# Patent

## Title
Solid oxide fuel cell column temperature equalization by internal reforming and fuel cascading

## Abstract

A fuel cell system includes a fuel cell stack including a plurality of fuel cells. The fuel cell stack includes a middle portion of fuel cells and at least one end portion of fuel cells. The fuel cells of the end portion is arranged in a cascade configuration with the fuel cells of the middle portion. The system is configured such that in operation, at least partial reformation of hydrocarbon fuel occurs internally within the fuel cells of the middle portion and the fuel cells of the end portion are configured to use fuel exhaust from the middle portion as fuel.

## Background
This application is a continuation-in-part of U.S. application Ser. No. 11/274,928, which was filed on Nov. 16, 2005, which is hereby incorporated by reference in its entirety.


BACKGROUND OF THE INVENTION
The present invention is generally directed to fuel cells and more specifically to a cascaded fuel cell stack system.
Fuel cells are electrochemical devices which can convert energy stored in fuels to electrical energy with high efficiencies. High temperature fuel cells include solid oxide and molten carbonate fuel cells. There are classes of fuel cells, such as the solid oxide reversible fuel cells, that also allow reversed operation.
In a high temperature fuel cell system, such as a solid oxide fuel cell (SOFC) system, an oxidizing flow is passed through the cathode side of the fuel cell while a fuel flow is passed through the anode side of the fuel cell. The oxidizing flow is typically air, while the fuel flow is typically a hydrogen-rich gas created by reforming a hydrocarbon fuel source. The fuel cell, operating at a typical temperature between 750° C. and 950° C., enables the transport of negatively charged oxygen ions from the cathode flow stream to the anode flow stream, where the ion combines with either free hydrogen or hydrogen in a hydrocarbon molecule to form water vapor and/or with carbon monoxide to form carbon dioxide. The excess electrons from the negatively charged ion are routed back to the cathode side of the fuel cell through an electrical circuit completed between anode and cathode, resulting in an electrical current flow through the circuit.
Fuel cell stacks may be either internally or externally manifolded for fuel and air. In internally manifolded stacks, the fuel and air is distributed to each cell using risers contained within the stack. In other words, the gas flows through riser openings or holes in the supporting layer of each cell, such as the electrolyte layer, for example. In externally manifolded stacks, the stack is open on the fuel and air inlet and outlet sides, and the fuel and air are introduced and collected independently of the stack hardware. For example, the inlet and outlet fuel and air flow in separate channels between the stack and the manifold housing in which the stack is located.
Planar fuel cells are usually stacked on top of one another with the stacking direction perpendicular to the planar cell elements thereby forming an electrical series connection. Any fuel cell stack requires a supply of fuel and oxidizer as well as depleted reactant removal (which usually entails two fluid streams, but these two streams may be combined into a single stream). In a power generator containing a multitude of fuel cell stacks, the reactant fluid delivery and collection to/from these stacks can create significant complexity. Therefore it is often desirable to minimize the number of stacks which may be accomplished by stacking more cells into each stack.
However, the number of cells that can be operated in a single stack is often limited by the reactant fluid, such as fuel gas, flow to the individual cells. The fluids distribution plenum that delivers the reactant fluids to the individual cells imparts a pressure drop on the fluid flow. A taller stack implies a larger pressure drop in the distribution plenum. One consequence of increasing pressure drop is that the fluid movers in the system (pumps, blowers, or compressors) consume more energy. Another consequence of the pressure drop in the fluids distribution plenum is that cells in different regions of the stack may experience different fluid flow rates.
In a stack with identical repeating elements, the performance is limited by the weakest cell. Cells with lower reactant fluid flow rates usually perform worse than cells with higher flow rates. The fuel supply is usually kept high enough so the cell experiencing the least fuel flow can still fulfill the performance requirements of the stack.
In a stack, all cells are usually operated electrically in series. Therefore all cells operate at the same current and all cells consume the same amount of fluids. Excess fuel supplied to the cell either has to be recovered and recycled or contributes to losses in the system.
High efficiency systems strive to minimize the cell to cell flow differences and maximize the attainable fuel utilization. FIG. 1 shows a typical internally manifolded fuel cell stack 1 comprising a plurality of fuel cells 3 in which the fuel is distributed within the stack in the so called risers or riser channels, which are formed by aligned openings in all electrolytes (and/or electrodes in electrode supported cells) and interconnects. In FIG. 1, fuel is supplied upward through the fuel inlet riser 5 and depleted fuel (i.e., the fuel exhaust) is removed downward through the fuel exhaust riser 7. If this stack is built very tall, the upper cells 3 will experience less fuel flow than the lower cells 3. Therefore, the total fuel flow rate to the stack has to be increased to provide enough fuel to the cells with the lowest flow (i.e. upper cells), while cells at the bottom of the stack are supplied with excess fuel. This excess fuel contributes to a loss of efficiency, unless the unused fuel is recycled.
