTAL CONSULTANTS

06/07/SS 06/0S/SS

Date Analyzed 06/27/SS



## ------------------------------------------------------------------------------------
Sample Identification: #2 Date Sampled: 06/07/SS Lab Number: 002a Date Received: 06/0S/SS Sample Type: Impinger Analyst: 

### sc Concentration LOD Analytical Date Analyte (,ug) (,ug) Method Analyzed Fluoride <300 300 EPA l3B 06/27/SSSample Identification: Lab Number: Sample Type: Analyst: Analyte Fluoride #3 003a Analytical Results for NETWORK ENVIRONMENTAL Clayton Project No. 27503.00 Client Reference: 10.08
Date Date Impinger 

## sc Sampled: Received:

Concentration LOD Analytical (!'g) (!'g) Method 89,000 300 EPA 13B 

## Clayton fNVUi.0NM€NTAL (QNSULT,t.NTS

06/07/95 06/09/95

Date Analyzed 06/27/95 

# ------------------------------------------------------------------------------------

Sample Identification: #4 Date Sampled: 06/07/95 Lab Number: 004a Date Received: 06/09/95 Sample Type: Impinger Analyst: 

## sc Concentration LOD Analytical Date Analyte (!'g) (!'g) Method Analyzed Fluoride 140,000 300 EPA 13B 06/27/95



# ;fl-.Analytical Results for NETWORK ENVIRONMENTAL Clayton Project No. 27503.00 Client Reference: 10.08 Sample Identification: #5 Date Sampled: Lab Number: 005a Sample Type: Analyst: Analyte Fluoride General Notes: <: Less than the Impinger 

### sc Concentration ()lg) <300
indicated limit of



# -- . Information not available or not Date Received:

LOD Analytical ()lg) Method 300 EPA l.3B
detection (LOD) applicable 

## Clayton ENVIRONMENTAL CONSULTANTS

06/07/95 06/09/95

Date Analyzed 06/27/95"'I **~ ......_~**  !' Clayton - -.I For Clayton Use Only j

Paged ol d--

) \ ' ' .J ENVIRONMENTAL CONSULTANTS

A **~huh** & Md

**~nno~n Compo~ny**  REQUEST FOR LABORATORY ANALYTICAL SERVICES Project No.

' . I . ' ·' I . )

I 1 .• Balch

No. Client No.

'/· By

( ' [> Name

**~.<>-ILod** __ t" **~** "-

·, ,\"' 0 f

Purchase Order No. Client Job No. / t:J

, c-:J 2?

1-- --- -----

**~** (:! Company Dept. w Name

fL S Marling Address **--~** §'! B **f.,..o:-m=p a"'ny-:-----L,=---,Lt--.lh4-~:;:** 

ll! **~**

City, Stale, Zip **~**

> 1-- Address

a:

Telophone No.c J(r

u. n J **~** City, Stale, Zip

Dalo RestJII !Jequirod: 11ush Charges

**Aui~\Orized?** Phone Resulls Samples are:

( ' 5- 0 Yes [2j;No

· (check il applicable)

iSpodal

Jnslruclions: (method, limit ol detection, etc.) h D Drinking Water "Fillut'-r.l'< r"·Q,

EPA

- fl/dlw.!

- /3 5

D Collected in the

•

Explanation ol PresoJValivo: Stale ol New York

CLIENT SAMPLE IDENTIFICATION DATE MATRIX/ AIR VOLUME

I SAMPLED MEDIA (specify units) i" m c 'iii c 8 0 a; .0 E " z !.''

-<. f}. IDe

pi / " fOIILAil USE OIH.Y

'I ?I I l l' l l I I I

I

</r/hl ,_,LuI'.,,

'·i.e I, X. -,

/_/..,_ r7(:.-- **-D~.,~.n.-.** ,_''II

' ' I I I I I r I I X:

' -l I \lt 1'-Y I ,Jr ,, y -1TX

lA

CHAIN flecoived by:

_ c;• /

OF Received at Lab by:

**~?v:** <'ff

CUSTODY J:)- Sample Condition Upon Receipt:.-- J;] Acceptable

.

I Data/Time **Date!Tim~/ZJ')D**

O Other (explain)

AuthoriZe Date

_ _._'4--"'-/--L.L.....

