### ~i~1 DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfrY DMSION PO BOX 1677 OKLAHOMA CfTY, OK 73101-1677 

# EXCESS EMISSION FORM OTE[ The infom

~ ation requested below should be submitted to the address above witbin 10 worldng days after the immediate notice is given, tf you are using this form to corrcct a previous on, provide only the corzected infotmation below, sign the certification, and attach a copy of the pn:vious report.
REPORT DATE: COMPANYNAbtE:

1/972009 DaI-ttalia NAME OF INDIVIDUAL REPORTING: TITLE: PIIONE: Rkk l

~ d8ams Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: Dal-ItaBa Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: ll4/2009 0:00 0:00 0:00 Hours:Min Phase 1

7:50 9:30 1:40 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### t:40 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: BASiS OF ESTIMATE Compli.^-

~ ceTasti ~~~ X

_ ~ .._._.._.. __._.._.. - _....__. _. _ ...._. SOURCE GRP HF HCL SO ~ CO VOC NOx PM FI!C t

_ ...... ......._..._ ._...._._.... ....___ .. _..___... .__ .__.._. ._......_.__. . ._ .__...__. . ..._...__._.. ..._ f: U G 2 .._ .....___ _._...._ __.___. ..... _._ _..._..._ _.__.,_.__._... .._._._._. . _..__.. ._ Cont Fmission, `,tnnitoring _._ .......___ _.___. .._...__. ......__. . Pa

~~ G 3 sDl 0.33

....__. . ...__ 0.00

_.. ._. ____._ 0.1 ~

. ___...____ 5.33

...... _._ . . ...._ t.84

.__... . __._._._... 1.68

. ... . ____. 3.33

. ._....-_.__ .. Fnginccring C:dcul;uion X

..._...__ ._...__. ..__...._. .._._..._... ___.._. Et

~~ C3SD2

... _ O.t7 __ ....... ............ 0.00

._. . __...__..._ 0.00

. _-._...._..._ .. . 3.81

__---_. _ ___ 0.59

.__._. .._ ...._..._. L24

_ _._..._. 1.63

.._.______ Oper:aingt.ogs X

..._._. . __..._..__ _....... _.. ..____._ ___... ha' ~ G 3

~ 't)sl 0.03 0.00 ._ ._... . 0.00

. .... 6.11

. _._. ..._.......__. 0.77

. ._.__.._ L20

__ .. . 2.65

_..... _..._..__._ - . . OC+er (c

~ plain)

.____.. ........_.... _...__._._. . ___._.... i:UG41 - tis'

. 0.01
__ .._...._. 0.00

_... . _ 0.00

_ ..____ 1.78

.. .. __.._._ _ 0.-2 ._. __- 0.35 __. .__.. 0.77

_....._._.... .. _. _._._ . _..__.__ __......... ._. __...__. . . .____._. EUG5-

~ l;

~ l ..__ . ~~ ~ 0.01

..._..... 0.10 ~~~~~~~~~

_ ...... ..- ~~-~-~ 0.11

. . . ~~ - ~~~~~ 4.46

._ ... . . _

.. .... 0.29

....... . ..._._, L52

...._.._ 0.90

.. . . . ._._ ._ .._..

.._.._..._ .. .__._ ._____ ..._.____, FtiG5-lss? _._ . 8.68
. ~~~~~~~~

__ ......._ ..._.._..._._ 10.34
_ ~ 28.59

~~~~ . ~~~ 18.81

. _._._ .._ .._._.__.. ..... _ S;8 ..._ ....... . ........... ~~~ 7.40

....____ . ~~~ 10.07

_..__.__ ...._._.._._ .._____. ..__._...._._ . _..._._ . _.___ t:CG5-Trim ~ t.23 t.57 3.49 2.45 0.68 0.95 0.73 _....___ .___...__.. ..__..... .... _..__ ......._.. ALLOWED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO, CO VOC NOx PM EllG 1

_ .. ... ...... _.. _. _._.._ _- --..._........._. .............. .. .... .... . _....... _...._...._.._ . . ....._.._.. .,..._....... _____... El

~~ (; 2 .._ __. . .. .. _.... ... . _ . _ . ...._....... . _..____ . ._. ...__. ___ ELG3SUl __... _ _ 0.59

........_.. ___. 0.10

.... __._._....._. 0.

~ 45 1377 ....._._.... . .._.....__.. 967

.. _._._..._ _. 3.88

' ___._.__.. 7.98

.-_._.__..__.._..__. EIiC 3 SDZ __.. . 0.95

.._..__ ___.._ 0.90

..._ . ....._.._.._. 0.49

. _.. __ _.. 13,77

............ .. 9.67

.._.._ __.. ..._,..._ 3.88

... . ....__.__ 7.98

__.._.__....___. ECGa VD.cI ._... 0.72

_...._. .._... . 0.08

... .... .. ........_ O.Ifi

..._... . . 11.43

__ _... .. 38.33

.__... .. _. ........._ 3.51

. . .__._._. 5.89

.._._..._.._.. ..._._. Et'G 4 VUs? __._ _ _ 0.52

..._..... _..._.._. 0.06

.._......._ ___.... 0.05

._... 5.09

....._... ._. . 17,04

..... _ .. ___....._ t i6

......_.._.. 2.60

.__._..._ ................_. ELGS-

~ 1.SI

.. _......... L43

.......... ._..___...__ t.60

._____. 3.9b [2G0

.. 4.7R 7.73 .....__. 6.71 EUGS-FVS2

.............. .. . 2.85

.___.__. . _ _ _. ..._. 3.20

..__ . . ..._ _._.... 17,)Z

.. _ .. _.. .... 39.20

._._.... .. . . . _. 9.56

._...... .. ........_. 15,45

. _..._ ._.__... .. 13.42

. ... ._. .. ...._. EUG5-Trim 3.57 3.88 9.68 6.75 3.67 2.00 L80 EXCESS EMISSIONS: (based on i hour 17mhs EXCESS Eh11SSIONS: 24-Hr Totnlc SOURCEGRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG I

....... .. ...__.._ ..._......_ _._ _...._.._..._ ._._._....._. .. .__._ ........ ......... __.._... .. ....._._... _._.._... None ._.... .. _...._._ .._.__..... ....._.. .__.. _ .._...___ .__...._...... None ....,_.._ ..... EUG 2 _._. .___ ...... ............. ......._...._ ._........_._ .....___ _ _..__.._ ......__........ .__._..__ None ._._. _ __._.__ . ._____. .__ .. _._._.__ ......_.. None .._....._ EUG3SD1

......... None

._._.___ ... _..__ None

.._. .___._.___. None

.__.._._._ _._... ~ one

..___ ..... None

....... . .......__... None

.__.__.. Nonc

.___._ _ ~ une

.. None

..... .._._ None

. ....._._ None .___ . . None .._.._.._.. None

.._..._._.. None ...___._.. EUG 3 SD2 ......_.... None

..__....._. ._..___. None

... ...._....._ None

.......__._._ Aonc

. _..._.... None

.....__..._... None

. ._...__..._. None

_._....__... Nonc None .__._._. None

. __......._... None

.. None .___._. None _...___._.. None

_...__._._. EUG 4 CDst

.......... None

._...__._...,___ ........ None

. ..........._ None

......_..___. None

_...__.. . ..._..___... None

. _......._..... None

..._._..._. None

.._.............. ..._... Nune

__ None ....___.._... None

..._..__ None

__ . .. Noae _..,._..._ None

.__........ None ..._....._... EUG41

~ Ds2 .._.......... None

___... .._....-_._... None ,..__..__ None

_......... None

....__._. __ None

........ ._._..__._... Nune

. ____.._.... None

, ._..__... ........_..

None None

..._.._..__ None

..._._ None _ ..... ...........__.

None None

........... None ._....__... EUG s-tl:St

.... .... None

....___ . _ _ __..__ None

.__ .._...._... None

....__ None

.___... ._.. None

____ . . ............... None

...__........... None

_.._....__.. None

..._....... None ._._._...._... None

. - ...._. None __... ... None ___.._.._ .. None

..._._.. None ..____... EtiGi-

~ 1S2 .__._. _ .. 5.83

.__.. .___...___ 7.14

........__...... 10.67

......._.... None

__...___ . ................ None

.................. None

....._...... None

.._...._._.. _...._.._....

None , None _..._...___. None .._____.._.... None None _..._.._.. Nnne

.___..._. None ..._..._..__. EUG5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenance to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber N2 CORRECTIVE MEASURES TAKEN: (2) The no

~

sles were ckaned and the serubber was restarted. ADDITIONAL INFORMATION` t : The Wet Scrubber was maintamed and operated according to the manufacture's instructions. The repafrs and maintenance were done as quictdy as possOtle, utiliring overtinte if needed. I certify, based on information and be0ef formed after reasunable inquiry, the statements and'mformatiun in thic document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received Bv: Demonstration of Canse Submitted:

~ No ~ ~ ~ ~ AGENCY USE ONLY TrackingNumber: Team ID: DatcSubmitted:

~ ` Ifyrou u

~ ish to notify the DEQ about a technological limitation, do so here and attach supporting fnformation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for 1Vlaintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 1/5/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 1/4/2009 7:50AM SUBMITTED: SUBMITTED: 100 Minutes EE ID #, if a licable: 1/5/2009 1/6/2009 

# ***The owner or operator must delnonstrate each of the following items in order for the excess emission to be considered exempt fTom compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous 1ogs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to do the PM. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

### - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- 7

- . - . -



# (4) The facility was operated in a matmer consistent with good practice for mmlnl zmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to mininiize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible.

m 

# ------------------------------ = ---------------- (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, conteinporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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# c u - m e — n t -a r e — t r - u e — , accurate and complete.



# SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Forin # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALI7Y DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM . OTE: The infomiation requested below should be submitted to the address above within 10 working days afler the immediate notice is given. If you are using this form to correct a previous port, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

I19/2009 Da)•ItaBa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick 1V'dGams Plant hlanager (918) 6834043 FACIL1Tl': COUNTY: PERMIT NUMBER: Da6ltalia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMtSSION: Date Start Time: Stop Time: Duration: 117l2009 0:00 0:00 0:00 Hours:Min Phase 1

13:10 13:40 0:30 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 Hours:MinutesofWetScrubberpo\vnfinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Perntit No. 2004-198-TV (;11-1): SpecOk Conditiun t, EUG 5 ESTIMATED EMISS)ONS: BASIS OF ESTIMATE ComplianceTesting

. .. ,.._..___. .._.._._. ._..___. ...._.._. . .__.... X SOURCE GRP t{F HCL SO z CO VOC NOx PM EUG I ._.__.._._........ _._.... _.._. __. . .___... ....__.. .__.._.. .. __.._. _._.._._.. _...__._ __....__.._ EUG 2

...... _...... .._. . _ _._._. . ......... ........ . . .... ...... ...._.___ . ..._.__.. _..._._.... Cont Fmissions Monitoring ........___ .....__ . _.._..__ . .___._.. ._ ._......._ . X EUG3SDl .....___._.. _ OAO

.__........ _.__ 0.00

.__ . _..__...._ 0.17

.....__.. 6A1

_. ..__ _.. 2.21

_._......._. 2.01

.. ._._.__.. 4.00

.__...._ EnginceringCalculation

._..._.... _. ..... ...._.._.. _.. _ __.__. _._._..__.. X EUG 3 SD2 .-.. . _ 0.20

._...__ _. 0.00

_.._ 0.00

.._. . 4.38

...... . 0.67

. ._... 1.43

. 1.87

. ._ Operating Logs

.._.__.. . ..._.. . ...._. EUG4VDs1

...... . . 0.03
_

. ... .... . . 0.00

..._ . . ... _. 0.00

. . .._ 6.15

._._. . ... 0.77

.__..... _. 1.21 ~_~ .... _

_ . ...._. 2.67

_ .. .. ......_. ~-~--~ Other(explain)

_._..._. ._ .. .... . ._..... . . ...___._._ . ...___.__. EUG 4 VDs2 0 .01 ~ __.. 0.00 .._.. . _....__ 0.00 _2.68
_ . ._ . . .. 0.34

. . _ _ _ ._.._._._ _ 0.52

.. _ .__ . 1.16 EUGS-\VSI

. .._. . 0.01

_. _.._ . _.. _ _ 0.15

_.. __....... 0.17 ~

..... ... . _ 6.82

_ 0.44

. ._..._._ 2.32

. ...__ . ... _1.38

_ .... _ ..____ __.___.. ........... _._......_... . -,..___. EUGS-tVS2

.... ._. 2.08 - - _... 2A7 ._... .. __....__ 6.84

....__ 4.50

. .. --_-- 1.34

__._.. . . _ ..._.... 1.71

, . _ ..._._. 2.4t ._._._._ _.._...._ _._......... . ..__.___. . ..___.___. EUG 5- Trim 1.38 1.77 3.93 1 2.76 0.76 1.07 1 ~-~ 0.82 ~ ~ ALLO\VED EMISSIONS: Attach supporting data SOURCE GRP 1{F HCL SO i CO VOC NOx PM EUG 1 ..__....... . _ . .. ...........__ . ....__._. _....... . _......___.____._._ EUG 2 _.._.. _ . .._......_... __._._._ ....__.._.__ ._._.__._... ...___...._.._...____ .,.__._._...._.___. El'G3SD1 ..._. _.. 0.59

__......._.. . ._ ..... 0.10

... ....._......__ . ..__._._._ . __.._...._._... t3.77

_ .... 9.67

_....._-...._..._..... 3.88

._ _ 7.98

... ....._.___..___..._. F.CG3SD2 0.95

. _....... 0.90

...._ .. _ _......._._. 0.45

_ ..__ _._ ..... . .. 13.77

..... .......... .__. 9.67

_....._. . .....___._ 3.88

.. .. .. .._ ... 7.98

.._......_._._. _....... EU(:a\'DSl _..__ . 0.72

_.... ......_ 0.08

_ . ....__ . 0.18

................. t1A3

._.._...._.._ 38.33

..._...... ......_.._.._ 3.51

..._....__ .. 5.85

......_......._... F,t!( :4 \•nx2

_ 0.52

......... ..__ 0.06

. _.. . ..._.._.___. 0.08

. ..._.___.. 5,09

......__... . ._. 17.04

......._ __...._ 1.56

. _... __ . . 2.60

.._ .............._ .. EUG5-\\:SI

__ _ _ t.43

. ...._.. t.60

......._...._ 8.96 __ _ .....___ . t9.60

...._._... ._ 4.78

.._._._. .._....._._._ 7.73

._..._._...... 6.71

..__..._....... .._._.. EItG 5-\5S2 _._ ...___.. .. lA3

.__... ............ 1.60

.._._.._-_.. 8.96 ..__._ _........ 19.60

.........._ ............_ 4.78

_.._ _.._...... 7.73

. ........__ 6.71

....__....__......, EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS ED1ISSIONS: based on 1 hour Omits) 6XCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF t)CI SO i CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG I __.....__.. _ ._._.. ...__.__... . .___._._. .._....... ... ........_ _._..__. . __.._._ None .__..... ....____ ... ...__... ..._.... _ _...... _ ._...._.._ _...__.. None ,.. ........._.. EUG 2

. . _._.._. . ._....._. ........._ . __...___... . ....._.._ .._...._. ..._._. ....._.___. . ......._. None ..__. . _...__. .__..._ .___.. ._......____ ......._.. None ..__..__.... F.UG3SD1

. -_.__.._.. _. None

_._._....._ ._....._. None

__. _ None

. _.__...._._. None

_._.._.. ._. None

..._... ._ ...._..._._ None

_ . ...__...._. None

.._.._...._. . None

.........._._ None None

.. ...__._. None

_ . None __.._...... None

._......_ None ...___..._.._. t:UG 3 SD2

. . _ .. None

....___.. ._.... None

._. _..._.._.. None

.. __.,....__._. None

......_._. .. ._.....___ None

....._...__ None

.. ..._._._..__.. None

..___.__ ... ...... . Nonr

........._ None

..__... _. None

. .. ..._. None None

_._..._..._ None

_.. _...._ None

... ...._.._.. EU(:4 VDs(

. .. . None

......._... ......... None

..........___ None

...__.._._._. None None

. __...__............_.. None

.. .._...___.._.. None

_..._._....._ ..._ None

~ ....__._. None ._.__._.. None

._..._._..._. None None ....._._. None None

......._.._._...____..... EUG 4 VDs2 __........ None

.. . ..__._...... IVOne _...__..._ None ......_..__.._... None

.__ _...._._ _.._..__. None

.._ ._...___... None

_.._-_..._.. None

.___._._._.. None

.....__.__ None

..._. None

. __...._._.....

None None .__........ None

. _..__..___.._ None

_..__..._ FUG 5- R:SI

.. None ._.. None .__. . _...__._.__ None _._. Nnne

.. __. None

.__..._ .._. ...... None

. .. ....._...._.... None

. _.._...._.._.._..._ Nnne '.Vnnr None ...__._....._. None

... None ...__._.._ None

.__._.__..__ Nono

...._._._. BUG5-\\ti2 _.___... 0.65

_._....... 0.87

__. ._._..._._.._ None

.._.._.._.__. . ~ one None ._...._....__.._. ..._......_._._..__

None None __...._.._.__. \onc

......._._..__ \one

..._.__.___ None

._....._..__. None None .._ ............. None

.....__..._._._.._..

None ..._.. EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EbtISSION: (2) The scrubber was shut down due to a ntaifunction caused by the nordes being clogged. PROCESSES AND EQUtPMENT tNVOLVED: (2) \Vet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The nozrJes were cleaned and the scrubber was restarted. ADDITIONAL INFORMATION * : The \Vet Scrubber was maintamed and operated according to the ntanufacture`s instructions. The repairs and mafntenance were done as quicklg as possible, utilbing overtime if needed. I certify, based on mformation and be0ef furmed after reasonable inquiry, the statements and •mformation m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Danonstration of Cause Submilfed:

= No A("iENC.'Y USE ONLY DateSubmitted: TrackingNumba: Team tDe
' If you x+•ish to notify the DEQ about a technological limitation, do so here and attach supporting infonnation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF 

# ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 

# 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for Malfunctions OAC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Itaiia 1/8/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 1/7/09 13:10 SUBMITTED: SUBMIT°I'ED: 30 Minutes EE ID #, if 

## a licable: 1/8/09 1/8/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess einission to be considered exempt from compliance with air einission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conternporaneous 1ogs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due a malfunction caused by the nozzles being clogges.

This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was — maintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Form # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.


# - - - - - - - - - - - - - - - - - - - --- 7 -- - - - - - - - - - - - - - - - - - - - - - = - - (5) The amount and duration of the excess emissions (including any bypass) were ininimized to the maxiinum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minimize einissions.

--------------------------------- --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of produciiig valid data were kept in operation if at all possible. NA

----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recuning pattern indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recuning pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Form # 100-921 Page 2 of 2 Revised November 5, 2007

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The inforination requested below should be submitted to the address above within 10 working days after the imtnediate notice is given, tf you are using this form to cmrect a previous rep ort, provide only the corrected information below, sign the cenification, and attach a copy of tlie preldous report.
REPORT DATE: COMPANY NAMB:

1/912009 DaI-ttalia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick!l711ianrs Plant Manager (918) 6834043 FACILITY: COUNTY: PERMITNUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 1P72009 0:00 0:00 0:00 Hours:Min Phase 1

14:30 15:20 0:50 Hours:Min Phase2 DURATtON OF EXCESS EMISSION (HOURS:MINUTES): 0:50 Hours:MinutesofWetSctvbberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specifir Condition 1, EUG 5 ESTIMATED EMISStONS: BASIS OF ESTIMATE ComplianceTcsting X ..._..__ _._._. . _......... ..._...._.__. .......... SOURCE GRP tIF HCL SO s CO VOC NOx Pn1 EUG I

......... ......_. .. .__.__. _.._.__... . _...._....... ..._. _._ ._.__...... .___.._ ._..__.... EUG 2 _...._ ..___. _....... . . __.. _.._. . _.._.._.._... . ._..._.. ..._.._.. ..... Cont Emissions Monitoring _...__ . .._...__.. _.... ..____._.... _.___.._ _._._ EUC 3 SD(

. .... OAO

. ...._ _ 0.00 0.17 _._ _ 6.41

. . -._.. 2.21

_ . . 2.01

....__ 4.OD

. .. Fnginecring Calculation X

.......... .__....... ....._... _.._..___. .__..... EUG3SD2 ._.___ . 0.20

._._... .._.._. 0.00

. ..__..... 0.00

. ..___.. . 

# -.-- 4.38

_ . ._ 0.67_ .._.._..

..__....._._. 1.43 -

.._..._ ~~~~ 1.87

._...__._. _ eratin C.o ~ X Op g Fs ......_.... ...__... _._.. _ ...____.. _...__. EUG4 VDst

_ . ... 0.03

_ . . 0.00

._ D.DO _6.15 .__ _ 0.7? 1.21 2.67

..... .. ..... Other(explain) .....___...... .__....._. . . .... .._ .. .. ... ..._..___. EUG4 VDs2 ~ . __.. ~ 0.01

_..._ . . ...

0.00

_ _. ...... 0.00

. ... . . . 2.68 ~

.. . ......... 0.31

_ _ . _.._... 0.52 ~

._. 1.16

. .._...._.._._ . .___..._ ._..

.. _.__.._ __..... EUGS-WSl

. _ . D.OI ~

._.......... 0.15

_ ._ __.. 0.17

_. .... __ .-- 6.82

. . .__ O.a

~ t

..._.. ._ ___._... 2.32

....... ~~~ . 1.38

.. ....... ......._-'-_ ..______ . ....._._

.. .. ____ ....__... EUGS-WS? __.. ~ 2.22 .....__... 2.64 _. _.__.. 7.31

_.. 4.81

. ..._ IA3

... .......... t.89

_. .__.. 2.58

..__....._. ...._.____ ...._.....

. .._......_... ......_.. .._......_. EUG5-Trim1.38 1.77 3.93 2.76
. ~ . O.i6 1.07 0.82 _......... . .. ___ ._..._.. ..._._._. .___... Attach supportmg data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO. CO VOC NOx PM EUG I

.. _...__.. ...._ ...__.... .._........ -.__.__.._. . _ ._._....___ ..__._....__. __ ........ .... ..._.._.._..._......_... EUG 2 ._... .. _ ............._ _ _ _.._....--

_ . .._._.._.._ ... _..___..._ .,....._..__.. ._....._.--
.._..__._.._... .__.._....... ..__..__....._.__...._. _ EGC? SU1

........ .... 0.59

... .._ ...._..._ 0.10

. _ ._..___ 0.45

._....__..._.._ ....__.._..__.

13.77

. .._.....__.. 9.67

..__.._.__... 3.88

. ._ __.._.. 7.98

__.____.._......__._. EUG3SD2 099

. 0.90

. . _._.. 0.45

..._ .. . 13.77

.... 9.67___.._._. _.._ 3.88

. Z98

_ . . .._.._. Pa'

~ C a\

~ Dsl 0.72

___.. _..__.._....

0.08 .._._ .... 0.18

.... ......... 11.43

........._. .... 38.33

__. ..__.......... 3.S1

_._._._..._ - ~~~~ 5.85

_.__.......___._._.. Ll1G 4\'u

~ ' 0.52

. . ._..._ 0.06 _. , ._.._..._ 0.08

_....... 9.09

..._..._. _.. 17.04

_.._. ...._...__ 1.56

.__._...... 2.60

.___._. .....__ El ~~ G i-

~ A S 1 ._ _. _..___._ 1.43

. .........._ 1.60 8.96 ._ . 19.60

__._._ _... 4.78

_._.. ._._._..... 7.73

......._. 6.71

_.__.__. _........ EUGS-lVS2 _.. ._ _. tA3

...... _._...... 1.60 ......_.. 8.96

__.._.._... 19.60

_.____.. .__.__ 4.78

___.......... 7.73

.......... . 6.71

............... ..._..__. EUG5-Trim 3.57 3.88 9.68 6.75 3.67 t.80 EXCESS EMISStONS: (based on 1 hour Omits) EXCESS EMtSS10NS: 24-Hr Totals SOURCE GRP tiF HCI SO i CO VOC NOx PM t{F HCI SO z CO VOC NOx PM EUG I

. _...... ._..._. .._.._ _ None _...._._.._ . ._. .__... . . ...._. .... ......... . __...__ None ...__.._._. EUG 2

. ....__._ ..__.. _....._ __. ,._......___.. ._...._.__,. ......_.. Nonc __.__.. ....____. __._._.. ..._._-_. ........_ .___._._.. None ....._..._._.. EUG 3 SD1 .._... .__ None None - ..._.._.. None

.__.__ .. . None

_.... ....._. None

__._ _.....__._.... None

. ._ None

_.._._._. . None

._.._..._ None

._._._._. None ....._......_. None None

.......... None

.___.___... None

.__.___... EUG 3 SD2 ._....._ . .._...... e - None _._.._ _._...._.. None

. None

. ..__....._ . None

_...___. .. _...___. None

__._._._. None

.. None None ....__.. None

......._. None ._......__ None

..... ............

None None

__...... None

.__._..... EUG4 VDsI

.. - None

._ _.._. None

.... _ .._. None

._.. _. . None

_ . _ . _ - None

. .. _ __.... None

.._._ None ._...._ _.... Nune

.... ... None ..., ...._.._. Nonc

. _ .... None _. .......

None ...._ None _ _. __... None

_....... Ft~~ G 4!'Ds2

~ 

### None

..__ ... None

... . . . _ None

_ _ .. . None

........ . .._.. None

__.._ .. _.__.._._.. Nono

___...._ None

.. __._....._. _ None

... _. None

.___.... None

_ . None

. ...._ None _.. . None ....___.._., None

._.._....

~ EUG

~ -!1"til

. None

_..._.._. ._.._. None

. ..__..._ None

...__ None .._....__._. ...__ None

__.. ___.__.._. None

_.._._. None

.__.__ . .. None

......... None

. ........_ None ~

...__ ~ None __.. ..... None

. ..... . _... None

_... None

......... EliGS-!\"ti? .._. .....___. 0.79 ._....._ 1.04 _._..._.... None None

. _...___.. _..._._.... None

._..___.__. None

._.__.. None _.......__.. ....___._.

None

. None ...____ Nono

. .__.._....

None None ......_.. None

__._..._ .... None

......... EUG 5- Trim None None None None None None None None None None None I None I None I None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down due to a malfunction caused by the nonks being clogged and the quench Oow befng low. PROCESSES AND EQUIPMENT tNVOLVED: (2) Wet Scrubber #2 CORRBCTIVE MEASURES TAKEN: (2) The nornles were cleaned and the scrubber was restarted. ADDITIONAL INFORMATION*: T6e Wet Scrubber was maintained and uperated according to the manufaeture's mstructions. The repairs and mafntenance were done as qukkly as possibM, util?dng overtune if needed. 1 certify, based on information and belief fornred aner reasonable inqurcy, the statements and inforntation in this document are true, accurate and eomptete

SIGNATURE OF REPORTING PERSON

D.I. Reccived: Rcceived By: Demonstration of Causc Submitted:

~ No AGENCY USE ONLY Tracking Numba: Team ID: Date Submitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supponing information. DEQ-Form #100-920 Re

~ ised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for Malfunctions OAC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days affter the occuiTence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 1/8/09 NAME OF INDIVIDUAL REPORTINC: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 1/7/09 14:30 SUBMITTED: SUBMITTED: 50 Minutes EE ID #, if a Iicable: 1/8/09 1/8/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due a malfunction caused by the nozzles being cloggeg and the quench flow being low. This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minunizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions. DEQ Fonn # 100-921 Page 1 of 3 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.
(5) The amount and duration of the excess emissions (including any bypass) were minimized to the maxiinum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to rriinimize einissions.

-------------------------------- % --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of producing valid data were kept in operation if at all possible. 

# lm"

----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recurring pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recuning pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Fonn # 100-921 Page 2 of 3 Revised Novel

- nber 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALriY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above wdthin 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the corrected infonnation below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

1/9/2009 Dal•italia NAME OF INDR'IDUAL REPORTING: TITLE: PHONE: Rick W70iams Piant 6ianager (918) 6834043 FACILITY: COUNTY: PERMIT NUM1iBER: Dat-ItaBa Muskogee 2004-198-TV (M-i) DATE AND TIM1tE OF EXCESS EM1i1SS10N: Date Start Time: Stop 15me: Dnration: i/712009 0:00 0:00 0:00 Hours:Min Phase 1

0:00 1:05 1:05 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:05 Hours:MinutesofWetScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Perntit No. 2004-198-TV (M-t): SpeciOc Cond'dion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF EST[MATE CotnplianeeTesting X .._._... .__.._.. . . ...____ . ............._ ... _._-_.._. SOURCE GRP IIF HCL SO, CO VOC NOx PM EUG I ...__ _... __._.. . .._...___.. _ ._ ........._._. .. __.._... . .__._...... ...._........... ....__.___ ___.___ _. ECC 2

.. .._ _ . ...___.. _ _.___._.... . ....__...__ _.__.... ._. ..__. ..._ ... ...... . ......... _. ....__.. Cont Emissions htonitoring ...__.... ._... . . . ___.__ .._............ ......_._..._ _ Iil:G35U1

. 0.40 0.00

.. _....__..._. 0.17

. ._...._._....___._. 6.J1 2.21 .__.......... 2.01 4.00 ..._..... ........._.. FngineeringCalculation X

_.___... __.____. ._.__._... __._._.._ F:CC 7 SD2 0.20

_ ._.._.___. ... ......._. 0.00

.. .___..__.. 0.00

.. .__...._.... . 3.38

..__.._... ............. 0.67 La3 ..__..__..........__... .. 1.87

._...__...._ _......._ Operating Logs X _._......_.. . _................ ....._...__.-. t:CC4VDs1

_ ... 0.03 _._.._. . ..___.. 0.00

.. . _._.... 0.00

. . 6.15

.. __.... . .._. OJ7

_.. _.._ 1.21

_....__ . 2.67

...__.__.__ .. Other(explain)

........ ....._ _.. . ....._.._...._. .. _._...._... ... _..._. EI

~ G 4\ Ds2 0.01 0.00 ._ . . 0.00 2.68 ---_. 0.34

. .- _ 0 . 5 2 1.16 ___..._ ...._..___ .__......_.. _._..._ - -- EUG 5-R

~ SI ._ ....._..._. 0.01 --,... 0.t5 ......_ _._ ._. ... _ .- ~

_ 0.17

_ .... . __

_ ..... 6.R2

. OA4 - .._. . ...._- 2.72. _ ...._. _ __ 1 3 8
_

. . . _ ._..___.. _. . . ..._..___._ ._...__.._ ._....._.___ ....____..._. EUGS-R'S2

_ 4.50_

. _ 5.36 .__.... ~ _14.83

. . _ ._.. 2.89 __. . ..__ ....... 3.84

. ......_. 5.22

.___...__-_ ....._............ . ..____.._ . . . _..._.__... ..._...._. .___._....._ EUGS - Trim 1.38 ~~~~~~~ 1.77 3.93 2.76 0.76 L07 ~~~ 0.82 __.. ..._.___ .. _._._._._ __........._ .._.----- Attach supporting data ALLOWED EM1TISSIONS: SOURCE GRP HF HCL SO r CO VOC NOx Ph7 EUG t

_ -... _ ... _. . _.. _ ~ _. ._ --_.._...... ._.._...._ ._ ...... __ ... .........._.. ........._.._.. ._.._..__.._.._... . EUG2

.... .. .. ..._...._. _. ...__.._ ..______. ..__._... .__........._. ..._ ...... ........_ . ._...._. _. EUG3SDl

.... _._. 0.59

._...__. . . ._.__. 0.I0

... . _.___.._. . 0.45

.. ......._..._. . . 13.77

........_.._. ........_ 9.67

._ ... . ................ 3.88

........_. 7.98

......._.__ __........ EU(: 3 SD2 ._._ . ._.. 0.95

..___. . __........ 0.90

_. 0.45

__..... 13.77

.......___. _..._ .._ 9.67

..__ __.........._. 3.88

..... __.. 7.98

...__._.. .._.___. F.UG d VDsI . _ . __ 0.72

....... .. 0.08 ._._._._ _0.18

_ . . . _II.43

.... . _._._ 3833

_.. _ 3.51
_

. ... _ .. 5.85

..... _. ..__..__.. EUG4 VDs2 _..... . _ O.S2

__._. _ . . 006

.__.......... .__._._ 0.08

. . .. ._ 5.09

.__._. .. 1704

_._.. 1. 56

.. 2.60

...........__.... ECCS_N

~ SI ._ _. ._._ 1.43

_ ._. . ._........... 160

.. _.__..__._. 8.96

. ..__....._... 19.60 -._

...._..__ .. ...____ .._._ 4.78 .' -_.

....... _ _.._.......__ 7.73

. _ 6.71

_.._._.._. EUG5-\

~ "S2

. .. _ ?.85 3.20
_ . .. __.._ 17.92

.... .... . 39.20

. _.. 9.56

. . _ ,..__... 15.45

..__. 13.a2

.._. _. ...__.._.. EUG 5- Trim 1 3.57 1 1.88 1
. ~~ 9.68 1 6.75 1 1.67 1 2.00 1.80 EXCESS EMISSIONS: based on t hour 8mits 6XCESS EMISSIONS: 24-Hr Totals SOURCE GRP liF HCI SO r CO VOC NOx PM HF HCI SO s CO VOC I NOx PM EUGi ._......._ ... ___..___. ...._....__ , ....._..... ... ..__ . _._..._.._... _...___.._ None
_ ... .__.._. _..__...... ..._......_ ......_._. . .. __..__. None _... _._..... .__._. _ G .._ _...._._._ EU 2 _....._._. _.__.._.._ ..._._.... __..._.__._... ._..._. .____ _._...._. .....___....... __.._.__. None .__...... ......_.__ _._._._. ._._.___... None _...__.___.._...__._.._. EUG3SDI _._.._._ ... None

_..._... ._.__. None

_ ..._.. _._._.. None

....___._ None

..__.._.. ._. None

___. ..._........._ None

.__._..... None

...._.__... ._ None

._.__. None

.._.._.._ None

.._._...._ None ..__ None __...._.. None ..._ __._... None ._ .._...___. 

### EUG 3 SD2

. ._.... _. _ 

### None _._._... 

### None _. _ _...._.. 

### None

. ..... ._.__. 

### None

. ....... . 

### Nonc

_.._. ... _ ......._.. 

### None

._. . 

### N_one

.... .. _.. 

### None

.__ .._ 

### None

_.__... 

### None

..._. 

### None

..... .. 

### None .._._...... . 

### None

... 

### None

.. _.___... EUG 4 VDsI Nonc

. 

### None

...... _.._..._ 

### None

. ._ ....._. 

### None

....__. _ .__.. 

### None

_.._ .. _._ .......... 

### None

. - 

### None None None _.....__.__ 

### None

_.......... 

### None None ._......_.__._ . 

### None None

_....__.__._. EUG4 VDs2 _.... _ _ . . ...._....... tione ......_.._ None . ______. None

. ........ None

_ .

._._. . ........... None

....._.._.... None None None None ...____. None

..._._. None

.. .. None __..__. . None

. ... ._ _. None

_ _..__.. 

### EUG 5-tiVSI

.. .......... . . _ 

### None

.......... . __.......... 

### None

_ . ....__._. 

### None

.._ ....._.. 

### None

....._.__. ..__. 

### None

_ ___......... 

### None

. 

### None None_ None

. __..__.. 

### None

........ 

### None ._ . 

### None _....__ . 

### None

. .___.._. 

### None _.. .._._._.. EUG5-WS2

............... 1.65

......... ______...._.. 2.16

. ....__.__._. None

....._._. None

.____.. ..___...._._.____.. ~ None None

_._.. None

. None

..__. None

_.____. None

__.._._._.. None None

__.._..... None None

.....__.._.._....._....--.. 

### EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenance to ciean the no

~~ les and Rush the lines. PROCESSES AND EQUIPMENT INVOLVED: (2) 1Vet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The noales were cleaned, th Imes were Oushed, and the scrubber was restarted. 

### ADDITIONALINFORMATION*: The Wet Scrubber was mafntauted and operated according to the manufacture's mstructions. The repairs and ma6ttenance were done as quickly as poss0ile, utiibing overtune if needed. 1 certify, baaed on htformation and be8ef formed after reasonable inquiry, the statements and'mformation m thls document are true, accurate and complete

StGNATURE OF REPORTING PERSON

Date Rcceivat: Reccived Bv: Danonrnation of Cause Submittcd:

~ No AGENCY USE ONLY Traeking Number: Team ID: Date Submitted: * If you wish to notify the DEQ about a technologica) limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: _ 

## COMPANY NAME: Dal-Italia 1/8/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 1/7/09 12:OOAM SUBMITTED: SUBMITTED: 65 Minutes EE ID #, if a licable: 1/8/09 1/8/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean the nozzles and flush the lines. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recornmended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- - - 7 

# -- - - - - - -

(4) The facility was operated in a manner consistent with good practice for mmlmlzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be constiued to automatically require the shutdown of process equipment to miniinize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

--------------------------------- 

# % --------------- (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the sclubber downtime.

----------------------------------------------- 

# (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA

------------------------------- 1 ~ - 

# = ---------------- (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

— 

# m — eT — — — 

# J

- - - - - - - - - - - - - - - - - - - - - — 

# C ments and information in this document are true, t7 io d Teli;f To, af 7

tr reasona e inqu ry, Teirtify, 

# ~ a;ed on miorma n a h 

# ~ state accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised November 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALrfY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM ,'OTE: The informmion requested below should be submitted to the address above within 10 working days aftef the immediate notice is given. If you are using this fonn to correct a previous eport, provide only the corrected infonnation below, sign the cenifieation, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

8/10l2007 DaFlta6a NAME OF INDtVIDUAL REPORTING: TITLE: . PHONE: Rick \V'dlfams Plant Manager (918) 683-4043 FACtLITY: COUNTY: PERMIT NUMBER: DaI-lta6a Muskogee 2004-198-T1' (M-1) DATE AND TIME OF EXCESS BMISStON: Date Start Time: Stop Time: Duration: U712009 0:00 0:00 0:00 Hours:Min Phase 1

4:25 6:00 1:35 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1.35 Hours:Minutes of Wet Serubber pownt9me APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specirio Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplfanceTesting

.............. _.___.. ._....._._ __.._...-._.. X SOURCE GRP ftF HCL SO i CO VOC NOx PM EUG1 __......._.. .._....... . ._._._._ .............._.. .._.._._._- .._.._._._ ......._...___ ._.__...... ......._.__.. _..._.....___- EUG 2 

### ._........._. ._ ..__.._ ._.____......._..._._...._ ... ............_.._._......_......_.._..-_.. _......__.._.. ...._.__.._... ._.._..___..-.._...__._.- Cont Emissions Monitoring 

### ........-.._-_. ._.__.._ ..____. _......_........ X EUG3SD1 ._ ........... . O.dO

..._...... ._._._._._ 0.00

_- __.._.__.._.. 0.17

....____..._ . 6.41 2.21 __..... ._....__.__.. 2.0t

.._.__._.. - _ 4.00

. . .. .. FnginecringCalculation

.. .._.._.__ . . _..__._. _............_ _._.._. X EUG 3 SD2 _..._. . 0.20

.__..._._ _..__ 0.00

_.. .._ .._._...... 0.00

. -_-_...._._ ..__._....._

4 38

............... 0.67

.. . .._._._._. 1.43

._.__.. 1.87

...__._._ .. .. Operatin, 1 n_s

._____ ...__..... ... _.___ __.._._ . EUG4 VDsI _0.03 

### _ .-..._._ 0.00 

### _.. . _......_. 0.00



### _.. _ - 6.15 

### ... __ 0.77 

### _._. _ _.._.._ L2t



### ... .._... 2.67



### ._ .... . . _. _ Other(explain) 

### .... _. .._ . ._..__. .___._. ..____. .__._.._._ VDs2 _EUG4

.. . . O.ot

. .. . ............. 0.00

_ .___.. 0.00

..---_.__. ~ 

### 2.68

...._____ _....-.-........ 034 _.._._._- 0.52

. . 1.16 .-__..__.._.

...-.... ._._.... ..___..._.. . ._...._._. ........_...... EUCS-wSl ._. _._ . . ~~~~~~ . ~ . 

### 0.0t ..._.... ~ 

### O.15

__ O.17

.._.__.._.. . 6.82

_....__. . . ~ 

### ...... 0.44

.__.. ._.._...... 2.32

. . _..... L38

__.. ......__.___... _____ .......... . ..___..._ ..._. .... 

### .._ EUG5-wS2 ._...._. . ~ 

### . 4.22

... ............. 5.02 .._..._.

. . ._......... 13.89 9.14

_ -.... ....._-___..........-_._.- 2.71 - ._._..._.. 3.60 4.89 _..._.. ..... .._...._.__... ._...._._... ___.__._ ___._._.. __._.._... EUG5-Trim 1.38 1 1.77 1 3.93 1 2.76 1 0.76 1.07 0.82 ....__._ _...._..._. ._..._.___ _ ALLOIVED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO i CO VOC NOx PM11 EUG I 

### -_....__..__... .__._.__ ..._.....__.... .._........_. .__...__... ._....__.__ .._._._ _._._ ..._____._.. -____._.__ .___..__._.._....__. EUG2 ._._. ___.... ... _...._._.... ._.__.._ .._ .........__.... ._......_ _.__..... .-._....._.... ..._.___._. . . ..___ ........ ... . ..._.-...__........_... EUG 3 SD t__ ....._ _._..... . 0 59

,,.._.._.. .......... 0.10

... - 

### _...._.... OA5_

,. . . - .. ._....13.77 ._

.. __. 9.67 

### _ . ._ _ .... 3.88

. ._____.... . 7.98

-... _.-......_.._..__._.. .._EUG3SD2



### . _ .. _ . _ ... __095



### . . .. 090



### . ....._..__ OAH



### -_. ...._._ . . ..-.___,1377-__...._......967



### ... ... _..._.__. 388 

### _.._..__.... 7. 98



### . .__ ECG4\'Ust

. ... _._. __.. _. .. 0.72

. .. .. ._ _..__... 0.08

._. .... 0.18

..___......._. . ILd3

.__..__ ..... ......... 3833

..._... ._..._..__.......- 3.St

- . 5.85

. EUG4 VDs2

. .... 0.52

. .__._. _._.._._. 0.06

_.. .._... 0.08

. . - ..-..._.-. .-_ 5.09

...___._. - ..._._ 17.05

.__... _.__...._._. 1.56

._._... _ ... 2.60

.... .__.._ [t

~ C 5-\\'St

. t.J3

..... 1.60

.-_._..._.._.. 8.96

. . . - _.__.... .. 19.60

_..___. _.. _._ d.78

_.__. . _ ............... 7.73

.._..... 6.7t

._.___...____._._.. LI

~ G5-1\'S2

.. .. _ 2.1d

_._.__... ... ..__.._. 2A0

_.. . . ____._... 13.dd

._ _._......... 29.d0

_._._..-. ..- ._.._ 7.17

_...... _._.__....... 11.59

. ...._._....._ . t007 ...._.....

...._.___..... EGG 5- Trim 3.57 1 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSiONS: based on I hour Omits EXCESS EMISSIONS: 24-Hr Totak SOURCEGRP HF FiCi SO s CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUGt .....__ ......... ......._._.. .__....._. ..._....__._. . .........._..... _....__...._ ...._.__._.__.....-...____. . .. . ...__.__- ...... None ...._... ........____.. . _..__._._. . __.._.._... . None .._..._.._.... EUG 2 _.._. .._ .. _ _......___ __..__ __ ______.... ............._ ._..._........ ._._. ......_ ...._._._._ . . .. ..__.__.. . None -._ _.. __..._. -..... ....__._ . _ _. _ _ . ......_... __. ._.... ._. ...._. ._.__..__._. None ._..._........ EUG3SD1 .._ ......._.... ....__ None

......_.. ._._._ None

._. .....__...._... None

........... None

................ _........__ None

..... ..__.._.. None

.....- ...- . None

.. ._...... _ Nonc

_.....__.. .. Nonr

_ ~ one
. ....._...__

None ..._ None None None

......_._.._ 

### F.UG 3 SD2 None

._... _.. 

### None ._. .. . _.._..___.... 

### kone

_. .. 

### None

.__.._.__ ................. 

### None

. ._. 

### None -. . _ .__.__.. .... 

### None

_ _ ... -.._. 

### None

_......_.. .... 

### None .._.. - _. 

### None

..-._ _._ 

### None

...... ._..... 

### None ._ .. . 

### None -- -_.._........ 

### None

....._........ 

### EUG d\'Dsl

.__.. 

### None

.. .... 

### None

..._..___.._. ~ 

### one

.. ........ ...... . . 

### None _

...._._.. ... .....

. 

### None ._. .. ...... 

### None

. _.. -........_.... 

### None

...._. .. 

### None

__......... .. 

### None

.... _.. _.. 

### None

-_.._... 

### None __.. _.._...._ ~ 

### one

.. 

### None None EUG 4V'Ds2

.... . .. ... ... 

### None

. . ..__._. 

### None _.. .. - _ ....___- - 

### None

. .... ...-_... . 

### None

._ . ___.. - . __. 

### None

._..... ._.__.___._. 

### None

.....,._._... . .. 

### None

. _ .. . _ .. .-. . _ . 

### None

_ . ..... .- 

### None

. .. . __._.... 

### None None

-' ..._.. 

### None

. ._. . 

### None

. . . ........ 

### None - - 

### EUG 9- WSI

.. . .. 

### \one

. -._.. - 

### None

.... - 

### None Nona

. ._._._ 

### None .._.... . .. __.._._... 

### Nono_

.. 

### None

.. 

### None .......__ 

### None

_._...__ - - 

### None ....._... 

### Nonc ..._ _- 

### Nonc

. .. .~ 

### `one

_.,.......... 

### None ._ _....._.. EUGS-\\"S'_

. .._ .....____...__.. 2.08 _. 2.62 ._.._. _ -- ... _ ._. - OA5

_ ... ...___. . . None

- _.._..-.. . - . __ '~ one

. .___ _ ..... ...__... None

. .. ....._._._ .. None

.... .........._.. - ... _. None

. _._ None

....._._...... None

. __._._. 

### None .__. .. .. 

### None . _.__.._. . 

### 9ono

..... ..____.. 

### None

...._._.._. 

### EUG 5- Trim None None None None None None None None None I None None I None None None NATURE AND CAUSE OF EXCESS Eh11SS10N: (2) KOn 4 was vented to Atmosphere due to a malfunetion causing the w•et scrubber to overheat. PROCESSES AND EQUIPMENT INVOLVED: (2) R'et Scrubber 02 CORRECTIVE h1EASURES TAKEN: (2) The scrubber was shnt down, the nordes were eleaned, and the scrubber was restarted.
ADDITIONAL INFORMATION*: The {Vet Scrubber w•as maintalned and operated accordetg to the manufacture's instructiuns. The repairs and mahrtenance were done as qukkly as possble, utirving overtime if needed. 1 certify, based on information and be8ef formed after reasonable inquiry, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Reeeived By: Demonstration of Cause Submitted: 

# =Nn 0 I I I AGENCY USE ONLY Date Submitted: Tracking Number: Team 1D: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infonnation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for 1Vlalfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 1/8/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 1/7/09 4:25 SUBMITTED: SUBMITTED: 95 Minutes EE ID #, if a licable: 1/8/09 1/9/09 

# ***The owner or operator must dernonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air enlission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous 1ogs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due a malfunction that caused the scrubber to overheat.

This failure was not reasonably preventable. (2) The excess einissions did not stem froln an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maxilnum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for rninimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown ofprocess equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Form # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

— - — - — - — - — - — - — - — - - - - - - 7 -- - - - - - - - - - - - - - - - - - - - - -- 7 -- - 

# (5) The amount and duration of the excess emissions (including any bypass) were miniinized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minirnize emissions.

--------------------------------- % --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of producing valid data were kept in operation if at all possible. 

# lm ,

----------------------------------------------- 

# (8) The owner or operatoes actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recuning pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recurring pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUAI.ITY DNISION PO BOX 1677 OKLAHOMA CtTY, OK 73101-1677 

# EXCESS EMISSION FOItM 'OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this forni to correct a previous eport, provide only the con'ected information below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

1/232009 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rkk wOtiams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMtT NUMSER: Dal-ItaOa Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EAi1SSION: Date Start Time: Stop Time: Duration: It192009 0:00 0:00 0:00 Hours:Min Phase 1

9:45 11:15 1:30 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:30 Hours:hiinutes of Wet Scrubber powntime APPLICABLE LIMITA170N(S) OR REQUIREMENT(S) EXCEEDED: Permh No.2004-198-TV (M-i): Specifrc Condhion 1, EUG 5 ESTIMATED EMISSIONS: D 151S OF ESTIMATE ComplianceTesting X _... ....._... . _.....__ ._.__........ . __ _..... ._.__.._._ SOURCE GRP HF HCL SO s CO VOC NOx PM EUG I ._. ._ .._.__. ._...__. _ _ _..._.. __...._. .__.... .. .............. ._......__..._ .. __....__..__ .... EUG 2 _._..__.. .._..____.. .....__.. .._...._. _.__.. _........ .._......_ ... .........._.._. .....__.___ Cont Emissions Monitoring ._._...... ...._....__.. ..___.._.._". EUG35D1 ____.__. ..._ OJt ._.._. 0.00

. 0.13

._......... ..__._ 5.06

. _."._ 1.75

..._. ........__.._. 1.59

_ ..._-. 3.15

._..._ _ EngineeringCalculation X

..._..._ . _....._.._. ......_.__ . .__..... ..-_..._. EUG 3 SD2 __.__.._ . . .. 0.36

.__...... . . ._._. 0.00

_. . ._....... 0.00

.....__... 8.11

.......... . _. 1.24

..__. ..___._.. 2.64

...._".__..._... 3.46

... ... .. Operating Logs X

. _.__.. . . ._...__... ........ ...__._._ .._._._.._. EUG4 VDst

_ ..._. .._ 0.02 0.00 .._._.. 0.00

.. _ 514

. __....... 0.67 ....._.._ i.05

. .... .... 2.31

......... ......__... Other(ecplain) ._...._._ ...___..._... ...... ......_.__ 4 VDs2

. .. ..._ 0.01 ......._. 0.00 _. 0.00

.. .. . ~ 2.58 0.32

.......... ..._.._.._. 0.51

.. _._ . 1.12 ..._..__._ ...__..__ ........._.. . __......_... ._.__.._.._ EUGS-FVSt

. .. .. ... 0.01 .._._. 0.16

_ _. _.. 0.18

. . .. .. 23t

.-. __.. 0.47

.__.. ... . _. 2.48

...... . 1.48

_ _ ... . .......... _.._..___ ." ....__._. .. _.__ ....___ EUGS-VVS2 ._ ..._. 8.99

..._._. 10.70 .._.._._ 29.59

. ..._ 19.47

. .._ 5.78

.... . ............. 7.66

._. "
. _". 10.42

_ . ...._._.... .......__.. .._._..... . __..._._._. .___...._. EUGS-Trim 1.31 ...__... - 1.67 3.73 2.61 0.72 1.02 - ~ ~ 0.78 Attach supporting data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO, CO vOC NOx PM EUG 1 --......... EUG 2 .___.. ._.__..... .............. ._...___. ...----...._.._.._ _ ._._.._.__ __.._..._.._ ._...___. _..._.__-.__ EUG3 SD1

......... . 0.59

___.._. ._...__ 0.10

_., . ..._-_- 045

--... ,(3.77

_ 9.67

_ _....__...... 3.88

.

....._..._..... 7.98

_.__.__. EUG3SD2_ ._... 095

, _. ...___.__ 090

. . _..._._........ 0.45

_....._..._.. . 13.77

....._._._ ..__. 967

_", .....__._._ 3.88

. _.._...... 7.98 EUG4VDs1 _. .. .. .. 0.72

_..._ ...____..__. 0.08

.._...._._.. 0.t8

.._......_... tL43

._._._ ._..__._... 38.33

__._..___ 3.51

. ...__....__. 5.85

....._.........._._. F:I:G4VDx2

_ . .. .. 0.52

..___... _ .._...____ 0.06

.. ..._. ..__. ." . 0.08

.... .... ... . 5.09

....__.. . . _. 17.04

. . . __ _...._.. 1.56

_ ..._.._._. 2.60

._.__.._ _..__._-. ECG5-\\'SI 1.43

.. 1.60 8.96 t9.60

_ _..... 4.78

_ _. _ ...__._... 7.73

...___..__ 6.71

. ..__.... .____.. EUG 5- N

~ 82 _..... .. 2.85

._. _..... .. 3.20

_ .. ....._... 17.92

_._..._...... _ 39.20

. .._.. ._. 9.56

..__- _ -- - _....._.. t5,45

_. .....__...... 13.42

..._..__....... EUG5-Trim 1 3.57 1 3.88 9.68 1 6.75 3.67 2.00 1.80 BXCESS EDI ISSIONS: based on I hour Omits EXCESS EMISSIONS: 24-Hr Totats S OURCE GRP HF HCI SO i CO yOC NOx PM HF HCI SO z CO VOC NOx PM EUG I ...__.__.. ___ ..__..... .___.._. .. . __._._.._ . _. _.. .___.. .___._._.. ...._......... .._____._. __"__._.._. ...._ None ___.._ . .._ ................ . . __..._. .._.___.. .... ._ ...__.__.. None EUG 2 _ .... ..... ......___. _..__._.._.. _._...____ .-_.--...___ . ___..___. ...._...._.. _....._._ ._.....___. ..___......_. None

. .__..._._. ._._._.__. _.____........ .___.___. ..__._._ None _.__..___. EUG 3 SDI __. .. _ None

._..__ ._ ~ _.. __. None

_ .__...._...._ None None None .._... ......._....-_- None

.___._._... ._ None

_..__...._ _... None

_.._._. None .._._..._..__ None

_._..._._ None

....... .. None _._.__. _ None None

.._.._ _.__. ICUG 3 SD2 Nono

..._.__. .....__.._._. None

. __..._.__._ None

-_...__ ........ None

......... ....._....___ None

_......___..".. None

..__..__....... None

.__..__.._. None None

_..._.........____... None

_..__.__..... None None

...._._____. None

. _..__......_. None

.._.___....... I:UG 4 VDsI None

_...__.. None

. .. _.._.... . None

_ _ _ . None

___... ...... None

_..._ .._.._....__... None

... _. ..._..,...... None

_...._._. None

... None ......_..__._ None None

_. ..... iVone _.. _... None

"... _._._ None

___.... ._.. El'C 4 VDs2 

### None

.._._. 

### None ._.. None __....."..._. None

. _.. ....._ None

.._..__. None

. . .._..._._.........._...

None .."_.... None

... None .._._.._ None

_. None .._ _._.._...__

None None

......__... None .._.____.. El'C s_A

~ 51

.. None

.___._.. . _.....__ None

... .. None None .._..._.... ....__ None

...._ .. ......._._._ None

. .. _.._ .. ._... None

...._.__. .._._ None_

.__._ None

_ _._...__ None

_._..._" None _. __..._.._..

None None

.._._.__. None

....____.. Et'CS_

~~ ti:

. 6.t3

__........ .._.... 7.50

._ ._ _._.._._. 11.67

_. None

.._ _... . ....._. None

. . . _._ . ----- -- _ _ . _.. . None

._. .. _ ... None

.. .... ...... None

....._. Yono

_ .._.___... None

.._- None _. . .. None

..... ._.. None

.._._..__.. 

### None EUG 5-"Crbu None None None None None None ~ None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenanee to do the pm. PROCESSES AND EQUIPMENT INVOLVED: (2) wet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The PM was completed and the scrubber w•as restarted.
ADDITIONAL INFORMATION*: The Wet Scrubber was maintained and operated accord'mg to the manufacture's instructions. Tbe repairs and mamtenance were done as quickly as posstlrle, utifamg overtime if needed. t certify, based on htformation and betief fornted after reasonable mquiry, the statements and infurmation in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submined: O N

' o AGENCY USE ONLY DateSttbmitted: TrackingNumber: Team ID: *)f you vvish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form fo r Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia i/22/09 NAME OF INDIVIDUAL REPORTING: TITLE: PRONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 1/19/09 9:45AM SUBMITTED: SUBMITTED: 90 Minutes EE ID #, if a licable: 1/20/09 1/22/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down to for maintenance to do the PM. The scrubber downtilne was as short as possible to colnplete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recominended preventative maintenance procedures. (3) Ifthe excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- - - 7 

# -- - - - - - -

(4) The facility was operated in a manner consistent with good practice for mn

- limizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipinent to niinimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

------------------------------- 

# -% --------------- (5) Reasonable steps were taken to niinimize the impact of the excess emissions on ambient air quality. The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA

-------------------------------
~ 

# -= ---------------- (7) The owner or operatoes actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised Novel

- nber 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALrrY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fonn to correct a previous rt, provide only the corrected infortnation below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAM E:



### 1/23/2009 Dai-ita6a NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: 

### Rick 4V'd8ams Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: 

### DaFltatia Muskogee 2004-198-TV (M-1) DATE AND T1M E OF EXCESS EMISSION: 

### Date StartTime: StopTime: Duration. 1/22/2009 0:00 0:00 0:00 Hours:Min Phase 1



### 4:12 4:30 0:18 Hours:Min Phase 2 DURATION OF EXCESS EMISSION (IiOURS:MINUTES): 0:18 Hours:Minutes of Wet Scrabber powntitne APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: RASIS OF ESTIMATE 

### CompiianceTesting X .._...__...__..._..............._. . ..._.__. .-_..._........ .._..._._...- SOURCE GRP HF HCL SO r CO VOC NOx P; 7 

### F,t!C I _.... .. . ..._.__..._... ....___._... .._...__.._._. .__._-_._... _-......_ ...... ............. ........................ EUG 2 __. .. _.. ... . _. .. _. ._._ - .....__.... ...... _ . . . ... ... .___... . . . Cont Finissions Monitoring _-____ ......._. ....... . . .. . ._.__.. _ . ..._.... _.. ..._....... EUG3bD1 ._..__...--O.d2

_._. .. ... ._.._._._. . 0.00 0.18

. . . __ . _. ~~ - ~~~~~~~~~ 

### 6.74

_- .. .. ...._ 233 - ~~~~~~~ . ~



### _.._. ._.._..._... 2.12

~~~ .....



### . .._._ ~"
. ~ 

### 4.20 ..__..... _ .. . EngineeringCalcuiation X ...._........ ............ ..........._._.. . _.._._.___. ._._____ EL'G3SD2 ____._ 0.31 - ~~~~~~~~~~ - ~



### ..._._.____ _._ ....... 0.00 ~~~~~~~~~~



### ...... ..._..__ 0.00

... _.__...._.. ~ --- ~~ 

### 6.94

...._...__......-__.....__.....

1.07 ..__... 2.26

. ._.._...__......._ 2.96

_....._._... .__.....__... OperatingLogs X ..._......... ........._._.... ....-...._._.._ ..._.__...__. F.C(:4 \T)st 0.02
_ . 0.00
_ .. -_.._ 0.00

_ _ . _ -_...._. . . 5.71

-.... __ 0.72

. .._.__... 1.12

. . ...._._._ . 2.48

.. .. _. .. _..... Other(txplain)

.__...._........ .._._..... ..._...____ ..... ._...._ .. ............._. I{CG4

~ 

### 'Ds?

.. 0.01

._._.._ _ -__... 0.00

_... -. - . ..._... 0.00

-- ._.... .... . - 2.57



### ... 0.32 __...._.. _......_.. .. 0.50

. . ...._.- . _ l.11

.. . __ . ....._._._ . . -........_._ . .... . ......_.... __._. EUGS-

~~ 

### .tit

.. ... 0.01

. . . ._ 0.t6

..... _ . ...._._ 0.19

. . .- ... _.. . .. . 7.47

.._ __.._ _ . 0.48

. .___...... 2.54

. _..._...-.... ~ 

### L51

_.__ ...

--. __...._... . . . _...__... ..___..__. ...._...__.._ ___.__... EUGS-

~~ 

### 52_ .. _- .. t.71

__ . ..___ . .._. 2.03

_ .. . . ...........- 5.61_

- - .. _.. _ 3.69

. .__..__... -..._ . 1.10

_...__ . . .... _ L45_
_ 1.98 ...._.. . .__ ._........_ ...__..__.._. ___.....__.

_..___. .....__._.._. EUGS-'frim t.45 L85 4.13 2.90 0.80

~ 

### 1.13 ~ 

### 0.86

. _...._ ..... ........__._. ....._._.. .___.___ .. .. _..._..._.. ALLOWBD EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO i CO VOC NOz PM EUG 1 

### ... _. ~ 

### . _.... ... __._.._... .______ __. . .............__ _..._....... ... . ___._......_ _...... ..____. ... __ ..... _.. - _ . . .__.... .. _...._____.__......_.. EUG 2 

### _.. -. .. ___..._ .... ._..._.. ._. ... ._._._...._ _.__ ...,.__ . _.__....__ ._ .-_ ._.._.. - _ ..__._.. ..__......_. ... .__.._.__..._.._..__.. EUG3SD1

. . _._ . _..._ . 059

- . . .__. .._- D10

-. .. .. . _._._.. _ 0.45

- .. . ... 1377 _.... . _.._... ... .. 967

. . _.. .._... 388

.. . _._____._ . 7.98

.. ... ....__......_..._... EUG 3 SD2,

_ . .. . ....._... 0 95

__ . _.. .....__. 0 90

..... . _._.__...._. 0.45

_.._.__.__... 13 77

._........., 9 67

. ._ ._ _.... 3.88

....__........ 7.98

__._._._..........__...... EUG 4 VDs1 

### _......_.._. _ . ,_,_.., 0 72

_ 

### ._ ... . __ .... 0 08



### ....... ... . ........._.. 0.18



### ..... ....__._. . .__.._.,_, l l_ 43



### . -. . ..._ -,.__.__ 38J3 

### ._ - ......_ . __ 3 51



### . . . .. ._.__.._ _ 5.85



### ....._._..........._....._.. EUG4y'Ds2 - ......._..._ , .. .. 052

.. .____ . 006

. . _. ....._.__ 008

.. . .. ..._..._......... 5.09

. .__.. . ~ 

### ... _. 17.04

.._.... - ....._ _ . _ 156

. . . - _.__..._.. -

_2_60

.. .. _..__._. EUGS-1VSl

. - ... __.......__ . _ . 1.43

_ . _ .... ... . ....... 1.60

._... . . . ._._.._.._... 8.96

. . .__._...._... . 19.60

... .._...__ .. . .. ... 4.78

_._.._.. -.. _ . ... _ 7.73

. ................_ 6.7t

.. ..._...__..._. _._..._. EUG5-

~ 

### VS2 ...._..... . 1.43

........._ .. ........- 1.60



### - , 8.96 

### _I9.60

. _.. . 4.78 .__..... 7.73 ._. .- . . _.. .. 6.71

. . _... EUG 5- Trim 3.57 3.88 9.68 6.75 ~~~~ ~~ ~~~~~~~~~~ ~ 

### 3.67 2.00 1.80 EXCESS EMISSIONS: based on t hour rnnhs EXCESS EMISSIONS: 24-tlr Total.s SOURCEGRP HF HCI SO r CO VOC NOs PM HF HCI SO r CO VOC NOz PM EUG 1



### . . ..._..__...._ . ..._.__.__.._....... . . ..._.._._._._ _..... ..__. ... . ....._..._. . ..._._. _....._ . _ _ ........ _......_..._ ... .. None



### .... ........_._... .. . .._....... . ._ ..._.._._.. ... .._.._ .__. . ....._._...... .__...__. ... None



### _................ EUG 2 

### .-..._..._.._ ,..._......___.._........__ ._._..._.._._....__..._.__ ..._..___._..........__..._.. ..__ ....................... None 

### .....__........ _...._..___.. _._.___.._ _.........._._. .. .....__......._.__..__ None 

### ...._.__.... EUG3SD1



### . _..._._. ._. None



### ______ ... .....__...... None



### .. ...._.._...._ None



### .. ._.._..._.... None



### ....__......__ ._.._.._....- None



### ._-._._ __ None 

### ._. _.__.__. None



### _._.._._.. _. . None



### _.....__._ None 

### _ .......... None



### ............. None None 

### ............._. None



### ._.._.....___ None 

### _.......__.... EUG3SD2 

### ............._ . None



### .....__.... ......__.. None



### ...._ .. - - --___. None



### -.. ..._..._._.. . .. None



### ... .. ___.... ._ None



### .....__ ... . . .._...._ None



### ._ .. _- .. -.- __ None



### _.. .......__... _.... None



### ._........ . None



### .. . _._._.... None



### . . _ . _.... None 

### _.._. ... None 

### _....._._._ .. None



### . .... _._._.. None



### . .. ......_.._. EUC4 VDsI 

### ......._. . None



### .._......_.. .... __._..._. None



### -._ . .._._._.._. None



### .... _._......... _. None



### ._.__....... ._..._.........

None



### . ..._._.._.. None



### ..-..._- __. -. None



### . _..._..__. ... None



### .._.....__. None 

### .-.._......_..- None



### _ ._.._. None 

### _..._ .....__...._..

None None



### ..._.._.. None 

### ...__....__.. EUG 4 l'Ds2 

### ..._ ._. . None



### ...._.._._ ._ ......... None



### ........_._.._. None


### ... None



### .... ..._ None



### ...._... .........___. None



### ..-.._- __..__ None

__ 

### -...._ . _......_.__

None None



### ....__.. None 

### ...--..-...._..

None None



### ... ,.__... None



### ... _._.__..... None



### - ___._._. EUG 5- WSt 

### .__..._...__... . _. None



### ......_.._ .._..____.. Nono



### .._..._.._ None


### . . ..._........_. None



### ._..._._. ......._ None



### _._._.... ... _ ._.__.- None



### - - .._..__...- ... ~ None



### ._._ ......... ._.. None



### __......._ . None


### .. ...____ .. None


### ....... ... None 

### ...._ ... None 

### _._....._._ None



### ..._...__ _... . None



### ._..___.._.. EUG 5- WS2 

### ........_._. ..._ 0.28



### ..._..__._ ........... 0.43



### ..... ._....__..__. None



### -....__._...... None



### .__.___.. _...............

None 

### ....____.. Nonc 

### _... _.... -.._ None



### _..._____.... ... None



### ........._..-.- None 

### _. _..._., None



### ......__..._.... None



### . None



### _ ....._._. None 

### ..__......_... None



### . ........_ EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: 

### (2) The scrubber was shut down due to a malfunetion causecd by the tower Oow dropping. PROCESSES AAiD EQUIPMENT INVOLVED: 

### (2) wet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The pumps w•ere stopped, wahed unt0 the flow w•as rero, and restarted the scrubber. Flow rate good, wiH continue to monhor.
ADDITIONAL INFORMATION*: The LVet Scrubber was maintained and operated according to the manufacture's ktstructions. The reparcs and maintenance were done as quickly as possible, utitbing overtfine if needed. 

### I certify, based on information and be8ef formed after reasonable mquiry, the statements and information in this document are true, accurate and complete

StGNATURE OF REPORTING PERSON



### Date Received: Received By: Demonstration of Cause Submitted:

~ N o ~ ~ ~ ( AGENCY USE ONLY DateSubmittut: TrackingNumber: Tcam ID: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. 

### DEQ-Form #100-920 Rewsed February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION 

# IP. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for Malfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it rnay be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 1/26/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDI.ATE NOTICE DATE WRITTEN REPORT EMISSION: 1/22/09 4:12AM SUBMITTED: SUBMITTED: 18 minutes EE ID #, if a licable: 1/23/09 1/26/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due a sudden malfunction caused by the tower flow dropping. This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was lnaintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown ofprocess equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Form 9 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtiine were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

- - - - - - - - - - - - - - - - - - - -
- 7 -- - - - - - - - - - - - - - - - - - - - - - 7--- 

# (5) The amount and duration of the excess einissions (including any bypass) were mi-nimized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minimize emissions.

-------------------------------- --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ainbient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of producing valid data were kept in operation if at all possible. 

# =I

----------------------------------------------- (8) The owner or operatoes actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recurring pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recurring pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Form # 100-921 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALI7Y DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The information requested below should be submitted to the address above wdthin 10 working days afier the immediate notice is given. If you are using this form to correct a previous eport, provide only the conuted infomtation below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

21672009 Da4ltaGa NANIE OF INDMDUAL REPORTING: TITLE: PHONE: Rick liiilGams Plant Manager (918) 6834043 FACtL1TY: COUNTY: PERMIT NUMBER: Dal-ItaBa M uskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 2/2l2009 7:45 8:30 0:45 HODrs:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCBSS EMISSION (HOURS:MINUTES): 0:45 Hours:A4inutes of Wet Scrubber pow•ntinie APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-t): Speciric Condition 1, EUG 5 ESTIMATED EMISSIONS: BAStS OF ESTIM1iATE ComplianceTesting X ._._._... ._..__..._ .........._. SOURCE GRP IiF HCL SO i CO VOC NOx PM EUG1

. . ._...._ . ._. __._.._ . ....__.._. ._..._._._ ..____...... ..__...__....._ .__ _....... _._........_._ ._..__.....- _ ... ...__._... . ...._.._._... EUC 2 __.___.__ ... .__...._. ........_..... _...._._.._..._ .__._._._. ._..__. ___.._... ._.........._ ......_.. .._..._...._.. Cont EmissionsMonitoring _.._._._.._ _.._.._..._.. ._._.___..... ......___._ . ..._...... . EUG 3 SD 1 _. ._..__._...._. 039

._..._._ __.._ 0.00

.... ._....__. 0.17

._..__.__.. . 6.30

_.__.._... ..___..___ 2.17

_..._....._. 1.98

.......... 3.93

......_...__..... Engincering Calculation X

._.._.._ ...__.... ._..____ ...._..___._.. ._._.._..._ EUG 3 SD2

. ........,.. -_...__.... 0.31 .__..... 0.00 ..._.__..__ 0.00

. .__.._....... 6.94

._......._ _._._.___ 1.07

._._.......... 2.26

........_. 2.96 .__....__.... ..._........._. Operating Logs X ..__...._.... _._._... __...__.... ....__..... EUG 4 VDsI ._ .. ___... 0.03

_ ._.... 0.00

.._ . 0.00

..__ . ._.. _ _6 .05 0.76

...... ........._._ 1.18

....... 2.62

. .... Other (explain) ..__.__. . ____.......... _._._. .__......... ......_..___ EUG4VDs2

.. .. ~ 0.01 .._..... . _.. 0.00 ~ ~

_. . ___.._.. 0.00

_ _ ..._.... ._.._......._

3.55 __._...._.__ 0.45

.._..._...... 0.70

. 1.54

........._......_......__.. ..._...... .___._.___ ...__...._ ...._.__..._. EI C 5-

~~ 'S1 _. . 2.15

. . . . _..... 2.56

. _..__.. 7.08

. . ... 4.66

....____ .. _._.. 1.38

___.... . ...____... 1.83

._....._.... 2.49

.....____._ . ._ .....___...._. ....._.._.__..

..._.__... _ ........... ......._____ EUGS-

~~~ ti2

. _. 0.00

._._.._.._ ....._. 0.00

_.. _ 0.01

. ......._... . 5.44

_.._...__... ...__.. 0.9t

. ..__._...._ I.75

..._..... 1.60

_._...___ ... ........... ._._._......._ .._..__.....

__._._.... .. ____._ EUG 5- Trim 1 2.03 1 2.59 5.76 4.04 1 1.12 1.57 1.21 ...____. __..__. ._._._.._... ................ _ .___._.... Attach supporting data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EUG 1 .._. _..__._.. . ..___.._.. .__.___.... ....._._____ . .._.___ ..... .................. .................. .._._...__._

.. _.._..._. .... ......._._. .__..___ . .._._..__.... ... _._.... .___....._.... ..... _......_ . .. . .._ _._.._ .__.__.... EUG3SD1 ___....._.__ .. 059 0.10
. .._._..._.. . 0.45

.... t3.77

.. _. 967

............._.. 388

...._ 7.98

__..___..._... EUG3SD2,_„__,,,,,,095

. _......_.. .... . ..._..._ _.... 0.90

.. .._._...... __ .. 0.45

......_ . _,,,_,1377

_ .__._... 967 ..__ ... .._.__._ ....... 388

. .......... 7.98

..___..__.....___..._. EUG 4 VDsI

. ... 0.72 .._._.._.__ .. ___ 0.08

.._.. . _.._......_ 0.18

..._........... 11.43

___........ ..... 38.33

._..._ .. .. _._.._--.. 3.51

.. . . _ _..._. _. . 5.85

_ _...... _... ._...._.._.. ._.._... . 0.52

- ... ___...... 0.06

...__........_ EUG 4 VDs2 0.08 ._.._.___ 5.09

__..... _ 

### 17.04

. _.__.........._. 1.56

_. .._ 2.60 .__.___. EUGS-WSI . _._..__. _ ._ IA3

_..._._.. . .... ..._.._ 1.60

.._ ..... ............. 8.96

._._..... 19.60

..._.._._.. ......_. 4.78

......... . .. .__.____. 7.73

_ .. .. 6.71

.._ _. ._............_._. EUG 5- WS2

. __._..._... ....._ IA3

.._.___. ....___...... 1.60

. ..._._._._. 8.96

..__.......... 19.60

._...._.._. ......_.. 4.78

...__....... ... ._.._._. 7.73

_._ . ..... ... . . 6.71

.._.._.._____.._.._.... EUG 5- Trim 1 3.57 1 3.88 9.68 1 6.75 3.67 2.00 1.80 EXCESS EMISStONS: based on 1 hour Ihnits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO z CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG 1 ....._ ... ._......... .._. . ... _ . _ _.__...._.... . .._..._..__ _ ..._._. _.._.... ... .. ....._._.._ _.___...._ ..... . .... None

.. .._._.. ... ._ ___._.... ._..__.._ ...._ ...._ . .....___._. _._.._.._... None _....__._-. . . I:UG 2 ._..... ......__._ ..... ...._..._ . .._... _._._ ... __._......._ .. .. ..... ........ . ....... ...__.._._. None .......__....... ..... ._..._._._. _.... .._. ...._..___ _....._.. None

.. ...._...._._. ECC 3 SUI ..__. .. . .._ None

_._..._...._ _ ... -._.. None

...... ....... None

..... ...._._.... None

.._._._.._ _...._. ._ None

._.._ ... ... _....__. None

.. . _...___._ None

..._.......... ._.. None

._..._.._. None None

. None None

,_.__..... None

.__.__._. None

... ..._.......... EUG3SD2 ._._...._ _ _. None

...._____ _._. _ .._ . _ None

_ ... _ . _.._._ None

... _ ......._..._.. . . None

. _. ......_. _ . _ _. _. None _.._ .._._ None

...... . None

...._.._____ ...... None

__.._.._ ... None None

._..__... None _.... . .._ None

._. _...._ . . None

_._._._..._ None ...._.__.__.. EUG 4 VDst _......._ . . - _ None

- _ _ . _ .... -- None

.__ ...._....__.._ None

...... . ..--.._ None

_ ... ....... --.__ None

_ . ._._.. ._.... . . None

. _ . None

. . __._.. ... _ _- None

._ ... None

. . _..._._._ None

_.._._. None ._.... . . None .._._._... None None EUG 4 VDs2

_ .. .._ . . None

.. .. _. _ None

_ . . ........_.. None

. ...._. .__.._.. . None

.__ _.._ . ___..- None

_....__. _ ... _ . None

_ .... -_.... None

_....._.. ...... None

... None

... ...__.. None

.. _. _. . None _.. . . ....._.._....._.

None None None EUC 5-
~ VS1 0.72

. _._...._ 0.96 .__ . _.... _..... None

. _._ _.. . None

......_ . . . ..... None

__.._ .... ....__.. None

. . ....__..__ None

. ... None

._.. _ None

_ .___._... None

_.._.._ None

.. .. None

... ....... None

.. . None EUG 5- WS2

. . ~ None

--- - -- ~ . None

_ . _ None

.. . . ........ None

_ . _ _ . None _._. . . -. _.r None

. . .__......._ None

. _. . _ _... . None

._ . .. . _ . None None None

.... ._ . .. None None None - - -- EUG 5-Trim None None _ None None None None None None _ _- None ~ -- None None - -'-- ~

None None None NATURB AND CAUSE OF EXCESS EMISSION: (1) The scrubber was shut down for maintenance to do the PM. PROCESSES AND EQUIPM ENT IN VOLVED: (1) Wet Scrubbertll CORRECTIVE MEASURES TAKEN: (1) Checked nordes, mister, and sarety devices. Restarted the scrubber.
ADDITIONAL INFORMATION*: The lVet Scrubber was mnmtained and operated accordatg to the manufacture's instructions. Tbe repairs and maintenance were done as quickh , as possOtle, uttl'ving overtinte if needed. I certify, based on mformation and be8ef formed after reasonable mquiry, the statements and information m this docuntent are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted:



## ~ No AC"iENCY USE ONLY TrackingNumber: Tcam tD: DateSubmitted: 'a If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEO-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown UAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 2/3/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 2/2/2009 7:45PM SUBMITTED: SUBMITTED: 45 Minutes EE ID #, if a licable: 2/3/09 2/3/09 

# ***The owner or operator Inust demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to do the PM. The scrubber downtime was as short as possible to cornplete the work that had to be done. (2) The excess emissions were not part of a recurring pattem indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) Ifthe excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Fonn # 100-922 Page 1 of 2 Revised November 5, 2007

### - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- - - 7 - - - - - - - -



# (4) The facility was operated in a manner consistent with good practice for minunlzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

--------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ainbient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA

— - — - — - — - — - — - — - — - - - - - - - - - - - - ---- - - - - - - - - - - - - - - - - - 

# (7) The owner or operatoes actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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- u e — , accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUAL(TY AIR QUALtrY DMSION PO t30X 1677 OKLAHOMA CIfY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 w•orking days after the immediate notice is given. If you are using this form to cotrect a prevdous epoTt, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

216l2009 Dal•ItaOa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick SV"dfiams Plant Manager (918) 6834043 FAC7LITY: COUNTY: PERMIT NUMBER: Da41ta0a Muskogee 2004-198-TV (M-t) DATE AND 77ME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 2/2/2009 0:00 0:00 0:00 Htxtrs:Min Phase 1



### 13:15 15:00 1:45 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:45 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMtTATiON(S) OR REQUIREMENT(S) EXCEEDED: PermR No.2004-198-TV (M-1): Spec(fic Condhion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIAIATE ComplianceTesting X

. . _.._._ ...__.._.__. ......_...... . . __._._.__.._ ......._._.... SOURCE GRP HF HCL 80, CO VOC NOx PM EUG I _._._... .... _ ...._...... ..._.._..__ _. _.___._. . . ..._._.._.. ..._.__._ .. ___.._.._. .._..___ _.._.._.._ _ ____..... ._._ EUG 2 _._ _...._. _.. _..... _. _._._.... ._ . _.. ___.. .__.._..... . ._._._._.... .._. ....._. ......_.......__. . . _ _ _.._....__ _ _ .. _ __......_ ._. Conl Emissions Monitoring ......._.... _.. _.._ ........__ _._. ,.......... EUG3SD1 ..._._...._. . _0.39

. ..__......_ 000

__._._.__. 0.17

_._._..___ 6J0

. ._. 217

___._ ....... 198

.. ........ .._ .. 3.93

_..___._.. . EnginearinbCalculation X

........._ _.___..... .__.... _.......... EUG 3 SD2 .__._._..... 0.31

_ .._._._ .... 0 00

.... .. ....._..._.. 0.00

....___..._.. . . 6.94

_ . . . . _ 1.07

.. _..._....._._ 2.26 _. . _._......_ . . 2.96

. _ .__.__.. . . .._ Operating Logs X

_...__... .._..._ _ .._.... _. ...__... .. EUG 4\ Dst

.. . .., .. 0 03

..-- . . 0 00

_. _ 0.00

.-__. _ 6 OS

_ .- 0 76

.__ .._....... I 18

. . .... .. _2.62

. . .............. Other (explain) . ____.__. ._.____ _...__._._ ._..._... EUG4 VDs2 ..___ ......__._ 0.01

_ _._..._.... 0.00

_ __._.... 0.00

........ _. 3.55

_ _ . _ 0.45

...__ . ....._.__. 0.70

_ . _.._.__ 1.54

..___._.._.... _......._._. __...... ...._..._. ........... ._.. EUGS-wSl

. ._...__..._... 0.02 .._..._..... 0.28 _. _ Oi3

._. ._...._ ~ ~~ 13.05 0.85 ......._...... 4.44

._._....... 2.64 ._.. .._ _........... ..._..__..._ ._._...... ..__._.... .._.._.._. EOG 5- wS2

...... ... ....__._ 4.05

.. ......_.. 4.82 ._. t3.34 8.77

. _ ..._.... . .._.. 2.60

. ..._....._ 3.45

_ 4.70

_ __..... ._ _.._.__.. ..... EUG 5 - Trhn 2.03 2.59
. ~ ~ ~ 5.76 ~ - - 4.04 ~ 1.12 1.57 ~ 1.21 ALLOwED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO s CO VOC NOx PM EUG 1

... ___...__ --....__...__ .. ..._....___... _....__._._ _ _..__-__.._..........._ . .................. . . ..__.___. .... .____...__.... EUG2 ._.____ _.._...._...... ...._._.__.... .._.___.__ . ......._.._ _._......__.__...._.._.... ......__ ..... .........___. .__._._..._...____.- EUG 3 SD l _.. __....__ .__ 0.59

.._. ___. ...__...._. O.IO

.... . . _ _ ._._..__ 0.45

._._. _......... 13.77

...__......_. . _... __ . 9.67

....... . ...._...._..... 3.88

_ __......._..._ . 7.98

_ _...__...__ ___.__. EttG 3 SD2 ......_ 0.95

........._..... ..._.._ 0.90

.... ... . _....._.._.. . 0.45

.. . .. . _ .... . . .. 13.77

....._....... ___ 9.67

_...... _.. _... ......._ 3.88

....__..._..._ _. 7.98

........_._... _...._..._ F:I-C 4\'D sl 0.7 2

_ 0.08

. O.IS

.. .._..... 11.43

.__..__.. ____...._... 38J3

. _.._....._ 3.5t

_. ._._. 5.85

_..._.. _... ___...._ EU(:4 YDs2 . ..___ _ _ 052

._._...... . . ___..._. 0.o6

~~~~~ - ~~

_.. .. . ._..___._ ~ 0.08

....._..___... . . 5.09

_..____ _..._.. t7.04

......._ _._ __._.._... L56

...._...___. _ 2.60

. . _..._._.... ..._..._.. EUG 5-\V'S 1

. .._____ .. L43

___.._ ._...._. 1.60

._. _._.._ 8.96

..._ _-._ . __ 19.60

. . ....... 4.78

. . ...... 7.73 6.71 _...... . _... ___._... EUG9-WS2

. ...__._,_._ .... ___..... 2.14 ..._...._.