Furthermore, solid oxide fuel cell stack columns can develop relatively large thermal gradients due to their configuration. For instance, the middle of two hundred cell stack column may be 100° C. greater than areas at the ends of the column. Such thermal gradients can affect the operation of the fuel cell stack because cells within the stack are not operating at an optimum temperature or within an optimum temperature range. For example, cells operating at a temperature that is lower than an optimum temperature can have a higher internal impedance, resulting in a lower voltage, and cells operating at a temperature that is higher than an optimum temperature can be subjected to higher rates of material degradation, causing the hotter cells to experience shorter cell lifetimes.
BRIEF SUMMARY OF THE INVENTION
One aspect of the present invention provides a fuel cell system, comprising a first fuel cell stack comprising a plurality of fuel cells of a first type, a second fuel cell stack comprising a plurality of fuel cells of the first type, and at least one hydrocarbon fuel reformer which is thermally integrated with at least a portion of the first stack. The second stack is arranged in a cascade configuration with the first fuel cell stack. The system is configured such that in operation, at least partial reformation of hydrocarbon fuel occurs prior to entry into the first stack or in the first stack, and the second stack uses fuel exhaust from the first stack as fuel.
Another aspect of the present invention provides a method of operating the fuel cell system, comprising reforming a hydrocarbon fuel to form a reformed fuel while cooling at least a portion of a first fuel cell stack, generating electricity in the first fuel cell stack using the reformed fuel, providing a fuel exhaust stream from the first fuel cell stack into a second fuel cell stack comprising the same types of fuel cells as the first stack, and generating electricity in the second fuel cell stack using the fuel exhaust stream from the first fuel stack as a fuel.
Another aspect of the present invention provides a fuel cell system, comprising a fuel cell stack comprising a plurality of fuel cells, wherein the fuel cell stack includes a middle portion of fuel cells and at least one end portion of fuel cells, wherein the fuel cells of the end portion is arranged in a cascade configuration with the fuel cells of the middle portion, wherein the system is configured such that in operation, at least partial reformation of hydrocarbon fuel occurs internally within the fuel cells of the middle portion and the fuel cells of the end portion are configured to use fuel exhaust from the middle portion as fuel.
Another aspect of the present invention provides a fuel cell system, comprising a fuel cell stack comprising a plurality of fuel cells, wherein the fuel cell stack includes a middle portion of fuel cells and at least one end portion of fuel cells, wherein the fuel cells of the end portion are arranged in a cascade configuration with the fuel cells of the middle portion, wherein the fuel cells of the middle portion are configured to internally reform a hydrocarbon fuel while cooling at least one of the fuel cells of the middle portion and configured to provide a reformed fuel to the fuel cells of the end portion.
Another aspect of the present invention provides a method of operating a fuel cell system, comprising internally reforming a hydrocarbon fuel to form a reformed fuel while cooling at least a fuel cell located in a middle portion of a fuel cell stack, generating electricity in the fuel cell stack using the reformed fuel, providing a fuel exhaust stream from the middle portion of the fuel cell stack into an end portion of the fuel cell stack, and generating electricity in the end portion of the fuel cell stack using the fuel exhaust stream from the middle portion as a fuel, wherein the middle portion and the end portion of the stack are arranged in a cascade configuration.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic side cross sectional view of a prior art fuel cell system.
FIGS. 2 and 3 are schematic side cross sectional views fuel cell systems of alternative embodiments of the present invention.
FIG. 4 is schematic, side cross sectional view of a portion of the fuel cell system with an external reformer of the embodiments of the present invention.
FIG. 5 is a schematic, side cross section view of a portion of a fuel cell system with internal reformation and fuel cascading of the embodiments of the present invention.



DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
FIG. 2 illustrates a fuel cell system 11 which includes a first fuel cell stack 21, and a second fuel cell stack 31 arranged in a cascade configuration with the first fuel cell stack 21. Preferably, the incoming fuel, such as a hydrocarbon fuel, is reformed internally in the first stack (i.e., in the anode chamber or outside the anode chamber) or externally to the first stack. The internal or external reformer is preferably thermally integrated with the first stack such that the external or internal reformation cools at least a portion of the first stack. The fuel then flows upward on the left hand side of the first stack 21. For example, the reformed fuel inlet stream may flow through a fuel inlet riser 25 if the fuel cells 23 of the first stack are internally manifolded on the fuel side. The depleted fuel (i.e., the fuel exhaust) stream is removed upward through the fuel exhaust riser 27 and into the fuel inlet of the second fuel cell stack 31. The fuel inlet riser 25 is blocked off at the interface between the first stack 21 and the second stack 31. Therefore, the depleted fuel of the first stack 21 is fed from the fuel exhaust riser 27 of the first stack 21 into the fuel inlet riser 35 of the second stack containing a plurality of fuel cells 33. Thus, the second stack 31 acts as a scavenger stack, operating on fuel left behind from the first stack 21.