RECEIVED JUtl 9 **19~~**

Please

return completed !arm and s;;;;rel'es to one ol the Clayton Environmental Consullants, Inc. Jabs listed below:

**~** 22345 Roethel Drive
**~** Novi, Ml 48375

\ (313) 344-1770 Raritan Canter 160 Fieldcrest Ave. Edison, NJ 08837 (201) 225-6040 400

**Chastai~,J;;enter** Blvd., N.W. Suite

490 Kennesaw, GA 30144 (404) 499-7500 1252 Quarry Lane Pleasanton, CA 945Sir' (415) 426-2600 6/90 DISTRIBUTION: WHITE Clayton Laboratory YELLOW - Clayton At=unting PINK Client Copy

## ·.

Network Environmental, Inc. P.O. Box 202l Grand Rapids, MI 4950l 

### SOURCE EMISSION TESTING 

### at MICHIGAN DIV:tSION, U.S. BRJ:CK CORUNNA, MICHIGAN

t2 lULN EXHAUST

DATE: 6/7/95Network Environmental, Znc. PZTOT TRAVERSE DATA
COMPANY NAME: MJ:CBZGAN DZVJ:SZON, U.S. BIUCK TEST DATE: 6/7/95 COMPANY LOCATZON: CORUNNA, MJ:CBIGAN SOURCE NAME: f2 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT
RUN NUMBER: 1 % CARBON DIOXIDE: STACK RADIUS, in.: 19.5 % OXYGEN: GAS TEMPERATURE, Deg F: 295 % CARBON MONOXIDE: STATIC PRESSURE, in. H20: -.32 PITOT FACTOR: .87 BAROMETIUC PRESSURE: 28.6 POINT VELOCITY PRESSURE, rNCBES OF WATER PT. LOCATION, PORT



# • INCHES 1 2 1 1.72 0.33 0.30 2 5.69 0.41 0.40 3 11.54 0.49 0.47 4 27.46 0.48 0.51 5 33.31 0.47 0.51 6 37.28 0.46 0.51



### C("' ) ';CNetwork Environmental, Inc. SAMPLING TRAIN DATA
COMPANY NAME: MICHIGAN DIVISION, 

### u.s. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: t2 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT SAMPLE NUMBER: 1 IMPINGER BOX 

### #: 1 GAS METER START: 169.274 TYPE OF TRAIN: EPA-5 FILTER SET 

### #: 29 METER CAL. FACTOR: l.OOO NOZZLE DIA, in: .3125 PRIM. FILTER 

### #: DH-756 CLOCK TIME START: 9:42 VENTURI NUMBER: SEC. FILTER i: BH-756 METER TIME START: 0 CONTROL BOX i: 1 BAROMETRIC PRESS: 28.6 METER TIME STOP: 1 PITOT CAL. FACTOR: .87 VELOCITY RATE MTR GAS METER POMP GAS METER STACK FILTER PRESSURE PRESSURE READING VAC. TEMP.' F TEMP. TEMP. PORT POINT IN. H20 IN. H20 CU. FT. IN. HG IN OUT F F 2 6 0.48 3.53 174.320 3.00 90 90 296 254 5 0.49 3.61 179.490 3.50 90 90 296 256 4 0.50 3.68 184.710 3.50 92 90 298 256 3 0.44 3.24 189.630 3.50 94 90 299 256 2 0.40 2.95 194.350 3.50 95 90 300 256 1 0.34 2.51 198.727 3.00 96 91 298 255 1 6 0.45 3.35 203.680 3.50 95 91 292 258 5 0.46 3.40 208.720 3.50 96 91 298 258 4 0.48 3.55 213.850 3.50 98 91 299 258 3 0.45 3.33 218.830 3.50 99 92 300 256 2 0.43 3.19 223.720 3.50 99 93 300 257 1 0.33 2.45 228.080 3.00 100 93 300 256 

# ;LJ/Network Environmental, Inc. SAMPLING TRAIN DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: 12 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT SAMPLE NUMBER: 2 IMPINGER BOX 

### f: 1 GAS METER START: 228.268 TYPE OF TRAIN: EPA-5 FILTER SET 

### f: 34 METER CAL. FACTOR: 1.000 NOZZLE OrA, in: .3125 PRIM. FILTER 

### f: DH-758 CLOCK TIME START: 11:05 VENTURI NUMBER: CONTROL BOX 

### f: 1

VELOCITY PRESSURE PORT POINT IN. H20 1 6 0.46 5 0.47 4 0.48 3 0.48 2 0.43 1 0.45 2 6 0.45 5 0.51 4 0.51 3 0.46 2 0.41 1 0.36 SEC. FILTER 

### i: BH-758 METER TIME START: 0 BAROMETRIC PRESS: 28.6 PITOT CAL. FACTOR: .87

RATE MTR GAS METER PRESSURE READING IN. H20 CO. FT. 3.19 233.100 3.26 238.020 3.33 242.970 3.33 247.920 2.98 252.650 3.15 257.512 3.13 262.330 3.55 267.490 3.54 272.630 3.18 277.440 2.84 282.070 2.49 286.462 METER TIME STOP: 1

POMP GAS METER STACK FILTER VAC. TEMP. , F TEMP. TEMP. IN. HG IN OUT F F

2.50 93 93 295 254 3.00 93 92 294 256 3.00 94 92 293 257 3.00 96 92 295 256 3.00 96 92 295 257 3.00 95 92 290 252 3.00 92 91 289 257 3.00 92 90 289 256 3.00 93 90 292 257 3.00 95 90 296 257 3.00 96 90 296 257 3.00 96 90 296 257