.. 2.40

.... _.__..____._. 13.44

....._.._.._........ ~ 29.40

_ ._......_.. ......... 7. 1 7

_.._.. ......__....._. 11.59

_. . _ _...__.._. t0.07

.... .._._ ._......_.. EL7G 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMtSS10NS: (based on 1 hour Gmks) EXCESS EMISSIONS: 24-Hr Totats SOURCE GRP HF HCI SOz CO VOC NOx PM HF HCt SOz CO VOC NOx PM EUG i _.... ....._.._. _ .. .................. . .._.._..___ . .___._._.. . _ ._ . _....... ...._.._..._._ ._ .. ____...__.. ..._....-_-... None .__..- --.......__... _ _ _..._. ._ None

..._...._ ..__._.... _... . _.___.. _.._ . . ___ . _._._. . __...__.__ _ ._..__._. .._. ............ ..... ..._....__ ._ __.._.... None ___... _. _.. _.._ . ... _...._... .._.......... 

### EUG 3 SD t

.. None

. . _. ... None

.. None

...... .. None

. . . ........ None

. ._._..__ None

. ._ ____. None

. ...._..... .... None

_....._.. None _. None

_._..,. None _..... __. _ None

_. ..._ . None

. ......_...._.... None

_.._.. EUC 3 SD2

. on

Ne

.. . _ ..__... N

_one _. ...__._..... None

.... . N one None None None ...._..._.. . None

._ ....... None

.. .......... Non e

._ ....._.. None _ None _.......__._.. None

......_._..... None

. _..__.. 

### EUC 4 VDSI None

.. _.__. .......... None

... . _._.._._._... . None

. . . .._._.. . . None

. ..._.._. . ..__ None

_......_. .. ._...._. ...................

None

. _. . _.._._. .. None

. ._........... None None None None _._... _ _ . _ None

._...__ . None

. . ..._.._._ None

_ _._...__ EUG 4\'ns2 _..__.._. .. None

..___._ _......__ Nonc

_... .. ..._..._..... None

. _.._.__.__.... _ None

_......_ . .. .... None

........ ... ........_ None

.. _.... _... ..... None

......__..__... ..._ Nono

..._.___. _. None

. _.._.....__ None

. ..._._. None .__. _.. _ None _._._...._ . None

_ ....._._.. None

.. .. ......_.... EUG 5-\

~ 51 ......._.._..._ __._ None ......_...__ None __....._._.__ None

._.._........_... None

_._.__..__. ...._. None

.._._. .....__._.__ None

......,.._.._.. .__..._.._....

None None ..._........_. None

_..._._.___ None ._..__._..._.._... None None

.. ..__.. None

.__._.._._. None

...____.._._. EUG 5-

~~ 52 ._.... _..__. 1.91

. ._...._ ..... 2.42

.. ......._.__ None

___......... . None

__.__..__ . .... None

..___. ......___._... None

... _ _ _._..... . None

__..._....... None

..__._.. None

._....___ Nonc

_... None ._._ . _ None ..._,......__. Nono

. _.._._.._. None _...._.__..._ EUG 5- Trim I None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenance to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber N2 CORRECTIVE MEASURES TAKEN: (2) Checked no -

rdas, mister, and safety deviees. Restarted the scrubber.
ADDITIONAL 1NFORMATION * : The wet Scrubber was maintafned and operated according to the manufacture's mstructions. The repairs and ntahrtenance were done as qufcklv as possiltk, utilbing overtime if needed. 1 certify, based on informatfon and betief formed after reasonabk inqulry, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Rceeived By: [kmonstration of Cause Submitted: 

### = No AGENCY USE ONLY TrackingNumber: TeamlD: DateSubmittal: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEO-Form #100-920 ReAsed February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The inforrnation requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 2/3/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 2/2/2009 1:15PM SUBMITTED: SUBMITTED: 105 Minutes EE ID #, if a licable: 2/3/09 2/3/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to do the PM. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattem indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. L '



# DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

### .-.- - - 7 -- - - - - - -



# (4) The facility was operated in a manner consistent with good practice for mmimlzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipinent to niinimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- --------------- 

# (5) Reasonable steps were taken to minin

- iize the impact of the excess emissions on ainbient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Emissions monitoring systems capable of produc'mg valid data were kept in operation if at all possible. 

# m (7) The owner or operator's actions during the period of excess emissions were documented 

# by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

on in 

# - ma n a - MeT 

# — 

# ~ l = - — - — - — - — - — - — - — - — - — - — - — - — 

# T,ertify, ;a,,d ior t 7 io n7d Teli;f For after reasona e inquiry, the statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Form 

# # 100-922 Page 2 of 2 Revised Noveinber 

# 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: The information requested beloEV shoutd be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fomt to correct a previous epon, provide only the corrected infotmation below, sign the cenification, and attach a copy oftlte previous report.
REPORT DATE: COMPANY NAME:

2/132009 Dat-ItaOa NAMEOFINDIVIDUALREPORTING: TITLE: PHONE: Rick NYtlliams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUM1TBER: DaF(talia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date StartTime: StopTime: Duration: 2/122009 0:00 0:00 0:00 Hours:Min Phase 1

9:40 11:20 1:40 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:40 Hours:Minutes ofWet Scrubber potrrntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCE6DED: Permit No. 2004-198-TV (M-1): SpeciBe Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE Co mplianceTesting X _.__.... . . ..... SOURCE GRP HF HCL SO i CO VOC NOx PM Et ' G 1 .._ ._ . _ .. . ___.__._ ..__._..._.. . __....... ._._._._.... _._ _ . . _ .._. .. . . __... ._...___ .. _____.._.. ......_._.. ....._.._ .__ __ .._..._.___._.. _.._._... ......._.. ._ issionsMonitoring ._.__._ ... _.._ _.. ............_. . ._._.._._. . ..._.._.. Ct'G3SD1

.... ._._. _ ._.._..___ 0.37

. ..._.___ 0.00

.. ......_.._ 0.16

..__...___ 5.98

_._........ ..._ 2.06

_._ ._._. __.. 1.88

_ 3.73

.._.. ....... ...... EngincaingCalculation X

..._..... .,_..._ .. ..___.... . _._...__.. . . __...... GI - G 3 SD2

. ..._....... 0.28

_ ...._.._... 0.00

. ...__...... 0.00

_.._.__._ 6.27

_.._..___ . ...._ 0.96

_._ ...---- -.._... 2.04 2.68

...... Operating Logs X .._.._...._... ....__.. _._... _.._.... I:I:G

~ 1VDs1 -- ..... 0.02

_..___... . ._..... 0.00

.. _._..... 0.00

. . . . ......_._..__.

5.25 0.66_ .__....___...... _ 1.03_

.. _ . 2.28

..__...._.. ...._...__ Other(explain) ....._...._._.. . .. EEG4

~ 'Ds2 0.01

__._.._.. ~ 0.00

.. _ ~ 0.00

. 2.64

. _....._ 0.33

. _ .._ __. 0.52

_ 1.14

_.._._..... ..__.___.

.._....... ..__._..._. . . .__ .__.__ ..... ...... EUG S- 11

~ 51

... . - ~~ 0.01 _.._..... 0.20

. ._.__ 0.23

_ . _... ._.. 9.03

_ _ . . _....._. 0..59

......._.__ 3.07

. . . . _ .... ... 1.83

..._.__... ...__..._ ..______.. ._ ........... .._..___._ ...._._.. EUG 5_- R

~ 52

. . 9.60 ..._...... 11.43 5.I8 11.13 EUG5-Trim 1 1.07 1.37 3.05 1 2.14 0.59 0.83 0.64 _... _. ...... . ....... ___._.. . ____... Attach supporting data ALLOWED EMISSIONS: SOURCE GRP HF HCL S0 2 CO VOC NOx PM FIIG 1 ..._ .__.._._.. .. ..._.._...__ ._...._.._.. .._.__ ... _._. _._...._ __...___.. t:UG 2 EUG 3 SD 1

. 0.59

.___._. .._._..._ 0.10

_ . __.._..__... 0.45

..._.._._.. 13.77

...___.. ._...._... 9.67

_..._..._ . 3.88

......__. .. 7.98

_ ..___.__.....___._._ . F.CG 3 SD2

.. _ 0.95

_....._ .._. .._.__. 0.90

.. ....__.._._.. 0.45

..._........... 13.77

.......... .......... 9.67

._. .........._.. 3.88

........_._. 7.95

..___'-..._. ____.._.. t:UG 3\'UsI

. .. 0.72 0.08 .__._..__. O.18

..._._._..._._. _......._..._.

11.43 ._.._...._... 38.33 3.St

_...___.._... 5.85 EIiG 4 VDs2

. 0.52

.._ _ . .....__._ 0.06

.. ..... ._ ..._.__. 0.08

. ..._.__....._. .._ 5.09

.__-.._._ . . .._.__ 17.04

.__. ...._....__. 1.56 - _ 2.60 - ..._.__... _..___.. EUG 5-

~ \'S1

.. _.__.__. .._...._._ L43

_____....._ 1.60

__ 8.96

_.__.._... ..._ 19.60

............ .__.....__... 4.78

......__...__. 7.73

__......._. ...... 6.71

._._........__._..._ EIIG5-R'S2 ._.. ._.... .. ...._.._ 2.85 _.__..._. 3.20

....,._____.. 17.92

.._.....___.. 39.20

._........_. ..._.._..... 9.56

..__......_.... 15A5 13.42

...__.._..._. __..._...__..._.._..._.__. EUG5-Trim 1 3.57 1 3.88 1 9.68 1 6.75 1 3.67 1 2.00 1 1.80 EXCESS EMISSIONS: based on I hour Omhs EXCESS EMISSIONS: 24-Flr Totals SOURCE GRP HF HCI SO r CO VOC NOx PM IiF IFCI SO, CO VOC NOx PM EUG 1

. ._......_ ..... _.._._ ._ . ........._ _... ._._.__ . ... _

.._ ._._....._. _..._._.__. . None

............ _ . __...._.__.. ._....... _. __.._.._._ None ...__.. EUG2 --_... . _...__... . ...__... .......... __...._... .._..._._ ..___..._._. None ...__ ._.. .............._..__.._........_._.... _...._...... _........ ......_..._.... ._.....-_.... None ..____. 

### EUC 3 SDI None

.__..... . _.._._._ .. 

### None

.. .........___ 

### None

.___.... 

### None

__._...__ ._.. 

### None

_..._ ..... .... 

### None

... _......._._. 

### None

.__.._._..... _._ 

### None

.._..._.. .. 

### None

. ...._.._..... 

### None

. ._._._ 

### None ._. ....... 

### None ...._..._ ... 

### None

_..__.__ 

### None

............. tiUG3SD2 _...... ._ .. _._...___ None

_____..._... None

._....____... None

__....__._. Nnne

__......_.. .__...._._.....___.

None None

.____....._. None

................ ....... None

......... None ._..___.__ None

. .__...___. None None

.............._.... . None

._.._ None _....__....... 

### EUG 4 VDsI

. 

### None None None

_ ....__.. 

### None

_ _ . . . __. 

### _ None

. 

### _ -. 

### _None

---- 

### None

. .. ... _...... 

### None

_.. .._ 

### None .,. _..__._.. 

### None

. . 

### None

.... . . _.. 

### None

...... _. 

### None None EI7G 4 VDs2 None .....__ None _.. ~ _. .._ _ . . None

.._._.._.._ . _.. . 

### None

. _ ... . ___.. ~ 

### Nono

_.._. .._...____. 

### None

_ -...-- 

### None

_.__.._ 

### None

_... _.. 

### None

....__.... 

### None

. __ ..._ 

### None _.. _ 

### None ...,.__._. 

### None None

.._. .._.._.. 

### EUG 5-WSI _..._._.._ ...... 

### Nane

..___.__.. ... __..._ 

### None

_ .. . .._ 

### None

...__..-_._.... .. ..._._._......

.- ~ -- 

### None None __..._._. ... . 

### None

. . _ _ .. __.._... . 

### None

_ __._._. _ ..._. 

### None

. _...... 

### None

.._.._.. 

### None ..__._.._ 

### None

..... _._ 

### None

. 

### None

...... ......._. 

### None

........__._. EUG 5- WS2 6.74

._..__. 8.23

.. ~ ...._ _ . _13.69

. .. .. ... . None

... . .__......._ None ____...._... None

. . . None

._ .._.. . . _._ None

... .__ None

.. __._.... None

..... None

._. ... None ._.._. None

_ .__._...._. None 

### EUG 5-Tr'un None None None None None None None I None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenanee to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (2)1Vet Scrubber #2 CORRECTI!'E MEASURES TAKEN: (2) The nor

~ ks were taken out, cleaned the mslde of the tank, and Bushed Gnes w•hhout novJes. The nordes were msta8ed and the scrubber was restarted.


### ADDITIONALINFORMATION*: The R'et Scrubber w•as maintained and operated accordmg to the manufacture's instructions. The repairs and mamtenance were done as qulckly as posstltle, utitiring overtime if needed. I certifc, based on mforntatlon and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Reccived By: Demonstration of Cause Submittal:



## ~ Nn AGENCY USE ONC.Y TrackingNumber: Team ID: DateSubmitted: "` If you wish to notify the DEQ about a technological limitation, do so here and attach supponing information. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QIIALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown UAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 2/16/09 NAME OF INDIVIDUAL REPORTING: TITLE: PFIONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIaTE NOTICE DATE WRITTEN REPORT EMISSION: 2/12/2009 9:40AM SUBMITTED: SUBMITTED: 100 Minutes EE ID #, if applicable. 2/12/09 2/16/09 

# ***The owner or operator must demonstrate each of the following itelns in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages lnay be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conteinporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess elnissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to do the PM. The nozzles were taken out, the inside ofthe tank was cleaned, and the lines were flushed without nozzles. The nozzles were installed and the scrubber was restarted. Th_e scrubber downtime was as short as possible to complete the work that had to be done.

_ _ _____ (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to colnplete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Fonn # 100-922 Page 1 of 2 Revised November 5, 2007

# .-.- - - -- - - - - - -



# (4) The facility was operated in a manner consistent with good practice for mmlmlzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to miniinize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ai
- nbient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Ernissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA

— - — - — - — - — - — - — - — - - - - - - - - - - - - - = -: -- - - - - - - - - - - - - - - - - 

# (7) The owner or operatoes actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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# SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised Noveluber 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUAl.1TY DIVISION PO BOX 1677 OKLAHOMA C(fY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The infonnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If }rou are using this form to correct a previous eport, provide only the corrected information below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

227t2009 Dal-Ilalia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rkk Williams Plant Manager (918) 6834043 BACILITY: COUNTY: PERMIT NUMBER: DaHtaOa Muskogee 2004498-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 

### 2232009 10:00 11:30 1:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:30 Hours:MinutesofWet 

### Sc rubb 

### e rp 

### otvnt i 

### me APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specific Conditron 1, EUG 5 ESTIMATED EMtSS10NS: BASIS OF ESTIMATE ComplianccTesting X __.._ ..._...._. ..__._.._.. ...._..._.._. SOURCE GRP HF HCL SO i CO VOC NOx PM

_~ . EI1G 1

.. ._.__.. .. .........__ . _._._._._ _...___ ___._.. . ...__._. ___.__...._ __.____.... . _........__. .._.....__._ EUG2

... _ . _ _ .... ........

. _ . . .._.___.

.... . ..___._. _....... __ ...__ .._..-.....__. .. ...._._._. ....._....__ . ..._._..._._ _..........ContEmissionsMonitori n g _..._..._... . - ..__..__ ......._. EttG 3 SDI 0 48

.. -. 0 00 __. .........._. O.16

.--..._.... . G06 2 09 -, ... t 90

. . .._.. 3.78

.. . Engmeering Calculation X ..._. . __. 1•:CC35D2 ._ ._ .. 0.37

... . --.._._

. 0.00 _... _...._.__.... 0.00

..._._____. -. ~ 8.20

.........._. -...._ L26

.. 2.67

. ... .............. 3.50

.._.___.. _.. Operaiingt.ogs X

.._...___ . .__......_ ..- -_........__. . .._.._..._ _._..__.. ,.EC(:aVDsl

... _ -.. 002

_.,_. . ._. ..._.... 000 ,...0.00 -.-..... 5.42

..._._... . ._._ 068_.._....

._..._ . ... . 1•06

___ .......... . 2,35

... ...__._. .. Other(cxplain) El1G 4 VDs2

_ . . 0.01

.._ ...... . ... .. ........_..._--

0.00 ..._ . ..__.._-.. 0.00 2.79

. _. .. . ..... _- 0.35

..._.._. . ..... .. . __. 0.55

. . .......__ 1.21

.... __... _ .._...._.... .. ..._._......... . -----..._.._ - ....___-__. .. _.. ___ .

__....._._ . .__.__..._ . .__.___ . _ ___.__ . .._____. EUG5-R'SI

.. _. . ._--

4.99

... . - _.._._....... 5.93

. _..___. 16.42

.. . . _. .. . ]0.80

...___.... . ....._ 3.20

___.... . ....._.._... ~ 4.25

. ...._ . 5.78

...._.... ... ___....._ . ........_.._. ... ...._._.__... ....._ _..._ . . _-_..._._._ EUG 5- WS2

. ~ -- 0.00

.. 0.01

- ....._. 0.02

. ...... _.. 11.44

.._......_.. . _ .. 1.91

._..__. . .._.__.. 3.69

. .._ 3.36

. . .. ___.___.. ._.__..._. . ._.__.._... . ..._.__.__ ..._....__...- EUGS -Tr'un 1.65 2.10 4.68 3.28 0.91 1.28 0.98 _._.._... _......__._ ..__.___ _._-._._..._. ALLOWED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO i CO YOC NOx PM EUG I ._._. ..._ . .._... __.. ..._._..._.._ ._..___..... _.._......._ -- _...- _........ .. ......_....._ . ._._._..... _ _.___.._..___.__. 

### EUG2

. ._____.. .....__ .._..__._.. ._.___._ ..__...._.__ _...___. ._._.._._.._........_ _... . ._._......... ..._....______.___ EUG3SD1 _ _.._.__.. 0.59

._____ . ._.._....... 0.10

.__. - ......_. 0 .45

. ._ _... ._._... 13.77

.__....... _._ 9. 8

67 .__... 3.8

. .__._. 7.98

........_....____..._.... EUG3SD2 --._____ .... 0.95

.......... ...___. 0.90

_... ............_..... 0.45

- ....__._._.. . -........._..._

13.77 ...._. 9.67

__._... ..._.-.. .._.... 3.88

. ..__._._... 7.98

.. __.__._.._.._._.___. EUG4VDst __,_......__ .. . 0.72

._____. __._.. 0.08

..._. ..._._ ...._.._ 0.18

. - ._..._._.__ iL43

_ .............. ..-- 38.33

-_._..... ......- .._..._. 3.5t

. __._. _ . . 5.85

_ .. _ ....._._._.._._.-_ EUG 4 VDs2

.. 0.52 0.06 ._._...._.. 0.08

..__..__._ ... 5.09

...... _ ___ t7.04

___... .. __ _. ... _... L56

_ . .............._ 2.60

..._..... _ ._._.__. WSI

.. . . 2.85 _ ............ . .....___ 3.20

__.. ...._._..___ t7.92

- . _..........._. . 39.20

.............. _ .. 9.56

._....._._ ...... I5.45

. _...._._....... 13A2

....__...._. _.._._.. I(UGS-

~ VS2

. .. 1.43

............... ... _ L60 _.._.....__ 8.96 ...._. _. ._.-.. t9.60

__..__.._..... . _ _ 4.78

.. _.. _..._.. . _ ...... 7.73

. , ...___._..... 6.71

...._._...._._._..____. 

### EUG 5- Trlm 1 3.57 1 3.88 9.68 1 6.75 1 3.67 1 2.00 1.80 EXCESS EMISSIONS: based on I hour Icnits EXCESS EMISSIONS: 24-Hr Tobls SOURCE GRP HF HCI SO z CO VOC NOx PM tIF HCI SO, CO VOC NOx PM EUG I _. . ._. ....._ _._ _...____ . .,-__.._.. . ...._...... ._ __.... ._.._-.._... . _ ......... .. None

.. ..._._.__ .___.._ . .___-.... .. ._...._.._. . .. _.__...._ None

. _. __....-.... EUG 2

.. ._..__. . ........ ..... ._._..__.._ . _...... _. _.._. __.. . ._ .......... _ ........... . .._._.... None ....___..__ . . _ __....__ ._._..._. ..._.. .......__.. .__........ None

.. _.....___._. EUG3SD1 ..__.__...._ None

..__.__ _.._ None

..... .__..._.._.. None

. None

...___..._ .__._ None

__...._ . _____...... None

. ............. None

.._..__.._. _ - None

..-...___. None None None None .........._ .. None

__.__.__ None . _._..__._._ EUG3SD2 _.....__... _... _ None

_ _.._...._ None

__........_ .... None

. .........__ None

. . . ._. None

_...._. __.._...... None

_ ._.._.__ None

. ... . . _ None

.... ..._.. _. None

.... _..,_ ._. . __-.

ne ._

_ .. . .__ Noone ._._. N ..... .__... Non e ._......._. None

._..__...._ None

. . _..._......_ EUG 4 VDsI

......... None _._._.. None __. .._.._._..._ None

...._..__... None

___.._ . _..._..._.... None

._... None

.. .___... None

..__._._._._ ~ . .._. None

__..._.. None ....__._._ None

___....... None None ....._...__. None

......,_ ........ None

........_.. EUG 4 VDs2

........... . None

.__._.. None

._..._._ ..__......_._. None None None ......_._. ..........___... None

._..._.__._.. None

_...-. __.._... ......._........

None None

.._..._...._. None None

......_..... None

....._.__... None

........._.. None __.._._._.. 

### EUG 5- W St 2.t3 ... _._.. .__ 2.73

.. . ............ None

...._...._._ . None

. - . ....._.... None

._ ... .........._._. None

. _-.._..._._ None

. .. ..._.. . None

__.._._.. None

........... None

. None _. None None

_.. _._..__ None

...._.... 

### EUG 5-
~ VS2 None

.-.._.. ...__._...._ None

_ .. . ._. _.. None

._....... .. None .__._. .... None - ..._._. \one _.. .. .____._.-.........._._.

None

. None

._ _... None

._...._.._. None

........ None _.__ ...._..._.....

None Nnne

__.__. None ..__....._. EUG 5-Trhn None None None None Nono 

### None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenance to do the PM. PROCESSES AND EQUIPMENT tNVOLVED: (2) Wet Scrubber 92 CORRECTIVE MEASURES TAKEN: (20 The noifks were cleaned, the sludge level was checked, and the scrubber was restarted.
ADDITIONAL INFORMATION*: The LVet Scrubber was maintafned and operated accord'ntg to the manufacture's instructions. 7'Ihe repa'vs and mamtenance were done as quiek(y as possible, utilvmg overtime if needed. I certi)y, based on hdormatiun and beGef formed after reasonable inqurcy, the statements and ioformation m this document are true, accurate and comptete

SIGNATURE OF REPORTING PERSON

Date Received: Rcccived By: Demonstration of Cause Submitted: = No AGENCY USE ONLY TrackingNumber: TcamlD: DateSubmittcd: ' If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause laeport Form for Maintenance, Startup or Shutdown QAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 2/24/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 2/23/2009 10:OOAM SUBMITTED: SUBMITTED: 90 Minutes EE ID #, if a licable: 2/24/09 2/24/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in perinits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conternporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess einissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down to for maintenance to clean the nozzles and check the sludge level (P1V1). The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property dainage. M 2.1



# DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# (4) The facility was operated in a manner consistent with good practice for mlnimlzmg emissions; provided,

however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize einissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the iinpact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible.

m
— - — - — - — - — - — - — - — - - - - - - - - - - - - ---- % - : - - - - - - - - - - - - - - - - - 

# (7) The owner or operator's actions during the period of excess emissions were documented by properlY signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALI7Y AIR QUALlTY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 wrork-ing days after the immediate notice is given. If you are using this form to cotrect a previous pon, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAM@:

2127l2009 Dal-ItaBa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick WilSams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal•ItaGa htuskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 2/25l2009 0:00 0:00 0:00 Hours:Min Phase 1



### 10:00 10:25 0:25 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINllTES): 0:25 Hours:Minutes of Wet Sctvbber powtttime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: PermB No.2004-198-TV (M-1): Specirie CondBion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting ..._.._.... .._...._._... . __._...._......._ __._.... _ ..._.__._._ X SOURCE GRP tfF HCL SO i CO VOC NOx PM EUG I _.. . ..... _.. __....._._ .. ._._...___ . .._ ............ . ._..._. .._.._.. _...._ . .- ___....__. . ._-._.__..... _._._....._.. _..._ .EGG 2 ...___._ _........__. _ ._ __._....__. . .._._.__._ _._.___...__ ..___......__. __..._.._..... ....__....__.. ___.._.__.... Cont Emissions Monitoring

............. ..........._. _. _._._.._..._ ...... _.._ X E U C 3 SDl

..... .. .. _ . 0.36

. _.__..... 0.00

,... . . _._. _..._. 0.16

.___... .. 5.87

...___._._. ..._.... 2.02

. ... __...___... 1.84

. ._ _......_ 3.66

_.......__. ._.. Fmgincering Calculation

_..__... ......___ _......... ._ ............... . ........_.__. EUG 3 SD2 _.._ _ . . 0.32

...._._._ _ 0.00

_ . _.._. _... 0.00

.. ...____.... 7.07

... ... _ _ .___ 1.09

...._ . ... ..... . . ...... 2 3 0

.........._.. 3.02

........._._ ..._ Oporating Loys

._......... ....__... .. __...__ ....__...___. ... . ___._.. X El'C4VDs1 0.02

. ......__.. 0.00

_. _ .__.......... 0.00

......... ._ . 5.t0 0.64

. .._......._ L00

. ..... . 2.21

_.. __..._ . .._ Othcr(erplain)

__.._... . __...__. _..._.._. ._.......... ..._.....__ EliG4 YDs2 ....._. _ ~ 0.01

._..._. ._._.._._ 0.00

.. . . . 0.00 ~. . . ~~~ -- ~~~~ 2.66 ~~~~~~~

_.. .. ~~~~~.. ~ 0.34

.. _ . .. 0.52

.._. 1.15

. _ .__ . __..._... _ _.._ . _...._.__.. __....._.. EUG5-R

~ S1 - _ .__._.. 0.01 ._....._. 0.16 ._ . ....._.... 0.19

...._.__ . _ .. 7.4t ~

_ ..___ 0.48

_._. . ......_._ 2.52 ...._ 1.50

... ... ___._.. . .____._.... _ _._._._..... . ...._._._. ._..._._. EUGS-

~ ''S2 2.46 2.93 8.10

_ _ . 5.33

. . _. 1.58 _.._. ......._- 2.10 2.85 EUG5-Trlm 1.43 1.83 ~~~~~~_ ...... 4.08 ~ ~ -- ~~~~~ - 2.86 079 1.11 ALLOWED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO z CO VOC NOx Pbi EUG t ..____. _.. .___. _ _.......... ____.. . .__.___.. . ..__ ........ ......_.... _...___._.. ._. _...._ ___._. EUG 2

_ .., _........_ .....____.... .__.__... .__..._._._ ..._._..._.._ _............ __......... ...._..__..._.._._..._. EUG3St>l ..__..... ..._.____. 0.59 .._._. 0.10 ._ _.___._._....__. f1.45 13.77 ___...___ .. .__._.._._. 4.67 ...._.._._. 3.88 7.98 EUG3SU2 ._...... . 0.95 ....._.._ 0.90

_ ... ..__.._ .... OA5

..........._. 13.77

.__._....._ _ ......._.... 9.67

..____.__. 3.88

....._... _._.. 7.98

...._...___. ._..._.... EUG a VDSI _..._.. ..._ 0.72

_.._. _. . _ .... 0.08

.. ............... O.IS

......_... 11.43

..._ ..___. 38.33

_...... . __......._... 3.5t

........_..___. 5.85

.._._..__.._ __..._. El~G4~~u4 ..._ _.._. _ 0.52 _...__.. 0.06 _. . . .._...._.. 0.08

_.__..._... 5.09

_.... _..__. 17.04

_.... ......._..... 1.56 2. 6 0 _.. .._...._... EUGS -

~ VSI ...__. _ - 1.43

__.._._ ...._ 1.60

... . ......_..._ 8.96

.......__._... t9.60 _._ 4.78 ._.... .......__.. 7.73

......... 6.7t

...__...._.. _...._. EUG 5- WS2 _.. .... 1.43

___..._. ..._.___._ 1.60

... _._.._.__. 8.96

_..__.._... ... t9.60

._.._. _.... ...__... 4.78

__. .. __.._..... 7.73 6.71

_ ............... EUG5-Trlm 1 3.57 1 3.88 1 9.68 1 6.75 1 3.67 1 2.00 1 I-80 EXCESS EMtSSIONS: based on t hour SmHs EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG ( .._.__... ._....._... ...._.._._ ___.... _._.__.... _._.... ___. .._.....__. _._.... None

. __...._.. _ - -- ._...__._. ._..._..__ . _ ____ . _ ._.__..___. None

... ....._.... EUG 2 _._......_ ...._.__..._. ... __.._ _......_..__. _ _._.......... .. __.... .._._....__ ._.. .._ . . None _.....__.._ .... ...... ......_ . _..___._... . ____.....__ .._. _...___ . ...._._ _.___ None ..._......__... EUG 3 SD1

. .__.___ . _ None

.__..... .....__..__ None

._ __........___ None

. ___.._.._._. None

.....__.__... _..... None

__.._. ... _..._._.._ Nnne

... ....___.- None

__-._._.._.._. _.. None

.__..__. ... None

.. ___._.... None None

_....- .. _ None

.._.._._ _ None _ .. ......... None

... ...._._.... EUG3SD2 ...__ ._. None

.__...... None

._.. ..._..... _. None

.._.__..._._ .. None

._.._. .. ........ None

...... . ____..._. Nunr

_ .._._.__.. ... . None

._- _... . ....._ None

. ___... . None

._....__. None ..,._.__.. None __. . ._ . None .___...._. . None

... .... __.._.. None

_ ._ ._..._.. EUG

~ 44Ds1 _._ ._._.._.. None

......_. ___.._.. None

.. ._._.__ .._ None

_. _......__ Noue

._...__._. ...._..._... None

--- .. _._....._. Nnne

._._. None

___..__...._ None

_._....... None

.....__._. None

._.. None

.... ..._.__._..

None

. None .._.._...__. Nono

... ......._._..

. EUG 4 V6s2 None

...__.... _ _..___... None

... _._.._.._..... None

. . ...___ ........ . .. None

. ...___.... .......__ None

.._._. _ .. __ .__..._. None

.. .. _..._... None

. _._......... None

.......__ None

....__....__.. None

__.., . None _... . _ _............_.

None

.. None _._......_. None _.. _ ._.. ..._.._ ._ F:CG 5- WSt None

._._.__. . . _..._ None

._ _.._.__._. None

_..._...__._ None

....__..... _ .....__ None

._...._ _... ........_.... None

_. _.... ...__... None

......_..... ... None

.__.._._ None

._...._... None ..___._ None .._ None .._......... None

.._..._.... None

_._.__... laUG 5-%

~~ S2 1.03

......._ ......... 1.33

....._.._...__ None

_._.._..._.... ......__._.

None None _._._..._.._......_..._..__... None _._.._..__ None

..__..._..,.._ _....._..__

None None ............._ None

_.._...._.._. None None .._.__ None

.__.._._..._ None

..._.__..... EUG 5-

~ Crim I None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber w'as shut down due to a ntaifunctlon caused by luw quench flow becaause debris broke bose and clogged the nordes. PROCESSES AND EQUI PM ENT IN VOLVED: (2) Wet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The quench nosde and empenger novles were cleaned and the scrubber was restarted.
ADDITIONAL INFORMATION*: The Wet Scrubber was maintamed and operated according to the ntanufacture's instructions. The repairs and malntenance were done as quickl , as possible, utJ'rring overtime if needed. 1 certify, based on information and betief formed after reasonable inquiry, the statements and informatiun m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: ReceivcA By: Danonstration of Cause Submitted: AGENCY USE ONLY = No DateSubmincd: TrackingNumber: Team ID: " Ifyou wish to notify the DEQ about a technologieal limitation, do so ltere and attach supporting informatfon. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLA.HOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause 12eport Form

for lVIalfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be subinitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: 2/26/09 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 2/25/09 10:OOAM SUBMITTED: SUBMITTED: 25 Minutes EE ID #, if a licable: 2/26/09 2/26/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exeinpt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a nonnal or usual manner. The wet scrubber was shut down due to the sudden malfunction caused debris breaking loose and clogging the nozzles. This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision sha11 not be construed to automatically require the shutdown of process equipment to miniinize emissions. The scrubber was maintained and operated according the manufacturer's instructions. DEQ Form # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

- - - - - - - - - - - - - - - - - - - - - 7 -- - - - - - - - - - - - - - - - - - - - - - 7 -- - 

# (5) The amount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of malfunction; I'lowever, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minimize ei

- nissions.

-------------------------------- --------------- 

# (6) Reasonable steps were taken to niinimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of producing valid data were kept in operation if at all possible. 

# m

----------------------------------------------- (8) The owner or operatoes actions in response to the malfunction were documented by properly signed, conteinporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recun

- ing pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recurring pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfTY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EAIISSION FORM OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous 

### rep orL provide only the corrected information below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:



### 2272009 Dal-ItaOa NAM1tE OF INDIVIDUAL REPORTtNG: TtTLE: PHONE: 

### Rick 'fflil8ams Plant Manager (918) 683-4043 FACILITY: COUNTI': PERMIT NUMBER: 

### Dal-ItaBa Muskogee 2004-198-TV (M-t) DATE AND TIM1tE OF EXCESS EMISSION: Date Start Tme: Stop Time: Duration: 

### 2252009 0:00 0:00 0:00 Hours:Min Phase 1

8:00 9:20 1:20 Hours:Min Phase 2 DURATION OF EXCESS EM1iISS10N (liOURS:MINUTES): 1:20 Hours:Minutes of Wet Scrubber powrotinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Speciric Conditiun i, EUG 5 ESTIMATED EMISSIONS: BAS[S OF ESTIMATE 

### ComplianceTesting X _._ _._....... _.._....... .._.._ ....__ .__.._.. _._..._... . SOURCE GRP t(F HCL SO i CO VOC NOs PM1i 

### EUG I ____.._...._ .. .. _____ .. _ ._...._. ._. . .___._ _. ......._._ .......__...... .._ .__._.. .........._.._.. . .-_- _- _.___ ..__....... _... EUG 2 . _ .. ..__ ..... . . . .. ...._ ... . ......_. ..... ........___.. _...__...___. ...__.._.._.. ....._. ....... . _._.......__.. _.__.__.._. _._..._- ..... Cont Fmissions Moniloring ......__... ___..___... ._... _.._ ..._.._ _....._. __.._.._._ EUG 3 SD 1



### . _....._...._.. .. 0 36



### ___.__ -......._.. 0.00



### _.. _.._.__.__ 0.16



### __......__ 5.87



### .__...._. 2.02



### .._........ .... _.____. 1.84



### . .. __.._. . 3.66



### . ............... ._...__._.... Engineering Caleulation X 

### _._.__.__.. ....___...__ ._...___.. ..._..___._. EUG 3 SD2 ...__...._._. . . OJ2

__....._.. ..__... 0.00

..... __ ............ 0.00

....__....___ 7.07

__...... .. 1.09

___.. ................_. 2_l0

... .._. ._.__._ 3.02

... _.._._...._ .........._.... OperatinS LoSs X ......_.. . ..._. __... _._..._._ .._......__..._ EUG 4 VDsI _. - ...._ 0.02

_ . ..__...... 0.00

.._ _0.00 _

. .. _ 5.10

. . _ 0.64

_ ...___.. 1.00
_ 2.2t _ _.. Other (explain)

.............. _.___._... .___..._ ..__.___._. EUG4 VDs2 ..._...._ . 0.01

__ .. ....... 0.00 .._._.. 0.00

.... . ~ 

### 2.66

..._.... .... 0.34

_ _._.._._. 0.52 ~



### . -._. Lt5

....._ _ .. . __..._. ....__ .... . . ....... _ ...__......

..._...__ EUG6-

~ 

### YSS

. .._._ . 0.01 ~



### . ._ . _ 0.16

.._ _....._.... 0.19

....._ .. 7.41

. . 0.

~ 

### 48

. . .. ..... . 2.52

... ......... 1.50

......._..... ...... . 

### . ........_ _....____.._

._._... ......___.__ EUGS-iVS2 7.87 9.37 

### 25.92

_ _ - 

### .._ . 17.06 ..........

___.._.. _.__..._._. 5.06

. ..._.__ 6.71 1111111 

### ... 9 

### . 13 ._ .... . ......._.. _..

__.._..__ _.... ... ............. EUG 5- Trhn (A3 11 

### 1.83 4.08 1 2.86 1 0.79 1.11 0.85 __.__... .._......__ .... .............. ._.__..... ......_._ Attaeh supporting data ALLONED EMISSIONS: SOURCE GRP HF IiCL SO, CO VOC NOx PM EUG I



### ...... .... EUC 2

....... ..._.._.__.....____ __ ...._.._.__._ - ___ _.._._ ..._.___..... ._.._._._.. ....___.._.....__......_. EUG3SD1 _._ _ ... ... 059

........__. .. .. 0.10

.....___. _.__.._.._....

0.45 _.___.. . 1377

... 967

_ . ...__._._._. 3.88

_

.......... _..... _. 7.98

_ . .. ...._.. EUG3SD2 ___......_. . 095

..__...__. .. .. ..___ 090

..._--- .-_.. _.__._. 045

. -- _ . .. _ _ _ _I377

.. 967

. _ .. ..__._. 3.88

........_ ........ .. 7.98

.. . . ...__._._.__- EUG41'USl ...__.__..... .. 0.72

.____._... _ ._ .._. 0.08

_... . ...._.._.....__ 0.t8

_ _.. __....... . _ 11.43

..._ ._.._._ _..-- -- 38.33

.__...._. . _..._._.. 3.51

. . ._.._......... . _ _. 5.85

..__.__.._.._.,_-. EUG4 VDs2 .._._. _ _ ..__.._. .. _ _. ..__. .... ...__...._.....

052 .._...__.._ . .... . _ ...._..___ 156

..... . _.. 2.60 __. . __......_.___..._-. EUG5- ~\~ 

### SI __..._...._._ 1.43

..._.... _..____....... L60

._.._.__.__ 8.96

....,._.._. t9.60

..___...._ . .___.......... 4.78

..._..._.._.__ Z73

. ..._ -..._._ 6.71

....._..__. EIiG 5- R

~ 

### S2 _._.. 2.85

, .._._..._ 3.20

.... ......_......__ 17.92

.....__..... 39.20

....._......._ .... . ._ 9.56

._._.._ . 15.45

. .. ...__..._._ _ 13.42

. .._.__..._.__..... _... EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on t hour funhs) EXCESS EMISSIONS: 24-Hr Totals S OURCE GRP HF HCI SO i CO VOC NOx PM HF tiCl SO i CO VOC NOs PM 

### F:(1G i _._......_ ._.... _.__ __ . .. .. _..._.__. _._ .. ..._ ...._ _ ..._._.__.... _. . ......... . ....._....__. .. ... ..__.__.__ . None

.. .... ._._ .... . _........... . .. _ ...__.._. . _ _ ........ ..._.._ . _ _ _......_.. .__.._._. _ _ None

. _.__... EUG 2 

### .....___ _ _.___._ . - ..._.. _... .._..._.._ ..__ ...._.... .._._ . . _,_._......_ ........ ......... ...._........_. ...__._.__.....- None 

### _........_ ... ._.. . ._......... . ...._..._.__, .._.._._....... _ ...._ _........ ._....._.__.. None



### . ._..____. EUC 3 SDi , ___.___ . _ N

.



### ._._._- - -.. _ ..... _. None

_. .._ . _.. None

. ... ..._.._._ . None

..._...___.._ . _. _... Nune

..___.. . .. _..__...._ None

. ._....,__.._..,_ None

. . . _...._.. . . ..... None

. . None

. ._ ..........._ None

. . _._.. None .._... .._ None
. None

._..__.._.__ .. None

_....._._ .. . EUG3SD2 

### .__.......__ .... None



### ___._..... .._.... None



### __.._ None



### . ._._ ..._.._ . .. None



### _ ...__.. None



### _..__. .... ....__......_ None



### .._,..._.__.- None



### _ _ ........ ... None



### .._.._.._. .. None 

### .......__..._. None



### .._._.._. None 

### .__. ,. ..__.__...

None



### . None 

### ._..._......... None 

### ..._. _..._.. EUC 4 VDsI

_ ........_..._. _.. ._ .. None

.._._. ._ ......... None

_... _._.. ..._. None

._ ............. ... None

. .......... . ...... None

_...__... ..._._-.... None

...... ._____..... None

.. .._......_ . _.. None

.__........ .... None

. ...._._.._ None

. _ . _..... None -- ..._... . None - ._...._. None _......_...__ None

. . .. _..-_._ EUG4 VDs2 None 

### _.__..._. _ ....._..._._........._...__.. None 

### __.....___. None 

### ._.._ ._. __.. _ None



### .. ............... None



### ....._..._.__. None



### .... ......__._. None



### ....... ._.... ...... None None



### _....__... ......__..___ None



### ...__.__...... None None 

### _..._.._.. None 

### ......._._._... None 

### EUG 5- WSI 11 

### ... None

_......... None

_ . ....__ None

_ _._...._. . None

_ _.._... None

_ .._.....__ None None

.......___. None None

._.._.._._ . None

.. . ...._._..._ None

__._......._. None

. None

. _.. _... None

._.._....._. . _..___._. EUG 5- WS2 

### ._. _. 5.02 6.17 

### ._._...__ 8.00 

### _. .._ ..... None



### ........ . .. ~ Nane



### ....._ . ......_._.... None



### _ , _ 

### .. ... None



### . __... .._._ ._ None



### ..__.._. . None



### . _.__... None



### ....._ None



### . Nane 

### ......_ None



### .. _..._...._ N . 

### . .. __._..... EUG 5-Trim None None None None None None None Nono None None None None None I None NATURE AND CAUSE OF EXCESS EMISSION: 

### (2) The scrubber was shut down for maintenance to do the PbI. PROCESSES AND EQUIPMENT INVOLVED: 

### (2) NVet Scrubber #2 CORRECTIVE ME.ISURES TAKEN: (2) The quench nonles, empenger noi

~ les, and traps were a0 cleaned. Restarted the scrubber.
ADDITTONAL INFORMATION * : The 1Vet Scrubber was ntaintalned and operated accord'utg to the ntanufacture's mstructions. The repairs and mafntenance were done as quickt.v as poss0>le, utSvatg overtime if needed. 

### I certify, based on information and be8ef formed after reasonable mquky, the statements and'mformation m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON



### Date Received: Received By: [kmonmation of Cause Submitted: =Ne AGENCY USE ONLY DateSubmitted: TrackingNumber: Team tD: * if you wish to notify the DEQ about a technological limitation, do so here and attach supporung infonnation. DEQ-Form #100-920 Rewsed February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonst ation of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 2/26/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERIYIIT NUMBER: Muskogee Muskogee 2004-198-TV (M-i) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 2/25/09 8:00AM SUBMITTED: SUBMITTED: 80 Minutes EE ID #, if a licable: 2/26/09 2/26/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages lnay be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous 1ogs, charts, maintenance records, etc). *** (1) The periods of excess ernissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down to for maintenance to do the PM. Cleaned Quench/Impenger nozzles and trap. Restarted the scrubber. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. 

# lim

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# (4)

The facility was operated in a manner consistent with good practice for mmimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant poflution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize einissions. This work was done in order to prevent a 1

- nalfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- 

# --------------- (5) Reasonable steps were taken to minimize the impact of the excess emissions on ainbient air quality. The work was done as quickly as possible to minimize the scrubber downtilne.

----------------------------------------------- 

# (6) Ernissions monitoring systems capable of producing valid data were kept in operation if at all possible. M ,

- - - - - - - - - - - - - - - 

# - — - — - — - — - — - — - --

~ 

# - = - — - — - — - — - — - — - — - — (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

—— - — — - — - — - — - — - — - — - — - — T — - — - — - — - — - — - — - — - — - — - — 

# - TeeTtify, ;a;ed on inf 7

ormation and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Form # 100-922 Page 2 of 2 Revised November 5, 2007

## OKL.AHOMA DEPARTMENT OF ENVIRONMENTAL QUALHY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FOItM 'OTE: The infomtation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous rep ort, provide only the cotrected infomtation below, sign the cenification, and attach a copy of the previous rcpon.
REPORT DATE: COh1PANY NAME:

413l2009 Dal-Itarm NAME OF INDIVIDUAL REPORTING: TtTLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Dnration: 4!3/2009 0:00 0:00 0:00 Hours:Min Phase 1



### 11:10 11:40 0:30 Hours:Min Phase 2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 Hours:Minutes of Wet Scrubber powntinte APPLtCABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 2004-198-T\' (M-1): Specirtc Conditiun 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIAtATE ComplianceTesting X ..__.._._.... -_..--_....._---.... __..._.. .....__._. SOURCE GRP HF HCL SO, CO VOC NOx PM EUGI ......_..-..._. .......__._... .....__.....- _..._.__.._. . ..___.._.__ ._____ .._.__.._..._--. __.__._.. -....__.._.___. ..__._....._...._ .._._-._. EUG 2 .- ............. ............ _ . ........ .-.._..._. __ ..... .

~ . .. . _......_.__ Cont Fmissions Monitoring ._ .._. . ..._.---..__._. __._.. EUG3SD1 ........_ _.. .._._..__ 0.76 _.._..._. 0.00

_ _ ...... _._..... 0.33

..._.._...._... _. ~ 12.24

..__..__... .._._...

_......_--- 4.23 .._._ ___.__ ....... ~ 3.85

... _ --._...._.._.. .. .._...__ . FngmeeringCalculation X _..__.__ ._.-_.._..__.. . _. _._._._. ._..___ ..... ................ EUG 3 SD2

.. 0.27

... -._ 0.00 _.. .....__ 0.00

...._........_ 6.02

.._....__.._ . ...__ 0.92

__.... - -. . . _._. L96

... .._._ .. 2.57

... . .. .. Operating t.ogs X

._..._...-_ _._--- _..._ . ............ EUG4VDsi _.

. . - 0.02

.... . . _._.-.......- 0.00

... .. 0.00

. _ 5.27

. - . .-.. . . __ 0.66

_.-_. . . _.._ t.03

. .._... 2.28

............ - . -... ~ Otha(explain)

.__._..... .___ . . _..___. _.__.. ...._..._.-.. EUG 4 VD s2 0.01 0.00 _.._.... 0.00 _. ... .. _ 3.53

.__.._....- - .. ..__ 0.44

.__..._ . _ . -....._ 0.69

_ . -_ 1.53

.. . . ....... ... . .._ . .. _....- . . .. ._ .. _.._._ . - --..._.._ _ .._ . __.._... . _.-_.._-...... EUC 5- W'51 O.Ot 0-16 .._.._ 0.t8

. _ 7.23

...._........ __.__ 0.47

._. 2.46

. ...__._ - t.46

_-- ___.... . .... - _.._.__ . .. ..... __... ___..__ ...___.__ ........._.._. EUGS-\VS2 .- 2.95

. ..._.-... 3._51

... .._..__. ~ 9.71 ~

. . ._.. ... 6.39

-_ .-_. . .._.. - I.90

__..._.. 2.51

.. _ ....-__ 3A2 _. .-. - .._...... . ....__... . . __...._ ......_._ ___._. EUG 5- Trim 1.65 2.1( 4.70 3.29 0.91 1.28

~ 0.98 ..,..._... .__.....___. . ._...._.... ._..-..._ ....._._..- ALLO\YED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO r CO VOC NOx PM EUG 1 -...___... ...___.._..... ___......__. ~ . .._....___. ._....__.... .__._ .-._.... ...._.....__... .

............ . EUG2 .

....._. - ...-..-. ... __ .-._..__-.-. . .._........._ . ..__._._.__ _..-.-.. .......- .. _ ...__....._ __.._...__._ _..__--__._.......__.. EUG 3 SD 1

.... ..._-..__..._ _._.._._059 -.._.__.... 0.10 ..__.___ ......... 045

....._. .. ,,,.,,_,13.77 ._.__....967
.. .. ... .._ _____,._._. 3.88

. _.__.....- _.. 7.98

.__._..........__..... EUG 3 SD2 ._._............ 0.95

. . - . -....._ 0.90 0.45 .__. ... .- t3.77

. .. ___.. ..... 9.67

._._.. .. .._.-.....__. 3.88

. _.___._. _.. 7.98

_.._..___ _....._.. EUG4VDst ._-.._.__....- .... 0.72

__....__.. ._._._..._. .. 6.0 8 0.18

__.__._....___.......__. t1A3 .___...._ .... ... ........_.. 38.33

-......_.___.. 3.51

.._.._...____ 5.85

.___._...._.__._......... . EUG4 VDs2 _._._.. 0.52
........ _ _ ..... 0.06

.. . ._..._. 0.08

. . .. 5,09

. - . . 17.04

- 1.56

. .....__ . .. 2.60

_ .... _.. __....._.

... EUG S- li'Si

. . _.._..... . ... 1.43

.__...___ ... ._....._. 1.60

._. . ... .. __...._.... 8.96 ~ ~~

. . _.-._-.-._ ~~~~ ~ --19.60 ~ __

.._.____.. ._. ._ .. ......._. ~ 4 78

...._... . ____... 7.73

.. .. . 6.71 EUG 5- W'S2

. ... ...._._.. .._ 1.43

__..._._ _._....__. 1.60

_.. _ -. .__.__. . 8.96

. . _......_.-.. 19.60

_..__. ..__ .. 4.78

........ . .. ._..._. 7.73

. -. . .. .__....__ . 6.71

. .. . ..._._._......_... EUG 5- Trim 3.57 3.88 9.68 1 6.75 1 3.67 2.00 1.80 EXCESS EMISSIONS: (based on 1 hour Omits) EXCESS EMISSiONS: 24-Hr Totals SOURCE GRP HF tiCl SO z CO VOC NOx PM tIF HCI I SO, CO VOC NOx PM EUG 1

... ._... _ _......_.._ . __.. __ .__-_._. _._..__.__. .. .._._.__... . .... .___.. . .._.______ ...._. _.. None ...-....-._ _ ..... ___._.. .... __..__. ..... ....... . ....__.._ .. _ ___....__ None

.. .. ._ ..-. EUG 2

. _._.....,.. ._..__. ._..__.. __ .....__.._..... . _.____..... .._......___ . ............._.. ._......... None _...._.... ..._..... - ..... ..__.___. ......_.__... None _.. ..._.. EUG3SD1

. _.__. ..... O.t7

_... _____ None

__ ............. None

. ...__.__..... - None

___.._....._....._ None

..._.... ..-...-.._... None

...___...__ None

.-..........._... _. None

....._.-..- None

..._._......_ None

._......._. None ._._ None _....__... None

. .._...__..__ None

. ._ _.......... EUG 3 SD2 ._.. None .___..- ..__._.. None

. .. .............. None

_._ _.._....... _ None

..__.__..-. ..._........_... None

.._.._...___ None

....-........_... None

.._.._.._.._..._... None

...-.._.._. None

...._._._ None

__.._..__. None None .__.__........_...._. None ._. Nnne

_._. EUG 4\'Dsl _...-.._.._.. ._ .. None

_._.__.. -._ . ........ None

.......___.__ None

- __ -.__.__. ... _. None

._. -..-. ...__......._.. None

..._-.._..-_... None

-__._..-.._.. None

_....__...._ ._.. None

.__._.._ ... None

....._.__... None

_....._.. None None

-..__......_.__...._....

None None EUG 4\'Ds2 _._....__ .. None

_........._... - - --._...._. None

.... .__...__..._ None

. .-._._ . None

._._. .... - .._._.. None

__..._ _ _.... ....___ None

.. ......._ ........ None

. .........._._. .....__._....

None

.. None Nano

--__._......_. None None ........-.-.._._... None

._..__.__.._... ]unc

.._.... EUG 5- N'SI

.. .. None

. . _....._ . . ___.. None

.... . __.._.. None_

- _ ..._ None

...._-. _. . ...... None

._..._. _._.......-_._ None

..... . .._... .. No 

### ne
. . 

### N one
. None

... ............ None

. None ._. . ... . None

. .-_.._.-. None

... _..__. ... None _. _... ... ELG5-\\S2 ....__ 1.52 .__...._ ~ 1.91 _... ......_...__.._ 0.15 ~

-..._ -.._ .. None

...___._ . -_ _.... None

-._._.-.._.... None

............ None .._ _...___.... - ..._ None

. _._.._..... None

_...__.._. None

__...-.....__ None

... None _...____.. None .._......-....... None

._....._...... EUG 5- Trhn None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The no -

r,les were cleaned and the scrubber was restarted.
ADDITIONALINFORMATION*: The W'et Scrubber wwas maintained and operated according to the manufacture's mstructions. Tbe repairs and maintenance were done as quickly as possdtle, ut0iring overtime if needed. 1 certify, based on information and betief formed after reasonable inqulrp, the statements and information in this document are true, accurate and compiete

SIGNATURE OF REPORTING PERSON

Date Rcceived: Reccived By: IDemonstrationof Cause Submitted: O No AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: e` If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Rewsed February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — I)emonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/6/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/3/09 11:10AM SUBMITTED: SUBMITTED: 30 Minutes EE ID #, if a licable: 4/6/09 4/7/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt froln compliance with air emission lilnitations established in perinits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down to clean the nozzles. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- 7 --- - - 7 

# - - - - - - - -



# (4) The facility was operated in a manner consistent with good practice for mmimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

------------------------------- 

# *"% --------------- 

# (5) Reasonable steps were taken to ir6nimize the impact of the excess emissions on ambient air quality. 

# The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. 

# M IT.

------------------------------- ~ 

# -= ---------------- 

# (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

-— - — - —



# in — T —



# st - — - — -



# i — - — - — - — - — - — - — - — 

# _ U 7 easonable quiry, the atements and nformation in this document are true, TcJtFfy, 

# ~ a;ed on mformat 7 ion ar 

# ~ d Teli;f For e af 7

ter r accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Fon - n # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AtR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The informatlon requested below should be submitted to the address above within 10 working days aRer the immediate notice is given. If you are using this fortn to cmrut a prevaous port, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COM PANY NAM E:



### 4l1012009 DaNtaOa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: 

### DaHtatia Muskogee 2004-199-TV (M-1) DATE AND TIME OF EXCESS EMISSION: 

### Date StartT'ime: StopTinte: Duration: 4/712009 9:45 I0:45 1:00 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:00 Hours:MinutesofWetSerubberpown6me APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: 

### Permit No.2004-198-TV (M-1): Specifie Condhion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE 

### ComplianceTesting X .__.__.._.. __..._._.. . __..._..._._ SOURCE GRP HF HCL SO i CO VOC NOx PM 

### EUG 1 .._ ..__.. . .._.__.._ _.._...._. ._...._._.._.. .._...__.. ........... . ...__._....... .. _._......___. ._...._.___. ..__.....__.. EUC 2 

### .._.__..._.. .,._._.___ . ............... ......__ ....__.__.. _..____. .....__..._. __...__...__. ._..__._..._...... __ ____.. .. .....__. Conf Fmissions Monitoring 

### ....._._....._ _._..__.... _........___..... .._._... EUG3SD1 _ 

### . ._ .. ........... 039 

### _... 0.00 _ 

### _ ..._..._ . 0.17



### . 6.30 

### __..._..... .. .... 2.17



### ._... ....___.. 1.98



### .....,___.. ......_ 3.93



### _. ... . __.... Engineering('alculation X 

### .__. ._.__ ......_.....__._ _._......_... ...__.__...
~ 

### EUG 3 SD2

. . ._... _.. .. .- 0 i8

_ _ _ . ... _.._ . . . . . 8.52

.......... . 1.31

..._.. . __..._... 2.75

.. _.. ..__ ... 3.64

_ _ _. _._ _ _ _. O 

### per ~ 

### i i„ 1 nGS X

._-- ........__ EUG4 VDsI



### ... . .._. _. ~ 0.03 

### _..__._.

._..__.. 0.00 ~



### .. ~ 0.00



### . .... .. ..... . . 6.92
_ D.87
_ 

### ..._.._.... 1.35



### . 3.00 

### .._.._

....__..... Other(explain)



### .. _._ . . _.......__.. ..__.._ _. . . EUG4 VDs2

. . .--- . 0.01

. . .__

_.. 0.00

_ _ . . 0.00

_ . . . ~ 

### 3.41 ~



### .._......_. ~ 

### 0.43

. .. . .._.._.. 0.67

. . . ._.. . 1.48

. _ _....__. . . _ _._ . . -__..__.. _...__.... . .....__.........

...___. _.. _......_._.. EUGS- \VSt 

### 3.38

.. __..._ 4.03

.. . . ....._.._ ~~ 

### __ ~ 

### 11.15 ... _ . ...... ......_..,..

7.33 - ~-~-~~ 

### 2.18

.. .__ ..... 2.89

.. ...... _ 3.92

............. .__. ....___. ..__._.__ ...__...__.. ._____...._.

.._....._..__ EUG 5-\VS2

_ . .. .. 0.00

. _ O.OI

_.. .__.._. 0.02

. . . _ . . 14.1-5

............... .... 2.37

. . . ....._.._.. 4.56

. .... . _ 4.16

. . __........__ _....__...... __ ...... 

### .._ ... 

### Et1G5-Trim 1.32 --- 1.69 3.76 2.63 - ~ ~-~ 

### 0.73 1 1.02 0.79 ALLOWED EMISSIONS: 

### Attach supporting data SOURCEGRP HF HCL SO, CO VOC NOx PM EUG 1 ....__._ ... ...... .....__.... _._.__... . _...__........ ......___ .. ........._..... _._........ ... _...____.. .. . ._ _._...._ . _ _._._._.._...___... EUG2



### . ....___._ ..__. .__._.. .. . _ __..._.... ._.,._._._...._ _ ...._ .__._.... ._ . ._._,.__... _....._..._.__. 0.45 ... ._ ..

. _ .. ..... 17

... ,77 ..... ......... .. . 9 67

. ...__.. _.. ...__.._...... _ .... 3_._

88 ____ _. .

_ ._.._..__.... .. .._ ..._._.. 8

.__.._ _7.9

................ EUG 3 SD2



### . 0.9i

__ . .,.... 0.90

. ._......_ . 0.45

._._. . .. _..__ 17.77

.. 9.67 3.88 .._..__ 7.98 ._....._... EUG 4VDsl 

### 0.72 ~



### . _ .. .. 0.08

... .. ........... .. 0.18

... .... _ .. 11.43 38.33 3.51 5,85 _..__.... EUG44Ds2



### . .. .. . _. 052



### ..._._._ . . _ __.... 006



### . . _ --_...,... . O.OR



### _..__ .. .. . ..._. -_ _ .09 .__..

. .__.._. _ _..__. ._. _. .17.04 ~ ~ -



### ._._ . .. . . .. _ _... 1.56 2.60 

### EUG 5\VSl ._.._._._._. ... 2.14

..-._.._ .._.__.__... 2.40

_ .........._. . 13.44

.. . ._. 29 40 7.17

...... _._..___ 11.59 10.07

. _ .__..._..._. _._...._...__.......__._._... EUG 5-\VS2 ._ ......._... .. ._- 1.43

-...._... .. ..._..___ 1.60

_ ............... S96

....___. . .. 19.60

_._.......... ...._._._..._. 4.78

. _..._.. _...... 7.73

..........____ ... 6.71

_ ...__.._._....__....... EUG S- Trim 3.57 3.88 9.65 6.75 3.67 2.00 1.80 EXCESS E611SSIONS: based on 1 hour IimNs EXCESS EMISSIONS: 24-Flr Totats SOURCE GRP HF HCI SO i CO VOC NOx PAI HF HCI 1 SO z CO VOC NOx Phi EUG I 

### _._.._...._ . ._ .._.._._ .. _ _..__..._.. . _ ......_._..... ..._._._.._ ...._...... _._ ._._._._..... . ......._.__._. . None



### . . _._..... _ _ . ._.__.. . ...__... _..... _. .___... _. .__.._.. ..____...__ None 

### _..__.__... EUG 2



### .. None 

### _........_._.. . . ._.._. ....__... _._..__ ._. .. _ _ None



### ... .... 1:1'G3SD1



### .... ... ._._. None



### ._.__ ._..__._ None



### ._... _ ._.._ None



### .. _....._.._._ None 

### ...._......._ None



### ................. None



### .. .. .._....._ . None



### ......._.._...._...... -. None



### _._.._ None



### .__..._.. None 

### .._ ...___ None 

### _. ........_._.....

None None 

### _....._.._._ None



### __.__....... ta'G 3 SD? None

.. ._..___._ None

_ . ..__. __._.... . None

. ...... .._. _ .._ None

....__._ _ . . __. None

. . .....__.___ None

......_.__._.. . None

... ...___ ..... .. .... . None

........_ _ None _ _ _......_... None

...._.._.. None .._ .. . None

. . None ._....._.._._ . None

. _........ EUG 4

~ 

### l)sl .._ . _.. . None

.. _._.._.._. None

... ... _....._... None

. _ _. None

. ._.__._. . .._. .._. None

...._. . _.._._.._... None

....__...._. None

_...__.. ......... None

_._ .. . None

. .. ......... None

... . ..... .... None

... ..... None

.......... None

....._.__._ None ...._....___.. EUG4\

~ Ds2 

### _._ _...._... _.._ None



### __..._._ ... ._.._.. None



### ... ___ .......... . None



### ........_......_ . None



### _.._.._._. . ............_......

None



### _ _. _....._ None



### _. _._ ......._ None



### ._.__..... ._ None



### __._._.. ._ None 

### ._._. _. .. None



### .._..__._..... None 

### ,..._.__._ . .. None



### . None 

### ._.._.._. None 

### ,. ..._...__ EUG 5- WSI 

### _. ....._.._ .. 1.24 

### .._. _.. 1.63



### .. ............. None



### ........_.... . None



### _._ .._. . _. None



### ..... _ .. __... __.._ None



### .__. _.....__. . None None 

### ...__._. Nono 

### ...._._..__. None 

### _..........__ None



### ... _. None 

### ., None



### ......_..._. None 

### ...._.___. EUG 5- RS2

. - None None

... ._ .............. None

......._..__..... None

._.._ .. . . _..... None

.._. _ .. _._..__.. None

. . _...._.._... . tione

...._...__.._. ......... None

..__... _ None

.. ._..__... None

. ......_..... None

... . _ None .._._.__.. . None

__...._ None ..._.._,....,_ EUG 5-Trim I None None None None None None None None None I None I None None I None I None NATURE AND CAUSE OF EXCESS EMISSION: 

### (t) The scrubber was shut down to do the PM. PROCESSES AND EQUIPMENT 1NVOLVED: 

### (1) Wet Scrubber#I CORRECTIVE MEASURES TAKEN: 

### (1) Instalted a new bleed line and quech preuure swhch and restarted the scrubber.
ADDITIONAL INFORMATION*: The \Vet Scrubber was maintained and operated accordktg to the manufacture's instructions. The repairs and mahnenance were done as quickly as poss8tle, utilimtg overtime if needed. 

### 1 certify, based on information and be6ef formed after reasonable inquky, the statements and information m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON



### Date Received: Received By: Demonstration of Causc Submitted: =No AGENCY USE ONLY DateSubmitted: TrackingNumber: Team ID: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. 

### DEO-Form #100-920 Revfsed February 8. 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it inay be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/6/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/7/09:4509 9:45AM SUBMITTED: SUBMITTED: 60 Minutes EE ID #, if a licable: 4/8/09 4/8/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt frozn compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to install a new bleed line and quench pressure switch. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Fonn # 100-922 Page I of 2 Revised November 5, 2007

# (4) The facility was operated in a mam m er consistent with good practice for mimizing einissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

--------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the iinpact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

— - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — 

# (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. LM
------------------------------- % - = - - - - - - - - - - - - - - - - 

# (7) The owner or operator's actions during the period of excess enussions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtirne and the work done.

TC e - r t 

# i Ty, - b a s

— e d

- o n i

— n f

- o r m
— a t i - o n
— a n - d b — e I i e

- f f

— o r m - e d

— a ft - 

## e r
— r e a - s o n
— a b - I e i

— n q - u i r

— y, t - h e

— s t a t - e m
— e n t - s a — n d

- i n f

— o r - m a t — i o n - i n

— t 

## h i

- s d

— o c u - m e
— n t - a r e
— t r
- u e — , accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised November 5, 2007

## OKLAHONiIA DEPARTMENT OF ENVIRONMENTAL QUALRY AIR QUALFTY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM 'OTE: The infonnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the corrected infonnation below, sign the certification, and attach a copy of the previous reporc.
REPORT DATE: COMPANY NAME:

4/102009 Dal-Itafia NAME OF INDIVIDUAL REPORTING: T1TLE: PHONE: Ed Smart Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS BMISSION: Date Start Time: Stop T;me: Duration: 4/102009 0:00 0:00 0:00 Hours:Min Phase 1

12:15 12:40 0:25 Hours:Min Phase2 DURATION OF EXCESS EMISSION (tIOURS:MINUTES): 0:25 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-19&TV (M-1): Specifk Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE Co mplianceTesting X ._. _.. __...._ 

# _-.. SOURCE GRP HF HCL SO i CO VOC NOx PM EUG 1 .___... ... ._....._ .....____ . . - .._..-._ .... . . ........ . ..._._._.. .__._ _._ ... ............-_ . -- _..... -- _. .. t:UG2

.. .........._ . ....._..___ _. .... _...__.... , ....__..__ _. _......__ . .............._ ..._..._._._._ ~-~~-

.. ....-._...._. . . - ~ -- ~ -

...-.._..__.. ...... ContEmissionsMonitoring

_..__.. .._...._..__ .___.__ ..._.__._... . .._...... I(t'G3SDY

_ OAO

_ . _._.._._... 0.00

.__.....__. 0.17

.__....._ 6.51

_.__._... .___...... 2.25

.._.._..._._... 2.04

_._._._ _. 1.06

.. _._._..__. EngineeaingCalculation X

._.._.. ._......_ ._._..__ ..._....._. EUG 3 SD2

. . _ 0.18

. ._.._....._. 0.00

. ..._.__._ 0.00

..._.._ 4.08

_......__._ ...._ 0.63

..._ . ............_.._ 133

... ....._..._... ...._.-...._ 1.74 _-_.. Operating Logs X ._.._... ._..___.. ._____..... ............. . .....___.._. El'G 4 VDsI
_ 0.03

. 0.00

_._._.. 0.00

_.. .. . _ 6.18

__..__._. _._....__ 0.78 ._._._.... L21

_.. . __-_ ..._ 2.68

. ......._ Othcr(explain) _ ............ ...__.__._. ._ _... ._..._.__ ._____

~ EUG 4\ Ds- ~~ ... _..___.

0.01 ~ _..__.. 0.00

- 0.00

.... 3.50 .____..._.. 0.44 - ..._...___ 0.68

... ... _ ~ 1.52

_ .... __... _........ ...._._._... __.._____ . _.. ...__._... ...__.__._ EUG5-RSI

_ ._.. .. 0.01

___.. ..._.._

- . 0. 14

. .. 0.16

.__.. -._ 6.25

_._...._. ___._ 0.41

_ ._._ . .........._ 2.13 ~

. -.... . 1.27 _.....__._ EUG5-\VS2 ...._...._ ..._ 2.21
_ ..___.. 2.63

....__.... 7.27

. _... . 4.78

._.__._ 1.42 -....._._ ~ 1.88 ._ .... 2.56

...__..... .,._... ..__._... ...__.__._. _. _.__..__.. ...__..._..-_

.___.. EUG 5- Trim 133 1.70 1 3.79 2.66 0.74 1.03 0.79 Attach supportbtg data ALLOWED EMISSIONS: SOURCEGRP HF FtCL SOz CO VOC NOx PM EUG 1 .._.... -. ..____. ___..__._ . . .._. _...._. __-._._ _.. _._._.__ __..._._ . .__._._._ _...__._.. ...._...._....._._.____. EUG 2 - ..._ _ __._.....-. . . _..__..__.. _ _ . _ _ ._.._._.... ._ ......... .........._.__ EUG 3 SD t . ..._..._ ._ . 0.59

....._.. . _..__._ O 10

.. _._.___._. . , 0.45 77 , t3 9 67

-.- ....____. 3.88

._......._ 798

........_._ ......_...... EUG3SD2 __.,_.__. .. ... 0.95_,...._....

........... , 0.90

.__......._ ......_..

OAS

__ ... _ ,. _13.77 ._...

_ . 9.67

_ .._ ._.__.._. 3.88

...-_._....... ..... 7.98

__............__._._. EUG4 VDsI

......... ~ ._ . .............._. 0.72 .__...... 008 ..._____._. 0_IS

_ - ... 11.43

_._... ..._..__ 3833 3.51 ._..__._._ .. 5.85

...._..-_...__.__.__.... EUC d VDs2 ._......_._ _.. ..._.._.... 0.52 ....._._.. 0.06 __..___.._ 0.08

. .___.___... ...._...__....

5.09 ..___..._. 17.04

..._._..... L56

..._._.._. .... 2.60

......___....____._. EUGS-WSt ....__-.._. ....._..._ 1.43 _.._.... 1.60 ...._...__._.. .._. 8.96

._.. 19.60 _...._.._. ..__.__.._._ 4.78

.....____.._. 7.73

....._._. 6.71

__.._..._...._....-_._.. EUG 5- WS2

, ........_. 1.43

_._._.. ._........_._ L60

....- _ 8.96

.-_ 19.60

..__.__._ ..----_.. 4.78

_._ .-....._ .. . ... 7.73

. ............. 6.71

__......_.... .............._ . EUG5-Trim 1 3.57 3.88 9.68 1 6.75 3.67 1 2.00 1.80 EXCESS EMISSIONS: (based on I hour Omhs) EXCESS EMISSIONS: 24-Hr Totats SOURCE GRP HF HCI SO, CO vOC NOx PM HF ttCl SO t CO VOC NOx PM EUGI __....... ..._.... __.._.. . . ..._. . . _._._._.._.... -_.. ... ............._ None .....__.. .. .._.__... . _-..__._. _ ....._.__- ___........ None

...... .-.___... EUG 2 .__......_ .___.. _.._.._._.- _._..._....._.. .....__...._..... ..._ .............._._.__- ..__._._._. .. .._.._.__... None ._..._.__. _...... ....._... . .._._..__._........ . __. None ___.. EUG3SD1 _._... None

......__ ._..-.__._ None

... ....__ .._... None

.._---_.._... ......__..._ None

... ............ None

..__. .... ._.....-.. None

... .-_- ...__.. .... None

.._....__. .. None

_........ None

......-_...__ None

....._...___ None

.. .____.. None

.._.... ~ nne _._.. None _._..... EUG 3 SD2 .....___ None

...___ . __.-.._ None

_ . _... __....._ None

...__._......_- . ... None ._..._._. None _..._ _.... . ._..__. None

.. .... ....__. None .__.. None .___. None

....._._- None

..._..-__. None _._._.. .~ one None

.._... _ None EUG 4\'DSi __.__._ ..._ None

.._.__.__. None

.. ....._...._.. None

....__ . None

_._.._..__ ......__.. None

...._..... .......__._ None

. _ ....__..._ ._._. None

...-. _._._. ._.. None

_.._... None

....._....._ None ._....._ None

. ~ 'mre '\one - None - -._._.-.... EUG 4 VDs2

... ._. None

- _ ._..__..__ None

.. ................. None

.....__.... _ None .__... None ..-_ _...._._.... None

..._.....__ None

. _.._.._.... _..- .... None

_.._- - None ...._.._....._ None

.___....... Nooe

. _ .... .. ~

Noue ...- . Nune

._.....,_...._. None

. .._.-.._-.__ EUGS-\\'SI _. . . None

_ .. _..... None

.. . . _._. None

__. ....__ _ None

.. . __.... None_
_

..__ ...__..... . None

.._...__._ None_

_._ .. . .. -_ None

.__.._ . . None -. _..._._. None

........ None ._ . None

. None

. None EUGS-w"S2

. .. . . 0.78

.__ ...-- - 1.03 None -_~ . _None

- -. None

_ .___..._.. None _.. None ......._ _ ........... .. None None

... _._..__ None

.........._.. None Vone

...

._ None None EUG 5- Trbn None - --_ None None ~ None Nono None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The serubber was shut dmvn due to a malfunction caused by a motor ovorload. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber 92 CORRECTIVE MEASURES TAKEN: (2) Reset overloaded motor, checked current, and restarted the scrubber.
ADDITIONAL INFORMATION*: The 1Vet Scrubber was mafntained and operated accorditg to the manufacture's instructions. The repairs and maintenance were done as qufckly as possible, ut8'v'mg overtime if needed. I certify, based on information and be6ef formed after reasonable inquiry, the statements and information m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: ONn AGENCY USE ONLY Tracking Number: Team ID: Date Submitted:

' t )f you wish to notify the DEQ about a technologicat limitation, do so here and attach supporting information. DEQ-Fam #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for Malfunctions OAC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be subinitted with their quarterly report. DATE: COMPANY NAME: Da1-Italia 4/16/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/10/2009 SUBMITTED: SUBMITTED: 12:15 25 minutes EE ID #, if a licable: 4/13/2009 1 

## 4/16/2009 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due to the sudden malfunction caused by a motor overload.

This failure was not reasonably preventable. (2) The excess emissions did not steln from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Form # 100-921 Page 1 of 2 Revised Noveinber 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable ei

- nission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

— - — - — - — - — - — - — - — - — - — - - 7 -- - — - — - — - — - — - — - — - — - — - — - 7 --- 

# (5) The ainount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to niinimize emissions.

-------------------------------- --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess einissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of producing valid data were kept in operation if at all possible. WMA

----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.

7
- 7 ------------------------------------ 

# (9) The excess emissions were not part of a recuning pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recurring pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALtrY AIR QUALffY DIVISION PO BOX 1677 OKLAHOMA C(TY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: T6e infomiation requested below should be submitted to the address above N+ithin 10 working days aRer the immediate notice is given. If you are using this fomt to cotrect a previous port, provide only the com;eted information below, sign the cenification, amd attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

4/10f2009 Dal-ItaBa NAb1E OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Pbtnt Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-ItaBa Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 4712l2009 8:00 8:42 0:42 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:42 Hours:MinutesofWetScrubberpowntitne APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-t98-TV (M-1): Specifx Condhion 1, EUG 5 ESTIMATED EMISSIONS: BAS1S OF EST(MATE X ,Compl

~ anceTesting . _.._.. . -._...._.. _ ..._._ . _ . .. .. ___._.. SOURCE GRP HF tiCL SO s CO VOC NOx PM

. _EUG I - . . .. . _...... ....._.. _.. __.._.... _._... _ .._.._..__ ..__. ___ _.__..._._ _.._..... . .. _ .. _....._... ._ __ EUG 2 ____..-._. . ..._..... ._____... _ _._._____. _.__...._.. . _......_ ...... ....._ .._._._._._. .._._.._._ ..._._.__..... Cont Emissions Monitoring ._._....___- . ..,_.__.._.. ._.__.._ ._._._._. ..._.._......,.. EUG 3 SDI __._._.... 0.42

......__.. ._____... 0.00 .._.__.. 0.18

.-..__... 6.82

___....__ 2J5

_._. ....._...._.._ 2.t4

..__.._.. 4.25

_...._.._.... _. Engincering Calculation X

.._...._ . ._.__._._ . __.__ __....._. ..__... _._.. EUG 3 SD2 .._ _ __.. ._ .... 0.20

_._._... . ...__.... 0.00

. ...__..__._ 0.00

. ._..__.. 4.39

......._. _._. 0.67

._._ . _._._._-._. 1.43

.. _ .... -.-_..._. _ 1.88

.. .___..._.. ._ .. Operating Logs X

__.__.. ... ...... .._...__ . _...._._. .. . ..__._.. _......... ECG4VDs1 0.03_
_ 0.00

..... ...._._ 0.00

.. 6.05

...._.. .._._.._... 0.76_
_

. . . 1.19

._ . ._. .. 2.62

._ ._..__. ... ._ Other(c+cplain)

_..._._. ..____ . .._._...._ .. ._._.__ _ EUG4YDs2 0.01 0.00 0.00

..... ._ 3.29

.._.___.. _ OAI ~ 0.64 1.42 _......__ ._...__.... .__..._..._... __._.____ ....._____.._ _-___ ...._......_. - ...__..... 7.54

. . . 4.96 ._._-

. _ ... - _._._. .._. . t.47 __._.