The fuel cells 23 of the first stack 21 are the same type of fuel cells as the fuel cells 33 of the second stack 31. For example, the fuel cells 23, 33 may both comprise coplanar solid oxide fuel cells containing a solid oxide (i.e., ceramic) electrolyte, such as YSZ, an anode electrode, such as Ni-YSZ or another electrically conductive cermet, and a cathode electrode, such as LSM or another electrically conductive ceramic. Preferably, both stacks 21, 31 are located in the same housing or enclosure. Preferably, the first stack 21 contains more fuel cells than the second stack 31.
It should be noted that the fuel cells 23, 33 do not necessarily have to be internally manifolded and may comprise externally manifolded cells. Furthermore, while FIG. 2 shows that the stacks 21, 31 comprise a plurality of planar or plate shaped fuel cells 23, 33, the fuel cells may have other configurations, such as tubular. Furthermore, while solid oxide fuel cells are preferred as the fuel cells in the stacks, other fuel cell types, such as PEM and molten carbonate fuel cells may also be used. Still further, while vertically oriented stacks are shown in FIG. 2, the fuel cells may be stacked horizontally or in any other suitable direction between vertical and horizontal.
The term “fuel cell stack”, as used herein, means a plurality of stacked fuel cells which share common fuel inlet and exhaust passages or risers. The term “fuel cell stack” as used herein, includes a distinct electrical entity which contains two end plates which are connected to power conditioning equipment and the power (i.e., electricity) output of the stack. Thus, in some configurations, the electrical power output from such a distinct electrical entity may be separately controlled from other stacks.
The term “fuel cell stack” as used herein, also includes a part of the distinct electrical entity. For example, the stacks 21, 31 shown in FIG. 2 may share the same end plates, with one end plate being located below stack 21 and the second end plate being located above stack 31. In this case, the stacks 21, 31 jointly comprise a distinct electrical entity. In this case, the electrical power output from both stacks 21, 31 cannot be separately controlled.
During the operation of the system 11 to generate electricity from stacks 21 and 31, at least partial reformation of hydrocarbon fuel occurs prior to entry into the second stack 31. Preferably, but not necessarily, the second stack 31 lacks an internal hydrocarbon fuel reformer, such that no additional hydrocarbon fuel reformation occurs in the second stack during operation.
The hydrocarbon fuel may be reformed internally in the first stack 21, in which case the first stack 21 contains an internal reformer inside its housing. In other words, the reformer(s) may be located inside the stack 21 housing, outside and/or inside the anode chamber(s) of the stack. The fuel reformer may comprise a reformation catalyst coated passage located adjacent to the fuel cells.
Alternatively, the hydrocarbon fuel may be reformed externally in an external reformer. An external reformer is located outside the housing of the first stack 21. In this case, the external reformer is preferably thermally integrated with at least a portion of the first stack 21. The term “thermally integrated” in this context means that the heat from the reaction in the fuel cell stack 21 drives the net endothermic fuel reformation reaction in the fuel reformer and the endothermic reformation reaction in the reformer thus cools the stack 21. As illustrated in FIG. 4 and as described in more detail below, the external fuel reformer may be thermally integrated with the fuel cell stack 21 by placing the reformer and stack in the same hot box and/or in thermal contact with each other, or by providing a thermal conduit or thermally conductive material which connects the stack 21 to the reformer.
Thus, the internal or the external thermally integrated reformer is used for cooling at least a portion of the first stack 21 using the endothermic hydrocarbon reformation reaction in the reformer. For example, the hydrocarbon fuel may comprise methane or natural gas (which comprises methane and other gases) and the endothermic reformation reaction may comprise the steam-methane reformation (SMR) reaction. Other hydrocarbon fuels, such as pentane, propane, etc. may also be used. The cooling of the stack allows the average temperature of the stack to be decreased. This helps to reduce high temperature oxidation of the metal interconnects/gas separator plates located between the fuel cells.
As shown in FIG. 2, the first fuel cell stack 21 includes a fuel inlet port 22 and a fuel exhaust port 24. The second fuel cell stack 31 includes a fuel exhaust port 34 and a fuel inlet port 32 which is fluidly connected to the fuel exhaust port 24 of the first stack 21. The term fluidly connected, as used herein, means that the fuel exhaust stream from the first stack can travel from the fuel exhaust port 24 into the fuel inlet port 32 either directly or indirectly through a connecting conduit.