### Network Environmental, Inc. LABORATORY ANALYSIS REPORT
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: t2 KILN EXHAUST SAMPLING STAFF: CARGILL/ENGELHARDT DATE SUBMITTED TO LAB: 6/9/95 RECEIVED BY: DDE DATE REPORTED FROM LAB: 6/12/95 CHEMIST(S) : DDE PARTICULATE TRAIN SAMPLE NUMBER 1 -----PARTICULATE WEIGHT GAIN, MGS.----- CAPTURED WATER LAB SAMPLE ALT 1 ALT 2 !DENT. !DENT. STD. 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS. 1 DH-756 0.50 9.0 180.0 BH-756 0.00 NW-1 1.40 TOTALS 1.90 

## o.oo 0.00 9.0 180.0 PARTICULATE TRAIN SAMPLE NUMBER 2 -----PARTICOLAXE WEIGHT GAIN, MGS.----- CAPTURED WATER LAB SAMPLE ALT 1 ALT2 !DENT. IDENT. STD. 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS. 2 DH-758 0.80 8.0 194.0 BH-758 

## o.oo NW-2 1.30 TOTALS 2.10 0.00 0.00 8.0 194.0

### Network Environmental, Znc. P.O. Box 2021 Grand Rapids, HZ 49501 

### SOURCE EMISSION TESTING 

### at MZCIUGAN D:rv:tSZON, U.S. BRICK CORUNNA, MZCBZGAN f2 KILN EXHAUST (FLUORIDE) DATE: 6/7/95Network Environmental, Inc. PITOT TRAVERSE DATA
COMPANY NAME: KICBIGAN DI:VJ:SION, U.S. B!UCK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, KICBIGAN SOURCE NAME: f2 KILN EXHAUST (FLUO!UDE) SAMPLING STAFP: BYRD/ENGELHARDT RUN NUMBER: 1 % CARBON DIOXIDE: STACK RADIUS, 

### in.: 19.5 % OXYGEN: GAS TEMPERATURE, Deg F: 295 % CARBON MONOXIDE: STATIC PRESSURE, in. B20: -.32 PITOT FACTOR: .87 BAROMETRIC PRESSURE: 28.6 POINT VELOCITY PRESSURE, INCHES OF WATER PT. LOCATION, PORT

t INCHES 1 2 1 1.72 0.33 0.30 2 5.69 0.41 0.40 3 11.54 0.49 0.47 4 27.46 0.48 0.51 5 33.31 0.47 0.51 6 37.28 0.46 0.51Network Environmental, Inc. SAMPLING TRAIN DATA COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: #2 KILN EXHAUST (FLUORIDE) SAMPLING STAFF: BYRD/ENGELHARDT SAMPLE NUMBER: 1 IMPINGER BOX t: 1 GAS METER START: 286.595 TYPE OF TRAIN: FLUORID FILTER SET t: METER CAL. FACTOR: 1.000 NOZZLE DLA, in: .3125 PRIM. FILTER #: CLOCK TIME START: 14:10 VENTUIU NUMBER: SEC. FILTER i: METER TIME START: 0 CONTROL BOX t: 1 BAROMETRIC PRESS: 28.6 METER TIME STOP: 1 PITOT CAL. FACTOR: .87 VELOCITY PRESSURE PORT POINT IN. H20 RATE MTR GAS METER PUMP GAS METER STACK FILTER PRESSURE READING VAC. TEMP. , F TEMP. TEMP. IN. H20 CU. FT. IN. HG IN OUT F F 2 6 0.51 3.43 291.550 2.50 90 90 298 5 0.52 3.49 296.710 2.50 93 90 301 4 0.52 3.48 299.500 2.50 90 90 301 3 0.46 3.08 304.760 2.50 92 90 300 2 0.40 2.68 309.100 2.50 94 90 298 1 0.28 1.89 313.369 2.50 93 90 299 1 6 0.47 3.18 318.100 2.50 92 90 298 5 0.50 3.16 323.060 2.50 95 90 299 4 0.48 3.23 328.000 2.50 97 90 300 3 0.47 3.17 332.900 2.50 98 91 300 2 0.58 3.92 338.300 3.00 100 92 298 1 0.32 2.17 342.493 2.00 100 92 297 