_... . __...._. .. t.9$_.

. _. ..... ._.._..-2.65

. . . ._ EUG 5- WS2_

... . .

- ~ . ... 0.00

.............. 0.01 ._ ...... ~ 0.02

. 13.73 .___.._ 2.29

__. .- .. . 4A2

__.....__..__. ~-~ ~ 4.03

_.. .. ...._.._. _._.._..- ...._____ .. __-_-_.. EUG 5 - Trun ~ ~ 1.59 2.03 ~ ~ 1 4.52 3.17 0.88 ~ 1.23 0.95

.......... ......._.. ...._... _._..__- .__...__.... _.._ Attach supporting data ALLOWEDEMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM1i EUG l ._ .___. _. _ . _ _.___.... .

........... . __._._.._. _ -_-__._.. .____._ ._._._. _ .. _..-.....___ ._ ._..._ .._. ........___._._._.___. EUG3SD1 ...._._.. 0.59

- _ . . _ .._._ 0.10

... ..._._..._ 0.45

.. . _ _.... ,.,1377

. _..._ 967

.._... . _ . __._._.. 3
. 88

.. . .. . . . 7.98

.. ...__ _ _....__. EUG 3 SD2

. 0.95 ..._.._. 0.90 ..._-.__. OA5

. . . .. 13.77

....... .___ 9.61

___... . ....._. 3.88

. . _ _ 7.98

.............. _._.__..._ EUG4YDs1 ...._...._.. ... _.._.__ 0.72

_...___.._ 0.08

... ............. 0.18

._.__._.. .....__........ ~ 11.43 _._._. 38.33

__.. .. ._.._.....__. 3.51 ~

. .._.. . S.SS

___...... .._..__..__.. , BUG 4 VDs2 O.S2

.. . . ._...._._. 0.0 6

_ 0.08

..... ..... 5,09

_._._ _....._ 17.04 1.56 ....__..__ EUG5 \kSl . _ 1.43

- --.. 1.60 ~

.. -- -_ __8.96

. . . 19.60 .__- 478 ~ ._... . 7.73

_. . _ ____6.71 EUG S- WS2 1.43

- - - - 1.60

_ ...__... 8.96 ~~~-

_.... .. --..... ~ 19.60

. __.. ....... 4 78 - ~~~-~~~ ~~

............ 7.73

_. -. ... _.-. ~~ 6.71

~~~~~ - ~~ - ~ -

. ____.._ ...__..._-_ EItG 5- Trim 3 57 3.88 9.68 6.75 9 67 2.00 L80 EXCESS EMISSIONS: based on I hour liniBs EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx P81 HF HCI SO s CO VOC NOz PM HUG 1 ..._ .._. _ . ........... ... ___.___. ....__..._. .._..._.... .... ...._. ._._._._._... ._____ . None

.. ._._..._.._ __.. __._._ . ...... __.__. ...._._. __. . .._ ___..._ _______. None ...._._.._.. ........_ ____..... ........____. ......_ ...... . ........ ...._ __... .._._____ . ..._._..._. ,None

. _._.. _.__. ._..___.__. _..__.._. _. ........__. . . _..._. None __.._..._.. 

### EUG 3 SDl None

-...._.. ..___. None

. ...._-..._. None

.. ._.._. ._. None

. _

..__ _ ......__.. None

.__.._.__.. None

. ....___._ .. None

- .....- .... ...... None

.......... None

._._... None ....__.._.. None

.. . _ None ....._. . None

... -._..... _None _. . _..._..... EUG 3 SD2 ._......_ _._.._ None

.. ._._... None

_ _.._.....__.... None

-_.._... None

._..._... -.....__ None

.... ........._... None

._ ......_...._. None

- __ . ........_...,

None None

........... None

.,........ None None

.. ....._....._.... None

......-....... None

._....._._... EUC 4\'Usi None

....... None

.. . ......._..._... None

........._. ..__._....._

None

. ....._. None __.... .._...._..._. None

..._.__..... .. None

. _...._...._. _ None

._..._. None _._...__..... None

._._._ None ._ .. None

............ . None

.. None EUG 1 YIls2 _...-_. ...... _ _ None

.. ........... . __._.._ None

._ .. .._.__....._ None

. .__.....__.. _ .. None

_ _ _._.. __. None

_._.. . . .. ._..__. None

.. _....._._._. None

........--.... ....... None

_._.. _ .. None

..... ..... None

...__..._. None ._. .._ None ___..._.. None

. None

..._..... EUG 5-AYSI ._.._... ... 0.86

._._.._.. _....___ 1.12

_. _ ....... None

. .......... ..._ None

__.-........... .._.. None

....._ . ..._.._....__ None

...._._. None

. _ _. None _........ _.- None

.. -..._ ..._. None

..__..,_ None .._. . _. None

_.._. Nunc ._. .... Aone

..._..._..... EUG 5-WS2 ..._. _. .... None

._.._-._. . _._.._.._ None

........_ None

._.._..._...- .. None

._._..._. ........... None

.._.. .._..._..._._. None

....___....__ . None

.. - ..._.._ - .__ None

.._.._.._... None ........__. None

. ........_.. None .._ .. _. None _._.-__.._...._.._

None

.. _ None

. . ...._...._.. EUG 5-Trim None None None None None None None None None Noue None None None Nono NATURE AND CAUSE OF EXCESS EMISSION: (1) The serubber was shut down due to a malfunction caused by a power spil:e. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet ScrubberRl CORRECTIVE MEASURES TAKEN: (1) Rest gas valve on kiln, reset dampers on scrubber, restarted the scrubber.
ADDITIONAL INFORMATION*: The Wet Scrubber was maintained and operated accurding to the manufacture's instructions. The repairs and maintenance were done as quickty as possihle, util'ving overtime if needed. 1 certify, based on Informatlon and be8ef formed after reasonable inquiry, the statements and information m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Receivcd: Received Bv: jDcmonstration of Cause Submitted: ONo AGENCY USE ONLY TrackingNumba': Team ID: DateSubmitted: 'k if you wish to notify the DEQ about a technologicai timitahon, do so here and attach supponing information. DEQ-Form #100-920 Re

~ vised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause laeport Form

for Malfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COIVIPANY NAME: Dal-Italia 4/15/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IIYIMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/12/09 8:OOAM SUBMITTED: SUBMITTED: 42 Minutes EE ID #, if a licable: 4/13/09 4/15/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air einission limitations established in perinits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e, contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due to the sudden malfunction caused by a power strike, dropped out kiln This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing elnissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Fonn # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were madc as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtii
- ne as needed.

— - — - — - — - — - — - — - — - — - — --- 7 -- - — - — - — - — - — - — - — - — - — - — - = - — 

# (5) The amount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minimize eniissions.

------------------------------- I'% --------------- 

# (6) Reasonable steps were taken to ininimize the ii

- npact of the excess emissions on ainbient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of producing valid data were kept 'm operation if at all possible. LM. ,


# ----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
7 - 7 -- — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — 

# (9) The excess emissions were not part of a recun

- ing pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recuning pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: 17te infonnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. lf you are using this form to correct a prevdous eport, provide only the corrected infotmation below, sign the certification, and attach a copy of tlre previous report.
REPORT DATE: COMPANY NAME:

4t17f2009 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dat-Italia M uskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Tinte: Stop Time: Dttration: 4/15l2009 0:00 0:00 0:00 Hours:Min Phase 1



### 9:30 11:30 2:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 2:00 Hours:MinutesofWetScrubberpowntime APPLICABLE LIM1TATtON(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198•TV (M-1): Specirw Condhron 1, EUG S ESTIMATED EMISSIONS: BASIS OF ESTIh1ATE ComplianceTesting X __..._. ...___. ......_ .____ ............ SOURCE GRP HF HCL SO i CO VOC NOx PM EUG 1

_ _.. ...._ ___ .......__._. ....._...._ ._ _...______. .. .._.___ .._... __. .__........_... ..._._._. ...._....._.. ..._ FI'G 2 ........._. .. .__.......__ . _.._._._.. _ ._.._.. _ _..... _... ._._...._.... ....._.._... .. ...._....._... .__ Cont Pinissions Monitoring _._._. ....._.. _.....__. . . . _..... ._ ..._.. Ia

~~ G3SDt

. _ . . 0.41

.............. 0.00

.. ....__.._..._ 0.18

.._..._ G.53 2.29 2.08 4.t4

. _ EngineeringCaladation X _...._._ __._.__ ..._._.... ......_..___ _. . El
- G 3 SD2

.. . ..._.__.. 0.15

__..__._..... 0.00

.___._._._... 0.00

._._.......__ ..____ 3A3 0.53 _.__...._._ ..... .......... 1.12

.. ....___._.__..__. 1.46

_.. ..._-._.. Operatin_ Ia

~ „s X

._._.. .. . ______ __......__.... ._.._._.. _.._. . EUG4VDst

. .. 0.03

_ ........ . . ..._.. 0.00

.. . ......._._. O.OD

..._ ... . . 6.d0 _. _0.81 . _ _. . .. . 1.25

.... _. .._.._ _2.78 .._

......... Othcr(cy

~ lain)

.____.. .. . . ... .._....._.. ..........__....._.._.. EUG4 VDs2



### _ . 0.02 0.00

.. 0.00

_ _. _.... ... ~ 3.6t

_._.__._. ~ 0.45

.__. ._..... _. 0.71

.. ......._ L56 ._.., .._.._... __.._ ....._.._ _____.._.. _._.._ ...... .......... _._. EUGS-1VSI

. .._ _. O.Ot
_ 0.16._._. .. 0.19

.... _ 7.53 _..___..._..

_ ....._ 0.49

.._... ..___... 2.56

....._.. __ ... L52

._.... ... __ _.__._. .._.._._....... .. _._ _.._.. _...__ .......... EUGS-1VS2

.. ... 11.87

__.. 14 ._._

.13 39.08 ~

. ~ 25.71

.

. _..... ~ 7.63

..... _ _._._.__ 10.12

_ ._ _.. t3.76

. ......__... .. ~ .__.__ . ...._ _ ___. . ._......_. ._._..._. EUG5-Trim 1 1.21 1.55 3.44 2.41 0.67 0.94 ..... ~ 0.72

........... ...._.__._ ._..__.__. . ___._.. ..__..._. Attach supporting data ALLOW6D EMISSIONS: SOURCE GRP IiF HCL SO i CO VOC NOx PM EUG I ...._..... __ ....._._._ .. _....._..... ...._.._._ . _..-_-... . ..._.____. .. .___.. ___. , _..__....__... ...__...._ ................._..__... EUC2 .._. ._....._. _.......... ..____.. ......_...._ _.....__.. ..._..._...._ _...__...... ..._.______.___._... EllG3SDi -_ . 0.59

.___.._ 0.(0

.. . 0.45

. . . . _13.77

_ 967
_ .._. ... _ ......... 3.88

..... _.. 7.98

.... _ .. , .......__.._ EUG 3 SD2

.. 0.95

._..._. .. _. ... 0.90

_ 0.45

_ .. 13.77 9.67 ..__ ........._._. 3.88

. _... 7.98

... ...__...._ __.___.. EUG4VDs t 072 __.

. ....._. Q-pg...--..

_ 

### -. "
. O.IS

. .... 

### .___- 1L43 .._. _. _.. 3843

..... . . . ~ 3.5t

.... ... 5.85

_. _ __.__.. EUG 4 VDs2

_ 0.52 _..._.._._ 0.06

.. .....__._. 0.08

_._........_. _. .. _. ~ 5.09

._. .._._. .. .__ ..... 17.04 .__ .. .. ......_....... 1.56

. __....._.. . 2.60

......_._._........_.... EUG 5- WS I

... 1.43

_ _ . .. ......... 1.60

. 8.96

. _. . .. 19.60

. 4.78

. ._....._.. 7.73

.. _. 6.71

...._...._.. ..___... EUG 5- WS2 4.28

.._. ._.__.._. 4.80 26.88 ..._.._ _..._..__.._

58.80 I4J4 ............._... 23.18 20.13 .........._... ...._... EUG 5- Trim 3.57 3.88 9.68 6.75 3.57 2.00 1.86 EXCESS EMISStONS: (based on I hour 8mits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO z CO VOC NOx PM FIF HCI SO_, CO VOC NO: PM EUG 1

.. _..._._ .._.. ._._.._...._.... ._._... .. _..___.. ... . ...._. ._.__. None

. ___._...... . ._.. _.__. _ ..._._. . ..._._ _ ,.._ ... .__. _ ......._.... None .___......._. E11G2 _.._.._ _._..__.... ...._..._. _.._.. _._ . _.__.._ ..____..__. _.____....._. . ...._...._.__ . _Nono ._ .......... None

.. ............ 

### EUG 3 SD1 None

.___._._... None

..._._.._ .._...- None

_ .. None

-- ~~ ~ -...._.. None_ None

. .......... .. None

_..__._._. .... None None

~ one None None None None EUG3SD2

... _.... _.. None

... _.. _.._ 

### __ None

__...._._. 

### None ..__._ . ~ None

._.__.__ . _._._. None

_..... . __._...___. None

..__.._._.... None

.............. _...__ None

............_......_ None

._. ~ one ~

_ _..._ Nono 

### None ._....__ 

### IVonc

..._...__. 

### None

.__.._..... EUG4 VDsI

......... ..._.. None

_ .. .. None

..._._..__. None

_ . None

.... ........... None

_.._......._._..._. .. None

.. ..._.._._.... ......_._.........

None ..___ None

.__.._....._. None

... .. .~ onc None

.... None None ...__... ...._...._....... None

._..__.... EUG4 VDs2 .__._. . _ Nonc

.__._.. ._._ .._ None

_._.... ~ 'one

..._..._..__ . None

._..,._... ._....._.. None _._..... None

...__.... None

..._.......__ ..... None

_...__. _. None _._......._. Nooc

_.._.._.._ None None

.._.._..._.._.. None

....._...... None

_.....__. EUG 5- WSl .__.....___.. .. _ ~ onc

_...... ......_.. None

_ . _._..._ ..... . None

......._. ... Nono

............. None

._.. ....__._ None

.___._..... None

.._......._. _.__.. None

......._ None

__...__.. None

....._...._. Nono

. None ._.....-..... . None

._....._._. None

._.._......... EUG 5- WS2 7.59 9 i3 .--..__ t2.20

._ .__... None

_ ._ None

_- . _--- None None

. _ -._ _ ..__.. None

_.. .._.. None

__...__ None

._.. None

.. . _ . _. None .._...._. None None

__..._._ EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber w•as shut down for maintenance to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber 02 CORRECTIVE h7EASURES TAKEN: (2) Cleaned nonks, checked pumps, cleaned sludge fronr pit on empenger ritter, and restarted the scrubber.
ADDITIONAL INFORMATION*: The \Vet Scrubber was maintained and operated according to the manufacture's Instructions. The repa'vs and mafntenance w•ere done as quickly as possible, utiliring overtime if needed. 1 certify, based on information and be6ef formed after reasonable inquiry, the statements and inforntation in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Rcceivcd: Reccived By: Demonstration of Cause Submitted: ONo AGENCY USE ONLY Tracking Number: Team ID: Date Submitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infonnation. DEO-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/16/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE wRITTEN REPORT EMISSION: 4/15/2009 9:30AM SUBMITTED: SUBMITTED: 120 Minutes EE ID #, if a licable: 4/16/2009 4/16/2009 

# ***The owner or operator inust dernonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to do the PM. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's reconunended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Forin # 100-922 Page 1 of 2 Revised November 5, 2007

# — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - - - - :- - - -- - - - - - -



# (4) The facility was operated in a manner consistent with good practice for mmimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize ernissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA
— - — - — - — - — - — - — - — - - - - - - - - - - - - - --- %- = - - - - - - - - - - - - - - - - 

# (7) The owner or operator's actions during the period of excess emissions were doculuented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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# SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fon
- n # 100-922 Page 2 of 2 Revised Noveluber 5, 2007

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CIiY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to comct a previous eport, provide only the corrected infomtation below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

4/172009 Dal-Italia NAb1E OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dablta8a Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EM1SSION: Date StartTime: StopTSme: Duration: 4t152009 0:00 0:00 0:00 Hours:Min Phase 1



### 14:00 19:00 5:00 Hours:Min Phase 2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 5:00 Hours:MinutesofWetScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Perntit No.2004-198-TV (M-1): Specific Cond'dron 1, EUG 5 ESTIMATBD E611SSIONS: BASIS OF ESTIM1IATE ComplianceTesting _.. . . ._..._- X SOURCE GRP HF HCL SO, CO VOC NOx P;i EI:G 1 _. _. _ . 

### f.VG2

.... .._._._.. ._.__.._ . ----_._... .._._......._ .. ..__.._ . . ..... .... ..............__ _...._._.__.._ Cont Fmissions Monitoring .....__._ ............ ._..._.__ F:CG3SD1

. . . . OAt ..._...... . 0.00

.. . _ _.. ...... 0.18

_ _._.__._. . ._ _ 663

....... .__ . _....... 229

_.. ...__.....__. ,2.08

... _._.._. ... 4.14

..._. ..__.. _ .._. FngineeringCalculation

_._.__ .. ._.__..._._ . __.....__ . _ ___...... ..__.._.._ X ICL

~ (:3 SD2

.. 0.15 .._..... .... 0.00 ......_.._ 0.00

.__....__.. . 3.43 ...__..._.. 0.53 .__........_.. 1.12

__...__ .... 1.46

.........._...._...---__... OperatingLogs

. _.._._.._..._. .._.___.._ .___._.._._. .__...... X EGG

~ t1'Ust

...... ._ 0.03

......... _...._._ 0.00

_ .......... . 0.00

.___._.. 6.40

..._..._ . ... 08I

__........___ 1.25

____._..._ 2.78

.... ...__. ...._...._._.. Other(explain)

..___...._._ . .___..... _...._........ .._... EUG4VDs2 -... 0.02

._..._._. ._...._. _ 0.00

._ _ 0.00

... 3.61

..... _.. ___.. 0.45

_._ . _.._.._. 0.71 t.56

.. .. .. _..__ .................. . ....__.__ . . . __.... _.___ . ..._..._... EUGS - WSI

.. _..._ O.OI

_ _ _ ..__._ ...... 0.16 ~ 0.19

. _...__ _... 7.53
_

.._.._ . ._. 0.49

~ 2.56 ~ _ . _._.. ... 1.52

...._.._.._.. ....... _..._. ..__ ....... ......__........ ._.__._.__.. _.. .____._. EUG5-WS2 -.. . ._ 29.67

.._.._.. ..._......._. 3532

._ .. . __._. _97.70

. ... ... 64.28
- ~~ -

.. _..__.._.. __.. 19.07 - ~

___._ _ ..._ ..... 25.29

. _ _.._ 34A0

._ ... ._. .....__. _...._._.._. __..__... ._...._......... . ....__..__ EUG 5- Trim 

### 1 .21 1.55 3.44 2.41 0.67 0.94 0.72 .___._ __.._.__... ..__._.. ........__ . _...._._. ALLOIYED EMISSIONS: Attach supporting data

. SOURCE GRP HF HCL SO z CO VOC NOx PM EUG I ..__.. ........ .. .. ..._..... _.. ......... __... ---._. . _._..... . ..... ............. _._.......... . .. EUG2

. _._.__ _ ._ ... ... __ . . ~ _ .._ ...__. _ . ....... . _._. EUG3SD1 .____. . _..- ~ - ~ - ~~ - 0.59 __..._ 010

_ _....__._.... 0.45

._._....._ . 

### 13.11 - ~~ --

_.._.___...... _.... ~ 9.67

_ 3.88 _._._.._ 7.98 ...._...__....._..._____. EUG3SD2
. ._.. ..... __. _ _._.._. 095 ._. ..... 0.90

. . _ .__.. 0.45

....._ _ ..___13.77 __._...

... .._._ _. . 9.G7
. _ ........

. . 3.88

_ ............. 7.98

.__..._. __ _._....... EUG4VDs7 ......._.. 0.72

_._._. 0.08

... , _._...__._.. 0.18

. ..__........ _ . _ t1.43

_....._..,. . .__.. 38.33

_._. ....... ___..._ 3.51

....___.___ 5.85

_........_.__._._____.._ EUG 4 VDs2 .._...... 0.52 _..... - - 0.06

.. . .._...__ 0.08

.. .... . .. 5.09

__._.._._ .. .. 17.04

. ... .. . . ., _._... t.56

, 

### - 2.60_

._......_ . . ... . EUG5-WSl

. 1.43

. 1.60

_ . ._.._......... 8.96

..._ ...... . 19.60 

### -'

_ _. .. _..... 478 ......_ 7.73_

. 6.71___ EUG 5- W52 .........._. ._ _.... 8.56

..____. 9 60

.._. ._ .......__.. 53.77

........__.._.... . _ I17.60

_____...._..._._.. 28.68

......_.... ...._... 46.36 40.26

.__..__. ......_..__.._.._..__.__.. EUG 5- Trim 1 3.57 1 3.88 9.68 6.75 1 3.67 1 2.00 1.8o EXCESS EMISSIONS: (based on I hour rimiis) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF IiCi SO i CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG I - _ ... . .._.__..._ _..... ._...__ . _...__._. __...__.. -.._....._..._. _..... ._.... .. . . . ........... None

. . . ....___.._ ____..._. ..__..__ ...._._..._ None , . ... __.... EUG2 .___.. ._... .. . _.....__.... ._._........_ ......_... .._...._ .. .... ..... ...._.._._.._ ._. ...... ...._
- None ...__........ . ._ ..._.__ ...._.._.._._ __.._._...__ _.._ ........__.. None ..__.__. EUG 3 SD1

.......... ......_. !VOne

_ None

._ __ ....._..._._ None

.._....._. ... None

__._........ . ._ None

..__ .......... _..._. Nnnc

....._...... None

__._....... ._. None

_.._..... None _.._..._........ None

. .._. None _._ ..... None ....____ None

__...... None

_ ._...._.. EUG 3 SD2 __.. ._. ._._ . Yane ..._ ........ None

.. ............... None

............. ... None

.......... .... . ...... None

...... __............ Nnne

.. . None

_.___. . None

._ ..._ None

_.._._..___ None .._. _. _._ None ._. _._. None ..___.._..._ None .._. None EI:G 4 ~~i~sl _.... None

_... .._._..._._. None

.. . . ........... None None ...._.__. _ ..._ _.. None

..__ ..._..__... \one

........_ None

_._._....... ... None

......._. None

. ._..__.. None

. ,.,___... None None

.,_....__. . None

.... _ _. None

_ .._.. EUG a VD.2 ..._...._ .. None

._. _ None

_ __...._ None

......____._ _ None None

_. ...._._ ..............__....._._........_._... Nunr None _........_. ......_ None

.__.... None .__..._..._. None

._.._ ___...... None None _. ..._.___...._..._.

None _..__ ~ ane _._....__.. EUG 5- ~t~ .til _. None

_ .._ None ....__.._ None

-__._.._ None None None

._...... ..__........_._.._..._..._..__._...._........___._..._....._ None None

_._ None ...__...__ None

...._..._....._ None None ...._.___.. None None

_...._.__.__.._....... EUG 5-NN

~ 52 21.11

. _ ....._ . 25.72 ._ ...._....._.._ 43.93

_ - -... None

.. . - N 

### one

._._.. None

_... __ . None

._._...__.. . .__. None

_---_. None

. ..,.___ None

___ ....... None

........ None

_ None

....___.. None _... EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down due to a malfunction caused by the fogger water Iine bursting. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) Replaced the busted fogger 6ne and nonks. Restarted the scrubber.
ADDITIONAL INFORMATIONi`: The Wet Scrubber was ninintained and operated according to the manufacture's instructions. The repa'vs and malntenance were done as qulekly as possible, utirving overtime if needed. I certify, based on information and berwf formed after reasonable mquiry, the statements and'mformation in this document are true, accurate and compkte

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submittcd: 

## =Nn 0 I I I AGENCY USE ONLY DateSubmitted: TrackingNumber: Team ID: If you wish to notifv the DEQ about a technological limitation, do so here and attach supponing infortnation. DEQ-Fam #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for Malfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/16/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/15/2009 SUBMITTED: SUBMITTED: 14:00 300 minutes EE ID #, if a licable: 4/16/2009 4/16/2009 

# ***The owner or operator must delnonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess elnissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipinent or a process to operate in a normal or usual manner. The wet scrubber was shut down due to a sudden malfunction caused by the fogger water line bursting. This failure was not reasonably preventable. (2) The excess emissions did not stem froln an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Fonn # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable ei

- nission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

— - — - — - — - — - — - — - — - — - — - = -- — — — — — — — — — — — — — — — — — — — — — 7 — — — 

# (5) The amount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipi

- nent not otherwise required. Repairs were started and conducted as quickly as possible to minimize emissions.

-------------------------------- --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any iinpact of emissions.

----------------------------------------------- (7) En
- iission monitoring systems capable of producing valid data were kept in operation if at all possible. M IT

----------------------------------------------- 

# (8) The owner or operator's actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recurring pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recurring pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Forrn # 100-921 Page 2 of 2 Revised Noveluber 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALD'Y AIR QUALIrY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSIOIY FORM . OTE: 'Ihe information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fomt to corcect a prcwious eport, provide only the cotrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

4724/2009 Dal-ItaOa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick l4illiams Plant Manager (918) 683-4043 FACILITY: COUNTY: PERM IT NUM B ER: Dal•Ita6a Muskogee 2004-198-TV (M-1) DATE AND T1ME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 4/1712009 0:00 0:00 0:00 Hours:Min Phase 1

14:30 17:20 2:50 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 2:50 Hours:Minutes of Wet Scrubber powntime APPLICABLE LU1i1TAT10N(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Speciric Condhion t, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X

.. . . ____..._ __..._. ._ ......___ .. ._....._ .____.._ SOURCE GRP IiF HCL SO i CO vOC NOx PM EUG 1 .._. ._. . . _...__ . .. . ..... ....._. .._...._. ......._._ . ..._... _._. . _.....____... ~ . ._. __._._ .. ___....__. ..___ EUG 2 .._ . ._ . ..._..._._ .. ............... _ _........._.. . ...__.__.. ...__....._. ..__......_._. . _.__...._.. ..__.._.__... ...._..__.. Cont Fmissions Monitoring ._.__--. .___._ ........_.. .__.... ICUG3SD1

. . OAO

_......._. ......... 0.00

.. ._..__.._ 0.17

____.._...._ 6.47

.,.___.._.. . _.__ 2.23

_...... ............. 2.03

.. ..__._.._.. 4.04

..._._.___.. . ..._. FngineeringCalculation X

_.___.. . ....._.____. . _....._.._... __.._.. __.. _... EUG 3 SD2

_ 0.25

_ ....... . ........ 0.00

...._._ 0.00

- -_.__.._.. _ 5.63

___.._. . ._......_.. 0.86

. __ ..._..__ 1.83

...._._..._.. 2.40

..___..._.. . ._. Operating Logs X

..___.. ...__.._. . ___._..._ . ._.._.. EI'G 4 YDSI 0.03

..____.. . _ . _... .. 0.00

.._.__... 0.00

.___..._ ... 6.00

. .._. 0.76
_ _ .._.._._. 1.18

.. ._. . ... .. 2.60 Other (explain)

__._....__._ ...._..___. ...._.__._. _............ .._._.... EUG 4 VDs2

. 0.01

_ . . .___. 0.00

... 0.00

_ _... 3.47

. _._ ...._._..._.. 0.44

_. ....._... 0.68

.. _..._ L50 _.....__._._ ._.. _...._.. ..___.... - _- ...._..

~ EUG 5-R'S1
. ~ .. . 0.01

_.__. . _........ 0.16

._. ....._- 0.19 ~ ~

-_._ ._. .....___._.

7.52 0.49

._......_ 2.56

_ .... L52

. _........ _. . ........ .__.... ......__.. .___._._ ... __._.._ ............. EUGS-A"S2

.. .._ . 16.52

._.. _ .._.._ _t9.67

_. _.._._. 54.4t

. ......... . 35.80

._._.. . ...... 

### _

10.62 .__.. .___._. 14.08

.._ ... 19.t6

.............. ......._._ _._........ ._....__... . ._._..__._... ._....__ EUG5-Trim 1 1.54 1 1.96 4.37 3.07 0.85 I.19 1 0.92 _._..._. _.__.._ _......__ ......___.._ . .__._.. Attach supporting data ALLOWED EMISSiONS: SOURCEGRP HF HCL SO s CO vOC NOx PM EUG 1

. ..__...... __ _...... .__._.......... . ._....__.... ..._....._._. ...._.__.. __.._...._._ __...._._.... .. _____._. _ ._..._._.__.._..___..._ EUG2 _.___._ ._.__._ . ._.._.. __ . ... ...._..... _.._ _.._. _..__...._._

... . . ...._..._......___...___.. EUG3SD1

. ._......._. 0.59

...__ ___..... O.tO

_.. . _._..._._..._ O.JS

.......__.... 13.77

.._...._._ __.._.._. 9.67

.. . ..._......_ 3.88

. .. _.._. _.._ .. .. 7.98

... ................._.. EUG 3 SD2 ..._..._ 0.95

..__... ._.__..._ 0.90

..._._ ........... OAS

....._...__ 13.77

_..._._..._ 9.67

-- -._____.. 3.88

... ..._...__.. 7.98

..._..__.._......._. EUG4 VDst

. ._.__.. _ 072

. .._ . _..__. ._. .... 008..__.._

. ... 0.t8 .......11.43 ..._.....__. . . 3833

.._..__...._._ 3.51

...._.__.--_... 5.85

..........._.._._..__.._ EUG4 VDs2 .._._._ . .._.._. 0.52 .....__._ 0.06 0.08 ....._.... 5,09

__........ ___... IZ6i

....._ .__._....__.. L56

..._.__.. 2,60

..____..__..___.__. EUG 5-

~ VS 1

.. . 1.43

.._ .....__...__. . 11 . 6 __.___.

_ ....__.__.. 8.96

...... 19.60

_._._.. 4.78 7.73

. 6,71

. _ .._.._._. _ .. . . EUG 5-

~~~ S2 4.28 4.80 _. . _ 26.88

. _... 58.80

.. 14.34 23.18 20.13 ...__._._. EUG5-Trim 1 3.57 1 3.88 9.68 675 ..__._. 367 1 2.00 1.80 EXCESS EMISSIONS: based on I hour limhs EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO vOC NOx PM HF HCI SO i CO VOC NOx PM EUGI .__.__._. ....._._ _. ....__._._. .._._._..,... __._...... ._. ...._. _....__..... _.__....___. . . None

. _ ...______ _._._. ..__ ..._. .... .......__. ...._____._ None ....._._...__. G .........._. EU 2 .._....__. .....__. ._....._. .. .._._.__...__ _....__. _......__. . . .._ . ___.. . None

.. _.__.. _._.. ..._._.__. _.. _ __.. ....._._.. ..... . ._... _... . ._.._._ ...... None

.............

. EUG 3 SDt

............ _. None

..__.__..._ None ._ . . . ._..._..__.... Nnne

.. _.. ......._..._....

None __.. _ Nnnr

_._._. . None

.. None ._.... _._... . ._ None

___....__....._ ~ one , .._.__ None

.._._. _.. Nono __. None None

.._....... None

..__..._ EUG 3 SD2 .._.._.____ None

...___._ None

._ . ......_._._ ... None

...... ....... None

_._.._. .__._.__.....

None _.._...... None

. ....__.__ None

...._._..._...._.._ None

_..__....... Nune None

.. __._...._.

None None ..._.__.. None

...__....__.. None

........_ EUG 4 VDsI None

....__..._.. . .___.._.... None ._..__.... None .._.. __. _ None

-.___..._ .._..._ Nono

___.. _._._._.._. None

-. ._._ Nonc

.. ..._._._ ....... Nonr

........_. ~ one
. ~ one

___.._._._.. Nono

.. None .........__ None

..._..........._ None

_._....... EUG 4 VDs2

....... .. . None

....... . ... ..... None

.... _. _.... . Nonr

..__._ None

._.__.._ . .... _._ None

..___ _ _.._..__.. None

. __.__ _.. . None

. _ .. _.._.__.. ...__ Nonc

._._ ..... ~ one None

. _ ... __ None __.. _ _ _ None

_ __._. None

. ..._..__... None

.... ..__..._ EUG 5-1YS1

......... _ None None

.... . ._ __.... Nono

......._.. _._. None

. ._ None

.._._ .._... __....... None _. None ...__. ._. None

._._.... . IVOne _... ..._.. None

..._....._.. None

.... None

. None None

_..._....._.... EUG5-11 

### S 2 ._. _...... . 12.24

.___... . _.._..... t4.87 .__._._._ 27.53 None

__.._.. . None

_...... . ....._.._ ....... None

............._ None

................ _. None

...... _ ....._. None

_ _ None None

..... .. ..__ None

... ___.. None _....__.__. None

__....__._._ EUG5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shot down for maintenance to replace the pipe on the fogger. PROCESSES AND EQUIPMENT INVOLVED: (2) %Vet Scrubber #2 CORRBCTIVE MEISURES TAKEN: (2) The pipe was repatced, the bnpengers w•ere cleaned, and the scrubber was restarted.
ADDITIONAL INFORMATION*: The 1Vet Scrubber was maintained and operated according to the manufaeture's mstruetions. The repa'vs and maintenance were done as quickly as poss ➢ tte, utilbing overtime if needed. t certify, based on inforntatfon and betief formed after reasonable inquiry, the statements and information m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Reccived: Received By: Domonstrmion of Cause Submitted:

= No ACENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: 't If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVtRONPAENTAL QUALrrY AIR QUALfTY DMSION PO BOX 1677 OKLAHOMA CtTY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 worldng days aRer the immediate notice is given. If you are using this form to correct a previous eport, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

4R4l2009 DaEltaGa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick 1Vil0ams Plant Manager (918) 6834043 FACILITY: COUNTY: PERhtIT NUMBER: Dal-ItaOa Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS Bbi1SS10N: Date Start Time: Stop Time: Duration: 4124/2009 0:00 0:00 0:00 Htwrs:Min Phase 1

10:15 11:00 0:45 Hours:Min Phase 2 DURATION OF EXCESS EMISStON (HOURS:MINUTES): 0:45 Hours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permk No. 2004-198-TV (M-I): Specitic Condhion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE C'nmplianceTcstirtc X _..__. .._.... _._... SOURCE CRP HF HCL SO, CO VOC NOx PM EUG I

. ......... .........__.._ .......___ EUG 2

. .__.... _ - _..._ ,-.. _ ..... _._ _ .. - .. _. . . _..__. ...... .._.._.._.. .. _ _ _._. _ _ Cont Fmi

~ sions

~~ 4on'rmrin_

_ EU G 3 SD I __. ...._.._.. 0.4_ .__._._ 0.00 ........__. O.19

......__ .... ... 7.26

......... ........... 2.51

....._.._-.._. 2.28

. __..-.._._. . 4.53

___..._._ .___ ~ Fngineering t:4culation X

_....._.. ...-.__..._._. .. .._____ . ..._.__..... .._...... FUG3SD2

.. ......-... _. 030

._._._._ . ....__._ 0.00

.. ._.__._ 0.00

-.._...... 6.76

....._.. _ ._. t04

__.. _. ---._.._ .. 220

. . ............. 2.89

. .......... . ...........__.. Opc.ningLogs X __._..... . .__._..... ...._.._.. FDG 4 VDsI 0.03 -._.. _ .._ 0.00 ._.. 0.00

.. _. _ ...... .. 6.26_

....... , 0.79

.. ...... 1.22

--. _..__ 2.71

..._._.._.. Othertcxplain)

..... ..........._..... ........_..._ . . . t1'G a Us? . _..._._ 0.01 -_ ~ 0.00 __.__.. 0.00 _ _.. ._..... 2.64

.. . 0.33 .._ .__. ~ 0.52

- .. .. _.__ 1.14

_._........ ........... ._..... ........... ... _.._.. ECGS-R`S1 ..._.. 0.01

____.... . -_..... 0.16

._. . 0.18

. _ .. . .__.. _7.28 .__........._

.. . 0.47

-..........._ 2.A8

...._ . .... ..... 1 .47

...... .... ...._..._ _____ ..__..-__.... ..... ___._...-. -._..._.._._. EUG5-

~ VS2

. _ 4.66 __._. . 5.55

~ - .... ..._._. (5.3ti

.- ... . 10.11

._.__. ...___-._..._ 3.00

. .... _.... 3.98

. . . _._... 5.41

........... ......._._..._ ..___._...... ...._.._ _.__.__ . .__.._.._.-. EUC:

~ -Tr'un 1„36 1.74 3.88 1 2.72 1 0.75 1 1.06 1 0.81 _.. _..... ..___........ _._.._. .. _......_.. . .__._._ Attach supporting data ALLOWED EM1t1SS10NS: SOURCE GRP HF HCL SO i CO VOC NOx PM EI1G I _._.. _....... ..._...._.. ........ ... ... . __.____. _.._....... ...._.._ . _.__ _.___. ... ._. ....._. ....._...... ........._._._ ............ EUG 2 ...._.. ..._......-..._. ..__-._._ .._..__....... ._._..__. _ _..-.___........_... ._.._ ....._._..._.._ _._.__. . _._..___._.___.__._.. EUG3SD1

......... ............. 0.59 0.10

.___.._.. ._......... 0.45 13.77 __-..._... .. ........_.._ 9.67

__.._.._.._. 3.88

....___. 7.98

.__.._._..__.__._._... EUG 3 SD2 ....__..... .. __..._._. 0.95
. 0.90 0.45 .__. 13.77

...._..._ ._._.. . 9.67

...._.. .. _... -._..__. 3.88

_.._._... Z98

. __. _.-.._...._....._. EUG 4 V

~ st _......__..__ . ... 0.72

__....._ ... .._.__ 0.08

._.. ___....... 0.18

__..___.. .. ._ 11.43

._..__.... ...... 38.33

.._..... ._ ...___._... 3.51

. . ._ -- 5.85

..- -___._.._.._._.__.. EUG4VDs2 .__...__-. .. -..._._. 0.52

-_._._._..... 0.06

.-_.........._ 0.08

...-..._._.__... 5.09

.._..____ ._.. t7.04

__._ ..._.___..__ 1.56

...... ......... ... 2.60

..................... EUC 5- WSl , ...____.._.. 1.43

..___..._ ....__._ t.60

..... ....__...........- 8.96

_.__... t9.60

... _..__ 4.78

_._... 7.73

. . .............. . 6.71

......................._... EUG 5- R'S2

. ___...__... -_... 1.43

..._...._. ....___....._ 1.60

._...._.._._. 8.96

.__.. ._- .__.. ... 19.60

_ ........_... 4.78

........ . . _..__..._._. 7.73

_ 6.71

_ .._._____ ....._.. EUG 5- Trim 1 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 bour Bmits EXCESS EMISSIONS: 24-lir Totals SOIIRCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO z CO VOC NOx PM1t EttG l __... _... . ._..___ . _-..-..._..... .......__.__. ._....__.-._. . ...____..... .._..... _....... ..._...._..._.. __..___._.. None ...-__.._..._... _. ........_._... .. _.._.__. ..-...-___ .......... ........__... None .._.._.... ta'G 2

. _ ........._ .._._....._.. . ..___...... _....___._._... _..._.._.__ ._.__..- ...._._._ ...... None ......._....._. -.__..-.._.._......_ -.- .___ _ ___ ___ . ____.,..__ -.. _..____.. .._.___..__.. None .._.._.._... _.. ICU(:3 SD1 None

.._._.... None

.__._...._ None

.._...__.._. None

._,.._._. ......_..... None

...,._._.._.... None

-_.._.._.._ None

_ __.._..._.-_-.. None

..___... . None None None None .---.._._. None

___._.__... N .

one _.......__..... EUG 3 SD2

... . None

_..._.._. __...__ None

..._.._.......... None

._..__... _ . None

_.._..- -.........._. None

... ..__...._.. None

._._........ None

__.__...__. .._ ............

None

. None ._ _..__.._ None

. . _._._ None ..._ . None ._...._..._ . None

..._........._. None

.......___.... ECG a VDsI

_._ None _..._ ..... .......... None

.. . .. ........... \one

...... ...._. None

..__.__.. . _ None

.__............._...._ None

. ..__._....._ None

....__......._. . None

..._..__.. ..- Nono

_ __._._.. Nono

...__...._._. None None ....._.__ None

._._._... None

....._._.. 1=1 G i
~ 'Ds2

. ._ _ None

_. _. None_

_._ .. _ . None _None ._._ .. . . _._ . None

......... . ....._.... None

_ ..........._. _None

.._ ..... - .._ None

............ . . None

.___. None None N _one
.. None

.. ......... None

.. .. _......... t:UF,S - NN St None

. _ ._._..._ Nou e

.-...__._......_. ~ one

._ None None

_._..._._..._..__......_......_.___.. None .._.....__... None None

........... Ivone ......__..__. Nono

. __......_ None None ___.._.. None

...._.__....... None

....___....._ I:UGS-

~~ S2

. .. .. 3.24

_. .... ....._. 3.95

_....__._._ 6.

~ t0

.. None .._.._._ _ . .... _- None

.__.... ...... _.._.. None

__............ None

............ .... None

........ None None

._.... None .__ . None ._........_. None

......,........ None

....... _.._ EUG 5-Trun None None Nonc None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for mamtenance to replacedo the PDi. PROCESSES AND EQllIPMENTINVOLVED: (2) R'et Scrubber 42 CORRECTIVE MEASURES TAKEN: (2) Checked the foggers and Impenger fdters, cleaned noMes, and restarted the scrubber.
ADDITIONAL INFORhtATIONa': The \Vet Scrubber was maintalned and operated according to the manufacture's instructions. The repairs and maintenance were done as quickly as poss0>le, utitL'mg overtime if needed. 1 certify, based on information and berwf formed after reasonabk Inqu'vy, the statements and information in this document are true, accurate and comptete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: D«nonstration of Cause Submittcd: = No AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: # If you wfsh to notify the DEQ about a technological limitation, do so here and attach supporting infomtation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — I)emonstration of Cause RepOrt Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days affter the occurrence has ended. For those that report quarterly it inay be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/22/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/24/09 10:15AM SUBMITTED: SUBMITTED: 45 Minutes EE ID #, if a licable: 4/27/2009 4/27/2009 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt fro1rl compliance with air elnission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conteinporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean nozzles, check the foggers, and to check the impenger filters. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess enussions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recorninended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

### — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — 

# :- - - 7 

### -- - — - — - —



# (4) The facility was operated in a mamer consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipi

- nent to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

--------------------------------- 

### % --------------- 

# (5) Reasonable steps were taken to minimize the ii

- npact of the excess emissions on ambient air quality. The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible.

------------------------------- ~ 

# - = - — - — - — - — - — - — - — - — 

# (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.



# Records are kept of the scrubber downtime and the work done.

n — a 

# — - T --- 

# 6 1 - 7 - -----------------------

- 

# Fcjrt.fy, b 

# a;ed on infin-mation 

# ~ beli;f Forme a&r reasona e inquiry, the statements and information in this document are true, accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Forrn # 100-922 Page 2 of 2 Revised November 5, 2007

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALlTY AIR QUAL!TY DNISION PO BOX 1677 OKLAHOMA CtTY, OK 73101-1677 

# EXCESS EMISSION FOItM :'OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous epori, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

5/12009 DaI-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: R)ck \YiOiams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal

~ ltafw Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS Eh11SS10N: Date Start Time: Stop Time: Duration: 4/27/2009 0:00 0:00 0:00 Hours:Min Phase 1



### 10:20 12:10 1:50 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:50 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Pernid No. 2004-198-TV (M-t): Specitk Condhion 1, EUG 5 ESTIMATED EMISSIONS: [iASIS OF ESTIMATE ComplwrceT

~

-Gr•_ X - ......._ .. __._ . .__.._._. _....._. SOURCE GRP HF HCL SO r CO VOC NOx PM EUG t

. _._.. _._ ... _._._ ..____.. _ __..... .....__ .. _ __..._..._ _..... ..... . ____....._ . ._._._... ....._._..... .._ EUG 2

_ _...... . .__.._ . ...._._.... . ...... _. __.._. ............ ...... .._._ ._._.__.. ...._._. . _ Cont Fmissiona \lunilo ~ In_• - _._. ._. ..._. ..____ .__. ..- EUG3SD(

. 0.49

.. . _._._ _ 0.00 0.21

...... . . 7.96

_..-..... ......_.. 2.75

_._-.__ _.........

2.50

... ._. 4.96

_._.... . EngineeringCalcul:iion X

_._... ..... ... __.___ . .. _. EUG 3 SD2

.. . ...._ _ . ~ 0.34

__..._._ _. 0.00

. ..... _... 0.00

.. . ..__._ 7.55 ~

._..__.__ _..... L16

_. .__...... 2A6

.......... 3.22 Oper ti:m Logs X - .._.___. ... .. EUG4 VDsI

.. .. 0.02

- ._ . ..-_. . 0.00 __... 0.00

.. ..- .... 5.24

_ _... _._.. 0.66 ........-__ 1.03

. ..__ _...

2.27 ._...... Othcr(explain)

.._...._ ._.__ ... ..__... _. .______....- EUG 4 VOs2

. _ . ._.__. 0.01 .__.. . 0.00

.. .__... . 0.00

_ ... .... 2.60 0.33 0.51 Lt3 EUG5-{VSt 0.01 .._.__ 0.13

.. . - 0.15 5.93 . .. 0.39 ~ _ .___.. 2.02 1.20 EUG 5- WS2

_. t t.63 - ..._.. _ ._..._. 13.SH

. _...... _ 38.30

.. 25.20 7A8 9.92

_ ._... . 13ft9

. .._ .. EUGS - Trun 1.29 1.64 3.66 .

~ - ~~~ -- 2.57 ~~ ~~~-~~-~ 0.71

~~~ - ~~~~~~ . ~~~ 1.00 0.77 .._..._ . . ___ ._._ . . _..-._._ . .....____ ._........ Attach supporting data ALLOWED EMISSIONS: SOURCEGRP HF IiCL SO i CO VOC NOx PM FUG t - __ . . _ ......_. ...__...... . . .._.._....__. . .._..... _ .. _...._..-... ._____ .._._._._ ...__ _... Et1c 2 

### __. ....____ __ __....... _.__-_. ._._.._.... I:I C:3 SD1 0.59 O.tO

. . -- 0.35 13.77

_ ...... . _ 9.67

.... . .. .........._ 3.88

.. - 7.98

__._... .. ...._..__ Ct'C 3 SD2 0.95

. _.. ...._. 0.90

_ __._..._ OA>

..._..._....... 13.77

.__._.. ._..._._ 9.67

._._...___.. 3.88

..____._... 7.98

_...___.__..._. b:UG a ~ us!

_ 0.72

..... .. _._.._ 0.08

_. . ...___..._. 0.18

.._....___.. . LIA3

_ .__. _.. ._ 38.33

... _ . . ____..._... 3.51

_..__. _ 5.85

.__ ._.._._.__. ICl

~~ G4Alls? .._ 0.52 .-...._ 0.06

.. .._.____. 0.08

. ....__....._ _. 5.09

.._ _. _.. t7.04

... ._.._..._._.. I-56

_ 2.60 _._.__... _..__.... I[! GS -A N S[

._. 1.13

_ .. ._ ..._.._. 1.60

_. ___. _._.. 8.96

. _ _._ ....._.._.._.._.._. t9.e0 4.78

.... ...-._... 7.73 6.71

. __.._._..___.._._... EI - GS ti2

_.._ 2.R5 ..__... . _..... 3.20

.. .__.-_. 17.92

..._...___ ._.. 39.20

._....__. ._. __. 9.56

._ ......_._.._._ !>.•45

___... 13.42

_._........ .__...._.. ECG 5 - Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on I hour llmits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF FiCI SO s CO VOC NOx PM HF HCI I SO i CO VOC NOx PM EI7G 1 ._ ....-_ -__._.___.. ......_.. ._._.____ _ ___....__. .......__ __...._._.._. . ___._..... ....._.....___. None __... ._.._.... . ._ _._.._._ . ..__.._._._. None .._..._...__. ICl'G 2

. .___..._. ._ ........_. ..._._..._._ .. _._..___ _......._ ...._......__.. ...._. .,_._..._ None ___...... ..._.... .. .. ., _ _....__ . _.._.._. -... _... _. . _ . .._..._._. None ._._.__... ICI'G 3 SD1 None

._._.._.. . _...._ _.._ None

__. ..._...... None

......_._.._ . ... None

..._. . .__.. None

_._. ... ... None

. ........._.._. None

. _.___..._ _____.... None

_ .. ._ None _,... None

_..._.. Nonc ._...__.__._ None

_ .. None

_.... Nane ..._.._.__ Ef

~ C 3 SD2

. None

...__._ ..___...._.... None None None None ............_._ None

..._._..__._. None

............_ _ ~ one None ..._.___. None

. ._._._..,_. Nonr

_ Nnnr None

.__.._.. None EI:G 3 VDsI None

___._.._.. None _ . .... .. ......... None

....._.._. None

_._._.. . . _.

. _ None .__. __... None

__._..... _ None

_......._. . None

_.... -. None

. - _.-_. None

. ..._..... None __..__.. _._ Nane

.. 

### Vone No ne

......... EUC 4 VDc2 .__ _,......_ None __._.. None

.. ............ None

......._._._ .._.__........

None None

.._._._._._ None

_._. .....___. None ~

.__.._.__. None None

_._._.. None None \one _.___._.... None

..._._.._.__. None

..._.._..__. F.UC 5-AA

~ S1 None

.__ _ None None ....._.__ ..._-.....___

None

... _......... None None __.._.....__. . IVone

._._....__.... .__. None ___. --- _..-.._.-.. _......... . None ...__........_ None

_. .___..._.. None _.._..___ Nnne

. . None

_ ..-__..._. None

_._.._._._.. 6UG 5- \
~ SZ 8.78

_ ......_.._.._ t0.65

............... 2038

.... None

... ...__.. None

_ ..__.__._.- None

_ _ O.D7

. _ None None ._..____ None

..._......._... None None ....._._.._ . None

.._.__..... None

..__... EUG 5- Trmr Nono None None None None None None None None None Aone None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for mamtenance. PROCESSES AND EQUIPMENTINVOLVED: (2) NVet Scrubber 92 CORRECTI VE M EASURES TAKEN: (2) Insta!!ed new fogger heads, reheat traced Gnes for new• insulatfon, cleaned nonles, cheeked impenger rdters, and restarted the scrubber.
ADDITIONAL INFORMATION * : The Wet Scrubber was maintained and operated aceording to the manufacture's instructions. The repairs and maintenance were done as quicklp as possOrk, util'v7ng overtime if needed. I certify, based on information and be8ef formed after reasonable inqu'n-y, the statentents and!nformation in this document are true, accurate and contplete

SIGNATURE OF REPORTING PERSON

Date Recdved: Rcceived By: Demonstration of Cause Sub:nitted:

= No AGENCY USE ONLY TrackfngNumber: Teatn ID: DateSubmitted:
* If you wish to notify the DEQ about a teehnological limitation, do so here and attach supporting infonnation. DEQ-Form #100-920 Revsed February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it lnay be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/28/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/27/2009 10:20AM SUBMITTED: SUBMITTED: 110 Minutes EE ID #, if a licable: 4/28/2009 4/28/2009 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air elnission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to install new fogger heads, reheat traced lines for new insulation, cleaned nozzles, and to checked impenger filters. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

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# uired and that thi3provisiouohall notbe construed tO Got0u%atio4}l«roqnirethcmhotdovvu0fl000coa equipment to nzininzizc cuzin8iooS. Thisnmckvvandoocioorderto prevent a malfunction of the wet scrubber. The scrubber was operated according to tbe `minm1ructi000.

_______________________________________________ (5) Reamouoble stcoonxeretakcntomininzizethe iinpact ofth:oacoonouiogioumooaoibient air Theworkvvus doueao quickly aop0SSibletooziniozizethencrubbcr downtinc

_______________________________________________________________________ AB Emissions monitoring systems onpobleofpro volid doiowmere kentiu operationifo1ullpnosible.

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# SIGNATU080F RE0P0NSIBLE8yFNCIAL OR DO0IGNOE

DE()Forn#l00-g22 Pogc2of2 RevisedNVvoozbcr5,2007

### r ~ 

# ANO&WO

- WilrT , DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfTY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The infomtation requested below should be submitted to the address above s4dthin 10 xvorking days after the immediate notice is given. If you are using this fonn to correct a previous eport, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

5112009 Daldtalia NAME OF 1NDIVIDUAL REPORTING: TITLE: PHONE: Rick 1YOiams Plant ManaBer (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Itafia Muskogee 2004-199-11 1 (M-I) DATE AND TIME OF EXCESS EMISSION: Date Start Tinte: Stop Time: Duration: 4t29l2009 8c00 9:30 1:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:30 Hours:Minutes ofR'et Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Perntit No. 2004-198-TV (M-1): Speciric Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianccTesting X _......_. .__._. ._...._. . ... _..... _..__.___ SOURCE GRP HF HCL SO, CO VOC NOx PM Et1G I ._. ___ .. ._..._.._ _ .... _. ._. _____.._. ..__.... _.._._.. ._ _.__ .__ _........._._. .__._..._... _..._._ . . EUG 2

.... ....._ . ..___.. .._. __ ._...._..._.... ............. __...__ . ___ ._..... ._.......__.. ._..._..._... .__._._. ._._..-_.... Cont Enissions hlonitoring ._.__.. . ..__....._ . ._.._._._.. . ... .._.._. 1•:I

~ GiSDI - 0.44

-._ ............ 0.00

....___.__ 0.19

. .__.._. 7.15 2A7

_......_ ...._..__._............_... 2.25 ._...__....... 4.d6

...._.._... ._......_. FngineaingCalculation X __....._ _.._....._. _.._.._....... ..__.__._. ka'G 3 SD2

... .. ___.. OJ4

_.. _ .__ 0.00

_-_ -..__._._._.. 0.00

...._.__..._ 7.56

...____ . . ..._. 1.16

___... .__ 2.46

....._..._.. 3.23

......_.._ Operating Logs X

....._.... .__._. .__......_ . .....__.._. . .__._. EI"C 4 1

~ Dsl

_. 0.02

. ._.. ........ 0.00

. . ...__.... 0.00 5.22 ..__ _ . _..

. 0.66 _...._ . . 1.02

. .... 2.26

..... .. _ . Other (explain)

........._ _......_ ....___.. ...._.__._. Et - G J VDc2 . 0.01 _._.__. 0.00 _... ....__.._ 0.00

._ __.... 2.67 ..........._. 0.34 ....__..._ 0.52

. _._ Ltb

_-.._.... _ _......_. .......... ._..._.....__. ..._....._. ....___.._ .._ ... 4.65 __.._. 5.54

. _ t5.32 _......_ . ~ 10.08

...__._ . ..__._ 2.99 3.97 ..-.. 5.39

_... .. ttl

~ G.1-t

~ S2

___ ..... 0.00

. 0.01

~~ . ~~~~ -

. . ..... _. 0.02

. _. t4.29

. . _. 2.39

. ............ 4.61

. 4.20

_-.._.... .. . _.__...._ .___.._._ .....__.... . ..._. _ . , .. _......- EUG5-Trfm I 1.79 2.29 5.09 3.57 0.99 1.39 1.07 .__....... __.___._.... __.. _._.._... ...... ..._...... ALLO\VED EMISSIONS: Attach supporting da[a SOURCE GRP tiF HCL SO s CO VOC NOx PM EUG 1 ......_.. _. . . .._ .. .... . . ............ ..... .......... ......._. .__ .._...... ... ..... ._._ . .. .... .__.._.. .. _. ____... _.____... EUG2

. ._._ . ..__._ _....._.- _..__.._.__. ...____. .__.._ ._..__. _..__. -_ ...... ...... ................. . ............... ........... EUG 3 SDI ._....... ._._. 0.59

....._._ . ......... 0.10

.... ..__._.__.._. 0.45

._.._..._.._.. 13.77

.. __-.. .__ 9.67

..__. _ ._._ 3.88

.. ._ ......__... 7.98

__._.._._...._..__....-. EUG3SD2 _..__.._._._ . 095

.. ..._._.._. 090

_._..._.._._ ~ O.dS

. .._...__.. _ . 1377
_

.._ 967

__. _.__........__. 3.88

.....__.__._ 7.98

...______... ...__._. EUG4YDsl ___.. ____. _ 0.7?

.. 0.08

.._ _....____.. 0.18

. ._.._.__ 1L43

__._.._. ___..___. 38.33

_ ._-.___._. 3.S1

.. .......__..... 5.85

...._.__._.. _....._.. EUG 4 YDs2 ..__...._....___._.... 0.

~ ?

. . .......__. 0.06

... .. .........._.... 0.08

...__...._. 5.09

. .._._. ..__.. .4

1 70 _...__ .__...___._. L 56

.._.___...._. 2.6 0

..._..-__......._..
..._._._.._. .._._._ 2.14

.... ............_._. 2.40 13.44

. _....___....- 24.40

___._.._. . _.. 7.17

_..___.__.. 11.59

.. ...._.....__. 10.07

.._.....___.._.._...... EUGS- WSI EUG 5- \VS2 ..._-._.._.__ ..._ (A?

.__ ........ ..........__ _ . __. ,._
---- -- - 1.60 _..__.._.... 8.96 19.60

.__..._.-._.. 4.78 7.73 _,._.._..._ 6.71

.........._..... ...__.._.. EUGS-Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour timits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO, CO YOC NOx PM HF HCI SO, CO VOC NOx PM EUG I

. _. ._. ._. _.. ..... _ ........._ ..._..... . ._____ --.___._...._ __._.._.. . None

... . _._. _. _...____. .... .. ...._. Nonc EUG2 ._._.._. . . .. ._ .._.___._. . _.. _ _.__.. ._._. .. ..... __..._ .. . _.._.. . ..__._.__ None

. . .. .. .._. . . .. . ..._ _.._ _.. None

. ... .. EIIG 3 SDI __... . None

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.._. ._ ~ onr _. .... . ~ bne Vnnr None EUG5-

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._. _..._.... 1.88

._....._. None

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.__... EUG 5- Trim None None None None None None None None None I None I None I None I None lone NATURE AND CAUSE OF EXCESS EMISSION: (1) The scrubber was shut down for ntaintenance to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (7) AYet Scrubber 01 CORRECTI\'E MEASURES TAKEN: (1) Cleaned norfks, 011ers, and restarted the scrubber.
ADDITIONAL INFORMATION*: The \Vet Serubber svas maintained and operated accordmg to the manufacture's instructions. The repairs and maintenance were done as quickly as possOtle, util'ving overtime if needed. I certify, based on information and be5ef formed after reasonable inquiry, the statements and information m this doeument are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Reccived By^ Demonstration of Causc Submittcd: F
---- ]No E_____1 AGENCY USE ONLY Tracking Number: Team ID: Date Submiltel: `" If you wish to notify the DEQ about a teehnological limitation, do so here and attach supporting information. DEQ-F(xm #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause laeport Form for Maintenance, Startup or Shutdown ®AC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAi'VIE: Dal-Italia 4/30/09 NAME OF INDIVIDUAL REPORTINC: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-i) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT E1t1ISSION: 4/29/09 8:OOAM SUBMITTED: SUBMITTED: 90 Minutes EE ID #, if a licable: 4/30/2009 4/30/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in perinits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous 1ogs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean nozzles and filter. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recoininended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Forin # 100-922 Page 1 of 2 Revised Noveinber 5, 2007

### - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 7 - - 7 -- - - - - - -



# (4) The facility was operated in a manner consistent with good practice for minimizmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.



# -------------------------------- --------------- (5) Reasonable steps were taken to iTiinimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to ininimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. 

# =I ------------------------------- %-= ---------------- (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

------------------------------ ma n and bel 

# T r reasonable inqu ry, th 

# TceTti

- fy, ;a;ed on 

# mfo, t7

io ief Forme aite i e statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fon

- n # 100-922 Page 2 of 2 Revised November 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALRY AIR QUALRY DIVISION PO BOX 1677 OKLAHOMA CrfY, OK 73101-1677 

# EXCESS EMISSION FORM , OTE: The information requested below should be submitted to the address above within 10 wor6ing days a0er the immediate notice is given. If you are using this form to con•ect a pmious port, provide only the corrected infomtation below, sign the eertification, and attach a copy of tlie prevdous report.
REPORT DATE: COMPANY NAh1E:

5/1/2009 DaHtalia NAME OF UVDIVIDUAL REPORTING: TtTLE: PHONE: Rick Killiams P4ant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 4/29/2009 0:00 0:00 0:00 Hours:Min Phase 1

4:30 5:20 0:50 Hours:PAin Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:50 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No.2004-198-TF' (M-1): Specific Condhion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X .___..__. .....__ ._... .. ....__. SOURCE GRP HF HCL SO i CO vOC NOx PM EUG I

......... .. ..._.__ .__..... ..___.__.. ...__._._ _..._.._. ._....._.. .__._._._.. . _---........_. ..........._.. __...__.... 

### EUC 2 ..._.__.. .._..__.._. ......_._... . .._.__..__ ._.._...__-.....__._._.. .._-..._.. __....._ . ...._....__ ._.__..... ..._....... Cont Fmissions Momtoring ____... .......... _...._.__.. .......___.. EUG3SDt 

### .__..._. D.d1 0.00



### _ . _....... 0.19



### _ . _..-_._._ ..._.__......

Zt5 

### ._. 247



### __. . 

### ....._._._... 2~ 5 4.46 

### ......._._ .... EnbincerinbCalwlation X



### ._.._.. ..._.... ._...__. ..._ ........ .........__. EUG3SD2

. ._._...- O.z4

_ ._._ - 000

. .__.._._.-- _0.00

.... .. 7.56 ......._._.... _ 1.16

_...._ ______ 246

. __.-... __.. 3.23

.__........ OperatingLoe

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### ,c X ..__.__ ....__.... .___... _ __... EUG4VDs1 _... .. __.. 0.02

__ __._._... 0.00

..._..___.. 0.00

-_.____._ . . 5,22

......_._ _......_._.. 0.66

__.._.__ 1.02

. ..___._ 2.26

....... ..... Otha'(explain)

...__._. __......_.. ._._... . .___. _..__.. EIJC: a VDs2

_ . 0.01 0.00 _.._ ....__.. 0.00

. __...._ _ 2.67 034 _..._.__ ___.._. 0.52

.. .... .__. 1.16

__. .. _....._. ._.._..... ...__...... ._._._ .._....... EUCS-\\Si
. ~ 

### - 0.01 - ~-~~ ~



### ...__ _ 

### 0.15 _. .._..._. 0.17

-. .,..- 6.71 0.44

.. 

### 2.28

.. ..... 13 

### 6

_..... .____. .._...___._ _......_... _..._. ._....... EL'GS-\y52

. .... .._ 5.07

.__. ..__...._. 6.03

_ _..._._ 16.69

..__ ... . ~~~~~ . ~ 

### t0.98
. ~~ -



### __.. 3.26 ._..._ ___._... 4.32

._... .._. 5.88

.... .. . ..___... ___..._.. ..__ .____ . . ___._. ....._.._...

~ EUG 5- Trim 1.79 2.29 5.09 --_. 3.57 0.99 I39 1.07 

### ....__ ... . .......... _.__.___.. ...___... ____._.... ALLOWED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO, CO voC NOx PM EUG l 

### .._ .__.__. . .._....._ ___._.__ ____..._ ._._... .-.__...__.... ._.._..._.... ..__._. ._..___..........._.._ EUG 2 .._ .. __...._ . ._...._._.. ._ ...._..._-- --__.._..... ............ .........._ ..........._. ..__.__ .._..._.__.. .__._.. 1:I:G 3 SDI ..._... 0.59

. _ _......_ 0.(0

.. __._.-__. 0.35

___ ._ _ 13.77

___..._ ... ......... 9.67

..._... _ _......_.... 3.88

__...__ 7.98

........._... __..._.._. t:UC:3 SD2 .__...._ 0.95 ..._...._... 0.90

_ ... ._...._._.. 0.45

...... __._ 13.77

_...._.._ . 9.67

_.._. _ ................ 3.88

.._....___ . 7.98

._.._.....____.__._._. GU(7J \

~ USI

. .. 0.72 .._.._.._. 0.08 ..___....__ 0.18 11.43 .......__.... .._-..._ . . 3SJ3

...... . ................. 3.51

....__.... 5.85

._...__._......_.__.._..... LU(;dVDs2

.. . ...__.._ 0.52 .....__.. 0.06 ..- _- _-_..._.._ U.O8

.._....___.. _ _..._._..__...

5.09 ..._.._..._. 17.04

. .............._. 1.56

........__._... _.._- 2.60 Pt'GS-\\"S(

_ ..__. .._._ ._.-_. L43

......_...__ 1.60

.. .. _ _.._........ 8.96

....__...__ I9.60

.__._.-.... ...._.... 4.78

_ ... .. ............... 7.73

._..__... 6.71

...._..._.__.. t:t - C9-\\'S2

_ 1.43

_.__. 1.60

__. .. - - 8.96

_._...__. 19.60

.._...._.._ ... . .._.......... 4.78

_.__..__.._ . 7.73

....._.._ _. 6.7t

.... ....._...._........_- CI:G5-'I'rbn 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour Tunfts EXCESS EbitSSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx PM HF tICI SO z CO VOC NOx PM

_ EtiG I _...__. .. .....___._. _..____ _.__.._.._... . ___...___ _ ___ ._...._..__ ..............._ None ._......... _... ...__._. _..___.. __.. __.. _...._.._. .._......._.... None ....__....... EUG 2 _.__.._. _.__.__..._ .__........_._ _._-._._._.. .__.._.. __._... __._ _ ._ _ ....._.... __.._..._. None ._.._._. ..____. ..._.. ........_..._.. .. . .__._.. _._......_.. None ..._.._..... EI G 3 SDI None

.___.._. _- -- .___... None

_. ._ ............. . None

.. . . .__.._... N one

_._._._..._ ._ None

..__.__.__.. None

. ..._.__.... None

.._.......... .. __. None

....____ 

### N

_...__ one ...__._.___ None

_...._... None _._. _. None _._.__.. None

. .._....__. None

. _ ....._._.._. ft i G 3 SD2

. . None

.. .___ .-_ .... None

.. ............. None

_ . . None

._.__..___. ..._. None

._.._ ..__. _ ..__._ None

. .. _....___.. . None

........_....... ....... None

..__._ None

..._.___. None

._.... None

..... None ..__.._._ None None

._._._.__... EU(;a YDsI None __._.._.... None __...__. None

-. ._._.__._. _...___..._.

None None .......__....... .. .._..._.. None

. __ .._......._... None

......._..__ .._._.__.

None None

. _ ............... None

..... None

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__._... None

_...._.._ None 61 t'G 4 VDs2 None

. None ._ .._._._ None

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._._._.. ... .. None

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.... ..... ..... None

.._ _... _ N 

### one
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### None None

. . None - _.__- No 

### ne

_. 

### Non e

._._. EUGS-FVSt

......... __....._.. . None

..___._ . _..__... None

. _ ...._...._.. None

.. . ... None

.............. ..__ None

_...._. .__._.._- None

. ... ._._..._.. None

.__..___. .. None None ._......._._ None

._..___ None

. . None

. . None

. None EUG 5- AA'S2 3.64

_._.._.. . ..___.._. 4-43

_.._....._.. 7.73 ..._......_. None

..._._.. None

.--.._ None

. . _ None

. ..... ..........__.

None None - _......._ None

_..._.- None

....... None

. __- None

....___ None

__..___. EUG 5-'Trim None None None None None None ~ None None ~ None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut dow•n for maintenance to do the PM. PROCESSES AND EQUIPMENT INVOLVED: (2) \Vet Scrubber 02 CORRECTI VE M EASURES TAKEN: (2) Cleaned nonles, fdters, Ousbed out Ones, and restarted the scrubber.
ADDITION'AL INFORMATION*: The \Vet Scrubber was maintained and operated accordmg to the manufacture's instructions. The repairs and mamtenance were done as quickly as possible, utifbing overtime irneeded. 1 certify, based on utformation and betief formed after reasonabk inqurcy, the statements and inforntation m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: = No AGEYCY USE ONLY TrackingNumber: TeamlD: DateSubmitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supponing information. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown ®AC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 4/30/09 

## NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 4/29/09 4:30AM SUBMITTED: SUBMITTED: 50 Minutes 

## EE ID #, if a licable: 4/30/2009 4/30/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean nozzles, thermocouplers, and flushed out lines. The scrubber downtime was as short as possible to cornplete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance 

# procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. I~ 

# 71



# DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

### - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- - - 7 -- - - - - - -



# (4) The facility was operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipluent not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to rninimize einissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scr
- ubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible.

— - — - — - — - — - — - — - — - - - - - - - - - - - - ---- %- = - - - - - - - - - - - - - - - - 

# The owner or operator's actions during the period of excess emissions were documented by properly signed, conteinporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

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# SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fon

-

n # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENV(RONMENTAL QUAL(TY AIR QUALITY DIVIS(ON PO BOX 1677 OKLAHOMA CIiY, OK 73101-1677 

# EXCESS EMISSIOIV FORM OTE: The infonnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a pret•ious port, provide only the cotrected infortnation below, sign the certification, and attach a copy of tlte previous report.
REPORT DATE: COM PANY NAM E:

5/8/2009 DaNtatia NAME OF INDI VIDUAL REPORTING: TITLE: PHONE: RicklWlliams Plant ManaBer (918) 683-4043 FACILITY: COUNTY: PERMIT NUh1BER: DaNtalia Muskogee 2004-198-TV (M-I) DATE AND TIME OF EXCESS EMISSION: Date Start'time: StopTime: Duration: 5/S12009 0:00 0:00 0:00 Hours:Min Phase 1

6:25 7:18 0:53 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:53 Hours:MinutesofWetScrubberpowntime APPLICABL6 LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Pernrh No. 2004-198-TV (M-1): Specific Cond'nion l, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTcsti. ~~ X .._._._ . . ._..__. . ..___.....__...... .. SOURCE GRP HF HCL SO i CO VOC NOx PM EUG I ..__._ _.........__ ..... _. .._.._._. ._._.. ......... ........... _....___. .. ..._..____ --- _..._..._. ..
_._ ...._.. . _... _ _.... ..._.__.. ....._.__ __.._.._._. Cont Fmissions Monitoring ._._... __....... .._.....__ ....__ EUG3SD1 ......__ ...._. 0.45

.. ...._.._ 0.00

_ .._._.._... 0.19

. .___.._ . 7.32 ~

...._._._._ . _._ 2.53

_..... ......_._.. 2.30

........__ . 4.57

.._.__..._ ._ Enginccrin g C l lcut ' n~ n X

.___.._ . _._._.. _...___. EUG 3 SD2 _..._ .. . 0.25

_.... _.._..._ 0.00

.._.__...._.. 0.00

. _._.._._. 5.50

. _. 0.85

.._. ._..___. 1.79

_....,...._. 2.35

_ . ._ Operating L

~~ cs X ..__.-- __..._.. _........ ._......... ..._.._... EUG4 \ - 1I5t

. 0.03

._...._. __._.. 0.00_

._ _ 0.00

_.__.... _ .. 6.86

.._..___. . 0.86

_ 114

. .._. . 2.97

. .

_ _ . Other(explain)

...__.__ . ._....... . ._..

~ EUG

~ t \ Ds2 _. . _ . 0.oi

.....__ __.. 0.00 ~

_. . _ _0.00

. . 3.55

._...- . 0.45

. ._...___ 0.70

. ...._ 1.54 .._ ___..__ ___.... _. ....__._ ..._ .... _ .. EUG-S-\\bl

. . ... _ 0.01

.._ ._....-. 0.t6 ~

_ .. .._..._.. 0.18

_ . . 7.18

. . - OA7 _._. , ..._._.._ 2.44

. . __.. t.4a

....... __ .__._._ .. _.___. ........_ EUGS-\\S2

.. ..... . -- ~ 4.93

_....._.. ..._. 5.86

._ ...._.... t6.22_

_ .. 10.67

....._ 3.17

..._... .... 4.20

. .. _... 5.7t

. .. ._ . ._.._._ ...._.... . ...._.._ ... ___. .......__ EUGS-'1'rim 1.35 L72 3.83 2.69 0.74 1.04

. ~~ 0.80

.. ..... . . . ....._.__ ...___. . . . _.___. .__ _ Attach supportin8 data :1LLOWED EMISSIONS: SOURCE GRP HF HCL SO r CO VOC NOx Pi•1 EUG 1

... .... .. ... . .. .__ . . ..._._. .__..._. .. . . .

_ . EUG 2

. ._ . .____ __.. _._. ........... ._ ..._ .__ .. ....___... ha G3Su1 _ .. .. .... 0.59

.. . ....___ 0.10

. ..._.__ . ~ 0.45

. ._....__ . 13.77

__. .... 9.67

_...... _ 3.88

.

......_.. 7.98 ._._.._.__. ......__._ Ci

~ G 3 SD2 0.95

. __...._ 0.90

.._..,.__ 0.45

.. ....__..._. . 13.77

._....... . _._..._.. 9.67 ._.._.. 3.88

....... 7.98 ......._....___..._..._. EI G i\

~ o,i 0.72

_ -._._.. 0.08 O.IS

. ...._ . 1t.43

. _.....__ __.. 38.33

.._..._ .. ..._..._..__ 3.51

. ._....... 5.85

.._...__.... _____..... El~~ .(;4 \'oti?

. 0.52 0.06 ._ .. ___....._. 0.08

. . ___._.._._ . . 5.09 .__ . 17.04

..... .. ......._...._ 1.56 2.60

. __ EUG ~-~~SI _. ., .. _ tA3

... .. . __.._.. 1.60

_. . . ...._.___.. 8.96

._..... ....... 19.60

. ___. ......._ 4.78

__.... . 7.73

. _.._._.. 6.7 1

__..___......_._._ EUGS-

~~~ 52 ._,_._... IA3

_.__.._. 1.60

._..._._._.__ 8.96

......___._.._.. 19.60

__.._._... 4.78

_._........._.. 7.73

.......__ 6.7 1

.....__.._....______._. EUG 5- Trun 3S7 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on 1 hour (imits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO, CO VOC NOx PM HB HCI SO i CO VOC NOx PM EOG l _...__ ._._.._ ._.__.___... .._..____ ._.. _._. ...........__. .___.....__. .- None - .---......_ . .._ _. __.__... ......__ ..... .. ........ _._ . .. ......... ._.__..._ None __........,. ICI' 2 .__ ... ......... .._. ._.. . . .. .__.._ .... .. _. ._ ...__.._ _.. _ _._.. ...__.__...... . .. _..... ..__ . . None ._. _._._.... _ __.....__...... ...... _. ...... ........_.. ._.__._._ None ...._... . EI:G 3 SDI None

...._......... ~ nnr None

.. . Nnnc

. ........... None

......._....._.. None

. _... None

. __. None None

..._.. ................_ ~ onc

._. .. None

.._.. None None

. _......__... None

__..._._.. ECG3SD2

. _. . None

.. ... ...... . None

.. ..__._ None

.._.___._. .._... Yone

. _.... None ._.._ .. ...... .....- _ None

.. _ .. ._..._._ None

..__._.__. .. None

.._..... None . _..._..__.. None

_............ None

_.... None .._.___. . None

..._. None

_.....__... CI

~ C 1 VDsI None .......__._ ~ one _. . None

...__.....__ ..._..__. ~ one

. .. ..._.. None _._.. ..__ _._..... Non e .__._ None

.... ....._. None

.. . ... None

.. ___..._. None

... .... None

... .. None None

. .. _... None

. .. _._. Pa G 4\'Ds2 ~ None

...... ......_. None

_. .._.__ None

.._. _....... . _. None

.__... .._ None

._.._ . None

. . _... None

.___...._.. _...... None

_ _.._ None

__-.....__. N

bne ___._....... None

_ ._.. None _._...__ None

. . None ......____ CI;G 5-\\:SI None ....__.._.... None

_ ............. None

~ nne
. ..._. None

..._._..._ None

. .._....___._ None

__...._ None None

..__.._.__._ None

....._.__ None

.. ..._.__._.

None None

. .......... None

- ..._._...-.... CI GS-N"S2

. 3.50

......_..... 4.26

.. . . 7.26

.....__. None

...._.._ . . . ._ None

..__ .._._ ..._..._. None

._._..__. None

._._ ._ ..._ _... None

_... .. i9one

_ ............ None

.__ None ._ . ._ .. None _._ _ None

. None EUG 5- Trim None None Nono None Nono None None None None None None Nono None None N ATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down due to the scrubber ilow below 500. PROCESSES AND EQUIPMENT INVOLVED: (2) Ni'et Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) Found tank low on w•ater, cleaned fdl sensor and novks, Oushed the lines, and restarted the scrubber.
ADDITIONAL INFORMATION*: The 4Vet Scrubber was maintafned and operated according to the manufacture's instructions. The repairs and maintenance were done as quickly as poss8tle, utObing overtime if needed. I certif}^, based on informatiun and betief formed after reasonabk inquiry, thestatements and'mformation m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Dafc Received: Received By: Demonstration of Cause Submitted:

= h ` o AGENCY USE ONLY DateSubmitted: TrackingNumber: Team ID: # If you wish to notify the DEQ about a teehnological limitation, do so here and attach supporfing infoanation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OI+ ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause laeport Form

for IYlalfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be subinitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 5/6/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/5/2009 6:25AM SUBMITTED: SUBMITTED: 53 Minutes EE ID #, if a licable: 5/6/2009 5/6/2009 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in perinits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a nonnal or usual manner. The wet scrubber was shut down due to the sudden malfunction causing the scrubber flow to drop below 500. This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing elnissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Form # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

— - — - — - — - — - — - — - — - — - — - - 7 -- - - - - - - - - - - - - - - - - - - - - - 

# (5) The amount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of inalfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minimize emissions.

--------------------------------- --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any iinpact of emissions.

----------------------------------------------- (7) Emission inonftoring systems capable of producing valid data were kept in operation if at all possible. IM A

----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were documented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recurring pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recuning pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

# OKL.AHOMA DEPARTMENT OF ENVIRONMENTAL QUALfTY AIR QUALI'f Y OIVISION PO BOX 1677 OKLAHOMA CRY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above %vdthin 10 working days afier the immediate notice is given. If you are using this form to correct a previous port, provide only the cotrected infonnation below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

5/152009 Dal-Italia NAME OF IND[VIDUAL REPORTING: TITLE: PHONE: R(ck \YiOiams PFant htanager (918) 68,i-4043 FACiLiTY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start T"ime: Stop Time: Duration: 5182009 9:50 10:10 0:20 Hours:Min Phase 1

9:50 10:10 0:20 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 0:40 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMtTATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianccTesting X .__...___ . _....____ . ........__.. .._._..__ ......_. SOURCE GRP HF tiCL SO, CO vOC NOx PM EUG f ._..__.._ .___._. _._..._._. _....__. _......__._... ........._ _ ... ..... ....._._........ .._..__._.. _ ._.......__ EUG 2 _.._... . ._..._. __.._ _. ._._._... _...___..___ ....__. ._......._.. ....._...._.. ._. __.........._... .__._...__.. Cont Ernissions Monitoring ......_... _ ............. . ......._ , _._...__. _ EUG3SDt _.._.... 0.43

__.._ ........_._. 0.00 0.18

_._.__..,......__._._. . 6.94 _.......... ._.._.._.. 2.39

_.......__..... 2.18

..._....__..... 4.33

._...__.._....._._ FitgineeringCalculation X

_..__... ....__..__. .__..._._. .._. .._.-_._... EUG 3 SD2

. _._..... .. 0.23

. ...._..__..._ 0.00

._.._.._. 0.00

. ..____.. 5.06

._........... ..__ 0.78

_.._. . ..__._.._. L65

. .__._. _...,.. . 2.16

. _......_._.. .. ... Operating Logs X

__.._..._ ......_. __...... .... ..__ . EUG 4 VDsI .___._.. 0.03 ......._ 0.00
_ 0.00 _ _..._. 6A3

..