For example, as shown in FIG. 2, the fuel exhaust riser 27 of the first stack 21 is aligned to the fuel inlet riser 35 of the second stack 31. In this case, the fuel exhaust port 24 and fuel inlet port 32 comprise adjacent contacting portions of the fuel exhaust riser 27 and the fuel inlet riser 35, respectively. In other words, the fuel cells 23, 33 are simply stacked over each other and the risers 27 and 35 constitute a single, continuous passage through the fuel cells of the stacks 21 and 31, respectively. One of the fuel cells, designated as 23A, contains a blocked fuel inlet riser channel 25 by lacking a fuel inlet riser opening in its supporting layer, such as in an electrolyte, in an electrode and/or in a gas separator plate. This fuel cell 23A acts as a partition between the first stack 21 and the second stack 31. Thus, the fuel inlet riser 25 of the first stack 21 is connected to the fuel inlet port 22 of the first stack 21. The fuel exhaust riser 27 of the first stack 21 is connected to the fuel inlet riser 35 of the second stack 31. The fuel exhaust riser 37 of the second stack 31 is connected to the fuel exhaust port 34 of the second stack 31. In the configuration of the embodiment of FIG. 2, there is only one inlet port 22 and one exhaust port 34 which are connected to outside components for both stacks 21, 31. This reduces the complexity of the system.
In configuration described above, the first stack 21 and the second stack 31 comprise a common electrical entity and share the same set of end plates. In other words, all fuel cells 23, 23A and 33 of both stacks 21, 31 are connected in series with each other, with one end plate being located in electrical contact with the bottom fuel cell of the first stack while the second end plate being located in electrical contact with the top fuel cell of the second stack, and both end plates being connected to a power conditioning system.
The first stack 21 can be built higher than commonly practiced by accepting the fuel misdistribution the first stack 21. In other words, the total fuel flow rate to the stack 21 is increased to provide enough fuel to the cells with the lowest flow (i.e. upper cells), while cells at the bottom of the stack are supplied with excess fuel. However, this excess fuel is not wasted with the fuel exhaust, because the fuel exhaust is provided as fuel to the second stack 31. The second stack 31 is preferably kept short enough to satisfy approximately equal flow through all fuel cells 23, 33, which allows maximum fuel utilization. The distribution of the cells between the stacks 21, 31 can be optimized.
While two stacks 21, 31 are illustrated in FIG. 2, three or more stacks, such as three to ten stacks may be provided in the cascade configuration. In this configuration, each subsequent stack uses the fuel exhaust stream from the previous stack as a fuel source.
FIG. 3 illustrates a fuel cell system 41 according to a second embodiment of the invention. The system 41 is the same as the system 11 of the first embodiment, except that the first stack 21 is located above the second stack 31. In other words, the system 41 comprises a vertical system which is turned upside down compared to the system 11 of the first embodiment. Preferably, the fuel inlet port 22 of the first stack 21 of the system 41 is located in an upper portion of the first stack 21.
In the third embodiment, the reformer is selectively thermally integrated with a portion of the first stack 21 which operates at a higher temperature than one or more other portions of the first stack.
In general, the fuel cells in the middle portion of a fuel cell stack operate at a higher temperature than fuel cells in the end portions of the stack. In vertical fuel cell systems, where the fuel cells are stacked in a vertical direction, this means that the middle fuel cells generally operate at a higher temperature than the upper or lower fuel cells. However, it is possible that in some stack designs, the upper fuel cells may operate at a higher temperature than the lower fuel cells or even the middle fuel cells. Thus, the average operating temperature of the fuel cell system is often kept below a desired temperature in order to maintain the operating temperature of the middle fuel cells below a temperature at which the adjacent metal interconnects are significantly oxidized or damaged. This means that the end (i.e., upper and lower) fuel cells are operated below a desired operating temperature in order to maintain the predetermined average operating temperature of the system.
Thus, in the third embodiment of the invention, the hydrocarbon fuel reformation reaction is used to selectively cool the middle fuel cells in the system in order to provide a higher average operating temperature for the system. For example, the middle fuel cells may be cooled to a greater extent than the upper and lower fuel cells to provide a more uniform operating temperature among all fuel cells of the system and to allow the system as a whole to operate at a higher average temperature without significantly oxidizing or damaging the metal interconnects adjacent to the middle fuel cells.