# ;9fcNetwork Environmental, Inc. SAMPLING TRAIN DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: #2 KILN EXHAUST (FLUORIDE) SAMPLING STAFF: BYRD/ENGELHARDT SAMPLE NUMBER: 2 IMPINGER BOX t: 1 GAS METER START: 342.816 TYPE OF TRAIN: FLUORID FILTER SET #: METER CAL. FACTOR: 1.000 NOZZLE DIA, in: .3125 PRIM. FILTER #: CLOCK TIME START: 16:05 VENTURI NUMBER: SEC. FILTER t: METER TIME START: 0 CONTROL BOX #: 1 BAROMETRIC PRESS: 28.6 METER TIME STOP: 1 PITOT CAL. FACTOR: .87 VELOCITY PRESSURE PORT POINT IN. B20 RATE MTR GAS METER PUMP GAS METER PRESSURE READING VAC. TEMP. , F STACK FILTER TEMP. TEMP. IN. B20 CO. FT. IN. BG IN OUT F F 1 6 0.48 3.12 347.650 2.50 93 92 296 5 0.50 3.38 352.640 2.50 97 92 300 4 0.49 3.31 357.650 2.50 100 93 300 3 0.48 3.25 362.585 2.50 101 93 300 2 0.43 2.92 367.350 2.50 101 94 298 1 0.35 2.38 371.538 2.50 101 94 296 2 6 0.51 3.47 376.000 2.50 99 94 298 5 0.48 3.36 381.510 2.50 102 95 301 4 0.47 3.19 386.470 2.50 102 95 300 3 0.51 3.47 391.540 3.00 103 95 299 2 0.38 2.59 396.460 2.50 103 95 298 1 0.28 1.91 400.081 2.00 102 95 297 

## !9}Network Environmental, Inc. ORSAT ANALYSIS DATA
COMPANY NAME: MICHIGAN DIVISION, 

## u.s. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: t2 KILN EXHAUST (FLUORIDE) SAMPLING STAFF: BYRD/ENGELHARDT DATE OF ANALYSIS: 6/7/96 METHOD: MULTIPOINT INTEGRATED SAMPLE

PART CARBON DIOXIDE OxYGEN CARBON MONOXIDE SMPL. CONT RUN



### t t t FINAL INIT. 

# ' FINAL INIT. 

# ' FINAL INIT. 

# ' 1 1 1 3.4 0.0 3.4 18.7 3.4 15.3 18.7 18.7 0.0 2 3.4 0.0 3.4 18.7 3.4 15.3 18.7 18.7 0.0 3 3.4 

## o.o 3.4 18.7 3.4 15.3 18.7 18.7 0.0 2 2 1 2.8 

## o.o 2.S 19.1 2.8 16.3 19.1 19.1 0.0 2 2.8 0.0 2.8 19.1 2.8 16.3 19.1 19.1 0.0 3 2.8 0.0 2.8 19.1 2.8 16.3 19.1 19.1 

## o.o

### Network Environmental, Inc. LABORATORY ANALYSIS REPORT
COMPANY NAME: HJ:CHIGAN D:rvJ:SION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, HJ:CBIGAN SOURCE NAME: f2 KILN EXHAUST (FLUORIDE) SAMPLING STAFF: BYRD/ENGELHARDT DATE SUBHJ:TTED TO LAB: 6/9/95 RECEIVED BY: DOE DATE REPORTED FROM LAB: CBEHJ:ST(S): CLAYTON PARTICULATE TRAIN SAMPLE NtlMBER 1 -----PARTICULATE WEIGHT GAIN, MGS.----- LAB SAMPLE ALT 1 ALT 2 IDENT. IDENT. STD.

NO. MARK ANAL. F01 TOTALS 0.00 

## o.oo 0.00 PARTICULATE TRAIN SAMPLE NtlMBER 2 -----PARTICULATE WEIGHT GAIN, MGS.----- LAB SAMPLE ALT 1 ALT 2 IDENT. IDENT. STD.

NO. MARK ANAL. F02 TOTALS 0.00 

## o.oo 0.00 CAPTURED WATER S. GEL GRAMS 12.0 12.0

CAPTURED 

### s. GEL GRAMS 12

## .o 12

## .o CONDSR MLS. 176.0 176.0

WATER CONDSR

MLS. 178.0 178.0



# /9:7:



### Network Environmental, Inc. P.O. Box 2021 Grand Rapids, HI 49501 

### SOURCE EMISSION TESTING 

### at MICHIGAN DIVJ:SION, 0.S. BRICK CORUNNA, MICHIGAN t2 lULN INLET (FLUORIDE) DATE: 6/7/95

### Network Environmental, Inc. PITOT TRAVERSE DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORO'NNA, MICHIGAN SOURCE NAME: t2 KILN INLET (FLUORIDE) SAMPLING STAFF: CARGILL/SCBO'LTES RUN NO'MBER: 1 ' CARBON DIOXIDE: STACK RADIO'S, 

### in.: 21 ' OXYGEN: GAS TEMPERATO'RE, Deg P: 542 ' CARBON MONOXIDE: STATIC PRESSURE, 

### in. H20: -2 PITOT PACTOR: .87 BAROMETRIC PRESSURE: 28.6 POINT VELOCITY PRESSURE, INCHES OP WATER PT. LOCATION, PORT

t INCHES 1 2 1 1.84 0.47 0.43 2 6.13 0.45 0.42 3 12.43 0.43 0.39 4 29.56 0.39 0.33 5 35.86 0.31 0.25 6 40.15 0.36 0.25Network Environmental, Inc. ORSAT ANALYSIS DATA
COMPANY NAME: MICHIGAN DIVISION, 