.._.__ . _ 0.81

__.... . _......_... 1.26

..._ .._... 2.79

. . . Other (explain)

........_. ._....._ ..__. ___... . ._._....._.. . .______.. EUG4YDs2 0.01 .

_ 0.00

.... ....._._..._ 0.00

. . . . . 3.47

_._. . .._._ 0.44

._.... _. ...- 0.68

.. ..._._... 1.51

.. ............ ...._...... ............. EUG 5- WS I

. ___._.._..

1.12

.. 1 13

_. . ._.__._.. 3.67

. ...._ 2.42

.. . 0.72

...._.._.._ 0.95

. .__._ t.29 __..__ ._..._._.. ........_.. ...................... ..-__- EUGS-\\'S2

.... ... _..___... 2.01 ..__ 2A0 _.. .. _._.__ 6.63

_.._....._ 4.36 ._... 1.29 1.72 ...._... 2.33

...._ .. ~ _.... ......_.... .....__... ._._...__.. ......_.__. EUG5-Trim 1.53 L96 4.36
- ~~ - 3.06 0.85 1.19 0.91 .._.___ ___.._. ...._.._.. _ ..._.._ . _..._. Attach supporting data ALLOIV'ED EMISSIONS: 

### SOURCEGRP HF HCL SO z CO vOC NOx PM EI1G 1 .....___. .. _.. .... .....__. . ______.. ............. ... .. ....... ............. .. ....._...__ _ _. _...__... . .. ... .... ._... LI'G 2

_____ ..__ . ... _.___...._. ._.__.._.__ . ..__..._.. _. _.__. ..._._...... __ . . .._..___ ............ .__..._... F( G 3 SUI 0..59

--__- . _._. 0.10

... .___..__. 0.45

. _....._..._ 13.77

...___.... _ 9.67 3.88

. .._... 7.98

...__..._........_.....

. [1'.G 3 S

~ ? 0.95 .._..... 0.90

.. .........___ 0.45

. __.......... 13.77 9.67

. ....___._.. 3.88

_..._... 7.95

........_... .__._..__. EU(:4

~ - usl

_ 0.72

..._._.. ._.._._..... 0.08

_._._..._.._ 0.18

... _.._..._._ 11.43

._..__.___.... _...._ 38.33

.. ............ 3.51

_....._ 5.85 .._._..___..__.__._... F,l'G4VD,2 . 0.52

_.._ .. ....._ ._. 0.06 .__...._ 0.08 ...._...__. _ 5.09

. .._..___. 17.Qi .._._... 1.56 ._.__._._ 2.60

_........_. .._._.. EGGS-%

~ :til .__...__.... _ 1.43

_. 1.60

.._....._.... 8.96

......____ . 19.60

.-_...._._._ .. ._... 4.78

..___. ._...._..._ 7.73

_....... 6.71

.........__. ....__.. EUG 5- ~~.~2 __.... . .. 1.43

_._..... 1.60

.._ _.__.._..__ 8.96

.......__. . 19.60

...._._.__ . .......... 4.78

.............. 7.73

._.._.... 6.71

_._..........___..__... EUG 5- Trim 1 3.57 1 3.88 1 9.68 1 6.75 1 3.67 1 2.00 1 1.80 EXCESS EbtISSIONS: (based un t hour Ibnhs) EXCESS EMISSIONS: 24-Hr Totats SOURCEGRP HF HCI SO i CO vOC NOx PM HF IICI SO i CO VOC NOx PM EUG I

. .__.__... _._.___. ._.._.._ ._ .............__ ___._.. .__....____. _ ._.. _ __._. ._...__..._. ..._._.... None __..__._.._. _.. ___.._.. _.__..._.. _... ..._.. ......__.__._ ....._....._ None ......_.. EUG 2 None

.. .. .._._._._. . ........ .... ._ ....._..... ......._. None ._._. _. EUG3SD1 _....__ . None

.._.__ ._.. None

..._ ._......._...__ None

...._..__.. None

_...__.. _. ...._.._ None

. _..___.._ None

_. __._ None

. .__._......_. _ None

......._.. . None

___..._ None None

..._.. .._ None .__..._... None

..__.._... None

____._... EUG3SD2 _.... __.. . None

__.._. ..........__-- None

- ..._..__ None

..._....___. None

. ...___... ._._ None

.............. .._...__ None

_._.,..... None

.._......... _....___...

None None

...._...___ None

....._. None

..... None

._._..... None

............ None

__.__. 

### E['G 4 VDst ..._ _... 

### None

_......_ _...__..._._ 

### None ._._....____. 

### None

, ......__.... 

### None

.__.__...... 

### None

....._..._... 

### None

. .___._... 

### None None None

. _........ 

### None

..___ 

### None _.._ .........___



### None None

......._._... 

### None

.....__. EOC 4V'DS2

_...._.__._._ None ...__. None

__.__..__. None

. . ...__.... None

_ None _..__. .. _._.._.__._ None

. ..,__.___._ None

._.._...._... _. None

.._.... None

.._._.... None

............. None None

........... None

_..,....... None

.............. 

### t`['G 5-"51 None ._..._. 

### None .__.__.._ 

### None

. ........._... 

### None

_.....__.. _....._...._...



### None .._._...._. 

### None

. ...._....__. 

### None

......._.. 

### None

........_. 

### None None None ._.__.. 

### None

......._.... 

### None

..._...... 

### None

....._.... Lt

~ G 5- tN

~ S2

. 0.59

- _.. ....._... 0.80

._. ......__ ....... None

............... None

._.._._. .__..._.._ None

. __.__.._._.. None

. .._.. _.__._ None

. _.._... None

...._.__ None

........._ None

._... None

..... _ None ._.._... None

_._.._... None

__..._. EtiGS-Trim Nonc None None None None None None None IVone None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) The scrubber was shut down due to a power fal[ure caused by bad weather. (2) The serubber was shut down due to a power failure caused by bad weather. PROCESSES AND EQUIPMENT 1NYOLYED: (l) Wet Scrubber£tl (2) N'et Scrubber N2 CORRECTIVE MEASURES TAKEN: (1) Restarted the scrubber, no probkms. (2) Restarted the scrubber, no problems. ADDITIONAL 1NFORMATION * : The Wet Scrubber w'as mamtamed and operated aecord'mg to the manufacture's instructions. The repalrs and mamtenance were done as quicklp as possible, utilbing overtime if needed. 1 certify, based un inforntation and be8ef formed after reasonable mquiry, the statements and information in thg document are true, accurate and compkte

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submittcd:

= No AGENCY USE ONLY TrackingNumber: Team ID; DateSubmiuel:

' s If you vish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form k100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for 1VIalfunctions OAC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days affter the occurrence has ended. For those that report quarterly it rnay be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 5/13/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (lYI-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/8/09 9:50AM SUBMITTED: SUBMITTED: 20 Minutes EE ID #, if a licable: 5/11/09 5/13/09 

# ***The owner or operator must dernonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden arnd not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due to the sudden malfunction caused by a power failure.

This failure was not reasonably preventable. (2) The excess emissions did not steln from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions.
DEQ Fonn # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and fmished as quickly as possible, using overtime as needed.



# -------------------- = ----------------------- 7 --- 

# (5) The amount and duration of the excess emissions (including any bypass) were minimized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required. Repairs were started and conducted as quickly as possible to minimize emissions.



# --------------------------------- --------------- (6) Reasonable steps were taken to minirnize the finpact of the excess emissions on ai
- nbient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission monitoring systems capable of produciiig valid data were kept in operation if at all possible.
m

----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were documented by properly signed, conteinporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.

7 - 7 ------------------------------------ 

# (9) The excess emissions were not part of a recurring pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recuning pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.
SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE 

# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALriY AIR QUALrrY DMSION PO BOX 1677 OKLAHOMA CffY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 working days afler the immediate notice is given, lf you are using this form to correct a previous epon, provide only the cormcted information below, sign the cenification, and attach a copy of the previous repon.
REPORT DATE: COMPANY NAME:

5!812009 Dal-Itafia NAME OF INDIVIDUAL REPORTING: TITL& PHONE: Bd Sntart Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: DaFltalia Muskogee 2000.-198-TV (M-I) DATE AND TIME OF EXCESS EMISSION: Date Start Titne: Stop'[5me: Duration: 5f14/2009 0:00 0:00 0:00 Hours:Min Phase 1

10:30 11:30 1:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:00 Hours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-t): Speeifie Cond'Nton 1, EUG 5 ESTIMATED E81ISSIONS: BASIS OF ESTIMATE ComplianceTcstine X - _. ._....__ ._._.._. ............. SOURCE GRP HF HCL SO s CO vOC NOx PM EUG 1 ...__.. . .....__ __... ._.__.._. ........_. ...__ _....___. __.__..... _.._....... __........ EUG 2 ..._.__ _._ . _ ... . ....._ . _ . . ._ _. Cont Fmissions St°nitm

~ ing ___...._ . .._._._ . ._.... . EUG3SD1 . ___... .. ._ . 0.40

... ...._. .._..__ 0.00

.._ .... . _..___. 0.17

._..._.. 6.

~ 11

.......... .... . _._2

......_.._. _.__..... 2.02

........_. .. 4.02 __.. .. . . -.-. ~~~ - EngineeringCalculation X

._.__.. ....... _-_.. . .._...__._. ___........._._ ... EUG 3 SD2 .-_...._ 0.27

..._._.. . 0.00

_...._._.__.._ 0.00

..._._. 5.95

.._._.. __......_ 0.91

......_....... 1.94

.......__ 2.54 ....._..._ ..___.._....._. Operating Logs X .._____._. ..._..._...._. .__..._... ..._. ._._.. EUC4VDs1

.. . 0.03

__.._. . .._... 0.00

.._ . ..__..._.. 0.00

.. ... ...... 6.38

_ _... ._ O.RO

..___ _ ___...._ 1.25

.. .._. 2.77 Otha(cxplain) _._.___ ..._...._.. . . ,..._.._ ....__._._ ...._.._ EUG 4 VDs2

... ... 0.01

_ _ . , _ 0.00
_ _ . _ _.._._._.. 0.00

.. . ............. ?.>G

. OA5 0.70

.. _..._. -._. ,

1.:4

. ..... _...._ .... __..... . _ _._._.. ..._._._ _.. _._. EUG5-\VSI

.. 0.01 ~

_....._. .. .__..._.. 0.15

. .___... 0.t8

..... 7.01

...._..... . 0.46

_ ....___. 2.38

. 1.l2

._. ._.__.. ............ . ........... _.___._ ._... .... EUG 5-\YS2 6.41

. .__.._ 7.63 ..._ .. _.._._.. 21.10

.. .._. 13.88

_....._._ ~ 4.12

.. .. ... ...... 5.46

. . . .. ..__ ~ 7.43

. _.__.._. ...... . ... ............ . .............. ._._.__._ ....._..... EUG5-Trim 1 - ~ 152 1.95 4.33 1 3.04 0.84 1.18 0.91 __...___ _._....._. .....__._._ . .__..__ __._.. Attach supporting data ALLOWED EMISSIONS: SOURCEGRP HF HCL SO z CO vOC NOx PM EUG t _.. .__.... ._.__ __. ..__.._._.__ _........... .__........ _... ....._. .....__.._..... .._.....__..__ .._..__.__..._......._.. Et'G2

. .__ _ _...... _ . . .. ........... ............. .._._...._ _ __._.. . _.___....._ . ......_._.... ........__. .__.... EI'G 3 SDt 0.59 .___._...._ 0.10 ..._.._._._.. 0.45

.. ...._.. 13.77

......... _._.__... 9.67

.___._.__.. 3.88

__...._ 7.98

._.._.._...._....._... El'G 3 SD2 0.95

__.. . . _ 0.90

... ...._.....__ 0.45

_ ..._.... t3.77 ._. 9.67 3.88

. .._._.... Z98 ....___ rU(:aV"Dsl 0.72

._.__.. . .___... 008

_.._ . . .__..._.... 0.18

.....,..... It.43

.....__ _. 384i

._...._ _......_..._... 1.51

. __.___. 5.85

_.... _._....._..... PI : a t'D.t? (: 0.52

. _.___.... 0.06

._...._.._ 0.08

_...__._. 5.09

_..._....._ ._._.__ 17.04

...__._.__. 1.56

. . 2.60

____..._.....__.. EU(:5-\\"Sl

_ 1.43

. ...._..__. 1.60

.... ...__._.. 8.96 19.60 4.78

_ ._._. .....__ 7.73

. ... _ _ _...._. .. 6.71

. _ EUG5-\\S2

_._ 2.85

_ __ .....__ 3.20

_... .._........._. 17.92

__._._.._. ......___..._.

39.20

. ...._- 9.56 t5.45

..... .......... 13.42 EUG 5-Trim 1 3.57 3.88 9.68 6.75 3.67 2.00 L80 EXCESS EMISSIONS: (based on I hour 6mhs) EXCESS EMISSIONS: 24-Hr Totals SOURCEGRP HF HCI SO, CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUC 1 ._.. _.. . _ ..._....._ . .__..__ ..._ _._..._ ......_._.. . .. -._ ..___.._ .... . _..... . _ ...._.___.. . None ._ _ ......... .... ......_._ ...._. _._.. _ _..... . _...._... None

. ._......_.._ EItG 2

... _ ._. . _ ... ._._. ........ ..... ._..___... ..______ .. . .._.._._ _...._..... . . __..._.._. . ... _..._._.._ . None _.__._._. __. . ...._._.._ . .. __.. ......._.._ ......._. None _...___.. ECG 3 SD1 ..._.. . None

____...., _...._._..._ None ._._.__ None

__....__. . None

...._.._.__. _.__.. None

_.__.. _. ____...._ None

... ...._ ._.__.. None

_....__.... .._. None

_.._.._.... None

.... None None

......_.__.. None None

......_.. ......_._._. None

. ...___.... EUG 3 SD2 None

_ . None

.__....__ None

_..__.._. None Nonc

.._....__.._.___.._...._ None

_...__.._ .... None

............_.. ._..._

None None ....__...._.._ None None None ._...... None _._...__ None ....._..- EI

~ G 4\'Usl

.. None

_..__... .__.._. None

._.. ._._ _._. None

_....___. None

......._.. .. . _. None

_.._.. ._ . ........... None

. .. None None None _._.__-... None None

_._...__ None

........... None .._....._ None

.. _.__._. FI'C 4 VDs2
_ None

__..... __...... None

._._ . . None None

.... None None

.. None

. _......_. . None

.._.__.._ None

. .. None

.. None ._. None .._..__. None

.__..._ None

. __._.... I:t

~ G 5-

~~ ti1 None

.._..._._. ._..__ None

.._ _......___ None

.._....__ None

...__._._ . ...._ None

._.___ ..._._..._.. Nono

.. None

. ..__..__._ .. .. None None .._..._._ None ...._.._._.... None None ....._._ None

._...._ ~ None

.........._. t't'G5- N C~ ? ..._._....

3.55 4.43

_._ .._..._._ 3.18

.__._. None None ___._ ........._...__ None

...__.__. None

._. . None __.-._... . None

.__._._ None ........_._.._. None None

... None

.......... None

......_._.. LGG i-Truu 1 None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS E671SSION: (2) The scrubber was shut down ror maintenance to clean the sludge out of the entpenger port. PROCESSES AND EQUIPMENT INVOLVED: (2) \Vet Scrubber 92 CORRECTIVE MEASURES TAKEN: (2) The sludge was eManed and the serubber was restarted.
ADDITIONAL INFORMATION*: The \Vet Scrubber was mamtained and operated according to the manufacture's instructions. The repairs and ntaintenance were done as quickW as possRtle, utiruing overtmte if needed. I certify, based on mformation and beGef formed after reasonable inquiry, the statements and'mformation m this docuntent are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Reccived: Received By: Dcmonstration of Cause Submitted: 

## ON° 0 Al;ENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: * lf you wish to notify the DEQ about a technological limitation, do so here and attach supporting infonnation. DEQ-Form #100-920 Re4ised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAIIOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for IVlaintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dat-Italia 5/15/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIIVIE, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/14/2009 10:30AM SUBMITTED: SUBMITTED: 60 Minutes EE ID #, if a licable: 5/15/09 5/15/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess einission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean the sludge from the empenger port. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# (4) The facility was operated in a manner consistent with good practice for mminnzmg emissions; provided,

however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipi

- nent not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.



# --------------------------------- --------------- (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA 

# — - — - — - — - — - — - — - — - - - - - - - - - - - - ----- %- = - - - - - - - - - - - - - - - - (7) The owner or operatoes actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.



# T —- 

# — — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — cjrtify, ba7ed on inf r

ormation and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised November 5, 2007

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The inforntation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous epori, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

5/22/2009 DaFltalia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Ptant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: DaI-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 5/I812009 0:00 0:00 0:00 Hours:Min Phase 1



### 7:20 14:30 7:10 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 7:10 Hours:Minutes of Wet Scrubber powntime APPLICAHLE LIhiITATtON(S) OR REQUIRHMENT(S) EXCEEDED: Perntit No. 2004-198-TV (M-1): Specific Cond"dion l, EUG 5 ESTIMATED EMISSIONS: 6ASI5 OF EST(MATE ComplianceTesting X
_ _.___.. . _,____... . .__ _ ...__. SOURCE GRP FIF HCL SO i CO VOC NOx PM EUG I _..__.. ..__.,_. ......__..__. ..__..._. . .____._._ .... ...._ ._.__... _...____. . _._..__.._. _._. EUG 2 __.__.. . ....___ _._...__ . .._._..._. ..._._._ .._...._...... _.__... Cont Emissions Monitoring ._.____. ._...._ ._........ F'C?SDl

. .. ._ _... 0.36

_.. .__._... 0.00

. ........_ 0.15

.....__._ 5.83

...._____ 2.01

_ _........_. L83

....._. 3.64 .____.._... . _....._.___. EnginecringCalculation X .._.._._. .._.._._. ..... ..._ . . _ _.. .__..

. F:I

~ G 3 3D2

_ .. ....... O.I3 ._. ... __. 0.00

......... ._ 0.00

...___. 2.95 ..__. __. .. . . ._. 0.45

...._.. ._...._._ 0.96

......__ 1.26

.___ ..... .. . .. Operating (..ogs X

........... _.. _.._.._ ___.. . ... ... .._ _ .. .. _. cC(: d

~~ ust 0.03 0.00 _.. .. _. . 0.00

_ _. 6.t7

_ 0.78 _... L21 _... 2.6?

.. . Other(cacplain) ___.._ .__._.... _..... ......_...,

._. Et Ga

~ Ds2 0.02

.. . . 0.00

._ . 0.00

_ . _ 3.60

_....._ . . _.. 0.45
~ .._.._.

.__.-. - . 0.70 ..._.. 1.56

. . . .__.._.. . ____... ._..___.. . _.. .._. __..._.__. E1:G>-}1St _.. ._.._._.. . _... 0.01 ~ ._.._..... 0.17 - ~ __.._ ...._... 0.19

. . .. 7.64

._ . .. _ .. O.aO

..... . 2.60

. _1.55

. _. __..___ . ___...__.. .___._.. ._._... ....._.... EUGS-R52

_ . .. ..._ _. 44.05

. _.... 52.44

. _.__. 145.04

.. _.. .. 95.44

. . ._...._.._. 28.32 ....._.__. 37.-55

__.....__. 51.08

_..._._._ _.. ___..___. ._..__.. ....__.__ ...__... _...._._. El G 5- Trim 1 1.69 2.16 1 4.82 338 0.94 1.31 1 1.01

.. ...____. ...._._. ..____. Attac h supporting data ALLOIVED EMISSIONS: SOURCE GRP HF HCL SO z CO VOC NOx PM EUG 7 .__._... ._____ .... __......._.__ ___..._._ ... . ......... .........._..---.- -......._.. _ ._._.___ _ ......____..__..__ ._.___._ UG 2 E .....__.. .._..__ .__...__... _ __..__._._ . .___.._. .._...... .... _._._ ...__........ .. ._......... . _._.......... _... EUC 3 SDI

... _ 0.59 .._ 0.10

. OAS ._... _. 13.77

...__. . 9.67

_ . . __._._... 3.88

.. . ....._. 7.98

..__.._. .. ___.. . EUC3SD2 _ ..... . .... - 0.95

. ... . .... _ 0.90

_ .. _ .._._._._ OAS

......_ .. 13.77

._....... _._.. 9.67

_.._...__....... ._._ 3.88

. ..._._._.__ 7.98

... ...... ._..._.. EUG 4 VDsI

........ ._ 0.72

.._...__. ........._.....- 0.08

--....__...__. 0.18

........... 11.43

.._.__. .._._.. 3S

~ 3

_.. ....._..._ 3.51

...._.._. 5.85

__....._..._....._.... EUG 4 VDs2 _...._... _ ._...__.... 0.52 ....._._ 0.06 ._. . _.._.__.._ 0.08

.._..__.._... 5.09

........... . .__.._._.. 17.0 ~

............_... 1 S6

._._._. 2.60

....__..._..__._...__ EUC 5- WSI _._... . ._... 1.43

_ L60

. _..._._ 8.96

_._...... 19.60

. .......... 4.78

..__..__..... ....._. 7.73

.......... 6.71

......._...._ .._.___.. EUC3-w52 ..._..__ ._ ..... 11.42

_. .. .. 12.80

. . ___.._. 71.69

, ..._.__. 156.80

__..._.__...__._ 78.24 61.81

............. 53.68

..__.__...._._._.._.. EUGS-Trim 3.57 3.88 9.68 6.75 3.67 2.00 t.80 EXCESS EMISSIONS: (based on I hour IimHs) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF NCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PhT

. EUG t

.. _..__.__ . ........_ __.....__._.. ..._._..._._ ..... .... _.._._ . ........ _._.. ___._......... ...._.._._. Nonr ----. ._..._._ . ..___ _ ..__. . . _ ....._._.._.. __.......__. None ...._. _..-.._.. EUG 2 __.... . _._.. ._._._... ...... . .............. .__._._ ._ _..._._._ . _.. __..._ _...._........_ ..._....._..._.. Nnne __.._ .. _. ._.._._.. ._.......___ . ___._..___..._. .. .. _ .._._..._ None ..._..___.... EUG 3 SDI

.. __ ._.._ . ... _ None

.. _.. . _.__.._ Nonc

..... . _. . _.._....._ None

_..._...... Nono

_.._.._ ... ... .... . .. None

..... . .. . ......._.. . None ..__. None .__._.. _._ .... None

_.._..-_ None .._ . _......_... None None

...__.. .__ None None

_..._.._. None

....._...._.. EUG3SD2 None

_......... ..._._....._. None

....__..._ .... None

... ......._ None

..__.___ . .._.._ None

__._. ...._...__.._. None ..._._._ None .._.. _....-__. . . None

. . None None

. ._...__ None ._____..__ Nnne None

....._. None .___.. EU(:4 \'Usl ._ .... _._ None

..._._.__ . . ... ........__ None

__. ._.._.._._ None

. ,..___... . None

..__...._._.. _...__. None None ......__. None

.._..._ Nono

.....__. _ ...

-

e
- , None ..._.__....... None

.._._......_.. Nnnc \onc Vone None ..___.... E(IG 4 VDs2 _.. . _ ..__ None

_. .. None

.... . ...____._. None

.._.._....... None

..._._... ...__ None

.-..__. ......._._._... None

....._...._ ._.... None

_....._..._.. .... None

.__...__ None

._._._..._ None _. . _..._ None _._... ......._. ~ une

.__ \one ......__.. None

__....... ECiG 5-

~~ 51 ._.._...._. None

_....._.. _ ....... None

.... .._.._.__. None

...._._......._ None

.....__. ..._._ None

__._. _._.._..__. None

.._... ..._...._ None

......._ None

......._.. None None None

._..._..._.____.. None

.. _ tone

.._._.. None

.......... EI!C5-

~~~ 52 __. _ _ 32.63 ._..._._.. 39.64

... _ _ _ ._._...... 73.36

..__.. __.._._ None

....... ..... ...._ None

__. _.. . .. _. ......_.._ None

...._._.._..... None

_ _.... ... 9.79

.. _. __. 14.26

_....__..... None None

_......... ~ one

. _...... ~ one

.. _..._.. None

.......... EUG 5-Trbn None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut dow•n for maintenance to ckan the tank and replace the scrubber packing. PROCESSES AND EQUIPMENT INVOLVED: (2) wet Scrubber tt2 CORRECTIVE MEA.SURES TAKEN: (2) The tank was cleaned, the scrubber packing was replaced, and the scrubber was restarted.
ADDITIONAL INFORMATION*: The Wet Scrubber was mamtamed and operated according to the manufacture's instructions. The repairs and maintenance were done as qufckly as possdtle, ut8bing overtlme if needed. I certify, based on rsmformation and be8ef formed after reasonabte inquiry, the statements and'mformation in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

DateReceived: ReceivedBy: IDemonstration ofCauseSubmitted:

~ No AGENCY USE QNLY TrackingNumber: Team ID: DateSubmitted: * If you ivish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Rewsed February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause lieport Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it inay be submitted with their quarterly report. DATE: COMPANY NAiVIE: Dal-Itatia 5/19/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/18/09 7:20AM SUBMITTED: SUBMITTED: 430 Minutes EE ID #, if a licable: 5/19/09 5/19/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conteinporaneous logs, charts, inaintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to replace the scrubber packing and clean the tank. The scrubber downtime was as short as possible to colnplete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recormnended preventative maintenance procedures. (3) Ifthe excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. 

# m

DEQ Fonn # 100-922 Page 1 of 2 Revised November 5, 2007— - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — :- - - 7 -- - — - — - —



# (4) The facility was operated in a mamer consistent with good practice for mmimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

------------------------------- 11 ~ --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ainbient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Emissions inonitoring systems capable of producing valid data were kept in operation if at all possible. NA

— - — - — - — - — - — - — - — - — - — - — - — - — - — ---- ~ 

### - 7 — - — - — - — - — - — - — - — - — 

# (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.



# T —— - — — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — 

# cjrtify, ba;ed on mf 7

ormation and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Fonn # 100-922 Page 2 of 2 Revised November 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALD'Y AIR QUALtTY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above xvithin 10 working days after the immediate notice is given. If you are using this fonn to correct a previous eport, provdde only the corrected infonnation below, sign the certification, and attach a copy of ihe previous report.
REPORT DATE: COMPANY NAME:

512212009 Dai-Italia NAMEOFINDIVIDUALREPORTING: TITLE: PHONE: Ed Smart Piant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: DaI-ItaOa MuskoSee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 5l19/2009 0c00 0:00 0:00 Hours:Min Phase 1



### 14:00 14:30 0:30 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 Hours:MinutesofWetScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Specific Condition l, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE Compl!anceTcsting X ..._..... ........_. ..__._. ..._..._..._.. .. _. ___.. SOURCE GRP HF HCL SO t CO VOC NOx PM EUGI

.......... ._ ._._..__ . ._....._ ..._.........__ _._.____._ . .. _.._...__.. ... __.. ._.___.__. .__.... .___ . . . ............. EUG 2 ......._ . .___. ..._.... . . _.._..._ _____.._ . __._.__.. ..__.__ _......_......_. . .._...__....._.... ...._..._ Cont Fmissions Monitoring .._..... .._........ ._..__. .......___.._. ......_..__._ EUG 3 SDt _ ...._..__. 0.36 ._.___.. 0.00

_ .._..... 0.16

...___.._. _ 5.85

._.____. ...... 2 02

_.. .__..__...__ 1.94

-. _.._... 3.65

_..,.__.. Cngfnecriny Calculation X

._..._... ...._.... ...____ ._...._...._. EUG 3SD2 ._....... 0 .13

__. ....__.... 0.00 0 .00 ..__..... 2.78

__.._...... _. 0.43 ...___ 0.91

. . 1.19

. ......_._.... . _..._._._ Op

~ 'attng Logs X

. _....__...._. ._..._.._.. . ___._... ...._____ EUG4VDsl _........ _ 0.03

. _ . ...... 0.00

.. . .... ......... 0.00

_..._._. .._ 6.05

. .._.._.. 076

. __......... Il9 262 _ ... _. ... _. . Other(explain)

. ........_. ...... _._._..._ . __....___ . . ... __.- EUG 4 VDs2 O.Ot 0.00

. . 0.00

. .... . 3.52

. _._ O.a

~ l

....... ... . . ._._ _.._ 0.69 ...._ . . I S2

. _..._ . . . __ ..__.__. ._...__ . ._........ ..._.__... _..._._. EUGS - \VSi

. ._ - ~~~-~- 0.0t ~ _..... ... 0.17

~~~~ .. ~~~~ ._ . ~~ - 0.20

_.. 7.74 .....__ 0.50

.. 2.63 1.57

_ ....... .... . .. ......._ ........... ......._ __....___ . . _..____... EUG 5- WS2

.. 3.28

_ . 3.90

.. . .....__. 

### . ~ 10.79

. ..... 7.t0

~ .

.__._._ .... . 2.11".._ _..

.._._ . . _...__ _

i,79
_ ....__. 3.80

........ ._.__... ..._...._. ___. ..._._......._.. . _..___. EUGS-Trim ..._. 

### ._ 1.70 2.17 4.83 3.38 091 1.32 1.01 ' Attach supporting data ALLO\i"ED EMISSIONS: SOURCE GRP HF HCL SO, CO \'OC NOx PM EUGI

.. _._... .. _.._._....._ .__-__.. . _.._..__.. _____ ...._.__.__. ............... ___...__. ___...._..____..._. F!!G 2 .._ .. ..._._. . __.. ._ . ._.__...._. _......_ ..___._ .. . ._. ___ ...._ ..._._.. ..___._. ___._...._ _.___..

. I[I G3SUl 0.59

..._.._.. .......... O.IO

. .___.._ 0.15 t3,77 ..._._...._. .._.._.._..... 9.67 ..._........ 3.88

...._...._ . 7.98

_.__......._._..__._ _ CI G 3 SD2 0.95

-_..... _._._.. 0.90

.. ..._.._._. 0.45

._. .._.__ 13.77

..__... ..._._._.. 9.67

._._....._.._ 3.88

.._...__._ . 7.98

..__._..__..___.._ FI

~ Ca

~ 'u,l

_ . _.. _._ 0.72 0.08 0.18 tL43 _...__. . _.__ 38.33

..._.. . __.. ._.._ 3.51

_..._._ . 5.85

..____....___...,- CI GaV

~ uv 0.52

. ...._... 0.06

.....__... 0.08

..._.____ . 5.09

.......__ .......__ i7.04 156 2.60 EU G

~ - %% ti 1

... . .. ._ . 

### 1 43 .....__ 1 .60 ._. ._.._.. _...__ 8.96

..._......._ . 19.60

._._.._ .... 4-78

._ .. ...__._. 7.73

._. .._..... 6.71

....._._..._..__._....._.. F,t`GS-\1S2

... ....._._ 1.43

_ .... 1.60

... .. ..____.. 8.96

__.__..... 19.60

. 4.78

._..____ 7.73

.. ._.__.._.. 6.71

..__._.._ _......._... EUG S- Trim 3.57 3.88 9.68 6.75 3.67 2.00 t.80 EXCESS EMISSIONS: based on 1 hour limits) EXCESS EMISSIONS: 24-lir Totals SOURCEGRP HF HCI SOi CO VOC NOx PM HF HCI SO i CO VOC I NOx PM I:I`G t ._.__ . .. .. _...._.. ..._..... _ . _..__.. __......__ . . .__...._. ...... ____ __._____ . . . .... ........ None ............_. __. ...__... .._. _._... .__.. __. .......__.._. _..._..... None _......__.... f-l'(%2

_ . __...__ _ __... ._ . .__.._.... ..___....__. ......._.._.__ . __....._..._ .....__... ...._._._____ . None

_ -_ _._._.. . .. _.___... .... _._....... _ ........ .. .......... . ............. None ............_.. F:UG 3 SDi None

........... None

. ._.._..__.. None

._..___._ . . None

___..__.... None None None ..._ None _..__._.. None

_............ None

.._._....... None None ....___.._.. None

........_...__.._. None

. ____._. EI'G 3 S02 None

. ...... None .._ . ._.__...__ Nono

_....._.__. _ None

_..___.._.. . . ._._. None

.._..... ..._._....... Nono

_ ..._______ _ __ None

_____ ____. .. ._ None

._...__... None

.___._._.... None

._..._ None

...... .._.. None None

... ......___ ..__ None

. _............... EI'C 1

~ 'Util

. .. None

.......... None

... . . .. ._._.._. None

_...._.__..._ .. None

. ...._... ___..... None

...__ __._....__ None

._.__.._.. _ None

._ .._ .._._. . . _... None

._...__. None

..._._.......... None

....._ None

...... ..... None .._.__._. None ._.__........... None

..._............. El:(:4 %'D ~~ . .. .._.. None

...__.. _ . .....__.. None

... _.__ None

__._.__._.... . None

. _...__.._.... . ...... _ None

_.._. . . .._ ..__.._.. None

.._.._..._ ... None

. ... ............ . ... .... None

. ....... None

.. _..____ None

. . ._._ None __... . __ _ None

...... None .....___.__ None

.._.._... I ~a~ G c-tt51 None

.. _._... None ._ None None

. __.... None ...__.. _....__._.. None

...__..__. None

.....__......._.. _._ None

.. __._ None

....___._ None

. _. _..._ None

__ . _.. None ___.__. None

_._.._...__ None

. ....__..... L'UG

~ -1152

. _ ._. _. L85

. ._ ._,._.-_.._. 2.30 _.._._ 1.83

. ._..__._... None

......._ _. None

...... . ......_....._. None

._._._ None

_...._.._.... None

..._..._. None

_._._.._.._ None ...__._. None

..... ..._ None _._...__ . None

...___..._.. None

.._..._.._._.. EUG 5-Trim Nono None None None None None None None None None None None None Nonc NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for maintenance to adjust the level of the scrubber packmg. PROCESSES AND EQUIPMENT INVOLVED: (2) \Vet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) Leveled packing material for better absorbtion of beat and the scrubber was restarted.
ADDITIONAL INFORMATION * : The Wet Scrubber was maintained and operated according to the manufacture's instructions. The repairs and mamtenance were done as quiekly as possitle, utiining overtime if needed. I certify, based on information and be0ef formed after reasonable in nquiry, the statements and Information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

DateRcecived: ReceivedBv: DemonstratfonofCauseSubmittcd: 

### = No AGENCY USE ONLY TrackingNumber: TcamlD: DateSubmitted: * lf pou wish to notify the DHQ about a technological limitation, do so here and attach supponing infomiation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be subinitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 5/20/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/19/09 2:00 PM SUBMITTED: SUBMITTED: 30 Minutes EE ID #, if a licable: 5/20/09 5/20/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess einission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contelnporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to adjust level of scrubber packing. The scrubber downtime was as short as possible to coinplete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

# (4) The facility was operated in a manner consistent with good practice for mmlmlzmg emissions; provided,

however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The sci ubber was operated according to the manufacturer's instructions.

----------------------------------------------- (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality.

The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. 

# m 

# ----------------------------- -%_= ---------------- (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.



# - - - - - - - - - - - - - - - - - - - - - - - - - TeeTtTy, ;a;

—

ed

— on - 14o_r_ mat7 ,ou - and be_li;f Form

— eTal 7 ter
— rea — so — natTle inquiry, the statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ Form # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CffY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The infonnation requested below should be submitted to the address above within 10 working days afier the immediate notice is given. If you are using this form to correct a previous eport, provide only the coaected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANYNAME:

5l122009 Dai-Itarw NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACtL1TY: COUNTY: PERMIT NUMBER: DaF(talia Muskogee 2005-198-TV (M-t) DATE AND T1ME OF EXCESS EMISStON: Date Start Tinte: Stop Time: Duration: 5212009 7:40 9:00 1:20 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase 2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:20 Hours:Ntinutes of Wet Sctvbber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Pcrntit No. 2004-198-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComphanceTesting X .._..___. _ .. .. SOURCEGR P HF HCL SO s CO VOC NOx PM . . EUG 1 .....__.... .. . ..._._ _._.. _..._._...._. ._......._ . .....___.. _ . EUG 2

. _. - ..._._._ . .......... .. . - .....__ ..._._ ._..._,_. . .._._. _..__ ...._.......__ _.....__ . ...----___ . . _...._.___ ContF

~ nissionsMomtoring

. ...._._.__.... . __..- _ .. _..._._,. . ._._._. EUG 3 SDl _ .. _._ .. 0.39

. 0 00 _.. .._ ___... . . 0.17

... . ... 6 27

_ . _ __.. _ 2.16

... _ .... ......._ 1.97

..__.___. _ 3.9 1

.._. .__._.... .- Fny neering Calculation X

. . _ ...__..___ .. . .__._.. . ... ...... ... EUG 3 SD2 __. .__ .

0.28

. 0.00

.........__... 0.00

.___......_ 6.13

_..._...__.._....... 0.94

. 2.00 _....__.. 2.62

...__..._.-.,._ . __...__._. Operating Logs X

_ _. ... . ._.__..__ ......_ ._ _._ EUG4 VDsI

.. .. ... ._.... 0.03
...... . 0.00 _. _....__..... 0.00

...._...._ 6.06

__...._ . . ... 0.76

._._. . _........_ LI9

........_. 2.63

_._._... _ __.. Other(explain)

.__.. . ....__..._ .. __._.._. . . ._...._.__- EUG4 VDs2

.. .... 0.02 0.00

. _.._.,_ 0.00

. ..... 3.58

..... ._ 0.45

_..._.... . _ 0.70 1.55

. ............_.. ...._-__._. .._._.._..._. . . ..._..._.__.. . __ EUCS-WSI

.. ._.. 4.65

._---_ ..._

5.53

. .._._..._ ]5.30

, _..... . t0.07

. 2.99

........._... ...._....._

3.96 ~~~ .._..._.....__ . _......_ ...__.__..... . ...__... ..._...._._. EUG 5- WS2

. .. 0.00 " ~ ._..

_ _. _..__ O.Ot

... _.._.__. 0.02

_ . . ._.. IS.lS _...._... 2.53

_ __...__. _ ..

4.88_ ._._. .. .............. ... _.... ___.._. ___._. _.__._. EUGS - Trim 1.67 2.t4 4.75 3.33 0.92 1.30 ~ 1.00 _..._._............ _..._... ._.__. ....___ ......_.. Attach supporting data ALLOK'ED EMISSIONS: SOURCEGRP HF HCL SO i CO VOC NOx PM EUG 1 ...__ .. _ ....__ .. .___...._ ......_. __ ..____._.. .. .___._ ._._...___. _... _.__ .... ._...._..._ ._..._.__...._...___ ElG2

. ._.__. . . _._._._ ... ....._._.... _ _ ......_.__... _. _ ..__..__._____.._. _.- ¢t'c 3 SDI 0.59

_... _. _. _....._._ 0.10

... .___._._... OAS

......._.__ _ 13.77 ._. . ---- 9.67 .._._ . . 3.88

_...__..... 7.98

.._.__.._. ct

~ G}SD2 0.95

.__....___.. 0.90

_....._...__. O.d3

__.._..._. _..__....._...

13.77

. 9.67 __._. .__..._.._.... 3.88

.__....__ 7.98

.._______..._ Et

~ G 11'Usl

.. .._.___ 0.72 ____....... 0.08

.. ---_ _ O.IS 1i.43 ..__._.. . ._..__.. 38.33

...... . .............. 3.51

_.._._._ 5.85

._..__...______.__. Et'

~ C 4 VD52

_ . 0.52 _...... . ....._.... 0.06

... ....___....__.... 0.05

_ __. 5.09

. ..__ 17.04 ..._ L56

. .2.60

..__ ....... ......___.. I:t

~ (;5-\\:SI

.. 2.14

..__.... ._... 2.40

.._ . .___.._..._ 11.aJ

._._.. _ _ . . 29.40

_.__._... ........... 7.17

. ......__._. 11.59

. __..._.. 10,07 ia'CS-\\'S2 _ IA3 1.60 ....___.... 8.96 .____. ...._ . . I9.60

._.......__ ._.._.. 4.78

___.. _._.___... Z73 6.71 .____.. ........__. LGGi -Trim 1 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMtSSiONS: based on 1 hour Omits EXCESS EMISSIONS: 24-11r Totals SOURCE GRP HF liCl SO i CO VOC NOx PM HF HCl SO z CO VOC NOx PM EUG i

. ..__._. __.._.._..... .. _.___ ...___._. . . _...__ .___... ........ _ _._. ._..._.. . ____._.. None ......._._ ._ ..._.._. _.__..._ ._._ . .. ....___ __...._.__ None __...___.. EUG 2 __... .. ..__. .____._._.. _ .. __._..._.... .__.._._. .._. .._.... ..__.__._... .. ..__._._... None .__._ _._., ._.._... ... . ...__.... __. . __.._.._ None t:t

~ G 3 SDI None

_.. .._ . __..._._ ~ 'one

._. .__..__ _ None

._.__....__. _ _ None

..._.._...._ ...... ... None

_...._ . _ _..__.._. None

... .__.____ None

. ..._._ _.. _....._ None

... _ ... Nunc None

.._.... None .__ _. None ._..._... None

__...__._ None _....._.._._. ft

~ G 3 SD2 .._._ None ._. None _.__-..,_... None

._._._... . None None None .._.__...... None

. . Nouc ....__......_... Aonc

_ ~ oue ......__. None None .._..._.._ None

_..._._......_ None

....__.._. FI'

~ G 4 V - D , 1 None

__. ......_.._._ None

_. _ ._...._.._._ None

......._....... ...... __......._

None __.._ ~ ... Nonc

.._.... ._ ............. None

_....._._. . None

...... .._._. . None

._..,_._ ._. None

...... ... _.. None

....__.._. None ..._._._ ..... None

.. None ._...___... None ......_.......... Ct!G 4A

~ ust

.. .....__. None

.............. '`bne

_ _-_....._.. None

.._._..._... None

___...__ ..._ None ......__. Nonc

._____..._. None

...._..__._.. None

..__.__... None

. __..._...._._...__. None None _...._ .. Aone None

.......... None ..__..._.. EUG S-AA

~ SI

.... _ ._..___._ 2.51

. _._.._._._ 3.13

..._...__.. 1.86

...___.. None

............_. None ..._._.. None

- __... Nonc

____..___.__. None

_._._.... None

..._._._.___._..... Nonc honc Vonc None ..___... None ..._..___.... EUG 5-vA

~ S2

.. _.__._. None

._..._ ........ None

.. None None _. ._ _...... None

_.._ . None

.__..._.._. Nonc

._._......_._.. __. None

..____ None ..__._._..........__._

Nonc

_ ~ 'o
~ tc _.. ... Aunr

... Aone

......... None EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut dow•n for maintenance tu change the pumps and ciean the nordes. PROCESSES AND EQUfPMENT 1NVOLVED: (2) \Vet Serubber #2 CORRECTIVE MEISURES TAKEN: (2) The pumps were changed, no'riles were cleaned, and the scrubber was restarted.
ADDITIONAL INFORMATION*: The wet Scrubber was maintained and operated according to the mamtfacture's instructions. The repairs and maintenancewere done as quickt,v as poss8tie, ut8'ving overtime if needed. i certify, based on information and befief formed after reasonable mqurcy, the statements and'mformatfon m this document are true, accurate and complete

SIGNATURE OF REPORTING PERSQN

Date Received: Received By: Demonstration of Cause Submitted: = No AGENCY USE ONLY TrackingNumber: TeamlD: DateSubmitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infomtation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Eorm for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 5/26/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-i) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/21/09 7:40AM SUBMITTED: SUBMITTED: 80 Minutes EE ID #, if a licabte: 5/21/09 5/26/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exernpt from compliance with air emission Iimitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infTequent and could not have been prevented through caref

- ul planning and design. The scrubber was shut down for maintenance to change the pumps and clean the nozzles. The scrubber downtime was as short as possible to cornplete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to colnplete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage.

.

.



# DEQ Fonn # 100-922 Page 1 of 2 Revised November 5, 2007

### - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- - - 7 

### -- - - - - - -



# (4) The facility was operated in a manner consistent with good practice for mmimlzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not othetwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to ininimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

------------------------------- 

### 7 --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. 

# The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Eiriissions monitoring systems capable of producing valid data were kept in operation if at all possible. 

# m

— - — - — - — - — - — - — - — 

### - - - - - - - - - - - - ---- ~ - : 

### -- - - - - - - - - - - - - - - - - 

# (7) The owner or operator's actions during the period of excess emissions were documented 

# by properly signed, contemporaneous operating logs, or other relevant evidence.

Records are kept of the scrubber downtime and the work done.

Te e - r t i — 

# fy, - b a s — e 

# d
- o n — i n 

# f
- o r m — a t i
- o n — a n - d b
— e 

# I i e
- f f
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— a ft
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# b - I e i
— n 

# q - u i r
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— o r - m a t — i o n - i n
— t h i
- s 

# d — O c u - m e — n t - a r e — t r - u e 

# — , accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Fonn 

# # 100-922 Page 2 of 2 Revised November 

# 5, 2007

# OKLAHONIA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CrfY, OK 73101-1677 

# EXCESS EMISSION FORM 'OTE: The information requested below should be subntitted to the address above within 10 working days a0er the immediate notice is given. If you are using this form to correct a previous epon, provide only the corrected information below, sign the eetification, and attach a copy of the previous report.
REPORT DATE: COM PANY NAM E:

615t2009 Dal-Italia NAMEOFINDtVIDUALREPORTING: TITLE: PHONE: Ed Smart Plant Mnnager (918) 6834043 FACILITY: COUNTY: PERMITNUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Tinte: Duration: 5129l2009 0:00 0:00 0:00 Hours:Min Phase 1



### 8:00 11:00 3:00 HOurs:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 3:00 Hours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No.2004-198-TV (M-1): Specifie Condition 1, EUG 5 ESTIMATED EMISSiONS: BASIS OF ESTIMATE ComphanceTcsting X ._._...." ........." "..___...._. ..._.._._.

.. SOURCE GRP HF HCL SO_, CO vOC NOx PM EUG t

.. .__. __. ....._ . ._....__.. ____ ._....".."... ......_.._.... ...._.__... . ..__.._.._. _."_..... ..._...._ RUC 2 ..._ _ . __.... .__.._.._ ."_..__"._
. _.._._ _._. ....._"_.
........ . ......_..._ _. ._ ..__ ._..."_. ('ora Emfasions Lfoniforing .__.... .__._. ._.__. .. EUG3SD1 0.43

.. ___... 0.00

. . ... .... _.. _ 0. 1 9

.._.___. . ."...___.

7.02

__ ...._ 2.42 _... .._.._.._. 2.20

._..._..._ 4 

## 3 8

.__...._. _ Linbi

~ icc:iny;('alculativa X

.__._ . _._..... _._...._ . ..__ _..._.. 

### I:UG?SD? 0.24

__ .. .._.__._ _. 

### 0.00

.. ... .__ 

### 0.00

__._.. . 

### g.3g

_._._.. _..._ 

### 0.83

__. ___._.. 

### 1.75

. ___._._... . 

### 2.30

.._..._...... ..__.... 

### OperatingLogs X

_. .... . _ ___. ....._.. .._._... _ ._......_ EUG4% DO 0.03

_. " 0.00 ._.._. _0.00

. . 639 0.80 1.25
_ 2.77 Other(explain) ....._.. ........_. . .._.._._.. . ._...._. _.. . . el:G a ctn? O.OI

_ __.._.. . . 0.00

....... ~ 0.(10

. ___ . . 3.51 0.44 .._....._ .

.. _.. 0.69

. _. . _ 

### t'{2

. .... _..._.._. ...._... ___... .__.. ...... ba (: 5- v } ti I 0.01 0.16

. _.._. O.IS 7.22 0.47 ~ . 2.46

.. . _ L46

_ .. . _ ._.__.. . ._._.. . .. _._ ... ._ ..."
. ._...__ IUG 5-v,53 19.01 .....__ _ . 22-63

.

.. 62.60

__ .. . _ .. 41.14

.._..._.. 12.22 _._._..._ 16.20

. .. . ._. 22.D4

......... _.. ..._..... ......_. _._.. _. __...... CI'GS-"3"rim 1.63 2-09 4.64 3.26 0.90 11.27 1 0.97 

### .__ .__._. .._._.. "......_... ....__._. Attach supporting dala 

### ALLO\i'EDEMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM Et I G t

_ _...... . _...... . ._ ......... . ..."......_
_ ._._ ...._. . _ .___ _..__"...._. _.__._. . _...._.... ._.__.__ EUG 2

. .- .-- . . . _ . . _._.... ---- ._. EUC.3 ~~~ l .._..... 0.59 .__._... 0.10 _. .___. 0.45

.._. __. _ 13.77

_.........._. . 9.67

....... _............"... 3.88

__.__ . 7.98

____.__...._..._.._.._- 4:UG 3 SD2 ._. _".__ ___..". 0.95 __._.. 0.90

. .. ._._"_"_. O.dS

._.._..___ _ 13.77

._...__".."
........... 9.67

.. _._...._..... 3.88

._ __ .__ 7.98

..__....__. _._.._.__. . 1Cl"G4 ~~t~st 0.72

. .. ._._..__ _ . 0.08 ._..._.. 0.18

..__......._ . lIA3

........._ ._ 38.33

...__ _ ..,_ ..._...__ 3.51

... .__..__... 5.85

.......... ...."...... ECG 4 % Ds' 0.52 0.06 ._ .._.._._ 0.08

. 5.09

__.._.- .._. 17.04

.._. 1.56 2.60 ..__.__ _"..___... EUG 5- \\

~ sl _.. .. .._.__. . 1.43 __.__.. 1.60

. __..._......_. 8.96

.........___... 19.60

......__... 4.78

. _. . .._......-. 7.73

. .. ......."....." 6.71

.__..__.._._....__.._. EUC, 5-

~ \.ti2 ._ . .. 5.71

__ ... . ............ 6.40

.__..._._.._ . 35.84

._._ 78.40

........_. ..___._ t9.12

__. ..... .. _.__..... 30.91

......_._.. 26.84

____....__._..._.__ EUG 5- Trim 3.57 3.88 9.6S 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on l hour limits) EXCESS EA7ISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO r CO VOC NOx PM HF HCI SO r CO VOC NOx PM EUG I

.... .. _. ..._.._ . ....._"_.
.. .._..._._.. ... "___ _.......__. . _...._ .._"
. " ............... .._..__ None ._.._.._._ ......_ .._....... .. ........_._ _ ....._. ._ .._ .._._.. .".."._.... None

~ iCC 2 None . _._ .._.__.. .. ._ _.. .... _".. ..." _. ._ .. _ ......._ .. ._ N .._.._... one "......... El (:J SDI

. None

. _..__._ .._ ___... None

_ _...____ None

_._._.___ None

..___._ . .. None

_.._"......... None

."._".__...._
. _. None

_ _..__..... ..._ None

__--._.. . None

.... ......... None

... ._..._"_ None

__ ___._. None

. None

.. None

. ..._..._.... };l'G 1 SU2

.. . None

......_._ . __...._.. None

_. ..___._..._... None

.".._ ..__... ...__..__._

None ._._..._._. None

._. ..._._...... None

......__.._._. . _ None

.__._..__ ...___.._._..__.....

None None

...._ ... None

...__..__ None

._... None .....__.. None _.._....._ None

_ ._...-..._. P;l'C 4 VDsI

_._ None ___.... None ___._..._... None

.__..__ . None

_ ...__ None

...... .... .....__._.. None

...._ __. None

...___..__. ._ _. None

...__ ~ onc
. None

.. _....._..._ None

. ..... Natc ._..._-... . Nonr None

__..... Gt'G 1\'Us2

.. None

. .. ." ......... None

.. .......__. None

_..._... _. ... None

._._....._- -_ ..._. _ None

._.... . _._._._.".... None

__._._._._. None

_ _ .._._ None ..__._ - ~ one

. None

. .. None

....". Nonc _.......... ._ ~ nne
_ _ .. None F.UE;S- N:SI None

_ _______.... None

.___._.__. None

. None

_..._.__ _.._ None

_..... _ ._.... _.._._ None

_....___ None

..__..__ ...... None



## o, n e... . None

__ .__.._ None

. __._..._._ None

..... ._ None .___._._..._. Yone

__ .. _ None

__.___..._ . P:I

~~ GS-\\'S2

. .. .... 13.30

._..__ . 16.23

_..__..__. 26.75

........._. Nono

_....___ None

.........._...".. None

......... None

.._...._.__ _..._.__.__

None

. None .._...._..__. None .__..._....._ None

. .. None _._._.__...._.._.. ~ one None

. __._.._. EUG 5-Trb None I None I None I None I None I None None None I None I None I None I None I None I None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down for mahttenanee to clean nonks, replace some serews nn the tow"er, and to wekl the ftange around the boBs. PROCESSES AND EQUIPh1ENT INVOLVED: (2) lYet Serubber #2 CORRECTIVE MEASURES TAKEN: (2) The noricls were cleaned, screws were replaced, and the (lange was wekled. ADDITiONAL INFORMATION*: The Wet Scrubber w•as maintamed and operated accordmg to the manufacture's instructions. The repalrs and maintenance were done as qufckly as possiide, utd'ving overtirne if needed. 1 certify, based on mformation and belief fornted after reasonable mquiry, the statentents and inrormation in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Roceived: Received By: Demonstration of Cause Submitted: F____1No E____1 A('iENCY USE ONLY Tracking Number: Team ID: Date Submitted: * If you xvish to notify the DEQ about a technological limitation. do so here and attach supponine infomiation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause 1Zeport Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAIYIE: Dal-Italia 6/4/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 5/29/2009 8:OOAM SUBMITTED: SUBIYIITTED: 180 Minutes EE ID #, if a licable: 6/1/2009 6/4/2009 

# ***The owner or operator must demonstrate each of the following iterns in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting docuinentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down to for maintenance clean nozzles, replace some screws on tower, and weld the flange around bolts. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recorrnnended preventative lnaintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Fonn # 100-922 Page 1 of 2 Revised November 5, 2007— - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — 

### :- 7 — . - . — - - 7 -- - — - — - — 

# (4) The facility was operated in a manner consistent with good practice for lumimlzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not othemise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize einissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

--------------------------------- --------------- 

# (5) Reasonable steps were taken to minimize the impact of the excess emissions on ainbient air quality. The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Eniissions monitoring systems capable of producing valid data were kept in operation if at all possible. OW N

— - — - — - — - — - — - — - — - — - — - — - — - — - — ---- ~ 

### - 7 — - — - — - — - — - — - — - — - — 

# (7) The owner or operator's actions during the period of excess einissions were documented by properly signed, conteinporaneous operating logs, or other relevant evidence.



# Records are kept of the scrubber downtime and the work done.

----------------------------------------------- 

# I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Form # 100-922 Page 2 of 2 Revised November 5, 2007

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALffY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is ytven. If you are using this fomt to con-ect a previous eport, provide only the corrected information belocv, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

6/5f2009 Dal-ttalia NAMEOFINDIVIDUALREPORTtNG: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 BACILITY: COUNTY: PERMIT NUMBER: DaI-Itaria Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Dttration: 615/2009 13:15 13:45 0:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS E:1i1SSION (I(OURS:MINUTES): 0:30 Hours:Minutes of Wet Sctvbber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Speciric Condition 1, EUG 5 ESTIMATED EMISSIONS: BAS(S OF ESTIMATE ComplianceTesting X .___. ._._ _...... _ ..-.....-.. - _ _....__. SOURCE GRP HF HCL SO r CO VOC NOx PM EI.`G 1 - _ . ............ . ........_.. .._ _ .... ____._._ . ....._...._.. __........... ._...._._.._. _.._.._.__... . _ .-____.... . . . _ _EtiG2

. - ._...._. . ..._... ._ . . _.... _ ._. _.__.....__. . . .. - .. Cont Fmissions Monitoring .._._._... -.__... -..__... .. _.__..

_.. .. FItG3SDt 0.43

___ . ... .... 000 ..__. 018
_ _ . . ~ .. ~ 6.87

. . ... . .. 2.37

~ " ...._.

.__ .__......... 2.16

. _..__.. ~ 4.29

. . .__... EngineeringCalculalion X __.__.. .. _. _. ..._. .. . ...__ .__. .. . . . ICt'G3SD2 , ......._. X _...___..._ .._.._ . . . EU(:4\Ds1_......__.003 -- - .. . . _ 000 ._ 000

. .. . . 6.06 076 (.19 2.63 

# -
~~ Other(explain) EU(:4 VDs2

. .__, 0.01

"
... 0.00 __...__ _0.00

. . . 2.60

_._.._... . 0.33 . -- 0.51 -- . .. -

1.13 ..._ --- -- --- '--

....-___. .._._... ......._._. ..__.._._ .__.._. EIICS_\VSI

. _ . ... .__.3.32.__._..._-

.. .... ..."...._. 3.96

.._ .__..._.. 10.94

. _ 7.20 ..._.._...._

...._.. _ .2.(4 -

_ .._.._

...._ . ~ 2.83 .._.

. .,...... 

# ..- 3.85 ,. .... _._.__. . ....__._ ...___.. __.__- __.._.._... EUG 5- LVS2

.. .. - __. ... _ . 0.00 0.01 . ._.._ _. 0.02

. (4.10

. .. ... . . .... 2.36

.. . ......_.- 4.54

. . . .. ., "._. 4.14

. - .___.__ . __ _.._. ...._.._. ....... .. .. ._.__.. EUGS-Trim 0.62 0.79 L75 ~.~ ~ - 1.23 ~ 0.34 0.48

~ .. 0.37 __..._.. . . _.__ .. . _..._.. ...._.. _.__... Attach supportmg data ALL0IVED EhHSS10NS: 

### SOURCEGRP HF HCL SOi CO VOC NOx PM EUG 1

. ... ....._ _...... .._ ..,.__. . .. _.._._.- . ._._._ ...._... ___.._.. . _.. ----- ._. ...___.__. __._..... EUG2 ....."
.. . . _....._... -_.... . ._..__ ..... .. EUC 3 SDi ._ _. _ O.S9 ~ 0.10

. .. _. .... -.__._.. 0.45 13.77

. . . 9.67

.......... 3.88

_ ~ _ _. 7.98

__ .... ..... EUG 3 SD2 _....... 09S

.._ ._..__._ ._ 0.90

.._.____ . 0.4 ~ . 13.77

_...__... . ... 9.67

....... _.. __- 3.88

. __._.... _._" 7.98

_....._ ._._.__._ EUG 4 t'Dct _ 0.72
_ _. 0.08

__ ..- .._. 0.18

....... _I1.43

- -. 38.33

-, .._..__". 3.51

.... 5.85

._... EUG4ti

~ s2

. .. ... .. . O.S2

~ " .__ . 0.06 "

. 0.08

_ _.. 5.09

. -- 1704

. _. . -- . _.. L ~ 6

. . .._... . 2.60

_ - - __...... __..._. . EPC;-tVSt L43 160 8.96 19.60 4.78 .._...._ . 7.73 _.._.. 6-7t

. . _...._. C5-vt til

. . . - .. 1.43 160

. 8.96

- .._ ... 19.60

__._.. 478 ~

. ..__..._. 7.73 ..._. 6.71 .____._..._._. EUG 5- Tr'un -"

1 3.57 3.88 9.68 6.75 3.67 2.00 L80 EXCESS EMISSIONS: based on I hour 1'mtits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF tiCl SO i CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG 1

.. _

. . None _.. _... None EUG 2 " _.. ... ..._.. __ . _.... .. _.-...... ... .. . _ .. .... .... .... . . .._...__.._. None

. . .._.. . - __... . .._..__ ._... _... .._. None

. . _.. EUG3SDt

. . .. ~ None

. __.. . _ None

. ,...._..._. _None

_... ..... None

.. _ - None

.. _..._. , None

_._..._,_. . , None None

_ , None ---, None

...... None_ ._ ~ None .._..._. ...._.._.__

None _..._.__....- None

-,.___.. EUG3SD2 None None

... ............... None

. ._ _....... None

. .. .. __._ None

_....._ -..._...__. None

_... . None

. ..._. ...... None

._._ None

.. _..".._.._ None

_.... None

.. _. None .._ None None

- _,_.___ 

### EUG 4 VUsI

. ., 

### None

_.._.... .__._. 

### None

_... ...__._....... 

### None

_.. _ ..___ . 

### None

.__ . ...._. 

### None

_..__. ._._........_ 

### None

_._._.__ 

### None

.. _ ........... . 

### None

........_ . 

### None

. ___.... .. 

### None

.._..._ 

### None _... 

### None

_ ..... ._... 

### None

-.__._.... 

### None

.. _.._.._ 

### EUG 4

~ 

### 'Ds2

.. . 

### _ None _ . .... . 

### None

.... ........... 

### N

_ one
. . .._ . 

### None

. ...... . ....... 

### None

_...__ .. __._....... 

### None

......_.___ . 

### None Nono __ __.._ 

### _None -. . 

### None

. . ,._.. 

### None ._ _ ._ 

### None None

. .. . . . ... 

### None

.... ...._.... EUGS-RSI

_ ~ " 1.90

._...- ...__...._.. 2J6

- .._. _....__.. 1.98

. ..._.._._ None

.._. _ . ._.._.._..._ None

......_....._. None

. - __ ......... . ._. ..._. ..

None

.............. None _ _-.. None

. ._.......... None

__........._ None

_ ............_ .... ...__- ... None

. None

. .____."..........

None .._._. 

### EU(:5-t1S2 ..- 

### None

. _.._._ .. 

### None

...... . . . ........_... 

### None

. .._..._. . 

### None

_._._... . 

### None

_ __..._...._ 

### None

. .._._._..._. 

### None

._...._ 

### None None ....__. 

### None

._... 

### hone

. 

### None _. .___ . 

### None

____. 

### None

~ .. EUGS-'1'rim None None None - --- None " Nonc None None --- --- None None None None - None None None NATURE AND CAUSE OF EXC6SS EMISSION: (t) The scrubber was shut dow•n fur maintenace to check nonles, fitter, and puntps. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Scrubberkl CORRECTIVE MEASURES TAKEN: (1) Cleaned noides, did visuat inspection of tank, readjusted difrerential fiuw, and restarted the scrubber. ADDITIONAL INFORMATION * : The Wet Scrubber was maintamed and nperated accord'mg to the manufacture's instructions. The repalrs and maintenance were done as qufekly as possible, utOning overtime if needed. 1 cerlify, based on information and beGef formed after reasonable inquiry, the statements and information in this document are true, accurate and compkte

SIGNATURE OF REPORTING PERSON

Data Rceeived: Received By: Demonstration of Cause Submitted: No AGENCY USE ONLY TrackingNumber: TcamlD: Date$ubmittcd: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infonnation, DEQ-Fonn #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# I Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) 

# I NOTE: The information requested below should be submitted to the address above within 30 days after the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 6/8/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 6/5/09 1:15PM SUBMITTED: SUBMITTED: 30 Minutes EE ID #, if applicable: 6/8/09 6/8/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conteinporaneous logs, charts, maintenance records, etc). ***

— — — — — — — — — — — — — --- 7 — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — 

# (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance on to check nozzles, filter, and pumps. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess einissions were not part of a recuning pattem indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures.

— - — - — - — - — - 7 -- — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — 

# (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Fon

- n # 100-922 Page 1 of 2 Revised November 5, 2007

# - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - :- - - 7 

# -- - - - - - -

(4) The facility was operated in a manner consistent with good practice for mmimizing emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not other\vise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

-------------------------------- 1 ~ 

# --------------- (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. 

# The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) Emissions monitoring systems capable of producing valid data were kept in operation if at all possible. 

# m

------------------------------- ~ 

# -= ---------------- (7) The owner or operatoes actions during the period of excess emissions were documented 

# by properly signed, contemporaneous operating logs, or other relevant evidence.



# Records are kept of the scrubber downtime and the work done.



# -F - — — - — — — - - - - — - — 

# ~ i .7 - - — T — - — - — - — - — - — - — - — - — - — - — 

# certify,;asedoninf 7

ormati7onat 

# ~

d7eii;fFormejaf r

terreasona e inquiry, the statements and information in this document are true, accurate and complete.



# SIGNATURE OF 

# RESPONSIBLE OFFICIAL OR 

# DESIGNEE



# DEQ Fon - n 

# # 100-922 Page 2 of 2 Revised November 

# 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALRY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSIOIV FORM NOTE: The infomtation requested below should be submitted to the address above Ntithin 10 working days after the immediate notice is given. If you are using this form to cocrect a previous 

### rep ort, provide only the cotrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COM PANY NAM E:

6/12/2009 Dai-ItaGa NAME OF INDIVIDUAL REPORTING: TITLE: PIIONE: Ed Smart Plant hianager (918) 683-4033 FACILITY: COUNTY: PERMIT NUMBER: Da4ltalia Muskogee 2004-198-TV (M-t) DATE AND TIMB OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 6/12/2009 0:00 0:00 0:00 Hours:Min Phase 1

7:30 9:30 2:00 Hours:Min Phase 2 DURAT[ON OF EXCESS EMISSION (HOURS:MINUTES): 2:00 Hours:MinutesofWetScrubberpowntime APPLICABLE LIM(TATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Specifie Condition t, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE Cmm

~ li;m ~~ Tntin_ X
~ -~ ..._..... ......_ . ....._. SOURCE GRP IIF HCL sO i CO VOC NOx PM EUG I .__...__ . .. __.. _.__...____ . .__.__ . .....___. ._._.__ . ..._ _.. ._..._...._.. ___..._ .. .. __..._.. . EUG 2 

### __._.... ......_. ..._.._... ....____. .......___ .... _..._. . . __...... .........___. .._.._.._. . _ __... _. .... Conl Lini"i,

~ ns
~ funi;o:ine



### _ ._.. ._...._.... ._._...... _.... .. . ....-. 0.41 0.00
.. _ 0.18 . 6.65 ....__ 30 ...._ . _... _ 2

. 2.09
... _ .. _ -.... 4.15
. _ Calculation X _..__.. ..._..... ........._. .Engineerinb EUG3SD2 __.. . _.._.. 0.29

_ ._..__. 0.00

__.._ 0.00

._.._...__ ~ 6.38

. . ......_.._ 0.98

. ....___... 2.08

.__._._... 2.72

..._.....__.. ......__. ~ OperatingLogs X ...._..._ .....__ __ _._.. ..._.._._ EUC4 VDsI

.......... .. 003

_...___.__ 0.00

........ 0.00

.........__ .. 611

. 0.77

..._..._._ 1.20

__.._.. 2.65

. . ._._._.. . Othcr(explain) ......__ . __._. ...__.. ......_...__ EUG4 VDs2

..... ._. 0.01

_..... . 0.00 _...._. 0.00

. . 3.46 _...._... 0.44

_ .. ..._._. 0.68

......... 1.S0 _.___._._. . ...._. _...__ . ._...____. .. _._..._. . _.._....._. . _......._.... EUG5-R'SI

. . . . 0.02 0.29

~ 0.34 13.27 0.86

. __._...... 4.51

._.....__. 2.69 ..._. EUGS-NVS2

_ ... _... i1.63

__... _..._.._ 13.84

. _ ......_. ?8.?3 25.t9 ._.._.. .... 7.47

.... ........... 9.91

.... ._ I;,qg

... .._ _... ..__.. ..._ __._ ..._.__ ...__... . __. __._ EUG 5-Trim 1.24 1.58 ~ 3 Sl 2A7 0.68 0.96 0.74 .____. .. ....__..._. ._.___.. . ..__.- _...._._ Attach supporting data ALLOWEDEMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EUG 1 ._._._... _. .._.. _..__. _._ ..... ..... ..._.. ....____._.. .. __ _.. ..___._.... . .........._.._.... _.....__... ...............

_ . ...._... .. .._..__._.. ........... .__.__ . __.. ._.. .. __........_ . _ _..__...._ . ..........._ .._...._._. ba - G ] SD1 ..._ . .. 0.59

. .. ._. ..._ 0.10

.. . _...___. 0.45

......._.. 13.77

. ...... 9.67

....... .. 3.88

. . _.___... . 7.98

._...._.. _ ._...... . Et'(:3.9D 2 0.95

_ _ ........ 0.90

_ -- ............ 0.45

.._.__....._ .. t3.77

.__..__ .. 9.67

__.. ..._.__...._.. 3.88

.. .__..__ ._. .. 7.98

_......_ ..._.._.. Ct

~~ C4

~ lls1

_ .. _ _._..._. 0.72 .._.__ 0.08

_ . ..._.......... 0. 1 8

......_....._ . . .... tt.43

.... ..... _ _.. 38.33

.__. .- ._....._.._ 3.51 5.85 .___..._ __.._._. fa

~ G 4

~ - DS2 _ 0..52

..__ .. _.___. 0.06

.. .....____._. 0.08

.._._. .__ 5.09

_...... ..._.. 17.04

_._. ..___._.__. LSG

_ 2.60

._. _.._.._. . ..___. EUGS-WSl

. .._ ....._.... 1.43

._.__,____ L60

. ......_.._.... . 8.96

___.._._.._ 19.60

............ ..._.. 4.78

__. .__.._.__.._ i.i3

....... ..... 6.71

.........._.__ -___.._.._ F.l!GS-V,S? 4.28 4.80 _...._ __26.88

_ _... ......_....

5 8.80 14J4

....................

23.t8

.... 20.13

._..__. _ _.._._._.- EGG 5- Trun 1 57 3.88 9.68 6.75 ..._ ---- 3 67 2.00 1.80 EXCESS EMISSIONS: based on t hour timits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCi SO i CO VOC NOx PM HF HCI SO, CO VOC NOx PM

.. Ft'G 1 ..__ ... . _._.. .. __,_._. ..__.__. .___..__ . _..__..__ _.__._....... ..__._ .. . ______.._ None

... ... . .. . .........__,.. ._...... .. .... .._........ None GGG2

. . ._._.. . __.____. _.__... ....._...__._ ._._... . ...._... __..._.._ _____. Nonc - ..____.... ._... ....,.. .

. _ _.._...__. ....___. _. _. ._........ .._. _ _ None ...__.... E['C3SD1 None

_.._._.. ....._._... None

_.. ._,.._._. None

.__.._.... None

__...__. . __._.. None

___. ....___...._.. None

._......._.__ . None

--_.._._..._. ....._...-_....

None None ._.._....._._. None

......... None

_ .........

None None ........._. None

._ ...... PUG 3 SD2 ._ . . None

. None

__.____.. None

._.......... None

..._..._. ._...__. None

.._.........._ None

.............. None

............... . ..._. None

__...... .......___....

None None

, .__. None _.. , .._. None

_._.... None None

.....__. E['G 4 VDst

. None

.. __.._ __ _ ._. _ \'one ....__._ None ..._ - _._..... None

....___ _._._,_ None

_._...___ _... ..... None

._._.... None

. _... None _..__..... ... None

__..__.._ None

. __.. None .._. _. .._. None __._... . None

..._._.... None

. ._._..._.

_ El

~ (;4

~~ Its2

. None

._ __..._ _ ._.. None None ._ _ . _.._. _.. None

...__ ... . . ... .. ... None

._..._ . .... _ ..__.._... None

._.............. None

.....__.__... . . ... _ None

___._.. _ . None

_ ......_._ None

... ___ _.. None ._. . ....... None . _.. _.. None

_......_._ _ None . _ . _.. _... _- EUG 5-NVSI _..__ . _ None

....... __...___. None

. .........__._ None

..__...._.._ ..._.___

None

........ None

_._...._ _ _._._._ None

. ..._..__._._ None

_ None _._._.._ None ....__....__._. None None

_.._..__.. ..._ None

_._..._.. None

_ .__.. None

.._.._.. EUGS-R'S2

.. __ 1.34

..... ... .__.._. 9.04

_ _..._._. 1t.40

.__._...._.. _ None

_ -._.... _._ None

.___. ---.. _..___,. None

..__. .....___ None

_._._._.. _... None

_.._._.. None

..__._..__ None

._....__.._ None

_ _._ None _._._._ . None

.._..._._ None

..__.____ EUG 5- Trim None None None None Nona None None None None None None Nono None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut duw•n for mafntenance to ckan noriks, pits, and impinger. PROCESSES AND EQUI PM ENT INVOLVED: (2) NVet Serubber k2 CORRECTIVE MEASURES TAKEN: (2) Cieaned noriks and pits, Bushed foggers, and switched fans. Restarted the scrnbber. ADDITIONAL INFORMATION * : The N'et Scrubber was maintained and operated according to the ntanufaeture's instructions. The repairs and mamtenanee were dune as quickty as possible, utiliring overtinte if needed. 1 certify, based on information and berMf formed after reasunable mquiry, the statements and information m thls document are true, accurate and contplete

SIGNATURE OF REPORTING PERSON

Date Received: Reccived By: Demonstration of Cause Submittcd:

= No AGENCY USE ONLY 7}acking Number: Team ID: Date Submitted: " If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# DEPA.RTMENT OI+ ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 6/15/09 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMIVIEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 6/12/09 7:30AM SUBMITTED: SUBMITTED: 120 Minutes EE ID #, if a licable: 6/12/09 6/15/09 

# **'"The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages inay be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. conternporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean nozzles and pits, flush foggers, and switch fans. The scrubber downtirne was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recoinmended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage.

.

## ► 

# ._

DEQ Form # 100-922 Page 1 of 2 Revised Noveinber 5, 2007

# ____________________ --- __________________________ (4) T he 

# vvaG i 

# vaozOoozorcouo

~ 

# t« n 

# tn i 

# t h g o0 

# d ~ f~ 

# r ' tbatthis provi sion 

# Gholluotbouoostrucdbo require the use or installation of additional or redundant pollutioocontro| equipment not otherwiscrequ i 

# redmd that this provisionshall notbe construed tn automatically rcqoirethuohotdovvuofpu)co8s equipment t0 nninioztrc eoimainuS. ThisvvnrkTvuod0oe in0rderto prevent omalfhootioxoofthep/etoomubbxer.Theoorobbxrnam operated according t0

------------------------------- _--------------- (5) ReamnnobleStemoweretukentooinimizeth: impact ofthe exccaoen

- iiooi0000000bieotair T h 

# e w0rk was done a8 quickly nap000ibletominimizot h 

# e scnubbczdowntime.

_______________________________________________________________________ NA



# _______________________________________________________________________ Cq T he 

# nvvnc r 

# 0r n
~~ 

# no duri 

# `pt h 

# ) ' d0foceaoeoisSi0oSwcre d0coozen1ed bvproperly



# operati ng 

# logm,orotherre}cvon1cvidcnuc. Recordmacokent0ftheuorubbcrdnwmtincaodthcwx)rk dOuc

_______________________________________________________________________ Iwurtoy,uuamdooioformui"nwodxc|k{bnmcduftcr,raoouuhlefuqotr»tbomut0000muodinhvmudoointohdvo"muutamt,"e,

8IGNA7UREQF RE8PON8IBLE0FFKIA[0RD00IGN0E

DE0F000#l00-Q22 9ago20f2 Revised Novenzber 5,2007

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALtrY AIR QUALITY DNISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM

~ OTE: The infortnation requested below should be submitted to the address above within 10 working days a0er the immediate notice is given. If you are using this fonn to cotrect a previous eport, provide only the eorrected information below, sign the certification, and attaeh a eopy of the previous report.
REPORT DATE: COMPANY NAh7E:

6/19/2009 Da{-Italia NAME OF INDIy

~ IDUAI. REPORTING: TITLE: P}IONE: Ed Smart Plant Manager (918) 683-0043 FACILITY: COUNTY: PERMIT NUMBER: Da4ttalia Muskogee 200a-198-7V (M-t) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 6/15l2009 0:00 0:00 0:00 Hours:Min Phase 1

13:t0 14:50 1:40 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:40 Hours:MinutesofWetScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Speciric Conditlon 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE Compliance Testing X ._.___.. ....__.... -.__.__.. .___.... ........ SOURCE GRP tIF HCL SO z CO VOC NOx PM FUG t _._._.... . .. __._ .... ._._..._.._._ ......._.__... __._..._ . ............ ____...__. ...___.-._. ........_...

..... 1 iUGl

.. _._..... .._-_._.. _. _.....__. .__.._.._. . ...._...._. _ ..__ ....._ ._.-.._....._ - . .._.__- - __ ._......-_._ . __........_ContEmissionsM o nitoring __._..._. ..__.___ . _.._.._.._.. ......

_ E['G 3 SD1
.~~ 0.49 . _ 0 00

_ - .._ 0.2 (

..___. _ 7.88

__,. . . ._... . 2 72,._
. _ ... _,

. 2 47 ._ . _ 4h1

- Pnginccrinc Calcnla!inn X - _._. _-.__ ....._. __ ....Cl'(:7SD?

.. 024

. _...._. 000 .._._

-. ._..... . . _._ 0.00 ..__..._.. ____5_l8

- . .__ 083

..__ ......_._.. _ t75 ~

.._...-..... _. .. . _ .. _2.30
... OperahngLo. ~ X - .___._.. .-........ . _...._. ..... ..-_. . EIIG4VDri
__ 0.02 -....

. . ._.... 000

.__...._...._. 0.00

.._._......__ _,____i.26 ,...._._

. 0.66

..__.___. 1.03

._.._.._. ._ .- ,_„_ . ,228

_ ..__._._. Otitcrlc<plain)

.. ._.__. ...-......-. ........._-.. . __.. tCUG a\

~ Ds? 0.01 0.00 ._. 0.00

-...-_..__. . 3.

~ t

. ... . .... 0.45

_... .- ___.... 0.69

......___ .. 1.54 _._..._.__ .. ... _.__.._.. . ___..._ _......___ ..._.._.. ....__... EtiG 5-\c.til

... ... _... . ~~ _... ~

....__ 0.01 ___.._...... 0.19 ~~~-_~~~ ~

._. _... 0.22 ~~

. ...-..._ . -._._._._., ~.~ ~~~ 8.82

. . -...._...... 0.57 .._..._.... 3.00 ...___ 1.79 -__ ......... . ........._..... ..__._... .._._....-._ ..__._... .__._.. _ EUGS-\1S2 .......... 8.62
...... t0.26 ~ ... . ..__._.. 28.38

.. ..... 18.68

__ _ .. .. .._..-_...... 5,54

. ....._.___ 735

... ...___ . 9.99

_... _.._... ...... ._....-._. __...._. ..._._.. .__...... ..____. F,UGS-Trim 2.16 2J5 6.13 4.30 1.19 L67 L28 - --- ~~ ......._.. . __.._.. . .... ..... _.. _. Attach supporting data ALLOIVED EMtSS10NS: SOURCE GRP IiF IiCL SO z CO VOC NOx P11 EUG 1 ....._. . _._. _ ....... ..... . . _.__..._.... _..... _ _ .___. . . . . .._ _. . _.__._ .....__... _._...._._. _ _ _.. EI'C?

.... . ___.... __... _. .. _._ _ ........ ......__.. _ _.____ .. ....__. -. _.__...__ . ._._........_ . ..._.. ... _....... Ct

~ G 3 SD1

... .._.,_. 0.59 ...._. 0.t0

__. .._.._.__.. O.

~ iS

. _ 13.77 _._..,__ . 9.67

......_ ..._.,._._.. 3.88

_..,..... 7.98

..._ ..._ _.__.... Ct

~ G? SD?