In one aspect of the third embodiment, an internal reformer is provided in a middle portion of the first stack 21. The internal hydrocarbon fuel reformation reaction in the middle portion of the first stack 21 cools the fuel cells 23 in the middle portion of stack 21 more than fuel cells 23 in upper and lower portions of the first stack 21 as well as more than the fuel cells 33 in the second stack 31. An internal reformer located inside the riser channels would not selectively cool the stack in the hottest area. Thus, in the third embodiment, an internal reformer cavity may be added into the stack in which the fuel flows from a center feed outward while being reformed. At the end of the stack, the fuel flow gets turned back into the normal stack riser channel. This allows the first stack or the first and second stacks to be operated at a higher average temperature without significantly oxidizing or damaging the metal interconnects adjacent to the middle fuel cells 23. It should be noted that the internal reformer may be provided in an upper portion of the stack 21 if the stack 21 is configured such that the upper portion usually operates at a higher temperature than the middle portion of the stack 21.
In another aspect of the second embodiment, an external reformer is thermally integrated with the middle portion of the first stack 21. This thermal integration may be provided by placing the reformer in thermal contact with the middle portion of the stack 21 or by providing a thermal conduit or thermally conductive material which connects the middle portion of the stack 21 to the reformer. However, the external reformer is not intentionally thermally integrated with the end portions of the stack (i.e., the reformer is not placed in thermal contact with the end portions of the stack where the upper and lower fuel cells are located). It should be noted that the external reformer may be thermally integrated with an upper portion of the stack 21 if the stack 21 is configured such that the upper portion usually operates at a higher temperature than the middle portion of the stack 21.
FIG. 4 schematically illustrates a system 51 in which an external reformer 9 may be thermally integrated with the middle portion of the first stack 21. Examples of reformer-stack configurations are provided in US Published Application 2005/0164051 A1 filed as U.S. application Ser. No. 11/002,682 filed on Dec. 2, 2004, incorporated herein by reference in its entirety. The external hydrocarbon fuel reformer 9 is located separately from but thermally integrated with at least the first fuel cell stack 21 to support the endothermic reaction in the reformer 9 and to cool at least the middle portion of the first stack 21. The external reformer 9 may be thermally integrated only with middle but not upper or lower fuel cells of the first stack 21. For example, the reformer 9 may be located adjacent to the middle fuel cells of the first stack 21 but not adjacent to the upper or lower fuel cells of the first stack 21. Thus, the reformation reaction in the reformer 9 cools the middle cells more than the upper or lower cells of the first stack 21.
The system 11, 41, 51 of the first, second and third embodiments may also contain a burner or combustor 15, as shown in FIG. 4. Thus, the system comprises a thermally integrated reformer 9, combustor 15 and stack 21. The reformer 9 may be heated by the fuel or air exhaust from the stack, by radiative and convective heat from the stack and/or by the combustor heat during steady state operation.
Preferably, the reformer 9 is sandwiched between the combustor 15 and the stack 21 to assist heat transfer as described in more detail below. For example, the reformer 9 and the housing of the stack 21 share at least one wall. Thus, the stack 21 is located on one side and the reformer 9 is located on the other side of the wall. The wall may comprise the stack 21 housing wall.
The reformer 9 and combustor 15 may also share at least one common wall. Thus, the reformer 9 may comprise a reformation catalyst coated channel located between the stack 21 and the burner 15. For example, the reformer 9 may comprise a cylindrical reformer with the burner 15 comprising a concentric cylinder located in the core of the reformer cylinder. Alternatively, the reformer may comprise a plate shaped reformer comprising a catalyst coated passage located between the burner 15 and stack 21.
The combustor 15, when attached to the reformer 9, closes the heat balance and provides additional heat required by the reformer. When no heat is required by the reformer, the combustor unit acts as a heat exchanger. Thus, the same combustor (i.e., burner) 15 may be used in both start-up and steady-state operation of the system 1. When using combustion catalysts coated on the conduit walls, natural gas is preferably introduced at several places in the combustion zone to avoid auto ignition and local heating.
A method of operating a fuel cell systems 11, 41 of the first and the second embodiments includes reforming a hydrocarbon fuel to form a reformed fuel, generating electricity in the first fuel cell stack using the reformed fuel, providing a fuel exhaust stream from the first fuel cell stack into a second fuel cell stack, and generating electricity in the second fuel cell stack using the fuel exhaust stream from the first fuel stack as a fuel.
The step of reforming includes reforming a hydrocarbon fuel, such as methane or natural gas, in an internal reformer in the first stack 21 or in an external reformer 9 which is thermally integrated with at least a portion of the first stack 21. In operation, the hydrocarbon fuel and steam mixture is fed into the reformer 9 through a fuel inlet conduit 13. If desired, some of the fuel may be provided directly into the stack via a by-pass conduit which by-passes the reformer 9. In case of methane or natural gas fuel, the fuel and steam mixture is at least partially reformed by the SMR reaction to produce a reformed fuel stream comprising hydrogen and carbon monoxide as well as unreformed methane and carbon dioxide. The reformed fuel stream is provided from the reformer 9 into the stack fuel inlet 22 (i.e., the anode inlet in a SOFC stack) through conduit 14. Preferably, the reformed fuel stream is provided into the upper portion of the first stack 21 in the system 41 of the second embodiment. The reformation reaction, such as the partial SMR reaction in the reformer 9, cools at least a portion of the first stack 21.