### u.s. BJUCK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN S0t1RCE NAME: t2 KILN INLET (FLOOJUDE) SAMPLING STAFF: CARGILL/SCBOLTES DATE OF ANALYSIS: 617/95 METHOD: KIJLTIPOINT INTEGRATED SAMPLE

PART CARBON DIOXIDE OXYGEN CARBON MONOXIDE SMPL CONT RON

t t t FINAL INIT. '!; FINAL INIT. '!; FINAL INIT. '!; 1 1 1 2.4 0.0 2.4 19.4 2.4 17.0 19.4 19.4 0.0 2 2.4 0.0 2.4 19.4 2.4 17.0 19.4 19.4 0.0 3 2.4 0.0 2.4 19.4 2.4 17.0 19.4 19.4 0.0 2 2 1 2.5 0.0 2.5 19.1 2.5 16.6 19.1 19.1 

## o.o 2 2.5 

## o.o 2.5 19.1 2.5 16.6 19.1 19.1 0.0 3 2.5 

## o.o 2.5 19.1 2.5 16.6 19.1 19.1 

## o.o

.•Network Environmental, Inc. LABORATORY ANALYSIS REPORT
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/7/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: f2 KILN INLET (FLUORIDE) SAMPLING STAPF: CARGILL/SCHULTES DATE SUBMITTED TO LAB: 6/9/95 RECEIVED BY: DDE DATE REPORTED FROM LAB: CBEMIST(S): CLAYTON PARTICULATE TRAIN SAMPLE NUMBER 1 -----PARTICULATE WEIGHT GAIN, MGS.----- CAPTURED WATER LAB SAMPLE ALT 1 ALT2 IDENT. IDENT. STD. 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS. FI1 8.0 50.0 TOTALS 

## o.oo o.oo 0.00 8.0 50.0 PARTICULATE TRAIN SAMPLE NUMBER 2 -----PARTICULATE WEIGHT GAIN, MGS.----- CAPTURED WATER LAB SAMPLE ALT 1 ALT2 IDENT. IDENT. STD. 

### s. GEL CONDSR

NO. MARK ANAL. GRAMS MLS. FI2 12.0 68.0 TOTALS 0.00 0.00 

## o.oo 12.0 68.0



## .·Network Environmental, Inc. P.O. BoX 2021 Grand**Rap~ds,** MI 49501 

### SOURCE EMISSION TESTING 

### at MICHIGAN DIVISION, U.S. BRICK CORUNNA, MICHIGAN DRYER DATE: 6/8/95Network Environmental, Inc. PITOT TRAVERSE DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BlUCK TEST DATE: 6/8/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: DRYER SAMPLING STAPF: SCHULTES/SMITH RUN NUMBER: 1 • CARBON DIOXIDE: STACK DIMENSIONS, in.: 57 by 42 • OXYGEN: GAS TEMPERATURE, Deg F: 145 • CARBON MONOXIDE: STATIC PRESSURE, in. H20: -.12 PITOT FACTOR: .87 BAROMETRIC PRESSURE: 29 POINT VELOCITY PRESSURE, INCHES OF WATER PT. LOCATION, PORT

t INCHES 1 2 3 1 7.00 0.68 0.70 0.64 2 21.00 0.52 0.40 0.57 3 35.00 0.74 0.50 0.57



## ·.Network Environmental, Xnc. ORSAT ANALYSIS DATA
COMPANY NAME: MICHIGAN DIVISION, U.S. BRICK TEST DATE: 6/8/95 COMPANY LOCATION: CORUNNA, MICHIGAN SOURCE NAME: DRYER SAMPLING STAFF: SCHULTES/SMITH DATE OF ANALYSIS: 6/8/95 METHOD: MULTIPOINT INTEGRATED SAMPLE

PART CARBON DIOXIDE OXYGEN CARBON MONOXIDE SMPL CONT RUN

t t t FINAL INIT. 

# ' FINAL INIT. 

# ' FINAL INIT. 

# ' 1 1 1 1.6 0.0 1.6 19.3 1.6 17.7 19.3 19.3 0.0 2 1.6 0.0 1.6 19.3 1.6 17.7 19.3 19.3 0.0 3 1.6 0.0 1.6 19.3 1.6 17.7 19.3 19.3 0.0

### APPENDIXE 

### • CALCULATIONSNetwork Environmental, Xnc. CALCULATION FORMULAs MOISTURE TRAIN CALCULATIONS: Ml. BAROMETRIC PRESSURE, inches of Mercury H2 • DURATION OF SAMPLE, minutes M3 • METER CALIBRATION FACTOR M4. AVERAGE METER TEMPERATURE, degrees F MS. AVERAGE METER PRESSURE, inches of water M6. METER VOLUME, ACTUAL, cubic feet M7. METER VOLUME, STP, cubic feet 530 Ml 

### + .07355 

### * H5 M7 = H3 

### * M6 

### * ---------- * ------------------ M4 

### + 460 29.92 MS. LIQUID VOLUME OF WATER CONDENSED, milliliters H9. VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet H9 = MB 