._. 0.95 ..._. . _._..- . 0.90

-.. ....._.... O.aS

_. _._. -_.. . 13.77

........__... _ 9.67

._..._ . _.,..._..__. 3.88

. _._._......._ 7.98

...-.__....___.__.__.._ ~tl~(~ aV~ Dst . 0.72

... _.._.. _.__ 0.08

_.. ......_.......... 0.18

. _.._..._..... _. 11.43

..-..__.-._ . ._. 38.33

_.___.. ....__..._..- 3.51

._.._._. 5.85

.___._....-.._.... [l

~ G a\

~ D,_' 0.52

._....._ ..___........ 0.06

.._.__..__ 0.08

. -..-_.._. 5.09

....._.___ ................ 17.04

. ............ 1.56

____ 2.60 .______._.._.__._ EGG

~ -\\

~ .til .._._ 1.43

.._.___ . ...-.._...._ 1.60

_ _.__..__.. 8.96

........__ I9.60

_.__._.... .._..._-.. d.78 ..__..-..... 7.73 __...-.___. 6.71

..._._._..._...._.-..... EUG F- AA

~ S2

.... _......._ 2.85 ........_ 3.20

. ._..._.__.. 17.92

__.____.. ...__.._.._.

39.20 9.56

.......... .........._..... 15.45

_._._____ . 13.42

._........_._.__.... EliG5-Trim 3.57 3.88 9.68 6.75 3.67 2.00 t.80 EXCESS EMISSIONS: based on 1 hour limfts EXCESS 6NtISSIONS: 24-tir Totals SOURCEGRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM Et1G 1 _.. __.. ......... ......... .... ............. ......___._.. _...._.__.__ __ ____ .-_-.._..__... . ___....__.. None ....._._- ......__..__ ____.___ . ____. _.._. _ _____..... . ......._._-.-_ None

... .._...._._.. EUG 2 _.__.,.__. . ...._._. -_...__....._. .._...._ . ...__.._.-.._ .._...... ..._____ ................ ._.-_....-. None .___.___ ....__...__. .._......_._ ._.....__.__. _...._.. ...__....... None ...__. El'G 3 SDI

_ .. .. None

._..._. .__.__....... None

.............. IYone

.. .___....._ Nono None

........._._ .-..._.___.--....--...._... None ..._.__.. None None

-.._..__.__.. ........._.-._.......__-._...- None None .._._ .. _.__...

None None ...._._.. None

.....__._ None ........___....

. ICl'(:3 SD2 None .._._._ None

..... _...___.__. None

.. _...____.. None

___...__. ...-_ None

___ ....... ..... ..._ None

. ._.._._........ None

...._._.. _- . - None

...._._.... None _. _..-__._ None

.._.__- None .__.. .. ...__.......

None None .__.._......_ None

. .....__..._.. t:t'

~ (;4 \ ~D~t .. __ ~~ one

. _ . _....__.. . None

_ . ............. None

. . ._ -..___..... . Nono

__.__. ._.._ None

_...._.... . ._...._._. None

. __ _.._...._. None

..._..._.. .-.. None

_._._.._.. . None

..._.-._._... None

. . . _.._ None ___- _. . . None ..__.___ None

.......___._ None

_.___.__. LUG !\

- Dc2 ._.._.. __ None

..__ ._.._ None

__.. __..__- None

..._..__-_.. . . None

....._......-_ ........ None

_.._._...... ...... _ .. None

. ............._... None

_..-.___... .._ None

.-.....-.._. None _......____ None .__-...... - None

. ... .. .. None --...._._.. . None _...___..__... None

._.___.... EUG 5-\\.tit .._.. .. ... Nono __ _... None ...._ .-...-_.__ None

___ ... _ . None

... -._ .. .. __. None

._....__ . .. ......... None .._. None

_ ....... . None _ Nono

. .__.__. None

. ._ - .._ None -._. _ None

.............. None

.. _. _._-__.. Nonc

. ... ... ..__... EUGS-\\.ti? _..____ - 5.76 _._......._. 7.06

.. ..,_...._.. 10.46

_._.._____ None

__.._. ......_.._.. None

_.--_- ....... None

... ............._ None

..._..__. . None

_....._.._......

None .._....._ None .-. _.._..._...

None None ......_-.._._.... None

... __........._..._

None -..._. EUG 5-1
- run None None None None None No ne None None None None Nonc None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The serubber was shut down for mamtenance to clean nonJes, sludge, and check foggers. PROCESSES AND EQUIPMENTINVOLVED: (2) lVet Scrubber #2 CORRECTIVE MEASUR6S TAKEN: (2) Cleaned nonles and sludge, Oushed foggers, and restarted the scrubber. ADDITION`AL INFORMATION

~ `: The iVet Scrubber was maintained and operated according to the manufacture's Instructions. The repa'vs and ntafntenance were done as qulckly as possOrle, utilb)ng overtinte ifneeded. 1 certil'y, based on information and betief formed after reasonable mquiry, the statements and inforntation in thic document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Receival: Reccival By: Demonstration of Cause Submitted: O No 0 ( ~ ~ AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supponing infomiation. DEQ-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission —1)emonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The inforination requested below should be subinitted to the address above within 30 days a$er the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 6/16/09 

## NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 6/15/09 I:IOPM SUBMITTED: SUBiVIITTED: 200 Minutes EE ID #, if a licable: 6/16/09 6/16/09 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional inforination and supporting documentation is to be attached to this report (i.e. contelnporaneous 1ogs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean nozzles, sludge, and check foggers. The scrubber downtime was as short as possible to complete the work that had to be done. (2) The excess emissions were not part of a recurring pattern indicative of inadequate operation or maintenance. The scrubber was shut down to colnplete the manufacturer's recommended preventative maintenance procedures. (3) Ifthe excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property dainage.

~ 

# 1

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

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SXGNAT0REOF RE8pONQIBLE@Pp0CIAL0R D08IGN88

T]EAPoon#l00-A22 9age 2of2 Bevised Noveozbcr5,20O7

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FOItM NOTE: The infonnation requested below should be submitted to the addreas above within 10 working days aRer the immediate notice is given. If you are using this form to correct a previous eport, provide only the corrected information below, sign the certification, and attach a copy of tlte previous report.
REPORT DATE: COM PANY NAM E:

6f26l2009 Dal-Itatfa NAME OF INDIVIDUAL REPORTING: TITLE: PIiONE: Ed Smart Plant 14fanager (918) 683-4043 FACILITI': COUNTY: PERMIT NUMBER: DaNtalia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 612512009 6:00 8:30 2:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 2:30 Hoors:Minutes of Wet Scrubber powntinte APPLICABLE LIMtTAT10N(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specifx Condkion l, EUG 5 ESTIMATED EMISSIONS: BASIS OF EST(MATE ComplianceTr.ain ~

• _..__. ..._...__ ._.._... ........... .. X SOURCEGRP HF HCL SO i CO vOC NOs PM EC G t ....._ _ . __..._....._ _. ...._ .. .....___. . ._.____. __..._. . __..___.. ._.____.. .... ..._._.__. . __._.___.. _... F,LG 2

. . . .._.,_ _ __......_ . . ... _ . Cont Fmissions Monitm

~ ing
_.._.__ _..._..... X lcf

~ G)SDI

. .. . _. - 0.53

_...__. 0.00

.. .__._... 0.23

__.._.__... . . . 8.5t

_.___ . ......._. 2.94

_._ . .._._ ........ 2.67

. . .....___ __..5.31

_...._ .. _..... EnginccringCalculation

__._. .__....._ . . _.__.._ _.._.... ..._.___.... X Et.(; 1 SD2

. 0.37

___... . _._....... 0.00

. .._._...._. 0.00

._._..._.. . 8.24

__.._._ .. ._....._._ t.27

. . ..__._....._ 2.69

_.__... . 3.52

._.___..__. ...... OperatingLoes

..._ ___..._.. ... -._....... ._...._.. _.__.. El'

~ G- lGllst

. . 0.03 ____.... . ._.._.__ 0.00

.. ....__ _0 .0 0

. . 6.t4
_ _......_. .: _ .. 0.78 t.21
_ . ._. 2.68

. . .. Other(explain) -._.... .._.... .__ .... . .......... ._.._......

~ EUG4VDs2

. 0.02 .._.__ . .__.__... 0.00
_

. . _ 0.00

. 3.

~ 9

.. 0.45

_ ..._.__. 0.70 1.56

.. . . EUG 5- WSl

. _ 16.08_
_

. ._. 19.14 ~

. .......... 52.9 4

. . . . 34.83

_ ._... 10.33

._.... . . .._..._.. 13.70

.. _..__. 18.64

.. . . ._. _ ._..

..__... . . ___._.. ..._....... . _.__.__. EUG5-lVS2

. .... 0.00

__ . . O.OI

... _,.. 0.02 ~ 11.3 4 1.91 ...._. . ..___.. 3.69 3.36

....... .. . ._. _._.

.._..__. .___ . __.._...... ....._.._ EUGS-Trim 1.47 1.88 4.19 2.94 0.81 1.14 0.88 _ ......... . ....____. ._.__._. ......._..._. _.__... ALLOWED EhtISS10NS: Attach supporting data SOURCE GRP HF tiCL SO i CO vOC NOx PM EUG Y .._..... .__.... __..___ ... _.-__.... ...._....__ ._.__.._. ......__ __..._..__ . . _._...._. _.___._.. ..._..._- EUG2

... ... _._____.._ . ..__._.__ ...... _ __ ... ...__. .... _..._.... ...._..___ _ __.._.__ _.....__... EUG3SD1

.. _0.59 .....__.._ 0_t0

. 0.45

. _ i3.77 967

. ...._..__. 3.88

. . . . ,,_ . ,,..7.98_,____,_, EUG 3 SD2

......... ....__... 0.95 _._..__ 0.90 _. __.._____... 0.45 ~

. _........._.. ..._ 13.77

_ __._..__.._.... ..._ 9.67

...._.___,___. 3.88 ~

... _...___.. 7.98

.............. E-t

~ G4 VDsI ._. . 0.72

_._..._. .. .-_-... 0.08

. ...._.._..... 0.18

._._._....-.. .. 1t.J.3

....._.... ._ 38.33 3.St 5.85 ____..... _.___... EI ~G~ ! VDs2

. . . 0.52

__... _. _._...._. 0.06

_ ......_... 0.08

_ ._._.. . 5.09

... .___ .. 17.04 __.._... (.56 ...._ ... _. 2.60

..__.........._.........._. Cl

~ GS-ttS1 - 4?8

_ 4.80

_...._.. ?6.88 58.80 ._.__ ..._.__. 1414

... 23.t8

_......_ 20.13

_ ....... ......_...... I ~a~ G5-t

~ S2 ._ . . 1.43 ..

.

.. ._. . . t.60

._ ._........ SJ6

_ .. .. __ 19.60

_ . . . 4.78

_ . . _..._... 7.73

........._ 6.71

......... ........_ EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 6XCESS EMISSIONS: based on t hour limits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO r CO VOC NOx PD7 HF HCI SO i CO VOC NOx PM EUG I _....__ .. _.._..._ . _.__.__..... ....__.__.._ ._.._...._..._ __.._.. ._..._,.. ____.._... __._........ .._.__...._.._ None ..__.._...__. ..___. ._. ._.. . _.__.._. ..____. None .....__.. EUG 2 ..___ . ......___.... . __.__._ _ . ...._....... ...__...._ . .. __... . .._. __.. __._....... ....__._.._ None __.._...... .._. _....._ . ____.__ __ __ ._.. _.. ..._ ._ ......__ None ._.____ EUG 3 SDt _._.._.. ___.._. None

_.._........ None

..__...._.._. None

_....._...._ None

_.._.__.._ __...._... None __.__..... None

..__._._... None

.... .............

None

. None _.....__. None

._ _..__..... ~ une None

_.....__ None

.....__.. . None

__....... EUG 3 SD2 None

_...___. . _.._..... None

_. ........... None None __.... ._ None

. _ __......... None

...__... None

...._._.. .. None

._.... None

......_._._ None .._ _._ ;vbnc None None .. _.._.__. None

..._......__.. kiCG4lllst ._ .... _. _ Noae

. ...___ None

... , ._._ .__ None

...__.... None

......_.... .... None

..._. ._.........._ None

_. ...._ ._. None

......._ _._ ...._ None

...... _ . _. None

___..._. Nonc

...... _. , ~a~~c Nmte

._ ... None

. ._.___._. None

.__.._. EVG 4 VDs2

_ _ ...__. None

_ . None

_._._._.._ None

_......... None

......_.. ..._.__ None

._...__.._.. None

.......... None

_..._.__ ..... . ...... None

....._.... . None .__......_.... None

._.__....__ ~~ one
. None

..... None None

.___.._

~~ SI

... . . t1.79

_._ . _..._ t4.34

.. . ...____ 26.06

.. ....__... None

......__ _..._ None

...... .....__.__. None

_........_. None

......_......_ . . None

..__...._ None

............. None

._.___.. None None

. __... None

....___ None

..._....._... El'

~ C 5-k

~ S? _.. None

_. ._ ..._._ None

_. _.,.._ None

_..___. None

...._.... ... None

...._ ._..._... None

.___..... None

_._ . .._. None

._..,. . . None

._..-_._.._. None

__ None None

_ .. None

. _._...._..._ None

........_.. EUG 5- Truu Nono None None None None None Nonc None Nont None Xonc None None None NATURE AND CAUSE OF EXCESS EBIISSION: (t) The scrubber was shut dow•n due to a the computer Inshig control of the fans. PROCESSES AND EQUIPMENT INVOLVED: ( t) !!'et Scrubber N t CORRECTIVE MEASURES TAKEN: (1) The scniputer was rebooted and the scrubber w•as restarted. ADDITION AL 1NFORMATION * : The R'et Scrubber was maintained and operated according to the manufacture's instructions. The reparcs and maintenance were done as quickh , as possible, util'ving overtime if needed. 1 certify^, based on inforniatiun and belief formed after reasonable mquiry, the statements and infnrmation in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Causa Submitted: 

## =Nn 0 I I I A(sENCY [JSE ONLY DateSubmitted: TrackingNumber: Team ID:

' s If you wish to notify the DHQ about a technological limitation, do so here and attach supporting infonnation. DEO-Form #100-920 Revised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission — Demonstration of Cause Report Form

for 1Vlalfunctions ®AC 252:100-9-3.3(a) NOTE: The information requested below should be submitted to the address above within 30 days afler the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 6/26/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee 2004-198-TV (M-1) Muskogee DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 6/25/2009 6:OOAM SUBMIT°TED: SUBMITTED: 150 Minutes EE ID #, if a licable: 6/26/2009 1 

## 6/26/2009 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders of the DEQ. Additional pages may be attached if extra space is required. Additional information and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The excess emissions were caused by a sudden and not reasonably preventable failure of air pollution control equipment, process equipment or a process to operate in a normal or usual manner. The wet scrubber was shut down due to the sudden malfunction of the computer causing the computer to lose control of the fans. This failure was not reasonably preventable. (2) The excess emissions did not stem from an activity or event that could have been reasonably foreseen and avoided or planned for, and could not have been avoided by better operation and maintenance practices. The scrubber was maintained and operated according the manufacturer's instructions. The malfunction was not anticipated and could not have been reasonably foreseen. (3) To the maximum extent practicable, the air pollution control equipment or process equipment was maintained and operated in a manner consistent with good practice for minimizing emissions; provided, however, that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. The scrubber was maintained and operated according the manufacturer's instructions. DEQ Fonn # 100-921 Page 1 of 2 Revised November 5, 2007

# (4) Repairs were made in an expeditious fashion when the operator knew or should have known that an

applicable emission limitation was being exceeded. Off-shift labor and overtime were utilized, to the extent practicable, to ensure that such repairs were made as expeditiously as practicable. Repairs were initiated and finished as quickly as possible, using overtime as needed.

— - — - — - — - — - — - — - — - — - — - - 7 -- - — - — - — - — - — - — - — - — - — - — - 

# (5) The amount and duration of the excess ei

- nissions (including any bypass) were miniinized to the maximum extent practicable during periods of malfunction; however, this provision shall not be construed to require the use or installation of additional or redundant pollution control equipi

- nent not otherwise required. Repairs were started and conducted as quickly as possible to miniiriize emissions.

-------------------------------- *% --------------- 

# (6) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. Repairs were started and conducted as quickly as possible to minimize any impact of emissions.

----------------------------------------------- (7) Emission inonitoring systeins capable of producing valid data were kept in operation if at all possible.
m

----------------------------------------------- (8) The owner or operator's actions in response to the malfunction were docuinented by properly signed, contemporaneous operation logs, or other relevant evidence. Records of the malfunction and repair work was maintained.
(9) The excess emissions were not part of a recuning pattem indicative of inadequate design, operation or maintenance of the facility.

This malfunction does not appear to be part of a recuning pattem.

I certify, based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.

SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE


# DEQ Fonn # 100-921 Page 2 of 2 Revised November 5, 2007

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY. OK 73101-1677 

# EXCESS EMISSIOlV FORM `OTE: The information requested belocv should be submitted to the address above within 10 working days after the immediate notice is given. tf you are using this fomi to cmrect a previous port, provide only the corrected information below, sign the eertification, and attach a copy of the previous report.
REPORT D ATE: C06TPANY NAM1TE:

7/3/2009 DaI-Itatia NAME OF INDtVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMiSS10N: Dato Start Time: Stop Tinte: Duration: 6L10/2009 0:00 0:00 0:00 Hours:Min Phase 1

9:43 10:50 1:07 Hours:Min Phase2 DIJRATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 1:07 Hours:MinutesofWetScrubberpoticntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 2004-198-TV (M-1): Specific Condition t, EUG 5 ESTIb1ATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X .....___. .-__...... .... ..... _...__.. ... ..... SOURCE GRP HF HCL SO i CO VOC NOs PM

.__ Fl`R I __.___. _ ..._ ._.._.. ._.____ ._..._. . ___ ..__........__..... .. _.__.._. _._...._. .._ EG G'- ._._ . . _ . ...__._. _.. .. . _... ._....___. _._.._ . . ................. ..__...._... .__.._._._. ._...._.. Cont Fmissions Monitoring

. ..__.._._. ............ EUG?ti11t

.. 0.42

.. _. ..____._ 0.00

._. . .......... 0.18

.__._.._... 6.72

___ . __ 2.3?

.... _.. .___... 2.11

......_.._ 4.t9

..__..._. EngineeringCaiculation X

_...__. ...__._. .._._ ...... ............... EUG3tiD2 ._ 0.43

. ...._ 0.00

.... ...... 0.00

_.. _ , 9.66

_ . 1.48

.......... 3.I5 ._.. _ 4.12

...... . ... OperatingLogs X

... ._ . . _ . ..__. El:c4 \

~ Uit 0.03

..... 0.00 _.__.. 0.00

. _ 7.06 ~ 0.89

... t.38

. .._.__ 3.06

.__. _._.... ~~~ -- -- ~ "

~ Other(etcplain)

....___ _..._.._ _-._..._. .._._.._ ....._... ta

~ c 4\

~ i),3 0.02 ._.._

. .._._.._.._ ._ 0.00 

### .... 0.00

... ._ . ___ .._ 3.60

_..__._.. __. 

### .._. 6..t> 0.71

_ ..__. . 1.56

____ ._ _-...._.. ............ ....._...__._ . _..._.__ _._..

. ~ E 0 G ~-\~ S 1 0.02 0.30
~~ .___ ._... . 0.35 I3.80

. . . . ~ 0.90

__... 4.69

. ..._.. 2.79

.... . .. ._...._ .__._... . .___... .. _._._.. _._... EI'GS-AAti2 6.44 7.66

. ...._... 2t.20

. . t3.95

_ ... _... 4,14

_._.. . 5.49

_. .._.. . 7.46

.....__.._ .. _.......... .__._._. . .__.._._ .__.._ __._.._ Et;G 5-'fr"un 1.38 1.77 3.93 -
-- ~~ ~-~ 2.76 0.76 (,07 0.82 ..._._.__ _.._____ __..__._.. ..__..... ....__.. Attach supporting data ALLOWED EMISSIONS: SOURCE GRP HF IiCL SO., CO VOC NOx PM EUG t t;UG 2 ..._.._ ......_.. __ . ___._.__.... . . .._...._.. . ..._.._. _.. ._.._ ____..._ .___......_. _ _.....__._......____ FUG 3 SDI _

. 0.59 ..._ . _

.- 0.10

.. -__._ 0.45

..-. ...... . .._ 13.77

_._ . .. - 9.67

_._. ___.... . 3.88

_ .._.. 7.98

_.._ .._._.._ Ll'

~ G 3 SD2

.. 0.95 ...._.. 0.90 _. . ......._. 0.45

._... ,..... t3.77

__._. ... 9.67

_.__.. __.__ 3.88

.. .__. __........ . 7.98

_. ..__.._. _...___._. El - G 4 Dst

.. 0.72

. .. _..._... 0.08

._. . ...._..__. 0.18

. ..... __.. 11.43

_._.... _ 38.33

_.._. ..._.._.._ 3.51

. ._.... _ _.... 5.85

____..___.._......__ Ct G .1 Ds2 052

. .___._ 0.06 ._. ............ 0.08

._....__ 5.09

..__...._.. _.. 17.03

_._. . _ _..._ _.._ 1.5G

.. . .._._...__. 2.60

_.____...___._._. Et ~G~ -\\.S1

_ . . 1.43 1.60 ._ 8.96

._........ 19.60

._._._., _.._. 4.78

_..__ ._ ._._...._._ 7.73

.._. _ 6.71

._.._.._..__...__.._. Et

~ G5-\1S2

.. .. 2.85

.,..___ . . _._...._ 3.20 .._._... 17.92 ....._.___... . 39.20

__..__....._ . __....._._ 9.56

_..___...... I5.4S

._......_. 13.42

..__....___._....._.._ EU G 5- Trim 1 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour tinths EXCESS EMISSIONS: 24-ttr Totals SOURCE GRP HF HCI SO, CO VOC NOz PM HF IiCI SO i CO VOC NOc PM EUG1

. _.- -_._. .___. __ _._____.. . _......_... ......_...... ... ...._.. ._.._____. . ._...__._.. Nono ._._.___. .__ ._._._... __. .....__.. ........__. None ___..__.. EUG 2

. .... ... ... .. ._.. ..._ . _._.___... ......_.__.__. ._.__.... None ..---_.. ~ . _._. . _._. __._ ...... . .. ....... .........._. None _...-. ._. ia'C 3 SDI None

_ .. .. ._.._. None

_.. .. .__..._......

None None

._..._.._.. ..._. None

_...._ _..._..___ None

...__.__ ...... None

.... ......__ . None

........._ . None

....._.____. None

.__....._ None _... None

........__ . None

_..__... Nonc

_......... EUG 3 SD2

.. . None

. . None _... .. _ None

......____. . None

~ --- ~ - ..... .... None

....... .. _._..__._.. None

. . None

. . _.....__ . - None None None .__ None

..... None

. .._... None None

...._. EUG4 VD

~ t ~ --._ ._._-

None .__...__ , ---

None _.. . __._..._. None

. ... ...... None

_ -..._ .. ._ None

._..._.__.... None

_. None _. _ -~- ~ None _....-._ .. - ~ -'--

None ..__._.._. None

....... Nune None None ....___.. None

..._. EUG4 A P ~~ . ._ . None

._..... ._.__ None None None ....._ Aone _.... _....._..._.._ None

_....._.. Nonc

_..__.._ . _ .. None

...__..__ None __.___...._ None

...._.. None _._. ......__..__

None None

_. .......... None

......__.. EI'

~ G 5-\\

~ St ..._ None

. _.. . _...._. None

_.._ . ..._.__- None

._..__.. ._. _.... None

...._ . None

.. .. _ . _ . _.. _ None

. .___.._... None None None None .. _ None .._ None

. . _.... None None

........_.. EIIG .
- -\\ti ~

`

..__ ._ ___ 3.58

......_. . 4.46 ...__.. 3.28 __._. _._._..._ . _ None

..__._.... _... None

_._.... _._______ None

__ ......... .---

None .........._.... None

..._...._ None

.......... - None __... None

..... .._ None .__........ - ~ ---

None ._..__......_. None

._....._.._.. EUG 5-Trim None None None None None None None None Nono None None None None None NATURE AND C.4USE OF EXCESS EMISSION: (2) The scrubber was shut down for mamtenance tu clean nonJes and mesh pad. PROCESSES AND EQUIPMENT INVOLVED: (2) R'et Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The nonks and mesh pad were ekaned, operation was checked, and the scrubber was restarted.
ADDITIONAL INFORMATION * : The Wet Serubber was maintained and operated accordmg to the manufacture's mstruetions. The repairs and malntenanee were done as qukkly as possibte, utilving overtime if needed. I certify, based on informatlon and balief furmed aRer reasonable inqu'vy, the statements and bmformatton in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Receivod: Received Byc Demonstration of Cause Subtnitted:

= No AGENCY USE ONLY TrackingNumbcr: Tcam tD: DatcSubmittcd: * If you xvish to notify the DEQ about a technological limitation, do so here and attach supponing information. DEQ-Form #100-920 Reeised February 8, 2008

# DEPARTMENT OF ENVIRONMENTAL QUALITY 

# AIR QUALITY DIVISION P. O. BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# Excess Emission —Demonstration of Cause Report Form for Maintenance, Startup or Shutdown OAC 252:100-9-3.3(b) NOTE: The information requested below should be submitted to the address above within 30 days affter the occurrence has ended. For those that report quarterly it may be submitted with their quarterly report. DATE: COMPANY NAME: Dal-Italia 7/2/2009 NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Tiffany Acker Safety Admin. (918) 781-7142 FACILITY: COUNTY: PERMIT NUMBER: Muskogee Muskogee 2004-198-TV (M-1) DATE, TIME, AND DURATION OF EXCESS DATE IMMEDIATE NOTICE DATE WRITTEN REPORT EMISSION: 6/30/2009 9:43AM SUBMITTED: SUBMITTED: 67 Minutes EE ID #, if a licable: 7/1/2009 

# ***The owner or operator must demonstrate each of the following items in order for the excess emission to be considered exempt from compliance with air emission limitations established in permits, rules, and orders ofthe DEQ. Additional pages may be attached if extra space is required. Additional inforination and supporting documentation is to be attached to this report (i.e. contemporaneous logs, charts, maintenance records, etc). *** (1) The periods of excess emissions were short and infrequent and could not have been prevented through careful planning and design. The scrubber was shut down for maintenance to clean nozzles and mesh pad. The scrubber downtime was as short as possible to complete the work that had to be done.

T 

# (2) The excess emissions were not part of a recurring pattem indicative of inadequate operation or maintenance. The scrubber was shut down to complete the manufacturer's recommended preventative maintenance procedures. (3) If the excess emissions were caused by a bypass, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage. NA

DEQ Form # 100-922 Page 1 of 2 Revised November 5, 2007

### 7 — . - . — - - 7 

# -- - — - — - — (4) The facility was operated in a manner consistent with good practice for mminuzmg emissions; provided, however, that this provision shall not be construed to require the use or installation of additional or redundant pollution control equipment not otherwise required and that this provision shall not be construed to automatically require the shutdown of process equipment to minimize emissions. This work was done in order to prevent a malfunction of the wet scrubber. The scrubber was operated according to the manufacturer's instructions.

------------------------------- 11 ~ 

# --------------- (5) Reasonable steps were taken to minimize the impact of the excess emissions on ambient air quality. 

# The work was done as quickly as possible to minimize the scrubber downtime.

----------------------------------------------- 

# (6) En - iissions monitoring systems capable of producing valid data were kept in operation if at all possible. NA

-------------------------------
~ 

# -= ---------------- (7) The owner or operator's actions during the period of excess emissions were documented by properly signed, contemporaneous operating logs, or other relevant evidence.



# Records are kept of the scrubber downtime and the work done.

—— - — — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — - — 

# Tcjrtify, gased on inf 7

ormation and belief formed after reasonable inquiry, the statements and information in this document are true, accurate and complete.



# SIGNATURE OF RESPONSIBLE OFFICIAL OR DESIGNEE



# DEQ 

# Fonn # 100-922 

# Page 2 of 2 Revised Noveinber 5, 2007

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALrfY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CfrY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: 'Ihe infonnation requested below should be submitted to the address above udthin 10 working days afier the immediate notice is given. If you are using this fomt to correct a prevlous 

### rcp ort, provide only the corrected inforn)ation below, sign the certification, and attach a copy of the presdous report.
REPORT DATE: COMPANYNAME:

71102009 Dal-1ta0a NAME OF INDIVIDUAL REPORT[NG: TITLE: PHONE: Ed Smart P4ant Manager (918) 6834043 FACILITY: COUNTY: P ERM IT NUM BER: DaF-Itatia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Tinte: Stop Time: Duration: 7192009 8:00 8:50 0:50 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase 2 DURATION OF EXCESS EMiSStON (HOURS:MINUTES): 0:50 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: PermB No. 2004-198-TV (M-t): Specifc Conditmn 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE X _ComphaneeTesting ......_.... ....._._.... ..._.__. . . _._ _ . .__._..__ SOURCE GRP HF EiCL SO r CO VOC NOx Pbt EUC I ..__ .. . ..._ . _ _. _.. . ......_.... __..__.. . __..... ... ......_ . .............._. . _.._..__._ .._ __.__. .._ [ifG 2 ._._ _. . . ....._... ......_..._. ._....._ _. _.._... ._._ ___.._._. . ..._. .. Cont Fmissions Monitoring ._._._._ _._... _.. .__.__.. ...__ . ..._._._... El

- G i SD1 0.45

.. _ ......._. 0.00

._.._____. 0.19

__......._ .. 7.20

.__..._. 2A8

-._. 126

__.._.. ._....__._ 4.49

.._........ . EnginaringCalculation X

_.._._._ .._...._._ __._... _..._.__ ._.... _....... El

~ G3$UZ ._... .. . OJ2

.. __. .. _.._........ 0.00

...____._ 0.00 7.01

.......... ._.._.__ LOS

_._....._.... 2.28

. 2.99

.__.._ ...... OptratingLoss X .__.._.. ... __. __...... .. .._..__.. EI'C 4\"Ust .._. _

0.03

... . . ... 0.00

. .. . .... 6.14

_ 0.77 . .__.._... 1.20

.. . ..... 2.66

.._. . . Otha (explain}

_._..__ ....__ _ . _...... .. _ . ..... El G a\

~ DS? _.. . 0.01
_

... . . . 0.00

. 0.00

. ...... ~ 3.45

.... .. .... ~ 0.43

... .. .. ._._..._. 0.68

. 1.50

. ._........ .__.... . ._ ._... . . _.. _. _._. ... _ _. EI

~~ G 5-\\

~ ti I 5.65

. . 6.76 18.70

........ 12.30

.._.. ._.__.._- 3.65 4.84 ._... ...._. ~~ . ~ - 6.59 __...._.. ._.__.... _......... .....__ ..__..._ EUG 5- %

~ 'S2

~.~ 0.00 "

~ -....

._ . . ...._.._.

..... 0.01

.. 0.02

.. .. _ 13.56

......_. _ 2.32

_ 4.47

. . ......__._ ~ 4.07

..._ .. ._......... ._........_ __.. _. ___.._ _ __._.

. ~~ EUG5-Trim L49 1.91 4.25 2.98
. ~~ 0.82 1.16 0.89 Attach supportmg data ALLOWED EM ISSiONS: SOURCF.GRP HF HCL SO i CO VOC NOx PM EUG I _._. ... .. .__..__ ._._...... .......... . .....__.___ _...__.._ ...._..._ _........_. . --___..__... ........_._.........__.._ EL`G 2

_ _..._.._... . ..__. ....__.__... _ _ ..._.._ _._.._.... El!G 3 SD1 ._.-. . .. 0.59

........ ..._... 0.10

_._ ___.. _.. 0.45

_. .__ _._ .. 13.77

._....._ . __. .. . . 9.67

_..._. .....__.._... 3.88

_._ __...._ 7.95

. ._-._..._.__.._......... F.l

~ (:35D? 0.95 0.90 _._ . ....___... 0.45

.. ... .__. 13.77

_..._. .. .. 9.67

_... ....._._. 3.85

.__._- 7.98 - _ _.......__.__..... E[

~ G

~ t \'Dsl

. ..__... 0.72

. 0.08

......... ..._...__._. 0.t8

.... .............. t i.

~ t3

.. 38.33

.....__...__ 3.51

...._.__._.. 5,55

.___..__.........._. h:l

~ G 4 VDs2 0.52

._...._. ._._..__. 0.06 _.__. 0.08 ..._..-...._..___..... S.U9

.. ..__ 17.04 _.._..__.. 1.56

. __...... 2.60

......._.._..___.___._... Ef'(]5-N

~ St

_ 1.43 _._._._. . ._.... 1.60

....._._........ 5.96

.. _.._........ t9.60

.__.._.. . ._ 4.78

_...__ __..__._.... 7.73

..._.___.... 6.7 1

._......... __._.... Ft'GS-N

~ S2 1.43

. ... ..... I-60

..... _...__._. 8.96

. ....__. _. 19.60

.... _.._. . __ 4.75

__._ . ..__......_. 7.73

._.. 6.71

_-__... ._.._._. EUGS- 'frim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 6XCESS EMISSIONS: (based on 1 Ihour limits) EXCESS EMISSIONS: 24-llr Totals SOURCE GRP HF HCI SO, CO VOC NOx PM HF HCI 

### I SO, CO VOC NOx PM EUG t ._..._ _ __._._ . . _. ..__..

. _.... ._.__. .... . _. ...__.. . ___.__... _.......- . ._ _.. None

..._.. .. _ _ ....... _. -.......... _._ _ ............ _. _ . __. None EUG2 _....... .___... .. _. _... .___..__. . _.._._..... ._.._ ... .. .._........_.. ..._ ... None . ..___ ._ _ _..._.... ._._._____ .__ __._._. _.. ,. _ . . .__....... None ._...__._ EUG3SD) ....._... ...._ . None

. .. ....... None

. . None

._............ None

.._._.._ .... None

. ....._. None

.........._.. Aonc None __.._ . Nono _ __._._._. None

. ... No*rr ..___ _ ~ anr
~ 'one

.__..... Nono .___.._... EUG 3 SD2 __..._._ None

_ ...._... ..... None

.._ ....__. None

_.._._... _ Nonc

.__.__. _....._._. None

.... .__...._ None

......_._... None

._......._... __. None None

._......._ None

. _.. None _._ Sonc _. _. Aone

_.._.._.. None

_...._.. EUG 4 VDsI ...__.. Nonc

_._._. .... None

_._ . .._.._..... None _ None ..____.. ._ tione

__ .... ............... None

_.....___ None

_._..___.._. .... None

_._..._ None

___.._.. None

. _._._ None

. _._ None

_ ..._ None None

__...._.._.._ EUG 4 VDs2 _.__.......__.. Nnrte None

. . . ........_. None

_.___.. None

_._...... __._. _ ~ one

........._. None

...__..__ None

_..._......_ . None

._.._..__ None

.._._.._ None ....__ ... None

. .... . ....__.._....

None None .___...__. None

__.__... EUG 5- WSI

. _ ...... .... a.?5

. ... ... 5.t6

__. . __..... 9.74

.._....__ . None None None .__....__.._. None

__.__._....... _. None

.._..__.... None ...._ __..._ None

._.._. None _.... . ..._.._...

None None .._...__._.. None

. .._..__... EUG 5-1VS2

. _...... _ _ None

..._ _._ None

_.._ . .__.... None None

. .._.__. ... _ Nwte

_.._... .....__... Nono ._..__. None ..._.._....__.. .. None

.____ None

..._ .._ None

. ..._.. None _._ . .. None _. .._._... None

..._.......... None

.._.-.__.... EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: Wet scrubber I was shut down to chan8e the scrubber pump and prevent a malfunction PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Serubber # t CORRECTIVE MEASURES TAKEN: Change the scrubber pump
ADDITIONAL INFORhiAT10N'k: 1 certify, based on information and belief fornted after reasonable Inquiry, the statements and information in thiv docuntent are true, accurate and complete

SIGNATURE OF REPORTING PERSON

DateReceived: ReceivcdBy: IDemonstration ofCauseSubmitted: ONo AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: * If you Wish to notify the DEQ about a technological limitation, do so here and attach supporting infomtation. DEQ-Form #100-920 Revised February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALrrY AIR QUALrrY DMSION PO BOX 1677 OKLAHOMA CrrY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 working days aftcr the immediate notice is given. If you are using this fomt to correct a previous 

### rep on, provide only the cotrected infomiation below, sign the certification, and attach a copy of the pm

~ ious report.
REPORT DATE: COMPANY NAME:

7110l2009 Dal-ItaOa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 683-40.13 FACILITY: COUNTY: P ERM IT NUM BER: Dal-Ital'w Muskogee 2004-198-TV (hi-1) DATE AND TIME OF EXCESS EM1HSSION: Date Start Time: Stop Time: Duration: 7/92009 0:00 0:00 0:00 Hours:Min Phase 1

10:00 11:40 1:40 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:40 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Perntit No. 2004-198-TV (h1-1): Specific CondBion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTcsting X _.___.. ......__. . __.....__ ._..._... ._...._._. SOURCE GRP HF HCL SO, CO VOC NOx PM EUG I ._._ ... _._... ..._..._.. _.. _ _-.___ . _...._ ......__.. ....._.._ ....._.-.._.._ . __.._.. __.._.. ..

.. EUG 2

........ ... ._.... ._._..._.._... . .._..._. ........._ _..__... ._.. _..... ......._...._. ..__......_ .._..._ Cont Emissions Monitoring _......... ...._.._.__- . . ._...__... _..._..__. F.I'G3SD1

..... . 0.45

_._.._. .__.._ 0.00

._ -._ 0.19

._ .-....... 7.20

. _. 2A8

_..._.. -.......__..... 2.26

....... _ a.a9 EngineeringCalculation X

.__..._ - ..__.. ._.. _..__. ___... _.__......_.. 1:1'G 3 SD2 _._. 0.32 .._..._..... 0.00 ..__._. 0.00

_...._._ 7.01

..._._.___ . _.._...... t.08

.-.____._... 2.28

_....._.__.. 2.99

.____ ......._... Operating Lots X .__..... . _.._..._- .___._... ECCa\'Dsl _0.03

....__. __.. 0.00 .......-. 0.00

. ..- 6.14

_ . 0.77

_...._.... L20

. -....- 2.66

. . Other(explain)

.._.__. ........... . ...... . . ___._.._.. 

### Erc; a\ usz o.ol _._ o.00 _. o:o0

_ 3.a5 _.._. o.a;

_- _...... 0:68 _.~ {o



### _..... _._ ___.. -....._..__.. _...__. EltGS-WS1 0.02

.___.... 0.32... ....0

~ 

## i 1a.75

_ 0.96 _.-____. 5:02

_._ . 2.99 ....-_.._ ._.___... . -.__..__. ...__..... ____....... EUG5-NS2

.... 9.83

........ ..__._. It.70

. . - 32.37

_ ...._. 21.30

.. ..... 642 ._.__.... 8.38 ......___._ IIAO

........ .. .__._

._...._._ . . .__.....-_ . _._...__ .__._.._ ._..._ EliG5-Trim 1.49
. ~ ~~ - 1.91

~~ . ~~~~~~~ •1.25 ~ _.._ 2,98 0.82 1.16 1 0.89 ......__. .._._.._. . __-___. __.._._. _._...... ALLO\VEDEMISSIONS: Attach sapporting data SOURCE GRP HF HCL SO z CO VOC NOx PM EUG i ...._. ._ .. -. -..._... ..._._-_.._. . .,____. . _ _..._..._.... ......._.__. . . __ ___ .. ................ ..__.._.___. ......__............._._._ EUG 2

.. _..__. .._...._ ... ..__._. ......... ................ ...._._..._.. ._._..._._... . .. .._____-......_._..._. 4:1'G 3 SDt

. . 0.59

.__.- .. ._. ..... 0.10

._ ._.___

0.45 t3.77

. 9.67 3.88 7.98 _ CI'G 7 gD:

. - -_.._ 0.95

.. . ............ 0.90

... .. 0.45

. __. ._.._..-- .... 13.77

_.. _.__.._ .._..__ 9.67

_._....... . . ..__.._. 3.88

._.____.. . 7.98

._ ..._.___..._._._._._ EUG4 VDst ..___ . ...__ 0.72

..... ........... 0.08

_._._.-.._ 0.t8 .-..---.-.._.... .. 11A3

_._.._.... .._... 3513

..-...... .._.._._...... 3.

~ 1

..__ _._..- . 5.85

._.__........-_._...__

... EUC-1 VDs2

.. ... 0.52 _... . 0.06 __.__.... 0.08

. _-__ ......_. 5.09

._..._._.. _.... .. 17.Oa 1.5C ---.._.... __. 2.60

_..._......._ .._.._.... EI 1 G 5- 

### x \~ .ti t

.... . L43

_.._.._ .. .__. L60

._. _..... _.. 8.96

. 19.60 .. _. _.._ . . ... 4.78

........ ._.__......_ 7.7,3

._ . - . _ 6.71

...__............. EUGS- ~A~ S2 _. 2.85

_..__. ___.. 3,20

_ ....._.._... t7.92

.._...... .. 39.20

_ ........ ...... 9.56

...... .............. !Sa> 13.42 ._-.._.........-,.... EUG5-Trim 1 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on i hour Omits) EXCESS EMISSIONS: 24-llr Totals SOURCE GRP HF HCI SO i CO VOC NOx Pht HF HCI SO, CO I VOC NOx PM EUGI

. -_._ ..... .... .... .... .._.___..... .....____._. .. _-_...-__ ...._- -_... . .___..-_ . ._ -.....__.. .. None

. .._._.._._. ..._.- ..._. . ___._.. __._.__ .-.... ._..._._... ...._._._._._ None

_ _-.-..-._._.. ._....._ __.. UG E 2

. . . .. ..._._. .- .......... _.. . ..___..... . ___.___ . . __....._ . ....._... ...._.__..... . ..__ ......... . None

.... ._. _ . ........_.. Nonc .- EttG3SD1

. _ Nonc

..._._ . None

_.. ......___._.. None

.._..._.-_- . None

._._..._. ....... _ None

-. _ . None None ___._. .. __. None

._..__.. . . None --__ ......... None

.. ...._... None _.. . None .__...__ None

.......__ None - _.__. FCG 3 SD2 .._ ._... None

... . None

.. ._...._.__ None

.. ._.... _........ _ None

....._.....__. ._...__._. None

. _..._._._...-. None

.._.___-... None

..._._._._.. ..._. None

._...._... None _._........._ None

_..__ None None

_ .. None

...... .._ _. ~ 'one _.. ... F.I

~ C 4 VDeI Nnne

- None

..__._.__. None

..__ _......__ None

_._.._ .... None

....... .._.........._._ None

..__...._... None

._....... None

......_.. None None .~ 'onr

.. Nnne

_ __. __.

Nonc LC(;4

~~ Ds2 _._. ... .. __ Nnne

.._ __.._.- None

...__.._..__ - ~ 1'one ..._._._. None

.__...._. ....._..__.._ None

.._-....._._... None

.___...___. None

.._..._._.. ... None

.._.._. None ..___.......... None

....._.__ Xone

_ .. -_ None

.. Nunc ..._...._.. Aouc

......._... Et'

~ GS-

~~ 51

. . . ._ . Anne

_ __... _..._ None

... . .. .... _ .. None

. None None

. . None

. _ . _..__.... None

... .. _. ..... None

._ _.._.. None

...._...... None

.. ... _. _None

. Nono .. .__ . None .... _ _._._ None

._.....__ Et(G S- st 52


### - -. _. 6,98

_...__ . ..._.._ 8.50

._ . _...__ 14.45

......_... None

__..._._ None

..._...._ -... None

..._..--_._.. . None

.._...__ None

__...... None

......__. None

........ None ._. None

._.__..... None ...._-.-_._. None

.._.._._. EUG 5-Trhn None None None None Nono None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: Wet Scrubber 92 was shut duwn due to decreasmg tlow m the bleed 1'ute. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber 92 CORRECTIVE MEASURES TAKEN: Cleaned out the bteed Bne.
ADDITIONAL INFORMATION * : 1 certifv, based on mformation and belief formed after reasonable inquiry, the statentents and inforntatlon in thls document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: O No AC.ENCY USE ONLY Tracking Number: Team ID: Date Submitted: * If you wdsh to notify the DEQ about a technological limitation, do so hem and attach supporting information. DEQ-Form #100-920 Rewsed February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfrY DIVISION PO BOX 1677 OKLAHOMA CHY, OK 73101-1677 

# EXCESS EMISSION FORM : OTF: The infovnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fomt to correct a preF4ous epon, pro4ide only the corfected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

7f24/2009 Dal-ItaBa NAMEOFINDIVIDUALREPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 711712009 0:00 0:00 0:00 Hours:Min Phase 1

8:00 9:45 1:45 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:h11NUTES): 1:45 Hours:NlinutesofWetScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-T}' (M-1): Speciric Condition i, EUG 5 ESTIMATED EMISSIONS: BAS[S OF EST1Mr1TE

_. ComplianceTesting X

. . .._ . .__..._. ._..__. ._. ___... SOURCE GRP HF NCL SO i CO VOC NOx PM Et'C 1

... . _ . ....__ ... ......... . _. _.__..._._... _ .__.._-_ ..__._.. _.. ___. ...._._ ........_. . _.......__ .........._..... EUG 2

... _ ....__ .._.. .._ ____.._. . _._.._.._ ..._..... ... _.__... ........_.... ..___.. ___. __. Cont F

~ nissions Monitoring

_ .._. ...._._. ...._. _ ...__.._.... F('GtSDt 0.91

. ...._..... 0.00 .._._..__. 0.39

. ....._.._.. 14.74

._....... .._._..__ 5.09

.... ..........._.... 4.63

.........._ 9.19

._......_ Engincering('aloulxtion X

.__...._.. ...__.._. . _......... - __.___. _..__... LI

~ G? 5D?

. 032

...._._ _. ._ 0.00

..._ ,..._... 0.00

. _.. __ 7.t6

._..._. .... 1.10

....__ . . .___._.._. 2.33

.._.. _..__... 3.06

_....._.. Opera,ingloes X
~ .__...... .......... _....._. . . _..__. _ _.. ELG1VDs1 ._.._ . _.__.... 0.03 ..__..._ 0.00 ..._...._._ _0.00

. . 6.18

_.._._. . ._.._.__. 0.78 ._.._.._.... L21 ...._... 2.68

.._.... Other(explain)

...__... .._.._..... ...._..... .._._._. _ EUG 4 VDs2 0.01

__...._ . ... 0.00

_ ._ . ..__..,. 0.00

. .. .. . 3.51

...._. 0.44

.. ___.._. 0.69

. _ ....... 1.52

......... _.. _ __._.._.. ......__ .. . _._...... . ____.__. ___.. . EUG5-W'St - . o.02

__._... __.._.. 0.32

.. _0.38 ~ 14.87 0.97 ..._..____ 5.06

. ..._.. 3.01

_ . . ..._..._..._. ..........._. ____._. .. _._..._ . ._.___. EUGS-W'S2

.. . . 10.79 __. . . ..._..._ (2.85

.. 35.53 ~

. ... _._ . ..___23.38 ....__....

.. __. ._ 6.94

............ 9.20 ._..... 12.S1 ...__._. ......... . ....... _..__..... ..... EUG5-Trim --- ~~ 1.35 1.73
~ ..._.... 3 .85 2.70 ~ ..__.._ 0.75 1.05

~~ . ~ . 0.81 Attach supporting data ALLOWF.D EMISSIONS: SOURCE GRP 9F HCL SO i CO VOC NOx P1i EUG 1

_ ....... ....__ .. ___._. _... ....._._. .___... . ..,.__._.._. . . ..._....__... _.__._._. .. . .....____ . _..._..___._______-. EUG 2

..... __..._. _._..__ . ._ ._........ ____---.. _ ........_ ..... .. ... . ........._ . . . __. __.......______ EUG 3 SD1 _,0.59

. . __.. 0.t0 _. OAS

_ _ .__.__,._

13.77
_ ..

9.67 ..._.. _...-._ EUG3SD2

. . _._.. 0.95

_...._.._. ._._. 0.90 ~

_._ . . ._._ .......... 0.45

...__.. ~ 13.77

_..._._ _. ___.. _._._.....__

9.67

. .. .._.._.._ ... _._.._.._. ____... EtiG4YDs1

. _, . . 0.72

........... _ _ 0.08

__.. . _ ......_.__.. 0.18 tL43 _........._ ._ 38.33

...._.... .. __._..__. 3.51

. _...__._. 5.85

..__.__.__ .. _._.

. F,UG4 VDs2 _._.... OS2

._...._._ ....._._ 0.06

.____..._.. i].OS

_.._. 5.09

.._.._. _....._._ tZ04 L56 2.60 .__._....._._ EUGS-}VSt __._..... 1.43

..__...... _.._...__.... 1.60

.._...__.... 896

............. 19.60

_._ ..__.._ 4.78

_._.._..___ 7.73

.. .._-_ 6.71

__.__....__..._........ EUG S- W'S2 2.85

--_ -.._. 3.20

. . 17.92

. .. - 39.20

- - -- 9.56

_-.. _.._ 15.45 _ . 13.42 .._ EtiGS-Tr'un 3.51 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on 1 hour runits) EXCESS EDIISSIONS: 24-Hr TotaLc SOURCE GRP HF F1C1 SO s CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG 1

.. __.._ .._._.. ..__...__. _____. . ........._.. .._...._ .. ..........._ ..._._.......... ........_... None ._......_... .... ....._. .._...._.. ..... __.. .. None ...__.._.__. El'G 2 _....._ . . .__. . .... .._....._ . ........ None

.. _ . ........ ..... . _._ _.. . Noue

.. _. ._-. Et
- (: 3 Slll 032

..._._. None

. . ...._.__ None

_._..... 0.97

.._._... .. None

.._.._. _ ...__......_ 0.75

_ ._._... . 1.21

.__.___.. _ None

..__..._. None ._. _.__._._ None

.. None

..._.. None

............. Nnne

. .. None ..._._.._._.. EIiG 3 SD2 None

_.....__ ____.... None

_.. .. .......__..._. None

._...._.. None

._...._ ._. None

_.__.._..... None

.. ._.._...._.. None

_._..__....___ ._ _ None

_._.._.._ None

. _.__.._. None

_... None _. ..._...... None None

.......... None .._....... EI
~~ G J

~ 'Dsl

.. ..___._._

Nona

. ..._.__ None _.. ...__.._..._ None

.__._.. None

._._..__ _.._._._ None

..__....._... Nonc

.._...._.__ Nona

..__.._.._... ._ Nono None .._....__._ None

. .__...___ None None _.___.. None

.__..... None _....__. Et'G a

~ 'Ds2 None

. .. __ None

. .. ....__........ None

.._....... . None

_. ._ . _-_ .. None

. .. . None _

.. . ...... . None

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None None ....__...__ None

.. .. .. None .._. .. None -_ __... None None -. .. I:CG 5- R;til Aone .

.._.__._ None .....__... None

. _. _. None

_ _ _ None

_ ._.,._._._._. None

. _ . ..._.__ None ~

_ ._ . _. one

. None

... None ._ . _ _. None

. . None None None ._ LUG5-}}:ti2

.... . __. .. _. 7.94

__...__.. .._....__.._._ 9.65 17.61 ._.._._.. None

...._... None _...___. _._.. _._ None

... _._.._.._... None

... 

# 1

- Z one ___......._. . None

..._.__.._. None

.. _... _ None .._ .... ....... None

.. ___.. None None

___.._._.. EUG 5- Trim None None None None None Nonc None None I None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: Wet scrubber 2 was shut down due to sludge buildup in the scrubber tank affecting water now. PROCESSES AND EQUIPMENT 1NVOLVED: (2) }Vet Serubber 02 CORRECTIVE MEASURES TAKEN: Clean sludge out of scrubber tank.
ADDITIONAL INFORMATION' k : 1 certify, based on mformation and betief fornted after reasonable inquiry, the statements and information m this document are true, accurate and complete

StGNATURE OF REPORTING PERSON

Date Received: Received B}': Demonstration of Cause Submitted:

= No AGENCY USE ONLY TrackingNumber; Team ID: DateSubmitted: * If you uish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Rewsed February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIftONMENTAL QUAI.fTY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: Theinformation requested belosv should be submitted to the address above within 10 wotl.ing days after the immediate notiee is given. If you are using this fonn to correct a previous eport, provide only the con

~ ected infonnation below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANYNAME:

7t2412009 DaFltaOa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 683-4043 FACI L[TY: COUNTY: PERM IT NU M BER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TiME OF EXCESS EMISSION: Date Start Tinte: Stop Time: Duration: 7/22l2009 14:30 23:35 9:05 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase 2 DURATION OF EXCESS 6bi1SS10N (HOURS:MINUTES): 9:05 11ours:iVlinutes of Wet Scrubber powntinte APPLICABLE LIM(TATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No.2004-198-TV (M-1): Speciric CondOfon 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianccTesting X

. .. _ .. ._. SOURCE GRP HF HCL SO i CO VOC NOx p; 1 EUG I _...__ . _....._.. ..., ........ _.__._. ._____.. ..... _._.. ........_.-_ _... ... .. ..__..... F.1!C 2 .__._... _.._.. ContFmissionsbtonitoring ..__.._.. ...__ _ __ __ .. . ............. El'(:3 SUI

.... . 0.42

_..-__. . _......... 0.00

. ____.. O.18

.. _..___. 6.74

_._..__ ... 2.33

....._ ._._.._. 2.12 ._...._._.... 4.I0

_ . Enginccring Calcnt.nton X _..._._ ._..._.._ _.....__. _._....__ _.._. __.. F.UG3SD2_ _. . 0.43

....-_. . .._. . 0.00_
_ 0.00 ._ . 9.48

...._ _ 1.46

._._ . .__.__.. 3-09

. __._ 4.05 Oper:.!fn , Lo~~ X ......___ _ ._ .

.. E(

~ G4 VDsI

.. ._...._ 0.02 0.00
_ 0.00

_ .. _ 5.79 0.73 ..__ ._.._.__ 1.13

. . 2.51

. .... ~ Other(explain)

___._. ..__.._._. _ . ___ ._. _. -- ~ ._ .. Et'C 4 t'Ds?

_ 0.01 _._....
_. . 0.00 ~ ... 0.00

. .. -.. 3.45

.. ... .. 0.43

.. ..__.__. 0.68 ~~~~~ ~

.. ... - ~~~~~~ 1.50

_._.... .__ _..___ _..__... _. .._.... ...__._. . . _..._.__ EUGS-v

~ .Sl

. . 27.26

.__._ _..__._. 32.45

~ --

_ 89.76

... .._ ._. 59.06 ._ 17.52 23.24

. ... ...._ 3i.61

.._......_. __.._......_. ...__ ......... . .___._. _ .._._..._... EUGS-vtiti2 .

. 0.00

_.... _ O.Ot - ~~ - ~~~

. 0.02 13.03

_ .. 2.18' ..___.. _

. .____.... 4,20

. . .__ 3.83

_... _ . .. ........... . __.._.. _......... .__.. _. ..___. EUG 5 - Trim 1 1.39 ~ .~ 1 1.78 ~ 1 . 3.96 ~ 1 ~ .~~ 2.78 1 . ~ . 0.77 1 1.08 1 0.83 _.._._._ ..__... ...._ __.. ..__.. _._,_ Attach supporting data ALLOWED EMISSIONS: SOURCEGRP HF HCL SO, CO VOC NOx Pbt Et7G t

... _ .._._..__ .. _ _.. __,._... .._._......... _.__.... __... .._... _..__...._ ....._.. . . . _.___ __._... _ Ia!G 2

. _.. .......... ._.__.. EI

~ G 3 SDI -. ~ 0.59

....__..._ .._.___ 0. t0

_. ._._.._ 0.45

._..._. _ .._.... ... 13.77

.....___._. . ._. 9.67

..._... ...._.__. 3.88

..._-...... 7.98

........._ _............ El'G 3 tiD2. __._._. 0.95

..__.._.. 0.90

..__...__ OA5

....._,_.. . 13.77

..._..._. ......__ 9.67 __........._. 3.88

.....__. 7.98 _.__... 1-U(:4 %

~ ud 0.72

__..._ .__.... 0.08

.._ ..___._. O.18

..._____. . 11.43

....._.._- . _...._ 38.33

.... .............. 3.St

...._._..._ a85

...._._......__.... t't G 4 Vuti2

.. 0.52 _ _.._._. . 0.06

..-. .__..... 0.08

._ ._.___. 5.09

..___.... .._ _ 17.04

_ .... .. ........_., 1.56

.._..... ... _.. I.60

._ _.. _ __..... . IU.G5-

~ NS1

_ .._..... 8.56 ... _. ... 9.60

.... .._..._. 53.76

.. ......_._. _... t17.60

.. ....._ ... . 28.68

_ .._._.__ 46.36

... _ ___._.. 4(1.26

. ._ _ _.._._... . EUGS-

~~ 5?

_ ....._.... 1.43 _..... L60 .._ . .._._._... 8.96 _._ . 19.60

. ... ._ 4.78

...__ ......_. _ 7.73

.._...._._ 6 .71 E[iG5-Trim 3.57 3.8R 9.G8 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on t hour Ihnits EXCESS EMISSIONS: 24-Hr Totats SOURCE GRP IiF NCl SO, CO VOC NOx PM1i IiF HCI SO i CO VOC NOx PM EI"G 1 ......__ _..._._ .._ .___.... ... ......... _.._._..._ .._....__ . .. ..._.._.. None

. __.. . .__..__ __...__. . _._.._._ None ..___.. Et:G2 __. . . _ .._._ .__.. . . .. -..... _.

_ . _ ~ None ._. _ _.. _. _ . .. . __. . _. - __. None

.. _ ..... CI G J SD1 Nanc

.... None _.... None

. None None _ . ..__.__.. None

... -_._..... _None

._.. . ._ N

_one

_ _ . None

. ._..__. _ ~

_mic

... None None

....._ None

. ... None Pl G3SD2 Nm:r .._ None .___._ , ~~ ono None ~ _ _..._. ._ None

_....... . ._.._..._. None

........... .......... ...... None

... N one None -- _ None None None

_ _ Nanr ..... ~

None .__.. ~ EUG 4 1'DSl ._.. .. ~.~ nnr Nonr None

. . None

. ... ._ None ....._.._. None

... _.. None

.__.._ __ None

. __._.__..... ~ Nonc

.._ Nnne Nnne

~ Nonr ..., _.._. ~ onc '~ 'one

. ...... EU(;4V'Ds2

. .....__.. ~ onc

... _ .-.. . Nonc

... .._.....__.._. None

_.__..._. None

_.._._._ ........._ None

. ............_.. None

.............. None

..- _... ..... None

.. _. None

.._... ._ ~ one

. Vone

. _.._. None

__.__ . ~~ unc

... _... Sone

._....___. EUG5-

~~~ SI

__-- t8.70 _._ ......_. 22.85

. ...__.. 36.00

...._-... None

._..._..... . .. None

_.__ ..._.........._. None _._..... None

_.._. __........_.-

None None

.........._ None

_ _._. None None

.. ...._..-_.._.._

Nm

~ c

.. None _.....___.... EUG 5-

~~~ 52

. __..._. ~ ane _._..__. ~ une ._ None

... None _...___... . Nonc

...__._... ... None

. .......... None

......__._. None

._._..__ None

..__._.._.. Nnne

_.._...._._._ \onc _.. None __..._._. 1\nne

__... None ..__.__. EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISStON: (1) Wet Scrubber kI was shut down due to a maifunetion causmg the scrubber to overheat and the packmp to melt. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Serubber 91 CORRECTIVE MEASURES TAKEN: (1) Cleaned out serubber, replaced paekmg, restarted the scrubber.
ADDITIONAL INFORMATION*: The Wet Scrubber w•as ntaintamed and operated according to the manufacture's instruetlons. The repa'vs and ntaintenanee were done as quickly as poss0ile, u[iliring overtime if needed. 1 certify, based on mformatfon and beGef formed after reasonable inquiry, the statements antl mforntation m this document are true, aecurate and complete

SIGNATURE OF REPORTING PERSON

Dato Rcceived: Received Dv: Dcmonstration of Cause Submined:

= No AGENCY USE ONLY TrackingNumber: Tcam ID: DafeSubmitted: * If you svish to notify the DEQ about a technological limitation, do so here and attach eupporting infomtation. DEQ-Form #100-920 Revised February 8, 2008

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALHY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS E1VfISSION FORM OTE: The information requested below should be submitted to the address above within 10 working days after the immediate noticc is given. If you are using this form to correct a previous eport, provide only the corrected informa6on below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

7J31/2009 DAF[talfa NAME OF INDIViDUAL REPORTiNG: TITLE: PHONE: Ed Smart Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: DaNtalia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 7/28t2009 18:30 20:20 1:50 Hours:Min Phase 1

13:00 14:45 1:45 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 3:35 Hours:Minutes of Wet Scrubber powntinte APPLICABLE LIM17:1TION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Speciric Condition 1, EUG 5 ESTIMATED EMISSIONS: BAS1S OF EST111ATE ComplianceTcsting X .._._...... ......._. _ ... _._..__. _...... SOURCE GRP HF HCL SO z CO VOC NOx PM EUG t ..__ . __.. ... ..._.__ EUC 2 _.. . . __. .__ ....__. ..__...... . _._.._..... . . _ Cont Emissions Monitoring ._._..... . .__... ._.._.__. . . _......._.- .......__. ECG3SDI

_ _. 0.51

_ _ 0.00

. 0.22 .._ .__.._._ . . 8.16

........._._ 2.82

_.__. ._ 2.56

. . . ... _.._._.. 5.09

._.__ . FngineeringCalculation X

.___.__. ___.... __ ..__ ___._. _._.. ECC:3SD2 ._.,__ 0.25

.___. ._......__ 0.00 ____._ 0.00 ____._.._._ 6.16

............. .. __._.._._. 0.95

.._.._..._.... 2.01

.. _._._.._.. 2.63

. .__....__. __._..__... OperatingLogs X _.__._.. .._..... _..._.__ .. __._.... Ft:C1}'D,t 0.03 0.00 .._..._. . .. .._._.__ 0.00

. . .._ 6.16

__._.._ _ .._ 0.78

_..... . . 1.21

, _..._ 2.67 ..._ Other(explain)

...____._. _._..._ ....._._. ..__..__._ ._.__....._. Et G a v Dt? 0.01

. 0.00 _._ . .......__. 0.00

. _ _ 3.55

... .. . _... 0.45

~~ "_ ._....

.___... . _.._. 0.69

. ... .. .. L54 ___.__... ... .. P:ll(:5-v):til IISa 13.73 .__._._._ 37.98

.... . 24.99

. . _._ 7.42

..__... __._.._ 9.83

. .. . . 13.38

. ............ . .. __._.___.

.._._._._ ._.__.... ._.__._ .._....__.. L!' G i- 1):S2

.. _. l QS2

.. . 12.52
_

. _ _...._. 34.64

.___.. . ._. . . 22.80

_ . ._......._ 6.76

...._.__ 8.97
_ .. . . . I2.20

.._...._--. .. _..___.- . . ..__...._. .____. ......_____ .._..___.. EUG5-Trim L4I 1.80 4.00 2.81 0.78 1 1.09 0.84 .___.... ._..._. .. .__... _._._ ALLO}VED EMISSIONS: Attach supporting data SOURCE GRP HF HCL SO z CO VOC NOx PM EUG 1

... _ ..__ . .._.._ _ .._.... _._ . _ _._.__. ...... ..._....._ .._...__... _ ..__._ .......__.. . _._.__.._ ...._____.....____. EUG 2

.... _ _-...._ ___..... __..._. __._._. ...__ ..._-.... . _..._.__ .___ _.._. ......_...___. _.._...._ . ......... ...__.__.._._ EUC.3 SD1 ...__...._ 0.59

_._._. ._. 0(0

, ..._....___. 0.45

. .._._.__.... 13.77

...__..._.. . 6.67

............. 3.88

._._..__..-.. 7.98

....__._..__._._.__. EUG3SD2

. _ .. __. _.. , . 0.9.5

... . _ 090 .._ .. _...._._- 045

. . _ _ __.. __.. . ,1377

.. . ..___ 967

.__.._. . .. . ...._...._. l88

_ ..._... . 7.98

. -. .__.. ._.__..____. Et

~ G4\Dsl

.... . _. . 0.72

.__._.. ._..._. 0.08

.__.._.._ 0.18

....__.__ 11.43

....__._._... . ._...__._.._ 38_l3

..............._....__....

3.51 ..._._. 5.85 .____.__..____. EUG 4 VDs2 .._.__. ._ ..__. 0.52

_._.... ...._. 0.06

_... ..._........_. 0.08

...-----.. . 5.09

_._ .......... ......._.._. 17.Q4

..._.._._._- 1.56

---.........__... 2.60

... _... . FUGS-}VSI

.. __... ... 2.85

_ ..... 3.20

...._ ..__._.__... 17.92

__......_.._ . 39.20

..____.._. ....._. 9.56

_..._._ _ .......__.._.. 15.45

. _..____ .......... t3.42

.. ..___.._._..____ Et I C5-

~~ S3

_ 2.85

..... 310

. _. ..._.. _.. 17.92

_.. _. . . 39.20 ._. _ ___ ... ...... 9.56

......_.. . ...._.. _....- t5.45

_ . _ ..__.____ 13.42

. _ _...___ __ ......_.._.. EUG 5-

~ fr1m 3.57 3.88 9.68 6.75 3.67 2.00 t.80 EXCESS EMISSIONS: based on 1 hour 8mhs EXCESS Eb11SSIONS: 24-Nr Totals SOURCE GRP HF HCI SO z CO VOC NOx PM HF HCI SO z CO VOC NOx PM EIiG I

. ___ .._ ....... _ ....,..__. __........ _ _.__._._... ..__._. None

_ ...._. .__.... . . .._ _ . . None ._.... IQ 'G 2

. ...__........ ._ _...._._ __.._._ . ...... _._- __..___.. . ..__._. None _... ._.._ .._ I None EI

~ G 3 SD(

_ _ . None

. ...,.._ None

._.. .....__......_. None

_ ............ . None

_............. _ None

.... _._.__. None

. _ ._. _..._.._. None

... Nona

.._...._. None

.......... None

...... None _.... None

..._..._. None

..__.._ 11 -

None

. ___..__. F.l'G 3 SU2 _. None

_._....._. ._.. None

_.... None

_ _. _ .__..__ . . None

..._._,..._ . __.. None

_.._...._._ ..__._ None

.. . __...._._ _ None

._._ . ._... None

_...._._ None

._....... None

_ .. None

....... ... None

._._..._ None ._..___. None

. ..._.._... EC(:! % Dsl None

......__ ......._. None

..___..._... None

_.__._.._._ . None None ..._..._..... None

........_._..._.._..__.._.....

None ._ None

..._..... . Nune

_._._ None

. _..._..__

None None _..__.. None

._.__.. None

.._...__. EI

~ G a vDs2 _... None

.__._._ _.__...._ None

. ..._.......__. None

..._._.._.._... None

._..._._..._....... Nonc None ......___... None

....-....._._ ... ..............

None None _._.._.__.. None

.__._....__ None ._ None ___.._.._. None

...._.._.. None

_..____ E(`G5-IVSI

... .. 8.68 .__....___. 10.53 ...___..._. 20.06

._-..,..._.... None

.._._.... .._. Nonc .__.._ None ........_ None _._........ ...._._.....

None

. Nono _...__.._. None None

.__.... None ...._____. None

__..,_.. None

_.._...... ECG 5-}VS2

...... ... 7.67 _.._.__ 9.32 ._..._ ..--_..._.. 16.72

. ..._.._ ._.. None

__..._ _. Nonc

........ ._._...... None

..__._ None

_._.__,... None

___..._ . None ..._..__..-_ None

. . ..__._.__

None None None

.......__. None

__._.. 

### U. 5- Trim None None None None N 'one None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: Wet Scrubber 91 was shut down due to the quench pressure read'otgs getting too hlgh. Needed to check nor

~ Jes. R`et Scrubber #2 was shut dorvn due to the quench pressure readings getting too high. Needed to check nooles. PROCESSES AND EQUIPMENT INVOLVED: Wet Scrubber #! Wet Scrubber #2 CORRECTI VE M Er1SURES TAKEN: Rentoved a0 nor

~ ks and ran svstem to Bush any debrls out of 8nes. Reinsta8ed novles, restarted the scrubber, checked quench pressure, and every4hing was good. Renroved a0 nor

~ ks and ran system to Bush any debrls out of 8nes. Reinstalled nurdes, restarted the scrubber, cheeked quench pressure, and everything was good. ADDITIONAL INFORMATION*: 1 certify, based on informatlon and belief formed after reasonable inqu'rcy, the statements and information m this document are true, aceurate and complete

SIGNATURE OF REPORTING PERSON

Date Reeeived: Receivut By: Demonstration of Cause Submitted:


## ~ `vo A(`iENCY USE ONLY TrackingNumber: Team ID: DateSubmittedt 'e If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infortnation. DEQ-Form 9100-920 Revised February 8, 2008

## O K l. A H O M A DEPARTMENT OF ENVIRONMENTAL QUALrrY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CffY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The information requested below should be subniitted to the address above within 10 working days after the immediate notice is given. If you are using this fonn to correct a previous rep ort, provdde only the cotrected infomtation belou•, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

8/14/2009 DaNtalia NAbiE OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Sntart Plant Managar (918) 683-4043 FACiLITY: COUNTY: PERMIT NUNIBER: Dal-Italia Muskogee 2004-198-TV (M-t) DAT6 AND TIME OF EXCESS EMfSS10N: Date Start Time: Stop Time: Duration: 817l2009 14:30 14:45 0:15 Hours:Min Phase 1



### 13:30 14:00 0:30 Hours:Min Phase 2 DURATIOh OF EXCESS EMISSION (HOURS:MINUTES): 0:45 Hours:Minutes of Wet Scrubber powntinte APPLICABLE LIMITATtON(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-19&TV (M-1): Speciric Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComphanccTestinc X - _.._.._.. . _....._- .__ _._. SOURCE GRP HF t{CL SO i CO VOC NOx PM EUG I ._.. _... . ....._.._. .__..___. _.......___ . .._...___. .._ _._... ...._......_. ....__. ...___ . F.[tC 2 .._ __..... ...... .. __..__.. ._..._.. . Cont EGnissions % lonitoring ._..___ ... . ......... ..__.___.. _ ._.. .. Il G3SU1

.. OA2

. .. .__._.._ 0.00 __.._.__ .._.__

0.18

. ....._...... 6.81 2.35

.....__..__.. ._.....__....__. 2.14 __._._... 4.25

__...._.... __..._.... Engineerin_C:deulation X

.. _____ .._._._ I:I G3SU2 0.25 ____._. 0.00 ____.._.._ 0.00

. .__..__. 5.63

..__.___ .. ___-_._..__...._._._

0.87 1.84

_.__.._. 2.41

_......._. . Operatin ~ta , g~ X

.......__. _____ _......_ _.. Et~Ga\~ Usl 0.03

.. .. _.... ._. 0.00

_.. . . 0.00

. . 6.00 ._...._. 0.75

. ._...._._ 1.i7

. ..._. 2.60

___. __.. Other(cxPlain )

. .__..... ....._._ . ...._.__.. _.__.._ P:I

~ G a\

~ Us? O.Ot

. 0.00

~ .. ~~~~~~~ _ - ~ ~ 0.00

. . _ .. . . ....

3.57 _..__ _. ._.__... _ . ___. ...___. ___.... .__..._ ..._... ._...._ bu(;5-vA:SI 1.70

.._...... 2.02 5.60 3.68 1.09 1.45 L97 ut'C;-\\12 2.61

_ ... _... 3.10

. ..__._.. 8.58

..... . 5.65

........ ... . 1.68

..... ......_.._ 2.22

. _.__. 3.02

_....._.... EUGS-Trim 1.60

~ . 2.04 4.55 3.t9 0.88 1.24 0.95 Attach supporting data ALLOWED EhtISS10NS: SOURCEGRP HF fiCL SO, CO vOC NOx PAi EUG 1 F.tIC 2

_ _ _.___ . _ ...... ._... ___ ___...... . ..._... ...... ..__.... [a Y: 3 5D t 059

_ _ 0.1_0_ _13.77 9.67 3.88 7.98 Ct G 3 SD?. 095

. _... _._,_.. ~ 0.90 -

.... . 0.45 ~ ~ - 13.77 9.67

_ ....__.... 3.88 --

_____..._. - 7.98 --

_._..__... _ _.. ._.. EI G aVl)sl 0.72

......_. .__...._ 0.08 .____..._. 0.18

.__.._...__.. 11.43

_.___.... _._ 3R.33 ._._._.._.. 3.51

............. 5.85

..__.....____._...._ c1 GaVDs2

. . . 0.52

. .._ ..._ 0.06

. ..___.__. 0.08

.__...._ 5.09

..__._.. ._..- t7.04

__.._._ .....__.... 1.56

...._._.. 2.60

....... .._ .._...__.. I

~ a'

~ (;5-R:til Ia3 1.60 8.96

... . 19.b0

_ __... 4.7R __.. 7.73 __... 6.7( __._..... ._. LCG,-

~ \:tii

. . . t.a3

.._ 1.60 __.._... 8.96 19.60 ....._....__......_.______._.._._ 1.7R _...._....._.._ 7.73

_..._._.. 6.71

_.._._..__._... EUGS - Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour funOs EXCESS Et111SSIONS: 24-Hr Totals SOURCE GRP IIF HCI SO i CO VOC NOz PM HF HCI SO_, CO I VOC NOx PM R'C I ._._. _._ . _...._. _ ._.. __.._. ...._..... .._........ ..... _ ._.. . _. . . None

. _ ..._. . ..__. .._ _ __...._... . . None ....__.__. El G 2

_ _ _ ._...._... ~-~~ ~ None _.... _.. .._. ._. _ ._. _. _. _ None .. EiIC i SDI ... None Nune ..__..
._. None None

. _.. None.__.....

-~ -._.__ None

_.._.... None

.... _. ..... None

.. ... None

. __,.._._.. None None None None None E( G 3 SD2 ..... None _. ..

._-- .__ None

..... - - - _No_n e



### _ . - . . None

. .. _.. None

._._ ------. None

. None .__ None

..... None

.. __._... None

_.._.. None Nonc Nonc

. - None El

~ G4 VDsI .____ None

..._._.. Vnnr None

. ...._.__._.. None

_..._...__ ._.. Nonr

_..._.. .....__........ None

. _._ None

.__.__.._.. None None _..._.._ Nonr

._....__.._. None None

. .._......__. None

_._..._. None

....__.___.-. ECG 4 VDs2 .__.__ . None

._.._._ ...____...._ \onc

..____..__ None

.._._.... None None

.._..____ ..........................__.. None ._--___... None

_.._._._.. None

_.....__ None

.__..._.. None

..__.._... None Nono

. __..__..__ None

_....._.._ None

. ___-._ Et1G 5- WSI .__.__. ._.......__ 0.27

...__..__.... 0.42

..__.._ None

.._.._._. None

...._... ....._._.._

None

.. ............. Nona

__.____. None

____. ___.._..

None None

.__..... None None

. None ..._....... None

...__.. None

..____ EUG 5- WS2 .._.... .. . 1.18

.__.._.. _. _....._. 1.50

.... . .......... None

.__-_.._. None

.......-. . . None

.._.._. _..._........_ None

. __...__._... None

__._.__. ._... None

.___... None

.._.__. None ......_.. None .__ . None

_._....__ None

_._ _ _._.. None

_......_ .- HUG 5- Trim None None None None Nonr None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) 1Vet Scrubber I was shut down to clean the nonks and the bleed 1'me. (2) R'et Scrubber 2 was shut down to check nonks and impenger rilter. PROCESSES AND EQUIPMENT INVOLVED: (t) NVet Scrubber 1 (2) NVet Scrubber 2 CORRECTIVE MEASURESTAKEN: (1) Cleaned the noi

~ Jes to prevent over heating and cleaned the bleed Ime to cycle ciean water in scrubber. (2) Cleaned nonks and fitter to prevent over heating. ADDITIONAL INFORMATION * : The tiVet Scrubber was maintained and operated aecord'mg to the manufacture's instruetions. The repairs and maintenance ivere done as quieklv as possible, tnihring overtime if needed. 1 certify, based on mforntation and belief formed after reasonable Inquiry, the statentents and information in this docnment are true, accurate and eomplete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Subtnitted: O No AGENCY USE ONLY TrackingNumber: Tcam ID: Date Subm ittcd: * If you wish to notify the DEQ about a technological limitation, do so here and attaeh supporting infonnation. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALtiY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTB: "Hte information requested below should be submitted to the address above within 10 working days aftef the immediate notice is given. lf you are using this form to correct a previous eport, provide only the corrected information below, sign the certification, and attach a copy of the prcvious report.
REPORT DATE: COMPANY NAME:

8/14/2009 Da41ta6a NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Hd Smart Plant Manager (918) 683-4043 FACILtTY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EM ISSiON: Date Start T'ime: Stop Time: Duration: 8/13/2009 0:00 0:00 0:00 Hours:Min Phase 1

10:30 14:40 4:10 Hours:Min Phase2 DURATION OF EXCESS EMISSION (ItOURS:MINUTES): 

### 4a0 Bours:Minutes of Wet Scrubber powntime APPLICA6LE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-t): Specific Condition t, EUG 5 ESTIMATED EM1IISSIONS: RASIS OF ESTIMATE ComplianceTcating X

._.__._.... SOURCE GRP HF HCL SO i CO VOC NOx PM EUG I ._. . ...... . ... _._ . ..__.__ _.. ... .......__ ._.__....._ . . ...___._.. __.._.. __.... ...... _.._.__ .__.._. EUG 2 ._._.___ . ..._....._ ____..__. __..__.._ . - Cont Fmissions \fonitoring .__._..... ._.._....... EUG3SDt __...__ . 0.46

.._.___ . ..... _._.. 0.00

..._._.._ .. 0.20

...... ......_ . ..._.__._.. . .._...........

7.48 .__._..___ _.. -

2.58 _..... _. ._.......__ 2.35

.. _._..... 4.67

._._.__....... __. Fsgincerin_(.'alculation X

__......_ ........_...._ . ..._. .... EUG 3 SD2 ._....... . 0.25 0.00 _._._.. 0.00

... ..____._. . .. 5.50

_..._.__.. ._ _ 0.84

....._. ...__..._._.. 1.79

..__.... 235

.._........ . Operating Lons X

_....__. ......... ....___.._. ..._.... _ Et7G 4 VDsI _.__._ . 0.03

.__._ . _....._.. 0.00

.. _... 0.00

. _._.._...... . 6.39

_.._.___. ._ 0.80

_..._ _._......... 1.25

............ 2.77

.._....._... _._ Otiicr ~ cxplain)

__... ......... .. ..___.. .._.... . EUG 4 VDs2

. ....._ _. 0.01 0.00 0.00 _._.......... 3.52 . _ 0.44

. _....___. 0.69 1.53 ....__..... . ._._.... _........ .....__. . __._. .....__ EUGS-WSt

. . . .. . ... ____. 0.02 _ .......... - 2 0.8

... _ ._..__. 0.32

__ .._... 12.84
_

.._.. . 0.83

. _..... 4.37 2.6 0

. _..___.._. ....__.. .__...__. ._____ . . ..._.._.. EUG 5- WS2

.. . 20.59

. __._. 24.51 ..____ 67.79

......... _ _ 44.60

_... _.. . 13.23

...__. ......._... 17.55

. ...__. 23.87

..._ _ . _ ___.... .. ...._. . _ _.__ ......._.. __. EUG 5- Trim I L45 1.85 4.12 2.89 0.80 1.12 0.86 _.__.. .__..... . _.. ..... . . _ __.. .._....... Attacb supporting data ALLOWED EM ISSIONS: SOURCE GRP 9F tiCL SO r CO VOC NOx PM Fl

~ G t _.._._ ..._..._ .... .___..__ .._...._ __...._. ._ ....... - - -.__ _._.._.. ..... _._._ _ ....__..___ ._._.._._ t>G G 2 .._.... _._. . ._.._. ..._ __., . ..__.__. ... . ._.._ ......._. _...__. ICl'C i SDt

_... 0.59

...... 0.10

._.__..._.. 0.4.5 .