The reformed fuel passes through the fuel inlet port 22 of the first stack 21 into the fuel inlet riser 25. The fuel then moves across the fuel cells 23 and out through the fuel exhaust riser 27 as a fuel exhaust stream. The fuel exhaust stream is then provided through ports 24 and 32 into the fuel inlet riser 35 of the second stack 31. This stream then moves across the fuel cells 33 and out through the fuel exhaust riser 37 and fuel exhaust port 34.
The air or another oxidizer enters the stack 21 through the air (i.e., cathode in a SOFC stack) inlet and exits through the air exhaust conduit (not shown for clarity in the figures). The system 11, 41, 51 of the first, second and third embodiments may be internally or externally manifolded on the air side. Furthermore, the air may be provided in a cascade or a non-cascade configuration through the stacks 21, 31. In a SOFC, the oxygen ions travel through the electrolyte of the fuel cells 23, 33 to combine with hydrogen in the fuel stream to form water. The oxygen ion conduction generates electricity from the fuel cells.
In a further aspect, a fuel cell stack can be provided to minimize thermal gradients that can occur within fuel cell stacks. Such a fuel cell stack can be configured to perform internal reformation in a middle portion of the stack and to cascade fuel from the middle portion of the stack to the top and bottom ends of the stack.
FIG. 5 shows an example of a stack 100 of fuel cells 110 that include a first group of fuel cells 110 arranged in a middle portion A of the stack 100 and groups of fuel cells 110 arranged in end portions B of the stack 100. The middle portion A of the stack 100 can be a stack portion where the temperature of the stack is highest. The middle portion A can also be referred to as a first stack of fuel cells and an end portion B, as shown in the example of FIG. 5, can be referred to as a second stack of fuel cells.
Fuel cells 110 of the middle portion A of the stack 100 can be configured to perform internal reformation. Internal reformation can be conducted by, for example, steam reformation or other forms of internal reformation used in the art. Because internal reformation is an endothermic process that absorbs surrounding heat, the fuel cells 110 of the middle portion A can thus be configured to assist in the thermal management of the stack 100 due to the internal reformation. The fuel can be partially, substantially completely, or completely reformed within the middle portion A of the stack 100 to form reformation products, such as, for example, carbon monoxide and hydrogen. Some of the reformation products are consumed by reactions within the middle portion A to produce waste heat, and this waste heat can be absorbed or consumed by the endothermic reformation reaction within the middle portion A. Thus, the fuel cells 110 of the middle portion A can be configured to reduce or minimize thermal gradients that can exist between a middle portion or region of the stack 100 and the top and bottom end portions or regions of the stack 100.
As a further step for reducing or minimizing thermal gradients within a stack 100, the stack 100 can be configured so that fuel, reformation products, and/or other species flowing through the fuel cells 110 of the stack 100 flow in a cascading pattern. Such a cascading pattern can act to more evenly distribute heat amongst the fuel cells 110 of a stack 100.
In the example of FIG. 5, air can be introduced to the stack 100 as indicated by arrow AI and the exhaust air can exit the stack 100 as indicated by arrow AE. Fuel can be introduced to the middle portion A of the stack 100 as indicated by arrow FI. For example, the fuel can be introduced into the stack 100 by a middle fuel distributor plate 130 that separates fuel cells 110. The fuel can be, for example, a mixture of natural gas and water vapor, such as that used for single pass internal reformation, or a fuel mixture typically used for simple partial anode exhaust recycling (where the stack anode (i.e., fuel) exhaust stream is directly recycled into the fuel inlet stream), or a fuel mixture typically used for anode exhaust fuel separation and recycling (where hydrogen and/or water are separated from the anode exhaust stream and recycled into the fuel inlet stream), or other fuel mixtures used in the art.
After the fuel is introduced into the middle portion A of the stack 100, such as, for example, via a middle fuel distributor plate 130, the fuel can enter into and flow vertically within a riser 120. The fuel can then flow horizontally from the riser 120 to fuel cells 110 within the middle portion A of the stack 100 and be internally reformed. The top and bottom ends of the riser 120 can be closed or sealed by separation plates 140 within the stack 100. In one configuration, fuel, reformation products, and/or other species can flow through the fuel cells 110 in the middle portion A in a counter flow arrangement in which the fuel flows on one side of a gas separator/interconnect in an opposite direction to the air flow on the other side of the gas separator/interconnect. Fuel, reformation products, and/or other species flowing through the fuel cells 110 within the middle portion A can then be collected by a second risers 122 that bridge the fuel cells of the middle portion A and the end portions B of the stack 100. The second risers 122 can be closed or sealed in a middle portions of the stack by the fuel distribution plate 130 or another partition, as shown in the example of FIG. 5.