### * 0.0474 MlO. TOTAL GAS SAMPLED, @ STP, cubic feet MlO 

### = M7 +H9 Mll. PERCENT MOISTURE H9 Mll 

### = * 100 MlO EXHAUST GAS CALCULATIONS: Gl. STACK DIMENSIONS, inches G2. AREA OF STACK, square feet3.14159 

### * (DIA/2)•2 G2 (ROUND) = --------------------- 144 WIDTH 

### * LENGTH G2 (RECT.) = ---------------- 144 G3. BAROMETRIC PRESSURE, inches of Mercury G4. STATIC PRESSURE IN STACK, inches of water G5. STACK GAS TEMPERATURE, degrees F G6 • AVG. SQRT VELOCITY PRESSURE OF POINTS SAMPLED G7. PERCENT MOISTURE AT TEST LOCATION Pl3 G7 = ----- 

### * 100 Pl4Network Environmental, Inc. CALCULATION FORMULAS CONTIIIUED GS. PERCENT MOISTURE BEFORE COLLECTOR G9. DRY GAS COMPOSITION, %02, %C02, %CO, %N2 G10. PERCENT EXCESS AIR AT TEST LOCATION %02
- 0.5 

### * %CO G10 = 100 

### * ----------------------------- .264 

## * %N2
- %02 + .5 

## * %CO G11. DENSITY, DRY, @STP, lbs./cu. ft. •0827 

### * %02 + .1137 

### * %C02 + (%CO + %N2) 

### * .0724 G11 = -------------------------------------------------- G12. DENSITY, WET, @STP, lbs./cu. ft. 100
- G7 100 G12 = G11 

### * ---------- + .0465 

### * 100 G13. DENSITY, WET, @STACK CONDITIONS, lbs./cu. ft.G7 100 530 G3 + .07355 

### * G4 G13 = G12 

### * ---------- * ------------------ G5 + 460 29.92 G14. MOLECULAR WEIGHT, DRY, lbs./mole G14 = G11 

### * 386.9 G15. AVERAGE GAS VELOCITY, feet/minute 1096 G15 = P5 

### * G6 

### * ----------- SQRT(G13) G16. STACK GAS FLOW RATE, ACFM G16 = G2 

### * Gl5 Gl7. STACK GAS FLOW RATE, SCFM 530 G3 + .07355 

### * G4 

## •. Gl7 = Gl6 

### * ---------- * ------------------ G5 + 460 29.92 Gl8. STACK GAS FLOW RATE, DRY, DSCFM 100
- G7 Gl8 

# = Gl7 

### * ---------- 100Network Environmental, Inc. CALCULATION FORMULAs CONTINUED
PARTICULATE TRAIN CALCULATIONS: Pl. NUMBER OF POINTS SAMPLED P2. DURATION OF SAMPLE, minutes P3. NOZZLE DIAMETER, inches P4. NOZZLE AREA, square feet 3.14159 

### * (P3/2)"2 P4 

# =-------------------- P5. PITOT CALIBRATION FACTOR P6. METER CALIBRATION FACTOR 144
P7. AVERAGE FILTER TEMPERATURE, degrees F PB. AVERAGE METER TEMPERATURE, degrees F P9. AVERAGE METER PRESSURE, inches of water PlO. METER VOLUME, ACTUAL, cubic feet Pll. METER VOLOME, @ STP, cubic feet 530 G3 + .07355 

### * P9 Pll = PlO 

### * P6 

### * ---------- 

### * ------------------ PB + 460 29.92 Pl2. LIQUID VOLUME OF WATER CONDENSED, milliliters Pl3. VAPOR VOLUME OF WATER CONDENSED, @ STP, cubic feet Pl3 = Pl2 

## * 0.0474 Pl4. TOTAL GAS SAMPLED, @ STP, cubic feet Pl4 = Pll + Pl3 Pl5. WEIGHT OF GAS SAMPLED, DRY, pounds Pl5 = Pll 

### * Gll Pl6. WEIGHT OF GAS SAMPLED, WET, pounds Pl6 = Pl4 

### * Gl2 Pl7. PERCENT ISOKINETICS Pl7 = 100 

### * 29.92 

### * (G5 + 460) 

### * Pl4 530 

### * (G3 + .07355 

### * G4) 

### * P2 

### * P4 

### * Gl5Network Environmental, Inc. CALCULATION FORMlJI.AS CONTINUED
CONCENTRATION CONVERSION FACTORS: P18. 50 % EXCESS AIR, AFER COLLECTOR G14 + 18 