..__..._. 

### .__ 13.77

......_... 9.67

.. ............... 3.88

. . ..__. . 7.98

.._.......___ _._..__ ta' ~ G t SD2 ._ 0.95

...... 0.90

.. _........ 0.45

.._._... 13.77

.._.....__.._ _._.._ 9.67

_. _. _.._.._.. 3.88

. ..__. 7.98

... .__.__._ ...._._.._ l:lIGaVDsl 0.72 ..._.._ 0.08 ._. . . _..._.__. 0.18

._...___. . IL43

.__..___.. . _ 38.33

. 3.51 5.85 I:t

~ G4\'Ds?

. .. 0.52

_ _.. .___._._ 0.06

._ __....... 0.08

..........._ _ 5.09

__..._.... ____.. 17.04

.__._ 1.56

. ._._..._.._. 2.60

_._. _.._.___.. EI

~ GS-

~ VSI

. _. . L43

_..._._. L60 _......_ 8.96

..._.....__ 19.60

_.__._._.. 4.78

.._.__..._. 7.73

_..._.._. _.. 6.7t

.____.__._.._.. ECG

~ -\\'S2

. 7.14

_..._.. ...__.._.. 8.00

.. ......... 44.81

._._.... 98.00

_..._...- _-....___ 23.90

... ........__.. 38.63

. _._........._. 33.55

.._......._ ._.___.. EIiG 5- Trim 3 57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on 1 bonr lim8s) EXCESS EMtSS10NS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO z CO VOC NOx PM EUG I _._ . _ ...

...__ ... ..... .. __.._.._.. . ____.__ __..__._ . . .......... ._ ____. ..___.... None ...._._..... .__.__._._.._.... .. ._....__.. .__ .....__._. .. _.._..._ None __...... i.t ~<~' , .. .._..____. _.....__.. None .__._.... . .... _....._.. ..... ._. ._. . ...___.. None .....__.. _.. EI'

~ (:3 SD1

. .. None

. .. ....__ 11

None

... . _.. None

. _.. None

._ ._ . _. None

__... None

._....._. None ._...__.._. None

..._.. None

....___._._..... Nonc

_. Vnnr Nnne

._ None

. ._.__..__ None

_._.__ ECG 3 SD2

. .. None

_..._.. ._...... None

_... ..._..__._. None

_.._... None

.......... __.... None

. - None

._ . .._ None

_.._.__... ..... None

__ .. Nono

.. .......... Nonc

._.._.. .. ~ 'onc .~b~ee ._. None .__. . None

_.__..._.. F.UC a VDsI

.. None

__....... __... None

.... _._.......... None

._..._. None

_..__....._ ._. None

..._. _.. __.._..._. None None _.. None _.__._. None

.._._._...__ None .___..... ?'one

_ ~o~ te

... None

_ _._ Nono

. _ _..._._.. ECG ~ VDs2

........ . None

__.._.. ...__..._ None ..__.._ None

_._._.._ None ._._. None __... ...____.__ None

.... ._._._. . Nonc

....._..._._. . ..._. Nono

..._...... None .._._._._. None .._._.__._ lunc Aoue None

. None __....._...._ EUG 5- R

~ SI ......__. . None

. _...__... None ._ _........._ None

_.._..__... None

.._.___. _. _.. None

_ ...... _ .__._. None

. ._......__. _ None

.... .....__... . .. ._ None

.__...... . None _...._. ___ None

.. ._ ...._.. Vorte None Nnnc None

_ ......_.._.. EUGS-
~ 1S2 ......_._ 13.45

._..__._ ..__-._ 16.5t

._ . .............. 22.98

._........_ None

.._.__.. .._. Nono

..._._ .. ..._. _._... None

.. ....._.____ None

.___._.. .._ None

......__. .. None

_._._..._ None

. _.... Aonc _._. . Nune ...__..._. None None

.__.._.._ EUGS-Trim Nonc None None Nono None None None None None Nono None None _...__._. .~ 'one None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down to replace a bent empenger pipe. PROCESSES AND EQUIPh1ENT INVOLVED: (2) Wet serubber #2 CORRECTIVE MEASURES TAKEN: (2) Replaced empenger pvc pipe, cleaned nordes, check tMw, and restarted the serubber.
ADDITIONAL INFORMATION * : The Wet Scrubber was maintained and operated accurding to the manufacture's instructions. The repairs and maintenance were done as quicktv as poss8de, uti!'rring overtime if needed. 1 certify, based on information and be0ef formed after reasonable inquirp, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Receivcd By: Ucmonstration of Cause Submitted: = 1`w AGENCY USE ONLY Tracking Numbtt: Team ID: Date Submitted:
's If you svish to notify the DEQ about a technological timitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO 80X 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The information requested below should be submitted to the address abovee within 10 working days after the intntediate notice is given. If you are using this form to correct a prevlous eport, provide only the corrected infonnation below, sign the certification, and attach a wpy of the previous report.
REPORT DATE: COMPANY NAME:

8/2 112 0 0 9 DaI-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Snrart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: DaI-Italia Muskogee 2004-198-TV (D7-1) DATE AND TIME OF HXCESS EMISSION: Date Start Time: Stop Time: Duration: 8J20I2009 9:30 t 1:00 1:30 Hours:Min Phase 1

0:00 0:00 0:00 Htwrs:AAin Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:30 Hours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Speeirie Condition i, EUG 5

- ESTIMATED EMISSIONS: BAS1S OF ESTIMATE CmnplianceTating X _.___. . _...__ . ._..... . . _._.. ...._...._.. SOURCE GRP HF HCL SO i CO vOC NOx PM EUG I _...._.. .._.__ .. ._...._. _. .._.__ . ........ .. ......___.. _._ ._..... .......__.._.. . ...._.._. .___..._ . EUG 2

. . . ._._....... .___. . .._ . . . ._._. .._.. Cont Finissions Monitoring .._._.__ _ .._.... _ . ....-...

_. _. EUG35D7 _...__. 0.•!a

._ . _ .__. 0.00

._ _.__._._. 0.19

._. _. 7.06

_...... ..... ~ 2.44

.._. __ _......

2.22

_ .. ..._.. 4.41

_.._.._. . EogineeringCalculalion X

__._...._. _ ___._ _ ._.. .. ... _. _.._._. . ..__.-.._. EUG 3 SD2

... 0.30

...._. 0.00 0.00

... .. 6.66

..._._ . _ L02

..___ 2.17

.._. .. 2.84

. . Operating Logs X

. .. _._.... .. ... ...._. EUG 4 t'DSt

.. _ . . . _ 0.03

_ ....... 0.00

_ ~.~~.-

... 0.00_ 6.02 ._._ 0.76 _... . .__....._..

1.18

~ .

._. _ ~ .2.61 ........._.. _._.. Otha (explain)

.._... .......... _._.._ _..._.... . EUC4

~ ns2 01

.....___. 0.00 ~

___.. . 0.00

. 3.48

. 0.44 ..._..___. 0.68

. ._ 1.51

_ . . .._..__. ._._.... .._.._._.. ...._.._._. ._._...... El'G5-I

~ SI ...... 10.08 ....... 12.00

~ -- .._. ...._._. 33.20 .._ _. 21.85 ~ -...... 6.48 ..._...__ 8.60 ...._..__ 11.69

_._..... ._..._....__. ... ._.___.. .. ._._._ _..... ..__......_- --- EUG 5- 0.00 ....._. 0.01

. ..._. .. --

0.02 .. _ . -._'-'
--- ~ -

14.30

.... 2.39

..___ .___.... -

4.61 ........_ 4.20

..... ... .._.____..

._.. __.. ._.___. . ...._._ ....._.. EUG 5-

~ lrun 1.3 ~ 1.72 3.83 ~ 2.69 0.74 1.04 0.80 .._..__... ._... . _....__. _.._._-_ Attaeh support)ng data ALLONV'ED EMISSIONS: SOURCEGRP HF HCL SO i CO VOC NOx PM EUG t ._...._. _.___. .._....._._ ................_. .__..___ .._...__ .__...._. ....___..._.. . ..____.... .__...__.. .__._.. EUG2 ._. _.._.. .. _._._. ___.. _. . . _.......... ..__.._. ..___.._ ....... ___ __..._...__. . .._.__... .-...__... .____.. EUC35D1

. .._.._...._ 0.59

_._....... ...__._..,,. 010

,....____._.. 0.45

...._...._._ 13.77

........._ _ .......... 9.67

......_._._.. 3.88

...___.. 7.98

..___..__......_..... EUC? SD2 ..__ __. 095

._..... _..___.._..... 0.90

__.._._.. 0.45

..........__. 13.77

_.__...._ _......__. 9.67 3.88 ...__._.... 7.98

.._....__.__..........

. F.nG

~ vDst

_ _ 0.72 0.08

... 0.f8

. .._......_.__ IlA3

_._... . . _ . 38.33

... .._ . _ .... ......... 3.51

...__._._..._ 5.85

....._...._ F.IiGa

~ - Ds2

. . _ 0.5?

... . _ . 0.06

._. . .._.___._. 0.08

......_ __ ._. 5.09

_ 17.04 ..._... .. _........_... 1.56

............ . 2.60

_._._._.__..._..__._. EUG5_-WSI 2.85 3.20_
_ 1.6 0 17.92 39.20 9.56 1_5.4.5 13.42 EUG5-

~~ S2 ....._._..._... . 1.43

_....__. __....._ .....__.._ 8.96

.. .....__ t9.60

._..._... ......... 4 .78

.................. 7.73

........... 6.71

........_._..._._._.. EUG 5- Trim 1 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour Smits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO r CO VOC NOx PM EUG 1
_ . ...._. .... ._..._..._ ____.__ . .....__.._ . ___. .. ..._.... _._....__.. _....... None ..___...... ..__.._.. ___...._. __.__....... _._.__.. .._._..__ None .___..... EUG 2 ..........._.... ......_... . ___ _. ________ . ._.._.._.. _.._._... ... ..._ ... ... ............... .._.__. None __..._.. ..._ ..._........ ____._.. . _._.... .__ ..._...___ _. ._ Nonc EUG 3 SD1 Nono

...._........ ...._ _...... None

.... ____._. None

.._._...._.... . _ None

.._.....___. . . .._ None

..._._....... ...._._.. None

.._._..__.. None

._........-_.. ._... None

_.__._ . None

_._.._.._ N000

. . ._......

None None

.......... _. Nuoc __.. N onc
_ ...___.... EUC.3 SD2

.. None .._.._... None .._ None

. . _.... None

..__._.... None

.............. None None ..._...,_. _... None

. ...._ None

_...._ None

. ._. Nono None

.. __. None

..........._ Nnne

__.

~ EUG a V'Dcl _.__... _ .. . None

_._.... ._.._...._ None ~

_... _...__._ None None ..._._ .... None

_... .._........_._... None

____.... None

..._..__ . ............_

None None ...._.__.... None

_......_. 1Vone None

. ..._....._._. None

. ~~ one

._. EIIG 4 vDs? None None __..._ ..._......__ None

._.__.. . None

.._..... None

._.._. None

. _....__._..._ None

.__..____.. _ None

_.._.._. None

........... None

._.._ .. None

..... ......_,.

None __..... Nonr __.. .. ~~ bnc Ll

~ GS-

~~ 51

_ 7.23 ...__.._... _._._ 8.80

.._ .._..____. 15.28

..._.....__ .. None

...._..._..__ . _......__ Nono

_... _._._._ None

_._..___. None

.__.___ _ None

____... None None

_ .......... None

... None ..___..__....._....

None _.. . Vone

. _ ._. h:CG

~ -nS2 __.. .._ . None None __.......__ None

__.._.._._ None

_._..._.._. _.___..._ None

. None

.. ....__. None

. _.__-_._ ..._ None

__....._. None

. _._....._ None

... ._..._..

None

.. None ......__ None

....._._.__. None

_ ELG5-Trim I None None None None None None None I None None None None None None None NATURE AND C.4USE OF EXCESS EMfSSION: (1) SVet Scrubber # I was shut down to clean the nornJes and check the sludge. PROCESSES AND EQUIPMENT INVOLVED: (1) P4`et Scrubber # I CORRECTIVE MEASURES TAKEN: (() Cleaned the nordes, cleaned the meshpad, and restarted the scrubber.
ADDITIONAL INFORMATtON*: The Wet Scrubber was maintafned and operated accord'mg to the nianufacture's instruct)ons. Tbe repairs and maintenance were done as quickly as possdtlo, utObing overtime if needed. I certify, based on mformation and be6erformed after reasonable mquiry, the statements and information in this document are true, accurate and complete

SIGNATURB OF REPORTING PERSON

Date Reccived: Rcceivcd By: Demonstration of Cause Submittcd:

~ yo AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8. 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfTY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is giren. If you are using this fotm to correct a previous port, provide only the cotrected information beiow, sign the certification, and attach a copy of the previous report.
REPORT DATE: COM1IPANY NAItiE:

8l28l2009 Dai-(talia NANtE OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: Dal-ItaBa Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Tinte: Stop Time: Durationc 8l23l2009 21:00 21:30 0:30 Hours:Min Phase 1



### 0:00 0:00 0:00 Hours:Min Phase2 DURATTON OF EXCESS EMISSION (HOURS:MUIUTES): 0:30 Hours:Minutes of Wet Scrubber powntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.200t-t98-TV (M-1): Specific Condiiion 1, EUG 5 ESTIMATED EMtSS10NS: tiASIS OF ESTIMATE Complinnec Tertinc X - SOURCE GRP HF HCL SO r CO VOC NOx PM EUGt _.___._.. . _.._..... ..__...._ .._ FuG z



### . . Cont Pat

~ issions

~ lonhoarg 

### _._ _.... LUG3SD1 ..___. .. .. 0.56

..._.. .___.__.... 0.00 ...__... 0.24

_.__.. 9.00

__..._. 3.1t

._.___..__.. 2.83

......._.. 5.62 ._......... F.ngineerinaCalculmion X

...__.._. ._...... _ . _....._.

. G3SD2 0.29 0.00 ....._._.. 0.00

_._..._._ 6A7

.__...... ...._.... 0.99 __..._._ 2.It .._._... 2.76

... ...... ..... OperatingLogs X

..... ... _...._._. . ..._ _ ....._.. .. Et ~~ G4VDs1 _0.03

_..._. . 0.00

._ 0.00

- _. 6.22

... ... ...._ 0.78

. ..___._.. 1.22

... ._... 2.69

_. .... _ Olhcr(explain)

.......... _....... . _.._.. __.__... EIUG4 VDs2 _. 0.02 ._..__._. . . _

0.00 ...__...

.. . .. _.. 

### - ~ 0.00

. _ . . . 3.62

..._._.... OA6 ._..__._.. 0.71
. ~ .~ 1.57 EUG5-wSt

. _._.._.. 3.25 .__..._ 3.87

. 10.7i

......._... 7.05

_ __.. _ ..._ 2.09

__.---_ 2.77 ..._. - -._.__ 3.77 EUG S- WS2 ..._ . .._. 0.00

...... . .. 0.0t ~

_. ._._. 0.02

_. . t3.67 ~

.._... ... 2.29

. .. _ ._..... 4.41

. . .__.. . 4.02

. ._ _._. EUGS-Trim 1.17 L49 3.32 2.33 0.65 031 0.70 -.___. __.....__ ...__... ......... ._.___ Attach supporting data ALLOR'EDEMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM BUG 1 _..____. _._...__ . ...._.._... .__.._ ...__.__... . _.._.__..._. .__......_..__ .. __.._.... __......._.. __._._. EUG 2

. ..._..._._..._.._. _ _.. _.._........_ ......._ __.___.. _._.....__... _.__..._...._ . _._..._ .._.....___... ......_.... EUG3SD1

.... ..... 0.59

.. ...... 0.10

.__ ....___.... 0.45

....__.... 13.77

.. ___. . . ._ 9.67

,_._.. ..-- - . .. _.__. 3.88

. . . __._.__.. . 7.98

. __ _._._.... _._... EUG3SD2 ...._..____ 0.95

........._.. .__._.._ 0.90 .._....__.._ 0.45

___...._ t3.77

.._.._. .__..._._... 9.67

__.__...._ 3.88

...__._......_ . 7.98

...._._.____....._.._,__ EUG 4 VDst

.. _..._ 0.72 ___....... 0.08

. _.._._.._.. 0.18

.._.__.. I L43 38.33

..__.__ . _._..__._ 3.51

. ......._._.._ 5.85

___.__._ EUG 4 VDs2 _. 0.52

. __.._._ .._ 0.06

._. _ 0.08

. _... .. ._ 5.09

_.._ . . 17.04

._ 1 i6 2.60 __.._.. EUGS-wSl

......... t.43

._..___... ..._._._ ... t60 __..__._. 896

_.._._ t9.60

_._..... _.. 4.78

__. ......__.._ 7.73

._._.._ 6.71

_....._.._._.._... EUGS-wS2 ._...._ . L43

.._....._._ ._._..._. L60 8.96 19.60 ..___._... _... 4.78

_.._ .._.__... 7.73

...__._.. 6.7(

...__._._._. .__.... EUG 5- Trim 1 3.57 3.88 1 9.68 1 6 1 75 1 3.67 1 2.00 1 1.80 EXCESS EMISSIONS: based on 1 hour cimits EXCESS EMISSIONS: 24-lir Totals SOURCE GRP HF tiCl SO z CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG1

_ _.... _ .... _._.__._ ... ..._._ ._. ....._...._. .___.... . ._____.. . _._.. ._.__ ..___._..._ ._.._.... None ...__._ . ...._..._ __....... ...__ _..._ . ... .__._.._... ._....._._. None

. _. . _. EUG 2 ...__-. __...._.._. .._.___ .. ._...._.. ..._.___. . ____._. __.. ._.__ _.. _.....__.... _..._.__ None

... _ .. _ ._._. _........ .__... _ .... ..........._.... . ...__._.. None

. ...._.... EUG 3 SD1 ._...... __......_..._..

None __.......___. None

.___._....._ None

..._._._.__._ None

. ._...__..__... None

.._......_..._.. None

_._...__._. None

._...___._. ......__...

None None ....__._.... None

_._........_. None

. None ._._._...... None

..__.._..._ None _._. EUG 3 SD2 ......._ _.._._._..

None

. None

_._..._..._. None

......._...__. None

_ ....._._ None

_._..._.._.... None Nonc None .____... None

..._..... None None

__..__. ... None

_..... None

. _.._..._ Nono

................ EUG 4 VDsI

. .._....... None

___._ ......._.. None

_... ......_....._.. None .._ None ._ ..._ None ___._ .. .._.___._.. None

_._.__...... None

.__.__..._. .. None

..._._. None

......... None

......._ None ..._. . .- None

.._.., None None _...._._....._....__.. EUG4 VDs2 ....._ .._ _ ...__._ None _.........._. None _...___._ None

. _._..__._... _._...._.___.

None

. None

......._ _..__.._._... None

__....._.. None

. None ._..._ . None ............__. None

...._.......__ None

....... None ._.._._ None ......._..... None

__....__. EUGS-
~~~ SI ...._. 1.82 2.27 1.75 ._..__..... None

...__.. . . None

..___. _..._._..__.. None

.. __ .__..__._ None

._..__-.._. .. None

._._.__ None None None

_._....._.. Irone

....__ None

...._._. None

. .__._. EUG 5-
~ 1S2 __._.. .._...... ~ Yone None ._. None None .....___ ..._...._ None

...__......._. None None

. None

. None

. .._..._. None

. ........_ None _...... None _._...._._ None

.._._.._ None

__._......._.. EUG 5- Trim None None None None None None None None None None Nonc None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) The scrubber was shut down due to a malfunction causing low• readatgs on recurcutation ilow. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Scrubber # 1 CORRECTIVE RiEASURES TAKEN: (1) Checked out water kveis and fbw, no problem, sensor not reading correcth•. ADDIT[ONAL INFORMATION i `: The W®t Scrubber was maintalned and operated according to the manufacture's instructions- The repa'as and ntamtenancew•ere done as quickty as possOrie, utii'ving overtinte if needed. i certify, based on information and be0ef formed after reasonable mquiry, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Receivr.d By: Demonstration of Causc Submitted:

= No A
~ ' iENCY USE ONLY TrackingNumber: Team 1D: DateSubmitted:

1 ` lf you wish to notify the DEQ about a technological limitation, do so here and attach supporrting information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALFTY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CtTY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: The infonnation requested below• should be submitted to the address above within 10 working days a0er the immediate notice is given. If you are using this fonn to correct a previous epon, provide only the cotrected information below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANYNAME:

8/28l2009 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Ptant Manager (918) 683-4043 FACI LITY: COUNTY: PERM IT NUM RER: Dal-Italia Muskogee 2004-198-TV (M-1)
IDate Start Tinte: Stop Time: Duration: 811512009 16:45 17:30 0:45 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 0:45 } I 

### o u 

### rs: Mi 

### n u 

### tes of Wet Sc rubb 

### e r p 

### ow n 

### t int 

### e D: Permit No. 2004-198-TV (M-1): Specific Condhion 1, EUG 5 ESTIMATED EMISSIONS: SOURCE GRP NF HCL SO i CO VOC EUG1 _.___ -. ....__ .__. ._. . .__._._... _. ..__.._._ . ........__ -_. .._... . ___....-._. EUG 2

.... .. _._.... _._.. .... .. __ ._......_. EUG3SD1 __._... .... OA9

. ...._ . ...___-..... 0.00

...__..._.... 0.21

_.__.... 7.87

.____... _....__ 2.72 ..._._..._.. EUG 3 SD2 0.27

_ 0.00
_ 0.00

. . S.

._.._. .. _... 0.92

.. ._...__.. EUG 4 VDst 0.03 0.00 0.00 6.05 0.76 EUG 4 VDs2 .___... 0.01 __. _.. _.. 0.00._. _. 0.00 3.46 _. ....._ 0.44.._.__.. EIJG5- 

# V VSI ._.---' 4.55_..._._ . 5.42 ......._. 14.99 .. ._...9.86
. _ . _.._ 2.93-._._....- EUG

~ 5- WS2 _..__.. 0.00

. _. .._ 0.01____ .

_ ... . _..0.02. .

_. . - . ... 14.06

-.. . _........... 2.35......._..

____... EUG 5- Trim ~ L22 t.56 ~ 3.48 2.44 0.68

.._ . . . _.. EUG 1 .._. . . .- __. ICt'G 2 _- . . . .. __ . .._..-._.. ' 1 ~.t~~ G3SD1 _._ . 0.59

~ ... 0.10 0.45 13.77 t`t

~ (%zSD2 -.

0.95 ___._ 0.90

. . _ --- ~

0.45

_ ---- -- ~

13.77 _._._... .- ---_.

-- Et G4A'usl 0.72 0.08 0.18 11.43 F'l G 4\ Dv

_ ._...._- 0.52 ....._._..... 6.06 ._.... 0.08. .___.5.09

_ _ \\til - 1.43 ...-__. . 1.60 ._ _ _. S. 19.60 .__.... _. ._.. EUG±-\\>> .._ _ - 1.43 1.60 8.96 _ ._. 19.60 NOx pM BASIS OF ESTIMATE ComplianceTesting

....... . ... .. __. ...._.._ _.. ___... . . __.. _ Cont Fmissions Manitoring

. _.. _.... ____..._ .... .._. . _.. _.._ Engineering Caletdation __._. ..__._._. . .. _......__ ._...__..
_._.. ...._._ ........ OperatingLogs

~ Other(explain) .._... ... _._ . ._._.... ..... _.
_._... ......_. ......... - _ _.- . . _. ... .

..._....... ....____ . ___._. ...__...... ..._ ..._.- ARach supporting data _....__. _.. . 4.t3 .. ... .__ .
._. 2.47 ._..._._ 1.94 ..._ L IS

.. 0.68

_ _,- 3.88

.... ,_. 4.53

... .... 0.95 _. ...._..__ . .

_ ..... 4.91 .__._. 2.55 ..__.. . 2.62 ..___..._ _._ 1.50 ...__.._........ 5.28

_...._ _ . 0.73 X X X

NOx Pbt

3.88 -.._..__.. 3.51 . _ .. _.__...

1.56 __. 7.73 7.73 ... .__._.__.

.. ...

... EUG2 ..__...
, . . _.-.__.-_

_ ._.__. .. . .__. .

. . . _. _. ._-.. . -.._....._

.. . . ........... ...

_. . . _.._.__

. . ......_ -

..... ..... ...

None

.... , _._.._.

._. _ .. ~ _.

.. . ___

. ..._ _. _.

. _ ....._.._

.. ......._

. .._.. . . ....__

~ None

... ... . _.. ' Cl'C.3 SD1 None

......... None

_ .._ _ None

.. ... . . None

_.....- ._... None

_............. None ~

____... . None

. .... Nonc

._..._. 'Vanr Nnnr Nnne None

.. None _. ._ _.. None

..,. _.__.

. Et"G 3 SD2 , . ..... None

... ..__. None

_.. . None

...,,_.-._ . None

.__._..__ .__........_ None ._.._.__... None

_....._ .. None

............. .. None

.. _._._..-_... Aonr

.. . ~ one

. _...._ . ~ unr

... .. Nnne None

._-._._ None

. _. ...-_..- Pa'C J VDsI None Nono .- .._. None

_ .. . . ..... None

............ __. None

__. ...__..... None

-_....__ None

_..._. ......__-__..

None None

.. None

..____...... None

____ ~ une .~ one

_.._._ None _.. _....._ EI G 4 VD,2

. None

_. _ _....-_ None

_- ..__ None None None ...._.. ..._...._.. None

._...__.... None

... None ._. -.... Nnne None

- ...... None

_ ~ onc Aone

.. None

.._.. .. F1'G 5 - R;\t . ~ 3.12

.. _.... _ 3.82

. ___.._. ~ .. 6.03 ~ . . ._.__.. . 

# -...... None

..... . _. _ None

.__. ...._.......... None

.. .... None

. . _ None

.. ... -._... \'one Nnne

...... Nonr

- \onr

. ~ 'one None

..._.-_.. ba

~ G 5- ~1~ 52

_ . . _._..- None

... ..____. None

.., _._..__. None

. _..,.... None

...._ ._ None

.._. _..._..._ None

...._.__.. None None

. _ .... ... ~ one

'

. _ ~ one

._.. None -_..__.- ~ oor - .._ ~ uuc

.___.. None

.. ._.... 

# - ECG5-Trim None None None None None None None None None None None None None None NATURB AND CAUSE OF EXCESS EMISSION: (1) The scrubber was shut down due to the caustic level being high.
(1) \Vet Scrubber 41 CORRECTI VE M EASU RES TAKEN: (I) Replaced PH Probe, recalOtrated PH unh, and restarted the scrubber.
ADDITIONAL INFORMATION*: The 1Vet Scrubber was maintained and operated according to the manufacture's instructions. The repairs and mamtenance were done as quickly as possibte, ut0iring overtinte if needed. 1 certify, based on information and beGef formed after reasonable mqu'vy, the statentents and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Receivtti By: Demonstration of Cause Submined:

~ AGENCY USE ONLY m_--..._., . r ... No
* If you svish to notify the DEQ about a technological limitation, do so here and attaeh supporting infomtation. DEQ-Form #100-920 Re4ised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALf1Y AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: The information requested below should be submitted to the address above vrithin 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the cotrected information below, sign the certification, and attach a copy of the presious repon.
REPORT DATE: COMPANY NAME:

8/282009 Dal•Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Ed Smart Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: DaNtaOa Muskogee 2004-198-TV (M-I) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 8262009 0:00 0:00 0:00 Hours:Min Phasei

7:30 10:45 3:15 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 3:15 Hours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-t98-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF F.STIMATE ComplianceTesting X SOURCE GRP HF HCL SO i CO VOC NOx PM F'PC, t

.. ... _ .. _ ....... .._.-.... .___..-... f.UG2 _... _.. . . ._._.._.__ .. ._....__.. .___..._. ~ ....-.

. .. _ .._._.... ...-.._..

. _.___ ~ ....___.___ . ..._...__ ..._.._ _ S ContEmissionshlonitorin ..___.._.._ ..__._.__ ..__..... Et'

~ C3SD1

..... .._ . ...___.._ 0.48

.. .___. 0.00 -. .___..._. 0.20

___...... . 7.67

.._._.__ . _. 2.65

__-__.-_.._ 2.41

. . _.._.._ 4.79

.__...._..__ . _ GngincttingCalculation X

_.__.... _......._ .._.___._. ._.._._.._- EI

~ G 3 SD2 ._... . _. 0.27 ._...._.. 0.00

_ __......_. 0.00

_. . 6.05 ._..._.. . _..___ 0.93

__.. ..____..._ 1 .97

. -...__...._ . 2.58

.........__._. .._ Operating Logs X

...__..._ __...... . . . __..._. ._..-..... EUG 4 VDst -.. _.. .-...._...... 0.03 ....__... 0.00

. .._._.. . 0.00

__ ._._. _....._._.. 6.39

. .

.... 0.80
_ _ __. .. 1.25
_

_ . . . 2.77

_ ._._. ..___._... ._.. Other (explain)

. ____.... _.__.. _._.._.__ . .__.__.... EUG4VDs2

... . 0.01 _....... 0.00 ..___. 0.00

. ._ 3.St

._..._.. 0.44

. .._..._._.. 0.69 1.52 .._ ..... . ............_ _._-___. ........... _._.....- ._....._...._... EUGS -

~ VSi ..._ 0.02

_. 0.28

...._._. 0.32

.. . . 12.81_._.

....... ~ -.- 0.8,i , 3.3' ...._._...._....__.. 2.59

.. . __._,...

.._.__. . .....___ _.____ __......... EUG

~ 5-WS2 ..._ . 18.92

._.._.. ._.._,_._ 22.52

~ 62.29 4 _0.99
_ . . 12.16

._._ 16.12

.__ .... _ 2L93 .........__ ___..._ .__._.__.. ....__... ...._.__-. EUG5-Trun 1 1-65 2.10 4.69 3.29 0.91 1.28 0.98 ...___. -...___ . _ - _...__._ . ......_.. _.. . _. .. ._. Attach supporting data ALLOiVED EMISSIONS: SOURCE GRP HF HCL SO r CO VOC NOx PM EUG 1 ._ _.... _.._._ F.I tC 2

.. _._ .. _.__ _ ....... .. ............... _ .._ _.... . ._...__...._ ....._____ _......._.__............._ 1CCG3SD1 0.59

. 0.10 _.__._.. OAS

__.....__.__. 13.77

_._..._.... ...._.._..__.. 9.67

_ ....._..__ 3.88

.__..__.._... 7.98

_._._.._._.__..___... I:C(: 3 SD2

_ . .. . .. 0.95

. . .. ... ... 0.90

._ _.. _._._.._.. 0.45 13.77 _.__...._._. . .... ._.. 9.67

.._... . ___....._... 3.88

. __...._.__. . 7.98

. ...__..._._ __.__.._... ECC 4

~ 'Dsl

_ 0.72 ..._._. 0.08

. .._..__. ._.....

0.18

.. __.__..._ _ ... I1.43

_ __.._..._.. . _-__ 38.33

__.. _ ..... ._.__.. 3St

. _..__.....__ . 5.85

... _...__._._ .._..__ EUG 4\'Ds2 0.52 0.06 0.08 5.09 17.04 t.5

...... ._ . ...__....... EL'G5-NCtil 1.43 _....._. 1.60 ..- ...._....._.._. 8.96

..- _-__._... 19.60

._.. ..._... 4.78

._..._. _.. _. ...__.. 7.73

_.-_-_-.. 6.71 .._ .__.....____..___.. EIiG 5-\\'S2 .__ . _ __ 5.71

...._._._ ...._.. 6A0

.. .. 35.84

__._.... ._ 78.40 _._ .._. _ ............... 19.12

. ..._.___. 30.9t

.. ......._._ 26.84

.. _._....... ..__.___. EUG 5- Trnn 1 3.57 3.88 9.68 6 75 3 67 2.00 180 EXCESS ENi1SSIONS: based on I hour limits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI 50 i CO VOC NOz PM HF HCI SO i CO VOC NOz PM

t ,EUG

_ .._ .. ...___. .._ _. _.. _.._.._._ ....._____... .._..__._ __ __... ...._._.._.._.. . _._.._..___ . None

. . ._._..._ .. __.... .__.._.._... _____ .... . ._._..... __...__. None

. ... _ ... EUG 2

.... .. _ . .._ .._._.._ .__....... .. _._._.__.. . None ..___ . .._ __..._. _._._._.._ .._. __. ._. . .._. . .._..._._.. None .____.._. EUG 3 SD1

.... .._ _.. None Nonc ..._.__..__. None

_,__._..._. ......____

None

... __._._.__ .............._.

None _.. __._...__ None

.___ ._____-_..._ None

_...... .._.,_ None

..._ ...... None

.......... None .___ . None

.. ._.._ None _..-.._. . None

.._.. _.__ None ._.___.._.._ ICI'G 3 SD2 _ __.__. N . ......__....

None

. ......._ None

_..._._..... None None

.. ...__ None

....__ _ . ___ Nonr None ..._. ..__ None None

_._.... Nunc None

. None ._.. None

_ .......___ Nunc

_ .. _.._ ._.__. EUG 4 VDsI _._. ...___. None

. __._... None _. ._..._ . Aonc

............ None

. _. ___......._. None

_.-____._.._._... None None _..._..___... ...._ None

_.__.-- None Aonc Aouc None ..___.... . None

_.._..._ None ...__.._._-. EUG4 VDs2 _.. _... , . None

_....... . ...__..._. None

_. ...__._._... None Nono _.._.___ . .__ None

_...... ......_....__._ None

._ _._. ._ ._. None

.........._.__ _ None

.__.... . None

. None ._ .._... None

_ None

.......-._ None

__.. None __._._.__ EUG 5-
~ VS1 ._ . _.- ._ __. None ...._._.. None -.. ....__.....___ Nonr

. None _..._._._. _.._. None

_.._ __.._.._..._ None

._..._._. . . None

. ... . _. None

_._... None ..__....__. None

.. __. .... None None

._..._.... None

.._._._ None ...._.__.... El'G 5- WS2

... . _ 13.21

......... ....-.. 16.12

_.. . 26.45 None ...____ . ._. None

_.__. ....__.,._.._. None

......_._ None

....._.._. . None

_..._. .. None .._.. ..._ Nonr __._... None

_ None

..._.__ None

__..._._ None

___... EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: ( I) \Vet Scrubber #2 w•as shut down due to the quench itow• bemg tow• PROCESSES AND EQUIPAIENT INVOLVED: (1) lVet Scrubber #2 CORRECTIVE MEASURES TAKEN: (t) Cleaned nonles, cleaned sludge out uf tank, cleaned inipenger nonles, checked pumps, and restarted the scrubber.
ADDITIONAL INFORMATION*: The SVet Scrubber w•as maintafned and operated according to the manufacture's mstructions. The repairs and mafntenance were done as quickh• as possible, utitiring overtime if needed. I certify, based on information and be0ef formed aner reasonable inquire, the statements and'mformatiun in thts document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Reccived By: Demonstration of Cause $ubmitted:

= No AGENCY USE ONLY TrackingNumbcr: Tcam 1D: DateSubmitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infomtation. DEQ-Form #100-920 Revised February 8, 2008

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfi'Y DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above vtdthin 10 ivorking days after the immedfate notice is given. If you are using this form to correct a previous epon, provide only the corrected infonnation beloxv, sign the certification, and attach a copy of tlhe previous report.
REPORT DATE: COMPANY NA67 E:

9!4l2009 Dal-ltalla NAME OF INDIVIDUAL R6PORTING: TITLE: PHONE: Ed Smart Plant blanager (918) 6834043 FACILtTY: COUNTY: PERMIT NUMBER: Dabitalia Muskogee 2004-198-TV (Yt-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 8l28t2009 0:00 0:00 0:00 Hours:Min Phase 1

15:40 16:10 0:30 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 Hours:Minutes of Wet Scrubber powntitne APPLICABLE LtMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Speciric Condttion 1, EUG 5 ESTIMATED EMISSIONS: BAStS OF ESTIMATE ComplianceTesting X

. ._. ..._..._ . _._..__ . .. ..__.__. SOURCE GRP HF HCL SO s CO VOC NOx PM EUG I ..._._ . .._. . .... .. ._____ .._.__.. . ____.. ...___ _..._._.__ . ...._..._." _..._... __. EUG 2 ___._. .. _.._ .._ .__....__ .. ......__ .._ ._. . . .._..._... ... Cont Emissions Monitoring ,_.... ." _...._.. . .____.. . __ _.._.__.. LGG 3 SD1 _... . _ _. ...._.__ 0.40 ___..._. 0.00

. . _.._....... 0.17

.._........ . -.. 6.47

_..__ _ _ ._.._..__

2.23 _.... 2.03

...___..- _ . 4.03

._..__.-.. . .. Engincering Calculation X

....... ..._.._... . . . _.._..._._. C2'G3SD2 _.. . ..__... 0.25 ___... 0.00 _..__. 0.00

......_-.. 5.65

.__..... .....__ 0.87

....._...._._- 1.8a 2At ._._...._ ..._...._. OperatingLogs X

......_. .. ......._.__. . _..__.._. ._...___. I ~a~ G a\

~ DSI

_ ..._._._ OA3 ....._._...._ 0.00

. _...._....__ 0.00

. . .._ ...... . 6.20

......... .._ 0.78

.__ ..__......__. 1.21

.... _. 2.69

... ._... Other(cxplain)

.......... ....._... __.... . ..._...- I(I:(; 4 Ds2 ___.. 0.01 _ 0.00 .._.__. 0.00

_ . .._. 3.50

....... _._.. 0.44

. ....._._. 0.69

_..._._ 1.52

.. ....._. .._. ..... ...._... ....... ... ....... k:UG>-

~ YSI

.. . 0.02

. ,.........

0_l0

. 035 13.81 _.__. 0.90 4.70 2.80 ._..._.._. .._ .__._._. .._..._. .. _ .._... EUG 5- WS2 --- 2.94 3.50_ ._. . ._.__ _ 9.68 6.37 ...__.. . ...... L89 ............

. .......__.. ..

.. GO ._. _. 1., l

_ _..__. . _.._.... .___.. ._..... EliGS- 'frim 

### -.._-- 0.33 ..__ OA2 

### ._. 0.94 

### ..... 0.66 .__....___ 0.18 0.26 020 ._.. . .__._.. . _.___.. .._._.__... ..__-.- Attach supporting data ALLONED EMISSIONS; SOURCE GRP HF HCL SO i CO VOC NOx Pht EUG I ..__. ... . _. . ...._. ...___. ., .__...._ _...__ .. ..._ _..._. ...__ ._.. .__.-...... _ ....__ _............_.._.. EUG 2

... ._ ..._.. .... ........... .. .....___... . _. _____... ....._... ._..._... _..__._.. . _.....__.__ ._..._..... ..._._..... EUG3SD1

_ . . 0.59

...._... _._.-__ . 0.10 ..__._ 0.45

._.._-_ ... t3.77

.. _.. ". 9.67

__.. -.__._..._.... 3.88

.. . __. _

..... 7.98

......_...".. _.._.__... F:CC; } SD2

_ . 0.95

. ...._ . ._._..... 090

.. .._..__.. 0.45

_..._.. .._ . . I3.77

. _...._. ...._ 9.67

._... - 3.88

._........_ 7.98

_...__... . I

~ :UG ~1 ~~ Dst

.... 0.72

....__ .,.___..... 0.08

_ _._......__ 0.18

______......... 11.43

_ 38.33 .._ .....__-._..._ 3.51

..__......_ 5.85

_....._. ...._.._.. EUG a VDs2

... _ .. 0.52 _..__.._- 0.06

.. .......__...._. 0.08

_......___ 5,09

_....._.._ ...._..._ 17.04

...... . ._.-_.. 1.56

. ...._...... 2.60

... ............" El'G S- AA

~ S t

.. .... t.43

.__... . ..._.._..__ 1.60

.. 8.96

._.._ .......... .. 19.60

...__.... ..__......_... 4.78

......__.._... 7.73

._ ......._ 6.71

.._....._._ ....___... EI - C 5-AA

~ s .._ 1.43

.. -...._.___... L60

._....._._._ 8.96

. _ .___._... 19.60

.._.._". _..._.._ 4.78

.. ...___..._. 7.73

...._....__._. 6.71

.._._._ ............. EUG 5- Truu 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on t hour thnits) EXCESS EMISSiONS: 24-Hr Totals SOURCE GRP HF HC) SO i CO vOC NOx PM HF HCt S0. CO VOC NOx Phi EUG 1

.......... ._ _...._ ...._. _. ..__...._.... _._...... __. _....__. _ .......... .........._ . _...._..._ None ._._..._. _. .......... .._._... .._..... __._._.. _...._._ None _._.__.... EUG 2 _.._.- _._"
. ..... ............. ..____... .....__._.. ....._._.-. ._......_._ ...__...__.... __. None .....___._ _. __.._ _..._.._ .__.._.... _.._._.. Nonc EUG 3 SDt

.. _......_. .~ 'one

..._..... ..._......-.. None

_ ..__._.... None

_._..__. . None

_.._".... ._.. None

_._. ___.._... Nouc

.._..__. .._ None

...._.. . None

._...... None

..._._.._. None

..._ None

. _ None _._....._ None

__.._.. None

-__.._ EC'G 3 SD2 .._ __.. -

._ .~ onc

.... None

. ._...__. None

___.._ None

__._... ._._. None

._... .-.._.____. ~'on~~

_.._._. ._. None

_...___ .. None

._ _... None

_.._.._ None

.___...... None

..._..... None _... None

.......... None

.__..._.__ EUG 4A

~ USt

.... _ _ ~ nnc

. . None __..._.. None

.____.... Nono

_._...._. __" None

___ .__.__.. None

..._ ..._...-... None

.._._.__. ... None

__...... None

....__. None

..._...... None

.__.... None

... None ..._..__ None

..._.__ EGG

~ FV
~ Ds2 _.-...... ... \onc

..__ _. _._..-..__ None ..._.... None ._...___.. None

._.__... .._..___ None

.,..___....... None

_.._..._ None

.........__ ..____._

None None _._.__..... Nono

..._...__. :Vnne

__ _.-_.- None None

___...._. None

.......... EUGS-AA

~ Sl _._...-.. None

... .. _-....__._.... None ........__ None

_....._.. .._.. None

_.._._._.. ...._. None

__.. _- None

_.._..__.._ None

......_._. _. None

_...__ Nono

__....._._ None

.-....__.._..__.. Aunc Aonc None

..__.__.. None

. ._...___ EUGS-\\52

. 1.51

_...... ..-...__.... 1.90

.. _.._._..__._ 0.72

.._........... None

.._ _.._ . ...._._. None

,.___._... None

._.....___. None

_._._.._ ..__ None

___...._ None

.___.._._.. IVone None

_.._._.....__...._..._._ Nonc Yone

............ None

........... EUG 5- Trim Nono None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) Wet Scrubber #2 was shut down due to the water level reading extrememh low. PROCESSES AND EQUIPMENT INVOLVED: (1) 1Vet Scrubber 92 CORRECTIVE MEASURES TAKEN: (1) Replaced the low level probe and restarted the scrubber.
ADDITIONAL DYFORMATI ON*: The 1Yet Scrubber was mamtained and operated according to the manufacture's instrnetiuns. The repairs and mamtenance were done as quickh , as poss2tk, utiliiing overtinte ifneeded. 1 certify, based on information and bellef formed aBer reasonable inqufry, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Reccived: Received By: Danonstration of Cause Snbmitted: = No AGENCY USE ONGY TrackingNumber: Tcam tD: DateSubinitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supponing information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUAL(rY AlR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address aboee xvithin 10 working days after the immediate notice is given. If you are using this form to correct a previous port, provide only the cotrected infomtation below, sign the certifieation, and attaeh a copy of the previous report.
REPORT DATE: C0MPANY NAhiF.:

9/4Q009 Dai-Itaifa NAME OF INDIVIDUAL REPORTING: TITLE: PtiONE: Ed Sntart Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: Da41ta8a Muskogee 2004-198-TV (M-1) DATE AND TIi14E OF EXCESS EMISSION: Date Start Tinte: Stop Time: Duration: 8/3012009 9:45 10:55 1:10 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 1:10 Hours:iVlinutesofR'etScrubberpowntime APPLICADLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-Tt' (M-1): Specific CondOion 1, EUG 5 ESTIhtATED EMISSIONS: RASIS OF ESTtMATE ComplianceTesting X

..... ._. ._.. .._. .. . SOURCE GRP HF HCL SO i CO VOC NOx PM1t Fa1G 1 _......._ .......

.. _ _.__..._._. ......._ __...._ .._._._ . _..__.._._ . _....... ._........ EUG2 .__... . .. ..._._. . _. . . ....- ~ ContFmissionsMonitoring ._._._ . . _...._- h.l

~ G?SDI

. _ - ~~~ - 0.45

._..._.... __.._._ 0.00

~ - ~~~~~

. . ___. ... 0.19

_. __...... 7.26

._ ....__. 2.51

..__ __........... 2.28

.__..._ 4.53

..__..__. .... .._._ _._.... ..__._
~ ginceringCaiculation X .._._... ...__ ...__.. LI G 3 SD2

. 0.26 0.00 _.._...... 0.00

.._..._... __. . 9.7i

.__._ __. 0.88

_.._ .._.__..... t.86 .._._...._ 2A4

............_. . ._ Operating LoBs X

.___... _.__. _... ...... ..__ ... I:t:(;4 Vn

~ 1 0.03 __.._. 0.00 _. . __. 0.00

_ . . 6.49

. . . 0.82 _._......_ 1.27

. ...... 2.81

_ _.._...._.. Olher(explain)

. __...__ . _. _.. _... ..___.. _.._... P:t - G 4\ Ds2

.. 0.01

..... .....__ _ _ 0.00

_. ....._... 0.00

. 3.47 ._........
_._... __...__. 0.44

. _..._. 0.68

_ . .._ 1.50

.. _ .. . ..___ .... . ......... __ ---. ___ . .._ ... .....__. El' ~G~-~ VSI

. . 3.96

._.___. . _ _. 4.72

_ ...._._ 13.06

_..... _. 8.59

._ .. __._... 2.55 .___._. 3.38

..... _ _ ~ - ~~~ 4.60 ._.. _ _......... . ._...._. ___ _. . .___ . ____..

_ ECG$-\1ti ~ . 0.00

.._...... . _._.... 0.01
_ 0.01 7.08 ._... 1.IS

_ .._..._ ..... ~ 2.28

. . ..... 2.08

......_.... ._. _....... _....._ ...._._ __.__ EUG5-Tr'un 0.47 0.60 ~ 1.33 0.93 0.26 0.36 0.28 ......_. ..._..._. . .. .... ......_._ . .__._._ Attach supporting data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EUG t _._ . ___....... . _...... .. ___....._.. ....__.. . ...__.._.. ..___......_. __ __.......... .._..._._ _....._ __.._..._. F.tIG 2

. _ . .. .._.. ............. .. .__. ___. ..._...._.._ _....__.. h:UC 3 SDi 0.

~ 9 . 0.t0

.. ....._ 0.45

... _ t3.77

..__. . ....._._ 9.67

. . ............. 3.88

_. _._ 7.9_8

_ ._. _. 1CU(:3 8D2

. 095

._ ._.__.._._ D.90 .._.....__ 0.45 13.77

. _-.._..__....___ 9 67

. 3.88 7.98 ____._.....___.__.._. CI'C:4 1),1

. 0.72

._.... __.,__.... 0.08

._... 0.18

_.._._..._.. ... 11.43

.__._ .... ...... 38.33

.... _._._... 3.51

_._.._.._.._ 5.85

.____._.._._.....__._ EEG 4 ~~D~2
.. __ 0.52

._._._ ..___..... 0.06 ........._ 0.08

..._._.._._._ 5.09 17.OJ ._......._ ..___...... L56 2.60 ICUGS- ItiSt 2 .8 5 ._...._._...... 3.20

......_..... 1 7. 92

_._._._ 39.20

__._.._. ......_..... 9.56

.. . _....._._ 15,45

__.__.. 13A2

.._...___..___.._._ EUG5-

~~ ti? .__ . t.43

...... _ .._. 1.60

._ . ........ .... 8.96

_.__._. 19.60

.____...._ .. . _.... 4.78

._.._ ........._ 7.73 _._..__ 6.7t

. ..__..__..__....__... EUG5-Trim 1 3.57 3.88 1 9.68 1 6.75 1 3.67 1 2.00 1 1.80 EXCESS EMISSIONS: (based on I hour timits) EXCESS EMISSIONS: 24-Hr Totais SOURCE GRP HF tiCl SO, CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUGi __.._. .._.. __._.. ...__.... _....._.... __._.._... ____.._. .._._.,.__ .___......._.. .._..._... .. None ......._... ....___ .._.__..._.. .._...._. ._...___._.. _..__.. None ___._...... EUG 2 _. ........ _. ____... ._..._.._. _.____._ ...---...__. . . ... ...._ None

... ..__.._ . . . _ ...._._. .... .__. ... _.._ ... _..... None .._.._.. EUG3SD1 None

_.._.. . ...._.. None

. None

_. None

... __. . ._ Nonc

_ _ . ._____.. None

.._......_.. None

. _.. luue _ None

.... .. None None None

.. None .....__ None

. ...._._.. EUG 3 SD2 None

..._._.. . _.. None ..._._._... None

._-. __._. None

.._.... _._. None

__.._ . _ .._ _ None

. _. . None

. __.. None Nonc Nonc None ~ None

..... ._.. None None ........_. EUG4 VDsI

... None

...__.._ . ._.

..._... None

. . _..__... . None

_ . _... ___... None

. ._... . . --- None ~~

__. .._.__.._.._ None

. . .....___. Nmte

._..... \'onc Ivnnc Nnne •~ 'onc None _.. ... None

~ ...._. . _ None

......._.. EUG 4 VDs2 ..._._. None __._..._ None __...._. None

.._._.__.._ None _.. None _..... ____.._.. None

._...___. _.__.._....._ ~ None Nonc ._...._...__._._., ~ \une

_ . ~ 'ooc Nouc - None .__...... None

._........... ~ one

........... EUGS-1VS1

_ .._..... .._.._.__...

Ltt _.._...._ 1.52

__.._._. None

..__.._... None

......... .___. None .__._-.. None

.. _.____... None

._....._.._ None

......... ...... ~~ une

. Nonc None None

......... None

.........._.. None

._._.._. EUG5-tiVS2 ......._ ._.._. None .._...... None .._ _._.__.._ None

. ..__..... None

... ...... ... None

.... .......__.._ None

._...____.. .. None

._._...... . None

......... Nonc

............ None

..._. None

... None

._..._. None

...._..._. None

.__.._... EUG 5-Trvn None None None None None None None None None None None None I None IVone NATURE AND CAUSE OF EXCESS EMtSSION: (1) The scrubber was shut down due to a malfunction caused by a water leak at 2" ntale adapter to regulator for ehy water infeed. PROCESSES AND EQUIPMENT INVOLVED: (i) Wet Scrubber 41 CORRECTIVE MEASURES TAKEN: (1) Install new make adapter on rme and restarted the scrubber.
ADDITIONAL INFORMATION' x ': The 1Vet Scrubber w•as maintained and operated aceording tu the ntanufacture's instructions. The repairs and makttenance were done as qulekh' as possibie, utilirine overtkne if needed. I certiry, based on 9nformation and belief formed aRer reasunable inquiry, the statements and informatiun m this ducument are true, accurate and complete

SIGNATURE OF REPORTING PERSON

DateReceived: ReccivedBy: DemonstrationofCauseSubmitted: 

### = No AGENCY USE ONLY Tracking Number: Team ID: Date Submitied: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALrrY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FO" NOTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the comected inforntation below. sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

9f11l2009 Da4ltalfa NAMEOFINDIVIDUALREPORTING: TITLE: PFIONE: Rick Williams Plant Manager (918) 6834043 FACtLITY: COUNTY: PERMIT NUMBER: DaI-Italia Muskogee 2004-198-TV (bf-I) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Tinte: Duration: 919/2009 10:30 11:00 0:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 0:30 Honrs:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Perntit No. 2004-198-TV (M-1): SpeciBc Conditlon 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF F,ST(MATE ComplianccTcsting X .._._...._ . ._ .._... ._.. .._. ___. _ . ...._. _. ... SOURCE GRP HF HCL S0 2 CO VOC NOx PM EUG 1 ......_. _._..._ .._.. _.. ._._.__. _ .__._ ....._.._._ ...... ._. _. _ ..__.. _..._ .._.._._. . __ ......._ . EUG 2 .....__. .......__ ._..._....__. .._.... _ ..__.._-_. ._ .....__ _..._..... ._._... .. Cont E.missions Monitoring ...___._. ....... . .... ._ __._.. EUG3SDt ......._. 031

...___ . ........ 000

. .. _.. 0.13

...__.._- 5.03

-- _ 1.73
_ L58 .._._._. 3.14

_ _. _. _.. F ~ gineerinbCalculation X ..._.._._. ....._..... ._._..._ . EUG 3 SD2

.......... ._.._._. 0.30 0.00 ....._.. ._._....__.. 0.00 ._....... 6.76 _.. 1.04 _.... ._._..___. 2.20

__...._ 2.89 Operating Logs X _...._.._. _.._.._ ......._. . __._.... _.__.. EUG4 VDsi .._....._. __._ . 0.03 0.00 _._...__.. 0.00

.__...._ ._._ 7.?J _. ._ . .. 0.91

._ ______ 1.42

.. . .._____ 3.14

. ._...__. _ Other(explain)

__....... _._. .... ...___ . .. ......_. .__..... ELfG4 VDs2 ._.. ... _ 0.02

. . ..... 0.00 _..._.. 0.00 .._ 7.63 0.46 .._._._. 0.7t

. 1.57

.. .... ..__. _.... ... _ ._._ _. _....._ ..... EUGS-

~ YSI _...._.. 2.'7a

....__. . . 3.50

_ . . _..... 9.68

_ .... . 6.3",

...... 1.89

_ . _..._.._.. 2.5t _._.. 3.41 ..__ EUGS-

~ YS2

. ... . 0.00 _.__ O.OI .._. ......__ 0.02

_ ___ 12sC

__.... . . 2.t0

_ _ _._._.._ 4.05

_ 3.69

_ ... ._.._._ __...__ .___._._ __._._ ____.. EUGS -Trim - L10 1.4t 3.13 2.2U 0.6t 0.85 ~~~~ 0.6G .........- ..._..... ........._ ...___._.. . ___._ Attaeh supparting data ALLOWEDEMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EIIG ( .._... .. ..._..... ......... _,. ..._...._...... ....__. ..._..._... _._..__ ._..__..__.........__.._. ..._......__.._...__ I!lIC2 _. . .......... ......... .... ......___.......__ ._. . _..._... ._.....__ . _ _____.__ ...._..._. .._.._..... __._.... I[tG 3 SDI

. 0.59 _.___... __._... 0.10

__. . _.._.._ 0.45

_._. 13.77

.___.._ __.. 9.67

__........_ 3.88

. .._.. 7.98

....__...... __..... T

~ ;I

~ G3SD2 ..__ 0.95

.....__. ....._,_._.. 0.90 0.45 __.__........ 13.77

...._._ ......_. 9.67

_.__ .. ..__........... 3.88

. 7.98

_.....,._... _._..__.. EUG 4 VDsI ....._ 0.72

..___ ._.__.... 0.08

.... ._._.__..... 0.t8

. __._.._._. 11.43

.______. . ..._._.___ 38.33

..._.._..._.... 3.51 ._._... .. .... 5.85

..__..,.___.._.._ EIIG 3 VDs2

. ...._. 0.52

...._._ _......._ 0.06

.__._....._ 0.08

......... 5.09

_._._._ _..._.._._._. 17.01

............._... 1.56

_...._...__._ 2.60

.._._....__._..__..... EUGS-tiYSI

. ____.. IA3 ___._....._ 1.60 .....___._ 8.96 .._.._........_ 19.60

.__.__.. ..__...__.._ 4.78

............_.... 273

..__.. .._ 6.71

._.__._.._.__....__.. EUG 5- WS2

. . ........._ 1.43

_.....__... .._.___..._. 1.60

.. _ ....._._.._ R.96

. . ...__._.. 19.60

.._...___. _._. 4.78

_._.... _....___...__ 7.73

_ ............. 6.71

____._._...__ F.UG 5- Trim .i.57 3.88 9.6R 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on t hour timits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF t1C1 SO s CO VOC NOx PM tiF HCI SO, CO YOC NOx PM EUG I

. _,._._.__ __..__ ._-.....__. .........__... ..__.._......... _..___...... .._._........_ ___ ...... ...... ........... None ...__... ._ None EUG 2 ....._.. _._. . ..._. ... ___... __. .._....... . ...._...__._ . . .......... ..... .___ _ .. ._ _.._..__ . . .._._._.. None ...._.._.... _ __._...._ _.___.___._ . ..._.._. ._.. . .___..._ . , _.......... None

. _....._... EUG 3 SD1 .._..__._._ . None

._.._... ...._.._ .__ None

._._..._ ... None

.............. None

.._..__. ._ ._._ None

.._.... _....___... None

...._. _.... None

.._.._ .._. None

._.__._ None

.._.__._._ None

. .._.._.. None _.._ None None None EUG 3 SD2 None

.__...... ..,_._.. None .._.._. None .._._._...___... None

_..._.__.__ _..... None

...... _._...__._ None

. .._..._.___. None

._._._. .........._.._

None None None

..._....... None None

.. None

,...... None

.......... FO(:4 Vllsl

_ . None

...__... _.._.. None

.__ .....___.___ None

____.....__.._.. None

_...._._._ None

...__... .._ ............. None

.. .....___._. None

.......__ None

__......... None

_.._.._.._._ None

. _.._._ None

...... . None _._..__ None

. .._..._._. None

............

. 6d'G a VDs2

. None

. . .__. _..._ None

...._ _..._.__....... None

__.__..._ . . None

_._..._._. .. None

.___ ___...._.... None

. . . .__.._...._ _. . None

....._ .___ None

...._..... None

.._..._.._ None

. . __.._ None None

_. . None .._._ _ _. None

.. _......._.. t:UCS-AA

~ SI 1.51

-..... ............. 1.90

.._..........__ 0.72

_.._._._ None

.._.._..._ . None

......... _._..._.__ None

... .__._..__ . None

........_.... .... None None ....__._. None

...____.__.. None

. _ None .__..___._ None

_ _..._..... None

._....__.. El'G

~ -AA"ti2 ...____ . Yone ._........_ _._. None

_.... ._...__........ None

_...._..._ . None

......_._._. ._. None

_._._ None None

. ._.._....._. None

...._... None

._......_ None

_..._ None

. . Nono __....___ None

.. _.__..... None ..__.....__. GUG 5- Tr)m I one None None None None None None None None None None None I None None NATURE AND CAUSE OF EXCESS EMISSION: (I) NVet Scrubber 91 weas shut down due to the PH Readings being low at the bleed and on PH transmitter. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Scrubber#1 CORRECTIVE MEASURES TAKEN: (t) Replaced PH probe and cal8trated'm buffer solution.
ADDITIONAL iNFORMATION * : The Wet Scrubber was maintained and operated according to the manufacture's instructions. The repairs and maintenance were done as quickly as possible, utifving overtune if needed. I certify, based on information and be0ef fornted afler reasonable inquiry, the statements and inforntation in this document are true, accurate and cumplete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Dcmonstration of Cause Submitted: 

### F----] 

## ~ No AGENCY USE ONLY TrackingNumbcr: Team ID: DateSubmitted:

' 1 If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infotmation. DEO-Form #100-920 Revised February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA C(TY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The infomtation requested below should be subniitted to the address above vtithin 10 working days alier the immediate notice is given. If you are using this form to cmTect a previous report, provide only the corrected infonnation below, sign the ceti6eation, and attach a copy of tlie previous report.
REPORT DATE: COMPANY NAME:

9t1812009 DaFltalia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick lVllriams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: DaI-Itafia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start 7inte: Stop Time: Duration: 9117l2009 7:45 15:00 7:15 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 7:15 Elours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-t): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTcsting X .___.._ . ...__.. ...._._ ..___.. ........._ SOURCE GRP HF HCL SO i CO VOC NOx PM EUG I

.. __.._ ..____ _ ___. _....__. .......... 

# _ ... ...... __-___ EUG 2 __.....- . ....._ ._ ._._____ ......._. _.._. . _. _ .... .__....._ .__._._ ~ _ __._.._. Cont Emissions Monitorine

__.._... ..__._. .._..... .___._. . ...___- EUG3SD1 ......._. 0.48

__...._._. . __... 0.00

.._ _.._.... 0.2i

..__..__...._..._

7.74

.. ......... 2.67

.._. .._..._. 2.43

..___.. 4.83 ...__.__..._. EngineeringCaleulation X

___.... __.... _..._... _..._. . _-_--- EUG 3 SD2

.. 0.34

..-..._. . 0.00 ....-.._. 0.00 ...., .. 7.65

____.. L(8

. 2.49

.. . 3.27

. Operating Lngs X ...__.... .. .. __ _.. EUG4VDs1

....... .._ ..__ 0.03 .._.. 0.00

.... .....__-. 0.00

._ .. .. _6.93
. ~~ . 0.87 ~~~~~ ._.... ..__.._.... 1.36

. . _3.01 ....._. ...- Other(explafn)

_ . .-._.. ._.._.... __..___.. EUG 4 VDs2

..... 0.01 .._._ 0.00 0.00

. . ...._ . ~ 3.a8

_ 0.44

....... ......__. 0.68

._...... ~ 1.51

__ ._ ._.......__ ...__-. ......_. ......_. .. ___ EUG5-WSI

. .,..., . _ ... 23.76 ..__.- 28.29

... __. 78.24

. .... .. ..._ ~ 51.48

.. .... 15.27 20.25 ._..._. . 27.55

. ..... _.._.. ... ........ ..__.. _ .__._._. ._._.... ._ . . ... EUC_5-R

~ S2

. 0.o0 0.01

_ ._....._ 0.02

._.. . .. 14.04

.-._. . 215

___.. .. .._..- 4.52

_. 4.12

__.. . . ...._._.- . __ _. . .,_....... _._.... _ . ... . EUC.S-Trim t.

~ 41 1.80 4.00 2.81 0.78
- ~~ 1.09 ....... 0.94
-.......... _.___ -.__. .._._._ _....._ Attach supporting data ALLOWEDEMISSIONS: SOURCE GRP HF HCL SO t CO VOC NOx PD1 EL,G t

.. .. __ .... -_ .. _ _-. . ..._._. .. ._. ..... . ___... _...._._...__ _.___.. . _. ....._., __ F.CC 2 ._ ...._..__... ..._._... .... _... EC(:3SD1 ~ ~ 0.59

..... 0,10

.. . ......_. 0.45

. 

### ._.-- 13.77 967 _._.. ,___.._.. 3.88

. . _._. 7.98

...__..-- ._......_. IiCG 3 SU2

. . . 095

_ 0.90

... . . ....__.. 0.45 ~ 

### ._. 13.77 _..... _. ..__, 9.67

....__.._ 3.88

.. .. .. .,... . 7.98

_. ... .... ECG4 VDsI _. _ . ~ 0.72

......... ._..._ 0.08

. ._ 0.18

_.__.. 11.43

_._..._ ._....._. 3ti.?.3

___. .._..._.. 3.51

........_. 5,85

._. ....... ._....... EUG 4 VDs2 ... _..._ ... 0,52

....... ._... _ 0.06

_.. ..._....._.. 0.08

...._._,., 5.09 17.04

._......__ ._.._..... L56

.......... 2.60

.....__ _..._....... EUGS-1VS1 _....__. 6A2

- ....-._... 7.20

. ._.....-.._ 40.32

. 88.20

.. ._. 2I52

.__. __._.... 34.77

_......_ 30.20

...._............_._. EUG 5- WS2 __._...._. 1.43

.._._. ._.... 1.60

_ _.._....... 8.96

._____.. _ 19.60

_....__.__ ._..._ . 4.78

_.. ..._-..._.. 7.73

.._._.__ 6.7t

. .....__._._.__.... EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour Omits EXCESS EMISSIONS: 24-lir Totals SOURCEGRP )1F HCI SO i CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG 1

. .__ ..__ ...___ __ .......... _ _._ . .. . . __... __ _

. . .....__ ...._...._.._ __...-..... None

. .. _......-. . .. _.......- .. _ . __.. ....-.._. . _.._.._. None EUG 2 .

.._...._.. __.__._.._. _ .._..._._ ._....._. ___.._.._ . .__..__. ._.._...___ ____.. None ._._._..._.... ._.._._.- ._.__ ......._ ...... .. ........ ._........ None .._........ ..._.._. UG ..
, E 3 SD1 _. .. . None

.. ._.,_ None

. .._...... None

__...._ ._ None

.. . _. . .. ... _....___ None

._....._.. None

..__..-. None

.. _ ..._...__.

Nono None

.._..__. None

. ._.._ None None

. _.... None _.-._-. None 

# _..
._ E['C 7 SD? None

. _ _..... None

. . .___._. None

. ~ one None .....__._.__. ...___..._. None ...__. None

.......__ None None_ .- None None

_...... None

.._ .... None

. .......... None

.._._ EUG1
~ Dsl

_ . . None

._.._. _..._ None

_... .._...__.. None

.__-...._ None _. None ...___. ..__._...... None

......... None

.._..._. None

_.._._ None

_....-.. None

.._. None

..... ... None

.. ...... None

..__.... None ~ _ _._.,. EUG 4 VDs2 ..__...... None

..__... ............ None

..___....___. None

....._.. ._....__. None

. ._........._ None

.._...._.__. None

..____... None

........_.. .. None

.._.._. None

....._..__._. None None

_.._._ None

...._.... None

.-...._. None ...-..___. EUGS-lYSI

. .._._. 17.34

. ..... ..___ 2t.09

.. 37.92 Nonc

... _.___ . _ None

..._.._ . _.._._...._ None

. ._..._..., _ None

-..._..... ... ..........

None None

......_._ None _....__... None

.. _.. None _....__. . None

...._._._ None

... __._. EUG 5-

~~~ .S2

.. ..._.._ ... None

.......... None

._...._ _..._._._._... None _._..... None

..__...__ None

...__-......_._ None

......__.... None

...___.._ None

.__....- None

_._..... None None

....__. None ....._....._-. None

......_.... None

.........,. EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EM1LISSION: (t) Wet Scrubber # I was shut down to clean the sludge. Ni'hite ekaning a pipe that supports the mesh pad was broken. PROCESSES AND EQUIPMENT INVOLVED: (I) Wet Scrubber Nt CORRECTIVE MEASURBS TAKEN: (t) Wekied broken pipe, cbecBed mesh pad, install eirculating pump, cleaned the sludge, and restarted the serubbr.
ADDITIONAL INFORMATION * : The Wet Scrubber was maintalned and operated according to the manufacture's mstructions. The repairs and mamtenance w•ere done as quicklg as possible, util'ving overtime if needed, I certify, based on inforntation and belief formed after reasonable fnquiry, the statements and information in this document are true, accurate and contptete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: O No A(iENCY USE ONLY TrackingNumber: Team ID: DateSubmitted:
* If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infmTnation. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIYISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be submitted to the address above within 10 working days afler the imtnediate notice is given. lf you are using this fonn to cotrect a previous port, provide only the corrected information below, sign the cenification, and attach a copy of the previous repon.
REPORT DATE: COMPANY NAME:

9118/2009 Dal-Halia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick WilRams Piant Manager (918) 683-4043 FACI LITY: COUNTY: PERht IT NUM BER: Dal-Itatia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 9/1712009 6:25 6:48 0:23 Hours:Min Phase 1



### 0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:i•tINUTES): 

### 0:23 Hours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specifk Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OB ESTIMATE ComplianceTesting X ____.. .._.._.__ . . .__....__ _...__. SOURCE GRP IiF HCL SO, CO VOC NOx PM EUG I .......__ ._..__ ......... .. ....._.... ____.._ . _____ .._....._. ...__..._ _.....__. ..__._.._ . EUG 2

......... ....._.__ .......... _.____. . _..-__.. . .__....._ ...... .__._...__ _....._. ......._ ... Cont Emissiom.

~ lonitoring _._._._. .__...__._. .._...__ ..____. ......._ .. EUG3SD( .._._.... . 0.48

.._..._. ..._..__ 0.00

.. _.._._.._._ 0.21

._.__ . 7.74

_.....__ . ... 2.67

_..... .___........_. 2.43

._ ........ 4.83

......_._.. . Fsginreriri,:C:

~ leulation X

..._.... _._.._ . ..._._._. .___..._ EUG 3 SD2 _..._. . _ ._.__. 0.34 __....__.... 0.00 ...._._.._.._ 0.00

_.___.___ 7.65

_ . .._._. 1.18

_..._ ...._............ 2.49

__.__.__ 3.27

._....___..._. .__ Opere.ii

~ zg Logs X

.. _ __. . ..___._ ._......_.._ _.__ . EUG4 VDst

.. 0.03

..... ........... 0.00

- - 0.00

-.. .. 6.93

. . _........_. 0.87

. .._...__.. 1.36

........_.... 3.0(

... ....__.. Othcr(uplain)

_...__ ._........ ._.._._. _......_ ...._.._- EUG4 VDs2 0.01

.._._._ 0.00 0.00

......... . 3.48

. OA4

_ __.._. 0.68

..... .. . ~ L51

. . . . _...._.____ . ...._.._..... . __._._ .._._.... ._._... EUGS- WSI

_._ 2AR

... 2.9.5 ....___. 8.16

... ... ...._ ~ ~ ~ 5.37

~ --

__...._ . .._..__.._.. 1.59

._._.__._.. 2.11

- ~~ ~

.... .__. 2.87

._. . .. ..........._.._ ...__.__.._ . __.___ __..__.. ......___. EUG 5- WS2

.. ..___..... 0.00

. _ .._. O.Oi

......... 0.02
_ _. 14.04

.._...._ . . ......... 2.35

. ......... 4.52 4.12 _..... ...._........ ._.. _ ..._... .._..____ .. ..._._ .....__..... EUG 5- Trim 1.41 1.80 1 ~ 4.00 2.81 0.78 1.09 ~ 0.84 ......__ ___.... __...._ . _.._.__ ...__.. Attach supportmg data ALLOWED EMISSIONS: SOURCE GRP tiF NCL SO r CO VOC NOx PM EUG t

......... _....._.. .._..._.__ .. . _......__. .... _.. ... ....__._... _... ....._ . ..._ ... _......_ ._ . . .. _._._..... _. _.__.___ ._..._...._ F.1(G2 .._. . .. .__._. ......__ _ .........._. _.._..._.. ._.._... .__.__ ..._ ......_...._.__ . ......._.. ._..._.__._._. EItG3SD1

... 0.59

..___.._ . ._.__ O.10

.. . . ..._ _.... 0.45

..._..__.. 13.77

_..___. 9.67

. .....,._._._. 3.88

. ....,..__._ .. 7.98

. _,_...._..___.___ ICIiG? SU3 0.95

_. _ 0.90

._..._.. 0.45

_........._.. 13.77

.._.. ___ . 9.67 _._.._. 3.88

_ _.._.._....._. 7.98

..._......__...._...__. 1'.l'G 4 \ 'Dsl 0.72

_ .. ..._. 0.08

... ._......... 0.t8

...___...._.. . 11.43

___..._._ ?R.??

.... 3.51

. .....__._ 5.85

.................... F.l'G 4 ~ D.? 0.52

.. 0.06

.. . ........_...__ 0.08

....___........ 5.09

.__...__ . .. ._.._ 17.04

_._....... .. ........_ 1.56

._..._.. 2.60 ....._.._....... _._._._ . iCl

~ (;5-

~~ SI . t.43

_ _ __......... 1.60

._._.._.__ 8.96

__..__..._.. . . I9.60

.._._..._.. _. 4.78

_.._ . ...._..._...... 7.73

.............. 6.7t

.....__... .....__. EliG5-V, ti2 1.43

_..__.. __._.... 1.60 __._._. 8.9 6 _._...__..._ . ....._._.._...

t9.60 ..._........_.. 4.78

.__...._.._.. 7.73

......._.. 6.71

.................._... El: G? - Triun 3.57 3.88 9.68 6.75 3 .6 7 2.00 1.80 EXCESS EMISSIONS: based on t hour timhs EXCESS EMISSIONS: 24-lir Totah SOURCEGRP HB HCI SO r CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG 1 ..__.._..._ . .._ ._

... _........_ ...__.._._ ..._.__._.- . _._.. _... __ _._._ ..........._.... .__..._. None ..__..._... ..... _..._. .__._. . ...._._ .. .... ... ........ ...__ __. None

. ._._____ F.UG 2 __.._._.. ....._..... __ ._.___...... _______._ - _._._._.. ._...._......_. .__...._..... ..__.. ... None .____........ .__....... ..._...... ._...___ None ...._._..___ EUG 3 SD1 ,..... _.. . _.... None

_. .... .... None

_ . . ............. None

. _.._..___.. .. None

.__._.... ........_ None

._.... _..........__ None

._ ...._. None

.__...._.._.. _... Nonc

........_. .. lonc

.. .... None

..... None .._ .._ ..... Nnnc _. Nonc Nono F:UC,3 SD2 None

_ ... .... ............ None

.... ._.... _ None

,__...._..._. . None

_..__._.. ._ None

.__._. . .._....._.. None

.. ...___ ._..... .._ lone

._. ... ._._ None

...... Nonc None

...._. None .__ .........__.

None .. _ None _... _.... .._ None

_._..__. EU(:4 Dai None

_.__ .. _ _...__._. None

_. ..... _... None

_ ..._._.._.._. . None

__._._._ . .._. None

__..... . _.___.__ None

__.... _.. _ .._ None

_ ..__. ..... None

.... _.. __. Sooc

. .. None

... _ . None

,.._.. None ._._._ _ .. None

....._... ._._ None . _.. __.._ ...._ EUG 4

~ 'Usl

.. _ ..,..___... None .._....__ None

_._.....__. Nono

..._._.. None

.___.._ __.__... None

._....__.__. None

.___..._.. Nonc Nonc ...___ A'uue None .._... None

... ....__.._..

None None

. .__._.._ None

...___. F.tiG5-W`SI .._... _.. 1.05

.__.__ .__...... 1.35

_.. _.._.__ None

...__... . None

._.._._ ....___ None

._. ..... ........__.... None

. ._._._._. .. ~ 'one

_.... Nonc

._.._... None

. None

.. . _.. None

... None

_ None

..__....___ None

._.__-._- ECG 5- WS2

... ._... .__.... None ___.....__ None ._........_. None

.._..__._. None

_.._.._ ._._ None

.............._...._... None

__.__..__ _......._.._...

None None

___... ._.... Nune

_ None ........__ None

. None _..___. None _..__....._. None

_._.._... EUG 5-Trinr None None None None None None None None
~ 'une None None None Nono None NATURE AND CAUSE OF EXCESS En1ISS10N: (1) The scrubber was shut down due to the fiow meter reading below set point. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Scrubber 81 CORRECTI VE n7EASURES TAKEN: (1) Reset the dighal readout, reset fbw meter, and restarted the scrubber.
ADDITIONAL INFORMATION * : The Wet Scrubber was maintained and operated accord'mg to the manufacture's instructions. The repa'vs and maintenanee were done as qulekly as possOrle, util'ving overtime if needed. I certify, based on mformation and betief formed after reasonabM inquiry, the statements and information in this document are true, accurate and compMte

SIGNATURE OF REPORTING PERSON

DateReceived: ReceivedBy[ DemonstrationofCauseSubmitted:

= ho AGENCY USE ONLY TrackingNumber: Team 1D: DateSubmitted: * if you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALFTY AIR QUALfrY DIVISION PO BOX 1677 OKLAHOMA CfTY, OK 73101-1677 

# EXCESS EMISSION FORM N07fi: The information requested below should be submitted to the address above xvithin 10 working days after the intmediate notice is given. If you are using this form to correct a previous eport, provide only the corrected infovnation below, sign the cenifieation, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

9252009 Dal-italia NAME OB INDIVIDUAL REPORT[NG: TITLE: PF10NE: Rick\VOliants Plant Manager (918) 6&14043 FACILITY: COUNTY: PERMIT NUMBER: Da{-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EhtISS10N: Date Start Time: Stop Tinte: Duratian: 9l182009 6:45 7:15 0:30 Hour6:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 Hours:Minutes of Wet Scrubber powntime APPLICABLH LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No.2004-198-TV (M-1): Specific Condhion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X __..._._ . ____... . _ . ...._...._. SOURCE GRP HF IICL SO i CO VOC NOx PM1{ EUG1

. .._ . _...__.. ............ ..__...._.. . _...... ..__.._ .... EU 6 2 _. ._.__.. ....__ _._.... .. ... _ . _... .,..._.._.. . ._ _ _...._ ~~ - ~ ConlFmissionsMonitoring ..._.___. ..._._ ..._.__.. ._. EUG 3 SD 1 ._ 0.55

. . .. . . 0.00 0.24

. .. . . 8.92

. _ . _. ~ 3 08

..... __..._._. 2.80

. ...... 5.57 Engineering Calculaiion X

. . ... LtC;3SD2 

### .._. 0.32

._. . ... 000 '

. ...__.._... 0.00

....._.... 7.21

....__ . . .. _ Lll

..._. .....____ 2.35
. ~~ 3.08 ......_. .___.. __ ...- OperatingLogs X .._._..__ .. . __.._ t:tJG4 N Ds1

.......... 0-02

_____. 0.00

.. ____ 0.00

...._._ ..._.__

436 0.55

_ ._._. _.__....__ 0.8_ ~ __._.. _ 1.89

.___.... ._ Otha(explain)

..__ .. ........... _...__... .._....._ _...._. CI

~ G 4\

~ Ds2 0.02 0.00 0.00 3.58 __. .. 0.45 ._.. 0.70

. . .. 1.55 Et'GS-V4'St 3.29

. . ~ . 3.92

. ._...._._ 

### . I0.83 7.t3 2.t1 ._._._. 2.80

. . ...._ 3.81

_ .. .. _.... . ._...__.- .___..___ ...._..._._.
. ~ EUG

_ 5-\VS2 0.00

.___.. ....._._....

0.01

.. 0.02

. _._ 13.90 2.32

. 4.4R .._..._ .__ __..._. .___..___ . ._........ . _____... __......._.. EUGS - Trim 1 .54 L97 ..._.._ 4.38 

### ....._.. 3.07 0.85 1.19...... 0.92

........ . . ._...__ . _.._.... __.._.. __ ..._... Attach supportmg data ALLOR'ED EMISSIONS: SOURCEGRP HF HCL SO i CO VOC NOz PM t~ . t ~ (7 I _.... _.. ....... ...___...... ..._...__.__. . ._......._.. .__._.._. .... .__. ....._..._. .__...._._ . .. _._......_..__.__.. t

~ a' C :

__ . ..... _.. ..._.____.. _ . _..__.__ ......... ...__.._... .._.. ..__ _.__._._. _ ... _._.___ . ......... .......... ._ r;t (:3 SDI 0.59

._.. _.. . 0.10 _.._._. 0.45

. _......_.. 13.77

...__... . .. 9.67

._.... 3.88

__..__._.... 7.9 8

.....___.........._.. . EUG.i SD2 ._ ... . ... 0.95

......_ . ._.__ 0.90

... . ..._...___.. 0.45

............. .. 13.77

____...__.. ._....__ 9.67

..._ _ ........_ 3.88

_..._... . 7.9R

..___._.... ........_._. EUG i\'llsl _.. . _._._. 0.72 ._._ 0.08 _. ._.__... 0.18 l 1.43

......... 38.33 ._ __....____.._.__._-

3.51 5.85

.__._... ._.___. EUG 4 VDs2

.... 0.52

...... . 0.06

_ . 0.08

_....._.__ 5.09

__...... _ . .. 17.04

_..... __...._.__ L5G

_. .... 2.60

._....... .._.._.. EttCS-\\'St

... tA3 L60
_ ...... 8.96 t9.60

..__.. .... 4.78

...._ __...._.. 7.73

. ._. 6.71

.._._ ... .. ..__.. F.UG 5- \1'S2 ..___ . . 1.43

.__._.. _ . _ . ..... ... 1.60

.. ..._.. _ .._._.. 8.96

...._..... 19.60

.___._.._ . .. .. 