Fuel, reformation products, and/or other species flowing within the second riser 122 can then flow horizontally from the second riser 122 into fuel cells 110 within the end portions B of the stack 100, as shown in the example of FIG. 5. Thus, fuel cells 110 in the end portions B, which can be “colder” (i.e., operating at lower temperature) than fuel cells 110 within the middle portion A when a temperature gradient exists, can be warmed by the fuel, reformation products, and/or other species flowing into the fuel cells 110 of the end portions B. In one configuration, fuel, reformation products, and/or other species flowing through the fuel cells 110 of the end portions B can flow, in a co-flow configuration in which the fuel flows on one side of a gas separator/interconnect in the same direction to the air flow on the other side of the gas separator/interconnect. Fuel, reformation products, and/or other species flowing through the fuel cells of the end portions B can then be collected by the fuel exhaust risers 124 so it can be exhausted from end plates 150 in the stack, as indicated by arrows FE in the example of FIG. 5.
Depending on the desired layout, the fuel cells 110 can be arranged so that fuel, air, and/or other species flow in a co-flow, counter flow or cross flow arrangement within fuel cells 110 of the same or different portions of a stack 100, such as a middle portion A and/or end portion B of the stack 100. However, it is preferred to arrange the cells in the internally reforming portion A of the stack in a counter flow configuration, and to arrange the cells in the non-internally reforming portion(s) B of the stack in a co-flow configuration because in an internally reforming fuel cell, the internal reformation typically happens near the fuel inlet (i.e., the leading edge of the cell) which provides substantial cooling in this area. The fresh air also provides cooling to each cell near the air inlet on the opposite side of stack. In the counter flow configuration, one side of the stack (and thus one side of each cell) is cooled by internal fuel reformation and the other side of the stack (ad thus the other side of each cell) is cooled by the cool air to maintain a relatively uniform temperature across each cell and across the stack. In other words, the cool air is not required to cool the fuel inlet side of each stack due to the endothermic reformation reaction at that side of the stack. In the non-internal reformation portion of the stack, the fuel inlet side typically runs at higher current densities (and thus a higher temperature), due to the fresh or fresher fuel provided to that side of the stack compared to the fuel outlet portion. In this part of the stack, the cool air is provided into the same side of the stack as the fuel to balance or counteract the additional heating provided by the higher current densities at the fuel inlet side of the stack. Therefore, the co/counter flow configuration shown in FIG. 5 is thermally advantageous.
In a further example, the fuel cells 110 of the end portions B can be designed to include oxidation tolerant or oxidation resistant anodes while the fuel cells of the middle portion A include anodes which are less oxidation resistant but which contain a fuel reformation catalyst material. The risk of anode oxidation increases as the fuel gets more and more depleted. Therefore, the trailing edge of the last (scavenging) stage(s) of the stack (e.g., the end portions B of the stack) benefit the most from the generally poorer performing oxidation resistant anodes. With a fully oxidation resistant anode, a higher fuel utilization can be realized (e.g., higher than 75%, such as 80 up to 100% utilization), even in the normal non-ideal case where some areas of the stack receive less fuel than others.
For example, the fuel cells 110 of the end portions B can include oxidation resistant anodes as discussed in U.S. application Ser. No. 11/526,029, filed on Sep. 25, 2006, which is hereby incorporated by reference in its entirety. Such oxidation resistant anodes can also be made from a noble metal, such as, for example, platinum, or from a conductive ceramic, such as, for example, LSM.
In another example disclosed in U.S. application Ser. No. 11/526,029, the oxidation resistant anode is composed of a mixed composition of the higher oxidation resistant material and the higher performance, lower oxidation-resistant material. This composition is a ceramic in the oxidized state, and is a cermet comprising a metal phase of nickel and at least one of Fe or Co, and a ceramic phase comprising TiO2 in the reduced state. Through reoxidation, the nickel forms insulating NiO in the oxidized state, while the titanium-based phase provides electrical conductivity, thus preserving performance while minimizing anode damage due to high fuel utilization. As one example, in an oxidized state, the anode electrode may comprise TiNi(1-x)(Co, Fe)xO3, where 0.2≦x≦0.5. The Co and/or Fe acts as the conductivity enhancing dopant. If the end user reduces the composition, the anode electrode will comprise a cermet having a ceramic phase comprising titanium oxide, and a metal phase comprising nickel and at least one of Co or Fe.