### * G7/(100
- G7) P18 = ------------------------------------------------------- .1826 

### * %N2
- 2.0592 

### * %02 

### + G14 

### + 18 

### * G7/(100
- G7) P19. 50 %EXCESS AIR, BEFORE COLLECTOR G14 

### + 18 

### * G7/(100
- G7) P19 = ------------------------------------------------------- .1826 

### * %N2
- 2.0592 

## * %02 + G14 + 18 

## * G8/(100
- G8) P20. MOISTURE BEFORE COLLECTOR G14 + 18 

### * G7/(100
- G7) P20 

# = G14 + 18 

### * G8/(100
- G8) PARTICULATE EMISSION CALCULATIONS: El. E2.
E3. E4. TOTAL WEIGHT PARTICULATE COLLECTED, grams LBS. PARTICULATE/1000 LBS. GAS, ACTUAL 1000 . E2 = E1 

### * 

# ----------- 454 

### * P16 LBS. PARTICULATE/1000 LBS. GAS, DRY E3 = E2 

### * P20 LBS. PARTICULATE/ 1000 LBS. GAS, WET, 50% EA E4 = E2 

### * P18 E5. LBS. PARTICULATE/1000 LBS. GAS, DRY, 50% EA E5 = E2 

### * P19 E6. GRAINS/DRY STANDARD CUBIC FOOT E1 

### * 7000 

### * 100 E6 

### = ------------------------ 454 

### * P14 

### * (100
- G7) E7. POUNDS/BOOR G17 

### * G12 

### * 1000 

### * E1 

### * .06 E7 = ----------------------------- 454 

### * P16 E8. POUNDS/MILLION BTU E7 E8 = --------------------- CAPACITY, MM BTU/BR 

# /}J/

### EPA METI:IOD 6C 

### AVERAGE GAS 

### CONCENTRATIONFORMULA Eq. 6C-l



# - c C =(C-C) 103



### gas o (C., 

### -Co)



### Where: C 

## =Effiuent gas concentration, drybasisppm or%.

p.s • 

### C 

### =Averagegas concentration indicated by gas analyzer, drybasisppmor%. Co=Average ofinitial 

### andfinal systemcalibrationbias checkresponsesforthe zero gas ppmor%. C =Averageofinitial 

### andfinal 

### systemcalibrationbiascheckresponsesforthe

m . 

### upscale calibration gas ppm or%. C.,.= Actual concentration ofthe upscale gas, ppm orpercentDate: _ 

### __,c,c....----.:.S_-_<1__::.s- ___ _ INCOQPOQATED



## ("\,·"~

# ,'5c.."' 

# er 

# ,·c. t Clients: 

# Pitot Traverse Data Form Proj. No.:--------- Plant: __ 

## U..:::::.__,S::._.,;,3~,.-!..._·~· **<-"--!:k~-=---C,~.:....'~"'-;:._:"'-_"'-_:_:."'-;:._**_________ 

## ~---------- Source: __ 

# __:Wt,~, **__,l~~_,_\** c..:"-'-"';J;--.c.R_.."'-o..:::.-..=._ ____ _ '7 / (( Stack Size, Inches __ **____:<>~"''-------** Barometric Pressure, "Hg __ 

# z_c:;_._ 0

## _o ___ _ / 0 2 ., Gas Temperature, "F ___ **....~**

_ __::::____ _ 

# -. osStatic Pressure, "H 20 ---------- Pitot Tube [] Standard 

## (5rS-Type 

### %0z _______ %C02 -------- 

## 3 "'/, 1-.- j:t- 

## Cp - 

# '?1- ""-<> i( 

### .,.. 

## - - 0 

## >,.Veloclty ,'_ - 

## Point . 

# .I 

# L. ·::·Velocity ., 

## ..,,• v lo lty 

# - ,... :Velocity
.. 

# - : .·- e c

. 

## ·Location ·f-=- 

## '.....**Presst.~re** 

### ·1-:-:- 

## :·:Pressure

**~--:** 

# --;: ···:::Pressure 

# 7 :Pressure Inches . . . 't: 

### .. .,.,H 0 .. 

## ... ·:'t: 

### ···:>·"H 0 

# :·

**~- .·~H20**  

### "H20 .. 0 . ·. 

### ...... 2 :-;. 0 

### ....... 2 0 0

. ll. ... ·c .., _,. ll. ll. 