### 4.18

......._ _ _..._....__.. 7.73

. ...__.._._ 6.71

..._..... _..__.._. EUG 5- Trim 1 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on I hour Omits EXCESS EMISSIONS: 24-lir Totak SOURCE GRP HF HCI SO, CO VOC NOx PM HF IiCt SO i CO VOC NOx P6i EUG 1 None .._____._. ..._..__ ._....___._ ___ __ ... . .......... ...___..__ None ._..,...__.. EUG 2

. .. __._.. ._.__.__. ... .._.__..___ .._.___..._. . ._____. . ......._. .__.__... . . ..._......._. None .__._......__ . _...._.. .._.....__.__ _____ _._. . ....._..._ . ._._.__._ None _._..._.. DI EOC 3 S one

N None

.._._..- None _ -- .__...... None

....__... .... None

___. ........._.. . None

_._.._..__.._ None

_ .. _ ._._ _. _ _ None

_..._.... None

........__. None None

..._. None

..._ __. . None

_....._ .... None _ .. ............ F:I

~ C 3 Sn? None None

.. .... _.. None

_....__.. Nnnc

.. .__ None

......._ ......_..__.... None

.. .__.___. None None None

............ None

....___ None __. . None _..__.. None

. __.._._... None

. .._ ......... F:UGa\'Pst _. None

.. ___.__ ._. None

. ..._ ........ None

. . ..._.... ~ '.Vonr

. None

..._. _.._. ._ ...._.. None

.__._..._. None

_. .___.__ .._ None

_......._ None

.____... None

... None

.._ None

. .___. _.. None

_....._. None .._.__.. -.._. EUG 4\'DQ _. .. _,._...._..

None None None ~ Nune

. None ._.._ .. _._ .. _._ None

. ...._._ None

_ ...._......_. . .__. None

_. __....... None _. Nnne None

.... None ._ . _.._ None _ _ _.. None

...___.

~ EUG5-N%SI

. . . 1.86 2.32

. ...._._ 1.87

_ ..... . None

_ ........ . __ . None

..._ . ___..._.. . None None

.. _ .... None

..___._.. Nooc _. Nooc N one None

... . ._._ . \one _ ._.__..._ Nonc _.. ._ ._... EGG 5-1\S2

. None

......____ _.. None

.........__. None

...___ None

. .. None

. ._.._...__... ..........._.

None .._____ None

_-_ _ -- None

-.. _.... None

. _ _.. . ~ 'one

...... None ._. _. ...._.

None ._. . None

... __.... __. None

._.__._... EUGS-Trim None None None --- ---' None None None None ---' None None

~ one - None None Nonc - Nono NATURE AND CAUSE OF EXCESS EMISSION: (t) \Vet Scrubber #1 was shut down to recalibrate the PH probe. PROCESSES AND EQUIPMENT [NVOLVED: (1) \Vet Serubber t01 CORRECTIVE MEASURES TAKEN: (I) Recatiltrated the PH probe and restarted the scrubber.
ADDITIONAL INFORMATION * : The Wet Serubber was ntaintained and operated aecording to the manufacture's instructions. The repairs and maintenance were done as quickh - as posslble, utilFring overthne if needed. I certily, based on informatfun and be0ef rormed after reasonable mquiry, the statements and informatfon m this document are true, accurate and complete

StGNATURE OF REPORTING PERSON

Date Received: Received By: IDernonstration of Cause Submitted: F ---- ] No 0 AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: 'r If you wish to notify the DEQ about a technologieal limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8. 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALffY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CIiY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The information requested below should be submitted to the address above within 10 working days afier the immediate notice is given. If you are using this form to correct a prexdous eport, provdde only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

912512009 Dal-Itaiia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick WilOams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EDiiSSION: Date Start Time: Stop TSme: Duration: 9/18l2009 15:15 15:45 0:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 Hours:MinutesofWetScrubberpowntinm APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 2004-198-TV (M-1): Specira: Condflion 1, EUG 5 ESTIMATED EM111SS10NS: BASIS OF ESTIMATF. ComplianceTesting X

. ._.__....._ _.__.. ...___. _..__. _.__.. SOURCE GRP tiF tiCL SO i CO VOC NOx PM EUG 1

_ . .... . ......... . __....__.. . . __._.... . ......._._. ..._ __.. .._..._.. .._._...... . ..._...... ICI;G 2

_ ._..... ._ ____._...... _ _.._ .__._._ .... _... .... ..._ .

._ .___.. ......_.. Cont Emissions Monitorine .____.._ .. .........._ _....._.... EUG i SDI

. .. 0.55

_.._._.... ...._.._... 0.00

....______. 0.24

. _...___.... . 8.92

__...___. . _.._.. 3.08

.._._ .. .. ..._ 2.80

.. .____. _ 5.57

..._.__.. _. EnginecringC alculotion X

__.__.. ._...___. _._.._ . 1•;UG 3SD2

. . _ 032 ...... _ . ...._. 0.00

.. __.. _ 0.00

. _ ... 7.21

......... ..__ ... 1.11

. .. ._...__ 2.35

_._. .. 3.08

..... _ . .. Operating Logs X

_ _ ... _- _ ... _..._.. .. __.. . _ ..

~ F:CG4VDsl 0.02 _..._ 0.00 0.00

... _ . _ .... 436 .._...._. 0.5 0.85

. ..... t.89 ~ Other(explain) .____ ....._._ __...... ...... ... ... . ECG41

~ Ds2

. - ~~~ - 0.02

. _ 0.00

~~ -.. .

.__.._ 0.00

... . . 3.58 0.45

_ 0.70 15.5

.. _ . . __._.... ........_ ..____ __. _... _. _ _.. EUG 5- W51 _... . . .. 3.29. ..

...... ;.92 10.83

... . 7.13

.... .. .... 2.11

... 2.80

.... ._ 3.81 _...._...... ...._._._.. ..__.....___ _..__._. ......_ -_ _EUGS-\VS2 0.00 _._.

_..__ O.Oi

~~~ - ~~~ - _._.._. ~~~~~~ 0.02

.. . ...._. 13.90
. ~

_.... ...... . ~ 2.32

.. _....___ 4.48

..._.. 4.08

.. .. ......_._.. ..__...

_........... .._____ _._.. EUG5-Trim i_54
. ~ ~ 1.97 4.38 3.07 0.85 1.19
. ~~ 0.92 ___._. _......._ _..._ _. ... ..... . .. .... .... Attach supporting data ALLOA'ED EMISSIONS: 

### SOURCEGRP HF HCL SO i CO VOC NOx PM EUG 1 ._....... _ ........_ . _...__ .. __..... ._._..___ _ ..___.___ .. ._... _.... . .._..._._... .._ ........... ... .._..__..........__.._.. F.PC35D1 ~ 059 0.10 - 0-45

.. .. 13.77

.......... 9.67

....__.._.. 3.88

.. _...._ 7.98

_... . ._._...._..

~~ - LLG3 tiD2 ..__..._. ...... 0.95 0.90 ~ ~~~-. .._...._.. 0.45

......_. ...__...._ 13.77
.. ~ - 9.67

.......__._ _._.__.__. 3.88 ......_.. 7.98

_..___..._.__._._.... EUG 4

~~ I)st _. ._ . 0.72

. .... _. __.. 0.08

_. . ....__..__. 0.18

..... ..._... 11.43

_....._ .__ 38.33

. ...__._ 3.51

.. ............_ 5.85

_..._._ __._._. E[tC, aV ~D~?
.. 0.52

.--- _..... 0.06

_. . ......._.. D.OS

.._.._. 5.09

_._ . .__ 17.OA 1.56 2.G0 l

~ a' (; S-vN'ti l 1.43

.____.... 1.60

......... 8.96

_....____. . 19.60 4.78

__..._.. _.-._....__ 7.73

.. ........_.. 6.71

_____.._._..__.. L'L'C5-

~~ 52 .__. .. L43 1.60 8.96 . _._ 19.G0

.. _. _ . 4.78

__.. _. _ . .. ...._..... 7.73

. _.._._ __.. . 6.71

...__._...._ . .._...... . ECG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on I hour limits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO z CO VOC NOx PAi HF tiCl SO i CO VOC I NOx PM EUGI _....._. ... ...____ ._.__.__.. ... ........... .__..__. .._.._..... _ .._..__ ___... . _......... ._. .. __.___ .. _ None _. ....__. _ ___ ._.___. .____..._ _...._._ __. ...._...._.... ....___._ None .._.... _. EUG 2 _ ....__ . . ....__ .. .. . ..... ... ...__ ..___. ._...... ... None _.._._ . ... ._. _-._.__. ._.. ....._ _. ....... . __ _._.. None

.. ... ... ___.... F.UG 3 SD1

... ...__ None ....___ None _. ... _ ..._..._._ None

..........._ None

._._..... .__

None _.......__. None

.. ._ ..__..... None

.._......_...... . __. None

_._ None

.___.._ None

_...__ None _... ._. None __......_ . Nono ._ _....._._. None _--- __._.. EI'G 3 SD2 None

_. . _...___ Nonc

_. _.. None

._....__..... None

.__.......... _.._ None

...__ _ ... .........._. None

.__.__......_ None None .__.._._. _ . None

.......___ None

............_. None Nono

._..__......... Nono

_ ......_..._. None ._. __......_._ EI
~ G a VUs( __. .._ None

.... ._ _...... Nono

.._.... _._.. None

._. ____._ None

..__.._.... .__ None

....... .........._... None

...___.__. -on-e .

None .._....__...._ _.. None

..___. . None ........_._._. None

. _....__. None _......_ None ....__.. . None

_...__.... None ..._._._... EUC:a \'Ds2

. None

.. _. ._._......._._ Nonc

...... __..__ .. None

_....__.__ None

_._.._.. .._......_. None

_....__ ........ None

.. .......__..__. None

___.._..... None None _.__...._. None ._ ___.__. None .._.... - - None - _...._ None

_._.._.__. None

.__....... EUG SI _._.__.. . 1.86

..... , .__....._ 2.32 1.87

.... - .............._.... ._ None __.____ ..._._...._._...._.......____

None None

........____... ......_....__._ ~

None None ...._._... None

.....__..__.. None

......_._. None None ..._......__. None

._........_ None __....__.... EUG S-\

~~ S? .._.. None

. .__.... None

_. _......._._ None

_____..._... None

..__._.. ........_...__. None

....._.._....._ None

...__.__._..... None

____._._.. _...... None

__._._ None .....__.__... None

.. __._...__ None None

...__._. None

........ None

............... EUG 5-Trim None None I None None None None None None None None ;r`one I None None None NATURE AND CAUSE OF EXCESS EH1ISSION: (1) NYet Scrubber 91 was shut down due to the Ptl Readings being low and the amperage was too high on recirculation pump. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Serubber#I CORRECTIVE MEASURES TAKEN: (1) Found a loose wire connection on PH probe and swhched pump to #2
ADDITIONAL INFORMATION * : The Wet Serubber was mamtamed and operated accordhtg to the manufacture's instructiuns. The repairs and maintenance were done as quickly as possfl»le, utllirLtg overtinte if needed. I certify, based on information and belief formed after reasonable inqu - ay, the statements and inforniatfon in this document are true, accurate and comptete

SIGNATURE OF REPORTING PERSON

Date Receivod: Rcceived Bv: Demonsnation of Cause Submitted:

~ No AGENCY USE ONLY TrackingNumber; Tcam ID: DateSubmitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infotmation. DEQ-Form #100-920 Revised February 8, 2008

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfrY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM : OTE: The infonnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the corrected infomation below, sign the eertification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

9125J2009 Dal-I lalia NAhtE OF INDIVIDUAL REPORTING: TITLE: PtIONE: Rkk W'iliiams Plant Manager (918) 6834043 FACILITY: COUNTY: PERbI1T NUMBER: DaNtalia Muskogee 2004-198-TV (M-1) DATE AND TIhIE OF BXCESS EMISSION: Date Start Tinte: Stop Time: Daration: 9/24/2009 14:00 14:30 0:30 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:30 flours:MinutesofWetScrubberpowntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (b1-1): Speeifk Conditiun 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X _._._._ .__._.. SOURCE GRP IiF HCL SO, CO VOC NOx PM EUG t

. _ .._..._ .______. ..._.._. ..._....._._... ..._.____ _..__-__. ._._......_ ._...._._ .._. 1'['C 2

. ._.__ ._ ._._.__ ._.._........_ .......__. .....___ .. -_.._...... ._...._....._ __._. Cont Emission ~ \h nitoring ._.__. _...__.._ ......... ...... .. l:l

~ G3SD1 0.43 0.00

_ ._..._019 699 ... _. 241._.._.._

_._.. 2.20 ..._.'

~ _36 Engineerit t..alculation X

_ . _. ba

~~ G3SD2 _ ,_.. 0.28 0.00.......
.. . 0.00

...._ . 

### . ~ . 6.2t

.._ , ,.,..... 0.95 _._.._... 202

. . . ..... 2.65

... _.._

~ .Opc-ating(.ogs X

.. El - G 4\ D

~ t

. _ 0.03

...... 0.00

... . .......... 0.00

_.._.._...._.... 7.04

_.__._... .......... 0.89

..._. 1 .38

..._._ 3.05

.._......_ . Otl6cr(explain}

........ _.__. ...__... __.._. _... .___... EUG4

~~ Ds2

. 0.01

.__. ._._,._ 0.00

. 0.00

__._ _ . .. ... 3A5

.......... ..._ . 0.43

.__. . 0.67

_... ..._ 1.49

_..._ .. .... ....... ._._._ .._._. ... .._ .... .._._... EUGS - WSi
. ~ - .. .. 3.45

.... . 4.10 ~ ._.

... 1t95

. ._ ... 7.47

._._... .._.._.... 2.22

_ 2.94

. ,.. .._. 4.00

._....... . ..____. ..____. ...__.._. .._...... __..._.. EUGS-\

~ S2 - .. 0.00

..._ ._._....... 0.01 _...._. 0.02 .._. . . 13.89

..... 2.32
_ _ ._..._..._ 4A7

..._..._ 4.08 ._......_. . ........... ___.... ...__.. _..._._ . _.. EUG5-Trfm 1 1.54 1.97 4i8 3.07 0.85 1.19 0.92 Attach supporting data ALLOWED E611SSIONS: SOURCE GRP IIF HCL SO i CO VOC NOx PM EUG t

. .__..__ .. . .... .. .___.._._. __._...._ .. . ._.._.__ . __. ...__ ....__......._ . _...__ ...___ __ . _..... _...... EUG 2 ._.__ . ..__.... ....._ .___.._ ..._. . __..._. __.. ._.._ .___.___ . .-._._ ._........_.._....... EUG35D1

.. 0.59

_. . _.._.. 0.10

.. 0.45

_ . ._. l7.77 _._ 9.67_
_ ._._. .. _.. 3.88

.. . 7.98

.._ .. .._._ EUG 3 SD2 _..._. 0.95

...___ ....____ 0.90

.. ..... _...._ ~ 0.45

. .._....._ _ _.. 13.77

.. _ _. 9 67 ~

..._,_ _ ...._._._.. 3.88

.____... 7.98

._...___.. EI)G4\'DSt

. .., . .......... 0.72 ..__ 0.08 .._ ._._._ 0.t8

._..._._.. I1.43

.._....._. _.._.. 38.33

...._ _...._.... 3.5t

..._..._ 5.85

.__._._..__.._.._.. E[ I Ga

~~ os2

.. 0.52

.. . .. 0.06

. _... _ 0.08

.__ .._ .. 5.09

.._._... __. fZ04

. ._._...._.._ 1.56

_..__. AGO EUGS - WSl ...._.._. _ ..._ L43 ....._._ 1.60

. . . ......._..._ 8.s6 19.60

........... ..... 4.78

..__ ......_.__..._ 7.73

.._ 6.71

....._.__..._...._. EUGS-t

~ 52 __..... _. 1.43

._._. .._ 1.60

_. . 8.96

_... .. .._. ... 19.60

_..._....._ ...... 4.78

....... .__.___.. 7.73

. ___._._... 6.71

......_...._. ..._.__.... EUG 5- Trim 1 3.57 1 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EM ISSIONS: (based on t hour 8mhs) EXCESS EMISSIONS: 24-tlr Totals SOURCE GRP NF HCI SO z CO VOC NOx PM HF HCI SO z CO VOC NOx PM EI'G 1 .._. _ _..._.. .... .... . ... .... ._..__.._.... .__....... ......._... ..._.___. . _...__. . __ None ._........ . __._..._ ._.._... . __...__..__. .._._ _. .__.._. None _.._..__.._... EUG'- __... _ ...._. ..._ _.. . .. __..._ .____.._.. .. .. _.._ _.__.__._... . ..____._. None ..__.... . ....._..... . ..__.._. _... . . .__...._ . .. _..._....__ None ._.._._. ta'G 3 SDi

_ Nono _._...._ None

_. .. _ ..._.... None

._.__.._._.._ None

___.._...._ ... None

. .......__._... None

._......_...... . None

.._.___.. None

._......... None

_ _...____... None

....._.. None

.. ._ None __......_ . None

.. _ ~ __.._.._ None

.._..__...... Ft"G 3 SD2 _- . None ..._.... _.._.. None

. ._.___._.... None

. None ..____._.. ._..._.. None

_____....... None

. _.._......._. None

. _........ _ None

._..._ None None None _. .......... None ......_ .. ... None

..._...__.. None

.... ___....._.

. t!l

~ G 4 VDsi

. None

._...__ .... None

.... ....__.__._... None

...._ . None

.___..__..... ..__. None

._._. ......___.__. None

. .. _.. None

.___ ......... ... None

...._. None ._..._..__._ None

.__ None

. .. _ None ..____. _ None

. _._.___.._ None

. __....... 1[l

~ G

~ V'Ds2

... .. None

._.., , ......._.. _ None

._ . .__._._._. None

...... _..__ . . None

. ___..__ . . _. None

...__.. . _.... ...__.._ None

___..._._ . None

_ ...._. _. None

..._ .... None

_..__.._._.. None

.. .. ___.. Nono _._. . . . None _..___... . None _._ ....._._ None

. . _ _.... ta'C 5- WSI

_ 2.02

._...__ ......_ .. 2.50

._.......,_. 2.34

...._..._ . None

._.___.. . .._ None

_...... ...._....... Nono

.__ ........... . None

..__....__. .._ None

_.._.... None

...........__ None

...__._._ None .__ _.. None .___.._ None __.__..._. None _..._... __.... LGG 5-1A

~ S2 ._...._ _.._.__. None

. . ..._.... None

__....._._. None

_....__. None

. __.._._.. None

____....__. None

..... . None

..._.__._. ..._.....

None None

._......... Nonc None

.__._._ None

......___.._ None

_.._._.._.._ None ..............._ EUG 5-Trim None None None None None Nono Nono None None None None Nono None None NATURE AND CAUSE OF EXCESS EMISSION: (1) The scrubber was shut down to check the nordes and the w've eonnections on the ph probe. PROCESSES AND EQUIPMENT INVOLVED: (t) R'et Scrubber kl CORRECTIVE MEASURBS TAKEN: (t) The wire connections were so0dered to prevent faaure on the ph probe. The nor

~ ks were cleaned to prevent overheathtg.
ADDITIONAL INFORMATION*: The Wet Scrubber was mafntamed and operated according to the manufacture's instructions. The repairs and ntamtenance were dune as qukkiy as possible, utifving overtime if needed. 1 certify, based on information and belkf formed aRer reasonable inquiry, the statentents and'mforntation in this document are true, aceurate and eomplete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: F ----- l'Vo 0 AGENCY USE ONLY Tracking Numbcr: Team ID: Date Submitted: * If you «ish to notify the DEQ about a technological limitation, do so here and attach supportinG information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALIrY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CtTY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The infonnation requested below should be submitted to the address above within 10 wm'king days after the immediate notice is gieen. If you are using this fomt to correct a previous eport, proxide only the corrected infonnation below, sign the certification- and attach a copy of tlte previous report.
REPORT DATE: COMPANY NAME:

10/9/2009 DaNtalia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick 1V00ams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-ttalia Muskogee 2004-198-TV (R1-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 10/72009 0:00 0:00 0:00 Hours:Min Phase 1

10:00 17:30 1:30 Hours:Min Phase 2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 1:30 Iiours:ilTinutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specific Condhion 1, EUG 5 ESTIMATED EMISSIONS: RASIS OF ESTIMATE ComplianceTesting X

. .._.._.. ._._... .... _.._ SOURCE GRP tIF HCL SO r CO VOC NOx PM11 .._ EUG t

..... ....._.. ...._ .___._.. . .. _ .__..... ___._....__ . _.._.__. _.__ ....._..... _._.... ._.. _.... ......__ ...... .... . . .. ......... ... Cont Fanissions Monitoring

. . . . _.._. ._.... ...__... ....._.__ _,...._....._ EUG 3 SD 1 0.46

.__._ ._.___.. 0.00 _....._ 0.20 ._ .. . 7.39

.__... . ..._.. 2.55

.__ . .__..... ?.32 4.61 _..._ _ Fng_ineering Calculation X .._...__. . _ . . _. .__. El1G3SD2 _..__ .... ............ 0.40 __.._.... 0.00

. ......_..__ 0.00

._...._.___. 8.80

_..__.. _....-___. 1.35

..........__._ 2.57

....._._..._ 3.76

._..._ _....-_ ~ OperatingLogs X ..._._.... .__..__.. . ...._._ .. EUG4 VDst

_ .... 0.03

..... .....

0.00

. . ......... 0.00_

. . . . . 738

_ . ._. . .._..__ 0.93

_..._ ._ ....._.. 1.45

. .. ...._ 3.20

__._.... _ Othcr(cxplain)

_._..._.. . _.._... . .._..._ . . __.. _.. EUG4 VDs2

.. . .._ O.DI

.. ..__. 0.00

. _ 0.00

. . . ~ 338 0.43 ..._....._. _ . _ ___.. 0.66

. _ .. L47

. .. ..... __ ..... .. ......._.__ . .._...._ ._..._ ...... ....... EUG5-R'St

_ 0.02 .__...__. 0.32

_ . .___.. 037

. .. .. _ (4.71

.___.._.. ..__...._.._.. 0.95

. ..._.... 5.00 ...._. . .__._ .....__...__.

2.98 _...._.._..... ..._..___...... ..---.._._.. ..____...... .......__... EUG 5-

~ YS2

. . _ . . ~~ 9.07

. 10.80 .._._ 29.87

.. . _ . _... 19.65

. . _.. 5.83

..._._ _ . . ._ _... .. 7.73

. .. . .__ . . . _ t0.52

_ _.. . . . __ ..._..__.. __.._,_ . .. _ _._.._ ___... ..... ....... ._ _._.. EUGS - Trim IA6 1.86 4.14 2.90 0.80 t.13 0.87 _....._ . ___._.__. .____ ......... .. __.... . Attach supporting data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO, CO VOC NOx PM EUG I ....__ . . _ _.._.. _. _._._ .._ ......_..___ . _.... ._..___ ........... ........ ..__ __...._.___.. _ . _._....__._. .. .. _. _.__........_.__. EUG2

_ ...._. . .. .__..... _.... . _. ...._...._..._. ...... __..._... ..._........_.. ._.......___ . __.._... EUG 3 SD I

_ . _ 0.59 _. _ _.

.. 0.10

... . .._.._._ OA5 13.77

. 9 67 3.88
_ . -- 7.98 - - - ._ ~ -.._ EUG 3 SD2 ....._.... .._ 0.95

. ......... 0.90

...._.._........ 0.45

.____....... 13.77

.........._ ... 9.67

__.... _..... ........__ 3.88 ~

. ...___.___ . 7.98

.... _.... ._.-_._........ EUG4 VOsI _.___..._ 0.72

..__.... _..__._.._.. 0.08

_.....__...._.. 0.18 IIA3 ..___.. ... __... 38.33

___. ......__......_. 3.5t

.. ..... _...._._ 5.85

..__.._..__.._..._..._... EUG4VDv .._. _ _. _ 0.52

.... ....._._ 0.06

.__..__._ . 0.08

....._. 5.09

._._.._.._ __...__... 17.04

._.____...... 1.56

.._.._..._ 2.60

....____._._ ..._._.__ EUG5-

~~ 'SI

... __ 1.43 _.__ L60 ._. . - .._..__ 8.96

.. ...__......._ 19.60

....._.__. .. 4.78

_.__. . ... __ ....._. 7.73

_...._.__. 6.71

......._._......._..._._.._. EUG 5- N;52 ..__ _.. _.. 2.85

_....__ ___..._...._ 3.20

. ..___...._ 17.92

_......._ 39.20 9.56

___.__..... ..__._._......_.._._._ 15.45

.............. 13.42

___..._._._..__. EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on I hour timits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO t CO VOC NOx PM HF HCI SO z CO VOC NOx Pi1t EUG I _....... _..._.._ . .......... .. . _......._ .. ...__.._... ..... .._._ .._.__..._. ......_.._._.. None __..-_ .. ...._ ..._.._. _._...___. ._._.__. ._ .... __.. . -_...._ None _....._ EUG 2 ....._._ ._.._.._ .___... _. ...._. ._._..... ..__._ ....._.....__ ....._._...__. _ None ....__.... .._.....__..... .__........ ..._._...._. ......._._........___ Nono

.. EUG 3 SDI ,_.._..._. _ None _._...__ None __...___. None

........._..... None

._.__... None None .....__ . None

.......... ......__..

None None

_....... None

..........._ None None ..._._.._ None

_....__... None

_._.._..._ EI'G 3 SD2 ..._. _ . None

_...__. ._....... None

.._ ._._...____.. None

. .._..._. None

.__....._ .._...._...__ None

......._.__. None

.. __.....___ .. None

......... ..._. ._._..._...__

None None ___... . None

...... _ None

...... None ..._.__ None

._..__.._._ None

__......_ El'G4YDst

.... .... None

......... __.... None

.._ . ......__ None

. _._.._. None

__...._ ._ None

_._.. _ ____.._.. None

. - ._._ None

...._..... None

__...._ None

___.. None ._ None

_... None .._ _... None

..._.... None .._....._.... EUG 4 YUs2

.... None

........... ..._.._... None

.___..... None

.._.__... None None

...._._... __....._.....___._._. None __.._.__..._.. None

.._.__.. _....._.....__

None None

_.__. None

......__ None None ..___., None

....,..... IVone .__.....__. EUG 5-11S1

_ _ . __ _ . None

.._._. _. _ _. None

.._. ...._.. __.. None

. _. None ___._ .... None

_.._ _ . _.._____. None

. . ...__.... None

_ .......... None

._..._. None

...... .._.. None

.._ . None _._ ...... None

.. ._ None

...... _....,. None E11G5-R:S2 .._ _ . 6.22

._._.. ........_. 7.60

.......__.... 11.94

.. .___. None

._...._. ......... None

.......____. None

. ._...._.._ None

..._____... _.. None

...._._. None

......_._ None

_._.._. None None None ......._. .._..._._..., None

_..___... EI:(:5-'frim I None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The \Vet Scrubber was shut down to ckan the nonles and impenger fihers. PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber k2 CORRECTI VE M E 1SU RES TAKEN: (2) The sludge was eleaned out of the inpenger pft, cleaned Intpenger fdters and nonks, checked pumps, and restarted the scrubber.
ADDITI ONAL INFORMATION*: The 1Yet Scrubber was mamtained and operated accord'mg to the manufacture's instructions. The repairs and maintenance were done as quickly as possibte, utilbing overtime if needed. 1 certify, based on mformation and be0ef formed after reasonable inquiry, the statements and kdormatton in this document are truc, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Reccived By: Damonstration of Cause Submitted:

= No AGENCY USE ONLY TrackingNumber: Team ID: DateSul6mitted: '" If you xvdsh to notify the DEQ about a technological limitation, do so here and attach supponine infonnation. DEQ-Form #100-920 Re

~ ised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DNISION PO BOX 1677 OKLAHOMA C(TY, OK 73101-1677 

# EXCESS EMISSION FORM , OTE: The information requested below should be submitted to the address above within 10 working days afier the immediate notice is given. If you are using this form to cotrect a previous 

### rep ort, provide onty the corrected infomtation below, sign the certification, and attach a copy of 6te previous report.
REPORT DATE: COMPANY NAME:

10192009 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick W'd0ams Phant hianager (918) 683-4043 FACtLiTY: COUNTY: PERMIT NUMBER: DaNtalia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 10182009 8:20 9:10 0:50 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (ItOURS:MINUTES): 

### 0:50 Hours:MinutesofWetScrubberpow•ntinte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 2004-198-11 7 (M-1): Specirrc Condition l, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTtMATE ComplianceTesting X

. ___._.._ .__...._. ............_. ..___.___...._ SOURCE GRP HF IfCL SO i CO VOC NOx PM EUG 1 .__..... __._...__ .........._... .. ...... ......._.__.. . .._.._.___... ..__....._._......_ _.._.... ...._. ..__._ ....... . ...... .......__._.

. .__....__. .. . _. . _... . ._ EUG 2 . _ .__._.... .... .. .__.._.... . _ Cont Emissions Monitoring

_ . . __..__. . _._..__._ . . ..... _ _. EUG35Dt .._.__. ... 0.48

__._. . .. ____....... 0.00 - -

._....___ -- 0.21

_.._.._.. 7.76 -._.._.

.._.__... .. _._..._. 2.68

__.. ... _.....__.._ 2.44

. ....._.___._.__ 4.84

....._.._.. . FsgineeringCalculation X

___... .. __...._.._. ..___.. _....._.. EUG 3 SD2 ..___.._ .. 0.40

..._._ . ........_...... 0.00

_........__ 0.00

_..._.._._. 8.85

_.._... _,... 1.36

_._... .. ......._._ .. 2.88

. .........._ . 3.78

..._ .._..___.. _._ Operating Logs X

__.._..

- . .._..._._... .. ___.._._ EUG4VDst 0.03

. ......____ 0.00

.. . . .._._... 0.00

_ . ... 6.19

__._ ._ 0.78

..__ _ ._.___ 1.21

. . . _ ..._ . 2.68

_ .. .. Other(explain) ___.... ._._...._ _....__._._ . _ __..__... EUG4 VDs2 0.01 ...._....... 0.00 _. ..... 0.00

.... . 3.44

.__..._.. __. 0.43 0.67

. . IA9

. . .... __........ .__.__. .._.._. ._._.......__ . ..___ ...__. EUG 5- WSl 5.6 3 6.70

~~ - ._..__...._. 18.St

. ._.... . 12.20

...._. .-__..._.._...

- 3.62

......__ 4.80

. _. ._..._._ . 6.53

. . . __..._.._.._. ____._...... ........._. _____..... . ..____.. EUG 5- WS2 11 0.00

. 0.0(

. _.._._. 4.6t

.. . . _ 0.02

_ ....... 14.30

_...._.__ 2.39

_. .. .. _ . _ _.. . .._. _....__._ . __.._...._.. ..._._..... .__.__. . _.__.._... EUGS-Trim 1,54 -_.._.-.. 1.96 4.37 1 3.07 F

~ . ....._.___ __._._ .....___..__ .._._..... .......... ALLOWED EMISSIONS: Attach supportmg data SOURCE GRP HF HCL SO i CO VOC NOx PM F(tG 1

__ ......_.... __.._._.._. .._.. __....._. __...___._ ....__.._..... __......_ . ................. .._....._._. __.....__.._.__._.._._. EUG2 .._._.. ........._._ .___....__... . ___....__ ........._.. ...._._._ _.._._._..... _...... _...___ ..___ .. ..._..._.......__......._. EUG 3 SD 1

......... ... 0 59

.. ____....... 0.10

.....___ 0.45

.__.._. 13 77 9 67 ..___....... _ 3.88

. .______ _....._ 7.98

.._._._...___._,.... EUG3 SD2 __.._.._. . 0 95

..__, _ ___ . ...._... , 0 90

.. _..._......._. 0.45

_..._.._ 13 77

. . ._ . .,. 9 67

, _ . .._. ._ 3 88

_ .. _._._._ .. ._.. 7.98

_ _..__.._._..___.- F.l!G 4 VDsI .._. . 0.72 _._... 0.08

... 0.18

...... . 11.43 _._____ ... ... ........_. 38.33

... .....___.. 3.51

. ._ ...._._... .... 5.85

......-_._....___..__. EGG a VDS2 _._ ....... ........__ 0.52 _..__...... 0.06

. _.__...__ 0.08 5.09 ...._.. .__......... 17.04

. ._......._.._. L56

._....._.._... 2.60

._............_.__......__. EUGS-R'Sl ____.... 1.43 _.......... 1.60 .._...._..._. __..._...___

8.96 _...--,_-- ~ _ . t9.60

._..._..__. ._._...._. 4.78

.... 7.73

_...._._...._... 6.7t EUG 5- WS2 .___._.._.. IA3

_..._....__... 1.60

_.. _.___......-- 8.96

- .__..... ... t9.60

_.__...._ .. .............._. 4.78

. .._.._...__.. 7.73

..._..... - ..__ .......... ......__

-

6.7t ........_..._........___.._. EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on I hour ronifs EXCESS EMISSIONS: 24-tir Totais SOURCE GRP HF HCI I SO, CO VOC NOx PM HF HCI SO i CO VOC NOx PM

. ._....... __._....._.. _ . ...........__.. EllG 1

. . .. ...__.____ .__....__.. ... .. _ __ ..__ ... __..._-. _ .. . _...._.._.... . _ None

... ......... _ ............ . .. ..._.._._._ __. _... .... . ... . ... ._.._...__. None

.. . ..._.__.. F.UG 2

...... . . ..._. __ ......._.. . ...__.__.. .. ..._ ..._...._.. . ........ ..........__. . . _ .._.._..... . .._ . ........ . . ._...._.._._ _......_.._.. _ None

................ .. _ .___....... .. .__..... ._.. .._. _._.__... . _...___..__ None

_ ___ _...._..- EUG 3 SDI

.. ._. _._._....._.. None

....__.. __..___...... None

-._. . _.___ None

...._....._.__ ._ . None

.._._.._... .._.. None

..__ __..__._... None

.._.___ ... None

.........._.... None

....._._. None

.....__.._. None ____........_ None

. None _._. . . None __.... _ .._. None

_ .._. ......_. EUG 3 SD2 _._.._........ _ ._ None

_.._..._. _......___ None

.... ...._.._ _._.... None

_..___ . ... None

_....._. _.... None

__._. ....__..__. Nonc

_._..... .. None

._.._ .......... ......___.._.

None None ..__....._.. None

. ...._._.... None ._. ._. None _..._.__. ... Nono

.... _ ____ None ___. _......... EUG 4 VDst

. __.___... None _._. None _. ...___.____ None

_ ._..__._.. .......____..

None _.___. None

.._... ..,.._......_. None

.....__. _ _ ... ... None

... .......__ ..._......_._

None

. None ......_......._ None

. __.._... None

__ . ._ None __.._. . None

_._...__..__ None EUC 4 VDs2

.. ._._..._ .. . None

_......_ . .__..__.._ None

_ .............. None

_--- --- _.__. .. None _...._..... .__..._ None

. _.. . ....._._._ None

.__.___ None

_._.._..__... ..... None

..._...... .. None ...._.....__. None

. .._. ........ None ..._ ... .... None _._..._._ _ None

._..._......_ None

. _._...__.... EUGS-1VS1 .___...._._ 4.20 5.10 9.58 _.. None ._......_.........._. ~ 'one

. .. None

.. None

.....___.... ...._.. None

_.__... None _._..._..__.. None

. .._._ . None

.... . ......._..._...

None

_ None

.... ___._.. None

._.._.._ EUG 5- WS2

. ._.._...._. . .. None

._._.._.. . ._..___._ None

... __.__......_ None

....__..__._ ._ _ None

.____ . ....__. \one

__.. ._....,....___ \onc

.._.._.. __.. . . None

...__.__.._ ..._ None

.__..... None

._....__._.... None

...__ .......... None None

. ... .........._. None

.. _. None

_ _.._.._.._... EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) The lVet Scrubber was shut down to check fdters, ckan sprap nonles, and Bush lines. PROCESSES AND EQUIPMENT INVOLVED: (1) NYet Scrubber #I CORRECTIVE MEASURES TAKEN: (1) The 1"itters and pump were checked, the spray noiiks were ckaned, and the scrubber was restarted.
ADDITIONAL 1NFORMATION * : The 1Vet Scrubber was maintained and operated accord'm8 to the manufacture's instructiuns. Tbe repairs and maintenance were done as quickly as possOtle, utObing overtbne if needed. i certify, based on information and belief formed after reasonable mquiry, the statements and information in this document are true, accurate and contpiete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: O No AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted:

' a If you wish to notify the DEQ about a technological limitation, do so here and attaeh supporting infonnation. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALHY DNISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The infocmation requested below should be subntitted to the address above within 10 working days after the imtnediate notice is given. If you are using this form to correct a previous port, provide on)y the corrected infortnation below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANYNAME:

1023(1009 Dal-ItaBa NAhtE OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick Wil6ams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUIIIBER: Dal•Italia Muskogee 2004-198-TV (M-1) DATE AND TIi1E OF EXCESS EMISSION: Date StartTime: StopT'ime: Duration: 

### 10222009 0:00 0:00 0:00 Htwrs:Min Phase 1

10:00 12:01 2:01 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 2:01 Hours:MinutesofWetScrubberpowntime APPLICABLE LtMITATION(S) OR REQUIREP7ENT(S) EXCEEDED: Permit No.2004-198-TV (M-1): Specific Condition 1, EUC 5 ESTIbiATED EMISSIONS: BASiS OF ESTIMATE ColianceTesting X mp

.. ..... .... __,_._ _.._... -_._.__.. ...___.._.. SOURCE GRP HF I/CL SO, CO VOC NOx Ph1 EUGI ..._.__..._ .._. _ .._ ...... ................ . ...___... . ................ . - __.._.._... ____._._. ..._..._._.._. ..._....__ _..._..__._.-......_-.. EUG 2 ..___..__ ....__ _._.._ ............ _ ..___.._.__.. ._ .__.___.. ....___.__ ..__..._._. ......_....__. ..__._..... _..._.._ ........... Cont Fmissions Monitoring

.. _... . ..._......._ ........_... _.__._....__. _.._.__.. F•,t'G3SDt -._ 036

..._._. .....__ 0.00

... .._. __..___. 0.16

_..__.._..._.. ...___._._

5.85

... _........._.. 2.02

....__ 1.84

._..__._..... . 3.65

. . FsgineeringCalculation X ..__...... -- -._...._.... ..._..__. I ~:l~(.~ 3 SD2 032 0.00 0.00 7.02 1.08 2.29 3.00 OPerazing

......... BI:C4VDS1 0.03
_

_ ... . _........._ 0.00 ___.... 0.00 - _ .-. _6.05

...._. ... .__.__. 0.76

.. . ......._ t.t8_

_ - . 2.62

... ..__._._. Othcr(explain)

._.._.... _..._._ .....___ _...__._. EG(: J VDs2

. ... O.Ot

_ .. . 0.00

... 0.00 ~ 3.48 .._ 0.44 ._...... . . ..._._ 0.68

. . _ -..._.. 1.51

. _. .. ._._. ._.__.. ........... ... ...... _-_. .___.... ._ ..._.... EUC5-N'Si ~ _. ... . 0.02

. . . . _.. OJt-.._...

.. ......._. - ""036 ~

. 14.12

. . 0.92

_ ..-..._ ... 4.80

_-.... 2.86

_ .__... ....___...

_.___. ...._..__. ......__.___ _. ............. . EUCS-\\S2

........ ._ . 12.00

. .. _.... 14.28

._ .. .. 39.51

-.. _._ .. . ~ 25.99 ~ 7.71 .._.. 10.23 . _ ... ._._ 13.91

.- _.... ._.___. ._._.._.._. ....._____. ............... __.___._. EUG5-Trim_ ....- ~ - 1.39 1.78 ~ 3.96

~ .77 0.77 1.08 0.83 .__..._. ..__ ......... .. ...___ . _..__._.. ..__.__. Attach supportmg data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EUG l ..__.._... .. -...___.. ......._ _ .._........__. ..._____._. ___.___. _..__._.__. ........_.___. . ...._...__.... -.-.._._.._.___..___... EUG 2 .._..._..... .__....... .._..__ ... ..--._.___._ .... _......_._ .._........_ .._.._. ._.... ..__.__.___ ....._......._.. .. . _...__....._...._. . EUG3SDt .... _.... .___.._. 0.59 ...__._ ... 0.t0

... . ....... ..._..... . O.JS t3.77 ._...._..__. __.. 9.67

.__.. _.. ._..._._. . 3.R8

. 7.98

.._._......_ ._.._.._.._. EUC3SD2

.......... ..... 0.95

.___._. ._..--. 0.90

._.. ..._.........__...._..._. OA5

. ...... 13.77

_ ..._._.. --._..... 9.67

_..... . ....-....._._.. 3.88

.__.._..._.. 7.98

..........._._.. ............ EUG4 VDs1 ._ _......_ _. 0.72

._...____. . . 0.08

.... . .._. .__ ..... 0.18

.. ..... ..... . 11A3

........... .._.. 38.33

...... ..._..._..._.. 3.51

..._.._... 5.85

............... _...._...... EUG4 VDs2 0.52

. 0.06

. .. ........_. 0.08 5.09 ..__... 17.Od .__. L56

... . . 2.60

. __.._._.. ........ EUCS - R`SI 143

_ 1.60 8.96 _. _ 19.60 d78 ._ 7.73 ...__ _ ... 6.71

.............. .......___ EUG 5-\VS2 4 28 4-80

. . ...__... 26.88

.._ . _ - .. . 58.8o

..._. . 14 34

...._._._ 23.18

. 20.13

.. __..._. .__._...... EUG 5- Trtm 3.57 3.88 9.68 6 75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on t hour rnnits) EXCESS E67ISSIONS: 24-Hr 7'otals SOURCE GRP HF tiCl SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG I _--._ .. ... ........ ................ .. . ......._- -....____...- .-.-_---.__._ .__..__...__..-. .._. ._.__ _.......-_.._ _ None -_____.. ..__ .__._... ._._.._....._. ......_....... -.. _.. .__._..... None

_ -.. ... EUG 2 .-.__..._.-.. . .. __..___ ...._......_. _. .. ._....._.__. ---..._.__... ...-._____._ ..._._. ___ . ...... ..._._. .. ......._... ..- None .- -_.._._... . _.. ....__.. _.__._.___ ....__.. .... _ ._._._..._. . --____-.... None _._...- _..._. EUC 3 SD1 ...._..___..... _- _ None

___._....... _.._.._ None

... .... ......_..... None

._._._.... _..___.,....

None None

.._._ _ ._.. _...___ None

.. . .. _._._.. . - None

-- -...._._..._. ...... None

.._._.. None __...._.___ None

.._............ None None

... ...._....__ ...... None

. _.....,... None

... . ._.._._.. EUG3SD2 None

. . _... None _. ... _._........._ fione

_._.._._... _ None

. _...._.._... _.._.._ None

.__.... _.. ._ .......... None

. ... ... ..___ _ None

. .. __...._... ._..... None

......__ . .. None

. ............_ None

.._.._._ None .._ _ _ None .- _..... . . None

.. -.. .__... None

__............. 

### EUC 4 VD sI

.. .. None ....__-_. . .. . _ .. None

_._._...._.. None

. ...... . . 

### None

. .... 

### None

......... None

. . - ..___.. None

_ __...._ _... ...... None

..._ _. None

.. ...._._.... None

. None

..... . _ None

- - None

. None EUG 4 VDs2

. _ ._... ._ Nono

. ... _ ....._. None

._. . .._... . . None

-._._.__.... None

_ . . .. . _ 

### N one

.. ._.._ . None

..... . ......... None

. __...__.. . .. _ None

.. .... .. Nonc

. __.._.... Nono

.....___ None _.. None None

........ None - ...._..._. EUG 5- WS1 __..._. .. None

--.-._.._...._ None

_..___...._. Nnne

....._._._ None

__._._.._ ......._... None

.._._ .___._. None

_...__....... None

__......_...... ..._ None

....__._ None _....___..._. None

... None

-.._.. None __.._. None

._...._ None __._._...._.. EUG 5- W'S2 7.72

. _ ._ - . 9.48

__._ .. . . _- .. 12.62

. .. ... None

_. _ . _....._ None

.._ ... . ........... None

......_.. None

......._... .. .. ._.. None

.... ... None

..._....._. None

. .__._ Nono

... ... ... None - _ . _. None

. _......._.. None EUG 5- Trim None None None - None None None None None None None None None I None None NATURE AND CAUSE OF EXCESS EMISSION: (2) \Vet Serubber # 2 a•as shut down to insta0 cam loeks on the level sensors. PROCESSES AND EQUIPMENT INVOLVED: (2) \Vet Scrubber #2 CORRECTI VE Si EASURES TAKEN:(2) Cleaned spray nonks, cleaned out pit to keep water ilowmg and prevent overheating, InstaOed cam loeks on the level sensor, and restarted the scrubberADDITIONAL INFORMATION * : The Wet Scrubber was mamtained and operated according to the manufacture's instructions. The repairs and mamtenance were done as quickly as possOtle, utOvmg overtinte if needed. 1 certify, based on information and belief formed after reasonable inqurcy, the statements and information m this document are true, accurate and eompkte

SIGNATURE OF REPORTING PERSON

Date Received: Received By: tkmonstration of Cause Submiued: O No 

### AGENCY USE ONLY TrackingNumber: Team tD: DateSubmitted: * If you wish to notify the DEQ about a technotogical limitation, do so here and attach supporting infomtation. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The information requested below should be subniftted to the address above within 10 working days after the immediate notice is given. lf you are using this fonn to cotrect a previous eport, provide only the corrected information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

t 1/6/2009 DaFltatia NAb1E OB INDIVIDUALREPORTING: TITLE: PHONE: Rick Williams Plant Manager (918) 6834043 FACILITY: COUNTl': PERMIT NUMBER: DaNtalia Muskogee 2004-198-TV (M-1) DATE AND TIMEOF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 10/30/2009 0:00 0:00 0:00 Hours:Min Phase 1

21:31 21:45 0:14 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:14 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUFREMENT(S) EXCEEDED: Pernih No. 2004-198-TV (M-1): SpeciBc Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIh1ATE ComplianceTesting X ..__......_ ...__._.._. _.__....... ..- ...-_._-_.._ . _ _.._....._ SOURCE GRP HF HCL SO, CO VOC NOx PM E17G I ..__. . .... _._..._.. ..._ ..... .... .... ...__.__ . ..._..___.. ..._......._ _.... ....._. . _.-.- _.__... . .... ...._.._..._ ___._..... FUC2 .

. . __ __..._.. _ .. . .. .. ......__ . _ ......_....... ......._.. .. _.._ . ._.._.._.. - _ ..._... . _ _......_..._. _.__......_. ... Cont Emissions Monitoring ...._...__ _........_. ._..__....._ .... ._ .-._._.. _ . - __.._.. EI'G 3 SU1 ._... 0.38

......___ ......_........ 0.00

_.... ._._..._ 0.16

.._ .______ 6.11

..........._..... ___....._... 2.11

_ ._. __.___ 1.92

.....-.____-._. _ 3.81

..._.._..__ ......__.__.... Enginecring Calculation X ._._.._.__. _.._...._. . . .__...._. .._..__.___.. EI:G 3 SD2 _.._...._ 0.27

._.__._ ....._.._...._ 0.00

_.._._ ........ 0.00

.. .. ._ _.__... - 6.03

..._....._.._. ._......_..._.

0.93 -. ....__ 1.97

. ._ ......____. .. 2.58

... _._..._. . . Operating Logs X

...__.. . ...._...__... . ....__.___ _ EUG4\'Usl

. .... 0.03

.. .. 0.00 0.00

. - .. ... 6.19 0.18
_ _ . _ ... 1.21 - ._.._..__ 2.68

_.......... Other(explain)

....__._. __..._...._ .___. . EDG 4 ~ Ds2 O.OI 0.00 0.00 3.54

............ . 0.45

........_ ..._....._ 0.69

. . - . .._..-... - 1.54

... ... ..._ .. . _ ._.___.._ .. . _._.._....... . ..._.._._.... . . _.... _. _ _... . .._.._.......

.. ~ . .............. ._..__. . . .... _14.48

_ .. ..._. 0.94_

_...___ 4.92

... . ...... 2.93

......_._... . ... _._._..... .__....... ....._...__ .._.__.__. ._._.-._.

.. EUGS-\\S2

. _. ... __. ... ._..._... _4.60 ._ . 3.03

. . 0.90 - ..__. 1.19

. . . _ 1.62

. - . F.UGS-Trim ...- 1.70
..... 2.17

~ 4.54 ...._--3.39 _..._.__. 0.94 632 ..... .....LOt .__._...._ __.._. _..._... ._........... . ____. Attach supporting da[a ALLOIVEDEMISSIONS: SOURCE GRP HF HCL SO s CO VOC NOz PM EUG l

. _...._.. ...____ _._. __.. _ -_-._..__. ____._ .._._.__. ...,. ..___. ......._.__._ . .._...._.... ..._..._..._._ _.___.._ EUG 2 _. ......_ . -._._..._..... _..._..___._ _.____._ _..__ ...... ...._........ . .......... ..... ...____._...._._. EUG3SDl ..-....._..._... . 0.59

..._.._. ._.__._._. 0.t0

_ ................ 0.45 ......___...._._..-.........._

t3.77 9.67 ._.._.... ..__...._..... 3.88 _____.._._. 7.98

_.__._._____._._. EUG3SD2 .....__..__ _.......__._-.

0.9_5 __....__._ 0.90

................ 0.45

............ 13.77

.._...__... .. 9.67 3.88 ..._._.__...- 7.98

.-_.__._..__..._.___. EUG4VDs1 _._.__.__. 0.72

........... . ..... 0.08

..... ._......._..... 0.18

-... ..__...-. 11.43

_..._ .._ _. 38.33

...__... . __ 3.51

_ _ . . ........_- 5.85

_. -._.... ._.....____._. EUG4 VDs2 _... .._._ 0.52

...._._ _ _.... 0.06

_.. ...___..__.. 0.08

. _.._- ......_. 5.09

...._._ _. t7.03

._.__. ....._.___.. L56

. ._..__.._..... . 2.60

_._..._._.___...__..__ EUG 5-NVS I L43

... 1.60 .__ _ 8.96

._. . . _ 19.60

.. _ _.._. 4.78

_... .. ..... 7.73

- .. . ._..__ 6.71

. __._.._... ._..-- EUGS-tiVS2 t43

--- ...._. 1.60

_.... 8.96

....... 19.60 ~ _.._._..... _. ~ 4.78

. . ....... 7.73

. . .. . 6.7t

............._.._._.. 9.68 6.75 3 67 2.00 1.80 EXCESS EMISSIONS: based on I hour funifs EXCESS EMISSIONS: 24-Hr Totak SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG I

. __.... ....... _... ... __.____. .....__ .._.__. . ._..- ._... . ..._.....__.. _ ............... None ...._... . .._. ..._ .... .._. .._._._... ._...._... _ _..._......... __..._._ None

. . ..._....... _.._._.. ..__...__ __... _... _..__.____ . ..-_......_.._ .._..._..... .__ ____....-..- - .-.._. . . ....__._...__._ __..... ......__.__ __...._..._ __...__. _,......__. . ~ None .__......_... EUG 3 SDI ........._. .._ None

.._.__... ._......_ None

__.. ...._.____ None

... ____..._.. None

..__._._.._.. None

.____.....-_....._ Nonc

.... _ ............. .. Nonc

. ......__.... .. \oue

_.._........ None

...___.__ None

.. .._._..__... None None ....._._._.._ None

___._._._.. None

................. EUG3SD2 None Vonr Non

-- ..... ....... .........__ . ............. _-.._..._ . _ -.- - ..-._..._... . ......_...-.. .._ .---..... .__.___ ....._.._ __... ... ...___..... ._......... . ..... 4 VDsl _._._.._.__. None

.__._..._._.__.__ Nonc

. _. None ...._.._._.__ None

...__._.. ......_._....._. None None None

. ....__ .................-_.......____,..._.._.._-......._.._...._ None None None

................. None None .......__....._... None None

..._..__......._._...... EUG4 VDs2 None .._..__. None _... .. _...__...._. None

__.._..__. None

.___.... ......._....... None

. .. ..__.. None

... _ ..._... _.._.._ None

-.. _ ._ ._.__. None

...._ . ... None .........._.. None

._...... None

.. None

. ._..._._.... None

. _......... None

._.._...._._. EUG 5-NVSI _._.._..._.. ... None

..._...._... ._._ _.... None

._._ .. ............._ None

. - - . _ .. _._.... .. None

.. ... _........ _....._ None

_ . _.. _ . .. ..__.__ None

.. . .._..__._._ Nono

. - _ _ ___- _ _ None

- __._ . - None .. _. ......__ None

. .. . _. None ..._..,... . . _ None

.. ........_. - None

. . -. ....... None

. . ................. EUGS-WS2 None

__._... . _ 0.06

- . . . __..._..__.. None

.. _ . .. _. _ . . None

_. .. .........__.._ None

- . ...._..... _None None None ......_.. None

_.....__ None

. . - ....-. None

_.. .. None -. .. -.._. _.. None

- . _ ._ None -. - ..__.._ ....__. _ EUG 5-Trim None None None None None -._._....._ None _ ...... ..

None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) Wet Scrubber # 2 w•as shut down due to a hlgh temp alarm. PROCESSES AND EQUIPMENT INVOLVED: (2) Wot Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) Took kiln off scrubber and let cool down, cleaned probe, put back on scrubber. Also eleaned and calirrated the high level probe.
ADDITIONAL INFORMATION*: The 1Vet Scrubber was mamtahted and operated according to the manufacture's instructions. The repairs and maintenance were done as quickly as possOtte, ut0'vLrg overtime if needed. 1 certify, based on mformation and beGef formed aRer reasonable mqufry, the statements and information bt this document are true, accurate and compkte

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonrnation of Cause Submitted: F
---- INe AGENCY USE ONLY TrackingNumbcr: Team ID: DateSubmincd: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALfrY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM i OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fomt to correct a previous rep ort, provide only the corrected infomtation below, sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANYNAME:

11/6/2009 Da41ta0a NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick \\"d7iams Plant Manager (918) 683-4043 FACILITY: COUNTY: PERhtIT NUMBER: DaFltallA Muskogee 2004-I98-TV (M-1) DATE AND TIME OF EXCESS EMISStON: Date Start Time: Stop Time: Duration: 1013112009 0:00 0:00 0:00 Hours:Min Phase 1



### 17:15 17:44 0:29 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:29 Hours:Minutes of Wet Scrubber pown6ime APPLICABLE LtMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permlt No.2004-t98-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: RASIS OF ESTIMATE ComplianceTesting X _.._._..__ _ _.__.._.. .._._....._... .__.__.._._. SOURCE GRP HF IICL SO, CO VOC NOx PM EUGI _._. ... ...___ ........_ _.. _ _..____. .._..__....... ._..._.. ..____._. ..___..__._ .. ._._.._.._ _ ...._.__._ _....._.__. EUG 2 ._. . ____._..... ._...-_..._... .__....__..... .._......... ..._.._._._... ____.._._.-. __.._.___._ Cont F.missions Monitoring

. . ...__.__ ._.._...._ ._._.__ ___.._...... EC(:3SD1

. ._.___... 0.42 ..__.__.. 0.00 ._ _. ..._._.._. 0.18

.___....__._ 6.86

..._._._. ... 2J7

._.__ __._........ 2.15

...._...___...... 4.28

. -__ ....._.. EngineeringCalculatfon X __._.._....... ._..-_...._ El'(:3SU2 ._. . 0.27

............. 0.00

.. 0.00

. _..... . _... . 5.95 ._..._ 0.92 _.._._. 1.95_

_ . -- _ 2.55

_ _ _ _. . Operating[.ogs X _._.___.. . .._..... ___..._..._.. ....._... I

~ a'

~ G 1 VDst

--- ~ 0.03

_ 0.00 ._ . . 0.00

. 6.13 0.77 .-......_ 1?0 ~ _. ..._. _ 2.66

.. .. _ _._ _ _ _ _ - Other(e.eplain)

. ~ ,. . . ...-._.. . _ _._. ._....- -- -- El'G 4 !'lls2

_ .._. 0.01
... .._. 0.00

.... . _ _-___ -- 0.00

_... ....._. _ _3.51

_ .. .

.. ._.._. 0.44 .._..... _..._ 0. 69_

.... _ _ 1.52
_ .. .._ . . .. _ ...__.... _......._. .__..___ ___.._.. ..__...._. et'G5-AASi 0.02

..... ... 0.33

... . ...._....._ OJS

. __...._.. . t4.98

...._ . 0.97

...__. ......_..._ 5.09 ~

... __.. .. 3.03

_ _.... .._ .._.._._ ....__...._ .._._ .... ......_..... ..._.__... LCGi-\\ti2 3.D5

--- ....__ 3.63 10.04 _ _. _.. 6.6t

. . ._...._..... 1.96 ........_._. 2.60 _.. .. _.. 3.53 _...........__. ...__._._.. ...___. . ..__._........ ......_._._. EUGS-Trim 1.67 1 2.14 4.76 3.33 0.92 1.30 1.00 ____._ _.___. ....__.. .............. .___......._ Attach supporting data ALLOWED EMISSIONS: 

### SOURCEGRP HF HCL SO i CO VOC NOx PM EUG t _........_.. _.........__. _..... _..._.___.. ._._..._...._. ............. ..__ _..._. _ _._ _........._. . _. .. .___.__ _ . .. ...._______........... EUG 2 __._... .. ....__.. ___ .... ...___._ ...._ .__........ ._.__. .._.... ___. ._ _....._._.... .. _..._....__ .. ........._._._.__.___. EUC3SDt _.._..._.. . ,.,_,,,___059

. .._.......... . __Ot0

._ _ 045

_... . . _._._ 1377

. .. . 967

_ _.._ _....._, 388

..._ _. 7.98

.._.__._._._._..._... EUG 3 SD2 _.._..._ 0.95

... _._._. 0.90

... ........__.__ 0.45 13.77

.......... . ..__-_-.... 9.67

. ._..,........_. 3.88

.. .__.._..__. . 798

.._.._._..___...._.... El'G4V ~U~I
._ .... .. _._ 0.72

., .__.. ._.._..._. 0.08

_ .. . ............. 0.18

._....._..._ ._ .. 11.43

._ __. . .._... 35.33

.._._. ......_____. 3.51

... ___..__._ 5.85

__...___._..._....__... EUG4 VD.2 ...__.._.. 0.52

__......_ ..._......._.... 0.06

..._...._.__.. 0.08

._.__..._ _ 5.09

..__...__ _._._ 17.04

.._.... __......_..._ L56 __._. _ 2.60 ..._..._.._.._..._._. EUG 5-\\

~ ti i

......... ._.__._ L43

_.........,.._.. 1.60

.._........._. 8.96

. _..__.__. 19.60

__....... ... 4.78

......... .._......_...__. 7.73

......__,..- 6.71

._. .._.._._ EUG5-\\

~ 52 _ __.._. . _...._.. L43 _....... [.60 _.. __ .. __..__. 8.96

_ ... _.._....,. 19.60

..._..._.. . __. 4.78

.._.... _ _ _ . _._..__ 7.73

. ...__. ___.. _ 6.7t

............. ...._._..._.. EUG 5- Trim 1 3.57 3.88 9.68 6.75 3.67 2.OD 1.80 EXCESS EMISSIONS: based on 1 hour runits EXCESS EMISSIONS: 24-Hr Totats SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG 1 _...._. .... .._.__.. .__..._ ._. ..........._. __..__.._... __ ...__._._ ... _ .._. _...... .__....._.... ...._ _..._.__ .... None _.__._ .. ... ... ........_ _. _... .___. .__.._ . _._.- . None

. _._____ .._._.._. .._. __...._. _.._..__._ .,. _._._...._. _...._ ..___ _.._.....__... ..___.__._.. None ._ _..__._ ... . . ........_ . __ ... __ _...__... _... . .... __.-_ None Ll;G 3 SDI ._....._.. . None

..._._.. . ..____ None

.... ..........._. None

___...._ . None

_.._.. .... _ _ _ None

_.._... _ __ . ......._... None

_.__......._...... None

. _.....____... .. None

._..-__ _. None

_._._-_.. None

_._. None ___. ... . None __.___..._ None

.... ....._.. None

__._.._. EttG3 SD2 .._. None

._.._... ....._.__..._ None

. . ............... None

.._........._ None

..._____ _. ....__.__._ None

__._..._.._ None

........_.._.._ None

_.._-_..._.. None None ..__.___.._ None None

__.._.__.._....._. _. None

.___. None .._-.,__._. Nonc ._ ____........ EI G 4 VDst

._ None ..._._ _. . ___...._. ._. None

.._._....._._ None

.. _ . ..._..... None

._..__.. ... None

_...._ ..._.. None

. _...__ Non e

..._... .._._. None None None N one ..__. _ None

.. _..... None

. ___._._. None

._.__.... EI:G

~ t\'Ds2 None _.._._.- None _... . ......._..... No ne

... __ None

_._ _....__..

None

. . N`one

. _....__.... None

. .._. __. None

.. None ...._.. Nono

. ._.._ None None

- _....

None None EUG 5- N

~ SI

. None

_..__ _..._...__ None

__ _..._.___.. None

......_._._ _. None

. ...... . ..__.... None ~

..._... ..__..._.._... None

..._...._._.... None

....__..___.. ..... ~

None None

__._.___.. None

..._.._ _.... --- None

...... . . . ..... None

..... . None

.. . ........ None

...... ....... EUG 5- WS2 _.._... . _......_._ L62 _.___._ 2.03 _... ._... . _..... 1.08

...... ...... None

......_.... . ......_. None

._.._. .__._....._. None

... .._._. None

..._... ...__ __._.....

Nono None None None None None .._. .__.. None EUG 5-Trhn None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSiON: (2) Net Scrubber # 2 was shut down due to a water level control failure. PROCESSES AND EQUIPMENT INVOLVED: (2) 1Vet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) Removed level eontrols and cleaned, reinsta0ed and caMrated (ntaterial buikt up on prube). Sehedule to ekan probes more often.
ADDITIONAL UYFORMATION * : The R'et Scrubber w•as maintained and operated according to the manufacture's mstructions. The repairs and mamtenance were done as quickly as posstltle, utilirntg overtbne if needed. 1 certify, based on information and be0ef formed after reasonable inquiry, the statements and information in this document are trae, accurate and complete

SIGNATURE OF REPORTING PERSON

Daie Received: Received By: Demonstration of Cause Submitted:

= No AC.ENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: '^ lf you wish to notify the DEQ about a technological limitation, do so here and attach suppouing information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALtrY AIR QUALtTY DMSION PO BOX 1677 OKLAHOMA CfTY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: The infomnation requested below should be submitted to the address above within 10 w•orking days after the immediate notice is given. If you are using this form to con'ect a previous eport, provide only the corrected infomtation below, sign the certification, and attach a copy of tthe previous repon.
REPORT DATE: COMPANY NAME:

1 1/612 0 0 9 Dal-Italia NAME OF INDI\7DUAL REPORTING: TITLE: PIiONE: Rick lYdOams Plant Manager (918) 683-4043 FACILITY: COUNTY: PERMIT NUMBER: Da4ltalia hluskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop TSme: Duration: 10/31l2009 0:00 0:00 0:00 Hours:Min Phase 1



### 19:30 19:50 0:20 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:20 Hours:Minutes of Wet Scrubber powntitne APPLICABLE LIMITATtON(S) OR REQUIREMENT(S) EXCEEDED: Perntit No. 2004-198-TV (M-1): Speciric Condkion 1, EUG 5 ESTIMATED EMISSIONS: BASiS OF ESTIMATE ComplianceTcsting X ...._._... ._._._._. __._......._.. .....___.... SOURCE GRP HF HCL SO i CO VOC NOx PM EUG I _..._.._._ . .._.._..._.. _. ............. ..___..__. ._ ___.__. .. __......._... ._..._......_.. _........._. ...._.....__... ..........._..._ EUG Z

. _..___._..... ...._....... .____....._. ._.___..._... .....__.___ . - .____.__ ... _ ___ _.__ _....._.... ......__._.__ _.._._.._.. ...... Cont Finissions Monitoring __.._... .......__. _..._..__ ... ..... ...._.._. _ .._......... EUG 3 SDI 0.42 0.00 ._..___._......_..._ ...._.. 0.18

... ...._..__.._. 6.86

__.._......_. _.__....._. 2.37

....._.._...__. 2.15

.........__.._ 4.28

_...._._.___ Engineering Calculatfon X

._.._._. ...._....... __..__..__. . ..____. EUG 3 SD2

.. _._..___. 0.27

.._._..... ...._____.._ 0.00

._.... _.._...__ 0.00

......._....__. ._.._.__.__..

5.98 --_._...._.... 0.92

.. ._._....__. 1.95

_..._....____.. 2.55

....._._._ _..._._........ Operating Loys X _._...___._. .__._ .......... .....__.__._ _...._..___. EGG4VDs1

......... 0.03 _.._._._ 0.00 .__......_ 0.00

.... 6.i3 _.... _ ... __.. .. 0.77

...... . .. ......._ L20
_ ~ . .._ . 2.66

. ._.__ . ....___... Other(

~ cplafn) ...._.__ _.___._ . .___.._. ._.......__ EUG4\'Ds2 - 0.01 .._.... __ .__.._ 0.00

. _ _ _ 0.00

. _. _.... 3.a1 ~

...._..... 0.44

_ ...._... 0.69

.._..._.--- 1.52

--...._.. .. ._....._ . __._._ ____.._.__ ...._._.__.__ ...__._ EUG5-H

~ SI

..... _. _ 0.02 ..__. 0.33 ..._ ..

0.38

. ........ _ _.. 14.98

. ._. . _. 0.97 ...___.._ 5.09

. _ . . 3.03 EUCS-WS2

_ _ 2.t0

_..___ .._._._... 2.50

_. . 6.92

_ _ 

### - 4.56

......... ._ 1.35 ...._._.. 1.79 .....__ _. _2.44 .. _ ..,.__.._... .. __.__ . .....___._ ._._..__.. __..___.. EUGS-Trim 1.67 ._.....- 2.14 4.76 3.33 0.92 IJO - ~ - L00 .....___.. . . _.._..___. . . .____.... . __._...... _.___..._...

Attach supporting data ALLOWED EM(SSIONS: 

### SOURCEGRP HF HCL SO i CO YOC NOx PM EUG 1 _._..._ ...___.... ..._.__...._. _.._.,__..._ _._... ..._.. ......._ _.....__._ .... __.._-_.._ . .. .._____.._ . _._.___..___..___... 

### EDG2 _._. _,. .__..__..._ _..._.._. _.___..__ _...__..._ ._.._..._....._..__...._.. ,._ EUG 3 SD 1 ._ __ 0.59

....__.._. ._._ .. 0 t0

... ...... .....__ 0.45

.. ... ._._._.. .._....__., .._..._

...__.1 3.71 .. ._......__._....__.__.._.....__...._..

4 67

. . .._.._..._.. 3 88

_ ._ _...._._ 7.98

......_.........._..._..._... 

# 960.3 SD2

...... ._....... 0.95

.. ._. ...__._._ 0.90

_. .__ .__._..__ 0.45

......___.. t3.77

_._ ....._ 9.67

_.__. ~ .._.. . _....._ 3.88

. .._ , _._._._. _ .... 7.98

.._..___............._ ECGa Vllst 0 .72 0.08 ._ ............ 0.t8

. .. .. 11.43

._ _.. . _ _..... 38.33

_ . .. _.._. 3.51

_ ....._._. 5.85

_.__..._...._...__... ECC3\ lls2 ._.. .... 052 006

~ 0.08 5.09 17.04

.. ....__....__ 156

.___....... 2.60

___..___...__._..._.. EI

~ G5-

~ CSI

. . 1.43

._._.._.. _._.._

1.60

_ .. _ .............. 8.96

.... .___..... 19.60

_....._.. .............. 4.78

..... 7.73 6.71 EtiG5-Rb3 .__..__. .. 143

_. .._ ............. 160

.__ .............. 8.96

..._......._ 19.60

........ 478 .__.._._-- -- ..._.._ 7.73

._ __...__._.. .. 6.71

- _-..._.__...__..___ EUGS-Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMtSSIONS: based on t hour limits) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM

. EUG I _,__... __. ._..... .._ .._.___._... ........__.. . .._._........ _.._... _..__.. _...._.....___ _._....__.. None ........._.__. _ .....__.. __...._... .._...... ...... _._..._. ..........._..... None ...._._......... EUG 2

......... ___...._..._. _____. ,..._..._._ ..._ .. _ _...._. ..........._..._ __..._.... None .._.... ._...__.. ._...___..._ .._._ _.._ ...._._... ......._. None

... .__ 

### EUG 3 SDt

... _ .._.___ .. 

### None

.__._..._. ..___. 

### None

._ _.. _....._..... 

### None

..__.....__. 

### None

_..._...__. _.._ 

### None

..._._.......... .__. . 

### None

_....._....... 

### None

__..__..._._ .... 

### None None .........._. 

### None

. ...._.._ 

### None

....... . ..._._...._...



### None None

..___._ 

### None

_........

. 

### E UG 3 SD2 .._.....___._ ..._. 

### None

..___. .......__. 

### None

..... ._ __.__.._... 

### Nunc

._._. . .. .... 

### None

..____.___ . ___ _. 

### None

_.___... .....___. 

### None

... _ . _.__._.. 

### None

._ _.. . _..._.. ._.... 

### None

._........ 

### Nune

._.__... 

### None

......__ 

### None _.._ 

### None

_........ 

### None

_...._... 

### None .._...._.... EUG4 VDsI _.._ .._._ . None

.__.._._ .___..._. None ...._..._ None

._.__ .. None

._._...._._ _ None

-._ .... .... . .......__. None

.... _ __..._ .. None

.. _.. .._.._ None

......... None None

. _ ._. None ..__. __ .. None __....._. . None

. ................ None

.._...._...__. EUG4 VDs2 ..._..__.._. _ .. None

........... None

. ... ........_._. None

.._._..._.. . None ._.___ None __..._. ....... __._. None

_ ....-_...._... ........_._..._.

None None ...._.....__. None

..._......._. None

_..._._ None _._ ._.._..........

None None ....._..__.... None

......_........ 

### EUG 5- WS1 _. .._.._.... .._ 

### None

....__.__. .. ..._.___ 

### None

_.. _. _... _....._.... 

### Nonc

. 

### None

._..__..._ ._.._._..__... 

### None

_..._._.._._ . 

### None

....... . ...._..._ . 

### None

_ ....._....... -- -- 

### None

. 

### None None

_... 

### None .__. ....__.____. 

### None None

...____... 

### None

.. . .......... 

### EUG 5-\VS2

__ __....__....._........_ 

### 0.68

. . ............. 

### 0.90

......_...._.._ 

### None

......_...._.._ 

### None ._.__...._ 

### None _....__._._ 

### None

_.._............ ..... 

### None

.._.___ .. .... 

### None

_..__... 

### None

.__...._.___ 

### None None None

. _.....____. 

### None

.... _...._._..... 

### None EUG 5-Trint None None None None None None I None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) Wet Scrubber # 2 w•as shut down to perform a probe swftch. Change the high/high probe wHit the low level probe. PROCESSES AND EQUIPMENT INVOLVED: (2) \Vet Scrubber #2 CORRECTI VE 6iEASURES TAKEN: (2) Sw•Bched probes to a0eviate water level probknt, will monitor closely all nlght.
ADDITIOIVAL INFORMATION * : The Wet Scrubber was mamtained and operated according to the manufacture's ktstructions. The repairs and maintenance were done as quickly as possOtle, utifving overtime if needed. 1 certifv, based on information and be8ef formed after reasunable inquiry, the statements and inforntation in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: O No AGENCY USE ONLY DateSubmitted: TrackingNumber: Team ID: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting inforniation. DEQ-Form #100-920 Revised February 8, 2008

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM , OTE: The information requested below should be submitted to the address above xvithin 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the corrected information below, sign the certification, and attach a copy of the previous repon.
REPORT DATE: COMPANY NAME:

t I/62009 Dal•Italla NAME OF INDIVIDUAL REPORTING: TITLE: PHONF.: Rlck Williams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBEl2: Datdtalia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISStON: Date Start Time: Stop Time: Duration: 112/2009 0:00 0:00 0:00 Hours:Min Phase 1

22:42 23:21 0:39 Hours:Min Phase 2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:39 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 2004-198-TV (M-1): SpeciBe Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF EST[MATE Compliancc Testing X _._...... . ..__... ._..._......_ SOURCE GRP HF HCL SO z CO VOC NOx PM r:[G I ' .__.._ . __....__ .. .........__. .... _........_.. . _ ..__._ _. . .__ .. .. ____..... ..__._..._. ......__.._ _. EI,G 2 _. . _.__ . ...._..._.... . ......__ _._. ._..._.. ... ___..__.. ._...... .._..._ Cont Fmissions Monitoring

........ . ......... ._......_ . ... .._.__.. .. .__._._.... 1:I

~ G z SDt

.. 0.31 0.00 0.13 .._. .._... . . 5.02

.__._.__. . ___... 1.73 .._..._._ IS8

.._......... 3.13

...._.__.. .. Esc.ineerim_ ('alculztion X

...._._ ..._.__...._. ..._.__ .. ._ f.t - G 3 SD+ 0.33

..____. . ..__._. 0.00 _.._.__.._.. 0.00 7.44

.. .__.._._ .-._.._,.___..-.--_-.__._ I. .___..._....... 2A2

" ............. 3.t8

............. .__.__._... Opuating Logs X

_ ._._.___.. ___.... _. ._._ EU(: J t'Dsl 0.03

.. _.. _...___.._ 0.00

_ ... . ._ . 0.00

. .. _..... 6.07

.. _. . . _. 0.76 [.19

... .._.. 2.63

.

............. ........._. Other(cxplain) .__..__. ._.__._... ._._ t:I1G 4 VDs2

. O.ot

. _.... 0.00 _. 0.00
- ~ . - ~ ~-~~ - 3.56

.. . . _.. 0.45

....._ ._... 0.70

.. .._. t.51 _..

...._..._ _.. _...___. .__..___ ...._...__ __...... __.__..._. EUG5-w;Sl .._.. 0.02

.. . 0.31 0.36

_ . _ - . .. .. t4.35

. _. .. _ _ 0.93 .."
.

.._._ " _._... 4.88

..._... .... 2.90

.._. _. . .. . .

_ EIrG 5 w:ti> 3.63 4.32


### _ IL96 7.87 

### _..._ 2.33 

### __.. 3.10


### _ . . 4.21 

### _._ .. . EUGS -'frim 

## 1 .64 ._._. 2.t0"...... --""y.67 3.27 0.9I L27 0.98 Attach supporting data ALLOtVED EM ISSIONS: SOURCE GRP tiF HCL SO t CO VOC NOx PM FOG t ._ .._. ...._. _. .__._..... ..__...... _._.__. ...__ .__... . __.....__... . ....._......_ . _.._._._._..____.... El ,2

_ . _ _.... _ _......._ _ ....___._.. ._.._..... ......._. ... . ..... . . ..._._.__ _ ....... ___ .. . .__.___ ..____.. ECG 3 SDI

.. 0.59

_..._... .__. 0.10

_ ___..._ 0.45

.._._..._ . 13.77

.__.._..... _... 9.67

_...._ _.._......_ 3.88

_. _._......_._ . 7.98

. _.._._......._._....._. CI G 3 SD2 0.95 0.90 0.45 13.77 9.67 3.SS 7.98 Ft G a \ua 0.72
..... _.__... . 0.08 ._...... .. ..___._ . ..O.i8

_ . _ -___...it43 _.__...__.

_._....._ ._...__ 

### 3833 ...__._....

. .__....... ..... i { i .__. _...__...

. 

### ;.8=

. _.- GI'G a\'U.t? _. _...... 0.52 0.06

..............__._._. 0.08 5.09 17.04

. .._._..__....._........__ L56

........... 2.60

_.__.___.._._.... EI:GS_R51

_ . tA3

.. ..... t.60

. .. ........ 8.96

. .. . t9.60

..__._._.. .. .____..... 4.78

_ ._. 7 .73

.... _._. 6.71

............_..___..._._. EU(:i-wy2 ....__.._ .. 1•43

. _...._.... 1.60

... ..___._.._... 8.96

_....__...__ 1960

.._..__.. 4.78 7.73 6.71 _._..._._.._...__.... EUG5-Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on t hour IhnOs) EXCESS EMISSIONS: 24-Hr Totalc SOURCE GRP HF HCI s0, CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG I _......._. _. .._. _. "._.._.
. ....._ ... ._.._..._ .. . .. __.. .__ _.... ....._.._....... .. . ______ None _......_ __ ___... ...______. ___._..._. _..._..... ..._____.. None .._._..... EUG 2

. . ._. _.

.. ..__... _ ....___. _ . ~ .__. .. ... .......__ ...... .. ..... None _.. ._ .. . _.._..

.. .. . . . _._._ . . _. . .. "... ._. .... .__ None EUG 3 SDt None

_ _.___... None

.... None

. ._.... None

.__. ._.__ None

...._._._..._ 

### N

_.._ o _ ne _.._._._ Nune

_...._ ...........

No ne None .
..__...._. None

.. N . one e ._....... Nonone

... N None EUG3SD2 ..._. .. .. None

._._.__ _..._. None ~

.. ._.._..... None

_......... None

_..____ .._ .......... None

...__...___. None

....__.._..__ .. Nono

._.._..__.. _.. None

.._.__ None None

__... None _.. None _....._...._...._.. None

_ None

... _.__.._. EUG 4\1Tsl _.. . _ _. None

.. ........_.. None

_. .__...... None

.___.._. .. None

___..._. _....__.. None

... ___..__.. None

_.._...___ ...._..._.__....

None None .._._...... None

_......_..._ Nune .....___.._ None None ...._...__.........._.

Nene None F.UC;4 VDs? None

........... .._.__. None

... _..._.___.. None

.. _.....__. None

...__.. None None None

.... None .._..... None None None None ......._...._. _. None None

. ._..._.__.._. F:1'G 5-AtSl

_ _....._ None

. ............. None

_........ None

....._....._ . None

.__... ..._..__. None

..._...__.... None

.. ..__..__._ ...___._._....

None None

...__..... Nune

..._........._ None _.._.._..__ None None ...___.__ None

._.....__.. None .._.._.__.. EIiG 5-AAS2

........... .. . 2.20

...... _. .........._ 2.72

.. .__.._.., 3.00

...._... None

..._.... .... None

.......... . ...._....... None

. .___...__. . None

_ ....._. None

.....__ .. None .__....__._ None

.__. None _.. __. None ___...... None None EUG 5- Trim None None None None None None None None None I None I None None None None NATURE AND CAUSE OF EXCESS E\1ISSION: (2) The Scrubber was shut down to check the nonJes to ensure they were dispensing water. Tentp was ricing above 147 PROCESSES AND EQUIPMENTINVOLVED: (2) FVet Scrubber #2 CORRECTIt7 ✓ MEASURES TAKEN: (2) Noncls were eleaned and the scrubber was restarted.
ADDITIONAL INFORMATION * : The Wet Scrubber was maintained and operated accord'mg to the manufacture's instructlons. The repairs and maintenance w•ere done as qulckly as poss0ble, utilidng overtinte ifneeded. 1 certify, based on informatfon and belief formed aRer reasonable mquiry, the statements and information in this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted:



## ~ No AGENCY USE ONLY TrackingNumber: Tea,n tD: DatcSubmitted:



### x ` If you tvish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALtTY AIR QUALffY DMSION PO BOX 1677 OKLAHOMA GtTY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The infortnation requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this form to correct a previous eport, provide only the correeted information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

1 t/6/1009 DaFltaOa NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick WiOiants Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: DaI-Italia Muskogee 2004-198-71' (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 11/52009 0:00 0:00 0:00 Hours:Min Phasel

10:15 11:15 1:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (IIOURS:MINUTES): 1:00 Hours:Minutes of Wet Scrubber powntitne APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (hl-1): Speciric CondHion 1, EUG 5 ESTIMATED EMtSSIONS: BASI5 OF E5TIMATE ComplianeeTesting X

. ....._.._..... ._._._ _........ . _.....__.. _.._..._.._. SOURCE GRP HF HCL SO z CO VOC NOx PM EUG 1 __.. . .. ..___ _ ....__. . __...__ _._....__ . . .._.__ .. .... ... ..... ............_ .._._.... ._...____. _ EUG 2

......... ..__._ . _._.._... _ . _...._..__. . ......._..._... ._... _... ...._.__.. .__.... ...__. ._.......__.. Cont Emissions Monitoring ._..__.._. ...._...___ .......__.... _._._..._._. ... EUG3SD1 _......__. ..... OJ9 0.00 O.t7 ........_.._. . 6_l5

._..._._._ . ....... 2.19

._... ...__......... 2.00

._...._.... _. 3.96

. _. EngineeringCalculation X

_..._._. ........_... ._......_._.. .._..____... _...._. _....__. EUG 3SD2 .__....... . 0.28

._.__. .. _...__... 0.00

..._.__. 0.00

.._....._._. . . 6.31

__.__. ._.._....... 0.97 ......__.._. 2.06

..__.... 2.70

_.__..__... ...__.... Operating Logs X

....... .......___.... .._.._ __. ... EUG 4

~~ Dst

.... .. 0.02

. .. ..___....... 0.00

...._.. . . 0.00

_ _ . .. _.. - 5.82

..._ ._.._....... 0.73

.

..__.. 1.14

. _.._.. 2.52

. . .._...__..._ Other(explain)

.....__.__. _......_.... _......__..__ _.._.._.__.... EUC 4!'Ds2

. 0.0t

.._._._. . ...__._.. 0.00

.. ..___.. 0.00

_... _ . . 3.49

__ . ....__. 0.44

...... .._.._.... 0.68

. . .... t.51

_ ..... ..._ __ ._...._.. . . ..._.....___ .. .._.___..... . . _.-._.__.. EUG5-

~~ 'tit ._ . _.. ....._....._ ..__._.._._.

0.02 ...__ ........ . ....... ... ~~~ 14.64

.. ._._...__ 0.95

.............. ~ 4.98

.. ..... . _2.96 ....._. ..._..... ..._.._.._..... __._...._..._ -._..._. ._.._._...__ EUG 5%N.S2

_ . 6.22

_.___..__.. 7.40 .._..... 20.47

. ___.._ . 13.47

............

.... 4.00

. _ 530

. . . 7.21

._... .....-._- .__.........._. _......_....__ .._._...... ....._...__ . ..__._._..... EUGS-Trim 42t L55 3.45 2.42 0.67 0.94 0.72 Attach supportmg data ALLOWED EMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EUG 1 ___.._ ._.._._. .. .__............ _._.__..... . _ ______ . .___.._.... ._ ____....._ ...__._. ........... ........... EUG 2

. ___._ ._.__. ..____.._._ .__..._.... __.._._.__. ..._..._.__. .. ...-_._. ..._.._..__... .__..._...__. ..._.__...... .__..... EUG 3 SDl ...._.._ 0.59

...._.._ __...__.__ 0.10

. ..__...__ 0.45

.--_- -._..._...... ... t3.77

___..... .. ........ 9.67

................. 3.88 7.98 _......__.-.. __.._. EUG3SD2

......... _.......__ 0.95

_......._...._.. 0.90 0.45 13.77 ._...__..__. 9.67 ..._....._.._... ...._.__

3.88 7.98 _......___ ....__.__._._....___.. EUG4 VDsI_

.. . . 0.72 0.08

.. _ ...___ _0.18

. 11.43

. _ 38.33

. .._._ 3.51 5.85 ...__._ .._ .. _..._.._... EUG4 VDs2 ___.._ .._ 0.52

_..._._ ..__..__. 006

~ 0.08 ...___.... _....._.__

5.09 ._._..__

..__..__.. ..1704 _..._...._..._. L56

... _..._.._. 2.60

_...__._.._ ...._._..._ EUG5-W'S1 .._.._._..._.. 1.43

____._ ._...._..._. 1.60

__......_._.. 8.96

............ 19.60 4.78

_..._... _ -_._._....._ 7.73 6.7t .....__......__.__. EUGS-WS2

. .....___ . 2.85

......... ..... ..__..._ 3.20

. ..._._.,_..._. 17.92

.__.._...._ _ 39.20

__.....___. __._..... 9.56

.._.. _. ...._ 15.45

_ .. . 13.42

._..._.._........_....___. EUG 5- Trim 3S7 3.88 9.68 6.75 3.67 2.00 L80 EXCESS EMISSIONS: (based on 1 hour fimits) EXCESS EMISSIONS: 24-Hr TotaLs SOURCE GRP HF HCI SO. CO vOC NOx Phi tIF HCI SO i CO vOC NOx PM EUG i ......._ _ .._._._ ._....._.__.._ ..___._ _ ...._ ...__._ . .. ___._..._. . ..__..... .__. .._ _......__.. .........._. None .........._._ ... .____.. _.._.__.. ...._..._ _. ..___..._ ....___.. None ..__ _._.. F.UC. 2

__ ....._..__... .. ........_.. . __._.._. _ ...._._.__ ......._ _.._. .............. ._. _.._.. None _._..._....._ _... ._.._..__. ... _.. ._ ......___..._........ _ None

.... .. .. ..__.

_ ECG 3 SDI None

_._ .. ...__._..._ None

... ......_.._..._ None

- - .. _...._..._ None

....__ ... ...... None

....... .. .. . . ............ None

..._____ None

..._...._._... ..._ None

.. . None

. . _.._...... None None

.._ . _.. _. None ..........__.. ~ one None

......_.. Et'C 3 SD2

... __...._.. None

...._._..__ None

... .. ... .. .._..__. None

...._._.._._ .. None

_... None

.._._._..._. None

............ None

............ ..._.. None

._.._._. None

___._.... None

.._._._. None

__ None ....__.... ..._. ~ 'onc _. None ._ ....-.... EUG a VDsI

.... __. . None

_..._ __......_._. None

. .. _____....._ . Nono

_ _.. _._.._. . None

....__._.._ _._.... None

...._ _.._..._..._. None

.._....._ .. None ..._____._ .... _. None

_...._..._,._ None ..__. .. ._ None

.._..__. None

__ .._ _ None __......__ - ~~ onc _.. Aone

..._._...._.... EItG 4 VDs?

.. Nonc

_ . ...__.._. None

._ ..__....___ None

. ._.. _ None

.___..__. .._.._...._... None

.___.._....... None None ...._......_. ._._... None

...._._ _ _. None ..__ . .. ~ nne

__..__ None

.. . None

.......... . ~ unc
.... . None

.... _ .. EL:G

~ -At

~ 51

. None

... .__ - None

._ ...._._.....__. . None

.. ..__...___ _.. _. Nono

. _......_ _ _ . None

_ ...... . .... .._..... None

. _____.._.. , . None

...._._...._ ._. None

_......._.....__. Nonc _.. Aune

. _.. None None

.._..._.. ,~ 'on< Nune

. Et-G_i-