In another example disclosed in U.S. application Ser. No. 11/526,029, an anode electrode comprises two portions of anode material. The first portion comprises a first anode material and the second portion comprises a second anode material. The first anode material comprises a first higher performance, lower oxidation resistant material than the second anode material. In one configuration, the first anode material is located adjacent to fuel inlet and the second anode material in portion is located adjacent to fuel outlet of each anode electrode of each cell 110 in portions A and/or B. In another configuration, the first anode material is located in cells 110 in portion A and the second anode material is located in cells in portions B. The first anode material may comprise a nickel cermet material. The second anode material may comprise a titanium containing rutile or pyrochlore material. For example, the first anode material may comprise a nickel-stabilized zirconia cermet, such as a nickel-yttria or scandia stabilized zirconia. The second anode material may comprise materials such as Nb0.7Ti0.3O2 or Gd2Ti0.6Mo1.4O7.
The number of fuel cells 10 in each of the middle portion A and the end portions B of the stack 100 can be varied, as well as the ratio of the size of the middle portion A to the end portions B. For example, the number of fuel cells 10 in each portion and the relative size of these portions can be varied to control the thermal management of the stack 100 and to reduce or minimize thermal gradients within the stack 100.
In another example, the size of the middle portion A can be the same size as the cumulative size of the end portions B. In another example, a middle area or portion of the middle portion A of the stack 100 is configured to cool fuel cells 10 in the middle portion A of the stack more than fuel cells 110 in upper and lower end portions B of the stack.
The example of FIG. 5 shows fuel cells 110 configured to perform internal reformation grouped together as a single group within the middle portion A of a stack 100 and fuel cells 110 grouped together in end portions B that do not perform internal reformation. In another example, fuel cells configured to perform internal reformation can be interspersed or distributed amongst non-internally reforming fuel cells in order to manage thermal gradients within a fuel cell stack. For example, non-reforming and internally reforming fuel cells can alternate with one another, every third fuel cell can be configured to perform internal reformation, or other configurations can be used to control thermal gradients within a fuel cell stack.
A fuel cell stack 100 configured as described above can advantageously have an extended lifetime in comparison with conventional fuel cells, provide an increased voltage and efficiency in comparison with conventional fuel cells, provide a higher single pass fuel utilization rate due to the cascading configuration of the stack, and provide lower fuel utilization per cascade, which permits the use of cell components, such as manifolds, with smaller diameter holes or passages. Furthermore, introducing fuel into a middle portion of a stack provides a single fuel inlet, which reduces the complexity and cost of a fuel cell stack.
The foregoing description of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed, and modifications and variations are possible in light of the above teachings or may be acquired from practice of the invention. The description was chosen in order to explain the principles of the invention and its practical application. It is intended that the scope of the invention be defined by the claims appended hereto, and their equivalents.

## Claims

1. A method of operating a fuel cell system, comprising:
internally reforming a hydrocarbon fuel to form a reformed fuel in at least one fuel cell located in a middle portion of a fuel cell stack;
generating electricity in the at least one fuel cell located in the middle portion of a fuel cell stack using the reformed fuel;
providing a fuel exhaust stream from the at least one fuel cell located in the middle portion of the fuel cell stack into at least one fuel cell located in an end portion of the fuel cell stack; and
generating electricity in the at least one fuel cell located in the end portion of the fuel cell stack using the fuel exhaust stream from the at least one fuel cell located in the middle portion of the fuel cell stack as a fuel;
wherein the fuel cells located in the middle portion and the end portion of the fuel cell stack are arranged in a cascade configuration; and
wherein the internally reforming step selectively cools the at least one fuel cell located in the middle portion of the fuel cell stack using a hydrocarbon reformation reaction.

2. The method of claim 1, further comprising a step of introducing the hydrocarbon fuel into a fuel inlet port located in the middle portion of the fuel cell stack.

3. The method of claim 1, wherein the internally reforming and generating electricity steps include:
flowing the hydrocarbon fuel and the reformed fuel in a counter-flow arrangement with air within the at least one fuel cell located in the middle portion of the fuel cell stack; and
flowing the fuel exhaust stream in a co-flow arrangement with air within the at least one fuel cell located in the end portion of the fuel cell stack.

4. The method of claim 1, wherein the end portion of the fuel cell stack comprises:
the at least one fuel cell located in a first end portion of the fuel cell stack arranged on top of the middle portion of the fuel cell stack; and
at least one fuel cell located in a second end portion of the fuel cell stack arranged below the middle portion of the fuel cell stack, wherein the at least one fuel cell located in the second end portion is configured to use fuel exhaust from the at least one fuel cell located in the middle portion of the fuel cell stack as fuel.

5. The method of claim 1, wherein the fuel cells located in the first and the second end portions of the fuel cell stack include oxidation resistant anodes and the at least one fuel cell located in the middle portion includes an anode comprising a fuel reformation catalyst.