# . .. . . ll. .· 

## I. s-S 1 

# I .43 1

**-~** 

### 1 1 

## 5.'.2..-.5 2 

## .f.. 

# I 2 

# .--::;.

**~** 

### 2 2 

## I

## o.

**(,~** 

### 3

**,(..~** 

### 3

**·~** b 

### 3 3 

# 2s-. 3t.f 4 

# t.o b 

### 4 

## ,g) 4 4 

## 3D.:f'j 5 

# \.D 0 5 

## .4 

# s;- 5 5 

## 3<-\.£{ 

# ' 6 

# .82._ 

# I 6 

# .7'5'"' 6 6 7 

# I 7 7 7 

### 8 

# I 8 8 8 9 9 9 9 

### 10 10 10 11) 11 11 11 11 12 112 12 12 13 13 13 13 14 14 14 14
Wall Thickness 

## 1\)f\- . Zero Point



## tJ~ Port SizerType 

# I' I



## 14..,~Date: 

## h- 8- '1.r

**INCO~PO~ATED** Clients: 

# (11,·J.ti,(l,..,_

**~rl~**

# k. 

# Pitot Traverse Data Form Proj. No.:--------- 

# u._

# s '? (' ; Ll - 

# c"( (A .,_ "'- "'-- Plant: _ 

### __;::..:;:..::::..,__;D~-'-'""'--'~"--"""'...:::v:...:_~----=~--------------------- Source: __ 

### J)'-"'I::...:_r_:i1-e_"'--r __________ _ Staff:



# ----"'S=c-__,(=.J'-.!.~=e."'-s **___:.+__::Si::..c:Ml.!.;+.!...L....~----** s-=; I{ V '-{

## L (( Stack Size, Inches ---=-_..:__,.t;l"-::,_..,;_:;.=----- Barametric Pressure, "Hg _ 

### __::::;;:l:......:.<f_._o_v __ _ 

## I '{S'D Gas Temperature, •F ___ .:.._--'------ 

### l'Z... Static Pressure, "H 20 ---------- Pita! Tube [] Standard



### ~ S-Type %02 ---------- %C02 ---------- 

### Foint Location

Inches 

# /.oo

Z.l.oD 

# 55'. 0 6

Wall Thickness Zero Point Port SizerType 

## ~ 

# I Cp 

# =•

# '81-

. 

### - ._ 

## l ·- ,"\VeloCity _ 2_



## ~

0 

### c.

1 

### 2 3 

# I 4 5 6 

### 7 8 

### 9 10 11 

### 12 13 

### 14 

# Nit



# !O rt 

### " .....Pressure 1--t:: 

### '"H 0 . ·· -. -. - 2 . ,__ - 0 

### c.

1 

# I 2 3 

# I 4 

# I 5 

# I 6 

### 7 8 

# I 9

10 11 13

' 

# 3 1

# 'Porf- -:Velocity - _ 

# 3 

# '-._..·,v'elocttY -· -·Pressure -: · ;-:-:- ·Pressure



### ., .,.H 0 • -- t:: - :,_

### H 0

-··- 2.
-- 0
- . 2.



### - -- c. ---. .- .. 

## 9-0 2



### , S'D 3 4 

### 5 6 

### 7 8 

### 9 10 11 

### 12 13 

### 14 

# -

**-~** 0 

### c.

1 

### 2 3 4 

### 5 6 

### 7 8 

### 9 10 

### 11 

### 12 13 

### 14 

### Velocity -Pressure 

## "H20

# Pitot tube calibration data.
P11or 1uas: roel'lnFICATioN

# NuMaE.~: __ 

## lf'--...

# 2~--- oAr<: 

# /J};If? . A?/?**;~**

### CAL!ER~TEOEY: __

### ~I~'IL----------------------

RUN NO. 

# I
t 

# I 2 

# I 3 

# I

RU"' NO. 

### t .2 -,.··SlOE CAL!!;;AiiO!I ilF::::! tl.**~**(;) 

# r c,rll =HzO =HzO (in. HzOI (in. HzOI



## . ':J..L/0 

# I < 

# J;r;- 

# I. f&LJ 

# I ,;] 'I 0 

# I .3/D 

# 1-6'7/ 

# I .J..vo 

# I**~** 

## 3;')

# J.~,cr 

# I

-

··a·· SlOE**C.!LI~;;:.TIO!'I** 

### c.;::;::: """ HzO (in. HzOI

J**c.~(~** c:.-, HzG lin. Hzul . C;:fll 

## .. CEVIAriO:'! C;:(11•

### t.,L~I**I(';?~**



### . Ov

## c::;**~** 

### 1:::>2._

0€¥1.!11011 C;;( 1i · C;:ISI 0 (
I[) 

### 0 ( 

# I

:::I C;:iii·C,I.! OFi Sll 1 P.VERAGE OEVl-"riOM ''' (;1 p;; Sl • ..:......_______ -MUST SE <:;a.Qt 

# 1



# c., !SloE ;:.J

# -c., !s1a: s1/--Musr se <a.at 

# .7;7

# Pitot tube calibration data.

PITOiiU!!E ICE!HlFIC.:.IlON



# HI.!Mo~iL __ Fl:!.·

__ · ___

# O~ri:: II

# h/<?.:1 Oc/ 

# 1 1

**C~lloR~7ECBY:_4f\~,~~,L~----------------------------~-------**

RUN HO. 1 2 3

fl[Jiollo!Q.
.2 J C,. P,::! =HzO (in. HzO I 

## c9.. 

# s7S 

# I 

# 5"1

**c..~~=** ""' HzO (i". HzOI 

# I 

# I ll.p[,l =HzO (i.,_ HzOI 

## ' ,3o7S"" c_ 1s1a: 1.1

'

**c.~~<.)**

e.-, HzO (in. Hzul

C:;; (SIO E Bl
3 OEVl.il.

**iTO~** 

## c:,(,) .C;:IAI



# ' 

# DS

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