~~~ .ti7,

. .. .. .__ 3,36

._...._ _ ....._._._ 4.20

._ .__..... 2.55

..._.___.._. None

___..._. ..__. None

....._ . ...... ......._.. None

.._..._._..._. None

._.___..,... ....... None

.._... Aone

_....... Aone

. _..__......_. None

.._ Nouc .._............. : ~ 'uuc

.. .__ .. Nonc

.. ...___.__.. EUG 5-Trlm None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down to clean the spray nonks, check water lines, and change thermocoupler. PROCESSES AND EQUIPMENT tNVOL\'ED: (2) Wet Scrubber #2 CORRECTIVE MEASURES TAKEN: (2) The nor

~ les were cleaned, thermocoupler was changed, and the scrubber was restarted.
ADDITIONAL INFORMATION*: The W'et Scrubber was mamtamed and operated accord'mg to the manufacture's instructions. The repafrs and maintenance were done as quickh , as possdtle, utiG+ing ocertime if needed. 1 certifv, based on mformation and belief formed after reasonable inqu'r,v, the statements and information in this docuntent are true, accurate and complete

StGNATURE OF REPORTING PERSON

Dato Received: Received By: Demonstration of Cause Submitted:

= No AGENCY USE ONLY TrackingNumber: Team ID: DateSubmiued: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Rewsed February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALffY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM , OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fonn to correct a previous 

### rep ori, provide only the corrected infonnation below, sign the certification, and attach a copy of tha pre4ious repon.
REPORT DATE: COM1I PANY NAl1i E:

I 1lt3l2009 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick FP'dGams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Itatia Muekogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 111672009 10:40 12:30 1:50 Hours:Min Phase 1

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS Eh1ISSION (HOURS:MINUTES): 1:50 Hours:MinutesofWetScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 2004-198-TV (bt-1): Speciric CondHion t, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIM1IATE ComplianceTating X ........_ .___....._. _...__. _ . ._._._..._.. ........._._. SOURCE GRP IIF IICL SO t CO VOC NOx PM1i EUC I ......._ .._..._.___ ...._.__.._. . _._.._._.__. _....__... ...._.._...- --.._,. __.___..-...... .._ .._._.____ ...._. ........ ... EUG 2 _........_.. _.__ ....__ ._... _.._ _. _.._..__..__.. _....._._... .__ . _._._... .-__ __ __... .........__..... __ ........ . ....._....__. ............... Cont Fmissions Monitoring .__..... .. .._.._..._.. _ .......__._ .. . .___.._. EUG3SD1 ._._......_.......__... 0.45 ._._. 0.00

. ......_.... 0.19

._.._._.-._ .. 7.23

_..__._.. . ...._... 2.50

..._.. . _..___...... 2.27

.__._._ _... 4.51

. .__. ......... ..... EngineeringCalculation X

_.___.. .._._......._. ...__.... __. ._...._..__.._ EUG 3 SD2 0.30 ____..... _. . . 0.00 .._......... 0.00

__...._.__. ..- 6.78

_-_.__..... 1.04

.. ..._._._...... 2.21

.... 2.90

.._........_.. ..._._. Operating tAgs X

........... .._...._....._ ..__...............__ . _ _. EUC 4 VDsI

. .. _ .._ _. 0.03 ...._._ . ._..___ 0.00

_ . ........... . 0.00

. . ... .. .. 6.05

......__._ ,_..._.. 0.76

..... . _..__..... 1.19

..__._ . 2.63

_. _._.... _ ._ .... Othcr(explain)

.._....._ _.._._. ....__ . .__...___._. . . ._.,.__._ EUG4 VDs2 .._....._ ._.._._.__ 0.01 __ ....... 0.00

...... . 0.00

. .. .. . 3.52

_ __._.... 0.44

.. .....__....._ 0.69

. 1.53

_.._.. . ....._.._... _ _.......__. ..__... ._..___._... . ..,.._.__. EUGS-WSI ._. ..._ ... 12.02

........... .._._... 14.31__ ...

. _ _ . ~~ 39.57 26.04 7.72 ._.._....... 10.24

.. _.... 13.30

._ _. .. . _......_.._.. ._____.. ___...._ .. _...._.._...._ . _ _ ...._._... . EUGS-WS2 _ _. 0.00 ..... _... __.___ O.Ot ~ ...... ~

... . . - ~ 0.02 ~~~~ _.._......... .._.. . 14.34

~~ "'_ .._.._... __. ..... 2.40 .__. 4.6 ~ 4.21

. . ..... ........_. ._. __..__. . . .....___ __...._.. _..._..,_.... EUG 5 - Trim 1.59 2.03...._._. - -

~ 4.52 3.17 .... .._.. 0.88 - -_.. ..__ 1-23 _......._ .___... ._._ .. ........... __.... Aftach supporting data ALLOWED EMISSIONS: SOURCEGRP HF HCL 50 i CO VOC NOx PM EUG t _.._._.. . _..... ._ ...__.__ ....._.. .__._... .._._. __.. . ._._....__. _... ._..._..... _.....__......._.......... ......... UC2 E

... .. _ _.....__ .__._.. . ____..._. ._._.._ .. . .. ..__._...._. ........._.__ __..._..___._._. hUG3SDI

.... .. - ._._..._. 0.59 .._...... 0.10 ....____.,.... 0.45

...__...__ I3.77

....._..._ . ._...___.... 9.67

....___....... 3.88

_....... 7.98

._......_..._......... _ El'(:3 SD2 __.. 0.95

____.... _.._..._ 0.90

._ . . __......_ OAS

___...._.._ .. 13.77

__._.._ .__._._ 9.67

___. _._......._...... 3.88

............. 7.98

_._......_.._..._..._. EU(:JVDsI

.._... 0.72 _...._.. ._.... 0.08

_.. . _._._... 0.18

.____..._. . IIA3

___..._.. ._._._....__ 38J3

_.........._._. 3.51

. _............ 5.85

.__.___...._...___. ECG4 VDs2

..... ._ . ...._ ...._.__ 0.52 _.._._._ 11.06 _. . _........__. 0.08

.__ _. _ 5.09

.__._..... .._. . ._.. 17.03

_.._. . ._..._..._._ 1.56

....___ 2.60

........_.. , _........ Et:GS-FVSt __. _....._. . . 2.85

.._..__. ._........._._ 3.20

.__......... 17.92

.._....,.-._........ 39.20

.__..._.. ...._._......... 9.56

..__......-__. ISAS

..._._....... . 13.42

_.._.._____.._.._...._ EIIC S- WS2 ._.._.._...._ _._.._. 1.43

........ ......__.___. L60

.__...._..._. 8.96

_.___..__.... _._ 19.60

..._..._. 4.78

... .............. 7.73

.._._._..... 6.7I

.. __......___..._....._. EUCS-Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on 1 hour IimBs) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO z I CO VOC NOx PM HF HCI SO, CO VOC NOx PM EUG I ._..__. _...._..__. .__..__.... _.....__._._. _._._._...._ . __.__. __._.......__......___....... ._......... None ._._....... _......_..__. ._._... .._.... ...._._ ._._..__.. ......_..__._ None

. _...__... EU('2 ....._. .._. ' ....___... .. _ ...... .. .. .........__ .._...._... ....._.._._ . .-_. _...._._....__... ...._ . . ....__.._ _ None _..._.__..._ _._ .._._... ...__. ..._. _.... _._ ._ .._._....__ .... ... .__._ None

. . _.._..._... EUG3SD1 ..__ ._. _._ ... None

.. _._....__ None

... .__. _._..._ .... None

..........._ None

._...__ None

_.._ ...... None

.. . __._._...... None

_...._ ...... None

..._..... None ____.__._.. None

. . _.._._..._._..

None

. None .._.._.. None .._. _._...._ None

. ....._..._... EUC 3 SD2

.... ..... _......_. None ___....__..... None

..._._.__.. None ___..._ _...._ _..._......_...

None None

__...... . ._.__. None

. -. _...._._._..._ None

_.._._ ._..._ ..... None

_...._. ... _ None _., ........_ None

.. ...._.__ None

...... ... _. None

. ......_... .. None

__. _.._ None

_ _ ....__. EUG a\Dsl

.. None

__._..__ _ _ .........._. None

... ......_.....__ . None

. . . None

_....... _..__. None

_ .. . _ ......... _ None

. . ___...__. .._ None

.. ....... . None

. __.... None ...._._.....,_. None

_ ..... None

.... ... None _. ....... .. None _.. ... ...._. None _.. _ . ..__.... EUC 4 YDs2 _......... .._ _.. None

. ..._......_._. None

...._........_ None

...__....__... ......._.._._

None _.._.._ None

......... ......._.._. None

..... .......__. _...._.. None

.._._...._ None

... ... ._... None

......_.... None None

..__..._._._.._.....__..__

None None _.. _...._ Nonc

.. ........_.. EUG 5-\YSI _.. _..._.... .. 9.16

.._._._. . _ _.._._ .... tl.lt

... _.____... . 21.65

.. _ ._.......... . _. None

..._._..... ...__.._ None

..._....__ _. _ ........ None

. ..... _. _..__----....._._

None

........ .. None .__... None .._......_.__. None

. ....... None _......._....._..._....

None None ...._ ..___ None

._._ ._....... EUG 5- W

~ S2

. ,_.___....._ _._ None

.....__._ _.._.._ .. None

... ..........__ None

. _._........._.. ... None

........._.._ _....... None

....._... .. . ._......_, None

. .___.._.__ ._. None

.. _...._.__..... .. .. None

.....___ _ None

.............. None

..... __.._ None _._. . _ None ..._..___. .... None ...._.._ ___. None ...._._.. ....... EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) The Scrubber wae shut down to clean the norks. PROCESSES AND EQUIPMENT INVOLVED: (1) Wet Scrubber#1 CORRECTIVE 11EASURES TAKEN: (1) Cleaned novks and checked Itow 6nes, restarted the scrubber.
ADDITIONAL INFORMATION*: The Wet Scrubber was mafntained and operated according to the manufacture's instructfons. The repairs and ntauttenance were done as quicklv as possOtle, utilbing overtime if needed. 1 certify, based on mformation and betief formed after reasouable inquiry, the statements and information in this document are true, accurate and complete

SIGNATURB OF REPORTING PERSON

Date Rec<ived: Received By: Demonstratfon of Cause Submitted: O No AGENCY USE ONLY TrackingNumbcr: Team ID: DateSubmibed: * lf you wish to notify the DEQ about a technological limitation, do so here and attach supporting inforniation. DEQ-Form #100-920 Revised February 8, 2008

## O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALrfY AIR QUALtTY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM

~ OTE: ?he infortnation requested betow should be submitted to the address above uithin I O.vorking days after the immediate notice is given. if you are using this fonn to correct a prevfous eport, provide only the corteeted information below, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

i l/13/2009 Dal-Italia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick R70iams Plant Managcr (918) 683-4043 FACILtTY: COUNTY: PERMIT NUM1IBER: DaHtaifa Muskogee 2004-198-TV (M-t) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 11/9/2009 0:00 0:00 0:00 Hours:Min Phase 1



### 10:50 12:50 2:00 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTF.S): 2:00 Hours:Minutes of Wet Scrubber powntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No. 200.1-198-TV (M-1): Specirce Condition t, EUG 5 ESTIMATED EM1115SIONS: BASIS OF ESTIMATE ComplianeeTesting ......._.. .__.__.. .._._...... . X SOURCE GRP HF HCL SO ~ CO VOC NOx PM EUG I ......_ . ....___._ ...___.._. . .___ _.._._. ._ . . .__

. _.__._.._ . ._._ ........... ..... EUG 2

. .._...._._ _ ____..._ _...__._ ._ . .._._,_.... ._......_ .__...__ .___ ._..._.__. ....__._. .. , _ .___... . ._.__...__..... ._._ _.,..._.... ..._ g Cont Fmissions Monitorin

. _.-...._- .._._.._.. __.......__ _......... .._...____.. X EUG 3 SO1 _......__ ._ _...._._ 0.36 ..._..... 0.00

__ _....___.__. 0.15

. __._..._._.__.._... 5.73 1.98

.. ......._.__ 1.80

. __._..... 3.58

_ __._.___. _..._ Enginecring Calculation

.__...._. _....___ . . . ....... ............._. . ..._.._.__... X EUG 3 5D2

.... ........ . . _ 0.28

.__..._._ _. __.. 0.00

_ . .,_ ._ ..._._. 0.00

_...._._....._ 6.? 7

_.._...... _.... 0.96

.._..__ _._ _ . _ _...__. 2.04

. ._........ . _ .. .. . . 2.68

. _ _.. __.._.... ._ . Opa'ating Logs

_. _.._._ . . _ _.__._. ___....._. ............ _.... _..__ .. EUG4 VDs(

. .. _ 0.03

.__.._.. _

. . 0.00

... . .......... 0.00

. . ... . 6.21

.._....._.._ _....... 0.78

....._. _ . ...._.__. L22

_ .. ... _. . 2.69

__ ___ _.. . . Oihcr(cxplain)

........ ......__ .__._. _.__._.._.. ....._..- __....._._._-. EUG 4 VDs2

. . 0.01

. . _ 0.00

_ .._._....... 0.00

.._.... _.. 3A2

..___... .. _ ... 0.43

..._..__ . .._...._ 0.67

.. _.. ...._ .. ~~ L48

.._ ...._ .._ . _ ..... ....._.._ .. ...._..__.... .____ _._.__.. ...__._..__.. EUGS- ~~~1

.. 0.02

. . ._,.__.. 0_l2

_.. _ . . .__... 0.37

......... . 14.68

......... . . 0.95

...._...._.. 4.99

_ .. ..._. .. 2.97

_. ..._..... ..._.. _._...._. .. _..._.... ...__. _._._. _._.__... _.._.._...

~~~ EUi. - : S- WS2

_ .. ~ -......_ 12.41

. . _..__.... t4.78

_ ......__._.. 40.88

. . _ 26.90
- ~--~

. ._..._ . ~~-~~-~~ 7.98

.--- _ . . .. ~~~~ ~ 10.58

. . .. . 13.74

. ..._ . ............ . ....___.._ ._. _.._.._. .__.._.__. __._..... EUG5-Trbn 1.44 1.84 4.10

~~~~ - 2.87 ~-~-~--~~~ 0.80 ~~~~~~ ~~~ 1.12 ~~~~~ ~~~~~~ 0.86 .......__. ..._._._...__ .._.__.__ . ______.. _.__._. ALLOWED EMISSIONS: Attach supportmg data SOURCEGRP HF HCL SO z CO VOC NOx PM EUG 1 ....._.. ...__.____ . _..-......... _.______. _.__ .____ ..... ............ ._........ ............_.... ....._._ _._...__.__...._... EL'G 2 .__ . ..- ___...... __. ._ __._.._ .._._..._ .... ............ .... __._. ..._........__. ...._.._. . ___........_..._._._. EL

~ G3SDt

.. __..._. .. __ ..
_ .. 059

. ..._._..._ 0.10

. ............. 0.45

......._.. ._

_.._.__1377_„_...,,,,,__. 9.67

_ .....__. 388

. ......._._. 7.98

__...__.._...._....._.. FUC? SD2 0.95

.____........ ._..... 0.90

_. ..._..__.._. 0.45

..._......__.. . 13.77

_._.__...._.__ _._...._.._..........._..

9.67 3.88

............ 7.98

................___.__...._ ll: C J ~ Dsl

.. 0.72

._....... ..___._.... 0.08

.........._. 0.18

__..._ I 1.43 ._.....,.__ . .__......_.._ 38.33

_......_...._. 3.51

.._ ........... . 5.85

......................... EUG-I VDs?

......... . .. 0.52

.._._.__. __.__.._. 0.06

._ ....._..... 0.08

._....__..._. _.. 5.09

._.._.._.... ....._ .....__.. 17.04

.. ......_..- ... 1.56

. .. ............. 2.60

.__...___...-_.-_..... EUG5-WSl .__. ... _...... . t.43

..____ ... ..............__ 1.60

....._._....._. 8.96

.__ _._....___ 19.60

_.._.__...__ _ _.._. 4.78

_...,._ .. ,.. _._.._ 7.73

. . __.__.._.... 6.71

._.......__.........._. EUG ;- 1VS2 4.28

.._.___. __....... 4.80

_.__..._.__. 26.88

-_-..__....._ _. 58.80

....._...._. ..___...__.. 14.34

. ....._......_ 23.18

_._._..._... 20.t3

.._..__........_...__._.. ED__G_±-'I"rim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSION5: based on I hour 8mhs EXCESS EMISSIONS: 24-Hr Totats SOURCE GRP HF HCI SO i CO VOC NOx PM tiF HCI SO r CO VOC NOx PM EUG I

___ . __.__.. . .__ ..... ..... ......__....._ ..._..._._.... .- - - __.___.. ...._.... _.__ .. _.__.___.. ..__....__.. None ........._..._. ._.. _.-_..._ ___.....__._. . ._._. ._._ _.... ...._... ..._.._____ None _........___. EUG ? ___._ -_. ..____.. . _._.... _.. .__._._ .__.__..__ . ..._.._._..._ _...._ __..__ _. ___..._.... ___._.._.._. None .._.......__... .... __......... .. ._._._.._.._ ._..._ ._.. ......._..._. . ..._. _..._.. None , _..__ EUG3SD1 _.. ... . None

......_.. ._._....._.. None

___........ None

...._._._ None

_____. _...... None

._ ...... .........__.. None

. ....._._....._....._..._ None

.. __. _ ... None

.__....._ ._ None

.._..___.. None

.____.. None _.._..... . None

._.._..... None

_.-._.__ None

_....... EUG 3 SD2

. . .._ None

_...... . ........ None

.... . ............... None

_._..__.. _ None

.._._..... .._._. None

__._.. . _ _._._._._. None

...._._.____ _.._.. None

._..__. ._._ None

._._.__ .. Nonc .__ _..___ None

. __... None .__ . _ None __...._ . None

__..._.__ None

_.._..... tai(:4 VDs1 None None

.......... ...__._...... None

. __.. _._.. None

._._._..... .___. None

..___. . _. _.___.. None

.._ _ _ ._.__ ...._ None

_ ..___. ._.,._ None

. _._. . None

_.__. None

. ...__..... None

. None

........_. None .._._...__ None

....-.._. EUG 4 VDs2 ..._ ._. .._ None

__.__ ....__ ....... None

. ......._.._ None

-__..._ None

..__... _..... None

____._... _ _ _.._._ None

. . ---____ None

. ____................. None

_ __... . None

...____... None ._._,....-_ Nnne Nnne

. ._ . None

. ...._.___ None

.___.._... EUG 5-AVS1 _._..... ... None

___..... _...._._ Nono

.__ . ...._._. None

.__....... None

_._...._ _._ None

..._....__. . ......._.. Nane

.. -. ._. _ _._ . None

_ _..__-.__ ,.... None

..._ __ None .__..___._. Nonc

....._._. None _..._... . Nono

_ ,. None

_._._... None

...._...... EUG 5-

~ VS2 ._._.__ . 8.13

_....._._ 9.98

_____._.... _...._.__ 14.00 .._.__._._ None

.____._ ...._...__.... None

. ...._......._. None

....._.._.. None

_._......_..__..._ None

.._.._... None

_____... None

_._..._.__ None None .._.._.___ None

__.____. None

..__.._.._ EUG 5- Trim None None None Nune None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMIS5tON: (1) The Scrubber was shut down to ciean the nonles. PROCESSES AND EQUIPMENT INVOLVED: (1) SVet Scrubber tf2 CORRECTIVE MEASURES TAKEN: (1) Cleaned nonks and ehecked Dow• lines, restarted the scrubber.
ADDITIONAL INFORMATION*: The wet Scrubber was mamtamed and operated aeeurding to the manutacture's instructiuns. The repa'vs and malntenance were done as quleklp as possOtie, utOb3ng overtime if needed. 1 eertify, based on information and be6ef formed after reasonabie mquiry, the statements and information in thls document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Receivr.d: Received By: Demonstration of Cause Submitted: ON~ 

# 0 I I I AGENCY USE ONLY DateSubmitted: TrackingNumber: Team ID: * lf you wish to notify the DEQ about a technological limitation, do so here and attach supponing infotmation. DEQ-Fonn #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM 'OTE: The information requested below should be submitted to the address above within 10 working days after the imntediate notice is giaen. If you are using this fortn to correct a previous 

### rep ort, provide only the corrected information below. sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANY Nr1ME:

I 1/13t2009 Dal-ItaBa NAME OF INDIVIDUAL REPORTFNG: TITLE: PHONE: Rick \V"dliams Plant Manager (918) 6834043 FACILITY: COUNTY: PERM1FIT NUM1IBER: DaLltalia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 1I/12n009 8:00 8:30 0:30 Hours:Min Phasel

0:00 0:00 0:00 Hours:Min Phase2 DURATION OF EXCESS EM1FISSION (HOURS:MINUTES): 0:30 Hours:MinutesofWetScrubberpowntime APPLICABLE L1MtTATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Speeific CondBiun 1, EUG 5 ESTIMATF.D EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X .__ _..__ .

.. . ..._..__ SOURCEGRP IIF F1CL SO i CO VOC NOx PM EttG 1

.... .._.._ ____....... ..__..._. .. __.. _... ..._. _.___.._ . _._.._ ........ _ _

.. I:I.G2 ...___ .._._..... .__._.__. .. .......__. ._.___ _......... _._____...._ . .__._ _......_.. _......_.._ "

~~~~~ - ~~ ContFmissionsMoniloring

. -._...._ ._......_. ..__.__..... _._..___. iId:3SDl ...___ 036 . _ 0.00

. -_. 0.15

. _ . . _5.83 201 3.63

_ ... FsgineeringCalcutation X

._..___. __...__- ....._. _..__ _.._ _ C1 G3S0?

.... . 030

_.._. . ._..... 000

.. 0.00

..__.. 657

__ .._ IOI

...__._... 1.83_

214

~ . . _ 2.81 ~ --. Operatingt.ogs X

...__ _ _ F.UC a VDct ._..... 0.03

.. . 0.00_

.- 0.00

........._. . . ... 6.37

_._ _ O80

._...... .........._. 1 25

,.., . .....__... 2.76

_.... .... . _ Oihci Icaplam)

._._._.... . ... __ _ _. _ _ ....... .... .. _ _ . _ .. fa

~ G 4 VDst

.. _._.... 0.01
___ 0.00

.. _ ...__.. 0.00

..... 3.55

. OAS 0.69

. .._._..__ I.44

._... .._.___. ....__._ ..__...,_.._ .. ..._...... . .............. EUGS- R'St

.. .__._. 3.40

. _ ...._.. 4.04_

_. 11.18

. .. .. _

- 7.36

...... 2.18

.__. . 2.89

..... ... 3.76

.._ .... ...._.... .....__.._ . ..._..._.__ .____._._. ..._....._ EUG 5- WS2 11 - ~ 0.00 0.01 0.02 "" t3.61 2.28 4.38 " 4.00 S-Trimt.38

~ . 7.76

~ - "~~~" ~~~ 3.9t 2.74 0.76 - (.07 0.82 .___..._ _...._.. __.._.._ _.__... ._......... Attach supporting data ALLO\VED EMISSIONS: SOURCE GRP IiF HCL SOt CO VOC NOx PM Et1G I ._. _.. ._. ....__. _.__ ... . ..._._ _. . ___...._._ .. ..._....... ._. ._.__ ... _...__.... ...____ _......___.._. ._._. EUG 2 ...__ ... ._ . _ .. . _ __ __ .._...__.. ..____ ._._... . . _ ..___ ... ....__._... . ..__... .. ..__..__ _...._. EUG3SD1

_ . n.59 0.t0 0.45 ._...__... 13.77

.__.... 9.67 __..._-_. 3.88 .._....__.. 7.98

_........ ._....... LCG 3 tiD ~ _ - 0.? ~ _._...._ 0.90 _...__.._. O.

~ IS t3.77

..... _....__

9.67 ......._._ .... 1.88

.. ........ 7.98

.__._._..._...._._...

_ EUG4\'Dsl 0.72

. .._..._.. 0.08

.__......_. 0.18

......_.__.._. IIA3

..___._. ...._._.._ 38.33 ._____._.. 3.5i

. ._.__..... 5.85

_..___.___..._...__ El'GJ\'Ds2

.. ._. .. 0.52

...____ . 0.06

_....__ . .._...... 0.08

. 5.09 ,.....__... .. _... 17.04

.._ __.._ .._._ 1.56

......._ 2.60

__...__.__...____._ F.UCS-\\;S1 IA3

_ . .............. 1.60 8.96 _...._..._ . t9.60

_........ _.....__.... 4.78

_..._ ._..._.. 7.73

.......... 6.71

_..___......___.-__. EUGS-\\52 .__..... . lA3

_ ..... .............. . 1.60

_.....,....._ 8.96

___.._.._._.. t9.60

._..__. ... 4.78

.___ ..._._.......... 7.73

. _.....__..__. 6.7t

._ ...___..-.........._._... EUGS-Trim 3.57 3 .8 8 9.68 6.75 3.67 2.00 1.80 EXCESS EMFSSIONS: based on I hour runits EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG t ____._... ...........__ .._._...__.... _..._____..... . ...__... ...._ .._.._ _ .__.__..._. . _.._ .._.__. None _. __.. . .. .._._._.. . _......._..... . _..__. _._. .. .._...._._.. -___...... None ...._._.. _. ._._...... . .._ ... . ._..____ .......__.. . . -.. . ._. .. ..... _.__.. _..__..__.. ~ None

. . ........._ ._....._. ...._. .._ . _ _.....__ . ...-... _. None

_ -.__.. Ef1G i SDI ..._...._.

None ..___._.. - None

..__......._.. None

_ .._._.._.. . None

_._.-.._.._ ..........._ None

.... ........... None

-.__....._.._. \one

___...._.._ . None

.. . Nono

.. _.__..._.. None None

..__...___.. _.. None

_..._._. None

. ..__.....__ None

.._....

. EI!C:3

~ D? Vone

_ .............. None__

. _ . ... None

..__._. . None ~ _ .- . .. ....__ None

_....... ... .._.._... None ....._.__... .. None

_. ._..._._ __. None

_....._ None

.__._._ None

_ .._ None_

....... None

.__.__..._ . None

._....... \une

... _.. ._ fa'(:J l'I1s1 None

...._.._..... ... None

_.......__. None

. _....._.. _ None \one ._.__. __ ..._...._ None

. .... None

... _ None

_.. ,... None

....__.._.. None

.. None

.. . .. None

. None

. _. None

.. . ._.._.. EUG4 \ Uc2

. Vone ,.___... ......_ None _.._..._... Nono

..... . .._ ........ ..._...

__None _... . ..__.__ None .....___.._ None

..__........ None

...__....._ . None

..... None None

. _...._ ........ None

....... None

..... None

... Nune EUCS-

~~ til

. . . 197 2.44 _......_ - 2.22 .._._. . " None

.. ._ \one

.._.___. None

._____... None

. ... None

. _ .... None

..._._..._ None _. . None

_.... _... Nonr

_........ '`'unc Nnne __.._. EUG 5-\\S2 N 

### one N one
... _ None

___..... None

.._.... .._ . None

__._... ___.._.._.. None

. ....._. ~ None

_.._......_ . None

. ..... None

....__... None

.-.._. None _.._ _.. None

_......_.. . None

. .._.._... _ None

...___. EUG

~ -"Crun Vone None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (1) The Scrubber was shut down to check nordes, pumps, and to inspect sludge on water. PROCESSES AND EQUIPMENT tNVOLVED: (1) Wet Scrubber k t CORRECTIVE MEASURES TAKEN: (1) Made sure the noriks were workmg properly to get good water tbw and prevent overheatmg.
ADDITIONAL INFORMATION*: The \Vet Scrubber was maintamed and operated accord'mg to the manufacture's instructions. Tbc repairs and maintenance were done as quicklv as possible, utilbing overtlnte if needed. 1 certify, based on information and be0ef formed after reasonable mquiry, the statements and in(ormation m this document are true, accurate and compkte

StGNATURE OF REPORTING PERSON

Date Reccived: Receivcd By: t.kmonstration of Cause Submitted: = yo AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: * If you svish to notify the DEQ about a technological litnitation, do so here and attaeh supporting infonnation. DEQ-Form #100-920 Revised February 8, 2008

# O K L A H O M A DEPARTMENT OF ENVIRONMENTAL QUALfTY AIR QUALH'Y DIVISION PO 80X 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM NOTE: 'Slre infomtation requested below should be submitted to the addmss above within 10 working days aRer the immediate notice is given. if you are using this form to cotrect a prevdous eport, provide only the corrected information below. sign the cenification, and attach a copy of the previous report.
REPORT DATE: COMPANYNAME:

11113f1009 Dal-Italia NAMEOFINDIVIDUALREPORTING: TITLE: PHONE: Rick \Vdliams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Itatia Muskogee 2004-198-TV (M-I) DATE AND TDNE OF EXCESS EMISSION: Date Start Tinte: Stop Time: Duration: 11l1272009 0:00 0:00 0:00 Hours:Min Phase 1



### 11:00 12:00 1:00 Hours:Min Phase2 DURATION OF EXCESS EMtSStON (HOURS.MINUTES): 1:00 Hours:lFlinutes of Wet Scrubber powntittte APPLICA6LE L1MITATION(S) OR REQUFREMENT(S) EXCEEDED: Permft No. 2004-198-TV (M-1): Specifie Condition 1, EUG 5 ESTIMATED EMISSIONS: RASIS OF ESTIMATE ComplianceTesting X

. ._..._.. ..___.-. .__.._. ___.... ........__ SOURCE GRP HF HCL SO t CO VOC NOx PM EUG I ._._ ..._ . _....... . _.._... _ ...._._. . .__ . ....._._. ...... -._ ____..-_.. ._._._. _.._._.__. . EUG 2 .__. . .___.. _._....._. _ .._...-._... ._..___. . . ._..__.. ................ ._...._. _.. __ Cont Emissions Monitoring _...._. ...___. ...._._. ...__...._.... .._.._._,_ EU(l3SDI 0.36

---- ,..._...._.. 0.00

_._..__._. 0.t5

._...__.._ 5.83

__......_ . ._._ 2.01

__.. ......_....._.-. t.83

..._._. 3.63

_._._..... . EnBinaeringCalcvlation X

........... ..__... .._.._..__. ____._. _

. I'U(; 7 SD2

_ ..__.... 0.30 0.00 .__..__._... 0.00

_._...__.. 6.57

._._.._... __.......... 1.0t

_... . ..... _... 2.t4

. ........... 2.81

..-.....-_. .._ Operating Logs X

.._....._ ..._.._... _._.._ .__......___. _ . ___...... Ct

~ Ga\'Ds1 0.03 _ ._._ 0.00

_ _ 0.00

... ... _ 6.37

._..__.. . 0.8o __..._._... L25_

. ..... 2.76

.___ _ .... Other(explain)

......... _..__... ..._ .__. ..._.__.... . _..._-_._ CI:(74 VDs2

.. . -._.._ 0.01
. ...... ~ 0.00

. 0.00 3.55 ._. 0.45 _._. . . _ 0.69

. . .. . 1.94

. _ ._ EUG5-RS1 ....._.._ . 0.02 ...._..

. 032

...._._._. 0.37

.. ... 14.70

___ _._......_.. 0.95

_ _..-..._. 5.00 ~~~~~

._...._-. - ~~~~~~ 2.97

_.. .. _...__._. ...__._...... ..._..__ ....__. ____..__.. EDG 9\cti2

... . 5.79.. _....._

..___. ._._._ - 6.89

... . . _. 19.07

. .. 12.55

.. . 3.72 4.94

. . ...___.. 6.41

. ...._ . .. _ _. ._._...__ __...__. . ......___._. EUG5-Trim 1.38 1.76 3.91 2.74 0.76 1 1.07 1 0.82 Attach supporttng data ALLOWED EMISSIONS: SOURCEGRP HF HCL SO, CO VOC NOx PM EUG t _.._.__. _....._ .. ._...__. _. .._.._.... ..._._._ . . ___...... ..__ _..._.... _......_._ ._._....._._. .......___ ..___. EUG 2 ._...... ...._......_.._ .__._.._... _._._..... . . .._._._. EUG3SD1

......... .._. 0.59

_.._._ ....._. 0.10

.._._.__... OAS

. _______. 13.77

__.... ._ 9.67

_._... ._.........._.. 3.88

_... 7.98 EUG 3 SD2 ..._..._._ .._.. 0.95

.... _ 0.90 0.45 13.77 9.67 3.88 7.98 ..... _..... EUG 4V'Dsl _..._.. .._. 0.72

.. . ..-.__.. 0.08

_ .__........... 0.18

..__-.__ ._ 11.43

....... .__.__ . _. 38.33

.. ........_..... 3.5 1

_._...___.._ 5.85

___......__ ..._..._ EUG 4\'Ds2

.... __ ._ 0.52 __....__ 0.06 _. . ._._._._..... 0.08

.__._ _ 5.09 ___...._.... 17.04

.._......_.__... 1.56

._-....._.. .. 2.60

_.._..._ . _..- ...._ EUGS-\\:SI

...... .... __ IA3 .._..._._... L60 _. ......__._.._ 8.96

_-..__.._. . 19.60

_..____... ... __........ 4.78

.. ___._._.... 7.73 6.7 1 _...__.._..._.._.._. EUG5-\C42 ..._... . ._._ ._ 2.85

.__.... . ...._...__ 3.20

.. . ...______.. 17.92

..__._.__. _ . 39.20

__-_._..._. , 9.56

. .. _ ........_. I5.ai

. ......__. 13.42

._.. -....-__._.._........ EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS Eb1tSStONS: (based on 1 hour BmHs) EXCESS EMISStONS: 24-Hr Totals SOURCEGRP HF tiCl SO r CO VOC NOx Phi HF HCI SOs CO VOC NOx PM EUG 1 ..__.._-...... .-. _____..__ _._..._ _. ...__..._._ . . . ............. _ ._._ . ._..._... ._.._.._. .. . _._.......... ....._._..._.. _ . None

.. _. ._........ . _._ .__....... _ _. _ .._..__ ___....__ ,.. _ _.._._... . .__._..-.... None

.. ..-._......_ EUG 2 _..._ .. . . ......... ....... __ ._. ..........__.... ._...___..._.. _ ..__...___ .. _...... ._.... ...._._........ ._._._..- None .._..._..._.. _.. . _ _ ..._.._. _ ...__.__..._ _._....__ ._._ . . _ .._.._._. . _..._..._.... None .._..-......__. EUC 3 SDI

. None

.._ . .__.. None

... ....._._.__ None None

...... . ........___. None

. _..-..._..__. None

._.._._._-.._ None

_..__._._... _. .... None

.._.__._ None

_...._...__... None

_ , .._... None _._.._ _ .. None

..__._ . Nono

... ..-._._.._.... None

.-.-......_-.. F:fiG 3 SU2

_ None

........ ..... _._ .. None ._ ... ......__..... ...__._..._

None

.... . .____.._ _ Nane

.__.._.... . ... ..._ None

...__. ...._.....__.. None

.._...__....._ None

_ _.._.__._ None

. . \one ..,.. ..._... ~ onc
_ None

... .. . None ..___.... None

.....-..._-_. None

.. .....-.......-.. EUG 4 VDst None

......... .......... None

.. ............... None

.___..__. __. None

_............ . _._._ None

_...._ . .__._..-_... None

. .._..........._ None

.....-...-....._. ._....._......_

None None _. ._.-....... None

.__. ....__ None None __.._..._.__. None

.....__.... None -..__.__.. EUG 4 VDs2

... ...__.. Nune None None None

. ___-.. None _.__ . . . ..... ....._.... None

__ . _._.....-.. . None

.. _.__..._._. _. _ .. None

.. _....._ . . None

._.___...._ None

. . _. ..... None .._. .. .. _ None _._._._ None

.._..__._ None

. _.-....... _.... EI?G S-\{:til None None None None No ----- .. ... .._....___. _. ._._...... ._..._._.._ .__.__ . ......__.._ ._..___.. ._....._.._ EUG 5-AA'S2

_ ....._...__ ..__..._. 2.94 .._..._...._.. 3.69 .._.__._.._.. 1.15

...-.-__..._. None

....____. .. ._. None

...._ .. ..... ............. None

..._...._....._ None

..-....__._.._ .-..._._._..

None

.. None ...__.__... None

. . __..._..._.

None _.. _._ None _._... None

_....__.__. None ._-...-._._... EUG 5- Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMtSS10N: (1) The Scrubber w•as shut down tu check noriJes, pumps, and to inspect sludge on water. PROCESSES AND EQUIPMENT INVOLVED: (1) \Vet Scrubber # 1 CORRECTIVE MEASURES TAKEN: (t) Made sure the nor

~ les were working properly to get good water pow and prevent overheating.
ADDITIONAL INFORMATION * : The Wet Scrubber was mamtained and operated aecord'mg to the manufaeture's Instructions. The repairs and maintenance were done as qukkly as possible, utilPring overtime if needed. I certify, based on mformation and betief formed after reasonable mquiry, the statements and intormation in this docnment are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Reeeived By: Demonstration ofCause Submitted: O No AGEiVCY TJSE /)NL,Y Tracking Number: Team ID: Date Submitted: * If you wish to notify the DEQ about a teehnological limitation, do so here and attaeh supporting information. DEQ-Form #100-920 Revised February 8, 2008

## O K l. A H O M A DEPARTMENT OF ENVIRONMENTAL QUALlTY AIR QUALITY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM = OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. If you are using this fomi to cotrect a previous port, provide only the corrected information below, sign the certification, and attach a eopy of the ptevious report.
REPORT DATE: COMPANY NAM E:

11/20/2009 DaI-ltalia NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rkk wi0iams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Itatia Muskogee 2004-198-TV (M-i) DATE AND TIME OF EXCESS EMISSION: Date StartTime: StopTime: Duration: 11/17/2009 0:00 0:00 0:00 Hours:Min Phase 1

7:00 12:00 5:00 Haurs:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 5:00 Hours:MinutesofR'etScrubberpowntime APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permit No. 2004-198-TV (M-1): Specific Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X _....__. _.._..__.. ._.___._ ....... .. ....._...__.. . SOURCEGRP HF HCL SO z CO vOC NOx PM EUG I .._.. _._. _ ... __._._. . ... ._.___ . .._.__._ . __.._... . _ _._... _...___..... __....._._. ___...... ._. F'OG 2 ____.___ . .._.._,_._. .._._....__ .... __._ ........._._. .__...... ....__....... Cont Fmissions Monitoring

_.. .__._._ ............. ........_.._ ._.._.._._.. ..._._.____ _..__... __. ._....._.. _.._.__.. .....__.... .. ......_.... .. _.._......... . _..__.._ .._......_ .tion X .___.... . ._._.._...... .._..._ _____.. ......._._.-. b:t'(:?SD2 O.16

. .__ ..... 0.00

....._..__. 0.00

.._...__. . . 3.52

_...__. . .__ O.St ..._..... 1.15

. ._.....__ . 1.50 OperatingLogs X

.__._...__. __...... ...._.._... ICGd

~ DSI 0.03

. ...__. 0.00

_ _........ 0.00

_ . 6.93
_ _ 0.87 1.36

.... . __... 3.01

_....__ .. . Othcr(

~ plain) _...._. . _._._. EI'G J VDs2 0.01

....__.. . . 0.00

. ....__... 0.00

.. _ 3.48 O.aJ 0.68

. _ .._... 1.51

_ ....__._ ....__.... ..._..._._. .......... ........... F.UGS-\\SI

.. .. . 0.02

_. _... 0.32

.. . ._._... 0.38

.. . t4.9t

_.._ . 0.97 __......_ 5,07

~ 3.02

. . - ...... ........ .. . __._._.. EUG 5- \\ S? - 23.89

._.__ . . ..__._

28.44

.... __...._.. 78.68

_ _ _ . 51.77

...._._ . . 15.36

. . - __.

20.37 _...._.. ..._ . .... ..____ . . __..._. . ._._. . _....... _..__... EUG 5- Irim 1.41 1.81 1 4.02 2.82 0.78 1.10 0.84 Attach supporting data ALL01iBD EMISSIONS: SOURCE GRP HF HCL SOi CO VOC NOx Ph1 FUC 1

. _ .._._.._.. _.._._... _.. ___,.._ .. ._.__..._._ _..... __ .. ._._.. _.._.._.._. ..___._._. .....__..._. ._ . __.... EUG 2 .._...___._ ._......_ ........_. .._ .__._...... ____.._ . _...__ . ..... .___. ___....___.. ....._..... . .__...._. _ ._..____. EUC3SD1

. __.___ . 0.59

.___. __...._. O.IO

._. ........... 0.45

......_.... ... t3.77

. ........_ 4.67

.__...____. 3.88

_........... 7.98

......_.. _._..._. EUG3SD2

. ._....._._ . 0.95

___. _ _._.._ 0.90

_.... ......._._._ ... 0.45

....... .. .. 13.77

............ .._... 9.67

...... ........._ 3.88

__.__._.. 7.98

.._...._.............._.. EUG4 VDst . _______. _ 0.72

.. _... ...__....... 0.08

._ .. .... ........_.. . 0.18

_.__._.. _ ... 1t.43

..____. 38.33

..._._........_ 3.51

. ......_.__ 5.85

.._.__.___...._._..._. EUG 4 VDe2

.......... 0.52 .__ ........ 0.06

. ...._...._. 0.08

_..._._... 5.09

___._... ...___ 17.04

._..... .._..___ 1.56

. . _._.__..._ 2.60

._...._.__........_.._. EUG5-}VSl 1.43 1.60

. __....... 8.96

.....__..._. 19.60

..____. _.__.__.... 4.78

.____......_ 7.73

.. _. __ ....___ .. 6.71

__._...._....._...._- EUCS-R'S2 ......._ .._.___. 8.56

. .___.__.. 9.60

. ..... _ __. 53.77

...__._ 117.60

._.__._ __ 28.68

.........._ _ _.... _.__.. 46.36

.. _..._.._... 40.26

.. __._.._-.._._...__ EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: based on I hour Iimhs EXCESS EMISSiONS: 24-Hr Totats SOURCE GRP HF IiCi SO z CO VOC NOx PM HF HCI S% CO VOC NOx PM EUG I

........ ___.... ____..__ .._ . .......... ....... ._.... _.._....._. ..__ .._.._

. . None ...._._._. _ None .__. EUC 2 . _.._._.. __..__.. _...__,.._ __ .___......._.. ._ ...... ....... .. _ _...__. ._._... . _...___.. . .......___.. _ . None _ ._._._._. . _.. _....__._ . _.._.__.. . . ___ __ . ... ............ .._._..._.. None

........... _.... EUG 3 SDi ......_... ...._.__. None

__...__... None ._... ....._....._. None

.._._....... . \nnr None _....._... __..._..__.. None

. ...._..___' None

____._... __ .... None None

.......... ..........._..... None

. ...._...__

None None

.......... None _..._...._.. None

......._.... EUG3SD2

........... ...._.._....

None _....__ None \unc None None ._.._.__.._ None

_ . . .____...-. ..._ None

_._...... None None None None None ._.._..._._ . None

._.....__... None

._..._.... EUG4 VDsi ._...... ._. ... None

._.._..._ .........__ None

._ . ._._._...._. N'one

.......... _ None

_...._._.._. _._ None None

___.. . ... None None

.... None _,. . .._..._ None

. _ None ._. None

..._....._ . None

. _._.___. None

... ___._ EUG4 VDs2 ........._. .......__._.

None _..._._.__. None

.._..._....._. None

. _.. _.._ None

.__...... _. None

__._... -- None None None ..._...._.... None

_..__.._.. Snne

_ .__ .... None

. . . ... None ........_ None

.._._.._. None ..._....__.. EUG 5- WSI ......._.. None

._._.... ...._._._... None

. .............. Nonc None None ..__..__ ._..___.._....._..---._.. None ...._.__..-_ _._._..._._..

None None ...._-_ .__._....-__._...._

Nnnr

. A'nnc None

._.__._._.....__..

None Nune

_....... None

.____.. EUG 5- N VS2

.. .. _ ......._. 1533

._ _... I8.84

..........__ 24.91

.. ........... None

..... _... _..___.. None

. ..._......__.. None

_..__._..__ None

._._. __.. None

_......__ . None

..-__._.. iyone

. _... None .._.. None _____. None

__..... None ._._.._. EUG 5-Trim None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut duwn to ekan the nonles, remoce sludge front tank, elean impenger ftlters, and replace Impenger pipe. PROCESSES AND EQU[Pp1ENT INVOLVED: (2) wet Scrubber 42 CORRECTIVE MEASURESTAKEN: (2) TBe nozdes were ekaned, removed sludge from water tank and inipenger pit, ekaned impenger fdters, and replaced impenger pipe.
ADD7TIONAL tNFORMAT10N V `: Tbe wet Scrubber was mamtained and operated according to tbe manufacture's mstructions. The repairs and mafntenance were done as qnkkly as possOtle, utilidng overtime if needed. 1 certify, based on information and be8ef formed aRer reasonable inquirp, the statements and bmformation m this document are true, accurate and compkte

SIGNATURE OF REPORTING PERSON

Date Received: Receivcd By: Demonsnation of Cause Submitted: O No F - D ( I I AGENCY USE ONLY TrackingNumber: Team ID: DateSubmitted: * If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEO-Form #100-920 Revised February 8, 2008

# OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. lf you are using this form to correct a previous repon, pro4ide only the corrected information belo\e, sign the certification, and attach a copy of the previous report.
REPORT DATE: COMPANY NAME:

11f20/2009 DaI-itaua NAME OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick RiOiams P4xnt Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: DaHtaiGa Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 11l18/2009 0:00 0:00 0:00 Hours:Min Phase 1

16:25 16:45 0:20 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 

### 0:20 Hours:MinutesofWetScrubberpowntinte APPLtCABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: Permh No.2004-198-TV (A1-1): Specific CondBion 1, EUG 5 ESTIMATED EMISSIONS: BAS(S OF ESTIMATE ComplianceTesting ._.._.. . . _._.._._ . __.__.__ _ ..._.... ......... X SOURCE GRP lIF HCL SO. CO VOC NOx PM

. EI!C I ._._... __._..._.. .. ___..._..__ ............_ .___._. .____. ___.. ._ _..... _.__ ._..__... _._._._.... .__ C IIG 2 '

. .___._. ........_ ._-_ __._.._. _.__.__ __._.._. ...... _._. ._.__.__... ._.........- ____.__ . Cont Fmissions Monitoring ._..__ .__..__. ._.._.._._ _._.._._ ......._. X , F:UG3 b D1 ..._._.. 0
~ 5

. . . ...._... 0.00

_ _._.__._... 0.15

. ..___... __ . _ . _ . ,.._563

. _._ 1 94 ....._. ,.,..._..._ . _ 177

. . .. ......... 3. 51

.. . EngineeringCalculation

__.. .._...._ ..__......._ ._.........

_ EI:G.3 SD? ..._ . O.t7

.. .._ _._.- _ 0.00

..._._.___ 0.00

.. ......__.._. 69

._ ..... , 3

. . ... 0.57

. . t.20

......._... 1.58 Logs

._...__..... .. Operating _.__....... ..._. _._..... X EUG4\

~ Dsl 0.03

.. .__._. 0.00

. 0.00

... 6.02

.. __ 0.76

_ ... . .........._ 1.18 2.61

. _ Otha(explain)

_........ ........_._ . ._.._. ....._..__..... ._...__... EUG4\

~ Ds? _. 0.0t

... ._. . . _.__._ 0.00 ...__

... .. 

## __. 0.00

.. . 

## ._..__.. 3.49

......... _ _ 0.

~ 44

._._ .. 0.68
.... ._.. 

## .__. 1.51

...._ _ ..___... __.._.__ ._.._... ._._._..._. . _.. .... EUG5-\\

~ SI ._.. .. 0.02

._..._.. 0.32

..__....._. 0.37 14.81 0.96 ...._.. _ . .. 5.03

..... . . . 3.00

. .. ... ._._ ._....__ _.......... .._..___._.. .. ......_.__ .. ........._..._ EUGS-WS2 _... ... ....__. 2.03
. . 2A1

. 6.68

... 439

. _ _ 1.30 _._. _._._._. L73

._ 2.25

....__..._. ._. ......_. ._...... ..__.___ ____... EUG5-Trim 1 1.09 ~ 1.39 ~ 3.10 2.18 1 0.60 0.85 0.65 _....__ _..__... . _...__.._ .__.._.___ _._.._._.. ALL09VEDEMISSIONS: Attach supporting data SOURCE GRP HF HCL SO i CO VOC NOx PM EIIG I . _. . .__.__ _._.__... ... _ ....._._ __._ _._.__... . ._._..__ __. .... ...... __........ .___..__ . __._._..... _._.._._. I(C(' 2 ' ..__.. _..___._.... ._......_.__ _._._..____ . ..._.._.. _.._...._. ._..._......_... __..__ ..._. .....___ _. ._.__._. EI'G3SD1

. .. 0.59

.__.._ _.__._. 0.to

.._...__.... 0.45

__._.___.... t3.77 9.67

.._..__. .._........._._...._..._. 3.88 .._..__...... 7.98

._.__...... ._...._. EI'C 3 SD2 .._..._._ 0.95

___._..._.. 0.90

... ._......._.,.... 0.45

..___..._.._ t3.77

......._.. ._....._ 9.67

...................... 3.88

. .._._.._ 7.95

..__...._.._.__._...

_ EI G 4\ Dst 0.72

.___..... __.....__ 0.08

.... ___._.__... 0 . 1 8

. ._..._.._ 11.43

..__.__... .._..._... 38.33

. 3.5t

......_._._ 5.85

..._._._ ._...__._. El I G4VUs:

. ._...__.,

0.52 .__.._. 0.06

....._._...._.. 0.08

. .._........ 5.09

._ . __......._.. 17.04

. ........_.__.. 1.56

._..__._.. 2.60

_...__..._._..___. LUG

~ -\\tit .._ .. ...__._ 1.43 1.60 _..___....... 8.96

..._._._...._.. 19.60 4.78

__......_.. . ._...__..........__...... 7.73 ......_._....... 6.71

..__...___._._.__._.._ EUG

~ -\\S2

......... _...._... IA3

_ L60

_ .._.__.__ .. 8.96

............._ ._._ 19.60

...... 4.78 .__. ._...._....... 7.73

__.__.... 6.71

._..._.__. EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on 1 hour Gmits) EXCESS EMISSIONS: 24-Hr Totals SOURCEGRPI HF HCI SO i CO VOC NOx PM HF HCI SO i CO VOC NOx PM EUG 1

......... ........... __..._......_ . . .--- ___...._ ._ ._...... ._._.__ . _.._._. .__.. ..._._.._.... _._____ . None

_ ..._._ . _ .._._.... ......._.___. .... _ ........ .... .._... __._.__ .......... None __........._... EUG 2

. __.... . . ....___ . ............_. .. _ _ .___._.__ .__........ _.._._... ......_ _.___....... .......... .....___._._ - None ----._._..__ . ....__.._... _ _ _ ___.._. ..____._... . .... .__........ ._,..___.. None .............._. EUG SDI 

### 3 None None None None None None None N - . ._. __._..__. . _.._.__ .._.. . _ _ _._.. _............. . . G 3 SD2 None

........._....... __....._ None

._ __.._..__ None

....._......__. None

_....__. . ....__. None

___.. _ ._._._..__. None

..._ ....... None ..........__... ...__ None

._..__. Nune

___ None .................._

None

.. _ None

... ___.. None

. _.....__.... None

.__... EtiG 4 VDst

... ._ None ..._...._ None .._ .__.___ None

....._. .. . None

._____... ._.._.. None

_.._. . . _..._....... None

....._..._... None

......_.. ... None

..... None

.. _....__.. None

...___ None _..... _..... None

..._.__. .. _None

....... None

...__. EUG 4 VDs2

. .. None

_._..__ ._..__.___ Nono

.. __._._ ......... None

....___,._. None

.._._._.. ..__._..._..........._.

None _.._ None

.._...._.__ None

_............_.. _. None

......... None

..__..._ None

. _..._._.._ None None

_ ._.._.._.._. _ None

__......_.. None

..._._- ICC(.7 5-

~~ :til

_ _ .. None

..._...._. _ ...__._... None

.... .. _...____... None

.. .._.....__.. None

.._ _.... ..... _._. None

._.._. _. _ ........_. None

. _ ._ _... ...._.. None

._.......- None

._........ None

..._......_.. None

._.__._ None ..__ . ....- None -__..._. . None

. .._ _ _._.__. None

. .____........ EUG 5-
~~ 52

. ... 0.60 ..___ ._____.._ 0.81

_.. ..._....... None None .__ None ...__. _.... None None ....___...._.. .. None

......._. None

..____.._.. None

....._ None ._._ _ ._ None .__..__. . None

.___...__ None ...._.____.._ EUG 5- Trim None None None None None None I None None None None None None None None NATURE AND CAUSE OF BXCESS EMISSION: (2) The scrubber w•as shut down due to a malfunetion of the PH probe.
PROCESSES AND EQUIPMENT INVOLVED: (2) Wet Scrubber #2 CORRECTIVE DIEASURES TAKEN: (2) The Pli probe was repiaced and the scrubber w•as restarted.
ADDITIONAL INFORMATION * : The ii'et Scrubber w•as mamtained and operated according to the manufacture's mstructions. The repairs and mairrtenance were done as quickly as possOrle, uti(bing overtime if needed. 1 certify, based on information and be&f formed after reasonable inquiry, the statements and Information br this document are true, accurate and complete

SIGNATURE OF REPORTING PERSON

Date Received: Received By: Demonstration of Cause Submitted: 

### AGENCY USE ONLY = No DateSubmitted: TrackingNumber: Team ID:

' s If you wish to notify the DEQ about a technological limitation, do so here and attach supporting information. DEQ-Form #100-920 Revised February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DNISION PO BOX 1677 OKLAHOMA CIrY, OK 73101-1677 

# EXCESS EMISSION FORM . OTE: The information requested below should be submitted to the addmss above xvithin 10 worl:ing days after the immediate notice is given. If you are using this fomi to correct a previous eport, provide only the cotrected information below, sign the certifieation, and attach a copy of the preFious report.
REPORT DATE: COMPANY NAME:

11I2012009 Dal-Italia NAMEOFINDIVtDUALREPORTING: TITLE: PtIONE: RickR 1 4tiams Plant Manager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Dal-Italia Muskogee 2004-198-TV (M-1) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 11/19l2009 0:00 0:00 0:00 Hours:Min Phase 1

12:04 12:32 0:28 Hours:Min Phase2 Dl1RATtON OF EXC,ESS EMISSION (HOURS:MINUTES): 0:28 Hours:Minutes of Wet Scrubber powntinte APPLICABLE LIMITATtON(S) OR REQUIREMENT(S) EXCEEDED: Permtt No.2004-198-TV (M-1): Specific CondBion 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTesting X _....._. ._.___ . . ___._. ...._.__._.. . SOURCE GRP HF tfCL SO i CO VOC NOx PM EUG t ..__... __ ..._._._. .._._._. .. ._..__ .... ........._._.. ...._.._. _.._ ._.. _ _...._..__ _ -_._.__... . ....._._..... ......_ EUG 2 .__ ....._ . . .. _.. ...._.____.._ . _.__. ........__.... .....__ ....... .........._... ..._..._.....__ .__._.__.... _ __.__...._._ . . _ Cont Enissions Monitoring ..__..._ . ..._._..__.. ____..... . .....__..._._ . _..._._ EUG3SD1 ..__ 0.39

._...... _.__._. 0.00

........_ 0.17

._..._.___ .. 6.25

__._._...... ___...... 2.16 .___.__... 1.96 3.90 ..___.. ..._._.___ EngineeringCaleulation X ._.__.._. . __.... ___.__... .......... EGf: 3 SD2

...... .. 0.15

_... ._._... 0.00

.......__._ 0.00

. ___.._... . 3.34

._.._.__ .. __...... 0.51

......_.__.._ L09

. _.._._._._. 1.43

...__._._.... _._ Operating I-ogs X

___.... .___._._. .. -___.... ... .__.._.... . __._... F.C(:4\'Dsl 0.03 ..___. ... . 0.00 .__.._. 0.00

. .. _ . 6.14 ._. 0.77

_ _... .. L20

_._.. _.. . 2.66

...__.... _ .. .. Other(rxplain) .__.__._. ......._ .._.__ _......_. I:GC 4\'Ds2 0.0( _. _ 0.00

...... ... . .... 0.00

... . _ .. _._ . _ ~~~~~ - ~~~~~ - 3.56

... _._._.. .... ~~ . 0.45
. ~~

_..... _.._...._ 0.70

.. ...._.. 1.54

_ El

~ `GS-

~ \.tit

.... _ 0.02 0.34

.. .._..._. 0.39

_ _. .. .. . ISA7

._.__.. _... L00 5.26 3.13

. __.. . _. _ . ._ _.___... . .___... __.._ ......_. _, ._..._... EUG5-

~ AS2

. . .. . 2.69 3.21 _. . . _....._. _8.57 5.83 .....__. t.73

..._ _ _._.._.. 2.30 2,98 ._... _.____ . . . __...... . _..__ . _..___. .._... _ EUG ... . 1.26 3.58 ~~~~ ~~ ~ 2.51 0.69 0.98 0.75 Attach supporting data ALLOWED EM78SIONS: SOURCE GRP HF I{CL 80 i CO VOC NOx PM E1tG I _... _ ...._._. ._. _..._ . _____.__._ __.._... . ... .._.__._ _ ._,_... . _____. . _._...._ .._._... _.._...... 

### EUC2 EUG3SDl

. - 0.59

_ . _. 0.10

._ . .__. _ 0.J5 13.77 _.__. . _. .___ 9.67

...__ _ ........._. 3.88

.. ........ 7.98 _.._.. F'G3SD2 ._. . - ~- ~~~ 0.95

...._.._ _.. _ 0.90

_ . . .....__. OA5

__..___.... 1377

._... ____. .__.. 9.67

.._._ ___._._... 3.88

.........__ 7.98

_ ............._ _ .. __.... I:t - G a

~ Dsl

. ..__...... 0.72 0.08 ..._._.... 0.18

__._..._. ..._..__._._

11.43 38.33 ........._. ....._..__ 3.51 .._....__ 5.85

_.._.._.__._.____.... IC l ~ G 4\'Ds2 0.52

_..._._ _..__...... 0.06 _....._.... 0.08

_..._._...__. 5.09

._.....__.... ._..._.... 17.04

____.._...... 1.56

.__._.._ 2.60

..._..._._..._ ._..._.__. P:PG

~ -\55l

. . __._._. 1.43 ._-_._.. 1.60 _. _ ___......__ . 8.96

............... 19.60

....__... 4 .7 8

...___._._.. 7.73

. _..._._.__. 6.7t

....._......_..____...... EUGS-\1S2 _...... _ 1.43

..___._ . ..._.... LGO

_ . ._..._. 8.96

.... _.._.... 19.60

.._.._. .. 4.78

..__ . _ ....._._.... 7.73

..___._._ 6.7t

.___... .____.... EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 EXCESS EMISSIONS: (based on I hour timbs) EXCESS EMISSIONS: 24-Hr Totals SOURCE GRP HF HCI SO r CO VOC NOx PM HF IICI SO s CO VOC NOx PM EUG i _...._- ..._..__. ......__.. -_ _.._._..._ ._..___ . ......__.. . _.._... _.._. . --- - .._.._._.. ...._ None

__ ......_... _ .__.. .___.. . _.__..__... . ._ .._ . ._ __ ........... .._ _.__._ None ..._.._._.... EUC 2 _..._._.. .. _._..... ......_..._ _ .........._ _...___._. . .._.__...._ ......_._. _.._.._...__ . ._._._.._.. None ...__. ._ _.......... .___.. .._..... _ ..._.__ ..._.__.. None .....__... EUG 3 SDl ...._.._ .. . . ... None

.........._ __...... None

... . __........ None

._..... None

..____..... . _.._..... None

...... ...._.__.. None

_......_ None

-___.._.. ...... None

.__.._... None

__.... Nonc ..___. Nonr None

__ ...... None .__.._......... None

..__._... 

### EUG 3 SD 2

. ......_..... None .....__..... None _.._......__. None

_._._.._._ None

._..__..._ . . ...._...

. None

._...._..._... None

............... None

. ...... ............

None

. None

.................

Nonc None

. __.._ None_ _..... None

....... , .... None

.. . .. ._..._. 

### EUG 4 VD sI

._ None ...._ _. None

..___....__ None

..._._._. . None

_ _._.. . .. .. None

__._....... None

__......._ None

_........,.._. _._ None

_.... None

... ....._._._ Nonr None None ..._..._. None

......_.._ None

. _. __ __... EUG 4 VDs2

............ . . . . None

__....._.. ...._.._ \one

... _. _.......__.. None

._....._.... .. ..... None

__.._. . __......_.._.. None

. ._..__.._ None

._.._.._. None .._ __..__... -_ _.. None

__.__ . None ...._.___._ None ..._.__ . . ~ 'one _.._ ___......_._.__

None

. None

. ....___ .... None

... ... ......_.. 

### EUG 5-AVSI ....._.._... None

. ... _ None

. ............ None

._._ _. .. . Nono

__._... _ None

.._._. _ _ ._ None_

...... . . - ~ None

._......_. _ _. None

._..._.... None

_ . _.._.._.. None None

_... _.._.._._..

None None

.._.__._ None

.....__. EUG 5- WS2 __...._ .._. __.__.. 1.27

..... 1.6t

... .... ....._._._. None

. ........... None

._.__.._.._. . ___....._.._..-._....

None ..._... None

___..__. None

.___._.... .__ None

_.._._._ -

None __._._.._ None ..._ .... _........ None - None ---.._.__._... None

... None

_ __._. EUG 5- Trun None Nonr None None Non 

### r None None None None None Nono None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down due to a high temp alarm and lost consent to K3 & K4. PROCESSES AND EQUtPMENT INVOLVED: (2) AVet Scrubber N2 CORRECTI VE MEASURES TAKEN: (2) The PLC was rebooted to clear the alarms and the tentp was monitored.
ADDITIONAL fNFORMATION'*: The \Vet Scrubber was maintamed and operated according to the manufacturets mstructiuns. Thc repairs and mamtenance were done as qufckly as possible, util'vutg overtinte if needed. I certify, based on mformation and bef+ef formed atter reasonable inquey, the statements and Inforntation m thic doeument are true, accurate and complete

SIGNATURE OF REPORT)NG PERSON

Datc Reaived: Received By: Demonstralion of Cause Submitted: = ho AGENCY USE ONLY TrackingNumber: TeamlD: DateSubmitted: 's If you wish to notify the DEQ about a technological limitation, do so here and attach supporting infomtation. DEQ-Form #100-920 Remsed February 8, 2008

## OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALfrY DMSION PO BOX 1677 OKLAHOMA CITY, OK 73101-1677 

# EXCESS EMISSION FORM 'OTE: The information requested below should be submitted to the address above within 10 working days after the immediate notice is given. if you are using this form to corcect a pn,wious eport, provide only the comcted infotmation below, sign the certification, and attach a copy of tlte previous repon.
REPORT DATE: COMPANY NAh1E:

12l1812009 DaNtaOa NAM E OF INDIVIDUAL REPORTING: TITLE: PHONE: Rick Wi6fwms Plant htanager (918) 6834043 FACILITY: COUNTY: PERMIT NUMBER: Da4ltalia Muskogee 2004-198-TV (M-i) DATE AND TIME OF EXCESS EMISSION: Date Start Time: Stop Time: Duration: 12/8l2009 0:00 0:00 0:00 Hours:Min Phase 1

21:17 21:41 0:24 Hours:Min Phase2 DURATION OF EXCESS EMISSION (HOURS:MINUTES): 0:24 Houts:6linutes of Wet Sctvbber po\\•ntittte APPLICABLE LIMITATION(S) OR REQUIREMENT(S) EXCEEDED: PermH No. 2004-198-TV (M-t): Specifu: Condition 1, EUG 5 ESTIMATED EMISSIONS: BASIS OF ESTIMATE ComplianceTcsting X

__._._.. 

### SOURCEGRP HB NCL SO i CO VOC NOx PM EUG 1

.... ..... ___.... _...._ _ F.UG 2

... . _. _...._ ....__ _ _..... ...... _........ . ..._._._ .._.. . .. _".......
. ..._._..... . _. Cont Fmissions Monitoring ._. . ..__... .._.. __..___.. .__........ ._..._...._... F.UG3SD1 _.. _ _ 0.36

_...._.. ._.__.. 0.00

_ . .._..._.._.. 0.15

.____.. 5.82

. _. __ .

.

2.0I

...... .. ._.__.._. 1.83

.._....__.. 3.63

........... . EngineeringCalalation X

....__ ._....... .._.__.._ . _.. ... ...._. ta

~ C.3 SD2

. .._ .__. 0.22

_ . . . ......... 0.00

. .._._...- 0.00

--_..... 4.98

._.._._. . _...__.. 0.77 _..____._ L62

____.._.... 2.13

_....... _ Operating Logs X

.___.. __.. _. ._..__. .___..___ . ._.___.. El"(:4 VDsi 0.03 0.00

_ . . ._._.. 0.00

_ . .. 6.93 ..__.. .. 0.87 _.......... 1.36 3.00

.. Other(explain)

........ .. ......... ...._--..... ._....._.._.... _._..___. F.Ii(:4 \'Ds2

... .. O.UI

_....._.. 0.00

....._ ....._.. 0.00

. _ 3.53

_.._...._ OA4 ........_.. 0.69

....... 

### - 1.53

_._.._. __. ___._. ..._...__. .....__.. ._-_-_... EUGS-\i'Si _. .. . O.UI

___._.. . _ 0.26 

### - 0.31

.. . 12.17

__.. ..___... 0.79

. _....._. 4.I4

....__ 2.46

_....... _.._..... ......__.. ...___..... .. __..__... ..._.__... EUGS-WS2

__ . 2.30

............ . ..... _2.74 7.58 ..._. . ~ .. ~~ 4.99

. .....__... 1.48 ...__..._ 1.96

. ......... 2.55

.._..... ... ....._. ...__........ ._..__._. ._____..... _.,_.__..... EUGS

~ -Trim 1.61 -- "~ - ~~ 2.05_ ...._. 4.57

~ 3.20 0.89 1.25 0.96 Attach supporting data ALLOWEDEMISSIONS: SOURCE GRP HF HCL SO i CO VOC NOx PM EUG l __..._. .__....._ .__.__......_ ......_.....__. ..._._.._._ ___. 

### cl

~ 

### G2 _.__. . _.. EUG3SDI ._......._.. ... 0.59

....__ ... ............... 0.10 ..__..... ~ OAS

. ...__..___ 13.77

.__ __. 9.67 ~" - ~

..._. _..,._.... ~ 3.88

......_._. 7.98

.__..._..... .._....__.. Pi`C3SD2

. - 0.95

......._._..... 0.90

......._...._ 0.45

. .._.___.._._ 13.77

..._......._ 9.67

._... __..._._. 3.58

...____.. 7.98

_.__..__....._.._._. FI:Ca

~~ lasi

. 0.72

.._..._ .__._.... 0.08 ........_. 0.t8

. __..._._._......_. ti.43

..._.__ . ...... 38.33

....... ......_._...... 3.51 ...._._. 5.85

. ____. ._._.... .. El - G OS2 ._.__._ 0.52 ,._.._ ... 0.(16

.... ......._.._.._. 0.08

.. . 5.09

.__._._._ ........ 17.04

.... _.. _............ 1.56 ._._._.... 2.60

....._._....... _...._..._.._ EI'G5- \ \~ tit

.. .____ L43 ....._.,_.._ 1.60 .......__... 8.96

."._.__...
. t9.60

......_.. ..._ 4.78

....... .._..__.._.... 7.73 6.7t ...._._..._.... ._......_.. EUG5- \ \~ S2 .._..._.... L43

.__..._. _ . ....__ L60

... .__....___ 8,96

_ .__.__._... . _. 19.60

._.._ _. 4.78

.._... ...____._ 7.73 6.7t

......_.....__. EUG 5- Trim 3.57 3.88 9.68 6.75 3.67 2.00 1.80 BXCESS EMISSIONS: (based on 1 hour runhs) EXCESS EMISSIONS: 24-lir Totals SOURCE GRP HF HCI SO, CO VOC NOx PM HF HCt SO z CO VOC NOx PM EUG I

. . . . _ ,_._... ._........ ._ . . ..._.__._ . _._.._..._. ............ .__. __... _.___.....__ .. _.._. ___ . None _ . ._. __....._ ... _. _... ..._.._ . _.... ... _ .._.._. ....... ........__.. None

_ ..._ ... _. EUG 2 ._..__ ..........._. _._.._......_ _._."_.__. .....__ ___.__.._ ._ . None

. ..... .. ........ ..__...._. _... ._..... . .__..__ None .__. _._._.. EUG3SD1

.. _ . . None

...._ ...__. None

._ . .. ..__.__. _None None ..___ . . None

_ _ _ .. _. None

... _......_........ Aone None None ......__ None

....... None

.. ._.._ None

. ... .. None

... None _. EUG3SD2 ._._...__ _ None

.._...._._ .__..._ None

.. __._..___. None

._.._._... None

.....___.... ~ None ._.._.__.._ None

_......_.... None

. . None

__...._ None

..._.._._ None

_ ......... None

.... None None Nnne EUG a VDsI

.. . _ ... . None

. _.._ _ _.._.._.

. . None

... ...____... None

._..._.._ None

.._... ._ .._._. None

. __ .._.._..._.. None _.___...._ ... Nonu .._ . . ... None None ....__...__. None

. _.._ Nune .._ Nmm

. None

_ ...._.. Nanr EI:G 4\'Ds2 _. . None

_ _ ..____ ..." None

...._........ None

.._._.._._.. . None

.__._.. ..._. . None

..__. ..._..._... None .._..._ ._ None ..__ .. ..._._. None

.. __.. None

...._._..__ None

. _._._. None _.. . ..___ None

... .. . None

__._.. None

._. ._. Fl

~~ (;5_AA'SI None

__. ..._._.... None

__......._ None

..__._._ None

_.....__ ....._......_ None None None .____._ ....__ None

.__... None

.._.._.,___ None None

...__.._.._.._... Nonc

.. . . Nonu

...__.._.. None

.._...- El'GS-\\"S2

...... . 0.88 .__._..... 1.14 ._.__...._ None

_.._...... _... . None

....... ......... None

. None

. __.._... None None

.... . None

..... .._ None

__........_ None None Nmte ...._._... None F.CG 5- Trun None None None None None None None None None None None None None None NATURE AND CAUSE OF EXCESS EMISSION: (2) The scrubber was shut down due to a ntalfunetion caused by a leak in the caustic tine. PROCESSES AND EQUIPMENT INVOLVED: (2) AYet ScrubberlS2 CORRECTI VE MEASURES TAKEN: (2) InstaOed new pipe and rdtings, restarted the scrubber.
ADDITIONAL INFORMATION*: The \Vet Scrubber was maintained and operated according to the ntanufacture's ktstructions. The repairs and maintenance w'ere done as quickly as poss8tle, ut0iring overtime if needed. 1 certify, based on information and belief formed after reasonable inquiry, the statements and inforntation in this document are true, accurate and compiete

SIGNATURE OF REPORTING PERSON

Date Received: Receivcd By: Demonstration of Cause Submitted: 

### = No AGENCY USE ONLY Tracking Number: Team ID: Date Submitted: (f you wish to notify the DEQ about a technological limitation, do so here and attach supportinc information. DEQ-Form #100-920 Revised February 8, 2008